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Sample records for supercritical steam pressure

  1. Topping PCFB combustion plant with supercritical steam pressure

    Energy Technology Data Exchange (ETDEWEB)

    Robertson, A. [Foster Wheeler Development Corp., Livingston, NJ (United States); White, J. [Parsons Power Group Inc., Reading, PA (United States)

    1997-11-01

    Research is being conducted to develop a new type of coal fired plant for electric power generation. This new type of plant, called a second generation or topping pressurized circulating fluidized bed combustion (topping PCFB) plant, offers the promise of efficiencies greater than 46 percent (HHV), with both emissions and a cost of electricity that are significantly lower than conventional pulverized coal fired plants with scrubbers. The topping PCFB plant incorporates the partial gasification of coal in a carbonizer, the combustion of carbonizer char in a pressurized circulating fluidized bed combustor (PCFB), and the combustion of carbonizer fuel gas in a topping combustor to achieve gas turbine inlet temperatures of 2,300 F and higher. After completing pilot plant tests of a carbonizer, a PCFB, and a gas turbine topping combustor, all being developed for this new plant, the authors calculated a higher heating value efficiency of 46.2 percent for the plant. In that analysis, the plant operated with a conventional 2,400 psig steam cycle with 1,000 F superheat and reheat steam and a 2.5 inch mercury condenser back pressure. This paper identifies the efficiency gains that this plant will achieve by using supercritical pressure steam conditions.

  2. High Materials Performance in Supercritical CO2 in Comparison with Atmospheric Pressure CO2 and Supercritical Steam

    Energy Technology Data Exchange (ETDEWEB)

    Holcomb, Gordon [National Energy Technology Lab. (NETL), Pittsburgh, PA, (United States); Tylczak, Joseph [National Energy Technology Lab. (NETL), Pittsburgh, PA, (United States); Carney, Casey [National Energy Technology Lab. (NETL), Pittsburgh, PA, (United States); Dogan, Omer N. [National Energy Technology Lab. (NETL), Pittsburgh, PA, (United States)

    2017-02-26

    This presentation covers environments (including advanced ultra-supercritical (A-USC) steam boiler/turbine and sCO2 indirect power cycle), effects of pressure, exposure tests, oxidation results, and mechanical behavior after exposure.

  3. Development of Steam Turbine Inlet Control Valve for Supercritical Pressure at Siemens Industrial Turbomachinery AB

    OpenAIRE

    Sors, Felix; Holm, Patrik

    2010-01-01

    The development in the steam turbine business is heading for applications with much higher steam parameters since this enables a raised efficiency. Steam parameters refer to the pressure and the temperature of the steam. The aim of this study was to generate concepts for steam turbine inlet control valves designed for higher pressure and temperature in comparison with the present design. Future steam power plants using solar energy, based on tower technology, request this kind of performance ...

  4. Influence of steam leakage through vane, gland, and shaft seals on rotordynamics of high-pressure rotor of a 1,000 MW ultra-supercritical steam turbine

    Energy Technology Data Exchange (ETDEWEB)

    Jiang, P.N. [Shanghai Jiao Tong University, Key Laboratory of Power Machinery and Engineering, Ministry of Education, School of Mechanical Engineering, Shanghai (China); Shanghai Turbine Company, Department of R and D, Shanghai (China); Wang, W.Z.; Liu, Y.Z. [Shanghai Jiao Tong University, Key Laboratory of Power Machinery and Engineering, Ministry of Education, School of Mechanical Engineering, Shanghai (China); Meng, G. [Shanghai Jiao Tong University, State Key Laboratory of Mechanical System and Vibration, School of Mechanical Engineering, Shanghai (China)

    2012-02-15

    A comparative analysis of the influence of steam leakage through vane, gland, and shaft seals on the rotordynamics of the high-pressure rotor of a 1,000 MW ultra-supercritical steam turbine was performed using numerical calculations. The rotordynamic coefficients associated with steam leakage through the three labyrinth seals were calculated using the control-volume method and perturbation analysis. A stability analysis of the rotor system subject to the steam forcing induced by the leakage flow was performed using the finite element method. An analysis of the influence of the labyrinth seal forcing on the rotordynamics was carried out by varying the geometrical parameters pertaining to the tooth number, seal clearance, and inner diameter of the labyrinth seals, along with the thermal parameters with respect to pressures and temperatures. The results demonstrated that the steam forcing with an increase in the length of the blade for the vane seal significantly influences the rotordynamic coefficients. Furthermore, the contribution of steam forcing to the instability of the rotor is decreased and increased with increases in the seal clearance and tooth number, respectively. The comparison of the rotordynamic coefficients associated with steam leakage through the vane seal, gland seal, and shaft seal convincingly disclosed that, although the steam forcing attenuates the stability of the rotor system, the steam turbine is still operating under safe conditions. (orig.)

  5. Thermodynamic properties of superheated and supercritical steam

    Energy Technology Data Exchange (ETDEWEB)

    Malhotra, A. [Indian Inst. of Technology, New Delhi (India). Dept. of Mechanical Engineering; Panda, D.M.R. [Dadri Gas Power Station, NTPC, Gautam Buddha Nagar (India)

    2001-07-01

    An existing formulation for steam properties is due to Irvine and Liley. Their equations are convenient to program and do not require excessive computational time to produce results. The properties computed from these equations compare favourably with standard data. An additional advantage of these equations is that they follow prescribed theoretical trends by reducing to perfect-gas behaviour away from the saturation dome. However, a difficulty with these equations is that, at pressures above 10 MPa and close to the saturation dome, unacceptably large errors (above 10%) are produced. These equations are examined in the present work with a view towards enhancing their range of application through the use of additional functions. It is shown that the errors may be reduced to within 1% over the entire range of pressures (both sub-critical and super-critical pressures) required in steam-plant calculations. (author)

  6. Incorporating supercritical steam turbines into molten-salt power tower plants :

    Energy Technology Data Exchange (ETDEWEB)

    Pacheco, James Edward; Wolf, Thorsten; Muley, Nishant

    2013-03-01

    Sandia National Laboratories and Siemens Energy, Inc., examined 14 different subcritical and supercritical steam cycles to determine if it is feasible to configure a molten-salt supercritical steam plant that has a capacity in the range of 150 to 200 MWe. The effects of main steam pressure and temperature, final feedwater temperature, and hot salt and cold salt return temperatures were determined on gross and half-net efficiencies. The main steam pressures ranged from 120 bar-a (subcritical) to 260 bar-a (supercritical). Hot salt temperatures of 566 and 600ÀC were evaluated, which resulted in main steam temperatures of 553 and 580ÀC, respectively. Also, the effects of final feedwater temperature (between 260 and 320ÀC) were evaluated, which impacted the cold salt return temperature. The annual energy production and levelized cost of energy (LCOE) were calculated using the System Advisory Model on 165 MWe subcritical plants (baseline and advanced) and the most promising supercritical plants. It was concluded that the supercritical steam plants produced more annual energy than the baseline subcritical steam plant for the same-size heliostat field, receiver, and thermal storage system. Two supercritical steam plants had the highest annual performance and had nearly the same LCOE. Both operated at 230 bar-a main steam pressure. One was designed for a hot salt temperature of 600ÀC and the other 565ÀC. The LCOEs for these plants were about 10% lower than the baseline subcritical plant operating at 120 bar-a main steam pressure and a hot salt temperature of 565ÀC. Based on the results of this study, it appears economically and technically feasible to incorporate supercritical steam turbines in molten-salt power tower plants.

  7. 1000 MW ultra-supercritical turbine steam parameter optimization

    Institute of Scientific and Technical Information of China (English)

    2008-01-01

    The 2 ×1000 MW ultra-supercritical steam turbine of Shanghai Waigaoqiao Phase Ⅲ project,which uses grid frequency regulation and overload control through an overload valve,is manufactured by Shanghai Turbine Company using Siemens technology.Through optimization,the steam pressure is regarded as the criterion between constant pressure and sliding pressure operation.At high circulating water temperature,the turbine overload valve is kept closed when the unit load is lower than 1000 MW while at other circulating water temperatures the turbine can run in sliding pressure operation when the unit load is higher than 1000 MW and the pressure is lower than 27 MPa This increases the unit operation efficiency.The 3D bending technology in the critical piping helps to reduce the project investment and minimize the reheat system pressure drop which improves the unit operation efficiency and safety.By choosing lower circulating water design temperature and by setting the individual Boiler Feedwater Turbine condenser to reduce the exhaust steam flow and the heat load to the main condenser,the unit average back pressure and the terminal temperature difference are minimized.Therefore,the unit heat efficiency is increased.

  8. Steam Oxidation and Chromia Evaporation in Ultra-Supercritical Steam Boilers and Turbines

    Energy Technology Data Exchange (ETDEWEB)

    Gordon H. Holcomb

    2009-01-01

    U.S. Department of Energy’s goals include power generation from coal at 60% efficiency, which requires steam conditions of up to 760 °C and 340 atm, so-called ultra-supercritical (USC) conditions. Evaporation of protective chromia scales is expected to be a primary corrosion mechanism. A methodology to calculate Cr evaporation rates from chromia scales was developed and combined with Cr diffusion calculations within the alloy (with a constant flux of Cr leaving the alloy from evaporation) to predict Cr concentration profiles and to predict the time until breakaway oxidation. At the highest temperatures and pressures, the time until breakaway oxidation was predicted to be quite short for the turbine blade, and of concern within the steam pipe and the higher temperature portions of the superheater tube. Alloy additions such as Ti may allow for a reduction in evaporation rate with time, mitigating the deleterious effects of chromia evaporation.

  9. Application of Stable-pressure Steam Purging Technology in 660MW Supercritical Once--through Boiler%660MW超临界机组稳压吹管的实践

    Institute of Scientific and Technical Information of China (English)

    郭刚; 邢燕

    2011-01-01

    Combining with the engineering practice of stable-pressure steam purging in 660 MW supercritical once-through boiler,and calculating the steam purging parameters, the application was analyzed in some aspects including parameter selection ,parameter contro%通过对超临界机组的吹管参数的计算,结合稳压吹管的实践,从吹管参数的选择、吹管过程中参数的控制以及系统的变更等几个方面进行了分析总结,对超临界机组的吹管具有一定的借鉴意义。

  10. Improvement of steam temperature control in supercritical once thru boilers

    OpenAIRE

    黒石, 卓司; 藤川, 卓爾

    2009-01-01

     New steam temperature control logic for supercritical once thru boilers was developed from the view point of simplicity similar to that of the conventional sub-critical drum type boilers. Water wall outlet steam temperature can be controlled more easily due to larger specific heat capacity of steam than super heater outlet steam temperature. By dividing temperature control into two parts, one at water wall outlet by fuel flow and the other at SH(super heater) outlet by SH spray flow, boiler ...

  11. Ultra supercritical pressure. Cho rinkaiatsu kara chocho rinkaiatsu e

    Energy Technology Data Exchange (ETDEWEB)

    Matsuo, T. (Mitsubishi Heavy Industries Ltd., Tokyo (Japan))

    1992-10-05

    In Japanese thermoelectric power plants the steam condition was made higher in pressure and temperature with a rise in the requirement to enhance the plant efficiency being spurred by a rapid increasement in the demand of electric power since 1955. It was 1967 when a supercritical power plant of 24.2 MPa steam pressure started its operation. Afterwards, the enhancement of the plant efficiency by upgrading the steam condition was again paid attention against the sharp rise in fuel cost caused by oil shock in two times originating from 1973. In 1989 Japan's first ultra supercritical pressure plant of 31.1 MPa steam pressure, Kawagoe No.1 of Chubu Electric Power Co.,Inc. began its operation and achieved an efficiency of 41.9 %, approximately 5 % higher than hitherto. In Kawagoe No.1 boiler, a 9Cr-1 Mo system material excellent in high temperature strength was put to practical use and applied to main steam tubes and super-heater tube exit headers, also a fine grained 18Cr-11Ni-Nb-Ta steel excellent in high temperature strength as well as steam oxidizing property was developed and adopted to super-heater tubes. Thus, the reduction of thermal stress and the improvement of responsiveness were attained by thinning the thickness of tube with these materials. 3 refs., 2 figs.

  12. An experimental study on flowrate and stability for 600MW supercritical steam-turbine control valve

    Institute of Scientific and Technical Information of China (English)

    相晓伟; 毛靖儒; 孙弼

    2007-01-01

    An experimental study on flowrate and stability of a type of control valve of 600MW supercritical steam-turbine was presented by measuring instruments of static, dynamic pressure and vibration in self-designed test rig. The investigation shows that flow coefficient is 30% up more than that of the control valve of GX-1 type used widely in domestic power plants now, as small-medium lifts. If the relative lift (h/D) is less than 20%, the valve can always work steadily in all the pressure ratios. When the h/D i...

  13. Ultra-Supercritical Pressure CFB Boiler Conceptual Design Study

    Energy Technology Data Exchange (ETDEWEB)

    Zhen Fan; Steve Goidich; Archie Robertson; Song Wu

    2006-06-30

    Electric utility interest in supercritical pressure steam cycles has revived in the United States after waning in the 1980s. Since supercritical cycles yield higher plant efficiencies than subcritical plants along with a proportional reduction in traditional stack gas pollutants and CO{sub 2} release rates, the interest is to pursue even more advanced steam conditions. The advantages of supercritical (SC) and ultra supercritical (USC) pressure steam conditions have been demonstrated in the high gas temperature, high heat flux environment of large pulverized coal-fired (PC) boilers. Interest in circulating fluidized bed (CFB) combustion, as an alternative to PC combustion, has been steadily increasing. Although CFB boilers as large as 300 MWe are now in operation, they are drum type, subcritical pressure units. With their sizes being much smaller than and their combustion temperatures much lower than those of PC boilers (300 MWe versus 1,000 MWe and 1600 F versus 3500 F), a conceptual design study was conducted herein to investigate the technical feasibility and economics of USC CFB boilers. The conceptual study was conducted at 400 MWe and 800 MWe nominal plant sizes with high sulfur Illinois No. 6 coal used as the fuel. The USC CFB plants had higher heating value efficiencies of 40.6 and 41.3 percent respectively and their CFB boilers, which reflect conventional design practices, can be built without the need for an R&D effort. Assuming construction at a generic Ohio River Valley site with union labor, total plant costs in January 2006 dollars were estimated to be $1,551/kW and $1,244/kW with costs of electricity of $52.21/MWhr and $44.08/MWhr, respectively. Based on the above, this study has shown that large USC CFB boilers are feasible and that they can operate with performance and costs that are competitive with comparable USC PC boilers.

  14. Cooling performance of grid-sheets for highly loaded ultra-supercritical steam turbines

    Institute of Scientific and Technical Information of China (English)

    Dieter BOHN; Robert KREWINKEL; Shuqing TIAN

    2009-01-01

    In order to increase efficiency and achieve a further CO2-reduction, the next generation of power plant turbines will have steam turbine inlet temperatures that are considerably higher than the current ones. The high pressure steam turbine inlet temperature is expected to be increased up to approximately 700℃ with a live steam pressure of 30 MPa. The elevated steam parameters in the high and intermediate pressure turbines can be encountered with Ni-base alloys, but this is a costly alternative associated with many manufacturing difficulties. Colla-borative research centre 561 "Thermally Highly Loaded,Porous and Cooled Multi-Layer Systems for Combined Cycle Power Plants" at RWTH Aachen University proposes cooling the highly loaded turbines instead, as this would necessitate the application of far less Ni-base alloys.To protect the thermally highly loaded components, a sandwich material consisting of two thin face sheets and a core made from a woven wire mesh is used to cover the walls of the steam turbine casing. The cooling steam is led through the woven wire mesh between the two face sheets to achieve a cooling effect. The wire mesh provides the grid-sheet with structural rigidity under varying operating conditions.In the present work, the cooling performance of the grid-sheets will be investigated applying the conjugate heat transfer method to ultra-supercritical live and cooling steam conditions for a section of the cooling structure. The behaviour of the flow and the heat transfer in the grid-sheet will be analyzed in detail using a parameter variation. The numerical results should give a first prediction of the cooling performance under future operating conditions.

  15. Review of the coal-fired, over-supercritical and ultra-supercritical steam power plants

    Science.gov (United States)

    Tumanovskii, A. G.; Shvarts, A. L.; Somova, E. V.; Verbovetskii, E. Kh.; Avrutskii, G. D.; Ermakova, S. V.; Kalugin, R. N.; Lazarev, M. V.

    2017-02-01

    The article presents a review of developments of modern high-capacity coal-fired over-supercritical (OSC) and ultra-supercritical (USC) steam power plants and their implementation. The basic engineering solutions are reported that ensure the reliability, economic performance, and low atmospheric pollution levels. The net efficiency of the power plants is increased by optimizing the heat balance, improving the primary and auxiliary equipment, and, which is the main thing, by increasing the throttle conditions. As a result of the enhanced efficiency, emissions of hazardous substances into the atmosphere, including carbon dioxide, the "greenhouse" gas, are reduced. To date, the exhaust steam conditions in the world power industry are p 0 ≈ 30 MPa and t 0 = 610/620°C. The efficiency of such power plants reaches 47%. The OSC plants are being operated in Germany, Denmark, Japan, China, and Korea; pilot plants are being developed in Russia. Currently, a project of a power plant for the ultra-supercritical steam conditions p 0 ≈ 35 MPa and t 0 = 700/720°C with efficiency of approximately 50% is being studied in the EU within the framework of the Thermie AD700 program, project AD 700PF. Investigations in this field have also been launched in the United States, Japan, and China. Engineering solutions are also being sought in Russia by the All-Russia Thermal Engineering Research Institute (VTI) and the Moscow Power Engineering Institute. The stated steam parameter level necessitates application of new materials, namely, nickel-base alloys. Taking into consideration high costs of nickel-base alloys and the absence in Russia of technologies for their production and manufacture of products from these materials for steam-turbine power plants, the development of power plants for steam parameters of 32 MPa and 650/650°C should be considered to be the first stage in creating the USC plants as, to achieve the above parameters, no expensive alloys are require. To develop and

  16. An experimental study on flowrate and stability for 600MW supercritical steam-turbine control valve

    Institute of Scientific and Technical Information of China (English)

    2007-01-01

    An experimental study on flowrate and stability of a type of control valve of 600MW supercritical steam-turbine was presented by measuring instruments of static, dynamic pressure and vibration in self-designed test rig. The investigation shows that flow coefficient is 30% up more than that of the control valve of GX-1 type used widely in domestic power plants now, as small-medium lifts. If the relative lift (h/D) is less than 20%, the valve can always work steadily in all the pressure ratios. When the h/D is between 20% to 24%, big vibration of valve stem occurs if the pressure ratio is between 0.7 to 0.8. When h/D is more than 25%, relatively great vibration happens in a wide range of pressure ratios of 0.4 to 0.85.

  17. Steam-Reheat Option for Supercritical-Water-Cooled Reactors

    Science.gov (United States)

    Saltanov, Eugene

    SuperCritical-Water-cooled Reactors (SCWRs) are being developed as one of the Generation-IV nuclear-reactor concepts. Main objectives of the development are to increase thermal efficiency of a Nuclear Power Plant (NPP) and to decrease capital and operational costs. The first objective can be achieved by introducing nuclear steam reheat inside a reactor and utilizing regenerative feedwater heaters. The second objective can be achieved by designing a steam cycle that closely matches that of the mature supercritical fossil-fuelled power plants. The feasibility of these objectives is discussed. As a part of this discussion, heat-transfer calculations have been performed and analyzed for SuperCritical-Water (SCW) and SuperHeated-Steam (SHS) channels of the proposed reactor concept. In the calculations a uniform and three non-uniform Axial Heat Flux Profiles (AHFPs) were considered for six different fuels (UO2, ThO 2, MOX, UC2, UC, and UN) and at average and maximum channel power. Bulk-fluid, sheath, and fuel centerline temperatures as well as the Heat Transfer Coefficient (HTC) profiles were obtained along the fuel-channel length. The HTC values are within a range of 4.7--20 kW/m2·K and 9.7--10 kW/m2·K for the SCW and SHS channels respectively. The main conclusion is that while all the mentioned fuels may be used for the SHS channel, only UC2, UC, or UN are suitable for a SCW channel, because their fuel centerline temperatures are at least 1000°C below melting point, while that of UO2, ThO2 , and MOX may reach melting point.

  18. Supercritical Fluid Chromatography, Pressurized Liquid Extraction and Supercritical Fluid Extraction

    Energy Technology Data Exchange (ETDEWEB)

    Henry, Matthew C.; Yonker, Clement R.

    2006-06-15

    In this review we examine the related fields of supercritical fluid chromatography (SFC) and supercritical fluid extraction (SFE). We reviewed the published literature in the period from November 2003 to November 2005. Well over 300 papers were published in this period. This large body of work indicates continuing active growth of the field, but an exhaustive review is beyond the scope of this work. We have chosen to include a sampling of publications that best represent the continuing trends and new ideas in the field. In keeping with past reviews on this subject1, we have broadened our scope to include fluid systems operating at high temperature and pressure, but below the critical point. Various terms have been applied to this state: sub-critical fluid extraction, pressurized liquid extraction, and accelerated solvent extraction. The term accelerated solvent extraction has been used by instrument manufacturers to refer to this process, but we will use the more descriptive term pressurized liquid extraction (PLE) to refer to these systems. Most of the research in the field is of an “evolutionary” rather than “revolutionary” nature. As in the previous review period, applications papers make up a majority of the published work. Pharmaceutical applications continue to be a strong theme. Most of the pharmaceutical work has centered on preparative, rather than analytical, separations. Chiral separations are an exception, as analytical scale separations of chiral compounds are an area of intense interest. Food and natural products represent the next largest body of work. Major themes are the isolation and characterization of high-value added foodstuffs, fragrances, and flavor compounds from novel natural materials or agricultural by-products. The areas of food, natural products, and pharmaceutical separation science converge in the area of so-called nutraceuticals. These are typically high-value products, either sold alone or as part of a fortified food, that

  19. DNS of High Pressure Supercritical Combustion

    Science.gov (United States)

    Chong, Shao Teng; Raman, Venkatramanan

    2016-11-01

    Supercritical flows have always been important to rocket motors, and more recently to aircraft engines and stationary gas turbines. The purpose of the present study is to understand effects of differential diffusion on reacting scalars using supercritical isotropic turbulence. Focus is on fuel and oxidant reacting in the transcritical region where density, heat capacity and transport properties are highly sensitive to variations in temperature and pressure. Reynolds and Damkohler number vary as a result and although it is common to neglect differential diffusion effects if Re is sufficiently large, this large variation in temperature with heat release can accentuate molecular transport differences. Direct numerical simulations (DNS) for one step chemistry reaction between fuel and oxidizer are used to examine the differential diffusion effects. A key issue investigated in this paper is if the flamelet progress variable approach, where the Lewis number is usually assumed to be unity and constant for all species, can be accurately applied to simulate supercritical combustion.

  20. Novel Supercritical Carbon Dioxide Power Cycle Utilizing Pressured Oxy-combustion in Conjunction with Cryogenic Compression

    Energy Technology Data Exchange (ETDEWEB)

    Brun, Klaus; McClung, Aaron; Davis, John

    2014-03-31

    The team of Southwest Research Institute® (SwRI) and Thar Energy LLC (Thar) applied technology engineering and economic analysis to evaluate two advanced oxy-combustion power cycles, the Cryogenic Pressurized Oxy-combustion Cycle (CPOC), and the Supercritical Oxy-combustion Cycle. This assessment evaluated the performance and economic cost of the two proposed cycles with carbon capture, and included a technology gap analysis of the proposed technologies to determine the technology readiness level of the cycle and the cycle components. The results of the engineering and economic analysis and the technology gap analysis were used to identify the next steps along the technology development roadmap for the selected cycle. The project objectives, as outlined in the FOA, were 90% CO{sub 2} removal at no more than a 35% increase in cost of electricity (COE) as compared to a Supercritical Pulverized Coal Plant without CO{sub 2} capture. The supercritical oxy-combustion power cycle with 99% carbon capture achieves a COE of $121/MWe. This revised COE represents a 21% reduction in cost as compared to supercritical steam with 90% carbon capture ($137/MWe). However, this represents a 49% increase in the COE over supercritical steam without carbon capture ($80.95/MWe), exceeding the 35% target. The supercritical oxy-combustion cycle with 99% carbon capture achieved a 37.9% HHV plant efficiency (39.3% LHV plant efficiency), when coupling a supercritical oxy-combustion thermal loop to an indirect supercritical CO{sub 2} (sCO{sub 2}) power block. In this configuration, the power block achieved 48% thermal efficiency for turbine inlet conditions of 650°C and 290 atm. Power block efficiencies near 60% are feasible with higher turbine inlet temperatures, however a design tradeoff to limit firing temperature to 650°C was made in order to use austenitic stainless steels for the high temperature pressure vessels and piping and to minimize the need for advanced turbomachinery features

  1. RPV steam generator pressure boundary

    Energy Technology Data Exchange (ETDEWEB)

    Strosnider, J.

    1996-03-01

    As the types of SG tube degradation affecting PWR SGs has changed, and improvements in tube inspection and repair technology have occurred, current SG regulatory requirements and guidance have become increasingly out of date. This regulatory situation has been dealt with on a plant-specific basis, however to resolve this problem in the long term, the NRC has begun development of a performance-based rule. As currently structured, the proposed steam generator rule would require licensees to implement SG programs that monitor the condition of the steam generator tubes against accepted performance criteria to provide reasonable assurance that the steam generator tubes remain capable of performing their intended safety functions. Currently the staff is developing three performance criteria that will ensure the tubes can continue to perform their safety function and therefore satisfy the SG rule requirements. The staff, in developing the criteria, is striving to ensure that the performance criteria have the two key attributes of being (1) measurable (enabling the tube condition to be {open_quotes}measured{close_quotes} against the criteria) and (2) tolerable (ensuring that failures to meet the criteria do not result in unacceptable consequences). A general description of the criteria are: (1) Structural integrity criteria: Ensures that the structural integrity of the SG tubes is maintained for the operating cycle consistent with the margins intended by the ASME Code. (2) Leakage integrity criteria: Ensures that postulated accident leakages and the associated dose releases are limited relative to 10 CFR Part 50 guidelines and 10 CFR Part 50 Appendix A GDC 19. (3) Operational leakage criteria: Ensures that the operating unit will be shut down as a defense-in depth measure when operational SG tube leakage exceeds established leakage limits.

  2. Supercritical-pressure light water cooled reactors

    CERN Document Server

    Oka, Yoshiaki

    2014-01-01

    This book focuses on the latest reactor concepts, single pass core and experimental findings in thermal hydraulics, materials, corrosion, and water chemistry. It highlights research on supercritical-pressure light water cooled reactors (SCWRs), one of the Generation IV reactors that are studied around the world. This book includes cladding material development and experimental findings on heat transfer, corrosion and water chemistry. The work presented here will help readers to understand the fundamental elements of reactor design and analysis methods, thermal hydraulics, materials and water

  3. Steam Oxidation at High Pressure

    Energy Technology Data Exchange (ETDEWEB)

    Holcomb, Gordon R. [NETL; Carney, Casey [URS

    2013-07-19

    A first high pressure test was completed: 293 hr at 267 bar and 670{degrees}C; A parallel 1 bar test was done for comparison; Mass gains were higher for all alloys at 267 bar than at 1 bar; Longer term exposures, over a range of temperatures and pressures, are planned to provide information as to the commercial implications of pressure effects; The planned tests are at a higher combination of temperatures and pressures than in the existing literature. A comparison was made with longer-term literature data: The short term exposures are largely consistent with the longer-term corrosion literature; Ferritic steels--no consistent pressure effect; Austenitic steels--fine grain alloys less able to maintain protective chromia scale as pressure increases; Ni-base alloys--more mass gains above 105 bar than below. Not based on many data points.

  4. Gasification Mechanism of Carbon with Supercritical Water at Very High Pressures: Effects on H2 Production.

    Science.gov (United States)

    Martin-Sanchez, Nicolas; Salvador, Francisco; Sanchez-Montero, M Jesus; Izquierdo, Carmen

    2014-08-07

    The scarce data concerning the gasification of carbonaceous solids with supercritical water (SCW) suggest the great potential of this method to produce a valuable green fuel such as H2. However, the extraordinary properties of SCW have not been properly applied to H2 production because the mechanism that governs gasification under these conditions remains unclear. Here, we present a study in which this reaction is explored within the largest pressure range ever assayed in this field, from 1 to 1000 bar. The amplitude of the experimental conditions investigated highlights the various pathways that govern gasification with steam and SCW. Under supercritical conditions, the clusters formed around the superficial groups of the solid reduce the energetic requirements for gasification and generate CO2 as a primary product of the reaction. Consequently, gasification with SCW is significantly faster than that using steam, and the produced gases are richer and more appropriate to obtain pure H2.

  5. Simulation of heat transfer in combustion chamber waterwall tubes of supercritical steam boilers

    Directory of Open Access Journals (Sweden)

    Grądziel Sławomir

    2016-06-01

    Full Text Available The paper presents the results of numerical computations performed for the furnace chamber waterwalls of a supercritical boiler with a steam output of 2400 × 103 kg/h. A model of distributed parameters is proposed for the waterwall operation simulation. It is based on the solution of equations describing the mass, momentum and energy conservation laws. The aim of the calculations was to determine the distribution of enthalpy, mass flow and fluid pressure in tubes. The balance equations can be brought to a form where on the left-hand side space derivatives, and on the right-hand side – time derivatives are obtained. The time derivatives on the right-hand side were replaced with backward difference quotients. This system of ordinary differential equations was solved using the Runge-Kutta method. The calculation also takes account of the variable thermal load of the chamber along its height. This thermal load distribution is known from the calculations of the heat exchange in the combustion chamber. The calculations were carried out with the zone method.

  6. Features of steam turbine cooling by the example of an SKR-100 turbine for supercritical steam parameters

    Science.gov (United States)

    Arkadyev, B. A.

    2015-10-01

    Basic principles of cooling of high-temperature steam turbines and constructive solutions used for development of the world's first cooled steam turbine SKR-100 (R-100-300) are described. Principal differences between the thermodynamic properties of cooling medium in the steam and gas turbines and the preference of making flow passes of cooled cylinders of steam turbines as reactive are shown. Some of its operation results and their conclusions are given. This turbine with a power of 100 MW, initial steam parameters approximately 30 MPa and 650°C, and back pressure 3 MPa was made by a Kharkov turbine plant in 1961 and ran successfully at a Kashira GRES (state district power plant) up to 1979, when it was taken out of use in a still fully operating condition. For comparison, some data on construction features and operation results of the super-high pressure cylinder of steam turbines of American Philo 6 (made by General Electric Co.) and Eddystone 1 (made by Westinghouse Co.) power generating units, which are close to the SKR-100 turbine by design initial steam parameters and the implementation time, are given. The high operational reliability and effectiveness of the cooling system that was used in the super-high pressure cylinder of the SKR-100 turbine of the power-generating unit, which were demonstrated in operation, confirms rightfulness and expediency of principles and constructive solutions laid at its development. As process steam temperatures are increased, the realization of the proposed approach to cooling of multistage turbines makes it possible to limit for large turbine parts the application of new, more expensive high-temperature materials, which are required for making steam boilers, and, in some cases, to do completely away with their utilization.

  7. Next Generation Engineered Materials for Ultra Supercritical Steam Turbines

    Energy Technology Data Exchange (ETDEWEB)

    Douglas Arrell

    2006-05-31

    To reduce the effect of global warming on our climate, the levels of CO{sub 2} emissions should be reduced. One way to do this is to increase the efficiency of electricity production from fossil fuels. This will in turn reduce the amount of CO{sub 2} emissions for a given power output. Using US practice for efficiency calculations, then a move from a typical US plant running at 37% efficiency to a 760 C /38.5 MPa (1400 F/5580 psi) plant running at 48% efficiency would reduce CO2 emissions by 170kg/MW.hr or 25%. This report presents a literature review and roadmap for the materials development required to produce a 760 C (1400 F) / 38.5MPa (5580 psi) steam turbine without use of cooling steam to reduce the material temperature. The report reviews the materials solutions available for operation in components exposed to temperatures in the range of 600 to 760 C, i.e. above the current range of operating conditions for today's turbines. A roadmap of the timescale and approximate cost for carrying out the required development is also included. The nano-structured austenitic alloy CF8C+ was investigated during the program, and the mechanical behavior of this alloy is presented and discussed as an illustration of the potential benefits available from nano-control of the material structure.

  8. Study on Oxygenated Treatment of High-pressure Heater Steam-Liquid Phase Transition Zone for Ultra-Supercritical Units%高压加热器汽液相变区氧化处理技术在超超临界发电机组上的应用

    Institute of Scientific and Technical Information of China (English)

    施国忠; 刘春红

    2015-01-01

    The traditional oxygenated treatment of feedwater jeopardizes operation safety of units due to falling-off of oxide skin of superheater. However, low oxygenated treatment of feedwater can not drastically e-liminate flow accelerated corrosion of feedwater and steam-liquid phase transition zone. After oxygenated treat-ment in steam-liquid phase transition zone of high-pressure heater of ultra-supercritical units, accurate, fixed-point and quantitative oxygenated treatment is achieved and flow accelerated corrosion of phase transition zone for high-pressure heater is successfully eliminated; in the meantime, the risk of oxide skin falling-off of superheater is prevented and the security and economical efficiency of the units are improved. After oxygenat-ed treatment of steam-liquid phase transition zone, conversion speed of the dense Fe2O3 oxide film is fast, Fe concentration of high-pressure heater drainage decreases by 85%and Fe concentration is less than 1μg/L.%传统的给水加氧工艺由于存在过热器氧化皮剥落风险,危及机组安全运行,而给水低氧处理工艺又无法彻底解决给水和汽液相变区流动加速腐蚀的问题。对超超临界发电机组高压加热器汽液相变区采用氧化处理技术,实现精确、定点、定量加氧处理,成功解决了高压加热器汽液相变区的流动加速腐蚀问题,又避免了过热器氧化皮剥落的风险,提高了机组的安全经济性。高加汽液相变区进行氧化处理后,致密的Fe2O3氧化膜转化速度快,高加疏水Fe浓度下降达85%, Fe浓度小于1μg/L。

  9. Novel Supercritical Carbon Dioxide Power Cycle Utilizing Pressured Oxy-combustion in Conjunction with Cryogenic Compression

    Energy Technology Data Exchange (ETDEWEB)

    Brun, Klaus; McClung, Aaron; Davis, John

    2014-03-31

    The team of Southwest Research Institute® (SwRI) and Thar Energy LLC (Thar) applied technology engineering and economic analysis to evaluate two advanced oxy-combustion power cycles, the Cryogenic Pressurized Oxy-combustion Cycle (CPOC), and the Supercritical Oxy-combustion Cycle. This assessment evaluated the performance and economic cost of the two proposed cycles with carbon capture, and included a technology gap analysis of the proposed technologies to determine the technology readiness level of the cycle and the cycle components. The results of the engineering and economic analysis and the technology gap analysis were used to identify the next steps along the technology development roadmap for the selected cycle. The project objectives, as outlined in the FOA, were 90% CO{sub 2} removal at no more than a 35% increase in cost of electricity (COE) as compared to a Supercritical Pulverized Coal Plant without CO{sub 2} capture. The supercritical oxy-combustion power cycle with 99% carbon capture achieves a COE of $121/MWe. This revised COE represents a 21% reduction in cost as compared to supercritical steam with 90% carbon capture ($137/MWe). However, this represents a 49% increase in the COE over supercritical steam without carbon capture ($80.95/MWe), exceeding the 35% target. The supercritical oxy-combustion cycle with 99% carbon capture achieved a 37.9% HHV plant efficiency (39.3% LHV plant efficiency), when coupling a supercritical oxy-combustion thermal loop to an indirect supercritical CO{sub 2} (sCO{sub 2}) power block. In this configuration, the power block achieved 48% thermal efficiency for turbine inlet conditions of 650°C and 290 atm. Power block efficiencies near 60% are feasible with higher turbine inlet temperatures, however a design tradeoff to limit firing temperature to 650°C was made in order to use austenitic stainless steels for the high temperature pressure vessels and piping and to minimize the need for advanced turbomachinery features

  10. Modeling steam pressure under martian lava flows

    Science.gov (United States)

    Dundas, Colin M.; Keszthelyi, Laszlo P.

    2013-01-01

    Rootless cones on Mars are a valuable indicator of past interactions between lava and water. However, the details of the lava–water interactions are not fully understood, limiting the ability to use these features to infer new information about past water on Mars. We have developed a model for the pressurization of a dry layer of porous regolith by melting and boiling ground ice in the shallow subsurface. This model builds on previous models of lava cooling and melting of subsurface ice. We find that for reasonable regolith properties and ice depths of decimeters, explosive pressures can be reached. However, the energy stored within such lags is insufficient to excavate thick flows unless they draw steam from a broader region than the local eruption site. These results indicate that lag pressurization can drive rootless cone formation under favorable circumstances, but in other instances molten fuel–coolant interactions are probably required. We use the model results to consider a range of scenarios for rootless cone formation in Athabasca Valles. Pressure buildup by melting and boiling ice under a desiccated lag is possible in some locations, consistent with the expected distribution of ice implanted from atmospheric water vapor. However, it is uncertain whether such ice has existed in the vicinity of Athabasca Valles in recent history. Plausible alternative sources include surface snow or an aqueous flood shortly before the emplacement of the lava flow.

  11. Modeling Creep-Fatigue-Environment Interactions in Steam Turbine Rotor Materials for Advanced Ultra-supercritical Coal Power Plants

    Energy Technology Data Exchange (ETDEWEB)

    Shen, Chen [General Electric Global Research, Niskayuna, NY (United States)

    2014-04-01

    The goal of this project is to model creep-fatigue-environment interactions in steam turbine rotor materials for advanced ultra-supercritical (A-USC) coal power Alloy 282 plants, to develop and demonstrate computational algorithms for alloy property predictions, and to determine and model key mechanisms that contribute to the damages caused by creep-fatigue-environment interactions.

  12. Corrosion of several metals in supercritical steam at 538/sup 0/C. [85 alloys

    Energy Technology Data Exchange (ETDEWEB)

    McCoy, H. E.; McNabb, B.

    1977-05-01

    The corrosion of several iron- and nickel-base alloys in supercritical steam at 24.1 MPa (3500 psi) and 538/sup 0/C was measured to 7.92 x 10/sup 7/ s (22,000 h). The experiments were carried out in TVA's Bull Run Steam Plant. Corrosion was measured almost entirely by weight change and visual appearance; a few samples were evaluated by more descriptive analytical techniques. The corrosion rates of low-alloy ferritic steels containing from 1.1 to 8.7 percent Cr and 0.5 to 1.0 percent Mo differed by less than a factor of 2 in steam. Several modified compositions of Hastelloy N were evaluated and found to corrode at about equivalent rates. Of the alloys studied, the lowest weight gain in 3.6 x 10/sup 7/ sec (10,000 hr) was 0.01 mg/cm/sup 2/ for Inconel 718 and the highest 10 mg/cm/sup 2/ for the low-alloy ferritic steels. 25 figures, 3 tables.

  13. Materials for Advanced Ultra-supercritical (A-USC) Steam Turbines – A-USC Component Demonstration

    Energy Technology Data Exchange (ETDEWEB)

    Purgert, Robert [Energy Industries Of Ohio Inc., Independence, OH (United States); Phillips, Jeffrey [Energy Industries Of Ohio Inc., Independence, OH (United States); Hendrix, Howard [Energy Industries Of Ohio Inc., Independence, OH (United States); Shingledecker, John [Energy Industries Of Ohio Inc., Independence, OH (United States); Tanzosh, James [Energy Industries Of Ohio Inc., Independence, OH (United States)

    2016-10-01

    The work by the United States Department of Energy (U.S. DOE)/Ohio Coal Development Office (OCDO) advanced ultra-supercritical (A-USC) Steam Boiler and Turbine Materials Consortia from 2001 through September 2015 was primarily focused on lab scale and pilot scale materials testing. This testing included air- or steam-cooled “loops” that were inserted into existing utility boilers to gain exposure of these materials to realistic conditions of high temperature and corrosion due to the constituents in the coal. Successful research and development resulted in metallic alloy materials and fabrication processes suited for power generation applications with metal temperatures up to approximately 1472°F (800°C). These materials or alloys have shown, in extensive laboratory tests and shop fabrication studies, to have excellent applicability for high-efficiency low CO2 transformational power generation technologies previously mentioned. However, as valuable as these material loops have been for obtaining information, their scale is significantly below that required to minimize the risk associated with a power company building a multi-billion dollar A-USC power plant. To decrease the identified risk barriers to full-scale implementation of these advanced materials, the U.S. DOE/OCDO A-USC Steam Boiler and Turbine Materials Consortia identified the key areas of the technology that need to be tested at a larger scale. Based upon the recommendations and outcome of a Consortia-sponsored workshop with the U.S.’s leading utilities, a Component Test (ComTest) Program for A-USC was proposed. The A-USC ComTest program would define materials performance requirements, plan for overall advanced system integration, design critical component tests, fabricate components for testing from advanced materials, and carry out the tests. The AUSC Component Test was premised on the program occurring at multiple facilities, with the operating temperatures, pressure and/or size of

  14. Vortex Pressure-Reducing Desuperheating Plants and Steam Coolers

    Directory of Open Access Journals (Sweden)

    V. Kascheev

    2012-01-01

    Full Text Available The authors have developed and tested the entire device class that appeared as a result of fundamental investigations of multiphase flows in centrifugal force fields, understanding of process mechanism occurring in them and their mathematical description for optimization. Method for reduction of pressure and steam temperature in vortex pressure-reducing desuperheating plants and steam coolers has been proposed for the first time in the paper.

  15. Subchannel analysis with turbulent mixing rate of supercritical pressure fluid

    Energy Technology Data Exchange (ETDEWEB)

    Wu, Jianhui, E-mail: wjianhui1985@gmail.com [Department of Applied Physics, Waseda University, Tokyo 169-8555 (Japan); Oka, Yoshiaki [Emeritus Professor the University of Tokyo, Tokyo (Japan)

    2015-06-15

    Highlights: • Subchannel analysis with turbulent mixing rate law of supercritical pressure fluid (SPF) is carried out. • Turbulent mixing rate is enhanced, compared with that calculated by the law of pressurized water reactor (PWR). • Increase in maximum cladding surface temperature (MCST) is smaller comparing with PWR model. • The sensitivities of MCST on non-uniformity of subchannel area and power peaking are reduced by using SPF model. - Abstract: The subchannel analysis with turbulent mixing rate law of supercritical pressure fluid (SPF) is carried out for supercritical-pressurized light water cooled and moderated reactor (Super LWR). It is different from the turbulent mixing rate law of pressurized water reactor (PWR), which is widely adopted in Super LWR subchannel analysis study, the density difference between adjacent subchannels is taken into account for turbulent mixing rate law of SPF. MCSTs are evaluated on three kinds of fuel assemblies with different pin power distribution patterns, gap spacings and mass flow rates. Compared with that calculated by employing turbulent mixing rate law of PWR, the increase in MCST is smaller even when peaking factor is large and gap spacing is uneven. The sensitivities of MCST on non-uniformity of the subchannel area and power peaking are reduced.

  16. 49 CFR 230.63 - Smoke box, steam pipes and pressure parts.

    Science.gov (United States)

    2010-10-01

    ... ADMINISTRATION, DEPARTMENT OF TRANSPORTATION STEAM LOCOMOTIVE INSPECTION AND MAINTENANCE STANDARDS Boilers and Appurtenances Steam Pipes § 230.63 Smoke box, steam pipes and pressure parts. The smoke box, steam pipes and... 49 Transportation 4 2010-10-01 2010-10-01 false Smoke box, steam pipes and pressure parts....

  17. Development of a Facility for Combustion Stability Experiments at Supercritical Pressure

    Science.gov (United States)

    2013-12-01

    Supercritical Pressure 5a. CONTRACT NUMBER In-House 5b. GRANT NUMBER 5c. PROGRAM ELEMENT NUMBER 6. AUTHOR(S) Wegener, Leyva, Forliti, Talley 5d... supercritical pressures that are relevant to high-performance liquid rocket engines, accurately-controlled and cryogenically-conditioned propellants, and... Supercritical Pressure Jeffrey L. Wegener1 University of California at Los Angeles, CA 90095 Ivett A. Leyva2 AFRL/RQRE, Edwards AFB, CA 93524

  18. The condensation of steam from steam-water mixture on water jets at high pressure

    Science.gov (United States)

    Somova, E. V.; Kisina, V. I.; Shvarts, A. L.; Kolbasnikov, A. V.; Kanishchev, V. P.

    2009-01-01

    A physical model for condensation of steam in water flow at high pressure is developed, and analytical dependences for calculating heat transfer are obtained, in particular as applied to the operation of a direct-contact feedwater heater for a new-generation reactor plant with lead coolant.

  19. Effect of pressurized steam on AA1050 aluminium

    DEFF Research Database (Denmark)

    Jariyaboon, Manthana; Møller, Per; Ambat, Rajan

    2012-01-01

    Purpose - The purpose of this paper is to understand the effect of pressurized steam on surface changes, structures of intermetallic particles and corrosion behavior of AA1050 aluminium. Design/methodology/approach - Industrially pure aluminium (AA1050, 99.5 per cent) surfaces were exposed...... reactivities was observed due to the formation of the compact oxide layer. Originality/value - This paper reveals a detailed investigation of how pressurized steam can affect the corrosion behaviour of AA1050 aluminium and the structure of Fe-containing intermetallic particles....

  20. Stability analysis of supercritical-pressure light water-cooled reactor in constant pressure operation

    Energy Technology Data Exchange (ETDEWEB)

    Suhwan, JI; Shirahama, H.; Koshizuka, S.; Oka, Y. [Tokyo Univ., Tokai, Ibaraki (Japan). Nuclear Engineering Research Lab.

    2001-07-01

    The purpose of this study is to evaluate the thermal-hydraulic and the thermal-nuclear coupled stabilities of a supercritical pressure light water-cooled reactor. A stability analysis code at supercritical pressure is developed. Using this code, stabilities of full and partial-power reactor operating at supercritical pressure are investigated by the frequency-domain analysis. Two types of SCRs are analyzed; a supercritical light water reactor (SCLWR) and a supercritical water-cooled fast reactor (SCFR). The same stability criteria as Boiling Water Reactor are applied. The thermal-hydraulic stability of SCLWR and SCFR satisfies the criteria with a reasonable orifice loss coefficient. The decay ratio of the thermal-nuclear coupled stability in SCFR is almost zero because of a small coolant density coefficient of the fast reactor. The evaluated decay ratio of the thermal-nuclear coupled stability is 3,41 {approx} 10{sup -V} at 100% power in SCFR and 0,028 at 100% power in SCLWR. The sensitivity is investigated. It is found that the thermal-hydraulic stability is sensitive to the mass flow rate strongly and the thermal-nuclear coupled stability to the coolant density coefficient. The bottom power peak distribution makes the thermal-nuclear stability worse and the thermal-nuclear stability better. (author)

  1. Length scales in cryogenic injection at supercritical pressure

    Energy Technology Data Exchange (ETDEWEB)

    Branam, R.; Mayer, W. [German Aerospace Center, DLR Lampoldshausen, 74239 Hardthausen (Germany)

    2002-09-01

    Length scales provide some understanding of the injection of cryogenic propellants in rocket chambers on mixing efficiency, which translates to burning efficiency and performance. This project uses supercritical cryogenic nitrogen to look at high-density core flows such as those of coaxial injectors used in rocket engines. The investigation considers test conditions from 4.0 to 6.0 MPa chamber pressure at two injection velocities and temperatures. Experimental data taken by using shadowgraph images provides a means of characterizing turbulent flow structures using a two-point correlation method to determine length scales and structure shapes. The experimental results are compared to computational models. (orig.)

  2. Large Eddy Simulations of turbulent flows at supercritical pressure

    Energy Technology Data Exchange (ETDEWEB)

    Kunik, C.; Otic, I.; Schulenberg, T., E-mail: claus.kunik@kit.edu, E-mail: ivan.otic@kit.edu, E-mail: thomas.schulenberg@kit.edu [Karlsruhe Inst. of Tech. (KIT), Karlsruhe (Germany)

    2011-07-01

    A Large Eddy Simulation (LES) method is used to investigate turbulent heat transfer to CO{sub 2} at supercritical pressure for upward flows. At those pressure conditions the fluid undergoes strong variations of fluid properties in a certain temperature range, which can lead to a deterioration of heat transfer (DHT). In this analysis, the LES method is applied on turbulent forced convection conditions to investigate the influence of several subgrid scale models (SGS-model). At first, only velocity profiles of the so-called inflow generator are considered, whereas in the second part temperature profiles of the heated section are investigated in detail. The results are statistically analyzed and compared with DNS data from the literature. (author)

  3. Estimation of ex-vessel steam explosion pressure loads

    Energy Technology Data Exchange (ETDEWEB)

    Leskovar, Matjaz [Jozef Stefan Institute, Jamova cesta 39, SI-1000 Ljubljana (Slovenia)], E-mail: matjaz.leskovar@ijs.si; Ursic, Mitja [Jozef Stefan Institute, Jamova cesta 39, SI-1000 Ljubljana (Slovenia)

    2009-11-15

    An ex-vessel steam explosion may occur when, during a severe reactor accident, the reactor vessel fails and the molten core pours into the water in the reactor cavity. A steam explosion is a fuel coolant interaction process where the heat transfer from the melt to water is so intense and rapid that the timescale for heat transfer is shorter than the timescale for pressure relief. This can lead to the formation of shock waves and production of missiles that may endanger surrounding structures. A strong enough steam explosion in a nuclear power plant could jeopardize the containment integrity and so lead to a direct release of radioactive material to the environment. In this article, different scenarios of ex-vessel steam explosions in a typical pressurized water reactor cavity are analyzed with the code MC3D, which is being developed for the simulation of fuel-coolant interactions. A parametric study was performed varying the location of the melt release (central, right and left side melt pour), the cavity water subcooling, the primary system overpressure at vessel failure and the triggering time for explosion calculations. The main purpose of the study was to establish the influence of the varied parameters on the fuel-coolant interaction behaviour, to determine the most challenging cases and to estimate the expected pressure loadings on the cavity walls. For the most explosive central, right side and left side melt pour scenarios a detailed analysis of the explosion simulation results was performed. The study shows that for some ex-vessel steam explosion scenarios higher pressure loads are predicted than obtained in the OECD programme SERENA phase 1.

  4. Dual Pressure versus Hybrid Recuperation in an Integrated Solid Oxide Fuel Cell Cycle – Steam Cycle

    DEFF Research Database (Denmark)

    Rokni, Masoud

    2014-01-01

    steam in a HRSG (heat recovery steam generator). The bottoming steam cycle was modeled with two configurations: (1) a simple single pressure level and (2) a dual pressure level with both a reheat and a pre-heater. The SOFC stacks in the present SOFC-ST hybrid cycles were not pressurized. The dual...

  5. 46 CFR 54.01-10 - Steam-generating pressure vessels (modifies U-1(g)).

    Science.gov (United States)

    2010-10-01

    ...)). (a) Pressure vessels in which steam is generated are classed as “Unfired Steam Boilers” except as required otherwise by paragraph (b) of this section. Unfired steam boilers must be fitted with an efficient... § 54.15-15. Unfired steam boilers must be constructed in accordance with this part other than when...

  6. Simulations of dissociation constants in low pressure supercritical water

    Science.gov (United States)

    Halstead, S. J.; An, P.; Zhang, S.

    2014-09-01

    This article reports molecular dynamics simulations of the dissociation of hydrochloric acid and sodium hydroxide in water from ambient to supercritical temperatures at a fixed pressure of 250 atm. Corrosion of reaction vessels is known to be a serious problem of supercritical water, and acid/base dissociation can be a significant contributing factor to this. The SPC/e model was used in conjunction with solute models determined from density functional calculations and OPLSAA Lennard-Jones parameters. Radial distribution functions were calculated, and these show a significant increase in solute-solvent ordering upon forming the product ions at all temperatures. For both dissociations, rapidly decreasing entropy of reaction was found to be the controlling thermodynamic factor, and this is thought to arise due to the ions produced from dissociation maintaining a relatively high density and ordered solvation shell compared to the reactants. The change in entropy of reaction reaches a minimum at the critical temperature. The values of pKa and pKb were calculated and both increased with temperature, in qualitative agreement with other work, until a maximum value at 748 K, after which there was a slight decrease.

  7. COMPUTATIONAL FLUID DYNAMIC ANALYSIS OF INTERMEDIATE PRESSURE STEAM TURBINE

    OpenAIRE

    C RAJESH BABU

    2013-01-01

    a steam prime mover with rotary motion of the driving element, or rotor, and continuous operation. It converts the thermal energy of steam into mechanical work. The steam flow proceeds through directing devices and impinges on curved blades mounted along the periphery of the rotor. By exerting a force on the blades, the steam flow causes the rotor to rotate. Unlike the reciprocating steam engine, the steam turbine makes use of the kinetic rather than the potential energy of steam. The perform...

  8. Supercritical Once-through Boiler Main Steam Temperature Control%超临界直流锅炉主汽温的控制

    Institute of Scientific and Technical Information of China (English)

    丁超

    2014-01-01

    在超临界直流锅炉的运行过程中,主蒸汽温度是一个重要的参数,其控制方法与汽包锅炉不同。通过分析超临界直流锅炉主汽温控制的基本方法,以期对现场主汽温的控制起到理论指导的作用。%In the process of running a supercritical once-through boiler, the main steam temperature is an important parameter, which controls the different methods and drum boiler. This paper analyzes the basic method of supercritical once-through boiler main steam temperature control;with a view of the main steam temperature control of the scene plays the role of theoretical guidance.

  9. Engineering solutions related to the furnace arrangement of a boiler designed for operating at supercritical steam conditions

    Science.gov (United States)

    Shtegman, A. V.; Ryzhii, I. A.; Sosin, D. V.; Kotler, V. R.

    2014-04-01

    When developing a coal-fired power unit designed for operating at supercritical steam conditions (SSCs), it is necessary not only to achieve high economic performance and the high reliability of a new power unit, but also to tackle many problems related to the efficient combustion of the solid fuel without exceeding the future standards for limitations on emissions of harmful substances into the atmosphere. The technological methods of suppression of nitrogen oxides capable of providing the permissible NO x emissions are discussed. The results of calculations are given that demonstrate the feasibility of achieving the purpose in view by means of installation of new low-NO x burners and staged injection of the fuel even on combustion of the Ekibastuz black coal high in ash content.

  10. Literature survey of heat transfer and hydraulic resistance of water, carbon dioxide, helium and other fluids at supercritical and near-critical pressures

    Energy Technology Data Exchange (ETDEWEB)

    Pioro, I.L.; Duffey, R.B

    2003-04-01

    This survey consists of 430 references, including 269 Russian publications and 161 Western publications devoted to the problems of heat transfer and hydraulic resistance of a fluid at near-critical and supercritical pressures. The objective of the literature survey is to compile and summarize findings in the area of heat transfer and hydraulic resistance at supercritical pressures for various fluids for the last fifty years published in the open Russian and Western literature. The analysis of the publications showed that the majority of the papers were devoted to the heat transfer of fluids at near-critical and supercritical pressures flowing inside a circular tube. Three major working fluids are involved: water, carbon dioxide, and helium. The main objective of these studies was the development and design of supercritical steam generators for power stations (utilizing water as a working fluid) in the 1950s, 1960s, and 1970s. Carbon dioxide was usually used as the modeling fluid due to lower values of the critical parameters. Helium, and sometimes carbon dioxide, were considered as possible working fluids in some special designs of nuclear reactors. (author)

  11. Discussion on Feasibility and Economy of 1000-MW Ultra-Supercritical Air-Cooling Unit

    Institute of Scientific and Technical Information of China (English)

    Zhu Jun; Wang Yunze; Jin Wen

    2007-01-01

    @@ Based on analysis on types and features of domestically made 1000-MW large ultra supercritical steam turbine and 600-MW air cooling steam turbine,the author puts forward that 1000-MW ultra supercritical air-cooling turbine can be assembled with high and medium pressure cylinder modules of 1000-MW ultra-supercritical steam turbine and low-pressure cylinder module of 600-MW tow-cylinder and tow-exhaust air-cooling turbine.In addition,the economy of the assembled turbine is discussed, and designing considerations and issues need to be furtherstudied are proposed as well.

  12. Accelerated growth of oxide film on aluminium alloys under steam: Part II: Effects of alloy chemistry and steam vapour pressure on corrosion and adhesion performance

    DEFF Research Database (Denmark)

    Din, Rameez Ud; Bordo, Kirill; Jellesen, Morten Stendahl

    2015-01-01

    The steam treatment of aluminium alloys with varying vapour pressure of steamresulted in the growth of aluminium oxyhydroxide films of thickness range between 450 - 825nm. The surface composition, corrosion resistance, and adhesion of the produced films was characterised by XPS, potentiodynamic...... of the vapour pressure of the steam. The accelerated corrosion and adhesion tests on steam generated oxide films with commercial powder coating verified that the performance of the oxide coating is highly dependent on the vapour pressure of the steam....

  13. Accelerated growth of oxide film on aluminium alloys under steam: Part II: Effects of alloy chemistry and steam vapour pressure on corrosion and adhesion performance

    DEFF Research Database (Denmark)

    Din, Rameez Ud; Bordo, Kirill; Jellesen, Morten Stendahl;

    2015-01-01

    The steam treatment of aluminium alloys with varying vapour pressure of steamresulted in the growth of aluminium oxyhydroxide films of thickness range between 450 - 825nm. The surface composition, corrosion resistance, and adhesion of the produced films was characterised by XPS, potentiodynamic...... of the vapour pressure of the steam. The accelerated corrosion and adhesion tests on steam generated oxide films with commercial powder coating verified that the performance of the oxide coating is highly dependent on the vapour pressure of the steam....

  14. Digest of "Invariant Method of Load Independent Pressure Control in Steam Boiler"

    OpenAIRE

    Sniders, Andris; Komass, Toms

    2012-01-01

    The paper considers the possibility of steam production and supply process improvement by perfection of the steam boiler control system, applying invariance principle that makes possible preemptive compensation of the influence of steam expenditure as a disturbance on the control process quality and efficiency. For the development of invariant control system, the mathematical modeling and simulation in MATLAB - SIMULINK environment is made. The control unit is low pressure steam boiler with o...

  15. Rupture pressure of wear degraded alloy 600 steam generator tubings

    Science.gov (United States)

    Hwang, Seong Sik; Namgung, Chan; Jung, Man Kyo; Kim, Hong Pyo; Kim, Joung Soo

    2008-02-01

    Fretting/wear degradation at the tube support in the U-bend region of a steam generator (SG) of a pressurized water reactor (PWR) has been reported. Simulated fretted flaws were machined on SG tubes of 195 mm in length. A pressure test was carried out with the tubes at room temperature by using a high pressure test facility which consisted of a water pressurizing pump, a test specimen section and a control unit. Water leak rates just after a ligament rupture or a burst were measured. Tubes degraded by up to 70% of the tube wall thickness (TW) showed a high safety margin in terms of the burst pressure during normal operating conditions. Tubes degraded by up to 50% of the TW did not show burst. Burst pressure depended on the defect depths rather than on the wrap angles. The tube with a wrap angle of 0° showed a fish mouth fracture, whereas the tube with a 45° wrap angle showed a three way fracture.

  16. Large scale steam flow test: Pressure drop data and calculated pressure loss coefficients

    Energy Technology Data Exchange (ETDEWEB)

    Meadows, J.B.; Spears, J.R.; Feder, A.R.; Moore, B.P.; Young, C.E. [Bettis Atomic Power Lab., Pittsburgh, PA (United States)

    1993-12-01

    This report presents the result of large scale steam flow testing, 3 million to 7 million lbs/hr., conducted at approximate steam qualities of 25, 45, 70 and 100 percent (dry, saturated). It is concluded from the test data that reasonable estimates of piping component pressure loss coefficients for single phase flow in complex piping geometries can be calculated using available engineering literature. This includes the effects of nearby upstream and downstream components, compressibility, and internal obstructions, such as splitters, and ladder rungs on individual piping components. Despite expected uncertainties in the data resulting from the complexity of the piping geometry and two-phase flow, the test data support the conclusion that the predicted dry steam K-factors are accurate and provide useful insight into the effect of entrained liquid on the flow resistance. The K-factors calculated from the wet steam test data were compared to two-phase K-factors based on the Martinelli-Nelson pressure drop correlations. This comparison supports the concept of a two-phase multiplier for estimating the resistance of piping with liquid entrained into the flow. The test data in general appears to be reasonably consistent with the shape of a curve based on the Martinelli-Nelson correlation over the tested range of steam quality.

  17. INFLUENCE OF STEAM PRESSURE ON CHEMICAL CHANGES OF HEAT-TREATED MONGOLIAN PINE WOOD

    Directory of Open Access Journals (Sweden)

    Tao Ding

    2011-04-01

    Full Text Available Properties of heat-treated wood have been studied extensively in recent years. However, study on wood that has been treated in pressurized steam is limited, as most wood heat treatments are carried out in atmospheric steam. The main purpose of this study was to explore the influence of steam pressure on chemical changes of heat-treated wood. Wet chemical analysis, elemental analysis, and FTIR analysis were performed to investigate the changes of cell wall components of Mongolian pine wood. Samples treated in pressurized steam had lower percentages of polysaccharides and higher percentages of lignin compared to those treated in atmospheric steam, indicating greater chemical changes during the treatment. It was also found that thermal degradation of both samples was modest at the treatment temperature of 205 °C. These results help to explain the better dimensional stability and limited strength deterioration of wood treated in pressurized steam.

  18. Effects of press sizes on internal steam pressure during particleboard hot-pressing process

    Science.gov (United States)

    Zhiyong Cai; Michael Birkeland; James M. Wescott; Jane O' Dell; Jerrold E. Winandy

    2009-01-01

    Internal steam pressure produced during the hot-pressing cycle in particleboard production is critical to the newly developed bond strength that will determine the overall performance of particleboard. The difference between the accumulation of internal steam pressure for small panels made in the laboratory and that of large commercial-sized panels makes it difficult...

  19. Measurements of mixtures with carbon dioxide under supercritical conditions using commercial high pressure equipment

    Energy Technology Data Exchange (ETDEWEB)

    Andrade, Luciana L.P.R. de; Rutledge, Luis Augusto Medeiros; Moreno, Eesteban L.; Hovell, Ian; Rajagopal, Krishnaswamy [Universidade Federal do Rio de Janeiro (LATCA-EQ-UFRJ), RJ (Brazil). Escola de Quimica. Lab. de Termodinamica e Cinetica Aplicada

    2012-07-01

    There is a growing interest in studying physical properties of binary and multicomponent fluid mixtures with supercritical carbon dioxide (CO{sub 2}) over an extended range of temperature and pressure. The estimation of properties such as density, viscosity, saturation pressure, compressibility, solubility and surface tension of mixtures is important in design, operation and control as well as optimization of chemical processes especially in extractions, separations, catalytic and enzymatic reactions. The phase behaviour of binary and multicomponent mixtures with supercritical CO{sub 2} is also important in the production and refining of petroleum where mixtures of paraffin, naphthene and aromatics with supercritical fluids are often encountered. Petroleum fluids can present a complex phase behaviour in the presence of CO{sub 2}, where two-phase (VLE and LLE) and three phase regions (VLLE) might occur within ranges of supercritical conditions of temperature and pressure. The objective of this study is to develop an experimental methodology for measuring the phase behaviour of mixtures containing CO{sub 2} in supercritical regions, using commercial high-pressure equipment. (author)

  20. [Comparison of supercritical fluid extraction and steam distillation methods for the extraction of essential oils from Schizonepeta tenuifolia Briq].

    Science.gov (United States)

    Qiu, Qin; Ling, Jianya; Ding, Yuping; Chang, Hongwen; Wang, Jiang; Liu, Tingli

    2005-11-01

    Essential oil was extracted from Schizonepeta tenuifolia Briq. by supercritical fluid extraction (SFE) and steam distillation (SD). The components extracted were determined by gas chromatography with area normalization method and identified by gas chromatography-mass spectrometry (GC-MS). The optimal chromatographic conditions were: capillary column, SE-54 (30 m x 0.25 mm i.d., 0.25 microm); column temperature, 50 degrees C (3 min) --> (5 degrees c/min) 180 degrees C (2 min --> (10 degrees C/ min) 260 degrees C 50 min); split injection, split ratio 1: 50; injector temperature, 280 degrees C. Fifty-four components were identified for the essential oils extracted by SFE, and its main components were found to be pulegone, menthone, linoleic acid chloride etc. Thirty-nine components were identified for the essential oil obtained by SD, and its main components were found to be pulegone, menthone, limonene etc. The SFE method is better than the SD method in reliability stability and reproducibility, and is thus well suitable for similar applications involving for extraction of other traditional Chinese herbal medicines.

  1. Ex-vessel Steam Explosion Analysis for Pressurized Water Reactor and Boiling Water Reactor

    OpenAIRE

    Matjaž Leskovar; Mitja Uršič

    2016-01-01

    A steam explosion may occur during a severe accident, when the molten core comes into contact with water. The pressurized water reactor and boiling water reactor ex-vessel steam explosion study, which was carried out with the multicomponent three-dimensional Eulerian fuel–coolant interaction code under the conditions of the Organisation for Economic Co-operation and Development (OECD) Steam Explosion Resolution for Nuclear Applications project reactor exercise, is presented and discussed. In ...

  2. Stability analysis of closed-loop super-critical pressure systems

    Science.gov (United States)

    Smith, Walter Castro

    The current study investigates the mechanisms governing flow induced stability of super-critical pressure fluid systems. Super-critical pressure fluid systems have been investigated as a mechanism for heat extraction from power systems for over a century. There are numerous benefits to these systems, but also potential pitfalls which must be examined. While super-critical pressure systems do not undergo phase change, they may be subject to the same flow induced instabilities which affect and limit two-phase systems. The objective of the current study is to develop a modeling and analysis framework to evaluate and understand flow-induced instabilities in super-critical pressure systems. The developed framework is used to evaluate experimental systems which have been constructed and tested by other investigators. The developed model shows good comparison with both the steady state and transient results published by other researchers. The model has been used to predict instabilities in experimental systems, as well as to show how some systems are more susceptible to instability than others. Stability maps have been constructed in a similar manner to those published for single heated flow path analysis.

  3. Preliminary Study on the High Efficiency Supercritical Pressure Water-Cooled Reactor for Electricity Generation

    Energy Technology Data Exchange (ETDEWEB)

    Bae, Yoon Yeong; Park, Jong Kyun; Cho, Bong Hyun and others

    2006-01-15

    This research has been performed to introduce a concept of supercritical pressure water cooled reactor(SCWR) in Korea The area of research includes core conceptual design, evaluation of candidate fuel, fluid systems conceptual design with mechanical consideration, preparation of safety analysis code, and construction of supercritical pressure heat transfer test facility, SPHINX, and preliminary test. As a result of the research, a set of tools for the reactor core design has been developed and the conceptual core design with solid moderator was proposed. The direct thermodynamic cycle has been studied to find a optimum design. The safety analysis code has also been adapted to supercritical pressure condition. A supercritical pressure CO2 heat transfer test facility has been constructed and preliminary test proved the facility works as expected. The result of this project will be good basis for the participation in the international collaboration under GIF GEN-IV program and next 5-year mid and long term nuclear research program of MOST. The heat transfer test loop, SPHINX, completed as a result of this project may be used for the power cycle study as well as further heat transfer study for the various geometries.

  4. SELECTION OF RUSSIAN STEAM TURBINES FOR THE VIETNAMESE COMBINED GASSTEAM PLANT. THE INFLUENCE OF THE EFFICIENCY OF HIGH-PRESSURE CYLINDER OF STEAM TURBINE K-300-240-2 ON THE POWER OF A GAS-STEAM PLANT IN VIETNAM

    Directory of Open Access Journals (Sweden)

    Pham A. H.

    2015-06-01

    Full Text Available The article looks at the current state of energy in Vietnam and the selection of new Russian steam turbines for operation in combined gas-steam plant in Vietnam. The calculated results of thermal performance scheme 3x1 with combined gas-steam plant 1090 MW based on the Russian steam turbines K-330-240-2 and on the steam turbines TS2A40 Mitsubishi (station PhuMy-1, Vietnam. It also looks at the influence of the efficiency of high-pressure cylinders of Russian steam turbine K-330-240-2 on the efficiency and power of a gas-steam plant 3x1 with 1090 MW, increasing the efficiency of high-pressure cylinder of steam turbine through the use of honeycomb seals in flow part

  5. Nonlinear optics in Xe-filled hollow-core PCF in high pressure and supercritical regimes

    CERN Document Server

    Azhar, M; Travers, J C; Russell, P St J

    2013-01-01

    Supercritical Xe at 293 K offers a Kerr nonlinearity that can exceed that of fused silica while being free of Raman scattering. It also has a much higher optical damage threshold and a transparency window that extends from the UV to the infrared. We report the observation of nonlinear phenomena, such as self-phase modulation, in hollow-core photonic crystal fiber filled with supercritical Xe. In the subcritical regime, intermodal four-wave-mixing resulted in the generation of UV light in the HE12 mode. The normal dispersion of the fiber at high pressures means that spectral broadening can clearly obtained without influence from soliton effects or material damage.

  6. Influence of various aspects of low Reynolds number k-ε turbulence models on predicting in-tube buoyancy affected heat transfer to supercritical pressure fluids

    Energy Technology Data Exchange (ETDEWEB)

    Zhao, Chen-Ru; Zhang, Zhen [Institute of Nuclear and New Energy Technology of Tsinghua University, Advanced Nuclear Energy Technology Cooperation Innovation Centre, Key Laboratory of Advanced Nuclear Engineering and Safety, Ministry of Education, Beijing 100084 (China); Jiang, Pei-Xue, E-mail: jiangpx@tsinghua.edu.cn [Beijing Key Laboratory of CO_2 Utilization and Reduction Technology/Key Laboratory for Thermal Science and Power Engineering of Ministry of Education, Department of Thermal Engineering, Tsinghua University, Beijing 100084 (China); Bo, Han-Liang [Institute of Nuclear and New Energy Technology of Tsinghua University, Advanced Nuclear Energy Technology Cooperation Innovation Centre, Key Laboratory of Advanced Nuclear Engineering and Safety, Ministry of Education, Beijing 100084 (China)

    2017-03-15

    Highlights: • Understanding of the mechanism of buoyancy effect on supercritical heat transfer. • Turbulence related parameters in upward and downward flows were compared. • Turbulent Prandtl number affected the prediction insignificantly. • Buoyancy production was insignificant compared with shear production. • Damping function had the greatest effect and is a priority for further modification. - Abstract: Heat transfer to supercritical pressure fluids was modeled for normal and buoyancy affected conditions using several low Reynolds number k-ε models, including the Launder and Sharma, Myong and Kasagi, and Abe, Kondoh and Nagano, with the predictions compared with experimental data. All three turbulence models accurately predicted the cases without heat transfer deterioration, but failed to accurately predict the cases with heat transfer deterioration although the general trends were captured, indicating that further improvements and modifications are needed for the low Reynolds number k-ε turbulence models to better predict buoyancy deteriorated heat transfer. Further investigations studied the influence of various aspects of the low Reynolds number k-ε turbulence models, including the turbulent Prandtl number, the buoyancy production of turbulent kinetic energy, and the damping function to provide guidelines for model development to more precisely predict buoyancy affected heat transfer. The results show that the turbulent Prandtl number and the buoyancy production of turbulent kinetic energy have little influence on the predictions for cases in this study, while new damping functions with carefully selected control parameters are needed in the low Reynolds number k-ε turbulence models to correctly predict the buoyancy effect for heat transfer simulations in various applications such as supercritical pressure steam generators (SPSGs) in the high temperature gas cooled reactor (HTR) and the supercritical pressure water reactor (SCWR).

  7. Experimental investigation of heat transfer from a 2 × 2 rod bundle to supercritical pressure water

    Energy Technology Data Exchange (ETDEWEB)

    Wang, Han [State Key Laboratory of Multiphase Flow in Power Engineering, Xi’an Jiaotong University, Xi’an 710049 (China); Bi, Qincheng, E-mail: qcbi@mail.xjtu.edu.cn [State Key Laboratory of Multiphase Flow in Power Engineering, Xi’an Jiaotong University, Xi’an 710049 (China); Wang, Linchuan; Lv, Haicai [State Key Laboratory of Multiphase Flow in Power Engineering, Xi’an Jiaotong University, Xi’an 710049 (China); Leung, Laurence K.H. [Atomic Energy of Canada Limited, Chalk River, Ont., Canada K0J 1J0 (Canada)

    2014-08-15

    Highlights: • Heat transfer of supercritical water through a 2 × 2 rod bundles is investigated. • Circumferential wall temperature distribution is obtained. • Effects of system parameters on heat transfer characteristics are analyzed. • Heat transfer correlations are compared against the rod bundle test data. - Abstract: Heat transfer experiments with supercritical pressure water flowing vertically upward through a 2 × 2 rod bundle have been performed at Xi’an Jiaotong University. A fuel-assembly simulator with four heated rods was installed inside a square channel with rounded corner. The outer diameter of each heated rod is 8 mm with an effective heated length of 600 mm. The experiments covered the pressure range of 23–28 MPa, mass-flux range of 350–1000 kg/(m{sup 2} s) and heat-flux range on the rod surface of 200–1000 kW/m{sup 2}. Heat transfer characteristics of supercritical pressure water through the bundle were examined with respect to variations of heat flux, system pressure, and mass flux. These characteristics were shown to be similar to those previously observed in tubes or annuli. The experimental data indicate a non-uniform circumferential wall-temperature distribution around the heated rod. A maximum wall temperature was observed at the surface facing the corner gap between the heated rod and the ceramic tube, while the minimum wall temperature was observed at the surface facing the center subchannel. The difference between maximum and minimum wall temperatures varies with heat flux and/or mass flux. Eight heat transfer correlations developed for supercritical water were assessed against the current set of test data. Prediction of the Jackson correlation agrees closely with the experimental Nusselt number. A new correlation has been derived based on Jackson correlation to improve the prediction accuracy of supercritical heat transfer coefficient in a 2 × 2 rod bundle.

  8. [Analyze on chemical compositions of Dalbergia odorifera essential oils extracted by CO2-supercritical-fluid-extraction and steam distillation extraction].

    Science.gov (United States)

    Song, Wei-Feng; Liao, Mei-Jin; Luo, Shu-Yuan

    2011-11-01

    To analyze the chemical compositions of Dalbergia odorifera essential oils extacted by CO2-supercritical-fluid-extraction (SFE-CO2) and steam distillation extraction (SD). The essential oils of Dalbergia odorifera were extracted by steam distillation extraction and SFE-CO2. The chemical components were separated and analyzed by gas chromatography-mass spectrometry. 12 compounds were identified in SFE sample. The major components from essential oils were 2-propenoic acid-3(4-methoxyphenyl)-ethyl ester (14.53%), nerolidol (14.95%), ageratochromene (1.33%). 9 compounds were identified in SD sample. The major components from essential oils were nerolidol (26.61%), cedrol (1.65%). The SFE method is better than the SD method in reliability stability and reproducibility, and suitable for essential oils extraction of Dalbergia odorifera.

  9. Three-dimensional numerical study of supercritical pressure effect on heat transfer of cryogenic methane%Three-dimensional numerical study of supercritical pressure effect on heat transfer of cryogenic methane

    Institute of Scientific and Technical Information of China (English)

    RUAN Bo; MENG Hua

    2011-01-01

    A three-dimensional numerical study of the turbulent convective heat transfer of the cryogenic methane flowing inside a square engine cooling channel under supercritical pressures was systematically conducted.Numerical results indicate that increasing the fluid pressure results in enhanced heat transfer of the cryogenic methane under supercritical pressures.At the pseudo-critical temperature under a corresponding supercritical pressure,drastic property variations cause heat transfer deterioration and sharp wall temperature increase at a high wall heat flux of 7MW/m2.A modified Jackson and Hall heat transfer equation,which can be used for supercritical heat transfer calculations of the cryogenic methane,has been successfully established in this paper.

  10. Effect of pressure of supercritical carbon dioxide on morphology of wool fibers during dyeing process

    Directory of Open Access Journals (Sweden)

    Zheng Lai-Jiu

    2015-01-01

    Full Text Available In this paper, the effect of pressure release rate on dyeing of wool fibers was studied in the supercritical carbon dioxide dyeing. Surface morphology, chemical composition and color difference at different pressure release rates were investigated by employing scanning electron microscope, color matching, and measuring instrument. Experiment data reveal that wool fibers are easy to be damaged with increasing pressure release rate. Fiber’s surface brightness varies also with the pressure release rate. The phenomena are theoretically explained using Bernoulli's principle.

  11. THERMODYNAMICAL ANALYSIS OF HIGH-PRESSURE FEED WATER HEATER IN STEAM PROPULSION SYSTEM DURING EXPLOITATION

    Directory of Open Access Journals (Sweden)

    Igor Poljak

    2017-01-01

    Full Text Available Nowadays diesel engines prevail as ship propulsion. However, steam propulsion is still primary drive for LNG carriers. In the presented paper high-pressure feed water heater was analyzed, as one of the essential components in LNG carrier steam propulsion system. Measurements of all operating parameters (fluid streams at the analyzed heat exchanger inlets and outlets were performed. Change of the operating parameters was measured at different steam system loads, not at full load as usual. Through these measurements was enabled the insight into the behaviour of the heat exchanger operating parameters during the whole exploitation. The numerical analysis was performed, based on the measured data. The changes in energy and exergy efficiency of the heat exchanger were analyzed. Energetic and exergetic power inputs and outputs were also calculated, which enabled an insight into the change of energetic and exergetic power losses of the heat exchanger at different steam system loads. Change in energetic and exergetic power losses and operating parameters, which have the strongest influence on the high-pressure feed water heater losses, were described. Analyzed heat exchanger was compared with similar heat exchangers in the base loaded conventional steam power plants. From the conducted analysis, it is concluded that the adjustment and control modes of these high-pressure heat exchangers are equal, regardless of whether they were mounted in the base loaded conventional steam power plants or marine steam systems, while their operating parameters and behaviour patterns differ greatly.

  12. Chemical compositions and antioxidant properties of essential oils from nine species of Turkish plants obtained by supercritical carbon dioxide extraction and steam distillation.

    Science.gov (United States)

    Topal, Ummihan; Sasaki, Mitsuru; Goto, Motonobu; Otles, Semih

    2008-01-01

    Chemical compositions and antioxidant activities of essential oils from nine different species of Turkish plants, namely Melissa officinalis L., Rosmarinus officinalis L., Cuminum cyminum L., Piper nigrum L., Lavandula stoechas spp., Foeniculum vulgare, Pimpinella anisum L., Thymus serpyllum and Liquidamber orientalis Mill., were studied. Essential oils were obtained by supercritical carbon dioxide (SCCO2) extraction and steam distillation, and were analyzed by gas chromatography-mass spectrometry. The antioxidant activities of SCCO2 extraction and steam distillation extracts were tested by means of the 1,1-diphenyl-2-picrylhydrazyl (DPPH) assay. Essential oils extracted by SCCO2 and steam distillation showed different compositions in different species. In the DPPH assay, R. officinalis, C. cyminum, P. anisum, T. serpyllum and L. orientalis essential oils obtained by SCCO2 extraction showed higher antioxidant activity than steam distillation extracts, with radical scavenging activities ranging from 87.1 +/- 0.23% to 92.0 +/- 0.34% compared with the butylated hydroxytoluene positive control (91.4 +/- 0.21%).

  13. Enrichment of vanillin in barley malt by hydrolysis in high temperature and high pressure steam.

    Science.gov (United States)

    Nakahara, Koichi; Kageyama, Norihiko; Nagami, Kenzo

    2012-12-19

    Malted barley was treated with saturated steam at temperatures ranging from 180 to 220 °C, that is, high temperature and high pressure steam (HHS), and a control sample exposed to saturated liquid water in the same temperature range. The malt treated in steam was extracted with water (70 °C) for 15 min after drying. Vanillin which gave beer preferable flavor was detected in all malt extracts, both after treatment with steam and in effluent from malt exposed to liquid water. Hydrolysis of ingredients in the malt occurred even in steam. The treatment of natural products in HHS could be a new thermal technique to provide a special ingredient for food industry, for example, malt for beer.

  14. Worldwide assessment of steam-generator problems in pressurized-water-reactor nuclear power plants

    Energy Technology Data Exchange (ETDEWEB)

    Woo, H.H.; Lu, S.C.

    1981-09-15

    Objective is to assess the reliability of steam generators of pressurized water reactor (PWR) power plants in the United States and abroad. The assessment is based on operation experience of both domestic and foreign PWR plants. The approach taken is to collect and review papers and reports available from the literature as well as information obtained by contacting research institutes both here and abroad. This report presents the results of the assessment. It contains a general background of PWR plant operations, plant types, and materials used in PWR plants. A review of the worldwide distribution of PWR plants is also given. The report describes in detail the degradation problems discovered in PWR steam generators: their causes, their impacts on the performance of steam generators, and the actions to mitigate and avoid them. One chapter is devoted to operating experience of PWR steam generators in foreign countries. Another discusses the improvements in future steam generator design.

  15. Experimental study on the minimum drag coefficient of supercritical pressure water in horizontal tubes

    Energy Technology Data Exchange (ETDEWEB)

    Lei, Xianliang, E-mail: xianlianglei@mail.xjtu.edu.cn; Li, Huixiong; Guo, YuMeng; Zhang, Qing; Zhang, Weiqiang; Zhang, Qian

    2016-05-15

    Highlights: • The minimum drag coefficient phenomenon (MDC) has been observed and further investigated. • Effects of heat flux, mass flux and pressure to MDC have been discussed. • A series of comparisons between existing correlations and data have been conducted. • Two correlations of drag coefficient are proposed for isothermal and nonisothermal flow. - Abstract: Hydraulic resistance and its components are of great importance for understanding the turbulence nature of supercritical fluid and establishing prediction methods. Under supercritical pressures, the hydraulic resistance of the fluid exhibits a “pit” in the regions near its pseudo-critical point, which is hereafter called the minimum drag coefficient phenomenon. However, this special phenomenon was paid a little attention before. Hence systematical experiments have been carried out to investigate the hydraulic resistance of supercritical pressure water in both adiabatic and heated horizontal tubes. Parametric effects of heat flux, pressure and mass fluxes to drag coefficient are further compared. It is found that almost all of the existing correlations don’t agree well with the experimental data due to the insufficient consideration of thermal-properties near the pseudocritical point. Two correlations of the drag coefficients are finally proposed by introducing the new variable of the derivative of density with respect to temperature or Prandtl number, which can better predict the drag coefficient of isothermal and nonisothermal flow respectively.

  16. Three years of experience with polyamines in the high pressure steam system of a naphtha cracker

    Energy Technology Data Exchange (ETDEWEB)

    Lier, Roy van; Janssen, Gerard [SABIC Europe BV, Geleen (Netherlands). Site Improvement, Competence Center Manufacturing; Savelkoul, Jo

    2008-12-15

    The design and operation of the high pressure steam system of a naphtha cracker pose specific problems which in some cases cannot be satisfactorily resolved with conventional water/steam treatment programs. Following a decade of operational experience with polyamine products at lower pressures at the Geleen (petro)chemical site in the Netherlands, the ammonia/morpholine treatment of the 12.5 MPa steam system of one of SABIC Europe's naphtha crackers was converted to a polyamine program in November 2005. In this paper, the characteristics of the cracker's steam system are first described. Particular aspects of the conversion are then discussed. Finally, the experience gained and insights obtained into the polyamine treatment during the first three years are elaborated. (orig.)

  17. Influence of pressure and time on extraction process using supercritical CO2

    Directory of Open Access Journals (Sweden)

    Mićić V.

    2008-01-01

    Full Text Available The supercritical fluid extraction (SFE by carbon dioxide (CO2 of Salvia officinalis L. was investigated. SFE by CO2 was performed at different pressure (80, 100, 150, 200 and 300 bar and constant temperature of 40ºC (all other extraction conditions, such are flow rate, particle diameter of Salvia officinalis, extraction time were kept constant. The GC-MS method was used for determination of qualitative and quantitative composition of obtained extracts and essential oils.

  18. An experimental study of constant-pressure steam injection and transient condensing flow in an air-saturated porous medium

    NARCIS (Netherlands)

    Brouwers, H.J.H.

    1996-01-01

    In this paper the unsteady process of constant pressure steam injection into an air–saturated porous medium is studied experimentally. To this end, vertical glass tubes are packed with dry quartz sand and injected with dry steam. The propagation of the steam front appears to be proportional to t. It

  19. Dynamical analysis of high-pressure supercritical carbon dioxide jet in well drilling

    Institute of Scientific and Technical Information of China (English)

    DU Yu-kun; WANG Rui-he; NI Hong-jian; HUANG Zhi-yuan; LI Mu-kun

    2013-01-01

    This paper presents the design of an experimental setup and mathematical and physical models to determine the dynamical characteristics of the high-pressure supercritical carbon dioxide (SC-CO2) jet with a highly potential applications in the well drilling.The effects of three major factors on the wellbore dynamical characteristics of the high-pressure SC-CO2 jet,i.e.,the nozzle diameter,the standoff distance and the jet pressure are determined.It is indicated that the pressure of CO2 reduces severely in the SC-CO2 jet impact process.It is also found that the bottom-hole pressure and the temperature increase as the nozzle diameter increases but decrease with the increase of the standoff distance.The higher the jet pressure at the wellbore inlet is,the higher the pressure and the lower the temperature at the bottom-hole will be.

  20. Recovery of Minerals in Martian Soils Via Supercritical Fluid Extraction

    Science.gov (United States)

    Debelak, Kenneth A.; Roth, John A.

    2001-03-01

    We are investigating the use of supercritical fluids to extract mineral and/or carbonaceous material from Martian surface soils and its igneous crust. Two candidate supercritical fluids are carbon dioxide and water. The Martian atmosphere is composed mostly of carbon dioxide (approx. 95.3%) and could therefore provide an in-situ source of carbon dioxide. Water, although present in the Martian atmosphere at only approx. 0.03%, is also a candidate supercritical solvent. Previous work done with supercritical fluids has focused primarily on their solvating properties with organic compounds. Interestingly, the first work reported by Hannay and Hogarth at a meeting of the Royal Society of London in 1879 observed that increasing or decreasing the pressure caused several inorganic salts e.g., cobalt chloride, potassium iodide, and potassium bromide, to dissolve or precipitate in supercritical ethanol. In high-pressure boilers, silica, present in most boiler feed waters, is dissolved in supercritical steam and transported as dissolved silica to the turbine blades. As the pressure is reduced the silica precipitates onto the turbine blades eventually requiring the shutdown of the generator. In supercritical water oxidation processes for waste treatment, dissolved salts present a similar problem. The solubility of silicon dioxide (SiO2) in supercritical water is shown. The solubility curve has a shape characteristic of supercritical systems. At a high pressure (greater than 1750 atmospheres) increasing the temperature results in an increase in solubility of silica, while at low pressures, less than 400 atm., the solubility decreases as temperature increases. There are only a few studies in the literature where supercritical fluids are used in extractive metallurgy. Bolt modified the Mond process in which supercritical carbon monoxide was used to produce nickel carbonyl (Ni(CO)4). Tolley and Tester studied the solubility of titanium tetrachloride (TiCl4) in supercritical CO2

  1. Effect of Low Pressure End Conditions on Steam Power Plant Performance

    Directory of Open Access Journals (Sweden)

    Ali Syed Haider

    2014-07-01

    Full Text Available Most of the electricity produced throughout the world today is from steam power plants and improving the performance of power plants is crucial to minimize the greenhouse gas emissions and fuel consumption. Energy efficiency of a thermal power plant strongly depends on its boiler-condenser operating conditions. The low pressure end conditions of a condenser have influence on the power output, steam consumption and efficiency of a plant. Hence, the objective this paper is to study the effect of the low pressure end conditions on a steam power plant performance. For the study each component was modelled thermodynamically. Simulation was done and the results showed that performance of the condenser is highly a function of its pressure which in turn depends on the flow rate and temperature of the cooling water. Furthermore, when the condenser pressure increases both net power output and plant efficiency decrease whereas the steam consumption increases. The results can be used to run a steam power cycle at optimum conditions.

  2. Determination of Minimum Miscibility Pressure in supercritical extractor using oil saturated sample

    DEFF Research Database (Denmark)

    Rudyk, Svetlana Nikolayevna; Søgaard, Erik Gydesen; Abbasi, Waqas A.

    2009-01-01

    , in order to investigate the MMP, we suggest another method by using a supercritical extractor. Spe-ed SFE equipment with oil saturated natural rock samples were used for the purpose. The clean chalk samples were saturated with oil from the Dan field under vacuum. The CO2 gas was injected into the extractor...... vessel containing the sample at different increasing pressure levels. The oil displaced in such a way was collected and measured. The volume of extracted oil was plotted against the increasing pressure. The form of the graph is similar to that typically obtained from a slim tube experiment.  Following...

  3. Experimental study on steam-water two-phase flow frictional pressure drops in helical coils

    Institute of Scientific and Technical Information of China (English)

    1997-01-01

    Experiments of steam-water two-phase flow frictional pressure drop in a vertical helical coil were carried out in the high-pressure water test loop of Xi'an jiaotong University,The coil is made of stainless steel tube with an inner diameter of 16mm,the helix diameter measured from tube axis to tube axis is 1.3m,and helix angle of the coil is 3.65°,The experimental conditions are:pressurep=4-18MPa,mass velocity G=400-1400kg/(m2.s),inner wall heat flux q=100-700kW/m2,Based on these data,a correlation for predicting the steam-water two-phase flow frictional pressure drop was derived,it can be used for the design of steam generator of HTGR.

  4. A high-pressure atomic force microscope for imaging in supercritical carbon dioxide

    Energy Technology Data Exchange (ETDEWEB)

    Lea, A. S.; Higgins, S. R.; Knauss, K. G.; Rosso, K. M.

    2011-01-01

    A high-pressure atomic force microscope(AFM) that enables in situ, atomic scale measurements of topography of solid surfaces in contact with supercritical CO2 (scCO2) fluids has been developed. This apparatus overcomes the pressure limitations of the hydrothermal AFM and is designed to handle pressures up to 100 atm at temperatures up to ~350 K. A standard optically-based cantilever deflection detection system was chosen. When imaging in compressible supercritical fluids such as scCO2, precise control of pressure and temperature in the fluid cell is the primary technical challenge. Noise levels and imaging resolution depend on minimization of fluid density fluctuations that change the fluidrefractive index and hence the laser path. We demonstrate with our apparatus in situ atomic scale imaging of a calcite (CaCO3) mineral surface in scCO2; both single, monatomic steps and dynamic processes occurring on the (101¯4) surface are presented. Finally, this new AFM provides unprecedented in situ access to interfacial phenomena at solid–fluid interfaces under pressure.

  5. [Comparison of Chemical Components of Essential Oil from Ocimum basilicum var. pilosum Extracted by Supercritical CO2 Fluid and Steam Distillation].

    Science.gov (United States)

    Wang, Zhao-yu; Zheng, Jia-huan; Shi, Sheng-ying; Luo, Zhi-xiong; Ni, Shun-yu; Lin, Jing-ming

    2015-11-01

    To compare the chemical components of essential oil prepared by steam distillation extraction (SD) and supercritical CO2 fluid extraction (SFE-CO2) from Ocimum basilicum var. pilosum whole plant. The essential oil of Ocimum basilicum var. pilosum were extracted by SD and SFE-CO2. The chemical components of essential oil were separated and analyzed by gas chromatography-mass spectrometry( GC-MS). Their relative contents were determined by normalization of peak area. 40 and 42 compounds were detected in the essential oil prepared by SD and SFE-CO2 respectively. 25 compounds were common. Thereare significant differences of the chemical components between the Ocimum basilicum var. pilosum essential oil prepared by SD and thatby SFE-CO2. Different methods showed different extraction efficiency with a special compound. It might be a good idea to unite several methods in the modern traditional Chinese medicine industry.

  6. Study on Water Hammer Suppression of Pipeline in Opening Process of Ultra-supercritical Steam Trap%超(超)临界疏水阀开启过程管道水锤抑制研究

    Institute of Scientific and Technical Information of China (English)

    李树勋; 娄燕鹏; 徐晓刚; 丁强伟

    2016-01-01

    针对超(超)临界疏水阀开启过程中管道水锤振动问题,采用特征线法对阀控管道水锤瞬变模型进行了数值计算,运用 Matlab 求解得到了疏水阀在不同流量特性、不同节流效应下开启时管道中流量和水锤压头的时域曲线。研究表明:选用等百分比流量特性的疏水阀,可以减缓阀开启时阀后管道的水锤现象,同时节流效应对疏水阀开启时阀后管道水锤的影响显著,节流越明显,管道中水锤压头幅值越小,水锤波动趋势也越缓和。研究结果为抑制管路水锤与冲击设计提供理论参考。%Aiming at severe vibration phenomenon of pipe behind the ultra-supercritical steam trap during the valve-opening process,the transient model on water hammer in the pipe was calculated by method of characteristics (MOC).Based on Matlab software,the time domain curves of flow and water hammer pressure head on fluid was obtained in different flow characteristic and different throttling effect for valve.The analyses show that adopting equal percentage flow characteristic about the valve could alle-viate water hammer in the pipe.Moreover,the influences of throttling effect for steam trap on water hammer are obvious,and the more obvious the throttling effect for steam trap,the more relieving water hammer wave and the smaller water hammer pressure head peak.The results provide theoretical references for design of steam trap in preventing water hammer and anti-shock analysis of the fluid on pipeline.

  7. Thermal calculation and experimental studies on flue gas and steam temperature deviation of supercritical boiler%超临界锅炉烟温与汽温偏差热力计算与试验研究

    Institute of Scientific and Technical Information of China (English)

    2015-01-01

    针对大型电站超临界锅炉烟温与汽温偏差问题,结合国内首台600 MW超临界W型锅炉,重点研究不同负荷下汽水分离器出口汽温偏差,以及尾部受热面汽温偏差变化规律,并从优化汽温偏差出发,首次提出汽水分离器出口管道交叉布置结构,从而改变汽水流动方向,并结合锅炉热力计算,验证交叉布置结构减少汽温偏差的效果:当采用汽水分离器出口交叉布置结构后,屏式过热器入口左、右侧汽温偏差减小到原汽温偏差的1/2左右。%To solve the problems of flue gas and steam temperature deviation of supercritical boiler, the temperature deviation of the steam separator and the following heating surface are investigated in the domestic first 600 MW supercritical W-shaped flame boiler. Moreover, a special outlet cross layout structure of steam separator is designed and the role of the special outlet cross structure is investigated by thermal calculation. The results indicate that the steam temperature deviation of supercritical boiler is increased with the the flue gas temperature deviation and the growth of the following heating surface during actual operation. Meanwhile, the special outlet cross layout structure of steam separator has a remarkable effect on decreasing the steam temperature deviation, which has been reduced to half of the original level. Therefore, the special outlet cross layout structure of supercritical boiler steam separator is worthwhile to distinctly decrease the steam temperature deviation and increase the safe in operation of supercritical boil.

  8. Experimental study of critical flow of water at supercritical pressure

    Institute of Scientific and Technical Information of China (English)

    Yuzhou CHEN; Chunsheng YANG; Shuming ZHANG; Minfu ZHAO; Kaiwen DU; Xu CHENG

    2009-01-01

    Experimental studies of the critical flow of water were conducted under steady-state conditions with a nozzle 1.41mm in diameter and 4.35 mm in length, covering the inlet pressure range of 22.1-26.8 MPa and inlet temperature range of 38^74°C. The parametric trend of the flow rate was investigated, and the experimental data were compared with the predictions of the homogeneous equilibrium model, the Bernoulli correlation, and the models used in the reactor safety analysis code RELAP5/ MOD3.3. It is concluded that in the near or beyond pseudo-critical region, thermal-dynamic equilibrium is dominant, and at a lower temperature, choking does not occur. The onset of the choking condition is not predicted reasonably by the RELAP5 code.

  9. Supercritical boiler material selection using fuzzy analytic network process

    Directory of Open Access Journals (Sweden)

    Saikat Ranjan Maity

    2012-08-01

    Full Text Available The recent development of world is being adversely affected by the scarcity of power and energy. To survive in the next generation, it is thus necessary to explore the non-conventional energy sources and efficiently consume the available sources. For efficient exploitation of the existing energy sources, a great scope lies in the use of Rankin cycle-based thermal power plants. Today, the gross efficiency of Rankin cycle-based thermal power plants is less than 28% which has been increased up to 40% with reheating and regenerative cycles. But, it can be further improved up to 47% by using supercritical power plant technology. Supercritical power plants use supercritical boilers which are able to withstand a very high temperature (650-720˚C and pressure (22.1 MPa while producing superheated steam. The thermal efficiency of a supercritical boiler greatly depends on the material of its different components. The supercritical boiler material should possess high creep rupture strength, high thermal conductivity, low thermal expansion, high specific heat and very high temperature withstandability. This paper considers a list of seven supercritical boiler materials whose performance is evaluated based on seven pivotal criteria. Given the intricacy and difficulty of this supercritical boiler material selection problem having interactions and interdependencies between different criteria, this paper applies fuzzy analytic network process to select the most appropriate material for a supercritical boiler. Rene 41 is the best supercritical boiler material, whereas, Haynes 230 is the worst preferred choice.

  10. Ex-vessel Steam Explosion Analysis for Pressurized Water Reactor and Boiling Water Reactor

    Directory of Open Access Journals (Sweden)

    Matjaž Leskovar

    2016-02-01

    Full Text Available A steam explosion may occur during a severe accident, when the molten core comes into contact with water. The pressurized water reactor and boiling water reactor ex-vessel steam explosion study, which was carried out with the multicomponent three-dimensional Eulerian fuel–coolant interaction code under the conditions of the Organisation for Economic Co-operation and Development (OECD Steam Explosion Resolution for Nuclear Applications project reactor exercise, is presented and discussed. In reactor calculations, the largest uncertainties in the prediction of the steam explosion strength are expected to be caused by the large uncertainties related to the jet breakup. To obtain some insight into these uncertainties, premixing simulations were performed with both available jet breakup models, i.e., the global and the local models. The simulations revealed that weaker explosions are predicted by the local model, compared to the global model, due to the predicted smaller melt droplet size, resulting in increased melt solidification and increased void buildup, both reducing the explosion strength. Despite the lower active melt mass predicted for the pressurized water reactor case, pressure loads at the cavity walls are typically higher than that for the boiling water reactor case. This is because of the significantly larger boiling water reactor cavity, where the explosion pressure wave originating from the premixture in the center of the cavity has already been significantly weakened on reaching the distant cavity wall.

  11. Steam Pressure-Reducing Station Safety and Energy Efficiency Improvement Project

    Energy Technology Data Exchange (ETDEWEB)

    Lower, Mark D [ORNL; Christopher, Timothy W [ORNL; Oland, C Barry [ORNL

    2011-06-01

    The Facilities and Operations (F&O) Directorate is sponsoring a continuous process improvement (CPI) program. Its purpose is to stimulate, promote, and sustain a culture of improvement throughout all levels of the organization. The CPI program ensures that a scientific and repeatable process exists for improving the delivery of F&O products and services in support of Oak Ridge National Laboratory (ORNL) Management Systems. Strategic objectives of the CPI program include achieving excellence in laboratory operations in the areas of safety, health, and the environment. Identifying and promoting opportunities for achieving the following critical outcomes are important business goals of the CPI program: improved safety performance; process focused on consumer needs; modern and secure campus; flexibility to respond to changing laboratory needs; bench strength for the future; and elimination of legacy issues. The Steam Pressure-Reducing Station (SPRS) Safety and Energy Efficiency Improvement Project, which is under the CPI program, focuses on maintaining and upgrading SPRSs that are part of the ORNL steam distribution network. This steam pipe network transports steam produced at the ORNL steam plant to many buildings in the main campus site. The SPRS Safety and Energy Efficiency Improvement Project promotes excellence in laboratory operations by (1) improving personnel safety, (2) decreasing fuel consumption through improved steam system energy efficiency, and (3) achieving compliance with applicable worker health and safety requirements. The SPRS Safety and Energy Efficiency Improvement Project being performed by F&O is helping ORNL improve both energy efficiency and worker safety by modifying, maintaining, and repairing SPRSs. Since work began in 2006, numerous energy-wasting steam leaks have been eliminated, heat losses from uninsulated steam pipe surfaces have been reduced, and deficient pressure retaining components have been replaced. These improvements helped ORNL

  12. High-pressure Phase Equilibria for Binary Ethanol System Containing Supercritical CO2

    Institute of Scientific and Technical Information of China (English)

    2001-01-01

    High-pressure phase behavior of supercritical (SC) CO2+ethanol system was investigated at 333.2 K, 348.2 K, 353.2 K, 368.2 K, 413.2 K and 453.2 K and pressure from 2.0 MPa to 14.3 MPa. The measurement was carried out in a cylindrical autoclave with a moveable piston and a window for adjustment and observation of phase equilibria at given T and p. The samples were taken from two coexisting phases and were analyzed to obtain their compositions. It is shown that the solubility of SC CO2 in ethanol increases drastically with pressures at the given temperature, but the content of ethanol in CO2-rich phase increase faintly.

  13. Steam reforming of tars at low temperature and elevated pressure for model tar component naphthalene

    OpenAIRE

    Speidel, Michael; Fischer, Holger

    2016-01-01

    A process of pressurized gasification and power generation in a hybrid system of Solid Oxide Fuel Cell (SOFC) and gas turbine enables an efficient use of biomass. This process requires tar reforming in order to protect the SOFC from plugging. Tars must be converted at 5 bar absolute pressure (bara) while avoiding secondary steam reforming of methane in order to reduce the required heat input for the tar reformer. This can be realized at low reforming temperatures (

  14. Transient-pressure analysis in geothermal steam reservoirs with an immobile vaporizing liquid phase

    Science.gov (United States)

    Moench, A.F.; Atkinson, P.G.

    1978-01-01

    A finite-difference model for the radial horizontal flow of steam through a porous medium is used to evaluate transient-pressure behavior in the presence of an immobile vaporizing or condensing liquid phase. Graphs of pressure drawdown and buildup in terms of dimensionless pressure and time are obtained for a well discharging steam at a constant mass flow rate for a specified time. The assumptions are made that the steam is in local thermal equilibrium with the reservoir rocks, that temperature changes are due only to phase change, and that effects of vapor-pressure lowering are negligible. Computations show that when a vaporizing liquid phase is present the pressure drawdown exhibits behavior similar to that observed in noncondensable gas reservoirs, but delayed in time. A theoretical analysis allows for the computation of this delay and demonstrates that it is independent of flow geometry. The response that occurs upon pressure buildup is markedly different from that in a noncondensable gas system. This result may provide a diagnostic tool for establishing the existence of phase-change phenomena within a reservoir. ?? 1979.

  15. Practical development of continuous supercritical fluid process using high pressure and high temperature micromixer

    Science.gov (United States)

    Kawasaki, Shin-Ichiro; Sue, Kiwamu; Ookawara, Ryuto; Wakashima, Yuichiro; Suzuki, Akira

    2015-12-01

    In the synthesis of metal oxide fine particles by continuous supercritical hydrothermal method, the particle characteristics are greatly affected by not only the reaction conditions (temperature, pressure, residence time, concentration, etc.), but also the heating rate from ambient to reaction temperature. Therefore, the heating method by direct mixing of starting solution at room temperature with supercritical water is a key technology for the particle production having smaller size and narrow distribution. In this paper, mixing engineering study through comparison between conventional T-shaped mixers and recently developed swirl mixers was carried out in the hydrothermal synthesis of NiO nanoparticles from Ni(NO3)2 aqueous solution at 400 °C and 30 MPa. Inner diameter in the mixers and total flow rates were varied. Furthermore, the heating rate was calculated by computational fluid dynamics (CFD) simulation. Relationship between the heating rate and the average particle size were discussed. It was clarified that the miniaturization of mixer inner diameter and the use of the swirl flow were effective for improving mixing performance and contributed to produce small and narrow distribution particle under same experimental condition of flow rate, temperature, pressure, residence time, and concentration of the starting materials. We have focused the mixer optimization due to a difference in fluid viscosity.

  16. Effect of turbulence models on predicting convective heat transfer to hydrocarbon fuel at supercritical pressure

    Institute of Scientific and Technical Information of China (English)

    Tao Zhi; Cheng Zeyuan; Zhu Jianqin; Li Haiwang

    2016-01-01

    A variety of turbulence models were used to perform numerical simulations of heat transfer for hydrocarbon fuel flowing upward and downward through uniformly heated vertical pipes at supercritical pressure. Inlet temperatures varied from 373 K to 663 K, with heat flux rang-ing from 300 kW/m2 to 550 kW/m2. Comparative analyses between predicted and experimental results were used to evaluate the ability of turbulence models to respond to variable thermophys-ical properties of hydrocarbon fuel at supercritical pressure. It was found that the prediction per-formance of turbulence models is mainly determined by the damping function, which enables them to respond differently to local flow conditions. Although prediction accuracy for experimental results varied from condition to condition, the shear stress transport (SST) and launder and sharma models performed better than all other models used in the study. For very small buoyancy-influenced runs, the thermal-induced acceleration due to variations in density lead to the impairment of heat transfer occurring in the vicinity of pseudo-critical points, and heat transfer was enhanced at higher temperatures through the combined action of four thermophysical properties: density, viscosity, thermal conductivity and specific heat. For very large buoyancy-influenced runs, the thermal-induced acceleration effect was over predicted by the LS and AB models.

  17. Effect of turbulence models on predicting convective heat transfer to hydrocarbon fuel at supercritical pressure

    Directory of Open Access Journals (Sweden)

    Tao Zhi

    2016-10-01

    Full Text Available A variety of turbulence models were used to perform numerical simulations of heat transfer for hydrocarbon fuel flowing upward and downward through uniformly heated vertical pipes at supercritical pressure. Inlet temperatures varied from 373 K to 663 K, with heat flux ranging from 300 kW/m2 to 550 kW/m2. Comparative analyses between predicted and experimental results were used to evaluate the ability of turbulence models to respond to variable thermophysical properties of hydrocarbon fuel at supercritical pressure. It was found that the prediction performance of turbulence models is mainly determined by the damping function, which enables them to respond differently to local flow conditions. Although prediction accuracy for experimental results varied from condition to condition, the shear stress transport (SST and launder and sharma models performed better than all other models used in the study. For very small buoyancy-influenced runs, the thermal-induced acceleration due to variations in density lead to the impairment of heat transfer occurring in the vicinity of pseudo-critical points, and heat transfer was enhanced at higher temperatures through the combined action of four thermophysical properties: density, viscosity, thermal conductivity and specific heat. For very large buoyancy-influenced runs, the thermal-induced acceleration effect was over predicted by the LS and AB models.

  18. Recent Experimental Efforts on High-Pressure Supercritical Injection for Liquid Rockets and Their Implications

    Directory of Open Access Journals (Sweden)

    Bruce Chehroudi

    2012-01-01

    Full Text Available Pressure and temperature of the liquid rocket thrust chambers into which propellants are injected have been in an ascending trajectory to gain higher specific impulse. It is quite possible then that the thermodynamic condition into which liquid propellants are injected reaches or surpasses the critical point of one or more of the injected fluids. For example, in cryogenic hydrogen/oxygen liquid rocket engines, such as Space Shuttle Main Engine (SSME or Vulcain (Ariane 5, the injected liquid oxygen finds itself in a supercritical condition. Very little detailed information was available on the behavior of liquid jets under such a harsh environment nearly two decades ago. The author had the opportunity to be intimately involved in the evolutionary understanding of injection processes at the Air Force Research Laboratory (AFRL, spanning sub- to supercritical conditions during this period. The information included here attempts to present a coherent summary of experimental achievements pertinent to liquid rockets, focusing only on the injection of nonreacting cryogenic liquids into a high-pressure environment surpassing the critical point of at least one of the propellants. Moreover, some implications of the results acquired under such an environment are offered in the context of the liquid rocket combustion instability problem.

  19. Experimental unsteady pressures at flutter on the Supercritical Wing Benchmark Model

    Science.gov (United States)

    Dansberry, Bryan E.; Durham, Michael H.; Bennett, Robert M.; Rivera, Jose A.; Silva, Walter A.; Wieseman, Carol D.; Turnock, David L.

    1993-01-01

    This paper describes selected results from the flutter testing of the Supercritical Wing (SW) model. This model is a rigid semispan wing having a rectangular planform and a supercritical airfoil shape. The model was flutter tested in the Langley Transonic Dynamics Tunnel (TDT) as part of the Benchmark Models Program, a multi-year wind tunnel activity currently being conducted by the Structural Dynamics Division of NASA Langley Research Center. The primary objective of this program is to assist in the development and evaluation of aeroelastic computational fluid dynamics codes. The SW is the second of a series of three similar models which are designed to be flutter tested in the TDT on a flexible mount known as the Pitch and Plunge Apparatus. Data sets acquired with these models, including simultaneous unsteady surface pressures and model response data, are meant to be used for correlation with analytical codes. Presented in this report are experimental flutter boundaries and corresponding steady and unsteady pressure distribution data acquired over two model chords located at the 60 and 95 percent span stations.

  20. Theoretical and Computational Study of Forced-Convection Heat Transfer at Supercritical Pressures

    Science.gov (United States)

    Zhong, Jianguo

    In the simulation of turbulent fluid flow and heat transfer at supercritical pressures, substantial difficulties have been encountered in the modeling of turbulence and bounda-ry layer. This is due to significant fluid property variations with respect to the local temperature and pressure, especially in the near-wall region of a heated wall, where large temperature differences occur. The classical turbulence models available in literature were typically developed for constant-property fluids, where an empirical wall function in the high-Re k-epsilon model, and a damping function in the low-Re k-epsilon model were derived based on the constant-property data to solve the boundary layer. As it can be found in the existing literature, large differences have been observed between the experimental and numerical simulation results of the heat transfer coefficient predictions in the en-hanced and deteriorated heat transfer situations for supercritical fluids. In this thesis, a novel near-wall treatment method is proposed to treat large property variations in the thermal and velocity sub-layers. In the near-wall region, the supercritical fluids can be considered thermal-conductive and viscous forces dominated. The thick-ness of the viscous sub-layer (VSL) and the conduction sub-layer (CSL) can be related to the wall shear stress and local Prandtl number information by using computational CFD models, such as that implemented in the NPHASE-CMFD code. The fluids' bulk and wall temperature information has been obtained from the literature review of experi-mental measurements. The wall temperature and heat transfer coefficient calculated from the k-epsilon model with the proposed wall treatment method have been found to be in good agreement with experimental data for both heat transfer enhancement and deterioration cases for two most widely used fluids: CO2 and water. The proposed model has been applied in the reactor-scale thermal-hydraulic analysis of different flow path

  1. Experimental study on pressure and temperature distributions for low mass flux steam jet in subcooled water

    Institute of Scientific and Technical Information of China (English)

    YAN JunJie; WU XinZhuang; CHONG DaoTong

    2009-01-01

    A low mass flux steam jet in subcooled water was experimentally investigated. The transition of flow pattern from stable jet to condensation oscillation was observed at relatively high water temperature. The axial total pressures, the axial and radial temperature distributions were measured in the jet region. The results indicated that the pressure and temperature distributions were mainly influenced by the water temperature. The correlations corrected with water temperature were given to predict the dimen-sionless axial pressure peak distance and axial temperature distributions in the jet region, the results showed s good agreement between the predictions and experiments. Moreover, the self-similarity property of the radial temperature was obtained, which agreed well with Gauss distribution. In present work, all the dimensionless properties were mainly dependent on the water temperature but weakly on the nozzle size under a certain steam mass flux.

  2. I000MW超超临界机组过热汽温控制策略%Controlling strategy to the superheated steam temperature for 1000MW supercritical unit

    Institute of Scientific and Technical Information of China (English)

    宋强; 石磐

    2011-01-01

    Guangzhou Taishan 1000MW supercritical unit , as an example,the paper analyzes dynamic characteristic of the superheated steam temperature control for supercritical Unit of dynamic characteristic and discusses control strategy to superheated steam temperature fuel - water ratio and desuperheating water control. Finally, according to the practical examples, the paper carries out deliberate analysis and research.%以广州台山1000MW超超临界机组为例,分析了超超临界机组过热汽温控制的动态特性,论述了过热汽温控制中的燃水比和减温水控制策略,并根据实例进行了详细的分析和研究。

  3. Study of high-pressure adsorption from supercritical fluids by the potential theory

    DEFF Research Database (Denmark)

    Monsalvo, Matias Alfonso; Shapiro, Alexander

    2009-01-01

    The multicomponent potential theory of adsorption (MPTA), which has been previously used to study low-pressure adsorption of subcritical fluids, is extended to adsorption equilibria from supercritical fluids up to high pressures. The MPTA describes an adsorbed phase as an inhomogeneous fluid...... with thermodynamic properties that depend on the distance from the solid surface (or position in the porous space). The description involves the two kinds of interactions present in the adsorbed fluid, i.e. the fluid-fluid and fluid-solid interactions. accounted for by means of an equation of state (Eo......S) and interaction potential functions, respectively. This makes it possible to generate the different MPTA models by combination of the relevant EoS/potentials. In the present work, the simplified perturbed-chain statistical associating fluid theory (sPC-SAFT) EoS is used for the thermodynamic description of both...

  4. Design of experimental setup for supercritical CO2 jet under high ambient pressure conditions.

    Science.gov (United States)

    Shi, Huaizhong; Li, Gensheng; He, Zhenguo; Wang, Haizhu; Zhang, Shikun

    2016-12-01

    With the commercial extraction of hydrocarbons in shale and tight reservoirs, efficient methods are needed to accelerate developing process. Supercritical CO2 (SC-CO2) jet has been considered as a potential way due to its unique fluid properties. In this article, a new setup is designed for laboratory experiment to research the SC-CO2 jet's characteristics in different jet temperatures, pressures, standoff distances, ambient pressures, etc. The setup is composed of five modules, including SC-CO2 generation system, pure SC-CO2 jet system, abrasive SC-CO2 jet system, CO2 recovery system, and data acquisition system. Now, a series of rock perforating (or case cutting) experiments have been successfully conducted using the setup about pure and abrasive SC-CO2 jet, and the results have proven the great perforating efficiency of SC-CO2 jet and the applications of this setup.

  5. Preliminary Design of In-Pile Supercritical Pressurized Water Test Loop

    Institute of Scientific and Technical Information of China (English)

    2008-01-01

    <正>Based on two proven technologies, current light water reactors (LWRs) and the supercritical coal-fired power plants, the supercritical water-cooled reactor (SCWR) is one of the six Generation-Ⅳ

  6. Effects of Supercritical Fluids, Pressure, Temperature, and Molecular Structure on the Rheological Properties of Molten Polymers

    Science.gov (United States)

    Park, Hee Eon; Dealy, John M.

    2008-07-01

    Since high pressures are involved in most plastics forming processes, reliable high-pressure rheological data are required for the simulation of the processes. The effect of pressure is in some ways the reverse of that of temperature; for example increasing temperature decreases the viscosity, while pressure increases it. Supercritical fluids (SCFs) such as carbon dioxide and nitrogen can act as physical blowing agents in the manufacture of foams and as plasticizers to reduce melt viscosity during processing. The effects of dissolved SCF, pressure, and temperature on the rheological properties of a melt must be known to achieve optimum processing conditions. We used a rotational rheometer and a high-pressure sliding plate rheometer, in which the shear strain, temperature, pressure, and SCF concentration are all uniform. A shear stress transducer senses the stress in the center of the sample to avoid edge effects. It was possible to use shift factors for temperature, pressure and SCF (CO2 or N2) concentration to obtain a master curve. The effect of temperature could be described by the Arrhenius or WLF models, and the effect of pressure was described by the Barus equation. The effect of SCF concentration could be described by the Fujita-Kishimoto equation. The relative effects of pressure and temperature on the viscosity were quantified. To study the effects of short and long chain branching and a phenyl side group, three polymers were used: polyethylene, polypropylene, and polystyrene. We quantified the effects of short- and long-chain branching, pressure, temperature and dissolved SCF on the rheological properties of these three polymers by use of shift factors.

  7. Thermodynamic Optimization of Supercritical CO{sub 2} Brayton Cycles

    Energy Technology Data Exchange (ETDEWEB)

    Rhim, Dong-Ryul; Park, Sung-Ho; Kim, Su-Hyun; Yeom, Choong-Sub [Institute for Advanced Engineering, Yongin (Korea, Republic of)

    2015-05-15

    The supercritical CO{sub 2} Brayton cycle has been studied for nuclear applications, mainly for one of the alternative power conversion systems of the sodium cooled fast reactor, since 1960's. Although the supercritical CO{sub 2} Brayton cycle has not been expected to show higher efficiency at lower turbine inlet temperature over the conventional steam Rankine cycle, the higher density of supercritical CO{sub 2} like a liquid in the supercritical region could reduce turbo-machinery sizes, and the potential problem of sodium-water reaction with the sodium cooled fast reactor might be solved with the use of CO{sub 2} instead of water. The supercritical CO{sub 2} recompression Brayton cycle was proposed for the better thermodynamic efficiency than for the simple supercritical CO{sub 2} Brayton cycle. Thus this paper presents the efficiencies of the supercritical CO{sub 2} recompression Brayton cycle along with several decision variables for the thermodynamic optimization of the supercritical CO{sub 2} recompression Brayton cycle. The analytic results in this study show that the system efficiency reaches its maximum value at a compressor outlet pressure of 200 bars and a recycle fraction of 30 %, and the lower minimum temperature approach at the two heat exchangers shows higher system efficiency as expected.

  8. 火电厂600MW超临界机组汽轮机胀差控制分析%Steam Turbine Differential Expansion Controlling Analysis of 600 MW Supercritical Unit in Thermal Power Plant

    Institute of Scientific and Technical Information of China (English)

    杨晨; 朱懿

    2012-01-01

    N600-24.2/566/566 supercritical steam turbine which is made by Shanghai Steam Turbine Plant, for example, importance and variation of differential expansion controlling of steam turbine, mutual relations of the rotor and stator expansion, and the most effective technical measures of controlling differential expansion in the start-up process of Phase I 2 x 600 MW supercritical steam turbine of Huangjinbu Power Generation Co.,Ltd. of State Power Grid in Jiangxi were analyzed, and had some reference values for other turbines.%以上海汽轮机厂生产的N600.24.2/566/566型超临界汽轮机为例,分析了江西国电黄金埠发电有限公司1期2台600MW超临界汽轮机启动过程中,汽轮机胀差控制的重要性、变化规律、转子和静子膨胀的相互关系以及采取的最有效的控制胀差的技术措施,对于其它汽轮机具有一定的参考价值。

  9. Effect of Heated Perimeter on Forced Convection Heat Transfer of he i at a Supercritical Pressure

    Science.gov (United States)

    Doi, D.; Shiotsu, M.; Shirai, Y.; Hama, K.

    2008-03-01

    The forced convection heat transfer coefficients were measured on two pairs of test plates all 6.0 mm in width and located face to face on inner walls of a rectangular duct. Each pair having length of 20 mm and 80 mm, respectively, was connected in series electrically. The rectangular duct was 420 mm in length and 5 mm×6 mm in inner cross section. The experiments were performed for inlet temperatures from 2.2 to 6.5 K, flow velocities from 0.1 to 5.6 m/s, and at a supercritical pressure of 2.8 atm. Comparison of the obtained Nusselt numbers with the former results with a single test plate showed the clear effect of a heated perimeter. Non-dimensional heat transfer equation including the effect of heated perimeter is presented.

  10. Design and evaluation of a high temperature/pressure supercritical carbon dioxide direct tubular receiver for concentrating solar power applications

    Science.gov (United States)

    Ortega, Jesus Daniel

    This work focuses on the development of a solar power thermal receiver for a supercritical-carbon dioxide (sCO2), Brayton power-cycle to produce ~1 MWe. Closed-loop sCO2 Brayton cycles are being evaluated in combination with concentrating solar power to provide higher thermal-to-electric conversion efficiencies relative to conventional steam Rankine cycles. High temperatures (923--973 K) and pressures (20--25 MPa) are required in the solar receiver to achieve thermal efficiencies of ~50%, making concentrating solar power (CSP) technologies a competitive alternative to current power generation methods. In this study, the CSP receiver is required to achieve an outlet temperature of 923 K at 25 MPa or 973 K at 20 MPa to meet the operating needs. To obtain compatible receiver tube material, an extensive material review was performed based the ASME Boiler and Pressure Vessel Code, ASME B31.1 and ASME B313.3 codes respectively. Subsequently, a thermal-structural model was developed using a commercial computational fluid (CFD) dynamics and structural mechanics software for designing and analyzing the tubular receiver that could provide the heat input for a ~2 MWth plant. These results were used to perform an analytical cumulative damage creep-fatigue analysis to estimate the work-life of the tubes. In sequence, an optical-thermal-fluid model was developed to evaluate the resulting thermal efficiency of the tubular receiver from the NSTTF heliostat field. The ray-tracing tool SolTrace was used to obtain the heat-flux distribution on the surfaces of the receiver. The K-ω SST turbulence model and P-1 radiation model used in Fluent were coupled with SolTrace to provide the heat flux distribution on the receiver surface. The creep-fatigue analysis displays the damage accumulated due to the cycling and the permanent deformation of the tubes. Nonetheless, they are able to support the required lifetime. The receiver surface temperatures were found to be within the safe

  11. Hydrolases in supercritical CO2 and their use in a high-pressure membrane reactor.

    Science.gov (United States)

    Knez, Z; Habulin, M; Primozic, M

    2003-03-01

    The thermal stability and activity of enzymes in supercritical carbon dioxide (SC CO(2)) and near-critical propane were studied at a pressure of 300 bar in the temperature range 20-90 degrees C. Proteinase from Carica papaya was incubated in microaqueous SC CO(2) at atmospheric pressure in a nonaqueous system. Lipase stability in an aqueous medium at atmospheric pressure and in SC CO(2) as well as near-critical propane at 100 bar and 40 degrees C was studied. In order to investigate the impact of solvent on lipases, these were chosen from different sources: Pseudomonas fluorescences, Rhizpous javanicus, Rhizopus niveus and porcine pancreas. On the basis of our previous study on lipase activities in dense gases, a high-pressure continuous flat-shape membrane reactor was designed. The hydrolysis of sunflower oil in SC CO(2) was performed as a model reaction in this reactor. The reaction was catalyzed by the lipase preparation Lipolase 100T and was performed at 50 degrees C and 200 bar.

  12. LOCA steam condensation loads in BWR Mark II pressure suppression containment system

    Energy Technology Data Exchange (ETDEWEB)

    Kukita, Y.; Namatame, K.; Takeshita, I.; Shiba, M.

    1987-06-01

    Hydrodynamic loads induced in the BWR Mark II pressure suppression containment system during a loss-of-coolant accident (LOCA) were investigated using a large scale test facility. The maximum-bounding loading conditions on the pressure suppression pool-boundary structures were defined by conducting experiments for a wide range of parameters. The maximum-bounding loads occurred when steam, with air concentration less than 1% in weight, was injected at moderate rates (approx. = 30 kg/m/sup 2/.s) into a low-temperature (below 310 K) pool. Such conditions are most likely to be encountered during LOCAs with intermediate break sizes.

  13. Pressure losses during steam flow and condensation in tubes and channels

    Science.gov (United States)

    Leontiev, A. I.; Milman, O. O.

    2014-12-01

    Theoretical and experimental investigations have revealed the dependence of parameters of the process of steam condensation in tubes and channels on the scheme of heat-exchange fluid flow, including counter, forward, and cross flow systems. The total pressure losses in the case of counter flow are greater than those in the case of forward and cross flow. This dependence is valid for the flow of gases and plasma in channels with significant density variation (e.g., due to heating and cooling). Pressure losses have been evaluated using various computational models, and the results are compared to experimental data.

  14. 超超临界二次再热汽轮机发展综述%Development of Ultra-supercritical Double-reheat Steam Turbine

    Institute of Scientific and Technical Information of China (English)

    王建录; 张晓东

    2016-01-01

    文章概述了汽轮机二次再热技术的发展历程,当前我国超超临界二次再热汽轮机技术研发情况,并重点介绍了我国首台超超临界二次再热汽轮机技术特点及运行情况,对未来二次再热汽轮机技术发展方向和典型机型进行了探讨。%This paper introduces the evolution of double-reheat turbine technology, the development of the ultra-supercritical double-reheat turbine technology in China,and mainly introduces the technical charateristic and operation conditions of the first ultra-super⁃critical double-reheat turbine unit made by DTC in China. The new development direction and typical models of the double-reheat steam turbine designed by DTC is discussed in this paper.

  15. Steam chemistry - interaction of chemical species with water, steam, and materials during evaporation, superheating, and condensation. Proceedings

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    1999-07-01

    Topics of this proceedings are: steam chemistry, supercritical water, effects of chemicals in steam (acetic acid, formic acid, phosphoric acid or other impurities); solubility and deposition, condensation processes and effect of impurities; nucleation; gas-liquid interfaces; steam treatment. (SR)

  16. An Isothermal Steam Expander for an Industrial Steam Supplying System

    OpenAIRE

    Chen-Kuang Lin; Guang-Jer Lai; Yoshiyuki Kobayashi; Masahiro Matsuo; Min-Chie Chiu

    2015-01-01

    Steam is an essential medium used in the industrial process. To ensure steam quality, small and middle scale boilers are often adopted. However, because a higher steam pressure (compared to the necessary steam pressure) is generated, the boiler’s steam pressure will be reduced via a pressure regulator before the steam is directed through the process. Unfortunately, pressure is somewhat wasted during the reducing process. Therefore, in order to promote energy efficiency, a pressure regulator i...

  17. Erosion study of final stage blading of low pressure steam turbines

    Science.gov (United States)

    Dehouve, J.; Nardin, P.; Zeghmati, M.

    1999-04-01

    In order to increase our knowledge of erosion phenomena, the Steam Turbine Groupe (STG) of ALSTOM has been using an erosion test facility in the C.R.T.V. (Centre de Recherche Turbines à Vapeur). This test facility simulates erosion in low pressure steam turbine cylinders in order to compare the erosion resistance of various blade materials (12% chromium steel, titanium alloys, etc.) and their protection (superficial hardening, coatings, etc.). This test facility also allows us to understand the mechanism causing damage at a macroscopic level (impact energy of the droplets and the loss of eroded volume) and at a microscopic level (residual stress and metallurgic analysis) and therefore to determine an evolution law of material surface damage. In this paper, the behaviour of the materials (12% chromium steel and titanium alloys), which has been analysed by image production measurement methods, will be presented according to different impact velocities.

  18. DETERMINATION OF ROCK-BREAKING PERFORMANCE OF HIGH-PRESSURE SUPERCRITICAL CARBON DIOXIDE JET

    Institute of Scientific and Technical Information of China (English)

    DU Yu-kun; WANG Rui-he; NI Hong-jian; LI Mu-kun; SONG Wei-qiang; SONG Hui-fang

    2012-01-01

    In this study,a well-designcd cxperimental setup is used to determine the rock-breaking performance of a high-pressure supercritical carbon dioxide (SC-CO2) jet.Its rock-breaking performance is first compared with that of a high-pressure water jet under the same operation conditions.The effects of five major factors that affect the rock-breaking performance of the high-pressure SC-CO2 jet,i.e.,the nozzle diameter,the standoff distance,the jet pressure,the rock compressive strength and the jet temperature are experimentally determined.The experimental results indicate that the rock-breaking performance of the SC-CO2 jet is significantly improved over the high-pressure water jet.It is also found that the rock-breaking performance of the SC-CO2 jet is improved with the increase of the nozzle diameter or the standoff distance,until the nozzle diameter or the standoff distance reaches a certain critical value and after that it begins to deteriorate.The rock-breaking performance of the SC-CO2 jet improves monotonically with the increase of the jet pressure,while it shows a monotonic deterioration with the increase of the rock compressive strength.In addition,it is found that,under the same working conditions,the SC-CO2 jet can always provide a better rock-breaking performance than the subcritical liquid CO2 jet.

  19. Simulation of Oxygen Disintegration and Mixing With Hydrogen or Helium at Supercritical Pressure

    Science.gov (United States)

    Bellan, Josette; Taskinoglu, Ezgi

    2012-01-01

    The simulation of high-pressure turbulent flows, where the pressure, p, is larger than the critical value, p(sub c), for the species under consideration, is relevant to a wide array of propulsion systems, e.g. gas turbine, diesel, and liquid rocket engines. Most turbulence models, however, have been developed for atmospheric-p turbulent flows. The difference between atmospheric-p and supercritical-p turbulence is that, in the former situation, the coupling between dynamics and thermodynamics is moderate to negligible, but for the latter it is very significant, and can dominate the flow characteristics. The reason for this stems from the mathematical form of the equation of state (EOS), which is the perfect-gas EOS in the former case, and the real-gas EOS in the latter case. For flows at supercritical pressure, p, the large eddy simulation (LES) equations consist of the differential conservation equations coupled with a real-gas EOS. The equations use transport properties that depend on the thermodynamic variables. Compared to previous LES models, the differential equations contain not only the subgrid scale (SGS) fluxes, but also new SGS terms, each denoted as a correction. These additional terms, typically assumed null for atmospheric pressure flows, stem from filtering the differential governing equations, and represent differences between a filtered term and the same term computed as a function of the filtered flow field. In particular, the energy equation contains a heat-flux correction (q-correction) that is the difference between the filtered divergence of the heat flux and the divergence of the heat flux computed as a function of the filtered flow field. In a previous study, there was only partial success in modeling the q-correction term, but in this innovation, success has been achieved by using a different modeling approach. This analysis, based on a temporal mixing layer Direct Numerical Simulation database, shows that the focus in modeling the q

  20. Steam Turbine Materials and Corrosion

    Energy Technology Data Exchange (ETDEWEB)

    Holcomb, G.H.; Hsu, D.H.

    2008-07-01

    Ultra-supercritical (USC) power plants offer the promise of higher efficiencies and lower emissions. Current goals of the U.S. Department of Energy’s Advanced Power Systems Initiatives include coal generation at 60% efficiency, which would require steam temperatures of up to 760 °C. In prior years this project examined the steamside oxidation of alloys for use in high- and intermediate-pressure USC turbines. This steamside oxidation research is continuing and progress is presented, with emphasis on chromia evaporation.

  1. Characteristics of turbulent heat transfer in an annulus at supercritical pressure

    Science.gov (United States)

    Peeters, J. W. R.; Pecnik, R.; Rohde, M.; van der Hagen, T. H. J. J.; Boersma, B. J.

    2017-02-01

    Heat transfer to fluids at supercritical pressure is different from heat transfer at lower pressures due to strong variations of the thermophysical properties with the temperature. We present and analyze results of direct numerical simulations of heat transfer to turbulent CO2 at 8 MPa in an annulus. Periodic streamwise conditions are imposed so that mean streamwise acceleration due to variations in the density does not occur. The inner wall of the annulus is kept at a temperature of 323 K, while the outer wall is kept at a temperature of 303 K. The pseudocritical temperature Tp c=307.7 K, which is the temperature where the thermophysical properties vary the most, can be found close to the inner wall. This work is a continuation of an earlier study, in which turbulence attenuation due to the variable thermophysical properties of a fluid at supercritical pressure was studied. In the current work, the direct effects of variations in the specific heat capacity, thermal diffusivity, density, and the molecular Prandtl number on heat transfer are investigated using different techniques. Variations in the specific heat capacity cause significant differences between the mean nondimensionalized temperature and enthalpy profiles. Compared to the enthalpy fluctuations, temperature fluctuations are enhanced in regions with low specific heat capacity and diminished in regions with a large specific heat capacity. The thermal diffusivity causes local changes to the mean enthalpy gradient, which in turn affects molecular conduction of thermal energy. The turbulent heat flux is directly affected by the density, but it is also affected by the mean molecular Prandtl number and attenuated or enhanced turbulent motions. In general, enthalpy fluctuations are enhanced in regions with a large mean molecular Prandtl number, which enhances the turbulent heat flux. While analyzing the Nusselt numbers under different conditions it is found that heat transfer deterioration or enhancement can

  2. Two-Phase Instability Characteristics of Printed Circuit Steam Generator for the Low Pressure Condition

    Energy Technology Data Exchange (ETDEWEB)

    Kang, Han-Ok; Han, Hun Sik; Kim, Young-In; Kim, Keung Koo [Korea Atomic Energy Research Institute, Daejeon (Korea, Republic of)

    2015-05-15

    Reduction of installation space for steam generators can lead to much smaller reactor vessel with resultant decrease of overall manufacturing cost for the components. A PCHE(Printed Circuit Heat Exchanger) is one of the compact types of heat exchangers available as an alternative to conventional shell and tube heat exchangers. Its name is derived from the procedure used to manufacture the flat metal plates that form the core of the heat exchanger, which is done by chemical milling. These plates are then stacked and diffusion bonded, converting the plates into a solid metal block containing precisely engineered fluid flow passages. PCSG(Printed Circuit Steam Generator) is a potential candidate to be applied to the integral reactor with its compactness and mechanical robustness. For the introduction of new steam generator, design requirement for the two-phase flow instability should be considered. This paper describes two-phase flow instability characteristics of PCSG for the low pressure condition. PCSG is a potential candidate to be applied to the integral reactor with its compactness and mechanical robustness. Interconnecting flow path was developed to mitigate the two-phase flow instability in the cold side. The flow characteristics of two-phase flow instability at the PCSG is examined experimentally in this study.

  3. Steam pressure induced in crack-like cavities in moisture saturated polymer matrix composities during rapid heating

    Energy Technology Data Exchange (ETDEWEB)

    Chung Yuen Hui; Muralidhharan, V. [Cornell Univ., Ithaca, NY (United States). Dept. of Theoretical and Applied Mechanics; Thompson, M.O. [Cornell Univ., Ithaca, NY (United States). Dept. of Material Science and Engineering

    2005-02-01

    The time history of steam pressure inside an isolated ''crack-like'' micro-cavity in a polymer matrix composite is studied by assuming that the chemical potential of water is continuous across the cavity/polymer interface. Steam pressure inside the cavity is due to rapid heating of moisture-saturated composites from its initial temperature to a final temperature T{sub f}. Exact closed form solutions are obtained for a ''crack-like'' cavity inside an infinite and a finite plate. For the case of an infinite plate, the exact solution shows that the steam pressure approaches the saturated steam pressure p{sub sat}(T{sub f}) at a characteristic time t{sub c}{approx_equal}25h{sup 2}/D{sub f}(M{sub w}p{sub sat}(T{sub f})/RT{sub f}{psi}{sub 0}){sup 2}, where h is the cavity height, D{sub f} is the diffusivity of water at T{sub f}, M{sub w} is the molecular weight of water, {psi}{sub 0} is the initial moisture concentration of the composite and R is the universal gas constant. When moisture is allowed to escape from the composite, such as in the case of a finite plate, the maximum steam pressure depends on a single dimensionless parameter {alpha}=LRT{sub f}{psi}{sub 0}/hM{sub w}p{sub sat}(T{sub f}), where L is the thickness of the composite plate. For large {alpha}, the maximum steam pressure approaches p{sub sat}(T{sub f}). However, the maximum steam pressure can be significantly less than p{sub sat}(T{sub f}) when {alpha} {<=} 4. The present model can also be used to study the 'popcorning' observed in electronic packages. (author)

  4. Exploration of Adopting 623 ℃ Reheat Steam Temperature in 660-MW Ultra-Supercritical Type Ⅱ Boilers%660 MW超超临界Ⅱ型锅炉再热汽温623 ℃探索

    Institute of Scientific and Technical Information of China (English)

    翟德双

    2013-01-01

    The 623℃ reheat steam temperature will be adopted for two 660-MW ultra-supercritical units in phase Ⅱ of a power plant project. This is the first case for type Ⅱ boilers in the world. The operation of the 660-MW ultra-supercritical units with 603 ℃ reheat steam temperature is introduced, and then the design of elevating the reheat steam temperature up to 623℃ is presented. Further, related economic analysis is conducted and security measures are proposed. Finally, some suggestions on the installation, debugging and operation of the two boilers are also included.%某电厂二期工程2台660 MW超超临界机组再热汽温选择623C高参数,在全球的Ⅱ型锅炉中将是首次采用.介绍了目前660 MW超超临界机组冉热汽温603℃的使用运行情况,分析提出了再热汽温提高到623℃的相关设计方案及相应的安全措施,并进行了经济性分析,指出锅炉在安装、调试和运行中应注意的问题.

  5. The noncondensable gas effects on loss-of-coolant accident steam condensation loads in boiling water reactor pressure suppression pool

    Energy Technology Data Exchange (ETDEWEB)

    Kukita, Y.; Namatame, K.; Shiba, M.; Takeshita, I.

    1983-11-01

    The noncondensable gas effects on the loss-ofcoolant-accident-induced steam condensation loads in the boiling water reactor pressure suppression pool have been investigated with regard to experimental data obtained from a large-scale multivent test program. Previous studies have noted that the presence of the noncondensable gas (air), which initially fills the containment drywell space, stabilizes the direct-contact condensation in the pressure suppression pool and hampers onset of the chugging phenomenon, which induces most significant steam condensation load onto the pool boundary. This was found to be true for the tests with relatively small-break diameters, where the maximum steam mass fluxes in the vent pipe were lower than the upper threshold value for the onset of chugging. However, in the tests with the maximum vent steam mass fluxes moderately higher than the chugging upper threshold value, early depletion of the noncondensable gas tended to result in significant stabilization of steam condensation accompanied by an excursion of temperature of pool water surrounding the vent pipe outlets, which led to a delayed onset of chugging. Due to this combined influence of the noncondensable gas and nonuniform pool temperature, and due to dependence of magnitude of chugging load on the vent steam mass flux, the peak magnitude of the steam condensation load appearing in a blowdown can be very sensitive to the initial and break conditions.

  6. Peculiarities of heat transfer to a turbulent flow of liquid under supercritical pressure

    Energy Technology Data Exchange (ETDEWEB)

    Kafengauz, N.L.

    1967-03-21

    The modern theory of thermal exchange is based on the hypothesis that the state of a fluid heat-carrier always remains in a thermodynamic equilibrium, and all the thermo- physical properties can be determined according to the corresponding tales if temperature and pressure are known. In the critical region, the substances acquire certain peculiar features, thus making the applicability of this hypothesis doubtful. This problem was studied experimentally at supercritical pressures when tDfU pDcriticalU) occurs along the thickness of the boundary layer only at sufficiently high temperature gradients. When the flow velocities are high, the boundary layer is thin, and the heat flux is high, the temperature gradient is also high and phase transitions take place. At low velocities, when the gradient is low, the substance preserves the properties of a fluid despite the fact that the temperature of the boundary layer may exceed by several hundreds of degrees that of tDmax. th. cap.U.

  7. 1000 MW超超临界汽轮机高压外缸蠕变强度的分析%Creep Strength Analysis on HP Outer Casing of a 1 000 MW Ultra Supercritical Steam Turbine

    Institute of Scientific and Technical Information of China (English)

    蒋浦宁

    2013-01-01

    以1 000 MW超超临界汽轮机高压外缸为研究对象,通过引入Norton-Bailey材料蠕变本构方程和Cocks-Ashby多轴韧度系数,对汽缸轴对称二维模型的温度场、应力场和CA蠕变等效应变分布进行了计算,找出了结构设计中不合理区域并提出相应的结构改进方案.结果表明:经改进的高压外缸结构设计是合理的;CA蠕变等效应变计算结果均小于推荐考核标准,该1 000 MW超超临界汽轮机高压外缸的高温蠕变应变强度能够满足设计要求.%Taking the high-pressure outer casing of a 1 000 MW ultra supercritical steam turbine as an object of study, and by adopting the Norton-Bailey material creep constitutive equation and Cocks-Ashby multiaxial coefficient, the temperature field, stress field and the CA equivalent creep strain dictribution of the 2D axisymmetric model were calculated, during which the unreasonable structure of original design was found out and impoved with corresponding schemes. Results show that the improved structure of the HP outer casing is reasonable; all the calculated results of CA equivalent creep strain are less than those in the recommended criteria for assessment. The high-temperature creep strain of above mentioned outer casing can meet the design requirements.

  8. INFLUENCE OF STEAM PRESSURE ON THE PHYSICO-CHEMICAL PROPERTIES OF DEGRADED HEMICELLULOSES OBTAINED FROM STEAM-EXPLODED LESPEDEZA STALKS

    Directory of Open Access Journals (Sweden)

    Kun Wang

    2010-06-01

    Full Text Available Steam explosion pretreatment was used to release hemicelluloses from the stalks of Lespedeza crytobotrya, a potential woody biomass crop. Hemicelluloses from Lespedeza crytobotrya subjected to five different pretreatment severities were extracted with 60% aqueous ethanol solution containing 1% NaOH, characterized by component analysis, gel permeation chromatography (GPC, FT-IR, NMR spectroscopy, and thermal analysis, and compared with hemicelluloses obtained from untreated stalks. It was found that the hemicellulosic fractions mainly consisted of arabinoxylans and β-glucans or xyloglucans. Steam explosion pretreatment yielded noticeable degradation and debranching reactions, illustrated by a linear decrease of molecular weight and Ara/Xyl ratio with increasing severity. For further high-value utilization of the hemicellulosic polymers, steam explosion at 20 or 22.5 kg/m2 for 4 min is promising because of improved extraction efficiency and avoidance of over-drastic degradation of the polymers.

  9. Supercritical impregnation of polymer matrices spatially confined in microcontainers for oral drug delivery: Effect of temperature, pressure and time

    DEFF Research Database (Denmark)

    Marizza, Paolo; Pontoni, L.; Rindzevicius, Tomas

    2016-01-01

    parameters(temperature, pressure, time, drug concentration in the supercritical phase) was elucidated with respectto the loading capacity. The microcontainer filling was observed by means of optical macroimaging, X-ray microtomography and scanning electron microscopy. The physical state of the drug...... described. The drug loading can be controlled with high accuracy and reproducibility andthe impregnated drug is in amorphous state. These results demonstrate that SCI can be used as a highthroughput loading technique for microfabricated devices for oral drug delivery....

  10. Ultra high efficiency/low pressure supercritical fluid chromatography with superficially porous particles for triglyceride separation.

    Science.gov (United States)

    Lesellier, E; Latos, A; de Oliveira, A Lopes

    2014-01-31

    This paper reports the development of the separation of vegetable oil triglycerides (TG) in supercritical chromatography (SFC), using superficially porous particles (SPPs). The SPP, having a small diameter (2-3μm), provide a higher theoretical plate number (N), which allows to improve separation of critical pairs of compounds. However, compared to fully porous particles of larger diameter (5μm), the pressure drop is also increased. Fortunately, supercritical fluids have a low viscosity, which allows coupling several columns to achieve high N values, while maintaining flow rate above 1ml/min, ensuring a ultra high efficiency (UHE) at low pressure (LP) (below 40MPa), with regards to the one reached with liquid and sub-two micron particles (around 100MPa). The use of two detector systems (UV and ELSD) connected in series to the UHE-LP-SFC system provides complementary responses, due to their specific detection principles. Working in a first part with three coupled Kinetex C18 columns (45cm total length), the effect of modifier nature and percentage were studied with two reference oils, argan and rapeseed, chosen for their different and well-known TG composition. The analytical method was developed from previous studies performed with fully porous particles (FPP). Optimized conditions with three Kinetex were as follows: 17°C, 12% of ACN/MeOH (90/10; v/v). With these conditions, and by using an increased length of Kinetex C18 column (60cm), another additional column was selected from ten different commercial SPP C18 bonded phases, by applying a Derringer function on varied parameters: theoretical plate number (TPN), separation index (SI) for critical pairs of peaks (the peaks of compounds difficult to separate due to subtle structural differences), the analysis duration, and the total peak number. This function normalizes the values of any parameters, between 0 and 1, from the worst value to the better, allowing to take account of various parameters in the final

  11. Analysis of the temperature distribution of a water wall in the furnace of a supercritical steam power plant

    Energy Technology Data Exchange (ETDEWEB)

    Matsumura, Norihide; Yagi, Nobuyoshi; Shibayama, Motoaki; Hayasaka, Hiroshi

    1988-07-25

    It is one of the important subjects for maintenance and management of modern boilers to establish the technology for estimating the residual life of a water wall tube composing a boiler furnace for a thermal power plant. Various studies on the residual life of material itself for a boiler water-wall tube have so far been in progress, but concerning a temperature of a water wall tube at a particular place inside a boiler furnace, the development of a practical method of analysis estimating the amount of the radiant heat transfer has not so far been progressed. Accordingly, in this report, a practical method for obtaining the temperature distribution of a water wall tube was examined and an idea that the radiant heat ray method was used for the analysis of radiant heat transfer and at the same time, the actual result of the operation was used for steam flow rate, etc. was elaborated and brought into operation. As a result, the following was revealed inter alia: (1) The heat flux became the maximum around the uppermost stages of the burners of the front and rear walls. (2) The temperature of a tube wall became the maximum around the uppermost stages of the burners in the center of the wall. (3) Deviation of the flow distribution affected the wall tube temperature considerably. The above is considered to suggest the adequacy of this analytical method. (12 figs, 9 refs)

  12. High Temperature and Pressure Steam-H2 Interaction with Candidate Advanced LWR Fuel Claddings

    Energy Technology Data Exchange (ETDEWEB)

    Pint, Bruce A [ORNL

    2012-08-01

    This report summarizes the work completed to evaluate cladding materials that could serve as improvements to Zircaloy in terms of accident tolerance. This testing involved oxidation resistance to steam or H{sub 2}-50% steam environments at 800-1350 C at 1-20 bar for short times. A selection of conventional alloys, SiC-based ceramics and model alloys were used to explore a wide range of materials options and provide guidance for future materials development work. Typically, the SiC-based ceramic materials, alumina-forming alloys and Fe-Cr alloys with {ge}25% Cr showed the best potential for oxidation resistance at {ge}1200 C. At 1350 C, FeCrAl alloys and SiC remained oxidation resistant in steam. Conventional austenitic steels do not have sufficient oxidation resistance with only {approx}18Cr-10Ni. Higher alloyed type 310 stainless steel is protective but Ni is not a desirable alloy addition for this application and high Cr contents raise concern about {alpha}{prime} formation. Higher pressures (up to 20.7 bar) and H{sub 2} additions appeared to have a limited effect on the oxidation behavior of the most oxidation resistant alloys but higher pressures accelerated the maximum metal loss for less oxidation resistant steels and less metal loss was observed in a H{sub 2}-50%H{sub 2}O environment at 10.3 bar. As some of the results regarding low-alloyed FeCrAl and Fe-Cr alloys were unexpected, further work is needed to fundamentally understand the minimum Cr and Al alloy contents needed for protective behavior in these environments in order to assist in alloy selection and guide alloy development.

  13. 超临界直流炉主蒸汽温度控制积分饱和问题解决方法%Solution of Integral Saturationon Steam Temperature Control in Supercritical Monotubeboiler

    Institute of Scientific and Technical Information of China (English)

    蒋明达

    2015-01-01

    The paper introduces the cause and its effect and puts forward a solution to the problem of integral saturation in main steam temperature control system in Luohe Power Plant of Datang Power's #6 supercritical monotube boiler.%本文分析了超临界直流炉主蒸汽温度控制积分饱和问题产生原因及影响,对大唐洛河发电厂#6超临界直流锅炉主蒸汽温控制系统出现的积分饱和问题提出了解决方案.

  14. Investigation of high pressure steaming (HPS) as a thermal treatment for lipid extraction from Chlorella vulgaris.

    Science.gov (United States)

    Aguirre, Ana-Maria; Bassi, Amarjeet

    2014-07-01

    Biofuels from algae are considered a technically viable energy source that overcomes several of the problems present in previous generations of biofuels. In this research high pressure steaming (HPS) was studied as a hydrothermal pre-treatment for extraction of lipids from Chlorella vulgaris, and analysis by response surface methodology allowed finding operational points in terms of target temperature and algae concentration for high lipid and glucose yields. Within the range covered by these experiments the best conditions for high bio-crude yield are temperatures higher than 174°C and low biomass concentrations (<5 g/L). For high glucose yield there are two suitable operational ranges, either low temperatures (<105°C) and low biomass concentrations (<4 g/L); or low temperatures (<105°C) and high biomass concentrations (<110 g/L). High pressure steaming is a good hydrothermal treatment for lipid recovery and does not significantly change the fatty acids profile for the range of temperatures studied.

  15. Effect of Dietary Levels of High Pressure Steam Native Lablab purpureus (L sweet on Broiler Performance

    Directory of Open Access Journals (Sweden)

    Muhammad Ludfi

    2014-06-01

    Full Text Available Lablab purpureus (L sweet was origin planted on east java province, Indonesia. The native name is komak beans. It has high protein (30% -33%, but the inclusion is limited caused by anti-nutrition factors such as tannin, phytic acid, and anti-trypsin. Anti-nutrition substances interfere with metabolism and protein synthesis in intestinal tract. Komak beans were processed with high pressure steam (2 atm; 121 0C; 20 min and called Komak Beans Meal (KBM. This study focused on replacing Soybeans Meal (SBM based diet using uplift level until totally replaced with KBM. The study designated for 100 birds one-day old Cobb strain. Raising period was 5 weeks. The treatments were: Control (Basal diet; 25 % KBM replacement; 50 % KBM replacement; 75 % KBM replacement and 100 % KBM replacement. Data were analyzed using analysis of variance (ANOVA. The results showed that 25% KBM replacement was not significantly different with control and could increase 1.04 % feed consumption; 1.23 % body weights gain, 0.97 % production index and decreased feed conversion rate (0.73 %. High pressure steam KBM process had been effective in decreasing anti-nutrition effect and didn’t cause abnormalities on broiler production performance. It could improve the broiler production performance at level of 25% KBM inclusion replacement.

  16. Combination of Low-pressure Steam Explosion and Alkaline Peroxide Pretreatment for Separation of Hemicellulose

    Directory of Open Access Journals (Sweden)

    Yang Xing

    2014-04-01

    Full Text Available Low-pressure steam explosion (LPSE combined with alkaline peroxide (AP pretreatment was first employed to separate hemicellulose from Lespedeza stalks. The monosaccharide composition and molecular weight distribution of the obtained hemicellulose fractions were characterized in this study. The results show that the hemicellulose extracted from Lespedeza stalks consisted of xylose, glucose, galactose, and mannose, which was a mixture of arabinoxylans and xyloglucans or β-glucans. The yield of hemicellulose fractions after AP pretreatment ranged from 11.2% (2.5% hydrogen peroxide (H2O2, w/v for 12 h to 12.2% (3.3% H2O2, w/v for 72 h. The molecular weight of hemicellulose decreased from 2,458 g/mol to 1,984 g/mol after AP pretreatment, indicating its degradation reaction. The structure of hemicellulose was analyzed by Fourier transform infrared spectroscopy, proton nuclear magnetic resonance, and heteronuclear single quantum coherence. The AP pretreatment partially cleaved the backbone and the ether linkage between lignin and hemicelluloses. Also, branched-chain α-D-arabinofuranosyl in which β-D-xylose substituted at the C-3 position (monosubstituted was removed, illustrating a partial debranching reaction. Therefore, the combination of low-pressure steam explosion and alkaline peroxide pretreatment (LPSE-AP is an effective pretreatment method to separate hemicellulose from Lespedeza stalk.

  17. Capillary pressure heterogeneity and hysteresis for the supercritical CO2/water system in a sandstone

    Science.gov (United States)

    Pini, Ronny; Benson, Sally M.

    2017-10-01

    We report results from an experimental investigation on the hysteretic behaviour of the capillary pressure curve for the supercritical CO2-water system in a Berea Sandstone core. Previous observations have highlighted the importance of subcore-scale capillary heterogeneity in developing local saturations during drainage; we show in this study that the same is true for the imbibition process. Spatially distributed drainage and imbibition scanning curves were obtained for mm-scale subsets of the rock sample non-invasively using X-ray CT imagery. Core- and subcore-scale measurements are well described using the Brooks-Corey formalism, which uses a linear trapping model to compute mobile saturations during imbibition. Capillary scaling yields two separate universal drainage and imbibition curves that are representative of the full subcore-scale data set. This enables accurate parameterisation of rock properties at the subcore-scale in terms of capillary scaling factors and permeability, which in turn serve as effective indicators of heterogeneity at the same scale even when hysteresis is a factor. As such, the proposed core-analysis workflow is quite general and provides the required information to populate numerical models that can be used to extend core-flooding experiments to conditions prevalent in the subsurface, which would be otherwise not attainable in the laboratory.

  18. 700℃以上超超临界汽轮机高中压转子用材研究%Research on the Materials of HP and MP Rotor of More than 700℃Ultra-supercritical Steam Turbine

    Institute of Scientific and Technical Information of China (English)

    彭建强

    2013-01-01

    综合国外700℃以上汽轮机高中压转子材料研究情况,结合我国高温合金材料的发展水平,给出我国700℃以上超超临界汽轮机高中压转子用材建议。%Integrated with domestic and international research situation on HP and MP rotor of more than 700℃steam turbine , and combined with the development level of high temperature alloy materials in China , the suggestion are given for the material of HP and MP rotor of more than 700℃ultra-supercritical steam turbine in China .

  19. Stress and integrity analysis of steam superheater tubes of a high pressure boiler

    Directory of Open Access Journals (Sweden)

    Neves Daniel Leite Cypriano

    2004-01-01

    Full Text Available Sources that can lead to deterioration of steam superheater tubes of a high pressure boiler were studied by a stress analysis, focused on internal pressure and temperature experienced by the material at real operating conditions. Loss of flame control, internal deposits and unexpected peak charge are factors that generate loads above the design limit of tube materials, which can be subjected to strain, buckling, cracks and finally rupture in service. To evaluate integrity and dependability of these components, the microstructure of selected samples along the superheater was studied by optical microscopy. Associated with this analysis, dimensional inspection, nondestructive testing, hardness measurement and deposit examination were made to determine the resultant material condition after twenty three years of operation.

  20. [The effect of growth media on recovery of test microorganisms after exposure to saturated steam under pressure].

    Science.gov (United States)

    Krzywicka, H; Jakimiak, B; Zarzycka, E

    1996-01-01

    The aim of this study was to find out which growth media give the best condition for the development of test bacteria after exposure to saturated steam under pressure. The test organisms were strains of Bacillus subtilis NCTC 3610 and Bacillus stearothermophilus NCTC 8923. The test prepared from spore suspension were exposed to saturated steam under pressure 0.2 atn-B.subtilis, and 0.7 atn-B. stearothermophilus with various length of exposure /sublethal conditions/. After the exposure the tests were placed in growth media. The obtained results show that the compositions of the medium in which spore-forming bacteria are grown after the exposure under sublethal conditions to saturated steam under pressure affects the recovery of the test organism. The media with glucose, tryptose and L-alanine provided the best conditions for growth.

  1. Effects of supercritical fluid extraction pressure on chemical composition, microbial population, polar lipid profile, and microstructure of goat cheese.

    Science.gov (United States)

    Sánchez-Macías, D; Laubscher, A; Castro, N; Argüello, A; Jiménez-Flores, R

    2013-03-01

    The consumer trend for healthier food choices and preferences for low-fat products has increased the interest in low-fat cheese and nutraceutical dairy products. However, consumer preference is still for delicious food. Low- and reduced-fat cheeses are not completely accepted because of their unappealing properties compared with full-fat cheeses. The method reported here provides another option to the conventional cheese-making process to obtain lower fat cheese. Using CO(2) as a supercritical fluid offers an alternative to reduce fat in cheese after ripening, while maintaining the initial characteristics and flavor. The aim of this experiment was to evaluate the effect of pressure (10, 20, 30, and 40 × 10(6) Pa) of supercritical CO(2) on the amount of fat extracted, microbial population, polar lipid profile, and microstructure of 2 varieties of goat cheese: Majorero, a protected denomination of origin cheese from Spain, and goat Gouda-type cheese. The amount of fat was reduced 50 to 57% and 48 to 55% for Majorero and goat Gouda-type cheeses, respectively. Higher contents (on a fat basis) of sphingomyelin and phosphatidylcholine were found in Majorero cheese compared with control and goat Gouda-type cheeses. The microbial population was reduced after supercritical fluid extraction in both cheeses, and the lethality was higher as pressure increased in Majorero cheese, most noticeably on lactococcus and lactobacillus bacteria. The Gouda-type cheese did not contain any lactobacilli. Micrographs obtained from confocal laser scanning microscopy showed a more open matrix and whey pockets in the Majorero control cheese. This could explain the ease of extracting fat and reducing the microbial counts in this cheese after treatment with supercritical CO(2). Supercritical fluid extraction with CO(2) has great potential in the dairy industry and in commercial applications. The Majorero cheese obtained after the supercritical fluid extraction treatment was an excellent

  2. Effect of Ovality on Maximum External Pressure of Helically Coiled Steam Generator Tubes with a Rectangular Wear

    Energy Technology Data Exchange (ETDEWEB)

    Shin, Dong In; Lim, Eun Mo; Huh, Nam Su [Seoul National Univ. of Science and Technology, Seoul (Korea, Republic of); Choi, Shin Beom; Yu, Je Yong; Kim, Ji Ho; Choi, Suhn [Korea Atomic Energy Research Institute, Daejeon (Korea, Republic of)

    2013-10-15

    A structural integrity of steam generator tubes of nuclear power plants is one of crucial parameters for safe operation of nuclear power plants. Thus, many studies have been made to provide engineering methods to assess integrity of defective tubes of commercial nuclear power plants considering its operating environments and defect characteristics. As described above, the geometric and operating conditions of steam generator tubes in integral reactor are significantly different from those of commercial reactor. Therefore, the structural integrity assessment of defective tubes of integral reactor taking into account its own operating conditions and geometric characteristics, i. e., external pressure and helically coiled shape, should be made to demonstrate compliance with the current design criteria. Also, ovality is very specific characteristics of the helically coiled tube because it is occurred during the coiling processes. The wear, occurring from FIV (Flow Induced Vibration) and so on, is main degradation of steam generator tube. In the present study, maximum external pressure of helically coiled steam generator tube with wear is predicted based on the detailed 3-dimensional finite element analysis. As for shape of wear defect, the rectangular shape is considered. In particular, the effect of ovality on the maximum external pressure of helically coiled tubes with rectangular shaped wear is investigated. In the present work, the maximum external pressure of helically coiled steam generator tube with rectangular shaped wear is investigated via detailed 3-D FE analyses. In order to cover a practical range of geometries for defective tube, the variables affecting the maximum external pressure were systematically varied. In particular, the effect of tube ovality on the maximum external pressure is evaluated. It is expected that the present results can be used as a technical backgrounds for establishing a practical structural integrity assessment guideline of

  3. Subsonic and transonic pressure measurements on a high-aspect-ratio supercritical-wing model with oscillating control surfaces

    Science.gov (United States)

    Sandford, M. C.; Ricketts, R. H.; Watson, J. J.

    1981-01-01

    A high aspect ratio supercritical wing with oscillating control surfaces is described. The semispan wing model was instrumented with 252 static orifices and 164 in situ dynamic pressure gases for studying the effects of control surface position and sinusoidal motion on steady and unsteady pressures. Data from the present test (this is the second in a series of tests on this model) were obtained in the Langley Transonic Dynamics Tunnel at Mach numbers of 0.60 and 0.78 and are presented in tabular form.

  4. Research on Key Technology of Supercritical Steam Turbine%超临界汽轮机研制的关键技术及解决策略研究

    Institute of Scientific and Technical Information of China (English)

    杨其国

    2011-01-01

    针对超临界汽轮机蒸汽参数高的运行特点,指出了汽轮机零部件高温安全问题、固体颗粒腐蚀、汽流激振以及对机组效率的更高要求等关键难点.通过开发高温材料,采用转子冷却、防汽流激振和同体颗粒腐蚀等设计技术.设计制造了超临界汽轮机,圆满地解决了以上难题,在实际运行中安全高效.也为我国自主开发更高等级机组打下坚实基础.%According to the high steam parameter of supercritical steam turbine in running, this paper indicates a series of key difficulties, such as safety of parts in high temperature condition, solid particles erosion , steam excited vibration,more higher efficiency, etc. These difficulties above were solved successfully by technologies of high temperature materials,rotor cooling, protection against steam excited vibration and solid particles erosion. This power unit has high safety and efficiency in working, lays a solid foundation for development of high parameters units by self-research in China.

  5. On the gasification of wet biomass in supercritical water : over de vergassing van natte biomassa in superkritiek water

    NARCIS (Netherlands)

    Withag, J.A.M.

    2013-01-01

    Supercritical water gasification (SCWG) is a challenging thermo-chemical conversion route for wet biomass and waste streams into hydrogen and/or methane. At temperatures and pressures above the critical point the physical properties of water differ strongly from liquid water or steam. Because of the

  6. The deterministic prediction of damage functions to low pressure steam turbines

    Energy Technology Data Exchange (ETDEWEB)

    Liu, Chun; Macdonald, D.D.

    1993-01-01

    Localized corrosion phenomena, including pitting corrosion, stress corrosion cracking, and corrosion fatigue, are the principal causes of corrosion-induced damage in electric power generating facilities and typically result in more than 50% of the unscheduled outages. Prediction of damage, so that repairs and inspections can be made during scheduled outages, could have an enormous impact on the economics of electric power generation. To date, prediction of corrosion damage has been made on the basis of empirical/statistical methods that have proven to be insufficiently robust and accurate to form the basis for the desired inspection/repair protocol. In this paper, we describe a deterministic method for predicting localized corrosion damage. We have used the method to illustrate how pitting corrosion initiates stress corrosion cracking (SCC) for low pressure steam turbine disks downstream of the Wilson line, where a thin condensed liquid layer exists on the steel disk surfaces. Our calculations show that the SCC initiation and propagation are sensitive to the oxygen content of the steam, the environment in the thin liquid condensed layer, and the stresses that the disk experiences in service.

  7. The deterministic prediction of damage functions to low pressure steam turbines

    Energy Technology Data Exchange (ETDEWEB)

    Liu, Chun; Macdonald, D.D.

    1993-06-01

    Localized corrosion phenomena, including pitting corrosion, stress corrosion cracking, and corrosion fatigue, are the principal causes of corrosion-induced damage in electric power generating facilities and typically result in more than 50% of the unscheduled outages. Prediction of damage, so that repairs and inspections can be made during scheduled outages, could have an enormous impact on the economics of electric power generation. To date, prediction of corrosion damage has been made on the basis of empirical/statistical methods that have proven to be insufficiently robust and accurate to form the basis for the desired inspection/repair protocol. In this paper, we describe a deterministic method for predicting localized corrosion damage. We have used the method to illustrate how pitting corrosion initiates stress corrosion cracking (SCC) for low pressure steam turbine disks downstream of the Wilson line, where a thin condensed liquid layer exists on the steel disk surfaces. Our calculations show that the SCC initiation and propagation are sensitive to the oxygen content of the steam, the environment in the thin liquid condensed layer, and the stresses that the disk experiences in service.

  8. The deterministic prediction of failure of low pressure steam turbine disks

    Energy Technology Data Exchange (ETDEWEB)

    Liu, Chun; Macdonald, D.D.

    1993-05-01

    Localized corrosion phenomena, including pitting corrosion, stress corrosion cracking, and corrosion fatigue, are the principal causes of corrosion-induced damage in electric power generating facilities and typically result in more than 50% of the unscheduled outages. Prediction of damage, so that repairs and inspections can be made during scheduled outages, could have an enormous impact on the economics of electric power generation. To date, prediction of corrosion damage has been made on the basis of empirical/statistical methods that have proven to be insufficiently robust and accurate to form the basis for the desired inspection/repair protocol. In this paper, we describe a deterministic method for predicting localized corrosion damage. We have used the method to illustrate how pitting corrosion initiates stress corrosion cracking (SCC) for low pressure steam turbine disks downstream of the Wilson line, where a thin condensed liquid layer exists on the steel disk surfaces. Our calculations show that the SCC initiation and propagation are sensitive to the oxygen content of the steam, the environment in the thin liquid condensed layer, and the stresses that the disk experiences in service.

  9. Supercritical fluid extraction: Application in the food industry

    Directory of Open Access Journals (Sweden)

    Skala Dejan U.

    2002-01-01

    Full Text Available Supercritical fluid extraction is an extraction process realized with supercritical fluids, which are at a temperature and pressure above their critical temperature and critical pressure. This process has shown to be very efficient one for the isolation of different substances of medium molecular weights and molecules of relatively low polarity. The solubility of more polar substances in supercritical fluids can be improved by the addition of small amounts of other polar solvents (cosolvent to the supercritical fluids, which is the main solvent in extraction process. The advantage of supercritical extraction compared to other extraction procedures (the application of classical organic solvents hydrodistillation, distillation with steam is that SFE is usually performed at moderate temperature (e.g. with SF CO2 at 40-70°C so it can be applied for the separation of different substances which are thermally unstable and have a larger vapour pressure. All of these facts indicate that SFE is of special interest for the food and pharmaceutical industry.

  10. Effects of vapor pressure/velocity and concentration on condensation heat transfer for steam-ethanol vapor mixture

    Energy Technology Data Exchange (ETDEWEB)

    Yan, Junjie; Yang, Yusen; Hu, Shenhua; Zhen, Kejian; Liu, Jiping [Xi' an Jiaotong University, State Key Laboratory of Multiphase Flow in Power Engineering, Xi' an (China)

    2007-11-15

    When a steam-ethanol vapor mixture condenses on a vertical flat plate, the form of the condensate film changes and many drops are created. This non-film condensation is called pseudo-dropwise or Marangoni condensation. This paper aims to study the main influencing factors on the Marangoni condensation of steam-ethanol vapor.The factors include the ethanol concentration, vapor pressure, vapor velocity and vapor-to-surface temperature difference. The experiments show that the heat transfer coefficient has a maximum value of approximately 42 kW/m{sup 2} K when the ethanol concentration is 1%. At the low concentrations of 0.5, 1, 5.1 and 9.8%, the condensation heat transfer is greater than for pure steam. In addition, the heat transfer for all vapor mixtures increases with both the rise of vapor pressure and vapor velocity. (orig.)

  11. Effects of vapor pressure/velocity and concentration on condensation heat transfer for steam-ethanol vapor mixture

    Science.gov (United States)

    Yan, Junjie; Yang, Yusen; Hu, Shenhua; Zhen, Kejian; Liu, Jiping

    2007-11-01

    When a steam-ethanol vapor mixture condenses on a vertical flat plate, the form of the condensate film changes and many drops are created. This non-film condensation is called pseudo-dropwise or Marangoni condensation. This paper aims to study the main influencing factors on the Marangoni condensation of steam-ethanol vapor.The factors include the ethanol concentration, vapor pressure, vapor velocity and vapor-to-surface temperature difference. The experiments show that the heat transfer coefficient has a maximum value of approximately 42 kW/m2 K when the ethanol concentration is 1%. At the low concentrations of 0.5, 1, 5.1 and 9.8%, the condensation heat transfer is greater than for pure steam. In addition, the heat transfer for all vapor mixtures increases with both the rise of vapor pressure and vapor velocity.

  12. Analysis and generalization of experimental data on heat transfer to supercritical pressure water flow in annular channels and rod bundles

    Science.gov (United States)

    Deev, V. I.; Kharitonov, V. S.; Churkin, A. N.

    2017-02-01

    Experimental data on heat transfer to supercritical pressure water presented at ISSCWR-5, 6, and 7 international symposiums—which took place in 2011-2015 in Canada, China, and Finland—and data printed in recent periodical scientific publications were analyzed. Results of experiments with annular channels and three- and four-rod bundles of heating elements positioned in square or triangular grids were examined. Methodology used for round pipes was applied at generalization of experimental data and establishing of correlations suitable for engineering analysis of heat exchange coefficient in conditions of strongly changing water properties in the near-critical pressure region. Empiric formulas describing normal heat transfer to supercritical pressure water mowing in annular channels and rod bundles were obtained. As compared to existing recommendations, suggested correlations are distinguished by specified dependency of heat exchange coefficient on density of heat flux and mass flow velocity of water near pseudo-critical temperature. Differences between computed values of heat exchange coefficient and experimental data usually do not exceed ±25%. Detailed statistical analysis of deviations between computed and experimental results at different states of supercritical pressure water flow was carried out. Peculiarities of deteriorated heat exchange were considered and their existence boundaries were defined. Experimental results obtained for these regimes were generalized using criteria by J.D. Jackson that take the influence of thermal acceleration and Archimedes forces on heat exchange processes into account. Satisfactory agreement between experimental data on heat exchange at flowing of water in annular channels and rod bundles and data for round pipes was shown.

  13. Analysis of pressure oscillations and safety relief valve vibrations in the main steam system of a Boiling Water Reactor

    Energy Technology Data Exchange (ETDEWEB)

    Galbally, David, E-mail: dgalbally@innomerics.com [Innomerics, Calle San Juan de la Cruz 2, 28223 Madrid (Spain); García, Gonzalo [Alava Ingenieros, Calle Albasanz 16, 28037 Madrid (Spain); Hernando, Jesús; Sánchez, Juan de Dios [Iberdrola, Calle Tomás Redondo 1, 28033 Madrid (Spain); Barral, Marcos [Alava Ingenieros, Calle Albasanz 16, 28037 Madrid (Spain)

    2015-11-15

    Highlights: • We analyze the vibratory response of safety relief valves in the main steam system of a Boiling Water Reactor. • We show that valve internals experience acceleration spikes of more than 20 g. • Spikes are caused by impacts between the valve disc and the seating surface of the valve nozzle. • Resonances occur at higher Strouhal numbers than those reported in the literature for tandem side branches. • Valves experience high vibration levels even for resonances caused by second order hydrodynamic modes. - Abstract: Steam flow inside the main steam lines of a Boiling Water Reactor can generate high-amplitude pressure oscillations due to coupling between the separated shear layer at the mouth of the safety relief valves (SRVs) and the acoustic modes of the side branches where the SRVs are mounted. It is known that certain combinations of flow velocities and main steam line geometries are capable of generating self-excited pressure oscillations with very high amplitudes, which can endanger the structural integrity of main steam system components, such as safety valves, or reactor internals such as steam dryers. However, main steam systems may also experience lower amplitude pressure oscillations due, for example, to coupling of higher order hydrodynamic modes with acoustic cavity modes, or to incipient resonances where the free stream velocity is slightly lower than the critical flow velocity required to develop a stable locked-on acoustic resonance. The amplitude of these pressure oscillations is typically insufficient to cause readily observable structural damage to main steam system components, but may still have subtle effects on safety relief valves. The investigation presented in this article focuses on the characterization of the response of SRVs under the effects of pressure oscillations associated with acoustic excitations that are insufficient to cause structural damage to the valves or associated equipment. It is shown that valve

  14. On synthesis and optimization of steam system networks. 3. Pressure drop consideration

    CSIR Research Space (South Africa)

    Price, T

    2010-08-01

    Full Text Available Heat exchanger networks in steam systems are traditionally designed to operate in parallel. Coetzee and Majozi (Ind. Eng. Chem. Res. 2008, 47, 4405-4413) found that by reusing steam condensate within the network the steam flow rate could be reduced...

  15. Sliding Mode Predictive Control of Main Steam Pressure in Coal-fired Power Plant Boiler

    Institute of Scientific and Technical Information of China (English)

    史元浩; 王景成; 章云锋

    2012-01-01

    Since the combustion system of coal-fired boiler in thermal power plant is characterized as time varying, strongly coupled, and nonlinear, it is hard to achieve a satisfactory performance by the conventional proportional integral derivative (PID) control scheme. For the characteristics of the main steam pressure in coal-fired power plant boiler, the sliding mode control system with Smith predictive structure is proposed to look for performance and robustness improvement. First, internal model control (IMC) and Smith predictor (SP) is used to deal with the time delay, and sliding mode controller (SMCr) is designed to overcome the model mismatch. Simulation results show the effectiveness of the proposed controller compared with conventional ones.

  16. Generation and characterization of OH and O radicals by atmospheric pressure steam/oxygen plasma

    CERN Document Server

    Roy, N C; Alam, M K; Talukder, M R

    2016-01-01

    Atmospheric pressure steam/oxygen plasma is generated by a 88 Hz, 6kV AC power supply. The properties of the produced plasma are investigated by optical emission spectroscopy (OES). The relative intensity, rotational, vibrational, excitation temperatures and electron density are studied as function of applied voltage, electrode spacing and oxygen flow rate. The rotational and vibrational temperatures are determined simulating the bands with the aid of LIFBASE simulation software. The excitation temperature is obtained from the CuI transition taking non-thermal equilibrium condition into account employing intensity ratio method. The electron density is approximated from the H_{\\alpha} Stark broadening using the Voigt profile fitting method. It is observed that the rotational and vibrational temperatures are decreased with increasing electrode spacing and O2 flow rate, but increased with the applied voltage. The excitation temperature is found to increase with increasing applied voltage and O2 flow rate, but de...

  17. EFFECT OF HIGH-PRESSURE STEAM TREATMENT ON ENZYMATIC SACCHARIFICATION OF OIL PALM EMPTY FRUIT BUNCHES

    Directory of Open Access Journals (Sweden)

    Azhari Samsu Baharuddin,

    2012-06-01

    Full Text Available The effectiveness of high-pressure steam treatment (HPST with various treatment temperatures (170, 190, 210, and 230 °C on the enzymatic hydrolysis yield of oil palm empty fruit bunches (OPEFB was successfully investigated. Analysis of the compositions of raw and treated OPEFB showed that significant changes occurred after the HPST was performed. Scanning electron microscopy (SEM analysis showed that the treated OPEFB gave better results in removing the silica bodies as compared to the untreated OPEFB. This analysis was in agreement with FTIR results, which revealed a significant decrease in the content of hemicelluloses after HPST. During saccharification, the amount of sugar produced was higher for treated OPEFB than untreated OPEFB. Thus, the results suggest that HPST can be applied as an alternative treatment method for the alteration of OPEFB structure and to enhance of the digestibility of the biomass, therefore improving enzymatic hydrolysis.

  18. Physicochemical property changes of oil palm mesocarp fibers treated with high-pressure steam

    Directory of Open Access Journals (Sweden)

    Noor Seribainun Hidayah Md Yunos

    2012-11-01

    Full Text Available High-pressure steam treatment (HPST is a potential alternative method for the modification of lignocellulosic materials. The effect of HPST on oil palm mesocarp fibers (OPMF was successfully investigated with treatment conditions of 170 ºC/ 0.82 MPa, 190 ºC/ 1.32 MPa, 210 ºC/ 2.03 MPa, and 230 ºC/ 3.00 MPa for 2 min. treatment time. Significant changes in the colour, smell, and mechanical properties of the samples were observed after the treatment. Scanning electron microscope (SEM images revealed changes in the surface morphology of the OPMF after the pretreatment. The degradation of hemicelluloses and changes in the functional groups of the lignocellulosic components were identified using Fourier Transform Infrared (FTIR and Thermogravimetric (TG analysis. These results suggest that HPST is a promising method for the pretreatment of OPMF.

  19. Experimental study of heat transfer of ultra-supercritical pressure water in vertical upward internally ribbed tube

    Institute of Scientific and Technical Information of China (English)

    Wang Weishu; Chen Tingkuan; Luo Yushan; Gu Hongfang; Yin Fei

    2007-01-01

    Under ultra-supercritical pressure, the heat transfer characteristics of water in vertical upward 4-head internally ribbed tubes with a diameter of 28.65mm and thickness of 8mm were experimentally studied.The experiments were performed at P=25~34MPa,G=450~1800kg/(m2·s)and q=200~600kW/m2. The results show that the pressure has only a moderate effect on the heat transfer of ultra-supercritical water when the water temperature is below the pseudocritical point. Sharp rise of the wall temperature near the pesudocritical region occurs earlier at a higher pressure. Increasing the mass velocity improves the heat transfer with a much stronger effect below the pesudocritical point than that above the pesudocritical point. For given pressure and mass velocity, the inner wall heat flux also shows a significant effect on the inner wall temperature, with a higher inner wall heat flux leading to a higher inner wall temperature. Increasing of inner wall heat flux leads to an early occurrence of sharp rise of the wall temperature. Correlations of heat transfer coefficients are also presented for vertical upward internally ribbed tubes.

  20. Studies of the Methane Steam Reforming Reaction at High Pressure in a Ceramic Membrane Reactor

    Institute of Scientific and Technical Information of China (English)

    P.Hacarlioglu; Y.Gu; S.T.Oyama

    2006-01-01

    The effects of temperature and pressure on the steam reforming of methane (CH4+H2O(→)3H2+CO) were investigated in a membrane reactor (MR)with a hydrogen permeable membrane. The studies used a novel silica-based membrane prepared by using the chemical vapor deposition (CVD) techreactor (PBR) were compared to those of the membrane reactor at various temperatures (773-923 K)and pressures (1-20 atm, 101.3-2026.5 kPa) using a commercial Ni/MgAl2O4 catalyst. The conversion of methane was improved significantly in the MR by the countercurrent removal of hydrogen at all temperatures and allowed product yields higher than the equilibrium to be obtained. Pressure had a positive effect on the hydrogen yield because of the increase in driving force for the permeance of hydrogen. The yield. The results obtained with the silica-based membrane were similar to those obtained with various other membranes as reported in the literature.

  1. Supercritical fluid chromatography coupled with in-source atmospheric pressure ionization hydrogen/deuterium exchange mass spectrometry for compound speciation.

    Science.gov (United States)

    Cho, Yunju; Choi, Man-Ho; Kim, Byungjoo; Kim, Sunghwan

    2016-04-29

    An experimental setup for the speciation of compounds by hydrogen/deuterium exchange (HDX) with atmospheric pressure ionization while performing chromatographic separation is presented. The proposed experimental setup combines the high performance supercritical fluid chromatography (SFC) system that can be readily used as an inlet for mass spectrometry (MS) and atmospheric pressure photo ionization (APPI) or atmospheric pressure chemical ionization (APCI) HDX. This combination overcomes the limitation of an approach using conventional liquid chromatography (LC) by minimizing the amount of deuterium solvents used for separation. In the SFC separation, supercritical CO2 was used as a major component of the mobile phase, and methanol was used as a minor co-solvent. By using deuterated methanol (CH3OD), AP HDX was achieved during SFC separation. To prove the concept, thirty one nitrogen- and/or oxygen-containing standard compounds were analyzed by SFC-AP HDX MS. The compounds were successfully speciated from the obtained SFC-MS spectra. The exchange ions were observed with as low as 1% of CH3OD in the mobile phase, and separation could be performed within approximately 20min using approximately 0.24 mL of CH3OD. The results showed that SFC separation and APPI/APCI HDX could be successfully performed using the suggested method.

  2. Performance of a pilot-scale, steam-blown, pressurized fluidized bed biomass gasifier

    Science.gov (United States)

    Sweeney, Daniel Joseph

    With the discovery of vast fossil resources, and the subsequent development of the fossil fuel and petrochemical industry, the role of biomass-based products has declined. However, concerns about the finite and decreasing amount of fossil and mineral resources, in addition to health and climate impacts of fossil resource use, have elevated interest in innovative methods for converting renewable biomass resources into products that fit our modern lifestyle. Thermal conversion through gasification is an appealing method for utilizing biomass due to its operability using a wide variety of feedstocks at a wide range of scales, the product has a variety of uses (e.g., transportation fuel production, electricity production, chemicals synthesis), and in many cases, results in significantly lower greenhouse gas emissions. In spite of the advantages of gasification, several technical hurdles have hindered its commercial development. A number of studies have focused on laboratory-scale and atmospheric biomass gasification. However, few studies have reported on pilot-scale, woody biomass gasification under pressurized conditions. The purpose of this research is an assessment of the performance of a pilot-scale, steam-blown, pressurized fluidized bed biomass gasifier. The 200 kWth fluidized bed gasifier is capable of operation using solid feedstocks at feedrates up to 65 lb/hr, bed temperatures up to 1600°F, and pressures up to 8 atm. Gasifier performance was assessed under various temperatures, pressure, and feedstock (untreated woody biomass, dark and medium torrefied biomass) conditions by measuring product gas yield and composition, residue (e.g., tar and char) production, and mass and energy conversion efficiencies. Elevated temperature and pressure, and feedstock pretreatment were shown to have a significant influence on gasifier operability, tar production, carbon conversion, and process efficiency. High-pressure and temperature gasification of dark torrefied biomass

  3. An innovative approach for Steam Generator Pressure Control of a nuclear power plant

    Energy Technology Data Exchange (ETDEWEB)

    Gaikwad, Avinash J., E-mail: avinashg@barc.gov.in [Reactor Safety Division, BARC, Trombay, Mumbai 400094 (India); Vijayan, P.K. [Reactor Engineering Divisions, BARC, Trombay, Mumbai 400094 (India); Bhartiya, Sharad [Chemical Engineering Departments, IIT, Powai, Mumbai (India); Kumar, Rajesh; Lele, H.G.; Vaze, K.K. [Reactor Safety Division, BARC, Trombay, Mumbai 400094 (India)

    2011-12-15

    Highlights: Black-Right-Pointing-Pointer Most of the transients/accidents have their origin in the mismatch among the heat generated in the reactor core and the heat removal in the SGs. Black-Right-Pointing-Pointer The main objective of balancing the heat generation, transfer and removal gets lost due to simplification of SGPC leading to reduced availability. Black-Right-Pointing-Pointer A new Advanced Process Control (APC) is proposed to ride over the existing SGPC to achieve the goal of prompt removal of the heat transfer mismatch. Black-Right-Pointing-Pointer The APC logic will lead to overall performance improvements and plant availability for all other transients also. - Abstract: The main function of the Steam Generator Pressure Control (SGPC) Program is to match the power (heat) generation in the reactor core with the heat removal in the steam generators (SGs). For most of the designs these programs have been over simplified to cater to the limitation of the instrumentation and control, hardware and software. The main objective of balancing the heat generation, transfer and removal gets lost in the process, which leads to reduction in the availability of the nuclear power plant. This is reflected in under utilization of the process and control system provisions to avoid reactor trips on low/high pressure. Most of the transients/accidents have their origin in the mismatch among the heat generated in the reactor core and the heat removal in the SGs. A new Advanced Process Control (APC) based supervisory controller is proposed to ride over the existing SGPC to achieve the goal. This APC makes use of the estimated/measured heat generation-removal error to alter the SGPC set point to tide over the transients after detection. The transients are detected based on the magnitude of this error to activate the APC. After tiding over the transient successfully the control switches back to the existing SGPC. For evaluation of this error additional instrumentation is

  4. Optimization of Steam Pressure Levels in a Total Site Using a Thermoeconomic Method

    Directory of Open Access Journals (Sweden)

    Shahin Shamsi

    2012-03-01

    Full Text Available The present study aims to develop a thermoeconomic-based approach for optimization of steam levels in a steam production and distribution system by use of the specific exergy costing (SPECO method for determining optimum steam levels to minimize the cost caused by exergy destruction. In the field of total site optimization, incremental cost of the utility system caused by exergy destruction has been selected as an objective function and the result is compared with the case that energy minimization has been selected as the prime objective. The steam levels are optimized considering steam demand at each level, output power generated by turbines, boiler duty, fuel and cold utility requirements as well as capital cost of equipments. The analysis showed that thermoeconomic (exergoeconomic approach in optimization not only can change the optimum structure of steam levels but also may reduce the total cost of utility system up to 8%.

  5. Effect of compaction pressure and powder grade on the microstructure, hardness and surface topography of steam oxidized sintered iron

    Energy Technology Data Exchange (ETDEWEB)

    Mello, J.D.B. de; Hutchings, I.M. [Univ. of Cambridge (United Kingdom); Binder, R. [Embraco, Joinville, S.C. (Brazil); Klein, A.N. [Labmat, UFSC, Florianopolis, S.C. (Brazil)

    2000-07-01

    Steam oxidation has proved to be an effective process to improve the properties of sintered iron components. The wear processes of such surfaces might be expected to be influenced by the presence of pores, the extent of pore closure and the nature and morphology of the oxide produced. In this paper, the influence of compaction pressure and powder grade on the microstructure, oxide content, hardness and surface topography of steam treated sintered iron is analysed. Specimens prepared from atomised powders in different sizes were compacted using 4 different pressure, sintered and then subjected to a continuous steam treatment. A clear influence of the processing parameters on porosity was highlighted. Low porosity is always associated with high compaction pressure and greater powder size. Decreasing powder size always leads to high hardness. Samples produced with smaller powder size show a continuous decrease in hardness as the compaction pressure increases although for the large powder size there is a slight increase to a constant value of ultimate hardness. For the intermediate grain size a maximum hardness is obtained as the compaction pressure increases. X-ray diffraction shows that the oxide layer is composed of magnetite and haematite. No general correlation was found between topographic features, examined using vertical scanning interferometry, and processing parameters or microstructure. (orig.)

  6. Mineral Carbonation in Wet Supercritical CO2: An in situ High-Pressure Magic Angle Spinning Nuclear Magnetic Resonance Study

    Science.gov (United States)

    Turcu, R. V.; Hoyt, D. H.; Sears, J. A.; Rosso, K. M.; Felmy, A. R.; Hu, J. Z.

    2011-12-01

    Understanding the mechanisms and kinetics of mineral carbonation reactions relevant to sequestering carbon dioxide as a supercritical fluid (scCO2) in geologic formations is crucial for accurately predicting long-term storage risks. In situ probes that provide molecular-level information at geologically relevant temperatures and pressures are highly desirable and challenging to develop. Magic angle spinning nuclear magnetic resonance (MAS NMR) is a powerful tool for obtaining detailed molecular structure and dynamics information of a system regardless whether the system is in a solid, a liquid, a gaseous, a supercritical state, or a mixture thereof. However, MAS NMR under scCO2 conditions has never been realized due to the tremendous technical difficulties of achieving and maintaining high pressure within a fast spinning MAS sample rotor. In this work, we report development of a unique high pressure MAS NMR capability capable of handling fluid pressure exceeding 170 bars and temperatures up to 80°C, and its application to mineral carbonation in scCO2 under geologically relevant temperatures and pressures. Mineral carbonation reactions of the magnesium silicate mineral forsterite and the magnesium hydroxide brucite reacted with scCO2 (up to 170 bar) and containing variable content of H2O (at, below, and above saturation in scCO2) were investigated at 50 to 70°C. In situ 13C MAS NMR spectra show peaks corresponding to the reactants, intermediates, and the magnesium carbonation products in a single spectrum. For example, Figure 1 shows the reaction dynamics, i.e., the formation and conversion of reaction intermediates, i.e., HCO3- and nesquehonite, to magnesite as a function of time at 70°C. This capability offers a significant advantage over traditional ex situ 13C MAS experiments on similar systems, where, for example, CO2 and HCO3- are not directly observable.

  7. An Isothermal Steam Expander for an Industrial Steam Supplying System

    Directory of Open Access Journals (Sweden)

    Chen-Kuang Lin

    2015-01-01

    Full Text Available Steam is an essential medium used in the industrial process. To ensure steam quality, small and middle scale boilers are often adopted. However, because a higher steam pressure (compared to the necessary steam pressure is generated, the boiler’s steam pressure will be reduced via a pressure regulator before the steam is directed through the process. Unfortunately, pressure is somewhat wasted during the reducing process. Therefore, in order to promote energy efficiency, a pressure regulator is replaced by a steam expander. With this steam expander, the pressure will be transformed into mechanical energy and extracted during the expansion process. A new type of isothermal steam expander for an industrial steam supplying system will be presented in the paper. The isothermal steam expander will improve the energy efficiency of a traditional steam expander by replacing the isentropic process with an isothermal expansion process. With this, steam condensation will decrease, energy will increase, and steam quality will be improved. Moreover, the mathematical model of the isothermal steam expander will be established by using the Schmidt theory, the same principle used to analyze Stirling engines. Consequently, by verifying the correctness of the theoretical model for the isothermal steam expander using experimental data, a prototype of 100 c.c. isothermal steam expander is constructed.

  8. Thermal-Conductivity Measurements of Aviation Kerosene RP-3 from (285 to 513) K at Sub- and Supercritical Pressures

    Science.gov (United States)

    Xu, G. Q.; Jia, Z. X.; Wen, J.; Deng, H. W.; Fu, Y. C.

    2015-04-01

    The thermal conductivity of a representative endothermic hydrocarbon aviation kerosene fuel RP-3 was accurately measured using the classical transient hot-wire method at sub- and supercritical pressures. The measured data cover a temperature range of 285 K to 513 K and a pressure range of 0.1 MPa to 5 MPa. The expanded uncertainty of the experiment was less than 3.0 % based on an uncertainty analysis. Furthermore, the measured data were correlated using a polynomial equation to analyze the deviations; 97.6 % of the measured data were within a 2 % error band. The average absolute deviation ( AAD) and maximum absolute deviation ( MAD) of the fitted thermal-conductivity data were 0.209 % and 2.31 % for all values, respectively.

  9. Valve Assembly Technology of 660 MW Ultra-supercritical Double-reheat Steam Turbine%660 MW超超临界二次再热汽轮机阀门装配技术

    Institute of Scientific and Technical Information of China (English)

    张桂明; 胡开吉

    2016-01-01

    文章就公司自主开发的660 MW二次再热机组的阀门装配技术进行介绍。针对阀门的结构特点,详细介绍了其装配工艺流程、阀芯及阀盖部件的安装,文章内容将为同类型阀门的安装提供有益的借鉴。%This paper introduced the valve assembly technology of 660 MW ultra-supercritical double-reheat steam turbine indepen⁃dent researched and developed by Dongfang Turbine Co.,Ltd.(abbreviate DTC). For the valve design feature, the valve assembly pro⁃cess,valve core and valve seat installation were detailedly introduced. The paper can provide helpful reference for homotype valve as⁃sembly.

  10. Determination of Minimum Miscibility Pressure in supercritical extractor using oil saturated sample

    DEFF Research Database (Denmark)

    Rudyk, Svetlana Nikolayevna; Søgaard, Erik Gydesen; Abbasi, Waqas A.

    2009-01-01

    , in order to investigate the MMP, we suggest another method by using a supercritical extractor. Spe-ed SFE equipment with oil saturated natural rock samples were used for the purpose. The clean chalk samples were saturated with oil from the Dan field under vacuum. The CO2 gas was injected into the extractor...... the breakover point criterion the MMP read from the plot was found equal to 20 MPa.  ...

  11. Intelligent coordinated control of power-plant main steam pressure and power output

    Institute of Scientific and Technical Information of China (English)

    刘红波; 李少远; 柴天佑

    2004-01-01

    An intelligent coordinated control strategy has been proposed and successfully applied to a 300MW boiler-turbine unit i.e. Unit 1 of Yuanbaoshan power plant in China. Load following operation of coal-fired boiler-turbine unit in the power plant leads to changes in operating points which result in nonlinear variations of the plant variables and parameters. For the variation of operating condition and slowly varying dynamics, an intelligent control scheme has been developed by combining fuzzy self-tuning with adaptive control and auto-tuning techniques. As there exist strong couplings between control loops of main steam pressure and power output in the unit, a new design for static decoupler aimed at decoupling for setpoints and unmeasured pulverized coal disturbance of the system at the same time is presented. Satisfactory industrial application results show that such a control system has enhanced adaptability and robustness to the complex process, and better control performance and high economic benefit have been obtained.

  12. COMPARISONS OF SOXHLET EXTRACTION, PRESSURIZED LIQUID EXTRACTION, SUPERCRITICAL FLUID EXTRACTION, AND SUBCRITICAL WATER EXTRACTION FOR ENVIRONMENTAL SOLIDS: RECOVERY, SELECTIVITY, AND EFFECTS ON SAMPLE MATRIX. (R825394)

    Science.gov (United States)

    Extractions of a polycyclic aromatic hydrocarbon (PAH)-contaminated soil from a former manufactured gas plant site were performed with a Soxhlet apparatus (18 h), by pressurized liquid extraction (PLE) (50 min at 100°C), supercritical fluid extraction (SFE) (1 h at 150°...

  13. Application of GC–MS chromatography for the analysis of the oil fractions extracted by supercritical CO2 at high pressure

    DEFF Research Database (Denmark)

    Rudyk, Svetlana Nikolayevna; Spirov, Pavel; Søgaard, Erik Gydesen

    2013-01-01

    GC–MS chromatographic analysis has been applied for the investigation of the fractions of oil extracted by supercritical carbon dioxide at a temperature of 60 °C and at pressure values ranging from 22 to 56 MPa. The observations revealed, that the whole extraction process is clearly reflected...... of the chromatographic method for the quantitative evaluation of oil recovery. --------------------------------------------------------------------------------...

  14. COMPARISONS OF SOXHLET EXTRACTION, PRESSURIZED LIQUID EXTRACTION, SUPERCRITICAL FLUID EXTRACTION, AND SUBCRITICAL WATER EXTRACTION FOR ENVIRONMENTAL SOLIDS: RECOVERY, SELECTIVITY, AND EFFECTS ON SAMPLE MATRIX. (R825394)

    Science.gov (United States)

    Extractions of a polycyclic aromatic hydrocarbon (PAH)-contaminated soil from a former manufactured gas plant site were performed with a Soxhlet apparatus (18 h), by pressurized liquid extraction (PLE) (50 min at 100°C), supercritical fluid extraction (SFE) (1 h at 150°...

  15. Substantial rate enhancements of the esterification reaction of phthalic anhydride with methanol at high pressure and using supercritical CO2 as a co-solvent in a glass microreactor

    NARCIS (Netherlands)

    Benito-Lopez, F.; Tiggelaar, Roald M.; Salblut, K.; Huskens, Jurriaan; Egberink, Richard J.M.; Reinhoudt, David; Gardeniers, Johannes G.E.; Verboom, Willem

    2007-01-01

    The esterification reaction of phthalic anhydride with methanol was performed at different temperatures in a continuous flow glass microreactor at pressures up to 110 bar and using supercritical CO2 as a co-solvent. The design is such that supercritical CO2 can be generated inside the microreactor.

  16. Field test of two high-pressure, direct-contact downhole steam generators. Volume I. Air/diesel system

    Energy Technology Data Exchange (ETDEWEB)

    Marshall, B.W.

    1983-05-01

    As a part of the Project DEEP STEAM to develop technology to more efficiently utilize steam for the recovery of heavy oil from deep reservoirs, a field test of a downhole steam generator (DSG) was performed. The DSG burned No. 2 diesel fuel in air and was a direct-contact, high pressure device which mixed the steam with the combustion products and injected the resulting mixture directly into the oil reservoir. The objectives of the test program included demonstration of long-term operation of a DSG, development of operational methods, assessment of the effects of the steam/combustion gases on the reservoir and comparison of this air/diesel DSG with an adjacent oxygen/diesel direct contact generator. Downhole operation of the air/diesel DSG was started in June 1981 and was terminated in late February 1982. During this period two units were placed downhole with the first operating for about 20 days. It was removed, the support systems were slightly modified, and the second one was operated for 106 days. During this latter interval the generator operated for 70% of the time with surface air compressor problems the primary source of the down time. Thermal contact, as evidenced by a temperature increase in the production well casing gases, and an oil production increase were measured in one of the four wells in the air/diesel pattern. Reservoir scrubbing of carbon monoxide was observed, but no conclusive data on scrubbing of SO/sub x/ and NO/sub x/ were obtained. Corrosion of the DSG combustor walls and some other parts of the downhole package were noted. Metallurgical studies have been completed and recommendations made for other materials that are expected to better withstand the downhole combustion environment. 39 figures, 8 tables.

  17. Field test of two high-pressure direct-contact downhole steam generators. Volume II. Oxygen/diesel system

    Energy Technology Data Exchange (ETDEWEB)

    Moreno, J.B.

    1983-07-01

    A field test of an oxygen/diesel fuel, direct contact steam generator has been completed. The field test, which was a part of Project DEEP STEAM and was sponsored by the US Department of Energy, involved the thermal stimulation of a well pattern in the Tar Zone of the Wilmington Oil Field. The activity was carried out in cooperation with the City of Long Beach and the Long Beach Oil Development Company. The steam generator was operated at ground level, with the steam and combustion products delivered to the reservoir through 2022 feet of calcium-silicate insulated tubing. The objectives of the test included demonstrations of safety, operational ease, reliability and lifetime; investigations of reservoir response, environmental impact, and economics; and comparison of those points with a second generator that used air rather than oxygen. The test was extensively instrumented to provide the required data. Excluding interruptions not attributable to the oxygen/diesel system, steam was injected 78% of the time. System lifetime was limited by the combustor, which required some parts replacement every 2 to 3 weeks. For the conditions of this particular test, the use of trucked-in LOX resulted in liess expense than did the production of the equivalent amount of high pressure air using on site compressors. No statistically significant production change in the eight-acre oxygen system well pattern occurred during the test, nor were any adverse effects on the reservoir character detected. Gas analyses during the field test showed very low levels of SOX (less than or equal to 1 ppM) in the generator gaseous effluent. The SOX and NOX data did not permit any conclusion to be drawn regarding reservoir scrubbing. Appreciable levels of CO (less than or equal to 5%) were measured at the generator, and in this case produced-gas analyses showed evidence of significant gas scrubbing. 64 figures, 10 tables.

  18. Transonic steady- and unsteady-pressure measurements on a high-aspect-ratio supercritical-wing model with oscillating control surfaces

    Science.gov (United States)

    Sandford, M. C.; Ricketts, R. H.; Cazier, F. W., Jr.

    1980-01-01

    A supercritical wing with an aspect ratio of 10.76 and with two trailing-edge oscillating control surfaces is described. The semispan wing is instrumented with 252 static orifices and 164 in situ dynamic-pressure gages for studying the effects of control-surface position and motion on steady- and unsteady-pressures at transonic speeds. Results from initial tests conducted in the Langley Transonic Dynamics Tunnel at two Reynolds numbers are presented in tabular form.

  19. High Pressure Vapor-Liquid Equilibrium of Supercritical Carbon Dioxide + n-Hexane System

    Institute of Scientific and Technical Information of China (English)

    YU Jinglin; TIAN Yiling; ZHU Rongjiao; LIU Zhihua

    2006-01-01

    Vapor-liquid equilibrium data of supercritical carbon dioxide + n-hexane system were measured at 313.15 K,333.15 K,353.15 K,and 373.15 K and their molar volumes and densities were measured both in the subcritical and supercritical regions ranging from 2.15 to 12.63 MPa using a variable-volume autoclave.The thermodynamic properties including mole fractions,densities,and molar volumes of the system were calculated with an equation of state by Heilig and Franck,in which a repulsion term and a square-well potential attraction term for intermolecular interaction was used.The pairwise combination rule was used to calculate the square-well molecular interaction potential and three adjustable parameters (ω,kε,kσ) were obtained.The Heilig-Franck equation of state is found to have good correlation with binary vapor-liquid equilibrium data of the carbon dioxide + n-hexane system.

  20. Short-time Oxidation of Alloy 690 in High-temperature and High-pressure Steam and Water

    Institute of Scientific and Technical Information of China (English)

    F. Huang; J.Q. Wang; E.H. Han; W. Ke

    2012-01-01

    The oxidation behavior of alloy 690 exposed to high-temperature and high-pressure steam and water at 280℃ for 1 h was investigated by scanning electron microscopy (SEM), atomic force microscopy (AFM) and X-ray photoelectron spectroscopy (XPS). In high-temperature and high-pressure steam, the oxide film is composed of an outermost Ni-rich hydroxides layer, an intermediate layer of hydroxides and oxides enriched in Cr, an inner oxide layer. The film formed in high-temperature water is similar to that in steam, except for missing the Ni-rich hydroxides layer. Samples with different surface finishes (electropolished, mechanically polished, ground, and as-received) were prepared for comparison. A general increase of the oxide thickness with the degree of surface roughness is observed. The equivalent oxide thicknesses lie in the range of 100-200 nm for the as-received samples, 150-250 nm for the samples ground to 400# and 10-20 nm for the samples ground to 1500#, mechanically polished, and electropolished.

  1. The Recovery and Power Generation Technology for Low Pressure Exhaust Steam%低压放散蒸汽回收发电技术

    Institute of Scientific and Technical Information of China (English)

    戴海波

    2015-01-01

    对钢铁企业低压饱和蒸汽管网运行情况进行研究,分析总结低压低温饱和的间断性放散蒸汽放散规律,通过放散蒸汽的有效回收,并利用螺杆膨胀机发电技术,形成低压饱和蒸汽资源化和再利用的项目方案。%The operation state of low pressure saturated steam pipeline networks of steel enterprises was investigated and the pattern of intermittent exhausting of low-pressure low-temperature saturated steam was analyzed. Through effective recovery of the exhaust steam and adopting of the power generation technology of screw expander, a project plan for recy-cling and utilization of low pressure saturated steam was drawn up.

  2. [On the importance of the steam trap to the efficient sterilization of solutions in stored blood bottles by saturated steam under pressure (author's transl)].

    Science.gov (United States)

    Schreiber, M; Göbel, M

    1979-01-01

    Biological tests with soil samples were performed to fix the sterilization time for a new steam sterilizer. These tests yielded repeatedly positive spore findings despite modifications of the conditions of sterilization. Having excluded a series of possible sources of trouble, the authors stated that the quality of the steam was the assignable cause. After restoration of the functionality of the steam traps, the biological tests yielded negative results also under normal conditions of sterilization.

  3. Numerical Study on the Heat Transfer of Carbon Dioxide in Horizontal Straight Tubes under Supercritical Pressure.

    Directory of Open Access Journals (Sweden)

    Mei Yang

    Full Text Available Cooling heat transfer of supercritical CO2 in horizontal straight tubes with wall is numerically investigated by using FLUENT. The results show that almost all models are able to present the trend of heat transfer qualitatively, and the stand k-ε with enhanced wall treatment model shows the best agreement with the experimental data, followed by LB low Re turbulence model. Then further studies are discussed on velocity, temperature and turbulence distributions. The parameters which are defined as the criterion of buoyancy effect on convection heat transfer are introduced to judge the condition of the fluid. The relationships among the inlet temperature, outlet temperature, the mass flow rate, the heat flux and the diameter are discussed and the difference between the cooling and heating of CO2 are compared.

  4. Numerical Study on the Heat Transfer of Carbon Dioxide in Horizontal Straight Tubes under Supercritical Pressure.

    Science.gov (United States)

    Yang, Mei

    2016-01-01

    Cooling heat transfer of supercritical CO2 in horizontal straight tubes with wall is numerically investigated by using FLUENT. The results show that almost all models are able to present the trend of heat transfer qualitatively, and the stand k-ε with enhanced wall treatment model shows the best agreement with the experimental data, followed by LB low Re turbulence model. Then further studies are discussed on velocity, temperature and turbulence distributions. The parameters which are defined as the criterion of buoyancy effect on convection heat transfer are introduced to judge the condition of the fluid. The relationships among the inlet temperature, outlet temperature, the mass flow rate, the heat flux and the diameter are discussed and the difference between the cooling and heating of CO2 are compared.

  5. Supercritical water

    CERN Document Server

    Marcus, Yizhak

    2012-01-01

    Discover the many new and emerging applications of supercritical water as a green solvent Drawing from thousands of original research articles, this book reviews and summarizes what is currently known about the properties and uses of supercritical water. In particular, it focuses on new and emerging applications of supercritical water as a green solvent, including the catalytic conversion of biomass into fuels and the oxidation of hazardous materials. Supercritical Water begins with an introduction that defines supercritical fluids in general. It then defines supercritical wa

  6. Ionic Effects on Supercritical CO2-Brine Interfacial Tensions: Molecular Dynamics Simulations and a Universal Correlation with Ionic Strength, Temperature, and Pressure.

    Science.gov (United States)

    Zhao, Lingling; Ji, Jiayuan; Tao, Lu; Lin, Shangchao

    2016-09-13

    For geological CO2 storage in deep saline aquifers, the interfacial tension (IFT) between supercritical CO2 and brine is critical for the storage security and design of the storage capacitance. However, currently, no predictive model exists to determine the IFT of supercritical CO2 against complex electrolyte solutions involving various mixed salt species at different concentrations and compositions. In this paper, we use molecular dynamics (MD) simulations to investigate the effect of salt ions on the incremental IFT at the supercritical CO2-brine interface with respect to that at the reference supercritical CO2-water interface. Supercritical CO2-NaCl solution, CO2-CaCl2 solution and CO2-(NaCl+CaCl2) mixed solution systems are simulated at 343 K and 20 MPa under different salinities and salt compositions. We find that the valence of the cations is the primary contributor to the variation in IFT, while the Lennard-Jones potentials for the cations pose a smaller impact on the IFT. Interestingly, the incremental IFT exhibits a general linear correlation with the ionic strength in the above three electrolyte systems, and the slopes are almost identical and independent of the solution types. Based on this finding, a universal predictive formula for IFTs of CO2-complex electrolyte solution systems is established, as a function of ionic strength, temperature, and pressure. The predicted IFTs using the established formula agree perfectly (with a high statistical confidence level of ∼96%) with a wide range of experimental data for CO2 interfacing with different electrolyte solutions, such as those involving MgCl2 and Na2SO4. This work provides an efficient and accurate route to directly predict IFTs in supercritical CO2-complex electrolyte solution systems for practical engineering applications, such as geological CO2 sequestration in deep saline aquifers and other interfacial systems involving complex electrolyte solutions.

  7. Effect of Powder Type and Compaction Pressure on the Density, Hardness and Oxidation Resistance of Sintered and Steam-treated Steels

    Science.gov (United States)

    Wang, Wen-Fung

    2007-10-01

    Two types of Hoganas iron powders—sponge (NC), and highly compressible (SC) were investigated. These specimens were compacted with a pressure of 300, 400, 500, 600, and 700 MPa, before sintering in a production belt-type furnace. Steam treatment of the specimens was at 570 °C for 30 min. The sintered density and as-sintered hardness increase with increasing compaction pressure, and are significantly influenced by the powder structural characteristics. During steam treatment the type of powder and compaction pressure have an important influence on the extent of pore closure and weight gain. The maximum hardness was obtained for the components compacted at a pressure of 500 MPa for both groups of iron powders. Surface pore closure and oxidation resistance of the steam-treated components are improved with increasing compaction pressure.

  8. Niederaussem电站1000MW超临界汽轮机%1000 MW Supercritical Steam Turbine for the Niederaussem Plant

    Institute of Scientific and Technical Information of China (English)

    Wilfried Ulm; Dale Ernette; John Kern; Ralf M. Bell

    2003-01-01

    本文对Niederaussem K电站汽轮机的初始运行情况展开讨论,并对已使用的最新技术进行了详细的论述.%This paper will discuss the details of this latest technology as well as the initial operating experience of the Niederaussem K steam turbine.

  9. 低压蒸汽节能回收改造总结%Sum-Up of Renovation of Energy Saving and Recovery of Low-Pressure Steam

    Institute of Scientific and Technical Information of China (English)

    马飞跃; 陈隆

    2015-01-01

    Due to design flaws,there is an unbalanced byproduct low-pressure steam from waste heat boiler,and the surplus low-pressure steam has to vent directly.In order to reduce energy consumption and save production cost,the surplus low-pressure steam is used to drive steam turbine, and steam turbine drives circulating water pump,and the excess energy is used to generate electricity. The implementation of technological renovation measures,not only has recovered and utilized surplus low-pressure steam,but also has significant economic benefit.%由于设计上的缺陷,导致废热锅炉副产的低压蒸汽不平衡,富余的低压蒸汽只能直接放空。为了降低能耗、节约生产成本,采用富余的低压蒸汽作为汽轮机的动能,由汽轮机拖动循环水泵,多余的能量用于发电。改造措施实施后,不仅回收利用了富余的低压蒸汽,而且具有明显的经济效益。

  10. Neural Network Internal Model Control for Superheated Steam Temperature of Supercritical Boiler Unit%超临界锅炉过热汽温神经网络内模控制

    Institute of Scientific and Technical Information of China (English)

    马良玉; 冯谦; 易祖耀

    2013-01-01

    锅炉过热汽温是燃煤机组运行中的重要参数,过高、过低都会对机组的安全经济运行构成威胁.由于锅炉结构复杂,系统庞大,汽温对象具有变时滞、变参数等特性,喷水减温系统采用的串级PID控制,在大范围变工况下效果往往很不理想,且PID参数整定耗时耗力.为此,该文针对600 MW超临界锅炉过热器的喷水减温系统,研究了过热汽温神经网络(ANN)内模控制方案.基于Matlab建立了汽温系统的ANN正模型和逆模型,并设计出ANN内模实时控制器.仿真表明,与原串级PID控制相比,该方案显著改善了过热汽温的控制品质.%Boiler SST was an important parameter closely related to the safe and economic operation of a coal-fired power plant. Superheated steam temperature either too high or too low will pose a threat on the operation safety and economy. Because the boiler superheater system was relatively complex with large delay,large inertia and higher non-linearity, satisfactory control effects can often not be obtained with conventional cascade PID control scheme at wide operating range. Retuning of the PID parameters was often a time-consuming and labor-intensive work. For this reason, a neural network IMC scheme was studied for the two-stage desuperheating system of a 600 MW supercritical boiler unit, studying the system with the method based on superheated steam temperature control scheme. The neural network direct models and inverse models of the superheater system are built and trained with MATLAB software. Then neural network model based IMC controllers for the superheated steam temperature were designed,programmed and tested with a full-scope power plant simulator. It was shown that the neural network IMC scheme can significantly improve the superheated steam temperature control quality compared to the original cascade PID control.

  11. Structural and Phase State of Fractured Rotor of High-Pressure Steam Turbine

    Science.gov (United States)

    Smirnov, A. N.; Ababkov, N. V.; Kozlov, E. V.; Koneva, N. A.; Popova, N. A.

    2016-03-01

    The structural and phase state of the metal of a fractured rotor of a steam turbine is studied with the use of modern methods of physical research. The metal is shown to contain gradient structures. The cause of the failure of the rotor is established. The gradient structures are determined by the developed method of acoustic scanning.

  12. Method for growth of crystals by pressure reduction of supercritical or subcritical solution

    Science.gov (United States)

    Shlichta, P. J. (Inventor)

    1985-01-01

    Crystals of high morphological quality are grown by dissolution of a substance to be grown into the crystal in a suitable solvent under high pressure, and by subsequent slow, time-controlled reduction of the pressure of the resulting solution. During the reduction of the pressure interchange of heat between the solution and the environment is minimized by performing the pressure reduction either under isothermal or adiabatic conditions.

  13. Pressurized solvent extraction of environmental organic compounds in soils using a supercritical fluid extractor

    Energy Technology Data Exchange (ETDEWEB)

    Li, K.; Landriault, M.; Fingas, M. [Emergencies Science Division, Environmement Canada, Environment Technology Centre, Ontario (Canada); Llompart, M. [Universidad de Santiago de Compostela (Spain). Dept. de Quimica Analitica, Nutricieon y bromatologia, Facultad de Quimica

    1998-11-01

    The applicability of pressurised solvent extraction (PSE) for the quantitative extraction of different of semi-volatiles, including polycyclic aromatic hydrocarbons (PAHs), phenols, polychlorinated biphenyls (PCBs) and total petroleum hydrocarbons have been evaluated. For this study a conventional supercritical fluid extraction (SFE) system, the Suprex SFE/50 was adapted to function as a pressurised solvent extraction system. Solid samples were weighed into the SFE thimble and extracted using conventional extraction solvents instead of superficial carbon dioxide. Parameters such as extraction temperature and effect of modifiers were investigated. Although limited by the 150 deg. C maximum oven temperature, it was found effective extraction could still be carried out in less than 25 min for all the compounds studied. The technique was applied to different real matrices contaminated with hydrocarbons, PAHs and phenols. Validations of the technique were performed using standard reference materials. Recoveries for these matrices were good (> 75 %) and precision was generally less than a 10 % RSD. Extensive comparison of this technique with sonication and with microwave assisted extraction (MAE) were made, and recoveries were found to be comparable to MAE and superior to sonication. (authors) 15 refs.

  14. Steady- and unsteady-pressure measurements on a supercritical-wing model with oscillating control surfaces at subsonic and transonic speeds

    Science.gov (United States)

    Sandford, M. C.; Ricketts, R. H.

    1983-01-01

    A high aspect ratio supercritical wing with oscillating control surfaces is described. The semispan wing model was instrumented with 252 static pressure orifices and 164 in situ dynamic pressure gages for studying the effects of control surface position and sinusoidal motion on steady and unsteady pressures. Results from the present test (the third in a series of tests on this model) were obtained in the Langley Transonic Dynamics Tunnel at Mach numbers of 0.60, 0.78, and 0.86 and are presented in tabular form.

  15. Corrosion Analysis of Low Pressure Steam Turbine%某汽轮机低压缸腐蚀分析

    Institute of Scientific and Technical Information of China (English)

    徐洪; 张建国; 杨贤彪

    2011-01-01

    The case of erosion/corrosion damage occurring in a low pressure steam turbine was evaluated. This fossil power unit had been put into operation for nearly twenty years, and the used ion exchange resins for water treatment had never been scrapped. The leaked organism of aged ion exchange resins was decomposed into corrosive irons in the water-steam cycle. The action of enriched corrosion irons in the primary condensate water with the water steam made a severe erosion/corrosion of the low pressure turbine. It is important to detect the contents of corrosion irons and displace aged ion exchange resins in time.%对某汽轮机低压缸的腐蚀一磨蚀案例进行了研究.该火电机组投运近20年,从未对补给水处理系统的离子交换树脂进行过报废处理.老化的树脂产生大量有机溶出物,随补给水进入热力系统,受热分解为乙酸根、硫酸根等腐蚀性离子.这些腐蚀性离子在初凝水中富集使其呈酸性,与湿蒸汽共同冲刷腐蚀低压缸内壁,导致严重腐蚀.采用离子色谱仪监测水汽中腐蚀性离子含量,及时报废老化的离子交换树脂,对预防低压缸腐蚀十分必要.

  16. Structural Transition in Supercritical Fluids

    Directory of Open Access Journals (Sweden)

    Boris I. Sedunov

    2011-01-01

    Full Text Available The extension of the saturation curve ( on the PT diagram in the supercritical region for a number of monocomponent supercritical fluids by peak values for different thermophysical properties, such as heat capacities and and compressibility has been studied. These peaks signal about some sort of fluid structural transition in the supercritical region. Different methods give similar but progressively diverging curves st( for this transition. The zone of temperatures and pressures near these curves can be named as the zone of the fluid structural transition. The outstanding properties of supercritical fluids in this zone help to understand the physical sense of the fluid structural transition.

  17. Kinetics of hydrothermal crystallization under saturated steam pressure and the self-healing effect by nanocrystallite for hydroxyapatite coatings.

    Science.gov (United States)

    Yang, Chung-Wei; Lui, Truan-Sheng

    2009-09-01

    Hydroxyapatite coatings (HACs) with a low crystalline state were prepared using the plasma spraying process followed by hermetic autoclaving hydrothermal treatment at 100, 150 and 200 degrees C. Experimental evidence confirmed that the HACs became significantly crystallized and the content of amorphous calcium phosphate decreased by performing the autoclaving hydrothermal treatment in an ambient saturated steam pressure system. The obvious chemisorbed hydroxy groups (OH) peak in the X-ray photoelectron spectra detected from the hydrothermally crystallized HAC specimens means that the hydroxyl-deficient state of plasma-sprayed HACs is significantly improved by the abundant replenished OH groups. The HA nanocrystallite observed from scanning electron microscopy and transmission electron microscopy images within hydrothermally treated HACs is the result of nucleation and grain growth through the replenishment of OH groups into the hydroxyl-deficient HA crystal structure. The microstructural self-healing effect is a result of reduction in defects (pores, microcracks and lamellar boundaries) due to new-growth HA nanocrystallite. According to the systematic derivation of the Arrhenius equation, the HA crystallization is a second-order Arrhenius reaction kinetics. Besides the effects of heating temperature and an atmosphere with abundant water molecules, the saturated steam pressure is a crucial factor which significantly improves the crystallization rate constant and further reduces the activation energy for the hydrothermal HA crystallization.

  18. Hydrogen production from high-moisture content biomass in supercritical water

    Energy Technology Data Exchange (ETDEWEB)

    Antal, M.J. Jr.; Adschiri, T.; Ekbom, T. [Univ. of Hawaii, Honolulu, HI (United States)] [and others

    1996-10-01

    Most hydrogen is produced by steam reforming methane at elevated pressures. The goal of this research is to develop commercial processes for the catalytic steam reforming of biomass and other organic wastes at high pressures. This approach avoids the high cost of gas compression and takes advantage of the unique properties of water at high pressures. Prior to this year the authors reported the ability of carbon to catalyze the decomposition of biomass and related model compounds in supercritical water. The product gas consists of hydrogen, carbon dioxide, carbon monoxide, methane, and traces of higher hydrocarbons. During the past year the authors have: (a) developed a method to extend the catalyst life, (b) begun studies of the role of the shift reaction, (c) completed studies of carbon dioxide absorption from the product effluent by high pressure water, (d) measured the rate of carbon catalyst gasification in supercritical water, (e) discovered the pumpability of oil-biomass slurries, and (f) completed the design and begun fabrication of a flow reactor that will steam reform whole biomass feedstocks (i.e. sewage sludge) and produce a hydrogen rich synthesis gas at very high pressure (>22 MPa).

  19. Investigation of temperature fluctuation phenomena in a stratified steam-water two-phase flow in a simulating pressurizer spray pipe of a pressurized water reactor

    Energy Technology Data Exchange (ETDEWEB)

    Miyoshi, Koji, E-mail: miyoshi.koj@inss.co.jp; Takenaka, Nobuyuki; Ishida, Taisuke; Sugimoto, Katsumi

    2017-05-15

    Highlights: • Thermal hydraulics phenomena were discussed in a spray pipe of pressurizer. • Temperature fluctuation was investigated in a stratified steam-water two-phase. • Remarkable liquid temperature fluctuations were observed in the liquid layer. • The observed temperature fluctuations were caused by the internal gravity wave. • The temperature fluctuations decreased with increasing dissolved oxygen. - Abstract: Temperature fluctuation phenomena in a stratified steam-water two-phase flow in a horizontal rectangular duct, which simulate a pressurizer spray pipe of a pressurized water reactor, were studied experimentally. Vertical distributions of the temperature and the liquid velocity were measured with water of various dissolved oxygen concentrations. Large liquid temperature fluctuations were observed when the water was deaerated well and dissolved oxygen concentration was around 10 ppb. The large temperature fluctuations were not observed when the oxygen concentration was higher. It was shown that the observed temperature fluctuations were caused by the internal gravity wave since the Richardson numbers were larger than 0.25 and the temperature fluctuation frequencies were around the Brunt-Väisälä frequencies in the present experimental conditions. The temperature fluctuations decreased by the non-condensable gas since the non-condensable gas suppressed the condensation and the temperature difference in the liquid layer was small.

  20. Accelerated growth of oxide film on aluminium alloys under steam: Part I: Effects of alloy chemistry and steam vapour pressure on microstructure

    DEFF Research Database (Denmark)

    Din, Rameez Ud; Gudla, Visweswara C.; Jellesen, Morten S.;

    2015-01-01

    at the top. The kinetics of formation of film understeamwas rapid; approx. 350nm thick layers were generated within 5 s of steam treatment, however increase in thickness of the oxide retarded further growth. The enrichment or depletion of different alloying elements at the surface of aluminium as a result...... of alkaline etching pre-treatment influenced the thickness and growth of theoxide. Moreover the steam treatment resulted in the partial oxidation of second phase intermetallic particles present in the aluminium alloy microstructure....

  1. SFC-APLI-(TOF)MS: Hyphenation of Supercritical Fluid Chromatography to Atmospheric Pressure Laser Ionization Mass Spectrometry.

    Science.gov (United States)

    Klink, Dennis; Schmitz, Oliver Johannes

    2016-01-05

    Atmospheric-pressure laser ionization mass spectrometry (APLI-MS) is a powerful method for the analysis of polycyclic aromatic hydrocarbon (PAH) molecules, which are ionized in a selective and highly sensitive way via resonance-enhanced multiphoton ionization. APLI was presented in 2005 and has been hyphenated successfully to chromatographic separation techniques like high performance liquid chromatography (HPLC) and gas chromatography (GC). In order to expand the portfolio of chromatographic couplings to APLI, a new hyphenation setup of APLI and supercritical-fluid chromatography (SFC) was constructed and aim of this work. Here, we demonstrate the first hyphenation of SFC and APLI in a simple designed way with respect to different optimization steps to ensure a sensitive analysis. The new setup permits qualitative and quantitative determination of native and also more polar PAH molecules. As a result of the altered ambient characteristics within the source enclosure, the quantification of 1-hydroxypyrene (1-HP) in human urine is possible without prior derivatization. The limit of detection for 1-HP by SFC-APLI-TOF(MS) was found to be 0.5 μg L(-1), which is lower than the 1-HP concentrations found in exposed persons.

  2. Feasibility Study of Supercritical Light Water Cooled Reactors for Electric Power Production, Progress Report for Work Through September 2003, 2nd Annual/8th Quarterly Report

    Energy Technology Data Exchange (ETDEWEB)

    Philip E. MacDonald

    2003-09-01

    The supercritical water-cooled reactor (SCWR) is one of the six reactor technologies selected for research and development under the Generation-IV program. SCWRs are promising advanced nuclear systems because of their high thermal efficiency (i.e., about 45% vs. about 33% efficiency for current Light Water Reactors, LWRs) and considerable plant simplification. SCWRs are basically LWRs operating at higher pressure and temperatures with a direct once-through cycle. Operation above the critical pressure eliminates coolant boiling, so the coolant remains single-phase throughout the system. Thus the need for recirculation and jet pumps, a pressurizer, steam generators, steam separators and dryers is eliminated. The main mission of the SCWR is generation of low-cost electricity. It is built upon two proven technologies, LWRs, which are the most commonly deployed power generating reactors in the world, and supercritical fossil-fired boilers, a large number of which is also in use around the world.

  3. Effects of temperature and pressure on the performance of a solid oxide fuel cell running on steam reformate of kerosene

    Energy Technology Data Exchange (ETDEWEB)

    Chick, Lawrence A.; Marina, Olga A.; Coyle, Christopher A.; Thomsen, Edwin C.

    2013-08-15

    A button solid oxide fuel cell with a La0.6Sr0.4Co0.2Fe0.8O3 cathode and a nickel-YSZ anode was tested over a range of temperatures from 650 to 800°C and a range of pressures from 101 to 724 kPa. The fuel was simulated steam-reformed kerosene and the oxidant was air. The observed increases in open circuit voltages (OCV) were accurately predicted by the Nernst equation. Kinetics also increased, although the power boost due to kinetics was about two thirds as large as the boost due to OCV. The total power boost in going from 101 to 724 kPa at 750°C and 0.8 volts was 66%. Impedance spectroscopy demonstrated a significant decrease in electrodic losses at elevated pressures. Complex impedance spectra were dominated by a combination of low frequency processes that decreased markedly with increasing pressure. A composite of high-frequency processes also decreased with pressure, but to a lesser extent. An empirical algorithm that accurately predicts the increased fuel cell performance at elevated pressures was developed for our results and was also suitable for some, but not all, data reported in the literature.

  4. On the transition between two-phase and single-phase interface dynamics in multicomponent fluids at supercritical pressures

    Science.gov (United States)

    Dahms, Rainer N.; Oefelein, Joseph C.

    2013-09-01

    A theory that explains the operating pressures where liquid injection processes transition from exhibiting classical two-phase spray atomization phenomena to single-phase diffusion-dominated mixing is presented. Imaging from a variety of experiments have long shown that under certain conditions, typically when the pressure of the working fluid exceeds the thermodynamic critical pressure of the liquid phase, the presence of discrete two-phase flow processes become diminished. Instead, the classical gas-liquid interface is replaced by diffusion-dominated mixing. When and how this transition occurs, however, is not well understood. Modern theory still lacks a physically based model to quantify this transition and the precise mechanisms that lead to it. In this paper, we derive a new model that explains how the transition occurs in multicomponent fluids and present a detailed analysis to quantify it. The model applies a detailed property evaluation scheme based on a modified 32-term Benedict-Webb-Rubin equation of state that accounts for the relevant real-fluid thermodynamic and transport properties of the multicomponent system. This framework is combined with Linear Gradient Theory, which describes the detailed molecular structure of the vapor-liquid interface region. Our analysis reveals that the two-phase interface breaks down not necessarily due to vanishing surface tension forces, but due to thickened interfaces at high subcritical temperatures coupled with an inherent reduction of the mean free molecular path. At a certain point, the combination of reduced surface tension, the thicker interface, and reduced mean free molecular path enter the continuum length scale regime. When this occurs, inter-molecular forces approach that of the multicomponent continuum where transport processes dominate across the interfacial region. This leads to a continuous phase transition from compressed liquid to supercritical mixture states. Based on this theory, a regime diagram for

  5. Experimental investigation of system parameters and structure influence on steam-water flow regime and pressure oscillation

    Energy Technology Data Exchange (ETDEWEB)

    Proskouriakov, K. N.; Moukhine, V. S.; Sabouni, Kh. [Moscow Power Engineering Institute, Moscow (Russian Federation)

    2003-07-01

    Primary circuit of heat removal from reactors are the complex multi loop back spatial systems which are carrying out the main tasks- maintenance of reliable heat removal at normal operating in design modes and minimization of consequences of abnormal and emergency operation. For a substantiation serviceability of these systems out specially developed computer codes are used. These calculations of thermal hydraulic processes are based on use of laws of preservation and drawing up of power balances for the consecutive elements forming a contour of a heat-removal path. Comparisons of the result assumed on the basis of calculation with use of computer codes to the date of experiments show, that in the certain time period in system of cooling there are fluctuation of pressure and flow rate which are not described by model of system used in code. Synchronous investigation of statistic behavior of signals from Resistance Transducer (RT) of vapor content and Pressure Pulses Transducer (PPT) was provided. There was discovered variations of statistical performance of pressure pulsation on condition of different vapor content and flow regime. System parameters and structure influence on steam-water flow regime and pressure oscillation are discussed.

  6. Capillary pressure and saturation relations for supercritical CO2 and brine in sand: High-pressure Pc(Sw) controller/meter measurements and capillary scaling predictions

    Science.gov (United States)

    Tokunaga, Tetsu K.; Wan, Jiamin; Jung, Jong-Won; Kim, Tae Wook; Kim, Yongman; Dong, Wenming

    2013-08-01

    In geologic carbon sequestration, reliable predictions of CO2 storage require understanding the capillary behavior of supercritical (sc) CO2. Given the limited availability of measurements of the capillary pressure (Pc) dependence on water saturation (Sw) with scCO2 as the displacing fluid, simulations of CO2 sequestration commonly rely on modifying more familiar air/H2O and oil/H2O Pc(Sw) relations, adjusted to account for differences in interfacial tensions. In order to test such capillary scaling-based predictions, we developed a high-pressure Pc(Sw) controller/meter, allowing accurate Pc and Sw measurements. Drainage and imbibition processes were measured on quartz sand with scCO2-brine at pressures of 8.5 and 12.0 MPa (45°C), and air-brine at 21°C and 0.1 MPa. Drainage and rewetting at intermediate Sw levels shifted to Pc values that were from 30% to 90% lower than predicted based on interfacial tension changes. Augmenting interfacial tension-based predictions with differences in independently measured contact angles from different sources led to more similar scaled Pc(Sw) relations but still did not converge onto universal drainage and imbibition curves. Equilibrium capillary trapping of the nonwetting phases was determined for Pc = 0 during rewetting. The capillary-trapped volumes for scCO2 were significantly greater than for air. Given that the experiments were all conducted on a system with well-defined pore geometry (homogeneous sand), and that scCO2-brine interfacial tensions are fairly well constrained, we conclude that the observed deviations from scaling predictions resulted from scCO2-induced decreased wettability. Wettability alteration by scCO2 makes predicting hydraulic behavior more challenging than for less reactive fluids.

  7. Numerical Simulation Study on IP Rotor Coding Coupled Heat Transfer of 1000MW Ultra-supercritical Steam Turbine%1000MW超超临界汽轮机中压转子冷却耦合换热数值模拟研究

    Institute of Scientific and Technical Information of China (English)

    杨明; 李长宝; 管继伟; 刘云峰

    2013-01-01

    By using CFD and conjugate heat transfer(CHT) methods,IP Rotor Cooling of 1000MW Ultra-supercritical Steam Turbine has been numerical simulated.The temperature distribution whether the fluid and solid coupled heat transfer,cooling steam temperature effects on IP Rotor and the temperature distribution of the two half-rotor have been investigated.The fluid and solid temperature field distribution characteristics has been more realistic simulated.This article can provide a reliable basis for the structural design of ultra-supercritical steam turbine.%通过采用CFD和CHT(共轭换热)的数值方法,对超超临界1000MW汽轮机中压转子冷却进行了数值模拟,研究了有无流体与固体耦合换热的温度场分布差别,冷却蒸汽温度对中压转子冷却效果的影响,中压二级半转子冷却的温度分布,较真实地模拟了流体、固体区域温度场的分布特性.

  8. Supercritical power plant 600 MW with cryogenic oxygen plant and CCS installation

    Science.gov (United States)

    Kotowicz, Janusz; Dryjańska, Aleksandra

    2013-09-01

    This article describes a thermodynamic analysis of an oxy type power plant. The analyzed power plant consists of: 1) steam turbine for supercritical steam parameters of 600 °C/29 MPa with a capacity of 600 MW; 2) circulating fluidized bed boiler, in which brown coal with high moisture content (42.5%) is burned in the atmosphere enriched in oxygen; 3) air separation unit (ASU); 4) CO2 capture installation, where flue gases obtained in the combustion process are compressed to the pressure of 150 MPa. The circulated fluidized bed (CFB) boiler is integrated with a fuel dryer and a cryogenic air separation unit. Waste nitrogen from ASU is heated in the boiler, and then is used as a coal drying medium. In this study, the thermal efficiency of the boiler, steam cycle thermal efficiency and power demand were determined. These quantities made possible to determine the net efficiency of the test power plant.

  9. An Investigation of Steam Curing Pressure Effect on Pozzolan Additive Autoclaved Aerated Concrete

    Directory of Open Access Journals (Sweden)

    Kadir Güçlüer

    2015-02-01

    Full Text Available Autoclaved Aerated Concrete (AAC is a porous light weight concrete obtained by adding a pore-forming material to a mixture made of finely pulverized siliceous aggregate and inorganic binder (lime and/or cement and hardened by steam cure. In this study fly ash was used instead of siliceous aggregate and experiment samples were obtained by adding 3%, 6%, 9%, 12% silica fume to the cement. Samples were cured under 1560C and 4 bars and 1770C and 8 bars, and were investigated for compressive strength, bulk density and ultrasound pulse velocity to determine their mechanical and physical properties. Microstructure of samples was observed by using SEM and XRD techniques. Samples’ bulk density values and compressive strengths are changing between 0.6-0.7 kg/dm3 and 2.5-4.4 MPa respectively.

  10. Supercritical Water Reactor Cycle for Medium Power Applications

    Energy Technology Data Exchange (ETDEWEB)

    BD Middleton; J Buongiorno

    2007-04-25

    Scoping studies for a power conversion system based on a direct-cycle supercritical water reactor have been conducted. The electric power range of interest is 5-30 MWe with a design point of 20 MWe. The overall design objective is to develop a system that has minimized physical size and performs satisfactorily over a broad range of operating conditions. The design constraints are as follows: Net cycle thermal efficiency {ge}20%; Steam turbine outlet quality {ge}90%; and Pumping power {le}2500 kW (at nominal conditions). Three basic cycle configurations were analyzed. Listed in order of increased plant complexity, they are: (1) Simple supercritical Rankine cycle; (2) All-supercritical Brayton cycle; and (3) Supercritical Rankine cycle with feedwater preheating. The sensitivity of these three configurations to various parameters, such as reactor exit temperature, reactor pressure, condenser pressure, etc., was assessed. The Thermoflex software package was used for this task. The results are as follows: (a) The simple supercritical Rankine cycle offers the greatest hardware simplification, but its high reactor temperature rise and reactor outlet temperature may pose serious problems from the viewpoint of thermal stresses, stability and materials in the core. (b) The all-supercritical Brayton cycle is not a contender, due to its poor thermal efficiency. (c) The supercritical Rankine cycle with feedwater preheating affords acceptable thermal efficiency with lower reactor temperature rise and outlet temperature. (d) The use of a moisture separator improves the performance of the supercritical Rankine cycle with feedwater preheating and allows for a further reduction of the reactor outlet temperature, thus it was selected for the next step. Preliminary engineering design of the supercritical Rankine cycle with feedwater preheating and moisture separation was performed. All major components including the turbine, feedwater heater, feedwater pump, condenser, condenser pump

  11. Parameters optimization of supercritical fluid-CO2 extracts of frankincense using response surface methodology and its pharmacodynamics effects.

    Science.gov (United States)

    Zhou, Jing; Ma, Xing-miao; Qiu, Bi-Han; Chen, Jun-xia; Bian, Lin; Pan, Lin-mei

    2013-01-01

    The volatile oil parts of frankincense (Boswellia carterii Birdw.) were extracted with supercritical carbon dioxide under constant pressure (15, 20, or 25 MPa) and fixed temperature (40, 50, or 60°C), given time (60, 90, or 120 min) aiming at the acquisition of enriched fractions containing octyl acetate, compounds of pharmaceutical interest. A mathematical model was created by Box-Behnken design, a popular template for response surface methodology, for the extraction process. The response value was characterized by synthetical score, which comprised yields accounting for 20% and content of octyl acetate for 80%. The content of octyl acetate was determined by GC. The supercritical fluid extraction showed higher selectivity than conventional steam distillation. Supercritical fluid-CO(2) for extracting frankincense under optimum condition was of great validity, which was also successfully verified by the pharmacological experiments.

  12. THE EFFECT OF SYSTEM TEMPERATURE AND PRESSURE ON THE FLUID-DYNAMIC BEHAVIOR OF THE SUPERCRITICAL ANTISOLVENT MICRONIZATION PROCESS: A NUMERICAL APPROACH

    Directory of Open Access Journals (Sweden)

    R. A. Almeida

    Full Text Available Abstract The Supercritical Antisolvent (SAS technique allows for the precipitation of drugs and biopolymers in nanometer size in a wide range of industrial applications, while guaranteeing the physical and chemical integrity of such materials. However, a suitable combination of operating parameters is needed for each type of solute. The knowledge of fluid dynamics behavior plays a key role in the search for such parameter combinations. This work presents a numerical study concerning the impact of operating temperature and pressure upon the physical properties and mixture dynamics within the SAS process, because in supercritical conditions the radius of the droplets formed exhibits great sensitivity to these variables. For the conditions analyzed, to account for the heat of mixture in the energy balance, subtle variations in the temperature fields were observed, with almost negligible pressure drop. From analyses of the intensity of segregation, there is an enhancement of the mixture on the molecular scale when the system is operated at higher pressure. This corroborates experimental observations from the literature, related to smaller diameters of particles under higher pressures. Hence, the model resulted in a versatile tool for selecting conditions that may promote a better control over the performance of the SAS process.

  13. Pressure Fluctuations in the Gasostatic Bearing Supply System on Supercritical Operation Mode

    Directory of Open Access Journals (Sweden)

    Prodan Nikolay Vasilevich

    2014-07-01

    Full Text Available This study discusses the oscillatory mode occurring in the gap between the stator and the rotor in gas-static bearing during the outflow of under expanded gas jets out of the supply system, which interacts with the surface of the rotor. The results of studies on the oscillation regimes, their causes, mechanisms and frequency characteristics of pressure fluctuations in the working fluid supply system and the lubricating layer of gas bearing. A one-dimensional model of central shock oscillations in a gas jet leaking on a perpendicular barrier is considered. Experiments were carried out. The regions, where oscillation regimes exist are revealed.

  14. Optimization of High Temperature and Pressurized Steam Modified Wood Fibers for High-Density Polyethylene Matrix Composites Using the Orthogonal Design Method

    Directory of Open Access Journals (Sweden)

    Xun Gao

    2016-10-01

    Full Text Available The orthogonal design method was used to determine the optimum conditions for modifying poplar fibers through a high temperature and pressurized steam treatment for the subsequent preparation of wood fiber/high-density polyethylene (HDPE composites. The extreme difference, variance, and significance analyses were performed to reveal the effect of the modification parameters on the mechanical properties of the prepared composites, and they yielded consistent results. The main findings indicated that the modification temperature most strongly affected the mechanical properties of the prepared composites, followed by the steam pressure. A temperature of 170 °C, a steam pressure of 0.8 MPa, and a processing time of 20 min were determined as the optimum parameters for fiber modification. Compared to the composites prepared from untreated fibers, the tensile, flexural, and impact strength of the composites prepared from modified fibers increased by 20.17%, 18.5%, and 19.3%, respectively. The effect on the properties of the composites was also investigated by scanning electron microscopy and dynamic mechanical analysis. When the temperature, steam pressure, and processing time reached the highest values, the composites exhibited the best mechanical properties, which were also well in agreement with the results of the extreme difference, variance, and significance analyses. Moreover, the crystallinity and thermal stability of the fibers and the storage modulus of the prepared composites improved; however, the hollocellulose content and the pH of the wood fibers decreased.

  15. 机械加压蒸汽喷射器的性能分析%Performance analysis of steam ejector after mechanical pressurization in the suction-casing

    Institute of Scientific and Technical Information of China (English)

    凌莹; 张书廷; 张蕊

    2012-01-01

    To solve the problem that steam ejector had a limit ejector capacity at certain steam pressure, it was proposed that a fan was installed in the suction-casing to pressurize the secondary steam and to enhance the ejecting impetus. By comparing the performance of steam ejector with mechanical pressurization in the suction-casing and without, the influences of the cross section ratio, the primary steam pressure and the evaporation temperature on the ejecting performance with mechanical pressurization in the suction-casing were investigated, and its economic efficiency was evaluated. The results show that the entrainment ratio and the available energy efficiency are improved under the condition that steam ejector with mechanical pressurization in the suction-casing. The entrainment ratio and the available energy efficiency increase by 2.3% and 1.1% with mechanical pressurization in the suction-casing than that of traditional steam ejector without mechanical pressurization, respectively, when the cross section ratio of 9. 0 and the evaporation temperature of 98℃ are used. The entrainment ratio of steam ejector with mechanical pressurization in the suction-casing increases with the increasing of the cross section ratio, the primary steam pressure and the evaporation temperature,respectively. Economic evaluation indicates that the saving expense of more steam produced is 4. 5 time than electric consumption of fan installed in the suction-casing.%针对蒸汽喷射器在一定工作蒸汽压力下存在引射极限的问题,提出了在传统蒸汽喷射器的引射蒸汽吸入段设置风机用以提高喷射器的引射推动力.通过对机械加压和传统蒸汽喷射器性能的比较,研究了截面积比、工作蒸汽压力和蒸发温度对机械加压喷射器性能的影响,同时对机械加压喷射器的经济性进行了评价.结果表明,吸入段机械加压使喷射器的引射系数和有效能利用率都得到了提高,当截面积比为9.0,

  16. Investigation of radiation equilibrium in nitrogen tetroxide at supercritical temperatures and pressures

    Energy Technology Data Exchange (ETDEWEB)

    Gol' tsev, A.A.; Doroshkevich, V.N.; Nesterenko, V.B.; Nichipor, G.V.; Ukraintseva, L.V.

    1982-01-01

    The amounts of nitrogen and nitrous oxide as a result of nitrogen tetroxide ..gamma..-radiolysis have been measured at the temperature of 473 K, pressure of 15.7 MPa, dose rate of 5Wt/kg, D = 9.6x10/sup 7/ j/kg, times to 5350 hours to maximum degree of conversion of 15%. The amounts of nitrogen and nitrous oxide from nitrogen tetroxide n, ..gamma..-radiolysis have been measured at 523 K, 11.7 MPa, dose of 2.4x10/sup 8/ j/kg to the degree of conversion of 39%. Kinetic analysis of the experimental data with reference to the known reactions evidence that the calculated and experimental concentrations agree satisfactorily at small degrees of conversion.

  17. A process for generating power from the oxidation of coal in supercritical water

    Energy Technology Data Exchange (ETDEWEB)

    M.D. Bermejo; M.J. Cocero; F. Fernandez-Polanco [Universidad de Valladolid, Valladolid (Spain). Departamento de Ingenieria Quimica

    2004-01-01

    A theoretical study of power generation from oxidation of coal by supercritical water oxidation (SCWO) is presented. Two versions of SCWO power plant are compared to two of the most efficient conventional power plant processes: pulverised coal power plants and pressurised fluidised bed power plant. The effects of steam pressure and temperature on produced (W{sub p}), consumed (W{sub c}) and net work (W{sub N}) are calculated in order to compare the efficiency of these power plants for the same steam conditions. Enthalpies have been calculated using residual enthalpies by Peng Robinson equation of state. Calculated results show that net work in SCWO power plant is 5% higher than in other power plants, due to the fact that no air surplus is necessary for complete combustion and because steam is produced by direct heating. Energetic efficiency of SCWO increases more quickly with temperature than for the other power plants. The effect of steam pressure is different: until 30 MPa power plant efficiencies increase more quickly in SCWO power plants than in conventional plants, but when steam pressures increases beyond 30 MPa, efficiencies decrease in SCWO power plants. 21 refs., 12 figs., 7 tabs.

  18. Reduction of Erosion Wear of Mean Pressure Cylinder of Steam Turbines Operating Beyond Critical Parameters

    Directory of Open Access Journals (Sweden)

    V. P. Kascheev

    2009-01-01

    Full Text Available The paper considers problems leading to erosion wear of flowing part of a mean pressure turbine cylinder operating beyond critical parameters. Explanation of erosion wear of flowing part of a mean pressure turbine cylinder which is proved in practice and recommendations for wear reduction are given in the paper

  19. Experimental study on temperature distribution of membrane water wall in an ultra-supercritical pressure once-through boiler burning zhundong coal

    Science.gov (United States)

    He, Honghao; Li, Wenjun; Zeng, Jun; Xie, Guohong; Peng, Min; Duan, Xuenong

    2017-05-01

    Taking an ultra-supercritical pressure once-through boiler as an example, the temperature distribution of the lower membrane water wall is investigated experimentally, the conclusion reveals that increasing the proportion of Zhundong coal can effectively reduce the district heat load, which benefits the temperature uniformity in the lower membrane water wall. When the boiler being operated at middle load, the temperature deviation in lower membrane water wall increase simultaneously, one of the reasons is that the restriction orifice could not adjust the flow rate of working fluid as expected. By adjusting boiler performance, the temperature uniformity of lower membrane water wall can be improved to a certain degree.

  20. Complete Fiber/Copper Cable Solution for Long-Term Temperature and Pressure Measurement in Supercritical Reservoirs and EGS Wells

    Energy Technology Data Exchange (ETDEWEB)

    Pastouret, Alan [Draka Cableteq USA, Inc., North Dighton, MA (United States); Gooijer, Frans [Draka Cableteq USA, Inc., North Dighton, MA (United States); Overton, Bob [Draka Cableteq USA, Inc., North Dighton, MA (United States); Jonker, Jan [Draka Cableteq USA, Inc., North Dighton, MA (United States); Curley, Jim [Draka Cableteq USA, Inc., North Dighton, MA (United States); Constantine, Walter [Draka Cableteq USA, Inc., North Dighton, MA (United States); Waterman, Kendall Miller [Draka Cableteq USA, Inc., North Dighton, MA (United States)

    2015-11-13

    High Temperature insulated wire and optical fiber cable is a key enabling technology for the Geothermal Technologies Program (GTP). Without insulated electrical wires and optical fiber, downhole temperature and pressure sensors, flow meters and gauges cannot communicate with the surface. Unfortunately, there are currently no insulated electrical wire or fiber cable constructions capable of surviving for extended periods of deployment in a geothermal well (240-325°C) or supercritical (374°C) reservoir. This has severely hindered engineered reservoir creation, management and utilization, as hot zones and cool water intrusions cannot be understood over time. The lack of a insulated electrical wire and fiber cable solution is a fundamental limitation to the viability of this energy source. The High Temperature Downhole Tools target specification is development of tools and sensors for logging and monitoring wellbore conditions at depths of up to 10,000 meters and temperatures up to 374oC. It well recognized in the industry that no current electronic or fiber cable can be successfully deployed in a well and function successfully for more a few days at temperatures over 240oC. The goal of this project was to raise this performance level significantly. Prysmian Group’s objective in this project was to develop a complete, multi-purpose cable solution for long-term deployment in geothermal wells/reservoirs that can be used with the widest variety of sensors. In particular, the overall project objective was to produce a manufacturable cable design that can perform without serious degradation: • At temperatures up to 374°C; • At pressures up to 220 bar; • In a hydrogen-rich environment; and • For the life of the well (> 5 years). This cable incorporates: • Specialty optical fibers, with specific glass chemistry and high temperature and pressure protective coatings for data communication and distributed temperature and pressure sensing, and • High

  1. An investigation into the heat transfer characteristics of spiral wall with internal rib in a supercritical sliding-pressure operation once-through boiler

    Institute of Scientific and Technical Information of China (English)

    TANG Renhu; YIN Fei; WANG Haijun; CHEN Tingkuan

    2007-01-01

    Within the pressure range of 9-28 MPa,mass 200-500 kW/m2,experiments were performed to investigate the heat transfer to water in the inclined upward internally ribbed tube with an inclined angle of 19.5 degrees,a maximum outer diameter of 38.1 mm,and a thickness of 7.5 mm.Based on the experiments,it was found that heat transfer enhancement of the internally ribbed tube could postpone departure from nucleate boiling at the sub-critical pressure.However,the heat transfer enhancement decreased near the critical pressure.At supercritical pressure,the temperature difference between the wall and the fluid increased near the pseudo-critical temperature,but the increase of wall temperature was less than that of departure from nucleate boiling at sub-critical pressure.When pressure is closer to the critical pressure,the temperature difference between the wall and the fluid increased greatly near the pseudo-critical temperature.Heat transfer to supercritical water in the inclined upward internally ribbed tube was enhanced or deteriorated near the pseudo-critical temperature with the variety of ratio between the mass velocity and the heat flux.Because the rotational flow of the internal groove reduced the effect of natural convection,the internal wall temperature of internally ribbed tube uniformly distributed along the circumference.The maximum internal wall temperature difference of the tube along the circumference was only 10 degrees when the fluid enthalpy exceeded 2 000 J/g.Considering the effect of acute variety of the fluid property on heat transfer,the correlation of heat transfer coefficient on the top of the internally ribbed tube was orovided.

  2. Coupling of Modular High-Temperature Gas-Cooled Reactor with Supercritical Rankine Cycle

    Directory of Open Access Journals (Sweden)

    Shutang Zhu

    2008-01-01

    Full Text Available This paper presents investigations on the possible combination of modular high-temperature gas-cooled reactor (MHTGR technology with the supercritical (SC steam turbine technology and the prospective deployments of the MHTGR SC power plant. Energy conversion efficiency of steam turbine cycle can be improved by increasing the main steam pressure and temperature. Investigations on SC water reactor (SCWR reveal that the development of SCWR power plants still needs further research and development. The MHTGR SC plant coupling the existing technologies of current MHTGR module design with operation experiences of SC FPP will achieve high cycle efficiency in addition to its inherent safety. The standard once-reheat SC steam turbine cycle and the once-reheat steam cycle with life-steam have been studied and corresponding parameters were computed. Efficiencies of thermodynamic processes of MHTGR SC plants were analyzed, while comparisons were made between an MHTGR SC plant and a designed advanced passive PWR - AP1000. It was shown that the net plant efficiency of an MHTGR SC plant can reach 45% or above, 30% higher than that of AP1000 (35% net efficiency. Furthermore, an MHTGR SC plant has higher environmental competitiveness without emission of greenhouse gases and other pollutants.

  3. Experimental Investigation of High-Pressure Steam-Induced Surge in a Transonic Compressor Stage

    Science.gov (United States)

    2008-06-01

    phenomena that reduce the operational effectiveness of compressors and pose a considerable threat of damage to essential turbomachine components. In...interrupts the compressor flow field in a manner that leads to violent, periodically steady pressure oscillations in a turbomachine stage [7

  4. A new control valve with a push rod for intermediate-pressure cylinders of steam turbines

    Science.gov (United States)

    Zaryankin, A. E.; Arianov, S. V.; Paramonov, A. N.; Gotovtsev, A. M.; Storozhuk, S. K.

    2007-11-01

    We describe a new design of a control valve for intermediate-pressure cylinders with a perforated cup and a push rod that ensures smaller loss under rated operating conditions and features better reliability. Model tests were carried out to check the main design solutions.

  5. Silicate Carbonation in Supercritical CO2 Containing Dissolved H2O: An in situ High Pressure X-Ray Diffraction Study

    Energy Technology Data Exchange (ETDEWEB)

    Schaef, Herbert T.; Miller, Quin RS; Thompson, Christopher J.; Loring, John S.; Bowden, Mark E.; Arey, Bruce W.; McGrail, B. Peter; Rosso, Kevin M.

    2013-06-30

    Technological advances have been significant in recent years for managing environmentally harmful emissions (mostly CO2) resulting from combustion of fossil fuels. Deep underground geologic formations are emerging as reasonable options for long term storage of CO2 but mechanisms controlling rock and mineral stability in contact with injected supercritical fluids containing water are relatively unknown. In this paper, we discuss mineral transformation reactions occurring between supercritical CO2 containing water and the silicate minerals forsterite (Mg2SiO4), wollastonite (CaSiO3), and enstatite (MgSiO3). This study utilizes newly developed in situ high pressure x-ray diffraction (HXRD) and in situ infra red (IR) to examine mineral transformation reactions. Forsterite and enstatite were selected as they are important minerals present in igneous and mafic rocks and have been the subject of a large number of aqueous dissolution studies that can be compared with non-aqueous fluid tests in this study. Wollastonite, classified as a pyroxenoid (similar to a pyroxene), was chosen as a suitably fast reacting proxy for examining silicate carbonation processes associated with a wet scCO2 fluid as related to geologic carbon sequestration. The experiments were conducted under modest pressures (90 to 160 bar), temperatures between 35° to 70° C, and varying concentrations of dissolved water. Under these conditions scCO2 contains up to 3,500 ppm dissolved water.

  6. Descaling cleaning summary of turbine using low-pressure steam%汽轮机组用低压饱和蒸汽除垢清洗总结

    Institute of Scientific and Technical Information of China (English)

    薛春野; 沈良锋; 张黎明

    2014-01-01

    中化吉林长山化工有限公司空分车间蒸汽透平空压机汽轮机为16000Nm3/h空分装置配套汽轮机。由于高压蒸汽品质问题,在运行过程中汽轮机转子叶轮、上下持环等部件结垢,影响正常运行。2014年1月28日利用低压饱和蒸汽对汽轮机进行清洗,从清洗后机组运行状态来看,此次清洗效果良好,达到了预期目标。%The steam turbine compressor turbine is 16 000 Nm3/h in Sinochem Jilin Changshan Chemical Co., Ltd. for air separation plant. Because of quality of high pressure steam, rotor wheel and ring up and down of steam turbine scaling while in operation which effects normal operation. By using low pressure saturated steam on January 28, 2014, the result of cleaning effect is good, which achieves desired goals.

  7. Sterilization Effect Survey of Downward-discharged Pressure steam sterilizar%下排气压力蒸汽灭菌器灭菌效果的综合监测

    Institute of Scientific and Technical Information of China (English)

    刘红萍; 王凤茹

    2002-01-01

    The downward - discharged pressure, steam sterilizor was surveyed 60 times from July 1996 to February 1997. The majormeans included 121°C centigrade pressed- steam sterilization chemical indicator card 3M adhesive plaster, stationary point thermometer,themophilic lipobacillus spore bacteria card and process.

  8. Phenomenological and mathematical modeling of a high pressure steam driven jet injector. Part 2

    Energy Technology Data Exchange (ETDEWEB)

    Anand, G.

    1993-12-31

    An injector is a particular type of jet pump which uses condensable vapor to entrain a liquid and discharge against a pressure higher than either motive or suction pressures. The injector has no moving parts and requires no external power supply nor any complex control system. Thus, the injector is particularly suited for emergency core cooling operations. A detailed survey has indicated that various injector designs are available for operating pressures below 250 psig. However, the design of these injectors from the viewpoint of a basic understanding of heat and mass transfer processes has not been well developed. A critical review of the models showed serious discrepancies between the analytical models and the experimental observations. The discrepancies evolved from the neglect of non-equilibrium aspects of the flow. The origin of the non-equilibrium aspects can be traced to the extremely small time scales governing the flow in the injector. Thus, time scales of the order of 10{sup {minus}2} seconds are involved in the injector, accompanied by mass, momentum, and heat transfer rates of orders of magnitude higher than that observed in conventional two-phase flows. The present study focuses on the phenomenological and mathematical modeling of the processes in the injector from the viewpoint of its non-equilibrium nature.

  9. Experimental and numerical simulations of bottom hole temperature and pre-ssure distributions of supercritical CO2 jet for well-drilling

    Institute of Scientific and Technical Information of China (English)

    王瑞和; 霍洪俊; 黄志远; 宋慧芳; 倪红坚

    2014-01-01

    The supercritical carbon dioxide (SC-CO2) drilling is a novel drilling technique developed in recent years. A detailed study of temperature and pressure distributions of the SC-CO2 jet on the bottom of a well is essensial to the SC-CO2 drilling. In this paper, the distributions of pressure and temperature on the bottom of the hole during the SC-CO2 jet drilling are simulated experimentally and numerically, and the impacts of the nozzle diameter, the jet length, and the inlet pressure of the SC-CO2 jet are analyzed. It is shown that, the bottom hole temperature and pressure increase with the increase of the nozzle diameter, and the bottom hole temperature reduces and the pressure increases first and then decreases with the increase of the jet length, indicating that the jet length has an optimum value. The increase of the inlet pressure can increase the temperature and pressure on the bottom, which has a positive effect on the drilling rate.

  10. 升温升压过程对聚丙烯在超临界水中降解的影响%Effect of Increasing Course of Temperature and Pressure on Polypropylene Degradation in Supercritical Water

    Institute of Scientific and Technical Information of China (English)

    苏磊; 吴学华; 刘秀茹; 陈丽英; 陈克宇; 洪时明

    2007-01-01

    The effect of increasing course of temperature and pressure on polypropylene (PP) degradation in supercritical water was investigated for developing a process of recycling waste plastic. A group of experiments was carried out in a reaction system at a pressure of 26MPa, temperature of 380℃ or 400℃ for 30min, 70min, and 120main by Course One (the increasing course of temperature and pressure is via gaseous regions to supercritical regions), and the other group was carried out at corresponding holding conditions by Course Two (the increasing course of temperature and pressure is via liquid regions to supercritical regions). The time of the increasing courses was about 30min. Products were analyzed by Ostward-type viscometer, gaseous chromatography, and mass spectrometers (GC/MS). Characterization results suggested that different increasing courses of temperature and pressure would give rise to different results, although they were treated under the similar holding conditions. It was also found that Course Two was more effective on PP degradation in supercritical water.

  11. Geometric and structural properties of a rectangular supercritical wing oscillated in pitch for measurement of unsteady transonic pressure distributions

    Science.gov (United States)

    Ricketts, R. H.; Watson, J. J.; Sandford, M. C.; Seidel, D. A.

    1983-01-01

    Wind-tunnel tests to measure unsteady aerodynamic data in the transonic region have been completed on an aspect ratio 2.0 rectangular wing with a supercritical airfoil. The geometric and structural properties of the wing are presented. (Other references contain the measured aerodynamic data.) Both measured and design airfoil coordinates are presented and compared. In addition, measured wing bending and torsional stiffness distributions and some trailing-edge flexibility influence coefficients are presented.

  12. Effect of Co-solvent and Pressure on the Thermal Decomposition of 2, 2' Azobis - (isobutyronitrile) in Supercritical CO2

    Institute of Scientific and Technical Information of China (English)

    2001-01-01

    The thermal decomposition of 2, 2'-azobis (isobutyronitrile) (AIBN) in supercritical CO2 with cosolvent methanol or cyclohexane has been studied by using UV/Vis spectroscopic method at 335.15 K and at 12.0 MPa and 14.0 MPa. Both of the cosolvents can accelerate the decomposition rate, and the effect of methanol is more significant than that of the cyclohexane.

  13. 超临界水通道内压降特性分析%Analysis of Pressure Drop Characteristic in Supercritical Water Channel

    Institute of Scientific and Technical Information of China (English)

    徐莉; 臧金光; 曾小康; 闫晓

    2014-01-01

    Supercritical water-colded reactor (SCWR) is one of the fourth generation nuclear energy systems with the supercritical water as the reactor coolant and moderator .The sharp variation of fluid property near the pseudo-critical point will have influence on the pressure drop characteristics of the flow channel .In this study ,the pressure drops due to gravity , acceleration and friction were investigated under supercritical conditions and some suggestions were provided as reference .The flow path integration effect in gravity pressure drop needed to be accounted for .The explicit PKN formula was obtained based on the implicit PKN form which could be applied into isothermal flow .The comparison of different frictional pressure drop correlations with CFD numerical simulation results was made ,and it is found that the Kirillov correlation is close to CFD calculation results .%超临界水冷堆是以超临界水作为冷却剂和慢化剂的第4代核能系统之一,超临界水在拟临界区附近剧烈的物性变化会给通道内的压降特性带来影响。本文分析了超临界条件下重力压降、加速压降和摩擦压降的特点,并对具体的计算方式提供了一些建议和参考:重力压降需考虑沿程的积分效应;基于隐式PKN公式得到了显式PKN公式,用于求解等温流动摩擦系数;采用CFD数值分析工具比较了超临界条件下不同摩擦关系式的异同,发现Kirillov公式与CFD计算结果较为接近。

  14. Active latent heat storage with a screw heat exchanger - experimental results for heat transfer and concept for high pressure steam

    Science.gov (United States)

    Zipf, Verena; Willert, Daniel; Neuhäuser, Anton

    2016-05-01

    An innovative active latent heat storage concept was invented and developed at Fraunhofer ISE. It uses a screw heat exchanger (SHE) for the phase change during the transport of a phase change material (PCM) from a cold to a hot tank or vice versa. This separates heat transfer and storage tank in comparison to existing concepts. A test rig has been built in order to investigate the heat transfer coefficients of the SHE during melting and crystallization of the PCM. The knowledge of these characteristics is crucial in order to assess the performance of the latent heat storage in a thermal system. The test rig contains a double shafted SHE, which is heated or cooled with thermal oil. The overall heat transfer coefficient U and the convective heat transfer coefficient on the PCM side hPCM both for charging and discharging have been calculated based on the measured data. For charging, the overall heat transfer coefficient in the tested SHE was Uch = 308 W/m2K and for discharging Udis = 210 W/m2K. Based on the values for hPCM the overall heat transfer coefficients for a larger SHE with steam as heat transfer fluid and an optimized geometry were calculated with Uch = 320 W/m2K for charging and Udis = 243 W/m2K for discharging. For pressures as high as p = 100 bar, an SHE concept has been developed, which uses an organic fluid inside the flight of the SHE as working media. With this concept, the SHE can also be deployed for very high pressure, e.g. as storage in solar thermal power plants.

  15. Optimization of supercritical fluid extraction of essential oils and fatty acids from flixweed (Descurainia Sophia L.) seed using response surface methodology and central composite design.

    Science.gov (United States)

    Ara, Katayoun Mahdavi; Jowkarderis, Mina; Raofie, Farhad

    2015-07-01

    Essential oils and fatty acids of Descurainia sophia L. seed were obtained by supercritical CO2 extraction and steam distillation methods. The effect of different parameters such as pressure, temperature, modifier volume, dynamic and static extraction timeon the extraction yield were optimized using a central composite design after a 2 (n-1) fractional factorial design. The results showed that under the pressure of 355 bar, temperature of 65 °C, methanol volume of 150 μL, dynamic and static extraction times of 35 and 10 min, respectively, the major components were methyl linoleate (18.2 %), camphor (12.32 %), cis-thujone (11.3 %) and trans-caryophyllene (9.17 %). The results indicated that by using the proper conditions, the supercritical fluid extraction is more selective than the steam distillation method. Extraction yields based on supercritical fluid extraction varied in the range of 0.68 to 17.1 % (w/w), and the extraction yield based on the steam distillation was 0.25 % (v/w).

  16. A Comparison of Supercritical Carbon Dioxide Power Cycle Configurations with an Emphasis on CSP Applications (Presentation)

    Energy Technology Data Exchange (ETDEWEB)

    Neises, T.; Turchi, C.

    2013-09-01

    Recent research suggests that an emerging power cycle technology using supercritical carbon dioxide (s-CO2) operated in a closed-loop Brayton cycle offers the potential of equivalent or higher cycle efficiency versus supercritical or superheated steam cycles at temperatures relevant for CSP applications. Preliminary design-point modeling suggests that s-CO2 cycle configurations can be devised that have similar overall efficiency but different temperature and/or pressure characteristics. This paper employs a more detailed heat exchanger model than previous work to compare the recompression and partial cooling cycles, two cycles with high design-point efficiencies, and illustrates the potential advantages of the latter. Integration of the cycles into CSP systems is studied, with a focus on sensible heat thermal storage and direct s-CO2 receivers. Results show the partial cooling cycle may offer a larger temperature difference across the primary heat exchanger, thereby potentially reducing heat exchanger cost and improving CSP receiver efficiency.

  17. Prospects for development of an innovative water-cooled nuclear reactor for supercritical parameters of coolant

    Science.gov (United States)

    Kalyakin, S. G.; Kirillov, P. L.; Baranaev, Yu. D.; Glebov, A. P.; Bogoslovskaya, G. P.; Nikitenko, M. P.; Makhin, V. M.; Churkin, A. N.

    2014-08-01

    The state of nuclear power engineering as of February 1, 2014 and the accomplished elaborations of a supercritical-pressure water-cooled reactor are briefly reviewed, and the prospects of this new project are discussed based on this review. The new project rests on the experience gained from the development and operation of stationary water-cooled reactor plants, including VVERs, PWRs, BWRs, and RBMKs (their combined service life totals more than 15 000 reactor-years), and long-term experience gained around the world with operation of thermal power plants the turbines of which are driven by steam with supercritical and ultrasupercritical parameters. The advantages of such reactor are pointed out together with the scientific-technical problems that need to be solved during further development of such installations. The knowledge gained for the last decade makes it possible to refine the concept and to commence the work on designing an experimental small-capacity reactor.

  18. Sliding Mode Control for the Boiler Steam Pressure of Fuel-steam Pressure System Based on Delayed Output Observer%基于输出延时观测器的燃料-汽压系统锅炉蒸汽压力滑模控制

    Institute of Scientific and Technical Information of China (English)

    崔志强; 刘吉臻; 刘金琨

    2011-01-01

    The boiler steam pressure is a important parameter reflecting the state of boiler operation. According to the delayed measurement of the boiler steam pressure, a delayed output observer was designed for fuel-steam pressure system. In the delayed output observer, only the boiler steam pressure was needed, then the observed value of the boiler steam pressure, the first derivative and the second derivative value of the boiler steam pressure were obtained. The convergence of the observer was proved. Sliding mode controller was designed by using the observed value which can improve the system robustness, and the result show that the closed system stability can be guarantee from Lyapunov stability analysis. Only the boiler steam pressure signal was used in the observer and the controller, which indicates that the proposed method has important significance in engineering. Simulation results are presented to validate the good tracking performance of the control system.%锅炉蒸汽压力是表征锅炉运行状态的重要参数.针对燃料-汽压系统锅炉蒸汽压力测量信号的延迟问题,设计一种延迟观测器,只需要实测的延迟锅炉蒸汽压力信号,便可实现延迟锅炉蒸汽压力及其一阶和二阶导数的观测,理论分析证明了观测器的收敛性.将延时观测器的观测值用于控制器中,利用滑模控制方法设计控制器,通过Lyapunov稳定性分析方法证明了闭环系统的稳定性.由于观测器和控制器中只采用了延迟锅炉蒸汽压力信号,因此本算法具有重要的工程意义.仿真结果显示了良好的跟踪效果,证明了该方法的有效性.

  19. Revamping of Temperature and Pressure Reduction Interlock in High Pressure Steam System of Large Chemical Plant%大型化工厂高压蒸汽减温减压联锁改造

    Institute of Scientific and Technical Information of China (English)

    乜春晖; 何魁邦; 杨德林

    2014-01-01

    Describe the importance of stability of both high and medium pressure steam systems in large chemical plant . After modifying the steam control system and interlock logic drawbacks in the design ,the foundation for smooth delivery of steam power is laid ,continuity of the production in chemical plant is guaranteed ,and economic benefits are improved .%阐述了调解大型化工厂高压蒸汽与中压过热蒸汽的稳定对于化工企业的重要性。修改设计存在的蒸汽调解及联锁逻辑弊端,为蒸汽动力的平稳输送奠定了基础,保证了化工企业的生产连续性,提高了经济效益。

  20. Supercritical solvent coal extraction

    Science.gov (United States)

    Compton, L. E. (Inventor)

    1984-01-01

    Yields of soluble organic extract are increased up to about 50% by the supercritical extraction of particulate coal at a temperature below the polymerization temperature for coal extract fragments (450 C.) and a pressure from 500 psig to 5,000 psig by the conjoint use of a solvent mixture containing a low volatility, high critical temperature coal dissolution catalyst such as phenanthrene and a high volatility, low critical temperature solvent such as toluene.

  1. Angle-dependent hard X-ray photoemission study of Nb hydride formation in high-pressure supercritical water

    Energy Technology Data Exchange (ETDEWEB)

    Soda, Kazuo, E-mail: j45880a@cc.nagoya-u.ac.jp [Department of Quantum Engineering, Graduate School of Engineering, Nagoya University, Furo-cho, Chikusa-ku, Nagoya 464-8603 (Japan); Kondo, Hiroki; Yamaguchi, Kanta; Kato, Masahiko [Department of Quantum Engineering, Graduate School of Engineering, Nagoya University, Furo-cho, Chikusa-ku, Nagoya 464-8603 (Japan); Shiraki, Tatsuhito; Niwa, Ken; Kusaba, Keiji; Hasegawa, Masashi [Department of Crystalline Materials Science, Graduate School of Engineering, Nagoya University, Furo-cho, Chikusa-ku, Nagoya 464-8603 (Japan); Xeniya, Kozina; Ikenaga, Eiji [Japan Synchrotron Radiation Research Institute, 1-1-1, Kouto, Sayo-cho, Sayo-gun, Hyogo 679-5198 (Japan)

    2015-09-15

    Highlights: • Nb hydrides in 10-GPa supercritical water are studied by photoelectron spectroscopy. • The hydride components of the Nb 3d core-level spectra are increased with the depth. • The bulk valence-band spectrum shows a split band due to the Nb–H bond formation. • The hydrides are formed in the bulk and their surfaces are covered with Nb oxides. - Abstract: Nb hydrides formation in 10-GPa supercritical water has been investigated by angle-dependent micro-beam hard X-ray photoemission spectroscopy. In the Nb 3d core-level spectra, Nb hydride components are found in the slightly high binding energy side of the metallic components, and the oxide ones are observed even though little oxides are recognized in X-ray diffraction patterns. Obtained emission-angle dependence of the Nb 3d core-level spectra of Nb hydride specimens shows that the Nb hydride components increase with the emission angle decreased i.e. the sampling depth increased, while the oxide ones decrease. The bulk valence-band spectrum is obtained by decomposing the measured valence-band spectra into a bulk and surface components with use of the emission-angle dependence of the core-level and valence-band spectra; it consists of two bands. This implies the Nb–H chemical bond formation and Nb in an oxidation state, consistent with reported band structure calculations and the observed core-level chemical shifts. Thus it is confirmed by valence-band and core-level photoelectron spectroscopy that the Nb hydrides are formed inside the specimen, irrespective to the well-known high oxidation ability of supercritical water.

  2. Development of tubes and pipe for ultra-supercritical power plant boilers. Chocho rinkaiatsu boira yo kokan no kaihatsu

    Energy Technology Data Exchange (ETDEWEB)

    Naoi, H.; Mimura, H.; Ogami, M.; Sakakibara, M.; Araki, S.; Sogo, Y.; Ogawa, T.; Sakurai, H. (Nippon Steel Corp., Tokyo (Japan)); Fujita, T. (Tokyo Univ. (Japan))

    1992-11-30

    For aiming to improve the power plant efficiency for a purpose of the energy saving, in recent years, the steam condition of the boilers has become to be supercritical in a degree of the high temperature 566[degree]C[times] high pressure 246 atm. For protecting the global environment, the extensive researches for the further improvement of power plant efficiency are under way in many countries, and the immediate targets of the steam condition for boilers are 316 atm [times]593[degree]C while the final targets are ultra-supercritical as 352 atm [times]649[degree]C. In order to realize the plant which can withstand these conditions, the Nippon Steel Corp. has been conducting a development of the materials which can withstand the high temperature and pressure. Those are the ferritic steel 9Cr-0.5Mo-1.8W-Nb-V (NF616) and the austenitic steel 20Cr-25Ni-1.5Mo-Nb-Ti-N (NF709). The creep rupture strength of the former steel at 600[degree]C is equal to or higher than that of existing 18-8 austenitic stainless steel, while the creep rupture strength of the latter steel at 700[degree]C[times] 100,000 hours is 88MPa or above. The development of these 2 kinds of tubes and pipes for the ultra-supercritical boilers is described. 7 refs., 14 figs., 3 tabs.

  3. Evaluation of cracking in feedwater piping adjacent to the steam generators in Nine Pressurized Water Reactor Plants

    Energy Technology Data Exchange (ETDEWEB)

    Goldberg, A.; Streit, R.D.; Scott, R.G.

    1980-06-25

    Cracking in ASTM A106-B and A106-C feedwater piping was detected near the inlet to the steam generators in a number of pressurized water reactor plants. We received sections with cracks from nine of the plants with the objective of identifying the cracking mechanism and assessing various factors that might contribute to this cracking. Variations were observed in piping surface irregularities, corrosion-product, pit, and crack morphology, surface elmental and crystal structure analyses, and steel microstructures and mechanical properties. However, with but two exceptions, namely, arrest bands and major surface irregularities, we were unable to relate the extent of cracking to any of these factors. Tensile and fracture toughness (J/sub Ic/ and tearing modulus) properties were measured over a range of temperatures and strain rates. No unusual properties or microstructures were observed that could be related to the cracking problem. All crack surfaces contained thick oxide deposits and showed evidence of cyclic events in the form of arrest bands. Transmission electron microscopy revealed fatigue striations on replicas of cleaned crack surfaces from one plant and possibly from three others. Calculations based on the observed striation spacings gave a value of ..delta..sigma = 150 MPa (22 ksi) for one of the major cracks. The direction of crack propagation was invariably related to the piping surface and not to the piping axis. These two factors are consistent with the proposed concept of thermally induced, cyclic, tensile surface stresses. Although surface irregularities and corrosion pits were sources for crack initiation and corrosion may have contributed to crack propagation, it is proposed that the overriding factor in the cracking problem is the presence of unforeseen cyclic loads.

  4. Supercritical Extraction of Lycopene from Tomato Industrial Wastes with Ethane

    OpenAIRE

    Mendes, Rui L.; Cristino, Ana F.; Nobre, Beatriz P.; Luisa Gouveia; António F. Palavra; Patricia G. S. Matos

    2012-01-01

    Supercritical fluid extraction of all-E-lycopene from tomato industrial wastes (mixture of skins and seeds) was carried out in a semi-continuous flow apparatus using ethane as supercritical solvent. The effect of pressure, temperature, feed particle size, solvent superficial velocity and matrix initial composition was evaluated. Moreover, the yield of the extraction was compared with that obtained with other supercritical solvents (supercritical CO2...

  5. Supercritical Extraction of Lycopene from Tomato Industrial Waste with Ethane

    OpenAIRE

    Nobre, Beatriz P.; Gouveia, L.; Patricia G. S. Matos; Cristino, Ana F.; António F. Palavra; Mendes, Rui L.

    2012-01-01

    Supercritical fluid extraction of all-E-lycopene from tomato industrial wastes (mixture of skins and seeds) was carried out in a semi-continuous flow apparatus using ethane as supercritical solvent. The effect of pressure, temperature, feed particle size, solvent superficial velocity and matrix initial composition was evaluated. Moreover, the yield of the extraction was compared with that obtained with other supercritical solvents (supercritical CO2 and a near critical mixture of ethane and p...

  6. Fuel composition optimization in a 78-element fuel bundle for use in a pressure tube type supercritical water-cooled reactor

    Energy Technology Data Exchange (ETDEWEB)

    Hummel, D.W.; Novog, D.R. [McMaster Univ., Hamilton, Ontario (Canada)

    2012-07-01

    A 78-element fuel bundle containing a plutonium-thorium fuel mixture has been proposed for a Generation IV pressure tube type supercritical water-cooled reactor. In this work, using a lattice cell model created with the code DRAGON,the lattice pitch, fuel composition (fraction of PuO{sub 2} in ThO{sub 2}) and radial enrichment profile of the 78-element bundle is optimized using a merit function and a metaheuristic search algorithm.The merit function is designed such that the optimal fuel maximizes fuel utilization while minimizing peak element ratings and coolant void reactivity. A radial enrichment profile of 10 wt%, 11 wt% and 20 wt% PuO{sub 2} (inner to outer ring) with a lattice pitch of 25.0 cm was found to provide the optimal merit score based on the aforementioned criteria. (author)

  7. Influence of high-pressure homogenization, ultrasonication, and supercritical fluid on free astaxanthin extraction from β-glucanase-treated Phaffia rhodozyma cells.

    Science.gov (United States)

    Hasan, Mojeer; Azhar, Mohd; Nangia, Hina; Bhatt, Prakash Chandra; Panda, Bibhu Prasad

    2016-01-01

    In this study astaxanthin production by Phaffia rhodozyma was enhanced by chemical mutation using ethyl methane sulfonate. The mutant produces a higher amount of astaxanthin than the wild yeast strain. In comparison to supercritical fluid technique, high-pressure homogenization is better for extracting astaxanthin from yeast cells. Ultrasonication of dimethyl sulfoxide, hexane, and acetone-treated cells yielded less astaxanthin than β-glucanase enzyme-treated cells. The combination of ultrasonication with β-glucanase enzyme is found to be the most efficient method of extraction among all the tested physical and chemical extraction methods. It gives a maximum yield of 435.71 ± 6.55 µg free astaxanthin per gram of yeast cell mass.

  8. Components Comparison of Essential Oil Extracted from Schisandrae Sphenantherae Fructus by Supercritical Fluid CO2 Extraction and Steam Distillation%超临界流体CO2提取法与水蒸汽蒸馏法提取南五味子挥发油的成分比较

    Institute of Scientific and Technical Information of China (English)

    毛日文; 张敏; 徐佐旗; 赵婷; 樊懿娜; 周叶; 仰榴青

    2011-01-01

    Objective To compare the different chemical constituents of essential oil from Schisandrae Sphenantherae Fractus extracted by supercritical fluid C02 extraction (SFE-C02) and steam distillation (SD).Methods The orthogonal test was carried out to determine the optimal extraction conditions according to the yield of essential oil extracted by SFE-C02.The SFE-C02 and SD were used to extract essential oil which was identified by GC-MS.Results The optimal SFE-C02 extraction conditions were as follows: The extraction temperature was 40 ℃, with extraction pressure 15 Mpa and extraction time 3 hours.The average extraction rate of the essential oil by SFE-C02 and SD were 8.2 7% and 1.4 %, and 16 and 24 components were identified by GC-MS analysis, respectively.Conclusion The results indicated that the average extraction rate of essential oil by SFE-C02 was higher than that by SD, and both the components and content of the oil were different.%目的:比较超临界流体CO2提取法和水蒸汽蒸馏法提取南五味子挥发油的主要化学成分.方法:通过正交试验确定超临界流体CO2提取的最佳工艺条件,采用超临界流体CO2提取和水蒸汽蒸馏法提取五味子挥发油,并采用GC-MS方法分析成分.结果:超临界流体CO2提取的最佳工艺条件为提取温度40℃、提取压力15MPa、提取时间3h,在此条件下南五味子挥发油得率为8.2%,鉴定出16个成分.水蒸汽蒸馏法提取南五味子挥发油得率为1.4%,鉴定出24个成分.结论:超临界流体CO2提取南五味子挥发油的得率比水蒸汽蒸馏法高,挥发油的组分和含量均有一定的差异.

  9. 超临界CO2萃取法与水蒸气蒸馏法提取香茅草挥发油化学成分比较%Comparison of Chemical Components in the Essential Oil Extracted by Supercritical CO2 Fluid and Steam Distillation from Cymbopogon citratus

    Institute of Scientific and Technical Information of China (English)

    谢丽莎; 龚志强; 欧阳炜; 黄振园

    2012-01-01

    [Objective] To compare the chemical components in the essential oil extracled by different methods from Cymbopogon citratus (DC. ) Stapf. [ Method] The essential oils were extracted by supercritical CO3 fluid and steam distillation. And then their chemical components were qualitatively and quantitatively analyzed by GC-MS. [Result] 31 components were identified in the essential oil extracted by supercritical CO, fluid from Cymbopogon citratus, accounting for over 91% of the total volatile components; while 17 components were identified in the essential oil extracted by steam distillation, accounting for about 94% of the total components. The essential oil extracted by the two methods had different types and different contents of chemical components, geranial and neral were the most. [ Conclusion ] The essential oil extracted by supercritical C02 fluid is better than that extracted by steam distillation to truly and comprehensively reflect the chemical components in medicines.%[目的]比较不同方法提取的香茅草挥发油化学成分.[方法]采用超临界CO2流体萃取法(SCDE)及水蒸气蒸馏法(SD)从香茅草中提取挥发油,用气相色谱-质谱联用技术(GC-MS)对其化学成分进行定性定量分析.[结果]在超临界CO2流体萃取法提取的挥发油中共鉴定了31种成分,占挥发油总成分的91%以上;在水蒸气蒸馏法提取的挥发油中共鉴定了17种成分,占挥发油的94%以上.2种提取方法得到的挥发油组分及其含量差异较大,含量最高的都是香叶醛和橙花醛.[结论]超临界CO2流体萃取法提取的挥发油比水蒸气蒸馏法能更真实、全面的反映药材中的化学成分.

  10. Use of steam condensing at subatmospheric pressures to reduce Escherichia coli O157:H7 numbers on bovine hide.

    Science.gov (United States)

    McEvoy, J M; Doherty, A M; Sheridan, J J; Blair, I S; McDowell, D A

    2001-11-01

    This study used a laboratory-scale apparatus to apply subatmospheric steam to bovine hide pieces inoculated with Escherichia coli O157:H7 in maximum recovery diluent (MRD) and in high-liquid content and low-liquid content fecal suspensions (HLC fecal and LLC fecal, respectively). The survival of the organism in fecal clods, which were stored for 24 days in a desiccated state, was assessed. Inoculated fecal clods were also treated with subatmospheric steam. Steam treatment at 80 +/- 2 degrees C for 20 s reduced E. coli O157:H7 concentrations on hide inoculated to initial concentrations of approximately 7 log10 CFU/g by 5.46 (MRD inoculum), 4.17 (HLC fecal inoculum), and 5.99 (LLC fecal inoculum) log10 CFU/g. The reductions achieved in samples inoculated with LLC feces were larger than in samples inoculated with HLC feces (P Steam treatment (20 s) of 3-day-old clods reduced surviving E. coli O157:H7 numbers from 4.20 log10 CFU/g to below the limit of detection of the assay used (1.20 log10 CFU/g). This study shows that steam condensing at or below 80 +/- 2 degrees C can reduce E. coli O157:H7 when present on bovine hide, reducing the risk of cross contamination to the carcass during slaughter and dressing.

  11. Multi-model Predictive Control of Ultra-supercritical Coal-fired Power Unit

    Institute of Scientific and Technical Information of China (English)

    Guoliang Wang; Weiwu Yan; Shihe Chen; Xi Zhang; Huihe Shao

    2014-01-01

    The control of ultra-supercritical (USC) power unit is a difficult issue for its characteristic of the nonlinearity, large dead time and coupling of the unit. In this paper, model predictive control (MPC) based on multi-model and double layered optimization is introduced for coordinated control of USC unit. The linear programming (LP) com-bined with quadratic programming (QP) is used in steady optimization for computation of the ideal value of dynamic optimization. Three inputs (i.e. valve opening, coal flow and feedwater flow) are employed to control three outputs (i.e. load, main steam temperature and main steam pressure). The step response models for the dynamic matrix control (DMC) are constructed using the three inputs and the three outputs. Piecewise models are built at selected operation points. Double-layered multi-model predictive controller is implemented in sim-ulation with satisfactory performance.

  12. Hydrogen production from high moisture content biomass in supercritical water

    Energy Technology Data Exchange (ETDEWEB)

    Antal, M.J. Jr.; Xu, X. [Univ. of Hawaii, Honolulu, HI (United States). Hawaii Natural Energy Inst.

    1998-08-01

    By mixing wood sawdust with a corn starch gel, a viscous paste can be produced that is easily delivered to a supercritical flow reactor by means of a cement pump. Mixtures of about 10 wt% wood sawdust with 3.65 wt% starch are employed in this work, which the authors estimate to cost about $0.043 per lb. Significant reductions in feed cost can be achieved by increasing the wood sawdust loading, but such an increase may require a more complex pump. When this feed is rapidly heated in a tubular flow reactor at pressures above the critical pressure of water (22 MPa), the sawdust paste vaporizes without the formation of char. A packed bed of carbon catalyst in the reactor operating at about 650 C causes the tarry vapors to react with water, producing hydrogen, carbon dioxide, and some methane with a trace of carbon monoxide. The temperature and history of the reactor`s wall influence the hydrogen-methane product equilibrium by catalyzing the methane steam reforming reaction. The water effluent from the reactor is clean. Other biomass feedstocks, such as the waste product of biodiesel production, behave similarly. Unfortunately, sewage sludge does not evidence favorable gasification characteristics and is not a promising feedstock for supercritical water gasification.

  13. Studies on supercritical water reactor fuel assemblies using the sub-channel code COBRA-EN

    Energy Technology Data Exchange (ETDEWEB)

    Ammirabile, Luca, E-mail: luca.ammirabile@ec.europa.e [European Commission, JRC, Institute for Energy, Westerduinweg 3, 1755 LE Petten (Netherlands)

    2010-10-15

    In the Generation IV International Forum (GIF) program, the supercritical water reactor (SCWR) concept is among the six innovative reactor types selected for development in the near future. In principle the higher efficiency and better economics make the SCWR concept competitive with the current reactor design. Due to different technical challenges that, however exist, fuel assembly design represents a crucial aspect for the success of this concept. In particular large density variations, low moderation, heat transfer enhancement and deterioration have a strong effect on the core design parameters. Only a few computational tools are currently able to perform sub-channel thermal-hydraulic analysis under supercritical water conditions. At JRC-IE the existing sub-channel code COBRA-EN has been improved to work above the critical pressure of water. The water properties package of the IAPWS Industrial Formulation 1997 was integrated in COBRA-EN to compute the Thermodynamic Properties of Water and Steam. New heat transfer and pressure drop correlations more indicated for the supercritical region of water have also been incorporated in the code. As part of the efforts to appraise the new code capabilities, a code assessment was carried out on the hexagonal fuel assembly of a fast supercritical water reactor. COBRA-EN was also applied in combination with the neutronic code MCNP to investigate on the use of hydride fuel in the HPLWR supercritical water fuel assembly. The results showed that COBRA-EN was able to reproduce the results of similar studies with acceptable accuracy. Future activities will focus on the validation of the code against experimental data and the implementation of new features (counter-current moderator channel, wall, and wire-wrap models).

  14. Study on softening Tilapia backbone by high pressure steam cooking%高压蒸煮软化罗非鱼鱼骨的研究

    Institute of Scientific and Technical Information of China (English)

    吴克刚; 张文祥; 柴向华; 何文龙

    2013-01-01

    To study softening Tilapia backbone by high pressure steam cooking,with pH,cooking pressure,steaming time and material/water ratio for study factors,the hardness of Tilapia backbone was evaluated with its maximum bearable pressure on universal testing machine.Results of single-factor experiments and orthogonal experiments showed that the softening effect of backbone was the best with the treatment condition of pH6.5,pressure of 0.13MPa,steaming time of 75min and material/water ratio of 1∶1.Under this condition,the hardness of Tilapia backbone was 33.0N.%以罗非鱼鱼骨为实验对象,以pH、蒸煮压力、蒸煮时间以及料液比为研究因素,采用万能试验机测量鱼骨最大承受压力来评价其硬度,研究高压蒸煮软化工艺.通过单因素实验及正交实验表明:当pH为6.5、蒸煮压力为0.13MPa、时间为75min、料液比为1∶1时,对鱼骨的软化效果最好,此工艺下所得鱼骨硬度为33.0N.

  15. Energetic approach of biomass hydrolysis in supercritical water.

    Science.gov (United States)

    Cantero, Danilo A; Vaquerizo, Luis; Mato, Fidel; Bermejo, M Dolores; Cocero, M José

    2015-03-01

    Cellulose hydrolysis can be performed in supercritical water with a high selectivity of soluble sugars. The process produces high-pressure steam that can be integrated, from an energy point of view, with the whole biomass treating process. This work investigates the integration of biomass hydrolysis reactors with commercial combined heat and power (CHP) schemes, with special attention to reactor outlet streams. The innovation developed in this work allows adequate energy integration possibilities for heating and compression by using high temperature of the flue gases and direct shaft work from the turbine. The integration of biomass hydrolysis with a CHP process allows the selective conversion of biomass into sugars with low heat requirements. Integrating these two processes, the CHP scheme yield is enhanced around 10% by injecting water in the gas turbine. Furthermore, the hydrolysis reactor can be held at 400°C and 23 MPa using only the gas turbine outlet streams.

  16. Capillary pressure-saturation relations for supercritical CO2 and brine in limestone/dolomite sands: implications for geologic carbon sequestration in carbonate reservoirs.

    Science.gov (United States)

    Wang, Shibo; Tokunaga, Tetsu K

    2015-06-16

    In geologic carbon sequestration, capillary pressure (Pc)-saturation (Sw) relations are needed to predict reservoir processes. Capillarity and its hysteresis have been extensively studied in oil-water and gas-water systems, but few measurements have been reported for supercritical (sc) CO2-water. Here, Pc-Sw relations of scCO2 displacing brine (drainage), and brine rewetting (imbibition) were studied to understand CO2 transport and trapping behavior under reservoir conditions. Hysteretic drainage and imbibition Pc-Sw curves were measured in limestone sands at 45 °C under elevated pressures (8.5 and 12.0 MPa) for scCO2-brine, and in limestone and dolomite sands at 23 °C (0.1 MPa) for air-brine using a new computer programmed porous plate apparatus. scCO2-brine drainage and imbibition curves shifted to lower Pc relative to predictions based on interfacial tension, and therefore deviated from capillary scaling predictions for hydrophilic interactions. Fitting universal scaled drainage and imbibition curves show that wettability alteration resulted from scCO2 exposure over the course of months-long experiments. Residual trapping of the nonwetting phases was determined at Pc = 0 during imbibition. Amounts of trapped scCO2 were significantly larger than for those for air, and increased with pressure (depth), initial scCO2 saturation, and time. These results have important implications for scCO2 distribution, trapping, and leakage potential.

  17. The effect of flow rate at different pressures and temperatures on cocoa butter extracted from cocoa nib using supercritical carbon dioxide.

    Science.gov (United States)

    Asep, E K; Jinap, S; Russly, A R; Jahurul, M H A; Ghafoor, Kashif; Zaidul, I S M

    2016-05-01

    The effects of flow rate, different pressures and temperatures on cocoa butter extracted from cocoa nib using supercritical carbon dioxide (scCO2) were investigated. The yield was analyzed for total fat content, triacylglycerol (TG) profile, and fatty acid (FA) profile. Extractions were carried out at pressures of 20 and 35 MPa, temperatures of 50 and 60 °C, and CO2 flow rates of 0.5, 1, 2, 4 mL min(-1). The result shows that the yield of cocoa butter extract increased with increasing pressure, temperature, and flow rate and the optimum conditions for the maximum cocoa butter extraction were 35 MPa, 60 °C and 2 mL min(-1), repectively. TGs and FAs were found to be similar in composition to those of cocoa butter obtained by conventional methods. The lower molecular weight TGs and FAs showed higher selectivity compared to higher molecular weight TGs and FAs.

  18. 川芎水蒸气蒸馏和超临界CO2提取物化学成分的GC-MS分析鉴别%GC-MS Analysis and Determination of Chemical Components of the Extracts from Ligusticum Chuanxiong Hort.by Steam Distillation and Supercritical CO2 Extraction

    Institute of Scientific and Technical Information of China (English)

    曾志; 谢润乾; 谭丽贤; 张涛

    2011-01-01

    The chemical components of Ligusticum chuanxiong Hort. Were extracted by steam distillation and supercritical C02 extraction, and analyzed by combined capillary gas chromatography-mass spectrometry(GC-MS). Thirty and thirty four compounds were identified, respectively, and their relative contents were determined. This study revealed that the major components of L chuanxiong Hort. By steam distillation and supercritical CO2 extraction were (Z) -ligustilide. The chemical components from L chuanxiong Hort. Extracted by supercritical CO2 extraction possessed more bioactive substances such as butylphthalide, butylidene phthalide, senkyunolide A, (Z)-ligustilide, (E)-ligustilide and senkyunobde I. However, the components from L chuanxiong Hort. Extracted by steam distillation contained more terpenes except for the bioactive substances. Therefore, supercritical CO2 extraction has more productivity than steam distillation for the extraction of the bioactive substances from L chuanxiong Hort. Through the interpretation and summarization of the regular patterns of the lactones with unsaturated and saturated side chains from L. Chuanxiong Hort. , the structures of the lactones with unsaturated side chain such as (Z)-ligustilide, (E)-ligustilide, butylidene phthalide and senkyunolide I as well as the lactones with saturated side chain such as butylphthalide and senkyunolide A have been determined.%用水蒸气蒸馏和超临界CO2提取方法对川芎药材中的化学成分进行提取,用气相色谱-质谱联用技术(GC-MS)对提取物进行分析,分别鉴定出30和34个化合物,测定了其相对含量.结果表明,水蒸气蒸馏和超临界CO2提取物的主要成分均为(Z)-藁本内酯.超临界CO2提取方法能提取出较多的川芎药效物质,如丁基酞内酯、丁烯基酞内酯、川芎内酯A、(Z)-藁本内酯、(E)-藁本内酯和川芎内酯I.而水蒸气蒸馏提取物中除了川芎药效物质外,还含有较多的萜烯类化

  19. Improved Sterilization of Sensitive Biomaterials with Supercritical Carbon Dioxide at Low Temperature: e0129205

    National Research Council Canada - National Science Library

    Anne Bernhardt; Markus Wehrl; Birgit Paul; Thomas Hochmuth; Matthias Schumacher; Kathleen Schütz; Michael Gelinsky

    2015-01-01

    ... sterilization procedures like steam, ethylene oxide treatment or gamma irradiation. Supercritical CO2 (scCO2) treatment is a promising strategy for the terminal sterilization of sensitive biomaterials at low temperature...

  20. Feasibility Study of Supercritical Light Water Cooled Fast Reactors for Actinide Burning and Electric Power Production, 3rd Quarterly Report

    Energy Technology Data Exchange (ETDEWEB)

    Mac Donald, Philip Elsworth

    2002-06-01

    The use of light water at supercritical pressures as the coolant in a nuclear reactor offers the potential for considerable plant simplification and consequent capital and O&M cost reduction compared with current light water reactor (LWR) designs. Also, given the thermodynamic conditions of the coolant at the core outlet (i.e. temperature and pressure beyond the water critical point), very high thermal efficiencies of the power conversion cycle are possible (i.e. up to about 45%). Because no change of phase occurs in the core, the need for steam separators and dryers as well as for BWR-type re-circulation pumps is eliminated, which, for a given reactor power, results in a substantially shorter reactor vessel and smaller containment building than the current BWRs. Furthermore, in a direct cycle the steam generators are not needed.

  1. Steam generator tube failures

    Energy Technology Data Exchange (ETDEWEB)

    MacDonald, P.E.; Shah, V.N.; Ward, L.W.; Ellison, P.G.

    1996-04-01

    A review and summary of the available information on steam generator tubing failures and the impact of these failures on plant safety is presented. The following topics are covered: pressurized water reactor (PWR), Canadian deuterium uranium (CANDU) reactor, and Russian water moderated, water cooled energy reactor (VVER) steam generator degradation, PWR steam generator tube ruptures, the thermal-hydraulic response of a PWR plant with a faulted steam generator, the risk significance of steam generator tube rupture accidents, tubing inspection requirements and fitness-for-service criteria in various countries, and defect detection reliability and sizing accuracy. A significant number of steam generator tubes are defective and are removed from service or repaired each year. This wide spread damage has been caused by many diverse degradation mechanisms, some of which are difficult to detect and predict. In addition, spontaneous tube ruptures have occurred at the rate of about one every 2 years over the last 20 years, and incipient tube ruptures (tube failures usually identified with leak detection monitors just before rupture) have been occurring at the rate of about one per year. These ruptures have caused complex plant transients which have not always been easy for the reactor operators to control. Our analysis shows that if more than 15 tubes rupture during a main steam line break, the system response could lead to core melting. Although spontaneous and induced steam generator tube ruptures are small contributors to the total core damage frequency calculated in probabilistic risk assessments, they are risk significant because the radionuclides are likely to bypass the reactor containment building. The frequency of steam generator tube ruptures can be significantly reduced through appropriate and timely inspections and repairs or removal from service.

  2. Advanced 12% chromium steel and its application to ultra-supercritical turbine. Chocho rinkaiatsu turbine eno kairyo 12 kuromuko no tekiyo

    Energy Technology Data Exchange (ETDEWEB)

    Hadano, Y.; Kubota, T.; Yamada, M. (Toshiba Corp., Tokyo (Japan))

    1993-05-01

    Introduction of high-pressure and high-temperature steam into the turbine directly contributes to the improvement of thermal efficiency of the thermal power plant. The phase 1 of the ultra-supercritical (USC) turbine with steam pressure of 31MPa or more uses the steam of 593[degree]C level which is about 30[degree]C higher than that used for the phase 0. In order to realize high-pressure and high-temperature steam conditions, it is indispensable to improve high-temperature strength such as creep rupture strength of major parts of the turbine. This report describes the development of heat-resistant materials used for this purpose, and, in particular, advanced 12% chromium steel used for high-temperature rotors and blades. About 1.3 times creep rupture strength of the conventional 12Cr has been obtained by CrMoVWNbN steel with optimized alloying element volume and W addition. Moreover, advanced 12Cr cast steel developed for the turbine casing and steam valves, present state of the development of materials for clamping bolts, and improved points in turbine design to realize high-pressure and high-temperature conditions are outlined. 5 refs., 4 figs., 1tab.

  3. 利用低压饱和蒸汽发电的实例%Examples of Power Generation by Use of Low-pressure Saturated Steam

    Institute of Scientific and Technical Information of China (English)

    莫宾; 蔡鸣; 蒋洁

    2011-01-01

    Use of the low-pressure saturated steam which is the byproduct of the patent technology of "thermal phosphoric acid production of heat recovery",for power generation,the problem of excess low-pressure saturated steam in the thermal phosphoric acid production enterprises is solved.Via examples,the performance characteristics of generating units,power generation process and connection considerations with the external network are explained.With this technology,the electricity load in thermal phosphoric acid can be met,product energy consumption and cost can be reduced.It provides a new way for the comprehensive utilization of low-pressure saturated steam in thermal phosphoric acid production for the domestic enterprises.%利用"热法磷酸生产热能回收"专利技术副产的低压饱和蒸汽发电,解决了热法磷酸生产企业低压饱和蒸汽过剩的问题。通过实例,讲述了发电机组的性能特点、发电的工艺流程及与外网联接的注意事项。通过此技术的应用,基本能满足热法磷酸装置用电负荷,可降低产品的能耗和成本,达到节能减排的效果,为国内热法磷酸生产企业和其它行业低压饱和蒸汽的综合利用提供了一条新途径。

  4. Independent Research and Design of 600-MW Supercritical CFB Boiler

    Institute of Scientific and Technical Information of China (English)

    2010-01-01

    In order to further develop and improve the technologies for large-capacity supercritical CFB boiler, the key technologies for large CFB boiler were systematically studied, based on the development of first domestically-made 210-MW and 330-MW CFB boilers. The scheme of 600-MW supercritical CFB boiler was designed, including the furnace structure, key components, steam-water system and auxiliary systems, which laid a technical foundation for the engineering applications.

  5. Numerical simulation of effect of catalyst wire-mesh pressure drop characteristics on flow distribution in catalytic parallel plate steam reformer

    DEFF Research Database (Denmark)

    Sigurdsson, Haftor Örn; Kær, Søren Knudsen

    2012-01-01

    , is considered to investigate the effect of catalyst wire-mesh pressure drop characteristics on flow distribution in the CPHE reformer. Flow distribution in a CPHE reformer is rarely uniform due to inlet and exhaust manifold design. Poorly-designed manifolds may lead to severe flow maldistribution, flow reversal...... in some of the CPHE reformer channels and increased overall pressure drop. Excessive flow maldistribution can significantly reduce the CPHE reformer performance. Detailed three-dimensional models are used to investigate the flow distribution at three different catalyst wire-mesh pressure drop coefficients......Steam reforming of hydrocarbons using a catalytic plate-type-heat-exchanger (CPHE) reformer is an attractive method of producing hydrogen for a fuel cell-based micro combined-heat-and-power system. In this study the flow distribution in a CPHE reformer, which uses a coated wire-mesh catalyst...

  6. Feasibility Study of Supercritical Light Water Cooled Fast Reactors for Actinide Burning and Electric Power Production

    Energy Technology Data Exchange (ETDEWEB)

    Mac Donald, Philip Elsworth; Buongiorno, Jacopo; Davis, Cliff Bybee; Weaver, Kevan Dean

    2002-01-01

    The use of supercritical temperature and pressure light water as the coolant in a direct-cycle nuclear reactor offers potential for considerable plant simplification and consequent capital and O&M cost reduction compared with current light water reactor (LWR) designs. Also, given the thermodynamic conditions of the coolant at the core outlet (i.e. temperature and pressure beyond the water critical point), very high thermal efficiencies of the power conversion cycle are possible (i.e. up to 46%). Because no change of phase occurs in the core, the need for steam separators and dryers as well as for BWR-type recirculation pumps is eliminated, which, for a given reactor power, results in a substantially shorter reactor vessel than the current BWRs. Furthermore, in a direct cycle the steam generators are not needed. If a tight fuel rod lattice is adopted, it is possible to significantly reduce the neutron moderation and attain fast neutron energy spectrum conditions. In this project a supercritical water reactor concept with a simple, blanket-free, pancake-shaped core will be developed. This type of core can make use of either fertile or fertile-free fuel and retain the hard spectrum to effectively burn plutonium and minor actinides from LWR spent fuel while efficiently generating electricity.

  7. 3-D FEM Analysis of Stress Distribution for Connecting Pipe in Mid-pressure Steam Drum%中压汽包接管应力分布的三维有限元分析

    Institute of Scientific and Technical Information of China (English)

    杨伟春; 梁基照

    2000-01-01

    In this paper a stress distribution analysis for connecting pipes in a mid-pressure steam drum has been made by means of the 3-dimensional finite element of ANSYS structure analysis software.The results showed that the maximum values of all kinds of stresses were in the inside of the conjunction area betw een the pipe and the steam-drum cylinder,and these stresses decreased with incre asing distance from this area.

  8. Efficient use of low-temperature and low-pressure steam for heating different media by dynamic steam blending; Effiziente Dampfverwertung von niedrig Temperatur und Niederdruck-Dampf zur Aufheizung verschiedenster Medien mittels dynamischer Dampfeinmischung

    Energy Technology Data Exchange (ETDEWEB)

    Michal, L. [Andritz AG, Graz (Austria); Wallner, C.

    2007-07-01

    In this novel steam blending system, steam is added to the medium to be heated at a high relative speed. The dynamic mixing process provides even and fine distribution of the steam through the medium. The contact surfaces of the various phases of the gaseous steam and the liquid medium are enlarged substantially. This results in rapid and careful heat transfer from the steam to the medium, because the steam condenses immediately, minimizing steam bubbles. The key component consists mainly of a mixer casing and a rotating steam manifold. The steam needed to heat the stock is fed to the manifold through the specially shaped casing. The manifold, which is mounted on the extended motor shaft, rotates at the motor speed. The rotating steam nozzles cover the entire cross-section and 'plough' through the linear medium flow in radial direction. The large contact surfaces between the steam and the medium, as well as preventing local overheating of the medium, obviate condensation surges to a large extent. (orig.)

  9. Using supercritical fluids to refine hydrocarbons

    Science.gov (United States)

    Yarbro, Stephen Lee

    2015-06-09

    A system and method for reactively refining hydrocarbons, such as heavy oils with API gravities of less than 20 degrees and bitumen-like hydrocarbons with viscosities greater than 1000 cp at standard temperature and pressure, using a selected fluid at supercritical conditions. A reaction portion of the system and method delivers lightweight, volatile hydrocarbons to an associated contacting unit which operates in mixed subcritical/supercritical or supercritical modes. Using thermal diffusion, multiphase contact, or a momentum generating pressure gradient, the contacting unit separates the reaction products into portions that are viable for use or sale without further conventional refining and hydro-processing techniques.

  10. Regenerative superheated steam turbine cycles

    Science.gov (United States)

    Fuller, L. C.; Stovall, T. K.

    1980-01-01

    PRESTO computer program was developed to analyze performance of wide range of steam turbine cycles with special attention given to regenerative superheated steam turbine cycles. It can be used to model standard turbine cycles, including such features as process steam extraction, induction and feedwater heating by external sources, peaking, and high back pressure. Expansion line efficiencies, exhaust loss, leakages, mechanical losses, and generator losses are used to calculate cycle heat rate and generator output. Program provides power engineer with flexible aid for design and analysis of steam turbine systems.

  11. 超临界CO2萃取穿心莲内酯的实验研究%Supercritical Carbon Dioxide Extraction of Andrographolide from Andrographis paniculata: Effect of the Solvent Flow Rate,Pressure,and Temperature

    Institute of Scientific and Technical Information of China (English)

    2007-01-01

    Andrographis paniculata Nees has been extensively used for traditional medicine and help against fever,dysentery,diarrhoea,inflammation,and sore throat. In this study,andrographolide,the main component of this plant was extracted from the leaves of A. paniculata using supercritical carbon dioxide. The operating pressures were varied from 7.50 to 20 MPa,the temperatures were varied from 30℃ to 60℃,and the flow rates were varied 3g sample of A. paniculata ground-dried leaves. The measured extraction rate was found to be about 0.0174g of andrographolide per gram of andrographolide present in the leaves per hour of operation. The future studies must focus on the interaction between the various operating parameters such as temperature,pressure,and flow rate of supercritical carbon dioxide.

  12. Tabulated pressure measurements of a NASA supercritical-wing research airplane model with and without fuselage area-rule additions at Mach 0.25 to 1.00

    Science.gov (United States)

    Harris, C. D.; Bartlett, D. W.

    1972-01-01

    Basic pressure measurements were made on a 0.087-scale model of a supercritical wing research airplane in the Langley 8 foot transonic pressure tunnel at Mach numbers from 0.25 to 1.00 to determine the effects on the local aerodynamic loads over the wing and rear fuselage of area-rule additions to the sides of the fuselage. In addition, pressure measurements over the surface of the area-rule additions themselves were obtained at angles of sideslip of approximately - 5 deg, 0 deg, and 5 deg to aid in the structural design of the additions. Except for representative figures, results are presented in tabular form without analysis.

  13. Experimental and Modeling Studies of the Methane Steam Reforming Reaction at High Pressure in a Ceramic Membrane Reactor

    OpenAIRE

    Hacarlioglu, Pelin

    2007-01-01

    This dissertation describes the preparation of a novel inorganic membrane for hydrogen permeation and its application in a membrane reactor for the study of the methane steam reforming reaction. The investigations include both experimental studies of the membrane permeation mechanism and theoretical modeling of mass transfer through the membrane and simulation of the membrane reactor with 1-D and 2-D models. A hydrothermally stable and hydrogen selective membrane composed of silica and a...

  14. Comprehensive Evaluation of a CO2-Capturing NOx-Free Repowering System with Utilization of Middle Pressure Steam in a Thermal Power Plant

    Science.gov (United States)

    Sik Pak, Pyong

    A CO2-capturing NOx-free H2O turbine power generation system is proposed in which middle pressure steam produced in a thermal power plant is utilized to increase generated power when demand for electricity is large. The proposed system can capture all the generated CO2 based on the oxygen combustion method and emits no NOx, so that it causes no urban and global environmental problems. A combined cycle power generation system with 200MW gas turbine power output is adopted as an example of a thermal power plant. It was assumed that 32 t/h of steam with 25kg/cm2 pressure produced at waste heat recovery boiler was utilized in the proposed system.It has been shown through simulation study that increase of power output by 11.8MW or 4.51% of the rated output is possible with no efficiency decrease. The amount of CO2 reduction is estimated to be 19600t/y.The unit cost of generated power is estimated to be 8.38yen/kWh, annual gross profit of the proposed system 271 million yen, depreciation year 4.87, and thus the proposed system is estimated to be economically feasible.

  15. 压力蒸汽灭菌后湿包分析及防控措施%Analysis and control measures of wet pack after pressure steam sterilization

    Institute of Scientific and Technical Information of China (English)

    顾运珠

    2015-01-01

    Objective To analyze and take measures to control the occurrence of wet bag after the pulse vacuum sterilization.Methods By steam quality, pressure cooker loading, overweight package management, packaging material requirements, ensure the drying time, the cooling 30min, personnel management and other measures.Results There was no wet bag after the pressure steam sterilization.Conclusion The establishment of scientific quality standards and operational procedures, to do a good job training, to ensure the quality of sterilization.%目的:通过分析脉动真空灭菌后湿包及采取措施,防控湿包的发生。方法通过蒸汽质量、压力锅装载摆放、超重包管理、包装材料要求、保证干燥时间、出锅后冷却30min、人员管理等措施。结果压力蒸汽灭菌后未发生湿包。结论建立科学的工作质量标准和操作规程,做好人员培训,保证灭菌质量。

  16. Linear parameter-varying modeling and control of the steam temperature in a Canadian SCWR

    Energy Technology Data Exchange (ETDEWEB)

    Sun, Peiwei, E-mail: sunpeiwei@mail.xjtu.edu.cn; Zhang, Jianmin; Su, Guanghui

    2017-03-15

    Highlights: • Nonlinearity of Canadian SCWR is analyzed based on step responses and Nyquist plots. • LPV model is derived through Jacobian linearization and curve fitting. • An output feedback H{sub ∞} controller is synthesized for the steam temperature. • The control performance is evaluated by step disturbances and wide range operation. • The controller can stabilize the system and reject the reactor power disturbance. - Abstract: The Canadian direct-cycle Supercritical Water-cooled Reactor (SCWR) is a pressure-tube type SCWR under development in Canada. The dynamics of the steam temperature have a high degree of nonlinearity and are highly sensitive to reactor power disturbances. Traditional gain scheduling control cannot theoretically guarantee stability for all operating regions. The control performance can also be deteriorated when the controllers are switched. In this paper, a linear parameter-varying (LPV) strategy is proposed to solve such problems. Jacobian linearization and curve fitting are applied to derive the LPV model, which is verified using a nonlinear dynamic model and determined to be sufficiently accurate for control studies. An output feedback H{sub ∞} controller is synthesized to stabilize the steam temperature system and reject reactor power disturbances. The LPV steam temperature controller is implemented using a nonlinear dynamic model, and step changes in the setpoints and typical load patterns are carried out in the testing process. It is demonstrated through numerical simulation that the LPV controller not only stabilizes the steam temperature under different disturbances but also efficiently rejects reactor power disturbances and suppresses the steam temperature variation at different power levels. The LPV approach is effective in solving control problems of the steam temperature in the Canadian SCWR.

  17. SCW Pressure-Channel Nuclear Reactor Some Design Features

    Science.gov (United States)

    Pioro, Igor L.; Khan, Mosin; Hopps, Victory; Jacobs, Chris; Patkunam, Ruban; Gopaul, Sandeep; Bakan, Kurtulus

    Concepts of nuclear reactors cooled with water at supercritical pressures were studied as early as the 1950s and 1960s in the USA and Russia. After a 30-year break, the idea of developing nuclear reactors cooled with SuperCritical Water (SCW) became attractive again as the ultimate development path for water cooling. The main objectives of using SCW in nuclear reactors are: 1) to increase the thermal efficiency of modern Nuclear Power Plants (NPPs) from 30-35% to about 45-48%, and 2) to decrease capital and operational costs and hence decrease electrical energy costs (˜1000 US/kW or even less). SCW NPPs will have much higher operating parameters compared to modern NPPs (pressure about 25 MPa and outlet temperature up to 625°C), and a simplified flow circuit, in which steam generators, steam dryers, steam separators, etc., can be eliminated. Also, higher SCW temperatures allow direct thermo-chemical production of hydrogen at low cost, due to increased reaction rates. Pressure-tube or pressure-channel SCW nuclear reactor concepts are being developed in Canada and Russia for some time. Some design features of the Canadian concept related to fuel channels are discussed in this paper. The main conclusion is that the development of SCW pressure-tube nuclear reactors is feasible and significant benefits can be expected over other thermal-energy systems.

  18. Application of Low-pressure Saturated Steam Power Generating Technology in Steel Enterprises%低压饱和蒸汽发电技术在钢铁企业的应用

    Institute of Scientific and Technical Information of China (English)

    刘颖; 马永锋

    2016-01-01

    介绍了钢铁企业饱和蒸汽发电主要的应用技术,并通过某钢厂的低压饱和蒸汽利用方案,对比了饱和蒸汽汽轮机和饱和蒸汽螺杆发电机应用的优缺点.%The main application technology of saturated steam power generating in steel enterprises is introduced. Taking the utilization program of low-pressure saturated steam pow-er generating of some steelmaker as an example, the advantages and disadvantages of saturat-ed steam turbine generator and saturated steam screw generator are compared.

  19. Steam generated conversion coating on aluminium alloys

    DEFF Research Database (Denmark)

    Din, Rameez Ud; Jellesen, Morten Stendahl; Ambat, Rajan

    pressure steam produced by an autoclave at a temperature of 107 – 121 °C and pressure of 15 -17 psi for 10 minutes to produce a thin coating of aluminium oxide. The aim of this study is to understand the effect of high pressure steam with and without different chemical additives on surface morphology...

  20. 汽轮机低压调节级动叶片水蚀分析%Analysis on Water - Erosion of Moving Blade in Low - pressure Control Stage of a Steam Turbine

    Institute of Scientific and Technical Information of China (English)

    周文远; 朱正写; 王鹏; 纪绣涛

    2012-01-01

    烯烃装置裂解气压缩机组大检修期间发现汽轮机低压调节级动叶片“蜂窝状点蚀”现象比较严重,对应的静叶片及后2级静叶片也有点蚀现象。分析发现利用湿蒸汽对汽轮机吹扫的方法存在缺陷,在主蒸汽降温的过程中只考虑了高压缸防水蚀的影响,忽略了抽汽背压不可控,导致低压缸进汽压力相对该处的进汽温度过高,部分蒸汽产生冷凝液,蒸汽中夹带的水滴撞击在动叶片出汽边背弧上,致使材料疲劳破坏形成水蚀。根据操作经验和理论分析确定:吹扫工况时,低压调节级的进汽压力应低于170℃时的蒸汽饱和压力,抽汽压力应低于0.8MPa,并利用蒸汽管网改造,控制抽汽压力在0.4~1.6MPa。通过优化操作参数完全可以避免低压调节级动叶片水蚀。%Serious "honeycomb pitting corrosions" were found in the moving blades of the steam turbine's low -pressure control stage in the overhaul of the cracked gas compressor train, corresponding stationary blades and after the two - stage stationary blades also had "pitting corrosion". The analysis concluded that there was negligence in the flushing of steam turbine with wet steam. In the process of lowering the steam temperature, only the impact of water erosion of HP cylinder was considered and uncontrollable extracted steam pressure was ignored. These led to excessive higher temperature of inlet steam as compared with the pressure. Condensate was formed from some steam, water droplets entrained in the steam impinged on the back arc of the moving blades, the material was fatigued and water erosion was formed. Based upon the operating experience and theoretical analysis, in flushing operation, the pressure of inlet steam of LP control stage should be lower than steam saturation steam at 170℃, and the pressure of extracted steam should be lower than 0.8 MPa. The pressure of extracted steam was controlled within 0. 4 1

  1. Corrosion in Supercritical carbon Dioxide: Materials, Environmental Purity, Surface Treatments, and Flow Issues

    Energy Technology Data Exchange (ETDEWEB)

    Sridharan, Kumar; Anderson, Mark

    2013-12-10

    The supercritical CO{sub 2} Brayton cycle is gaining importance for power conversion in the Generation IV fast reactor system because of its high conversion efficiencies. When used in conjunction with a sodium fast reactor, the supercritical CO{sub 2} cycle offers additional safety advantages by eliminating potential sodium-water interactions that may occur in a steam cycle. In power conversion systems for Generation IV fast reactors, supercritical CO{sub 2} temperatures could be in the range of 30°C to 650°C, depending on the specific component in the system. Materials corrosion primarily at high temperatures will be an important issue. Therefore, the corrosion performance limits for materials at various temperatures must be established. The proposed research will have four objectives centered on addressing corrosion issues in a high-temperature supercritical CO{sub 2} environment: Task 1: Evaluation of corrosion performance of candidate alloys in high-purity supercritical CO{sub 2}: The following alloys will be tested: Ferritic-martensitic Steels NF616 and HCM12A, austenitic alloys Incoloy 800H and 347 stainless steel, and two advanced concept alloys, AFA (alumina forming austenitic) steel and MA754. Supercritical CO{sub 2} testing will be performed at 450°C, 550°C, and 650°C at a pressure of 20 MPa, in a test facility that is already in place at the proposing university. High purity CO{sub 2} (99.9998%) will be used for these tests. Task 2: Investigation of the effects of CO, H{sub 2}O, and O{sub 2} impurities in supercritical CO{sub 2} on corrosion: Impurities that will inevitably present in the CO{sub 2} will play a critical role in dictating the extent of corrosion and corrosion mechanisms. These effects must be understood to identify the level of CO{sub 2} chemistry control needed to maintain sufficient levels of purity to manage corrosion. The individual effects of important impurities CO, H{sub 2}O, and O{sub 2} will be investigated by adding them

  2. Pressure Control Method for Parallel Boiler Steam Header%并炉蒸汽母管压力控制方案研究

    Institute of Scientific and Technical Information of China (English)

    白安坤

    2013-01-01

    With the development of economy and the progress of science and technology, the development of industrial enterprises is very fast. Under the new industrial development situation, the boiler control system, as the power source of enterprise also needs to follow the step of the era. In this paper, the boiler steam pressure control process are described, and the working process of the system of single boiler and parallel boiler are introduced. Taking the operating system of the parallel as the research object, the problems existing in the original boiler steam pressure control method is found, and according to this, a new header pressure control method is designed, which is greatly helpful for the efficient operation of the boiler system.%随着经济的发展和科技的进步,工业企业的发展势如破竹,在新的工业发展形势下,作为企业动力源的锅炉控制系统也需要跟随时代进行改进。本文对锅炉蒸汽压力的控制过程进行了描述,并对单炉和并炉系统的工作过程进行了介绍,以并炉的运行系统作为研究对象,发现了原始锅炉蒸汽压力控制方案中存在的问题,并针对此,进行了新的锅炉蒸汽母管控制方案的设计,对于锅炉系统的高效运行有着重要的推动作用。

  3. Oxidation performance of high temperature steels and coatings for future supercritical power plants

    Energy Technology Data Exchange (ETDEWEB)

    Auerkari, Pertti; Salonen, Jorma; Toivonen, Aki; Penttilae, Sami [VTT, Espoo (Finland); Haekkilae, Juha [Foster Wheeler Energia, Varkaus (Finland); Aguero, Alina; Gutierrez, Marcos; Muelas, Raul [INTA, Madrid (Spain); Fry, Tony [NPL (United Kingdom)

    2010-07-01

    The operating efficiency of current and future thermal power plants is largely dependent on the applied temperature and pressure, which are in part limited by the internal oxidation resistance of the structural materials in the steam systems. Alternative and reference materials for such systems have been tested within the COST 536 (ACCEPT) project, including bulk reference materials (ferritic P92 and austenitic 316 LN steels) and several types of coatings under supercritical combined (oxygen) water chemistry (150 ppb DO) at 650 C/300 bar. The testing results from a circulating USC autoclave showed that under such conditions the reference bulk steels performed poorly, with extensive oxidation already after relatively short term exposure to the supercritical medium. Better protection was attained by suitable coatings, although there were clear differences in the protective capabilities between different coating types, and some challenges remain in applying (and repairing) coatings for the internal surfaces of welded structures. The materials performance seems to be worse in supercritical than in subcritical conditions, and this appears not to be only due to the effect of temperature. The implications are considered from the point of view of the operating conditions and materials selection for future power plants. (orig.)

  4. Steam Turbines

    Science.gov (United States)

    1981-01-01

    Turbonetics Energy, Inc.'s steam turbines are used as power generating systems in the oil and gas, chemical, pharmaceuticals, metals and mining, and pulp and paper industries. The Turbonetics line benefited from use of NASA research data on radial inflow steam turbines and from company contact with personnel of Lewis Research Center, also use of Lewis-developed computer programs to determine performance characteristics of turbines.

  5. Dependence of Reaction Rate Constants on Density in Supercritical Fluids

    Institute of Scientific and Technical Information of China (English)

    WANGTao; SHENZhongyao

    2002-01-01

    A new method,which correlates rate constants of chemical reactions and density or pressure in supercritical fluids,was developed.Based on the transition state theory and thermodynamic principles, the rate constant can be reasonably correlated with the density of the supercritical fluid,and a correlation equation was obtained. Coupled with the equation of state (EOS) of a supercritical solvent,the effect of pressure on reaction rate constant could be represented.Two typical systems were used to test this method.The result indicates that this method is suitable for dilute supercritical fluid solutions.

  6. Effect of steaming, blanching, and high temperature/high pressure processing on the amino Acid contents of commonly consumed korean vegetables and pulses.

    Science.gov (United States)

    Kim, Su-Yeon; Kim, Bo-Min; Kim, Jung-Bong; Shanmugavelan, Poovan; Kim, Heon-Woong; Kim, So-Young; Kim, Se-Na; Cho, Young-Sook; Choi, Han-Seok; Park, Ki-Moon

    2014-09-01

    In the present report, the effects of blanching, steaming, and high temperature/high pressure processing (HTHP) on the amino acid contents of commonly consumed Korean root vegetables, leaf vegetables, and pulses were evaluated using an Automatic Amino Acid Analyzer. The total amino acid content of the samples tested was between 3.38 g/100 g dry weight (DW) and 21.32 g/100 g DW in raw vegetables and between 29.36 g/100 g DW and 30.55 g/100 g DW in raw pulses. With HTHP, we observed significant decreases in the lysine and arginine contents of vegetables and the lysine, arginine, and cysteine contents of pulses. Moreover, the amino acid contents of blanched vegetables and steamed pulses were more similar than the amino acid contents of the HTHP vegetables and HTHP pulses. Interestingly, lysine, arginine, and cysteine were more sensitive to HTHP than the other amino acids. Partial Least Squares-Discriminate Analyses were also performed to discriminate the clusters and patterns of amino acids.

  7. High-Pressure Enzymatic Hydrolysis to Reveal Physicochemical and Thermal Properties of Bamboo Fiber Using a Supercritical Water Fermenter

    Directory of Open Access Journals (Sweden)

    H. P. S. Abdul Khalil

    2014-10-01

    Full Text Available Bamboo fiber was treated using a high-pressure enzyme hydrolysis process. The process performance was compared with the pulping and bleaching process for bamboo fiber. Several analytical methods, including field emission scanning electron microscopy, Fourier transform infrared spectroscopy, X-ray diffraction, thermogravimetry, and differential scanning calorimetry, were employed to determine the physicochemical and thermal properties of the treated cellulosic bamboo fiber. It was found that the pressurized enzyme hydrolysis treated bamboo fiber had the most uniform morphological structure, along with lowest crystallinity and highest thermal stability. Thus, utilizing high-pressure enzyme hydrolysis is the most effective process for treating fiber to remove non-cellulosic components from the raw material, including lignin, hemicelluloses, and waxy materials.

  8. Research and Application of No Steam and Negative Pressure Ammonia Distillation Process%无蒸汽负压蒸氨工艺的研究与应用

    Institute of Scientific and Technical Information of China (English)

    祝仰勇; 宁述芹; 王贺红; 张顺贤; 叶冰

    2012-01-01

      By redesigning the negative pressure ammonia distillation process, transforming the ammonia distillation tower, increasing the stable vacuum system, selecting different device material, improving the process of adding alkali, adding tail gas recycling device and other reform measures, no steam and negative pressure ammonia distillation was achieved in No.6 and No.7 coke ovens, but also the consumption of coal gas was reduced. The quality of adding alkali negative pressure evaporation ammonia water achieved the requirements of atmospheric pressure ammonia distillation and realized the recovery of all tail gas.%  济钢通过重新设计6#、7#焦炉负压蒸氨工艺流程,改造蒸氨塔,增加稳定的真空系统,选择不同的设备材质,改进加碱工艺,增加尾气回收利用装置等改造措施,实现了无蒸汽负压蒸氨,同时降低了煤气消耗,加碱负压蒸氨废水水质达到了常压蒸氨的要求,尾气实现了全部回收。

  9. Electrochemistry in Near-Critical and Supercritical Fluids. 8. Methyl Viologen, Decamethylferrocene, Os(bpy)3(2+) and Ferrocene in Acetonitrile and the Effect of Pressure on Diffusion Coefficients under Supercritical Conditions

    Science.gov (United States)

    1989-07-20

    Electroanalytical Chemistry The Univeristy of Texas at Austin _rCTEDepartment of Chemistry OT1 isAustin, Texas 78712 0 C T July 20, 1989 Reproduction in whole or...correlated to values calculated by the Stokes- Einstein relation.(’ : (end of abstract) -I--- IM~t I I Submitted to the Journal of Electroanalytical ... Chemistry June 1989 2 INTRODUCTION We report here further studies of electrode reactions in near-critical and supercritical acetonitrile (MeCN). We

  10. Water in supercritical carbon dioxide dyeing

    Directory of Open Access Journals (Sweden)

    Zheng Lai-Jiu

    2015-01-01

    Full Text Available This paper investigates the effect of water serving as entrainer on the dyeing of wool fabrics in supercritical carbon dioxide. Compared with previous supercritical dyeing methods, addition of water makes the dyeing process more effective under low temperature and low pressure. During dyeing process, dyestuff can be uniformly distributed on fabrics’s surface due to water interaction, as a result coloration is enhanced while color difference is decreased.

  11. Influence of Laser Power on the Hardening of Ti6Al4V Low-Pressure Steam Turbine Blade Material for Enhancing Water Droplet Erosion Resistance

    Science.gov (United States)

    Mann, B. S.; Arya, Vivek; Pant, B. K.

    2011-03-01

    To overcome water droplet erosion of Ti6Al4V alloy blade material used in low-pressure steam turbine (LPST) of high-rating nuclear and super critical thermal power plants, high-power diode laser (HPDL) surface treatment at two temperatures corresponding to two different power levels was carried out. During incubation as well as under prolonged erosion testing, the HPDL surface treatment of this alloy has enhanced its resistance significantly. This is due to the formation of fine-grained martensitic (ά) phase due to rapid heating and cooling associated with laser treatment. The droplet erosion test results after HPDL surface treatment on this alloy, SEM, XRD analysis, and residual stresses developed due to HPDL surface treatment are given in this paper.

  12. Drying of foodstuffs by low-pressure superheated steam%食品低压过热蒸汽干燥技甫

    Institute of Scientific and Technical Information of China (English)

    马怡光; 张绪坤; 佘蓉; 魏伟

    2012-01-01

    Superheated steam drying is a new technology developed recently, compared with conventional hot air drying, it has some advantages, such as high drying efficiency, low energy consumption, better products' quality and so on. Drying of foodstuffs with superheated steam features advantages in comparison with traditional hot air drying are absence of oxygen prevents oxidative reactions, rendering a very porous material, easily rehydrated and with a minimum of volume reduction in most cases. Especially, drying of foodstuffs with low-pressure superheated which avoid the disadvantages of products qualities dried use atmospheric pressure or higher, it will be widely developed in the future.%过热蒸汽干燥是近年来发展起来的新技术,和传统的热风对流干燥相比具有干燥效率高、能耗低和干燥产品质量好等优点。过热蒸汽应用于食品的干燥,其显著的特点是能实现无氧或少氧的干燥环境,干燥过程不会出现“硬壳”或“结皮”的现象,消除了进一步干燥可能出现的障碍,产品具有多孔的结构。特别是低压过热蒸汽干燥应用于食品等热敏性物料,避免了过热蒸汽干燥操作温度高,从而影响产品质量的问题,具有广阔的发展前景。

  13. Steam Temperature Control of Plasma Ignition Start of Ultra-Supercritical Unit%超超临界机组等离子点火启动汽温控制

    Institute of Scientific and Technical Information of China (English)

    孙磊

    2013-01-01

    本文介绍了超超临界机组在整套启动期间,采用等离子点火燃煤启动时,易发生的超温等不良现象,分析其原因和危害,并提出了针对性的解决措施。%This paper introduces that the overheating and other undesirable phenomena of ultra supercritical units easily occurred when using plasma ignition to start coal during the entire startup, and analyzes causes and hazards, proposes specific measures.

  14. Solvent adsorption in SFC : Adsorption of methanol under supercritical conditions

    OpenAIRE

    Edström, Emelie

    2015-01-01

    Chromatography is a widely used separation technique including many different modes, for example supercritical fluid chromatography (SFC) which uses a supercritical fluid as mobile phase. A supercritical fluid is achieved when a substance is subjected to a temperature and pressure above the critical point and the boundary between the liquid phase and gas phase is erased. The interest for SFC has increased in recent years, mainly for separation of chiral molecules in the pharmaceutical industr...

  15. Steam generators

    Energy Technology Data Exchange (ETDEWEB)

    Beckmann, G.; Gilli, P.V.; Fritz, K.; Lippitsch, J.

    1975-12-02

    A steam generator is disclosed which is particularly adapted to be used in nuclear power plants. A casing is provided with an inlet and outlet to receive and discharge a primary heating fluid from which heat is to be extracted. A pair of tube plates extend across the interior of the casing at the region of the inlet and outlet thereof, and a plurality of tubes extend along the interior of the casing and are connected in parallel between the tube plates with all of the tubes having open ends communicating with the inlet and outlet of the casing so that the primary heating fluid will flow through the interior of the tubes while a fluid in the casing at the exterior of the tubes will extract heat from the primary fluid. The casing has between the tubes at the region of the inlet a superheating chamber and at the region of the outlet a preheating chamber and between the latter chambers an evaporating chamber, the casing receiving water through an inlet at the preheating chamber and discharging superheated steam through an outlet at the superheating chamber. A separator communicates with the evaporating chamber to receive a mixture of steam and water therefrom for separating the steam from the water and for delivering the separated steam to the superheating chamber.

  16. Methane production from steam-exploded bamboo.

    Science.gov (United States)

    Kobayashi, Fumihisa; Take, Harumi; Asada, Chikako; Nakamura, Yoshitoshi

    2004-01-01

    To convert unutilized plant biomass into a useful energy source, methane production from bamboo was investigated using a steam explosion pretreatment. Methane could not be produced from raw bamboo but methane production was enhanced by steam explosion. The maximum amount of methane produced, i.e., about 215 ml, was obtained from 1 g of exploded bamboo at a steam pressure of 3.53 MPa and a steaming time of 5 min. A negative correlation between the amount of methane produced and the amount of Klason lignin was observed in the methane fermentation of steam-exploded bamboo.

  17. In situ investigation of supercritical CO2 assisted impregnation of drugs into a polymer by high pressure FTIR micro-spectroscopy.

    Science.gov (United States)

    Champeau, M; Thomassin, J-M; Jérôme, C; Tassaing, T

    2015-02-01

    An original experimental set-up combining a FTIR micro-spectrometer with a high pressure cell has been built in order to analyze in situ the impregnation of a solute into microscopic polymer samples, such as fibers or films, subjected to supercritical CO2. Thanks to this experimental set-up, key factors governing the impregnation process can be simultaneously followed such as the swelling of the polymeric matrix, the CO2 sorption, the kinetics of impregnation and the drug loading into the matrix. Moreover, the solute/polymer interactions and the speciation of the solute can be analyzed. We have monitored in situ the impregnation of aspirin and ketoprofen into PEO (Polyethylene Oxide) platelets at T = 40 °C and P = 5; 10 and 15 MPa. The kinetics of impregnation of aspirin was quicker than the one of ketoprofen and the final drug loading was also higher in the case of aspirin. Whereas the CO2 sorption and the PEO swelling remain constant when PEO is just subjected to CO2 under isobaric conditions, we noticed that both parameters can increase while the drug impregnates PEO. Coupling these results with DSC measurements, we underlined the plasticizing effect of the drug that also leads to a decrease in the crystallinity of PEO in situ thus favoring the sorption of CO2 molecules into the matrix and the swelling of the matrix. The plasticizing effect increases with the drug loading. Finally, the speciation of drugs was investigated considering the shift of the carboxyl bands of the drugs. Both drugs were found to be mainly homogeneously dispersed into PEO.

  18. Corrosion in supercritical fluids

    Energy Technology Data Exchange (ETDEWEB)

    Propp, W.A.; Carleson, T.E.; Wai, Chen M.; Taylor, P.R.; Daehling, K.W.; Huang, Shaoping; Abdel-Latif, M.

    1996-05-01

    Integrated studies were carried out in the areas of corrosion, thermodynamic modeling, and electrochemistry under pressure and temperature conditions appropriate for potential applications of supercritical fluid (SCF) extractive metallurgy. Carbon dioxide and water were the primary fluids studied. Modifiers were used in some tests; these consisted of 1 wt% water and 10 wt% methanol for carbon dioxide and of sulfuric acid, sodium sulfate, ammonium sulfate, and ammonium nitrate at concentrations ranging from 0.00517 to 0.010 M for the aqueous fluids. The materials studied were Types 304 and 316 (UNS S30400 and S31600) stainless steel, iron, and AISI-SAE 1080 (UNS G10800) carbon steel. The thermodynamic modeling consisted of development of a personal computer-based program for generating Pourbaix diagrams at supercritical conditions in aqueous systems. As part of the model, a general method for extrapolating entropies and related thermodynamic properties from ambient to SCF conditions was developed. The experimental work was used as a tool to evaluate the predictions of the model for these systems. The model predicted a general loss of passivation in iron-based alloys at SCF conditions that was consistent with experimentally measured corrosion rates and open circuit potentials. For carbon-dioxide-based SCFs, measured corrosion rates were low, indicating that carbon steel would be suitable for use with unmodified carbon dioxide, while Type 304 stainless steel would be suitable for use with water or methanol as modifiers.

  19. Oxy-combustor operable with supercritical fluid

    Energy Technology Data Exchange (ETDEWEB)

    Brun, Klaus; McClung, Aaron M.; Owston, Rebecca A.

    2017-04-04

    An oxy-combustor is provided which comprises a combustion vessel including at least one solid fuel slurry inlet port, at least one oxygen inlet port and at least one supercritical fluid inlet port, wherein the combustion vessel is operable at an operating pressure of at least 1,100 psi; an interior of the combustion vessel comprises a combustion chamber and a supercritical fluid infusion chamber surrounding at least a part of the combustion chamber, the supercritical fluid infusion chamber and the combustion chamber are separated by a porous liner surrounding the combustion chamber, and the supercritical infusion chamber is located between the porous liner and an outer casing of the combustion vessel.

  20. 200 MW汽轮机多背压运行的热经济性分析%An Analysis of the The rmodynamic Effectiveness of a 200 MW Steam Turbine with Mu ltiple Back-pressure Operation

    Institute of Scientific and Technical Information of China (English)

    李勇; 曹祖庆

    2001-01-01

    通过对某200 MW汽轮机采用三背压凝汽器运行相对于单压运 行的凝结水温度、1号低压加热器抽汽量、各排汽缸最末级相对内效率及整机功率的变化 情况的计算,定量分析了200 MW汽轮机采用三背压运行的经济性,并给出了200 MW汽轮机采 用三背压运行冷却水温应满足的条件。%A calculation was conducted of the variation of parameters when a 200 MW steam t urbine employs a triple back-pressure condenser instead of a single back-press ur e one. Such parameters include the condensate temperature, the steam extraction rate of No.1 low-pressure heater, the relative inner efficiency of the last sta g e of various exhaust cylinders and the power output of the turbine unit as a who le. On this basis a quantitative analysis was performed of the thermodynamic eff ectiveness of the 200 MW steam turbine employing the triple back-pressure conde n ser. In addition, also given are the cooling water temperature requirements to b e met by the above-mentioned 200 MW steam turbine unit.

  1. Supercritical Water Reactor (SCWR) - Survey of Materials Research and Development Needs to Assess Viability

    Energy Technology Data Exchange (ETDEWEB)

    Philip E. MacDonald

    2003-09-01

    Supercritical water-cooled reactors (SCWRs) are among the most promising advanced nuclear systems because of their high thermal efficiency [i.e., about 45% vs. 33% of current light water reactors (LWRs)] and considerable plant simplification. SCWRs achieve this with superior thermodynamic conditions (i.e., high operating pressure and temperature), and by reducing the containment volume and eliminating the need for recirculation and jet pumps, pressurizer, steam generators, steam separators and dryers. The reference SCWR design in the U.S. is a direct cycle, thermal spectrum, light-water-cooled and moderated reactor with an operating pressure of 25 MPa and inlet/outlet coolant temperature of 280/500 °C. The inlet flow splits, partly to a down-comer and partly to a plenum at the top of the reactor pressure vessel to flow downward through the core in special water rods to the inlet plenum. This strategy is employed to provide good moderation at the top of the core, where the coolant density is only about 15-20% that of liquid water. The SCWR uses a power conversion cycle similar to that used in supercritical fossil-fired plants: high- intermediate- and low-pressure turbines are employed with one moisture-separator re-heater and up to eight feedwater heaters. The reference power is 3575 MWt, the net electric power is 1600 MWe and the thermal efficiency is 44.8%. The fuel is low-enriched uranium oxide fuel and the plant is designed primarily for base load operation. The purpose of this report is to survey existing materials for fossil, fission and fusion applications and identify the materials research and development needed to establish the SCWR viabilitya with regard to possible materials of construction. The two most significant materials related factors in going from the current LWR designs to the SCWR are the increase in outlet coolant temperature from 300 to 500 °C and the possible compatibility issues associated with the supercritical water environment.

  2. Supercritical CO{sub 2} fluid for chip resistor cleaning

    Energy Technology Data Exchange (ETDEWEB)

    Wang, C.W.; Chang, R.T.; Lin, W.K.; Lin, R.D.; Liang, M.T.; Yang, J.F.; Wang, J.B.

    1999-09-01

    The cleaning ability of supercritical CO{sub 2} was examined on chip resistors. Extraction analyses were made by atomic absorption spectroscopy and the extent of surface cleaning observed by scanning electron microscopy. Experimental results showed that the flow-cleaning process of supercritical CO{sub 2} possessed the advantages of having a superior cleaning ability and permitting a nondrying step. These characteristics strongly suggest that supercritical CO{sub 2} is a superior alternative to the traditional deionized water used in rinsing chip resistors. Moreover, a higher pressure and temperature can benefit the cleaning ability of this novel supercritical CO{sub 2} cleaning technique.

  3. Hydraulic Calculation and Purging Coefficient Determination for High Pressure Steam Network%高压蒸汽管网的水力学计算及吹扫参数确定

    Institute of Scientific and Technical Information of China (English)

    袁良正; 贾金洁

    2016-01-01

    Exampled with a large scale of coal-to-natural gas plant, hydraulic and purging parameters for high pressure and superheated steam pipe network were studied in this article. By using chemical process simulation software ASPEN HYSIS, the model of steam pipeline net was established and then it was calculated, with which the method based on quantitative analysis for calculating steam purging parameters was found.%以某大型煤制天然气项目为例,对高压过热蒸汽管网的水力学及吹扫参数进行研究。采用化工流程模拟软件ASPEN HYSYS对蒸汽管网进行建模计算,找到了一种定量分析计算蒸汽吹扫参数的方法。

  4. Bio-oil production from biomass via supercritical fluid extraction

    Energy Technology Data Exchange (ETDEWEB)

    Durak, Halil, E-mail: halildurak@yyu.edu.tr [Yuzuncu Yıl University, Vocational School of Health Services, 65080, Van (Turkey)

    2016-04-18

    Supercritical fluid extraction is used for producing bio-fuel from biomass. Supercritical fluid extraction process under supercritical conditions is the thermally disruption process of the lignocellulose or other organic materials at 250-400 °C temperature range under high pressure (4-5 MPa). Supercritical fluid extraction trials were performed in a cylindrical reactor (75 mL) in organic solvents (acetone, ethanol) under supercritical conditions with (calcium hydroxide, sodium carbonate) and without catalyst at the temperatures of 250, 275 and 300 °C. The produced liquids at 300 °C in supercritical liquefaction were analyzed and characterized by elemental, GC-MS and FT-IR. 36 and 37 different types of compounds were identified by GC-MS obtained in acetone and ethanol respectively.

  5. Bio-oil production from biomass via supercritical fluid extraction

    Science.gov (United States)

    Durak, Halil

    2016-04-01

    Supercritical fluid extraction is used for producing bio-fuel from biomass. Supercritical fluid extraction process under supercritical conditions is the thermally disruption process of the lignocellulose or other organic materials at 250-400 °C temperature range under high pressure (4-5 MPa). Supercritical fluid extraction trials were performed in a cylindrical reactor (75 mL) in organic solvents (acetone, ethanol) under supercritical conditions with (calcium hydroxide, sodium carbonate) and without catalyst at the temperatures of 250, 275 and 300 °C. The produced liquids at 300 °C in supercritical liquefaction were analyzed and characterized by elemental, GC-MS and FT-IR. 36 and 37 different types of compounds were identified by GC-MS obtained in acetone and ethanol respectively.

  6. Supercritical fluid technology

    Energy Technology Data Exchange (ETDEWEB)

    Penninger, J.M.L.; McHugh, M.A.; Radosz, M.; Krukonis, V.J.

    1985-01-01

    This book presents the state-of-the-art in the science and technology of supercritical fluid (scf) processing. Current research as described in the book, focuses on developments in equations of state for binary and multicomponent mixtures (including polymer solutions), solubility measurements at near-critical conditions, measurements of critical properties of binary mixtures and their correlation with equations of state. Progress in thermodynamics, coupled with advances in the design and construction of high pressure equipment, has opened up a wide avenue of commercial application (e.g. decaffeination of coffee beans, extractions of flavours and spices, purification of pharmaceutical products, separations of polymeric materials, deodorization and deacidification of vegetable oils, fractionation of fatty acids, coal liquefaction, wood delignitication, etc.)

  7. Molecular dynamics simulation of the key characteristics of the supercritical CO2-pentaerythritol tetraacetate system

    Science.gov (United States)

    Lei, Peiyu; Jin, Zunlong; Liu, Hong; Wang, Dingbiao; Liu, Donglai

    2016-12-01

    Supercritical CO2 is widely used in many fields of industry. Investigation of statistical mechanics of CO2 fluid under quasi critical and supercritical state has great significance. Equilibrium molecular dynamics (EMD) simulations are carried out to investigate the statistical mechanics and macroscopic performance of CO2 fluid under the quasi critical and supercritical state. The results show that the bond length and bond angle distributions for supercritical CO2 are Gaussian distribution basically. The dimers' proportion of supercritical CO2 system changes with pressure increasing. T-type dimer has high share within the system when pressure is higher than 9MPa. It can be inferred that T-type dimer leads to CO2 physical properties changing tempestuously under supercritical state. The effect that lubricating oil has on microstructure and heat transfer of supercritical CO2 is also investigated in the present work. The results show the lubricating oil produces significant effect on the dimers' structure under low pressure.

  8. Processing of Advanced Cast Alloys for A-USC Steam Turbine Applications

    Science.gov (United States)

    Jablonski, Paul D.; Hawk, Jeffery A.; Cowen, Christopher J.; Maziasz, Philip J.

    2012-02-01

    The high-temperature components within conventional supercritical coal-fired power plants are manufactured from ferritic/martensitic steels. To reduce greenhouse-gas emissions, the efficiency of pulverized coal steam power plants must be increased to as high a temperature and pressure as feasible. The proposed steam temperature in the DOE/NETL Advanced Ultra Supercritical power plant is high enough (760°C) that ferritic/martensitic steels will not work for the majority of high-temperature components in the turbine or for pipes and tubes in the boiler due to temperature limitations of this class of materials. Thus, Ni-based superalloys are being considered for many of these components. Off-the-shelf forged nickel alloys have shown good promise at these temperatures, but further improvements can be made through experimentation within the nominal chemistry range as well as through thermomechanical processing and subsequent heat treatment. However, cast nickel-based superalloys, which possess high strength, creep resistance, and weldability, are typically not available, particularly those with good ductility and toughness that are weldable in thick sections. To address those issues related to thick casting for turbine casings, for example, cast analogs of selected wrought nickel-based superalloys such as alloy 263, Haynes 282, and Nimonic 105 have been produced. Alloy design criteria, melt processing experiences, and heat treatment are discussed with respect to the as-processed and heat-treated microstructures and selected mechanical properties. The discussion concludes with the prospects for full-scale development of a thick section casting for a steam turbine valve chest or rotor casing.

  9. Supercritical Water Mixture (SCWM) Experiment

    Science.gov (United States)

    Hicks, Michael C.; Hegde, Uday G.

    2012-01-01

    The subject presentation, entitled, Supercritical Water Mixture (SCWM) Experiment, was presented at the International Space Station (ISS) Increment 33/34 Science Symposium. This presentation provides an overview of an international collaboration between NASA and CNES to study the behavior of a dilute aqueous solution of Na2SO4 (5% w) at near-critical conditions. The Supercritical Water Mixture (SCWM) investigation, serves as important precursor work for subsequent Supercritical Water Oxidation (SCWO) experiments. The SCWM investigation will be performed in DECLICs High Temperature Insert (HTI) for the purpose of studying critical fluid phenomena at high temperatures and pressures. The HTI includes a completely sealed and integrated test cell (i.e., Sample Cell Unit SCU) that will contain approximately 0.3 ml of the aqueous test solution. During the sequence of tests, scheduled to be performed in FY13, temperatures and pressures will be elevated to critical conditions (i.e., Tc = 374C and Pc = 22 MPa) in order to observe salt precipitation, precipitate agglomeration and precipitate transport in the presence of a temperature gradient without the influences of gravitational forces. This presentation provides an overview of the motivation for this work, a description of the DECLIC HTI hardware, the proposed test sequences, and a brief discussion of the scientific research objectives.

  10. Welding and assembly process of 1000 MW ultra-supercritical steam turbine generator frame%1000WM超超临界汽轮发电机机座装焊工艺研究

    Institute of Scientific and Technical Information of China (English)

    侯勇; 李明

    2012-01-01

    分析了1000 MW超超临界汽轮发电机定子机座的结构,该汽发定子机座尺寸大、制造难度高.为了满足制造技术要求,提出以汽端和励端分别为基准,机座分两段进行装配焊接,然后再将两段总装的焊接装配方案.有效地控制了装配尺寸,防止焊接变形,确保机座装配质量满足设计要求.%According to stator frame structure analysis of 1000MW Ultra-supercritical turbine generator,this .stator frame with big size would be fabricated very difficult meeting the design standards.This article puts forward a welding assembly proposal: taking turbine end and exciter side as the bases to weld the frame in two separate sections,then to combine the two sections together.The article also discusses measures of controlling assembly size to prevent welding deformation in order to ensure the final welding assembly quality of turbine frame so as to meet the design standards.

  11. BP neural network based online prediction of steam turbine exhaust dryness

    Institute of Scientific and Technical Information of China (English)

    XIE Danmei; CHEN Chang; XIONG Yangheng; GAO Shang; WANG Chun

    2014-01-01

    In large scale condensing turbine unit,the exhaust status always lies in wet steam area.Due to the lack of effective measuring method,the exhaust dryness of the steam turbine is difficult to obtain di-rectly,which has been the difficult problem in online economic analysis for thermal power units.By taking an N1000-25/600/600 ultra-supercritical steam turbine as an example,the nonlinear mapping ability of BP neural network was used to establish a model which can reflect the relationship between exhaust dryness and unit load and exhaust pressure.After learning and training under some typical conditions,this model was used for exhaust dryness online calculation under full condition.The results show the final error of the training samples and verifying samples were controlled within -0.006 1 and -0.001 0,which satisfies the accuracy requirement for engineering calculation,indicating the established BP neural network can be used in exhaust dryness prediction.

  12. Optimizing steam flood performance utilizing a new and highly accurate two phase steam measurement system

    Energy Technology Data Exchange (ETDEWEB)

    Huff, B. D.; Warren, P. B. [CalResources LLC (Canada); Whorff, F. [ITT Barton (Canada)

    1995-11-01

    The development of a two phase steam measurement system was documented. The system consists of a `V` cone differential pressure device and a vortex meter velocity device in series through which the steam flows. Temperature and pressure sensors are electronically interfaced with a data logging system. The design was described as being very simple and rugged, consequently, well suited to monitoring in the field.. Steam quality measurements were made in the Kern River Field and the Coalinga Field thermal projects using a surface steam separator. In steam flood operations, steam cost is very high, hence appropriate distribution of the steam can result in significant cost reduction. This technology allows the measurement of steam flow and quality at any point in the steam distribution system. The metering system`s orifice meter was found to have a total average error of 45%, with 25% of that attributable to `cold leg` problem. Installation of the metering system was expected to result in a steam use reduction of 8%, without any impact on production. Steam re-distribution could result in a potential oil production increase of 10%. 12 refs., 8 tabs., 9 figs.

  13. Supercritical fluid extraction

    Science.gov (United States)

    Wai, Chien M.; Laintz, Kenneth

    1994-01-01

    A method of extracting metalloid and metal species from a solid or liquid material by exposing the material to a supercritical fluid solvent containing a chelating agent. The chelating agent forms chelates that are soluble in the supercritical fluid to allow removal of the species from the material. In preferred embodiments, the extraction solvent is supercritical carbon dioxide and the chelating agent is a fluorinated or lipophilic crown ether or fluorinated dithiocarbamate. The method provides an environmentally benign process for removing contaminants from industrial waste without using acids or biologically harmful solvents. The chelate and supercritical fluid can be regenerated, and the contaminant species recovered, to provide an economic, efficient process.

  14. Steam Flooding after Steam Soak in Heavy Oil Reservoirs through Extended-reach Horizontal Wells

    Institute of Scientific and Technical Information of China (English)

    Ning Zhengfu; Liu Huiqing; Zhang Hongling

    2007-01-01

    This paper presents a new development scheme of simultaneous injection and production in a single horizontal well drilled for developing small block reservoirs or offshore reservoirs.It is possible to set special packers within the long completion horizontal interval to establish an injection zone and a production zone.This method can also be used in steam flooding after steam soak through a horizontal well.Simulation results showed that it was desirable to start steam flooding after six steam soaking cycles and at this time the oil/steam ratio was 0.25 and oil recovery efficiency was 23.48%.Steam flooding performance was affected by separation interval and steam injection rate.Reservoir numerical simulation indicated that maximum oil recovery would be achieved at a separation section of 40-50 m at steam injection rate of 100-180 t/d; and the larger the steam injection rate,the greater the water cut and pressure difference between injection zone and production zone.A steam injection rate of 120 t/d was suitable for steam flooding under practical injection-production conditions.All the results could be useful for the guidance of steam flooding projects.

  15. US-UK Phase 3 Task 1 Oxidation in Supercritical Fluids

    Energy Technology Data Exchange (ETDEWEB)

    Holcomb, Gordon R. [National Energy Technology Lab. (NETL), Albany, OR (United States)

    2017-03-20

    A presentation of the US-UK Phase 3 Task 1 Oxidation in Supercritical Fluids. Includes slides on Supercritical Steam, sCO2 Power Cycles – Indirect, sCO2 Power Cycles – Direct, Experimental Exposures, Alloys, Why Si, Results—Ni-xCr Alloys (5-24Cr), Fatigue Crack Growth$-$Experiment, and Alloys and Samples, Fatigue Crack Growth—Results (H282).

  16. Advanced Thermal Storage for Central Receivers with Supercritical Coolants

    Energy Technology Data Exchange (ETDEWEB)

    Kelly, Bruce D.

    2010-06-15

    The principal objective of the study is to determine if supercritical heat transport fluids in a central receiver power plant, in combination with ceramic thermocline storage systems, offer a reduction in levelized energy cost over a baseline nitrate salt concept. The baseline concept uses a nitrate salt receiver, two-tank (hot and cold) nitrate salt thermal storage, and a subcritical Rankine cycle. A total of 6 plant designs were analyzed, as follows: Plant Designation Receiver Fluid Thermal Storage Rankine Cycle Subcritical nitrate salt Nitrate salt Two tank nitrate salt Subcritical Supercritical nitrate salt Nitrate salt Two tank nitrate salt Supercritical Low temperature H2O Supercritical H2O Two tank nitrate salt Supercritical High temperature H2O Supercritical H2O Packed bed thermocline Supercritical Low temperature CO2 Supercritical CO2 Two tank nitrate salt Supercritical High temperature CO2 Supercritical CO2 Packed bed thermocline Supercritical Several conclusions have been drawn from the results of the study, as follows: 1) The use of supercritical H2O as the heat transport fluid in a packed bed thermocline is likely not a practical approach. The specific heat of the fluid is a strong function of the temperatures at values near 400 °C, and the temperature profile in the bed during a charging cycle is markedly different than the profile during a discharging cycle. 2) The use of supercritical CO2 as the heat transport fluid in a packed bed thermocline is judged to be technically feasible. Nonetheless, the high operating pressures for the supercritical fluid require the use of pressure vessels to contain the storage inventory. The unit cost of the two-tank nitrate salt system is approximately $24/kWht, while the unit cost of the high pressure thermocline system is nominally 10 times as high. 3) For the supercritical fluids, the outer crown temperatures of the receiver tubes are in the range of 700 to 800 °C. At temperatures of 700 °C and above

  17. Characteristics of compressible flow of supercritical kerosene

    Institute of Scientific and Technical Information of China (English)

    Feng-Quan Zhong; Xue-Jun Fan; Jing Wang; Gong Yu; Jian-Guo Li

    2012-01-01

    In this paper,compressible flow of aviation kerosene at supercritical conditions has been studied both numerically and experimentally.The thermophysical properties of supercritical kerosene are calculated using a 10-species surrogate based on the principle of extended corresponding states (ECS).Isentropic acceleration of supercritical kerosene to subsonic and supersonic speeds has been analyzed numerically.It has been found that the isentropic relationships of supercritical kerosene are significantly different from those of ideal gases.A two-stage fuel heating and delivery system is used to heat the kerosene up to a temperature of 820 K and pressure of 5.5 MPa with a maximum mass flow rate of 100 g/s.The characteristics of supercritical kerosene flows in a converging-diverging nozzle (Laval nozzle) have been studied experimentally.The results show that stable supersonic flows of kerosene could be established in the temperature range of 730 K-820 K and the measurements in the wall pressure agree with the numerical calculation.

  18. 超临界二氧化碳萃取及水蒸气蒸馏法提取降香挥发油及其GC-MS分析%Analyze on Chemical Compositions of Dalbergia odorifera Essential Oils Extracted by CO2-Supercritical-Fluid-Extraction and Steam Distillation Extraction

    Institute of Scientific and Technical Information of China (English)

    宋伟峰; 廖美金; 罗淑媛

    2011-01-01

    目的:用超临界二氧化碳萃取及水蒸气蒸馏法提取降香挥发油,并对挥发油进行GC-MS分析.方法:采用超临界二氧化碳萃取法(SFE-CO2)及水蒸气蒸馏法提取降香挥发油,并应用气相色谱-质谱联用(GC-MS)技术分析挥发油的化学成分,用峰面积归一法测定各化合物的相对含量.结果:在超临界CO2提取物中共鉴定出12种化合物,占总峰面积的34.49%,含量最高的是橙花叔醇(14.95%)、2-丙烯酸3-(4-甲氧基)乙酯(14.53%)、胜红蓟色烯(1.33%).在水蒸气蒸馏法提取的降香挥发油中共鉴定出9种化合物,占总峰面积的30.62%,含量最高的是橙花叔醇(26.61%)、雪松醇(1.65%).结论:超临界法较水蒸气法更加稳定可靠、重现性好,适用于降香挥发油的提取.%Objective;To analyze the chemical compositions of Dalbergia odorifera essential oils extacted by CO2-supercritical-fluid-extraction (SFE-CO2)and steam distillation extraction (SD). Methods:The essential oils of Dalbergia odorifera were extracted by steam distillation extraction and SFE-CO2. The chemical components were separated and analyzed by gas chromatography-mass spec-trometry. Results: 12 compounds were identified in SFE sample. The major components from essential oils were 2-propenoic acid-3(4-methoxyphenyl)-ethyl ester( 14. 53% ), nerolidol( 14. 95% ), ageratochromene(1. 33% ). 9 compounds were identified in SD sample. The major components from essential oils were nerolidol(26. 61% ) ,cedrol( 1. 65% ). Conclusion:The SFE method is better than the SD method in reliability stability and reproducibility, and suitable for essential oils extraction of Dalbergia odorifera.

  19. Supercritical Fluid Extraction of Aflatoxin B 1 from Soil

    Science.gov (United States)

    This research describes the development of a Supercritical Fluid Extraction (SFE) method to recover aflatoxin B1 from fortified soil. The effects of temperature, pressure, modifier (identity and percentage), and extraction type were assessed. Using the optimized SFE conditions, ...

  20. Supercritical Fluid Extraction of Aflatoxin B 1 from Soil

    Science.gov (United States)

    This research describes the development of a Supercritical Fluid Extraction (SFE) method to recover aflatoxin B1 from fortified soil. The effects of temperature, pressure, modifier (identity and percentage), and extraction type were assessed. Using the optimized SFE conditions, ...

  1. How to compute the power of a steam turbine with condensation, knowing the steam quality of saturated steam in the turbine discharge

    Energy Technology Data Exchange (ETDEWEB)

    Hernandez Albarran, Manuel Jaime; Krever, Marcos Paulo Souza [Braskem, Sao Paulo, SP (Brazil)

    2009-07-01

    To compute the power and the thermodynamic performance in a steam turbine with condensation, it is necessary to know the quality of the steam in the turbine discharge and, information of process variables that permit to identifying with high precision the enthalpy of saturated steam. This paper proposes to install an operational device that will expand the steam from high pressure point on the shell turbine to atmosphere, both points with measures of pressure and temperature. Arranging these values on the Mollier chart, it can be know the steam quality value and with this data one can compute the enthalpy value of saturated steam. With the support of this small instrument and using the ASME correlations to determine the equilibrium temperature and knowing the discharge pressure in the inlet of surface condenser, the absolute enthalpy of the steam discharge can be computed with high precision and used to determine the power and thermodynamic efficiency of the turbine. (author)

  2. 火电机组回热系统抽汽压损对火用损分布的影响%The influence of extraction steam pressure loss to exergy loss in reheating system of thermal power unit

    Institute of Scientific and Technical Information of China (English)

    黄超; 房林铁; 王慧兴

    2012-01-01

    抽汽压损是一种不明显的热力损失,对机组的热经济性产生一定的影响。假定抽汽口的压力不变,加热器端差不变,根据小扰动理论,定性分析抽汽压损对回热系统的影响。根据热力系统热平衡原理和汽水分布方程建立抽汽压损对回热系统抽汽系数影响的数学模型。根据火用平衡原理和火用分析法建立抽汽压损对火用损分布的影响的数学模型。以某电厂N1000—25/600/600机组热力系统为例,在TRL工况下,定量计算回热系统抽汽系数和火用损分布的变化。根据定量计算结果从理论上分析了抽汽压损对热力系统产生的影响。%Extraction pressure loss is a kind of tmconspicuons heat loss,and has some impacts on the unit's thermal econotmy. Assuming the constant pressure, of extraction port and temperature difference of the heater, qualitative analysis about the influence of changes is made to extraction steam pres-sure loss to heat system according to small disturbance theory. From heating system heat balance principle and steam water distribution equation, it establishes the mathenutical model about the influence of extraction steam pressure loss to abstract coefficient of the reheating system. The mathematical motel about the influence of extraction steam pressure less to exergy loss distribution is established combining exergy balance principle and exergy analysis. The change on extraction coefficient and exergy loss of reheating system is calculated on a N1000 -25/600/600 unit thermal system in TRL condition. On the basis of quantitative results, it analyzes the effect of extraction steam pressure loss to heat system in theory.

  3. Advanced Supercritical Carbon Dioxide Brayton Cycle Development

    Energy Technology Data Exchange (ETDEWEB)

    Anderson, Mark [Univ. of Wisconsin, Madison, WI (United States); Sienicki, James [Argonne National Lab. (ANL), Argonne, IL (United States); Moisseytsev, Anton [Argonne National Lab. (ANL), Argonne, IL (United States); Nellis, Gregory [Univ. of Wisconsin, Madison, WI (United States); Klein, Sanford [Univ. of Wisconsin, Madison, WI (United States)

    2015-10-21

    Fluids operating in the supercritical state have promising characteristics for future high efficiency power cycles. In order to develop power cycles using supercritical fluids, it is necessary to understand the flow characteristics of fluids under both supercritical and two-phase conditions. In this study, a Computational Fluid Dynamic (CFD) methodology was developed for supercritical fluids flowing through complex geometries. A real fluid property module was implemented to provide properties for different supercritical fluids. However, in each simulation case, there is only one species of fluid. As a result, the fluid property module provides properties for either supercritical CO2 (S-CO2) or supercritical water (SCW). The Homogeneous Equilibrium Model (HEM) was employed to model the two-phase flow. HEM assumes two phases have same velocity, pressure, and temperature, making it only applicable for the dilute dispersed two-phase flow situation. Three example geometries, including orifices, labyrinth seals, and valves, were used to validate this methodology with experimental data. For the first geometry, S-CO2 and SCW flowing through orifices were simulated and compared with experimental data. The maximum difference between the mass flow rate predictions and experimental measurements is less than 5%. This is a significant improvement as previous works can only guarantee 10% error. In this research, several efforts were made to help this improvement. First, an accurate real fluid module was used to provide properties. Second, the upstream condition was determined by pressure and density, which determines supercritical states more precise than using pressure and temperature. For the second geometry, the flow through labyrinth seals was studied. After a successful validation, parametric studies were performed to study geometric effects on the leakage rate. Based on these parametric studies, an optimum design strategy for the see

  4. Design of Multi Cleaning System Using Steam

    Directory of Open Access Journals (Sweden)

    Abhijeetsinh v Makwana

    2016-11-01

    Full Text Available The multi cleaning system is supposed to be system that uses steam which can clean up things that are used by human in day to day life. The commercial detergent washers are compared with the system and it was found that the washing is very convenient and soapy forms are not produced that made the washing very clumsy. The removal of bacterial populations formed on surface of any material would be totally eradicated. The surface to be cleaned are given bath with steam with high pressure from 3 bar to 7 bar by which removal of dirt and stain particles were washed off very comfortably. High pressure steam would be generated by heat the water in the tank which will mounted on the system itself. The reason behind using the steam for washing purpose is the less wastage of water and also its availability. The development of steam based cleaning system has revolutionized the process of washing. One can choose an appropriate type of high power steam cleaners for challenging cleaning applications in office, commercial and industrial settings. The steam does that thing that commercial washing system cannot do. A steam can remove grease and grime while for normal cleaning requires expensive detergents. The multi cleaning system cannot be only used for industrial use but also for the housework stuff. So our prime focus is to use the steam and make multiple cleaning

  5. Supercritical hydrogenation and acid-catalysed reactions "without gases".

    Science.gov (United States)

    Hyde, Jason R; Poliakoff, Martyn

    2004-07-07

    The high temperature catalytic decomposition of HCO2H and HCO2Et are used to generate the high pressure H2 and the supercritical fluids needed for micro-scale hydrogenation of organic compounds; our approach overcomes the problems and limitations of handling high pressure gases on a small-scale and opens the way to the widespread use of continuous supercritical reactions in the laboratory.

  6. Cogeneration turbine unit with a new T-295/335-23.5 steam turbine

    Science.gov (United States)

    Valamin, A. E.; Kultyshev, A. Yu.; Shibaev, T. L.; Gol'dberg, A. A.; Sakhnin, Yu. A.; Stepanov, M. Yu.; Shekhter, M. V.; Bilan, V. N.; Polyaeva, E. N.

    2016-11-01

    The design, schematics, and arrangement of a T-295/335-23.5 turbine and the basic features of a steam-turbine unit (STU) intended for replacement of STUs with a T-250/300-23.5 turbine with the expired service life and installed in large cities, such as Moscow, St. Petersburg, Kiev, Minsk, and Kharkov, for heat and power generation are considered. The basic solutions for an automatic electrohydraulic control and protection system using high-pressure (HP) technology are described. As the turbine operates in a power unit together with a supercritical boiler and the design turbine service life of 250000 hours must be attained, turbine component construction materials complying with these requirements are listed.

  7. 46 CFR 61.15-5 - Steam piping.

    Science.gov (United States)

    2010-10-01

    ... 46 Shipping 2 2010-10-01 2010-10-01 false Steam piping. 61.15-5 Section 61.15-5 Shipping COAST... Periodic Tests of Piping Systems § 61.15-5 Steam piping. (a) Main steam piping shall be subjected to a.... If the covering of the piping is not removed, the test pressure shall be maintained on the piping...

  8. Effect of supercritical fluid density on nanoencapsulated drug particle size using the supercritical antisolvent method.

    Science.gov (United States)

    Kalani, Mahshid; Yunus, Robiah

    2012-01-01

    The reported work demonstrates and discusses the effect of supercritical fluid density (pressure and temperature of supercritical fluid carbon dioxide) on particle size and distribution using the supercritical antisolvent (SAS) method in the purpose of drug encapsulation. In this study, paracetamol was encapsulated inside L-polylactic acid, a semicrystalline polymer, with different process parameters, including pressure and temperature, using the SAS process. The morphology and particle size of the prepared nanoparticles were determined by scanning electron microscopy and transmission electron microscopy. The results revealed that increasing temperature enhanced mean particle size due to the plasticizing effect. Furthermore, increasing pressure enhanced molecular interaction and solubility; thus, particle size was reduced. Transmission electron microscopy images defined the internal structure of nanoparticles. Thermal characteristics of nanoparticles were also investigated via differential scanning calorimetry. Furthermore, X-ray diffraction pattern revealed the changes in crystallinity structure during the SAS process. In vitro drug release analysis determined the sustained release of paracetamol in over 4 weeks.

  9. Steam Drum Design for Direct Steam Generation

    OpenAIRE

    Willwerth, Lisa; Müller, Svenja; Krüger, Joachim; Succo, Manuel; Feldhoff, Jan Fabian; Tiedemann, Jörg; Pandian, Juvaraj; Krüger, Dirk; Hennecke, Klaus

    2016-01-01

    For the direct steam generation in solar fields, the recirculation concept has been demonstrated in several installations. Water masses in the solar field vary during transient phases, such as passing clouds. The volume of the steam drum can serve as a buffer during such transients by taking in excess water and providing water storage. The saturated steam mass flow to the superheating section or the consumer can be maintained almost constant during short transients; therefore the steam drum p...

  10. Supercritical-Multiple-Solvent Extraction From Coal

    Science.gov (United States)

    Corcoran, W.; Fong, W.; Pichaichanarong, P.; Chan, P.; Lawson, D.

    1983-01-01

    Large and small molecules dissolve different constituents. Experimental apparatus used to test supercritical extraction of hydrogen rich compounds from coal in various organic solvents. In decreasing order of importance, relevant process parameters were found to be temperature, solvent type, pressure, and residence time.

  11. HVOF coatings for steam oxidation protection

    Energy Technology Data Exchange (ETDEWEB)

    Agueero, A.; Muelas, R.; Gonzalez, V. [Instituto Nacional de Tecnica Aeroespacial (INTA), Area de Materiales Metalicos, Madrid (Spain)

    2008-05-15

    In the context of the European project 'Coatings for Supercritical Steam Cycles' (SUPERCOAT), the use of steam oxidation resistant coatings on currently available ferritic materials with high creep strength but poor oxidation resistance was investigated in order to allow increase in the operating temperature of steam power plants from 550 to 650 C. Among the explored coating techniques for this application, chosen on the basis of being potentially appropriate for coating steam turbine components, High Velocity Oxy Fuel (HVOF) thermal spray has resulted in one of the most successful techniques. Different alloyed materials such as FeCrAl, NiCrSiFeB, FeAl, NiCr and FeCr have been deposited, optimized and tested under flowing steam at 650 C. Characterization of as deposited and tested samples by metallography, SEM-EDS and XRD was carried out. Some of these coatings form protective pure chromium or aluminium oxides exhibiting excellent behaviour for at least 15 000 h of exposure, whereas others form less stable complex mixed oxides which nevertheless grow at considerably slower rates than the oxides formed on uncoated P92 (9 wt%Cr ferritic steel). (Abstract Copyright [2008], Wiley Periodicals, Inc.)

  12. Analysis of experimental characteristics of multistage steam-jet electors of steam turbines

    Science.gov (United States)

    Aronson, K. E.; Ryabchikov, A. Yu.; Brodov, Yu. M.; Brezgin, D. V.; Zhelonkin, N. V.; Murmanskii, I. B.

    2017-02-01

    A series of questions for specification of physical gas dynamics model in flow range of steam-jet unit and ejector computation methodology, as well as functioning peculiarities of intercoolers, was formulated based on analysis of experimental characteristics of multistage team-jet steam turbines. It was established that coefficient defining position of critical cross-section of injected flow depends on characteristics of the "sound tube" zone. Speed of injected flow within this tube may exceed that of sound, and pressure jumps in work-steam decrease at the same time. Characteristics of the "sound tube" define optimal axial sizes of the ejector. According to measurement results, the part of steam condensing in the first-stage coolant constitutes 70-80% of steam amount supplied into coolant and is almost independent of air content in steam. Coolant efficiency depends on steam pressure defined by operation of steam-jet unit of ejector of the next stage after coolant of steam-jet stage, temperature, and condensing water flow. As a rule, steam entering content of steam-air mixture supplied to coolant is overheated with respect to saturation temperature of steam in the mixture. This should be taken into account during coolant computation. Long-term operation causes changes in roughness of walls of the ejector's mixing chamber. The influence of change of wall roughness on ejector characteristic is similar to the influence of reverse pressure of the steam-jet stage. Until some roughness value, injection coefficient of the ejector stage operating in superlimiting regime hardly changed. After reaching critical roughness, the ejector switches to prelimiting operating regime.

  13. Direct energy recovery from primary and secondary sludges by supercritical water oxidation.

    Science.gov (United States)

    Svanström, M; Modell, M; Tester, J

    2004-01-01

    Supercritical water oxidation (SCWO) oxidizes organic and biological materials virtually completely to benign products without the need for stack gas scrubbing. Heavy metals are recovered as stabilized solid, along with the sand and clay that is present in the feed. The technology has been under development for twenty years. The major obstacle to commercialization has been developing reactors that are not clogged by inorganic solid deposits. That problem has been solved by using tubular reactors with fluid velocities that are high enough to keep solids in suspension. Recently, system designs have been created that reduce the cost of processing sewage sludges below that of incineration. At 10 wt- % dry solids, sludge can be oxidized with virtually complete recovery of the sludge heating value as hot water or high-pressure steam. Liquid carbon dioxide of high purity can be recovered from the gaseous effluent and excess oxygen can be recovered for recycle. The net effect is to reduce the stack to a harmless vent with minimal flow rate of a clean gas. Complete simulations have been developed using physical property models that accurately simulate the thermodynamic properties of sub- and supercritical water in mixtures with O2, N2, CO2, and organics. Capital and operating cost estimates are given for sewage sludge treatment, which are less costly than incineration. The scenario of direct recovery of energy from sludges has inherent benefits compared to other gasification or liquefaction options.

  14. Direct Energy Recovery from Primary and Secondary Sludges by Supercritical Water Oxidation

    Energy Technology Data Exchange (ETDEWEB)

    Svanstroem, Magdalena; Modell, Michael; Tester, Jefferson

    2003-07-01

    Supercritical water oxidation (SCWO) oxidizes organic and biological materials virtually completely to benign products without the need for stack gas scrubbing. Heavy metals are recovered as stabilized solid, along with the sand and clay that is present in the feed. The technology has been under development for twenty years. The major obstacle to commercialization has been developing reactors that are not clogged by inorganic solid deposits. That problem has been solved by using tubular reactors with fluid velocities that are high enough to keep solids in suspension. Recently, system designs have been created that reduce the cost of processing sewage sludges below that of incineration. At 10 wt-% dry solids, sludge can be oxidized with virtually complete recovery of the sludge heating value as hot water or high-pressure steam. Liquid carbon dioxide of high purity can be recovered from the gaseous effluent and excess oxygen can be recovered for recycle. The net effect is to reduce the stack to a harmless vent with minimal flow rate of a clean gas. Complete simulations have been developed using physical property models that accurately simulate the thermodynamic properties of sub- and supercritical water in mixtures with O{sub 2}, N{sub 2}, CO{sub 2}. and organics. Capital and operating cost estimates are given for sewage sludge treatment, which are less costly than incineration. The scenario of direct recovery of energy from sludges has inherent benefits compared to other gasification or liquefaction options. (author)

  15. Adsorption from Experimental Isotherms of Supercritical Gases

    Institute of Scientific and Technical Information of China (English)

    2001-01-01

    A mathematical method was proposed for the determination of absolute adsorption from experimental isotherms. The method is based on the numerical equality of the absolute and the excess adsorption when either the gas phase density or the amount adsorbed is not quite considerable. The initial part of the experimental isotherms, which represents the absolute adsorption, became linear with some mathematical manipulations. The linear isotherms were reliably formulated. As consequence, either the volume or the density of the supercritical adsorbate could be determined by a non-empirical way. This method was illustrated by the adsorption data of supercritical hydrogen and methane on a superactivated carbon in large ranges of temperature and pressure.

  16. Study of Scaling Development on Tube Surfaces of Water Steam Loop in Steam Generator of CEFR

    Institute of Scientific and Technical Information of China (English)

    ZHANG; Lu; LIU; Fu-chen; LUO; De-kang; WU; Qiang; ZHANG; Huan-qi

    2012-01-01

    <正>The steam generator worked as pressure boundary of Na-H2O loop in China Experimental FastReactor (CEFR), which was quite important for nuclear reactor safety. Once the tubes separating the water from steam leak because of corrosion by scaling, Na-H2O reaction would lead to severe accident. So it’s critically important to study how the scaling develops on the water-steam sides.

  17. Metal Nanoparticles Preparation In Supercritical Carbon Dioxide Solutions

    Energy Technology Data Exchange (ETDEWEB)

    Harry W. Rollins

    2004-04-01

    The novel optical, electronic, and/or magnetic properties of metal and semiconductor nanoparticles have resulted in extensive research on new methods for their preparation. An ideal preparation method would allow the particle size, size distribution, crystallinity, and particle shape to be easily controlled, and would be applicable to a wide variety of material systems. Numerous preparation methods have been reported, each with its inherent advantages and disadvantages; however, an ideal method has yet to emerge. The most widely applied methods for nanoparticle preparation include the sonochemical reduction of organometallic reagents,(1&2) the solvothermal method of Alivisatos,(3) reactions in microemulsions,(4-6) the polyol method (reduction by alcohols),(7-9) and the use of polymer and solgel materials as hosts.(10-13) In addition to these methods, there are a variety of methods that take advantage of the unique properties of a supercritical fluid.(14&15) Through simple variations of temperature and pressure, the properties of a supercritical fluid can be continuously tuned from gas-like to liquid-like without undergoing a phase change. Nanoparticle preparation methods that utilize supercritical fluids are briefly reviewed below using the following categories: Rapid Expansion of Supercritical Solutions (RESS), Reactive Supercritical Fluid Processing, and Supercritical Fluid Microemulsions. Because of its easily accessible critical temperature and pressure and environmentally benign nature, carbon dioxide is the most widely used supercritical solvent. Supercritical CO2 is unfortunately a poor solvent for many polar or ionic species, which has impeded its use in the preparation of metal and semiconductor nanoparticles. We have developed a reactive supercritical fluid processing method using supercritical carbon dioxide for the preparation of metal and metal sulfide particles and used it to prepare narrowly distributed nanoparticles of silver (Ag) and silver sulfide

  18. Supercritical fluid mixing in Diesel Engine Applications

    Science.gov (United States)

    Bravo, Luis; Ma, Peter; Kurman, Matthew; Tess, Michael; Ihme, Matthias; Kweon, Chol-Bum

    2014-11-01

    A numerical framework for simulating supercritical fluids mixing with large density ratios is presented in the context of diesel sprays. Accurate modeling of real fluid effects on the fuel air mixture formation process is critical in characterizing engine combustion. Recent work (Dahms, 2013) has suggested that liquid fuel enters the chamber in a transcritical state and rapidly evolves to supercritical regime where the interface transitions from a distinct liquid/gas interface into a continuous turbulent mixing layer. In this work, the Peng Robinson EoS is invoked as the real fluid model due to an acceptable compromise between accuracy and computational tractability. Measurements at supercritical conditions are reported from the Constant Pressure Flow (CPF) chamber facility at the Army Research Laboratory. Mie and Schlieren optical spray diagnostics are utilized to provide time resolved liquid and vapor penetration length measurement. The quantitative comparison presented is discussed. Oak Ridge Associated Universities (ORAU).

  19. Heat Transfer Phenomena of Supercritical Fluids

    Energy Technology Data Exchange (ETDEWEB)

    Krau, Carmen Isabella; Kuhn, Dietmar; Schulenberg, Thomas [Forschungszentrum Karlsruhe, Institute for Nuclear and Energy Technologies, 76021 Karlsruhe (Germany)

    2008-07-01

    In concepts for supercritical water cooled reactors, the reactor core is cooled and moderated by water at supercritical pressures. The significant temperature dependence of the fluid properties of water requires an exact knowledge of the heat transfer mechanism to avoid fuel pin damages. Near the pseudo-critical point a deterioration of heat transfer might happen. Processes, that take place in this case, are not fully understood and are due to be examined systematically. In this paper a general overview on the properties of supercritical water is given, experimental observations of different authors will be reviewed in order to identify heat transfer phenomena and onset of occurrence. The conceptional design of a test rig to investigate heat transfer in the boundary layer will be discussed. Both, water and carbon dioxide, may serve as operating fluids. The loop, including instrumentation and safety devices, is shown and suitable measuring methods are described. (authors)

  20. 停运汽动风机高压加热器提高煤气锅炉效率的实践%Practice of Improving Gas Boiler Efficiency by Stopping the Steam-driven High Pressure Blower Heater

    Institute of Scientific and Technical Information of China (English)

    赵晓雷; 彭建军

    2015-01-01

    兴澄特钢一台SG-260/9.8-Q8501型全烧高炉煤气锅炉,利用停运对应的汽动鼓风机高压加热器,降低给水温度,从而降低锅炉排烟温度,达到节约蒸汽,提高锅炉效率的作用。%The SG 260/9.8 Q8501 type all-BFG boiler at Xingcheng Special Steel is introduced. Steam was saved and efficiency of the boiler was improved by shutting down the corresponding steam-driven high pressure fan heater to reduce the temperature of feed water and thereby lower the temperature of boiler flue gas.

  1. Application of Power Generation Technology with Low-pressure Saturated Steam in Xuanhua Steel%低压饱和蒸汽发电技术在宣钢的应用

    Institute of Scientific and Technical Information of China (English)

    闫新明

    2014-01-01

    利用低压饱和蒸汽发电已成为钢铁企业的共识,就2013年宣钢新建一台14 MW级间再热补凝汽式汽轮发电机的成功典例,说明余热蒸汽发电的节能效益和推广价值。%The technology of power generation with low-pressure saturated steam has been generally accepted in domestic steel industry. The energy saving effect and promotion value of power generation with vapour from waste heat are demonstrated with the successful example of the 14 MW reheat condensing steam turbine newly built in Xuanhua Steel.

  2. 饱和蒸汽压式波纹管疏水阀热动元件实验研究%Experimental study on the saturated vapor pressure type thermostatic bellows for steam traps

    Institute of Scientific and Technical Information of China (English)

    李树勋; 徐登伟; 把桥环

    2011-01-01

    针对液体膨胀式波纹管蒸汽疏水阀排量不稳定、漏汽率高等问题,分析波纹管热动元件的热工特性.基于Riedel蒸汽压方程和气液平衡方程,建立饱和蒸汽压式波纹管热动元件的热力学模型,设计相应实验系统,进行不同参数下的实验研究.结果表明,饱和蒸汽压式波纹管热动元件伸长量是相变温度的单值函数,近似呈指数关系;采用不同混合比、刚度及填充方式,可调节疏水阀的排水过冷度.%In view of the instabilities of displacement and high steam leakage rate for the liquid-expansion type ther-mostatic bellows steam traps, thermodynamic characteristical of thermostatic bellows was analyzed. Based on the Riedel equation and the vapor-liquid equilibrium equation, thermodynamic model of the saturated vapor pressure type thermostatic bellows was set up, corresponding experimental system was designed, and experimental studies with different parameters was carried out. The experimental results agree well with the theoretical analysis. The results show that the elongation A/I of the saturated vapor pressure type thermostatic bellows is monodrome function of phase transition temperature T, and relationship between the elongation A/I and the phase change temperature t is an exponential function. The subcooled temperature of steam trap can be adjusted by using different mixture ratio, different bellows' stiffness and different sufficient attire method. This paper establishes theoretical and experimental foundation for improving the performance of thermostatic bellows steam traps.

  3. Computational Modeling of Supercritical and Transcritical Flows

    Science.gov (United States)

    2017-01-09

    reasonably accurate for supercritical and transcritical combustion. 15. SUBJECT TERMS N/A 16. SECURITY CLASSIFICATION OF: 17. LIMITATION OF...pr Reduced pressure (p/pc) Tc Critical temperature Tr Reduced temperature (T/Tc) Vm Molar volume Xi Mole fraction of species i Z Compressibility ω...pressure states. A 5.5mm by 0.4064mm domain uses a uniform 256 × 512 Cartesian grid. The code is fifth order accurate in space and a third order

  4. Supercritical CO2 Extraction of Ethanol

    OpenAIRE

    GÜVENÇ, A.; MEHMETOĞLU, Ü.; ÇALIMLI, A.

    1999-01-01

    Extraction of ethanol was studied from both synthetic ethanol solution and fermentation broth using supercritical CO2 in an extraction apparatus in ranges of 313 to 333 K and 80 to 160 atmospheres, for varying extraction times. The experimental system consists mainly of four parts: a CO2 storage system, a high-pressure liquid pump, an extractor and a product collection unit. Samples were analyzed by gas chromatography. Effects of temperature, pressure, extraction time, initial ethan...

  5. Steam-water relative permeability

    Energy Technology Data Exchange (ETDEWEB)

    Ambusso, W.; Satik, C.; Home, R.N. [Stanford Univ., CA (United States)

    1997-12-31

    A set of relative permeability relations for simultaneous flow of steam and water in porous media have been measured in steady state experiments conducted under the conditions that eliminate most errors associated with saturation and pressure measurements. These relations show that the relative permeabilities for steam-water flow in porous media vary approximately linearly with saturation. This departure from the nitrogen/water behavior indicates that there are fundamental differences between steam/water and nitrogen/water flows. The saturations in these experiments were measured by using a high resolution X-ray computer tomography (CT) scanner. In addition the pressure gradients were obtained from the measurements of liquid phase pressure over the portions with flat saturation profiles. These two aspects constitute a major improvement in the experimental method compared to those used in the past. Comparison of the saturation profiles measured by the X-ray CT scanner during the experiments shows a good agreement with those predicted by numerical simulations. To obtain results that are applicable to general flow of steam and water in porous media similar experiments will be conducted at higher temperature and with porous rocks of different wetting characteristics and porosity distribution.

  6. Effects of supercritical environment on hydrocarbon-fuel injection

    Science.gov (United States)

    Shin, Bongchul; Kim, Dohun; Son, Min; Koo, Jaye

    2017-04-01

    In this study, the effects of environment conditions on decane were investigated. Decane was injected in subcritical and supercritical ambient conditions. The visualization chamber was pressurized to 1.68 MPa by using nitrogen gas at a temperature of 653 K for subcritical ambient conditions. For supercritical ambient conditions, the visualization chamber was pressurized to 2.52 MPa by using helium at a temperature of 653 K. The decane injection in the pressurized chamber was visualized via a shadowgraph technique and gradient images were obtained by a post processing method. A large variation in density gradient was observed at jet interface in the case of subcritical injection in subcritical ambient conditions. Conversely, for supercritical injection in supercritical ambient conditions, a small density gradient was observed at the jet interface. In a manner similar to that observed in other cases, supercritical injection in subcritical ambient conditions differed from supercritical ambient conditions such as sphere shape liquid. Additionally, there were changes in the interface, and the supercritical injection core width was thicker than that in the subcritical injection. Furthermore, in cases with the same injection conditions, the change in the supercritical ambient normalized core width was smaller than the change in the subcritical ambient normalized core width owing to high specific heat at the supercritical injection and small phase change at the interface. Therefore, the interface was affected by the changing ambient condition. Given that the effect of changing the thermodynamic properties of propellants could be essential for a variable thrust rocket engine, the effects of the ambient conditions were investigated experimentally.

  7. Electrochemistry in supercritical fluids

    Science.gov (United States)

    Branch, Jack A.; Bartlett, Philip N.

    2015-01-01

    A wide range of supercritical fluids (SCFs) have been studied as solvents for electrochemistry with carbon dioxide and hydrofluorocarbons (HFCs) being the most extensively studied. Recent advances have shown that it is possible to get well-resolved voltammetry in SCFs by suitable choice of the conditions and the electrolyte. In this review, we discuss the voltammetry obtained in these systems, studies of the double-layer capacitance, work on the electrodeposition of metals into high aspect ratio nanopores and the use of metallocenes as redox probes and standards in both supercritical carbon dioxide–acetonitrile and supercritical HFCs. PMID:26574527

  8. Electrochemistry in supercritical fluids.

    Science.gov (United States)

    Branch, Jack A; Bartlett, Philip N

    2015-12-28

    A wide range of supercritical fluids (SCFs) have been studied as solvents for electrochemistry with carbon dioxide and hydrofluorocarbons (HFCs) being the most extensively studied. Recent advances have shown that it is possible to get well-resolved voltammetry in SCFs by suitable choice of the conditions and the electrolyte. In this review, we discuss the voltammetry obtained in these systems, studies of the double-layer capacitance, work on the electrodeposition of metals into high aspect ratio nanopores and the use of metallocenes as redox probes and standards in both supercritical carbon dioxide-acetonitrile and supercritical HFCs.

  9. Microbiological and sensory effects of the combined application of hot-cold organic acid sprays and steam condensation at subatmospheric pressure for decontamination of inoculated pig tissue surfaces.

    Science.gov (United States)

    Smulders, Frans J M; Wellm, Gabriele; Hiesberger, Johann; Rohrbacher, Irene; Bauer, Alexandra; Paulsen, Peter

    2011-08-01

    We studied microbiological and sensory effects of treating pig tissue for 15 s with 55 and 10°C sprays of acetic acid (AA; 0.15 to 0.3 M) and lactic acid (LA; 0.1 to 0.2 M) solutions prior to the tissue being subjected to steam condensation (18 s at 65°C or 10 s at 75°C). LA or AA spraying and then steam treatment resulted in 3- to 4-log average reductions of Pseudomonas fragi and Yersinia enterocolitica inocula (6 to 7 log CFU/cm(2)), regardless of acid temperature or concentration. Buffered LA or 1:1 mixtures of AA:LA and then steam treatment yielded similar reductions. Most of the acid-steam-treated samples had microbial counts below the limit of detection (2 log CFU/cm(2)); thus, the results likely underestimate the potential of this procedure. When the period between inoculation and acid-steam treatment was extended from 0.5 to 24 h, up to a 1-log-higher microbial reduction was observed, due to a 1- to 2-log-greater initial contamination. Increasing the LA contact time to 6 min increased the microbial reduction by 0.8 log. Acid-steam treatment effected lower L* values (darker color) on pigskin, but higher L* values on muscle and fat tissue (paler color). Many muscle samples exhibited lower a* values and off-color brown hues. Off-odors were observed immediately after treatment, but with the exception of fat tissue and AA-treated samples, they largely disappeared during further storage. Off-flavors were only detected in AA-treated muscle samples.

  10. Pretreatment of Corn Stalk by Steam Explosion

    Institute of Scientific and Technical Information of China (English)

    邵自强; 田永生; 谭惠民

    2003-01-01

    A steam explosion pretreatment, which is one of the best ways of pretreating plant stalk, is applied at various severities to corn stalk. It could effectively modify the super-molecular structure of corn stalk and defibrating corn stalk into individual components. The relationship between yield of reducing sugar and the operating conditions, including temperature, pressure of steam explosion pretreatment and acidity, is also established. Experimental results prove that the steam explosion substantially increases the yield of reducing sugar, and the optimal condition for steam explosion is as follows: the pressure is 2.0 MPa, the pressure-retaining time 300 s, the initial acid concentration 1% and the acid treatment time 24 h.

  11. Supercritical Airfoil Coordinates

    Data.gov (United States)

    National Aeronautics and Space Administration — Rectangular Supercritical Wing (Ricketts) - design and measured locations are provided in an Excel file RSW_airfoil_coordinates_ricketts.xls . One sheet is with Non...

  12. Petrophysical core characterization at supercritical geothermal conditions

    Science.gov (United States)

    Kummerow, Juliane; Raab, Siegfried

    2015-04-01

    There is a growing scientific interest in the exploitation of supercritical geothermal reservoirs to increase the efficiency of geothermal power plants. The utilisation of geothermal energy requires in any case the detailed knowledge of the reservoir. In reservoir engineering, the characterisation of the geothermal system by electrical resistivity tomography (ERT) is a common geophysical exploration and monitoring strategy. For a realistic interpretation of the field measurements it is necessary to know both, the physical properties of the rock and those of the interacting fluid at defined temperature and pressure conditions. While there have been made great effort in determine the physical and chemical properties of water above its critical point (Tcritical = 374.21° C and pcritical = 221.2 bar), the influence of fluid-rock interactions on petrophysical properties in supercritical aqueous systems is nearly unknown. At supercritical conditions the viscosity of the fluid is low, which enhances the mass transfer and diffusion-controlled chemical reactions. This may have considerable effects on the porosity and hydraulic properties of a rock. To investigate high-enthalpy fluid-rock systems, in the framework of the EU-funded project IMAGE we have built a new percolation set-up, which allows for the measurement of electrical resistivity and permeability of rock samples at controlled supercritical conditions of aqueous fluids (pore pressure = 400 bar and a temperature = 400° C). First results will be presented.

  13. System for Steam Leak Detection by using CCTV Camera

    Energy Technology Data Exchange (ETDEWEB)

    Choi, Young Chul; Lee, Min Soo; Choi, Hui Ju [Korea Atomic Energy Research Institute, Daejeon (Korea, Republic of); Son, Ki Sung; Jeon, Hyeong Seop [SAEAN.Co., Seoul (Korea, Republic of)

    2012-05-15

    There are many pipes in the secondary cooling systems of nuclear power plants and coal-fired power plants. In these pipes, high pressure fluids are moving with at high velocity, which can cause steam leakage due to pipe thinning. Steam leakage is one of the major issues for the structural fracture of pipes. Therefore, a method to inspect a large area of piping systems quickly and accurately is needed. Steam leakage is almost invisible, because the flow has very high velocity and pressure. Therefore, it is very difficult to detect a steam leakage. In this paper, we proposed the method for detecting steam leakage using image signal processing. Our basic idea comes from a heat shimmer, which shines with a soft light that looks as if it is being shaken slightly. To test the performance of this technique, experiments have been performed for a steam generator. Results show that the proposed technique is quite powerful for steam leak detection

  14. Numerical simulation of effect of catalyst wire-mesh pressure drop characteristics on flow distribution in catalytic parallel plate steam reformer

    DEFF Research Database (Denmark)

    Sigurdsson, Haftor Örn; Kær, Søren Knudsen

    2012-01-01

    Steam reforming of hydrocarbons using a catalytic plate-type-heat-exchanger (CPHE) reformer is an attractive method of producing hydrogen for a fuel cell-based micro combined-heat-and-power system. In this study the flow distribution in a CPHE reformer, which uses a coated wire-mesh catalyst...

  15. Isolation of Organochlorine Pesticide from Ginseng with Supercritical CO2

    Institute of Scientific and Technical Information of China (English)

    李淑芬; 王幼君; 全灿; 田松江

    2005-01-01

    The feasibility of removal of the organochlorine pesticides residues of hexachlorocyclohexane(BHC) from radix ginseng with supercritical CO2 was explored. Some factors, such as extraction pressure, extraction temperature, and kinds of co-solvents were investigated. The experimental results indicate that it is possible to reduce BHC residues in radix ginseng to the level of 0.1 × 10-6 with supercritical CO2 in the presence of suitable amount of co-solvent, such as water.

  16. Production of primary materials for duro-plastic glue, ethanol, and enzymes, from lignocellulose-containing by-products and organic waste in the Fritz-Werner pilot plant (steam pressure extraction)

    Energy Technology Data Exchange (ETDEWEB)

    Sinner, M.; Langer, J.

    1983-01-01

    By the steam pressure extraction process ligno-cellulose-containing annual plants and deciduous wood can be pulped without the need for chemicals. The pre-ground material is treated continuously with saturated steam at elevated pressures in a boiler for approx. 10-20 min. and is shredded upon discharge from the boiler by reduction of pressure to atmospheric conditions. This decomposition process leads to a softening of the cell wall bonds thereby exposing the bio-structure. Extraction of the fibrous material with water or strongly diluted aqueous alkali gives rise to the hemicellular form of the starting material, in particular to soluble xylane degradation products. The extracted fibrous material consists chiefly of cellulose and lignin. These fibres are so loosely inter-connected that they are readily accessible for chemical and in particular biochemical reaction. The fibres can be converted to glucose by enzymatic or acid hydrolysis, they can be used as a substrate for microorganisms, or as energy source and raw fodder for ruminants, or they can be compressed to form fibre-board without the need for binding agents.

  17. 300MW及以上汽轮机低压转子冶炼工艺研究%Smelting Process of Steam Turbine Low Pressure Rotor of 300 MW & Above

    Institute of Scientific and Technical Information of China (English)

    魏雪晴; 李奇; 管仲毅

    2014-01-01

    介绍了300 MW及以上汽轮机低压转子的冶炼工艺控制要点。对耐火材料和辅具进行了改进和优化,最终生产出合格的转子锻件。%This paper presents the smelting process control key points of 300 MV and above steam turbine low pressure rotor .Refractory materials and auxiliary tools have been improved and optimized , eventually acceptable rotor has been produced .

  18. 超临界氨合成%AMMONIA SYNTHESIS AT SUPERCRITICAL CONDITIONS

    Institute of Scientific and Technical Information of China (English)

    刘化章; 唐浩东; 李小年

    2004-01-01

    Ammonia synthesis at supercritical conditions was first studied over iron and active carbonsupported ruthenium catalysts in a fixed-bed reactor. The influences of 15 kinds of different supercritical media, such as alkanes of C7-C13, 1, 2, 3, 4-tetrahydronaphthalene, cis-decalin, o-xylene,ethylbenzene, quinolin, n-hexane and aniline etc. and reaction conditions (catalyst, temperature, space velocity, particial pressure of media) on ammonia at supercritical condition were investigated.Supercritical medium was decomposed under reaction conditions over Fe and Ru/AC catalysts. The decomposition products deactivated the catalysts. Alkane decomposed the least, and the rate of deactivation was the slowest. Therefore alklane was a relatively good medium. The decomposion of supercritical medium was the key for the deactivation of catalysts. Another important reason for the decrease of ammonia concentration was that the effective pressure of syngas decreased because of the presence of supercritical media. The active temperature of catalyst was the decisive factor in supercritical ammonia synthesis. Supercritical catalytic reaction was viable only at a lower temperature. Ammonia ynthesis at supercritical conditions is possible if a catalyst with active temperature lower than 573 K could e developed and the decomposition of supercritical media could be prevented.

  19. The microbial-kill characteristics of saturated steam plus 1,000 to 10,000 ppm hydrogen peroxide at atmospheric pressure.

    Science.gov (United States)

    Pflug, Irving J; Melgaard, Hans L; Schaffer, Shawn M; Lysfjord, Jack P

    2008-01-01

    This is the report of a project carried out to determine the microbial-kill characteristics of saturated steam plus hydrogen peroxide (H2O2) using a specially-constructed test apparatus. Spores on stainless-steel planchets were inserted into a flowing gaseous atmosphere of steam plus H2O2 for a timed exposure to the lethal agent. The specially-designed test apparatus and its operating parameters are described. Geobacillus stearothermophilus (former name, Bacillus stearothermophilus) spore-death rates were evaluated in several spore-planchet handling modes. Enumeration microbial recovery methods were used. The data were analyzed using survivor-curve methods; D-values were calculated using the initial number of spores per planchet and the number of spores surviving the process. Extensive tests were carried out using Geobacillus stearothermophilus spores; limited tests were carried out using Bacillus smithii ATCC 51232 (former name, Bacillus coagulans), Bacillus macerans, and Bacillus subtilis, subtilis ATCC 35021 spores (former name, Bacillus subtilis, CCC 5230, Kerns 15U). For G. stearothermophilus spores subjected to steam plus H2O2 and recovered using the 2B procedure (planchets deposited in sterile, 100-mL bottles containing 50.0 mL of buffer immediately after they were subjected to the steam-H2O2 condition; 11 experiments), the mean D-value was 0.48 min at 2,500 ppm and 0.22 min at 7,500 ppm. The application of steam plus H2O2 to the sterilization of barrier isolator enclosures is discussed.

  20. 49 CFR 230.23 - Responsibility for general construction and safe working pressure.

    Science.gov (United States)

    2010-10-01

    ... construction of the steam locomotive boilers under their control. The steam locomotive owner shall establish the safe working pressure for each steam locomotive boiler, after giving full consideration to the... (Continued) FEDERAL RAILROAD ADMINISTRATION, DEPARTMENT OF TRANSPORTATION STEAM LOCOMOTIVE INSPECTION...

  1. Molecular Dynamics Simulation of Diffusion Coefficients of Oxygen, Nitrogen and Sodium Chloride in Supercritical Water

    Institute of Scientific and Technical Information of China (English)

    肖吉; 陆九芳; 陈健; 李以圭

    2001-01-01

    Molecular dynamics simulation has been performed to determine the infinite-dilution diffusion coefficients of oxygen and nitrogen, and the diffusion coefficients of NaCl in supercritical water from 703.2- 763.2 K and 30-45 MPa.The results obtained show that the diffusion coefficients in supercritical water increase with temperature, while decreasing with pressure. Nevertheless, the diffusion coefficients in supercritical water are much larger than those in normal water.

  2. Determination of binary diffusion coefficients in supercritical carbon dioxide with supercritical fluid chromatography (SFC)

    Energy Technology Data Exchange (ETDEWEB)

    Dahmen, N.; Duelberg, A.; Schneider, G.M. (Bochum Univ. (Germany, F.R.). Lehrstuhl fuer Physikalische Chemie 2)

    1990-03-01

    Binary diffusion coefficient D{sub 12} in supercritical carbon dioxide were determined in a Supercritical Fluid Chromatography (SFC) apparatus by the peak broadening method (PBM). Some cyclic and linear ketones were investigated as a function of pressure between 9.5 and 18 MPa at about 314 K corresponding to densities form 513 to 820 kg m{sup -3}. The resulting D{sub 12} values are of the order of 10{sup -8} m{sup 2} s{sup -1} and lnD{sub 12} decreases about linearly with increasing density {rho} of the CO{sub 2}. (orig.).

  3. Steam Digest 2001

    Energy Technology Data Exchange (ETDEWEB)

    2002-01-01

    Steam Digest 2001 chronicles BestPractices Program's contributions to the industrial trade press for 2001, and presents articles that cover technical, financial and managerial aspects of steam optimization.

  4. Condensation-Induced Steam Bubble Collapse in a Pipeline

    Institute of Scientific and Technical Information of China (English)

    2000-01-01

    Steam bubbles often occur in pipelines due to the pipeline structure or operational errors. The water hammer force induced by the steam bubble collapse is a hidden safety concern. This paper experimentally and numerically investigates the conditions for steam bubble formation and collapse. A series of video pictures taken in the laboratory show that steam bubbles form and collapse over several cycles. The pressure history of the steam bubbles is measured in conjunction with the pictures. In the experiment, the liquid column cavitated at the low pressures and then the cavities collapsed due to condensation causing high pressure pulses. The process was also simulated numerically. The results suggest that coolant pipeline design and operation must include procedures to avoid steam bubble formation.

  5. A small pelton turbine for steam turbocharger

    Energy Technology Data Exchange (ETDEWEB)

    Rautenberg, M.; Abdelkader, M.; Malobabic, M.; Mobarak, A.

    1984-08-01

    The use of exhaust gas turbocharger for internal combustion engines is usually accompanied by mechanical loss. This loss is due to the raise of exhaust gas back pressure with the increase of engine speed. This back pressure prevents the discharge of the exhaust gas from the engine and causes mechanical loss. To avoid this undesirable phenomenon, a Clausius-Rankine cycle is used. In this case the thermal energy in the exhaust gas is used to vaporise water in a steam generator. The generated steam expands in a steam turbocharger which supercharges the engine. A small Pelton steam turbine has been designed and fabricated. The expected output for this small turbine is 10 kW. A computer program has been prepared to estimate the values of optimum cycle parameters.

  6. The latent heat of vaporization of supercritical fluids

    Science.gov (United States)

    Banuti, Daniel; Raju, Muralikrishna; Hickey, Jean-Pierre; Ihme, Matthias

    2016-11-01

    The enthalpy of vaporization is the energy required to overcome intermolecular attractive forces and to expand the fluid volume against the ambient pressure when transforming a liquid into a gas. It diminishes for rising pressure until it vanishes at the critical point. Counterintuitively, we show that a latent heat is in fact also required to heat a supercritical fluid from a liquid to a gaseous state. Unlike its subcritical counterpart, the supercritical pseudoboiling transition is spread over a finite temperature range. Thus, in addition to overcoming intermolecular attractive forces, added energy simultaneously heats the fluid. Then, considering a transition from a liquid to an ideal gas state, we demonstrate that the required enthalpy is invariant to changes in pressure for 0 intermolecular forces in the real fluid vapor during heating. At supercritical pressures, all of the transition occurs at non-equilibrium; for p -> 0 , all of the transition occurs at equilibrium.

  7. Steam Digest Volume IV

    Energy Technology Data Exchange (ETDEWEB)

    None

    2004-07-01

    This edition of the Steam Digest is a compendium of 2003 articles on the technical and financial benefits of steam efficiency, presented by the stakeholders of the U.S. Department of Energy's BestPractices Steam effort.

  8. The Invisibility of Steam

    Science.gov (United States)

    Greenslade, Thomas B., Jr.

    2014-01-01

    Almost everyone "knows" that steam is visible. After all, one can see the cloud of white issuing from the spout of a boiling tea kettle. In reality, steam is the gaseous phase of water and is invisible. What you see is light scattered from the tiny droplets of water that are the result of the condensation of the steam as its temperature…

  9. Biocompatibility of supercritical CO2-treated titanium implants in a rat model.

    Science.gov (United States)

    Hill, C M; Kang, Q K; Wahl, C; Jimenez, A; Laberge, M; Drews, M; Matthews, M A; An, Y H

    2006-04-01

    Supercritical phase CO2 is a promising method for sterilizing implantable devices and tissue grafts. The goal of this study is to evaluate the biocompatibility of titanium implants sterilized by supercritical phase CO2 in a rat subcutaneous implantation model. At 5 weeks post implantation titanium implants sterilized by supercritical phase CO2 produce a soft tissue reaction that is comparable to other methods of sterilization (steam autoclave, ultraviolet light radiation, ethylene oxide gas, and radio-frequency glow-discharge), as indicated by the thickness and density of the foreign body capsule, although there were some differences on the capillary density. Overall the soft tissue response to the implants was similar among all methods of sterilization, indicating supercritical phase CO2 treatment did not compromise the biocompatibility of the titanium implant.

  10. World largest KAWASAKI KJ type soda recovery boiler, generating high pressure and high temperature steam. For the Iwakuni mill of Nippon Paper Industries Co. Ltd.; Sekai saidaikyu no koatsu koon soda kaishu boiler. Nippon seishi (kabu) Iwakuni kojo dono muke

    Energy Technology Data Exchange (ETDEWEB)

    Hirokawa, M.; Matsuda, T.; Masuda, T.; Suemitsu, N.; Makito, Y.; Tanihara, T.; Asada, S. [Kawasaki Heavy Industries, Ltd., Kobe (Japan)

    1996-10-15

    This paper presents the important notices in design and issues on the large KAWASAKI KJ type soda recovery boiler under construction for the Iwakuni mill of Nippon Paper Industries Co., Ltd. This soda recovery boiler is the largest one in volume in Japan, and the highest one in pressure and temperature in the world. Since saturation temperature rises with steam pressure, corrosion resistance of the water cooling wall of a combustion chamber should be considered enough. This boiler thus adopts the double contact tube with an outer tube of SUS310 most superior in corrosion resistance. Alkaline molten salt corrosion of a superheater is one of the most severe problems on steam temperature rise. This boiler thus adopts SUS309J2TB superior in alkaline molten salt corrosion resistance for the highest-temperature portion of a superheater and the lower U bent subjected to radiant heat from a combustion chamber. Flow in a furnace and stress of a superheater were analyzed using computer for scale-up of boiler and preliminary verification. 1 ref., 14 figs., 2 tabs.

  11. 大型联合化工项目中压蒸汽管网吹扫方案及实施%Purging Scheme and Implementation of Medium Pressure Steam Pipe Network of Large Scale Integration Chemical Project

    Institute of Scientific and Technical Information of China (English)

    郭玉林; 刘俊青; 史学廷

    2014-01-01

    介绍了中压蒸汽管网总体吹扫方案及实施情况,并针对吹扫过程中出现的问题提出了相应的解决措施。此次中压蒸汽管网吹扫工作取得了圆满成功,对二期项目建设过程中改进管线设计、施工、监理、验收方法以及同类管线吹扫工作具有十分重要的参考意义。%The overall purging scheme of medium pressure steam pipe network and implementation is presented , and in connection with problems in purging process , relevant counter measures are suggested .The medium pressure steam pipe network purging scheme is a complete success , and it has important reference value for improvement of pipe network design , construction , supervision , acceptance check method in construction of the second phase and for same kind of pipe network purging .

  12. 49 CFR 230.37 - Steam test following repairs or alterations.

    Science.gov (United States)

    2010-10-01

    ... Boilers and Appurtenances Pressure Testing of Boilers § 230.37 Steam test following repairs or alterations... test of the boiler with steam pressure raised to between 95 percent and 100 percent of the MAWP. At... 49 Transportation 4 2010-10-01 2010-10-01 false Steam test following repairs or alterations....

  13. Supercritical separation process for complex organic mixtures

    Science.gov (United States)

    Chum, Helena L.; Filardo, Giuseppe

    1990-01-01

    A process is disclosed for separating low molecular weight components from complex aqueous organic mixtures. The process includes preparing a separation solution of supercritical carbon dioxide with an effective amount of an entrainer to modify the solvation power of the supercritical carbon dioxide and extract preselected low molecular weight components. The separation solution is maintained at a temperature of at least about 70.degree. C. and a pressure of at least about 1,500 psi. The separation solution is then contacted with the organic mixtures while maintaining the temperature and pressure as above until the mixtures and solution reach equilibrium to extract the preselected low molecular weight components from the organic mixtures. Finally, the entrainer/extracted components portion of the equilibrium mixture is isolated from the separation solution.

  14. Supercritical Fluid Extraction of Flavonoids from Dandelion

    Directory of Open Access Journals (Sweden)

    Wu Jun

    2014-01-01

    Full Text Available In this study, the total flavonoids from dandelion was extracted by supercritical CO2 and the total flavonoids content in the extract was investigated by the sodium nitrite-aluminum nitrate method with Rutin as a standard product. Single-factor experiments were carried out to map the effects of extraction pressure, temperature, time and entrainer amount on the yield of flavonoids. The orthogonal experiments on the optimum technology parameters demonstrated that the influence of the experimental conditions over the yield from high to low was: (a pressure, (b temperature, (c entrainer amount, (d time. The optimization result showed that under the conditions of 50°C, 35 MPa, 80 min and 4.0 mL/g entrainer amount, the yield of the preparative supercritical fluid extraction was 4.974%.

  15. Integrated vacuum absorption steam cycle gas separation

    Science.gov (United States)

    Chen, Shiaguo; Lu, Yonggi; Rostam-Abadi, Massoud

    2011-11-22

    Methods and systems for separating a targeted gas from a gas stream emitted from a power plant. The gas stream is brought into contact with an absorption solution to preferentially absorb the targeted gas to be separated from the gas stream so that an absorbed gas is present within the absorption solution. This provides a gas-rich solution, which is introduced into a stripper. Low pressure exhaust steam from a low pressure steam turbine of the power plant is injected into the stripper with the gas-rich solution. The absorbed gas from the gas-rich solution is stripped in the stripper using the injected low pressure steam to provide a gas stream containing the targeted gas. The stripper is at or near vacuum. Water vapor in a gas stream from the stripper is condensed in a condenser operating at a pressure lower than the stripper to concentrate the targeted gas. Condensed water is separated from the concentrated targeted gas.

  16. Supercritical fluid technology for energy and environmental applications

    CERN Document Server

    Anikeev, Vladimir

    2014-01-01

    Supercritical Fluid Technology for Energy and Environmental Applications covers the fundamental principles involved in the preparation and characterization of supercritical fluids (SCFs) used in the energy production and other environmental applications. Energy production from diversified resources - including renewable materials - using clean processes can be accomplished using technologies like SCFs. This book is focused on critical issues scientists and engineers face in applying SCFs to energy production and environmental protection, the innovative solutions they have found, and the challenges they need to overcome. The book also covers the basics of sub- and supercritical fluids, like the thermodynamics of phase and chemical equilibria, mathematical modeling, and process calculations. A supercritical fluid is any substance at a temperature and pressure above its critical point where distinct liquid and gas phases do not exist. At this state the compound demonstrates unique properties, which can be "fine...

  17. Physical properties of the benchmark models program supercritical wing

    Science.gov (United States)

    Dansberry, Bryan E.; Durham, Michael H.; Bennett, Robert M.; Turnock, David L.; Silva, Walter A.; Rivera, Jose A., Jr.

    1993-01-01

    The goal of the Benchmark Models Program is to provide data useful in the development and evaluation of aeroelastic computational fluid dynamics (CFD) codes. To that end, a series of three similar wing models are being flutter tested in the Langley Transonic Dynamics Tunnel. These models are designed to simultaneously acquire model response data and unsteady surface pressure data during wing flutter conditions. The supercritical wing is the second model of this series. It is a rigid semispan model with a rectangular planform and a NASA SC(2)-0414 supercritical airfoil shape. The supercritical wing model was flutter tested on a flexible mount, called the Pitch and Plunge Apparatus, that provides a well-defined, two-degree-of-freedom dynamic system. The supercritical wing model and associated flutter test apparatus is described and experimentally determined wind-off structural dynamic characteristics of the combined rigid model and flexible mount system are included.

  18. Supercritical extraction of lycopene from tomato industrial wastes with ethane.

    Science.gov (United States)

    Nobre, Beatriz P; Gouveia, Luisa; Matos, Patricia G S; Cristino, Ana F; Palavra, António F; Mendes, Rui L

    2012-07-11

    Supercritical fluid extraction of all-E-lycopene from tomato industrial wastes (mixture of skins and seeds) was carried out in a semi-continuous flow apparatus using ethane as supercritical solvent. The effect of pressure, temperature, feed particle size, solvent superficial velocity and matrix initial composition was evaluated. Moreover, the yield of the extraction was compared with that obtained with other supercritical solvents (supercritical CO₂ and a near critical mixture of ethane and propane). The recovery of all-E-lycopene increased with pressure, decreased with the increase of the particle size in the initial stages of the extraction and was not practically affected by the solvent superficial velocity. The effect of the temperature was more complex. When the temperature increased from 40 to 60 °C the recovery of all-E-lycopene increased from 80 to 90%. However, for a further increase to 80 °C, the recovery remained almost the same, indicating that some E-Z isomerization could have occurred, as well as some degradation of lycopene. The recovery of all-E-lycopene was almost the same for feed samples with different all-E-lycopene content. Furthermore, when a batch with a higher all-E-lycopene content was used, supercritical ethane and a near critical mixture of ethane and propane showed to be better solvents than supercritical CO₂ leading to a faster extraction with a higher recovery of the carotenoid.

  19. Dye solubility in supercritical carbon dioxide fluid

    Directory of Open Access Journals (Sweden)

    Yan Jun

    2015-01-01

    Full Text Available Supercritical carbon dioxide fluid is an alternative solvent for the water of the traditional dyeing. The solubility of dyestuff affects greatly the dyeing process. A theoretical model for predicting the dye solubility is proposed and verified experimentally. The paper concludes that the pressure has a greater impact on the dyestuff solubility than temperature, and an optimal dyeing condition is suggested for the highest distribution coefficient of dyestuff.

  20. Supercritical fluid extraction of mercury species.

    Science.gov (United States)

    Foy, G P; Pacey, G E

    2003-12-23

    Supercritical fluid extraction was used to recover organic and inorganic mercury species. Variations in pressure, water, methanol, and chelator create methods that allowed separation of inorganic from organic mercury species. When extracted using a compromised set of extraction conditions, the order of extraction was methyl, phenyl and inorganic mercury. For the individually optimized conditions, quantitative recoveries were observed. Level as low as 20 ppb were extracted and then determined using ICP.

  1. A three-dimensional laboratory steam injection model allowing in situ saturation measurements. [Comparing steam injection and steam foam injection with nitrogen and without nitrogen

    Energy Technology Data Exchange (ETDEWEB)

    Demiral, B.M.R.; Pettit, P.A.; Castanier, L.M.; Brigham, W.E.

    1992-08-01

    The CT imaging technique together with temperature and pressure measurements were used to follow the steam propagation during steam and steam foam injection experiments in a three dimensional laboratory steam injection model. The advantages and disadvantages of different geometries were examined to find out which could best represent radial and gravity override flows and also fit the dimensions of the scanning field of the CT scanner. During experiments, steam was injected continuously at a constant rate into the water saturated model and CT scans were taken at six different cross sections of the model. Pressure and temperature data were collected with time at three different levels in the model. During steam injection experiments, the saturations obtained by CT matched well with the temperature data. That is, the steam override as observed by temperature data was also clearly seen on the CT pictures. During the runs where foam was present, the saturation distributions obtained from CT pictures showed a piston like displacement. However, the temperature distributions were different depending on the type of steam foam process used. The results clearly show that the pressure/temperature data alone are not sufficient to study steam foam in the presence of non-condensible gas.

  2. Drug delivery goes supercritical

    Directory of Open Access Journals (Sweden)

    Patrick J. Ginty

    2005-08-01

    Full Text Available In the field of drug delivery, the ability to control the size, morphology, and release of drug particles is fundamental to good targeting, but is often hampered by harsh processing conditions or inadequate methods; likewise for the processing of polymeric controlled-release systems. However, the use of supercritical fluids such as supercritical CO2 (scCO2 has provided a ‘clean’ and effective alternative to traditional methods of drug and polymer processing. In particular, scCO2 has a number of unique properties that make it possible to process both bioactive molecules and amorphous polymers without using toxic organic solvents or elevated temperatures. Here, we review the positive impact that supercritical fluids have had on the micronization, encapsulation, and impregnation of molecules of interest to both the pharmaceutical and biotechnology industries.

  3. Aerobic Oxidation of Methyl Vinyl Ketone in Supercritical Carbon Dioxide

    Institute of Scientific and Technical Information of China (English)

    OUYANG,Xiao-Yue(欧阳小月); JIANG,Huan-Feng(江焕峰); CHENG,Jin-Sheng(程金生); ZHANG,Qun-Jian(张群健)

    2002-01-01

    Aerobic oxidation of methyl vinyl ketone to acetal in supercritical carbon dioxide are achieved in high conversion and high selectivity when oxygen pressure reaches 0.5MPa. The effects of cocatalysts,additive, pressure and temperature of the reaction are studied in detail.

  4. Materials processing using supercritical fluids

    Directory of Open Access Journals (Sweden)

    Orlović Aleksandar M.

    2005-01-01

    Full Text Available One of the most interesting areas of supercritical fluids applications is the processing of novel materials. These new materials are designed to meet specific requirements and to make possible new applications in Pharmaceuticals design, heterogeneous catalysis, micro- and nano-particles with unique structures, special insulating materials, super capacitors and other special technical materials. Two distinct possibilities to apply supercritical fluids in processing of materials: synthesis of materials in supercritical fluid environment and/or further processing of already obtained materials with the help of supercritical fluids. By adjusting synthesis parameters the properties of supercritical fluids can be significantly altered which further results in the materials with different structures. Unique materials can be also obtained by conducting synthesis in quite specific environments like reversed micelles. This paper is mainly devoted to processing of previously synthesized materials which are further processed using supercritical fluids. Several new methods have been developed to produce micro- and nano-particles with the use of supercritical fluids. The following methods: rapid expansion of supercritical solutions (RESS supercritical anti-solvent (SAS, materials synthesis under supercritical conditions and encapsulation and coating using supercritical fluids were recently developed.

  5. Selective chelation and extraction of lanthanides and actinides with supercritical fluids

    Energy Technology Data Exchange (ETDEWEB)

    Brauer, R.D.; Carleson, T.E.; Harrington, J.D.; Jean, F.; Jiang, H.; Lin, Y.; Wai, C.M.

    1994-01-01

    This report is made up of three independent papers: (1) Supercritical Fluid Extraction of Thorium and Uranium with Fluorinated Beta-Diketones and Tributyl Phosphate, (2) Supercritical Fluid Extraction of Lanthanides with Beta-Diketones and Mixed Ligands, and (3) A Group Contribution Method for Predicting the Solubility of Solid Organic Compounds in Supercritical Carbon Dioxide. Experimental data are presented demonstrating the successful extraction of thorium and uranium using fluorinated beta-diketones to form stable complexes that are extracted with supercritical carbon dioxide. The conditions for extracting the lanthanide ions from liquid and solid materials using supercritical carbon dioxide are presented. In addition, the Peng-Robison equation of state and thermodynamic equilibrium are used to predict the solubilities of organic solids in supercritical carbon dioxide from the sublimation pressure, critical properties, and a centric factor of the solid of interest.

  6. Estimation of the Isotherms of Phenol on Activated Carbons and Polymeric Adsorbents under Supercritical Condition

    Institute of Scientific and Technical Information of China (English)

    奚红霞; 谢兰英; 李祥斌; 李忠

    2003-01-01

    A method named as "volume-expanding and pressure-reducing adsorption" is proposed. It can be used to measure the isotherms under supercritical condition. The adsorption isotherms of phenol on activated carbons and polymeric adsorbents are estimated and compared respectively for the systems of "phenol-activated carbon-supercritical fluid CO2" and "phenol-polymeric adsorbent-supercritical fluid CO2". The results show that the amount of phenol adsorbed on the activated carbons and the polymeric adsorbents under the supercritical condition is much less than that under the general condition, which can be utilized to develop a technology regenerating the activated carbon with supercritical fluid. Moreover, the effects of ethyl alcohol, used as the third component, on the isotherms of phenol on the activated carbons and polymeric adsorbents under the supercritical condition are also investigated.

  7. Supercritical Synthesis of Biodiesel

    Directory of Open Access Journals (Sweden)

    Michel Vaultier

    2012-07-01

    Full Text Available The synthesis of biodiesel fuel from lipids (vegetable oils and animal fats has gained in importance as a possible source of renewable non-fossil energy in an attempt to reduce our dependence on petroleum-based fuels. The catalytic processes commonly used for the production of biodiesel fuel present a series of limitations and drawbacks, among them the high energy consumption required for complex purification operations and undesirable side reactions. Supercritical fluid (SCF technologies offer an interesting alternative to conventional processes for preparing biodiesel. This review highlights the advances, advantages, drawbacks and new tendencies involved in the use of supercritical fluids (SCFs for biodiesel synthesis.

  8. Experimental study of elliptical jet from sub to supercritical conditions

    Science.gov (United States)

    Muthukumaran, C. K.; Vaidyanathan, Aravind

    2014-04-01

    The jet mixing at supercritical conditions involves fluid dynamics as well as thermodynamic phenomena. All the jet mixing studies at critical conditions to the present date have focused only on axisymmetric jets. When the liquid jet is injected into supercritical environment, the thermodynamic transition could be well understood by considering one of the important fluid properties such as surface tension since it decides the existence of distinct boundary between the liquid and gaseous phase. It is well known that an elliptical liquid jet undergoes axis-switching phenomena under atmospheric conditions due to the presence of surface tension. The experimental investigations were carried out with low speed elliptical jet under supercritical condition. Investigation of the binary component system with fluoroketone jet and N2 gas as environment shows that the surface tension force dominates for a large downstream distance, indicating delayed thermodynamic transition. The increase in pressure to critical state at supercritical temperature is found to expedite the thermodynamic transition. The ligament like structures has been observed rather than droplets for supercritical pressures. However, for the single component system with fluoroketone jet and fluoroketone environment shows that the jet disintegrates into droplets as it is subjected to the chamber conditions even for the subcritical pressures and no axis switching phenomenon is observed. For a single component system, as the pressure is increased to critical state, the liquid jet exhibits gas-gas like mixing behavior and that too without exhibiting axis-switching behavior.

  9. Experimental study of elliptical jet from sub to supercritical conditions

    Energy Technology Data Exchange (ETDEWEB)

    Muthukumaran, C. K.; Vaidyanathan, Aravind, E-mail: aravind7@iist.ac.in [Department of Aerospace Engineering, Indian Institute of Space Science and Technology, Trivandrum, Kerala 695547 (India)

    2014-04-15

    The jet mixing at supercritical conditions involves fluid dynamics as well as thermodynamic phenomena. All the jet mixing studies at critical conditions to the present date have focused only on axisymmetric jets. When the liquid jet is injected into supercritical environment, the thermodynamic transition could be well understood by considering one of the important fluid properties such as surface tension since it decides the existence of distinct boundary between the liquid and gaseous phase. It is well known that an elliptical liquid jet undergoes axis-switching phenomena under atmospheric conditions due to the presence of surface tension. The experimental investigations were carried out with low speed elliptical jet under supercritical condition. Investigation of the binary component system with fluoroketone jet and N{sub 2} gas as environment shows that the surface tension force dominates for a large downstream distance, indicating delayed thermodynamic transition. The increase in pressure to critical state at supercritical temperature is found to expedite the thermodynamic transition. The ligament like structures has been observed rather than droplets for supercritical pressures. However, for the single component system with fluoroketone jet and fluoroketone environment shows that the jet disintegrates into droplets as it is subjected to the chamber conditions even for the subcritical pressures and no axis switching phenomenon is observed. For a single component system, as the pressure is increased to critical state, the liquid jet exhibits gas-gas like mixing behavior and that too without exhibiting axis-switching behavior.

  10. MALEIC ANHYDRIDE HYDROGENATION OF PD/AL2O3 CATALYST UNDER SUPERCRITICAL CO2 MEDIUM

    Science.gov (United States)

    Hydrogenation of maleic anhydride (MA) to either y-butyrolactone of succinic anhydride over simple Pd/Al2O3 impregnated catalyst in supercritical CO2 medium has been studied at different temperatures and pressures. A comparison of the supercritical CO2 medium reaction with the c...

  11. Study on Supercritical Fluid Extraction of Pu(Ⅳ)in Simulative Contaminated Soils

    Institute of Scientific and Technical Information of China (English)

    SONG; Zhi-jun; DING; You-qian; ZHOU; Li-qiang

    2015-01-01

    Supercritical fluid has advantages of rapid mass transfer and high solubility,which can extract different substance through changing the extracting temperature and pressure.So in comparison to conventional solvent extraction process,supercritical fluid extraction do not need to pretreatment of the matrix,minimizes the amount of secondary waste,and the extraction

  12. Modeling the outflow of liquid with initial supercritical parameters using the relaxation model for condensation

    Directory of Open Access Journals (Sweden)

    Lezhnin Sergey

    2017-01-01

    Full Text Available The two-temperature model of the outflow from a vessel with initial supercritical parameters of medium has been realized. The model uses thermodynamic non-equilibrium relaxation approach to describe phase transitions. Based on a new asymptotic model for computing the relaxation time, the outflow of water with supercritical initial pressure and super- and subcritical temperatures has been calculated.

  13. Modelling and simulation of the steam line, the high and low pressure turbines and the pressure regulator for the SUN-RAH nucleo electric university simulator; Modelado y simulacion de la linea de vapor, las turbinas de alta y de baja presion y el regulador de presion para el simulador universitario de nucleo electricas SUN RAH

    Energy Technology Data Exchange (ETDEWEB)

    Lopez R, A. [DEPFI, Campus Morelos, en IMTA Jiutepec, Morelos, UNAM (Mexico)]. e-mail: andyskamx@yahoo.com.mx

    2003-07-01

    In the following article the development of a simulator that allows to represent the dynamics of the following systems: steam line, nozzle, vapor separator, reheater, high pressure turbine, low pressure turbine, power generator and the pressure regulator of a nucleo electric power station. We start from the supposition that this plant will be modeled from a nuclear reactor type BWR (Boiling Water Reactor), using models of reduced order that represent the more important dynamic variables of the physical processes that happen along the steam line until the one generator. To be able to carry out the simulation in real time the Mat lab mathematical modeling software is used, as well as the specific simulation tool Simulink. It is necessary to point out that the platform on which the one is executed the simulator is the Windows operating system, to allow the intuitive use that only this operating system offers. The above-mentioned obeys to that the objective of the simulator it is to help the user to understand some of the dynamic phenomena that are present in the systems of a nuclear plant, and to provide a tool of analysis and measurement of variables to predict the desirable behavior of the same ones. The model of a pressure controller for the steam lines, the high pressure turbine and the low pressure turbine is also presented that it will be the one in charge of regulating the demand of the system according to the characteristics and critic restrictions of safety and control, assigned according to those wanted parameters of performance of this system inside the nucleo electric plant. This simulator is totally well defined and it is part of the University student nucleo electric simulator with Boiling Water Reactor (SUN-RAH), an integral project and of greater capacity. (Author)

  14. Validation of Hiriart equation to compute steam production by the lip pressure method; Validacion de la ecuacion de Hiriart para calculo de gasto de vapor por el metodo de presion de labio

    Energy Technology Data Exchange (ETDEWEB)

    Flores Armenta, Magaly [Gerencia de Proyectos Geotermoelectricos de la Comision Federal de Electricidad, Morelia (Mexico)

    1996-09-01

    Mainly in new geothermal wells, it is necessary to evaluate the production in a very fast, simple and not expensive way, to know the convenience to install surface equipment, such as silencers and separators, to drive the steam to the commercial gathering system. In practice, one of the most known methods is the lip pressure one, which requires a simple set of installations. The objective of this paper is to validate the steam flow rate calculated by the lip pressure method, with respect to the ASME method. The ASME method is known for its accuracy, and is done by measuring the steam and liquid after a high pressure separator, by an orifice plate of known diameter and a triangular weir. Results of the validation show up the feasibility of application of the lip pressure method by using a simple adjustment equation. Percentage of mistake results less than 1%, without any notable influence of the production enthalpy. That equation to be applied in a general case, is as follows: Q{nu} =(20642)(F*P*D{sup 2}/{radical}h-2000). For the particular case of the Los Azufres geothermal field, the equation is: Q{nu}= 810*P*D{sup 2} [Espanol] En los pozos geotermicos, principalmente en los nuevos, es necesario evaluar su produccion de manera rapida, sencilla y economica, para determinar la conveniencia de instalar equipo superficial, como separadores, silenciadores, etc., que permita la integracion del vapor al sistema comercial de generacion electrica. Para fines practicos uno de los metodos mas conocidos es el de presion de labio, que solo requiere un arreglo sencillo de instalaciones superficiales. En este documento se validan y ajustan los calculos de produccion de vapor por ese metodo de presion de labio, con respecto a las mediciones exactas efectuadas con el metodo ASME. Este ultimo es reconocido internacionalmente por su precision, y se lleva a cabo separando la mezcla obtenida en superficie en un recipiente a presion para medir el vapor a traves de una placa de orificio

  15. Development and design of advanced heat recovery steam generator

    Energy Technology Data Exchange (ETDEWEB)

    Peral, V.; Roa, A. [Babcock & Wilcox Espanola (Spain)

    1998-12-31

    The work carried out investigated: cycle considerations, pressure dependence between superheater and reheater and the condenser vacuum pressure; boiler restrictions by pinch points and heat available; and boiler design. The starting point was based on design experience of IGCC power plant at Puertollano. In this case, the heat recovery boiler has been designed for two fuel types: mixed coal and natural gas. The design of the boiler is in agreement with these two cases achieving highest steam temperature with natural gas and due to high pressure steam imported, the steam flow and pressure to turbine is higher with mixed coal + petroleum coke. The last section provides the construction data. 6 figs.

  16. Quick-homogeneous Corrosion of Ti-2Al-2.5Zr Alloy in High-temperature and High-pressure Water Steam

    Institute of Scientific and Technical Information of China (English)

    2001-01-01

    The corrosion behavior of Ti-2Al-2.5Zr alloy with 5 alloy contents and 5 surface states were studied in water steam at 400°C, 10.3 MPa for 72 h. The weight-increments of all samples are under 4 mg/dm2, better than Zr and Zr-alloy. α-Ti is oxidized into anatase-type TiO2 preferentially. The corrosion resistance is improved by adding Al element or pre-oxidizing treatment, the latter is more effective relatively.

  17. Supercritical fluid reverse micelle separation

    Science.gov (United States)

    Fulton, John L.; Smith, Richard D.

    1993-01-01

    A method of separating solute material from a polar fluid in a first polar fluid phase is provided. The method comprises combining a polar fluid, a second fluid that is a gas at standard temperature and pressure and has a critical density, and a surfactant. The solute material is dissolved in the polar fluid to define the first polar fluid phase. The combined polar and second fluids, surfactant, and solute material dissolved in the polar fluid is maintained under near critical or supercritical temperature and pressure conditions such that the density of the second fluid exceeds the critical density thereof. In this way, a reverse micelle system defining a reverse micelle solvent is formed which comprises a continuous phase in the second fluid and a plurality of reverse micelles dispersed in the continuous phase. The solute material is dissolved in the polar fluid and is in chemical equilibrium with the reverse micelles. The first polar fluid phase and the continuous phase are immiscible. The reverse micelles each comprise a dynamic aggregate of surfactant molecules surrounding a core of the polar fluid. The reverse micelle solvent has a polar fluid-to-surfactant molar ratio W, which can vary over a range having a maximum ratio W.sub.o that determines the maximum size of the reverse micelles. The maximum ratio W.sub.o of the reverse micelle solvent is then varied, and the solute material from the first polar fluid phase is transported into the reverse micelles in the continuous phase at an extraction efficiency determined by the critical or supercritical conditions.

  18. Supercritical fluid reverse micelle separation

    Science.gov (United States)

    Fulton, J.L.; Smith, R.D.

    1993-11-30

    A method of separating solute material from a polar fluid in a first polar fluid phase is provided. The method comprises combining a polar fluid, a second fluid that is a gas at standard temperature and pressure and has a critical density, and a surfactant. The solute material is dissolved in the polar fluid to define the first polar fluid phase. The combined polar and second fluids, surfactant, and solute material dissolved in the polar fluid is maintained under near critical or supercritical temperature and pressure conditions such that the density of the second fluid exceeds the critical density thereof. In this way, a reverse micelle system defining a reverse micelle solvent is formed which comprises a continuous phase in the second fluid and a plurality of reverse micelles dispersed in the continuous phase. The solute material is dissolved in the polar fluid and is in chemical equilibrium with the reverse micelles. The first polar fluid phase and the continuous phase are immiscible. The reverse micelles each comprise a dynamic aggregate of surfactant molecules surrounding a core of the polar fluid. The reverse micelle solvent has a polar fluid-to-surfactant molar ratio W, which can vary over a range having a maximum ratio W[sub o] that determines the maximum size of the reverse micelles. The maximum ratio W[sub o] of the reverse micelle solvent is then varied, and the solute material from the first polar fluid phase is transported into the reverse micelles in the continuous phase at an extraction efficiency determined by the critical or supercritical conditions. 27 figures.

  19. Mathematical modeling of control system for the experimental steam generator

    Directory of Open Access Journals (Sweden)

    Podlasek Szymon

    2016-01-01

    Full Text Available A steam generator is an essential unit of each cogeneration system using steam machines. Currently one of the cheapest ways of the steam generation can be application of old steam generators came from army surplus store. They have relatively simple construction and in case of not so exploited units – quite good general conditions, and functionality of mechanical components. By contrast, electrical components and control systems (mostly based on relay automatics are definitely obsolete. It is not possible to use such units with cooperation of steam bus or with steam engines. In particular, there is no possibility for automatically adjustment of the pressure and the temperature of the generated steam supplying steam engines. Such adjustment is necessary in case of variation of a generator load. The paper is devoted to description of improvement of an exemplary unit together with construction of the measurement-control system based on a PLC. The aim was to enable for communication between the steam generator and controllers of the steam bus and steam engines in order to construction of a complete, fully autonomic and maintenance-free microcogeneration system.

  20. Mathematical modeling of control system for the experimental steam generator

    Science.gov (United States)

    Podlasek, Szymon; Lalik, Krzysztof; Filipowicz, Mariusz; Sornek, Krzysztof; Kupski, Robert; Raś, Anita

    2016-03-01

    A steam generator is an essential unit of each cogeneration system using steam machines. Currently one of the cheapest ways of the steam generation can be application of old steam generators came from army surplus store. They have relatively simple construction and in case of not so exploited units - quite good general conditions, and functionality of mechanical components. By contrast, electrical components and control systems (mostly based on relay automatics) are definitely obsolete. It is not possible to use such units with cooperation of steam bus or with steam engines. In particular, there is no possibility for automatically adjustment of the pressure and the temperature of the generated steam supplying steam engines. Such adjustment is necessary in case of variation of a generator load. The paper is devoted to description of improvement of an exemplary unit together with construction of the measurement-control system based on a PLC. The aim was to enable for communication between the steam generator and controllers of the steam bus and steam engines in order to construction of a complete, fully autonomic and maintenance-free microcogeneration system.

  1. A universal salt model based on under-ground precipitation of solid salts due to supercritical water `out-salting'

    Science.gov (United States)

    Rueslåtten, H.; Hovland, M. T.

    2010-12-01

    One of the common characteristics of planets Earth and Mars is that both host water (H2O) and large accumulations of salt. Whereas Earth’s surface-environment can be regarded as ‘water-friendly’ and ‘salt hostile’, the reverse can be said for the surface of Mars. This is because liquid water is stable on Earth, and the atmosphere transports humidity around the globe, whereas on planet Mars, liquid water is unstable, rendering the atmosphere dry and, therefore, ‘salt-friendly’. The riddle as to how the salt accumulated in various locations on those two planets, is one of long-lasting and great debate. The salt accumulations on Earth are traditionally termed ‘evaporites’, meaning that they formed as a consequence of the evaporation of large masses of seawater. How the accumulations on Mars formed is much harder to explain, as an ocean only existed briefly. Although water molecules and OH-groups may exist in abundance in bound form (crystal water, adsorbed water, etc.), the only place where free water is expected to be stable on Mars is within underground faults, fractures, and crevices. Here it likely occurs as brine or in the form of ice. Based on these conditions, a key to understanding the accumulation of large deposits of salt on both planets is linked to how brines behave in the subsurface when pressurized and heated beyond their supercritical point. At depths greater than about 3 km (P>300 bars) water will no longer boil in a steam phase. Rather, it becomes supercritical and will attain the phase of supercritical water vapor (SCRIW) with a specific gravity of typically 0.3 g/cm3. An important characteristic of SCRIW is its inability to dissolve the common sea salts. The salt dissolved in the brines will therefore precipitate as solid particles when brines (seawater on the Earth) move into the supercritical P&T-domain (T>400°C, P>300 bars). Numerical modeling of a hydrothermal system in the Atlantis II Deep of the Red Sea indicates that a

  2. Thermodynamics of supersaturated steam: Molecular simulation results

    Science.gov (United States)

    Moučka, Filip; Nezbeda, Ivo

    2016-12-01

    Supersaturated steam modeled by the Gaussian charge polarizable model [P. Paricaud, M. Předota, and A. A. Chialvo, J. Chem. Phys. 122, 244511 (2005)] and BK3 model [P. Kiss and A. Baranyai, J. Chem. Phys. 138, 204507 (2013)] has been simulated at conditions occurring in steam turbines using the multiple-particle-move Monte Carlo for both the homogeneous phase and also implemented for the Gibbs ensemble Monte Carlo molecular simulation methods. Because of these thermodynamic conditions, a specific simulation algorithm has been developed to bypass common simulation problems resulting from very low densities of steam and cluster formation therein. In addition to pressure-temperature-density and orthobaric data, the distribution of clusters has also been evaluated. The obtained extensive data of high precision should serve as a basis for development of reliable molecular-based equations for properties of metastable steam.

  3. Long term steam oxidation of TP 347H FG in power plants

    DEFF Research Database (Denmark)

    Hansson, Anette Nørgaard; Korcakova, Leona; Hald, John

    2005-01-01

    The long term oxidation behaviour of TP 347H FG at ultra supercritical steam conditions was assessed by exposing the steel in test superheater loops in a Danish coal-fired power plant. The steamside oxide layer was investigated with scanning electron microscopy and energy dispersive Xray diffract......The long term oxidation behaviour of TP 347H FG at ultra supercritical steam conditions was assessed by exposing the steel in test superheater loops in a Danish coal-fired power plant. The steamside oxide layer was investigated with scanning electron microscopy and energy dispersive Xray...... diffraction in order to reveal the effect of oxidation time and temperature on the microstructure. A double layered oxide formed during steam oxidation. The morphology of the inner Cr-containing layer was influenced by the oxidation temperature. At temperatures below 585 degrees C, it consisted of regions...

  4. On the Behavior of a Shear-Coaxial Jet, Spanning Sub- to Supercritical Pressures, with and without an Externally Imposed Transverse Acoustic Field

    Science.gov (United States)

    2006-05-01

    processes. For example, Zuo and Stenby [13] used a modified form of the Soave Redlich Kwong equation of state along with the assumption of a linear density...causes combustion instability, but all have limited ranges of applicability (see Hulka and Hutt [3]). 4 Liquid rocket engines, burning cryogenic...propulsion applications were performed at low pressure, even though many liquid rocket engines are operated at pressures well above the critical

  5. Failure analysis of retired steam generator tubings

    Energy Technology Data Exchange (ETDEWEB)

    Kim, Hong Pyo; Kim, J. S.; Hwang, S. S. and others

    2005-04-15

    Degradation of steam generator leads to forced outage and extension of outage, which causes increase in repair cost, cost of purchasing replacement power and radiation exposure of workers. Steam generator tube rupture incident occurred in Uljin 4 in 2002, which made public sensitive to nuclear power plant. To keep nuclear energy as a main energy source, integrity of steam generator should be demonstrated. Quantitative relationship between ECT(eddy current test) signal and crack size is needed in assesment of integrity of steam generator in pressurized water reactor. However, it is not fully established for application in industry. Retired steam generator of Kori 1 has many kinds of crack such as circumferential and axial primary water stress corrosion crack and outer diameter stress corrosion crack(ODSCC). So, it can be used in qualifying and improving ECT technology and in condition monitoring assesment for crack detected in ISI(in service inspection). In addition, examination of pulled tube of Kori 1 retired steam generator will give information about effectiveness of non welded sleeving technology which was employed to repair defect tubes and remedial action which was applied to mitigate ODSCC. In this project, hardware such as semi hot lab. for pulled tube examination and modification transportation cask for pulled tube and software such as procedure of transportation of radioactive steam generator tube and non-destructive and destructive examination of pulled tube were established. Non-destructive and destructive examination of pulled tubes from Kori 1 retired steam generator were performed in semi hot lab. Remedial actions applied to Kori 1 retired steam generator, PWSCC trend and bulk water chemistry and crevice chemistry in Kori 1 were evaluated. Electrochemical decontamination technology for pulled tube was developed to reduce radiation exposure and enhance effectiveness of pulled tube examination. Multiparameter algorithm developed at ANL, USA was

  6. SOLID PHASE TRANSITION OF SYNDIOTACTIC POLYSTYRENE IN SUPERCRITICAL CO2

    Institute of Scientific and Technical Information of China (English)

    Yu-ying Li; Jia-song He

    2002-01-01

    Solid phase transition of the a form crystals to the β form crystals in syndiotactic polystyrene (sPS) samples has occurred in supercritical CO2. This transformation is different from those detected under other conditions. The effects of some factors (e.g. time, temperature, and pressure) on the solid phase transformation of sPS in supercritical CO2 were analyzed in detail. Experimental results show that longer time, higher temperature or higher pressure favors the transformation of the α form crystals to the β form crystals.

  7. Extraction of oil from wheat germ by supercritical CO2.

    Science.gov (United States)

    Piras, Alessandra; Rosa, Antonella; Falconieri, Danilo; Porcedda, Silvia; Dessì, Maria A; Marongiu, Bruno

    2009-07-15

    This study examined the supercritical fluid extraction of wheat germ oil. The effects of pressure (200-300 bar at 40 degrees C) and extraction time on the oil quality/quantity were studied. A comparison was also made between the relative qualities of material obtained by SFE and by organic solvent extraction. The extracts were analyzed for alpha-tocopherol and polyunsaturated fatty acid content. The maximum wheat germ oil yield at about 9% was obtained with supercritical carbon dioxide extraction at 300 bar, while fatty acid and alpha-tocopherol composition of the extracts was not remarkable affected by either pressure or the extraction method.

  8. Numerical simulation in steam injection process by a mechanistic approach

    Energy Technology Data Exchange (ETDEWEB)

    De Souza, J.C.Jr.; Campos, W.; Lopes, D.; Moura, L.S.S. [Petrobras, Rio de Janeiro (Brazil)

    2008-10-15

    Steam injection is a common thermal recovery method used in very viscous oil reservoirs. The method involves the injection of heat to reduce viscosity and mobilize oil. A steam generation and injection system consists primarily of a steam source, distribution lines, injection wells and a discarding tank. In order to optimize injection and improve the oil recovery factor, one must determine the parameters of steam flow such as pressure, temperature and steam quality. This study focused on developing a unified mathematical model by means of a mechanistic approach for two-phase steam flow in pipelines and wells. The hydrodynamic and heat transfer mechanistic model was implemented in a computer simulator to model the parameters of steam injection while trying to avoid the use of empirical correlations. A marching algorithm was used to determine the distribution of pressure and temperature along the pipelines and wellbores. The mathematical model for steam flow in injection systems, developed by a mechanistic approach (VapMec) performed well when the simulated values of pressures and temperatures were compared with the values measured during field tests. The newly developed VapMec model was incorporated in the LinVap-3 simulator that constitutes an engineering supporting tool for steam injection wells operated by Petrobras. 23 refs., 7 tabs., 6 figs.

  9. Effects of Gravity on Supercritical Water Oxidation (SCWO) Processes

    Science.gov (United States)

    Hegde, Uday; Hicks, Michael

    2013-01-01

    The effects of gravity on the fluid mechanics of supercritical water jets are being studied at NASA to develop a better understanding of flow behaviors for purposes of advancing supercritical water oxidation (SCWO) technologies for applications in reduced gravity environments. These studies provide guidance for the development of future SCWO experiments in new experimental platforms that will extend the current operational range of the DECLIC (Device for the Study of Critical Liquids and Crystallization) Facility on board the International Space Station (ISS). The hydrodynamics of supercritical fluid jets is one of the basic unit processes of a SCWO reactor. These hydrodynamics are often complicated by significant changes in the thermo-physical properties that govern flow behavior (e.g., viscosity, thermal conductivity, specific heat, compressibility, etc), particularly when fluids transition from sub-critical to supercritical conditions. Experiments were conducted in a 150 ml reactor cell under constant pressure with water injections at various flow rates. Flow configurations included supercritical jets injected into either sub-critical or supercritical water. Profound gravitational influences were observed, particularly in the transition to turbulence, for the flow conditions under study. These results will be presented and the parameters of the flow that control jet behavior will be examined and discussed.

  10. Steam generator tubesheet waterlancing at Bruce B

    Energy Technology Data Exchange (ETDEWEB)

    Persad, R. [Babcock and Wilcox Canada, Cambridge, Ontario (Canada); Eybergen, D. [Bruce Power, Tiverton, Ontario (Canada)

    2006-07-01

    High pressure water cleaning of steam generator secondary side tubesheet surfaces is an important and effective strategy for reducing or eliminating under-deposit chemical attack of the tubing. At the Bruce B station, reaching the interior of the tube bundle with a high-pressure water lance is particularly challenging due to the requirement to setup on-boiler equipment within the containment bellows. This paper presents how these and other design constraints were solved with new equipment. Also discussed is the application of new high-resolution inter-tube video probe capability to the Bruce B steam generator tubesheets. (author)

  11. The pseudocritical regions for supercritical water

    Energy Technology Data Exchange (ETDEWEB)

    Imre, A.R., E-mail: imre.attila@energia.mta.hu [HAS Centre for Energy Research, Thermohydraulics Department, P.O. Box 49, H-1525 Budapest (Hungary); University Cologne, Institute for Physical Chemistry, Luxemburger Str. 116, D-50939 Koeln (Germany); Deiters, U.K.; Kraska, T. [University Cologne, Institute for Physical Chemistry, Luxemburger Str. 116, D-50939 Koeln (Germany); Tiselj, I. [Jozef Stefan Institute, Reactor Engineering Division, Jamova 39, 1000 Ljubljana (Slovenia)

    2012-11-15

    Highlights: Black-Right-Pointing-Pointer Supercritical water behaves anomalously around the Widom lines. Black-Right-Pointing-Pointer We calculated the location of the Widom lines for several thermodynamic functions. Black-Right-Pointing-Pointer Simple quadratic fitting equations are given to describe these lines. - Abstract: Vapour pressure curves and stability lines can be extended beyond the critical points into the supercritical domain by so-called Widom lines, along which some thermodynamic property undergoes a rapid change and liquid-like behaviour turns to vapour-like one. Knowledge about such lines is therefore important for thermohydraulic calculations and design. There are several properties that can be chosen as defining property of a Widom line. In this short note we calculate and compare several kinds of Widom lines for water.

  12. Depolymerization of polyethylene terephthalate in supercritical methanol

    Science.gov (United States)

    Goto, Motonobu; Koyamoto, Hiroshi; Kodama, Akio; Hirose, Tsutomu; Nagaoka, Shoji

    2002-11-01

    The degradation of polyethylene terephthalate (PET) in supercritical methanol was investigated with the aim of developing a process for chemical recycling of waste plastics. A batch reactor was used at temperatures of 573-623 K under an estimated pressure of 20 MPa for a reaction time of 2-120 min. PET was decomposed to its monomers, dimethyl terephthalate and ethylene glycol, by methanolysis in supercritical methanol. The reaction products were analysed using size-exclusion chromatography, gas chromatography-mass spectrometry, and reversed-phase liquid chromatography. The molecular weight distribution of the products was obtained as a function of reaction time. The yields of monomer components of the decomposition products including by-products were measured. Continuous kinetics analysis was performed on the experimental data.

  13. Using supercritical fluids to refine hydrocarbons

    Science.gov (United States)

    Yarbro, Stephen Lee

    2014-11-25

    This is a method to reactively refine hydrocarbons, such as heavy oils with API gravities of less than 20.degree. and bitumen-like hydrocarbons with viscosities greater than 1000 cp at standard temperature and pressure using a selected fluid at supercritical conditions. The reaction portion of the method delivers lighter weight, more volatile hydrocarbons to an attached contacting device that operates in mixed subcritical or supercritical modes. This separates the reaction products into portions that are viable for use or sale without further conventional refining and hydro-processing techniques. This method produces valuable products with fewer processing steps, lower costs, increased worker safety due to less processing and handling, allow greater opportunity for new oil field development and subsequent positive economic impact, reduce related carbon dioxide, and wastes typical with conventional refineries.

  14. Supercritical fluid thermodynamics from equations of state

    Science.gov (United States)

    Giovangigli, Vincent; Matuszewski, Lionel

    2012-03-01

    Supercritical multicomponent fluid thermodynamics are often built from equations of state. We investigate mathematically such a construction of a Gibbsian thermodynamics compatible at low density with that of ideal gas mixtures starting from a pressure law. We further study the structure of chemical production rates obtained from nonequilibrium statistical thermodynamics. As a typical application, we consider the Soave-Redlich-Kwong cubic equation of state and investigate mathematically the corresponding thermodynamics. This thermodynamics is then used to study the stability of H2-O2-N2 mixtures at high pressure and low temperature as well as to illustrate the role of nonidealities in a transcritical H2-O2-N2 flame.

  15. Study of safety relief valve operation under ATWS conditions. [Supercritical flow

    Energy Technology Data Exchange (ETDEWEB)

    Hutmacher, E.S.; Whitten, S.D.

    1979-09-01

    In March 1979, the NRC published a report (NUREG/CR-0687) prepared by the Energy Technology Engineering Center (ETEC-TDR-78-19). That report presented a literature survey which updated earlier NRC studies of saturated or subcooled water flow through relief valves, under ATWS conditions. This supplement expands upon that search to include supercritical steam-water flow. No applicable data for the supercritical conditions were found, nor were any newer data on saturated or subcooled conditions uncovered. This supplement also updates a look for facilities currently capable of simultaneously imposing all ATWS conditions upon test relief valves. Results confirmed the negative findings of NUREG/CR-0687.

  16. Pressurized fluid extraction of essential oil from Lavandula hybrida using a modified supercritical fluid extractor and a central composite design for optimization.

    Science.gov (United States)

    Kamali, Hossein; Jalilvand, Mohammad Reza; Aminimoghadamfarouj, Noushin

    2012-06-01

    Essential oil components were extracted from lavandin (Lavandula hybrida) flowers using pressurized fluid extraction. A central composite design was used to optimize the effective extraction variables. The chemical composition of extracted samples was analyzed by a gas chromatograph-flame ionization detector column. For achieving 100% extraction yield, the temperature, pressure, extraction time, and the solvent flow rate were adjusted at 90.6°C, 63 bar, 30.4 min, and 0.2 mL/min, respectively. The results showed that pressurized fluid extraction is a practical technique for separation of constituents such as 1,8-cineole (8.1%), linalool (34.1%), linalyl acetate (30.5%), and camphor (7.3%) from lavandin to be applied in the food, fragrance, pharmaceutical, and natural biocides industries.

  17. 低压余热回收蒸汽发电技术在球团厂的应用%Application of the Technology of Power Generation with Low-pressure Steam from Recovered Waste Heat in a Pelletizing Plant

    Institute of Scientific and Technical Information of China (English)

    王荣雷

    2014-01-01

    The application of the technology of power generation with low-pressure steam from recovered waste heat in a pelletizing plant and the good economic results are discussed through introduction of a waste heat power generation project at a pelletizing plant of some steel company. The process flow, principle, main equipment and technical parameters and e-conomic result of the project are described in detail.%通过某公司球团厂余热发电项目的介绍,探讨低压余热回收蒸汽发电技术在球团厂的应用及其产生的良好经济效益。详细介绍了工艺流程、原理及主要设备技术参数、经济效益等。

  18. Boiler materials for ultra supercritical coal power plants

    Energy Technology Data Exchange (ETDEWEB)

    Purgert, Robert [Energy Industries of Ohio, Independence, OH (United States); Shingledecker, John [Electric Power Research Inst., Palo Alto, CA (United States); Pschirer, James [Alstom Power Inc., Windsor, CT (Untied States); Ganta, Reddy [Alstom Power Inc., Windsor, CT (Untied States); Weitzel, Paul [The Babcock & Wilcox Company, Baberton, OH (United States); Sarver, Jeff [The Babcock & Wilcox Company, Baberton, OH (United States); Vitalis, Brian [Riley Power Inc., Worchester, WA (United States); Gagliano, Michael [Foster Wheeler North America Corp., Hampton, NJ (United States); Stanko, Greg [Foster Wheeler North America Corp., Hampton, NJ (United States); Tortorelli, Peter [Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States)

    2015-12-29

    The U.S. Department of Energy (DOE) and the Ohio Coal Development Office (OCDO) have undertaken a project aimed at identifying, evaluating, and qualifying the materials needed for the construction of the critical components of coal-fired boilers capable of operating at much higher efficiencies than current generation of supercritical plants. This increased efficiency is expected to be achieved principally through the use of advanced ultrasupercritical (A-USC) steam conditions up to 760°C (1400°F) and 35 MPa (5000 psi). A limiting factor to achieving these higher temperatures and pressures for future A-USC plants are the materials of construction. The goal of this project is to assess/develop materials technology to build and operate an A-USC boiler capable of delivering steam with conditions up to 760°C (1400°F)/35 MPa (5000 psi). The project has successfully met this goal through a focused long-term public-private consortium partnership. The project was based on an R&D plan developed by the Electric Power Research Institute (EPRI) and an industry consortium that supplemented the recommendations of several DOE workshops on the subject of advanced materials. In view of the variety of skills and expertise required for the successful completion of the proposed work, a consortium led by the Energy Industries of Ohio (EIO) with cost-sharing participation of all the major domestic boiler manufacturers, ALSTOM Power (Alstom), Babcock and Wilcox Power Generation Group, Inc. (B&W), Foster Wheeler (FW), and Riley Power, Inc. (Riley), technical management by EPRI and research conducted by Oak Ridge National Laboratory (ORNL) has been developed. The project has clearly identified and tested materials that can withstand 760°C (1400°F) steam conditions and can also make a 700°C (1300°F) plant more economically attractive. In this project, the maximum temperature capabilities of these and other available high-temperature alloys have been assessed to provide a basis for

  19. Feasibility Study of Supercritical Light Water Cooled Fast Reactors for Actinide Burning and Electric Power Production, Progress Report for Work Through September 2002, 4th Quarterly Report

    Energy Technology Data Exchange (ETDEWEB)

    Mac Donald, Philip Elsworth

    2002-09-01

    The use of light water at supercritical pressures as the coolant in a nuclear reactor offers the potential for considerable plant simplification and consequent capital and O&M cost reduction compared with current light water reactor (LWR) designs. Also, given the thermodynamic conditions of the coolant at the core outlet (i.e. temperature and pressure beyond the water critical point), very high thermal efficiencies of the power conversion cycle are possible (i.e. up to about 45%). Because no change of phase occurs in the core, the need for steam separators and dryers as well as for BWR-type re-circulation pumps is eliminated, which, for a given reactor power, results in a substantially shorter reactor vessel and smaller containment building than the current BWRs. Furthermore, in a direct cycle the steam generators are not needed. If no additional moderator is added to the fuel rod lattice, it is possible to attain fast neutron energy spectrum conditions in a supercritical water-cooled reactor (SCWR). This type of core can make use of either fertile or fertile-free fuel and retain a hard spectrum to effectively burn plutonium and minor actinides from LWR spent fuel while efficiently generating electricity. One can also add moderation and design a thermal spectrum SCWR. The Generation IV Roadmap effort has identified the thermal spectrum SCWR (followed by the fast spectrum SCWR) as one of the advanced concepts that should be developed for future use. Therefore, the work in this NERI project is addressing both types of SCWRs.

  20. Fatigue life and damage evolution of martensitic steels for low-pressure steam turbine blades in the VHCF regime; Lebensdauer und Schaedigungsentwicklung martensitischer Staehle fuer Niederdruck-Dampfturbinenschaufeln bei Ermuedungsbeanspruchung im VHCF-Bereich

    Energy Technology Data Exchange (ETDEWEB)

    Kovacs, Stephan

    2014-07-01

    Low-pressure steam turbine blades are usually made of martensitic steels with Cr contents between 9 and 12%, which combine good corrosion resistance, high mechanical strength and sufficient ductility. The inhomogeneous flow field behind the vanes generates high-frequency oscillations above 1 kHz. In addition, the blades with lengths up to 1.5 m are operated at rotational speeds up to 3000 rpm, resulting in large centrifugal forces leading to the superposition of extremely high mean stresses. Also resonance oscillations during start-up and shutdown cannot be completely excluded. Currently, the components are designed using high safety factors against S-N curves with an assumed asymptotic fatigue limit above 107 load cycles. Nevertheless, fatigue cracks are observed even at high number of cycles, starting from the blade root without pre-damage by erosion or steam droplet impingement. While fatigue failure usually occurs at the surface, fatigue cracks at very high number of cycles (> 108) initiate at oxides or intermetallic inclusions below the surface. This transition between both failure mechanisms in the Very High-Cycle Fatigue (VHCF) regime is in the focus of numerous current research activities, because numbers of cycles above 108 can be attained in a viable period of time using the recently developed high-frequency testing techniques operated at 20 kHz. Also for wind turbines, gas turbines, bearings, springs, etc. VHCF issues become increasingly important. Within this work, the fatigue life and damage behavior of a martensitic Cr-steel during fatigue loading with and without high mean stresses at number of cycles to failure above 108 was analyzed. On the one hand, the studies gave insights into the relation between fatigue life and fatigue damage evolution of the investigated group of high-strength steels in the very high cycle fatigue regime (up to 2·109). In particular, the influence of high mean stresses on the VHCF behavior (fracture origin, crack growth

  1. Material developments for supercritical boilers and pipework. Bridging the gap?

    Energy Technology Data Exchange (ETDEWEB)

    Barnard, P.M.; Buchanan, L.W.; Barrie, M. [Doosan Power Systems Ltd, Renfrew (United Kingdom). Technology and Engineering

    2010-07-01

    This paper briefly reviews the current state of developments for ferritic, austenitic and nickel alloys for supercritical steam raising power plant applications. Some of the challenges are touches upon as well as various activities ongoing to meet these challenges. It is likely that, although the technical challenges are significant, developments in ferritic alloys will allow a more incremental increase in plant efficiency than the step change required to justify the cost of nickel alloys. This conclusion may change as the cost of fuel increases such that the economic and commercial risks of using nickel are compensated by the saving in fuel costs. (orig.)

  2. Equations for calculating the properties of dissociated steam

    Science.gov (United States)

    Aminov, R. Z.; Gudym, A. A.

    2017-08-01

    The equations of state for dissociated steam have been developed in the temperature and pressure ranges of 1250-2300 K and 0.01-10.00 MPa for calculating thermodynamic processes in thermal power units operating on high-temperature steam. These equations are based on the property tables for dissociated steam derived at a reference temperature of 0 K. It is assumed that the initial substance is steam, the dissociation of which—in accordance with the most likely chemical reactions—results in formation of molecules of hydrogen, oxygen, steam, hydroxyl, and atoms of oxygen and hydrogen. Differential thermodynamic correlations, considering a change in the chemical potential and the composition of the mixture, during the steam dissociation are used. A reference temperature of 0.01°C used in the calculation of parameters of nondissociated steam has been adopted to predict processes in thermal power units without matching the reference temperatures and to account for transformation of dissociated steam into its usual form for which there is the international system of equations with the water triple point of 0.01°C taken as the reference. In the investigated region, the deviation of dissociated steam properties from those of nondissociated steam, which increases with decreasing the pressure or increasing the temperature, was determined. For a pressure of 0.02 MPa and a temperature of 2200 K, these deviations are 512 kJ/kg for the enthalpy, 0.2574 kJ/(kg K) for the entropy, and 3.431 kJ/(kg K) for the heat capacity at constant pressure. The maximum deviation of the dissociated steam properties calculated by the developed equations from the handbook values that these equations are based on does not exceed 0.03-0.05%.

  3. Supercritical droplet combustion and related transport phenomena

    Science.gov (United States)

    Yang, Vigor; Hsieh, K. C.; Shuen, J. S.

    1993-01-01

    An overview of recent advances in theoretical analyses of supercritical droplet vaporization and combustion is conducted. Both hydrocarbon and cryogenic liquid droplets over a wide range of thermodynamic states are considered. Various important high-pressure effects on droplet behavior, such as thermodynamic non-ideality, transport anomaly, and property variation, are reviewed. Results indicate that the ambient gas pressure exerts significant control of droplet gasification and burning processes through its influence on fluid transport, gas-liquid interfacial thermodynamics, and chemical reactions. The droplet gasification rate increases progressively with pressure. However, the data for the overall burnout time exhibit a considerable change in the combustion mechanism at the criticl pressure, mainly as a result of reduced mass diffusivity and latent heat of vaporization with increased pressure. The influence of droplet size on the burning characteristics is also noted.

  4. Functioning efficiency of intermediate coolers of multistage steam-jet ejectors of steam turbines

    Science.gov (United States)

    Aronson, K. E.; Ryabchikov, A. Yu.; Brodov, Yu. M.; Zhelonkin, N. V.; Murmanskii, I. B.

    2017-03-01

    Designs of various types of intermediate coolers of multistage ejectors are analyzed and thermal effectiveness and gas-dynamic resistance of coolers are estimated. Data on quantity of steam condensed from steam-air mixture in stage I of an ejector cooler was obtained on the basis of experimental results. It is established that the amount of steam condensed in the cooler constitutes 0.6-0.7 and is almost independent of operating steam pressure (and, consequently, of steam flow) and air amount in steam-air mixture. It is suggested to estimate the amount of condensed steam in a cooler of stage I based on comparison of computed and experimental characteristics of stage II. Computation taking this hypothesis for main types of mass produced multistage ejectors into account shows that 0.60-0.85 of steam amount should be condensed in stage I of the cooler. For ejectors with "pipe-in-pipe" type coolers (EPO-3-200) and helical coolers (EO-30), amount of condensed steam may reach 0.93-0.98. Estimation of gas-dynamic resistance of coolers shows that resistance from steam side in coolers with built-in and remote pipe bundle constitutes 100-300 Pa. Gas-dynamic resistance of "pipein- pipe" and helical type coolers is significantly higher (3-6 times) compared with pipe bundle. However, performance by "dry" (atmospheric) air is higher for ejectors with relatively high gas-dynamic resistance of coolers than those with low resistance at approximately equal operating flow values of ejectors.

  5. Processing of polyolefin blends in supercritical propane solution

    Science.gov (United States)

    Han, Suh Joon

    New polymer blending methods are developed and studied by processing polyolefins in supercritical propane in this research. Polypropylene and ethylene copolymers were dissolved in supercritical propane, and processed via various paths and reactions, i.e., RESS (rapid expansion of supercritical solution), ICSS (isobaric crystallization from supercritical solution), and thermoplastic vulcanizate (TPV) formation. Each process resulted in a unique morphology of polyolefin blends. The effect of polyolefin microstructure on the solution behavior in supercritical propane was investigated, and the relationship between the morphology of the polyolefin blends and processing paths in supercritical propane solutions was established. To understand the thermodynamic properties of polyolefins in bulk and solutions, the solubility parameter was estimated by measurement of the internal pressure from the experimental P-V-T data for polyolefins in the melt state. As the short chain branch content in the ethylene copolymers increased, the internal pressure decreased. The cloud-point pressures of binary polymer solutions in propane decreased as the extent of short chain branching increased in the ethylene copolymers. At the same degree of branching, the cloud-point pressure decreased slightly with increasing branch length. The cloud-point pressures of a ternary polymer solution in the pressure-temperature phase diagrams were higher than those of binary polymer solutions at the same composition (indicating poorer solubility). Microfibers and microparticles (10 ˜ 50 mum diameter) were precipitated from the RESS process while microcellular foams were obtained from the ICSS process. The phase domains of the ethylene-butene (EB) copolymer in the polypropylene from the RESS process were smaller for highly branched EB copolymer. The surface morphology of ethylene copolymers in the microcelluar foams was also changed by increasing the branch content from microparticles to a viscous layer. New

  6. Numerical solution of the problem of optimizing the process of oil displacement by steam

    Science.gov (United States)

    Temirbekov, N. M.; Baigereyev, D. R.

    2016-06-01

    The paper is devoted to the problem of optimizing the process of steam stimulation on the oil reservoir by controlling the steam pressure on the injection well to achieve preassigned temperature distribution along the reservoir at a given time of development. The relevance of the study of this problem is related to the need to improve methods of heavy oil development, the proportion of which exceeds the reserves of light oils, and it tends to grow. As a mathematical model of oil displacement by steam, three-phase non-isothermal flow equations is considered. The problem of optimal control is formulated, an algorithm for the numerical solution is proposed. As a reference regime, temperature distribution corresponding to the constant pressure of injected steam is accepted. The solution of the optimization problem shows that choosing the steam pressure on the injection well, one can improve the efficiency of steam-stimulation and reduce the pressure of the injected steam.

  7. Conceptual design of a thermalhydraulic loop for multiple test geometries at supercritical conditions named Supercritical Phenomena Experimental Test Apparatus (SPETA)

    Science.gov (United States)

    Adenariwo, Adepoju

    The efficiency of nuclear reactors can be improved by increasing the operating pressure of current nuclear reactors. Current CANDU-type nuclear reactors use heavy water as coolant at an outlet pressure of up to 11.5 MPa. Conceptual SuperCritical Water Reactors (SCWRs) will operate at a higher coolant outlet pressure of 25 MPa. Supercritical water technology has been used in advanced coal plants and its application proves promising to be employed in nuclear reactors. To better understand how supercritical water technology can be applied in nuclear power plants, supercritical water loops are used to study the heat transfer phenomena as it applies to CANDU-type reactors. A conceptual design of a loop known as the Supercritical Phenomena Experimental Apparatus (SPETA) has been done. This loop has been designed to fit in a 9 m by 2 m by 2.8 m enclosure that will be installed at the University of Ontario Institute of Technology Energy Research Laboratory. The loop include components to safely start up and shut down various test sections, produce a heat source to the test section, and to remove reject heat. It is expected that loop will be able to investigate the behaviour of supercritical water in various geometries including bare tubes, annulus tubes, and multi-element-type bundles. The experimental geometries are designed to match the fluid properties of Canadian SCWR fuel channel designs so that they are representative of a practical application of supercritical water technology in nuclear plants. This loop will investigate various test section orientations which are the horizontal, vertical, and inclined to investigate buoyancy effects. Frictional pressure drop effects and satisfactory methods of estimating hydraulic resistances in supercritical fluid shall also be estimated with the loop. Operating limits for SPETA have been established to be able to capture the important heat transfer phenomena at supercritical conditions. Heat balance and flow calculations have

  8. Slug flow transitions in horizontal gas/liquid two-phase flows. Dependence on channel height and system pressure for air/water and steam/water two-phase flows

    Energy Technology Data Exchange (ETDEWEB)

    Nakamura, Hideo [Japan Atomic Energy Research Inst., Tokai, Ibaraki (Japan). Tokai Research Establishment

    1996-05-01

    The slug flow transitions and related phenomena for horizontal two-phase flows were studied for a better prediction of two-phase flows that typically appear during the reactor loss-of-coolant accidents (LOCAs). For better representation of the flow conditions experimentally, two large-scaled facility: TPTF for high-pressure steam/water two-phase flows and large duct test facility for air/water two-phase flows, were used. The visual observation of the flow using a video-probe was performed in the TPTF experiments for good understanding of the phenomena. The currently-used models and correlations based mostly on the small-scale low-pressure experiments were reviewed and improved based on these experimental results. The modified Taitel-Dukler model for prediction of transition into slug flow from wavy flow and the modified Steen-Wallis correlation for prediction of onset of liquid entrainment from the interfacial waves were obtained. An empirical correlation for the gas-liquid interfacial friction factor was obtained further for prediction of liquid levels at wavy flow. The region of slug flow regime that is generally under influences of the channel height and system pressure was predicted well when these models and correlations were applied together. (author). 90 refs.

  9. Reciprocating wear in a steam environment

    Energy Technology Data Exchange (ETDEWEB)

    Brown, L.J.; Gee, M.G. [National Physical Laboratory, Teddington, Middlesex (United Kingdom)

    2010-07-01

    Tests to simulate the wear between sliding components in steam power plant have been performed using a low frequency wear apparatus at elevated temperatures under static load, at ambient pressure, in a steam environment. The apparatus was modified to accept a novel method of steam delivery. The materials tested were pre-exposed in a flowing steam furnace at temperature for either 500 or 3000 hours to provide some simulation of long term ageing. The duration of each wear test was 50 hours and tests were also performed on as-received material for comparison purposes. Data has been compared with results of tests performed on non-oxidised material for longer durations and also on tests without steam to examine the effect of different environments. Data collected from each test consists of mass change, stub height measurement and friction coefficient as well as visual inspection of the wear track. Within this paper, it is reported that both pre-ageing and the addition of steam during testing clearly influence the friction between material surfaces. (orig.)

  10. Safety Picks up "STEAM"

    Science.gov (United States)

    Roy, Ken

    2016-01-01

    This column shares safety information for the classroom. STEAM subjects--science, technology, engineering, art, and mathematics--are essential for fostering students' 21st-century skills. STEAM promotes critical-thinking skills, including analysis, assessment, categorization, classification, interpretation, justification, and prediction, and are…

  11. Steam feed and effect of steam-thermal seal in thermolysis of tire shreds in a screw-type reactor

    Science.gov (United States)

    Kalitko, V. A.

    2010-05-01

    On the basis of experience in commercial operation, the effect of steam seal in tire-shred pyrolysis in a screw-type reactor with superheated steam has been considered and analytically substantiated; there, local steam feed produces the above effect at the total reduced pressure and keeps air from entering the reactor without sluices or valves used for hermetization of its loading and unloading. It has been shown that the increase in the production rate of pyrolysis due to the heating by steam amounts to 10-15% and is limited by the diffusion transfer in the reactor’s charge bed.

  12. Oxidation behavior of Incoloy 800 under simulated supercritical water conditions

    Energy Technology Data Exchange (ETDEWEB)

    Fulger, M. [Institute for Nuclear Research Pitesti, POB 78, Campului Street, No. 1, 115400 Mioveni (Romania)], E-mail: manuela.fulger@nuclear.ro; Ohai, D.; Mihalache, M.; Pantiru, M. [Institute for Nuclear Research Pitesti, POB 78, Campului Street, No. 1, 115400 Mioveni (Romania); Malinovschi, V. [University of Pitesti, Research Center for Advanced Materials, Targul din Vale Street, No. 1, 110040 Pitesti (Romania)

    2009-03-31

    For a correct design of supercritical water-cooled reactor (SCWR) components, data regarding the behavior of candidate materials in supercritical water are necessary. Corrosion has been identified as a critical problem because the high temperature and the oxidative nature of supercritical water may accelerate the corrosion kinetics. The goal of this paper is to investigate the oxidation behavior of Incoloy 800 exposed in autoclaves under supercritical water conditions for up to 1440 h. The exposure conditions (thermal deaerated water, temperatures of 723, 773, 823 and 873 K and a pressure of 25 MPa) have been selected as relevant for a supercritical power plant concept. To investigate the structural changes of the oxide films, X-ray diffraction (XRD), scanning electron microscopy (SEM), energy dispersive X-ray spectrometry (EDX) and electrochemical impedance spectroscopy (EIS) analyses were used. Results show changes in the oxides chemical composition, microstructure and thickness versus testing conditions (pressure, temperature and time). The oxide films are composed of two layers: an outer layer enriched in Fe oxide and an inner layer enriched in Cr and Ni oxides corresponding to small cavities supposedly due to internal oxidation.

  13. Experimental study of elliptical jet from supercritical to subcritical conditions using planar laser induced fluorescence

    Science.gov (United States)

    Muthukumaran, C. K.; Vaidyanathan, Aravind

    2015-03-01

    The study of fluid jet dynamics at supercritical conditions involves strong coupling between fluid dynamic and thermodynamic phenomena. Beyond the critical point, the liquid-vapor coexistence ceases to exist, and the fluid exists as a single phase known as supercritical fluid with its properties that are entirely different from liquids and gases. At the critical point, the liquids do not possess surface tension and latent heat of evaporation. Around the critical point, the fluid undergoes large changes in density and possesses thermodynamic anomaly like enhancement in thermal conductivity and specific heat. In the present work, the transition of the supercritical and near-critical elliptical jet into subcritical as well as supercritical environment is investigated experimentally with nitrogen and helium as the surrounding environment. Under atmospheric condition, a liquid jet injected from the elliptical orifice exhibits axis switching phenomena. As the injection temperature increases, the axis switching length also increases. Beyond the critical temperature, the axis switching is not observed. The investigation also revealed that pressure plays a major role in determining the thermodynamic transition of the elliptical jet only for the case of supercritical jet injected into subcritical chamber conditions. At larger pressures, the supercritical jet undergoes disintegration and formation of droplets in the subcritical environment is observed. However, for supercritical jet injection into supercritical environment, the gas-gas like mixing behavior is observed.

  14. Experimental study of elliptical jet from supercritical to subcritical conditions using planar laser induced fluorescence

    Energy Technology Data Exchange (ETDEWEB)

    Muthukumaran, C. K.; Vaidyanathan, Aravind, E-mail: aravind7@iist.ac.in [Department of Aerospace Engineering, Indian Institute of Space Science and Technology, Trivandrum, Kerala 695547 (India)

    2015-03-15

    The study of fluid jet dynamics at supercritical conditions involves strong coupling between fluid dynamic and thermodynamic phenomena. Beyond the critical point, the liquid-vapor coexistence ceases to exist, and the fluid exists as a single phase known as supercritical fluid with its properties that are entirely different from liquids and gases. At the critical point, the liquids do not possess surface tension and latent heat of evaporation. Around the critical point, the fluid undergoes large changes in density and possesses thermodynamic anomaly like enhancement in thermal conductivity and specific heat. In the present work, the transition of the supercritical and near-critical elliptical jet into subcritical as well as supercritical environment is investigated experimentally with nitrogen and helium as the surrounding environment. Under atmospheric condition, a liquid jet injected from the elliptical orifice exhibits axis switching phenomena. As the injection temperature increases, the axis switching length also increases. Beyond the critical temperature, the axis switching is not observed. The investigation also revealed that pressure plays a major role in determining the thermodynamic transition of the elliptical jet only for the case of supercritical jet injected into subcritical chamber conditions. At larger pressures, the supercritical jet undergoes disintegration and formation of droplets in the subcritical environment is observed. However, for supercritical jet injection into supercritical environment, the gas-gas like mixing behavior is observed.

  15. Cryogenic Cooling System for Zero-Venting Storage of Supercritical Air Packs Project

    Data.gov (United States)

    National Aeronautics and Space Administration — Supercritical air at cryogenic temperature is an attractive source of breathing air because of its very high density and low pressure. However, heat leak into the...

  16. Cryogenic Cooling System for Zero-Venting Storage of Supercritical Air Packs Project

    Data.gov (United States)

    National Aeronautics and Space Administration — Supercritical air at cryogenic temperature is an attractive source of breathing air because of its very high density and low pressure. However, heat leak into the...

  17. Selected aspects of operation of supercritical (transcritical organic Rankine cycle

    Directory of Open Access Journals (Sweden)

    Mocarsk Szymon

    2015-06-01

    Full Text Available The paper presents a literature review on the topic of vapour power plants working according to the two-phase thermodynamic cycle with supercritical parameters. The main attention was focused on a review of articles and papers on the vapour power plants working using organic circulation fluids powered with low- and medium-temperature heat sources. Power plants with water-steam cycle supplied with a high-temperature sources have also been shown, however, it has been done mainly to show fundamental differences in the efficiency of the power plant and applications of organic and water-steam cycles. Based on a review of available literature references a comparative analysis of the parameters generated by power plants was conducted, depending on the working fluid used, the type and parameters of the heat source, with particular attention to the needs of power plant internal load.

  18. Production of D-lactic acid from sugarcane bagasse using steam-explosion

    Science.gov (United States)

    Sasaki, Chizuru; Okumura, Ryosuke; Asakawa, Ai; Asada, Chikako; Nakamura, Yoshitoshi

    2012-03-01

    This study investigated the production of D-lactic acid from unutilized sugarcane bagasse using steam explosion pretreatment. The optimal steam pressure for a steaming time of 5 min was determined. By enzymatic saccharification using Meicellase, the highest recovery of glucose from raw bagasse, 73.7%, was obtained at a steam pressure of 20 atm. For residue washed with water after steam explosion, the glucose recovery increased up to 94.9% at a steam pressure of 20 atm. These results showed that washing with water is effective in removing enzymatic reaction inhibitors. After steam pretreatment (steam pressure of 20 atm), D-lactic acid was produced by Lactobacillus delbrueckii NBRC 3534 from the enzymatic hydrolyzate of steam-exploded bagasse and washed residue. The conversion rate of D-lactic acid obtained from the initial glucose concentration was 66.6% for the hydrolyzate derived from steam-exploded bagasse and 90.0% for that derived from the washed residue after steam explosion. These results also demonstrated that the hydrolyzate of steam-exploded bagasse (without washing with water) contains fermentation inhibitors and washing with water can remove them.

  19. Cogeneration steam turbines from Siemens: New solutions

    Science.gov (United States)

    Kasilov, V. F.; Kholodkov, S. V.

    2017-03-01

    The Enhanced Platform system intended for the design and manufacture of Siemens AG turbines is presented. It combines organizational and production measures allowing the production of various types of steam-turbine units with a power of up to 250 MWel from standard components. The Enhanced Platform designs feature higher efficiency, improved reliability, better flexibility, longer overhaul intervals, and lower production costs. The design features of SST-700 and SST-900 steam turbines are outlined. The SST-700 turbine is used in backpressure steam-turbine units (STU) or as a high-pressure cylinder in a two-cylinder condensing turbine with steam reheat. The design of an SST-700 single-cylinder turbine with a casing without horizontal split featuring better flexibility of the turbine unit is presented. An SST-900 turbine can be used as a combined IP and LP cylinder (IPLPC) in steam-turbine or combined-cycle power units with steam reheat. The arrangements of a turbine unit based on a combination of SST-700 and SST-900 turbines or SST-500 and SST-800 turbines are presented. Examples of this combination include, respectively, PGU-410 combinedcycle units (CCU) with a condensing turbine and PGU-420 CCUs with a cogeneration turbine. The main equipment items of a PGU-410 CCU comprise an SGT5-4000F gas-turbine unit (GTU) and STU consisting of SST-700 and SST-900RH steam turbines. The steam-turbine section of a PGU-420 cogeneration power unit has a single-shaft turbine unit with two SST-800 turbines and one SST-500 turbine giving a power output of N el. STU = 150 MW under condensing conditions.

  20. Distributed parameter modeling and thermal analysis of a spiral water wall in a supercritical boiler

    Directory of Open Access Journals (Sweden)

    Zheng Shu

    2013-01-01

    Full Text Available In this paper, a distributed parameter model for the evaporation system of a supercritical spiral water wall boiler is developed based on a 3-D temperature field. The mathematical method is formulated for predicting the heat flux and the metal-surface temperature. The results show that the influence of the heat flux distribution is more obvious than that of the heat transfer coefficient distribution in the spiral water wall tube, and the peak of the heat transfer coefficient decreases with an increment of supercritical pressure. This distributed parameter model can be used for a 600 MW supercritical-pressure power plant.

  1. Thermal hydraulic studies in steam generator test facility

    Energy Technology Data Exchange (ETDEWEB)

    Vinod, V.; Suresh Kumar, V.A.; Noushad, I.B.; Ellappan, T.R.; Rajan, K.K.; Rajan, M.; Vaidyanathan, G. [Engineering Development Group Indira Gandhi Centre for Atomic Research, Kalpakkam-603102 (India)

    2005-07-01

    Full text of publication follows: A 500 MWe fast breeder reactor is being constructed at Kalpakkam, India. This is a sodium cooled reactor with two primary and two secondary sodium loops with total 8 steam generators. The typical advantage of fast breeder plants is the high operating temperature of steam cycles and the high plant efficiency. To produce this high pressure and high temperature steam, once through straight tube vertical sodium heated steam generators are used. The steam is generated from the heat produced in the reactor core and being transported through primary and secondary sodium circuits. The steam generator is a 25 m high middle supported steam generator with expansion bend and 23 m heat transfer length. Steam Generator Test Facility (SGTF) constructed at Indira Gandhi Centre for Atomic Research (IGCAR), Kalpakkam aims at performing various tests on a 5.5 MWt steam generator. This vertically simulated test article is similar in all respects to the proposed 157 MWt steam generator module for the Prototype Fast Breeder Reactor (PFBR), with reduced number of tubes. Heat transfer performance tests are done with this 19 tube steam generator at various load conditions. Sodium circuit for the SGTF is equipped with oil fired heater as heat source and centrifugal sodium pump, to pump sodium at 105 m{sup 3}/hr flow rate. Other typical components like sodium to air heat exchanger, sodium purification system and hydrogen leak detection system is also present in the sodium circuit. High pressure steam produced in the steam generator is dumped in a condenser and recycled. Important tests planned in SGTF are the heat transfer performance test, stability test, endurance test and performance test of steam generator under various transients. The controlled operation of steam generator will be studied with possible control schemes. A steady state simulation of the steam generator is done with a mathematical model. This paper gives the details of heat transfer

  2. Computer modeling of a convective steam superheater

    Science.gov (United States)

    Trojan, Marcin

    2015-03-01

    Superheater is for generating superheated steam from the saturated steam from the evaporator outlet. In the case of pulverized coal fired boiler, a relatively small amount of ash causes problems with ash fouling on the heating surfaces, including the superheaters. In the convection pass of the boiler, the flue gas temperature is lower and ash deposits can be loose or sintered. Ash fouling not only reduces heat transfer from the flue gas to the steam, but also is the cause of a higher pressure drop on the flue gas flow path. In the case the pressure drop is greater than the power consumed by the fan increases. If the superheater surfaces are covered with ash than the steam temperature at the outlet of the superheater stages falls, and the flow rates of the water injected into attemperator should be reduced. There is also an increase in flue gas temperature after the different stages of the superheater. Consequently, this leads to a reduction in boiler efficiency. The paper presents the results of computational fluid dynamics simulations of the first stage superheater of both the boiler OP-210M using the commercial software. The temperature distributions of the steam and flue gas along the way they flow together with temperature of the tube walls and temperature of the ash deposits will be determined. The calculated steam temperature is compared with measurement results. Knowledge of these temperatures is of great practical importance because it allows to choose the grade of steel for a given superheater stage. Using the developed model of the superheater to determine its degree of ash fouling in the on-line mode one can control the activation frequency of steam sootblowers.

  3. Computer modeling of a convective steam superheater

    Directory of Open Access Journals (Sweden)

    Trojan Marcin

    2015-03-01

    Full Text Available Superheater is for generating superheated steam from the saturated steam from the evaporator outlet. In the case of pulverized coal fired boiler, a relatively small amount of ash causes problems with ash fouling on the heating surfaces, including the superheaters. In the convection pass of the boiler, the flue gas temperature is lower and ash deposits can be loose or sintered. Ash fouling not only reduces heat transfer from the flue gas to the steam, but also is the cause of a higher pressure drop on the flue gas flow path. In the case the pressure drop is greater than the power consumed by the fan increases. If the superheater surfaces are covered with ash than the steam temperature at the outlet of the superheater stages falls, and the flow rates of the water injected into attemperator should be reduced. There is also an increase in flue gas temperature after the different stages of the superheater. Consequently, this leads to a reduction in boiler efficiency. The paper presents the results of computational fluid dynamics simulations of the first stage superheater of both the boiler OP-210M using the commercial software. The temperature distributions of the steam and flue gas along the way they flow together with temperature of the tube walls and temperature of the ash deposits will be determined. The calculated steam temperature is compared with measurement results. Knowledge of these temperatures is of great practical importance because it allows to choose the grade of steel for a given superheater stage. Using the developed model of the superheater to determine its degree of ash fouling in the on-line mode one can control the activation frequency of steam sootblowers.

  4. Boxberg - a new benchmark for high efficiency steam turbines

    Energy Technology Data Exchange (ETDEWEB)

    Hoffstadt, U.; Klauke, U.; Hinz, H. [Siemens Power Generation (Germany)

    2001-07-01

    One of the primary tasks associated with the development of modern power plant facilities is to improve the economy of operation, while at the same time reducing environmental pollution. In addition to investigations focused on supercritical steam conditions, Siemens Power generation has made enormous efforts to improve the overall efficiency by decreasing the steam flow energy losses of each steam turbine component: optimization of the admission and exhaust geometries; fully three-dimensional blading profiles; reduction of the seal-steam losses; high reliability, availability and safety of operation; optimization of the efficiency/cost-relations. As a result of these efforts the 907 MW power plant Boxberg was handed over to the customer Vereinigte Energiewerke AG recently. With a thermal gross-efficiency of 48,65% the steam turbine represents a milestone for lignite-fired cogeneration units in the history of modern turbine technology. In conjunction with the presentation of the special turbine features and its optimised fluid dynamic components, the results of assembly, commissioning and acceptance testing will be a key issue in the proposed paper. 14 overheads/slides.

  5. Use of supercritical carbon dioxide extraction

    Energy Technology Data Exchange (ETDEWEB)

    Taniguchi, Masayuki (Niigata Univ., Faculty of Engineering, Niigata, (Japan))

    1989-09-25

    Supercritical fluid extraction is a novel diffusion and separation technique which exploits simultaneously the increase of vapor pressure and the difference of chemical affinities of fluids near the critical point. A solvent which is used as the supercritical fluid has the following features: the critical point exists in the position of relatively ease of handling, the solvent is applicable to the extraction of a physiological active substance of thermal instability. Carbon dioxide as the solvent is non-flammable, non-corrosive, non-toxic, cheap, and readily available of high purity. The results of studies on the use of supercritical carbon dioxide (SC-CO{sub 2}) as a solvent for natural products in the fermentation and food industries, were collected. SC-CO{sub 2} extraction are used in many fields, examples for the application are as follows: removal of organic solvents from antibiotics; extraction of vegetable oils contained in wheat germ oil, high quality mustard seeds, rice bran and so on; brewing of sake using rice and rice-koji; use as a non-aqueous medium for the synthesis of precursors of the Aspartame; and use in sterilization. 66 refs., 17 figs., 21 tabs.

  6. An alternative chemistry for both operational and layup protection of high-pressure steam-water cycles using an organic filming amine

    Energy Technology Data Exchange (ETDEWEB)

    Verib, George J. [FirstEnergy Corp., Akron, OH (United States)

    2011-05-15

    Current economic conditions have caused many fossil-fired units to cycle load where previous operation had been a constant-load operation. At best, this operation has become a low-load, or minimum-load, operation during off electric demand periods and full-load operation during peak-load periods. At the most demanding times, the operation of these units has been a daily startup-shutdown situation. Current cycle chemistry guidelines have not minimized corrosion and have not provided protection of unit equipment during economic reserve off periods. Current unit protection strategies are limited since the units must be operationally ready if called upon to generate. The FirstEnergy Corp. has been using an alternative proprietary, organic filming amine to protect units during operation and short-term non-operational periods. This proprietary chemistry has shown the ability to successfully and significantly reduce corrosion throughout the steam-water cycle during transient load situations and during non-operational periods. (orig.)

  7. Solar steam generation: Steam by thermal concentration

    Science.gov (United States)

    Shang, Wen; Deng, Tao

    2016-09-01

    The solar-driven generation of water steam at 100 °C under one sun normally requires the use of optical concentrators to provide the necessary energy flux. Now, thermal concentration is used to raise the vapour temperature to 100 °C without the need for costly optical concentrators.

  8. Preparation of PMMA Foam by Supercritical CO2 with Ethanol

    Institute of Scientific and Technical Information of China (English)

    2001-01-01

    Supercritical CO2 with ethanol as blowing agent foamed poly(methylmethacrylate) (PMMA) fiber at 308.15K and in the pressure range from 12-15MPa. The foam structure was detected using scanning electron microscope. It was found that the concentration of ethanol in the fluid is a major parameter to affect the foam structure.

  9. Extraction of heavy oil by supercritical carbon dioxide

    DEFF Research Database (Denmark)

    Rudyk, Svetlana Nikolayevna; Spirov, Pavel; Søgaard, Erik Gydesen

    2010-01-01

    The present study deals with the extraction of heavy oil by supercritical carbon dioxide at the pressure values changing from 16 to 56 MPa at the fixed value of temperature: 60oC. The amount of the recovered liquid phase of oil was calculated as a percentage of the extracted amount to the initial...

  10. Synthesis of fatty acid starch esters in supercritical carbon dioxide

    NARCIS (Netherlands)

    Muljana, Henky; van der Knoop, Sjoerd; Keijzer, Danielle; Picchioni, Francesco; Janssen, Leon P. B. M.; Heeres, Hero J.

    2010-01-01

    This manuscript describes an exploratory study on the synthesis of fatty acid/potato starch esters using supercritical carbon dioxide (scCO(2)) as the solvent. The effects of process variables such as pressure (6-25 MPa), temperature (120-150 degrees C) and various basic catalysts and fatty acid der

  11. Supercritical flows past a square cylinder with rounded corners

    Science.gov (United States)

    Cao, Yong; Tamura, Tetsuro

    2017-08-01

    Large-eddy simulations were used to investigate the supercritical aerodynamics of a square cylinder with rounded corners in comparison with those in the subcritical regime. First, the numerical methods, especially the dynamic mixed model, were validated on the basis of their prediction of supercritical flows past a circular cylinder. Then, the supercritical flows past a rounded-corner square cylinder were simulated and systematically clarified. Strong Reynolds number (Re) effects existed in the forces and local pressures as Re increased from o(104) to o(106). Changeover of flow patterns occurred as Re increased. At the supercritical Re, the free stream overall flowed along the cross sections of the cylinder, separated from the leeward corners and generated Karman vortices behind the cylinder. This pattern resulted in a much smaller recirculation region behind the cylinder compared with the subcritical flow. At the micro level, the flow experienced laminar separation and flow reattachment near the frontal corners, followed by the spatial development of turbulent boundary layers (TBLs) on the side faces and turbulent separation near the leeward corners. The feedback by large-scale primary vortex shedding and the small-scale turbulent motions in the high-frequency region with a slope of -5/3 were detected in the TBL. Their interaction affected the spanwise correlations of wall pressure fluctuations. The TBL on the side face differed from the zero-pressure-gradient flat-plate one; it was subjected to pressure gradients varying in space and time.

  12. Precipitation of fluticasone propionate microparticles using supercritical antisolvent

    Directory of Open Access Journals (Sweden)

    A Vatanara

    2009-03-01

    Full Text Available ABSTRACT Background: The ability of supercritical fluids (SCFs, such as carbon dioxide, to dissolve and expand or extract organic solvents and as result lower their solvation power, makes it possible the use of SCFs for the precipitation of solids from organic solutions. The process could be the injection of a solution of the substrate in an organic solvent into a vessel which is swept by a supercritical fluid. The aim of this study was to ascertain the feasibility of supercritical processing to prepare different particulate forms of fluticasone propionate (FP, and to evaluate the influence of different liquid solvents and precipitation temperatures on the morphology, size and crystal habit of particles. Method: The solution of FP in organic solvents, was precipitated by supercritical carbon dioxide (SCCO2 at two pressure and temperature levels. Effects of process parameters on the physicochemical characteristics of harvested microparticles were evaluated. Results: Particle formation was observed only at the lower selected pressure, whilst at the higher pressure, no precipitation of particles was occurred due to dissolution of FP in supercritical antisolvent. The micrographs of the produced particles showed different morphologies for FP obtained from different conditions. The results of thermal analysis of the resulted particles showed that changes in the processing conditions didn't influence thermal behavior of the precipitated particles. Evaluation of the effect of temperature on the size distribution of particles showed that increase in the temperature from 40 oC to 50 oC, resulted in reduction of the mean particle size from about 30 µm to about 12 μm. ‍Conclusion: From the results of this study it may be concluded that, processing of FP by supercritical antisolvent could be an approach for production of diverse forms of the drug and drastic changes in the physical characteristics of microparticles could be achieved by changing the

  13. Destruction of energetic materials by supercritical water oxidation

    Energy Technology Data Exchange (ETDEWEB)

    Beulow, S.J.; Dyer, R.B.; Harradine, D.M.; Robinson, J.M.; Oldenborg, R.C.; Funk, K.A.; McInroy, R.E.; Sanchez, J.A.; Spontarelli, T.

    1993-10-01

    Supercritical water oxidation is a relatively low-temperature process that can give high destruction efficiencies for a variety of hazardous chemical wastes. Results are presented examining the destruction of high explosives and propellants in supercritical water and the use of low temperature, low pressure hydrolysis as a pretreatment process. Reactions of cyclotrimethylene trinitramine (RDX), cyclotetramethylene tetranitramine (HMX), nitroguanidine (NQ), pentaerythritol tetranitrate (PETN), and 2,4,6-trinitrotoluene (TNT) are examined in a flow reactor operated at temperatures between 400{degrees}C and 650{degrees}C. Explosives are introduced into the reactor at concentrations below the solubility limits. For each of the compounds, over 99.9% is destroyed in less than 30 seconds at temperatures above 600{degrees}C. The reactions produce primarily N{sub 2}, N{sub 2}O,CO{sub 2}, and some nitrate and nitrite ions. The distribution of reaction products depends on reactor pressure, temperature, and oxidizer concentration. Kinetics studies of the reactions of nitrate and nitrite ions with various reducing reagents in supercritical water show that they can be rapidly and completely destroyed at temperatures above 525{degrees}C. The use of slurries and hydrolysis to introduce high concentrations of explosives into a supercritical water reactor is examined. For some compounds the rate of reaction depends on particle size. The hydrolysis of explosives at low temperatures (<100{degrees}C) and low pressures (<1 atm) under basic conditions produces water soluble, non-explosive products which are easily destroyed by supercritical water oxidation. Large pieces of explosives (13 cm diameter) have been successfully hydrolyzed. The rate, extent, and products of the hydrolysis depend on the type and concentration of base. Results from the base hydrolysis of triple base propellant M31A1E1 and the subsequent supercritical water oxidation of the hydrolysis products are presented.

  14. Ukraine Steam Partnership

    Energy Technology Data Exchange (ETDEWEB)

    Gurvinder Singh

    2000-02-15

    The Ukraine Steam Partnership program is designed to implement energy efficiency improvements in industrial steam systems. These improvements are to be made by the private plants and local government departments responsible for generation and delivery of energy to end-users. One of the activities planned under this program was to provide a two-day training workshop on industrial steam systems focusing on energy efficiency issues related to the generation, distribution, and consumption of steam. The workshop was geared towards plant managers, who are not only technically oriented, but are also key decision makers in their respective companies. The Agency for Rational Energy Use and Ecology (ARENA-ECO), a non-governmental, not-for-profit organization founded to promote energy efficiency and environmental protection in Ukraine, in conjunction with the Alliance staff in Kiev sent out invitations to potential participants in all the regions of Ukraine. The purpose of this report is the describe the proceedings from the workshop and provide recommendations from the workshop's roundtable discussion. The workshop was broken down into two main areas: (1) Energy efficient boiler house steam generation; and Energy efficient steam distribution and consumption. The workshop also covered the following topics: (1) Ukrainian boilers; (2) Water treatment systems; (3) A profile of UKRESCO (Ukrainian Energy Services Company); (4) Turbine expanders and electricity generation; (5) Enterprise energy audit basics; and (6) Experience of steam use in Donetsk oblast.

  15. Optimization of power-cycle arrangements for Supercritical Water cooled Reactors (SCWRs)

    Science.gov (United States)

    Lizon-A-Lugrin, Laure

    The world energy demand is continuously rising due to the increase of both the world population and the standard of life quality. Further, to assure both a healthy world economy as well as adequate social standards, in a relatively short term, new energy-conversion technologies are mandatory. Within this framework, a Generation IV International Forum (GIF) was established by the participation of 10 countries to collaborate for developing nuclear power reactors that will replace the present technology by 2030. The main goals of these nuclear-power reactors are: economic competitiveness, sustainability, safety, reliability and resistance to proliferation. As a member of the GIF, Canada has decided to orient its efforts towards the design of a CANDU-type Super Critical Water-cooled Reactor (SCWR). Such a system must run at a coolant outlet temperature of about 625°C and at a pressure of 25 MPa. It is obvious that at such conditions the overall efficiency of this kind of Nuclear Power Plant (NPP) will compete with actual supercritical water-power boilers. In addition, from a heat-transfer viewpoint, the use of a supercritical fluid allows the limitation imposed by Critical Heat Flux (CHF) conditions, which characterize actual technologies, to be removed. Furthermore, it will be also possible to use direct thermodynamic cycles where the supercritical fluid expands right away in a turbine without the necessity of using intermediate steam generators and/or separators. This work presents several thermodynamic cycles that could be appropriate to run SCWR power plants. Improving both thermal efficiency and mechanical power constitutes a multi-objective optimization problem and requires specific tools. To this aim, an efficient and robust evolutionary algorithm, based on genetic algorithm, is used and coupled to an appropriate power plant thermodynamic simulation model. The results provide numerous combinations to achieve a thermal efficiency higher than 50% with a

  16. [Research of the essential oil of Plumeria rubra var. actifolia from Laos by supercritical carbon dioxide extraction].

    Science.gov (United States)

    Xiao, Xin-Yu; Cui, Long-Hai; Zhou, Xin-Xin; Wu, Yan; Ge, Fa-Huan

    2011-05-01

    The orthogonal test and the supercritical carbon dioxide fluid extraction were used for optimizing the extraction of the essential oil from Plumeria rubra var. actifolia for the first time. Compared with the steam distillation, the optimal operation parameter of extraction was as follows: extraction pressure 25 MPa, extraction temperature 45 degrees C; separator I pressure 12 MPa, separator I temperature 55 degrees C; separator II pressure 6 MPa, separator II temperature 30 degrees C. Under this condition the yield of the essential oil was 5.8927%. The components were separated and identified by GC-MS. 53 components of Plumeria rubra var. actifolia measured by SFE method were identified and determined by normalization method. The main components were 1, 6, 10-dodecatrien-3-ol, 3, 7, 11-trimethyl, benzoic acid, 2-hydroxy-, phenylmethyl ester, 1, 2-benzenedicarboxylic acid, bis(2-methylpropyl) ester,etc.. 1, 2-Benzenedicarboxylic acid, bis (2-methylpropyl) este. took up 66.11% of the total amount, and there was much difference of the results from SD method.

  17. Thermodynamic behaviour of supercritical matter.

    Science.gov (United States)

    Bolmatov, Dima; Brazhkin, V V; Trachenko, K

    2013-01-01

    Since their discovery in 1822, supercritical fluids have been of enduring interest and have started to be deployed in many important applications. Theoretical understanding of the supercritical state is lacking and is seen to limit further industrial deployment. Here we study thermodynamic properties of the supercritical state and discover that specific heat shows a crossover between two different regimes, an unexpected result in view of currently perceived homogeneity of supercritical state in terms of physical properties. We subsequently formulate a theory of system thermodynamics above the crossover, and find good agreement between calculated and experimental specific heat with no free-fitting parameters. In this theory, energy and heat capacity are governed by the minimal length of the longitudinal mode in the system only, and do not explicitly depend on system-specific structure and interactions. We derive a power law and analyse supercritical scaling exponents in the system above the Frenkel line.

  18. Characterization of steam generated anti-corrosive oxide films on Aluminium alloys

    DEFF Research Database (Denmark)

    Din, Rameez Ud; Jellesen, Morten Stendahl; Ambat, Rajan

    2014-01-01

    alloy surfaces were exposed to high pressure steam produced by an autoclave at a temperature of 107 – 121 °C and pressure of 15 -17 psi for 10 minutes to produce a thin coating of aluminium oxide. The aim of this study is to understand the effect of high pressure steam with and without different...

  19. Industrial applications and current trends in supercritical fluid technologies

    Directory of Open Access Journals (Sweden)

    Gamse Thomas

    2005-01-01

    Full Text Available Supercritical fluids have a great potential for wide fields of processes Although CO2 is still one of the most used supercritical gases, for special purposes propane or even fluorinated-chlorinated fluids have also been tested. The specific characteristics of supercritical fluids behaviour were analyzed such as for example the solubilities of different components and the phase equilibria between the solute and solvent. The application at industrial scale (decaffeinating of tea and coffee, hop extraction or removal of pesticides from rice, activity in supercritical extraction producing total extract from the raw material or different fractions by using the fractionated separation of beverages (rum, cognac, whisky, wine, beer cider, of citrus oils and of lipids (fish oils, tall oil were also discussed. The main interest is still for the extraction of natural raw materials producing food ingredients, nutraceuticals and phytopharmaceuticals but also cleaning purposes were tested such as the decontamination of soils the removal of residual solvents from pharmaceutical products, the extraction of flame retardants from electronic waste or precision degreasing and cleaning of mechanical and electronic parts. An increasing interest obviously exists for impregnation purposes based on supercritical fluids behaviour, as well as for the dying of fibres and textiles. The production of fine particles in the micron and submicron range, mainly for pharmaceutical products is another important application of supercritical fluids. Completely new products can be produced which is not possible under normal conditions. Supercritical fluid technology has always had to compete with the widespread opinion that these processes are very expensive due to very high investment costs in comparison with classical low-pressure equipment. Thus the opinion is that these processes should be restricted to high-added value products. A cost estimation for different plant sizes and

  20. Supercritical fluid (SCF) technologies: Assessment of applicability to installation restoration processes

    Science.gov (United States)

    1994-03-01

    USAEC has conducted an evaluation of supercritical fluid (SCF) technologies for their applicability to treatment of explosives, chlorinated hydrocarbons, and metals in soils, water, and/or waste sludge media. Off-specification explosives and propellants that have traditionally been open burned or openly detonated were also examined. Supercritical fluids are substances which have been heated and compressed to above their critical temperatures and pressures and which possess unique transport and mass transfer properties. Supercritical fluid extraction (SFE) uses the solvating properties of supercritical fluids to extract one or more organic components from a mixture into a supercritical solvent (commonly CO2). The concentrated extract stream may then be recycled, reclaimed, or destroyed by other methods.

  1. Solubilities of triolein in supercritical CO{sub 2}

    Energy Technology Data Exchange (ETDEWEB)

    Ribeiro, M.A.; Bernardo-Gil, M.G. [Instituto Superior Tecnico, Lisboa (Portugal). Dept. de Engenharia Quimica

    1995-11-01

    A vegetable oil typically consists of a range of triglycerides, approximately 10% diglycerides, and a small fraction of free fatty acids and other minor constituents. The use of supercritical carbon dioxide for solvent extraction is currently the subject of numerous investigations. The solubilities of triolein in supercritical carbon dioxide were measured over a temperature range of 308--328 K and at pressures between 8 and 20 MPa by the static method. The data were correlated by the model proposed by Chrastil and the modification proposed by Adachi and Lu and Del Valle and Aguilera.

  2. Hydraulic drag at the condensing steam flow in tubes

    Science.gov (United States)

    Leontiev, A. I.; Milman, O. O.

    2014-12-01

    The dependency of condensing steam flow parameters in tubes and channels was studied as a function of different flow modes for the coolant: counter-flow, co-flow, cross-flow. The drop for the total pressure of steam is higher for the counter-flow than for the co-flow or cross-flow modes. The pressure drop was estimated with different computation models as a function flow mode. Calculation results were compared with experimental data.

  3. Methane Steam Reforming Kinetics for a Rhodium-Based Catalyst

    DEFF Research Database (Denmark)

    Jakobsen, Jon Geest; Jakobsen, M.; Chorkendorff, Ib

    2010-01-01

    Methane steam reforming is the key reaction to produce synthesis gas and hydrogen at the industrial scale. Here the kinetics of methane steam reforming over a rhodium-based catalyst is investigated in the temperature range 500-800 A degrees C and as a function of CH4, H2O and H-2 partial pressures....... The methane steam reforming reaction cannot be modeled without taking CO and H coverages into account. This is especially important at low temperatures and higher partial pressures of CO and H-2. For methane CO2 reforming experiments, it is also necessary to consider the repulsive interaction of CO...

  4. Preliminary Development of Thermal Power Calculation Code H-Power for a Supercritical Water Reactor

    Directory of Open Access Journals (Sweden)

    Fan Zhang

    2014-01-01

    Full Text Available SCWR (Supercritical Water Reactor is one of the promising Generation IV nuclear systems, which has higher thermal power efficiency than current pressurized water reactor. It is necessary to perform the thermal equilibrium and thermal power calculation for the conceptual design and further monitoring and calibration of the SCWR. One visual software named H-Power was developed to calculate thermal power and its uncertainty of SCWR, in which the advanced IAPWS-IF97 industrial formulation was used to calculate the thermodynamic properties of water and steam. The ISO-5167-4: 2003 standard was incorporated in the code as the basis of orifice plate to compute the flow rate. New heat balance model and uncertainty estimate have also been included in the code. In order to validate H-Power, an assessment was carried out by using data published by US and Qinshan Phase II. The results showed that H-Power was able to estimate the thermal power of SCWR.

  5. Temperature Control via Affine Nonlinear Systems for Intermediate Point of Supercritical Once-Through Boiler Units

    OpenAIRE

    Hong Zhou; Changkun Liu; Zhi-Wei Liu; Wenshan Hu

    2014-01-01

    For the operation of the supercritical once-through boiler generation units, the control of the temperature at intermediate point (IPT) is highly significant. IPT is the steam temperature at the outlet of the separator. Currently, PID control algorithms are widely adopted for the IPT control. However, PID cannot achieve the optimal performances as the units’ dynamic characteristic changes at different working points due to the severe nonlinearity. To address the problem, a new control algorit...

  6. Laboratory investigations of the physics of steam flow in a porous medium

    Science.gov (United States)

    Herkelrath, W.N.; Moench, A.F.

    1982-01-01

    Experiments were carried out in the laboratory to test a theory of transient flow of pure steam in a uniform porous medium. This theory is used extensively in modeling pressure-transient behavior in vapor-dominated geothermal systems. Transient, superheated steam-flow experiments were run by bringing a cylinder of porous material to a uniform initial pressure, and then making a step increase in pressure at one end of the sample, while monitoring the pressure-transient breakthrough at the other end. It was found in experiments run at 100?, 125?, and 146?C that the time required for steam-pressure transients to propagate through an unconsolidated material containing sand, silt, and clay was 10 to 25 times longer than predicted by theory. It is hypothesized that the delay in the steam-pressure transient was caused by adsorption of steam in the porous sample. In order to account for steam adsorption, a sink term was included in the conservation of mass equation. In addition, energy transfer in the system has to be considered because latent heat is released when steam adsorption occurs, increasing the sample temperature by as much as 10?C. Finally, it was recognized that the steam pressure was a function of both the temperature and the amount of adsorption in the sample. For simplicity, this function was assumed to be in equilibrium adsorption isotherm, which was determined by experiment. By solving the modified mass and energy equations numerically, subject to the empirical adsorption isotherm relationship, excellent theoretical simulation of the experiments was achieved. The experiments support the hypothesis that adsorption of steam can strongly influence steam pressure-transient behavior in porous media; the results suggest that the modified steam-flow theory, which includes steam adsorption terms, should be used in modeling steam flow in vapor-dominated geothermal systems.

  7. Development of an Experimental Data Base and Theories for Prediction of Thermodynamic Properties of Aqueous Electrolytes and Nonelectrolytes of Geochemical Significance at Supercritical Temperatures and Pressures.

    Energy Technology Data Exchange (ETDEWEB)

    Wood, Robert H.

    2005-10-11

    The objective of this research was to combine new experimental measurements on heat capacities, volumes, and association constants of key compounds with theoretical equations of state and with first principles quantum mechanical calculations to generate predictions of thermodynamic data. The resulting thermodynamic data allow quantitative models of geochemical processes at high temperatures and pressures. Research funded by a DOE grant to Prof. Robert Wood at the University of Delaware involved the development of new theoretical equations of state for aqueous solutions of electrolytes and non-electrolytes, methods to estimate thermodynamic data not available from experiments, collection of data on model compounds through experiments and predictions of properties using ab initio quantum mechanics. During the last three and a half years, with support from our DOE grant, 16 papers have been accepted or published, and 3 more are in preparation. Results of this research have been reported in numerous invited and contributed presentations at national and international meetings. For this report, we will briefly comment on the highlights of the last 3 and a half years and give a complete list of papers published, accepted, or submitted during these years.

  8. Biodiesel fuel from rapeseed oil as prepared in supercritical methanol

    Energy Technology Data Exchange (ETDEWEB)

    Saka, S.; Kusdiana, D. [Kyoto University, Kyoto (Japan). Dept. of Socio-Environmental Energy Science, Graduate School of Energy Science

    2001-01-01

    Transesterification reaction of rapeseed oil in supercritical methanol was investigated without using any catalyst. An experiment has been carried out in the batch-type reaction vessel preheated at 350 and 400{degree}C and at a pressure of 45-65 MPa, and with a molar ratio of 1:42 of the rapeseed oil to methanol. It was consequently demonstrated that, in a preheating temperature of 350{degree}C, 240 s of supercritical treatment of methanol was sufficient to convert the rapeseed oil to methyl esters and that, although the prepared methyl esters were basically the same as those of the common method with a basic catalyst, the yield of methyl esters by the former was found to be higher than that by the latter. In addition, it was found that this supercritical methanol process requires the shorter reaction time and simpler purification procedure because of the unused catalyst. 16 refs., 9 figs., 2 tabs.

  9. Preparation of drug delivery systems using supercritical fluid technology.

    Science.gov (United States)

    Kompella, U B; Koushik, K

    2001-01-01

    Small changes in temperature and pressure near the critical region induce dramatic changes in the density and solubility of supercritical fluids, thereby facilitating the use of environmentally benign agents such as CO2 for their solvent and antisolvent properties in processing a wide variety of materials. While supercritical fluid technologies have been in commercial use in the food and chromatography industries for several years, only recently has this technology made inroads in the formulation of drug delivery systems. This review summarizes some of the recent applications of supercritical fluid technology in the preparation of drug delivery systems. Drugs containing polymeric particles, plain drug particles, solute-containing liposomes, and inclusion complexes of drug and carrier have been formulated using this technology. Also, polymer separation using this technology is enabling the selection of a pure fraction of a polymer, thereby allowing a more precise control of drug release from polymeric delivery systems.

  10. Application of Neutron Radiography to Flow Visualization in Supercritical Water

    Science.gov (United States)

    Takenaka, N.; Sugimoto, K.; Takami, S.; Sugioka, K.; Tsukada, T.; Adschiri, T.; Saito, Y.

    Supercritical water is used in various chemical reaction processes including hydrothermal synthesis of metal oxide nano-particles, oxidation, chemical conversion of biomass and plastics. Density of the super critical water is much less than that of the sub-critical water. By using neutron radiography, Peterson et al. have studied salt precipitation processes in supercritical water and the flow pattern in a reverse-flow vessel for salt precipitation, and Balasko et al. have revealed the behaviour of supercritical water in a container. The nano-particles were made by mixing the super critical flow and the sub critical water solution. In the present study, neutron radiography was applied to the flow visualization of the super and sub critical water mixture in a T-junction made of stainless steel pipes for high pressure and temperature conditions to investigate their mixing process. Still images by a CCD camera were obtained by using the neutron radiography system at B4 port in KUR.

  11. Application of supercritical antisolvent method in drug encapsulation: a review

    Directory of Open Access Journals (Sweden)

    Kalani M

    2011-07-01

    Full Text Available Mahshid Kalani, Robiah YunusChemical and Environmental Engineering, Faculty of Engineering, University Putra Malaysia, Selangor Darul Ehsan, MalaysiaAbstract: The review focuses on the application of supercritical fluids as antisolvents in the pharmaceutical field and demonstrates the supercritical antisolvent method in the use of drug encapsulation. The main factors for choosing the solvent and biodegradable polymer to produce fine particles to ensure effective drug delivery are emphasized and the effect of polymer structure on drug encapsulation is illustrated. The review also demonstrates the drug release mechanism and polymeric controlled release system, and discusses the effects of the various conditions in the process, such as pressure, temperature, concentration, chemical compositions (organic solvents, drug, and biodegradable polymer, nozzle geometry, CO2 flow rate, and the liquid phase flow rate on particle size and its distribution.Keywords: supercritical antisolvent method, drug encapsulation, particle size, drug release mechanisms, drug delivery

  12. Molecular Dynamics Investigation of Benzene in Supercritical Water

    Institute of Scientific and Technical Information of China (English)

    2001-01-01

    Microscopic structure and diffusion properties of benzene in ambient water (298 K, 0.1 MPa) and super critical water (673-773 K, 25-35 MPa) are investigated by molecular dynamics simulation with site-site models. It is found that at the ambient condition, the water molecules surrounding a benzene molecule form a hydrogen bond network. The hydrogen bond interaction between supercritical water molecules decreases dramatically under supercritical conditions. The diffusion coefficients of both the solute molecule and solvent molecule at supercritical conditions increase by 30-180 times than those at the ambient condition. With the temperature approaching the critical temperature, the change of diffusion coefficient with pressure becomes pronounced.

  13. Experimental research of heterogeneous nuclei in superheated steam

    Directory of Open Access Journals (Sweden)

    Bartoš Ondřej

    2016-01-01

    Full Text Available A mobile steam expansion chamber has been developed to investigate experimentally homogeneous and heterogeneous nucleation processes in steam, both in the laboratory and at power plants using the steam withdrawn from the steam turbine. The purpose of the device is to provide new insight into the physics of nonequilibrium wet steam formation, which is one of the factors limiting the efficiency and reliability of steam turbines. The expanded steam or a mixture of steam with a non-condensable gas rapidly expands in the expansion chamber. Due to adiabatic cooling, the temperature drops below the dew point of the steam at a given pressure. When reaching a sufficiently high supersaturation, droplets are nucleated. By tuning the supersaturation in the so-called nucleation pulse, particles of various size ranges can be activated. This fact is used in the present study to measure the aerosol particles present in the air. Homogeneous nucleation was negligible in this case. The experiment demonstrates the functionality of the device, data acquisition system and data evaluation methods.

  14. Experimental research of heterogeneous nuclei in superheated steam

    Science.gov (United States)

    Bartoš, Ondřej; Kolovratník, Michal; Šmíd, Bohuslav; Hrubý, Jan

    2016-03-01

    A mobile steam expansion chamber has been developed to investigate experimentally homogeneous and heterogeneous nucleation processes in steam, both in the laboratory and at power plants using the steam withdrawn from the steam turbine. The purpose of the device is to provide new insight into the physics of nonequilibrium wet steam formation, which is one of the factors limiting the efficiency and reliability of steam turbines. The expanded steam or a mixture of steam with a non-condensable gas rapidly expands in the expansion chamber. Due to adiabatic cooling, the temperature drops below the dew point of the steam at a given pressure. When reaching a sufficiently high supersaturation, droplets are nucleated. By tuning the supersaturation in the so-called nucleation pulse, particles of various size ranges can be activated. This fact is used in the present study to measure the aerosol particles present in the air. Homogeneous nucleation was negligible in this case. The experiment demonstrates the functionality of the device, data acquisition system and data evaluation methods.

  15. Optimal operations and resilient investments in steam networks

    Directory of Open Access Journals (Sweden)

    Stephane Laurent Bungener

    2016-01-01

    Full Text Available Steam is a key energy vector for industrial sites, most commonly used for process heating and cooling, cogeneration of heat and mechanical power, as a motive fluid or for stripping. Steam networks are used to carry steam from producers to consumers and between pressure levels through letdowns and steam turbines. The steam producers (boilers, heat and power cogeneration units, heat exchangers, chemical reactors should be sized to supply the consumers at nominal operating conditions as well as peak demand.This paper firstly proposes an Mixed Integer Linear Programming formulation to optimise the operations of steam networks in normal operating conditions and exceptional demand (when operating reserves fall to zero, through the introduction of load shedding. Optimisation of investments based on operational and investment costs are included in the formulation.Though rare, boiler failures can have a heavy impact of steam network operations and costs, leading to undercapacity and unit shutdowns. A method is therefore proposed to simulate steam network operations when facing boiler failures. Key performance indicators are introduced to quantify the network's resilience.The proposed methods are applied and demonstrated in an industrial case study using industrial data. The results indicate the importance of oversizing key steam producing equipments and the value of industrial symbiosis to increase industrial site resilience.

  16. Improvement of dissolution property of poorly water-soluble drug by supercritical freeze granulation.

    Science.gov (United States)

    Sonoda, Ryoichi; Hara, Yuko; Iwasaki, Tomohiro; Watano, Satoru

    2009-10-01

    The dissolution property of the poorly water-soluble drug, flurbiprofen (FP) was improved by a novel supercritical freeze granulation using supercritical carbon dioxide. Supercritical freeze granulation was defined as a production method of the granulated substances by using the dry ice to generate intentionally for the rapid atomization of the supercritical carbon dioxide to the atmospheric pressure. This process utilized a rapid expansion of supercritical solutions (RESS) process with the mixture of the drug and lactose. In the supercritical freeze granulation, needle-like FP fine particles were obtained which adhered to the surface of lactose particles, which did not dissolve in supercritical carbon dioxide. The number of FP particles that adhered to the surface of particles decreased with an increase in the ratio of lactose added, leading to markedly improve the dissolution rate. This improvement was caused not only by the increase in the specific surface area but also the improvement of the dispersibility of FP in water. It is thus concluded that the supercritical freeze granulation is a useful technique to improve the dissolution property of the poorly water-soluble flurbiprofen.

  17. Toward Better Modeling of Supercritical Turbulent Mixing

    Science.gov (United States)

    Selle, Laurent; Okongo'o, Nora; Bellan, Josette; Harstad, Kenneth

    2008-01-01

    study was done as part of an effort to develop computational models representing turbulent mixing under thermodynamic supercritical (here, high pressure) conditions. The question was whether the large-eddy simulation (LES) approach, developed previously for atmospheric-pressure compressible-perfect-gas and incompressible flows, can be extended to real-gas non-ideal (including supercritical) fluid mixtures. [In LES, the governing equations are approximated such that the flow field is spatially filtered and subgrid-scale (SGS) phenomena are represented by models.] The study included analyses of results from direct numerical simulation (DNS) of several such mixing layers based on the Navier-Stokes, total-energy, and conservation- of-chemical-species governing equations. Comparison of LES and DNS results revealed the need to augment the atmospheric- pressure LES equations with additional SGS momentum and energy terms. These new terms are the direct result of high-density-gradient-magnitude regions found in the DNS and observed experimentally under fully turbulent flow conditions. A model has been derived for the new term in the momentum equation and was found to perform well at small filter size but to deteriorate with increasing filter size. Several alternative models were derived for the new SGS term in the energy equation that would need further investigations to determine if they are too computationally intensive in LES.

  18. Supercritical Fluid Extraction of Palm Carotenoids

    Directory of Open Access Journals (Sweden)

    Puah C. Wei

    2005-01-01

    Full Text Available The extraction of carotenoids from crude palm oil was carried out in a dynamic (flow- through supercritical fluid extraction system. The carotenoids obtained were quantified using off-line UV-visible spectrophotometry. The effects of operating pressure and temperature, flow rate of the supercritical carbon dioxide (SC-CO2, sample size of feed used on the solubility of palm carotenoids were investigated. The results showed that the extraction of carotenoids was governed by its solubility in the SC-CO2 and can be enhanced by increasing pressure at a constant temperature or decreasing temperature at a constant pressure. Increasing the flow rate and decreasing the sample size can reduce the extraction time but do not enhance the solubility. Palm carotenoids have very low solubility in SC-CO2 in the range of 1.31 x 10-4 g kg-1 to 1.58 x 10-3 g kg-1 for the conditions investigated in this study. The experimental data obtained were compared with those published by other workers and correlated by a density-based equation as proposed by Chrastil.

  19. A Numerical Study on the Supersonic Steam Ejector Use in Steam Turbine System

    Directory of Open Access Journals (Sweden)

    Lin Cai

    2013-01-01

    Full Text Available Supersonic steam ejector is widely used in steam energy systems such as refrigeration, wood drying equipment, papermaking machine, and steam turbine. In this paper the Computational Fluids Dynamics (CFD method was employed to simulate a supersonic steam ejector, SST k-w turbulence model was adopted, and both real gas model and ideal gas model for fluid property were considered and compared. The mixing chamber angle, throat length, and nozzle exit position (NXP primary pressure and temperature effects on entrainment ratio were investigated. The results show that performance of the ejector is underestimated using ideal gas model, and the entrainment ratio is 20%–40% lower than that when using real gas model. There is an optimum mixing chamber angel and NXP makes the entrainment ratio achieve its maximum; as throat length is decreased within a range, the entrainment ratio remains unchanged. Primary fluid pressure has a critical value, and the entrainment ratio reaches its peak at working critical pressure; when working steam superheat degree increases, the entrainment ratio is increased.

  20. Surfactant/Supercritical Fluid Cleaning of Contaminated Substrates

    Science.gov (United States)

    White, Gary L.

    1997-01-01

    CFC's and halogenated hydrocarbon solvents have been the solvents of choice to degrease and otherwise clean precision metal parts to allow proper function. Recent regulations have, however, rendered most of these solvents unacceptable for these purposes. New processes which are being used or which have been proposed to replace these solvents usually either fail to remove water soluble contaminants or produce significant aqueous wastes which must then be disposed of. In this work, a new method for cleaning surfaces will be investigated. Solubility of typical contaminants such as lubricating greases and phosphatizing bath residues will be studied in several surfactant/supercritical fluid solutions. The effect of temperature, pressure, and the composition of the cleaning mixture on the solubility of oily, polar, and ionic contaminants will be investigated. A reverse micellar solution in a supercritical light hydrocarbon solvent will be used to clean samples of industrial wastes. A reverse micellar solution is one where water is dissolved into a non-polar solvent with the aid of a surfactant. The solution will be capable of dissolving both water-soluble contaminants and oil soluble contaminants. Once the contaminants have been dissolved into the solution they will be separated from the light hydrocarbon and precipitated by a relatively small pressure drop and the supercritical solvent will be available for recycle for reuse. The process will be compared to the efficacy of supercritical CO2 cleaning by attempting to clean the same types of substrates and machining wastes with the same contaminants using supercritical CO2. It is anticipated that the supercritical CO2 process will not be capable of removing ionic residues.

  1. Supercritical Extraction of Lycopene from Tomato Industrial Wastes with Ethane

    Directory of Open Access Journals (Sweden)

    Rui L. Mendes

    2012-07-01

    Full Text Available Supercritical fluid extraction of all-E-lycopene from tomato industrial wastes (mixture of skins and seeds was carried out in a semi-continuous flow apparatus using ethane as supercritical solvent. The effect of pressure, temperature, feed particle size, solvent superficial velocity and matrix initial composition was evaluated. Moreover, the yield of the extraction was compared with that obtained with other supercritical solvents (supercritical CO2 and a near critical mixture of ethane and propane. The recovery of all-E-lycopene increased with pressure, decreased with the increase of the particle size in the initial stages of the extraction and was not practically affected by the solvent superficial velocity. The effect of the temperature was more complex. When the temperature increased from 40 to 60 °C the recovery of all-E-lycopene increased from 80 to 90%. However, for a further increase to 80 °C, the recovery remained almost the same, indicating that some E-Z isomerization could have occurred, as well as some degradation of lycopene. The recovery of all-E-lycopene was almost the same for feed samples with different all-E-lycopene content. Furthermore, when a batch with a higher all-E-lycopene content was used, supercritical ethane and a near critical mixture of ethane and propane showed to be better solvents than supercritical CO2 leading to a faster extraction with a higher recovery of the carotenoid.

  2. New ferritic steels for advanced steam plants

    Energy Technology Data Exchange (ETDEWEB)

    Mayer, K.H; Koenig, H. [GEC ALSTHOM Energie GmbH, Nuremberg (Germany)

    1998-12-31

    During the last 15-20 years ferritic-martensitic 9-12 % chromium steels have been developed under international research programmes which permit inlet steam temperatures up to approx. 625 deg C and pressures up to about 300 bars, thus leading to improvements in thermal efficiency of around 8 % and a CO{sub 2} reduction of about 20 % versus conventional steam parameters. These new steels are already being applied in 13 European and 34 Japanese power stations with inlet steam temperature up to 610 deg C. This presentation will give an account of the content, scope and results of the research programmes and of the experience gained during the production of components which have been manufactured from the new steels. (orig.) 13 refs.

  3. Theoretical Model and Output Decouple Regulation of Lifting Pressure Steam-water Injector%升压汽水喷射器的理论模型及输出量的解耦控制

    Institute of Scientific and Technical Information of China (English)

    黄云鸿; 李刚

    2011-01-01

    Taking into account the process and mechanism of lifting pressure were complex due to the condensation and shock wave, a theoretical model based on direct contact condensation is presented, and some key issues, such as inter-phase mass transfer computed by the average condensation heat transfer coefficient and phase volume fraction determined by steam plume, are discussed in detail. The regulations of discharge mass flow and output temperature are decoupling control according to the theory model, and the inlet water mass flow is to determine the output temperature, the variable throat section of steam nozzle is to determine the discharge mass flow. The regulation of output pressure is just to change backpressure, and the regulation does not affect the input states according to the relevant experiments.%针对汽水喷射器内所产生的凝结和激波现象,使其升压过程和机理非常复杂,提出利用直接接触凝结理论建立升压汽水喷射器的理论模型,并对求解该模型的一些关键问题进行论述,如采用平均凝结换热系数计算相间质量传递及利用汽羽确定各相体积分数等.根据该理论模型给出升压式汽水喷射器出口温度和流量的调节方案,理论分析表明出口温度及流量的调节是解耦的,调节进水的质量流量可控制出口温度;调节蒸汽喷嘴的喉部截面大小可控制出口质量流量.结合相关的实验结果表明输出压力具有定量特性,只须调节出口背压即可以实现对输出压力的调节且不影响进口状态.

  4. 2 232 case reports of pressure steam sterilization for orthopedic surgical instruments%运用压力蒸汽灭菌法灭菌骨科手术器械2232例报道

    Institute of Scientific and Technical Information of China (English)

    周玉英

    2014-01-01

    目的:运用压力蒸汽灭菌法灭菌,确保骨科手术器械灭菌质量,加强医院供应室灭菌质量管理,预防医院感染的发生。方法:采用回顾性分析方法对2232件骨科手术器械进行物理、化学、生物监测,严格控制发放标准。结果:2232件骨科手术器械,经物理监测、化学监测、快速生物监测均合格,但2件出现棉包布有破洞,2件出现无纺布高温炼成破洞,5件出现湿包,3件出现清洗质量不合格。结论:骨科手术器械大多为植入物,系为高度危险性物品,必须严格把握灭菌质量,细化过程管理,保证患者安全。%Objective:To use pressure steam sterilization in order to ensure the quality of orthopedic surgical instruments steri-lization, strengthen quality management of hospital supply room sterilization and prevent the occurrence of hospital infections. Meth-ods:2232 pieces of orthopedic surgical instruments were monitored physically, chemically and biologically by applying pressure steam sterilization, and the provision standard was controlled strictly. Results: 2232 pieces of orthopedic surgical instruments were qualified through the physical, chemical and rapid biological monitoring, however, the cotton cloth of 2 pieces had holes, non-woven fabric of 2 pieces had be heated into holes, 5 pieces had wet bags, and the cleaning quality of 3 pieces was not qualified. Conclusions: Most or-thopedic surgical instruments are implantable, as well as highly dangerous goods. Therefore, it must strictly grasp the quality of sterili-zation and refine process management so as to ensure the safety of patients.

  5. Condensation heat transfer of pure steam and steam from gas-steam mixture in tubes of AES-2006 PHRS SG heat exchanger

    Science.gov (United States)

    Balunov, B. F.; Il'in, V. A.; Shcheglov, A. A.; Lychakov, V. D.; Alekseev, S. B.; Kuhtevich, V. O.; Svetlov, S. V.; Sidorov, V. G.

    2017-01-01

    Results of experimental determination of the average heat transfer coefficient upon condensation of pure steam αc and steam from air-steam mixture αas.m in tubes of a large-scale model of the emergency cooling heat exchanger in the system of passive heat removal through steam generators of AES-2006 project at Leningrad II NPP are presented. The model contained 16 parallel tubes with a diameter of 16 × 2 mm and a length of 2.9 m connected to the upper steam distributing and lower condensate gathering horizontal collectors; the distance between their axes was 2.28 m. The tube segments were vertical, horizontal, or inclined. The internal diameter of the collectors was 40 or 60 mm. The model was placed in the lower part of a tank with a height of 6.5 m and a volume of 5.85 m3 filled with boiling water at atmospheric pressure. The experimental parameters were as follows: pressure range 0.43-7.77 MPa, condensate Reynolds number Ref = (0.87-9.3) × 103, and average air volume fraction at the segment with air-steam mixture 0.18-0.85. The studies showed that nonuniformity of static pressure distribution along the steam-distributing collector strongly influences the reduction of αc value (ejecting effect). The agreement between experimental and calculated according to statutory guidelines values of αc for vertical tubes is achieved if the dynamic head of the steam flow at the input of the steam-distributing collector does not exceed 1 kPa. Equations for calculation of the diffusion heat transfer coefficient at steam condensation from the air-steam mixture αas.m on the internal tube surface are proposed. In the considered conditions, air is completely displaced by steam flow from the upper to the lower part of the tubes. The boundary between these regions is characterized by an average reduced steam velocity through this cross section of 1.6 ± 0.4 m/s. Above the boundary cross section, it is recommended to calculate αc. according to [1].

  6. Materials for advanced ultrasupercritical steam turbines

    Energy Technology Data Exchange (ETDEWEB)

    Purgert, Robert [Energy Industries Of Ohio Inc., Independence, OH (United States); Shingledecker, John [Energy Industries Of Ohio Inc., Independence, OH (United States); Saha, Deepak [Energy Industries Of Ohio Inc., Independence, OH (United States); Thangirala, Mani [Energy Industries Of Ohio Inc., Independence, OH (United States); Booras, George [Energy Industries Of Ohio Inc., Independence, OH (United States); Powers, John [Energy Industries Of Ohio Inc., Independence, OH (United States); Riley, Colin [Energy Industries Of Ohio Inc., Independence, OH (United States); Hendrix, Howard [Energy Industries Of Ohio Inc., Independence, OH (United States)

    2015-12-01

    The U.S. Department of Energy (DOE) and the Ohio Coal Development Office (OCDO) have sponsored a project aimed at identifying, evaluating, and qualifying the materials needed for the construction of the critical components of coal-fired power plants capable of operating at much higher efficiencies than the current generation of supercritical plants. This increased efficiency is expected to be achieved principally through the use of advanced ultrasupercritical (A-USC) steam conditions. A limiting factor in this can be the materials of construction for boilers and for steam turbines. The overall project goal is to assess/develop materials technology that will enable achieving turbine throttle steam conditions of 760°C (1400°F)/35MPa (5000 psi). This final technical report covers the research completed by the General Electric Company (GE) and Electric Power Research Institute (EPRI), with support from Oak Ridge National Laboratory (ORNL) and the National Energy Technology Laboratory (NETL) – Albany Research Center, to develop the A-USC steam turbine materials technology to meet the overall project goals. Specifically, this report summarizes the industrial scale-up and materials property database development for non-welded rotors (disc forgings), buckets (blades), bolting, castings (needed for casing and valve bodies), casting weld repair, and casting to pipe welding. Additionally, the report provides an engineering and economic assessment of an A-USC power plant without and with partial carbon capture and storage. This research project successfully demonstrated the materials technology at a sufficient scale and with corresponding materials property data to enable the design of an A-USC steam turbine. The key accomplishments included the development of a triple-melt and forged Haynes 282 disc for bolted rotor construction, long-term property development for Nimonic 105 for blading and bolting, successful scale-up of Haynes 282 and Nimonic 263 castings using

  7. Supercritical waste oxidation pump investigation

    Energy Technology Data Exchange (ETDEWEB)

    Thurston, G.; Garcia, K.

    1993-02-01

    This report investigates the pumping techniques and pumping equipment that would be appropriate for a 5,000 gallon per day supercritical water oxidation waste disposal facility. The pumps must boost water, waste, and additives from atmospheric pressure to approximately 27.6 MPa (4,000 psia). The required flow ranges from 10 gpm to less than 0.1 gpm. For the higher flows, many commercial piston pumps are available. These pumps have packing and check-valves that will require periodic maintenance; probably at 2 to 6 month intervals. Several commercial diaphragm pumps were also discovered that could pump the higher flow rates. Diaphragm pumps have the advantage of not requiring dynamic seals. For the lower flows associated with the waste and additive materials, commercial diaphragm pumps. are available. Difficult to pump materials that are sticky, radioactive, or contain solids, could be injected with an accumulator using an inert gas as the driving mechanism. The information presented in this report serves as a spring board for trade studies and the development of equipment specifications.

  8. Supercritical Water Oxidation Data Acquisition Testing

    Energy Technology Data Exchange (ETDEWEB)

    K. M. Garcia

    1996-08-01

    Supercritical Water Oxidation (SCWO) is a high pressure oxidation process that blends air, water, and organic waste material in an oxidizer in which where the temperature and pressure in the oxidizer are maintained above the critical point of water. Supercritical water mixed with hydrocarbons, which would be insoluble at subcritical conditions, forms a homogeneous phase which possesses properties associated with both a gas and a liquid. Hydrocarbons in contact with oxygen and SCW are readily oxidized. These properties of SCW make it an attractive means for the destruction of waste streams containing organic materials. SCWO technology holds great promise for treating mixed wastes in an environmentally safe and efficient manner. In the spring of 1994 the U.S. Department of Energy (DOE) initiated a Supercritical Water Oxidation Data Acquisition Testing (SCWODAT) program. The SCWODAT program provided further information and operational data on the effectiveness of treating both simulated mixed waste and typical Navy hazardous waste using the SCWO technology. The program concentrated on the acquisition of data through pilot plant testing. The Phase I DOE testing used a simulated waste stream that contained a complex machine cutting oil and metals, that acted as surrogates for radionuclides. The Phase II Navy testing included pilot testing using hazardous waste materials to demonstrate the effectiveness of the SCWO technology. The SCWODAT program demonstrated that the SCWO process oxidized the simulated waste stream containing complex machine cutting oil, selected by DOE as representative of one of the most difficult of the organic waste streams for which SCWO had been applied. The simulated waste stream with surrogate metals in solution was oxidized, with a high destruction efficiency, on the order of 99.97%, in both the neutralized and unneutralized modes of operation.

  9. Losses estimation in transonic wet steam flow through linear blade cascade

    Science.gov (United States)

    Dykas, Sławomir; Majkut, Mirosław; Strozik, Michał; Smołka, Krystian

    2015-04-01

    Experimental investigations of non-equilibrium spontaneous condensation in transonic steam flow were carried out in linear blade cascade. The linear cascade consists of the stator blades of the last stage of low pressure steam turbine. The applied experimental test section is a part of a small scale steam power plant located at Silesian University of Technology in Gliwice. The steam parameters at the test section inlet correspond to the real conditions in low pressure part of 200MWe steam turbine. The losses in the cascade were estimated using measured static pressure and temperature behind the cascade and the total parameters at inlet. The static pressure measurements on the blade surface as well as the Schlieren pictures were used to assess the flow field in linear cascade of steam turbine stator blades.

  10. Calculation of partial molar volume of components in supercritical ammonia synthesis system

    Institute of Scientific and Technical Information of China (English)

    Cunwen WANG; Chuanbo YU; Wen CHEN; Weiguo WANG; Yuanxin WU; Junfeng ZHANG

    2008-01-01

    The partial molar volumes of components in supercritical ammonia synthesis system are calculated in detail by the calculation formula of partial molar volume derived from the R-K equation of state under different conditions. The objectives are to comprehend phase beha-vior of components and to provide the theoretic explana-tion and guidance for probing novel processes of ammonia synthesis under supercritical conditions. The conditions of calculation are H2/N2= 3, at a concentra-tion of NH3 in synthesis gas ranging from 2% to 15%, Concentration of medium in supercritical ammonia syn-thesis system ranging from 20% to 50%, temperature ran-ging from 243 K to 699 K and pressure ranging from 0.1 MPa to 187 MPa. The results show that the ammonia synthesis system can reach supercritical state by adding a suitable supercritical medium and then controlling the reaction conditions. It is helpful for the supercritical ammonia synthesis that medium reaches supercritical state under the conditions of the corresponding total pres-sure and components near the normal temperature or near the critical temperature of medium or in the range of tem-perature of industrialized ammonia synthesis.

  11. Reaction kinetics of cellulose hydrolysis in subcritical and supercritical water

    Science.gov (United States)

    Olanrewaju, Kazeem Bode

    The uncertainties in the continuous supply of fossil fuels from the crisis-ridden oil-rich region of the world is fast shifting focus on the need to utilize cellulosic biomass and develop more efficient technologies for its conversion to fuels and chemicals. One such technology is the rapid degradation of cellulose in supercritical water without the need for an enzyme or inorganic catalyst such as acid. This project focused on the study of reaction kinetics of cellulose hydrolysis in subcritical and supercritical water. Cellulose reactions at hydrothermal conditions can proceed via the homogeneous route involving dissolution and hydrolysis or the heterogeneous path of surface hydrolysis. The work is divided into three main parts. First, the detailed kinetic analysis of cellulose reactions in micro- and tubular reactors was conducted. Reaction kinetics models were applied, and kinetics parameters at both subcritical and supercritical conditions were evaluated. The second major task was the evaluation of yields of water soluble hydrolysates obtained from the hydrolysis of cellulose and starch in hydrothermal reactors. Lastly, changes in molecular weight distribution due to hydrothermolytic degradation of cellulose were investigated. These changes were also simulated based on different modes of scission, and the pattern generated from simulation was compared with the distribution pattern from experiments. For a better understanding of the reaction kinetics of cellulose in subcritical and supercritical water, a series of reactions was conducted in the microreactor. Hydrolysis of cellulose was performed at subcritical temperatures ranging from 270 to 340 °C (tau = 0.40--0.88 s). For the dissolution of cellulose, the reaction was conducted at supercritical temperatures ranging from 375 to 395 °C (tau = 0.27--0.44 s). The operating pressure for the reactions at both subcritical and supercritical conditions was 5000 psig. The results show that the rate-limiting step in

  12. Modeling a Helical-coil Steam Generator in RELAP5-3D for the Next Generation Nuclear Plant

    Energy Technology Data Exchange (ETDEWEB)

    Nathan V. Hoffer; Piyush Sabharwall; Nolan A. Anderson

    2011-01-01

    Options for the primary heat transport loop heat exchangers for the Next Generation Nuclear Plant are currently being evaluated. A helical-coil steam generator is one heat exchanger design under consideration. Safety is an integral part of the helical-coil steam generator evaluation. Transient analysis plays a key role in evaluation of the steam generators safety. Using RELAP5-3D to model the helical-coil steam generator, a loss of pressure in the primary side of the steam generator is simulated. This report details the development of the steam generator model, the loss of pressure transient, and the response of the steam generator primary and secondary systems to the loss of primary pressure. Back ground on High Temperature Gas-cooled reactors, steam generators, the Next Generation Nuclear Plant is provided to increase the readers understanding of the material presented.

  13. Analysis of supercritical CO{sub 2} cooling in macro- and micro-channels

    Energy Technology Data Exchange (ETDEWEB)

    Cheng, Lixin; Thome, John R. [Laboratory of Heat and Mass Transfer (LTCM), Faculty of Engineering Science (STI), Ecole Polytechnique Federale de Lausanne (EPFL), Station 9, Lausanne CH-1015 (Switzerland); Ribatski, Gherhardt [Laboratory of Heat and Mass Transfer (LTCM), Faculty of Engineering Science (STI), Ecole Polytechnique Federale de Lausanne (EPFL), Station 9, Lausanne CH-1015 (Switzerland); Department of Mechanical Engineering, Escola de Engenharia de Sao Carlos (EESC), University of Sao Paulo (USP), Sao Carlos, SP 13566-590 (Brazil)

    2008-12-15

    A comprehensive analysis of heat transfer and pressure drop experimental data and correlations for supercritical CO{sub 2} cooling in macro- and micro-channels is presented in this article. First, the physical and transport properties of CO{sub 2} at supercritical conditions are discussed and then their influence on heat transfer and pressure drops. Next, a review of experimental studies on heat transfer and pressure drops of supercritical CO{sub 2} cooling is provided and detailed comparisons and analysis relative to the available heat transfer and pressure drop correlations for supercritical CO{sub 2} cooling were done where possible. Furthermore, noting the lack of all pertinent experimental details required to use the data published in many of these studies, comments are given on how to reduce and present supercritical CO{sub 2} experimental data properly in the future. In addition, the effect of oil on heat transfer and pressure drops for supercritical CO{sub 2} is shown to significantly decrease the former and to increase the latter. Comparison of experimental data to a selection of heat transfer correlations shows that the Fang et al. [2001b. Modeling and analysis of gas coolers. ASHRAE Trans. 107 (1), 4-13] correlation gives the closest values to the experimental data but is still not satisfactory. According to the comparison and analysis, it is recommended that further efforts be made to develop good heat transfer methods for supercritical CO{sub 2} cooling based on accurate database in the future. To achieve this, more careful experiments should be done over a wide range of test parameters to meet the requirement in practical applications. In addition, four experimental studies show that the Blasius equation works well for CO{sub 2} cooling in the near supercritical region. More careful experimental data are still needed to further validate this conclusion because some experimental data are much different from others. (author)

  14. Improvements in the simulation of a main steam line break with steam generator tube rupture

    Science.gov (United States)

    Gallardo, Sergio; Querol, Andrea; Verdú, Gumersindo

    2014-06-01

    The result of simultaneous Main Steam Line Break (MSLB) and a Steam Generator Tube Rupture (SGTR) in a Pressurized Water Reactor (PWR) is a depressurization in the secondary and primary system because both systems are connected through the SGTR. The OECD/NEA ROSA-2 Test 5 performed in the Large Scale Test Facility (LSTF) reproduces these simultaneous breaks in a Pressurized Water Reactor (PWR). A simulation of this Test 5 was made with the thermal-hydraulic code TRACE5. Some discrepancies found, such as an underestimation of SG-A secondary pressure during the depressurization and overestimation of the primary pressure drop after the first Power Operated Relief Valve (PORV) opening can be improved increasing the nodalization of the Upper Head in the pressure vessel and meeting the actual fluid conditions of Upper Head during the transient.

  15. Modifikasi Alat Steam untuk Pembengkokan Rotan

    Directory of Open Access Journals (Sweden)

    Eustasia Sri Murwati

    2016-04-01

    distribution of steam because there are no spaces between rattans besides contact with rust stains from tube steamer. The purpose of this study was to modify steamer that is designed multi-purpose steam, can soften rattan with wet steam in a steamer tube, can also be sprayed with dry steam on the rattan surfaces. The method is carried out field survey and literature, design planning, procurement of materials, manufacturing equipment, testing equipment, finishing equipment, evaluation and reporting. The test tool with rattan variable crosssection of 2,4 cm, 2,8 cm 3,2 cm and a steaming rattan 5 minutes, 10 minutes, and 15 minutes, with boiler and steamer tube temperature 110° C, 2 bar maximum pressure (kg / cm2. Results obtained in the form of 1 unit Steam Tool For Bending Rattan consists of: Heating, Steam boiler stainless steel base material JIS G 3116-2000 standard specifications, 118 liter of volume, steam tube SUS 340 Grade, soaking tub and bending table. The trial results are best with a steaming time of 15 minutes, rattan is not broken, no cracking or not deflated, for all variable diameter. Can bend U shape rattan, Ω, semi-circular and spiral. Dry steam trials with great results at the time of spraying is greater than 20 minutes.Keywords: steamer, furniture, bending, rattan

  16. Condensers for measuring steam quality at the inlet of back-pressure units of the Los Azufres, Mich., geothermal field; Condensadores para medir la calidad del vapor a la entrada de las turbinas a contrapresion del campo geotermico de Los Azufres, Mich.

    Energy Technology Data Exchange (ETDEWEB)

    Sandoval Medina, Fernando; Gonzalez Gonzalez, Rubi; Reyes Delgado, Lisette; Medina Martinez, Moises [Comision Federal de Electricidad, Gerencia de Proyectos Geotermoelectricos, Residencia de Los Azufres (Mexico)]. E-mail: fernando.sandoval@cfe.gob.mx

    2007-01-15

    Electrical conductivity is an indirect measurement of the quality of the steam supplied to power units. In the Los Azufres, Mich., geothermal field, the electrical conductivity once was measured in a discrete and periodic way by condensing steam samples through a water-cooled condenser. In an attempt to continuously measure conductivity, conductivity meters were installed where the units discharged, but the values proved unstable and unrepresentative. Thereafter, taking into account that steam quality should be measured at the steam delivery-reception point, equipment was designed and tested for continuously condensing steam. Finally it was possible to get an air-cooled condenser able to condense 500 milliliters per minute, enough to collect a representative flow of the steam and to measure its electrical conductivity. The equipment was installed in all seven back-pressure units operating in the field and to date has been operating in an optimal manner. [Spanish] La conductividad electrica es una medida indirecta de la calidad del vapor que se suministra a las unidades turbogeneradoras. En el campo geotermico de Los Azufres, Mich., la conductividad electrica se media en forma puntual y periodica, condensando muestras de vapor por medio de un serpentin enfriado con agua. Despues, ante la necesidad de medirla en forma continua, se instalaron conductivimetros en las descargas de las unidades, pero los valores resultaron muy inestables y poco representativos. Considerando, ademas, que la calidad del vapor debe medirse en el punto de entrega-recepcion, se disenaron y probaron equipos para condensar vapor de manera continua, lograndose construir un condensador enfriado por aire que logra condensar un flujo de 500 mililitros por minuto, cantidad suficiente para tener un flujo representativo del vapor que alimenta a las turbinas y medirle su conductividad electrica. Se instalaron estos equipos en las siete unidades turbogeneradoras a contrapresion que funcionan en el campo

  17. Steam regulation for 5 MW back-pressure units when a failure occurs in the Los Humeros, Pue., field, Mexico; Regulacion del vapor en caso de falla a unidades a contrapresion de 5 MW en el campo de Los Humeros, Pue., Mexico

    Energy Technology Data Exchange (ETDEWEB)

    Rosales Lopez, Cesar [Comision Federal de Electricidad, Puebla (Mexico)]. E-mail: cesar.rosales@cfe.gob.mx

    2006-07-15

    Four out of the seven back-pressure power units of 5 MW operating in the Los Humeros geothermal field, State of Puebla, Mexico, are fed by one steam pipe gathering the steam produced by nine wells. When a failure occurred in any of the units and the excedence valve had to be open to deviate the steam, a decrease in the steam flow for the remaining units was noted, along with lower electrical generation. The cause for that is analyzed and explained in this paper by comparing the interconnected steam supply system to an electric circuit. A way to maintain a uniform and continuous supply of steam in the Los Humeros field has been found. It was implemented several months ago and the problem has not reoccurred. [Spanish] Cuatro de las siete unidades de 5 MW a contrapresion que operan en el campo geotermico de Los Humeros, Puebla, son alimentadas por un solo vaporducto que reune el vapor de nueve pozos productores. Cuando ocurria una falla en alguna de estas unidades y se abria por completo la valvula de excedencia para desviar el vapor, se observaba una reduccion en el flujo de vapor que llegaba a las otras tres unidades, lo que a su vez ocasionaba que la generacion de electricidad se redujera notoriamente. En este trabajo se analiza y explica la causa de ello, mediante la comparacion de este sistema interconectado de suministro de vapor con un circuito electrico, y se explica la solucion que se encontro e implemento en el campo de Los Humeros para regular el suministro continuo y uniforme de vapor, con resultados satisfactorios a varios meses de su implementacion en las cuatro unidades interconectadas.

  18. Fischer-Tropsch Reaction Kinetics of Cobalt Catalyst in Supercritical Phase

    Institute of Scientific and Technical Information of China (English)

    Abdullah Irankhah; Ali Haghtalab; Ebrahim Vasheghani Farahani; Kambiz Sadaghianizadeh

    2007-01-01

    Fischer-Tropsch synthesis under supercritical phase condition was examined in a continuous and a high-pressure fixed bed reactor by employing a cobalt catalyst (Co-Ru/γ-Al2O3). An integral reactor model involving Fischer-Tropsch reaction kinetics in the supercritical fluid n-hexane was used to describe the overall performance. On the basis of Langmuir-Hinshelwood-Hougen-Watson (LHHW) model, the reaction rate constants were obtained for the rate equations of CO conversion to CH4 formation under supercritical conditions.

  19. Experimental study on heat transfer characteristics of supercritical carbon dioxide in horizontal tube

    Institute of Scientific and Technical Information of China (English)

    Jing LV; Meng FU; Na QIN; Bin DONG

    2008-01-01

    The heat transfer characteristics of supercrit-ical carbon dioxide in a horizontal tube with water in the vertical cross flow form were experimentally investi-gated. The results indicate that the changes of inlet pres-sure, mass flow rate, and cooling water flow rate have major effects on heat transfer performance. The varia-tions of Reynolds number and Prandtl number were obtained in counter flow and vertical cross flow. The four conventional correlations for convection heat transfer of supercritical carbon dioxide were verified by the experi-mental data in this study and the correlation agree with this experimental condition was determined.

  20. Solubility of climbazole and triclocarban in supercritical carbon dioxide: Measurement and correlation

    Energy Technology Data Exchange (ETDEWEB)

    Park, Chan Ik [School of Chemical and Biological Engineering and Institute of Chemical Processes, Seoul National University, Seoul 151-744 (Korea, Republic of); Department of Cosmeceutical Science, Daegu Hanny University, Gyeongsangbuk-do 712-230 (Korea, Republic of); Shin, Moon Sam [School of Chemical and Biological Engineering and Institute of Chemical Processes, Seoul National University, Seoul 151-744 (Korea, Republic of); Kim, Hwayong [School of Chemical and Biological Engineering and Institute of Chemical Processes, Seoul National University, Seoul 151-744 (Korea, Republic of)], E-mail: hwayongk@snu.ac.kr

    2009-01-15

    The supercritical technology has been considered as an appropriate alternative for separation of biomaterials from cosmetic, food, and pharmaceutical products. The solid solubility of biological compounds is the most important thermodynamic parameter in the supercritical extraction and purification. The equilibrium solubility of two biocides, climbazole, and triclocarban was measured in supercritical carbon dioxide with static method in the pressure range from (10 to 40) MPa and at temperatures equal to (313.2, 323.2, and 333.2) K. The experimental data were correlated by Peng-Robinson equation of state and quasi-chemical nonrandom lattice fluid model.