WorldWideScience

Sample records for superfund site clean-up

  1. National Policies for cleaning up contaminated sites

    NARCIS (Netherlands)

    Veenman, S.A.

    2014-01-01

    Policies for the remediation of contaminated sites emerged relatively late as a subfield of environmental protection. The policy area is adjacent to other policies, such as waste policy, which often includes provisions on how to deal with waste dumps, as well as soil and groundwater protection polic

  2. Superfund Site Information

    Data.gov (United States)

    U.S. Environmental Protection Agency — This asset includes a number of individual data sets related to site-specific information for Superfund, which is governed under the Comprehensive Environmental...

  3. SITE COMPREHENSIVE LISTING (CERCLIS) (Superfund) - NPL Sites

    Data.gov (United States)

    U.S. Environmental Protection Agency — National Priorities List (NPL) Sites - The Comprehensive Environmental Response, Compensation and Liability Information System (CERCLIS) (Superfund) Public Access...

  4. Superfund Site Information - Site Sampling Data

    Data.gov (United States)

    U.S. Environmental Protection Agency — This asset includes Superfund site-specific sampling information including location of samples, types of samples, and analytical chemistry characteristics of...

  5. Superfund National Priority List (NPL) Site Boundaries

    Data.gov (United States)

    U.S. Environmental Protection Agency — A set of site boundaries for each site in EPA Region 1 (Connecticut, Maine, Massachusetts, New Hampshire, Rhode Island, and Vermont) on EPA's Superfund National...

  6. SITE COMPREHENSIVE LISTING (CERCLIS) (Superfund)

    Data.gov (United States)

    U.S. Environmental Protection Agency — The Comprehensive Environmental Response, Compensation and Liability Information System (CERCLIS) (Superfund) Public Access Database contains a selected set of...

  7. Policies to clean up toxic industrial contaminated sites of Gela and Priolo: a cost-benefit analysis.

    Science.gov (United States)

    Guerriero, Carla; Bianchi, Fabrizio; Cairns, John; Cori, Liliana

    2011-07-28

    Cost-benefit analysis is a transparent tool to inform policy makers about the potential effect of regulatory interventions, nevertheless its use to evaluate clean-up interventions in polluted industrial sites is limited. The two industrial areas of Gela and Priolo in Italy were declared "at high risk of environmental crisis" in 1990. Since then little has been done to clean the polluted sites and reduce the health outcomes attributable to pollution exposure. This study, aims to quantify the monetary benefits resulting from clean-up interventions in the contaminated sites of Gela and Priolo. A damage function approach was used to estimate the number of health outcomes attributable to industrial pollution exposure. Extensive one way analyses and probabilistic analyses were conducted to investigate the sensitivity of results to different model assumptions. It has been estimated that, on average, 47 cases of premature death, 281 cases of cancer and 2,702 cases of non-cancer hospital admission could be avoided each year by removing environmental exposure in these two areas. Assuming a 20 year cessation lag and a 4% discount rate we calculate that the potential monetary benefit of removing industrial pollution is €3,592 million in Priolo and €6,639 million in Gela. Given the annual number of health outcomes attributable to pollution exposure the effective clean-up of Gela and Priolo should be prioritised. This study suggests that clean-up policies costing up to €6,639 million in Gela and €3,592 million in Priolo would be cost beneficial. These two amounts are notably higher than the funds allocated thus far to clean up the two sites, €127.4 million in Gela and €774.5 million in Priolo, implying that further economic investments - even considerable ones - could still prove cost beneficial.

  8. SITE COMPREHENSIVE LISTING (CERCLIS) (Superfund) - Non-NPL Sites

    Data.gov (United States)

    U.S. Environmental Protection Agency — Non-NPL Sites - The Comprehensive Environmental Response, Compensation and Liability Information System (CERCLIS) (Superfund) Public Access Database contains a...

  9. SITE COMPREHENSIVE LISTING (CERCLIS) - Contaminants at CERCLIS (Superfund) Sites

    Data.gov (United States)

    U.S. Environmental Protection Agency — Contaminants at Comprehensive Environmental Response, Compensation and Liability Information System (CERCLIS) (Superfund) Sites - The CERCLIS Public Access Database...

  10. SITE COMPREHENSIVE LISTING (CERCLIS) (Superfund) - Responsible Parties at CERCLIS Sites

    Data.gov (United States)

    U.S. Environmental Protection Agency — Responsible Parties at CERCLIS Sites - The Comprehensive Environmental Response, Compensation and Liability Information System (CERCLIS) (Superfund) Public Access...

  11. EPA Finalizes Plan to Address Contaminated Groundwater at Curtis Specialty Papers Superfund Site in Milford Borough and Alexandria Township, N.J.

    Science.gov (United States)

    (New York, N.Y.) The U.S. Environmental Protection Agency has finalized a plan to clean up contaminated groundwater at the Curtis Specialty Papers Superfund site in Milford Borough and Alexandria Township, New Jersey. The site includes the former Milford P

  12. TECHNICAL APPROACHES TO CHARACTERIZING AND CLEANING UP IRON AND STEEL MILL SITES UNDER THE BROWNFIELDS INITIATIVE

    Science.gov (United States)

    This document provides brownfields planners with an overview of the technical methods that can be used to achieve successful site assessment and cleanup which are two key components of the brownfields redevelopment process. No two brownfields sites are identical and planners will...

  13. High intensity magnetic separation for the clean-up of a site polluted by lead metallurgy.

    Science.gov (United States)

    Sierra, C; Martínez, J; Menéndez-Aguado, J M; Afif, E; Gallego, J R

    2013-03-15

    The industrial history in the district of Linares (Spain) has had a severe impact on soil quality. Here we examined soil contaminated by lead and other heavy metals in "La Cruz" site, a brownfield affected by metallurgical residues. Initially, the presence of contaminants mainly associated with the presence of lead slag fragments mixed with the soil was evaluated. The subsequent analysis showed a quasi-uniform distribution of the pollution irrespective of the grain-size fractions. This study was accompanied by a characterization of the lead slag behavior under the presence of a magnetic field. Two main magnetic components were detected: first a ferromagnetic and/or ferrimagnetic contribution, second a paramagnetic and/or antiferromagnetic one. It was also established that the slag was composed mainly of lead spherules and iron oxides embedded in a silicate matrix. Under these conditions, the capacity of magnetic separation to remove pollutants was examined. Therefore, two high intensity magnetic separators (dry and wet devices, respectively) were used. Dry separation proved to be successful at decontaminating soil in the first stages of a soil washing plant. In contrast, wet separation was found effective as a post-process for the finer fractions. Copyright © 2013 Elsevier B.V. All rights reserved.

  14. Spatial disparity in the distribution of superfund sites in South Carolina: an ecological study.

    Science.gov (United States)

    Burwell-Naney, Kristen; Zhang, Hongmei; Samantapudi, Ashok; Jiang, Chengsheng; Dalemarre, Laura; Rice, LaShanta; Williams, Edith; Wilson, Sacoby

    2013-11-06

    According to the US Environmental Protection Agency (EPA), Superfund is a federal government program implemented to clean up uncontrolled hazardous waste sites. Twenty-six sites in South Carolina (SC) have been included on the National Priorities List (NPL), which has serious human health and environmental implications. The purpose of this study was to assess spatial disparities in the distribution of Superfund sites in SC. The 2000 US census tract and block level data were used to generate population characteristics, which included race/ethnicity, socioeconomic status (SES), education, home ownership, and home built before 1950. Geographic Information Systems (GIS) were used to map Superfund facilities and develop choropleth maps based on the aforementioned sociodemographic variables. Spatial methods, including mean and median distance analysis, buffer analysis, and spatial approximation were employed to characterize burden disparities. Regression analysis was performed to assess the relationship between the number of Superfund facilities and population characteristics. Spatial coincidence results showed that of the 29.5% of Blacks living in SC, 55.9% live in Superfund host census tracts. Among all populations in SC living below poverty (14.2%), 57.2% were located in Superfund host census tracts. Buffer analyses results (0.5mi, 1.0mi, 5.0mi, 0.5km, 1.0km, and 5.0km) showed a higher percentage of Whites compared to Blacks hosting a Superfund facility. Conversely, a slightly higher percentage of Blacks hosted (30.2%) a Superfund facility than those not hosting (28.8%) while their White counterparts had more equivalent values (66.7% and 67.8%, respectively). Regression analyses in the reduced model (Adj. R2 = 0.038) only explained a small percentage of the variance. In addition, the mean distance for percent of Blacks in the 90th percentile for Superfund facilities was 0.48mi. Burden disparities exist in the distribution of Superfund facilities in SC at the block and

  15. Region 9 NPL Sites (Superfund Sites) Polygons

    Data.gov (United States)

    U.S. Environmental Protection Agency — NPL site POLYGON locations for the US EPA Region 9. NPL (National Priorities List) sites are hazardous waste sites that are eligible for extensive long-term cleanup...

  16. Region 9 NPL Sites (Superfund Sites 2013)

    Data.gov (United States)

    U.S. Environmental Protection Agency — NPL site POINT locations for the US EPA Region 9. NPL (National Priorities List) sites are hazardous waste sites that are eligible for extensive long-term cleanup...

  17. Region 9 NPL Sites (Superfund Sites)

    Data.gov (United States)

    U.S. Environmental Protection Agency — NPL site POINT locations for the US EPA Region 9. NPL (National Priorities List) sites are hazardous waste sites that are eligible for extensive long-term cleanup...

  18. Feasibility study for the United Heckathorn Superfund Site, Richmond, California

    Energy Technology Data Exchange (ETDEWEB)

    Lincoff, A.H. [US Environmental Protection Agency, San Francisco, CA (United States). Region IX; Costan, G.P.; Montgomery, M.S.; White, P.J. [Pacific Northwest Lab., Richland, WA (United States)

    1994-07-01

    The United Heckathom Superfund Site in Richmond, California, was used to formulate pesticides from approximately 1947 to 1966. Soils at the site and sediments in the harbor were contaminated with various chlorinated pesticides, primarily DDT, as a result of these activities. The US Environmental Protection Agency listed the site on the Superfund National Priorities List in 1990. This document is part of the Remedial Investigation and Feasibility Study phase of the Superfund response, which will provide the basis for selection of a final remedy that will protect human health and the environment and achieve compliance with federal and state envirorunental laws.

  19. EPA Encourages the Public to Provide Input on Plan to Address Contaminated Groundwater at Curtis Specialty Papers Superfund Site in Milford and Alexandria Township, New Jersey, Public Meeting to Take Place May 28

    Science.gov (United States)

    (New York, N.Y.) The U.S. Environmental Protection Agency has proposed a plan to clean up contaminated groundwater at the Curtis Specialty Papers Superfund site in Milford and Alexandria Township, New Jersey. The site includes the 86-acre historic former M

  20. Field analytical support during Superfund site remediation

    Energy Technology Data Exchange (ETDEWEB)

    Goldschmidt, W.L.; Catherman, D.R. [Environmental Resources Management, Inc., Exton, PA (United States)

    1995-12-31

    ERM-FAST{reg_sign} Services has provided cost-effective and critical field analytical support for a wide variety of investigatory and remedial projects over the past four years. Two recent projects involving soils remediation at Superfund sites exemplify the power of real time field analytical support in reducing time and expense during a project`s remedial phase. ERM-FAST on-site analytical facilities were able to meet, in a real time scenario, all data quality objectives (DQOs), all regulatory agency requirements, and satisfied the client`s needs. ERM-FAST made this possible through the development of unique analytical strategies, the proper selection of analytical technologies, and by streamlining the analytical methodologies. Both of these remedial efforts offer illustrations of the effectiveness of field analysis for vastly differing site contaminants. This case study focuses on the use of portable Gas Chromatography (GC) instrumentation as a tool for providing analytical support during a CERCLA site remediation program. The project discussed provides an example of how low cost portable analytical instrumentation can be utilized in a field setting to meet analytical DQOs consistent with CERCLA compliance and to meet the requirements for remedial activity cost control. Substantial savings were realized both by reducing total project analytical cost, and by efficient and effective process and schedule management.

  1. 78 FR 13056 - Proposed CERCLA Administrative Cost Recovery Settlement; in re: Factory H Superfund Site, Meriden...

    Science.gov (United States)

    2013-02-26

    ... AGENCY Proposed CERCLA Administrative Cost Recovery Settlement; in re: Factory H Superfund Site, Meriden...)(1) concerning the Factory H Superfund Site in Meriden, Connecticut (``Site'') with the following... refer to the Factory H Superfund Site, U.S. EPA Docket No. CERCLA-01-2012-0112. FOR FURTHER...

  2. EPA Proposes to Remove Most of Fulton, Oswego County, New York Site from Superfund List

    Science.gov (United States)

    (New York, N.Y) After cleaning up more than 10,000 cubic yards of contaminated soil and approximately 9 million gallons of contaminated groundwater, the U.S. Environmental Protection Agency is proposing to remove a portion of the Fulton Terminals Superfund

  3. 77 FR 13603 - Anniston PCB Superfund Site; Anniston, Calhoun County, AL; Correction

    Science.gov (United States)

    2012-03-07

    ... AGENCY Anniston PCB Superfund Site; Anniston, Calhoun County, AL; Correction AGENCY: Environmental... concerning the Anniston PCB Superfund Site located in Anniston. The settlement is not an amendment, but a new... name Anniston PCB by one of the following methods:...

  4. 78 FR 729 - Ellman Battery Superfund Site; Orlando, Orange County, FL; Notice of Settlement

    Science.gov (United States)

    2013-01-04

    ... From the Federal Register Online via the Government Publishing Office ENVIRONMENTAL PROTECTION AGENCY Ellman Battery Superfund Site; Orlando, Orange County, FL; Notice of Settlement AGENCY... concerning a previous Removal Action at the Ellman Battery Superfund Site located in Orlando, Orange...

  5. 75 FR 53694 - Florida Petroleum Reprocessors Superfund Site; Davie, Broward County, FL; Notice of Settlement

    Science.gov (United States)

    2010-09-01

    ...] Florida Petroleum Reprocessors Superfund Site; Davie, Broward County, FL; Notice of Settlement AGENCY... Florida Petroleum Reprocessors Superfund Site located in Davie, Broward County, Florida for publication..., identified by Docket ID No. EPA-RO4- SFUND-2010-0729 or Site name Florida Petroleum Reprocessors Superfund...

  6. 77 FR 8255 - Constitution Road Drum Superfund Site, Atlanta, Dekalb County, GA; Notice of Settlement

    Science.gov (United States)

    2012-02-14

    ... AGENCY Constitution Road Drum Superfund Site, Atlanta, Dekalb County, GA; Notice of Settlement AGENCY... entered into a settlement for past response costs concerning the Constitution Road Drum Superfund Site... available from Ms. Paula V. Painter. Submit your comments by Site name Constitution Road Drum Superfund...

  7. Rodent Control: Seal Up! Trap Up! Clean Up!

    Science.gov (United States)

    ... rodent food sources and nesting sites... Diseases from rodents Diseases directly transmitted by rodents Diseases indirectly transmitted by rodents Cleaning up after rodents Take precautions before and during clean up of ...

  8. Cleanups In My Community (CIMC) - Superfund National Priority List (NPL) Sites, National Layer

    Data.gov (United States)

    U.S. Environmental Protection Agency — This data layer provides access to Superfund National Priority List Sites as part of the CIMC web service. Superfund is a program administered by the EPA to locate,...

  9. SUPERFUND CLEANUPS AND INFANT HEALTH

    Science.gov (United States)

    Currie, Janet; Greenstone, Michael; Moretti, Enrico

    2013-01-01

    We are the first to examine the effect of Superfund cleanups on infant health rather than focusing on proximity to a site. We study singleton births to mothers residing within 5km of a Superfund site between 1989–2003 in five large states. Our “difference in differences” approach compares birth outcomes before and after a site clean-up for mothers who live within 2,000 meters of the site and those who live between 2,000– 5,000 meters of a site. We find that proximity to a Superfund site before cleanup is associated with a 20 to 25% increase in the risk of congenital anomalies. PMID:25152535

  10. Remediation System Evaluation, Havertown PCP Superfund Site

    Science.gov (United States)

    The Havertown PCP site is located in Havertown, Haverford Township, Delaware County, in southeastern Pennsylvania. The site contamination was first discovered in 1962 when the Pennsylvania State Department of Health became aware of contaminants in ...

  11. 77 FR 11533 - Anniston PCB Superfund Site, Anniston, Calhoun County, Alabama; Notice of Amended Settlement

    Science.gov (United States)

    2012-02-27

    ... AGENCY Anniston PCB Superfund Site, Anniston, Calhoun County, Alabama; Notice of Amended Settlement... Agency has entered into a settlement for past response costs concerning the Anniston PCB Superfund Site... available from Ms. Paula V. Painter. Submit your comments by Site name Anniston PCB by one of the...

  12. 75 FR 81269 - Ward Transformer Superfund Site Raleigh, Wake County, NC; Notice of Settlements

    Science.gov (United States)

    2010-12-27

    ... AGENCY Ward Transformer Superfund Site Raleigh, Wake County, NC; Notice of Settlements AGENCY... Ward Transformer Superfund Site located in Raleigh, Wake County, North Carolina for publication. DATES... your comments, identified by Docket ID No. EPA-RO4- SFUND-2010-1053 or Site name Ward...

  13. 78 FR 14543 - Ward Transformer Superfund Site; Raleigh, Wake County, NC; Notice of Settlement

    Science.gov (United States)

    2013-03-06

    ... AGENCY Ward Transformer Superfund Site; Raleigh, Wake County, NC; Notice of Settlement AGENCY... Agency has entered into a settlement at the Ward Transformer Superfund Site located in Raleigh, Wake... EPA Region 4 contact Ms. Paula V. Painter. Submit your comments by Site name Ward...

  14. Deriving site-specific soil clean-up values for metals and metalloids: rationale for including protection of soil microbial processes.

    Science.gov (United States)

    Kuperman, Roman G; Siciliano, Steven D; Römbke, Jörg; Oorts, Koen

    2014-07-01

    Although it is widely recognized that microorganisms are essential for sustaining soil fertility, structure, nutrient cycling, groundwater purification, and other soil functions, soil microbial toxicity data were excluded from the derivation of Ecological Soil Screening Levels (Eco-SSL) in the United States. Among the reasons for such exclusion were claims that microbial toxicity tests were too difficult to interpret because of the high variability of microbial responses, uncertainty regarding the relevance of the various endpoints, and functional redundancy. Since the release of the first draft of the Eco-SSL Guidance document by the US Environmental Protection Agency in 2003, soil microbial toxicity testing and its use in ecological risk assessments have substantially improved. A wide range of standardized and nonstandardized methods became available for testing chemical toxicity to microbial functions in soil. Regulatory frameworks in the European Union and Australia have successfully incorporated microbial toxicity data into the derivation of soil threshold concentrations for ecological risk assessments. This article provides the 3-part rationale for including soil microbial processes in the development of soil clean-up values (SCVs): 1) presenting a brief overview of relevant test methods for assessing microbial functions in soil, 2) examining data sets for Cu, Ni, Zn, and Mo that incorporated soil microbial toxicity data into regulatory frameworks, and 3) offering recommendations on how to integrate the best available science into the method development for deriving site-specific SCVs that account for bioavailability of metals and metalloids in soil. Although the primary focus of this article is on the development of the approach for deriving SCVs for metals and metalloids in the United States, the recommendations provided in this article may also be applicable in other jurisdictions that aim at developing ecological soil threshold values for protection of

  15. Remediation System Evaluation, McCormick and Baxter Superfund SiteRemediation System Evaluation, McCormick and Baxter Superfund Site

    Science.gov (United States)

    The McCormick and Baxter Creosoting Company, Portland Plant, Superfund Site is located adjacent tothe Willamette River in Portland, Oregon and addresses contamination of soil, groundwater, and riversediments stemming from creosoting operations...

  16. Pollute first, clean up later?

    NARCIS (Netherlands)

    Azadi, Hossein; Verheijke, Gijs; Witlox, Frank

    2011-01-01

    There is a growing concern with regard to sustainability in emerging economies like China. The Chinese growth is characterized by a strategy which is known as "pollute first, clean up later". Here we show that based on this strategy, the pollution alarm can often be postponed by a tremendous economi

  17. Radioactive Waste and Clean-up: Introduction

    Energy Technology Data Exchange (ETDEWEB)

    Collard, G

    2000-07-01

    SCK-CEN's Radioactive Waste and Clean-up Division performs studies and develops strategies, techniques and technologies in the area of radioactive waste management, the decontamination and decommissioning of nuclear installations and the remediation of radioactive-contaminated sites. These activities are performed in the context of our responsibility towards the safety of present and future generations and contribute to achieve intrageneration equity.

  18. Remediation System Evaluation, Streamlined Remediation System Evaluation (RSE-Lite), Circuitron Corporation Superfund Site

    Science.gov (United States)

    The Circuitron Corporation Superfund Site is located at 82 Milbar Boulevard, East Farmingdale, Suffolk County, New York. The site is situated on a 1-acre lot in an industrial/commercial area that is surrounded by similar small manufacturers...

  19. Remediation of the Wells G & H Superfund Site, Woburn, Massachusetts.

    Science.gov (United States)

    Bair, E Scott; Metheny, Maura A

    2002-01-01

    Remediation of ground water and soil contamination at the Wells G & H Superfund Site, Woburn, Massachusetts, uses technologies that reflect differences in hydrogeologic settings, concentrations of volatile organic compounds (VOCs), and costs of treatment. The poorly permeable glacial materials that overlie fractured bedrock at the W.R. Grace property necessitate use of closely spaced recovery wells. Contaminated ground water is treated with hydrogen peroxide and ultraviolet (UV) oxidation. At UniFirst, a deep well completed in fractured bedrock removes contaminated ground water, which is treated by hydrogen peroxide, UV oxidation, and granular activated carbon (GAC). The remediation system at Wildwood integrates air sparging, soil-vapor extraction, and ground water pumping. Air stripping and GAC are used to treat contaminated water; GAC is used to treat contaminated air. New England Plastics (NEP) uses air sparging and soil-vapor extraction to remove VOCs from the unsaturated zone and shallow ground water. Contaminated air and water are treated using separate GAC systems. After nine years of operation at W.R. Grace and UniFirst, 30 and 786 kg, respectively, of VOCs have been removed. In three years of operation, 866 kg of VOCs have been removed at Wildwood. In 15 months of operation, 36 kg of VOCs were removed at NEP. Characterization work continues at the Olympia Nominee Trust, Whitney Barrel, Murphy Waste Oil, and Aberjona Auto Parts properties. Risk assessments are being finalized that address heavy metals in the floodplain sediments along the Aberjona River that are mobilized from the Industri-Plex Superfund Site located a few miles upstream.

  20. Superfund and Toxic Release Inventory Sites - MDC_ContaminatedSite

    Data.gov (United States)

    NSGIC GIS Inventory (aka Ramona) — A point feature class of open DERM Contaminated sites - see phase code for status of site. Contaminated sites identifies properties where environmental contamination...

  1. Region 9 NPL Sites (Superfund Sites 2013) Polygons

    Data.gov (United States)

    U.S. Environmental Protection Agency — NPL site POLYGON locations for the US EPA Region 9. NPL (National Priorities List) sites are hazardous waste sites that are eligible for extensive long-term cleanup...

  2. Superfund and Toxic Release Inventory Sites - MDC_ContaminatedSite

    Data.gov (United States)

    NSGIC Local Govt | GIS Inventory — A point feature class of open DERM Contaminated sites - see phase code for status of site. Contaminated sites identifies properties where environmental contamination...

  3. Cleanups In My Community (CIMC) - Federal facilities that are also Superfund sites, National Layer

    Data.gov (United States)

    U.S. Environmental Protection Agency — Federal facilities are properties owned by the federal government. This data layer provides access to Federal facilities that are Superfund sites as part of the CIMC...

  4. Preliminary estimate of natural resource damage : Rocky Mountain Arsenal Superfund Site

    Data.gov (United States)

    US Fish and Wildlife Service, Department of the Interior — This is a preliminary estimate of natural resource damages associated with uncontrolled release of hazardous materials at the Rocky Mountain Arsenal Superfund Site...

  5. Cleanups In My Community (CIMC) - Base Realignment and Closure (BRAC) Superfund Sites, National Layer

    Data.gov (United States)

    U.S. Environmental Protection Agency — This data layer provides access to Base Realignment and Closure (BRAC) Superfund Sites as part of the CIMC web service. EPA works with DoD to facilitate the reuse...

  6. EPA, 12 Private Entities Agree to Remove Contamination and Conduct Study at Metro Container Superfund Site

    Science.gov (United States)

    PHILADELPHIA (October 21, 2015) -- The U.S. Environmental Protection Agency and 12 private entities have agreed to settle on actions that will lead to increased environmental protection at the Metro Container Superfund Site in Trainer, Delaware Co.,

  7. Report: Remedial Project Manager Turnover at Superfund Sites

    Science.gov (United States)

    Report #2001-M-000015, June 15, 2001. We determined that EPA Region III did not have formal procedures in place to mitigate continuity problems caused by turnover of EPA personnel in the Superfund program.

  8. Air-water exchange of PAHs and OPAHs at a superfund mega-site.

    Science.gov (United States)

    Tidwell, Lane G; Blair Paulik, L; Anderson, Kim A

    2017-12-15

    Chemical fate is a concern at environmentally contaminated sites, but characterizing that fate can be difficult. Identifying and quantifying the movement of chemicals at the air-water interface are important steps in characterizing chemical fate. Superfund sites are often suspected sources of air pollution due to legacy sediment and water contamination. A quantitative assessment of polycyclic aromatic hydrocarbons (PAHs) and oxygenated PAH (OPAHs) diffusive flux in a river system that contains a Superfund Mega-site, and passes through residential, urban and agricultural land, has not been reported before. Here, passive sampling devices (PSDs) were used to measure 60 polycyclic aromatic hydrocarbons (PAHs) and 22 oxygenated PAH (OPAHs) in air and water. From these concentrations the magnitude and direction of contaminant flux between these two compartments was calculated. The magnitude of PAH flux was greater at sites near or within the Superfund Mega-site than outside of the Superfund Mega-site. The largest net individual PAH deposition at a single site was naphthalene at a rate of -14,200 (±5780) (ng/m(2))/day. The estimated one-year total flux of phenanthrene was -7.9×10(5) (ng/m(2))/year. Human health risk associated with inhalation of vapor phase PAHs and dermal exposure to PAHs in water were assessed by calculating benzo[a]pyrene equivalent concentrations. Excess lifetime cancer risk estimates show potential increased risk associated with exposure to PAHs at sites within and in close proximity to the Superfund Mega-site. Specifically, estimated excess lifetime cancer risk associated with dermal exposure and inhalation of PAHs was above 1 in 1 million within the Superfund Mega-site. The predominant depositional flux profile observed in this study suggests that the river water in this Superfund site is largely a sink for airborne PAHs, rather than a source. Copyright © 2017 Elsevier B.V. All rights reserved.

  9. 48 CFR 36.512 - Cleaning up.

    Science.gov (United States)

    2010-10-01

    ... 48 Federal Acquisition Regulations System 1 2010-10-01 2010-10-01 false Cleaning up. 36.512... CONTRACTING CONSTRUCTION AND ARCHITECT-ENGINEER CONTRACTS Contract Clauses 36.512 Cleaning up. The contracting officer shall insert the clause at 52.236-12, Cleaning Up, in solicitations and contracts when a...

  10. Superfund and Toxic Release Inventory Sites - SUPERFUND_IDEM_IN: Superfund Program Facilities in Indiana (Indiana Department of Environmental Management, Point Shapefile)

    Data.gov (United States)

    NSGIC GIS Inventory (aka Ramona) — SUPERFUND_IDEM_IN is a point shapefile that contains GPS-located Superfund Program facility locations in Indiana, provided by personnel of Indiana Department of...

  11. 76 FR 24479 - In the Matter of the Taylor Lumber and Treating Superfund Site, Sheridan, Oregon, Amendment to...

    Science.gov (United States)

    2011-05-02

    ... AGENCY In the Matter of the Taylor Lumber and Treating Superfund Site, Sheridan, Oregon, Amendment to... with PWPO provided a covenant not to sue for response costs at the Taylor Lumber and Treating Site... should reference the Taylor Lumber and Treating Superfund Site in Sheridan, Oregon, EPA Docket No....

  12. 78 FR 47317 - Ore Knob Mine Superfund Site; Laurel Springs, Ashe County, North Carolina; Notice of Settlement

    Science.gov (United States)

    2013-08-05

    ... AGENCY Ore Knob Mine Superfund Site; Laurel Springs, Ashe County, North Carolina; Notice of Settlement... Protection Agency has entered into a settlement with Herbert N. Francis concerning the Ore Knob Mine... comments by site name ``Ore Knob Mine Superfund Site'' by one of the following methods:...

  13. 75 FR 68788 - Ore Knob Mine Superfund Site; Jefferson, Ashe County, North Carolina; Notice of Settlement

    Science.gov (United States)

    2010-11-09

    ... Doc No: 2010-28260] ENVIRONMENTAL PROTECTION AGENCY [Docket EPA-RO4-SFUND-2010-0893, FRL-9223-8] Ore... Protection Agency has entered into a settlement for reimbursement of past response costs concerning the Ore..., identified by Docket ID No. EPA-RO4- SFUND-2010-0893 or Site name Ore Knob Mine Superfund Site by one of...

  14. 77 FR 16548 - Florida Petroleum Reprocessors Superfund Site; Davie, Broward County, FL; Notice of Settlements

    Science.gov (United States)

    2012-03-21

    ...] Florida Petroleum Reprocessors Superfund Site; Davie, Broward County, FL; Notice of Settlements AGENCY... entered into four (4) settlements for past response costs concerning the Florida Petroleum Reprocessors... settlement are available from Ms. Paula V. Painter. Submit your comments by Site name Florida Petroleum...

  15. 77 FR 2981 - Constitution Road Drum Superfund Site; Atlanta, Dekalb County, GA; Notice of Settlement

    Science.gov (United States)

    2012-01-20

    ... AGENCY Constitution Road Drum Superfund Site; Atlanta, Dekalb County, GA; Notice of Settlement AGENCY... Protection Agency has entered into a settlement for past response costs concerning the Constitution Road Drum... settlement are available from Ms. Paula V. Painter. Submit your comments by Site name Constitution Road...

  16. Medical costs and lost productivity from health conditions at volatile organic compound-contaminated Superfund sites

    Energy Technology Data Exchange (ETDEWEB)

    Lybarger, J.A.; Spengler, R.F.; Brown, D.R. [Agency for Toxic Substances and Disease Registry, Atlanta, GA (United States). Div. of Health Studies; Lee, R.; Vogt, D.P. [Oak Ridge National Lab., TN (United States)]|[Joint Inst. for Energy and Environment, Oak Ridge, TN (United States); Perhac, R.M. Jr. [Univ. of Tennessee, Knoxville, TN (United States)]|[Joint Inst. for Energy and Environment, Oak Ridge, TN (United States)

    1998-10-01

    This paper estimates the health costs at Superfund sites for conditions associated with volatile organic compounds (VOCs) in drinking water. Health conditions were identified from published literature and registry information as occurring at excess rates in VOC-exposed populations. These health conditions were: (1) some categories of birth defects, (2) urinary tract disorders, (3) diabetes, (4) eczema and skin conditions, (5) anemia, (6) speech and hearing impairments in children under 10 years of age, and (7) stroke. Excess rates were used to estimate the excess number of cases occurring among the total population living within one-half mile of 258 Superfund sites. These sites had evidence of completed human exposure pathways for VOCs in drinking water. For each type of medical condition, an individual`s expected medical costs, long-term care costs, and lost work time due to illness or premature mortality were estimated. Costs were calculated to be approximately $330 million per year, in the absence of any remediation or public health intervention programs. The results indicate the general magnitude of the economic burden associated with a limited number of contaminants at a portion of all Superfund sites, thus suggesting that the burden would be greater than that estimated in this study if all contaminants at all Superfund sites could be taken into account.

  17. A General Chemistry Assignment Analyzing Environmental Contamination for the Depue, IL, National Superfund Site

    Science.gov (United States)

    Saslow Gomez, Sarah A.; Faurie-Wisniewski, Danielle; Parsa, Arlen; Spitz, Jeff; Spitz, Jennifer Amdur; Loeb, Nancy C.; Geiger, Franz M.

    2015-01-01

    The classroom exercise outlined here is a self-directed assignment that connects students to the environmental contamination problem surrounding the DePue Superfund site. By connecting chemistry knowledge gained in the classroom with a real-world problem, students are encouraged to personally connect with the problem while simultaneously…

  18. A General Chemistry Assignment Analyzing Environmental Contamination for the Depue, IL, National Superfund Site

    Science.gov (United States)

    Saslow Gomez, Sarah A.; Faurie-Wisniewski, Danielle; Parsa, Arlen; Spitz, Jeff; Spitz, Jennifer Amdur; Loeb, Nancy C.; Geiger, Franz M.

    2015-01-01

    The classroom exercise outlined here is a self-directed assignment that connects students to the environmental contamination problem surrounding the DePue Superfund site. By connecting chemistry knowledge gained in the classroom with a real-world problem, students are encouraged to personally connect with the problem while simultaneously…

  19. Biomonitoring for metal contamination near two Superfund sites in Woburn, Massachusetts, using phytochelatins

    Energy Technology Data Exchange (ETDEWEB)

    Gawel, James E.; Hemond, Harold F

    2004-09-01

    Characterizing the spatial extent of groundwater metal contamination traditionally requires installing sampling wells, an expensive and time-consuming process in urban areas. Moreover, extrapolating biotic effects from metal concentrations alone is problematic, making ecological risk assessment difficult. Our study is the first to examine the use of phytochelatin measurements in tree leaves for delimiting biological metal stress in shallow, metal-contaminated groundwater systems. Three tree species (Rhamnus frangula, Acer platanoides, and Betula populifolia) growing above the shallow groundwater aquifer of the Aberjona River watershed in Woburn, Massachusetts, display a pattern of phytochelatin production consistent with known sources of metal contamination and groundwater flow direction near the Industri-Plex Superfund site. Results also suggest the existence of a second area of contaminated groundwater and elevated metal stress near the Wells G and H Superfund site downstream, in agreement with a recent EPA ecological risk assessment. Possible contamination pathways at this site are discussed.

  20. Report: Independent Ground Water Sampling Generally Confirms EPA’s Data at Wheeler Pit Superfund Site in Wisconsin

    Science.gov (United States)

    Report #10-P-0218, September 8, 2010. With minimal exceptions, our independent sampling results at the Wheeler Pit Superfund Site were consistent with the sampling results that EPA Region 5 has obtained historically.

  1. Issuance of Final Guidance: Ecological Risk Assessment and Risk Management Principles for Superfund Sites, October 7, 1999

    Science.gov (United States)

    This guidance is intended to help Superfund risk managers make ecological risk management decisions that are based on sound science, consistent across Regions, and present a characterization of site risks that is transparent to the public.

  2. Deriving site-specific clean-up criteria to protect ecological receptors (plants and soil invertebrates) exposed to metal or metalloid soil contaminants via the direct contact exposure pathway

    Science.gov (United States)

    Checkai, Ron; Van Genderen, Eric; Sousa, José Paulo; Stephenson, Gladys; Smolders, Erik

    2014-01-01

    Soil contaminant concentration limits for the protection of terrestrial plants and soil invertebrates are commonly based on thresholds derived using data from laboratory ecotoxicity tests. A comprehensive assessment has been made for the derivation of ecological soil screening levels (Eco-SSL) in the United States; however, these limits are conservative because of their focus on high bioavailability scenarios. Here, we explain and evaluate approaches to soil limit derivation taken by 4 jurisdictions, 2 of which allow for correction of data for factors affecting bioavailability among soils, and between spiked and field-contaminated soils (Registration Evaluation Authorisation and Restriction of Chemicals [REACH] Regulation, European Union [EU], and the National Environment Protection Council [NEPC], Australia). Scientifically advanced features from these methods have been integrated into a newly developed method for deriving soil clean-up values (SCVs) within the context of site-specific baseline ecological risk assessment. Resulting site-specific SCVs that account for bioavailability may permit a greater residual concentration in soil when compared to generic screening limit concentrations (e.g., Eco-SSL), while still affording acceptable protection. Two choices for selecting the level of protection are compared (i.e., allowing higher effect levels per species, or allowing a higher percentile of species that are potentially unprotected). Implementation of this new method is presented for the jurisdiction of the United States, with a focus on metal and metalloid contaminants; however, the new method can be used in any jurisdiction. A case study for molybdate shows the large effect of bioavailability corrections and smaller effects of protection level choices when deriving SCVs. Integr Environ Assess Manag 2014;10:346–357. PMID:24470189

  3. Electrochemical peroxidation of PCBs and VOCs in superfund site water and sediments

    Energy Technology Data Exchange (ETDEWEB)

    Scrudato, R.J.; Chiarenzelli, J.R. [SUNY, Oswego, NY (United States)

    1996-12-31

    An electrochemical peroxidation (ECP) process has been developed and used to degrade polychlorinated biphenyls (PCB) and volatile organic compounds (VOC)-contaminated water, sludge, and sediments at a New York State Federal and State Superfund Site. The process involves passing an oscillating low-amperage (<10 amps) current through steel electrodes immersed in an acidified water or sediment slurry into which hydrogen peroxide (<1,000 ppm) is added. The generated free radicals attack organic compounds, including organo-metallic complexes and refractory compounds including PCBs. PCB degradation ranged from about 30% to 80% in experiments involving Federal Superfund Site sediments; total PCBs were reduced by {approximately}97% to 68%, respectively, in water and slurry collected from a State Superfund subsurface storage tank. VOC bench-scale experiments involved chloroethane, 1,1-dichloroethane, dichloromethane, 1,1,1-trichloroethane, and acetone and after a 3-min ECP treatment, degradation ranged from >94% to about 99.9%. Results indicate the ECP is a viable process to degrade organic contaminants in water and sediment suspensions. Because the treated water suspensions are acidified, select trace metal sorbed to the particulates is solubilized and therefore can be segregated from the particulates, offering a process that simultaneously degrades organic contaminants and separates trace metals. 19 refs., 1 fig., 4 tabs.

  4. Aquatic assessment of the Ely Copper Mine Superfund site, Vershire, Vermont

    Science.gov (United States)

    Seal, Robert R.; Kiah, Richard G.; Piatak, Nadine M.; Besser, John M.; Coles, James F.; Hammarstrom, Jane M.; Argue, Denise M.; Levitan, Denise M.; Deacon, Jeffrey R.; Ingersoll, Christopher G.

    2010-01-01

    The Ely Mine, which operated from 1821 to 1905, and its area of downstream impact constitute the Ely Copper Mine Superfund site. The site was placed on the National Priorities List in 2001. The mine comprises underground workings, foundations from historical structures, several waste-rock piles, roast beds associated with the smelting operation, and slag piles resulting from the smelting. The mine site is drained by Ely Brook, which includes several tributaries, one of which drains a series of six ponds. Ely Brook empties into Schoolhouse Brook, which flows 3.3 kilometers and joins the Ompompanoosuc River.

  5. Geophysical logging at the Cristex Drum National Priorities List Superfund Site near Oxford, North Carolina

    Science.gov (United States)

    Antolino, Dominick J.

    2017-01-01

    The collection of borehole geophysical logs data was conducted by the U.S. Geological Survey South Atlantic Water Science Center in the vicinity of the Cristex Drum National Priorities List Superfund Site near Oxford, North Carolina, during January through March 2016. In an effort to assist the U.S. Environmental Protection Agency in the development of a conceptual groundwater model for the assessment of current contaminant distribution and future migration of contaminants, borehole geophysical log and image data collection, which included the delineation of more than 150 subsurface features (primarily fracture orientations) in 3 open borehole wells.

  6. Contaminated sites from the past: experience of the US Environmental Protection Agency.

    Science.gov (United States)

    Boyd, M A

    2016-06-01

    The purpose of this paper is to provide an overview of the experience of the US Environmental Protection Agency (EPA) in cleaning up radioactively contaminated sites. In the USA, EPA regulates the radiological clean-up of uranium mill tailings sites, some Department of Energy legacy sites within the US nuclear weapons complex, and Superfund National Priorities List sites. The approach to site remediation decisions, including the determination of clean-up levels, varies according to the enabling legislation granting EPA these authorities. Past practices that gave rise to many of the existing exposure situations at legacy sites were permissible before the advent of environmental clean-up legislation. The Uranium Mill Tailings Radiation Control Act of 1978 authorised EPA to set applicable radioactivity concentration standards for soil clean-up at inactive uranium mill sites and vicinity properties. For the other categories of sites mentioned above, remediation goals are typically based on not exceeding a target excess cancer risk range established under the Comprehensive Environmental Response, Compensation, and Liability Act (also known as 'Superfund'). EPA's regulations for cleaning up various contaminated sites in existing exposure situations often result in residual doses that are typical of optimised doses in planned exposure situations. Although the clean-up levels selected may differ from those adopted in other countries, recommendations from the International Commission on Radiological Protection are reflected in the exposure assessment methodologies used in their establishment.

  7. Surface geophysics and porewater evaluation at the Lower Darby Creek Area Superfund Site, Philadelphia, Pennsylvania, 2013

    Science.gov (United States)

    Walker, Charles W.; Degnan, James R.; Brayton, Michael J.; Cruz, Roberto M.; Lorah, Michelle M.

    2015-01-01

    In cooperation with the U.S. Environmental Protection Agency (EPA), Region 3, the U.S. Geological Survey (USGS) is participating in an ongoing study to aid in the identification of subsurface heterogeneities that may act as preferential pathways for contaminant transport in and around the Lower Darby Creek Area (LDCA) Superfund Site, Philadelphia Pa. Lower Darby Creek, which flows into the Delaware River, borders the western part of the former landfill site. In 2013, the USGS conducted surface geophysics measurements and stream porewater sampling to provide additional data for EPA’s site characterization. This report contains data collected from field measurements of direct current (DC) resistivity, frequency-domain electromagnetic (FDEM) surveys, and stream porewater specific conductance (SC).

  8. Continued geophysical logging near the GMH Electronics National Priorities List Superfund site near Roxboro, North Carolina

    Science.gov (United States)

    Antolino, Dominick J.; Chapman, Melinda J.

    2017-01-06

    The U.S. Geological Survey South Atlantic Water Science Center collected borehole geophysical logs and images and continuous water-level data near the GMH Electronics National Priorities List Superfund site near Roxboro, North Carolina, during December 2012 through July 2015. Previous work by the U.S. Geological Survey South Atlantic Water Science Center at the site involved the collection of borehole geophysical log data in 15 wells, in addition to surface geologic mapping and passive diffusion bag sampling. In a continued effort to assist the U.S. Environmental Protection Agency in developing a conceptual groundwater model to assess current contaminant distribution and future migration of contaminants, more than 900 subsurface features (primarily fracture orientations) in 10 open borehole wells were delineated and continuous water-level data information from 14 monitoring wells within close proximity of the initially drilled boreholes was collected to observe any induced water-level fluctuations during drilling operations

  9. 48 CFR 52.236-12 - Cleaning Up.

    Science.gov (United States)

    2010-10-01

    ... 48 Federal Acquisition Regulations System 2 2010-10-01 2010-10-01 false Cleaning Up. 52.236-12 Section 52.236-12 Federal Acquisition Regulations System FEDERAL ACQUISITION REGULATION (CONTINUED... Cleaning Up. As prescribed in 36.512, insert the following clause: Cleaning Up (APR 1984) The...

  10. ASSESSMENT OF VAPOR INTRUSION IN HOMES NEAR THE RAYMARK SUPERFUND SITE USING BASEMENT AND SUB-SLAB AIR SAMPLES

    Science.gov (United States)

    This report describes the results of an investigation conducted to assist EPA’s New England Regional Office in evaluating vapor intrusion at 15 homes and one commercial building near the Raymark Superfund Site in Stratford, Connecticut. Methods were developed to sample sub-slab ...

  11. Mining-related sediment and soil contamination in a large Superfund site: Characterization, habitat implications, and remediation

    Science.gov (United States)

    Juracek, Kyle E.; Drake, K. D.

    2016-01-01

    Historical mining activity (1850–1970) in the now inactive Tri-State Mining District provided an ongoing source of lead and zinc to the environment including the US Environmental Protection Agency Superfund site located in Cherokee County, southeast Kansas, USA. The resultant contamination adversely affected biota and caused human health problems and risks. Remediation in the Superfund site requires an understanding of the magnitude and extent of contamination. To provide some of the required information, a series of sediment and soil investigations were conducted in and near the Superfund site to characterize lead and zinc contamination in the aquatic and floodplain environments along the main-stem Spring River and its major tributaries. In the Superfund site, the most pronounced lead and zinc contamination, with concentrations that far exceed sediment quality guidelines associated with potential adverse biological effects, was measured for streambed sediments and floodplain soils located within or downstream from the most intensive mining-affected areas. Tributary streambeds and floodplains in affected areas are heavily contaminated with some sites having lead and zinc concentrations that are an order of magnitude (or more) greater than the sediment quality guidelines. For the main-stem Spring River, the streambed is contaminated but the floodplain is mostly uncontaminated. Measured lead and zinc concentrations in streambed sediments, lakebed sediments, and floodplain soils documented a persistence of the post-mining contamination on a decadal timescale. These results provide a basis for the prioritization, development, and implementation of plans to remediate contamination in the affected aquatic and floodplain environments within the Superfund site.

  12. Mining-Related Sediment and Soil Contamination in a Large Superfund Site: Characterization, Habitat Implications, and Remediation.

    Science.gov (United States)

    Juracek, K E; Drake, K D

    2016-10-01

    Historical mining activity (1850-1970) in the now inactive Tri-State Mining District provided an ongoing source of lead and zinc to the environment including the US Environmental Protection Agency Superfund site located in Cherokee County, southeast Kansas, USA. The resultant contamination adversely affected biota and caused human health problems and risks. Remediation in the Superfund site requires an understanding of the magnitude and extent of contamination. To provide some of the required information, a series of sediment and soil investigations were conducted in and near the Superfund site to characterize lead and zinc contamination in the aquatic and floodplain environments along the main-stem Spring River and its major tributaries. In the Superfund site, the most pronounced lead and zinc contamination, with concentrations that far exceed sediment quality guidelines associated with potential adverse biological effects, was measured for streambed sediments and floodplain soils located within or downstream from the most intensive mining-affected areas. Tributary streambeds and floodplains in affected areas are heavily contaminated with some sites having lead and zinc concentrations that are an order of magnitude (or more) greater than the sediment quality guidelines. For the main-stem Spring River, the streambed is contaminated but the floodplain is mostly uncontaminated. Measured lead and zinc concentrations in streambed sediments, lakebed sediments, and floodplain soils documented a persistence of the post-mining contamination on a decadal timescale. These results provide a basis for the prioritization, development, and implementation of plans to remediate contamination in the affected aquatic and floodplain environments within the Superfund site.

  13. Mining-Related Sediment and Soil Contamination in a Large Superfund Site: Characterization, Habitat Implications, and Remediation

    Science.gov (United States)

    Juracek, K. E.; Drake, K. D.

    2016-10-01

    Historical mining activity (1850-1970) in the now inactive Tri-State Mining District provided an ongoing source of lead and zinc to the environment including the US Environmental Protection Agency Superfund site located in Cherokee County, southeast Kansas, USA. The resultant contamination adversely affected biota and caused human health problems and risks. Remediation in the Superfund site requires an understanding of the magnitude and extent of contamination. To provide some of the required information, a series of sediment and soil investigations were conducted in and near the Superfund site to characterize lead and zinc contamination in the aquatic and floodplain environments along the main-stem Spring River and its major tributaries. In the Superfund site, the most pronounced lead and zinc contamination, with concentrations that far exceed sediment quality guidelines associated with potential adverse biological effects, was measured for streambed sediments and floodplain soils located within or downstream from the most intensive mining-affected areas. Tributary streambeds and floodplains in affected areas are heavily contaminated with some sites having lead and zinc concentrations that are an order of magnitude (or more) greater than the sediment quality guidelines. For the main-stem Spring River, the streambed is contaminated but the floodplain is mostly uncontaminated. Measured lead and zinc concentrations in streambed sediments, lakebed sediments, and floodplain soils documented a persistence of the post-mining contamination on a decadal timescale. These results provide a basis for the prioritization, development, and implementation of plans to remediate contamination in the affected aquatic and floodplain environments within the Superfund site.

  14. Raman spectroscopy of efflorescent sulfate salts from Iron Mountain Mine Superfund Site, California.

    Science.gov (United States)

    Sobron, Pablo; Alpers, Charles N

    2013-03-01

    The Iron Mountain Mine Superfund Site near Redding, California, is a massive sulfide ore deposit that was mined for iron, silver, gold, copper, zinc, and pyrite intermittently for nearly 100 years. As a result, both water and air reached the sulfide deposits deep within the mountain, producing acid mine drainage consisting of sulfuric acid and heavy metals from the ore. Particularly, the drainage water from the Richmond Mine at Iron Mountain is among the most acidic waters naturally found on Earth. The mineralogy at Iron Mountain can serve as a proxy for understanding sulfate formation on Mars. Selected sulfate efflorescent salts from Iron Mountain, formed from extremely acidic waters via drainage from sulfide mining, have been characterized by means of Raman spectroscopy. Gypsum, ferricopiapite, copiapite, melanterite, coquimbite, and voltaite are found within the samples. This work has implications for Mars mineralogical and geochemical investigations as well as for terrestrial environmental investigations related to acid mine drainage contamination.

  15. Raman spectroscopy of efflorescent sulfate salts from Iron Mountain Mine Superfund Site, California

    Science.gov (United States)

    Sobron, Pablo; Alpers, Charles N.

    2013-01-01

    The Iron Mountain Mine Superfund Site near Redding, California, is a massive sulfide ore deposit that was mined for iron, silver, gold, copper, zinc, and pyrite intermittently for nearly 100 years. As a result, both water and air reached the sulfide deposits deep within the mountain, producing acid mine drainage consisting of sulfuric acid and heavy metals from the ore. Particularly, the drainage water from the Richmond Mine at Iron Mountain is among the most acidic waters naturally found on Earth. The mineralogy at Iron Mountain can serve as a proxy for understanding sulfate formation on Mars. Selected sulfate efflorescent salts from Iron Mountain, formed from extremely acidic waters via drainage from sulfide mining, have been characterized by means of Raman spectroscopy. Gypsum, ferricopiapite, copiapite, melanterite, coquimbite, and voltaite are found within the samples. This work has implications for Mars mineralogical and geochemical investigations as well as for terrestrial environmental investigations related to acid mine drainage contamination.

  16. Fishing a superfund site: Dissonance and risk perception of environmental hazards by fishermen in Puerto Rico

    Energy Technology Data Exchange (ETDEWEB)

    Burger, J.; Gochfeld, M. (Rutgers University, Piscataway, NJ (USA))

    1991-06-01

    Risk perception studies show that individuals tend to underestimate significant risks, overestimate negligible ones, and distrust authorities. They also rely on a variety of strategies or heuristics to reach decisions regarding their risk-taking behavior. The authors report on a survey of fishermen and crabbers engaged in recreational and substance fishing in a Puerto Rican estuary (near Humacao), which has been declared a Superfund site because of suspected contamination by mercury, and at ecologically similar control sites. Nearly everyone interviewed at the Humacao site was aware of the mercury contamination, but either denied its importance, believed the contamination was restricted to a distant part of the estuary, or assumed that the estuary would be closed by the authorities if the threat was real. All site-users consumed the fish and crabs they caught. At Humacao, the average catch was 7 fish per fishermen (mostly tilapia, Tilapia mossambica, and tarpon, Megalops atlantica) and 13 crabs per crabber (all blue crabs, Callinectes sapidus). On average, the site-users returned to the lagoons about 3-4 times per month. At control sites, fewer fish were eaten. The worst case consumption of tarpon, a species which concentrated mercury at Eastern Puerto Rico, provided an exposure exceeding the EPA reference dose, whereas consumption of one tarpon per week did not entail excess exposure. Fortunately, few individuals caught tarpon exclusively. Unlike counterparts in the northeastern United States, they trusted authorities and indicated that they would have heeded warnings of mercury contamination posted where they fished.

  17. Cockroaches probably cleaned up after dinosaurs.

    Science.gov (United States)

    Vršanský, Peter; van de Kamp, Thomas; Azar, Dany; Prokin, Alexander; Vidlička, L'ubomír; Vagovič, Patrik

    2013-01-01

    Dinosaurs undoubtedly produced huge quantities of excrements. But who cleaned up after them? Dung beetles and flies with rapid development were rare during most of the Mesozoic. Candidates for these duties are extinct cockroaches (Blattulidae), whose temporal range is associated with herbivorous dinosaurs. An opportunity to test this hypothesis arises from coprolites to some extent extruded from an immature cockroach preserved in the amber of Lebanon, studied using synchrotron X-ray microtomography. 1.06% of their volume is filled by particles of wood with smooth edges, in which size distribution directly supports their external pre-digestion. Because fungal pre-processing can be excluded based on the presence of large particles (combined with small total amount of wood) and absence of damages on wood, the likely source of wood are herbivore feces. Smaller particles were broken down biochemically in the cockroach hind gut, which indicates that the recent lignin-decomposing termite and cockroach endosymbionts might have been transferred to the cockroach gut upon feeding on dinosaur feces.

  18. Superfund and Toxic Release Inventory Sites, StateCERCLIS-This data set contains potential EPA Superfund sites. These locations represent sites, not contaminated areas., Published in 2008, 1:100000 (1in=8333ft) scale, State of Utah Automated Geographic Reference Center.

    Data.gov (United States)

    NSGIC GIS Inventory (aka Ramona) — This Superfund and Toxic Release Inventory Sites dataset, published at 1:100000 (1in=8333ft) scale, was produced all or in part from Field Survey/GPS information as...

  19. Environmental contaminants in fish and mussels from Meddybemps Lake, the Dennys River, and East Machias River - Eastern Surplus Superfund Site, Meddybemps, Maine

    Data.gov (United States)

    US Fish and Wildlife Service, Department of the Interior — From 1946 to the early 1980s, the 3-acre Eastern Surplus Superfund Site in Meddybemps, Maine, was used for the disposal and storage of surplus military equipment and...

  20. Integrating Monitoring and Genetic Methods To Infer Historical Risks of PCBs and DDE to Common and Roseate Terns Nesting Near the New Bedford Harbor Superfund Site (Massachusetts, USA)

    Science.gov (United States)

    Common and roseate terns are migratory piscivorous seabirds with major breeding colonies within feeding range of thepolychlorinated biphenyl (PCB)-contaminated New Bedford Harbor (NBH, MA, USA) Superfund site. Our longitudinal study shows that before PCB discharges into NBH cease...

  1. Evaluation of Exposure to Radon Levels in Relation to Climatic Conditions at a Superfund Site.

    Science.gov (United States)

    Merrill, Elaine Alice

    1995-11-01

    Workers at a Superfund site have expressed concern that they may be exposed to elevated levels of radon gas, especially when meteorology is suitable. The site, formally a uranium processing site, stores the world's largest quantity of Ra-226 in two concrete silos. A layer of bentonite foam was placed over the contents of the silos in 1991 as a means to reduce the amount of radon emissions. Hourly real-time outdoor and indoor site radon data covering an entire year was statistically evaluated in relation to meteorological data covering the same time period. The hourly data was found to be lognormally distributed. Radon levels were highest during the early morning hours and during the summer months. Both outdoor and indoor concentrations were found to significantly vary with temporal and climatic factors, namely wind direction and relative humidity. Radon levels in the work areas were not found to be statistically different from off-site levels. Only radon levels in the vicinity of the storage silos, which is an exclusion zone, were significantly higher than levels off-site. Hence, the protective bentonite covering seems to be effective in reducing radon emissions. Two methods were used to calculate a hypothetical dose, based upon the annual average concentrations of radon in the work areas onsite, the BEIR IV method and the NCRP method, respectively. The BEIR IV method, which accounts for the activity ratio of radon and its daughter products, resulted in a slightly higher dose than the NCRP method. As expected, based on the mean concentrations, the hypothetical annual exposures from radon in the work areas of the site were below recommended exposure limits.

  2. 40 CFR 263.31 - Discharge clean up.

    Science.gov (United States)

    2010-07-01

    ... 40 Protection of Environment 25 2010-07-01 2010-07-01 false Discharge clean up. 263.31 Section 263.31 Protection of Environment ENVIRONMENTAL PROTECTION AGENCY (CONTINUED) SOLID WASTES (CONTINUED... up. A transporter must clean up any hazardous waste discharge that occurs during transportation...

  3. Characterization of ecological risks at the Milltown Reservoir-Clark Fork River Sediments Superfund Site, Montana

    Science.gov (United States)

    Pascoe, Gary A.; Blanchet, Richard J.; Linder, Greg L.; Palawski, Don; Brumbaugh, William G.; Canfield, Tim J.; Kemble, Nile E.; Ingersoll, Chris G.; Farag, Aïda M.; DalSoglio, Julie A.

    1994-01-01

    A comprehensive field and laboratory approach to the ecological risk assessment for the Milltown Reservoir-Clark Fork River Sediments Site, a Superfund site in the Rocky Mountains of Montana, has been described in the preceding reports of this series. The risk assessment addresses concerns over the ecological impacts of upstream releases of mining wastes to fisheries of the upper Clark Fork River (CFR) and the benthic and terrestrial habitats further downstream in Milltown Reservoir. The risk characterization component of the process integrated results from a triad of information sources: (a) chemistry studies of environmental media to identify and quantify exposures of terrestrial and aquatic organisms to site-related contaminants; (b) ecological or population studies of terrestrial vegetation, birds, benthic communities, and fish; and (c) in situ and laboratory toxicity studies with terrestrial and aquatic invertebrates and plants, small mammals, amphibians, and fish exposed to contaminated surface water, sediments, wetland soils, and food sources. Trophic transfer studies were performed on waterfowl, mammals, and predatory birds using field measurement data on metals concentrations in environmental media and lower trophic food sources. Studies with sediment exposures were incorporated into the Sediment Quality Triad approach to evaluate risks to benthic ecology. Overall results of the wetland and terrestrial studies suggested that acute adverse biological effects were largely absent from the wetland; however, adverse effects to reproductive, growth, and physiological end points of various terrestrial and aquatic species were related to metals exposures in more highly contaminated depositional areas. Feeding studies with contaminated diet collected from the upper CFR indicated that trout are at high risk from elevated metals concentrations in surface water, sediment, and aquatic invertebrates. Integration of chemical analyses with toxicological and ecological

  4. Progress and challenges in cleaning up Hanford

    Energy Technology Data Exchange (ETDEWEB)

    Wagoner, J.D. [Dept. of Energy, Richland, WA (United States)

    1997-08-01

    This paper presents captioned viewgraphs which briefly summarize cleanup efforts at the Hanford Site. Underground waste tank and spent nuclear fuel issues are described. Progress is reported for the Plutonium Finishing Plant, PUREX plant, B-Plant/Waste Encapsulation Storage Facility, and Fast Flux Test Facility. A very brief overview of costs and number of sites remediated and/or decommissioned is given.

  5. Evaluation of geophysical logs, phase I, for Crossley Farms Superfund Site, Berks County, Pennsylvania

    Science.gov (United States)

    Conger, Randall W.

    1998-01-01

    Twenty-one wells were drilled at Crossley Farms Superfund Site between December 15, 1987, and May 1, 1988, to define and monitor the horizontal and vertical distribution of ground-water contamination emanating from a suspected contaminant source area (Blackhead Hill). Eight well clusters were drilled on or near the Crossley Site and three well clusters were drilled at locations hydrologically down gradient from the site. Depths of wells range from 21 to 299 feet below land surface. These wells were installed in saprolite in shallow, intermediate, and deep water-producing zones of the fractured bedrock aquifer. Borehole-geophysical and video logging were conducted between April 24, 1997, and May 8, 1997, to determine the water-producing zones, water-receiving zones, zones of vertical flow, borehole depth, and casing integrity in each well. This data and interpretation will be used to determine the location of the well intake for the existing open-hole wells, which will be retrofitted to isolate and monitor water-producing zones and prevent further cross-contamination within each open borehole, and identify wells that may need rehabilitation or replacement. Caliper and video logs were used to locate fractures, inflections on fluid-temperature and fluidresistivity logs indicated possible fluid-bearing fractures, and flowmeter measurements verified these locations. Single-point-resistance and natural-gamma logs provided information on stratigraphy. After interpretation of geophysical logs, video logs, and driller?s notes, all wells will be constructed so that water-level fluctuations can be monitored and discrete water samples collected from shallow, intermediate, and deep water-bearing zones in each well. Geophysical logs were run on seven bedrock and two deep bedrock wells. Gamma logs were run on 10 bedrock wells. Twenty-two wells were inspected visually with the borehole video camera for casing integrity.

  6. Detection of environmentally persistent free radicals at a superfund wood treating site.

    Science.gov (United States)

    dela Cruz, Albert Leo N; Gehling, William; Lomnicki, Slawomir; Cook, Robert; Dellinger, Barry

    2011-08-01

    Environmentally persistent free radicals (EPFRs) have previously been observed in association with combustion-generated particles and airborne PM(2.5) (particulate matter, d 2.5um). The purpose of this study was to determine if similar radicals were present in soils and sediments at Superfund sites. The site was a former wood treating facility containing pentachlorophenol (PCP) as a major contaminant. Both contaminated and noncontaminated (just outside the contaminated area) soil samples were collected. The samples were subjected to the conventional humic substances (HS) extraction procedure. Electron paramagnetic resonance (EPR) spectroscopy was used to measure the EPFR concentrations and determine their structure for each sample fraction. Analyses revealed a ∼30× higher EPFR concentration in the PCP contaminated soils (20.2 × 10(17) spins/g) than in the noncontaminated soil (0.7 × 10(17) spins/g). Almost 90% of the EPFR signal originated from the minerals/clays/humins fraction. GC-MS analyses revealed ∼6500 ppm of PCP in the contaminated soil samples and none detected in the background samples. Inductively coupled plasma-atomic emission spectrophotometry (ICP-AES) analyses revealed ∼7× higher concentrations of redox-active transition metals, in the contaminated soils than the noncontaminated soil. Vapor phase and liquid phase dosing of the clays/minerals/humins fraction of the soil with PCP resulted in an EPR signal identical to that observed in the contaminated soil, strongly suggesting the observed EPFR is pentachlorophenoxyl radical. Chemisorption and electron transfer from PCP to transition metals and other electron sinks in the soil are proposed to be responsible for EPFR formation.

  7. Geochemical Characteristics of TP3 Mine Wastes at the Elizabeth Copper Mine Superfund Site, Orange County, Vermont

    Science.gov (United States)

    Hammarstrom, Jane M.; Piatak, Nadine M.; Seal, Robert R., II; Briggs, Paul H.; Meier, Allen L.; Muzik, Timothy L.

    2003-01-01

    Remediation of the Elizabeth mine Superfund site in the Vermont copper belt poses challenges for balancing environmental restoration goals with issues of historic preservation while adopting cost-effective strategies for site cleanup and long-term maintenance. The waste-rock pile known as TP3, at the headwaters of Copperas Brook, is especially noteworthy in this regard because it is the worst source of surface- and ground-water contamination identified to date, while also being the area of greatest historical significance. The U.S. Geological Survey (USGS) conducted a study of the historic mine-waste piles known as TP3 at the Elizabeth mine Superfund site near South Strafford, Orange County, VT. TP3 is a 12.3-acre (49,780 m2) subarea of the Elizabeth mine site. It is a focus area for historic preservation because it encompasses an early 19th century copperas works as well as waste from late 19th- and 20th century copper mining (Kierstead, 2001). Surface runoff and seeps from TP3 form the headwaters of Copperas Brook. The stream flows down a valley onto flotation tailings from 20th century copper mining operations and enters the West Branch of the Ompompanoosuc River approximately 1 kilometer downstream from the mine site. Shallow drinking water wells down gradient from TP3 exceed drinking water standards for copper and cadmium (Hathaway and others, 2001). The Elizabeth mine was listed as a Superfund site in 2001, mainly because of impacts of acid-mine drainage on the Ompompanoosuc River.

  8. Slow clean-up for fast reactor

    Science.gov (United States)

    Banks, Michael

    2008-05-01

    The year 2300 is so distant that one may be forgiven for thinking of it only in terms of science fiction. But this is the year that workers at the Dounreay power station in Northern Scotland - the UK's only centre for research into "fast" nuclear reactors - term as the "end point" by which time the site will be completely clear of radioactive material. More than 180 facilities - including the iconic dome that housed the Dounreay Fast Reactor (DFR) - were built at at the site since it opened in 1959, with almost 50 having been used to handle radioactive material.

  9. Superfund and Toxic Release Inventory Sites, Point or polygon geo-location of federally designated superfund sites in Wisconsin. Usually geolocated via on screen digitizing against DOPs (could be geo-located via GPS). Source year of DOPs vary, Published in unknown, 1:4800 (1in=400ft) scale, Wisconsin DNR - Bureau of Remediation and Redevelopment.

    Data.gov (United States)

    NSGIC GIS Inventory (aka Ramona) — This Superfund and Toxic Release Inventory Sites dataset, published at 1:4800 (1in=400ft) scale, was produced all or in part from Orthoimagery information as of...

  10. Using a triad approach in the assessment of hazardous waste site leaching from a Superfund site to an adjacent stream

    Energy Technology Data Exchange (ETDEWEB)

    Leppanen, C.J. [Univ. of Maine, Orono, ME (United States). Dept. of Biochemistry, Microbiology, and Molecular Biology; Blanner, P.M.; Allan, R.S.; Maier, K.J. [Univ. of Memphis, TN (United States); Benson, W.H. [Univ. of Mississippi, University, MS (United States)

    1998-10-01

    A triad approach was used in the evaluation of sediment in the Wolf River adjacent to the North Hollywood Dump, a federally listed Superfund site. Chemical analyses were done for 18 organochlorine pesticides, 21 polychlorinated biphenyl (PCB) congeners, and 10 metals. Sediment toxicity was evaluated with freshwater invertebrates. Chironomus tentans and Hyalella azteca. Benthic macroinvertebrate diversity and abundance were assessed with a family-level biotic index. Mean Al, Ba, Cd, Cu, Fe, Ni, Pb, and Zn concentrations were significantly higher in sediments collected in the spring. Both spring and fall sediments exhibited toxicity downstream from, adjacent to, and upstream from the dump, with toxicity significantly higher in fall sediments; however, a consistent trend was not observed. Toxicity was typically greater in the fall, and metal concentrations were typically higher in spring sediments, suggesting that metals were not responsible for the toxicity. Sediment-associated organochlorine pesticide and PCB congener concentrations were all below detectable limits, suggesting that these potential contaminants are not contributing to the observed toxicity. No differences were found in benthic macroinvertebrate community structure, which was composed of predominantly pollution-tolerant families, among seasons or river reaches, which appear to be limited by the physical characteristics of the river. Sediments in urban reaches of the Wolf River appear to be degraded; the North Hollywood Dump cannot be isolated as a source of toxicity in this study. In situ testing, sediment toxicity identification and evaluation testing, acid-volatile sulfide analyses, or artificial substrate work would be appropriate to follow.

  11. Superfund and Toxic Release Inventory Sites - MO 2010 Permitted Hazardous Waste Sites - Areas(SHP)

    Data.gov (United States)

    NSGIC GIS Inventory (aka Ramona) — This is a polygon data set depicting locations of facilities' property boundaries. The data set contains sites permitted to treat, store or dispose of hazardous...

  12. Analysis of geophysical logs, at North Penn Area 6 Superfund Site, Lansdale, Montgomery County, Pennsylvania

    Science.gov (United States)

    Conger, Randall W.

    1999-01-01

    The U.S. Geological Survey (USGS), as part of technical assistance to the U.S. Environmental Protection Agency (USEPA), collected borehole geophysical log data in 34 industrial, commercial, and public supply wells and 28 monitor wells at the North Penn Area 6 Superfund Site, in Lansdale, Pa., from August 22, 1995, through August 29, 1997. The wells range in depth from 50 to 1,027 feet below land surface and are drilled in Triassic-age shales and siltstones of the Brunswick Group and Lockatong Formation. The geophysical log data were collected to help describe the hydrogeologic framework in the area and to provide guidance in the reconstruction of the 28 monitor wells drilled during summer 1997. At the time of logging, all wells had open-hole construction. The geophysical logs, caliper, fluid-resistivity, and fluid-temperature, and borehole video logs were used to determine the vertical distribution of water-bearing fractures. Heatpulse-flowmeter measurements were used to determine vertical borehole flow under pumping and nonpumping conditions. The most productive fractures generally could be determined from heatpulse-flowmeter measurements under pumping conditions. Vertical borehole flow was measured under nonpumping conditions in most wells that had more than one water-bearing fracture. Upward flow was measured in 35 wells and probably is a result of natural head differences between fractures in the local ground-water-flow system. Downward flow was measured in 11 wells and commonly indicated differences in hydraulic heads of the fractures caused by nearby pumping. Both upward and downward flow was measured in three wells. No flow was detected in eight wells. Natural-gamma-ray logs were used to estimate the attitude of bedding. Thin shale marker beds, shown as spikes of elevated radioactivity in the natural-gamma logs of some wells throughout the area, enable the determination of bedding-plane orientation from three-point correlations. Generally, the marker beds in

  13. Superfund Query

    Data.gov (United States)

    U.S. Environmental Protection Agency — The Superfund Query allows users to retrieve data from the Comprehensive Environmental Response, Compensation, and Liability Information System (CERCLIS) database.

  14. Feasibility Study of Economics and Performance of Solar Photovoltaics at the Stringfellow Superfund Site in Riverside, California

    Energy Technology Data Exchange (ETDEWEB)

    Mosey, G.; Van Geet, O.

    2010-12-01

    This report presents the results of an assessment of the technical and economic feasibility of deploying a photovoltaics (PV) system on the Stringfellow Superfund Site in Riverside, California. The site was assessed for possible PV installations. The cost, performance, and site impacts of different PV options were estimated. The economics of the potential systems were analyzed using an electric rate of $0.13/kWh and incentives offered by Southern California Edison under the California Solar Initiative. According to the assessment, a government-owned, ground-mounted PV system represents a technically and economically feasible option. The report recommends financing options that could assist in the implementation of such a system.

  15. In situ field screening for polynuclear aromatic hydrocarbons with a portable spectrofluorometer at a Superfund site near Jackson, Tennessee

    Energy Technology Data Exchange (ETDEWEB)

    Amick, E.N.; Pollard, J.E. [Lockheed Environmental Systems and Technologies Co., Las Vegas, NV (United States); Engelmann, W.H. [Environmental Protection Agency, Las Vegas, NV (United States). Environmental Monitoring Systems Lab.; Vo-Dinh, T. [Oak Ridge National Lab., TN (United States). Advanced Monitoring Development Group

    1994-12-31

    The US Environmental Protection Agency`s (EPA) Environmental Monitoring Systems Laboratory in Las Vegas, Nevada (EMSL-LV) is currently evaluating the use of scanning ultraviolet-visible (UV-vis) fluorescence as a field screening technology. A prototype field-portable spectrofluorometer capable of excitation, emission, and synchronous scans has been developed and was field tested at the American Creosote Works Superfund site. The UV-vis fluorescence spectra of various polynuclear aromatic hydrocarbons (PAHs) were clearly seen in the synchronous spectra of soil samples extracted on site. Split soil samples were analyzed by gas chromatography/mass spectroscopy and by immunoassay methods. Although a comparison of results with these other methods has not been completed, the synchronous fluorescence method shows promise in that analytical results have the potential to provide compound- or class-selective results and can be immediately available on-site at a reasonable cost.

  16. Superfund Reauthorization 1994: DoD’s Opportunity to Clean Up Its Hazardous Waste Act

    Science.gov (United States)

    1994-04-01

    House Comm. on Government Operations, 101st Cong., 1st Sess. 3 (1989) (testimony of Richard L. Hembra , Director, Environmental Protection Issues...Public Works and Transportation, 102d Cong., 2d Sess. 701 (1992) (statement of Richard Hembra , Director, Environmental Protection Issues, Resources

  17. Geophysical logging and thermal imaging near the Hemphill Road TCE National Priorities List Superfund site near Gastonia, North Carolina

    Science.gov (United States)

    Antolino, Dominick J.; Chapman, Melinda J.

    2017-03-27

    Borehole geophysical logs and thermal imaging data were collected by the U.S. Geological Survey near the Hemphill Road TCE (trichloroethylene) National Priorities List Superfund site near Gastonia, North Carolina, during August 2014 through February 2015. In an effort to assist the U.S. Environmental Protection Agency in the development of a conceptual groundwater model for the assessment of current contaminant distribution and future migration of contaminants, surface geological mapping and borehole geophysical log and thermal imaging data collection, which included the delineation of more than 600 subsurface features (primarily fracture orientations), was completed in five open borehole wells and two private supply bedrock wells. In addition, areas of possible groundwater discharge within a nearby creek downgradient of the study site were determined based on temperature differences between the stream and bank seepage using thermal imagery.

  18. Calculating the Diffusive Flux of Persistent Organic Pollutants between Sediments and the Water Column on the Palos Verdes Shelf Superfund Site using Polymeric Passive Samplers

    Science.gov (United States)

    Passive samplers were used to determine water concentrations of persistent organic pollutants (POPs) in the surface sediments and near-bottom water of a marine Superfund site on the Palos Verdes Shelf, California, USA. Measured concentrations in the porewater and water column at...

  19. Passive Sampling to Measure Baseline Dissolved Persistent Organic Pollutant Concentrations in the Water Column of the Palos Verdes Shelf Superfund Site

    Science.gov (United States)

    Passive sampling was used to deduce water concentrations of persistent organic pollutants (POPs) in the vicinity of a marine Superfund site on the Palos Verdes Shelf, California, USA. Pre-calibrated solid phase microextraction (SPME) fibers and polyethylene (PE) strips that were...

  20. DOJ News Release: New York Man Ordered to Pay Over $400,000 in Restitution and Fines for Role in Kickback Scheme at New Jersey Superfund Sites

    Science.gov (United States)

    WASHINGTON, D.C. – An Amherst, New York, man was ordered to pay over $400,000 in restitution and fines and placed on five years’ probation for his role in a kickback scheme at the Federal Creosote and Diamond Alkali Superfund sites in New Jersey.

  1. Occurences and Fate of DDT Principal Isomers/Metabolites, DDA, and o,p'-DDD Enantiomers in Fish, Sediment and Water at a DDT-Impacted Superfund Site

    Science.gov (United States)

    In the 1950s and 60s, discharges from a DDT manufacturing plant contaminated a tributary system of the Tennessee River near Huntsville, Alabama, USA. Regulatory action resulted in declaring the area a Superfund site which required remediation and extensive monitoring. Monitoring ...

  2. Ethanol-Fed Or Solid-Phase Organic Sulfate Reducing Bioreactors For The National Tunnel Drainage, Clear Creek/Central City Superfund Site (Presentation)

    Science.gov (United States)

    The U.S. Environmental Protection Agency (EPA) is planning to treat mining influenced water (MIW) from the National Tunnel Adit that discharges to North Clear Creek near the City of Blackhawk, Colorado. North Clear Creek is part of the Clear Creek/Central City Superfund Site, an...

  3. Ethanol-Fed Or Solid-Phase Organic Sulfate Reducing Bioreactors For The National Tunnel Drainage, Clear Creek/Central City Superfund Site

    Science.gov (United States)

    The U.S. Environmental Protection Agency (EPA) is planning to treat mining influenced water (MIW) from the National Tunnel Adit that discharges to North Clear Creek near the City of Blackhawk, Colorado. North Clear Creek is part of the Clear Creek/Central City Superfund Site, an...

  4. COMPARISON OF GEOPROBE PRT AND AMS GVP SOIL-GAS SAMPLING SYSTEMS WITH DEDICATED VAPOR PROBES IN SANDY SOILS AT THE RAYMARK SUPERFUND SITE

    Science.gov (United States)

    A study was conducted near the Raymark Superfund Site in Stratford, Connecticut to compare results of soil-gas sampling using dedicated vapor probes, a truck-mounted direct-push technique - the Geoprobe Post-Run-Tubing (PRT) system, and a hand-held rotary hammer technique - the A...

  5. Post-Remediation Biomonitoring of Pesticides in Marine Waters Near the United Heckathorn Superfund Site, Richmond, California

    Energy Technology Data Exchange (ETDEWEB)

    LD Antrim; NP Kohn

    2000-09-05

    This report, PNNL-11911 Rev. 1, was published in July 2000 and replaces PNNL-11911, which was published in September 1998. The revision corrects tissue concentration units that were reported as dry weight but were actually wet weight, and updates conclusions based on the correct reporting units. Marine sediment remediation at the United Heckathorn Superfund Site was completed in April 1997. Water and mussel tissues were sampled in January 1998 from four stations near Lauritzen Canal in Richmond, California, for the first post-remediation monitoring of marine areas near the United Heckathorn Site. Dieldrin and DDT were analyzed in water samples, tissue samples from resident mussels, and tissue samples from transplanted mussels deployed for 4 months. Concentrations of dieldrin and total DDT in water and total DDT in tissue were compared to pre-remediation data available from the California State Mussel Watch program (tissues) and the Ecological Risk Assessment for the United Heckathorn Superfund Site (tissues and water). Chlorinated pesticide concentrations in water samples were similar to pre-remediation levels and did not meet remediation goals. Mean dieldrin concentrations in water ranged from 0.65 ng/L to 18.1 ng/L and were higher than the remediation goal (0.14 ng/L) at all stations. Mean total DDT concentrations in water ranged from 0.65 ng/L to 103 ng/L and exceeded the remediation goal of 0.59 ng/L. The highest concentrations of both pesticides were found in Lauritzen Canal, and the lowest levels were from the Richmond Inner Harbor Channel water. Unusual amounts of detritus in the water column at the time of sampling, particularly in Lauritzen Canal, could have contributed to the elevated pesticide concentrations and poor analytical precision.

  6. Aquatic assessment of the Pike Hill Copper Mine Superfund site, Corinth, Vermont

    Science.gov (United States)

    Piatak, Nadine M.; Argue, Denise M.; Seal, Robert R.; Kiah, Richard G.; Besser, John M.; Coles, James F.; Hammarstrom, Jane M.; Levitan, Denise M.; Deacon, Jeffrey R.; Ingersoll, Christopher G.

    2013-01-01

    The Pike Hill Copper Mine Superfund site in Corinth, Orange County, Vermont, includes the Eureka, Union, and Smith mines along with areas of downstream aquatic ecosystem impairment. The site was placed on the U.S. Environmental Protection Agency (USEPA) National Priorities List in 2004. The mines, which operated from about 1847 to 1919, contain underground workings, foundations from historical structures, several waste-rock piles, and some flotation tailings. The mine site is drained to the northeast by Pike Hill Brook, which includes several wetland areas, and to the southeast by an unnamed tributary that flows to the south and enters Cookville Brook. Both brooks eventually drain into the Waits River, which flows into the Connecticut River. The aquatic ecosystem at the site was assessed using a variety of approaches that investigated surface-water quality, sediment quality, and various ecological indicators of stream-ecosystem health. The degradation of surface-water quality is caused by elevated concentrations of copper, and to a lesser extent cadmium, with localized effects caused by aluminum, iron, and zinc. Copper concentrations in surface waters reached or exceeded the USEPA national recommended chronic water-quality criteria for the protection of aquatic life in all of the Pike Hill Brook sampling locations except for the location farthest downstream, in half of the locations sampled in the tributary to Cookville Brook, and in about half of the locations in one wetland area located in Pike Hill Brook. Most of these same locations also contained concentrations of cadmium that exceeded the chronic water-quality criteria. In contrast, surface waters at background sampling locations were below these criteria for copper and cadmium. Comparison of hardness-based and Biotic Ligand Model (BLM)-based criteria for copper yields similar results with respect to the extent or number of stations impaired for surface waters in the affected area. However, the BLM

  7. Geophysical logging and geologic mapping data in the vicinity of the GMH Electronics Superfund site near Roxboro, North Carolina

    Science.gov (United States)

    Chapman, Melinda J.; Clark, Timothy W.; Williams, John H.

    2013-01-01

    Geologic mapping, the collection of borehole geophysical logs and images, and passive diffusion bag sampling were conducted by the U.S. Geological Survey North Carolina Water Science Center in the vicinity of the GMH Electronics Superfund site near Roxboro, North Carolina, during March through October 2011. The study purpose was to assist the U.S. Environmental Protection Agency in the development of a conceptual groundwater model for the assessment of current contaminant distribution and future migration of contaminants. Data compilation efforts included geologic mapping of more than 250 features, including rock type and secondary joints, delineation of more than 1,300 subsurface features (primarily fracture orientations) in 15 open borehole wells, and the collection of passive diffusion-bag samples from 42 fracture zones at various depths in the 15 wells.

  8. Geophysical logging and thermal imaging at the Hemphill Road TCE NPL Superfund site near Gastonia, North Carolina

    Science.gov (United States)

    Antolino, Dominick J.; Chapman, Melinda J.

    2017-01-01

    The collection of borehole geophysical logs and thermal imaging data was conducted by the U.S. Geological Survey South Atlantic Water Science Center in the vicinity of the Hemphill Road TCE National Priorities List Superfund site near Gastonia, North Carolina, during August 2014 through February 2015. In an effort to assist the U.S. Environmental Protection Agency in the development of a conceptual groundwater model for the assessment of current contaminant distribution and future migration of contaminants, surface geological mapping and borehole geophysical log and image data collection, which included the delineation of more than 600 subsurface features (primarily fracture orientations) was conducted in 5 open borehole wells and 2 private supply bedrock wells. In addition, areas of potential groundwater discharge within a down-gradient, nearby creek were determined using thermal imagery to calculate temperature differences between the stream and bank seepage.

  9. Investigation of total and hexavalent chromium in filtered and unfiltered groundwater samples at the Tucson International Airport Superfund Site

    Science.gov (United States)

    Tillman, Fred; McCleskey, R. Blaine; Hermosillo, Edyth

    2016-01-01

    Potential health effects from hexavalent chromium in groundwater have recently become a concern to regulators at the Tucson International Airport Area Superfund site. In 2016, the U.S. Geological Survey sampled 46 wells in the area to characterize the nature and extent of chromium in groundwater, to understand what proportion of total chromium is in the hexavalent state, and to determine if substantial differences are present between filtered and unfiltered chromium concentrations. Results indicate detectable chromium concentrations in all wells, over 75 % of total chromium is in the hexavalent state in a majority of wells, and filtered and unfiltered results differ substantially in only a few high-turbidity total chromium samples.

  10. Influence of a chlor-alkali superfund site on mercury bioaccumulation in periphyton and low-trophic level fauna

    Science.gov (United States)

    Buckman, Kate L.; Marvin-DiPasquale, Mark C.; Taylor, Vivien F.; Chalmers, Ann T.; Broadley, Hannah J.; Agee, Jennifer L.; Jackson, Brian P.; Chen, Celia Y.

    2015-01-01

    In Berlin, New Hampshire, USA, the Androscoggin River flows adjacent to a former chlor-alkali facility that is a US Environmental Protection Agency Superfund site and source of mercury (Hg) to the river. The present study was conducted to determine the fate and bioaccumulation of methylmercury (MeHg) to lower trophic-level taxa in the river. Surface sediment directly adjacent to the source showed significantly elevated MeHg (10–40× increase, mean ± standard deviation [SD]: 20.1 ± 24.8 ng g–1 dry wt) and total mercury (THg; 10–30× increase, mean ± SD: 2045 ± 2669 ng g–1 dry wt) compared with all other reaches, with sediment THg and MeHg from downstream reaches elevated (3–7× on average) relative to the reference (THg mean ± SD: 33.5 ± 9.33 ng g–1 dry wt; MeHg mean ± SD: 0.52 ± 0.21 ng g–1 dry wt). Water column THg concentrations adjacent to the point source for both particulate (0.23 ng L–1) and dissolved (0.76 ng L–1) fractions were 5-fold higher than at the reference sites, and 2-fold to 5-fold higher than downstream. Methylmercury production potential of periphyton material was highest (2–9 ng g–1 d–1 dry wt) adjacent to the Superfund site; other reaches were close to or below reporting limits (0. 1 ng g–1 d–1 dry wt). Total Hg and MeHg bioaccumulation in fauna was variable across sites and taxa, with no clear spatial patterns downstream of the contamination source. Crayfish, mayflies, and shiners showed a weak positive relationship with porewater MeHg concentration.

  11. Sinopec offers HK$10m to clean up affected beaches

    Institute of Scientific and Technical Information of China (English)

    2012-01-01

    Sinopec has established a HK$10 million fund to assist green groups in cleaning up the millions of plastic pellets from a container ship that have been washed ashore on local beaches and fish farms. The 150 tons of polypropylene pellets were being shipped on board a freighter Yong Xin .lie 1 from Nansha Port to Shantou when signal l0 typhoon Vicente struck on ,luly 23. The pellets, in six containers, were blown into the sea. The pellets then washed onto the outlying islands of Hong Kong, stirring concerns over environmental damage to the ocean itself, as well as to marine life.

  12. Project strategy for clean-up of sedimentary radioactive material in Fukushima bay areas using snake-like robotics

    Directory of Open Access Journals (Sweden)

    Cho Hyo Sung

    2015-01-01

    Full Text Available The snake-like robot is used for clean-up project in Fukushima nuclear disaster site. The contaminated water at the Fukushima Daiichi nuclear power plants has been purified by the water treatment system, called Advanced Liquid Processing System, co-developed by Japanese and international technologies. The system is used to remove most remaining radioactive contaminants in water that had to be stored at the facility. In this paper, a snake-like robot, incorporated with Advanced Liquid Processing System is introduced for the severe accident in the nuclear power plants in which human cannot control the cleaning-up in the sea where the radioactive materials have been submerged and some resolved in the sea water. The effective strategy of the cleaning-up is analyzed from the environmental protection aspect with the snake's biomechanics and radioactive hazards.

  13. Surface-Water Hydrology and Quality at the Pike Hill Superfund Site, Corinth, Vermont, October 2004 to December 2005

    Science.gov (United States)

    Kiah, Richard G.; Deacon, Jeffrey R.; Piatak, Nadine M.; Seal, Robert R.; Coles, James F.; Hammarstrom, Jane M.

    2007-01-01

    The hydrology and quality of surface water in and around the Pike Hill Brook watershed, in Corinth, Vermont, was studied from October 2004 to December 2005 by the U.S. Geological Survey in cooperation with the U.S. Environmental Protection Agency (USEPA). Pike Hill was mined intermittently for copper from 1847 to 1919 and the site is known to be contributing trace elements and acidity to Pike Hill Brook and an unnamed tributary to Cookville Brook. The site has been listed as a Superfund site since 2004. Streamflow, specific conductance, pH, and water temperature were measured continuously and monthly at three sites on Pike Hill Brook to determine the variation in these parameters over an annual cycle. Synoptic water-quality sampling was done at 10 stream sites in October 2004, April 2005, and June 2005 and at 13 stream sites in August 2005 to characterize the quality of surface water in the watershed on a seasonal and spatial basis, as well as to assess the effects of wetlands on water quality. Samples for analysis of benthic macroinvertebrate populations were collected at 11 stream sites in August 2005. Water samples were analyzed for 5 major ions and 32 trace elements. Concentrations of trace elements at sites in the Pike Hill Brook watershed exceeded USEPA National Recommended Water Quality Criteria acute and chronic toxicity standards for aluminum, iron, cadmium, copper, and zinc. Concentrations of copper exceeded the chronic criteria in an unnamed tributary to Cookville Brook in one sample. Concentrations of sulfate, calcium, aluminum, iron, cadmium, copper, and zinc decreased with distance from a site directly downstream from the mine (site 1), as a result of dilution and through sorption and precipitation of the trace elements. Maximum concentrations of aluminum, iron, cadmium, copper, and zinc were observed during spring snowmelt. Concentrations of sulfate, calcium, cadmium, copper, and zinc, and instantaneous loads of calcium and aluminum were

  14. Surface-Water Hydrology and Quality at the Pike Hill Superfund Site, Corinth, Vermont, October 2004 to December 2005

    Science.gov (United States)

    Kiah, Richard G.; Deacon, Jeffrey R.; Piatak, Nadine M.; Seal, Robert R., II; Coles, James F.; Hammarstrom, Jane M.

    2007-01-01

    The hydrology and quality of surface water in and around the Pike Hill Brook watershed, in Corinth, Vermont, was studied from October 2004 to December 2005 by the U.S. Geological Survey in cooperation with the U.S. Environmental Protection Agency (USEPA). Pike Hill was mined intermittently for copper from 1847 to 1919 and the site is known to be contributing trace elements and acidity to Pike Hill Brook and an unnamed tributary to Cookville Brook. The site has been listed as a Superfund site since 2004. Streamflow, specific conductance, pH, and water temperature were measured continuously and monthly at three sites on Pike Hill Brook to determine the variation in these parameters over an annual cycle. Synoptic water-quality sampling was done at 10 stream sites in October 2004, April 2005, and June 2005 and at 13 stream sites in August 2005 to characterize the quality of surface water in the watershed on a seasonal and spatial basis, as well as to assess the effects of wetlands on water quality. Samples for analysis of benthic macroinvertebrate populations were collected at 11 stream sites in August 2005. Water samples were analyzed for 5 major ions and 32 trace elements. Concentrations of trace elements at sites in the Pike Hill Brook watershed exceeded USEPA National Recommended Water Quality Criteria acute and chronic toxicity standards for aluminum, iron, cadmium, copper, and zinc. Concentrations of copper exceeded the chronic criteria in an unnamed tributary to Cookville Brook in one sample. Concentrations of sulfate, calcium, aluminum, iron, cadmium, copper, and zinc decreased with distance from a site directly downstream from the mine (site 1), as a result of dilution and through sorption and precipitation of the trace elements. Maximum concentrations of aluminum, iron, cadmium, copper, and zinc were observed during spring snowmelt. Concentrations of sulfate, calcium, cadmium, copper, and zinc, and instantaneous loads of calcium and aluminum were

  15. Lawmakers Order EPA To Clean Up Work Environment

    Directory of Open Access Journals (Sweden)

    Nicole Ruediger

    2000-01-01

    Full Text Available Washington, Oct 6 — On Wednesday, members of Congress ordered the Environmental Protection Agency (EPA to do a “Superfund” cleanup of its own work environment. For 3 hours, lawmakers and the public listened as witnesses testified to patterns of intolerance, discrimination, and retaliation within the EPA — “This agency is run like a 21st century plantation and this has to stop,” said witness and EPA policy analyst Marsha Coleman-Adebayo.

  16. Evaluation of borehole geophysical and video logs, at Butz Landfill Superfund Site, Jackson Township, Monroe County, Pennsylvania

    Science.gov (United States)

    Low, D.J.; Conger, R.W.

    2001-01-01

    Between February 1996 and November 2000, geophysical logging was conducted in 27 open borehole wells in and adjacent to the Butz Landfill Superfund Site, Jackson Township, Monroe County, Pa., to determine casing depth and depths of water-producing zones, water-receiving zones, and zones of vertical borehole flow. The wells range in depth from 57 to 319 feet below land surface. The geophysical logging determined the placement of well screens and packers, which allow monitoring and sampling of water-bearing zones in the fractured bedrock so that the horizontal and vertical distribution of contaminated ground water migrating from known sources could be determined. Geophysical logging included collection of caliper, natural-gamma, single-point-resistance, fluid-resistivity, fluid-temperature, and video logs. Caliper and video logs were used to locate fractures, joints, and weathered zones. Inflections on single-point-resistance, fluid-temperature, and fluid-resistivity logs indicated possible water-bearing fractures, and heatpulse-flowmeter measurements verified these locations. Natural-gamma logs provided information on stratigraphy.

  17. The electro-thermal dynamic stripping process for the remediation of a creosote-contaminated superfund site

    Energy Technology Data Exchange (ETDEWEB)

    Northington, C.D. [WRS Infrastructure and Environment, Tampa, FL (United States); McGee, B.C.W. [McMillan-McGee Corp., Calgary, AB (Canada)

    2005-07-01

    Pump-and-treat is a conventional soil and groundwater contaminant removal method that depends on factors such as the chemical nature of the contaminant, subsurface heterogeneity, sorption of contaminants to subsurface materials, difficulties in characterizing the subsurface, and system design. The cleanup of dense non-aqueous phase liquids (DNAPLs) is further complicated by the uncertain contaminant fate due to the tendency of DNAPLs to migrate downward, where they become difficult to locate and where they become immobile residual globules and a long-term source of ground water contamination. This paper presents the results of a pilot scale study in which an in-situ thermal decontamination technology was tested. The technology known as the Electro-Thermal Dynamic Stripping Process{sup TM} (ET-DS), was developed for a creosote-contaminated Superfund site to show the effectiveness of full-scale implementation of this method over the currently used pump-and- treat system to address contamination in the source zone. The pilot study follows similar methods used by reservoir engineers in the evaluation of thermal recovery methods for the recovery of bitumen and heavy oil. ET-DS was field test in the oil sands in order to use some operating data from the pilot to design oil sand specific ET-DS.

  18. Relating Magnetic Parameters to Heavy Metal Concentrations and Environmental Factors at Formosa Mine Superfund Site, Douglas County, OR

    Science.gov (United States)

    Upton, T. L.

    2016-12-01

    Advances in the field of environmental magnetism have led to exciting new applications for this field. Magnetic minerals are ubiquitous in the environment and tend to have an affinity for heavy metals. Hence, it has been demonstrated that magnetic properties are often significantly related to concentrations of heavy metals and other pollutants. As a result, magnetic techniques have been used as proxy for determining hot spots of several types of pollution produced from a diversity of anthropogenic sources. Magnetic measurements are non-destructive and relatively inexpensive compared to geochemical analyses. The utility of environmental magnetic methods varies widely depending on biological, chemical and physical processes that create and transform soils and sediments. Applications in the direction of mapping heavy metals have been studied and shown to be quite useful in countries such as China and India but to date, little research has been done in the US. As such, there is need to expand the scope of research to a wider range of soil types and land uses, especially within the US. This study investigates the application of environmental magnetic techniques to mapping of heavy metal concentrations at the Formosa Mine Superfund Site, an abandoned mine about 25 miles southwest of Roseburg, OR. The soils and sediment at this site are derived from pyrite-rich bedrock which is weak in terms of magnetic susceptibility. Using hotspot analysis, correlation and cluster analyses, interactions between metals and magnetic parameters are investigated in relation to environmental factors such as proximity to seeps and adits. Preliminary results suggest significant correlation of magnetic susceptibility with certain heavy metals, signifying that magnetic methods may be useful in mapping heavy metal hotspots at this site. Further analysis examines the relation of various land use differences in magnetic signatures obtained throughout the Cow Creek watershed.

  19. Description of borehole geophysical and geologist logs, Berks Sand Pit Superfund Site, Longswamp Township, Berks County, Pennsylvania

    Science.gov (United States)

    Low, Dennis J.; Conger, Randall W.

    2003-01-01

    Between October 2002 and January 2003, geophysical logging was conducted in six boreholes at the Berks Sand Pit Superfund Site, Longswamp Township, Berks County, Pa., to determine (1) the waterproducing zones, water-receiving zones, zones of vertical borehole flow, orientation of fractures, and borehole and casing depth; and (2) the hydraulic interconnection between the six boreholes and the site extraction well. The boreholes range in depth from 61 to 270 feet. Geophysical logging included collection of caliper, natural-gamma, single-point-resistance, fluid-temperature, fluid-flow, and acoustic-televiewer logs. Caliper and acoustic-televiewer logs were used to locate fractures, joints, and weathered zones. Inflections on fluid-temperature and single-point-resistance logs indicated possible water-bearing fractures, and flowmeter measurements verified these locations. Single-point-resistance, natural-gamma, and geologist logs provided information on stratigraphy. Flowmeter measurements were conducted while the site extraction well was pumping and when it was inactive to determine the hydraulic connections between the extraction well and the boreholes. Borehole geophysical logging and heatpulse flowmetering indicate active flow in the boreholes. Two of the boreholes are in ground-water discharge areas, two boreholes are in ground-water recharge areas, and one borehole is in an intermediate regime. Flow was not determined in one borehole. Heatpulse flowmetering, in conjunction with the geologist logs, indicates highly weathered zones in the granitic gneiss can be permeable and effective transmitters of water, confirming the presence of a two-tiered ground-water-flow system. The effort to determine a hydraulic connection between the site extraction well and six logged boreholes was not conclusive. Three boreholes showed decreases in depth to water after pumping of the site extraction well; in two boreholes, the depth to water increased. One borehole was cased its

  20. Pilot demonstration for containment using in situ soil mixing techniques at a chemical disposal superfund site

    Energy Technology Data Exchange (ETDEWEB)

    Zarlinski, S.J.; Kingham, N.W.; Semenak, R. [Kiber Environmental Services, Inc., Atlanta, GA (United States)

    1997-12-31

    Kiber Environmental Services, Inc. (Kiber), under contract to McLaren-Hart Corporation and the site PRP group, performed technical oversight and on-site sampling and analyses at the confidential site located in Texas. The site consists of 15,000 cubic meters (20,000 cubic yards) of contaminated materials that were to be solidified on-site. The contaminants included heavy metals, PAHs, oil and grease, and volatile organics. Groundwater is less than 1 meter from the surface. Kiber was retained after several unsuccessful efforts to find on-site containment methods that effectively solidified the waste pits while achieving the performance goals. The PRP group then contracted with Kiber to perform the treatability and pilot oversight studies. The full-scale pilot demonstration was performed by Geo-Con. Pilot-scale treatment was performed to evaluate the effectiveness of in situ solidification treatment at achieving the site specific performance criteria, including an unconfined compressive strength of greater than 170 kPa (25 psi) and a permeability of less than 1x10{sup -6} cm/sec. Technical oversight and on-site sampling and analysis were provided to evaluate pilot-scale application of the selected technology and verify treatment effectiveness. The project was divided into several subtasks. First, laboratory treatability testing was conducted to verify that performance specifications were achievable using the proposed reagent formulations. Next, a pilot demonstration was performed by Geo-Con using a Manotowoc 4000 crane equipped with a 1.5-meter diameter auger to evaluate shallow soil mixing. The final task included a comparative study between the performance of test specimens collected using wet sampling techniques versus in situ post-treatment coring.

  1. Major clean-up effort in the ATLAS cavern

    CERN Multimedia

    Marzio Nessi

    On Tuesday 10 October, 58 ATLAS collaborators volunteered to give a hand for a major clean-up of the ATLAS detector prior to the toroid magnet ramp-up. This special task monopolised all of the technical coordination team and eight supervisors to oversee the volunteers who were assigned to two separate five-hour shifts. The volunteers removed all sorts of loose material inside and outside the detector, focusing mainly on potentially magnetic material lost inside the detector and dirt accumulated over several months, not to mention zillions of clipped cable ties! The technical crew provided 120 garbage bags and all were used. All sorts of material that had been lost inside the detector by various people was retrieved, in particular small tools which could potentially damage the detector, as well as metallic fillings hazardous for the electronics once the magnet will be ramped up. A more detailed inspection followed for all the inside of the detector, making sure the current on the magnet could be raised to 5KA ...

  2. PRP: The Proven Solution for Cleaning Up Oil Spills

    Science.gov (United States)

    2006-01-01

    The basic technology behind PRP is thousands of microcapsules, tiny balls of beeswax with hollow centers. Water cannot penetrate the microcapsule s cell, but oil is absorbed right into the beeswax spheres as they float on the water s surface. This way, the contaminants, chemical compounds that originally come from crude oil such as fuels, motor oils, or petroleum hydrocarbons, are caught before they settle. PRP works well as a loose powder for cleaning up contaminants in lakes and other ecologically fragile areas. The powder can be spread over a contaminated body of water or soil, and it will absorb contaminants, contain them in isolation, and dispose of them safely. In water, it is important that PRP floats and keeps the oil on the surface, because, even if oil exposure is not immediately lethal, it can cause long-term harm if allowed to settle. Bottom-dwelling fish exposed to compounds released after oil spills may develop liver disease, in addition to reproductive and growth problems. This use of PRP is especially effective for environmental cleanup in sensitive areas like coral reefs and mangroves.

  3. Environmental Factor{trademark} system: Superfund site information from five EPA databases

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    1999-03-01

    Environmental Factor puts today`s technology to work to provide a better, more cost-efficient and time-saving way to access EPA information on hazardous waste sites. Environmental consultants, insurers, and reinsurers, corporate risk assessors and companies actively involved in the generation, transport, storage or cleanup of hazardous waste materials can use its user-friendly information retrieval system to gain rapid access to vital information in immediately-usable form. Search, retrieve, and export information in real time. No more waiting for the mail or overnight delivery services to deliver hard copies of voluminous listings and individual site reports. More than 200,000 pages of EPA hazardous waste site information are contained in 5 related databases: (1) Site data from the National Priority List (NPL) and CERCLIS databases, Potentially Responsible Parties (PRP) and Records of Decision (RODs) summaries; (2) Complete PRP information; (3) EPA Records of Decision (Full Text); (4) entire Civil Enforcement Docket; and (5) Glossary of EPA terms, abbreviations and acronyms. Environmental Factor`s powerful database management engine gives even the most inexperienced computer user extensive search capabilities, including wildcard, phonetic and direct cross reference searches across multiple databases.

  4. Passive Treatment And Monitoring At The Standard Mine Superfund Site, Crested Butte, CO (Presentation)

    Science.gov (United States)

    At the 2008 ASMR conference, data from the initial two months of operation of a U.S. EPA pilot biochemical reactor (BCR) was reported. The BCR was designed and constructed in August, 2007 to treat mining influenced water (MIW) emanating from an adit at a remote site in southern ...

  5. Passive Treatment And Monitoring At The Standard Mine Superfund Site, Crested Butte, CO

    Science.gov (United States)

    At the 2008 ASMR conference, data from the initial two months of operation of a U.S. EPA pilot biochemical reactor (BCR) was reported. The BCR was designed and constructed in August, 2007 to treat mining influenced water (MIW) emanating from an adit at a remote site in southern ...

  6. CHARACTERIZATION AND FATE OF PAH-CONTAMINATED SEDIMENTS AT THE WYCKOFF/EAGLE HARBOR SUPERFUND SITE

    Science.gov (United States)

    Eagle Harbor is a shallow marine embayment of Bainbridge Island, WA and formerly the site of the Wyckoff wood-treatment facility. The facility became operational in the early 1900s and used large quantities of creosote in its wood-treating processes. Creosote percolated through t...

  7. Cyclodiene insecticide, DDE, DDT, arsenic, and mercury contamination of big brown bats (Eptesicus fuscus) foraging at a Colorado Superfund site

    Science.gov (United States)

    O'Shea, T.J.; Everette, A.L.; Ellison, L.E.

    2001-01-01

    Rocky Mountain Arsenal (RMA) National Wildlife Area, near Denver, Colorado, is a Superfund site contaminated by past military and industrial uses, including pesticide manufacturing. From an ecosystem standpoint, the most critical contaminants at RMA are certain cyclodiene insecticides and metabolites, p,p???-DDE, p,p???-DDT, arsenic, and mercury. Bats are important ecosystem components that can be impacted by persistent contaminants because of their position in the food chain and their potential longevity and thus duration of exposure. Big brown bats (Eptesicus fuscus) were captured (n = 51) while foraging at RMA in the summers of 1997 and 1998 for determination of concentrations of contaminants of concern in carcasses, brains, and stomach contents. Adult females (n = 15) were also tracked by radiotelemetry to determine locations of nearest maternity roosts for sampling of guano for contaminant analysis and inspection for potential contaminant-induced mortality. Bats captured while foraging at RMA had measurable quantities of dieldrin and DDE in masticated insect samples from stomach contents and significantly higher concentrations of dieldrin, DDE, DDT, and mercury (juveniles) in carcasses than big brown bats (n = 26) sampled at a reference area 80 km to the north. Concentrations of dieldrin and DDE in brains of bats captured while foraging at RMA were also greater than in bats from the reference area, but not high enough to suggest mortality. Maximum concentrations of DDE, DDT, and cyclodienes in brains of big brown bats were found in adult males from RMA. Guano from the two closest known roosts had significantly higher concentrations of dieldrin, DDE, and mercury than guano from two roosts at the reference area. Dieldrin concentrations in carcasses of bats from RMA were highest in juveniles, followed by adult males and adult females. DDE concentrations in carcasses were lowest in adult females at both sites and highest in adult males at RMA. No contaminant

  8. Radon in Soil Gas Above Bedrock Fracture Sets at the Shepley’s Hill Superfund Site

    Energy Technology Data Exchange (ETDEWEB)

    J.R. Giles; T.L. McLing; M.V. Carpenter; C.J. Smith; W. Brandon

    2012-12-01

    The Idaho National Laboratory (INL) recently provided technical support for ongoing environmental remediation activities at the Shepley’s Hill remediation site near Devens, MA (Figure 1). The technical support was requested as follow-on work to an initial screening level radiation survey conducted in 2008. The purpose of the original study was to assess the efficacy of the INL-developed Backpack Sodium Iodide System (BaSIS) for detecting elevated areas of natural radioactivity due to the decay of radon-222 gases emanating from the underlying fracture sets. Although the results from the initial study were mixed, the BaSIS radiation surveys did confirm that exposed bedrock outcrops have higher natural radioactivity than the surficial soils, thus a high potential for detecting elevated levels of radon and/or radon daughter products. (INL 2009) The short count times associated with the BaSIS measurements limited the ability of the system to respond to elevated levels of radioactivity from a subsurface source, in this instance radon gas emanating from fracture sets. Thus, it was postulated that a different methodology be employed to directly detect the radon in the soil gases. The CR-39 particle track detectors were investigated through an extensive literature and technology search. The relatively long deployment or “detection” time of several days, as well as the sensitivity of the measurement and robustness of the detectors made the CR-39 technology promising for deployment at the Shepley’s Hill site.

  9. Using Phytoremediation to Clean Up Contamination at Military Installations

    Energy Technology Data Exchange (ETDEWEB)

    Zellmer, S.D.; Hinchman, R.R.; Negri, M.C.; Schneider, J.F. [Argonne National Lab., IL (United States); Gatliff, E.G. [Applied Natural Sciences, Inc., Fairfield, OH (United States)

    1997-07-01

    During and following World War II, wastes from the production of munitions and other military materials were disposed of using the best available practices acceptable at that time. However, these disposal methods often contaminated soil and groundwater with organic compounds and metals that require cleanup under current regulations. An emerging technology for cleaning contaminated soils and shallow groundwater is phytoremediation, an environmentally friendly, low- cost, and low-tech process. Phytoremediation encompasses all plant- influenced biological, chemical, and physical processes that aid in the uptake, degradation, and metabolism of contaminants by either plants or free-living organisms in the plant`s rhizosphere. A phytoremediation system can be viewed as a biological, solar-driven, pump-and-treat system with an extensive, self-extending uptake network (the root system) that enhances the soil and below-ground ecosystem for subsequent productive use. Argonne National Laboratory (ANL) has been conducting basic and applied research in phytoremediation since 1990. Initial greenhouse studies evaluated salt-tolerant wetland plants to clean UP and reduce the volume of salty `produced water` from petroleum wells. Results of these studies were used to design a bioreactor for processing produced water that is being demonstrated at a natural gas well in Oklahoma; this system can reduce produced water volume by about 75% in less than eight days, representing substantial savings in waste disposal cost. During 1994, ANL conducted a TNT plant uptake and in situ remediation study in a ridge-and-furrow area used for the disposal of pink water at the Joliet Army Ammunition Plant.

  10. The integration of science and politics to clean up 50 years in the nuclear sandbox

    Energy Technology Data Exchange (ETDEWEB)

    Lyons, C.E.; Holeman, T.

    1999-07-01

    The Cold War was fought between world superpowers for approximately 40 years from the end of the second World War until the end of the 1980s. During that time, the US government devoted billions of dollars to the development and production of nuclear weapons. Now the Cold War is over and the US is left with numerous nuclear weapons factories, stockpiles of nuclear materials, and mountains of waste to decontaminate and decommission. In the heat of the Cold War, little or no thought was given to how the facilities building bombs would be dismantled. Far too little attention was paid to the potential human health and environmental impact of the weapons production. Now, dozens of communities across the country face the problems this negligence created. In many cases, the location, extent, and characteristics of the waste and contamination are unknown, due to negligence or due to intentional hiding of waste and associated problems. Water supplies are contaminated and threatened; air quality is degraded and threatened; workers and residents risk contamination and health impacts; entire communities risk disaster from potential nuclear catastrophe. The US government, in the form of the US Department of Energy (DOE), now accepts responsibility for creating and cleaning up the mess. But it is the local communities, the home towns of the bomb factories and laboratories, that carry a significant share of the burden of inventing the science and politics required to clean up 50 years in the nuclear sandbox. The purpose of this paper is to evaluate the role of the local community in addressing the cleanup of the US nuclear weapons complex. Local governments do not own nor are responsible for the environmental aftermath, but remain the perpetual neighbor to the facility, the hometown of workers, and long-term caretaker of the off-site impacts of the on-site contamination and health risks.

  11. Selected Water- and Sediment-Quality, Aquatic Biology, and Mine-Waste Data from the Ely Copper Mine Superfund Site, Vershire, VT, 1998-2007

    Science.gov (United States)

    Argue, Denise M.; Kiah, Richard G.; Piatak, Nadine M.; Seal, Robert R., II; Hammarstrom, Jane M.; Hathaway, Edward; Coles, James F.

    2008-01-01

    The data contained in this report are a compilation of selected water- and sediment-quality, aquatic biology, and mine-waste data collected at the Ely Copper Mine Superfund site in Vershire, VT, from August 1998 through May 2007. The Ely Copper Mine Superfund site is in eastern, central Vermont (fig. 1) within the Vermont Copper Belt (Hammarstrom and others, 2001). The Ely Copper Mine site was placed on the U.S. Environmental Protection Agency (USEPA) National Priorities List in 2001. Previous investigations conducted at the site documented that the mine is contributing metals and highly acidic waters to local streams (Hammarstrom and others, 2001; Holmes and others, 2002; Piatak and others, 2003, 2004, and 2006). The U.S. Geological Survey (USGS), in cooperation with the USEPA, compiled selected data from previous investigations into uniform datasets that will be used to help characterize the extent of contamination at the mine. The data may be used to determine the magnitude of biological impacts from the contamination and in the development of remediation activities. This report contains analytical data for samples collected from 98 stream locations, 6 pond locations, 21 surface-water seeps, and 29 mine-waste locations. The 98 stream locations are within 3 streams and their tributaries. Ely Brook flows directly through the Ely Copper Mine then into Schoolhouse Brook (fig. 2), which joins the Ompompanoosuc River (fig. 1). The six pond locations are along Ely Brook Tributary 2 (fig. 2). The surface-water seeps and mine-waste locations are near the headwaters of Ely Brook (fig. 2 and fig. 3). The datasets 'Site_Directory' and 'Coordinates' contain specific information about each of the sample locations including stream name, number of meters from the mouth of stream, geographic coordinates, types of samples collected (matrix of sample), and the figure on which the sample location is depicted. Data have been collected at the Ely Copper Mine Superfund site by the

  12. Superfund Record of Decision (EPA Region 9): Intel Santa Clara III Superfund site, Santa Clara, CA. (First remedial action), September 1990. Final report

    Energy Technology Data Exchange (ETDEWEB)

    1990-09-20

    The Intel (Santa Clara III) site includes a plant that performs quality control testing of chemicals and electrical testing of semiconductors in Santa Clara, Santa Clara County, California. The site is in a predominantly industrial area, and overlies a major ground regional source of ground water, the Santa Clara Valley ground water basin. In 1982, the State conducted a leak detection program, which identified VOC contamination in an onsite shallow aquifer. Possible sources for the contamination may include the accidental dumping of solvents into an acid neutralization tank, accidental spills near an above-ground solvent storage facility, and cleaning of solvent-contaminated pipes during plant construction. It has been determined that no onsite source is presently contributing to ground water contamination. Since 1985, Intel has been pumping and treating ground water using granular activated carbon as an Initial Remedial Measure (IRM). The Record of Decision (ROD) addresses a final solution for restoring ground water to its beneficial use. The primary contaminants of concern affecting the ground water are VOCs including TCE.

  13. Arsenic species in weathering mine tailings and biogenic solids at the Lava Cap Mine Superfund Site, Nevada City, CA

    Directory of Open Access Journals (Sweden)

    Ashley Roger P

    2011-01-01

    Full Text Available Abstract Background A realistic estimation of the health risk of human exposure to solid-phase arsenic (As derived from historic mining operations is a major challenge to redevelopment of California's famed "Mother Lode" region. Arsenic, a known carcinogen, occurs in multiple solid forms that vary in bioaccessibility. X-ray absorption fine-structure spectroscopy (XAFS was used to identify and quantify the forms of As in mine wastes and biogenic solids at the Lava Cap Mine Superfund (LCMS site, a historic "Mother Lode" gold mine. Principal component analysis (PCA was used to assess variance within water chemistry, solids chemistry, and XAFS spectral datasets. Linear combination, least-squares fits constrained in part by PCA results were then used to quantify arsenic speciation in XAFS spectra of tailings and biogenic solids. Results The highest dissolved arsenic concentrations were found in Lost Lake porewater and in a groundwater-fed pond in the tailings deposition area. Iron, dissolved oxygen, alkalinity, specific conductivity, and As were the major variables in the water chemistry PCA. Arsenic was, on average, 14 times more concentrated in biologically-produced iron (hydroxide than in mine tailings. Phosphorous, manganese, calcium, aluminum, and As were the major variables in the solids chemistry PCA. Linear combination fits to XAFS spectra indicate that arsenopyrite (FeAsS, the dominant form of As in ore material, remains abundant (average: 65% in minimally-weathered ore samples and water-saturated tailings at the bottom of Lost Lake. However, tailings that underwent drying and wetting cycles contain an average of only 30% arsenopyrite. The predominant products of arsenopyrite weathering were identified by XAFS to be As-bearing Fe (hydroxide and arseniosiderite (Ca2Fe(AsO43O3•3H2O. Existence of the former species is not in question, but the presence of the latter species was not confirmed by additional measurements, so its identification is

  14. Long term alterations of blood plasma albumin in Chernobyl clean-up workers

    Directory of Open Access Journals (Sweden)

    Inta Kalnina

    2014-09-01

    Full Text Available Albumin is the most generously represented protein in human blood plasma. Therefore it is important to follow and assess the transport function of albumin in clinic researches. Disturbances in structural/functional properties of albumin play an important role in the pathogenesis of various diseases and immune state in patients. Changes in albumin transformation can serve as a diagnostic and prognostic criterion in pathologies. ABM (3-aminobenzanthrone derivative developed at the Daugavpils University, Latvia has been previously shown as a potential biomarker for determination of the immune state of patients with different pathologies. The aim of this study was to determine the several aspects of plasma albumin alterations in the group of Chernobyl clean-up workers in long term period in relation with humans having no professional contact with radioactivity. The following parameters were examined: (1 spectral characteristics of ABM in blood plasma; (2 and #8216;effective and #8217; and total albumin (EA and TA concentration in blood plasma; (3 quantitative parameters of albumin auto-fluorescence; (4 albumin binding site characteristics. Screening of the individuals with a period of 25-26 years after the work in Chernobyl revealed two groups of patients differing in structural and functional albumin properties; first on conformations of plasma albumin, and second characteristics of tryptophanyl region of the molecule. The revealed structural modifications of albumin are dependent on radiation-induced factors. Concomitant diseases such as diabetes mellitus or cardio-vascular diseases reinforce radiation-induced effects. In conclusion, ABM is a sensitive probe for albumin alterations and can be used to elucidate the changes in protein systems. Significant differences in albumin dynamics exist between control (donors and groups of Chernobyl clean-up workers. [J Exp Integr Med 2014; 4(3.000: 165-170

  15. Geophysical log analysis of selected test and residential wells at the Shenandoah Road National Superfund Site, East Fishkill, Dutchess County, New York

    Science.gov (United States)

    Reynolds, Richard J.; Anderson, J. Alton; Williams, John H.

    2015-01-01

    The U.S. Geological Survey collected and analyzed geophysical logs from 20 test wells and 23 residential wells at the Shenandoah Road National Superfund Site in East Fishkill, New York, from 2006 through 2010 as part of an Interagency Agreement to provide hydrogeologic technical support to the U.S. Environmental Protection Agency, Region 2. The geophysical logs collected include caliper, gamma, acoustic and optical televiewer, deviation, electromagnetic-induction, magnetic-susceptibility, fluid-property, and flow under ambient and pumped conditions. The geophysical logs were analyzed along with single-well aquifer test data and drilling logs to characterize the lithology, fabric, fractures, and flow zones penetrated by the wells. The results of the geophysical log analysis were used as part of the hydrogeologic characterization of the site and in the design of discrete-zone monitoring installations in the test wells and selected residential wells.

  16. Real-Time and Delayed Analysis of Tree and Shrub Cores as Indicators of Subsurface Volatile Organic Compound Contamination, Durham Meadows Superfund Site, Durham, Connecticut, August 29, 2006

    Science.gov (United States)

    Vroblesky, Don A.; Willey, Richard E.; Clifford, Scott; Murphy, James J.

    2008-01-01

    This study examined volatile organic compound concentrations in cores from trees and shrubs for use as indicators of vadose-zone contamination or potential vapor intrusion by volatile organic compounds into buildings at the Durham Meadows Superfund Site, Durham, Connecticut. The study used both (1) real-time tree- and shrub-core analysis, which involved field heating the core samples for 5 to 10 minutes prior to field analysis, and (2) delayed analysis, which involved allowing the gases in the cores to equilibrate with the headspace gas in the sample vials unheated for 1 to 2 days prior to analysis. General correspondence was found between the two approaches, indicating that preheating and field analysis of vegetation cores is a viable approach to real-time monitoring of subsurface volatile organic compounds. In most cases, volatile organic compounds in cores from trees and shrubs at the Merriam Manufacturing Company property showed a general correspondence to the distribution of volatile organic compounds detected in a soil-gas survey, despite the fact that most of the soil-gas survey data in close proximity to the relevant trees were collected about 3 years prior to the tree-core collection. Most of the trees cored at the Durham Meadows Superfund Site, outside of the Merriam Manufacturing Company property, contained no volatile organic compounds and were in areas where indoor air sampling and soil-gas sampling showed little or no volatile organic compound concentrations. An exception was tree DM11, which contained barely detectable concentrations of trichloroethene near a house where previous investigations found low concentrations of trichloroethene (0.13 to 1.2 parts per billion by volume) in indoor air and 7.7 micrograms per liter of trichloroethene in the ground water. The barely detectable concentration of trichloroethene in tree DM11 and the lack of volatile organic compound detection in nearby tree DM10 (adjacent to the well having 7.7 micrograms of

  17. A review of the Texas, USA San Jacinto Superfund site and the deposition of polychlorinated dibenzo-p-dioxins and dibenzofurans in the San Jacinto River and Houston Ship Channel.

    Science.gov (United States)

    Iyer, Rupa; Aggarwal, Juhi; Iken, Brian

    2016-12-01

    The San Jacinto River (SJR) waste pits that lie just under the 1-10 overpass in eastern Harris County east of Houston, Texas, USA, were created in the 1960s as dumping grounds for paper mill waste. The deposition of this waste led to accumulation of highly toxic polychlorinated dibenzo-p-dioxins and dibenzofurans (PCCDDs/PCDFs) over the course of several decades. After abandonment, the waste material eventually became submerged under the waters of the SJR, resulting in widespread environmental contamination that currently constitutes a significant health concern for eastern Harris County communities. The original waste pits were rediscovered in 2005, and the San Jacinto waste site is now a designated EPA superfund site. The objective of this review then is to discuss the history and current state of containment around the San Jacinto waste pits and analyze spatial and temporal trends in the PCDD/PCDF deposition through the SJR system from the data available. We will discuss the current exposure and health risks represented by the Superfund site and the SJR system itself, as well as the discovery of liver, kidney, brain (glioma), and retinoblastoma cancer clusters in eastern Harris County across multiple census tracts that border the Superfund site. We will also cover the two primary management options, containment versus removal of the waste from the Superfund and provide recommendations for increased monitoring of existing concentrations of polychlorinated waste in the SJR and its nearby associated communities.

  18. TREATABILITY STUDY REPORT OF GREEN MOUNTAIN LABORATORIES, INC.'S BIOREMEDIATION PROCESS, TREATMENT OF PCB CONTAMINATED SOILS, AT BEEDE WASTE OIL/CASH ENERGY SUPERFUND SITE, PLAISTOW, NEW HAMPSHIRE

    Science.gov (United States)

    In 1998, Green Mountain Laboratories, Inc. (GML) and the USEPA agreed to carry out a Superfund Innovative Technology Evaluation (SITE) project to evaluate the effectiveness of GML's Bioremediation Process for the treatment of PCB contaminated soils at the Beede Waste Oil/Cash Ene...

  19. Hanford tank clean up: A guide to understanding the technical issues

    Energy Technology Data Exchange (ETDEWEB)

    Gephart, R.E.; Lundgren, R.E.

    1995-12-31

    One of the most difficult technical challenges in cleaning up the US Department of Energy`s (DOE) Hanford Site in southeast Washington State will be to process the radioactive and chemically complex waste found in the Site`s 177 underground storage tanks. Solid, liquid, and sludge-like wastes are contained in 149 single- and 28 double-shelled steel tanks. These wastes contain about one half of the curies of radioactivity and mass of hazardous chemicals found on the Hanford Site. Therefore, Hanford cleanup means tank cleanup. Safely removing the waste from the tanks, separating radioactive elements from inert chemicals, and creating a final waste form for disposal will require the use of our nation`s best available technology coupled with scientific advances, and an extraordinary commitment by all involved. The purpose of this guide is to inform the reader about critical issues facing tank cleanup. It is written as an information resource for the general reader as well as the technically trained person wanting to gain a basic understanding about the waste in Hanford`s tanks -- how the waste was created, what is in the waste, how it is stored, and what are the key technical issues facing tank cleanup. Access to information is key to better understanding the issues and more knowledgeably participating in cleanup decisions. This guide provides such information without promoting a given cleanup approach or technology use.

  20. Post-Remediation Biomonitoring of Pesticides and Other Contaminants in Marine Waters and Sediment Near the United Heckathorn Superfund Site, Richmond, California

    Energy Technology Data Exchange (ETDEWEB)

    LD Antrim; NP Kohn

    2000-09-06

    This report, PNNL-1 3059 Rev. 1, was published in July 2000 and replaces PNNL-1 3059 which is dated October 1999. The revision corrects tissue concentration units that were reported as dry weight but were actually wet weight, and updates conclusions based on the correct reporting units. Marine sediment remediation at the United Heckathorn Superfund Site was completed in April 1997. Water and mussel tissues were sampled in February 1999 from four stations near Lauritzen Canal in Richmond, California, for Year 2 of post-remediation monitoring of marine areas near the United Heckathom Site. Dieldrin and dichlorodiphenyl trichloroethane (DDT) were analyzed in water samples, tissue samples from resident mussels, and tissue samples from transplanted mussels deployed for 4 months. Concentrations of dieldrin and total DDT in water and total DDT in tissue were compared with Year 1 of post-remediation monitoring, and with preremediation data from the California State Mussel Watch program (tissue s) and the Ecological Risk Assessment for the United Heckathorn Superfund Site (tissues and water). Mussel tissues were also analyzed for polychlorinated biphenyls (PCB), which were detected in sediment samples. Chlorinated pesticide concentrations in water samples were similar to preremediation levels and did not meet remediation goals. Mean dieldrin concentrations in water ranged from 0.62 ng/L to 12.5 ng/L and were higher than the remediation goal (0.14 ng/L) at all stations. Mean total DDT concentrations in water ranged from 14.4 ng/L to 62.3 ng/L and exceeded the remediation goal (0.59 ng/L) at all stations. The highest concentrations of both DDT and dieldrin were found at the Lauritzen Canal/End station. Despite exceedence of the remediation goals, chlorinated pesticide concentrations in Lauritzen Canal water samples were notably lower in 1999 than in 1998. PCBS were not detected in water samples in 1999.

  1. Investigations of groundwater system and simulation of regional groundwater flow for North Penn Area 7 Superfund site, Montgomery County, Pennsylvania

    Science.gov (United States)

    Senior, Lisa A.; Goode, Daniel J.

    2013-01-01

    Groundwater in the vicinity of several industrial facilities in Upper Gwynedd Township and vicinity, Montgomery County, in southeast Pennsylvania has been shown to be contaminated with volatile organic compounds (VOCs), the most common of which is the solvent trichloroethylene (TCE). The 2-square-mile area was placed on the National Priorities List as the North Penn Area 7 Superfund site by the U.S. Environmental Protection Agency (USEPA) in 1989. The U.S. Geological Survey (USGS) conducted geophysical logging, aquifer testing, and water-level monitoring, and measured streamflows in and near North Penn Area 7 from fall 2000 through fall 2006 in a technical assistance study for the USEPA to develop an understanding of the hydrogeologic framework in the area as part of the USEPA Remedial Investigation. In addition, the USGS developed a groundwater-flow computer model based on the hydrogeologic framework to simulate regional groundwater flow and to estimate directions of groundwater flow and pathways of groundwater contaminants. The study area is underlain by Triassic- and Jurassic-age sandstones and shales of the Lockatong Formation and Brunswick Group in the Mesozoic Newark Basin. Regionally, these rocks strike northeast and dip to the northwest. The sequence of rocks form a fractured-sedimentary-rock aquifer that acts as a set of confined to partially confined layers of differing permeabilities. Depth to competent bedrock typically is less than 20 ft below land surface. The aquifer layers are recharged locally by precipitation and discharge locally to streams. The general configuration of the potentiometric surface in the aquifer is similar to topography, except in areas affected by pumping. The headwaters of Wissahickon Creek are nearby, and the stream flows southwest, parallel to strike, to bisect North Penn Area 7. Groundwater is pumped in the vicinity of North Penn Area 7 for industrial use, public supply, and residential supply. Results of field investigations

  2. Treatability Study of In Situ Technologies for Remediation of Hexavalent Chromium in Groundwater at the Puchack Well Field Superfund Site, New Jersey

    Energy Technology Data Exchange (ETDEWEB)

    Vermeul, Vince R.; Szecsody, Jim E.; Truex, Michael J.; Burns, Carolyn A.; Girvin, Donald C.; Phillips, Jerry L.; Devary, Brooks J.; Fischer, Ashley E.; Li, Shu-Mei W.

    2006-11-13

    This treatability study was conducted by Pacific Northwest National Laboratory (PNNL), at the request of the U. S. Environmental Protection Agency (EPA) Region 2, to evaluate the feasibility of using in situ treatment technologies for chromate reduction and immobilization at the Puchack Well Field Superfund Site in Pennsauken Township, New Jersey. In addition to in situ reductive treatments, which included the evaluation of both abiotic and biotic reduction of Puchack aquifer sediments, natural attenuation mechanisms were evaluated (i.e., chromate adsorption and reduction). Chromate exhibited typical anionic adsorption behavior, with greater adsorption at lower pH, at lower chromate concentration, and at lower concentrations of other competing anions. In particular, sulfate (at 50 mg/L) suppressed chromate adsorption by up to 50%. Chromate adsorption was not influenced by inorganic colloids.

  3. Renewable Natural Gas Clean-up Challenges and Applications

    Science.gov (United States)

    2011-01-13

    removed including CO, CO2,CH4) Illustrative Process Flow Diagram for On-site H2 Supply System & SOFC Power Generation...day 1.5 to SOFC ) 13.2 scfm . 8.0 scfm Flow rate: ~ 2.9 scfm ( PSA: ~ 31.7scfm) Usable Heat Electricity 2 CO: ~0.5% H2: ~73.5 Total Flow...34.6 scfm SOFC : 17 t 18 Example Gas Cl eanup Sys em for WWDG > Configured a gas cleanup system utilizing a membrane module for CO

  4. PCBs and DDE in tree swallow (Tachycineta bicolor) eggs and nestlings from an estuarine PCB superfund site, New Bedford Harbor, MA, U.S.A.

    Science.gov (United States)

    Jayaraman, Saro; Nacci, Diane E.; Champlin, Denise M.; Pruell, Richard J.; Rocha, Kenneth J.; Custer, Christine M.; Custer, Thomas W.; Cantwell, Mark

    2009-01-01

    While breeding tree swallows (Tachycineta bicolor) have been used as biomonitors for freshwater sites, we report the first use of this species to assess contaminant bioaccumulation from estuarine breeding grounds into these aerial insectivores. Eggs and nestlings were collected from nest boxes in a polychlorinated biphenyl (PCB) contaminated estuary, the New Bedford Harbor Superfund site (NBH, Massachusetts, USA), and a reference salt marsh, Fox Hill (FH, Jamestown, Rhode Island, USA). Sediments, eggs, and nestlings were compared on a ng g−1 wet weight basis for total PCBs and DDE (1,1-bis-(4-chlorophenyl)-2,2-dichloroethene), metabolite of DDT (1,1,1-trichloro-2,2-bis-(p-chlorophenyl)ethane). NBH samples contained high concentrations of PCBs compared to FH for sediment (36,500 and 0.2), eggs (11,200 and 323), and nestlings (16,800 and 26). PCB homologue patterns linked tree swallow contamination to NBH sediment. NBH samples were also contaminated with DDE compared to FH for sediment (207 and 0.9) and nestlings (235 and 30) but not for eggs (526 and 488), suggesting both NBH and nonbreeding ground sources for DDE. The relationships between sediment and tree swallow egg and nestling PCBs were similar to those reported for freshwater sites. Like some highly contaminated freshwater sites, NBH PCB bioaccumulation had little apparent effect on reproductive success.

  5. Identification of potential water-bearing zones by the use of borehole geophysics in the vicinity of Keystone Sanitation Superfund Site, Adams County, Pennsylvania and Carroll County, Maryland

    Science.gov (United States)

    Conger, Randall W.

    1997-01-01

    Between April 23, 1996, and June 21, 1996, the U.S. Environmental Protection Agency contracted Haliburton-NUS, Inc., to drill four clusters of three monitoring wells near the Keystone Sanitation Superfund Site. The purpose of the wells is to allow monitoring and sampling of shallow, intermediate, and deep waterbearing zones for the purpose of determining the horizontal and vertical distribution of any contaminated ground water migrating from the Keystone Site. Twelve monitoring wells, ranging in depth from 50 to 397.9 feet below land surface, were drilled in the vicinity of the Keystone Site. The U.S. Geological Survey conducted borehole-geophysical logging and determined, with geophysical logs and other available data, the ideal intervals to be screened in each well. Geophysical logs were run on four intermediate and four deep wells, and a caliper log only was run on shallow well CL-AD-173 (HN-1S). Interpretation of geophysical logs and existing data determined the placement of screens within each borehole.

  6. Cleaning up

    DEFF Research Database (Denmark)

    Thomsen, Michael Kirkedal; Axelsen, Holger Bock; Glück, Robert

    2013-01-01

    Reversible logic is a computational model that ensure that no values are discarded or duplicated. This gives the connection to Landauer’s principle if and only if the underlying circuits are garbage-free. This paper shows how to describe and implement garbage-free reversible logic circuits...... in an easy and concise way. We use two domain-specific languages that are designed to describe reversible logic at different levels and garbage-free methods to translate between these. This approach relies heavily on programming language technology that is known and used for conventional functional languages....... Though the languages ensure reversibility of the logic descriptions, they are not guaranteed to be garbage- free. It is still an important task for the designer to find the correct embeddings....

  7. Evaluation of geophysical logs and slug tests, phase II, at AIW Frank/Mid-County Mustang Superfund Site, Chester County, Pennsylvania

    Science.gov (United States)

    Conger, R.W.; Goode, D.J.; Sloto, R.A.

    2000-01-01

    Between September 1997 and October 1998, nine monitor wells were drilled at the AIW Frank/Mid-County Mustang Superfund Site in Chester County, Pa., to determine the horizontal and vertical distribution of contaminated ground water migrating from known contaminant sources. The U.S. Geological Survey conducted borehole geophysical logging and borehole television surveys in these boreholes to identify water-producing zones so that appropriate intervals could be screened in each borehole. Caliper logs and borehole television surveys were used to locate fractures; inflections on fluid-temperature and fluid-resistivity logs were used to locate possible water-bearing fractures, and heatpulseflowmeter measurements verified these locations. The borehole television surveys indicated that locally, the rocks of the Conestoga Limestone and Ledger Dolomite that underlie the site strike generally from northeast-southwest to east-west and dip steeply to the southeast and south approximately 63? to 76?. Slug tests were conducted at six boreholes to estimate transmissivity. Transmissivity from slug tests ranged from 21 feet squared per day in borehole CH-5669 to greater than 12,000 feet squared per day in boreholes CH-5665 and CH-5667. After interpretation of geophysical logs, borehole television surveys, and driller's logs, all boreholes were screened such that water-level fluctuations could be monitored and discrete water samples collected from one or more water-producing zones in each borehole.

  8. POST-REMEDIATION BIOMONITORING OF PESTICIDES AND OTHER CONTAMINANTS IN MARINE WATERS AND SEDIMENT NEAR THE UNITED HECKATHORN SUPERFUND SITE, RICHMOND, CALIFORNIA

    Energy Technology Data Exchange (ETDEWEB)

    Antrim, Liam D.; Kohn, Nancy P.

    2000-09-06

    Marine sediment remediation at the United Heckathorn Superfund Site was completed in April 1997. Water and mussel tissues were sampled in February 1999 from four stations near Lauritzen Canal in Richmond, California, for Year 2 of post-remediation monitoring of marine areas near the United Heckathorn Site. Dieldrin and dichlorodiphenyl trichloroethane (DDT) were analyzed in water samples, tissue samples from resident mussels, and tissue samples from transplanted mussels deployed for 4 months. Mussel tissues were also analyzed for polychlorinated biphenyls (PCB), which were detected in sediment samples. Chlorinated pesticide concentrations in water samples were similar to preremediation levels and did not meet remediation goals. Biomonitoring results indicated that the bioavailability of chlorinated pesticides has been reduced from preremediation levels both in the dredged area and throughout Richmond Harbor. Total DDT and dieldrin concentrations in mussel tissues were lower than measured levels from preremediation surveys and also lower than Year 1 levels from post-remediation biomonitoring. Sediment analyses showed the presence of elevated DDT, dieldrin, PCB aroclor 1254, and very high levels of polynuclear aromatic hydrocarbons (PAH) in Lauritzen Channel.

  9. Clean-up and disposal process of polluted sediments from urban rivers

    Institute of Scientific and Technical Information of China (English)

    2001-01-01

    In this paper, the discussion is concentrated on the properties of the polluted sediments and the combination of clean-up and disposal process for the upper layer heavily polluted sediments with good flowability. Based on the systematic analyses of various clean-up processes, a suitable engineering process has been evaluated and recommended. The process has been applied to the river reclamation in Yangpu District of Shanghai metropolis. An improved centrifuge is used for dewatering the dredged sludge,which plays an important role in the combination of clean-up and disposal process. The assessment of the engineering process shows its environmental and technical economy feasibility, which is much better than that of traditional dredging-disposal processes.

  10. Radiochemical Analyses of the Filter Cake, Granular Activated Carbon, and Treated Ground Water from the DTSC Stringfellow Superfund Site Pretreatment Plant

    Energy Technology Data Exchange (ETDEWEB)

    Esser, B K; McConachie, W; Fischer, R; Sutton, M; Szechenyi, S

    2005-09-16

    The Department of Toxic Substance Control (DTSC) requested that Lawrence Livermore National Laboratory (LLNL) evaluate the treatment process currently employed at the Department's Stringfellow Superfund Site Pretreatment Plant (PTP) site to determine if wastes originating from the site were properly managed with regards to their radioactivity. In order to evaluate the current management strategy, LLNL suggested that DTSC characterize the effluents from the waste treatment system for radionuclide content. A sampling plan was developed; samples were collected and analyzed for radioactive constituents. Following is brief summary of those results and what implications for waste characterization may be made. (1) The sampling and analysis provides strong evidence that the radionuclides present are Naturally Occurring Radioactive Material (NORM). (2) The greatest source of radioactivity in the samples was naturally occurring uranium. The sample results indicate that the uranium concentration in the filter cake is higher than the Granular Activated Carbon (GAC) samples. (11 -14 and 2-6 ppm respectively). (3) No radiologic background for geologic materials has been established for the Stringfellow site, and comprehensive testing of the process stream has not been conducted. Without site-specific testing of geologic materials and waste process streams, it is not possible to conclude if filter cake and spent GAC samples contain radioactivity concentrated above natural background levels, or if radionuclides are being concentrated by the waste treatment process. Recommendation: The regulation of Technologically Enhanced, Naturally Occurring Radioactive Materials (T-NORM) is complex. Since the results of this study do not conclusively demonstrate that natural radioactive materials have not been concentrated by the treatment process it is recommended that the DTSC consult with the Department of Health Services (DHS) Radiological Health Branch to determine if any further

  11. Microbial Diversity and Metal Speciation Changes in Mine Tailings Following Compost-Assisted Direct Planting: A Four-Year Superfund Site Field Study

    Science.gov (United States)

    Maier, R. M.; Gil-Loaiza, J.; Honeker, L. K.; Hottenstein, J. D.; Valentin-Vargas, A.; Jennings, L. L.; Hammond, C.; Neilson, J. W.; Root, R. A.; Chorover, J.

    2015-12-01

    EPA estimates that future mine tailings remediation costs will exceed US $50 billion using present technologies based on constructing an inert or biological cap on the tailings. Both approaches require large amounts of capping materials that can be difficult and expensive to obtain especially for sites several thousand hectares in size. An alternative technology is direct planting into tailings. However, direct planting alone is not feasible for many legacy sites due to extreme acidity and high metal content which prevent plant germination and growth. Therefore the process must be "assisted" through the addition of amendments such as compost. Here we present results from the first four years of a field study at the Iron King Mine and Humboldt Smelter Superfund site demonstrating the feasibility of compost-assisted direct planting. Parameters measured during the field study included: canopy cover, pH, nutrient content, plant metal uptake, metal(loid) speciation, mineral analysis, microbiome analysis, and plant root-metal-microbe interactions. Integrated analysis of these parameters suggests that even in this "worst-case scenario" mine tailings site (pH 2.5; As and Pb each exceeding 2 g kg-1), we have created a sustainable system. In this system, phyto-catalyzed stabilization of inorganic contaminants in the root zone is driven by plant root exudates and the associated rhizosphere microbial community. The results of this research will be put into context of a larger topic- that of ecological engineering of mine tailings sites - a technique being proposed to prevent creation of acidic conditions and metal(loid) mobilization in the first place.

  12. The mental health of clean-up workers 18 years after the Chernobyl accident.

    Science.gov (United States)

    Loganovsky, K; Havenaar, J M; Tintle, N L; Guey, L T; Kotov, R; Bromet, E J

    2008-04-01

    The psychological aftermath of the Chernobyl accident is regarded as the largest public health problem unleashed by the accident to date. Yet the mental health of the clean-up workers, who faced the greatest radiation exposure and threat to life, has not been systematically evaluated. This study describes the long-term psychological effects of Chernobyl in a sample of clean-up workers in Ukraine. The cohorts were 295 male clean-up workers sent to Chernobyl between 1986 and 1990 interviewed 18 years after the accident (71% participation rate) and 397 geographically matched controls interviewed as part of the Ukraine World Mental Health (WMS) Survey 16 years after the accident. The World Health Organization (WHO) Composite International Diagnostic Interview (CIDI) was administered. We examined group differences in common psychiatric disorders, suicide ideation and severe headaches, differential effects of disorder on days lost from work, and in the clean-up workers, the relationship of exposure severity to disorder and current trauma and somatic symptoms. Analyses were adjusted for age in 1986 and mental health prior to the accident. Relatively more clean-up workers than controls experienced depression (18.0% v. 13.1%) and suicide ideation (9.2% v. 4.1%) after the accident. In the year preceding interview, the rates of depression (14.9% v. 7.1%), post-traumatic stress disorder (PTSD) (4.1% v. 1.0%) and headaches (69.2% v. 12.4%) were elevated. Affected workers lost more work days than affected controls. Exposure level was associated with current somatic and PTSD symptom severity. Long-term mental health consequences of Chernobyl were observed in clean-up workers.

  13. Dyscirculatory encephalopathy in Chernobyl disaster clean-up workers (a 20-year study).

    Science.gov (United States)

    Podsonnaya, I V; Shumakher, G I; Golovin, V A

    2010-05-01

    Results obtained over 20-years of following 536 Chernobyl clean-up workers and 436 control subjects are presented. Dyscirculatory encephalopathy developed more frequently in persons exposed to radiation at age 30 years. As compared with the control group, workers were characterized by early onset of disease, faster progression, stable symptomatology for 5-6 years, and further progression of disease in the form of autonomic dysfunction, psycho-organic syndrome, and epilepsy. Major strokes were also more common in clean-up workers.

  14. Data clean-up and management a practical guide for librarians

    CERN Document Server

    Hogarth, Margaret

    2012-01-01

    Data use in the library has specific characteristics and common problems. Data Clean-up and Management addresses these, and provides methods to clean up frequently-occurring data problems using readily-available applications. The authors highlight the importance and methods of data analysis and presentation, and offer guidelines and recommendations for a data quality policy. The book gives step-by-step how-to directions for common dirty data issues.focused towards libraries and practicing librariansdeals with practical, real-life issues and addresses common problems that all libraries faceoffe

  15. Evaluation of geophysical logs and video surveys in boreholes adjacent to the Berkley Products Superfund Site, West Cocalico Township, Lancaster County, Pennsylvania

    Science.gov (United States)

    Low, Dennis J.; Conger, Randall W.

    1998-01-01

    Between February 1998 and April 1998, geophysical logs were collected in nine boreholes adjacent to the Berkley Products Superfund Site, West Cocalico Township, Lancaster County, Pa. Video surveys were conducted on four of the nine boreholes. The boreholes range in depth from 320 to 508 feet below land surface, are completed open holes, have ambient vertical flow of water, and penetrate a series of interbedded siltstone, sandstone, and conglomerate units. The purpose of collecting geophysical-log data was to help determine horizontal and vertical distribution of contaminated ground water migrating from known or suspected sources and to aid in the placement of permanent borehole packers. The primary contaminants were derived from paint waste that included pigment sludges and wash solvents. The chlorinated volatile organic compounds probably originated from the wash solvents. Caliper logs and video surveys were used to locate fractures; inflections on fluid-resistivity and fluid-temperature logs were used to locate possible water-bearing fractures. Heatpulse-flowmeter measurements were used to verify the locations of water-producing or water-receiving zones and to measure rates of flow between water-bearing fractures. Single-point-resistance and natural-gamma logs provided information on stratigraphy. After interpretation of geophysical logs, video surveys, and driller's logs, permanent multiple-packer systems were installed in each borehole to obtain depth specific water samples from one or more water-bearing fractures in each borehole.

  16. Time series geophysical monitoring of permanganate injections and in situ chemical oxidation of PCE, OU1 area, Savage Superfund Site, Milford, NH, USA.

    Science.gov (United States)

    Harte, Philip T; Smith, Thor E; Williams, John H; Degnan, James R

    2012-05-01

    In situ chemical oxidation (ISCO) treatment with sodium permanganate, an electrically conductive oxidant, provides a strong electrical signal for tracking of injectate transport using time series geophysical surveys including direct current (DC) resistivity and electromagnetic (EM) methods. Effective remediation is dependent upon placing the oxidant in close contact with the contaminated aquifer. Therefore, monitoring tools that provide enhanced tracking capability of the injectate offer considerable benefit to guide subsequent ISCO injections. Time-series geophysical surveys were performed at a superfund site in New Hampshire, USA over a one-year period to identify temporal changes in the bulk electrical conductivity of a tetrachloroethylene (PCE; also called tetrachloroethene) contaminated, glacially deposited aquifer due to the injection of sodium permanganate. The ISCO treatment involved a series of pulse injections of sodium permanganate from multiple injection wells within a contained area of the aquifer. After the initial injection, the permanganate was allowed to disperse under ambient groundwater velocities. Time series geophysical surveys identified the downward sinking and pooling of the sodium permanganate atop of the underlying till or bedrock surface caused by density-driven flow, and the limited horizontal spread of the sodium permanganate in the shallow parts of the aquifer during this injection period. When coupled with conventional monitoring, the surveys allowed for an assessment of ISCO treatment effectiveness in targeting the PCE plume and helped target areas for subsequent treatment.

  17. Occurrences and fate of DDT principal isomers/metabolites, DDA, and o,p'-DDD enantiomers in fish, sediment and water at a DDT-impacted Superfund site.

    Science.gov (United States)

    Garrison, A W; Cyterski, M; Roberts, K D; Burdette, D; Williamson, J; Avants, J K

    2014-11-01

    In the 1950s and 60s, discharges from a DDT manufacturing plant contaminated a tributary system of the Tennessee River near Huntsville, Alabama, USA. Regulatory action resulted in declaring the area a Superfund site which required remediation and extensive monitoring. Monitoring data collected from 1988, after remediation, through 2011 showed annual decreases approximating first-order decay in concentrations of total DDT and its six principal congeners (p,p'-DDT, o,p'-DDT, p,p'-DDD, o,p'-DDD, p,p'-DDE and o,p'-DDE) in filets from three species of fish. As of 2013, these concentrations met the regulatory requirements of 5 mg/kg or less total DDT for each fish tested. The enantiomer fractions (EF) of chiral o,p'-DDD in smallmouth buffalo and channel catfish were always below 0.5, indicating preferential decay of the (+)-enantiomer of this congener; this EF did not change significantly over 15 years. The often-neglected DDT metabolite p,p'-DDA was found at a concentration of about 20 μg/l in the ecosystem water.

  18. Geophysical Logs, Specific Capacity, and Water Quality of Four Wells at Rogers Mechanical (former Tate Andale) Property, North Penn Area 6 Superfund Site, Lansdale, Pennsylvania, 2006-07

    Science.gov (United States)

    Senior, Lisa A.; Bird, Philip H.

    2010-01-01

    As part of technical assistance to the U.S. Environmental Protection Agency (USEPA) in the remediation of properties on the North Penn Area 6 Superfund Site in Lansdale, Pa., the U.S. Geological Survey (USGS) in 2006-07 collected data in four monitor wells at the Rogers Mechanical (former Tate Andale) property. During this period, USGS collected and analyzed borehole geophysical and video logs of three new monitor wells (Rogers 4, Rogers 5, and Rogers 6) ranging in depth from 80 to 180 feet, a borehole video log and additional heatpulse-flowmeter measurements (to quantify vertical borehole flow) in one existing 100-foot deep well (Rogers 3S), and water-level data during development of two wells (Rogers 5 and Rogers 6) to determine specific capacity. USGS also summarized results of passive-diffusion bag sampling for volatile organic compounds (VOCs) in the four wells. These data were intended to help understand the groundwater system and the distribution of VOC contaminants in groundwater at the property.

  19. Time series geophysical monitoring of permanganate injections and in situ chemical oxidation of PCE, OU1 area, Savage Superfund Site, Milford, NH, USA

    Science.gov (United States)

    Harte, Philip T.; Smith, Thor E.; Williams, John H.; Degnan, James R.

    2012-05-01

    In situ chemical oxidation (ISCO) treatment with sodium permanganate, an electrically conductive oxidant, provides a strong electrical signal for tracking of injectate transport using time series geophysical surveys including direct current (DC) resistivity and electromagnetic (EM) methods. Effective remediation is dependent upon placing the oxidant in close contact with the contaminated aquifer. Therefore, monitoring tools that provide enhanced tracking capability of the injectate offer considerable benefit to guide subsequent ISCO injections. Time-series geophysical surveys were performed at a superfund site in New Hampshire, USA over a one-year period to identify temporal changes in the bulk electrical conductivity of a tetrachloroethylene (PCE; also called tetrachloroethene) contaminated, glacially deposited aquifer due to the injection of sodium permanganate. The ISCO treatment involved a series of pulse injections of sodium permanganate from multiple injection wells within a contained area of the aquifer. After the initial injection, the permanganate was allowed to disperse under ambient groundwater velocities. Time series geophysical surveys identified the downward sinking and pooling of the sodium permanganate atop of the underlying till or bedrock surface caused by density-driven flow, and the limited horizontal spread of the sodium permanganate in the shallow parts of the aquifer during this injection period. When coupled with conventional monitoring, the surveys allowed for an assessment of ISCO treatment effectiveness in targeting the PCE plume and helped target areas for subsequent treatment.

  20. From conceptual model to remediation: bioavailability, a key to clean up heavy metal contaminated soils.

    Science.gov (United States)

    Petruzzelli, Gianniantonio; Pedron, Francesca; Pezzarossa, Beatrice

    2013-04-01

    Processes of metal bioavailability in the soil To know the bioavailability processes at site specific levels is essential to understand in detail the risks associated with pollution, and to support the decision-making process, i.e. description of the conceptual model and choice of clean up technologies. It is particularly important to assess how chemical, physical and biological processes in the soil affect the reactions leading to adsorption, precipitation or release of contaminants. The measurement of bioavailability One of the main difficulties in the practical application of the bioavailability concept in soil remediation is the lack of consensus on the method to be used to measure bioavailability. The best strategy is to apply a series of tests to assess bioavailability, since no applicable method is universally valid under all conditions. As an example, bioavailability tests for phytotechnology application should consider two distinct aspects: a physico-chemical driven solubilization process and a physiologically driven uptake process. Soil and plant characteristics strongly influence bioavailability. Bioavailability as a tool in remediation strategies Bioavailability can be used at all stages in remediation strategies: development of the conceptual model, evaluation of risk assessment, and selection of the best technology, considering different scenarios and including different environmental objectives. Two different strategies can be followed: the reduction and the increase of bioavailability. Procedures that reduce bioavailability aim to prevent the movement of pollutants from the soil to the living organisms, essentially by: i) removal of the labile phase of the contaminant, i.e. the fraction which is intrinsic to the processes of bioavailability (phytostabilization); ii) conversion of the labile fraction into a stable fraction (precipitation or adsorption); iii) increase of the resistance to mass transfer of the contaminants (inertization). Procedures

  1. Case Study: Using Microbe Molecular Biology for Gulf Oil Spill Clean Up

    Science.gov (United States)

    Jones, Daniel R.

    2011-01-01

    This case has the student actively investigate the regulation of expression of a novel bacterial gene in the context of attempts to solve a real world problem, clean up of the April 2010 Deep Water Horizon oil spill in the Gulf of Mexico. Although the case is fictitious, it is based on factual gene regulatory characteristics of oil-degrading…

  2. An alternative clean-up column for the determination of polychlorinated biphenyls in solid matrices.

    Science.gov (United States)

    Ndunda, Elizabeth N; Madadi, Vincent O; Mizaikoff, Boris

    2015-12-01

    The need for continuous monitoring of polychlorinated biphenyls (PCBs) has necessitated the development of analytical techniques that are sensitive and selective with minimal reagent requirement. In light of this, we developed a column for clean-up of soil and sediment extracts, which is less demanding in terms of the amount of solvent and sorbent. The dual-layer column consists of acidified silica gel and molecularly imprinted polymers (MIPs). MIPs were synthesized via aqueous suspension polymerization using PCB 15 as the dummy template, 4-vinylpyridine as the functional monomer and ethylene glycol dimethacrylate as the cross-linker and the obtained particles characterized via SEM, BET, and batch rebinding assays. Pre-concentration of the spiked real-world water sample using MISPE gave recoveries between 85.2 and 104.4% (RSD clean-up of extracts from complex matrices provided recoveries of 91.6-102.5% (RSD clean-up using acidified silica (70.4-90.5%; RSD clean-up procedure for continuous monitoring of PCBs. Method detection limits were 0.01-0.08 ng g(-1) and 0.002-0.01 ng mL(-1) for solid matrices and water, respectively.

  3. Refractive properties of separate erythrocytes of Chernobyl clean-up workers at different pH

    Science.gov (United States)

    Mazarevica, Gunta; Freivalds, Talivaldis; Bruvere, Ruta; Gabruseva, Natalija; Leice, Alevtine; Zvagule, Tija

    2000-04-01

    This study is focused on the modifications in erythrocytes of Chernobyl nuclear power plant accident clean-up workers as a late health effect of short-term impact of high level radioactive contamination. As a result, a new method based on erythrocyte refractive index properties at different pH has been elaborated.

  4. Improving the Quality of Conforming Triangular Meshes by Topological Clean up and DSI

    Institute of Scientific and Technical Information of China (English)

    MENGXian-hai; YANGQin; LIJl-gang; CHENQi-ming

    2004-01-01

    A new method as a post-processing step is presented to improve the shape quality of triangular meshes, which uses a topological clean up procedure and discrete smoothing interpolate (DSI) algorithm together. This method can improve the angle distribution of mesh element, while keeping the resulting meshes conform to the predefined constraints which are inputted as a PSLG.

  5. Clean Up, Rehabilitation, Resettlement of Enewetak Atoll -Marshall Islands. Volume III.

    Science.gov (United States)

    The documentation is a summary of the Draft Environmental Impact Statement (DEIS) for a proposed project to clean up the Atoll of Enewetak and...resettle the Enewetak people on the Atoll . The summary has been prepared specifically for translation into the language of the Enewetak people.

  6. PCR inhibitor removal using the NucleoSpin® DNA Clean-Up XS kit.

    Science.gov (United States)

    Faber, Korie L; Person, Eric C; Hudlow, William R

    2013-01-01

    Forensic evidence samples are collected from an unlimited variety of substrates, which may contain compounds known to inhibit the polymerase chain reaction (PCR). These PCR inhibitors are co-extracted with the DNA sample and can negatively affect the DNA typing results, which can range from partial to complete inhibition of the short tandem repeat (STR) PCR. One potential solution is to remove the PCR inhibitors from the extracts prior to the STR PCR with the NucleoSpin(®) DNA Clean-Up XS kit. The kit contains a NucleoSpin(®) XS silica column that has a special funnel design of thrust rings along with a very small silica membrane, which allows for sample elution in a small volume that is appropriate for use with current STR typing kits. The NucleoSpin(®) DNA Clean-Up XS kit was optimized for the best possible DNA recovery and then evaluated for its ability to remove eight commonly encountered PCR inhibitors including: bile salt, collagen, hematin, humic acid, indigo, melanin, tannic acid and urea. Each of these PCR inhibitors was effectively removed by the NucleoSpin(®) DNA Clean-Up XS kit as demonstrated by generating more complete STR profiles from the cleaned up inhibitor samples than from the raw inhibitor samples. Copyright © 2012 Elsevier Ireland Ltd. All rights reserved.

  7. Proposals for intervention values for soil clean-up: Second series of chemicals

    NARCIS (Netherlands)

    Berg R van den; Bockting GJM; Crommentuijn GH; Jansen PJCM; LBG

    1994-01-01

    The thoroughly revised intervention values for soil clean-up have recently come into force. In this report, proposals will be presented for intervention values for other chemicals on the basis of an ecotoxicological and a human-toxicological evaluation. The proposals made have followed the procedure

  8. Efficiency of different protocols for enamel clean-up after bracket debonding: an in vitro study

    Science.gov (United States)

    Sigilião, Lara Carvalho Freitas; Marquezan, Mariana; Elias, Carlos Nelson; Ruellas, Antônio Carlos; Sant'Anna, Eduardo Franzotti

    2015-01-01

    Objective: This study aimed to assess the efficiency of six protocols for cleaning-up tooth enamel after bracket debonding. Methods: A total of 60 premolars were divided into six groups, according to the tools used for clean-up: 12-blade bur at low speed (G12L), 12-blade bur at high speed (G12H), 30-blade bur at low speed (G30L), DU10CO ORTHO polisher (GDU), Renew System (GR) and Diagloss polisher (GD). Mean roughness (Ra) and mean roughness depth (Rz) of enamel surface were analyzed with a profilometer. Paired t-test was used to assess Ra and Rz before and after enamel clean-up. ANOVA/Tukey tests were used for intergroup comparison. The duration of removal procedures was recorded. The association between time and variation in enamel roughness (∆Ra, ∆Rz) were evaluated by Pearson's correlation test. Enamel topography was assessed by scanning electron microscopy (SEM). Results: In Groups G12L and G12H, original enamel roughness did not change significantly. In Groups G30L, GDU, GR and GD, a smoother surface (p < 0.05) was found after clean-up. In Groups G30L and GD, the protocols used were more time-consuming than those used in the other groups. Negative and moderate correlation was observed between time and (∆Ra, ∆Rz); Ra and (∆Ra, ∆Rz); Rz (r = - 0.445, r = - 0.475, p < 0.01). Conclusion: All enamel clean-up protocols were efficient because they did not result in increased surface roughness. The longer the time spent performing the protocol, the lower the surface roughness. PMID:26560825

  9. Efficiency of different protocols for enamel clean-up after bracket debonding: an in vitro study

    Directory of Open Access Journals (Sweden)

    Lara Carvalho Freitas Sigilião

    2015-10-01

    Full Text Available Objective: This study aimed to assess the efficiency of six protocols for cleaning-up tooth enamel after bracket debonding.Methods:A total of 60 premolars were divided into six groups, according to the tools used for clean-up: 12-blade bur at low speed (G12L, 12-blade bur at high speed (G12H, 30-blade bur at low speed (G30L, DU10CO ORTHO polisher (GDU, Renew System (GR and Diagloss polisher (GD. Mean roughness (Ra and mean roughness depth (Rz of enamel surface were analyzed with a profilometer. Paired t-test was used to assess Ra and Rz before and after enamel clean-up. ANOVA/Tukey tests were used for intergroup comparison. The duration of removal procedures was recorded. The association between time and variation in enamel roughness (∆Ra, ∆Rz were evaluated by Pearson's correlation test. Enamel topography was assessed by scanning electron microscopy (SEM.Results:In Groups G12L and G12H, original enamel roughness did not change significantly. In Groups G30L, GDU, GR and GD, a smoother surface (p < 0.05 was found after clean-up. In Groups G30L and GD, the protocols used were more time-consuming than those used in the other groups. Negative and moderate correlation was observed between time and (∆Ra, ∆Rz; Ra and (∆Ra, ∆Rz; Rz (r = - 0.445, r = - 0.475, p < 0.01.Conclusion:All enamel clean-up protocols were efficient because they did not result in increased surface roughness. The longer the time spent performing the protocol, the lower the surface roughness.

  10. Transcriptomic assessment of resistance to effects of an aryl hydrocarbon receptor (AHR agonist in embryos of Atlantic killifish (Fundulus heteroclitus from a marine Superfund site

    Directory of Open Access Journals (Sweden)

    Franks Diana G

    2011-05-01

    Full Text Available Abstract Background Populations of Atlantic killifish (Fundulus heteroclitus have evolved resistance to the embryotoxic effects of polychlorinated biphenyls (PCBs and other halogenated and nonhalogenated aromatic hydrocarbons that act through an aryl hydrocarbon receptor (AHR-dependent signaling pathway. The resistance is accompanied by reduced sensitivity to induction of cytochrome P450 1A (CYP1A, a widely used biomarker of aromatic hydrocarbon exposure and effect, but whether the reduced sensitivity is specific to CYP1A or reflects a genome-wide reduction in responsiveness to all AHR-mediated changes in gene expression is unknown. We compared gene expression profiles and the response to 3,3',4,4',5-pentachlorobiphenyl (PCB-126 exposure in embryos (5 and 10 dpf and larvae (15 dpf from F. heteroclitus populations inhabiting the New Bedford Harbor, Massachusetts (NBH Superfund site (PCB-resistant and a reference site, Scorton Creek, Massachusetts (SC; PCB-sensitive. Results Analysis using a 7,000-gene cDNA array revealed striking differences in responsiveness to PCB-126 between the populations; the differences occur at all three stages examined. There was a sizeable set of PCB-responsive genes in the sensitive SC population, a much smaller set of PCB-responsive genes in NBH fish, and few similarities in PCB-responsive genes between the two populations. Most of the array results were confirmed, and additional PCB-regulated genes identified, by RNA-Seq (deep pyrosequencing. Conclusions The results suggest that NBH fish possess a gene regulatory defect that is not specific to one target gene such as CYP1A but rather lies in a regulatory pathway that controls the transcriptional response of multiple genes to PCB exposure. The results are consistent with genome-wide disruption of AHR-dependent signaling in NBH fish.

  11. SUPERFUND TREATABILITY CLEARINGHOUSE: SUMMARY REPORT ON THE FIELD INVESTIGATION OF THE SAPP BATTERY SITE JACKSON COUNTY, FLORIDA

    Science.gov (United States)

    This treatability study presents the results of field investigations at the Sapp Battery site in Florida, an abandoned battery recycling operation. The site is estimated to contain 14,300 cubic yards of soils with lead levels in excess of 1,000 ppm. The soils in the immediate v...

  12. Changes in Groundwater Flow and Volatile Organic Compound Concentrations at the Fischer and Porter Superfund Site, Warminster Township, Bucks County, Pennsylvania, 1993-2009

    Science.gov (United States)

    Sloto, Ronald A.

    2010-01-01

    The 38-acre Fischer and Porter Company Superfund Site is in Warminster Township, Bucks County, Pa. Historically, as part of the manufacturing process, trichloroethylene (TCE) degreasers were used for parts cleaning. In 1979, the Bucks County Health Department detected TCE and other volatile organic compounds (VOCs) in water from the Fischer and Porter on-site supply wells and nearby public-supply wells. The Fischer and Porter Site was designated as a Superfund Site and placed on the National Priorities List in September 1983. A 1984 Record of Decision for the site required the Fischer and Porter Company to pump and treat groundwater contaminated by VOCs from three on-site wells at a combined rate of 75 gallons per minute to contain groundwater contamination on the property. Additionally, the Record of Decision recognized the need for treatment of the water from two nearby privately owned supply wells operated by the Warminster Heights Home Ownership Association. In 2004, the Warminster Heights Home Ownership Association sold its water distribution system, and both wells were taken out of service. The report describes changes in groundwater levels and contaminant concentrations and migration caused by the shutdown of the Warminster Heights supply wells and presents a delineation of the off-site groundwater-contamination plume. The U.S. Geological Survey (USGS) conducted this study (2006-09) in cooperation with the U.S. Environmental Protection Agency (USEPA). The Fischer and Porter Site and surrounding area are underlain by sedimentary rocks of the Stockton Formation of Late Triassic age. The rocks are chiefly interbedded arkosic sandstone and siltstone. The Stockton aquifer system is comprised of a series of gently dipping lithologic units with different hydraulic properties. A three-dimensional lithostratigraphic model was developed for the site on the basis of rock cores and borehole geophysical logs. The model was simplified by combining individual lithologic

  13. Post-remediation biomonitoring of pesticides and other contaminants in marine waters and sediment near the United Heckathorn Superfund Site, Richmond, California

    Energy Technology Data Exchange (ETDEWEB)

    LD Antrim; NP Kohn

    2000-05-26

    Marine sediment remediation at the United Heckathorn Superfund Site was completed in April 1997. Water and mussel tissues were sampled in February 1999 from four stations near Lauritzen Canal in Richmond, California, for Year 2 of post-remediation monitoring of marine areas near the United Heckathorn Site. Dieldrin and dichlorodiphenyl trichloroethane (DDT) were analyzed in water samples, tissue samples from resident mussels, and tissue samples from transplanted mussels deployed for 4 months. Concentrations of dieldrin and total DDT in water and total DDT in tissue were compared with Year 1 of post-remediation monitoring, and with preremediation data from the California State Mussel Watch program (tissues) and the Ecological Risk Assessment for the United Heckathorn Superfund Site (tissues and water). Mussel tissues were also analyzed for polychlorinated biphenyls (PCB), which were detected in sediment samples. Chlorinated pesticide concentrations in water samples were similar to preremediation levels and did not meet remediation goals. Mean dieidrin concentrations in water ranged from 0.62 rig/L to 12.5 ng/L and were higher than the remediation goal (0.14 ng/L) at all stations. Mean total DDT concentrations in water ranged from 14.4 ng/L to 62.3 ng/L and exceeded the remediation goal (0.59 ng/L) at all stations. The highest concentrations of both pesticides were found at the Lauritzen Canal/End station. Despite exceedence of the remediation goals, chlorinated pesticide concentrations in Lauritzen Canal water samples were notably lower in 1999 than in 1998. Tissue samples from biomonitoring organisms (mussels) provide an indication of the longer-term integrated exposure to contaminants in the water column, which overcomes the limitations of grab samples of water. Biomonitoring results indicated that the bioavailability of chlorinated pesticides has been reduced from preremediation levels both in the dredged area and throughout Richmond Harbor. Total DDT and

  14. NPL Site Boundaries

    Data.gov (United States)

    U.S. Environmental Protection Agency — The National Priorities List (NPL) is a list published by EPA of Superfund sites. A site must be added to this list before remediation can begin under Superfund. The...

  15. NPL Site Locations

    Data.gov (United States)

    U.S. Environmental Protection Agency — The National Priorities List (NPL) is a list published by EPA of Superfund sites. A site must be added to this list before remediation can begin under Superfund. The...

  16. NPL Site Locations

    Data.gov (United States)

    U.S. Environmental Protection Agency — The National Priorities List (NPL) is a list published by EPA of Superfund sites. A site must be added to this list before remediation can begin under Superfund. The...

  17. Guidance for performing site inspections under CERCLA

    Energy Technology Data Exchange (ETDEWEB)

    1992-09-01

    This guidance presents EPA`s site inspection (SI) strategy. The strategy discusses procedural guidelines to investigate potential Superfund (CERCLA) sites for evaluation pursuant to the Hazard Ranking System (HRS), revised in accordance with the Superfund Amendments and Reauthorization Act of 1986. The HRS is the primary means by which EPA evaluates sites for superfund`s National Priorities List (NPL).

  18. Superfund Technical Assistance Grants

    Data.gov (United States)

    U.S. Environmental Protection Agency — This asset includes data related to the Superfund Technical Assistance Grant program, including grant number, award amounts, award dates, period of performance,...

  19. Water-quality trends and constituent-transport analysis for selected sampling sites in the Milltown Reservoir/Clark Fork River Superfund Site in the upper Clark Fork Basin, Montana, water years 1996–2015

    Science.gov (United States)

    Sando, Steven K.; Vecchia, Aldo V.

    2016-07-20

    During the extended history of mining in the upper Clark Fork Basin in Montana, large amounts of waste materials enriched with metallic contaminants (cadmium, copper, lead, and zinc) and the metalloid trace element arsenic were generated from mining operations near Butte and milling and smelting operations near Anaconda. Extensive deposition of mining wastes in the Silver Bow Creek and Clark Fork channels and flood plains had substantial effects on water quality. Federal Superfund remediation activities in the upper Clark Fork Basin began in 1983 and have included substantial remediation near Butte and removal of the former Milltown Dam near Missoula. To aid in evaluating the effects of remediation activities on water quality, the U.S. Geological Survey began collecting streamflow and water-quality data in the upper Clark Fork Basin in the 1980s.Trend analysis was done on specific conductance, selected trace elements (arsenic, copper, and zinc), and suspended sediment for seven sampling sites in the Milltown Reservoir/Clark Fork River Superfund Site for water years 1996–2015. The most upstream site included in trend analysis is Silver Bow Creek at Warm Springs, Montana (sampling site 8), and the most downstream site is Clark Fork above Missoula, Montana (sampling site 22), which is just downstream from the former Milltown Dam. Water year is the 12-month period from October 1 through September 30 and is designated by the year in which it ends. Trend analysis was done by using a joint time-series model for concentration and streamflow. To provide temporal resolution of changes in water quality, trend analysis was conducted for four sequential 5-year periods: period 1 (water years 1996–2000), period 2 (water years 2001–5), period 3 (water years 2006–10), and period 4 (water years 2011–15). Because of the substantial effect of the intentional breach of Milltown Dam on March 28, 2008, period 3 was subdivided into period 3A (October 1, 2005–March 27, 2008

  20. Environmental Factor(tm) system: Superfund site information from five EPA databases (on cd-rom). Database

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    1996-07-01

    Environmental Factor puts today`s technology to work to provide a better, more cost-efficient and time-saving way to access EPA information on hazardous waste sites. Environmental consultants, insurers, and reinsurers, corporate risk assessors and companies actively involved in the generation, transport, storage or cleanup of hazardous waste materials can use its user-friendly information retrieval system to gain rapid access to vital information in immediately-usable form. Search, retrieve, and export information in real time. No more waiting for the mail or overnight delivery services to deliver hard copies of voluminous listings and individual site reports. More than 200,000 pages of EPA hazardous waste site information are contained in 5 related databases: (1) Site data from the National Priority List (NPL) and CERCLIS databases, Potentially Responsible Parties (PRP) and Records of Decision (RODs) summaries; (2) Complete PRP information; (3) EPA Records of Decision (Full Text); (4) entire Civil Enforcement Docket; and (5) Glossary of EPA terms, abbreviations and acronyms. Environmental Factor`s powerful database management engine gives even the most inexperienced computer user extensive search capabilities, including wildcard, phonetic and direct cross reference searches across multiple databases. The first menu option delivers information from the NPL, CERCLIS site data, PRP and RODs summary information. Enter a set of search criteria and then immediately access displays containing information from all of these databases. Get full PRP information and Full Text RODs by using their respective menu options. If your search turns up multiple items, a list of site names appears. To bring up the data, highlight the specific site you want and hit Enter. That`s how easy it is to access the vast amount of data stored in the Environmental Factor CD-ROM.

  1. Hydrogeologic characterization and assessment of bioremediation of chlorinated benzenes and benzene in wetland areas, Standard Chlorine of Delaware, Inc. Superfund Site, New Castle County, Delaware, 2009-12

    Science.gov (United States)

    Lorah, Michelle M.; Walker, Charles W.; Baker, Anna C.; Teunis, Jessica A.; Majcher, Emily H.; Brayton, Michael J.; Raffensperger, Jeff P.; Cozzarelli, Isabelle M.

    2014-01-01

    Wetlands at the Standard Chlorine of Delaware, Inc. Superfund Site (SCD) in New Castle County, Delaware, are affected by contamination with chlorobenzenes and benzene from past waste storage and disposal, spills, leaks, and contaminated groundwater discharge. In cooperation with the U.S. Environmental Protection Agency, the U.S. Geological Survey began an investigation in June 2009 to characterize the hydrogeology and geochemistry in the wetlands and assess the feasibility of monitored natural attenuation and enhanced bioremediation as remedial strategies. Groundwater flow in the wetland study area is predominantly vertically upward in the wetland sediments and the underlying aquifer, and groundwater discharge accounts for a minimum of 47 percent of the total discharge for the subwatershed of tidal Red Lion Creek. Thus, groundwater transport of contaminants to surface water could be significant. The major contaminants detected in groundwater in the wetland study area included benzene, monochlorobenzene, and tri- and di-chlorobenzenes. Shallow wetland groundwater in the northwest part of the wetland study area was characterized by high concentrations of total chlorinated benzenes and benzene (maximum about 75,000 micrograms per liter [μg/L]), low pH, and high chloride. In the northeast part of the wetland study area, wetland groundwater had low to moderate concentrations of total chlorinated benzenes and benzene (generally not greater than 10,000 μg/L), moderate pH, and high sulfate concentrations. Concentrations in the groundwater in excess of 1 percent of the solubility of the individual chlorinated benzenes indicate that a contaminant source is present in the wetland sediments as dense nonaqueous phase liquids (DNAPLs). Consistently higher contaminant concentrations in the shallow wetland groundwater than deeper in the wetland sediments or the aquifer also indicate a continued source in the wetland sediments, which could include dissolution of DNAPLs and

  2. Radiological assessment in case of an incident at the hot cells clean-up

    Directory of Open Access Journals (Sweden)

    Dragolici Cristian A.

    2014-01-01

    Full Text Available The clean-up and decontamination of the hot cells will be performed in the second phase of the WWR-S research reactor decommissioning. Identification of possible incidents or accidents is the key element in radiological assessment and prevention. As major incident it was considered a fire burst that occurred during the progress of the clean-up operations. The postulated incident has, as a consequence, thick smoke generation from the burned radioactive material and the dispersion of this material in the environment through the technological ventilation system and the evacuation chimney. From the performed analysis it can be seen that in the case of an incident to the reactor hot cells, an operator engaged in intervention operations could take an effective dose of 5.29 Sv per event, coming from both external and internal exposure. Such an incident, if it happens, would be classified of level 3 on the INES scale.

  3. HYDRAULIC ELEVATOR INSTALLATION ESTIMATION FOR THE WATER SOURCE WELL SAND-PACK CLEANING UP

    Directory of Open Access Journals (Sweden)

    V. V. Ivashechkin

    2016-01-01

    Full Text Available The article offers design of a hydraulic elevator installation for cleaning up water-source wells of sand packs. It considerers the installation hydraulic circuit according to which the normal pump feeds the high-level tank water into the borehole through two parallel water lines. The water-jet line with washing nozzle for destroying the sand-pack and the supply pipe-line coupled with the operational nozzle of the hydraulic elevator containing the inlet and the supply pipelines for respectively intaking the hydromixture and removing it from the well. The paper adduces equations for fluid motion in the supply and the water-jet pipelines and offers expressions for evaluating the required heads in them. For determining water flow in the supply and the water-jet pipe lines the author proposes to employ graphical approach allowing finding the regime point in Q–H chart by means of building characteristics of the pump and the pipe-lines. For calculating the useful vertical head, supply and dimensions of the hydraulic elevator the article employs the equation of motion quantity with consistency admission of the motion quantity before and after mixing the flows in the hydraulic elevator. The suggested correlations for evaluating the hydraulic elevator efficiency determine the sand pack removal duration as function of its sizes and the ejected fluid flow rate. A hydraulic-elevator installation parameters estimation example illustrates removing a sand pack from a water-source borehole of 41 m deep and 150 mm diameter bored in the village of Uzla of Myadelsk region, of Minsk oblast. The working efficiency of a manufactured and laboratory tested engineering prototype of the hydraulic elevator installation was acknowledged in actual tests at the indicated borehole site. With application of graphical approach, the suggested for the hydraulic elevator installation parameters calculation procedure allows selecting, with given depth and the borehole diameter

  4. Process for cleaning up hard coal mines containing salt water. Verfahren zur Entsorgung von salzwasserfuehrenden Steinkohlenzechen

    Energy Technology Data Exchange (ETDEWEB)

    Hoelter, H.; Igelbuescher, H.; Gresch, H.; Dewert, H.

    1987-03-12

    The process for cleaning up pits with a great deal of salt water in them and the associated high proportion of flotation material is characterized by the fact that the pre-treated salt water content forms a mass with the flotation coal/rock mass, which is burnt to a residue in fluidized-bed combustion, where the residue as a building material containing salt is particularly suitable for building roads and paths secure against frost and for similar building processes.

  5. Impact of oil spill and posterior clean-up activities on wrack-living talitrid amphipods on estuarine beaches

    Directory of Open Access Journals (Sweden)

    Carlos A. Borzone

    2009-12-01

    Full Text Available A geomorphological and faunistic seasonal study of six estuarine beaches on Paranaguá Bay, Brazil, was abruptly interrupted when the Chilean ship "Vicuña" exploded and sank, spilling 291 tons of bunker fuel oil. The beaches sampled twice before the accident were affected by the oil spill deposition and the posterior clean-up activities. Neither drastic reduction in abundances nor occurrences of oil-covered individuals were registered. Significant variation in both amount of debris and talitrid amphipod densities was directly related to beach clean-up activities. A short (1-3 month manual clean-up of polluted wrack resulted in an increase in talitrid abundances, with the local distribution expansion of one species, Platorchestia monodi, from three to six of the beaches sampled. The active migration and concentration of organisms at sites without wrack during cleaning activities and a massive and continuous recovery of new debris, characteristic of estuarine beaches, may contribute to the findings.Um estudo sazonal da geomorfologia e fauna de seis praias estuarinas na baia de Paranaguá, Brasil, foi interrompido bruscamente pela explosão e posterior afundamento do navio chileno Vicuña, que derramou 291 toneladas de óleo bunker. As praias que foram afetadas pela deposição de óleo e pelas posteriores atividades de limpeza, tinham sido amostradas duas vezes antes do acidente. Nas coletas posteriores ao acidente não foram registradas nem reduções drásticas das abundâncias nem indivíduos impregnados por óleo. As significativas variações tanto da quantidade de detrito quanto nas densidades de anfipodes talitrídeos foram relacionadas às atividades de limpeza. Uma limpeza manual e de curta duração (1 a 3 meses resultou num aumento das abundâncias dos talitrídeos, juntamente com o aumento da distribuição de uma das espécies, Platorchestia monodi, que de três passou a ser encontrada em seis praias amostradas.Os fatores que

  6. 76 FR 72405 - San Fernando Valley Area 2 Superfund Site; Notice of Proposed Prospective Purchaser Agreement Re...

    Science.gov (United States)

    2011-11-23

    ... Site; Notice of Proposed Prospective Purchaser Agreement Re: 4057 and 4059 Goodwin Avenue, Los Angeles...) concerning 4057 and 4059 Goodwin Avenue, Los Angeles, California (Property). The Agreement is entered into..., Glendale/Goodwin Realty I, LLC, an Ohio limited liability company, The Kroger Co., an Ohio corporation,...

  7. Coupling detergent lysis/clean-up methodology with intact protein fractionation for enhanced proteome characterization

    Energy Technology Data Exchange (ETDEWEB)

    Sharma, Ritin [ORNL; Dill, Brian [ORNL; Chourey, Karuna [ORNL; Shah, Manesh B [ORNL; Verberkmoes, Nathan C [ORNL; Hettich, Robert {Bob} L [ORNL

    2012-01-01

    The expanding use of surfactants for proteome sample preparations has prompted the need to systematically optimize the application and removal of these MS-deleterious agents prior to proteome measurements. Here we compare four different detergent clean-up methods (Trichloroacetic acid (TCA) precipitation, Chloroform/Methanol/Water (CMW) extraction, commercial detergent removal spin column method (DRS) and filter-aided sample preparation(FASP)) with respect to varying amounts of protein biomass in the samples, and provide efficiency benchmarks with respect to protein, peptide, and spectral identifications for each method. Our results show that for protein limited samples, FASP outperforms the other three clean-up methods, while at high protein amount all the methods are comparable. This information was used in a dual strategy of comparing molecular weight based fractionated and unfractionated lysates from three increasingly complex samples (Escherichia coli, a five microbial isolate mixture, and a natural microbial community groundwater sample), which were all lysed with SDS and cleaned up using FASP. The two approaches complemented each other by enhancing the number of protein identifications by 8%-25% across the three samples and provided broad pathway coverage.

  8. Water-quality trends and constituent-transport analysis for selected sampling sites in the Milltown Reservoir/Clark Fork River Superfund Site in the upper Clark Fork Basin, Montana, water years 1996–2015

    Science.gov (United States)

    Sando, Steven K.; Vecchia, Aldo V.

    2016-07-20

    During the extended history of mining in the upper Clark Fork Basin in Montana, large amounts of waste materials enriched with metallic contaminants (cadmium, copper, lead, and zinc) and the metalloid trace element arsenic were generated from mining operations near Butte and milling and smelting operations near Anaconda. Extensive deposition of mining wastes in the Silver Bow Creek and Clark Fork channels and flood plains had substantial effects on water quality. Federal Superfund remediation activities in the upper Clark Fork Basin began in 1983 and have included substantial remediation near Butte and removal of the former Milltown Dam near Missoula. To aid in evaluating the effects of remediation activities on water quality, the U.S. Geological Survey began collecting streamflow and water-quality data in the upper Clark Fork Basin in the 1980s.Trend analysis was done on specific conductance, selected trace elements (arsenic, copper, and zinc), and suspended sediment for seven sampling sites in the Milltown Reservoir/Clark Fork River Superfund Site for water years 1996–2015. The most upstream site included in trend analysis is Silver Bow Creek at Warm Springs, Montana (sampling site 8), and the most downstream site is Clark Fork above Missoula, Montana (sampling site 22), which is just downstream from the former Milltown Dam. Water year is the 12-month period from October 1 through September 30 and is designated by the year in which it ends. Trend analysis was done by using a joint time-series model for concentration and streamflow. To provide temporal resolution of changes in water quality, trend analysis was conducted for four sequential 5-year periods: period 1 (water years 1996–2000), period 2 (water years 2001–5), period 3 (water years 2006–10), and period 4 (water years 2011–15). Because of the substantial effect of the intentional breach of Milltown Dam on March 28, 2008, period 3 was subdivided into period 3A (October 1, 2005–March 27, 2008

  9. Groundwater Contamination: DOD Uses and Develops a Range of Remediation Technologies to Clean Up Military Sites

    Science.gov (United States)

    2005-06-01

    DNAPL dense nonaqueous phase liquids DOD Department of Defense EPA Environmental Protection Agency ESTCP Environmental Security Technology Certification...copper, lead, mercury , selenium, silver, and zinc. eIncludes, but is not limited to, oxygen-bearing chemicals that can be added to fuel to bring...technology is applicable to both dense and light nonaqueous phase liquids ( DNAPL and LNAPL).3 Benefits of enhanced recovery approaches include the

  10. Hydrogeology and simulation of ground-water flow at the Gettysburg Elevator Plant Superfund Site, Adams County, Pennsylvania

    Science.gov (United States)

    Low, Dennis J.; Goode, Daniel J.; Risser, Dennis W.

    2000-01-01

    Ground water in Triassic-age sedimentary fractured-rock aquifers in the area of Gettysburg, Pa., is used as drinking water and for industrial and commercial supply. In 1983, ground water at the Gettysburg Elevator Plant was found by the Pennsylvania Department of Environmental Resources to be contaminated with trichloroethene, 1,1,1-trichloroethane, and other synthetic organic compounds. As part of the U.S. Environmental Protection Agency?s Comprehensive Environmental Response, Compensation, and Liability Act, 1980 process, a Remedial Investigation was completed in July 1991, a method of site remediation was issued in the Record of Decision dated June 1992, and a Final Design Report was completed in May 1997. In cooperation with the U.S. Environmental Protection Agency in the hydrogeologic assessment of the site remediation, the U.S. Geological Survey began a study in 1997 to determine the effects of the onsite and offsite extraction wells on ground-water flow and contaminant migration from the Gettysburg Elevator Plant. This determination is based on hydrologic and geophysical data collected from 1991 to 1998 and on results of numerical model simulations of the local ground-water flow-system. The Gettysburg Elevator Site is underlain by red, green, gray, and black shales of the Heidlersburg Member of the Gettysburg Formation. Correlation of natural-gamma logs indicates the sedimentary rock strike about N. 23 degrees E. and dip about 23 degrees NW. Depth to bedrock onsite commonly is about 6 feet but offsite may be as deep as 40 feet. The ground-water system consists of two zones?a thin, shallow zone composed of soil, clay, and highly weathered bedrock and a thicker, nonweathered or fractured bedrock zone. The shallow zone overlies the bedrock zone and truncates the dipping beds parallel to land surface. Diabase dikes are barriers to ground-water flow in the bedrock zone. The ground-water system is generally confined or semi-confined, even at shallow depths. Depth

  11. Temporal Chemical Data for Sediment, Water, and Biological Samples from the Lava Cap Mine Superfund Site, Nevada County, California-2006-2008

    Science.gov (United States)

    Foster, Andrea L.; Ona-Nguema, Georges; Tufano, Kate; White, Richard III

    2010-01-01

    the possibility of future movement of tailings, and began an assessment of the risks posed by physical and chemical hazards at the site. The EPA's assessment identified arsenic (As) as the primary hazard of concern. Three main exposure routes were identified: inhalation/ingestion of mine tailings, dermal absorption/ingestion of As in lake water from swimming, and ingestion of As-contaminated ground water or surface water. Lost Lake is a private lake which is completely surrounded by low-density residential development. Prior to the dam failure, the lake was used by the local residents for swimming and boating. An estimated 1,776 people reside within one mile of the lake, and almost all residents of the area use potable groundwater for domestic use. Risk factors for human exposure to As derived from mine wastes were high enough to merit placement of the mine site and surrounding area on the National Priority List (commonly called ?Superfund?). The Lava Cap Mine Superfund site (LCMS) encompasses approximately 33 acres that include the mine site, the stretch of Little Clipper Creek between the mine and Lost Lake, the lake itself, and the area between the lake and the confluence of Little Clipper Creek with its parent stream, Clipper Creek. The area between the two creeks is named the ?deposition area? due to the estimated 24 m thick layer of tailings that were laid down there during and after active mining. The lobate structure of Lost Lake is also due to deposition in this area. The deposition area and Lost Lake are together estimated to contain 382,277 m3 of tailings. The primary goals of the EPA have been to minimize tailings movement downstream of Lost Lake and to ensure that residents in the area have drinking water that meets national water quality standards. EPA has officially decided to construct a public water supply line to deliver safe water to affected residences, since some residential wells in the area have As concentrations above the curr

  12. Geochemical Characterization of Mine Waste, Mine Drainage, and Stream Sediments at the Pike Hill Copper Mine Superfund Site, Orange County, Vermont

    Science.gov (United States)

    Piatak, Nadine M.; Seal, Robert R.; Hammarstrom, Jane M.; Kiah, Richard G.; Deacon, Jeffrey R.; Adams, Monique; Anthony, Michael W.; Briggs, Paul H.; Jackson, John C.

    2006-01-01

    The Pike Hill Copper Mine Superfund Site in the Vermont copper belt consists of the abandoned Smith, Eureka, and Union mines, all of which exploited Besshi-type massive sulfide deposits. The site was listed on the U.S. Environmental Protection Agency (USEPA) National Priorities List in 2004 due to aquatic ecosystem impacts. This study was intended to be a precursor to a formal remedial investigation by the USEPA, and it focused on the characterization of mine waste, mine drainage, and stream sediments. A related study investigated the effects of the mine drainage on downstream surface waters. The potential for mine waste and drainage to have an adverse impact on aquatic ecosystems, on drinking- water supplies, and to human health was assessed on the basis of mineralogy, chemical concentrations, acid generation, and potential for metals to be leached from mine waste and soils. The results were compared to those from analyses of other Vermont copper belt Superfund sites, the Elizabeth Mine and Ely Copper Mine, to evaluate if the waste material at the Pike Hill Copper Mine was sufficiently similar to that of the other mine sites that USEPA can streamline the evaluation of remediation technologies. Mine-waste samples consisted of oxidized and unoxidized sulfidic ore and waste rock, and flotation-mill tailings. These samples contained as much as 16 weight percent sulfides that included chalcopyrite, pyrite, pyrrhotite, and sphalerite. During oxidation, sulfides weather and may release potentially toxic trace elements and may produce acid. In addition, soluble efflorescent sulfate salts were identified at the mines; during rain events, the dissolution of these salts contributes acid and metals to receiving waters. Mine waste contained concentrations of cadmium, copper, and iron that exceeded USEPA Preliminary Remediation Goals. The concentrations of selenium in mine waste were higher than the average composition of eastern United States soils. Most mine waste was

  13. Geohydrology and vertical distribution of volatile organic compounds in ground water, Fischer and Porter Company Superfund Site, Warminster, Bucks County, Pennsylvania

    Science.gov (United States)

    Sloto, R.A.; Macchiaroli, Paola; Conger, R.W.

    1995-01-01

    The Fischer and Porter company Superfund Site is underlain by sedimentary rocks of the Upper Triassic Stockton Formation, which consists of interbedded siltstone, very-fine grained to coarse-grained sandstone, and conglomerate in crudely defined upward fining cycles. These rocks form a complex, heterogeneous, leaky, multiaquifer system comprised of a series of gently dipping lithologic units with different hydraulic properties. Ground water is unconfined in the shallower part of the aquifer and confined or semiconfined in the deeper part of the aquifer. Water levels measured in monitor well clusters and borehole-flow measurements made in open boreholes show a downward hydraulic head gradient at the site, caused in part by the pumping of nearby, deep public-supply wells and the Fischer and Porter treatment system extraction wells. Downward borehole flow was measured at rates up to 9 gallons per minute. Aquifer-isolation tests were run in the six boreholes to obtain depth-discrete specific-capacity and water-quality data. On the basis of specific-capacity data for 27 isolated intervals, specific capacity is not related to depth. Water levels in monitor wells at the Fischer and Porter Site are greatly affected by the pumping of nearby public-supply wells, as well as the pumping of the Fischer and Porter treatment system extraction wells. Pumping of the public-supply wells causes daily water-level fluctuations in wells at the site as great as 5.3 feet. The shutdown of the Fischer and Porter treatment system extraction wells caused a rise in water level in all wells screened in the intermediate and deep zones. The rise in water level was as great as 4.3 feet in the intermediate zone and as great as 5.9 feet in the deep zone. The direction of ground-water flow is toward the north in the shallow and intermediate zones and toward the west and west-southwest in the deep zone. Ground-water discharge probably is to the unnamed tributary to Pennypack Creek north and west of

  14. Monitoring the clean-up operation of agricultural fields flooded with red mud in Hungary.

    Science.gov (United States)

    Uzinger, Nikolett; Rékási, Márk; Anton, Áron D; Koós, Sándor; László, Péter; Anton, Attila

    2016-12-01

    In the course of the clean-up operation after the red mud inundation in 2010, red mud was removed from the soil surface in places where the layer was more than 5 cm deep. Before its removal, the red mud seeped into the soil. In 2012, soil samples were taken from depths of 0 to 20 and 20 to 40 cm on some of the affected areas. The parameters investigated were pH, organic matter, salt%, and the total and mobile fractions of various elements. The values recorded in 2012 were compared with those measured immediately after the removal of the red mud in 2010 and with the background and clean-up target concentrations. The pH values remained below the designated limit, while the salt content only exhibited values in the weakly salty range on areas at the greatest distance from the dam. In the central part of the inundated area, total Na contents above the 900 mg/kg target value were observed, but the Na content in the 0-20-cm layer generally exhibited a decrease due to leaching. The pH and As concentration also showed a decline on several areas compared with the values recorded in 2010. Total As and Co contents in excess of the target values were recorded on the lowest-lying part of the flooded area, probably because the finest red mud particles were deposited the furthest from the dam, where they seeped into the soil. Nevertheless, the mobility and plant availability of both elements remained moderate. The total contents of both Co and Mo, however, exhibited a significant rise compared with both the background value and the 2010 data. The monitoring of the cleaned-up areas showed that after a 2-year period element concentrations that exceeded the target values and could be attributed to the red mud pollution were only detectable on the lowest-lying areas.

  15. Evaluation of geophysical logs and aquifer-isolation tests, Phase III, August 2002 to March 2004, Crossley Farm superfund site, Hereford township, Berks County, Pennsylvania

    Science.gov (United States)

    Conger, Randall W.; Low, Dennis J.

    2006-01-01

    Between August 2002 and March 2004, geophysical logging was conducted in 23 boreholes at the Crossley Farm Superfund Site, Hereford Township, Berks County, Pa., to determine the water-producing zones, water-receiving zones, zones of vertical-borehole flow, and fracture orientation where applicable. The boreholes ranged in depth from 71 to 503 ft(feet) below land surface. The geophysical logging determined the placement of well screens and packers, which allow monitoring and sampling of water-bearing zones in the fractured bedrock so the horizontal and vertical distribution of contaminated ground water migrating from known sources could be determined. Geophysical logging included collection of caliper (22 boreholes), fluid-temperature (17 boreholes),single-point-resistance (17 boreholes), natural-gamma (17 boreholes), fluid-flow (18 boreholes), and acoustic-televiewer (13 boreholes) logs. Caliper and acoustic-televiewer logs were used to locate fractures, joints, and weathered zones. Inflections on fluid-temperature and single-point-resistance logs indicated possible water-bearing zones, and flowmeter measurements verified these locations. Single-point-resistance, natural-gamma, and geologist logs provided information on stratigraphy; the geologist log also provided information on the location of possible water-producing zones. Borehole geophysical logging and heatpulse flowmetering indicated active flow in 10 boreholes. Seven of the boreholes are in ground-water discharge areas and three boreholes are in ground-water recharge areas. Heatpulse flowmetering, in conjunction with the geologist logs, indicates lithologic contacts (changes in lithology from a gneiss dominated by quartz-plagioclase-feldspar mineralogy to a gneiss dominated by hornblende mineralogy) are typically fractured, permeable, and effective transmitters of water. Single-well, aquifer-isolation (packer) tests were performed on two boreholes. Packers were set at depths ranging from 210 to 465 ft

  16. Geochemical, isotopic, and dissolved gas characteristics of groundwater in a fractured crystalline-rock aquifer, Savage Municipal Well Superfund site, Milford, New Hampshire, 2011

    Science.gov (United States)

    Harte, Philip T.

    2013-01-01

    Tetrachloroethylene (PCE), a volatile organic compound, was detected in groundwater from deep (more than (>) 300 feet (ft) below land surface) fractures in monitoring wells tapping a crystalline-rock aquifer beneath operable unit 1 (OU1) of the Savage Municipal Well Superfund site (Weston, Inc., 2010). Operable units define remedial areas of contaminant concern. PCE contamination within the fractured-rock aquifer has been designated as a separate operable unit, operable unit 3 (OU3; Weston, Inc., 2010). PCE contamination was previously detected in the overlying glacial sand and gravel deposits and basal till, hereafter termed the Milford-Souhegan glacial-drift (MSGD) aquifer (Harte, 2004, 2006). Operable units 1 and 2 encompass areas within the MSGD aquifer, whereas the extent of the underlying OU3 has yet to be defined. The primary original source of contamination has been identified as a former manufacturing facility—the OK Tool manufacturing facility; hence OU1 sometimes has been referred to as the OK Tool Source Area (New Hampshire Department of Environmental Services, undated). A residential neighborhood of 30 to 40 houses is located in close proximity (one-quarter of a mile) from the PCE-contaminated monitoring wells. Each house has its own water-supply well installed in similar rocks as those of the monitoring wells, as indicated by the New Hampshire State geologic map (Lyons and others, 1997). An investigation was initiated in 2010 by the U.S. Environmental Protection Agency (USEPA) region 1, and the New Hampshire Department of Environmental Services (NHDES) to assess the potential for PCE transport from known contaminant locations (monitoring wells) to the residential wells. The U.S. Geological Survey (USGS) and the NHDES entered into a cooperative agreement in 2011 to assist in the evaluation of PCE transport in the fractured-rock aquifer. Periodic sampling over the last decade by the USEPA and NHDES has yet to detect PCE in groundwater from the

  17. Oak Ridge Cleanup Vision: Moving to the Future by Cleaning Up the Past - 13291

    Energy Technology Data Exchange (ETDEWEB)

    Cange, Susan M. [DOE Oak Ridge, P.O. Box 2001, Oak Ridge, TN 37831 (United States); Wieland, Christopher C.; DePaoli, Susan M. [Pro2Serve, 1100 Bethel Valley Rd., Oak Ridge, TN 37830 (United States)

    2013-07-01

    successfully revised Program priorities and has received buy-in from the leadership in Headquarters, the regulators, and the community. Issues EM was facing in 2009 are presented. Resulting lessons learned and subsequent changes that the Office has gone through in the past several years in order to improve performance in the safe execution of work, relationships with external stakeholders, and communications both internally and externally are discussed. Results of these efforts are provided as a summary of Program accomplishments, including a strong focus on the future. EM's motto, Moving to the Future by Cleaning up the Past, will be demonstrated through the Program's mission, which includes protecting the region's health and environment; ensuring the continuation of ongoing vital missions being conducted by DOE on the Oak Ridge Reservation; and making clean land available for future use at all three sites, with a near-term focus on Re-industrialization of ETTP. (authors)

  18. Sol-gel immunoaffinity chromatography for the clean up of ochratoxin A contaminated grains.

    Science.gov (United States)

    Reiter, Elisabeth Viktoria; Cichna-Markl, Margit; Tansakul, Natthasit; Shim, Won-Bo; Chung, Duck-Hwa; Zentek, Jürgen; Razzazi-Fazeli, Ebrahim

    2011-10-21

    This paper describes the application of sol-gel immunoaffinity columns for clean up of ochratoxin A contaminated cereal crops. Monoclonal antibodies selective for OTA have been entrapped into the pores of a sol-gel matrix in order to prepare immunoaffinity columns. Different parameters such as amount of entrapped antibodies and loading conditions were optimized to obtain highest possible recoveries of OTA. The method has been found to be a suitable tool in sample preparation prior to HPLC-FLD determination and as selective as conventional commercially available immunoaffinity columns. In the clean up of different cereals mean recoveries of 82±5%, 90±6% and 91±3%, were obtained for wheat, barley and rye, respectively, with sol-gel columns containing 1mg of anti-OTA antibodies. The detection limit (signal-to-noise ratio, 3) was 0.5 μg/kg and the limit of quantification (signal-to-noise ratio, 10) determined to be 1 μg/kg. Sol-gel columns can be reused 7 times without significant loss of recovery. After 10 applications the recovery decreased to approx. 50%.

  19. Determination of amphetamines in hair by integrating sample disruption, clean-up and solid phase derivatization.

    Science.gov (United States)

    Argente-García, A; Moliner-Martínez, Y; Campíns-Falcó, P; Verdú-Andrés, J; Herráez-Hernández, R

    2016-05-20

    The utility of matrix solid phase dispersion (MSPD) for the direct analysis of amphetamines in hair samples has been evaluated, using liquid chromatography (LC) with fluorescence detection and precolumn derivatization. The proposed approach is based on the employment of MSPD for matrix disruption and clean-up, followed by the derivatization of the analytes onto the dispersant-sample blend. The fluorogenic reagent 9-fluorenylmethyl chloroformate (FMOC) has been used for derivatization. Different conditions for MSPD, analyte purification and solid phase derivatization have been tested, using amphetamine (AMP), methamphetamine (MET), ephedrine (EPE) and 3,4-methylenedioxymethamphetamine (MDMA) as model compounds. The results have been compared with those achieved by using ultrasound-assisted alkaline digestion and by MSPD combined with conventional solution derivatization. On the basis of the results obtained, a methodology is proposed for the analysis of amphetamines in hair which integrates sample disruption, clean-up and derivatization using a C18 phase. Improved sensitivity is achieved with respect to that obtained by the alkaline digestion or by the MSPD followed by solution derivatization methods. The method can be used for the quantification of the tested amphetamines within the 2.0-20.0ng/mg concentration interval, with limits of detection (LODs) of 0.25-0.75ng/mg. The methodology is very simple and rapid (the preparation of the sample takes less than 15min).

  20. Dosimetry for a study of low-dose radiation cataracts among Chernobyl clean-up workers.

    Science.gov (United States)

    Chumak, V V; Worgul, B V; Kundiyev, Y I; Sergiyenko, N M; Vitte, P M; Medvedovsky, C; Bakhanova, E V; Junk, A K; Kyrychenko, O Y; Musijachenko, N V; Sholom, S V; Shylo, S A; Vitte, O P; Xu, S; Xue, X; Shore, R E

    2007-05-01

    A cohort of 8,607 Ukrainian Chernobyl clean-up workers during 1986-1987 was formed to study cataract formation after ionizing radiation exposure. Study eligibility required the availability of sufficient exposure information to permit the reconstruction of doses to the lens of the eye. Eligible groups included civilian workers, such as those who built the "sarcophagus" over the reactor, Chernobyl Nuclear Power Plant Workers, and military reservists who were conscripted for clean-up work. Many of the official doses for workers were estimates, because only a minority wore radiation badges. For 106 military workers, electron paramagnetic resonance (EPR) measurements of extracted teeth were compared with the recorded doses as the basis to adjust the recorded gamma-ray doses and provide estimates of uncertainties. Beta-particle doses to the lens were estimated with an algorithm devised to take into account the nature and location of Chernobyl work, time since the accident, and protective measures taken. A Monte Carlo routine generated 500 random estimates for each individual from the uncertainty distributions of the gamma-ray dose and of the ratio of beta-particle to gamma-ray doses. The geometric mean of the 500 combined beta-particle and gamma-ray dose estimates for each individual was used in the data analyses. The median estimated lens dose for the cohort was 123 mGy, while 4.4% received >500 mGy.

  1. Hazardous Waste Clean-Up Information (CLU-IN) On-line Characterization and Remediation Databases Fact Sheet

    Science.gov (United States)

    This fact sheet provides an overview of the 10 on-line characterization and remediation databases available on the Hazardous Waste Clean-Up Information (CLU-IN) website sponsored by the U.S. Environmental Protection Agency.

  2. Superfund and Toxic Release Inventory Sites - INSTITUTIONAL_CONTROLS_IDEM_IN.SHP: Institutional Control Sites in Indiana (Indiana Department of Environmental Management, Polygon Shapefile)

    Data.gov (United States)

    NSGIC State | GIS Inventory — INSTITUTIONAL_CONTROLS_IDEM_IN is a polygon shapefile that contains Institutional Control (IC) site locations in Indiana, provided by personnel of Indiana Department...

  3. Hydrogeologic framework, arsenic distribution, and groundwater geochemistry of the glacial-sediment aquifer at the Auburn Road landfill superfund site, Londonderry, New Hampshire

    Science.gov (United States)

    Degnan, James R.; Harte, Philip T.

    2013-01-01

    Leachate continues to be generated from landfills at the Auburn Road Landfill Superfund Site in Londonderry, New Hampshire. Impermeable caps on the three landfills at the site inhibit direct infiltration of precipitation; however, high water-table conditions allow groundwater to interact with landfill materials from below, creating leachate and ultimately reducing conditions in downgradient groundwater. Reducing conditions can facilitate arsenic transport by allowing it to stay in solution or by liberating arsenic adsorbed to surfaces and from geologic sources, such as glacial sediments and bedrock. The site occupies a 180-acre parcel of land containing streams, ponds, wetlands, and former gravel pits located in glacial sediment. Four areas, totaling 14 acres, including three landfills and one septage lagoon, were used for waste disposal. The site was closed in 1980 after volatile organic compounds associated with industrial waste dumping were detected. The site was added to the U.S. Environmental Protection Agency National Priority List in 1982, and the landfills were capped in 1996. Although volatile organic compound concentrations in groundwater have declined substantially, some measurable concentrations remain. Temporally variable and persistent elevated arsenic concentrations have been measured in groundwater affected by the landfill leachate. Microbial consumption of carbon found in leachate is a driver of reducing conditions that liberate arsenic at the site. In addition to sources of carbon in landfill leachate, wetland areas throughout the site also could contribute carbon to groundwater, but it is currently unknown if any of the wetland areas have downward or reversing gradients that could allow the infiltration of surface water to groundwater. Red-stained sediments and water indicate iron-rich groundwater discharge to surface water and are also associated with elevated concentrations of arsenic in sediment and groundwater. Ironrich groundwater seeps have

  4. Geophysical Logs, Aquifer Tests, and Water Levels in Wells in and Near the North Penn Area 7 Superfund Site, Upper Gwynedd Township, Montgomery County, Pennsylvania, 2002-2006

    Science.gov (United States)

    Senior, Lisa A.; Conger, Randall W.; Bird, Philip H.

    2008-01-01

    Ground water in the vicinity of several industrial facilities in Upper Gwynedd Township and Lansdale Borough, Montgomery County, Pa., is contaminated with several volatile organic compounds (VOCs). The 2-square-mile area was placed on the National Priorities List as the North Penn Area 7 Superfund Site by the U.S. Environmental Protection Agency (USEPA) in 1989. The U.S. Geological Survey (USGS) conducted geophysical logging, aquifer testing, water-level monitoring, and streamflow measurements in the vicinity of North Penn Area 7 from October 2002 through December 2006. This followed work that began in 2000 to assist the USEPA in developing an understanding of the hydrogeologic framework in the area as part of the USEPA Remedial Investigation. The study area is underlain by Triassic- and Jurassic-age sandstones, siltstones, and shales of the Lockatong Formation and the Brunswick Group. Regionally, these rocks strike northeast and dip to the northwest. The sequence of rocks form fractured-rock aquifers that act as a set of confined to semi-confined layered aquifers of differing permeabilities. The aquifers are recharged by precipitation and discharge to streams and wells. The Wissahickon Creek headwaters are less than 1 mile northeast of the study area. This stream flows southwest approximately parallel to strike and bisects North Penn Area 7. Ground water is pumped in the vicinity of North Penn Area 7 for industrial use and public supply. The USGS collected geophysical logs for 42 wells that ranged in depth from 40 to 477 ft. Aquifer-interval-isolation testing was done in 17 of the 42 wells, for a total of 122 zones tested. A multiple-well aquifer test was conducted by monitoring the response of 14 wells to pumping and shutdown of a 600-ft deep production well in November-December 2004. In addition, water levels were monitored continuously in four wells in the area from October 2002 through September 2006, and streamflow was measured quarterly at two sites on

  5. Hydrostratigraphic mapping of the Milford-Souhegan glacial drift aquifer, and effects of hydrostratigraphy on transport of PCE, Operable Unit 1, Savage Superfund Site, Milford, New Hampshire

    Science.gov (United States)

    Harte, Philip T.

    2010-01-01

    The Savage Municipal Well Superfund site in the Town of Milford, New Hampshire, was underlain by a 0.5-square mile plume (as mapped in 1994) of volatile organic compounds (VOCs), most of which consisted of tetrachloroethylene (PCE). The plume occurs mostly within highly transmissive stratified-drift deposits but also extends into underlying till and bedrock. The plume has been divided into two areas called Operable Unit 1 (OU1), which contains the primary source area, and Operable Unit 2 (OU2), which is defined as the extended plume area outside of OU1. The OU1 remedial system includes a low-permeability barrier wall that encircles the highest detected concentrations of PCE and a series of injection and extraction wells to contain and remove contaminants. The barrier wall likely penetrates the full thickness of the sand and gravel; in many places, it also penetrates the full thickness of the underlying basal till and sits atop bedrock.From 1998 to 2004, PCE concentrations decreased by an average of 80 percent at most wells outside the barrier wall. However, inside the barrier, PCE concentrations greater than 10,000 micrograms per liter (μg/L) still exist (2008). The remediation of these areas of recalcitrant PCE presents challenges to successful remediation.The U.S. Geological Survey (USGS), in cooperation with the New Hampshire Department of Environmental Services (NHDES) and the U.S. Environmental Protection Agency (USEPA), Region 1, is studying the solute transport of VOCs (primarily PCE) in contaminated groundwater in the unconsolidated sediments (overburden) of the Savage site and specifically assisting in the evaluation of the effectiveness of remedial operations in the OU1 area. As part of this effort, the USGS analyzed the subsurface stratigraphy to help understand hydrostratigraphic controls on remediation.A combination of lithologic, borehole natural gamma-ray and electromagnetic (EM) induction logging, and test drilling has identified 11 primary

  6. Technology evaluation report: SITE (Superfund Innovative Technology Evaluation) program demonstration test. The American Combustion Pyretron Thermal Destruction System at the US EPA's (Environmental Protection Agency's) combustion research facility

    Energy Technology Data Exchange (ETDEWEB)

    Waterland, L.; Lee, J.W.

    1989-04-01

    A series of demonstration tests of the American Combustion, Inc., Thermal Destruction System was performed under the SITE program. This oxygen-enhanced combustion system was retrofit to the rotary-kiln incinerator at EPA's Combustion Research Facility. The system's performance was tested firing contaminated soil from the Stringfellow Superfund Site, both alone and mixed with a coal tar waste (KO87). Comparative performance with conventional incinerator operation was also tested. Compliance with the incinerator performance standards of 99.99% principal organic hazardous constituents (POHC) destruction and removal efficiency and particulate emissions of less than 180 mg/dscm at 7% O2 was measured for all tests. The Pyretron system was capable of in-compliance performance at double the mixed waste feedrate and at a 60% increase in batch waste charge mass than possible with conventional incineration. Scrubber blowdown and kiln ash contained no detectable levels of any of the POHCs chosen.

  7. Social and psychological state of the Chornobyl clean up workers. Risk factors for negative changes.

    Science.gov (United States)

    Buzunov, V O; Loganovsky, K N; Krasnikova, L I; Bomko, M O; Belyaev, Yu M; Yaroshenko, Zh S; Domashevska, T Ye

    2016-12-01

    It is generally recognized that the Chornobyl nuclear accident caused strong psychosocial stress affecting the entire population of Ukraine, primarily people involved in recovery operations. But what are the reasons? What is the struc ture of stressors? What are their social, medical and biological consequences, what are strategy and preventive meas ures? Issues that require special research and development. To study social and psychological state of the Chornobyl cleanup workers 1986-1987, and to determine regularities of changes and dangerous risk factors. On the basis of Polyclinic of Radiation Registry, NRCRM, we conducted sample epidemiolog ical study of social and psychological state of the Chornobyl clean up workers 1986-1987. We used method of inter viewing based on «questionnaire», specially developed for this purpose. The study was conducted in October 2013 - May 2015. The sample numbered 235 males aged 18-50 at the time of the accident. Their average age was (31.3 ± 5.3) years at the time of the accident and (58.9 ± 5.3) at the time of survey. The results revealed that the Chornobyl nuclear accident and its consequences caused strong social and psychological stress among clean up workers 1986-1987. We have identified a set of factors closely related to the Chornobyl accident, they have caused a sustainable development of mental syndrome - «Anxiety about their own health and the health of family members, especially children». The other set of stressors which are not closely relat ed to the Chornobyl accident but are the result of the social and economic, social and political situation in the coun try. However the former was found to be the cause of such a psychological state as «dissatisfaction with the com pleteness and quality of life». Social and psychological state of the Chornobyl clean up workers 1986-1987 is estimated as «poor» and it integrally can be characterized as a state of chronic psychosocial stress. Mental syndrome

  8. Improved exposure estimation in soil screening and clean-up criteria for volatile organic chemicals.

    Science.gov (United States)

    DeVaull, George E

    2017-02-18

    Soil clean-up criteria define acceptable concentrations of organic chemical constituents for exposed humans. These criteria sum the estimated soil exposure over multiple pathways. Assumptions for ingestion, dermal contact, and dust exposure generally presume a chemical persists in surface soils at a constant concentration level for the entire exposure duration. For volatile chemicals this is an unrealistic assumption. A calculation method is presented for surficial soil criteria which include volatile depletion of chemical for these uptake pathways. The depletion estimates compare favorably with measured concentration profiles and with field measurements of soil concentration. Corresponding volatilization estimates compare favorably with measured data for a wide range of volatile and semi-volatile chemicals, including instances with and without the presence of a mixed-chemical residual phase. Selected examples show application of the revised factors in estimating screening levels for benzene in surficial soils. This article is protected by copyright. All rights reserved.

  9. Sorbent biomaterials for cleaning up hydrocarbon spills on soil and bodies of water

    Directory of Open Access Journals (Sweden)

    Diana Paola Ortíz González

    2010-04-01

    Full Text Available This study was aimed at identifying and evaluating natural organic materials which could be used as sorbents in clean-up operations following hydrocarbons spills on both soils and bodies of water. The sorption capacity of three materials (sugarcane fibre, coco fibre and water Eichornia crassipies was evaluated with three hydrocarbons (35°, 30° and 25°API and two types of water (distilled and artificial marine water adopting the ASTM F-726 standard and following the methodology suggested in the “Oil spill sorbents: testing protocol and certification listing programme” Canadian protocol. It was found that the three materials being evaluated had a sorption capacity equal to or greater than that of the commercial material to which they were compared. It was observed that sorption capacity results depended on some variables such as hydrocarbon viscosity, granulometry (particle size in Tyler sieve and the structure of the material. Sugarcane fibre sorption in water showed the greatest hydrophobicity, different to Eichornia crassipies which is extremely hydrophilic. The materials’ sorption kinetics were determined and modelled with the three hydrocarbons (35°, 30° and 25°API. It was found that the materials became saturated in less than a minute, leading to a rapid alternative for cleaning-up and controlling hydrocarbon spills. Materials were also thermally treated for improving their hydrophobicity and behaviour during spills on bodies of water. Sugarcane fibre was the material which presented the best results with the thermal treatment, followed by water Eichornia crassipies. Coco fibre did not present any significant change in its hydrophobicity.

  10. Extraction and clean-up methods for organochlorine pesticides determination in milk.

    Science.gov (United States)

    Martins, Joana Gomes; Amaya Chávez, Araceli; Waliszewski, Stefan M; Colín Cruz, Arturo; García Fabila, María Magdalena

    2013-07-01

    Organochlorine pesticides (OCPs) can cause environmental damage and human health risks since they are lipophilic compounds with high resistance to degradation and long half-lives in humans. As most persistent OCPs have been banned years ago, it is expected to find these compounds at trace levels in environment. Therefore, increasingly sensitive and reliable analytical techniques are required to ensure effective monitoring of these compounds. The aim of this review is to discuss extraction and clean-up methods used to monitor OCP residues in milk, reported in the last 20 years. To carry out this review, an exhaustive bibliographic review was conducted. Despite the disadvantages of conventional extraction and clean-up methods, such as liquid-liquid, solid-phase or Soxhlet extractions, these procedures are still used due to their reliability. New extraction methods, like solid-phase microextraction, matrix solid-phase dispersion or QuEChERS, have not been thoroughly evaluated for OCP determination in milk. Almost all the methodologies analyzed in this review presented good performance characteristics according to the performance acceptability criteria set in SANCO's procedure. Comparison between limits of quantification (LOQ) and detection (LOD), for the reported methodologies, is not always possible due to the heterogeneity of the units. Thus, researchers should take into account an homogenization of LOD and LOQ units, according to the international regulations and MRLs established. Finally, more research is necessary to obtain the ideal methodology for OCPs determination in milk, which comprises the environmentally friendly characteristics of the new techniques and the reliability of the traditional methodologies. Copyright © 2013 Elsevier Ltd. All rights reserved.

  11. Enamel Surface Roughness after Debonding of Orthodontic Brackets and Various Clean-Up Techniques

    Directory of Open Access Journals (Sweden)

    Farzaneh Ahrari

    2013-01-01

    Full Text Available Objective: This study aimed to evaluate enamel roughness after adhesive removal using different burs and an Er:YAG laser.Materials and Methods: The buccal surfaces of forty human premolars were sealed by two layers of nail varnish, except for a circular area of 3 mm in diameter on the middle third. The enamel surfaces were initially subjected to profilometry analysis and four parameters of surface irregularity (Ra, Rq, Rt and Rz were recorded. Following bracket bonding and debonding, adhesive remnants were removed by tungsten carbide burs in low- or high- speed handpieces (group 1 and 2, respectively, an ultrafine diamond bur (group 3 or an Er:YAG laser (250 mJ, long pulse, 4 Hz (group 4, and surface roughness parameters were measured again. Then, the buccal surfaces were polished and the third profilometry measurements were performed.Results: The specimens that were cleaned with a low speed tungsten carbide bur showed no significant difference in surface irregularity between the different treatment stages (p>0.05. Surface roughness increased significantly after clean-up with the diamond bur and the Er:YAG laser (p<0.01. In comparison between groups, adhesive removal with tungsten carbide burs at slow- or high-speed handpieces produced the lowest, while enamel clean-up with the Er:YAG laser caused the highest values of roughness measurements (P<0.05.Conclusion: Under the study conditions, application of the ultrafine diamond bur or the Er:YAG laser caused irreversible enamel damage on tooth surface, and thus these methods could not be recommended for removing adhesive remnants after debonding of orthodontic brackets.

  12. Mercury and Cyanide Contaminations in Gold Mine Environment and Possible Solution of Cleaning Up by Using Phytoextraction

    Directory of Open Access Journals (Sweden)

    NURIL HIDAYATI

    2009-09-01

    Full Text Available Water contamination with heavy metals, mainly mercury and cyanide (CN due to small scale of public mines and large scale of industrial mines have been in concern to residents around the area. Surveys of heavy metal contamination in aquatic environments, such as rivers and paddy fields over two gold mine areas in West Jawa were conducted and possible solution of using indigenous plants for phytoremediation was studied. The results showed that most of the rivers and other aquatic environments were affected by gold mine activities. Rivers, ponds, and paddy fields around illegal public mines were mostly contaminated by mercury in considerably high levels, such as paddy fields in two locations (Nunggul and Leuwijamang, Pongkor were contaminated up to 22.68 and 7.73 ppm of Hg, respectively. Whereas rivers located around large scale industrial mines were contaminated by CN. Possible solution of cleaning up by using green technology of phytoremediation was examined. Some plant species grew in the contaminated sites showed high tolerance and potentially effective in accumulating cyanide or mercury in their roots and above ground portions. Lindernia crustacea (L. F.M., Digitaria radicosa (Presl Miq, Paspalum conjugatum, Cyperus kyllingia accumulated 89.13, 50.93, 1.78, and 0.77 ppm of Hg, respectively. Whereas, Paspalum conjugatum, Cyperus kyllingia accumulated 16.52 and 33. 16 ppm of CN respectively.

  13. A cross-site comparison of methods used for hydrogeologic characterization of the Galena-Platteville aquifer in Illinois and Wisconsin, with examples from selected Superfund sites

    Science.gov (United States)

    Kay, Robert T.; Mills, Patrick C.; Dunning, Charles P.; Yeskis, Douglas J.; Ursic, James R.; Vendl, Mark

    2004-01-01

    The effectiveness of 28 methods used to characterize the fractured Galena-Platteville aquifer at eight sites in northern Illinois and Wisconsin is evaluated. Analysis of government databases, previous investigations, topographic maps, aerial photographs, and outcrops was essential to understanding the hydrogeology in the area to be investigated. The effectiveness of surface-geophysical methods depended on site geology. Lithologic logging provided essential information for site characterization. Cores were used for stratigraphy and geotechnical analysis. Natural-gamma logging helped identify the effect of lithology on the location of secondary- permeability features. Caliper logging identified large secondary-permeability features. Neutron logs identified trends in matrix porosity. Acoustic-televiewer logs identified numerous secondary-permeability features and their orientation. Borehole-camera logs also identified a number of secondary-permeability features. Borehole ground-penetrating radar identified lithologic and secondary-permeability features. However, the accuracy and completeness of this method is uncertain. Single-point-resistance, density, and normal resistivity logs were of limited use. Water-level and water-quality data identified flow directions and indicated the horizontal and vertical distribution of aquifer permeability and the depth of the permeable features. Temperature, spontaneous potential, and fluid-resistivity logging identified few secondary-permeability features at some sites and several features at others. Flowmeter logging was the most effective geophysical method for characterizing secondary-permeability features. Aquifer tests provided insight into the permeability distribution, identified hydraulically interconnected features, the presence of heterogeneity and anisotropy, and determined effective porosity. Aquifer heterogeneity prevented calculation of accurate hydraulic properties from some tests. Different methods, such as flowmeter

  14. Assessment of subsurface chlorinated solvent contamination using tree cores at the front street site and a former dry cleaning facility at the Riverfront Superfund site, New Haven, Missouri, 1999-2003

    Science.gov (United States)

    Schumacher, John G.; Struckhoff, Garrett C.; Burken, Joel G.

    2004-01-01

    Tree-core sampling has been a reliable and inexpensive tool to quickly assess the presence of shallow (less than about 30 feet deep) tetrachloroethene (PCE) and trichloroethene (TCE) contamination in soils and ground water at the Riverfront Superfund Site. This report presents the results of tree-core sampling that was successfully used to determine the presence and extent of chlorinated solvent contamination at two sites, the Front Street site (operable unit OU1) and the former dry cleaning facility, that are part of the overall Riverfront Superfund Site. Traditional soil and ground-water sampling at these two sites later confirmed the results from the tree-core sampling. Results obtained from the tree-core sampling were used to design and focus subsequent soil and ground-water investigations, resulting in substantial savings in time and site assessment costs. The Front Street site is a small (less than 1-acre) site located on the Missouri River alluvium in downtown New Haven, Missouri, about 500 feet from the south bank of the Missouri River. Tree-core sampling detected the presence of subsurface PCE contamination at the Front Street site and beneath residential property downgradient from the site. Core samples from trees at the site contained PCE concentrations as large as 3,850 mg-h/kg (micrograms in headspace per kilogram of wet core) and TCE concentrations as large as 249 mg-h/kg. Soils at the Front Street site contained PCE concentrations as large as 6,200,000 mg/kg (micrograms per kilogram) and ground-water samples contained PCE concentrations as large as 11,000 mg/L (micrograms per liter). The former dry cleaning facility is located at the base of the upland that forms the south bank of the Missouri River alluvial valley. Tree-core sampling did not indicate the presence of PCE or TCE contamination at the former dry cleaning facility, a finding that was later confirmed by the analyses of soil samples collected from the site. The lateral extent of PCE

  15. Comparison of clean-up methods for ochratoxin A on wine, beer, roasted coffee and chili commercialized in Italy.

    Science.gov (United States)

    Prelle, Ambra; Spadaro, Davide; Denca, Aleksandra; Garibaldi, Angelo; Gullino, Maria Lodovica

    2013-10-22

    The most common technique used to detect ochratoxin A (OTA) in food matrices is based on extraction, clean-up, and chromatography detection. Different clean-up cartridges, such as immunoaffinity columns (IAC), molecular imprinting polymers (MIP), Mycosep™ 229, Mycospin™, and Oasis® HLB (Hydrophilic Lipophilic balance) as solid phase extraction were tested to optimize the purification for red wine, beer, roasted coffee and chili. Recovery, reproducibility, reproducibility, limit of detection (LOD) and limit of quantification (LOQ) were calculated for each clean-up method. IAC demonstrated to be suitable for OTA analysis in wine and beer with recovery rate >90%, as well as Mycosep™ for wine and chili. On the contrary, MIP columns were the most appropriate to clean up coffee. A total of 120 samples (30 wines, 30 beers, 30 roasted coffee, 30 chili) marketed in Italy were analyzed, by applying the developed clean-up methods. Twenty-seven out of 120 samples analyzed (22.7%: two wines, five beers, eight coffees, and 12 chili) resulted positive to OTA. A higher incidence of OTA was found in chili (40.0%) more than wine (6.6%), beers (16.6%) and coffee (26.6%). Moreover, OTA concentration in chili was the highest detected, reaching 47.8 µg/kg. Furthermore, three samples (2.5%), two wines and one chili, exceeded the European threshold.

  16. Comparison of Clean-Up Methods for Ochratoxin A on Wine, Beer, Roasted Coffee and Chili Commercialized in Italy

    Directory of Open Access Journals (Sweden)

    Ambra Prelle

    2013-10-01

    Full Text Available The most common technique used to detect ochratoxin A (OTA in food matrices is based on extraction, clean-up, and chromatography detection. Different clean-up cartridges, such as immunoaffinity columns (IAC, molecular imprinting polymers (MIP, Mycosep™ 229, Mycospin™, and Oasis® HLB (Hydrophilic Lipophilic balance as solid phase extraction were tested to optimize the purification for red wine, beer, roasted coffee and chili. Recovery, reproducibility, reproducibility, limit of detection (LOD and limit of quantification (LOQ were calculated for each clean-up method. IAC demonstrated to be suitable for OTA analysis in wine and beer with recovery rate >90%, as well as Mycosep™ for wine and chili. On the contrary, MIP columns were the most appropriate to clean up coffee. A total of 120 samples (30 wines, 30 beers, 30 roasted coffee, 30 chili marketed in Italy were analyzed, by applying the developed clean-up methods. Twenty-seven out of 120 samples analyzed (22.7%: two wines, five beers, eight coffees, and 12 chili resulted positive to OTA. A higher incidence of OTA was found in chili (40.0% more than wine (6.6%, beers (16.6% and coffee (26.6%. Moreover, OTA concentration in chili was the highest detected, reaching 47.8 µg/kg. Furthermore, three samples (2.5%, two wines and one chili, exceeded the European threshold.

  17. Comparison of Clean-Up Methods for Ochratoxin A on Wine, Beer, Roasted Coffee and Chili Commercialized in Italy

    Science.gov (United States)

    Prelle, Ambra; Spadaro, Davide; Denca, Aleksandra; Garibaldi, Angelo; Gullino, Maria Lodovica

    2013-01-01

    The most common technique used to detect ochratoxin A (OTA) in food matrices is based on extraction, clean-up, and chromatography detection. Different clean-up cartridges, such as immunoaffinity columns (IAC), molecular imprinting polymers (MIP), Mycosep™ 229, Mycospin™, and Oasis® HLB (Hydrophilic Lipophilic balance) as solid phase extraction were tested to optimize the purification for red wine, beer, roasted coffee and chili. Recovery, reproducibility, reproducibility, limit of detection (LOD) and limit of quantification (LOQ) were calculated for each clean-up method. IAC demonstrated to be suitable for OTA analysis in wine and beer with recovery rate >90%, as well as Mycosep™ for wine and chili. On the contrary, MIP columns were the most appropriate to clean up coffee. A total of 120 samples (30 wines, 30 beers, 30 roasted coffee, 30 chili) marketed in Italy were analyzed, by applying the developed clean-up methods. Twenty-seven out of 120 samples analyzed (22.7%: two wines, five beers, eight coffees, and 12 chili) resulted positive to OTA. A higher incidence of OTA was found in chili (40.0%) more than wine (6.6%), beers (16.6%) and coffee (26.6%). Moreover, OTA concentration in chili was the highest detected, reaching 47.8 µg/kg. Furthermore, three samples (2.5%), two wines and one chili, exceeded the European threshold. PMID:24152987

  18. Evaluation of modeling for groundwater flow and tetrachloroethylene transport in the Milford-Souhegan glacial-drift aquifer at the Savage Municipal Well Superfund site, Milford, New Hampshire, 2011

    Science.gov (United States)

    Harte, Philip T.

    2012-01-01

    The U.S. Geological Survey and the New Hampshire Department of Environmental Services entered into a cooperative agreement to assist in the evaluation of remedy simulations of the MSGD aquifer that are being performed by various parties to track the remedial progress of the PCE plume. This report summarizes findings from this evaluation. Topics covered include description of groundwater flow and transport models used in the study of the Savage Superfund site (section 2), evaluation of models and their results (section 3), testing of several new simulations (section 4), an assessment of the representation of models to simulate field conditions (section 5), and an assessment of models as a tool in remedial operational decision making (section 6).

  19. 75 FR 49414 - Cooperative Agreements and Superfund State Contracts for Superfund Response Actions

    Science.gov (United States)

    2010-08-13

    ... AGENCY 40 CFR Part 35 RIN 2050-AG58 Cooperative Agreements and Superfund State Contracts for Superfund... Superfund Cooperative Agreements and Superfund State Contracts. DATES: This rule is effective October 12... requirements shall apply to all new Cooperative Agreements and Superfund State Contracts, funded under...

  20. Biochemical observations relating to oxidant stress injury in Chernobyl clean-up workers ("liquidators") from Latvia.

    Science.gov (United States)

    Skesters, Andrejs; Zvagule, T; Silova, A; Rusakova, N; Larmane, L; Reste, J; Eglite, M; Rainsford, K D; Callingham, B A; Bake, M-A; Lece, A

    2010-02-01

    To establish if there is further evidence for the long-term oxidant stress injury (as reported previously--Kumerova et al. in Biol Trace Elem Res 77:1-12, 2000) in surviving Chernobyl nuclear power plant (NPP) workers from Latvia. The overall objectives of this study have been to establish if there have been long-term systemic changes in the oxidant/antioxidant status of clean-up workers that might reflect adaptation to the progression of oxidative stress injury. Biochemical analyses of the circulating levels of endogenous oxidants and anti-oxidants were undertaken over two periods (Stage 1 in 1998-1999 and Stage 2 in 2005-2006) at approximately 6-7 years time interval, in order to establish if there have been time-dependent changes in the parameters that may be important for the health of the clean-up workers. The biochemical analyses included (a) plasma levels of the anti-oxidant, selenium, (b) blood and plasma levels of glutathione peroxidase, (c) red blood cell catalase, (d) plasma total oxidant status as lipid peroxides and hydroperoxides, (e) plasma ceruloplasmin, and (f) total blood levels of zinc and copper. The circulating content of lipid peroxides, plasma oxidisability, lipid peroxides, catalase, Zn, and Cu were elevated above normal values at both the stages of this study. Glutathione peroxidase was increased above normal values at Stage 1 but not at Stage 2. The most pronounced changes between Stage 1 and Stage 2 were (a) a reduction by about (1/2) in the content of lipid peroxides and lipid peroxidation, but not in the blood oxidisability and (b) increased plasma selenium. The data show that there may be a partial improvement in the anti-oxidant/oxidant status of the Chernobyl NPP workers over the 7-year period of investigation. The NPP patients may be undergoing progressive reduction in blood oxidants accompanied by adaptation to oxidant stress injury due to the increased anti-oxidant activity measured in their plasma and blood.

  1. Validation of extraction, clean-up and DR CALUX {sup registered} bioanalysis. Pt. I. Feedingstuff

    Energy Technology Data Exchange (ETDEWEB)

    Besselink, H.; Jonas, A.; Brouwer, B. [BioDetection Systems BV (BDS), Amsterdam (Netherlands); Pijnappels, M.; Swinkels, A. [Masterlab BV, Boxmeer (Netherlands)

    2004-09-15

    Feed safety is a high priority issue for the feed sector as it directly impacts at the beginning of the food-chain. Currently stringent EU limit values are in force for dioxins in feedingstuffs for animal and public health protection. Biodetection Systems BV's (BDS) DR CALUX {sup registered} bioassay is a cost-effective and rapid method to measure low levels of dioxins and dioxin-like compounds in various matrices. The use of bioassays for monitoring dioxins in feed allows the (pre)-selection of samples suspected of being contaminated above limit values with dioxins. To permit bioassays to be used for screening feedingstuffs for the presence of dioxins and related compounds, the EU has laid down general requirements for the determination of dioxins and dioxin-like PCBs in feedingstuffs and specific requirements for cell-based bioassays. To ensure reliability the DR CALUX {sup registered} bioassay, validated methods for extraction and DR CALUX {sup registered} analysis are necessary. Within the framework of the development of DR CALUX {sup registered} analysis methods, extraction and clean-up methods for 13 feedingstuffs were evaluated, selected and validated. In this paper we present the results of this substantive multi-matrix feedingstuffs validation study.

  2. Diving behaviour of wildlife impacted by an oil spill: A clean-up and rehabilitation success?

    Science.gov (United States)

    Chilvers, B L; Morgan, K M; Finlayson, G; Sievwright, K A

    2015-11-15

    The value of rehabilitating oiled wildlife is an on-going global debate. On October 5, 2011, the cargo vessel C/V Rena grounded on Astrolabe Reef, New Zealand (NZ), spilling over 300 tonnes of heavy fuel oil. As part of the Rena oil spill response, 383 little blue penguins (LBP, Eudyptula minor) were captured, cleaned, rehabilitated and released back into a cleaned environment. This research investigates foraging behaviour changes due either to the oil spill or by the rehabilitation process by comparing the diving behaviour of rehabilitated (n=8) and non-rehabilitated (n=6) LBPs and with LBP populations throughout NZ. Stabile isotope analysis of feathers was also used to investigate diet. There were no foraging behaviour differences between rehabilitated and non-rehabilitated LBPs and the overall diving behaviour of these LBPs have similar, if not less energetic, foraging behaviour than other LBPs in NZ. This suggests the rehabilitation process and clean-up undertaken after the Rena appears effective and helps justify the rehabilitation of oiled wildlife across the world.

  3. Cancer incidence and thyroid disease among Estonian Chernobyl clean-up workers

    Energy Technology Data Exchange (ETDEWEB)

    Auvinen, A.; Salomaa, S. [eds.] [Radiation and Nuclear Safety Authority, Helsinki (Finland); Rahu, M.; Veidebaum, T.; Tekkel, M. [eds.] [Inst. of Experimental and Clinical Medicine, Tallinn (Estonia); Hakulinen, T. [ed.] [Finnish Cancer Registry, Helsinki (Finland); Boice, J.D. Jr. [ed.] [Int. Epidemiology Inst., MD (United States)

    1998-09-01

    The report describes the development and summarizes the results of the project Cancer incidence and thyroid disease among Estonian Chernobyl clean-up workers. One of the goals of the report is to give research protocols and questionnaires for researchers involved in other studies. Eight previously published articles are also included summarizing the results. The development of the collaboration work of the project is described in the introduction of the report. Epidemiological methods are described in an article complemented by the protocol and English version of the questionnaire administered to all cleanup workers, as well as the data collection form of the thyroid study. The results from biological biodosimetry using both glycophorin A and FISH methods have shown that the radiation doses received by the Chernobyl cleanup workers were relatively low. Thyroid nodularity was not associated with any radiation exposure characteristic in the thyroid screening study. Estonian Chernobyl cleanup workers were followed up for cancer incidence through the Estonian Cancer Registry. No cases of leukemia or thyroid cancer were observed by the end of 1993. It is too early to observe possible effect on other types of cancer. However, mortality from suicides was increased compared with general population. Further follow-up and the extension to other Baltic countries in the future will undoubtedly strengthen the study. There are also plans for future projects covering areas from psychosocial factors to radiation biology

  4. Commissioning of the catalytic plasma exhaust clean-up facility caprice and first experimental results

    Energy Technology Data Exchange (ETDEWEB)

    Glugla, M.; Kraemer, R.; Penzhorn, R.D.; Le, T.L.; Simon, K.H.; Guenther, K.; Besserer, U.; Schaefer, P.; Hellriegel, W. [Research Center Karlsruhe (Germany); Geissler, H. [Kraftanlagen Heidelberg (Germany)

    1995-10-01

    A fuel clean-up process for all plasma exhaust gases from DT fusion machines, based on catalytic conversion reactions combined with permeation of hydrogen isotopes through palladium/silver, has been developed. The complete process has already been proven with relevant concentrations of tritium at laboratory scale. On the basis of the results obtained the technical facility `CAPRICE` was designed, and is now under tritium operation at the Tritium Laboratory Karlsruhe (TLK). The facility is being used to demonstrate the process on a target throughput of 10 mol/h DT and 1 mol/h tritiated and non-tritiated impurities. Full scale experiments with hydrogen and deuterium have been completed to verify the design parameters of the facility and to gain detailed knowledge on the performance of the different subsystems under a variety of experimental conditions. Decontamination factors were obtained from these experiments as well as from first tritium runs employing about 350 Ci (0.5%) tritium in deuterium. 4 refs., 6 figs., 1 tab.

  5. Simulation of solute transport of tetrachloroethylene in ground water of the glacial-drift aquifer at the Savage Municipal Well Superfund Site, Milford, New Hampshire, 1960-2000

    Science.gov (United States)

    Harte, Philip T.

    2004-01-01

    The Savage Municipal Well Superfund site, named after the former municipal water-supply well for the town of Milford, is underlain by a 0.5-square mile plume of volatile organic compounds (VOCs), primarily tetrachloroethylene (PCE). The plume occurs mostly within a highly transmissive sand-and-gravel unit, but also extends to an underlying till and bedrock unit. The plume logistically is divided into two areas termed Operable Unit No. 1 (OU1), which contains the primary source area, and Operable Unit No. 2 (OU2), which is the extended plume area. PCE concentrations in excess of 100,000 parts per billion (ppb) had been detected in the OU1 area in 1995, indicating a likely Dense Non-Aqueous Phase Liquid (DNAPL) source. In the fall of 1998, the New Hampshire Department of Environmental Services (NHDES) and the U.S. Environmental Protection Agency (USEPA) installed a remedial system in OU1. The OU1 remedial system includes a low-permeability barrier that encircles the highest detected concentrations of PCE, and a series of injection and extraction wells. The barrier primarily sits atop bedrock and penetrates the full thickness of the sand and gravel; and in some places, the full thickness of the underlying basal till. The sand and gravel unit and the till comprise the aquifer termed the Milford-Souhegan glacial-drift aquifer (MSGD). Two-dimensional and three-dimensional finite-difference solute-transport models of the unconsolidated sediments (MSGD aquifer) were constructed to help evaluate solute-transport processes, assess the effectiveness of remedial activities in OU1, and to help design remedial strategies in OU2. The solute-transport models simulate PCE concentrations, and model results were compared to observed concentrations of PCE. Simulations were grouped into the following three time periods: an historical calibration of the distribution of PCE from the initial input (circa 1960) of PCE into the subsurface to the 1990s, a pre-remedial calibration from 1995

  6. Borehole geophysical logging and aquifer-isolation tests conducted in well MG-1693 at North Penn Area 5 Superfund Site near Colmar, Montgomery County, Pennsylvania

    Science.gov (United States)

    Bird, Philip H.

    2006-01-01

    Borehole geophysical logging and aquifer-isolation (packer) tests were conducted in well MG-1693 (NP-87) at the North Penn Area 5 Superfund Site near Colmar, Montgomery County, Pa. Objectives of the study were to identify the depth and yield of water-bearing zones, occurrence of vertical borehole flow, and effects of pumping on water levels in nearby wells. Caliper, natural-gamma, single-point-resistance, fluid-temperature, fluid-resistivity, heatpulse-flowmeter, and borehole-video logs were collected. Vertical borehole-fluid movement direction and rate were measured under nonpumping conditions. The suite of logs was used to locate water-bearing fractures, determine zones of vertical borehole-fluid movement, and select depths to set packers. Aquifer-isolation tests were conducted to sample discrete intervals and to determine specific capacities of water-bearing zones and effects of pumping individual zones on water levels in two nearby monitor wells. Specific capacities of isolated zones during aquifer-isolation tests ranged from 0.03 to 3.09 (gal/min)/ft (gallons per minute per foot). Fractures identified by borehole geophysical methods as water-producing or water-receiving zones produced water when isolated and pumped. Water enters the borehole primarily through high-angle fractures at 416 to 435 ft bls (feet below land surface) and 129 to 136 ft bls. Water exits the borehole through a high-angle fracture at 104 to 107 ft bls, a broken casing joint at 82 ft bls, and sometimes as artesian flow through the top of the well. Thirteen intervals were selected for aquifer-isolation testing, using a straddle-packer assembly. The specific capacity of interval 1 was 2.09 (gal/min)/ft. The specific capacities of intervals 2, 3, and 4 were similar: 0.27, 0.30, and 0.29 (gal/min)/ft,respectively. The specific capacities of intervals 5, 6, 7, 8, and 10 were similar: 0.03, 0.04, 0.09, 0.09, and 0.04 (gal/min)/ft,respectively. Intervals 9, 11, and 12 each showed a strong

  7. Use of molecularly imprinted solid-phase extraction for the selective clean-up of clenbuterol from calf urine

    NARCIS (Netherlands)

    Berggren, C; Bayoudh, S; Sherrington, D; Ensing, K

    2000-01-01

    A feasibility study was performed in order to study the possibilities in using molecularly imprinted polymers (MIPs) as sorbent material in solid-phase extraction (MISPE) for clean-up of clenbuterol from urine. A binding study of clenbuterol in several solvents was performed on a clenbuterol imprint

  8. Methode van onderzoek voor residuen van bestrijdingsmiddelen na clean-up m.b.v. gelpermeatiechromatografie (GPC) (Multimethode 12)

    NARCIS (Netherlands)

    Greve PA

    1988-01-01

    In dit rapport wordt een methode gegeven voor de clean-up van extracten m.b.v. gelpermeatie-chromatografie (GPC) t.b.v. de bepaling van residuen van electroncaptieve en organofosforbestrijdingsmiddelen. Een oudere versie van de GPC-methode, die alleen de organochloorbestrijdingsmiddelen omvatte,

  9. Rapid and simple clean-up and derivatizaton procedure for the gas chromatographic determination of acidic drugs in plasma

    NARCIS (Netherlands)

    Roseboom, H.; Hulshoff, A.

    1979-01-01

    A rapid and simple clean-up and derivatization procedure that can be generally applied to the gas chromatographie (GC) determination of acidic drugs of various chemical and therapeutic classes is described. The drugs are extracted from acidified plasma with chloroform containing 5% of isopropanol, w

  10. Cleaning up: environmental services are bound to stay a growth industry

    Energy Technology Data Exchange (ETDEWEB)

    Stonehouse, D.

    2000-05-01

    Environmental protection regulations with particular regard for the oil and natural gas industry are reviewed. New flaring regulations will be reduced by 70 per cent within the next seven years and remaining flares will operate at nearly 100 per cent efficiency in burning harmful substances. The Canadian Council of Ministers of the Environment (CCME) is currently targeting other emission sources from oilfield equipment. Benzene emissions from glycol dehydrators will be reduced by 90 per cent by 2007. Soil remediation targets are also very ambitious. The standard is 1,000 parts per million of hydrocarbons. As an indication of the difficulties experienced by oil companies in land reclamation, one out of five topsoil replacement and revegetation applications have failed. As a result of these stringent regulations, a multi-billion dollar environmental industry has emerged, constantly searching for better and more cost effective ways to comply with rising standards. The most immediate challenge is to snuff out some 5,300 flare stacks. The science behind environmental protection is still weak and controversial, and satisfactory answers are still some years away; in the meantime oil companies must meet existing requirements, inventing new equipment and approaches in the process. Incineration may be one answer, but alternative approaches are also being investigated. Wellsite reclamation, cleaning up of exhausted fields, identifying and preserving wild animal habitats, protecting endangered species, accounting for human populations and their effects, greenhouse gas emissions and the complex issues of emissions trading and credits are just some of the issues that will ensure that environmental services will continue to be a growth industry.

  11. Results of a monitoring program of continuous water levels and physical water properties at the Operable Unit 1 area of the Savage Municipal Well Superfund site, Milford, New Hampshire, water years 2000-03

    Science.gov (United States)

    Harte, Philip T.

    2005-01-01

    The Milford-Souhegan glacial-drift (MSGD) aquifer, in south-central New Hampshire, is an important source of industrial, commercial, and domestic water. The MSGD aquifer was also an important source of drinking water for the town of Milford until it was found to contain high concentrations of volatile organic compounds (VOCs) in the Savage and Keyes municipal-supply wells in the early 1980s. A VOC plume was found to cover part of the southwestern half of the MSGD aquifer. In September 1984, the site was designated a Superfund site, called the Savage Municipal Well Superfund site. The primary source area of contaminants was a former tool manufacturing facility (called the OK Tool facility, and now called the Operable Unit 1 (OU1) area) that disposed of solvents at the surface and in the subsurface. The facility was closed in 1987 and removed in 1998. A low-permeability containment barrier wall was constructed and installed in the overburden (MSGD aquifer) in 1998 to encapsulate the highest concentrations of VOCs, and a pump-and-treat remediation facility was also added. Remedial operations of extraction and injection wells started in May 1999. A network of water-level monitoring sites was implemented in water year 2000 (October 1, 1999, through September 30, 2000) in the OU1 area to help assess the effectiveness of remedial operations to mitigate the VOC plume, and to evaluate the effect of the barrier wall and remedial operations on the hydraulic connections across the barrier and between the overburden and underlying bedrock. Remedial extraction and injections wells inside and outside the barrier help isolate ground-water flow inside the barrier and the further spreading of VOCs. This report summarizes both continuous and selected periodic manual measurements of water level and physical water properties (specific conductance and water temperature) for 10 monitoring locations during water years 2000-03. Additional periodic manual measurements of water levels were

  12. Acetonitrile extraction and dual-layer solid phase extraction clean-up for pesticide residue analysis in propolis.

    Science.gov (United States)

    Oellig, Claudia

    2016-05-06

    Propolis is a very complex mixture of substances that is produced by honey bees and is known to be a rather challenging matrix for residue analysis. Besides resins, flavonoids and phenols, high amount of wax is co-extracted resulting in immense matrix effects. Therefore a suitable clean-up is crucial and indispensable. In this study, a reliable solid phase extraction (SPE) clean-up was developed for pesticide residue analysis in propolis. The clean-up success was quickly and easily monitored by high-performance thin-layer chromatography with different detection possibilities. The final method consists of the extraction of propolis with acetonitrile according to the QuEChERS method followed by an effective extract purification on dual-layer SPE cartridges with spherical hydrophobic polystyrene-divinylbenzene resin/primary secondary amine as sorbent and a mixture of toluene/acetone (95:5, v/v) for elution. Besides fat-soluble components like waxes, flavonoids, and terpenoids, more polar compounds like organic acids, fatty acids, sugars and anthocyanins were also removed to large extent. Method performance was assessed by recovery experiments at spiking levels of 0.5 and 1mg/kg (n=5) for fourteen pesticides that are relevant for propolis. Mean recoveries determined by HPLC-MS against solvent standards were between 40 and 101%, while calculation against matrix-matched standards provided recoveries of 79-104%. Precision of recovery, assessed by relative standard deviations, were below 9%. Thus, the developed dual-layer SPE clean-up enables the reliable pesticide residue analysis in propolis and provides a suitable alternative to time-consuming clean-up procedures proposed in literature.

  13. Site Features

    Data.gov (United States)

    U.S. Environmental Protection Agency — This dataset consists of various site features from multiple Superfund sites in U.S. EPA Region 8. These data were acquired from multiple sources at different times...

  14. Region 9 Removal Sites

    Data.gov (United States)

    U.S. Environmental Protection Agency — Point geospatial dataset representing locations of CERCLA (Superfund) Removal sites. CERCLA (Comprehensive Environmental Response, Compensation, and Liability Act)...

  15. Report: EPA’s Distribution of Superfund Human Resources Does Not Support Current Regional Workload

    Science.gov (United States)

    Report #17-P-0397, September 19, 2017. Due to insufficient human resources to cover all Superfund site work, some regions have had to slow down or discontinue their efforts to protect human health and the environment.

  16. Ultrasonic extraction followed by a novel filtration and clean-up device for screening of some polyphenols in tobaccos.

    Science.gov (United States)

    Gu, Xungang; Cai, Jibao; Yang, Jun; Su, Qingde

    2005-02-01

    A simple and efficient HPLC method using a diode array detector (DAD) was developed for simultaneous determination of six polyphenols in tobaccos. Ultrasonic extraction was employed at 25 degrees C to extract the polyphenols present in tobaccos into anhydrous methanol. A novel filtration device linked to a clean-up cartridge was designed for simultaneous extract filtration and clean-up. Optimized HPLC-DAD analysis, with multi-wavelength detection, was used for determination of the polyphenols. Because the content of some of the polyphenols is too low to be quantified directly, a concentration step was necessary. Anhydrous methanol was employed for extraction of the polyphenols because of its high extraction efficiency and its low boiling point in the concentration step. Using the proposed method, six polyphenols were quantified in tobaccos (Nicotina tobaccum L.).

  17. Analysis of polycyclic aromatic hydrocarbons in vegetable oils combining gel permeation chromatography with solid-phase extraction clean-up

    DEFF Research Database (Denmark)

    Fromberg, Arvid; Højgård, A.; Duedahl-Olesen, Lene

    2007-01-01

    of benzo[a]pyrene levels in foods laid down by the Commission of the European Communities. A survey of 69 vegetable oils sampled from the Danish market included olive oil as well as other vegetable oils such as rapeseed oil, sunflower oil, grape seed oil and sesame oil. Levels of benzo[a]pyrene in all......A semi-automatic method for the determination of polycyclic aromatic hydrocarbons (PAHs) in edible oils using a combined gel permeation chromatography/solid-phase extraction (GPC/SPE) clean-up is presented. The method takes advantage of automatic injections using a Gilson ASPEC XL sample handling...... system equipped with a GPC column (S-X3) and pre-packed silica SPE columns for the subsequent clean-up and finally gas chromatography-mass spectrometry (GC-MS) determination. The method was validated for the determination of PAHs in vegetable oils and it can meet the criteria for the official control...

  18. Clean-up of the sea bed in the North Sea 1996; Opprydding av havbunnen i Nordsjoeen 1996

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    1997-01-01

    The petroleum activities in the North Sea have inadvertently caused some conflict with fishermen getting their trawls etc. into trash from littering of the sea bed. In the present report, the Norwegian Petroleum Directorate describes a clean-up operation undertaken in 1996 and paid by the State. A clean-up area of 1000 km{sup 2} off Karmoey was selected. This area was mapped by side scan sonar along survey lines 300 m equidistant and a sonar range of 200 m. The sonar data were continuously interpreted by a geophysicist. Selected targets were then identified by ROV and eventually removed. Of the 59 targets examined, 11 were removed and dumped onshore. The largest part elevated was a chain cable of 9 tons. There is also a brief discussion of the compensation agreement with Norwegian fishermen. 4 figs.

  19. Long term evolution of recycled DIAMEX solvent properties under hydrolysis and radiolysis with or without solvent clean-up

    Energy Technology Data Exchange (ETDEWEB)

    Cames, B.; Saucerotte, B.; Faucon, M.; Rudloff, D.; Gastaldi, M.; Bisel, I

    2004-07-01

    As part of the SPIN program, CEA has developed DIAMEX process allowing co-extraction of actinides(III) and lanthanides(III) thanks to a diamide extractant, the Di-Methyl Di-Octyl Hexyl-Ethoxy Malonamide, symbolized by DMDOHEMA. Along the different process steps, diamide undergoes radiolytic and hydrolytic degradation leading to reaction products changing extraction performances and hydrodynamic behavior of the solvent. If to be industrially used, extractant has to be recycled. Therefore an alkaline solvent clean-up step has been defined to remove acidic degradation products whose modifying extraction properties. Nevertheless long-term recycling may allow accumulation of amounts of products which can influence process operating and separation performances. MARCEL is a laboratory scale bench mark, simulating chemical and radiolytic conditions of the process, designed for the long term evolution studies of the recycled solvent properties. Extraction, scrubbing and stripping are performed in mixer-settlers whereas centrifugal contactors are used for solvent clean-up. Different flow-sheets have been tested through various runs during about 200 hours each: - Hydrolysis with or without solvent clean-up; - Hydrolysis coupled with radiolysis with solvent clean-up. For each solvent cycle, DMDOHEMA undergoes a 2.5 hours hydrolysis at 40 deg C and, if radiolysis is studied, a 8.5 kGy exposure. Solvent properties have been followed-up by steady tests (viscosity, density, surface tension, refraction index, phase settling time ratio (RTD), distribution coefficients of several cations) and quantitative analysis of the degradation products. The efficiency and correct hydrodynamic behavior of the alkaline treatment has been shown, remaining hydrolysis and radiolysis degradation products having no significant influence on solvent properties. (authors)

  20. Evaluation of alternative PCB clean-up strategies using an individual-based population model of mink

    Energy Technology Data Exchange (ETDEWEB)

    Salice, Christopher J., E-mail: Chris.salice@ttu.edu [Department of Environmental Toxicology, Texas Tech University, Lubbock, TX 79410 (United States); Sample, Bradley E., E-mail: bsample@ecorisk.com [Ecological Risk Inc., Rancho Murieta, CA 95683 (United States); Miller Neilan, Rachael; Rose, Kenneth A.; Sable, Shaye [Department of Oceanography and Coastal Sciences, Energy, Coast and Environment Building, Louisiana State University, Baton Rouge, LA 70803 (United States)

    2011-12-15

    Population models can be used to place observed toxic effects into an assessment of the impacts on population-level endpoints, which are generally considered to provide greater ecological insight and relevance. We used an individual-based model of mink to evaluate the population-level effects of exposure to polychlorinated biphenyls (PCBs) and the impact that different remediation strategies had on mink population endpoints (population size and extinction risk). Our simulations indicated that the initial population size had a strong impact on mink population dynamics. In addition, mink populations were extremely responsive to clean-up scenarios that were initiated soon after the contamination event. In fact, the rate of PCB clean-up did not have as strong a positive effect on mink as did the initiation of clean-up (start time). We show that population-level approaches can be used to understand adverse effects of contamination and to also explore the potential benefits of various remediation strategies. - Highlights: > We used an individual-based model of mink to evaluate population-level impacts of PCB contamination. > The model was also used to explore the population responses to different PCB remediation strategies. > Population size had a large impact on whether mink populations persisted or went extinct. > Starting remediation sooner had a stronger positive effect on mink populations than did the rate of PCB clean-up. > Individual-based models are useful in understanding effects of contamination and different remediation strategies. - An individual-based model of mink showed strong population-level effects of PCB contamination and provided insight into optimal PCB remediation strategies.

  1. Novel fracture technology proves marginal Viking prospect economic, part II: Well clean-up, flowback and testing

    Energy Technology Data Exchange (ETDEWEB)

    Haidar, S.; Rylance, M.; Tybero, G. [and others

    1996-12-31

    Having completed both fracture treatments as discussed in a companion paper, this paper continues on to describe the post fracture shut-in, clean-up and well testing operations that took place on the Viking Wx exploration well 49/17-12. These operations involved the removal of Resin Coated Proppant (RCP) from the wellbore, via Coiled Tubing (CT), through the use of a specially designed jetting nozzle. The RCP pack stability at a concentration of 3.0 lb/ft{sup 2} (as per planned design) had already been tested in a flowback cell. The use of a Surface Read-Out (SRO) gauge, combined with gas, water and proppant flow rates as well as the viscosity of fracturing fluids returns, enabled real time calculation of the drag forces, on the proppant pack, during clean-up. The flow rate, in the field, was controlled such that the calculated drag forces remained below those observed in the laboratory. Following the clean-up a flow and build-up test was conducted, to evaluate the fracture half length and fracture conductivity, from which a Pseudo-radial skin was calculated. The Non-Darcy effects in the fracture were also evaluated, and finally the short term and long term well deliverabilities were assessed.

  2. Evaluation of the persistence of functional and biological respiratory health effects in clean-up workers 6 years after the Prestige oil spill.

    NARCIS (Netherlands)

    Zock, J.P.; Rodríguez-Trigo, G.; Rodríguez-Rodríguez, E.; Souto-Alonso, A.; Espinosa, A.; Pozo-Rodríguez, F.; Gómez, F.P.; Fuster, C.; Castaño-Vinyals, G.; Antó, J.M.; Barberà, J.A.

    2014-01-01

    Fishermen who had participated in clean-up activities of the Prestige oil spill showed increased bronchial responsiveness and higher levels of respiratory biomarkers 2years later. We aimed to evaluate the persistence of these functional and biological respiratory health effects 6years after clean-up

  3. SUPERFUND TREATABILITY CLEARINGHOUSE: BDAT INCINERATION OF CERCLA SARMS AT THE JOHN ZINK COMPANY TEST FACILITY (FINAL PROJECT REPORT)

    Science.gov (United States)

    This report presents the results of a treatability study of rotary kiln incineration of a synthetic "Superfund soil" bearing a wide range of chemical contaminants typically occurring at Superfund sites. This surrogate soil is referred to as a synthetic analytical reference ...

  4. A systematic assessment of the state of hazardous waste clean-up technologies. Quarterly technical progress report, April 1--June 30, 1993

    Energy Technology Data Exchange (ETDEWEB)

    Berg, M.T.; Reed, B.E.; Gabr, M.

    1993-07-01

    West Virginia University (WVU) and the US DOE Morgantown Energy Technology Center (METC) entered into a Cooperative Agreement on August 29, 1992 entitled ``Decontamination Systems Information and Research Programs.`` Stipulated within the Agreement is the requirement that WVU submit to METC a series of Technical Progress Report for Year 1 of the Agreement. This report reflects the progress and/or efforts performed on the following nine technical projects encompassed by the Year 1 Agreement for the period of April 1 through June 30, 1993: Systematic assessment of the state of hazardous waste clean-up technologies; site remediation technologies -- drain-enhanced soil flushing (DESF) for organic contaminants removal; site remediation technologies -- in situ bioremediation of organic contaminants; excavation systems for hazardous waste sites; chemical destruction of polychlorinated biphenyls; development of organic sensors -- monolayer and multilayer self-assembled films for chemical sensors; Winfield lock and dam remediation; Assessments of Technologies for hazardous waste site remediation -- non-treatment technologies and pilot scale test facility implementation; and remediation of hazardous sites with stream reforming.

  5. Comprehensive Environmental Response, Compensation, and Liability Act, as amended by the Superfund Amendments and Reauthorization Act Section 120(e)(5). Annual report to Congress for Fiscal year 1992

    Energy Technology Data Exchange (ETDEWEB)

    1993-08-01

    The US Department of Energy (DOE) is committed to conducting its operations in a safe and environmentally sound manner. High priorities for the Department are identifying and correcting environmental problems at DOE facilities that resulted from past operations, and preventing environmental problems from occurring during present and future operations. In this regard, the Department is committed to clean up the 1989 inventory of sites in the Environmental Restoration Program by the year 2019. DOE has issued an Order and guidance establishing policy and procedures for activities conducted under the Comprehensive Environmental Response, Compensation, and Liability Act (CERCLA), as amended by the Superfund Amendments and Reauthorization Act (SARA), and has developed a Five-Year Plan, updated annually, that integrates planning for corrective activities, environmental restoration and waste management operations at its facilities. DOE also continues to conduct assessments (e.g., Management Audits, Environmental Safety and Health (ES & H) Progress Assessments, Internal Self Assessments) at its operating facilities to provide the Secretary of Energy with information on current environmental compliance status and follow-up on findings.

  6. Evaluation of native microbial soil populations at a trichloroethylene contaminated Superfund site in the presence of a permeable reactive barrier (biowall) using a metagenomics approach

    Science.gov (United States)

    The Beaverdam Road Landfill occupies 3.5 acres and was an active disposal site for miscellaneous non-hazardous waste from 1943 to 1990, before being capped. In 1994, this site was included on the Nation Priorities List (NPL) for periodic inspection and remediation in accordance with the program regu...

  7. Superfund record of decision (EPA Region 2): Malta Rocket Fuel Area Site, Towns of Malta and Stillwater, Saratoga County, NY, July 13, 1996

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    1997-01-01

    This Record of Decision (ROD) documents the U.S. Environmental Protection Agency`s (EPA`s) selection of the remedial action for the Malta Rocket Fuel Area site (the Site). The remedy addresses the principal threats to human health and the environment that are posed by conditions at the Site. Exposure to soil contamination at the Malta Test Station will be addressed by excavation and off-site disposal of the contaminated soil. Ingestion of contaminated ground water by on-site employees will be addressed by pumping the Test Station water supply wells and treating the water to acceptable drinking water standards using an air stripper. Ground water not captured by the air stripper will be remediated to cleanup standards through natural attenuation and degradation processes.

  8. THE ROLE OF LIQUID WASTE PRETREATMENT TECHNOLOGIES IN SOLVING THE DOE CLEAN-UP MISSION

    Energy Technology Data Exchange (ETDEWEB)

    Wilmarth, B; Sheryl Bush, S

    2008-10-31

    The objective of this report is to describe the pretreatment solutions that allow treatment to be tailored to specific wastes, processing ahead of the completion schedules for the main treatment facilities, and reduction of technical risks associated with future processing schedules. Wastes stored at Hanford and Savannah River offer challenging scientific and engineering tasks. At both sites, space limitations confound the ability to effectively retrieve and treat the wastes. Additionally, the radiation dose to the worker operating and maintaining the radiochemical plants has a large role in establishing the desired radioactivity removal. However, the regulatory requirements to treat supernatant and saltcake tank wastes differ at the two sites. Hanford must treat and remove radioactivity from the tanks based on the TriParty Agreement and Waste Incidental to Reprocessing (WIR) documentation. These authorizing documents do not specify treatment technologies; rather, they specify endstate conditions. Dissimilarly, Waste Determinations prepared at SRS in accordance with Section 3116 of the 2005 National Defense Authorization Act along with state operating permits establish the methodology and amounts of radioactivity that must be removed and may be disposed of in South Carolina. After removal of entrained solids and site-specific radionuclides, supernatant and saltcake wastes are considered to be low activity waste (LAW) and are immobilized in glass and disposed of at the Hanford Site Integrated Disposal Facility (IDF) or formulated into a grout for disposal at the Savannah River Site Saltstone Disposal Facility. Wastes stored at the Hanford Site or SRS comprise saltcake, supernate, and sludges. The supernatant and saltcake waste fractions contain primarily sodium salts, metals (e.g., Al, Cr), cesium-137 (Cs-137), technetium-99 (Tc-99) and entrained solids containing radionuclides such as strontium-90 (Sr-90) and transuranic elements. The sludges contain many of the

  9. Absorbent pads for Containment, Neutralization, and Clean-Up of Environmental Spills Containing Chemically-Reactive Agents

    Science.gov (United States)

    Davis, Dennis D. (Inventor)

    1997-01-01

    A pad for cleaning up liquid spills is described which contains a porous surface covering, and an absorbent interior containing chemically reactive reagents for neutralizing noxious chemicals within the spilled liquid. The porous surface and the absorbent component would normally consist of chemically resistant materials allowing tentative spill to pass. The absorbent interior which contains the neutralizing reagents can but is not required to be chemically resilient and conducts the liquid chemical spill towards the absorbent interior containing the chemically reactive reagents where the dangerous and undesirable chemicals within the chemical spill are then neutralized as well as removed from the premises.

  10. Environmental remediation 1991: ``Cleaning up the environment for the 21st Century``. Proceedings

    Energy Technology Data Exchange (ETDEWEB)

    Wood, D.E. [ed.] [Westinghouse Hanford Co., Richland, WA (United States)

    1991-12-31

    This report presents discussions given at a conference on environmental remediation, September 8--11, Pasco, Washington. Topics include: public confidence; education; in-situ remediation; Hanford tank operations; risk assessments; field experiences; standards; site characterization and monitoring; technology discussions; regulatory issues; compliance; and the UMTRA project. Individual projects are processed separately for the data bases.

  11. Effects of changes in pumping on regional groundwater-flow paths, 2005 and 2010, and areas contributing recharge to discharging wells, 1990–2010, in the vicinity of North Penn Area 7 Superfund site, Montgomery County, Pennsylvania

    Science.gov (United States)

    Senior, Lisa A.; Goode, Daniel J.

    2017-06-06

    A previously developed regional groundwater flow model was used to simulate the effects of changes in pumping rates on groundwater-flow paths and extent of recharge discharging to wells for a contaminated fractured bedrock aquifer in southeastern Pennsylvania. Groundwater in the vicinity of the North Penn Area 7 Superfund site, Montgomery County, Pennsylvania, was found to be contaminated with organic compounds, such as trichloroethylene (TCE), in 1979. At the time contamination was discovered, groundwater from the underlying fractured bedrock (shale) aquifer was the main source of supply for public drinking water and industrial use. As part of technical support to the U.S. Environmental Protection Agency (EPA) during the Remedial Investigation of the North Penn Area 7 Superfund site from 2000 to 2005, the U.S. Geological Survey (USGS) developed a model of regional groundwater flow to describe changes in groundwater flow and contaminant directions as a result of changes in pumping. Subsequently, large decreases in TCE concentrations (as much as 400 micrograms per liter) were measured in groundwater samples collected by the EPA from selected wells in 2010 compared to 2005‒06 concentrations.To provide insight on the fate of potentially contaminated groundwater during the period of generally decreasing pumping rates from 1990 to 2010, steady-state simulations were run using the previously developed groundwater-flow model for two conditions prior to extensive remediation, 1990 and 2000, two conditions subsequent to some remediation 2005 and 2010, and a No Pumping case, representing pre-development or cessation of pumping conditions. The model was used to (1) quantify the amount of recharge, including potentially contaminated recharge from sources near the land surface, that discharged to wells or streams and (2) delineate the areas contributing recharge that discharged to wells or streams for the five conditions.In all simulations, groundwater divides differed from

  12. Region 9 Removal Sites 2012

    Data.gov (United States)

    U.S. Environmental Protection Agency — Point geospatial dataset representing locations of CERCLA (Superfund) Removal sites. CERCLA (Comprehensive Environmental Response, Compensation, and Liability Act)...

  13. Evaluation of borehole geophysical logging, aquifer-isolation tests, distribution of contaminants, and water-level measurements at the North Penn Area 5 Superfund Site, Bucks and Montgomery counties, Pennsylvania

    Science.gov (United States)

    Bird, Philip H.; Conger, Randall W.

    2002-01-01

    Borehole geophysical logging and aquiferisolation (packer) tests were conducted at the North Penn Area 5 Superfund site in Bucks and Montgomery Counties, Pa. Caliper, naturalgamma, single-point-resistance, fluid-temperature, fluid-resistivity, heatpulse-flowmeter, and digital acoustic-televiewer logs and borehole television surveys were collected in 32 new and previously drilled wells that ranged in depth from 68 to 302 feet. Vertical borehole-fluid movement direction and rate were measured with a high-resolution heatpulse flowmeter under nonpumping conditions. The suite of logs was used to locate water-bearing fractures, determine zones of vertical borehole- fluid movement, select depths to set packers, and locate appropriate screen intervals for reconstructing new wells as monitoring wells. Aquifer-isolation tests were conducted in four wells to sample discrete intervals and to determine specific capacities of discrete water-bearing zones. Specific capacities of isolated zones during packer testing ranged from 0.12 to 15.30 gallons per minute per foot. Most fractures identified by borehole geophysical methods as water-producing or water-receiving zones produced water when isolated and pumped. The acoustic-televiewer logs define two basic fracture sets, bedding-plane partings with a mean strike of N. 62? E. and a mean dip of 27? NW., and high-angle fractures with a mean strike of N. 58? E. and a mean dip of 72? SE. Correlation of heatpulse-flowmeter data and acoustic-televiewer logs showed 83 percent of identified water-bearing fractures were high-angle fractures.

  14. AHR-related activities in a creosote-adapted population of adult atlantic killifish, Fundulus heteroclitus, two decades post-EPA superfund status at the Atlantic Wood Site, Portsmouth, VA USA

    Energy Technology Data Exchange (ETDEWEB)

    Wojdylo, Josephine V. [Department of Biological Sciences, Environmental Toxicology Graduate Program, Clemson University, Clemson, SC 29634 (United States); Vogelbein, Wolfgang [The College of William & Mary, Gloucester Point, VA 23062 (United States); Bain, Lisa J. [Department of Biological Sciences, Environmental Toxicology Graduate Program, Clemson University, Clemson, SC 29634 (United States); Rice, Charles D., E-mail: cdrice@clemson.edu [Department of Biological Sciences, Environmental Toxicology Graduate Program, Clemson University, Clemson, SC 29634 (United States)

    2016-08-15

    Highlights: • AHR-related activities in creosote-adapted adult killifish were examined. • Creosote-adapted adult killifish have elevated intestine CYP1A. • Creosote-adapted adult killifish have elevated liver COX2 mRNA expression. • Most creosote-adapted adult killifish have lesions varying in severity. • Liver lesions in creosote-adapted adult killifish express CYP1A and AHR2 proteins. - Abstract: Atlantic killifish, Fundulus heteroclitus, are adapted to creosote-based PAHs at the US EPA Superfund site known as Atlantic Wood (AW) on the southern branch of the Elizabeth River, VA USA. Subsequent to the discovery of the AW population in the early 1990s, these fish were shown to be recalcitrant to CYP1A induction by PAHs under experimental conditions, and even to the time of this study, killifish embryos collected from the AW site are resistant to developmental deformities typically associated with exposure to PAHs in reference fish. Historically, however, 90 +% of the adult killifish at this site have proliferative hepatic lesions including cancer of varying severity. Several PAHs at this site are known to be ligands for the aryl hydrocarbon receptor (AHR). In this study, AHR-related activities in AW fish collected between 2011 and 2013 were re-examined nearly 2 decades after first discovery. This study shows that CYP1A mRNA expression is three-fold higher in intestines of AW killifish compared to a reference population. Using immunohistochemistry, CYP1A staining in intestines was uniformly positive compared to negative staining in reference fish. Livers of AW killifish were examined by IHC to show that CYP1A and AHR2 protein expression reflect lesions-specific patterns, probably representing differences in intrinsic cellular physiology of the spectrum of proliferative lesions comprising the hepatocarcinogenic process. We also found that COX2 mRNA expression levels were higher in AW fish livers compared to those in the reference population, suggesting a

  15. Comparison of Two Procedures for Extraction and Clean-up of Organophosphorus and Pyrethroid Pesticides in Sediment

    Institute of Scientific and Technical Information of China (English)

    WANG Li-Gang; JIANG Xin; YAN Dong-Yun; S.FORSTER; D.MARTENS

    2004-01-01

    Two procedures were compared for extraction and clean-up of 20 organophosphorus and 19 pyrethroid pesticides in sediment to identify the more effective procedure for groups of pesticides or individual compounds. In Procedure Ⅰ,methanol/water and n-hexane were used for extraction,and 1:10 (v/v) dichloromethane in n-hexane and acetone were used as eluents for eluting the analyte through the cartridge,with one evaporating steps on a rotary evaporator and two eluting steps on the cartridge. n-hexane/acetone (2:1,v/v) was used for extraction and elution in Procedure Ⅱ with one evaporating step on a rotary evaporator and one eluting step on the cartridge. All extractions were performed under an ultrasonic bath and gas chromatography and mass spectrometry were utilized for measurements. Procedure Ⅱ was developed as a rapid,timesaving,less costly and safer substitute for Procedure Ⅰ which was an old method. Procedure Ⅱ was more effective for ahnost all the organophosphorus pesticides tested and 11 of the 19 pyrethroid pesticides,while Procedure Ⅰ was more appropriate for analysis of 5 pyrethroid pesticides. However,recoveries of most pyrethroid pesticides were fairly low. Thus,further studies should focus on adjustment and formulation of solvents for more efficient extraction and clean-up of pyrethroid pesticides from sediment samples.

  16. A novel polymer inclusion membrane based method for continuous clean-up of thiocyanate from gold mine tailings water.

    Science.gov (United States)

    Cho, Youngsoo; Cattrall, Robert W; Kolev, Spas D

    2018-01-05

    Thiocyanate is present in gold mine tailings waters in concentrations up to 1000mgL(-1) and this has a serious environmental impact by not allowing water reuse in the flotation of gold ore. This significantly increases the consumption of fresh water and the amount of wastewater discharged in tailings dams. At the same time thiocyanate in tailings waters often leads to groundwater contamination. A novel continuous membrane-based method for the complete clean-up of thiocyanate in concentrations as high as 1000mgL(-1) from its aqueous solutions has been developed. It employs a flat sheet polymer inclusion membrane (PIM) of composition 70wt% PVC, 20wt% Aliquat 336 and 10wt% 1-tetradecanol which separates counter-current streams of a feed thiocyanate solution and a 1M NaNO3 receiving solution. The PIM-based system has been operated continuously for 45days with 99% separation efficiency. The volume of the receiving solution has been drastically reduced by recirculating it and continuously removing thiocyanate by precipitating it with in-situ generated Cu(I). The newly developed PIM-based thiocyanate clean-up method is environmentally friendly in terms of reagent use and inexpensive with respect to both equipment and running costs. Copyright © 2017 Elsevier B.V. All rights reserved.

  17. Application of single immunoaffinity clean-up for simultaneous determination of regulated mycotoxins in cereals and nuts.

    Science.gov (United States)

    Vaclavikova, Marta; MacMahon, Shaun; Zhang, Kai; Begley, Timothy H

    2013-12-15

    A rapid and sensitive analytical strategy for the simultaneous determination of twelve mycotoxins (aflatoxins, fumonisins, zearalenon, deoxynivalenol, ochratoxin A, T-2 and HT-2 toxins) using ultra-high performance liquid chromatography coupled to tandem mass spectrometry (UHPLC-MS/MS) was developed and validated. The method was validated for peanuts, barley and maize-breakfast cereals; selected as they represent the matrices most often contaminated by mycotoxins. The method is designed for fast and reliable analyses of mycotoxins in regulatory, industrial and private laboratories. Multi-target immunoaffinity columns containing antibodies for all mycotoxins studied herein were used for sample clean-up. Method optimization was predominantly focused on the simplification of extraction and clean-up procedure recommended by column producers. This newly developed and simplified procedure decreased both the sample preparation time and the solvent volumes used for their processing. The analysis of all regulated mycotoxins was conducted by a newly developed UHPLC-MS/MS method with a sample run time of only ten minutes. The method trueness was tested with analytical spikes and certified reference materials, with recoveries ranging from 71% to 112% for all of the examined mycotoxins.

  18. Superfund record of decision (EPA Region 2): General Motors/Central Foundry Division Site, St. Lawrence County, Massena, NY. (Second remedial action), March 1992. Final report

    Energy Technology Data Exchange (ETDEWEB)

    1992-03-31

    The 270-acre General Motors/Central Foundry Division site is an aluminum casting plant in Massena, St. Lawrence County, New York. From 1985 to 1989, General Motors investigations detected contamination in soil, sludge, debris, sediment, ground water and surface water. In 1988, an interim cap was placed over the industrial landfill. A 1990 ROD addressed most affected areas of the site, including the St. Lawrence River System sediments, contaminated ground water, soils on the facility and the St. Regis Mohawk Indian Reservation, and material at four lagoons and the North Disposal Area. The ROD provides the final remedy for the contaminated soil, sludge, debris, and groundwater at the East Disposal Area and the Industrial Lagoon. The primary contaminants of concern are VOCs, including TCE; and other organics, including PCBs, phenols, and PAHs. The selected remedial action for the site are included.

  19. Superfund explanation of significant difference for the record of decision (EPA Region 3): Fairchild, Intel, and Raytheon Sites, (Mew Study Area), Mountain View, CA, September 1990

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    1995-02-01

    The purpose of the document is to explain the significant differences between the Record of Decision (ROD) signed by the U.S. Environmental Protection Agency (EPA) on June 9, 1989 (PB90-118225) and the remedy that will be implemented at the Middlefield/Ellis/Whisman Study Area (MEW Site). The document provides a brief background on the MEW Site, describes the change to the ROD that EPA is now making and explains the ways in which this change affects implementation of the remedy selected by EPA in June of 1989.

  20. Application of boreal forest toxicity data in the decision-making process for contaminated soil clean-up remediation at oil and gas fields in Western Canada

    Energy Technology Data Exchange (ETDEWEB)

    Scroggins, R.; Princz, J. [Environment Canada, Ottawa, ON (Canada); Moody, M. [Saskatchewan Research Council, Regina, SK (Canada); Olsgard-Dumanski, M.; Haderlein, L. [WorleyParsons Canada, Calgary, AB (Canada); Moore, B. [Devon Canada Corp., Calgary, AB (Canada)

    2010-07-01

    This presentation reported on a multi-year research project in which a broad range of boreal forest test methods for assessing petroleum hydrocarbon (PHC) toxicity in contaminated soil were used to show that clean-up decisions can be made on a field-wide basis through focused biological testing of typical drill sump and flare pit locations within an oil and gas field. Remediation at most sites will likely be limited to the Alberta soil eco-contact guidelines for PHC F2 and F3 fractions. Since Tier 1 eco-contact guidelines are derived using toxicity data from fresh crude and using agricultural plant species, it was more logical to follow a Tier 2 eco-contact pathway approach because most contamination was related to drilling sumps and flare pits containing highly weathered PHCs and species native to the boreal eco-zone of Canada. The site-specific remedial objective (SSRO) option within the Tier 2 guideline was used because of the large number of sites requiring remediation, and the similarity of sites within pre-determined Risk Assessment Zones. For representative contaminated soils, a SSRO was derived from the twenty-fifth percentile of the estimated species sensitivity distribution of all acceptable boreal plant, earthworm, springtail and mite test endpoints. The purpose of the project was to reduce soil volumes sent to landfill during site remediation by showing that residual impacts from weathered PHC in soil do not have damaging effects on boreal forest receptors following remediation. Data was included to show the value of this approach and the variability between sites and their effect on regionalizing a Tier 2 eco-contact guideline.

  1. Superfund Record of Decision (EPA Region 2): General Motors/Central Foundry Division site, St. Lawrence County, Massena, NY. (First remedial action), December 1990

    Energy Technology Data Exchange (ETDEWEB)

    1990-12-17

    The 270-acre General Motors/Central Foundry Division site is an active aluminum casting plant in Massena, St. Lawrence County, New York. The site overlies a surficial alluvial aquifer and is adjacent to wetlands, both of which have been contaminated. Additional onsite features of concern include the unlined North and East Disposal Areas and the Industrial Landfill, which contain contaminated soil, debris, sludge; four unlined Industrial Lagoons, which contain contaminated liquids, sludge, and soil; the rivers and creek which contains contaminated sediment; contaminated soil on the St. Regis Mohawk Reservation and on General Motors property; and contaminated associated wetlands. The Record of Decision (ROD) provides a final remedy for all site areas and media except the East Disposal Area and the Industrial Landfill, which will be addressed in a subsequent ROD. The primary contaminants of concern affecting the soil, sediment, sludge, debris, ground water, and surface water are PCBs, and to a much lesser degree, VOCs including TCE; and other organics including PAHs, and phenols. The selected remedial action for this site is included.

  2. Relevance of Nuclear Weapons Clean-Up Experience to Dirty Bomb Response

    Energy Technology Data Exchange (ETDEWEB)

    Vantine, H C; Crites, T R

    2002-08-19

    During the past 50 years, the United States has experienced 32 major nuclear weapons accidents, nine of which released special nuclear material to the environment. Response to these accidents, coupled with recovery experience following the Russian satellite reentry and weapons test site cleanup, form the basis for determining actions that might be required following a nuclear terrorist event involving the release of radioactive material. Though valuable information has been gained following the recovery from various commercial accidents, most notably the Chernobyl nuclear power plant failure and the dismantled radiography source in the Brazilian city of Goi nia, this paper will focus on the lessons learned from the U.S. nuclear weapons program.

  3. In-Cell Clean-Up Pressurised Liquid Extraction Method to Determine Pesticides in Mushroom Compost by Gas Chromatography-Tandem Mass Spectrometry

    OpenAIRE

    María Teresa Tena; María Pilar Martínez-Moral; Patricia Labarta

    2012-01-01

    A fast, simple, and easily automated method for the determination of two insecticides, diazinon and deltamethrin, and two fungicides, iprodione and prochloraz, in mushroom cultivation compost samples, based on selective pressurised liquid extraction (SPLE) and gas chromatography coupled to tandem mass spectrometry, is presented. The proposed method integrates extraction and clean-up processes in one single step, by adding a clean-up sorbent into the extraction cell. SPLE variables were thorou...

  4. Cleaning up the biogeography of Labroides dimidiatus using phylogenetics and morphometrics

    Science.gov (United States)

    Sims, C. A.; Riginos, C.; Blomberg, S. P.; Huelsken, T.; Drew, J.; Grutter, A. S.

    2014-03-01

    Cleaner fishes are some of the most conspicuous organisms on coral reefs due to their behaviour and prominent body pattern, consisting of a lateral stripe and blue/yellow colouration. All obligate cleaner fishes share this body stripe pattern, which is an important signal for attracting client fishes. However, variability in the cleaning signal of the cleaner fish Labroides dimidiatus has been documented across its range. Here, we investigate the geographic distribution of cleaner signal polymorphisms in L. dimidiatus and contrast this to phylogeographic variation in mitochondrial (mt) DNA. We used samples from 12 sites for genetic analyses, encompassing much of L. dimidiatus' range from the Red Sea to Fiji. We obtained morphometric measures of the cleaner signal body stripe width from individuals among six of the sites and qualitatively grouped tail stripe shape. mtDNA control region sequences were used for phylogenetic and population genetic analyses. We found that body stripe width was significantly correlated with tail stripe shape and geographical location, with Indian Ocean populations differing in morphology from western Pacific populations. L. dimidiatus haplotypes formed two reciprocally monophyletic clades, although in contrast to morphology, Japanese cleaner fish fell within the same clade as Indian Ocean cleaner fish and both clade types were sympatric in Papua New Guinea. An additional novel finding of our research was that the inclusion of two closely related cleaner fish species, Labroides pectoralis and Labroides bicolor, in the phylogenetic analysis rendered L. dimidiatus polyphyletic. Overall, the findings suggest the diversity within L. dimidiatus is underestimated.

  5. Contaminated land clean-up using composted wastes and impacts of VOCs on land.

    Science.gov (United States)

    Williamson, J C; Akinola, M; Nason, M A; Tandy, S; Healey, J R; Jones, D L

    2009-05-01

    This paper describes experiments that demonstrate the effects and potential for remediation of a former steelworks site in Wales polluted with polycyclic aromatic hydrocarbons (PAHs) and volatile organic compounds (VOCs). Under field conditions, PAH-contaminated soil was composted in-vessel, with or without organic feedstocks, receiving forced aeration for 80 days followed by 4 months maturation. Treatments compared PAH removal in contaminated soil to contaminated soil mixed with three different organic waste mixes after composting and after composts were spread to land. After composting, PAH concentrations declined in all treatments, by up to 38%. Sixteen months after the composts were landspread and vegetation was established, only those containing contaminated soil with organic additions exhibited further PAH removal, by up to 29%. Composting resulted in a decline in the relative concentration of small PAHs, whereas the landspreading-vegetation phase saw a decline in the relative concentration of medium PAHs in two of the three composts exhibiting PAH removal. Under controlled glasshouse conditions, vegetated soil columns of differing depths were exposed to VOCs from beneath. VOC vapour affected both shoot and root growth and soil microbial activity; effects varied with distance from the VOC source. This work demonstrated that on-site remediation of aged PAH-contaminated land can be successfully initiated by in-vessel co-composting followed by land spreading and vegetation, within a practical timeframe.

  6. Commencement Bay Nearshore/Tideflats Superfund Site, Tacoma, Washington Remedial Investigations. Evaluation of Alternative Dredging Methods and Equipment, Disposal Methods and Sites, and Site Control and Treatment Practices for Contaminated Sediments.

    Science.gov (United States)

    1985-06-01

    Material Disposal in the Ocean, John Wiley & Sons, Inc., New York, New York. Myers, A. C., 1979. "Summer and Winter Burrows of a Mantis Shrimp , Squilla...Deep water is any depth below the influence of storm waves, which will vary between sites. Theoretically, depths are unlimited, although in fact ...Swann, et. al., uses the term in a thermodynamic sense. He classifies the organic compounds by mobility class when in fact his classifica- tion

  7. Re-injection accelerates groundwater clean up at Fernald, Fluor Fernald, Inc.

    Energy Technology Data Exchange (ETDEWEB)

    Dave Brettschneider; William Hertel; Ken Broberg

    2000-09-29

    A successful one year long, field scale demonstration of the use of groundwater re-infection at Fernald was recently completed bringing DOE one step closer to achieving an accelerated site remediation (DOE 2000). The demonstration marks the end of a several year effort to evaluate whether: re-injection could be conducted efficiently at Fernald, and if the approved aquifer remedy at Fernald would benefit by incorporating re-infection. Evaluation of re-injection technology involved not only technical considerations, but also participation and cooperation of regulators and stakeholders. The demonstration was considered to be unique in that it was integrated into the design of the current approved aquifer remedy and utilized the existing remediation infrastructure. Information collected during the demonstration indicated that re-injection wells could be operated efficiently at Fernald and that the current approved groundwater remedy should be modified to include the use of re-injection.

  8. Brownfields Technology Primer: Selecting and Using Phytoremediation for Site Cleanup

    Science.gov (United States)

    This primer explains the phytoremediation process, discusses the potential advantages and considerations in selecting phytoremediation to clean up brownfields sites, and provides information on additional resources about phytoremediation.

  9. Biodegradation of 2,3,7,8 TCDD by anaerobic and aerobic microcosms collected from bioremediation treatments for cleaning up dioxin contaminated soils

    Energy Technology Data Exchange (ETDEWEB)

    Ha, Dang Thi; Tuan, Mai Anh; Viet, Nguyen Quoc; Sanh, Nguyen Thi [Vietnamese Academy of Science and Technology (VAST) (Viet Nam). Inst. of Biotechnology; Sau, Trinh Khac [Vietnam-Russian Tropical Center (Viet Nam); Papke, O. [ERGO Forschungsgesellschaft, Hamburg (Germany)

    2004-09-15

    There are many microbes that can degrade polychlorinated dibenzo-p-dioxins (PCDDs), polychlorinated dibenzofurants (PCDFs) and polychlorinated biphenyls (PCBs) have been isolated including purified bacteria, actinomycetes, white rods, filamentous fungi, anaerobes and also anaerobic and aerobic consortia. Bioremediation one of biological remediation has been studied as hopeful alternative to physical and chemical treatments that using for cleaning up PCDDs, PCDFs. In Vietnam for cleaning up ''hot spot'' of some former military air bases, bioremediation has been studying in different scales of Danang site. After 18 to 24 month treatments, the reduction of toxicity was significally detected. In order to study biodegradability by different groups and one of dominated strain that are existing microorganisms in our treatments, the investigation of 2,3,7,8 TCDD anaerobic and aerobic degradations was carried out in the laboratory condition. Anaerobic microbial consortium containing three different bacteria such as two Gram- negative vibrio and rod and one gram positive cocoides bacteria. This consortium could degrade 118 pg TEQ/ml 2,3,7,8 TCDD after 133 days under sulfate reduction. Concentration of 2,3,7,8 TCDD in the soil extract that adding to medium at starting point of cultivation was 144.6 pg TEQ/ml. About 81% toxicity was removed. Aerobic consortium containing all three Gram-negative bacteria and one fungal strain. After 9 day shaking at 180 rpm/min and 30 C, 85.6 % of 164.45 pg TEQ/ml 2,3,7,8 TCDD was removed. Other preliminary results of study of 2,3,7,8 TCDD biodegradation as sole carbon and energy by show that this strain FDN30 could remove 43,45 pg TEQ/ml (59%) of 73,1 pgTEQ/ml adding dioxin after two weeks. These findings explain why high concentration of contaminants in treated soil was decreased after two year treatment. Indigenous microorganisms play leading role in the detoxification of 2,3,7,8 TCDD in contaminated soils.

  10. Biodegradation of 2,3,7,8 TCDD by anaerobic and aerobic microcosms collected from bioremediation treatments for cleaning up dioxin contaminated soils

    Energy Technology Data Exchange (ETDEWEB)

    Ha, Dang Thi; Tuan, Mai Anh; Viet, Nguyen Quoc; Sanh, Nguyen Thi [Vietnamese Academy of Science and Technology (VAST) (Viet Nam). Inst. of Biotechnology; Sau, Trinh Khac [Vietnam-Russian Tropical Center (Viet Nam); Papke, O. [ERGO Forschungsgesellschaft, Hamburg (Germany)

    2004-09-15

    There are many microbes that can degrade polychlorinated dibenzo-p-dioxins (PCDDs), polychlorinated dibenzofurants (PCDFs) and polychlorinated biphenyls (PCBs) have been isolated including purified bacteria, actinomycetes, white rods, filamentous fungi, anaerobes and also anaerobic and aerobic consortia. Bioremediation one of biological remediation has been studied as hopeful alternative to physical and chemical treatments that using for cleaning up PCDDs, PCDFs. In Vietnam for cleaning up ''hot spot'' of some former military air bases, bioremediation has been studying in different scales of Danang site. After 18 to 24 month treatments, the reduction of toxicity was significally detected. In order to study biodegradability by different groups and one of dominated strain that are existing microorganisms in our treatments, the investigation of 2,3,7,8 TCDD anaerobic and aerobic degradations was carried out in the laboratory condition. Anaerobic microbial consortium containing three different bacteria such as two Gram- negative vibrio and rod and one gram positive cocoides bacteria. This consortium could degrade 118 pg TEQ/ml 2,3,7,8 TCDD after 133 days under sulfate reduction. Concentration of 2,3,7,8 TCDD in the soil extract that adding to medium at starting point of cultivation was 144.6 pg TEQ/ml. About 81% toxicity was removed. Aerobic consortium containing all three Gram-negative bacteria and one fungal strain. After 9 day shaking at 180 rpm/min and 30 C, 85.6 % of 164.45 pg TEQ/ml 2,3,7,8 TCDD was removed. Other preliminary results of study of 2,3,7,8 TCDD biodegradation as sole carbon and energy by show that this strain FDN30 could remove 43,45 pg TEQ/ml (59%) of 73,1 pgTEQ/ml adding dioxin after two weeks. These findings explain why high concentration of contaminants in treated soil was decreased after two year treatment. Indigenous microorganisms play leading role in the detoxification of 2,3,7,8 TCDD in contaminated soils.

  11. CERCLIS (Superfund) ASCII Text Format - CPAD Database

    Data.gov (United States)

    U.S. Environmental Protection Agency — The Comprehensive Environmental Response, Compensation and Liability Information System (CERCLIS) (Superfund) Public Access Database (CPAD) contains a selected set...

  12. A new multiple-stage electrocoagulation process on anaerobic digestion effluent to simultaneously reclaim water and clean up biogas.

    Science.gov (United States)

    Liu, Zhiguo; Stromberg, David; Liu, Xuming; Liao, Wei; Liu, Yan

    2015-03-21

    A new multiple-stage treatment process was developed via integrating electrocoagulation with biogas pumping to simultaneously reclaim anaerobic digestion effluent and clean up biogas. The 1st stage of electrocoagulation treatment under the preferred reaction condition led to removal efficiencies of 30%, 81%, 37% and >99.9% for total solids, chemical oxygen demand, total nitrogen and total phosphorus, respectively. Raw biogas was then used as a reactant and pumped into the effluent to simultaneously neutralize pH of the effluent and remove H2S in the biogas. The 2nd stage of electrocoagulation treatment on the neutralized effluent showed that under the selected reaction condition, additional 60% and 10% of turbidity and chemical oxygen demand were further removed. The study concluded a dual-purpose approach for the first time to synergistically combine biogas purification and water reclamation for anaerobic digestion system, which well addresses the downstream challenges of anaerobic digestion technology.

  13. Effective clean-up and ultra high-performance liquid chromatography-tandem mass spectrometry for isoflavone determination in legumes.

    Science.gov (United States)

    Vila-Donat, Pilar; Caprioli, Giovanni; Maggi, Filippo; Ricciutelli, Massimo; Torregiani, Elisabetta; Vittori, Sauro; Sagratini, Gianni

    2015-05-01

    Legumes are an excellent source of macronutrients and phytochemicals as isoflavones. The aim of this work was to develop a new analytical method for determining five isoflavone compounds, three of which are aglycons, namely daidzein, genistein, biochanin A, and two of which, daidzin and genistin, are glycosilated, in lentils and other pulses, using an effective clean-up system and UHPLC-MS/MS (triple quadrupole) method. The recoveries obtained by spiking the lentil samples with a standard mixture of isoflavones at three levels of fortification (5, 25 and 100 μg kg(-1)) were in the range of 54.4-111.1%, 68.6-91.1%, and 84.4-114%, respectively. The method was applied to analyse 48 lentil samples from central Italy and pulses for determining the isoflavone content, which was found to range from 1.1 to 95.6 μg kg(-1).

  14. Superfund record of decision (EPA Region 9): Carson River Mercury Site, operable unit 1, Lyon, Storey and Churchill County, NV, March 30, 1995

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    1995-06-01

    The Record of Decision (ROD) presents the selected remedial action for Operable Unit 1 (OU-1) of the Carson River Mercury Site (CRMS) which is located in Lyon, Storey and Churchill Counties, Nevada. The selected remedy for the five residential yards is to excavate contaminated surface soil (estimated to go to a depth of approximately 2 feet below ground surface), dispose of the soil at the RCRA municipal landfill if the soils do not exceed the TCLP standards, and restore the excavated areas. If it is determined that all or part of the excavated soil exceeds the TCLP standards, then the excavated soil will either be treated and disposed of at a RCRA municipal landfill or disposed of at the RCRA hazardous waste landfill.

  15. Application of zirconium dioxide nanoparticle sorbent for the clean-up step in post-harvest pesticide residue analysis.

    Science.gov (United States)

    Uclés, Ana; Herrera López, Sonia; Dolores Hernando, Maria; Rosal, Roberto; Ferrer, Carmen; Fernández-Alba, Amadeo R

    2015-11-01

    The use of yttria-stabilized zirconium dioxide nanoparticles as d-SPE clean-up sorbent for a rapid and sensitive liquid chromatography-electrospray ionization-tandem mass spectrometry (LC-ESI-MS/MS) method for the determination of post-harvest fungicides (carbaryl, carbendazim, chlorpropham, diphenylamine, ethoxyquin, flutriafol, imazalil, iprodione, methomyl, myclobutanil, pirimiphos-methyl, prochloraz, pyrimethanil, thiabendazole, thiophanate-methyl and tolclofos-methyl) in orange and pear samples has been evaluated and validated. The sample preparation was a modification of the QuEChERS extraction method using yttria-stabilized zirconium dioxide and multi-walled carbon nanotubes (MWCNTs) nanoparticles as the solid phase extraction (d-SPE) clean-up sorbents prior to injecting the ten-fold diluted extracts into the LC system. By using the yttria-stabilized zirconium dioxide extraction method, more recoveries in the 70-120% range were obtained - thus this method was used for the validation. Quantification was carried out using a matrix-matched calibration curve which was linear in the 1-500 µg kg(-1) range for almost all the pesticides studied. The validated limit of quantification was 10 µg kg(-1) for most of the studied compounds, except chlorpropham, ethoxyquin and thiophanate-methyl. Pesticide recoveries at the 10 and 100 µg kg(-1) concentration levels were satisfactory, with values between 77% and 120% and relative standard deviations (RSD) lower than 10% (n=5). The developed method was applied for the determination of selected fungicides in 20 real orange and pear samples. Four different pesticide residues were detected in 10 of these commodities; 20% of the samples contained pesticide residues at a quantifiable level (equal to or above the LOQs) for at least one pesticide residue. The most frequently-detected pesticide residues were: carbendazim, thiabendazole and imazalil-all were below the MRL. The highest concentration found was imazalil at 1175 µg kg

  16. Delineation of areas having elevated electrical conductivity, orientation and characterization of bedrock fractures, and occurrence of groundwater discharge to surface water at the U.S. Environmental Protection Agency Barite Hill/Nevada Goldfields Superfund site near McCormick, South Carolina

    Science.gov (United States)

    Chapman, Melinda J.; Huffman, Brad A.; McSwain, Kristen Bukowski

    2015-07-16

    During October 2012 through March 2013, the U.S. Geological Survey (USGS), in cooperation with the U.S. Environmental Protection Agency (EPA) Region 4, Superfund Section, conducted borehole geophysical logging, surface geophysical surveys, and water-quality profiling in selected wells and areas to characterize or delineate the extent of elevated subsurface electrical conductivity at the EPA Barite Hill/Nevada Goldfields Superfund site near McCormick, South Carolina. Elevated electrical conductivity measured at the site may be related to native rock materials, waste rock disposal areas used in past operations, and (or) groundwater having elevated dissolved solids (primarily metals and major ions) related to waste migration. Five shallow screened wells and four open-borehole bedrock wells were logged by using a suite of borehole tools, and downhole water-quality profiles were recorded in two additional wells. Well depths ranged from about 26 to 300 feet below land surface. Surface geophysical surveys based on frequency-domain electromagnetic and distributed temperature sensing (DTS) techniques were used to identify areas of elevated electrical conductivity (Earth materials and groundwater) and potential high dissolved solids in groundwater and surface water on land and in areas along the northern unnamed tributary at the site.

  17. Earthworm survival and behavior results from a Clark Fork River Superfund site: Grant-Kohrs Ranch N.H.S., Montana

    Energy Technology Data Exchange (ETDEWEB)

    Rader, B.R.; Nimmo, D.R.; Chapman, P.L. [Colorado State Univ., Fort Collins, CO (United States)

    1995-12-31

    Concentrations of heavy metals in sediments and soils deposited along the floodplain of the Clark Fork River, within the boundaries of the Grant-Kohrs Ranch National Historic Site, have exceeded those typically found in uncontaminated soils. Upstream mining activities along the Clark Fork River in the Deer Lodge Valley, Montana, have produced substantial quantities of mine waste which have been deposited throughout the watershed. Releases and re-releases of these contaminated substances continue to occur, and appear to be preventing the germination and establishment of critical riparian plant species and depressing soil microbe activity. Slickens, bare spots devoid of all vegetation, occur frequently in the floodplain along the Clark Fork River. This research investigates the toxicity of slicken soils using a series of earthworm (Eisenia foetida andrei) survival and behavior tests. In dilution tests, earthworm survival was reduced significantly in as little as 12.5% slicken soil. Results from earthworm behavior tests currently being conducted using non-lethal slicken soil dilutions will also be presented.

  18. Evaluation of the persistence of functional and biological respiratory health effects in clean-up workers 6 years after the prestige oil spill.

    Science.gov (United States)

    Zock, Jan-Paul; Rodríguez-Trigo, Gema; Rodríguez-Rodríguez, Emma; Souto-Alonso, Ana; Espinosa, Ana; Pozo-Rodríguez, Francisco; Gómez, Federico P; Fuster, Carme; Castaño-Vinyals, Gemma; Antó, Josep Maria; Barberà, Joan Albert

    2014-01-01

    Fishermen who had participated in clean-up activities of the Prestige oil spill showed increased bronchial responsiveness and higher levels of respiratory biomarkers 2 years later. We aimed to evaluate the persistence of these functional and biological respiratory health effects 6 years after clean-up work. In 2008/2009 a follow-up study was done in 230 never-smoking fishermen who had been exposed to clean-up work in 2002/2003 and 87 non-exposed fishermen. Lung function and bronchial responsiveness testing and the determination of respiratory biomarkers in exhaled breath condensate were done identically as in the baseline survey in 2004/2005. Associations between participation in clean-up work and respiratory health parameters were assessed using linear and logistic regression analyses adjusting for sex and age. Information from 158 exposed (69%) and 57 non-exposed (66%) fishermen was obtained. Loss to follow-up in the non-exposed was characterised by less respiratory symptoms at baseline. During the 4-year follow-up period lung function, bronchial hyperresponsiveness and the levels of respiratory biomarkers of oxidative stress and growth factors had deteriorated notably more among non-exposed than among exposed. At follow-up, respiratory health indices were similar or better in clean-up workers than in non-exposed. No clear differences between highly exposed and moderately exposed clean-up workers were found. In conclusion, we could not detect long-term respiratory health effects in clean-up workers 6 years after the Prestige oil spill. Methodological issues that need to be considered in this type of studies include the choice of a non-exposed control group and limitation of follow-up to subgroups such as never smokers.

  19. Trophic transfer and effects of DDT in male hornyhead turbot (Pleuronichthys verticalis) from Palos Verdes Superfund site, CA (USA) and comparisons to field monitoring.

    Science.gov (United States)

    Crago, Jordan; Xu, Elvis Genbo; Kupsco, Allison; Jia, Fang; Mehinto, Alvine C; Lao, Wenjian; Maruya, Keith A; Gan, Jay; Schlenk, Daniel

    2016-06-01

    High concentrations of DDT and metabolites (ΣDDT) have been detected in sediment and the demersal flatfish hornyhead turbot (Pleuronichtys verticalis) collected from Palos Verdes (PV), California, USA, a site contaminated with over 100 metric tons of DDT throughout 1960s-70s. This study was conducted to assess the transfer of ΣDDT from PV-sediment into polychaetes (Neanthes arenaceodentata) and hornyhead turbot, and to investigate if the responses in turbots from two different laboratory exposures mimic those in turbots caught in PV (PV-turbot). Turbot fed PV-sediment-contaminated polychaete for 7 days had liver concentrations of ΣDDT similar to PV-turbot. After 28 days, ΣDDT also accumulated in livers of turbot gavaged with a ΣDDT mixture. In vitro cell bioassays indicated significant increases of 17β-estradiol equivalents (EEQ) in turbot bile extracts as compared to the control in the 7-day study. These responses corresponded to those measured in PV-fish. Glucocorticoid receptor (GR), anti-androgen receptor (anti-AR), estrogen receptor (ER) or aryl hydrocarbon receptor (AhR) activities were also observed in extracts of PV-sediment, and PV-sediment-exposed worm. Anti-AR, AhR and GR activities were significantly higher in PV-sediment than reference sediment (San Diego, SD). Higher transcripts of hepatic VTG, ERα and ERβ were found in PV-turbot than SD-turbot, but were unaltered in fish exposed to sediment-contaminated worms for the 7-day study. In contrast, liver extracts from the 28-day treatment of ΣDDT showed lower EEQ but similar hepatic VTG and ERβ transcripts relative to those of PV-turbot. These data indicated that trophic transfer of sediment-associated DDT in 7-day exposures corresponded to field measurements of DDT residues and in vitro ER bioactivities, but failed to mimic in vivo biological effects observed in field fish. In contrast, treatment with ΣDDT alone for 28 days mimicked in vivo biological effects of DDTs in PV fish, but did not

  20. Site Area Boundaries

    Data.gov (United States)

    U.S. Environmental Protection Agency — This dataset consists of site boundaries from multiple Superfund sites in U.S. EPA Region 8. These data were acquired from multiple sources at different times and...

  1. Site Area Boundaries

    Data.gov (United States)

    U.S. Environmental Protection Agency — This dataset consists of site boundaries from multiple Superfund sites in U.S. EPA Region 8. These data were acquired from multiple sources at different times and...

  2. Cleaning up dark matter

    CERN Multimedia

    Bignami, Giovanni Fabrizio

    2006-01-01

    "An experiment in Italy has found tantalizing but puzzling evidence for axions, one if the leading candidates for dark matter. The authors explain how a pair of spinning neutron stars should settle the issue once and for all." (3 pages)

  3. Challenges in Obtaining Property Access: The FUSRAP Maywood Site Experience - 13433

    Energy Technology Data Exchange (ETDEWEB)

    Kollar, William [Shaw Environmental, Inc., 100 West Hunter Avenue, Maywood, NJ 07607 (United States)

    2013-07-01

    The Formerly Utilized Sites Remedial Action Program (FUSRAP) is the US government program started in 1974 to identify, investigate and clean up or control sites that became contaminated as a result of the nation's early atomic programs. Many of these sites are not owned by the federal government and therefore require owner permission to enter. The experience in pursuing such access at the FUSRAP Maywood Superfund Site (the Maywood Site or the Site) in Bergen County, New Jersey, is extensive. Since the US Army Corps of Engineers (the Corps) assumed responsibility for the Maywood Site from the US Department of Energy in 1997, at least 186 separate property access agreements (known in FUSRAP as a Real Estate Right-of- Entry or ROE) have been executed between the Corps and approximately 55 different land owners and tenant occupants at the Maywood Site (agreement renewals with the same owners over time account for the difference). Maywood's experience during the Corps' tenure, reflected here in three case studies of representative property access efforts, offers some lessons and best practices that may apply to other remedial programs. While the Site Community Relations Manager (the author of this paper) managed the property access task, multi-disciplinary support from across the project was also critical to success in this endeavor. (authors)

  4. Electrical field assisted matrix solid phase dispersion as a powerful tool to improve the extraction efficiency and clean-up of fluoroquinolones in bovine milk.

    Science.gov (United States)

    da Silva, Mariana Cristina; Orlando, Ricardo Mathias; Faria, Adriana Ferreira

    2016-08-26

    This work presents a new method by electrical matrix solid phase dispersion for the extraction and clean-up of marbofloxacin, ofloxacin, norfloxacin, ciprofloxacin, enrofloxacin, difloxacin and sarafloxacin in bovine milk. Composition and pH of the eluent, applied electrical potential and polarity were optimized by experimental designs. The combination of the chromatographic and electrophoretic mechanisms allowed the extraction and clean-up in one step with low organic solvent consumption, high extraction throughput and elution automation. Linearity, precision, trueness and limit of quantification were evaluated and provided values in accordance with other methods recently developed for the analysis of fluoroquinolones in milk. This technique proved to be promising for the extraction and clean-up of ionizable analytes in different milk matrices. Copyright © 2016 Elsevier B.V. All rights reserved.

  5. Remediation System Evaluation, FCX Statesville Superfund Site

    Science.gov (United States)

    The FCX property was an agriculture distribution center that formulated, repackaged, and warehoused pesticides and fertilizers. The former Burlington Industries property to the north and upgradient of the FCX property was a textile facility.

  6. Superfund record of decision (EPA Region 5): Ormet Corporation, Hannibal, OH, September 1994

    Energy Technology Data Exchange (ETDEWEB)

    1994-09-12

    The Record of Decision presents the selected remedy for the Ormet Corporation Superfund Site. The purpose of this remedy is to eliminate or reduce contamination in soils, sediments and ground water, and to reduce the risks associated with exposure to contaminated materials. This is the first and final remedy planned for the Site.

  7. Optimization of solid phase extraction clean up and validation of quantitative determination of corticosteroids in urine by liquid chromatography-tandem mass spectrometry

    DEFF Research Database (Denmark)

    Andersen, Jens Hinge; Hansen, Lene Gram; Pedersen, Mikael

    2008-01-01

    A solid phase extraction (SPE) method for extraction and clean up of 9 synthetic corticosteroids was optimized for quantification by reversed-phase high-performance liquid chromatography/negative electrospray ionisation mass spectrometry. Clean up was accomplished using a mixed mode polymeric...... strong anion exchange SPE column. The final method was validated according to EU regulations for determination of residues of veterinarian drugs in products of animal origin. Initial results showed a large difference in ion suppression between samples of porcine and bovine urine. The aim of optimisation...

  8. Physicochemical regeneration of high silica zeolite Y used to clean-up water polluted with sulfonamide antibiotics.

    Science.gov (United States)

    Braschi, I; Blasioli, S; Buscaroli, E; Montecchio, D; Martucci, A

    2016-05-01

    High silica zeolite Y has been positively evaluated to clean-up water polluted with sulfonamides, an antibiotic family which is known to be involved in the antibiotic resistance evolution. To define possible strategies for the exhausted zeolite regeneration, the efficacy of some chemico-physical treatments on the zeolite loaded with four different sulfonamides was evaluated. The evolution of photolysis, Fenton-like reaction, thermal treatments, and solvent extractions and the occurrence in the zeolite pores of organic residues eventually entrapped was elucidated by a combined thermogravimetric (TGA-DTA), diffractometric (XRPD), and spectroscopic (FT-IR) approach. The chemical processes were not able to remove the organic guest from zeolite pores and a limited transformation on embedded molecules was observed. On the contrary, both thermal treatment and solvent extraction succeeded in the regeneration of the zeolite loaded from deionized and natural fresh water. The recyclability of regenerated zeolite was evaluated over several adsorption/regeneration cycles, due to the treatment efficacy and its stability as well as the ability to regain the structural features of the unloaded material.

  9. Validation of an HPLC analytical method coupled to a multifunctional clean-up column for the determination of deoxynivalenol.

    Science.gov (United States)

    Sugita-Konsihi, Yoshiko; Tanaka, Toshitsugu; Tabata, Setsuko; Nakajima, Masahiro; Nouno, Masanori; Nakaie, Yoko; Chonan, Takao; Aoyagi, Mitsutoshi; Kibune, Nobuyuki; Mizuno, Kazutoshi; Ishikuro, Eiichi; Kanamaru, Naoki; Minamisawa, Masatoshi; Aita, Norio; Kushiro, Masayo; Tanaka, Kenji; Takatori, Kosuke

    2006-04-01

    To evaluate a method using a multifunctional clean-up column coupled with high performance liquid chromatography as an official analytical method for the determination of deoxynivalenol in wheat used as food or feed, an inter-laboratory study was performed in 12 laboratories using four naturally contaminated wheat samples and one spiked sample. The relative standard deviations for repeatability (RSDr) and reproducibility (RSDR) of naturally contaminated wheat were in the range 5.8-11.3% and 12.0-20.7%, respectively. The HORRAT was less than 1.0 in each sample. From the spiking test, the recovery rate, RSDr, RSDR and HORRAT value were 100.0%, 11.2%, 10.3% and 0.5, respectively. The limit of quantification is 0.10 mg/kg from the range obtained in a linear calibration. Thus, it should be useful as a sensitive and validated analytical method for the determination of deoxynivalenol in wheat intended for use in food and feed.

  10. Tackling the challenge of selective analytical clean-up of complex natural extracts: the curious case of chlorophyll removal.

    Science.gov (United States)

    Bijttebier, Sebastiaan; D'Hondt, Els; Noten, Bart; Hermans, Nina; Apers, Sandra; Voorspoels, Stefan

    2014-11-15

    Alkaline saponification is often used to remove interfering chlorophylls and lipids during carotenoids analysis. However, saponification also hydrolyses esterified carotenoids and is known to induce artifacts. To avoid carotenoid artifact formation during saponification, Larsen and Christensen (2005) developed a gentler and simpler analytical clean-up procedure involving the use of a strong basic resin (Ambersep 900 OH). They hypothesised a saponification mechanism based on their Liquid Chromatography-Photodiode Array (LC-PDA) data. In the present study, we show with LC-PDA-accurate mass-Mass Spectrometry that the main chlorophyll removal mechanism is not based on saponification, apolar adsorption or anion exchange, but most probably an adsorption mechanism caused by H-bonds and dipole-dipole interactions. We showed experimentally that esterified carotenoids and glycerolipids were not removed, indicating a much more selective mechanism than initially hypothesised. This opens new research opportunities towards a much wider scope of applications (e.g. the refinement of oils rich in phytochemical content).

  11. Temperature performance of portable radiation survey instruments used for environmental monitoring and clean-up activities in Fukushima

    Science.gov (United States)

    Saegusa, Jun; Yanagisawa, Kayo; Hasumi, Atsushi; Shimizu, Takenori; Uchita, Yoshiaki

    2017-08-01

    Following the Fukushima Dai-ichi Nuclear Power Plant accident in March 2011, extensive radiation monitoring and environmental clean-up activities have been conducted throughout the Fukushima region. Outside air temperatures there reach 40 °C in summer and -20 °C in winter, which are beyond the quoted operational range of many radiation survey instruments. Herein, temperature performance of four types of portable Japanese radiation survey instruments widely used in Fukushima was experimentally investigated using a temperature-controlled chamber. They included two ionization chamber type instruments, Fuji NHA1 and Aloka ICS-323C, and two NaI(Tl) scintillation type ones, Fuji NHC7 and Aloka TCS-172B. Experimental results showed significantly diverse characteristics on the temperature dependences from one type of instrument to another. For example, NHA1 overestimated the ambient dose-equivalent rate by as much as 17% at -30 °C and 10% at 40 °C, whereas the TCS-172B readings underestimated the rate by 30% at -30 °C and 7% at 40 °C.

  12. A probabilistic model estimating oil spill clean-up costs--a case study for the Gulf of Finland.

    Science.gov (United States)

    Montewka, Jakub; Weckström, Mia; Kujala, Pentti

    2013-11-15

    Existing models estimating oil spill costs at sea are based on data from the past, and they usually lack a systematic approach. This make them passive, and limits their ability to forecast the effect of the changes in the oil combating fleet or location of a spill on the oil spill costs. In this paper we make an attempt towards the development of a probabilistic and systematic model estimating the costs of clean-up operations for the Gulf of Finland. For this purpose we utilize expert knowledge along with the available data and information from literature. Then, the obtained information is combined into a framework with the use of a Bayesian Belief Networks. Due to lack of data, we validate the model by comparing its results with existing models, with which we found good agreement. We anticipate that the presented model can contribute to the cost-effective oil-combating fleet optimization for the Gulf of Finland. It can also facilitate the accident consequences estimation in the framework of formal safety assessment (FSA).

  13. Site Restoration

    Energy Technology Data Exchange (ETDEWEB)

    Noynaert, L.; Bruggeman, A.; Cornelissen, R.; Massaut, V.; Rahier, A

    2001-04-01

    The objectives, the programme, and the achievements of the Site Restoration Department of SCK-CEN in 2000 are summarised. Main activities include the decommissioning of the BR3 PWR-reactor as well as other clean-up activities, projects on waste minimisation and activities related to the management of decommissioning projects. The department provides consultancy and services to external organisations.

  14. Site Environmental Report for 2014

    Energy Technology Data Exchange (ETDEWEB)

    Pauer, Ronald O. [Lawrence Berkeley National Lab. (LBNL), Berkeley, CA (United States); Baskin, David [Lawrence Berkeley National Lab. (LBNL), Berkeley, CA (United States); Borglin, Ned [Lawrence Berkeley National Lab. (LBNL), Berkeley, CA (United States); Fox, Robert [Lawrence Berkeley National Lab. (LBNL), Berkeley, CA (United States); Harvey, Zachary [Lawrence Berkeley National Lab. (LBNL), Berkeley, CA (United States); Jelinski, John [Lawrence Berkeley National Lab. (LBNL), Berkeley, CA (United States); Thorson, Patrick [Lawrence Berkeley National Lab. (LBNL), Berkeley, CA (United States); Wehle, Petra [Lawrence Berkeley National Lab. (LBNL), Berkeley, CA (United States); Xu, Suying [Lawrence Berkeley National Lab. (LBNL), Berkeley, CA (United States)

    2015-09-01

    The annual Site Environmental Report documents Lawrence Berkeley National Laboratory’s performance in reducing its environmental impacts, progress toward cleaning up groundwater contamination, and compliance with applicable Department of Energy, federal, state, and local environmental regulations.

  15. Effects of a remedial system and its operation on volatile organic compound-contaminated ground water, Operable Unit 1, Savage Municipal Well Superfund Site, Milford, New Hampshire, 1998-2004

    Science.gov (United States)

    Harte, Philip T.

    2006-01-01

    The Savage Municipal Well Superfund site in the Town of Milford, N.H., is underlain by a 0.5-square mile plume of volatile organic compounds (VOCs), mostly tetrachloroethylene (PCE). The plume occurs mostly within a highly transmissive sand and gravel layer, but also extends into underlying till and bedrock. The plume has been divided into two areas called Operable Unit 1 (OU1), which contains the primary source area, and Operable Unit 2 (OU2), which is defined as the extended plume area. PCE concentrations in excess of 100,000 parts per billion (ppb) had been detected in the OU1 area in 1995, indicating a likely Dense Non-Aqueous Phase Liquid (DNAPL) source. In the fall of 1998, the New Hampshire Department of Environmental Services (NHDES) and the U.S. Environmental Protection Agency (USEPA) installed a remedial system in OU1 to contain and capture the dissolved VOC plume. The OU1 remedial system includes a low-permeability barrier wall that encircles the highest detected concentrations of PCE, and a series of injection and extraction wells to contain and remove contaminants. The barrier wall likely penetrates the full thickness of the sand and gravel; in most places, it also penetrates the full thickness of the underlying basal till and sits atop bedrock. Remedial injection and extraction wells have been operating since the spring of 1999 and include a series of interior (inside the barrier wall) injection and extractions wells and exterior (outside the barrier wall) injection and extraction wells. A recharge gallery outside the barrier wall receives the bulk of the treated water and reinjects it into the shallow aquifer. From 1998 to 2004, PCE concentrations decreased by an average of 80 percent at most wells outside the barrier wall. This decrease indicates (1) the barrier wall and interior extraction effectively contained high PCE concentrations inside the wall, (2) other sources of PCE did not appear to be outside of the wall, and (3) ambient ground

  16. The Development of an Automated Clean-up for Fat Extracts in the Routine Analysis of Organochlorine Compounds in Fish Meat

    Directory of Open Access Journals (Sweden)

    Ana Andreea CIOCA

    2017-05-01

    Full Text Available The present work describes the development of a new, automatic High Performance Liquid Chromatography (HPLC Clean-up step, in the methodology of sample preparation and multi-residue determination of organochlorine compounds (OCs in fish meat. 24 OCs were taken into study. In addition 7 Polychlorinated Biphenyls (PCBs, 7 chlorobenzene compounds and one 2,3,7,8-Tetrachlorodibenzo-p-dioxin (TCDD were investigated. The HPLC conditions were established in accordance with the validated traditional Clean-up step of the laboratory. The technique was applied on a dilution of analytes of interest in order to establish the period of time in which the compounds are eluted. Another set of experiments involved fish oil, in order to identify and separate the fat fraction from the analytes. To confirm the findings of the experiments mentioned above, extracts of fish samples obtained after Accelerated Solvent Extraction (ASE were examined. The samples were spiked with the analytes of interest before HPLC clean-up step and quantified through Gas Chromatography coupled with tandem Mass Spectrometry (GC-MS/MS. A HPLC clean-up technique lasting 38 minutes/sample was developed. The method is not suitable for OCs such as Endosulfansulfat and Endrine Ketone due to the very low recovery results.Â

  17. Multiplug filtration clean-up with multiwalled carbon nanotubes in the analysis of pesticide residues using LC-ESI-MS/MS.

    Science.gov (United States)

    Zhao, Pengyue; Fan, Sufang; Yu, Chuanshan; Zhang, Junyan; Pan, Canping

    2013-10-01

    A novel design for a rapid clean-up method was developed for the analysis of pesticide residues in fruit and vegetables followed by LC-ESI-MS/MS. The acetonitrile-based sample extraction technique was used to obtain the extracts, and further clean-up was carried out by applying the streamlined procedure on a multiplug filtration clean-up column coupled with a syringe. The sorbent used for clean-up in this research is multiwalled carbon nanotubes, which was mixed with anhydrous magnesium sulfate to remove water from the extracts. This method was validated on 40 representative pesticides and apple, cabbage, and potato sample matrices spiked at two concentration levels of 10 and 100 μg/kg. It exhibited recoveries between 71 and 117% for most pesticides with RSDs 0.995 for most studied pesticides between concentration levels of 10-500 μg/L. The LOQs for 40 pesticides ranged from 2 to 50 μg/kg. The developed method was successfully applied to the determination of pesticide residues in market fruit and vegetable samples.

  18. Molecular level insights to the interaction of toluene with ZrO2-based biomass gasification gas clean-up catalysts

    NARCIS (Netherlands)

    Viinikainen, T.; Kauppi, I.; Korhonen, S.; Lefferts, L.; Kanervo, J.; Lehtonen, J.

    2013-01-01

    Gasification of biomass, followed by ZrO2-catalyzed hot gas clean-up at 600–900 °C for the oxidation of impurities (such as tar), is an environmentally attractive way to produce heat and power or synthesis gas. The interaction of toluene (as a model compound for tar) with ZrO2-based gasification gas

  19. A LC/UV/Vis method for determination of cyanocobalamin in multivitamin dietary supplements with on-line sample clean-up

    Science.gov (United States)

    A HPLC-UV method using a two-column strategy with a switching valve for on-line sample clean-up was developed for the determination of cyanocobalamin (CN-CBL-vitamin B12, in dietary supplements. The method uses two columns, an Agilent Zorbax C8 (150 mm x 4.6 mm, 5 um particle) reversed-phase column...

  20. Analysis of sterigmatocystin in cereals, animal feed, seeds, beer and cheese by immunoaffinity column clean-up and HPLC and LC-MS/MS quantification.

    Science.gov (United States)

    Marley, Elaine; Brown, Phyllis; Mackie, Jennifer; Donnelly, Carol; Wilcox, Joyce; Pietri, Amedeo; Macdonald, Susan

    2015-01-01

    A method is reported for the analysis of sterigmatocystin in various food and feed matrices using a commercial sterigmatocystin immunoaffinity column (IAC) for sample clean-up prior to HPLC analysis by UV with mass spectrometric detection (LC-MS/MS). Cereals (wheat, oats, rye, maize and rice), sunflower seeds and animal feed were spiked with sterigmatocystin at levels from 0.75 to 50 µg kg(-1) to establish method performance. Using acetonitrile/water extraction followed by IAC clean-up, and analysis by HPLC with detection at 325 nm, recoveries ranged from 68% to 106%, with repeatability from 4.2% to 17.5%. The limit of quantification with UV detection in these matrices was 1.5 µg kg(-1). For the analysis of beer and cheese the sample preparation prior to IAC clean-up was changed to accommodate the different properties of the matrix, prior to analysis by LC-MS/MS. For beer and cheese spiked at 5.0 µg kg(-1) the recoveries were 94% and 104%, and precision (RSDs) were 1.9% and 2.9% respectively. The limits of quantification by LC-MS/MS in beer and cheese were 0.02 and 0.6 µg kg(-1) respectively. The sterigmatocystin IAC was demonstrated to provide an efficient clean-up of various matrices to enable this mycotoxin to be determined by either HPLC with UV detection or LC-MS/MS.

  1. Separation and determination of citrinin in corn using HPLC fluorescence detection assisted by molecularly imprinted solid phase extraction clean-up

    Science.gov (United States)

    A liquid chromatography based method to detect citrinin in corn was developed using molecularly imprinted solid phase extraction (MISPE) sample clean-up. Molecularly imprinted polymers were synthesized using 1,4-dihydroxy-2-naphthoic acid as the template and an amine functional monomer. Density func...

  2. Molecular level insights to the interaction of toluene with ZrO2-based biomass gasification gas clean-up catalysts

    NARCIS (Netherlands)

    Viinikainen, T.; Kauppi, I.; Korhonen, S.; Lefferts, Leonardus; Kanervo, J.; Lehtonen, J.

    2013-01-01

    Gasification of biomass, followed by ZrO2-catalyzed hot gas clean-up at 600–900 °C for the oxidation of impurities (such as tar), is an environmentally attractive way to produce heat and power or synthesis gas. The interaction of toluene (as a model compound for tar) with ZrO2-based gasification gas

  3. Human Genotoxic Study Carried Out Two Years after Oil Exposure during the Clean-up Activities Using Two Different Biomarkers

    Directory of Open Access Journals (Sweden)

    Gloria Biern

    2015-11-01

    Full Text Available Micronuclei, comet and chromosome alterations assays are the most widely used biomarkers for determining the genotoxic damage in a population exposed to genotoxic chemicals. While chromosome alterations are an excellent biomarker to detect short- and long-term genotoxic effects, the comet assay only measures early biological effects, and furthermore it is unknown whether nuclear abnormalies, such as those measured in the micronucleus test, remain detectable long-term after an acute exposure. In our previous study, an increase in structural chromosome alterations in fishermen involved in the clean-up of the Prestige oil spill, two years after acute exposure, was detected. The aim of this study is to investigate whether, in lymphocytes from peripheral blood, the nuclear abnormalies (micronucleus, nucleoplasmic bridges and nuclear buds have a similar sensitivity to the chromosome damage analysis for genotoxic detection two years after oil exposure in the same non-smoker individuals and in the same peripheral blood extraction. No significant differences in nuclear abnormalies frequencies between exposed and non-exposed individuals were found (p > 0.05. However, chromosome damage, in the same individuals, was higher in exposed vs. non-exposed individuals, especially for chromosome lesions (p < 0.05. These findings, despite the small sample size, suggest that nuclear abnormalities are probably less-successful biomarkers than are chromosome alterations to evaluate genotoxic effects two or more years after an exposure to oil. Due to the great advantage of micronucleus automatic determination, which allows for a rapid study of hundreds of individuals exposed to genotoxic chemical exposure, further studies are needed to confirm whether this assay is or is not useful in long-term genotoxic studies after the toxic agent is no longer present.

  4. A Membrane-Based Electro-Separation Method (MBES) for Sample Clean-Up and Norovirus Concentration.

    Science.gov (United States)

    Kang, Wei; Cannon, Jennifer L

    2015-01-01

    Noroviruses are the leading cause of acute gastroenteritis and foodborne illnesses in the United States. Enhanced methods for detecting noroviruses in food matrices are needed as current methods are complex, labor intensive and insensitive, often resulting in inhibition of downstream molecular detection and inefficient recovery. Membrane-based electro-separation (MBES) is a technique to exchange charged particles through a size-specific dialysis membrane from one solution to another using electric current as the driving force. Norovirus has a net negative surface charge in a neutrally buffered environment, so when placed in an electric field, it moves towards the anode. It can then be separated from the cathodic compartment where the sample is placed and then collected in the anodic compartment for downstream detection. In this study, a MBES-based system was designed, developed and evaluated for concentrating and recovering murine norovirus (MNV-1) from phosphate buffer. As high as 30.8% MNV-1 migrated from the 3.5 ml sample chamber to the 1.5 ml collection chamber across a 1 μm separation membrane when 20 V was applied for 30 min using 20 mM sodium phosphate with 0.01% SDS (pH 7.5) as the electrolyte. In optimization of the method, weak applied voltage (20 V), moderate duration (30 min), and low ionic strength electrolytes with SDS addition were needed to increase virus movement efficacy. The electric field strength of the system was the key factor to enhance virus movement, which could only be improved by shortening the electrodes distance, instead of increasing system applied voltage because of virus stability. This study successfully demonstrated the norovirus mobility in an electric field and migration across a size-specific membrane barrier in sodium phosphate electrolyte. With further modification and validation in food matrixes, a novel, quick, and cost-effective sample clean-up technique might be developed to separate norovirus particles from food

  5. 净化网络环境及其机制%On Cleaning up Network Environment and Developing its Mechanism

    Institute of Scientific and Technical Information of China (English)

    盛剑锋; 余凌

    2011-01-01

    我国互联网规模的高速发展给人们的工作、学习与生活带来了便利,但互联网的虚拟性、开放性和交互性等特征,使网络也成为一些人从事违法活动的场所。依法采取监管措施,规范净化网络环境,已成为世界各国的共识。我国在借鉴国外经验与方法的基础上,应结合我国国情,在开展打击整治网络色情等专项行动的同时,要不断完善网络立法、技术监控、行业自律、社会监督、国际合作等措施,建立健全防范和查处的长效管理机制。%With China's rapid development of the Internet in its scale, people's work, study and life are made easier, but the Internet is likely to be a venue for illegal activities because it is virtual, open and interactive. It has been a common practice in all the countries to take regulatory measures to regulate and clean up the network environment according to law. We need to borrow foreign practices and methods, and combine them with China's actual conditions. In the special campaign to crack down on the online pornography, we must constantly improve our work at the network legislation, technical monitoring, self-discipline of the network trades, social supervision, and international cooperation to establish a long-acting management mechanism for a sound prevention and investigation.

  6. A Membrane-Based Electro-Separation Method (MBES for Sample Clean-Up and Norovirus Concentration.

    Directory of Open Access Journals (Sweden)

    Wei Kang

    Full Text Available Noroviruses are the leading cause of acute gastroenteritis and foodborne illnesses in the United States. Enhanced methods for detecting noroviruses in food matrices are needed as current methods are complex, labor intensive and insensitive, often resulting in inhibition of downstream molecular detection and inefficient recovery. Membrane-based electro-separation (MBES is a technique to exchange charged particles through a size-specific dialysis membrane from one solution to another using electric current as the driving force. Norovirus has a net negative surface charge in a neutrally buffered environment, so when placed in an electric field, it moves towards the anode. It can then be separated from the cathodic compartment where the sample is placed and then collected in the anodic compartment for downstream detection. In this study, a MBES-based system was designed, developed and evaluated for concentrating and recovering murine norovirus (MNV-1 from phosphate buffer. As high as 30.8% MNV-1 migrated from the 3.5 ml sample chamber to the 1.5 ml collection chamber across a 1 μm separation membrane when 20 V was applied for 30 min using 20 mM sodium phosphate with 0.01% SDS (pH 7.5 as the electrolyte. In optimization of the method, weak applied voltage (20 V, moderate duration (30 min, and low ionic strength electrolytes with SDS addition were needed to increase virus movement efficacy. The electric field strength of the system was the key factor to enhance virus movement, which could only be improved by shortening the electrodes distance, instead of increasing system applied voltage because of virus stability. This study successfully demonstrated the norovirus mobility in an electric field and migration across a size-specific membrane barrier in sodium phosphate electrolyte. With further modification and validation in food matrixes, a novel, quick, and cost-effective sample clean-up technique might be developed to separate norovirus particles

  7. Superfund: Interagency Agreements and Improved Project Management Needed to Achieve Cleanup Progress at Key Defense Installations

    Science.gov (United States)

    2010-07-01

    Superfund completing the remedial investigation, which would include a human and ecological risk assessment , feasibility study, proposed plan...EPA said that a human and ecological risk assessment —which would estimate how threatening a hazardous waste site is to human health and the

  8. Grain Handling Facility at Freeman, Washington Added to Superfund Cleanup List

    Science.gov (United States)

    (September 28, 2015 - Seattle) The U.S. Environmental Protection Agency has added the Grain Handling Facility at Freeman, in Spokane County, Washington, to the Superfund National Priorities List. The site was added to the NPL after EPA considered input rec

  9. The NucleoSpin® DNA Clean-up XS kit for the concentration and purification of genomic DNA extracts: an alternative to microdialysis filtration.

    Science.gov (United States)

    Hudlow, William R; Krieger, Robert; Meusel, Markus; Sehhat, Joshua C; Timken, Mark D; Buoncristiani, Martin R

    2011-06-01

    Traditionally, DNA extracts from biological evidence items have been concentrated and rinsed using microdialysis filtration units, including the Centricon(®) and Microcon(®) centrifugal filter devices. As an alternative to microdialysis filtration, we present an optimized method for using NucleoSpin(®) XS silica columns to concentrate and clean-up aqueous extracts from the organic extraction of DNA from biological samples. The method can be used with standard organic extraction and dithiothreitol (DTT)-based differential extraction methods with no modifications to these methods prior to the concentration and clean-up step. Extracts from laboratory-prepared bloodstains, saliva and semen stains have been successfully amplified with both qPCR and STR assays. Finally, the total time to process a set of samples with the NucleoSpin(®) XS column is approximately 30 min vs. approximately 1.5h with the Centricon(®) YM-100 filter device.

  10. A review of polymer nanofibres by electrospinning and their application in oil-water separation for cleaning up marine oil spills.

    Science.gov (United States)

    Sarbatly, Rosalam; Krishnaiah, Duduku; Kamin, Zykamilia

    2016-05-15

    The growths of oil and gas exploration and production activities have increased environmental problems, such as oil spillage and the resulting pollution. The study of the methods for cleaning up oil spills is a critical issue to protect the environment. Various techniques are available to contain oil spills, but they are typically time consuming, energy inefficient and create secondary pollution. The use of a sorbent, such as a nanofibre sorbent, is a technique for controlling oil spills because of its good physical and oil sorption properties. This review discusses about the application of nanofibre sorbent for oil removal from water and its current developments. With their unique physical and mechanical properties coupled with their very high surface area and small pore sizes, nanofibre sorbents are alternative materials for cleaning up oil spills.

  11. Technology for the oil spills clean-up which provides preliminary accumulation of sorbents into the area of emergence and localization oil spills

    Directory of Open Access Journals (Sweden)

    M.L.Soroka

    2012-12-01

    Full Text Available Introduction: The implementation of measures for the prevention and spill of dangerous goods is an important aspect of sustainable development of railway transport. oil spills accident are the most dangerous. They are accompanied by significant pollution of all environmental objects. Studying and development of oil localization and clean-up technologies of such accidents is an important problem of environmental protection to modern conditions of railway transport development. The purpose: to improve the effectiveness of traditional methods of oil spill elimination and the development of new clean-up technologies adapted to the real conditions of the railway transport of Ukraine. Methods: To achieve the research purposes was used analysis of material flows, typical for places emergence and localization of the oil spill on the railways. Results: Analysis of standard technological scheme for the oil spills eliminations has shown that the most difficult task of effective clean-up surfaces is the timely delivery of oil sorbents and special equipment to the area spill containment. The general effectiveness of the elimination activities specifies the time from the beginning contact of dangerous goods with environmental objects to the absorption it into the structure of sorbent . Us was developed the technological scheme of oil spill elimination. This scheme provide a permanent and fast access to the sorbents into the oil spill localization area. It was proposed to device that allows you to transport the sorbent into sorption booms directly on the tank for transportation of petroleum products. Conclusions: Preventative accumulation of sorbents to the oil spill elimination into the localization area provides the organizational and operational simplicity of all stages of clean-up technology. Technical and economic assessment shows that the proposed technology is effective, technologically feasible and economically competitive.

  12. Aptamer-affinity column clean-up coupled with ultra high performance liquid chromatography and fluorescence detection for the rapid determination of ochratoxin A in ginger powder.

    Science.gov (United States)

    Yang, Xihui; Kong, Weijun; Hu, Yichen; Yang, Meihua; Huang, Luqi; Zhao, Ming; Ouyang, Zhen

    2014-04-01

    Aptamers are single-stranded oligonucleotides with high affinity and specificity and are widely used in targets separation and enrichment. Here, an aptamer-affinity column (AAC) was firstly prepared in-house through a covalent immobilization strategy. Then, ochratoxin A (OTA) in ginger powder was absorbed and enriched using the new aptamer-based clean-up technology for the first time, and was further analyzed by ultra high performance liquid chromatography with fluorescence detection. After optimization, the average recoveries for blank samples spiked with OTA at 5, 15, and 45 μg/kg ranged from 85.36 to 96.83%. Furthermore, the AAC exhibited a similar accuracy as an immunoaffinity column to clean up OTA in ginger powder. Above all, it exhibited better reusability, twice that of the immunoaffinity column, had lower toxicity and cost, and took less time. Of 25 contaminated ginger powder samples, OTA contamination levels ranged from 1.51 to 4.31 μg/kg, which were lower than the European Union (EU) regulatory limits. All the positive samples were further confirmed by ultra-fast LC with MS/MS. In conclusion, the method of clean-up based on the AAC coupled to ultra-HPLC with fluorescence detection was rapid, specific, and sensitive for the quantitative analysis of OTA in a complex matrix.

  13. The Ability of Watercress (Nasturtiumofficinale and Pennyroyal (Menthapulegium in Clean up Excess Nitrate and Phosphate of Water

    Directory of Open Access Journals (Sweden)

    Z. Ahmadpoor

    2016-02-01

    Full Text Available Introduction: There is necessary to clean up the nitrate and phosphate from surface waters before effluence of them to environment and eutrophication formation because of water health importance and considering to nitrate and phosphate consequences. Nitrate and ammonium as the - forms of inorganic and nitrogen have been subjected to the center of issues related to environment pollutants and water resources in a long time. The nitrate is more important than other inorganic nitrogen forms such as ammonium because of various reasons such as high dynamics and causing diseases such as some of digestion system and lymph nodes cancers in adults and methemoglobinemia in infants. Therefore the maximum concentration of this ion in drinking water has been determined as 45 mg.Lit-1 by WHO. Regarding the importance of the water health and the complications due to existence of some compounds such as nitrate and phosphate, in this experiment, the possibility of elimination or decreasing excess nitrate and phosphate from water in hydroponic conditions using of two watercress and pennyroyal plants was evaluated. Watercress(Nasturtiumofficinale and pennyroyal (Menthapulegiumwere selected because of some properties such as adaptability with the most climates of Iranamd less requirements care. Materials and Methods: Two RCD factorial experiments were carried out to evaluate the ability of watercress and pennyroyal to biosorption of nitrate and phosphate from polluted water in hydroponic conditions. First factor was plant species including watercress and pennyroyal. Second factor included nitrate (50, 100, 150 Mg/L and phosphate (5, 10, 15 Mg/L in first and second experiment respectively.The final concentrations of nitrate and phosphate in water was measured using spectrophotometer in wavelength of 410 nm and 690 nm by sulphatebrucine and chloride methods , respectively, which are mentioned in Standard Methods for the Examination of Water and Wastewater. At the end

  14. Development of sample preparation method for auxin analysis in plants by vacuum microwave-assisted extraction combined with molecularly imprinted clean-up procedure.

    Science.gov (United States)

    Hu, Yuling; Li, Yuanwen; Zhang, Yi; Li, Gongke; Chen, Yueqin

    2011-04-01

    A novel sample preparation method for auxin analysis in plant samples was developed by vacuum microwave-assisted extraction (VMAE) followed by molecularly imprinted clean-up procedure. The method was based on two steps. In the first one, conventional solvent extraction was replaced by VMAE for extraction of auxins from plant tissues. This step provided efficient extraction of 3-indole acetic acid (IAA) from plant with dramatically decreased extraction time, furthermore prevented auxins from degradation by creating a reduced oxygen environment under vacuum condition. In the second step, the raw extract of VMAE was further subjected to a clean-up procedure by magnetic molecularly imprinted polymer (MIP) beads. Owing to the high molecular recognition ability of the magnetic MIP beads for IAA and 3-indole-butyric acid (IBA), the two target auxins in plants can be selectively enriched and the interfering substance can be eliminated by dealing with a magnetic separation procedure. Both the VMAE and the molecularly imprinted clean-up conditions were investigated. The proposed sample preparation method was coupled with high-performance liquid chromatogram and fluorescence detection for determination of IAA and IBA in peas and rice. The detection limits obtained for IAA and IBA were 0.47 and 1.6 ng/mL and the relative standard deviation were 2.3% and 2.1%, respectively. The IAA contents in pea seeds, pea embryo, pea roots and rice seeds were determined. The recoveries were ranged from 70.0% to 85.6%. The proposed method was also applied to investigate the developmental profiles of IAA concentration in pea seeds and rice seeds during seed germination.

  15. Efficient sample clean-up and online preconcentration for sensitive determination of melamine in milk samples by capillary electrophoresis with contactless conductivity detection.

    Science.gov (United States)

    Ji, Yan-ling; Chen, Xiao-wei; Zhang, Zhu-bao; Li, Jing; Xie, Tian-yao

    2014-10-01

    Based on an efficient sample clean-up and field-amplified sample injection online preconcentration technique in capillary electrophoresis with contactless conductivity detection, a new analytical method for the sensitive determination of melamine in milk samples was established. In order to remove the complex matrix interference, which resulted in a serious problem during field-amplified sample injection, liquid-liquid extraction was utilized. As a result, liquid-liquid extraction provides excellent sample clean-up efficiency when ethyl acetate was used as organic extraction by adjusting the pH of the sample solution to 9.5. Both inorganic salts and biological macromolecules are effectively removed by liquid-liquid extraction. The sample clean-up procedure, capillary electrophoresis separation parameters and field-amplified sample injection conditions are discussed in detail. The capillary electrophoresis separation was achieved within 5 min under the following conditions: an uncoated fused-silica capillary, 12 mM HAc + 10 mM NaAc (pH = 4.6) as running buffer, separation voltage of +13 kV, electrokinetic injection of +12 kV × 10 s. Preliminary validation of the method performance with spiked melamine provided recoveries >90%, with limits of detection and quantification of 0.015 and 0.050 mg/kg, respectively. The relative standard deviations of intra- and inter-day were below 6%. This newly developed method is sensitive and cost effective, therefore, suitable for screening of melamine contamination in milk products.

  16. Determination of mycophenolic acid in mest products using mixed mode reversed phase-anion exchange clean-up and liquid chromatography-high-resolution mass spectrometry

    DEFF Research Database (Denmark)

    Sørensen, Louise Marie; Nielsen, Kristian Fog; Jacobsen, Thomas

    2008-01-01

    A method for determination of mycophenolic acid (MPA) in dry-cured ham, fermented sausage and liver pate is described. MPA was extracted from meat with bicarbonate-acetonitrile, further cleaned-up by mixed mode reversed phase-anion exchange and detected using a LC-MS system with electrospray...... ionisation-time-of-flight detection. The limit of detection was 4 mu g/kg in sausage and 6 mu g/kg in ham and pate. The method was successfully used for quantification of MPA in dry-cured ham and liver pate artificially inoculated with Penicillium brevicompactum. Levels ranged from 190 mu g/kg in centre to I...

  17. SITE TECHNOLOGY CAPSULE: TEXACO GASIFICATION PROCESS

    Science.gov (United States)

    In 1980, the U.S. Congress passed the Comprehensive Environmental Response, Compensation, and Liability Act (CERCLA), also known as Superfund. to protect human health and the environment from uncontrolled hazardous waste sites. CERCLA was amended by the Superfund Amendments and R...

  18. Cleaning up the Legacy of the Cold War: Plutonium Oxides and the Role of Synchrotron Radiation Research

    Energy Technology Data Exchange (ETDEWEB)

    Clark, David Lewis [Los Alamos National Lab. (LANL), Los Alamos, NM (United States)

    2015-01-21

    The deceptively simple binary formula of AnO2 belies an incredibly complex structural nature, and propensity to form mixed-valent, nonstoichiometric phases of composition AnO2±x. For plutonium, the very formation of PuO2+x has challenged a long-established dogma, and raised fundamental questions for long-term storage and environmental migration. This presentation covers two aspects of Los Alamos synchrotron radiation studies of plutonium oxides: (1) the structural chemistry of laboratory-prepared AnO2+x systems (An = U, Pu; 0 ≤ x ≤ 0.25) determined through a combination of x-ray absorption fine structure spectroscopy (XAFS) and x-ray scattering of laboratory prepared samples; and (2) the application of synchrotron radiation towards the decontamination and decommissioning of the Rocky Flats Environmental Technology Site. Making the case for particle transport mechanisms as the basis of plutonium and americium mobility, rather than aqueous sorption-desorption processes, established a successful scientific basis for the dominance of physical transport processes by wind and water. The scientific basis was successful because it was in agreement with general theory on insolubility of PuO2 in oxidation state IV, results of ultrafiltration analyses of field water/sediment samples, XAFS analyses of soil, sediment, and concrete samples, and was also in general agreement with on-site monitoring data. This understanding allowed Site contractors to rapidly move to application of soil erosion and sediment transport models as the means of predicting plutonium and americium transport, which led to design and application of site-wide soil erosion control technology to help control downstream concentrations of plutonium and americium in streamflow.

  19. Development and demonstration of a mobile reverse osmosis adsorption treatment system for environmental emergency clean-ups

    Energy Technology Data Exchange (ETDEWEB)

    1988-03-01

    A project was undertaken to develop and demonstrate a mobile reverse osmosis/adsorption system for treating water contaminated by organic chemicals. The system has two primary unit operations. The contaminated water is processed by reverse osmosis to produce a clean stream for discharge and a stream for further processing in which the organic contaminants have been concentrated up to 10 times their original concentration. The latter stream is treated in granular adsorbent columns where the contaminants are removed and an effluent suitable for discharge is produced. The contaminated water can be treated on-site and the contaminants can be removed from the site adsorbed on a relatively small amount of carbon. Field tests were conducted at two sites, one contaminated by leachate from a former chemical waste landfill and the other by drainage water from a petroleum and petrochemical transfer station. The 60-day demonstrations showed that reverse osmosis technology can be successfully used for treatment of water contaminated by toxic volatile organics and that granular activated carbon adsorption columns can be successfully used to remove those organics from the concentrate produced by reverse osmosis processing. However, the study also showed that the presence of significant quantities of suspended materials or Fe cause operational problems which limit the success of reverse osmosis processing under these conditions. These problems can be effectively addressed by adding an ultrafiltration pretreatment. 13 refs., 60 figs., 56 tabs.

  20. Validation and robustness testing of a HPLC method for the determination of avermectins and moxidectin in animal liver samples using an alumina column clean-up.

    Science.gov (United States)

    Danaher, M; O'Keeffe, M; Glennon, J D

    2000-10-01

    A multi-residue method has been developed for the quantitative determination of moxidectin, abamectin, doramectin and ivermectin in liver samples, with capability for qualitative identification of the presence of eprinomectin. Liver samples are extracted with isooctane, followed by clean-up on alumina-N solid phase extraction (SPE) cartridges. Extracts are derivatised and determined by high-performance liquid chromatography (HPLC) with fluorescence detection. The method was validated using bovine liver fortified at levels of 4 and 20 micrograms kg-1 with the drugs. The mean recovery from bovine liver ranged between 90 and 96%. The intra and inter-assay variations showed RSD typically of < 5% and < 10%, respectively. The procedure was applied also to ovine and porcine liver, giving similar results. A robustness study, carried out on the alumina clean-up step, indicated that the step is relatively insensitive to method changes. However, significant differences overall were found for the type of alumina and/or commercial SPE cartridge used. The limit of quantitation of the method is 2 micrograms kg-1 (ppb).

  1. [Simultaneous determination of zeranols and chloramphenicol in foodstuffs of animal origin by combination immunoaffinity column clean-up and liquid chromatography-tandem mass spectrometry].

    Science.gov (United States)

    Wang, Qing; Wang, Guomin; Xi, Cunxian; Li, Xianliang; Chen, Dongdong; Tang, Bobin; Zhang, Lei; Zhao, Hua

    2014-06-01

    A combination immunoaffinity column (IAC-CZ) clean-up and liquid chromatography-tandem mass spectrometry (LC-MS/MS) analytical method was successfully developed for zearalenol, beta-zearalenol and zearalenone) and chloramphenicol (CAP) in foodstuffs of animal origin. The samples (fish, liver, milk and honey) were enzymatically digested by beta-glucuronidase/sulfatase for about 16 h and then extracted with ether. The extracts were evaporated to dryness and then the residues were dissolved by 1.0 mL of 50% acetonitrile solution. After filtered and diluted with PBS buffer, the reconstituted solution were cleaned-up with a IAC-CZ and then analyzed by LC-MS/MS in multiple reaction monitoring (MRM) mode. The chromatographic separation was performed on a Shimadzu Shim-pack VP-ODS column with gradient elution by acetonitrile and 2 mmol/L ammonium acetate solution. The detection was carried out by electrospray negative ionization mass spectrometry in MRM mode. The proposed method was validated by the limit of detection (0.04-0.10 microg/kg), linearity (R2 > or = 0.999 0), average recoveries (70.9%-95.6%) and precisions (2.0% - 11.8%). The developed method is reliable, sensitive and has good applicability. The combination immunoaffinity column was proved to be an effective pretreatment technique to decrease the matrix effect, and it met the requirements of residue analysis of co-occurring zeranols and chloramphenicol.

  2. Determination of carbendazim, thiabendazole, and o-phenylphenol residues in lemons by HPLC following sample clean-up by ion-pairing.

    Science.gov (United States)

    Prousalis, Konstantinos P; Polygenis, Dimitris A; Syrokou, Alexandra; Lamari, Fotini N; Tsegenidis, Theodore

    2004-06-01

    An efficient analytical method is presented involving effective sample clean-up with solid-phase extraction and HPLC-UV analysis for the simultaneous determination of carbendazim, thiabendazole, and o-phenylphenol residues in lemons. Sample preparation involves extraction with acetonitrile acidified with trifluoroacetic acid and an ethyl acetate/petroleum ether mixture. Purification of the crude extract was carried out with liquid-liquid partitioning after addition of an aqueous ammonia solution. Final clean-up was performed on polymeric reversed-phase cartridges pretreated with sodium dodecyl sulfate. Chromatographic analysis was performed on a reversed-phase HPLC column isocratically eluted with an acetonitrile/water/ammonia mixture and UV detection at 254 nm. The chromatographic method is repeatable, reproducible, and sensitive. Fungicide recoveries from lemon samples fortified at levels of 5 and 1 mg kg(-1) were 81-85% for carbendazim, 96-98% for thiabendazole, and 81-106% for o-phenylphenol with coefficients of variation of 2.5-7.4%. Detection limits for carbendazim, thiabendazole, and o-phenylphenol in lemons were 0.21, 0.27, and 0.51 mg kg(-1), respectively.

  3. 移动互联网有害信息清理研究%Research on Cleaning up the Harmful Information on the Mobile Internet

    Institute of Scientific and Technical Information of China (English)

    文湘江; 马少武; 姜智峰; 唐雄燕

    2011-01-01

    With regard to the spread of harmful information which is hidden deeply and governed difficultly on the mobile internet,such as pornography,this paper provides the technical scheme and deployment scheme of cleaning up the harmful information,makes a comparative analysis on various network deployment modes,describes the steps and typical scenes of cleaning up the harmful information and finally proposes relevant suggestions of management.%针对在移动互联网上传播淫秽色情等有害信息具有隐蔽性大、治理难的问题,给出有害信息清理的技术方案,分析有害信息系统的网络部署方案,对几种系统的网络部署方式进行比较分析,描述了有害信息清理的步骤和典型场景,最后给出相应的监管建议。

  4. Simultaneous determination of multi-class veterinary drugs in chicken processed foods and muscle using solid-supported liquid extraction clean-up.

    Science.gov (United States)

    Yoshikawa, Souichi; Nagano, Chieko; Kanda, Maki; Hayashi, Hiroshi; Matsushima, Yoko; Nakajima, Takayuki; Tsuruoka, Yumi; Nagata, Marie; Koike, Hiroshi; Sekimura, Kotaro; Hashimoto, Tsuneo; Takano, Ichiro; Shindo, Tetsuya

    2017-07-01

    We developed a simultaneous determination method for 37 veterinary drugs in two chicken processed foods (deep-fried chicken and non-fried chicken cutlet) and muscle via liquid chromatography-mass spectrometry. The veterinary drugs belong to 7 different classes, including 4 antifolics, 4 benzimidazoles, 5 macrolides, 7 polyethers, 2 quinolones, 7 sulfonamides, and 8 other classes. The samples were extracted with ethyl acetate followed by acetonitrile with salt and buffers extraction. The two-step extraction enabled analyte extraction from highly lipid samples. The clean-up procedure, a solid-supported liquid extraction clean-up using a diatomaceous earth mini-cartridge, eliminated lipid co-extraction. The prepared sample matrix did not have an effect on the 36 analytes. The method was validated in accordance with the requirements of Japanese validation guidelines. Almost all targeted veterinary drugs successfully satisfied the guideline criteria in the three types of food matrices. The method exhibited recoveries of 70-105%, and the precision of repeatability and within-laboratory reproducibility ranged from 1 to 11% and 1 to 15%, respectively. The limits of quantification were estimated to range from 0.2 to 1.0μg/kg. Applying this method to samples commercially available in Tokyo, residues were detected in 3 out of 26 deep-fried chickens, 5 out of 20 non-fried chicken cutlets, and 17 out of 39 chicken muscles. Copyright © 2017 Elsevier B.V. All rights reserved.

  5. Comparison of solid phase extraction, saponification and gel permeation chromatography for the clean-up of microwave-assisted biological extracts in the analysis of polycyclic aromatic hydrocarbons.

    Science.gov (United States)

    Navarro, P; Cortazar, E; Bartolomé, L; Deusto, M; Raposo, J C; Zuloaga, O; Arana, G; Etxebarria, N

    2006-09-22

    The feasibility of different clean-up procedures was studied for the determination of polycyclic aromatic hydrocarbons (PAHs) in biota samples such as oysters, mussels and fish liver. In this sense, once the samples were extracted--essentially with acetone and in a microwave system--and before they could be analysed by gas chromatography-mass spectrometry (GC-MS), three different approaches were studied for the clean-up step: solid phase extraction (SPE), microwave-assisted saponification (MAS) and gel permeation chromatography (GPC). The main aim of this work was to maximise the recoveries of PAHs and to minimise the presence of interfering compounds in the last extract. In the case of SPE, Florisil cartridges of 1, 2 and 5 g, and silica cartridges of 5 g were studied. In that case, and with oysters and mussels, microwave-assisted extraction and 5 g Florisil cartridges provided good results. In addition, the concentrations obtained for Standard Reference Material (SRM) NIST 2977 (mussel tissue) were in good agreement with the certified values. In the case of microwave-assisted saponification, the extracts were not as clean as those obtained with 5 g Florisil and this fact lead to overestimate the concentration of the heaviest PAHs. Finally, the cleanest extracts were obtained by GPC. The method was successfully applied to mussels, oysters and hake liver, and the results obtained for NIST 2977 (mussel tissue) were within the confidence interval of the certified reference material for most of the certified analytes.

  6. Determination of Aflatoxin M1 in Milk Powder by Ultrasonic-Assisted Extraction and Dispersive Solid-Phase Clean-up.

    Science.gov (United States)

    Manoochehri, Mahboobeh; Asgharinezhad, Ali Akbar; Safaei, Mahdi

    2015-07-01

    This work describes the application of ultrasound-assisted dispersive solid-phase extraction (UA-DSPE) as a sample preparation approach for aflatoxin M1 (AFM1) and also its subsequent determination by HPLC-fluorescence detection. A Box-Behnken design in combination with response surface methodology was implemented to determine the variables affecting the extraction procedure. The effects of different variables, including type and quantity of clean-up phase, ultrasonication time, ultrasonication temperature, nature and volume of the leaching solvent, were investigated in the optimization study. Primary secondary amine (PSA) and acetonitrile were selected as the clean-up phase and the leaching solvent, respectively. The obtained optimized values were 30 mg of PSA, 10 min ultrasonication time, 32°C ultrasonication temperature and 10 mL of acetonitrile. Under the optimal conditions, the limit of detection and limit of quantification were 0.0012 and 0.0045 µg kg(-1), respectively. The recoveries of the UA-DSPE procedure ranged from 80 to 92%, with relative standard deviations lower than 10% in all cases. Eventually, this method was successfully applied to the extraction of AFM1 in milk powder samples. © The Author 2014. Published by Oxford University Press. All rights reserved. For Permissions, please email: journals.permissions@oup.com.

  7. Study of clean up procedures using Charcoal-Alumina-Celite column, immunoaffinity column and strata x column to determine deoxynivalenol by high performance liquid chromatography in wheat

    Directory of Open Access Journals (Sweden)

    Jacqueline Cea

    2011-04-01

    Full Text Available Fusarium graminearum is the most common toxic fungal species affecting grains in Uruguay. Since 1977, due to favorable climate conditions, there have been harvests with prominent Fusarium Head Blight in wheat. This were in 1984, 1990, 1993, 1996 and 2001.Natural Toxin Department of Technological Laboratory of Uruguay as National Reference Laboratory, is continuously improving the analytical methods in order to have a good response to the industry requirements and to the monitoring programs for import and exports commodities. The objective of this work was to compare different clean up methods in order to select the best one for routine determination of deoxynivalenol (DON in wheat (grain and flour.  Charcoal-alumina-celite (7+5+3,  immunoaffinity columns DONPREP R-Biopharm Rhone and Strata X 33 m polymeric sorbent  Phenomenex columns were used to perform the study. Considering as reference analytical method the internal protocol  PEC.TOX.063 accredited by United Kingdom Accreditation Service (UKAS  following the ISO 17025 requirements, and  based on AOAC method 986.17( chapter 49, 2002 for extraction and clean-up  and on J.AOAC 70(3, 1987:479-483 for the high performance liquid chromatography (HPLC detection, two more clean up methods were evaluated. In all of them PEC.TOX.063 detection procedure was carried out. PEC.TOX.063 used for the clean up an in house column chromatography prepared with charcoal-alumina-celite (7+5+3 . Extraction was performed using acetonitrile- water (84+16 and an aliquot of the extract was passed through the column. Extract was dryed under vacuum and DON detected by HPLC using photodiode array detector. For the method that used immunoaffinity columns, water was the extraction solvent, and manufacture protocol was followed up. An aliquot of the extract was passed through the column. Column was washed using water and DON eluated using methanol 100%. For the method that used Strata X column for the clean up, the

  8. INDUST.SUPERFUND_POLY_09

    Data.gov (United States)

    U.S. Environmental Protection Agency — This polygon layer represents a current (as of April 2009) list of CERCLIS' sites in EPA Region 7. Some of the sites are expanded to include plumes and others not.

  9. 77 FR 4559 - Ecusta Mill Site, Pisgah Forest, Transylvania County, NC; Notice of Amended Settlement

    Science.gov (United States)

    2012-01-30

    ... AGENCY Ecusta Mill Site, Pisgah Forest, Transylvania County, NC; Notice of Amended Settlement AGENCY... Ecusta Mill Superfund Site located in Pisgah Forest, Transylvania County, North Carolina. DATES: The... by Site name Ecusta Mill Superfund Site by one of the following methods:...

  10. Environmental Asbestos Assessment Manual Superfund Method for the Determination of Asbestos in Ambient Air Part 2: Technical Background Document

    Science.gov (United States)

    A sampling and analysis method for the determination of asbestos in air is presented in Part 1 of this report, under separate cover. This method is designed specifically to provide results suitable for supporting risk assessments at Superfund sites, although it is applicable t...

  11. Dispersive solid-phase extraction as a simplified clean-up technique for biological sample extracts. Determination of polybrominated diphenyl ethers by gas chromatography-tandem mass spectrometry.

    Science.gov (United States)

    Fontana, Ariel R; Camargo, Alejandra; Martinez, Luis D; Altamirano, Jorgelina C

    2011-05-06

    Dispersive solid-phase extraction (DSPE) is proposed for the first time as a simplified, fast and low cost clean-up technique of biological sample extracts for polybrominated diphenyl ethers (PBDEs) determination. The combination of a traditional extraction technique, such as ultrasound-assisted leaching (USAL) with DSPE was successfully applied for sample preparation prior to gas chromatography-tandem mass spectrometry (GC-MS/MS) analysis. The analytes were first extracted from 1g homogenized sample in n-hexane:dichloromethane (8:2) by applying USAL technique and further cleaned-up using DSPE with 0.20 g C(18)-silica as sorbent material. Different solvent mixtures, sorbent type and amount, and lipid digestion procedures were evaluated in terms of clean-up and extraction efficiency. Under optimum conditions, the method detection limits (MDLs) for PBDEs, calculated as three times the signal-to-noise ratio (S/N) were within the range 9-44 pg g(-1) wet weight. The calibration graphs were linear within the concentration range of 53-500,000 pg g(-1), 66-500,000 pg g(-1), 89-500,000 pg g(-1) and 151-500,000 pg g(-1) for BDE-47, BDE-100, BDE-99 and BDE-153, respectively; and the coefficient of determination (r(2)) exceeded 0.9992 for all analytes. The proposed methodology was compared with a reference solid-phase extraction technique. The applicability of the methodology for the screening of PBDEs has been demonstrated by analyzing spiked and real samples of biological nature (fish, egg and chicken) with different lipid content as well as reference material (WELL-WMF-01). Recovery values ranged between 75% and 114% and the measured concentrations in certified material showed a reasonable agreement with the certified ones. BDE-47, BDE-100 and BDE-99 were quantified in three of the seven analyzed samples and the concentrations ranged between 91 and 140 pg g(-1). In addition, this work is the first description of PBDEs detected in fish of Argentinean environment.

  12. Soil clean up by vapour extraction: parametrical study; Depollution des sols par extraction sous pression reduite: etude de quelques parametres

    Energy Technology Data Exchange (ETDEWEB)

    Dutheil, C.

    2003-05-15

    Soil vapour extraction is a treatment process for soils polluted by volatile organic compounds. Its principle relies on the circulation of gaseous flow in soil by the application of a depression of some hundreds milli-bars. A parametrical study has been led on a soil artificially polluted by tri-chloro-ethene. It shows that the gaseous flow rate has a slight influence on pollutants extraction yield. This is due to rate limited mass transfer processes. Soil moisture plays a negative role on treatment efficiency because of the reduction of the porosity available for the gas circulation. Tests have been performed on a soil polluted by a complex mixture of organic pollutants to elaborate a methodology of technical feasibility assessment. This methodology aims at identifying and limiting risks of site rehabilitation failure. Tests results show that soil vapour extraction was inadequate to treat the soil tested in this study because of the strong affinity between a dense organic phase (grease) and chlorinated solvents. (author)

  13. An exercise on clean-up actions in an urban environment after a nuclear accident. Report of the NKS EKO 4 programme

    Energy Technology Data Exchange (ETDEWEB)

    French, S. [ed.] [Leeds Univ. (United Kingdom). School of Computer Studies; Finck, R. [ed.] [Swedish Radiation Protection Inst., Stockholm (Sweden); Haemaelaeinen, R. [ed.] [Helsinki Univ. of Technology, Espoo (Finland); Naadland, E. [ed.] [Norwegian Radiation Protection Authority, Oesteraas (Norway); Roed, J. [ed.] [Risoe National Lab., Roskilde (Denmark); Salo, A. [ed.] [Helsinki (Finland); Sinkko, K. [ed.] [Finnish Centre for Radiation and Nuclear Safety, Helsinki (Finland)

    1996-03-01

    The EKO 4/c working group of the environmental effects and emergency preparedness programme (EKO) of the Nordic Nuclear Safety Research (NKS) organised a decision conference on August 30th and 31st, 1995 in Stockholm, Sweden. The meeting was designed to be attended by those responsible for planning and deciding on protective actions in the Nordic countries after a nuclear accident. Issues concerning clean-up strategies in an urban environment after a hypothetical and very severe reactor accident were discussed at the meeting. The objectives of the meeting were to provide a shared understanding between the decision makers and the radiation protection community on concerns and issues related to decision on protective actions after a nuclear accident. (6 refs., 2 figs., 3 tabs.).

  14. Determination of BPA, BPB, BPF, BADGE and BFDGE in canned energy drinks by molecularly imprinted polymer cleaning up and UPLC with fluorescence detection.

    Science.gov (United States)

    Gallo, Pasquale; Di Marco Pisciottano, Ilaria; Esposito, Francesco; Fasano, Evelina; Scognamiglio, Gelsomina; Mita, Gustavo Damiano; Cirillo, Teresa

    2017-04-01

    A new method for simultaneous determination of five bisphenols in canned energy drinks by UPLC with fluorescence detection, after clean up on molecularly imprinted polymers, is herein described. The method was validated at two concentration levels, calculating trueness, repeatability and within-laboratory reproducibility, specificity, linearity of detector response, the limits of quantifications and the limits of detection for each bisphenol. The method is specific, reliable and very sensitive, allowing for determination of bisphenol F diglycidyl ether (BFDGE), bisphenol A (BPA), bisphenol B (BPB), bisphenol F (BPF) and bisphenol A diglycidyl ether (BADGE) down to 0.50ng/mL; it was employed to determine contamination levels from these bisphenols in forty energy drinks of different brands, collected from the market in Naples. BPA was detected in 17 out of 40 samples (42.5%); in some energy drinks also BPF, BADGE and BFDGE were determined.

  15. On-line clean-up and screening of oxacillin and cloxacillin in human urine and plasma with a weak ion exchange monolithic column.

    Science.gov (United States)

    Yang, Gengliang; Feng, Sha; Liu, Haiyan; Yin, Junfa; Zhang, Li; Cai, Liping

    2007-07-01

    A weak ion exchange monolithic column prepared by modifying the GMA-MAA-EDMA (glycidyl methacrylate-methacrylic acid-ethylene glycol dimethacrylate) monoliths with ethylenediamine was applied to remove matrix compounds in biological fluid. Using this monolithic column, on-line clean-up and screening of oxacillin and cloxacillin in human urine and plasma samples had been investigated. Chromatography was performed by reversed-phase HPLC on a C(18) column with ultraviolet detection at 225 nm. Results showed that the ion exchange monolithic column could be used for deproteinization and retaining oxacillin and cloxacillin in human urine and plasma, which provided a simple and fast method for assaying drugs in human urine and plasma.

  16. Microwave-assisted extraction at atmospheric pressure coupled to different clean-up methods for the determination of organophosphorus pesticides in olive and avocado oil.

    Science.gov (United States)

    Fuentes, Edwar; Báez, María E; Díaz, Juan

    2009-12-18

    An effective extraction method was devised for the determination of organophosphorus pesticides (OPPs) in olive and avocado oil samples, using atmospheric pressure microwave-assisted liquid-liquid extraction (APMAE) and solid-phase extraction or low-temperature precipitation as clean-up step. A simple glass system equipped with an air-cooled condenser was designed as an extraction vessel. The pesticides were partitioned between acetonitrile and oil solution in hexane. Analytical determinations were carried out by gas chromatography-flame photometric detection and gas chromatography-tandem mass spectrometry, using a triple quadrupole mass analyzer, for confirmation purposes. Several factors influencing the extraction efficiency were investigated and optimized through fractional factorial design and Doehlert design. Under optimal conditions the recovery of pesticides from oil at 0.025 microg g(-1) ranged from 71% to 103%, except for fenthion in avocado oil, with RSDs avocado oils produced in Chile. Detectable residues of different OPPs were observed in 85% of samples.

  17. Simultaneous determination of four aflatoxins and ochratoxin A in ginger and related products by HPLC with fluorescence detection after immunoaffinity column clean-up and postcolumn photochemical derivatization.

    Science.gov (United States)

    Wen, Jing; Kong, Weijun; Wang, Jian; Yang, Meihua

    2013-12-01

    Ginger, a widely used spice and traditional Chinese medicine, is prone to be contaminated by mycotoxins. A simple, sensitive, and reproducible method based on immunoaffinity column clean-up coupled with HPLC and on-line postcolumn photochemical derivatization with fluorescence detection was developed for the simultaneous determination of aflatoxins (AFs) B1 , B2 , G1 , G2 , and ochratoxin A (OTA) in 25 batches of gingers and related products marketed in China for the first time. The samples were first extracted by ultrasonication with methanol/water (80:20, v/v) and then cleaned up with immunoaffinity columns for analysis. Under the optimized conditions, the LODs and LOQs for the five mycotoxins were 0.03-0.3 and 0.1-0.9 μg/kg, respectively. The average recoveries ranged from 81.3-100.8% for AFs and from 88.6-99.5% for OTA at three spiking levels. Good linearity was observed for the analytes with correlation coefficients all >0.9995. All moldy gingers were contaminated with at least one kind of the five investigated mycotoxins, while none of them were found in normal gingers. Ginger powder samples were contaminated slightly with the contamination levels below the LOQs, while ginger tea bags were mainly contaminated by OTA at 1.05-1.19 μg/kg and ginger black tea bags were mainly contaminated by AFs at 3.37-5.76 μg/kg. All the contamination levels were below the legally allowable limits.

  18. Determination of endocrine disrupting compounds in fish liver, brain, and muscle using focused ultrasound solid-liquid extraction and dispersive solid phase extraction as clean-up strategy.

    Science.gov (United States)

    Ros, Oihana; Vallejo, Asier; Olivares, Maitane; Etxebarria, Nestor; Prieto, Ailette

    2016-08-01

    This study describes a new method for the simultaneous extraction of several endocrine disrupting compounds, including alkylphenols (APs), estrogen, bisphenol-A (BPA) and one phthalate metabolite (mono-2-ethylhexyl ester, MEHP) in fish liver, brain, and muscle. Parameters affecting the extraction (extraction solvent and temperature) and the clean-up (dispersive phase nature and amount) steps were evaluated. The extraction was performed by means of focused ultrasound solid-liquid extraction (FUSLE) using 10 mL of n-hexane:acetone (50:50, v/v) for 5 min at ~0 °C, and the clean-up was done by means of dispersive solid phase extraction (dSPE) using 100 mg of ENVI-CARB and 100 mg of MgSO4 for the cleaning of brain and muscle extracts together with 100 mg of PSA in the case of liver extracts. Good apparent recoveries were obtained in the case of liver (62-132 %), brain (66-120 %), and muscle (74-129 %), relative standard deviation (RSD%) was always below 26 %, and the method detection limits (MDLs) were at low ng/g level. The developed method was applied to fish captured in Urdaibai estuary (Bay of Biscay) in December 2015, and the concentrations obtained were in the range MDL-1115 ng/g in brain, MDL-962 ng/g in muscle, and MDL-672 ng/g in liver. In general, the highest concentrations were measured in liver, followed by brain and muscle. In addition, diethylstilbestrol was only detected in fish brain. Graphical Abstract MS method scheme for the/MS method scheme for the determination of EDCs in fish liver, brain and muscle.

  19. Simultaneous analysis of organochlorinated pesticides (OCPs) and polychlorinated biphenyls (PCBs) from marine samples using automated pressurized liquid extraction (PLE) and Power Prep™ clean-up.

    Science.gov (United States)

    Helaleh, Murad I H; Al-Rashdan, Amal; Ibtisam, A

    2012-05-30

    An automated pressurized liquid extraction (PLE) method followed by Power Prep™ clean-up was developed for organochlorinated pesticide (OCP) and polychlorinated biphenyl (PCB) analysis in environmental marine samples of fish, squid, bivalves, shells, octopus and shrimp. OCPs and PCBs were simultaneously determined in a single chromatographic run using gas chromatography-mass spectrometry-negative chemical ionization (GC-MS-NCI). About 5 g of each biological marine sample was mixed with anhydrous sodium sulphate and placed in the extraction cell of the PLE system. PLE is controlled by means of a PC using DMS 6000 software. Purification of the extract was accomplished using automated Power Prep™ clean-up with a pre-packed disposable silica column (6 g) supplied by Fluid Management Systems (FMS). All OCPs and PCBs were eluted from the silica column using two types of solvent: 80 mL of hexane and a 50 mL mixture of hexane and dichloromethane (1:1). A wide variety of fish and shellfish were collected from the fish market and analyzed using this method. The total PCB concentrations were 2.53, 0.25, 0.24, 0.24, 0.17 and 1.38 ng g(-1) (w/w) for fish, squid, bivalves, shells, octopus and shrimp, respectively, and the corresponding total OCP concentrations were 30.47, 2.86, 0.92, 10.72, 5.13 and 18.39 ng g(-1) (w/w). Lipids were removed using an SX-3 Bio-Beads gel permeation chromatography (GPC) column. Analytical criteria such as recovery, reproducibility and repeatability were evaluated through a range of biological matrices. Copyright © 2012 Elsevier B.V. All rights reserved.

  20. Superfund Training/Tech Transfer

    Data.gov (United States)

    U.S. Environmental Protection Agency — This asset includes a collection of information resources, training, and other media related to hazardous waste site cleanup and characterization. A major part of...

  1. The StreamCat Dataset: Accumulated Attributes for NHDPlusV2 Catchments (Version 2.1) for the Conterminous United States: Facility Registry Services (FRS) : Toxic Release Inventory (TRI) , National Pollutant Discharge Elimination System (NPDES) , and Superfund Sites

    Data.gov (United States)

    U.S. Environmental Protection Agency — This dataset represents the estimated density of georeferenced sites within individual, local NHDPlusV2 catchments and upstream, contributing watersheds based on the...

  2. Development of a simple extraction and clean-up procedure for determination of organochlorine pesticides in soil using gas chromatography-tandem mass spectrometry.

    Science.gov (United States)

    Rashid, A; Nawaz, S; Barker, H; Ahmad, I; Ashraf, M

    2010-04-23

    A procedure based on QuEChERS extraction and a simultaneous liquid-liquid partition clean-up was developed. The procedure involved extraction of hydrated soil samples using acetonitrile and clean-up by liquid-liquid partition into n-hexane. The hexane extracts produced were clean and suitable for determination using gas chromatography-tandem mass spectrometry (GC-MS/MS). The method was validated by analysis of soil samples, spiked at five levels between 1 and 200 microg kg(-1). The recovery values were generally between 70 and 100% and the relative standard deviation values (%RSDs) were at or below 20%. The procedure was validated for determination of 19 organochlorine (OC) pesticides. These were hexachlorobenzene (HCB), alpha-HCH, beta-HCH, gamma-HCH, heptachlor, heptachlor epoxide (trans), aldrin, dieldrin, chlordane (trans), chlordane (cis), oxychlordane, alpha-endosulfan, beta-endosulfan, endosulfan sulfate, endrin, p,p'-DDT, o,p'-DDT, p,p'-DDD and p,p'-DDE. The method achieved low limits of detection (LOD; typically 0.3 microg kg(-1)) and low limits of quantification (LOQ; typically 1.0 microg kg(-1)). The method performance was also assessed using five fortified soil samples with different physico-chemical properties and the method performance was consistent for the different types of soil samples. The proposed method was compared with an established procedure based on Soxtec extraction. This comparison was carried out using six soil samples collected from regions of Pakistan with a history of intensive pesticide use. The results of this comparison showed that the two procedures produced results with good agreement. The proposed method produced cleaner extracts and therefore led to lower limits of quantification. The proposed method was less time consuming and safer to use. The six samples tested during this comparison showed that soils from cotton growing regions contained a number of persistent OC residues at relatively low levels (<10 microg kg(-1)). These

  3. EPA Region 2 SEMS_CERCLIS Sites All [R2] and SEMS_CERCLIS Sites NPL [R2] GIS Layers

    Data.gov (United States)

    U.S. Environmental Protection Agency — The Region 2 SEMS_CERCLIS Sites All [R2] GIS layer contains unique Superfund Enterprise Management System (SEMS) site records. These records have the following...

  4. Trivalent copper chelate-luminol chemiluminescence system for highly sensitive CE detection of dopamine in biological sample after clean-up using SPE.

    Science.gov (United States)

    Wang, Lin; Liu, Ying; Xie, Haoyue; Fu, Zhifeng

    2012-06-01

    A transition metal chelate unstable at a high oxidation state, diperiodatocuprate (III) (K₅[Cu(HIO₆)₂], DPC), was synthesized and applied in the luminol-based chemiluminescence (CL) system for highly sensitive CE end-column detection of dopamine (DA). This method was based on the fact that DA enhanced the CL emission resulting from the reaction between luminol and DPC in alkaline medium. The DPC-luminol-DA CL system showed very intensive emission and very fast kinetic characteristics, thus resulting in a high sensitivity in flow-through detection mode for CE. Under optimal conditions, the linear range was 1.0 × 10⁻⁸-5.0 × 10⁻⁵ g/mL (R² = 0.9984) with a limit of detection of 6.0 × 10⁻⁹ g/mL (S/N = 3). The RSDs of the peak height and the migration time were about 4.2 and 2.4% for a standard sample at 3.0 × 10⁻⁶ g/mL (n = 5), respectively. The presented method has been successfully used for the determination of DA in commercial preparation and human urine samples after clean-up using SPE.

  5. Results of the clean-up operation to reduce pollution on flooded agricultural fields after the red mud spill in Hungary.

    Science.gov (United States)

    Uzinger, Nikolett; Anton, Áron Dániel; Ötvös, Károly; Tamás, Péter; Anton, Attila

    2015-07-01

    In Hungary, the dam of a red mud reservoir breached shortly after noon on October 4, 2010. Approximately 0.7-1 million m(3) highly alkaline red mud with very low dry matter content flowed into the Torna Creek and the surrounding area, covering 1017 ha of agricultural land. Results of the risk assessment of the accident indicated that the red mud should be removed from the surface of fields where it formed a continuous layer of more than 5 cm. After the removal, samples were taken manually from depths of 0.0-0.2 m and 0.2-0.4 m in a sampling grid and background samples unaffected by red mud from the depth of 0.0-0.3 m. Total element contents (Ag, As, Ba, Cd, Co, Cr, Cu, Hg, Mo, Ni, Pb, Sn, Zn, and Na) and pH values were measured, and the results were analysed using correlation analysis and the Kruskal-Wallis probe. Dependence of the measured variables from elevation above sea level was studied using a 10 m by 10 m digital elevation model. Only ∼6.5% of the flooded area was temporarily designated as unsuitable for the production of food and fodder crops. In summary, the clean-up operation can be said to have been a success.

  6. Development of a bi-functional silica monolith for electro-osmotic pumping and DNA clean-up/extraction using gel-supported reagents in a microfluidic device.

    Science.gov (United States)

    Oakley, Jennifer A; Shaw, Kirsty J; Docker, Peter T; Dyer, Charlotte E; Greenman, John; Greenway, Gillian M; Haswell, Stephen J

    2009-06-07

    A silica monolith used to support both electro-osmotic pumping (EOP) and the extraction/elution of DNA coupled with gel-supported reagents is described. The benefits of the combined EOP extraction/elution system were illustrated by combining DNA extraction and gene amplification using the polymerase chain reaction (PCR) process. All the reagents necessary for both processes were supported within pre-loaded gels that allow the reagents to be stored at 4 degrees C for up to four weeks in the microfluidic device. When carrying out an analysis the crude sample only needed to be hydrodynamically introduced into the device which was connected to an external computer controlled power supply via platinum wire electrodes. DNA was extracted with 65% efficiency after loading lysed cells onto a silica monolith. Ethanol contained within an agarose gel matrix was then used to wash unwanted debris away from the sample by EOP (100 V cm(-1) for 5 min). The retained DNA was subsequently eluted from the monolith by water contained in a second agarose gel, again by EOP using an electric field of 100 V cm(-1) for 5 min, and transferred into the PCR reagent containing gel. The eluted DNA in solution was successfully amplified by PCR, confirming that the concept of a complete self-contained microfluidic device could be realised for DNA sample clean up and amplification, using a simple pumping and on-chip reagent storage methodology.

  7. Analysis of endocrine disruptor compounds in marine sediments by in cell clean up-pressurized liquid extraction-liquid chromatography tandem mass spectrometry determination.

    Science.gov (United States)

    Salgueiro-González, N; Turnes-Carou, I; Muniategui-Lorenzo, S; López-Mahía, P; Prada-Rodríguez, D

    2014-12-10

    A less time-, solvent- and sorbent-consuming analytical methodology for the determination of bisphenol A and alkylphenols (4-tert-octylphenol, 4-octylphenol, 4-n-nonylphenol, nonylphenol) in marine sediment was developed and validated. The method was based on selective pressurized liquid extraction (SPLE) with a simultaneous in cell clean up combined with liquid chromatography-electrospray ionization tandem mass spectrometry in negative mode (LC-ESI-MS/MS). The SPLE extraction conditions were optimized by a Plackett-Burman design followed by a central composite design. Quantitation was performed by standard addition curves in order to correct matrix effects. The analytical features of the method were satisfactory: relative recoveries varied between 94 and 100% and repeatability and intermediate precision were <6% for all compounds. Uncertainty assessment of measurement was estimated on the basis of an in-house validation according to EURACHEM/CITAC guide. Quantitation limits of the method (MQL) ranged between 0.17 (4-n-nonylphenol) and 4.01 ng g(-1) dry weight (nonylphenol). Sensitivity, selectivity, automaticity and fastness are the main advantages of this green methodology. As an application, marine sediment samples from Galicia coast (NW of Spain) were analysed. Nonylphenol and 4-tert-octylphenol were measured in all samples at concentrations between 20.1 and 1409 ng g(-1) dry weight, respectively. Sediment toxicity was estimated and no risk to aquatic biota was found.

  8. In-house validation of an improved sample extraction and clean-up method for GC determination of isomers of nervonic acid in meat products.

    Science.gov (United States)

    Agazzi, Marie-Elisabeth; Bau, Andrea; Barcarolo, Robertino; Luecker, Ernst; Barrero-Moreno, Josefa; Anklam, Elke

    2003-06-01

    An improved extraction and clean-up method for determination of brain-specific fatty acids, in particular lignoceric acid (C24:0) and the cis/ trans isomers of nervonic acid (15 c-t C24:1), in meat products has been developed. The method is based on isolation of the polar lipids of interest from the bulk lipids by solid-phase extraction. The fatty acids, derivatised to their fatty acid methyl esters, are quantified by GC in a DB5 column. Fresh meat samples were extracted by using a mixture of n-butanol:hexane (1:9) as solvent. The extract was loaded in a silica gel cartridge column previously equilibrated with hexane. The first fraction containing the major part of the fat was eluted with hexane while acetone and methanol allowed the elution of fatty acids bound to polar moieties such as nervonic and lignoceric acids. This second fraction containing the analyte was methylated and injected into the GC for quantification after addition octacosane (C(28)) as internal standard.

  9. In-cell clean-up pressurized liquid extraction and gas chromatography-tandem mass spectrometry determination of hydrophobic persistent and emerging organic pollutants in coastal sediments.

    Science.gov (United States)

    Pintado-Herrera, Marina G; González-Mazo, Eduardo; Lara-Martín, Pablo A

    2016-01-15

    The main goal of this work was to develop, optimize and validate a multi-residue method for the simultaneous determination of 97 contaminants, including fragrances, UV filters, repellents, endocrine disruptors, biocides, polycyclic aromatic hydrocarbons (PAHs), polychlorinated biphenyls (PCBs), organophosphorus flame retardants, and several types of pesticides in marine sediment samples. Extraction and cleanup were integrated into the same step using pressurized liquid extraction (PLE) with in-cell clean-up (1g of alumina). The extraction was performed using dichloromethane at 100 °C, 1500 psi and 3 extraction cycles (5 min per cycle). Extracts were derivatized with N-(tert-butyldimethylsilyl)-N-methyltrifluoroacetamide (MTBSTFA) to improve the signal and sensitivity of some target compounds (i.e., triclosan, 2-hydroxybenzophenone). Separation, identification and quantification of analytes were carried out by gas chromatography (GC) coupled to tandem mass spectrometry. Under optimal conditions, the optimized protocol showed good recovery percentages (70-100%), linearity (>0.99) and limits of detection below 1 ng g(-1) for all compounds. Finally, the method was applied to the analysis of sediment samples from different coastal areas from Andalusia (Spain), where occurrence and distribution of emerging contaminants in sediments is very scarce. Twenty five compounds out of 98 were detected in all samples, with the endocrine disruptor nonylphenol and the fragrance galaxolide showing the highest concentrations, up to 377.6 ng g(-1) and 237.4 ng g(-1), respectively.

  10. Screening of pollution control and clean-up materials for river chemical spills using the multiple case-based reasoning method with a difference-driven revision strategy.

    Science.gov (United States)

    Liu, Rentao; Jiang, Jiping; Guo, Liang; Shi, Bin; Liu, Jie; Du, Zhaolin; Wang, Peng

    2016-06-01

    In-depth filtering of emergency disposal technology (EDT) and materials has been required in the process of environmental pollution emergency disposal. However, an urgent problem that must be solved is how to quickly and accurately select the most appropriate materials for treating a pollution event from the existing spill control and clean-up materials (SCCM). To meet this need, the following objectives were addressed in this study. First, the material base and a case base for environment pollution emergency disposal were established to build a foundation and provide material for SCCM screening. Second, the multiple case-based reasoning model method with a difference-driven revision strategy (DDRS-MCBR) was applied to improve the original dual case-based reasoning model method system, and screening and decision-making was performed for SCCM using this model. Third, an actual environmental pollution accident from 2012 was used as a case study to verify the material base, case base, and screening model. The results demonstrated that the DDRS-MCBR method was fast, efficient, and practical. The DDRS-MCBR method changes the passive situation in which the choice of SCCM screening depends only on the subjective experience of the decision maker and offers a new approach to screening SCCM.

  11. EPA Removes Burrows Sanitation Site in Michigan from National List of Most Contaminated Sites

    Science.gov (United States)

    For Immediate Release No. 15-OPA142 CHICAGO - The U.S. Environmental Protection Agency today announced that the Burrows Sanitation Superfund site in Hartford Township, Van Buren County, Michigan, has been officially removed from the Agency's l

  12. Implementation of an ex situ stabilization technique at the Sand Springs superfund site to solidify and stabilize acid tar sludges involving a quick-lime based stabilization process and innovative equipment design

    Energy Technology Data Exchange (ETDEWEB)

    McManus, R.W. [SOUND Environmental Services, Inc., Dallas, TX (United States); Grajczak, P. [ARCO, Los Angeles, CA (United States); Wilcoxson, J.C. [ARCO, Plano, TX (United States); Webster, S.D. [Environmental Protection Agency, Dallas, TX (United States)

    1997-12-31

    An old refinery site was safely remediated a year before schedule and for 25% less than final engineering estimates for the stabilization remedy thanks to energetic project management and innovative design involving ex situ stabilization/solidification of acid tar sludges. A quicklime based process, Dispersion by Chemical Reaction (DCR{trademark}), was employed to solidify and stabilize (SS) over 103,000 cubic meters (135,000 cubic yards) of petroleum waste, mostly acidic tarry sludge. The SS process was selected over competing methods because it afforded minimal volume increase, could readily achieve Record of Decision (ROD) specified physical and chemical treatment goals, could be implemented with treatment equipment that minimized emissions, and could be performed with low reagent usage and at low cost. To ensure treatment goals were achieved and an accelerated schedule met, a custom designed and fabricated transportable treatment unit (TTU) was employed to implement the process. The treated material was visually soil-like in character, it was left in stockpiles for periods of time, and it was placed and compacted in the on site landfill using standard earth-moving equipment.

  13. Feasibility Study of Economics and Performance of Solar Photovoltaics at the Standard Chlorine of Delaware Superfund Site in Delaware City, Delaware. A Study Prepared in Partnership with the Environmental Protection Agency for the RE-Powering America's Land Initiative: Siting Renewable Energy on Potentially Contaminated Land and Mine Sites

    Energy Technology Data Exchange (ETDEWEB)

    Salasovich, J.; Geiger, J.; Mosey, G.; Healey, V.

    2013-06-01

    The U.S. Environmental Protection Agency (EPA), in accordance with the RE-Powering America's Land initiative, selected the Standard Chlorine of Delaware site in Delaware City, Delaware, for a feasibility study of renewable energy production. The National Renewable Energy Laboratory (NREL) provided technical assistance for this project. The purpose of this report is to assess the site for a possible photovoltaic (PV) system installation and estimate the cost, performance, and site impacts of different PV options. In addition, the report recommends financing options that could assist in the implementation of a PV system at the site.

  14. Hydrogeologic framework, hydrology, and refined conceptual model of groundwater flow for Coastal Plain aquifers at the Standard Chlorine of Delaware, Inc. Superfund Site, New Castle County, Delaware, 2005-12

    Science.gov (United States)

    Brayton, Michael J.; Cruz, Roberto M.; Myers, Luke; Degnan, James R.; Raffensperger, Jeff P.

    2015-01-01

    From 1966 to 2002, activities at the Standard Chlorine of Delaware chemical facility in New Castle County, Delaware resulted in the contamination of groundwater, soils, and wetland sediment. In 2005, the U.S. Geological Survey (USGS), in partnership with the U.S. Environmental Protection Agency, Region 3, and the Delaware Department of Natural Resources and Environmental Control began a multi-year investigation of the hydrogeologic framework and hydrology of the confined aquifer system. The goals of the ongoing study at the site (the Potomac Aquifer Study) are to determine the hydraulic connection between the Columbia and Potomac aquifers, determine the direction of groundwater flow in the Potomac aquifer, and identify factors affecting the fate of contaminated groundwater. This report describes progress made towards these goals based on available data collected through September 2012.

  15. Superfund record of decision (EPA Region 4): Helena Chemical Company, (Tampa Plant), Hillsborough County, Tampa, FL, May 7, 1996

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    1996-06-01

    The decision document (Record of Decision), presents the selected remedial action for the Helena Chemical Company Superfund Site, Tampa, Hillsborough County, Florida. This action addresses soil, sediment, and ground water contamination at the site and calls for the implementation of response measures which will protect human health and the environment. The selected remedy includes biological treatment (i.e., bioremediation) of pesticides and other site related contaminants located in surface soil sand sediments to levels appropriate for future industrial use of the Site. In addition, the selected remedy includes ground water recovery and treatment to remove pesticides and other site related contaminants.

  16. Determination of ten steroid hormones in animal waste manure and agricultural soil using inverse and integrated clean-up pressurized liquid extraction and gas chromatography-tandem mass spectrometry

    DEFF Research Database (Denmark)

    Hansen, Martin; Krogh, Kristine A; Halling-Sørensen, Bent

    2011-01-01

    ... Martin Hansen , Kristine A. Krogh , Bent Halling ... in a 22 mL PLE cell : firstly by flushing the sample with heptane to remove unwanted matrix components (inverse- PLE , i- PLE ) and secondly, performing internal clean-up (ic- PLE ) and eluting the steroid hormones by attaching an ...

  17. Development of sample extraction and clean-up strategies for target and non-target analysis of environmental contaminants in biological matrices.

    Science.gov (United States)

    Baduel, Christine; Mueller, Jochen F; Tsai, Henghang; Gomez Ramos, Maria Jose

    2015-12-24

    Recently, there has been an increasing trend towards multi-targeted analysis and non-target screening methods as a means to increase the number of monitored analytes. Previous studies have developed biomonitoring methods which specifically focus on only a small number of analytes with similar physico-chemical properties. In this paper, we present a simple and rapid multi-residue method for simultaneous extraction of polar and non-polar organic chemicals from biological matrices, containing up to 5% lipid content. Our method combines targeted multi-residue analysis using gas chromatography triple quadrupole mass spectrometry (GC-QqQ-MS/MS) and a multi-targeted analysis complemented with non-target screening using liquid chromatography coupled to a quadrupole time of flight mass spectrometry (LC-QTOF-MS/MS). The optimization of the chemical extraction procedure and the effectiveness of different clean-up methods were evaluated for two biological matrices: fish muscle (lipid content ∼2%) and breast milk (∼4%). To extract a wide range of chemicals, the partition/extraction procedure used for the QuEChERS (Quick, Easy, Cheap, Effective, Rugged and Safe) approach was tested as the initial step for the extraction of 77 target compounds covering a broad compound domain. All the target analytes have different physico-chemical properties (log Kow ranges from -0.3 to 10) and cover a broad activity spectrum; from polar pesticides, pharmaceuticals, personal care products (PPCPs) to highly lipophilic chemicals such as polybrominated diphenyl ethers (PBDEs), polychlorinated biphenyls (PCBs), polycyclic aromatic hydrocarbons (PAHs) and organochloride pesticides (OCPs). A number of options were explored for the clean-up of lipids, proteins and other impurities present in the matrix. Zirconium dioxide-based sorbents as dispersive solid-phase extraction (d-SPE) and protein-lipid removal filter cartridges (Captiva ND Lipids) provided the best results for GC-MS and LC-MS analysis

  18. Simultaneous pressurized enzymatic hydrolysis extraction and clean up for arsenic speciation in seafood samples before high performance liquid chromatography-inductively coupled plasma-mass spectrometry determination.

    Science.gov (United States)

    Moreda-Piñeiro, Jorge; Alonso-Rodríguez, Elia; Moreda-Piñeiro, Antonio; Moscoso-Pérez, Carmen; Muniategui-Lorenzo, Soledad; López-Mahía, Purificación; Prada-Rodríguez, Darío; Bermejo-Barrera, Pilar

    2010-10-29

    The feasibility of pressurized conditions to assist enzymatic hydrolysis of seafood tissues for arsenic speciation was novelty studied. A simultaneous in situ (in cell) clean-up procedure was also optimized, which speeds up the whole sample treatment. Arsenic species (As(III), MMA, DMA, As(V), AsB and AsC) were released from dried seafood tissues using pepsin as a protease, and the arsenic species were separated/quantified by anion exchange high performance liquid chromatography (HPLC) coupled to inductively coupled plasma-mass spectrometry (ICP-MS). Variables inherent to the enzymatic activity (pH, temperature and ionic strength), the amount of enzyme (pepsin), and factors affecting pressurization (pressure, static time, number of cycles and amount of dispersing agent, C-18) were fully evaluated. Pressurized assisted enzymatic hydrolysis (PAEH) with pepsin can be finished after few minutes (two cycles of 2 min each one plus 3 min to reach the hydrolysis temperature of 50 °C). A total sample solubilisation is not achieved after the procedure, however it is efficient enough for breaking down certain bonds of bio-molecules and for releasing arsenic species. The developed method has been found to be precise (RSDs lower than 6% for As(III), DMA and As(V); and 3% for AsB) and sensitive (LOQs of 18.1, 36.2, 35.7, 28.6, 20.6 and 22.5 ng/g for As(III), MMA, DMA, As(V), AsB and AsC, respectively). The optimized methodology was successfully applied to different certified reference materials (DORM-2 and BCR 627) which offer certified AsB and DMA contents, and also to different seafood products (mollusks, white fishes and cold water fishes).

  19. Development of molecularly imprinted poly(methacrylic acid)/silica for clean-up and selective extraction of cholesterol in milk prior to analysis by HPLC-UV.

    Science.gov (United States)

    Clausen, D N; Visentainer, J V; Tarley, C R T

    2014-10-07

    In the present paper the assessment of a novel molecularly imprinted polymer, poly(methacrylic acid)/silica, for clean-up and selective extraction of cholesterol in milk samples is described. The relative selectivity coefficient (k) values for cholesterol/5-α-cholestane and cholesterol/7-dehydrocholesterol systems were found to be 5.08 and 6.08, respectively, thus attesting the selectivity of the MIP for cholesterol under competitive adsorption with structurally analogous steroid compounds. The milk analysis was initially based on saponification followed by liquid-liquid extraction with n-hexane. Then, the protocol of molecularly imprinted solid phase extraction (MISPE) was carried out by loading the milk hexanic extract through 200 mg of MIP or NIP (non-imprinted polymer) packed into SPE cartridges at a flow rate of 0.6 mL min(-1). The washing step was performed by using n-hexane followed by further elution with ethanol and HPLC-UV analysis at 208 nm. From the breakthrough curve the maximum adsorption capacity of the MIP towards cholesterol was found to be 29.51 mg g(-1). The precision of the MISPE protocol was assessed as intra- and inter-days yielding RSD (relative standard deviations) lower than 4.10%. Cleaner HPLC chromatograms were obtained for milk samples submitted to the MISPE protocol in comparison to the solid phase extraction using the NIP or modified octadecyl silica (C18). Recoveries varying from 96.6 up to 102.2% for milk samples spiked with cholesterol were achieved, thus ensuring the accuracy of the proposed method.

  20. Site Environmental Report for 2015

    Energy Technology Data Exchange (ETDEWEB)

    Pauer, Ron O. [Lawrence Berkeley National Lab. (LBNL), Berkeley, CA (United States); Baskin, David A. [Lawrence Berkeley National Lab. (LBNL), Berkeley, CA (United States); Borglin, Ned K. [Lawrence Berkeley National Lab. (LBNL), Berkeley, CA (United States); Fox, Robert A. [Lawrence Berkeley National Lab. (LBNL), Berkeley, CA (United States); Harvey, Zachary R. [Lawrence Berkeley National Lab. (LBNL), Berkeley, CA (United States); Jelinski, John A. [Lawrence Berkeley National Lab. (LBNL), Berkeley, CA (United States); Kassis, Maram M. [Lawrence Berkeley National Lab. (LBNL), Berkeley, CA (United States); Muhlholland, Brendan J. [Lawrence Berkeley National Lab. (LBNL), Berkeley, CA (United States); Thorson, Patrick A. [Lawrence Berkeley National Lab. (LBNL), Berkeley, CA (United States); Xu, Suying Y. [Lawrence Berkeley National Lab. (LBNL), Berkeley, CA (United States); Sutherland, Nancy L. [Lawrence Berkeley National Lab. (LBNL), Berkeley, CA (United States); Wehle, Petra C. [Lawrence Berkeley National Lab. (LBNL), Berkeley, CA (United States)

    2016-09-30

    The annual Site Environmental Report documents Lawrence Berkeley National Laboratory’s performance in reducing its environmental impacts, progress toward cleaning up groundwater contamination, and compliance with applicable Department of Energy, federal, state, and local environmental regulations. The report is required by DOE Order 231.1B, Environment, Safety, and Health Reporting.

  1. EPA Proposes to Add Dutchess County Creek, N.Y. to the Federal Superfund List, Sediment Contaminated with Mercury, Polycyclic Aromatic Hydrocarbons

    Science.gov (United States)

    (New York, N.Y.) The U.S. Environmental Protection Agency today proposed adding the Wappinger Creek in Dutchess County, N.Y. to its Superfund National Priorities List of the country's most hazardous waste sites. Sediment within the two mile long tidal port

  2. Determination of cocaine in postmortem human liver exposed to overdose. Application of an innovative and efficient extraction/clean up procedure and gas chromatography-mass spectrometry analysis.

    Science.gov (United States)

    Magalhães, Elisângela Jaqueline; Ribeiro de Queiroz, Maria Eliana Lopes; Penido, Marcus Luiz de Oliveira; Paiva, Marco Antônio Ribeiro; Teodoro, Janaína Aparecida Reis; Augusti, Rodinei; Nascentes, Clésia Cristina

    2013-09-27

    A simple and efficient method was developed for the determination of cocaine in post-mortem samples of human liver via solid-liquid extraction with low temperature partitioning (SLE-LTP) and analysis by gas chromatography coupled to mass spectrometry (GC-MS). The extraction procedure was optimized by evaluating the influence of the following variables: pH of the extract, volume and composition of the extractor solvent, addition of a sorbent material (PSA: primary-secondary amine) and NaCl to clean up and increase the ionic strength of the extract. A bovine liver sample that was free of cocaine was used as a blank for the optimization of the SLE-LTP extraction procedure. The highest recovery was obtained when crushed bovine liver (2g) was treated with 2mL of ultrapure water plus 8mL of acetonitrile at physiological pH (7.4). The results also indicated no need for using PSA and NaCl. The complete analytical procedure was validated for the following figures of merit: selectivity, lower limit of quantification (LLOQ), calibration curve, recovery, precision and accuracy (for within-run and between-run experiments), matrix effect, dilution integrity and stability. The within-run and between-run precision (at four levels) varied from 2.1% to 9.4% and from 4.0% to 17.0%, respectively. A maximum deviation of 11.62% for the within-run and between-run accuracies in relation to the nominal concentrations was observed. Moreover, the LLOQ value for cocaine was 50.0ngg(-1) whereas no significant effects were noticed in the assays of dilution integrity and stability. To assess its overall performance, the optimized method was applied to the analysis of eight human liver samples collected from individuals who died due to the abusive consumption of cocaine. Due to the existence of a significant matrix effect, a blank human liver was used to construct a matrix-matched analytical curve. The concentrations of cocaine found in these samples ranged from 333.5 to 5969ngg(-1). Copyright

  3. Carson Lake Pasture : Mercury Superfund Site : Soil investigation

    Data.gov (United States)

    US Fish and Wildlife Service, Department of the Interior — The objective of this investigation is to determine whether the soil in the CLkP exceeds the EPA's hazardous waste level criterion for mercury and whether there is...

  4. BIOLOGICAL TREATMENT OF LEACHATE FROM A SUPERFUND SITE

    Science.gov (United States)

    Studies have heen completed on treating a leachate from New Lyme, Ohio. The leachate was transported to Cincinnati, Ohio, where a pilot-sized rotating biological contactor (RBC) was used for a treatment evaluation. he biomass was developed on the ARC discs with primary effluent f...

  5. A biological assessment of Wildcat Landfill Superfund Site

    Data.gov (United States)

    US Fish and Wildlife Service, Department of the Interior — This document was prepared as part of the Wildcat Landfill Remedial Investigation (RI) Report; the report was financed through a grant and authority of CERCLA as...

  6. Optimization Review, Fairfield Coal Gasification Plant Superfund Site, Fairfield, Iowa

    Science.gov (United States)

    The Fairfield Coal Gasification Plant (FCGP) also known as the Fairfield Former Manufactured Gas Plant (MGP) is located in the southwest 1/4 of the southeast 1/4, Section 26, Township 72 North, Range 10 West of Jefferson County, Iowa.

  7. OLEM Center for Program Analysis Site Analysis Data

    Data.gov (United States)

    U.S. Environmental Protection Agency — This asset includes environmental justice-related analyses of population located within a mile of Superfund and RCRA Corrective Action sites. It characterizes...

  8. Toxicity tests and sediment chemistry at Site 9 (Neptune Drive Disposal Site) - U.S. Naval Air Station, Brunswick, Maine

    Data.gov (United States)

    US Fish and Wildlife Service, Department of the Interior — During a remedial investigation of the U.S. Naval Air Station Superfund Site in Brunswick, Maine (NASB), elevated concentrations of total polycyclic aromatic...

  9. AMCO Off-Site Air Monitoring Polygons, Oakland CA, 2017, US EPA Region 9

    Data.gov (United States)

    U.S. Environmental Protection Agency — This feature class was developed to support the AMCO Chemical Superfund Site air monitoring process and depicts a single polygon layer, Off-Site Air Monitors,...

  10. The use of immunoaffinity columns connected in tandem for selective and cost-effective mycotoxin clean-up prior to multi-mycotoxin liquid chromatographic-tandem mass spectrometric analysis in food matrices.

    Science.gov (United States)

    Wilcox, Joyce; Donnelly, Carol; Leeman, David; Marley, Elaine

    2015-06-26

    This paper describes the use of two immunoaffinity columns (IACs) coupled in tandem, providing selective clean-up, based on targeted mycotoxins known to co-occur in specific matrices. An IAC for aflatoxins+ochratoxin A+fumonisins (AOF) was combined with an IAC for deoxynivalenol+zearalenone+T-2/HT-2 toxins (DZT); an IAC for ochratoxin A (O) was combined with a DZT column; and an aflatoxin+ochratoxin (AO) column was combined with a DZT column. By combining pairs of columns it was demonstrated that specific clean-up can be achieved as required for different matrices. Samples of rye flour, maize, breakfast cereal and wholemeal bread were analysed for mycotoxins regulated in the EU, by spiking at levels close to EU limits for adult and infant foods. After IAC clean-up extracts were analysed by LC-MS/MS with quantification using multiple reaction monitoring. Recoveries were found to be in range from 60 to 108%, RSDs below 10% depending on the matrix and mycotoxin combination and LOQs ranged from 0.1n g/g for aflatoxin B1 to 13.0 ng/g for deoxynivalenol. Surplus cereal proficiency test materials (FAPAS(®)) were also analysed with found levels of mycotoxins falling within the satisfactory range of concentrations (Z score ≤ ± 2), demonstrating the accuracy of the proposed multi-mycotoxin IAC methods.

  11. Superfund reform: US Environmental Protection Agency`s 30-day study and its implication for the US Department of Energy

    Energy Technology Data Exchange (ETDEWEB)

    Siegel, M.R.; Friedman, J.R.; Neff, R.W.

    1993-03-01

    As part of an ongoing effort to reform and restructure the US Environmental Protection Agency`s (EPAS) Superfund program, the EPA Administrator on October 21, 1991, announced several key programmatic reforms. These reforms are a result of the Superfund 30-Day Task Force Report (30-Day Study, EPA 1991a), an effort carried out by EPAs office of Solid Waste and Emergency Response (OSWER). The EPA OSWER oversees environmental cleanup activities under a number of statutory authorities, including the Comprehensive Environmental response, Compensation, and Liability Act (CERCLA, also known as Superfund). CERCLA and its implementing regulation, the National Contingency Plan (NCP), establish a regulatory framework to govern the cleanup of existing, and often abandoned, hazardous waste sites. The purposes of this report are to (1) review the background and recommendations of EPNs 30-Day Study, (2) identify and discuss the initiatives from the 30-Day Study that may impact DOE`s environmental restoration mission, (3) report on EPAs progress in implementing the selected priority initiatives, and (4) describe potentially related DOE activities.

  12. SUPERFUND GROUND WATER ISSUE - ACCURACY OF DEPTH TO WATER MEASUREMENTS

    Science.gov (United States)

    Accuracy of depth to water measurements is an issue identified by the Forum as a concern of Superfund decision-makers as they attempt to determine directions of ground-water flow, areas of recharge of discharge, the hydraulic characteristics of aquifers, or the effects of manmade...

  13. Combining the quick, easy, cheap, effective, rugged and safe approach and clean-up by immunoaffinity column for the analysis of 15 mycotoxins by isotope dilution liquid chromatography tandem mass spectrometry.

    Science.gov (United States)

    Desmarchelier, Aurélien; Tessiot, Sabine; Bessaire, Thomas; Racault, Lucie; Fiorese, Elisa; Urbani, Alessandro; Chan, Wai-Chinn; Cheng, Pearly; Mottier, Pascal

    2014-04-11

    Optimization and validation of a multi-mycotoxin method by LC-MS/MS is presented. The method covers the EU-regulated mycotoxins (aflatoxins, fumonisins, ochratoxin A, deoxynivalenol, zearalenone, T-2 and HT-2), as well as nivalenol and 3- and 15-acetyldeoxynivalenol for analysis of cereals, cocoa, oil, spices, infant formula, coffee and nuts. The proposed procedure combines two clean-up strategies: First, a generic preparation suitable for all mycotoxins based on the QuEChERS (for quick, easy, cheap, effective, rugged and safe) protocol. Second, a specific clean-up devoted to aflatoxins and ochratoxin A using immunoaffinity column (IAC) clean-up. Positive identification of mycotoxins in matrix was conducted according to the confirmation criteria defined in EU Commission Decision 2002/657/EC while quantification was performed by isotopic dilution using (13)C-labeled mycotoxins as internal standards. Limits of quantification were at or below the maximum levels set in the EC/1886/2006 document for all mycotoxin/matrix combinations under regulation. In particular, the inclusion of an IAC step allowed achieving LOQs as low as 0.05 and 0.25μg/kg in cereals for aflatoxins and ochratoxin A, respectively. Other performance parameters like linearity [(r)(2)>0.99], recovery [71-118%], precision [(RSDr and RSDiR)<33%], and trueness [78-117%] were all compliant with the analytical requirements stipulated in the CEN/TR/16059 document. Method ruggedness was proved by a verification process conducted by another laboratory. Copyright © 2014 Elsevier B.V. All rights reserved.

  14. 从宙斯轮案论燃油清污费用的责任限制问题%On the Limitation of Liability of Clean -up Costs of Bunker based on Zeus Case

    Institute of Scientific and Technical Information of China (English)

    庞凯华

    2015-01-01

    Maritime safety administration of sinking, killed, stranded ship compulsory clean-up measures to produce fuel oil clean-up costs, after the Supreme Court Zeus rounds a case as a nonrestrictive creditor' s rights, it is conform to the law, but also to ensure the maritime safety administration in the practice of sewage disposal cost of pay of full specified amount. For fuel oil clean-up fees shall apply for maritime claims limit judicial interpretation from the supreme people' s court "the 17th paragraph 1 and the oil from the supreme people' s court judicial interpretation" stipulated in article 20 as unrestricted claims. Take effect at the same time soon the Nairobi convention on international debris removal has important significance for China' s leg-islation.%海事局对沉没、遇难、搁浅船舶采取强制清污措施产生的燃油清污费用,最高院在宙斯轮一案中认定为非限制性债权.此举既符合法律规定,同时也保障了实践中海事局清污费用的足额偿付.对于燃油清污费用应适用《最高院海事赔偿限制司法解释》第17条1款和《最高院油污司法解释》第20条规定认定为非限制性债权.同时生效不久的《内罗毕国际残骸清除公约》对于我国立法具有重要借鉴意义.

  15. Revegetation Plan for Areas of the Fitzner-Eberhardt Arid Lands Ecology Reserve Affected by Decommissioning of Buildings and Infrastructure and Debris Clean-up Actions

    Energy Technology Data Exchange (ETDEWEB)

    Downs, Janelle L.; Durham, Robin E.; Larson, Kyle B.

    2011-01-01

    The U.S. Department of Energy (DOE), Richland Operations Office is working to remove a number of facilities on the Fitzner Eberhardt Arid Lands Ecology Reserve (ALE), which is part of the Hanford Reach National Monument. Decommissioning and removal of buildings and debris on ALE will leave bare soils and excavated areas that need to be revegetated to prevent erosion and weed invasion. Four main areas within ALE are affected by these activities (DOE 2009;DOE/EA-1660F): 1) facilities along the ridgeline of Rattlesnake Mountain, 2) the former Nike missile base and ALE HQ laboratory buildings, 3) the aquatic research laboratory at Rattlesnake Springs area, and 4) a number of small sites across ALE where various types of debris remain from previous uses. This revegetation plan addresses the revegetation and restoration of those land areas disturbed by decommissioning and removal of buildings, facilities and associated infrastructure or debris removal. The primary objective of the revegetation efforts on ALE is to establish native vegetation at each of the sites that will enhance and accelerate the recovery of the native plant community that naturally persists at that location. Revegetation is intended to meet the direction specified by the Environmental Assessment (DOE 2009; DOE/EA-1660F) and by Stipulation C.7 of the Memorandum of Agreement (MOA) for the Rattlesnake Mountain Combined Community Communication Facility and InfrastructureCleanup on the Fitzner/Eberhardt Arid Lands Ecology Reserve, Hanford Site, Richland Washington(DOE 2009; Appendix B). Pacific Northwest National Laboratory (PNNL) under contract with CH2M Hill Plateau Remediation Company (CPRC) and in consultation with the tribes and DOE-RL developed a site-specific strategy for each of the revegetation units identified within this document. The strategy and implementation approach for each revegetation unit identifies an appropriate native species mix and outlines the necessary site preparation activities

  16. Site Restoration

    Energy Technology Data Exchange (ETDEWEB)

    Noynaert, L.; Bruggeman, A.; Cornelissen, R.; Massaut, V.; Rahier, A

    2002-04-01

    The objectives, the programme, and the achievements of SCK-CEN's Site Restoration Department for 2001 are described. Main activities include the decommissioning of the BR3 PWR-reactor as well as other clean-up activities, projects on waste minimisation and the management of spent fuel and the flow of dismantled materials and the recycling of materials from decommissioning activities based on the smelting of metallic materials in specialised foundries. The department provides consultancy and services to external organisations and performs R and D on new techniques including processes for the treatment of various waste components including the reprocessing of spent fuel, the treatment of tritium, the treatment of liquid alkali metals into cabonates through oxidation, the treatment of radioactive organic waste and the reconditioning of bituminised waste products.

  17. Optimization of ultrasonic extraction and clean-up protocol for the determination of polycyclic aromatic hydrocarbons in marine sediments by high-performance liquid chromatography coupled with fluorescence detection

    Science.gov (United States)

    Peng, Xuewei; Yan, Guofang; Li, Xianguo; Guo, Xinyun; Zhou, Xiao; Wang, Yan

    2012-09-01

    The procedures of ultrasonic extraction and clean-up were optimized for the determination of polycyclic aromatic hydrocarbons (PAHs) in marine sediments. Samples were ultrasonically extracted, and the extracts were purified with a miniaturized silica gel chromatographic column and analyzed with high performance liquid chromatography (HPLC) with a fluorescence detector. Ultrasonication with methanol-dichloromethane (2:1, v/v) mixture gave higher extraction efficiency than that with dichloromethane. Among the three elution solvents used in clean-up step, dichloromethane-hexane (2:3, v/v) mixture was the most satisfactory. Under the optimized conditions, the recoveries in the range of 54.82% to 94.70% with RSDs of 3.02% to 23.22% for a spiked blank, and in the range of 61.20% to 127.08% with RSDs of 7.61% to 26.93% for a spiked matrix, were obtained for the 15 PAHs studied, while the recoveries for a NIST standard reference SRM 1941b were in the range of 50.79% to 83.78% with RSDs of 5.24% to 21.38%. The detection limits were between 0.75 ng L-1 and 10.99 ng L-1for different PAHs. A sample from the Jiaozhou Bay area was examined to test the established methods.

  18. Evaluation of alternative sorbents for dispersive solid-phase extraction clean-up in the QuEChERS method for the determination of pesticide residues in rice by liquid chromatography with tandem mass spectrometry.

    Science.gov (United States)

    Cabrera, Liziara da C; Caldas, Sergiane S; Prestes, Osmar D; Primel, Ednei G; Zanella, Renato

    2016-05-01

    Many compounds are used for pest control during the production and storage of rice, making it necessary to employ multiclass methods for pesticide residues determination. For this purpose, QuEChERS-based methods are very efficient, fast and accurate, and improvements in the clean-up step are important, especially for complex matrices, like cereals. In this work, different sorbents such as chitosan, florisil(®) , alumina, diatomaceous earth, graphitized carbon black, besides the commonly used primary secondary amine and octadecylsilane, were evaluated for dispersive solid-phase extraction clean-up in acetate-buffered QuEChERS method for the determination of residues of 20 representative pesticides and one metabolite in rice by liquid chromatography coupled to tandem mass spectrometry. The sorbent C18 presented the best results, however, chitosan showed similar results, and the best performance among the unconventional sorbents evaluated. The method limit of quantification, attending accuracy (70-120% recovery) and precision (RSD ≤20%) criteria, ranged from 5 to 20 μg/kg. Results showed that chitosan is an effective alternative to reduce analysis costs, maintaining the method reliability and accuracy.

  19. Determination of brominated diphenyl ethers (from mono- to hexa- congeners) in indoor dust by pressurised liquid extraction with in-cell clean-up and gas chromatography-mass spectrometry.

    Science.gov (United States)

    Martínez, María Pilar; Carrillo, José David; Tena, María Teresa

    2010-05-01

    This study presents a selective pressurised liquid extraction (PLE) and gas chromatography-mass spectrometry/mass spectrometry method for the determination of brominated diphenyl ethers (BDEs) in indoor dust. Selective PLE consisted of the addition of Florisil mixed with the sample in order to perform an in-cell clean-up. This approach provided a cleaner and almost colourless extract, ready to be injected in the gas chromatograph. The PLE conditions were studied using an experimental design, firstly a 4 x 3 x 2 multifactor categorical design to screen sorbent, solvent and temperature and then a central composite design to optimise sorbent mass, temperature and time. Finally, the number of extraction cycles was studied. The selected conditions were 4 g of Florisil all mixed with the sample and no additional clean-up sorbent layer, 1:1 n-hexane-dichloromethane, 60% flush volume, 40 degrees C, 1,500 psi, 2-min static time and one cycle. The proposed method allowed accurate determination of BDEs, with recovery values between 82% and 101% and detection limits between 0.06 and 0.24 ng g(-1). It also has advantages over other existing methods in terms of simplicity, automation, analysis time and solvent consumption.

  20. Optimization of Ultrasonic Extraction and Clean-up Protocol for the Determination of Polycyclic Aromatic Hydrocarbons in Marine Sediments by High-performance Liquid Chromatography Coupled with Fluorescence Detection

    Institute of Scientific and Technical Information of China (English)

    PENG Xuewei; YAN Guofang; LI Xianguo; GUO Xinyun; ZHOU Xiao; WANG Yan

    2012-01-01

    The procedures of ultrasonic extraction and clean-up were optimized for the determination of polycyclic aromatic hydrocarbons(PAHs)in marine sediments.Samples were ultrasonically extracted,and the extracts were purified with a miniaturized silica gel chromatographic column and analyzed with high performance liquid chromatography(HPLC)with a fluorescence detector.Ultrasonication with methanol-dichloromethane(2:1,v/v)mixture gave higher extraction efficiency than that with dichloromethane.Among the three elution solvents used in clean-up step,dichloromethane-hexane(2:3,v/v)mixture was the most satisfactory.Under the optimized conditions,the recoveries in the range of 54.82% to 94.70% with RSDs of 3.02% to 23.22% for a spiked blank,and in the range of 61.20% to 127.08% with RSDs of 7.61% to 26.93% for a spiked matrix,were obtained for the 15 PAHs studied,while the recoveries for a NIST standard reference SRM 1941b were in the range of 50.79% to 83.78% with RSDs of 5.24% to 21.38%.The detection limits were between 0.75ngL-1 and 10.99ngL-1for different PAHs.A sample from the Jiaozhou Bay area was examined to test the established methods.

  1. QuEChERS-based extraction with dispersive solid phase extraction clean-up using PSA and ZrO2-based sorbents for determination of pesticides in bovine milk samples by HPLC-DAD.

    Science.gov (United States)

    Rejczak, Tomasz; Tuzimski, Tomasz

    2017-02-15

    In this study, a quick, easy, cheap, effective, rugged and safe (QuEChERS) extraction technique was adapted to develop a simple sample treatment for multi-residue pesticide analysis in milk samples. The proposed method is based on liquid-liquid partitioning with acetonitrile followed by dispersive solid phase extraction clean-up using primary secondary amine along with zirconia-coated silica particles for extract purification. Identification and quantification of 30 pesticides was conducted via high performance liquid chromatography with diode-array detection (HPLC-DAD). Recoveries were from 70 to 100% for the vast majority of the analytes, with relative standard deviations less than 20% being observed. HPLC-DAD provided suitable linearity, precision and accuracy. For 28 of 30 analytes in the study method limit of quantification values (mLOQs) comply with the most recent European Union guidelines for the maximum residue levels (MRLs) in milk. Negligible matrix effect was observed due to efficient extract clean-up with ZrO2-based sorbents.

  2. Characterization and reclamation assessment for the Central Shops Diesel Storage Facility, Savannah River Site, Aiken, South Carolina

    Energy Technology Data Exchange (ETDEWEB)

    Fliermans, C.B.; Hazen, T.C.; Bledsoe, H.

    1993-10-01

    The contamination of subsurface terrestrial environments by organic contaminants is a global phenomenon. The remediation of such environments requires innovative assessment techniques and strategies for successful clean-ups. Central Shops Diesel Storage Facility at Savannah River Site was characterized to determine the extent of subsurface diesel fuel contamination using innovative approaches and effective bioremediation techniques for clean-up of the contaminant plume have been established.

  3. Hindcast, GIS and susceptibility modelling to assist oil spill clean-up and mitigation on the southern coast of Cyprus (Eastern Mediterranean)

    Science.gov (United States)

    Alves, Tiago M.; Kokinou, Eleni; Zodiatis, George; Lardner, Robin

    2016-11-01

    This study uses new oil-spill models, bathymetric, meteorological, oceanographic, geomorphological and geological data to assess the impact of distinct oil spill scenarios on the southern coast of Cyprus, Eastern Mediterranean. This approach results from the urgent need to predict oil spill dispersion after new oil terminals and depots were built at Vasilikos, southern coast of Cyprus. The terminals have been able to receive tankers with 500,000 deadweight tonnes from November 2014. The new geomorphological and geological data in this work show the shoreline of Cyprus to be of high susceptibility due to: (a) the presence of a narrow continental shelf capable of trapping large quantities of hydrocarbons; (b) the existence of uplifted wave-cut platforms, coastal lagoons and pools forming natural traps for oil, and (c) the presence of important tourist and Natura 2000 sites. Under particular weather and oceanographic conditions, oil spills offshore Larnaca Bay will quickly spread and reach the shoreline 46 h after the initial accident. Significantly, the models in this paper show a reduction from 84% to 19% in the volume of oil trapped on the coast if dispersants are applied, with the latter 19% being potentially kept at bay using booms and mechanical removal techniques. Based on these results, we suggest the early use of dispersants, booms and mechanical removal procedures to prevent the spreading of oil spilt in the broad area of Larnaca Bay.

  4. Horizontal directional drilling: a green and sustainable technology for site remediation.

    Science.gov (United States)

    Lubrecht, Michael D

    2012-03-06

    Sustainability has become an important factor in the selection of remedies to clean up contaminated sites. Horizontal directional drilling (HDD) is a relatively new drilling technology that has been successfully adapted to site remediation. In addition to the benefits that HDD provides for the logistics of site cleanup, it also delivers sustainability advantages, compared to alternative construction methods.

  5. Superfund/IGD: EF_NPL

    Data.gov (United States)

    U.S. Environmental Protection Agency — EF_NPL is a subset of facilities from FRS_INTEREST and FRS_FACILITY_SITE which are updated on a monthly basis as part of the Locational Reference Tables (LRT)...

  6. Cleaning up the Nalon, Caudal and Nora rivers: FEDER provide 1,000 million pesetas for the HUNOSA project. Saneamiento de los rios Nalon, Caudal y Nora. El FEDER aporta mil millones para un proyecto de HUNOSA

    Energy Technology Data Exchange (ETDEWEB)

    1990-09-01

    The Commission of the European Communities has recently approved aid from FEDER (European Regional Development Fund) for the HUNOSA project 'Cleaning discharge into public waterways from HUNOSA's coal washeries' to the value of 1,000 million pesetas. This is the maximum grant available from the Fund and equates to 45% of the total investment, estimated at 2,200 million pesetas. The project has been organised and carried out by HUNOSA and involves cleaning up the Nalon, Caudal and Nora rivers between 1990 and 1992. The project also includes a comprehensive study of the six washeries contributing to the pollution of the rivers and will apply to each the cheapest and most viable solution from an operational standpoint. 1 fig.

  7. The role of peer review in responsive decisions - a case study of clean-up and safe long-term management of historic waste at Port Hope and Clarington

    Energy Technology Data Exchange (ETDEWEB)

    Hardy, D. [Hardy Stevenson and Associates Inc., Toronto, Ontario (Canada)

    2006-07-01

    'Full text:' The Municipalities of Port Hope and Clarington ('Municipalities') are committed to leading the clean- up and safe long-term management of historic low- level radioactive and hazardous wastes deposited in Port Granby (in the Municipality of Clarington) and several locations in the Municipality of Port Hope. They are supported by the Government of Canada through Atomic Energy of Canada Limited's (AECL) Low- Level Radioactive Waste Management Office (LLRWMO). The wastes are the result of radium and uranium processing in Port Hope by Eldorado since the 1930s. To establish the parameters of the clean- up, including the ability to veto the project, the local municipalities negotiated and signed a Legal Agreement with the Government of Canada in 2001. As a Responsible Authority, Natural Resources Canada has defined and approved the scope of the two projects. The LLRWMO is designated as the proponent. Accordingly, the LLRWMO is conducting the Environmental Assessment (EA) Studies and seeking approval of a preferred method of conducting the clean up for each municipality. The municipalities recognized that these large and complex environmental assessment studies would challenge the resources of citizens, municipal professional staff and politicians. Thus, the Legal Agreement specified that both municipalities would have funded staff to work together to coordinate and expedite the project. A Peer Review Team (PRT) would be retained by the municipalities and funded by the Government of Canada. The PRT is made up of experienced professionals led by Hardy Stevenson and Associates Limited in disciplines appropriate to the peer review tasks on hand. The PRT has brought a unique approach to the peer review. The PRT is headed by planners and social scientists trained to be sensitive to the 'people aspects' of the EA process as a major priority. They are supported by engineers and technical specialists. The team includes a physician

  8. Erika: evaluation of residual sanitary risks linked to the beaches-going after cleaning-up; Erika: evaluation des risques sanitaires residuels lies a la frequentation des plages apres depollution

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    2000-07-01

    The aim of this study is to evaluate the sanitary risks for the populations frequenting the coast beaches affected by the fuel oils of the tanker Erika, after their cleaning up. This quantitative evaluation of sanitary risks is led according to a protocol developed jointly between the two institutes ( the national institute of industrial environment and risks, I.N.E.R.I.S., and the national institute of sanitary watch I.n.V.S.). It does not give the risks in function the residual pollution level of concerned beaches but supplies to the authorities elements of scientific information in order to allow them to choose criteria appropriate for the management of eventual residual risks. (N.C.)

  9. Strategic plan for Hanford site information management

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    1994-09-01

    The Hanford Site missions are to clean up the Site, to provide scientific knowledge and technology to meet global needs, and to partner in the economic diversification of the region. To achieve these long-term missions and increase confidence in the quality of the Site`s decision making process, a dramatically different information management culture is required, consistent with US Department of Energy (DOE) mandates on increased safety, productivity, and openness at its sites. This plan presents a vision and six strategies that will move the Site toward an information management culture that will support the Site missions and address the mandates of DOE.

  10. Hazardous waste sites

    Energy Technology Data Exchange (ETDEWEB)

    Hembra, R.L

    1989-01-01

    This report has found that while most states have accomplished few or no cleanups of sites contaminated by hazardous waste, some have enacted tough cleanup laws, committed relatively large resources to the cleanup effort, and achieved considerable results. At the 17 cleanup sites analyzed, state cleanup plans were generally stringent. However, no federal standards have been set for over half of the contaminants found at these sites. For 11 sites, the states set cleanup levels without doing formal risk assessments. Also, most states reviewed did not consider the full range of alternatives EPA requires. Most states have not shown that they can effectively clean up large, hazardous waste sites. This report recommends that EPA turn sites targeted for cleanup over to the states only if there are adequate controls and oversight.

  11. Simultaneous extraction and clean-up of polybrominated diphenyl ethers and polychlorinated biphenyls from sheep liver tissue by selective pressurized liquid extraction and analysis by gas chromatography-mass spectrometry.

    Science.gov (United States)

    Zhang, Zulin; Ohiozebau, Ehimai; Rhind, Stewart M

    2011-02-25

    We describe a selective pressurized liquid extraction (SPLE) method, followed by gas chromatography-mass spectrometry (GC-MS), for the simultaneous extraction and clean-up of polybrominated diphenyl ethers (PBDEs) and polychlorinated biphenyls (PCBs) in sheep liver tissue samples. The on-line clean-up of liver tissue by SPLE was tested using differing amount of acid-modified silica (sulphuric acid:silica gel, 1:2, w/w), the most effective amount being 20 g. Different extraction solvents (iso-hexane and dichloromethane), either alone or in various combinations, were used to extract these target compounds from spiked liver samples. Variables affecting the SPLE extraction efficiency, including temperature, pressure, number of extraction cycles and static extraction time were studied; the optimum parameters were 80 °C, 10.3 MPa, 2 cycles and 5 min, respectively. The SPLE based method was compared with more traditional Soxhlet, off-line PLE, ultrasonic and heating extraction methods. Overall the mean percentage recoveries for all target chemicals using SPLE were 86-103% (n=3, SD extraction methods. The limits of detection of the proposed method were 5-96 pg g⁻¹ and 2-29 pg g⁻¹ for the different PBDE and PCB chemicals studied, respectively. The outputs of the proposed method were linear over the range from 0.02 to 30 ng g⁻¹, for all PCB and PBDE congeners except for PBDE 100 and 153 (0.05-30 ng g⁻¹) and PBDE 183 (0.1-30 ng g⁻¹). The method was successfully applied to sheep liver samples for the determination of the target PBDE and PCB compounds.

  12. Shoreline clean-up methods : biological treatments

    Energy Technology Data Exchange (ETDEWEB)

    Massoura, S.T. [Oil Spill Response Limited, Southampton (United Kingdom)

    2009-07-01

    The cleanup of oil spills in shoreline environments is a challenging issue worldwide. Oil spills receive public and media attention, particularly in the event of a coastal impact. It is important to evaluate the efficiency and effectiveness of cleanup methods when defining the level of effort and consequences that are appropriate to remove or treat different types of oil on different shoreline substrates. Of the many studies that have compared different mechanical, chemical and biological treatments for their effectiveness on various types of oil, biological techniques have received the most attention. For that reason, this paper evaluated the effectiveness and effects of shoreline cleanup methods using biological techniques. It summarized data from field experiments and oil spill incidents, including the Exxon Valdez, Sea Empress, Prestige, Grand Eagle, Nakhodka, Guanabara Bay and various Gulf war oil spills. Five major shoreline types were examined, notably rocky intertidal, cobble/pebble/gravel, sand/mud, saltmarsh, and mangrove/sea-grass. The biological techniques that were addressed were nutrient enrichment, hydrocarbon-utilizing bacteria, vegetable oil biosolvents, plants, surf washing, oil-particle interactions and natural attenuation. The study considered the oil type, volume and fate of stranded oil, location of coastal materials, extent of pollution and the impact of biological techniques. The main factors that affect biodegradation of hydrocarbons are the volume, chemical composition and weathering state of the petroleum product as well as the temperature, oxygen availability of nutrients, water salinity, pH level, water content, and microorganisms in the shoreline environment. The interaction of these factors also affect the biodegradation of oil. It was concluded that understanding the fate of stranded oil can help in the development of techniques that improve the weathering and degradation of oil on complex shoreline substrates. 39 refs.

  13. Clean-up at the ISR

    CERN Multimedia

    2001-01-01

    After six months of work, the part of the ISR coming under EP Division has been emptied and refurbished. The area is now ready to start building the LHC experiments. People who know the ISR from way back are likely to be surprised when they push open the doors to the old collider. Whereas the part of the tunnel allocated to EP (Experimental Physics) Division now stands empty, a few months ago, it was piled high with odds and ends. For more than 20 years, this part of the former Intersecting Storage Rings, a full quarter of the loop, had been used as storage space. Both items of value and pure junk had been dumped there, ranging from detector prototypes and 30 years old pumps with signs saying 'not to be thrown out', down to planks, a beautiful velvet armchair, and hundreds of electricity racks. Aloïs Girardoz, lost in the huge ISR hall, which will now be used for building the muon chambers of CMS. An audit carried out in 1996 on the research sector storage areas and accelerators signalled an end t...

  14. Head to Toe Clean-Up

    Institute of Scientific and Technical Information of China (English)

    Li Li

    2013-01-01

    Concerted effort to rectify extravagance and corruption begins within Party's national leadership Since their election at the 18th National Congress of the Communist Party of China(CPC) last November,the new leaders of the CPC have engaged in projects to raise public satisfaction by fighting corruption,bringing leaders closer to

  15. Cleaning up the future of coal

    Institute of Scientific and Technical Information of China (English)

    2007-01-01

    @@ CAS is making efforts to seek green solutions to address the pollution problem of the traditional forms of coal utilization. For instance, as SONG Jianlan reports, a research team from the Taiyuan-based CAS Institute of Coal Chemistry has developed clean, efficient ways to convert coal into liquefied fuels.

  16. Clorox cleans up its light quality

    Energy Technology Data Exchange (ETDEWEB)

    Anon.

    2009-01-15

    Clorox Canada introduced a new lighting solution at its 300,000 square foot distribution centre in an effort to upgrade its energy management practices. High pressure sodium lamps were replaced with six-lamp T-8 high bay fixtures supplied by Nexstar Lighting. Light sensors were installed so that side aisles would only be lit when needed. Both cost savings and light quality were taken into account. The retrofit reduced energy use by 51 per cent and light levels were improved considerably. The payback period was 1.2 years for the entire project. In addition, maintenance costs are expected to decrease as the expected service life of a T-8 fixture is about 8 years. 2 figs.

  17. Cleaning up the slop: Pt. 2

    Energy Technology Data Exchange (ETDEWEB)

    Goldman, G.K.; Idzqandar, A.B.; Paille, A.

    1999-12-01

    The paper describes how waste minimisation and recovery of saleable oil from slop emulsion sludges have achieved a BS and W of 0.00% for waxy crude. Tests on the new product (called 505-SD Slop Oil Dispersant or simply 505-SD) have shown that apart from being able to keep paraffin wax suspended in crude oil without separating out at ambient or lower temperature (the original purpose for developing the product), a modified form can be used as an additive to lube oil base stocks and reduce the cloud point of the base stocks by up to 15{sup o}C. The paper focuses on the use of 505-SD in waste minimisation. A two-step tank cleaning process is described. Two laboratory case studies demonstrated how oily emulsions were treated to successfully recover the hydrocarbon fraction. A pilot scale field study was also successful. The new technology is likely to lead to many new methods of utilising wax and sludge oil wastes that in the past were regarded as worthless.

  18. lnfluence of Trapping and Cleaning up Dead Pine Trees on the Amount of Monoehanusaternatus%诱捕和清理枯死松木对松墨天牛数量的影响

    Institute of Scientific and Technical Information of China (English)

    陈丽莉; 宋美兰; 范海元; 罗洪

    2016-01-01

    利用广东省林业科学研究院研制的A-3型松墨天牛引诱剂进行诱捕松墨天牛试验,结果表明,松墨天牛在江西省峡江县马尾松林区发生期为5月上旬至8月上旬,大量发生期为6月中下旬,在活动期内有一个明显的活动高峰期,并伴随着活动小高峰。而在清理枯死松木的林分,没有明显的活动高峰期,松墨天牛的种群密度少,只占未清理枯死松木松林的21.7%,松墨天牛种群密度减退十分明显。采用引诱剂诱捕的方法可以杀灭大量的松墨天牛,长期彻底清理枯死松木也可使松墨天牛种群数量大量减少,诱捕和清理结合可大大降低松材线虫病传播机率,从而控制松材线虫病蔓延。%A-3 researched and pro-duced by Guangdong Academy of Forestry was used to trap Monoehanusa ternatus. The results showed that M. ter-natus adult stage in Xiajiang County oc-curred from the early May to the early August, and the occurrence peak was the last 20 days of June. The population density of M. ternatus in the forest that cleaning up dead pine trees accounted for 21.7% of the forest that untreated dead pine trees. Therefore, trapping and cleaning up dead pine trees could great-ly reduce the population number of M. ternatus and the spreading of pine wood nematode disease.

  19. 76 FR 13615 - B&B Manufacturing Site; Mobile, Mobile County, AL; Notice of Settlement

    Science.gov (United States)

    2011-03-14

    ... AGENCY B&B Manufacturing Site; Mobile, Mobile County, AL; Notice of Settlement AGENCY: Environmental... Manufacturing Site located in Mobile, Mobile County, Alabama for publication. DATES: The Agency will consider... No. EPA-RO4- SFUND-2011-0192 or Site name B&B Manufacturing Superfund Site by one of the...

  20. 76 FR 2112 - Peach Orchard Road Groundwater Plume Site, Augusta, Richmond County, GA; Notice of Settlement

    Science.gov (United States)

    2011-01-12

    ... AGENCY Peach Orchard Road Groundwater Plume Site, Augusta, Richmond County, GA; Notice of Settlement... costs concerning the Peach Orchard Road Groundwater Plume Site located in Augusta, Richmond County... Site name Peach Orchard Road Groundwater Plume Superfund Site by one of the following methods: http...

  1. Pressurized liquid extraction with in-cell clean-up followed by gas chromatography-tandem mass spectrometry for the selective determination of parabens and triclosan in indoor dust.

    Science.gov (United States)

    Canosa, P; Pérez-Palacios, D; Garrido-López, A; Tena, M T; Rodríguez, I; Rubí, E; Cela, R

    2007-08-17

    A sample preparation method based on the use of pressurized liquid extraction is proposed for the determination of four alkyl parabens and triclosan in indoor dust. Extraction of analytes and removal of interfering species were achieved in the same step, by placing an appropriate sorbent in the extraction cell and by choosing a right combination of washing and elution solvents. Compounds, as silylated derivatives, were determined by gas chromatography in combination with tandem mass spectrometry (GC-MS/MS). Factors affecting the yield and selectivity of the sample preparation procedure were carefully evaluated. Under final conditions, dried samples (0.5 g of dust and 1g of sodium sulphate) were dispersed with 3g of Florisil and loaded into an 11 mL stainless-steel extraction cell containing 1g of the same material as clean-up sorbent. Non-polar species were removed with n-hexane under mild conditions (40 degrees C, 3.4 MPa) and then analytes were extracted with ethyl acetate. The best compromise extraction conditions were 103 degrees C, 13.8 MPa and 3 static extraction cycles of 1 min. The proposed method provided recoveries from 76 to 98%, relative standard deviations under 11% (operating under reproducibility conditions) and quantification limits from 1 to 4 ng/g. The analysis of dust samples from private houses and office buildings confirmed the ubiquitous presence of target bacteriocides in these environments.

  2. Liquid chromatography-high resolution mass spectrometry with immunoaffinity clean-up for the determination of the oxidative stress biomarker 8-iso-prostaglandin F2alpha in wastewater.

    Science.gov (United States)

    Ryu, Yeonsuk; Reid, Malcolm J; Thomas, Kevin V

    2015-08-28

    A reliable oxidative stress biomarker, 8-iso-prostaglandin F2α (8-iso-PGF2α), was for the first time quantitatively analysed in wastewater using an analytical method consisting of liquid chromatography-high resolution mass spectrometry coupled to immunoaffinity clean-up (IAC-LC-HRMS). Factors influencing the method's robustness were investigated, including analyte stability in sewage and enzymatic deconjugation with β-glucuronidase. The IAC-LC-HRMS method was linear over the range of 0.1-100ng/mL with correlation coefficient (R(2)) of 0.999. The quantification limits were sufficiently low to detect 8-iso-PGF2α in sewage (method quantification limit of 0.3ng/L) and precision, expressed as relative standard deviation was less than 7% and the accuracy expressed as relative recovery was in the 103-113% range. As a result, the application of the method to 24-h composite wastewater samples from Oslo showed 8-iso-PGF2α concentrations of 18.9-23.3ng/L for 8 days in March 2015. This study demonstrates a standard method to analyse 8-iso-PGF2α in sewage that will contribute to the further investigation of the potential use of 8-iso-PGF2α as a sewage biomarker for assessing the status of community health. Copyright © 2015 Elsevier B.V. All rights reserved.

  3. Ultra-fast liquid chromatography with tandem mass spectrometry determination of ochratoxin A in traditional Chinese medicines based on vortex-assisted solid-liquid microextraction and aptamer-affinity column clean-up.

    Science.gov (United States)

    Yang, Xihui; Hu, Yichen; Kong, Weijun; Chu, Xianfeng; Yang, Meihua; Zhao, Ming; Ouyang, Zhen

    2014-11-01

    A rapid, selective, and sensitive ultra-fast liquid chromatography with tandem mass spectrometry method was developed for the determination of ochratoxin A in traditional Chinese medicines based on vortex-assisted solid-liquid microextraction and aptamer-affinity column clean-up. Through optimizing the sample pretreatment procedures and chromatographic conditions, good linearity (r(2) ≥ 0.9993), low limit of detection (0.5-0.8 μg/kg), and satisfactory recovery (83.54-94.44%) expressed the good reliability and applicability of the established method in various traditional Chinese medicines. Moreover, the aptamer-affinity column, prepared in-house, showed an excellent feasibility owing to its specific identification of ochratoxin A in various kinds of selected traditional Chinese medicines. The maximum adsorption amount and applicability value were 188.96 ± 10.56 ng and 72.3%, respectively. The matrix effects were effectively eliminated, especially for m/z 404.2→358.0 of ochratoxin A. The application of the developed method for screening the natural contamination levels of ochratoxin A in 25 random traditional Chinese medicines on the market in China indicated that only eight samples were contaminated with low levels below the legal limit (5.0 μg/kg) set by the European Union. This study provided a preferred choice for the rapid and accurate monitoring of ochratoxin A in complex matrices.

  4. Application of ion-exchange cartridge clean-up in food analysis. VI. Determination of six penicillins in bovine tissues by liquid chromatography-electrospray ionization tandem mass spectrometry.

    Science.gov (United States)

    Ito, Yuko; Goto, Tomomi; Oka, Hisao; Matsumoto, Hiroshi; Takeba, Kazue

    2004-07-09

    A multiresidue analytical method was developed for the quantification of benzylpenicillin (PCG), phenoxymethylpenicillin (PCV), oxacillin (MPIPC), cloxacillin (MCIPC), nafcillin (NFPC) and dicloxacillin (MDIPC) in bovine tissues using liquid chromatography- electrospray ionization tandem mass spectrometry (LC-ESI MS/MS) with a multiple reaction monitoring technique. Using the deuterated PCG and NFPC as internal standard was effective for improvement of repeatability and accuracy. We chose [M-H-141]- as a monitor ion of MRM analysis and [M-H]- as a precursor ion for each penicillin. Combination of an ion-exchange cartridge clean-up and ion-pair LC enable us to determine the residual penicillins using the standard curves made from standard solutions without the influence of sample matrix on the MS. The average recoveries of PCG, PCV, MPIPC, MCIPC, NFPC and MDIPC from bovine liver, kidney and muscle at the same concentrations as the tolerance levels of PCG (50 microg/kg) ranged from 77 to 101% with the coefficients of variation ranging from 0.7 to 4.2% (n = 5). The limits of quantification for the six penicillins were 2-10 microg/kg in bovine muscle, liver and kidney (S/N ratio >10).

  5. Application of ion-exchange cartridge clean-up in food analysis III. Determination of benzylpenicillin, phenoxymethyl-penicillin, oxacillin, cloxacillin, nafcillin and dicloxacillin in bovine liver and kidney by liquid chromatography with ultraviolet detection.

    Science.gov (United States)

    Ito, Y; Ikai, Y; Oka, H; Matsumoto, H; Kagami, T; Takeba, K

    2000-06-02

    A multiresidue analytical method was developed for the simultaneous determination of benzylpenicillin (PCG), phenoxymethylpenicillin (PCV), oxacillin (MPIPC), cloxacillin (MCIPC), nafcillin (NFPC) and dicloxacillin (MDIPC) in bovine liver and kidney. The method involves the use of an ion-exchange cartridge for sample clean-up followed by ion-pair high-performance liquid chromatography with ultraviolet detection. The recoveries of PCG, PCV, MPIPC, MCIPC, NFPC and MDIPC from bovine liver spiked at levels of 0.5 mg/kg and 0.1 mg/kg were in the range of 73-91% and 83-96% with coefficients of variation of 1.4-4.2% and 3.4-8.7%, respectively. For bovine kidney spiked at levels of 0.5 mg/kg and 0.1 mg/kg, the recoveries of these compounds were 79-92% and 82-92% with RSDs of 1.8-5.9% and 2.7-7.8%, respectively. The detection limits for the six penicillins were 0.02-0.05 mg/kg in bovine liver and kidney.

  6. Letter to Silverton and San Juan County Regarding Potential Superfund Listing

    Science.gov (United States)

    Feb. 12, 2016 Update: EPA added a letter to the Town of Silverton and San Juan County regarding the agency’s commitment to the Town and County’s involvement during a potential Superfund listing process.

  7. Grain Handling Facility at Freeman, Washington Proposed to Superfund Cleanup List

    Science.gov (United States)

    (March 24, 2015 - Seattle) The U.S. Environmental Protection Agency is proposing to add the Grain Handling Facility at Freeman, in Spokane County, Washington, to the Superfund National Priorities List. The proposed listing includes a 60-day public comment

  8. Improved method for the simultaneous determination of aflatoxins, ochratoxin A and Fusarium toxins in cereals and derived products by liquid chromatography-tandem mass spectrometry after multi-toxin immunoaffinity clean up.

    Science.gov (United States)

    Lattanzio, Veronica Maria Teresa; Ciasca, Biancamaria; Powers, Stephen; Visconti, Angelo

    2014-08-01

    An improved method for the quantitative determination of aflatoxins (B1, B2, G1, G2), ochratoxin A, fumonisins (B1, B2), zearalenone, deoxynivalenol, nivalenol, T-2 and HT-2 toxins in cereals and derived products, at levels comparable with EU maximum permitted levels, was developed. The effective co-extraction of the mycotoxins under investigation was achieved in 4min by a double extraction approach, using water followed by methanol. Clean up of the extract was performed by a new multi-toxin immunoaffinity column. Analytical performance characteristics were evaluated through single laboratory validation. Raw wheat and maize, corn flakes and maize snacks were chosen as representative matrices for method validation. The validation assay was carried out at 50, 100 and 150% of EU maximum permitted levels for each mycotoxin. Statistical analysis of the results (ANOVA) provided the within laboratory reproducibility and the error contributions from repeatability, between day effects, and influences from different matrix composition. Recoveries generally higher than 70% were obtained for all tested mycotoxins with relative standard deviation (within laboratory reproducibility) lesser than 37%. Limits of quantification (calculated as the lowest amount of each analyte which could be determined with a precision of 10%) ranged from 1μg/kg to 30μg/kg. The trueness of generated data was assessed by analysis of reference materials. The proposed method was proven to be suitable to assess, with a single analysis, compliance of the selected cereal based foods with the EU maximum permitted or recommended levels for all regulated mycotoxins.

  9. Association between health information, use of protective devices and occurrence of acute health problems in the Prestige oil spill clean-up in Asturias and Cantabria (Spain: a cross-sectional study

    Directory of Open Access Journals (Sweden)

    Rodríguez-Artalejo Fernando

    2006-01-01

    Full Text Available Abstract Background This paper examines the association between use of protective devices, frequency of acute health problems and health-protection information received by participants engaged in the Prestige oil spill clean-up in Asturias and Cantabria, Spain. Methods We studied 133 seamen, 135 bird cleaners, 266 volunteers and 265 paid workers selected by random sampling, stratified by type of worker and number of working days. Information was collected by telephone interview conducted in June 2003. The association of interest was summarized, using odds ratios (OR obtained from logistic regression. Results Health-protection briefing was associated with use of protective devices and clothing. Uninformed subjects registered a significant excess risk of itchy eyes (OR:2.89; 95%CI:1.21–6.90, nausea/vomiting/dizziness (OR:2.25; 95%CI:1.17–4.32 and throat and respiratory problems (OR:2.30; 95%CI:1.15–4.61. There was a noteworthy significant excess risk of headaches (OR:3.86: 95%CI:1.74–8.54 and respiratory problems (OR:2.43; 95%CI:1.02–5.79 among uninformed paid workers. Seamen, the group most exposed to the fuel-oil, were the worst informed and registered the highest frequency of toxicological problems. Conclusion Proper health-protection briefing was associated with greater use of protective devices and lower frequency of health problems. Among seamen, however, the results indicate poorer dissemination of information and the need of specific guidelines for removing fuel-oil at sea.

  10. Rapid estimation of readily leachable triazine residues in soils using automatic kinetic bioaccessibility assays followed by on-line sorptive clean-up as a front-end to liquid chromatography.

    Science.gov (United States)

    Vida, Ana C F; Cocovi-Solberg, David J; Zagatto, Elias A G; Miró, Manuel

    2016-08-15

    An automatic batchwise bioaccessibility test was proposed for on-line monitoring of readily mobile pools of ametryn and atrazine residues in agricultural soils with different physicochemical properties. A 0.01molL(-1) CaCl2 solution mimicking rainwater percolation through the soil profiles was used for the herbicide extractions. The extract aliquots were successively sampled at regular time intervals in order to investigate the extraction kinetics. For extract clean-up and retention of freely dissolved target species, 30mg of restricted-access like copolymer were used as in-line sorptive material followed by elution with methanol and on-line heart-cut injection towards a C18 silica reversed-phase monolithic column (100×4.6mm) in a liquid chromatographic system. A mathematical model emphasized that the readily available pools vs time can be in most instances described by a first-order exponential equation, thus an asymptotical value is approached. Consequently, the leaching assays can be performed without attaining chemical equilibrium. Enhancement factors and detection limits were 10.2 and 18.8, and 0.40 and 0.37mgkg(-1) for ametryn and atrazine, respectively. The automatic method features good repeatability for leaching tests (r.s.d.: 11.8-10.2% for sandy and 3.7-6.2% for clayey soil). Reliable data, demonstrated with relative recoveries in the soil leachates ranging from 86 to 104%, were achieved in less than 35min, thus avoiding the need for up to 24h as recommended by standard leaching methods.

  11. Site Enforcement Tracking System (SETS): PRP listing by site for Region 9

    Energy Technology Data Exchange (ETDEWEB)

    1992-07-01

    When expending Superfund monies at a CERCLA (Comprehensive Environmental Response, Compensation and Liability Act) site, EPA must conduct a search to identify parties with potential financial responsibility for remediation of uncontrolled hazardous waste sites. EPA regional Superfund Waste Management Staff issue a notice letter to the potentially responsible party (PRP). Data from the notice letter is used to form the Site Enforcement Tracking System (SETS). This data includes PRP name and address, a company contact person, the date the notice was issued, and the related CERCLA site name and identification number. SETS was created to track PRP identification at both NPL (National Priorities List) and non-NPL sites. SETS does not address the range of other administrative duties related to tracking the PRP. Region 9 includes American Samoa, Arizona, California, Guam, Hawaii, Midway, Nevada, Northern Marianas, Pacific Islands, Trust Territories, and Wake Island.

  12. Phytoextraction of Pb and Cd from a superfund soil: effects of amendments and croppings.

    Science.gov (United States)

    Bricker, T J; Pichtel, J; Brown, H J; Simmons, M

    2001-01-01

    In a growth chamber, maize (Zea mays) and Indian mustard (Brassica juncea) were grown over two croppings in soil from a Superfund site (PbTotal = 65,200 mg/kg and CdTotal = 52mg/kg). Soil treatments consisted of ethylenediaminetetraacetic acid, sodium citrate and composted sewage sludge, each at two rates (EDTA .05%, EDTA .2%, citrate .05%, citrate .2%, CSS 5% and CSS 10%, respectively). In most cases, the EDTA and citrate treatments were superior in terms of solubilizing soil Pb for root uptake and translocation into above-ground biomass. In the first maize crop, the EDTA .2% treatment resulted in 2,435 and 9,389mg/kg Pb in shoot and root tissues, respectively. The CSS treatments typically resulted in lowest Pb and Cd removal efficiencies. Lead remaining in the soil after two croppings was mainly associated with the carbonate, organic, and residual fractions, which represent the less bioavailable forms. Soil Cd was generally more mobile for plant uptake than soil Pb. The EDTA .2% and citrate treatments were most successful in promoting Cd uptake by both maize and mustard. Although Pb concentrations (mg/kg tissue) were lower for maize than mustard, the former removed more total Pb (0.2 mg per pot, mean over all treatments), compared to mustard (0.03 mg), by virtue of its higher biomass production.

  13. Superfund record of decision (EPA Region 9): McClellan Air Force Base, Basewide Groundwater Operable Unit, Sacramento, CA, May 11, 1995

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    1995-07-01

    The Interim Record of Decision (ROD) presents the interim remedial action for the Groundwater Operable Unit (Groundwater OU) at the McClellan Air Force Base (McClellan AFB) Superfund site in Sacramento, California. The Groundwater OU addresses all of the VOC-contaminated groundwater at McClellan AFB. The Groundwater OU remedy is designed to prevent the spread of contamination that is already in the groundwater by containing groundwater with concentrations greater than maximum contaminant levels (MCLs). The remedy is also designed to remove to the maximum extent practicable the mass of contamination that lies in that volume of the groundwater.

  14. Borehole induction logging for the Dynamic Underground Stripping Project LLNL gasoline spill site

    Energy Technology Data Exchange (ETDEWEB)

    Boyd, S.; Newmark, R.; Wilt, M.

    1994-01-21

    Borehole induction logs were acquired for the purpose of characterizing subsurface physical properties and monitoring steam clean up activities at the Lawrence Livermore National Laboratory. This work was part of the Dynamic Underground Stripping Project`s demonstrated clean up of a gasoline spin. The site is composed of unconsolidated days, sands and gravels which contain gasoline both above and below the water table. Induction logs were used to characterize lithology, to provide ``ground truth`` resistivity values for electrical resistance tomography (ERT), and to monitor the movement of an underground steam plume used to heat the soil and drive volatile organic compounds (VOCs) to the extraction wells.

  15. The StreamCat Dataset: Accumulated Attributes for NHDPlusV2 (Version 2.1) Catchments Riparian Buffer for the Conterminous United States: Facility Registry Services (FRS) : Toxic Release Inventory (TRI) , National Pollutant Discharge Elimination System (NPDES) , and Superfund Sites

    Data.gov (United States)

    U.S. Environmental Protection Agency — This dataset represents the estimated density of georeferenced sites within individual, local NHDPlusV2 catchments and upstream, contributing watersheds riparian...

  16. ANAEROBIC COMPOST CONSTRUCTED WETLANDS SYSTEM TECHNOLOGY - SITE TECHNOLOGY CAPSULE

    Science.gov (United States)

    In fall 1994, anaerobic compost wetlands in both upflow and down flow configurations were constructed adjacent to and received drainage from the Burleigh tunnel, which forms part of the Clear Creek/Central City Superfund site. The systems were operated over a 3 year period. The ...

  17. ANAEROBIC COMPOST CONSTRUCTED WETLANDS SYSTEM TECHNOLOGY - SITE ITER

    Science.gov (United States)

    In Fall 1994, anaerobic compost wetlands in both upflow and downflow configurations were constructed adjacent to and received drainage from the Burleigh Tunnel, which forms part of the Clear Creek/Central City Superfund site. The systems were operated over a 3 year period. The e...

  18. ANAEROBIC COMPOST CONSTRUCTED WETLANDS SYSTEM TECHNOLOGY - SITE TECHNOLOGY CAPSULE

    Science.gov (United States)

    In fall 1994, anaerobic compost wetlands in both upflow and down flow configurations were constructed adjacent to and received drainage from the Burleigh tunnel, which forms part of the Clear Creek/Central City Superfund site. The systems were operated over a 3 year period. The ...

  19. ANAEROBIC COMPOST CONSTRUCTED WETLANDS SYSTEM TECHNOLOGY - SITE ITER

    Science.gov (United States)

    In Fall 1994, anaerobic compost wetlands in both upflow and downflow configurations were constructed adjacent to and received drainage from the Burleigh Tunnel, which forms part of the Clear Creek/Central City Superfund site. The systems were operated over a 3 year period. The e...

  20. 78 FR 46948 - Proposed Agreement Regarding Site Costs and Covenants Not To Sue for American Lead and Zinc Mill...

    Science.gov (United States)

    2013-08-02

    ... AGENCY Proposed Agreement Regarding Site Costs and Covenants Not To Sue for American Lead and Zinc Mill... response costs incurred at the American Lead and Zinc Mill Superfund Site near Ouray, Colorado. The... via electric mail at rudy.mike@epa.gov and should reference the American Lead and Zinc Mill Site,...

  1. 77 FR 47840 - American Drum and Pallet Company Site; Memphis, Shelby County, Tennessee; Notice of settlement

    Science.gov (United States)

    2012-08-10

    ... AGENCY American Drum and Pallet Company Site; Memphis, Shelby County, Tennessee; Notice of settlement... Agency has entered into a settlement for past response costs concerning the American Drum and Pallet... Drum and Pallet Company Site by one of the following methods: www.epa.gov/region4/superfund/programs...

  2. SITE TECHNOLOGY CAPSULE: INPLANT SYSTEMS, INC. SFC 0.5 OLEOFILTRATION SYSTEM

    Science.gov (United States)

    Oleofiltration is used to separate suspended, emulsified and a portion of dissolved hydrocarbons from water. The InPlant Systems, Inc., SFC 0.5 Oleofiltration System was demonstrated under the SITE Program in June 1994 at a Superfund site in Florida that was contaminated with 29,...

  3. Sustainable exposure prevention through innovative detection and remediation technologies from the NIEHS Superfund Research Program.

    Science.gov (United States)

    Henry, Heather F; Suk, William A

    2017-03-01

    Innovative devices and tools for exposure assessment and remediation play an integral role in preventing exposure to hazardous substances. New solutions for detecting and remediating organic, inorganic, and mixtures of contaminants can improve public health as a means of primary prevention. Using a public health prevention model, detection and remediation technologies contribute to primary prevention as tools to identify areas of high risk (e.g. contamination hotspots), to recognize hazards (bioassay tests), and to prevent exposure through contaminant cleanups. Primary prevention success is ultimately governed by the widespread acceptance of the prevention tool. And, in like fashion, detection and remediation technologies must convey technical and sustainability advantages to be adopted for use. Hence, sustainability - economic, environmental, and societal - drives innovation in detection and remediation technology. The National Institute of Health (NIH) National Institute of Environmental Health Sciences (NIEHS) Superfund Research Program (SRP) is mandated to advance innovative detection, remediation, and toxicity screening technology development through grants to universities and small businesses. SRP recognizes the importance of fast, accurate, robust, and advanced detection technologies that allow for portable real-time, on-site characterization, monitoring, and assessment of contaminant concentration and/or toxicity. Advances in non-targeted screening, biological-based assays, passive sampling devices (PSDs), sophisticated modeling approaches, and precision-based analytical tools are making it easier to quickly identify hazardous "hotspots" and, therefore, prevent exposures. Innovation in sustainable remediation uses a variety of approaches: in situ remediation; harnessing the natural catalytic properties of biological processes (such as bioremediation and phytotechnologies); and application of novel materials science (such as nanotechnology, advanced

  4. A multi-attribute methodology for the prioritisation of oil contaminated sites in the Niger Delta.

    Science.gov (United States)

    Sam, Kabari; Coulon, Frédéric; Prpich, George

    2017-02-01

    The Ogoniland region of the Niger Delta contains a vast number of sites contaminated with petroleum hydrocarbons that originated from Nigeria's active oil sector. The United Nations Environment Programme (UNEP) reported on this widespread contamination in 2011, however, wide-scale action to clean-up these sites has yet to be initiated. A challenge for decision makers responsible for the clean-up of these sites has been the prioritisation of sites to enable appropriate allocation of scarce resources. In this study, a risk-based multi-criteria decision analysis framework was used to prioritise high-risk sites contaminated with petroleum hydrocarbons in the Ogoniland region of Nigeria. The prioritisation method used a set of risk-based attributes that took into account chemical and ecological impacts, as well as socio-economic impacts, providing a holistic assessment of the risk. Data for the analysis was taken from the UNEP Environmental Assessment of Ogoniland, where over 110 communities were assessed for oil-contamination. Results from our prioritisation show that the highest-ranking sites were not necessarily the sites with the highest observed level of hydrocarbon contamination. This differentiation was due to our use of proximity as a surrogate measure for likelihood of exposure. Composite measures of risk provide a more robust assessment, and can enrich discussions about risk management and the allocation of resources for the clean-up of affected sites.

  5. SUPERFUND TREATABILITY CLEARINGHOUSE: CERCLA BDAT SARM PREPARATION AND RESULTS OF PHYSICAL SOILS WASHING EXPERIMENTS (FINAL REPORT)

    Science.gov (United States)

    This study reports on the results of work preparing 30,000 Ibs of SARM or synthetic analytical reference matrix, a surrogate Superfund soil containing a vide range of contaminants. It also reports the results ©f bench scale treatability experiments designed to simulate the EP...

  6. Site Support Program Plan Infrastructure Program

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    1995-09-26

    The Fiscal Year 1996 Infrastructure Program Site Support Program Plan addresses the mission objectives, workscope, work breakdown structures (WBS), management approach, and resource requirements for the Infrastructure Program. Attached to the plan are appendices that provide more detailed information associated with scope definition. The Hanford Site`s infrastructure has served the Site for nearly 50 years during defense materials production. Now with the challenges of the new environmental cleanup mission, Hanford`s infrastructure must meet current and future mission needs in a constrained budget environment, while complying with more stringent environmental, safety, and health regulations. The infrastructure requires upgrading, streamlining, and enhancement in order to successfully support the site mission of cleaning up the Site, research and development, and economic transition.

  7. Site Support Program Plan Infrastructure Program

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    1995-09-26

    The Fiscal Year 1996 Infrastructure Program Site Support Program Plan addresses the mission objectives, workscope, work breakdown structures (WBS), management approach, and resource requirements for the Infrastructure Program. Attached to the plan are appendices that provide more detailed information associated with scope definition. The Hanford Site`s infrastructure has served the Site for nearly 50 years during defense materials production. Now with the challenges of the new environmental cleanup mission, Hanford`s infrastructure must meet current and future mission needs in a constrained budget environment, while complying with more stringent environmental, safety, and health regulations. The infrastructure requires upgrading, streamlining, and enhancement in order to successfully support the site mission of cleaning up the Site, research and development, and economic transition.

  8. The Environmental Protection Agency's program to close and clean up hazardous waste land disposal facilities. Hearing before the Environment, Energy, and Natural Resources Subcommittee of the Committee on Government Operations, House of Representatives, One Hundred Second Congress, Second Session, May 28, 1992

    Energy Technology Data Exchange (ETDEWEB)

    1993-01-01

    This hearing concerns the slow pace of EPA's actions to close and clean up most of the US hazardous waste land disposal facilities. Statements made personally to the subcommittee include Don R. Clay, Solid Waste and Emergency Response, EPA; Richard L. Hembra, Environmental Issues, Resources, Community, and Economic Development Division of the US General Accounting Office; Harold F. Reheis, Environmental Protection Division, Georgia Department of Natural Resources; Hon. Mike Synar, Chairman of the Subcommittee. Submitted for the record were 4 prepared documents from Don R. Clay, Richard L. Hembra; Sylvia Lowrance, Office of Solid Waste, EPA; Harold F. Reheis.

  9. A review on the clean-up, determination, toxicity and biodetoxification of deoxynivalenol and zearalenone from cereals%谷物中DON、ZEA毒素的净化、检测、毒性与生物脱毒技术的研究

    Institute of Scientific and Technical Information of China (English)

    吴丽; 王步军

    2014-01-01

    Fusarium graminearum colonizes cereals and produces toxic secondary metabolites, such as trichothecenes [deoxynivalenol (DON), nivalenol (NIV)] and zearalenone(ZEA). Mycotoxins contamination of cereal grains and cereal-based products is a major problem in agricultural grains production. Clean-up is necessary step for determining the mycotoxins extracted by solid-liquid extraction. There are kinds of clean-up methods applied to purify Fusarium toxins, including solid phase extraction (SPE) columns, such as specific immunoaffinity clean-up columns and mycosep multifunctional columns, as well as the cheap and effective QuEChERS-base method for cleaning-up complex samples. The determination of foods and feeds contaminated by mycotoxins, toxin-producing conditions, toxicity and biological detoxification of Fusarium graminearum toxins were also reviewed in this paper. It is crucial to develop and explore a safe, efficient and cost effective biological detoxification technology, with the purpose of supplying safety and high quality ce-reals and foods.%禾谷镰刀菌在侵染谷物过程中所产生的次生代谢产物——单端孢霉烯族毒素[脱氧雪腐镰刀菌烯醇(deoxynivalenol, DON)、雪腐镰刀菌烯醇(nivalenol, NIV)]以及玉米赤霉烯酮(zearalenone, ZEA)是世界上粮食安全的一个重大问题。毒素经固液萃取技术提取后,需要通过净化处理才能进行检测与分析。目前有多种净化技术用于毒素的净化,如免疫亲和柱、多功能净化柱等固相萃取柱等,以及广泛使用且简便经济的QuEChERS前处理技术。本文还介绍了禾谷镰刀菌毒素中DON、ZEA的检测方法、产毒条件、毒性以及生物脱毒技术等方面的研究进展,旨在开发与应用更安全、高效、经济的生物脱毒技术进行毒素的防御与去除,以提供安全、优质的粮食与食品。

  10. The glass bead game: nuclear tourism at the Australian weapon test sites.

    Science.gov (United States)

    Roff, S R

    1998-01-01

    In mid-summer 1997, just as the United States National Cancer Institute was acknowledging that the nuclear bomb tests at the Nevada Test Site may ultimately cause up to 75,000 cases of thyroid cancer in people who were living in the USA in the 1950s and 1960s, the Australian authorities were mooting the possibility that the Maralinga test sites in South Australia should become a tourist attraction. Some Aboriginal tribal leaders welcomed this proposed use when the 20 million Pounds 'clean-up' being paid for by the United Kingdom government as some compensation for using the area for its weapons tests in the 1950s and 1960s is completed. This paper surveys the attempts to clean up the site of UK nuclear weapons tests in the 1950s, not least by attempting to vitrify vast tracts of desert.

  11. Mercury Exposure in Piscivorous Birds at the Carson River (NV) Superfund Site, 1997-2006

    Data.gov (United States)

    U.S. Geological Survey, Department of the Interior — The persistence and degree of mercury contamination of the lower Carson River system (LCRS) have led to placement of a portion of the Carson River Basin (including...

  12. 76 FR 1154 - Operating Industries, Inc., Superfund Site, Monterey Park, CA; Notice of Proposed CERCLA...

    Science.gov (United States)

    2011-01-07

    ...., Beren Corporation, Beylik Drilling, Inc., Big Penny Car Wash General Partnership, Bimbo Bakeries USA... Metal Finishing Corp., dba Barron Anodizing, Cackle Fresh Egg Farms, Inc., Califone International, Inc...-interest to Lightolier, Inc., Geo Drilling Fluids, Inc., George O. Ladner, Jr., Trustee, Trepanier...

  13. POLYCHLORINATED BIPHENYLS IN HOUSE DUST AND YARD SOIL NEAR A SUPERFUND SITE. (R825173)

    Science.gov (United States)

    Polychlorinated biphenyls (PCBs) were measured in house dust and yard soil at 34 homes surrounding New Bedford Harbor during dredging of highly contaminated harbor sediments. PCBs can volatilize from sediments and seawater and subsequently deposit on surrounding soil, resulting i...

  14. 78 FR 5801 - Operating Industries, Inc. Superfund Site, Monterey Park, CA; Notice of Proposed CERCLA...

    Science.gov (United States)

    2013-01-28

    ... Corradini Corporation, George J. Peckham, Jr., H.W. Hull & Sons, Inc., Hacienda Car Wash, Inc., Hiro's Transmission, Inc., International Paper Company, International Transportation Service, Inc., John Crane,...

  15. Technical Guidelines on Performing a Sediment Erosion and Deposition Assessment (SEDA) at Superfund Sites

    Science.gov (United States)

    2014-09-01

    A. Shipp, and R. L. Ulery. 1996. Water quality in the Trinity River Basin, Texas , 1992-95. U.S. Geological Survey Circular 1171. Available at...and W. Lick. 1997. Effects of bulk density on sediment erosion rates. Water , Air, and Soil Pollution 99:21-31. Jepsen, R., J. Roberts, and J...sciences, water resources, and environmental sciences for the Army, the Department of Defense, civilian agencies, and our nation’s public good. Find

  16. SITE TECHNOLOGY CAPSULE: FILTER FLOW TECHNOLOGY, INC. - COLLOID POLISHING FILTER METHOD

    Science.gov (United States)

    The Filter Flow Technology, Inc. (FFT) Coloid Polishing Filter Method (CPFM) was demonstrated at the U.S Department of Energy's (DOE) Rock Flats Plant (RFP) as part of the U.S. Environmental Protection Agency's (EPA) Superfund and Innovative Technology Evaluation (SITE) program. ...

  17. EPA SITE DEMONSTRATION OF THE INTERNATIONAL WASTE TECHNOLOGIES/GEO-CON IN SITU STABILIZATION/ SOLIDIFICATION PROCESS

    Science.gov (United States)

    This paper presents an EPA evaluation of the first field demonstration of an in situ stabilization/solidification process for contaminated soil under the EPA Superfund Innovative Technology Evaluation (SITE) program. Demonstration of this process was a joint effort of two vendors...

  18. EPA Contract Laboratory Program Statement of Work for Inorganic Superfund Methods Multi-Media, Multi-Concentration ISM02.2

    Science.gov (United States)

    This document contains analytical methods for the analysis of metals and cyanide in environmental samples. It also contains contractual requirements for laboratories participating in Superfund's Contract Laboratory Program.

  19. EPA Contract Laboratory Program Statement of Work for Inorganic Superfund Methods Multi-Media, Multi-Concentration ISM02.3

    Science.gov (United States)

    This document contains analytical methods for the analysis of metals and cyanide in environmental samples. It also contains contractual requirements for laboratories participating in Superfund's Contract Laboratory Program.

  20. 1999 SITE ENVIRONMENTAL REPORT

    Energy Technology Data Exchange (ETDEWEB)

    ENGEL-COX,J.; ZIMMERMAN,E.; LEE,R.; WILLIAMS,J.; GREEN,T.; PAQUETTE,D.; HOODA,B.; SCARPITTA,S.; GENZER,P.; ET AL

    2000-09-01

    Throughout the scientific community, Brookhaven National Laboratory (BNL) is renowned for its leading-edge research in physics, medicine, chemistry, biology, materials, and the environment. BNL is committed to supporting its world-class scientific research with an internationally recognized environmental protection program. The 1999 Site Environmental Report (SER) summarizes the status of the Laboratory's environmental programs and performance, including the steady progress towards cleaning up the site and fully integrating environmental stewardship into all facets of the Laboratory's mission. BNL is located on 5,265 acres of pine barrens in Suffolk County in the center of Long Island, New York. The Laboratory is situated above a sole source aquifer at the headwaters of the Peconic River; therefore, protecting ground and surface water quality is a special concern. Approximately 3,600 acres of the site are undeveloped and serve as habitat for a wide variety of animals and plants, including one New York State endangered species, the tiger salamander, and two New York State threatened species, the banded sunfish and the stiff goldenrod. Monitoring, preserving, and restoring these ecological resources is a high priority for the Laboratory.

  1. Site Enforcement Tracking System (SETS): PRP listing by site for region 9

    Energy Technology Data Exchange (ETDEWEB)

    1992-04-01

    When expending Superfund monies at a CERCLA (Comprehensive Environmental Response, Compensation and Liability Act) site, EPA must conduct a search to identify parties with potential financial responsibility for remediation of uncontrolled hazardous waste sites. EPA regional Superfund Waste Management Staff issue a notice letter to the potentially responsible party (PRP). Data from the notice letter are used to form the Site Enforcement Tracking System (SETS). The data include PRP name and address, a company contact person, the date the notice was issued, and the related CERCLA site name and identification number. SETS was created to track PRP identification at both NPL (National Priorities List) and non-NPL sites. SETS does not address the range of other administrative duties related to tracking the PRP. The site report is designed to provide PRP information linked by the associated site, which appears according to the state where the site is located. Region 9 includes American Samoa, Arizona, California, Guam, Hawaii, Midway, Nevada, Northern Marianas, Pacific Islands, Trust Territories, and Wake Island.

  2. Union job fight boiling at DOE cleanup sites

    Energy Technology Data Exchange (ETDEWEB)

    Setzer, S.W.

    1993-11-15

    The US DOE is facing a growing jurisdictional dispute over which unions will perform the majority of clean-up work at its facilities. Unions affiliated with the AFL-CIO Metal Trades Council representing operations employees at the sites believe they have a fundamental right to work. Unions in the AFL-CIO's Building and Construction Trades Dept. insist that they have a clear mandate under federal labor law and the Davis-Bacon Act. The issue has heated up in recent weeks at the policy level and is boiling in a contentious dispute at DOE's Fernald site in Ohio.

  3. Using a Consensus Conference to Characterize Regulatory Concerns Regarding Bioremediation of Radionuclides and Heavy Metals in Mixed Waste at DOE Sites

    Energy Technology Data Exchange (ETDEWEB)

    Denise Lach; Stephanie Sanford

    2006-09-01

    A consensus workshop was developed and convened with ten state regulators to characterize concerns regarding emerging bioremediation technology to be used to clean-up radionuclides and heavy metals in mixed wastes at US DOE sites. Two questions were explored: integrated questions: (1) What impact does participation in a consensus workshop have on the knowledge, attitudes, and practices of state regulators regarding bioremediation technology? (2) How effective is a consensus workshop as a strategy for eliciting and articulating regulators’ concerns regarding the use of bioremediation to clean up radionuclides and heavy metals in mixed wastes at U.S. Department of Energy Sites around the county? State regulators met together for five days over two months to learn about bioremediation technology and develop a consensus report of their recommendations regarding state regulatory concerns. In summary we found that panel members: - quickly grasped the science related to bioremediation and were able to effectively interact with scientists working on complicated issues related to the development and implementation of the technology; - are generally accepting of in situ bioremediation, but concerned about costs, implementation (e.g., institutional controls), and long-term effectiveness of the technology; - are concerned equally about technological and implementation issues; and - believed that the consensus workshop approach to learning about bioremediation was appropriate and useful. Finally, regulators wanted decision makers at US DOE to know they are willing to work with DOE regarding innovative approaches to clean-up at their sites, and consider a strong relationship between states and the DOE as critical to any effective clean-up. They do not want perceive themselves to be and do not want others to perceive them as barriers to successful clean-up at their sites.

  4. Cost-Effective, Ultra-Sensitive Groundwater Monitoring for Site Remediation and Management

    Science.gov (United States)

    2015-08-01

    research stage, the IS2 is similar in 12 price to other practices and can be expected to improve in cost-effectiveness if brought to market . 13 1.0...M., & Puls, R. W. (1993). Passive sampling of groundwater monitoring wells without purging: multilevel well chemistry and tracer disappearance...sgrp/GWRep10/start.htm. USEPA. (2004). Cleaning Up the Nation’s Waste Sites: Markets and Technology Trends. Washington, DC. Verreydt, G., Bronders

  5. Direct observation of heavy metal-mineral association from the Clark Fork River Superfund Complex: Implications for metal transport and bioavailability

    Science.gov (United States)

    Hochella, M.F.; Moore, J.N.; Putnis, C.V.; Putnis, A.; Kasama, T.; Eberl, D.D.

    2005-01-01

    Two sets of samples from riverbeds and adjacent floodplains, separated by 80 river kilometers, were collected from the Clark Fork River Superfund Complex, Montana, (the largest Superfund site in the United States), and studied primarily with transmission electron microscopy (TEM) with several supporting techniques to determine heavy metal-mineral association. Seven of the eight samples studied were strongly influenced by material that once resided in mining and smelting dumps and impoundments; this material was transported downstream sometime during the last century and a half from the Butte/Anaconda areas. The eighth sample was from a deeper floodplain level and dates to premining days. The TEM observations afford a direct look, down to the nanometer level, at secondary mineral formation as a result of the breakdown of sulfides and silicates in the acid environment of this massive mine-drainage system. In the shallow, oxic floodplain sediments, heavy metals of concern in this system (As, Cu, Pb, and Zn) are taken up by the formation of sulfates (particularly Pb in jarosite), as well as hydrous metal oxides (As, Cu, Pb, and Zn in and on ferrihydrite, and a possibly new vernadite-like mineral). The oxides are long-lived in these systems, as they were also found in the anoxic riverbeds. Metals are also taken up by the formation of sulfides in sulfate-reducing environments as observed in the formation of nanoclusters of chalcopyrite and sphalerite. In all samples, clays make up between 5 and 20% of the sediment and carry significant amounts of Cu and Zn. The hydrous oxides, secondary sulfides, and clays provide several routes for metal transport downstream over long distances. Besides the potential bioavailability of heavy metals exchanged on and off the hydrous metal oxides and clays, nanometer-sized sulfides may also be highly reactive in the presence of biologic systems. Copyright ?? 2005 Elsevier Ltd.

  6. Comprehensive Environmental Response, Compensation and Liability Act

    Data.gov (United States)

    National Oceanic and Atmospheric Administration, Department of Commerce — The Comprehensive Environmental Response, Compensation, and Liability Act (CERCLA), commonly known as Superfund, provides a federal "superfund" to clean up...

  7. Post-Remediation Biomonitoring of Pesticides in Marine Waters Near the United Heckathorn Site, Richmond, California

    Energy Technology Data Exchange (ETDEWEB)

    Antrim, Liam D.; Kohn, Nancy P.

    2000-09-05

    Marine sediment remediation at the United Heckathorn Superfund Site was completed in April 1997. Water and mussel tissues were sampled in January 1998 from four stations near Lauritzen Canal in Richmond, California, for the first post-remediation monitoring of marine areas near the United Heckathorn Site. Dieldrin and DDT were analyzed in water samples, tissue samples from resident mussels, and tissue samples from transplanted mussels deployed for 4 months. Concentrations of dieldrin and total DDT in water and total DDT in tissue were compared to pre-remediation data available from the California State Mussel Watch program (tissues) and the Ecological Risk Assessment for the United Heckathorn Superfund Site (tissues and water). Biomonitoring results indicated that pesticides were still bioavailable in the water column, and have not been reduced from pre-remediation levels. Annual biomonitoring will continue to assess the effectiveness of remedial actions at the United Heckathorn Site.

  8. HANFORD SITE RIVER CORRIDOR CLEANUP

    Energy Technology Data Exchange (ETDEWEB)

    BAZZELL, K.D.

    2006-02-01

    In 2005, the US Department of Energy (DOE) launched the third generation of closure contracts, including the River Corridor Closure (RCC) Contract at Hanford. Over the past decade, significant progress has been made on cleaning up the river shore that bordes Hanford. However, the most important cleanup challenges lie ahead. In March 2005, DOE awarded the Hanford River Corridor Closure Contract to Washington Closure Hanford (WCH), a limited liability company owned by Washington Group International, Bechtel National and CH2M HILL. It is a single-purpose company whose goal is to safely and efficiently accelerate cleanup in the 544 km{sup 2} Hanford river corridor and reduce or eliminate future obligations to DOE for maintaining long-term stewardship over the site. The RCC Contract is a cost-plus-incentive-fee closure contract, which incentivizes the contractor to reduce cost and accelerate the schedule. At $1.9 billion and seven years, WCH has accelerated cleaning up Hanford's river corridor significantly compared to the $3.2 billion and 10 years originally estimated by the US Army Corps of Engineers. Predictable funding is one of the key features of the new contract, with funding set by contract at $183 million in fiscal year (FY) 2006 and peaking at $387 million in FY2012. Another feature of the contract allows for Washington Closure to perform up to 40% of the value of the contract and subcontract the balance. One of the major challenges in the next few years will be to identify and qualify sufficient subcontractors to meet the goal.

  9. Site Enforcement Tracking System (SETS): PRP listing by site for region 9

    Energy Technology Data Exchange (ETDEWEB)

    1994-05-01

    EPA must conduct a search to identify parties with potential financial responsibility and remediation of uncontrolled hazardous waste sites. EPA regional Superfund Waste Management Staff issue a notice letter to the potentially responsible party (PRP). Data from the notice letter is used to form the Site Enforcement Tracking System (SETS). The data includes PRP name and address, a company contact person, the date the notice was issued, and the related CERCLA site name and identification number. These lists represent EPA's preliminary findings on the identities of potentially responsible parties. The site report is designed to provide PRP information linked by the associated site, which appears according to the state where the site is located. Region 9 includes American Samoa, Arizona, California, Guam, Hawaii, Midway, Nevada, Northern Marianas, Pacific Islands, Trust Territories, and Wake Island.

  10. US EPA record of decision review for landfills: Sanitary landfill (740-G), Savannah River Site

    Energy Technology Data Exchange (ETDEWEB)

    1993-06-01

    This report presents the results of a review of the US Environmental Protection Agency (EPA) Record of Decision System (RODS) database search conducted to identify Superfund landfill sites where a Record of Decision (ROD) has been prepared by EPA, the States or the US Army Corps of Engineers describing the selected remedy at the site. ROD abstracts from the database were reviewed to identify site information including site type, contaminants of concern, components of the selected remedy, and cleanup goals. Only RODs from landfill sites were evaluated so that the results of the analysis can be used to support the remedy selection process for the Sanitary Landfill at the Savannah River Site (SRS).

  11. Chlorine dioxide project allows Stora to clean up, use hardwoods

    Energy Technology Data Exchange (ETDEWEB)

    Butters, G.

    1988-10-01

    Effluent fouling into the Strait of Canso between Nova Scotia mainland and Cape Breton Island has caused Stora Forest Industries Ltd. to develop a $5.6 million solution to its chlorine and acid problems. In 1987, Stora produced about 160,000 tonnes of market pulp where their resource base increasingly consisted of hardwood. The company uses hardwood chips for a growing percentage of its annual pulp production and for its hog fuel boiler, but became faced with having to use more local hardwoods which contributes to the resin problem. Their solution was to construct a 12-tpd chlorine dioxide generator, a process using dry sodium chlorate added to concentrated H/sub 2/SO/sub 4/, The products are chlorine dioxide and highly concentrated sulphuric acid resulting from the elimination of water at the starting point. This will eliminate the acid effluent from the generator and the sulphuric acid will be recycled to the top of the chlorine dioxide generation process. In the new process, ClCO/sub 2/ replaces 70% of the chlorine in the first stage, with 100% substitution a goal. In addition to eliminating the chlorine, other benefits include an increase in pulp production, a nominal increase in pulp strength, lower production costs, and an economic incentive to harvest the area's mixed-wood stands.

  12. Time for the VA to clean up its act

    Directory of Open Access Journals (Sweden)

    Robbins RA

    2015-06-01

    Full Text Available No abstract available. Article truncated after 150 words. One year after a Veterans Affairs (VA scandal was ignited here in Phoenix, the number of veterans on wait lists is 50 percent higher than at the same time last year, according to VA data (1. The VA is also facing a nearly $3 billion budget shortfall. VA Secretary Bob McDonald has asked for “flexibility” to reallocate billions of dollars in clinical funds to cover the shortfall. Since the scandal broke last year, VA providers have increased their workloads, adding 2.7 million more appointments than the previous year. However, the VA has played "games" with patient eligibility for years. When money was plentiful VA administrators would open the doors to patients since the following years' budgets were based on the number of patients seen. However, when money was tight, the doors would be slammed shut leaving many patients in the lurch scrambling to obtain health care elsewhere. Now it appears ...

  13. Modeling Internet-Scale Policies for Cleaning up Malware

    CERN Document Server

    Hofmeyr, Steven; Forrest, Stephanie; Edwards, Benjamin; Stelle, George

    2012-01-01

    An emerging consensus among policy makers is that interventions undertaken by Internet Service Providers are the best way to counter the rising incidence of malware. However, assessing the suitability of countermeasures at this scale is hard. In this paper, we use an agent-based model, called ASIM, to investigate the impact of policy interventions at the Autonomous System level of the Internet. For instance, we find that coordinated intervention by the 0.2%-biggest ASes is more effective than uncoordinated efforts adopted by 30% of all ASes. Furthermore, countermeasures that block malicious transit traffic appear more effective than ones that block outgoing traffic. The model allows us to quantify and compare positive externalities created by different countermeasures. Our results give an initial indication of the types and levels of intervention that are most cost-effective at large scale.

  14. GaAs clean up studied with synchrotron radiation photoemission

    Science.gov (United States)

    Tallarida, Massimo; Adelmann, Christoph; Delabie, Annelies; van Elshocht, Sven; Caymax, Matty; Schmeisser, Dieter

    2012-12-01

    In this contribution we describe the chemical changes at the surface of GaAs upon adsorption of tri-methyl-aluminum (TMA). TMA is used to grow Al2O3 with atomic layer deposition (ALD) usually using H2O as oxygen source. Recently, it was pointed out that the adsorption of TMA on various III-V surfaces reduces the native oxide, allowing the growth of an abrupt III-V/High-K interface with reduced density of defects. Synchrotron radiation photoemission spectroscopy (SR-PES) is a powerful method to characterize surfaces and interfaces of many materials, as it is capable to determine their chemical composition as well as the electronic properties. We performed in-situ SR-PES measurements after exposing a GaAs surface to TMA pulses at about 250°C. Upon using the possibility of tuning the incident photon energy we compared the Ga3d spectra at 41 eV, 71 eV, 91 eV and 121 eV, as well as the As3d at 71 eV and 91 eV. Finally, we show that using SR-PES allows a further understanding of the surface composition, which is usually not accessible with other techniques.

  15. Nano-remediation: tiny particles cleaning up big environmental problems

    DEFF Research Database (Denmark)

    Grieger, Khara; Hjorth, Rune; Rice, Jacelyn;

    2015-01-01

    in clothes and food packaging may be rinsed off during washing, and for many ENMs it remains unclear whether current wastewater treatment systems can filter them out before releasing water back into the environment. Overall, this thematic group will focus on the potential impacts of ENMs in the environment...

  16. 75 FR 62923 - WRC-07 Table Clean-up Order

    Science.gov (United States)

    2010-10-13

    ... Table Frequency Nomenclature 1. In Radio Regulation No. 2.1 of the 2008 Edition of the ITU Radio Regulations, frequencies are expressed in kilohertz (kHz) up to and including ``3 000'' kHz (i.e., 3,000 kHz... limited to emission type 2K80J3E and as specified in Sec. 90.266. Also, although 20 frequencies...

  17. Comparison of extraction and clean-up techniques for the ...

    African Journals Online (AJOL)

    user

    cyclohexane, 2- propanol, methanol, acetonitrile and dichloromethane, were tested to select the most suitable solvent for ... carbon dioxide, hydrocarbon fragments are generated which can ... soxhlet) (Lopez-Avila et al., 1993) supercritical fluid extraction ... that it can produce good results within a short time with minimum ...

  18. Bioenergy residues as novel sorbents to clean up pesticide pollution

    Science.gov (United States)

    Mukherjee, Santanu

    2016-04-01

    Worldwide, water contamination from agricultural use of pesticides has received increasing attention within the last decades. In general, sources of pesticide water pollution are categorized into diffuse (stemming from treated fields) and point sources (stemming from farmyards and spillages). Research has demonstrated that 40 to 90% of surface water pesticide contamination is due to point source pollution. To reduce point pollution from farm yards, where the spray equipment is washed, biobed or biofilter systems are used to treat the washing water. The organic material usually used in these systems is often not environmentally sustainable (e.g. peat) and incorporated organic material such as straw leads to a highly heterogeneous water flow, with negative effects on the retention and degradation behavior of the pesticides. Therefore, the objective of this study was to assess the suitability of alternative materials based on bioenergy residues (biochar and digestate) for use in biofilters. To this aim the sorption-desorption potential of three contrasting pesticides (bentazone, boscalid, and pyrimethanil) on mixtures of soil with digestate and/or biochar were investigated in laboratory batch equilibrium experiments. The results indicate that the mixture of digestate and biochar increased pesticide sorption potential, whereby in all cases, the Kd des / Kf des values were lower than the Kd ads / Kf ads values indicating that the retention of the pesticides was weak. Thus, as Kf des were lower than the Kf ads values and H values were below 1, it can be concluded that the biomixtures presented negative desorption (higher hysteresis) in those cases. A higher Kd (>78 L kg-1), Kf (>400 μM1-1/nf L1/nfkg-1) and KL (>40 L kg-1) was obtained for all pesticides for the digestate and biochar based mixtures, which had a higher organic matter content. However, lower sorption of the pesticides was observed in blank soil compared to the other biomixtures, which was attributed to the lower organic carbon content of the blank soil. Our results showed that boscalid and pyrimethanil are highly sorbed to the mixture of digestate and biochar. SUVA254 values justified the aromatic character of digestate (5%) and biochar (5%) mixture which showed highest Koc values among all mixtures for all pesticides. This mixture was found to be the most promising substrate amongst the tested ones for a biobed setup and can be used as an effective and alternative adsorbent for removing pesticides, because of its higher adsorption capacity.

  19. Recent developments in novel sorbents for flue gas clean up

    Energy Technology Data Exchange (ETDEWEB)

    Liu, Yan; Bisson, Teresa M.; Yang, Hongqun; Xu, Zhenghe [Department of Chemical and Materials Engineering, University of Alberta, Edmonton, Alberta (Canada)

    2010-10-15

    Coal combustion is one of the most important energy sources for electricity generation, but also produces airborne pollutants. The amount of SO{sub 2} and NO{sub x} for example, is in the order of hundreds to thousands of ppm, and tens to hundreds of ppm, respectively, while Hg in flue gases could be up to tens to hundreds of ppb. Flue gas desulphurization technology is already in place for SO{sub 2} removal, and new sorbents such as zeolites are being investigated for such an application. NO{sub x} can be removed by selective catalytic reduction with various catalysts. Mercury is the hardest to remove due to its persistent nature and relatively low concentration in flue gases. New sorbents have also been developed for mercury removal applications. A current trend in flue gas emission control is to remove Hg, NO{sub x} and SO{sub 2} simultaneously. Various catalytic sorbents have been investigated to remove two or more of these pollutants concurrently. This article reviews recent developments made for emission control of coal-fired power plant flue gases using novel sorbents to target individual or multiple pollutants. (author)

  20. Novel Sorbent to Clean Up Biogas for CHPs

    Energy Technology Data Exchange (ETDEWEB)

    Alptekin, Gökhan O. [TDA Research, Incorporated, Wheat Ridge, CO (United States); Jayataman, Ambalavanan [TDA Research, Incorporated, Wheat Ridge, CO (United States); Schaefer, Matthew [TDA Research, Incorporated, Wheat Ridge, CO (United States); Ware, Michael [TDA Research, Incorporated, Wheat Ridge, CO (United States); Hunt, Jennifer [FuelCell Energy, Inc., Danbury, CT (United States); Dobek, Frank [FuelCell Energy, Inc., Danbury, CT (United States)

    2015-05-30

    In this project, TDA Research Inc. (TDA) has developed low-cost (on a per unit volume of gas processed basis), high-capacity expendable sorbents that can remove both the H2S and organic sulfur species in biogas to the ppb levels. The proposed sorbents will operate downstream of a bulk desulfurization system as a polishing bed to provide an essentially sulfur-free gas to a fuel cell (or any other application that needs a completely sulfur-free feed). Our sorbents use a highly dispersed mixed metal oxides active phase with desired modifiers prepared over on a mesoporous support. The support structure allows the large organic sulfur compounds (such as the diethyl sulfide and dipropyl sulfide phases with a large kinetic diameter) to enter the sorbent pores so that they can be adsorbed and removed from the gas stream.

  1. Hot gas clean-up with ceramic filter elements

    Energy Technology Data Exchange (ETDEWEB)

    Christ, A.; Gross, R.; Renz, U. [Rheinisch-Westfaelische Technische Hochschule, Aachen (Germany). Lehrstuhl fuer Waermeuebertragung und Klimatechnik

    1998-12-31

    Hot gas cleanup is necessary during the combined cycle combustion of coal, ceramic filters are frequently used for filtration. Pressure and velocity measurements inside the filter elements during pulse cleaning of a single ceramic candle filter element were carried out. The experimental set-up is described and the results for filter element cleaning at {var_theta} = 25,500 and 900{degree}C and cleaning pressures of P{sub B} = 1.4, 1.9 and 2.8 bar are presented and discussed. Numerical simulations of filter element cleaning for the experimental conditions are presented and discussed as well. Regarding the good agreement of experimental results with numerical predictions it is proven that numerical simulations of the back-pulse cleaning should be employed as design tool for filter cleaning systems. 32 figs., 2 tabs.

  2. Cleaning up That Mess: A Framework for Classifying Educational Apps

    Science.gov (United States)

    Cherner, Todd; Dix , Judy; Lee, Corey

    2014-01-01

    As tablet technologies continue to evolve, the emergence of educational applications (apps) is impacting the work of teacher educators. Beyond online lists of best apps for education and recommendations from colleagues, teacher educators have few resources available to support their teaching of how to select educational apps. In response, this…

  3. News from Online: Cleaning Up--Soap, Detergent, and More.

    Science.gov (United States)

    Judd, Carolyn Sweeney

    2002-01-01

    Provides a guide to web resources on cleaning and hygiene. Answers the questions, What do you want to clean--your hair? your carpet? your rusty lawn furniture? Develops special products for different tasks. Focuses on products to use and the environmental impact of our choices. (MM)

  4. The 7% Solution - Cleaning Up After Fred Vine's Outstanding Successes

    Science.gov (United States)

    Hey, R. N.

    2013-12-01

    Fred Vine was the first & greatest of the wiggle pickers, founding the marine magnetic anomaly field with his 1963 Vine & Matthews paper. Two of his classic study areas were Juan de Fuca & the Reykjanes Ridge. In Juan de Fuca, he recognized the axial symmetry in the Raff & Mason data that had shown the existence of magnetic stripes on the seafloor, demonstrating the seafloor spreading there that Tuzo Wilson had predicted. Fred's iconic color figure of these anomalies perfectly correlated with the magnetic reversal time scale (after the discovery of the Jaramillo event) became the striking cover illustration of 'The History of the Earth's Crust', the symposium volume of the influential 1966 Goddard meeting that confirmed the reality of seafloor spreading & continental drift. Everything Fred did in Juan de Fuca was correct, but fortunately for me he didn't do everything. Some of the linear magnetic anomaly offsets there became a major puzzle in 1967 when Jason Morgan & Dan McKenzie discovered plate tectonics, because those offsets were oblique to the ridges & transforms & thus were incompatible with simple plate tectonics. Although the oblique anomaly offsets look like faults, they instead turned out to be propagating rift pseudofault wakes with no relative motion along them, an interpretation resulting from my analysis of Galapagos magnetic anomalies. Fred's other iconic color figure was his correlation of the Heirtzler et al. Reykjanes Ridge aeromagnetic data with the reversal timescale. This figure, showing the symmetry predicted by seafloor spreading & field reversals, was another key step in the scientific revolution. At the Goddard Symposium Fred was asked if he'd tested the symmetry statistically & he replied "I never touch statistics. I just deal with the facts'. Fred was trying to have a scientific revolution, & of course on that scale pretty symmetric seafloor spreading is a reality. However, fine-scale asymmetric spreading can be seen in his figure (the asymmetry increases towards Iceland where we had the great advantage of working), & contrary to conventional wisdom the V-shaped ridges, scarps & troughs (VSRs) discovered by Peter Vogt are not symmetric about the Reykjanes Ridge axis. Analysis of magnetic anomaly data from our 2007 expedition by Benediktsdóttir et al. shows these asymmetries were created by rift propagation both away from & towards Iceland, suggesting a tectonic alternative to the magmatic pulsing plume explanation for the VSRs. These results further suggest that the massive transform-eliminating North Atlantic plate boundary reorganization that created the linear obliquely-spreading Reykjanes Ridge might also be a propagating rift phenomenon instead of a thermal phenomenon as generally assumed, & we hope to present results from a new Reykjanes Ridge expedition later this summer designed to determine exactly how this reorganization is occurring. That so much research for several decades has resulted from the small (the 7% number in the title is made up - inspired by Fred I never did learn statistics) modification of Fred's results is a tribute to the overwhelming success of seafloor spreading & plate tectonics. Unfortunately for Vine, Morgan & McKenzie, this scientific revolution appears to have been too profound for Nobel Prizes.

  5. Wet-air oxidation cleans up black wastewater

    Energy Technology Data Exchange (ETDEWEB)

    1993-09-01

    Sterling Organics produces the analgesic paracetamol (acetaminophen) at its Dudley, England, plant. The wastewater from the batch process contains intermediates such as para-aminophenol (PAP) and byproducts such as thiosulfates, sulfites and sulfides. To stay ahead of increasingly strict environmental legislation, Sterling Organics installed a wet-air oxidation system at the Dudley facility in August 1992. The system is made by Zimpro Environmental Inc. (Rothschild, Wis.). Zimpro's wet-air oxidation system finds a way around the limitations of purely chemical or physical processes. In the process, compressed air at elevated temperature and pressure oxidizes the process intermediates and byproducts and removes the color from the wastewater.

  6. Nano-remediation: tiny particles cleaning up big environmental problems

    DEFF Research Database (Denmark)

    Grieger, Khara; Hjorth, Rune; Rice, Jacelyn

    2015-01-01

    Over the past decade, there has been an increased use of engineered nanomaterials (ENMs) in everything from consumer products to industrial manufacturing. Nanomaterials are substances which are less than 100 nanometres in size (a nanometre is one billionth of a metre). Although natural nanomateri......Over the past decade, there has been an increased use of engineered nanomaterials (ENMs) in everything from consumer products to industrial manufacturing. Nanomaterials are substances which are less than 100 nanometres in size (a nanometre is one billionth of a metre). Although natural...... nanomaterials exist, engineered nanomaterials are being designed with very specific properties, and the impacts to humans and ecosystem health are largely unknown. With the normal production, use, and disposal of these products, it is very likely that many ENMs will end up in the environment. ENMs contained...... in clothes and food packaging may be rinsed off during washing, and for many ENMs it remains unclear whether current wastewater treatment systems can filter them out before releasing water back into the environment. Overall, this thematic group will focus on the potential impacts of ENMs in the environment...

  7. Cleaning up That Mess: A Framework for Classifying Educational Apps

    Science.gov (United States)

    Cherner, Todd; Dix , Judy; Lee, Corey

    2014-01-01

    As tablet technologies continue to evolve, the emergence of educational applications (apps) is impacting the work of teacher educators. Beyond online lists of best apps for education and recommendations from colleagues, teacher educators have few resources available to support their teaching of how to select educational apps. In response, this…

  8. Growing Up and Cleaning Up: The Environmental Kuznets Curve Redux.

    Science.gov (United States)

    Franklin, Rachel S; Ruth, Matthias

    2012-01-01

    Borrowing from the Kuznets curve literature, researchers have coined the term "environmental Kuznets curve" or EKC to characterize the relationship between pollution levels and income: pollution levels will increase with income but some threshold of income will eventually be reached, beyond which pollution levels will decrease. The link between the original Kuznets curve, which posited a similar relationship between income and inequality, and its pollution-concerned offspring lies primarily with the shape of both curves (an upside-down U) and the central role played by income change. Although the EKC literature has burgeoned over the past several years, few concrete conclusions have been drawn, the main themes of the literature have remained constant, and no consensus has been reached regarding the existence of an environmental Kuznets curve. EKC research has used a variety of types of data and a range of geographical units to examine the effects of income levels on pollution. Changes in pollution levels might also be at least partly explained by countries' position in the demographic transition and their general population structure, however little research has included this important aspect in the analysis. In addition, few analyses confine themselves to an evaluation for one country of the long-term relationship between income and pollution. Using United States CO2 emissions as well as demographic, employment, trade and energy price data, this paper seeks to highlight the potential impact of population and economic structure in explaining the relationship between income and pollution levels.

  9. Cleaning up and standardizing a folktale corpus for humanities research

    NARCIS (Netherlands)

    Muiser, Iwe Everhardus Christiaan; Theune, Mariët; Meder, Theo; Mambrini, F.; Passarotti, M.; Sporleder, C.

    2012-01-01

    Recordings in the field of folk narrative have been made around the world for many decades. By digitizing and annotating these texts, they are frozen in time and are better suited for searching, sorting and performing research on. This paper describes the first steps of the process of standardizatio

  10. Pipeline clean-up : speed, environment drive pipelining equipment

    Energy Technology Data Exchange (ETDEWEB)

    Budd, G.

    2004-08-01

    Horizontal drilling technology is the single most important enhanced oil recovery technology which has resulted in a significant increase in pipeline utilization. Pipeline operators such as Calgary-based Denim Pipeline Construction Ltd. are responding by using the latest equipment, including excavation equipment, to avoid maintenance delays and downtime. The sales of Denim's horizontal pipe bending equipment have increased due to their attention to worker safety. Denim's horizontal bending machine does not require as much technical support, plus it is faster to install and speeds up production. The machine consists of 3 hydraulic jacks that move on a horizontal plate. Curved dies can be modified to accommodate various diameters of pipe. The bending operation is performed very near to the ground, thereby significantly reducing the risk of pipe injury. Environmental damage is minimized through the use of mechanized mulching which has replaced burning of unwanted trees and brush to clean for pipelines. 1 fig.

  11. Mobile laboratories: An innovative and efficient solution for radiological characterization of sites under or after decommissioning.

    Science.gov (United States)

    Goudeau, V; Daniel, B; Dubot, D

    2017-04-21

    During the operation and the decommissioning of a nuclear site the operator must assure the protection of the workers and the environment. It must furthermore identify and classify the various wastes, while optimizing the associated costs. At all stages of the decommissioning radiological measurements are performed to determine the initial situation, to monitor the demolition and clean-up, and to verify the final situation. Radiochemical analysis is crucial for the radiological evaluation process to optimize the clean-up operations and to the respect limits defined with the authorities. Even though these types of analysis are omnipresent in activities such as the exploitation, the monitoring, and the cleaning up of nuclear plants, some nuclear sites do not have their own radiochemical analysis laboratory. Mobile facilities can overcome this lack when nuclear facilities are dismantled, when contaminated sites are cleaned-up, or in a post-accident situation. The current operations for the characterization of radiological soils of CEA nuclear facilities, lead to a large increase of radiochemical analysis. To manage this high throughput of samples in a timely manner, the CEA has developed a new mobile laboratory for the clean-up of its soils, called SMaRT (Shelter for Monitoring and nucleAR chemisTry). This laboratory is dedicated to the preparation and the radiochemical analysis (alpha, beta, and gamma) of potentially contaminated samples. In this framework, CEA and Eichrom laboratories has signed a partnership agreement to extend the analytical capacities and bring on site optimized and validated methods for different problematic. Gamma-emitting radionuclides can usually be measured in situ as little or no sample preparation is required. Alpha and beta-emitting radionuclides are a different matter. Analytical chemistry laboratory facilities are required. Mobile and transportable laboratories equipped with the necessary tools can provide all that is needed. The main

  12. 权利博弈:国民政府省内机关的公产清理冲突与协调%Game of Power:Conflict and Coordination in the Cleaning up of Public Property within Departments of KMT Government at Provincial Level

    Institute of Scientific and Technical Information of China (English)

    冯兵

    2015-01-01

    After founding of KMT government, society and governments at all levels reconstructed the function of leadership and replaced the revolutionary politics to be dominant. The gradual development of economic construction, national education, health care, and social security was in extreme need of money. Financial reform, therefore, became an important channel for local governments to raise funds. Cleaning up public property left over by the predecessors as a part of the full-scale reforms was very much emphasized. The policies of cleaning up of public property were the authoritarian social value distribution plan, but as they were confined to interest reallocation and adjustment and restriction or change of personnel, the implementation of the policies were very complicated processes. Affected by many interest groups, pressure, tension, and conflict were common in implementation. As the cleaning-up work was carried out, the contradictions arising from public property management became increasingly obvious. The administrative offices at provincial level competed and fought against one another, the administrative offices against military offices, province-level offices against city-level offices; province-level against county-level units, all for the property management. They were all involved in a game of power by using equal power, rights and interests.%国民政府建立后,各级政府社会重构领导职能取代革命政治而成主导,经济建设、国民教育、医疗卫生、社会救济等事业渐次开展需款甚亟,财政改革成为各地政府筹措发展资金重要渠道,前代遗留公产的清理作为全方位财政改革组成部分备受重视,作为权威社会价值分配方案的公产清理政策,囿于其出台表现为利益重新分配与调整,对人事进行制约或改变,政策执行成为极度复杂之过程。受多方利益影响,执行过程压力、紧张与冲突成为常态。随着清理工作开展,围

  13. Environmental Assessment of Remedial Action at the Mexican Hat Uranium Mill Tailings Site, Mexican Hat, Utah

    OpenAIRE

    U.S. Department of Energy

    1987-01-01

    This document assesses the environmental impacts of the proposed remedial action at the Mexican Hat uranium mill tailings site located on the Navajo Reservation in southern Utah. The site covers 235 acres and contains 69 acres of tailings and several of the original mill structures. The Uranium Mill Tailings Radiation Control Act (UMTRCA) of 1978, Public Law 95-604 (PL95-604), authorized the U.S. Department of Energy to clean up the site to reduce the potential health impacts associated wit...

  14. 免疫亲和柱净化-光化学柱后衍生高效液相色谱荧光法测定粮食中黄曲霉毒素%Determination of aflatoxin in cereal by immune-affinity column clean-up and HPLC-FLD with post-column photochemical derivation

    Institute of Scientific and Technical Information of China (English)

    方芳; 张旭; 郑睿行

    2012-01-01

    建立了粮食中黄曲霉毒素B1、B2、G1、G2的免疫亲和柱净化-光化学柱后衍生高效液相色谱荧光检测法.样品经甲醇-水提取,免疫亲和柱净化,高效液相色谱分离,光化学柱后衍生,荧光检测器测定.结果表明,黄曲霉毒素B1、B2、G1、G2的检出限分别为0.50、0.25、0.50、0.25μg/kg,回收率为67.2%~91.7%,RSD小于10%.该方法快速、准确、灵敏度高、重现性好,能满足我国对粮食中黄曲霉毒素限量的检测要求.%A method for determination of aflatoxin B1, B2, G1 and G2 by immune-affinity column clean-up and HPLC with post column photochemical derivation was developed. Samples were extracted with methanol- water solution and cleaned up by immune-affinity columns. Separation of aflatoxins was conducted by HPLC and the determination was carried out by fluorescence detector after photochemical derivatioa The results showed that the limits of detection of aflatoxin B1, B2 , G1 and G2 were 0. 5, 0. 25, 0. 5, 0. 25 μg/kg respectively ,and the recovery rates were from 67. 2% to 91. 7% ,RSD was below 10%. The method is quick, precise,high-sensitive and good-repeatabie,which is suitable for the determination of aflatoxin in cereals in China.

  15. Bioremediation in oil-contaminated sites: bacteria and surfactant accelerated remediation

    Science.gov (United States)

    Strong-Gunderson, Janet M.; Guzman, Francisco

    1996-11-01

    In Mexico, there are several environmental issues which are being addressed under the current governmental legislation. One important issue is restoring sites belonging to Petroleos Mexicanos (PEMEX). PEMEX is a large government owned oil company that regulates and manages the oil reserves. These sites are primarily contaminated with weathered hydrocarbons which are a consequence of extracting millions of barrels of oil. Within the southern regions of Mexico there are sites which were contaminated by activities and spills that have occurred during the past 30 years. PEMEX has taken the leadership in correcting environmental problems and is very concerned about cleaning up the contaminated sites as quickly as possible. The most significant contaminated sites are located to the north of Veracruz and south of Tabasco. These sites areas are close to refineries or locations of oil exploration. The primary category of contaminants are hydrocarbons, among them asphaltens, aromatic and other contaminants. The concentration of the contaminants varies depending on the location of the sites, but it can reach as high as 500,000 ppm. PEMEX has been searching for appropriate, and cost- effective technologies to clean up these sites. Biologically based remediation activities are of primary interest to PEMEX. However, other treatment technologies such as chemical-physical methods, encapsulation and incineration are also being considered. The present report summarizes preliminary experiments that measured the feasibility of bioremediation for a contaminated site in southern Mexico.

  16. Corrective Action Plan for Corrective Action Unit 214: Bunkers and Storage Areas, Nevada Test Site, Nevada - Revision 0 - March 2005

    Energy Technology Data Exchange (ETDEWEB)

    U.S. Department of Energy, National Nuclear Security Administration, Nevada Site Office; Bechtel Nevada

    2005-03-01

    Corrective Action Unit 214, Bunkers and Storage Areas, is identified in the Federal Facility Agreement and Consent Order of 1996. Corrective Action Unit 214 consists of nine Corrective Action Sites located in Areas 5, 11, and 25 of the Nevada Test Site. The Nevada Test Site is located approximately 105 kilometers (65 miles) northwest of Las Vegas, Nevada, in Nye County. Corrective Action Unit 214 was previously characterized in 2004, and results were presented in the Corrective Action Decision Document for 214. Site characterization indicated that soil and/or debris exceeded clean-up criteria for Total Petroleum Hydrocarbons, pesticides, metals, and radiological contamination.

  17. Congressional Testimony: Statement of Wade T. Najjum Before the Subcommittee on Superfund and Environmental Health Committee on Environment and Public Works United States Senate

    Science.gov (United States)

    Statement of Wade T. Najjum Assistant Inspector General for Program Evaluation U.S. EPA Office of Inspector General Before the Subcommittee on Superfund and Environmental Health Committee on Environment and Public Works United States Senate

  18. 凝胶渗透色谱净化烟叶有机磷、拟除虫菊酯类农药残留的研究%Study on GPC Clean-up of Residues of organophosphorous Pesticides and Synthetic Pyrethroid Pesticides in Tobacco Leaf

    Institute of Scientific and Technical Information of China (English)

    方敦煌; 师君丽; 宋春满

    2011-01-01

    为确定凝胶渗透色谱(GPC)净化烟草有机磷和拟除虫菊酯农药残留的最佳收集时间,提高烟草有机磷和拟除虫菊酯农药残留的净化效果和回收率,进行了此项试验.采用添加3个浓度梯度农药标准品进行回收试验的方法,研究了烟叶中9种有机磷农药和7种拟除虫菊酯农药在GPC柱上的流出规律.结果表明,有机磷农药的最佳收集时间为26~68 min,拟除虫菊酯类农药的最佳收集时间为26~42 min.有机磷农药的回收率为80.28%~96.81%,相对标准偏差为4.44%~8.74%,拟除虫菊酯类农药回收率为76.39%~97.95%,相对标准偏差为2.69%~7.58%.GPC净化烟草有机磷和拟除虫菊酯农药残留的最佳收集时间与国家标准GB/T 13595不同,主要是因为农药品种不同而造成的,因此最佳收集时间必须根据具体试验来确定.%In order to determine the optimum collecting time of GPC clean-up organophosphorous and pyrethroid residue in tobacco, and improve of purificatory effect and recoveries of those pesticide residues, the test was in progress. According to recovery tests for 16 organophosphorous and pyrethroid pesticide standard spiked samples with 3 concentration gradients, elution behavior of from a gel permeation chromatography column (GPC) was determined for these pesticides in tobacco leaf. The results showed that the optimum collection time of 9 organophosphorous pesticides from GPC column was 26-68 min and that for 7 pyrethroid pesticides was 26-42 min. The recoveries of organophosphorous pesticides were 80.28%-96.81%, the relative standard deviation were 4.44%-8.74%, the recoveries of pyrethroid pesticides were 76.39%-97.95%, the relative standard deviation were 2.69%-7.58%. The optimum collecting time of GPC clean-up pesticide residue is different from GB/T 13595, so the optimum collecting time must be determined by test.

  19. Status of rehabilitation of the Maralinga and Emu sites

    Energy Technology Data Exchange (ETDEWEB)

    Rawson, R.; Davoren, P.; Perkins, C. [Department of Primary Industries and Energy, Canberra, ACT (Australia)

    1997-12-31

    The $100 million rehabilitation project of the former British nuclear test sites at Maralinga and Emu, South Australia, is progressing with implementation of an option identified by a Technical Assessment Group. The Maralinga Rehabilitation Project was agreed by the Commonwealth and South Australian Governments, and by the Maralinga Tjarutja traditional owners. The Project, which was assisted by an ex gratia payment of 20 million pounds by the British Government, is the largest clean-up of a former nuclear test site, and the first to be undertaken on a commercial basis. The work program is proceeding on time and within budget and is due to be completed in 1998/99. At Maralinga, plutonium-contaminated soil is being removed and buried in trenches at the Taranaki, TM and Wewak sites, with the work due to be completed at the end of 1997. After monitoring and clearance by the Australian Radiation Laboratory, clean soil will be distributed over rehabilitated lots and trenches, and the areas re vegetated. At Taranaki, 21 radioactively contaminated burial pits will be stabilised using in-situ vitrification (ISV), a process which melts contaminated soil by means of large electric currents applied through graphitic electrodes, producing a strong, leach resistant, glass ceramic block. Construction of ISV equipment is in progress, and the vitrification of the pits due to commence in early 1998. The Emu site does not have a significant plutonium contamination hazard, and will be left without rehabilitation. By the end of 1997, boundary markers will be placed around the Taranaki area at Maralinga, to indicate that the area is suitable for transit, but not permanent habitation, by the traditional owners. Boundary markers will also be placed around sites at Emu. Once the clean up is completed, it is intended that control of the site be returned from Commonwealth to the South Australian Government for addition to the freehold lands of Maralinga Tjarutja. 7 refs., 3 figs.

  20. Site technology capsule. Inplant Systems, Inc. SFC 0. 5 oleofiltration system

    Energy Technology Data Exchange (ETDEWEB)

    Whitford, K.

    1994-12-01

    Oleofiltration is used to separate suspended, emulsified and a portion of dissolved hydrocarbons from water. the InPlant Systems, Inc., SFC 0.5 Oleofiltration System was demonstrated under the SITE Program in June 1994 at a Superfund site in Florida that was contaminated with 29,000 gallons of Light Non-Aqueous Phase Liquid (LNAPL) hydrocarbon. More than 90% of the TRPH was removed from the oil/water emulsion during the demonstration. This capsule provides information on the technology applicability, technology limitations, a technology description, process residuals, site requirements, latest performance data, the technology status, and the source of further information.

  1. Mercury Exposure in Piscivorous Birds at the Carson River (NV) Superfund Site, 1997-2006: egg data

    Data.gov (United States)

    U.S. Geological Survey, Department of the Interior — The persistence and degree of mercury contamination of the lower Carson River system (LCRS) have led to placement of a portion of the Carson River Basin (including...

  2. GIS-Mapping and Statistical Analyses to Identify Climate-Vulnerable Communities and Populations Exposed to Superfund Sites

    Science.gov (United States)

    Climate change-related cumulative health risks are expected to be disproportionately greater for overburdened communities, due to differential proximity and exposures to chemical sources and flood zones. Communities and populations vulnerable to climate change-associated impacts ...

  3. GIS-Mapping and Statistical Analyses to Identify Climate-Vulnerable Communities and Populations Exposed to Superfund Sites

    Science.gov (United States)

    Climate change-related cumulative health risks are expected to be disproportionately greater for overburdened communities, due to differential proximity and exposures to chemical sources and flood zones. Communities and populations vulnerable to climate change-associated impacts ...

  4. Negative pH, efflorescent mineralogy, and consequences for environmental restoration at the Iron Mountain Superfund site, California.

    Science.gov (United States)

    Nordstrom, D K; Alpers, C N

    1999-03-30

    The Richmond Mine of the Iron Mountain copper deposit contains some of the most acid mine waters ever reported. Values of pH have been measured as low as -3.6, combined metal concentrations as high as 200 g/liter, and sulfate concentrations as high as 760 g/liter. Copious quantities of soluble metal sulfate salts such as melanterite, chalcanthite, coquimbite, rhomboclase, voltaite, copiapite, and halotrichite have been identified, and some of these are forming from negative-pH mine waters. Geochemical calculations show that, under a mine-plugging remediation scenario, these salts would dissolve and the resultant 600,000-m3 mine pool would have a pH of 1 or less and contain several grams of dissolved metals per liter, much like the current portal effluent water. In the absence of plugging or other at-source control, current weathering rates indicate that the portal effluent will continue for approximately 3, 000 years. Other remedial actions have greatly reduced metal loads into downstream drainages and the Sacramento River, primarily by capturing the major acidic discharges and routing them to a lime neutralization plant. Incorporation of geochemical modeling and mineralogical expertise into the decision-making process for remediation can save time, save money, and reduce the likelihood of deleterious consequences.

  5. U.S. EPA’s Technical Support for the Reich Farm (Toms River, NJ) Superfund Site Remediation

    Science.gov (United States)

    PowerPoint slide file that gives a brief history of the SAN Trimer contamination in Toms River, NJ as well as the EPA's provided technical support, specifically the development and application of the Provisional Peer-Reviewed Toxicity Value (PPRTV) assessment for SAN Trimer.

  6. 76 FR 20287 - Superfund Site, New Bedford Harbor, New Bedford, MA: Anchorage Ground and Regulated Navigation Area

    Science.gov (United States)

    2011-04-12

    ... New Bedford Harbor hurricane barrier in the outer harbor. The pilot cap consists of sand and gravel... revising paragraph (a)(2) to read as follows: Sec. 110.140 Buzzards Bay, Nantucket Sound, and...

  7. Chemical and biological methods for the analysis and remediation of environmental contaminants frequently identified at superfund sites

    Energy Technology Data Exchange (ETDEWEB)

    Melinda Christine Wiles [Texas A& amp; M University, College Station, TX (United States). Department of Veterinary Anatomy & Public Health

    2004-08-15

    Substantial environmental contamination has occurred from coal tar creosote and pentachlorophenol (C5P) in wood preserving solutions. The present studies focused on the characterization and remediation of these contaminants. The first objective was to delineate a sequence of biological changes caused by chlorinated phenol (CP) exposure. The second study was to develop multi-functional sorbents to remediate CPs and other components of wood preserving waste from groundwater. Following water remediation, the final aim of this work was to explore the safety of the parent clay minerals as potential enterosorbents for contaminants ingested in water and food. Based on evaluations of toxicity and neutron activation analysis of tissues, no significant differences were observed between animals receiving clay supplements and control animals, with the exception of slightly decreased brain Rb in animals ingesting clay. Overall, the results suggest that neither clay mineral, at relatively high dietary concentrations, influences mineral uptake or utilization in the pregnant rat. 420 refs., 28 figs, 15 tabs.

  8. 77 FR 46433 - Proposed CERCLA Administrative Cost Recovery Settlements for the Buckbee-Mears Co. Superfund Site...

    Science.gov (United States)

    2012-08-03

    ...; request for public comment. SUMMARY: Under Section 122(h) of the Comprehensive Environmental Response... attributable to the costs of marketing and selling the Properties. Any proceeds from the Bank's foreclosure... proportion to the percentage that the following amounts represent in relation to the combined total of...

  9. 75 FR 76280 - Regulated Navigation Area; Thea Foss and Wheeler-Osgood Waterways EPA Superfund Cleanup Site...

    Science.gov (United States)

    2010-12-08

    ... SECURITY Coast Guard 33 CFR Part 165 RIN 1625-AA11 Regulated Navigation Area; Thea Foss and Wheeler-Osgood... of the Thea Foss and Wheeler-Osgood Waterways in Commencement Bay, Tacoma, Washington. The RNA will... notice of proposed rulemaking (SNPRM) entitled Regulated Navigation Area; Thea Foss and Wheeler-Osgood...

  10. 75 FR 30753 - Regulated Navigation Area; Thea Foss and Wheeler-Osgood Waterways EPA Superfund Cleanup Site...

    Science.gov (United States)

    2010-06-02

    ... SECURITY Coast Guard 33 CFR Part 165 RIN 1625-AA11 Regulated Navigation Area; Thea Foss and Wheeler-Osgood... and Wheeler-Osgood Waterways in Commencement Bay, Tacoma, Washington. The RNA would protect the seabed... rulemaking (NPRM) entitled ``Regulated Navigation Area; Thea Foss and Wheeler-Osgood Waterways EPA...

  11. SAVANNAH RIVER SITE ENVIRONMENTAL REPORT FOR 2010

    Energy Technology Data Exchange (ETDEWEB)

    Mamatey, A.; Dunaway-Ackerman, J.

    2011-08-16

    This report was prepared in accordance with U.S. Department of Energy (DOE) Order 231.1A, 'Environment, Safety and Health Reporting,' to present summary environmental data for the purpose of: (a) characterizing site's environmental management performance; (b) summarizing environmental occurrences and responses reported during the calendar year; (c) describing compliance status with respect to environmental standards and requirements; and (d) highlighting significant site programs and efforts. This report is the principal document that demonstrates compliance with the requirements of DOE Order 5400.5, 'Radiation Protection of the Public and the Environment,' and is a key component of DOE's effort to keep the public informed of environmental conditions at Savannah River Site (SRS). SRS has four primary missions: (1) Environmental Management - Cleaning up the legacy of the Cold War efforts and preparing decommissioned facilities and areas for long-term stewardship; (2) Nuclear Weapons Stockpile Support - Meeting the needs of the U.S. nuclear weapons stockpile through the tritium programs of the National Nuclear Security Administration (NNSA); (3) Nuclear Nonproliferation Support - Meeting the needs of the NNSA's nuclear nonproliferation programs by safely storing and dispositioning excess special nuclear materials; and (4) Research and Development - Supporting the application of science by the Savannah River National Laboratory (SRNL) to meet the needs of SRS, the DOE complex, and other federal agencies During 2010, SRS worked to fulfill these missions and position the site for future operations. SRS continued to work with the South Carolina Department of Health and Environmental Control (SCDHEC), the Environmental Protection Agency (EPA), and the Nuclear Regulatory Commission to find and implement solutions and schedules for waste management and disposition. As part of its mission to clean up the Cold War legacy, SRS will continue

  12. Phase 1 Environmental Baseline Survey for the Leasing of Nevada Test and Training Range, EC-South Range, Well Site ER-EC-11, for the Underground Test Area Pahute Mesa Phase 2 Drilling and Testing Program Nye County, Nevada

    Science.gov (United States)

    2009-05-01

    radioactive sites. The FFACO serves as the fundamental clean-up agreement for the execution of the NNSA/NSO Environmental Restoration Project (ERP...m (1,477 ft). Groundwater chemistry at the subject property and adjacent NTS ranges from a sodium-potassium-bicarbonate type to a calcium-magnesium...ID: 110007979697 PONOERQSA DAIRY ICP: NVA000041 I n!a n!a TOWNSHIP 17 S RANGE 49 E SECTION 9, 10& 15 [ AMARGOSA VAl. LEY. NV 89020 ICP

  13. Investigation on Detection of Aflatoxins in Chinese Materia Medica and Pharmaceutical Intermediates Microbiological Contaminated by Immunoaffinity Column Clean-up Combined with Post-column Derivatization%免疫亲和柱净化HPLC柱后光化学衍生化法检测中药及染菌中药制剂中间体的黄曲霉毒素

    Institute of Scientific and Technical Information of China (English)

    胡一晨; 万丽; 范成杰; 吕维; 杨芳; 吉琅

    2012-01-01

    Objective; To establish a method to determine aflatoxins B,, B2, G1, G2 in Chinese Materia Medica and pharmaceutical intermediates microbiological contaminated by immunoaffinity column clean-up combined with post-column derivatization and HPLC-FD detection. Method: Using immunoaffinity column cleanup combined with post-column derivatization, the analytical method to detect aflatoxins B1 , B2, G,, G2 was established firstly, and then 14 kind of Chinese Materia Medica and pharmaceutical intermediates microbiological contaminated was detected respectively. Result: The method with the great linear concentration range of 0. 15-6.0 ng-mL-1 for aflatoxins G2, B2, and 0.5-20.0 ug·L-1'for G,, B, respectively, was stable and accurate. As a result, aflatoxins B,was detected in Chuanxiong Rhizoma and Platycladi Semen in the 14 kind of Chinese Materia Medica, while there were none of aflatoxins in the pharmaceutical intermediates made by Chuanxiong Rhizoma. Conclusion: The method established in this study was specific and accurate for the detection of aflatoxins in Chinese Materia Medica and pharmaceutical intermediates.%目的:采用免疫亲和柱净化,结合柱后光化学衍生化的高效液相色谱-荧光检测器建立同步检测常用中药材及染菌中药制剂中间体中的黄曲霉毒素B1,B2,G1,G2的方法.方法:采用免疫亲和柱净化洗脱结合柱后光化学衍生手段,建立黄曲霉毒素B1,B2,G1,G2的分析方法,并分别对14种中药材及染菌中药制剂中间体进行检测.结果:黄曲霉毒素B2和G2,B1和G1分别在0.15 ~ 6.0和0.5 ~20.0 ng·mL-1线性关系良好,方法准确稳定.所选的14种中药中川芎和柏子仁检测出黄曲霉毒素B1,而以染菌中药川芎所制备的5种提取物中均未检出黄曲霉毒素.结论:采用此方法检测常用中药材及其制剂中间体中的黄曲霉毒素无干扰性杂峰,结果准确可靠.

  14. 超滤离心净化-高效液相色谱法同时测定配方乳粉中的单糖、双糖和低聚果糖%Simultaneous determination of monosaccharides, disaccharides and fructo-oligosaccharides in milk powder by ultra-filtration clean up coupled with high performance liquid chromatography

    Institute of Scientific and Technical Information of China (English)

    许丽珠; 李秀英; 黄金凤; 陈晓丹; 邓伟恒; 黄伟乾; 冼燕萍; 曾庆祝; 郭新东

    2015-01-01

    ABSTRACT:Objective To establish a simple and rapid method based on ultra-filtration clean up method and high performance liquid chromatography (HPLC) to determine 7 kinds of carbohydrate compounds (fructose, glucose, sucrose, lactose, kestose, nystose and 1F-fructofuranosylnystose) in milk powder.Methods Milk powder sample was dissolved by water, and then treated with ultra-filtration centrifugal molecular weight cut-off 3000 tube to remove protein, nucleic acid and polysaccharide macromolecular substances by high-speed centrifugation. The separation was performed on a Luna NH2 column with isocratic elution of acetonitrile: water (75:25,v:v)as the mobile phase. The analytes were determined by a refractive index detector (RID). Results Under the optimal conditions, the calibration curves were linear in the range of 0.15 to 10.0 mg/mL with correlation coefficients larger than 0.999. The limits of detection (LODs) were from 0.039 to 0.087 g/100 g. The mean recoveries for milk powder sample at three spiked concentration levels of 0.50~2.0 g/100 g were in the range of 81.2% to 105%, and the relative standard deviations (RSD) ranged from 1.1% to 6.2% (n=6). Conclusion This method is simple, rapid, and it is suitable for the identification and quantification of monosaccharides, disaccharides and fructo-oligosaccharides in milk powder.%目的:采用超滤离心截留技术快速除杂,结合高效液相色谱仪,建立一种同时检测配方乳粉中7种糖类化合物(果糖、葡萄糖、蔗糖、乳糖、蔗果三糖、蔗果四糖、蔗果五糖)的分析方法。方法经实验优化,选用截留分子量3000的超滤离心管高速离心去除样品溶液中的蛋白质、核酸和多糖等大分子物质,以乙腈-水为流动相(75:25,v:v)等度洗脱, Luna氨基色谱柱分离,示差折光检测器检测。结果7种目标分析物在0.15~10.0 mg/mL范围内线性关系良好,相关系数大于0.999,方法检出限在0.039~0.087 g/100 g

  15. Determination of Tetrodotoxin in Human Urine and Plasma after Immunoaffinity Column Clean-up Using Ultra-Performanc Hydrophilic Interaction Chromatography Coupled with Triple Quadrupole Mass Spectrometry%免疫亲和柱净化-超高效亲水色谱-三重四极杆质谱联用法测定人尿液和血浆中河豚毒素

    Institute of Scientific and Technical Information of China (English)

    张秀尧; 蔡欣欣; 张晓艺; 李瑞芬

    2014-01-01

    Anultra-performancehydrophilicinteractionliquidchromatography-triplequadrupolemass spectrometric ( UPLC-MS/MS) method was developed for the determination of tetrodotoxin ( TTX) in human urine and plasma. After the sample was cleaned-up and concentrated by immunoaffinity column, the separation of the TTX was carried out on an Acquity UPLC BEH amide column (100 mm×2. 1 mm, 1. 7 μm) with gradient elution using mobile phases of 0. 1% ( V/V) formic acid in water and acetonitrile. The analyte was detected by positive electrospray ionization mass spectrometry in the multiple reaction monitoring ( MRM) mode, and quantified by external solvent standard calibration. The measuring ranges of TTX in urine and plasma were 0. 05-400 μg/L. The average recoveries were 92%-95% and 91%-96% for TTX respectively spiked in urine and plasma with relative standard deviations of 3 . 3%-7 . 2% and 3 . 9%-7 . 8% ( n=5 ) . The limits of detection (LOD, S/N=3) and limits of quantitation (LOQ, S/N=10) of TTX were 0. 02 μg/L and 0. 05μg/L for urine and plasma, respectively. This method is suitable for the detection of TTX in urine and plasma for both forensic and clinical purposes.%建立了测定人尿液和血浆中河豚毒素( TTX)的超高液相色谱-三重四极杆质谱联用分析方法。尿液和血浆样品经免疫亲和柱净化,以0.1%甲酸-乙腈和0.1%甲酸溶液作为流动相进行梯度洗脱,在UPLC BEH Amide柱上实现分离,正离子电喷雾多反应监测( MRM)模式检测,溶剂标准外标法定量。尿液和血浆中TTX的测量范围为0.05~400μg/L,平均加标回收率分别为92%~95%和91%~96%,相对标准偏差在3.3%~7.2%和3.9%~7.8%(n=5)之间,样品中 TTX的检出限(S/N=3)均为0.02μg/L,定量限(S/N=10)为0.05μg/L。本方法适用于尿液和血浆中TTX的中毒检测和临床监测。

  16. A future for nuclear sites beyond their service life. Nuclear site value development; Un avenir pour les sites nucleaires en fin de cycle. Valorisation des sites nucleaires

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    2008-07-01

    As the nuclear industry moves into a new development phase, many facilities built in the fifties and sixties are reaching the end of their service life. Dismantling them and rehabilitating the sites on which they stand is a major industrial challenge which will give rise to a number of new projects. AREVA has more than 20 years' experience in these highly technical fields. As more and more sites reach the end of their service life, AREVA considers nuclear site value development as a fully-fledged industrial activity. The group's competencies in this field have been grouped together to form a dedicated entity: the Nuclear Site Value Development Business Unit, created in 2008. Several billion euros are invested in site value development projects which are far-reaching and complex, and often last for several decades. Long before work actually begins, lengthy studies and preparations are required to schedule operations, select the techniques to be used and optimize costs and deadlines. The Nuclear Site Value Development BU is currently working on four major projects involving its own facilities and those of the CEA: - La Hague: dismantling of the first generation of used fuel recycling facilities. Between 1966 and 1998, almost 5,000 tons of used fuel from graphite-moderated gas-cooled reactors, 4,500 tons of light water reactor fuel, as well as fuel from fast reactors and research reactors, were treated at UP2 400, the very first industrial recycling plant on the La Hague site. - Marcoule: first-time dismantling of a recycling plant. 1,000 rooms to be cleaned up, 30,000 tons of waste to be treated, 30 years of work. - Cadarache: first-time dismantling of a Mox fuel fabrication plant. The Cadarache plant was commissioned in 1962 to fabricate fuel for fast reactors; this was followed by MOX fuel for light water reactors, an activity which continued until the plant was shut down in 2003. - Annecy and Veurey: giving a new lease of life to former industrial sites

  17. A socio-ecological adaptive approach to contaminated mega-site management: From 'control and correct' to 'coping with change'

    Science.gov (United States)

    Schirmer, Mario; Lyon, Ken; Armstrong, James E.; Farrell, Katharine N.

    2012-01-01

    Mega-sites have a notable impact on surrounding ecological systems. At such sites there are substantial risks associated with complex socio-ecological interactions that are hard to characterize, let alone model and predict. While the urge to control and clean-up mega-sites (control and correct) is understandable, rather than setting a goal of cleaning up such sites, we suggest a more realistic response strategy is to address these massive and persistent sources of contamination by acknowledging their position as new features of the socio-ecological landscapes within which they are located. As it seems nearly impossible to clean up such sites, we argue for consideration of a 'coping with change' rather than a 'control and correct' approach. This strategy recognizes that the current management option for a mega-site, in light of its physical complexities and due to changing societal preferences, geochemical transformations, hydrogeology knowledge and remedial technology options may not remain optimal in future, and therefore needs to be continuously adapted, as community, ecology, technology and understanding change over time. This approach creates an opportunity to consider the relationship between a mega-site and its human and ecological environments in a different and more dynamic way. Our proposed approach relies on iterative adaptive management to incorporate mega-site management into the overall socio-ecological systems of the site's context. This approach effectively embeds mega-site management planning in a triple bottom line and environmental sustainability structure, rather than simply using single measures of success, such as contaminant-based guidelines. Recognizing that there is probably no best solution for managing a mega-site, we present a starting point for engaging constructively with this seemingly intractable issue. Therefore, we aim to initiate discussion about a new approach to mega-site management, in which the complexity of the problems posed

  18. Technical support for the EPA cleanup rule on radioactively contaminated sites

    Energy Technology Data Exchange (ETDEWEB)

    Hull, H.B.; Newman, A.; Wolbarst, A.B. [Environmental Protection Agency, Washington, DC (United States)] [and others

    1995-12-31

    The U.S. Environmental Protection Agency (EPA) is developing a radiation site cleanup regulation for the protection of the public from radionuclide contamination at sites that are to be cleaned up and released for public use. The regulation will apply to sites under the control of Federal agencies, and to sites licensed by the Nuclear Regulatory Commission (NRC) or NRC Agreement States. The agency is therefore conducting a comprehensive technical analysis aimed at developing information that will be used to support the rule. This presentation describes the regulation and the approach developed to determine how radiological health impacts and volumes of soil requiring remediation vary as functions of the possible cleanup dose or risk level.

  19. Mitigation and Monitoring Plan for impacted wetlands at the Gunnison UMTRA Project site, Gunnison, Colorado. Revision 1

    Energy Technology Data Exchange (ETDEWEB)

    1994-12-01

    The Gunnison, Colorado, abandoned uranium mill site is one site being cleaned up by the DOE under UMTRCA authority. This site`s contaminated material is being transported to a disposal site on US Bureau of Land Management (BLM) land east of Gunnison. Remedial action activities have temporarily disturbed 0.8 acre (ac) (0.3 hectares [ha]) of wetlands and permanently eliminated 4.3 ac (1.7 ha). As required by the Clean Water Act, the US Army Corps of Engineers (USACE) prepared a Section 404 Permit that addresses the loss of wetlands as a result of remedial action at the Gunnison UMTRA Project site. The 404 permit includes this report as an attachment and it describes the wetland mitigation and monitoring plan. The DOE formulated this plan in consultation with the BLM and the USACE. This report represents a revised version of the mitigation and monitoring plan (DOE, 1992b).

  20. 1996 Site environmental report Tonopah test range Tonopah, Nevada

    Energy Technology Data Exchange (ETDEWEB)

    Culp, T. [Sandia National Labs., Albuquerque, NM (United States); Forston, W. [Kirk-Mayer, Inc., Tonopah, NV (United States); Duncan, D. [ed.] [GRAM, Inc., Albuquerque, NM (United States); Sanchez, R. [Jobs Plus, Albuquerque, NM (United States)

    1997-08-01

    Sandia National Laboratories (SNL) operates the Tonopah Test Range (TTR) for the Department of Energy`s (DOE) Weapons Ordnance Program. This annual report (calendar year 1996) summarizes the compliance status to environmental regulations applicable at the site including those statutes that govern air and water quality, waste management, clean-up of contaminated areas, control of toxic substances, and adherence to requirements as related to the National Environmental Policy Act (NEPA). In compliance with DOE Orders, SNL also conducts environmental surveillance for radiological and nonradiological contaminants. SNL`s responsibility for environmentals surveillance for radiological and nonradiological contaminants. SNL`s responsibility for environmental surveillance extends only to those activities performed by SNL or under its direction. Annual radiological and nonradiological routine releases and unplanned releases (occurrences) are also summarized herein.