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Sample records for superstructures anti-phase domains

  1. Integral ceramic superstructure evaluation using time domain optical coherence tomography

    Science.gov (United States)

    Sinescu, Cosmin; Bradu, Adrian; Topala, Florin I.; Negrutiu, Meda Lavinia; Duma, Virgil-Florin; Podoleanu, Adrian G.

    2014-02-01

    Optical Coherence Tomography (OCT) is a non-invasive low coherence interferometry technique that includes several technologies (and the corresponding devices and components), such as illumination and detection, interferometry, scanning, adaptive optics, microscopy and endoscopy. From its large area of applications, we consider in this paper a critical aspect in dentistry - to be investigated with a Time Domain (TD) OCT system. The clinical situation of an edentulous mandible is considered; it can be solved by inserting 2 to 6 implants. On these implants a mesostructure will be manufactured and on it a superstructure is needed. This superstructure can be integral ceramic; in this case materials defects could be trapped inside the ceramic layers and those defects could lead to fractures of the entire superstructure. In this paper we demonstrate that a TD-OCT imaging system has the potential to properly evaluate the presence of the defects inside the ceramic layers and those defects can be fixed before inserting the prosthesis inside the oral cavity. Three integral ceramic superstructures were developed by using a CAD/CAM technology. After the milling, the ceramic layers were applied on the core. All the three samples were evaluated by a TD-OCT system working at 1300 nm. For two of the superstructures evaluated, no defects were found in the most stressed areas. The third superstructure presented four ceramic defects in the mentioned areas. Because of those defects the superstructure may fracture. The integral ceramic prosthesis was send back to the dental laboratory to fix the problems related to the material defects found. Thus, TD-OCT proved to be a valuable method for diagnosing the ceramic defects inside the integral ceramic superstructures in order to prevent fractures at this level.

  2. Anti-phase boundaries and magnetic domain structures in Ni{sub 2}MnGa-type Heusler alloys

    Energy Technology Data Exchange (ETDEWEB)

    Venkateswaran, S.P. [Department of Materials Science and Engineering, Carnegie Mellon University, 5000 Forbes Avenue, Pittsburgh, PA 15213 (United States); Nuhfer, N.T. [Department of Materials Science and Engineering, Carnegie Mellon University, 5000 Forbes Avenue, Pittsburgh, PA 15213 (United States); De Graef, M. [Department of Materials Science and Engineering, Carnegie Mellon University, 5000 Forbes Avenue, Pittsburgh, PA 15213 (United States)]. E-mail: degraef@cmu.edu

    2007-05-15

    The microstructure and magnetic domain structure of austenitic Heusler Ni{sub 2}MnGa are investigated as a function of heat treatment to study the interplay of anti-phase boundaries and magnetic domain walls. Conventional electron microscopy observations on arc-melted polycrystalline samples show that anti-phase boundaries in this system are invisible for standard two-beam imaging conditions, due to the large extinction distance of the Heusler superlattice reflections. Lorentz Fresnel and Foucault observations on quenched samples reveal a wavy magnetic domain morphology, reminiscent of curved anti-phase boundaries. A close inspection of the domain images indicates that the anti-phase boundaries have a magnetization state different from that of the matrix. Fresnel image simulations for a simple magnetization model are in good agreement with the observations. Magnetic coercivity measurements show a decrease in coercivity with annealing, which correlates with the microscopy observations of reduced anti-phase boundary density for annealed samples.

  3. Theoretical study of optical properties of anti phase domains in GaP

    Energy Technology Data Exchange (ETDEWEB)

    Tea, E., E-mail: etea.contact@gmail.com [Institute of R and D on Photovoltaic Energy (IRDEP) (UMR 7174, EDF-CNRS-ENSCP), 6 Quai Watier BP 49, 78401 Chatou cedex (France); FOTON INSA-Rennes (UMR 6082 CNRS), Université Européenne de Bretagne, 20 Avenue des Buttes de Coësmes, 35708 Rennes (France); Vidal, J.; Laribi, S.; Guillemoles, J.-F. [Institute of R and D on Photovoltaic Energy (IRDEP) (UMR 7174, EDF-CNRS-ENSCP), 6 Quai Watier BP 49, 78401 Chatou cedex (France); Pedesseau, L.; Cornet, C.; Jancu, J.-M.; Even, J.; Durand, O. [FOTON INSA-Rennes (UMR 6082 CNRS), Université Européenne de Bretagne, 20 Avenue des Buttes de Coësmes, 35708 Rennes (France)

    2014-02-14

    III-V/Si heterostructures are currently investigated for silicon photonics and solar energy conversion. In particular, dilute nitride alloy GaAsPN grown on a GaP/Si platform exhibits lattice match with Si and an optimal band gap configuration for tandem solar cell devices. However, monolithic “coherent” growth of the GaP thin layer on Si suffers from the nucleation of extended structural defects, which can hamper device operation as well as the GaP/Si interface level and through their propagation inside the overall heterostructure. However, the effect of such structural defects on optical and transport properties is actually not well understood in details. In this letter, we investigate the anti phase domains defect (also called inversion domains) by means of ab initio calculations giving insights into the alteration of optical and transport properties of GaP due to the defective GaP/Si interface.

  4. The Role of Anti-Phase Domains in InSb-Based Structures Grown on On-Axis and Off-Axis Ge Substrates

    Energy Technology Data Exchange (ETDEWEB)

    Debnath, M. C.; Mishima, T. D.; Santos, M. B. [Homer L. Dodge Department of Physics and Astronomy, University of Oklahoma, Norman, OK 73019 (United States); Hossain, K.; Holland, O. W. [Amethyst Research, Inc., 1405 4th Ave NW, Ardmore, OK 73401 (United States)

    2011-12-26

    Anti-phase domains form in InSb epilayers and InSb/Al{sub 0.20}In{sub 0.80}Sb single quantum wells when grown upon on-axis (001) Ge substrates by molecular beam epitaxy. Domain formation is partially suppressed through growth on Ge substrates with surfaces that are several degrees off the (001) or (211) axis. By using off-axis Ge substrates, room-temperature electron mobilities increased to {approx}60,000 cm{sup 2}/V-s and {approx}14,000 cm{sup 2}/V-s for a 4.0-{mu}m-thick InSb epilayer and a 25-nm InSb quantum well, respectively.

  5. Simulations of super-structure domain walls in two dimensional assemblies of magnetic nanoparticles

    DEFF Research Database (Denmark)

    Jordanovic, Jelena; Beleggia, Marco; Schiøtz, Jakob

    2015-01-01

    taking the role of the atomic spins. The coupling is, however, different. The superspins interact only by dipolar interactions as exchange coupling between individual nanoparticles may be neglected due to interparticle spacing. We observe that it is energetically favorable to introduce domain walls...... oriented along the long dimension of nanoparticle assemblies rather than along the short dimension. This is unlike what is typically observed in continuous magnetic materials, where the exchange interaction introduces an energetic cost proportional to the area of the domain walls. Structural disorder...

  6. Topological Insulators from Electronic Superstructures

    Science.gov (United States)

    Sugita, Yusuke; Motome, Yukitoshi

    2016-07-01

    The possibility of realizing topological insulators by the spontaneous formation of electronic superstructures is theoretically investigated in a minimal two-orbital model including both the spin-orbit coupling and electron correlations on a triangular lattice. Using the mean-field approximation, we show that the model exhibits several different types of charge-ordered insulators, where the charge disproportionation forms a honeycomb or kagome superstructure. We find that the charge-ordered insulators in the presence of strong spin-orbit coupling can be topological insulators showing quantized spin Hall conductivity. Their band gap is dependent on electron correlations as well as the spin-orbit coupling, and even vanishes while showing the massless Dirac dispersion at the transition to a trivial charge-ordered insulator. Our results suggest a new route to realize and control topological states of quantum matter by the interplay between the spin-orbit coupling and electron correlations.

  7. Implementing Composite Superstructures in Large Passenger Ships

    DEFF Research Database (Denmark)

    Karatzas, Vasileios; Berggreen, Christian; Jensen, Jørgen Juncher;

    2015-01-01

    This study focuses on the structural response of the part of the superstructure of a RoPax ferry that has been redesigned using composite materials. The composite superstructure is presented and subsequently compared to the existing steel design considering different loading conditions by the use...... of FE modelling.Results indicate that it is not the structural response of the superstructure that inhibits the implementation of composites in the superstructures of large passenger ships but the complicated design procedure and the acceptance of such solutions by the regulatory bodies....

  8. Superstructures in Rayleigh-Benard convection

    Science.gov (United States)

    Stevens, Richard; Verzicco, Roberto; Lohse, Detlef

    2016-11-01

    We study the heat transfer and the flow structures in Rayleigh-Bénard convection as function of the Rayleigh number Ra and the aspect ratio. We consider three-dimensional direct numerical simulations (DNS) in a laterally periodic geometry with aspect ratios up to Γ =Lx /Lz =Ly /Lz = 64 at Ra =108 , where Lx and Ly indicate the horizontal domain sizes and Lz the height. We find that the heat transport convergences relatively quickly with increasing aspect ratio. In contrast, we find that the large scale flow structures change significantly with increasing aspect ratio due to the formation of superstructures. For example, at Ra =108 we find the formation of basically only one large scale circulation roll in boxes with an aspect ratio up to 8. For larger boxes we find the formation of multiple of these extremely large convection rolls. We illustrate this by movies of horizontal cross-section of the bulk and the boundary layer and analyze them by using spectra in the boundary layer and the bulk. In addition, we study the effect of the large scale flow structures on the mean and higher order temperature and velocity statistics in the boundary layer and the bulk by comparing the simulation results obtained in different aspect ratio boxes. Foundation for fundamental Research on Matter (FOM), Netherlands Center for Multiscale Catalytic Energy Conversion (MCEC), SURFsara, Gauss Large Scale project.

  9. Superstructures: First Cold Test and Future Applications

    Energy Technology Data Exchange (ETDEWEB)

    J. Sekutowicz; C Albrecht; V Ayvazyan; R Bandelmann; T Buttner; P Castro; S Choroba; J Eschke; B Faatz; A Gossel; K Honkavaara; B Horst; J Iverson; K Jensch; H Kaiser; R Kammering; G Kreps; D Kostin; J Lorkiewicz; R Lange; A Matheisen; W -D Moller; H -B Peters; D Proch; K Rehlich; H Schlarb; S Schrieber; D Reschke; S Simrock; W Singer; X Singer; K Twarowski; T Weichert; M Wojtkiewicz; G Wendt; K Zapfe; M Liepe; M Huening; M Ferrario; E Plawski; C Pagani; P Kneisel; G Wu; N Baboi; C Thomas; H Chen; W Huang; C Tang; S Zheng

    2003-09-01

    Superstructures, chains of superconducting multi-cell cavities (subunits) connected by e/2 long tube(s) have been proposed as an alternative layout for the TESLA main accelerator [1]. After three years of preparation, two superstructures, each made of two weakly coupled superconducting 7-cell subunits driven by a single Fundamental Power Coupler (FPC), have been installed in the Tesla Test Facility linac for beam tests. Energy stability, HOM damping, frequency and field adjustment methods were tested. The measured results confirmeSuperstructures, chains of superconducting multi-cell cavities (subunits) connected by e/2 long tube(s) have been proposed as an alternative layout for the TESLA main accelerator [1]. After three years of preparation, two superstructures, each made of two weakly coupled superconducting 7-cell subunits driven by a single Fundamental Power Coupler (FPC), have been installed in the Tesla Test Facility linac for beam tests. Energy stability, HOM damping, frequency and field adjustment methods were tested. The measured results confirmed expectation on the superstructure performance and proved that an alternative layout for the 800 GeV upgrade of the TESLA collider is feasible. We report on the test and give here an overview of its results. The tests confirmed very good damping of HOMs in superstructures and thus has opened a possible new application of this concept to high current energy recovery machines. We have built two 1.5 GHz copper models of two superstructures: 2x5-cells and 2x2-cells to prove further improvement of HOM damping. This contribution presents also measured results on these models. d expectations on the superstructure performance and proved that an alternative layout for the 800 GeV upgrade of the TESLA collider is feasible. We report on the test and give here an overview of its results.

  10. Tetrahedral Units: For Dodecahedral Super-Structures

    CERN Document Server

    Ortiz, Y; Liebman, J F

    2016-01-01

    Different novel organic-chemical possibilities for tetrahedral building units are considered, with attention to their utility in constructing different super-structures. As a representative construction we consider the use of sets of 20 such identical tetrahedral units to form a super-dodecahedron.

  11. Atomic model of anti-phase boundaries in a face-centred icosahedral Zn-Mg-Dy quasicrystal

    CERN Document Server

    Wang Jian Bo; Wang Ren Hui

    2003-01-01

    An atomic model in the physical space for an anti-phase boundary (APB) in the ordered face-centred icosahedral Zn-Mg-Dy quasicrystal phase is presented, based on a six-dimensional model suggested by Ishimasa and Shimizu (2000 Mater. Sci. Eng. A 294-296 232, Ishimasa 2001 private communication). The physical space atomic positions of the defected structure were used for the calculation of the corresponding exit-plane wavefunction and high-resolution transmission electron microscopy images. The analysis of the defect by inverse Fourier transformation reveals that when superstructure reflection spots are used for back-transformation, then at the APB, bright lattice fringes are found to turn into dark ones, and vice versa. When fundamental reflections are used, the APB is not visible. This phenomenon is the same as the corresponding experimental study recently published by Heggen et al(2001a Phys. Rev. B 64 014202). Based on this atomic model it is found that the APB perpendicular to a fivefold axis A5 (APB-A5) i...

  12. Superstructure of stapes. An analysis by HRCT

    Energy Technology Data Exchange (ETDEWEB)

    Horiuchi, Yasuharu; Hunai, Hiroaki; Ichimura; Keiiti; Iinuma, Toshitaka; Oyama, Kazuyuki

    1989-03-01

    High-resolution Computed Tomography (HRCT) of the temporal bone has now become a routine test for the diagnosis of various temporal bone lesions. Correct assessment of such minute structures as ossicles, especially stapes, is important in the pre-operative HRCT evaluation. On the other hand, analysis for the reliability of HRCT findings has not been done, including the superstructure of the stapes. A retrospectively study was done in order to assess the availability of HRCT findings in axial overlapping scans in 226 ears, with respect to the superstructures of stapes. The study was concerned with the analysis of HRCTs of 148 normal ears, 71 ears of chronic otitis media and 7 ears of ossicular abnormalities. HRCT findings were compared to those of surgeries in pathological cases. The present study revealed that the superstructures of stapes are noted in 70% when the stapes is surrounded by air. The major limitations in the proper analysis of stapes by HRCT are partial volume averaging and effects of soft tissue silhouetting, this is especially so when the stapes is surrounded by soft tissue density.

  13. Dental implant superstructures by superplastic forming

    Energy Technology Data Exchange (ETDEWEB)

    Curtis, R.V.; Garriga-Majo, D.; Soo, S.; Pagliaria, D. [Kings Coll., London (United Kingdom). Dept. of Dental Biomaterials Science; Juszczyk, A.S.; Walter, J.D. [Kings Coll., London (United Kingdom). Dept. of Prosthetic Dentistry

    2001-07-01

    A novel application of superplastic forming is described for the production of fixed-bridge dental implant superstructures. Finite element analysis (FEA) has shown that Ti-6Al-4V sheet would be a suitable candidate material for the design of a fixed-bridge dental implant superstructure. Traditionally superstructures are cast in gold alloy onto pre-machined gold alloy cylinders but castings are often quite bulky and 25% of castings do not fit accurately (1) which means that sectioning and soldering is required to obtain a fit that is clinically acceptable and will not prejudice the integrity of the commercially pure cp-titanium implants osseointegrated with the bone. Superplastic forming is shown to be a forming technique that would allow the production of strong, light-weight components of thin section with low residual stress that could be suitable for such applications. Considerable cost savings over traditional dental techniques can be achieved using a low-cost ceramic die material. The properties of these die materials are optimised so that suitable components can be produced. Satisfactory hot strength is demonstrated and thermal properties are matched to those of the titanium alloy for accurate fit of the prosthesis. (orig.)

  14. Modular assembly of superstructures from polyphenol-functionalized building blocks

    Science.gov (United States)

    Guo, Junling; Tardy, Blaise L.; Christofferson, Andrew J.; Dai, Yunlu; Richardson, Joseph J.; Zhu, Wei; Hu, Ming; Ju, Yi; Cui, Jiwei; Dagastine, Raymond R.; Yarovsky, Irene; Caruso, Frank

    2016-12-01

    The organized assembly of particles into superstructures is typically governed by specific molecular interactions or external directing factors associated with the particle building blocks, both of which are particle-dependent. These superstructures are of interest to a variety of fields because of their distinct mechanical, electronic, magnetic and optical properties. Here, we establish a facile route to a diverse range of superstructures based on the polyphenol surface-functionalization of micro- and nanoparticles, nanowires, nanosheets, nanocubes and even cells. This strategy can be used to access a large number of modularly assembled superstructures, including core-satellite, hollow and hierarchically organized supraparticles. Colloidal-probe atomic force microscopy and molecular dynamics simulations provide detailed insights into the role of surface functionalization and how this facilitates superstructure construction. Our work provides a platform for the rapid generation of superstructured assemblies across a wide range of length scales, from nanometres to centimetres.

  15. The line shape of the Ortho-II superstructure reflection in YBa2Cu3O6.5

    DEFF Research Database (Denmark)

    Schleger, P.; Hadfield, R.; Casalta, H.;

    1994-01-01

    Neutron and synchrotron x-ray measurements of the Ortho-II superstructure reflections on a high quality single crystal of YBa2Cu3O6.5 revealed that the intrinsic line shape is a Lorentzian to the power 5/2. It is argued that such a line shape implies late-stage domain coarsening of a quenched...

  16. The route to protein aggregate superstructures

    DEFF Research Database (Denmark)

    Vetri, Valeria; Foderà, Vito

    2015-01-01

    Depending on external conditions, native proteins may change their structure and undergo different association routes leading to a large scale polymorphism of the aggregates. This feature has been widely observed but is not fully understood yet. This review focuses on morphologies, physico......-chemical properties and mechanisms of formation of amyloid structures and protein superstructures. In particular, the main focus will be on protein particulates and amyloid-like spherulites, briefly summarizing possible experimental methods of analysis. Moreover, we will highlight the role of protein conformational...

  17. Hydrothermal synthesis and photoluminescent properties of stacked indium sulfide superstructures.

    Science.gov (United States)

    Xing, Yan; Zhang, Hongjie; Song, Shuyan; Feng, Jing; Lei, Yongqian; Zhao, Lijun; Li, Meiye

    2008-03-28

    Unusual hierarchical stacked superstructures of cubic beta-In2S3 were fabricated via a facile hydrothermal process in the presence of a surfactant cetyltrimethylammonium bromide CTAB; the 3D superstructures were developed by helical propagation of surface steps from microflakes of 10-20 nm thickness.

  18. Non covalent assembly of coordination superstructures

    CERN Document Server

    Khlobystov, A N

    2002-01-01

    The main topic of this work is the design of discrete and polymeric multi-component coordination structures using non-covalent interactions between organic and inorganic molecular components. All of the structures described herein are based on transition metal cations and N-donor heterocyclic bis-exodentate ligands with different geometries and various spacer functionalities. The predominant method used for the structural characterisation of the complexes was single crystal X-ray crystallography. X-ray powder diffraction, IR and NMR spectroscopies and TEM and AFM imaging were used to characterise the bulk products from the reactions. Chapter 1 is a comparative review of non-covalent interactions relevant to coordination superstructures and covers the latest developments in the area of crystal engineering and supramolecular chemistry. The nature, geometry and relative energy of the non-covalent interactions are considered in detail in order to reveal their influence on the structure and properties of complexes...

  19. Enhanced thermophysical properties via PAO superstructure

    Science.gov (United States)

    Pournorouz, Zahra; Mostafavi, Amirhossein; Pinto, Aditya; Bokka, Apparao; Jeon, Junha; Shin, Donghyun

    2017-01-01

    For the last few years, molten salt nanomaterials have attracted many scientists for their enhanced specific heat by doping a minute concentration of nanoparticles (up to 1% by weight). Likewise, enhancing the specific heat of liquid media is important in many aspects of engineering such as engine oil, coolant, and lubricant. However, such enhancement in specific heat was only observed for molten salts, yet other engineering fluids such as water, ethylene glycol, and oil have shown a decrease of specific heat with doped nanoparticles. Recent studies have shown that the observed specific heat enhancement resulted from unique nanostructures that were formed by molten salt molecules when interacting with nanoparticles. Thus, such enhancement in specific heat is only possible for molten salts because other fluids may not naturally form such nanostructures. In this study, we hypothesized such nanostructures can be mimicked through in situ formation of fabricated nano-additives, which are putative nanoparticles coated with useful organic materials (e.g., polar-group-ended organic molecules) leading to superstructures, and thus can be directly used for other engineering fluids. We first applied this approach to polyalphaolefin (PAO). A differential scanning calorimeter (DSC), a rheometer, and a customized setup were employed to characterize the heat capacity, viscosity, and thermal conductivity of PAO and PAO with fabricated nano-additives. Results showed 44.5% enhanced heat capacity and 19.8 and 22.98% enhancement for thermal conductivity and viscosity, respectively, by an addition of only 2% of fabricated nanostructures in comparison with pure PAO. Moreover, a partial melting of the polar-group-ended organic molecules was observed in the first thermal cycle and the peak disappeared in the following cycles. This indicates that the in situ formation of fabricated nano-additives spontaneously occurs in the thermal cycle to form nanostructures. Figure of merit analyses have

  20. ELABORATION OF THE SUPERSTRUCTURE OF THE BULGARIAN HOTEL INDUSTRY

    Directory of Open Access Journals (Sweden)

    Tanya Dabeva

    2010-12-01

    Full Text Available The purpose of the paper is to suggest some terms of reference for the elaboration of the superstructure of the Bulgarian hotel industry. The suggestions are based on the analysis of the superstructure at present. Its capacity, main types of accommodation establishments and their distribution by categories and territory are examined. An analysis is made of some resulting indices such as overnight stays and average stay. The main positive, respectively negative features of the superstructure have been analyzed. Concrete terms of reference have been given in order to overcome the problems specified.

  1. A Generic Methodology for Superstructure Optimization of Different Processing Networks

    DEFF Research Database (Denmark)

    Bertran, Maria-Ona; Frauzem, Rebecca; Zhang, Lei

    2016-01-01

    In this paper, we propose a generic computer-aided methodology for synthesis of different processing networks using superstructure optimization. The methodology can handle different network optimization problems of various application fields. It integrates databases with a common data architectur...

  2. A Generic Methodology for Superstructure Optimization of Different Processing Networks

    DEFF Research Database (Denmark)

    Bertran, Maria-Ona; Frauzem, Rebecca; Zhang, Lei;

    2016-01-01

    In this paper, we propose a generic computer-aided methodology for synthesis of different processing networks using superstructure optimization. The methodology can handle different network optimization problems of various application fields. It integrates databases with a common data architecture...

  3. Superstructure formation and the structural phase diagram of YBasub>2sub>Cu>3sub>O>6sub>+x>

    DEFF Research Database (Denmark)

    Andersen, N.H.; Zimmermann, M. von; Frello, T.

    1999-01-01

    of the 2D ASYNNNI lattice gas model to include Coulomb interactions between oxygen atoms on chains that are 2a apart, we account for the observed structural phases, and confirm that the superstructures freeze into finite size domains at low temperatures. (C) 1999 Elsevier Science B.V. All rights reserved....

  4. Organization of anti-phase synchronization pattern in neural networks: what are the key factors?

    Directory of Open Access Journals (Sweden)

    Dong eLi

    2011-12-01

    Full Text Available Anti-phase oscillation has been widely observed in cortical neuralnetwork. Elucidating the mechanism underlying the organization ofanti-phase pattern is of significance for better understanding morecomplicated pattern formations in brain networks. In dynamicalsystems theory, the organization of anti-phase oscillation patternhas usually been considered to relate to time-delay in coupling.This is consistent to conduction delays in real neural networks inthe brain due to finite propagation velocity of action potentials.However, other structural factors in cortical neural network, suchas modular organization (connection density and the coupling types(excitatory or inhibitory, could also play an important role. Inthis work, we investigate the anti-phase oscillation patternorganized on a two-module network of either neuronal cell model orneural mass model, and analyze the impact of the conduction delaytimes, the connection densities, and coupling types. Our resultsshow that delay times and coupling types can play key roles in thisorganization. The connection densities may have an influence on thestability if an anti-phase pattern exists due to the other factors.Furthermore, we show that anti-phase synchronization of slowoscillations can be achieved with small delay times if there isinteraction between slow and fast oscillations. These results aresignificant for further understanding more realistic spatiotemporaldynamics of cortico-cortical communications.

  5. Phase synchronization and anti-phase synchronization of chaos for degenerate optical parametric oscillator

    Institute of Scientific and Technical Information of China (English)

    Feng Xiu-Qin; Shen Ke

    2005-01-01

    We have investigated chaotic synchronization in the generalized sense for the degenerate optical parametric oscillator (DOPO). The numerical results show that two unidirectional coupling DOPOs in chaos can be completely phase synchronization or anti-phase synchronization with a suitable coupling coefficient under which the maximum condition Lyapunov exponent (MCLE) is negative. Phase synchronization and anti-phase synchronization of chaos can be realized through positive and negative coupling. On the other hand, the different synchronization states depend on the coupling types used in the DOPO systems.

  6. Modifications of the superstructure for the staple implant.

    Science.gov (United States)

    Guerra, L R; Larsen, H D; Finger, I M; Jaen, F

    1984-12-01

    Two techniques have been described to expedite fabrication and reduce the cost of prostheses made for staple implants. The techniques permit placement of a simulated transosseous pin within the master cast. At the time of denture placement in technique No. 1, the coping-bar attachment assembly is cemented (Fig. 12). In technique No. 2 the superstructure is placed over the transosteal pins and secured between the locknuts to maintain the base of the lower locknut 1.5 mm from the crest of the alveolar ridge (Fig. 13). Technique No. 2 permits removal of the superstructure as desired. Patients should be instructed in proper oral hygiene and denture care.

  7. Superstructure-based optimization of biorefinery networks: Production of biodiesel

    DEFF Research Database (Denmark)

    2015-01-01

    through a practical case study for the production biodiesel from a variety of feedstock. The different biorefinery processing alternatives are represented in a superstructure and the associated data is collected and stored in a database. Once a specific biorefinery synthesis problem is formulated...

  8. Templated and template-free fabrication strategies for zero-dimensional hollow MOF superstructures.

    Science.gov (United States)

    Kim, Hyehyun; Lah, Myoung Soo

    2017-03-23

    Various fabrication strategies for hollow metal-organic framework (MOF) superstructures are reviewed and classified using various types of external templates and their properties. Hollow MOF superstructures have also been prepared without external templates, wherein unstable intermediates obtained during reactions convert to the final hollow MOF superstructures. Many hollow MOF superstructures have been fabricated using hard templates. After the core-shell core@MOF structure was prepared using a hard template, the core was selectively etched to generate a hollow MOF superstructure. Another approach for generating hollow superstructures is to use a solid reactant as a sacrificial template; this method requires no additional etching process. Soft templates such as discontinuous liquid/emulsion droplets and gas bubbles in a continuous soft phase have also been employed to prepare hollow MOF superstructures.

  9. Anti-phase synchronization and ergodicity in arrays of oscillators coupled by an elastic force

    Science.gov (United States)

    Dilão, Rui

    2014-04-01

    We have proposed a mechanism of interaction between two non-linear dissipative oscillators, leading to exact and robust anti-phase and in-phase synchronization. The system we have analyzed is a model for the Huygens's two pendulum clocks system, as well as a model for synchronization mediated by an elastic media. Here, we extend these results to arrays, finite or infinite, of conservative pendula coupled by linear elastic forces. We show that, for two interacting pendula, this mechanism leads always to synchronized anti-phase small amplitude oscillations, and it is robust upon variation of the parameters. For three or more interacting pendula, this mechanism leads always to ergodic non-synchronized oscillations. In the continuum limit, the pattern of synchronization is described by a quasi-periodic longitudinal wave.

  10. Experimental demonstration of a dual-frequency laser free from anti-phase noise

    CERN Document Server

    Amili, Abdelkrim El; De, Syamsundar; Schwartz, Sylvain; Feugnet, Gilles; Pocholle, Jean-Paul; Bretenaker, Fabien; Alouini, Mehdi

    2012-01-01

    A reduction of more than 20 dB of the intensity noise at the anti-phase relaxation oscillation frequency is experimentally demonstrated in a two-polarization dual-frequency solid-state laser without any optical or electronic feedback loop. Such a behavior is inherently obtained by aligning the two orthogonally polarized oscillating modes with the crystallographic axes of a (100)-cut neodymium-doped yttrium aluminum garnet active medium. The anti-phase noise level is shown to increase as soon as one departs from this peculiar configuration, evidencing the predominant role of the nonlinear coupling constant. This experimental demonstration opens new perspectives on the design and realization of extremely low noise dual-frequency solid-state lasers.

  11. Partner influence and in-phase versus anti-phase physiological linkage in romantic couples.

    Science.gov (United States)

    Reed, Rebecca G; Randall, Ashley K; Post, Jessica H; Butler, Emily A

    2013-06-01

    Between-partner physiological linkage can be in-phase (changes in unison), or anti-phase (changes in opposite directions). In the context of conversation we predicted that in-phase linkage would occur when partners exert strong influence on each other; anti-phase linkage would occur due to the behavioral coordination of turn taking. To test this, blood pressure, inter-beat interval, and skin conductance were recorded from 44 heterosexual couples while they discussed how they influence each other's health-related behaviors. Partner influence was assessed in two ways: 1) partners' global perceptions of how they try to influence each other's health; and 2) behavioral manifestations of influence, specifically demand-withdraw behavior. As predicted, both measures of partner influence moderated physiological linkage of blood pressure such that at low levels of influence linkage was "anti-phase" and at high levels linkage was "in-phase." Several alternative hypotheses were ruled out; the effects were not due to relationship conflict, emotional experience, or simply the pattern of blood pressure over time. These results suggest that partner influence may be driving physiological linkage, which may be one avenue through which partners can affect each other's health.

  12. A Generic Methodology for Superstructure Optimization of Different Processing Networks

    DEFF Research Database (Denmark)

    Bertran, Maria-Ona; Frauzem, Rebecca; Zhang, Lei

    , biorefineries, and carbon dioxide utilization are considered.In the synthesis stage, the processing alternatives are represented in a superstructure and the associated data is collected and stored in a database. Once a specific process synthesis problem is formulated, the existing superstructure is retrieved...... of processing networks. This is illustrated through case studies from two applications: the synthesis of biorefinery networks and the synthesis of sustainable carbon dioxide utilization processes.......A large focus is placed on sustainability and sustainable practices as a result of the arising environmental issues. As an element of this, sustainable process synthesis and design becomes important. A generic, systematic methodology is proposed for solving the problem of optimal design...

  13. The impact of superstructures in the Cosmic Microwave Background

    Science.gov (United States)

    Ilić, Stéphane; Langer, Mathieu; Douspis, Marian

    2016-10-01

    In 2008, Granett et al. claimed a direct detection of the integrated Sachs-Wolfe (iSW) effect, through the stacking of CMB patches at the positions of identified superstructures. Additionally, the high amplitude of their measured signal was reported to be at odds with predictions from the standard model of cosmology. However, a closer inspection of these results prompts multiple questions, more specifically about the amplitude and significance of the expected signal. We propose here an original theoretical prediction of the iSW effect produced by such superstructures. We use simulations based on GR and the LTB metric to reproduce cosmic structures and predict their exact theoretical iSW effect on the CMB. The amplitudes predicted with this method are consistent with the signal measured when properly accounting the contribution of the non-negligible (and fortuitous) primordial CMB fluctuations to the total signal. It also highlights the tricky nature of stacking measurements and their interpretation.

  14. Permanent excimer superstructures by supramolecular networking of metal quantum clusters

    Science.gov (United States)

    Santiago-Gonzalez, Beatriz; Monguzzi, Angelo; Azpiroz, Jon Mikel; Prato, Mirko; Erratico, Silvia; Campione, Marcello; Lorenzi, Roberto; Pedrini, Jacopo; Santambrogio, Carlo; Torrente, Yvan; De Angelis, Filippo; Meinardi, Francesco; Brovelli, Sergio

    2016-08-01

    Excimers are evanescent quasi-particles that typically form during collisional intermolecular interactions and exist exclusively for their excited-state lifetime. We exploited the distinctive structure of metal quantum clusters to fabricate permanent excimer-like colloidal superstructures made of ground-state noninteracting gold cores, held together by a network of hydrogen bonds between their capping ligands. This previously unknown aggregation state of matter, studied through spectroscopic experiments and ab initio calculations, conveys the photophysics of excimers into stable nanoparticles, which overcome the intrinsic limitation of excimers in single-particle applications—that is, their nearly zero formation probability in ultra-diluted solutions. In vitro experiments demonstrate the suitability of the superstructures as nonresonant intracellular probes and further reveal their ability to scavenge reactive oxygen species, which enhances their potential as anticytotoxic agents for biomedical applications.

  15. Superstructure Strategy: Do Indonesian EFL Learners Use It?

    Directory of Open Access Journals (Sweden)

    Evy C Ridwan

    1997-01-01

    Full Text Available Abstract: This paper reports on a study conducted among Indonesian undergraduate students majoring in English as a Foreign Language (EFL. One strategy that learners generally use to understand the main ideas of an expository text is the superstructure strategy (i.e., utilizing the text structure to understand the main ideas. While research in English as First Language reading has demonstrated the benefit of using this strategy, little do we know whether Indonesian EFL learners use this strategy in reading and whether this strategy is beneficial to them or not. Two versions of an expository text were developed: One version had an explicit text structure, with the inclusion of discourse markers, to elicit learners to use the superstructure strategy; the other was without discourse markers. It was hypothesized that learners who read the version with an explicit text structure would utilize the superstructure strategy thereby comprehending main ideas better than those who read the other version. Additionally, to confirm the hypothesis learners were also asked to answer a questionnaire developed from O'Malley and Chamot (1993 followed by an interview to find out if EFL learners used other strategies to comprehend main ideas.

  16. SELF-ORGANIZATION OF LEAD SULFIDE QUANTUM DOTS INTO SUPERSTRUCTURES

    Directory of Open Access Journals (Sweden)

    Elena V. Ushakova

    2014-11-01

    Full Text Available The method of X-ray structural analysis (X-ray scattering at small angles is used to show that the structures obtained by self-organization on a substrate of lead sulfide (PbS quantum dots are ordered arrays. Self-organization of quantum dots occurs at slow evaporation of solvent from a cuvette. The cuvette is a thin layer of mica with teflon ring on it. The positions of peaks in SAXS pattern are used to calculate crystal lattice of obtained ordered structures. Such structures have a primitive orthorhombic crystal lattice. Calculated lattice parameters are: a = 21,1 (nm; b = 36,2 (nm; c = 62,5 (nm. Dimensions of structures are tens of micrometers. The spectral properties of PbS QDs superstructures and kinetic parameters of their luminescence are investigated. Absorption band of superstructures is broadened as compared to the absorption band of the quantum dots in solution; the luminescence band is slightly shifted to the red region of the spectrum, while its bandwidth is not changed much. Luminescence lifetime of obtained structures has been significantly decreased in comparison with the isolated quantum dots in solution, but remained the same for the lead sulfide quantum dots close-packed ensembles. Such superstructures can be used to produce solar cells with improved characteristics.

  17. Fabrication of luminescent Eu{sub 2}O{sub 3} superstructures.

    Energy Technology Data Exchange (ETDEWEB)

    Pol, V. G.; Calderon-Moreno, J. M.; Chemical Sciences and Engineering Division; Inst. of Physical Chemistry

    2010-01-01

    This Letter demonstrates a solvent-free efficient synthesis process to prepare self-assembled two-dimensional Eu{sub 2}O{sub 3} luminescent nanoplates to yield a superstructure. In the first step, Eu{sub 2}O{sub 3}CO{sub 3} superstructures are fabricated by the thermolysis [700C] of a single precursor, europium acetate, in a closed reactor under autogenic pressure. The as-prepared Eu{sub 2}O{sub 3}CO{sub 3} superstructures are further heated in air to 750C to facilitate the fabrication of Eu{sub 2}O{sub 3} superstructures. A systematic morphological, structural, and compositional characterization of Eu{sub 2}O{sub 3} superstructures is carried out. The photoluminescent properties and mechanism for the strong red emission of the photoexcited Eu{sub 2}O{sub 3} superstructures is proposed.

  18. Synchronized Anti-Phase and In-Phase Oscillations of Intracellular Calcium Ions in Two Coupled Hepatocytes System

    Institute of Scientific and Technical Information of China (English)

    SHEN Chuan-Sheng; CHEN Han-Shuang; ZHANG Ji-Qian

    2008-01-01

    @@ We study the dynamic behaviour of two intracellular calcium oscillators that are coupled through gap junctions both to Ca2+ and inositol(1,4,5)-trisphosphate(IPa).It is found that synchronized anti-phase and in-phase oscillations of cytoplasmic calcium coexist in parameters space.Especially,synchronized anti-phase oecillations only occur near the onset of a Hopf bifurcation point when the velocity of IP3 synthesis is increased.

  19. Self-organization of nickel nanoparticles dispersed in acetone: From separate nanoparticles to three-dimensional superstructures

    Directory of Open Access Journals (Sweden)

    I. Hernández-Pérez

    2017-02-01

    Full Text Available Sonochemical synthesis of monodisperse nickel nanoparticles (Ni-NPs by reduction of Ni acetylacetonate in the presence of polyvinylpyrrolidone stabilizer is reported. The Ni-NPs size is readily controlled to 5 nanometer diameter with a standard deviation of less than 5%. The as-prepared Ni-NPs sample was dispersed in acetone, for 4 weeks. For structural analysis was not applied to a magnetic field or heat treatment as key methods to direct the assembly. The transition from separate Ni-NPs into self-organization of three dimensions (3D superstructures was studied by electron microscopy. Experimental analysis suggests that the translation and rotation movement of the Ni-NPs are governed by magnetic frustration which promotes the formation of different geometric arrangements in two dimensions (2D. The formation of 3D superstructures is confirmed from scanning electron microscopy revealing a layered domain that consists of staking of several monolayers having multiple well-defined supercrystalline domains, enabling their use for optical, electronic and sensor applications.

  20. Garden-like perovskite superstructures with enhanced photocatalytic activity.

    Science.gov (United States)

    Ye, Meidan; Wang, Mengye; Zheng, Dajiang; Zhang, Nan; Lin, Changjian; Lin, Zhiqun

    2014-04-07

    By subjecting amorphous flower-like TiO2 to a facile hydrothermal synthesis in the presence of Sr(2+), garden-like perovskite SrTiO3 superstructures were achieved. The amorphous TiO2 was preformed using ZnO flowers as templates. Different three-dimensional SrTiO3 architectures were coexisted in the garden, including SrTiO3 flowers composed of several hollow sword-shaped petals, many sheet-shaped petals or numerous flake-shaped petals, and SrTiO3 grass consisting of a number of long blades. These SrTiO3 superstructures were simultaneously grown on fluorine-doped tin oxide (FTO) substrates. On the basis of a comprehensive study on the effects of growth time, temperature, initial concentrations of precursor, and pH, the formation of these various hierarchical architectures was attributed primarily to the dissolution of amorphous TiO2 and precipitation of perovskite crystals, followed by the Ostwald ripening process of perovskite nanocrystals and self-organization of perovskite building blocks. Interestingly, this approach can be readily extended to create other perovskite structures, including dendritic BaTiO3 and nest-like CaTiO3, as well as PbTiO3 transformed from plate-like pyrochlore Pb2Ti2O6 after post-thermal treatment. Garden-like SrTiO3 superstructures showed a superior photocatalytic performance when compared to other as-prepared semiconductors and perovskite materials (i.e., ZnO, TiO2, BaTiO3, CaTiO3 and PbTiO3), probably due to their intrinsic photocatalytic activity and special garden-like features with a coexistence of various structures that significantly facilitated the adsorption and diffusion of methyl blue (MB) molecules and oxygen species in the photochemical reaction of MB degradation.

  1. Imprint of DES superstructures on the cosmic microwave background

    Science.gov (United States)

    Kovács, A.; Sánchez, C.; García-Bellido, J.; Nadathur, S.; Crittenden, R.; Gruen, D.; Huterer, D.; Bacon, D.; Clampitt, J.; DeRose, J.; Dodelson, S.; Gaztañaga, E.; Jain, B.; Kirk, D.; Lahav, O.; Miquel, R.; Naidoo, K.; Peacock, J. A.; Soergel, B.; Whiteway, L.; Abdalla, F. B.; Allam, S.; Annis, J.; Benoit-Lévy, A.; Bertin, E.; Brooks, D.; Buckley-Geer, E.; Rosell, A. Carnero; Carrasco Kind, M.; Carretero, J.; Cunha, C. E.; D'Andrea, C. B.; da Costa, L. N.; DePoy, D. L.; Desai, S.; Eifler, T. F.; Finley, D. A.; Flaugher, B.; Fosalba, P.; Frieman, J.; Giannantonio, T.; Goldstein, D. A.; Gruendl, R. A.; Gutierrez, G.; James, D. J.; Kuehn, K.; Kuropatkin, N.; Marshall, J. L.; Melchior, P.; Menanteau, F.; Nord, B.; Ogando, R.; Plazas, A. A.; Romer, A. K.; Sanchez, E.; Scarpine, V.; Sevilla-Noarbe, I.; Sobreira, F.; Suchyta, E.; Swanson, M.; Tarle, G.; Thomas, D.; Walker, A. R.; DES Collaboration

    2017-03-01

    Small temperature anisotropies in the cosmic microwave background (CMB) can be sourced by density perturbations via the late-time integrated Sachs-Wolfe (ISW) effect. Large voids and superclusters are excellent environments to make a localized measurement of this tiny imprint. In some cases excess signals have been reported. We probed these claims with an independent data set, using the first year data of the Dark Energy Survey (DES) in a different footprint, and using a different superstructure finding strategy. We identified 52 large voids and 102 superclusters at redshifts 0.2 < z < 0.65. We used the Jubilee simulation to a priori evaluate the optimal ISW measurement configuration for our compensated top-hat filtering technique, and then performed a stacking measurement of the CMB temperature field based on the DES data. For optimal configurations, we detected a cumulative cold imprint of voids with ΔTf ≈ -5.0 ± 3.7 μK and a hot imprint of superclusters ΔTf ≈ 5.1 ± 3.2 μK; this is ∼1.2σ higher than the expected |ΔTf| ≈ 0.6 μK imprint of such superstructures in Λ cold dark matter (ΛCDM). If we instead use an a posteriori selected filter size (R/Rv = 0.6), we can find a temperature decrement as large as ΔTf ≈ -9.8 ± 4.7 μK for voids, which is ∼2σ above ΛCDM expectations and is comparable to previous measurements made using Sloan Digital Sky Survey superstructure data.

  2. Imprint of DES superstructures on the cosmic microwave background

    Energy Technology Data Exchange (ETDEWEB)

    Kovács, A.; Sánchez, C.; García-Bellido, J.; Nadathur, S.; Crittenden, R.; Gruen, D.; Huterer, D.; Bacon, D.; Clampitt, J.; DeRose, J.; Dodelson, S.; Gaztañaga, E.; Jain, B.; Kirk, D.; Lahav, O.; Miquel, R.; Naidoo, K.; Peacock, J. A.; Soergel, B.; Whiteway, L.; Abdalla, F. B.; Allam, S.; Annis, J.; Benoit-Lévy, A.; Bertin, E.; Brooks, D.; Buckley-Geer, E.; Rosell, A. Carnero; Carrasco Kind, M.; Carretero, J.; Cunha, C. E.; D' Andrea, C. B.; da Costa, L. N.; DePoy, D. L.; Desai, S.; Eifler, T. F.; Finley, D. A.; Flaugher, B.; Fosalba, P.; Frieman, J.; Giannantonio, T.; Goldstein, D. A.; Gruendl, R. A.; Gutierrez, G.; James, D. J.; Kuehn, K.; Kuropatkin, N.; Marshall, J. L.; Melchior, P.; Menanteau, F.; Nord, B.; Ogando, R.; Plazas, A. A.; Romer, A. K.; Sanchez, E.; Scarpine, V.; Sevilla-Noarbe, I.; Sobreira, F.; Suchyta, E.; Swanson, M.; Tarle, G.; Thomas, D.; Walker, A. R.

    2016-11-17

    Small temperature anisotropies in the Cosmic Microwave Background can be sourced by density perturbations via the late-time integrated Sachs-Wolfe effect. Large voids and superclusters are excellent environments to make a localized measurement of this tiny imprint. In some cases excess signals have been reported. We probed these claims with an independent data set, using the first year data of the Dark Energy Survey in a different footprint, and using a different super-structure finding strategy. We identified 52 large voids and 102 superclusters at redshifts $0.2 < z < 0.65$. We used the Jubilee simulation to a priori evaluate the optimal ISW measurement configuration for our compensated top-hat filtering technique, and then performed a stacking measurement of the CMB temperature field based on the DES data. For optimal configurations, we detected a cumulative cold imprint of voids with $\\Delta T_{f} \\approx -5.0\\pm3.7~\\mu K$ and a hot imprint of superclusters $\\Delta T_{f} \\approx 5.1\\pm3.2~\\mu K$ ; this is $\\sim1.2\\sigma$ higher than the expected $|\\Delta T_{f}| \\approx 0.6~\\mu K$ imprint of such super-structures in $\\Lambda$CDM. If we instead use an a posteriori selected filter size ($R/R_{v}=0.6$), we can find a temperature decrement as large as $\\Delta T_{f} \\approx -9.8\\pm4.7~\\mu K$ for voids, which is $\\sim2\\sigma$ above $\\Lambda$CDM expectations and is comparable to previous measurements made using SDSS super-structure data.

  3. Hierarchical super-structure identified by polarized light microscopy, electron microscopy and nanoindentation: Implications for the limits of biological control over the growth mode of abalone sea shells

    Directory of Open Access Journals (Sweden)

    Schneider Andreas S

    2012-09-01

    Full Text Available Abstract Background Mollusc shells are commonly investigated using high-resolution imaging techniques based on cryo-fixation. Less detailed information is available regarding the light-optical properties. Sea shells of Haliotis pulcherina were embedded for polishing in defined orientations in order to investigate the interface between prismatic calcite and nacreous aragonite by standard materialographic methods. A polished thin section of the interface was prepared with a defined thickness of 60 μm for quantitative birefringence analysis using polarized light and LC-PolScope microscopy. Scanning electron microscopy images were obtained for comparison. In order to study structural-mechanical relationships, nanoindentation experiments were performed. Results Incident light microscopy revealed a super-structure in semi-transparent regions of the polished cross-section under a defined angle. This super-structure is not visible in transmitted birefringence analysis due to the blurred polarization of small nacre platelets and numerous organic interfaces. The relative orientation and homogeneity of calcite prisms was directly identified, some of them with their optical axes exactly normal to the imaging plane. Co-oriented "prism colonies" were identified by polarized light analyses. The nacreous super-structure was also visualized by secondary electron imaging under defined angles. The domains of the super-structure were interpreted to consist of crystallographically aligned platelet stacks. Nanoindentation experiments showed that mechanical properties changed with the same periodicity as the domain size. Conclusions In this study, we have demonstrated that insights into the growth mechanisms of nacre can be obtained by conventional light-optical methods. For example, we observed super-structures formed by co-oriented nacre platelets as previously identified using X-ray Photo-electron Emission Microscopy (X-PEEM [Gilbert et al., Journal of the

  4. C60 superstructure and carbide formation on the Al-terminated Al9Co2(001 ) surface

    Science.gov (United States)

    Ledieu, J.; Gaudry, É.; de Weerd, M.-C.; Gille, P.; Diehl, R. D.; Fournée, V.

    2015-04-01

    We report the formation of an ordered C60 monolayer on the Al9Co2 (001) surface using scanning tunneling microscopy (STM), low-energy electron diffraction (LEED), x-ray and ultraviolet photoelectron spectroscopy (XPS/UPS), and ab initio calculations. Dosing fullerenes at 300 K results in a disordered overlayer. However, the adsorption of C60 with the sample held between 573-673 K leads to a [4, -2 ∣1 ,3 ] phase. The growth of C60 proceeds with the formation of two domains which are mirror symmetric with respect to the [100] direction. Within each domain, the superstructure unit cell contains six molecules and this implies an area per fullerene equal to 91 Å2. The molecules exhibit two types of contrast (bright and dim) which are bias dependent. The adsorption energies and preferred molecular configuration at several possible adsorption sites have been determined theoretically. These calculations lead to a possible scheme describing the configuration of each C60 in the observed superstructure. Several defects (vacancies, protrusions,…) and domain boundaries observed in the film are also discussed. If the sample temperature is higher than 693 K when dosing, impinging C60 molecules dissociate at the surface, hence leading to the formation of a carbide film as observed by STM and LEED measurements. The formation of Al4C3 domains and the molecular dissociation are confirmed by XPS/UPS measurements acquired at different stages of the experiment. The cluster substructure present at the Al9Co2 (001) surface dictates the carbide domain orientations.

  5. Magnetic-Field-Assisted Assembly of Anisotropic Superstructures by Iron Oxide Nanoparticles and Their Enhanced Magnetism.

    Science.gov (United States)

    Jiang, Chengpeng; Leung, Chi Wah; Pong, Philip W T

    2016-12-01

    Magnetic nanoparticle superstructures with controlled magnetic alignment and desired structural anisotropy hold promise for applications in data storage and energy storage. Assembly of monodisperse magnetic nanoparticles under a magnetic field could lead to highly ordered superstructures, providing distinctive magnetic properties. In this work, a low-cost fabrication technique was demonstrated to assemble sub-20-nm iron oxide nanoparticles into crystalline superstructures under an in-plane magnetic field. The gradient of the applied magnetic field contributes to the anisotropic formation of micron-sized superstructures. The magnitude of the applied magnetic field promotes the alignment of magnetic moments of the nanoparticles. The strong dipole-dipole interactions between the neighboring nanoparticles lead to a close-packed pattern as an energetically favorable configuration. Rod-shaped and spindle-shaped superstructures with uniform size and controlled spacing were obtained using spherical and polyhedral nanoparticles, respectively. The arrangement and alignment of the superstructures can be tuned by changing the experimental conditions. The two types of superstructures both show enhancement of coercivity and saturation magnetization along the applied field direction, which is presumably associated with the magnetic anisotropy and magnetic dipole interactions of the constituent nanoparticles and the increased shape anisotropy of the superstructures. Our results show that the magnetic-field-assisted assembly technique could be used for fabricating nanomaterial-based structures with controlled geometric dimensions and enhanced magnetic properties for magnetic and energy storage applications.

  6. Voids and superstructures: correlations and induced large-scale velocity flows

    Science.gov (United States)

    Lares, Marcelo; Luparello, Heliana E.; Maldonado, Victoria; Ruiz, Andrés N.; Paz, Dante J.; Ceccarelli, Laura; Garcia Lambas, Diego

    2017-09-01

    The expanding complex pattern of filaments, walls and voids build the evolving cosmic web with material flowing from underdense on to high density regions. Here, we explore the dynamical behaviour of voids and galaxies in void shells relative to neighbouring overdense superstructures, using the Millenium simulation and the main galaxy catalogue in Sloan Digital Sky Survey data. We define a correlation measure to estimate the tendency of voids to be located at a given distance from a superstructure. We find voids-in-clouds (S-types) preferentially located closer to superstructures than voids-in-voids (R-types) although we obtain that voids within ∼40 h-1 Mpc of superstructures are infalling in a similar fashion independently of void type. Galaxies residing in void shells show infall towards the closest superstructure, along with the void global motion, with a differential velocity component depending on their relative position in the shell with respect to the direction to the superstructure. This effect is produced by void expansion and therefore is stronger for R-types. We also find that galaxies in void shells facing the superstructure flow towards the overdensities faster than galaxies elsewhere at the same relative distance to the superstructure. The results obtained for the simulation are also reproduced for the Sky Survey Data Release data with a linearized velocity field implementation.

  7. 40 CFR 745.228 - Accreditation of training programs: public and commercial buildings, bridges and superstructures...

    Science.gov (United States)

    2010-07-01

    ... 40 Protection of Environment 30 2010-07-01 2010-07-01 false Accreditation of training programs: public and commercial buildings, bridges and superstructures. 745.228 Section 745.228 Protection of... of training programs: public and commercial buildings, bridges and superstructures....

  8. Cation ordering and superstructures in natural layered double hydroxides.

    Science.gov (United States)

    Krivovichev, Sergey V; Yakovenchuk, Victor N; Zolotarev, Andrey A; Ivanyuk, Gregory N; Pakhomovsky, Yakov A

    2010-01-01

    Layered double hydroxides (LDHs) constitute an important group of materials with many applications ranging from catalysis and absorption to carriers for drug delivery, DNA intercalation and carbon dioxide sequestration. The structures of LDHs are based upon double brucite-like hydroxide layers [M(2+)(n)M(3+)(m)(OH)(2(m+n)](m+), where M(2+) = Mg(2+), Fe(2+), Mn(2+), Zn(2+), etc.; M(3+) = Al(3+), Fe(3+), Cr(3+), Mn(3+), etc. Structural features of LDHs such as cation ordering, charge distribution and polytypism have an immediate influence upon their properties. However, all the structural studies on synthetic LDHs deal with powder samples that prevent elucidation of such fine details of structure architecture as formation of superstructures due to cation ordering. In contrast to synthetic materials, natural LDHs are known to form single crystals accessible to single-crystal X-ray diffraction analysis, which provides a unique possibility to investigate 3D cation ordering in LDHs that results in formation of complex superstructures, where 2D cation order is combined with a specific order of layer stacking (polytypism). Therefore LDH minerals provide an indispensable source of structural information for modeling of structures and processes happening in LDHs at the molecular and nanoscale levels.

  9. Collapse Mechanism Analysis in the Design of Superstructure Vehicle

    Science.gov (United States)

    Mohd Nor, M. K.

    2016-11-01

    The EU directive 2001/85/EC is an official European text which describes the specifications for “single deck class II and III vehicles” required to be approved by the regulation UN/ECE no.66 (R66). To prevent the catastrophic consequences by occupant during an accident, the Malaysian government has reinforced the same regulation upon superstructure construction. This paper discusses collapse mechanism analysis of a superstructure vehicle using a Crash D nonlinear analysis computer program based on this regulation. The analysis starts by hand calculation to define the required energy absorption by the chosen structure. Simple calculations were then performed to define the weakest collapse mechanism after undesirable collapse modes are eliminated. There are few factors highlighted in this work to pass the regulation. Using the selected cross section, Crash D simulation showed a good result. Generally, the deformation is linearly correlates to the energy absorption for the structure with low stiffness. Failure of critical members such as vertical lower side wall must be avoided to sustain safety of the passenger compartment and prevent from severe and fatal injuries to the trapped occupant.

  10. Nonlinear analysis of collapse mechanism in superstructure vehicle

    Science.gov (United States)

    Nor, M. K. Mohd; Ho, C. S.; Ma'at, N.

    2017-04-01

    The EU directive 2001/85/EC is an official European text which describes the specifications for "single deck class II and III vehicles" required to be approved by the regulation UN/ECE no.66 (R66). To prevent the catastrophic consequences by occupant during an accident, the Malaysian government has reinforced the same regulation upon superstructure construction. This paper discusses collapse mechanism analysis of a superstructure vehicle using a Crash D nonlinear analysis computer program based on this regulation. The analysis starts by hand calculation to define the required energy absorption by the chosen structure. Simple calculations were then performed to define the weakest collapse mechanism after undesirable collapse modes are eliminated. There are few factors highlighted in this work to pass the regulation. Using the selected cross section, Crash D simulation showed a good result. Generally, the deformation is linearly correlates to the energy absorption for the structure with low stiffness. Failure of critical members such as vertical lower side wall must be avoided to sustain safety of the passenger compartment and prevent from severe and fatal injuries to the trapped occupant.

  11. In-phase and anti-phase synchronization in noisy Hodgkin-Huxley neurons

    CERN Document Server

    Schmid, Gerhard; Hanggi, Peter

    2013-01-01

    We numerically investigate the influence of intrinsic channel noise on the dynamical response of delay-coupling in neuronal systems. The stochastic dynamics of the spiking is modeled within a stochastic modification of the standard Hodgkin-Huxley model wherein the delay-coupling accounts for the finite propagation time of an action potential along the neuronal axon. We quantify this delay-coupling of the Pyragas-type in terms of the difference between corresponding presynaptic and postsynaptic membrane potentials. In case of a single neuron we analyze the spiking activity in presence of an autaptic feedback loop. With vanishing channel noise the interspike interval increases with increasing delay time. For an elementary neuronal network consisting of two coupled neurons we detect characteristic stochastic synchronization patterns which exhibit multiple phase-flip bifurcations: The phase-flip bifurcations occur in form of alternate transitions from an in-phase spiking activity towards an anti-phase spiking act...

  12. In-phase and anti-phase synchronization in noisy Hodgkin-Huxley neurons.

    Science.gov (United States)

    Ao, Xue; Hänggi, Peter; Schmid, Gerhard

    2013-09-01

    We numerically investigate the influence of intrinsic channel noise on the dynamical response of delay-coupling in neuronal systems. The stochastic dynamics of the spiking is modeled within a stochastic modification of the standard Hodgkin-Huxley model wherein the delay-coupling accounts for the finite propagation time of an action potential along the neuronal axon. We quantify this delay-coupling of the Pyragas-type in terms of the difference between corresponding presynaptic and postsynaptic membrane potentials. For an elementary neuronal network consisting of two coupled neurons we detect characteristic stochastic synchronization patterns which exhibit multiple phase-flip bifurcations: The phase-flip bifurcations occur in form of alternate transitions from an in-phase spiking activity towards an anti-phase spiking activity. Interestingly, these phase-flips remain robust for strong channel noise and in turn cause a striking stabilization of the spiking frequency.

  13. Interhemispheric anti-phasing of rainfall during the last glacial period

    Science.gov (United States)

    Wang, Xianfeng; Auler, Augusto S.; Edwards, R. Lawrence; Cheng, Hai; Ito, Emi; Solheid, Maniko

    2006-12-01

    We have obtained a high-resolution oxygen isotopic record of cave calcite from Caverna Botuverá (27°13'S, 49°09'W), southern Brazil, which covers most of the last 36 thousand years (ka), with an average resolution of a few to several decades. The chronology was determined with 46 U/Th ages from two stalagmites. Tests for equilibrium conditions show that oxygen isotopic variations are primarily caused by climate change. We interpret our record in terms of meteoric precipitation changes, hence the variability of South American Monsoon (SAM) intensity. The oxygen isotopic profile broadly follows local insolation changes and shows clear millennial-scale variations during the last glacial period with amplitudes as large as 3‰ but with smaller centennial-scale shifts (<1‰) during the Holocene. The overall record is strikingly similar to, but strongly anti-correlated with, a number of records from the Northern Hemisphere. We compared our record to other precisely dated contemporaneous records from Hulu Cave eastern China. Minima in δ18O (wet periods, intense SAM) at our site are synchronous with maxima in δ18O (dry periods, weak East Asian Monsoon, EAM) in eastern China (within precise dating errors) and vice versa. This anti-phased precipitation relationship between two low-latitude locations may be interhemispheric in extent, based on comparison with records from other sites. Precipitation anti-phasing may be related to north-south shifts in the mean position of the intertropical convergence zone (ITCZ) and asymmetry in Hadley circulation in two hemispheres, associated not with seasonal changes as observed today, but with millennial-scale climate shifts. The millennial-scale atmospheric see-saw patterns that we observe could have important controls and feedbacks on climate within hemispheres because of water vapor's greenhouse properties.

  14. Final restoration of implants with a hybrid ceramic superstructure.

    Science.gov (United States)

    Kurbad, Andreas

    The use of materials with elastic properties for the fabrication of dental implant superstructures seems to be a promising way to reduce the functional occlusal forces on implants. Vita Enamic (Vita Zahnfabrik, Bad Säckingen), a hybrid ceramic material for CAD/CAM technology, is available in a special form that can be relatively easily combined with titanium (Ti) base connectors for the fabrication of abutment crowns and mesostructures. Thus, an easily manageable method is available for reducing peak loads on dental implant fixtures. Representative cases are presented to demonstrate the clinical workflows for a single- element solution (Ti base) and two-element solution (Ti base with mesostructure) for implant-supported crowns.

  15. Abnormal Congenital Location of Stapes’ Superstructure: Clinical and Embryological Implications

    Directory of Open Access Journals (Sweden)

    Vânia Henriques

    2016-01-01

    Full Text Available Congenital middle ear malformations are rare. Most part of them are usually associated with other malformations, such as aural atresia, microtia, and dysmorphic craniofacial features. A clinical case of a 24-year-old male with a right-sided conductive hearing loss since his childhood, without craniofacial malformation, is presented. He was proposed for exploratory tympanotomy under the suspicious diagnosis of otosclerosis. The surgery revealed an abnormal location of stapes’ superstructure, which was attached to the promontory and had an isolated and mobile osseous footplate in the oval window. A stapes prosthesis was inserted and resulted in closure of the air-bone gap by 25 dB. A review of the literature was also performed using MEDLINE. Two theories diverge on the embryologic origin of the stapes. Our findings seem to be in favour of the theory that defines two different embryologic origins to the stapes.

  16. Abnormal Congenital Location of Stapes' Superstructure: Clinical and Embryological Implications

    Science.gov (United States)

    Teles, Rafaela; Sousa, Ana; Estevão, Roberto; Rodrigues, Jorge; Gomes, Alexandra; Silva, Francisco; Fernandes, Ângelo; Fernandes, Fausto

    2016-01-01

    Congenital middle ear malformations are rare. Most part of them are usually associated with other malformations, such as aural atresia, microtia, and dysmorphic craniofacial features. A clinical case of a 24-year-old male with a right-sided conductive hearing loss since his childhood, without craniofacial malformation, is presented. He was proposed for exploratory tympanotomy under the suspicious diagnosis of otosclerosis. The surgery revealed an abnormal location of stapes' superstructure, which was attached to the promontory and had an isolated and mobile osseous footplate in the oval window. A stapes prosthesis was inserted and resulted in closure of the air-bone gap by 25 dB. A review of the literature was also performed using MEDLINE. Two theories diverge on the embryologic origin of the stapes. Our findings seem to be in favour of the theory that defines two different embryologic origins to the stapes. PMID:27648330

  17. Garden-like perovskite superstructures with enhanced photocatalytic activity

    Science.gov (United States)

    Ye, Meidan; Wang, Mengye; Zheng, Dajiang; Zhang, Nan; Lin, Changjian; Lin, Zhiqun

    2014-03-01

    By subjecting amorphous flower-like TiO2 to a facile hydrothermal synthesis in the presence of Sr2+, garden-like perovskite SrTiO3 superstructures were achieved. The amorphous TiO2 was preformed using ZnO flowers as templates. Different three-dimensional SrTiO3 architectures were coexisted in the garden, including SrTiO3 flowers composed of several hollow sword-shaped petals, many sheet-shaped petals or numerous flake-shaped petals, and SrTiO3 grass consisting of a number of long blades. These SrTiO3 superstructures were simultaneously grown on fluorine-doped tin oxide (FTO) substrates. On the basis of a comprehensive study on the effects of growth time, temperature, initial concentrations of precursor, and pH, the formation of these various hierarchical architectures was attributed primarily to the dissolution of amorphous TiO2 and precipitation of perovskite crystals, followed by the Ostwald ripening process of perovskite nanocrystals and self-organization of perovskite building blocks. Interestingly, this approach can be readily extended to create other perovskite structures, including dendritic BaTiO3 and nest-like CaTiO3, as well as PbTiO3 transformed from plate-like pyrochlore Pb2Ti2O6 after post-thermal treatment. Garden-like SrTiO3 superstructures showed a superior photocatalytic performance when compared to other as-prepared semiconductors and perovskite materials (i.e., ZnO, TiO2, BaTiO3, CaTiO3 and PbTiO3), probably due to their intrinsic photocatalytic activity and special garden-like features with a coexistence of various structures that significantly facilitated the adsorption and diffusion of methyl blue (MB) molecules and oxygen species in the photochemical reaction of MB degradation.By subjecting amorphous flower-like TiO2 to a facile hydrothermal synthesis in the presence of Sr2+, garden-like perovskite SrTiO3 superstructures were achieved. The amorphous TiO2 was preformed using ZnO flowers as templates. Different three-dimensional SrTiO3

  18. Study of superstructure Ⅱ in multiferroic BiMnO3

    Institute of Scientific and Technical Information of China (English)

    Ge Bing-Hui; Li Fang-Hua; Li Xue-Ming; Wang Yu-Mei; Chi Zhen-Hua; Jin Chang-Qing

    2008-01-01

    The crystal structure of the minor phase,named superstructure Ⅱ,existing in multiferroic compound BiMnO3 has been studied by electron diffraction and high-resolution transmission electron microscopy.Domains of major and minor phases coexisting in BiMnO3 were observed in high-resolution electron microscope images.The unit cell of minor phase Was determined to be triclinic with the size 4×4×4 times as large as the distorted perovskitc subcell.The[111] and [101]projected structure maps of the minor phase have been derived from the corresponding images by means of the image processing.A possible rough three-dimensional(3D)structure model was proposed based on the 3D structural information extracted from the two projected structure maps.Since there is no inversion centre in the proposed model,the minor phase may contribute to the ferroelectric property of BiMnO3.

  19. Recrystallization-induced self-assembly for the growth of Cu₂O superstructures.

    Science.gov (United States)

    Shang, Yang; Shao, Yi-Ming; Zhang, Dong-Feng; Guo, Lin

    2014-10-20

    The assembly of inorganic nanoparticles (NPs) into 3D superstructures with defined morphologies is of particular interest. A novel strategy that is based on recrystallization-induced self-assembly (RISA) for the construction of 3D Cu2O superstructures and employs Cu2O mesoporous spheres with diameters of approximately 300 nm as the building blocks has now been developed. Balancing the hydrolysis and recrystallization rates of the CuCl precursors through precisely adjusting the experimental parameters was key to success. Furthermore, the geometry of the superstructures can be tuned to obtain either cubes or tetrahedra and was shown to be dependent on the growth behavior of bulk CuCl. The overall strategy extends the applicability of recrystallization-based processes for the guided construction of assemblies and offers unique insights for assembling larger particles into complicated 3D superstructures.

  20. Design and application of inorganic nanoparticle superstructures: current status and future challenges.

    Science.gov (United States)

    Gao, Yan; Tang, Zhiyong

    2011-08-08

    Self-assembly of inorganic nanoparticles (NPs) into superstructures, which is used as a general way to integrate functional inorganic NPs into macroscale devices, has attracted much research interest. This review will summarize the recent progress and discuss future challenges of the inorganic NP superstructures. Examples include both DNA-based and polymer-based NP assemblies with controlled positioning and geometries, and quasicrystalline ordered structures from the self-assembly of binary or ternary NPs. Different from their individual NP counterparts, these self-assembled superstructures possess unique properties, such as optical chirality and dynamic structural change under an external stimulus. Due to their diversified structures and functionalities, inorganic NP superstructures have shown a wide range of promise for applications in electronic and photonic devices, such as field-effect transistors, magnetoresistive components, optical information recording, and solar cells.

  1. Joint Simultaneous Reconstruction of Regularized Building Superstructures from Low-Density LIDAR Data Using Icp

    Science.gov (United States)

    Wichmann, Andreas; Kada, Martin

    2016-06-01

    There are many applications for 3D city models, e.g., in visualizations, analysis, and simulations; each one requiring a certain level of detail to be effective. The overall trend goes towards including various kinds of anthropogenic and natural objects therein with ever increasing geometric and semantic details. A few years back, the featured 3D building models had only coarse roof geometry. But nowadays, they are expected to include detailed roof superstructures like dormers and chimneys. Several methods have been proposed for the automatic reconstruction of 3D building models from airborne based point clouds. However, they are usually unable to reliably recognize and reconstruct small roof superstructures as these objects are often represented by only few point measurements, especially in low-density point clouds. In this paper, we propose a recognition and reconstruction approach that overcomes this problem by identifying and simultaneously reconstructing regularized superstructures of similar shape. For this purpose, candidate areas for superstructures are detected by taking into account virtual sub-surface points that are assumed to lie on the main roof faces below the measured points. The areas with similar superstructures are detected, extracted, grouped together, and registered to one another with the Iterative Closest Point (ICP) algorithm. As an outcome, the joint point density of each detected group is increased, which helps to recognize the shape of the superstructure more reliably and in more detail. Finally, all instances of each group of superstructures are modeled at once and transformed back to their original position. Because superstructures are reconstructed in groups, symmetries, alignments, and regularities can be enforced in a straight-forward way. The validity of the approach is presented on a number of example buildings from the Vaihingen test data set.

  2. Anatomopathology of the Superstructure of the Stapes in Patients with Otosclerosis

    Directory of Open Access Journals (Sweden)

    Carvalho, Bettina

    2014-07-01

    Full Text Available Introduction Otosclerosis is a disease that causes bone resorption and deposition in the auditory structures, leading to deafness. Many studies have evaluated the histopathology of the stapes footplate in this disease (osteoblasts, osteoclasts, vascular proliferation, fibroblasts, and histiocytes, but we found no studies in the literature involving the histology of the superstructure of the stapes. Objectives To perform an analysis under optical microscopy of histopathologic findings of the superstructure of the stapes from patients with otosclerosis. Methods A contemporary cross-sectional cohort study of pathology analysis of superstructures of the stapes of patients with otosclerosis. Results Fifteen superstructures of stapes in patients with otosclerosis operated in our service and four stapes of cadavers used for dissection (controls were evaluated. No areas of bone resorption or deposition or presence of osteoclasts and osteoblasts in the superstructure of the stapes were found. However, we found in the more distal portions of the crura areas with prominent cementitious lines and woven bone, which was different than the mature trabecular bone found in the head of the stapes or in the controls. Conclusion There were histologic changes in the superstructure of the stapes in patients with otosclerosis operated in our service.

  3. Antisolvent crystallization approach to construction of CuI superstructures with defined geometries.

    Science.gov (United States)

    Kozhummal, Rajeevan; Yang, Yang; Güder, Firat; Küçükbayrak, Umut M; Zacharias, Margit

    2013-03-26

    A facile high-yield production of cuprous iodide (CuI) superstructures is reported by antisolvent crystallization using acetonitrile/water as a solvent/antisolvent couple under ambient conditions. In the presence of trace water, the metastable water droplets act as templates to induce the precipitation of hollow spherical CuI superstructures consisting of orderly aligned building blocks after drop coating. With water in excess in the mixed solution, an instant precipitation of CuI random aggregates takes place due to rapid crystal growth via ion-by-ion attachment induced by a strong antisolvent effect. However, this uncontrolled process can be modified by adding polymer polyvinyl pyrrolidone (PVP) in water to restrict the size of initially formed CuI crystal nuclei through the effective coordination effect of PVP. As a result, CuI superstructures with a cuboid geometry are constructed by gradual self-assembly of the small CuI crystals via oriented attachment. The precipitated CuI superstructures have been used as competent adsorbents to remove organic dyes from the water due to their mesocrystal feature. Besides, the CuI superstructures have been applied either as a self-sacrificial template or only as a structuring template for the flexible design of other porous materials such as CuO and TiO2. This system provides an ideal platform to simultaneously investigate the superstructure formation enforced by antisolvent crystallization with and without organic additives.

  4. Light-harvesting superstructures of green plant chloroplasts lacking photosystems.

    Science.gov (United States)

    Belgio, Erica; Ungerer, Petra; Ruban, Alexander V

    2015-10-01

    The light-harvesting antenna of higher plant photosystem II (LHCII) is the major photosynthetic membrane component encoded by an entire family of homologous nuclear genes. On the contrary, the great majority of proteins of photosystems and electron transport components are encoded by the chloroplast genome. In this work, we succeeded in gradually inhibiting the expression of the chloroplast genes that led to the disappearance of the photosystem complexes, mimicking almost total photoinhibition. The treated plants, despite displaying only some early signs of senescence, sustained their metabolism and growth for several weeks. The only major remaining membrane component was LHCII antenna that formed superstructures - stacks of dozens of thylakoids or supergrana. Freeze-fracture electron microscopy revealed specific organization, directly displaying frequently bifurcated membranes with reduced or totally absent photosystem II (PSII) reaction centre complexes. Our findings show that it is possible to accumulate large amounts of light-harvesting membranes, organized into three-dimensional structures, in the absence of reaction centre complexes. This points to the reciprocal role of LHCII and PSII in self-assembly of the three-dimensional matrix of the photosynthetic membrane, dictating its size and flexible adaptation to the light environment. © 2015 John Wiley & Sons Ltd.

  5. Bilateral Congenital Absence of the Stapes Superstructure in Two Siblings

    Science.gov (United States)

    Undabeitia, Jose Ignacio; Undabeitia, José; Cianci, Laura; Padilla, Luis; Petreñas, Eduardo; Municio, Antonio

    2014-01-01

    Middle ear ossicle malformations are an uncommon event. Among them, the congenital absence of the stapes is a very rare condition that is seldom described in the literature. We report the cases of two women, aged 19 and 22 , who presented with a long history of conductive deafness. An exploratory tympanotomy was performed and the absence of the stapes superstructure and an abnormal position of the facial nerve could be observed. A bone anchored hearing aid (BAHA) was implanted in both patients with good results. It is believed that stapes agenesis is related to an abnormal development of the facial nerve, which by the 5th to 6th week of gestation would interpose between the otic capsule and the stapes blastema, preventing these structures from contacting. A long history of nonprogressive hearing loss from birth or early childhood is the key to reach a diagnosis. Several treatment options have been described. The authors opted for a hearing aid due to the high risk of facial nerve lesion, with good functional results. PMID:25045568

  6. HD 240121 - An ACV variable showing anti-phase variations of the B and V light curves

    Science.gov (United States)

    Gröbel, Rainer; Hümmerich, Stefan; Paunzen, Ernst; Bernhard, Klaus

    2017-01-01

    The variability of HD 240121 = BD+59 2602 was first suspected by Särg and Wramdemark (1970) and later confirmed by Gröbel R. (1992a,b). Because of the observed anti-phase variations of the B and V light curves, the latter author tentatively suggested an ACV type. Apart from its inclusion in the catalog of New Suspected Variables (NSV 25977), no further investigations of the star have been published. HD 240121 was included into our target list of ACV candidates and investigated in order to determine the reason for the observed brightness variations. All available information on HD 240121 were collected via an exhaustive data mining procedure. Data from Gröbel (1992a,b) were re-analysed and photometric observations from the NSVS and Hipparcos archives were procured and investigated. Line-of-sight reddening and stellar parameters were calculated from archival photometric data. HD 240121 is a young, late B-type CP2 star of the silicon subgroup. The observed period, amplitude of light variations and variability pattern (anti-phase variations) are typical of ACV variables. The occurrence of anti-phase variations of the B and V light curves is rarely observed and points to the existence of a null wavelength in the visual spectrum. We therefore strongly encourage further multi-colour photometric observations of this star.

  7. Crystallographic superstructure in R2PdSi3 compounds (R=heavy rare earth)

    Science.gov (United States)

    Tang, Fei; Frontzek, Matthias; Dshemuchadse, Julia; Leisegang, Tilmann; Zschornak, Matthias; Mietrach, Robert; Hoffmann, Jens-Uwe; Löser, Wolfgang; Gemming, Sibylle; Meyer, Dirk C.; Loewenhaupt, Michael

    2011-09-01

    The R2PdSi3 intermetallic compounds have been reported to crystallize in a hexagonal AlB2-derived structure, with the rare earth atoms on the Al sites and Pd and Si atoms randomly distributed on the B sites. However, the intricate magnetic properties observed in the series of compounds have always suggested complications to the assumed structure. To clarify the situation, x-ray and neutron diffraction measurements were performed on the heavy rare earth compounds with R=Gd, Tb, Dy, Ho, Er, Tm, which revealed the existence of a crystallographic superstructure. The superstructure features a doubled unit cell in the hexagonal basal plane and an octuplication along the perpendicular c direction with respect to the primitive cell. No structural transition was observed between 300 and 1.5 K. Extended x-ray absorption fine structure (EXAFS) analysis as well as density functional theory (DFT) calculations were utilized to investigate the local environments of the respective atoms. In this paper the various experimental results will be presented and it will be shown that the superstructure is mainly due to the Pd-Si order on the B sites. A structure model will be proposed to fully describe the superstructure of Pd-Si order in R2PdSi3. The connection between the crystallographic superstructure and the magnetic properties will be discussed in the framework of the presented model.

  8. Light-Directed Dynamic Chirality Inversion in Functional Self-Organized Helical Superstructures.

    Science.gov (United States)

    Bisoyi, Hari Krishna; Li, Quan

    2016-02-24

    Helical superstructures are widely observed in nature, in synthetic polymers, and in supramolecular assemblies. Controlling the chirality (the handedness) of dynamic helical superstructures of molecular and macromolecular systems by external stimuli is a challenging task, but is of great fundamental significance with appealing morphology-dependent applications. Light-driven chirality inversion in self-organized helical superstructures (i.e. cholesteric, chiral nematic liquid crystals) is currently in the limelight because inversion of the handedness alters the chirality of the circularly polarized light that they selectively reflect, which has wide potential for application. Here we discuss the recent developments toward inversion of the handedness of cholesteric liquid crystals enabled by photoisomerizable chiral molecular switches or motors. Different classes of chiral photoresponsive dopants (guests) capable of conferring light-driven reversible chirality inversion of helical superstructures fabricated from different nematic hosts are discussed. Rational molecular designs of chiral molecular switches toward endowing handedness inversion to the induced helical superstructures of cholesteric liquid crystals are highlighted. This Review is concluded by throwing light on the challenges and opportunities in this emerging frontier, and it is expected to provide useful guidelines toward the development of self-organized soft materials with stimuli-directed chirality inversion capability and multifunctional host-guest systems.

  9. Influence of superstructure geometry on the mechanical behavior of zirconia implant abutments: a finite element analysis.

    Science.gov (United States)

    Geringer, Alexander; Diebels, Stefan; Nothdurft, Frank P

    2014-12-01

    To predict the clinical performance of zirconia abutments, it is crucial to examine the mechanical behavior of different dental implant-abutment connection configurations. The international standard protocol for dynamic fatigue tests of dental implants (ISO 14801) allows comparing these configurations using standardized superstructure geometries. However, from a mechanical point of view, the geometry of clinical crowns causes modified boundary conditions. The purpose of this finite element (FE) study was to evaluate the influence of the superstructure geometry on the maximum stress values of zirconia abutments with a conical implant-abutment connection. Geometry models of the experimental setup described in ISO 14801 were generated using CAD software following the reconstruction of computerized tomography scans from all relevant components. These models served as a basis for an FE simulation. To reduce the numerical complexity of the FE model, the interaction between loading stamp and superstructure geometry was taken into account by defining the boundary conditions with regard to the frictional force. The results of the FE simulations performed on standardized superstructure geometry and anatomically shaped crowns showed a strong influence of the superstructure geometry and related surface orientations on the mechanical behavior of the underlying zirconia abutments. In conclusion, ISO testing of zirconia abutments should be accompanied by load-bearing capacity testing under simulated clinical conditions to predict clinical performance.

  10. Linking experiment and theory for three-dimensional networked binary metal nanoparticle–triblock terpolymer superstructures

    KAUST Repository

    Li, Zihui

    2014-02-21

    © 2014 Macmillan Publishers Limited. Controlling superstructure of binary nanoparticle mixtures in three dimensions from self-assembly opens enormous opportunities for the design of materials with unique properties. Here we report on how the intimate coupling of synthesis, in-depth electron tomographic characterization and theory enables exquisite control of superstructure in highly ordered porous three-dimensional continuous networks from single and binary mixtures of metal nanoparticles with a triblock terpolymer. Poly(isoprene-block-styrene-block-(N,N-dimethylamino)ethyl methacrylate) is synthesized and used as structure-directing agent for ligand-stabilized platinum and gold nanoparticles. Quantitative analysis provides insights into short-and long-range nanoparticle-nanoparticle correlations, and local and global contributions to structural chirality in the networks. Results provide synthesis criteria for next-generation mesoporous network superstructures from binary nanoparticle mixtures for potential applications in areas including catalysis.

  11. Abstraction Super-structuring Normal Forms: Towards a Theory of Structural Induction

    CERN Document Server

    Silvescu, Adrian

    2011-01-01

    Induction is the process by which we obtain predictive laws or theories or models of the world. We consider the structural aspect of induction. We answer the question as to whether we can find a finite and minmalistic set of operations on structural elements in terms of which any theory can be expressed. We identify abstraction (grouping similar entities) and super-structuring (combining topologically e.g., spatio-temporally close entities) as the essential structural operations in the induction process. We show that only two more structural operations, namely, reverse abstraction and reverse super-structuring (the duals of abstraction and super-structuring respectively) suffice in order to exploit the full power of Turing-equivalent generative grammars in induction. We explore the implications of this theorem with respect to the nature of hidden variables, radical positivism and the 2-century old claim of David Hume about the principles of connexion among ideas.

  12. Large Number, Dark Matter, Dark Energy, and Superstructures in the Universe

    Institute of Scientific and Technical Information of China (English)

    HUANG Wu-Liang; HUANG Xiao-Dong

    2009-01-01

    Since there may exist dark matter particles v and 5 with mass ~ 10-1 eV in the universe, the superstructures with a scale of 1019 solar masses (large number A ~ 1019) appeared during the era near and before the hydrogen recombination. Since there are superstructures in the universe, there may be no necessity for the existence of dark energy. For checking the superstructure in the universe by CMB anisotropy, we need to measure CMB angular power spectrum -especially around ten degrees across the sky - in more details. While neutrino v is related to electroweak unification, the fourth stable elementary particle δ may be related to strong-gravity unification, which suggests p + p →, n + δ and that some new baryons appeared in the TeV region.

  13. A 3D AgCl hierarchical superstructure synthesized by a wet chemical oxidation method.

    Science.gov (United States)

    Lou, Zaizhu; Huang, Baibiao; Ma, Xiangchao; Zhang, Xiaoyang; Qin, Xiaoyan; Wang, Zeyan; Dai, Ying; Liu, Yuanyuan

    2012-12-07

    A novel 3D AgCl hierarchical superstructure, with fast growth along the 〈111〉 directions of cubic seeds, is synthesized by using a wet chemical oxidation method. The morphological structures and the growth process are investigated by scanning electron microscopy and X-ray diffraction. The crystal structures are analyzed by their crystallographic orientations. The surface energy of AgCl facets {100}, {110}, and {111} with absorbance of Cl(-) ions is studied by density functional theory calculations. Based on the experimental and computational results, a plausible mechanism is proposed to illustrate the formation of the 3D AgCl hierarchical superstructures. With more active sites, the photocatalytic activity of the 3D AgCl hierarchical superstructures is better than those of concave and cubic ones in oxygen evolution under irradiation by visible light.

  14. Superstructured Carbon Nanotube/Porous Silicon Hybrid Materials for Lithium-Ion Battery Anodes

    Science.gov (United States)

    Lee, Jun-Ki; Kang, Shin-Hyun; Choi, Sung-Min

    2015-03-01

    High energy Li-ion batteries (LIBs) are in great demand for electronics, electric-vehicles, and grid-scale energy storage. To further increase the energy and power densities of LIBs, Si anodes have been intensively explored due to their high capacity, and high abundance compared with traditional carbon anodes. However, the poor cycle-life caused by large volume expansion during charge/discharge process has been an impediment to its applications. Recently, superstructured Si materials were received attentions to solve above mentioned problem in excellent mechanical properties, large surface area, and fast Li and electron transportation aspects, but applying superstructures to anode is in early stage yet. Here, we synthesized superstructured carbon nanotubes (CNTs)/porous Si hybrid materials and its particular electrochemical properties will be presented. Department of Nuclear and Quantum Engineering

  15. Linking experiment and theory for three-dimensional networked binary metal nanoparticle-triblock terpolymer superstructures

    Science.gov (United States)

    Li, Zihui; Hur, Kahyun; Sai, Hiroaki; Higuchi, Takeshi; Takahara, Atsushi; Jinnai, Hiroshi; Gruner, Sol M.; Wiesner, Ulrich

    2014-02-01

    Controlling superstructure of binary nanoparticle mixtures in three dimensions from self-assembly opens enormous opportunities for the design of materials with unique properties. Here we report on how the intimate coupling of synthesis, in-depth electron tomographic characterization and theory enables exquisite control of superstructure in highly ordered porous three-dimensional continuous networks from single and binary mixtures of metal nanoparticles with a triblock terpolymer. Poly(isoprene-block-styrene-block-(N,N-dimethylamino)ethyl methacrylate) is synthesized and used as structure-directing agent for ligand-stabilized platinum and gold nanoparticles. Quantitative analysis provides insights into short- and long-range nanoparticle-nanoparticle correlations, and local and global contributions to structural chirality in the networks. Results provide synthesis criteria for next-generation mesoporous network superstructures from binary nanoparticle mixtures for potential applications in areas including catalysis.

  16. Monte-Carlo simulation of {Pb}/{Cu (100) } surface superstructures

    Science.gov (United States)

    Tan, S.; Ghazali, A.; Lévy, J.-C. S.

    1997-04-01

    Three surface superstructures of {Pb}/{Cu (100) } at low lead coverage are well known experimentally: c(4 × 4),c(2 × 2) and c(5√2×√2)R45°. The present study consists in (i) using generalized Lennard-Jones pair potentials for lead-lead and copper-copper interactions fitted on structural and elastic bulk properties, (ii) deriving an effective potential for lead-copper and (iii) developing a Monte-Carlo extensive relaxation of superstructure models. The MC simulations reveal the stability of these approximate superstructures and yield structural details that are all observed in STM and LEED experiments: the adlayer corrugation, surface alloying, structural modulations as well as PbPb and PbCu spacings. The simulated results on structures and on melting temperatures are in close agreement with experimental data.

  17. Pb/Cu (100) surface superstructures: Monte Carlo and molecular dynamics simulations

    Science.gov (United States)

    Tan, S.; Ghazali, A.; L´vy, J. C. S.

    1997-12-01

    Monte Carlo simulations with simple pair potentials of the Lennard-Jones type enable us to show the stability of the three experimentally known superstructures of Pb/Cu (100) at different lead submonolayer coverages: c(4 × 4)atθ = 3/8,c(2 × 2)atθ = 0.5 and c(5√2 × √2)R45° at θ = 0.6. In addition, numerous details of these superstructures, including interatomic distances, surface alloying, corrugation and weak modulation are obtained numerically in quantitative and qualitative accord with the experimentally observed and measured data. By molecular dynamics the melting of these structures is studied from the temperature dependence of the Pb-atom average energy and diffusion coefficient, with evidence for a first-order transition for every superstructure. The dispersion of surface phonons is also derived.

  18. Restoring oscillatory behavior from amplitude death with anti-phase synchronization patterns in networks of electrochemical oscillations

    Science.gov (United States)

    Nagao, Raphael; Zou, Wei; Kurths, Jürgen; Kiss, István Z.

    2016-09-01

    The dynamical behavior of delay-coupled networks of electrochemical reactions is investigated to explore the formation of amplitude death (AD) and the synchronization states in a parameter region around the amplitude death region. It is shown that difference coupling with odd and even numbered ring and random networks can produce the AD phenomenon. Furthermore, this AD can be restored by changing the coupling type from difference to direct coupling. The restored oscillations tend to create synchronization patterns in which neighboring elements are in nearly anti-phase configuration. The ring networks produce frozen and rotating phase waves, while the random network exhibits a complex synchronization pattern with interwoven frozen and propagating phase waves. The experimental results are interpreted with a coupled Stuart-Landau oscillator model. The experimental and theoretical results reveal that AD behavior is a robust feature of delayed coupled networks of chemical units; if an oscillatory behavior is required again, even a small amount of direct coupling could be sufficient to restore the oscillations. The restored nearly anti-phase oscillatory patterns, which, to a certain extent, reflect the symmetry of the network, represent an effective means to overcome the AD phenomenon.

  19. Dynamic interference of two anti-phase flapping foils in side-by-side arrangement in an incompressible flow

    Science.gov (United States)

    Bao, Y.; Zhou, D.; Tao, J. J.; Peng, Z.; Zhu, H. B.; Sun, Z. L.; Tong, H. L.

    2017-03-01

    A two-dimensional computational hydrodynamic model is developed to investigate the propulsive performance of a flapping foil system in viscous incompressible flows, which consists of two anti-phase flapping foils in side-by-side arrangement. In the simulations, the gap between the two foils is varied from 1.0 to 4.0 times of the diameter of the semi-circular leading edge; the amplitude-based Strouhal number is changed from 0.06 to 0.55. The simulations therefore cover the flow regimes from negligible to strong interference in the wake flow. The generations of drag and thrust are investigated as well. The numerical results reveal that the counter-phase flapping motion significantly changes the hydrodynamic force generation and associated propulsive wake. Furthermore, the wake interference becomes important for the case with a smaller foil-foil gap and induces the inverted Bénard von Kármán vortex streets. The results show that the hydrodynamic performance of two anti-phase flapping foils can be significantly different from an isolated pitching foil. Findings of this study are expected to provide new insight for developing hydrodynamic propulsive systems by improving the performance based on the foil-foil interaction.

  20. A superstructure-based electrochemical assay for signal-amplified detection of DNA methyltransferase activity.

    Science.gov (United States)

    Zhang, Hui; Yang, Yin; Dong, Huilei; Cai, Chenxin

    2016-12-15

    DNA methyltransferase (MTase) activity is highly correlated with the occurrence and development of cancer. This work reports a superstructure-based electrochemical assay for signal-amplified detection of DNA MTase activity using M.SssI as an example. First, low-density coverage of DNA duplexes on the surface of the gold electrode was achieved by immobilized mercaptohexanol, followed by immobilization of DNA duplexes. The duplex can be cleaved by BstUI endonuclease in the absence of DNA superstructures. However, the cleavage is blocked after the DNA is methylated by M.SssI. The DNA superstructures are formed with the addition of helper DNA. By using an electroactive complex, RuHex, which can bind to DNA double strands, the activity of M.SssI can be quantitatively detected by differential pulse voltammetry. Due to the high site-specific cleavage by BstUI and signal amplification by the DNA superstructure, the biosensor can achieve ultrasensitive detection of DNA MTase activity down to 0.025U/mL. The method can be used for evaluation and screening of the inhibitors of MTase, and thus has potential in the discovery of methylation-related anticancer drugs.

  1. Ab initio study of long-period superstructures in close-packed A3B compounds

    DEFF Research Database (Denmark)

    Rosengaard, N. M.; Skriver, Hans Lomholt

    1994-01-01

    We have performed ab initio calculations of the stability of one-dimensional long-period superstructures in Cu3Pd, Cu3Al, and Ag3Mg by means of an interface Green's function technique based on the linear-muffin-tin-orbitals method within the tight-binding and atomic-sphere approximations. The ene...

  2. A generic methodology for processing route synthesis and design based on superstructure optimization

    DEFF Research Database (Denmark)

    Bertran, Maria-Ona; Frauzem, Rebecca; Sanchez-Arcilla, Ana Sofia

    2017-01-01

    In this paper, a systematic framework for novel and sustainable synthesis-design of processing routes is presented along with the associated computer-aided methods and tools. In Stage 1, superstructure optimization is used to determine the optimal processing route(s). In Stage 2, the design issue...

  3. Optical scan analysis to detect minor misfit on implant-supported superstructures

    NARCIS (Netherlands)

    Tahmaseb, A.; Mercelis, P.; de Clerck, R.; Wismeijer, D.

    2011-01-01

    PURPOSE: Despite the development of novel and more precise fabrication methods, absolute passive fit of implant-supported superstructures has yet to be consistently achieved. In the past, several laboratory techniques have been described to analyze fit. The purpose of this study was to assess two me

  4. Assembling Synthesis of Barium Chromate Nano-superstructures Using Eggshell Membrane as Template

    Energy Technology Data Exchange (ETDEWEB)

    Liu, Jinku; Wu, Qingsheng; Yi, Yu [Tongji University, Shanghai (China); Ding, Yaping [Shanghai University, Shanghai (China)

    2004-12-15

    The branch-like, feather-like BaCrO{sub 4} nano-superstructures were synthesized with bioactive eggshell membrane as directing and assembly template. Studies on the two products revealed that they formed through the self-assembly of nanoparticles, and that the optical properties of the products were different from BaCrO{sub 4} bulk materials.

  5. Unknown Aspects of Self-Assembly of PbS Microscale Superstructures

    Science.gov (United States)

    Querejeta-Fernández, Ana; Hernández-Garrido, Juan C.; Yang, Hengxi; Zhou, Yunlong; Varela, Aurea; Parras, Marina; Calvino-Gámez, José J.; González-Calbet, Jose M.; Green, Peter F.; Kotov, Nicholas A.

    2012-01-01

    A lot of interesting and sophisticated examples of nanoparticle (NP) self-assembly (SA) are known. From both fundamental and technological standpoints this field requires advancements in three principle directions: a) understanding the mechanism and driving forces of three-dimensional (3D) SA with both nano- and micro-levels of organization; b) understanding of disassembly/deconstruction processes; and c) finding synthetic methods of assembly into continuous superstructures without insulating barriers. From this perspective, we investigated the formation of well-known star-like PbS superstructures and found a number of previously unknown or overlooked aspects that can advance the knowledge of NP self-assembly in these three directions. The primary one is that the formation of large seemingly monocrystalline PbS superstructures with multiple levels of octahedral symmetry can be explained only by SA of small octahedral NPs. We found five distinct periods in the formation PbS hyperbranched stars: 1) nucleation of early PbS NPs with an average diameter of 31 nm; 2) assembly into 100–500 nm octahedral mesocrystals; 3) assembly into 1000–2500 nm hyperbranched stars; 4) assembly and ionic recrystallization into six-arm rods accompanied by disappearance of fine nanoscale structure; 5) deconstruction into rods and cubooctahedral NPs. The switches in assembly patterns between the periods occur due to variable dominance of pattern–determining forces that include vander Waals and electrostatic (charge-charge, dipole-dipole, and polarization) interactions. The superstructure deconstruction is triggered by chemical changes in the deep eutectic solvent (DES) used as the media. PbS superstructures can be excellent models for fundamental studies of nanoscale organization and SA manufacturing of (opto)electronics and energy harvesting devices which require organization of PbS components at multiple scales. PMID:22515512

  6. Direct Fabrication of Free-Standing MOF Superstructures with Desired Shapes by Micro-Confined Interfacial Synthesis.

    Science.gov (United States)

    Kim, Jin-Oh; Min, Kyoung-Ik; Noh, Hyunwoo; Kim, Dong-Hwi; Park, Soo-Young; Kim, Dong-Pyo

    2016-06-13

    Recently, metal-organic frameworks (MOFs) with multifunctional pore chemistry have been intensively investigated for positioning the desired morphology at specific locations onto substrates for manufacturing devices. Herein, we develop a micro-confined interfacial synthesis (MIS) approach for fabrication of a variety of free-standing MOF superstructures with desired shapes. This approach for engineering MOFs provides three key features: 1) in situ synthesis of various free-standing MOF superstructures with controlled compositions, shape, and thickness using a mold membrane; 2) adding magnetic functionality into MOF superstructures by loading with Fe3 O4 nanoparticles; 3) transferring the synthesized MOF superstructural array on to flat or curved surface of various substrates. The MIS route with versatile potential opens the door for a number of new perspectives in various applications.

  7. Exploring the morphological and electronic properties of silicene superstructures

    Energy Technology Data Exchange (ETDEWEB)

    Grazianetti, Carlo, E-mail: carlo.grazianetti@mdm.imm.cnr.it [Laboratorio MDM, IMM-CNR, via C. Olivetti 2, I-20864 Agrate Brianza, MB (Italy); Dipartimento di Scienza dei Materiali, Università degli Studi di Milano Bicocca, via R. Cozzi 53, I-20126 Milano, MI (Italy); Chiappe, Daniele; Cinquanta, Eugenio; Tallarida, Grazia [Laboratorio MDM, IMM-CNR, via C. Olivetti 2, I-20864 Agrate Brianza, MB (Italy); Fanciulli, Marco [Laboratorio MDM, IMM-CNR, via C. Olivetti 2, I-20864 Agrate Brianza, MB (Italy); Dipartimento di Scienza dei Materiali, Università degli Studi di Milano Bicocca, via R. Cozzi 53, I-20126 Milano, MI (Italy); Molle, Alessandro, E-mail: alessandro.molle@mdm.imm.cnr.it [Laboratorio MDM, IMM-CNR, via C. Olivetti 2, I-20864 Agrate Brianza, MB (Italy)

    2014-02-01

    Silicene, the Si counterpart of graphene, grows on Ag(111) forming domains. Investigation, by means of scanning tunneling microscopy, of morphological properties is carried out by considering post-deposition process. Particular attention is here addressed to the post-deposition annealing temperature, which plays an important role in determining the resulting morphology. On the other hand, electronic properties are probed by scanning tunneling spectroscopy and a position-dependent local density of states results, which can be understood in terms of symmetry breaking in the honeycomb lattice.

  8. Analysis of raft foundation design based on considering influence of superstructure stiffness

    Institute of Scientific and Technical Information of China (English)

    WANG Bin; QIU Jianhui; ZHAO Dong; YANG Xi; DAI Shuai

    2009-01-01

    The finite element method was used for analysis of raft foundation design in high-rise building. Compared with other conventional methods, this method is more adapted to the practical condition since both superstructure stiffness and soil conditions were considered in calculation. The calculation results by example show that the base reaction is more uniform and the maximum reaction decreases obviously. Accordingly, the raft foundation design is more economic without any loss of security for high-rise building.

  9. Vibrational properties of the Pt(111)- p(2 × 2)-K surface superstructure

    Science.gov (United States)

    Rusina, G. G.; Eremeev, S. V.; Borisova, S. D.; Chulkov, E. V.

    2008-08-01

    The vibrational spectra of the Pt(111)- p(2 × 2)-K ordered surface superstructure formed on the platinum surface upon adsorption of 0.25 potassium monolayer are calculated using the interatomic interaction potentials obtained within the tight-binding approximation. The surface relaxation, the dispersion of surface phonons, the local density of surface vibrational states, and the polarization of vibrational modes of adatoms and substrate atoms are discussed. The theoretical results are in good agreement with the recently obtained experimental data.

  10. Superstructure-based Design and Optimization of Batch Biodiesel Production Using Heterogeneous Catalysts

    Science.gov (United States)

    Nuh, M. Z.; Nasir, N. F.

    2017-08-01

    Biodiesel as a fuel comprised of mono alkyl esters of long chain fatty acids derived from renewable lipid feedstock, such as vegetable oil and animal fat. Biodiesel production is complex process which need systematic design and optimization. However, no case study using the process system engineering (PSE) elements which are superstructure optimization of batch process, it involves complex problems and uses mixed-integer nonlinear programming (MINLP). The PSE offers a solution to complex engineering system by enabling the use of viable tools and techniques to better manage and comprehend the complexity of the system. This study is aimed to apply the PSE tools for the simulation of biodiesel process and optimization and to develop mathematical models for component of the plant for case A, B, C by using published kinetic data. Secondly, to determine economic analysis for biodiesel production, focusing on heterogeneous catalyst. Finally, the objective of this study is to develop the superstructure for biodiesel production by using heterogeneous catalyst. The mathematical models are developed by the superstructure and solving the resulting mixed integer non-linear model and estimation economic analysis by using MATLAB software. The results of the optimization process with the objective function of minimizing the annual production cost by batch process from case C is 23.2587 million USD. Overall, the implementation a study of process system engineering (PSE) has optimized the process of modelling, design and cost estimation. By optimizing the process, it results in solving the complex production and processing of biodiesel by batch.

  11. Automatic recognition of ship types from infrared images using superstructure moment invariants

    Science.gov (United States)

    Li, Heng; Wang, Xinyu

    2007-11-01

    Automatic object recognition is an active area of interest for military and commercial applications. In this paper, a system addressing autonomous recognition of ship types in infrared images is proposed. Firstly, an approach of segmentation based on detection of salient features of the target with subsequent shadow removing is proposed, as is the base of the subsequent object recognition. Considering the differences between the shapes of various ships mainly lie in their superstructures, we then use superstructure moment functions invariant to translation, rotation and scale differences in input patterns and develop a robust algorithm of obtaining ship superstructure. Subsequently a back-propagation neural network is used as a classifier in the recognition stage and projection images of simulated three-dimensional ship models are used as the training sets. Our recognition model was implemented and experimentally validated using both simulated three-dimensional ship model images and real images derived from video of an AN/AAS-44V Forward Looking Infrared(FLIR) sensor.

  12. Hierarchical Self-Assembly of Cu7Te5 Nanorods into Superstructures with Enhanced SERS Performance.

    Science.gov (United States)

    Zheng, Jiaojiao; Dai, Baosong; Liu, Jia; Liu, Jialong; Ji, Muwei; Liu, Jiajia; Zhou, Yuanmin; Xu, Meng; Zhang, Jiatao

    2016-12-28

    This paper reports a strategy to get self-assembly of Cu7Te5 nanorods into hierarchical superstructures: the side-by-side self-assembly of nanorods into microscale one-dimensional (1D) nanowires (primary structure), the side-by-side alignments of the 1D nanowires into two-dimensional (2D) nanowire bundles (secondary structure), and the further rolling up of the 2D bundles into three-dimensional (3D) microtubes (tertiary structure). It was found that the oleylamine (OLA)/n-dodecanethiol (DDT) mixture as a binary capping agent was key to produce Cu7Te5 nanorods in the quantum size regime with high monodispersity, and this was a prerequisite for their hierarchical self-assembly based on elaborate control of the solvent evaporation process. The obtained Cu7Te5 microtube superstructures were used as SERS substrate and showed much stronger SERS enhancement than the as-prepared Cu7Te5 nanorods before assembly. This was probably ascribed to the remarkably enhanced local electromagnetic field arising from the plasmon coupling of Cu7Te5 nanorods in the well-assembled superstructures.

  13. Evolution of Moiré Profiles from van der Waals Superstructures of Boron Nitride Nanosheets

    Science.gov (United States)

    Liao, Yunlong; Cao, Wei; Connell, John W.; Chen, Zhongfang; Lin, Yi

    2016-05-01

    Two-dimensional (2D) van der Waals (vdW) superstructures, or vdW solids, are formed by the precise restacking of 2D nanosheet lattices, which can lead to unique physical and electronic properties that are not available in the parent nanosheets. Moiré patterns formed by the crystalline mismatch between adjacent nanosheets are the most direct features for vdW superstructures under microscopic imaging. In this article, transmission electron microscopy (TEM) observation of hexagonal Moiré patterns with unusually large micrometer-sized lateral areas (up to ~1 μm2) and periodicities (up to ~50 nm) from restacking of liquid exfoliated hexagonal boron nitride nanosheets (BNNSs) is reported. This observation was attributed to the long range crystallinity and the contaminant-free surfaces of these chemically inert nanosheets. Parallel-line-like Moiré fringes with similarly large periodicities were also observed. The simulations and experiments unambiguously revealed that the hexagonal patterns and the parallel fringes originated from the same rotationally mismatched vdW stacking of BNNSs and can be inter-converted by simply tilting the TEM specimen following designated directions. This finding may pave the way for further structural decoding of other 2D vdW superstructure systems with more complex Moiré images.

  14. Z-contrast imaging and ab initio study on "d" superstructure in sedimentary dolomite

    CERN Document Server

    Shen, Zhizhang; Szlufarska, Izabela; Brown, Philip E; Xu, Huifang

    2016-01-01

    Nano-precipitates with tripled periodicity along the c-axis are observed in a Ca-rich dolomite sample from Proterozoic carbonate rocks with "molar tooth" structure. This observation is consistent with previous description of d reflections. High-angle annular dark-field STEM imaging (or Z-contrast imaging) that avoids dynamic diffraction as seen in electron diffraction and high-resolution TEM imaging modes, confirms that d reflections correspond to nanoscale precipitates aligned parallel to (001) of the host dolomite. The lamellae precipitates have a cation ordering sequence of Ca-Ca-Mg-Ca-Ca- Mg along the c direction resulting in a chemical composition of Ca0.67Mg0.33CO3. This superstructure is attributed to the extra or d reflections, thus is referred to as the d superstructure in this study. The structure can be simply described as interstratified calcite/dolomite. The crystal structure of the d superstructure calculated from density functional theory (DFT) has a space group of P31c and has a and c unit-cel...

  15. Superstructure formation and variation in Ni-GDC cermet anodes in SOFC.

    Science.gov (United States)

    Li, Zhi-Peng; Mori, Toshiyuki; Auchterlonie, Graeme John; Zou, Jin; Drennan, John

    2011-05-28

    The microstructures and spatial distributions of constituent elements at the anode in solid oxide fuel cells (SOFCs) have been characterized by analytical transmission electron microscopy (TEM). High resolution TEM observations demonstrate two different types of superstructure formation in grain interiors and at grain boundaries. Energy-filtered TEM elemental imaging qualitatively reveals that mixture zones exist at metal-ceramic grain boundaries, which is also quantitatively verified by STEM energy dispersive X-ray spectroscopy. It was apparent that both metallic Ni and the rare-earth elements Ce/Gd in gadolinium-doped ceria can diffuse into each other with equal diffusion lengths (about 100 nm). This will lead to the existence of mutual diffusion zones at grain boundaries, accompanied by a change in the valence state of the diffusing ions, as identified by electron energy-loss spectroscopy (EELS). Such mutual diffusion is believed to be the dominant factor that gives rise to superstructure formation at grain boundaries, while a different superstructure is formed at grain interiors, as a consequence solely of the reduction of Ce(4+) to Ce(3+) during H(2) treatment. This work will enhance the fundamental understanding of microstructural evolution at the anode, correlating with advancements in sample preparation in order to improve the performance of SOFC anodes.

  16. Silver-colloid-nucleated cytochrome c superstructures encapsulated in silica nanoarchitectures.

    Science.gov (United States)

    Wallace, Jean Marie; Dening, Brett M; Eden, Kristin B; Stroud, Rhonda M; Long, Jeffrey W; Rolison, Debra R

    2004-10-12

    We recently discovered that self-organized superstructures of the heme protein cytochrome c (cyt. c) are nucleated in buffer by gold nanoparticles. The protein molecules within the superstructure survive both silica sol-gel encapsulation and drying from supercritical carbon dioxide to form air-filled biocomposite aerogels that exhibit gas-phase binding activity for nitric oxide. In this investigation, we report that viable proteins are present in biocomposite aerogels when the nucleating metal nanoparticle is silver rather than gold. Silver colloids were synthesized via reduction of an aqueous solution of Ag+ using either citrate or borohydride reductants. As determined by transmission electron microscopy and UV-visible absorption spectroscopy, the silver nanoparticles vary in size and shape depending on the synthetic route, which affects the fraction of cyt. c that survives the processing necessary to form a biocomposite aerogel. Silver colloids synthesized via the citrate preparation are polydisperse, with sizes ranging from 1 to 100 nm, and lead to low cyt. c viability in the dried bioaerogels (approximately 15%). Protein superstructures nucleated at approximately 10-nm Ag colloids prepared via the borohydride route, including citrate stabilization of the borohydride-reduced metal, retain significant protein viability within the bioaerogels (approximately 45%).

  17. The emergence of superstructural order in insulin amyloid fibrils upon multiple rounds of self-seeding

    Science.gov (United States)

    Surmacz-Chwedoruk, Weronika; Babenko, Viktoria; Dec, Robert; Szymczak, Piotr; Dzwolak, Wojciech

    2016-08-01

    Typically, elongation of an amyloid fibril entails passing conformational details of the mother seed to daughter generations of fibrils with high fidelity. There are, however, several factors that can potentially prevent such transgenerational structural imprinting from perpetuating, for example heterogeneity of mother seeds or so-called conformational switching. Here, we examine phenotypic persistence of bovine insulin amyloid ([BI]) upon multiple rounds of self-seeding under quiescent conditions. According to infrared spectroscopy, with the following passages of homologous seeding, daughter fibrils gradually depart from the mother seed’s spectral characteristics. We note that this transgenerational structural drift in [BI] amyloid leads toward fibrils with infrared, chiroptical, and morphological traits similar to those of the superstructural variant of fibrils which normally forms upon strong agitation of insulin solutions. However, in contrast to agitation-induced insulin amyloid, the superstructural assemblies of daughter fibrils isolated through self-seeding are sonication-resistant. Our results suggest that formation of single amyloid fibrils is not a dead-end of the amyloidogenic self-assembly. Instead, the process appears to continue toward the self-assembly of higher-order structures although on longer time-scales. From this perspective, the fast agitation-induced aggregation of insulin appears to be a shortcut to amyloid superstructures whose formation under quiescent conditions is slow.

  18. Lacustrine evidence of anti-phase distribution of moisture in Southern South America during the Neoglacial period (Invited)

    Science.gov (United States)

    Piovano, E.; Ariztegui, D.; Sylvestre, F.; Córdoba, F.

    2009-12-01

    An increasing number of lacustrine records is now available for southern South America east of the Andes. As a result a network of well-studied sites is emerging allowing to track hydrological changes throughout time at a regional scale. New limnogeological results spanning the Holocene across the subtropical Pampean plains of Southern South America are compared with lacustrine records covering both Andean and extra Andean sectors of eastern Patagonia. The development of contrasting hydrological patterns can be observed between the Pampas (Laguna Mar Chiquita, 30°S; Laguna Melincué, 34°S; Lagunas Encadenadas del Oeste de Buenos Aires, 37°S) and eastern Patagonia (Lago Frías, 41°S; Lago Cardiel, 49°S; and Laguna Potrok Aike, 52°S) at both sides of the South American Arid Diagonal (AD) during prevailing warm or cold climatic phases, respectively. Paleohydrological reconstructions suggest wet conditions in regions located west and south of the AD, like Patagonia or even the Central Andes, during cold climatic phases such as those occurred during neoglaciations including the Little Ice Age (LIA). These phases are characterized by a dominant Pacific source of moisture. Conversely, dry conditions can be proposed for the same climatic interval across the subtropical low-lands east of the AD. These areas are mostly under the influence of an Atlantic summer rain regime. Conversely, extensive dryness across Patagonia and wet conditions in the Pampas can be inferred during warm climatic phases such as the Medieval Climatic Anomaly or the last part of the 20th century. This new paleohydrological data from Patagonia and the Pampean plains further indicate that the development of this anti-phase hydrological pattern was active only after the middle Holocene. Thus, it appears as contemporaneous to an intensification of the Southern Westerlies in concert with a weakened Monsoonal circulation. The anti-phasing cold/wet vs. cold/dry hydrological conditions at different

  19. HD 240121 - an ACV variable showing anti-phase variations of the B and V light curves

    CERN Document Server

    Gröbel, Rainer; Paunzen, Ernst; Bernhard, Klaus

    2016-01-01

    The variability of HD 240121 = BD+59 2602 was first suspected by S\\"arg & Wramdemark (1970) and later confirmed by Gr\\"obel (1992a,b). Because of the observed anti-phase variations of the B and V light curves, the latter author tentatively suggested an ACV type. Apart from its inclusion in the catalog of New Suspected Variables (NSV 25977), no further investigations of the star have been published. HD 240121 was included into our target list of ACV candidates and investigated in order to determine the reason for the observed brightness variations. All available information on HD 240121 were collected via an exhaustive data mining procedure. Data from Gr\\"obel (1992a,b) were re-analysed and photometric observations from the NSVS and Hipparcos archives were procured and investigated. Line-of-sight reddening and stellar parameters were calculated from archival photometric data. HD 240121 is a young, late B-type CP2 star of the silicon subgroup. The observed period, amplitude of light variations and variabili...

  20. Modulated structures of Cs2HgCl4: the 5a superstructure at 185 K and the 3c superstructure at 176 K.

    Science.gov (United States)

    Bagautdinov; Pilz; Ludecke; van Smaalen S

    1999-12-01

    Crystalline dicaesium mercury tetrachloride (Cs(2)HgCl(4)) is isomorphous with beta-K(2)SO(4) (space group Pnma, Z = 4) in its normal phase at room temperature. On cooling a sequence of incommensurate and commensurate superstructures occurs, below T = 221 K with modulations parallel to a*, and below 184 K with modulations along c*. The commensurately modulated structures at T = 185 K with q = (1/5)a* and at T = 176 K with q = (1/3)c* were determined using X-ray scattering with synchrotron radiation. The structure at T = 185 K has superspace group Pnma(alpha,0,0)0ss with alpha = 0.2. Lattice parameters were determined as a = 5 x 9.7729 (1), b = 7.5276 (4) and c = 13.3727 (7) Å. Structure refinements converged to R = 0.050 (R = 0.042 for 939 main reflections and R = 0.220 for 307 satellites) for the section t = 0.05 of superspace. The fivefold supercell has space group Pn2(1)a. The structure at T = 176 K has superspace group Pnma(0,0,gamma)0s0 with gamma = 1/3. Lattice parameters were determined as a = 9.789 (3), b = 7.541 (3) and c = 3 x 13.418 (4) Å. Structure refinements converged to R = 0.067 (R = 0.048 for 2130 main reflections, and R = 0.135 for 2382 satellite reflections) for the section t = 0. The threefold supercell has space group P112(1)/a. It is shown that the structures of both low-temperature phases can be characterized as different superstructures of the periodic room-temperature structure. The superstructure of the 5a-modulated phase is analysed in terms of displacements of the Cs atoms, and rotations and distortions of HgCl(4) tetrahedral groups. In the 3c-modulated phase the distortions of the tetrahedra are relaxed, but they are replaced by translations of the tetrahedral groups in addition to rotations.

  1. Confinement Effects on Watery Domains in Hydrated Block Copolymer Electrolyte Membranes

    Science.gov (United States)

    Park, Moon Jeong; Kim, Sung Yeon; Yeo, Joomi

    2011-03-01

    The morphology of a series of diblock copolymers comprising randomly sulfonated polystyrene (PSS) and polymethylbutylene (PMB) blocks equilibrated with humid air was determined by in- situ small angle neutron scattering (SANS). In-situ SANS data were collected over a wide angular range permitting the determination of the superstructure of the hydrophilic PSS-rich and hydrophobic PMB-rich domains and the substructure within the hydrophilic PSS-rich domains. When the characteristic length of the superstructure is larger than 10 nm, the hydrophilic PSS domains are heterogeneous with periodically arranged watery domains. The scattering signature of the watery domains is very similar to the well-established ``ionomer peak.'' This peak vanishes when the neutron scattering length density of the water (H2O/D2O mixture) is matched to that of the PSS block. The spacing between watery domains depends only on sulfonation level of the PSS block. When the characteristic length of the superstructure is less than 10 nm, the watery substructure disappears and homogeneous hydrated PSS-rich domains are obtained.

  2. Acquisition of the linearization process in text composition in third to ninth graders: effects of textual superstructure and macrostructural organization.

    Science.gov (United States)

    Favart, Monik; Coirier, Pierre

    2006-07-01

    Two complementary experiments analyzed the acquisition of text content linearization in writing, in French-speaking participants from third to ninth grades. In both experiments, a scrambled text paradigm was used: eleven ideas presented in random order had to be rearranged coherently so as to compose a text. Linearization was analyzed on the basis of the conceptual ordering of ideas and writing fluency. The first experiment focused on the effect of superstructural facilitation (in decreasing order: 1--instructional, 2--narrative, 3--argumentative), while the second experiment studied the effect of prewriting conditions: 1-scrambled presentation, 2--macrostructural facilitation, 3--ideas given in optimal order (control condition). As expected, scores in conceptual ordering and writing fluency improved through the grade levels. Students were most successful with respect to conceptual ordering in the instructional superstructure, followed by the narrative and finally the argumentative superstructures. The prewriting assignment also had the expected effect (control better than macrostructural presentation which, in turn, was better than the random order) but only with the argumentative superstructure. Contrary to conceptual ordering, writing fluency was not affected by the type of superstructure, although we did record an effect of the prewriting condition. The results are discussed in light of Bereiter and Scardamalia's knowledge transforming strategy (1987) taking into account cognitive development and French language curriculum.

  3. A spray-drying strategy for synthesis of nanoscale metal-organic frameworks and their assembly into hollow superstructures

    Science.gov (United States)

    Carné-Sánchez, Arnau; Imaz, Inhar; Cano-Sarabia, Mary; Maspoch, Daniel

    2013-03-01

    Metal-organic frameworks (MOFs) are among the most attractive porous materials known today. Their miniaturization to the nanoscale—into nanoMOFs—is expected to serve myriad applications from drug delivery to membranes, to open up novel avenues to more traditional storage and catalysis applications, and to enable the creation of sophisticated superstructures. Here, we report the use of spray-drying as a versatile methodology to assemble nanoMOFs, yielding spherical hollow superstructures with diameters smaller than 5 µm. This strategy conceptually mimics the emulsions used by chemists to confine the synthesis of materials, but does not require secondary immiscible solvents or surfactants. We demonstrate that the resulting spherical, hollow superstructures can be processed into stable colloids, whose disassembly by sonication affords discrete, homogeneous nanoMOFs. This spray-drying strategy enables the construction of multicomponent MOF superstructures, and the encapsulation of guest species within these superstructures. We anticipate that this will provide new routes to capsules, reactors and composite materials.

  4. Preparation of flowerlike BiOBr/Bi2MoO6 composite superstructures and the adsorption behavior to dyes

    Science.gov (United States)

    He, Qiong; Ni, Yonghong; Ye, Shiyong

    2017-05-01

    Flowerlike BiOBr/Bi2MoO6 composite superstructures were synthesized by a simple solvothermal route with subsequent direct precipitation at room temperature, employing bismuth nitrate, sodium molybdate, and cetyltrimethylammonium bromide (CTAB) as the raw materials. The phase and the morphology of the as-prepared products were characterized by SEM, TEM, SAED, XRD and EDS. BET investigation proved the mesoporous structure of flowerlike BiOBr/Bi2MoO6 composite superstructures. It was found that the composite superstructures exhibited higher adsorption ability to methylene blue (MB) and pyronine B (PB) dyes from their solutions than single component (BiOBr or Bi2MoO6). As a case, the adsorption behavior of MB aqueous solution on BiOBr/Bi2MoO6 composite superstructures was detailedly studied, including the adsorption isotherm, kinetics and thermodynamic parameters. The results indicated that flowerlike BiOBr/Bi2MoO6 composite superstructures have potential applications in the field of wastewater treatment.

  5. A spray-drying strategy for synthesis of nanoscale metal-organic frameworks and their assembly into hollow superstructures.

    Science.gov (United States)

    Carné-Sánchez, Arnau; Imaz, Inhar; Cano-Sarabia, Mary; Maspoch, Daniel

    2013-03-01

    Metal-organic frameworks (MOFs) are among the most attractive porous materials known today. Their miniaturization to the nanoscale--into nanoMOFs--is expected to serve myriad applications from drug delivery to membranes, to open up novel avenues to more traditional storage and catalysis applications, and to enable the creation of sophisticated superstructures. Here, we report the use of spray-drying as a versatile methodology to assemble nanoMOFs, yielding spherical hollow superstructures with diameters smaller than 5 µm. This strategy conceptually mimics the emulsions used by chemists to confine the synthesis of materials, but does not require secondary immiscible solvents or surfactants. We demonstrate that the resulting spherical, hollow superstructures can be processed into stable colloids, whose disassembly by sonication affords discrete, homogeneous nanoMOFs. This spray-drying strategy enables the construction of multicomponent MOF superstructures, and the encapsulation of guest species within these superstructures. We anticipate that this will provide new routes to capsules, reactors and composite materials.

  6. The emergence of two anti-phase oscillatory neural populations in a computational model of the Parkinsonian globus pallidus

    Directory of Open Access Journals (Sweden)

    Robert John Merrison-Hort

    2013-12-01

    Full Text Available Experiments in rodent models of Parkinson's Disease have demonstrated a prominent increase of oscillatory firing patterns in neurons within the Parkinsonian globus pallidus (GP which may underlie some of the motor symptoms of the disease. There are two main pathways from the cortex to GP: via the striatum and via the subthalamic nucleus (STN, but it is not known how these inputs sculpt the pathological pallidal firing patterns. To study this we developed a novel neural network model of conductance-based spiking pallidal neurons with cortex-modulated input from STN neurons. Our results support the hypothesis that entrainment occurs primarily via the subthalamic pathway. We find that as a result of the interplay between excitatory input from the STN and mutual inhibitory coupling between GP neurons, a homogeneous population of GP neurons demonstrates a self-organising dynamical behaviour where two groups of neurons emerge: one spiking in-phase with the cortical rhythm and the other in anti-phase. This finding mirrors what is seen in recordings from the GP of rodents that have had Parkinsonism induced via brain lesions. Our model also includes downregulation of Hyperpolarization-activated Cyclic Nucleotide-gated (HCN channels in response to burst firing of GP neurons, since this has been suggested as a possible mechanism for the emergence of Parkinsonian activity. We found that the downregulation of HCN channels provides even better correspondence with experimental data but that it is not essential in order for the two groups of oscillatory neurons to appear. We discuss how the influence of inhibitory striatal input will strengthen our results.

  7. Azobenzene mesogen-passivated gold nanoparticles: Controlled preparation, self-organized superstructures, thermal behavior and photoisomerization

    Energy Technology Data Exchange (ETDEWEB)

    Duan, Junfei [Key Laboratory of High Performance Polymer Materials and Technology of Ministry of Education, Department of Polymer Science and Engineering, School of Chemistry and Chemical Engineering, Nanjing University, Nanjing 210093 (China); Department of Physics and Electronic Science, Changsha University of Science and Technology, Changsha, Hunan 410076 (China); Wang, Meng; Bian, Huafeng; Zhou, Yang; Ma, Jie; Liu, Chengjie [Key Laboratory of High Performance Polymer Materials and Technology of Ministry of Education, Department of Polymer Science and Engineering, School of Chemistry and Chemical Engineering, Nanjing University, Nanjing 210093 (China); Chen, Dongzhong, E-mail: cdz@nju.edu.cn [Key Laboratory of High Performance Polymer Materials and Technology of Ministry of Education, Department of Polymer Science and Engineering, School of Chemistry and Chemical Engineering, Nanjing University, Nanjing 210093 (China)

    2014-12-15

    Liquid crystal nanoscience has aroused intensive interests mainly due to their unique and collective properties and a variety of potential applications. In this paper, gold nanoparticles (GNPs) coated with alkoxy azobenzene mesogenic thiol ligands of different length polymethylene spacer and linear alkyl thiol co-ligands have been prepared. The thermal properties, phase behavior of thus obtained hybrid GNPs and photophysical properties of their solid-state films have been investigated by differential scanning calorimetry (DSC), variable-temperature small and wide angle X-ray scattering (SAXS/WAXS) and UV–vis spectroscopy. The hybrid GNPs exclusively passivated with azobenzene mesogenic ligands showed lamellar structure while those with mixed ligands exhibited hexagonal columnar superstructure, and the latter complex hybrid GNPs exhibited noticeably improved thermolysis resistance. Moreover, it is very interesting that the solid-state films of the hybrid GNPs displayed reversible photoresponse owing to the trans–cis transformation of azobenzene mesogenic ligands, and compared with the hybrid GNPs coated with mesogenic ligands only, those with mixed ligands exhibited faster photoisomerization rate upon alternate UV and visible light irradiation, which may have some promising applications. - Graphical abstract: Gold nanoparticles (GNPs) coated with azobenzene mesogenic thiol ligands and linear alkyl thiol co-ligands have been prepared showing lamellar or hexagonal columnar superstructures. The complex hybrid GNPs with co-ligands exhibit much improved thermolysis resistance and the solid-state films of the hybrid GNPs display interesting reversible photoisomerization. - Highlights: • Gold nanoparticles (GNPs) coated with azobenzene thiol ligands have been prepared. • The hybrid GNPs with alkyl thiol co-ligands show enhanced thermolysis resistance. • The hybrid GNPs exhibit lamellar or hexagonal columnar superstructures. • The solid-state films of the hybrid

  8. A microwave promoted continuous flow approach to self-assembled hierarchical hematite superstructures

    OpenAIRE

    Bayazit, M.K.; Cao, E; Gavriilidis, A; Tang, J.

    2016-01-01

    In this work, a microwave promoted flow (MWPF) system to reproducibly synthesize self-assembled hierarchical hematite superstructures (Hem-SSs) using the sole precursor (Fe(NO3)3·9H2O) and single mode microwave under aqueous conditions was developed. The functional characterisation by XRD, (HR)TEM, XPS, UV-vis and Raman spectroscopy proved that highly crystalline ellipsoid Hem-SSs (∼180 nm × 140 nm) were produced, built from primary hematite nanoparticles, 5–10 nm in size using 0.05 mol L−1 p...

  9. Incommensurate superstructure in heavily doped fullerene layer on Bi/Si(111) surface

    Science.gov (United States)

    Gruznev, D. V.; Bondarenko, L. V.; Tupchaya, A. Y.; Matetskiy, A. V.; Zotov, A. V.; Saranin, A. A.

    2015-08-01

    Cs adsorption onto the C60-covered Si(111)-β- √{ 3 } × √{ 3 } -Bi reconstruction has been studied by means of scanning tunneling microscopy and photoelectron spectroscopy. Unexpected increase in apparent size of every second C60 molecule has been detected, hereupon the close packed molecular array almost doubles its periodicity. The change affects only the fullerenes that are in direct contact with the metal-induced reconstruction and takes no place already in the second layer. Photoelectron studies have revealed that this incommensurate "2 × 2" superstructure of a heavily doped C60 monolayer remains in an insulating state regardless of doping level.

  10. System design optimization for stand-alone photovoltaic systems sizing by using superstructure model

    Science.gov (United States)

    Azau, M. A. M.; Jaafar, S.; Samsudin, K.

    2013-06-01

    Although the photovoltaic (PV) systems have been increasingly installed as an alternative and renewable green power generation, the initial set up cost, maintenance cost and equipment mismatch are some of the key issues that slows down the installation in small household. This paper presents the design optimization of stand-alone photovoltaic systems using superstructure model where all possible types of technology of the equipment are captured and life cycle cost analysis is formulated as a mixed integer programming (MIP). A model for investment planning of power generation and long-term decision model are developed in order to help the system engineer to build a cost effective system.

  11. Low temperature synthesis of flower-like ZnMn 2O 4 superstructures with enhanced electrochemical lithium storage

    Science.gov (United States)

    Xiao, Lifen; Yang, Yanyan; Yin, Jia; Li, Qiao; Zhang, Lizhi

    In this communication, flower-like tetragonal ZnMn 2O 4 superstructures are synthesized by a facile low temperature solvothermal process. Characterizations show that these ZnMn 2O 4 superstructures are well crystallized and of high purity. The product exhibits an initial electrochemical capacity of 763 mAh g -1 and retains stable capacity of 626 mAh g -1 after 50 cycles. Its stable capacity is significantly higher than that of nanocrystalline ZnMn 2O 4 synthesized by a polymer-pyrolysis method. It is found that the higher capacity retention can be attributed to three-dimensional superstructural nature of the as-prepared flower-like ZnMn 2O 4 material. This study suggests that the solvothermally synthesized flower-like ZnMn 2O 4 is a promising anode material for lithium-ion batteries.

  12. Domains and domain loss

    DEFF Research Database (Denmark)

    Haberland, Hartmut

    2005-01-01

    The domain concept, originally suggested by Schmidt-Rohr in the 1930’s (as credited in Fishman’s writings in the 1970s), was an attempt to sort out different areas of language use in multilingual societies, which are relevant for language choice. In Fishman’s version, domains were considered...... not described in terms of domains, and recent research e.g. about the multilingual communities in the Danish-German border area seems to confirm this....

  13. Design and Simulation for Producing Two Amplitude Matched Anti-phase Sine Waveforms Using ±2.5 V CMOS Current-Mode Approach

    OpenAIRE

    Anil Kumar Sharma; Dipankar Pal

    2010-01-01

    In this paper the current mode approach called “Current Conveyor (CCII+)” has been incorporated to design and simulate the circuit for producing two amplitude matched anti-phase sine waveforms which are frequently used in various communication and instrumentation systems. PSpice simulation has been used to depict the output waveforms. The power supply used is ±2.5 V which can be easily incorporated with CMOS IC technology. The designed circuit has been simulated at variousfrequency ranges and...

  14. Evolution of Dislocation Subsystem Components During Plastic Deformation Depending on Parameters of Strengthening Phase with L12 Superstructure

    Science.gov (United States)

    Daneyko, O. I.; Kovalevskaya, T. A.; Kulaeva, N. A.; Kolupaeva, S. N.; Shalygina, T. A.

    2017-09-01

    The paper presents results of mathematical modelling of plastic deformation in dispersion-hardened materials with FCC crystal system and L12 superstructure particles. Research results show that the size and the distance between particles of the strengthening phase affect the strain hardening and the evolution of the dislocation subsystem of the FCC alloy hardened with coherent L12 superstructure particles. It is found that increased size of ordered particles or decreased distance between them enhances the abnormal growth in the flow stress and the density of the dislocation subsystem components. Investigations show that prismatic dislocation loops predominate in the dislocation subsystem of materials having a nano-dispersion strengthening phase.

  15. Superstructures formed by orientationally ordered tetrahedra in the bcc lattice: new diffusionless order-disorder transition in solids.

    Science.gov (United States)

    Tamura, Ryuji

    2015-03-04

    We investigated and clarified the superstructures formed by tetrahedra in the bcc lattice within the framework of second-order transitions. Compliance with both the Landau and Lifshitz conditions was investigated for all possible superstructures and, based on this, we demonstrate that bcc crystals that contain tetrahedra at an inversion center can exhibit a variety of second-order transitions, which are regarded as a new type of diffusionless order-disorder transition with antiferroic orientational orders. Finally, we show that the transition gives rise to a new glassy state. Breaking of the local inversion symmetry may lead to a new orientational glass, which is reminiscent of spin glasses in magnetism.

  16. The Effects on the Operating Condition of a Passenger Ship Retro-fitted with a Composite Superstructure

    DEFF Research Database (Denmark)

    Karatzas, Vasileios; Hjørnet, N. K.; Kristensen, Hans Otto Holmegaard

    2016-01-01

    the stability of the ship. In this work, the superstructure of a RoPax ferry has been redesigned using composite materials emphasizing the effects on the ship from an operational per-spective. The weight reduction has been calculated for a real-istic average operating condition quantifying the effects......As sustainability and climate change have come on the politi-cal agenda, the shipping industry will have to be operating energy efficient ships. An appealing step to achieve this goal is by designing superstructures made out of Fiber Reinforced Plastics (FRP) aiming at the reduction of the ship...

  17. Comparative analysis of cogeneration power plants optimization based on stochastic method using superstructure and process simulator

    Energy Technology Data Exchange (ETDEWEB)

    Araujo, Leonardo Rodrigues de [Instituto Federal do Espirito Santo, Vitoria, ES (Brazil)], E-mail: leoaraujo@ifes.edu.br; Donatelli, Joao Luiz Marcon [Universidade Federal do Espirito Santo (UFES), Vitoria, ES (Brazil)], E-mail: joaoluiz@npd.ufes.br; Silva, Edmar Alino da Cruz [Instituto Tecnologico de Aeronautica (ITA/CTA), Sao Jose dos Campos, SP (Brazil); Azevedo, Joao Luiz F. [Instituto de Aeronautica e Espaco (CTA/IAE/ALA), Sao Jose dos Campos, SP (Brazil)

    2010-07-01

    Thermal systems are essential in facilities such as thermoelectric plants, cogeneration plants, refrigeration systems and air conditioning, among others, in which much of the energy consumed by humanity is processed. In a world with finite natural sources of fuels and growing energy demand, issues related with thermal system design, such as cost estimative, design complexity, environmental protection and optimization are becoming increasingly important. Therefore the need to understand the mechanisms that degrade energy, improve energy sources use, reduce environmental impacts and also reduce project, operation and maintenance costs. In recent years, a consistent development of procedures and techniques for computational design of thermal systems has occurred. In this context, the fundamental objective of this study is a performance comparative analysis of structural and parametric optimization of a cogeneration system using stochastic methods: genetic algorithm and simulated annealing. This research work uses a superstructure, modelled in a process simulator, IPSEpro of SimTech, in which the appropriate design case studied options are included. Accordingly, the cogeneration system optimal configuration is determined as a consequence of the optimization process, restricted within the configuration options included in the superstructure. The optimization routines are written in MsExcel Visual Basic, in order to work perfectly coupled to the simulator process. At the end of the optimization process, the system optimal configuration, given the characteristics of each specific problem, should be defined. (author)

  18. Anomalous hexagonal superstructure of aluminum oxide layer grown on NiAl(110) surface

    Science.gov (United States)

    Krukowski, Pawel; Chaunchaiyakul, Songpol; Minagawa, Yuto; Yajima, Nami; Akai-Kasaya, Megumi; Saito, Akira; Kuwahara, Yuji

    2016-11-01

    A modified method for the fabrication of a highly crystallized layer of aluminum oxide on a NiAl(110) surface is reported. The fabrication method involves the multistep selective oxidation of aluminum atoms on a NiAl(110) surface resulting from successive oxygen deposition and annealing. The surface morphology and local electronic structure of the novel aluminum oxide layer were investigated by high-resolution imaging using scanning tunneling microscopy (STM) and current imaging tunneling spectroscopy. In contrast to the standard fabrication method of aluminum oxide on a NiAl(110) surface, the proposed method produces an atomically flat surface exhibiting a hexagonal superstructure. The superstructure exhibits a slightly distorted hexagonal array of close-packed bright protrusions with a periodicity of 4.5 ± 0.2 nm. Atomically resolved STM imaging of the aluminum oxide layer reveals a hexagonal arrangement of dark contrast spots with a periodicity of 0.27 ± 0.02 nm. On the basis of the atomic structure of the fabricated layer, the formation of α-Al2O3(0001) on the NiAl(110) surface is suggested.

  19. Solving a superstructure from two-wavelength x-ray powder diffraction data- a simulation

    Institute of Scientific and Technical Information of China (English)

    陈建荣; 古元新; 范海福

    2003-01-01

    Two different kinds of phase ambiguities are intrinsic in two-wavelength x-ray powder diffraction from acentric crystal structures having pseudo-translation symmetry. In a test calculation we have solved the problem for the first time by two different phasing procedures developed originally in single-crystal structure analysis. They are the direct method of breaking enantiomorphous phase ambiguity in protein crystallography and that of breaking translational phase ambiguity for superstructures. An artificial structure was used in the test, which is based on atomic coordinates of the known structure, SHAS (C5H6O5N3K), with the atom K replaced by Rb. The arrangement of Rb atoms possesses a subperiodicity of t = (a + b + c)/2. Two-wavelength synchrotron x-ray powder diffraction data were simulated with λ1 =0.0816nm and λ2=0.1319nm. Overlapped reflections were uniformly decomposed at the beginning and redecomposed afterward when the partial-structure information became available. The enantiomorphous phase ambiguity was resolved only for reflections with h + k + l even. Phases of reflections with h + k + l odd were derived by the direct method of solving superstructures. A fragment was then obtained, which led to the complete structure in five cycles of Fourier iteration.

  20. Solving a superstructure from two—wavelength x—ray powder diffraction data—a simulation

    Institute of Scientific and Technical Information of China (English)

    陈建荣; 古元新; 等

    2003-01-01

    Two different kinds of phase ambiguities are intrinsic in two-wavelength x-ray powder diffraction from acentric crystal structures having pseudo-translation symmetry.In a test calculation we have solved the problem for the first time by two different phasing procedures developed originally in single-crystal structure analysis.They are the direct method of breaking enantiomorphous phase ambiguity in protein crystallography and that of breaking translational phase ambiguity for superstructures.An artificial structure was used in the test,which is based on atomic coordinates of the known structure,SHAS(C5H6O5N3K),with the atom K replaced by Rb.The arrangement of Rb atoms possesses a subperiodicity of t =(a+b+c)/2.Two -wavelength synchrotron x-ray powder diffraction data were simulated with λ1=0.0816nm and λ2=0.1319nm.Overlapped reflections were uniformly decomposed at the beginning and rdedcomposed afterward when the partial-structure in formation became available.The enantiomorphous phase ambiguity was resolved only for reflections with h+k+l even.Phases of reflections with h+k+l odd were derived by the direct method of solving superstructures.A fragment was then obtained.which led to the the complete structure in five cycles of Fourier iteration.

  1. The Effect of Superstructures Connected to Implants with Different Surface Properties on the Surrounding Bone

    Directory of Open Access Journals (Sweden)

    Katsunori Koretake

    2015-07-01

    Full Text Available The objective of this study was to investigate how the connection of superstructures to implants with different surface properties affects the surrounding bone. The right and left mandibular premolars and molars of 5 dogs were extracted. After 12 weeks, a machined implant was placed mesially and an anodized implant was placed distally on one side of the edentulous jaw, with the positions reversed on the opposite side. Twelve weeks after implantation, splinted superstructures were set to the implants. At 24 weeks after implantation, the implant stability quotient (ISQ was measured, radiographs were obtained. Removal torque values were measured and histologic observation was performed. The ISQ values at 24 weeks after implantation were not significantly different between the groups. The removal torque values were significantly different between the distal anodized and distal machined implants (p < 0.05. From 12 to 24 weeks, marginal bone losses were not significantly different between the groups. Fluorescent observation of tissue samples revealed bone-remodeling activity around all of the implants. The results of this study suggest that when implants with different surface properties are connected, machined implants at the most distal sites might be a potential risk factor for implant-bone binding.

  2. Combined mass and heat exchange network synthesis based on stage-wise superstructure model☆

    Institute of Scientific and Technical Information of China (English)

    Linlin Liu; Jian Du; Fenglin Yang

    2015-01-01

    Integrating multiple systems into one has become an important trend in Process Systems Engineering research field since there is strong demand from the modern industries. In this study, a stage-wise superstructure-based method is proposed to synthesize a combined mass and heat exchange network (CM&HEN) which has two parts as the mass exchange network (MEN) and heat exchange network (HEN) involved. To express the pos-sible heat exchange requirements resulted from mass exchange operations, a so cal ed“indistinct HEN super-structure (IHS)”, which can contain the all potential matches between streams, is constructed at first. Then, a non-linear programming (NLP) mathematical model is established for the simultaneous synthesis and optimiza-tion of networks. Therein, the interaction between mass exchange and heat exchange is modeling formulated. The NLP model has later been examined using an example from literature, and the effectiveness of the proposed method has been demonstrated with the results.

  3. Antipulverization Electrode Based on Low-Carbon Triple-Shelled Superstructures for Lithium-Ion Batteries.

    Science.gov (United States)

    Zu, Lianhai; Su, Qingmei; Zhu, Feng; Chen, Bingjie; Lu, Huanhuan; Peng, Chengxin; He, Ting; Du, Gaohui; He, Pengfei; Chen, Kai; Yang, Shihe; Yang, Jinhu; Peng, Huisheng

    2017-09-01

    The realization of antipulverization electrode structures, especially using low-carbon-content anode materials, is crucial for developing high-energy and long-life lithium-ion batteries (LIBs); however, this technology remains challenging. This study shows that SnO2 triple-shelled hollow superstructures (TSHSs) with a low carbon content (4.83%) constructed by layer-by-layer assembly of various nanostructure units can withstand a huge volume expansion of ≈231.8% and deliver a high reversible capacity of 1099 mAh g(-1) even after 1450 cycles. These values represent the best comprehensive performance in SnO2 -based anodes to date. Mechanics simulations and in situ transmission electron microscopy suggest that the TSHSs enable a self-synergistic structure-preservation behavior upon lithiation/delithiation, protecting the superstructures from collapse and guaranteeing the electrode structural integrity during long-term cycling. Specifically, the outer shells during lithiation processes are fully lithiated, preventing the overlithiation and the collapse of the inner shells; in turn, in delithiation processes, the underlithiated inner shells work as robust cores to support the huge volume contraction of the outer shells; meanwhile, the middle shells with abundant pores offer sufficient space to accommodate the volume change from the outer shell during both lithiation and delithiation. This study opens a new avenue in the development of high-performance LIBs for practical energy applications. © 2017 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

  4. A Critical Reassessment of Marxian Base-Superstructure Explanations of the Role of Education in Social Change.

    Science.gov (United States)

    Chun, Kyung-Kap

    1986-01-01

    Examines how four major versions of neo-Marxism (i.e., Hegelian, Phenomenological, Structuralist Marxism, and the Frankfurt School) attempt to overcome the base-superstructure thesis of the political economists of education. Considers the implicit social ontological and epistemological assumptions and the related theory of education of each.…

  5. Nanoscale superstructures assembled by polymerase chain reaction (PCR): programmable construction, structural diversity, and emerging applications.

    Science.gov (United States)

    Kuang, Hua; Ma, Wei; Xu, Liguang; Wang, Libing; Xu, Chuanlai

    2013-11-19

    Polymerase chain reaction (PCR) is an essential tool in biotechnology laboratories and is becoming increasingly important in other areas of research. Extensive data obtained over the last 12 years has shown that the combination of PCR with nanoscale dispersions can resolve issues in the preparation DNA-based materials that include both inorganic and organic nanoscale components. Unlike conventional DNA hybridization and antibody-antigen complexes, PCR provides a new, effective assembly platform that both increases the yield of DNA-based nanomaterials and allows researchers to program and control assembly with predesigned parameters including those assisted and automated by computers. As a result, this method allows researchers to optimize to the combinatorial selection of the DNA strands for their nanoparticle conjugates. We have developed a PCR approach for producing various nanoscale assemblies including organic motifs such as small molecules, macromolecules, and inorganic building blocks, such as nanorods (NRs), metal, semiconductor, and magnetic nanoparticles (NPs). We start with a nanoscale primer and then modify that building block using the automated steps of PCR-based assembly including initialization, denaturation, annealing, extension, final elongation, and final hold. The intermediate steps of denaturation, annealing, and extension are cyclic, and we use computer control so that the assembled superstructures reach their predetermined complexity. The structures assembled using a small number of PCR cycles show a lower polydispersity than similar discrete structures obtained by direct hybridization between the nanoscale building blocks. Using different building blocks, we assembled the following structural motifs by PCR: (1) discrete nanostructures (NP dimers, NP multimers including trimers, pyramids, tetramers or hexamers, etc.), (2) branched NP superstructures and heterochains, (3) NP satellite-like superstructures, (4) Y-shaped nanostructures and DNA

  6. Coherent anti-phasing between solar forcing and tropical Pacific climate over the past millennium: derivation and implications

    Science.gov (United States)

    Emile-Geay, J.; Cobb, K.; Mann, M. E.; Wittenberg, A. T.

    2011-12-01

    Using a compilation of the most recent, high-resolution proxy data from the tropics, and a state-of-the-art climate reconstruction technique (RegEM iTTLS; Emile-Geay et al, submitted), we reconstruct sea-surface temperature (SST) in the central equatorial Pacific (NINO3.4 region) over the past millennium. Using frozen network experiments and pseudoproxy validation, the reconstruction is found skillful back to 1150 C.E., with inevitable amplitude reduction before 1500 C.E. due to the paucity of proxy predictors. Despite this caveat, wavelet coherency analysis reveals a marked anticorrelation between solar forcing (as estimated from cosmogenic isotope concentrations; Bard et al., 2007; Steinhilber et al., 2009) and the reconstructed NINO3.4 in the ~sim205-year spectral range (DeVries cycle). The phase angle between both signals is 156 ± 33o in this range, indicating that periods of high solar irradiance coincide with cool conditions in the NINO3.4 region, with time lag of 14 ± 19 years. We find this result robust to the reconstruction method, estimate of solar forcing, or analysis method used to estimate the phasing. We then discuss the implication of this result for the response of tropical Pacific climate to radiative forcing. While the anti-phasing seems to favor the ``ocean dynamical thermostat'' hypothesis of Clement et al [1996], this feedback appears subdued in most IPCC-class coupled general circulation models (CGCMs), where it is almost completely compensated by changes in the Pacific trade winds, linked to changes in the vertical structures of atmospheric moisture and temperature (Knutson & Manabe 1995; Held & Soden 2006; Vecchi et al. 2006). If the reconstruction is correct that past NINO3.4 SSTs have varied out of phase with solar irradiance on bicentennial scales, this would pose a new challenge both for CGCM simulations and for our understanding of the equatorial Pacific response to radiative forcing Clement, A. C., Seager, R., Cane, M. A., and Zebiak

  7. Systematic network synthesis and design: Problem formulation, superstructure generation, data management and solution

    DEFF Research Database (Denmark)

    Quaglia, Alberto; Gargalo, Carina L.; Chairakwongsa, Siwanat;

    2015-01-01

    The developments obtained in recent years in the field of mathematical programming considerably reduced the computational time and resources needed to solve large and complex Mixed Integer Non Linear Programming (MINLP) problems. Nevertheless, the application of these methods in industrial practice...... when large problems are considered. In an earlier work, we proposed a computer-aided framework for synthesis and design of process networks. In this contribution, we expand the framework by including methods and tools developed to structure, automate and simplify the mathematical formulation...... is still limited by the complexity associated with the mathematical formulation of some problems. In particular, the tasks of design space definition and representation as superstructure, as well as the data collection, validation and handling may become too complex and cumbersome to execute, especially...

  8. Template-free synthesis of beta-In2S3 superstructures and their photocatalytic activity.

    Science.gov (United States)

    Amutha, R; Akilandeswari, S; Ahmmad, Bashir; Muruganandham, M; Sillanpää, Mika

    2010-12-01

    In this article, we have successfully fabricated various morphological beta-Indium sulfide (In2S3) superstructures by using indium thiocyanate complex at acidic pH. All the synthesis has been performed by a template-free, hydrothermal method at 195 degrees C for 3 h. The photocatalytic activity of synthesized In2S3 have been investigated by using UV-B (lamda = 365 nm) light with Methyl Orange dye as a model pollutant. The synthesized photocatalyst was characterized by using XRD, FE-SEM, HR-TEM, DRS spectra and nitrogen adsorption analysis. The influence of indium precursors and solvents on the morphology as well as the surface properties has also been discussed. The XRD result shows that cubic phase beta-In2S3 formed under all experimental conditions. A plausible mechanism of the In2S3 microsphere formation has been discussed based on experimental observations.

  9. Growth and Transfer of Monolithic Horizontal ZnO Nanowire Superstructures onto Flexible Substrates

    KAUST Repository

    Xu, Sheng

    2010-04-28

    A method of fabricating horizontally aligned ZnO nanowire (NW) arrays with full control over the width and length is demonstrated. A cross-sectional view of the NWs by transmission electron microscopy shows a "mushroom-like" structure. Novel monolithic multisegment superstructures are fabricated by making use of the lateral overgrowth. Ultralong horizontal ZnO NWs of an aspect ratio on the order often thousand are also demonstrated. These horizontal NWs are lifted off and transferred onto a flexible polymer substrate, which may have many great applications in horizontal ZnO NW-based nanosensor arrays, light-emitting diodes, optical gratings, integrated circuit interconnects, and high-output-power alternating-current nanogenerators. © 2010 WILEY-VCH Verlag GmbH & Co. KGaA.

  10. Synthesis of noble metal nanoparticles and their superstructures; Darstellung von Edelmetallnanopartikeln und deren Ueberstrukturen

    Energy Technology Data Exchange (ETDEWEB)

    Bigall, Nadja-Carola

    2009-08-18

    A modified synthesis procedure for citrate-stabilized gold nanoparticles in aqueous solution is transferred under application of equal concentrations to the systems silver, platinum, and palladium. The nanoparticles are analyzed by means of absorption spectroscopy and electron microscopy. Ordered superstructures of the noble-metal nanoparticles can be synthesized by infiltration of templates of block-copolymer films with aqueous nanoparticle solution. In dependence on the pre-treatment of the polymer films either two-dimensional periodical arrangements with a periodicity of less than 30 nm or fingerprint-like arrangements with a groove distance in the same order of magnitude. By removal of the polymer one- respectively two-dimensional arrangements of platinum nanowires respectively nanoparticles on a silicon waver arise.

  11. Application of x-ray direct methods to surface reconstructions: The solution of projected superstructures

    Science.gov (United States)

    Torrelles, X.; Rius, J.; Boscherini, F.; Heun, S.; Mueller, B. H.; Ferrer, S.; Alvarez, J.; Miravitlles, C.

    1998-02-01

    The projections of surface reconstructions are normally solved from the interatomic vectors found in two-dimensional Patterson maps computed with the intensities of the in-plane superstructure reflections. Since for difficult reconstructions this procedure is not trivial, an alternative automated one based on the ``direct methods'' sum function [Rius, Miravitlles, and Allmann, Acta Crystallogr. A52, 634 (1996)] is shown. It has been applied successfully to the known c(4×2) reconstruction of Ge(001) and to the so-far unresolved In0.04Ga0.96As (001) p(4×2) surface reconstruction. For this last system we propose a modification of one of the models previously proposed for GaAs(001) whose characteristic feature is the presence of dimers along the fourfold direction.

  12. Plasma oscillations in two-dimensional semiconductor superstructures in the presence of a high electric field

    CERN Document Server

    Glazov, S Y

    2001-01-01

    The effect of the high permanent electric field on plasma oscillations in the two-dimensional electron gas with the superstructure and taking into account the transfer processes is investigated. The dispersions omega(k) is obtained for the case of high temperature T (DELTA << T, where DELTA is the width of the conductivity miniband). It is shown that the frequency of plasmons in the high electric field depends on the value of the electric field intensity and the wave number k as the oscillating function. The spectrum is periodic with the period equal to 2 pi/d for arbitrary values of k. The numerical estimation shown that the oscillations can be manifested at the electric field intensity more than 3 x 10 sup 3 V/cm

  13. Extended and quasi-continuous tuning of quantum cascade lasers using superstructure gratings and integrated heaters

    Energy Technology Data Exchange (ETDEWEB)

    Bidaux, Yves, E-mail: yves.bidaux@alpeslasers.ch [Alpes Lasers SA, 1-3 Passsage Max Meuron, CH-2001 Neuchâtel (Switzerland); Institute for Quantum Electronics, ETH-Zurich, CH-8093 Zurich (Switzerland); Bismuto, Alfredo, E-mail: alfredo.bismuto@alpeslasers.ch; Tardy, Camille; Terazzi, Romain; Gresch, Tobias; Blaser, Stéphane; Muller, Antoine [Alpes Lasers SA, 1-3 Passsage Max Meuron, CH-2001 Neuchâtel (Switzerland); Faist, Jerome [Institute for Quantum Electronics, ETH-Zurich, CH-8093 Zurich (Switzerland)

    2015-11-30

    In this work, we demonstrate broad electrical tuning of quantum cascade lasers at 9.25 μm, 8.5 μm, and 4.4 μm in continuous wave operation using Vernier-effect distributed Bragg reflectors based on superstructure gratings. Integrated micro-heaters allow to switch from one Vernier channel to the other, while predictable and mode-hop free tuning can be obtained in each channel modulating the laser current with a side mode suppression ratio as high as 30 dB. The resulting device behaves effectively as a switchable multicolour tunable source. Tuning up to 6.5% of the central wavelength is observed. To prove the importance of the developed devices for high resolution molecular spectroscopy, a N{sub 2}O absorption spectrum has been measured.

  14. Chemical ordering beyond the superstructure in long-range ordered systems

    CERN Document Server

    Stana, Markus; Kozubski, Rafal; Leitner, Michael

    2016-01-01

    To describe chemical ordering in solid solutions systems Warren-Cowley short-range parameters are ordinarily used. However, they are not directly suited for application to long-range ordered systems, as they do not converge to zero for large separations. It is the aim of this paper to generalize the theory to long-range ordered systems and quantitatively discuss chemical short-range order beyond the superstructure arrangements. This is demonstrated on the example of a non-stoichiometric B2-ordered intermetallic alloy. Parameters of interatomic potentials are taken from an embedded atom method (EAM) calculations and the degree of order is simulated by the Monte Carlo method. Both on-lattice and off-lattice methods, where the latter allows individual atoms to deviate from their regular lattice sites, were used, and the resulting effects are discussed.

  15. Construction and control technology of the main bridge superstructure of Sutong Bridge

    Institute of Scientific and Technical Information of China (English)

    Zhang Hong; Luo Chenbin; Zhang Yongtao; You Xinpeng

    2009-01-01

    The Sutong Yangtze River Bridge (short as Sutong Bridge) is now the largest span cable-stayed bridge in the world. The construction of the superstructure of the middle bridge covered several stages including erection of the big block girders for the side span, assistant span and tower area, erection of standard girders and closure of the middle span. The big block girders were hoisted by a floating crane, and the standard girders were hoisted by a double crane system on the deck. The pushing assistant method was adopted for the middle span closure construction. Furthermore, key technologies and innovative methods used in the processes of girder erection and cable assemblage in all stages were expatiated systematically. An all-stage self- adaptive geometry control method was used in the construction process. By accurately controlling the unstressed dimensions and shape of all structural components in each step, and realization that the control system and the controlled system adapt to each other, the goal was to make control of the final line shape and inner force of the bridge structure achievable. Two solutions, including GPS based and total station based dynamic geometry monitoring systems, were used to resolve the measure problem under the wide-range of wind-induced vibrations in the long cantilever state. Finally, research on the wind-induced vibration of the superstructure during the construction period was executed. Buffeting response analysis to the longest single and double cantilever states were carried out. The analysis and evaluation of wind resistance safety of the main girders under the longest single cantilever state was made, and corresponding wind resistance measures were suggested. The as-built geometric error and cable force error were controlled in a required design range, and this whole technological achievement can be a benchmark for construction of other large span cable-stayed bridges in the future.

  16. Prevention of Cutaneous Tissue Contracture During Removal of Craniofacial Implant Superstructures for CT and MRI Studies

    Directory of Open Access Journals (Sweden)

    Maureen Sullivan

    2010-04-01

    Full Text Available Objectives: Head and neck cancer patients who have lost facial parts following surgical intervention frequently require craniofacial implant retained facial prostheses for restoration. Many craniofacial implant patients require computed tomography and magnetic resonance imaging scans as part of their long-term follow-up care. Consequently removal of implant superstructures and peri-abutment tissue management is required for those studies. The purpose of the present paper was to describe a method for eliminating cranial imaging artifacts in patients with craniofacial implants.Material and Methods: Three patients wearing extraoral implant retained facial prostheses needing either computed tomography or magnetic resonance imaging studies were discussed. Peri-implant soft tissues contracture after removal of percutaneous craniofacial implant abutments during computed tomography and magnetic resonance imaging studies was prevented using a method proposed by authors. The procedure involves temporary removal of the supra-implant components prior to imaging and filling of the tissue openings with polyvinyl siloxane dental impression material.Results: Immediately after filling of the tissue openings with polyvinyl siloxane dental impression material patients were sent for the imaging studies, and were asked to return for removal of the silicone plugs and reconnection of all superstructure hardware after imaging procedures were complete. The silicone plugs were easily removed with a dental explorer. The percutaneous abutments were immediately replaced and screwed into the implants which were at the bone level.Conclusions: Presented herein method eliminates the source of artifacts and prevents contracture of percutaneous tissues upon removal of the implant abutments during imaging.

  17. Design and Simulation for Producing Two Amplitude Matched Anti-phase Sine Waveforms Using ±2.5 V CMOS Current-Mode Approach

    Directory of Open Access Journals (Sweden)

    Anil Kumar Sharma,

    2010-08-01

    Full Text Available In this paper the current mode approach called “Current Conveyor (CCII+” has been incorporated to design and simulate the circuit for producing two amplitude matched anti-phase sine waveforms which are frequently used in various communication and instrumentation systems. PSpice simulation has been used to depict the output waveforms. The power supply used is ±2.5 V which can be easily incorporated with CMOS IC technology. The designed circuit has been simulated at variousfrequency ranges and the waveforms are obtained after the circuit is optimized.

  18. Electrochemiluminescence induced photoelectrochemistry for sensing of the DNA based on DNA-linked CdS NPs superstructure with intercalator molecules.

    Science.gov (United States)

    Guo, Yingshu; Sun, Yuanshun; Zhang, Shusheng

    2011-02-07

    A novel detection protocol of DNA was developed using electrochemiluminescence (ECL) induced photoelectrochemistry (PEC) synthesis based on DNA-linked CdS NPs superstructure with methylene blue as the intercalator molecule.

  19. A detection of the integrated Sachs-Wolfe imprint of cosmic superstructures using a matched-filter approach

    CERN Document Server

    Nadathur, Seshadri

    2016-01-01

    We present a new method for detection of the integrated Sachs-Wolfe (ISW) imprints of cosmic superstructures on the cosmic microwave background, based on a matched filtering approach. The expected signal-to-noise ratio for this method is comparable to that obtained from the full cross-correlation, and unlike other stacked filtering techniques it is not subject to an a posteriori bias. We apply this method to Planck CMB data using voids and superclusters identified in the CMASS galaxy data from the Sloan Digital Sky Survey Data Release 12, and measure the ISW amplitude to be $A_\\mathrm{ISW}=1.64\\pm0.53$ relative to the $\\Lambda$CDM expectation, corresponding to a $3.1\\sigma$ detection. In contrast to some previous measurements of the ISW effect of superstructures, our result is in agreement with the $\\Lambda$CDM model.

  20. Analysis on the Superstructure of Russian Advertising Text%俄语广告语篇超结构分析

    Institute of Scientific and Technical Information of China (English)

    杨志欣

    2012-01-01

    本文把俄语广告语篇视为特殊的语篇类型,以超结构图式理论为基础分析了俄语广告语篇的超结构图式及其组成范畴,并从实义切分角度描写了俄语广告语篇的优控述位和主位的主要特征。%This paper regards Russian advertising text as a special textual type, and analyses the superstructure of Russian advertising text and its component categories on the basis of the theory of superstructure. It also describes some main features of the theme domination and themes of Russian advertising text according to theory of actual division of the sentence.

  1. A Detection of the Integrated Sachs–Wolfe Imprint of Cosmic Superstructures Using a Matched-filter Approach

    Science.gov (United States)

    Nadathur, Seshadri; Crittenden, Robert

    2016-10-01

    We present a new method for detection of the integrated Sachs–Wolfe (ISW) imprints of cosmic superstructures on the cosmic microwave background (CMB), based on a matched-filtering approach. The expected signal-to-noise ratio for this method is comparable to that obtained from the full cross-correlation, and unlike other stacked filtering techniques it is not subject to an a posteriori bias. We apply this method to Planck CMB data using voids and superclusters identified in the CMASS galaxy data from the Sloan Digital Sky Survey Data Release 12, and measure the ISW amplitude to be {A}{ISW}=1.64+/- 0.53 relative to the ΛCDM expectation, corresponding to a 3.1σ detection. In contrast to some previous measurements of the ISW effect of superstructures, our result is in agreement with the ΛCDM model.

  2. Pressure-Induced Oriented Attachment Growth of Large-Size Crystals for Constructing 3D Ordered Superstructures.

    Science.gov (United States)

    Wang, Jun; Lian, Gang; Si, Haibin; Wang, Qilong; Cui, Deliang; Wong, Ching-Ping

    2016-01-26

    Oriented attachment (OA), a nonclassical crystal growth mechanism, provides a powerful bottom-up approach to obtain ordered superstructures, which also demonstrate exciting charge transmission characteristic. However, there is little work observably pronouncing the achievement of 3D OA growth of crystallites with large size (e.g., submicrometer crystals). Here, we report that SnO2 3D ordered superstructures can be synthesized by means of a self-limited assembly assisted by OA in a designed high-pressure solvothermal system. The size of primary building blocks is 200-250 nm, which is significantly larger than that in previous results (normally pressure plays the key role in the formation of 3D configuration and fusion of adjacent crystals. Furthermore, this high-pressure strategy can be readily expanded to additional materials. We anticipate that the welded structures will constitute an ideal system with relevance to applications in optical responses, lithium ion battery, solar cells, and chemical sensing.

  3. Understanding the formation of CuS concave superstructures with peroxidase-like activity

    Science.gov (United States)

    He, Weiwei; Jia, Huimin; Li, Xiaoxiao; Lei, Yan; Li, Jing; Zhao, Hongxiao; Mi, Liwei; Zhang, Lizhi; Zheng, Zhi

    2012-05-01

    Copper sulfide (CuS) concave polyhedral superstructures (CPSs) have been successfully prepared in an ethanolic solution by a simple solvothermal reaction without the use of surfactants or templates. Two typical well defined, high symmetry CuS concave polyhedrons, forming a concave truncated cuboctahedron and icosahedron were prepared. The effect of the reaction time, temperature and different Cu ion and sulfur sources on the formation of CuS CPSs were investigated and a possible formation mechanism was proposed and discussed based on gas chromatography-mass spectrometry. More importantly, we found, for the first time, that the CuS CPSs exhibit intrinsic peroxidase-like activity, as they can quickly catalyze the oxidation of typical horseradish peroxidase (HRP) substrates, 3,3',5,5'-tetramethylbenzidine (TMB) and o-phenylenediamine (OPD), in the presence of hydrogen peroxide. In addition to the recent discoveries regarding peroxidase mimetics on Fe3O4 NPs and carbon nanostructures, our findings suggest a new kind of candidate for peroxidase mimics. This may open up a new application field of CuS micro-nano structures in biodetection, biocatalysis and environmental monitoring.Copper sulfide (CuS) concave polyhedral superstructures (CPSs) have been successfully prepared in an ethanolic solution by a simple solvothermal reaction without the use of surfactants or templates. Two typical well defined, high symmetry CuS concave polyhedrons, forming a concave truncated cuboctahedron and icosahedron were prepared. The effect of the reaction time, temperature and different Cu ion and sulfur sources on the formation of CuS CPSs were investigated and a possible formation mechanism was proposed and discussed based on gas chromatography-mass spectrometry. More importantly, we found, for the first time, that the CuS CPSs exhibit intrinsic peroxidase-like activity, as they can quickly catalyze the oxidation of typical horseradish peroxidase (HRP) substrates, 3

  4. Rotational superstructure in van der Waals heterostructure of self-assembled C60 monolayer on the WSe2 surface

    Energy Technology Data Exchange (ETDEWEB)

    Santos, Elton J.G.; Sullion, Declan; Chu, Ximo S.; Li, Duo O.; Guisinger, Nathan P.; Wang, Qing Hua

    2017-09-21

    Hybrid van der Waals (vdW) heterostructures composed of two-dimensional (2D) layered materials and self-assembled organic molecules are promising systems for electronic and optoelectronic applications with enhanced properties and performance. Control of molecular assembly is therefore paramount to fundamentally understand the nucleation, ordering, alignment, and electronic interaction of organic molecules with 2D materials. Here, we report the formation and detailed study of highly ordered, crystalline monolayers of C60 molecules self-assembled on the surface of WSe2 in well-ordered arrays with large grain sizes (∼5 μm). Using high-resolution scanning tunneling microscopy (STM), we observe a periodic 2 × 2 superstructure in the C60 monolayer and identify four distinct molecular appearances. Using vdW-corrected ab initio density functional theory (DFT) simulations, we determine that the interplay between vdW and Coulomb interactions as well as adsorbate–adsorbate and adsorbate–substrate interactions results in specific rotational arrangements of the molecules forming the superstructure. The orbital ordering through the relative positions of bonds in adjacent molecules creates a charge redistribution that links the molecule units in a long-range network. This rotational superstructure extends throughout the self-assembled monolayer and opens a pathway towards engineering aligned hybrid organic/inorganic vdW heterostructures with 2D layered materials in a precise and controlled way.

  5. "Dual-template" synthesis of one-dimensional conductive nanoparticle superstructures from coordination metal-peptide polymer crystals.

    Science.gov (United States)

    Rubio-Martínez, Marta; Puigmartí-Luis, Josep; Imaz, Inhar; Dittrich, Petra S; Maspoch, Daniel

    2013-12-20

    Bottom-up fabrication of self-assembled structures made of nanoparticles may lead to new materials, arrays and devices with great promise for myriad applications. Here a new class of metal-peptide scaffolds is reported: coordination polymer Ag(I)-DLL belt-like crystals, which enable the dual-template synthesis of more sophisticated nanoparticle superstructures. In these biorelated scaffolds, the self-assembly and recognition capacities of peptides and the selective reduction of Ag(I) ions to Ag are simultaneously exploited to control the growth and assembly of inorganic nanoparticles: first on their surfaces, and then inside the structures themselves. The templated internal Ag nanoparticles are well confined and closely packed, conditions that favour electrical conductivity in the superstructures. It is anticipated that these Ag(I)-DLL belts could be applied to create long (>100 μm) conductive Ag@Ag nanoparticle superstructures and polymetallic, multifunctional Fe3 O4 @Ag nanoparticle composites that marry the magnetic and conductive properties of the two nanoparticle types.

  6. Domain analysis

    DEFF Research Database (Denmark)

    Hjørland, Birger

    2017-01-01

    The domain-analytic approach to knowledge organization (KO) (and to the broader field of library and information science, LIS) is outlined. The article reviews the discussions and proposals on the definition of domains, and provides an example of a domain-analytic study in the field of art studie....... Varieties of domain analysis as well as criticism and controversies are presented and discussed....

  7. X-ray diffraction and spectroscopy of photoinduced ferroic superstructures (Conference Presentation)

    Science.gov (United States)

    Stoica, Vladimir A.; Wen, Haidan; Zhang, Xiaoyi; Zhang, Zhan; Freeland, John W.; Martin, Lane; Ramesh, Ramamoorthy; Gopalan, Venkatraman

    2016-10-01

    Complex oxides and strongly correlated electron systems are at the forefront of science due to their exquisite potential for optical, spintronic, transducing/actuating, multiferroic, electrochemical, and superconducting property enhancements. Accordingly, at the nanoscale, engineering of complex oxide compounds is a promising route for discovery of novel quantum functionalities in a vast space of synthesis technique, calling for high-resolution control and visualization of physical properties and their structural basis. The advent of optical pulse techniques and related instrumentation advances is used to access dynamical separation of correlated orders that hide at equilibrium and also to create novel phases, not available via mainstream synthesis techniques. In this this talk, I will discuss resonant and non-resonant spectroscopic manipulation of phase transitions in nanoferroic oxides, focusing on ultrafast optical creation of artificial supercrystals in epitaxial superlattices. While table top nonlinear optical techniques are used to access the ferroic properties, synchrotron based time-resolved structural techniques, including diffraction and spectroscopy are decisive tools for revealing the nature of orderings in superstructures, their symmetries, phase quantification and spatial distribution with sub-micron resolution.

  8. Presenting a Multi-level Superstructure Optimization Approach for Mechatronic System Design

    DEFF Research Database (Denmark)

    Pedersen, Henrik C.; Andersen, Torben Ole; Bech, Michael Møller

    2010-01-01

    Synergism and integration in the design process is what sets apart a Mechatronic System from a traditional, multidisciplinary system. However the typical design approach has been to divide the design problem into sub problems for each technology area (mechanics, electronics and control) and descr......Synergism and integration in the design process is what sets apart a Mechatronic System from a traditional, multidisciplinary system. However the typical design approach has been to divide the design problem into sub problems for each technology area (mechanics, electronics and control......) and describe the interface between the technologies, whereas the lack of well-established, systematic engineering methods to form the basic set-off in analysis and design of complete mechatronic systems has been obvious. The focus of the current paper is therefore to present an integrated design approach...... for mechatronic system design, utilizing a multi-level superstructure optimization based approach. Finally two design examples are presented and the possibilities and limitations of the approach are outlined....

  9. Influence of plasma-treatments on the structure, superstructure, and function of membrane lipids

    Science.gov (United States)

    Hammer, Malte U.; Forbrig, Enrico; Weltmann, Klaus-Dieter; Reuter, Stephan

    2012-10-01

    Every cell, eu- or prokaryotic, has a membrane as an interface to the environment. Every substance that is applied from outside the cell has to interact with it. This includes plasma-generated reactive species in the liquid cell environment created by plasma-treatment. By the Singer and Nicolson model, proteins are embedded in a lipid bilayer. Proteins are the functional elements, lipids are the structural elements. Due to the amphiphilic nature of the lipids, they form (super-) structures in an aqueous environment. The exact superstructure is determined by a structural parameter of the lipid, its shape. Here, we show experiments on lipids by fluorophore-based liposome assays and raman spectroscopy. The results show a membrane-activity of plasma-born reactive species against lipids and lipid structures. Based on this results and literature, we propose a model for a lesion-forming mechanism in membranes of some reactive species created by plasma-treatment. It is based on a hydrophobic-hydrophilic mismatch due to lipid peroxidization induced by reactive species generated in liquids by plasma-treatment.

  10. Efficient exciton funneling in cascaded PbS quantum dot superstructures.

    Science.gov (United States)

    Xu, Fan; Ma, Xin; Haughn, Chelsea R; Benavides, Jamie; Doty, Matthew F; Cloutier, Sylvain G

    2011-12-27

    Benzenedithiol (BDT) and ethanedithiol (EDT) ligand-exchange treatments can be used to cross-link colloidal PbS quantum dots into nanocrystalline film structures with distinct optoelectronic properties. Such structures can provide a unique platform to study the energy transfer between layers of quantum dots with different sizes. In this report, efficient exciton funneling and recycling of surface state-bound excitons is observed in cascaded PbS quantum dot-based multilayered superstructures, where the excitons transfer from the larger band gap or donor layers to the smallest band gap or acceptor layers. In this system, both the BDT- and EDT-treated cascaded structures exhibit dramatically enhanced photoluminescence from the acceptor layers. As we show, the energy transfer mechanisms involved and their efficiencies are significantly different depending on the ligand-exchange treatment. In the future, we believe these efficient exciton recycling and funneling mechanisms could be used to improve significantly the photocurrent, charge-transport, and conversion efficiencies in low-cost nanocrystalline and hybrid solar cells and the emission efficiencies in hybrid light-emitting devices.

  11. Imprint of DES super-structures on the Cosmic Microwave Background

    CERN Document Server

    Kovács, A; García-Bellido, J; Nadathur, S; Crittenden, R; Gruen, D; Huterer, D; Bacon, D; DeRose, J; Dodelson, S; Gaztañaga, E; Kirk, D; Lahav, O; Miquel, R; Naidoo, K; Soergel, B; Whiteway, L; Abdalla, F B; Allam, S; Annis, J; Benoit-Lévy, A; Bertin, E; Brooks, D; Buckley-Geer, E; Rosell, A Carnero; Kind, M Carrasco; Carretero, J; Cunha, C E; D'Andrea, C B; da Costa, L N; DePoy, D L; Desai, S; Eifler, T F; Finley, D A; Flaugher, B; Fosalba, P; Frieman, J; Giannantonio, T; Goldstein, D A; Gruendl, R A; Gutierrez, G; James, D J; Kuehn, K; Kuropatkin, N; Marshall, J L; Melchior, P; Menanteau, F; Nord, B; Ogando, R; Plazas, A A; Romer, A K; Sanchez, E; Scarpine, V; Sevilla-Noarbe, I; Sobreira, F; Suchyta, E; Swanson, M; Tarle, G; Thomas, D; Walker, A R

    2016-01-01

    Small temperature anisotropies in the Cosmic Microwave Background can be sourced by density perturbations via the late-time integrated Sachs-Wolfe effect. Large voids and superclusters are excellent environments to make a localized measurement of this tiny imprint. In some cases excess signals have been reported. We probed these claims with an independent data set, using the first year data of the Dark Energy Survey in a different footprint, and using a different super-structure finding strategy. We identified 52 large voids and 102 superclusters at redshifts $0.2 < z < 0.65$. We used the Jubilee simulation to a priori evaluate the optimal ISW measurement configuration for our compensated top-hat filtering technique, and then performed a stacking measurement of the CMB temperature field based on the DES data. For optimal configurations, we detected a cumulative cold imprint of voids with $\\Delta T_{f} \\approx -5.0\\pm3.7~\\mu K$ and a hot imprint of superclusters $\\Delta T_{f} \\approx 5.1\\pm3.2~\\mu K$ ; t...

  12. Alkyl imidazolium ionic-liquid-mediated formation of gold particle superstructures.

    Science.gov (United States)

    Ji, Qingmin; Acharya, Somobrata; Richards, Gary J; Zhang, Shaoling; Vieaud, Julien; Hill, Jonathan P; Ariga, Katsuhiko

    2013-06-18

    The development of new methodologies for controlling the organization of quantum materials in multiple dimensions is crucial to the advancement of device fabrication. By using a self-assembly route using selected imidazolium ionic liquids bearing long alkyl chains (C(n)Imida, n = 8, 10, 12) as ligands, we have achieved a tunable assembly of quantum-sized gold nanoparticles. The initial stabilizer of the gold nanoparticles was partially or wholly substituted depending on the concentration and alkyl chain length. π-π interactions between imidazolium rings also promote the generation of spatially controlled aggregates from the nanometer to micrometer size regimes. In particular, in the case of an imidazolium ionic liquid with decyl chains, gold particles assemble into a core-shell spherical superstructure induced by the aggregation of imidazolium ionic liquid molecules during ligand exchange. Conceptually, the assemblies of nanoparticles mimic biological systems and provide strategies for the organization of single-component nanomaterials into functional assemblies for potential applications. Our approach is general and can be applied to other types of nanomaterials for facile manipulation of the assembly processes, permitting an exploration of physicochemical properties as well as technological applications.

  13. Two-Dimensional Bipyramid Plasmonic Nanoparticle Liquid Crystalline Superstructure with Four Distinct Orientational Packing Orders.

    Science.gov (United States)

    Shi, Qianqian; Si, Kae Jye; Sikdar, Debabrata; Yap, Lim Wei; Premaratne, Malin; Cheng, Wenlong

    2016-01-26

    Anisotropic plasmonic nanoparticles have been successfully used as constituent elements for growing ordered nanoparticle arrays. However, orientational control over their spatial ordering remains challenging. Here, we report on a self-assembled two-dimensional (2D) nanoparticle liquid crystalline superstructure (NLCS) from bipyramid gold nanoparticles (BNPs), which showed four distinct orientational packing orders, corresponding to horizontal alignment (H-NLCS), circular arrangement (C-NLCS), slanted alignment (S-NLCS), and vertical alignment (V-NLCS) of constituent particle building elements. These packing orders are characteristic of the unique shape of BNPs because all four packing modes were observed for particles with various sizes. Nevertheless, only H-NLCS and V-NLCS packing orders were observed for the free-standing ordered array nanosheets formed from a drying-mediated self-assembly at the air/water interface of a sessile droplet. This is due to strong surface tension and the absence of particle-substrate interaction. In addition, we found the collective plasmonic coupling properties mainly depend on the packing type, and characteristic coupling peak locations depend on particle sizes. Interestingly, surface-enhanced Raman scattering (SERS) enhancements were heavily dependent on the orientational packing ordering. In particular, V-NLCS showed the highest Raman enhancement factor, which was about 77-fold greater than the H-NLCS and about 19-fold greater than C-NLCS. The results presented here reveal the nature and significance of orientational ordering in controlling plasmonic coupling and SERS enhancements of ordered plasmonic nanoparticle arrays.

  14. [Composition, physico-chemical properties and molecular superstructure of dietary fiber preparations of the cellan type].

    Science.gov (United States)

    Dongowski, G; Frigge, K; Zenke, I

    1995-07-01

    Dietary fiber preparations of "cellan" type were prepared from apples, white cabbage, sugar beet pulp, soy hulls and wheat bran by treatment with amylolytic and proteolytic enzymes as well as by chemical extractions. Scanning electron microscopic examinations show different morphological structures of the preparations and a high maintenance of native biomolecular superstructure. The content of pectin, protein, polysaccharide-hexoses and -pentoses and the composition of monosaccharides (also after their treatment with 4 or 8% sodium hydroxide) were determined. The cellans possess waterbinding capacities (WBC) between 25 g H2O/g and waterholding capacities between 50 g H2O/g. The WBC is related to the internal surface; it diminishes after treatment with NaOH. The interactions between the cellans and the adsorbed water were characterized by NMR-spin-lattice relaxation time T1. The molecular mobility increases as the water content grows. The T1-values of dried cellans decreased with increasing degree of moisture before drying. The supermolecular structure is comparatively disordered. Only in case of soy cellan a crystalline cellulose-I-modification could be identified by X-ray-diffraction pattern, esp. after NaOH treatment. The low degree of order of cellans was observed in the 13C-NMR spectra, too. Only the soy hull preparation resulted in a spectrum corresponding to well-ordered cellulose. The botanic source has an essential influence on the physico-chemical properties of dietary fiber preparations of cellan type.

  15. LADDER SUPERSTRUCTURE-DIRECTED SYNTHESIS OF A WELL-DEFINED m-PHENELENEDIIMINO-BRIDGED LADDER POLYMETHYLSILOXANE

    Institute of Scientific and Technical Information of China (English)

    Yin-sheng Lv; Zhong-jie Ren; You-zhi Wan; Ping Xie; Rong-ben Zhang

    2009-01-01

    A well-defined m-phenylenediimino-bridged ladder polymethylsiloxane (LP) was first synthesized through a well-defined ladder superstructure (LS) acting as synthetic template, which was self-assembled by concerted interaction of hydrogen bonding and aromatic π-π stacking of the monomer (M), N,N'-bis(phenyldichlorosilyl)-m-phenylenediamine. Some key characterization data of LP and, in particular, the extremely vulnerable LS with very unstable Si--Cl and Si-N groups were given. The molecular weights (Mn) of LS and LP are 5010 and 10480, corresponding to about 15 and 46 monomer units, respectively. To monitor the real in situ status of LS in solution the XRD measurements of special freeze-drying samples were performed, demonstrating two characteristic peaks of ladder structure. Most importantly, both LP and LS display exceedingly sharp resonance absorption peaks with a half peak width (△1/2) as small as < 0.3 of MeSi(NH)O2/2 moieties in 29Si-NMR spectra. It is well-known that the higher the regularity of the ladder polysiloxane, the narrower the resonance peak of the siloxane moiety on the ladder backbone, and the smaller the half peak width △1/2. Therefore, the very small values of △1/2 for both LS and LP confirm that both LS and LP possess well-defined ladder structures.

  16. Presenting a Multi-level Superstructure Optimization Approach for Mechatronic System Design

    DEFF Research Database (Denmark)

    Pedersen, Henrik C.; Andersen, Torben Ole; Bech, Michael Møller

    2010-01-01

    Synergism and integration in the design process is what sets apart a Mechatronic System from a traditional, multidisciplinary system. However the typical design approach has been to divide the design problem into sub problems for each technology area (mechanics, electronics and control) and descr......Synergism and integration in the design process is what sets apart a Mechatronic System from a traditional, multidisciplinary system. However the typical design approach has been to divide the design problem into sub problems for each technology area (mechanics, electronics and control......) and describe the interface between the technologies, whereas the lack of well-established, systematic engineering methods to form the basic set-off in analysis and design of complete mechatronic systems has been obvious. The focus of the current paper is therefore to present an integrated design approach...... for mechatronic system design, utilizing a multi-level superstructure optimization based approach. Finally two design examples are presented and the possibilities and limitations of the approach are outlined....

  17. Direct measurement of antiferromagnetic domain fluctuations.

    Energy Technology Data Exchange (ETDEWEB)

    Shpyrko, O. G.; Isaacs, E. D.; Logan, J. M.; Feng, Y.; Aeppli, G.; Jaramillo, R.; Kim, H. C.; Rosenbaum, T. F.; Zschack, P.; Sprung, M.; Narayanan, S.; Sandy, A.; Univ. of Chicago; Univ. College London

    2007-05-03

    Measurements of magnetic noise emanating from ferromagnets owing to domain motion were first carried out nearly 100 years ago1, and have underpinned much science and technology2, 3. Antiferromagnets, which carry no net external magnetic dipole moment, yet have a periodic arrangement of the electron spins extending over macroscopic distances, should also display magnetic noise. However, this must be sampled at spatial wavelengths of the order of several interatomic spacings, rather than the macroscopic scales characteristic of ferromagnets. Here we present a direct measurement of the fluctuations in the nanometer-scale superstructure of spin- and charge-density waves associated with antiferromagnetism in elemental chromium. The technique used is X-ray photon correlation spectroscopy, where coherent X-ray diffraction produces a speckle pattern that serves as a 'fingerprint' of a particular magnetic domain configuration. The temporal evolution of the patterns corresponds to domain walls advancing and retreating over micrometer distances. This work demonstrates a useful measurement tool for antiferromagnetic domain wall engineering, but also reveals a fundamental finding about spin dynamics in the simplest antiferromagnet: although the domain wall motion is thermally activated at temperatures above 100 K, it is not so at lower temperatures, and indeed has a rate that saturates at a finite value--consistent with quantum fluctuations--on cooling below 40 K.

  18. Bone-repair properties of biodegradable hydroxyapatite nano-rod superstructures

    Science.gov (United States)

    D'Elía, Noelia L.; Mathieu, Colleen; Hoemann, Caroline D.; Laiuppa, Juan A.; Santillán, Graciela E.; Messina, Paula V.

    2015-11-01

    Nano-hydroxyapatite (nano-HAp) materials show an analogous chemical composition to the biogenic mineral components of calcified tissues and depending on their topography they may mimic the specific arrangement of the crystals in bone. In this work, we have evaluated the potential of four synthesized nano-HAp superstructures for the in vitro conditions of bone-repair. Experiments are underway to investigate the effects of the material microstructure, surface roughness and hydrophilicity on their osseo-integration, osteo-conduction and osteo-induction abilities. Materials were tested in the presence of both, rat primary osteoblasts and rabbit mesenchymal stem cells. The following aspects are discussed: (i) cytotoxicity and material degradation; (ii) rat osteoblast spreading, proliferation and differentiation; and (iii) rabbit mesenchymal stem cell adhesion on nano-HAp and nano-HAp/collagen type I coatings. We effectively prepared a material based on biomimetic HAp nano-rods displaying the appropriate surface topography, hydrophilicity and degradation properties to induce the in vitro desired cellular responses for bone bonding and healing. Cells seeded on the selected material readily attached, proliferated and differentiated, as confirmed by cell viability, mitochondrial metabolic activity, alkaline phosphatase (ALP) activity and cytoskeletal integrity analysis by immunofluorescence localization of alpha-smooth muscle actin (α-SMA) protein. These results highlight the influence of material's surface characteristics to determine their tissue regeneration potential and their future use in engineering osteogenic scaffolds for orthopedic implants.Nano-hydroxyapatite (nano-HAp) materials show an analogous chemical composition to the biogenic mineral components of calcified tissues and depending on their topography they may mimic the specific arrangement of the crystals in bone. In this work, we have evaluated the potential of four synthesized nano-HAp superstructures

  19. System identification of superstructures with rocking motion and deformation of bases; Kiso ga henkeishi rocking suru kozobutsu no shindo tokusei suiteiho

    Energy Technology Data Exchange (ETDEWEB)

    Sato, K.; Naito, Y.; Uchiyama, S.; Maeda, T.; Matsuda, K. [Kajima Corp., Tokyo (Japan)

    1995-12-20

    Transfer functions of individual parts against bases are generally used as a method for estimating dynamic characteristics of superstructures from observation records of earthquakes or microtremors. However, since soil-structure-interaction (SSI) is included in the observation records, it is difficult to clarify the dynamic characteristics of superstructures, independently. A method has been previously proposed, by which the dynamic characteristics of superstructures without the effect of SSI can be estimated by restricting the vibration mode using equivalent height even in the case of the ground motion condition for multi-particle systems as same as in the case of that for one-particle systems. In this study, this method has been applied to models of SSI systems with rocking and deformation of bases, to estimate the dynamic characteristics of superstructures for ground motion and top excitation conditions. Rigidity of bases was varied as a parameter. Consequently, it was confirmed that the present method can provide accurate estimates of dynamic characteristics of superstructures for both ground motion and top excitation conditions if deformation of bases is not so large. 2 refs., 11 figs., 3 tabs.

  20. A Simplified Model of a Reinforced Square Hollow Section (SHS) T-Joint for Stress Evaluation in Bus Superstructures

    Science.gov (United States)

    Vichiensamuth, T.; Pimsarn, M.; Takahashi, K.; Tantanawat, T.

    2013-06-01

    This study aims to create a simplified model of a reinforced square hollow section (SHS) T-joint found in bus superstructures. The approach is to use a combination of one- and two-dimensional finite element models to represent a reference three-dimensional finite element (solid) model of the joint and determine stress concentration factors (SCFs) as functions of the geometrical variables of the joint. This approach requires the stiffness of the simplified model to be equivalent to the stiffness of the reference solid model. Trial models, therefore, must be proposed and their stiffnesses must be evaluated against the stiffness of the reference solid model. The best trial model is then selected based on the stiffness error function defined to represent the deviation of the simplified model's stiffness from the reference model's stiffness. After a trial model with minimum stiffness error is selected, its SCFs, relating the maximum stress in the simplified model to the maximum stress in the reference solid model, are determined. Since the maximum stress is assumed to be at the weld toe where structural discontinuity exists, the maximum stresses on both simplified model and reference solid model are evaluated based on a hot spot stress (HSS) method. In this study, three trial models, namely Model A, Model B, and Model C, were investigated. Model B, consisting of beam and shell elements with particular constraints on the joint-reinforcement geometry, was found to provide the minimum stiffness errors of 8.09%, 6.87%, and 6.44% for three different joint dimensions. The SCFs were then determined as a function of the thickness-to-width ratio of the joint under static in-plane bending load. The resulting simplified model allows the stress evaluation on the bus superstructures to be done more quickly compared to a solid model while maintaining the accuracy of the solutions. Consequently, the designs of bus superstructures can be explored more thoroughly, leading to a better

  1. Cellulose acetate-directed growth of bamboo-raft-like single-crystalline selenium superstructures: high-yield synthesis, characterization, and formation mechanism.

    Science.gov (United States)

    Song, Ji-Ming; Zhan, Yong-Jie; Xu, An-Wu; Yu, Shu-Hong

    2007-06-19

    High-yield synthesis of bamboo-raft-like single-crystalline selenium superstructures has been realized for the first time via a facile solvothermal approach by reducing SeO2 with ethylene alcohol in the presence of cellulose acetate. The formation of a raftlike superstructure with various forms is strongly dependent on the temperature, amount of cellulose acetate, reaction time, and even preheating treatment. The suitable amount of cellulose acetate is essential for the formation of elegant and uniform raft Se. The morphology, microstructure, optical properties, and chemical compositions of bamboo-raft-like selenium were characterized using various techniques (X-ray diffraction, field emission scanning electron microscopy, transmission electron microscopy (TEM), high-resolution (HR) TEM, X-ray photoelectron spectroscopy, UV-vis spectroscopy, FTIR spectroscopy, and Raman spectroscopy). A possible growth mechanism has been proposed. Such special superstructures could provide a useful precursor for potential applications.

  2. Enzyme oscillation can enhance the thermodynamic efficiency of cellular metabolism: consequence of anti-phase coupling between reaction flux and affinity

    Science.gov (United States)

    Himeoka, Yusuke; Kaneko, Kunihiko

    2016-04-01

    Cells generally convert nutrient resources to products via energy transduction. Accordingly, the thermodynamic efficiency of this conversion process is one of the most essential characteristics of living organisms. However, although these processes occur under conditions of dynamic metabolism, most studies of cellular thermodynamic efficiency have been restricted to examining steady states; thus, the relevance of dynamics to this efficiency has not yet been elucidated. Here, we develop a simple model of metabolic reactions with anabolism-catabolism coupling catalyzed by enzymes. Through application of external oscillation in the enzyme abundances, the thermodynamic efficiency of metabolism was found to be improved. This result is in strong contrast with that observed in the oscillatory input, in which the efficiency always decreased with oscillation. This improvement was effectively achieved by separating the anabolic and catabolic reactions, which tend to disequilibrate each other, and taking advantage of the temporal oscillations so that each of the antagonistic reactions could progress near equilibrium. In this case, anti-phase oscillation between the reaction flux and chemical affinity through oscillation of enzyme abundances is essential. This improvement was also confirmed in a model capable of generating autonomous oscillations in enzyme abundances. Finally, the possible relevance of the improvement in thermodynamic efficiency is discussed with respect to the potential for manipulation of metabolic oscillations in microorganisms.

  3. Enzyme oscillation can enhance the thermodynamic efficiency of cellular metabolism: consequence of anti-phase coupling between reaction flux and affinity.

    Science.gov (United States)

    Himeoka, Yusuke; Kaneko, Kunihiko

    2016-04-05

    Cells generally convert nutrient resources to products via energy transduction. Accordingly, the thermodynamic efficiency of this conversion process is one of the most essential characteristics of living organisms. However, although these processes occur under conditions of dynamic metabolism, most studies of cellular thermodynamic efficiency have been restricted to examining steady states; thus, the relevance of dynamics to this efficiency has not yet been elucidated. Here, we develop a simple model of metabolic reactions with anabolism-catabolism coupling catalyzed by enzymes. Through application of external oscillation in the enzyme abundances, the thermodynamic efficiency of metabolism was found to be improved. This result is in strong contrast with that observed in the oscillatory input, in which the efficiency always decreased with oscillation. This improvement was effectively achieved by separating the anabolic and catabolic reactions, which tend to disequilibrate each other, and taking advantage of the temporal oscillations so that each of the antagonistic reactions could progress near equilibrium. In this case, anti-phase oscillation between the reaction flux and chemical affinity through oscillation of enzyme abundances is essential. This improvement was also confirmed in a model capable of generating autonomous oscillations in enzyme abundances. Finally, the possible relevance of the improvement in thermodynamic efficiency is discussed with respect to the potential for manipulation of metabolic oscillations in microorganisms.

  4. Bipartite electronic superstructures in the vortex core of Bi2Sr2CaCu2O8+δ

    Science.gov (United States)

    Machida, T.; Kohsaka, Y.; Matsuoka, K.; Iwaya, K.; Hanaguri, T.; Tamegai, T.

    2016-05-01

    The central issue in the physics of cuprate superconductivity is the mutual relationship among superconductivity, pseudogap and broken-spatial-symmetry states. A magnetic field B suppresses superconductivity, providing an opportunity to investigate the competition among these states. Although various B-induced electronic superstructures have been reported, their energy, spatial and momentum-space structures are unclear. Here, we show using spectroscopic-imaging scanning tunnelling microscopy on Bi2Sr2CaCu2O8+δ that there are two distinct B-induced electronic superstructures, both being localized in the vortex core but appearing at different energies. In the low-energy range where the nodal Bogoliubov quasiparticles are well-defined, we observe the so-called vortex checkerboard that we identify as the B-enhanced quasiparticle interference pattern. By contrast, in the high-energy region where the pseudogap develops, the broken-spatial-symmetry patterns that pre-exist at B=0 T is locally enhanced in the vortex core. This evidences the competition between superconductivity and the broken-spatial-symmetry state that is associated with the pseudogap.

  5. Facile hydrothermal synthesis of TiO2-Bi2WO6 hollow superstructures with excellent photocatalysis and recycle properties.

    Science.gov (United States)

    Hou, Ya-Fei; Liu, Shu-Juan; Zhang, Jing-huai; Cheng, Xiao; Wang, You

    2014-01-21

    One-dimensional mesoporous TiO2-Bi2WO6 hollow superstructures are prepared using a hydrothermal method and their photocatalysis and recycle properties are investigated. Experimental results indicate that anatase TiO2 nanoparticles are coupled with hierarchical Bi2WO6 hollow tubes on their surfaces. The TiO2-Bi2WO6 structure has a mesoporous wall and the pores in the wall are on average 21 nm. The hierarchical TiO2-Bi2WO6 heterostructures exhibit the highest photocatalytic activity in comparison with P25, pure Bi2WO6 hollow tube and mechanical mixture of Bi2WO6 tube and TiO2 nanoparticle in the degradation of rhodamine B (RhB) under simulated sunlight irradiation. The as-prepared TiO2-Bi2WO6 heterostructures can be easily recycled through sedimentation and they retains their high photocatalytic activity during the cycling use in the simulated sunlight-driving photodegradation process of RhB. The prepared mesoporous TiO2-Bi2WO6 with hollow superstructure is therefore a promising candidate material for water decontamination use.

  6. Analysis of connection element classes and locations and of some structural requirements for the mounting of different superstructure types on transport vehicles

    Directory of Open Access Journals (Sweden)

    Zoran Đ. Majkić

    2011-04-01

    Full Text Available The paper presents the basic requirements for transport vehicles. A special request regarding the adaptation of transport vehicles for the transport of various types of cargo was taken into consideration. Superstructures and the situation arising after mounting superstructures on wheeled transport vehicles were analyzed and the following was described: console coupling, stirrups, simplex elastic coupling, two-way elastic and rigid connection elements. Vehicle torsional elasticity is provided by a proper choice of the type of connection between the superstructure and the vehicle chassis. Applying the instructions of vehicle manufacturers for using appropriate connections between the truck superstructure and the vehicle chassis provides positive torsional elasticity of the vehicle. The paper gives the general recommendations of the Volvo, Mercedes and Renault transport vehicle producers for the use of particular connection types of locations as well as structural requirements for the mounting of concrete mixers, tippers and truck tanks on their vehicles. Introduction Achieving a high level of transport effectiveness depends on a number of factors. One of the most important ones is the possibility to increase the payload share in the gross vehicle weight. This share depends on the net vehicle weight, a method of coupling the truck superstructure with the chassis frame as well as on the truck superstructure construction. Realization of this requirement is of significant importance, particularly for large business systems since it results in the reduction of number of necessary vehicles, more economic fleet maintenance and the fleet capacity increase. It is also relatively easy to adapt the vehicle for the transportation of other loads, depending on user's current needs. The adaptation is correctly performed if manufacturer's recommendations are followed during the mounting of the superstructure on the chassis. This paper gives the analysis of the

  7. Ag on Ge(111): 2D x-ray structure analysis of the #sq root#3 x #sq root#3 superstructure

    DEFF Research Database (Denmark)

    Dornisch, D.; Moritz, W.; Schulz, H.;

    1992-01-01

    We have studied the Ag/Ge(111) square-root 3 x square-root 3 superstructure by grazing-incidence X-ray diffraction. In our structural analysis we find striking similarities to the geometry of Au on Si(111). The Ag atoms form trimer clusters with an Ag-Ag distance of 2.94 +/- 0.04 angstrom...

  8. [A new virus of rabbit. III. Study on morphological superstructure and antigenicity of rabbit hemorrhagic disease virus (RHDV)].

    Science.gov (United States)

    Zhao, L; Li, T; Song, B; Sun, F

    1992-10-01

    In the spring 1986, an acute infectious disease occurred in Wuhan Second Producing Medical Manufactory, and the rabbit almost died. We tested the mortal symptom and confirmed rabbit Hemorrhagic Disease (RHD) as same as Huang Yinyao report. Hubei Traditional Chinese Medicine Institute appear this RHD also. After we purified virus of above two source by low speed, high speed and sucrose density gradient centrifugation, they can react with antiserum of RHDV from Nanjing Agricultural University in agar gel immunodiffusion tests. These results proved that they belong to the same serotype. Data indicate RHDV have difference morphological superstructure, viral polypeptides and especially RHDV can't react with antiserum of standard Parvovirus of rabbit and so on, so we suggest RHDV is a new virus.

  9. Topotactic epitaxy of SrTiO{sub 3} mesocrystal superstructures with anisotropic construction for efficient overall water splitting

    Energy Technology Data Exchange (ETDEWEB)

    Zhang, Peng; Fujitsuka, Mamoru; Majima, Tetsuro [The Institute of Scientific and Industrial Research (SANKEN), Osaka University (Japan); Ochi, Tomoya [Department of Chemistry, Graduate School of Science, Kobe University (Japan); Kobori, Yasuhiro [Department of Chemistry, Graduate School of Science, Kobe University (Japan); Molecular Photoscience Research Center, Kobe University (Japan); Tachikawa, Takashi [Department of Chemistry, Graduate School of Science, Kobe University (Japan); Molecular Photoscience Research Center, Kobe University (Japan); PRESTO, Science and Technology Agency (JST), Saitama (Japan)

    2017-05-02

    The higher-order structures of semiconductor-based photocatalysts play crucial roles in their physicochemical properties for efficient light-to-energy conversion. A novel perovskite SrTiO{sub 3} mesocrystal superstructure with well-defined orientation of assembled cubic nanocrystals was synthesized by topotactic epitaxy from TiO{sub 2} mesocrystals through a facile hydrothermal treatment. The SrTiO{sub 3} mesocrystal exhibits three times the efficiency for the hydrogen evolution of conventional disordered systems in alkaline aqueous solution. It also exhibits a high quantum yield of 6.7 % at 360 nm in overall water splitting and even good durability up to 1 day. Temporal and spatial spectroscopic observations revealed that the synergy of the efficient electron flow along the internal nanocube network and efficient collection at the larger external cubes produces remarkably long-lived charges for enhanced photocatalysis. (copyright 2017 Wiley-VCH Verlag GmbH and Co. KGaA, Weinheim)

  10. Hierarchical assembly of inorganic nanostructure building blocks to octahedral superstructures-a true template-free self-assembly

    Energy Technology Data Exchange (ETDEWEB)

    Kuchibhatla, Satyanarayana V N T [Advanced Materials Processing and Analysis Center, University of Central Florida, Orlando, FL-32816 (United States); Karakoti, Ajay S [Advanced Materials Processing and Analysis Center, University of Central Florida, Orlando, FL-32816 (United States); Seal, Sudipta [Advanced Materials Processing and Analysis Center, University of Central Florida, Orlando, FL-32816 (United States)

    2007-02-21

    A room temperature, template-free, wet chemical synthesis of ceria nanoparticles and their long term ageing characteristics are reported. High resolution transmission electron microscopy and UV-visible spectroscopy techniques are used to observe the variation in size, structure and oxidation state, respectively as a function of time. The morphology variation and the hierarchical assembly (octahedral superstructure) of nanostructures are imputed to the inherent structural aspects of cerium oxide. It is hypothesized that the 3-5 nm individual building blocks will undergo an intra-agglomerate re-orientation to attain the low energy configuration. This communication also emphasizes the need for long term ageing studies of nanomaterials in various solvents for multiple functionalities.

  11. Ultrasensitive SERS detection of VEGF based on a self-assembled Ag ornamented-AU pyramid superstructure.

    Science.gov (United States)

    Zhao, Sen; Ma, Wei; Xu, Liguang; Wu, Xiaoling; Kuang, Hua; Wang, Libing; Xu, Chuanlai

    2015-06-15

    For the first time, we demonstrated the fabrication of silver nanoparticle ornamented-gold nanoparticle pyramids (Ag-Au Pys) using an aptamer-based self-assembly process and investigated their surface-enhanced Raman scattering (SERS) properties in the detection of vascular endothelial growth factor (VEGF). Under optimized conditions, the SERS signal was negatively related to VEGF concentration over the range 0.01-1.0 fM and the limit of detection (LOD) was as low as 22.6 aM. The matrix effect and the specificity of this developed method were further examined, and the results showed that the superstructure sensor was ultrasensitive and highly selective. This developed aptamer-based SERS detection method suggests that it may be a promising strategy for a variety of sensing applications.

  12. Helical superstructure of continuum graphene cone uncovered by TEM analysis of herringbone-striped pattern in graphitic whiskers

    Science.gov (United States)

    Saito, Yukie; Nishio-Hamane, Daisuke

    2016-10-01

    Cone-shaped graphitic whiskers (CGWs) are a form of pyrolytic carbon, consisting of conically stacked hexagonal carbon layers with an apex angle of ~135-140°. Under transmission electron microscopy (TEM), CGWs often exhibit herringbone-striped patterns. Bright-field (BF) and dark-field (DF) TEM images indicated that the stripes are due to periodical appearance of a strong inter-planar reflection, which is consistent with helical rotation of layers with stepwise "layer overlap". High-resolution TEM revealed that the period was ~14-15 layers. The relationship between apex angle and stripe periodicity of CGWs could be consistently explained in terms of a helical superstructure of tightly coiled continuous graphene cone.

  13. Structures of the ZrZn22 family: suprapolyhedral nanoclusters, methods of self-assembly and superstructural ordering.

    Science.gov (United States)

    Ilyushin, G D; Blatov, V A

    2009-06-01

    A combinatorial topological analysis is carried out by means of the program package TOPOS4.0 [Blatov (2006), IUCr Comput. Commun. Newsl. 7, 4-38] and the matrix self-assembly is modeled for crystal structures of the ZrZn22 family (space group Fd3m, Pearson code cF184), including the compounds with superstructural ordering. A number of strict rules are proposed to model the crystal structures of intermetallics as a network of cluster precursors. According to these rules the self-assembly of the ZrZn22-like structures was considered within the hierarchical scheme: primary polyhedral cluster --> zero-dimensional nanocluster precursor --> one-dimensional primary chain --> two-dimensional microlayer --> three-dimensional microframework (three-dimensional supraprecursor). The suprapolyhedral cluster precursor AB2X37 of diameter approximately 12 A and volume approximately 350 A3 consists of three polyhedra (one AX16 of the 43m point symmetry and two regular icosahedra BX12 of the 3m point symmetry); the packing of the clusters determines the translations in the resulting crystal structure. A novel topological type of the two-dimensional crystal-forming 4,4-coordinated binodal net AB2, with the Schläfli symbols 3636 and 3366 for nodes A and B, is discovered. It is shown that the ZrZn22 superstructures are formed by substituting some atoms in the cluster precursors. Computer analysis of the CRYSTMET and ICSD databases shows that the cluster AB2X37 occurs in 111 intermetallics belonging to 28 structure types.

  14. Hybrid framework with cobalt-chromium alloy and gold cylinder for implant superstructure: Bond strength and corrosion resistance.

    Science.gov (United States)

    Yoshinari, Masao; Uzawa, Shinobu; Komiyama, Yataro

    2016-10-01

    The aim of this in vitro study was to evaluate tensile bond strengths and corrosion resistance of CoCr alloys joined with gold cylinder by a soldering system in comparison with the conventional cast-joining system. CoCr alloys joined with gold cylinder by a soldering system using a high-fusing gold solder (CoCr/Solder/Gold cylinder), gold alloy joined with gold cylinder by a cast joining system (Gold alloy/Gold cylinder) and CoCr castings were fabricated. The tensile bond strength and corrosion resistance in 0.9% NaCl solution (pH 7.4 and pH 2.3) were evaluated. Scanning electron microscopy (SEM) of the fractured surface and electron probe microanalysis (EPMA) of the joined interfaces were also performed. The tensile bond strengths of the CoCr/Solder/Gold cylinder specimens showed similar values as the Gold alloy/Gold cylinder specimens. SEM observation and EPMA analyses suggested firm bonding between the CoCr alloy and gold cylinder. The released elements from the CoCr/Solder/Gold cylinder specimens were similar to ones from CoCr castings. Results showed that superstructures made of CoCr alloys joined with the gold cylinder using a high-fusing gold solder had sufficient bond strength and high corrosion resistance. These hybrid frameworks with cobalt-chromium alloy and gold cylinder are promising prosthesis for implant superstructures with the low cost and favorable mechanical properties instead of conventional high-gold alloys. Copyright © 2016 Japan Prosthodontic Society. Published by Elsevier Ltd. All rights reserved.

  15. Trusted Domain

    DEFF Research Database (Denmark)

    Hjorth, Theis Solberg; Torbensen, Rune

    2012-01-01

    that enables secure end-to-end communication with home automation devices, and it supports device revocations as well as a structure of intersecting sets of nodes for scalability. Devices in the Trusted Domain are registered in a list that is distributed using a robust epidemic protocol optimized...

  16. Domain crossing

    DEFF Research Database (Denmark)

    Schraefel, M. C.; Rouncefield, Mark; Kellogg, Wendy

    2012-01-01

    In CSCW, how much do we need to know about another domain/culture before we observe, intersect and intervene with designs. What optimally would that other culture need to know about us? Is this a “how long is a piece of string” question, or an inquiry where we can consider a variety of contexts a...

  17. Inverting polar domains via electrical pulsing in metallic germanium telluride

    Science.gov (United States)

    Nukala, Pavan; Ren, Mingliang; Agarwal, Rahul; Berger, Jacob; Liu, Gerui; Johnson, A. T. Charlie; Agarwal, Ritesh

    2017-04-01

    Germanium telluride (GeTe) is both polar and metallic, an unusual combination of properties in any material system. The large concentration of free-carriers in GeTe precludes the coupling of external electric field with internal polarization, rendering it ineffective for conventional ferroelectric applications and polarization switching. Here we investigate alternate ways of coupling the polar domains in GeTe to external electrical stimuli through optical second harmonic generation polarimetry and in situ TEM electrical testing on single-crystalline GeTe nanowires. We show that anti-phase boundaries, created from current pulses (heat shocks), invert the polarization of selective domains resulting in reorganization of certain 71o domain boundaries into 109o boundaries. These boundaries subsequently interact and evolve with the partial dislocations, which migrate from domain to domain with the carrier-wind force (electrical current). This work suggests that current pulses and carrier-wind force could be external stimuli for domain engineering in ferroelectrics with significant current leakage.

  18. Inverting polar domains via electrical pulsing in metallic germanium telluride

    Science.gov (United States)

    Nukala, Pavan; Ren, Mingliang; Agarwal, Rahul; Berger, Jacob; Liu, Gerui; Johnson, A. T. Charlie; Agarwal, Ritesh

    2017-01-01

    Germanium telluride (GeTe) is both polar and metallic, an unusual combination of properties in any material system. The large concentration of free-carriers in GeTe precludes the coupling of external electric field with internal polarization, rendering it ineffective for conventional ferroelectric applications and polarization switching. Here we investigate alternate ways of coupling the polar domains in GeTe to external electrical stimuli through optical second harmonic generation polarimetry and in situ TEM electrical testing on single-crystalline GeTe nanowires. We show that anti-phase boundaries, created from current pulses (heat shocks), invert the polarization of selective domains resulting in reorganization of certain 71o domain boundaries into 109o boundaries. These boundaries subsequently interact and evolve with the partial dislocations, which migrate from domain to domain with the carrier-wind force (electrical current). This work suggests that current pulses and carrier-wind force could be external stimuli for domain engineering in ferroelectrics with significant current leakage. PMID:28401949

  19. Direct observation of multiferroic vortex domains in YMnO3.

    Science.gov (United States)

    Zhang, Qinghua; Tan, Guotai; Gu, Lin; Yao, Yuan; Jin, Changqing; Wang, Yanguo; Duan, Xiaofeng; Yu, Richeng

    2013-01-01

    Topological vortices with swirling ferroelectric, magnetic and structural anti-phase relationship in hexagonal RMnO3 (R = Ho to Lu, Y, and Sc) have attracted much attention because of their intriguing behaviors. Herein, we report the structure of multiferroic vortex domains in YMnO3 at atomic scale using state-of-the-art aberration-corrected scanning transmission electron microscopy (STEM). Two types of displacements were identified among six domain walls (DWs); six translation-ferroelectric domains denoted by α+, γ-, β+, α-, γ+ and β-, respectively, were recognized, demonstrating the interlocking nature of the anti-vortex domain. We found that the anti-vortex core is about four unit cells wide. In addition, we reconstructed the vortex model with three swirling pairs of DWs along the [001] direction. These results are very critical for the understanding of topological behaviors and unusual properties of the multiferroic vortex.

  20. TEM and SEM observations of super-structures constructed in organogel systems from a combination of boronic-acid-appended bola-amphiphiles with chiral diols

    Science.gov (United States)

    Koumoto, Kazuya; Yamashita, Tadahiro; Kimura, Taro; Luboradzki, Roman; Shinkai, Seiji

    2001-03-01

    Two bola-amphiphilic α,ω-diboronic acids separated by a (CH2)11 or (CH2)12 group were synthesized. Complexation with chiral diols readily gave new amphiphiles end-capped with the chiral substituents. Some of these acted as good gelators of organic solvents. Transmission electron microscope and scanning electron microscope observations established that a variety of super-structures are created in the organogels, depending on the solvents and the structure of the chiral end-cap groups. In most cases, the fibrous aggregates, the network structure which is the driving-force for gelation, showed a helical higher-order structure reflecting the chirality of the end-cap groups. The results indicate that the combinatorial approach utilizing boronic acid functions and diol compounds is useful in creating a variety of new super-structures in the gel phase.

  1. Optomagnetic Detection of MicroRNA Based on Duplex-Specific Nuclease-Assisted Target Recycling and Multilayer Core-Satellite Magnetic Superstructures

    DEFF Research Database (Denmark)

    Tian, Bo; Ma, Jing; Qiu, Zhen

    2017-01-01

    -efficiency, and potential for bioresponsive multiplexing. Herein, we demonstrate a sensitive and rapid miRNA detection method based on optomagnetic read-out, duplex-specific nuclease (DSN)-assisted target recycling, and the use of multilayer core-satellite magnetic superstructures. Triggered by the presence of target mi......RNA and DSN-assisted target recycling, the core-satellite magnetic superstructures release their "satellites" to the suspension, which subsequently can be quantified accurately in a low-cost and user-friendly optomagnetic setup. Target miRNAs are preserved in the cleaving reaction and can thereby trigger more...... cleavage and release of "satellites". For singleplex detection of let-7b, a linear detection range between 10 fM and 10 nM was observed, and a detection limit of 4.8 fM was obtained within a total assay time of 70 min. Multiplexing was achieved by releasing nanoparticles of different sizes in the presence...

  2. Giant reversible magnetocaloric effect in flower-like β-Co(OH){sub 2} hierarchical superstructures self-assembled by nanosheets

    Energy Technology Data Exchange (ETDEWEB)

    Liu, Xianguo; Feng, Chao; Xiao, Feng; Jin, Chuangui; Xia, Ailin, E-mail: liuxianguohugh@gmail.com, E-mail: eeswor@polyu.edu.hk [Anhui Key Laboratory of Metal Materials and Processing, School of Materials Science and Engineering, Anhui University of Technology, Ma' anshan, PR (China); Or, Siu Wing [Department of Electrical Engineering, The Hong Kong Polytechnic University, Hung Hom, Kowloon (Hong Kong); Sun, Yuping [Center for Engineering Practice and Innovation Education, Anhui University of Technology, Ma' anshan, PR (China)

    2014-01-15

    A facile hydrothermal strategy is proposed to synthesize flower-like β- Co(OH){sub 2} hierarchical microspherical superstructures with a diameter of 0.5-1.5 µm, which are self-assembled by β - Co(OH){sub 2} nano sheets with the average thickness ranging between 20 and 40 nm. The magnetocaloric effect associated with magnetic phase transitions in Co(OH){sub 2} superstructures has been investigated. A sign change in the magnetocaloric effect is induced by a magnetic field, which is related to a filed-induced transition from the antiferromagnetic to the ferromagnetic state below the Néel temperature. The large reversible magnetic-entropy change –ΔS{sub m} (13.4 J/kg K at 15 K for a field change of 5 T) indicates that flower-like Co(OH){sub 2} superstructures is a potential candidate for application in magnetic refrigeration in the low-temperature range. (author)

  3. High-Tc ferromagnetic semiconductor-like behavior and unusual electrical properties in compounds with a 2×2×2 superstructure of the half-Heusler phase.

    Science.gov (United States)

    Xiong, Ding-Bang; Okamoto, Norihiko L; Waki, Takeshi; Zhao, Yufeng; Kishida, Kyosuke; Inui, Haruyuki

    2012-02-27

    Heusler phases, including the full- and half-Heusler families, represent an outstanding class of multifunctional materials on account of their great tunability in compositions, valence electron counts (VEC), and properties. Here we demonstrate a systematic design of a series of new compounds with a 2×2×2 superstructure of the half-Heusler unit cell in X-Y-Z (X=Fe, Ru, Co, Rh, Ir; Y=Zn, Mn; Z=Sn, Sb) systems. Their structures were solved by using both powder and single-crystal X-ray diffraction, and also directly observed by using high-angle annular dark-field imaging in a scanning transmission electron microscope (HAADF-STEM). The VEC values of these new compounds span a wide and continuous range comparable to those for the full- and half-Heusler families, thereby implying tunability in compositions and physical properties in the superstructure. In fact, we observed abnormal electrical properties and a ferromagnetic semiconductor-like behavior with a high and tunable Curie temperature in these superstructures. Copyright © 2012 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

  4. Spatial Separation of Charge Carriers in In2O3-x(OH)y Nanocrystal Superstructures for Enhanced Gas-Phase Photocatalytic Activity.

    Science.gov (United States)

    He, Le; Wood, Thomas E; Wu, Bo; Dong, Yuchan; Hoch, Laura B; Reyes, Laura M; Wang, Di; Kübel, Christian; Qian, Chenxi; Jia, Jia; Liao, Kristine; O'Brien, Paul G; Sandhel, Amit; Loh, Joel Y Y; Szymanski, Paul; Kherani, Nazir P; Sum, Tze Chien; Mims, Charles A; Ozin, Geoffrey A

    2016-05-24

    The development of strategies for increasing the lifetime of photoexcited charge carriers in nanostructured metal oxide semiconductors is important for enhancing their photocatalytic activity. Intensive efforts have been made in tailoring the properties of the nanostructured photocatalysts through different ways, mainly including band-structure engineering, doping, catalyst-support interaction, and loading cocatalysts. In liquid-phase photocatalytic dye degradation and water splitting, it was recently found that nanocrystal superstructure based semiconductors exhibited improved spatial separation of photoexcited charge carriers and enhanced photocatalytic performance. Nevertheless, it remains unknown whether this strategy is applicable in gas-phase photocatalysis. Using porous indium oxide nanorods in catalyzing the reverse water-gas shift reaction as a model system, we demonstrate here that assembling semiconductor nanocrystals into superstructures can also promote gas-phase photocatalytic processes. Transient absorption studies prove that the improved activity is a result of prolonged photoexcited charge carrier lifetimes due to the charge transfer within the nanocrystal network comprising the nanorods. Our study reveals that the spatial charge separation within the nanocrystal networks could also benefit gas-phase photocatalysis and sheds light on the design principles of efficient nanocrystal superstructure based photocatalysts.

  5. Conceptual design and scaled experimental validation of an actively damped carbon tie rods support system for the stabilization of future particle collider superstructures.

    Science.gov (United States)

    Collette, C; Tshilumba, D; Fueyo-Rosa, L; Romanescu, I

    2013-02-01

    This paper presents a simple solution to increase the stability of the large superstructures supporting the final electromagnets of future linear particle collider. It consists of active carbon fiber tie rods, fixed at one end on the structure and at the other end to the detector through active tendons. In the first part of the paper, the solution has been tested on a finite element model of one half of the CLIC_ILD final focus structure. With a reasonable design, it is shown numerically that the compliance can be decreased by at least a factor 4, i.e., that the structure is 4 times more robust to technical noise at low frequency. Two additional features of the active rods are that they can also actively damp the structural resonances and realign the superstructures. The second part of the paper presents a successful experimental validation of the concept, applied to a scaled test bench, especially designed to contain the same modal characteristics as the full scale superstructure.

  6. Neutron diffraction study of the formation of ordered antiphase domains in cubic titanium carbide TiC{sub 0.60}

    Energy Technology Data Exchange (ETDEWEB)

    Khidirov, I., E-mail: khidirov@inp.uz; Parpiev, A. S. [Academy of Sciences of Uzbekistan, Institute of Nuclear Physics (Uzbekistan)

    2013-05-15

    A series of superstructural reflections (described within the sp. gr. Fd3m) are found to be split into three symmetric parts in the neutron powder diffraction pattern of titanium carbide TiC{sub 0.60} annealed at a temperature of 600 Degree-Sign C. No splitting of superstructural reflections is observed in the neutron diffraction pattern of TiC{sub 0.60} annealed at relatively high temperatures (780 Degree-Sign C). This phenomenon can be explained by that fact that the ordering of carbon atoms at relatively high temperatures (780 Degree-Sign C) is accompanied by the formation of randomly oriented rather large antiphase domains (APDs) (450 A). At relatively low temperatures (600 Degree-Sign C), stacking faults arise in the arrangement of partially ordered carbon atoms. In this case, relatively small ordered APDs (290 A) are formed, along with disordered ones.

  7. Using Finite Element and Eigenmode Expansion Methods to Investigate the Periodic and Spectral Characteristic of Superstructure Fiber Bragg Gratings

    Directory of Open Access Journals (Sweden)

    Yue-Jing He

    2016-02-01

    Full Text Available In this study, a numerical simulation method was employed to investigate and analyze superstructure fiber Bragg gratings (SFBGs with five duty cycles (50%, 33.33%, 14.28%, 12.5%, and 10%. This study focuses on demonstrating the relevance between design period and spectral characteristics of SFBGs (in the form of graphics for SFBGs of all duty cycles. Compared with complicated and hard-to-learn conventional coupled-mode theory, the result of the present study may assist beginner and expert designers in understanding the basic application aspects, optical characteristics, and design techniques of SFBGs, thereby indirectly lowering the physical concepts and mathematical skills required for entering the design field. To effectively improve the accuracy of overall computational performance and numerical calculations and to shorten the gap between simulation results and actual production, this study integrated a perfectly matched layer (PML, perfectly reflecting boundary (PRB, object meshing method (OMM, and boundary meshing method (BMM into the finite element method (FEM and eigenmode expansion method (EEM. The integrated method enables designers to easily and flexibly design optical fiber communication systems that conform to the specific spectral characteristic by using the simulation data in this paper, which includes bandwidth, number of channels, and band gap size.

  8. Improved charge transport and injection in a meso-superstructured solar cell by a tractable pre-spin-coating process.

    Science.gov (United States)

    Li, Nan; Li, Haoyuan; Li, Yu; Wang, Shufeng; Wang, Liduo

    2015-10-07

    In meso-superstructured solar cells (MSSCs), the state-of-the-art perovskite acts as both the light harvester and electron transporter due to its ambipolar properties. The inefficient pore filling and infiltration of perovskite directly affect the continuous distribution of perovskite in mesoporous Al2O3, resulting in discontinuous carrier transport in the mesoporous structure and insufficient electron injection to the compact TiO2 layer. Herein, we introduce a simple pre-spin-coating process to improve the infiltration and pore filling of perovskite, which results in higher light absorption and enhanced electron injection, as seen in UV-vis spectra and photoluminescence (PL) spectra, respectively. We first apply time of flight (TOF) experiments to characterize charge transport in MSSCs, and the results reveal that more continuous charge transport pathways are formed with the pre-spin-coating process. This effective method, with ease of processing, demonstrates obviously improved photocurrents, reaching an efficiency as high as 14%, and promotes the application of lead halide perovskite materials in the photovoltaics field.

  9. Proposal for the award of an industrial services contract for civil engineering superstructure and internal construction building work

    CERN Document Server

    2001-01-01

    This document concerns the award of an Industrial Services contract for civil engineering superstructure and internal construction building work. Following a market survey carried out among 112 firms in fifteen Member States, a call for tenders (IT-2546/ST/Rev.) was sent on 12 April 2001 to eleven consortia, four consisting of four firms, three consisting of three firms and four consisting of two firms, in seven Member States. By the closing date, CERN had received tenders from eight consortia in six Member States. The Finance Committee is invited to agree to the negotiation of a contract with the consortium SPIE CITRA SUD-EST(FR)-ANTIRUST TECHNOLOGY (GR), the lowest bidder, for an initial period of three years from 1 January 2002 for an amount not exceeding 15 375 000 Swiss francs, not subject to revision. The contract will include options for two one-year extensions beyond the initial three-year period. The consortium has indicated the following distribution by country of the contract value covered by this ...

  10. Yb{sub 6}Ir{sub 5}Ga{sub 7} - a MgZn{sub 2} superstructure

    Energy Technology Data Exchange (ETDEWEB)

    Seidel, Stefan; Poettgen, Rainer [Institut fuer Anorganische und Analytische Chemie, Universitaet Muenster, Corrensstrasse 30, 48149, Muenster (Germany)

    2017-02-15

    The gallide Yb{sub 6}Ir{sub 5}Ga{sub 7} was synthesized by high-frequency melting of the elements in a sealed niobium ampoule. The structure was refined from single-crystal X-ray diffractometer data: Nb{sub 6.4}Ir{sub 4}Al{sub 7.6} type, P6{sub 3}/mcm, a = 930.4(1), c = 843.0(1) pm, wR{sub 2} = 0.0597, 379 F{sup 2} values and 22 variables. Yb{sub 6}Ir{sub 5}Ga{sub 7} adopts a superstructure of the MgZn{sub 2} Laves phase by a complete ordering of the iridium and gallium atoms on the zinc substructure, i.e. the network consists of ordered and condensed Ir{sub 3}Ga and IrGa{sub 3} tetrahedra with Ir-Ga distances ranging from 260 to 265 pm. The crystal chemical details and the underlying group-subgroup scheme are discussed. (copyright 2017 WILEY-VCH Verlag GmbH and Co. KGaA, Weinheim)

  11. A LEED study of NO superstructures on the Pd(111) surface.

    Science.gov (United States)

    Kostelník, Petr; Sikola, Tomáš; Varga, Peter; Schmid, Michael

    2009-04-01

    We have examined two adsorption structures of NO on the Pd(111) surface and the transformation between them. Low-energy electron diffraction (LEED) I(V) curves of the Pd(111)-p(2 × 2)-NO and Pd(111)-c(4 × 2)-NO surface structures were acquired and analyzed using tensor LEED. Our structural models confirm a previous study by scanning tunneling microscopy and DFT (Hansen et al 2002 Surf. Sci. 496 1). In the c(4 × 2)-NO structure, which forms at an NO coverage of 0.5 monolayers (ML), the NO molecules occupy fcc and hcp hollow sites and are almost upright with only slight tilting, possibly related to NO-NO repulsion. In the p(2 × 2)-NO structure (0.75 ML), with two NO molecules in hollow sites and one in an on-top site, we find strong tilting of the on-top molecule. Upon heating, thermal desorption of NO leads to a transition from the p(2 × 2) to the c(4 × 2) structure, which leads to splitting of the diffraction spots and/or streaky spots. The transition is discussed in terms of domain walls.

  12. Adsorbate-induced facetting reconstruction and self-organized domain patterning of vicinal Ag(111) surfaces; Adsorbatinduzierte richtungsabhaengige Facettierung und selbstorganisierte Domaenen-Musterbildung auf vizinalen Ag(111)-Oberflaechen

    Energy Technology Data Exchange (ETDEWEB)

    Schmitt, Stefan

    2007-02-05

    This thesis investigates structural aspects of adsorbate-induced facetting of vicinal Ag(111) surfaces. It is mainly based on scanning tunneling microscope (STM) and low energy electron diffraction (LEED) experiments performed under UHV conditions. The planar dye-molecule perylene-3,4,9,10-tetracarboxilicacid-dianhydride (PTCDA) adsorbs preferentially at the step edges of the 8.5 Ag(111) vicinal surfaces used in the experiments. It causes a facetting reconstruction by the formation of (111) terraces and facets with a high step density. Moreover, two distinct preferential inclinations of facets were observed, which can only be explained by the selective influence of the adsorbate superstructure. In terms of thermodynamics, the facetting reconstruction can be described as an orientational phase separation, adapted to the constraints of planar surfaces. This concept is capable of explaining the local facetting phenomena. The formalism used predicts an important role of nucleation kinetics. This aspect is taken into account by introducing an additional phase of mobile molecules (2D molecular gas), which cannot be measured directly. Furthermore, strong arguments for the appearance of a critical island size for the PTCDA/ Ag(111) superstructure were found. This work presents structural information of all stable superstructures of PTCDA on vicinal Ag(111) surfaces. Altogether 16 such superstructures were found, 3 of which had been observed and published before. Density and commensurability were found to systematically depend on the step-structure. The two preferred inclinations of facets are related to two characteristic types of domain boundaries of the herringbone superstructure to the adjacent (111)-terrace. On the (111) terraces, small islands of metastable superstructures were found. Facets and (111) terraces form a regular grating-like domain pattern with a variable structural width of 5 to 75 nm. STM measurements show direct evidence for a long-range interaction

  13. .Gov Domains API

    Data.gov (United States)

    General Services Administration — This dataset offers the list of all .gov domains, including state, local, and tribal .gov domains. It does not include .mil domains, or other federal domains outside...

  14. On the Influence of Superstructures and Deckhouses upon Longitudinal Strength%上层建筑(甲板室)参与总纵强度程度分析

    Institute of Scientific and Technical Information of China (English)

    郭际; 肖渤舰

    2014-01-01

    具有发达上层建筑的大型豪华游轮已经成为当前游轮的发展趋势,而关于其上层建筑参与总纵弯曲的程度并未得到系统研究。文中结合有限元方法就这一问题进行探讨,定量分析上层建筑层数、开口尺寸及侧壁距舷侧距离等因素对上层建筑参与总纵弯曲的影响。%Cruise ship with multiple floor superstructures has become more and more popular .However , the longitudinal strength of superstructures has not been well studied .In this paper , the number of superstructures , hole size and the distance be-tween superstructure side and ship side which may have influence on the longitudinal strength of superstructures were studied by finite element method .

  15. Yttrium and hydrogen superstructure and correlation of lattice expansion and proton conductivity in the BaZr0.9Y0.1O2.95 proton conductor

    Science.gov (United States)

    Braun, A.; Ovalle, A.; Pomjakushin, V.; Cervellino, A.; Erat, S.; Stolte, W. C.; Graule, T.

    2009-11-01

    Bragg reflections in Y-resonant x-ray diffractograms of BaZr0.9Y0.1O2.95 (BZY10) reveal that Y is organized in a superstructure. Comparison with neutron diffraction superstructure reflections in protonated/deuterated BZY10 suggests that both superstructures are linked, and that protons move in the landscape imposed by the Y. The thermal lattice expansion decreases abruptly for protonated BZY10 at T ≥648±20 K, coinciding with the onset of lateral proton diffusion and suggesting a correlation of structural changes and proton conductivity. The chemical shift in the Y L1-shell x-ray absorption spectra reveals a reduction from Y3+ toward Y2+ upon protonation.

  16. Investigation of the incommensurate and commensurate magnetic superstructures of LiCuVO4 and CuO on the basis of the isotropic spin exchange and classical spin approximations.

    Science.gov (United States)

    Dai, D; Koo, H-J; Whangbo, M-H

    2004-06-28

    The spin lattices of magnetic oxides LiCuVO(4) and CuO are made up of CuO(2) ribbon chains. The incommensurate and commensurate magnetic superstructures of these oxides were examined by calculating the total spin exchange interaction energies of their long-range order spin arrangements on the basis of the isotropic spin exchange and classical spin approximations. The incommensurate superstructure (0, 0.532, 0) of LiCuVO(4) was analyzed to find that the next-nearest-neighbor spin exchange interaction J(nnn) is more strongly antiferromagnetic than the nearest-neighbor spin exchange interaction J(nn) in the CuO(2) chains. With this finding, we reassessed the relative strengths of the spin exchange interactions of LiCuVO(4) and CuO and then analyzed the relative energies of their long-range order spin arrangements. The incommensurate superstructure (0, 0.532, 0) of LiCuVO(4) is explained when the J(nn)/J(nnn) ratio is -0.40. Both the incommensurate superstructure (0.506, 0, -0.483) and the commensurate superstructure (0.5, 0, -0.5) of CuO, which occur at 231 and 212.5 K, respectively, are well explained in terms of the calculated total spin exchange interaction energies. The incommensurate superstructure of CuO becomes commensurate by a slight change in one interchain spin exchange interaction, which is due probably to a slight structure change brought about by the temperature lowering.

  17. Spiral Patterning of Au Nanoparticles on Au Nanorod Surface to Form Chiral AuNR@AuNP Helical Superstructures Templated by DNA Origami.

    Science.gov (United States)

    Shen, Chenqi; Lan, Xiang; Zhu, Chenggan; Zhang, Wei; Wang, Leyu; Wang, Qiangbin

    2017-02-20

    Plasmonic motifs with precise surface recognition sites are crucial for assembling defined nanostructures with novel functionalities and properties. In this work, a unique and effective strategy is successfully developed to pattern DNA recognition sites in a helical arrangement around a gold nanorod (AuNR), and a new set of heterogeneous AuNR@AuNP plasmonic helices is fabricated by attaching complementary-DNA-modified gold nanoparticles (AuNPs) to the predesigned sites on the AuNR surface. AuNR is first assembled to one side of a bifacial rectangular DNA origami, where eight groups of capture strands are selectively patterned on the other side. The subsequently added link strands make the rectangular DNA origami roll up around the AuNR into a tubular shape, therefore giving birth to a chiral patterning of DNA recognition sites on the surface of AuNR. Following the hybridization with the AuNPs capped with the complementary strands to the capture strands on the DNA origami, left-handed and right-handed AuNR@AuNP helical superstructures are precisely formed by tuning the pattern of the recognition sites on the AuNR surface. Our strategy of nanoparticle surface patterning innovatively realizes hierarchical self-assembly of plasmonic superstructures with tunable chiroptical responses, and will certainly broaden the horizon of bottom-up construction of other functional nanoarchitectures with growing complexity.

  18. Controllable synthesis of 3D BiVO₄ superstructures with visible-light-induced photocatalytic oxidation of NO in the gas phase and mechanistic analysis.

    Science.gov (United States)

    Ou, Man; Nie, Haoyu; Zhong, Qin; Zhang, Shule; Zhong, Lei

    2015-11-21

    A surfactant-free solvothermal method was developed for the controlled synthesis of diverse 3D ms-BiVO4 superstructures, including a flower, a double-layer half-open flower and a hollow tube with square cross-sections, via facilely adjusting the pH values with the aid of NH3·H2O. The effects of the morphologies of the prepared 3D ms-BiVO4 superstructure on the photocatalytic oxidation of NO were investigated, indicating that the enhanced photoactivity was not related to the surface area, but associated with the unique morphology, surface structure and good crystallinity. Moreover, the flower-like ms-BiVO4 photocatalyst with a more (040) reactive crystal plane exhibited higher photoactivity than those of other samples. The unique morphology helped with flushing the oxidation products accumulated on the surface of photocatalysts in the H2O2 system, and further improved the photoactivity. A trapping experiment was also conducted to examine the effects of the active species involved in the PCO of NO intuitively.

  19. Contribution of TEMPO-Oxidized Cellulose Gel in the Formation of Flower-Like Zinc Oxide Superstructures: Characterization of the TOCgel/ZnO Composite Films

    Directory of Open Access Journals (Sweden)

    Khalil Jradi

    2015-11-01

    Full Text Available In the present paper, we report on a simple and new approach for the synthesis of hierarchical flower-like zinc oxide superstructures ZnO (FL in the presence of the TEMPO-oxidized cellulose gel (TOCgel through a room temperature sol-gel process in aqueous medium. Resulting composite films based on TOCgel and ZnO were investigated by several techniques including scanning electron microscopy (SEM, Fourier transform infrared spectroscopy (FTIR, X-ray photoelectron spectroscopy (XPS, thermogravimetric analysis (TGA and mechanical tests. SEM images demonstrated the formation of well-shaped flower-like ZnO superstructures within the fibrous structure of the TOCgel with a uniform diameter (~5 μm. FTIR and XPS results clearly confirmed the formation of such ZnO structures. We suggested that the carboxylate groups of TOCgel fibers act as capping agents and promote the construction of such flower-like ZnO via a nucleation-growth process. A proposed mechanism based on the oriented attachment-driven growth was discussed in order to explain the formation of ZnO (FL. The photocatalytic activity of the TOCgel/ZnO composite in the degradation of methylene blue (MB under UV irradiation was clearly confirmed. Finally, mechanical tests demonstrated that the former TOCgel/ZnO film maintained a good flexibility (bent up to ~120° without losing its photocatalytic activity.

  20. Protein domain prediction

    NARCIS (Netherlands)

    Ingolfsson, Helgi; Yona, Golan

    2008-01-01

    Domains are considered to be the building blocks of protein structures. A protein can contain a single domain or multiple domains, each one typically associated with a specific function. The combination of domains determines the function of the protein, its subcellular localization and the interacti

  1. Membrane binding domains

    OpenAIRE

    Hurley, James H.

    2006-01-01

    Eukaryotic signaling and trafficking proteins are rich in modular domains that bind cell membranes. These binding events are tightly regulated in space and time. The structural, biochemical, and biophysical mechanisms for targeting have been worked out for many families of membrane binding domains. This review takes a comparative view of seven major classes of membrane binding domains, the C1, C2, PH, FYVE, PX, ENTH, and BAR domains. These domains use a combination of specific headgroup inter...

  2. Quantitative analysis of defects and domain boundaries in mesoporous SBA-16 films.

    Science.gov (United States)

    Wang, R H; Chen, Q; Chen, F R; Kai, J J; Peng, L-M

    2007-01-01

    Some quantitative structural analyses on defects and domain boundaries observed in SBA-16 films were performed using the lattice concept and geometric phase method. These analyses show that there exist low angle, high angle and translational anti-phase domain boundaries in SBA-16 films. While some of the domain boundaries bear analogue to those found in normal solid crystals, others are similar to that found in the liquid crystals. In particular near Sigma11 and Sigma13b high angle boundaries were observed. On the one hand the Sigma11 boundaries were found to exist with or without steps (ledge) associated with them depending on whether or not the boundary plane is parallel to the densely packed lattice plane. On the other hand segments of the boundary plane in the Sigma13b boundary were found being always associated with densely packed lattice plane, with the {011} type of lattice plane in one domain being parallel to the {112} type of plane in the other domain. The translational domain boundary was observed to have a translation vector having a projected component of (1/2) on the (111) plane. The bending deformation similar to that found in the nematics liquid crystal was also observed and quantitatively analyzed using the geometric phase method, and rotational field associated with the deformation was identified.

  3. Synthesis and Characterization of Featherlike Hierarchical Fe-Co Alloy Superstructures%羽状Fe-Co合金分级结构粒子的合成与表征

    Institute of Scientific and Technical Information of China (English)

    王维; 阳振军

    2016-01-01

    Featherlike hierarchical Fe-Co alloy superstructures are synthesized by using FeCl3 ·6H2 O as the source of iron and sodium citrate as shape-controlling agent. The morphology and composition of the samples are characterized by SEM, EDX and XRD etc. It is have been found that sodium citrate play a key role in forming hierarchical superstructures,the formation mechanism of featherlike superstructures could be ascribed to Diffusion-Limited Aggregation ( DLA) theory: The previous nanocrystals tend to join each other along with direction of the crystal plane without adsorbed sodium citrate and then to form intermediate superstruc-tures, and well-development featherlike superstructures are generated after further growth under the action of Ostwald ripening.%分别以柠檬酸钠和FeCl3·6H2 O为形状控制剂和铁源制备了羽状Fe-Co合金分级结构粒子。用扫描电镜、能谱和X射线衍射对样品的形貌、成分进行了表征分析,并研究了柠檬酸钠用量对产物的影响。结果表明羽状分级结构形成机理可以用扩散限制聚集理论解释,即前期纳米晶核在没有柠檬酸根吸附的晶面上定向聚集形成松散的枝状结构,最后经过奥斯特瓦尔德熟化成羽叶状分级结构。

  4. Role of Ordering Energy in Formation of Grain Structure and Special Boundaries Spectrum in OrderedAlloys with L12 Superstructure

    Institute of Scientific and Technical Information of China (English)

    2000-01-01

    It was revealed that an average energy of special boundaries is proportional to APB energy in the alloys with the L12 superstructure. This fact proves the appearance of the GAPBs in the planes of location of special boundaries in coincidence sites of ordered alloys. It was determined that the more energy of special boundaries in ordered alloys, the more energy of complex stacking fault. There is a correlation between the distribution of special boundaries as a function its relative energy and ordering energy: the more ordering energy, the more degree of washed away of distribution. The correlation between average relative energy of special boundaries and ordering energy was detected: the more ordering energy, the more average energy of special boundaries. The reverse dependence between ordering energy and average number of special boundaries in grains limited by boundaries of general type was discovered.

  5. 抗氧化剂BHT微胶囊化产品超微结构的测定%Study on Superstructure of Microencapsulated Antioxidant BHT

    Institute of Scientific and Technical Information of China (English)

    陈梅香

    2012-01-01

    Scanning electron microscopy (SEM) was applied to study the superstructure of microencapsulated star butylated hydroxytoluene (BHT) manufactured by various preparation techniques. The results showed that preparation techniques had significant effects on the structure of microencapsulated products, and thus affected the qualities of products. The research about superstructure of BHT could provide information for analyses on the quality of microencapsulate products.%用扫描电子显微镜(SEM)研究抗氧化剂二丁基羟基甲苯(BHT)微胶囊化产品的超微结构.观察了喷雾干燥法不同壁材组成和工艺条件下制作的微胶囊化产品的表面结构和内部结构,同时考察了喷雾干燥进风温度对微胶囊化产品膜结构的影响.结果表明,不同壁材组成和工艺条件下制作的微胶囊化产品的超微结构有较大差异,合适的壁材组成和工艺条件有利于提高产品质量,同时喷雾干燥进风温度对微胶囊化产品的结构有很大影响,从而也影响到产品的质量.微胶囊化产品超微结构的研究为分析影响产品质量的因素提供了重要依据.

  6. Three-dimensional surface-enhanced Raman scattering hotspots in spherical colloidal superstructure for identification and detection of drugs in human urine.

    Science.gov (United States)

    Han, Zhenzhen; Liu, Honglin; Wang, Bin; Weng, Shizhuang; Yang, Liangbao; Liu, Jinhuai

    2015-01-01

    Rapid component separation and robust surface-enhanced Raman scattering (SERS) identification of drugs in real human urine remain an attractive challenge because of the sample complexity, low molecular affinity for metal surface, and inefficient use of hotspots in one- or two-dimensional (2D) geometries. Here, we developed a 5 min strategy of cyclohexane (CYH) extraction for separating amphetamines from human urine. Simultaneously, an oil-in-water emulsion method is used to assemble monodisperse Ag nanoparticles in the CYH phase into spherical colloidal superstructures in the aqueous phase. These superstructures create three-dimensional (3D) SERS hotspots which exist between every two adjacent particles in 3D space, break the traditional 2D limitation, and extend the hotspots into the third dimension along the z-axis. In this platform, a conservative estimate of Raman enhancement factor is larger than 10(7), and the same CYH extraction processing results in a high acceptability and enrichment of drug molecules in 3D hotspots which demonstrates excellent stability and reproducibility and is suitable for the quantitative examination of amphetamines in both aqueous and organic phases. Parallel ultraperformance liquid chromatography (UPLC) examinations corroborate an excellent performance of our SERS platform for the quantitative analysis of methamphetamine (MA) in both aqueous solution and real human urine, of which the detection limits reach 1 and 10 ppb, respectively, with tolerable signal-to-noise ratios. Moreover, SERS examinations on different proportions of MA and 3,4-methylenedioxymethamphetamine (MDMA) in human urine demonstrate an excellent capability of multiplex quantification of ultratrace analytes. By virtue of a spectral classification algorithm, we realize the rapid and accurate recognition of weak Raman signals of amphetamines at trace levels and also clearly distinguish various proportions of multiplex components. Our platform for detecting drugs

  7. Influence of temperature on the controlled growth kinetics and superstructural phase formation of indium on a reconstructed Si (113) 3 × 2 surface

    Science.gov (United States)

    Krishna TC, Shibin; Deshmukh, Rahul; Singh Chauhan, Amit Kumar; Goswami, Lalit; Govind

    2014-03-01

    The kinetics of growth, thermal stability and superstructural phase formation of the indium atom on a reconstructed Si (113) 3 × 2 surface at room temperature (RT), as well as at high substrate temperature (HT), is discussed. It was observed that at a very low flux rate of 0.08 ML min-1, In-adsorption at RT follows the Frank-van der Merwe (FM) growth mode, while for HT (>200 °C), In-islands (the Volmer-Weber-growth mode) were formed. The residual thermal desorption (RTD) analysis revealed the anomalous behaviour of temperature-driven layering to the clustering rearrangement of In atoms on the Si (113) surface for RT- and 200 °C-grown systems. The RTD study also demonstrates the effect of temperature on growth kinetics as well as on the multilayer/monolayer desorption pathway. The calculated bilayer desorption energy was found to be different for RT- (T B, 0.48 eV) and HT- (T B, 1.57 eV) grown In/Si(113) systems, while the monolayer desorption energy (T M, 2.56 eV) was the same in both the cases. Various coverage-dependent superstructural phases, such as Si(113) 3 × 2 + 3 × 1, 3 × 1, 3 × 2 + 1 × 3 and 1 × 1, have been observed during the RT- and HT-growth of In on the Si (113) surface. A complete phase diagram of In/Si(113) is deduced which depicts the evolution of novel phases as a function of substrate temperature and coverage.

  8. Domains via Graphs

    Institute of Scientific and Technical Information of China (English)

    ZHANG Guoqiang; CHEN Yixiang

    2001-01-01

    This paper provides a concrete and simple introduction to two pillars of domain theory: (1) solving recursive domain equations, and (2) universal and saturated domains. Our exposition combines Larsen and Winskel's idea on solving domain equations using information systems with Girard's idea of stable domain theory in the form of coherence spaces, or graphs.Detailed constructions are given for universal and even homogeneous objects in two categories of graphs: one representing binary complete, prime algebraic domains with complete primes covering the bottom; the other representing ω-algebraic, prime algebraic lattices. The backand-forth argument in model theory helps to enlighten the constructions.

  9. Domains of laminin

    DEFF Research Database (Denmark)

    Engvall, E; Wewer, U M

    1996-01-01

    Extracellular matrix molecules are often very large and made up of several independent domains, frequently with autonomous activities. Laminin is no exception. A number of globular and rod-like domains can be identified in laminin and its isoforms by sequence analysis as well as by electron...... microscopy. Here we present the structure-function relations in laminins by examination of their individual domains. This approach to viewing laminin is based on recent results from several laboratories. First, some mutations in laminin genes that cause disease have affected single laminin domains, and some...... laminin isoforms lack particular domains. These mutants and isoforms are informative with regard to the activities of the mutated and missing domains. These mutants and isoforms are informative with regard to the activities of the mutated and missing domains. Second, laminin-like domains have now been...

  10. Color theorems, chiral domain topology, and magnetic properties of Fe(x)TaS2.

    Science.gov (United States)

    Horibe, Yoichi; Yang, Junjie; Cho, Yong-Heum; Luo, Xuan; Kim, Sung Baek; Oh, Yoon Seok; Huang, Fei-Ting; Asada, Toshihiro; Tanimura, Makoto; Jeong, Dalyoung; Cheong, Sang-Wook

    2014-06-11

    Common mathematical theories can have profound applications in understanding real materials. The intrinsic connection between aperiodic orders observed in the Fibonacci sequence, Penrose tiling, and quasicrystals is a well-known example. Another example is the self-similarity in fractals and dendrites. From transmission electron microscopy experiments, we found that FexTaS2 crystals with x = 1/4 and 1/3 exhibit complicated antiphase and chiral domain structures related to ordering of intercalated Fe ions with 2a × 2a and √3a × √3a superstructures, respectively. These complex domain patterns are found to be deeply related with the four color theorem, stating that four colors are sufficient to identify the countries on a planar map with proper coloring and its variations for two-step proper coloring. Furthermore, the domain topology is closely relevant to their magnetic properties. Our discovery unveils the importance of understanding the global topology of domain configurations in functional materials.

  11. Preparation and properties of CeTe/sub 2/O/sub 6/ and ThTe/sub 2/O/sub 6/, compounds with a new superstructure of the fluorite type

    Energy Technology Data Exchange (ETDEWEB)

    Botto, I.L.; Baran, E.J. (La Plata Univ. Nacional (Argentina). Facultad de Ciencias Exactas)

    1982-01-01

    It is demonstrated that in the systems MO/sub 2//TeO/sub 2/ (with M = Ce, Th), treated in air and at 600 /sup 0/C, only phases of composition MTe/sub 2/O/sub 6/ are formed. They pertains to the cubic crystal system and constitutes a new type of fluorite-superstructure. Different aspects of its crystal chemistry are commented and also the infrared spectra are recorded and briefly discussed.

  12. Magnetic field directed assembly of superstructures of ferrite-ferroelectric core-shell nanoparticles and studies on magneto-electric interactions

    Energy Technology Data Exchange (ETDEWEB)

    Srinivasan, G., E-mail: srinivas@oakland.edu; Sreenivasulu, G.; Benoit, Crystal [Physics Department, Oakland University, Rochester, Michigan 48309 (United States); Petrov, V. M. [Physics Department, Oakland University, Rochester, Michigan 48309 (United States); Institute of Electronic and Information Systems, Novgorod State University, Veliky Novgorod 173003 (Russian Federation); Chavez, F. [Chemistry Department, Oakland University, Rochester, Michigan 48309 (United States)

    2015-05-07

    Composites of ferromagnetic and ferroelectric are of interest for studies on mechanical strain mediated magneto-electric (ME) interactions and for useful technologies. Here, we report on magnetic-field-assisted-assembly of barium titanate (BTO)-nickel ferrite (NFO) core-shell particles into linear chains and 2D/3D arrays and measurements of ME effects in such assemblies. First, we synthesized the core-shell nano-particles with 50–600 nm BTO and 10–200 nm NFO by chemical self-assembly by coating the ferroic particles with complementary coupling groups and allowing them to self-assemble in the presence of a catalyst via the “click” reaction. The core-shell structure was confirmed with electron microscopy and scanning probe microscopy. We obtained superstructure of the core-shell particles by subjecting them to a magnetic field gradient that exerts an attractive force on the particles and align them toward the regions of high field strengths. At low particle concentration, linear chains were formed and they evolved into 2D and 3D arrays at high particle concentrations. Magnetoelectric characterization on unassembled films and assembled arrays has been performed through measurements of low-frequency ME voltage coefficient (MEVC) by subjecting the sample to a bias magnetic field and an ac magnetic field. The MEVC is higher for field-assembled samples than for unassembled films and is found to be sensitive to field orientation with a higher MEVC for magnetic fields parallel to the array direction than for magnetic fields perpendicular to the array. A maximum MEVC of 20 mV/cm Oe, one of the highest reported for any bulk nanocomposite, is measured across the array thickness. A model is provided for ME coupling in the superstructures of BTO-NFO particulate composites. First, we estimated the MEVC for a free-standing BTO-NFO core-shell particle and then extended the model to include an array of linear chains of the particles. The theoretical estimates are in

  13. Polymorphism of NaVO2F2: a P2₁/c superstructure with pseudosymmetry of P2₁/m in the subcell.

    Science.gov (United States)

    Yu, Zi-Qun; Wang, Jing-Quan; Huang, Ya-Xi; Botis, Sanda M; Pan, Yuanming; Mi, Jin-Xiao

    2015-06-01

    The ADDSYM routine in the program PLATON [Spek (2015). Acta Cryst. C71, 9-18] has helped researchers to avoid structures of (metal-)organic compounds being reported in an unnecessarily low symmetry space group. However, determination of the correct space group may get more complicated in cases of pseudosymmetric inorganic compounds. One example is NaVO2F2, which was reported [Crosnier-Lopez et al. (1994). Eur. J. Solid State Inorg. Chem. 31, 957-965] in the acentric space group P2₁ based on properties but flagged by ADDSYM as (pseudo)centrosymmetric P2₁/m within default distance tolerances. Herein a systematic investigation reveals that NaVO2F2 exists in at least four polymorphs: P2₁, (I), P2₁/m, (II), P2₁/c, (III), and one or more low-temperature ones. The new centrosymmetric modification, (III), with the space group P2₁/c has a similar atomic packing geometry to phase (I), except for having a doubled c axis. The double-cell of phase (III) arises from atomic shifts from the glide plane c at (x, ¼, z). With increasing temperature, the number of observed reflections decreases. The odd l reflections gradually become weaker and, correspondingly, all atoms shift towards the glide plane, resulting in a gradual second-order transformation of (III) into high-temperature phase (II) (P2₁/m) at below 493 K. At least one first-order enantiotropic phase transition was observed below 139 K from both the single-crystal X-ray diffraction and the differential scanning calorimetry analyses. Periodic first-principles calculations within density functional theory show that both P2₁/c superstructure (III) and P2₁ substructure (I) are more stable than P2₁/m structure (II), and that P2₁/c superstructure (III) is more stable that P2₁ substructure (I).

  14. Synthesis, morphology and microstructure of pomegranate-like hematite ({alpha}-Fe{sub 2}O{sub 3}) superstructure with high coercivity

    Energy Technology Data Exchange (ETDEWEB)

    Tadic, Marin, E-mail: marint@vinca.rs [Condensed Matter Physics Laboratory, Vinca Institute, University of Belgrade, P.O. Box 522, 11001 Belgrade (Serbia); Citakovic, Nada [Military Academy, Generala Pavla Jurisica Sturma 33, University of Belgrade, 11000 Belgrade (Serbia); Panjan, Matjaz [Jozef Stefan Institute, Jamova 39, 1000 Ljubljana (Slovenia); Stanojevic, Boban [Vinca Institute of Nuclear Sciences, P.O. Box 522, 11001 Belgrade, University of Belgrade (Serbia); Markovic, Dragana [Condensed Matter Physics Laboratory, Vinca Institute, University of Belgrade, P.O. Box 522, 11001 Belgrade (Serbia); Jovanovic, Dorde [Center for Solid State Physics and New Materials, Institute of Physics, University of Belgrade, Pregrevica 118, 11080 Belgrade (Serbia); Spasojevic, Vojislav [Condensed Matter Physics Laboratory, Vinca Institute, University of Belgrade, P.O. Box 522, 11001 Belgrade (Serbia)

    2012-12-05

    Highlights: Black-Right-Pointing-Pointer We found superior magnetic properties of the hematite ({alpha}-Fe{sub 2}O{sub 3}). Black-Right-Pointing-Pointer TEM and HRTEM images show a pomegranate-like superstructure. Black-Right-Pointing-Pointer Magnetic measurements display high coercivity H{sub C} = 4350 Oe at the room temperature. - Abstract: We found novel and superior magnetic properties of the hematite ({alpha}-Fe{sub 2}O{sub 3}) that originate from an internal microstructure of particles and strong inter-particle interactions between nanocrystal sub-units. The hematite particles were synthesized by thermal decomposition of iron (III) nitrate without any template or surfactant. The purity, size, crystallinity, morphology, microstructure and magnetic features of the as-prepared particles were characterized by X-ray diffraction (XRD), scanning electron microscope (SEM), energy-dispersive X-ray spectroscopy (EDX), transmission electron microscopy (TEM), high resolution transmission electron microscopy (HRTEM), Raman spectroscopy (RS) and SQUID magnetometry. An XRD study reveals a pure phase of {alpha}-Fe{sub 2}O{sub 3} whereas TEM shows {alpha}-Fe{sub 2}O{sub 3} spheres with a diameter of about 150 nm. RS also shows high quality and purity of the sample. Moreover, TEM and HRTEM images show a pomegranate-like superstructure and evidence that the spherical particles are composed of individual well-crystallized nanoparticle sub-units (self-assembled nanoparticles) with a size of about 20 nm. Magnetic measurements display hysteretic behavior at the room temperature with remanent magnetization M{sub r} = 0.731 emu/g, saturation magnetization M{sub S} = 6.83 emu/g and coercivity H{sub C} = 4350 Oe, as well as the Morin transition at T{sub M} = 261 K. These results and comparison with those in the literature reveal that the sample has extremely high coercivity. The magnetic properties of the sample are discussed in relation to morphology, internal microstructure, surface

  15. Translation domains in multiferroics

    OpenAIRE

    Meier, D; Leo, N; Jungk, T.; Soergel, E.; Becker, P.; Bohaty, L.; Fiebig, M.

    2010-01-01

    Translation domains differing in the phase but not in the orientation of the corresponding order parameter are resolved in two types of multiferroics. Hexagonal (h-) YMnO$_3$ is a split-order-parameter multiferroic in which commensurate ferroelectric translation domains are resolved by piezoresponse force microscopy whereas MnWO$_4$ is a joint-order-parameter multiferroic in which incommensurate magnetic translation domains are observed by optical second harmonic generation. The pronounced ma...

  16. Frustratingly Easy Domain Adaptation

    CERN Document Server

    Daumé, Hal

    2009-01-01

    We describe an approach to domain adaptation that is appropriate exactly in the case when one has enough ``target'' data to do slightly better than just using only ``source'' data. Our approach is incredibly simple, easy to implement as a preprocessing step (10 lines of Perl!) and outperforms state-of-the-art approaches on a range of datasets. Moreover, it is trivially extended to a multi-domain adaptation problem, where one has data from a variety of different domains.

  17. Staggered domain wall fermions

    CERN Document Server

    Hoelbling, Christian

    2016-01-01

    We construct domain wall fermions with a staggered kernel and investigate their spectral and chiral properties numerically in the Schwinger model. In some relevant cases we see an improvement of chirality by more than an order of magnitude as compared to usual domain wall fermions. Moreover, we present first results for four-dimensional quantum chromodynamics, where we also observe significant reductions of chiral symmetry violations for staggered domain wall fermions.

  18. Pragmatic circuits frequency domain

    CERN Document Server

    Eccles, William

    2006-01-01

    Pragmatic Circuits: Frequency Domain goes through the Laplace transform to get from the time domain to topics that include the s-plane, Bode diagrams, and the sinusoidal steady state. This second of three volumes ends with a-c power, which, although it is just a special case of the sinusoidal steady state, is an important topic with unique techniques and terminology. Pragmatic Circuits: Frequency Domain is focused on the frequency domain. In other words, time will no longer be the independent variable in our analysis. The two other volumes in the Pragmatic Circuits series include titles on DC

  19. Visualizing domain wall and reverse domain superconductivity.

    Science.gov (United States)

    Iavarone, M; Moore, S A; Fedor, J; Ciocys, S T; Karapetrov, G; Pearson, J; Novosad, V; Bader, S D

    2014-08-28

    In magnetically coupled, planar ferromagnet-superconductor (F/S) hybrid structures, magnetic domain walls can be used to spatially confine the superconductivity. In contrast to a superconductor in a uniform applied magnetic field, the nucleation of the superconducting order parameter in F/S structures is governed by the inhomogeneous magnetic field distribution. The interplay between the superconductivity localized at the domain walls and far from the walls leads to effects such as re-entrant superconductivity and reverse domain superconductivity with the critical temperature depending upon the location. Here we use scanning tunnelling spectroscopy to directly image the nucleation of superconductivity at the domain wall in F/S structures realized with Co-Pd multilayers and Pb thin films. Our results demonstrate that such F/S structures are attractive model systems that offer the possibility to control the strength and the location of the superconducting nucleus by applying an external magnetic field, potentially useful to guide vortices for computing application.

  20. On the crystal structure of Cr2N precipitates in high-nitrogen austenitic stainless steel. III. Neutron diffraction study on the ordered Cr2N superstructure.

    Science.gov (United States)

    Lee, Tae-Ho; Kim, Sung-Joon; Shin, Eunjoo; Takaki, Setsuo

    2006-12-01

    The ordered structure of Cr(2)N precipitates in high-nitrogen austenitic steel was investigated utilizing high-resolution neutron powder diffractometry (HRPD). On the basis of the Rietveld refinement of neutron diffraction patterns, the ordered Cr2N superstructure was confirmed to be trigonal (space group P31m), with lattice parameters a=4.800 (4) and c=4.472 (5) A, as suggested in previous transmission electron microscopy studies [Lee, Oh, Han, Lee, Kim & Takaki (2005). Acta Cryst. B61, 137-144; Lee, Kim & Takaki (2006). Acta Cryst. B62, 190-196]. The occupancies of the N atoms in four crystallographic sites [1(a), 1(b), 2(d) and 2(c) Wyckoff sites] were determined to be 1.00 (5), 0.0, 0.74 (9) and 0.12 (3), respectively, reflecting a partial disordering of N atoms along the c axis. The position of the metal atom was specified to be x=0.346 (8) and z=0.244 (6), corresponding to a deviation from the ideal position (x=0.333 and z=0.250). This deviation caused the ((1/3 1/3)(0))-type superlattice reflection to appear. A comparison between the ideal and measured crystal structures of Cr2N was performed using a computer simulation of selected-area diffraction patterns.

  1. The Triple Salt Sr14[Ta4N13][TaN4]O-A Nitridotantalate Oxide with 19-fold Rock Salt Superstructure.

    Science.gov (United States)

    Wörsching, Matthias; Daiger, Martin; Hoch, Constantin

    2017-02-21

    A new structure motif in nitridometalate chemistry is the tetracatena-nitridotantalate anion [Ta4N13](19-). It occurs in the crystal structure of the triple salt Sr14[Ta4N13][TaN4]O (monoclinic, space group P21/c with a = 15.062(2) Å, b = 7.2484(6) Å, c = 24.266(3) Å, and β = 97.280(10)(o)) together with ortho-tantalate and isolated oxide anions. Synthesis followed a new approach with employment of Sr surplus and reductive conditions aimed at the preparation of subvalent compounds. The new structure type was established on the basis of single-crystal X-ray diffraction data and also Rietveld refinement. It is a complex superstructure of the rock salt structure type with Ta and Sr atoms forming the face-centered cubic packing and N and O atoms occupying 18/19 of the octahedral voids. We discuss structure and stability of the triple salt with respect to other known nitridometalates and the use of this triple salt for preparative access toward new metal-rich compounds in this field.

  2. The enterprise engineering domain

    CSIR Research Space (South Africa)

    De Vries, M

    2015-06-01

    Full Text Available representation of the EE domain within the emerging EE discipline. We used a questionnaire to gather the views of EE and enterprise architecture (EA) researchers and practitioners on the EE domain. The main contributions of this article include: (1...

  3. Domain wall filters

    CERN Document Server

    Bär, O; Neuberger, H; Witzel, O; Baer, Oliver; Narayanan, Rajamani; Neuberger, Herbert; Witzel, Oliver

    2007-01-01

    We propose using the extra dimension separating the domain walls carrying lattice quarks of opposite handedness to gradually filter out the ultraviolet fluctuations of the gauge fields that are felt by the fermionic excitations living in the bulk. This generalization of the homogeneous domain wall construction has some theoretical features that seem nontrivial.

  4. Domain Walls on Singularities

    CERN Document Server

    Halyo, Edi

    2009-01-01

    We describe domain walls that live on $A_2$ and $A_3$ singularities. The walls are BPS if the singularity is resolved and non--BPS if it is deformed and fibered. We show that these domain walls may interpolate between vacua that support monopoles and/or vortices.

  5. Domains of Learning.

    Science.gov (United States)

    Gagne, Robert M.

    In planning educational research, recognition needs to be made of five domains of learning: (1) motor skills, (2) verbal information, (3) intellectual skills, (4) cognitive strategies, and (5) attitudes. In being cognizant of these domains, the researcher is able to distinguish the parts of a content area which are subject to different…

  6. A Domain Analysis Bibliography

    Science.gov (United States)

    1990-06-01

    Bauhaus , a prototype CASE workstation for D-SAPS development. [ARAN88A] Guillermo F. Arango. Domain Engineering for Software Reuse. PhD thesis...34 VITA90B: Domain Analysis within the ISEC Rapid Center 48 CMU/SEI-90-SR-3 Appendix III Alphabetical by Organization/Project BAUHAUS * ALLE87A

  7. Controlling superstructural ordering in the clathrate-I Ba 8 M 16 P 30 (M = Cu, Zn) through the formation of metal–metal bonds

    Energy Technology Data Exchange (ETDEWEB)

    Dolyniuk, J.; Whitfield, P. S.; Lee, K.; Lebedev, O. I.; Kovnir, K.

    2017-01-01

    Order–disorder–order phase transitions in the clathrate-I Ba8Cu16P30 were induced and controlled by aliovalent substitutions of Zn into the framework. Unaltered Ba8Cu16P30 crystallizes in an ordered orthorhombic (Pbcn) clathrate-I superstructure that maintains complete segregation of metal and phosphorus atoms over 23 different crystallographic positions in the clathrate framework. The driving force for the formation of this Pbcn superstructure is the avoidance of Cu–Cu bonds. This superstructure is preserved upon aliovalent substitution of Zn for Cu in Ba8Cu16-xZnxP30 with 0 < x < 1.6 (10% Zn/Mtotal), but vanishes at greater substitution concentrations. Higher Zn concentrations (up to 35% Zn/Mtotal) resulted in the additional substitution of Zn for P in Ba8M16+yP30-y (M = Cu, Zn) with 0 ≤ y ≤ 1. This causes the formation of Cu–Zn bonds in the framework, leading to a collapse of the orthorhombic superstructure into the more common cubic subcell of clathrate-I (Pm[3 with combining macron]n). In the resulting cubic phases, each clathrate framework position is jointly occupied by three different elements: Cu, Zn, and P. Detailed structural characterization of the Ba–Cu–Zn–P clathrates-I via single crystal X-ray diffraction, joint synchrotron X-ray and neutron powder diffractions, pair distribution function analysis, electron diffraction and high-resolution electron microscopy, along with elemental analysis, indicates that local ordering is present in the cubic clathrate framework, suggesting the evolution of Cu–Zn bonds. For the compounds with the highest Zn content, a disorder–order transformation is detected due to the formation of another superstructure with trigonal symmetry and Cu–Zn bonds in the clathrate-I framework. It is shown that small changes in the composition, synthesis, and crystal structure have significant impacts on the structural and transport properties of Zn-substituted Ba8Cu16P30.

  8. Domain-Specific Multimodeling

    DEFF Research Database (Denmark)

    Hessellund, Anders

    Enterprise systems are complex artifacts. They are hard to build, manage, understand, and evolve. Existing software development paradigms fail to properly address challenges such as system size, domain complexity, and software evolution when development is scaled to enterprise systems. We propose...... domain-specific multimodeling as a development paradigm to tackle these challenges in a language-oriented manner. The different concerns of a system are conceptually separated and made explicit as independent domain-specific languages. This approach increases productivity and quality by raising...... the overall level of abstraction. It does, however, also introduce a new problem of coordinating multiple different languages in a single system. We call this problem the coordination problem. In this thesis, we present the coordination method for domain-specific multimodeling that explicitly targets...

  9. Conserved Domain Database (CDD)

    Data.gov (United States)

    U.S. Department of Health & Human Services — CDD is a protein annotation resource that consists of a collection of well-annotated multiple sequence alignment models for ancient domains and full-length proteins.

  10. 上海城市交通政策的顶层设计思考%Superstructure Design for Shanghai's Urban Transport Policy

    Institute of Scientific and Technical Information of China (English)

    潘海啸

    2012-01-01

    首先分析了城市交通与城市发展及可持续发展的关系,指出包括城市规划和城市交通规划内的城市管理能力是实现人们享受较高的城市交通方便性(城市机动性的提高),同时避免城市交通的外部性及对城市环境和全球气候环境的影响的重要因素.正是由于有比较明确的城市交通政策导向,面临城市快速经济发展和城市面积的扩展,与国内一些曾经希望适应小汽车发展的城市相比,上海城市交通状况和城市环境质量具有明显的优势.为此,对上海的城市交通政策的作用进行了系统的分析,指出在新的发展形势下一些曾经十分有效的政策其作用正在降低,人们必须对上海城市交通政策的顶层设计进行调整,将上海建设成为世界绿色城市交通之都.%The paper analyzes the fundamental relationship between urban transport and sustainable urban development in China' s fast urbanizing context. It points to the importance of urban management capacity to ensure people' s enjoyment of convenience and mobility without exerting negative externalities on physical environment, public health and global climate change. It is evident that urban planning and urban comprehensive transport management is the key components of urban management capacity. Compared with other mega cities in China such as Beijing, Guangzhou and Shenzhen, the performance of Shanghai' s urban transport system is superior in terms of quality of service and environmental impacts. This was achieved because Shanghai has maintained a clear urban transport policy orientation for more than 20 years, given the rapid economic development, fast urban expansion and continued rise in personal incomes. There has been consensus among all stakeholders involved in urban transport planning, management and infrastructure construction that Shanghai cannot afford endless growth of car ownership and superstructure of urban transport policy must be

  11. Strongly Semicontinuous Domains and Semi-FS Domains

    Directory of Open Access Journals (Sweden)

    Qingyu He

    2014-01-01

    Full Text Available We are mainly concerned with some special kinds of semicontinuous domains and relationships between them. New concepts of strongly semicontinuous domains, meet semicontinuous domains and semi-FS domains are introduced. It is shown that a dcpo L is strongly semicontinuous if and only if L is semicontinuous and meet semicontinuous. It is proved that semi-FS domains are strongly semicontinuous. Some interpolation properties of semiway-below relations in (strongly semicontinuous bc-domains are given. In terms of these properties, it is proved that strongly semicontinuous bc-domains, in particular strongly semicontinuous lattices, are all semi-FS domains.

  12. Highly Efficient Retention of Polysulfides in "Sea Urchin"-Like Carbon Nanotube/Nanopolyhedra Superstructures as Cathode Material for Ultralong-Life Lithium-Sulfur Batteries.

    Science.gov (United States)

    Chen, Tao; Cheng, Baorui; Zhu, Guoyin; Chen, Renpeng; Hu, Yi; Ma, Lianbo; Lv, Hongling; Wang, Yanrong; Liang, Jia; Tie, Zuoxiu; Jin, Zhong; Liu, Jie

    2017-01-11

    Despite high theoretical energy density, the practical deployment of lithium-sulfur (Li-S) batteries is still not implemented because of the severe capacity decay caused by polysulfide shuttling and the poor rate capability induced by low electrical conductivity of sulfur. Herein, we report a novel sulfur host material based on "sea urchin"-like cobalt nanoparticle embedded and nitrogen-doped carbon nanotube/nanopolyhedra (Co-NCNT/NP) superstructures for Li-S batteries. The hierarchical micromesopores in Co-NCNT/NP can allow efficient impregnation of sulfur and block diffusion of soluble polysulfides by physical confinement, and the incorporation of embedded Co nanoparticles and nitrogen doping (∼4.6 at. %) can synergistically improve the adsorption of polysulfides, as evidenced by beaker cell tests. Moreover, the conductive networks of Co-NCNT/NP interconnected by nitrogen-doped carbon nanotubes (NCNTs) can facilitate electron transport and electrolyte infiltration. Therefore, the specific capacity, rate capability, and cycle stability of Li-S batteries are significantly enhanced. As a result, the Co-NCNT/NP based cathode (loaded with 80 wt % sulfur) delivers a high discharge capacity of 1240 mAh g(-1) after 100 cycles at 0.1 C (based on the weight of sulfur), high rate capacity (755 mAh g(-1) at 2.0 C), and ultralong cycling life (a very low capacity decay of 0.026% per cycle over 1500 cycles at 1.0 C). Remarkably, the composite cathode with high areal sulfur loading of 3.2 mg cm(-2) shows high rate capacities and stable cycling performance over 200 cycles.

  13. 船舶上层建筑端部实板厚疲劳试验研究%Real-thickness fatigue strength test of the ship superstructure end

    Institute of Scientific and Technical Information of China (English)

    任慧龙; 崔兵兵; 冯国庆; 成兵

    2015-01-01

    In order to research the fatigue characteristics of the ship superstructure end, the real⁃thickness four⁃point bending model tests were designed and actualized. The number of cycles to failure in the fatigue tests were ob⁃tained under different stress levels. The mid⁃value S-N curve and P-S-N curve were drawn through the fixed⁃slope maximum likehood method. The fatigue strength of the position was caculated and compared by testing P-S-N curve and the E curve of CCS codes. The research showed that the S-N curve obtained from fatigue tests can offer a reference for the design and analysis of ships in practice.%为研究船体上层建筑端部的疲劳特性,设计和实施了实板厚四点弯曲疲劳模型试验。获得疲劳试验中不同应力水平下的疲劳失效循环次数,并采用定斜率极大似然法拟合应力水平-疲劳失效循环次数得到中值S-N曲线和P-S-N曲线。分别采用试验P-S-N曲线和CCS规范E曲线计算和比较研究该部位的疲劳强度。结果表明,试验得到的S-N曲线可为实船设计和分析提供参考。

  14. Características ultra-estruturais do nó sinoatrial de rato Wistar Superstructural features of the wistar strain male rats' sinoatrial node (SAN

    Directory of Open Access Journals (Sweden)

    Carlos Alberto Mandarim de Lacerda

    2002-04-01

    Full Text Available As características ultra-estruturais do nó sinoatrial (NSA de 5 ratos machos da variedade Wistar, com 3 meses de idade, foram estudadas por meio de microscopia eletrônica de transmissão (MET. Fragmento pequeno, contendo a região do NSA e área adjacente do átrio direito do coração, foi retirado e fixado em glutaraldeído 2,5% e processado de acordo com técnica convencional para MET. A morfologia do nó sinoatrial de ratos é semelhante a de outros mamíferos. O NSA é uma estrutura anatômica independente do miocárdio atrial, constituído por células típicas (miócitos nodais, células de transição e, principalmente, células nodais imersos em matriz extracelular, na qual predominam fibras colágenas, fibroblastos e nervosThe superstructural features of five Wistar strain male rats' sinoatrial node (SAN at 3-mo-old were studied through transmission electron microscopy (TEM. Small fragments with the regions containing the SAN were cut off, fixed in glutaraldehyde 2.5% and processed according to the conventional technique for TEM. The morphology of the sinoatrial node of the rats is similar as found in other mammals. The SAN is an independent anatomic structure of the atrial myocardial, constituted of typical cells (nodal myocytes, transition cells and nodal cells principally immersed in the extra cellular matrix where collagen fibers, fibroblasts and nerve predominate

  15. Domains in Ferroelectric Nanostructures

    Science.gov (United States)

    Gregg, Marty

    2010-03-01

    Ferroelectric materials have great potential in influencing the future of small scale electronics. At a basic level, this is because ferroelectric surfaces are charged, and so interact strongly with charge-carrying metals and semiconductors - the building blocks for all electronic systems. Since the electrical polarity of the ferroelectric can be reversed, surfaces can both attract and repel charges in nearby materials, and can thereby exert complete control over both charge distribution and movement. It should be no surprise, therefore, that microelectronics industries have already looked very seriously at harnessing ferroelectric materials in a variety of applications, from solid state memory chips (FeRAMs) to field effect transistors (FeFETs). In all such applications, switching the direction of the polarity of the ferroelectric is a key aspect of functional behavior. The mechanism for switching involves the field-induced nucleation and growth of domains. Domain coarsening, through domain wall propagation, eventually causes the entire ferroelectric to switch its polar direction. It is thus the existence and behavior of domains that determine the switching response, and ultimately the performance of the ferroelectric device. A major issue, associated with the integration of ferroelectrics into microelectronic devices, has been that the fundamental properties associated with ferroelectrics, when in bulk form, appear to change quite dramatically and unpredictably when at the nanoscale: new modes of behaviour, and different functional characteristics from those seen in bulk appear. For domains, in particular, the proximity of surfaces and boundaries have a dramatic effect: surface tension and depolarizing fields both serve to increase the equilibrium density of domains, such that minor changes in scale or morphology can have major ramifications for domain redistribution. Given the importance of domains in dictating the overall switching characteristics of a device

  16. Parameters of passive fit using a new technique to mill implant-supported superstructures: an in vitro study of a novel three-dimensional force measurement-misfit method.

    Science.gov (United States)

    Tahmaseb, Ali; van de Weijden, J J; Mercelis, Peter; De Clerck, Renaat; Wismeijer, Daniel

    2010-01-01

    The objectives of this study are to describe, in vitro, a novel technique to measure the misfit of digitally designed and manufactured implant-supported frameworks according to a new concept based on computer-guided surgery in combination with previously placed mini-implants. Also, the digitally created framework and an impression-based milled structure were compared using strain gauge measurements. Acrylic resin and plaster models were prepared to represent the edentulous mandible. After insertion of three mini-implants in the acrylic resin model, a cone-beam computed tomographic scan was performed. The data were imported to planning software, where six implants were virtually inserted. A drill guide and titanium framework were designed and milled using a fully digital computer-aided design/computer-assisted machining protocol. Six implants were inserted using the drill guide attached to the mini-implants. After an impression was made of the acrylic resin model with six implants, the second model (plaster model) was prepared. A second milled titanium structure was fabricated following optical scanning of the acrylic resin model. Strain gauge measurements were done on both structures attached to both models. To validate the results, a high-accuracy industrial optical scanning system was used to capture all connection geometry and the measurements were compared. The accuracy of the digital superstructures was 19, 22, and 10 Microm with standard deviations (SD) of 19.2 (17.9), 21.5 (28.3), and 10.3 (10.1) Microm for the x-, y-, and z-axes, respectively. For the impression-based superstructure the measured misfit was 11, 20, and 17 Microm, with SD 11.8 (10.5), 19.7 (11.7), and 16.7 (8.2) Microm for the x-, y-, and z-axes, respectively. The misfit of the digitally designed and produced superstructure on the digitally planned and inserted implants was clinically insignificant.

  17. Just how versatile are domains?

    Directory of Open Access Journals (Sweden)

    Bornberg-Bauer Erich

    2008-10-01

    Full Text Available Abstract Background Creating new protein domain arrangements is a frequent mechanism of evolutionary innovation. While some domains always form the same combinations, others form many different arrangements. This ability, which is often referred to as versatility or promiscuity of domains, its a random evolutionary model in which a domain's promiscuity is based on its relative frequency of domains. Results We show that there is a clear relationship across genomes between the promiscuity of a given domain and its frequency. However, the strength of this relationship differs for different domains. We thus redefine domain promiscuity by defining a new index, DV I ("domain versatility index", which eliminates the effect of domain frequency. We explore links between a domain's versatility, when unlinked from abundance, and its biological properties. Conclusion Our results indicate that domains occurring as single domain proteins and domains appearing frequently at protein termini have a higher DV I. This is consistent with previous observations that the evolution of domain re-arrangements is primarily driven by fusion of pre-existing arrangements and single domains as well as loss of domains at protein termini. Furthermore, we studied the link between domain age, defined as the first appearance of a domain in the species tree, and the DV I. Contrary to previous studies based on domain promiscuity, it seems as if the DV I is age independent. Finally, we find that contrary to previously reported findings, versatility is lower in Eukaryotes. In summary, our measure of domain versatility indicates that a random attachment process is sufficient to explain the observed distribution of domain arrangements and that several views on domain promiscuity need to be revised.

  18. Axion domain wall baryogenesis

    Energy Technology Data Exchange (ETDEWEB)

    Daido, Ryuji; Kitajima, Naoya [Department of Physics, Tohoku University,Sendai 980-8578 (Japan); Takahashi, Fuminobu [Department of Physics, Tohoku University,Sendai 980-8578 (Japan); Kavli IPMU, TODIAS, University of Tokyo,Kashiwa 277-8583 (Japan)

    2015-07-28

    We propose a new scenario of baryogenesis, in which annihilation of axion domain walls generates a sizable baryon asymmetry. Successful baryogenesis is possible for a wide range of the axion mass and decay constant, m≃10{sup 8}–10{sup 13} GeV and f≃10{sup 13}–10{sup 16} GeV. Baryonic isocurvature perturbations are significantly suppressed in our model, in contrast to various spontaneous baryogenesis scenarios in the slow-roll regime. In particular, the axion domain wall baryogenesis is consistent with high-scale inflation which generates a large tensor-to-scalar ratio within the reach of future CMB B-mode experiments. We also discuss the gravitational waves produced by the domain wall annihilation and its implications for the future gravitational wave experiments.

  19. On Binding Domains

    NARCIS (Netherlands)

    Everaert, M.B.H.

    2005-01-01

    In this paper I want to explore reasons for replacing Binding Theory based on the anaphor-pronoun dichotomy by a Binding Theory allowing more domains restricting/defining anaphoric dependencies. This will, thus, have consequences for the partitioning of anaphoric elements, presupposing more types of

  20. Cellulose binding domain proteins

    Science.gov (United States)

    Shoseyov, Oded; Shpiegl, Itai; Goldstein, Marc; Doi, Roy

    1998-01-01

    A cellulose binding domain (CBD) having a high affinity for crystalline cellulose and chitin is disclosed, along with methods for the molecular cloning and recombinant production thereof. Fusion products comprising the CBD and a second protein are likewise described. A wide range of applications are contemplated for both the CBD and the fusion products, including drug delivery, affinity separations, and diagnostic techniques.

  1. Domain: Labour market

    NARCIS (Netherlands)

    Oude Mulders, J.; Wadensjö, E.; Hasselhorn, H.M.; Apt, W.

    This domain chapter is dedicated to summarize research on the effects of labour market contextual factors on labour market participation of older workers (aged 50+) and identify research gaps. While employment participation and the timing of (early) retirement is often modelled as an individual

  2. Normed Domains of Holomorphy

    Directory of Open Access Journals (Sweden)

    Steven G. Krantz

    2010-01-01

    Full Text Available We treat the classical concept of domain of holomorphy in ℂn when the holomorphic functions considered are restricted to lie in some Banach space. Positive and negative results are presented. A new view of the case n=1 is considered.

  3. Domain: Labour market

    NARCIS (Netherlands)

    Oude Mulders, J.; Wadensjö, E.; Hasselhorn, H.M.; Apt, W.

    2015-01-01

    This domain chapter is dedicated to summarize research on the effects of labour market contextual factors on labour market participation of older workers (aged 50+) and identify research gaps. While employment participation and the timing of (early) retirement is often modelled as an individual deci

  4. 有蓄能的联供系统超结构优化配置%Superstructure-based Optimal Planning of Cogeneration Systems With Storage

    Institute of Scientific and Technical Information of China (English)

    肖小清; 阚伟民; 杨允; 张士杰; 肖云汉

    2012-01-01

    In this paper, the storage was introduced into a superstructure-based optimal planning mixed integer linear programming (MILP) model of cogeneration systems The model can achieve simultaneous optimization of system structure and operation as well as simultaneous optimization of all equipment including storage. At the same time the branch and bound method combined with the simplex method was used as a solution algorithm. Through a case study, the validity and effectiveness of the proposed model and the method were verified. The computational results also indicate that, the introduction of storages in cogeneration systems reduces the capacities of other refrigeration equipment; under time of use electricity rates, storage enhances the system flexibility and economic and energy saving can be obtained through removing some of the strong coupling relationship between cooling/heating demands and generators. The optimal operation strategies of storage are different in typical days, which depend on electricity price, energy demands et al.%将蓄能装置引入到基于超结构方法的分布式联供系统优化配置混合整数线性规划模型之中,所得模型可实现系统结构和运行同步优化、各设备与蓄能装置同时优化,采用分枝定界法结合单纯形算法实现对模型的求解.通过研究案例,验证了计算模型和求解方法的可行性和有效性.计算结果亦表明,联供系统中引入蓄能装置可以减小系统内其它制冷设备的容量;在分时电价体系下引入蓄能装置可以部分解除冷热负荷与发电机组之间的强耦合关系,使联供系统运行更灵活,并降低供能成本和能耗;在不同的典型日内蓄能装置的优化运行规律不同,取决于电价、负荷需求等.

  5. Time Domain Induced Polarization

    DEFF Research Database (Denmark)

    Fiandaca, Gianluca; Auken, Esben; Christiansen, Anders Vest

    2012-01-01

    Time-domain-induced polarization has significantly broadened its field of reference during the last decade, from mineral exploration to environmental geophysics, e.g., for clay and peat identification and landfill characterization. Though, insufficient modeling tools have hitherto limited the use...... of time-domaininduced polarization for wider purposes. For these reasons, a new forward code and inversion algorithm have been developed using the full-time decay of the induced polarization response, together with an accurate description of the transmitter waveform and of the receiver transfer function......%. Furthermore, the presence of low-pass filters in time-domain-induced polarization instruments affects the early times of the acquired decays (typically up to 100 ms) and has to be modeled in the forward response to avoid significant loss of resolution. The developed forward code has been implemented in a 1D...

  6. Comparison of the domain and frequency domain state feedbacks

    Energy Technology Data Exchange (ETDEWEB)

    Zhang, S.Y.

    1986-01-01

    In this paper, we present explicitly the equivalence of the time domain and frequency domain state feedbacks, as well as the dynamic state feedback and a modified frequency domain state feedback, from the closed-loop transfer function point of view. The difference of the two approaches is also shown.

  7. Domains of Disoriented Chiral Condensate

    CERN Document Server

    Amado, R D; Lu, Yang

    1996-01-01

    The probability distribution of neutral pion fraction from independent domains of disoriented chiral condensate is characterized. The signal for the condensate is clear for a small number of domains but is greatly reduced for more than three.

  8. Summarization by domain ontology navigation

    DEFF Research Database (Denmark)

    Andreasen, Troels; Bulskov, Henrik

    2013-01-01

    of the subject. In between these two extremes, conceptual summaries encompass selected concepts derived using background knowledge. We address in this paper an approach where conceptual summaries are provided through a conceptualization as given by an ontology. The ontology guiding the summarization can...... be a simple taxonomy or a generative domain ontology. A domain ontology can be provided by a preanalysis of a domain corpus and can be used to condense improved summaries that better reflects the conceptualization of a given domain....

  9. Genome cartography through domain annotation.

    Science.gov (United States)

    Ponting, C P; Dickens, N J

    2001-01-01

    The evolutionary history of eukaryotic proteins involves rapid sequence divergence, addition and deletion of domains, and fusion and fission of genes. Although the protein repertoires of distantly related species differ greatly, their domain repertoires do not. To account for the great diversity of domain contexts and an unexpected paucity of ortholog conservation, we must categorize the coding regions of completely sequenced genomes into domain families, as well as protein families.

  10. Ligand binding by PDZ domains

    OpenAIRE

    Celestine N. Chi; Bach, Anders; Stromgaard, Kristian; Gianni, Stefano; Jemth, Per

    2012-01-01

    The postsynaptic density protein-95/disks large/zonula occludens-1 (PDZ) protein domain family is one of the most common proteinprotein interaction modules in mammalian cells, with paralogs present in several hundred human proteins. PDZ domains are found in most cell types, but neuronal proteins, for example, are particularly rich in these domains. The general function of PDZ domains is to bring proteins together within the appropriate cellular compartment, thereby facilitating scaffolding, s...

  11. Chaotic domains: A numerical investigation

    OpenAIRE

    Cross, M. C.; Meiron, D.; Tu, Yuhai

    1994-01-01

    We study the chaotic domain state in rotating convection using a model equation that allows for a continuous range of roll orientations as in the experimental system. Methods are developed for extracting the domain configuration from the resulting patterns that should be applicable to a wide range of domain states. Comparison with the truncated three mode amplitude equation description is made.

  12. Gershgorin domains for partitioned matrices

    NARCIS (Netherlands)

    Sluis, A. van der

    1979-01-01

    Inclusion domains for the eigenvalues of a partitioned matrix are specified in terms of perturbations of its diagonal blocks. The size of such perturbations is measured using the Kantorovitch-Robert-Deutsch vectorial norms. The inclusion domains obtained thereby are compared with inclusion domains o

  13. Feature-level domain adaptation

    DEFF Research Database (Denmark)

    Kouw, Wouter M.; Van Der Maaten, Laurens J P; Krijthe, Jesse H.

    2016-01-01

    Domain adaptation is the supervised learning setting in which the training and test data are sampled from different distributions: training data is sampled from a source domain, whilst test data is sampled from a target domain. This paper proposes and studies an approach, called feature...

  14. Classification of Noncommutative Domain Algebras

    CERN Document Server

    Arias, Alvaro

    2012-01-01

    Noncommutative domain algebras are noncommutative analogues of the algebras of holomorphic functions on domains of $\\C^n$ defined by holomorphic polynomials, and they generalize the noncommutative Hardy algebras. We present here a complete classification of these algebras based upon techniques inspired by multivariate complex analysis, and more specifically the classification of domains in hermitian spaces up to biholomorphic equivalence.

  15. 乌苏大桥主桥上部结构设计与计算%Design and Calculation of Superstructure of Main Bridge of Wusu Bridge

    Institute of Scientific and Technical Information of China (English)

    康晋; 肖海珠; 徐伟

    2011-01-01

    The main bridge of the Wusu Bridge is a single pylon and single cable plane cablestayed bridge with span arrangement (140+140) m and with a structural system of rigid fixity of the pylon, pier and girder. A summarized account of the design and calculation of the superstructure of the bridge is presented herewith. The main girder of the bridge is a composite girder with long cantilevers, the central part of the girder is designed as a two-cell and single-box steel girder and the steel cantilever at each side of the girder is the variable depth I-beam and is provided wiht a trough stringer at the far side, which are all topped with 25 cm thick concrete deck slabs connected with the girder via shearing studs. The part of the main girder close to the pylon is designed as a prestressed concrete box girder to facilitate the fixity of the girder with the pylon. The pylon is the single column pylon, 117 m in height. The stay cables, made up of low relaxation galvanized high strength parallel steel wire strands, are of the harp pattern cable plane arranged in the central alignment of the bridge deck. The finite element software MIDAS Civil 2006 and the SCDS programme are employed to calculate and analyze structure of the bridge. The results of the calculation and analysis indicate that the static, stability and dynamic characteristics of the bridge can meet the requirements in the relevant codes.%乌苏大桥主桥为独塔单索面斜拉桥,跨径布置为(140+140) m,采用塔、墩、梁固结体系,综述该桥上部结构设计与计算.主梁为带大挑臂的钢箱结合梁,中间钢箱梁采用单箱双室截面,两侧钢挑臂为变高度工字形梁,挑臂端部设槽形小纵梁;混凝土桥面板厚25 cm,与钢梁通过剪力钉连接;塔根部主梁采用预应力混凝土箱梁,以方便与桥塔固结;桥塔采用独柱式塔,高117 m;斜拉索为竖琴形中央平行索面布置,采用低松弛镀锌高强度平行钢丝束.采用有限元软件MIDAS Civil

  16. Expansion of protein domain repeats.

    Directory of Open Access Journals (Sweden)

    Asa K Björklund

    2006-08-01

    Full Text Available Many proteins, especially in eukaryotes, contain tandem repeats of several domains from the same family. These repeats have a variety of binding properties and are involved in protein-protein interactions as well as binding to other ligands such as DNA and RNA. The rapid expansion of protein domain repeats is assumed to have evolved through internal tandem duplications. However, the exact mechanisms behind these tandem duplications are not well-understood. Here, we have studied the evolution, function, protein structure, gene structure, and phylogenetic distribution of domain repeats. For this purpose we have assigned Pfam-A domain families to 24 proteomes with more sensitive domain assignments in the repeat regions. These assignments confirmed previous findings that eukaryotes, and in particular vertebrates, contain a much higher fraction of proteins with repeats compared with prokaryotes. The internal sequence similarity in each protein revealed that the domain repeats are often expanded through duplications of several domains at a time, while the duplication of one domain is less common. Many of the repeats appear to have been duplicated in the middle of the repeat region. This is in strong contrast to the evolution of other proteins that mainly works through additions of single domains at either terminus. Further, we found that some domain families show distinct duplication patterns, e.g., nebulin domains have mainly been expanded with a unit of seven domains at a time, while duplications of other domain families involve varying numbers of domains. Finally, no common mechanism for the expansion of all repeats could be detected. We found that the duplication patterns show no dependence on the size of the domains. Further, repeat expansion in some families can possibly be explained by shuffling of exons. However, exon shuffling could not have created all repeats.

  17. Metaphors, domains and embodiment

    Directory of Open Access Journals (Sweden)

    M.E. Botha

    2005-07-01

    Full Text Available Investigations of metaphorical meaning constitution and meaning (in- variance have revealed the significance of semantic and semiotic domains and the contexts within which they function as basis for the grounding of metaphorical meaning. In this article some of the current views concerning the grounding of metaphorical meaning in experience and embodiment are explored. My provisional agreement with Lakoff, Johnson and others about the “conceptual” nature of metaphor rests on an important caveat, viz. that this bodily based conceptual structure which lies at the basis of linguistic articulations of metaphor, is grounded in a deeper ontic structure of the world and of human experience. It is the “metaphorical” (actually “analogical” ontological structure of this grounding that is of interest for the line of argumentation followed in this article. Because Johnson, Lakoff and other’s proposal to ground metaphorical meaning in embodiment and neural processes is open to being construed as subjectivist and materialist, I shall attempt to articulate the contours of an alternative theory of conceptual metaphor, meaning and embodiment which counteracts these possibilities. This theory grounds metaphorical meaning and meaning change in an ontological and anthropological framework which recognises the presence and conditioning functioning of radially ordered structures for reality. These categorisations in which humankind, human knowledge and reality participate, condition and constrain (ground analogical and metaphorical meaning transfer, cross-domain mappings, and blends in cognition and in language, provide the basis for the analogical concepts found in these disciplines.

  18. Ligand binding by PDZ domains

    DEFF Research Database (Denmark)

    Chi, Celestine N.; Bach, Anders; Strømgaard, Kristian

    2012-01-01

    The postsynaptic density protein-95/disks large/zonula occludens-1 (PDZ) protein domain family is one of the most common protein-protein interaction modules in mammalian cells, with paralogs present in several hundred human proteins. PDZ domains are found in most cell types, but neuronal proteins......, for example, are particularly rich in these domains. The general function of PDZ domains is to bring proteins together within the appropriate cellular compartment, thereby facilitating scaffolding, signaling, and trafficking events. The many functions of PDZ domains under normal physiological as well...

  19. The framing of scientific domains

    DEFF Research Database (Denmark)

    Dam Christensen, Hans

    2014-01-01

    Purpose: By using the UNISIST models this article argues for the necessity of domain analysis in order to qualify scientific information seeking. The models better understanding of communication processes in a scientific domain and embraces the point that domains are always both unstable over time...... and changeable according to the specific perspective. This understanding is even more important today as numerous digitally generated information tools as well as collaborative and interdisciplinary research are blurring the domain borders. Nevertheless, researchers navigate “intuitively” in “their” specific...... as according to the agents that are charting them. As such, power in a Foucauldian sense is unavoidable in outlining a domain. Originality/value 1. The UNISIST models are applied to the domain of art history; and 2. the article discusses the instability of a scientific domain as well as, at the same time...

  20. The framing of scientific domains

    DEFF Research Database (Denmark)

    Dam Christensen, Hans

    2014-01-01

    Purpose: By using the UNISIST models this article argues for the necessity of domain analysis in order to qualify scientific information seeking. The models better understanding of communication processes in a scientific domain and embraces the point that domains are always both unstable over time...... as according to the agents that are charting them. As such, power in a Foucauldian sense is unavoidable in outlining a domain. Originality/value 1. The UNISIST models are applied to the domain of art history; and 2. the article discusses the instability of a scientific domain as well as, at the same time......, the significance of framing a domain; an implication which is often neglected in scientific information seeking....

  1. Near-field optical second-harmonic technique for detection and characterization of semiconductor thin film electron-scattering domain boundaries

    Science.gov (United States)

    Shafiei, Farbod; Orzali, Tommaso; Bersuker, Gennadi; Michael, Downer

    2015-03-01

    Understanding electron transport in epitaxial semiconductor thin films and low dimension systems is crucial for new electro-optic devices. III-V films grown on Si integrate high carrier mobility into the established Si platform, but are susceptible to formation of sub-micron anti-phase domains that possess unwanted Ga-Ga or As-As electron-scattering defects at their boundaries. Optical second-harmonic generation provides sensitive, specific and noninvasive but so far only spatially-integrated characterization for these defects. We introduce a fiber based nearfield scanning optical second harmonic microscopy for the first time to fully resolve the electron scattering boundaries on III-V/Si films. This technique reveal variations in electron scattering boundaries structure as growth conditions, epitaxial film composition, and substrate vary, and are compared with surface topography, darkfield transmission electron microscopy and electron back scatter diffraction. Suppression of the electron-scattering boundaries has been explored.

  2. 用于超结构换热器网络热计算和网络综合的显式解%An Explicit Solution for Thermal Calculation and Synthesis of Superstructure Heat Exchanger Networks

    Institute of Scientific and Technical Information of China (English)

    陈德珍; 杨杉杉; 罗行; 温卿云; 马虎根

    2007-01-01

    For the optimal design of a heat exchanger network,the inlet and outlet stream temperatures of each heat exchanger in the network should be known.An explicit analytical solution of stream temperatures of an arbitrary connected heat exchanger network was introduced,which is suitable for the thermal calculation of heat exchanger networks.For the heat exchanger network synthesis,this solution was further developed and coupled with the stage-wise superstructure heat exchanger networks.The new calculation procedure reduced the computer memory requirement dramatically.On the basis of this solution,a mathematical model for synthesis of heat exchanger networks with genetic algorithm was formulated,which is always feasible and no iteration is needed.Two examples were calculated with the proposed approach and better results were obtained.

  3. Periodic domain boundary ordering in a dense molecular adlayer: Sub-saturation carbon monoxide on Pd(111)

    Science.gov (United States)

    Xu, Pan; Liu, Shizhong; Hong, Sung-Young; Liu, Ping; White, Michael G.; Camillone, Nicholas

    2017-04-01

    We describe a previously unreported ordered phase of carbon monoxide adsorbed on the (111) facet of single crystal palladium at near-saturation coverage. The adlayer superstructure is identified from low energy electron diffraction to be c(16×2) with respect to the underlying Pd(111) surface net. The ideal coverage is determined to be 0.6875 ML, approximately 92% of the 0.75-ML saturation coverage. Density functional theory calculations support a model for the molecular packing characterized by strips of locally-saturated (2×2) regions, with the CO bound near high-symmetry surface sites, separated by antiphase domain boundaries. The structure exists in a narrow coverage range and is prepared by heating the saturated adlayer to desorb a small fraction of the CO. Comparison of the c(16×2) domain-boundary structure with structural motifs at lower coverages suggests that between 0.6 and 0.6875 ML the adlayer order may be more strongly influenced by interadsorbate repulsion than by adsorption-site-specific interactions. The system is an example of the structural complexity that results from the compromise between adsorbate-substrate and adsorbate-adsorbate interactions.

  4. All-in-one bioprobe devised with hierarchical-ordered magnetic NiCo2O4 superstructure for ultrasensitive dual-readout immunosensor for logic diagnosis of tumor marker.

    Science.gov (United States)

    Dai, Hong; Gong, Lingshan; Zhang, Shupei; Xu, Guifang; Li, Yilin; Hong, Zhensheng; Lin, Yanyu

    2016-03-15

    A new enzyme-free all-in-one bioprobe, consisted of hematin decorated magnetic NiCo2O4 superstructure (ATS-MNS-Hb), was designed for ultrasensitive photoelectrochemical and electrochemical dual-readout immunosensing of carcinoembryonic antigen (CEA) on carbon nanohorns (CNH) support. Herein, the MNS, possessed hierarchical-ordered structure, good porosity and magnetism, acted as nanocarrier to absorb abundant Hb molecular after functionalization, providing a convenient collection means by magnetic control as well as enhanced dual-readout sensing performances. CNH superstructures were employed as support to immobilize abounding captured antibodies, and then as-designed dual mode bioprobe, covalent binding with secondary antibody of CEA, was introduced for ultrasensitive detection of CEA by sandwich immunosensing. Photoelectrochemical response originated from plentiful hematin molecular, a excellent photosensitizer with good visible light harvesting efficiency, absorbed by functionalized porous MNS. The resultant concentration dependant linear calibration range was from 10 fg/mL to 1 ng/mL with ultralow detection limit of 10 fg/mL. For electrochemical process, catalase-like property of MNS was validated, moreover, MNS-Hb hybrid exhibited much higher mimic enzyme catalytic activity and evidently amplified electrocatalytic signal, performing a wide dynamic linear range from 1 ng/mL to 40 ng/mL with low detection limit of 1 ng/mL. Additionally, due to the improved accuracy of dual signals detection, the exact diagnoses of serum samples were gotten by operating resulting dual signals with AND logic system. This work demonstrated the promising application of MNS in developing ultrasensitive, cost-effective and environment friendly dual-readout immunosensor and accurate diagnoses strategy for tumor markers.

  5. Protein domain organisation: adding order

    Directory of Open Access Journals (Sweden)

    Kummerfeld Sarah K

    2009-01-01

    Full Text Available Abstract Background Domains are the building blocks of proteins. During evolution, they have been duplicated, fused and recombined, to produce proteins with novel structures and functions. Structural and genome-scale studies have shown that pairs or groups of domains observed together in a protein are almost always found in only one N to C terminal order and are the result of a single recombination event that has been propagated by duplication of the multi-domain unit. Previous studies of domain organisation have used graph theory to represent the co-occurrence of domains within proteins. We build on this approach by adding directionality to the graphs and connecting nodes based on their relative order in the protein. Most of the time, the linear order of domains is conserved. However, using the directed graph representation we have identified non-linear features of domain organization that are over-represented in genomes. Recognising these patterns and unravelling how they have arisen may allow us to understand the functional relationships between domains and understand how the protein repertoire has evolved. Results We identify groups of domains that are not linearly conserved, but instead have been shuffled during evolution so that they occur in multiple different orders. We consider 192 genomes across all three kingdoms of life and use domain and protein annotation to understand their functional significance. To identify these features and assess their statistical significance, we represent the linear order of domains in proteins as a directed graph and apply graph theoretical methods. We describe two higher-order patterns of domain organisation: clusters and bi-directionally associated domain pairs and explore their functional importance and phylogenetic conservation. Conclusion Taking into account the order of domains, we have derived a novel picture of global protein organization. We found that all genomes have a higher than expected

  6. Domain imaging in FINEMET ribbons

    Energy Technology Data Exchange (ETDEWEB)

    Silveyra, J.M., E-mail: jsilveyra@fi.uba.a [Laboratorio de Solidos Amorfos, INTECIN, Facultad de Ingenieria, UBA-CONICET, Paseo Colon 850, (C1063ACV) Buenos Aires (Argentina); Vlasak, G.; Svec, P.; Janickovic, D. [Institute of Physics, Slovak Academy of Sciences, Dubravska cesta 9, 845 11 Bratislava (Slovakia); Cremaschi, V.J., E-mail: vcremas@gmail.co [Laboratorio de Solidos Amorfos, INTECIN, Facultad de Ingenieria, UBA-CONICET, Paseo Colon 850, (C1063ACV) Buenos Aires (Argentina); Member of Carrera del Investigador, CONICET (Argentina)

    2010-09-15

    The magnetization behaviour of a ferromagnetic material depends on its domain structure, which in turn is largely determined by magnetic anisotropies. In this work, domain patterns were observed by a quite forgotten but still the simplest and the cheapest technique: the Bitter method. A systematic study of the evolution of the domain structure in FINEMET ribbons after thermal annealing is presented, correlating the results with the crystalline structure, magnetostriction and coercivity measurements.

  7. Dynamical domain wall and localization

    Directory of Open Access Journals (Sweden)

    Yuta Toyozato

    2016-03-01

    Full Text Available Based on the previous works (Toyozato et al., 2013 [24]; Higuchi and Nojiri, 2014 [25], we investigate the localization of the fields on the dynamical domain wall, where the four-dimensional FRW universe is realized on the domain wall in the five-dimensional space–time. Especially we show that the chiral spinor can localize on the domain wall, which has not been succeeded in the past works as the seminal work in George et al. (2009 [23].

  8. Tem analyses of the local crystal and domain structures in (Na(1-x)K(x))0.5Bi(0.5)TiO3 perovskite ceramics.

    Science.gov (United States)

    Otonicar, Mojca; Skapin, Sreco D; Jancar, Bostjan

    2011-09-01

    The local crystal and domain structures of the ((Na(1-x)K(x))(0.5)Bi(0.5)TiO(3) (NBT-KBT) solid solutions were studied because of their influence on the enhanced electromechanical properties of ceramics. Based on X-ray diffraction, the morphotropic phase boundary (MPB) was determined for the composition x = 0.20, in which the rhombohedral and the tetragonal structures were observed to coexist. However, detailed domain-structure analyses using transmission electron microscopy (TEM), performed on the NBT, KBT, and five NBT-KBT solid-solution compositions, revealed some structural changes at/near the MPB. In the samples on the tetragonal side of the MPB, the grains showed a lamellar domain structure with 90° orientations of the individual domains, separated by straight domain boundaries, i.e., (011)/(101) twin planes. The rhombohedral samples on the other side of the MPB showed a typical square-net pattern with needle-like or lamellar ~71°/109° rhombohedral domains with (001) and/or (110) twin planes separating the individual domains. The domain structure at the MPB showed well-defined lamellar domains. Based on the occurrence of the superstructure reflections in the SAED patterns of various crystallographic zones, on the characteristic splitting of the reflections, and on the domain morphology observations, the crystal structure in/near the boundary region was determined to be a tetragonal structure with an in-phase oxygen octahedral tilt system (probably a(0)a(0)c(+)). It is suggested that the tetragonal polar order is partly induced from the rhombohedral structure at the MPB as a result of mechanical loading during TEM sample preparation.

  9. Mapping the Moral Domain

    Science.gov (United States)

    Graham, Jesse; Nosek, Brian A.; Haidt, Jonathan; Iyer, Ravi; Koleva, Spassena; Ditto, Peter H.

    2010-01-01

    The moral domain is broader than the empathy and justice concerns assessed by existing measures of moral competence, and it is not just a subset of the values assessed by value inventories. To fill the need for reliable and theoretically-grounded measurement of the full range of moral concerns, we developed the Moral Foundations Questionnaire (MFQ) based on a theoretical model of five universally available (but variably developed) sets of moral intuitions: Harm/care, Fairness/reciprocity, Ingroup/loyalty, Authority/respect, and Purity/sanctity. We present evidence for the internal and external validity of the scale and the model, and in doing so present new findings about morality: 1. Comparative model fitting of confirmatory factor analyses provides empirical justification for a five-factor structure of moral concerns. 2. Convergent/discriminant validity evidence suggests that moral concerns predict personality features and social group attitudes not previously considered morally relevant. 3. We establish pragmatic validity of the measure in providing new knowledge and research opportunities concerning demographic and cultural differences in moral intuitions. These analyses provide evidence for the usefulness of Moral Foundations Theory in simultaneously increasing the scope and sharpening the resolution of psychological views of morality. PMID:21244182

  10. Discoidin Domain Receptor 1

    Science.gov (United States)

    Song, Sunmi; Shackel, Nicholas A.; Wang, Xin M.; Ajami, Katerina; McCaughan, Geoffrey W.; Gorrell, Mark D.

    2011-01-01

    Discoidin domain receptor 1 (DDR1) is a receptor tyrosine kinase that binds and is activated by collagens. Transcriptional profiling of cirrhosis in human liver using a DNA array and quantitative PCR detected elevated mRNA expression of DDR1 compared with that in nondiseased liver. The present study characterized DDR1 expression in cirrhotic and nondiseased human liver and examined the cellular effects of DDR1 expression. mRNA expression of all five isoforms of DDR1 was detected in human liver, whereas DDR1a demonstrated differential expression in liver with hepatitis C virus and primary biliary cirrhosis compared with nondiseased liver. In addition, immunoblot analysis detected shed fragments of DDR1 more readily in cirrhotic liver than in nondiseased liver. Inasmuch as DDR1 is subject to protease-mediated cleavage after prolonged interaction with collagen, this differential expression may indicate more intense activation of DDR1 protein in cirrhotic compared with nondiseased liver. In situ hybridization and immunofluorescence localized intense DDR1 mRNA and protein expression to epithelial cells including hepatocytes at the portal-parenchymal interface and the luminal aspect of the biliary epithelium. Overexpression of DDR1a altered hepatocyte behavior including increased adhesion and less migration on extracelular matrix substrates. DDR1a regulated extracellular expression of matrix metalloproteinases 1 and 2. These data elucidate DDR1 function pertinent to cirrhosis and indicate the importance of epithelial cell–collagen interactions in chronic liver injury. PMID:21356365

  11. Ontology development for Sufism domain

    Science.gov (United States)

    Iqbal, Rizwan

    2012-01-01

    Domain ontology is a descriptive representation of any particular domain which in detail describes the concepts in a domain, the relationships among those concepts and organizes them in a hierarchal manner. It is also defined as a structure of knowledge, used as a means of knowledge sharing to the community. An Important aspect of using ontologies is to make information retrieval more accurate and efficient. Thousands of domain ontologies from all around the world are available online on ontology repositories. Ontology repositories like SWOOGLE currently have over 1000 ontologies covering a wide range of domains. It was found that up to date there was no ontology available covering the domain of "Sufism". This unavailability of "Sufism" domain ontology became a motivation factor for this research. This research came up with a working "Sufism" domain ontology as well a framework, design of the proposed framework focuses on the resolution to problems which were experienced while creating the "Sufism" ontology. The development and working of the "Sufism" domain ontology are covered in detail in this research. The word "Sufism" is a term which refers to Islamic mysticism. One of the reasons to choose "Sufism" for ontology creation is its global curiosity. This research has also managed to create some individuals which inherit the concepts from the "Sufism" ontology. The creation of individuals helps to demonstrate the efficient and precise retrieval of data from the "Sufism" domain ontology. The experiment of creating the "Sufism" domain ontology was carried out on a tool called Protégé. Protégé is a tool which is used for ontology creation, editing and it is open source.

  12. On Probability Domains

    Science.gov (United States)

    Frič, Roman; Papčo, Martin

    2010-12-01

    Motivated by IF-probability theory (intuitionistic fuzzy), we study n-component probability domains in which each event represents a body of competing components and the range of a state represents a simplex S n of n-tuples of possible rewards-the sum of the rewards is a number from [0,1]. For n=1 we get fuzzy events, for example a bold algebra, and the corresponding fuzzy probability theory can be developed within the category ID of D-posets (equivalently effect algebras) of fuzzy sets and sequentially continuous D-homomorphisms. For n=2 we get IF-events, i.e., pairs ( μ, ν) of fuzzy sets μ, ν∈[0,1] X such that μ( x)+ ν( x)≤1 for all x∈ X, but we order our pairs (events) coordinatewise. Hence the structure of IF-events (where ( μ 1, ν 1)≤( μ 2, ν 2) whenever μ 1≤ μ 2 and ν 2≤ ν 1) is different and, consequently, the resulting IF-probability theory models a different principle. The category ID is cogenerated by I=[0,1] (objects of ID are subobjects of powers I X ), has nice properties and basic probabilistic notions and constructions are categorical. For example, states are morphisms. We introduce the category S n D cogenerated by Sn=\\{(x1,x2,ldots ,xn)in In;sum_{i=1}nxi≤ 1\\} carrying the coordinatewise partial order, difference, and sequential convergence and we show how basic probability notions can be defined within S n D.

  13. Taxonomies of Educational Objective Domain

    OpenAIRE

    Eman Ghanem Nayef; Nik Rosila Nik Yaacob; Hairul Nizam Ismail

    2013-01-01

    This paper highlights an effort to study the educational objective domain taxonomies including Bloom’s taxonomy, Lorin Anderson’s taxonomy, and Wilson’s taxonomy. In this study a comparison among these three taxonomies have been done. Results show that Bloom’s taxonomy is more suitable as an analysis tool to Educational Objective domain.

  14. Phase-domain photoacoustic sensing

    Science.gov (United States)

    Gao, Fei; Zhang, Ruochong; Feng, Xiaohua; Liu, Siyu; Ding, Ran; Kishor, Rahul; Qiu, Lei; Zheng, Yuanjin

    2017-01-01

    As one of the fastest-growing imaging modalities in recent years, photoacoustic imaging has attracted tremendous research interest for various applications including anatomical, functional, and molecular imaging. The majority of the photoacoustic imaging systems are based on the time-domain pulsed photoacoustic method, which utilizes a pulsed laser source to induce a wideband photoacoustic signal, revealing optical absorption contrast. An alternative way is the frequency-domain photoacoustic method utilizing the chirping modulation of laser intensity to achieve lower system cost. In this paper, we report another way of the photoacoustic method, called phase-domain photoacoustic sensing, which explores the phase difference between two consequent intensity-modulated laser pulse induced photoacoustic measurements to reveal the optical properties. The basic principle is introduced, modeled, and experimentally validated in this paper, which opens another potential pathway to perform photoacoustic sensing and imaging, eliminating acoustic detection variations beyond the conventional time-domain and frequency-domain photoacoustic methods.

  15. Domain wall description of superconductivity

    CERN Document Server

    Brito, F A; Silva, J C M

    2012-01-01

    In the present work we shall address the issue of electrical conductivity in superconductors in the perspective of superconducting domain wall solutions in the realm of field theory. We take our set up made out of a dynamical complex scalar field coupled to gauge field to be responsible for superconductivity and an extra scalar real field that plays the role of superconducting domain walls. The temperature of the system is interpreted as the parameter to move type I to type II domain walls. Alternatively, this means that the domain wall surface is suffering an acceleration as one goes from one type to another. On the other hand, changing from type I to type II state means a formation of a condensate what is in perfect sense of lowering the temperature around the superconductor. One can think of this scenario as an analog of holographic scenarios where this set up is replaced by a black hole near the domain wall.

  16. Texture of lipid bilayer domains

    DEFF Research Database (Denmark)

    Jensen, Uffe Bernchou; Brewer, Jonathan R.; Midtiby, Henrik Skov

    2009-01-01

    chains. By imaging the intensity variations as a function of the polarization angle, we map the lateral variations of the lipid tilt within domains. Results reveal that gel domains are composed of subdomains with different lipid tilt directions. We have applied a Fourier decomposition method......We investigate the texture of gel (g) domains in binary lipid membranes composed of the phospholipids DPPC and DOPC. Lateral organization of lipid bilayer membranes is a topic of fundamental and biological importance. Whereas questions related to size and composition of fluid membrane domain...... are well studied, the possibility of texture in gel domains has so far not been examined. When using polarized light for two-photon excitation of the fluorescent lipid probe Laurdan, the emission intensity is highly sensitive to the angle between the polarization and the tilt orientation of lipid acyl...

  17. Mutation of domain III and domain VI in L gene conserved domain of Nipah virus

    Science.gov (United States)

    Jalani, Siti Aishah; Ibrahim, Nazlina

    2016-11-01

    Nipah virus (NiV) is the etiologic agent responsible for the respiratory illness and causes fatal encephalitis in human. NiV L protein subunit is thought to be responsible for the majority of enzymatic activities involved in viral transcription and replication. The L protein which is the viral RNA dependent RNA polymerase has high sequence homology among negative sense RNA viruses. In negative stranded RNA viruses, based on sequence alignment six conserved domain (domain I-IV) have been determined. Each domain is separated on variable regions that suggest the structure to consist concatenated functional domain. To directly address the roles of domains III and VI, site-directed mutations were constructed by the substitution of bases at sequences 2497, 2500, 5528 and 5532. Each mutated L gene can be used in future studies to test the ability for expression on in vitro translation.

  18. Domain Walls in SU(5)

    CERN Document Server

    Poghosian, L E; Pogosian, Levon; Vachaspati, Tanmay

    2000-01-01

    We consider the Grand Unified SU(5) model with a small or vanishing cubic term in the adjoint scalar field in the potential. This gives the model an approximate or exact Z$_2$ symmetry whose breaking leads to domain walls. The simplest domain wall has the structure of a kink across which the Higgs field changes sign ($\\Phi \\to -\\Phi$) and inside which the full SU(5) is restored. The kink is shown to be perturbatively unstable for all parameters. We then construct a domain wall solution that is lighter than the kink and show it to be perturbatively stable for a range of parameters. The symmetry in the core of this domain wall is smaller than that outside. The interactions of the domain wall with magnetic monopole is discussed and it is shown that magnetic monopoles with certain internal space orientations relative to the wall pass through the domain wall. Magnetic monopoles in other relative internal space orientations are likely to be swept away on collision with the domain walls, suggesting a scenario where ...

  19. Predicting domain-domain interaction based on domain profiles with feature selection and support vector machines

    Directory of Open Access Journals (Sweden)

    Liao Li

    2010-10-01

    Full Text Available Abstract Background Protein-protein interaction (PPI plays essential roles in cellular functions. The cost, time and other limitations associated with the current experimental methods have motivated the development of computational methods for predicting PPIs. As protein interactions generally occur via domains instead of the whole molecules, predicting domain-domain interaction (DDI is an important step toward PPI prediction. Computational methods developed so far have utilized information from various sources at different levels, from primary sequences, to molecular structures, to evolutionary profiles. Results In this paper, we propose a computational method to predict DDI using support vector machines (SVMs, based on domains represented as interaction profile hidden Markov models (ipHMM where interacting residues in domains are explicitly modeled according to the three dimensional structural information available at the Protein Data Bank (PDB. Features about the domains are extracted first as the Fisher scores derived from the ipHMM and then selected using singular value decomposition (SVD. Domain pairs are represented by concatenating their selected feature vectors, and classified by a support vector machine trained on these feature vectors. The method is tested by leave-one-out cross validation experiments with a set of interacting protein pairs adopted from the 3DID database. The prediction accuracy has shown significant improvement as compared to InterPreTS (Interaction Prediction through Tertiary Structure, an existing method for PPI prediction that also uses the sequences and complexes of known 3D structure. Conclusions We show that domain-domain interaction prediction can be significantly enhanced by exploiting information inherent in the domain profiles via feature selection based on Fisher scores, singular value decomposition and supervised learning based on support vector machines. Datasets and source code are freely available on

  20. 超高车辆-桥梁上部结构撞击力的工程计算方法%Engineering Calculation Method for Collision Force Between Over-height Truck and Bridge Superstructure

    Institute of Scientific and Technical Information of China (English)

    陆新征; 卢啸; 张炎圣; 何水涛

    2011-01-01

    为了弥补中国在超高车辆撞击桥梁上部结构领域研究的不足,完善其工程设计方法,在超高车辆撞击桥梁上部结构的事故案例调查和精细化有限元分析的基础上,提出了超高车辆-桥梁上部结构撞击的简化计算模型,建立了简化模型的微分方程组,利用数值试验的方法确定了简化模型中的部分参数,从而得出简化计算模型的撞击荷载;为了满足工程设计的需要,在简化模型的基础上提出了形式简单的撞击力设计公式,以表格的形式给出了设计公式中基本参数的主要取值,并将简化模型和设计公式的计算结果与有限元结果进行了比较.结果表明:根据简化模型和设计公式计算得到的撞击荷载与精细有限元模型的计算结果吻合较好,且偏于安全,可为工程设计提供参考.%In order to make up the insufficient research on the collisions between over-high truck and bridge superstructure in China and to improve the corresponding engineering design method,based on the accident investigation and high precision finite element analysis on the collision between over-high truck and bridge superstructure, a simplified computational model was proposed to calculate the collision between over-high truck and bridge superstructure. The differential equations of the simplified model were established and parts of factors in the model were determined by numerical experiments. Therefore, the collision load can be computed by the simplified model. Furthermore, in order to satisfy the engineering application, design formula of collision force with simple form based on the simplified model was proposed, and the basic factor values in the design formula were given in a table. Results show that the design formula results and the simplified model results are in good agreement with finite element results, and they are relatively safe. So they can provide reference for engineering design.

  1. Wavefield extrapolation in pseudodepth domain

    KAUST Repository

    Ma, Xuxin

    2013-02-01

    Wavefields are commonly computed in the Cartesian coordinate frame. Its efficiency is inherently limited due to spatial oversampling in deep layers, where the velocity is high and wavelengths are long. To alleviate this computational waste due to uneven wavelength sampling, we convert the vertical axis of the conventional domain from depth to vertical time or pseudodepth. This creates a nonorthognal Riemannian coordinate system. Isotropic and anisotropic wavefields can be extrapolated in the new coordinate frame with improved efficiency and good consistency with Cartesian domain extrapolation results. Prestack depth migrations are also evaluated based on the wavefield extrapolation in the pseudodepth domain.© 2013 Society of Exploration Geophysicists. All rights reserved.

  2. Anatomy of Mammalian Replication Domains

    Science.gov (United States)

    Takebayashi, Shin-ichiro; Ogata, Masato; Okumura, Katsuzumi

    2017-01-01

    Genetic information is faithfully copied by DNA replication through many rounds of cell division. In mammals, DNA is replicated in Mb-sized chromosomal units called “replication domains.” While genome-wide maps in multiple cell types and disease states have uncovered both dynamic and static properties of replication domains, we are still in the process of understanding the mechanisms that give rise to these properties. A better understanding of the molecular basis of replication domain regulation will bring new insights into chromosome structure and function. PMID:28350365

  3. Study of Superstructure of Two-Lane Suspension Bridge with Integral Cross Section%整体式断面双车道索道桥上部结构研究

    Institute of Scientific and Technical Information of China (English)

    景天虎; 马小龙; 刘均利; 莫时旭

    2016-01-01

    为寻求整体式断面双车道索道桥上部结构的可行布置形式,采用考虑索梁组合结构几何非线性的空间有限元法,对几种桥面系构造方案的结构特性进行研究。研究结果表明:对于双车道索道桥,活载单车道偏载是比活载双车道同时偏载更为不利的荷载工况;在活载作用下,整个桥面系在横桥向不再保持线性变位;简单地采用横向线性扩展车道宽度的措施来构造双车道索道桥上部结构方案,将很难满足结构横倾稳定性要求;主索在横桥向的不同分布是影响索道桥结构抗扭能力的最主要因素;在桥面中央布置适量的主索对优化横梁内力分布状况是有益的。%To find a rational superstructure configuration for two‐lane suspension bridges with integral cross section ,the spatial finite element method taking into consideration of non‐linearity of cable‐beam composite structure was employed and the structural features of different bridge deck system schemes were studied .The results of the study demonstrate that for a two‐lane suspension bridge ,the load case of single‐lane unbalanced live loads is much more unfavorable than that of two‐lane unbalanced live load .Under the action of live loads ,the overall bridge deck system no longer exhibits linear variation in the transverse bridge direction .To form the superstructure of the two‐lane suspension bridge simply via linear expansion of traffic lanes in the transverse direc‐tion is hard to meet the demands of the transverse overturning stability of the structure .How to arrange the main cables in the transverse direction is the key concerning the torsional capacity of a suspension bridge .Installing a proper amount of main cables in the central part of the bridge deck is good to optimize the internal force distribution in the floor beams .

  4. Critical SQG in bounded domains

    OpenAIRE

    Constantin, Peter; Ignatova, Mihaela

    2016-01-01

    We consider the critical dissipative SQG equation in bounded domains, with the square root of the Dirichlet Laplacian dissipation. We prove global a priori interior $C^{\\alpha}$ and Lipschitz bounds for large data.

  5. Concept Convergence in Empirical Domains

    Science.gov (United States)

    Ontañón, Santiago; Plaza, Enric

    How to achieve shared meaning is a significant issue when more than one intelligent agent is involved in the same domain. We define the task of concept convergence, by which intelligent agents can achieve a shared, agreed-upon meaning of a concept (restricted to empirical domains). For this purpose we present a framework that, integrating computational argumentation and inductive concept learning, allows a pair of agents to (1) learn a concept in an empirical domain, (2) argue about the concept's meaning, and (3) reach a shared agreed-upon concept definition. We apply this framework to marine sponges, a biological domain where the actual definitions of concepts such as orders, families and species are currently open to discussion. An experimental evaluation on marine sponges shows that concept convergence is achieved, within a reasonable number of interchanged arguments, and reaching short and accurate definitions (with respect to precision and recall).

  6. Structure of axionic domain walls

    Science.gov (United States)

    Huang, M. C.; Sikivie, P.

    1985-09-01

    The structure of axionic domain walls is investigated using the low-energy effective theory of axions and pions. We derive the spatial dependence of the phases of the Peccei-Quinn scalar field and the QCD quark-antiquark condensates inside an axionic domain wall. Thence an accurate estimate of the wall surface energy density is obtained. The equations of motion for axions, photons, leptons, and baryons in the neighborhood of axionic domain walls are written down and estimates are given for the wall reflection and transmission coefficients of these particles. Finally, we discuss the energy dissipation by axionic domain walls oscillating in the early universe due to the reflection of particles in the primordial soup.

  7. Structure of axionic domain walls

    Energy Technology Data Exchange (ETDEWEB)

    Huang, M.C.; Sikivie, P.

    1985-09-15

    The structure of axionic domain walls is investigated using the low-energy effective theory of axions and pions. We derive the spatial dependence of the phases of the Peccei-Quinn scalar field and the QCD quark-antiquark condensates inside an axionic domain wall. Thence an accurate estimate of the wall surface energy density is obtained. The equations of motion for axions, photons, leptons, and baryons in the neighborhood of axionic domain walls are written down and estimates are given for the wall reflection and transmission coefficients of these particles. Finally, we discuss the energy dissipation by axionic domain walls oscillating in the early universe due to the reflection of particles in the primordial soup.

  8. Toeplitz operators on connected domains

    Institute of Scientific and Technical Information of China (English)

    CAO; Guangfu

    2006-01-01

    The proof of the index formula of the Toeplitz operator with a continuous symbol on the Hardy space for the unit circle in the complex plane depends on the Hopftheorem. However,the analogue result of the Hopf theorem does not hold on a general connected domain. Hence,the extension of the index formula of the Toeplitz operator on a general domain needs a method which is different from that for the case of the unit circle. In the present paper, the index formula of the Toeplitz operator with a continuous symbol on the finite complex connected domain in the complex plane is obtained, and the cohomology groups of Toeplitz algebras on general domains are discussed. In addition, the Toeplitz operators with symbols in QC are also discussed.

  9. A segmental labeling strategy for unambiguous determination of domain-domain interactions of large multi-domain proteins

    Energy Technology Data Exchange (ETDEWEB)

    Chen Jianglei; Wang Jianjun, E-mail: jjwang@med.wayne.edu [Wayne State University, Department of Biochemistry and Molecular Biology, School of Medicine (United States)

    2011-08-15

    NMR structural determination of large multi-domain proteins is a challenging task due to significant spectral overlap with a particular difficulty in unambiguous identification of domain-domain interactions. Segmental labeling is a NMR strategy that allows for isotopically labeling one domain and leaves the other domain unlabeled. This significantly simplifies spectral overlaps and allows for quick identification of domain-domain interaction. Here, a novel segmental labeling strategy is presented for detection of inter-domain NOEs. To identify domain-domain interactions in human apolipoprotein E (apoE), a multi-domain, 299-residues {alpha}-helical protein, on-column expressed protein ligation was utilized to generate a segmental-labeled apoE samples in which the N-terminal (NT-) domain was {sup 2}H(99%)/{sup 15}N-labeled whereas the C-terminal (CT-) domain was either {sup 15}N- or {sup 15}N/{sup 13}C-labeled. 3-D {sup 15}N-edited NOESY spectra of these segmental-labeled apoE samples allow for direct observation of the inter-domain NOEs between the backbone amide protons of the NT-domain and the aliphatic protons of the CT-domain. This straightforward approach permits unambiguous identification of 78 inter-domain NOEs, enabling accurate definition of the relative positions of both the NT- and the CT-domains and determination of the NMR structure of apoE.

  10. 连续梁拱组合桥梁上部结构施工关键技术研究%On the Key Construction Technology of the Superstructure of Continuous Beam-arch Combination Bridge

    Institute of Scientific and Technical Information of China (English)

    何永泉

    2015-01-01

    随着我国社会水平的提升,经济步伐的推进,我国的交通事业也在这个过程中得到了较大程度的发展。其中,连续梁拱组合桥梁是我国现今桥梁建设中非常重要的一个类型,近年来,已经有很多城市利用该种类型建设桥梁。本文将深入地研究分析连续梁拱组合桥梁上部结构施工关键技术,同时提出相应的政策建议。%With the ascension of social level and the progress of economic, the transportation industry of China also gets a larger degree of development in the process. The combination bridge of continuous beam-arc is a very important type in the current bridge construction of China. In recent years, there are many cities using this type to construct bridges. This paper deeply researches and analyzes the key construction technology of the superstructure of continuous beam-arch combination bridge and puts forward the related policy suggestions.

  11. RE{sub 13}Pd{sub 25+x}Zn{sub 28-x} (RE = Y, Ho-Lu). A 4 x 4 x 4 tungsten superstructure with short Pd/Zn dumbbells as structural motif

    Energy Technology Data Exchange (ETDEWEB)

    Gerke, Birgit; Hoffmann, Rolf-Dieter; Niehaus, Oliver; Poettgen, Rainer [Muenster Univ. (Germany). Inst. fuer Anorganische und Analytische Chemie

    2016-08-01

    The rare earth-based zinc compounds RE{sub 13}Pd{sub 25+x}Zn{sub 28-x} (RE = Y, Ho-Lu) were synthesized from the elements in sealed niobium ampoules with a maximum reaction temperature of 1470 K followed by different annealing sequences. The structures of all compounds were refined from single crystal X-ray diffraction data, indicating substantial Zn/Pd mixing on one 8c and one 24g zinc site. Exemplarily, the homogeneity range of the solid solution Yb{sub 13}Pd{sub 25+x}Zn{sub 28-x} was manifested from samples of different starting compositions and five single crystal data sets. The RE{sub 13}Pd{sub 25+x}Zn{sub 28-x} structures are cubic, space group I anti 43m with lattice parameters ranging from 1295 to 1307 pm, as a function of the rare earth element and the Zn/Pd mixing. Hierarchically, one can derive the RE{sub 13}Pd{sub 25+x}Zn{sub 28-x} structures from the simple bcc packing. A group-subgroup scheme was developed for this new 4 x 4 x 4 tungsten superstructure which shows vacancy ordering and dumbbell formation. Temperature dependent magnetic susceptibility measurements show diamagnetism for a Lu{sub 13}Pd{sub 29}Zn{sub 24} sample and Curie-Weiss paramagnetism for Tm{sub 13}Pd{sub 29}Zn{sub 24} down to 3 K.

  12. Domain Decomposition Solvers for Frequency-Domain Finite Element Equations

    KAUST Repository

    Copeland, Dylan

    2010-10-05

    The paper is devoted to fast iterative solvers for frequency-domain finite element equations approximating linear and nonlinear parabolic initial boundary value problems with time-harmonic excitations. Switching from the time domain to the frequency domain allows us to replace the expensive time-integration procedure by the solution of a simple linear elliptic system for the amplitudes belonging to the sine- and to the cosine-excitation or a large nonlinear elliptic system for the Fourier coefficients in the linear and nonlinear case, respectively. The fast solution of the corresponding linear and nonlinear system of finite element equations is crucial for the competitiveness of this method. © 2011 Springer-Verlag Berlin Heidelberg.

  13. Z-拟代数Domain%Z-Quasialgebraic Domain

    Institute of Scientific and Technical Information of China (English)

    杨金波; 罗懋康

    2005-01-01

    对一般的子集系统Z,引入Z-拟代数domain的概念,证明了Z-domain P是Z-拟代数的当且仅当P上的Z-Scott拓扑σz(P)在集包含序下是代数的超连续格,即超代数格;Z-拟代数domain P上的Z-Scott拓扑σz(P)是Sober的当且仅当空间(P,σz(P))具有弱Rudin性质.

  14. Incommensurate and commensurate modulations of Ba5RTi3Nb7O30 (R = La, Nd) tungsten bronzes and the ferroelectric domain structures

    Science.gov (United States)

    Mao, Min Min; Li, Kun; Zhu, Xiao Li; Chen, Xiang Ming

    2015-04-01

    Incommensurate and commensurate structural modulations of Ba5RTi3Nb7O30 (R = La, Nd) tungsten bronze ceramics were investigated by using a cooling holder equipped transmission electron microscopy in the temperature range from 100 K to 363 K. The incommensurate modulation was observed in both Ba5LaTi3Nb7O30 and Ba5NdTi3Nb7O30 at room temperature, while there was a transition from incommensurate tilted structure to commensurate superstructure for Ba5NdTi3Nb7O30 with decreasing temperature. The incommensurate and commensurate modulations were determined by the A-site occupancy of Ba and R cations. The A-site disorder resulted in larger incommensurability parameter δ and the diffusion of the satellite reflection spots. The effect of A-site disorder on the coupling between long-range dipolar order and the commensurate modulation was also discussed. The obvious ferroelectric 180° domains with spike-like shape parallel to c axis were observed for Ba5NdTi3Nb7O30, while no macro ferroelectric domain was determined for Ba5LaTi3Nb7O30.

  15. Structural, optical and vibrational properties of self-assembled Pbn+1(Ti1-x Fex)nO(3n+1)-δ Ruddlesden-Popper superstructures.

    Science.gov (United States)

    Doig, K I; Peters, J J P; Nawaz, S; Walker, D; Walker, M; Lees, M R; Beanland, R; Sanchez, A M; McConville, C F; Palkar, V R; Lloyd-Hughes, J

    2015-01-16

    Bulk crystals and thin films of PbTi(1-x)FexO3(-δ) (PTFO) are multiferroic, exhibiting ferroelectricity and ferromagnetism at room temperature. Here we report that the Ruddlesden-Popper phase Pbn+1(Ti(1-x)Fex)nO3(n+1)-δ forms spontaneously during pulsed laser deposition of PTFO on LaAlO3 substrates. High-resolution transmission electron microscopy, x-ray diffraction and x-ray photoemission spectroscopy were utilised to perform a structural and compositional analysis, demonstrating that n ≃ 8 and x ≃ 0.5. The complex dielectric function of the films was determined from far-infrared to ultraviolet energies using a combination of terahertz time-domain spectroscopy, Fourier transform spectroscopy, and spectroscopic ellipsometry. The simultaneous Raman and infrared activity of phonon modes and the observation of second harmonic generation establishes a non-centrosymmetric point group for Pbn+1(Ti0.5Fe0.5)nO3(n+1)-δ, a prerequisite for (but not proof of) ferroelectricity. No evidence of macroscopic ferromagnetism was found in SQUID magnetometry. The ultrafast optical response exhibited coherent magnon oscillations compatible with local magnetic order, and additionally was used to study photocarrier cooling on picosecond timescales. An optical gap smaller than that of BiFeO3 and long photocarrier lifetimes may make this system interesting as a ferroelectric photovoltaic.

  16. Learning processes across knowledge domains

    DEFF Research Database (Denmark)

    Hall-Andersen, Lene Bjerg; Broberg, Ole

    2014-01-01

    organization, it remained discrete in 'pockets' of learning; mainly at an individual level, at project level or as domain-specific learning. Learning processes were intertwined with elements of domain-specific interests, power, managerial support, structural conditions, material and epistemic differences...... informed by selected perspectives on learning processes and boundary processes was applied on three illustrative vignettes to illuminate learning potentials and shortcomings in boundary processes. Findings - In the engineering consultancy, it was found that while learning did occur in the consultancy......Purpose - The purpose of this paper is to shed light on the problematics of learning across knowledge boundaries in organizational settings. The paper specifically explores learning processes that emerge, when a new knowledge domain is introduced into an existing organizational practice...

  17. Domain similarity based orthology detection.

    Science.gov (United States)

    Bitard-Feildel, Tristan; Kemena, Carsten; Greenwood, Jenny M; Bornberg-Bauer, Erich

    2015-05-13

    Orthologous protein detection software mostly uses pairwise comparisons of amino-acid sequences to assert whether two proteins are orthologous or not. Accordingly, when the number of sequences for comparison increases, the number of comparisons to compute grows in a quadratic order. A current challenge of bioinformatic research, especially when taking into account the increasing number of sequenced organisms available, is to make this ever-growing number of comparisons computationally feasible in a reasonable amount of time. We propose to speed up the detection of orthologous proteins by using strings of domains to characterize the proteins. We present two new protein similarity measures, a cosine and a maximal weight matching score based on domain content similarity, and new software, named porthoDom. The qualities of the cosine and the maximal weight matching similarity measures are compared against curated datasets. The measures show that domain content similarities are able to correctly group proteins into their families. Accordingly, the cosine similarity measure is used inside porthoDom, the wrapper developed for proteinortho. porthoDom makes use of domain content similarity measures to group proteins together before searching for orthologs. By using domains instead of amino acid sequences, the reduction of the search space decreases the computational complexity of an all-against-all sequence comparison. We demonstrate that representing and comparing proteins as strings of discrete domains, i.e. as a concatenation of their unique identifiers, allows a drastic simplification of search space. porthoDom has the advantage of speeding up orthology detection while maintaining a degree of accuracy similar to proteinortho. The implementation of porthoDom is released using python and C++ languages and is available under the GNU GPL licence 3 at http://www.bornberglab.org/pages/porthoda .

  18. Ubiquitin domain proteins in disease

    DEFF Research Database (Denmark)

    Klausen, Louise Kjær; Schulze, Andrea; Seeger, Michael

    2007-01-01

    The human genome encodes several ubiquitin-like (UBL) domain proteins (UDPs). Members of this protein family are involved in a variety of cellular functions and many are connected to the ubiquitin proteasome system, an essential pathway for protein degradation in eukaryotic cells. Despite their s...... and cancer. Publication history: Republished from Current BioData's Targeted Proteins database (TPdb; http://www.targetedproteinsdb.com).......The human genome encodes several ubiquitin-like (UBL) domain proteins (UDPs). Members of this protein family are involved in a variety of cellular functions and many are connected to the ubiquitin proteasome system, an essential pathway for protein degradation in eukaryotic cells. Despite...

  19. Domain wall description of superconductivity

    Energy Technology Data Exchange (ETDEWEB)

    Brito, F.A. [Departamento de Física, Universidade Federal de Campina Grande, Caixa Postal 10071, 58109-970 Campina Grande, Paraíba (Brazil); Freire, M.L.F. [Departamento de Física, Universidade Estadual da Paraíba, 58109-753 Campina Grande, Paraíba (Brazil); Mota-Silva, J.C. [Departamento de Física, Universidade Federal de Campina Grande, Caixa Postal 10071, 58109-970 Campina Grande, Paraíba (Brazil); Departamento de Física, Universidade Federal da Paraíba, Caixa Postal 5008, 58051-970 João Pessoa, Paraíba (Brazil)

    2014-01-20

    In the present work we shall address the issue of electrical conductivity in superconductors in the perspective of superconducting domain wall solutions in the realm of field theory. We take our set up made out of a dynamical complex scalar field coupled to gauge field to be responsible for superconductivity and an extra scalar real field that plays the role of superconducting domain walls. The temperature of the system is interpreted through the fact that the soliton following accelerating orbits is a Rindler observer experiencing a thermal bath.

  20. The evolutionary history of protein domains viewed by species phylogeny

    National Research Council Canada - National Science Library

    Yang, Song; Bourne, Philip E

    2009-01-01

    .... The evolutionary history of protein domains, including the origin of protein domains, the identification of domain loss, transfer, duplication and combination with other domains to form new proteins...

  1. Inferring domain-domain interactions from protein-protein interactions with formal concept analysis.

    Directory of Open Access Journals (Sweden)

    Susan Khor

    Full Text Available Identifying reliable domain-domain interactions will increase our ability to predict novel protein-protein interactions, to unravel interactions in protein complexes, and thus gain more information about the function and behavior of genes. One of the challenges of identifying reliable domain-domain interactions is domain promiscuity. Promiscuous domains are domains that can occur in many domain architectures and are therefore found in many proteins. This becomes a problem for a method where the score of a domain-pair is the ratio between observed and expected frequencies because the protein-protein interaction network is sparse. As such, many protein-pairs will be non-interacting and domain-pairs with promiscuous domains will be penalized. This domain promiscuity challenge to the problem of inferring reliable domain-domain interactions from protein-protein interactions has been recognized, and a number of work-arounds have been proposed. This paper reports on an application of Formal Concept Analysis to this problem. It is found that the relationship between formal concepts provides a natural way for rare domains to elevate the rank of promiscuous domain-pairs and enrich highly ranked domain-pairs with reliable domain-domain interactions. This piggybacking of promiscuous domain-pairs onto less promiscuous domain-pairs is possible only with concept lattices whose attribute-labels are not reduced and is enhanced by the presence of proteins that comprise both promiscuous and rare domains.

  2. Computations of Bergman Kernels on Hua Domains

    Institute of Scientific and Technical Information of China (English)

    殷慰萍; 王安; 赵振刚; 赵晓霞; 管冰辛

    2001-01-01

    @@The Bergman kernel function plays an important ro1e in several complex variables.There exists the Bergman kernel function on any bounded domain in Cn. But we can get the Bergman kernel functions in explicit formulas for a few types of domains only,for example:the bounded homogeneous domains and the egg domain in some cases.

  3. A Method to Examine Content Domain Structures

    Science.gov (United States)

    D'Agostino, Jerome; Karpinski, Aryn; Welsh, Megan

    2011-01-01

    After a test is developed, most content validation analyses shift from ascertaining domain definition to studying domain representation and relevance because the domain is assumed to be set once a test exists. We present an approach that allows for the examination of alternative domain structures based on extant test items. In our example based on…

  4. Categorization in the Affective Domain

    DEFF Research Database (Denmark)

    Sauciuc, Gabriela-Alina

    2011-01-01

    Data collected in Romance and Scandinavian languages (N=474) in a superordinate category name production task indicate that a multiple-strategy approach would be more suitable for accounting of categorization in the affective domain instead of a prototype approach as suggested by previous studies...

  5. Nonlinear Evolution of Ferroelectric Domains

    Institute of Scientific and Technical Information of China (English)

    WeiLU; Dai-NingFANG; 等

    1997-01-01

    The nonlinear evolution of ferroelectric domains is investigated in the paper and amodel is proposed which can be applied to numerical computation.Numerical results show that the model can accurately predict some nonlinear behavior and consist with those experimental results.

  6. Overlap/Domain-wall reweighting

    CERN Document Server

    Fukaya, H; Cossu, G; Hashimoto, S; Kaneko, T; Noaki, J

    2013-01-01

    We investigate the eigenvalues of nearly chiral lattice Dirac operators constructed with five-dimensional implementations. Allowing small violation of the Ginsparg-Wilson relation, the HMC simulation is made much faster while the eigenvalues are not significantly affected. We discuss the possibility of reweighting the gauge configurations generated with domain-wall fermions to those of exactly chiral lattice fermions.

  7. The Distributed-SDF Domain

    DEFF Research Database (Denmark)

    Cuadrado, Daniel Lázaro; Ravn, Anders Peter; Koch, Peter

    2005-01-01

    . Those relations are in charge of receiving the tokens and placing them at the right receiver. The same goes for the output ports. Tokens are sent over the net to the distributed processes that are expecting to receive them. The distributed-SDF domain provides certain advantages derived from its...

  8. Cellulose binding domain fusion proteins

    Science.gov (United States)

    Shoseyov, Oded; Shpiegl, Itai; Goldstein, Marc A.; Doi, Roy H.

    1998-01-01

    A cellulose binding domain (CBD) having a high affinity for crystalline cellulose and chitin is disclosed, along with methods for the molecular cloning and recombinant production thereof. Fusion products comprising the CBD and a second protein are likewise described. A wide range of applications are contemplated for both the CBD and the fusion products, including drug delivery, affinity separations, and diagnostic techniques.

  9. Development in the Food Domain.

    Science.gov (United States)

    Rozin, Paul

    1990-01-01

    Discusses problems of general interest in developmental psychology that can be successfully studied in the domain of food; these include (1) development of food likes and dislikes; (2) establishment of the edible/inedible distinction; (3) disgust and contagion; (4) transgenerational communication of preferences; and (5) transition to food…

  10. Frequency-Domain Optical Mammogram

    Science.gov (United States)

    2002-10-01

    the tumor. * Combination of the above two points into a composite false-color breast image containing structural information (from the second...Antonangeli, A. Savoia, T. Parasassi, and N. Rosato, " Plastique : a synchrotron radiation beamline for time resolved fluorescence in the frequency domain

  11. Partial domain wall partition functions

    CERN Document Server

    Foda, O

    2012-01-01

    We consider six-vertex model configurations on a rectangular lattice with n (N) horizontal (vertical) lines, and "partial domain wall boundary conditions" defined as 1. all 2n arrows on the left and right boundaries point inwards, 2. n_u (n_l) arrows on the upper (lower) boundary, such that n_u + n_l = N - n, also point inwards, 3. all remaining n+N arrows on the upper and lower boundaries point outwards, and 4. all spin configurations on the upper and lower boundaries are summed over. To generate (n-by-N) "partial domain wall configurations", one can start from A. (N-by-N) configurations with domain wall boundary conditions and delete n_u (n_l) upper (lower) horizontal lines, or B. (2n-by-N) configurations that represent the scalar product of an n-magnon Bethe eigenstate and an n-magnon generic state on an N-site spin-1/2 chain, and delete the n lines that represent the Bethe eigenstate. The corresponding "partial domain wall partition function" is computed in construction {A} ({B}) as an N-by-N (n-by-n) det...

  12. Life sciences domain analysis model.

    Science.gov (United States)

    Freimuth, Robert R; Freund, Elaine T; Schick, Lisa; Sharma, Mukesh K; Stafford, Grace A; Suzek, Baris E; Hernandez, Joyce; Hipp, Jason; Kelley, Jenny M; Rokicki, Konrad; Pan, Sue; Buckler, Andrew; Stokes, Todd H; Fernandez, Anna; Fore, Ian; Buetow, Kenneth H; Klemm, Juli D

    2012-01-01

    Meaningful exchange of information is a fundamental challenge in collaborative biomedical research. To help address this, the authors developed the Life Sciences Domain Analysis Model (LS DAM), an information model that provides a framework for communication among domain experts and technical teams developing information systems to support biomedical research. The LS DAM is harmonized with the Biomedical Research Integrated Domain Group (BRIDG) model of protocol-driven clinical research. Together, these models can facilitate data exchange for translational research. The content of the LS DAM was driven by analysis of life sciences and translational research scenarios and the concepts in the model are derived from existing information models, reference models and data exchange formats. The model is represented in the Unified Modeling Language and uses ISO 21090 data types. The LS DAM v2.2.1 is comprised of 130 classes and covers several core areas including Experiment, Molecular Biology, Molecular Databases and Specimen. Nearly half of these classes originate from the BRIDG model, emphasizing the semantic harmonization between these models. Validation of the LS DAM against independently derived information models, research scenarios and reference databases supports its general applicability to represent life sciences research. The LS DAM provides unambiguous definitions for concepts required to describe life sciences research. The processes established to achieve consensus among domain experts will be applied in future iterations and may be broadly applicable to other standardization efforts. The LS DAM provides common semantics for life sciences research. Through harmonization with BRIDG, it promotes interoperability in translational science.

  13. Domain specific MT in use

    DEFF Research Database (Denmark)

    Offersgaard, Lene; Povlsen, Claus; Almsten, Lisbeth Kjeldgaard

    2008-01-01

    The paper focuses on domain specific use of MT with a special focus on SMT in the workflow of a Language Service Provider (LSP). We report on the feedback of post-editors using fluency/adequacy evaluation and the evaluation metric ’Usability’, understood in this context as where users on a three ...

  14. Weakly distributive domains(Ⅱ)

    Institute of Scientific and Technical Information of China (English)

    JIANG Ying; ZHANG Guo-Qiang

    2007-01-01

    In our previous work(Inform.and Comput.,2005,202:87-103),we have shown that for any ω-algebraic meet-cpo D,if all higher-order stable function spaces built from D are ω-algebraic,then D is finitary.This accomplishes the first of a possible,two-step process in solving the problem raised(LNCS,1991,530:16-33;Domainsand lambda-calculi,Cambridge Univ.Press,1998)whetherthe category of stable bifinite domains of Amadio-Droste-G(o)bel(LNCS,1991,530:16-33;Theor.Comput.Sci.,1993,111:89-101)is the largest cartesian closed full subcategory within the category of ω-algebraic meet-cpos with stable functions.This paper presents the results of the second step,which is to show that for any ω-algebraic meet-cpo D satisfying axioms M and I to be contained in a cartesian closed full sub-category using ω-algebraic meet-cpos with stable functions,it must not violate M I∞.We introduce a new class of domains called weakly distributive domains and show that for these domains to be in a cartesian closed category using ω-algebraic meet-cpos,property M I must not be violated.Further,we demonstrate that principally distributive domains(those for which each principle ideal is distributive)form a proper subclass of weakly distributive domains,and Birkhoff's M3 and N5(Introduction to Lattices and order,Cambridge Univ.Press,2002)are weakly distributive(but non-distributive).Then,we establish characterization results for weakly distributive domains.We also introduce the notion of meet-generators in constructing stable functions and show that if an ω-algebraic meet-cpo D contains an infinite number of meet-generators,then[D→D]fails I.However,the original problem of Amadio and Curien remains open.

  15. Domains of Awareness in Schizophrenia

    Science.gov (United States)

    Gilleen, J.; Greenwood, K.; David, A. S.

    2011-01-01

    Patients with schizophrenia are often characterized as lacking insight or awareness into their illness and symptoms, yet despite considerable research, we still lack a full understanding of the factors involved in causing poor awareness. Within schizophrenia, there has been shown to be a fractionation across dimensions of awareness into mental illness: of being ill, of symptoms, and of treatment compliance. Recently, attention has turned to evidence of a fractionation between awareness of illness and of cognitive impairments and functioning. The current study investigated the degree of fractionation across a broad range of domains of function in schizophrenia and how each domain may be associated with neuropsychological functioning, clinical, mood, and demographic variables. Thirty-one mostly chronic stable patients with schizophrenia completed a battery of neuropsychological tests and measures of psychopathology, including mood. Cognitive insight and awareness of illness, symptoms, memory, and behavioral functioning were also measured. Insight and awareness were assessed using a combination of semistructured interview, observer-rated, self-rated, and objective measures, and included measures of the discrepancy between carer and self-ratings of impairment. Results revealed that awareness of functioning in each domain was largely independent and that awareness in each domain was predicted by different factors. Insight into symptoms was relatively poor while insight into cognitive deficits was preserved. Relative to neuropsychological variables, cognitive insight, comprising self-certainty and self-reflexivity, was a greater predictor of awareness. In conclusion, awareness is multiply fractionated and multiply determined. Therapeutic interventions could, therefore, produce beneficial changes within specific domains of awareness. PMID:20851850

  16. Diffusion-damped domain wall dynamics

    Energy Technology Data Exchange (ETDEWEB)

    Varga, R; Infante, G [Inst. Phys., Fac. Sci., UPJS, Park Angelinum 9, 04154 Kosice (Slovakia); Badini-Confalonieri, G A; Vazquez, M, E-mail: rvarga@upjs.s [Instituto de Ciencia de Materiales de Madrid, CSIC, Cantoblanco, 28049, Madrid (Spain)

    2010-01-01

    In the given work, the influence of diffusional damping on the domain wall dynamics of heat treated FeSiBP microwires is presented. Two regions of the domain wall dynamics have been found. At low applied fields diffusion damping prevails, keeping the domain wall velocity and mobility low. At higher fields, the diffusional effects are overcomed and domain wall velocity increases steeply and so does the domain wall mobility.

  17. Evolution studied through protein structural domains

    OpenAIRE

    YANG, SONG

    2007-01-01

    A protein structural domain is defined as a compact, spatially distinct part of a protein that can fold independently of neighboring sequences. Since the number of protein domains is limited, and protein domains are evolutionarily more conserved than protein sequences, protein domains play an important role in our understanding of the structure, function and evolution of proteins. As fundamental evolutionary units, protein domains are associated with a variety of evolutionary processes such a...

  18. Decomposition and Removability Properties of John Domains

    Indian Academy of Sciences (India)

    M Huang; S Ponnusamy; X Wang

    2008-08-01

    In this paper we characterize John domains in terms of John domain decomposition property. In addition, we also show that a domain in $\\mathbb{R}^n$ is a John domain if and only if $D\\backslash P$ is a John domain, where is a subset of containing finitely many points of . The best possibility and an application of the second result are also discussed.

  19. IMPLICATIONS OF CROSS DOMAIN FIRES IN MULTI-DOMAIN BATTLE

    Science.gov (United States)

    2017-04-06

    Adversaries saw the success of AirLand battle and sought ways to fracture the concept. Today, as adversaries leverage technological advances... two -dimensions that the US military is accustomed to fighting in. In accordance with the projected trends occurring in the forthcoming security...capabilities and limitations of our enemy to include the terrain that we would be contending with throughout operations. There were only two viable domains

  20. PUBLIC DOMAIN PROTECTION. USES AND REUSES OF PUBLIC DOMAIN WORKS

    OpenAIRE

    Monica Adriana LUPAȘCU

    2015-01-01

    This study tries to highlight the necessity of an awareness of the right of access to the public domain, particularly using the example of works whose protection period has expired, as well as the ones which the law considers to be excluded from protection. Such works are used not only by large libraries from around the world, but also by rights holders, via different means of use, including incorporations into original works or adaptations. However, the reuse that follows these uses often on...

  1. DIMA 3.0: Domain Interaction Map.

    Science.gov (United States)

    Luo, Qibin; Pagel, Philipp; Vilne, Baiba; Frishman, Dmitrij

    2011-01-01

    Domain Interaction MAp (DIMA, available at http://webclu.bio.wzw.tum.de/dima) is a database of predicted and known interactions between protein domains. It integrates 5807 structurally known interactions imported from the iPfam and 3did databases and 46,900 domain interactions predicted by four computational methods: domain phylogenetic profiling, domain pair exclusion algorithm correlated mutations and domain interaction prediction in a discriminative way. Additionally predictions are filtered to exclude those domain pairs that are reported as non-interacting by the Negatome database. The DIMA Web site allows to calculate domain interaction networks either for a domain of interest or for entire organisms, and to explore them interactively using the Flash-based Cytoscape Web software.

  2. A Domain Specific DSP Processor

    OpenAIRE

    Tell, Eric

    2001-01-01

    This thesis describes the design of a domain specific DSP processor. The thesis is divided into two parts. The first part gives some theoretical background, describes the different steps of the design process (both for DSP processors in general and for this project) and motivates the design decisions made for this processor. The second part is a nearly complete design specification. The intended use of the processor is as a platform for hardware acceleration units. Support for this has howe...

  3. Balanced metrics on Hartogs domains

    CERN Document Server

    Loi, Andrea

    2010-01-01

    An n-dimensional strictly pseudoconvex Hartogs domain $D_F$ can be equipped with a natural Kaehler metric g_F. In this paper we prove that if m_0g_F is balanced for a given positive integer m_0 then m_0>n and (D_F, g_F) is holomorphically isometric to an open subset of the n-dimensional complex hyperbolic space.

  4. Superconductivity in domains with corners

    DEFF Research Database (Denmark)

    Bonnaillie-Noel, Virginie; Fournais, Søren

    2007-01-01

    We study the two-dimensional Ginzburg-Landau functional in a domain with corners for exterior magnetic field strengths near the critical field where the transition from the superconducting to the normal state occurs. We discuss and clarify the definition of this field and obtain a complete...... asymptotic expansion for it in the large $\\kappa$ regime. Furthermore, we discuss nucleation of superconductivity at the boundary....

  5. Domain Relaxation in Langmuir Films

    Science.gov (United States)

    Bernoff, Andrew J.; Alexander, James C.; Mann, Elizabeth K.; Mann, J. Adin; Zou, Lu; Wintersmith, Jacob R.

    2007-11-01

    We report on an experimental, theoretical and computational study of a molecularly thin polymer Langmuir layer domain on the surface of a subfluid. When stretched (by a transient stagnation flow), the Langmuir layer takes the form of a bola consisting of two roughly circular reservoirs connected by a thin tether. This shape relaxes to the circular minimum energy configuration. The tether is never observed to rupture, even when it is more than a hundred times as long as it is thin. We model these experiments as a free boundary problem where motion is driven by the line tension of the domain and damped by the viscosity of the subfluid. We process the digital images of the experiment to extract the domain shape, use one of these shapes as an initial condition for the numerical solution of a boundary-integral model of the underlying hydrodynamics, and compare the subsequent images of the experiment to the numerical simulation. The numerical evolutions verify that our hydrodynamical model can reproduce the observed dynamics. They also allow us to deduce the magnitude of the line tension in the system, often to within 1%.

  6. Subharmonic Fourier domain mode locking.

    Science.gov (United States)

    Eigenwillig, Christoph M; Wieser, Wolfgang; Biedermann, Benjamin R; Huber, Robert

    2009-03-15

    We demonstrate a subharmonically Fourier domain mode-locked wavelength-swept laser source with a substantially reduced cavity fiber length. In contrast to a standard Fourier domain mode-locked configuration, light is recirculated repetitively in the delay line with the optical bandpass filter used as switch. The laser has a fundamental optical round trip frequency of 285 kHz and can be operated at integer fractions thereof (subharmonics). Sweep ranges up to 95 nm full width centred at 1317 nm are achieved at the 1/5th subharmonic. A maximum sensitivity of 116 dB and an axial resolution of 12 microm in air are measured at an average sweep power of 12 mW. A sensitivity roll-off of 11 dB over 4 mm and 25 dB over 10 mm is observed and optical coherence tomography imaging is demonstrated. Besides the advantage of a reduced fiber length, subharmonic Fourier domain mode locking (shFDML) enables simple scaling of the sweep speed by extracting light from the delay part of the resonator. A sweep rate of 570 kHz is achieved. Characteristic features of shFDML operation, such as power leakage during fly-back and cw breakthrough, are investigated.

  7. HIGH PRECISION FINITE ELEMENT SIMULATION AND SIMPLIFIED CALCULATION FOR THE COLLISION LOAD BETWEEN OVER-HIGH TRUCK AND BRIDGE SUPERSTRUCTURE%超高车辆-桥梁上部结构碰撞荷载精细有限元模拟与简化计算

    Institute of Scientific and Technical Information of China (English)

    张炎圣; 陆新征; 叶列平; 何水涛

    2011-01-01

    近年,超高车辆撞击桥梁上部结构问题成为城市交通安全的重要威胁.为减少超高车辆撞击桥梁上部结构造成的损失,关键是准确计算撞击荷载.该文首先基于精细有限元,对超高车辆-桥梁上部结构碰撞过程进行了模拟,对影响撞击的主要参数进行了分析.进而通过忽略次要影响因素,对车辆、桥梁受力行为进行合理简化,建立了超高车辆-桥梁上部结构碰撞的简化计算模型.简化模型与精细有限元模型的撞击力时程结果吻合较好,可为工程设计提供参考.%Recently the collisions between over-high trucks and bridge superstructures have become a serious threaten to the safety of city traffic. In order to reduce the loss due to collision accidents, it's critical to precisely calculate the collision loads. This work firstly simulates the collision process between over-high trucks and bridge superstructures based on high precision finite element model, with primary influencing factors that control the collision loads being discussed. Then by ignoring the minor influencing factors, a simplified model for the collision between over-high trucks and bridge superstructures has been developed. The time-history results of simplified model agree well with those of the high precision finite element model, thus the proposed simplified model can be used in practical application.

  8. The YARHG domain: an extracellular domain in search of a function.

    Directory of Open Access Journals (Sweden)

    Penny Coggill

    Full Text Available We have identified a new bacterial protein domain that we hypothesise binds to peptidoglycan. This domain is called the YARHG domain after the most highly conserved sequence-segment. The domain is found in the extracellular space and is likely to be composed of four alpha-helices. The domain is found associated with protein kinase domains, suggesting it is associated with signalling in some bacteria. The domain is also found associated with three different families of peptidases. The large number of different domains that are found associated with YARHG suggests that it is a useful functional module that nature has recombined multiple times.

  9. Beyond cross-domain learning: Multiple-domain nonnegative matrix factorization

    KAUST Repository

    Wang, Jim Jing-Yan

    2014-02-01

    Traditional cross-domain learning methods transfer learning from a source domain to a target domain. In this paper, we propose the multiple-domain learning problem for several equally treated domains. The multiple-domain learning problem assumes that samples from different domains have different distributions, but share the same feature and class label spaces. Each domain could be a target domain, while also be a source domain for other domains. A novel multiple-domain representation method is proposed for the multiple-domain learning problem. This method is based on nonnegative matrix factorization (NMF), and tries to learn a basis matrix and coding vectors for samples, so that the domain distribution mismatch among different domains will be reduced under an extended variation of the maximum mean discrepancy (MMD) criterion. The novel algorithm - multiple-domain NMF (MDNMF) - was evaluated on two challenging multiple-domain learning problems - multiple user spam email detection and multiple-domain glioma diagnosis. The effectiveness of the proposed algorithm is experimentally verified. © 2013 Elsevier Ltd. All rights reserved.

  10. Bergman kernel on generalized exceptional Hua domain

    Institute of Scientific and Technical Information of China (English)

    YIN; weipng(殷慰萍); ZHAO; zhengang(赵振刚)

    2002-01-01

    We have computed the Bergman kernel functions explicitly for two types of generalized exceptional Hua domains, and also studied the asymptotic behavior of the Bergman kernel function of exceptional Hua domain near boundary points, based on Appell's multivariable hypergeometric function.

  11. Configurable Monitoring for Multi-domain Networks

    OpenAIRE

    Belghith, Aymen; Cousin, Bernard; Lahoud, Samer

    2014-01-01

    International audience; In this paper, we review the state-of-the-art monitoring architectures proposed for multi-domain networks. We establish the five requirements a multi-domain monitoring architecture must fulfilled. We note that these architectures do not support measurement configuration that enables the providers to perform flexible multi-domain measurements. Therefore, we propose a configurable multi-domain network monitoring architecture in order to give more flexibility in monitorin...

  12. The Bergman kernel functions on Hua domains

    Institute of Scientific and Technical Information of China (English)

    2001-01-01

    We get the Bergman kernel functions in explicit formulas on four types of Hua domain.There are two key steps: First, we give the holomorphic automorphism groups of four types of Hua domain; second, we introduce the concept of semi-Reinhardt domain and give their complete orthonormal systems. Based on these two aspects we obtain the Bergman kernel function in explicit formulas on Hua domains.

  13. Emergence of novel domains in proteins

    OpenAIRE

    Toll-Riera, Macarena; Albà Soler, Mar

    2013-01-01

    Background Proteins are composed of a combination of discrete, well-defined, sequence domains, associated with specific functions that have arisen at different times during evolutionary history. The emergence of novel domains is related to protein functional diversification and adaptation. But currently little is known about how novel domains arise and how they subsequently evolve. Results To gain insights into the impact of recently emerged domains in protein evolution we have identified all...

  14. Generic domain models in software engineering

    Science.gov (United States)

    Maiden, Neil

    1992-01-01

    This paper outlines three research directions related to domain-specific software development: (1) reuse of generic models for domain-specific software development; (2) empirical evidence to determine these generic models, namely elicitation of mental knowledge schema possessed by expert software developers; and (3) exploitation of generic domain models to assist modelling of specific applications. It focuses on knowledge acquisition for domain-specific software development, with emphasis on tool support for the most important phases of software development.

  15. Defining Domain Language of Graphical User Interfaces

    OpenAIRE

    Baciková, Michaela; PORUBÄN Jaroslav; Lakatos, Dominik

    2013-01-01

    Domain-specific languages are computer (programming, modeling, specification) languages devoted to solving problems in a specific domain. The least examined DSL development phases are analysis and design. Various formal methodologies exist, however domain analysis is still done informally most of the time. There are also methodologies of deriving DSLs from existing ontologies but the presumption is to have an ontology for the specific domain. We propose a solution of a user interface driven d...

  16. Defining Domain Language of Graphical User Interfaces

    OpenAIRE

    Baciková, Michaela; PORUBÄN Jaroslav; Lakatos, Dominik

    2013-01-01

    Domain-specific languages are computer (programming, modeling, specification) languages devoted to solving problems in a specific domain. The least examined DSL development phases are analysis and design. Various formal methodologies exist, however domain analysis is still done informally most of the time. There are also methodologies of deriving DSLs from existing ontologies but the presumption is to have an ontology for the specific domain. We propose a solution of a user interface driven d...

  17. Safe domain and elementary geometry

    CERN Document Server

    Richard, J M

    2004-01-01

    A classical problem of mechanics involves a projectile fired from a given point with a given velocity whose direction is varied. This results in a family of trajectories whose envelope defines the border of a 'safe' domain. In the simple cases of a constant force, harmonic potential and Kepler or Coulomb motion, the trajectories are conic curves whose envelope in a plane is another conic section which can be derived either by simple calculus or by geometrical considerations. The case of harmonic forces reveals a subtle property of the maximal sum of distances within an ellipse.

  18. Wavelet transform domain communication systems

    Science.gov (United States)

    Orr, Richard S.; Pike, Cameron; Lyall, Michael J.

    1995-04-01

    In this paper we introduce a new class of communications systems called wavelet transform domain (WTD) systems. WTD systems are transmultiplexer (TMUX) structures in which information to be communicated over a channel is encoded, via an inverse discrete wavelet transform (IDWT), as the wavelet coefficients of the transmitted signal, and extracted at the receiver by a discrete wavelet transform (DWT). WTD constructs can be used for covert, or low probability of intercept/detection (LPI/D) communications, baseband bandwidth efficient communications, or code-division multiple access (CDMA). This paper concentrates on the spread spectrum applications.

  19. Securing the Domain Name System

    OpenAIRE

    Massey, Daniel; Denning, Dorothy E.

    2009-01-01

    The article of record as published may be located at http://dx.doi.org/10.1109/MSP.2009.121 The Domain Name System (DNS) is a critical part of the Internet infrastructure. Virtually every Internet application depends on some form of DNS data, yet access to and the reliability of that data aren't assured. DNS attacks and abuses, meanwhile, are increasingly common and sophisticated. Part of the problem is that security wasn't a major goal of the original DNS design. The DNS community has...

  20. A Domain Standard for Land Administration

    NARCIS (Netherlands)

    Lemmen, C.; Van Oosterom, P.; Van der Molen, P.

    2013-01-01

    This paper presents the design of a Domain Model for Land Administration (LA). As a result a formal International Standard is available: ISO 19152 Geographic Information – Land Administration Domain Model (LADM) (ISO, 2012). Domain specific standardisation is needed to capture the semantics of the

  1. Static domain wall in braneworld gravity

    Energy Technology Data Exchange (ETDEWEB)

    Abdalla, M.C.B.; Carlesso, P.F. [UNESP, Universidade Estadual Paulista, Instituto de Fisica Teiorica, Rua Dr. Bento Teobaldo Ferraz 271, Bloco II, Barra-Funda, Caixa Postal 70532-2, Sao Paulo, SP (Brazil); Hoff da Silva, J.M. [UNESP, Universidade Estadual Paulista, Departamento de Fisica e Quimica, Guaratingueta, SP (Brazil)

    2014-01-15

    In this paper we consider a static domain wall inside a 3-brane. Different from the standard achievement obtained in General Relativity, the analysis performed here gives a consistency condition for the existence of static domain walls in a braneworld gravitational scenario. Also the behavior of the domain wall's gravitational field in the newtonian limit is shown. (orig.)

  2. On the structure of order domains

    DEFF Research Database (Denmark)

    Geil, Olav; Pellikaan, Ruud

    2002-01-01

    The notion of an order domain is generalized. The behaviour of an order domain by taking a subalgebra, the extension of scalars, and the tensor product is studied. The relation of an order domain with valuation theory, Gröbner algebras, and graded structures is given. The theory of Gröbner bases ...

  3. Pectin Homogalacturonans: Nanostructural Characterization of Methylesterified Domains

    Science.gov (United States)

    Functionality of pectic hydrocolloids is largely dependent on the two major domains commonly found in their homogalacturonan (HG) regions, i.e., methylester protected domains (MPDs)and non methylesterified domains (NMDs). MPDs can participate in hydrogen bonding and hydrophobic interactions but unli...

  4. Teaching-Learning in the Affective Domain

    Science.gov (United States)

    Holt, Brett J.; Hannon, James C.

    2006-01-01

    Affect is an important domain in which children learn. The affective domain of learning in physical education focuses on feelings, values, social behavior, and attitudes as they relate to human movement. Learning in the affective domain in physical education means that students learn such concepts as sportsmanship, "fair play," respect for others,…

  5. One Health Core Competency Domains.

    Science.gov (United States)

    Frankson, Rebekah; Hueston, William; Christian, Kira; Olson, Debra; Lee, Mary; Valeri, Linda; Hyatt, Raymond; Annelli, Joseph; Rubin, Carol

    2016-01-01

    The emergence of complex global challenges at the convergence of human, animal, and environmental health has catalyzed a movement supporting "One Health" approaches. Despite recognition of the importance of One Health approaches to address these complex challenges, little effort has been directed at identifying the seminal knowledge, skills, and attitudes necessary for individuals to successfully contribute to One Health efforts. Between 2008 and 2011, three groups independently embarked on separate initiatives to identify core competencies for professionals involved with One Health approaches. Core competencies were considered critically important for guiding curriculum development and continuing professional education, as they describe the knowledge, skills, and attitudes required to be effective. A workshop was convened in 2012 to synthesize the various strands of work on One Health competencies. Despite having different mandates, participants, and approaches, all of these initiatives identified similar core competency domains: management; communication and informatics; values and ethics; leadership; teams and collaboration; roles and responsibilities; and systems thinking. These core competency domains have been used to develop new continuing professional education programs for One Health professionals and help university curricula prepare new graduates to be able to contribute more effectively to One Health approaches.

  6. One Health Core Competency Domains

    Science.gov (United States)

    Frankson, Rebekah; Hueston, William; Christian, Kira; Olson, Debra; Lee, Mary; Valeri, Linda; Hyatt, Raymond; Annelli, Joseph; Rubin, Carol

    2016-01-01

    The emergence of complex global challenges at the convergence of human, animal, and environmental health has catalyzed a movement supporting “One Health” approaches. Despite recognition of the importance of One Health approaches to address these complex challenges, little effort has been directed at identifying the seminal knowledge, skills, and attitudes necessary for individuals to successfully contribute to One Health efforts. Between 2008 and 2011, three groups independently embarked on separate initiatives to identify core competencies for professionals involved with One Health approaches. Core competencies were considered critically important for guiding curriculum development and continuing professional education, as they describe the knowledge, skills, and attitudes required to be effective. A workshop was convened in 2012 to synthesize the various strands of work on One Health competencies. Despite having different mandates, participants, and approaches, all of these initiatives identified similar core competency domains: management; communication and informatics; values and ethics; leadership; teams and collaboration; roles and responsibilities; and systems thinking. These core competency domains have been used to develop new continuing professional education programs for One Health professionals and help university curricula prepare new graduates to be able to contribute more effectively to One Health approaches. PMID:27679794

  7. One Health Core Competency Domains

    Directory of Open Access Journals (Sweden)

    Rebekah Frankson

    2016-09-01

    Full Text Available The emergence of complex global challenges at the convergence of human, animal, and environmental health has catalyzed a movement supporting ‘One Health’ approaches. Despite recognition of the importance of One Health approaches to address these complex challenges, little effort has been directed at identifying the seminal knowledge, skills and attitudes necessary for individuals to successfully contribute to One Health efforts. Between 2008 and 2011, three groups independently embarked on separate initiatives to identify core competencies for professionals involved with One Health approaches. Core competencies were considered critically important for guiding curriculum development and continuing professional education as they describe the knowledge, skills and attitudes required to be effective. A workshop was convened in 2012 to synthesize the various strands of work on One Health competencies. Despite having different mandates, participants, and approaches, all of these initiatives identified similar core competency domains: management; communication and informatics; values and ethics; leadership; teams and collaboration; roles and responsibilities; and systems thinking. These core competency domains have been used to develop new continuing professional education programs for One Health professionals and help university curricula prepare new graduates to be able to contribute more effectively to One Health approaches.

  8. Unsharp Values, Domains and Topoi

    CERN Document Server

    Doering, Andreas

    2011-01-01

    The so-called topos approach provides a radical reformulation of quantum theory. Structurally, quantum theory in the topos formulation is very similar to classical physics. There is a state object, analogous to the state space of a classical system, and a quantity-value object, generalising the real numbers. Physical quantities are maps from the state object to the quantity-value object -- hence the `values' of physical quantities are not just real numbers in this formalism. Rather, they are families of real intervals, interpreted as `unsharp values'. We will motivate and explain these aspects of the topos approach and show that the structure of the quantity-value object can be analysed using tools from domain theory, a branch of order theory that originated in theoretical computer science. Moreover, the base category of the topos associated with a quantum system turns out to be a domain if the underlying von Neumann algebra is a matrix algebra. For general algebras, the base category still is a highly struct...

  9. Word Domain Disambiguation via Word Sense Disambiguation

    Energy Technology Data Exchange (ETDEWEB)

    Sanfilippo, Antonio P.; Tratz, Stephen C.; Gregory, Michelle L.

    2006-06-04

    Word subject domains have been widely used to improve the perform-ance of word sense disambiguation al-gorithms. However, comparatively little effort has been devoted so far to the disambiguation of word subject do-mains. The few existing approaches have focused on the development of al-gorithms specific to word domain dis-ambiguation. In this paper we explore an alternative approach where word domain disambiguation is achieved via word sense disambiguation. Our study shows that this approach yields very strong results, suggesting that word domain disambiguation can be ad-dressed in terms of word sense disam-biguation with no need for special purpose algorithms.

  10. Single-domain antibodies for biomedical applications.

    Science.gov (United States)

    Krah, Simon; Schröter, Christian; Zielonka, Stefan; Empting, Martin; Valldorf, Bernhard; Kolmar, Harald

    2016-01-01

    Single-domain antibodies are the smallest antigen-binding units of antibodies, consisting either only of one variable domain or one engineered constant domain that solely facilitates target binding. This class of antibody derivatives comprises naturally occurring variable domains derived from camelids and sharks as well as engineered human variable or constant antibody domains of the heavy or light chain. Because of their high affinity and specificity as well as stability, small size and benefit of multiple re-formatting opportunities, those molecules emerged as promising candidates for biomedical applications and some of these entities have already proven to be successful in clinical development.

  11. Multi-domain proteins in the three kingdoms of life: orphan domains and other unassigned regions.

    Science.gov (United States)

    Ekman, Diana; Björklund, Asa K; Frey-Skött, Johannes; Elofsson, Arne

    2005-04-22

    Comparative studies of the proteomes from different organisms have provided valuable information about protein domain distribution in the kingdoms of life. Earlier studies have been limited by the fact that only about 50% of the proteomes could be matched to a domain. Here, we have extended these studies by including less well-defined domain definitions, Pfam-B and clustered domains, MAS, in addition to Pfam-A and SCOP domains. It was found that a significant fraction of these domain families are homologous to Pfam-A or SCOP domains. Further, we show that all regions that do not match a Pfam-A or SCOP domain contain a significantly higher fraction of disordered structure. These unstructured regions may be contained within orphan domains or function as linkers between structured domains. Using several different definitions we have re-estimated the number of multi-domain proteins in different organisms and found that several methods all predict that eukaryotes have approximately 65% multi-domain proteins, while the prokaryotes consist of approximately 40% multi-domain proteins. However, these numbers are strongly dependent on the exact choice of cut-off for domains in unassigned regions. In conclusion, all eukaryotes have similar fractions of multi-domain proteins and disorder, whereas a high fraction of repeating domain is distinguished only in multicellular eukaryotes. This implies a role for repeats in cell-cell contacts while the other two features are important for intracellular functions.

  12. Interoperable domain models: The ISO land administration domain model LADM and its external classes

    NARCIS (Netherlands)

    Lemmen, C.H.J.; Van Oosterom, P.J.M.; Uitermark, H.T.; Zevenbergen, J.A.; Cooper, A.K.

    2011-01-01

    This paper provides a brief overview of one of the first spatial domain standards: a standard for the domain of Land Administration (LA). This standard is in the draft stage of development now (May 2011). The development of domain standards is a logical follow up after domain-independent standards,

  13. Blocking-resistant communication through domain fronting

    Directory of Open Access Journals (Sweden)

    Fifield David

    2015-06-01

    Full Text Available We describe “domain fronting,” a versatile censorship circumvention technique that hides the remote endpoint of a communication. Domain fronting works at the application layer, using HTTPS, to communicate with a forbidden host while appearing to communicate with some other host, permitted by the censor. The key idea is the use of different domain names at different layers of communication. One domain appears on the “outside” of an HTTPS request—in the DNS request and TLS Server Name Indication—while another domain appears on the “inside”—in the HTTP Host header, invisible to the censor under HTTPS encryption. A censor, unable to distinguish fronted and nonfronted traffic to a domain, must choose between allowing circumvention traffic and blocking the domain entirely, which results in expensive collateral damage. Domain fronting is easy to deploy and use and does not require special cooperation by network intermediaries. We identify a number of hard-to-block web services, such as content delivery networks, that support domain-fronted connections and are useful for censorship circumvention. Domain fronting, in various forms, is now a circumvention workhorse. We describe several months of deployment experience in the Tor, Lantern, and Psiphon circumvention systems, whose domain-fronting transports now connect thousands of users daily and transfer many terabytes per month.

  14. Chromatin domain boundaries: insulators and beyond

    Institute of Scientific and Technical Information of China (English)

    Gong Hong WEI; De Pei LIU; Chih Chuan LIANG

    2005-01-01

    The eukaryotic genome is organized into functionally and structurally distinct domains, representing regulatory units for gene expression and chromosome behavior. DNA sequences that mark the border between adjacent domains are the insulators or boundary elements, which are required in maintenance of the function of different domains. Some insulators need others enable to play insulation activity. Chromatin domains are defined by distinct sets of post-translationally modified histones. Recent studies show that these histone modifications are also involved in establishment of sharp chromatin boundaries in order to prevent the spreading of distinct domains. Additionally, in some loci, the high-order chromatin structures for long-range looping interactions also have boundary activities, suggesting a correlation between insulators and chromatin loop domains. In this review, we will discuss recent progress in the field of chromatin domain boundaries.

  15. Reconstituting Protein Interaction Networks Using Parameter-Dependent Domain-Domain Interactions

    Science.gov (United States)

    2013-05-07

    that approximately 80% of eukaryotic proteins and 67% of prokaryotic proteins have multiple domains [13,14]. Most annotation databases characterize...domain annotations, Domain-domain interactions, Protein-protein interaction networks Background The living cell is a dynamic, interconnected system...detailed in Methods. Here, we illustrate its application on a well- annotated single- cell organism. We created a merged set of protein-domain annotations

  16. Domain Discretization and Circle Packings

    DEFF Research Database (Denmark)

    Dias, Kealey

    A circle packing is a configuration of circles which are tangent with one another in a prescribed pattern determined by a combinatorial triangulation, where the configuration fills a planar domain or a two-dimensional surface. The vertices in the triangulation correspond to centers of circles......, and edges correspond to two circles (having centers corresponding to the endpoints of the edge) being tangent to each other. This circle packing creates a rigid structure having an underlying geometric triangulation, where the centers of circles again correspond to vertices in the triangulation......, and the edges are geodesic segments (Euclidean, hyperbolic, or spherical) connecting centers of circles that are tangent to each other. Three circles that are mutually tangent form a face of the triangulation. Since circle packing is closely related to triangulation, circle packing methods can be applied...

  17. Incommensurate and commensurate modulations of Ba{sub 5}RTi{sub 3}Nb{sub 7}O{sub 30} (R = La, Nd) tungsten bronzes and the ferroelectric domain structures

    Energy Technology Data Exchange (ETDEWEB)

    Mao, Min Min; Li, Kun; Zhu, Xiao Li; Chen, Xiang Ming, E-mail: xmchen59@zju.edu.cn [Department of Materials Science and Engineering, Zhejiang University, 38 Zheda Road, Hangzhou 310027 (China)

    2015-04-07

    Incommensurate and commensurate structural modulations of Ba{sub 5}RTi{sub 3}Nb{sub 7}O{sub 30} (R = La, Nd) tungsten bronze ceramics were investigated by using a cooling holder equipped transmission electron microscopy in the temperature range from 100 K to 363 K. The incommensurate modulation was observed in both Ba{sub 5}LaTi{sub 3}Nb{sub 7}O{sub 30} and Ba{sub 5}NdTi{sub 3}Nb{sub 7}O{sub 30} at room temperature, while there was a transition from incommensurate tilted structure to commensurate superstructure for Ba{sub 5}NdTi{sub 3}Nb{sub 7}O{sub 30} with decreasing temperature. The incommensurate and commensurate modulations were determined by the A-site occupancy of Ba and R cations. The A-site disorder resulted in larger incommensurability parameter δ and the diffusion of the satellite reflection spots. The effect of A-site disorder on the coupling between long-range dipolar order and the commensurate modulation was also discussed. The obvious ferroelectric 180° domains with spike-like shape parallel to c axis were observed for Ba{sub 5}NdTi{sub 3}Nb{sub 7}O{sub 30}, while no macro ferroelectric domain was determined for Ba{sub 5}LaTi{sub 3}Nb{sub 7}O{sub 30}.

  18. Super-structure and building performance

    CSIR Research Space (South Africa)

    Van Wyk, Llewellyn V

    2010-11-01

    Full Text Available external finish or colour. Resistance to the passage of heat ? the walls should provide resistance to transfer of heat where there is normally sufficient air temperature difference on the opposite sides of the wall. This transfer of heat takes place... are required to resist moisture penetration from the outside; wind and thermal gain and/or loss, depending on the season and the climatic conditions. The functional requirements of a ?green? wall are: Resistance to weather and ground moisture ? the walls...

  19. NANOMETER SUPERSTRUCTURE IN LIQUID ALKALI THALLIUM ALLOYS

    NARCIS (Netherlands)

    XU, R; VERKERK, P; HOWELLS, WS; DEWIJS, GA; VANDERHORST, F; VANDERLUGT, W

    1993-01-01

    Structure factors obtained from neutron diffraction measurements on liquid K-Tl and Cs-Tl alloys exhibit large prepeaks at approximately 0.77 angstrom-1 and 0.70 angstrom-1, respectively. It is concluded that the liquid contains large units of thallium atoms, possibly bearing some resemblance to tho

  20. EuPathDomains: the divergent domain database for eukaryotic pathogens.

    Science.gov (United States)

    Ghouila, Amel; Terrapon, Nicolas; Gascuel, Olivier; Guerfali, Fatma Z; Laouini, Dhafer; Maréchal, Eric; Bréhélin, Laurent

    2011-06-01

    Eukaryotic pathogens (e.g. Plasmodium, Leishmania, Trypanosomes, etc.) are a major source of morbidity and mortality worldwide. In Africa, one of the most impacted continents, they cause millions of deaths and constitute an immense economic burden. While the genome sequence of several of these organisms is now available, the biological functions of more than half of their proteins are still unknown. This is a serious issue for bringing to the foreground the expected new therapeutic targets. In this context, the identification of protein domains is a key step to improve the functional annotation of the proteins. However, several domains are missed in eukaryotic pathogens because of the high phylogenetic distance of these organisms from the classical eukaryote models. We recently proposed a method, co-occurrence domain detection (CODD), that improves the sensitivity of Pfam domain detection by exploiting the tendency of domains to appear preferentially with a few other favorite domains in a protein. In this paper, we present EuPathDomains (http://www.atgc-montpellier.fr/EuPathDomains/), an extended database of protein domains belonging to ten major eukaryotic human pathogens. EuPathDomains gathers known and new domains detected by CODD, along with the associated confidence measurements and the GO annotations that can be deduced from the new domains. This database significantly extends the Pfam domain coverage of all selected genomes, by proposing new occurrences of domains as well as new domain families that have never been reported before. For example, with a false discovery rate lower than 20%, EuPathDomains increases the number of detected domains by 13% in Toxoplasma gondii genome and up to 28% in Cryptospordium parvum, and the total number of domain families by 10% in Plasmodium falciparum and up to 16% in C. parvum genome. The database can be queried by protein names, domain identifiers, Pfam or Interpro identifiers, or organisms, and should become a valuable

  1. Protein domain boundary prediction by combining support vector machine and domain guess by size algorithm

    Institute of Scientific and Technical Information of China (English)

    Dong Qiwen; Wang Xiaolong; Lin Lei

    2007-01-01

    Successful prediction of protein domain boundaries provides valuable information not only for the computational structure prediction of multi-domain proteins but also for the experimental structure determination. A novel method for domain boundary prediction has been presented, which combines the support vector machine with domain guess by size algorithm. Since the evolutional information of multiple domains can be detected by position specific score matrix, the support vector machine method is trained and tested using the values of position specific score matrix generated by PSI-BLAST. The candidate domain boundaries are selected from the output of support vector machine, and are then inputted to domain guess by size algorithm to give the final results of domain boundary prediction. The experimental results show that the combined method outperforms the individual method of both support vector machine and domain guess by size.

  2. Domains in Ferroic Crystals and Thin Films

    CERN Document Server

    Tagantsev, Alexander K; Fousek, Jan

    2010-01-01

    Domains in Ferroic Crystals and Thin Films presents experimental findings and theoretical understanding of ferroic (non-magnetic) domains developed during the past 60 years. It addresses the situation by looking specifically at bulk crystals and thin films, with a particular focus on recently-developed microelectronic applications and methods for observation of domains with techniques such as scanning force microscopy, polarized light microscopy, scanning optical microscopy, electron microscopy, and surface decorating techniques. Domains in Ferroic Crystals and Thin Films covers a large area of material properties and effects connected with static and dynamic properties of domains, which are extremely relevant to materials referred to as ferroics. In most solid state physics books, one large group of ferroics is customarily covered: those in which magnetic properties play a dominant role. Numerous books are specifically devoted to magnetic ferroics and cover a wide spectrum of magnetic domain phenomena. In co...

  3. Spread spectrum time domain reflectometry

    Science.gov (United States)

    Smith, Paul Samuel

    For many years, wiring has been treated as a system that could be installed and expected to work for the life of the aircraft. As aircraft age far beyond their original expected life span, this attitude is rapidly changing. Wiring problems have recently been identified as the cause of several tragic mishaps and hundreds of thousands of lost mission hours. Intermittent wiring faults have been and continue to be difficult to resolve. Test methods that pinpoint faults on the ground can miss intermittent failures. New test methods involving spread spectrum signals are investigated that could be used in flight to locate intermittent failures, including open circuits, short circuits, and arcs. Spread spectrum time domain reflectometry (SSTDR) and sequence time domain reflectometry (STDR) are analyzed in light of the signals commonly present on aircraft wiring. Pseudo noise codes used for the generation of STDR and SSTDR signals are analyzed for application in a STDR/SSTDR test system in the presence of noise. The effects of Mil-Std 1553 and white noise on the STDR and SSTDR signals are discussed analytically, through simulations, and with the use of test hardware. A test system using STDR and SSTDR is designed, built, and used to collect STDR and SSTDR test data. The data collected with the STDR/SSTDR test hardware is analyzed and compared to the theoretical results. Experimental data for open and short circuits collected using SSTDR and a curve fitting algorithm shows a maximum range estimation error of +/-0.2 ft for 75O coaxial cable up to 100ft, and +/-0.6ft for a sample 32.5ft non-controlled impedance aircraft cable. Mil-Std 1553 is specified to operate reliably with a signal-to-noise ratio of 17.5dB, and the SSTDR test system was able to locate an open circuit on a cable also carrying simulated Mil-Std 1553 data where the SSTDR signal was 50dB below the Mil-Std 1553 signal. STDR and SSTDR are shown to be effective in detecting and locating dry and wet arcs on wires.

  4. Domain-specific control of selective attention.

    Science.gov (United States)

    Lin, Szu-Hung; Yeh, Yei-Yu

    2014-01-01

    Previous research has shown that loading information on working memory affects selective attention. However, whether the load effect on selective attention is domain-general or domain-specific remains unresolved. The domain-general effect refers to the findings that load in one content (e.g. phonological) domain in working memory influences processing in another content (e.g., visuospatial) domain. Attentional control supervises selection regardless of information domain. The domain-specific effect refers to the constraint of influence only when maintenance and processing operate in the same domain. Selective attention operates in a specific content domain. This study is designed to resolve this controversy. Across three experiments, we manipulated the type of representation maintained in working memory and the type of representation upon which the participants must exert control to resolve conflict and select a target into the focus of attention. In Experiments 1a and 1b, participants maintained digits and nonverbalized objects, respectively, in working memory while selecting a target in a letter array. In Experiment 2, we presented auditory digits with a letter flanker task to exclude the involvement of resource competition within the same input modality. In Experiments 3a and 3b, we replaced the letter flanker task with an object flanker task while manipulating the memory load on object and digit representation, respectively. The results consistently showed that memory load modulated distractibility only when the stimuli of the two tasks were represented in the same domain. The magnitude of distractor interference was larger under high load than under low load, reflecting a lower efficacy of information prioritization. When the stimuli of the two tasks were represented in different domains, memory load did not modulate distractibility. Control of processing priority in selective attention demands domain-specific resources.

  5. Using context to improve protein domain identification

    Directory of Open Access Journals (Sweden)

    Llinás Manuel

    2011-03-01

    Full Text Available Abstract Background Identifying domains in protein sequences is an important step in protein structural and functional annotation. Existing domain recognition methods typically evaluate each domain prediction independently of the rest. However, the majority of proteins are multidomain, and pairwise domain co-occurrences are highly specific and non-transitive. Results Here, we demonstrate how to exploit domain co-occurrence to boost weak domain predictions that appear in previously observed combinations, while penalizing higher confidence domains if such combinations have never been observed. Our framework, Domain Prediction Using Context (dPUC, incorporates pairwise "context" scores between domains, along with traditional domain scores and thresholds, and improves domain prediction across a variety of organisms from bacteria to protozoa and metazoa. Among the genomes we tested, dPUC is most successful at improving predictions for the poorly-annotated malaria parasite Plasmodium falciparum, for which over 38% of the genome is currently unannotated. Our approach enables high-confidence annotations in this organism and the identification of orthologs to many core machinery proteins conserved in all eukaryotes, including those involved in ribosomal assembly and other RNA processing events, which surprisingly had not been previously known. Conclusions Overall, our results demonstrate that this new context-based approach will provide significant improvements in domain and function prediction, especially for poorly understood genomes for which the need for additional annotations is greatest. Source code for the algorithm is available under a GPL open source license at http://compbio.cs.princeton.edu/dpuc/. Pre-computed results for our test organisms and a web server are also available at that location.

  6. Multiple graph regularized protein domain ranking

    KAUST Repository

    Wang, Jim Jing-Yan

    2012-11-19

    Background: Protein domain ranking is a fundamental task in structural biology. Most protein domain ranking methods rely on the pairwise comparison of protein domains while neglecting the global manifold structure of the protein domain database. Recently, graph regularized ranking that exploits the global structure of the graph defined by the pairwise similarities has been proposed. However, the existing graph regularized ranking methods are very sensitive to the choice of the graph model and parameters, and this remains a difficult problem for most of the protein domain ranking methods.Results: To tackle this problem, we have developed the Multiple Graph regularized Ranking algorithm, MultiG-Rank. Instead of using a single graph to regularize the ranking scores, MultiG-Rank approximates the intrinsic manifold of protein domain distribution by combining multiple initial graphs for the regularization. Graph weights are learned with ranking scores jointly and automatically, by alternately minimizing an objective function in an iterative algorithm. Experimental results on a subset of the ASTRAL SCOP protein domain database demonstrate that MultiG-Rank achieves a better ranking performance than single graph regularized ranking methods and pairwise similarity based ranking methods.Conclusion: The problem of graph model and parameter selection in graph regularized protein domain ranking can be solved effectively by combining multiple graphs. This aspect of generalization introduces a new frontier in applying multiple graphs to solving protein domain ranking applications. 2012 Wang et al; licensee BioMed Central Ltd.

  7. Introduction to the Integrated Domain Modeling Toolset

    Directory of Open Access Journals (Sweden)

    Slihte Armands

    2014-12-01

    Full Text Available This paper describes the Integrated Domain Modeling approach and introduces the supporting toolset as a solution to the complex domain-modeling task. This approach integrates artificial intelligence (AI and system analysis by exploiting ontology, natural language processing (NLP, use cases and model-driven architecture (MDA for knowledge engineering and domain modeling. The IDM toolset provides the opportunity to automatically generate the initial AS-IS model from the formally defined domain knowledge. In this paper, we describe in detail the scope, architecture and implementation of the toolset.

  8. Transform domain steganography with blind source separation

    Science.gov (United States)

    Jouny, Ismail

    2015-05-01

    This paper applies blind source separation or independent component analysis for images that may contain mixtures of text, audio, or other images for steganography purposes. The paper focuses on separating mixtures in the transform domain such as Fourier domain or the Wavelet domain. The study addresses the effectiveness of steganography when using linear mixtures of multimedia components and the ability of standard blind sources separation techniques to discern hidden multimedia messages. Mixing in the space, frequency, and wavelet (scale) domains is compared. Effectiveness is measured using mean square error rate between original and recovered images.

  9. Domain wall solutions with Abelian gauge fields

    CERN Document Server

    Rozowsky, J S; Wali, K C

    2004-01-01

    We study kink (domain wall) solutions in a model consisting of two complex scalar fields coupled to two independent Abelian gauge fields in a Lagrangian that has $U(1)\\times U(1)$ gauge plus $\\mathbb{Z}_2$ discrete symmetry. We find consistent solutions such that while the U(1) symmetries of the fields are preserved while in their respective vacua, they are broken on the domain wall. The gauge field solutions show that the domain wall is sandwiched between domains with constant magnetic fields.

  10. Frequency domain FIR and IIR adaptive filters

    Science.gov (United States)

    Lynn, D. W.

    1990-01-01

    A discussion of the LMS adaptive filter relating to its convergence characteristics and the problems associated with disparate eigenvalues is presented. This is used to introduce the concept of proportional convergence. An approach is used to analyze the convergence characteristics of block frequency-domain adaptive filters. This leads to a development showing how the frequency-domain FIR adaptive filter is easily modified to provide proportional convergence. These ideas are extended to a block frequency-domain IIR adaptive filter and the idea of proportional convergence is applied. Experimental results illustrating proportional convergence in both FIR and IIR frequency-domain block adaptive filters is presented.

  11. Trade name and trademark versus domain

    Directory of Open Access Journals (Sweden)

    Jarmila Pokorná

    2013-01-01

    Full Text Available Internet domains have become an integral part of our lives, so one can easily understand that during their use, conflicts can arise, whose participants will search for rules enabling resolution of conflicts. Since the domain name is a replacement of the computer IP address, in the technical sense of the word, this does not concern for domain names a commercial name or brand, because it primarily does not belong to a person in the legal sense of the word and does not serve for its individualization. The average user regularly affiliates domain names with a person offering goods or services on the relevant Website. Domain names used by entrepreneurs in their business activity are often chosen so that the second-level domain (SLD would use words that form the trade name of corporations formed of trading companies. This fact brings domain names close to such designations that serve the individualization of persons or products, especially the trademarks and the commercial name. Domains can come into conflict with the rights to designations, especially trademarks and commercial names. Court practice is resolving these conflicts using rules for unfair competition, or rules for protection of commercial names and trademarks, but it is not ruled out that in the future, special legal regulation of domain names could be established.

  12. Definition and identification of homology domains.

    Science.gov (United States)

    Lawrence, C B; Goldman, D A

    1988-03-01

    A method is described for identifying and evaluating regions of significant similarity between two sequences. The notion of a 'homology domain' is employed which defines the boundaries of a region of sequence homology containing no insertions or deletions. The relative significance of different potential homology domains is evaluated using a non-linear similarity score related to the probability of finding the observed level of similarity in the region by chance. The sensitivity of the method is demonstrated by simulating the evolution of homology domains and applying the method to their detection. Several examples of the use of homology domain identification are given.

  13. Optical time-domain mixer

    Science.gov (United States)

    Valley, George C.; Sefler, George A.

    2010-08-01

    We simulate an optical time-domain mixer that can be used to make a photonic analog-to-digital converter (ADC) or a digital demodulator for high-speed optical communications signals. In the basic mixer, a high frequency RF signal modulates a repetitively chirped optical carrier; this RF/optical waveform then is dispersed in one transverse dimension, and imaged onto a 2-dimensional transparency or spatial light modulator whose pixels are modulated with randomly chosen transmission or reflection coefficients (the optical mixing matrix). Following transmission through or reflection from the mixing matrix, the optical waveform from each row of the matrix is recombined and directed to a photodiode and electronics that integrate over the repetition period of the chirped source. Finally, each of these signals is digitized by an independent ADC sampling at a rate equal to the pulse repetition rate of the chirp source. A digital replica of the input RF signal can be recovered by digital signal processing from the digital output of the ADCs and the values of the transmission or reflection coefficients of the mixing matrix. The effective sampling rate is given by the number of pixels per row of the mixing matrix times the repetition rate of the chirp source while the effective resolution is controlled by the resolution of the electronic ADCs and the distortions introduced by the optical mixing process.

  14. 基于状态空间超级结构的多流股换热网络最优设计%Optimal design of multistream heat exchanger network based on state space superstructure

    Institute of Scientific and Technical Information of China (English)

    李永强; 王兵; 邹雄; 董宏光; 姚平经

    2014-01-01

    多流股换热器以其结构紧凑、高效低耗等特点,成为过程强化研究的热门领域,但对于多流股换热的过程与设备优势所在仍然值得商榷。基于多流股换热匹配改进状态空间超级结构,将多流股换热网络综合转化为超级换热器设计。首先,构造级联多流股换热器匹配过程操作算子,通过相邻换热流股匹配,传递温位效应,实现多流股间传热严格计算;借助热容流率混合分配机制,实现各流股间任意分混操作。然后,考虑散热因素,改进目标函数,引入冷热损失和保温材料费用项,清晰体现多流股换热器因换热面互相覆盖而带来的外表面封包优势。进而,建立相应非线性数学规划模型,实现公用工程、设备投资、冷热损耗同步优化。最终,通过文献示例对所提方法可行性与优越性进行验证。%Multistream heat exchanger (MHEX) has attracted attention in the process intensification field with its compact structure, high efficiency and low heat loss. However, the potential advantages of its process and equipment are still worth discussing. An improved State-space superstructure based on MHEXs process operator (PO) was proposed to convert the network synthesis into a super-exchanger design. Hierarchy matching MHEXs PO was constructed, and the strict heat transfer calculation among multiple streams was implemented through temperature coordinated effect between adjacent streams. Arbitrary splitting and mixing of any stream was achieved by corresponding mixers and splitters in distribution network (DN). The objective function was ameliorated by taking heat loss into consideration. Through introducing the cost of heat loss and thermal insulation material, the external surface envelope advantage of MHEX was presented clearly owing to coverage between adjacent heat-transfer surfaces. Then, a corresponding nonlinear programming (NLP) mathematical model was

  15. Characterizing Class I WW domains defines key specificity determinants and generates mutant domains with novel specificities.

    Science.gov (United States)

    Kasanov, J; Pirozzi, G; Uveges, A J; Kay, B K

    2001-03-01

    WW domains are small protein interaction modules found in a wide range of eukaryotic signaling and structural proteins. Five classes of WW domains have been annotated to date, where each class is largely defined by the type of peptide ligand selected, rather than by similarities within WW domains. Class I WW domains bind Pro-Pro-Xxx-Tyr containing ligands, and it would be of interest to determine residues within the domains that determine this specificity. Fourteen WW domains selected Leu/Pro-Pro-Xxx-Tyr containing peptides ligands via phage display and were thus designated as Class 1 WW domains. These domains include those present in human YAP (hYAP) and WWP3, as well as those found in ubiquitin protein ligases of the Nedd4 family, including mouse Nedd4 (mNedd4), WWP1, WWP2 and Rsp5. Comparing the primary structures of these WW domains highlighted a set of highly conserved residues, in addition to those originally noted to occur within WW domains. Substitutions at two of these conserved positions completely inhibited ligand binding, whereas substitution at a non-conserved position did not. Moreover, mutant WW domains containing substitutions at conserved positions bound novel peptide ligands. Class I WW domains contain a highly conserved set of residues that are important in selecting Pro-Xxx-Tyr containing peptide ligands. The presence of these residues within an uncharacterized WW domain can be used to predict its ability to bind Pro-Xxx-Tyr containing peptide ligands.

  16. Aerosol influence domain of Beijing and peripheral city agglomeration and its climatic effect

    Institute of Scientific and Technical Information of China (English)

    XU Xiangde; SHI Xiaohui; ZHANG Shengjun; DING Guoan; MIAO Qiuju; ZHOU Li

    2006-01-01

    The aerosol distribution in Beijing and peripheral cities agglomeration (BPCA) and its regional climatic effect are investigated on the basis of the statistical analyses of satellite Total Ozone Mapping Spectrometer (TOMS) retrieval aerosol optical depth (AOD) and the meteorological data of sunshine duration, fog days, and low cloud cover, observed at Beijing and its peripheral meteorological stations. The analysis on multi-samples variational correction of the satellite remote sensing Moderate Resolution Imaging Spectroradiometer (MODIS) AOD under the clear sky and stable weather condition in conjunction with surface observations reveal that there was a "triangle-like" distribution pattern of the high values of aerosols in the southern "valley" of the "U-shape"megarelief of Beijing and its peripheral areas. The distribution pattern suggests that the large-scale transfer and diffusion of city agglomeration pollutants might form a relatively persistent characteristic spatial distribution of city agglomeration pollutants much larger than city-scale. Under the background of the particular megarelief effect of Beijing and peripheral areas, the high value area of TOMS AOD, as well as regional correlation distribution between clear sky sunshine duration and TOMS AOD are also similar to the composite image of MODIS AOD variational fields,that is to say, the effect of atmospheric aerosols was very distinctive in Beijing and peripheral areas. The high value area of the negative correlation between clear sky sunshine duration and TOMS AOD approximately accorded with the significant negative value area of the sunshine duration deviations of the 1980s to the 1990s, and the daily variations of the AOD also showed an anti-phase relation with those of clear sky sunshine duration. The above high correlation area of the urban aerosol impact of Beijing-Tianjin region leant towards south peripheral area,with its "center of gravity" in the south of Beijing-Tianjin agglomeration, and

  17. Frequency Domain Image Filtering Using CUDA

    Directory of Open Access Journals (Sweden)

    Muhammad Awais Rajput

    2014-10-01

    Full Text Available In this paper, we investigate the implementation of image filtering in frequency domain using NVIDIA?s CUDA (Compute Unified Device Architecture. In contrast to signal and image filtering in spatial domain which uses convolution operations and hence is more compute-intensive for filters having larger spatial extent, the frequency domain filtering uses FFT (Fast Fourier Transform which is much faster and significantly reduces the computational complexity of the filtering. We implement the frequency domain filtering on CPU and GPU respectively and analyze the speed-up obtained from the CUDA?s parallel processing paradigm. In order to demonstrate the efficiency of frequency domain filtering on CUDA, we implement three frequency domain filters, i.e., Butterworth, low-pass and Gaussian for processing different sizes of images on CPU and GPU respectively and perform the GPU vs. CPU benchmarks. The results presented in this paper show that the frequency domain filtering with CUDA achieves significant speed-up over the CPU processing in frequency domain with the same level of (output image quality on both the processing architectures

  18. Hydrogels with Micellar Hydrophobic (Nano)Domains

    OpenAIRE

    Pekař, Miloslav

    2015-01-01

    Hydrogels containing hydrophobic domains or nanodomains, especially of the micellar type, are reviewed. Examples of the reasons for introducing hydrophobic domains into hydrophilic gels are given; typology of these materials is introduced. Synthesis routes are exemplified and properties of a variety of such hydrogels in relation with their intended applications are described. Future research needs are identified briefly.

  19. Hydrogels with micellar hydrophobic (nano)domains

    OpenAIRE

    Miloslav ePekař

    2015-01-01

    Hydrogels containing hydrophobic domains or nanodomains, especially of the micellar type, are reviewed. Examples of the reasons for introducing hydrophobic domains into hydrophilic gels are given; typology of these materials is introduced. Synthesis routes are exemplified and properties of a variety of such hydrogels in relation with their intended applications are described. Future research needs are identified briefly.

  20. Structural principles governing domain motions in proteins

    NARCIS (Netherlands)

    Hayward, S

    1999-01-01

    With the use of a recently developed method, twenty-four proteins for which two or more X-ray conformers are known have been analyzed to reveal structural principles that govern domain motions in proteins. In all 24 cases, the domain motion is a rotation about a physical axis created through local i

  1. Time domain NMR applied to food products

    NARCIS (Netherlands)

    Duynhoven, van J.P.M.; Voda, A.; Witek, M.M.; As, van H.

    2010-01-01

    Time-domain NMR is being used throughout all areas of food science and technology. A wide range of one- and two-dimensional relaxometric and diffusometric applications have been implemented on cost-effective, robust and easy-to-use benchtop NMR equipment. Time-domain NMR applications do not only

  2. Domain 2: Sport Safety and Injury Prevention

    Science.gov (United States)

    Gurchiek, Larry; Mokha, Monique Butcher

    2004-01-01

    Most coaches recognize the importance of creating a safe environment and preventing injuries of their athletes. Domain 2 is dedicated to this important aspect of coaching, and outlines specific areas within safety and injury prevention that coaches should address. Domain 2 sets the standards for facility, equipment, and environmental safety…

  3. Structural principles governing domain motions in proteins

    NARCIS (Netherlands)

    Hayward, S

    1999-01-01

    With the use of a recently developed method, twenty-four proteins for which two or more X-ray conformers are known have been analyzed to reveal structural principles that govern domain motions in proteins. In all 24 cases, the domain motion is a rotation about a physical axis created through local

  4. BIVARIATE FRACTAL INTERPOLATION FUNCTIONS ON RECTANGULAR DOMAINS

    Institute of Scientific and Technical Information of China (English)

    Xiao-yuan Qian

    2002-01-01

    Non-tensor product bivariate fractal interpolation functions defined on gridded rectangular domains are constructed. Linear spaces consisting of these functions are introduced.The relevant Lagrange interpolation problem is discussed. A negative result about the existence of affine fractal interpolation functions defined on such domains is obtained.

  5. A Characterization of Complete Bounded Domain

    Institute of Scientific and Technical Information of China (English)

    殷慰萍; 苏简兵; 赵振刚

    2002-01-01

    @@ 1 IntroductionThis paper is concerned with biholomorphic mappings between two bounded domains D and G both in Cn.Consequently,an important question is whether the domain D is biholomorphic to G? We give an answer for this question under a very weak condition.

  6. The Domain Specificity of Academic Emotional Experiences

    Science.gov (United States)

    Goetz, Thomas; Frenzel, Anne C.; Pekrun, Reinhard; Hall, Nathan C.

    2006-01-01

    The authors analyzed the domain specificity of emotions and focused on experiences of enjoyment, anxiety, and boredom in the domains of mathematics, Latin, German, and English. On the basis of assumptions in R. Pekrun's (2000; in press) control-value theory and findings of pilot studies, the authors hypothesized the existence of a largely…

  7. Hydrogels with micellar hydrophobic (nano)domains

    Science.gov (United States)

    Pekař, Miloslav

    2014-12-01

    Hydrogels containing hydrophobic domains or nanodomains, especially of the micellar type, are reviewed. Examples of the reasons for introducing hydrophobic domains into hydrophilic gels are given; typology of these materials is introduced. Synthesis routes are exemplified and properties of a variety of such hydrogels in relation with their intended applications are described. Future research needs are identified briefly.

  8. Domain Wall Propagation through Spin Wave Emission

    NARCIS (Netherlands)

    Wang, X.S.; Yan, P.; Shen, Y.H.; Bauer, G.E.W.; Wang, X.R.

    2012-01-01

    We theoretically study field-induced domain wall motion in an electrically insulating ferromagnet with hard- and easy-axis anisotropies. Domain walls can propagate along a dissipationless wire through spin wave emission locked into the known soliton velocity at low fields. In the presence of damping

  9. Deformation of Entire Functions with Baker Domains

    DEFF Research Database (Denmark)

    Fagella, Nuria; Henriksen, Christian

    2006-01-01

    We consider entire transcendental functions f with an invariant (or periodic) Baker Domain. First, we classify these domains into three types (hyperbolic, simply parabolic and doubly parabolic) according to the surface they induce when we take the quotient by the dynamics. Second, we study...

  10. Evaluation Codes from Order Domain Theory

    DEFF Research Database (Denmark)

    Andersen, Henning Ejnar; Geil, Hans Olav

    2008-01-01

    bound is easily extended to deal with any generalized Hamming weights. We interpret our methods into the setting of order domain theory. In this way we fill in an obvious gap in the theory of order domains. [28] T. Shibuya and K. Sakaniwa, A Dual of Well-Behaving Type Designed Minimum Distance, IEICE...

  11. Strong diamagnetism for general domains and applications

    DEFF Research Database (Denmark)

    Fournais, Søren; Helffer, Bernard

    2007-01-01

    We consider the Neumann Laplacian with constant magnetic field on a regular domain. Let $B$ be the strength of the magnetic field, and let $\\lambda_1(B)$ be the first eigenvalue of the magnetic Neumann Laplacian on the domain. It is proved that $B \\mapsto \\lambda_1(B)$ is monotone increasing for ...

  12. The Private Legal Governance of Domain Names

    DEFF Research Database (Denmark)

    Schovsbo, Jens Hemmingsen

    2016-01-01

    This chapter evaluates the performance of the special private tribunals or panels such as the UDRP which have been developed within complicated systems of self- and co-regulation such as ICANN to decide disputes over domain names. It uses two different dispute resolution models viz. the UDRP (WIPO......) and the Danish Complaints Board for Internet Domain Names (the Board) to discuss how and to what extent the domain name system balances interests between trademark owners and other users of domain names and secures the rule of law (legal certainty and predictability) with a special focus on cases where...... trademarks are used as (parts of) domain names to express criticism of the trademark holder or the trademark itself (e.g. “TMsucks.com” / “lorteTM.dk”)....

  13. The Private Legal Governance of Domain Names

    DEFF Research Database (Denmark)

    Schovsbo, Jens Hemmingsen

    2015-01-01

    Abstract This article evaluates the performance of the special private tribunals or panels such as the UDRP which have been developed within complicated systems of self- and co-regulation such as ICANN to decide disputes over domain names. It uses two different dispute resolution models viz....... the UDRP (WIPO) and the Danish Complaints Board for Internet Domain Names (the Board) to discuss how and to what extent the domain name system balances interests between trademark owners and other users of domain names and secures the rule of law (legal certainty and predictability) with a special focus...... on cases where trademarks are used as (parts of) domain names to express criticism of the trademark holder or the trademark itself (e.g. “TMsucks.com” / “lorteTM.dk”). The article is part of a research project on “User Generated Law” and uses the methodologies developed as part of this. It is scheduled...

  14. Time Domain Stability Margin Assessment Method

    Science.gov (United States)

    Clements, Keith

    2017-01-01

    The baseline stability margins for NASA's Space Launch System (SLS) launch vehicle were generated via the classical approach of linearizing the system equations of motion and determining the gain and phase margins from the resulting frequency domain model. To improve the fidelity of the classical methods, the linear frequency domain approach can be extended by replacing static, memoryless nonlinearities with describing functions. This technique, however, does not address the time varying nature of the dynamics of a launch vehicle in flight. An alternative technique for the evaluation of the stability of the nonlinear launch vehicle dynamics along its trajectory is to incrementally adjust the gain and/or time delay in the time domain simulation until the system exhibits unstable behavior. This technique has the added benefit of providing a direct comparison between the time domain and frequency domain tools in support of simulation validation.

  15. Using ontology for domain specific information retrieval

    Science.gov (United States)

    Shashirekha, H. L.; Murali, S.; Nagabhushan, P.

    2010-02-01

    This paper presents a system for retrieving information from a domain specific document collection made up of data rich unnatural language text documents. Instead of conventional keyword based retrieval, our system makes use of domain ontology to retrieve the information from a collection of documents. The system addresses the problem of representing unnatural language text documents and constructing a classifier model that helps in the efficient retrieval of relevant information. Query to this system may be either the key phrases in terms of concepts or a domain specific unnatural language text document. The classifier used in this system can also be used to assign multiple labels to the previously unseen text document belonging to the same domain. An empirical evaluation of the system is conducted on the domain of text documents describing the classified matrimonial advertisements to determine its performance.

  16. Isomorphisms of noncommutative domain algebras II

    CERN Document Server

    Arias, Alvaro

    2010-01-01

    This paper extends the results of the previous work of the authors on the classification on noncommutative domain algebras up to completely isometric isomorphism. Using Sunada's classification of Reinhardt domains in $C^n$, we show that aspherical noncommutative domain algebras are isomorphic if and only if their defining symbols are equivalent, in the sense that one can be obtained from the other via permutation and scaling of the free variables. Our result also shows that the automorphism groups of aspherical noncommutative domain algebras consists of a subgroup of some finite dimensional unitary group. We conclude by illustrating how our methods can be used to extend to noncommutative domain algebras some results from analysis in $C^n$ with the example of Cartan's lemma.

  17. PLANE DOMAINS WITH SPECIAL CONE CONDITION

    Directory of Open Access Journals (Sweden)

    Anikiev

    2014-11-01

    Full Text Available The paper considers the domains with cone condition in C. We say that domain G satisfies the (weak cone condition, if p+V (e(p, H ⊂ G for all p ∈ G, where V (e(p, H denotes rightangled circular cone with vertex at the origin, a fixed solution ε and a height H, 0 1}. Unlike the paper of P. Liczberski and V. V. Starkov, here we consider domains, accessible outside by the cone, which symmetry axis inclined on fixed angle ϕ to the {pt : t > 1}, 0 < ∥ϕ∥ < < π/2. In this paper we give criteria for this class of domains when the boundaries of domains are smooth, and also give a sufficient condition when boundary is arbitrary. This article is the full variant of [5], published without proofs.

  18. A domain dictionary of trimeric autotransporter adhesins.

    Science.gov (United States)

    Bassler, Jens; Hernandez Alvarez, Birte; Hartmann, Marcus D; Lupas, Andrei N

    2015-02-01

    Trimeric autotransporter adhesins (TAAs) are modular, highly repetitive outer membrane proteins that mediate adhesion to external surfaces in many Gram-negative bacteria. In recent years, several TAAs have been investigated in considerable detail, also at the structural level. However, in their vast majority, putative TAAs in prokaryotic genomes remain poorly annotated, due to their sequence diversity and changeable domain architecture. In order to achieve an automated annotation of these proteins that is both detailed and accurate we have taken a domain dictionary approach, in which we identify recurrent domains by sequence comparisons, produce bioinformatic descriptors for each domain type, and connect these to structural information where available. We implemented this approach in a web-based platform, daTAA, in 2008 and demonstrated its applicability by reconstructing the complete fiber structure of a TAA conserved in enterobacteria. Here we review current knowledge on the domain structure of TAAs.

  19. Local coexpression domains in the genome of rice show no microsynteny with Arabidopsis domains

    NARCIS (Netherlands)

    Ren, X.Y.; Stiekema, W.J.; Nap, J.P.H.

    2007-01-01

    Chromosomal coexpression domains are found in a number of different genomes under various developmental conditions. The size of these domains and the number of genes they contain vary. Here, we define local coexpression domains as adjacent genes where all possible pair-wise correlations of

  20. Contribution of the CR domain to P-selectin lectin domain allostery by regulating the orientation of the EGF domain.

    Science.gov (United States)

    Lü, Shouqin; Chen, Shenbao; Mao, Debin; Zhang, Yan; Long, Mian

    2015-01-01

    The allostery of P-selectin has been studied extensively with a focus on the Lec and EGF domains, whereas the contribution of the CR domain remains unclear. Here, molecular dynamics simulations (MDS) combined with homology modeling were preformed to investigate the impact of the CR domain on P-selectin allostery. The results indicated that the CR domain plays a role in the allosteric dynamics of P-selectin in two ways. First, the CR1 domain tends to stabilize the low affinity of P-selectin during the equilibration processes with the transition inhibition from the S1 to S1' state by restraining the extension of the bent EGF orientation, or with the relaxation acceleration of the S2 state by promoting the bending of the extended EGF orientation. Second, the existence of CR domain increases intramolecular extension prior to complex separation, increasing the time available for the allosteric shift during forced dissociation with a prolonged bond duration. These findings further our understanding of the structure-function relationship of P-selectin with the enriched micro-structural bases of the CR domain.

  1. Microstructural comparison between Nb- and Ta-systems in Li{sub 1+x−y}M{sub 1−x−3y}Ti{sub x+4y}O{sub 3} (M = Nb{sup 5+}, Ta{sup 5+}) solid solution with superstructure

    Energy Technology Data Exchange (ETDEWEB)

    Nakano, Hiromi, E-mail: hiromi@crfc.tut.ac.jp [Cooperative Research Facility Center, Toyohashi University of Technology, Toyohashi 441-8580 (Japan); Department of Environmental and Life Sciences, Toyohashi University of Technology, Toyohashi 441-8580 (Japan); Suehiro, Shiho; Furuya, Syohei [Department of Environmental and Life Sciences, Toyohashi University of Technology, Toyohashi 441-8580 (Japan); Fukuda, Koichiro [Department of Materials Science and Engineering, Nagoya Institute of Technology, Nagoya 466-8555 (Japan)

    2015-01-05

    Highlights: • The composition range of superstructure formed by self-organization was clarified. • The detailed microstructures were analyzed using SEM, XRD and TEM. • The microstructural difference between LNT and LTT was determined. • The superstructure’s formation speed, period and area were controlled by Ti content. - Abstract: We successfully synthesized Li{sub 1+x−y}M{sub 1−x−3y}Ti{sub x+4y}O{sub 3} solid solutions (M = Nb or Ta, LMT, 0.07 ⩽ x ⩽ 0.33, 0 ⩽ y ⩽ 0.175) that have a superstructure, using a conventional electric furnace. The synthesizing time depended on the Ti content, and annealing was repeated for 24–264 h until a homogeneous structure was formed by the insertion of periodical intergrowth layers. We characterized the LMT solid solutions, from micro-scale to nano-scale, using X-ray diffraction, a scanning electron microscope, and a transmission electron microscope. The period of the intergrowth layer was controlled by the Ti content. LNT’s period of the intergrowth layer was narrower than that of LTT in the real lattice when the Ti content was the same. The narrowest interplanar distance (1.82 nm) of the intergrowth layer was formed in Li{sub 0.935}Ta{sub 0.365}Ti{sub 0.810}O{sub 3}. The widest distance (14.3 nm) appeared in Li{sub 1.11}Nb{sub 0.89}Ti{sub 0.11}O{sub 3}, but no such wide period formed in the Ta-system.

  2. J domain independent functions of J proteins.

    Science.gov (United States)

    Ajit Tamadaddi, Chetana; Sahi, Chandan

    2016-07-01

    Heat shock proteins of 40 kDa (Hsp40s), also called J proteins, are obligate partners of Hsp70s. Via their highly conserved and functionally critical J domain, J proteins interact and modulate the activity of their Hsp70 partners. Mutations in the critical residues in the J domain often result in the null phenotype for the J protein in question. However, as more J proteins have been characterized, it is becoming increasingly clear that a significant number of J proteins do not "completely" rely on their J domains to carry out their cellular functions, as previously thought. In some cases, regions outside the highly conserved J domain have become more important making the J domain dispensable for some, if not for all functions of a J protein. This has profound effects on the evolution of such J proteins. Here we present selected examples of J proteins that perform J domain independent functions and discuss this in the context of evolution of J proteins with dispensable J domains and J-like proteins in eukaryotes.

  3. MIT domain of Vps4 is a Ca2+-dependent phosphoinositide-binding domain.

    Science.gov (United States)

    Iwaya, Naoko; Takasu, Hirotoshi; Goda, Natsuko; Shirakawa, Masahiro; Tanaka, Toshiki; Hamada, Daizo; Hiroaki, Hidekazu

    2013-05-01

    The microtubule interacting and trafficking (MIT) domain is a small protein module that is conserved in proteins of diverged function, such as Vps4, spastin and sorting nexin 15 (SNX15). The molecular function of the MIT domain is protein-protein interaction, in which the domain recognizes peptides containing MIT-interacting motifs. Recently, we identified an evolutionarily related domain, 'variant' MIT domain at the N-terminal region of the microtubule severing enzyme katanin p60. We found that the domain was responsible for binding to microtubules and Ca(2+). Here, we have examined whether the authentic MIT domains also bind Ca(2+). We found that the loop between the first and second α-helices of the MIT domain binds a Ca(2+) ion. Furthermore, the MIT domains derived from Vps4b and SNX15a showed phosphoinositide-binding activities in a Ca(2+)-dependent manner. We propose that the MIT domain is a novel membrane-associating domain involved in endosomal trafficking.

  4. Analyses of domains and domain fusions in human proto-oncogenes

    Directory of Open Access Journals (Sweden)

    Wan Ping

    2009-03-01

    Full Text Available Abstract Background Understanding the constituent domains of oncogenes, their origins and their fusions may shed new light about the initiation and the development of cancers. Results We have developed a computational pipeline for identification of functional domains of human genes, prediction of the origins of these domains and their major fusion events during evolution through integration of existing and new tools of our own. An application of the pipeline to 124 well-characterized human oncogenes has led to the identification of a collection of domains and domain pairs that occur substantially more frequently in oncogenes than in human genes on average. Most of these enriched domains and domain pairs are related to tyrosine kinase activities. In addition, our analyses indicate that a substantial portion of the domain-fusion events of oncogenes took place in metazoans during evolution. Conclusion We expect that the computational pipeline for domain identification, domain origin and domain fusion prediction will prove to be useful for studying other groups of genes.

  5. Thermal variations of domain wall thickness and number of domains in magnetic rectangular grains

    Science.gov (United States)

    Xu, Song; Merrill, Ronald T.

    1990-12-01

    Equilibrium domain wall thickness and number of domains in rectangular magnetic grains are determined by using a modified Amar model. It is shown that domain structure, particularly domain wall thickness, in a magnetized grain depends strongly on grain shape and orientation. These dependencies are attributed to the existence of two competing self-magnetostatic interactions, one from the ends of the grain and the other from the sides. One of the consequences of this is that the thermal variation of domain wall thickness in an elongated grain is greater (smaller) than predicted by classical theory when the grain is magnetized along the shortest (longest) dimension. For magnetite, classical theory provides a good approximation in predicting both domain wall thickness and number of domains in equal-dimensional grains larger than about 4 μm.

  6. The domain-specific and domain-general relationships of visuospatial working memory to reasoning ability.

    Science.gov (United States)

    Shipstead, Zach; Yonehiro, Jade

    2016-10-01

    The degree to which visuospatial working memory (VSWM) is separable from working memory in general is an open question. On one hand, the construct is often researched as a unitary, domain-specific system. On the other, there is evidence that VWSM shares a common processing component with verbal memory. One might interpret this shared component as domain-general attention. We used confirmatory factor analysis to demonstrate that VSWM shares a domain-general component with verbal memory tasks and has a domain-specific component that is independent of verbal memory. Furthermore, the domain-general component was found to correlate with reasoning ability in both the visuospatial and verbal domains. The domain-specific component only correlated with reasoning ability when the tests had a strong visuospatial component. We argue that theories of VSWM need to place greater emphasis on its multiply determined nature.

  7. Cross domains Arabic named entity recognition system

    Science.gov (United States)

    Al-Ahmari, S. Saad; Abdullatif Al-Johar, B.

    2016-07-01

    Named Entity Recognition (NER) plays an important role in many Natural Language Processing (NLP) applications such as; Information Extraction (IE), Question Answering (QA), Text Clustering, Text Summarization and Word Sense Disambiguation. This paper presents the development and implementation of domain independent system to recognize three types of Arabic named entities. The system works based on a set of domain independent grammar-rules along with Arabic part of speech tagger in addition to gazetteers and lists of trigger words. The experimental results shown, that the system performed as good as other systems with better results in some cases of cross-domains corpora.

  8. Inferring Evolutionary Scenarios for Protein Domain Compositions

    Science.gov (United States)

    Wiedenhoeft, John; Krause, Roland; Eulenstein, Oliver

    Essential cellular processes are controlled by functional interactions of protein domains, which can be inferred from their evolutionary histories. Methods to reconstruct these histories are challenged by the complexity of reconstructing macroevolutionary events. In this work we model these events using a novel network-like structure that represents the evolution of domain combinations, called plexus. We describe an algorithm to find a plexus that represents the evolution of a given collection of domain histories as phylogenetic trees with the minimum number of macroevolutionary events, and demonstrate its effectiveness in practice.

  9. On the structure of Fatou domains

    Institute of Scientific and Technical Information of China (English)

    CUI GuiZhen; PENG Wen Juan

    2008-01-01

    Let U be a multiply-connected fixed attracting Fatou domain of a rational map f. We prove that there exist a rational map g and a completely invariant Fatou domain Ⅴ of g such that (f, U)and (g, V) are holomorphically conjugate, and each non-trivial Julia component of g is a quasi-circle which bounds an eventually superattracting Fatou domain of g containing at most one postcritical point of g. Moreover, g is unique up to a holomorphic conjugation.

  10. On the structure of Fatou domains

    Institute of Scientific and Technical Information of China (English)

    2008-01-01

    Let U be a multiply-connected fixed attracting Fatou domain of a rational map f.We prove that there exist a rational map g and a completely invariant Fatou domain V of g such that(f,U) and(g,V) are holomorphically conjugate,and each non-trivial Julia component of g is a quasi-circle which bounds an eventually superattracting Fatou domain of g containing at most one postcritical point of g.Moreover,g is unique up to a holomorphic conjugation.

  11. System Identification A Frequency Domain Approach

    CERN Document Server

    Pintelon, Rik

    2012-01-01

    System identification is a general term used to describe mathematical tools and algorithms that build dynamical models from measured data. Used for prediction, control, physical interpretation, and the designing of any electrical systems, they are vital in the fields of electrical, mechanical, civil, and chemical engineering. Focusing mainly on frequency domain techniques, System Identification: A Frequency Domain Approach, Second Edition also studies in detail the similarities and differences with the classical time domain approach. It high??lights many of the important steps in the identi

  12. Shape design sensitivity analysis using domain information

    Science.gov (United States)

    Seong, Hwal-Gyeong; Choi, Kyung K.

    1985-01-01

    A numerical method for obtaining accurate shape design sensitivity information for built-up structures is developed and demonstrated through analysis of examples. The basic character of the finite element method, which gives more accurate domain information than boundary information, is utilized for shape design sensitivity improvement. A domain approach for shape design sensitivity analysis of built-up structures is derived using the material derivative idea of structural mechanics and the adjoint variable method of design sensitivity analysis. Velocity elements and B-spline curves are introduced to alleviate difficulties in generating domain velocity fields. The regularity requirements of the design velocity field are studied.

  13. Domain Knowledge Uncertainty and Probabilistic Parameter Constraints

    CERN Document Server

    Mao, Yi

    2012-01-01

    Incorporating domain knowledge into the modeling process is an effective way to improve learning accuracy. However, as it is provided by humans, domain knowledge can only be specified with some degree of uncertainty. We propose to explicitly model such uncertainty through probabilistic constraints over the parameter space. In contrast to hard parameter constraints, our approach is effective also when the domain knowledge is inaccurate and generally results in superior modeling accuracy. We focus on generative and conditional modeling where the parameters are assigned a Dirichlet or Gaussian prior and demonstrate the framework with experiments on both synthetic and real-world data.

  14. Two-Domain DNA Strand Displacement

    CERN Document Server

    Cardelli, Luca

    2010-01-01

    We investigate the computing power of a restricted class of DNA strand displacement structures: those that are made of double strands with nicks (interruptions) in the top strand. To preserve this structural invariant, we impose restrictions on the single strands they interact with: we consider only two-domain single strands consisting of one toehold domain and one recognition domain. We study fork and join signal-processing gates based on these structures, and we show that these systems are amenable to formalization and to mechanical verification.

  15. Indices of Toeplitz tuples on pseudoregular domains

    Institute of Scientific and Technical Information of China (English)

    郭坤宇

    2000-01-01

    This paper proves an index theorem of Toeplitz tuples on pseudoregular domains in Cn. Geometrically, the index of Toeplitz tuple T n is ( -1)n time wrapping number of n around the origin. As one of the applications of the index theorem, we completely characterize the automorphism groups of Toeplitz algebras on Poincare domain. As another application, it is shown that C* (Ω) ≌ C* ( Bn) for every Poincare domain Ω in Cn( n≠2). It is also noticed that C* (Ω) ≌ C* ( B2) if and only if the Poincaré conjecture is true for Ω.

  16. Indices of Toeplitz tuples on pseudoregular domains

    Institute of Scientific and Technical Information of China (English)

    2000-01-01

    This paper proves an index theorem of Toeplitz tuples on pseudoregular domains in Cn. Geometrically, the index of Toeplitz tuple TΦn is (-1)n time wrapping number of Φn around the origin. As one of the applications of the index theorem, we completely characterize the automorphism groups of Toeplitz algebras on Poincaré domain. As another application, it is shown that C*(Ω)C*(Bn) for every Poincare domain Ω in Cn(n≠2). It is also noticed that C*(Ω)C*(B2) if and only if the Poincaré conjecture is true for Ω.

  17. Time-domain nature of group delay

    Institute of Scientific and Technical Information of China (English)

    王建武; 冯正和

    2015-01-01

    The characteristic of group delay is analyzed based on an electronic circuit, and its time-domain nature is studied with time-domain simulation and experiment. The time-domain simulations and experimental results show that group delay is the delay of the energy center of the amplitude-modulated pulse, rather than the propagation delay of the electromagnetic field. As group velocity originates from the definition of group delay and group delay is different from the propagation delay, the superluminality or negativity of group velocity does not mean the superluminal or negative propagation of the electromagnetic field.

  18. Domain Specific Language Support for Exascale

    Energy Technology Data Exchange (ETDEWEB)

    Sadayappan, Ponnuswamy [The Ohio State Univ., Columbus, OH (United States)

    2017-02-24

    Domain-Specific Languages (DSLs) offer an attractive path to Exascale software since they provide expressive power through appropriate abstractions and enable domain-specific optimizations. But the advantages of a DSL compete with the difficulties of implementing a DSL, even for a narrowly defined domain. The DTEC project addresses how a variety of DSLs can be easily implemented to leverage existing compiler analysis and transformation capabilities within the ROSE open source compiler as part of a research program focusing on Exascale challenges. The OSU contributions to the DTEC project are in the area of code generation from high-level DSL descriptions, as well as verification of the automatically-generated code.

  19. Domain decomposition algorithms and computational fluid dynamics

    Science.gov (United States)

    Chan, Tony F.

    1988-01-01

    Some of the new domain decomposition algorithms are applied to two model problems in computational fluid dynamics: the two-dimensional convection-diffusion problem and the incompressible driven cavity flow problem. First, a brief introduction to the various approaches of domain decomposition is given, and a survey of domain decomposition preconditioners for the operator on the interface separating the subdomains is then presented. For the convection-diffusion problem, the effect of the convection term and its discretization on the performance of some of the preconditioners is discussed. For the driven cavity problem, the effectiveness of a class of boundary probe preconditioners is examined.

  20. Patient Centric Ontology for Telehealth Domain

    DEFF Research Database (Denmark)

    Jørgensen, Daniel Bjerring; Hallenborg, Kasper; Demazeau, Yves

    2015-01-01

    This paper presents an ontology for the telehealth domain, a domain that concerns the use of telecommunication to support and deliver health related services e.g. patient monitoring and rehabilitative training. Our vision for the future of telehealth solutions is that they adapt their behavior...... to the needs, habits, and personality of the patient through user modeling and context awareness. The ontology will be our foundation for user modeling of patients in the telehealth domain, and hence it is one of the initial steps toward our vision. Compared to other ontologies within the domain, ours has...... explicit focus on: 1) personality traits of the patient, which is vital for fulfillment of our vision in term of adaptability, and 2) use of international standards to describe diseases, func-tioning and physiological measurement – ICD, ICF and SNOMED respectively – to promote interoperability...

  1. Domain wall magneto-Seebeck effect

    Science.gov (United States)

    Krzysteczko, Patryk; Hu, Xiukun; Liebing, Niklas; Sievers, Sibylle; Schumacher, Hans W.

    2015-10-01

    The interplay between charge, spin, and heat currents in magnetic nanostructures subjected to a temperature gradient has led to a variety of novel effects and promising applications studied in the fast-growing field of spin caloritronics. Here, we explore the magnetothermoelectrical properties of an individual magnetic domain wall in a permalloy nanowire. In thermal gradients of the order of few K /μ m along the long wire axis, we find a clear magneto-Seebeck signature due to the presence of a single domain wall. The observed domain wall magneto-Seebeck effect can be explained by the magnetization-dependent Seebeck coefficient of permalloy in combination with the local spin configuration of the domain wall.

  2. FHA domains: Phosphopeptide binding and beyond.

    Science.gov (United States)

    Almawi, Ahmad W; Matthews, Lindsay A; Guarné, Alba

    2017-08-01

    Forkhead-associated (FHA) domains are small phosphopeptide recognition modules found in eubacterial and eukaryotic, but not archeal, genomes. Although they were originally found in forkhead-type transcription factors, they have now been identified in many other signaling proteins. FHA domains share a remarkably conserved fold despite very low sequence conservation. They only have five conserved amino acids that are important for binding to phosphorylated epitopes. Recent work from several laboratories has demonstrated that FHA domains can mediate many interactions that do not depend on their ability to recognize a phosphorylated threonine. In this review, we present structural and biochemical work that has unveiled novel interaction interfaces on FHA domains. We discuss how these non-canonical interactions modulate the recognition of phosphorylated and non-phosphorylated substrates, as well as protein oligomerization - events that collectively determine FHA function. Copyright © 2016 Elsevier Ltd. All rights reserved.

  3. Collaborative Networks for biodiversity domain organizations

    NARCIS (Netherlands)

    Ermilova, E.; Afsarmanesh, H.

    2010-01-01

    European scientific research and development organizations, operating in the domains of biology, ecology, and biodiversity, strongly need to cooperate/collaborate with other centers. Unavailability of interoperation infrastructure as well as the needed collaboration environment among research

  4. Magnified time-domain ghost imaging

    Science.gov (United States)

    Ryczkowski, Piotr; Barbier, Margaux; Friberg, Ari T.; Dudley, John M.; Genty, Goëry

    2017-04-01

    Ghost imaging allows the imaging of an object without directly seeing this object. Originally demonstrated in the spatial domain, it was recently shown that ghost imaging can be transposed into the time domain to detect ultrafast signals, even in the presence of distortion. We propose and experimentally demonstrate a temporal ghost imaging scheme which generates a 5× magnified ghost image of an ultrafast waveform. Inspired by shadow imaging in the spatial domain and building on the dispersive Fourier transform of an incoherent supercontinuum in an optical fiber, the approach overcomes the resolution limit of standard time-domain ghost imaging generally imposed by the detectors speed. The method can be scaled up to higher magnification factors using longer fiber lengths and light source with shorter duration.

  5. De novo design of synthetic prion domains.

    Science.gov (United States)

    Toombs, James A; Petri, Michelina; Paul, Kacy R; Kan, Grace Y; Ben-Hur, Asa; Ross, Eric D

    2012-04-24

    Prions are important disease agents and epigenetic regulatory elements. Prion formation involves the structural conversion of proteins from a soluble form into an insoluble amyloid form. In many cases, this structural conversion is driven by a glutamine/asparagine (Q/N)-rich prion-forming domain. However, our understanding of the sequence requirements for prion formation and propagation by Q/N-rich domains has been insufficient for accurate prion propensity prediction or prion domain design. By focusing exclusively on amino acid composition, we have developed a prion aggregation prediction algorithm (PAPA), specifically designed to predict prion propensity of Q/N-rich proteins. Here, we show not only that this algorithm is far more effective than traditional amyloid prediction algorithms at predicting prion propensity of Q/N-rich proteins, but remarkably, also that PAPA is capable of rationally designing protein domains that function as prions in vivo.

  6. Oversampling analysis in fractional Fourier domain

    Institute of Scientific and Technical Information of China (English)

    ZHANG Feng; TAO Ran; WANG Yue

    2009-01-01

    Oversampling is widely used in practical applications of digital signal processing. As the fractional Fourier transform has been developed and applied in signal processing fields, it is necessary to consider the oversampling theorem in the fractional Fourier domain. In this paper, the oversampling theorem in the fractional Fourier domain is analyzed. The fractional Fourier spectral relation between the original oversampled sequence and its subsequences is derived first, and then the expression for exact reconstruction of the missing samples in terms of the subsequences is obtained. Moreover, by taking a chirp signal as an example, it is shown that, reconstruction of the missing samples in the oversampled signal Is suitable in the fractional Fourier domain for the signal whose time-frequency distribution has the minimum support in the fractional Fourier domain.

  7. Separating Cognitive and Content Domains in Mathematical Competence

    Science.gov (United States)

    Harks, Birgit; Klieme, Eckhard; Hartig, Johannes; Leiss, Dominik

    2014-01-01

    The present study investigates the empirical separability of mathematical (a) content domains, (b) cognitive domains, and (c) content-specific cognitive domains. There were 122 items representing two content domains (linear equations vs. theorem of Pythagoras) combined with two cognitive domains (modeling competence vs. technical competence)…

  8. Supporting multiple domains in a single reuse repository

    Science.gov (United States)

    Eichmann, David

    1992-01-01

    Domain analysis typically results in the construction of a domain-specific repository. Such a repository imposes artificial boundaries on the sharing of similar assets between related domains. A lattice-based approach to repository modeling can preserve a reuser's domain specific view of the repository, while avoiding replication of commonly used assets and supporting a more general perspective on domain interrelationships.

  9. Between-Domain Relations of Students’ Academic Emotions and Their Judgments of School Domain Similarity

    Directory of Open Access Journals (Sweden)

    Thomas eGoetz

    2014-10-01

    Full Text Available With the aim to deepen our understanding of the between-domain relations of academic emotions, a series of three studies was conducted. We theorized that between-domain relations of trait (i.e., habitual emotions reflected students’ judgments of domain similarities, whereas between-domain relations of state (i.e., momentary emotions did not. This supposition was based on the accessibility model of emotional self-report, according to which individuals’ beliefs tend to strongly impact trait, but not state emotions. The aim of Study 1 (interviews; N = 40; 8th and 11th graders was to gather salient characteristics of academic domains from students’ perspective. In Study 2 (N=1709; 8th and 11th graders the 13 characteristics identified in Study 1 were assessed along with academic emotions in four different domains (mathematics, physics, German, and English using a questionnaire-based trait assessment. With respect to the same domains, state emotions were assessed in Study 3 (N = 121; 8th and 11th graders by employing an experience sampling approach. In line with our initial assumptions, between-domain relations of trait but not state academic emotions reflected between-domain relations of domain characteristics. Implications for research and practice are discussed.

  10. Between-domain relations of students' academic emotions and their judgments of school domain similarity

    Science.gov (United States)

    Goetz, Thomas; Haag, Ludwig; Lipnevich, Anastasiya A.; Keller, Melanie M.; Frenzel, Anne C.; Collier, Antonie P. M.

    2014-01-01

    With the aim to deepen our understanding of the between-domain relations of academic emotions, a series of three studies was conducted. We theorized that between-domain relations of trait (i.e., habitual) emotions reflected students' judgments of domain similarities, whereas between-domain relations of state (i.e., momentary) emotions did not. This supposition was based on the accessibility model of emotional self-report, according to which individuals' beliefs tend to strongly impact trait, but not state emotions. The aim of Study 1 (interviews; N = 40; 8th and 11th graders) was to gather salient characteristics of academic domains from students' perspective. In Study 2 (N = 1709; 8th and 11th graders) the 13 characteristics identified in Study 1 were assessed along with academic emotions in four different domains (mathematics, physics, German, and English) using a questionnaire-based trait assessment. With respect to the same domains, state emotions were assessed in Study 3 (N = 121; 8th and 11th graders) by employing an experience sampling approach. In line with our initial assumptions, between-domain relations of trait but not state academic emotions reflected between-domain relations of domain characteristics. Implications for research and practice are discussed. PMID:25374547

  11. Domain Specific Languages for Interactive Web Services

    DEFF Research Database (Denmark)

    Brabrand, Claus

    This dissertation shows how domain specific languages may be applied to the domain of interactive Web services to obtain flexible, safe, and efficient solutions. We show how each of four key aspects of interactive Web services involving sessions, dynamic creation of HTML/XML documents, form field......, , that supports virtually all aspects of the development of interactive Web services and provides flexible, safe, and efficient solutions....

  12. Targeting Discoidin Domain Receptors in Prostate Cancer

    Science.gov (United States)

    2016-08-01

    1 AWARD NUMBER: W81XWH-15-1-0226 TITLE: Targeting Discoidin Domain Receptors in Prostate Cancer PRINCIPAL INVESTIGATOR: Dr. Rafael Fridman...4. TITLE AND SUBTITLE 5a. CONTRACT NUMBER W81XWH-15-1-0226 Targeting Discoidin Domain Receptors in Prostate Cancer 5b. GRANT NUMBER W81XWH-15...DDRs in prostate cancer . During the first funding period, we conducted immunohistochemical studies by staining a 200 case Grade/Stage tissue

  13. Canonical metrics on Cartan--Hartogs domains

    CERN Document Server

    Zedda, Michela

    2011-01-01

    In this paper we address two problems concerning a family of domains $M_{\\Omega}(\\mu) \\subset \\C^n$, called Cartan-Hartogs domains, endowed with a natural Kaehler metric $g(\\mu)$. The first one is determining when the metric $g(\\mu)$ is extremal (in the sense of Calabi), while the second one studies when the coefficient $a_2$ in the Engli\\v{s} expansion of Rawnsley $\\epsilon$-function associated to $g(\\mu)$ is constant.

  14. Domain Wall Evolution in Phase Transforming Oxides

    Science.gov (United States)

    2015-01-14

    PERFORMING ORGANIZATION NAMES AND ADDRESSES 8. PERFORMI:N’G ORGANIZATION REPORT University ofFioridaOffice ofEngineering NUMBER 339 Wei I Hall ...surveillance, navigation, tlrreat identification, target acquisition, and missile guidance. Domain wall motion, or the planar defects separating regions of...surveillance, navigation, threat identification, target acquisition, and missile guidance. Domain wall motion, or the planar defects separating regions of

  15. Univalent Biharmonic Mappings and Linearly Connected Domains

    Directory of Open Access Journals (Sweden)

    Zayid Abdulhadi

    2015-11-01

    Full Text Available A four times continuously differentiable complex valued function F = u + iv in a simply connected domain Ω is biharmonic if the laplacian of F is harmonic. Every biharmonic mapping F in Ω has the representation F = |z|^2 G + K, where G and K are harmonic in Ω. This paper investigates the relationship between the univalence of F and of K using the concept of linearly connected domains.

  16. Domain Decomposition Based High Performance Parallel Computing

    CERN Document Server

    Raju, Mandhapati P

    2009-01-01

    The study deals with the parallelization of finite element based Navier-Stokes codes using domain decomposition and state-ofart sparse direct solvers. There has been significant improvement in the performance of sparse direct solvers. Parallel sparse direct solvers are not found to exhibit good scalability. Hence, the parallelization of sparse direct solvers is done using domain decomposition techniques. A highly efficient sparse direct solver PARDISO is used in this study. The scalability of both Newton and modified Newton algorithms are tested.

  17. Neural network models of protein domain evolution

    OpenAIRE

    Sylvia Nagl

    2000-01-01

    Protein domains are complex adaptive systems, and here a novel procedure is presented that models the evolution of new functional sites within stable domain folds using neural networks. Neural networks, which were originally developed in cognitive science for the modeling of brain functions, can provide a fruitful methodology for the study of complex systems in general. Ethical implications of developing complex systems models of biomolecules are discussed, with particular reference to molecu...

  18. Barriers to Critical Thinking Across Domains

    OpenAIRE

    Geertsen, Reed

    2013-01-01

    The transfer of critical thinking across domains presents both a significant challenge and meaningful opportunity for college education as well as programs of continuing education and · efforts to encourage lifelong learning. After examining different approaches to teaching critical thinking, this paper examines some of the barriers to transfer across domains using an interactionist perspective. This perspective underscores the fact that developing and using critical thinking i...

  19. C3 Domain Analysis, Lessons Learned

    Science.gov (United States)

    1993-09-30

    Software Engineering Institute’s (SEI) Feature-Oriented Domain Analysis ( FODA ) [Cohen, et al., 19901 method were the original two methods used to analyze the...oriented methods traditionally used for systems analysis and design. Since these two domain analysis tasks are of a more recent vintage than RLPM and FODA ...object-oriented analysis method), and the FODA method do make the distinction between descriptive and prescriptive phases. Based on our examination of

  20. Multi-domain training enhances attentional control.

    Science.gov (United States)

    Binder, Julia C; Martin, Mike; Zöllig, Jacqueline; Röcke, Christina; Mérillat, Susan; Eschen, Anne; Jäncke, Lutz; Shing, Yee Lee

    2016-06-01

    Multi-domain training potentially increases the likelihood of overlap in processing components with transfer tasks and everyday life, and hence is a promising training approach for older adults. To empirically test this, 84 healthy older adults aged 64 to 75 years were randomly assigned to one of three single-domain training conditions (inhibition, visuomotor function, spatial navigation) or to the simultaneous training of all three cognitive functions (multi-domain training condition). All participants trained on an iPad at home for 50 training sessions. Before and after the training, and at a 6-month follow-up measurement, cognitive functioning and training transfer were assessed with a neuropsychological test battery including tests targeting the trained functions (near transfer) and transfer to executive functions (far transfer: attentional control, working memory, speed). Participants in all four training groups showed a linear increase in training performance over the 50 training sessions. Using a latent difference score model, the multi-domain training group, compared with the single-domain training groups, showed more improvement on the far transfer attentional control composite. Individuals with initially lower baseline performance showed higher training-related improvements, indicating that training compensated for lower initial cognitive performance. At the 6-month follow-up, performance on the cognitive test battery remained stable. This is one of the first studies to investigate systematically multi-domain training including comparable single-domain training conditions. Our findings suggest that multi-domain training enhances attentional control involved in handling several different tasks at the same time, an aspect in everyday life that is particularly challenging for older people. (PsycINFO Database Record

  1. Domain Name Server Security (DNSSEC) Protocol Deployment

    Science.gov (United States)

    2014-10-01

    was a 10-year effort to promote adoption of the DNS Security Extensions (DNSSEC), a method of cryptography securing domain name system ( DNS ) lookups...DISTRIBUTION UNLIMITED i 1. SUMMARY The DNSSEC Deployment Initiative was a 10-year effort to promote adoption of the DNS Security Extensions (DNSSEC), a...method of cryptographically securing domain name system ( DNS ) lookups. This paper describes the latter five years of the Initiative’s work, which

  2. Functional domains of the poliovirus receptor

    Energy Technology Data Exchange (ETDEWEB)

    Koike, Satoshi; Ise, Iku; Nomoto, Akio (Tokyo Metropolitan Institute of Medical Science (Japan))

    1991-05-15

    A number of mutant cDNAs of the human poliovirus receptor were constructed to identify essential regions of the molecule as the receptor. All mutant cDNAs carrying the sequence coding for the entire N-terminal immunoglobulin-like domain (domain I) confer permissiveness for poliovirus to mouse L cells, but a mutant cDNA lacking the sequence for domain I does not. The transformants permissive for poliovirus were able to bind the virus and were also recognized by monoclonal antibody D171, which competes with poliovirus for the cellular receptor. These results strongly suggest that the poliovirus binding site resides in domain I of the receptor. Mutant cDNAs for the sequence encoding the intracellular peptide were also constructed and expressed in mouse L cells. Susceptibility of these cells to poliovirus revealed that the entire putative cytoplasmic domain is not essential for virus infection. Thus, the cytoplasmic domain of the molecule appears not to play a role in the penetration of poliovirus.

  3. Constant domain-regulated antibody catalysis.

    Science.gov (United States)

    Sapparapu, Gopal; Planque, Stephanie; Mitsuda, Yukie; McLean, Gary; Nishiyama, Yasuhiro; Paul, Sudhir

    2012-10-19

    Some antibodies contain variable (V) domain catalytic sites. We report the superior amide and peptide bond-hydrolyzing activity of the same heavy and light chain V domains expressed in the IgM constant domain scaffold compared with the IgG scaffold. The superior catalytic activity of recombinant IgM was evident using two substrates, a small model peptide that is hydrolyzed without involvement of high affinity epitope binding, and HIV gp120, which is recognized specifically by noncovalent means prior to the hydrolytic reaction. The catalytic activity was inhibited by an electrophilic phosphonate diester, consistent with a nucleophilic catalytic mechanism. All 13 monoclonal IgMs tested displayed robust hydrolytic activities varying over a 91-fold range, consistent with expression of the catalytic functions at distinct levels by different V domains. The catalytic activity of polyclonal IgM was superior to polyclonal IgG from the same sera, indicating that on average IgMs express the catalytic function at levels greater than IgGs. The findings indicate a favorable effect of the remote IgM constant domain scaffold on the integrity of the V-domain catalytic site and provide a structural basis for conceiving antibody catalysis as a first line immune function expressed at high levels prior to development of mature IgG class antibodies.

  4. Quasicontinuous functions, domains, and extended calculus

    Directory of Open Access Journals (Sweden)

    Rodica Cazacu

    2007-04-01

    Full Text Available One of the aims of domain theory is the construction of an embedding of a given structure or data type as the maximal or “ideal” elements of an enveloping domain of “approximations,” sometimes called a domain environment. Typically the goal is to provide a computational model or framework for recursive and algorithmic reasoning about the original structure. In this paper we consider the function space of (natural equivalence classes of quasicontinuous functions from a locally compact space X into L, an n-fold product of the extended reals [−1,1] (more generally, into a bicontinuous lattice. We show that the domain of all “approximate maps” that assign to each point of X an order interval of L is a domain environment for the quasicontinuous function space. We rely upon the theory of domain environments to introduce an interesting and useful function space topology on the quasicontinuous function space. We then apply this machinery to define an extended differential calculus in the quasicontinuous function space, and draw connections with viscosity solutions of Hamiltonian equations. The theory depends heavily on topological properties of quasicontinuous functions that have been recently uncovered that involve dense sets of points of continuity and sections of closed relations and USCO maps. These and other basic results about quasicontinuous functions are surveyed and presented in the early sections.

  5. Pleckstrin homology domains and the cytoskeleton.

    Science.gov (United States)

    Lemmon, Mark A; Ferguson, Kathryn M; Abrams, Charles S

    2002-02-20

    Pleckstrin homology (PH) domains are 100-120 amino acid protein modules best known for their ability to bind phosphoinositides. All possess an identical core beta-sandwich fold and display marked electrostatic sidedness. The binding site for phosphoinositides lies in the center of the positively charged face. In some cases this binding site is well defined, allowing highly specific and strong ligand binding. In several of these cases the PH domains specifically recognize 3-phosphorylated phosphoinositides, allowing them to drive membrane recruitment in response to phosphatidylinositol 3-kinase activation. Examples of these PH domain-containing proteins include certain Dbl family guanine nucleotide exchange factors, protein kinase B, PhdA, and pleckstrin-2. PH domain-mediated membrane recruitment of these proteins contributes to regulated actin assembly and cell polarization. Many other PH domain-containing cytoskeletal proteins, such as spectrin, have PH domains that bind weakly, and to all phosphoinositides. In these cases, the individual phosphoinositide interactions may not be sufficient for membrane association, but appear to require self-assembly of their host protein and/or cooperation with other anchoring motifs within the same molecule to drive membrane attachment.

  6. Robust ferromagnetism carried by antiferromagnetic domain walls

    Science.gov (United States)

    Hirose, Hishiro T.; Yamaura, Jun-Ichi; Hiroi, Zenji

    2017-02-01

    Ferroic materials, such as ferromagnetic or ferroelectric materials, have been utilized as recording media for memory devices. A recent trend for downsizing, however, requires an alternative, because ferroic orders tend to become unstable for miniaturization. The domain wall nanoelectronics is a new developing direction for next-generation devices, in which atomic domain walls, rather than conventional, large domains themselves, are the active elements. Here we show that atomically thin magnetic domain walls generated in the antiferromagnetic insulator Cd2Os2O7 carry unusual ferromagnetic moments perpendicular to the wall as well as electron conductivity: the ferromagnetic moments are easily polarized even by a tiny field of 1 mT at high temperature, while, once cooled down, they are surprisingly robust even in an inverse magnetic field of 7 T. Thus, the magnetic domain walls could serve as a new-type of microscopic, switchable and electrically readable magnetic medium which is potentially important for future applications in the domain wall nanoelectronics.

  7. Structured hints : extracting and abstracting domain expertise.

    Energy Technology Data Exchange (ETDEWEB)

    Hereld, M.; Stevens, R.; Sterling, T.; Gao, G. R.; Mathematics and Computer Science; California Inst. of Tech.; Louisiana State Univ.; Univ. of Delaware

    2009-03-16

    We propose a new framework for providing information to help optimize domain-specific application codes. Its design addresses problems that derive from the widening gap between the domain problem statement by domain experts and the architectural details of new and future high-end computing systems. The design is particularly well suited to program execution models that incorporate dynamic adaptive methodologies for live tuning of program performance and resource utilization. This new framework, which we call 'structured hints', couples a vocabulary of annotations to a suite of performance metrics. The immediate target is development of a process by which a domain expert describes characteristics of objects and methods in the application code that would not be readily apparent to the compiler; the domain expert provides further information about what quantities might provide the best indications of desirable effect; and the interactive preprocessor identifies potential opportunities for the domain expert to evaluate. Our development of these ideas is progressing in stages from case study, through manual implementation, to automatic or semi-automatic implementation. In this paper we discuss results from our case study, an examination of a large simulation of a neural network modeled after the neocortex.

  8. Mechanical Properties of Nanoscopic Lipid Domains.

    Science.gov (United States)

    Nickels, Jonathan D; Cheng, Xiaolin; Mostofian, Barmak; Stanley, Christopher; Lindner, Benjamin; Heberle, Frederick A; Perticaroli, Stefania; Feygenson, Mikhail; Egami, Takeshi; Standaert, Robert F; Smith, Jeremy C; Myles, Dean A A; Ohl, Michael; Katsaras, John

    2015-12-23

    The lipid raft hypothesis presents insights into how the cell membrane organizes proteins and lipids to accomplish its many vital functions. Yet basic questions remain about the physical mechanisms that lead to the formation, stability, and size of lipid rafts. As a result, much interest has been generated in the study of systems that contain similar lateral heterogeneities, or domains. In the current work we present an experimental approach that is capable of isolating the bending moduli of lipid domains. This is accomplished using neutron scattering and its unique sensitivity to the isotopes of hydrogen. Combining contrast matching approaches with inelastic neutron scattering, we isolate the bending modulus of ∼13 nm diameter domains residing in 60 nm unilamellar vesicles, whose lipid composition mimics the mammalian plasma membrane outer leaflet. Importantly, the bending modulus of the nanoscopic domains differs from the modulus of the continuous phase surrounding them. From additional structural measurements and all-atom simulations, we also determine that nanoscopic domains are in-register across the bilayer leaflets. Taken together, these results inform a number of theoretical models of domain/raft formation and highlight the fact that mismatches in bending modulus must be accounted for when explaining the emergence of lateral heterogeneities in lipid systems and biological membranes.

  9. Perbandingan Bentuk Kelembagaan Pengelola Nama Domain di Indonesia dengan Lembaga Pengelola Nama Domain di Beberapa Negara

    Directory of Open Access Journals (Sweden)

    Helni Mutiarsih Jumhur

    2014-12-01

    Full Text Available Abstrak Lembaga pengelolaan dan pendaftaran nama domain di Indonesia dilakukan oleh lembaga yang didirikan oleh masyarakat atau pemerintah. Pengelolaan dan pendaftaran nama domain di Indonesia dilakukan oleh lembaga yang dinamakan PANDI (Pengelola Nama Domain Indonesia. PANDI merupakan organisasi nirlaba yang dibentuk oleh komunitas Internet Indonesia bersama pemerintah pada 29 Desember 2006 untuk menjadi registry domain (.id. Dalam tulisan ini akan dikemukakan beberapa perbandingan lembaga pengelola dan pendaftaran nama domain di beberapa negara yaitu, Australia, Singapura, dan Malaysia. Alasan dipilihnya negara-negara tersebut karena telah terbentuknya institusi dan peraturan yang komprehensif pada manajemen dan pendaftaran nama domain. Studi perbandingan ini bertujuan untuk menemukan bentuk nama lembaga yang dapat menjadi acuan dalam menentukan model lembaga negara serupa di Indonesia yang dapat mengatur manajemen domain pendaftaran yang tepat dan sesuai dengan undang-undang terkait. Kesimpulan dari penelitian ini adalah model lembaga pengelolaan dan pendaftaran nama domain yang paling tepat dan dapat digunakan sebagai acuan adalah lembaga pengelolaan dan pendaftaran nama domain di Australia (.AuDA. Abstract Domain Name Management is conducted by the institute founded by people or institutions established by the government. Management and the registration of Domain Name in Indonesia is conducted by an agency called PANDI (Domain Name Management of Indonesia. PANDI is a non-profit organization formed by the Indonesian Internet community and the government on December 29, 2006 to become the domain registry (.id on June 29, 2007. This paper will put forward some comparisons of Domain Name Managements in several countries, namely: Australia, Singapore, and Malaysia. These countries are chosen because they already have the institutions and comprehenshive regulations on the management and registration of domain names. The aim of this study is to

  10. The SHOCT domain: a widespread domain under-represented in model organisms.

    Directory of Open Access Journals (Sweden)

    Ruth Y Eberhardt

    Full Text Available We have identified a new protein domain, which we have named the SHOCT domain (Short C-terminal domain. This domain is widespread in bacteria with over a thousand examples. But we found it is missing from the most commonly studied model organisms, despite being present in closely related species. It's predominantly C-terminal location, co-occurrence with numerous other domains and short size is reminiscent of the Gram-positive anchor motif, however it is present in a much wider range of species. We suggest several hypotheses about the function of SHOCT, including oligomerisation and nucleic acid binding. Our initial experiments do not support its role as an oligomerisation domain.

  11. Domain-specific and domain-general processes in social perception--A complementary approach.

    Science.gov (United States)

    Michael, John; D'Ausilio, Alessandro

    2015-11-01

    In this brief discussion, we explicate and evaluate Heyes and colleagues' deflationary approach to interpreting apparent evidence of domain-specific processes for social perception. We argue that the deflationary approach sheds important light on how functionally specific processes in social perception can be subserved at least in part by domain-general processes. On the other hand, we also argue that the fruitfulness of this approach has been unnecessarily hampered by a contrastive conception of the relationship between domain-general and domain-specific processes. As an alternative, we propose a complementary conception: the identification of domain-general processes that are engaged in instances of social perception can play a positive, structuring role by adding additional constraints to be accounted for in modelling the domain-specific processes that are also involved in such instances. Copyright © 2014 Elsevier Inc. All rights reserved.

  12. Controllability of vortex domain structure in ferroelectric nanodot: fruitful domain patterns and transformation paths.

    Science.gov (United States)

    Wu, C M; Chen, W J; Zheng, Yue; Ma, D C; Wang, B; Liu, J Y; Woo, C H

    2014-02-04

    Ferroelectric vortex domain structure which exists in low-dimensional ferroelectrics is being intensively researched for future applications in functional nanodevices. Here we demonstrate that adjusting surface charge screening in combination with temperature can provide an efficient way to gain control of vortex domain structure in ferroelectric nanodot. Systematical simulating experiments have been conducted to reveal the stability and evolution mechanisms of domain structure in ferroelectric nanodot under various conditions, including processes of cooling-down/heating-up under different surface charge screening conditions, and increasing/decreasing surface charge screening at different temperatures. Fruitful phase diagrams as functions of surface screening and temperature are presented, together with evolution paths of various domain patterns. Calculations discover up to 25 different kinds of domain patterns and 22 typical evolution paths of phase transitions. The fruitful controllability of vortex domain structure by surface charge screening in combination with temperature should shed light on prospective nanodevice applications of low-dimensional ferroelectric nanostructures.

  13. Human-computer interface incorporating personal and application domains

    Science.gov (United States)

    Anderson, Thomas G.

    2011-03-29

    The present invention provides a human-computer interface. The interface includes provision of an application domain, for example corresponding to a three-dimensional application. The user is allowed to navigate and interact with the application domain. The interface also includes a personal domain, offering the user controls and interaction distinct from the application domain. The separation into two domains allows the most suitable interface methods in each: for example, three-dimensional navigation in the application domain, and two- or three-dimensional controls in the personal domain. Transitions between the application domain and the personal domain are under control of the user, and the transition method is substantially independent of the navigation in the application domain. For example, the user can fly through a three-dimensional application domain, and always move to the personal domain by moving a cursor near one extreme of the display.

  14. Electric-field-driven dynamics of magnetic domain walls in magnetic nanowires patterned on ferroelectric domains

    OpenAIRE

    Van de Wiele, Ben; Leliaert, Jonathan; Franke, Kévin; van Dijken, Sebastiaan

    2016-01-01

    Strong coupling of magnetic domain walls onto straight ferroelastic boundaries of a ferroelectric layer enables full and reversible electric-field control of magnetic domain wall motion. In this paper, the dynamics of this new driving mechanism is analyzed using micromagnetic simulations. We show that transverse domain walls with a near-180° spin structure are stabilized in magnetic nanowires and that electric fields can move these walls with high velocities. Above a critical velocity, which ...

  15. Conversion of Dielectric Data from the Time Domain to the Frequency Domain

    Directory of Open Access Journals (Sweden)

    Vladimir Durman

    2005-01-01

    Full Text Available Polarisation and conduction processes in dielectric systems can be identified by the time domain or the frequency domain measurements. If the systems is a linear one, the results of the time domain measurements can be transformed into the frequency domain, and vice versa. Commonly, the time domain data of the absorption conductivity are transformed into the frequency domain data of the dielectric susceptibility. In practice, the relaxation are mainly evaluated by the frequency domain data. In the time domain, the absorption current measurement were prefered up to now. Recent methods are based on the recovery voltage measurements. In this paper a new method of the recovery data conversion from the time the frequency domain is proposed. The method is based on the analysis of the recovery voltage transient based on the Maxwell equation for the current density in a dielectric. Unlike the previous published solutions, the Laplace fransform was used to derive a formula suitable for practical purposes. the proposed procedure allows also calculating of the insulation resistance and separating the polarisation and conduction losses.

  16. Low energy electron imaging of domains and domain walls in magnesium-doped lithium niobate

    Science.gov (United States)

    Nataf, G. F.; Grysan, P.; Guennou, M.; Kreisel, J.; Martinotti, D.; Rountree, C. L.; Mathieu, C.; Barrett, N.

    2016-09-01

    The understanding of domain structures, specifically domain walls, currently attracts a significant attention in the field of (multi)-ferroic materials. In this article, we analyze contrast formation in full field electron microscopy applied to domains and domain walls in the uniaxial ferroelectric lithium niobate, which presents a large 3.8 eV band gap and for which conductive domain walls have been reported. We show that the transition from Mirror Electron Microscopy (MEM - electrons reflected) to Low Energy Electron Microscopy (LEEM - electrons backscattered) gives rise to a robust contrast between domains with upwards (Pup) and downwards (Pdown) polarization, and provides a measure of the difference in surface potential between the domains. We demonstrate that out-of-focus conditions of imaging produce contrast inversion, due to image distortion induced by charged surfaces, and also carry information on the polarization direction in the domains. Finally, we show that the intensity profile at domain walls provides experimental evidence for a local stray, lateral electric field.

  17. A Review of Domain Modelling and Domain Imaging Techniques in Ferroelectric Crystals

    Directory of Open Access Journals (Sweden)

    John E. Huber

    2011-02-01

    Full Text Available The present paper reviews models of domain structure in ferroelectric crystals, thin films and bulk materials. Common crystal structures in ferroelectric materials are described and the theory of compatible domain patterns is introduced. Applications to multi-rank laminates are presented. Alternative models employing phase-field and related techniques are reviewed. The paper then presents methods of observing ferroelectric domain structure, including optical, polarized light, scanning electron microscopy, X-ray and neutron diffraction, atomic force microscopy and piezo-force microscopy. Use of more than one technique for unambiguous identification of the domain structure is also described.

  18. Low energy electron imaging of domains and domain walls in magnesium-doped lithium niobate

    Science.gov (United States)

    Nataf, G. F.; Grysan, P.; Guennou, M.; Kreisel, J.; Martinotti, D.; Rountree, C. L.; Mathieu, C.; Barrett, N.

    2016-01-01

    The understanding of domain structures, specifically domain walls, currently attracts a significant attention in the field of (multi)-ferroic materials. In this article, we analyze contrast formation in full field electron microscopy applied to domains and domain walls in the uniaxial ferroelectric lithium niobate, which presents a large 3.8 eV band gap and for which conductive domain walls have been reported. We show that the transition from Mirror Electron Microscopy (MEM – electrons reflected) to Low Energy Electron Microscopy (LEEM – electrons backscattered) gives rise to a robust contrast between domains with upwards (Pup) and downwards (Pdown) polarization, and provides a measure of the difference in surface potential between the domains. We demonstrate that out-of-focus conditions of imaging produce contrast inversion, due to image distortion induced by charged surfaces, and also carry information on the polarization direction in the domains. Finally, we show that the intensity profile at domain walls provides experimental evidence for a local stray, lateral electric field. PMID:27608605

  19. Domain structure of Lassa virus L protein.

    Science.gov (United States)

    Brunotte, Linda; Lelke, Michaela; Hass, Meike; Kleinsteuber, Katja; Becker-Ziaja, Beate; Günther, Stephan

    2011-01-01

    The 200-kDa L protein of arenaviruses plays a central role in viral genome replication and transcription. This study aimed at providing evidence for the domain structure of L protein by combining bioinformatics with a stepwise mutagenesis approach using the Lassa virus minireplicon system. Potential interdomain linkers were predicted using various algorithms. The prediction was challenged by insertion of flexible sequences into the predicted linkers. Insertion of 5 or 10 amino acid residues was tolerated at seven sites (S407, G446, G467, G774, G939, S1952, and V2074 in Lassa virus AV). At two of these sites, G467 and G939, L protein could be split into an N-terminal and a C-terminal part, which were able to trans-complement each other and reconstitute a functional complex upon coexpression. Coimmunoprecipitation studies revealed physical interaction between the N- and C-terminal domains, irrespective of whether L protein was split at G467 or G939. In confocal immunofluorescence microscopy, the N-terminal domains showed a dot-like, sometimes perinuclear, cytoplasmic distribution similar to that of full-length L protein, while the C-terminal domains were homogenously distributed in cytoplasm. The latter were redistributed into the dot-like structures upon coexpression with the corresponding N-terminal domain. In conclusion, this study demonstrates two interdomain linkers in Lassa virus L protein, at G467 and G939, suggesting that L protein is composed of at least three structural domains spanning residues 1 to 467, 467 to 939, and 939 to 2220. The first domain seems to mediate accumulation of L protein into cytoplasmic dot-like structures.

  20. The Evolutionary History of Protein Domains Viewed by Species Phylogeny

    OpenAIRE

    Song Yang; Philip E. Bourne

    2009-01-01

    BACKGROUND: Protein structural domains are evolutionary units whose relationships can be detected over long evolutionary distances. The evolutionary history of protein domains, including the origin of protein domains, the identification of domain loss, transfer, duplication and combination with other domains to form new proteins, and the formation of the entire protein domain repertoire, are of great interest. METHODOLOGY/PRINCIPAL FINDINGS: A methodology is presented for providing a parsimon...

  1. Wavefield Extrapolation in Pseudo-depth Domain

    KAUST Repository

    Ma, Xuxin

    2011-12-11

    Wave-equation based seismic migration and inversion tools are widely used by the energy industry to explore hydrocarbon and mineral resources. By design, most of these techniques simulate wave propagation in a space domain with the vertical axis being depth measured from the surface. Vertical depth is popular because it is a straightforward mapping of the subsurface space. It is, however, not computationally cost-effective because the wavelength changes with local elastic wave velocity, which in general increases with depth in the Earth. As a result, the sampling per wavelength also increases with depth. To avoid spatial aliasing in deep fast media, the seismic wave is oversampled in shallow slow media and therefore increase the total computation cost. This issue is effectively tackled by using the vertical time axis instead of vertical depth. This is because in a vertical time representation, the "wavelength" is essentially time period for vertical rays. This thesis extends the vertical time axis to the pseudo-depth axis, which features distance unit while preserving the properties of the vertical time representation. To explore the potentials of doing wave-equation based imaging in the pseudo-depth domain, a Partial Differential Equation (PDE) is derived to describe acoustic wave in this new domain. This new PDE is inherently anisotropic because the use of a constant vertical velocity to convert between depth and vertical time. Such anisotropy results in lower reflection coefficients compared with conventional space domain modeling results. This feature is helpful to suppress the low wavenumber artifacts in reverse-time migration images, which are caused by the widely used cross-correlation imaging condition. This thesis illustrates modeling acoustic waves in both conventional space domain and pseudo-depth domain. The numerical tool used to model acoustic waves is built based on the lowrank approximation of Fourier integral operators. To investigate the potential

  2. The Popeye domain-containing gene family.

    Science.gov (United States)

    Brand, Thomas

    2005-01-01

    The Popeye domain-containing gene family has been isolated on the basis of a subtractive screen aiming at the identification of novel genes with a heart-restricted gene expression pattern. The gene family codes for membrane proteins containing three transmembrane domains. The carboxy-terminal part of the protein is localized to the cytoplasm and contains a protein domain with high sequence conservation named the Popeye domain. This domain is involved in protein homo dimerization. The gene family is expressed in heart and skeletal muscle cells as well as smooth muscle cells. In addition, Popdc genes are expressed in other cell types such as neuronal cells in restricted areas of the brain, spinal cord, and dorsal root ganglia, and in various epithelial cells. Recently, it has been proposed that Popdc proteins may function as a novel family of adhesion proteins. That the expression pattern has been conserved during evolution and is very similar in all vertebrate classes and also in basal chordates suggests that Popdc proteins play an important role in cardiac and skeletal muscle.

  3. Work-domain knowledge in usability evaluation

    DEFF Research Database (Denmark)

    Følstad, Asbjørn; Hornbæk, Kasper

    2010-01-01

    whether such interpretation phases improve the relevance of usability evaluations in the development of work-domain specific systems. The study included two development cases. We conclude that the interpretation phases generate additional insight and redesign suggestions related to observed usability...... impact on the software development process. The benefits of the interpretation phases may be explained by the access these provide both to the test participants’ work-domain knowledge and to their experiences as users. .......Usability evaluation helps to determine whether interactive systems support users in their work tasks. However, knowledge about those tasks and, more generally, about the work-domain is difficult to bring to bear on the processes and outcome of usability evaluation. One way to include such work...

  4. Cross domains Arabic named entity recognition system

    KAUST Repository

    Al-Ahmari, S. Saad

    2016-07-11

    Named Entity Recognition (NER) plays an important role in many Natural Language Processing (NLP) applications such as; Information Extraction (IE), Question Answering (QA), Text Clustering, Text Summarization and Word Sense Disambiguation. This paper presents the development and implementation of domain independent system to recognize three types of Arabic named entities. The system works based on a set of domain independent grammar-rules along with Arabic part of speech tagger in addition to gazetteers and lists of trigger words. The experimental results shown, that the system performed as good as other systems with better results in some cases of cross-domains corpora. © (2016) COPYRIGHT Society of Photo-Optical Instrumentation Engineers (SPIE). Downloading of the abstract is permitted for personal use only.

  5. Collaborative Detection of Fast Flux Phishing Domains

    Directory of Open Access Journals (Sweden)

    Chenfeng Vincent Zhou

    2009-02-01

    Full Text Available Phishing is a significant security threat to users of Internet services. Nowadays, phishing has become more resilient to detection and trace-back with the invention of Fast Flux (FF service networks. We propose two approaches to correlate evidence from multiple DNS servers and multiple suspect FF domains. Real-world experiments show that our correlation approaches speed-up FF domain detection, based on an analytical model that we propose to quantify the number of DNS queries needed to confirm a FF domain. We also show how our correlation scheme can be implemented on a large scale by using a decentralized publish-subscribe correlation model called LarSID, which is more scalable than a fully centralized architecture.

  6. Transactions in domain-specific information systems

    Science.gov (United States)

    Zacek, Jaroslav

    2017-07-01

    Substantial number of the current information system (IS) implementations is based on transaction approach. In addition, most of the implementations are domain-specific (e.g. accounting IS, resource planning IS). Therefore, we have to have a generic transaction model to build and verify domain-specific IS. The paper proposes a new transaction model for domain-specific ontologies. This model is based on value oriented business process modelling technique. The transaction model is formalized by the Petri Net theory. First part of the paper presents common business processes and analyses related to business process modeling. Second part defines the transactional model delimited by REA enterprise ontology paradigm and introduces states of the generic transaction model. The generic model proposal is defined and visualized by the Petri Net modelling tool. Third part shows application of the generic transaction model. Last part of the paper concludes results and discusses a practical usability of the generic transaction model.

  7. Anomalous feedback and negative domain wall resistance

    Science.gov (United States)

    Cheng, Ran; Zhu, Jian-Gang; Xiao, Di

    2016-11-01

    Magnetic induction can be regarded as a negative feedback effect, where the motive-force opposes the change of magnetic flux that generates the motive-force. In artificial electromagnetics emerging from spintronics, however, this is not necessarily the case. By studying the current-induced domain wall dynamics in a cylindrical nanowire, we show that the spin motive-force exerting on electrons can either oppose or support the applied current that drives the domain wall. The switching into the anomalous feedback regime occurs when the strength of the dissipative torque β is about twice the value of the Gilbert damping constant α. The anomalous feedback manifests as a negative domain wall resistance, which has an analogy with the water turbine.

  8. Hallucinating face in the DCT domain.

    Science.gov (United States)

    Zhang, Wei; Cham, Wai-Kuen

    2011-10-01

    In this paper, we propose a novel learning-based face hallucination framework built in the DCT domain, which can produce a high-resolution face image from a single low-resolution one. The problem is formulated as inferring the DCT coefficients in frequency domain instead of estimating pixel intensities in spatial domain. Our study shows that DC coefficients can be estimated fairly accurately by simple interpolation-based methods. AC coefficients, which contain the information of local features of face image, cannot be estimated well using interpolation. A simple but effective learning-based inference model is proposed to infer the ac coefficients. Experiments have been conducted to demonstrate the effectiveness of the proposed method in producing high quality hallucinated face images.

  9. On thick domain walls in general relativity

    Science.gov (United States)

    Goetz, Guenter; Noetzold, Dirk

    1989-01-01

    Planar scalar field configurations in general relativity differ considerably from those in flat space. It is shown that static domain walls of finite thickness in curved space-time do not possess a reflection symmetry. At infinity, the space-time tends to the Taub vacuum on one side of the wall and to the Minkowski vacuum (Rindler space-time) on the other. Massive test particles are always accelerated towards the Minkowski side, i.e., domain walls are attractive on the Taub side, but repulsive on the Minkowski side (Taub-vacuum cleaner). It is also proved that the pressure in all directions is always negative. Finally, a brief comment is made concerning the possibility of infinite, i.e., bigger than horizon size, domain walls in our universe. All of the results are independent of the form of the potential V(phi) greater than or equal to 0 of the scalar field phi.

  10. Full traveltime inversion in source domain

    KAUST Repository

    Liu, Lu

    2017-06-01

    This paper presents a new method of source-domain full traveltime inversion (FTI). The objective of this study is automatically building near-surface velocity using the early arrivals of seismic data. This method can generate the inverted velocity that can kinetically best match the reconstructed plane-wave source of early arrivals with true source in source domain. It does not require picking first arrivals for tomography, which is one of the most challenging aspects of ray-based tomographic inversion. Besides, this method does not need estimate the source wavelet, which is a necessity for receiver-domain wave-equation velocity inversion. Furthermore, we applied our method on one synthetic dataset; the results show our method could generate a reasonable background velocity even when shingling first arrivals exist and could provide a good initial velocity for the conventional full waveform inversion (FWI).

  11. Matters of fiber size and myonuclear domain

    DEFF Research Database (Denmark)

    Karlsen, Anders; Couppé, Christian; Andersen, Jesper L.;

    2015-01-01

    INTRODUCTION: The relationship between fiber size and myonuclear content is understood poorly. METHODS: Biopsy cross-sections from young and old trained and untrained healthy individuals were analyzed for fiber area and myonuclei, and 2 fiber size-dependent cluster analyses were performed. RESULTS......: Comparing fibers of similar size, no effect of training or age was found for myonuclear domain. There was a linear relationship between fiber area and myonuclei per fiber (r=0.99; Pfiber area and domain (r=0.97-0.99; P... in fibers fibers below 3,000 μm(2) was observed in the old. DISCUSSION: These findings suggest that age-related reductions in myonuclear domain size could be explained by a larger proportion of small fibers and highlight the usefulness of fiber size...

  12. Domain Theory, Its Models and Concepts

    DEFF Research Database (Denmark)

    Andreasen, Mogens Myrup; Howard, Thomas J.; Bruun, Hans Peter Lomholt

    2014-01-01

    Domain Theory is a systems approach for the analysis and synthesis of products. Its basic idea is to view a product as systems of activities, organs and parts and to define structure, elements, behaviour and function in these domains. The theory is a basis for a long line of research contributions...... and industrial applications especially for the DFX areas (not reported here) and for product modelling. The theory therefore contains a rich ontology of interrelated concepts. The Domain Theory is not aiming to create normative methods but the creation of a collection of concepts related to design phenomena......, which can support design work and to form elements of designers’ mindsets and thereby their practice. The theory is a model-based theory, which means it is composed of concepts and models, which explains certain design phenomena. Many similar theories are described in the literature with differences...

  13. Quasiconformal Mappings and Weakly John Domains

    Institute of Scientific and Technical Information of China (English)

    褚玉明

    2003-01-01

    @@ Let D be a bounded domain in R2 and c (≥ 1) be a constant. We say that D is a c-Johndomain if there exists x0 ∈ D such that for any x ∈ D, there must be a rectifiable curve γ C D,which joins x and x0, satisfying l(γ(x, y)) ≤ cd(y, D) for any y ∈γ, where l(γ(x, y)) denotesthe Euclidean length of the subcurve γ between x and y, d(y, D) is the Euclidean distance fromy to the boundary D of D. We say that D is a John domain if D is a c-John domain for somec (≥ 1).

  14. Electric-field-driven dynamics of magnetic domain walls in magnetic nanowires patterned on ferroelectric domains

    Science.gov (United States)

    Van de Wiele, Ben; Leliaert, Jonathan; Franke, Kévin J. A.; van Dijken, Sebastiaan

    2016-03-01

    Strong coupling of magnetic domain walls onto straight ferroelastic boundaries of a ferroelectric layer enables full and reversible electric-field control of magnetic domain wall motion. In this paper, the dynamics of this new driving mechanism is analyzed using micromagnetic simulations. We show that transverse domain walls with a near-180° spin structure are stabilized in magnetic nanowires and that electric fields can move these walls with high velocities. Above a critical velocity, which depends on material parameters, nanowire geometry and the direction of domain wall motion, the magnetic domain walls depin abruptly from the ferroelastic boundaries. Depinning evolves either smoothly or via the emission and annihilation of a vortex or antivortex core (Walker breakdown). In both cases, the magnetic domain wall slows down after depinning in an oscillatory fashion and eventually comes to a halt. The simulations provide design rules for hybrid ferromagnetic-ferroelectric domain-wall-based devices and indicate that material disorder and structural imperfections only influence Walker-breakdown-like depinning at high domain wall velocities.

  15. PTEN-PDZ domain interactions: Binding of PTEN to PDZ domains of PTPN13.

    NARCIS (Netherlands)

    Sotelo, N.S.; Schepens, J.T.G.; Valiente, M.; Hendriks, W.J.A.J.; Pulido, R.

    2015-01-01

    Protein modular interactions mediated by PDZ domains are essential for the establishment of functional protein networks controlling diverse cellular functions. The tumor suppressor PTEN possesses a C-terminal PDZ-binding motif (PDZ-BM) that is recognized by a specific set of PDZ domains from scaffol

  16. SH3 Domains Differentially Stimulate Distinct Dynamin I Assembly Modes and G Domain Activity.

    Directory of Open Access Journals (Sweden)

    Sai Krishnan

    Full Text Available Dynamin I is a highly regulated GTPase enzyme enriched in nerve terminals which mediates vesicle fission during synaptic vesicle endocytosis. One regulatory mechanism involves its interactions with proteins containing Src homology 3 (SH3 domains. At least 30 SH3 domain-containing proteins bind dynamin at its proline-rich domain (PRD. Those that stimulate dynamin activity act by promoting its oligomerisation. We undertook a systematic parallel screening of 13 glutathione-S-transferase (GST-tagged endocytosis-related SH3 domains on dynamin binding, GTPase activity and oligomerisation. No correlation was found between dynamin binding and their potency to stimulate GTPase activity. There was limited correlation between the extent of their ability to stimulate dynamin activity and the level of oligomerisation, indicating an as yet uncharacterised allosteric coupling of the PRD and G domain. We examined the two variants, dynamin Iab and Ibb, which differ in the alternately splice middle domain α2 helix. They responded differently to the panel of SH3s, with the extent of stimulation between the splice variants varying greatly between the SH3s. This study reveals that SH3 binding can act as a heterotropic allosteric regulator of the G domain via the middle domain α2 helix, suggesting an involvement of this helix in communicating the PRD-mediated allostery. This indicates that SH3 binding both stabilises multiple conformations of the tetrameric building block of dynamin, and promotes assembly of dynamin-SH3 complexes with distinct rates of GTP hydrolysis.

  17. Design PID controllers for desired time-domain or frequency-domain response.

    Science.gov (United States)

    Zhang, Weidong; Xi, Yugeng; Yang, Genke; Xu, Xiaoming

    2002-10-01

    Practical requirements on the design of control systems, especially process control systems, are usually specified in terms of time-domain response, such as overshoot and rise time, or frequency-domain response, such as resonance peak and stability margin. Although numerous methods have been developed for the design of the proportional-integral-derivative (PID) controller, little work has been done in relation to the quantitative time-domain and frequency-domain responses. In this paper, we study the following problem: Given a nominal stable process with time delay, we design a suboptimal PID controller to achieve the required time-domain response or frequency-domain response for the nominal system or the uncertain system. An H(infinity) PID controller is developed based on optimal control theory and the parameters are derived analytically. Its properties are investigated and compared with that of two developed suboptimal controllers: an H2 PID controller and a Maclaurin PID controller. It is shown that all three controllers can provide the quantitative time-domain and frequency-domain responses.

  18. Impact of Domain Modeling Techniques on the Quality of Domain Model: An Experiment

    Directory of Open Access Journals (Sweden)

    Hiqmat Nisa

    2016-10-01

    Full Text Available The unified modeling language (UML is widely used to analyze and design different software development artifacts in an object oriented development. Domain model is a significant artifact that models the problem domain and visually represents real world objects and relationships among them. It facilitates the comprehension process by identifying the vocabulary and key concepts of the business world. Category list technique identifies concepts and associations with the help of pre defined categories, which are important to business information systems. Whereas noun phrasing technique performs grammatical analysis of use case description to recognize concepts and associations. Both of these techniques are used for the construction of domain model, however, no empirical evidence exists that evaluates the quality of the resultant domain model constructed via these two basic techniques. A controlled experiment was performed to investigate the impact of category list and noun phrasing technique on quality of the domain model. The constructed domain model is evaluated for completeness, correctness and effort required for its design. The obtained results show that category list technique is better than noun phrasing technique for the identification of concepts as it avoids generating unnecessary elements i.e. extra concepts, associations and attributes in the domain model. The noun phrasing technique produces a comprehensive domain model and requires less effort as compared to category list. There is no statistically significant difference between both techniques in case of correctness.

  19. Impact of Domain Modeling Techniques on the Quality of Domain Model: An Experiment

    Directory of Open Access Journals (Sweden)

    Hiqmat Nisa

    2016-11-01

    Full Text Available The unified modeling language (UML is widely used to analyze and design different software development artifacts in an object oriented development. Domain model is a significant artifact that models the problem domain and visually represents real world objects and relationships among them. It facilitates the comprehension process by identifying the vocabulary and key concepts of the business world. Category list technique identifies concepts and associations with the help of pre defined categories, which are important to business information systems. Whereas noun phrasing technique performs grammatical analysis of use case description to recognize concepts and associations. Both of these techniques are used for the construction of domain model, however, no empirical evidence exists that evaluates the quality of the resultant domain model constructed via these two basic techniques. A controlled experiment was performed to investigate the impact of category list and noun phrasing technique on quality of the domain model. The constructed domain model is evaluated for completeness, correctness and effort required for its design. The obtained results show that category list technique is better than noun phrasing technique for the identification of concepts as it avoids generating unnecessary elements i.e. extra concepts, associations and attributes in the domain model. The noun phrasing technique produces a comprehensive domain model and requires less effort as compared to category list. There is no statistically significant difference between both techniques in case of correctness.

  20. Changing domains in human capital measurement

    Directory of Open Access Journals (Sweden)

    Pharny D. Chrysler-Fox

    2014-02-01

    Full Text Available Orientation: The management context is dynamic; this is especially evident in human capital as the primary source of value creation as opposed to physical and natural resources. In response, measurement methodologies have moved from a transactional approach (strategy implementation to a transformational approach (human capital contribution paradigm, as well as diverging into different purposes. To date, there has been little overlap on recent domains to consider in managing and measuring the contribution of the human resource function and employees, and how to unlock and add value.Research purpose: The aim of the study was to explore and describe changing domains within human capital management to be managed and measured.Motivation for the study: The motivation was to advance the understanding of changing measurement domains to aid practitioners to manage and measure the contribution of the human resource function and employees, in order to unlock and add value and ultimately contribute to the success of an organisation.Research design, approach and method: Unstructured, in-depth interview data of purposively selected cases from a selected panel of human resource practitioners specialising in human capital measurement was thematically analysed in this exploratory-descriptive investigation.Main findings: Findings suggested that seven domains should be managed and measured. These domains highlight new areas of impact and levels of management. In addition, crossdomain relationships in measurement allow for an understanding of the impact and potential value on which to capitalise.Practical/managerial implications: New domains to manage and measure focus the attention of practitioners beyond the transactional performance management paradigm to a transformational approach to influence the business strategy. Higher education institutions need to develop students’ cognitive skills to facilitate systems thinking.Contribution: This study suggests a new

  1. Discoidin Domain Receptors Role in Human Diseases

    Directory of Open Access Journals (Sweden)

    Iker BADIOLA

    2011-11-01

    Full Text Available Discoidin Domain Receptor 1 and Discodin Domain Receptor 2 are the two only members of the DDR family. The DDR family is a Tyrosine Kinase Receptor (TKR family with some peculiarities compared with other Tyrosine Kinase Receptors such as their natural ligand; which in this case is the fibrillar collagen; or the slow phosphorylation pattern. These peculiarities confer a special role to the receptors present in many diseases development processes as cancer, cirrhosis or lung fibrosis. In this review it is described the overview of the DDRs structure and their role in the different disease development and the possibility to consider them as therapeutic targets.

  2. Clojure for domain-specific languages

    CERN Document Server

    Kelker, Ryan D

    2013-01-01

    An example-oriented approach to develop custom domain-specific languages.If you've already developed a few Clojure applications and wish to expand your knowledge on Clojure or domain-specific languages in general, then this book is for you. If you're an absolute Clojure beginner, then you may only find the detailed examples of the core Clojure components of value. If you've developed DSLs in other languages, this Lisp and Java-based book might surprise you with the power of Clojure.

  3. Load Estimation by Frequency Domain Decomposition

    DEFF Research Database (Denmark)

    Pedersen, Ivar Chr. Bjerg; Hansen, Søren Mosegaard; Brincker, Rune;

    2007-01-01

    When performing operational modal analysis the dynamic loading is unknown, however, once the modal properties of the structure have been estimated, the transfer matrix can be obtained, and the loading can be estimated by inverse filtering. In this paper loads in frequency domain are estimated...... by analysis of simulated responses of a 4 DOF system, for which the exact modal parameters are known. This estimation approach entails modal identification of the natural eigenfrequencies, mode shapes and damping ratios by the frequency domain decomposition technique. Scaled mode shapes are determined by use...

  4. Multigrid Algorithms for Domain-Wall Fermions

    CERN Document Server

    Cohen, Saul D; Clark, M A; Osborn, J C

    2012-01-01

    We describe an adaptive multigrid algorithm for solving inverses of the domain-wall fermion operator. Our multigrid algorithm uses an adaptive projection of near-null vectors of the domain-wall operator onto coarser four-dimensional lattices. This extension of multigrid techniques to a chiral fermion action will greatly reduce overall computation cost, and the elimination of the fifth dimension in the coarse space reduces the relative cost of using chiral fermions compared to discarding this symmetry. We demonstrate near-elimination of critical slowing as the quark mass is reduced and small volume dependence, which may be suppressed by taking advantage of the recursive nature of the algorithm.

  5. Convergence Analysis of a Domain Decomposition Paradigm

    Energy Technology Data Exchange (ETDEWEB)

    Bank, R E; Vassilevski, P S

    2006-06-12

    We describe a domain decomposition algorithm for use in several variants of the parallel adaptive meshing paradigm of Bank and Holst. This algorithm has low communication, makes extensive use of existing sequential solvers, and exploits in several important ways data generated as part of the adaptive meshing paradigm. We show that for an idealized version of the algorithm, the rate of convergence is independent of both the global problem size N and the number of subdomains p used in the domain decomposition partition. Numerical examples illustrate the effectiveness of the procedure.

  6. [Development of domain specific search engines].

    Science.gov (United States)

    Takai, T; Tokunaga, M; Maeda, K; Kaminuma, T

    2000-01-01

    As cyber space exploding in a pace that nobody has ever imagined, it becomes very important to search cyber space efficiently and effectively. One solution to this problem is search engines. Already a lot of commercial search engines have been put on the market. However these search engines respond with such cumbersome results that domain specific experts can not tolerate. Using a dedicate hardware and a commercial software called OpenText, we have tried to develop several domain specific search engines. These engines are for our institute's Web contents, drugs, chemical safety, endocrine disruptors, and emergent response for chemical hazard. These engines have been on our Web site for testing.

  7. Small domain-size multiblock copolymer electrolytes

    Science.gov (United States)

    Pistorino, Jonathan; Eitouni, Hany Basam

    2016-09-20

    New block polymer electrolytes have been developed which have higher conductivities than previously reported for other block copolymer electrolytes. The new materials are constructed of multiple blocks (>5) of relatively low domain size. The small domain size provides greater protection against formation of dendrites during cycling against lithium in an electrochemical cell, while the large total molecular weight insures poor long range alignment, which leads to higher conductivity. In addition to higher conductivity, these materials can be more easily synthesized because of reduced requirements on the purity level of the reagents.

  8. Magnetic domains the analysis of magnetic microstructures

    CERN Document Server

    Hubert, Alex

    1998-01-01

    The book gives a systematic and comprehensive survey of the complete area of magnetic microstructures. It reaches from micromagnetism of nanoparticles to complex structures of extended magnetic materials. The book starts with a comprehensive evaluation of traditional and modern experimental methods for the observation of magnetic domains and continues with the treatment of important methods for the theoretical analysis of magnetic microcstructures. A survey of the necessary techniques in materials characterization is given. The book offers an observation and analysis of magnetic domains in all

  9. Skyrmions from Instantons inside Domain Walls

    CERN Document Server

    Eto, M; Ohashi, K; Tong, D; Eto, Minoru; Nitta, Muneto; Ohashi, Keisuke; Tong, David

    2005-01-01

    Some years ago, Atiyah and Manton described a method to construct approximate Skyrmion solutions from Yang-Mills instantons. Here we present a dynamical realization of this construction using domain walls in a five-dimensional gauge theory. The non-abelian gauge symmetry is broken in each vacuum but restored in the core of the domain wall, allowing instantons to nestle inside the wall. We show that the worldvolume dynamics of the wall is given by the Skyrme model, including the four-derivative term, and the instantons appear as Skyrmions.

  10. Differential ghost imaging in time domain

    Science.gov (United States)

    O-oka, Yoshiki; Fukatsu, Susumu

    2017-08-01

    Differential ghost imaging is attempted in time domain, i.e., temporal differential ghost imaging (TDGI), using pseudo-randomized light pulses and a temporal object consisting of no-return-to-zero bit patterns of varying duty. Evaluation of the signal-to-noise characteristics by taking into account errors due to false cross-correlation between the reference and the bucket detector readings indicates that the TDGI outperforms its non-differential counterpart, i.e., time-domain GI, in terms of consistently high and even duty-independent signal-to-noise ratios that are achieved.

  11. Small domain-size multiblock copolymer electrolytes

    Energy Technology Data Exchange (ETDEWEB)

    Pistorino, Jonathan; Eitouni, Hany Basam

    2016-09-20

    New block polymer electrolytes have been developed which have higher conductivities than previously reported for other block copolymer electrolytes. The new materials are constructed of multiple blocks (>5) of relatively low domain size. The small domain size provides greater protection against formation of dendrites during cycling against lithium in an electrochemical cell, while the large total molecular weight insures poor long range alignment, which leads to higher conductivity. In addition to higher conductivity, these materials can be more easily synthesized because of reduced requirements on the purity level of the reagents.

  12. Narrowing the conformational space sampled by two-domain proteins with paramagnetic probes in both domains

    Energy Technology Data Exchange (ETDEWEB)

    Dasgupta, Soumyasri; Hu Xiaoyu [University of Florence, Magnetic Resonance Center (CERM) (Italy); Keizers, Peter H. J.; Liu Weimin [Leiden University, Leiden Institute of Chemistry, Gorlaeus Laboratories (Netherlands); Luchinat, Claudio, E-mail: luchinat@cerm.unifi.it; Nagulapalli, Malini [University of Florence, Magnetic Resonance Center (CERM) (Italy); Overhand, Mark [Leiden University, Leiden Institute of Chemistry, Gorlaeus Laboratories (Netherlands); Parigi, Giacomo [University of Florence, Magnetic Resonance Center (CERM) (Italy); Sgheri, Luca [Istituto per le Applicazioni del Calcolo, Sezione di Firenze, CNR (Italy); Ubbink, Marcellus [Leiden University, Leiden Institute of Chemistry, Gorlaeus Laboratories (Netherlands)

    2011-11-15

    Calmodulin is a two-domain protein which in solution can adopt a variety of conformations upon reorientation of its domains. The maximum occurrence (MO) of a set of calmodulin conformations that are representative of the overall conformational space possibly sampled by the protein, has been calculated from the paramagnetism-based restraints. These restraints were measured after inclusion of a lanthanide binding tag in the C-terminal domain to supplement the data obtained by substitution of three paramagnetic lanthanide ions to the calcium ion in the second calcium binding loop of the N-terminal domain. The analysis shows that the availability of paramagnetic restraints arising from metal ions placed on both domains, reduces the MO of the conformations to different extents, thereby helping to identify those conformations that can be mostly sampled by the protein.

  13. Roc, a Ras/GTPase domain in complex proteins

    NARCIS (Netherlands)

    Bosgraaf, Leonard; Haastert, Peter J.M. van

    2003-01-01

    We identified a novel group of the Ras/GTPase superfamily, termed Roc, that is present as domain in complex proteins together with other domains, including leucine-rich repeats (LRRs), ankyrin repeats, WD40 repeats, kinase domains, RasGEF and RhoGAP domains. Roc is always succeeded by a novel 300–40

  14. Software Ecosystems for the Life Sciences Application Domains

    NARCIS (Netherlands)

    Tekinerdogan, B.; Scholten, H.

    2015-01-01

    Software ecosystems (SECOs) are gaining importance in and have been applied to different application domains. In this paper we focus on the needs for SECOs for the life science application domains. Similar to other domains the life science application domains also witnesses the emergence and applica

  15. On the Approaching Domain Obtained by Finite Element Method

    Institute of Scientific and Technical Information of China (English)

    邹青松; 李永海

    2002-01-01

    The use of finite element method leads to replacing the initial domain by an approaching domain,Under some appropriate assumptions,we prove that there exists a W1,+∞-diffeomorphism from the original domain to the approaching domain.

  16. Reporting Valid and Reliable Overall Scores and Domain Scores

    Science.gov (United States)

    Yao, Lihua

    2010-01-01

    In educational assessment, overall scores obtained by simply averaging a number of domain scores are sometimes reported. However, simply averaging the domain scores ignores the fact that different domains have different score points, that scores from those domains are related, and that at different score points the relationship between overall…

  17. Domain-specific language design requires feature descriptions

    NARCIS (Netherlands)

    A. van Deursen (Arie); P. Klint (Paul)

    2001-01-01

    textabstractA domain-specific language (DSL) provides a notation tailored towards an application domain and is based on the relevant concepts and features of that domain. As such, a DSL is a means to describe and generate members of a family of programs in the domain. A prerequisite for the design

  18. A NONOVERLAPPING DOMAIN DECOMPOSITION METHOD FOR EXTERIOR 3-D PROBLEM

    Institute of Scientific and Technical Information of China (English)

    De-hao Yu; Ji-ming Wu; Ji-ming Wu

    2001-01-01

    In this paper, a nonoverlapping domain decomposition method, which is based on the natural boundary reduction(cf. [4, 13, 15]), is developed to solve the boundary value problem in exterior three-dimensional domain of general shape. Convergence analyses both for the exterior spherical domain and the general exterior domain are made. Some numerical examples are also provided to illustrate the method.

  19. User Requirements and Domain Model Engineering

    NARCIS (Netherlands)

    Specht, Marcus; Glahn, Christian

    2006-01-01

    Specht, M., & Glahn, C. (2006). User requirements and domain model engineering. Presentation at International Workshop in Learning Networks for Lifelong Competence Development. March, 30-31, 2006. Sofia, Bulgaria: TENCompetence Conference. Retrieved June 30th, 2006, from http://dspace.learningnetwor

  20. User Requirements and Domain Model Engineering

    NARCIS (Netherlands)

    Specht, Marcus; Glahn, Christian

    2006-01-01

    Specht, M., & Glahn, C. (2006). User requirements and domain model engineering. Presentation at International Workshop in Learning Networks for Lifelong Competence Development. March, 30-31, 2006. Sofia, Bulgaria: TENCompetence Conference. Retrieved June 30th, 2006, from http://dspace.learningnetwor