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Sample records for superdarn hokkaido hf

  1. Joint observations of a traveling ionospheric disturbance with the Paratunka OMTI camera and the Hokkaido HF radar

    Directory of Open Access Journals (Sweden)

    A. Koustov

    2009-06-01

    Full Text Available On 10 September 2007 between 10:00 and 14:00 UT, the OMTI all-sky imager at Paratunka (Kamchatka, Russia, GLAT~52° observed the onset and south-western progression of a localized depletion region in the airglow intensity. The perturbation, while being stretched in the NW-SE direction, crossed the entire field of view of the camera. During the event, the Hokkaido SuperDARN HF radar was monitoring echoes in the Paratunka longitudinal sector. It was detecting a localized band of ground scatter echoes progressing equatorward synchronously with the motion of the optical perturbation. It is suggested that both features resulted from the onset and south-western progression of a localized region with enhanced electric field that influenced the distribution of the plasma density in the ionosphere. Modeling of the HF ground scatter dynamics based on numerical ray tracing demonstrated qualitative consistency with the observations.

  2. Evidence of Polar Mesosphere Summer Echoes Observed by SuperDARN SANAE HF Radar in Antarctica

    OpenAIRE

    Olakunle Ogunjobi; Venkataraman Sivakumar; Judy Ann Elizabeth Stephenson; and William Tafon Sivla

    2015-01-01

    We report on the polar mesosphere summer echoes (PMSE) occurrence probability over SANAE (South African National Antarctic Expedition) IV, for the first time. A matching coincidence method is described and implemented for PMSE extraction from SuperDARN (Super Dual Auroral Radar Network) HF radar. Several SuperDARN-PMSE characteristics are studied during the summer period from years 2005 - 2007. The seasonal and interannual SuperDARN-PMSE variations in relation to the mesospheric neutral winds...

  3. First results of HF radio science with e-POP RRI and SuperDARN

    Science.gov (United States)

    Perry, G. W.; James, H. G.; Gillies, R. G.; Howarth, A.; Hussey, G. C.; McWilliams, K. A.; White, A.; Yau, A. W.

    2017-01-01

    The first results from coordinated experiments between the Radio Receiver Instrument (RRI) on the Enhanced Polar Outflow Probe (e-POP) and the Super Dual Auroral Radar Network (SuperDARN) Saskatoon high frequency (HF) radar are examined for a conjunction on 8 July 2014. e-POP, a payload on the CAScade, Smallsat and IOnospheric Polar Explorer spacecraft, was located at 380 km altitude, approximately 10° north (geographic) and 2° west of Saskatoon, Canada, moving in a southeast direction. We use a matched filter technique to extract individual received SuperDARN pulses from the RRI data stream. The pulses show characteristics of propagation through the F region ionosphere: they are heavily dispersed, they show significant pulse-to-pulse variability in magnitude, and there is clear evidence that they experienced multipath propagation. We calculate the polarization parameters of the pulses and use them to identify magnetoionic phenomena such as mode-splitting and single-mode fading. These first RRI results provide compelling insight into HF radio wave propagation and show RRI's potential to significantly advance radio science.

  4. PMSE long term observations using SuperDARN SANAE HF radar measurements

    Directory of Open Access Journals (Sweden)

    Olakunle Ogunjobi

    2017-01-01

    Full Text Available It is known that the presence of nanometre-scale ice particles and neutral air turbulence in the Polar summer mesosphere modify the D-region plasma, resulting in strong backscatter. These strong backscatters are referred to as Polar Mesosphere Summer Echoes (PMSE. Although studies on PMSE have been ongoing for over three decades, aspects revealed by various instruments are still the subject of discussion. As a sequel to the paper by Ogunjobi et al. (2015, we report on the long term trends and variations in PMSE occurrence probability from Super Dual Auroral Radar Network (SuperDARN high frequency (HF radar measurements over the South African National Antarctic Expedition IV (SANAE IV. In this current paper, a simple multiple-filter technique is employed to obtain the occurrence probability rate for SuperDARN-PMSE during the summer periods for the years 1998 - 2007. The SuperDARN-PMSE occurrence probability rate in relation to geomagnetic activity is examined. The mesospheric neutral winds and temperature trends during these periods, are further studied and presented in this paper. Both the monthly and diurnal variations in occurrence are consistent with previous reports, confirming the presence of PMSE from SuperDARN SANAE IV radar measurements and the influence of pole to pole mesospheric transport circulation. The special mesospheric mean flow observed prior to the year 2002 is ascribed to the influence of solar activity. The SuperDARN-PMSE occurrence probability peaks with lowered geomagnetic activity. These present results support the hypothesis that the particle precipitation also plays an important role in SuperDARN-PMSE occurrence.

  5. Detection of Transionospheric SuperDARN HF Waves by the Radio Receiver Instrument on the enhanced Polar Outflow Probe Satellite

    Science.gov (United States)

    Gillies, R. G.; Yau, A. W.; James, H. G.; Hussey, G. C.; McWilliams, K. A.

    2014-12-01

    The enhanced Polar Outflow Probe (ePOP) Canadian small-satellite was launched in September 2013. Included in this suite of eight scientific instruments is the Radio Receiver Instrument (RRI). The RRI has been used to measure VLF and HF radio waves from various ground and spontaneous ionospheric sources. The first dedicated ground transmission that was detected by RRI was from the Saskatoon Super Dual Auroral Radar Network (SuperDARN) radar on Nov. 7, 2013 at 14 MHz. Several other passes over the Saskatoon SuperDARN radar have been recorded since then. Ground transmissions have also been observed from other radars, such as the SPEAR, HAARP, and SURA ionospheric heaters. However, the focus of this study will be on the results obtained from the SuperDARN passes. An analysis of the signal recorded by the RRI provides estimates of signal power, Doppler shift, polarization, absolute time delay, differential mode delay, and angle of arrival. By comparing these parameters to similar parameters derived from ray tracing simulations, ionospheric electron density structures may be detected and measured. Further analysis of the results from the other ground transmitters and future SuperDARN passes will be used to refine these results.

  6. Evidence of Polar Mesosphere Summer Echoes Observed by SuperDARN SANAE HF Radar in Antarctica

    Directory of Open Access Journals (Sweden)

    Olakunle Ogunjobi

    2015-01-01

    Full Text Available We report on the polar mesosphere summer echoes (PMSE occurrence probability over SANAE (South African National Antarctic Expedition IV, for the first time. A matching coincidence method is described and implemented for PMSE extraction from SuperDARN (Super Dual Auroral Radar Network HF radar. Several SuperDARN-PMSE characteristics are studied during the summer period from years 2005 - 2007. The seasonal and interannual SuperDARN-PMSE variations in relation to the mesospheric neutral winds are studied and presented in this paper. The occurrence probability of SuperDARN-PMSE on the day-to-day scale show, predominantly, diurnal variation, with a broader peak between 12 - 14 LT and distinct minimum of 22 LT. The SuperDARN-PMSE occurrence probability rate is high in the summer solstice. Seasonal variations show a connection between the SuperDARN-PMSE occurrence probability rate and mesospheric temperature from SABER (Sounding of the Atmosphere using Broadband Emission Radiometry. The seasonal trend for both meridional and zonal winds is very stable year-to-year. Analysis of the neutral wind variations indicates the importance of pole-to-pole circulations in SuperDARN-PMSE generation.

  7. On determining the noon polar cap boundary from SuperDARN HF radar backscatter characteristics

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    M. Pinnock

    Full Text Available Previous work has shown that ionospheric HF radar backscatter in the noon sector can be used to locate the footprint of the magnetospheric cusp particle precipitation. This has enabled the radar data to be used as a proxy for the location of the polar cap boundary, and hence measure the flow of plasma across it to derive the reconnection electric field in the ionosphere. This work used only single radar data sets with a field of view limited to ~2 h of local time. In this case study using four of the SuperDARN radars, we examine the boundary determined over 6 h of magnetic local time around the noon sector and its relationship to the convection pattern. The variation with longitude of the latitude of the radar scatter with cusp characteristics shows a bay-like feature. It is shown that this feature is shaped by the variation with longitude of the poleward flow component of the ionospheric plasma and may be understood in terms of cusp ion time-of-flight effects. Using this interpretation, we derive the time-of-flight of the cusp ions and find that it is consistent with approximately 1 keV ions injected from a subsolar reconnection site. A method for deriving a more accurate estimate of the location of the open-closed field line boundary from HF radar data is described.

    Key words: Ionosphere (ionosphere–magnetosphere interactions; plasma convection · Magnetospheric physics (magnetopause · cusp · and boundary layers

  8. Mapping ionospheric backscatter measured by the SuperDARN HF radars – Part 1: A new empirical virtual height model

    Directory of Open Access Journals (Sweden)

    T. K. Yeoman

    2008-05-01

    Full Text Available Accurately mapping the location of ionospheric backscatter targets (density irregularities identified by the Super Dual Auroral Radar Network (SuperDARN HF radars can be a major problem, particularly at far ranges for which the radio propagation paths are longer and more uncertain. Assessing and increasing the accuracy of the mapping of scattering locations is crucial for the measurement of two-dimensional velocity structures on the small and meso-scale, for which overlapping velocity measurements from two radars need to be combined, and for studies in which SuperDARN data are used in conjunction with measurements from other instruments. The co-ordinates of scattering locations are presently estimated using a combination of the measured range and a model virtual height, assuming a straight line virtual propagation path. By studying elevation angle of arrival information of backscatterred signals from 5 years of data (1997–2001 from the Saskatoon SuperDARN radar we have determined the actual distribution of the backscatter target locations in range-virtual height space. This has allowed the derivation of a new empirical virtual height model that allows for a more accurate mapping of the locations of backscatter targets.

  9. Comparison of D-region Doppler drift winds measured by the SuperDARN Finland HF radar over an annual cycle using the Kiruna VHF meteor radar

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    N. F. Arnold

    Full Text Available The SuperDARN chain of oblique HF radars has provided an opportunity to generate a unique climatology of horizontal winds near the mesopause at a number of high latitude locations, via the Doppler shifted echoes from sources of ionisation in the D-region. Ablating meteor trails form the bulk of these targets, but other phenomena also contribute to the observations. Due to the poor vertical resolution of the radars, care must be taken to reduce possible biases from sporadic-E layers and Polar Mesospheric Summer echoes that can affect the effective altitude of the geophysical parameters being observed. Second, there is strong theoretical and observational evidence to suggest that the radars are picking up echoes from the backward looking direction that will tend to reduce the measured wind strengths. The effect is strongly frequency dependent, resulting in a 20% reduction at 12 MHz and a 50% reduction at 10 MHz. A comparison of the climatologies observed by the Super-DARN Finland radar between September 1999 and September 2000 and that obtained from the adjacent VHF meteor radar located at Kiruna is also presented. The agreement between the two instruments was very good. Extending the analysis to the SuperDARN Iceland East radar indicated that the principles outlined above could be applied successfully to the rest of the SuperDARN network.

    Key words. Ionosphere (ionosphere-atmosphere interactions; instruments and techniques – Meteorology and atmospheric dynamics (waves and tides

  10. Simultaneous PMC and PMSE observations with a ground-basedlidar and SuperDARN HF radar over Syowa Station, Antarctica

    Science.gov (United States)

    Suzuki, Hidehiko; Nakamura, Takuji; Tsutsumi, Masaki; Kawahara, Takuya D.; Ogawa, Tadahiko; Tomikawa, Yoshihiro; Ejiri, Mitsumu K.; Sessai Yukimatu, Akira; Abo, Makoto

    2012-07-01

    A Rayleigh-Raman lidar system had been installed by the 52nd JapaneseAntarctic Research Expedition on February, 2011 at Syowa Station Antarctica(69.0°S, 39.5°E). Polar Mesospheric Cloud (PMC) was detected by the lidar at22:30UT (+3hr for LT) on Feb 4th, 2011, the first day of a routineoperation. This event is the first time to detect PMC over Syowa Station bya lidar. In the same night, SuperDARN HF radar with oblique incidence beamsalso detected Polar Mesosphere Summer Echoes (PMSEs) during 21:30UT to23:00UT. Although these signals were detected at different times andlocations, PMC motion estimated using horizontal wind velocities obtained bya collocated MF radar strongly suggests that they have a common origin (i.e.ice particle). We consider that this event occurred in the end of PMCactivity period at Syowa Station in the austral summer season (2010-2011),since the lidar did not detected any PMC signals on other days in February,2011. This is consistent with satellite-born PMC observations by AIM/CIPSand atmospheric temperature observations by AURA/MLS instruments.

  11. Simultaneous PMC and PMSE observations with a ground-based lidar and SuperDARN HF radar at Syowa Station, Antarctica

    Directory of Open Access Journals (Sweden)

    H. Suzuki

    2013-10-01

    Full Text Available A Rayleigh–Raman lidar system was installed in January 2011 at Syowa Station, Antarctica (69.0° S, 39.6° E. Polar mesospheric clouds (PMCs were detected by lidar at around 22:30 UTC (LT −3 h on 4 February 2011, which was the first day of observation. This was the first detection of PMCs over Syowa Station by lidar. On the same day, a Super Dual Auroral Radar Network (SuperDARN HF radar with oblique-incidence beams detected polar mesospheric summer echoes (PMSE between 21:30 and 23:00 UTC. This event is regarded as the last PMC activity around Syowa Station during the austral summer season (2010–2011, since no other PMC signals were detected by lidar in February 2011. This is consistent with results of PMC and mesopause temperature observations by satellite-born instruments of AIM (Aeronomy of Ice in the Mesosphere/CIPS (Cloud Imaging and Particle Size and AURA/MLS (Microwave Limb Sounder and horizontal wind measurements taken by a separate MF radar. Doppler velocity of PMSE observed by the HF radar showed motion toward Syowa Station (westward. This westward motion is consistent with the wind velocities obtained by the MF radar. However, the PMSE region showed horizontal motion from a north-to-south direction during the PMC event. This event indicates that the apparent horizontal motion of the PMSE region can deviate from neutral wind directions and observed Doppler velocities.

  12. Simultaneous PMC and PMSE observations with a ground-based lidar and SuperDARN HF radar at Syowa Station, Antarctica

    Science.gov (United States)

    Suzuki, H.; Nakamura, T.; Ejiri, M. K.; Ogawa, T.; Tsutsumi, M.; Abo, M.; Kawahara, T. D.; Tomikawa, Y.; Yukimatu, A. S.; Sato, N.

    2013-10-01

    A Rayleigh-Raman lidar system was installed in January 2011 at Syowa Station, Antarctica (69.0° S, 39.6° E). Polar mesospheric clouds (PMCs) were detected by lidar at around 22:30 UTC (LT -3 h) on 4 February 2011, which was the first day of observation. This was the first detection of PMCs over Syowa Station by lidar. On the same day, a Super Dual Auroral Radar Network (SuperDARN) HF radar with oblique-incidence beams detected polar mesospheric summer echoes (PMSE) between 21:30 and 23:00 UTC. This event is regarded as the last PMC activity around Syowa Station during the austral summer season (2010-2011), since no other PMC signals were detected by lidar in February 2011. This is consistent with results of PMC and mesopause temperature observations by satellite-born instruments of AIM (Aeronomy of Ice in the Mesosphere)/CIPS (Cloud Imaging and Particle Size) and AURA/MLS (Microwave Limb Sounder) and horizontal wind measurements taken by a separate MF radar. Doppler velocity of PMSE observed by the HF radar showed motion toward Syowa Station (westward). This westward motion is consistent with the wind velocities obtained by the MF radar. However, the PMSE region showed horizontal motion from a north-to-south direction during the PMC event. This event indicates that the apparent horizontal motion of the PMSE region can deviate from neutral wind directions and observed Doppler velocities.

  13. A Statistical study of the Doppler spectral width of high-latitude ionospheric F-region echoes recorded with SuperDARN coherent HF radars

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    J.-P. Villain

    Full Text Available The HF radars of the Super Dual Auroral Radar Network (SuperDARN provide measurements of the E × B drift of ionospheric plasma over extended regions of the high-latitude ionosphere. We have conducted a statistical study of the associated Doppler spectral width of ionospheric F-region echoes. The study has been conducted with all available radars from the Northern Hemisphere for 2 specific periods of time. Period 1 corresponds to the winter months of 1994, while period 2 covers October 1996 to March 1997. The distributions of data points and average spectral width are presented as a function of Magnetic Latitude and Magnetic Local Time. The databases are very consistent and exhibit the same features. The most stringent features are: a region of very high spectral width, collocated with the ionospheric LLBL/cusp/mantle region; an oval shaped region of high spectral width, whose equator-ward boundary matches the poleward limit of the Holzworth and Meng auroral oval. A simulation has been conducted to evaluate the geometrical and instrumental effects on the spectral width. It shows that these effects cannot account for the observed spectral features. It is then concluded that these specific spectral width characteristics are the signature of ionospheric/magnetospheric coupling phenomena.

    Key words. Ionosphere (auroral ionosphere; ionosphere-magnetosphere interactions; ionospheric irregularities

  14. Comparison of DMSP cross-track ion drifts and SuperDARN line-of-sight velocities

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    R. A. Drayton

    2005-10-01

    Full Text Available Cross-track ion drifts measured by the DMSP satellites are compared with line-of-sight SuperDARN HF velocities in approximately the same directions. Good overall agreement is found for a data set comprising of 209 satellite passes over the field of view of nine SuperDARN radars in both the Northern and Southern Hemispheres. The slope of the best linear fit line relating the SuperDARN and DMSP velocities is of the order of 0.7 with a tendency for SuperDARN velocities to be smaller. The agreement implies that the satellite and radar data can be merged into a common set provided that spatial and temporal variations of the velocity as measured by both instruments are smooth.

    Keywords. Ionosphere (Ionospheric irregularities; Plasma convection; Auroral ionosphere

  15. The accuracy of using the spectral width boundary measured in off-meridional SuperDARN HF radar beams as a proxy for the open-closed field line boundary

    Science.gov (United States)

    Chisham, G.; Freeman, M. P.; Sotirelis, T.; Greenwald, R. A.

    2005-10-01

    Determining reliable proxies for the ionospheric signature of the open-closed field line boundary (OCB) is crucial for making accurate measurements of magnetic reconnection. This study compares the latitudes of spectral width boundaries (SWBs) measured by different beams of the Goose Bay radar of the Super Dual Auroral Radar Network (SuperDARN), with the latitudes of OCBs determined using the low-altitude Defense Meteorological Satellite Program (DMSP) spacecraft, in order to determine whether the accuracy of the SWB as a proxy for the ionospheric projection of the OCB depends on the line-of-sight direction of the radar beam. The latitudes of SWBs and OCBs were identified using automated algorithms applied to 5 years (1997 2001) of data measured in the 1000 1400 magnetic local time (MLT) range. Six different Goose Bay radar beams were used, ranging from those aligned in the geomagnetic meridional direction to those aligned in an almost zonal direction. The results show that the SWB is a good proxy for the OCB in near-meridionally-aligned beams but becomes progressively more unreliable for beams greater than 4 beams away from the meridional direction. We propose that SWBs are identified at latitudes lower than the OCB in the off-meridional beams due to the presence of high spectral width values that result from changes in the orientation of the beams with respect to the gradient in the large-scale ionospheric convection pattern. Keywords. Ionosphere (Instruments and techniques; Plasma convection) Magnetospheric physics (Magnetopause, cusp and boundary layers)

  16. 1993 Hokkaido, Japan Images

    Data.gov (United States)

    National Oceanic and Atmospheric Administration, Department of Commerce — On July 12, 1993, a magnitude 7.6 Ms (7.7 Mw) (HRV) earthquake at 13:17 UT in the Sea of Japan near Hokkaido caused a back-arc tsunami that caused damage in all of...

  17. Sapporo, Hokkaido, Japan

    Science.gov (United States)

    1992-01-01

    The city of Sapporo on the northernmost of the Japanese Home Island of Hokkaido (43.5N, 141.5E), host to the 1986 Winter Olympic Games is situated along the margin of a large valley which extends across the island from the Sea of Japan to the Pacific Ocean. The Valley is largely cultivated (the lighter green of the cultivated land distinguishes it from the gray urban development of Sapporo), but much of the island remains heavily forested.

  18. SuperDARN scalar radar equations

    CERN Document Server

    Berngardt, O I; Potekhin, A P

    2016-01-01

    The quadratic scalar radar equations are obtained for SuperDARN radars that are suitable for the analysis and interpretation of experimental data. The paper is based on a unified approach to the obtaining radar equations for the monostatic and bistatic sounding with use of hamiltonian optics and ray representation of scalar Green's function and without taking into account the polarization effects. The radar equation obtained is the sum of several terms corresponding to the propagation and scattering over the different kinds of trajectories, depending on their smoothness and the possibility of reflection from the ionosphere. It is shown that the monostatic sounding in the media with significant refraction, unlike the case of refraction-free media, should be analyzed as a combination of monostatic and bistatic scattering. This leads to strong dependence of scattering amplitude on background ionospheric density due to focusing mechanism and appearance of new (bistatic) areas of effective scattering with signific...

  19. SuperDARN convection and Sondrestrom plasma drift

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    L. Xu

    Full Text Available Plasma convection measurements by the Goose Bay and Stokkseyri SuperDARN radar pair and the Sondrestrom incoherent scatter radar are compared in three different ways, by looking at the line-of-sight (l-o-s velocities, by comparing the SuperDARN vectors and corresponding Sondrestrom l-o-s velocities and by comparing the end products of the instruments, the convection maps. All three comparisons show overall reasonable agreement of the convection measurements though the data spread is significant and for some points a strong disagreement is obvious. The convection map comparison shows a tendency for the SuperDARN velocities to be often less than the Sondrestrom drifts for strong flows (velocities > 1000 m/s and larger for weak flows (velocities < 500 m/s. On average, both effects do not exceed 35%. Data indicate that inconsistencies between the two data sets occur largely at times of fast temporal variations of the plasma drift and for strongly irregular flow ac-cording to the SuperDARN convection maps. These facts indicate that the observed discrepancies are in many cases a result of the different spatial and temporal resolutions of the instruments.

    Key words. Ionosphere (ionospheric irregularities; plasma convection; polar ionosphere

  20. Investigation of Third Gyro-harmonic Heating at HAARP Using Stimulated Radio Emissions, the MUIR and SuperDARN Radars

    Science.gov (United States)

    Mahmoudian, Alireza; Bernhardt, Paul; Ruohoniemi, J. Michael; Isham, Brett; Watkins, Brenton; Scales, Wayne

    2016-07-01

    Use of high frequency (HF) heating experiments has been extended in recent years as a useful methodology for plasma physicists wishing to remotely study the properties and behavior of the ionosphere as well as nonlinear plasma processes. Our recent work using high latitude heating experiments has lead to several important discoveries that have enabled assessment of active geomagnetic conditions, determination of minor ion species and their densities, ion mass spectrometry, electron temperature measurements in the heating ionosphere, as well a deeper understanding of physical processes associated with electron acceleration and formation of field aligned irregularities. The data recorded during two campaigns at HAARP in 2011 and 2012 will be presented. Several diagnostic instruments have been used to detect HAARP heater-generated ionospheric irregularities and plasma waves. These diagnostics include an ionosonde, MUIR (Modular UHF Ionospheric Radar at 446 MHz), SuperDARN HF backscatter radar and ground-based SEE receivers. Variation of the wideband/ narrowband SEE features, SuperDARN echoes, and enhanced ion lines were studied with pump power variation, pump frequency stepping near 3fce as well as changing beam angle relative to the magnetic zenith. In particular, formation of field-aligned irregularities (FAIs) and upper hybrid (UH) waves through oscillating two-stream instability (OSTI) and resonance instability is studied. During heating, Narrowband SEE (NSEE) showed enhancements that correlated with the enhanced MUIR radar ion lines. IA MSBS (Magnetized Stimulated Brillouin Scatter) lines are much narrower than Wideband SEE (WSEE) lines and as a result electron temperature calculated using NSEE line offset has potential to be more accurate. This technique may therefore complement the electron temperature calculation using ISR spectra. Strength of IA MSBS lines correlate with EHIL in the MUIR spectrum during HF pump frequency variation near 3fce. Therefore, NSEE

  1. PMSE long term observations using SuperDARN SANAE HF radar measurements

    National Research Council Canada - National Science Library

    Olakunle Ogunjobi; Venkataraman Sivakumar; Judy Ann Elizabeth Stephenson; Zolile Mtumela

    2017-01-01

    .... These strong backscatters are referred to as Polar Mesosphere Summer Echoes (PMSE). Although studies on PMSE have been ongoing for over three decades, aspects revealed by various instruments are still the subject of discussion...

  2. Origin of the SuperDARN broad Doppler spectra:simultaneous observation with Oersted satellite magnetometer

    Directory of Open Access Journals (Sweden)

    K. Hosokawa

    2004-01-01

    Full Text Available We perform a case study of a favorable conjunction of an overpass of the Oersted satellite with the field-of-view of the SuperDARN Syowa East radar during an interval of the southward IMF Bz. At the time, the radar observed an L-shell aligned boundary in the spectral width around the dayside ionosphere. Simultaneously, high-frequency (0.2–5Hz magnetic field fluctuations were observed by the Oersted satellite's high-time resolution magnetometer. These magnetic field fluctuations are considered to be Alfvén waves possibly associated with the particle which precipitates into the dayside high-latitude ionosphere when magnetic reconnection occurs. It has been theoretically predicted that the time-varying electric field is the dominant physical process to expand the broad HF radar Doppler spectra. Our observation clearly demonstrates that the boundary between narrow and broad spectral widths is corresponding well to the boundary in the level of the fluctuations, which supports the previous theoretical prediction. A close relationship between electric and magnetic field fluctuations and particle precipitations during southward IMF conditions has been confirmed by many authors. The present observation allows us to suggest that the boundary between narrow and broad Doppler spectral widths observed in the dayside ionosphere is connected with the signature of the open/closed field line boundary, such as the cusp particle precipitations via electric and magnetic field fluctuations for the case of the negative IMF Bz conditions.

    Key words. Ionosphere (ionosphere-magnetosphere interactions; plasma convection. Magnetospheric physics (magnetopause, cusp, and boundary layers

  3. Hokkaido Nansei-Oki Tsunami, July 12, 1993

    Data.gov (United States)

    National Oceanic and Atmospheric Administration, Department of Commerce — An earthquake occurred off the west coast of Hokkaido and the small offshore island of Okushiri in the Sea of Japan. In two to five minutes the tsunami, one of the...

  4. The effect of plasma density structure on HF radio wave propagation at auroral and polar latitudes measured by e-POP

    Science.gov (United States)

    Perry, G. W.; James, H. G.; Gillies, R.; McWilliams, K. A.; St-Maurice, J. P.; Yau, A. W.

    2015-12-01

    One of the scientific objectives of the enhanced Polar Outflow Probe (e-POP) Radio Receiver Instrument (RRI) is to study ionospheric density structure and its impact on High Frequency (HF) radio wave propagation. We present a survey of several ePOP RRI transits through isolated beams of the Super Dual Auroral Radar Network (SuperDARN) Saskatoon and Rankin Inlet radars. It reveals that the spreading of a SuperDARN beam beyond its nominal azimuthal beam width of 3.24° is a common occurrence at auroral and polar latitudes. Furthermore, on multiple occasions, lateral deviations of a beam's power peak by several beam widths was measured, indicating the presence of significant plasma density gradients along the ray path. The e-POP RRI measurements illustrate that our understanding and recognition of plasma density gradients and their influence on HF radio wave propagation is limited. We report on the results of employing HF ray tracing techniques to quantify the impact of ionospheric structuring on HF radio wave propagation, and consider the source of the gradients contributing to the spreading of the SuperDARN beams.

  5. On the SuperDARN cross polar cap potential saturation effect

    Directory of Open Access Journals (Sweden)

    A. V. Koustov

    2009-10-01

    Full Text Available Variation of the cross polar cap potential (CPCP with the interplanetary electric field (IEF, the merging electric field EKL, the Polar Cap North (PCN magnetic index, and the solar wind-magnetosphere coupling function EC of Newell et al. (2007 is investigated by considering convection data collected by the Super Dual Auroral Radar Network (SuperDARN in the Northern Hemisphere. Winter and summer observations are considered separately. All variations considered show close to linear trend at small values of the parameters and tendency for the saturation at large values. The threshold values starting from which the non-linearity was evident were estimated to be IEF*~EKL*~3 mV/m, PCN*~3–4, and EC*~1.5×104. The data indicate that saturation starts at larger values of the above parameters and reaches larger (up to 10 kV saturation levels during summer. Conclusions are supported by a limited data set of simultaneous SuperDARN observations in the Northern (summer and Southern (winter Hemispheres. It is argued that the SuperDARN CPCP saturation levels and the thresholds for the non-linearity to be seen are affected by the method of the CPCP estimates.

  6. Geothermal gradients map of Hokkaido; Hokkaido no chion kobaizu ni tsuite

    Energy Technology Data Exchange (ETDEWEB)

    Akita, F.; Matsunami, T.; Wakahama, H. [Hokkaido Geological Survey, Sapporo (Japan)

    1997-06-15

    This paper outlines the newly prepared geothermal gradient map (GGM) of Hokkaido which is important for survey on geothermal and hot spring resources. The temperature data of 687 wells were compiled by data collection and field survey. The geothermal gradient was calculated from the ratio of the temperature difference between the bottom (deepest well log) and the ground surface (10degC) to a bottom depth. GGM was prepared using data of 85 wells which show real geothermal temperatures through conductive temperature profiles, or SBHT (static bottom hole temperature) calculation is possible. Geological profiles were classified into three types based on base rocks. The thermal structure of GGM was clearly divided into a high geothermal gradient over 10degC/100m, and a low one within 3degC/100m. The former showed active volcano and high geothermal areas, while the latter showed a volcanic front arc area. This underground temperature structure relates to the formation process of volcanos and the origin of magma, and is also similar to the trend of a crust thermal flow rate. The geothermal gradient increases with a decrease in Curie point depth. 26 refs., 10 figs., 2 tabs.

  7. The Vision and Challenges of Hokkaido Pharmaceutical University's Affiliated Pharmacy.

    Science.gov (United States)

    Norose, Takahiko; Manabe, Tomohiro; Furuta, Seiichi; Watanabe, Kazuhiro

    2016-01-01

    Hokkaido Pharmaceutical University (HPU), according to its educational mission, seeks to "develop medical professionals who contribute to community medicine", and it has produced more than 6300 graduates since 1974. With recent medical advancements and a progressively aging society, the role of the pharmacist in community medicine has diversified and is increasing in importance. Therefore, in April 2012, the Hokkaido Pharmaceutical University Affiliated Pharmacy was established as a for-profit business of the Educational Foundation of the Hokkaido University of Science, the parent body of HPU. The pharmacy is located near the Sapporo station; it is operated by six pharmacists and four clerks, and supported by three faculty members who are engaged in providing HPU student education such as on-site clinical training, in addition to their pharmacy duties such as home care pharmaceutics. For the first two years it was open, the pharmacy focused on the establishment of pharmacy administration and fiscal consolidation. In April 2015, the Pharmacy Management Committee set the pharmacy's future vision, as well as its mid-term strategy, which consists of the four main components of pharmacy practices, education, research, and social contribution, in order for the pharmacy to serve as a model of community pharmacy.

  8. First observations of polar mesosphere summer echoes by SuperDARN Zhongshan radar

    Science.gov (United States)

    Liu, E. X.; Hu, H. Q.; Hosokawa, K.; Liu, R. Y.; Wu, Z. S.; Xing, Z. Y.

    2013-11-01

    We report the first observations of PMSE by SuperDARN Zhongshan radar in Antarctica and present a statistical analysis of PMSE from 2010 to 2012. The seasonal variations of occurrence are consistent with those before, with an obvious enhancement at the beginning of summer and a maximum several days after summer solstice. The special features of diurnal variations were observed because of high geomagnetic latitude of Zhongshan Station, which is that the maximum is near local midnight and the secondary maximum appears 1-2 h after the local noon. The results proved that the auroral particle precipitation plays a fairly important role in the PMSE occurrence.

  9. Finland HF and Esrange MST radar observations of polar mesosphere summer echoes

    Directory of Open Access Journals (Sweden)

    T. Ogawa

    Full Text Available Peculiar near range echoes observed in summer with the SuperDARN HF radar in Finland are presented. The echoes were detected at four frequencies of 9, 11, 13 and 15 MHz at slant ranges of 105–250 km for about 100 min. Interferometer measurements indicate that the echoes are returned from 80–100 km altitudes with elevation angles of 20°–60°. Echo power (< 16 dB, Doppler velocity (between –30 and + 30 ms-1 and spectral width (< 60 ms-1 fluctuate with periods of several to 20 min, perhaps due to short–period atmospheric gravity waves. When the HF radar detected the echoes, a vertical incidence MST radar, located at Esrange in Sweden (650 km north of the HF radar site, observed polar mesosphere summer echoes (PMSE at altitudes of 80–90 km. This fact suggests that the near range HF echoes are PMSE at HF band, although both radars did not probe a common volume. With increasing radar frequency, HF echo ranges are closer to the radar site and echo power becomes weaker. Possible mechanisms to explain these features are discussed.

    Key words. Meteorology and atmospheric dynamics (middle atmosphere dynamics; thermospheric dynamics; waves and tides; instruments and techniques

  10. First SuperDARN polar mesosphere summer echoes observed at SANAE IV, Antarctica

    Science.gov (United States)

    Ogunjobi, Olakunle; Sivakumar, Venkataraman; Judy; Stephenson, A. E.

    For over 3 decades studies on Polar mesosphere summer echo (PMSE) is ongoing. Its causative mechanism in the Antarctic and Arctic mesopause altitude is yet to be completely understood and is partly due to few observations from Antarctica. Also important were the varied influencing factors across the observable locations. For the first time, we report the PMSE occurrence probability rates over South African National Antarctic Expedition IV (SANAE IV). A comparison is made with observation from SANAE IV magnetic conjugate vicinity, Goose Bay in Arctic region. Here, a new matching coincidence method allowing filtration of possible contaminating echoes is described and implemented for extraction of PMSE during the 2005-2007 summers. In this method, Riometer and Super Dual Auroral Radar Network (SuperDARN) measurements from SANAE IV location are matched to obtain PMSE occurrence probability rate. Whereas the seasonal and diurnal variations followed the known features of PMSE, the percentage difference in probability occurrence rate is found to be remarkable. The SANAE IV probability rate is found to be high for the summer months reaching about 50% peak around the summer solstice. When the coincidence algorithm is relaxed, we found a substantial 30% increase in PMSE occurrence rate at SANAE IV. At this time, about 100% peak is found for Goose Bay. The contribution from the ionospheric D region electron density enhancements to SuperDARN PMSE occurrence rates at locations under auroral regions will be presented.

  11. Genetic uniformity of Echinococcus multilocularis collected from different intermediate host species in Hokkaido, Japan.

    Science.gov (United States)

    Okamoto, Munehiro; Oku, Yuzaburo; Kurosawa, Tsutomu; Kamiya, Masao

    2007-02-01

    DNA from several isolates of Taenia taeniaeformis and Echinococcus multilocularis were digested with restriction enzymes and hybridized with digoxigenated oligonucleotide probe (CAC)5. Within the six wild isolates of Taenia taeniaeformis from Norway rats in Hokkaido, although several bands were common among isolates, fingerprinting patterns were specific to each isolate. In the case of E. multilocularis, regardless of hosts from which each isolate has been isolated, the five isolates collected from Hokkaido, showed the same fingerprinting pattern. These results indicate that there was very little genetic difference among these isolates. Although the fingerprinting pattern of E. multilocularis from St. Lawrence Is. was similar to that of the Hokkaido isolates, some bands were different from those in the Hokkaido isolates. Echinococcus multilocularis in Hokkaido seems to be closely-related genetically to that from St. Lawrence Is.

  12. A long-term comparison of wind and tide measurements in the upper mesosphere recorded with an imaging Doppler interferometer and SuperDARN radar at Halley, Antarctica

    Directory of Open Access Journals (Sweden)

    R. E. Hibbins

    2008-03-01

    Full Text Available Data from a near co-located imaging Doppler interferometer (IDI and SuperDARN radar recorded since 1996 have been analysed in a consistent manner to compare the derived mean winds and tides in the upper mesosphere. By comparing only days when both techniques were recording good quality meridional wind data it is shown that the SuperDARN radar winds and tides correlate best with the IDI height bin 90–95 km. On timescales of one hour the winds derived from the IDI have a much greater associated variance and correlate poorly with the SuperDARN winds. Regression analysis reveals that the observed SuperDARN daily mean meridional wind strength is approximately 65% that recorded by the IDI, in good quantitative agreement with previous studies which have shown contamination to SuperDARN derived winds due to the significant back lobe of the radar radiation pattern. Climatologically the two techniques observe similar monthly mean winds with the SuperDARN meridional winds suppressed compared to the IDI which tends to record winds more poleward than those derived by the SuperDARN radar during the summer months, and to be slightly more equatorward during the winter. The 12-h tidal amplitude and phase derived from both techniques are in good agreement, whereas the 24-h tides are seen much more strongly in the SuperDARN radar, especially in wintertime, with poor phase agreement. Long term comparison of the two techniques reveals a tendency for the IDI meridional winds to be more poleward during solar maximum especially during summer time; an effect which is not reproduced in the meridional winds derived from the SuperDARN radar. These results are discussed in the context of previous studies to independently determine the veracity of each technique, and to highlight the circumstances where data derived from these two techniques can be used to draw reliable conclusions from comparative studies based on geographically distributed pairs of instruments.

  13. Three-dimensional analysis of the magnetic structure in Hokkaido, Japan; Hokkaido no sanjigen jiki kozo kaiseki

    Energy Technology Data Exchange (ETDEWEB)

    Makino, M. [Geological Survey of Japan, Tsukuba (Japan)

    1996-10-01

    The magnetic structure in Hokkaido was quantitatively analyzed by the magnetic anomaly distribution. This paper describes its characteristics. Detection of structural boundaries and 3-D analysis of double-layer structure were conducted for the regional magnetic data in a region with about 500 km square. There was not so large difference in patterns of magnetic anomaly distribution between the case that the direction of magnetization was set at 45{degree} to the west during the geomagnetic conversion according to Segawa and Oshima and the case that it was set as same as the current geomagnetic direction. The method of Blakely and Simpson was useful to detect the boundaries of magnetic structures. The structural boundaries obtained were more linear than the iso-magnetic contour lines. A new method has been conceived in which the approximation of 3-D magnetic structure analysis can be deduced, and the irregularity of magnetic basement can be determined by the repeated calculation. In practice, this method was applied to the magnetic data in the whole Hokkaido. The calculation was stably converged. It was found that the magnetic structure obtained in the Kamuikotan/Ishikari-Kitakami magnetic belt exhibited a fault structure having steep slopes accompanied by the basin structure in the western boundaries. 19 refs., 6 figs.

  14. Sources and Characteristics of Medium Scale Traveling Ionospheric Disturbances Observed by SuperDARN Radars in the North American Sector

    Science.gov (United States)

    Frissell, N. A.; Baker, J. B.; Ruohoniemi, J. M.; Greenwald, R. A.; Gerrard, A. J.; Miller, E. S.; West, M. L.

    2015-12-01

    Medium Scale Traveling Ionospheric Disturbances (MSTIDs) are wave-like perturbations of the F-region ionosphere with horizontal wavelengths on the order of several hundred kilometers, and periods between 15 - 60 min. In SuperDARN radar data, MSTID signatures are manifested as quasi-periodic enhancements of ground backscatter (i.e. skip focusing) which propagate through the radar field-of-view. At high latitudes, SuperDARN observations of MSTIDs have generally been attributed to atmospheric gravity waves (AGWs) launched by auroral sources (e.g. Joule heating). However, recent studies with newer mid-latitude radars have shown MSTIDs are routinely observed in the subauroral ionosphere as well. To develop a more complete picture of MSTID activity, we have surveyed observations from four high latitude and six mid latitude SuperDARN radars located in the North American sector collected between 2011 and 2015 during the months of November to May. Consistent with previous SuperDARN MSTID studies, all radars observed MSTIDs with horizontal wavelengths between ~250 - 500 km and horizontal velocities between ~100 - 250 m/s. The majority of the MSTIDs were observed to propagate in a predominantly southward direction, with bearings ranging from ~135 ̊ - 250 ̊ geographic azimuth. This is highly suggestive of high latitude auroral sources; however, no apparent correlation with geomagnetic or space weather activity could be identified. Rather, comparison of the SuperDARN MSTID time-series data with northern hemisphere geopotential data from the European Center for Medium Range Weather Forecasting (ECMWF) operational model reveals a strong correlation of MSTID activity with dynamics in the polar vortex structure on two primary time scales. First, a seasonal effect manifests as enhanced MSTID activity from November through January, followed by a depressed period from February to May. This appears to correspond with the seasonal development and later decay of the polar vortex. A

  15. Observations of HF backscatter decay rates from HAARP generated FAI

    Science.gov (United States)

    Bristow, W. A.; Hysell, D. L.

    2016-12-01

    Suitable experiments at the High-frequency Active Auroral Research Program (HAARP) facilities in Gakona, Alaska, create a region of ionospheric Field-Aligned Irregularities (FAI) that produces strong radar backscatter observed by the SuperDARN radar on Kodiak Island, Alaska. Creation of FAI in HF ionospheric modification experiments has been studied by a number of authors who have developed a rich theoretical background. The decay of the irregularities, however, has not been so widely studied yet it has the potential for providing estimates of the parameters of natural irregularity diffusion, which are difficult measure by other means. Hysell, et al. [1996] demonstrated using the decay of radar scatter above the Sura heating facility to estimate irregularity diffusion. A large database of radar backscatter from HAARP generated FAI has been collected over the years. Experiments often cycled the heater power on and off in a way that allowed estimates of the FAI decay rate. The database has been examined to extract decay time estimates and diffusion rates over a range of ionospheric conditions. This presentation will summarize the database and the estimated diffusion rates, and will discuss the potential for targeted experiments for aeronomy measurements. Hysell, D. L., M. C. Kelley, Y. M. Yampolski, V. S. Beley, A. V. Koloskov, P. V. Ponomarenko, and O. F. Tyrnov, HF radar observations of decaying artificial field aligned irregularities, J. Geophys. Res. , 101, 26,981, 1996.

  16. Observations of HF backscatter decay rates from HAARP generated FAI

    Science.gov (United States)

    Bristow, William; Hysell, David

    2016-07-01

    Suitable experiments at the High-frequency Active Auroral Research Program (HAARP) facilities in Gakona, Alaska, create a region of ionospheric Field-Aligned Irregularities (FAI) that produces strong radar backscatter observed by the SuperDARN radar on Kodiak Island, Alaska. Creation of FAI in HF ionospheric modification experiments has been studied by a number of authors who have developed a rich theoretical background. The decay of the irregularities, however, has not been so widely studied yet it has the potential for providing estimates of the parameters of natural irregularity diffusion, which are difficult measure by other means. Hysell, et al. [1996] demonstrated using the decay of radar scatter above the Sura heating facility to estimate irregularity diffusion. A large database of radar backscatter from HAARP generated FAI has been collected over the years. Experiments often cycled the heater power on and off in a way that allowed estimates of the FAI decay rate. The database has been examined to extract decay time estimates and diffusion rates over a range of ionospheric conditions. This presentation will summarize the database and the estimated diffusion rates, and will discuss the potential for targeted experiments for aeronomy measurements. Hysell, D. L., M. C. Kelley, Y. M. Yampolski, V. S. Beley, A. V. Koloskov, P. V. Ponomarenko, and O. F. Tyrnov, HF radar observations of decaying artificial field aligned irregularities, J. Geophys. Res. , 101, 26,981, 1996.

  17. Temporal and spatial resolved SuperDARN line of sight velocity measurements corrected for plasma index of refraction using Bayesian inference

    Science.gov (United States)

    Spaleta, J.; Bristow, W. A.; Klein, J.

    2015-04-01

    Recent work by Gillies et al. (2012, 2009, 2010) has sought an explanation for the SuperDARN line-of-sight velocity underestimate of ionospheric plasma velocity. The reason for the underestimation is thought to be from the modification of the measured Doppler shift of the backscattered signal due to phase refractive index of the ionospheric plasma in the scattering region. Presented here is an analysis technique to estimate the plasma drift velocity, correcting for the index of the refraction of the scattering medium. The technique requires dual frequency SuperDARN observations and calculates velocity from the phase of the SuperDARN autocorrelation function (ACF). Both plasma velocity and plasma density are treated as independent unknowns, and self-consistent error estimates are generated for each. This new technique was employed at the McMurdo radar, resulting in estimates of plasma velocity on scales relevant to existing SuperDARN data products. The McMurdo dual frequency analysis also provides a new SuperDARN data product, an estimate for the plasma density in the ionospheric region derived wholly from SuperDARN backscatter.

  18. [Cooperation with drug addiction rehabilitation center in Hokkaido area].

    Science.gov (United States)

    Ashizawa, Takeshi

    2012-10-01

    There are about sixty therapeutic communities for drug dependence called DARC (Drug Addiction Rehabilitation Center) that is the only rehabilitation facilities managed by staffs recovered from drug dependence to use the method of twelve steps in Japan. DARC plays an important role to resolve problems of drug dependence. The subject matter of this paper concerns how medical services should cooperate with DARC. A few studies had pointed out that DARC had some outstanding problems. But there have been no studies based on longitudinal observations. I have been cooperating with DARC in Hokkaido area (HDARC) for seven years. I reported the prognosis and the employment in the users of HDARC, as well as the foundation and the management of HDARC. I explained my policies that I did not prescribe benzodiazepine and its analogs, and that I did not urinalysis to detect illicit drugs. I discussed the meaning of recovered counselors, therapeutic communities for drug dependence and drug court in Japan.

  19. PCN magnetic index and average convection velocity in the polar cap inferred from SuperDARN radar measurements

    Science.gov (United States)

    Fiori, R. A. D.; Koustov, A. V.; Boteler, D.; Makarevich, R. A.

    2009-07-01

    The relationship between the polar cap north (PCN) magnetic index and the average convection velocity of the plasma flow across the polar cap is investigated using data from both the Rankin Inlet (RKN) polar cap Super Dual Auroral Radar Network (SuperDARN) radar and the entire SuperDARN network. Correlation between the PCN index and the average velocity, determined from the median RKN line of sight (LOS) velocity, maximizes near magnetic noon and midnight when the radar field of view is roughly aligned with the noon-midnight meridian. For observations between 1000 and 1100 MLT, a roughly linear increase of the average velocity was found for a PCN index between 0 and 2, but the rate of increase is ˜2 times faster than in previous publications in which the average velocity was estimated from DMSP ion drift measurements. Comparisons between the PCN index with the cross-polar cap velocity estimated from (1) SuperDARN convection maps and (2) median RKN LOS velocities show similar trends. Both the average cross-polar cap velocity (estimated by two methods) and the cross-polar cap potential show a tendency for saturation at PCN > 2. No significant seasonal change in the nature of the relationships was found.

  20. ExtraHF survey

    DEFF Research Database (Denmark)

    Piepoli, Massimo F; Binno, Simone; Corrà, Ugo

    2015-01-01

    AIMS: In heart failure (HF), exercise training programmes (ETPs) are a well-recognized intervention to improve symptoms, but are still poorly implemented. The Heart Failure Association promoted a survey to investigate whether and how cardiac centres in Europe are using ETPs in their HF patients...... of evidence on safety or benefit was cited. When implemented, an ETP was proposed to all HF patients in only 55% of the centres, with restriction according to severity or aetiology. CONCLUSIONS: With respect to previous surveys, there is evidence of increased availability of ETPs in HF in Europe, although too...

  1. Nitrous oxide fluxes from upland soils in central Hokkaido, Japan

    Institute of Scientific and Technical Information of China (English)

    MU Zhijian; Sonoko D. KIMURA; Yo TOMA; Ryusuke HATANO

    2008-01-01

    Nitrous oxide (N2O) fluxes from soils were measured using the closed chamber method during the snow-free seasons (middle April to early November), for three years, in a total of 11 upland crop fields in central Hokkaido, Japan. The annual mean N2O fluxes ranged fluxes showed a large temporal variation with peak emissions generally occurring following fertilization and heavy rainfall events around harvesting in autumn. No clear common factor regulating instantaneous N2O fluxes was found at any of the study sites. Instead,instantaneous N2O fluxes at different sites were affected by different soil variables. The cumulative N2O emissions during the study period within each year varied from 0.15 to 7.05 kgN/hm2 for different sites, which accounted for 0.33% to 5.09% of the applied fertilizer N. No obvious relationship was observed between cumulative N2O emission and applied fertilizer N rate (P>0.4). However,the cumulative N2O emission was significantly correlated with gross mineralized N as estimated by CO2 emissions from bare soils divided by C/N ratios of each soil, and with soil mineral N pool (I.e., the sum of gross mineralized N and fertilizer N) (P<0.001).

  2. A statistical approach for identifying the ionospheric footprint of magnetospheric boundaries from SuperDARN observations

    Directory of Open Access Journals (Sweden)

    G. Lointier

    2008-02-01

    Full Text Available Identifying and tracking the projection of magnetospheric regions on the high-latitude ionosphere is of primary importance for studying the Solar Wind-Magnetosphere-Ionosphere system and for space weather applications. By its unique spatial coverage and temporal resolution, the Super Dual Auroral Radar Network (SuperDARN provides key parameters, such as the Doppler spectral width, which allows the monitoring of the ionospheric footprint of some magnetospheric boundaries in near real-time. In this study, we present the first results of a statistical approach for monitoring these magnetospheric boundaries. The singular value decomposition is used as a data reduction tool to describe the backscattered echoes with a small set of parameters. One of these is strongly correlated with the Doppler spectral width, and can thus be used as a proxy for it. Based on this, we propose a Bayesian classifier for identifying the spectral width boundary, which is classically associated with the Polar Cap boundary. The results are in good agreement with previous studies. Two advantages of the method are: the possibility to apply it in near real-time, and its capacity to select the appropriate threshold level for the boundary detection.

  3. Studies of medium scale travelling ionospheric disturbances using TIGER SuperDARN radar sea echo observations

    Directory of Open Access Journals (Sweden)

    L.-S. He

    2004-12-01

    Full Text Available

    Seasonal and diurnal variations in the direction of propagation of medium-scale travelling ionospheric disturbances (MSTIDs have been investigated by analyzing sea echo returns detected by the TIGER SuperDARN radar located in Tasmania (43.4° S, 147.2° E geographic; –54.6°Λ. A strong dependency on local time was found, as well as significant seasonal variations. Generally, the propagation direction has a northward (i.e. equatorward component. In the early morning hours the direction of propagation is quite variable throughout the year. It then becomes predominantly northwest and changes to northeast around 09:00 LT. In late fall and winter it changes back to north/northwest around 15:00 LT. During the other seasons, northward propagation is very obvious near dawn and dusk, but no significant northward propagation is observed at noon.

    It is suggested that the variable propagation direction in the morning is related to irregular magnetic disturbances that occur at this local time. The changes in the MSTID propagation directions near dawn and dusk are generally consistent with changes in ionospheric electric fields occurring at these times and is consistent with dayside MSTIDs being generated by the Lorentz force.

    Key words. Ionosphere (ionospheric disturbances; wave propagation; ionospheric irregularities; signal processing

  4. Arctic and Antarctic polar mesosphere summer echoes observed with oblique incidence HF radars: analysis using simultaneous MF and VHF radar data

    Directory of Open Access Journals (Sweden)

    T. Ogawa

    2004-12-01

    Full Text Available Polar mesosphere summer echoes (PMSEs have been well studied using vertical incidence VHF radars at northern high-latitudes. In this paper, two PMSE events detected with the oblique incidence SuperDARN HF radars at Hankasalmi, Finland (62.3° N and Syowa Station, Antarctica (69.0° S, are analyzed, together with simultaneous VHF and medium-frequency (MF radar data. Altitude resolutions of the HF radars in the mesosphere and the lower thermosphere are too poor to know exact PMSE altitudes. However, a comparison of Doppler velocity from the HF radar and neutral wind velocity from the MF radar shows that PMSEs at the HF band appeared at altitudes within 80-90km, which are consistent with those from previous vertical incidence HF-VHF radar results. The HF-VHF PMSE occurrences exhibit a semidiurnal behavior, as observed by other researchers. It is found that in one event, PMSEs occurred when westward semidiurnal winds with large amplitude at 85-88km altitudes attained a maximum. When the HF-VHF PMSEs were observed at distances beyond 180km from MF radar sites, the MF radars detected no appreciable signatures of echo enhancement.

    Key words. Meteorology and atmospheric dynamics (middle atmosphere dynamics; thermospheric dynamics; waves and tides

  5. Load leveling efforts of The Hokkaido Electric Power Co. Inc.; Hokkaido Denryoku no fuka heijunka eno torikumi ni tsuite

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    1996-04-01

    The Hokkaido Electric Power Co., Inc., aiming to enhance power generation efficiency through power load levelling, strives to expand and substantiate its electricity billing menu and to popularize and encourage the use of levelling-oriented apparatuses and systems most of which are designed for utilizing midnight power. The billing menu has in it a snow-melting power which is cut off for load levelling during the peak demand time zone. For domestic use, a time zone-specified lighting system named Dream Eight is created, which is one of the billing systems dependent upon time zone. Introduced therein for industrial use is a demand/supply adjustment contract system. Furthermore, in compliance with the amended Electricity Business Law that came into force in 1995, efforts are under way for revising the period wherein power is to be supplied for melting snow, expanding the scope of application of the power supply system dependent upon time zone, and newly introducing a heat accumulation assisted peak adjustment contract system and an operation adjustment contract system. As for business efforts in relation to load levelling, the company proposes household electrical systems centering about 200V high-efficiency apparatuses, electric water warmer contributing to the enhancement of year-round load levelling, popularization and reinforcement of electric snow melting systems, and power utilizing technologies capable of meeting local demands raised for example by agriculture and fishery.

  6. Prevalence of human T-lymphotropic virus type 1 carriers among pregnant women in Hokkaido, Japan.

    Science.gov (United States)

    Yamada, Takahiro; Togashi, Takehiro; Tsutsumi, Hiroyuki; Imamura, Masahiro; Okubo, Hitoshi; Okabe, Mihiro; Takamuro, Noriko; Tashiro, Kunio; Yano, Koichi; Yamamoto, Nagafumi; Hirakawa, Yukiko; Minakami, Hisanori

    2014-08-01

    As there is a risk of MTCT of HTLV-1, the HSGP HTLV-1 MTCT was organized in 2011. To determine how many pregnant women are infected with HTLV-1 in Hokkaido, which is the northernmost and the second largest island in Japan with a population of 5,467,000 and 39,392 newborns in 2011, the HSGP HTLV-1 MTCT asked all facilities that may care for pregnant women in Hokkaido in July 2013 to provide information on the number of pregnant women who underwent screening for anti-HTLV-1 antibody using particle agglutination or chemiluminescent enzyme immunoassay, and the numbers of those with positive, equivocal, and negative test results in the screening and confirmation tests using western blotting or PCR methods in 2012, respectively. A total of 111 facilities participated in this study and provided information on 33,617 pregnant women who underwent screening in 2012, corresponding to approximately 85% of all pregnant women who gave birth in Hokkaido in 2012. Of 81 candidates for a confirmation test because of positive (n = 77) or equivocal (n = 4) results on screening, 63 (78%) underwent the confirmation test and, finally, 34 (0.1%) and 33,563 (99.8%) women were judged to be HTLV-1 carriers and non-carriers, respectively. It was concluded that the prevalence rate of HTLV-1 carriers was low, one per 1000 pregnant women in Hokkaido. Approximately 40 infants are born yearly to mothers infected with HTLV-1 in Hokkaido.

  7. HF Propagation Directions Observed by the e-POP Radio Receiver Instrument

    Science.gov (United States)

    James, H. G.; Perry, G. W.

    2016-12-01

    We have investigated high-frequency (HF) propagation direction measurements by the e-POP Radio Receiver Instrument (RRI) on the CASSIOPE spacecraft. The measurement of the direction of arrival (DOA) of electromagnetic waves propagating in the ionosphere is a desirable technique for the analysis of both spontaneous emissions and waves emitted by ground transmitters. In the case of detection of waves launched by HF radars, DOA evidence at low earth orbit close to regions of (coherent) backscatter may help to understand the details of the physics of scatter of radar waves, by the examination of waves both incident on and scattered by irregularities of density. The RRI has been used to observe direct transmissions from the ground for evaluation of a DOA detection algorithm. Signals are detected with two orthogonal 6-m distributed dipoles on RRI working at frequencies up to about 18 MHz. When ground sources emit electric-field polarisation of one of the Ordinary (O) and Extraordinary (X) cold-plasma modes, the DOA of transmissions propagating near the bore sight of the RRI crossed dipoles can be determined. In the instance of transversely polarized transmissions from a SuperDARN source, the emissions are the sum of the two cold-plasma modes and we depend on differential refraction to temporally resolve the pulsed transmissions into two modes for DOA measurement by the RRI. DOA information can help to confirm the existence of horizontal density gradients that can bend rays away from the great-circle beam paths traditionally assumed in the SuperDARN fields of view.

  8. Detecting Seismicity Rate Transients in the Hokkaido Corner

    Science.gov (United States)

    Llenos, A. L.; McGuire, J. J.; Ogata, Y.

    2009-12-01

    Transient aseismic processes alter the stress state of a region and can cause seismicity rate anomalies in space and time detectable by models such as the Epidemic Type Aftershock Sequence (ETAS) model (Ogata, 1988). The presence of such anomalies in subduction zones can therefore indicate stress changes are occurring due to processes such as afterslip or slow slip events. The Hokkaido corner in northeastern Japan is a good region to investigate these anomalies and their relationship to frictional conditions on the plate interface. This area consists of several asperities that rupture in great earthquakes such as the 2003 M8.3 Tokachi-oki earthquake. The abundance of high quality seismic and geodetic data for that event have led to the development of detailed coseismic and postseismic slip models (e.g., Yamanaka and Kikuchi, 2003; Miyazaki et al., 2004), from which stress changes can be inferred and compared to spatial and temporal variations in seismicity rate behavior. For example, an analysis of central Japan seismicity suggests that high aftershock productivities tend to cluster on the updip boundaries of major asperities (Ogata, 2005). Elevated stressing rates due to afterslip can also cause increased levels of background seismicity on the fault patches where afterslip is occurring. Therefore, mapping where these anomalies occur can lead to a better understanding of where and how stress is accumulating on the megathrust. We have developed a method that can directly map seismicity rate anomalies to the stressing rate changes due to aseismic processes. Because aftershocks often obscure changes in the background seismicity caused by these processes, we combine two models commonly used to estimate the time dependence of underlying driving mechanisms, the stochastic ETAS model and the physically based rate- and state-dependent friction model (Dieterich, 1994), into a single seismicity rate model that can explain both aftershock activity as well as changes in

  9. Crustal temperature structure derived from a ground temperature gradient chart of Hokkaido; Hokkaido no chion kobaizu kara motometa chikakunai ondo kozo

    Energy Technology Data Exchange (ETDEWEB)

    Okubo, Y. [Geological Survey of Japan, Tsukuba (Japan); Akita, F. [Hokkaido Geological Survey, Sapporo (Japan); Nagumo, S. [Oyo Corp., Tokyo (Japan)

    1997-05-27

    The Hokkaido Underground Resources Investigation Institute has prepared in 1995 a detailed temperature gradient chart that shows local anomalies around volcanoes. This paper describes an attempt to derive crustal temperature structure of Hokkaido from the above data. The model was hypothesized as a primary model in which no thermal convection exists. In volcanic and geothermal areas which show a temperature gradient of more than 100 {degree}C km {sup -1}, a solidus temperature is reached at a depth shallower than 10 km. Below the volcanic chain forming the Chishima arc, a partially melted region exists in a width of about 100 km. Most of the areas in the southern Hokkaido have the temperature reached the solidus temperature in the crust. On the other hand, in most of the areas of the forefront side, no solidus temperature is reached in the crust. In the temperature structure of a cross section crossing almost orthogonally with the volcanic front passing through Mt. Daisetsu, a high temperature area reaches to a shallow portion beneath Mt. Daisetsu, where the depth at which the solidus temperature is reached is 10 km or shallower. The range of area where the solidus depth is shallower than 10 km has a south-west width of about 40 km. This means that a partially melted area with a size of 40 km in the horizontal direction exists at a depth of several kilometers. 20 refs., 3 figs.

  10. SuperDARN CUTLASS Finland radar observations of high-latitude magnetic reconnections under northward interplanetary magnetic field (IMF) conditions

    Institute of Scientific and Technical Information of China (English)

    ZHANG QingHe; LIU RuiYuan; YANG HuiGen; HU HongQiao; ZHANG BeiChen; DUNLOP Malcolm; LESTER Mark; BOGDANOVA Yulia; WALSH Andrew

    2012-01-01

    A number of backscatter power enhancement events with “equatorward-moving radar auroral forms” in the high-latitude ionosphere were observed by SuperDARN CUTLASS Finland radar when the IMF was northward during 09:00 -10:00 UT on 26 March 2004.These events were also associated with sunward flow enhancements at each location in the Northern Hemisphere which were shown in ionospheric convections measured by the SuperDARN radars.These are typical features of high-latitude (lobe) magnetic reconnections.The durations of the velocity enhancements imply that the evolution time of the lobe reconnections is about 8-16 min from their origin at the reconnection site to their addition to the magnetotail lobe again.In additional,the Double Star TC-1 spacecraft was moving from magnetosheath into magnetosphere,and crossing the magnetopause near the subsolar region during this interval,and observed typical low-latitude magnetic reconnection signatures.This infers that the dayside high- and low-latitude reconnections may occur simultaneously.

  11. Thermal structure and intermediate-depth seismicity in the Tohoku-Hokkaido subduction zones

    Energy Technology Data Exchange (ETDEWEB)

    Van Keken, P.E. [Michigan Univ., Ann Arbor, MI (United States). Dept. of Earth and Environmental Sciences; Kita, S.; Nakajima, J. [Tohoku Univ., Sendai (Japan). Research Center for Prediction of Earthquakes and Volcanic Eruptions

    2012-07-01

    The cause of intermediate-depth (>40 km) seismicity in subduction zones is not well understood. The viability of proposed mechanisms, which include dehydration embrittlement, shear instabilities and the presence of fluids in general, depends significantly on local conditions, including pressure, temperature and composition. The wellinstrumented and well-studied subduction zone below Northern Japan (Tohoku and Hokkaido) provides an excellent testing ground to study the conditions under which intermediate-depth seismicity occurs. This study combines new finite element models that predict the dynamics and thermal structure of the Japan subduction system with a high-precision hypocenter data base. The upper plane of seismicity is principally contained in the crustal portion of the subducting slab and appears to thin and deepen within the crust at depths >80 km. The disappearance of seismicity overlaps in most of the region with the predicted phase change of blueschist to hydrous eclogite, which forms a major dehydration front in the crust. The correlation between the thermally predicted blueschist-out boundary and the disappearance of seismicity breaks down in the transition from the northern Japan to Kurile arc below western Hokkaido. Adjusted models that take into account the seismically imaged modified upper mantle structure in this region fail to adequately recover the correlation that is seen below Tohoku and eastern Hokkaido. We conclude that the thermal structure below Western Hokkaido is significantly affected by timedependent, 3-D dynamics of the slab. This study generally supports the role of fluids in the generation of intermediate-depth seismicity. (orig.)

  12. High-latitude poynting flux from combined Iridium and SuperDARN data

    Directory of Open Access Journals (Sweden)

    C. L. Waters

    2004-09-01

    Full Text Available Field-aligned currents convey stress between the magnetosphere and ionosphere, and the associated low altitude magnetic and electric fields reflect the flow of electromagnetic energy to the polar ionosphere. We introduce a new technique to measure the global distribution of high latitude Poynting flux, S||, by combining electric field estimates from the Super Dual Auroral Radar Network (SuperDARN with magnetic perturbations derived using magnetometer data from the Iridium satellite constellation. Spherical harmonic methods are used to merge the data sets and calculate S|| for any magnetic local time (MLT from the pole to 60° magnetic latitude (MLAT. The effective spatial resolutions are 2° MLAT, 2h MLT, and the time resolution is about one hour due to the telemetry rate of the Iridium magnetometer data. The technique allows for the assessment of high-latitude net S|| and its spatial distribution on one hour time scales with two key advantages: (1 it yields the net S|| including the contribution of neutral winds; and (2 the results are obtained without recourse to estimates of ionosphere conductivity. We present two examples, 23 November 1999, 14:00-15:00 UT, and 11 March 2000, 16:00-17:00 UT, to test the accuracy of the technique and to illustrate the distributions of S|| that it gives. Comparisons with in-situ S|| estimates from DMSP satellites show agreement to a few mW/m2 and in the locations of S|| enhancements to within the technique's resolution. The total electromagnetic energy flux was 50GW for these events. At auroral latitudes, S|| tends to maximize in the morning and afternoon in regions less than 5° in MLAT by two hours in MLT having S||=10 to 20mW/m2 and total power up to 10GW. The power poleward of the Region 1 currents is about one

  13. Frederiksberg HF kursus

    DEFF Research Database (Denmark)

    Lindstrøm, Maria Duclos

    2008-01-01

    Notatet bygger på et interviewmateriale med dimitterede HF-kursister 3 måneder efter endt eksamen. Notatet undersøger dels, hvad der har hjulpet til at gennemføre, dels hvad der har været negativt og vanskeligt ved uddannelsen. Endvidere belyser notatet hvad kursisterne oplever at tage med fra de...

  14. Validation of the CUTLASS HF radar gravity wave observing capability using EISCAT CP-1 data

    Directory of Open Access Journals (Sweden)

    N. F. Arnold

    Full Text Available Quasi-periodic fluctuations in the returned ground-scatter power from the SuperDARN HF radars have been linked to the passage of medium-scale gravity waves. We have applied a technique that extracts the first radar range returns from the F-region to study the spatial extent and characteristics of these waves in the CUTLASS field-of-view. Some ray tracing was carried out to test the applicability of this method. The EISCAT radar facility at Tromsø is well within the CUTLASS field-of-view for these waves and provides a unique opportunity to assess independently the ability of the HF radars to derive gravity wave information. Results from 1st March, 1995, where the EISCAT UHF radar was operating in its CP-1 mode, demonstrate that the radars were in good agreement, especially if one selects the electron density variations measured by EISCAT at around 235 km. CUTLASS and EISCAT gravity wave observations complement each other; the former extends the spatial field of view considerably, whilst the latter provides detailed vertical information about a range of ionospheric parameters.

    Key words. Ionosphere (ionosphere – atmosphere interactions · Meteorology and atmospheric dynamics (thermospheric dynamics · Radio science (ionospheric propagations

  15. Convertible source system of thermal neutron and X-ray at Hokkaido University electron linac facility

    Science.gov (United States)

    Kamiyama, T.; Hara, K. Y.; Taira, H.; Sato, H.

    2016-11-01

    The convertible source system for the neutron and the X-ray imagings was installed in the 45MeV electron linear accelerator facility at Hokkaido University. The source system is very useful for a complementary imaging. The imaging measurements for a sample were performed with both beams by using a vacuum tube type image intensifier. The enhanced contrast was obtained from the dataset of the radiograms measured with the neutron and X-ray beams.

  16. Tick surveillance for relapsing fever spirochete Borrelia miyamotoi in Hokkaido, Japan.

    Directory of Open Access Journals (Sweden)

    Ai Takano

    Full Text Available During 2012-2013, a total of 4325 host-seeking adult ticks belonging to the genus Ixodes were collected from various localities of Hokkaido, the northernmost island of Japan. Tick lysates were subjected to real-time PCR assay to detect borrelial infection. The assay was designed for specific detection of the Relapsing fever spirochete Borrelia miyamotoi and for unspecific detection of Lyme disease-related spirochetes. Overall prevalence of B. miyamotoi was 2% (71/3532 in Ixodes persulcatus, 4.3% (5/117 in Ixodes pavlovskyi and 0.1% (1/676 in Ixodes ovatus. The prevalence in I. persulcatus and I. pavlovskyi ticks were significantly higher than in I. ovatus. Co-infections with Lyme disease-related spirochetes were found in all of the tick species. During this investigation, we obtained 6 isolates of B. miyamotoi from I. persulcatus and I. pavlovskyi by culture in BSK-M medium. Phylogenetic trees of B. miyamotoi inferred from each of 3 housekeeping genes (glpQ, 16S rDNA, and flaB demonstrated that the Hokkaido isolates were clustered with Russian B. miyamotoi, but were distinguishable from North American and European B. miyamotoi. A multilocus sequence analysis using 8 genes (clpA, clpX, nifS, pepX, pyrG, recG, rplB, and uvrA suggested that all Japanese B. miyamotoi isolates, including past isolates, were genetically clonal, although these were isolated from different tick and vertebrate sources. From these results, B. miyamotoi-infected ticks are widely distributed throughout Hokkaido. Female I. persulcatus are responsible for most human tick-bites, thereby I. persulcatus is likely the most important vector of indigenous relapsing fever from tick bites in Hokkaido.

  17. Asymmetric distribution of the ionospheric electric potential in the opposite hemispheres as inferred from the SuperDARN observations and FAC-based convection model

    DEFF Research Database (Denmark)

    Lukianova, R.; Hanuise, C.; Christiansen, Freddy

    2008-01-01

    -altitude satellites. Both the solar and auroral precipitation contributions are included in order to derive the ionospheric conductance. Taking into account the electrodynamic coupling of the opposite hemispheres, the model allows one to obtain the convection patterns developed simultaneously in both hemispheres......We compare the SuperDARN convection patterns with the predictions of a new numerical model of the global distribution of ionospheric electric potentials. The model utilizes high-precision statistical maps of field-aligned currents (FAC) derived from measurements made by polar-orbiting low...... for given input parameters. SuperDARN, with its database containing global northern and southern convection maps, provides the unique opportunity to compare the model predictions of electric fields with observations. In the present study we focus on the effect of significant interhemispheric asymmetry...

  18. Pulsed inductive HF laser

    Energy Technology Data Exchange (ETDEWEB)

    Razhev, A M; Kargapol' tsev, E S [Institute of Laser Physics, Siberian Branch, Russian Academy of Sciences, Novosibirsk (Russian Federation); Churkin, D S; Demchuk, S V [Novosibirsk State University, Novosibirsk (Russian Federation)

    2016-03-31

    We report the results of experimentally investigated dependences of temporal, spectral and spatial characteristics of an inductive HF-laser generation on the pump conditions. Gas mixtures H{sub 2} – F{sub 2}(NF{sub 3} or SF6{sub 6}) and He(Ne) – H{sub 2} – F{sub 2}(NF{sub 3} or SF{sub 6}) were used as active media. The FWHM pulse duration reached 0.42 μs. This value corresponded to a pulsed power of 45 kW. For the first time, the emission spectrum of an inductive HF laser was investigated, which consisted of seven groups of bands with centres around the wavelengths of 2732, 2736, 2739, 2835, 2837, 2893 and 2913 nm. The cross section profile of the laser beam was a ring with a diameter of about 20 mm and width of about 5 mm. Parameters of laser operation in the repetitively pulsed regime were sufficiently stable. The amplitude instability of light pulses was no greater than 5% – 6%. (lasers)

  19. HF Interference, Procedures and Tools (Interferences HF, procedures et outils)

    Science.gov (United States)

    2007-06-01

    such sources. The existing HF background noise possibly may be increased via ground wave and/or sky wave propagation. Increase of the existing HF...télécommunications filaires à large bande. Les télécommunications via le réseau électrique courant, dites PowerLine Communications (PLT ou PLC) et diverses...cumulative de nombreuses sources de même type. Le bruit de fond HF existant risque d’être augmenté par propagation de l’onde terrestre et/ou aérienne

  20. Quaternary forest and climate history of Hokkaido, Japan, from marine sediments

    Science.gov (United States)

    Igarashi, Yaeko

    Pollen data from Quaternary marine sediments deposited in central Hokkaido, northern Japan provide insight into northeast Asian vegetation and climatic changes over the last few million years. During the Early Pleistocene, coniferous forest, dominated by Picea and Cryptomeria japonica, and taiga composed of Larix and Picea developed under cool/wet and cold/dry climates, respectively. Strong climatic contrasts are inferred from Late Pleistocene interglacial and glacial pollen assemblages which precede the last glacial cycle. In the former, cool temperate broad-leaf forest, mainly composed of Fagus, reflects a warmer and wetter climate than now. In the latter, taiga similar to that now found in northern Sakhalin apparently flourished in Hokkaido. The composition of pollen assemblages correlated with Oxygen Isotope Stage 5, changed from cool temperate forest of Quercus, Ulmus and Juglans (Substage 5e), to Picea-Larix taiga (Substage 5d), cool temperate forest of Quercus and Ulmus (Substage 5c) and Picea-Abies forest (Substage 5b). Compared with present conditions, climate during Stage 5 in northern Japan apparently fluctuated from warmer/wetter to colder/drier. Taiga composed of Picea, Pinus and Larix indicating colder/dry conditions during Stage 4, was replaced by Picea-Abies forest and Picea-Larix taiga in Stage 3, suggesting relatively cool and cold/dry environments. Taiga and mixed forest with taiga and cool temperate components characterize Stage 2. Holocene forests with Juglans-Betula and Quercus-Juglans were succeeded by Picea and Abies during the early Holocene warm interval ˜7000 BP. Subsequently, Quercus-Ulmus and Abies-Alnus assemblages reflect climatic deterioration. 'Pan-mixed' forest has been developed in Hokkaido since 2000 BP.

  1. Flux closure during a substorm observed by Cluster, Double Star, IMAGE FUV, SuperDARN, and Greenland magnetometers

    Directory of Open Access Journals (Sweden)

    S. E. Milan

    2006-03-01

    Full Text Available We examine magnetic flux closure during an extended substorm interval on 29 August 2004 involving a two-stage onset and subsequent re-intensifications. Cluster and Double Star provide observations of magnetotail dynamics, while the corresponding auroral evolution, convection response, and substorm current wedge development are monitored by IMAGE FUV, SuperDARN, and the Greenland magnetometer chain, respectively. The first stage of onset is associated with the reconnection of closed flux in the plasma sheet; this is accompanied by a short-lived auroral intensification, a modest substorm current wedge magnetic bay, but no significant ionospheric convection enhancement. The second stage follows the progression of reconnection to the open field lines of the lobes; accompanied by prolonged auroral bulge and westward-travelling surge development, enhanced magnetic bays and convection. We find that the tail dynamics are highly influenced by ongoing dayside creation of open flux, leading to flux pile-up in the near-tail and a step-wise down-tail motion of the tail reconnection site. In all, 5 dipolarizations are observed, each associated with the closure of ~0.1 GWb of flux. Very simple calculations indicate that the X-line should progress down-tail at a speed of 20 km s-1, or 6 RE between each dipolarization.

  2. Molecular survey of rickettsial agents in feral raccoons (Procyon lotor) in Hokkaido, Japan.

    Science.gov (United States)

    Sashika, Mariko; Abe, Go; Matsumoto, Kotaro; Inokuma, Hisashi

    2010-09-01

    Rickettsial infection in feral raccoons (Procyon lotor) in Hokkaido, Japan was analyzed by molecular methods. Genus-specific nested polymerase chain reaction (PCR) analysis based on the Rickettsia citrate synthase (gltA) gene showed that 13 of 699 raccoons (1.9%) examined were positive for Rickettsia. Twelve of the 13 partial gltA sequence amplicons were successfully analyzed. The nucleotide sequence of one amplicon was identical to both Rickettsia heilongjiangensis and R. japonica, one was identical to R. felis, and the rest to R. helvetica. This is the first report on the detection of rickettsial agents in peripheral blood of raccoons.

  3. Upper boundary of the Pacific plate subducting beneath Hokkaido, Japan, estimated from ScSp phase

    OpenAIRE

    Osada, Kinue; Yoshizawa, Kazunori; YOMOGIDA, Kiyoshi

    2010-01-01

    Three-dimensional geometry of the upper boundary of the Pacific plate subducting beneath Hokkaido, Japan, was obtained using the ScSp phase: the phase converted from ScS (S wave reflected at the core-mantle boundary) to P wave at the plate boundary. Taking the advantage of a dense seismic network, "Hi-net", recently deployed across the Japanese islands, we applied several seismic array analyses to the recorded waveform data for a large nearby deep earthquake, in order to enhance very weak ScS...

  4. Physics education of Japanese national colleges of technology in local community of Hokkaido

    Science.gov (United States)

    Kushino, Akihiro; Matsui, Hidenori

    2014-03-01

    The national colleges of technology in Japan, called KOSEN, were established about 50 years ago aiming to educate 15 to 20 years old students to become engineers who were necessary in period of high economic growth of Japan. In present, environment surrounding us has changed. Examples are low birth rate in Japan and the great earthquake in Tohoku area. There are 4 KOSENs in Hokkaido and we jointly make many efforts to contribute to local community in science. We present our efforts in physics education.

  5. Development of the Experimental Photo-Nuclear Reaction Database in Hokkaido University

    Science.gov (United States)

    Makinaga, A.

    2015-10-01

    Nuclear databases are important tools to apply nuclear phenomena to various fields of nuclear engineering. It is now recognized that the databases must be further developed for photo-nuclear reaction data for nuclear security, safety and nonproliferation applications. Hokkaido University Nuclear Reaction Data Centre (JCPRG) has contributed to the Experimental Nuclear Reaction Data Library (EXFOR) which is developed by the International Network of Nuclear Reaction Data Centres under coordination by IAEA. We report here on the recent compilation of the nuclear data files for the photonuclear reaction.

  6. ON THE LATE OCCURRENCE OF DRIFT ICE RETREAT FROM THE HOKKAIDO COAST IN THE 1992/93 SEA ICE SEASON

    OpenAIRE

    トヨタ, タケノブ; カミヒラ, エツロウ; Takenobu, TOYOTA; Etsuro, KAMIHIRA

    1994-01-01

    The 1992/93 sea ice season in the Sea of Okhotsk was characterized by the record-breaking late appearance and late disappearance of drift ice off the Hokkaido coast. The 1992/93 winter season was rather warm and the arrival of drift ice off the Hokkaido coast was a few weeks later than normal. The averaged amount of drift ice in sight at Kitamiesashi, Omu, Mombetsu, and Abashiri was half of normal. Nevertheless the last dates of drift ice at the four observatories were all in early May, about...

  7. Marburg Hemorrhagic Fever (Marburg HF)

    Science.gov (United States)

    ... CDC Cancel Submit Search The CDC Marburg hemorrhagic fever (Marburg HF) Note: Javascript is disabled or is ... first recognized in 1967, when outbreaks of hemorrhagic fever occurred simultaneously in laboratories in Marburg and Frankfurt, ...

  8. Seasonal changes in spermatogenesis and peripheral testosterone concentration in raccoons (Procyon lotor) in Hokkaido.

    Science.gov (United States)

    Okuyama, Minami W; Shimozuru, Michito; Takahashi, Nobuhiro; Fukui, Daisuke; Nakamura, Ryohei; Tsubota, Toshio

    2012-06-01

    Feral raccoons (Procyon lotor) have been increasing in number since 1979 and are currently subject to pest control in Hokkaido. One of the reasons for the increase in numbers is thought to be the high reproductive potential of raccoons, but little is known about their reproduction. The main aim of this study was to clarify seasonal changes in spermatogenesis and peripheral testosterone concentration of raccoons in Hokkaido. In the present study, external characteristics and histology of the testis and epididymis and the plasma testosterone concentration were investigated in 68 feral, male raccoons culled for pest control and once a month in one live, captive male. The feral males exhibited seasonal changes in spermatogenesis, showing active spermatogenesis in autumn, winter and spring (October-June) with noted spermatogenesis and inactive spermatogenesis in summer (July-September) with lower mean levels of spermatozoa in the cauda epididymis. Even in the inactive period, spermatozoa were observed in about half of the individuals (14/26); therefore, individuals producing spermatozoa existed every month throughout the year. Testosterone concentrations were significantly high in the winter mating season. In the captive male, the testosterone concentrations were low from June to August, and spermatozoa could not be observed from July to September. These results suggest that raccoons exhibit seasonality of reproduction, but the time and duration of spermatogenetic decline varies widely among individuals. This individual variation in the inactive period is a feature of male raccoon reproduction and is unique among seasonally breeding mammals.

  9. P wave azimuthal and radial anisotropy of the Hokkaido subduction zone

    Science.gov (United States)

    Niu, Xiongwei; Zhao, Dapeng; Li, Jiabiao; Ruan, Aiguo

    2016-04-01

    We present the first three-dimensional P wave radial anisotropy tomography of the Hokkaido subduction zone, as well as P wave azimuthal anisotropy and S wave tomography, which are determined by inverting 298,430 P wave and 233,934 S wave arrival times from 14,245 local earthquakes recorded by 344 seismic stations. Our results reveal significant velocity heterogeneity, seismic anisotropy, and upwelling flows beneath the study region. In the mantle wedge, prominent low-velocity (low-V) anomalies exhibit trench-normal fast-velocity directions (FVDs) and a negative radial anisotropy (i.e., vertical velocity > horizontal velocity), which may reflect upwelling mantle flows. Fan-shaped FVDs are found at depths of 65-90 km, and a detailed 3-D mantle flow pattern is revealed, which may be caused by a combination of oblique subduction of the Pacific plate and collision of the Kuril arc with the Honshu arc beneath southern Hokkaido. The radial anisotropy changes at ~100 km depth, which may reflect variations in temperature and fluid conditions there. The subducting Pacific slab exhibits a positive radial anisotropy (i.e., horizontal velocity > vertical velocity), which may reflect the original fossil anisotropy when the Pacific plate formed at the mid-ocean ridge.

  10. Nitrogen digestion and urea recycling in Hokkaido native horses fed hay-based diets.

    Science.gov (United States)

    Obitsu, Taketo; Hata, Hiroshi; Taniguchi, Kohzo

    2015-02-01

    Nitrogen (N) digestion and urea-N metabolism in Hokkaido native horses fed roughage-based diets containing different types and levels of protein sources were studied. Horses (173 ± 4.8 kg) fitted with an ileum cannula were fed four diets consisting of 100% timothy hay (TH), 88% TH and 12% soybean meal (SBM), 79% TH and 21% SBM, and 51% TH and 49% alfalfa hay at 2.2% of body weight. Dietary protein content varied from 5% to 15% of dry matter. Apparent N digestibilities in the pre-cecum and total tract for the TH diet were lower than those for other diets. However, the proportion of post-ileum N digestion to N intake was not affected by the diets. Urea-N production was linearly related to N intake, but gut urea-N entry was not affected by the diets. The proportion of gut urea-N entry to urea-N production tended to be higher for the TH diet (57%) than the two SBM diets (39%). Anabolic use of urea-N entering the gut was not affected by the diets (20-36% of gut urea-N entry). These results indicate that urea-N recycling provides additional N sources for microbial fermentation in the hindgut of Hokkaido native horses fed low-quality roughages.

  11. Transcriptome analysis of predator- and prey-induced phenotypic plasticity in the Hokkaido salamander (Hynobius retardatus).

    Science.gov (United States)

    Matsunami, Masatoshi; Kitano, Jun; Kishida, Osamu; Michimae, Hirofumi; Miura, Toru; Nishimura, Kinya

    2015-06-01

    Predator- and prey-induced phenotypic plasticity is widely observed among amphibian species. Although ecological factors inducing diverse phenotypic responses have been extensively characterized, we know little about the molecular bases of variation in phenotypic plasticity. Larvae of the Hokkaido salamander, Hynobius retardatus, exhibit two distinct morphs: the presence of their prey, Rana pirica tadpoles, induces a broad-headed attack morph, and the presence of predatory dragonfly nymphs (Aeshna nigroflava) induces a defence morph with enlarged external gills and a high tail. To compare the genes involved in predator- and prey-induced phenotypic plasticity, we carried out a de novo transcriptome analysis of Hokkaido salamander larvae exposed to either prey or predator individuals. First, we found that the number of genes involved in the expression of the defence morph was approximately five times the number involved in the expression of the attack morph. This result is consistent with the fact that the predator-induced plasticity involves more drastic morphological changes than the prey-induced plasticity. Second, we found that particular sets of genes were upregulated during the induction of both the attack and defence morphs, but others were specific to the expression of one or the other morph. Because both shared and unique molecular mechanisms were used in the expression of each morph, the evolution of a new plastic phenotype might involve both the co-option of pre-existing molecular mechanisms and the acquisition of novel regulatory mechanisms.

  12. Hf Transition Probabilities and Abundances

    CERN Document Server

    Lawler, J E; Labby, Z E; Sneden, C; Cowan, J J; Ivans, I I

    2006-01-01

    Radiative lifetimes from laser-induced fluorescence measurements, accurate to about +/- 5 percent, are reported for 41 odd-parity levels of Hf II. The lifetimes are combined with branching fractions measured using Fourier transform spectrometry to determine transition probabilities for 150 lines of Hf II. Approximately half of these new transition probabilities overlap with recent independent measurements using a similar approach. The two sets of measurements are found to be in good agreement for measurements in common. Our new laboratory data are applied to refine the hafnium photospheric solar abundance and to determine hafnium abundances in 10 metal-poor giant stars with enhanced r-process abundances. For the Sun we derive log epsilon (Hf) = 0.88 +/- 0.08 from four lines; the uncertainty is dominated by the weakness of the lines and their blending by other spectral features. Within the uncertainties of our analysis, the r-process-rich stars possess constant Hf/La and Hf/Eu abundance ratios, log epsilon (Hf...

  13. Direct determination of IMF B-Y-related cusp current systems, using SuperDARN radar and multiple ground magnetometer data: A link to theory on cusp current origin

    DEFF Research Database (Denmark)

    Amm, O.; Engebretson, M.J.; Greenwald, R.A.

    1999-01-01

    We analyze an ionospheric "enhanced convection event" in the cusp on November 13, 1996, at 1900 UT, by using data of the SuperDARN radar, and of the IMAGE, Greenland, MACCS and CANOPUS magnetometer arrays; and from other magnetometer stations. The event occurs similar to 20 minutes after a transi......We analyze an ionospheric "enhanced convection event" in the cusp on November 13, 1996, at 1900 UT, by using data of the SuperDARN radar, and of the IMAGE, Greenland, MACCS and CANOPUS magnetometer arrays; and from other magnetometer stations. The event occurs similar to 20 minutes after...

  14. Real-Time Ionospheric Plasma Density Estimates in the Polar Cap using Simultaneous Dual Frequency Doppler Measurements at the SuperDARN McMurdo Radar

    Science.gov (United States)

    Spaleta, J.; Bristow, W. A.

    2012-12-01

    SuperDARN radars estimate plasma drift velocities from the Doppler shift observed on signals scattered from field-aligned density irregularities. The radars operate in the range of 8 MHz to 20 MHz and have ray paths covering a wide range of elevation angles, in order to maximize the range over which the scattering conditions are satisfied. Upward-propagating electromagnetic signals in this frequency range can be significantly refracted by the ionospheric plasma. The propagation paths of the refracted signals are bent earthward and at some point along this refracted path propagate perpendicular to the local magnetic field and scatter on the field-aligned density irregularities. The refraction results from gradients of the index of refraction in the ionospheric plasma. The index inside the ionosphere is lower than its free-space value, which depresses the measured line of sight velocity relative to the actual velocity of the plasma. One way to account for the depression of the measured velocity is to estimate the index of refraction in the scattering region by making multiple velocities measurements at different operating frequencies. Together with the appropriate plasma dispersion relations, multiple frequency measurements can be used to construct relations for the index of refraction, plasma density and the line of sight velocity correction factor as functions of frequency weighted measured velocity differences. Recent studies have used frequency-switching events spanning many days during traditional SuperDARN radar operation to build a statistical estimate for index of refraction, which is insensitive to the real-time spatial dynamics of the ionosphere. This statistical approach has motivated the development of a new mode of radar operation that provides simultaneous dual frequency measurements in order to resolve the temporal and spatial dynamics of the index of refraction calculations. Newly-developed multi-channel capabilities available in the SuperDARN radar

  15. A Preliminary Comparison Between SuperDARN Flow Vectors and Equivalent Ionospheric Currents From the GIMA, Greenland, MACCS, THEMIS, CARISMA, and CANMOS Ground Magnetometer Arrays

    Science.gov (United States)

    Kivelson, M. G.; Amm, O.; Weygand, J. M.; Bristow, W. A.; Angelopoulos, V.; Beheshti, B.; Steinmetz, E. S.; Engebretson, M. J.; Murr, D.; Viljanen, A.; Pulkkinen, A.; Gleisner, H.; Mann, I.; Russell, C.

    2009-12-01

    With data from the GIMA, Greenland, MACCs, CARISMA, and CANMOS, and THEMIS ground magnetometer arrays, we obtain maps of equivalent ionospheric currents (EIC) over North America using the state-of-art technique based on SECS (spherical elementary currents systems) developed by Amm and Viljanen [1999] . The EIC maps can be calculated with the same time resolution as the magnetometer data, which is 10 sec. The results thus show in detail the dynamic evolution of the currents over the whole THEMIS ground network. The EIC maps can further be compared and quantitatively combined with near simultaneous images of the THEMIS all sky imager mosaics, SuperDARN RADAR data, and THEMIS spacecraft data. We find using 5 full days of SuperDARN flow vector data obtained during the northern hemisphere winter that the flows, in general, are antiparallel to the EICs. The largest differences from the antiparallel direction appear to occur during moderate to quiet geomagnetic conditions in the midnight sector. These differences are most likely the result of non-uniform conductivity in the ionosphere that influences the EIC direction.

  16. LOCAL INITIATIVES FOR SUSTAINABLE DEVELOPMENT IN RURAL HOKKAIDO: A CASE STUDY OF SAMANI

    Directory of Open Access Journals (Sweden)

    Devon Dublin

    2013-01-01

    Full Text Available The paper presents the results of a field investigation about sustainable development of Samani town—a rural area in Hidaka region, Hokkaido, Japan. Local activities, business, environmental, social and economic challenges that affect the town as well as the advantages were investigated. The research was done by means of field visits, questionnaires and interviews involving the local people and government. The main economic sectors: olivine industry, fishery, agriculture and tourism were targeted as well as the government sector and the local high school with a particular focus on rural-urban migration. Samani has quite unique natural features on hand but a few strong comprehensive challenges on the other hand. The authors focused on the citizens opinions and positions which were based on the uniqueness of Samani and their own local activities and initiatives for the sustainable development of the town in the future which can be replicated in other rural communities around the world.

  17. Seasonal and diurnal variability in historical warming due to the urbanization of Hokkaido, Japan

    Science.gov (United States)

    Sugimoto, Shiori; Sato, Tomonori; Sasaki, Tomonori

    2015-06-01

    The influence of historical urbanization on warming trends observed on Hokkaido Island (Japan) is discussed with an emphasis on seasonally and diurnally differential responses of air temperature to urban effects. Two numerical experiments using past and current land use scenarios successfully simulated the observed temperature trends, showing a greater rate of warming in winter than in summer and a greater increase in daily minimum than daily maximum temperatures. The results suggest that seasonal and diurnal variations in the thermal structure of the planetary boundary layer play a leading role in determining the warming rate of surface air. Under strongly stable stratification, anomalous heating within the urban canopy dissipates into a near-surface shallow layer, resulting in increased daily minimum temperatures during winter. In summer, however, anomalous urban heating due to increased Bowen ratios is attenuated by vertical mixing in the convective daytime boundary layer, suppressing the impact of urban heating on surface warming.

  18. High-resolution seismic attenuation structures beneath Hokkaido corner, northeastern Japan

    Science.gov (United States)

    Kita, S.; Nakajima, J.; Okada, T.; Hasegawa, A.; Katsumata, K.; Asano, Y.; Uchida, N.

    2013-12-01

    1. Introduction In the Hokkaido corner, the Kuril fore-arc sliver collides with the northeastern Japan arc. Using data from the nationwide Kiban seismic network and a temporary seismic network, Kita et al. [2012] determined high-resolution 3D seismic velocity structure beneath this area for deeper understanding of the collision process of two fore-arcs. The results show that a broad low-V zone (crust material) anomalously descends into the mantle wedge at depths of 30-90 km in the west of the Hidaka main thrust. On the other hand, several high-velocity zones having velocities of mantle materials are distributed in the crust at depths of 10-35 km. These high-velocity zones are inclined eastward, being nearly parallel to each other. Two of the western boundaries of these high-V zones correspond to the fault planes of the 1970 Mj 6.7 Hidaka and the 1982 Mj 7.1 Urakawa-oki earthquakes, respectively. In this study, we merged waveform data from the Kiban-network and from a dense temporary seismic network [Katsumata et al., 2002], and estimated the seismic attenuation structure to compare with the seismic velocity images of Kita et al. [2012]. 2. Data and method We estimated corner frequency for each earthquake by the spectral ratio method using the coda waves [e.g. Mayeda et al., 2007]. Then, we simultaneously determined values of t* and the amplitude level at lower frequencies from the observed spectra after correcting for the source spectrum. Seismic attenuation (Q-1 value) structure was obtained, inverting t* values with the tomographic code of Zhao et al. [1992]. We adopted the geometry of the Pacific plate which was precisely estimated by Kita et al. [2010b]. The study region covers an area of 41-45N, 140.5-146E, and a depth range of 0-200 km. We obtained 131,958 t* from 6,186 events (M>2.5) that occurred during the period from Aug. 1999 to Dec. 2012. The number of stations used is 353. Horizontal and vertical grid nodes were set with spacing of 0.10-0.3 degree and

  19. My Vision in Teaching at Health Sciences University of Hokkaido, Japan

    Directory of Open Access Journals (Sweden)

    Satomi Kondo

    2003-11-01

    Full Text Available This spring, I returned to my home country after eleven years of living in Vancouver, Canada. I worked as a music therapist at an acute care hospital and experienced music therapy to be a very important means to integrate cure and care in a medical setting. With my ever growing passion and wonder over the power of music, I now work at Health Sciences University of Hokkaido teaching the potency of music to a variety of health care students. I would like to share my experiences and in part some of the characteristics of this particular university that strive for new ideas of health sciences on the basis of integration of cure and care.

  20. Applying ICESat/GLAS data to estimate forest aboveground biomass on Hokkaido, Japan

    Science.gov (United States)

    Hayashi, M.; Saigusa, N.; Oguma, H.; Yamao, Y.; Yamagata, Y.; Takao, G.

    2013-12-01

    Spaceborne Light Detection And Ranging (LiDAR) has an ability to measure forest resources with high accuracy, therefore, it will contribute to evaluating global carbon cycle or addressing climate change. We then evaluated the potential of spaceborne LiDAR to measure forest resources, and used Geoscience Laser Altimeter System (GLAS) data obtained with the Ice, Cloud, and land Elevation Satellite (ICESat) to develop an estimation methodology for forest biomass. The study area was the island of Hokkaido, Japan. We compared two estimation methods: (i) a direct method that uses some of the GLAS waveform parameters to estimate aboveground biomass (AGB) directly, and (ii) an allometric method that uses an allometric equation to estimate AGB from the canopy height estimated from the GLAS waveform. We used two kinds of ground truth data: (i) field survey data in situ measurements of AGB by the Bitterlich method at 106 points within GLAS footprints, and (ii) airborne LiDAR data from maximum canopy height measurements at 481 points within GLAS footprints. We then used the field survey data to develop the AGB estimation equation of the direct method by carrying out a multiple regression analysis that related GLAS waveform parameters to AGB. For the allometric method, we also carried out a multiple regression analysis using the airborne LiDAR data to estimate canopy height from GLAS data. Two parameters were used as the explanatory variables: a 'terrain index' calculated from the ground elevation difference within a GLAS footprint, and a 'GLAS waveform extent'. The root mean square error (RMSE) of the canopy height estimates was 4.1 m. We used the allometric equation determined from the field survey data to relate canopy height to AGB and then estimated the AGB from the GLAS estimates of canopy height. The accuracy of the AGB estimates obtained by these two estimation methods was determined by comparison with the field survey data. The RMSEs of the direct and allometric

  1. Genetic and antigenic characterization of bovine viral diarrhea viruses isolated from cattle in Hokkaido, Japan.

    Science.gov (United States)

    Abe, Yuri; Tamura, Tomokazu; Torii, Shiho; Wakamori, Shiho; Nagai, Makoto; Mitsuhashi, Kazuya; Mine, Junki; Fujimoto, Yuri; Nagashima, Naofumi; Yoshino, Fumi; Sugita, Yukihiko; Nomura, Takushi; Okamatsu, Masatoshi; Kida, Hiroshi; Sakoda, Yoshihiro

    2016-01-01

    In our previous study, we genetically analyzed bovine viral diarrhea viruses (BVDVs) isolated from 2000 to 2006 in Japan and reported that subgenotype 1b viruses were predominant. In the present study, 766 BVDVs isolated from 2006 to 2014 in Hokkaido, Japan, were genetically analyzed to understand recent epidemics. Phylogenetic analysis based on nucleotide sequences of the 5'-untranslated region of viral genome revealed that 766 isolates were classified as genotype 1 (BVDV-1; 544 isolates) and genotype 2 (BVDV-2; 222). BVDV-1 isolates were further divided into BVDV-1a (93), 1b (371) and 1c (80) subgenotypes, and all BVDV-2 isolates were grouped into BVDV-2a subgenotype (222). Further comparative analysis was performed with BVDV-1a, 1b and 2a viruses isolated from 2001 to 2014. Phylogenetic analysis based on nucleotide sequences of the viral glycoprotein E2 gene, a major target of neutralizing antibodies, revealed that BVDV-1a, 1b and 2a isolates were further classified into several clusters. Cross-neutralization tests showed that BVDV-1b isolates were antigenically different from BVDV-1a isolates, and almost BVDV-1a, 1b and 2a isolates were antigenically similar among each subgenotype and each E2 cluster. Taken together, BVDV-1b viruses are still predominant, and BVDV-2a viruses have increased recently in Hokkaido, Japan. Field isolates of BVDV-1a, 1b and 2a show genetic diversity on the E2 gene with antigenic conservation among each subgenotype during the last 14 years.

  2. Magnetic local time, substorm, and particle precipitation-related variations in the behaviour of SuperDARN Doppler spectral widths

    Directory of Open Access Journals (Sweden)

    M. L. Parkinson

    2004-12-01

    Full Text Available Super Dual Auroral Radar Network (DARN radars often detect a distinct transition in line-of-sight Doppler velocity spread, or spectral width, from <50ms–1 at lower latitude to >200ms–1 at higher latitude. They also detect a similar boundary, namely the range at which ionospheric scatter with large spectral width suddenly commences (i.e. without preceding scatter with low spectral width. The location and behaviour of the spectral width boundary (SWB (and scatter boundary and the open-closed magnetic field line boundary (OCB are thought to be closely related. The location of the nightside OCB can be inferred from the poleward edge of the auroral oval determined using energy spectra of precipitating particles measured on board Defence Meteorology Satellite Program (DMSP satellites. Observations made with the Halley SuperDARN radar (75.5° S, 26.6° W, geographic; –62.0°Λ and the Tasman International Geospace Environment Radar (TIGER (43.4° S, 147.2° E; –54.5°Λ are used to compare the location of the SWB with the DMSP-inferred OCB during 08:00 to 22:00 UT on 1 April 2000. This study interval was chosen because it includes several moderate substorms, whilst the Halley radar provided almost continuous high-time resolution measurements of the dayside SWB location and shape, and TIGER provided the same in the nightside ionosphere. The behaviour of the day- and nightside SWB can be understood in terms of the expanding/contracting polar cap model of high-latitude convection change, and the behaviour of the nightside SWB can also be organised according to substorm phase. Previous comparisons with DMSP OCBs have proven that the radar SWB is often a reasonable proxy for the OCB from dusk to just past midnight (Chisham et al., 2004. However, the present case study actually suggests that the nightside SWB is often a better proxy for the poleward edge of Pedersen conductance enhanced by hot particle precipitation in the

  3. SuperDARN studies of the ionospheric convection response to a northward turning of the interplanetary magnetic field

    Directory of Open Access Journals (Sweden)

    J. R. Taylor

    Full Text Available The response of the dayside ionospheric flow to a sharp change in the direction of the interplanetary magnetic field (IMF measured by the WIND spacecraft from negative Bz and positive By, to positive Bz and small By, has been studied using SuperDARN radar, DMSP satellite, and ground magnetometer data. In response to the IMF change, the flow underwent a transition from a distorted twin-cell flow involving antisunward flow over the polar cap, to a multi-cell flow involving a region of sunward flow at high latitudes near noon. The radar data have been studied at the highest time resolution available (~2 min to determine how this transition took place. It is found that the dayside flow responded promptly to the change in the IMF, with changes in radar and magnetic data starting within a few minutes of the estimated time at which the effects could first have reached the dayside ionosphere. The data also indicate that sunward flows appeared promptly at the start of the flow change (within ~2 min, localised initially in a small region near noon at the equatorward edge of the radar backscatter band. Subsequently the region occupied by these flows expanded rapidly east-west and poleward, over intervals of ~7 and ~14 min respectively, to cover a region at least 2 h wide in local time and 5° in latitude, before rapid evolution ceased in the noon sector. In the lower latitude dusk sector the evolution extended for a further ~6 min before quasi-steady conditions again prevailed within the field-of-view. Overall, these observations are shown to be in close conformity with expectations based on prior theoretical discussion, except for the very prompt appearance of sunward flows after the onset of the flow change.

    Key words. Ionosphere (Auroral ionosphere · Magnetospheric physics (Magnetopause · cusp · and boundary layers; Magnetosphere · ionosphere interaction

  4. Application of tritium in precipitation and baseflow in Japan: a case study of groundwater transit times and storage in Hokkaido watersheds

    OpenAIRE

    Gusyev, Maksym A.; Morgenstern, Uwe; Stewart, Michael K.; Yamazaki, Yusuke; Kashiwaya, Kazuhisa; Nishihara, Terumasa; Kuribayashi, Daisuke; Sawano, Hisaya; Iwami, Yoichi

    2016-01-01

    In this study, we demonstrate the application of tritium in precipitation and baseflow to estimate groundwater transit times and storage volumes in Hokkaido, Japan. To establish the long-term history of tritium concentration in Japanese precipitation, we used tritium data from the global network of isotopes in precipitation and from local studies in Japan. The record developed for Tokyo area precipitation was scaled for Hokkaido using tritium values for precipitation based o...

  5. Accumulation properties of inorganic mercury and organic mercury in the red-crowned crane Grus japonensis in east Hokkaido, Japan.

    Science.gov (United States)

    Teraoka, Hiroki; Okamoto, Erika; Kudo, Moe; Nakayama, Shouta M M; Ikenaka, Yoshinori; Ishizuka, Mayumi; Endo, Tetsuya; Kitazawa, Takio; Hiraga, Takeo

    2015-12-01

    The red-crowned (Japanese) crane Grus japonensis is native to east Hokkaido, Japan, in contrast to the East Asia mainland. Previously, we reported that red-crowned cranes in Hokkaido were highly contaminated with mercury in the 1990s and that the contamination rapidly decreased to a moderate level in the 2000s. In the present study, we determined levels of organic mercury (O-Hg) in the liver and kidney of cranes in east Hokkaido in comparison with levels of total mercury (T-Hg). T-Hg levels in the kidneys were higher than those in the livers in adults but not in subadults and juveniles; however, the reverse was the case for O-Hg even for adults. The ratio of O-Hg to T-Hg in both the liver and kidney decreased as T-Hg increased in the three developmental stages. While the ratios of O-Hg to T-Hg in the liver and kidney of adults were significantly lower than those of juveniles, the ratios were similar for adults and juveniles in a lower range of T-Hg. The ratio of selenium (Se) to T-Hg decreased as T-Hg increased in both the liver and kidney, irrespective of stages. Mercury burdens in feathers were about 59% and 67% of the total body burdens for juveniles and adults, respectively. Furthermore, ratios of carbon and nitrogen stable isotopes to T-Hg varied greatly, with no relation to mercury level in the liver. The results suggest slow accumulation of inorganic mercury in the kidney of red-crowned cranes in east Hokkaido, Japan.

  6. Shallow repeating slow-slip-events along the convergent block boundary in northern Hokkaido, Japan

    Science.gov (United States)

    Ikeda, S.; Heki, K.; Kimura, T.

    2015-12-01

    The Japanese Islands are divided into several crustal blocks [e.g. Loveless and Meade, 2010 JGR]. In the Northern Hokkaido, the boundary between the Amurian and the North American Plates run north-south between 44.0N and 45.4N. The east-west block convergence is considered to be as fast as ~1 cm/year there, but few large earthquakes are known to have occurred along this boundary. Recently, a slow slip event (SSE) is reported to have occurred in a segment at ~45.0N over a 4 months period from 2012 summer to the early 2013 [Ohzono et al., 2014 GJI]. The maximum surface movements was about 15 mm, and the moment magnitude of the SSE would not exceed 6.0 (fault slip is estimated as 10 cm). This suggests that plate convergence takes place as episodic SSEs in this block boundary. In this research, we looked for signatures of repeating SSEs along this block boundary using continuous GNSS data of the dense array GEONET in Japan. In order to detect faint signatures of SSEs in the coordinate time series, we adopted the method using AIC (Akaike's Information Criterion) similar to Nishimura et al. [2013 JGR] and Nishimura [2014 PEPS]. As a result, we were able to find numbers of SSE signals in various segments along the boundary. The detected SSEs are all fairly small, and surface movements did not exceed a few millimeters (except the 2012-2013 SSE reported in Ohzono et al. [2014]). We also searched earthquakes that may have triggered these SSEs. Although the 2012 SSE seems to have been triggered by a deep earthquake beneath Sakhalin on Aug. 14, 2012, no clear triggering earthquakes were identified for other SSEs. SSEs in subduction zones are known to recur fairly regularly, e.g. biannually repeating SSE in the SW part of the Ryukyu Arc [Heki and Kataoka, 2008 JGR]. However, shallow SSEs along the block boundary in the northern Hokkaido did not show such regular occurrences. We plan to confirm these SSE occurrences by comparing GNSS data with the Hi-Net tiltmeter records.

  7. Magnetotelluric Study on the Donan Geothermal Field, Southern Part of Hokkaido, Japan

    Science.gov (United States)

    Hayakawa, M.; Mogi, T.

    2016-12-01

    We performed a MT study in the Donan geothermal field where deep seated hot granitic rocks are distributing as a source of geothermal resources. But no prominent fracture zone were found in this area. Imaging a fracture zone and clarifying geothermal reservoirs are purpose of the study. Quaternary volcanoes, such as Hokkaido Komagatake and Esan in the southern part, and Karibayama in the northern part, are situated in the surroundings of the Donan area, southwestern Hokkaido, Japan. Even though recent volcanic activity is not seen in the central part, geothermal gradient is high. The geological structure of this region is dominated by the movement of basement blocks aligning in the north-south, and folds and fractures have developed. Many hot springs and geothermal manifestations are seen in this region where called "Yakumo-Nigorikawa geothermal zone." The Mori geothermal power plant, located at south area, is operating in the Nigorikawa caldera formed about 12,000 years ago. Like Nigorikawa, the Yakumo area, located at the central part of the Donan area, have been thought as promising geothermal area, and many geothermal study were performed in the 1990th. Six drilling holes were excavated and they showed that hot granitic rock are distributing at around below 1000m depth, and temperature is higher than 200 degrees in this area. We carried out new magnetotelluric (MT) survey at 20 stations in the Yakumo area. We constructed 2-D and 3-D resistivity model with MT data. Because the anomalous phases exceeding 90 degree were seen in some sites at frequency less than 0.1Hz, we only used the data at frequency range of 320Hz and 0.1Hz in this study. We used Ogawa and Uchida (1996) as a 2D inversion and Han et al. (2008) that have applied approximate sensitivity, as 3D inversion respectively. From the resistivity models, the remarkable low resistivity zone extending from deep to shallower is seen at the center of the survey area, that is inclined from south to north. A

  8. Environmentally friendly HF (DF) lasers

    Science.gov (United States)

    Apollonov, V. V.

    2016-08-01

    Dedicated to the 100th anniversary of the birth of Academician A M Prokhorov, this paper reviews the physics of self-sustained volume discharge without preionization—self-initiated volume discharge (SIVD)—in the working mixtures of non-chain hydrofluoride HF (deuterofluoride (DF)) lasers. The dynamics of SIVD in discharge gaps with different geometries is thoroughly described. The mechanisms for the restriction of current density in a diffuse channel in electric discharges in SF6 and SF6 based mixtures (which determines whether SIVD is possible) are proposed and analyzed using simple models. The most probable mechanisms are the electron impact dissociation of SF6 and other mixture components, electron-ion recombination and electron attachment to vibrationally excited SF6 molecules. Starting from a comparative analysis of the rate coefficients of these processes, it is shown that electron-ion recombination is capable of compensating for electron detachment from negative ions via electron impact. It is also established that SIVD is not only observed in SF6, but also in other strongly electronegative gases. The factors that determine the uniformity of the active medium in non-chain HF (DF) lasers are analyzed. Some special features of non-chain HF (DF) lasers with different apertures operating are carefully examined. Consideration is given to the problem of increasing the aperture and discharge volume of non-chain HF (DF) lasers. Based on our experimental results, the possibility of increasing the energy of such lasers to ~1 kJ and above is shown.

  9. Plasma modifications induced by an X-mode HF heater wave in the high latitude F region of the ionosphere

    Science.gov (United States)

    Blagoveshchenskaya, N. F.; Borisova, T. D.; Yeoman, T. K.; Rietveld, M. T.; Häggström, I.; Ivanova, I. M.

    2013-12-01

    We presented experimental results of strong plasma modifications induced by X-mode powerful HF radio waves injected towards the magnetic zenith into the high latitude F region of the ionosphere. The experiments were conducted in 2009-2011 using the EISCAT Heating facility, UHF incoherent scatter radar and the EISCAT ionosonde at Tromsø, Norway; and the CUTLASS SuperDARN HF coherent radar at Hankasalmi, Finland. The results showed that the X-mode HF pump wave can generate strong small-scale artificial field aligned irregularities (AFAIs) in the F region of the high-latitude ionosphere. These irregularities, with spatial scales across the geomagnetic field of the order of 9-15 m, were excited when the heater frequency (fH) was above the ordinary-mode critical frequency (foF2) by 0.1-1.2 MHz. It was found that the X-mode AFAIs appeared between 10 s and 4 min after the heater is turned on. Their decay time varied over a wide range between 3 min and 30 min. The excitation of X-mode AFAIs was accompanied by electron temperature (Te) enhancements and an increase in the electron density (Ne) depending on the effective radiated power (ERP). Under ERPs of about 75-180 MW the Te enhances up to 50% above the background level and an increase in Ne of up to 30% were observed. Dramatic changes in the Te and Ne behavior occurred at effective radiated powers of about 370-840 MW, when the Ne and Te values increased up to 100% above the background ones. It was found that AFAIs, Ne and Te enhancements occurred, when the extraordinary-mode critical frequency (fxF2) lied in the frequency range fH-fce/2≤fxF2≤fH+fce/2, where fce is the electron gyrofrequency. The strong Ne enhancements were observed only in the magnetic field-aligned direction in a wide altitude range up to the upper limit of the UHF radar measurements. In addition, the maximum value of Ne is about 50 km higher than the Te enhancement peak. Such electron density enhancements (artificial ducts) cannot be explained by

  10. Multifidelity Sparse-Grid-Based Uncertainty Quantification for the Hokkaido Nansei-oki Tsunami

    Science.gov (United States)

    de Baar, Jouke H. S.; Roberts, Stephen G.

    2017-08-01

    With uncertainty quantification, we aim to efficiently propagate the uncertainties in the input parameters of a computer simulation, in order to obtain a probability distribution of its output. In this work, we use multi-fidelity sparse grid interpolation to propagate the uncertainty in the shape of the incoming wave for the Okushiri test-case, which is a wave tank model of a part of the 1993 Hokkaido Nansei-oki tsunami. An important issue with many uncertainty quantification approaches is the `curse of dimensionality': the overall computational cost of the uncertainty propagation increases rapidly when we increase the number of uncertain input parameters. We aim to mitigate the curse of dimensionality by using a multifidelity approach. In the multifidelity approach, we combine results from a small number of accurate and expensive high-fidelity simulations with a large number of less accurate but also less expensive low-fidelity simulations. For the Okushiri test-case, we find an improved scaling when we increase the number of uncertain input parameters. This results in a significant reduction of the overall computational cost. For example, for four uncertain input parameters, accurate uncertainty quantification based on only high-fidelity simulations comes at a normalised cost of 219 high-fidelity simulations; when we use a multifidelity approach, this is reduced to a normalised cost of only 10 high-fidelity simulations.

  11. Persistent organic pollutants in red-crowned cranes (Grus japonensis) from Hokkaido, Japan.

    Science.gov (United States)

    Kakimoto, Kensaku; Akutsu, Kazuhiko; Nagayoshi, Haruna; Konishi, Yoshimasa; Kajimura, Keiji; Tsukue, Naomi; Yoshino, Tomoo; Matsumoto, Fumio; Nakano, Takeshi; Tang, Ning; Hayakawa, Kazuichi; Toriba, Akira

    2017-09-01

    The red-crowned crane (Grus japonensis) from eastern Hokkaido is classified as a Special Natural Monument in Japan. In this study, we determined the concentrations of persistent organic pollutants (POPs) in red-crowned crane muscle tissues (n = 47). Polychlorinated biphenyls (PCBs) had the highest median concentration (240ng/g lipid weight), followed by dichlorodiphenyltrichloroethane and its metabolites (DDTs) (150ng/g lipid weight), chlordane-related compounds (CHLs) (36ng/g lipid weight), hexachlorobenzene (HCB) (16ng/g lipid weight), hexachlorocyclohexanes (HCHs) (4.4ng/g lipid weight), polybrominated diphenyl ethers (PBDEs) (1.8ng/g lipid weight), and finally, Mirex (1.5ng/g lipid weight). Additionally, a positive correlation was found among POP concentrations. No sex differences beyond body parameters were observed. Additionally, red-crowned cranes exhibited a high enantiomeric excess of (+)-alpha-HCH, with enantiomer fractions varying from 0.51 to 0.87 (average: 0.69). Copyright © 2017 Elsevier Inc. All rights reserved.

  12. Molecular survey of Anaplasma and Ehrlichia infections of feral raccoons (Procyon lotor) in Hokkaido, Japan.

    Science.gov (United States)

    Sashika, Mariko; Abe, Go; Matsumoto, Kotaro; Inokuma, Hisashi

    2011-04-01

    Infection by Anaplasma and Ehrlichia in feral raccoons (Procyon lotor) in Hokkaido, Japan, was examined by molecular methods. A polymerase chain reaction (PCR) screen for Anaplasmataceae, based on 16S rRNA, showed that 38 (5.4%) of 699 raccoons examined were positive. These 38 positive samples were examined for Anaplasma phagocytophilum, Anaplasma bovis, Ehrlichia chaffeensis, and Ehrlichia canis infection by species-specific nested PCR. Nested PCR results indicated that 36 of the 38 samples were positive for A. bovis. All 38 samples were PCR negative for A. phagocytophilum, E. chaffeensis, and E. canis. This is the first report of the detection of A. bovis in the peripheral blood of raccoons. A total of 124 raccoons were infested with ticks, including Ixodes ovatus, Ixodes persulcatus, and Haemaphysalis spp. The rate of A. bovis infection in raccoons infested with Haemaphysalis spp. (46.7%, 7/15) was significantly higher than that in raccoons without Haemaphysalis spp. infestation (3.7%, 4/109, p raccoons infested with I. ovatus or I. persulcatus and those not so infested. A total of four ticks (two males and two nymphs) and one larval pools from four raccoons showed positive for A. bovis-specific nested PCR. This results support the correlation between the A. bovis infection of raccoons and Haemaphysalis infestation. In conclusion, raccoons could be possible reservoir animals for A. bovis, and A. bovis infection in raccoons may be related to infestation with Haemaphysalis spp.

  13. Endogenous growth of a Miocene submarine dacite cryptodome, Rebun Island, Hokkaido, Japan

    Science.gov (United States)

    Goto, Yoshihiko; McPhie, Jocelyn

    1998-09-01

    Momo-iwa, Rebun Island, Hokkaido, Japan, is a dacite cryptodome 200-300 m across and 190 m high. The dome is inferred to have intruded wet, poorly consolidated sediment in a shallow marine environment. The internal structure of the dome is concentric, with a massive core, banded rim, and narrow brecciated border, all of which are composed of compositionally uniform feldspar-phyric dacite. Boundaries between each of the zones are distinct but gradational. The massive core consists of homogeneous coherent (unfractured) dacite and is characterized by radial columnar joints 60-200 cm across. The banded rim encircles the massive core and is 40 m wide. It is characterized by large-scale flow banding parallel to the dome surface. The flow banding comprises alternating partly crystalline and more glassy bands 80-150 cm thick. The outermost brecciated border is up to 80 cm thick, and consists of in situ breccia and blocky peperite. The in situ breccia comprises polyhedral dacite clasts 5-20 cm across and a cogenetic granular matrix. The blocky peperite consists of polyhedral dacite clasts 0.5-2 cm across separated by the host sediment (mudstone). The internal structures of the dome suggest endogenous growth involving a continuous magma supply during a single intrusive phase and simple expansion from the interior. Although much larger, the internal structures of Momo-iwa closely resemble those of lobes in subaqueous felsic lobe-hyaloclastite lavas.

  14. Object-Based Analysis and Change Detection of Paddy Field at Hokkaido, Japan

    Science.gov (United States)

    PARK, J.; Kim, Y.; Kwak, Y.

    2015-12-01

    Remote sensing technology has been used in land use and land cover classification. Especially paddy fields is an important cultivated area in Asia. To accurately extract the area is the important indicator to estimate the food production. In this research paddy fields classification in Hokkaido was performed using Topographical features (DEM), Climatic features (accumulated temperature), Spectrometer features (MODIS). Fig. 1. shows the overview of the analysis methods of this research. The process of this research is carried out in 3 steps.1. Determine the accumulated temperature by retrieving the temperature data from the AMeDAS data. 2. Extract the river from the DEM. Set the elevation of the river to 0 to seek the land elevation around it relatively. 3. Calculate the WI (Water Index) using MODIS band 4(Green)and Band 2(NIR). Time series NDVI has been corrected by the FFT method (use a low-pass filter). Phenology information was extracted such as vegetation Onset time, Max value and Duration. Result of the classification was compared with the current vegetation map of the Ministry of the Environment. As a result we can confirm that existence of vegetation map around Sapporo and Asahikawa is almost same. but around Obihiro it was clear that overestimate by water index.

  15. Estimating eroded soil and predicting further erosion in Daisetsuzan National Park in Hokkaido, Japan

    Science.gov (United States)

    Kobayashi, Yusuke; Watanabe, Teiji

    2017-04-01

    This study has three objectives: (1) to estimate changes of the eroded volume of mountain trails from 2014 to 2016 by making DSMs, (2) to understand a relationship between the trail erosion and micro-topography, and (3) to predict the volume of soil that can be eroded in future. Trail erosion has been investigated near Mt. Hokkai-dake in Daisetzuzan National Park, Hokkaido, northern Japan, with a drone (UAV) from 2014 to 2016. Seven segments with the soil erosion from starting sites to ending sites were selected to make DSMs and Orthophotographs by Agisoft, which is one of the Structure from Motion (SfM) software. Then, at fourteen points in each of the seven segments were selected to estimate the volume of soil that can be eroded in the future by PANDA2, a soil compaction penetrometer. The eroded volume in the segment with the largest eroded value attained 274.67 m3 for the two-year period although extremely heavy rain hit this area in the 2016 summer. The result obtained by PANDA2 shows that soil more than 100 cm in depth will be potentially eroded at four points in three years to one hundred years.

  16. Morphology and possible origins of near-range oblique HF backscatter at high and midlatitudes

    Science.gov (United States)

    Ponomarenko, Pavlo, V.; Iserhienrhien, Blessing; St.-Maurice, Jean-Pierre

    2016-06-01

    High-frequency radars (HF, ˜10-20 MHz) forming the Super Dual Auroral Radar Network (SuperDARN) regularly observe returns from very close ranges of ≤300-400 km (near-range echoes, NREs). These echoes are conventionally attributed to backscatter from meteor trails, but other sources of NRE have been invoked, including polar mesospheric summer echoes (PMSE), and non-field-aligned E region irregularities leading to high-aspect ionospheric returns. In order to relate NRE to a particular mechanism, it is essential to establish beforehand their spatiotemporal trends with respect to season, local time, and latitude. Systematic information of this kind is generally lacking from the literature, so we attempt to fill the gap by performing a statistical analysis of such echoes observed by five radars covering midlatitudes to polar latitudes over all seasons and local times. We detected two major echo populations which were observed at each radar site: (i) a nightside-early morning returns representing the well-known meteor backscatter and (ii) a midsummer population centered near the local noon. At high latitudes the summer daytime echoes are usually interpreted as PMSE, but the observed population extends to much lower latitudes and is centered well above the conventional PMSE height range. We hypothesize that this population could be related to neutral turbulence in the lower E region. In addition, there was a pronounced evening population restricted to the auroral region which we provisionally attribute to irregularities generated by the precipitating energetic particles and strong electric fields.

  17. A thirty second isomer in Hf-171

    NARCIS (Netherlands)

    Campbell, P; Billowes, J; Cochrane, ECA; Cooke, JL; Cooper, TG; Dendooven, P; Evans, DE; Grant, IS; Griffith, JAR; Honkanen, A; Huhta, M; Oinonen, M; Pearson, MR; Penttila, H; Persson, B.L.; Richardson, DS; Tungate, G; Wheeler, PD; Zybert, L; Aysto, J

    1997-01-01

    An isomer has been detected in Hf-171 with a half-life of T-1/2 = 29.5(9) s. The state was populated in the Yb-170(alpha,3n)Hf-171m reaction at a beam energy of E-alpha = 50 MeV in an on-line ion guide isotope separator. The isomeric Hf-17lm(+) beam was extracted from the ion guide, mass-analysed an

  18. Rb-Sr geochronological study on Tatehira granodiorite, Oshima Peninsula, Southwest Hokkaido, Japan

    Energy Technology Data Exchange (ETDEWEB)

    Iizumi, Shigeru; Kobayashi, Hideo; Toyoda, Minoru

    1984-10-01

    It has been known that Tatehira granodiorite, a pluton which occurs sporadically in the southwest region of Hokkaido, is related with Kanoite formation. The radiometric age of this granodiorite still remains unknown. The Tatehira granodiorite intrudes into late Paleozoic or early Mesozoic Matsumae group, and is overlain by Miocene Usubetsu formation unconformably. It occurs as several separated small plutons. The samples for Rb-Sr analysis were collected from one of the plutons in southern part. The determination of the isochron age of rock-minerals and the initial Sr isotopic ratio of Tatehira granodiorite were carried out. This granodiorite is able to be classified into two phases, namely melanocratic (WRM) and leucocratic (WRL) phases. The samples of WRM and WRL were powdered and subjected to X-ray analysis. It was found that the chemical compositions were similar except slight differences in FeO + Fe2O3, CaO and K2O. The Sr isotopic ratio was determined with a MAT 261 mass spectrometer, and the results were analyzed statistically. The Rb and Sr concentrations and the Sr isotopic ratio of WRM, WRL, and PRF (plagio-clase rich fraction) and BRF (biotite rich fraction) separated from the WRL were determined, and the age of 102.5 +- 0.3 Ma and the initial ratio of 0.70538 +- 0.00001 were obtained. The ratio of Tatehira granodiorite is comparable to that of Okushiri Island. Comparing with the data obtained from other region, the granodiorites of Tatehira and Okushiri Island should be related with the granitoids of Abukuma granite province.

  19. Formation processes of the 1909 Tarumai and the 1944 Usu lava domesin Hokkaido, Japan

    Directory of Open Access Journals (Sweden)

    I. Yokoyama

    2004-06-01

    Full Text Available The formation of the two particular lava domes in Hokkaido, Japan is described and interpreted mainly from geophysical viewpoints. The 1909 eruption of Tarumai volcano was not violent but produced a lava dome over four days. The growth rate of the dome is discussed under the assumption that the lava flow was viscous and plastic fluid during its effusion. By Hagen-Poiseuille?s Law, the length of the conduit of the lava dome is rather ambiguously determined as a function of viscosity of the magma and diameter of the conduit. The 1944 Usu dome extruded as a parasitic cone of Usu volcano, not in the crater, but in a flat cornfield at the foot of the volcano. From the beginning to the end for more than 17 months, seismometric and geodetic observations of the dome activity were carried out by several pioneering geophysicists. Utilizing their data, pseudo growth curves of the dome at each stage can be drawn. The lava ascended rather uniformly, causing uplift of the ground surface until half-solidified lava reached the surface six months after the deformation began. Thereafter, the lava dome added lateral displacements and finally achieved its onion structure. These two lava domes are of contrasting character, one is andesitic and formed quickly while the other is dacitic and formed slowly, but both of them behaved as viscous and plastic flows during effusion. It is concluded that both the lava domes formed by uplift of magma forced to flow through the conduits, analogous to squeezing toothpaste out of a tube.

  20. Net ecosystem CO{sub 2} exchange over a larch forest in Hokkaido, Japan

    Energy Technology Data Exchange (ETDEWEB)

    Huimin Wang; Saigusa, Nobuko; Yamamoto, Susumu; Kondo, Hiroaki [National Inst. of Advanced Industrial Science and Technology, Tsukuba Science City (Japan); Hirano, Takashi [Hokkaido Univ., Sapporo (Japan); Toriyama, Atsushi; Fujinuma, Yasumi [National Inst. for Environmental Studies, Tsukuba (Japan)

    2004-12-01

    Larch forests are distributed extensively in the east Eurasian continent and are expected to play a significant role in the terrestrial ecosystem carbon cycling process. In view of the fact that studies on carbon exchange for this important biome have been very limited, we have initiated a long-term flux observation in a larch forest ecosystem in Hokkaido in northern Japan since 2000. The net ecosystem CO{sub 2} exchange (NEE) showed large seasonal and diurnal variation. Generally, the larch forest ecosystem released CO{sub 2} in nighttime and assimilated CO{sub 2} in daytime during the growing season from May to October. The ecosystem started to become a net carbon sink in May, reaching a maximum carbon uptake as high as 186 g C m{sup -2} month{sup -1} in June. With the yellowing, senescing and leaf fall, the ecosystem turned into a carbon source in November. During the non-growing season, the larch forest ecosystem became a net source of CO{sub 2}, releasing an average of 16.7 g C m{sup -2} month{sup -1}. Overall, the ecosystem sequestered 141-240 g C m{sup -2} yr{sup -1} in 2001. The NEE was significantly influenced by environmental factors. Respiration of the ecosystem, for example, was exponentially dependent on air temperature, while photosynthesis was related to the incident PAR in a manner consistent with the Michaelis-Menten model. Although the vapor pressure deficit (VPD) was scarcely higher than 15 hPa, the CO{sub 2} uptake rate was also depressed when VPD surpassed 10 hPa (Author)

  1. Net ecosystem CO 2 exchange over a larch forest in Hokkaido, Japan

    Science.gov (United States)

    Wang, Huimin; Saigusa, Nobuko; Yamamoto, Susumu; Kondo, Hiroaki; Hirano, Takashi; Toriyama, Atsushi; Fujinuma, Yasumi

    Larch forests are distributed extensively in the east Eurasian continent and are expected to play a significant role in the terrestrial ecosystem carbon cycling process. In view of the fact that studies on carbon exchange for this important biome have been very limited, we have initiated a long-term flux observation in a larch forest ecosystem in Hokkaido in northern Japan since 2000. The net ecosystem CO 2 exchange (NEE) showed large seasonal and diurnal variation. Generally, the larch forest ecosystem released CO 2 in nighttime and assimilated CO 2 in daytime during the growing season from May to October. The ecosystem started to become a net carbon sink in May, reaching a maximum carbon uptake as high as 186 g C m -2 month -1 in June. With the yellowing, senescing and leaf fall, the ecosystem turned into a carbon source in November. During the non-growing season, the larch forest ecosystem became a net source of CO 2, releasing an average of 16.7 g C m -2 month -1. Overall, the ecosystem sequestered 141-240 g C m -2 yr -1 in 2001. The NEE was significantly influenced by environmental factors. Respiration of the ecosystem, for example, was exponentially dependent on air temperature, while photosynthesis was related to the incident PAR in a manner consistent with the Michaelis-Menten model. Although the vapor pressure deficit (VPD) was scarcely higher than 15 hPa, the CO 2 uptake rate was also depressed when VPD surpassed 10 hPa.

  2. The study of multilayers Fe/Hf and Ni/Hf by slow positron beam technique

    Science.gov (United States)

    Tashiro, Mutsumi; Nakajyo, Terunobu; Murashige, Yusuke; Koizumi, Tomoya; Kanazawa, Ikuzo; Komori, Fumio; Soe, We-Hyo; Yamamoto, Ryoichi; Ito, Yasuo

    1997-05-01

    The S-parameters versus the incident positron energy are measured in the Ni/Hf multilayer, thin Hf film, thin Fe film and the bilayer Fe/Hf. We have analyzed the change in vacancy-type defects in these multilayers and thin films with the deposition temperature in the MBE system.

  3. Upper Boundary of the Pacific Plate Subducting Under Hokkaido,Japan,Estimated from ScSp Phase

    OpenAIRE

    長田, 絹絵; 吉澤, 和範; 蓬田, 清

    2006-01-01

    Geometry of the upper boundary of the subducting Pacific plate or slab was estimated in the Hokkaido region, Japan, using the ScSp phase: the converted phase to P wave at the boundary from the S wave reflected at the core-mantle boundary and propagating nearly vertically (i.e., ScS phase). Taking the advantage of a dense seismic network named “Hi-net” recently deployed across the Japanese islands, we applied several seismic array analyses to the recorded waveform data for a large nearby deep ...

  4. Contamination status and accumulation characteristics of metals and a metalloid in birds on Teuri Island, Hokkaido, Japan.

    Science.gov (United States)

    Ishii, Chihiro; Ikenaka, Yoshinori; Nakayama, Shouta M M; Suzuki, Yuya; Watanuki, Yutaka; Watanabe, Yuji; Yohannes, Yared Beyene; Mizukawa, Hazuki; Ishizuka, Mayumi

    2014-08-01

    Teuri Island, Hokkaido in Japan is an important place for seabirds breeding. We measured the concentrations of heavy metals (Hg, Cd, Cr, Co, Ni, Cu, Zn, and Pb) and a metalloid (As) in rhinoceros auklet (Cerorhinca monocerata) (n = 7), thick-billed murre (Uria lomvia) (n = 2), spectacled guillemot (Cepphus carbo) (n = 6), slaty-backed gull (Larus schistisagus) (n = 15), jungle crow (Corvus macrorhynchos) (n = 3), Japanese anchovy (Engraulis japonica) (n = 6) and Atka mackerel (Pleurogrammus azonus) (n = 2). Spectacled guillemot had high As concentrations, with its source being their feeding habitat. Concentration of Hg in kidney of jungle crow was higher than other seabird species at Teuri.

  5. HF radiation emitted by chaotic leader processes

    Science.gov (United States)

    Mäkelä, J. S.; Edirisinghe, M.; Fernando, M.; Montaño, R.; Cooray, V.

    2007-04-01

    This paper presents direct measurements of narrowband 10 MHz HF radiation from so-called “chaotic leaders” associated with subsequent return strokes. Although the term is controversial and poorly defined, we find that more than 30% of subsequent strokes in close lightning flashes contain electric field characteristics that are best described as “chaotic”. In earlier studies, return strokes have consistently been observed to be the strongest sources of HF radiation, but the results for leader processes are less consistent. We also observe return strokes to be the main HF emitter, and the leaders before the first return stroke in a flash sequence also emit HF though somewhat less intensely. The leaders preceding subsequent strokes typically emit little or no HF radiation, whether they are dart or dart-stepped leaders. However, it was observed that the presence of a chaotic component increases the leader HF intensity dramatically Defining the HF intensity unequivocally can be problematic for processes like chaotic leaders which have a combination of continuous and impulsive phenomena. Two time-domain methods were used to measure the HF intensity, the peak energy and the RMS energy. In the frequency domain these correspond to the energy spectral density (ESD) and power spectral density (PSD), respectively. It was found that the methods are not necessarily compatible. Thus, it is suggested that to clarify future work, leader processes should be characterized by the PSD rather than the ESD.

  6. Integrated Monitoring of the Soya Warm Current Using HF Ocean Radars, Satellite Altimeters, Coastal Tide Gauges, and a Bottom-Mounted ADCP

    Science.gov (United States)

    Ebuchi, N.; Fukamachi, Y.; Ohshima, K. I.; Wakatsuchi, M.

    2007-12-01

    The Soya Warm Current (SWC) is a coastal boundary current, which flows along the coast of Hokkaido in the Sea of Okhotsk. The SWC flows into the Sea of Okhotsk from the Sea of Japan through the Soya/La Perouse Strait, which is located between Hokkaido, Japan, and Sakhalin, Russia. It supplies warm, saline water in the Sea of Japan to the Sea of Okhotsk and largely affects the ocean circulation and water mass formation in the Sea of Okhotsk, and local climate, environment and fishery in the region. However, the SWC has never been continuously monitored due to the difficulties involved in field observations related to, for example, severe weather conditions in the winter, political issues at the border strait, and conflicts with fishing activities in the strait. Detailed features of the SWC and its variations have not yet been clarified. In order to monitor variations in the SWC, three HF ocean radar stations were installed around the strait. The radar covers a range of approximately 70 km from the coast. It is shown that the HF radars clearly capture seasonal and subinertial variations of the SWC. The velocity of the SWC reaches its maximum, approximately 1 m/s, in summer, and weakens in winter. The velocity core is located 20 to 30 km from the coast, and its width is approximately 50 km. The surface transport by the Soya Warm Current shows a significant correlation with the sea level difference along the strait, as derived from coastal tide gauge records. The cross-current sea level difference, which is estimated from the sea level anomalies observed by the Jason-1 altimeter and a coastal tide gauge, also exhibits variation in concert with the surface transport and along-current sea level difference.

  7. HfS, Hyperfine Structure Fitting Tool

    CERN Document Server

    Estalella, Robert

    2016-01-01

    HfS is a tool to fit the hyperfine structure of spectral lines, with multiple velocity components. The HfS_nh3 procedures included in HfS fit simultaneously the hyperfine structure of the NH$_3$ (J,K)= (1,1) and (2,2) transitions, and perform a standard analysis to derive $T_\\mathrm{ex}$, NH$_3$ column density, $T_\\mathrm{rot}$, and $T_\\mathrm{k}$. HfS uses a Monte Carlo approach for fitting the line parameters. Especial attention is paid to the derivation of the parameter uncertainties. HfS includes procedures that make use of parallel computing for fitting spectra from a data cube.

  8. Timing of puberty and its relationship with body growth and season in male raccoons (Procyon lotor) in Hokkaido.

    Science.gov (United States)

    Okuyama, Minami W; Shimozuru, Michito; Abe, Go; Nakai, Mariko; Sashika, Mariko; Shimada, Ken-Ichiro; Takahashi, Nobuhiro; Fukui, Daisuke; Nakamura, Ryohei; Tsubota, Toshio

    2013-01-01

    The raccoon (Procyon lotor), indigenous to North America, has naturalized in Japan as an invasive alien species, having been introduced into the country in the 1970s. In Hokkaido, the northernmost island of Japan, feral raccoons have been increasing in number and spreading throughout the island. The age at the onset of puberty for raccoons is important for estimating individual lifetime reproductive success and population growth. The present study investigated the timing of and potential factors affecting the onset of puberty in male raccoons in Hokkaido. External characteristics and histology of testes were studied in 151 male feral raccoons and in 1 captive juvenile. For the majority of feral yearling raccoons, prepubertal development began in May, and spermatozoa production began in October prior to their second mating season. However, some larger juveniles attained puberty during the juvenile period. The captive juvenile, which was fed throughout the winter, attained puberty only 11 months after birth. These results suggest that if male raccoons can achieve enough body growth before the first mating season, puberty can be attained early. In both juveniles and yearlings, spermatozoa production was only observed after autumn. This timing coincided with the recrudescence of seasonally active spermatogenesis in adult males. Therefore, attaining puberty in male raccoons appears to require both adequate body nutrient development and several environmental factors that control seasonal testicular changes.

  9. Combination of Well-Logging Temperature and Thermal Remote Sensing for Characterization of Geothermal Resources in Hokkaido, Northern Japan

    Directory of Open Access Journals (Sweden)

    Bingwei Tian

    2015-03-01

    Full Text Available Geothermal resources have become an increasingly important source of renewable energy for electrical power generation worldwide. Combined Three Dimension (3D Subsurface Temperature (SST and Land Surface Temperature (LST measurements are essential for accurate assessment of geothermal resources. In this study, subsurface and surface temperature distributions were combined using a dataset comprised of well logs and Thermal Infrared Remote sensing (TIR images from Hokkaido island, northern Japan. Using 28,476 temperature data points from 433 boreholes sites and a method of Kriging with External Drift or trend (KED, SST distribution model from depths of 100 to 1500 m was produced. Regional LST was estimated from 13 scenes of Landsat 8 images. Resultant SST ranged from around 50 °C to 300 °C at a depth of 1500 m. Most of western and part of the eastern Hokkaido are characterized by high temperature gradients, while low temperatures were found in the central region. Higher temperatures in shallower crust imply the western region and part of the eastern region have high geothermal potential. Moreover, several LST zones considered to have high geothermal potential were identified upon clarification of the underground heat distribution according to 3D SST. LST in these zones showed the anomalies, 3 to 9 °C higher than the surrounding areas. These results demonstrate that our combination of TIR and 3D temperature modeling using well logging and geostatistics is an efficient and promising approach to geothermal resource exploration.

  10. Aspects of HF radio propagation

    Directory of Open Access Journals (Sweden)

    Stephane Saillant

    2009-06-01

    Full Text Available

    radio systems. From the point of view Working Group 2 of the COST 296 Action, interest lies with effects associated

    with propagation via the ionosphere of signals within the HF band. Several aspects are covered in this paper:

    a The directions of arrival and times of flight of signals received over a path oriented along the trough have

    been examined and several types of propagation effects identified. Of particular note, combining the HF observations

    with satellite measurements has identified the presence of irregularities within the floor of the trough that

    result in propagation displaced from the great circle direction. An understanding of the propagation effects that

    result in deviations of the signal path from the great circle direction are of particular relevance to the operation

    of HF radiolocation systems.

    b Inclusion of the results from the above mentioned measurements into a propagation model of the northerly

    ionosphere (i.e. those regions of the ionosphere located poleward of, and including, the mid-latitude trough

    and the use of this model to predict the coverage expected from transmitters where the signals impinge on the

    northerly ionosphere

  11. [Survey of keratinophilic fungi from soils and mating behaviour of Microsporum canis from human ringworm cases in Hokkaido Prefecture in Japan].

    Science.gov (United States)

    Kubo, H

    1988-03-01

    From 383 (38.3%) of a total 1000 of soil samples, collected from Hokkaido prefecture, keratinophilic fungi have been isolated using hair baiting technique. The fungi isolated were as follows: 318 strains of Trichophyton ajelloi (including 90 strains of Arthroderma uncinatum), 59 of Microsporum cookei (including 13 of Nannizzia cajetani), 32 of Chrysosporium keratinophilum, 23 of C. tropicum, 15 of Chrysosporium anamorph of A. tuberculatum, 6 of T. terrestre (including 3 of A. insingulare and one of A. quadrifidum), 4 of Chrysosporium sp., 2 of M. canis (including one of N. otae), one of M. gypseum, and one of Ctenomyces serratus. This is the first isolation of N. otae from soil. Because of the successful isolation of N. otae (and its anamorph) from soil sample, (+) strain of M. canis was suggested to be popular in Hokkaido prefecture. The prevalence of (+) strain of M. canis was investigated using 279 isolates obtained from human ringworm cases. Among the 279 isolates, 257 were (-) mating type, 8 were (+) and 14 were nonreactive. Results of the present study indicate that the distribution of keratinophilic fungi from soils in Hokkaido prefecture is markedly different from that in the southern parts of Japan. The unexpected isolation of N. otae and its anamorph from soil samples as well as the significant population of N. otae(+) strain from human ringworms suggest the peculiar distribution pattern of N. otae (+) in Hokkaido prefecture.

  12. Estimating subsurface water volumes and transit times in Hokkaido river catchments, Japan, using high-accuracy tritium analysis

    Science.gov (United States)

    Gusyev, Maksym; Yamazaki, Yusuke; Morgenstern, Uwe; Stewart, Mike; Kashiwaya, Kazuhisa; Hirai, Yasuyuki; Kuribayashi, Daisuke; Sawano, Hisaya

    2015-04-01

    The goal of this study is to estimate subsurface water transit times and volumes in headwater catchments of Hokkaido, Japan, using the New Zealand high-accuracy tritium analysis technique. Transit time provides insights into the subsurface water storage and therefore provides a robust and quick approach to quantifying the subsurface groundwater volume. Our method is based on tritium measurements in river water. Tritium is a component of meteoric water, decays with a half-life of 12.32 years, and is inert in the subsurface after the water enters the groundwater system. Therefore, tritium is ideally suited for characterization of the catchment's responses and can provide information on mean water transit times up to 200 years. Only in recent years has it become possible to use tritium for dating of stream and river water, due to the fading impact of the bomb-tritium from thermo-nuclear weapons testing, and due to improved measurement accuracy for the extremely low natural tritium concentrations. Transit time of the water discharge is one of the most crucial parameters for understanding the response of catchments and estimating subsurface water volume. While many tritium transit time studies have been conducted in New Zealand, only a limited number of tritium studies have been conducted in Japan. In addition, the meteorological, orographic and geological conditions of Hokkaido Island are similar to those in parts of New Zealand, allowing for comparison between these regions. In 2014, three field trips were conducted in Hokkaido in June, July and October to sample river water at river gauging stations operated by the Ministry of Land, Infrastructure, Transport and Tourism (MLIT). These stations have altitudes between 36 m and 860 m MSL and drainage areas between 45 and 377 km2. Each sampled point is located upstream of MLIT dams, with hourly measurements of precipitation and river water levels enabling us to distinguish between the snow melt and baseflow contributions

  13. HF Transverse Segmentation and Tagging Jet Capability

    CERN Document Server

    Doroshkevich, E A; Kuleshov, Sergey

    1998-01-01

    So called tagging jets and pile-up were simulated for the optimisation of the HF segmentation. The energy resolution, angular resolution and efficiency of jet reconstruction are defined for different calorimeter segmentation.

  14. Collisional quenching of highly rotationally excited HF

    CERN Document Server

    Yang, Benhui; Forrey, R C; Stancil, P C; Balakrishnan, N

    2015-01-01

    Collisional excitation rate coefficients play an important role in the dynamics of energy transfer in the interstellar medium. In particular, accurate rotational excitation rates are needed to interpret microwave and infrared observations of the interstellar gas for nonlocal thermodynamic equilibrium line formation. Theoretical cross sections and rate coefficients for collisional deexcitation of rotationally excited HF in the vibrational ground state are reported. The quantum-mechanical close-coupling approach implemented in the nonreactive scattering code MOLSCAT was applied in the cross section and rate coefficient calculations on an accurate 2D HF-He potential energy surface. Estimates of rate coefficients for H and H$_2$ colliders were obtained from the HF-He collisional data with a reduced-potential scaling approach. The calculation of state-to-state rotational quenching cross sections for HF due to He with initial rotational levels up to $j=20$ were performed for kinetic energies from 10$^{-5}$ to 15000...

  15. Microhardness evaluation alloys Hf-Si-B; Avaliacao de microdureza de ligas Hf-Si-B

    Energy Technology Data Exchange (ETDEWEB)

    Gigolotti, Joao Carlos Janio; Costa, Eliane Fernandes Brasil [Centro Universitario de Volta Redonda (UNIFOA), Volta Redonda, RJ (Brazil); Nunes, Carlos Angelo; Rocha, Elisa Gombio; Coelho, Gilberto Carvalho, E-mail: carlosjanio@uol.com.br, E-mail: eliane-costabrasi@hotmail.com, E-mail: cnunes@demar.eel.usp.br, E-mail: elisarocha@alunos.eel.usp.br, E-mail: coelho@demar.eel.usp.br [Universidade de Sao Paulo (USP), Lorena, SP (Brazil)

    2014-08-15

    The technological advance has generated increasing demand for materials that can be used under high temperature, what includes intermetallic MR-Si-B (MR = refractory metal) alloys with multiphase structures, that can also be applied in oxide environments. Thus, this work had for objective the micro hardness study of the Hf-Si-B system alloys, heat treated at 1600 deg C, in the Hf rich region. Hf-Si-B alloys had been produced with blades of Hf (min. 99.8%), Si (min. 99.998%) and B (min. 99.5%), in the voltaic arc furnace and heat treated at 1600 deg C under argon atmosphere. The relationship of the phases had been previously identified by X-ray diffraction and contrast in backscattered electron imaging mode. The alloys had their hardness analyzed by method Vickers (micro hardness) with load of 0.05 kgf and 0.2 kgf and application time of 20 s. The results, obtained from the arithmetic mean of measurements for each alloy on the heterogeneous region, showed a mean hardness of 11.08 GPA, with small coefficient of variation of 3.8%. The borides HfB2 (19.34 GPa) e HfB - 11.76 GPa, showed the hardness higher than the silicides Hf2Si (8.57 GPa), Hf5Si3 (9.63 GPa), Hf3Si2 (11.66 GPa), Hf5Si4 (10.00 GPa), HfSi (10.02 GPa) e HfSi2 (8.61 GPa). (author)

  16. Evaluation of Nitrogen Cycling Associated with Agricultural Production and Environmental Load in a Mountain Region, in Hokkaido, Japan

    Institute of Scientific and Technical Information of China (English)

    LIANG Lei; JIN Datian; HU Ning

    2008-01-01

    This study examined the nitrogen cycling associated with agricultural production and environmental load in central Hokkaido. The nitrogen (N) budget analysis model offers a new set of tools for evaluating N cycling in agro-ecosystems. The cycling index (CI) is a useful tool for estimating optimal N flows in farmlands. The fertilization index (FI) is a useful indicator for characterizing the N flows related to farms. Using these parameters, we analyzed all farm systems to estimate the optimal N cycling for minimizing N pollution in groundwater and maximizing agricultural production in mountain regions of Japan. The results showed that the critical N application rate (chemical fertilizer + manure) was 143.3 kg N ha-1 y-1. The critical inter-system input (chemical fertilizer N, imported food and feed N, and natural supplied N) was 169.9 kg N ha-1y-1.

  17. Serologic evidence of Brucella infection in pinnipeds along the coast of Hokkaido, the northernmost main island of Japan.

    Science.gov (United States)

    Abe, Erika; Ohishi, Kazue; Ishinazaka, Tsuyoshi; Fujii, Kei; Maruyama, Tadashi

    2017-04-01

    Brucella infection in Hokkaido was serologically surveyed in four species of pinnipeds inhabiting Cape Erimo during 2008-2013 and the Shiretoko Peninsula in 1999 by ELISA using Brucella abortus and B. canis as antigens. Anti-Brucella positive sera showed higher absorbance to B. abortus than B. canis in almost all samples. Anti-B. abortus antibodies were detected in serum samples from 24% (n = 55) of Western Pacific harbor seals (Phoca vitulina stejnegeri) in Cape Erimo and from 66% (n = 41) of spotted seals (P. largha), 15% (n = 20) of ribbon seals (Histriophoca fasciata) and 18% (n = 17) of Western Steller's sea lions (Eumetopias jubatus jubatus) in the Shiretoko Peninsula. Anti-Brucella antibodies were detected at higher absorbance in 1- to 4-year-old harbor seals than in the pups and mature animals, suggesting either that Brucella infection mainly occurs after weaning or that it is maternally transmitted to pups with premature or suppressed immunity. Anti-Brucella antibodies were detected in both immature and mature spotted seals and ribbon seals, with higher absorbance in the former. The antibodies were detected only in mature Western Steller's sea lions. Western blot analysis of the serum samples showed some differences in band appearances, namely discrete versus smeary, and in the number of bands, indicating that multiple different Brucella may be prevalent in pinnipeds in Hokkaido. Alternatively, the Brucella of pinnipeds may have some intra-species diversity. © 2017 The Societies and John Wiley & Sons Australia, Ltd.

  18. General concepts of modern HF communications

    Science.gov (United States)

    Aarons, Jules

    Both conceptual and hardware advancements have led to substantial systems developments in military HF communications; the former encompass coding and error correction techniques for security, in order to minimize propagation and interference, while the latter prominently include digital equipment permitting the selection of a frequency for a particular path and propagation mode, as well as modulation selection. Propagation-related advancements involve better statistical models as well as advancements in short-term forecasting methods responsive to changes in solar-geophysical parameters. Adaptive HF systems have been developed for meteor-scatter radio communications.

  19. Research on Multi-Layer Distributed HF Radio Network Structure

    Institute of Scientific and Technical Information of China (English)

    Hui Dai; Chun-Jiang Wang; Quan Yu

    2008-01-01

    High frequency (HF) transmission is an important communication techniques. However, conventional point-to-point transmission can be easily destroyed, which limits its utilization in practice. HF networking communication has the capability against demolishment. The network structure is one of the key factors for HF networking communication. In this paper, a novel analysis method of the network connectedness based on the eigenvalue is derived, and a multi-layer distributed HF radio network structure is proposed. Both the theore tical analysis and the computer simulation results verify that the application of the proposed network structure in the HF radio communication can improve the anti demolishment ability of the HF network efficiently.

  20. First imaging and identification of a noctilucent cloud from multiple sites in Hokkaido (43.2-44.4°N), Japan

    Science.gov (United States)

    Suzuki, Hidehiko; Sakanoi, Kazuyo; Nishitani, Nozomu; Ogawa, Tadahiko; Ejiri, Mitsumu K.; Kubota, Minoru; Kinoshita, Takenori; Murayama, Yasuhiro; Fujiyoshi, Yasushi

    2016-11-01

    Simultaneous imaging observations of a noctilucent cloud (NLC) from five sites in Hokkaido, Japan (43.17-45.36°N), were successfully carried out using digital cameras in the early hours of the morning (around 02:00 LST) on June 21, 2015. This is the first NLC event that has been captured from multiple sites in Japan. The simultaneous images obtained from multiple sites made it possible to calculate the exact altitude (=83.9 ± 0.1 km) and spatial distribution (47.5-50.0°N and 143.0-147.5°E) of the NLC by triangulation and image correlation methods. Based on a comparison of atmospheric parameters of the upper mesosphere provided by satellites and a middle-frequency (MF) radar in northern Hokkaido (Wakkanai) with the cloud distribution obtained from the Aeronomy of Ice in the Mesosphere satellite, this particular event is considered to be the result of southward advection of the NLC from a higher-latitude (i.e., colder) region. Anomalies in the upper mesospheric temperature of the northern hemispheric summer in 2015 were examined using AURA satellite data, because this is the first NLC event that has been identified in Japan. However, no remarkable temperature variations relative to other years were found in upper mesosphere. Based on a comparison between the NLC period and the record of sky conditions archived by the Japan Meteorological Agency, a high percentage of cloud (especially low-level) cover during the summer in Hokkaido cannot be ruled out as a possible reason why the NLC had not previously been sighted in Hokkaido.[Figure not available: see fulltext.

  1. The impacts of disturbance on the spatial and temporal variations of carbon balance in forest ecosystems on Hokkaido, Japan

    Science.gov (United States)

    Hirata, R.; Ito, A.; Saigusa, N.

    2013-12-01

    Carbon balance in a forest ecosystem can be quite variable if the forest ecosystem structure and function change abruptly as a result of disturbance and subsequent recovery processes. A map of forest age is useful for upscaling carbon balance from the site level to a regional scale because it provides information about when disturbance occurred and how it spread over a wide area. In this study, we used maps of forest age to help evaluate spatial and temporal variations in the carbon balance of forest ecosystems with a process-based ecosystem model. Forests less than 60 years old account for more than 70% of Japanese forests because forest stands have been quickly replaced after disturbance caused by thinning, harvesting, plantations, fires, typhoons, and insect damage. However, few studies have attempted to quantify how much disturbance affects the spatial and temporal variations of carbon balance. In this study, we focused on how disturbance and subsequent re-growth affected the spatial and temporal variations of the carbon balance of forests. We adapted the Vegetation Integrative SImulator for Trace Gases (VISIT) model in order to simulate carbon balance on Hokkaido, which is the northernmost island of Japan. The model was validated with tower flux data obtained from forests with ages between 0 and 43 years. Simulations of the carbon balance were conducted for the period 1948-2010 after a 1000-year spin-up at a spatial resolution of 1 km × 1 km. We investigated two case studies of simulated carbon balance: one that took into account the spatial distribution of forest ages derived from forest inventory data, and another that ignored the impact of disturbance (i.e., no disturbance and a homogeneous distribution of ages). We first focused on the difference from 2000-2010 in the spatial distribution of net ecosystem production (NEP) between the disturbance and non-disturbance cases. In the non-disturbance case, the temporal and spatial changes in NEP were gradual

  2. Different responses of northern and southern high latitude ionospheric convection to IMF rotations: a case study based on SuperDARN observations

    Directory of Open Access Journals (Sweden)

    D. Ambrosino

    2009-06-01

    Full Text Available We use SuperDARN data to study high-latitude ionospheric convection over a three hour period (starting at 22:00 UT on 2 January 2003, during which the Interplanetary Magnetic Field (IMF flipped between two states, one with By>>|Bz| and one with Bz>0, both with negative Bx. We find, as expected from previous works, that day side ionospheric convection is controlled by the IMF in both hemispheres. For strongly northward IMF, we observed signatures of two reverse cells, both in the Northern Hemisphere (NH and in the Southern Hemisphere (SH, due to lobe reconnection. On one occasion, we also observed in the NH two viscous cells at the sides of the reverse cell pair. For duskward IMF, we observed in the NH a large dusk clockwise cell, accompanied by a smaller dawn cell, and the signature of a corresponding pattern in the SH. On two occasions, a three cell pattern, composed of a large clockwise cell and two viscous cells, was observed in the NH. As regards the timings of the NH and SH convection reconfigurations, we find that the convection reconfiguration from a positive Bz dominated to a positive By dominated pattern occurred almost simultaneously (i.e. within a few minutes in the two hemispheres. On the contrary, the reconfiguration from a By dominated to a northward IMF pattern started in the NH 8–13 min earlier than in the SH. We suggest that part of such a delay can be due to the following mechanism: as IMF Bx<0, the northward-tailward magnetosheath magnetic field reconnects with the magnetospheric field first tailward of the northern cusp and later on tailward of the southern cusp, due to the IMF draping around the magnetopause.

  3. Systematic Comparison of HF CMOS Transconductors

    NARCIS (Netherlands)

    Klumperink, Eric A.M.; Nauta, Bram

    2003-01-01

    Transconductors are commonly used as active elements in high-frequency (HF) filters, amplifiers, mixers, and oscillators. This paper reviews transconductor design by focusing on the V-I kernel that determines the key transconductor properties. Based on bandwidth considerations, simple V-I kernels wi

  4. Electron impact on vibrationally cold {{HF}}^{+}

    Science.gov (United States)

    Cristian Stroe, Marius; Fifirig, Magda

    2016-12-01

    The dissociative recombination and vibrational excitation processes induced by electron impact on vibrationally cold {{HF}}+ are investigated in the framework of the multichannel quantum defect theory for electron energies below 1 eV. The thermal rate coefficients for the electron temperature range from 10 to 5000 K are reported.

  5. ORIGIN OF EXCESS (176)Hf IN METEORITES

    DEFF Research Database (Denmark)

    Thrane, Kristine; Connelly, James Norman; Bizzarro, Martin

    2010-01-01

    After considerable controversy regarding the (176)Lu decay constant (lambda(176)Lu), there is now widespread agreement that (1.867 +/- 0.008) x 10(-11) yr(-1) as confirmed by various terrestrial objects and a 4557 Myr meteorite is correct. This leaves the (176)Hf excesses that are correlated with...

  6. Dinoflagellate cyst biostratigraphy and age of the Oligocene Momijiyama formation, Yubari Coal-Field, central Hokkaido, Japan; Hokkaido yubari tanden chiiki, zenshinto momijiyamaso no kaben moso kasekisojo to nendai

    Energy Technology Data Exchange (ETDEWEB)

    Kurita, H.; Miwa, M. [Japan Petroleum Exploration Co. Ltd., Chiba (Japan). JAPEX Research Center

    1998-01-15

    The Momijiyama formation distributed in the Yubari coalfield region of Hokkaido is one of the typical sea Oligocenes in the northern Japan. However, there has been much argument about the age of the Momijiyama formation. This paper reports newly-obtained findings concerning the upper limit age of the Momijiyama formation determined by the analysis of a dinoflagellate fossil, an organic microfossil, conducting a fission track (FT) age determination, and putting together the results of the analysis and determination and the results of the analysis of dinoflagellate fossil reported by Kurita and Matsuoka (1994). It can currently be concluded on the basis of both the data on the dinoflagellate cyst biostratigraphy which were obtained in the Hobetsu region and those on the radioactive data that the upper limit age of the Momijiyama formation is an initial period of the Oligocene epoch. The age of the floating foraminifer and the calcareous nannofossil produced from the upper portion of the Horonai formation, a formation on the lower layer of the Momijiyama formation is the final period of the Eocene or the initial period of the Oligocene. Therefore, it is considered that the lower limit age of the Momijiyama formation is substantially before or after the transition from the Eocene epoch to the Oligocene epoch. 19 refs., 4 figs., 1 tab.

  7. Methicillin-resistant Staphylococcus aureus carriage among veterinary staff and dogs in private veterinary clinics in Hokkaido, Japan.

    Science.gov (United States)

    Ishihara, Kanako; Saito, Mieko; Shimokubo, Natsumi; Muramatsu, Yasukazu; Maetani, Shigeki; Tamura, Yutaka

    2014-03-01

    To explore the prevalence and molecular characteristics of methicillin-resistant Staphylococcus aureus (MRSA) in veterinary medical practices, MRSA carriage was tested among 96 veterinarians (Vets), 70 veterinary technicians (VTs) and 292 dogs with which they had contact at 71 private veterinary clinics (VCs) in Hokkaido, Japan. MRSA isolates were obtained from 22 Vets [22.9%] and 7 VTs [10%]. The prevalence of MRSA among Vets was as high as that found in an academic veterinary hospital in our previous study. In contrast, only two blood donor dogs and one dog with liver disease (1.0%, 3/292) yielded MRSA. All MRSA-positive dogs were reared or treated in different VCs, in each of which at least one veterinary staff member carrying MRSA worked. Sequence types (ST) identified by multilocus sequence typing, spa types, and SCCmec types for canine MRSA isolates (ST5-spa t002-SCCmec II [from two dogs] or ST30-spa t021-SCCmec IV [from a dog]) were concordant with those from veterinary staff members in the same clinics as the MRSA-positive dogs, with which they had potentially had contact. Most MRSA isolates from veterinary staff were the same genotype (SCCmec type II and spa type t002) as a major hospital-acquired MRSA clone in Japan. The remaining MRSA was the same genotypes as domestic and foreign community-associated MRSA. Measures against MRSA infection should be provided in private VCs.

  8. Cold-induced vasodilatation of finger and maximal oxygen consumption of young female athletes born in Hokkaido

    Science.gov (United States)

    Moriya, Kiyoshi; Nakagawa, Koya

    1990-03-01

    To determine whether there is a direct correlation between endurance capacity and cold tolerance, maximal oxygen consumption (VO2max), and cold-induced vasodilatation (CIVD), we measured these factors in 14 young female athletes born in Hokkaido, Japan's northernmost island. We determined the VO2max by a standard incremental test on a cycle ergometer and measured the oxygen consumption (VO2) by means of the Douglas-bag method. We determined the CIVD reaction by measuring the skin temperature of the left middle finger during immersion in cold water at 0°C for 20 min. The athletes showed significant positive correlations between VO2max, expressed as l/min, and CIVD as well as other peripheral cold tolerance indexes (resistance index against frostbite and CIVD index). The body weight VO2max (VO2max/kg body weight) failed to correlate significantly with either the CIVD or with other cold tolerance indexes. These results suggest that CIVD in females may depend on factors other than those determined in this study, in addition to the functional spread of the vascular beds in peripheral tissues, including striated muscle; it is known that the size and the vascular bed in this tissue are affected by exercise training and that this results in the elevation of VO2max and VO2max/kg body weight.

  9. Effects of silviculture treatments in a hurricane-damaged forest on car- bon storage and emissions in central Hokkaido, Japan

    Institute of Scientific and Technical Information of China (English)

    Toshiaki Owari; Naoto Kamata; Takeshi Tange; Mikio Kaji; Akio Shimomura

    2011-01-01

    Hurricanes cause abrupt carbon reduction in forests, but silviculture treatment can be an effective means of quickly regenerating and restoring hurricane-damaged sites. This study assessed how silviculture treatments affect carbon balance after hurricane damage in central Hokkaido, Japan. We examined carbon storage in trees and underground vegetation as well as carbon emissions from silviculture operations in 25year-old stands, where scarification and plantation occurred just after hurricane damage. The amount of carbon stored varied according to silviculture treatment. Among three scarification treatments, a scarified depth of 0 cm (understory vegetation removal) led to the largest amount of carbon stored (64.7 t·ha 1 C). Among four plantation treatments, the largest amount of carbon was stored in a Larix hybrid (L. gmelinii var. japonica × L. kaempferi) plantation (80.3 t·ha-1 C). The plantation of Abies sachalinensis was not successful at accumulating carbon (40.5·ha-1 C). The amount of carbon emitted from silviculture operations was 0.050.14 t·ha 1 C, and it marginally affected the net carbon balance of the silviculture project. Results indicate that silviculture treatments should be performed in an appropriate way to effectively recover the ability of carbon sequestration in hurricane-damaged forests.

  10. Continuous measurement of CO2 flux through the snowpack in a dwarf bamboo ecosystem on Rishiri Island, Hokkaido, Japan

    Science.gov (United States)

    Zhu, Chunmao; Nakayama, Momoko; Yoshikawa Inoue, Hisayuki

    2014-09-01

    To investigate the dynamics and environmental drivers of CO2 flux through the winter snowpack in a dwarf bamboo ecosystem (Hokkaido, northeast Japan), we constructed an automated sampling system to measured CO2 concentrations at five different levels in the snowpack, from the base to the upper snow surface. Using a gas diffusion approach, we estimated an average apparent soil CO2 flux of 0.26 μmol m-2 s-1 during the snow season (December-April); temporally, the CO2 flux increased until mid-snow season, but showed no clear trend thereafter; late-season snow-melting events resulted in rapid decreases in apparent CO2 flux values. Air temperature and subnivean CO2 flux exhibited a positive linear relationship. After eliminating the effects of wind pumping, we estimated the actual soil CO2 flux (0.41 μmol m-2 s-1) to be 54% larger than the apparent flux. This study provides new constraints on snow-season carbon emissions in a dwarf bamboo ecosystem in northeast Asia.

  11. Disturbances in VHF/UHF telemetry links as a possible effect of the 2003 Hokkaido Tokachi-oki earthquake

    Directory of Open Access Journals (Sweden)

    H. Nagamoto

    2008-08-01

    Full Text Available The data on radio telemetry links (for water information at VHF/UHF in Hokkaido are used to investigate the rate of disturbances on radio links (or connection failure and its association with a huge earthquake, Tokachi-oki earthquake on 26 September 2003. Especially, the telemetry links at the Tokachi region closest to the earthquake epicenter, showed a significant increase in disturbances on radio links two weeks to a few days before the earthquake on the basis of analysis during a long interval from 1 June 2002 to 3 November 2007 (over 5 years. We suggest that these severe disturbances in VHF/UHF telemetry links are attributed to the generation of seismogenic VHF/UHF radio noises (emissions. Based on this idea, we have estimated that the intensity of these seismogenic emissions is on the order of 10–19 dB μV/m. Finally, the present result was compared with other physical parameters already obtained for this earthquake.

  12. Influence of dried Hokkaido pumpkin and ascorbic acid addition on chemical properties and colour of corn extrudates.

    Science.gov (United States)

    Obradović, Valentina; Babić, Jurislav; Šubarić, Drago; Jozinović, Antun; Ačkar, Đurđica; Klarić, Ilija

    2015-09-15

    The influence of Hokkaido pumpkin powder (PP) addition to corn grits at levels 4%, 6%, and 8% and ascorbic acid (AA) addition at levels 0.5% and 1% was evaluated. Extrusion was done using a single-screw extruder at two temperature regimes: 135/170/170°C (E1) and 100/150/150°C (E2). Mathematical models that describe the influence of additives on the colour of extrudates were determined. Raw extrusion mixtures as well as obtained extrudates were tested for ascorbic acid, polyphenol, proteins, fat, crude fibre, ash and carotenoids content, and antioxidant activity. E1 extrusion regime acted favourably on polyphenols, crude fibre content, and antioxidant activity. It also caused higher fat degradation than E2 extrusion. Xanthophylls (lutein and zeaxanthin) were less sensitive to extrusion than carotenes (α-carotene, 9-cis-β-carotene and 13-cis-β-carotene). Ascorbic acid was more sensitive to higher extrusion temperatures (49-76% degradation). It provided protection to carotenoids and consequently the colour of the extrudates.

  13. Difference in Size at Maturity in Annual and Overwintering Generations in the Tanaidacean Zeuxo sp. in Oshoro Bay, Hokkaido, Japan.

    Science.gov (United States)

    Kakui, Keiichi; Hayakawa, Yoshinobu; Katakura, Haruo

    2017-04-01

    We investigated the life cycle of the tanaidid Zeuxo sp. 1 (Crustacea: Peracarida: Tanaidacea), which lives epiphytically in dwelling tubes on the algae Sargassum spp. and Neorhodomela aculeata in Oshoro Bay, Hokkaido, Japan. We obtained data on its population size distribution, age structure, and reproductive phenology through monthly sampling from April 2011 to June 2012. From these data, we detected an overwintering group (F0) that arises from mancae that are released in autumn, overwinters, reproduces the following spring, and then disappears. The overwintering group produces mancae (F1) that reach maturity and themselves reproduce within six weeks after release; the F1, mancae give rise to an F2 and possibly an F3 generation within a single summer. We refer to individuals that reproduce in the same summer that they were released as the 'annual group'. Reproduction overall was restricted to the period from May to October, when the seasurface temperature exceeded 10°C. During both years, overwintering females first became reproductive in May. Reproduction in the annual group began in June and continued through mid-October. Mancae were observed in samples from June through October. The two groups differed significantly in size at reproduction; compared to the annual group, females in the overwintering group reproduced at larger minimum and average body sizes, and males began to express enlarged chelae, a secondary sexual character, at a larger size. The difference in size at maturity may be related to the differences in water temperature during the main period of growth and maturation.

  14. Ice-brine and planktonic microheterotrophs from Saroma-ko Lagoon, Hokkaido (Japan): quantitative importance and trophodynamics

    Science.gov (United States)

    Sime-Ngando, Télesphore; Juniper, S. Kim; Demers, Serge

    1997-02-01

    Biologists have rarely had the opportunity to investigate the community characteristics and dynamics of heterotrophic microorganisms in highly productive first-year sea ice. In this study, sterile seawater was used as a salinity buffer to extract the ice-brine microheterotroph communities (bacteria, flagellates and ciliates) from a coastal lagoon in Japan (Saroma-ko, Hokkaido; 44°N, 144°E) during the late winter (February—March) of 1992. This procedure reduced osmotic shock during the melting of ice cores and allowed the recovery of up to 323% more cells than the traditional melting method. Most of the organisms were concentrated in the bottom 3-4 cm of the ice, where abundances were up to 33 times higher than in the plankton. In ice and plankton samples, heterotrophic flagellates were dominated by small species (sampling period while protozoa increased or attained their maximum number in late winter, toward the end of the sampling period. These observations support previous suggestions of the existence of a functional microbial food web within the sea-ice community. Heterotrophic flagellate biomass greatly exceeded bacterial biomass in the sea ice (30-60 x). Coupled with similar potential growth rates, this suggests the utilization of additional (non-bacterial) food items by ice-brine flagellates. Finally, the effects of salinity variations (ranging between 15 and 120 psu) on potential microheterotroph growth rates are discussed.

  15. REMPI Spectroscopy of HfF

    CERN Document Server

    Loh, Huanqian; Yahn, Tyler S; Looser, Herbert; Field, Robert W; Cornell, Eric A

    2012-01-01

    The spectrum of electronic states at 30000--33000 cm$^{-1}$ in hafnium fluoride has been studied using (1+1) resonance-enhanced multi-photon ionization (REMPI) and (1+1$'$) REMPI. Six $\\Omega' = 3/2$ and ten $\\Pi_{1/2}$ vibronic bands have been characterized. We report the molecular constants for these bands and estimate the electronic energies of the excited states using a correction derived from the observed isotope shifts. When either of two closely spaced $\\Pi_{1/2}$ electronic states is used as an intermediate state to access autoionizing Rydberg levels, qualitatively distinct autoionization spectra are observed. The intermediate state-specificity of the autoionization spectra bodes well for the possibility of using a selected $\\Pi_{1/2}$ state as an intermediate state to create ionic HfF$^+$ in various selected quantum states, an important requirement for our electron electric dipole moment (eEDM) search in HfF$^+$.

  16. Digitally Driven Antenna for HF Transmission

    Science.gov (United States)

    2010-09-01

    the 1-MHz carrier signal. This signal is then fed into the base terminals of an NPN/ PNP transistor pair arranged in a push–pull configura- tion. A dual...negative voltage connected to the collector terminal of the PNP transistor . Since it was not possible to explicitly simulate the radia- tion of the time...complementary pair of switching transistors is driven with a pulsewidth modulated HF signal, eliminating the requirement for a frequency-dependent

  17. RFID UHF i HF w bibliotekach

    Directory of Open Access Journals (Sweden)

    Gładysz Bartłomiej

    2015-06-01

    Full Text Available The potential of the innovative Radio Frequency Identification (RFID technology to be applied for support, acceleration and automation of the circulation process of library collection is presented. Technology basics, and hardware and software components are described. Two different radio standards used in libraries are compared. The goal is to present the potential of RFID technology for libraries, to highlight the differences and to build a basis for further consideration of UHF and HF alternatives.

  18. Application of tritium in precipitation and baseflow in Japan: a case study of groundwater transit times and storage in Hokkaido watersheds

    Science.gov (United States)

    Gusyev, Maksym A.; Morgenstern, Uwe; Stewart, Michael K.; Yamazaki, Yusuke; Kashiwaya, Kazuhisa; Nishihara, Terumasa; Kuribayashi, Daisuke; Sawano, Hisaya; Iwami, Yoichi

    2016-07-01

    In this study, we demonstrate the application of tritium in precipitation and baseflow to estimate groundwater transit times and storage volumes in Hokkaido, Japan. To establish the long-term history of tritium concentration in Japanese precipitation, we used tritium data from the global network of isotopes in precipitation and from local studies in Japan. The record developed for Tokyo area precipitation was scaled for Hokkaido using tritium values for precipitation based on wine grown at Hokkaido. Then, tritium concentrations measured with high accuracy in river water from Hokkaido, Japan, were compared to this scaled precipitation record and used to estimate groundwater mean transit times (MTTs). A total of 16 river water samples in Hokkaido were collected in June, July, and October 2014 at 12 locations with altitudes between 22 and 831 m above sea level and catchment areas between 14 and 377 km2. Measured tritium concentrations were between 4.07 (± 0.07) TU and 5.29 (± 0.09) TU in June, 5.06 (± 0.09) TU in July, and between 3.75 (± 0.07) TU and 4.85 (± 0.07) TU in October. We utilised TracerLPM (Jurgens et al., 2012) for MTT estimation and introduced a Visual Basic module to automatically simulate tritium concentrations and relative errors for selected ranges of MTTs, exponential-piston ratios, and scaling factors of tritium input. Using the exponential (70 %) piston flow (30 %) model (E70 %PM), we simulated unique MTTs for seven river samples collected in six Hokkaido headwater catchments because their low tritium concentrations were no longer ambiguous. These river catchments are clustered in similar hydrogeological settings of Quaternary lava as well as Tertiary propylite formations near Sapporo city. However, nine river samples from six other catchments produced up to three possible MTT values with E70 % PM due to the interference by the tritium from the atmospheric hydrogen bomb testing 5-6 decades ago. For these catchments, we show that tritium in

  19. Spatial distribution of microbial populations and carbon cycle in the subsurface environment of the Horonobe area, Hokkaido, Japan

    Science.gov (United States)

    Amano, Y.; Ise, K.; Terashima, M.; Sasaki, Y.; Amamiya, H.; Yoshikawa, H.

    2014-12-01

    Microorganisms are widely distributed in the subsurface environments. However, the distribution, role and rate of metabolisms, and the source of their activity are not well known. In this study, we investigated deep groundwater samples from sedimentary rocks, containing saturated methane and CO2, using boreholes at the Horonobe Underground Research Laboratory (URL), northern Hokkaido, Japan. The hydrochemical conditions of groundwaters, such as in-situ water pressure, temperature, electric conductivity, pH, redox potential, were monitored without degassing at multiple intervals along the borehole. Groundwater samples were taken periodically and chemical composition was analyzed using ICP-MS, etc. Cell counts were in the range of 103 to 105 cells ml-1. Molecular analyses revealed the spatial distribution and heterogeneity of the microbial population. Abundant methanogens were detected in the groundwater, and 80% of them were related to either Methanoregula boonei or Methanobacterium flexile that can utilize H2/CO2 by methanogenesis. Phylotypes clustered within the phylum Firmicutes, beta-Proteobacteria, delta-Proteobacteria and candidate division TM7 were dominant in the groundwater samples. Laboratory experiments using a culture technique showed that humic substances purified from the groundwater at Horonobe area appear to be degraded by microorganisms. Our results suggest that microbial spatial distributions in the subsurface environment were correlated closely with geochemical conditions, such as redox condition and carbon sources. In addition, it is inferred that humic substances are one of the important carbon sources for the subsurface microbial redox processes in the environment. This study was partly funded by the Ministry of Economy, Trade and Industry of Japan.

  20. Emplacement model of obsidian-rhyolite magma deduced from complete internal section of the Akaishiyama lava, Shirataki, northern Hokkaido, Japan

    Science.gov (United States)

    Wada, K.; Sano, K.

    2016-12-01

    Simultaneously explosive and effusive eruptions of silicic magmas has shed light on the vesiculation and outgassing history of ascending magmas in the conduit and emplacement model of obsidian-rhyolite lavas (Castro et al., 2014; Shipper et al, 2013). As well as the knowledge of newly erupted products such as 2008-2009 Chaitén and 2011-2012 Cordón Caule eruptions, field and micro-textural evidences of well-exposed internal structure of obsidian-rhyolite lava leads to reveal eruption processes of silicic magmas. The Shirataki monogenetic volcano field, 2.2 million year age, northern Hokkaido, Japan, contains many outcrops of obsidian and vesiculated rhyolite zones (SiO2=76.7-77.4 wt.%). Among their outcrops, Akaishiyama lava shows good exposures of internal sections from the top to the bottom along the Kyukasawa valley with thickness of about 190 meters, showing the symmetrical structure comprising a upper clastic zone (UCZ; 5m thick), an upper dense obsidian zone (UDO; 15m), an upper banded obsidian zone (UBO; 70-80m), a central rhyolite zone (CR; 65m), a lower banded obsidian zone (LBO; 15m), a lower dense obsidian zone (LDO; 20m), and a lower clastic zone (LCZ; 3m). The upper banded obsidian zone is characterized by existence of spherulite concentration layers with tuffisite veins and rhyolite enclaves. Spherulites consisting of albite, cristobalaite and obsidian glass, are clustered in the dense obsidian. Tuffisite veins show brecciated obsidians in tuffaceous matrix, showing an outgassing path during the emplacement of obsidian lava. Perpendicular dip of spherulite parallel rows indicates the banded zone itself was the domain of vent area. From the observation of these occurrences in the internal section and rock texture, we show the qualitative formation model of Shirataki obsidian-rhyolite lava.

  1. Diffusivity Models and Greenhouse Gases Fluxes from a Forest, Pasture, Grassland and Corn Field in Northern Hokkaido, Japan

    Institute of Scientific and Technical Information of China (English)

    N.V.NKONGOLO; R.HATANO; V.KAKEMBO

    2010-01-01

    Information on the most influential factors determining gas flux from soils is needed in predictive models for greenhouse gases emissions.We conducted an intensive soil and air sampling along a 2 000 m transect extending from a forest,pasture,grassland and corn field in Shizunai,Hokkaido (Japan),measured CO2,CH4,N2O and NO fluxes and calculated soil bulk density (ρb),air-filled porosity (fa) and total porosity (φ).Using diffusivity models based on either fa alone or on a combination of fa and φ,we predicted two pore space indices:the relative gas diffusion coefficient (Ds/Do) and the pore tortuosity factor (τ).The relationships between pore space indices (Dg/Do and τ) and CO2,CH4,N2O and NO fluxes were also studied.Results showed that the grassland had the highest ρb while fa and φ were the highest in the forest.CO2,CH4,N2O and NO fluxes were the highest in the grassland while N2O dominated in the corn field.Few correlations existed between fa,φ,ρb and gases fluxes while all models predicted that Ds/Do and τ significantly correlated with CO2 and CH4 with correlation coefficient (τ) ranging from 0.20 to 0.80.Overall,diffusivity models based on fa alone gave higher Ds/Do,lower τ and higher R2 and better explained the relationship between pore space indices (Ds/Do and τ) and gases fluxes.Inclusion of Ds/Do and τ in predictive models will improve our understanding of the dynamics of greenhouse gas fluxes from soils.Ds/Do and τ can be easily obtained by measurements of soil air and water and existing diffusivity models.

  2. Quantitative risk assessment of the introduction of rabies into Japan through the illegal landing of dogs from Russian fishing boats in the ports of Hokkaido, Japan.

    Science.gov (United States)

    Kwan, Nigel C L; Ogawa, Hidehito; Yamada, Akio; Sugiura, Katsuaki

    2016-06-01

    Japan has been free from rabies since 1958 and various preventive measures are in place protecting the country from the introduction of the disease. Historical reviews indicate that the illegal landing of dogs from Russian fishing boats in the ports of Hokkaido occurred frequently especially in the early 2000s and this could potentially be a source of introduction of rabies into Japan. The method of scenario tree modelling was used and the following entry and exposure pathway was considered the most likely route of rabies entry: a rabies-infected dog arriving on a Russian fishing boat lands in a port of Hokkaido in Japan, it becomes infectious, contacts and infects a susceptible domestic animal (companion dog, stray dog or wildlife). Input parameter values were based on surveys of Russian fishermen, expert opinion and scientific data from the literature. At present (2006-2015), the probability of the introduction of rabies as a result of one Russian fishing boat arriving at a port of Hokkaido is 8.33×10(-10) (90% Prediction Interval (PI): 7.15×10(-11)-5.34×10(-9)), while this probability would have been 7.70×10(-9) (90% PI: 6.40×10(-10)-4.81×10(-8)) in the past (1998-2005). Under the current situation (average annual number of boat arrivals is 1106), rabies would enter Japan every 1,084,849 (90% PI: 169,215-20,188,348) years, while the disease would have been introduced every 18,309 (90% PI: 2929-220,048) years in the past (average annual number of boat arrivals is 7092). The risk of rabies introduction has decreased 59 fold due to both the effective control of the issue of illegal landing of dogs and the decline in the number of Russian boat arrivals. Control efforts include education of Russian fishermen, establishment of warning signs, daily patrols and regular port surveillance of potential dog landing activity. Furthermore, scenario analysis revealed that the policy of mandatory domestic dog vaccination does not contribute effectively to Japan's rabies

  3. Data on the weights, specific gravities and chemical compositions of potato (Solanum tuberosum tubers for food processing from different areas of Hokkaido, Japan

    Directory of Open Access Journals (Sweden)

    Hiroaki Sato

    2017-04-01

    Full Text Available This data article provides the weights, specific gravities and chemical compositions (moisture, protein, fat, ash, and carbohydrate of potato tubers, for food processing use, from the Tokachi, Kamikawa and Abashiri areas of Hokkaido, Japan. Potato tubers of four cultivars (‘Toyoshiro’, ‘Kitahime’, ‘Snowden’ and ‘Poroshiri’ were employed in the current study. The weights and specific gravities of potato tubers from each cultivar, harvested from three areas, were measured, and those of near average weight and specific gravity from each group were analyzed for their chemical composition. In this article, weight, specific gravity, and chemical composition data are provided in tables.

  4. Spatial variation in tree seedling density after the site preparation for planting in a cleared coniferous plantation in Hokkaido, northern Japan

    OpenAIRE

    Shin, ChangSeob; Shibuya, Masato

    2007-01-01

    To study spatial variation in natural tree seedling density and the relationship between variation in seedling density and seed dispersal mode at a cleared site, we surveyed natural tree seedlings after the site preparation for planting in a coniferous plantation cleared by a typhoon disturbance in 2004. The site was located near Sikotsuko Lake, Hokkaido, northern Japan. Twenty-five tree seedling species were found and the mean seedling density was 9.8 seedlings/m2. Seedlings of non-animal-di...

  5. Improvements on Signal Processing for HF Radar

    Institute of Scientific and Technical Information of China (English)

    LIU Yongtan; SHEN Yiying

    2001-01-01

    In this paper improvements on signalprocessing are achieved to enhance the performancesof H-F radar system, being unobtainable by the con-ventional signal processing. Using the improved sig-nal processing both high range resolution and longcoherent integration time may be obtained for goodbenefit to the target resolution and weak signal de-tection. Modification to the unmatched correspon-dence between range delay samples and range resolu-tion ceils saves an additional accumulation loss in therange processing. Finally, comparisons between theimproved and the conventional signal processing aregiven by numerical simulation.

  6. Thermoluminescence dating of a tephra deposit of the ''Toya'' volcano (Hokkaido, Japan); Datation par thermoluminescence d'un niveau de tephra du volcan ''Toya'' (Hokkaido, Japon)

    Energy Technology Data Exchange (ETDEWEB)

    Sanzelle, S.; Pilleyre, Th.; Miallier, D.; Fain, J. [Universite Blaise Pascal, Clermont-Ferrand II, (CNRS), Lab. de Physique Corpusculaire, 63 - Aubiere (France); Ganzawa, Y. [Hokkaido Univ. of Education, Hakodate (Japan)

    2000-07-01

    Toya caldera which has a diameter of about 10 km and a hexagonal form is situated in the southern part of Hokkaido, northern Japan. The water level of the caldera lake is 84 m and the highest altitude of the central dome in the lake, Nakajima is 454 m. The volcanic activity is divided into 4 stages of the Toya Pyroclastic Flow Deposits 1 to 4. This tephra is composed of rhyolitic ash which is rich in glass and associated with hornblende, pyroxene and quartz. In a previous work, the age of eruption was estimated by utilising several dating methods and the stratigraphical correlation with other tephra. The ages which resulted from FT (Fission Tracks) dating and TL (Thermoluminescence) dating indicated 130{+-}30 ka and 103-134 ka, respectively. The overall estimated age, received from other information such as the environmental change of mineral marine deposits, has been accepted as 100-120 ka by Quaternary Researchers. Because this tephra can be found widely in the Quaternary field, many researchers can use it as an appropriate age indicator of the 5c or 5d Isotope Stage, the middle age of the Last Internal Glacial Age. A new dating program was initiated, using the red TL of quartz grains extracted from the tephra. The samples studied in the present work came from the southern part of the deposits, around 15 km away from the centre of the caldera. The TL measurements, using the red signal of xenolithic quartz grains from the tephra, were made at Aubiere. Three distinct sets of samples were measured. The first two differ from each other by grain size, 250-350 {mu}m (TOYA2, Aset2) and 150-250 {mu}m (TOYA1,Bset3), and were irradiated in Japan and the third one, 250-350 {mu}m (TOYA2, Cset2) was irradiated at Aubiere. The annual dose rate experienced by the samples during burial was estimated from a compilation of radionuclide contents evaluated in Japan using NAA and in France, using low level gamma spectroscopy (Aubiere) and ICPMS (CRPG, Nancy). In situ water content

  7. Systematic Study on Triaxial Superdeformed Bands of Hf Isotopes

    Institute of Scientific and Technical Information of China (English)

    ZHANG Da-Li; DING Bin-Gang

    2009-01-01

    Properties of the triaxial superdeformed (TSD) bands of Hf isotopes are investigated systematically within the supersymmetry scheme including many-body interactions and a perturbation possessing the SO(5) (or SU(5)) symmetry on the rotational symmetry. Quantitatively good results of the γ-ray energies, the dynamical moments of inertia,and the spin of the TSD bands in Hf isotopes are obtained. It shows that this approach is quite powerful in describing the properties of the triaxial superdeformation in Hf isotopes.

  8. Determining Energy Distributions of HF-Accelerated Electrons at HAARP

    Science.gov (United States)

    2015-11-18

    AFRL-AFOSR-VA-TR-2015-0383 Determining energy distributions of HF-accelerated electrons at HAARP Christopher Fallen University of Alaska Fairbanks...2012 - 11/14/2015 4. TITLE AND SUBTITLE Determining energy distributions of HF-accelerated electrons at HAARP 5a. CONTRACT NUMBER FA9550-12-1-0424...transmitted from the High-frequency Active Auroral Research Program ( HAARP ) transmitter in Alaska. For a given fixed HF-plasma interaction altitude

  9. Physics of the Geospace Response to Powerful HF Radio Waves

    Science.gov (United States)

    2012-10-31

    studies of the response of the Earth’s space plasma to high-power HF radio waves from the High-frequency Active Auroral Research Program ( HAARP ...of HF heating and explored to simulate artificial ducts. DMSP- HAARP experiments revealed that HF-created ion outflows and artificial density ducts...in the topside ionosphere appeared faster than predicted by the models, pointing to kinetic (suprathermal) effects. CHAMP/GRACE- HAARP experiments

  10. PEMISAHAN Zr – Hf SECARA SINAMBUNG MENGGUNAKAN MIXER SETTLER

    Directory of Open Access Journals (Sweden)

    Dwi Biyantoro

    2017-01-01

    Full Text Available ABSTRAK PEMISAHAN Zr – Hf SECARA SINAMBUNG MENGGUNAKANMIXER SETTLER. Telah dilakukan pemisahanZr – Hf secara sinambung menggunakan pengaduk pengenap (mixer settler 16 stage. Larutan umpan adalah zirkon nitrat dengan kadar Zr = 30786 ppm dan Hf = 499 ppm. Ekstraktan dipakai adalah solven 60 % TBP dalam kerosen dan larutan scrubbingyang dipakai adalah asam nitrat 1 M. Umpan masuk pada stageke 5 dikontakkan secara berlawanan arah dengan solven masuk pada stage ke 16 dan larutan scrubbing masuk pada stage ke 1. Tujuan penelitian ini adalah memisahkan unsur Zr dan Hf dari hasil olah pasir zirkon menggunakan solven TBP dengan alat mixer settler16 stage. Analisis umpan dan hasil proses pemisahan untuk zirkonium (Zr dilakukan dengan menggunakan alat pendar sinar-X, sedangkananalisis unsur hafnium (Hf menggunakan Analisis Pengaktifan Neutron (APN. Parameter penelitian dilakukan dengan variasi keasaman asam nitrat dalam umpan dan variasi waktu pada berbagai laju pengadukan. Hasil penelitian pemisahan unsur Zr dengan Hf diperolehkondisi optimum pada keasaman umpan 4 N HNO3, keseimbangan dicapai setelah 3jam dan laju pengadukan 3300 rpm. Hasil ekstrak  unsur zirkon (Zr diperoleh kadar sebesar 28577 ppm dengan efisiensi 92,76 % serta kadar pengotor hafnium (Hf sebesar 95 ppm. Kata Kunci: pemisahan Zr, Hf, ekstraksi, mixer settler, alat pendar sinar-X, APN. ABSTRACT SEPARATION of Zr - Hf CONTINUOUSLY USE THE MIXER SETTLER. Separation of Zr - Hf continuously using mixer settler 16 stage has been done. The feed solution is zircon nitrate concentration of Zr = 30786 ppm  and Hf = 499 ppm. As the solvent used extractant 60 % TBP in 40 % kerosene. Nitric acid solution used srubbing 1 M. The feed entered into stage to 5 is contacted with solvents direction on the stage to 16 and the scrubbing solution enter the stage to 1. The purpose of this study is to separate Zr and Hf of the results from the process of zircon sand using solvent TBP using 16 stage

  11. Mitigating Doppler shift effect in HF multitone data modem

    Science.gov (United States)

    Sonlu, Yasar

    1989-09-01

    Digital communications over High Frequency (HF) radio channels are getting important in recent years. Current HF requirements are for data transmission at rates 2.4 kbps or more to accommodate computer data links and digital secure voice. HF modems which were produced to meet these speeds are, serial modems and parallel modems. On the other hand, the HF sky-wave communication medium, the ionosphere, has some propagation problems such as multipath and Doppler shift. The effect of Doppler shift in a parallel modem which employs Differential Quadrature Phase Shift Keying (DQPSK) modulation is considered and a correction method to mitigate the Doppler Shift effect is introduced.

  12. Epitaxial Thin Films of Y doped HfO2

    Science.gov (United States)

    Serrao, Claudy; Khan, Asif; Ramamoorthy, Ramesh; Salahuddin, Sayeef

    Hafnium oxide (HfO2) is one of a few metal oxides that is thermodynamically stable on silicon and silicon oxide. There has been renewed interest in HfO2 due to the recent discovery of ferroelectricity and antiferroelectricity in doped HfO2. Typical ferroelectrics - such as strontium bismuth tantalate (SBT) and lead zirconium titanate (PZT) - contain elements that easily react with silicon and silicon oxide at elevated temperatures; therefore, such ferroelectrics are not suited for device applications. Meanwhile, ferroelectric HfO2 offers promise regarding integration with silicon. The stable phase of HfO2 at room temperature is monoclinic, but HfO2 can be stabilized in the tetragonal, orthorhombic or even cubic phase by suitable doping. We stabilized Y-doped HfO2 thin films using pulsed laser deposition. The strain state can be controlled using various perovskite substrates and controlled growth conditions. We report on Y-doped HfO2 domain structures from piezo-response force microscopy (PFM) and structural parameters via X-ray reciprocal space maps (RSM). We hope this work spurs further interest in strain-tuned ferroelectricity in doped HfO2.

  13. Microstructural characterization of as-cast hf-b alloys

    Directory of Open Access Journals (Sweden)

    João Carlos Jânio Gigolotti

    2012-04-01

    Full Text Available An accurate knowledge of several metal-boron phase diagrams is important to evaluation of higher order systems such as metal-silicon-boron ternaries. The refinement and reassessment of phase diagram data is a continuous work, thus the reevaluation of metal-boron systems provides the possibility to confirm previous data from an investigation using higher purity materials and better analytical techniques. This work presents results of rigorous microstructural characterization of as-cast hafnium-boron alloys which are significant to assess the liquid composition associated to most of the invariant reactions of this system. Alloys were prepared by arc melting high purity hafnium (minimum 99.8% and boron (minimum 99.5% slices under argon atmosphere in water-cooled copper crucible with non consumable tungsten electrode and titanium getter. The phases were identified by scanning electron microscopy, using back-scattered electron image mode and X-ray diffraction. In general, a good agreement was found between our data and those from the currently accepted Hafnium-Boron phase diagram. The phases identified are αHfSS and B-RhomSS, the intermediate compounds HfB and HfB2 and the liquide L. The reactions are the eutectic L ⇔ αHfSS + HfB and L ⇔ HfB2 + B-Rhom, the peritectic L + HfB2 ⇔ HfB and the congruent formation of HfB2.

  14. A DFT study of temperature dependent dissociation mechanism of HF in HF(H2O)7 cluster

    Indian Academy of Sciences (India)

    Swatantra K Yadav; Hirdyesh Mishra; Ashwani K Tiwari

    2015-10-01

    We report a Density Functional Theoretical (DFT) study of dissociation of Hydrogen Fluoride (HF) in HF(H2O)7 cluster, using B3LYP functional and empirical exchange correlation functional M06-2X along with 6-31+G(d,p) basis set. Dissociation constant, KRP, of HF dissociation and pKa values of HF in cluster at various temperatures have been reported. It has been found that both KRP and pKa are highly dependent on temperature. The variation of pKa with temperature suggests that HF is strong acid at lower temperatures. Our study also reveals that HF is a stronger acid in water cluster than in bulk water. Further, the results obtained by DFT calculations have been compared with the earlier reported results obtained from Monte Carlo (MC) simulation. It is found that DFT results are qualitatively consistent with the results of MC simulation but quantitatively different.

  15. Evaluating renewable natural resources flow and net primary productivity with a GIS-Emergy approach: A case study of Hokkaido, Japan

    Science.gov (United States)

    Wang, Chengdong; Zhang, Shenyan; Yan, Wanglin; Wang, Renqing; Liu, Jian; Wang, Yutao

    2016-11-01

    Renewable natural resources, such as solar radiation, rainfall, wind, and geothermal heat, together with ecosystem services, provide the elementary supports for the sustainable development of human society. To improve regional sustainability, we studied the spatial distributions and quantities of renewable natural resources and net primary productivity (NPP) in Hokkaido, which is the second largest island of Japan. With the help of Geographic Information System (GIS) software, distribution maps for each type of renewable natural resource were generated by kriging interpolation based on statistical records. A composite map of the flow of all types of renewable natural resources was also generated by map layer overlapping. Additionally, we utilized emergy analysis to convert each renewable flow with different attributes into a unified unit (i.e., solar equivalent joules [sej]). As a result, the spatial distributions of the flow of renewable natural resources of the Hokkaido region are presented in the form of thematic emergy maps. Thus, the areas with higher renewable emergy can be easily visualized and identified. The dominant renewable flow in certain areas can also be directly distinguished. The results can provide useful information for regional sustainable development, environmental conservation and ecological management.

  16. Evaluating renewable natural resources flow and net primary productivity with a GIS-Emergy approach: A case study of Hokkaido, Japan.

    Science.gov (United States)

    Wang, Chengdong; Zhang, Shenyan; Yan, Wanglin; Wang, Renqing; Liu, Jian; Wang, Yutao

    2016-11-18

    Renewable natural resources, such as solar radiation, rainfall, wind, and geothermal heat, together with ecosystem services, provide the elementary supports for the sustainable development of human society. To improve regional sustainability, we studied the spatial distributions and quantities of renewable natural resources and net primary productivity (NPP) in Hokkaido, which is the second largest island of Japan. With the help of Geographic Information System (GIS) software, distribution maps for each type of renewable natural resource were generated by kriging interpolation based on statistical records. A composite map of the flow of all types of renewable natural resources was also generated by map layer overlapping. Additionally, we utilized emergy analysis to convert each renewable flow with different attributes into a unified unit (i.e., solar equivalent joules [sej]). As a result, the spatial distributions of the flow of renewable natural resources of the Hokkaido region are presented in the form of thematic emergy maps. Thus, the areas with higher renewable emergy can be easily visualized and identified. The dominant renewable flow in certain areas can also be directly distinguished. The results can provide useful information for regional sustainable development, environmental conservation and ecological management.

  17. Hf-W chronometry of primitive achondrites

    Science.gov (United States)

    Schulz, T.; Münker, C.; Mezger, K.; Palme, H.

    2010-03-01

    Metal segregation and silicate melting on asteroids are the most incisive differentiation events in the early evolution of planetary bodies. The timing of these events can be constrained using the short-lived 182Hf- 182W radionuclide system. Here we present new 182Hf- 182W data for major types of primitive achondrites including acapulcoites, winonaites and one lodranite. These meteorites are of particular interest because they show only limited evidence for partial melting of silicates and are therefore intermediate between chondrites and achondrites. For acapulcoites we derived a 182Hf- 182W age of Δ tCAI = 4.1 +1.2/ -1.1 Ma. A model age for winonaite separates calculated from the intercept of the isochron defines an age of Δ tCAI = 4.8 +3.1/ -2.6 Ma (assuming a bulk Hf/W ratio of ˜1.2). Both ages most likely define primary magmatic events on the respective parent bodies, such as melting of metal, although metal stayed in place and did not segregate to form a core. A later thermal event is responsible for resetting of the winonaite isochron, yielding an age of Δ tCAI = 14.3 +2.7/ -2.2 Ma, significantly younger than the model age. Assuming a co-genetic relationship between winonaites and silicates present in IAB iron meteorites (based on oxygen isotope composition) and including data by Schulz et al. (2009), a common parent body chronology can be established. Magmatic activity occurred between ˜1.5 and 5 Ma after CAIs. More than 5 Ma later, intensive thermal metamorphism has redistributed Hf-W. Average cooling rates calculated for the winonaite/IAB parent asteroid range between ˜35 and ˜4 K/Ma, most likely reflecting different burial depths. Cooling rates obtained for acapulcoites were ˜40 K/Ma to ˜720 K and then ˜3 K/Ma to ˜550 K. Accretion and subsequent magmatism on the acapulcoite parent body occurred slightly later if compared to most achondrite parent bodies (e.g., angrites, ureilites and eucrites), in this case supporting the concept of an inverse

  18. Effects of a windthrow disturbance on the carbon balance of a broadleaf deciduous forest in Hokkaido, Japan

    Directory of Open Access Journals (Sweden)

    K. Yamanoi

    2015-12-01

    Full Text Available Forests play an important role in the terrestrial carbon balance, with most being in a carbon sequestration stage. The net carbon releases that occur result from forest disturbance, and windthrow is a typical disturbance event affecting the forest carbon balance in eastern Asia. The CO2 flux has been measured using the eddy covariance method in a deciduous broadleaf forest (Japanese white birch, Japanese oak, and castor aralia in Hokkaido, where incidental damage by the strong Typhoon Songda in 2004 occurred. We also used the biometrical method to demonstrate the CO2 flux within the forest in detail. Damaged trees amounted to 40 % of all trees, and they remained on site where they were not extracted by forest management. Gross primary production (GPP, ecosystem respiration (Re, and net ecosystem production were 1350, 975, and 375 g C m−2 yr−1 before the disturbance and 1262, 1359, and −97 g C m−2 yr−1 2 years after the disturbance, respectively. Before the disturbance, the forest was an evident carbon sink, and it subsequently transformed into a net carbon source. Because of increased light intensity at the forest floor, the leaf area index and biomass of the undergrowth (Sasa kurilensis and S. senanensis increased by factors of 2.4 and 1.7, respectively, in 3 years subsequent to the disturbance. The photosynthesis of Sasa increased rapidly and contributed to the total GPP after the disturbance. The annual GPP only decreased by 6 % just after the disturbance. On the other hand, the annual Re increased by 39 % mainly because of the decomposition of residual coarse-wood debris. The carbon balance after the disturbance was controlled by the new growth and the decomposition of residues. The forest management, which resulted in the dead trees remaining at the study site, strongly affected the carbon balance over the years. When comparing the carbon uptake efficiency at the study site with that at others, including those with various kinds

  19. Explosive eruptive activity and temporal magmatic changes at Yotei Volcano during the last 50,000 years, southwest Hokkaido, Japan

    Science.gov (United States)

    Uesawa, Shimpei; Nakagawa, Mitsuhiro; Umetsu, Akane

    2016-10-01

    To understand the eruptive history, structure, and magmatic evolution of Yotei Volcano, southwest Hokkaido, Japan, we investigated the geology and petrology of tephras located around the base of the volcano. We identified 43 tephra units interbedded with soils (in descending stratigraphic order, tephras Y1-Y43), and four widespread regional tephras. Ten radiocarbon ages were obtained from soils beneath the Yotei tephras. On the basis of petrologic differences and, the stratigraphic positions of thick layers of volcanic ash soil, indicative of volcanic stratigraphic gaps, the Yotei tephras are divided into four groups (in ascending stratigraphic order): Yotei tephra groups I, II-1, II-2, and II-3. We calculated the age of each eruptive deposit based on the soil accumulation rate, and estimated the volume of each eruption using isopach maps or the correlation between eruption volume and the maximum thickness at ~ 10 km from the summit crater. The results regarding eruptive activity and the rate of explosive eruptions indicate four eruptive stages at Yotei Volcano over the last 50,000 years. Stage I eruptions produced Yotei tephra group I between ca. 54 cal. ka BP and up to at least ca. 46 cal. ka BP, at relatively high average eruption rates of 0.07 km3 dense-rock equivalent (DRE)/ky. After a pause in activity of ca. 8000 years, Stage II-1 to II-2 eruptions produced Yotei tephra groups II-1 and II-2 from ca. 38 to ca. 21 cal. ka BP at high average eruption rates (0.10 km3 DRE/ky), after a pause in activity of 2000-3000 years. Finally, after another pause in activity of 4000-5000 years, Stage II-3 eruptions produced Yotei tephra group II-3 from ca. 16.5 cal. ka BP until the present day, at low average eruption rates (0.009 km3 DRE/ky). Whole-rock geochemical compositions vary within each tephra group over the entire eruption history. For example, group I and II-3 tephras contain the lowest and highest abundances, respectively, of K2O, P2O5, and Zr. Group II-1 has the

  20. Pressure induced novel compounds in the Hf-O system from first-principles calculations

    OpenAIRE

    2015-01-01

    Using first-principles evolutionary simulations, we have systematically investigated phase stability in the Hf-O system at pressure up to 120 GPa. New compounds Hf5O2, Hf3O2, HfO and HfO3 are discovered to be thermodynamically stable at certain pressure ranges and a new stable high-pressure phase is found for Hf2O with space group Pnnm and anti-CaCl2-type structure. Both P62m-HfO and P4m2-Hf2O3 show semimetallic character. Pnnm-HfO3 shows interesting structure, simultaneously containing oxide...

  1. Ferroelectricity of nondoped thin HfO2 films in TiN/HfO2/TiN stacks

    Science.gov (United States)

    Nishimura, Tomonori; Xu, Lun; Shibayama, Shigehisa; Yajima, Takeaki; Migita, Shinji; Toriumi, Akira

    2016-08-01

    We report on the impact of TiN interfaces on the ferroelectricity of nondoped HfO2. Ferroelectric properties of nondoped HfO2 in TiN/HfO2/TiN stacks are shown in capacitance-voltage and polarization-voltage characteristics. The Curie temperature is also estimated to be around 500 °C. The ferroelectricity of nondoped HfO2 clearly appears by thinning HfO2 film down to ˜35 nm. We directly revealed in thermal treatments that the ferroelectric HfO2 film on TiN was maintained by covering the top surface of HfO2 with TiN, while it was followed by a phase transition to the paraelectric phase in the case of the open surface of HfO2. Thus, it is concluded that the ferroelectricity in nondoped HfO2 in this study was mainly driven by both of top and bottom TiN interfaces.

  2. Synthesis of Freestanding HfO2 Nanostructures

    Science.gov (United States)

    2011-04-05

    Tang J, Fabbri J, Robinson RD, Zhu Y, Herman IP, Steigerwald ML, Brus LE: Solid-solution nanoparticles:use of a nonhydrolytic sol-gel synthesis to...colloidal HfO2 nanorods. Adv Mater 2007, 19:2608-2612. Page 21 5. Qiu X, Howe JY, Cardoso MB, Polat O, Heller W: Size control of highly ordered HfO2

  3. Parametric excitation of whistler waves by HF heater

    Science.gov (United States)

    Kuo, S. P.; Lee, M. C.

    1989-01-01

    Possible generation of whistler waves by Tromso HF heater is investigated. It is shown that the HF heater wave can parametrically decay into a whistler wave and a Langmuir wave. Since whistler waves may have a broad range of frequency, the simultaneously excited Langmuir waves can have a much broader frequency bandwidth than those excited by the parametric decay instability.

  4. Study of {sup 179}Hf{sup m2} excitation

    Energy Technology Data Exchange (ETDEWEB)

    Vishnevsky, I. N.; Zheltonozhsky, V. A., E-mail: zhelton@kinr.kiev.ua; Savrasov, A. N. [National Academy of Sciences of Ukraine, Institute for Nuclear Research (Ukraine); Mazur, V. M. [National Academy of Sciences of Ukraine, Institute of Electronic Physics (Ukraine)

    2016-12-15

    Isomeric ratios of {sup 179}Hf{sup m2,g} yields in the (γ, n) reaction and the cross section for the {sup 179}Hf{sup m2} population in the (α, p) reaction are measured for the first time at the end-point energies of 15.1 and 17.5 MeV for bremsstrahlung photons and 26 MeV for alpha particles. The results are σ = (1.1 ± 0.11) × 10{sup −27} cm{sup 2} for the {sup 176}Lu(α, p){sup 179}Hf{sup m2} reaction and Y{sub m2}/Y{sub g} = (6.1 ± 0.3) × 10{sup −6} and (3.7 ± 0.2) × 10{sup −6} for the {sup 180}Hf(γ, n){sup 179}Hf{sup m22} reaction at E{sub ep} =15.1 and 17.5 MeV, respectively. The experimental data on the relative {sup 179}Hf{sup m2} yield indicate a single-humped shape of the excitation function for the {sup 180}Hf(γ, n){sup 179}Hf{sup m2} reaction. Simulation is performed using the TALYS-1.4 and EMPIRE-3.2 codes.

  5. Diffusion of Hf and Nb in Zr-19%Nb

    Energy Technology Data Exchange (ETDEWEB)

    Zou, H. [Atomic Energy of Canada Ltd., Chalk River, ON (Canada). Chalk River Nuclear Labs.; Hood, G.M. [Atomic Energy of Canada Ltd., Chalk River, ON (Canada). Chalk River Nuclear Labs.; Schultz, R.J. [Atomic Energy of Canada Ltd., Chalk River, ON (Canada). Chalk River Nuclear Labs.; Matsuura, N. [Atomic Energy of Canada Ltd., Chalk River, ON (Canada). Chalk River Nuclear Labs.; Roy, J.A. [Atomic Energy of Canada Ltd., Chalk River, ON (Canada). Chalk River Nuclear Labs.; Jackman, J.A. [CANMET, Ottawa, Ont. (Canada). Met. Sci. and Technol.

    1996-05-01

    Diffusion of Hf and Nb in large-grained bcc Zr-19%Nb has been studied. Diffusion coefficients of Hf, D(Hf), were measured in the range 620-1173 K and D(Nb) was measured at 920 and 1167 K. The Hf diffusion profiles were determined by SIMS and the Nb profiles by microtome sectioning and radio-tracer counting. The Hf data show a smooth, temperature-dependent behaviour through the monotectoid temperature, 875 K, and may be characterised by D{approx}10{sup -9}.exp-1.4 (eV/kT) m{sup 2}/s. D(Nb) tends to be lower than the corresponding values for D(Hf). Overall, diffusion of Hf and Nb are characteristic of diffusion in bcc Zr. Surface hold-up (oxide film) at low temperatures was overcome by using ion-implanted Hf diffusion sources. The results are compared with earlier work and discussed in terms of diffusion mechanisms and the {beta}-phase transformation of commercial Zr-2.5Nb. (orig.).

  6. Pulsed flows at the high-altitude cusp poleward boundary, and associated ionospheric convection and particle signatures, during a Cluster - FAST - SuperDARN- Søndrestrøm conjunction under a southwest IMF

    Directory of Open Access Journals (Sweden)

    C. J. Farrugia

    2004-09-01

    Full Text Available Particle and magnetic field observations during a magnetic conjunction Cluster 1-FAST-Søndrestrøm within the field of view of SuperDARN radars on 21 January 2001 allow us to draw a detailed, comprehensive and self-consistent picture at three heights of signatures associated with transient reconnection under a steady south-westerly IMF (clock angle ≈130°. Cluster 1 was outbound through the high altitude (~12RE exterior northern cusp tailward of the bifurcation line (geomagnetic Bx>0 when a solar wind dynamic pressure release shifted the spacecraft into a boundary layer downstream of the cusp. The centerpiece of the investigation is a series of flow bursts observed there by the spacecraft, which were accompanied by strong field perturbations and tailward flow deflections. Analysis shows these to be Alfvén waves. We interpret these flow events as being due to a sequence of reconnected flux tubes, with field-aligned currents in the associated Alfvén waves carrying stresses to the underlying ionosphere, a view strengthened by the other observations. At the magnetic footprint of the region of Cluster flow bursts, FAST observed an ion energy-latitude disperison of the stepped cusp type, with individual cusp ion steps corresponding to individual flow bursts. Simultaneously, the SuperDARN Stokkseyri radar observed very strong poleward-moving radar auroral forms (PMRAFs which were conjugate to the flow bursts at Cluster. FAST was traversing these PMRAFs when it observed the cusp ion steps. The Søndrestrøm radar observed pulsed ionospheric flows (PIFs just poleward of the convection reversal boundary. As at Cluster, the flow was eastward (tailward, implying a coherent eastward (tailward motion of the hypothesized open flux tubes. The joint Søndrestrøm and FAST observations indicate that the open/closed field line boundary was equatorward of the convection reversal boundary by ~2°. The unprecedented accuracy

  7. Oxygen Recovery in Hf Oxide Films Fabricated by Sputtering

    Institute of Scientific and Technical Information of China (English)

    JIANG Ran; LI Zi-Feng

    2009-01-01

    The chemical structure of ultrathin Hf oxide films (< 10 nm) fabricated by a standard sputtering method is investigated using x-ray spectroscopy and Rutherford backscattering spectroscopy. According to the experiments,oxygen species are impacted to the HfO2/Si interface during the initial sputtering, and then released back to the upper Hf02 region driven by the oxygen concentration grads. A vacuum annealing can greatly enhance this recovery process. Additionally, significant SiO2 reduction in the interface is observed after the vacuum annealing for the thick HfO2 films in our experiment. It might be an effective method to confine the interracial layer thickness by sputtering thick HfO2 in no-oxygen ambient.

  8. Crystal structure of Si-doped HfO2

    Science.gov (United States)

    Zhao, Lili; Nelson, Matthew; Aldridge, Henry; Iamsasri, Thanakorn; Fancher, Chris M.; Forrester, Jennifer S.; Nishida, Toshikazu; Moghaddam, Saeed; Jones, Jacob L.

    2014-01-01

    Si-doped HfO2 was prepared by solid state synthesis of the starting oxides. Using Rietveld refinement of high resolution X-ray diffraction patterns, a substitutional limit of Si in HfO2 was determined as less than 9 at. %. A second phase was identified as Cristobalite (SiO2) rather than HfSiO4, the latter of which would be expected from existing SiO2-HfO2 phase diagrams. Crystallographic refinement with increased Si-dopant concentration in monoclinic HfO2 shows that c/b increases, while β decreases. The spontaneous strain, which characterizes the ferroelastic distortion of the unit cell, was calculated and shown to decrease with increasing Si substitution.

  9. The (178m2)Hf Controversy

    Energy Technology Data Exchange (ETDEWEB)

    Becker, J A; Gemmell, D S; Schiffer, J P; Wilhelmy, J B

    2003-07-24

    Since its discovery in the 1960's the {sup 178m2}Hf isomer has garnered high attention from both the basic and applied communities in nuclear science. It's combination of high spin (16+), long half life (31 yrs), and high excitation energy (2.446 MeV) offer unique possibilities as an energy storage medium. Interest in the isomer was rekindled beginning in 1999 when a series of publications began to appear from a group (referred to here as the ''Texas collaboration'') primarily based at the University of Texas, Dallas [1]. They reported observations that some of the stored energy could be released (''triggered'') when the isomer was exposed to a fluence of photons in the energy range {approx}10 to {approx}60 keV. The implications of this observation are profound. Even though the claimed cross section for the process was {approx}7 orders of magnitude greater than would be predicted from the known systematics of photon absorption by nuclei in this mass range [2], such a highly efficient method for triggering the isomeric deexcitation immediately suggested applications utilizing the explosive or the controlled gradual energy release from a very compact source. The prospect of such applications has focused considerable interest on realizing the promise that is implicit in the reported observations. However, two experiments performed by a group from ANL/LANL/LLNL at the Advanced Photon Source at Argonne (the ''APS collaboration'') reported negative results for the observation of any photon-triggered deexcitation of the {sup 178m2}Hf isomer [3]. This has led to a continued controversy, where both sides have adamantly defended their observations. At this point an outsider has difficulty determining whether there is indeed a triggering effect that should be pursued energetically with substantial resources, or whether the phenomenon consists of overly optimistic interpretation of data.

  10. Characterization of a non-pathogenic H5N1 influenza virus isolated from a migratory duck flying from Siberia in Hokkaido, Japan, in October 2009

    Directory of Open Access Journals (Sweden)

    Okamatsu Masatoshi

    2011-02-01

    Full Text Available Abstract Background Infection with H5N1 highly pathogenic avian influenza viruses (HPAIVs of domestic poultry and wild birds has spread to more than 60 countries in Eurasia and Africa. It is concerned that HPAIVs may be perpetuated in the lakes in Siberia where migratory water birds nest in summer. To monitor whether HPAIVs circulate in migratory water birds, intensive surveillance of avian influenza has been performed in Mongolia and Japan in autumn each year. Until 2008, there had not been any H5N1 viruses isolated from migratory water birds that flew from their nesting lakes in Siberia. In autumn 2009, A/mallard/Hokkaido/24/09 (H5N1 (Mal/Hok/24/09 was isolated from a fecal sample of a mallard (Anas platyrhynchos that flew from Siberia to Hokkaido, Japan. The isolate was assessed for pathogenicity in chickens, domestic ducks, and quails and analyzed antigenically and phylogenetically. Results No clinical signs were observed in chickens inoculated intravenously with Mal/Hok/24/09 (H5N1. There was no viral replication in chickens inoculated intranasally with the isolate. None of the domestic ducks and quails inoculated intranasally with the isolate showed any clinical signs. There were no multiple basic amino acid residues at the cleavage site of the hemagglutinin (HA of the isolate. Each gene of Mal/Hok/24/09 (H5N1 is phylogenetically closely related to that of influenza viruses isolated from migratory water birds that flew from their nesting lakes in autumn. Additionally, the antigenicity of the HA of the isolate was similar to that of the viruses isolated from migratory water birds in Hokkaido that flew from their northern territory in autumn and different from those of HPAIVs isolated from birds found dead in China, Mongolia, and Japan on the way back to their northern territory in spring. Conclusion Mal/Hok/24/09 (H5N1 is a non-pathogenic avian influenza virus for chickens, domestic ducks, and quails, and is antigenically and genetically

  11. Ferroelectricity-modulated resistive switching in Pt/Si:HfO2/HfO2-x /Pt memory

    Science.gov (United States)

    Ran, Jiang; Xianghao, Du; Zuyin, Han

    2016-08-01

    It is investigated for the effect of a ferroelectric Si:HfO2 thin film on the resistive switching in a stacked Pt/Si:HfO2/highly-oxygen-deficient HfO2-x /Pt structure. Improved resistance performance was observed. It was concluded that the observed resistive switching behavior was related to the modulation of the width and height of a depletion barrier in the HfO2-x layer, which was caused by the Si:HfO2 ferroelectric polarization field effect. Reliable switching reproducibility and long data retention were observed in these memory cells, suggesting their great potential in non-volatile memories applications with full compatibility and simplicity. Project supported by the National Natural Science Foundation of China (No. 11374182), the Natural Science Foundation of Shandong Province (No. ZR2012FQ012), and the Jinan Independent Innovation Projects of Universities (No. 201303019).

  12. Power-Stepped HF Cross Modulation Experiments at HAARP

    Science.gov (United States)

    Greene, S.; Moore, R. C.; Langston, J. S.

    2013-12-01

    High frequency (HF) cross modulation experiments are a well established means for probing the HF-modified characteristics of the D-region ionosphere. In this paper, we apply experimental observations of HF cross-modulation to the related problem of ELF/VLF wave generation. HF cross-modulation measurements are used to evaluate the efficiency of ionospheric conductivity modulation during power-stepped modulated HF heating experiments. The results are compared to previously published dependencies of ELF/VLF wave amplitude on HF peak power. The experiments were performed during the March 2013 campaign at the High Frequency Active Auroral Research Program (HAARP) Observatory. HAARP was operated in a dual-beam transmission format: the first beam heated the ionosphere using sinusoidal amplitude modulation while the second beam broadcast a series of low-power probe pulses. The peak power of the modulating beam was incremented in 1-dB steps. We compare the minimum and maximum cross-modulation effect and the amplitude of the resulting cross-modulation waveform to the expected power-law dependence of ELF/VLF wave amplitude on HF power.

  13. Chemical deicer poisoning was suspected as a cause of the 2005-2006 wintertime mortality of small wild birds in Hokkaido.

    Science.gov (United States)

    Tanaka, Tomohisa; Tanoue, Ginpei; Yamasaki, Masahiro; Takashima, Ikuo; Sakoda, Yoshihiro; Ochiai, Kenji; Umemura, Takashi

    2008-06-01

    Many small wild birds died in the 2005-2006 wintertime in Hokkaido. Thirteen birds were pathologically examined and it was attempted to detect West Nile and influenza viruses from their organs. Consecutive pathological changes were fresh hemorrhage and acute circulatory failure. Viral detections were negative. Selective occurrence in wintertime, literature review and the results of pathological and virological examinations suggested chemical deicer poisoning as the cause of wild bird death. Chicks treated orally with deicer showed acute death and their pathological changes were similar to those of the wild birds. Because the chicks showed significant elevation of plasma Na concentration, plasma electrolyte analysis of the affected wild birds might be crucial to confirm our tentative diagnosis.

  14. Characteristics of postseismic deformation following the 2003 Tokachi-oki earthquake and estimation of the viscoelastic structure in Hokkaido, northern Japan

    Science.gov (United States)

    Itoh, Yuji; Nishimura, Takuya

    2016-09-01

    Postseismic deformation of the 2003 Tokachi-oki earthquake ( M w 8.0) has been observed by GNSS. We analyzed the deformation observed in Hokkaido in the 2nd to the 7th year following the 2003 Tokachi-oki earthquake and examined the effect of two major mechanisms (i.e., afterslip and viscoelastic relaxation) for the observed postseismic deformation by fitting it with a model consisting of afterslip and viscoelastic relaxation. The thickness of the lithosphere, the viscosity of the asthenosphere, and the time decaying constant of afterslip were estimated to be 50 km, 2.0 × 1019 Pa s, and 0.110 year, respectively, which are concordant with those in the Tohoku region estimated in previous studies. The revealed characteristics of postseismic deformation are as follows. At most of the used stations, afterslip played the dominant role in the 2nd year and was still sustained near the coseismic area even in the 7th year. However, the calculated velocity due to viscoelastic relaxation was comparable to that due to afterslip at the stations in northern Hokkaido after the 5th year. Because the calculated velocity due to viscoelastic relaxation was landward near the coseismic slip area, afterslip near the coseismic slip area will be biased to be smaller if viscoelastic relaxation is ignored. A systematic spatial pattern of the residuals considering afterslip only highlights an importance for explaining the observation data. We also examined the effect of viscoelastic relaxation due to afterslip for the parameter estimation and found that it was too small to affect the estimated structure parameters.[Figure not available: see fulltext.

  15. Landscape patterns of overstory litterfall and related nutrient fluxes in a cool-temperate forest watershed in northern Hokkaido,Japan

    Institute of Scientific and Technical Information of China (English)

    XU Xiao-niu; Hideaki SHIBATA

    2007-01-01

    Within a forested watershed at the Uryu Experimental Forest of Hokkaido University in northern Hokkaido, overstory litterfall and related nutrient fluxes were measured at different landscape zones over two years. The wetland zone covered with Picea glehnii pure stand. The riparian zone was deciduous broad-leaved stand dominated by Alnus hirsuta and Salix spp., while the mixture of deciduous broadleaf and evergreen conifer dominated by Betula platyphylla, Quercus crispula and Abies sachalinensis distributed on the upland zone.Annual litterfall averaged 1444, 5122, and 4123 kg·hm-2·a-1 in the wetland, riparian and upland zones, respectively. Litterfall production peaked in September-ctober,and foliage litter contributed the greatest amount (73.4%-87.6 %) of the annual total litterfall. Concentrations of nutrients analyzed in foliage litter of the dominant species showed a similar seasonal variation over the year except for N in P. Glehnii and A. Hirsuta. The nutrient fluxes for all elements analyzed were greatest on riparian zone and lowest in wetland zone. Nutrient fluxes via lit terfall followed the decreasing sequence: N (11-129 kg·hm-2·a-1) > Ca (9-69) > K (5-20) > Mg (3-15) > P (0.4-4.7) for all stands. Significant differences were found in litterfall production and nutrient fluxes among the different landscape components. There existed significantdif ferences in soil chemistry between the different landscape zones. The consistently low soil C:N ratios at the riparian zone might be due to the higher-quality litter inputs (largely N-fixing alder).

  16. Brachylaima ezohelicis sp. nov. (Trematoda: Brachylaimidae) found from the land snail Ezohelix gainesi, with a note of an unidentified Brachylaima species in Hokkaido, Japan.

    Science.gov (United States)

    Nakao, Minoru; Waki, Tsukasa; Sasaki, Mizuki; Anders, Jason L; Koga, Daisuke; Asakawa, Mitsuhiko

    2017-06-01

    In the Japanese Archipelago, Ezohelix gainesi, a member of bradybaenid land snails, is endemic mainly to the island of Hokkaido. During July to August of 2016, a survey to detect trematode infections from E. gainesi was carried out at a forest city park in Asahikawa, Hokkaido. Systemic infections of the snails with sporocysts containing short-tailed cercariae were found in 5.3% of 94 individuals examined. Furthermore, most of them (90.4%) harbored non-encysted metacercariae within their kidneys. A DNA sequence identification revealed that both of the sporocyst and the metacercaria belong to an unknown species of the family Brachylaimidae. The metacercariae showed a genetic diversity with 6 haplotypes of mitochondrial DNA (mtDNA) even in the limited sampling area. A definitive host of the unknown species could not be determined, although 34 field mice (Apodemus speciosus) and 21 voles (Myodes rufocanus) from the city park were examined for intestinal parasites. To examine the adult stage, the metacercariae were perorally administrated to mice, together with anti-inflammatory treatment with methylprednisolone. Fully matured adult worms were recovered from the intestinal ileum 8 and 14days postinfection. The gravid adults showed typical features of the genus Brachylaima. A morphological and biogeographical evaluation prompted us to propose Brachylaima ezohelicis sp. nov. for the parasite from E. gainesi. The autochthony of the first intermediate host and the spatial heterogeneity of mtDNA suggest that the new species found in the city park is not a recently expanded population of immigrant origin. Copyright © 2017 Elsevier B.V. All rights reserved.

  17. HF dissociation in water clusters by computer simulations

    OpenAIRE

    Elena, Alin Marin

    2013-01-01

    We perform Restrained hybrid Monte Carlo simulations to compute the equilibrium constant of the dissociation reaction of HF in HF(H2O)7. We find that, like in the bulk, hydrofluoric acid, is a weak acid also in the cubic HF(H2O)7 cluster, and that its acidity is higher at lower T. This latter phenomenon has a (vibrational) entropic origin, namely it is due to the reduction of the (negative) T∆S contribution to the variation of free energy between the reactant and product. We found also ...

  18. Ionospheric heating with oblique HF waves

    Science.gov (United States)

    Field, Edward C., Jr.; Bloom, Ron M.

    1990-10-01

    Calculations of ionospheric electron density perturbations and ground-level signal changes produce by intense oblique high frequency (HF) transmitters are presented. This analysis considers radio field focusing at caustics, the consequent joule-heating of the surrounding plasma, heat conduction, diffusion, and recombination processes: these being the effects of a powerful oblique 'modifying' wave. It neglects whatever plasma instabilities might occur. Then effects on a secondary 'test' wave that is propagated along the same path as the first are investigated. Calculations predict ground-level field-strength reductions of several dB in the test wave for modifying waves having ERP in the 85 to 90 dBW range. These field-strength changes are similar in sign, magnitude, and location to ones measured in Soviet experiments. The results are sensitive to the model ionosphere assumed, so future experiments should employ the widest possible range of frequencies and propagation conditions. An effective power of 90 dBW seems to be a sort of threshold that, if exceeded, results in substantial rather than small signal changes. The conclusions are based solely on joule-heating and subsequent defocusing of waves passing through caustic regions.

  19. Process Simulation Analysis of HF Stripping

    Directory of Open Access Journals (Sweden)

    Thaer A. Abdulla

    2013-05-01

    Full Text Available    HYSYS process simulator is used for the analysis of existing HF stripping column in LAB plant (Arab Detergent Company, Baiji-Iraq. Simulated column performance and profiles curves are constructed. The variables considered are the thermodynamic model option, bottom temperature, feed temperature, and column profiles for the temperature, vapor flow rate, liquid flow rate and composition. The five thermodynamic models options used (Margules, UNIQUAC, van laar, Antoine, and Zudkevitch-Joffee, affecting the results within (0.1-58% variation for the most cases.        The simulated results show that about 4% of paraffin (C10 & C11 presents at the top stream, which may cause a problem in the LAB production plant. The major variations were noticed for the total top vapor flow rate with bottom temperature and with feed composition. The column profiles maintain fairly constants from tray 5 to tray 18. The study gives evidence about a successful simulation with HYSYS because the results correspond with the real plant operation data.

  20. The (178m2) Hf Controversy

    CERN Document Server

    Becker, J A; Schiffer, J P; Wilhelmy, J

    2003-01-01

    Since its discovery in the 1960's the sup 1 sup 7 sup 8 sup m sup 2 Hf isomer has garnered high attention from both the basic and applied communities in nuclear science. It's combination of high spin (16+), long half life (31 yrs), and high excitation energy (2.446 MeV) offer unique possibilities as an energy storage medium. Interest in the isomer was rekindled beginning in 1999 when a series of publications began to appear from a group (referred to here as the ''Texas collaboration'') primarily based at the University of Texas, Dallas [1]. They reported observations that some of the stored energy could be released (''triggered'') when the isomer was exposed to a fluence of photons in the energy range approx 10 to approx 60 keV. The implications of this observation are profound. Even though the claimed cross section for the process was approx 7 orders of magnitude greater than would be predicted from the known systematics of photon absorption by nuclei in this mass range [2], such a highly efficient method fo...

  1. Grindability of cast Ti-Hf alloys.

    Science.gov (United States)

    Kikuchi, Masafumi; Takahashi, Masatoshi; Sato, Hideki; Okuno, Osamu; Nunn, Martha E; Okabe, Toru

    2006-04-01

    As part of our systematic studies characterizing the properties of titanium alloys, we investigated the grindability of a series of cast Ti-Hf alloys. Alloy buttons with hafnium concentrations up to 40 mass% were made using an argon-arc melting furnace. Each button was cast into a magnesia-based mold using a dental titanium casting machine; three specimens were made for each metal. Prior to testing, the hardened surface layer was removed. The specimens were ground at five different speeds for 1 min at 0.98 N using a carborundum wheel on an electric dental handpiece. Grindability was evaluated as the volume of metal removed per minute (grinding rate) and the volume ratio of metal removed compared to the wheel material lost (grinding ratio). The data were analyzed using ANOVA. A trend of increasing grindability was found with increasing amounts of hafnium, although there was no statistical difference in the grindability with increasing hafnium contents. We also found that hafnium may be used to harden or strengthen titanium without deteriorating the grindability.

  2. The magnetic properties of $^{\\rm 177}$Hf and $^{\\rm 180}$Hf in the strong coupling deformed model

    OpenAIRE

    Muto, S.; Stone, N. J.; Bingham, C. R.; STONE, J.R; Walker, P. M.; Audi, G.; Gaulard, C.; Köster, U.(Institut Laue-Langevin (ILL), Grenoble, France); Nikolov, J.; Nishimura,K; Ohtsubo, T.; Podolyak, Z.; Risegari, L.; Simpson, G.S.; Veskovic, M.

    2014-01-01

    This paper reports NMR measurements of the magnetic dipole moments of two high-K isomers, the 37/2$^-$, 51.4 m, 2740 keV state in $^{\\rm 177}$Hf and the 8$^-$, 5.5 h, 1142 keV state in $^{\\rm 180}$Hf by the method of on-line nuclear orientation. Also included are results on the angular distributions of gamma transitions in the decay of the $^{\\rm 177}$Hf isotope. These yield high precision E2/M1 multipole mixing ratios for transitions in bands built on the 23/2$^+$, 1.1 s, isomer at 1315 keV ...

  3. A thirty second isomer in {sup 171}Hf

    Energy Technology Data Exchange (ETDEWEB)

    Campbell, P.; Billowes, J.; Cooper, T.G.; Grant, I.S.; Pearson, M.R.; Wheeler, P.D. [Schuster Laboratory, University of Manchester, M13 9PL (United Kingdom); Cochrane, E.C.A.; Cooke, J.L.; Evans, D.E.; Griffith, J.A.R.; Persson, J.R.; Richardson, D.S.; Tungate, G.; Zybert, L. [School of Physics and Space Research, University of Birmingham, Edgbaston, Birmingham B15 2TT (United Kingdom); Dendooven, P.; Honkanen, A.; Huhta, M.; Oinonen, M.; Penttilae, H.; Aeystoe, J. [Accelerator Laboratory, University of Jyvaeskylae, PL 35 Jyvaeskylae SF-403 51 (Finland)

    1997-09-01

    An isomer has been detected in {sup 171}Hf with a half-life of T{sub 1/2} 29.5(9) s. The state was populated in the {sup 170}Yb({alpha},3n){sup 171m}Hf reaction at a beam energy of E{sub {alpha}} = 50 MeV in an on-line ion guide isotope separator. The isomeric {sup 171m}Hf{sup +} beam was extracted from the ion guide, mass-analysed and implanted in the surface of a microchannel-plate. The half-life of the collected activity was measured from the decay of the microchannel-plate count rate. We associate the isomer with the first excited state in {sup 171}Hf with spin 1/2{sup -} at an excitation energy of 22(2) keV. (author)

  4. HF fiber stuffing in building 186 at CERN

    CERN Multimedia

    Tiziano Camporesi

    2003-01-01

    Each of the 36 HF wedges comprise ca 12000 quartz fibers which are the active element of the calorimeter. The fibers are produced by Polymicro (USA), cleaved and bundled at KFKI, Budapest, Hungary and inserted at CERN.

  5. Low-Frequency Waves in HF Heating of the Ionosphere

    Science.gov (United States)

    Sharma, A. S.; Eliasson, B.; Milikh, G. M.; Najmi, A.; Papadopoulos, K.; Shao, X.; Vartanyan, A.

    2016-02-01

    Ionospheric heating experiments have enabled an exploration of the ionosphere as a large-scale natural laboratory for the study of many plasma processes. These experiments inject high-frequency (HF) radio waves using high-power transmitters and an array of ground- and space-based diagnostics. This chapter discusses the excitation and propagation of low-frequency waves in HF heating of the ionosphere. The theoretical aspects and the associated models and simulations, and the results from experiments, mostly from the HAARP facility, are presented together to provide a comprehensive interpretation of the relevant plasma processes. The chapter presents the plasma model of the ionosphere for describing the physical processes during HF heating, the numerical code, and the simulations of the excitation of low-frequency waves by HF heating. It then gives the simulations of the high-latitude ionosphere and mid-latitude ionosphere. The chapter also briefly discusses the role of kinetic processes associated with wave generation.

  6. Near-infrared LIF spectroscopy of HfF

    CERN Document Server

    Grau, Matt; Loh, Huanqian; Sinclair, Laura C; Stutz, Russel P; Yahn, Tylser S; Cornell, Eric A

    2012-01-01

    The molecular ion HfF$^+$ is the chosen species for a JILA experiment to measure the electron electric dipole moment (eEDM). Detailed knowledge of the spectrum of HfF is crucial to prepare HfF$^+$ in a state suitable for performing an eEDM measurement\\cite{Leanhardt}. We investigated the near-infrared electronic spectrum of HfF using laser-induced fluorescence (LIF) of a supersonic molecular beam. We discovered eight unreported bands, and assign each of them unambiguously, four to vibrational bands belonging to the transition $[13.8]0.5 \\leftarrow X1.5$, and four to vibrational bands belonging to the transition $[14.2]1.5 \\leftarrow X1.5$. Additionally, we report an improved measurement of vibrational spacing of the ground state, as well as anharmonicity $\\omega_e x_e$.

  7. Theoretical Assessment of 178m2Hf De-Excitation

    Energy Technology Data Exchange (ETDEWEB)

    Hartouni, E P; Chen, M; Descalle, M A; Escher, J E; Loshak, A; Navratil, P; Ormand, W E; Pruet, J; Thompson, I J; Wang, T F

    2008-10-06

    This document contains a comprehensive literature review in support of the theoretical assessment of the {sup 178m2}Hf de-excitation, as well as a rigorous description of controlled energy release from an isomeric nuclear state.

  8. Integrated magnetics design for HF-link power converters

    DEFF Research Database (Denmark)

    Ljusev, Petar; Andersen, Michael Andreas E.

    2005-01-01

    This paper deals with the design of integrated magnetics for HF-link converters, where the integrated magnetic components do not necessarily belong to the same voltage loop. Depending on the specific HF-link converter topology, the proposed integrated magnetics can either alleviate the derivation...... of independent auxiliary supply voltages from the main transformer or integrate other magnetic structures, thus saving board space and cutting costs....

  9. Integrated magnetics design for HF-link power converters

    Energy Technology Data Exchange (ETDEWEB)

    Ljusev, P.; Andersen, Michael A.E.

    2005-07-01

    This paper deals with the design of integrated magnetics for HF-link converters, where the two integrated magnetic components on the same core do not necessarily belong to the same voltage loop. Depending on the specific HF-link converter topology, the proposed integrated magnetics can either alleviate the derivation of independent auxiliary supply voltages from the main transformer or integrate other magnetic structures, thus saving board space and cutting costs. (au)

  10. Synthesis of freestanding HfO2 nanostructures

    Directory of Open Access Journals (Sweden)

    Boyle Kayla

    2011-01-01

    Full Text Available Abstract Two new methods for synthesizing nanostructured HfO2 have been developed. The first method entails exposing HfTe2 powders to air. This simple process resulted in the formation of nanometer scale crystallites of HfO2. The second method involved a two-step heating process by which macroscopic, freestanding nanosheets of HfO2 were formed as a byproduct during the synthesis of HfTe2. These highly two-dimensional sheets had side lengths measuring up to several millimeters and were stable enough to be manipulated with tweezers and other instruments. The thickness of the sheets ranged from a few to a few hundred nanometers. The thinnest sheets appeared transparent when viewed in a scanning electron microscope. It was found that the presence of Mn enhanced the formation of HfO2 by exposure to ambient conditions and was necessary for the formation of the large scale nanosheets. These results present new routes to create freestanding nanostructured hafnium dioxide. PACS: 81.07.-b, 61.46.Hk, 68.37.Hk.

  11. The isobutylene-isobutane alkylation process in liquid HF revisited.

    Science.gov (United States)

    Esteves, P M; Araújo, C L; Horta, B A C; Alvarez, L J; Zicovich-Wilson, C M; Ramírez-Solís, A

    2005-07-07

    Details on the mechanism of HF catalyzed isobutylene-isobutane alkylation were investigated. On the basis of available experimental data and high-level quantum chemical calculations, a detailed reaction mechanism is proposed taking into account solvation effects of the medium. On the basis of our computational results, we explain why the density of the liquid media and stirring rates are the most important parameters to achieve maximum yield of alkylate, in agreement with experimental findings. The ab initio Car-Parrinello molecular dynamics calculations show that isobutylene is irreversibly protonated in the liquid HF medium at higher densities, leading to the ion pair formation, which is shown to be a minimum on the potential energy surface after optimization using periodic boundary conditions. The HF medium solvates preferentially the fluoride anion, which is found as solvated [FHF](-) or solvated F(-.)(HF)(3). On the other hand, the tert-butyl cation is weakly solvated, where the closest HF molecules appear at a distance of about 2.9 Angstrom with the fluorine termination of an HF chain.

  12. Hf impurity and defect interactions in helium-implanted NiHf

    Energy Technology Data Exchange (ETDEWEB)

    Govindaraj, R. E-mail: govind@igcar.ernet.in; Gopinathan, K.P.; Viswanathan, B

    2001-07-01

    TDPAC measurements on the reference and untreated sample indicate a loss in anisotropy which is attributed mainly to the association of probe atoms with defects produced by (n,{gamma}) reactions with isotopes of Ni and experiencing combined magnetic and quadrupole interactions of comparable strengths. Evolution of defect free and substitutional fraction of probe atoms experiencing Larmor frequency characteristic of Ni matrix has been studied as a function of isochronal annealing temperature in helium free {alpha}-irradiated and homogeneously helium-implanted samples. No defect associated Larmor precession frequency and/or quadrupole frequency could be deduced in these uncorrelated damage studies. Comparison of recovery stages in {alpha}-irradiated and helium-implanted samples indicates the binding of helium associated defects by Hf impurities. Segregation of Hf atoms is observed in the helium free {alpha}-irradiated sample for annealing treatment at 973 K, while no such effect is observed in the helium-implanted sample for isochronal annealing treatments up to 1273 K.

  13. Reconciliation of the excess 176Hf conundrum in meteorites: Recent disturbances of the Lu-Hf and Sm-Nd isotope systematics

    Science.gov (United States)

    Bast, Rebecca; Scherer, Erik E.; Sprung, Peter; Mezger, Klaus; Fischer-Gödde, Mario; Taetz, Stephan; Böhnke, Mischa; Schmid-Beurmann, Hinrich; Münker, Carsten; Kleine, Thorsten; Srinivasan, Gopalan

    2017-09-01

    The long-lived 176Lu-176Hf and 147Sm-143Nd radioisotope systems are commonly used chronometers, but when applied to meteorites, they can reveal disturbances. Specifically, Lu-Hf isochrons commonly yield dates up to ∼300 Myr older than the solar system and varying initial 176Hf/177Hf values. We investigated this problem by attempting to construct mineral and whole rock isochrons for eucrites and angrites. Meteorites from different parent bodies exhibit similar disturbance features suggesting that a common process is responsible. Minerals scatter away from isochron regressions for both meteorite classes, with low-Hf phases such as plagioclase and olivine typically being most displaced above (or left of) reference isochrons. Relatively Hf-rich pyroxene is less disturbed but still to the point of steepening Lu-Hf errorchrons. Using our Lu-Hf and Sm-Nd data, we tested various Hf and Lu redistribution scenarios and found that decoupling of Lu/Hf from 176Hf/177Hf must postdate the accumulation of significant radiogenic 176Hf. Therefore early irradiation or diffusion cannot explain the excess 176Hf. Instead, disturbed meteorite isochrons are more likely caused by terrestrial weathering, contamination, or common laboratory procedures. The partial dissolution of phosphate minerals may predominantly remove rare earth elements including Lu, leaving relatively immobile and radiogenic Hf behind. Robust Lu-Hf (and improved Sm-Nd) meteorite geochronology will require the development of chemical or physical methods for removing unsupported radiogenic Hf and silicate-hosted terrestrial contaminants without disturbing parent-daughter ratios.

  14. Tracking magmatic processes through Zr/Hf ratios in rocks and Hf and Ti zoning in zircons: An example from the Spirit Mountain batholith, Nevada

    Science.gov (United States)

    Lowery, Claiborne L.E.; Miller, C.F.; Walker, B.A.; Wooden, J.L.; Mazdab, F.K.; Bea, F.

    2006-01-01

    Zirconium and Hf are nearly identical geochemically, and therefore most of the crust maintains near-chondritic Zr/Hf ratios of ???35-40. By contrast, many high-silica rhyolites and granites have anomalously low Zr/Hf (15-30). As zircon is the primary reservoir for both Zr and Hf and preferentially incorporates Zr, crystallization of zircon controls Zr/ Hf, imprinting low Zr/Hf on coexisting melt. Thus, low Zr/Hf is a unique fingerprint of effective magmatic fractionation in the crust. Age and compositional zonation in zircons themselves provide a record of the thermal and compositional histories of magmatic systems. High Hf (low Zr/ Hf) in zircon zones demonstrates growth from fractionated melt, and Ti provides an estimate of temperature of crystallization (TTiZ) (Watson and Harrison, 2005). Whole-rock Zr/Hf and zircon zonation in the Spirit Mountain batholith, Nevada, document repeated fractionation and thermal fluctuations. Ratios of Zr/Hf are ???30-40 for cumulates and 18-30 for high-SiO2 granites. In zircons, Hf (and U) are inversely correlated with Ti, and concentrations indicate large fluctuations in melt composition and TTiZ (>100??C) for individual zircons. Such variations are consistent with field relations and ion-probe zircon geochronology that indicate a >1 million year history of repeated replenishment, fractionation, and extraction of melt from crystal mush to form the low Zr/Hf high-SiO2 zone. ?? 2006 The Mineralogical Society.

  15. Determination of isothermal section of Ni-Re-Hf ternary system at 1173 K

    Institute of Scientific and Technical Information of China (English)

    王日初; 柳春雷; 金展鹏

    2002-01-01

    The phase equilibriua in the Ni-Re-Hf ternary system at 1173K were investigated by means of diffusion triple technique and electron microprobe analysis(EMPA). The experimental results indicate that two ternary intermetallics (α and β) and five binary intermetallics (Ni3Hf, Ni10Hf7, Ni11Hf9, NiHf and NiHf2) exist in the Ni-Re-Hf system at 1173 K. A tentative isothermal section of this system at 1173 K was constructed on the basis of experimental results. The isothermal section consists of nine three-phase regions, five of which are supported by the experimental data.

  16. Spallation and fission products in the (p+{sup 179}Hf) and (p+{sup nat}Hf) reactions

    Energy Technology Data Exchange (ETDEWEB)

    Karamian, S.A. [Joint Institute for Nuclear Research, Moscow Region, Dubna 141980 (Russian Federation); Ur, C.A. [Horia Hulubei National Institute of Physics and Nuclear Engineering, P.O. Box MG-6, Bucharest 077125 (Romania); Induced Gamma Emission Foundation, P.O. Box 34-81, Bucharest 010044 (Romania)], E-mail: ur@pd.infn.it; Adam, J. [Joint Institute for Nuclear Research, Moscow Region, Dubna 141980 (Russian Federation); Institute of Nuclear Physics, Rez, Prague CZ-25068 (Czech Republic); Kalinnikov, V.G.; Lebedev, N.A.; Vostokin, G.K. [Joint Institute for Nuclear Research, Moscow Region, Dubna 141980 (Russian Federation); Collins, C.B. [Center for Quantum Electronics, University of Texas at Dallas, Richardson, TX 75083 (United States); Popescu, I.I. [Induced Gamma Emission Foundation, P.O. Box 34-81, Bucharest 010044 (Romania)

    2009-03-01

    Production of Hf and Lu high-spin isomers has been experimentally studied in spallation reactions induced by intermediate energy protons. Targets of enriched {sup 179}Hf (91%) and {sup nat}Hf were bombarded with protons of energy in the range from 90 to 650 MeV provided by the internal beam of the Dubna Phasotron synchrocyclotron. The activation yields of the reaction products were measured by using the {gamma}-ray spectroscopy and radiochemistry methods. The production cross-sections obtained for the {sup 179m2}Hf, {sup 178m2}Hf and {sup 177m}Lu isomers are similar to the previously measured values from the spallation of Ta, Re and W targets. Therefore, the reactions involving emission of only a few nucleons, like (p,p'), (p,p'n) and (p,2pn), can transfer high enough angular momentum to the final residual nuclei with reasonable large cross-sections. A significant gain in the isomeric yields was obtained when enriched {sup 179}Hf targets were used. The mass distribution of the residual nuclei was measured over a wide range of masses and the fission-to-spallation ratio could be deduced as a function of the projectile energy. Features of the reaction mechanism are briefly discussed.

  17. Hf-Nd isotope and trace element constraints on subduction inputs at island arcs: Limitations of Hf anomalies as sediment input indicators

    Science.gov (United States)

    Handley, Heather K.; Turner, Simon; Macpherson, Colin G.; Gertisser, Ralf; Davidson, Jon P.

    2011-04-01

    New Nd-Hf isotope and trace element data for Javanese volcanoes are combined with recently published data to place constraints on subduction inputs at the Sunda arc in Indonesia and assess the value of Hf anomalies (expressed as Hf/Hf* and Sm/Hf ratios) as tracers of such inputs. Hf anomaly does not correlate with Hf isotope ratio in Javanese lavas, however, Hf/Hf* and Sm/Hf ratios do correlate with SiO 2. Contrary to previous work, we show that Hf anomaly variation may be controlled by fractionation of clinopyroxene and/or amphibole during magmatic differentiation and does not represent the magnitude or type of subduction input in some arcs. Correlation of Sm/Hf with indices of differentiation for other arcs (e.g., Vanuatu, New Britain, and Mariana) suggests that differentiation control on Sm/Hf ratios in volcanic arc rocks may be a relatively common phenomenon. This study corroborates the use of Nd-Hf isotope co-variations in arc volcanic rocks to ascertain subduction input characteristics. The trajectories of regional volcano groups (East, Central and West Java) in Nd-Hf isotope space reveal heterogeneity in the subducted sediment input along Java, which reflects present-day spatial variations in sediment compositions on the down-going plate in the Java Trench. The high Sm/Hf ratio required in the sediment end-member for some Javanese basalts suggests that partial melting of subducted sediment occurs in the presence of residual zircon, and is inconsistent with residual monazite or allanite.

  18. Investigation and Development of Data-Driven D-Region Model for HF Systems Impacts

    Science.gov (United States)

    Eccles, J. V.; Rice, D.; Sojka, J. J.; Hunsucker, R. D.

    2002-01-01

    Space Environment Corporation (SEC) and RP Consultants (RPC) are to develop and validate a weather-capable D region model for making High Frequency (HF) absorption predictions in support of the HF communications and radar communities. The weather-capable model will assimilate solar and earth space observations from NASA satellites. The model will account for solar-induced impacts on HF absorption, including X-rays, Solar Proton Events (SPE's), and auroral precipitation. The work plan includes: I . Optimize D-region model to quickly obtain ion and electron densities for proper HF absorption calculations. 2. Develop indices-driven modules for D-region ionization sources for low, mid, & high latitudes including X-rays, cosmic rays, auroral precipitation, & solar protons. (Note: solar spectrum & auroral modules already exist). 3. Setup low-cost monitors of existing HF beacons and add one single-frequency beacon. 4. Use PENEX HF-link database with HF monitor data to validate D-region/HF absorption model using climatological ionization drivers. 5. Develop algorithms to assimilate NASA satellite data of solar, interplanetary, and auroral observations into ionization source modules. 6. Use PENEX HF-link & HF-beacon data for skill score comparison of assimilation versus climatological D-region/HF absorption model. Only some satellites are available for the PENEX time period, thus, HF-beacon data is necessary. 7. Use HF beacon monitors to develop HF-link data assimilation algorithms for regional improvement to the D-region/HF absorption model.

  19. Serpentinization Changes Nd, but not Hf Isotopes of Abyssal Peridotites

    Science.gov (United States)

    Bizimis, M.; Frisby, C. P.; Mallick, S.

    2015-12-01

    Serpentinization of the oceanic lithosphere is a known sink for fluid mobile elements (B, Cl, Li, Sr, etc.), while high field strength elements (HFSE: e.g., Hf, Zr, Ti, Nb) are thought to be unaffected by it. In contrast, the fate of REE during serpentinization is equivocal. Correlations between REE and HFSE concentrations in abyssal peridotites suggest control by magmatic processes (Niu, 2004, J. Pet), while some LREE enrichments in serpentinized peridotites compared to their clinopyroxene (cpx) and Nd, Sr isotope data (Delacour et al., 2008, Chem. Geol.) imply seawater-derived REE addition to the mantle protolith (Paulick et al., 2006, Chem. Geol). To further constrain peridotite-seawater interaction during serpentinization we compare bulk rock and cpx Hf and Nd isotope data in partially (up to ~70%) serpentinized abyssal peridotites (9-16°E South West Indian Ridge). We also present a new method that improves yields in Hf, Nd and Pb separations from depleted (90% of Hf, Zr, Ti are retained in the residue. LA-ICPMS data shows that serpentine after olivine typically has higher LREE/HREE ratios than cpx, pronounced negative Ce anomalies, high U, Sr concentrations and low HFSE, unlike the coexisting cpx. These data are consistent with some seawater-derived LREE addition to peridotite during serpentinization, localized in the serpentine and other secondary phases, while cpx retains the magmatic value. This process will lower the Sm/Nd relative to Lu/Hf ratio in the peridotite and can lead to decoupled radiogenic Hf and unradiogenic Nd isotopes upon recycling and aging. Our data further testifies to the fidelity of Hf isotopes in tracing mantle processes, even in serpentinized rocks.

  20. Joint Efforts Towards European HF Radar Integration

    Science.gov (United States)

    Rubio, A.; Mader, J.; Griffa, A.; Mantovani, C.; Corgnati, L.; Novellino, A.; Schulz-Stellenfleth, J.; Quentin, C.; Wyatt, L.; Ruiz, M. I.; Lorente, P.; Hartnett, M.; Gorringe, P.

    2016-12-01

    During the past two years, significant steps have been made in Europe for achieving the needed accessibility to High Frequency Radar (HFR) data for a pan-European use. Since 2015, EuroGOOS Ocean Observing Task Teams (TT), such as HFR TT, are operational networks of observing platforms. The main goal is on the harmonization of systems requirements, systems design, data quality, improvement and proof of the readiness and standardization of HFR data access and tools. Particular attention is being paid by HFR TT to converge from different projects and programs toward those common objectives. First, JERICO-NEXT (Joint European Research Infrastructure network for Coastal Observatory - Novel European eXpertise for coastal observaTories, H2020 2015 Programme) will contribute on describing the status of the European network, on seeking harmonization through exchange of best practices and standardization, on developing and giving access to quality control procedures and new products, and finally on demonstrating the use of such technology in the general scientific strategy focused by the Coastal Observatory. Then, EMODnet (European Marine Observation and Data Network) Physics started to assemble HF radar metadata and data products within Europe in a uniform way. This long term program is providing a combined array of services and functionalities to users for obtaining free of charge data, meta-data and data products on the physical conditions of European sea basins and oceans. Additionally, the Copernicus Marine Environment Monitoring Service (CMEMS) delivers from 2015 a core information service to any user related to 4 areas of benefits: Maritime Safety, Coastal and Marine Environment, Marine Resources, and Weather, Seasonal Forecasting and Climate activities. INCREASE (Innovation and Networking for the integration of Coastal Radars into EuropeAn marine SErvices - CMEMS Service Evolution 2016) will set the necessary developments towards the integration of existing European

  1. First-principles study of the Hf-based Heusler alloys: Hf2CoGa and Hf2CoIn

    Science.gov (United States)

    Hu, Yan; Zhang, Jian-Min

    2017-01-01

    The electronic structures and magnetic properties of the new Heusler alloys Hf2CoGa and Hf2CoIn have been studied by using the first-principles projector augmented wave (PAW) potential within the generalized gradient approximation (GGA). Both Hf2CoGa and Hf2CoIn Heusler alloys have the half-metallic character and completely (100%) spin polarization at the Fermi level (EF) and the indirect band gaps of 0.733 eV and 0.654 eV, respectively, in the minority spin channel. The total magnetic moments μt are all 2μB per formula unit, linearly scaled with the total number of valence electrons (Zt) by μt=Zt-18 and the atomic magnetic moments have localized character due to less affected by deformations. The origin of the indirect band gaps for these two new Heusler alloys is well understood. These two new Heusler alloys are the ideal candidates for spintronic devices.

  2. HF omnidirectional spectral CW auroral radar (HF-OSCAR) at very high latitude. Part 1: Technique

    Science.gov (United States)

    Olesen, J. K.; Jacobsen, K. E.; Stauning, P.; Henriksen, S.

    1983-12-01

    An HF system for studies of very high latitude ionospheric irregularities was described. Radio aurora from field-aligned E-region irregularities of the Slant E Condition type were discussed. The complete system combines an ionosonde, a 12 MHz pulse radar and a 12 MHz bistatic CW Doppler-range set-up. The two latter units use alternately a 360 deg rotating Yagi antenna. High precision oscillators secure the frequency stability of the Doppler system in which the received signal is mixed down to a center frequency of 500 Hz. The Doppler shift range is max + or - 500 Hz. The received signal is recorded in analog form on magnetic tape and may be monitored visually and audibly. Echo range of the CW Doppler signal is obtained by a 150 Hz amplitude modulation of the transmitted signal and phase comparison with the backscattered signal.

  3. Comparison of HfAlO, HfO2/Al2O3, and HfO2 on n-type GaAs using atomic layer deposition

    Science.gov (United States)

    Lu, Bin; Lv, Hongliang; Zhang, Yuming; Zhang, Yimen; Liu, Chen

    2016-11-01

    Different high-permittivity (high-k) gate dielectric structures of HfO2, HfAlO, and HfO2/Al2O3 deposited on HF-etched n-GaAs using ALD have been investigated. It has been demonstrated that the stacked structure of HfO2/Al2O3 has the lowest interface state density of 8.12 × 1012eV-1 cm-2 due to the "self-cleaning" reaction process, but the sample of HfAlO shows much better frequency dispersion and much higher dielectric permittivity extracted from the C-V curves. The investigation reveals that the electrical properties of gate dielectrics are improved by introducing alumina into HfO2.

  4. Molecular characterization and specific detection of Anaplasma species (AP-sd) in sika deer and its first detection in wild brown bears and rodents in Hokkaido, Japan.

    Science.gov (United States)

    Moustafa, Mohamed Abdallah Mohamed; Lee, Kyunglee; Taylor, Kyle; Nakao, Ryo; Sashika, Mariko; Shimozuru, Michito; Tsubota, Toshio

    2015-12-01

    A previously undescribed Anaplasma species (herein referred to as AP-sd) has been detected in sika deer, cattle and ticks in Japan. Despite being highly similar to some strains of A. phagocytophilum, AP-sd has never been detected in humans. Its ambiguous epidemiology and the lack of tools for its specific detection make it difficult to understand and interpret the prevalence of this Anaplasma species. We developed a method for specific detection, and examined AP-sd prevalence in Hokkaido wildlife. Our study included 250 sika deer (Cervus nippon yesoensis), 13 brown bears (Ursus arctos yesoensis) and 252 rodents including 138 (Apodemus speciosus), 45 (Apodemus argenteus), 42 (Myodes rufocanus) and 27 (Myodes rutilus) were collected from Hokkaido island, northern Japan, collected during 2010 to 2015. A 770 bp and 382 bp segment of the 16S rRNA and gltA genes, respectively, were amplified by nested PCR. Results were confirmed by cloning and sequencing of the positive PCR products. A reverse line blot hybridization (RLB) based on the 16S rRNA gene was then developed for the specific detection of AP-sd. The prevalence of AP-sd by nested PCR in sika deer was 51% (128/250). We detected this Anaplasma sp. for the first time in wild brown bears and rodents with a prevalence of 15% (2/13) and 2.4% (6/252), respectively. The sequencing results of the 16S rRNA and gltA gene amplicons were divergent from the selected A. phagocytophilum sequences in GenBank. Using a newly designed AP-sd specific probe for RLB has enabled us to specifically detect this Anaplasma species. Besides sika deer and cattle, wild brown bears and rodents were identified as potential reservoir hosts for AP-sd. This study provided a high throughput molecular method that specifically detects AP-sd, and which can be used to investigate its ecology and its potential as a threat to humans in Japan.

  5. Mechanical properties of cast Ti-Hf alloys.

    Science.gov (United States)

    Sato, Hideki; Kikuchi, Masafumi; Komatsu, Masashi; Okuno, Osamu; Okabe, Toru

    2005-02-15

    This study examined the mechanical properties of a series of Ti-Hf alloys. Titanium alloys with 10 to 40 mass % Hf were made with titanium and hafnium sponge in an argon-arc melting furnace. Specimens cast into magnesia-based investment molds were tested for yield strength, tensile strength, percentage elongation, and modulus of elasticity. Vickers microhardness was determined at 25 to 600 microm from the cast surface. X-ray diffractometry was also performed. Commercially pure Ti (CP Ti) and pure Ti prepared from titanium sponge were used as controls. The data (n = 5) were analyzed with a one-way ANOVA and the Student-Newman-Keuls test (alpha = 0.05). The diffraction peaks of all the metals matched those for alpha Ti; no beta phase peaks were found. Alloys with Hf > or = 25% had significantly (p 0.05) in elongation among all the Ti-Hf alloys and CP Ti, whereas the elongation of alloys with Hf > or = 30% was significantly (p alloys tested can be considered viable alternatives to CP Ti because they were stronger than CP Ti and had similar elongation.

  6. HfO2 Gate Dielectrics for Future Generation of CMOS Device Application

    Institute of Scientific and Technical Information of China (English)

    H.Y.Yu; J.F.Kang; Ren Chi; M.F.Li; D.L.Kwong

    2004-01-01

    The material and electrical properties of HfO2 high-k gate dielectric are reported.In the first part,the band alignment of HfO2 and (HfO2)x(Al2O3)1-x to (100)Si substrate and their thermal stability are studied by X-ray photoelectron spectroscopy and TEM.The energy gap of (HfO2)x(Al2O3)1-x,the valence band offset,and the conduction band offset between (HfO2)x(Al2O3)1-x and the Si substrate as functions of x are obtained based on the XPS results.Our XPS results also demonstrate that both the thermal stability and the resistance to oxygen diffusion of HfO2 are improved by adding Al to form Hf aluminates.In the second part,a thermally stable and high quality HfN/HfO2 gate stack is reported.Negligible changes in equivalent oxide thickness (EOT),gate leakage,and work function (close to Si mid-gap) of HfN/HfO2 gate stack are demonstrated even after 1000℃ post-metal annealing(PMA),which is attributed to the superior oxygen diffusion barrier of HfN as well as the thermal stability of the HfN/HfO2 interface.Therefore,even without surface nitridation prior to HfO2 deposition,the EOT of HfN/HfO2 gate stack has been successfully scaled down to less than 1nm after 1000℃ PMA with excellent leakage and long-term reliability.The last part demonstrates a novel replacement gate process employing a HfN dummy gate and sub-1nm EOT HfO2 gate dielectric.The excellent thermal stability of the HfN/HfO2 gate stack enables its use in high temperature CMOS processes.The replacement of HfN with other metal gate materials with work functions adequate for n- and p-MOS is facilitated by a high etch selectivity of HfN with respect to HfO2,without any degradation to the EOT,gate leakage,or TDDB characteristics of HfO2.

  7. Pressure-induced novel compounds in the Hf-O system from first-principles calculations

    Science.gov (United States)

    Zhang, Jin; Oganov, Artem R.; Li, Xinfeng; Xue, Kan-Hao; Wang, Zhenhai; Dong, Huafeng

    2015-11-01

    Using first-principles evolutionary simulations, we have systematically investigated phase stability in the Hf-O system at pressure up to 120 GPa. New compounds Hf5O2,Hf3O2 , HfO, and HfO3 are discovered to be thermodynamically stable at certain pressure ranges. Two new high-pressure phases are found for Hf2O : one with space group Pnnm and anti-CaCl2-type structure, another with space group I 41/amd. Pnnm-HfO3 shows interesting structure, simultaneously containing oxide O2 - and peroxide [O-O]2 - anions. Remarkably, it is P 6 ¯2 m -HfO rather than OII-HfO2 that exhibits the highest mechanical characteristics among Hf-O compounds. Pnnm-Hf2O , Imm2-Hf5O2 ,P 3 ¯1 m -Hf2O , and P 4 ¯m 2 -Hf2O3 phases also show superior mechanical properties; theoretically these phases become metastable phases to ambient pressure and their properties can be exploited.

  8. Effect of HF leaching on 14C dates of pottery

    Science.gov (United States)

    Goslar, Tomasz; Kozłowski, Janusz; Szmyt, Marzena; Czernik, Justyna

    2013-01-01

    This paper presents the experiments with 14C dating of two potsherds, which contained carbon dispersed rather homogeneously in their clay fabric. After AAA treatment, the potsherds still appeared to be contaminated with young carbon, presumably connected with humic acids. To make removal of humic acids more effective, we treated the sherds with HF acid of different concentration. The 14C results obtained demonstrate that HF treatment indeed helps to remove humic contaminants, but it also mobilizes carbon bound to raw clay, which may make 14C dates too old. We conclude therefore, that using a simple combination of HF and AAA treatment seems insufficient in reliable 14C dating of carbon homogeneously dispersed in the volume of potsherds.

  9. Specific molecular detection of Anaplasma sp. closely related to Anaplasma phagocytophilum in ixodid ticks and cattle in a pastureland in Hokkaido, Japan.

    Science.gov (United States)

    Ybañez, Adrian P; Tagawa, Michihito; Matsumoto, Kotaro; Kishimoto, Toshio; Yokoyama, Naoaki; Inokuma, Hisashi

    2013-01-01

    Recent molecular analyses of the Anaplasma sp. closely related to Anaplasma phagocytophilum (previously believed to be A. phagocytophilum) in Japan have clarified its distinct phylogenetic position. PCR methods relying on 16S rRNA- and P44/MSP2-based primers designed to detect this species have low sensitivity and specificity. In this study, a highly sensitive and specific nested PCR method using newly designed primers based on heat-shock operon gene (groEL) was developed to detect this species. The method was later used in an epidemiological study testing DNA samples from 85 Ixodid ticks (collected by flagging) and 50 cattle from the same pastureland in Nakaosobetsu, Hokkaido, Japan. Results revealed prevalence rates of 2.4% (2 of 85) in ticks and 2% (1 of 50) in cattle. The present study also reported the first molecular detection of the Anaplasma sp. closely related to A. phagocytophilum in Japan in H. douglasii, and established a new reliable PCR method that detects this Anaplasma sp. closely related to A. phagocytophilum in Japan.

  10. Genetic and antigenic characterization of H5 and H7 influenza viruses isolated from migratory water birds in Hokkaido, Japan and Mongolia from 2010 to 2014.

    Science.gov (United States)

    Hiono, Takahiro; Ohkawara, Ayako; Ogasawara, Kohei; Okamatsu, Masatoshi; Tamura, Tomokazu; Chu, Duc-Huy; Suzuki, Mizuho; Kuribayashi, Saya; Shichinohe, Shintaro; Takada, Ayato; Ogawa, Hirohito; Yoshida, Reiko; Miyamoto, Hiroko; Nao, Naganori; Furuyama, Wakako; Maruyama, Junki; Eguchi, Nao; Ulziibat, Gerelmaa; Enkhbold, Bazarragchaa; Shatar, Munkhduuren; Jargalsaikhan, Tserenjav; Byambadorj, Selenge; Damdinjav, Batchuluun; Sakoda, Yoshihiro; Kida, Hiroshi

    2015-08-01

    Migratory water birds are the natural reservoir of influenza A viruses. H5 and H7 influenza viruses are isolated over the world and also circulate among poultry in Asia. In 2010, two H5N1 highly pathogenic avian influenza viruses (HPAIVs) were isolated from fecal samples of water birds on the flyway of migration from Siberia, Russia to the south in Hokkaido, Japan. H7N9 viruses are sporadically isolated from humans and circulate in poultry in China. To monitor whether these viruses have spread in the wild bird population, we conducted virological surveillance of avian influenza in migratory water birds in autumn from 2010 to 2014. A total of 8103 fecal samples from migratory water birds were collected in Japan and Mongolia, and 350 influenza viruses including 13 H5 and 19 H7 influenza viruses were isolated. A phylogenetic analysis revealed that all isolates are genetically closely related to viruses circulating among wild water birds. The results of the antigenic analysis indicated that the antigenicity of viruses in wild water birds is highly stable despite their nucleotide sequence diversity but is distinct from that of HPAIVs recently isolated in Asia. The present results suggest that HPAIVs and Chinese H7N9 viruses were not predominantly circulating in migratory water birds; however, continued monitoring of H5 and H7 influenza viruses both in domestic and wild birds is recommended for the control of avian influenza.

  11. Short-Term Response of Sasa Dwarf Bamboo to a Change of Soil Nitrogen Fertility in a Forest Ecosystem in Northern Hokkaido, Japan.

    Science.gov (United States)

    Watanabe, Tsunehiro; Fukuzawa, Karibu; Shibata, Hideaki

    2016-04-14

    In forest ecosystems, a change of soil nitrogen (N) cycling after disturbance is regulated by various factors. Sasa dwarf bamboo (hereafter referred to as Sasa) is an understory plant that grows thickly on the forest floor in northern Hokkaido, Japan. However, the ecosystem function of Sasa after disturbances in the soil N cycling is not fully understood. The purpose of this study was to determine the short-term response of Sasa to a change of soil N fertility. Biomass, litterfall, litter decomposition, soil N pool, and N leaching from soil were measured in control, and low- (5 g N m(-2) year(-1)) and high-N (15 g N m(-2) year(-1)) addition plots. Sasa immobilized much N as the soil N fertility increased. However, the leaf N concentration in aboveground biomass did not increase, suggesting that the N in leaves was maintained because of the increase of leaf biomass. As a result, the decomposition and mineralization rates of the produced litter before and after N addition were comparable among plots, even though the soil inorganic N fertility increased greatly. These results suggest that immediate response of Sasa to an increase of soil inorganic N mitigates the excess N leaching from soil.

  12. Muon radiography and deformation analysis of the lava dome formed by the 1944 eruption of Usu, Hokkaido--contact between high-energy physics and volcano physics--.

    Science.gov (United States)

    K M Tanaka, Hiroyuki; Yokoyama, Izumi

    2008-01-01

    Lava domes are one of the conspicuous topographic features on volcanoes. The subsurface structure of the lava dome is important to discuss its formation mechanism. In the 1944 eruption of Volcano Usu, Hokkaido, a new lava dome was formed at its eastern foot. After the completion of the lava dome, various geophysical methods were applied to the dome to study its subsurface structure, but resulted in a rather ambiguous conclusion. Recently, from the results of the levelings, which were repeated during the eruption, "pseudo growth curves" of the lava dome were obtained. The curves suggest that the lava dome has a bulbous shape. In the present work, muon radiography, which previously proved effective in imaging the internal structure of Volcano Asama, has been applied to the Usu lava dome. The muon radiography measures the distribution of the "density length" of volcanic bodies when detectors are arranged properly. The result obtained is consistent with the model deduced from the pseudo growth curves. The measurement appears to afford useful method to clarify the subsurface structure of volcanoes and its temporal changes, and in its turn to discuss volcanic processes. This is a point of contact between high-energy physics and volcano physics.

  13. Genomic characterization of echovirus 6 causing aseptic meningitis in Hokkaido, Japan: a novel cluster in the nonstructural protein coding region of human enterovirus B.

    Science.gov (United States)

    Miyoshi, Masahiro; Komagome, Rika; Ishida, Setsuko; Nagano, Hideki; Takahashi, Kenichi; Okano, Motohiko

    2013-04-01

    We determined four complete nucleotide sequences of echovirus 6 (E6) isolated from an epidemic of aseptic meningitis (AM) in Hokkaido, Japan, in 2011. Phylogenetic analysis of the genes encoding viral capsid protein 1 revealed that the strains were closely related to E6 strains isolated in China in recent years, but they were distantly related to E6 strains isolated from patients with AM in Osaka Prefecture, Japan, in 2011. The genes encoding the viral protease and RNA-dependent RNA polymerase (3CD) were closely related to those of several non-E6 strains of the species Human enterovirus B isolated in China, South Korea, and Australia from 1999 to 2010, resulting in a novel cluster in the phylogenetic tree. These results suggest that the incidence of AM in Japan in 2011 was caused by at least two lineages of E6 strains, and a lineage of the 3CD gene was interspersed among different serotypic strains isolated in Western Pacific countries.

  14. Muon radiography and deformation analysis of the lava dome formed by the 1944 eruption of Usu, Hokkaido —Contact between high-energy physics and volcano physics—

    Science.gov (United States)

    TANAKA, Hiroyuki K. M.; YOKOYAMA, Izumi

    2008-01-01

    Lava domes are one of the conspicuous topographic features on volcanoes. The subsurface structure of the lava dome is important to discuss its formation mechanism. In the 1944 eruption of Volcano Usu, Hokkaido, a new lava dome was formed at its eastern foot. After the completion of the lava dome, various geophysical methods were applied to the dome to study its subsurface structure, but resulted in a rather ambiguous conclusion. Recently, from the results of the levelings, which were repeated during the eruption, “pseudo growth curves” of the lava dome were obtained. The curves suggest that the lava dome has a bulbous shape. In the present work, muon radiography, which previously proved effective in imaging the internal structure of Volcano Asama, has been applied to the Usu lava dome. The muon radiography measures the distribution of the “density length” of volcanic bodies when detectors are arranged properly. The result obtained is consistent with the model deduced from the pseudo growth curves. The measurement appears to afford useful method to clarify the subsurface structure of volcanoes and its temporal changes, and in its turn to discuss volcanic processes. This is a point of contact between high-energy physics and volcano physics. PMID:18941290

  15. Magnetotelluric investigation in and around southern part of Hidaka metamorphic belt in Hokkaido, Japan; Hidaka henseitai nanbuiki ni okeru MT kansoku

    Energy Technology Data Exchange (ETDEWEB)

    Sato, H.; Utsugi, M.; Hirano, K.; Doi, T.; Nishida, Y.; Arita, K. [Hokkaido University, Sapporo (Japan)

    1996-05-01

    An MT observation was conducted in the Hidaka district, Hokkaido, for the estimation of the 2D resistivity structure in the southern part of the metamorphic belt, when frequencies of the VLF, ELF, and ULF bands were used. An approximately 42km-long traverse line was set to cross the Hidaka metamorphic belt from east to west. As for the observation points, 48 VLF points, 16 ELF points, and 4 ULF points were provided. During the data processing, impedance tensor was calculated in the frequency domain for the determination of the apparent resistivity relative to frequency and the phase difference. As the result, it was found that there is a fairly large resistivity gap between observation spots MNS and KWR and that the boundary corresponds to the Hidaka metamorphic belt, that the metamorphic belt that is reflected as a conspicuous high-resistivity layer in the VLF-, ELF-MT slopes down toward the east and has a distribution as deep as 10km in the vicinity of observation point KWR, that this high-resistivity layer sandwiches a low-resistivity layer at a depth of 5-7km, and that on the east side of the metamorphic belt there is a medium-resistivity layer creeping under the belt from the east side toward the west side. 5 refs., 6 figs.

  16. The Status of Rotational Nonequilibrium in HF Chemical Lasers

    Science.gov (United States)

    1986-05-01

    later study from the same laboratory, Copeland et al. 5 3 used a NdYAG dye laser to pump HF into v = 2, j, and an HF pulsed laser to probe various P 2(J... Weston , Jr., J. Chem. Phys. 77, 4776 (1982). 51. J. J. Hinchen and R. H. Hobbs, Appl. Phys. 50, 628 (1979). 52. j. K. Lambert, G. M. Jursich, and F. F...Crim, Chem. Phys. Lett. 71, 258 (1980). 53. R. A. Copeland , D. J. Pearson, and F. F. Crim, Chem. Phys. Lett. 81, 541 (1981). 54. T. J. Foster and F. F

  17. New active load voltage clamp for HF-link converters

    Energy Technology Data Exchange (ETDEWEB)

    Ljusev, P.; Andersen, M.A.E.

    2005-07-01

    This paper proposes a new active clamp for HF-link converters, which features very high efficiency by returning the clamped energy back to the primary side through a small auxiliary converter. It also increases the reliability of HF-link converters by providing an alternative load current path during malfunctions of the secondary bidirectional bridge. The feasibility of the approach is shown on audio power amplifier prototype. New integrated magnetics design is presented that incorporates both the main power and auxiliary transformer on the same magnetic core. (au)

  18. HF-induced airglow at magnetic zenith: theoretical considerations

    Directory of Open Access Journals (Sweden)

    E. V. Mishin

    2005-01-01

    Full Text Available Observations of airglow at 630nm (red line and 557.7nm (green line during HF modification experiments at the High Frequency Active Auroral Research Program (HAARP heating facility are analyzed. We propose a theoretical framework for understanding the generation of Langmuir and ion acoustic waves during magnetic zenith injections. We show that observations of HF-induced airglow in an underdense ionosphere as well as a decrease in the height of the emitting volume are consistent with this scenario.

  19. HF-hash : Hash Functions Using Restricted HFE Challenge-1

    CERN Document Server

    Dey, Dhananjoy; Gupta, Indranath Sen

    2009-01-01

    Vulnerability of dedicated hash functions to various attacks has made the task of designing hash function much more challenging. This provides us a strong motivation to design a new cryptographic hash function viz. HF-hash. This is a hash function, whose compression function is designed by using first 32 polynomials of HFE Challenge-1 with 64 variables by forcing remaining 16 variables as zero. HF-hash gives 256 bits message digest and is as efficient as SHA-256. It is secure against the differential attack proposed by Chabaud and Joux as well as by Wang et. al. applied to SHA-0 and SHA-1.

  20. Hf--Co--B alloys as permanent magnet materials

    Energy Technology Data Exchange (ETDEWEB)

    McGuire, Michael Alan; Rios, Orlando; Ghimire, Nirmal Jeevi

    2017-01-24

    An alloy composition is composed essentially of Hf.sub.2-XZr.sub.XCo.sub.11B.sub.Y, wherein 0Hf.sub.2-XZr.sub.XCo.sub.11B.sub.Y, wherein 0.ltoreq.X<2 and 0

  1. First HF radar measurements of summer mesopause echoes at SURA

    Directory of Open Access Journals (Sweden)

    A. N. Karashtin

    Full Text Available HF sounding of the mesosphere was first carried out at SURA in summer 1994 at frequencies in the range 8–9 MHz using one of the sub-arrays of the SURA heating facility. The observations had a range resolution of 3 km. Almost all measurements indicated the presence of strong radar returns from altitudes between 83 and 90 km with features very similar to VHF measurements of mesopause summer echoes at mid-latitudes and polar mesopause summer echoes. In contrast to VHF observations, HF mesopause echoes are almost always present.

  2. New active load voltage clamp for HF-link converters

    DEFF Research Database (Denmark)

    Ljusev, Petar; Andersen, Michael Andreas E.

    2005-01-01

    This paper proposes a new active clamp for HF-link converters, which features very high efficiency by returning the clamped energy back to the primary side through a small auxiliary converter. It also increases the reliability of HF-link converters by providing an alternative load current path du...... during malfunctions of the secondary bidirectional bridge. The feasibility of the approach is shown on audio power amplifier prototype. New integrated magnetics design is presented that incorporates both the main power and auxiliary transformer on the same magnetic core....

  3. First HF radar measurements of summer mesopause echoes at SURA

    Science.gov (United States)

    Karashtin, A. N.; Shlyugaev, Y. V.; Abramov, V. I.; Belov, I. F.; Berezin, I. V.; Bychkov, V. V.; Eryshev, E. B.; Komrakov, G. P.

    1997-07-01

    HF sounding of the mesosphere was first carried out at SURA in summer 1994 at frequencies in the range 8-9 MHz using one of the sub-arrays of the SURA heating facility. The observations had a range resolution of 3 km. Almost all measurements indicated the presence of strong radar returns from altitudes between 83 and 90 km with features very similar to VHF measurements of mesopause summer echoes at mid-latitudes and polar mesopause summer echoes. In contrast to VHF observations, HF mesopause echoes are almost always present.

  4. European coordination for coastal HF radar data in EMODnet Physics

    Science.gov (United States)

    Mader, Julien; Novellino, Antonio; Gorringe, Patrick; Griffa, Annalisa; Schulz-Stellenfleth, Johannes; Montero, Pedro; Montovani, Carlo; Ayensa, Garbi; Vila, Begoña; Rubio, Anna; Sagarminaga, Yolanda

    2015-04-01

    Historically, joint effort has been put on observing open ocean, organizing, homogenizing, sharing and reinforcing the impact of the acquired information based on one technology: ARGO with profilers Argo floats, EuroSites, ESONET-NoE, FixO3 for deep water platforms, Ferrybox for stations in ships of opportunities, and GROOM for the more recent gliders. This kind of networking creates synergies and makes easier the implementation of this source of data in the European Data exchange services like EMODnet, ROOSs portals, or any applied services in the Blue economy. One main targeted improvement in the second phase of EMODnet projects is the assembling of data along coastline. In that sense, further coordination is recommended between platform operators around a specific technology in order to make easier the implementation of the data in the platforms (4th EuroGOOS DATAMEQ WG). HF radar is today recognized internationally as a cost-effective solution to provide high spatial and temporal resolution current maps (depending on the instrument operation frequency, covering from a few kilometres offshore up to 200 km) that are needed for many applications for issues related to ocean surface drift or sea state characterization. Significant heterogeneity still exists in Europe concerning technological configurations, data processing, quality standards and data availability. This makes more difficult the development of a significant network for achieving the needed accessibility to HF Radar data for a pan European use. EuroGOOS took the initiative to lead and coordinate activities within the various observation platforms by establishing a number of Ocean Observing Task Teams such as HF-Radars. The purpose is to coordinate and join the technological, scientific and operational HF radar communities at European level. The goal of the group is on the harmonization of systems requirements, systems design, data quality, improvement and proof of the readiness and standardization of

  5. HF radar transmissions that deviate from great-circle paths: new insight from e-POP RRI

    Science.gov (United States)

    Perry, G. W.; Miller, E. S.; James, H. G.; Howarth, A. D.; St-Maurice, J. P.; Yau, A. W.

    2016-12-01

    Significant deviations of SuperDARN radar transmissions from their expected great-circle paths have been detected at ionospheric altitudes using the Radio Receiver Instrument (RRI) on the Enhanced Polar Outflow Probe (e-POP). Experiments between SuperDARN Rankin Inlet and e-POP RRI were conducted at similar local times over consecutive days. Customized experiment modes which incorporated the agile frequency switching capabilities of each system were used. The RRI measurements show deviations of radar transmissions from their expected paths by as much as 2 or 3 SuperDARN beam widths, equivalent to 6° - 10° in bearing from Rankin Inlet. The deviations displayed a dependence on the radar carrier frequency and a day-to-day variability, suggesting that the deviations were transient in nature. We will discuss the deviations in the context of 3D ray trace modeling and measurements from the Resolute Bay Incoherent Scatter Radar - North (RISR-N). The latter provided diagnostic information of the ionosphere along the ray path between RRI and Rankin Inlet during the experiments.

  6. Evolution of E2 transition strength in deformed hafnium isotopes from new measurements on $^{172}$Hf, $^{174}$Hf, and $^{176}$Hf

    CERN Document Server

    Rudigier, M; Dannhoff, M; Gerst, R-B; Jolie, J; Saed-Samii, N; Stegemann, S; Régis, J-M; Robledo, L M; Rodríguez-Guzmán, R; Blazhev, A; Fransen, Ch; Warr, N; Zell, K O

    2015-01-01

    The available data for E2 transition strengths in the region between neutron-deficient Hf and Pt isotopes are far from complete. More and precise data are needed to enhance the picture of structure evolution in this region and to test state-of-the-art nuclear models. In a simple model, the maximum collectivity is expected at the middle of the major shell. However, for actual nuclei, this picture may no longer be the case, and one should use a more realistic nuclear-structure model. We address this point by studying the spectroscopy of Hf. We remeasure the 2^+_1 half-lives of 172,174,176Hf, for which there is some disagreement in the literature. The main goal is to measure, for the first time, the half-lives of higher-lying states of the rotational band. The new results are compared to a theoretical calculation for absolute transition strengths. The half-lives were measured using \\gamma-\\gamma and conversion-electron-\\gamma delayed coincidences with the fast timing method. For the determination of half-lives i...

  7. Comparative study of atomic-layer-deposited HfO2/Al2O3, Hf0.8Al0.2Ox and Hf0.5Al0.5Ox on N-GaAs

    Science.gov (United States)

    Yu, Xinjiang; Lv, Hongliang; Zhang, Yuming; Zhang, Yimen; Qin, Zaiyang

    2016-11-01

    Interfacial properties of n-GaAs metal-oxide-semiconductor (MOSCAPs) with the gate dielectrics of HfO2/Al2O3, Hf0.8Al0.2Ox and Hf0.5Al0.5Ox are investigated. The results reveal that Hf0.5Al0.5Ox has larger permittivity and lower interface trap density than that of HfO2/Al2O3. In order to explain the result from the physical perspective, the XPS tests of all three samples are performed. It is found that the main reason to form interface trap of three samples treated with 500 °C post-deposition annealing, is attributed to the interfacial component of Ga2O3 and The Hf0.5Al0.5Ox dielectric is beneficial to reducing the formation of Ga2O3.

  8. First 100 ms of HF modification at Tromso, Norway

    Science.gov (United States)

    Djuth, F. T.; Isham, B.; Rietveld, M. T.; Hagfors, T.; La Hoz, C.

    Experiments were performed with the high-power high-frequency HF facility at Troms o Norway to test theoretical predictions for the excitation of ion and Langmuir oscillations in the ionosphere The principal diagnostic of wave-plasma interactions was the VHF radar at the European Incoherent Scatter EISCAT facility High resolution radar techniques were used to monitor the temporal development of the ion and Langmuir oscillations HF pulses 100 ms in duration were periodically transmitted into a smooth background F region plasma Measurements of the radar backscatter spectra show that all key spectral features predicted by strong Langmuir turbulence SLT theory modified Zakharov model are simultaneously present in the plasma and that their evolution is in agreement with theoretical expectations However several new features have been observed that cannot be anticipated by current theory because of limitations in the electric field strength within the simulations The experimental results reinforce the notion that new theoretical developments are needed to accommodate the large HF electric fields produced at Troms o and HAARP Gakona Alaska and to treat the electron acceleration process in a self-consistent fashion The F region response to two HF effective radiated power levels sim 58 MW and sim 125 MW was investigated at Troms o These ERP values include absorptive losses resulting from the sunlit D region In general the results at 58 MW ERP and 125 MW ERP are consistent with many of the SLT

  9. The multilayer Fe/Hf studied with slow positron beam

    Science.gov (United States)

    Murashige, Y.; Tashiro, M.; Nakajyo, T.; Koizumi, T.; Kanazawa, I.; Komori, F.; Ito, Y.

    1997-04-01

    The positron annihilation parameter versus the incident positron energy is measured in the thin Fe films and the Fe/Hf bilayer on silica substrate, by means of the variable energetic slow-positron beam technique. We have analyzed the change in open-volume spaces and vacancy-type defects among the Fe microcrystals in these thin films with the deposition temperature.

  10. A CMOS OTA for HF filters with programmable transfer function

    NARCIS (Netherlands)

    van de Zwan, Eric J.; Klumperink, Eric A.M.; Seevinck, E.; Seevinck, Evert

    1991-01-01

    A CMOS operational transconductance amplifier (OTA) for programmable HF filters is presented. When used in an OTA-C integrator, the unity-gain frequency phase error remains less than 0.3° for frequencies up to more than one tenth of the OTA bandwidth. The OTA has built-in phase compensation, which

  11. Hf isotope evidence for a hidden mantle reservoir

    DEFF Research Database (Denmark)

    Bizzarro, Martin; Simonetti, A.; Stevenson, R.K.

    2002-01-01

    High-precision Hf isotopic analyses and U-Pb ages of carbonatites and kimberlites from Greenland and eastern North America, including Earth's oldest known carbonatite (3 Ga), indicate derivation from an enriched mantle source. This previously unidentified mantle reservoir-marked by an unradiogeni...

  12. Origin of excess 176Hf in meteorites

    DEFF Research Database (Denmark)

    Thrane, Kristine; Connelly, James; Bizzarro, Martin

    2010-01-01

    After considerable controversy regarding the (176)Lu decay constant (lambda(176)Lu), there is now widespread agreement that (1.867 +/- 0.008) x 10(-11) yr(-1) as confirmed by various terrestrial objects and a 4557 Myr meteorite is correct. This leaves the (176)Hf excesses that are correlated with...

  13. Self-diffusion of Er and Hf inpure and HfO/sub 2/-doped polycrystalline Er/sub 2/O/sub 3/. [Hf-175 and Er-169

    Energy Technology Data Exchange (ETDEWEB)

    Scheidecker, R.W.

    1979-01-01

    Using a tracer technique, self-diffusion of Er and Hf was measured over the approximate temperature interval of 1600 to 1970/sup 0/C in pure and HfO/sub 2/-doped polycryatalline Er/sub 2/O/sub 3/. Up to about 10 m/o HfO/sub 2/ dopant level, the Er self-diffusion coefficients followed a relationship based on cation vacancies. Above 10 m/o HfO/sub 2/, deviation from this relationship occurred, apparently due to clustering of cation vacancies and oxygen interstitials around the dopant hafnia ion. The activation energy for the self-diffusion of Er in pure Er/sub 2/O/sub 3/ was 82.2 Kcal/mole and increased with the HfO/sub 2/ dopant level present. Self-diffusion of Hf was measured in pure Er/sub 2/O/sub 3/ having two impurity levels, and a separation of the grain boundary. The volume diffusion of Hf showed both extrinsic and intrinsic behavior with the transition temperature increasing with the impurity level present in Er/sub 2/O/sub 3/. The activation energy for Hf volume diffusion in the intrinsic region was high, i.e. 235 -+ 9.5 Kcal/mole. The grain boundary diffusion was apparently extrinsic over the entire temperature interval Very low Hf self diffusion rates were found in both pure and HfO/sub 2/ doped Er/sub 2/O/sub 3/ compositions. Despite a clustering effect, the HfO/sub 2/ dopant increased the Hf volume diffusion coefficients.

  14. Helium implanted $\\rm\\underline{Al}$Hf as studied by 181Ta TDPAC

    Indian Academy of Sciences (India)

    R Govindaraj; K P Gopinathan; B Viswanathan

    2000-06-01

    Time differential perturbed angular correlation (TDPAC) measurement on $\\rm\\underline{Al}$Hf reference sample has shown that a fraction 0.88 of probe nuclei are defect free and are occupying the substitutional sites in fcc Al matrix, and the remaining are associated with Hf solute clusters. Measurements on helium implanted sample indicate the binding of helium associated defects by Hf solute clusters. Isochronal annealing measurements indicate the dissociation of the helium implantation induced defects from Hf solute clusters for annealing treatments beyond 650 K. On comparison of the present results with that reported in $\\rm\\underline{Cu}$Hf subjected to identical helium implantation, it is inferred that the Hf solute clusters in $\\rm\\underline{Al}$Hf bind less strongly the helium associated defects than in $\\rm\\underline{Cu}$Hf.

  15. Processing and crystallographic structure of non-equilibrium Si-doped HfO{sub 2}

    Energy Technology Data Exchange (ETDEWEB)

    Hou, Dong; Fancher, Chris M.; Esteves, Giovanni; Jones, Jacob L., E-mail: jacobjones@ncsu.edu [Department of Materials Science and Engineering, North Carolina State University, Raleigh, North Carolina 27695 (United States); Zhao, Lili [School of Information Science and Technology, Northwest University, Xi' an 710127 (China)

    2015-06-28

    Si-doped HfO{sub 2} was confirmed to exist as a non-equilibrium state. The crystallographic structures of Si-doped HfO{sub 2} were studied using high-resolution synchrotron X-ray diffraction and the Rietveld refinement method. Incorporation of Si into HfO{sub 2} and diffusion of Si out of (Hf,Si)O{sub 2} were determined as a function of calcination temperature. Higher thermal energy input at elevated calcination temperatures resulted in the formation of HfSiO{sub 4}, which is the expected major secondary phase in Si-doped HfO{sub 2}. The effect of SiO{sub 2} particle size (nano- and micron-sized) on the formation of Si-doped HfO{sub 2} was also determined. Nano-crystalline SiO{sub 2} was found to incorporate into HfO{sub 2} more readily.

  16. Data of evolutionary structure change: 1CLMA-2HF5A [Confc[Archive

    Lifescience Database Archive (English)

    Full Text Available 1CLMA-2HF5A 1CLM 2HF5 A A LTEEQIAEFKEAFALFDKDGDGTITTKELGTVMRSLGQN...PTEAELQDMINEVDADGNGTIDFPEFLSLMARKMKEQDSEEELIEAFKVFDRDGNGLISAAELRHVMTNLGEKL--TDDEVDEMIREADIDGDGHINYEEFVRMMVS-...ntryChain> 1CLM A 1CLMA LGEKL--TD...ne> 1CLM A 1CLMA

  17. Geographic variations in the PARADIGM-HF heart failure trial.

    Science.gov (United States)

    Kristensen, Søren Lund; Martinez, Felipe; Jhund, Pardeep S; Arango, Juan Luis; Bĕlohlávek, Jan; Boytsov, Sergey; Cabrera, Walter; Gomez, Efrain; Hagège, Albert A; Huang, Jun; Kiatchoosakun, Songsak; Kim, Kee-Sik; Mendoza, Iván; Senni, Michele; Squire, Iain B; Vinereanu, Dragos; Wong, Raymond Ching-Chiew; Gong, Jianjian; Lefkowitz, Martin P; Rizkala, Adel R; Rouleau, Jean L; Shi, Victor C; Solomon, Scott D; Swedberg, Karl; Zile, Michael R; Packer, Milton; McMurray, John J V

    2016-11-01

    The globalization of clinical trials has highlighted geographic variations in patient characteristics, event rates, and treatment effects. We investigated these further in PARADIGM-HF, the largest and most globally representative trial in heart failure (HF) to date. We looked at five regions: North America (NA) 602 (8%), Western Europe (WE) 1680 (20%), Central/Eastern Europe/Russia (CEER) 2762 (33%), Latin America (LA) 1433 (17%), and Asia-Pacific (AP) 1487 (18%). Notable differences included: WE patients (mean age 68 years) and NA (65 years) were older than AP (58 years) and LA (63 years) and had more coronary disease; NA and CEER patients had the worst signs, symptoms, and functional status. North American patients were the most likely to have a defibrillating-device (54 vs. 2% AP) and least likely prescribed a mineralocorticoid receptor antagonist (36 vs. 65% LA). Other evidence-based therapies were used most frequently in NA and WE. Rates of the primary composite outcome of cardiovascular (CV) death or HF hospitalization (per 100 patient-years) varied among regions: NA 13.6 (95% CI 11.7-15.7) WE 9.6 (8.6-10.6), CEER 12.3 (11.4-13.2), LA 11.2 (10.0-12.5), and AP 12.5 (11.3-13.8). After adjustment for prognostic variables, relative to NA, the risk of CV death was higher in LA and AP and the risk of HF hospitalization lower in WE. The benefit of sacubitril/valsartan was consistent across regions. There were many regional differences in PARADIGM-HF, including in age, symptoms, comorbidity, background therapy, and event-rates, although these did not modify the benefit of sacubitril/valsartan. CLINICAL TRIAL REGISTRATION URL: http://www.clinicaltrials.gov. Unique identifier: NCT01035255. © The Author 2016. Published by Oxford University Press on behalf of the European Society of Cardiology.

  18. Mid-Latitude Mobile Wideband HF- NVIS Channel Analysis: Part 1

    Science.gov (United States)

    2017-09-14

    communications (SATCOM) for beyond line-of- sight (LOS) links. However, standard HF systems operating over a 3-kHz bandwidth do not provide sufficient...wideband mid-latitude HF channel soundings and three-dimensional (3-D) ray-tracing simulations to develop a statistical model of a particular nearly...46 5 THE HF-NVIS CHANNEL SOUNDING SYSTEM ...................................................................... 47 5.1 TRANSMIT AND RECEIVE HF

  19. HF Radar observations of the Dardanelles outflow current in North Eastern Aegean using validated WERA HF radar data

    Directory of Open Access Journals (Sweden)

    Z. KOKKINI

    2015-01-01

    Full Text Available A two-site WERA HF radar station was installed in November 2009 at the eastern coast of Lemnos Island in North Aegean Sea, aiming to monitor the surface inflow of Black Sea waters exiting from the Dardanelles Strait, as well as to constitute a coastal management tool for incidents of oil-pollution or save-and-rescue operations. Strong interference by foreign transmissions is a source of noise deteriorating the quality of the backscattered signal, thus significantly reducing the HF radar’s effective data return rate. In order to ameliorate this problem, further quality-control and data gap interpolating procedures have been developed and applied, to be used in addition to the procedures incorporated and used by the manufacturer’s signal processing software. The second-level processing involves traditional despiking in the temporal domain, preceding Empirical Orthogonal Function analysis. The latter is used not only to filter high-frequency noise but also to fill data gaps in time and space. The data reconstruction procedure has been assessed via comparison of (a HF radial with CODE-type drifter radial velocities as well as (b HF-derived virtual drifter tracks with actual drifter tracks. The main circulation features and their variability, as revealed by the reconstructed fields, are presented.

  20. HF Radar observations of the Dardanelles outflow current in North Eastern Aegean using validated WERA HF radar data

    Directory of Open Access Journals (Sweden)

    Z. KOKKINI

    2014-12-01

    Full Text Available A two-site WERA HF radar station was installed in November 2009 at the eastern coast of Lemnos Island in North Aegean Sea, aiming to monitor the surface inflow of Black Sea waters exiting from the Dardanelles Strait, as well as to constitute a coastal management tool for incidents of oil-pollution or save-and-rescue operations. Strong interference by foreign transmissions is a source of noise deteriorating the quality of the backscattered signal, thus significantly reducing the HF radar’s effective data return rate. In order to ameliorate this problem, further quality-control and data gap interpolating procedures have been developed and applied, to be used in addition to the procedures incorporated and used by the manufacturer’s signal processing software. The second-level processing involves traditional despiking in the temporal domain, preceding Empirical Orthogonal Function analysis. The latter is used not only to filter high-frequency noise but also to fill data gaps in time and space. The data reconstruction procedure has been assessed via comparison of (a HF radial with CODE-type drifter radial velocities as well as (b HF-derived virtual drifter tracks with actual drifter tracks. The main circulation features and their variability, as revealed by the reconstructed fields, are presented.

  1. The stability of the bifluoride ion (HF - 2) in the gas phase

    Science.gov (United States)

    Heni, Martin; Illenberger, Eugen

    1985-12-01

    The bifluoride ion (HF-2) has been generated by dissociative electron attachment to trans-1,2-difluorethylene and cis-1,2-difluoroethylene. Evaluation of the energetics for these reactions leads to ΔH0f (HF-2) ≤-6.9 eV and E. A. (HF2)≥4.8 eV.

  2. Photon strength function in the Hf-181 nucleus by method of two-step cascade

    CERN Document Server

    Le Hong Khiem

    2003-01-01

    The applicability of sum-coincidence measurements of two-step cascade gamma ray spectra determining Photon Strength Function (PSF) of Hf-181 induced from Hf-180 (n,2 gamma) Hf-181 reaction is presented. Up to 80% intensity of the primary gamma ray transitions in a wide energy range have been deduced and compared to model calculation.

  3. Suppression Factor of ~(182)W for ~(182)Hf AMS at CIAE

    Institute of Scientific and Technical Information of China (English)

    2011-01-01

    Suppression factor of 182W is an important index in the measurement of 182Hf with AMS method. This factor is defined as the value of 182W/180Hf in blank samples divised by the measured value of 182 W/180Hf with AMS method. In order to satisfy a

  4. 40 CFR 180.1273 - Beauveria bassiana HF23; exemption from the requirement of a tolerance.

    Science.gov (United States)

    2010-07-01

    ... 40 Protection of Environment 23 2010-07-01 2010-07-01 false Beauveria bassiana HF23; exemption... FOOD Exemptions From Tolerances § 180.1273 Beauveria bassiana HF23; exemption from the requirement of a tolerance. Residues of Beauveria bassiana HF23 are exempt from the requirement of a tolerance on all...

  5. Long-term mean and seasonal variation of altimetry-derived Oyashio transport across the A-line off the southeastern coast of Hokkaido, Japan

    Science.gov (United States)

    Kuroda, Hiroshi; Wagawa, Taku; Kakehi, Shigeho; Shimizu, Yugo; Kusaka, Akira; Okunishi, Takeshi; Hasegawa, Daisuke; Ito, Shin-ichi

    2017-03-01

    To understand long-term mean and seasonal variations of the Oyashio transport off the southeastern coast of Hokkaido, time series of estimated transports were generated by combining satellite altimetry and CTD data from the period 1993-2014 along a monitoring transect referred to as the ;A-line;. Linear regressions between CTD-derived geostrophic transport and altimetry-derived sea level anomaly differences were calculated by minimizing a cost function newly proposed in this study. The horizontal structure of 21-year mean transport was characterized by a southwestward flow on the continental slope (SW-1) associated with the First Oyashio Intrusion, a northeastward flow (NE-2) likely trapped against the Kuril-Kamchatka trench, a southwestward flow (SW-3) related to the Second Oyashio Intrusion, and a very stable northeastward flow (NE-4) corresponding to a combination of the Oyashio Return Flow and quasi-stationary Jet. Analysis of long-term mean monthly transports revealed four alternating flows that were present throughout all seasons of the year. The boundaries between adjacent pairs of the four flows on the A-line did not change on a seasonal timescale as much as the southernmost latitude of the First Oyashio Intrusion. At a 0-month (1-month) time lag, the sum of the SW-1, NE-2, and SW-3 (SW-1 and NE-2) transports, which corresponds to net Oyashio transport (partial net Oyashio transport related to the southernmost latitude of the First Oyashio Intrusion), was correlated with Sverdrup transport more robustly than was each of the four alternating flows. This result suggests that as the Oyashio crossed the A-line, it responded barotropically to basin-scale wind stress by adjusting transports composed of both southwestward and northeastward flows.

  6. Analysis of HLA genes and haplotypes in Ainu (from Hokkaido, northern Japan) supports the premise that they descent from Upper Paleolithic populations of East Asia.

    Science.gov (United States)

    Bannai, M; Ohashi, J; Harihara, S; Takahashi, Y; Juji, T; Omoto, K; Tokunaga, K

    2000-02-01

    The Ainu people are assumed to be the descendants of pre-agricultural native populations of northern Japan, while the majority of population of present-day Japan (Hondo-Japanese) is considered to have descended mainly from post-neolithic migrants. Sequence-level polymorphisms of the HLA-class I (HLA-A and HLA-B) genes were investigated in DNA samples of 50 Ainu living in Hidaka district, Hokkaido. HLA-A*2402, A*0201, A*0206, A*2601, A*3101, B*1501, B*5101, B*3901, and B*3501 were observed at frequencies of more than 10% and most of these have previously been found in populations of not only Asians but also North and South American Indians. A*68012, which has not so far been detected in Hondo-Japanese, was found in the Ainu (3%). On the other hand, several alleles common in Hondo-Japanese, including HLA-A*3303, A*1101, B*4403, B*5201, B*5401, B*4601, and B*0702 were infrequent in Ainu (0-1%). Correspondence and neighbor-joining analyses of various populations based on HLA-A, -B and -DRB1 gene frequencies enabled distinction between Asian, Native South American, European, and African populations. The Ainu, as well as Tlingit (Na-Dene), were placed midway between other East Asians, including Hondo Japanese, and Native South Americans (Amerindians) in the correspondence analysis. Furthermore, several HLA-A-B and HLA-B-DR-DQ haplotypes common in the Ainu, are shared with some Native American populations. These observations strongly suggest a unique place for the Ainu as descendants of some Upper Paleolithic populations of East Asia, from whom some Native Americans may have descended.

  7. Stress drops for intermediate-depth intraslab earthquakes beneath Hokkaido, northern Japan: Differences between the subducting oceanic crust and mantle events

    Science.gov (United States)

    Kita, Saeko; Katsumata, Kei

    2015-02-01

    Spatial variations in the stress drop for 1726 intermediate-depth intraslab earthquakes were examined in the subducting Pacific plate beneath Hokkaido, using precisely relocated hypocenters, the corner frequencies of events, and detailed determined geometry of the upper interface of the Pacific plate. The results show that median stress drop for intraslab earthquakes generally increases with an increase in depth from ˜10 to 157 Mpa at depths of 70-300 km. More specifically, median stress drops for events in the oceanic crust decrease (9.9-6.8 MPa) at depths of 70-120 km and increase (6.8-17 MPa) at depths of 120-170 km, whereas median stress drop for events in the oceanic mantle decrease (21.6-14.0 MPa) at depths of 70-170 km, where the geometry of the Pacific plate is well determined. The increase in stress drop with depth in the oceanic crust at depths of 120-170 km, for which several studies have shown an increase in velocity, can be explained by an increase in the velocity and a decrease in the water content due to the phase boundary with dehydration in the oceanic crust. Stress drops for events in the oceanic mantle were larger than those for events in the oceanic crust at depths of 70-120 km. Differences in both the rigidity of the rock types and in the rupture mechanisms for events between the oceanic crust and mantle could be causes for the stress drop differences within a slab.

  8. THE USE OF REMOTE SENSING, REGRESSION QUANTILES, AND GIS APPROACHES FOR MODELING OF SCALLOP LARVAE: A Case Study in Funka Bay, Hokkaido, Japan

    Directory of Open Access Journals (Sweden)

    I Nyoman Radiarta

    2011-12-01

    Full Text Available In the development of scallop cultivation in Japan, larvae collection and propagation become an important factor. Although the monitoring program has been conducted, modeling of species distribution is becoming an important tool for understanding the effects of environmental changes and resources management. This study was conducted to construct a model for providing estimation of the scallop larvae distribution in Funka Bay, Hokkaido, Japan using the integration of remote sensing, Regression Quantile (RQ and Geographic Information System (GIS-based model. Data on scallop larvae were collected during one year spawning season from April to July 2003. Environmental parameters were extracted from multi sensor remotely sensed data (chlorophyll-a and sea surface temperature and a hydrographic chart (water depth. These parameters together with larvae data were then analyzed using RQ. Finally, spatial models were constructed within a GIS by combining the RQ models with digital map of environmental parameters. The results show that the model was best explained by using only sea surface temperature. The highest larvae densities were predicted in a relatively broad distribution along with the shallow water regions (Toyoura and Sawara to Yakumo and the deeper water areas (center of the bay. The spatial model built from the RQ provided robust estimation of the scallop larvae distributions in the study area, as confirmed by model validation using independent data. These findings could contribute on the monitoring program in this region in order to distinguish the potential areas for an effective spat collection.

  9. Rates of water exsolution and magma ascent inferred from microstructures and chemical analyses of the Tokachi-Ishizawa obsidian lava, Shirataki, northern Hokkaido, Japan

    Science.gov (United States)

    Sano, Kyohei; Wada, Keiji; Sato, Eiichi

    2015-02-01

    Very few quantitative textural data exist for viscous obsidian lava eruptions, and it is still unclear from the mechanical behavior of ascending magmas if outgassing is controlled dominantly by brittle or ductile deformation. In order to obtain insights into how degassing and ascent proceed in such highly viscous magmas, we conducted textural and chemical analyses of the Tokachi-Ishizawa (TI) obsidian lava, in the Shirataki rhyolite volcanic area, northern Hokkaido, Japan, and estimated the water exsolution rate and ascent rate. The storage conditions of the TI lava are estimated from the Rhyolite-MELTS program as T = 840-860 °C and P = 50 MPa using the mineral assemblages and the chemical compositions of plagioclase phenocrysts and glass. To estimate the magma ascent rate, we measured the length, width, and number of oxide microlites using three-dimensional techniques. Textural analysis indicates that the microlite number densities (Nv [number/m3]) of oxide microlites in TI lava samples are 2.1 × 1013 to 1.4 × 1014, which correspond to water exsolution rates of 3.5 × 10- 9 to 1.7 × 10- 8 wt.%/s and ascent rates of 1.7 × 10- 6 to 1.1 × 10- 5 m/s. Together with an estimate of viscosity, the inferred ascent velocities allow us to examine the mechanical behavior of the magma in the conduit. We conclude that the development of permeability leading to outgassing is controlled by ductile deformation rather than brittle fracturing.

  10. Borrelia miyamotoi infections among wild rodents show age and month independence and correlation with Ixodes persulcatus larval attachment in Hokkaido, Japan.

    Science.gov (United States)

    Taylor, Kyle R; Takano, Ai; Konnai, Satoru; Shimozuru, Michito; Kawabata, Hiroki; Tsubota, Toshio

    2013-02-01

    To clarify how Borrelia miyamotoi is maintained in the environment in Hokkaido, we examined Ixodes persulcatus for its prevalence among wild rodents and its tick vector by detecting a portion of the borrelial flaB gene in rodent urinary bladder and blood samples, and from whole ticks. We compared B. miyamotoi infection rates to Borrelia garinii and Borrelia afzelii, which are human Lyme disease pathogens also carried by wild rodents, and which are transmitted by the same vector tick. Whereas B. garinii and B. afzelii showed age dependence of infection rates among wild rodents (18.4% and 9.9% among adults and 6.0% and 3.4% among sub-adults, respectively) when looking at urinary bladder samples, B. miyamotoi infection rates were not age dependent for either blood (4.2% among adults, and 7.9% among sub-adults) or urinary bladder samples (1.0% among adults, and 1.7% among sub-adults). Moreover, while B. garinii and B. afzelii infection rates showed increases across months (June, July [prodents with B. garinii, and July and August had higher rates than in May [prodents with B. afzelii), B. miyamotoi infection rates did not show significant month dependence. These differences in month and age dependence led us to suspect that B. miyamotoi may not develop persistent infections in wild rodents, as B. garinii and B. afzelii are thought to. Furthermore, we examined the extent of rodent exposure to I. persulcatus nymphs and larvae throughout most of the tick's active season (May through September), and determined that B. miyamotoi infection rates in sub-adult rodents were correlated with larval burden (prodents.

  11. Two-dimensional semiconductor HfSe{sub 2} and MoSe{sub 2}/HfSe{sub 2} van der Waals heterostructures by molecular beam epitaxy

    Energy Technology Data Exchange (ETDEWEB)

    Aretouli, K. E.; Tsipas, P.; Tsoutsou, D.; Marquez-Velasco, J.; Xenogiannopoulou, E.; Giamini, S. A.; Vassalou, E.; Kelaidis, N.; Dimoulas, A., E-mail: a.dimoulas@inn.demokritos.gr [Institute of Nanoscience and Nanotechnology, National Center for Scientific Research “Demokritos,” 15310, Aghia Paraskevi, Athens (Greece)

    2015-04-06

    Using molecular beam epitaxy, atomically thin 2D semiconductor HfSe{sub 2} and MoSe{sub 2}/HfSe{sub 2} van der Waals heterostructures are grown on AlN(0001)/Si(111) substrates. Details of the electronic band structure of HfSe{sub 2} are imaged by in-situ angle resolved photoelectron spectroscopy indicating a high quality epitaxial layer. High-resolution surface tunneling microscopy supported by first principles calculations provides evidence of an ordered Se adlayer, which may be responsible for a reduction of the measured workfunction of HfSe{sub 2} compared to theoretical predictions. The latter reduction minimizes the workfunction difference between the HfSe{sub 2} and MoSe{sub 2} layers resulting in a small valence band offset of only 0.13 eV at the MoSe{sub 2}/HfSe{sub 2} heterointerface and a weak type II band alignment.

  12. Charge storage characteristics and tunneling mechanism of amorphous Ge-doped HfOx films

    Science.gov (United States)

    Qiu, X. Y.; Zhang, S. Y.; Zhang, T.; Wang, R. X.; Li, L. T.; Zhang, Y.; Dai, J. Y.

    2016-09-01

    Amorphous Ge-doped HfOx films have been deposited on p-Si(100) substrates by means of RF magnetron sputtering. Microstructural investigations reveal the partial oxidation of doped Ge atoms in the amorphous HfOx matrix and the existence of HfSiOx interfacial layer. Capacitance-voltage hysteresis of the Ag-/Ge-doped HfOx/Si/Ag memory capacitor exhibits a memory window of 3.15 V which can maintain for >5 × 104 cycles. Current-voltage characteristics reveal that Poole-Frenkel tunneling is responsible for electron transport in the Ge-doped HfOx film.

  13. Clinical trials update from the Heart Failure Society of America Meeting 2009: FAST, IMPROVE-HF, COACH galectin-3 substudy, HF-ACTION nuclear substudy, DAD-HF, and MARVEL-1.

    Science.gov (United States)

    Lainscak, Mitja; Coletta, Alison P; Sherwi, Nasser; Cleland, John G F

    2010-02-01

    This article presents findings and a commentary on late-breaking trials presented during the meeting of the Heart Failure Society of America in September 2009. Unpublished reports should be considered as preliminary, since analyses may change in the final publication. The FAST trial showed somewhat better performance of intrathoracic impedance for prediction of deterioration in patients with heart failure (HF) when compared with daily weighing. The IMPROVE-HF study reported the benefits of education on the management of patients with systolic HF. Galectin-3 appeared a useful method for improving risk stratification of patients with chronic HF in a substudy of the COACH trial. A nuclear substudy of the HF-ACTION trial failed to demonstrate that resting myocardial perfusion imaging, a measure of myocardial scar and viability, was clinically useful. A small randomized controlled trial (DAD-HF) suggested that the use of low-dose dopamine in patients with acutely decompensated HF was associated with less deterioration in renal function and less hypokalaemia. The MARVEL-1 trial raises further concerns about the safety of myoblast transplantation in ischaemic HF.

  14. The anisotropy of Hf diffusion in {alpha}-Zr

    Energy Technology Data Exchange (ETDEWEB)

    Hood, G.M. [Atomic Energy of Canada Ltd., Chalk River, ON (Canada). Chalk River Nuclear Labs.]|[Metals Technology Laboratory, CANMET, Ottawa, Ontario (Canada); Zou, H. [Atomic Energy of Canada Ltd., Chalk River, ON (Canada). Chalk River Nuclear Labs.]|[Metals Technology Laboratory, CANMET, Ottawa, Ontario (Canada); Roy, J.A. [Atomic Energy of Canada Ltd., Chalk River, ON (Canada). Chalk River Nuclear Labs.]|[Metals Technology Laboratory, CANMET, Ottawa, Ontario (Canada); Schultz, R.J. [Atomic Energy of Canada Ltd., Chalk River, ON (Canada). Chalk River Nuclear Labs.]|[Metals Technology Laboratory, CANMET, Ottawa, Ontario (Canada); Matsuura, N. [Atomic Energy of Canada Ltd., Chalk River, ON (Canada). Chalk River Nuclear Labs.]|[Metals Technology Laboratory, CANMET, Ottawa, Ontario (Canada); Jackman, J.A. [Atomic Energy of Canada Ltd., Chalk River, ON (Canada). Chalk River Nuclear Labs.]|[Metals Technology Laboratory, CANMET, Ottawa, Ontario (Canada)

    1996-02-01

    Hf diffusion coefficients (D) have been measured ({proportional_to}870-1100 K) in directions parallel (D{sub pa}) and perpendicular (D{sub pe}) to the c-axis of double-faced, single-crystal specimens of both high purity (HP) and nominally pure (NP) {alpha}-Zr. The diffusion profiles were measured by secondary ion mass spectrometry. Hf diffusion in HP {alpha}-Zr is characterised by an activation energy of about 3.0 eV and a pre-exponential factor of about 10{sup -5} m{sup 2}/s. The anisotropy ratio, D{sub pa}/D{sub pe}, is {proportional_to}<1.0 for the HP specimens and mostly >1.0 for the NP specimens. A dependence of D on diffusion time/depth is indicated for some experiments on NP Zr. (orig.).

  15. Photodetachment of HF-in an Electric Field

    Institute of Scientific and Technical Information of China (English)

    WANG De-Hua

    2008-01-01

    @@ Photdetachment of a negative HF-ion in an electric field is studied by using the two-centre model and the closed orbit theory.An analytic formula is presented for the electron flux of HF- in the presence of an electric field.The results show that the oscillation in the electron flux distribution is caused by the rescattering effect of the molecular ion core and the interference betweed the two nuclei.In addition,the interference between the orbits passing through the given spatial point also plays an important role in the electron flux distribution.This study provides a new understanding of the photodetachment of polar molecules in the presence of external field.

  16. Generation of ionospheric ducts by the HAARP HF heater

    Energy Technology Data Exchange (ETDEWEB)

    Cohen, J A; Pradipta, R; Burton, L M; Labno, A; Lee, M C [Massachusetts Institute of Technology, Cambridge, MA 02139 (United States); Watkins, B J; Fallen, C [University of Alaska Fairbanks, Fairbanks, AK 99775 (United States); Kuo, S P [New York University, Brooklyn, NY 11201 (United States); Burke, W J [Air Force Research Laboratory, Hanscom AFB, MA 01731 (United States); Mabius, D; See, B Z, E-mail: mclee@mit.edu [Boston University, Boston, MA 02215 (United States)

    2010-12-15

    We report an investigation of ionospheric ducts having the shape of large plasma sheets, generated by vertically transmitted HAARP HF heater waves in several experiments conducted in Gakona, Alaska. Theory predicts that O-mode heater wave-created ionospheric ducts form parallel-plate waveguides within the meridional plane, and those generated by the X-mode heater waves are orthogonal to the meridional plane. Our theoretical prediction is supported by measurements of ionosonde data (namely ionograms), range-time-intensity (RTI) plots of UHF and HF backscatter radars, as well as magnetometer data analyses. When these plasma sheets experienced ExB drifts, they were intercepted by the HAARP UHF radar and seen as slanted stripes in the RTI plots. This striking feature was also observed in our earlier experiments using the Arecibo UHF radar.

  17. Use of GPS network data for HF Doppler measurements interpretation

    CERN Document Server

    Petrova, Inna R; Latypov, Ruslan R

    2014-01-01

    The method of measurement of Doppler frequency shift of ionospheric signal - HF Doppler technique - is one of well-known and widely used methods of ionosphere research. It allows to research various disturbances in the ionosphere. There are some sources of disturbances in the ionosphere. These are geomagnetic storms, solar flashes, metrological effects, atmospheric waves. This method allows to find out the influence of earthquakes, explosions and other processes on the ionosphere, which occur near to the Earth. HF Doppler technique has the high sensitivity to small frequency variations and the high time resolution, but interpretation of results is difficult. In this work we make an attempt to use GPS data for Doppler measurements interpretation. Modeling of Doppler frequency shift variations with use of TEC allows to separate ionosphere disturbances of medium scale.

  18. Imaging HF-induced large-scale irregularities above HAARP

    Science.gov (United States)

    Djuth, Frank T.; Reinisch, Bodo W.; Kitrosser, David F.; Elder, John H.; Snyder, A. Lee; Sales, Gary S.

    2006-02-01

    The University of Massachusetts-Lowell digisonde is used with the HAARP high-frequency (HF), ionospheric modification facility to obtain radio images of artificially-produced, large-scale, geomagnetic field-aligned irregularities. F region irregularities generated with the HAARP beam pointed in the vertical and geomagnetic field-aligned directions are examined in a smooth background plasma. It is found that limited large-scale irregularity production takes place with vertical transmissions, whereas there is a dramatic increase in the number of source irregularities with the beam pointed parallel to the geomagnetic field. Strong irregularity production appears to be confined to within ~5° of the geomagnetic zenith and does not fill the volume occupied by the HF beam. A similar effect is observed in optical images of artificial airglow.

  19. Performance Analysis of HF Band FB-MC-SS

    Energy Technology Data Exchange (ETDEWEB)

    Hussein Moradi; Stephen Andrew Laraway; Behrouz Farhang-Boroujeny

    2016-01-01

    Abstract—In a recent paper [1] the filter bank multicarrier spread spectrum (FB-MC-SS) waveform was proposed for wideband spread spectrum HF communications. A significant benefit of this waveform is robustness against narrow and partial band interference. Simulation results in [1] demonstrated good performance in a wideband HF channel over a wide range of conditions. In this paper we present a theoretical analysis of the bit error probably for this system. Our analysis tailors the results from [2] where BER performance was analyzed for maximum ration combining systems that accounted for correlation between subcarriers and channel estimation error. Equations are give for BER that closely match the simulated performance in most situations.

  20. Investigation of new type Cu-Hf-Al bulk glassy alloys

    Science.gov (United States)

    Nagy, E.; Rontó, V.; Sólyom, J.; Roósz, A.

    2009-01-01

    In the last years new type Cu-Hf-Al ternary alloys were developed with high glass forming ability and ductility. The addition of Al to Cu-Hf alloys results in improvements in glass formation, thermal stability and mechanical properties of these alloys. We have investigated new Cu-based bulk amorphous alloys in Cu-Hf-Al ternary system. The alloys with Cu49Hf42Al9, Cu46Hf45Al9, Cu50Hf42.5Al7.5 and Cu50Hf45Al5 compositions were prepared by arc melting. The samples were made by centrifugal casting and were investigated by X-ray diffraction method. Thermodynamic properties were examined by differential scanning calorimetry and the structure of the crystallising phases by scanning electron microscopy. The determination of liquidus temperatures of alloys were measured by differential thermal analysis.

  1. First-principles studies of HF molecule adsorption on intrinsic graphene and Al-doped graphene

    Science.gov (United States)

    Sun, Yuanyuan; Chen, Li; Zhang, Feiwu; Li, Daoyong; Pan, Hongzhe; Ye, Jun

    2010-10-01

    In the search for a high-sensitivity sensor for HF gas, the adsorption of HF molecules on both intrinsic and Al-doped graphene sheets is studied by first-principles calculations. We find that the adsorption mechanisms of HF molecules are different for intrinsic graphene and Al-doped graphene. Al-doped graphene has higher adsorption energy and shorter connecting distance to the HF molecule than intrinsic graphene. The calculated net electron transfers, electronic density difference images and densities of states give evidence that the adsorption of HF molecules on Al-doped graphene is by chemisorption, while there is weak physisorption on intrinsic graphene. Therefore, Al-doped graphene can be expected to have applications as a novel sensor for the detection of HF gas. The HF molecules adsorbed on Al-doped graphene material can be reactivated by applying an external electric field of 0.013 a.u.

  2. Ferroelectric HfO2 for Emerging Ferroelectric Semiconductor Devices

    Science.gov (United States)

    Florent, Karine

    The spontaneous polarization in ferroelectrics (FE) makes them particularly attractive for non-volatile memory and logic applications. Non-volatile FRAM memories using perovskite structure materials, such as Lead Zirconate Titanate (PZT) and Strontium Bismuth Tantalate (SBT) have been studied for many years. However, because of their scaling limit and incompatibility with CMOS beyond 130 nm node, floating gate Flash memory technology has been preferred for manufacturing. The recent discovery of ferroelectricity in doped HfO2 in 2011 has opened the door for new ferroelectric based devices compatible with CMOS technology, such as Ferroelectric Field Effect Transistor (FeFET) and Ferroelectric Tunnel Junctions (FTJ). This work began with developing ferroelectric hysteresis characterization capabilities at RIT. Initially reactively sputtered aluminum doped HfO 2 films were investigated. It was observed that the composition control using co-sputtering was not achievable within the existing capabilities. During the course of this study, collaboration was established with the NaMLab group in Germany to investigate Si doped HfO2 deposited by Atomic Layer Deposition (ALD). Metal Ferroelectric Metal (MFM) devices were fabricated using TiN as the top and bottom electrode with Si:HfO2 thickness ranging from 6.4 nm to 22.9 nm. The devices were electrically tested for P-E, C-V and I-V characteristics. Structural characterizations included TEM, EELS, XRR, XRD and XPS/Auger spectroscopy. Higher remanant polarization (Pr) was observed for films of 9.3 nm and 13.1 nm thickness. Thicker film (22.9 nm) showed smaller Pr. Devices with 6.4 nm thick films exhibit tunneling behavior showing a memristor like I-V characteristics. The tunnel current and ferroelectricity showed decrease with cycling indicating a possible change in either the structure or the domain configurations. Theoretical simulations using the improved FE model were carried out to model the ferroelectric behavior of

  3. Centrifugal stretching of 170Hf in the interacting boson model

    Directory of Open Access Journals (Sweden)

    Werner V.

    2014-03-01

    Full Text Available We present the results of a recent experiment to deduce lifetimes of members of the ground state rotational band of 170Hf, which show the effect of centrifugal stretching in this deformed isotope. Results are compared to the geometrical confined beta-soft(CBS rotor model, as well as to the interacting boson model (IBM. Two methods to correct for effects due to the finite valence space within the IBM are proposed.

  4. Electrochemical characterization of cast Ti-Hf binary alloys.

    Science.gov (United States)

    Cai, Z; Koike, M; Sato, H; Brezner, M; Guo, Q; Komatsu, M; Okuno, O; Okabe, T

    2005-05-01

    This study characterized the electrochemical behavior of Ti-Hf binary alloys in a simulated oral environment. Ti-Hf alloys (10, 20, 25, 30, 35 and 40 mass% Hf) were prepared by arc-melting titanium sponge and hafnium sponge. Specimens of each alloy (n = 4) were prepared using a dental titanium casting system with a MgO-based investment. Specimens were inspected with X-ray radiography to ensure minimal internal porosity. Castings (n = 4) made from pure titanium and commercially pure titanium were used as controls. The ground flat surface (10 mm x 10 mm) on each specimen where approximately 30 microm was removed was used for the characterization. Sixteen-hour open-circuit potential (OCP) measurement, linear polarization and potentiodynamic cathodic polarization were performed sequentially in aerated (air + 10% CO2) MTZ synthetic saliva at 37 degrees C. Potentiodynamic anodic polarization was conducted in the same medium but deaerated (N2 + 10% CO2) 2 h before and during testing. Polarization resistance (R(P)) and Tafel slopes were determined, as were corrosion current density (I(CORR)) and passive current density (I(PASS)). Results were subjected to nonparametric statistical analysis (alpha = 0.05). The OCP stabilized (mean values -229 mV to -470 mV vs. SCE) for all specimens after the 16-h immersion. Similar passivation was observed for all the metals on their anodic polarization diagrams. The Kruskal-Wallis test showed significant differences in OCP among the test groups (p = 0.006). No significant differences were found in R(P), I(CORR) or I(PASS) among all the metals (p>0.3). Results indicate that the electrochemical behavior of the Ti-Hf alloys examined resembles that of pure titanium.

  5. Self-healing structural properties of thermoplastics in HF field

    Directory of Open Access Journals (Sweden)

    N. G. Filippenko

    2014-01-01

    Full Text Available The article concerns one of the possible ways for safe operation of polymer products with initiating a process of their self-healing. This is especially true for products from polymer materials, used in hard-to-reach areas and units of machines and mechanisms. In this regard, the aim of this study was to develop techniques for a self-healing process of the mechanical properties of products from polymer materials.To achieve this goal, the author has solved problems to define a complex method of HF self-healing of polymer material: damage detection in products from polymer materials, determination of signal initiating the recovery process, determining the efficiency of material regeneration. The present study uses proposed and developed by the author methods for the determination of necessary and sufficient indicators of the strength characteristics of products under realmeteorological and climatic conditions of their operation.To determine the practical results of the developed algorithm for self-healing the polymer products in the HF field, a series of experimental studies has been conducted to regenerate the polyamide cage fatigue destruction of the rolling stock axle equipment of Russian Railways JSC.The obtained results of the strength characteristics of the material under investigation prove the self-healing process of polymer materials in HF field.According to research results, the conclusion is drawn that it is required to provide a technological HF self-healing process of products from polymer materials. The created algorithm of regeneration enables a new approach to study the effects of electromagnetic fields on polymer and polymer-based composite materials when solving the practical tasks to improve the quality of repairing parts from thermoplastics.

  6. Hf--Co--B alloys as permanent magnet materials

    Science.gov (United States)

    McGuire, Michael Alan; Rios, Orlando; Ghimire, Nirmal Jeevi

    2017-01-24

    An alloy composition is composed essentially of Hf.sub.2-XZr.sub.XCo.sub.11B.sub.Y, wherein 0B.sub.Y, wherein 0.ltoreq.X<2 and 0

  7. Ionizing wave via high-power HF acceleration

    CERN Document Server

    Mishin, Evgeny

    2010-01-01

    Recent ionospheric modification experiments with the 3.6 MW transmitter at the High Frequency Active Auroral Research Program (HAARP) facility in Alaska led to discovery of artificial ionization descending from the nominal interaction altitude in the background F-region ionosphere by ~60 km. This paper presents a physical model of an ionizing wavefront created by suprathermal electrons accelerated by the HF-excited plasma turbulence.

  8. Study on Preparation of 182Hf AMS Standards

    Institute of Scientific and Technical Information of China (English)

    YINXin-yi; JIANGShan; HEMing; ZHANGChun-hua; ZHANGSheng-dong

    2003-01-01

    The neutron-rich isotope 182Hf with its half-life of (9±2)×106 a produced by neutron activation can be used to determine the neutron flux of some places, in order to study the transport of radioactive nuclides and the safe disposal of nuclear waste. AMS is a kind of relative measurement method with high sensitivity (10-15), it requires corresponding standard samples.

  9. Ionizing wave via high-power HF acceleration

    OpenAIRE

    Mishin, Evgeny; Pedersen, Todd

    2010-01-01

    Recent ionospheric modification experiments with the 3.6 MW transmitter at the High Frequency Active Auroral Research Program (HAARP) facility in Alaska led to discovery of artificial ionization descending from the nominal interaction altitude in the background F-region ionosphere by ~60 km. This paper presents a physical model of an ionizing wavefront created by suprathermal electrons accelerated by the HF-excited plasma turbulence.

  10. On the Onset of HF-Induced Airglow at HAARP

    Science.gov (United States)

    2007-11-02

    AFRL-VS-HA-TR-2005-1061 JOURNAL OF GEOPHYSICAL RESEARCH, VOL. 109, A02305, doi:10.1029/2003JA010205, 2004 On the onset of HF-induced airglow at HAARP ...line) during the February 2002 campaign at the High Frequency Active Auroral Research Program ( HAARP ) heating facility are analyzed. We find that... HAARP , J. Geophys. Res., 109, A02305, doi: 10.1029/2003JA010205. 1. Introduction known as the parametric decay (PDI) or oscillating two- [2] A

  11. HF Over-the-Horizon Radar System Performance Analysis

    Science.gov (United States)

    2007-09-01

    target detection technique and radar equations are applied. Chapter V uses PROPLAB model simulation to bring in the principle of raytracing and... RADAR SYSTEM PERFORMANCE ANALYSIS by Bin-Yi Liu September 2007 Thesis Co-Advisors: Phillip E. Pace Jeffrey B. Knorr THIS PAGE...Thesis 4. TITLE AND SUBTITLE HF Over-the-Horizon Radar System Performance Analysis 6. AUTHOR(S) Bin-Yi Liu 5. FUNDING NUMBERS 7. PERFORMING

  12. Wideband high frequency (HF) skywave channel parameters from narrowband measurements

    Science.gov (United States)

    Hausman, Cynthia L.; Uffelman, Donald R.; Walton, Thomas L.

    The HF wideband channel allow the use of spread-spectrum techniques to provide covert communications with low probability of intercept (LPI) and antijam protection. The objective of this work is to determine the extent to which oblique narrowband channel measurements can be used to infer effects in the wideband skywave channel. If oblique narrowband channel measurements can be used as a basis for developing wideband channel models, a large number of existing narrowband measurements can be made available for this task.

  13. Detection of HCl and HF by TTFMS and WMS.

    Science.gov (United States)

    De Luca, Anna Chiara; Pesce, Giuseppe; Rusciano, Giulia; Sasso, Antonio

    2006-04-01

    In this work we discuss on a compact spectrometer based on DFB diode lasers for detection of chloridric and fluoridric acids. HCl and HF concentrations are determined through optical absorption of the P(4) line (lambda=1.7 microm) and the R(3) line (lambda=1.3 microm), respectively. Both lines belong to first overtone vibrational bands and their line strengths are 7.8 x 10(-21)cm/molecule for HCl and 2.8 x 10(-20)cm/molecule for HF. We chose these lines for their relative high intensities and because they are quite far from water vapour lines which represent the main interfering gas for trace-gases analysis. To detect these species we used two different high frequency modulation techniques: two-tone frequency modulation spectroscopy (f(1)=800 MHz and f(2)=804 MHz) was used for HCl while for HF we followed a simpler approach based on wavelength modulation spectroscopy (f=600 kHz). We demonstrate that the two techniques provide comparable detection limit of about 80 ppbV at atmospheric pressure. Positive testing of our spectrometer makes it suitable for in situ measurements of exhaust gases coming from waste incinerators.

  14. Multiple excitation modes in 163Hf

    DEFF Research Database (Denmark)

    Yadav, Rachita; Ma, J.C.; Marsh, J.C.

    2014-01-01

    Excited states of Hf163 were populated using the Zr94(Ge74,5n) reaction and the decay γ rays were measured with the Gammasphere spectrometer. Two previously known bands were extended to higher spins, and nine new bands were identified. In addition to bands associated with three- and five-quasipar......Excited states of Hf163 were populated using the Zr94(Ge74,5n) reaction and the decay γ rays were measured with the Gammasphere spectrometer. Two previously known bands were extended to higher spins, and nine new bands were identified. In addition to bands associated with three- and five......-quasiparticle configurations, two γ−vibrational bands coupled to the i13/2 excitation were also observed. The lowest level of a newly identified, negative-parity band is proposed to be the ground state of the nucleus. A systematic delay of the high-spin proton crossing frequency with increasing quadrupole deformation from Hf...

  15. Electronic structures and properties of Ti, Zr and Hf metals

    Institute of Scientific and Technical Information of China (English)

    2001-01-01

    The electronic structures of pure Ti, Zr and Hf metals with hcp structure were determined by one-atom (OA) theory. According to the electronic structures of these metals,their potential curves, cohesive energies, lattice constants, elasticities and the temperature dependence of linear thermal expansion coefficients were calculated. The electronic structures and characteristic properties of these metals with bcc and fcc structures and liquids were also studied. The results show that the electronic structures of Ti, Zr and Hf metals are respectively [Ar](3dn)0.481 0(3dc)2.085 7(4sc)1.000 0(4sf)0.433 3, [Kr](4dn)0.396 8(4dc)2.142 8(5sc)1.262 0(5sf)0.198 4, [Xe](5dn)0.368 0(5dc)2.041 4(6sc)1.406 6(6sf)0.184 0. It is explained why the pure Ti, Zr and Hf metals with hcp and bcc structures can exist naturally, while those with fcc structure can not.

  16. Lu-Hf and Sm-Nd garnet geochronology

    DEFF Research Database (Denmark)

    Smit, Matthijs Arjen; Scherer, Erik E.; Mezger, Klaus

    2013-01-01

    are similar among grains having radii larger than 1.3 mm (weighted mean: 2714±6 Ma2714±6 Ma; 2 s.d.) and up to 20 Myr younger for finer fractions. In contrast, Sm–Nd dates are equal to or younger than the 2641–2637 Ma age of peak metamorphism. The roles of concurrently digested inclusions and core–rim Lu......To investigate the systematics of the 176Lu–176Hf and 147Sm–143Nd garnet chronometers, we performed REE and isotope analyses on garnet crystals of different size (0.55–3.1 mm radius) from a single granulite specimen (Archean Pikwitonei Granulite Domain, Manitoba, Canada). The Lu–Hf dates....../Sm fractionation are quantitatively evaluated and excluded as causes for the observed age heterogeneity. Instead, the isotope dates are interpreted to reflect partial loss of radiogenic 176Hf and 143Nd, and are used to constrain the systematics of the garnet chronometers at high temperature. The data constrain...

  17. TID measurement using oblique transmissions of HF pulses

    Science.gov (United States)

    Galkin, Ivan; Reinisch, Bodo; Huang, Xueqin; Paznukhov, Vadym; Hamel, Ryan; Kozlov, Alexander; Belehaki, Anna

    2017-04-01

    The Traveling Ionospheric Disturbance (TID), a wave-like signature of moving plasma density modulation in the ionosphere, is widely acknowledged for its utility in backtracking the anomalous events responsible for the TID generation, and as a major inconvenience to high-frequency (HF) operational systems because of its deleterious impact on the accuracy of navigation and geolocation. The pilot project "Net-TIDE" for the real-time detection and evaluation of TIDs began its operation in 2016 based on the remote-sensing data from synchronized, network-coordinated HF sounding between pairs of DPS4D ionosondes at five participating observatories in Europe. Measurement of all signal properties (Doppler frequency, angle of arrival, and time-of-flight from transmitter to receiver) proved to be instrumental in detecting the TID and deducing the TID parameters: amplitude, wavelength, phase velocity, and direction of propagation. Processing of the measured HF signal data required a specialized signal processing technique that is capable of consistently extracting different signals that have propagated along different ionospheric paths. The multi-path signal environment proved to be the greatest challenge for the reliable TID specification by Net-TIDE, demanding the development of an intelligent system for "signal tracking". The intelligent system is based on a neural network model of a pre-attentive vision capable of extracting continuous signal tracks from the multi-path signal ensemble. Specific examples of the Net-TIDE algorithm suite operation and its suitability for a fully automated TID warning service are discussed.

  18. High-spin positive-parity states in 179Hf studied by the 180Hf(τ, α) 179Hf reaction AT 32 MeV

    Science.gov (United States)

    Thorsteinsen, T. F.; Løvhøiden, G.; Vaagen, J. S.; Bjørnberg, A.; Burke, D. G.

    1981-06-01

    Full angular distributions are presented for states populated in the reaction 180Hf(τ, α) 179Hf at 32 MeV beam energy. Positive-parity states associated with the i {13}/{2} unique parity intruder orbital are given special attention. Thus, angular distributions for the five first members of the [624 {9}/{2}] groundstate sequence are given, as well as for a number of more highly excited states, some being new assignments. The distribution of l = 6 transfer strength is quite characteristic, two {13}/{2}+ states being substantially more populated than the rest. The characteristic features of the data are explained by a quasiparticle-rotor calculation employing deformed Woods-Saxon orbitals, but only if the hexadecapole shape parameter of the nuclear potential is β 4 ˜ -0.08. The often anomalous differential cross sections for I π ≠ {13}/{2}+ band members are well accounted for by a rotor model CCBA calculation employing transfer form factors extracted from the orbitals of the deformed Woods-Saxon field, and including non-adiabatic Coriolis mixing effects.

  19. Hf isotopic compositions of the standard zircons for U-Pb dating

    Institute of Scientific and Technical Information of China (English)

    XU Ping; WU Fuyuan; XIE Liewen; YANG Yueheng

    2004-01-01

    Using the newly published Yb isotopic abundances and the mass bias relationship between Yb and Hf, we carried out an analysis of Hf isotopes in the standard zircon 91500 by means of 193 nm laser attached to Neptune multi-collector ICP-MS (LA-MC-ICPMS). The obtained Hf isotopic data, in either in situ or line scan modes, are not only identical for different spot sizes, but also are consistent with previously published results obtained on TIMS or other MC-ICPMS machines within errors. This indicates that it is possible to obtain reliable 176Hf/177Hf isotopic ratios for zircon in either in situ or line scan conditions on LA-MC-ICPMS machine, and the applied procedures in our study for elemental interfering correction are appropriate for the purpose of acquiring satisfactory accuracy for Hf isotope analyses. The Hf isotopic compositions of four zircon standards in high spatial resolution U-Pb dating, 91500, CZ3,CN92-1 and TEMORA, are measured, respectively. The obtained 176Hf/177Hf ratios are 0.282316+4 (n = 34, 2σ) for 91500, 0.281704±6 (n = 16, 2σ) for CZ3, 0.282200±6 (n = 20,2σ-) for CN92-1 and 0.282684±14 (n = 24, 2σ) for TEMORA,respectively, with 176Lu/177Hf ratios of ~0.00031, 0.000036,0.00083 and 0.00127. Zircons 91500 and CZ3 show narrower variations in 176Hf/177Hf and 176Lu/177Hf ratios than those of zircons CN92-1 and TEMORA, and thus are appropriate standards for the Hf isotope analysis.

  20. Electrical characteristics of MOS capacitor with HfTiON gate dielectric and HfTiSiON interlayer

    Institute of Scientific and Technical Information of China (English)

    Chen Wei-Bing; Xu Jing-Ping; Lai Pui-To; Li Yan-Ping; Xu Sheng-Guo; Chan Chu-Lok

    2006-01-01

    The paper reports that HfTiO dielectric is deposited by reactive co-sputtering of Hf and Ti targets in an Ar/O2 ambience, followed by an annealing in different gas ambiences of N2, NO and NHa at 600°C for 2 min. Capacitance-voltage and gate-leakage properties are characterized and compared. The results indicate that the NO-annealed sample exhibits the lowest interface-state and dielectric-charge densities and best device reliability. This is attributed to the fact that nitridation can create strong Si≡N bonds to passivate dangling Si bonds and replace strained Si- O bonds, thus the sample forms a hardened dielectric/Si interface with high reliability.

  1. Nightside studies of coherent HF Radar spectral width behaviour

    Directory of Open Access Journals (Sweden)

    E. E. Woodfield

    Full Text Available A previous case study found a relationship between high spectral width measured by the CUTLASS Finland HF radar and elevated electron temperatures observed by the EISCAT and ESR incoherent scatter radars in the post-midnight sector of magnetic local time. This paper expands that work by briefly re-examining that interval and looking in depth at two further case studies. In all three cases a region of high HF spectral width (>200 ms-1 exists poleward of a region of low HF spectral width (<200 ms-1. Each case, however, occurs under quite different geomagnetic conditions. The original case study occurred during an interval with no observed electrojet activity, the second study during a transition from quiet to active conditions with a clear band of ion frictional heating indicating the location of the flow reversal boundary, and the third during an isolated sub-storm. These case studies indicate that the relationship between elevated electron temperature and high HF radar spectral width appears on closed field lines after 03:00 magnetic local time (MLT on the nightside. It is not clear whether the same relationship would hold on open field lines, since our analysis of this relationship is restricted in latitude. We find two important properties of high spectral width data on the nightside. Firstly the high spectral width values occur on both open and closed field lines, and secondly that the power spectra which exhibit high widths are both single-peak and multiple-peak. In general the regions of high spectral width (>200 ms-1 have more multiple-peak spectra than the regions of low spectral widths whilst still maintaining a majority of single-peak spectra. We also find that the region of ion frictional heating is collocated with many multiple-peak HF spectra. Several mechanisms for the generation of high spectral width have been proposed which would produce multiple-peak spectra, these are discussed in relation to

  2. Potency of a vaccine prepared from A/swine/Hokkaido/2/1981 (H1N1 against A/Narita/1/2009 (H1N1 pandemic influenza virus strain

    Directory of Open Access Journals (Sweden)

    Okamatsu Masatoshi

    2013-02-01

    Full Text Available Abstract Background The pandemic 2009 (H1N1 influenza virus has spread throughout the world and is now causing seasonal influenza. To prepare for the emergence of pandemic influenza, we have established a library of virus strains isolated from birds, pigs, and humans in global surveillance studies. Methods Inactivated whole virus particle (WV and ether-split (ES vaccines were prepared from an influenza virus strain, A/swine/Hokkaido/2/1981 (H1N1, from the library and from A/Narita/1/2009 (H1N1 pandemic strain. Each of the vaccines was injected subcutaneously into mice and their potencies were evaluated by challenge with A/Narita/1/2009 (H1N1 virus strain in mice. Results A/swine/Hokkaido/2/81 (H1N1, which was isolated from the lung of a diseased piglet, was selected on the basis of their antigenicity and growth capacity in embryonated chicken eggs. Two injections of the WV vaccine induced an immune response in mice, decreasing the impact of disease caused by the challenge with A/Narita/1/2009 (H1N1, as did the vaccine prepared from the homologous strain. Conclusion The WV vaccine prepared from an influenza virus in the library is useful as an emergency vaccine in the early phase of pandemic influenza.

  3. The magnetic properties of $^{\\rm 177}$Hf and $^{\\rm 180}$Hf in the strong coupling deformed model

    CERN Document Server

    Muto, S; Bingham, C R; Stone, J R; Walker, P M; Audi, G; Gaulard, C; Köster, U; Nikolov, J; Nishimura, K; Ohtsubo, T; Podolyak, Z; Risegari, L; Simpson, G S; Veskovic, M; Walters, W B

    2014-01-01

    This paper reports NMR measurements of the magnetic dipole moments of two high-K isomers, the 37/2$^-$, 51.4 m, 2740 keV state in $^{\\rm 177}$Hf and the 8$^-$, 5.5 h, 1142 keV state in $^{\\rm 180}$Hf by the method of on-line nuclear orientation. Also included are results on the angular distributions of gamma transitions in the decay of the $^{\\rm 177}$Hf isotope. These yield high precision E2/M1 multipole mixing ratios for transitions in bands built on the 23/2$^+$, 1.1 s, isomer at 1315 keV and on the 9/2$^+$, 0.663 ns, isomer at 321 keV. The new results are discussed in the light of the recently reported finding of systematic dependence of the behavior of the g$_{\\rm R}$ parameter upon the quasi-proton and quasi-neutron make up of high-K isomeric states in this region.

  4. Age and speciation of iodine in groundwater and mudstones of the Horonobe area, Hokkaido, Japan: Implications for the origin and migration of iodine during basin evolution

    Science.gov (United States)

    Togo, Yoko S.; Takahashi, Yoshio; Amano, Yuki; Matsuzaki, Hiroyuki; Suzuki, Yohey; Terada, Yasuko; Muramatsu, Yasuyuki; Ito, Kazumasa; Iwatsuki, Teruki

    2016-10-01

    This paper reports the concentration, speciation and isotope ratio (129I/127I) of iodine from both groundwater and host rocks in the Horonobe area, northern Hokkaido, Japan, to clarify the origin and migration of iodine in sedimentary rocks. Cretaceous to Quaternary sedimentary rocks deposited nearly horizontally in Tenpoku Basin and in the Horonobe area were uplifted above sea level during active tectonics to form folds and faults in the Quaternary. Samples were collected from the Pliocene Koetoi and late Miocene Wakkanai formations (Fms), which include diatomaceous and siliceous mudstones. The iodine concentration in groundwater, up to 270 μmol/L, is significantly higher than that of seawater, with the iodine enrichment factor relative to seawater reaching 800-1500. The iodine concentration in the rocks decreases from the Koetoi to Wakkanai Fms, suggesting that iodine was released into the water from the rocks of deeper formations. The iodine concentration in the rocks is sufficiently high for forming iodine-rich groundwater as found in this area. X-ray absorption near edge structure (XANES) analysis shows that iodine exists as organic iodine and iodide (I-) in host rocks, whereas it exists mainly as I- in groundwater. The isotope ratio is nearly constant for iodine in the groundwater, at [0.11-0.23] × 10-12, and it is higher for iodine in rocks, at [0.29-1.1] × 10-12, giving iodine ages of 42-60 Ma and 7-38 Ma, respectively. Some iodine in groundwater must have originated from Paleogene and even late Cretaceous Fms, which are also considered as possible sources of oil and gas, in view of the old iodine ages of the groundwater. The iodine ages of the rocks are older than the depositional ages, implying that the rocks adsorbed some iodine from groundwater, which was sourced from greater depths. The iodine concentration in groundwater decreases with decreasing chlorine concentration due to mixing of iodine-rich connate water and meteoric water. A likely scenario

  5. Polarity reversion of the operation mode of HfO2-based resistive random access memory devices by inserting Hf metal layer.

    Science.gov (United States)

    Peng, Ching-Shiang; Chang, Wen-Yuan; Lin, Ming-Ho; Chen, Wei-Su; Chen, Frederick; Tsai, Ming-Jinn

    2013-03-01

    The reversion of polarity within bipolar resistive switching operation occurs in Pt/HfO2/TiN and Pt/Hf/HfO2/TiN resistive random access memory devices. This reversion of voltage polarity is the result of interface generation which induces a conduction mechanism transformation from Poole-Frenkel emission to space charge limited current mechanism. To prove the reversion of polarity, this study uses curve fitting of I-V relations to verify the conduction mechanism theoretically and physical analysis to verify the oxygen ion distribution practically. The proposed Pt/Hf/HfO2/TiN devices exhibit good resistive switching characteristics, such as good uniformity, low voltage operation, robust endurance (10(3) dc sweep), and long retention (3 x 10(4) s at 85 degrees C).

  6. Vertically oriented few-layered HfS2 nanosheets: growth mechanism and optical properties

    Science.gov (United States)

    Zheng, Binjie; Chen, Yuanfu; Wang, Zegao; Qi, Fei; Huang, Zhishuo; Hao, Xin; Li, Pingjian; Zhang, Wanli; Li, Yanrong

    2016-09-01

    For the first time, large-area, vertically oriented few-layered hafnium disulfide (V-{{{HfS}}}2) nanosheets have been grown by chemical vapor deposition. The individual {{{HfS}}}2 nanosheets are well [001] oriented, with highly crystalline quality. Far different from conventional van der Waals epitaxial growth mechanism for two-dimensional transition metal dichalcogenides, a novel dangling-bond-assisted self-seeding growth mechanism is proposed to describe the growth of V-{{{HfS}}}2 nanosheets: difficult migration of {{{HfS}}}2 adatoms on substrate surface results in {{{HfS}}}2 seeds growing perpendicularly to the substrate; V-{{{HfS}}}2 nanosheets inherit the growth direction of {{{HfS}}}2 seeds; V-{{{HfS}}}2 nanosheets further expand in the in-plane direction with time evolution. Moreover, the V-{{{HfS}}}2 nanosheets show strong and broadened photons absorption from near infrared to ultraviolet; the V-{{{HfS}}}2-based photodetector exhibits an ultrafast photoresponse time of 24 ms, and a high photosensitivity ca. 103 for 405 nm laser.

  7. Empirical Study of the Multiaxial, Thermomechanical Behavior of NiTiHf Shape Memory Alloys

    Science.gov (United States)

    Shukla, Dhwanil; Noebe, Ronald D.; Stebner Aaron P.

    2013-01-01

    An empirical study was conducted to characterize the multiaxial, thermomechanical responses of new high temperature NiTiHf alloys. The experimentation included loading thin walled tube Ni(sub 50.3)Ti(sub 29.7)Hf(sub 20) alloy samples along both proportional and nonproportional axial-torsion paths at different temperatures while measuring surface strains using stereo digital image correlation. A Ni(sub 50.3)Ti(sub 33.7)Hf(sub 16) alloy was also studied in tension and compression to document the effect of slightly depleting the Hf content on the constitutive responses of NiTiHf alloys. Samples of both alloys were made from nearly texture free polycrystalline material processed by hot extrusion. Analysis of the data shows that very small changes in composition significantly alter NiTiHf alloy properties, as the austenite finish (Af) temperature of the 16-at Hf alloy was found to be approximately 60 C less than the 20-at Hf alloy (approximately 120 C vs. 180 C). In addition, the 16-at Hf alloy exhibited smaller compressive transformation strains (2 vs. 2.5 percent). Multi-axial characterization of the 20-at % Hf alloy showed that while the random polycrystal transformation strains in tension (4 percent) and compression (2.5 percent) are modest in comparison with binary NiTi (6 percent, 4 percent), the torsion performance is superior (7 vs. 4 shear strain width to the pseudoelastic plateau).

  8. Effects of HfB2 and HfN Additions on the Microstructures and Mechanical Properties of TiB2-Based Ceramic Tool Materials

    Directory of Open Access Journals (Sweden)

    Jing An

    2017-04-01

    Full Text Available The effects of HfB2 and HfN additions on the microstructures and mechanical properties of TiB2-based ceramic tool materials were investigated. The results showed that the HfB2 additive not only can inhibit the TiB2 grain growth but can also change the morphology of some TiB2 grains from bigger polygons to smaller polygons or longer ovals that are advantageous for forming a relatively fine microstructure, and that the HfN additive had a tendency toward agglomeration. The improvement of flexural strength and Vickers hardness of the TiB2-HfB2 ceramics was due to the relatively fine microstructure; the decrease of fracture toughness was ascribed to the formation of a weaker grain boundary strength due to the brittle rim phase and the poor wettability between HfB2 and Ni. The decrease of the flexural strength and Vickers hardness of the TiB2-HfN ceramics was due to the increase of defects such as TiB2 coarse grains and HfN agglomeration; the enhancement of fracture toughness was mainly attributed to the decrease of the pore number and the increase of the rim phase and TiB2 coarse grains. The toughening mechanisms of TiB2-HfB2 ceramics mainly included crack bridging and transgranular fracture, while the toughening mechanisms of TiB2-HfN ceramics mainly included crack deflection, crack bridging, transgranular fracture, and the core-rim structure.

  9. Crystallography of the NiHfSi Phase in a NiAl (0.5 Hf) Single-Crystal Alloy

    Science.gov (United States)

    Garg, A.; Noebe, R. D.; Darolia, R.

    1996-01-01

    Small additions of Hf to conventionally processed NiAl single crystals result in the precipitation of a high density of cuboidal G-phase along with a newly identified silicide phase. Both of these phases form in the presence of Si which is not an intentional alloying addition but is a contaminant resulting from contact with the ceramic shell molds during directional solidification of the single-crystal ingots. The morphology, crystal structure and Orientation Relationship (OR) of the silicide phase in a NiAl (0.5 at.%Hf) single-crystal alloy have been determined using transmission electron microscopy, electron microdiffraction and energy dispersive X-ray spectroscopy. Qualitative elemental analysis and indexing of the electron microdiffraction patterns from the new phase indicate that it is an orthorhombic NiHfSi phase with unit cell parameters, a = 0.639 nm, b = 0.389 nm and c = 0.72 nm, and space group Pnma. The NiHfSi phase forms as thin rectangular plates on NiAl/111/ planes with an OR that is given by NiHfSi(100))(parallel) NiAl(111) and NiHfSi zone axes(010) (parallel) NiAl zone axes (101). Twelve variants of the NiHfSi phase were observed in the alloy and the number of variants and rectangular morphology of NiHfSi plates are consistent with symmetry requirements. Quenching experiments indicate that nucleation of the NiHfSi phase in NiAI(Hf) alloys is aided by the formation of NiAl group of zone axes (111) vacancy loops that form on the NiAl /111/ planes.

  10. An ab initio study of the C2H2-HF, C2H(CH3)-HF and C2(CH3)2-HF hydrogen-bonded complexes.

    Science.gov (United States)

    Ramos, Mozart N; Lopes, Kelson C; Silva, Washington L V; Tavares, Alessandra M; Castriani, Fátima A; do Monte, Silmar A; Ventura, Elizete; Araújo, Regiane C M U

    2006-02-01

    MP2/6-31++G** and B3LYP/6-31++G** ab initio molecular orbital calculations have been performed in order to obtain molecular geometries, binding energies and vibrational properties of the C2H2-HF, C2H(CH3)-HF and C2(CH3)2-HF H-bonded complexes. As expected, the more pronounced effects on the structural properties of the isolated molecules due to complexation was verified for the C[triple bond]C and H-F bond lengths, which are directly involved in the H-bond formation. These bond distances increased after complexation. BSSE uncorrected B3LYP binding energies are always lower than the corresponding MP2 values. However, the opposite trend has been verified after BSSE correction by the counterpoise method since it is much lower at B3LYP than at MP2 level. The binding energies for these complexes as well as for the HF acid submolecule modes (the HF stretching and vibrational frequency modes) showed an increasing hydrogen-bonding strength with increasing methyl substitution. The splitting in the HF in-plane and out-of-plane bending modes reflects the anisotropy in the hydrogen-bonding interaction with the pi system of the C[triple bond]C bond. The H-F stretching frequency is shifted downward after complexation and it increases with the methyl substitution. The IR intensities of the HF acid submolecule fundamentals are adequately interpreted through the atomic polar tensor of the hydrogen atom using the charge-charge flux-overlap model. The skeletal stretching modes of the Alkyne submolecule are decreased in the complex. The new vibrational modes arising from complexation show several interesting features.

  11. Coalescence of silver clusters by immersion in diluted HF solution

    Energy Technology Data Exchange (ETDEWEB)

    Milazzo, R. G.; Mio, A. M.; D’Arrigo, G.; Spinella, C. [CNR-IMM Institute for Microelectronics and Microsystems, I-95121 Catania (Italy); Grimaldi, M. G. [Department of Physics and Astronomy, Università di Catania, I-95123 Catania (Italy); MATIS IMM-CNR, I-95123 Catania (Italy); Rimini, E. [CNR-IMM Institute for Microelectronics and Microsystems, I-95121 Catania (Italy); Department of Physics and Astronomy, Università di Catania, I-95123 Catania (Italy)

    2015-07-14

    The galvanic displacement deposition of silver on H-terminated Si (100) in the time scale of seconds is instantaneous and characterized by a cluster density of 10{sup 11}-10{sup 12} cm{sup −2}. The amount of deposited Ag follows a t{sup 1/2} dependence in agreement with a Cottrell diffusion limited mechanism. At the same time, during the deposition, the cluster density reduces by a factor 5. This behavior is in contrast with the assumption of immobile clusters. We show in the present work that coalescence and aggregation occur also in the samples immersed in the diluted hydrofluoric acid (HF) solution without the presence of Ag{sup +}. Clusters agglomerate according to a process of dynamic coalescence, typical of colloids, followed by atomic redistribution at the contact regions with the generation of multiple internal twins and stacking-faults. The normalized size distributions in terms of r/r{sub mean} follow also the prediction of the Smoluchowski ripening mechanism. No variation of the cluster density occurs for samples immersed in pure H{sub 2}O solution. The different behavior might be associated to the strong attraction of clusters to oxide-terminated Si surface in presence of water. The silver clusters are instead weakly bound to hydrophobic H-terminated Si in presence of HF. HF causes then the detachment of clusters and a random movement on the silicon surface with mobility of about 10{sup −13} cm{sup 2}/s. Attractive interaction (probably van der Waals) among particles promotes coarsening.

  12. Strong photoluminescence of the porous silicon with HfO2-filled microcavities

    Science.gov (United States)

    Jiang, Ran; Wu, Zhengran; Du, Xianghao; Han, Zuyin; Sun, Weideng

    2015-06-01

    Greatly enhanced blue emission was observed at room temperature in the single-crystal silicon with HfO2 filled into its microcavities. The broad blue band light was emitted from both the HfO2 dielectric and the porous Si. The ferroelectricity of HfO2 enhances the blue emission from Si by its filling into the microcaivities. At the same time, HfO2 contributes to the light emission for the transitions of the defect levels for oxygen vacancy. The observation of greatly enhanced blue light emission of the porous Si filled with HfO2 dielectric is remarkable as both HfO2 and Si are highly compatible with Si-based electronic industry.

  13. Ozone Treatment Improved the Resistive Switching Uniformity of HfAlO2 Based RRAM Devices

    Directory of Open Access Journals (Sweden)

    Lifeng Liu

    2015-01-01

    Full Text Available HfAlO2 based resistive random access memory (RRAM devices were fabricated using atomic layer deposition by modulating deposition cycles for HfO2 and Al2O3. Effect of ozone treatment on the resistive switching uniformity of HfAlO2 based RRAM devices was investigated. Compared to the as-fabricated devices, the resistive switching uniformity of HfAlO2 based RRAM devices with the ozone treatment is significantly improved. The uniformity improvement of HfAlO2 based RRAM devices is related to changes in compositional and structural properties of the HfAlO2 resistive switching film with the ozone treatment.

  14. Medium-Range Order Structure and Fragility of Superheated Melts of Amorphous CuHf Alloys

    Institute of Scientific and Technical Information of China (English)

    BIAN Xiu-Fang; SUN Bao-An; HU Li-Na

    2006-01-01

    @@ The structural factors of amorphous CuHf alloys at different temperatures are determined by using a high temperature x-ray diffractometer. It is found that not only the short-range order structure but also the medium-range order structure exists in amorphous CuHf alloys. The dynamic viscosities of CuHf alloy melts are measured by a torsional oscillation viscometer. The fragility of superheated melts of CuHf alloys is calculated based on the viscosity data. The experimental results show that the glass-forming ability of the CuHf alloys is closely related to the fragility of their superheated melt. The relationship between the medium-range order structures and the fragility of superheated melts has also been established in amorphous CuHf alloys. In contrast to the fragility of supercooled liquids, the fragility of superheated liquids promises a better approach to reflecting the dynamics of glass forming liquids.

  15. Ionosphere research with a HF/MF cubesat radio instrument

    Science.gov (United States)

    Kallio, Esa; Aikio, Anita; Alho, Markku; Fontell, Mathias; Harri, Ari-Matti; Kauristie, Kirsti; Kestilä, Antti; Koskimaa, Petri; Mäkelä, Jakke; Mäkelä, Miika; Turunen, Esa; Vanhamäki, Heikki; Verronen, Pekka

    2017-04-01

    New technology provides new possibilities to study geospace and 3D ionosphere by using spacecraft and computer simulations. A type of nanosatellites, CubeSats, provide a cost effective possibility to provide in-situ measurements in the ionosphere. Moreover, combined CubeSat observations with ground-based observations gives a new view on auroras and associated electromagnetic phenomena. Especially joint and active CubeSat - ground based observation campaigns enable the possibility of studying the 3D structure of the ionosphere. Furthermore using several CubeSats to form satellite constellations enables much higher temporal resolution. At the same time, increasing computation capacity has made it possible to perform simulations where properties of the ionosphere, such as propagation of the electromagnetic waves in the medium frequency, MF (0.3-3 MHz) and high frequency, HF (3-30 MHz), ranges is based on a 3D ionospheric model and on first-principles modelling. Electromagnetic waves at those frequencies are strongly affected by ionospheric electrons and, consequently, those frequencies can be used for studying the plasma. On the other hand, even if the ionosphere originally enables long-range telecommunication at MF and HF frequencies, the frequent occurrence of spatiotemporal variations in the ionosphere disturbs communication channels, especially at high latitudes. Therefore, study of the MF and HF waves in the ionosphere has both a strong science and technology interests. We introduce recently developed simulation models as well as measuring principles and techniques to investigate the arctic ionosphere by a polar orbiting CubeSat whose novel AM radio instrument measures HF and MF waves. The cubesat, which contains also a white light aurora camera, is planned to be launched in late 2017 (http://www.suomi100satelliitti.fi/eng). The new models are (1) a 3D ray tracing model and (2) a 3D full kinetic electromagnetic simulation. We also introduce how combining of the

  16. HF beacon network for ionospheric specification in Peru

    Science.gov (United States)

    Hysell, D. L.; Milla, M. A.; Vierinen, J.

    2016-12-01

    A growing network of HF beacon transmitters and receivers is being deployed in Peru for specifying the F region ionosphere regionally. The effort is motivated by ionospheric disturbances associated with equatorial spread F (ESF), especially disturbances arising under inauspicious ESF conditions. The beacons use dual frequencies (2.72 and 3.64 MHz). They incorporate PRN coding to afford group-delay measurements. Scatered power, Doppler shift, bearing, and polarization are also measured. An algorithm for inverting the beacon data combined with electron density profiles from Jicamarca is described. Data and representative solutions from recent campaigns will be reviewed.

  17. A SYNCHRONIZATION ALGORITHM FOR HF (HIGH FREQUENCY) BROADBAND OFDM SYSTEM

    Institute of Scientific and Technical Information of China (English)

    Yang Lei; Zhang You'ai

    2008-01-01

    In this letter, a kind of associated synchronization algorithm which is suitable for HF (High Frequency) broadband OFDM (Orthogonal Frequency Division Multiplexing) system is presented based on describing and constructing the GMW (Gorden, Mills and Welch) sequence. The algorithm is based on the Schmidl and Minn's symbol timing principle, the constructed GMW sequence is transmitted and disposed, and the synchronization is adjudicated using the correlation of GMW sequence. The simulation result indicates that this algorithm has high performance synchronization ability under the low SNR (Signal to Noise Ratio) at two different kinds of channel models.

  18. Meteorite zircon constraints on the bulk Lu-Hf isotope composition and early differentiation of the Earth.

    Science.gov (United States)

    Iizuka, Tsuyoshi; Yamaguchi, Takao; Hibiya, Yuki; Amelin, Yuri

    2015-04-28

    Knowledge of planetary differentiation is crucial for understanding the chemical and thermal evolution of terrestrial planets. The (176)Lu-(176)Hf radioactive decay system has been widely used to constrain the timescales and mechanisms of silicate differentiation on Earth, but the data interpretation requires accurate estimation of Hf isotope evolution of the bulk Earth. Because both Lu and Hf are refractory lithophile elements, the isotope evolution can be potentially extrapolated from the present-day (176)Hf/(177)Hf and (176)Lu/(177)Hf in undifferentiated chondrite meteorites. However, these ratios in chondrites are highly variable due to the metamorphic redistribution of Lu and Hf, making it difficult to ascertain the correct reference values for the bulk Earth. In addition, it has been proposed that chondrites contain excess (176)Hf due to the accelerated decay of (176)Lu resulting from photoexcitation to a short-lived isomer. If so, the paradigm of a chondritic Earth would be invalid for the Lu-Hf system. Herein we report the first, to our knowledge, high-precision Lu-Hf isotope analysis of meteorite crystalline zircon, a mineral that is resistant to metamorphism and has low Lu/Hf. We use the meteorite zircon data to define the Solar System initial (176)Hf/(177)Hf (0.279781 ± 0.000018) and further to identify pristine chondrites that contain no excess (176)Hf and accurately represent the Lu-Hf system of the bulk Earth ((176)Hf/(177)Hf = 0.282793 ± 0.000011; (176)Lu/(177)Hf = 0.0338 ± 0.0001). Our results provide firm evidence that the most primitive Hf in terrestrial zircon reflects the development of a chemically enriched silicate reservoir on Earth as far back as 4.5 billion years ago.

  19. Thermodynamic modeling of the Co–Hf system supported by key experiments and first-principles calculations

    Energy Technology Data Exchange (ETDEWEB)

    Lu, Xingxu [School of Materials Science and Engineering, Central South University, Changsha, Hunan 410083 (China); State Key Laboratory of Powder Metallurgy, Central South University, Changsha, Hunan 410083 (China); Liu, Shuhong, E-mail: shhliu@csu.edu.cn [State Key Laboratory of Powder Metallurgy, Central South University, Changsha, Hunan 410083 (China); Sino-German Cooperation Group “Microstructure in Al alloys”, Central South University, Changsha, Hunan 410083 (China); Cheng, Kaiming; Tang, Ying [State Key Laboratory of Powder Metallurgy, Central South University, Changsha, Hunan 410083 (China); Ou, Pengfei [School of Materials Science and Engineering, Central South University, Changsha, Hunan 410083 (China); State Key Laboratory of Powder Metallurgy, Central South University, Changsha, Hunan 410083 (China); Nash, Philip [Thermal Processing Technology Center, Illinois Institute of Technology (IIT), 10 West 32nd Street, Chicago, IL 60616 (United States); Sundman, Bo [INSTN, CEA Saclay, 91191 Gif-Sur-Yvette Cedex (France); Du, Yong [State Key Laboratory of Powder Metallurgy, Central South University, Changsha, Hunan 410083 (China); Sino-German Cooperation Group “Microstructure in Al alloys”, Central South University, Changsha, Hunan 410083 (China); Zheng, Feng [School of Materials Science and Engineering, Central South University, Changsha, Hunan 410083 (China)

    2015-05-20

    Highlights: • Heat contents of Co{sub 2}Hf and CoHf{sub 2} were measured by drop calorimetry. • Enthalpy of formation for Co{sub 23}Hf{sub 6} was computed via first-principles calculations. • Co–Hf system was assessed by means of CALPHAD approach. • Order–disorder model is used to describe B2 (CoHf) and A2 (βHf). • Glass forming range of the Co–Hf amorphous alloys was predicted. - Abstract: Phase equilibria and thermodynamic properties of the Co–Hf system were investigated via calorimetric measurements, first-principles calculations and thermodynamic modeling. Heat contents of Co{sub 2}Hf and CoHf{sub 2} were measured by drop calorimetry from 300 to 1200 °C. The enthalpy of formation for Co{sub 23}Hf{sub 6} at 0 K was computed via first-principles calculations. Based on the experimental measurements and first-principles calculations from the present work and the literature, the Co–Hf system was assessed by means of CALPHAD (CALculation of PHAse Diagram) approach. The excess Gibbs energy of solution phases was modeled with Redlich–Kister polynomial. Sublattice models were employed to describe the homogeneity ranges of Co{sub 2}Hf, CoHf and CoHf{sub 2}. The order–disorder transition between B2 (CoHf) and A2 (βHf) phases was taken into account in the current optimization. Using the optimized parameters, glass forming range (GFR) of the Co–Hf amorphous alloys was predicted to be 15–75 at.% Hf, which is in satisfactory agreement with the experimental observation.

  20. Description of $^{178}$Hf$^{m2}$ in the constrained relativistic mean field theory

    CERN Document Server

    Wei, Zhang; Shuang-Quan, Zhang

    2009-01-01

    The properties of the ground state of $^{178}$Hf and the isomeric state $^{178}$Hf$^{m2}$ are studied within the adiabatic and diabatic constrained relativistic mean field (RMF) approaches. The RMF calculations reproduce well the binding energy and the deformation for the ground state of $^{178}$Hf. Using the ground state single-particle eigenvalues obtained in the present calculation, the lowest excitation configuration with $K^\\pi=16^+$ is found to be $\

  1. Assembly of the CMS HF (hadron forward) calorimeter, April 2003 to June 2005

    CERN Multimedia

    Tejinder S. Virdee, CERN

    2005-01-01

    The forward calorimeters (HF) of the CMS hadron calorimeter system are located 11.2 m from the interaction point. Each HF module is composed by 18 wedges, made of steel absorbers and radiation-hard quartz fibers. The photogallery shows the wedges (Figs. 1-3, April 2003), the assembly of one HF module (Figs. 4-9, May and June 2004) and the assembly of the other (Figs. 10-11, June 2005)

  2. Far-Field Testing Method of Spurious Emission Produced by HF RFID

    OpenAIRE

    Nikola Gvozdenovic; Ralph Prestros; Mecklenbräuker, Christoph F.

    2016-01-01

    We present measurements of spurious emission produced by high-frequency radio frequency identification (HF RFID) using carrier frequency of 13.56 MHz. HF RFID tags produce unwanted emission due to rectification and more generally due to nonlinearity of analog front end. Depending on the conducting material of an HF RFID coil and surrounding dielectric material, the coil behaves as more or less good antenna on some harmonic frequencies. Exact characterization and analysis of unwanted emission ...

  3. Enhanced resistive switching and multilevel behavior in bilayered HfAlO/HfAlO{sub x} structures for non-volatile memory applications

    Energy Technology Data Exchange (ETDEWEB)

    Faita, F. L., E-mail: fabriciofaita@gmail.com [Centre of Physics, University of Minho, Campus de Gualtar, 4710-057 Braga (Portugal); Departamento de Física, Universidade Federal de Santa Catarina, Campus Trindade, 88040-900 Florianópolis, SC (Brazil); Silva, J. P. B., E-mail: josesilva@fisica.uminho.pt [Centre of Physics, University of Minho, Campus de Gualtar, 4710-057 Braga (Portugal); IFIMUP and IN-Institute of Nanoscience and Nanotechnology, Departamento de Física e Astronomia, Faculdade de Ciências da Universidade do Porto, 4169-007 Porto (Portugal); Pereira, M.; Gomes, M. J. M. [Centre of Physics, University of Minho, Campus de Gualtar, 4710-057 Braga (Portugal)

    2015-12-14

    In this work, hafnium aluminum oxide (HfAlO) thin films were deposited by ion beam sputtering deposition technique on Si substrate. The presence of oxygen vacancies in the HfAlO{sub x} layer deposited in oxygen deficient environment is evidenced from the photoluminescence spectra. Furthermore, HfAlO(oxygen rich)/HfAlO{sub x}(oxygen poor) bilayer structures exhibit multilevel resistive switching (RS), and the switching ratio becomes more prominent with increasing the HfAlO layer thickness. The bilayer structure with HfAlO/HfAlO{sub x} thickness of 30/40 nm displays the enhanced multilevel resistive switching characteristics, where the high resistance state/intermediate resistance state (IRS) and IRS/low resistance state resistance ratios are ≈10{sup 2} and ≈5 × 10{sup 5}, respectively. The switching mechanisms in the bilayer structures were investigated by the temperature dependence of the three resistance states. This study revealed that the multilevel RS is attributed to the coupling of ionic conduction and the metallic conduction, being the first associated to the formation and rupture of conductive filaments related to oxygen vacancies and the second with the formation of a metallic filament. Moreover, the bilayer structures exhibit good endurance and stability in time.

  4. Ferroelectric phase stabilization of HfO2 by nitrogen doping

    Science.gov (United States)

    Xu, Lun; Nishimura, Tomonori; Shibayama, Shigehisa; Yajima, Takeaki; Migita, Shinji; Toriumi, Akira

    2016-09-01

    We report that nitrogen (N) doping can drive the ferroelectricity of HfO2. It was found that N doping can cause the transition from a monoclinic phase to a highly symmetric phase. The role of N doping is discussed from the viewpoints of charge balance and bond-constraining effects. The former is responsible for the structural transformation from a paraelectric phase to a ferroelectric phase by forming an oxygen vacancy. In addition, Hf-N and N-O bonds with covalent characteristics have strong effects on HfO2 structural and electrical properties, and thus contribute to a marked HfO2 para-/ferroelectric transition.

  5. Efficient noble metal nanocatalysts supported on HfC(001 for O2 dissociation

    Directory of Open Access Journals (Sweden)

    Shiyan Wang

    2017-03-01

    Full Text Available The adsorption and dissociation of O2 on the M4 (M=Au, Pd, Pt clusters supported on HfC(001 (Hafnium Carbide are investigated using ab initio density functional theory calculations. The geometric and electronic structures are analyzed in detail. It is found that the dissociation barriers of O2 on Au4/HfC(001 (0.26 eV, Pd4/HfC(001 (0.49 eV and Pt4/HfC(001 (0.09 eV are much smaller than those on the clean surfaces of HfC(001 (1.60 eV, Au(111 (1.37 eV, Pd(111 (1.0 and 0.91 eV and Pt(111 (0.27–0.7 eV, respectively. The low dissociation barriers imply that the Pt4/HfC(001 exhibits the highest catalytic activity for O2 dissociation, and the Au4/HfC(001 and Pd4/HfC(001 may also be possible substitutes with lower cost for the current Pt/C catalyst for O2 dissociation. The present study is conductive to designing new efficient noble metal catalyst using HfC support for efficiently promoting O2 dissociation.

  6. Efficient noble metal nanocatalysts supported on HfC(001) for O2 dissociation

    Science.gov (United States)

    Wang, Shiyan; Zhang, Xilin; Zhang, Yanxing; Mao, Jianjun; Yang, Zongxian

    2017-03-01

    The adsorption and dissociation of O2 on the M4 (M=Au, Pd, Pt) clusters supported on HfC(001) (Hafnium Carbide) are investigated using ab initio density functional theory calculations. The geometric and electronic structures are analyzed in detail. It is found that the dissociation barriers of O2 on Au4/HfC(001) (0.26 eV), Pd4/HfC(001) (0.49 eV) and Pt4/HfC(001) (0.09 eV) are much smaller than those on the clean surfaces of HfC(001) (1.60 eV), Au(111) (1.37 eV), Pd(111) (1.0 and 0.91 eV) and Pt(111) (0.27-0.7 eV), respectively. The low dissociation barriers imply that the Pt4/HfC(001) exhibits the highest catalytic activity for O2 dissociation, and the Au4/HfC(001) and Pd4/HfC(001) may also be possible substitutes with lower cost for the current Pt/C catalyst for O2 dissociation. The present study is conductive to designing new efficient noble metal catalyst using HfC support for efficiently promoting O2 dissociation.

  7. Study of Direct-Contact HfO2/Si Interfaces

    Directory of Open Access Journals (Sweden)

    Noriyuki Miyata

    2012-03-01

    Full Text Available Controlling monolayer Si oxide at the HfO2/Si interface is a challenging issue in scaling the equivalent oxide thickness of HfO2/Si gate stack structures. A concept that the author proposes to control the Si oxide interface by using ultra-high vacuum electron-beam HfO2 deposition is described in this review paper, which enables the so-called direct-contact HfO2/Si structures to be prepared. The electrical characteristics of the HfO2/Si metal-oxide-semiconductor capacitors are reviewed, which suggest a sufficiently low interface state density for the operation of metal-oxide-semiconductor field-effect-transistors (MOSFETs but reveal the formation of an unexpected strong interface dipole. Kelvin probe measurements of the HfO2/Si structures provide obvious evidence for the formation of dipoles at the HfO2/Si interfaces. The author proposes that one-monolayer Si-O bonds at the HfO2/Si interface naturally lead to a large potential difference, mainly due to the large dielectric constant of the HfO2. Dipole scattering is demonstrated to not be a major concern in the channel mobility of MOSFETs.

  8. Structural degradation of thin HfO2 film on Ge during the postdeposition annealing

    Science.gov (United States)

    Miyata, Noriyuki; Yasuda, Tetsuji; Abe, Yasuhiro

    2010-05-01

    Securing the thermal robustness of thin hafnium oxide (HfO2) film on the semiconductor surface is an important technical issue in the fabrication of the metal-oxide-semiconductor field-effect transistor devices, as the HfO2-based high-k gate stacks usually undergo high-temperature processes. In this study, the structural development of thin HfO2 film on a Ge surface during postdeposition annealing in an ultrahigh vacuum was examined to explore the origin for the initial degradation of thin HfO2 film. Void nucleation and subsequent two-dimensional void growth take place at 780-840 °C, while the chemical composition of the remaining Hf oxide is virtually stable. Both the void nucleation and growth processes show similar larger activation energy of about 10 eV. Based on the observed manner of void growth and the estimated activation energies, the authors propose that mass transport on the HfO2 surface is responsible for void nucleation in the HfO2 films on Ge. The authors also compare the present results with the previous studies on HfO2/Si structures, and suggest that similar surface process leads to the local Hf silicidation.

  9. The effect of Cu doping concentration on resistive switching of HfO{sub 2} film

    Energy Technology Data Exchange (ETDEWEB)

    Guo, Tingting; Tan, Tingting, E-mail: tantt@nwpu.edu.cn; Liu, Zhengtang

    2015-10-01

    Graphical abstract: - Highlights: • The Cu doped and undoped HfO{sub 2} films were fabricated. • The improved RS behaviors were observed for Cu doped HfO{sub 2} film with BRS. • The 9.7% doped HfO{sub 2}:Cu film showed both BRS and URS behaviors. • The related switching mechanisms were illustrated. - Abstract: The Cu-doped and undoped HfO{sub 2} films were fabricated and the effect of Cu doping concentration on resistive switching (RS) of HfO{sub 2} film was demonstrated. The X-ray photoelectron spectroscopy (XPS) was carried out to investigate the chemical bonding states of Cu in HfO{sub 2}:Cu film. The improved RS behaviors in terms of ON/OFF ratio and switching parameters were observed for Cu-doped HfO{sub 2} film with bipolar resistive switching (BRS) behavior. With the increase of Cu doping concentration, the 9.7% Cu-doped HfO{sub 2} film showed both BRS and unipolar resistive switching (URS) behaviors with large operating voltages. The space charge limited current (SCLC) effect was proposed to interpret the switching mechanism of HfO{sub 2}:Cu films with BRS behavior and the URS behavior can be explained by the migration of Cu ions.

  10. Lu-hf total-rock isochron for the eucrite meteorites

    Science.gov (United States)

    Patchett, P.J.; Tatsumoto, M.

    1980-01-01

    The isotope 176Lu (2.6% of natural lutetium) decays by ??- to 176Hf, with a long half life. We present here the first Lu-Hf isochron. The eucrite meteorites, a suite of planetary igneous rocks of known age, 4,550 Myr, define a 10-point total-rock isochron with a slope of 0.0934 ?? 40, leading to a value of 3.53 ?? 0.14 ??1010yr for the ??--decay half life of 176Lu. The isochron intercept of 0.27973 ?? 12 gives the initial 176Hf/177Hf for the inner Solar System at the time of accretion. ?? 1980 Nature Publishing Group.

  11. Chemical stability and defect formation in CaHfO3

    KAUST Repository

    Alay-E-Abbas, Syed Muhammad

    2014-04-01

    Defects in CaHfO3 are investigated by ab initio calculations based on density functional theory. Pristine and anion-deficient CaHfO 3 are found to be insulating, whereas cation-deficient CaHfO 3 is hole-doped. The formation energies of neutral and charged cation and anion vacancies are evaluated to determine the stability in different chemical environments. Moreover, the energies of the partial and full Schottky defect reactions are computed. We show that clustering of anion vacancies in the HfO layers is energetically favorable for sufficiently high defect concentrations and results in metallicity. © 2014 EPLA.

  12. Anticooperativity of FHF hydrogen bonds in clusters of the type F- × (HF)n, RF × (HF)n and XF × (HF)n, R = alkyl and X = H, Br, Cl, F

    Science.gov (United States)

    Kucherov, S. Yu.; Bureiko, S. F.; Denisov, G. S.

    2016-02-01

    Properties of twenty five hydrogen-bonded complexes, namely, F- × (HF)n (n = 1-6), RF × (HF)n (R = t-Bu, i-Pr, Et, Me; n = 1-3), XF × (HF)n (X = H, Br, Cl; n = 1-2), and FF…HF with the hydrogen bond energy varying in a wide range have been calculated using ab initio methods at the MP2/6-31++G** level. For the first time, the energies, geometrical parameters and vibrational frequencies are obtained for the series of clusters, where the bonding character changes from covalent to van der Waals on the variation of proton-acceptor ability of the base, and the energies are in the range of 45-1 kcal/mol. The mutual influence of multiple hydrogen bonds of F…HF type in clusters, in which a fluorine anion or an atom participates in hydrogen bond formation as the acceptor, is systematically investigated. The relative changes in the values of the considered parameters on the sequential addition of an HF molecule (anticooperativity) were determined. It was shown that non-additivity of the interaction is most strongly pronounced in the energy and vibrational frequency values, geometrical parameters of hydrogen bonds are less sensitive to the mutual influence. The anticooperative effect is more pronounced on the hydrogen bridge length R(F...F) than on the geometry of proton donor r(HF). The hydrogen bond formation and the increase of the number n of ligands lead to successive lengthening of the r(XF) bond adjacent to the hydrogen bridge. The length of an XF bond changes stronger on formation of each hydrogen bond than the HF bond length.

  13. Effects of Hf Incorporation on Negative Bias-Illumination Stress Stability in Hf-In-Zn-O Thin-Film Transistors

    Science.gov (United States)

    Kim, Sangwook; Park, Jae Chul; Kim, Dae Hwan; Lee, Jang-Sik

    2013-04-01

    In this study, highly reliable amorphous oxide semiconductor-based thin-film transistors (TFTs) were developed. The Hf concentration was systematically changed in the Hf-incorporated In-Zn-O (HIZO) TFTs, and Hf played an important role in determining the negative bias-illumination instability. The process parameters were optimized in order to obtain HIZO TFTs with an excellent stability. HIZO can be processed on a 6-in. wafer at low temperatures and is almost transparent in the visible range. Thus this material is promising for use in current TFTs as well as future transparent electronic device components with good electrical performance and excellent stability.

  14. Phase1 upgrade of the CMS-HF Calorimeter

    CERN Document Server

    Gulmez, Erhan

    2016-01-01

    In this presentation, results of the Phase I upgrade of the CMS Hadron Forward Calorimeter (HF) are discussed. The CMS-HF Calorimeter was using regular PMTs. Cherenkov light produced in the quartz fibers embedded in the iron absorber was read out with the PMTs. However, occasionally, stray muons hitting the PMT windows cause Cherenkov radiation in the PMT itself and produce large signals. These large signals mimic a very high-energy particle and are tagged as important by the trigger. To reduce this problem, PMTs had to be replaced. The four-anode PMTs that were chosen have thinner windows; thereby reducing the Cherenkov radiation in the PMT window. As part of the upgrade, the read-out electronics is to be replaced so that the PMTs are read out in two channels by connecting each pair of anodes to a single channel. Information provided by these two channels will help us reject the false signals due to the stray muons since the Cherenkov radiation in the PMT window is more likely to produce a signal only in one...

  15. Reversible spin texture in ferroelectric Hf O2

    Science.gov (United States)

    Tao, L. L.; Paudel, Tula R.; Kovalev, Alexey A.; Tsymbal, Evgeny Y.

    2017-06-01

    Spin-orbit coupling effects occurring in noncentrosymmetric materials are known to be responsible for nontrivial spin configurations and a number of emergent physical phenomena. Ferroelectric materials may be especially interesting in this regard due to reversible spontaneous polarization making possible a nonvolatile electrical control of the spin degrees of freedom. Here, we explore a technologically relevant oxide material, Hf O2 , which has been shown to exhibit robust ferroelectricity in a noncentrosymmetric orthorhombic phase. Using theoretical modelling based on density-functional theory, we investigate the spin-dependent electronic structure of the ferroelectric Hf O2 and demonstrate the appearance of chiral spin textures driven by spin-orbit coupling. We analyze these spin configurations in terms of the Rashba and Dresselhaus effects within the k .p Hamiltonian model and find that the Rashba-type spin texture dominates around the valence-band maximum, while the Dresselhaus-type spin texture prevails around the conduction band minimum. The latter is characterized by a very large Dresselhaus constant λD= 0.578 eV Å, which allows using this material as a tunnel barrier to produce tunneling anomalous and spin Hall effects that are reversible by ferroelectric polarization.

  16. Radiation effects in Zr and Hf containing garnets

    Energy Technology Data Exchange (ETDEWEB)

    Whittle, Karl R. [Institute of Materials Engineering, Australian Nuclear Science and Technology Organisation, PMB1, Menai, NSW 2234 (Australia); Department of Materials Science and Engineering, University of Sheffield, Mappin Street, Sheffield S1 3JD (United Kingdom); Blackford, Mark G.; Smith, Katherine L. [Institute of Materials Engineering, Australian Nuclear Science and Technology Organisation, PMB1, Menai, NSW 2234 (Australia); Zaluzec, Nestor J. [Argonne National Laboratory, 9700 South Cass Avenue, Argonne, IL 60439 (United States); Weyland, Matthew [Monash Centre for Electron Microscopy, Monash University, Victoria 3800 (Australia); Department of Materials Engineering, Monash University, Victoria 3800 (Australia); Lumpkin, Gregory R. [Institute of Materials Engineering, Australian Nuclear Science and Technology Organisation, PMB1, Menai, NSW 2234 (Australia)

    2015-07-15

    Garnets have been considered as host phases for the safe immobilisation of high-level nuclear waste, as they have been shown to accommodate a wide range of elements across three different cation sites, such as Ca, Y, Mn on the a-site, Fe, Al, U, Zr, and Ti on the b-site, and Si, Fe, Al on the c-site. Garnets, due to their ability to have variable composition, make ideal model materials for the examination of radiation damage and recovery in nuclear materials, including as potential waste forms. Kimzeyite, Ca{sub 3}Zr{sub 2}FeAlSiO{sub 12}, has been shown naturally to contain up to 30 wt% Zr, and has previously been examined to elucidate both the structure and ordering within the lattice. This study examines the effects of radiation damage and recovery using in-situ ion beam irradiation with 1 MeV Kr ions at the IVEM-TANDEM facility, Argonne National Laboratory. The complementary Hf containing system Ca{sub 3}Hf{sub 2}FeAlSiO{sub 12} was also examined, and found to have a different response to irradiation damage. A sample of irradiated Ca{sub 3}Zr{sub 2}FeAlSiO{sub 12}, at 1000 K, was characterised using aberration corrected (S)TEM and found to contain discreet, nano-sized, crystalline Fe rich particles, indicating a competing process during recovery is occurring.

  17. Interrogation zone determination in HF RFID systems with multiplexed antennas*

    Directory of Open Access Journals (Sweden)

    Jankowski-Mihułowicz Piotr

    2015-09-01

    Full Text Available The operation of an anti-collision RFID system is characterized by the interrogation zone which should be estimated in any direction of 3D space for a group of electronic transponders. The interrogation zone should be as large as possible. However, the many problems in this area are due to the fact that energy can be transferred to transponders only on a limited distance. The greatest flexibility in developing RFID applications and shaping the interrogation zone can be achieved using the system with an antenna multiplexer. Therefore the problem of the interrogation zone determination in HF RFID systems with two orthogonal RWD antennas is presented in the paper. The perceived issues have been effectively dealt with and the solution has been proposed on the basis of the elaborated model. Conducted studies have been used to develop the software tool JankoRFIDmuxHF in the Mathcad environment. The research results are analysed in an example system configuration. The specialized measuring stand has been used for experimental verification of the identification efficiency. The convergence of the measurements and calculations confirms a practical usefulness of the presented concept of interrogation zone determination in anti-collision systems. It also shows the practical utility of the developed model and software tools.

  18. The role of Upper Hybrid Turbulence on HF Artificial Ionization

    Science.gov (United States)

    Papadopoulos, Konstantinos Dennis; Najmi, Amir; Eliasson, Bengt; Milikh, Gennady

    2016-07-01

    One of the most fascinating and scientifically interesting phenomena of active space experiments is the discovery of artificial ionization by Todd Pedersen when the HAARP ERP reached the GW level. The phenomenon has been well documented experimentally. A theoretical model based on ionization by energetic electrons accelerated by 50-100 V/m localized electric fields due to Strong Langmuir Turbulence (SLT) near the reflection surface of the HF pump wave, reproduced the observed dynamics of the descending plasma layer quite accurately. A major defect of the model was that the electron temperature in the SLT region was a free parameter. When taken as the 2000 K representing the ambient electron temperature the SLT driven electron flux was insufficient to produce ionization. An equivalent electron temperature of 5000 K or higher was necessary to reproduce the observations. The needed electron heating was attributed to the interaction of the HF at the Upper Hybrid (UH) resonant layer, approximately 5 Km below the reflection region where the HF electric field is perpendicular to the ambient magnetic field. The heated electrons expanded upwards along the magnetic field line and interacted with SLT fields near the resonance region. A consequence of this defect was that the theory could not explain the puzzling double resonance effect. Namely the observation that the ionization level was much stronger when the HF frequency and the UH resonance were a multiple of the electron cyclotron frequency. To remedy this we used a series of Vlasov simulations to explore the HF-plasma interaction in the vicinity of the UH resonance. The simulations followed the evolution of the spectral density of the electric field over a 7.5 MHz frequency band and cm scale lengths and of the electron distribution function over one millisecond for both double resonant and non-resonant cases. Many new features were revealed by the analysis of the simulations such as: 1. Broadening of the wave

  19. Electron Microprobe Analysis of Hf in Zircon: Suggestions for Improved Accuracy of a Difficult Measurement

    Science.gov (United States)

    Fournelle, J.; Hanchar, J. M.

    2013-12-01

    It is not commonly recognized as such, but the accurate measurement of Hf in zircon is not a trivial analytical issue. This is important to assess because Hf is often used as an internal standard for trace element analyses of zircon by LA-ICPMS. The issues pertaining to accuracy revolve around: (1) whether the Hf Ma or the La line is used; (2) what accelerating voltage is applied if Zr La is also measured, and (3) what standard for Hf is used. Weidenbach, et al.'s (2004) study of the 91500 zircon demonstrated the spread (in accuracy) of possible EPMA values for six EPMA labs, 2 of which used Hf Ma, 3 used Hf La, and one used Hf Lb, and standards ranged from HfO2, a ZrO2-HfO2 compound, Hf metal, and hafnon. Weidenbach, et al., used the ID-TIMS values as the correct value (0.695 wt.% Hf.), for which not one of the EPMA labs came close to that value (3 were low and 3 were high). Those data suggest: (1) that there is a systematic underestimation error of the 0.695 wt% Hf (ID-TIMS Hf) value if Hf Ma is used; most likely an issue with the matrix correction, as the analytical lines and absorption edges of Zr La, Si Ka and Hf Ma are rather tightly packed in the electromagnetic spectrum. Mass absorption coefficients are easily in error (e.g., Donovan's determination of the MAC of Hf by Si Ka of 5061 differs from the typically used Henke value of 5449 (Donovan et al, 2002); and (2) For utilization of the Hf La line, however, the second order Zr Ka line interferes with Hf La if the accelerating voltage is greater than 17.99 keV. If this higher keV is used and differential mode PHA is applied, only a portion of the interference is removed (e.g., removal of escape peaks), causing an overestimation of Hf content. Unfortunately, it is virtually impossible to apply an interference correction in this case, as it is impossible to locate Hf-free Zr probe standard. We have examined many of the combinations used by those six EPMA labs and concluded that the optimal EPMA is done with Hf

  20. Atomic scale engineering of HfO{sub 2}-based dielectrics for future DRAM applications

    Energy Technology Data Exchange (ETDEWEB)

    Dudek, Piotr

    2011-02-14

    Modern dielectrics in combination with appropriate metal electrodes have a great potential to solve many difficulties associated with continuing miniaturization process in the microelectronic industry. One significant branch of microelectronics incorporates dynamic random access memory (DRAM) market. The DRAM devices scaled for over 35 years starting from 4 kb density to several Gb nowadays. The scaling process led to the dielectric material thickness reduction, resulting in higher leakage current density, and as a consequence higher power consumption. As a possible solution for this problem, alternative dielectric materials with improved electrical and material science parameters were intensively studied by many research groups. The higher dielectric constant allows the use of physically thicker layers with high capacitance but strongly reduced leakage current density. This work focused on deposition and characterization of thin insulating layers. The material engineering process was based on Si cleanroom compatible HfO{sub 2} thin films deposited on TiN metal electrodes. A combined materials science and dielectric characterization study showed that Ba-added HfO{sub 2} (BaHfO{sub 3}) films and Ti-added BaHfO{sub 3} (BaHf{sub 0.5}Ti{sub 0.5}O{sub 3}) layers are promising candidates for future generation of state-of-the-art DRAMs. In especial a strong increase of the dielectric permittivity k was achieved for thin films of cubic BaHfO{sub 3} (k{proportional_to}38) and BaHf{sub 0.5}Ti{sub 0.5}O{sub 3} (k{proportional_to}90) with respect to monoclinic HfO{sub 2} (k{proportional_to}19). Meanwhile the CET values scaled down to 1 nm for BaHfO{sub 3} and {proportional_to}0.8 nm for BaHf{sub 0.5}Ti{sub 0.5}O{sub 3} with respect to HfO{sub 2} (CET=1.5 nm). The Hf{sup 4+} ions substitution in BaHfO{sub 3} by Ti{sup 4+} ions led to a significant decrease of thermal budget from 900 C for BaHfO{sub 3} to 700 C for BaHf{sub 0.5}Ti{sub 0.5}O{sub 3}. Future studies need to focus

  1. Evolution of continental crust and mantle heterogeneity: Evidence from Hf isotopes

    Science.gov (United States)

    Jonathan, Patchett P.; Kouvo, O.; Hedge, C.E.; Tatsumoto, M.

    1982-01-01

    We present initial 176Hf/177 Hf ratios for many samples of continental crust 3.7-0.3 Gy old. Results are based chiefly on zircons (1% Hf) and whole rocks: zircons are shown to be reliable carriers of essentially the initial Hf itself when properly chosen on the basis of U-Pb studies. Pre-3.0 Gy gneisses were apparently derived from an unfractionated mantle, but both depleted and undepleted mantle are evident as magma sources from 2.9 Gy to present. This mantle was sampled mainly from major crustal growth episodes 2.8, 1.8 and 0.7 Gy ago, all of which show gross heterogeneity of 176Hf/177Hf in magma sources from ??Hf=0 to +14, or about 60% of the variability of the present mantle. The approximate ??Hf=2??Nd relationship in ancient and modern igneous rocks shows that 176Lu/177Hf fractionates in general twice as much as 147Sm/144Nd in mantle melting processes. This allows an estimation of the relative value of the unknown bulk solid/liquid distribution coefficient for Hf. DLu/DHf=??? 2.3 holds for most mantle source regions. For garnet to be an important residual mantle phase, it must hold Hf strongly in order to preserve Hf-Nd isotopic relationships. The ancient Hf initials are consistent with only a small proportion of recycled older cratons in new continental crust, and with quasi-continuous, episodic growth of the continental crust with time. However, recycling of crust less than 150 My old cannot realistically be detected using Hf initials. The mantle shows clearly the general positive ??Hf resulting from a residual geochemical state at least back to 2.9 Gy ago, and seems to have repeatedly possessed a similar degree of heterogeneity, rather than a continuously-developing depletion. This is consistent with a complex dynamic disequilibrium model for the creation, maintenance and destruction of heterogeneity in the mantle. ?? 1981 Springer-Verlag.

  2. What Hf isotopes in zircon tell us about crust-mantle evolution

    Science.gov (United States)

    Iizuka, Tsuyoshi; Yamaguchi, Takao; Itano, Keita; Hibiya, Yuki; Suzuki, Kazue

    2017-03-01

    The 176Lu-176Hf radioactive decay system has been widely used to study planetary crust-mantle differentiation. Of considerable utility in this regard is zircon, a resistant mineral that can be precisely dated by the U-Pb chronometer and record its initial Hf isotope composition due to having low Lu/Hf. Here we review zircon U-Pb age and Hf isotopic data mainly obtained over the last two decades and discuss their contributions to our current understanding of crust-mantle evolution, with emphasis on the Lu-Hf isotope composition of the bulk silicate Earth (BSE), early differentiation of the silicate Earth, and the evolution of the continental crust over geologic history. Meteorite zircon encapsulates the most primitive Hf isotope composition of our solar system, which was used to identify chondritic meteorites best representative of the BSE (176Hf/177Hf = 0.282793 ± 0.000011; 176Lu/177Hf = 0.0338 ± 0.0001). Hadean-Eoarchean detrital zircons yield highly unradiogenic Hf isotope compositions relative to the BSE, providing evidence for the development of a geochemically enriched silicate reservoir as early as 4.5 Ga. By combining the Hf and O isotope systematics, we propose that the early enriched silicate reservoir has resided at depth within the Earth rather than near the surface and may represent a fractionated residuum of a magma ocean underlying the proto-crust, like urKREEP beneath the anorthositic crust on the Moon. Detrital zircons from world major rivers potentially provide the most robust Hf isotope record of the preserved granitoid crust on a continental scale, whereas mafic rocks with various emplacement ages offer an opportunity to trace the Hf isotope evolution of juvenile continental crust (from εHf[4.5 Ga] = 0 to εHf[present] = + 13). The river zircon data as compared to the juvenile crust composition highlight that the supercontinent cycle has controlled the evolution of the continental crust by regulating the rates of crustal generation and intra

  3. Influence of Hf contents on interface state properties in a-HfInZnO thin-film transistors with SiNx/SiOx gate dielectrics

    Science.gov (United States)

    Choi, Hyun-Sik; Jeon, Sanghun; Kim, Hojung; Shin, Jaikwang; Kim, Changjung; Chung, U.-In

    2011-10-01

    We evaluated the interface properties of amorphous hafnium-indium-zinc-oxide (a-HIZO) thin-film transistors (TFTs) with respect to various Hf contents. To this end, the subthreshold swing and the low-frequency noise (LFN) of the a-HIZO TFTs were measured and compared. From LFNs providing more accurate information, we quantitatively analyzed the interface trap densities and found that they decrease with increasing Hf contents. Although the acceptor-like tail state densities in bulk channel increase with Hf contents, higher Hf contents show lower threshold voltage shift under bias stress, implying that reliability characteristics of a-HIZO TFTs are more sensitive to interface quality rather than bulk property.

  4. Distribution of p-process 174Hf in early solar system materials and the origin of nucleosynthetic Hf and W isotope anomalies in Ca-Al rich inclusions

    Science.gov (United States)

    Peters, Stefan T. M.; Münker, Carsten; Pfeifer, Markus; Elfers, Bo-Magnus; Sprung, Peter

    2017-02-01

    Some nuclides that were produced in supernovae are heterogeneously distributed between different meteoritic materials. In some cases these heterogeneities have been interpreted as the result of interaction between ejecta from a nearby supernova and the nascent solar system. Particularly in the case of the oldest objects that formed in the solar system - Ca-Al rich inclusions (CAIs) - this view is confirm the hypothesis that a nearby supernova event facilitated or even triggered solar system formation. We present Hf isotope data for bulk meteorites, terrestrial materials and CAIs, for the first time including the low-abundance isotope 174Hf (∼0.16%). This rare isotope was likely produced during explosive O/Ne shell burning in massive stars (i.e., the classical "p-process"), and therefore its abundance potentially provides a sensitive tracer for putative heterogeneities within the solar system that were introduced by supernova ejecta. For CAIs and one LL chondrite, also complementary W isotope data are reported for the same sample cuts. Once corrected for small neutron capture effects, different chondrite groups, eucrites, a silicate inclusion of a IAB iron meteorite, and terrestrial materials display homogeneous Hf isotope compositions including 174Hf. Hafnium-174 was thus uniformly distributed in the inner solar system when planetesimals formed at the system composition, and also variable r-process (or s-process) Hf and W contributions. Based on combined Hf and W isotope compositions, we show that CAIs sampled at least one component in which the proportion of r- and s-process derived Hf and W deviates from that of supernova ejecta. The Hf and W isotope anomalies in CAIs are therefore best explained by selective processing of presolar carrier phases prior to CAI formation, and not by a late injection of supernova materials. Likewise, other isotope anomalies in additional elements in CAIs relative to the bulk solar system may reflect the same process. The isotopic

  5. Air sensitivity of MoS2, MoSe2, MoTe2, HfS2, and HfSe2

    Science.gov (United States)

    Mirabelli, Gioele; McGeough, Conor; Schmidt, Michael; McCarthy, Eoin K.; Monaghan, Scott; Povey, Ian M.; McCarthy, Melissa; Gity, Farzan; Nagle, Roger; Hughes, Greg; Cafolla, Attilio; Hurley, Paul K.; Duffy, Ray

    2016-09-01

    A surface sensitivity study was performed on different transition-metal dichalcogenides (TMDs) under ambient conditions in order to understand which material is the most suitable for future device applications. Initially, Atomic Force Microscopy and Scanning Electron Microscopy studies were carried out over a period of 27 days on mechanically exfoliated flakes of 5 different TMDs, namely, MoS2, MoSe2, MoTe2, HfS2, and HfSe2. The most reactive were MoTe2 and HfSe2. HfSe2, in particular, showed surface protrusions after ambient exposure, reaching a height and width of approximately 60 nm after a single day. This study was later supplemented by Transmission Electron Microscopy (TEM) cross-sectional analysis, which showed hemispherical-shaped surface blisters that are amorphous in nature, approximately 180-240 nm tall and 420-540 nm wide, after 5 months of air exposure, as well as surface deformation in regions between these structures, related to surface oxidation. An X-ray photoelectron spectroscopy study of atmosphere exposed HfSe2 was conducted over various time scales, which indicated that the Hf undergoes a preferential reaction with oxygen as compared to the Se. Energy-Dispersive X-Ray Spectroscopy showed that the blisters are Se-rich; thus, it is theorised that HfO2 forms when the HfSe2 reacts in ambient, which in turn causes the Se atoms to be aggregated at the surface in the form of blisters. Overall, it is evident that air contact drastically affects the structural properties of TMD materials. This issue poses one of the biggest challenges for future TMD-based devices and technologies.

  6. EURObservational Research Programme : The Heart Failure Pilot Survey (ESC-HF Pilot)

    NARCIS (Netherlands)

    Maggioni, Aldo P.; Dahlstrom, Ulf; Filippatos, Gerasimos; Chioncel, Ovidiu; Crespo Leiro, Marisa; Drozdz, Jaroslaw; Fruhwald, Friedrich; Gullestad, Lars; Logeart, Damien; Metra, Marco; Parissis, John; Persson, Hans; Ponikowski, Piotr; Rauchhaus, Mathias; Voors, Adriaan A.; Nielsen, Olav Wendelboe; Zannad, Faiez; Tavazzi, Luigi

    2010-01-01

    The primary objective of the new ESC-HF Pilot Survey was to describe the clinical epidemiology of outpatients and inpatients with heart failure (HF) and the diagnostic/therapeutic processes applied across 12 participating European countries. This pilot study was specifically aimed at validating the

  7. EURObservational Research Programme: the Heart Failure Pilot Survey (ESC-HF Pilot)

    DEFF Research Database (Denmark)

    Maggioni, Aldo P; Dahlström, Ulf; Filippatos, Gerasimos;

    2010-01-01

    The primary objective of the new ESC-HF Pilot Survey was to describe the clinical epidemiology of outpatients and inpatients with heart failure (HF) and the diagnostic/therapeutic processes applied across 12 participating European countries. This pilot study was specifically aimed at validating...... the structure, performance, and quality of the data set, for continuing the survey into a permanent registry....

  8. Effects of sol aging on resistive switching behaviors of HfO{sub x} resistive memories

    Energy Technology Data Exchange (ETDEWEB)

    Hsu, Chih-Chieh, E-mail: cchsu@yuntech.edu.tw [Graduate School of Engineering Science and Technology, National Yunlin University of Science and Technology, Douliu 64002, Taiwan, ROC (China); Department of Electronic Engineering, National Yunlin University of Science and Technology, Douliu 64002, Taiwan, ROC (China); Graduate School of Electronic Engineering, National Yunlin University of Science and Technology, Douliu 64002, Taiwan, ROC (China); Sun, Jhen-Kai; Tsao, Che-Chang; Chen, Yu-Ting [Graduate School of Electronic Engineering, National Yunlin University of Science and Technology, Douliu 64002, Taiwan, ROC (China)

    2017-03-01

    This work investigates effects of long-term sol-aging time on sol-gel HfO{sub x} resistive random access memories (RRAMs). A nontoxic solvent of ethanol is used to replace toxic 2-methoxyethanol, which is usually used in sol-gel processes. The top electrodes are fabricated by pressing indium balls onto the HfO{sub x} surface rather than by using conventional sputtering or evaporation processes. The maximum process temperature is limited to be 100 ℃. Therefore, influences of plasma and high temperature on HfO{sub x} film can be avoided. Under this circumstance, effects of sol aging time on the HfO{sub x} films can be more clearly studied. The current conduction mechanisms in low and high electric regions of the HfO{sub x} RRAM are found to be dominated by Ohmic conduction and trap-filled space charge limited conduction (TF-SCLC), respectively. When the sol aging time increases, the resistive switching characteristic of the HfO{sub x} layer becomes unstable and the transition voltage from Ohmic conduction to TF-SCLC is also increased. This suggests that an exceedingly long aging time will give a HfO{sub x} film with more defect states. The XPS results are consistent with FTIR analysis and they can further explain the unstable HfO{sub x} resistive switching characteristic induced by sol aging.

  9. The effects of composition on mechanical properties of W-4Re-Hf-C alloys

    Science.gov (United States)

    Witzke, W. R.

    1974-01-01

    Studies were made of the effects of alloy composition on the mechanical behavior of as-worked W-4Re-Hf-C alloys containing up to about 0.8 mol % Hfc. Extracted second-phase particles were analyzed and related to alloy composition and creep strength. While strengthening is attributed to HfC particles, the presence of excess hafnium or carbon (above the calculated amounts for stoichiometric HfC) in swaged W-4Re-Hf-C alloys generally causes a reduction of the high-temperature (1930 C) tensile strength; maximum creep strength is, however, indicated for alloys with a slight (about 0.05 to 0.1 at. %) excess of hafnium. Particle strengthening is reduced by WC in solid solution with HfC for allow compositions with an excess of carbon. The low-temperature ductility of worked W-4Re-Hf-C alloys appears to be far more dependent on the amount of excess C or Hf present than on the HfC particle content in the range studies.

  10. First results on the sorption behaviour of Rutherfordium from HCl/HF containing aqueous solution

    Energy Technology Data Exchange (ETDEWEB)

    Schumann, D.; Nitsche, H. [Technische Univ. Dresden (Germany); Taut, S. [Forschungszentrum Rossendorf e.V. (FZR), Dresden (Germany); Jost, D.T.; Gaeggeler, H.W. [Paul Scherrer Inst. (PSI), Villigen (Switzerland); Yakushev, A.B.; Buklanov, G.V.; Domanov, V.P.; Lien Din Thi [Joint Inst. for Nuclear Research, Dubna (Russian Federation); Kubica, B.; Misiak, R.; Szeglowski, Z. [NINP Cracow (Poland)

    1997-09-01

    Rutherfordium shows strong sorption on the cation exchanger DOWEX 50x8 at a concentration of 0.1 M HCl/10{sup -2} M HF. This shows that Rf behaves under these conditions differently from Hf and Zr and more like Th under these conditions. (author) 1 fig., 5 refs.

  11. Effects of sol aging on resistive switching behaviors of HfOx resistive memories

    Science.gov (United States)

    Hsu, Chih-Chieh; Sun, Jhen-Kai; Tsao, Che-Chang; Chen, Yu-Ting

    2017-03-01

    This work investigates effects of long-term sol-aging time on sol-gel HfOx resistive random access memories (RRAMs). A nontoxic solvent of ethanol is used to replace toxic 2-methoxyethanol, which is usually used in sol-gel processes. The top electrodes are fabricated by pressing indium balls onto the HfOx surface rather than by using conventional sputtering or evaporation processes. The maximum process temperature is limited to be 100 ℃. Therefore, influences of plasma and high temperature on HfOx film can be avoided. Under this circumstance, effects of sol aging time on the HfOx films can be more clearly studied. The current conduction mechanisms in low and high electric regions of the HfOx RRAM are found to be dominated by Ohmic conduction and trap-filled space charge limited conduction (TF-SCLC), respectively. When the sol aging time increases, the resistive switching characteristic of the HfOx layer becomes unstable and the transition voltage from Ohmic conduction to TF-SCLC is also increased. This suggests that an exceedingly long aging time will give a HfOx film with more defect states. The XPS results are consistent with FTIR analysis and they can further explain the unstable HfOx resistive switching characteristic induced by sol aging.

  12. The Modulation of Ionospheric Alfven Resonator on Heating HF Waves and the Doppler Effect

    Institute of Scientific and Technical Information of China (English)

    NiBin-bin; ZhaoZheng-yu; XieShu-guo

    2003-01-01

    The propagation of HF waves in IAR can produce many nonlinear effects, including the modulation effect of IAR on HF waves and the Doppler effect. To start with the dependence of the ionospheric electron temperature varia-tions on the Alfven resonant field, We discuss the mechanism of the modulation effect and lucubrate possible reasons for the Doppler effect. The results show that the Alfven resonant field can have an observable modulation effect on HF waves while its mechanism is quite different from that of Schumann resonant field on HF waves. The depth of modulation of IAR on HF waves has a quasi-quadratic relation with the Alfven field, which directly inspires the formation of cross-spectrum between ULF waves and HF waves and results in spectral peaks at some gyro-frequencies of IAR. With respect to the Doppler effect during the propagation of HF waves in IAR, it is mainly caused by the motion of the high-speed flyer and the drifting electrons and the frequency shift from the phase vari-ation of the reflected waves can be neglected when the frequency of HF incident wave is high enough.

  13. New PWM method and commutation strategy for HF-link converters for fuel cells and photovoltaics

    DEFF Research Database (Denmark)

    Ljusev, Petar; Andersen, Michael Andreas E.

    2005-01-01

    This paper presents a new PWM method and commutation strategy for HF-link converters, which leads to safe commutation of the load current in the output bidirectional bridge. The proposed implementation is independent of the particular HF-link converter topology and bidirectional switch selection...

  14. The first HF table, after heat treatment and ready to be machined in HEPCO, Arak (IRAN)

    CERN Multimedia

    Tiziano Camporesi

    2003-01-01

    The first HF support table 'load' tested by the team of people who have contributed to it from design to welding. This table will support the 240 tons of 1 HF detector and will integrate the raisers which will push it up to the beam line level. It is the first Iranian contribution to an HEP experiment.

  15. 47 CFR 73.758 - System specifications for digitally modulated emissions in the HF broadcasting service.

    Science.gov (United States)

    2010-10-01

    ... emissions in the HF broadcasting service. 73.758 Section 73.758 Telecommunication FEDERAL COMMUNICATIONS... § 73.758 System specifications for digitally modulated emissions in the HF broadcasting service. (a... digital audio broadcasting and datacasting are authorized. The RF requirements for the DRM system...

  16. Computed tomographic coronary angiography for patients with heart failure (CTA-HF): a randomized controlled trial (IMAGE HF Project 1-C).

    Science.gov (United States)

    Chow, Benjamin J W; Green, Rachel E; Coyle, Doug; Laine, Mika; Hanninen, Helena; Leskinen, Hanna; Rajda, Miroslav; Larose, Eric; Hartikainen, Juha; Hedman, Marja; Mielniczuk, Lisa; O'Meara, Eileen; deKemp, Robert A; Klein, Ran; Paterson, Ian; White, James A; Yla-Herttuala, Seppo; Leber, Alex; Tandon, Vikas; Lee, Ting; Al-Hesayen, Abdul; Hessian, Renee; Dowsley, Taylor; Kass, Malek; Kelly, Cathy; Garrard, Linda; Tardif, Jean-Claude; Knuuti, Juhani; Beanlands, Rob S; Wells, George A

    2013-12-26

    The prevalence of heart failure (HF) is rising in industrialized and developing countries. Though invasive coronary angiography (ICA) remains the gold standard for anatomical assessment of coronary artery disease in HF patients, alternatives are being sought. Computed tomographic coronary angiography (CTA) has emerged as an accurate non-invasive diagnostic tool for coronary artery disease (CAD) and has been demonstrated to have prognostic value. Whether or not CTA can be used in HF patients is unknown. Acknowledging the aging population, the growing prevalence of HF and the increasing financial burden of healthcare, we need to identify non-invasive diagnostic tests that are available, safe, accurate and cost-effective. The proposed study aims to provide insight into the efficacy of CTA in HF patients. A multicenter randomized controlled trial will enroll 250 HF patients requiring coronary anatomical definition. Enrolled patients will be randomized to either CTA or ICA (n = 125 per group) as the first test to define coronary anatomy. The primary outcomes will be collected to determine downstream resource utilization. Secondary outcomes will include the composite clinical events and major adverse cardiac events. In addition, the accuracy of CTA for detecting coronary anatomy and obstruction will be assessed in patients who subsequently undergo both CTA and ICA. It is expected that CTA will be a more cost-effective strategy for diagnosis: yielding similar outcomes with fewer procedural risks and improved resource utilization. ClinicalTrials.gov, NCT01283659. Team grant #CIF 99470.

  17. Signal processing technique for randomly discontinuous spectra HF radar waveforms

    Institute of Scientific and Technical Information of China (English)

    张东坡; 刘兴钊

    2004-01-01

    A major problem with all high frequency (HF) radars is a relatively poor range resolution available due to many interference sources. To avoid the interferences in frequency domain and operate with wideband, the randomly discontinuous spectra (RDS) signal is employed. However, it results in high range sidelobes when matching the reflected echo, which is much more difficult for target detection. A new signal processing technique that is radically different from the conventional technique to lower range sidelobes is introduced. This method is based on suppressing the selfclutter of the radar range ambiguity function (AF) by mismatched filtering. An effective algorithm is adopted to solve the filter coefficients. Simulation results show that the peak sidelobe level can be reduced to -30dB and the achievable system bandwidth is about 400KHz. The technique is adaptable to practical radar systems and applicable for other realtime signal processing.

  18. Modification of polarization filtering technique in HF ground wave radar

    Institute of Scientific and Technical Information of China (English)

    Zhang Guoyi; Tan Zhongji; Wang Jiantao

    2006-01-01

    The polarization filter using three orthogonal linear polarization antennas can suppress more disturbances than the polarization filter using two orthogonal linear polarization antennas in HF ground wave radar. But the algorithm of the threedimension filter is relatively complicated and not suitable for real-time processing. It can't use linear and nonlinear polarization vector translation technique directly. A modified polarization filter which is simple and has same suppressing ability as the three-dimension polarization filter is given. It only has half parameters of the primary one. Some problems about estimation of polarization parameters and selection of disturbances are discussed. A method of holding the phase of radar backscatter signal constantly is put forward so that unstationary disturbance signal can be processed.

  19. Toward an european Med HF-radar coastal monitoring

    Science.gov (United States)

    Molcard, A.; Fraunie, P.

    2010-12-01

    The monitoring of coastal areas through HF radar is developping in the european Mediterranean coasts, through national and international projects. Surface current maps may be used for process studies, forecast correction through assimilation, or for practical applications in transport studies (jellyfish, oil-spill, search-and-rescue operations). Results of radar campaigns in the North-western Mediterranean (evidence of mesoscale eddy in the Gulf of Lions and identification of dynamical structures by FSLE in the Ligurian Sea) are shown, as well as techniques for current reconstruction using a single site. A new inter-regional european project started in summer 2010, regrouping 5 countries for an integrated oil-spill coastal awarness network is presented.

  20. Telemonitoring Adherence to Medications in Heart Failure Patients (TEAM-HF): A Pilot Randomized Clinical Trial.

    Science.gov (United States)

    Gallagher, Benjamin D; Moise, Nathalie; Haerizadeh, Mytra; Ye, Siqin; Medina, Vivian; Kronish, Ian M

    2017-04-01

    Medication nonadherence contributes to hospitalizations in recently discharged patients with heart failure (HF). We aimed to test the feasibility of telemonitoring medication adherence in patients with HF. We randomized 40 patients (1:1) hospitalized for HF to 30 days of loop diuretic adherence monitoring with telephonic support or to passive adherence monitoring alone. Eighty-three percent of eligible patients agreed to participate. The median age of patients was 64 years, 25% were female, and 45% were Hispanic. Overall, 67% of patients were nonadherent (percentage of days that the correct number of doses were taken telemonitoring was acceptable to most patients with HF. Diuretic nonadherence was common even when patients knew they were being monitored. Future studies should assess whether adherence telemonitoring can improve adherence and reduce readmissions among patients with HF. Copyright © 2016 Elsevier Inc. All rights reserved.

  1. The electronic structure of HfF5- and WF5-

    Science.gov (United States)

    Chen, Hongshan; Andersson, Pontus; Lindahl, Anton O.; Hanstorp, Dag

    2011-08-01

    The electronic structure of HfF5-, WF5- and the related species HfF n and WF n is studied using ab initio methods. Computation reveals that the hafnium fluorides are much more stable than the corresponding tungsten fluorides. The detachment energy of HfF5- is 8.8 eV, whereas the corresponding quantity of WF5- is only 3.9 eV. These results show that WF5- can be photodetached while HfF5- is unaffected, and so it is possible by using photodetachment to suppress the interfering isobar 182W in the ion beam of 182Hf. Such information is the precondition for the successful implementation of a future photodetachment process in Accelerator Mass Spectrometry.

  2. Effect of hydrofluoric acid (HF) concentration to pores size diameter of silicon membrane.

    Science.gov (United States)

    Burham, Norhafizah; Hamzah, Azrul Azlan; Majlis, Burhanuddin Yeop

    2014-01-01

    This paper studies parameters which affect the pore size diameter of a silicon membrane. Electrochemical etching is performed in characterise the parameter involved in this process. The parameter has been studied is volume ratio of hydrofluoric acid (HF) and ethanol as an electrolyte aqueous for electrochemical etch. This electrolyte aqueous solution has been mixed between HF and ethanol with volume ratio 3:7, 5:5, 7:3 and 9:1. As a result, the higher volume of HF in this electrolyte gives the smallest pore size diameter compared to the lower volume of HF. These samples have been dipped into HF and ethanol electrolyte aqueous with supplied 25 mA/cm2 current density for 20, 30, 40, and 50 minutes. The samples will inspect under Scanning Electron Microscope (SEM) to execute the pore formations on silicon membrane surface.

  3. Suspended HfO{sub 2} photonic crystal slab on III-nitride/Si platform

    Energy Technology Data Exchange (ETDEWEB)

    Wang, Yongjin; Feng, Jiao; Cao, Ziping; Zhu, Hongbo [Nanjing University of Posts and Telecommunications, Grueenberg Research Centre, Nanjing, Jiang-Su (China)

    2014-06-15

    We present here the fabrication of suspended hafnium oxide (HfO{sub 2}) photonic crystal slab on a III-nitride/Si platform. The calculations are performed to model the suspended HfO{sub 2} photonic crystal slab. Aluminum nitride (AlN) film is employed as the sacrificial layer to form air gap. Photonic crystal patterns are defined by electron beam lithography and transferred into HfO{sub 2} film, and suspended HfO{sub 2} photonic crystal slab is achieved on a III-nitride/Si platform through wet-etching of AlN layer in the alkaline solution. The method is promising for the fabrication of suspended HfO{sub 2} nanostructures incorporating into a III-nitride/Si platform, or acting as the template for epitaxial growth of III-nitride materials. (orig.)

  4. Crystal structure of Si-doped HfO{sub 2}

    Energy Technology Data Exchange (ETDEWEB)

    Zhao, Lili [Department of Materials Science and Engineering, North Carolina State University, Raleigh, North Carolina 27695 (United States); School of Information Science and Technology, Northwest University, Xi' an 710127 (China); Department of Materials Science and Engineering, University of Florida, Gainesville, Florida 32611 (United States); Nelson, Matthew; Fancher, Chris M. [Department of Materials Science and Engineering, North Carolina State University, Raleigh, North Carolina 27695 (United States); Aldridge, Henry [Department of Materials Science and Engineering, University of Florida, Gainesville, Florida 32611 (United States); Iamsasri, Thanakorn; Forrester, Jennifer S.; Jones, Jacob L., E-mail: jacobjones@ncsu.edu [Department of Materials Science and Engineering, North Carolina State University, Raleigh, North Carolina 27695 (United States); Department of Materials Science and Engineering, University of Florida, Gainesville, Florida 32611 (United States); Nishida, Toshikazu [Department of Electrical and Computer Engineering, University of Florida, Gainesville, Florida 32611 (United States); Moghaddam, Saeed [Department of Mechanical and Aerospace Engineering, University of Florida, Gainesville, Florida 32611 (United States)

    2014-01-21

    Si-doped HfO{sub 2} was prepared by solid state synthesis of the starting oxides. Using Rietveld refinement of high resolution X-ray diffraction patterns, a substitutional limit of Si in HfO{sub 2} was determined as less than 9 at. %. A second phase was identified as Cristobalite (SiO{sub 2}) rather than HfSiO{sub 4}, the latter of which would be expected from existing SiO{sub 2}-HfO{sub 2} phase diagrams. Crystallographic refinement with increased Si-dopant concentration in monoclinic HfO{sub 2} shows that c/b increases, while β decreases. The spontaneous strain, which characterizes the ferroelastic distortion of the unit cell, was calculated and shown to decrease with increasing Si substitution.

  5. Tsunami Arrival Detection with High Frequency (HF Radar

    Directory of Open Access Journals (Sweden)

    Donald Barrick

    2012-05-01

    Full Text Available Quantitative real-time observations of a tsunami have been limited to deep-water, pressure-sensor observations of changes in the sea surface elevation and observations of sea level fluctuations at the coast, which are essentially point measurements. Constrained by these data, models have been used for predictions and warning of the arrival of a tsunami, but to date no system exists for local detection of an actual incoming wave with a significant warning capability. Networks of coastal high frequency (HF-radars are now routinely observing surface currents in many countries. We report here on an empirical method for the detection of the initial arrival of a tsunami, and demonstrate its use with results from data measured by fourteen HF radar sites in Japan and USA following the magnitude 9.0 earthquake off Sendai, Japan, on 11 March 2011. The distance offshore at which the tsunami can be detected, and hence the warning time provided, depends on the bathymetry: the wider the shallow continental shelf, the greater this time. We compare arrival times at the radars with those measured by neighboring tide gauges. Arrival times measured by the radars preceded those at neighboring tide gauges by an average of 19 min (Japan and 15 min (USA The initial water-height increase due to the tsunami as measured by the tide gauges was moderate, ranging from 0.3 to 2 m. Thus it appears possible to detect even moderate tsunamis using this method. Larger tsunamis could obviously be detected further from the coast. We find that tsunami arrival within the radar coverage area can be announced 8 min (i.e., twice the radar spectral time resolution after its first appearance. This can provide advance warning of the tsunami approach to the coastline locations.

  6. New Adaptive Data Transmission Scheme Over HF Radio

    Directory of Open Access Journals (Sweden)

    Adil H. Ahmad

    2008-01-01

    Full Text Available Acceptable Bit Error rate can be maintained by adapting some of the design parameters such as modulation, symbol rate, constellation size, and transmit power according to the channel state.An estimate of HF propagation effects can be used to design an adaptive data transmission system over HF link. The proposed system combines the well known Automatic Link Establishment (ALE together with variable rate transmission system. The standard ALE is modified to suite the required goal of selecting the best carrier frequency (channel for a given transmission. This is based on measuring SINAD (Signal plus Noise plus Distortion to Noise plus Distortion, RSL (Received Signal Level, multipath phase distortion and BER (Bit Error Rate for each channel in the frequency list. Channel condition evaluation is done by two arrangements. In the first an FFT analysis is used where a pilot signal is transmitted over the channel, while the data itself is used in the second arrangement. Passive channel assessment is used to avoid bad channels hence limiting the frequency pool size to be used in the point to point communication and the time required for scanning and linking. An exchange of channel information between the transmitting and receiving stations is considered to select the modulation scheme for transmission. Mainly MPSK and MFSK are considered with different levels giving different data rate according to the channel condition. The results of the computer simulation have shown that when transmitting at a fixed channel symbol rate of 1200 symbol/sec, the information rate ranges from 2400 bps using 4FSK up to 3600 bps using 8PSK for SNR ranges from 11dB up to 26dB.

  7. The Thermodynamic Characterization of ZrCo–H, HfCo−H, HfNi−H and Zr{sub 1–x}HfxNi(Co) Alloy–H Systems

    Energy Technology Data Exchange (ETDEWEB)

    Flanagan, Ted B., E-mail: ted.flanagan@uvm.edu; Noh, Hak; Luo, Suifang

    2016-08-25

    ZrCo and HfCo intermetallic compounds have the same cubic (CsCl-type) structure and their ternary (Zr{sub 1−x}Hf{sub x})Co alloys are also cubic. ZrNi and HfNi intermetallic compounds have the orthorhombic structure (CrB-type) and the ternary (Zr{sub 1−x}Hf{sub x})Ni alloys also have this structure. Thermodynamic data for hydride formation and decomposition in ZrCo, HfCo and HfNi intermetallic compounds have been determined from reaction calorimetry and from pressure-composition isotherms. Thermodynamic data have been determined for the three ternary alloys: (Zr{sub 0.75}Hf{sub 0.25})Co, (Zr{sub 0.50}Hf{sub 0.50})Co, and (Zr{sub 0.25}Hf{sub 0.75})Co and the four ternary alloys: (Zr{sub 0.875}Hf{sub 0.125})Ni, (Zr{sub 0.75}Hf{sub 0.25})Ni, (Zr{sub 0.50}Hf{sub 0.50})Ni, and (Zr{sub 0.25}Hf{sub 0.75})Ni. This offers the opportunity to learn how the thermodynamic properties of the ternary alloy-H systems change with the stoichiometry of alloys with the same structure. - Highlights: • Calorimetric enthalpies determined for H absorption by ZrCo, HfCo, HfNi are determined. • Ternary alloys, e.g., Zr{sub 1−x}Hf{sub x}Ni, prepared and characterized by x-ray diffraction. • Isotherms for the ternary alloys give thermodynamic parameters for H solution.

  8. Single layer of Ge quantum dots in HfO2 for floating gate memory capacitors.

    Science.gov (United States)

    Lepadatu, A M; Palade, C; Slav, A; Maraloiu, A V; Lazanu, S; Stoica, T; Logofatu, C; Teodorescu, V S; Ciurea, M L

    2017-04-28

    High performance trilayer memory capacitors with a floating gate of a single layer of Ge quantum dots (QDs) in HfO2 were fabricated using magnetron sputtering followed by rapid thermal annealing (RTA). The layer sequence of the capacitors is gate HfO 2/floating gate of single layer of Ge QDs in HfO 2/tunnel HfO 2/p-Si wafers. Both Ge and HfO2 are nanostructured by RTA at moderate temperatures of 600-700 °C. By nanostructuring at 600 °C, the formation of a single layer of well separated Ge QDs with diameters of 2-3 nm at a density of 4-5 × 10(15) m(-2) is achieved in the floating gate (intermediate layer). The Ge QDs inside the intermediate layer are arranged in a single layer and are separated from each other by HfO2 nanocrystals (NCs) about 8 nm in diameter with a tetragonal/orthorhombic structure. The Ge QDs in the single layer are located at the crossing of the HfO2 NCs boundaries. In the intermediate layer, besides Ge QDs, a part of the Ge atoms is segregated by RTA at the HfO2 NCs boundaries, while another part of the Ge atoms is present inside the HfO2 lattice stabilizing the tetragonal/orthorhombic structure. The fabricated capacitors show a memory window of 3.8 ± 0.5 V and a capacitance-time characteristic with 14% capacitance decay in the first 3000-4000 s followed by a very slow capacitance decrease extrapolated to 50% after 10 years. This high performance is mainly due to the floating gate of a single layer of well separated Ge QDs in HfO2, distanced from the Si substrate by the tunnel oxide layer with a precise thickness.

  9. Garnet effect on Nd-Hf isotope decoupling: Evidence from the Jinfosi batholith, Northern Tibetan Plateau

    Science.gov (United States)

    Huang, Hui; Niu, Yaoling; Mo, Xuanxue

    2017-03-01

    The initial Nd and Hf isotope ratios of a 420 Ma post-collisional dioritic-granitic batholith from the Northern Tibetan plateau define a negative trend above and orthogonal to the ԐHf(t)-ԐNd(t) terrestrial array. This uncommon trend offers an insight into the origin of the puzzling Nd-Hf isotope decoupling in the crustal rocks. On this trend, samples depleted in heavy rare earth elements (HREEs, i.e., [Dy/Yb]N ≫ 1) deviate most from the terrestrial array whereas samples with flat HREEs (i.e., [Dy/Yb]N ≥ 1) deviate less or plot within the terrestrial array, pointing to the controlling effect of garnet in the magma source. Ancient garnet-bearing residues after melt extraction will have elevated Lu/Hf ratios and can evolve with time to produce high ԐHf(t) at a low ԐNd(t) value. Mixing of melts derived from such source lithologies (high Lu/Hf) with melts possessing a within-terrestrial array Nd-Hf isotopic composition (low Lu/Hf) best explains the observed trend orthogonal to the terrestrial array. The samples from the Jinfosi batholith with the most decoupled Nd-Hf isotope compositions require a larger degree (> 40%) and ancient (i.e., ≥ 1.8 Gyr) previous melt extraction from their source. It follows that the ancient melts with depleted HREEs complementary to those garnet-bearing residues should have low ԐHf values and plot below the terrestrial array, which is indeed shown by some Archean/Paleoproterozic TTGs.

  10. Hardness and Second Phase Percentage of Ni-Ti-Hf Compounds After Heat Treatment at 700C

    Science.gov (United States)

    Stanford, Malcolm K.

    2017-01-01

    The Vickers hardness and second phase precipitation of three ternary intermetallic Ni-Ti-Hf compounds containing either 1, 3 or 5 at.% Hf were compared to 60-Nitinol (55 at.% Ni - 45 at.% Ti). Heat treatment either at 700 C or with a subsequent aging step, hardened the 3 and 5 at.% Hf-containing ternaries to approximately 620 HV (56 HRC). Heat treatment increased the hardness of the 1 at.% Hf compound by more than 25 percent. Average hardness of the 3 and 5 at.% Hf ternaries, though higher than that of the binary Ni-Ti or the Ni-Ti-Hf compound containing 1 at.% Hf, appeared to be fairly insensitive to the different heat treatments. There was a drastic reduction of fatigue-enhancing second phase precipitates for the 5 at.% Hf ternaries compared to the other compounds. These results should guide materials selection for development of aerospace componentry.

  11. Mixing and melt sources in the Miocene Aztec Wash pluton (Nevada, USA) as revealed by zircon Hf and O and whole rock Sr, Nd, and Hf isotopes

    Science.gov (United States)

    Ryan, M.; Miller, J. S.; Miller, C. F.; Bromley, S.; Davies, G. R.; Schmitt, A. K.

    2011-12-01

    The 15.6 Ma Aztec Wash Pluton (AWP) is one of several Miocene intrusions located within the northern Colorado River extensional corridor. Extensive E-W tilting of fault blocks has exposed the pluton from the roof to 5 km structural depth. Earlier field and petrologic studies subdivided the AWP into two distinct zones: (1) a Granite Zone (GZ) comprised of relatively homogeneous granite with subtle differences in textures and mineralogy; (2) a Heterogeneous Zone (HZ), which interfingers the GZ, contains evidence for mafic and felsic magma input with a wide compositional range (42-78 wt% SiO2), and abundant field evidence for hybridization. Previous whole rock geochemistry and zircon trace element analyses indicated that compositional variation was produced by multi-component mixing between mafic and felsic melts within the HZ. New whole rock Sr, Nd, and Hf isotope data from the HZ show that all rocks (including high-silica granites) formed by mixing Precambrian crust and enriched mantle, with mixtures having a large mantle fraction (≥50%). New Hf (n=189) and O (n=241) isotope analyses of zircon from samples in the HZ confirm these melt sources and provide a broader perspective on hybridization processes within the AWP. Zircon grains from all samples show heterogeneous Hf and O isotopic compositions (-5 to -18 ɛHf; 4.5-7.5% δ18O), but despite the clear signature of Precambrian crust in the whole rock data, obvious Precambrian zircons (or cores) were mostly absent; only one zircon was clearly Precambrian (ɛHf = -25). Resolvable intragrain variability is relatively limited (including the Precambrian grain, which is unzoned). Zircons from hand samples and from compositional groups also show heterogeneous ɛHf and δ18O values, although the spreads are more restricted than in the whole data set (6-10 ɛHf in granites, 5-7 ɛHf in intermediate "hybrids", 5-6 ɛHf in gabbro/diorite sheets). Oxygen isotope values for the zircons also show intra-handsample heterogeneity

  12. Computational-Experimental Processing of Boride/Carbide Composites by Reactive Infusion of Hf Alloy Melts into B4C

    Science.gov (United States)

    2015-09-16

    elements from the Hf family (i.e., Hf, Ti and Zr ) into a capillary to understand the effects of surface tension and viscosity during processing of melts...project primarily investigated computationally the infusion of liquid elements from the Hf family (i.e., Hf, Ti and Zr ) into a capillary to understand the... effects of surface tension and viscosity during processing of melts with a packed bed of B4C to form boride-carbide precipitates. Although the

  13. Structure, optical properties and thermal stability of HfErO films deposited by simultaneous RF and VHF magnetron sputtering

    Energy Technology Data Exchange (ETDEWEB)

    Zhang, H.Y. [Soochow University, College of Physics, Optoelectronics and Energy and Collaborative Innovation Center of Suzhou Nano Science and Technology, Suzhou (China); Nanjing University of Posts and Telecommunications, School of Tongda, Nanjing (China); Soochow University, Key Lab of Advanced Optical Manufacturing Technologies of Jiangsu Province and Key Lab of Modern Optical Technologies of Education Ministry of China, Suzhou (China); He, H.J.; Zhang, Z.; Jin, C.G.; Yang, Y.; Wang, Y.Y.; Ye, C. [Soochow University, College of Physics, Optoelectronics and Energy and Collaborative Innovation Center of Suzhou Nano Science and Technology, Suzhou (China); Soochow University, Key Lab of Advanced Optical Manufacturing Technologies of Jiangsu Province and Key Lab of Modern Optical Technologies of Education Ministry of China, Suzhou (China); Zhuge, L.J. [Soochow University, Key Lab of Advanced Optical Manufacturing Technologies of Jiangsu Province and Key Lab of Modern Optical Technologies of Education Ministry of China, Suzhou (China); Soochow University, Analysis and Testing Center, Suzhou (China); Wu, X.M. [Soochow University, College of Physics, Optoelectronics and Energy and Collaborative Innovation Center of Suzhou Nano Science and Technology, Suzhou (China); Soochow University, Key Lab of Advanced Optical Manufacturing Technologies of Jiangsu Province and Key Lab of Modern Optical Technologies of Education Ministry of China, Suzhou (China); Chinese Academy of Sciences, State Key Laboratory of Functional Materials for Informatics, Shanghai Institute of Microsystem and Information Technology, Shanghai (China)

    2015-01-23

    HfErO films are deposited on Si substrates by simultaneous radio frequency (RF) and very high frequency (VHF) magnetron sputtering technique. The content of the doped ingredient of Er and the body composition of HfO{sub x} are, respectively, controlled through the VHF and RF powers. Low content of Er doping in the HfErO films can be achieved, because the VHF source of 27.12 MHz has higher ion energy and lower ion flux than the RF source resulting in low sputtering rate in the magnetron sputtering system. The structure, optical properties and thermal stability of the HfErO films are investigated in this work. Results show that the doped content of Er is independently controlled by the VHF power. The oxygen vacancies are created by the Er incorporation. The hafnium in the HfErO films forms mixed valence of Hf{sup 2+} and Hf{sup 4+}. The HfErO films are composed with the structures of HfO{sub 2}, HfO and ErO{sub x}, which can be optimized through the VHF power. At high VHF power, the Hf-Er-O bonds are formed, which demonstrates that the Er atoms are doped into the lattice of HfO{sub 2} in the HfErO films. The HfErO films have bad thermal stability as the crystallization temperature decreases from 900 to 800 C. After thermal annealing, cubic phase of HfO{sub 2} are stabilized, which is ascribed to the oxygen vacancies creation by the Er incorporation. The optical properties such as the refractive index and the optical band gap of the HfErO films are optimized by the VHF power. (orig.)

  14. Archean Lithosphere Beneath Arctic Canada: Lu-Hf Isotope Systematics for Kimberlite-Hosted Garnet-Peridotites From Somerset Island

    Science.gov (United States)

    Schmidberger, S. S.; Simonetti, A.; Francis, D.; Gariepy, C.

    2001-05-01

    Knowledge of the age of lithospheric mantle underlying the continents provides valuable constraints for the timing of formation and stabilization of Archean cratons. This study reports Lu-Hf isotopic data for garnet-peridotites, and their constituent garnets, from the Nikos kimberlite (100 Ma) on Somerset Island in the Canadian Arctic obtained using a Micromass IsoProbe multicollector inductively coupled plasma mass spectrometer (MC-ICP-MS) at GEOTOP-UQAM. The low temperature peridotites (1100 C; 160-190 km) and their 176Hf/177Hf(0.1Ga) isotopic compositions (0.28265-0.28333; \\epsilonHf(0.1Ga)=-2 to +22) are less radiogenic than those of the shallow xenoliths. A Lu-Hf isochron for six peridotites yields a mid Archean age of 3.4\\pm0.3 Ga and an initial 176Hf/177Hf ratio of 0.28101\\pm24. The remaining peridotites (n=9), in contrast, are characterized by extremely high (+35) initial \\epsilonHf(3.4Ga) values, which correlate negatively with their 176Lu/177Hf ratios, suggesting addition of Hf as a result of metasomatic interaction with the host kimberlite. The garnets from the low temperature (3.4 Ga old) peridotites are characterized by high 176Lu/177Hf ratios and define an errorchron age of 1.4\\pm0.2 Ga, which may reflect re-equilibration of Hf during kimberlite magmatism.

  15. Design for human factors (DfHF): a grounded theory for integrating human factors into production design processes.

    Science.gov (United States)

    Village, Judy; Searcy, Cory; Salustri, Filipo; Patrick Neumann, W

    2015-01-01

    The 'design for human factors' grounded theory explains 'how' human factors (HF) went from a reactive, after-injury programme in safety, to being proactively integrated into each step of the production design process. In this longitudinal case study collaboration with engineers and HF Specialists in a large electronics manufacturer, qualitative data (e.g. meetings, interviews, observations and reflections) were analysed using a grounded theory methodology. The central tenet in the theory is that when HF Specialists acclimated to the engineering process, language and tools, and strategically aligned HF to the design and business goals of the organisation, HF became a means to improve business performance. This led to engineers 'pulling' HF Specialists onto their team. HF targets were adopted into engineering tools to communicate HF concerns quantitatively, drive continuous improvement, visibly demonstrate change and lead to benchmarking. Senior management held engineers accountable for HF as a key performance indicator, thus integrating HF into the production design process. Practitioner Summary: Research and practice lack explanations about how HF can be integrated early in design of production systems. This three-year case study and the theory derived demonstrate how ergonomists changed their focus to align with design and business goals to integrate HF into the design process.

  16. Photocurrent generation in carbon nanotube/cubic-phase HfO2 nanoparticle hybrid nanocomposites

    Directory of Open Access Journals (Sweden)

    Protima Rauwel

    2016-07-01

    Full Text Available A hybrid material consisting of nonfunctionalized multiwall carbon nanotubes (MWCNTs and cubic-phase HfO2 nanoparticles (NPs with an average diameter of 2.6 nm has been synthesized. Free standing HfO2 NPs present unusual optical properties and a strong photoluminescence emission in the visible region, originating from surface defects. Transmission electron microscopy studies show that these NPs decorate the MWCNTs on topological defect sites. The electronic structure of the C K-edge in the nanocomposites was probed by electron energy loss spectroscopy, highlighting the key role of the MWCNT growth defects in anchoring HfO2 NPs. A combined optical emission and absorption spectroscopy approach illustrated that, in contrast to HfO2 NPs, the metallic MWCNTs do not emit light but instead expose their discrete electronic structure in the absorption spectra. The hybrid material manifests characteristic absorption features with a gradual merger of the MWCNT π-plasmon resonance band with the intrinsic defect band and fundamental edge of HfO2. The photoluminescence of the nanocomposites indicates features attributed to combined effects of charge desaturation of HfO2 surface states and charge transfer to the MWCNTs with an overall reduction of radiative recombination. Finally, photocurrent generation under UV–vis illumination suggests that a HfO2 NP/MWCNT hybrid system can be used as a flexible nanodevice for light harvesting applications.

  17. Superelasticity and Shape Memory Behavior of NiTiHf Alloys

    Science.gov (United States)

    Sehitoglu, H.; Wu, Y.; Patriarca, L.; Li, G.; Ojha, A.; Zhang, S.; Chumlyakov, Y.; Nishida, M.

    2017-06-01

    The NiTiHf high-temperature shape memory alloys represent a significant advancement in extending the functionality of binary NiTi to elevated temperatures above 100 °C. Despite this potential, the previous results in the literature point to a disappointingly low shape memory strains with addition of Hf. On the other hand, based on theoretical analysis using the lattice constants, the transformation strains should increase substantially with increase in Hf content. The present paper addresses this discrepancy, and using atomistic simulations, determination of twinning modes in martensite with transmission electron microscopy, digital image measurements of habit plane orientation, and strains in single-crystal specimens show that the experimental transformation strains in NiTiHf indeed increase with increasing Hf to unprecedented strain levels near 20%. The Hf contents considered were in the range 6.25-25 at.%, and NiTi (0% Hf) results are provided as the baseline. The current work represents more than 60 experiments representing an extremely thorough study on single crystals and polycrystals.

  18. Isolation and Characterization of a Virulent Bacteriophage φPA-HF17 of Pseudomonas aeruginosa

    Directory of Open Access Journals (Sweden)

    Fang Han

    2014-09-01

    Full Text Available Pseudomonas aeruginosa, an important causative agent of nosocomial infection, is found throughout the hospital environment in moist reservoirs, and multidrug-resistant strains of P. aeruginosa have been increasingly reported worldwide. Bacteriophages are often considered potential therapeutic candidates in treating infectious diseases. In this study, a novel virulent bacteriophage φPA-HF17, specific infecting clinical isolates of P. aeruginosa, was isolated and characterized from environmental sewage. Transmission electron microscopy showed that phage φPA-HF17 had an icosahedral head with a very short tail, and exhibited characteristics typical of a podovirus. Restriction analysis indicated that phage φPA-HF17 was a double-stranded DNA virus, which might be digested by some restriction endonucleases. Phage φPA-HF17 was highly infectious with a rapid adsorption (>90% adsorbed in 4 min. In a one-step growth experiment, phage φPA-HF17 was shown having a latent period of 10 minute, with corresponding burst sizes of 200 PFU/cell. Furthermore, when φPA-HF17 alone was incubated at different pHs and different temperatures, the phage was stable over a wide pH range (4 to 10 and at extreme temperature (50°C. These results suggest that φPA-HF17 may be candidate therapeutic phage to control P. aeruginosa infection.

  19. In-situ atomic layer deposition growth of Hf-oxide

    Energy Technology Data Exchange (ETDEWEB)

    Karavaev, Konstantin

    2010-06-17

    We have grown HfO{sub 2} on Si(001) by atomic layer deposition (ALD) using HfCl{sub 4}, TEMAHf, TDMAHf and H{sub 2}O as precursors. The early stages of the ALD were investigated with high-resolution photoelectron spectroscopy and X-ray absorption spectroscopy. We observed the changes occurring in the Si 2p, O 1s, Hf 4f, Hf 4d, and Cl 2p (for HfCl{sub 4} experiment) core level lines after each ALD cycle up to the complete formation of two layers of HfO{sub 2}. The investigation was carried out in situ giving the possibility to determine the properties of the grown film after every ALD cycle or even after a half cycle. This work focused on the advantages in-situ approach in comparison with ex-situ experiments. The study provides to follow the evolution of the important properties of HfO{sub 2}: contamination level, density and stoichiometry, and influence of the experimental parameters to the interface layer formation during ALD. Our investigation shows that in-situ XPS approach for ALD gives much more information than ex-situ experiments. (orig.)

  20. Linear Trimeric Hafnium Clusters in Hf0.86(1I3

    Directory of Open Access Journals (Sweden)

    Jan Beekhuizen

    2011-05-01

    Full Text Available The reduction of hafnium tetraiodide, HfI4, with aluminum at 600 °C or 850 °C in the presence of a NaI flux resulted in black single crystals of Hf0.86(1I3. This composition corresponds well to the upper end of the non-stoichiometry range 0.89 ≤ x ≤ 1.00 previously reported for HfxI3. The crystal structure (a = 1250.3(2, c = 1999.6(3 pm, R-3m, Z = 18 is made up of hexagonal closest packed layers of iodide ions. One third of the octahedral holes would be filled as in TiI3 or ZrI3 if it were Hf1.00I3. In Hf0.86(1I3, one out of six octahedral holes along [001] are, however, only occupied by 16%. In contrast to TiI3-I and ZrI3, one striking structural feature is in the formation of linear hafnium trimers with identical Hf―Hf distances of 318.3(2 pm rather than the formation of dimers. These may be associated with Hf―Hf bonding although only 2.64 electrons are available for one Hf5.16I18 column.

  1. Microstructure and Phase Stability of Single Crystal NiAl Alloyed with Hf and Zr

    Science.gov (United States)

    Locci, I. E.; Dickerson, R. M.; Garg, A.; Noebe, R. D.; Whittenberger, J. D.; Nathal, M. V.; Darolia, R.

    1996-01-01

    Six near stoichiometric, NiAl single-crystal alloys, with 0.05-1.5 at.% of Hf and Zr additions plus Si impurities, were microstructurally analyzed in the as-cast, homogenized, and aged conditions. Hafnium-rich interdendritic regions, containing the Heusler phase (Ni2AlHf), were found in all the as-cast alloys containing Hf. Homogenization heat treatments partially reduced these interdendritic segregated regions. Transmission electron microscopy (TEM) observations of the as-cast and homogenized microstructures revealed the presence of a high density of fine Hf (or Zr) and Si-rich precipitates. These were identified as G-phase, Nil6X6Si7, or as an orthorhombic NiXSi phase, where X is Hf or Zr. Under these conditions the expected Heusler phase (beta') was almost completely absent. The Si responsible for the formation of the G and NiHfSi phases is the result of molten metal reacting with the Si-containing crucible used during the casting process. Varying the cooling rates after homogenization resulted in the refinement or complete suppression of the G and NiHfSi phases. In some of the alloys studied, long-term aging heat treatments resulted in the formation of Heusler precipitates, which were more stable at the aging temperature and coarsened at the expense of the G-phase. In other alloys, long-term aging resulted in the formation of the NiXSi phase. The stability of the Heusler or NiXSi phases can be traced to the reactive element (Hf or Zr) to silicon ratio. If the ratio is high, then the Heusler phase appears stable after long time aging. If the ratio is low, then the NiHfSi phase appears to be the stable phase.

  2. Vibrational relaxation of hydrogen fluoride by HF dimers in a laser excited nozzle beam

    Energy Technology Data Exchange (ETDEWEB)

    Knuth, E.L.; Rubahn, H.; Toennies, J.P.; Wanner, J.

    1986-09-01

    An HF nozzle beam and a cw HF laser beam in a coaxial and antiparallel arrangement facilitated exciting HF molecules vibrationally in v-italic = 1,J-italic up to the saturation limit. A beam consisting exclusively of monomeric HF was generated by heating the beam source to 600 K and was confirmed using a mass spectrometer. Energy-flux measurements made using a bolometer indicate that the vibrational energy distribution initiated by the laser is conserved, confirming that V--T energy transfer to monomers is slow. The maximum measured flux of HF(v-italic = 1,J-italic) molecules was 1.5 x 10/sup 17/ molecules s/sup -1/ sr/sup -1/ at 670 mbar stagnation pressure. Beams consisting of a mixture of monomeric and polymeric HF were generated using appropriate combinations of source temperature and pressure. In the presence of dimers, the excited monomers relax rapidly by a fast V--V transfer and subsequent predissociation of the metastable dimers. The loss of beam energy due to energy transport by the departing dimer fragments was detected bolometrically. The laser-induced depletion of dimers was determined over a wide source pressure range at T-italic/sub 0/ = 300 K using a mass spectrometer. From a kinetic model of these dimer-depletion data, the product of cross section and transfer probability for V--V energy transfer from HF (v-italic = 1) monomers to dimers was deduced to be 14 A-circle/sup 2/. The terminal-dimer-concentration equation for HF nozzle beams was refined. An analysis of the energy fluxes measured by the bolometer with no laser excitation of the beam revealed that, for an HF nozzle beam, the flow from the source to the detector is, in general, nonisenthalpic due to the onset of dimerization. Mach-number focusing enriches the dimer mole fractions detected by the bolometer.

  3. Properties of HfAlO film deposited by plasma enhanced atomic layer deposition

    Energy Technology Data Exchange (ETDEWEB)

    Cao, Duo [State Key Laboratory of Functional Materials for Informatics, Shanghai Institute of Micro-system and Information Technology, Chinese Academy of Sciences, Changning Road 865, Shanghai 200050 (China); Cheng, Xinhong, E-mail: xh_cheng@mail.sim.ac.cn [State Key Laboratory of Functional Materials for Informatics, Shanghai Institute of Micro-system and Information Technology, Chinese Academy of Sciences, Changning Road 865, Shanghai 200050 (China); Jia, Tingting; Zheng, Li; Xu, Dawei; Wang, Zhongjian; Xia, Chao; Yu, Yuehui [State Key Laboratory of Functional Materials for Informatics, Shanghai Institute of Micro-system and Information Technology, Chinese Academy of Sciences, Changning Road 865, Shanghai 200050 (China)

    2013-07-15

    Plasma enhanced atomic layer deposition (PEALD) method can reduce film growing temperature, and allow in situ plasma treatment. In this work, HfAlO and HfO{sub 2} films were deposited with PEALD at 160 °C. Microstructure analysis showed that both films were amorphous after rapid thermal annealing (RTA) treatment, and HfAlO sample showed better interfacial structure than HfO{sub 2}. X-ray photoelectron spectroscopy (XPS) spectra indicated that main component of the interfacial layer of HfAlO sample was Hf–Si–O and Al–Si–O bonds, the valence band offset value between the HfAlO film and Si substrate was calculated to be 2.5 eV. The dominant leakage current mechanism of the samples was Schottky emission at a low electric field (<1.4 MV/cm), and Poole–Frenkel emission mechanism at a higher electric field (>1.4 MV/cm). The equivalent oxide thicknesses (EOT) of the HfAlO samples were 1.0 nm and 1.3 nm, respectively. The density of interface states between dielectric and substrate were calculated to be 1.2 × 10{sup 12} eV{sup −1}cm{sup −2} and 1.3 × 10{sup 12} eV{sup −1}cm{sup −2}, respectively. In comparison with HfO{sub 2} film, HfAlO film has good interfacial structure and electrical performance.

  4. Ti insertion in the MTe5 (M = Zr, Hf structure type: Hf0.78Ti0.22Te5

    Directory of Open Access Journals (Sweden)

    Hoseop Yun

    2012-03-01

    Full Text Available The group 5 mixed-metal telluride, Hf0.78Ti0.22Te5 (hafnium titanium pentatelluride, is isostructural with the binary phases HfTe5 and ZrTe5 and forms a layered structure extending parallel to (010. The layers are made up from chains of bicapped metal-centered trigonal prisms and zigzag Te chains. The metal site (site symmetry m2m is occupied by statistically disordered Hf [78.1 (5%] and Ti [21.9 (5%]. In addition to the regular Te—Te pair [2.7448 (13 Å] forming the short base of the equilateral triangle of the trigonal prism, an intermediate Te...Te separation [2.9129 (9 Å] is also found. The classical charge balance of the compound can be described as [M4+][Te2−][Te22−][Te20] (M = Hf, Ti. The individual metal content can vary in different crystals, apparently forming a random substitutional solid solution (Hf1-xTixTe5, with 0.15 ≤ x ≤ 0.22.

  5. First-principles calculated spin-gapless semiconducting behavior in quaternary VCoHfGa and CrFeHfGa Heusler compounds

    Energy Technology Data Exchange (ETDEWEB)

    Yang, Xiude; Wu, Xiaolin [Institute of Theoretical Physics, Zunyi Normal College, Zunyi 563002 (China); Wu, Bo, E-mail: fqwubo@zync.edu.cn [Institute of Theoretical Physics, Zunyi Normal College, Zunyi 563002 (China); School of Marine Science and Technology, Northwestern Polytechnical University, Xian 710072 (China); Feng, Yu [School of Physical Science and Technology, Southwest University, Chongqing 400715 (China); Li, Ping [Institute for Clean Energy & Advanced Materials (ICAEM), Southwest University, Chongqing 400715 (China); Huang, Haishen [Institute of Theoretical Physics, Zunyi Normal College, Zunyi 563002 (China)

    2016-07-15

    Highlights: • Structural, electronic and magnetic properties of quaternary Heusler alloy [VCo,CrFe]HfGa were detected theoretically. • The quaternary Heusler alloy [VCo,CrFe]HfGa are (or are nearly) spin gapless semiconductors at the lowest energy state. • The ferromagnetic coupling plays an important role in magnetism. - Abstract: By using generalized gradient approximation (GGA) scheme within the density functional theory (DFT), the structural, electronic and magnetic properties of LiMgPdSn-type quaternary Heusler alloy CrFeHfGa and VCoHfGa were detected compressively. The results reveal that the two alloys are (or are nearly) potential spin gapless semiconductors with a magnetic moment of 3 μ{sub B} per primitive cell and the minority-spin gap of 0.8 eV and 0.6 eV at Fermi level (ε{sub F}) during the rate of lattice change of about −5%, respectively. We deduce that the ferromagnetic coupling among transitional metals plays an important role in magnetism of Heusler alloy [CrFe,VCo]HfGa.

  6. First-principles study of the (001) surface of cubic PbHfO3 and BaHfO3

    Institute of Scientific and Technical Information of China (English)

    Ni Guang-Xin; Wang Yuan-Xu

    2009-01-01

    Using first-principles techniques, we investigate the (001) surfaces of cubic PbHfO3 (PHO) and BaHfO3 (BHO) terminated with both AO (A=Pb and Ba) and HfO2- Surface structure, partial density of states, band structure, and surface energy are obtained. The BaO surface is found to be similar to its counterpart in BHO. For the HfO2-terminated surface of cubic PHO, the largest relaxation appears on the second-layer atoms but not on the first-layer ones. The analysis of the structure relaxation parameters reveals that the rumpling of the (001) surface for PHO is stronger than that for BHO. The surface thermodynamic stability is explored, and it is found that both the PbO- and the BaO-terminated surfaces are more stable than the HfO2-terminated surfaces for PHO and BHO, respectively. The surface energy calculations show that the (001) surface of PHO is more easily constructed than that of BHO.

  7. Recent progress in AMS measurement of 182Hf at the CIAE

    Institute of Scientific and Technical Information of China (English)

    LI Zhen-Yu; LI Heng; WU Shao-Yong; YUAN Jian; JIANG Shan; HE Ming; DONG Ke-Jun; HE Guo-Zhu; LI Chao-Li; HE Xian-Wen; ZHANG Wei; HU Hao; ZHENG Guo-Wen

    2012-01-01

    In order to improve the accuracy of accelerator mass spectrometry (AMS) measurement for 182Hf/180Hf,a series of measurements have been taken in the AMS laboratory at the China Institute of Atomic Energy (CIAE).The major ones include the instantaneous monitoring of 180HfF-5current,testing the stability of transmission,the alternate measurements of an unknown sample and standard,and the origin identification and minimization of background 182W.The experimental details and the improvement in the measurement accuracy,as well as some useful suggestions for better satisfying the requirements of certain practical applications,are presented in this paper.

  8. Crystal structure of Na2HfSi2O7 by Rietveld refinement

    Directory of Open Access Journals (Sweden)

    Nicolas Massoni

    2016-10-01

    Full Text Available The structure of triclinic disodium hafnium disilicate, Na2HfSi2O7, has been determined by laboratory powder X-ray diffraction and refined by the Rietveld refinement. The structure is a framework made of alternate layers of HfO6 octahedra and SiO4 tetrahedra linked by common O atoms. Sodium atoms are located in the voids of the framework, aligned into tunnels along the [010] direction. Na2HfSi2O7 is isostructural with the parakeldyshite Na2ZrSi2O7 phase.

  9. Structural and thermal properties of Cu-Hf-Ti bulk amorphous alloys

    Science.gov (United States)

    Rontó, V.; Nagy, E.; Svéda, M.; Roósz, A.; Tranta, F.

    2009-01-01

    Cu-Hf-Ti amorphous alloys are high strength and wear resistant materials. Master alloys of Cu57.5Hf27.5Ti15 and Cu57.5Hf25Ti17.5 ternary alloys have been prepared by arc melting, and wedge and rod shaped samples have been cast by centrifugal casting. Liquidus and solidus temperatures of the alloys were determined by DTA. The fully amorphous size was determined by X-ray diffraction. Thermodynamic properties of the amorphous alloys were studied by DSC measurements and Kissinger analyses were performed.

  10. Artificial Ionization and UHF Radar Response Associated with HF Frequencies near Electron Gyro-Harmonics (Invited)

    Science.gov (United States)

    Watkins, B. J.; Fallen, C. T.; Secan, J. A.

    2013-12-01

    We present new results from O-mode ionospheric heating experiments at the HAARP facility in Alaska to demonstrate that the magnitude of artificial ionization production is critically dependent on the choice of HF frequency near gyro-harmonics. For O-mode heating in the lower F-region ionosphere, typically about 200 km altitude, artificial ionization enhancements are observed in the lower ionosphere (about 150 - 220 km) and also in the topside ionosphere above about 500 km. Lower ionosphere density enhancements are inferred from HF-enhanced ion and plasma-line signals observed with UHF radar. Upper ionospheric density enhancements have been observed with TEC (total electron content) experiments by monitoring satellite radio beacons where signal paths traverse the HF-modified ionosphere. Both density enhancements and corresponding upward plasma fluxes have also been observed in the upper ionosphere via in-situ satellite observations. The data presented focus mainly on observations near the third and fourth gyro-harmonics. The specific values of the height-dependent gyro-harmonics have been computed from a magnetic model of the field line through the HF heated volume. Experiments with several closely spaced HF frequencies around the gyro-harmonic frequency region show that the magnitude of the lower-ionosphere artificial ionization production maximizes for HF frequencies about 1.0 - 1.5 MHz above the gyro-harmonic frequency. The response is progressively larger as the HF frequency is increased in the frequency region near the gyro-harmonics. For HF frequencies that are initially greater than the gyro-harmonic value the UHF radar scattering cross-section is relatively small, and non-existent or very weak signals are observed; as the signal returns drop in altitude due to density enhancements the HF interaction region passes through lower altitudes where the HF frequency is less than the gyro-harmonic value, for these conditions the radar scattering cross-section is

  11. Graphene contacts to a HfSe2/SnS2 heterostructure

    Science.gov (United States)

    Su, Shanshan; Das, Protik; Ge, Supeng; Lake, Roger K.

    2017-02-01

    Two-dimensional (2D) heterostructures and all-2D contacts are of high interest for electronic device applications, and the SnS2/HfSe2 bilayer heterostructure with graphene contacts has some unique, advantageous properties. The SnS2/HfSe2 heterostructure is interesting because of the strong intermixing of the two conduction bands and the large work function of the SnS2. The band lineup of the well separated materials indicates a type II heterostructure, but the conduction band minimum of the SnS2/HfSe2 bilayer is a coherent superposition of the orbitals from the two layers with a spectral weight of 60% on the SnS2 and 40% on the HfSe2 for AA stacking. These relative weights can be either increased or reversed by an applied vertical field. A 3 ×3 supercell of graphene and a 2 ×2 supercell of SnS2/HfSe2 have a lattice mismatch of 0.1% and both the SnS2/HfSe2 conduction band at M and the graphene Dirac point at K are zone-folded to Γ . Placing graphene on the SnS2/HfSe2 bilayer results in large n-type charge transfer doping of the SnS2/HfSe2 bilayer, on the order of 1013/cm2, and the charge transfer is accompanied by a negative Schottky barrier contact for electron injection from the graphene into the SnS2/HfSe2 bilayer conduction band. Binding energies and the anti-crossing gaps of the graphene and the SnS2/HfSe2 electronic bands both show that the coupling of graphene to the HfSe2 layer is significantly larger than its coupling to the SnS2 layer. A tunneling Hamiltonian estimate of the contact resistance of the graphene to the SnS2/HfSe2 heterostructure predicts an excellent low-resistance contact.

  12. Control of photoassociation reaction F+H→HF with ultrashort laser pulse

    Institute of Scientific and Technical Information of China (English)

    2007-01-01

    The laser-induced vibrational state-selectivity of product HF in photoassociation reaction H+F→HF is theoretically investigated by using the time-dependent quantum wave packet method. The population transfer process from the continuum state down to the bound vibrational states can be controlled by the driving laser. The effects of laser pulse parameters and the initial momentum of the two collision atoms on the vibrational population of the product HF are discussed in detail. Photodissociation accompanied with the photoassociation process is also described.

  13. [18F]Fluoride recovery via gaseous [18F]HF

    DEFF Research Database (Denmark)

    Mathiessen, Bente; Jensen, Mikael; Zhuravlev, Fedor

    2011-01-01

    Acidification of target water with H2SO4 in a specially constructed glassy carbon/polyethylene apparatus allowed for recovery of up to 82% of [18F]fluoride as [18F]HF gas. The [18F]HF distillate was found to be acid-free but moist; when passed through a solution of tBuPh2SiOTf, it yielded [18F......]tBuPh2SiF. The multivariate design of experiment showed that the key to high yield of [18F]HF was the efficient degassing of the reaction mixture....

  14. The role of phosphates for the Lu-Hf chronology of meteorites

    Science.gov (United States)

    Debaille, Vinciane; Van Orman, James; Yin, Qing-Zhu; Amelin, Yuri

    2017-09-01

    The 176Lu-176Hf isotopic system is widely used for dating and tracing cosmochemical and geological processes, but still suffers from two uncertainties. First, Lu-Hf isochrons for some early Solar System materials have excess slope of unknown origin that should not be expected for meteorites with ages precisely determined with other isotopic chronometers. This observation translates to an apparent Lu decay constant higher than the one calculated by comparing ages obtained with various dating methods on terrestrial samples. Second, unlike the well constrained Sm/Nd value (to within 2%) for the chondritic uniform reservoir (CHUR), the Lu/Hf ratios in chondrites vary up to 18% when considering all chondrites, adding uncertainty to the Lu/Hf CHUR value. In order to better understand the Lu-Hf systematics of chondrites, we analyzed mineral fractions from the Richardton H5 chondrite to construct an internal Lu-Hf isochron, and set up a numerical model to investigate the effect of preferential diffusion of Lu compared to Hf from phosphate, the phase with the highest Lu-Hf ratio in chondrites, to other minerals. The isochron yields an age of 4647 ± 210 million years (Myr) using the accepted 176Lu decay constant of 1.867 ± 0.008 ×10-11yr-1. Combining this study with the phosphate fractions measured in a previous study yields a slope of 0.08855 ± 0.00072, translating to a 176Lu decay constant of 1.862 ± 0.016 ×10-11yr-1 using the Pb-Pb age previously obtained, in agreement with the accepted value. The large variation of the Lu/Hf phosphates combined with observations in the present study identify phosphates as the key in perturbing Lu-Hf dating and generating the isochron slope discrepancy. This is critical as apatite has substantially higher diffusion rates of rare earth elements than most silicate minerals that comprise stony meteorites. Results of numerical modeling depending of temperature peak, size of the grains and duration of the metamorphic event, show that

  15. Interaction of La2O3 capping layers with HfO2 gate dielectrics

    Science.gov (United States)

    Copel, M.; Guha, S.; Bojarczuk, N.; Cartier, E.; Narayanan, V.; Paruchuri, V.

    2009-11-01

    We report the effect of La2O3 capping layers on HfO2/SiO2/Si dielectrics, proposed for use in threshold voltage tuning of field effect transistors. Depth profiling with medium energy ion scattering shows that an initial surface layer of La2O3 diffuses through the HfO2 at elevated temperatures, ultimately converting some of the thin interfacial SiO2 into a silicate. Core-level photoemission measurements indicate that the additional band-bending induced by the La2O3 only appears after diffusion, and the added charge resides between the HfO2 and the substrate.

  16. A first-principles high-pressure study of Hf2PX (X=B, C, N)

    Science.gov (United States)

    Li, Hui; Luo, Zhili; Liu, Zhe; Sun, Guodong; Wang, Zhenjun

    2017-06-01

    New members of MAX family Hf2PX (X=B, C, N) were studied by first-principles calculations under pressure range of 0-100 GPa. Their structural, elastic and electronic properties were reported. The results show that they are energetically stable at zero pressure and mechanically stable under pressure range from 0 to 100 GPa. It reveals that Hf2PB>Hf2PC>Hf2PN for the structural parameters of a and V, and Hf2PBpressure environments.

  17. Fabrication and characteristics of high-K HfO2 gate dielectrics on n-germanium

    Institute of Scientific and Technical Information of China (English)

    Han De-Dong; Kang Jin-Feng; Liu Xiao-Yan; Sun Lei; Luo Hao; Han Ru-Qi

    2007-01-01

    This paper reports that the high-K HfO2 gate dielectrics are fabricated on n-germanium substrates by sputtering Hf on Ge and following by a furnace annealing. The impacts of sputtering ambient, annealing ambient and annealing temperature on the electrical properties of high-K HfO2 gate dielectrics on germanium substrates are investigated.Experimental results indicate that high-K HfO2 gate dielectrics on germanium substrates with good electrical characteristics are obtained, the electrical properties of high-K HfO2 gate dielectrics is strongly correlated with sputtering ambient, annealing ambient and annealing temperature.

  18. Low modulus Ti-Nb-Hf alloy for biomedical applications.

    Science.gov (United States)

    González, M; Peña, J; Gil, F J; Manero, J M

    2014-09-01

    β-Type titanium alloys with a low elastic modulus are a potential strategy to reduce stress shielding effect and to enhance bone remodeling in implants used to substitute failed hard tissue. For biomaterial application, investigation on the mechanical behavior, the corrosion resistance and the cell response is required. The new Ti25Nb16Hf alloy was studied before and after 95% cold rolling (95% C.R.). The mechanical properties were determined by tensile testing and its corrosion behavior was analyzed by potentiostatic equipment in Hank's solution at 37°C. The cell response was studied by means of cytotoxicity evaluation, cell adhesion and proliferation measurements. The stress-strain curves showed the lowest elastic modulus (42GPa) in the cold worked alloy and high tensile strength, similar to that of Ti6Al4V. The new alloy exhibited better corrosion resistance in terms of open circuit potential (EOCP), but was similar in terms of corrosion current density (iCORR) compared to Ti grade II. Cytotoxicity studies revealed that the chemical composition of the alloy does not induce cytotoxic activity. Cell studies in the new alloy showed a lower adhesion and a higher proliferation compared to Ti grade II presenting, therefore, mechanical features similar to those of human cortical bone and, simultaneously, a good cell response.

  19. Anomalous phenomena on HF radio paths during geomagnetic disturbances

    Science.gov (United States)

    Blagoveshchenskii, D. V.

    2016-07-01

    We analyze ionospheric oblique sounding data on three high-latitude and one high-latitude-midlatitude HF radio paths for February 15 and 16, 2014, when two substorms and one magnetic storm occurred. We investigate cases of anomalous propagation of signals: their reflection from sporadic layer Es, lateral reflections, type "M" or "N" modes, the presence of traveling ionospheric disturbances, and the diffusivity of signals and triplets. The most significant results are the following. In geomagnetically undisturbed times, sporadic Es-layers with reduced maximum observed frequencies (MOF Es) on three high-latitude paths were observed in both days. The values of MOF Es during disturbances are large, which leads to the screening of other oblique sounding signals reflected from the ionosphere. On all four paths, the most frequently traveling ionospheric disturbances due to the terminator were observed in quiet hours from 03:00 to 15:00 UT on the first day and from 06:00 to 13:00 UT on the second day of the experiment. In addition, both the sunset terminator and the magnetic storm on the high-latitude-mid-latitude path were found to generate traveling ionospheric disturbances jointly. No such phenomenon was found on high-latitude paths.

  20. Large ionospheric disturbances produced by the HAARP HF facility

    Science.gov (United States)

    Bernhardt, Paul A.; Siefring, Carl L.; Briczinski, Stanley J.; McCarrick, Mike; Michell, Robert G.

    2016-07-01

    The enormous transmitter power, fully programmable antenna array, and agile frequency generation of the High Frequency Active Auroral Research Program (HAARP) facility in Alaska have allowed the production of unprecedented disturbances in the ionosphere. Using both pencil beams and conical (or twisted) beam transmissions, artificial ionization clouds have been generated near the second, third, fourth, and sixth harmonics of the electron gyrofrequency. The conical beam has been used to sustain these clouds for up to 5 h as opposed to less than 30 min durations produced using pencil beams. The largest density plasma clouds have been produced at the highest harmonic transmissions. Satellite radio transmissions at 253 MHz from the National Research Laboratory TACSat4 communications experiment have been severely disturbed by propagating through artificial plasma regions. The scintillation levels for UHF waves passing through artificial ionization clouds from HAARP are typically 16 dB. This is much larger than previously reported scintillations at other HF facilities which have been limited to 3 dB or less. The goals of future HAARP experiments should be to build on these discoveries to sustain plasma densities larger than that of the background ionosphere for use as ionospheric reflectors of radio signals.

  1. Equatorial ionospheric disturbance observed through a transequatorial HF propagation experiment

    Directory of Open Access Journals (Sweden)

    T. Maruyama

    2006-07-01

    Full Text Available A transequatorial radio-wave propagation experiment at shortwave frequencies (HF-TEP was done between Shepparton, Australia, and Oarai, Japan, using the radio broadcasting signals of Radio Australia. The receiving facility at Oarai was capable of direction finding based on the MUSIC (Multiple Signal Classification algorithm. The results were plotted in azimuth-time diagrams (AT plots. During the daytime, the propagation path was close to the great circle connecting Shepparton and Oarai, thus forming a single line in the AT plots. After sunset, off-great-circle paths, or satellite traces in the AT plot, often appeared abruptly to the west and gradually returned to the great circle direction. However, there were very few signals across the great circle to the east. The off-great-circle propagation was very similar to that previously reported and was attributed to reflection by an ionospheric structure near the equator. From the rate of change in the direction, we estimated the drift velocity of the structure to range mostly from 100 to 300 m/s eastward. Multiple instances of off-great-circle propagation with a quasi-periodicity were often observed and their spatial distance in the east-west direction was within the range of large-scale traveling ionospheric disturbances (LS-TIDs. Off-great-circle propagation events were frequently observed in the equinox seasons. Because there were many morphological similarities, the events were attributed to the onset of equatorial plasma bubbles.

  2. Formation of Al2O3-HfO2 Eutectic EBC Film on Silicon Carbide Substrate

    Directory of Open Access Journals (Sweden)

    Kyosuke Seya

    2015-01-01

    Full Text Available The formation mechanism of Al2O3-HfO2 eutectic structure, the preparation method, and the formation mechanism of the eutectic EBC layer on the silicon carbide substrate are summarized. Al2O3-HfO2 eutectic EBC film is prepared by optical zone melting method on the silicon carbide substrate. At high temperature, a small amount of silicon carbide decomposed into silicon and carbon. The components of Al2O3 and HfO2 in molten phase also react with the free carbon. The Al2O3 phase reacts with free carbon and vapor species of AlO phase is formed. The composition of the molten phase becomes HfO2 rich from the eutectic composition. HfO2 phase also reacts with the free carbon and HfC phase is formed on the silicon carbide substrate; then a high density intermediate layer is formed. The adhesion between the intermediate layer and the substrate is excellent by an anchor effect. When the solidification process finished before all of HfO2 phase is reduced to HfC phase, HfC-HfO2 functionally graded layer is formed on the silicon carbide substrate and the Al2O3-HfO2 eutectic structure grows from the top of the intermediate layer.

  3. Effects of Modified Precursor Solution on Microstructure of (Y,Yb)MnO3/HfO2/Si

    Science.gov (United States)

    Suzuki, Kazuyuki; Kato, Kazumi

    2007-10-01

    Ferroelectric/insulator/silicon structures were prepared using (Y,Yb)MnO3 films as ferroelectrics and HfO2 thin films as insulators through alkoxy-derived precursor solutions. The HfO2 solution was chemically modified in order to decrease the number of heating cycles required. The HfO2 films prepared using a partially hydrolyzed alkoxide solution had a uniform structure. From the results of measurements of the roughness level and refractive index of the HfO2 films, the partial hydrolysis of the HfO2 solution was found to be effective for the formation of a uniform microstructure in a thin insulator film. (Y,Yb)MnO3/HfO2/Si structures were constructed using the resultant HfO2 thin films prepared using the modified solutions.

  4. Effects of C and Hf concentration on phase relations and microstructure of a wrought powder-metallurgy superalloy

    Science.gov (United States)

    Miner, R. V., Jr.

    1977-01-01

    NASA IIB-11, a candidate alloy for advanced temperature turbine engine disks, and four modifications with varying C and Hf concentrations were produced from prealloyed powders. Several notable effects of C and Hf concentration in the alloys were observed. Both the amount of the gamma-prime phase and its solvus temperature increased with decreasing C, but only the gamma-prime solvus was affected by Hf, increasing with increasing Hf. Hf also promoted a cellular gamma-prime precipitation. Hf was, however, about equally distributed between gamma-prime and gamma. Hf and C both affected the carbides formed. Increasing both promoted formation of an MC relative to that of an M6C.

  5. The Modulation of Ionospheric Alfvén Resonator on Heating HF Waves and the Doppler Effect

    Institute of Scientific and Technical Information of China (English)

    Ni Bin-bin; Zhao Zheng-yu; Xie Shu-guo

    2003-01-01

    Abstract: The propagation of HF waves in IAR can produce many nonlinear effects, including the modulation effect of IAR on HF waves and the Doppler effect. To start with the dependence of the ionospheric electron temperature variaof the modulation effect and lucubrate possible reasons for the field can have an observable modulation effect on HF waves while its mechanism is quite different from that of Schumann resonant field on HF waves. The depth of modulation of IAR field, which directly inspires the formation of cross-spectrum between ULF waves and HF waves and results in spectral peaks at some gyro-frequencies of IAR. With respect to the Doppler effect during the propagation of HF waves in IAR, it is mainly caused by the motion of the high-speed flyer and the drifting electrons and the frequency shift from the phase variation of the reflected waves can be neglected when the frequency of HF incident wave is high enough.

  6. Ferroelectric modulation of terahertz waves with graphene/ultrathin-Si:HfO2/Si structures

    Science.gov (United States)

    Jiang, Ran; Han, Zuyin; Sun, Weideng; Du, Xianghao; Wu, Zhengran; Jung, Hyung-Suk

    2015-10-01

    Ferroelectric-field-effect-tunable modulation of terahertz waves in graphene/Si:HfO2/Si stack structure was observed. The modulation shows distinct behaviors when the samples under different gate polarities. At a negative voltage, a transmission modulation depth up to ˜74% was present without depending on the photo illumination power, whereas, at a positive voltage, the modulation of Thz wave shows dependence on the illumination power, which is ascribed to the creation/elimination of an extra barrier in Si layer in response to the polarization in the ferroelectric Si:HfO2 layer. Considering the good compatibility of HfO2 on Si-based semiconductor process, the ferroelectricity layer of Si:HfO2 may open up an avenue for the tunable modulation of Thz wave.

  7. Modulation of auroral electrojet currents using dual HF beams with ELF phase offset

    Science.gov (United States)

    Golkowski, M.; Cohen, M.; Moore, R. C.

    2012-12-01

    The modulation of naturally occuring ionospheric currents with high power radio waves in the high frequency (HF, 3-10 MHz) band is a well known technique for generation of extremely low frequency (ELF, 3-3000 Hz) and very low frequency (VLF, 3-30 kHz) waves. We use the heating facility of the High Frequency Active Auroral Research Program (HAARP) to investigate the effect of using dual HF beams with an ELF/VLF phase offset between the modulation waveforms. Experiments with offset HF beams confirm the model of independent ELF/VLF sources. Experiments with co-located HF beams exhibit interaction between the first and second harmonics of the modulated tones when square and sine wave modulation waveforms are employed. Using ELF/VLF phase offsets for co-loacted beams is also shown to be a potential diagnostic for the D-region ionospheric profile.

  8. Hf diffusion in dilute Fe-free Zr(Nb) alloys

    Energy Technology Data Exchange (ETDEWEB)

    Zou, H.; Hood, G.M.; Roy, J.A.; Schultz, R.J. [Atomic Energy of Canada Ltd., Chalk River, ON (Canada). Chalk River Nuclear Labs.; Jackman, J.A. [Canada Centre for Mineral and Energy Technology, Ottawa, ON (Canada)

    1995-04-01

    Hf diffusion coefficients D have been measured in the {alpha}-phase of the Fe-free binary alloys Zr-1.0 at.% Nb and Zr-2.5 at.% Nb in the temperature range 830-1100 K. The D values for the two alloys are essentially indistinguishable and little different from extant Hf diffusion coefficients measured in Fe-free polycrystalline {alpha}-Zr. The temperature dependence of D in the alloys is characteristic of intrinsic {alpha}-Zr bulk behaviour. The present hf D values are much lower than corresponding values measured in commercial Zr-2.5 Nb. The difference is attributable to the influence of solid-solution Fe. In addition, the absence of a strong enhancement of Hf diffusion in {alpha}-Zr by Nb suggests that intrinsic Nb diffusion in {alpha}-Zr may not be controlled by a normal vacancy mechanism. (author).

  9. HF183/BFDrev and HumM2 qPCR data

    Data.gov (United States)

    U.S. Environmental Protection Agency — Concentration estimates for HF183/BFDrev and HumM2 qPCR genetic markers in raw sewage collected from 54 geographic locations across the United States. This dataset...

  10. Phase Transformation and Thermal Stability of Aged Ti-Ni-Hf High Temperature Shape Memory Alloys

    Institute of Scientific and Technical Information of China (English)

    Xianglong MENG; Wei CAI; K.T.Lau; L.M.Zhou; Liancheng ZHAO

    2006-01-01

    The use of Ni-rich TiNiHf alloys as high temperature shape memory alloys(SMAs)through aging has been presented. For Ni-rich Ti80-xNixHf20 alloys, their phase transformation temperatures are averagely increased more than 100 K by aging at 823 K for 2 h. Especially for the alloys with Ni-content of 50.4 at. pct and 50.6 at. pct, their martensitic transformation start temperatures(Ms)are more than 473 K after aging. TEM observation confirmed that some fine particles precipitate from the matrix during aging. The aged Ni-rich TiNiHf SMAs show the better thermal stability of phase transformation temperatures than the solutiontreated TiNiHf alloys. The fine particles precipitated during aging should be responsible for the increase of phase transformation temperatures and its high stability.

  11. Luminescence and scintillation properties of Rb2HfCl6 crystals

    Science.gov (United States)

    Saeki, Keiichiro; Wakai, Yuki; Fujimoto, Yutaka; Koshimizu, Masanori; Yanagida, Takayuki; Nakauchi, Daisuke; Asai, Keisuke

    2016-11-01

    We developed a scintillator based on a Rb2HfCl6 crystal as a ternary halide crystal with intrinsic luminescence. In the photoluminescence spectra, two emission bands are observed at 383 and 434 nm. The 434 nm emission band for Rb2HfCl6 may be attributed to [HfCl6]2- complex ion or [ZrCl6]2- impurity, since the Rb2HfCl6 contained Zr as impurity at 0.62 mol %. The radioluminescence band is observed at 420 nm and can be attributed to the same origin as the photoluminescence band at 434 nm. The scintillation decay-time constants were 0.84 and 5.4 µs. The light yield was estimated to be 24,100 photons/MeV.

  12. Development of Hf(4+)-immobilized polydopamine-coated magnetic graphene for highly selective enrichment of phosphopeptides.

    Science.gov (United States)

    Lin, Haizhu; Deng, Chunhui

    2016-01-01

    In this work, we first designed and synthesized an IMAC material with Hf(4+) immobilized on polydopamine-coated magnetic graphene and applied it to phosphopeptides enrichment successfully. The newly prepared material gathered the advantages of large specific surface area of graphene, good hydrophilicity and biocompatibility of polydopamine and superparamagnetism of Fe3O4. We investigated the performance of Hf(4+)-immobilized polydopamine-coated magnetic graphene (denoted as magG@PDA-Hf(4+)) in phosphopeptides enrichment and the results showed high selectivity and sensitivity of the new material. Finally, we successfully applied magG@PDA-Hf(4+) to phosphopeptides enrichment from non-fat milk digests and human serum, further demonstrating excellent performance of this new material in phosphopeptides enrichment. Copyright © 2015 Elsevier B.V. All rights reserved.

  13. Intergrowth Structure in U- and Hf-Bearing Pyrochlore and Zirconolite: TEM Investigation

    Energy Technology Data Exchange (ETDEWEB)

    Xu, H; Wang, Y; Zhao, P; Bourcier, W L; Van Konynenburg, R; Shaw, H F

    2002-12-04

    Transmission electron microscopy results from a sintered ceramics with stoichiometry of Ca(U{sub 0.5}Ce{sub 0.25}Hf{sub 0.25})Ti{sub 2}O{sub 7} show the material contains both pyrochlore and zirconolite phases and structural intergrowth of zirconolite lamellae within pyrochlore. (001) plane of zirconolite is parallel to (111) plane of pyrochlore because of their structural similarities. The pyrochlore is relatively rich in U, Ce, and Ca with respect to the coexisting zirconolite. Average compositions for the coexisting pyrochlore and zirconolite produced by sintering at 1350 C are (Ca{sub 1.01}Ce{sub 0.13}{sup 3+}Ce{sub 0.19}{sup 4+}U{sub 0.52}Hf{sub 0.18})(Ti{sub 1.95}Hf{sub 0.05})O{sub 7} (with U/(U+Hf) (in the AB sites) = 0.74) and (Ca{sub 0.91}Ce{sub 0.09})(Ce{sub 0.08}{sup 3+}U{sub 0.26}Hf{sub 0.66}Ti{sub 0.01})Ti{sub 2.00}O{sub 7} (with U/(U+Hf) = 0.28) respectively. A single pyrochlore ((Ca,U,Hf){sub 2}Ti{sub 2}O{sub 7}) phase may be synthesized at 1350 C if the ratio of U/(U+Hf) is greater than 0.72, and a single zirconolite (Ca(Hf,U)Ti{sub 2}O{sub 7}) phase may be synthesized at 1350 C if the ratio of U/(U+Hf) is less than 0.28. An amorphous leached layer that is rich in Ti and Hf forms on the surface after the ceramics has been leached in pH 4 buffered solution. The thickness of the layer ranges from 5 nm to 15 nm. It is suggested that under these conditions, the leached layer functions as a protective layer, and reduces the leaching rate over time.

  14. Subduction Controls of Hf and Nd Isotopes in Lavas of the Aleutian Island Arc

    Energy Technology Data Exchange (ETDEWEB)

    Yogodzinski, Gene; Vervoort, Jeffery; Brown, Shaun Tyler; Gerseny, Megan

    2010-08-29

    The Hf and Nd isotopic compositions of 71 Quaternary lavas collected from locations along the full length of the Aleutian island arc are used to constrain the sources of Aleutian magmas and to provide insight into the geochemical behavior of Nd and Hf and related elements in the Aleutian subduction-magmatic system. Isotopic compositions of Aleutian lavas fall approximately at the center of, and form a trend parallel to, the terrestrial Hf-Nd isotopic array with {var_epsilon}{sub Hf} of +12.0 to +15.5 and {var_epsilon}{sub Nd} of +6.5 to +10.5. Basalts, andesites, and dacites within volcanic centers or in nearby volcanoes generally all have similar isotopic compositions, indicating that there is little measurable effect of crustal or other lithospheric assimilation within the volcanic plumbing systems of Aleutian volcanoes. Hafnium isotopic compositions have a clear pattern of along-arc increase that is continuous from the eastern-most locations near Cold Bay to Piip Seamount in the western-most part of the arc. This pattern is interpreted to reflect a westward decrease in the subducted sediment component present in Aleutian lavas, reflecting progressively lower rates of subduction westward as well as decreasing availability of trench sediment. Binary bulk mixing models (sediment + peridotite) demonstrate that 1-2% of the Hf in Aleutian lavas is derived from subducted sediment, indicating that Hf is mobilized out of the subducted sediment with an efficiency that is similar to that of Sr, Pb and Nd. Low published solubility for Hf and Nd in aqueous subduction fluids lead us to conclude that these elements are mobilized out of the subducted component and transferred to the mantle wedge as bulk sediment or as a silicate melt. Neodymium isotopes also generally increase from east to west, but the pattern is absent in the eastern third of the arc, where the sediment flux is high and increases from east to west, due to the presence of abundant terrigenous sediment in the

  15. Microstructure and Elevated Temperature Properties of a Refractory TaNbHfZrTi Alloy

    Science.gov (United States)

    2012-01-24

    alloy was prepared by vacuum arc melting of the equimolar mixtures of the corresponding elements. Titanium, zirconium, and hafnium were in the form of...AND ELEVATED TEMPERATURE PROPERTIES OF A REFRACTORY TaNbHfZrTi ALLOY (POSTPRINT) 5a. CONTRACT NUMBER In-house 5b. GRANT NUMBER 5c. PROGRAM...6260-2. 14. ABSTRACT Compression properties of a refractory multicomponent alloy , Ta20Nb20Hf20Zr20Ti20, were determined in the temperature range

  16. The Instagram: A Novel Sounding Technique for Enhanced HF Propagation Advice

    Science.gov (United States)

    2010-05-01

    The Instagram : A Novel Sounding Technique for Enhanced HF Propagation Advice Rod I. Barnes, G. Fred Earl Riverside Research Organization Rosslyn...low transmit powers, is reduced over conventional methods by up to three orders of magnitude leading to the term ‘ Instagram ’. The technique is...TYPE 3. DATES COVERED 00-00-2010 to 00-00-2010 4. TITLE AND SUBTITLE The Instagram : A Novel Sounding Technique for Enhanced HF Propagation Advice

  17. High-reflectivity HfO2/SiO2 ultraviolet mirrors.

    Science.gov (United States)

    Torchio, Philippe; Gatto, Alexandre; Alvisi, Marco; Albrand, Gérard; Kaiser, Norbert; Amra, Claude

    2002-06-01

    High-reflectivity dense multilayer coatings were produced for the ultraviolet spectral region. Thin-film single layers and UV mirrors were deposited by ion plating and plasma ion-assisted deposition high-energetic technologies. Optical characterizations of HfO2 and SiO2 single layers are made. The optical constants obtained for these two materials are presented. HfO2 and SiO2 mirrors with a reflectance of approximately 99% near 250 nm are reported.

  18. Soft Magnetic Thin Films FeCoHfO for High-Frequency Noise Suppression Applications

    Institute of Scientific and Technical Information of China (English)

    LU Guang-Duo; ZHANG Huai-Wu; TANG Xiao-Li

    2010-01-01

    @@ A series of FeCoHfO films were fabricated by dc magnetron reactive sputtering at varying partial pressure of oxygen(Po2)from 0 to 11.7%,and the electrical and magnetic properties of films have been studied.It is shown that optimal Fe43.29 Co19.51 Hf7.49O29.71 films with desired properties can be obtained when the films were prepared under Po2 = 5.1%.

  19. Creation of Artificial Ionospheric Layers Using High-Power HF Waves

    Science.gov (United States)

    2010-01-30

    Program ( HAARP ) transmitter in Gakona, Alaska. The HF- driven ionization process is initiated near the 2nd electron gyroharmonic at 220 km altitude in...the 3.6 MW High-Frequency Active Auroral Program ( HAARP ) transmitter in Gakona, Alaska. The HF-driven ionization process is initiated near the 2nd...Maine. USA. Copyright 2010 by the American Geophysical Union. 0094-8276/I0/2009GLO41895SO5.0O Research Program ( HAARP ) transmitter facility, however

  20. Characterization of Ionosphere Waveguide Propagation by Monitoring HAARP HF Transmissions in Antarctica

    Science.gov (United States)

    2015-04-17

    AFRL-AFOSR-UK-TR-2015-0024 CHARACTERIZATION OF IONOSPHERE WAVEGUIDE PROPAGATION BY MONITORING HAARP HF TRANSMISSIONS IN ANTARCTICA *Yuri M...31 December 2014 4. TITLE AND SUBTITLE CHARACTERIZATION OF IONOSPHERE WAVEGUIDE PROPAGATION BY MONITORING HAARP HF TRANSMISSIONS IN ANTARCTICA 5a...investigating the possibility of exciting the ionospheric interlayer duct channel using powerful radiation from the heaters HAARP (Alaska, USA) and EISCAT

  1. Longitudinal Plasmoid in High-Speed Vortex Gas Flow Created by Capacity HF Discharge

    Science.gov (United States)

    2010-10-28

    instrumentation will be used in this Project to study plasma and gas flow parameters, including new shadow device with excimer KrF laser, MW...vortex decay (attenuation) by HF plasma. The additional experiments with small helium jet injection prove the conclusion about vortex attenuation by a...equilibrium HF plasma. Plasma and airflow parameters are measured by different diagnostic instrumentation including shadow optical device with excimer

  2. Electron scattering cross sections with HF, OH, NH and CH molecules

    Energy Technology Data Exchange (ETDEWEB)

    Joshipura, K.N. [Sardar Patel Univ., Vallabh Vidyanagar (India). Dept. of Physics; Vinodkumar, M. [Sardar Patel Univ., Vallabh Vidyanagar (India). Dept. of Physics

    1997-01-20

    Total cross sections including elastic scattering, electronic excitation-ionisation and the dipole rotational excitation are calculated for electron impact on HF, OH, NH, and CH molecules. The additivity rules as well as single-centre expansion are employed for this purpose. A comparison was possible for the e-HF system only. Our results are expected to be good at intermediate to high energies (>50 eV). (orig.).

  3. Ultrathin Hf0.5Zr0.5O2 Ferroelectric Films on Si.

    Science.gov (United States)

    Chernikova, Anna; Kozodaev, Maksim; Markeev, Andrei; Negrov, Dmitrii; Spiridonov, Maksim; Zarubin, Sergei; Bak, Ohheum; Buragohain, Pratyush; Lu, Haidong; Suvorova, Elena; Gruverman, Alexei; Zenkevich, Andrei

    2016-03-23

    Because of their immense scalability and manufacturability potential, the HfO2-based ferroelectric films attract significant attention as strong candidates for application in ferroelectric memories and related electronic devices. Here, we report the ferroelectric behavior of ultrathin Hf0.5Zr0.5O2 films, with the thickness of just 2.5 nm, which makes them suitable for use in ferroelectric tunnel junctions, thereby further expanding the area of their practical application. Transmission electron microscopy and electron diffraction analysis of the films grown on highly doped Si substrates confirms formation of the fully crystalline non-centrosymmetric orthorhombic phase responsible for ferroelectricity in Hf0.5Zr0.5O2. Piezoresponse force microscopy and pulsed switching testing performed on the deposited top TiN electrodes provide further evidence of the ferroelectric behavior of the Hf0.5Zr0.5O2 films. The electronic band lineup at the top TiN/Hf0.5Zr0.5O2 interface and band bending at the adjacent n(+)-Si bottom layer attributed to the polarization charges in Hf0.5Zr0.5O2 have been determined using in situ X-ray photoelectron spectroscopy analysis. The obtained results represent a significant step toward the experimental implementation of Si-based ferroelectric tunnel junctions.

  4. ELF/VLF wave generation from the beating of two HF ionospheric heating sources

    Science.gov (United States)

    Cohen, M. B.; Moore, R. C.; Golkowski, M.; Lehtinen, N. G.

    2012-12-01

    It is well established that Extremely Low Frequency (ELF, 0.3-3 kHz) and Very Low Frequency (VLF, 3-30 kHz) radio waves can be generated via modulated High Frequency (HF, 3-10 MHz) heating of the lower ionosphere (60-100 km). The ionospheric absorption of HF power modifies the conductivity of the lower ionosphere, which in the presence of natural currents such as the auroral electrojet, creates an `antenna in the sky.' We utilize a theoretical model of the HF to ELF/VLF conversion and the ELF/VLF propagation, and calculate the amplitudes of the generated ELF/VLF waves when two HF heating waves, separated by the ELF/VLF frequency, are transmitted from two adjacent locations. The resulting ELF/VLF radiation pattern exhibits a strong directional dependence (as much as 15 dB) that depends on the physical spacing of the two HF sources. This beat wave source can produce signals 10-20 dB stronger than those generated using amplitude modulation, particularly for frequencies greater than 5-10 kHz. We evaluate recent suggestions that beating two HF waves generates ELF/VLF waves in the F-region (>150 km), and conclude that those experimental results may have misinterpreted, and can be explained strictly by the much more well established D region mechanism.

  5. Superconductivity in HfTe5 across weak to strong topological insulator transition induced via pressures.

    Science.gov (United States)

    Liu, Y; Long, Y J; Zhao, L X; Nie, S M; Zhang, S J; Weng, Y X; Jin, M L; Li, W M; Liu, Q Q; Long, Y W; Yu, R C; Gu, C Z; Sun, F; Yang, W G; Mao, H K; Feng, X L; Li, Q; Zheng, W T; Weng, H M; Dai, X; Fang, Z; Chen, G F; Jin, C Q

    2017-03-16

    Recently, theoretical studies show that layered HfTe5 is at the boundary of weak &strong topological insulator (TI) and might crossover to a Dirac semimetal state by changing lattice parameters. The topological properties of 3D stacked HfTe5 are expected hence to be sensitive to pressures tuning. Here, we report pressure induced phase evolution in both electronic &crystal structures for HfTe5 with a culmination of pressure induced superconductivity. Our experiments indicated that the temperature for anomaly resistance peak (Tp) due to Lifshitz transition decreases first before climbs up to a maximum with pressure while the Tp minimum corresponds to the transition from a weak TI to strong TI. The HfTe5 crystal becomes superconductive above ~5.5 GPa where the Tp reaches maximum. The highest superconducting transition temperature (Tc) around 5 K was achieved at 20 GPa. Crystal structure studies indicate that HfTe5 transforms from a Cmcm phase across a monoclinic C2/m phase then to a P-1 phase with increasing pressure. Based on transport, structure studies a comprehensive phase diagram of HfTe5 is constructed as function of pressure. The work provides valuable experimental insights into the evolution on how to proceed from a weak TI precursor across a strong TI to superconductors.

  6. Resistive switching characteristics of Pt/TaOx/HfNx structure and its performance improvement

    Directory of Open Access Journals (Sweden)

    Qigang Zhou

    2013-03-01

    Full Text Available The refractory transition metal nitride (TMN film Hafnium nitride (HfNx was successfully prepared on silicon-based substrates as bottom electrodes for resistive random access memory (RRAM cells in Pt (top/metal oxide/ HfNx (bottom sandwich structure. The reproducible resistive switching (RS characteristics of the memory cells were studied systematically for RRAM applications. The advantages of adopting HfNx instead of Pt as bottom electrode material were demonstrated, including the improvement of the low resistive state value, the RS endurance and the uniformity of RS parameters. The composition and chemical bonding states of the prepared HfNx was analyzed by X-ray photoelectron spectroscopy (XPS technique. The nitrogen content in the HfNx and the Gibbs free energy of the corresponding metal oxide formation has great influences on the RS properties. The oxygen reservoir ability and diffusion barrier effect of the HfNx play a key role in the RS performance improvement of the RRAM devices.

  7. First-principles calculations of adhesion, bonding and magnetism of the Fe/HfC interface

    Energy Technology Data Exchange (ETDEWEB)

    Si Abdelkader, H., E-mail: hayet.siabdelkader@mail.univ-tlemcen.dz [Laboratoire d' Etude et Prediction des Materiaux, Unite de Recherche Materiaux et Energies Renouvelables. LEPM-URMER. Universite de Tlemcen, Tlemcen 13000 (Algeria); Faraoun, H.I. [Laboratoire d' Etude et Prediction des Materiaux, Unite de Recherche Materiaux et Energies Renouvelables. LEPM-URMER. Universite de Tlemcen, Tlemcen 13000 (Algeria)

    2012-12-15

    First-principles plane-wave pseudopotential calculations of the adhesion, bonding and magnetism of the interface between the ferromagnetic bcc Fe and non-magnetic HfC are performed. The work of adhesion for C- and Hf-site Fe/HfC interfaces is calculated. High adhesion at C-site interface is found and Fe-C polar covalent bonds are formed across the interface. The magnetic moments of Fe atoms at interface are increased in both interfaces. The effect of the magnetism on the electronic structure of Fe/HfC interface is also investigated. It is shown that the change in band of majority-spin leads to enhance the magnetic moment of Fe. - Highlights: Black-Right-Pointing-Pointer Adhesion, electronic and magnetism of Fe(110)/HfC(100) interface are studied. Black-Right-Pointing-Pointer High adhesion at C-site interface is found and Fe-C polar covalent bonds are formed across the interface. Black-Right-Pointing-Pointer The magnetic moments of interfacial Fe atoms are increased in both C-site and Hf-site interfaces.

  8. Hf, Zr, and REE partition coefficients between ilmenite and liquid - Implications for lunar petrogenesis

    Science.gov (United States)

    Nakamura, Y.; Fujimaki, H.; Nakamura, N.; Tatsumoto, M.; Mckay, G. A.

    1986-01-01

    Partition coefficients (D) between ilmenite and coexisting liquid were determined under near-lunar conditions for Hf, Zr, and REE. Through isotope dilution analysis, ilmenite D values of 0.41 and 0.33 were obtained for Hf and Zr respectively, values significantly lower than those of ilmenite from a kimberlite megacryst. Partition coefficients of REE for the synthesized ilmenite are slightly smaller than those of ilmenite from the kimberlite megacryst, and the lunar (Lu) partition coefficient is 0.056. These results suggest that ilmenite was significant in the lunar-Hf evolution of lunar mare basalts. Using lunar and Hf D values for ilmenite, the Lu-Hf evolution of lunar cumulates and the coexisting magma was examined for various crystallization sequences. The Lu-Hf variation trend of most high-Ti mare basalts is explained by a small degree of partial cumulate melting, though a higher degree is required to explain the variation of very low-Ti basalts, green glass, and Apollo 12 low-Ti basalts. Apollo 15 low-Ti basalts may require chromite crystallization as well.

  9. Partition coefficients of Hf, Zr, and REE between phenocrysts and groundmasses

    Science.gov (United States)

    Fujimaki, H.; Tatsumoto, M.; Aoki, K.-I.

    1984-01-01

    Partition coefficients of Hf, Zr, and REE between olivine, orthopyroxene, clinopyroxene, plagioclase, garnet, amphibole, ilmenite, phlogopite, and liquid are presented. Samples consist of megacrysts in kimberlite, phenocrysts in alkaline basalts, tholeiitic basalts and andesitic to dacitic rocks, and synthetic garnet and clinopyroxene in Hawaiian tholeiites. The Hf-Lu and Zr-Lu elemental fractionations are as large as the Lu-Sm or Lu-Nd fractionation. The Hf and Zr partition coefficients between mafic phenocrysts and liquids are smaller than the Lu partition coefficients, but are similar to the Nd or Sm partition coefficients. The Hf and Zr partition coefficients between ilmenite, phlogopite, and liquid are larger than the Lu partition coefficients for these minerals and their corresponding liquids. The Hf-Zr elemental fractionation does not occur except for extreme fractionation involving Zr-minerals and extremely low fO2. These data have an important bearing on chronological and petrogenetic tracer studies involving the Lu-Hf isotopic system.

  10. Power-Stepped HF Cross-Modulation Experiments: Simulations and Experimental Observations

    Science.gov (United States)

    Greene, S.; Moore, R. C.

    2014-12-01

    High frequency (HF) cross modulation experiments are a well established means for probing the HF-modified characteristics of the D-region ionosphere. The interaction between the heating wave and the probing pulse depends on the ambient and modified conditions of the D-region ionosphere. Cross-modulation observations are employed as a measure of the HF-modified refractive index. We employ an optimized version of Fejer's method that we developed during previous experiments. Experiments were performed in March 2013 at the High Frequency Active Auroral Research Program (HAARP) observatory in Gakona, Alaska. During these experiments, the power of the HF heating signal incrementally increased in order to determine the dependence of cross-modulation on HF power. We found that a simple power law relationship does not hold at high power levels, similar to previous ELF/VLF wave generation experiments. In this paper, we critically compare these experimental observations with the predictions of a numerical ionospheric HF heating model and demonstrate close agreement.

  11. Ergonomics action research II: a framework for integrating HF into work system design.

    Science.gov (United States)

    Neumann, W P; Village, J

    2012-01-01

    This paper presents a conceptual framework that can support efforts to integrate human factors (HF) into the work system design process, where improved and cost-effective application of HF is possible. The framework advocates strategies of broad stakeholder participation, linking of performance and health goals, and process focussed change tools that can help practitioners engage in improvements to embed HF into a firm's work system design process. Recommended tools include business process mapping of the design process, implementing design criteria, using cognitive mapping to connect to managers' strategic goals, tactical use of training and adopting virtual HF (VHF) tools to support the integration effort. Consistent with organisational change research, the framework provides guidance but does not suggest a strict set of steps. This allows more adaptability for the practitioner who must navigate within a particular organisational context to secure support for embedding HF into the design process for improved operator wellbeing and system performance. There has been little scientific literature about how a practitioner might integrate HF into a company's work system design process. This paper proposes a framework for this effort by presenting a coherent conceptual framework, process tools, design tools and procedural advice that can be adapted for a target organisation.

  12. Influence of cointercalated HF on the electrochemical behavior of highly fluorinated graphite

    Science.gov (United States)

    Nakajima, Tsuyoshi; Gupta, Vinay; Ohzawa, Yoshimi; Groult, Henri; Mazej, Zoran; Žemva, Boris

    Highly fluorinated graphite was prepared at room temperature using high oxidation state transition metal complex fluoride (K 2PdF 6, K 2MnF 6, K 2NiF 6 or KAgF 4) and elemental fluorine under pressure ((5.9-11.8) ×10 5 Pa) in anhydrous liquid HF (aHF). The composition of the fluorinated graphite samples ranged from C 1.1F to C 1.9F containing small amounts of HF. IR absorption spectra revealed that stage 1 phase of C xF contained several different phases with planar (sp 2) and puckered (sp 3) graphene layers. Electrochemical discharge of the fluorinated graphite showed that profile of discharge potential and discharge capacity varied depending on the amount of cointercalated HF. The C xF samples with less amounts of HF and HF 2δ- had relatively flat discharge potentials and large discharge capacities. The discharge capacity reached 500-600 mAh/g in 1 mol/dm 3 LiClO 4-propylene carbonate solution at 25 °C. Chemical diffusion coefficients of Li + ion in the intermediate discharge products were (4.4-13) ×10 -12 cm 2/s from impedance measurement.

  13. Experimental and numerical investigation of the refinement of Hf by EBM

    Science.gov (United States)

    Donchev, Veliko; Vutova, Katia; Vassileva, Vania

    2014-05-01

    Electron beam melting (EBM) in vacuum is one of the most promising technologies for refining and recycling of metals that react with oxygen when heated. Hf is such a metal. Pure Hf (with a small content of gas and metal impurities) is needed for a variety of applications in the aerospace industry and metallurgy, in the production of components of nuclear reactors, microprocessors, optical components etc. We conducted experiments with the ELIT-60 equipment on Hf ingots at electron beam powers of 12, 15, 17 kW and obtained data about the concentration of impurities by the ICP-MS method. For further understanding and optimizing the Hf refining processes, a non-stationary heat model was applied for numerical simulation of the heat transfer processes. Simulation data about the liquid pool variation during the e-beam treatment was thus obtained. The flatness of the crystallization front shape, which is connected to the structure quality, was investigated by optimization criteria related to the curvature of the liquid/solid boundary curve. We also describe an algorithm for calculation of the criteria. One of the criteria was applied to EBM of Hf for different electron beam powers; the results obtained were confirmed by the experimental data. Combining experimental, theoretical and simulation results, a proper technological regime is proposed for better Hf refining.

  14. A new wideband HF technique for MHz-bandwidth spread-spectrum radio communications

    Science.gov (United States)

    Perry, B. D.

    1983-09-01

    The one-way results are seen as demonstrating that equalized MHz-bandwidth skywave HF channels can be achieved using long-range one-hop F-layer propagation paths. It has thus become possible to use direct-sequence pseudo-noise or coherent fast-frequency-hop signaling at HF with processing gains of several orders of magnitude for teletype data rates. Possibilities are seen for using the spread spectrum in covert and/or jam-resistant communications. What is more, the equalized wideband HF channel is not subject to the fading caused by multiple propagation modes; as a consequence, it is substantially more reliable than the traditional narrow-band HF channel. Conversely, reliability comparable to traditional HF can be attained at greatly reduced signal margins. Since the time stability of the wideband HF channel is of the order of 10 s, very little channel-transmission time is needed for initializing and maintaining the equalizer. It is noted that probe signals similar to the channel-measuring waveform described here or spread-spectrum training sequences at the beginning of each message are adequate. Results from the 1982 two-way experimentation show that N(omega) is not reciprocal between terminals 2000 km apart.

  15. Finishing and Commissioning the New Arecibo HF Facility

    Science.gov (United States)

    Sulzer, M. P.; Gonzalez, S. A.

    2011-12-01

    The imminent completion of the major tasks in the construction of the New Arecibo HF facility means that we must verify that the components are working as intended. The antenna system and the transmitters must be separately commissioned before they can be connected together so that we an be sure it will provide 83 dbW at 8.175 MHz, and 80 dbW at 5.1 MHz. The antenna system will be ready for initial testing in September. It Illuminates the 305 meter dish using dipoles near the surface of the dish transmitting upward to a wire mesh sub-reflector. There are three crossed dipoles for each of the two frequencies. The dipoles are supported on towers mounted on concrete pads underneath the dish. Each dipole element is connected to a transmitter through a three inch coax line. The tower foundations are nearly complete, and the towers will be erected in early September, and we expect to have at least one crossed dipole in place for initial testing by the end of September. We will need to make some measurements on the antenna system to ensure that it meets our requirements. One requirement is to match the antenna impedance to the transmission line and the transmitter closely enough to meet the transmitter specifications, the closer, the better. We have additional requirements; for example, it is necessary for efficient use of the facility that the polarization be close to circular. In most experiments, we want O mode excitation. If we were to transmit linear only half the power would reach the reflection height. The symmetry of the system assures that most of the conditions for achieving accurate circular polarization are met, but one condition is not: that exciting the transmitters driving the orthogonal elements at 90 degrees assures 90 degree separation in the corresponding antenna currents. One of the dipoles of each pair points toward the center of the array. If we think of the three crossed dipoles as consisting of a reference and two that are excited relative to it

  16. Low Threshold Voltage and High Mobility N-Channel Metal-Oxide-Semiconductor Field-Effect Transistor Using Hf-Si/HfO2 Gate Stack Fabricated by Gate-Last Process

    Science.gov (United States)

    Ando, Takashi; Hirano, Tomoyuki; Tai, Kaori; Yamaguchi, Shinpei; Yoshida, Shinichi; Iwamoto, Hayato; Kadomura, Shingo; Watanabe, Heiji

    2010-01-01

    Systematic characterization of Hf-Si/HfO2 gate stacks revealed two mobility degradation modes. One is carrier scattering by fixed charges and/or trapped charges induced by the crystallization in the thick HfO2 case (inversion oxide thickness, Tinv> 1.6 nm). The other is the Hf penetration into the interfacial layer with the Si substrate in the thin HfO2 case (Tinv< 1.6 nm) for the Hf-rich electrode. It was demonstrated that careful optimization of the HfO2 thickness and the Hf-Si composition can suppress both modes. As a result, a high electron mobility equivalent to that of n+polycrystalline silicon (poly-Si)/SiO2 (248 cm2 V-1 s-1 at Eeff=1 MV/cm) was obtained at Tinv of 1.47 nm. Moreover, the effective work function of the optimized Hf-Si/HfO2 gate stack is located within 50 mV from the Si band edge (Ec). An extremely high Ion of 1165 µA/µm (at Ioff = 81 nA/µm) at Vdd=1.0 V was demonstrated for a 45 nm gate n-channel metal-oxide-semiconductor field-effect transistor (n-MOSFET) without strain enhanced technology.

  17. Low modulus Ti–Nb–Hf alloy for biomedical applications

    Energy Technology Data Exchange (ETDEWEB)

    González, M., E-mail: Marta.Gonzalez.Colominas@upc.edu [Department of Materials Science and Metallurgy, Universitat Politècnica de Catalunya (UPC), Avda. Diagonal 647, 08028 Barcelona (Spain); Materials Science, Elisava Escola Superior de Disseny i Enginyeria de Barcelona, La Rambla 30-32, 08002 Barcelona (Spain); Peña, J. [Department of Materials Science and Metallurgy, Universitat Politècnica de Catalunya (UPC), Avda. Diagonal 647, 08028 Barcelona (Spain); Materials Science, Elisava Escola Superior de Disseny i Enginyeria de Barcelona, La Rambla 30-32, 08002 Barcelona (Spain); Gil, F.J.; Manero, J.M. [Department of Materials Science and Metallurgy, Universitat Politècnica de Catalunya (UPC), Avda. Diagonal 647, 08028 Barcelona (Spain); Ciber-BBN (Spain)

    2014-09-01

    β-Type titanium alloys with a low elastic modulus are a potential strategy to reduce stress shielding effect and to enhance bone remodeling in implants used to substitute failed hard tissue. For biomaterial application, investigation on the mechanical behavior, the corrosion resistance and the cell response is required. The new Ti25Nb16Hf alloy was studied before and after 95% cold rolling (95% C.R.). The mechanical properties were determined by tensile testing and its corrosion behavior was analyzed by potentiostatic equipment in Hank's solution at 37 °C. The cell response was studied by means of cytotoxicity evaluation, cell adhesion and proliferation measurements. The stress–strain curves showed the lowest elastic modulus (42 GPa) in the cold worked alloy and high tensile strength, similar to that of Ti6Al4V. The new alloy exhibited better corrosion resistance in terms of open circuit potential (E{sub OCP}), but was similar in terms of corrosion current density (i{sub CORR}) compared to Ti grade II. Cytotoxicity studies revealed that the chemical composition of the alloy does not induce cytotoxic activity. Cell studies in the new alloy showed a lower adhesion and a higher proliferation compared to Ti grade II presenting, therefore, mechanical features similar to those of human cortical bone and, simultaneously, a good cell response. - Highlights: • Presents low elastic modulus and high strength and elastic deformability. • Exhibits good biocompatibility in terms of cytotoxicity and cell response. • Corrosion resistance of this alloy is good, similar to that of Ti grade II. • Potential candidate for implants used to substitute failed hard tissue.

  18. Interstitial solid solution Hf{sub 5}Ga{sub x}Sn{sub 3} (x = 0-1)

    Energy Technology Data Exchange (ETDEWEB)

    Voznyak, I., E-mail: iravoznyak@gmail.com [Department of Inorganic Chemistry, Ivan Franko National University of Lviv, Kyryla i Mefodiya St. 6, 79005 Lviv (Ukraine); Tokaychuk, Ya. [Department of Inorganic Chemistry, Ivan Franko National University of Lviv, Kyryla i Mefodiya St. 6, 79005 Lviv (Ukraine); Hlukhyy, V.; Faessler, T.F. [Department of Chemistry, Technische Universitaet Muenchen, Lichtenbergstr. 4, 85747 Garching (Germany); Gladyshevskii, R. [Department of Inorganic Chemistry, Ivan Franko National University of Lviv, Kyryla i Mefodiya St. 6, 79005 Lviv (Ukraine)

    2012-01-25

    Highlights: Black-Right-Pointing-Pointer Formation of an interstitial solid solution Hf{sub 5}Ga{sub x}Sn{sub 3} (x = 0-1) based on the binary compound Hf{sub 5}Sn{sub 3} was established at 600 Degree-Sign C. Black-Right-Pointing-Pointer The Ga atoms occupy [Hf{sub 6}] octahedral interstices (Wyckoff position 2b) up to the composition Hf{sub 5}GaSn{sub 3}, which represents a Hf{sub 5}CuSn{sub 3}-type structure (ordered derivative of Ti{sub 5}Ga{sub 4}). Black-Right-Pointing-Pointer The cell parameters and cell volume increase with increasing gallium content. Black-Right-Pointing-Pointer The coordination number of the hafnium atoms in Wyckoff position 6g is reduced from 15 (Hf1Sn{sub 5}Hf{sub 10} for Hf{sub 5}Sn{sub 3}) to 11 (Hf1Sn{sub 5}Ga{sub 2}Hf{sub 4} for Hf{sub 5}GaSn{sub 3}). - Abstract: Formation of an interstitial solid solution Hf{sub 5}Ga{sub x}Sn{sub 3} (x = 0-1) based on the binary compound Hf{sub 5}Sn{sub 3} (structure type Mn{sub 5}Si{sub 3}, Pearson symbol hP16, space group P6{sub 3}/mcm, a = 8.36562(6), c = 5.70775(4) Angstrom-Sign from X-ray powder diffraction) was established at 600 Degree-Sign C. The crystal structure (structure type Hf{sub 5}CuSn{sub 3}, ordered derivative of Ti{sub 5}Ga{sub 4}, hP18, P6{sub 3}/mcm) was refined on X-ray single-crystal diffraction data for three compositions: Hf{sub 5}Ga{sub 0.16(3)}Sn{sub 3} (a = 8.3288(12), c = 5.6988(11) Angstrom-Sign ), Hf{sub 5}Ga{sub 0.53(2)}Sn{sub 3} (a = 8.4205(12), c = 5.7655(12) Angstrom-Sign ) and Hf{sub 5}GaSn{sub 3} (a = 8.5564(12), c = 5.7859(12) Angstrom-Sign ). The Ga atoms occupy Wyckoff position 2b at the centres of Hf{sub 6} octahedral interstices.

  19. Synthesis of metallic glasses and metallic glass based composites in the Cu-Mo-Hf system by ion beam mixing

    Institute of Scientific and Technical Information of China (English)

    BAI Xue; WANG TongLe; CUI YuanYuan; DING Ning; LI JiaHao; LIU BaiXin

    2012-01-01

    Single-phase and dual-phase metallic glasses as well as metallic glass based composites were synthesized in the Cu-Mo-Hf ternary metal system by 200 keV xenon ion beam mixing of far-from-equilibrium.It was found that Mo-Hf-based and Cu-Mo-based single-phase metallic glasses could be obtained at compositions around Cu17Mo20Hf63 and Cu34Mo57Hf9,respectively.Interestingly,at the nearly equal-atomic stoichiometry of Cu38Mo31Hf31,a dual-phase Cu-Mo-Hf metallic glass,consisting both of the Mo-Hf-based and Cu-Mo-based phases,was first obtained at relatively low irradiation doses ranging from (1-5)×1015 Xe+/cm2,and a single-phase metallic glass was eventually obtained at a dose of 7×1015 Xe+/cm2.In addition,two glass-based composites were obtained at the compositions of Cu14Mo62Hf24 and Cu77Mo14Hf9,and they consisted of the Mo-Hf based and Cu-Mo based metallic glasses,dissolved with some uniformly distributed BCC Mo-based and FCC Cu-based crystalline solid solutions,respectively.The formation mechanism of the above described non-equilibrium alloy phases was also discussed in terms of the atomic collision theory.

  20. Tracing Proterozoic arc mantle Hf isotope depletion of southern Fennoscandia through coupled zircon U-Pb and Lu-Hf isotopes

    Science.gov (United States)

    Petersson, Andreas; Bjärnborg, Karolina; Scherstén, Anders; Gerdes, Axel; Næraa, Tomas

    2017-07-01

    Constraints on the composition of the depleted mantle Sm-Nd and Lu-Hf crust formation ages have a long history of scientific debate. When calculating mantle extraction ages, and constructing crustal growth models, a linear evolution of incompatible trace elements in a depleted mantle since > 4 Ga is routinely used. Mantle depletion however varies regionally and over time and subduction of sediments and oceanic crust renders a mantle-wedge variously enriched relative to a modelled depleted mantle. Here we show that primitive mantle-derived subduction related gabbroic intrusions from southern Fennoscandia have Hf isotope compositions that are enriched relative to a MORB-like linear depleted mantle evolution curve. Extrapolation of primitive Paleoproterozoic gabbro suites enables the construction of a regional mantle evolution curve, providing improved constraints on model ages, crustal residence times and the fraction of juvenile versus reworked continental crust. Convergent margins are assumed to be one of the main sites of continental crust growth, and using an overly depleted mantle source yield model ages that are too old, and hence cumulative crustal growth models show too much crust generation early in the Earth's history. The approach of using the Hf isotope composition of zircon from primitive subduction related gabbroic intrusions as a proxy for mantle Hf isotope composition, piloted in this study, can be applied to other convergent margins.

  1. Contamination status and possibility of toxic effects of co-planar polychlorinated biphenyls, polycyclic aromatic hydrocarbons, and dichlorodiphenyltrichloroethane in large japanese field mouse (Apodemus speciosus) collected from Hokkaido and Aomori.

    Science.gov (United States)

    Mizukawa, Hazuki; Ikenaka, Yoshinori; Nakayama, Shouta M M; Sakamoto, Kentaro Q; Fujita, Shoichi; Ishizuka, Mayumi

    2014-08-01

    Contamination levels of coplanar polychlorinated biphenyls (Co-PCBs), polycyclic aromatic hydrocarbons (PAHs), and dichlorodiphenyltrichloroethane (DDTs) were measured in the entire body of the large Japanese field mouse (Apodemus speciosus) collected from Hokkaido (Ishikari and Rankoshi) and Aomori prefecture (Takko) in Japan. Higher concentrations of PCBs including Co-PCBs, were observed in the mice collected from Ishikari than those from Rankoshi. The concentration of PAHs in the soil from Ishikari was also higher than that in the other sampling sites. The findings suggest that Ishikari is the most polluted area, probably because of human activities, depending on the population distribution. However, the observed contaminant levels were extremely lower compared to those in previous studies. The ratio of testis weight to body weight (TW/BW) was the lowest in the mice collected from Ishikari, which is the area contaminated with PAHs and p,p'-dichlorodiphenyldichloroethylene (DDE). However, the serum testosterone levels of mice from the Ishikari area were higher than those from the non-contaminated other areas although no significant differences. Previous studies have shown that a low-level exposure to dioxin related compounds (DRCs) disturbances in sexual function, resulting in the production of testosterone. This study showed that POPs exposure is one of the possibility of the high testosterone concentration in the mice of the Ishikari area in addition to a cause of biological and environmental factors such as habitat density, age, temperatures and/or food riches.

  2. HfO{sub 2} dielectric thickness dependence of electrical properties in graphene field effect transistors with double conductance minima

    Energy Technology Data Exchange (ETDEWEB)

    Zhang, Cheng; Xie, Dan, E-mail: xiedan@mail.tsinghua.edu.cn; Xu, Jian-Long; Sun, Yi-Lin; Dai, Rui-Xuan; Li, Xian [Institute of Microelectronics, Tsinghua National Laboratory for Information Science and Technology (TNList), Tsinghua University, Beijing 100084 (China); Li, Xin-Ming [National Center for Nanoscience and Technology, Zhongguancun, Beijing 100190 (China); Zhu, Hong-Wei [School of Materials Science and Engineering, State Key Laboratory of New Ceramics and Fine Processing, Key Laboratory of Materials Processing Technology of MOE, Tsinghua University, Beijing 100084 (China); Center for Nano and Micro Mechanics, Tsinghua University, Beijing 100084 (China)

    2015-10-14

    We investigate the electrical properties in back-gated graphene field effect transistors (GFETs) with SiO{sub 2} dielectric and different thickness of high-k HfO{sub 2} dielectric. The results show that transform characteristic (I{sub ds}–V{sub gs}) curves of GFETs are uniquely W-shaped with two charge neutrality point (left and right) in both SiO{sub 2} and HfO{sub 2} dielectric (SiO{sub 2}-GFETs and HfO{sub 2}-GFETs). The gate voltage reduces drastically in HfO{sub 2}-GFETs compared with that in SiO{sub 2}-GFETs, and it becomes much smaller with the decline of HfO{sub 2} thickness. The left charge neutrality point in I{sub d}–V{sub g} curves of all HfO{sub 2}-GFETs is negative, compared to the positive ones in SiO{sub 2}-GFETs, which means that there exists n-doping in graphene with HfO{sub 2} as bottom dielectric. We speculate that this n-doping comes from the HfO{sub 2} layer, which brings fixed charged impurities in close proximity to graphene. The carrier mobility is also researched, demonstrating a decreasing trend of hole mobility in HfO{sub 2}-GFETs contrast to that in SiO{sub 2}-GFETs. In a series of HfO{sub 2}-GFETs with different HfO{sub 2} dielectric thickness, the hole mobility shows a tendency of rise when the thickness decreases to 7 nm. The possible reason might be due to the introduced impurities into HfO{sub 2} film from atomic layer deposition process, the concentration of which varies from the thickness of HfO{sub 2} layer.

  3. Early Differentiation of the Crust-Mantle System: a Hf Isotope Perspective

    Science.gov (United States)

    Scherer, E.; Munker, C.; Mezger, K.

    2001-12-01

    The Lu decay constant recently determined by Scherer et al. 2001 (i.e., 1.865 x 10-11 yr-1) agrees with the results of the two latest physical counting experiments (1.86 x 10-11 yr-1; Dalmasso et al 1992, Nir-El and Lavi 1998), but is ca. 4 percent lower than the decay constants that have been used throughout the Hf isotope literature (e.g., 1.94 x 10-11, Tatsumoto et al., 1981; 1.93 x 10-11 Sguigna et al, 1982). In addition to making Lu-Hf ages older by ca. 4 percent, the revised decay constant also shifts the calculated initial epsilon Hf values of early Archean and Hadean rocks and zircons that are used to constrain crust-mantle differentiation in the early Earth. The initial epsilon Hf values for low-Lu/Hf samples such as zircons and evolved felsic rocks shift downward by 2-4 epsilon units, primarily due to the shift in the position of the CHUR evolution curve rather than that of the samples themselves. Mafic rocks, such as komatiites have higher Lu/Hf ratios that are closer to that of CHUR and therefore their initial epsilon Hf values do not shift as much (up to 1.3 epsilon units lower or 0.4 epsilon units higher). Using the old decay constant, some early Archean rocks (e.g., Amitsoq gneisses; Vervoort et al., 1996, Vervoort and Blichert-Toft, 1999) seemed to have very high initial epsilon Hf values (up to +6), implying that the upper mantle was moderately depleted in the early Archean and that a substantial volume of crust was produced in the Hadean. However, when recalculated with the new decay constant, the data suggest that the mantle was only slightly depleted, requiring less early crust extraction, and allowing a later date for the onset of significant crust production. In contrast, the extremely low recalculated epsilon Hf values of Earth's oldest zircons (Amelin et al., 1999, Amelin et al., 2000) indicate that Earth's first crust formed at or before 4.3 Ga, and that this crust remained intact long enough (>200 million years) to evolve to such low

  4. Magnetism of coexisting rhombohedral and orthorhombic Hf{sub 2}Co{sub 11} phases in rapidly quenched Hf{sub 2}Co{sub 11}B

    Energy Technology Data Exchange (ETDEWEB)

    Musiał, A. [Institute of Molecular Physics, Polish Academy of Sciences, M. Smoluchowskiego 17, Poznań 60-179 (Poland); Nanobiomedical Centre, Adam Mickiewicz University in Poznań, Umultowska 85, Poznań 61-614 (Poland); Śniadecki, Z., E-mail: sniadecki@ifmpan.poznan.pl [Institute of Molecular Physics, Polish Academy of Sciences, M. Smoluchowskiego 17, Poznań 60-179 (Poland); Marcin, J.; Kováč, J.; Škorvánek, I. [Institute of Experimental Physics, Slovak Academy of Sciences, Watsonova 47, Košice 040 01 (Slovakia); Idzikowski, B. [Institute of Molecular Physics, Polish Academy of Sciences, M. Smoluchowskiego 17, Poznań 60-179 (Poland)

    2016-04-25

    Evolution of crystalline structure caused by heat treatment and its influence on magnetic properties of two melt-spun Hf{sub 2}Co{sub 11}B alloys in fully amorphous and partially crystalline states have been investigated. The as-cast ribbons were annealed in order to improve the hard magnetic properties by inducing the formation of nanocrystalline phases with high anisotropy. The X-ray diffraction and magnetic measurements confirmed the coexistence of two Hf{sub 2}Co{sub 11} phases, crystallizing in different structures, with the rhombohedral one showing hard magnetic properties. Annealing of fully amorphous alloy resulted in the lower coercive field in comparison to that of annealed partially crystalline ribbon. From the point of view of exchange coupling between magnetic phases and magnetic hardening, the optimum annealing temperature and time were determined to be 570 °C and 60 min, for partially crystalline sample. Annealing at 650 °C for 1 h leads to excess of the HfCo{sub 3}B{sub 2} phase above the critical value and results in a decrease in the coercive field. Isothermal annealing increases the magnetocrystalline anisotropy constant K{sub 1} from 7.52 for the as-quenched sample to 12.11 Merg/cm{sup 3} for the partially crystalline ribbon. The existence of quenched-in nanocrystals resulted in higher coercive fields, up to 3.23 kOe, after annealing. - Highlights: • Hf{sub 2}Co{sub 11}B rapidly quenched in two states: (i) amorphous, (ii) partially crystalline. • formation of nanocrystalline phases with high magnetic anisotropy. • high magnetocrystalline anisotropy constant K{sub 1} > 10 Merg/cm{sup 3} • coexistence of two Hf{sub 2}Co{sub 11} phases: (i) rhombohedral and (ii) orthorhombic.

  5. Curative effect of HF10 on liver and peritoneal metastasis mediated by host antitumor immunity

    Science.gov (United States)

    Hotta, Yoshihiro; Kasuya, Hideki; Bustos, Itzel; Naoe, Yoshinori; Ichinose, Toru; Tanaka, Maki; Kodera, Yasuhiro

    2017-01-01

    Background HF10 is a highly attenuated type 1 herpes simplex virus (HSV) with proven effective oncolytic effect. Previous investigations have demonstrated that colon cancer mice model treated with HF10 not only had better survival but were also resistant to the reimplantation of the antitumor effect mediated by host antitumor immunity. Importantly, it has also been noted that in mice with antitumors implanted on both sides of the back, an injection of HF10 on only one side strongly restrains not only the injected antitumor but also the non-injected ones. Materials and methods MC26 colon cancer cells were injected subcutaneously into the back, spleen, and intraperitoneal region of metastasis model mice. Antitumor volume and survival rate were monitored. To measure cytotoxic T lymphocytes (CTL) cytotoxicity against MC26, lymphocytes were extracted from the spleens of the peritoneal metastasis model mice as well as from the thymus of the liver metastasis model mice. The expression of interferon gamma was examined by enzyme-linked immunospot assay. Samples from the liver metastasis model mice were subjected to polymerase chain reaction to quantify the level of HSV genomes. Results HF10 was injected only on the back antitumor; however, a antitumor-suppressor effect was observed against liver and peritoneal metastases. When HF10 genome was measured, we observed lower genome on liver metastases compared to back antitumor genome quantity. CTL activity against MC26 was also observed. These results indicate that local administration of HF10 exerts a curative effect on systemic disease, mediated by host antitumor immunity. Conclusion HF10 local administration stimulates antitumor immunity to recognize antitumor-specific antigen, which then improves systemic disease. Metastatic antitumors lysis, on the other hand, appears to be mediated by the host immune system, rather than by virus-mediated direct oncolysis. PMID:28331843

  6. Effects of biased irradiation on charge trapping in HfO2 dielectric thin films

    Science.gov (United States)

    Mu, Yifei; Zhao, Ce Zhou; Lu, Qifeng; Zhao, Chun; Qi, Yanfei; Lam, Sang; Mitrovic, Ivona Z.; Taylor, Stephen; Chalker, Paul R.

    2017-09-01

    This paper reports the low-dose-rate radiation response of Al-HfO2/SiO2-Si MOS devices, in which the gate dielectric was formed by atomic layer deposition (ALD) with 5-nm equivalent oxide thickness. The degradation of the devices was characterized by a pulse capacitance-voltage (CV) and on-site radiation response technique under continuous gamma (γ) ray exposure at a relatively low dose rate of 0.116 rad (HfO2)/s. Compared with conventional CV measurements, the proposed measurements extract significant variations of flat-band voltage shift of the hafnium based MOS devices. The large flat-band voltage shift is mainly attributed to the radiation-induced oxide trapped charges, which are not readily compensated by bias-induced charges produced over the measurement timescales (for timescales less than 5 ms). A negative flat-band voltage shift up to -1.02 V was observed under a positive biased irradiation with the total dose up to 40 krad (HfO2) and with the electric field of 0.5 MV/cm. This is attributed to net positive charge generation in the HfO2 oxide layer. The generated charges are transported towards the HfO2/SiO2 interface, and then form effective trapped holes in the HfO2. Similarly, a positive flat-band voltage shift up to 1.1 V was observed from irradiation under negative bias with an electric field of -0.5 MV/cm. The positive shift is mainly due to the accumulation of trapped electrons. Analyses of the experimental results suggest that both hole and electron trapping can dominate the radiation response performance of the HfO2-based MOS devices depending upon the applied bias. It was also found there was no distinct border traps with irradiation in all cases.

  7. Early Postdischarge STOP-HF-Clinic Reduces 30-day Readmissions in Old and Frail Patients With Heart Failure.

    Science.gov (United States)

    Pacho, Cristina; Domingo, Mar; Núñez, Raquel; Lupón, Josep; Moliner, Pedro; de Antonio, Marta; González, Beatriz; Santesmases, Javier; Vela, Emili; Tor, Jordi; Bayes-Genis, Antoni

    2017-08-01

    Heart failure (HF) is associated with a high rate of readmissions within 30 days postdischarge. Strategies to lower readmission rates generally show modest results. To reduce readmission rates, we developed a STructured multidisciplinary outpatient clinic for Old and frail Postdischarge patients hospitalized for HF (STOP-HF-Clinic). This prospective all-comers study enrolled patients discharged from internal medicine or geriatric wards after HF hospitalization. The intervention involved a face-to-face early visit (within 7 days), HF nurse education, treatment titration, and intravenous medication when needed. Thirty-day readmission risk was calculated using the CORE-HF risk score. We also studied the impact of 30-day readmission burden on regional health care by comparing the readmission rate in the STOP-HF-Clinic Referral Area (∼250000 people) with that of the rest of the Catalan Health Service (CatSalut) (∼7.5 million people) during the pre-STOP-HF-Clinic (2012-2013) and post-STOP-HF-Clinic (2014-2015) time periods. From February 2014 to June 2016, 518 consecutive patients were included (age, 82 years; Barthel score, 70; Charlson index, 5.6, CORE-HF 30-day readmission risk, 26.5%). The observed all-cause 30-day readmission rate was 13.9% (47.5% relative risk reduction) and the observed HF-related 30-day readmission rate was 7.5%. The CatSalut registry included 65131 index HF admissions, with 9267 all-cause and 6686 HF-related 30-day readmissions. The 30-day readmission rate was significantly reduced in the STOP-HF-Clinic Referral Area in 2014-2015 compared with 2012-2013 (P < .001), mainly driven by fewer HF-related readmissions. The STOP-HF-Clinic, an approach that could be promptly implemented elsewhere, is a valuable intervention for reducing the global burden of early readmissions among elder and vulnerable patients with HF. Copyright © 2017 Sociedad Española de Cardiología. Published by Elsevier España, S.L.U. All rights reserved.

  8. Dual HF radar study of the subauroral polarization stream

    Directory of Open Access Journals (Sweden)

    R. A. Makarevich

    2008-01-01

    Full Text Available The dual HF radars comprising the Tasman International Geophysical Environment Radar (TIGER system often observe localized high-velocity F-region plasma flows (≥1500 m/s in the midnight sector (20:00–02:00 MLT at magnetic latitudes as low as Λ=60° S. The flow channels exhibit large variability in the latitudinal extent and electric field strength, and are similar to the subauroral polarization stream or SAPS, a plasma convection feature thought to be related to the polarization electric field due to the charge separation during substorm and storm development. In this study, the 2-D plasma drift velocity within the channel is derived for each of the two TIGER radars from the maximum velocities measured in all 16 radar beams within the latitudinally narrow channel, and the time variation of the subauroral electric field is examined near substorm onset. It is demonstrated that the flow channel often does not have a clear onset, rather it manifests differently in different phases of its evolution and can persist for at least two substorm cycles. During the growth phase the electric fields within the flow channel are difficult to distinguish from those of the background auroral convection but they start to increase near substorm onset and peak during the recovery phase, in contrast to what has been reported previously for auroral convection which peaks just before the substorm onset and falls sharply at the substorm onset. The response times to substorm onset range from −5 to +40 min and show some dependence on the substorm location with longer delays observed for substorms eastward of the radars' viewing area. The propagation velocity of the high-velocity region is also investigated by comparing the observations from the two closely-spaced TIGER radars. The observations are consistent with the notion that the polarization electric field is established with the energetic ions drifting westward and equatorward from the initial substorm

  9. Luminescence and scintillation properties of Tl- and Ce-doped Cs2HfCl6 crystals

    Science.gov (United States)

    Saeki, Keiichiro; Fujimoto, Yutaka; Koshimizu, Masanori; Nakauchi, Daisuke; Tanaka, Hironori; Yanagida, Takayuki; Asai, Keisuke

    2017-02-01

    The luminescence and scintillation properties of Tl- and Ce-doped Cs2HfCl6 crystals were investigated by photoluminescence and radioluminescence spectroscopy. In the photoluminescence spectra, emission bands of the activators were observed at 500 nm for Tl-doped Cs2HfCl6, and at 340 and 380 nm for Ce-doped Cs2HfCl6. The radioluminescence bands were observed at 405 and 430 nm for Tl- and Ce-doped Cs2HfCl6, respectively. Scintillation decay time constants for the Tl- and Ce-doped Cs2HfCl6 were smaller than those for the corresponding undoped crystals. Scintillation light yields for Tl- and Ce-doped Cs2HfCl6 were estimated to be 23,700 and 15,700 photons/MeV, respectively.

  10. The atomic structure and chemical composition of HfOx (x < 2) films prepared by ion-beam sputtering deposition

    Science.gov (United States)

    Aliev, V. S.; Gerasimova, A. K.; Kruchinin, V. N.; Gritsenko, V. A.; Prosvirin, I. P.; Badmaeva, I. A.

    2016-08-01

    Non-stoichiometric HfOx films of different chemical composition (x partial pressure in a chamber. An effect of chemical composition on the atomic structure of the films was studied by reflection high-energy electron diffraction, x-ray photoelectron spectroscopy and field emission scanning electron microscopy methods. The films were found to be amorphous, consisting only of three components: Hf-metal clusters, Hf4O7 suboxide and stoichiometric HfO2. The relative concentration of these components varies with changing x. The surface of the films contains the increased oxygen content compared to the bulk. It was found that the Hf4O7 suboxide concentration is maximal at x = 1.8. The concept of hafnium oxide film growth by the IBSD method is proposed to explain the lack of suboxides variety in the films and the instability of HfO2, when annealed at high temperature.

  11. The study of single station inverting the sea surface current by HF ground wave radar based on adjoint assimilation technology

    Science.gov (United States)

    Han, Shuzong; Yang, Hua; Xue, Wenhu; Wang, Xingchi

    2017-06-01

    This paper introduces the assimilation technology in an ocean dynamics model and discusses the feasibility of inverting the sea surface current in the detection zone by assimilating the sea current radial velocity detected by single station HF ground wave radar in ocean dynamics model. Based on the adjoint assimilation and POM model, the paper successfully inverts the sea surface current through single station HF ground wave radar in the Zhoushan sea area. The single station HF radar inversion results are also compared with the bistatic HF radar composite results and the fixed point measured results by Annderaa current meter. The error analysis shows that acquisition of flow velocity and flow direction data from the single station HF radar based on adjoint assimilation and POM model is viable and the data obtained have a high correlation and consistency with the flow field observed by HF radar.

  12. Microstructure and Corrosion Behavior of Hf-40 Wt Pct Ti Alloy in Nitric Acid Medium for Reprocessing Applications

    Science.gov (United States)

    Jayaraj, J.; Ravi, K. R.; Mallika, C.; Kamachi Mudali, U.

    2016-09-01

    The Hf-40 wt pct Ti (Hf-Ti) alloy was developed for neutron poison application in the spent nuclear fuel reprocessing plant. The furnace-cooled Hf-Ti sample exhibited the microstructure comprising equiaxed-α, lamellar-α, and feathery-α. The water-quenched Hf-Ti sample confirmed the presence of lath and internally twinned martensite. In comparison to the furnace-cooled sample, low corrosion current density and passivation current density values obtained for the water-quenched Hf-Ti in 6 M HNO3 at 298 K (25 °C) indicated better passivation ability. The martensitic structure exhibited high hardness (660 HV) and negligible corrosion rate in 6 M nitric acid at 298 K (25 °C). X-ray photoelectron spectroscopic (XPS) analysis confirmed that passivation behavior of this alloy was due to the protective passive film composed of TiO2 and HfO2.

  13. Ferroelectric-field-effect-enhanced resistance performance of TiN/Si:HfO2/oxygen-deficient HfO2/TiN resistive switching memory cells

    Science.gov (United States)

    Jiang, Ran; Wu, Zhengran; Du, Xianghao; Han, Zuyin; Sun, Weideng

    2015-07-01

    Greatly improved resistance performance, including high resistance ratio between the high resistance state and the low resistance state, long-time retention, and reliable endurance, was observed in TiN/Si:HfO2/oxygen-deficient HfO2/TiN memory cells. The enhanced resistance ratio is ascribed to the creation/elimination of an extra barrier in oxygen-deficient HfO2 layer in response to the polarization reversal in the ferroelectric Si:HfO2 layer. Along with the enhanced resistance ratio, the long retention and good endurance make the proposed device a promising candidate for non-volatile resistive memories.

  14. Gas-phase reaction studies of dipositive hafnium and hafnium oxide ions: generation of the peroxide HfO2(2+).

    Science.gov (United States)

    Lourenço, Célia; Michelini, Maria del Carmen; Marçalo, Joaquim; Gibson, John K; Oliveira, Maria Conceição

    2012-12-27

    Fourier transform ion cyclotron resonance mass spectrometry was used to characterize the gas-phase reactivity of Hf dipositive ions, Hf(2+)and HfO(2+), toward several oxidants: thermodynamically facile O-atom donor N(2)O, ineffective donor CO, and intermediate donors O(2), CO(2), NO, and CH(2)O. The Hf(2+) ion exhibited electron transfer with N(2)O, O(2), NO, and CH(2)O, reflecting the high ionization energy of Hf(+). The HfO(2+) ion was produced by O-atom transfer to Hf(2+) from N(2)O, O(2), and CO(2), and the HfO(2)(2+) ion by O-atom transfer to HfO(2+) from N(2)O; these reactions were fairly efficient. Density functional theory revealed the structure of HfO(2)(2+) as a peroxide. The HfO(2)(2+) ion reacted by electron transfer with N(2)O, CO(2), and CO to give HfO(2)(+). Estimates were made for the second ionization energies of Hf (14.5 ± 0.5 eV), HfO (14.3 ± 0.5 eV), and HfO(2) (16.2 ± 0.5 eV), and also for the bond dissociation energies, D[Hf(2+)-O] = 686 ± 69 kJ mol(-1) and D[OHf(2+)-O] = 186 ± 98 kJ mol(-1). The computed bond dissociation energies, 751 and 270 kJ mol(-1), respectively, are within these experimental ranges. Additionally, it was found that HfO(2)(2+) oxidized CO to CO(2) and is thus a catalyst in the oxidation of CO by N(2)O and that Hf(2+) activates methane to produce a carbene, HfCH(2)(2+).

  15. Bonding and Site Preferences in the New Quasi-Binary Zr 2.7Hf 11.3P 9

    Science.gov (United States)

    Kleinke, Holger; Franzen, Hugo F.

    1998-03-01

    The new quasi-binary Zr 2.7Hf 11.3P 9was synthesized by arc-melting of Zr, Hf, Co, and HfP in a ratio corresponding to the initial composition "Zr 2.25Hf 6.75Co 2P 4". Zr 2.7Hf 11.3P 9crystallizes in the Zr 14P 9structure type, which is unknown in the binary Hf/P system. The ideal orthorhombic lattice dimensions (space group Pnnm(No. 58), Z=4) were refined to a=16.640(7) Å, b=27.40(2) Å, c=3.619(1) Å, V=1650(2) Å 3. The structure consists of three-dimensional condensed one-, two-, and three-capped trigonal (Zr, Hf) 6P prisms, occurring with numerous short M- Mbonds ( M=Zr, Hf). Each of the 15 metal sites is statistically occupied by a mixture of Zr and Hf, which varies significantly from site to site. The Hf/Zr ratio in a given site depends on the M- Mand M-P interactions. The systematic increase of this ratio with increasing total bond order, as evaluated via Mulliken overlap populations and Pauling bond orders, can be understood based on the trend that Hf forms stronger M- Mand M-P bonds than Zr. As expected for a metal-rich phosphide, band structure calculations for the hypothetical "Hf 14P 9" carried out with the extended Hückel approximation result in a significant density of states at the Fermi level.

  16. Characteristics of high-quality HfSiON gate dielectric prepared by physical vapour deposition

    Institute of Scientific and Technical Information of China (English)

    Xu Gao-Bo; Xu Qiu-Xia

    2009-01-01

    This paper presents a method using simple physical vapour deposition to form high-quality hafnium silicon oxyni-tride (HfSiON) on ultrathin SiO2 buffer layer. The gate dielectric with 10A (1/A = 0.1 nm) equivalent oxide thickness is obtained. The experimental results indicate that the prepared HfSiON gate dielectric exhibits good physical and electrical characteristics, including very good thermal stability up to 1000℃, excellent interface properties, high dielec-tric constant (k = 14) and low gate-leakage current (Ig= 1.9×10-3 A/cm2@Vg = Vfb-1V for EOT of 10A). TaN metal gate electrode is integrated with the HfSiON gate dielectric.The effective work function of TaN on HfSiON is 4.3eV, meeting the requirements of NMOS for the metal gate. And, the impacts of sputtering ambient and annealing temperature on the electrical properties of HfSiON gate dielectric are investigated.

  17. Mixed Al and Si doping in ferroelectric HfO2 thin films

    Science.gov (United States)

    Lomenzo, Patrick D.; Takmeel, Qanit; Zhou, Chuanzhen; Chung, Ching-Chang; Moghaddam, Saeed; Jones, Jacob L.; Nishida, Toshikazu

    2015-12-01

    Ferroelectric HfO2 thin films 10 nm thick are simultaneously doped with Al and Si. The arrangement of the Al and Si dopant layers within the HfO2 greatly influences the resulting ferroelectric properties of the polycrystalline thin films. Optimizing the order of the Si and Al dopant layers led to a remanent polarization of ˜20 μC/cm2 and a coercive field strength of ˜1.2 MV/cm. Post-metallization anneal temperatures from 700 °C to 900 °C were used to crystallize the Al and Si doped HfO2 thin films. Grazing incidence x-ray diffraction detected differences in peak broadening between the mixed Al and Si doped HfO2 thin films, indicating that strain may influence the formation of the ferroelectric phase with variations in the dopant layering. Endurance characteristics show that the mixed Al and Si doped HfO2 thin films exhibit a remanent polarization greater than 15 μC/cm2 up to 108 cycles.

  18. Spectroscopic analysis of Al and N diffusion in HfO{sub 2}

    Energy Technology Data Exchange (ETDEWEB)

    Lysaght, P. S.; Price, J.; Kirsch, P. D. [SEMATECH, 257 Fuller Rd, Albany, New York 12203 (United States); Woicik, J. C.; Weiland, C. [National Institute of Standards and Technology, Gaithersburg, Maryland 20899 (United States); Sahiner, M. A. [Seton Hall University, 400 South Orange Ave, South Orange, New Jersey 07079 (United States)

    2012-09-15

    X-ray photoelectron core level spectroscopy, secondary ion mass spectroscopy, spectroscopic ellipsometry, and extended x-ray absorption fine structure measurements have been employed to distinguish the effects of Al and N diffusion on the local bonding and microstructure of HfO{sub 2} and its interface with the Si substrate in (001)Si/SiO{sub x}/2 nm HfO{sub 2}/1 nm AlO{sub x} film structures. The diffusion of Al from the thin AlO{sub x} cap layer deposited on both annealed and unannealed HfO{sub 2} has been observed following anneal in N{sub 2} and NH{sub 3} ambient. Both N{sub 2} and NH{sub 3} subsequent anneals were performed to decouple incorporated nitrogen from thermal reactions alone. Causal variations in the HfO{sub 2} microstructure combined with the dependence of Al and N diffusion on initial HfO{sub 2} conditions are presented with respect to anneal temperature and ambient.

  19. Height dependence of the observed spectrum of radar backscatter from HF-induced ionospheric Langmuir turbulence

    Science.gov (United States)

    Fejer, J. A.; Sulzer, M. P.; Djuth, F. T.

    1991-09-01

    Results are presented of observations of the spectrum of the 430-MHz radar backscatter from HF-induced Langmuir turbulence with height discrimination. During very stable ionospheric conditions under which the height of the below-threshold backscatter spectrum changed by less than 300 m during a 7-min period, a 20-s-long temporary increase in the HF power from 3 MW ERP to 38-MW-equivalent-radiated HF power is found to result in subsequent strong above-threshold spectra extending to heights up to 1200 m greater than the height of the below-threshold spectrum for more than a minute. The generation of irregularities in the plasma density during the 20 s of enhanced HF power is suggested as a possible cause of this persistence of strong above-threshold spectra at greater heights. The initial temporal evolution of the backscatter spectrum from Langmuir turbulence after the start of HF transmissions is observed for different heights. The observational results are compared with the predictions of existing theories of Langmuir turbulence.

  20. Current Progress of Hf (Zr)-Based High-k Gate Dielectric Thin Films

    Institute of Scientific and Technical Information of China (English)

    2007-01-01

    With the continued downscaling of complementary metal-oxide-semiconductor field effect transistor dimensions, high-dielectric constant (high-k) gate materials, as alternatives to SiO2, have been extensively investigated. Hf (Zr)-based high-k gate dielectric thin films have been regarded as the most promising candidates for high-k gate dielectric according to the International Technology Roadmap for Semiconductor due to their excellent physical properties and performance. This paper reviews the recent progress on Hf (Zr)-based high-k gate dielectrics based on PVD (physical vapor deposition) process. This article begins with a survey of various methods developed for generating Hf (Zr)-based high-k gate dielectrics, and then mainly focuses on microstructure, synthesis, characterization, formation mechanisms of interfacial layer, and optical properties of Hf (Zr)-based high-k gate dielectrics. Finally, this review concludes with personal perspectives towards future research on Hf (Zr)-based high-k gate dielectrics.

  1. Efficacy of Experimental Hydrofluoric Acid (HF on Bond Strength and Microleakage of Composite-Porcelain Interface

    Directory of Open Access Journals (Sweden)

    Samaneh Mahvidyzadeh

    2012-09-01

    Full Text Available Background and Aims: The aim of this study was to evaluate the quality of an experimental hydrofluoric acid (HF for preparation of porcelain and to compare it with two commercial hydrofluoric acids in Iranian trademark. Materials and Methods: A- Evaluation of etch pattern of experimental HF using scanning electron microscope (SEM: 6 feldespathic discs were divided into 3 groups. Each group was etched with related HF (experimental, Ultradent and Kimia for 1 minute. SEM images were recorded at 3 magnifications. B- Bond strength test: 18 feldespathic discs were considered for each acidic group. Then the porcelain surfaces were etched and bonded to composite with unfilled resin. Consequently, the microshear test was done. C- Microleakage test: 54 discs were divided into 3 groups (n=18. Then the porcelain surfaces were etched and bonded to composite with unfilled resin and finally observed under stereomicroscope. The data were analyzed with one-way ANOVA and Smirnov tests. Results: SEM analysis showed no difference between groups in terms of etch pattern. Microshear bond strength values for experimental, Kimia, and Ultradent HF were 28.53 (±4.92, 28.21 (±6.61, and 26.14 (±7.61 MPa, respectively. There was no significant difference between the bond strength of test groups (P0.05. Conclusion: Quality of experimental HF in terms of etch pattern, microshear bond strength and microleakage of composite/porcelain interface was similar to that of two commercial hydrofluoric acids.

  2. Synthesis and White-Light Emission of ZnO/HfO2: Eu Nanocables

    Directory of Open Access Journals (Sweden)

    Liu Lixin

    2010-01-01

    Full Text Available Abstract ZnO/HfO2:Eu nanocables were prepared by radio frequency sputtering with electrospun ZnO nanofibers as cores. The well-crystallized ZnO/HfO2:Eu nanocables showed a uniform intact core–shell structure, which consisted of a hexagonal ZnO core and a monoclinic HfO2 shell. The photoluminescence properties of the samples were characterized. A white-light band emission consisted of blue, green, and red emissions was observed in the nanocables. The blue and green emissions can be attributed to the zinc vacancy and oxygen vacancy defects in ZnO/HfO2:Eu nanocables, and the yellow–red emissions are derived from the inner 4f-shell transitions of corresponding Eu3+ ions in HfO2:Eu shells. Enhanced white-light emission was observed in the nanocables. The enhancement of the emission is ascribed to the structural changes after coaxial synthesis.

  3. Mixed Al and Si doping in ferroelectric HfO{sub 2} thin films

    Energy Technology Data Exchange (ETDEWEB)

    Lomenzo, Patrick D.; Nishida, Toshikazu, E-mail: nishida@ufl.edu [Department of Electrical and Computer Engineering, University of Florida, Gainesville, Florida 32611 (United States); Takmeel, Qanit [Department of Materials Science and Engineering, University of Florida, Gainesville, Florida 32611 (United States); Zhou, Chuanzhen [Analytical Instrumentation Center, College of Engineering at North Carolina State University, Raleigh, North Carolina 27696 (United States); Chung, Ching-Chang; Jones, Jacob L. [Department of Materials Science and Engineering, North Carolina State University, Raleigh, North Carolina 27696 (United States); Moghaddam, Saeed [Department of Mechanical and Aerospace Engineering, University of Florida, Gainesville, Florida 32611 (United States)

    2015-12-14

    Ferroelectric HfO{sub 2} thin films 10 nm thick are simultaneously doped with Al and Si. The arrangement of the Al and Si dopant layers within the HfO{sub 2} greatly influences the resulting ferroelectric properties of the polycrystalline thin films. Optimizing the order of the Si and Al dopant layers led to a remanent polarization of ∼20 μC/cm{sup 2} and a coercive field strength of ∼1.2 MV/cm. Post-metallization anneal temperatures from 700 °C to 900 °C were used to crystallize the Al and Si doped HfO{sub 2} thin films. Grazing incidence x-ray diffraction detected differences in peak broadening between the mixed Al and Si doped HfO{sub 2} thin films, indicating that strain may influence the formation of the ferroelectric phase with variations in the dopant layering. Endurance characteristics show that the mixed Al and Si doped HfO{sub 2} thin films exhibit a remanent polarization greater than 15 μC/cm{sup 2} up to 10{sup 8} cycles.

  4. Thermal evolution of CaO-doped HfO{sub 2} films and powders

    Energy Technology Data Exchange (ETDEWEB)

    Barolin, S A; Sanctis, O A de [Lab. Materiales Ceramicos, FCEIyA, Universidad Nacional de Rosario, IFIR-CONICET (Argentina); Caracoche, M C; Martinez, J A; Taylor, M A; Pasquevich, A F [Departamento de Fisica, FCE, Universidad Nacional de La Plata, IFLP-CONICET (Argentina); Rivas, P C, E-mail: oski@fceia.unr.edu.a [Facultad de Ciencias Agronomicas y Forestales, Universidad Nacional de La Plata, IFLP (Argentina)

    2009-05-01

    Solid solutions of ZrO2 and HfO2 are potential electrolyte materials for intermediate-temperature SOFC because both are oxygen-ion conductors. The main challenge for these compounds is to reduce the relatively high value of the activation energies vacancies diffusion, which is influenced by several factors. In this work the thermal evolution of CaO-HfO{sub 2} materials have been investigated. (CaO)y-Hf(1-y)O(2-y) (y = 0.06, 0.14 y 0.2) coatings and powders were synthesized by chemical solution deposition (CSD). Films were deposited onto alumina substrates by Dip Coating technique, the burning of organic waste was carried out at 500 deg. C under normal atmosphere and then the films were thermally treated at intervals of temperature rising to a maximum temperature of 1250 deg. C. By means Glazing Incidence X-ray Diffraction (rho-2theta configuration) the phases were studied in the annealed films. On the other hand, the thermal evolution and crystallization process of powders were analyzed in-situ by HT-XRD. The phenomena crystallization occurred in films and powders were analyzed. The activation energies of diffusion of oxygen vacancies of HfO2-14 mole% CaO and HfO2-20 mole% CaO films were measured from the thermal evolution of the relaxation constant measured by Perturbed Angular Correlation Technique.

  5. Atomic layer deposition of HfO{sub 2}: Growth initiation study on metallic underlayers

    Energy Technology Data Exchange (ETDEWEB)

    Platt, Christopher L., E-mail: Christopher.L.Platt@seagate.co [Seagate Technology, 47010 Kato Rd, Fremont, CA 94538 (United States); Li Ning; Li Kejing; Klein, Tonya M. [Department of Chemical and Biological Engineering, University of Alabama, A131 Bevill Building, Tuscaloosa, AL 35487-0203 (United States)

    2010-05-31

    The initial stages of HfO{sub 2} film growth by atomic layer deposition (ALD) on Co, Ta, and Pt thin films have been compared by x-ray photoelectron spectroscopy (XPS) and attenuated total reflection Fourier transform infrared spectroscopy. The initial tetrakis-dimethylamido(IV) hafnium (TDMAH) adsorption rate was highest on Co and increased with substrate temperature between 150 {sup o}C and 250 {sup o}C. The initial adsorption rate of TDMAH on Ta was less than on Co or Pt at the same substrate temperatures. The Ta surface also proved to be more stable with regard to TDMAH decomposition as fluctuations of adsorbed Hf and decomposition products were not observed during ALD cycling. Larger amounts of carbon were observed on Pt after TDMAH exposure compared to Co or Ta, suggestive of decomposition products. The XPS Hf(4f) peak measured after initial exposure of TDMAH on Pt showed evidence of two Hf oxidation states at the surface. It is postulated that the reaction of TDMAH and decomposition by-products with available oxygen or hydroxyl molecules at the surface of the various metal underlayers affected the initial growth of HfO{sub 2}.

  6. Properties of Dopants in HfOx for Improving the Performance of Nonvolatile Memory

    Science.gov (United States)

    Duncan, Dan; Magyari-Köpe, Blanka; Nishi, Yoshio

    2017-03-01

    Doping is an increasingly popular technique for improving the characteristics of cutting-edge HfOx nonvolatile memory devices, but relatively few dopant species have been investigated. In this work, the properties of 50 different cation and anion dopants in HfOx are explored using density-functional theory and are corroborated with experimental data. Depending on the atomic species, dopants are found to preferentially form on either substitutional or interstitial lattice sites and to reduce the formation energy of oxygen vacancies in the surrounding oxide. The behavior of cation dopants in HfOx is also found to be well predicted by six properties: dopant valence, atomic radius, native-oxide enthalpy of formation, coordination number, magnetization, and charge transfer with the HfOx lattice. These results can be used to optimize dopant selection for tuning of the switching characteristics of HfOx -based resistance-change random-access-memory and conductive-bridge random-access-memory devices.

  7. Surface characteristics of HA coated Ti-Hf binary alloysafter nanotube formation

    Institute of Scientific and Technical Information of China (English)

    Yong-Hoon JEONG; Won-Gi KIM; Geun-Hyeong PARK; Han-Cheol CHOE; Yeong-Mu KO

    2009-01-01

    Ti-Hf binary alloys contained 10%, 20%, 30% and 40% (mass fraction)Hf were manufactured in the vacuum furnace system. And then, specimens were homogenized for 24 h at 1 000 ℃ in argon atmosphere. The formation of oxide nanotubes was conducted by anodic oxidation on the Ti-Hf alloy in 1 mol/L H3PO4 electrolytes containing small amounts of NaF at room temperature. The hydroxyapatite (HA) coating made of tooth ash prepared by electron-beam physical vapor deposition (EB-PVD) method. The corrosion behaviors of the specimens were examined through potentiodynamic test in 0.9% NaCl solution by potentiostat. The microstructures of the alloys were examined by field emission scanning electron microscopy (FE-SEM) and x-ray diffractometer (XRD). It was observed that the lamellar structure translated to needle-like structure with Hf contents. Nanotube formed and HA coated Ti-xHf alloys had a good corrosion resistance.

  8. Elastic and vibrational properties of monoclinic HfO2 from first-principles study

    Science.gov (United States)

    Wu, Rui; Zhou, Bo; Li, Qian; Jiang, ZhenYi; Wang, WenBo; Ma, WenYan; Zhang, XiaoDong

    2012-03-01

    The elastic and vibrational properties of crystalline monoclinic HfO2 have been investigated using density functional perturbation theory. Using the Voigt and Reuss theory, we estimate the bulk, shear and Young's modulus for polycrystalline HfO2, which agree very well with the available experimental and theoretical data. Additionally, we present a systematic analysis of the elastic properties of HfO2 polymorphs and find the trends in the elastic parameters for the HfO2 structures are consistent with those for the ZrO2 structures. The choice of exchange-correlation functional has an important effect on the results of elastic and vibrational properties. The utilization of Hartwigzen-Goedecker-Hutter type functional is a great improvement on calculation of the zone-centre phonon frequencies, and shows the root-mean-square absolute deviation of 7 cm-1 with experiments. A rigorous assignment of all the Raman modes is achieved by combining symmetry analysis with the first-principles calculations, which helps us to identify the main peak and some other features of Raman spectra. Furthermore, the Raman spectrum of HfO2 powder has been simulated for the first time, providing a theoretical benchmark for the interpretation of the unresolved problems in experimental studies.

  9. Effects of Hf incorporation on indium zinc oxide thin-film transistors using solution process

    Science.gov (United States)

    Li, Xifeng; Xin, Enlong; Zhang, Jianhua

    2015-01-01

    Thin-film transistors (TFTs) were fabricated by employing amorphous hafnium indium zinc oxide (HIZO) thin films as the active channel layer by the solution process. Thermogravimetry-differential thermal analysis, transmittance measurements, atomic force microscopy, scanning electron microscopy, x-ray diffraction, and Fourier transform infrared analysis were used to study the formation, structure, and optical properties of the HIZO films. The results showed that the addition of Hf to the IZO system resulted in suppression of carrier generation. The HIZO TFTs exhibited lower off-currents and higher onoff current ratios than IZO TFTs without Hf doping. HIZO TFTs with a Hf doping content of 5 at. % obtained a threshold voltage of 3.7 V, a mobility of 0.27 cm2 V-1 s-1, a subthreshold swing of 1.2 V/dec, and an on-off current ratio of 106.

  10. Charge storage and tunneling mechanism of Ni nanocrystals embedded HfOx film

    Directory of Open Access Journals (Sweden)

    H. X. Zhu

    2016-05-01

    Full Text Available A nano-floating gate memory structure based on Ni nanocrystals (NCs embedded HfOx film is deposited by means of radio-frequency magnetron sputtering. Microstructure investigations reveal that self-organized Ni-NCs with diameters of 4-8 nm are well dispersed in amorphous HfOx matrix. Pt/Ni-NCs embedded HfOx/Si/Ag capacitor structures exhibit voltage-dependent capacitance-voltage hysteresis, and a maximum flat-band voltage shift of 1.5 V, corresponding to a charge storage density of 6.0 × 1012 electrons/cm2, is achieved. These capacitor memory cells exhibit good endurance characteristic up to 4 × 104 cycles and excellent retention performance of 105 s, fulfilling the requirements of next generation non-volatile memory devices. Schottky tunneling is proven to be responsible for electrons tunneling in these capacitors.

  11. Electrical Characteristics of MOS Capacitors with HfTiON as Gate Dielectric

    Institute of Scientific and Technical Information of China (English)

    CHEN Weibing; XU Jingping; LAI Puito; LI Yanping; XU Shengguo; CHAN Chulok

    2009-01-01

    HfTiN film was deposited by co-reactive sputtering and then was annealed in dif-ferent gas ambients at temperature of 650 ℃ for 2 min to form HfTiON film. Capacitance-voltage and gate-leakage characteristics were investigated. The N2O-annealed sample exhibited small inter-face-state and oxide-charge densities, and enhanced reliability, which was attributed to the fact that nitridation could create strong Si≡N bonds to passivate dangling Si bonds and replaced strained Si-O bonds, thus forming a hardened dielectric/Si interface with high reliability. As a result, it is possible to prepare high-quality HfTiON gate dielectric of small-scaling CMOS devices in the industry-preferred N2O environment.

  12. Sorption behaviour of rutherfordium and thorium from HCl/HF containing aqueous solution

    Energy Technology Data Exchange (ETDEWEB)

    Schumann, D.; Nitsche, H. [Technische Univ. Dresden (Germany). Inst. fuer Analytische Chemie; Taut, S. [Institut fuer Radiochemie, FZ Rossendorf (Germany); Jost, D.T.; Gaeggeler, H.W. [Labor fuer Radio- und Umweltchemie, PSI Villigen (Switzerland); Yakushev, A.B.; Buklanov, G.V.; Domanov, V.P.; Lien Din Thi [Flerov Laboratory of Nuclear Reactions, JINR Dubna (Russian Federation); Kubica, B.; Misiak, R.; Szeglowski, Z. [H. Niewodniczanski Institute of Nuclear Physics, Krakow (Poland)

    1998-06-12

    The sorption was studied of element 104 (rutherfordium, Rf) and thorium on the strongly acidic cation exchanger DOWEX 50 x 8. The experiments were carried out on-line. Rf is strongly retained on cation exchange resins from diluted HCl/HF solutions in a concentration range of 0.05 to 0.1 M HCl and HF concentrations up to 0.01 M. This behaviour is similar to its pseudohomologue thorium and very different from its lighter homologue hafnium which is desorbed from DOWEX 50 x 8 at HF concentrations above 10{sup -3} M. The tested ion exchange system is suitable for fast on-line separation of element 106 (seaborgium, Sg) from all other contaminations and its decay product Rf. It, therefore, allows the indirect identification of Sg. (orig.) 12 refs.

  13. Irradiation resistance, microstructure and mechanical properties of nanostructured (TiZrHfVNbTa)N coatings

    Energy Technology Data Exchange (ETDEWEB)

    Pogrebnjak, Alexander D. [Sumy State University, Sumy (Ukraine); Institute of Transport, Combustion Engines and Ecology, Lublin University of Technology, 20-618 Lublin (Poland); Yakushchenko, Ivan V.; Bondar, Oleksandr V. [Sumy State University, Sumy (Ukraine); Beresnev, Vyacheslav M. [Karazin National University, Kharkiv (Ukraine); Oyoshi, Keiji [National Institute for Material Science (NIMS), Tsukuba (Japan); Ivasishin, Orest M. [V. Kurdyumov Institute for Metal Physics, NAS of Ukraine, Kiev (Ukraine); Amekura, Hiroshi; Takeda, Yoshihiko [National Institute for Material Science (NIMS), Tsukuba (Japan); Opielak, Marek, E-mail: m.opielak@pollub.pl [Institute of Transport, Combustion Engines and Ecology, Lublin University of Technology, 20-618 Lublin (Poland); Kozak, Czeslaw [Department of Electrical Devices and High Voltage Technology, Lublin University of Technology, 20-618 Lublin (Poland)

    2016-09-15

    Nitrides of high-entropy alloys (TiHfZrNbVTa)N were fabricated using cathodic-vacuum-arc-vapor-deposition method. Morphology and topology of the surface of the coatings, roughness, elemental and phase composition, microstructure and mechanical properties were investigated. Dependence of deposition parameters on surface morphology and elemental composition was demonstrated. Influence of the heavy negative charged Au{sup −} ions implantation on phase structure, microstructure and hardness of nitride (TiHfZrNbVTa)N coatings was investigated. - Highlights: • (TiHfZrNbVTa)N fabricated using cathodic-vacuum-arc-vapor-deposition method. • Roughness, elemental and phase composition, microstructure and mechanical properties. • Influence of the heavy negative charged Au- ions implantation on mechanical properties.

  14. Promise and Pitfalls of Lu/Hf-Sm/Nd Garnet Geochronology

    Science.gov (United States)

    King, R. L.; Vervoort, J. D.; Kohn, M. J.; Zirakparvar, N. A.; Hart, G. L.; Corrie, S. L.; Cheng, H.

    2007-12-01

    Our ability to routinely measure Lu-Hf and Sm-Nd isotopes in garnet allows broad new applications in geochronology, petrology, and tectonics. However, applications of these data can be limited by challenges in interpreting the petrologic record and preparing garnets for analysis. Here, we examine petrologic and chemical pitfalls encountered in garnet geochronology. Petrologic factors influencing trace element compositions in garnet include reactions that modify REE availability and partitioning (1,2), kinetically limited transfer of REEs to garnet (3), and bulk compositional heterogeneities (4). Interpreting the effects of these processes on Sm/Nd and Lu/Hf ages requires characterizing REE zonation prior to isotope analysis and age interpretation. Because garnet fractions are traditionally picked from crushed samples without regard to intracrystalline origins or chemistries, isochrons will represent mixtures derived to varying degrees from all periods of garnet growth. While measured zoning might generally indicate what garnet portion dominates the Lu/Hf or Sm/Nd budget, traditional mineral separation will rarely realize the chronologic potential afforded by high precision Hf and Nd isotope measurements. The potential use of alternative techniques, such as microsampling, necessitates selective digestion and/or leaching to eliminate inclusions within garnet. For Sm/Nd geochronology, H2SO4 leaching removes LREE-rich phosphates (e.g. apatite), but not silicates (e.g. epidote), precluding Sm-Nd dating of some rocks. For Lu/Hf geochronology, ubiquitous zircon microinclusions (c. 1 μm) can significantly disrupt age determinations. Microinclusions cannot be detected optically or separated physically, requiring selective chemical digestion. If complete digestion methods, such as bomb digestion, are used for garnet fractions, then "common Hf" from zircon will be contained in final solutions. These mixed analyses are of dubious utility and will fall into one of two

  15. Pressure-induced structures of Si-doped HfO{sub 2}

    Energy Technology Data Exchange (ETDEWEB)

    Fancher, Chris M.; Nelson, Matthew; Jones, Jacob L., E-mail: jacob-jones@ncsu.edu [Department of Materials Science and Engineering, North Carolina State University Raleigh, North Carolina 27695 (United States); Zhao, Lili [Department of Materials Science and Engineering, North Carolina State University Raleigh, North Carolina 27695 (United States); School of Information Science and Technology, Northwest University, Xi' an 710127 (China); Bai, Ligang; Shen, Guoyin [HPCAT, Geophysical Laboratory, Carnegie Institution of Washington, Argonne, Illinois 60439 (United States)

    2015-06-21

    The effect of hydrostatic pressure on the structure of Si-doped HfO{sub 2} (Si:HfO{sub 2}) was studied by using a diamond anvil cell in combination with high-energy X-ray diffraction at a synchrotron source. Diffraction data were measured in situ during compression up to pressures of 31 GPa. Si:HfO{sub 2} with 3, 5, and 9 at. % Si were found to undergo a monoclinic to orthorhombic transition at pressures between 7 and 15 GPa. Whole pattern analysis was carried out using nonpolar (Pbca) and polar (Pca2{sub 1}) crystallographic models to investigate the symmetry of the observed high-pressure orthorhombic phase. Rietveld refinement results cannot discriminate a reliable difference between the Pbca and Pca2{sub 1} structures as they nearly equally model the measured diffraction data. The pressure dependent lattice parameters, relative volume, and spontaneous strain are reported.

  16. HfSe2 thin films: 2D transition metal dichalcogenides grown by molecular beam epitaxy.

    Science.gov (United States)

    Yue, Ruoyu; Barton, Adam T; Zhu, Hui; Azcatl, Angelica; Pena, Luis F; Wang, Jian; Peng, Xin; Lu, Ning; Cheng, Lanxia; Addou, Rafik; McDonnell, Stephen; Colombo, Luigi; Hsu, Julia W P; Kim, Jiyoung; Kim, Moon J; Wallace, Robert M; Hinkle, Christopher L

    2015-01-27

    In this work, we demonstrate the growth of HfSe2 thin films using molecular beam epitaxy. The relaxed growth criteria have allowed us to demonstrate layered, crystalline growth without misfit dislocations on other 2D substrates such as highly ordered pyrolytic graphite and MoS2. The HfSe2 thin films exhibit an atomically sharp interface with the substrates used, followed by flat, 2D layers with octahedral (1T) coordination. The resulting HfSe2 is slightly n-type with an indirect band gap of ∼ 1.1 eV and a measured energy band alignment significantly different from recent DFT calculations. These results demonstrate the feasibility and significant potential of fabricating 2D material based heterostructures with tunable band alignments for a variety of nanoelectronic and optoelectronic applications.

  17. Hf-W chronometry of core formation in planetesimals inferred from weakly irradiated iron meteorites

    Science.gov (United States)

    Kruijer, Thomas S.; Sprung, Peter; Kleine, Thorsten; Leya, Ingo; Burkhardt, Christoph; Wieler, Rainer

    2012-12-01

    The application of Hf-W chronometry to determine the timescales of core formation in the parent bodies of magmatic iron meteorites is severely hampered by 182W burnout during cosmic ray exposure of the parent meteoroids. Currently, no direct method exists to correct for the effects of 182W burnout, making the Hf-W ages for iron meteorites uncertain. Here we present noble gas and Hf-W isotope systematics of iron meteorite samples whose W isotopic compositions remained essentially unaffected by cosmic ray interactions. Most selected samples have concentrations of cosmogenic noble gases at or near the lowermost level observed in iron meteorites and, for iron meteorite standards, have very low noble gas and radionuclide based cosmic ray exposure ages (Mbosi), however, has elevated ɛ182W relative to the other investigated irons, indicating metal-silicate separation ˜2-3 Myr later than in the parent bodies of the three major iron meteorite groups studied here.

  18. HF-enhanced 4278-Å airglow: evidence of accelerated ionosphere electrons?

    Science.gov (United States)

    Fallen, C. T.; Watkins, B. J.

    2013-12-01

    We report calculations from a one-dimensional physics-based self-consistent ionosphere model (SCIM) demonstrating that HF-heating of F-region electrons can produce 4278-Å airglow enhancements comparable in magnitude to those reported during ionosphere HF modification experiments at the High-frequency Active Auroral Research Program (HAARP) observatory in Alaska. These artificial 'blue-line' emissions, also observed at the EISCAT ionosphere heating facility in Norway, have been attributed to arise solely from additional production of N2+ ions through impact ionization of N2 molecules by HF-accelerated electrons. Each N2+ ion produced by impact ionization or photoionization has a probability of being created in the N2+(1N) excited state, resulting in a blue-line emission from the allowed transition to its ground state. The ionization potential of N2 exceeds 18 eV, so enhanced impact ionization of N2 implies that significant electron acceleration processes occur in the HF-modified ionosphere. Further, because of the fast N2+ emission time, measurements of 4278-Å intensity during ionosphere HF modification experiments at HAARP have also been used to estimate artificial ionization rates. To the best of our knowledge, all observations of HF-enhanced blue-line emissions have been made during twilight conditions when resonant scattering of sunlight by N2+ ions is a significant source of 4278-Å airglow. Our model calculations show that F-region electron heating by powerful O-mode HF waves transmitted from HAARP is sufficient to increase N2+ ion densities above the shadow height through temperature-enhanced ambipolar diffusion and temperature-suppressed ion recombination. Resonant scattering from the modified sunlit region can cause a 10-20 R increase in 4278-Å airglow intensity, comparable in magnitude to artificial emissions measured during ionosphere HF-modification experiments. This thermally-induced artificial 4278-Å aurora occurs independently of any artificial

  19. Rules for maximum solid solubility of transition metals in Ti, Zr and Hf solvents

    Institute of Scientific and Technical Information of China (English)

    周自强; 方守狮; 冯锋

    2003-01-01

    Based on the principle of energy change of alloy formation, the rules for the maximum solid solubility (Cmax) of various transition metals in the metals Ti, Zr and Hf were studied. It is deduced that the Cmax of transition metals in the metals Ti, Zr and Hf can be described as a semi-empirical equation using three atomic parameters, i.e., electronegativity difference, atomic diameter and electron concentration. From the equation analysis by using experimental data, it shows that atomic size parameter and electronegativity difference are the main factors that affect the Cmax of the transition metals in the metals Ti, Zr and Hf while electron concentration parameter has the smallest effect on Cmax.

  20. Intrinsic electron traps in atomic-layer deposited HfO{sub 2} insulators

    Energy Technology Data Exchange (ETDEWEB)

    Cerbu, F.; Madia, O.; Afanas' ev, V. V.; Houssa, M.; Stesmans, A. [Laboratory of Semiconductor Physics, Department of Physics and Astronomy, University of Leuven, 3001 Leuven (Belgium); Andreev, D. V. [Laboratory of Semiconductor Physics, Department of Physics and Astronomy, University of Leuven, 3001 Leuven (Belgium); Bauman Moscow State Technical University—Kaluga Branch, 248000 Kaluga, Moscow obl. (Russian Federation); Fadida, S.; Eizenberg, M. [Department of Materials Science and Engineering, Technion-Israel Institute of Technology, 32000 Haifa (Israel); Breuil, L. [imec, 3001 Leuven (Belgium); Lisoni, J. G. [imec, 3001 Leuven (Belgium); Institute of Physics and Mathematics, Faculty of Science, Universidad Austral de Chile, Valdivia (Chile); Kittl, J. A. [Laboratory of Semiconductor Physics, Department of Physics and Astronomy, University of Leuven, 3001 Leuven (Belgium); Advanced Logic Lab, Samsung Semiconductor, Inc., Austin, 78754 Texas (United States); Strand, J.; Shluger, A. L. [Department of Physics and Astronomy, University College London, London WC1E 6BT (United Kingdom)

    2016-05-30

    Analysis of photodepopulation of electron traps in HfO{sub 2} films grown by atomic layer deposition is shown to provide the trap energy distribution across the entire oxide bandgap. The presence is revealed of two kinds of deep electron traps energetically distributed at around E{sub t} ≈ 2.0 eV and E{sub t} ≈ 3.0 eV below the oxide conduction band. Comparison of the trapped electron energy distributions in HfO{sub 2} layers prepared using different precursors or subjected to thermal treatment suggests that these centers are intrinsic in origin. However, the common assumption that these would implicate O vacancies cannot explain the charging behavior of HfO{sub 2}, suggesting that alternative defect models should be considered.

  1. Far-Field Testing Method of Spurious Emission Produced by HF RFID

    Directory of Open Access Journals (Sweden)

    Nikola Gvozdenovic

    2016-01-01

    Full Text Available We present measurements of spurious emission produced by high-frequency radio frequency identification (HF RFID using carrier frequency of 13.56 MHz. HF RFID tags produce unwanted emission due to rectification and more generally due to nonlinearity of analog front end. Depending on the conducting material of an HF RFID coil and surrounding dielectric material, the coil behaves as more or less good antenna on some harmonic frequencies. Exact characterization and analysis of unwanted emission is important from the security perspective as well as from the perspective of interference with other systems. Consequently we measured the harmonics produced in the integrated circuitry and characterized radiation properties of the antenna. Finally we present the measurements of the spurious emission performed in a Gigahertz Transverse Electromagnetic (GTEM cell.

  2. High-temperature grain size stabilization of nanocrystalline Fe–Cr alloys with Hf additions

    Energy Technology Data Exchange (ETDEWEB)

    Li, Lulu, E-mail: lli18@ncsu.edu; Saber, Mostafa; Xu, Weizong; Zhu, Yuntian; Koch, Carl C.; Scattergood, Ronald O.

    2014-09-08

    The influence of 1–4 at% Hf additions on the thermal stability of mechanically alloyed nanocrystalline Fe–14Cr alloys was studied in this work. XRD-calculated grain size and microhardness results were reported versus isochronal annealing treatments up to 1100 °C. Microstructural evolution was investigated using channeling contrast FIB imaging and TEM. Grain size of samples with 4 at% Hf was found to be maintained in the nanoscale range at temperatures up to 1000 °C. Zener pinning was considered as a major source of high temperature grain size stabilization. By comparing the Orowan strengthening contribution to the total hardness, the deviation of grain size predictions from the actual grain size in Fe–14Cr–4Hf suggests the presence of thermodynamic stabilization by the solute segregation to grain boundaries (GBs). A predictive thermodynamic model indicates that the thermodynamic stabilization can be expected.

  3. About the scheme of the infrared FEL system for the accelerator based on HF wells

    Energy Technology Data Exchange (ETDEWEB)

    Kabanov, V.S.; Dzergach, A.I. [Moscow Radiotechnical Institute (Russian Federation)

    1995-12-31

    Accelerators, based on localization of plasmoids in the HF wells (RF traps) of the axially-symmetric electromagnetic field E {sub omn} in an oversized (m,n>>1) resonant system, can give accelerating gradients {approximately}100 kV/{lambda}, e.g. 10 GV/m if {lambda}=10 {mu}m. One of possible variants of HF feeding for these accelerators is based on using the powerful infrared FEL System with 2 frequencies. The corresponding FEL`s may be similar to the Los Alamos compact Advanced FEL ({lambda}{sub 1,2}{approximately}10 pm, e-beam energy {approximately}15 MeV, e-beam current {approximately}100 A). Their power is defined mainly by the HF losses in the resonant system of the supposed accelerator.

  4. PNO-CEPA and MCSCF-SCEP calculations of transition probabilities in OH, HF + , and HCl +

    Science.gov (United States)

    Werner, Hans-Joachim; Rosmus, Pavel; Schätzl, Wolfgang; Meyer, Wilfried

    1984-01-01

    Electronic transition moment functions for the A 2Σ+-X2Π transitions in OH, HF+, and HCl+ have been calculated using RHF, PNO-CI, PNO-CEPA, MCSCF, and MCSCF-SCEP wave functions. The vibrational band transition probabilities are obtained, and the resulting radiative lifetimes are compared with measured values. For OH and HCl+ the deviations are smaller than 10%, but the theoretical lifetimes for HF+ are larger by about 300% than the experimental values. For the electronic ground states of HF+ and HCl+ vibrational transition probabilities have been calculated from MCSCF-SCEP dipole moment functions. Both ions are predicted to be excellent absorbers and emitters in the infrared spectral region.

  5. Effect of HF leaching on {sup 14}C dates of pottery

    Energy Technology Data Exchange (ETDEWEB)

    Goslar, Tomasz, E-mail: goslar@radiocarbon.pl [Faculty of Physics, Adam Mickiewicz University, ul. Umultowska 85, 61-614 Poznan (Poland); Poznan Radiocarbon Laboratory, ul. Rubiez 46, 61-612 Poznan (Poland); Kozlowski, Janusz [Institute of Archaeology, Jagiellonian University, ul. Golebia 11, 30-007 Krakow (Poland); Szmyt, Marzena [Institute for Eastern Studies, Adam Mickiewicz University, ul. 28 Czerwca 1956 nr 198, 61-486 Poznan (Poland); Czernik, Justyna [Poznan Radiocarbon Laboratory, ul. Rubiez 46, 61-612 Poznan (Poland)

    2013-01-15

    This paper presents the experiments with {sup 14}C dating of two potsherds, which contained carbon dispersed rather homogeneously in their clay fabric. After AAA treatment, the potsherds still appeared to be contaminated with young carbon, presumably connected with humic acids. To make removal of humic acids more effective, we treated the sherds with HF acid of different concentration. The {sup 14}C results obtained demonstrate that HF treatment indeed helps to remove humic contaminants, but it also mobilizes carbon bound to raw clay, which may make {sup 14}C dates too old. We conclude therefore, that using a simple combination of HF and AAA treatment seems insufficient in reliable {sup 14}C dating of carbon homogeneously dispersed in the volume of potsherds.

  6. Structural and dielectric properties of amorphous ZrO2 and HfO2

    Science.gov (United States)

    Ceresoli, Davide; Vanderbilt, David

    2006-09-01

    Zirconia (ZrO2) and hafnia (HfO2) are leading candidates for replacing SiO2 as the gate insulator in complementary metal-oxide semiconductor technology. Amorphous versions of these materials ( a-ZrO2 and a-HfO2 ) can be grown as metastable phases on top of a silicon buffer; while they tend to recrystallize during subsequent annealing steps, they would otherwise be of considerable interest because of the promise they hold for improved uniformity and electrical passivity. In this work, we report our theoretical studies of a-ZrO2 and a-HfO2 by first-principles density-functional methods. We construct realistic amorphous models using the “activation-relaxation” technique of Barkema and Mousseau. The structural, vibrational, and dielectric properties of the resulting models are analyzed in detail. The overall average dielectric constant is computed and found to be comparable to that of the monoclinic phase.

  7. Corrosion Characteristics of Ti-29Nb-xHf Ternary Alloy for Biomaterials

    Energy Technology Data Exchange (ETDEWEB)

    Pak, Sun Young; Choi, Han Chul [Chosun Univ., Kwangju (Korea, Republic of)

    2015-12-15

    The Cp-Ti and Ti-6Al-4V alloys were widely used for dental materials due to their mechanical properties and good corrosion resistance. However, Cp-Ti was known as bio-inert materials, Ti-6Al-4V alloy has a problem such as high Young modulus, potential loss of the surrounding bone, and to the release of potentially toxic ions from the alloy. To overcome this problem, Ti alloys containing Nb and Hf elements have been used for biomaterials due to low toxicity and high corrosion resistance. Especially, alloying element of Nb was known as β phase stabilizer. The β phase alloy was widely used to replace currently used implant materials. The corrosion resistances of Ti-29Nb-xHf ternary alloys were dependent on Hf content in oral environment solution.

  8. Refinement of the supercontinent cycle with Hf, Nd and Sr isotopes

    Directory of Open Access Journals (Sweden)

    Kent C. Condie

    2013-11-01

    External and internal orogens show similar patterns in ɛNd and ɛHf with age suggesting that both juvenile and reworked crustal components are produced in both types of orogens with similar proportions. However, both types of orogens clearly produce more juvenile isotopic signatures in retreating mode than in advancing mode. Many secular changes in ɛHf and ɛNd distributions correlate with the supercontinent cycle. Although supercontinent breakup is correlated with short-lived decreasing ɛHf and ɛNd (≤100 Myr for most supercontinents, there is no isotopic evidence for the breakup of the Paleoproterozoic supercontinent Nuna. Assembly of supercontinents by extroversion is recorded by decreasing ɛNd in granitoids and metasediments and decreasing ɛHf in zircons, attesting to the role of crustal reworking in external orogens in advancing mode. As expected, seawater Sr isotopes increase and seawater Nd isotopes decrease during supercontinent assembly by extroversion. Pangea is the only supercontinent that has a clear isotopic record of introversion assembly, during which median ɛNd and ɛHf rise rapidly for ≤100 Myr. Although expected to increase, radiogenic seawater Sr decreases (and seawater Nd increases during assembly of Pangea, a feature that may be caused by juvenile input into the oceans from new ocean ridges and external orogens in retreating mode. The fact that a probable onset of plate tectonics around 3 Ga is not recorded in isotopic distributions may be due the existence of widespread felsic crust formed prior to the onset of plate tectonics in a stagnant lid tectonic regime, as supported by Nd and Hf model ages.

  9. Um estudo teórico de propriedades moleculares em complexos de hidrogênio trimoleculares C2H4···2HF, C2H2···2HF e C3h6···2HF A theoretical study of molecular properties of C2H4···2HF, C2H2···2HF AND C3H6···2HF trimolecular hydrogen-bonded complexes

    Directory of Open Access Journals (Sweden)

    Boaz G. Oliveira

    2008-01-01

    Full Text Available We present a theoretical study of molecular properties in C2H4···2HF, C2H2···2HF and C3H6···2HF trimolecular hydrogen-bonded complexes. From B3LYP/6-311++G(d,p calculations, the most important structural deformations are related to the C=C (C2H4, C≡C (C2H2, C-C (C3H6 and HF bond lengths. According to the Bader's atoms in molecules and CHELPG calculations, it was identified a tertiary interaction between the fluorine atom of the second hydrofluoric acid molecule and hydrogen atoms of the ethylene and acetylene within the C2H4···2HF and C2H2···2HF complexes, respectively. Additionally, the evaluation of the infrared spectrum characterized the new vibrational modes and bathochromic effect of the HF molecules.

  10. Probing Archean lithosphere using the Lu-Hf isotope systematics of peridotite xenoliths from Somerset Island kimberlites, Canada

    Science.gov (United States)

    Schmidberger, Stefanie S.; Simonetti, Antonio; Francis, Don; Gariépy, Clément

    2002-04-01

    A knowledge of the Hf isotopic composition of the subcontinental lithosphere beneath Archean cratons is essential to constrain the Hf isotope budget of the Earth's mantle. Hf isotopic measurements were obtained by MC-ICP-MS for a suite of refractory peridotite xenoliths and constituent garnets from the Nikos kimberlite (100 Ma) on Somerset Island in order to constrain the isotopic composition and age of the lithosphere beneath the northern Canadian craton. The low-temperature Nikos peridotites (Somerset lithosphere, are characterized by higher 176Lu/ 177Hf ratios (0.03-0.05) and Hf isotopic values ( 176Hf/ 177Hf (0.1Ga)=0.28296-0.28419) than the deep-seated high-temperature peridotites (>1100°C; 0.004-0.03, 0.28265-0.28333, respectively). These differences in Hf isotope signatures suggest that shallow and deep subcontinental lithosphere beneath Somerset Island represent isotopically distinct domains and do not share a common petrogenetic history. The Lu-Hf isotope systematics of the shallow low-temperature peridotites define a positively sloped line that plot along a 2.8 Ga reference isochron. A number of these peridotites are characterized by highly radiogenic Hf isotopic compositions suggestive of long-term radiogenic ingrowth (billions of years). These findings are consistent with an interpretation that the shallow Somerset lithosphere (to depths of ˜150 km) stabilized in the Archean. The majority of the high-temperature peridotites plot closer to the composition of the host kimberlite. Although the observed isotopic variation may be attributed in part to kimberlite-related Hf addition, it is possible that these deep-seated xenoliths represent younger mantle. The superchondritic 176Lu/ 177Hf ratios observed for a number of the shallow low-temperature peridotites indicate strong fractionation of Lu and Hf, suggesting mantle root formation in the garnet stability field (depths >80 km). The Hf isotope compositions for the Somerset low-temperature peridotites

  11. Issues concerning the determination of solubility products of sparingly soluble crystalline solids. Solubility of HfO{sub 2}(cr)

    Energy Technology Data Exchange (ETDEWEB)

    Rai, Dhanpat [Rai Enviro-Chem, LLC, Yachats, OR (United States); Kitamura, Akira [Japan Atomic Energy Agency, Ibaraki (Japan); Rosso, Kevin M. [Pacific Northwest National Laboratory, Richland, WA (United States); Sasaki, Takayuki; Kobayashi, Taishi [Kyoto Univ. (Japan)

    2016-11-01

    Solubility studies were conducted with HfO{sub 2}(cr) solid as a function HCl and ionic strength ranging from 2.0 to 0.004 mol kg{sup -1}. These studies involved (1) using two different amounts of the solid phase, (2) acid washing the bulk solid phase, (3) preheating the solid phase to 1400 C, and (4) heating amorphous HfO{sub 2}(am) suspensions to 90 C to ascertain whether the HfO{sub 2}(am) converts to HfO{sub 2}(cr) and to determine the solubility from the oversaturation direction. Based on the results of these treatments it is concluded that the HfO{sub 2}(cr) contains a small fraction of less crystalline, but not amorphous, material [HfO{sub 2}(lcr)] and this, rather than the HfO{sub 2}(cr), is the solubility-controlling phase in the range of experimental variables investigated in this study. The solubility data are interpreted using both the Pitzer and SIT models and they provide log{sub 10} K{sup 0} values of -(59.75±0.35) and -(59.48±0.41), respectively, for the solubility product of HfO{sub 2}(lcr)[HfO{sub 2}(lcr) + 2H{sub 2}O ↔ Hf{sup 4+} + 4OH{sup -}]. The log{sub 10} of the solubility product of HfO{sub 2}(cr) is estimated to be < -63. The observation of a small fraction of less crystalline higher solubility material is consistent with the general picture that mineral surfaces are often structurally and/or compositionally imperfect leading to a higher solubility than the bulk crystalline solid. This study stresses the urgent need, during interpretation of solubility data, of taking precautions to make certain that the observed solubility behavior for sparingly-soluble solids is assigned to the proper solid phase.

  12. Effect of Peripheral Arterial Disease on Functional and Clinical Outcomes in Patients with Heart Failure From HF-ACTION

    Science.gov (United States)

    Jones, W. Schuyler; Clare, Robert; Ellis, Stephen J.; Mills, James S.; Fischman, David L.; Kraus, William E.; Whellan, David J.; O'Connor, Christopher M.; Patel, Manesh R.

    2011-01-01

    Patients with peripheral arterial disease (PAD) have lower functional capacity and worse clinical outcomes than age and gender matched patients. Few data exist on the relationship of PAD with functional and clinical outcomes in heart failure (HF) patients. We sought to compare HF patients with and without PAD for baseline functional capacity, response to exercise training, and clinical outcomes. HF-ACTION was a randomized controlled trial comparing usual care to structured exercise training plus usual care in HF patients with an ejection fraction ≤ 35% and NYHA class II – IV heart failure symptoms. Cardiopulmonary exercise (CPX) testing occurred at enrollment, 3 months, and 1 year. Clinical follow-up occurred up to 4 years. Of the 2331 HF-ACTION patients, 157 (6.8%) had PAD. At baseline, HF patients with PAD had a lower exercise duration (8.0 vs. 9.8 minutes, p<0.001), lower peak oxygen consumption (VO2) (12.5 vs. 14.6 mL/kg/min, p<0.001), and shorter six minute walking distance (306 vs. 371 meters, p<0.001) compared to HF patients without PAD. At three months, HF patients with PAD had less improvement on CPX testing [exercise duration (0.5 vs. 1.1 minutes; p=0.002) and peak VO2 (mean change; 0.1 vs. 0.6 mL/kg/min; p=0.04)] compared to HF patients without PAD. PAD was an independent predictor of all-cause death or hospitalization [hazard ratio (95% CI); 1.31 (1.06 – 1.62), p=0.011]. PAD patients with HF have depressed baseline exercise capacity and decreased response to exercise training. In conclusion, PAD is an independent predictor of all-cause death or hospitalization in HF patients. PMID:21565325

  13. On the structural origins of ferroelectricity in HfO2 thin films

    Science.gov (United States)

    Sang, Xiahan; Grimley, Everett D.; Schenk, Tony; Schroeder, Uwe; LeBeau, James M.

    2015-04-01

    Here, we present a structural study on the origin of ferroelectricity in Gd doped HfO2 thin films. We apply aberration corrected high-angle annular dark-field scanning transmission electron microscopy to directly determine the underlying lattice type using projected atom positions and measured lattice parameters. Furthermore, we apply nanoscale electron diffraction methods to visualize the crystal symmetry elements. Combined, the experimental results provide unambiguous evidence for the existence of a non-centrosymmetric orthorhombic phase that can support spontaneous polarization, resolving the origin of ferroelectricity in HfO2 thin films.

  14. Electrical Characterisation of Ferroelectric Field Effect Transistors based on Ferroelectric HfO2 Thin Films

    OpenAIRE

    Yurchuk, Ekaterina

    2015-01-01

    Ferroelectric field effect transistor (FeFET) memories based on a new type of ferroelectric material (silicon doped hafnium oxide) were studied within the scope of the present work. Utilisation of silicon doped hafnium oxide (Si:HfO2) thin films instead of conventional perovskite ferroelectrics as a functional layer in FeFETs provides compatibility to the CMOS process as well as improved device scalability. The influence of different process parameters on the properties of Si:HfO2 thin films ...

  15. Molecular beam epitaxy of thin HfTe2 semimetal films

    Science.gov (United States)

    Aminalragia-Giamini, S.; Marquez-Velasco, J.; Tsipas, P.; Tsoutsou, D.; Renaud, G.; Dimoulas, A.

    2017-03-01

    Epitaxial thin films of 1T-HfTe2 semimetal are grown by MBE on AlN(0001) substrates. The measured in-plane lattice parameter indicates an unstrained film which is also azimuthally aligned with the AlN substrate, albeit with an in-plane mosaic spread, as it would be expected for van der Waals epitaxy. Angle resolved photoemission spectroscopy combined with first principles electronic band structure calculations show steep linearly dispersing conduction and valence bands which cross near the Brillouin zone center, providing evidence that HfTe2/AlN is an epitaxial topological Dirac semimetal.

  16. Magnetic dipole moments of High-K isomeric states in Hf isotopes

    CERN Multimedia

    Walters, W; Nishimura, K; Bingham, C R

    2007-01-01

    It is proposed to make precision measurements of the magnetic moments of 5 multi-quasi-particle K-isomers in Hf nuclei by the Nuclear Magnetic Resonance of Oriented Nuclei (NMR/ON) technique using the NICOLE on-line nuclear orientation facility and exploiting the unique HfF$_{3}$ beams recently available at ISOLDE. Results will be used to extract single-particle and collective g-factors of the isomeric states and their excitations and to shed new light on their structure.

  17. First triaxial superdeformed band in sup 1 sup 7 sup 0 Hf

    CERN Document Server

    Neusser, A; Bringel, P; Domscheit, J; Mergel, E; Nenoff, N; Singh, A K; Hagemann, G B; Jensen, D R; Bhattacharya, S; Curien, D; Dorvaux, O; Hannachi, F; López-Martens, A

    2002-01-01

    First evidence is presented for triaxial superdeformation in sup 1 sup 7 sup 0 Hf. High-spin states in this nucleus have been investigated in a gamma-ray coincidence measurement using the EUROBALL spectrometer array. A new band was discovered which has moments of inertia that are very similar to the ones of triaxial superdeformed bands in neighbouring Hf and Lu nuclei. The intensities with which these bands are populated are different from what may be expected from calculated potential-energy minima. (orig.)

  18. Analysis of the operation of a diffraction-radiation generator with preliminary HF modulation

    Science.gov (United States)

    Pivovarova, A. G.

    1991-05-01

    The excitation conditions and output characteristics of a diffraction-radiation generator with preliminary HF modulation are determined. Attention is given to the effects of the modulation parameter, the phase shift, and the aiming distance on the displacement of the generation zone, variations of the minimum starting current, the frequency shift, the oscillation amplitude, and the efficiency of the generator. It is shown that the efficiency of a generator with preliminary HF modulation can be twice as high as that of a generator without modulation.

  19. Esfuerzo triaxial ideal de Ti, Zr y Hf con estructura fcc: un estudio de primeros principios

    OpenAIRE

    A. Bautista Hernández; J.H. Camacho García; M. Salazar Villanueva; E. Chigo Anota; A. Macias Cervantes

    2011-01-01

    A temperatura y presión ambiente el Ti, Zr y Hf cristalizan en la fase hexagonal compacta. Recientemente se ha reportado que estos elementos son élasticamente metaestables [14] en la estructura cúbica centrada en las caras (fcc). En este trabajo presentamos el esfuerzo triaxial ideal de los metales Ti, Zr y Hf con estructura fcc, obtenido mediante cálculos de primeros principios usando la teoría del funcional de la densidad. Se usó la aproximación de gradiente generalizado y local de la densi...

  20. Influences of Annealing on Residual Stress and Structure of HfO2 Films

    Institute of Scientific and Technical Information of China (English)

    SHEN Yan-Ming; SHAO Shu-Ying; DENG Zhen-Xia; HE Hong-Bo; SHAO Jian-Da; FAN Zheng-Xiu

    2007-01-01

    HfO2 films are deposited on BK7 glass substrates by electron beam evaporation. The influences of annealing between 100℃ and 400℃ on residual stresses and structures of HfO2 films are studied. It is found that little differences of spectra, residual stresses and structures are obtained after annealing at lower temperatures. After annealing at higher temperatures, the spectra shift to short wavelength, the residual stress increases with the increasing annealing temperature. At the same time, the crystallite size increases and interplanar distance decreases. The variations of optical spectra and residual stress correspond to the evolutions of structures induced by annealing.

  1. Numerical modeling of HF skywave radiation from antennas in irregular terrain

    Energy Technology Data Exchange (ETDEWEB)

    Burke, G.J.

    1990-11-01

    The problem of computing the radiation pattern of an HF antenna sited in irregular terrain was investigated. The primary interest is in antennas for skywave communication, however ionospheric models were not considered. Several methods for modeling terrain effects are briefly reviewed. A geometrical optics model for arbitrary terrain is developed and results are compared with published results from solution of a Volterra integral equation for scattering by a Gaussian ridge. This report covers work on the first phase of a project for the US Navy to develop and apply models for terrain effects in HF communications involving skywave. 45 refs., 16 figs.

  2. Vacancy induced metallicity at the CaHfO3/SrTiO3 interface

    KAUST Repository

    Nazir, Safdar

    2011-03-31

    Density functional theory is used to study the electronic properties of the oxide heterointerfaceCaHfO3/SrTiO3. Structural relaxation is carried out with and without O vacancies. As compared to related interfaces, strongly reduced octahedral distortions are found. Stoichiometric interfaces between the wide band gap insulatorsCaHfO3 and SrTiO3 turn out to exhibit an insulating state. However, interface metallicity is introduced by O vacancies, in agreement with experiment. The reduced octahedral distortions and necessity of O deficiency indicate a less complicated mechanism for the creation of the interfacial electron gas.

  3. HfO 2 -based ferroelectric modulator of terahertz waves with graphene metamaterial

    Science.gov (United States)

    Jiang, Ran; Wu, Zheng-Ran; Han, Zu-Yin; Jung, Hyung-Suk

    2016-10-01

    Tunable modulations of terahertz waves in a graphene/ferroelectric-layer/silicon hybrid structure are demonstrated at low bias voltages. The modulation is due to the creation/elimination of an extra barrier in Si layer in response to the polarization in the ferroelectric Si:HfO2 layer. Considering the good compatibility of HfO2 with the Si-based semiconductor process, the highly tunable characteristics of the graphene metamaterial device under ferroelectric effect open up new avenues for graphene-based high performance integrated active photonic devices compatible with the silicon technology. Project supported by the National Natural Science Foundation of China (Grant No. 11374182).

  4. Coastal Ocean State Estimates and Forecasts based on HF Radar Data

    Science.gov (United States)

    Stanev, E. V.; Schulz-Stellenfleth, J.; Staneva, J.; Seemann, J.

    2012-04-01

    Coastal Observing System for Northern and Arctic Seas (COSYNA) collects near real-time HF radar data, which are used in parallel with numerical models to provide continuously state estimates and coastal ocean forecasts. The forecasting suite includes nested 3-D hydrodynamic models running in data-assimilation mode, which are forced with an up-to-date meteorological forecast data. This paper reviews a new method focussed on intra-tidal time scales combining radial surface currents measurements from three HF radars in the German Bight with a priori information from the hydrodynamic model. The example provided in this study is considered as a step towards developing new coastal ocean products.

  5. Illumination of the Air Environment Using Radiation of HF Broadcast Stations

    Science.gov (United States)

    Lutsenko, V. I.; Lutsenko, I. V.; Popov, I. V.

    2015-06-01

    We consider the possibility of using illumination of the HF broadcast stations for location of air objects. The relationships for estimation of the detection range are obtained and requirements for the degree of suppression of a direct signal from the broadcast station are determined. Spectral characteristics of the signals from HF broadcast stations are studied experimentally for different polarizations of the received radiation. The possibility of air object detection using the Doppler effect is shown. Theoretical estimates of the radar cross section of air objects for different polarizations of the incident radiation are given. It is found experimentally that the radar cross section is about the same for the vertical and horizontal polarizations.

  6. Effect of HF Heating Array Directivity Pattern on the Frequency Response of Generated ELF/VLF.

    Science.gov (United States)

    1983-01-01

    hhEEE|hhEE 1H ; 11:j28 111125 . mm 11111 II ll1 111 .8 MICROCOPY RESOLUTION TESI CHART I fJC ’RL_-SCI-475l I( .-cmon Numters: 1.5.1. 3.1.4, 3.2.1,.3.3...the high power HF heating facility at the Arecibo Observatory in Puerto Rico. The pattern was calculated using pattern multi- plication and method of...high power HF heating facility at the Arecibo Observatory in Puerto Rico. The pattern was calculated using pattern multiplication and method of

  7. Terrestrial bitumen analogue of orgueil organic material demonstrates high sensitivity to usual HF-HCl treatment

    Science.gov (United States)

    Korochantsev, A. V.; Nikolaeva, O. V.

    1993-01-01

    The relationship between the chemical composition and the interlayer spacing (d002) of organic materials (OM's) is known for various terrestrial OM's. We improved this general trend by correlation with corresponding trend of natural solid bitumens (asphaltite-kerite-anthraxolite) up to graphite. Using the improved trend we identified bitumen analogs of carbonaceous chondrite OM's residued after HF-HCl treatment. Our laboratory experiment revealed that these analogs and, hence, structure and chemical composition of carbonaceous chondrite OM's are very sensitive to the HF-HCl treatment. So, usual extraction of OM from carbonaceous chondrites may change significantly structural and chemical composition of extracted OM.

  8. Hydrogen doping in HfO{sub 2} resistance change random access memory

    Energy Technology Data Exchange (ETDEWEB)

    Duncan, D.; Magyari-Köpe, B.; Nishi, Y. [Department of Electrical Engineering, Stanford University, Stanford, California 94305 (United States)

    2016-01-25

    The structures and energies of hydrogen-doped monoclinic hafnium dioxide were calculated using density-functional theory. The electronic interactions are described within the LDA + U formalism, where on-site Coulomb corrections are applied to the 5d orbital electrons of Hf atoms and 2p orbital electrons of the O atoms. The effects of charge state, defect-defect interactions, and hydrogenation are investigated and compared with experiment. It is found that hydrogenation of HfO{sub 2} resistance-change random access memory devices energetically stabilizes the formation of oxygen vacancies and conductive vacancy filaments through multiple mechanisms, leading to improved switching characteristic and device yield.

  9. Dosimetry of ultraviolet radiation with BaHfO{sub 3} powders; Dosimetria de radiacion ultravioleta con polvos de BaHfO{sub 3}

    Energy Technology Data Exchange (ETDEWEB)

    Barrera A, A. A.; Aguilar D, G. A.; Guzman M, J.; Rivera M, T. [IPN, Centro de Investigacion en Ciencia Aplicada y Tecnologia Avanzada, Av. Legaria 694, Col. Irrigacion, 11500 Ciudad de Mexico (Mexico); Ceron R, V., E-mail: abalba1@hotmail.com [Universidad de Guanajuato, 37670 Leon, Guanajuato (Mexico)

    2016-10-15

    Ceramic materials based on pure barium hafnate (BaHfO{sub 3}) have been obtained as a powder by the co-precipitation method. The powders obtained have a cubic structure that favors the thermoluminescent and optical properties, through which a better detection of the non-ionizing radiation is allowed. With these powders various tests were performed in the ultraviolet range at different exposure times. These thermoluminescent (Tl) studies were carried out using a Tl 3500 hand held reader which yielded a brightness curve that ranged from room temperature to the 350 degrees Celsius. This BaHfO{sub 3} response exhibits a broad brightness curve with a single peak centered around 225 degrees Celsius. Finally, is reported that there are materials of barium hafnate (BaHfO{sub 3}) doped with some rare earths (Eu, Tb) which, instead of improving the performance of the powders, decrease it, so that the use of intrinsic barium hafnate is the most appropriate. (Author)

  10. Electronic and magnetic properties of 1T-HfS2 by doping transition-metal atoms

    Science.gov (United States)

    Zhao, Xu; Wang, Tianxing; Wang, Guangtao; Dai, Xianqi; Xia, Congxin; Yang, Lin

    2016-10-01

    We explored the electronic and magnetic properties of 1T-HfS2 doped by transition metal (TM) atom using the first-principles calculation. We doped the transition metal atoms from the IIIB to VIB groups in nonmagnetic 1T-HfS2. Numerical results show that the pristine 1T-HfS2 is a semiconductor with indirect gaps of 1.250 eV. Magnetism can be observed for V, Cr, Mn, Fe, Co, and Cu doping. The polarized charges mainly arise from the localized 3d electrons of the TM atom. The strong p-d hybridization was found between the 3d orbitals of TM and 3p orbitals of S. The substituted 1T-HfS2 can be a metal, semiconductor or half-metal. Analysis of the band structure and magnetic properties indicates that TM-doped HfS2 (TM = V, Fe, Cu) are promising systems to explore two-dimensional diluted magnetic semiconductors. The formation energy calculations also indicate that it is energetically favorable and relatively easier to incorporate transition metal atom into the HfS2 under S-rich experimental conditions. In contrast, V-doped HfS2 has relatively wide half-metallic gap and low formation energy. So V-doped 1T-HfS2 is ideal for spin injection, which is important for application in semiconductor spintronics.

  11. U-Pb ages and Hf isotope compositions of zircons in plutonic rocks from the central Famatinian arc, Argentina

    Science.gov (United States)

    Otamendi, Juan E.; Ducea, Mihai N.; Cristofolini, Eber A.; Tibaldi, Alina M.; Camilletti, Giuliano C.; Bergantz, George W.

    2017-07-01

    The Famatinian arc formed around the South Iapetus rim during the Ordovician, when oceanic lithosphere subducted beneath the West Gondwana margin. We present combined in situ U-Th-Pb and Lu-Hf isotope analyses for zircon to gain insights into the origin and evolution of Famatinian magmatism. Zircon crystals sampled from four intermediate and silicic plutonic rocks confirm previous observations showing that voluminous magmatism took place during a relatively short pulse between the Early and Middle Ordovician (472-465 Ma). The entire zircon population for the four plutonic rocks yields coherent εHf negative values and spreads over several ranges of initial εHf(t) units (-0.3 to -8.0). The range of εHf units in detrital zircons of Famatinian metasedimentary rocks reflects a prolonged history of the cratonic sources during the Proterozoic to the earliest Phanerozoic. Typical tonalites and granodiorites that contain zircons with evolved Hf isotopic compositions formed upon incorporating (meta)sedimentary materials into calc-alkaline metaluminous magmas. The evolved Hf isotope ratios of zircons in the subduction related plutonic rocks strongly reflect the Hf isotopic character of the metasedimentary contaminant, even though the linked differentiation and growth of the Famatinian arc crust was driven by ascending and evolving mantle magmas. Geochronology and Hf isotope systematics in plutonic zircons allow us understanding the petrogenesis of igneous series and the provenance of magma sources. However, these data could be inadequate for computing model ages and supporting models of crustal evolution.

  12. MoS{sub 2} on an amorphous HfO{sub 2} surface: An ab initio investigation

    Energy Technology Data Exchange (ETDEWEB)

    Scopel, W. L., E-mail: wlscopel@if.uff.br [Departamento de Física, Universidade Federal do Espírito Santo, Vitória, Brazil and Departamento de Ciências Exatas, Universidade Federal Fluminense, Volta Redonda, Rio de Janerio (Brazil); Miwa, R. H., E-mail: hiroki@infis.ufu.br; Schmidt, T. M., E-mail: tome@infis.ufu.br [Instituto de Física, Universidade Federal de Uberlândia, Uberlândia, Minas Gerais (Brazil); Venezuela, P., E-mail: vene@if.uff.br [Instituto de Física, Universidade Federal Fluminense, Niterói, Rio de Janerio (Brazil)

    2015-05-21

    The energetic stability, electronic and structural properties of MoS{sub 2} adsorbed on an amorphous a-HfO{sub 2} surface (MoS{sub 2}/HfO{sub 2}) are examined through ab initio theoretical investigations. Our total energy results indicate that the formation of MoS{sub 2}/HfO{sub 2} is an exothermic process with an adsorption energy of 34 meV/Å{sup 2}, which means that it is more stable than similar systems like graphene/HfO{sub 2} and MoS{sub 2}/SiO{sub 2}. There are no chemical bonds at the MoS{sub 2}-HfO{sub 2} interface. Upon formation of MoS{sub 2}/HfO{sub 2}, the electronic charge distribution is mostly localized at the interface region with no net charge transfer between the adsorbed MoS{sub 2} sheet and –HfO{sub 2} surface. However, the MoS{sub 2} sheet becomes n-type doped when there are oxygen vacancies in the HfO{sub 2} surface. Further investigation of the electronic distribution reveals that there are no electron- and hole-rich regions (electron-hole puddles) on the MoS{sub 2} sheet, which makes this system promising for use in high-speed nanoelectronic devices.

  13. Isothermal gas chromatography of short-lived Hf isotopes and element 104 in chlorinating, oxygen containing carrier gas

    Energy Technology Data Exchange (ETDEWEB)

    Jost, D.T.; Dressler, R.; Eichler, B.; Piguet, D.; Tuerler, A.; Gaeggeler, H.W.; Gaertner, M. [Paul Scherrer Inst. (PSI), Villigen (Switzerland); Grantz, M.; Huebener, S. [FZR (Germany); Buklanov, G.; Lebedev, V.; Timkhin, S.; Vedeneev, M.V.; Yakushev, A.; Zvara, I. [Joint Inst. for Nuclear Research, Dubna (Russian Federation)

    1997-09-01

    Based on thermodynamic state functions retention times of Hf and element 104 were calculated in the case of the simple adsorption of the tetrachlorides and the case of a complex adsorption involving a substitution process with oxygen in the chlorinating gas. Preliminary results for {sup 261}104 and Hf are shown. (author) 1 fig., 1 tab., 3 refs.

  14. A combined ab initio and Franck-Condon factor simulation study on the photodetachment spectrum of HfO2-.

    Science.gov (United States)

    Mok, Daniel K W; Lee, Edmond P F; Chau, Foo-Tim; Dyke, John M

    2008-12-28

    Restricted-spin coupled-cluster single-double plus perturbative triple excitation {RCCSD(T)} potential energy functions (PEFs) of the X[combining tilde]1A1 state of HfO2 and the X[combining tilde]2A1 state of HfO2- were computed, employing the quasi-relativistic effective core potential, ECP60MWB, and an associated contracted [13s6p6d4f3g2h] basis set designed for Hf, and the augmented correlation-consistent polarized valence quadruple-zeta (aug-cc-pVQZ) basis set for O. Based on the differences between the computed r0 and re geometrical parameters obtained from the PEF, and available experimentally derived r0 geometrical parameters of the X[combining tilde]1A1 state of HfO2, the experimental re geometrical parameters of the X[combining tilde]1A1 state of HfO2 were estimated as:-re(HfO)=1.7751 A and thetae(OHfO)=107.37 degrees. In addition, Franck-Condon factors for the HfO2 (X[combining tilde]1A1)+eVDEs) to these neutral states from the X[combining tilde]2A1 state of HfO2-.

  15. Bipolar Resistive Switching Characteristics of HfO2/TiO2/HfO2 Trilayer-Structure RRAM Devices on Pt and TiN-Coated Substrates Fabricated by Atomic Layer Deposition

    Science.gov (United States)

    Zhang, Wei; Kong, Ji-Zhou; Cao, Zheng-Yi; Li, Ai-Dong; Wang, Lai-Guo; Zhu, Lin; Li, Xin; Cao, Yan-Qiang; Wu, Di

    2017-06-01

    The HfO2/TiO2/HfO2 trilayer-structure resistive random access memory (RRAM) devices have been fabricated on Pt- and TiN-coated Si substrates with Pt top electrodes by atomic layer deposition (ALD). The effect of the bottom electrodes of Pt and TiN on the resistive switching properties of trilayer-structure units has been investigated. Both Pt/HfO2/TiO2/HfO2/Pt and Pt/HfO2/TiO2/HfO2/TiN exhibit typical bipolar resistive switching behavior. The dominant conduction mechanisms in low and high resistance states (LRS and HRS) of both memory cells are Ohmic behavior and space-charge-limited current, respectively. It is found that the bottom electrodes of Pt and TiN have great influence on the electroforming polarity preference, ratio of high and low resistance, and dispersion of the operating voltages of trilayer-structure memory cells. Compared to using symmetric Pt top/bottom electrodes, the RRAM cells using asymmetric Pt top/TiN bottom electrodes show smaller negative forming voltage of -3.7 V, relatively narrow distribution of the set/reset voltages and lower ratio of high and low resistances of 102. The electrode-dependent electroforming polarity can be interpreted by considering electrodes' chemical activity with oxygen, the related reactions at anode, and the nonuniform distribution of oxygen vacancy concentration in trilayer-structure of HfO2/TiO2/HfO2 on Pt- and TiN-coated Si. Moreover, for Pt/HfO2/TiO2/HfO2/TiN devices, the TiN electrode as oxygen reservoir plays an important role in reducing forming voltage and improving uniformity of resistive switching parameters.

  16. Enhancement of the blue photoluminescence intensity for the porous silicon with HfO2 filling into microcavities

    Science.gov (United States)

    Jiang, Ran; Du, Xianghao; Sun, Weideng; Han, Zuyin; Wu, Zhengran

    2015-10-01

    With HfO2 filled into the microcavities of the porous single-crystal silicon, the blue photoluminescence was greatly enhanced at room temperature. On one hand, HfO2 contributes to the light emission with the transitions of the defect levels for oxygen vacancy. On the other hand, the special filling-into-microcavities structure of HfO2 leads to the presence of ferroelectricity, which greatly enhances the blue emission from porous silicon. Since both HfO2 and Si are highly compatible with Si-based electronic industry, combined the low-cost and convenient process, the HfO2-filled porous Si shows a promising application prospect.

  17. Charge storage characteristics and tunneling mechanism of amorphous Ge-doped HfO{sub x} films

    Energy Technology Data Exchange (ETDEWEB)

    Qiu, X.Y.; Zhang, S.Y.; Zhang, T.; Wang, R.X.; Li, L.T.; Zhang, Y. [Southwest University, School of Physical Science and Technology, Chongqing (China); Dai, J.Y. [The Hong Kong Polytechnic University, Department of Applied Physics, Hong Kong (China)

    2016-09-15

    Amorphous Ge-doped HfO{sub x} films have been deposited on p-Si(100) substrates by means of RF magnetron sputtering. Microstructural investigations reveal the partial oxidation of doped Ge atoms in the amorphous HfO{sub x} matrix and the existence of HfSiO{sub x} interfacial layer. Capacitance-voltage hysteresis of the Ag-/Ge-doped HfO{sub x}/Si/Ag memory capacitor exhibits a memory window of 3.15 V which can maintain for >5 x 10{sup 4} cycles. Current-voltage characteristics reveal that Poole-Frenkel tunneling is responsible for electron transport in the Ge-doped HfO{sub x} film. (orig.)

  18. Orientation and growth behavior of CaHfO3 thin films on non-oxide substrates

    Energy Technology Data Exchange (ETDEWEB)

    Kwon, Y. W. [University of Florida; Norton, David P. [University of Florida; Budai, John D [ORNL

    2007-01-01

    The growth behavior of CaHfO3 on (001) Ni and Ge substrates was examined. CaHfO3 is a perovskite insulator that is suitable for applications as a buffer layer or gate dielectric. The tendency for CaHfO3 growth on both (001) Ni and (001) Ge substrates is to orient with the CaHfO3 (200)+(121) planes parallel to the surface, which corresponds to the (110) orientation in the pseudo-cubic geometry. This differs from that of CaHfO3 on perovskites, such as (001) LaAlO3, where a pseudo-cube-on-cube orientation is observed.

  19. Optical properties of a HfO2/Si stack with a trace amount of nitrogen incorporation

    Institute of Scientific and Technical Information of China (English)

    Li Ye; Jiang Tingting; Sun Qingqing; Wang Pengfei; Ding Shijin; Zhang Wei

    2012-01-01

    HfO2 films were deposited by atomic layer deposition through alternating pulsing of Hf[N(C2H5)(CH3)]4 and H2O2.A trace amount of nitrogen was incorporated into the HfO2 through ammonia annealing.The composition,the interface stability of the HfO2/Si stack and the optical properties of the annealed films were analyzed to investigate the property evolution of HfO2 during thermal treatment.With a nitrogen concentration increase from 1.41 to 7.45%,the bandgap of the films decreased from 5.82 to 4.94 eV.

  20. Influences of different oxidants on the characteristics of HfAlOx films deposited by atomic layer deposition

    Institute of Scientific and Technical Information of China (English)

    Fan Ji-Bin; Liu Hong-Xia; Ma Fei; Zhuo Qing-Qing; Hao Yue

    2013-01-01

    A comparative study of two kinds of oxidants (H2O and O3) with the combinations of two metal precursors [trimethylaluminum (TMA) and tetrakis(ethylmethylamino) hafnium (TEMAH)] for atomic layer deposition (ALD) hafnium aluminum oxide (HfAlOx) films is carried out.The effects of different oxidants on the physical properties and electrical characteristics of HfAlOx films are studied.The preliminary testing results indicate that the impurity level of HfAlOx films grown with both H2O and O3 used as oxidants can be well controlled,which has significant effects on the dielectric constant,valence band,electrical properties,and stability of HfAlOx film.Additional thermal annealing effects on the properties of HfAlOx films grown with different oxidants are also investigated.