Supercontinuum noise in tapered photonic crystal fibers

DEFF Research Database (Denmark)

Møller, Uffe; Sørensen, Simon Toft; Moselund, Peter Morten

Supercontinuum generation (SCG) in highly nonlinear photonic crystal fibers (PCF) has drawn a lot of attention for the last decade. Pumping such PCFs with high-power picosecond laser pulses enables the creation of broadband and intense light. Picosecond SCG is initiated by modulation instability ...

A comparative study of noise in supercontinuum light sources for ultra-high resolution optical coherence tomography

DEFF Research Database (Denmark)

Maria J., Sanjuan-Ferrer,; Bravo Gonzalo, Ivan; Bondu, Magalie

2017-01-01

Supercontinuum (SC) light is a well-established technology, which finds applications in several domains ranging from chemistry to material science and imaging systems [1-2]. More specifically, its ultra-wide optical bandwidth and high average power make it an ideal tool for Optical Coherence...... Tomography (OCT). Over the last 5 years, numerous examples have demonstrated its high potential [3-4] in this context. However, SC light sources present pulse-to-pulse intensity variation that can limit the performance of any OCT system [5] by degrading their signal to noise ratio (SNR). To this goal, we...... have studied and compared the noise of several SC light sources and evaluated how their noise properties affect the performance of Ultra-High Resolution OCT (UHR-OCT) at 1300 nm. We have measured several SC light sources with different parameters (pulse length, energy, seed repetition rate, etc.). We...

Concept of white light in stage lighting

Science.gov (United States)

Rinaldi, Mauricio R.

2002-06-01

In perceiving objects, generally we see them in a white light situation. But, actually, there is not an absolute white, in such a manner that the different light sources have a determined kind of white, what it is known as color temperature. Even the white light may be of different kinds (different color temperature), the individual mind tends to perceive it as the same kind of white, that is to say, there is in our mind a psychological function by which we operate an integration in the perception in order to do the object perceptually invariable. On the other hand, it is a common practice in stage lighting to use color light sources. It is a well known phenomenon that a color of light produces a change in the object color perception. However, when we go to theater, we see the objects as having their real color, even if the lighting is not white. In this paper the concept of white light in stage lighting is presented, showing its possibilities of aesthetical expression.

Two-channel Hyperspectral LiDAR with a Supercontinuum Laser Source

Directory of Open Access Journals (Sweden)

Ruizhi Chen

2010-07-01

Full Text Available Recent advances in nonlinear fiber optics and compact pulsed lasers have resulted in creation of broadband directional light sources. These supercontinuum laser sources produce directional broadband light using cascaded nonlinear optical interactions in an optical fibre framework. This system is used to simultaneously measure distance and reflectance to demonstrate a technique capable of distinguishing between a vegetation target and inorganic material using the Normalized Difference Vegetation Index (NDVI parameters, while the range can be obtained from the waveform of the echoes. A two-channel, spectral range-finding system based on a supercontinuum laser source was used to determine its potential application of distinguishing the NDVI for Norway spruce, a coniferous tree, and its three-dimensional parameters at 600 nm and 800 nm. A prototype system was built using commercial components.

Supercontinuum optimization for dual-soliton based light sources using genetic algorithms in a grid platform.

Science.gov (United States)

Arteaga-Sierra, F R; Milián, C; Torres-Gómez, I; Torres-Cisneros, M; Moltó, G; Ferrando, A

2014-09-22

We present a numerical strategy to design fiber based dual pulse light sources exhibiting two predefined spectral peaks in the anomalous group velocity dispersion regime. The frequency conversion is based on the soliton fission and soliton self-frequency shift occurring during supercontinuum generation. The optimization process is carried out by a genetic algorithm that provides the optimum input pulse parameters: wavelength, temporal width and peak power. This algorithm is implemented in a Grid platform in order to take advantage of distributed computing. These results are useful for optical coherence tomography applications where bell-shaped pulses located in the second near-infrared window are needed.

Supercontinuum Generation in Uniform and Tapered Photonic Crystal Fibers

DEFF Research Database (Denmark)

Sørensen, Simon Toft; Møller, Uffe Visbech; Larsen, Casper

Supercontinuum generation (SCG) is a striking phenomenon of extreme spectral broadening involving a wealth of beautiful nonlinear physics. The study of SCG and development of today’s commercial sources really took off with the invention of the photonic crystal fiber (PCF), in which light can be m...

High power supercontinuum generation in tapered photonic crystal fibers

DEFF Research Database (Denmark)

Møller, Uffe; Sørensen, Simon Toft; Larsen, Casper

2012-01-01

the concept of a group-acceleration mismatch, that for a given taper length, the downtapering section should be as long as possible to enhance the amount of blueshifted light. We also discuss the noise properties of supercontinuum in uniform and tapered fibers and we demonstrate that the amplitude noise...

Compression of fiber supercontinuum pulses to the Fourier-limit in a high-numerical-aperture focus

DEFF Research Database (Denmark)

Tu, Haohua; Liu, Yuan; Turchinovich, Dmitry

2011-01-01

A multiphoton intrapulse interference phase scan (MIIPS) adaptively and automatically compensates the combined phase distortion from a fiber supercontinuum source, a spatial light modulator pulse shaper, and a high-NA microscope objective, allowing Fourier-transform-limited compression of the sup......A multiphoton intrapulse interference phase scan (MIIPS) adaptively and automatically compensates the combined phase distortion from a fiber supercontinuum source, a spatial light modulator pulse shaper, and a high-NA microscope objective, allowing Fourier-transform-limited compression...... power of 18–70mW, and a repetition rate of 76MHz, permitting the application of this source to nonlinear optical microscopy and coherently controlled microspectroscopy....

Record power, ultra-broadband supercontinuum source based on highly GeO2 doped silica fiber

DEFF Research Database (Denmark)

Jain, Deepak; Sidharthan, R.; Moselund, Peter M.

2016-01-01

the potential of germania based photonic crystal fiber or a step-index fiber supercontinuum source for high power ultra-broad band emission being by pumped a 1060 nm or a 1550 nm laser source. To the best of our knowledge, this is the record power, ultra-broadband, and all-fiberized supercontinuum light source...... based on silica and germania fiber ever demonstrated to the date. (C) 2016 Optical Society of America......We demonstrate highly germania doped fibers for mid-infrared supercontinuum generation. Experiments ensure a highest output power of 1.44 W for a broadest spectrum from 700 nm to 3200 nm and 6.4 W for 800 nm to 2700 nm from these fibers, while being pumped by a broadband Erbium-Ytterbium doped...

Multimode supercontinuum generation in chalcogenide glass fibres

DEFF Research Database (Denmark)

Kubat, Irnis; Bang, Ole

2016-01-01

Mid-infrared supercontinuum generation is considered in chalcogenide fibres when taking into account both polarisations and the necessary higher order modes. In particular we focus on high pulse energy supercontinuum generation with long pump pulses. The modeling indicates that when only a single...

Optimum PCF tapers for blue-enhanced supercontinuum sources

DEFF Research Database (Denmark)

Møller, Uffe Visbech; Sørensen, Simon Toft; Larsen, Casper

2012-01-01

Tapering of photonic crystal fibers has proven to be an effective way of blueshifting the dispersive wavelength edge of a supercontinuum spectrum down in the deep-blue. In this article we will review the state-of-the-art in fiber tapers, and discuss the underlying mechanisms of supercontinuum gen...... and tapered fibers, and we demonstrate that the intensity noise at the spectral edges of the generated supercontinuum is at a constant level independent on the pump power in both tapered and uniform fibers....

White Light Photorefractive Phase Zone Plates

International Nuclear Information System (INIS)

Yuan-Mei, Gao; Si-Min, Liu

2008-01-01

Incoherent white light from an incandescent source is employed to fabricate volume phase zone plates in LiNbO 3 : Fe, for the first time to our knowledge, which can guide and modulate the input white light or laser light. The diffractive efficiency of the white light volume phase zone plates fabricated can reach as high as 12%. In addition, we test the volume phase zone plates by a probe beam and find that the volume phase zone plate is present in the direction perpendicular to the c-axis and absent in the direction parallel to the c-axis. This directly proves the existence of photovoltaic photorefractive anisotropy of white light

White light wavefront control with a spatial light modulator

CSIR Research Space (South Africa)

Spangenberg, D-M

2014-01-01

Full Text Available manipulation. In this work we show that such devices can also be used to shape broadband sources without any wavelength dependence on the output beam’s phase. We outline the principle mathematically and then demonstrate it experimentally using a supercontinuum...

White-light-emitting supramolecular gels.

Science.gov (United States)

Praveen, Vakayil K; Ranjith, Choorikkat; Armaroli, Nicola

2014-01-07

Let there be light, let it be white: Recent developments in the use of chromophore-based gels as scaffolds for the assembly of white-light-emitting soft materials have been significant. The main advantage of this approach lies in the facile accommodation of selected luminescent components within the gel. Excitation-energy-transfer processes between these components ultimately generate the desired light output. Copyright © 2014 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

Zero-dispersion wavelength independent quasi-CW pumped supercontinuum generation

DEFF Research Database (Denmark)

Larsen, Casper; Sørensen, Simon Toft; Noordegraaf, Danny

2013-01-01

Continuous wave (CW) pumped supercontinuum generation depends strongly on the zero-dispersion wavelength (ZDW) of the fiber due to the low peak power. Here we study several photonic crystal fibers by use of a gain-switched CW pump laser and investigate for what power level the supercontinuum...

Studying Light Color using White LED Lighting

Science.gov (United States)

Yamagishi, Misako; Yamaba, Kazuo; Nagata, Manori; Kubo, Chiho; Nokura, Kunihiro

Recently, white Light Emitting Diodes (LEDs) are receiving attention worldwide as new lighting devices. This study examined effects of a lighting application on performance using white LEDs. The light color—the correlated color temperature (CCT) —was assessed. It affected to psychological states and physiological conditions. Three CCT conditions were respectively set for the experiment: 2500 K, 5000 K, and 8200 K. In all, 20 younger subjects (20-30 years old), 15 middle-aged to elderly subjects (45-60 years old) and 12 elderly subjects (over 65 years-old) participated. They were presented a Numerical Verification (NV) task for performance measurement. The psychological states on performance were evaluated using the lighting assessment questionnaire. The physiological conditions were recorded using an electrocardiograph. Results show that the effects of CCT differ among age groups. Especially, the performance of younger subjects might differ from CCT conditions; elderly subjects are affected by CCT condition because of their visual acuity or response to contrast of objects.

Light Sterile Neutrinos: A White Paper

DEFF Research Database (Denmark)

Abazajian, K. N.; Acero, M. A.; Agarwalla, S. K.

2012-01-01

This white paper addresses the hypothesis of light sterile neutrinos based on recent anomalies observed in neutrino experiments and the latest astrophysical data.......This white paper addresses the hypothesis of light sterile neutrinos based on recent anomalies observed in neutrino experiments and the latest astrophysical data....

Recent developments in white light emitting diodes

Science.gov (United States)

Lohe, P. P.; Nandanwar, D. V.; Belsare, P. D.; Moharil, S. V.

2018-05-01

In the recent years solid state lighting based on LEDs has revolutionized lighting technology. LEDs have many advantages over the conventional lighting based on fluorescent and incandescent lamps such as mercury free, high conversion efficiency of electrical energy into light, long lifetime reliability and ability to use with many types of devices. LEDs have emerged as a new potentially revolutionary technology that could save up to half of energy used for lighting applications. White LEDs would be the most important light source in the future, so much so that this aspect had been highlighted by the Nobel committee during the award of 2014 Nobel Prize for Physics. Recent advancement in the fabrication of GaN chip capable of emitting in blue and near UV region paved way for fabrication of white LED lamps. Mainly there are two approaches used for preparing white emitting solid state lamp. In the first approach blue light (λ=450 nm) emitted from the InGaN LED chip is partially absorbed by the YAG:Ce3+ phosphor coated on it and re-emitted as yellow fluorescence. A white light can be generated by the combination of blue + yellow emission bands. These lamps are already available. But they are suffering from major drawback that their Colour Rendering Index (CRI) is low. In the second approach, white LEDs are made by coating near ultraviolet emitting (360 to 410nm) LED with a mixture of high efficiency red, green and blue emitting phosphors, analogous to the fluorescent lamp. This method yields lamps with better color rendition. Addition of a yellow emitting phosphor improves CRI further. However conversion efficiency is compromised to some extent. Further the cost of near UV emitting chip is very high compared to blue emitting chips. Thus cost and light output wise, near UV chips are much inferior to blue chips. Recently some rare earth activated oxynitrides, silicates, fluorides have emerged as an important family of luminescent materials for white LED application

Efficient and stable laser-driven white lighting

Directory of Open Access Journals (Sweden)

Kristin A. Denault

2013-07-01

Full Text Available Laser-based white lighting offers a viable option as an efficient and color-stable high-power solid-state white light source. We show that white light generation is possible using blue or near-UV laser diodes in combination with yellow-emitting cerium-substituted yttrium aluminum garnet (YAG:Ce or a mixture of red-, green-, and blue-emitting phosphors. A variety of correlated color temperatures (CCT are achieved, ranging from cool white light with a CCT of 4400 K using a blue laser diode to a warm white light with a CCT of 2700 K using a near-UV laser diode, with respective color rendering indices of 57 and 95. The luminous flux of these devices are measured to be 252 lm and 53 lm with luminous efficacies of 76 lm/W and 19 lm/W, respectively. An estimation of the maximum efficacy of a device comprising a blue laser diode in combination with YAG:Ce is calculated and the results are used to optimize the device.

Power dependence of supercontinuum noise in uniform and tapered PCFs

DEFF Research Database (Denmark)

Møller, Uffe; Sørensen, Simon Toft; Jakobsen, C.

2012-01-01

We experimentally investigate the noise properties of picosecond supercontinuum spectra generated at different power levels in uniform and tapered photonic crystal fibers. We show that the noise at the spectral edges of the generated supercontinuum is at a constant level independent on the pump...

Optimization of Tapered Photonic Crystal Fibers for Blue-Enhanced Supercontinuum Generation

DEFF Research Database (Denmark)

Møller, Uffe; Sørensen, Simon Toft; Larsen, Casper

2012-01-01

Tapering of photonic crystal fibers is an effective way of shifting the dispersive wavelength edge of a supercontinuum spectrum down in the deep-blue. We discuss the optimum taper profile for blue-enhanced supercontinuum generation....

Multi-octave supercontinuum generation from mid-infrared filamentation in a bulk crystal

Directory of Open Access Journals (Sweden)

Faccio D.

2013-03-01

Full Text Available We present supercontinuum generation pumped by femtosecond mid-infrared pulses in a bulk homogeneous material. The spectrum extends from 450 nm into the midinfrared, and carries high spectral energy density (3 pJ/nm–10 nJ/nm. The supercontinuum has high shot-to-shot reproducibility and preserves the carrier-to-envelope phase. Our result paves the way for compact supercontinuum sources with unprecedented bandwidth.

White-Light Emission from Layered Halide Perovskites.

Science.gov (United States)

Smith, Matthew D; Karunadasa, Hemamala I

2018-03-20

With nearly 20% of global electricity consumed by lighting, more efficient illumination sources can enable massive energy savings. However, effectively creating the high-quality white light required for indoor illumination remains a challenge. To accurately represent color, the illumination source must provide photons with all the energies visible to our eye. Such a broad emission is difficult to achieve from a single material. In commercial white-light sources, one or more light-emitting diodes, coated by one or more phosphors, yield a combined emission that appears white. However, combining emitters leads to changes in the emission color over time due to the unequal degradation rates of the emitters and efficiency losses due to overlapping absorption and emission energies of the different components. A single material that emits broadband white light (a continuous emission spanning 400-700 nm) would obviate these problems. In 2014, we described broadband white-light emission upon near-UV excitation from three new layered perovskites. To date, nine white-light-emitting perovskites have been reported by us and others, making this a burgeoning field of study. This Account outlines our work on understanding how a bulk material, with no obvious emissive sites, can emit every color of the visible spectrum. Although the initial discoveries were fortuitous, our understanding of the emission mechanism and identification of structural parameters that correlate with the broad emission have now positioned us to design white-light emitters. Layered hybrid halide perovskites feature anionic layers of corner-sharing metal-halide octahedra partitioned by organic cations. The narrow, room-temperature photoluminescence of lead-halide perovskites has been studied for several decades, and attributed to the radiative recombination of free excitons (excited electron-hole pairs). We proposed that the broad white emission we observed primarily stems from exciton self-trapping. Here, the

Light extraction efficiency enhancement for fluorescent SiC based white light-emitting diodes

DEFF Research Database (Denmark)

Ou, Haiyan; Ou, Yiyu; Argyraki, Aikaterini

Fluorescent SiC based white light-emitting diodes(LEDs) light source, as an innovative energy-efficient light source, would even have longer lifetime, better light quality and eliminated blue-tone effect, compared to the current phosphor based white LED light source. In this paper, the yellow...

Recent advances in light outcoupling from white organic light-emitting diodes

Science.gov (United States)

Gather, Malte C.; Reineke, Sebastian

2015-01-01

Organic light-emitting diodes (OLEDs) have been successfully introduced to the smartphone display market and have geared up to become contenders for applications in general illumination where they promise to combine efficient generation of white light with excellent color quality, glare-free illumination, and highly attractive designs. Device efficiency is the key requirement for such white OLEDs, not only from a sustainability perspective, but also because at the high brightness required for general illumination, losses lead to heating and may, thus, cause rapid device degradation. The efficiency of white OLEDs increased tremendously over the past two decades, and internal charge-to-photon conversion can now be achieved at ˜100% yield. However, the extraction of photons remains rather inefficient (typically physics of outcoupling in white OLEDs and review recent progress toward making light extraction more efficient. We describe how structures that scatter, refract, or diffract light can be attached to the outside of white OLEDs (external outcoupling) or can be integrated close to the active layers of the device (internal outcoupling). Moreover, the prospects of using top-emitting metal-metal microcavity designs for white OLEDs and of tuning the average orientation of the emissive molecules within the OLED are discussed.

Influence of wave-front curvature on supercontinuum energy during filamentation of femtosecond laser pulses in water

Science.gov (United States)

Potemkin, F. V.; Mareev, E. I.; Smetanina, E. O.

2018-03-01

We demonstrate that using spatially divergent incident femtosecond 1240-nm laser pulses in water leads to an efficient supercontinuum generation in filaments. Optimal conditions were found when the focal plane is placed 100 -400 μ m before the water surface. Under sufficiently weak focusing conditions [numerical aperture (NA )laser pulses, the supercontinuum energy generated in divergent beams is higher than the supercontinuum energy generated in convergent beams. Analysis by means of the unidirectional pulse propagation equation shows a dramatic difference between filamentation scenarios of divergent and convergent beams, that explains corresponding features of the supercontinuum generation. Under strong focusing conditions (NA ⩾0.2 ) and high-energy laser pulses, the supercontinuum generation is suppressed for convergent beams in contrast to divergent beams that nevertheless are shown experimentally to allow supercontinuum generation. The presented technique of the supercontinuum generation in divergent beams in water is highly demanded in a development of femtosecond optical parametric amplifiers.

Modeling of dispersion engineered chalcogenide rib waveguide for ultraflat mid-infrared supercontinuum generation in all-normal dispersion regime

Science.gov (United States)

Ahmad, H.; Karim, M. R.; Rahman, B. M. A.

2018-03-01

A rigorous numerical investigation has been carried out through dispersion engineering of chalcogenide rib waveguide for near-infrared to mid-infrared ultraflat broadband supercontinuum generation in all-normal group-velocity dispersion regime. We propose a novel design of a 1-cm-long air-clad rib waveguide which is made from {Ge}_{11.5} {As}_{24} {Se}_{64.5} chalcogenide glass as the core with either silica or {Ge}_{11.5} {As}_{24} {S}_{64.5} chalcogenide glass as a lower cladding separately. A broadband ultraflat supercontinuum spanning from 1300 to 1900 nm could be generated when pumped at 1.55 μ {m} with a low input peak power of 100 W. Shifting the pump to 2 μ {m}, the supercontinuum spectra extended in the mid-infrared region up to 3400 nm with a moderate-input peak power of 500 W. To achieve further extension in mid-infrared, we excite our optimized rib waveguide in both the anomalous and all-normal dispersion pumping regions at 3.1 μ {m} with a largest input peak power of 3 kW. In the case of anomalous dispersion region pumping, numerical analysis shows that supercontinuum spectrum can be extended in the mid-infrared up to 10 μ {m}, although this contains high spectral amplitude fluctuations over the entire bandwidth which limits the supercontinuum sources in the field of high precision measurement applications. On the other hand, by optimizing a rib waveguide geometry for pumping in all-normal dispersion region, we are able to generate a smooth and flat-top coherent supercontinuum spectrum with a moderate bandwidth spanning the wavelength range 2-5.5 μ {m} with less than 5 dB spectral fluctuation over the entire output bandwidth. Our proposed design is highly suitable for making on-chip SC light sources for a variety of applications such as biomedical imaging, and environmental and industrial sensing in the mid-infrared region.

Polymer OLED White Light Development Program

Energy Technology Data Exchange (ETDEWEB)

Homer Antoniadis; Vi-En Choong; Stelios Choulis; Brian Cumpston; Rahul Gupta; Mathew Mathai; Michael Moyer; Franky So

2005-12-19

OSRAM Opto Semiconductors (OSRAM) successfully completed development, fabrication and characterization of the large area, polymer based white light OLED prototype at their OLED Research and Development (R&D) facility in San Jose, CA. The program, funded by the Department of Energy (DOE), consisted of three key objectives: (1) Develop new polymer materials and device architectures--in order to improve the performance of organic light emitters. (2) Develop processing techniques--in order to demonstrate and enable the manufacturing of large area, white light and color tunable, solid state light sources. (3) Develop new electronics and driving schemes for organic light sources, including color-tunable light sources. The key performance goals are listed. A world record efficiency of 25 lm/W was established for the solution processed white organic device from the significant improvements made during the project. However, the challenges to transfer this technology from an R&D level to a large tile format such as, the robustness of the device and the coating uniformity of large area panels, remain. In this regard, the purity and the blend nature of the materials are two factors that need to be addressed in future work. During the first year, OSRAM's Materials and Device group (M&D) worked closely with the major polymer material suppliers to develop the polymer emissive technology. M&D was successful in demonstrating a 7-8 lm/W white light source which was based on fluorescent materials. However, it became apparent that the major gains in efficiency could only be made if phosphorescent materials were utilized. Thus, in order to improve the performance of the resulting devices, the focus of the project shifted towards development of solution-processable phosphorescent light emitting diodes (PHOLEDs) and device architectures. The result is a higher efficiency than the outlined project milestone.

Light Converting Inorganic Phosphors for White Light-Emitting Diodes

OpenAIRE

Chen, Lei; Lin, Chun-Che; Yeh, Chiao-Wen; Liu, Ru-Shi

2010-01-01

White light-emitting diodes (WLEDs) have matched the emission efficiency of florescent lights and will rapidly spread as light source for homes and offices in the next 5 to 10 years. WLEDs provide a light element having a semiconductor light emitting layer (blue or near-ultraviolet (nUV) LEDs) and photoluminescence phosphors. These solid-state LED lamps, rather than organic light emitting diode (OLED) or polymer light-emitting diode (PLED), have a number of advantages over conventional incand...

White light coronagraph in OSO-7

International Nuclear Information System (INIS)

Koomen, M.J.; Detwiler, C.R.; Brueckner, G.E.; Cooper, H.W.; Tousey, R.

1975-01-01

A small, externally occulted Lyot-type coronagraph, designated for use in the seventh unmanned Orbiting Solar Observatory (OSO-7), is described. Optical configuration, suppression of stray light, SEC vidicon detector, and data system are discussed, as well as integration of the instrument into the spacecraft and operation in orbit. Orbital operation produced daily images of the white light corona, from 2.8 to 10 solar radii, at least once per day for 2 3/4 yr. The first records of white light coronal transient events were obtained, and the corona was shown to be constantly changing

White light Sagnac interferometer—a common (path) tale of light

International Nuclear Information System (INIS)

Schwartz, Eyal

2017-01-01

White or polychromatic light sources are vastly abundant in nature and lie in our most basic understanding of the theory of light, beginning from stars like our Sun and extending to every common household light bulb or street lamp. In this paper, I present concepts of white light interferometery using a common-path Sagnac interferometer, manifested in a straightforward laboratory experiment. I further show the use of this as a Fourier transform spectrometer while presenting a basic overview of the theoretical concepts and spectrum of different light sources obtained experimentally. This work, both experimentally and analytically, is suitable for upper-level undergraduate physics or engineering courses where electromagnetic theory and optics are discussed. The experiment and theory presents important deep concepts and aspects in modern optics and physics that every science student should acquire. (paper)

White light Sagnac interferometer—a common (path) tale of light

Science.gov (United States)

Schwartz, Eyal

2017-11-01

White or polychromatic light sources are vastly abundant in nature and lie in our most basic understanding of the theory of light, beginning from stars like our Sun and extending to every common household light bulb or street lamp. In this paper, I present concepts of white light interferometery using a common-path Sagnac interferometer, manifested in a straightforward laboratory experiment. I further show the use of this as a Fourier transform spectrometer while presenting a basic overview of the theoretical concepts and spectrum of different light sources obtained experimentally. This work, both experimentally and analytically, is suitable for upper-level undergraduate physics or engineering courses where electromagnetic theory and optics are discussed. The experiment and theory presents important deep concepts and aspects in modern optics and physics that every science student should acquire.

The High-Temperature Synthesis of the Nanoscaled White-Light Phosphors Applied in the White-Light LEDs

Directory of Open Access Journals (Sweden)

Hao-Ying Lu

2015-01-01

Full Text Available The white-light phosphors consisting of Dy3+ doped YPO4 and Dy3+ doped YP1-XVXO4 were prepared by the chemical coprecipitation method. After the 1200°C thermal treatment in the air atmosphere, the white-light phosphors with particle sizes around 90 nm can be obtained. In order to reduce the average particle size of phosphors, the alkaline washing method was applied to the original synthesis process, which reduces the particle sizes to 65 nm. From the PLE spectra, four absorption peaks locating at 325, 352, 366, and 390 nm can be observed in the YPO4-based phosphors. These peaks appear due to the following electron transitions: 6H15/2→4K15/2, 6H15/2→4M15/2+6P7/2, 6H15/2→4I11/2, and 6H15/2→4M19/2. Besides, the emission peaks of wavelengths 484 nm and 576 nm can be observed in the PL spectra. In order to obtain the white-light phosphors, the vanadium ions were applied to substitute the phosphorus ions to compose the YP1-XVXO4 phosphors. From the PL spectra, the strongest PL intensity can be obtained with 30% vanadium ions. As the concentration of vanadium ions increases to 40%, the phosphors with the CIE coordinates locating at the white-light area can be obtained.

Towards an analytical framework for tailoring supercontinuum generation.

Science.gov (United States)

Castelló-Lurbe, David; Vermeulen, Nathalie; Silvestre, Enrique

2016-11-14

A fully analytical toolbox for supercontinuum generation relying on scenarios without pulse splitting is presented. Furthermore, starting from the new insights provided by this formalism about the physical nature of direct and cascaded dispersive wave emission, a unified description of this radiation in both normal and anomalous dispersion regimes is derived. Previously unidentified physics of broadband spectra reported in earlier works is successfully explained on this basis. Finally, a foundry-compatible few-millimeters-long silicon waveguide allowing octave-spanning supercontinuum generation pumped at telecom wavelengths in the normal dispersion regime is designed, hence showcasing the potential of this new analytical approach.

High average power supercontinuum sources

Indian Academy of Sciences (India)

The physical mechanisms and basic experimental techniques for the creation of high average spectral power supercontinuum sources is briefly reviewed. We focus on the use of high-power ytterbium-doped fibre lasers as pump sources, and the use of highly nonlinear photonic crystal fibres as the nonlinear medium.

Light Converting Inorganic Phosphors for White Light-Emitting Diodes

Directory of Open Access Journals (Sweden)

Chiao-Wen Yeh

2010-03-01

Full Text Available White light-emitting diodes (WLEDs have matched the emission efficiency of florescent lights and will rapidly spread as light source for homes and offices in the next 5 to 10 years. WLEDs provide a light element having a semiconductor light emitting layer (blue or near-ultraviolet (nUV LEDs and photoluminescence phosphors. These solid-state LED lamps, rather than organic light emitting diode (OLED or polymer light-emitting diode (PLED, have a number of advantages over conventional incandescent bulbs and halogen lamps, such as high efficiency to convert electrical energy into light, reliability and long operating lifetime. To meet with the further requirement of high color rendering index, warm light with low color temperature, high thermal stability and higher energy efficiency for WLEDs, new phosphors that can absorb excitation energy from blue or nUV LEDs and generate visible emissions efficiently are desired. The criteria of choosing the best phosphors, for blue (450-480 nm and nUV (380-400 nm LEDs, strongly depends on the absorption and emission of the phosphors. Moreover, the balance of light between the emission from blue-nUV LEDs and the emissions from phosphors (such as yellow from Y3Al5O12:Ce3+ is important to obtain white light with proper color rendering index and color temperature. Here, we will review the status of phosphors for LEDs and prospect the future development.

Light Converting Inorganic Phosphors for White Light-Emitting Diodes

Science.gov (United States)

Chen, Lei; Lin, Chun-Che; Yeh, Chiao-Wen; Liu, Ru-Shi

2010-01-01

White light-emitting diodes (WLEDs) have matched the emission efficiency of florescent lights and will rapidly spread as light source for homes and offices in the next 5 to 10 years. WLEDs provide a light element having a semiconductor light emitting layer (blue or near-ultraviolet (nUV) LEDs) and photoluminescence phosphors. These solid-state LED lamps, rather than organic light emitting diode (OLED) or polymer light-emitting diode (PLED), have a number of advantages over conventional incandescent bulbs and halogen lamps, such as high efficiency to convert electrical energy into light, reliability and long operating lifetime. To meet with the further requirement of high color rendering index, warm light with low color temperature, high thermal stability and higher energy efficiency for WLEDs, new phosphors that can absorb excitation energy from blue or nUV LEDs and generate visible emissions efficiently are desired. The criteria of choosing the best phosphors, for blue (450−480 nm) and nUV (380−400 nm) LEDs, strongly depends on the absorption and emission of the phosphors. Moreover, the balance of light between the emission from blue-nUV LEDs and the emissions from phosphors (such as yellow from Y3Al5O12:Ce3+) is important to obtain white light with proper color rendering index and color temperature. Here, we will review the status of phosphors for LEDs and prospect the future development.

Supercontinuum generation in silicon waveguides relying on wave-breaking.

Science.gov (United States)

Castelló-Lurbe, David; Silvestre, Enrique

2015-10-05

Four-wave-mixing processes enabled during optical wave-breaking (OWB) are exploited in this paper for supercontinuum generation. Unlike conventional approaches based on OWB, phase-matching is achieved here for these nonlinear interactions, and, consequently, new frequency production becomes more efficient. We take advantage of this kind of pulse propagation to obtain numerically a coherent octave-spanning mid-infrared supercontinuum generation in a silicon waveguide pumping at telecom wavelengths in the normal dispersion regime. This scheme shows a feasible path to overcome limits imposed by two-photon absorption on spectral broadening in silicon waveguides.

Multispectral photoacoustic microscopy of lipids using a pulsed supercontinuum laser.

Science.gov (United States)

Buma, Takashi; Conley, Nicole C; Choi, Sang Won

2018-01-01

We demonstrate optical resolution photoacoustic microscopy (OR-PAM) of lipid-rich tissue between 1050-1714 nm using a pulsed supercontinuum laser based on a large-mode-area photonic crystal fiber. OR-PAM experiments of lipid-rich samples show the expected optical absorption peaks near 1210 and 1720 nm. These results show that pulsed supercontinuum lasers are promising for OR-PAM applications such as label-free histology of lipid-rich tissue and imaging small animal models of disease.

Octave-Spanning Mid-IR Supercontinuum Generation with Ultrafast Cascaded Nonlinearities

DEFF Research Database (Denmark)

Zhou, Binbin; Guo, Hairun; Liu, Xing

2014-01-01

An octave-spanning mid-IR supercontinuum is observed experimentally using ultrafast cascaded nonlinearities in an LiInS2 quadratic nonlinear crystal pumped with 70 fs energetic mid-IR pulses and cut for strongly phase-mismatched second-harmonic generation.......An octave-spanning mid-IR supercontinuum is observed experimentally using ultrafast cascaded nonlinearities in an LiInS2 quadratic nonlinear crystal pumped with 70 fs energetic mid-IR pulses and cut for strongly phase-mismatched second-harmonic generation....

Mid-infrared-to-mid-ultraviolet supercontinuum enhanced by third-to-fifteenth odd harmonics.

Science.gov (United States)

Mitrofanov, A V; Voronin, A A; Mitryukovskiy, S I; Sidorov-Biryukov, D A; Pugžlys, A; Andriukaitis, G; Flöry, T; Stepanov, E A; Fedotov, A B; Baltuška, A; Zheltikov, A M

2015-05-01

A high-energy supercontinuum spanning 4.7 octaves, from 250 to 6500 nm, is generated using a 0.3-TW, 3.9-μm output of a mid-infrared optical parametric chirped-pulse amplifier as a driver inducing a laser filament in the air. The high-frequency wing of the supercontinuum spectrum is enhanced by odd-order optical harmonics of the mid-infrared driver. Optical harmonics up to the 15th order are observed in supercontinuum spectra as overlapping, yet well-resolved peaks broadened, as verified by numerical modeling, due to spatially nonuniform ionization-induced blue shift.

Higher-Order Moment Characterisation of Rogue Wave Statistics in Supercontinuum Generation

DEFF Research Database (Denmark)

Sørensen, Simon Toft; Bang, Ole; Wetzel, Benjamin

2012-01-01

The noise characteristics of supercontinuum generation are characterized using higherorder statistical moments. Measures of skew and kurtosis, and the coefficient of variation allow quantitative identification of spectral regions dominated by rogue wave like behaviour.......The noise characteristics of supercontinuum generation are characterized using higherorder statistical moments. Measures of skew and kurtosis, and the coefficient of variation allow quantitative identification of spectral regions dominated by rogue wave like behaviour....

White LED visible light communication technology research

Science.gov (United States)

Yang, Chao

2017-03-01

Visible light communication is a new type of wireless optical communication technology. White LED to the success of development, the LED lighting technology is facing a new revolution. Because the LED has high sensitivity, modulation, the advantages of good performance, large transmission power, can make it in light transmission light signal at the same time. Use white LED light-emitting characteristics, on the modulation signals to the visible light transmission, can constitute a LED visible light communication system. We built a small visible optical communication system. The system composition and structure has certain value in the field of practical application, and we also research the key technology of transmitters and receivers, the key problem has been resolved. By studying on the optical and LED the characteristics of a high speed modulation driving circuit and a high sensitive receiving circuit was designed. And information transmission through the single chip microcomputer test, a preliminary verification has realized the data transmission function.

Laser induced white lighting of tungsten filament

Science.gov (United States)

Strek, W.; Tomala, R.; Lukaszewicz, M.

2018-04-01

The sustained bright white light emission of thin tungsten filament was induced under irradiation with focused beam of CW infrared laser diode. The broadband emission centered at 600 nm has demonstrated the threshold behavior on excitation power. Its intensity increased non-linearly with excitation power. The emission occurred only from the spot of focused beam of excitation laser diode. The white lighting was accompanied by efficient photocurrent flow and photoelectron emission which both increased non-linearly with laser irradiation power.

Warm-White-Light-Emitting Diode Based on a Dye-Loaded Metal-Organic Framework for Fast White-Light Communication.

Science.gov (United States)

Wang, Zhiye; Wang, Zi; Lin, Bangjiang; Hu, XueFu; Wei, YunFeng; Zhang, Cankun; An, Bing; Wang, Cheng; Lin, Wenbin

2017-10-11

A dye@metal-organic framework (MOF) hybrid was used as a fluorophore in a white-light-emitting diode (WLED) for fast visible-light communication (VLC). The white light was generated from a combination of blue emission of the 9,10-dibenzoate anthracene (DBA) linkers and yellow emission of the encapsulated Rhodamine B molecules. The MOF structure not only prevents dye molecules from aggregation-induced quenching but also efficiently transfers energy to the dye for dual emission. This light-emitting material shows emission lifetimes of 1.8 and 5.3 ns for the blue and yellow components, respectively, which are significantly shorter than the 200 ns lifetime of Y 3 Al 5 O 12 :Ce 3+ in commercial WLEDs. The MOF-WLED device exhibited a modulating frequency of 3.6 MHz for VLC, six times that of commercial WLEDs.

Generation of infrared supercontinuum radiation: spatial mode dispersion and higher-order mode propagation in ZBLAN step-index fibers

DEFF Research Database (Denmark)

Ramsay, Jacob Søndergaard; Dupont, Sune Vestergaard Lund; Johansen, Mikkel Willum

2013-01-01

Using femtosecond upconversion we investigate the time and wavelength structure of infrared supercontinuum generation. It is shown that radiation is scattered into higher order spatial modes (HOMs) when generating a supercontinuum using fibers that are not single-moded, such as a step-index ZBLAN...... fiber. As a consequence of intermodal scattering and the difference in group velocity for the modes, the supercontinuum splits up spatially and temporally. Experimental results indicate that a significant part of the radiation propagates in HOMs. Conventional simulations of super-continuum generation do...

Blue and white light emission from zinc oxide nanoforests

Directory of Open Access Journals (Sweden)

Nafisa Noor

2015-12-01

Full Text Available Blue and white light emission is observed when high voltage stress is applied using micrometer-separated tungsten probes across a nanoforest formed of ZnO nanorods. The optical spectrum of the emitted light consistently shows three fine peaks with very high amplitude in the 465–485 nm (blue range, corresponding to atomic transitions of zinc. Additional peaks with smaller amplitudes in the 330–650 nm range and broad spectrum white light is observed depending on the excitation conditions. The spatial and spectral distribution of the emitted light, with pink–orange regions identifying percolation paths in some cases and high intensity blue and white light with center to edge variations in others, indicate that multiple mechanisms lead to light emission. Under certain conditions, the tungsten probe tips used to make electrical contact with the ZnO structures melt during the excitation, indicating that the local temperature can exceed 3422 °C, which is the melting temperature of tungsten. The distinct and narrow peaks in the optical spectra and the abrupt increase in current at high electric fields suggest that a plasma is formed by application of the electrical bias, giving rise to light emission via atomic transitions in gaseous zinc and oxygen. The broad spectrum, white light emission is possibly due to the free electron transitions in the plasma and blackbody radiation from molten silicon. The white light may also arise from the recombination through multiple defect levels in ZnO or due to the optical excitation from solid ZnO. The electrical measurements performed at different ambient pressures result in light emission with distinguishable differences in the emission properties and I–V curves, which also indicate that the dielectric breakdown of ZnO, sublimation, and plasma formation processes are the underlying mechanisms.

Imaging camera system of OYGBR-phosphor-based white LED lighting

Science.gov (United States)

Kobashi, Katsuya; Taguchi, Tsunemasa

2005-03-01

The near-ultraviolet (nUV) white LED approach is analogous to three-color fluorescent lamp technology, which is based on the conversion of nUV radiation to visible light via the photoluminescence process in phosphor materials. The nUV light is not included in the white light generation from nUV-based white LED devices. This technology can thus provide a higher quality of white light than the blue and YAG method. A typical device demonstrates white luminescence with Tc=3,700 K, Ra > 93, K > 40 lm/W and chromaticity (x, y) = (0.39, 0.39), respectively. The orange, yellow, green and blue OYGB) or orange, yellow, red, green and blue (OYRGB) device shows a luminescence spectrum broader than of an RGB white LED and a better color rendering index. Such superior luminous characteristics could be useful for the application of several kinds of endoscope. We have shown the excellent pictures of digestive organs in a stomach of a dog due to the strong green component and high Ra.

Coherent fiber supercontinuum laser for nonlinear biomedical imaging

DEFF Research Database (Denmark)

Tu, Haohua; Liu, Yuan; Liu, Xiaomin

2012-01-01

Nonlinear biomedical imaging has not benefited from the well-known techniques of fiber supercontinuum generation for reasons such as poor coherence (or high noise), insufficient controllability, low spectral power intensity, and inadequate portability. Fortunately, a few techniques involving...... nonlinear fiber optics and femtosecond fiber laser development have emerged to overcome these critical limitations. These techniques pave the way for conducting point-of-care nonlinear biomedical imaging by a low-maintenance cost-effective coherent fiber supercontinuum laser, which covers a broad emission...... wavelength of 350-1700 nm. A prototype of this laser has been demonstrated in label-free multimodal nonlinear imaging of cell and tissue samples.© (2012) COPYRIGHT Society of Photo-Optical Instrumentation Engineers (SPIE). Downloading of the abstract is permitted for personal use only....

Supercontinuum - broad as a lamp, bright as a laser, now in the mid-infrared

DEFF Research Database (Denmark)

Moselund, Peter M.; Petersen, Christian; Dupont, Sune

2012-01-01

Based on the experience gained developing our market leading visible spectrum supercontinuum sources NKT Photonics has built the first mid-infrared supercontinuum source based on modelocked picosecond fiber lasers. The source is pumped by a ≈ 2 um laser based on a combination of erbium and thuliu...

Extension of supercontinuum spectrum generated in photonic crystal fiber by using chirped femtosecond pulses

Science.gov (United States)

Vengelis, Julius; Jarutis, Vygandas; Sirutkaitis, Valdas

2017-08-01

We present results of experimental and numerical investigation of supercontinuum generation in polarization maintaining photonic crystal fiber (PCF) using chirped femtosecond pulses. The initial unchirped pump pulse source was a mode-locked Yb:KGW laser generating 52 nJ energy 110 fs duration pulses at 1030 nm with 76 MHz repetition rate. The nonlinear medium was a 32 cm long polarization maintaining PCF manufactured by NKT Photonics A/S. We demonstrated the influence of pump pulse chirp on spectral characteristics of supercontinuum. We showed that by chirping pump pulses positively or negatively one can obtain broader supercontinuum spectrum than in case of unchirped pump pulses at the same peak power. Moreover, the extension can be controlled by changing the amount of pump pulse chirp. In our case the supercontinuum spectrum width was extended by up to 115 nm (at maximum chirp value of +10500 fs2 that we could achieve in our setup) compared to the case of unchirped pump at the same peak power.

A method for the coherence measurement of the supercontinuum source using Michelson interferometer

International Nuclear Information System (INIS)

Semenova, V A; Tsypkin, A V; Putilin, S E; Bespalov, V G

2014-01-01

Coherent properties of supercontinuum sources are highly significant for various applications, including low-coherence interferometry and optical frequency metrology. We propose a fast method for the spatial and temporal self-coherence of the SC measurement using Michelson interferometer without a mirror movement. Furthermore, we present self-coherence measurements of the supercontinuum, generated in microstructured fiber at 780 nm.

Infrared Supercontinuum Generation in Soft-glass Fibers

DEFF Research Database (Denmark)

Agger, Christian

This Ph.D.-project presents numerical simulations of supercontinuum (SC) generation in optical fiber laser systems based on various soft-glass materials. Extensive numerical modeling is performed in order to understand and characterize the generated SC. This includes a review of the generalized...

White organic light-emitting diodes with fluorescent tube efficiency.

Science.gov (United States)

Reineke, Sebastian; Lindner, Frank; Schwartz, Gregor; Seidler, Nico; Walzer, Karsten; Lüssem, Björn; Leo, Karl

2009-05-14

The development of white organic light-emitting diodes (OLEDs) holds great promise for the production of highly efficient large-area light sources. High internal quantum efficiencies for the conversion of electrical energy to light have been realized. Nevertheless, the overall device power efficiencies are still considerably below the 60-70 lumens per watt of fluorescent tubes, which is the current benchmark for novel light sources. Although some reports about highly power-efficient white OLEDs exist, details about structure and the measurement conditions of these structures have not been fully disclosed: the highest power efficiency reported in the scientific literature is 44 lm W(-1) (ref. 7). Here we report an improved OLED structure which reaches fluorescent tube efficiency. By combining a carefully chosen emitter layer with high-refractive-index substrates, and using a periodic outcoupling structure, we achieve a device power efficiency of 90 lm W(-1) at 1,000 candelas per square metre. This efficiency has the potential to be raised to 124 lm W(-1) if the light outcoupling can be further improved. Besides approaching internal quantum efficiency values of one, we have also focused on reducing energetic and ohmic losses that occur during electron-photon conversion. We anticipate that our results will be a starting point for further research, leading to white OLEDs having efficiencies beyond 100 lm W(-1). This could make white-light OLEDs, with their soft area light and high colour-rendering qualities, the light sources of choice for the future.

Supercontinuum: broad as a lamp, bright as a laser, now in the mid-infrared

Science.gov (United States)

Moselund, Peter M.; Petersen, Christian; Dupont, Sune; Agger, Christian; Bang, Ole; Keiding, Søren R.

2012-06-01

Based on the experience gained developing our market leading visible spectrum supercontinuum sources NKT Photonics has built the first mid-infrared supercontinuum source based on modelocked picosecond fiber lasers. The source is pumped by a ~ 2 um laser based on a combination of erbium and thulium and use ZBLAN fibers to generate a 1.75-4.4 μm spectrum. We will present results obtained by applying the source for mid-infrared microscopy where absorption spectra can be used to identify the chemical nature of different parts of a sample. Subsequently, we discuss the possible application of a mid-IR supercontinuum source in other areas including infrared countermeasures.

Exposing broiler eggs to green, red and white light during incubation.

Science.gov (United States)

Archer, G S

2017-07-01

Previous work has shown that exposing broiler eggs to white light during incubation can improve hatchability and post-hatch animal welfare. It was hypothesized that due to how different wavelengths of light can affect avian physiology differently, and how pigmented eggshells filter light that different monochromatic wavelengths would have differential effects on hatchability and post-hatch animal welfare indicators. To determine, we incubated chicken eggs (n=6912) under either no light (dark), green light, red light or white light; the light level was 250 lux. White and red light were observed to increase hatch of fertile (P0.05). Fear response of during isolation and tonic immobility was reduced (P0.05) from dark incubated broilers. All light incubated broilers had lower (Phatchery efficiency and post-hatch animal welfare at the same time.

Generation of infrared supercontinuum radiation: spatial mode dispersion and higher-order mode propagation in ZBLAN step-index fibers

DEFF Research Database (Denmark)

Ramsay, Jacob Søndergaard; Dupont, Sune Vestergaard Lund; Johansen, Mikkel Willum

2013-01-01

Using femtosecond upconversion we investigate the time and wavelength structure of infrared supercontinuum generation. It is shown that radiation is scattered into higher order spatial modes (HOMs) when generating a supercontinuum using fibers that are not single-moded, such as a step-index ZBLAN...... not include scattering into HOMs, and including this provides an extra degree of freedom for tailoring supercontinuum sources....

First demonstration of 'white-light' laser cooling of a stored ion beam

International Nuclear Information System (INIS)

Atutov, S.N.; Biancalana, V.; Calabrese, R.; Clauser, T.; Grimm, R.; Guidi, V.; Lamanna, G.; Lauer, I.; Lenisa, P.; Luger, V.; Mariotti, E.; Moi, L.; Schramm, U.; Stagno, V.; Stoessel, M.; Tecchio, L.; Variale, V.

1998-01-01

'White-light' cooling of an ion beam confined in a storage ring has been demonstrated at Test Storage Ring in Heidelberg. Measurements aimed at comparing 'white-light' with single-mode laser cooling show that 'white-light' cooling gives lower temperatures at higher ion densities both in a coasting and in a bunched beam

Spectrally resolved, broadband frequency response characterization of photodetectors using continuous-wave supercontinuum sources

Science.gov (United States)

Choudhury, Vishal; Prakash, Roopa; Nagarjun, K. P.; Supradeepa, V. R.

2018-02-01

A simple and powerful method using continuous wave supercontinuum lasers is demonstrated to perform spectrally resolved, broadband frequency response characterization of photodetectors in the NIR Band. In contrast to existing techniques, this method allows for a simple system to achieve the goal, requiring just a standard continuous wave(CW) high-power fiber laser source and an RF spectrum analyzer. From our recent work, we summarize methods to easily convert any high-power fiber laser into a CW supercontinuum. These sources in the time domain exhibit interesting properties all the way down to the femtosecond time scale. This enables measurement of broadband frequency response of photodetectors while the wide optical spectrum of the supercontinuum can be spectrally filtered to obtain this information in a spectrally resolved fashion. The method involves looking at the RF spectrum of the output of a photodetector under test when incident with the supercontinuum. By using prior knowledge of the RF spectrum of the source, the frequency response can be calculated. We utilize two techniques for calibration of the source spectrum, one using a prior measurement and the other relying on a fitted model. Here, we characterize multiple photodetectors from 150MHz bandwidth to >20GHz bandwidth at multiple bands in the NIR region. We utilize a supercontinuum source spanning over 700nm bandwidth from 1300nm to 2000nm. For spectrally resolved measurement, we utilize multiple wavelength bands such as around 1400nm and 1600nm. Interesting behavior was observed in the frequency response of the photodetectors when comparing broadband spectral excitation versus narrower band excitation.

White light-emitting diodes (LEDs) using (oxy)nitride phosphors

International Nuclear Information System (INIS)

Xie, R-J; Hirosaki, N; Sakuma, K; Kimura, N

2008-01-01

(Oxy)nitride phosphors have attracted great attention recently because they are promising luminescent materials for phosphor-converted white light-emitting diodes (LEDs). This paper reports the luminescent properties of (oxy)nitride phosphors in the system of M-Si-Al-O-N (M = Li, Ca or Sr), and optical properties of white LEDs using a GaN-based blue LED and (oxy)nitride phosphors. The phosphors show high conversion efficiency of blue light, suitable emission colours and small thermal quenching. The bichromatic white LEDs exhibit high luminous efficacy (∼55 lm W -1 ) and the multi-phosphor converted white LEDs show high colour rendering index (Ra 82-95). The results indicate that (oxy)nitride phosphors demonstrate their superior suitability to use as down-conversion luminescent materials in white LEDs

Three-peak standard white organic light-emitting devices for solid-state lighting

Science.gov (United States)

Guo, Kunping; Wei, Bin

2014-12-01

Standard white organic light-emitting device (OLED) lighting provides a warm and comfortable atmosphere and shows mild effect on melatonin suppression. A high-efficiency red OLED employing phosphorescent dopant has been investigated. The device generates saturated red emission with Commission Internationale de l'Eclairage (CIE) coordinates of (0.66, 0.34), characterized by a low driving voltage of 3.5 V and high external quantum efficiency of 20.1% at 130 cd m-2. In addition, we have demonstrated a two-peak cold white OLED by combining with a pure blue emitter with the electroluminescent emission of 464 nm, 6, 12-bis{[N-(3,4-dimethylpheyl)-N-(2,4,5-trimethylphenyl)]} chrysene (BmPAC). It was found that the man-made lighting device capable of yielding a relatively stable color emission within the luminance range of 1000-5000 cd m-2. And the chromaticity coordinates, varying from (0.25, 0.21) to (0.23, 0.21). Furthermore, an ultrathin layer of green-light-emitting tris (2-phenylpyridinato)iridium(Ⅲ) Ir(ppy)3 in the host material was introduced to the emissive region for compensating light. By appropriately controlling the layer thickness, the white light OLED achieved good performance of 1280 cd m-2 at 5.0 V and 5150 cd m-2 at 7.0 V, respectively. The CIE coordinates of the emitted light are quite stable at current densities from 759 cd m-2 to 5150 cd m-2, ranging from (0.34, 0.37) to (0.33, 0.33).

Optimization of Multiband White-Light Illuminants for Specified Color Temperatures

Directory of Open Access Journals (Sweden)

Snjezana Soltic

2015-01-01

Full Text Available This paper describes an effective approach for the optimization of multiband spectra to produce prospective white-light spectra having specific color temperatures. The optimization process employs a genetic algorithm known as differential evolution, which aims to minimize the color rendering differences between a prospective white-light spectrum and its corresponding reference illuminant. Color rendering is assessed by calculating the CIEDE2000 color difference (ΔE00 for 14 CIE test colors under the two sources. Optimized white-light spectra were matched to three CIE standard illuminants, that is, A (2856 K, D50 (5003 K, and D65 (6504 K. Optimal solutions for three- and four-band 25 and 50 nm Gaussian spectra are presented and analyzed, together with mixed 4-LED spectra that were optimized in the same way. In all cases, the simulated sources were shown to provide color rendering of such quality that ΔE00av ≤ 2.24 units. Such white-light sources would likely find wide acceptance in numerous lighting applications.

White OLED devices and processes for lighting applications

Science.gov (United States)

Ide, Nobuhiro; Tsuji, Hiroya; Ito, Norihiro; Matsuhisa, Yuko; Houzumi, Shingo; Nishimori, Taisuke

2010-05-01

In these days, the basic performances of white OLEDs are dramatically improved and application of OLEDs to "Lighting" is expected to be true in the near future. We have developed various technologies for OLED lighting with the aid of the Japanese governmental project, "High-efficiency lighting based on the organic light-emitting mechanism." In this project, a white OLED with high efficiency (37 lm/W) and high quality emission characteristics (CRI of 95 with a small variation of chromaticity in different directions and chromaticity just on the black-body radiation curve) applicable to "Lighting" was realized by a two-unit structure with a fluorescent deep blue emissive unit and a phosphorescent green and red emissive unit. Half-decay lifetime of this white OLED at 1,000 cd/m2 was over 40,000 h. A heat radiative, thin encapsulation structure (less than 1 mm) realized a very stable emission at high luminance of over 3,000 cd/m2. A new deposition source with a hot-wall and a rate controllable valve was developed. Thickness uniformity within +/- 3% at high deposition rate of over 8 nm/s, high material utilization of over 70 %, and repeatable deposition rate controllability were confirmed.

Colour tuning in white hybrid inorganic/organic light-emitting diodes

International Nuclear Information System (INIS)

Bruckbauer, Jochen; Brasser, Catherine; Edwards, Paul R; Martin, Robert W; Findlay, Neil J; Skabara, Peter J; Wallis, David J

2016-01-01

White hybrid inorganic/organic light-emitting diodes (LEDs) were fabricated by combining a novel organic colour converter with a blue inorganic LED. An organic small molecule was specifically synthesised to act as down-converter. The characteristics of the white colour were controlled by changing the concentration of the organic molecule based on the BODIPY unit, which was embedded in a transparent matrix, and volume of the molecule and encapsulant mixture. The concentration has a critical effect on the conversion efficiency, i.e. how much of the absorbed blue light is converted into yellow light. With increasing concentration the conversion efficiency decreases. This quenching effect is due to aggregation of the organic molecule at higher concentrations. Increasing the deposited amount of the converter does not increase the yellow emission despite more blue light being absorbed. Degradation of the organic converter was also observed during a period of 15 months from LED fabrication. Angular-dependent measurements revealed slight deviation from a Lambertian profile for the blue and yellow emission peaks leading to a small change in ‘whiteness’ with emission angle. Warm white and cool white light with correlated colour temperatures of 2770 K and 7680 K, respectively, were achieved using different concentrations of the converter molecule. Although further work is needed to improve the lifetime and poor colour rendering, these hybrid LEDs show promising results as an alternative approach for generating white LEDs compared with phosphor-based white LEDs. (paper)

Pure white-light emitting ultrasmall organic-inorganic hybrid perovskite nanoclusters.

Science.gov (United States)

Teunis, Meghan B; Lawrence, Katie N; Dutta, Poulami; Siegel, Amanda P; Sardar, Rajesh

2016-10-14

Organic-inorganic hybrid perovskites, direct band-gap semiconductors, have shown tremendous promise for optoelectronic device fabrication. We report the first colloidal synthetic approach to prepare ultrasmall (∼1.5 nm diameter), white-light emitting, organic-inorganic hybrid perovskite nanoclusters. The nearly pure white-light emitting ultrasmall nanoclusters were obtained by selectively manipulating the surface chemistry (passivating ligands and surface trap-states) and controlled substitution of halide ions. The nanoclusters displayed a combination of band-edge and broadband photoluminescence properties, covering a major part of the visible region of the solar spectrum with unprecedentedly large quantum yields of ∼12% and photoluminescence lifetime of ∼20 ns. The intrinsic white-light emission of perovskite nanoclusters makes them ideal and low cost hybrid nanomaterials for solid-state lighting applications.

White LEDs and modules in chip-on-board technology for general lighting

Science.gov (United States)

Hartmann, Paul; Wenzl, Franz P.; Sommer, Christian; Pachler, Peter; Hoschopf, Hans; Schweighart, Marko; Hartmann, Martin; Kuna, Ladislav; Jakopic, Georg; Leising, Guenther; Tasch, Stefan

2006-08-01

At present, light-emitting diode (LED) modules in various shapes are developed and designed for the general lighting, advertisement, emergency lighting, design and architectural markets. To compete with and to surpass the performance of traditional lighting systems, enhancement of Lumen output and the white light quality as well as the thermal management and the luminary integration are key factors for success. Regarding these issues, white LEDs based on the chip-on-board (COB) technology show pronounced advantages. State-of-the-art LEDs exploiting this technology are now ready to enter the general lighting segments. We introduce and discuss the specific properties of the Tridonic COB technology dedicated for general lighting. This technology, in combination with a comprehensive set of tools to improve and to enhance the Lumen output and the white light quality, including optical simulation, is the scaffolding for the application of white LEDs in emerging areas, for which an outlook will be given.

Gain-switched CW fiber laser for improved supercontinuum generation in a PCF

DEFF Research Database (Denmark)

Larsen, Casper; Noordegraaf, Danny; Skovgaard, P.M.W.

2011-01-01

We demonstrate supercontinuum generation in a PCF pumped by a gain-switched high-power continuous wave (CW) fiber laser. The pulses generated by gain-switching have a peak power of more than 700 W, a duration around 200 ns, and a repetition rate of 200 kHz giving a high average power of almost 30 W....... By coupling such a pulse train into a commercial nonlinear photonic crystal fiber, a supercontinuum is generated with a spectrum spanning from 500 to 2250 nm, a total output power of 12 W, and an infrared flatness of 6 dB over a bandwidth of more than 1000 nm with a power density above 5 dBm/nm (3 m......W/nm). This is considerably broader than when operating the same system under CW conditions. The presented approach is attractive due to the high power, power scalability, and reduced system complexity compared to picosecond-pumped supercontinuum sources. © 2011 Optical Society of America....

The Whiteness of Things and Light Scattering

Science.gov (United States)

Gratton, L. M.; Lopez-Arias, T.; Calza, G.; Oss, S.

2009-01-01

We discuss some simple experiments dealing with intriguing properties of light and its interaction with matter. In particular, we show how to emphasize that light reflection, refraction and scattering can provide a proper, physical description of human perception of the "colour" white. These experiments can be used in the classroom with an enquiry…

CdSe white quantum dots-based white light-emitting diodes with high color rendering index

Science.gov (United States)

Su, Yu-Sheng; Hsiao, Chih-Chun; Chung, Shu-Ru

2016-09-01

A white light emission CdSe quantum dots (QDs) can be prepared by chemical route under 180°C. An organic oleic acid (OA) is used to react with CdO to form Cd-OA complex. Hexadecylamine (HDA) and 1-Octadecene (ODE) were used as co-surfactants. By controlling the reaction time, a white light emission CdSe QDs can be obtained after reacts for 3 to 10 min. The luminescence spectra compose two obvious emission peaks and entire visible light ranges from 400 to 650 nm. Based on TEM measurement result, spherical morphologies with particle size 2.39+/-0.27 nm can be obtained. The quantum yields (QYs) of white CdSe QD are between 20 and 60 %, which depends on reaction time. A white CdSe QDs were mixed with UV cured gel (OPAS-226) with weight ratios 50.0 wt. %, and putted the mixture into reflective cup (3020, 13 mil) as convert type. The white LEDs have controllable CIE coordinates and correlated color temperature (CCT). The luminous efficacy of the device is less than 3 lm/W, but the color rendering index (CRI) for all devices are higher than 80. Since the luminous efficacy of hybrid devices has a direct dependence on the external QY of the UV-LED as well, the luminous efficacy can be improved by well dispersion of CdSe QDs in UV gel matrix and using optimized LED chips. Therefore, in this study, we provide a new and simple method to prepare high QY of white CdSe QDs and its have a potential to applicate in solid-state lighting.

Optical stealth transmission based on super-continuum generation in highly nonlinear fiber over WDM network.

Science.gov (United States)

Zhu, Huatao; Wang, Rong; Pu, Tao; Fang, Tao; Xiang, Peng; Zheng, Jilin; Chen, Dalei

2015-06-01

In this Letter, the optical stealth transmission carried by super-continuum spectrum optical pulses generated in highly nonlinear fiber is proposed and experimentally demonstrated. In the proposed transmission scheme, super-continuum signals are reshaped in the spectral domain through a wavelength-selective switch and are temporally spread by a chromatic dispersion device to achieve the same noise-like characteristic as the noise in optical networks, so that in both the time domain and the spectral domain, the stealth signals are hidden in public channel. Our experimental results show that compared with existing schemes where stealth channels are carried by amplified spontaneous emission noise, super-continuum signal can increase the transmission performance and robustness.

CORRELATION OF HARD X-RAY AND WHITE LIGHT EMISSION IN SOLAR FLARES

Energy Technology Data Exchange (ETDEWEB)

Kuhar, Matej; Krucker, Säm; Battaglia, Marina; Kleint, Lucia; Casadei, Diego [University of Applied Sciences and Arts Northwestern Switzerland, Bahnhofstrasse 6, 5210 Windisch (Switzerland); Oliveros, Juan Carlos Martinez; Hudson, Hugh S. [Space Sciences Laboratory, University of California, Berkeley, CA 94720-7450 (United States)

2016-01-01

A statistical study of the correlation between hard X-ray and white light emission in solar flares is performed in order to search for a link between flare-accelerated electrons and white light formation. We analyze 43 flares spanning GOES classes M and X using observations from the Reuven Ramaty High Energy Solar Spectroscopic Imager and Helioseismic and Magnetic Imager. We calculate X-ray fluxes at 30 keV and white light fluxes at 6173 Å summed over the hard X-ray flare ribbons with an integration time of 45 s around the peak hard-X ray time. We find a good correlation between hard X-ray fluxes and excess white light fluxes, with a highest correlation coefficient of 0.68 for photons with energy of 30 keV. Assuming the thick target model, a similar correlation is found between the deposited power by flare-accelerated electrons and the white light fluxes. The correlation coefficient is found to be largest for energy deposition by electrons above ∼50 keV. At higher electron energies the correlation decreases gradually while a rapid decrease is seen if the energy provided by low-energy electrons is added. This suggests that flare-accelerated electrons of energy ∼50 keV are the main source for white light production.

High energy supercontinuum sources using tapered photonic crystal fibers for multispectral photoacoustic microscopy

DEFF Research Database (Denmark)

Bondu, Magalie; Brooks, Christopher; Jakobsen, Christian

2016-01-01

We demonstrate a record bandwidth high energy supercontinuum source suitable for multispectral photoacoustic microscopy. The source has more than 150  nJ/10  nm150  nJ/10  nm bandwidth over a spectral range of 500 to 1600 nm. This performance is achieved using a carefully designed fiber taper...... with large-core input for improved power handling and small-core output that provides the desired spectral range of the supercontinuum source....

Determination of illuminants representing typical white light emitting diodes sources

DEFF Research Database (Denmark)

Jost, S.; Ngo, M.; Ferrero, A.

2017-01-01

is to develop LED-based illuminants that describe typical white LED products based on their Spectral Power Distributions (SPDs). Some of these new illuminants will be recommended in the update of the CIE publication 15 on colorimetry with the other typical illuminants, and among them, some could be used......Solid-state lighting (SSL) products are already in use by consumers and are rapidly gaining the lighting market. Especially, white Light Emitting Diode (LED) sources are replacing banned incandescent lamps and other lighting technologies in most general lighting applications. The aim of this work...... to complement the CIE standard illuminant A for calibration use in photometry....

White light emission from Tm3+/Dy3+ co-doped oxyfluoride germanate glasses under UV light excitation

International Nuclear Information System (INIS)

Lakshminarayana, G.; Yang Hucheng; Qiu Jianrong

2009-01-01

In this paper, we report on the absorption and photoluminescence properties of Tm 3+ /Dy 3+ ions co-doped oxyfluoride germanate glasses for white light emission. The X-ray diffraction (XRD) and differential thermal analysis (DTA) profiles of the host glass have been carried out to confirm its structure and thermal stability. From the measured absorption spectra, Judd-Ofelt (J-O) intensity parameters (Ω 2 , Ω 4 and Ω 6 ) have been evaluated for Tm 3+ and Dy 3+ ions. A combination of blue, yellow and red emissions has emerged in these glasses, which allows the observation of bright white light when the glasses are excited by the ultraviolet light. The white light luminescence colour could be changed by varying the excitation wavelength. Also, various colours of luminescence, including white light, can be easily tuned by adjusting the concentrations of Tm 3+ or Dy 3+ ions in the co-doped glasses. Concentration quenching effect was also investigated and possible energy transfer mechanism from Dy 3+ →Tm 3+ ions was explained which is also confirmed by the decay lifetime measurements. - Graphical Abstract: A combination of blue, yellow and red emissions has emerged from Tm 3+ /Dy 3+ co-doped glasses, which allows the observation of bright white light and makes them as excellent candidates applicable in the solid-state multi-colour three-dimensional display.

Soliton fission and supercontinuum generation in photonic crystal

Indian Academy of Sciences (India)

2015-10-17

Oct 17, 2015 ... We present a practical design of novel photonic crystal fibre (PCF) to investigate the nonlinear propagation of femtosecond pulses for the application of optical coherence tomography (OCT) based on supercontinuum generation (SCG) process. In addition, this paper contains a brief introduction of the ...

Tapered photonic crystal fibers for blue-enhanced supercontinuum generation

DEFF Research Database (Denmark)

Møller, Uffe; Sørensen, Simon Toft; Larsen, Casper

2012-01-01

Tapering of photonic crystal fibers is an effective way of shifting the blue edge of a supercontinuum spectrum down in the deep-blue. We discuss the optimum taper profile for enhancing the power in the blue edge....

Hydrothermal synthesis and white light emission of cubic ZrO2:Eu3+ nanocrystals

International Nuclear Information System (INIS)

Meetei, Sanoujam Dhiren; Singh, Shougaijam Dorendrajit

2014-01-01

Highlights: • White light emitting cubic ZrO 2 :Eu 3+ nanocrystal is synthesized by hydrothermal technique. • Eu 3+ is used to stabilize crystalline phase and to get red counterpart of the white light. • Defect emission and Eu 3+ emission combined to give white light. • The white light emitted from this nanocrystal resembles vertical daylight of the Sun. • Lifetime corresponding to red counterpart of the sample is far longer than conventional white light emitters. -- Abstract: Production of white light has been a promising area of luminescence studies. In this work, white light emitting nanocrystals of cubic zirconia doped with Eu 3+ are synthesized by hydrothermal technique. The dopant Eu 3+ is used to stabilize crystalline phase to cubic and at the same time to get red counterpart of the white light. The synthesis procedure is simple and precursor required no further annealing for crystallization. X-ray diffraction patterns show the crystalline phase of ZrO 2 :Eu 3+ to be cubic and it is confirmed by Fourier Transform Infrared spectroscopy. From transmission electron microscopy images, size of the crystals is found to be ∼5 nm. Photoluminescence emission spectrum of the sample, on monitoring excitation at O 2− –Eu 3+ charge transfer state shows broad peak due to O 2− of the zirconia and that of Eu 3+ emission. Commission Internationale de l’éclairage co-ordinate of this nanocrystal (0.32, 0.34) is closed to that of the ideal white light (0.33, 0.33). Correlated color temperature of the white light (5894 K) is within the range of vertical daylight. Lifetime (1.32 ms) corresponding to 5 D 0 energy level of the Eu 3+ is found to be far longer than conventional red counterparts of white light emitters. It suggests that the ZrO 2 :Eu 3+ nanocrystals synthesized by hydrothermal technique may find applications in simulating the vertical daylight of the Sun

Green light drives leaf photosynthesis more efficiently than red light in strong white light: revisiting the enigmatic question of why leaves are green.

Science.gov (United States)

Terashima, Ichiro; Fujita, Takashi; Inoue, Takeshi; Chow, Wah Soon; Oguchi, Riichi

2009-04-01

The literature and our present examinations indicate that the intra-leaf light absorption profile is in most cases steeper than the photosynthetic capacity profile. In strong white light, therefore, the quantum yield of photosynthesis would be lower in the upper chloroplasts, located near the illuminated surface, than that in the lower chloroplasts. Because green light can penetrate further into the leaf than red or blue light, in strong white light, any additional green light absorbed by the lower chloroplasts would increase leaf photosynthesis to a greater extent than would additional red or blue light. Based on the assessment of effects of the additional monochromatic light on leaf photosynthesis, we developed the differential quantum yield method that quantifies efficiency of any monochromatic light in white light. Application of this method to sunflower leaves clearly showed that, in moderate to strong white light, green light drove photosynthesis more effectively than red light. The green leaf should have a considerable volume of chloroplasts to accommodate the inefficient carboxylation enzyme, Rubisco, and deliver appropriate light to all the chloroplasts. By using chlorophylls that absorb green light weakly, modifying mesophyll structure and adjusting the Rubisco/chlorophyll ratio, the leaf appears to satisfy two somewhat conflicting requirements: to increase the absorptance of photosynthetically active radiation, and to drive photosynthesis efficiently in all the chloroplasts. We also discuss some serious problems that are caused by neglecting these intra-leaf profiles when estimating whole leaf electron transport rates and assessing photoinhibition by fluorescence techniques.

Nanoengineering of photonic crystal fibers for supercontinuum spectral shaping

DEFF Research Database (Denmark)

Frosz, Michael Henoch; Sørensen, Thorkild; Bang, Ole

2006-01-01

) on the location of the Stokes and anti-Stokes bands and gain bandwidth. An analysis shows that the Raman effect is responsible for reducing the four-wave mixing gain and a slight reduction in the corresponding frequency shift from the pump, when the frequency shift is much larger than the Raman shift. Using......Supercontinuum generation using picosecond pulses pumped into cobweb photonic crystal fibers is investigated. Dispersion profiles are calculated for several fiber designs and used to analytically investigate the influence of the fiber structural parameters (core size and wall thickness...... numerical simulations we find that four-wave mixing is the dominant physical mechanism for the pumping scheme considered, and that there is a trade-off between the spectral width and the spectral flatness of the supercontinuum. The balance of this trade-off is determined by nanometer-scale design...

Nearly penalty-free, less than 4 ps supercontinuum Gbit/s pulse generation over 1535-1560 nm

Science.gov (United States)

Morioka, T.; Kawanishi, S.; Mori, K.; Saruwatari, M.

1994-05-01

Nearly penalty-free less than 4ps supercontinuum WDM pulses are generated at 6.3 Gbit/s over 1535-1560 nm for the first time using a 200 nm superbroadened supercontinuum in an optical fibre pumped by 1.7 W, 3.3 ps, 1542 nm short pulses from an Er(3+)-doped fibre ring laser.

Polaron self-localization in white-light emitting hybrid perovskites

KAUST Repository

Cortecchia, Daniele

2017-02-03

Two-dimensional (2D) perovskites with the general formula APbX are attracting increasing interest as solution processable, white-light emissive materials. Recent studies have shown that their broadband emission is related to the formation of intra-gap colour centres. Here, we provide an in-depth description of the charge localization sites underlying the generation of such radiative centres and their corresponding decay dynamics, highlighting the formation of small polarons trapped within their lattice distortion field. Using a combination of spectroscopic techniques and first-principles calculations to study the white-light emitting 2D perovskites (EDBE)PbCl and (EDBE)PbBr, we infer the formation of Pb , Pb, and X (where X = Cl or Br) species confined within the inorganic perovskite framework. Due to strong Coulombic interactions, these species retain their original excitonic character and form self-trapped polaron-excitons acting as radiative colour centres. These findings are expected to be relevant for a broad class of white-light emitting perovskites with large polaron relaxation energy.

Supercontinuum based mid-IR imaging spectroscopy for cancer detection

DEFF Research Database (Denmark)

Bang, Ole; Møller, Uffe Visbech; Kubat, Irnis

2014-01-01

-power laser diodes, quantum cascade lasers and synchrotron radiation, have precluded mid-IR applications where the spatial coherence, broad bandwidth, high brightness and portability of a supercontinuum laser are all required. In an international collaboration in the EU project MINERVA [minerva...

Warm white LEDs lighting over Ra=95 and its applications

Science.gov (United States)

Kobashi, Katsuya; Taguchi, Tsunemasa

2007-02-01

We have for the first time developed warm white LEDs lighting using a combination of near ultraviolet LED and three-band (red, green and blue) white phosphors. This LED has the average color-rendering index Ra=96. Moreover, special color-rendering index R9 (red) and R15 (face color of Japanese) are estimated to be 95 and 97, respectively. We will describe the results of evaluation on the medical lighting applications such as operation, treatment and endoscope experiments, application to the LED fashions and application to the Japanese antique art (ink painting) lighting.

Photoluminescence from a Tb-doped photonic crystal microcavity for white light generation

International Nuclear Information System (INIS)

Li Yigang; Almeida, Rui M

2010-01-01

Terbium-doped one-dimensional triple microcavities have been prepared by sol-gel processing. The photoluminescence (PL) of Tb 3+ ions outside a microcavity structure, when excited by blue laser light at 488 nm, consisted of three distinct peaks at 542, 587 and 619 nm. When embedded in the microcavities, the three Tb 3+ PL peaks were enhanced, balanced and broadened by the photonic crystal structure and combined into a continuous broad band. An analysis in the CIE colour space showed that white light can be obtained by mixing the modified Tb 3+ PL with the blue exciting light, while this is impossible with the original PL profile. This novel technique may improve white light generation by enhancing and modifying the spontaneous emission of current phosphors. It may also lead to the development of new rare-earth phosphor materials based on 4f-4f transitions, able to generate white light more efficiently, via simpler and cheaper alternatives to the current phosphor compositions. A novel configuration to combine this kind of structure with a white light-emitting-diode (LED) is also proposed.

A phosphor-free white light-emitting diode using In2O3 : Tb transparent conductive light converter

International Nuclear Information System (INIS)

Chen, Lung-Chien; Tien, Ching-Ho; Liao, Wei-Chian

2011-01-01

Tb-doped indium oxide (In 2 O 3 : Tb) films were deposited on a GaN-based near-ultraviolet (NUV) light-emitting diode (LED) as a transparent conductive light converter to form a white LED. The transmittance of the In 2 O 3 : Tb film (Tb at 10 wt%) exceeded 80% in visible light and the resistivity was 0.325 Ω cm. The In 2 O 3 : Tb transparent conductive light converter was also employed on GaN-based LEDs. GaN-based NUV-LEDs with In 2 O 3 : Tb film (Tb at 10 wt%) produced forward biases of 3.42 V at an injection current of 20 mA. With increasing temperature, increasing Tb 3+ concentration and increasing injection current from 20 to 100 mA, the chromaticity coordinates barely changed in the white light area. Therefore, the GaN-based NUV-LED with In 2 O 3 : Tb film had a stable white light colour, when temperature and injection current changed, and is suitable for solid-state lighting.

Blue light filtered white light induces depression-like responses and temporary spatial learning deficits in rats.

Science.gov (United States)

Meng, Qinghe; Lian, Yuzheng; Jiang, Jianjun; Wang, Wei; Hou, Xiaohong; Pan, Yao; Chu, Hongqian; Shang, Lanqin; Wei, Xuetao; Hao, Weidong

2018-04-18

Ambient light has a vital impact on mood and cognitive functions. Blue light has been previously reported to play a salient role in the antidepressant effect via melanopsin. Whether blue light filtered white light (BFW) affects mood and cognitive functions remains unclear. The present study aimed to investigate whether BFW led to depression-like symptoms and cognitive deficits including spatial learning and memory abilities in rats, and whether they were associated with the light-responsive function in retinal explants. Male Sprague-Dawley albino rats were randomly divided into 2 groups (n = 10) and treated with a white light-emitting diode (LED) light source and BFW light source, respectively, under a standard 12 : 12 h L/D condition over 30 days. The sucrose consumption test, forced swim test (FST) and the level of plasma corticosterone (CORT) were employed to evaluate depression-like symptoms in rats. Cognitive functions were assessed by the Morris water maze (MWM) test. A multi-electrode array (MEA) system was utilized to measure electro-retinogram (ERG) responses induced by white or BFW flashes. The effect of BFW over 30 days on depression-like responses in rats was indicated by decreased sucrose consumption in the sucrose consumption test, an increased immobility time in the FST and an elevated level of plasma CORT. BFW led to temporary spatial learning deficits in rats, which was evidenced by prolonged escape latency and swimming distances in the spatial navigation test. However, no changes were observed in the short memory ability of rats treated with BFW. The micro-ERG results showed a delayed implicit time and reduced amplitudes evoked by BFW flashes compared to the white flash group. BFW induces depression-like symptoms and temporary spatial learning deficits in rats, which might be closely related to the impairment of light-evoked output signals in the retina.

Environmentally Benign Technology for Efficient Warm-White Light Emission

Science.gov (United States)

Shen, Pin-Chun; Lin, Ming-Shiun; Lin, Ching-Fuh

2014-06-01

Nowadays efficient down conversion for white light emission is mainly based on rare-earth doped phosphors or cadmium-containing quantum dots. Although they exhibit high luminescence efficiency, the rare-earth mining and cadmium pollution have so far led to extremely high environmental cost, which conflicts the original purpose of pursuing efficient lighting. Here, we explore a new strategy to achieve efficient luminescence conversion based on polymer-decorated nanoparticles. The ZnO and Mn2+ doped ZnS nanoparticles are encapsulated by poly(9,9-di-n- hexylfluorenyl-2,7-diyl). The resultant core-shell nanocomposites then encompass three UV-to-visible luminescence conversion routes for photon emissions at blue, green, and orange colors, respectively. As a result, the color temperature is widely tunable (2100 K ~ 6000 K), so candle light or pure white light can be generated. The quantum yield up to 91% could also be achieved. Such rare-earth-element free nanocomposites give the bright perspectives for energy-saving, healthy, and environmentally benign lighting.

Transforming White Light into Rainbows: Segmentation Strategies for Successful School Tax Elections

Science.gov (United States)

Senden, J. Bradford; Lifto, Don E.

2009-01-01

In the late 1600s, British physicist Sir Isaac Newton first demonstrated refraction and dispersion in a triangular prism. He discovered that a prism could decompose white light into a spectrum. Hold a prism up to the light at the correct angle and white light magically splits into vivid colors of the rainbow! So what do prisms and rainbows have to…

Towards supercontinuum-driven hyperspectral microscopy in the mid-infrared

DEFF Research Database (Denmark)

Lindsay, I. D.; Valle, S.; Ward, J.

2016-01-01

The extension of supercontinuum (SC) sources into the mid-infrared, via the use of fluoride and chalcogenide optical fibers, potentially offers the high radiance of a laser combined with spectral coverage far exceeding that of typical tunable lasers and comparable to traditional black-body emitte...

Towards a table-top synchrotron based on supercontinuum generation

DEFF Research Database (Denmark)

Petersen, Christian Rosenberg; Moselund, Peter M.; Huot, Laurent

2018-01-01

Recently, high brightness and broadband supercontinuum (SC) sources reaching far into the infrared (IR) have emerged with the potential to rival traditional broadband sources of IR radiation. Here, the brightness of these IR SC sources is compared with that of synchrotron IR beamlines and Si...

Efficient Mid-Infrared Supercontinuum Generation in Tapered Large Mode Area Chalcogenide Photonic Crystal Fibers

DEFF Research Database (Denmark)

Petersen, Christian Rosenberg; Engelsholm, Rasmus Dybbro; Markos, Christos

2017-01-01

Mid-infrared supercontinuum spanning from 1.8-9  μm with an output power of 41.5 mW is demonstrated by pumping tapered large mode area chalcogenide photonic crystal fibers using a 4 μm optical parametric source.......Mid-infrared supercontinuum spanning from 1.8-9  μm with an output power of 41.5 mW is demonstrated by pumping tapered large mode area chalcogenide photonic crystal fibers using a 4 μm optical parametric source....

White organic light emitting diodes based on fluorene-carbazole dendrimers

International Nuclear Information System (INIS)

Usluer, Özlem; Demic, Serafettin; Kus, Mahmut; Özel, Faruk; Serdar Sariciftci, Niyazi

2014-01-01

In this paper, we report on theProd. Type: FTP fabrication and characterization of blue and white light emitting devices based on two fluorene-carbazole containing dendrimers and para-sexiphenyl (6P) oligomers. Blue light emitting diodes were fabricated using 9′,9″-(9,9-dioctyl-9H-fluorene-2,7-diyl)bis-9′H-9,3′:6′,9″-tercarbazole (OFC-G2) and 9′,9″-(9,9′-spirobi[fluorene]-2,7-diyl)bis-9′H-9,3′:6′,9″-tercarbazole (SBFC-G2) dendrimers as a hole transport and emissive layer (EML) and 2,9-dimethyl-4,7-diphenyl-1,10-phenanthroline (BCP) as an electron transport layer. White light emitting diodes were fabricated using 6P and these two dendrimers as an EML. OLED device with the structure of ITO/PEDOT:PSS (50 nm)/OFC-G2 (40 nm)/6P (20 nm)/LiF:Al (0.5:100 nm) shows maximum luminance of nearly 1400 cd/m 2 and a Commission Internationale de l'Eclairage chromaticity coordinates of (0.27, 0.30) at 12 V. -- Highlights: • White organic light emitting diodes have been fabricated using two fluorene-carbazole dendrimers and para-sexiphenyl (6P) oligomers. • When only these two dendrimers are used as EML, OLED devices are emitted blue light. • The emission colors of OLED devices change from blue to white when 6P is coated on dendrimer films

Efficient light harvesting from flexible perovskite solar cells under indoor white light-emitting diode illumination

NARCIS (Netherlands)

Lucarelli, G.; Di Giacomo, F.; Zardetto, V.; Creatore, M.; Brown, T.M.

2017-01-01

This is the first report of an investigation on flexible perovskite solar cells for artificial light harvesting by using a white light-emitting diode (LED) lamp as a light source at 200 and 400 lx, values typically found in indoor environments. Flexible cells were developed using either

White light photoluminescence from ZnS films on porous Si substrates

International Nuclear Information System (INIS)

Wang Caifeng; Li Weibing; Li Qingshan; Hu Bo

2010-01-01

ZnS films were deposited on porous Si (PS) substrates using a pulsed laser deposition (PLD) technique. White light emission is observed in photoluminescence (PL) spectra, and the white light is the combination of blue and green emission from ZnS and red emission from PS. The white PL spectra are broad, intense in a visible band ranging from 450 to 700 nm. The effects of the excitation wavelength, growth temperature of ZnS films, PS porosity and annealing temperature on the PL spectra of ZnS/PS were also investigated. (semiconductor materials)

The role of phase coherence in seeded supercontinuum generation

DEFF Research Database (Denmark)

Sørensen, Simon Toft; Larsen, Casper; Møller, Uffe

2012-01-01

The noise properties of a supercontinuum can be controlled by modulating the pump with a seed pulse. In this paper, we numerically investigate the influence of seeding with a partially phase coherent weak pulse or continuous wave. We demonstrate that the noise properties of the generated supercon...

Initial steps of supercontinuum generation in photonic crystal fibers

DEFF Research Database (Denmark)

Hilligsøe, Karen Marie; Paulsen, H.N.; Thøgersen, J.

2003-01-01

The onset of supercontinuum generation in a photonic crystal fiber is investigated experimentally and numerically as a function of pump wavelength and intensity with 100-fs pulses. Soliton formation is found to be the determining factor in the initial step. The formation and behavior of a blueshi...

White light emission of carbon dots by creating different emissive traps

International Nuclear Information System (INIS)

Joseph, Julin; Anappara, Aji A.

2016-01-01

Here we report a facile and rapid synthetic strategy for white light emitting carbon dots (CDs) by creating inhomogeneity in the surface-moieties by carbonizing ethylene diamine tetra acetic acid (EDTA) and ethylene glycol (EG) which are having different functional groups. The aqueous solution of the as-synthesised nanoparticles exhibits broad-band emission at several excitation wavelengths, with CIE parameters in the white gamut. Furthermore, white light emission is demonstrated through remote-phosphor technology, by capping 365 nm UV chip with PMMA, after dispersing the polymer with CDs. The resulting emission from the white-LED reported colour parameters such as CIE (0.34, 0.38), CRI of 84 and CCT of 5078 K.

White light emission of carbon dots by creating different emissive traps

Energy Technology Data Exchange (ETDEWEB)

Joseph, Julin; Anappara, Aji A., E-mail: aji@nitc.ac.in

2016-10-15

Here we report a facile and rapid synthetic strategy for white light emitting carbon dots (CDs) by creating inhomogeneity in the surface-moieties by carbonizing ethylene diamine tetra acetic acid (EDTA) and ethylene glycol (EG) which are having different functional groups. The aqueous solution of the as-synthesised nanoparticles exhibits broad-band emission at several excitation wavelengths, with CIE parameters in the white gamut. Furthermore, white light emission is demonstrated through remote-phosphor technology, by capping 365 nm UV chip with PMMA, after dispersing the polymer with CDs. The resulting emission from the white-LED reported colour parameters such as CIE (0.34, 0.38), CRI of 84 and CCT of 5078 K.

Formulating CdSe quantum dots for white light-emitting diodes with high color rendering index

International Nuclear Information System (INIS)

Li, Fei; Li, Wan-Nan; Fu, Shao-Yun; Xiao, Hong-Mei

2015-01-01

Generation of white light using CdSe quantum dots (QDs) alone presents exciting possibilities for solid state lighting technology. In this work, Cd(Ac) 2 ·2H 2 O and Na 2 SeSO 3 are used as precursors to synthesize CdSe-QDs with an average diameter ranging from 2.77 to 4.65 nm at the low temperature from 60 to 180 °C. Smaller CdSe-QDs with an average diameter of 2.29 nm are got by an oxidation etching process using H 2 O 2 as oxidant. The structural and optical properties of these QDs are investigated and proper formulation of CdSe QDs with various sizes is carefully designed to achieve white light with a high color rendering index (CRI). It is observed for the first time that the as-prepared white light-emitting diodes from single CdSe-QDs show the Commission Inernationale del’Eclairage coordinate (CIE) of (0.30,0.34) very close to that (0.33,0.33) of pure white light and a high CRI of 84. Owing to these advantages, the as-prepared white light-emitting diodes from a single compound are promising for lighting applications. - Highlights: • CdSe-quantum dots (QDs) with a continuously changing size from 2.31 to 4.74 nm are prepared. • The obtained CdSe-QDs emit lights with tunable colors in the whole visible range. • The obtained mixture sample generates white light with a high color rendering index of 84. • The sample yields white light with the CIE coordinate (0.30, 0.34) very close to that of pure white light

Observation of an octave-spanning supercontinuum in the mid-infrared using ultrafast cascaded nonlinearities

DEFF Research Database (Denmark)

Bache, Morten; Liu, Xing; Zhou, Binbin

2014-01-01

An octave-spanning mid-IR supercontinuum is observed experimentally using ultrafast cascaded nonlinearities in an LiInS2 quadratic nonlinear crystal pumped with 70 fs energetic mid-IR pulses and cut for strongly phase-mismatched second-harmonic generation. ©OSA 2014.......An octave-spanning mid-IR supercontinuum is observed experimentally using ultrafast cascaded nonlinearities in an LiInS2 quadratic nonlinear crystal pumped with 70 fs energetic mid-IR pulses and cut for strongly phase-mismatched second-harmonic generation. ©OSA 2014....

White light emitting device based on single-phase CdS quantum dots

Science.gov (United States)

Li, Feng; Nie, Chao; You, Lai; Jin, Xiao; Zhang, Qin; Qin, Yuancheng; Zhao, Feng; Song, Yinglin; Chen, Zhongping; Li, Qinghua

2018-05-01

White light emitting diodes (WLEDs) based on quantum dots (QDs) are emerging as robust candidates for white light sources, however they are suffering from the problem of energy loss resulting from the re-absorption and self-absorption among the employed QDs of different peak wavelengths. It still remains a challenging task to construct WLEDs based on single-phase QD emitters. Here, CdS QDs with short synthesis times are introduced to the fabrication of WLEDs. With a short synthesis time, on one hand, CdS QDs with a small diameter with blue emission can be obtained. On the other hand, surface reconstruction barely has time to occur, and the surface is likely defect-ridden, which enables the existence of a broad emission covering the range of green, yellow and red regions. This is essential for the white light emission of CdS QDs, and is very important for WLED applications. The temporal evolution of the PL spectra for CdS QDs was obtained to investigate the influence of growth time on the luminescent properties. The CdS QDs with a growth time of 0.5 min exhibited a colour rendering index (CRI) of 79.5 and a correlated colour temperature (CCT) of 6238 K. With increasing reaction time, the colour coordinates of the CdS QDs will move away from the white light region in the CIE 1931 chromaticity diagram. By integrating the as prepared white light emission CdS QDs with a violet GaN chip, WLEDs were fabricated. The fabricated WLEDs exhibited a CRI of 87.9 and a CCT of 4619 K, which satisfy the demand of general illumination. The luminous flux and the luminous efficiency of the fabricated WLEDs, being less advanced than current commercial white light sources, can be further improved, meaning there is a need for much more in-depth studies on white light emission CdS QDs.

Human phase response curve to a 1 h pulse of bright white light

Science.gov (United States)

St Hilaire, Melissa A; Gooley, Joshua J; Khalsa, Sat Bir S; Kronauer, Richard E; Czeisler, Charles A; Lockley, Steven W

2012-01-01

The phase resetting response of the human circadian pacemaker to light depends on the timing of exposure and is described by a phase response curve (PRC). The current study aimed to construct a PRC for a 1 h exposure to bright white light (∼8000 lux) and to compare this PRC to a dim background light PRC. These data were also compared to a previously completed 6.7 h bright white light PRC and a dim background light PRC constructed under similar conditions. Participants were randomized for exposure to 1 h of either bright white light (n= 18) or dim background light (n= 18) scheduled at 1 of 18 circadian phases. Participants completed constant routine (CR) procedures in dim light (light exposure to assess circadian phase. Phase shifts were calculated as the difference in timing of dim light melatonin onset (DLMO) during pre- and post-stimulus CRs. Exposure to 1 h of bright white light induced a Type 1 PRC with a fitted peak-to-trough amplitude of 2.20 h. No discernible PRC was observed in the dim background light PRC. The fitted peak-to-trough amplitude of the 1 h bright light PRC was ∼40% of that for the 6.7 h PRC despite representing only 15% of the light exposure duration, consistent with previous studies showing a non-linear duration–response function for the effects of light on circadian resetting. PMID:22547633

Intrinsic white-light emission from layered hybrid perovskites.

Science.gov (United States)

Dohner, Emma R; Jaffe, Adam; Bradshaw, Liam R; Karunadasa, Hemamala I

2014-09-24

We report on the second family of layered perovskite white-light emitters with improved photoluminescence quantum efficiencies (PLQEs). Upon near-ultraviolet excitation, two new Pb-Cl and Pb-Br perovskites emit broadband "cold" and "warm" white light, respectively, with high color rendition. Emission from large, single crystals indicates an origin from the bulk material and not surface defect sites. The Pb-Br perovskite has a PLQE of 9%, which is undiminished after 3 months of continuous irradiation. Our mechanistic studies indicate that the emission has contributions from strong electron-phonon coupling in a deformable lattice and from a distribution of intrinsic trap states. These hybrids provide a tunable platform for combining the facile processability of organic materials with the structural definition of crystalline, inorganic solids.

An organic white light-emitting dye: very small molecular architecture displays panchromatic emission.

Science.gov (United States)

Nandhikonda, Premchendar; Heagy, Michael D

2010-11-14

The synthesis and photophysical characterization of a new white-light fluorophore is described. The optimization of excitation wavelengths allows the naphthalimide (NI) dyes to display blue, green or white light emission depending on the excitation wavelength.

White organic light emitting diodes based on fluorene-carbazole dendrimers

Energy Technology Data Exchange (ETDEWEB)

Usluer, Özlem, E-mail: usluerozlem@yahoo.com.tr [Department of Chemistry, Muğla Sıtkı Koçman University, 48000 Muğla (Turkey); Demic, Serafettin [Department of Materials Science and Engineering, Izmir Katip Çelebi University, 35620 Çiğli, Izmir (Turkey); Kus, Mahmut, E-mail: mahmutkus1@gmail.com [Chemical Engineering Department and Advanced Technology R and D Center, Selçuk University, Konya (Turkey); Özel, Faruk [Chemical Engineering Department and Advanced Technology R and D Center, Selçuk University, Konya (Turkey); Serdar Sariciftci, Niyazi [Linz Institute for Organic Solar Cells (LIOS), Physical Chemistry, Johannes Kepler University, Altenbergerstr. 69, A-4040 Linz (Austria)

2014-02-15

In this paper, we report on theProd. Type: FTP fabrication and characterization of blue and white light emitting devices based on two fluorene-carbazole containing dendrimers and para-sexiphenyl (6P) oligomers. Blue light emitting diodes were fabricated using 9′,9″-(9,9-dioctyl-9H-fluorene-2,7-diyl)bis-9′H-9,3′:6′,9″-tercarbazole (OFC-G2) and 9′,9″-(9,9′-spirobi[fluorene]-2,7-diyl)bis-9′H-9,3′:6′,9″-tercarbazole (SBFC-G2) dendrimers as a hole transport and emissive layer (EML) and 2,9-dimethyl-4,7-diphenyl-1,10-phenanthroline (BCP) as an electron transport layer. White light emitting diodes were fabricated using 6P and these two dendrimers as an EML. OLED device with the structure of ITO/PEDOT:PSS (50 nm)/OFC-G2 (40 nm)/6P (20 nm)/LiF:Al (0.5:100 nm) shows maximum luminance of nearly 1400 cd/m{sup 2} and a Commission Internationale de l'Eclairage chromaticity coordinates of (0.27, 0.30) at 12 V. -- Highlights: • White organic light emitting diodes have been fabricated using two fluorene-carbazole dendrimers and para-sexiphenyl (6P) oligomers. • When only these two dendrimers are used as EML, OLED devices are emitted blue light. • The emission colors of OLED devices change from blue to white when 6P is coated on dendrimer films.

Structure and Ultrafast Dynamics of White-Light-Emitting CdSe Nanocrystals

International Nuclear Information System (INIS)

Bowers, Michael J.; McBride, James; Garrett, Maria Danielle; Sammons, Jessica A.; Dukes, Albert; Schreuder, Michael A.; Watt, Tony L.; Lupini, Andrew R.; Pennycook, Stephen J.; Rosenthal, Sandra

2009-01-01

White-light emission from ultrasmall CdSe nanocrystals offers an alternative approach to the realization of solid-state lighting as an appealing technology for consumers. Unfortunately, their extremely small size limits the feasibility of traditional methods for nanocrystal characterization. This paper reports the first images of their structure, which were obtained using aberration-corrected atomic number contrast scanning transmission electron microscopy (Z-STEM). With subangstrom resolution, Z-STEM is one of the few available methods that can be used to directly image the nanocrystal's structure. The initial images suggest that they are crystalline and approximately four lattice planes in diameter. In addition to the structure, for the first time, the exciton dynamics were measured at different wavelengths of the white-light spectrum using ultrafast fluorescence upconversion spectroscopy. The data suggest that a myriad of trap states are responsible for the broad-spectrum emission. It is hoped that the information presented here will provide a foundation for the future development and improvement of white-light-emitting nanocrystals.

Photonic crystal fibers for supercontinuum generation pumped by a gain-switched CW fiber laser

DEFF Research Database (Denmark)

Larsen, Casper; Noordegraaf, Danny; Hansen, Kim P.

2012-01-01

Supercontinuum generation in photonics crystal fibers (PCFs) pumped by CW lasers yields high spectral power density and average power. However, such systems require very high pump power and long nonlinear fibers. By on/off modulating the pump diodes of the fiber laser, the relaxation oscillations...... of the laser can be exploited to enhance the broadening process. The physics behind the supercontinuum generation is investigated by sweeping the fiber length, the zero dispersion wavelength, and the fiber nonlinearity. We show that by applying gain-switching a high average output power of up to 30 W can...

Coherent multi-octave spanning supercontinuum in tapered sulphide fibres

DEFF Research Database (Denmark)

Kubat, Irnis; Mägi, Eric; Hu, Tomonori

A novel frequency comb design is proposed based on a newly developed ultrafast 3µm mid-infrared laser in conjunction with micro-taper chalcogenide fibre. The novel design allows for an all-fibre laser source yielding up to three octave coherent supercontinuum. The design is the first step in real...

Invited Article: Multiple-octave spanning high-energy mid-IR supercontinuum generation in bulk quadratic nonlinear crystals

Directory of Open Access Journals (Sweden)

Binbin Zhou

2016-08-01

Full Text Available Bright and broadband coherent mid-IR radiation is important for exciting and probing molecular vibrations. Using cascaded nonlinearities in conventional quadratic nonlinear crystals like lithium niobate, self-defocusing near-IR solitons have been demonstrated that led to very broadband supercontinuum generation in the visible, near-IR, and short-wavelength mid-IR. Here we conduct an experiment where a mid-IR crystal is pumped in the mid-IR. The crystal is cut for noncritical interaction, so the three-wave mixing of a single mid-IR femtosecond pump source leads to highly phase-mismatched second-harmonic generation. This self-acting cascaded process leads to the formation of a self-defocusing soliton at the mid-IR pump wavelength and after the self-compression point multiple octave-spanning supercontinua are observed. The results were recorded in a commercially available crystal LiInS2 pumped in the 3-4 μm range with 85 fs 50 μJ pulse energy, with the broadest supercontinuum covering 1.6-7.0 μm. We measured up 30 μJ energy in the supercontinuum, and the energy promises to scale favorably with an increased pump energy. Other mid-IR crystals can readily be used as well to cover other pump wavelengths and target other supercontinuum wavelength ranges.

Full phosphorescent white-light organic light-emitting diodes with improved color stability and efficiency by fine tuning primary emission contributions

Directory of Open Access Journals (Sweden)

Wang Hua

2014-02-01

Full Text Available In this paper, a novel type of white-light organic light emitting diode (OLED with high color stability was reported, in which the yellow-light emission layer of (4,4′-N,N′-dicarbazolebiphenyl (CBP : tris(2-phenylquinoline-C2,N′iridium(III (Ir(2-phq3 was sandwiched by double blue-light emission layers of 1,1-bis-[(di-4-tolylaminopheny1]cyclohexane (TAPC : bis[4,6-(di-fluorophenyl-pyridinato-N,C2′]picolinate (FIrpic and tris[3-(3-pyridylmesityl]borane (3TPYMB:FIrpic. And, it exhibited the maximum current efficiency of 33.1 cd/A, the turn-on voltage at about 3 V and the maximum luminance in excess of 20000 cd/m2. More important, it realized very stable white-light emission, and its CIE(x, y coordinates only shift from (0.34, 0.37 to (0.33, 0.37 as applied voltage increased from 5 V to 12 V. It is believed that the new scheme in emission layer of white-light OLED can fine tune the contribution of primary emission with applied voltage changed, resulting in high quality white-light OLED.

Full phosphorescent white-light organic light-emitting diodes with improved color stability and efficiency by fine tuning primary emission contributions

Energy Technology Data Exchange (ETDEWEB)

Hua, Wang, E-mail: wmsu2008@sinano.ac.cn, E-mail: wanghua001@tyut.edu.cn; Du, Xiaogang [Key Laboratory of Interface Science and Engineering in Advanced Materials, Taiyuan University of Technology, Ministry of Education, Taiyuan 030024 (China); Research Center of Advanced Materials Science and Technology, Taiyuan University of Technology, Taiyuan 030024 (China); Su, Wenming, E-mail: wmsu2008@sinano.ac.cn, E-mail: wanghua001@tyut.edu.cn; Zhang, Dongyu [Printable Electronics Research Centre, Suzhou Institute of Nano-Tech and Nano-Bionics, CAS, suzhou 215123 (China); Lin, Wenjing [Key Laboratory of Interface Science and Engineering in Advanced Materials, Taiyuan University of Technology, Ministry of Education, Taiyuan 030024 (China); Research Center of Advanced Materials Science and Technology, Taiyuan University of Technology, Taiyuan 030024 (China); Printable Electronics Research Centre, Suzhou Institute of Nano-Tech and Nano-Bionics, CAS, suzhou 215123 (China)

2014-02-15

In this paper, a novel type of white-light organic light emitting diode (OLED) with high color stability was reported, in which the yellow-light emission layer of (4,4{sup ′}-N,N{sup ′}-dicarbazole)biphenyl (CBP) : tris(2-phenylquinoline-C2,N{sup ′})iridium(III) (Ir(2-phq){sub 3}) was sandwiched by double blue-light emission layers of 1,1-bis-[(di-4-tolylamino)pheny1]cyclohexane (TAPC) : bis[4,6-(di-fluorophenyl)-pyridinato-N,C2{sup ′}]picolinate (FIrpic) and tris[3-(3-pyridyl)mesityl]borane (3TPYMB):FIrpic. And, it exhibited the maximum current efficiency of 33.1 cd/A, the turn-on voltage at about 3 V and the maximum luminance in excess of 20000 cd/m{sup 2}. More important, it realized very stable white-light emission, and its CIE(x, y) coordinates only shift from (0.34, 0.37) to (0.33, 0.37) as applied voltage increased from 5 V to 12 V. It is believed that the new scheme in emission layer of white-light OLED can fine tune the contribution of primary emission with applied voltage changed, resulting in high quality white-light OLED.

Full phosphorescent white-light organic light-emitting diodes with improved color stability and efficiency by fine tuning primary emission contributions

Science.gov (United States)

Hua, Wang; Du, Xiaogang; Su, Wenming; Lin, Wenjing; Zhang, Dongyu

2014-02-01

In this paper, a novel type of white-light organic light emitting diode (OLED) with high color stability was reported, in which the yellow-light emission layer of (4,4'-N,N'-dicarbazole)biphenyl (CBP) : tris(2-phenylquinoline-C2,N')iridium(III) (Ir(2-phq)3) was sandwiched by double blue-light emission layers of 1,1-bis-[(di-4-tolylamino)pheny1]cyclohexane (TAPC) : bis[4,6-(di-fluorophenyl)-pyridinato-N,C2']picolinate (FIrpic) and tris[3-(3-pyridyl)mesityl]borane (3TPYMB):FIrpic. And, it exhibited the maximum current efficiency of 33.1 cd/A, the turn-on voltage at about 3 V and the maximum luminance in excess of 20000 cd/m2. More important, it realized very stable white-light emission, and its CIE(x, y) coordinates only shift from (0.34, 0.37) to (0.33, 0.37) as applied voltage increased from 5 V to 12 V. It is believed that the new scheme in emission layer of white-light OLED can fine tune the contribution of primary emission with applied voltage changed, resulting in high quality white-light OLED.

Seeded Supercontinuum Generation - Modulation Instability Gain, Coherent and Incoherent Rogue Waves

DEFF Research Database (Denmark)

Sørensen, Simon Toft; Larsen, Casper; Møller, Uffe Visbech

2012-01-01

Deterministic supercontinuum can be generated by seeding the modulation instability-induced pulse break-up. We investigate the influence of the modulation instability gain on seeding and demonstrate the generation of coherent and incoherent rogue waves....

Tuning the colour of white polymer light emitting diodes

NARCIS (Netherlands)

Kok, M.M. de; Sarfert, W.; Paetzold, R.

2010-01-01

Colour tuning of white polymer light emitting diode (LED) light sources can be attained by various methods at various stages in the production process of the lamps and/or by the design of the active material incorporated in the LEDs. In this contribution we will describe the methods and discuss the

White light emission from fluorescent SiC with porous surface

DEFF Research Database (Denmark)

Lu, Weifang; Ou, Yiyu; Fiordaliso, Elisabetta Maria

2017-01-01

We report for the frst time a NUV light to white light conversion in a N-B co-doped 6H-SiC (fuorescent SiC) layer containing a hybrid structure. The surface of fuorescent SiC sample contains porous structures fabricated by anodic oxidation method. After passivation by 20nm thick Al2O3, the photol......We report for the frst time a NUV light to white light conversion in a N-B co-doped 6H-SiC (fuorescent SiC) layer containing a hybrid structure. The surface of fuorescent SiC sample contains porous structures fabricated by anodic oxidation method. After passivation by 20nm thick Al2O3...... the bulk fuorescent SiC layer. A high color rendering index of 81.1 has been achieved. Photoluminescence spectra in porous layers fabricated in both commercial n-type and lab grown N-B co-doped 6H-SiC show two emission peaks centered approximately at 460nm and 530nm. Such bluegreen emission phenomenon can......, the photoluminescence intensity from the porous layer was signifcant enhanced by a factor of more than 12. Using a porous layer of moderate thickness (~10µm), high-quality white light emission was realized by combining the independent emissions of blue-green emission from the porous layer and yellow emission from...

Wireless high-speed data transmission with phosphorescent white-light LEDs

NARCIS (Netherlands)

Grubor, J.; Lee, S.C.J.; Langer, K-D.; Koonen, A.M.J.; Walewski, J.

2007-01-01

Wireless transmission exceeding 100 Mbit/s is demonstrated using a phosphorescent white-light LED in a lighting-like scenario. The data rate was achieved by detecting the blue part of the optical spectrum and applying discrete multi-tone modulation.

White light signal simulator microcontroller design | Haghighi ...

African Journals Online (AJOL)

In this research, first through experimental studies, the recorded signals associated with the light white from human retina cells were digitized, then the digital data were calculated and the resulted mathematical equation was programmed on a microcontroller, and by designing a circuit, the output voltage over time similar to ...

Generation of three wide frequency bands within a single white-light cavity

Science.gov (United States)

Othman, Anas; Yevick, David; Al-Amri, M.

2018-04-01

We theoretically investigate the double-Λ scheme inside a Fabry-Pérot cavity employing a weak probe beam and two strong driving fields together with an incoherent pumping mechanism. By generating analytical expressions for the susceptibility and applying the white-light cavity conditions, we devise a procedure that reaches the white-light condition at a smaller gas density than the values typically cited in similar previous studies. Further, when the intensities of the two driving fields are equal, a single giant white band is obtained, while for unequal driving fields three white bands can be present in the cavity. Two additional techniques are then advanced for generating three white bands and a method is described for displacing the center frequency of the bands. Finally, some potential applications are suggested.

A stable Alq3@MOF composite for white-light emission.

Science.gov (United States)

Xie, Wei; He, Wen-Wen; Du, Dong-Ying; Li, Shun-Li; Qin, Jun-Sheng; Su, Zhong-Min; Sun, Chun-Yi; Lan, Ya-Qian

2016-02-25

A stable mesoporous blue-emitting MOF NENU-521 was successfully constructed. NENU-521 can serve as a host for encapsulating Alq3 to obtain tunable and efficient white-light emission. The Alq3@NENU-521 composite possesses excellent stability and can be used as a promising white phosphor in WLEDs.

Color design model of high color rendering index white-light LED module.

Science.gov (United States)

Ying, Shang-Ping; Fu, Han-Kuei; Hsieh, Hsin-Hsin; Hsieh, Kun-Yang

2017-05-10

The traditional white-light light-emitting diode (LED) is packaged with a single chip and a single phosphor but has a poor color rendering index (CRI). The next-generation package comprises two chips and a single phosphor, has a high CRI, and retains high luminous efficacy. This study employs two chips and two phosphors to improve the diode's color tunability with various proportions of two phosphors and various densities of phosphor in the silicone used. A color design model is established for color fine-tuning of the white-light LED module. The maximum difference between the measured and color-design-model simulated CIE 1931 color coordinates is approximately 0.0063 around a correlated color temperature (CCT) of 2500 K. This study provides a rapid method to obtain the color fine-tuning of a white-light LED module with a high CRI and luminous efficacy.

Odd harmonics-enhanced supercontinuum in bulk solid-state dielectric medium.

Science.gov (United States)

Garejev, N; Jukna, V; Tamošauskas, G; Veličkė, M; Šuminas, R; Couairon, A; Dubietis, A

2016-07-25

We report on generation of ultrabroadband, more than 4 octave spanning supercontinuum in thin CaF2 crystal, as pumped by intense mid-infrared laser pulses with central wavelength of 2.4 μm. The supercontinuum spectrum covers wavelength range from the ultraviolet to the mid-infrared and its short wavelength side is strongly enhanced by cascaded generation of third, fifth and seventh harmonics. Our results capture the transition from Kerr-dominated to plasma-dominated filamentation regime and uncover that in the latter the spectral superbroadening originates from dramatic plasma-induced compression of the driving pulse, which in turn induces broadening of the harmonics spectra due to cross-phase modulation effects. The experimental measurements are backed up by the numerical simulations based on a nonparaxial unidirectional propagation equation for the electric field of the pulse, which accounts for the cubic nonlinearity-induced effects, and which reproduce the experimental data in great detail.

Ultrafast supercontinuum fiber-laser based pump-probe scanning magneto-optical Kerr effect microscope for the investigation of electron spin dynamics in semiconductors at cryogenic temperatures with picosecond time and micrometer spatial resolution.

Science.gov (United States)

Henn, T; Kiessling, T; Ossau, W; Molenkamp, L W; Biermann, K; Santos, P V

2013-12-01

We describe a two-color pump-probe scanning magneto-optical Kerr effect microscope which we have developed to investigate electron spin phenomena in semiconductors at cryogenic temperatures with picosecond time and micrometer spatial resolution. The key innovation of our microscope is the usage of an ultrafast "white light" supercontinuum fiber-laser source which provides access to the whole visible and near-infrared spectral range. Our Kerr microscope allows for the independent selection of the excitation and detection energy while avoiding the necessity to synchronize the pulse trains of two separate picosecond laser systems. The ability to independently tune the pump and probe wavelength enables the investigation of the influence of excitation energy on the optically induced electron spin dynamics in semiconductors. We demonstrate picosecond real-space imaging of the diffusive expansion of optically excited electron spin packets in a (110) GaAs quantum well sample to illustrate the capabilities of the instrument.

Broadband white light emission from Ce:AlN ceramics: High thermal conductivity down-converters for LED and laser-driven solid state lighting

Directory of Open Access Journals (Sweden)

A. T. Wieg

2016-12-01

Full Text Available We introduce high thermal conductivity aluminum nitride (AlN as a transparent ceramic host for Ce3+, a well-known active ion dopant. We show that the Ce:AlN ceramics have overlapping photoluminescent (PL emission peaks that cover almost the entire visible range resulting in a white appearance under 375 nm excitation without the need for color mixing. The PL is due to a combination of intrinsic AlN defect complexes and Ce3+ electronic transitions. Importantly, the peak intensities can be tuned by varying the Ce concentration and processing parameters, causing different shades of white light without the need for multiple phosphors or light sources. The Commission Internationale de l’Eclairage coordinates calculated from the measured spectra confirm white light emission. In addition, we demonstrate the viability of laser driven white light emission by coupling the Ce:AlN to a readily available frequency tripled Nd-YAG laser emitting at 355 nm. The high thermal conductivity of these ceramic down-converters holds significant promise for producing higher power white light sources than those available today.

Broadband upconversion imaging around 4 μm using an all-fiber supercontinuum source

Science.gov (United States)

Huot, Laurent; Moselund, Peter M.; Leick, Lasse; Tidemand-Lichtenberg, Peter; Pedersen, Christian

2017-02-01

We present a novel mid-infrared imaging system born from the combination of an all-fiber mid-IR supercontinuum source developed at NKT with ultra-sensitive upconversion detection technology from DTU Fotonik. The source delivers 100 mW of average power and its spectrum extends up to 4.5 μm. The infrared signal is passed through a sample and then focused into a bulk AgGaS2 crystal and subsequently mixed with a synchronous mixing signal at 1550 nm extracted from the pump laser of the supercontinuum. Through sum frequency generation, an upconverted signal ranging from 1030 nm to 1155 nm is generated and acquired using an InGaAs camera.

Supercontinuum generation from 437 to 2850 nm in a tapered fluorotellurite microstructured fiber

Science.gov (United States)

Wang, F.; Jia, Z. X.; Yao, C. F.; Wang, S. B.; Hu, M. L.; Wu, C. F.; Ohishi, Y.; Qin, W. P.; Qin, G. S.

2016-12-01

We demonstrated supercontinuum (SC) generation in a tapered fluorotellurite microstructured fiber (MF) with a sub-micrometer core diameter. Fluorotellurite MFs based on TeO2-BaF2-Y2O3 glasses were fabricated by using a rod-in-tube method and a tapered fluorotellurite MF with a minimum core diameter of ~0.65 µm was prepared by employing a tapering system. A 1560 nm femtosecond fiber laser was used as the pumping source. With increasing the peak power of the launched pump laser to ~11 kW, SC light expanding from 437 to 2850 nm was generated in the tapered fluorotellurite MF. In addition, relatively strong blue-shifted dispersive wave at ~489 nm was also observed from the tapered fluorotellurite MF.

Zero- and two-dimensional hybrid carbon phosphors for high colorimetric purity white light-emission.

Science.gov (United States)

Ding, Yamei; Chang, Qing; Xiu, Fei; Chen, Yingying; Liu, Zhengdong; Ban, Chaoyi; Cheng, Shuai; Liu, Juqing; Huang, Wei

2018-03-01

Carbon nanomaterials are promising phosphors for white light emission. A facile single-step synthesis method has been developed to prepare zero- and two-dimensional hybrid carbon phosphors for the first time. Zero-dimensional carbon dots (C-dots) emit bright blue luminescence under 365 nm UV light and two-dimensional nanoplates improve the dispersity and film forming ability of C-dots. As a proof-of-concept application, the as-prepared hybrid carbon phosphors emit bright white luminescence in the solid state, and the phosphor-coated blue LEDs exhibit high colorimetric purity white light-emission with a color coordinate of (0.3308, 0.3312), potentially enabling the successful application of white emitting phosphors in the LED field.

Asymmetric Draw-Tower Tapers for Supercontinuum Generation and Verification of the Novel Concept of Group-Acceleration Matching

DEFF Research Database (Denmark)

Sørensen, Simon Toft; Møller, Uffe; Moselund, P. M.

2012-01-01

We present the first short asymmetrical draw-tower photonic crystal fiber taper for maximizing the power in the blue edge of a supercontinuum. The results clearly emphasize the importance of the taper shape on the spectrum.......We present the first short asymmetrical draw-tower photonic crystal fiber taper for maximizing the power in the blue edge of a supercontinuum. The results clearly emphasize the importance of the taper shape on the spectrum....

Fabrication of White Light-emitting Electrochemical Cells with Stable Emission from Exciplexes.

Science.gov (United States)

Uchida, Soichi; Takizawa, Daisuke; Ikeda, Satoru; Takeuchi, Hironori; Nishimura, Suzushi; Nishide, Hiroyuki; Nishikitani, Yoshinori

2016-11-15

The authors present an approach for fabricating stable white light emission from polymer light-emitting electrochemical cells (PLECs) having an active layer which consists of blue-fluorescent poly(9,9-di-n-dodecylfluorenyl-2,7-diyl) (PFD) and π-conjugated triphenylamine molecules. This white light emission originates from exciplexes formed between PFD and amines in electronically excited states. A device containing PFD, 4,4',4''-tris[2-naphthyl(phenyl)amino]triphenylamine (2-TNATA), Poly(ethylene oxide) and K2CF3SO3 showed white light emission with Commission internationale de l'éclairage (CIE) coordinates of (0.33, 0.43) and a Color Rendering Index (CRI) of Ra = 73 at an applied voltage of 3.5 V. Constant voltage measurements showed that the CIE coordinates of (0.27, 0.37), Ra of 67, and the emission color observed immediately after application of a voltage of 5 V were nearly unchanged and stable after 300 sec.

Non-doped-type white organic light-emitting diodes for lighting purpose

Energy Technology Data Exchange (ETDEWEB)

Zhu Jianzhuo [Key Laboratory of Excited State Processes, Changchun Institute of Optics, Fine Mechanics and Physics, Chinese Academy of Sciences, Changchun 130033 (China); Graduate School of Chinese Academy of Sciences, Beijing 100039 (China); Li Wenlian, E-mail: wllioel@yahoo.com.c [Key Laboratory of Excited State Processes, Changchun Institute of Optics, Fine Mechanics and Physics, Chinese Academy of Sciences, Changchun 130033 (China); Chu Bei, E-mail: beichu@163.co [Key Laboratory of Excited State Processes, Changchun Institute of Optics, Fine Mechanics and Physics, Chinese Academy of Sciences, Changchun 130033 (China); Yan Fei; Yang Dongfang; Liu Huihui; Wang Junbo [Key Laboratory of Excited State Processes, Changchun Institute of Optics, Fine Mechanics and Physics, Chinese Academy of Sciences, Changchun 130033 (China); Graduate School of Chinese Academy of Sciences, Beijing 100039 (China)

2010-05-15

We demonstrate a non-doped white organic light-emitting diode (WOLED) in which the blue-, green- and red-emissions are generated from 4,4'-bis(2,2'-diphenylvinyl)-1,1'-biphenyl, tris(8-hydroxyquinoline)aluminum (Alq) and 4-(dicyanomethylene)-2-t-butyl-6-(1,1,7,7-tetramethyl-julolidyl 9-enyl)-4H-pyran (DCJTB), which is used as an ultrathin layer. The DCJTB ultrathin layer plays the chromaticity tuning role in optimizing the white spectral band by modulating the location of the DCJTB ultrathin layer in the green emissive Alq layer. The optimized WOLED gives the Commission Internationale de l'Eclairage-1931 xy coordinates of (0.319, 0.335), a color rendering index of 91.2 at 10 V, a maximum brightness of 21010 cd/m{sup 2} at 12 V and a maximum current efficiency of 5.17 cd/A at 6.6 V. The electroluminescence mechanism of the white device is also discussed.

Submicron Resolution Spectral-Domain Optical Coherence Tomography

KAUST Repository

Alarousu, Erkki

2013-11-14

Apparatuses and systems for submicron resolution spectral-domain optical coherence tomography (OCT) are disclosed. The system may use white light sources having wavelengths within 400-1000 nanometers, and achieve resolution below 1 .mu.m. The apparatus is aggregated into a unitary piece, and a user can connect the apparatus to a user provided controller and/or light source. The light source may be a supercontinuum source.

Improved light extraction from white organic light-emitting devices using a binary random phase array

International Nuclear Information System (INIS)

Inada, Yasuhisa; Nishiwaki, Seiji; Hirasawa, Taku; Nakamura, Yoshitaka; Hashiya, Akira; Wakabayashi, Shin-ichi; Suzuki, Masa-aki; Matsuzaki, Jumpei

2014-01-01

We have developed a binary random phase array (BRPA) to improve the light extraction performance of white organic light-emitting devices (WOLEDs). We demonstrated that the scattering of incoming light can be controlled by employing diffraction optics to modify the structural parameters of the BRPA. Applying a BRPA to the substrate of the WOLED leads to enhanced extraction efficiency and suppression of angle-dependent color changes. Our systematic study clarifies the effect of scattering on the light extraction of WOLEDs

Improved light extraction from white organic light-emitting devices using a binary random phase array

Energy Technology Data Exchange (ETDEWEB)

Inada, Yasuhisa, E-mail: inada.yasuhisa@jp.panasonic.com; Nishiwaki, Seiji; Hirasawa, Taku; Nakamura, Yoshitaka; Hashiya, Akira; Wakabayashi, Shin-ichi; Suzuki, Masa-aki [R and D Division, Panasonic Corporation, 1006 Kadoma, Kadoma City, Osaka 571-8501 (Japan); Matsuzaki, Jumpei [Device Development Center, Eco Solutions Company, Panasonic Corporation, 1048 Kadoma, Osaka 571-8686 Japan (Japan)

2014-02-10

We have developed a binary random phase array (BRPA) to improve the light extraction performance of white organic light-emitting devices (WOLEDs). We demonstrated that the scattering of incoming light can be controlled by employing diffraction optics to modify the structural parameters of the BRPA. Applying a BRPA to the substrate of the WOLED leads to enhanced extraction efficiency and suppression of angle-dependent color changes. Our systematic study clarifies the effect of scattering on the light extraction of WOLEDs.

Dy:Eu doped CaBAl glasses for white light applications

Science.gov (United States)

Lodi, T. A.; Sandrini, M.; Medina, A. N.; Barboza, M. J.; Pedrochi, F.; Steimacher, A.

2018-02-01

The combination of Eu3+ and Dy3+ in co-doped glassy materials provides interesting applicability for white light emission devices. In this work, Dy:Eu doped Calcium Boroaluminate (CaBAl) glasses were prepared by conventional melting quenching, with 3 wt% of Dy2O3 and Eu2O3 content varying from 0 to 3 wt%, and results of absorption spectra, photoluminescence and photoluminescence lifetime are discussed in terms of Eu2O3 content. The photoluminescence of the samples was studied under excitation of 365 and 405 nm light source. The 365 nm excitation shows favor to the Dy3+ ion emission. The results of photoluminescence lifetime at 575 nm (Dy3+) shows a decrease due to Eu2O3 addition, which suggests an energy transfer from Dy3+ (donor) to the Eu3+ (acceptor). On the other hand, under excitation of 405 nm, the photoluminescence lifetime at 575 nm (Dy3+) shows no significant changes due to Eu2O3 amount, which indicates that the energy transfer from Dy3+ to Eu3+ (under λexc = 405 nm) is negligible. However, the results of photoluminescence under 405 nm excitation present a white yellowish emission in the CIE diagram, which shifts to red with Eu2O3 addition. The combination of a Blue LED (BL) emission with the emission of the samples was also studied in the CIE diagram, in order to improve light emission and to obtain ideal White Light (WL). The results show that by modifying the emission intensity of BL, it is possible to achieve a route for smart lighting, close to the circadian light cycle.

Spectral optimization simulation of white light based on the photopic eye-sensitivity curve

International Nuclear Information System (INIS)

Dai, Qi; Hao, Luoxi; Lin, Yi; Cui, Zhe

2016-01-01

Spectral optimization simulation of white light is studied to boost maximum attainable luminous efficacy of radiation at high color-rendering index (CRI) and various color temperatures. The photopic eye-sensitivity curve V(λ) is utilized as the dominant portion of white light spectra. Emission spectra of a blue InGaN light-emitting diode (LED) and a red AlInGaP LED are added to the spectrum of V(λ) to match white color coordinates. It is demonstrated that at the condition of color temperature from 2500 K to 6500 K and CRI above 90, such white sources can achieve spectral efficacy of 330–390 lm/W, which is higher than the previously reported theoretical maximum values. We show that this eye-sensitivity-based approach also has advantages on component energy conversion efficiency compared with previously reported optimization solutions

Spectral optimization simulation of white light based on the photopic eye-sensitivity curve

Energy Technology Data Exchange (ETDEWEB)

Dai, Qi, E-mail: qidai@tongji.edu.cn [College of Architecture and Urban Planning, Tongji University, 1239 Siping Road, Shanghai 200092 (China); Institute for Advanced Study, Tongji University, 1239 Siping Road, Shanghai 200092 (China); Key Laboratory of Ecology and Energy-saving Study of Dense Habitat (Tongji University), Ministry of Education, 1239 Siping Road, Shanghai 200092 (China); Hao, Luoxi; Lin, Yi; Cui, Zhe [College of Architecture and Urban Planning, Tongji University, 1239 Siping Road, Shanghai 200092 (China); Key Laboratory of Ecology and Energy-saving Study of Dense Habitat (Tongji University), Ministry of Education, 1239 Siping Road, Shanghai 200092 (China)

2016-02-07

Spectral optimization simulation of white light is studied to boost maximum attainable luminous efficacy of radiation at high color-rendering index (CRI) and various color temperatures. The photopic eye-sensitivity curve V(λ) is utilized as the dominant portion of white light spectra. Emission spectra of a blue InGaN light-emitting diode (LED) and a red AlInGaP LED are added to the spectrum of V(λ) to match white color coordinates. It is demonstrated that at the condition of color temperature from 2500 K to 6500 K and CRI above 90, such white sources can achieve spectral efficacy of 330–390 lm/W, which is higher than the previously reported theoretical maximum values. We show that this eye-sensitivity-based approach also has advantages on component energy conversion efficiency compared with previously reported optimization solutions.

White light emission from engineered silicon carbide

DEFF Research Database (Denmark)

Ou, Haiyan

Silicon carbide (SiC) is a wide indirect bandgap semiconductor. The light emission efficiency is low in nature. But this material has very unique physical properties like good thermal conductivity, high break down field etc in addition to its abundance. Therefore it is interesting to engineer its...... light emission property so that to take fully potential applications of this material. In this talk, two methods, i.e. doping SiC heavily by donor-acceptor pairs and making SiC porous are introduced to make light emission from SiC. By co-doping SiC with nitrogen and boron heavily, strong yellow emission...... is demonstrated. After optimizing the passivation conditions, strong blue-green emission from porous SiC is demonstrated as well. When combining the yellow emission from co-doped SiC and blue-green from porous SiC, a high color rendering index white light source is achieved....

Fluorescent Silicon Carbide and its Applications in White Light-Emitting Diodes

DEFF Research Database (Denmark)

Ou, Yiyu

light extraction efficiency are presented. White LEDs are the most promising techniques to replace the conventional lighting sources. A typical white LED consists of a Gallium Nitride (GaN) blue or Ultraviolet (UV) LED stack and a wavelengthconversion material. Silicon Carbide (SiC) has a wide optical...... rendering performance and a much longer material lifetime compared with the commonly used wavelength-conversion material like Phosphors. In this thesis, f-SiC with different doping concentrations are analyzed and optimized in order to enhance the quantum efficiency. On the other hand, semiconductor...

White light quality of phosphor converted light-emitting diodes: A phosphor materials perspective of view

International Nuclear Information System (INIS)

Sommer, Christian; Hartmann, Paul; Pachler, Peter; Hoschopf, Hans; Wenzl, Franz P.

2012-01-01

Highlights: ► We discuss the impact of the optical properties of a phosphor for colour temperature constancy in solid state lighting. ► Quantitative evaluation of permissible variations of the optical properties for batch-to-batch reproducibility. ► Quantitative evaluation of permissible variations of the optical properties upon temperature increase. ► Quantitative evaluation of permissible variations of the optical properties upon materials degradation. - Abstract: For a systematic approach to improve the white light quality of phosphor converted LEDs and to fulfil the demands for colour temperature reproducibility and constancy, it is imperative to understand how variations of the extinction coefficient and the quantum efficiency of the phosphor particles as well as variations of the excitation wavelength of the blue LED die affect the correlated colour temperature of the white LED source. Based on optical ray tracing of a phosphor converted white LED package we deduce permissible values for the variation of a given extinction coefficient and a given quantum efficiency of a phosphor material in order to maintain acceptable colour variations. These quantitative valuations of the required constancy of the optical properties of the phosphors will in particular provide some benchmarks for the synthesis of improved phosphor materials aiming at solid state lighting applications.

Phase shifting white light interferometry using colour CCD for optical metrology and bio-imaging applications

Science.gov (United States)

Upputuri, Paul Kumar; Pramanik, Manojit

2018-02-01

Phase shifting white light interferometry (PSWLI) has been widely used for optical metrology applications because of their precision, reliability, and versatility. White light interferometry using monochrome CCD makes the measurement process slow for metrology applications. WLI integrated with Red-Green-Blue (RGB) CCD camera is finding imaging applications in the fields optical metrology and bio-imaging. Wavelength dependent refractive index profiles of biological samples were computed from colour white light interferograms. In recent years, whole-filed refractive index profiles of red blood cells (RBCs), onion skin, fish cornea, etc. were measured from RGB interferograms. In this paper, we discuss the bio-imaging applications of colour CCD based white light interferometry. The approach makes the measurement faster, easier, cost-effective, and even dynamic by using single fringe analysis methods, for industrial applications.

Students’ conceptions on white light and implications for teaching and learning about colour

Science.gov (United States)

Haagen-Schützenhöfer, Claudia

2017-07-01

The quality of learning processes is mainly determined by the extent to which students’ conceptions are addressed and thus conceptual change is triggered. Colour phenomena are a topic within initial instruction of optics which is challenging. A physically adequate concept of white light is crucial for being able to grasp the processes underlying colour formation. Our previous research suggests that misconceptions on white light may influence the conceptual understanding of colour phenomena. For the design of a learning environment on light and colours, the literature was reviewed. Then an explorative interview study with participants (N  =  32), with and without instruction in introductory optics, was carried out. In addition, the representations used for white light in Austrian physics schoolbooks were analysed. Based on the results of the literature review, the interview study and the schoolbook analysis, a learning environment was designed and tested in teaching experiments. The results indicate that learners often lack an adequate concept of white light even after instruction in introductory optics. This seems to cause learning difficulties concerning colour phenomena. On the other hand, the evaluation of our learning environment showed that students are able to gain a good conceptual understanding of colour phenomena if instruction takes these content specific learning difficulties into account.

SEMICONDUCTOR MATERIALS: White light photoluminescence from ZnS films on porous Si substrates

Science.gov (United States)

Caifeng, Wang; Qingshan, Li; Bo, Hu; Weibing, Li

2010-03-01

ZnS films were deposited on porous Si (PS) substrates using a pulsed laser deposition (PLD) technique. White light emission is observed in photoluminescence (PL) spectra, and the white light is the combination of blue and green emission from ZnS and red emission from PS. The white PL spectra are broad, intense in a visible band ranging from 450 to 700 nm. The effects of the excitation wavelength, growth temperature of ZnS films, PS porosity and annealing temperature on the PL spectra of ZnS/PS were also investigated.

Mid-infrared supercontinuum generation in a suspended core chalcogenide fiber

DEFF Research Database (Denmark)

Møller, Uffe Visbech; Yu, Yi; Gai, Xin

The mid-infrared spectral region is of great interest because virtually all organic compounds display distinctive spectral fingerprints herein that reveal chemical information about them [1], and the mid-infrared region is therefore of key importance to many applications, including food quality...... control [2], gas sensing [3] and medical diagnostics [4] . We have used a low-loss suspended core As 38 Se 62 fiber with core diameter of 4.5 μ m and a zero - dispersion wavelength of 3.5 μ m to generate mid-infrared supercontinuum by pumping with an optical parametric amplifier delivering 320 fs pulses...... with a peak power of ~5.5 kW at a repetition rate of 21 MHz at different wavelengths from 3.3 to 4.7 μ m . By pumping at 4.4 μ m with a peak power of 5.2 kW coupled to the fiber a supercontinuum spanning from 1.7 to 7.5 μ m with an average output power of 15.6 mW was obtained. Figure 1 shows the results...

Supporting Information Blue and White light electroluminescence in ...

Indian Academy of Sciences (India)

Administrator

Blue and White light electroluminescence in a multilayer OLED using a new Aluminium complex. Pabitra K. Nayak a. , Neeraj Agarwal a. , Farman Ali a. , Meghan P. Patankar b. , K. L.. Narasimhan b. *, N. Periasamy a. *. 1. Department of Chemical Sciences,. 2. Department of Condensed Matter Physics and. Materials ...

High-efficiency white organic light-emitting diodes using thermally activated delayed fluorescence

International Nuclear Information System (INIS)

Nishide, Jun-ichi; Hiraga, Yasuhide; Nakanotani, Hajime; Adachi, Chihaya

2014-01-01

White organic light-emitting diodes (WOLEDs) have attracted much attention recently, aimed for next-generation lighting sources because of their high potential to realize high electroluminescence efficiency, flexibility, and low-cost manufacture. Here, we demonstrate high-efficiency WOLED using red, green, and blue thermally activated delayed fluorescence materials as emissive dopants to generate white electroluminescence. The WOLED has a maximum external quantum efficiency of over 17% with Commission Internationale de l'Eclairage coordinates of (0.30, 0.38).

High-flux focusable color-tunable and efficient white-light-emitting diode light engine for stage lighting

DEFF Research Database (Denmark)

Chakrabarti, Maumita; Pedersen, Henrik Chresten; Petersen, Paul Michael

2016-01-01

colors through a microlens array(MA) at the gate of ∅50 mm. Hence, it produces homogeneous color-mixed tunable white light from 3000 to6000 K that can be adjustable from flood to spot position providing 10% translational loss, whereas the correspondingloss from the halogen–Fresnel spotlight is 37...

Surface Topology Reconstruction From The White Light Interferogram By Means Of Prony Analysis

Directory of Open Access Journals (Sweden)

Khoma Anna

2015-12-01

Full Text Available The paper presents a new method of surface topology reconstruction from a white light interferogram. The method is based on interferogram modelling by complex exponents (Prony method. The compatibility of white light interferogram and Prony models has already been proven. Effectiveness of the method was tested by modelling and examining reconstruction of tilted and spherical surfaces, and by estimating the reconstruction accuracy.

White organic light-emitting diodes from three emitter layers

Energy Technology Data Exchange (ETDEWEB)

Kim, M.S. [Department of Advanced Materials Science and Engineering, SungKyunKwan University, Suwon, Gyonggi-Do, 440-746 (Korea, Republic of); Lim, J.T. [Department of Advanced Materials Science and Engineering, SungKyunKwan University, Suwon, Gyonggi-Do, 440-746 (Korea, Republic of); Jeong, C.H. [Department of Advanced Materials Science and Engineering, SungKyunKwan University, Suwon, Gyonggi-Do, 440-746 (Korea, Republic of); Lee, J.H. [Department of Advanced Materials Science and Engineering, SungKyunKwan University, Suwon, Gyonggi-Do, 440-746 (Korea, Republic of); Yeom, G.Y. [Department of Advanced Materials Science and Engineering, SungKyunKwan University, Suwon, Gyonggi-Do, 440-746 (Korea, Republic of)]. E-mail: gyyeom@skku.edu

2006-11-23

Three-wavelength white organic light-emitting diodes (WOLEDs) were fabricated using two doped layers, which were obtained by separating the recombination zones into three emitter layers. A sky blue emission originated from the 4,4'-bis(2,2'-diphenylethen-1-yl)biphenyl (DPVBi) layer. A green emission originated from a tris(8-quinolinolato)aluminum (III) (Alq{sub 3}) host doped with a green fluorescent 10-(2-benzothiazolyl)-1,1,7,7-tetramethyl-2,3,6,7-tetrahydro-1H,5H,11H-[1] benz opyrano [6,7,8-ij]-quinolizin-11-one (C545T) dye. An orange emission was obtained from the N,N'-bis(1-naphthyl)-N,N'-diphenyl-1,1'-biphenyl-4,4'-diamine (NPB) host doped with a red fluorescent dye, 4-(dicyanomethylene)-2-tert-butyl-6-(1,1,7,7-tetramethyljulolidyl-9-enyl)-4 H-pyran (DCJTB). A white light resulted from the partial excitations of these three emitter layers by controlling the layer thickness and concentration of the fluorescent dyes in each emissive layer simultaneously. The electroluminescent spectrum of the device was not sensitive to the driving voltage of the device. The white light device showed a maximum luminance of approximately 53,000 cd/m{sup 2}. The external quantum and power efficiency at a luminance of approximately 100 cd/m{sup 2} were 2.62% and 3.04 lm/W, respectively.

Efficient white organic light emission by single emitting layer

Energy Technology Data Exchange (ETDEWEB)

Ko, Young Wook; Chung, Choong-Heui; Lee, Jin Ho; Kim, Yong-Hae; Sohn, Choong-Yong; Kim, Bong-Chul; Hwang, Chi-Sun; Song, Yoon-Ho; Lim, Jongtae; Ahn, Young-Joo; Kang, Gi-Wook; Lee, Namheon; Lee, Changhee

2003-02-24

Stable organic white light-emitting diodes are successfully fabricated by a single organic white emitting layer, which is Bis (2-methyl-8-quinolinato) (triphenylsiloxy) aluminum (III) (SAlq) doped red fluorescent dye of 4-(dicyanomethylene)-2-tert-butyl-6(1,1,7,7-tetramethyljulolidyl-9-enyl)- 4H-pyran (DCJTB). The incomplete energy transfer from blue-emitting SAlq to red-emitting DCJTB enables to obtain a stable white balanced light-emission by the DCJTB doping concentration of 0.5%. A device with the structure of ITO/TPD (50 nm)/SAlq:DCJTB (30 nm, 0.5%)/Alq{sub 3} (20 nm)/LiF (0.5 nm)/Al (110 nm) shows maximum luminance of 20 400 cd/m{sup 2} at 810 mA/cm{sup 2}, external quantum efficiency of 2% at 200 cd/m{sup 2} ({approx}3 mA/cm{sup 2}), power efficiency of 2.3 lm/W at 67 cd/m{sup 2} ({approx}1 mA/cm{sup 2}), and a Commission Internationale de l'Eclairage chromaticity coordinates of (0.34, 0.39) at 1.8 mA/cm{sup 2} to (0.31, 0.38) at 36 mA/cm{sup 2}.

Vibration compensated high-resolution scanning white-light Linnik-interferometer

Science.gov (United States)

Tereschenko, Stanislav; Lehmann, Peter; Gollor, Pascal; Kuehnhold, Peter

2017-06-01

We present a high-resolution Linnik scanning white-light interferometer (SWLI) with integrated distance measuring interferometer (DMI) for close-to-machine applications in the presence of environmental vibrations. The distance, measured by DMI during the depth-scan, is used for vibration compensation of SWLI signals. The reconstruction of the white-light interference signals takes place after measurement by reordering the captured images in accordance with their real positions obtained by the DMI and subsequent trigonometrical approximation. This system is the further development of our previously presented Michelson-interferometer. We are able to compensate for arbitrary vibrations with frequencies up to several kilohertz and amplitudes in the lower micrometer range. Completely distorted SWLI signals can be reconstructed and the surface topography can be obtained with high accuracy. We demonstrate the feasibility of the method by examples of practical measurements with and without vibrational disturbances.

Filament-induced luminescence and supercontinuum generation in undoped, Yb-doped, and Nd-doped YAG crystals

Science.gov (United States)

Kudarauskas, D.; Tamošauskas, G.; Vengris, M.; Dubietis, A.

2018-01-01

We present a comparative spectral study of filament-induced luminescence and supercontinuum generation in undoped, Yb-doped, and Nd-doped YAG crystals. We show that supercontinuum spectra generated by femtosecond filamentation in undoped and doped YAG crystals are essentially identical in terms of spectral extent. On the other hand, undoped and doped YAG crystals exhibit remarkably different filament-induced luminescence spectra whose qualitative features are independent of the excitation wavelength and provide information on the energy deposition to embedded dopants, impurities, and the crystal lattice itself. Our findings suggest that filament-induced luminescence may serve as a simple and non-destructive tool for spectroscopic studies in various transparent dielectric media.

Zinc oxide nanorods/polymer hybrid heterojunctions for white light emitting diodes

Science.gov (United States)

Willander, M.; Nur, O.; Zaman, S.; Zainelabdin, A.; Bano, N.; Hussain, I.

2011-06-01

Zinc oxide (ZnO) with its deep level defect emission covering the whole visible spectrum holds promise for the development of intrinsic white lighting sources with no need of using phosphors for light conversion. ZnO nanorods (NRs) grown on flexible plastic as substrate using a low temperature approach (down to 50 °C) were combined with different organic semiconductors to form hybrid junction. White electroluminescence (EL) was observed from these hybrid junctions. The configuration used for the hybrid white light emitting diodes (LEDs) consists of two-layers of polymers on the flexible plastic with ZnO NRs on the top. The inorganic/organic hybrid heterojunction has been fabricated by spin coating the p-type polymer poly (3,4-ethylenedioxythiophene) poly(styrenesulfonate) (PEDOT : PSS) for hole injection with an ionization potential of 5.1 eV and poly(9, 9-dioctylfluorene) (PFO) is used as blue emitting material with a bandgap of 3.3 eV. ZnO NRs are grown on top of the organic layers. Two other configurations were also fabricated; these are using a single MEH PPV (red-emitting polymer) instead of the PFO and the third configuration was obtained from a blend of the PFO and the MEH PPV. The white LEDs were characterized by scanning electron microscope, x-ray diffraction (XRD), current-voltage (I-V) characteristics, room temperature photoluminescence (PL) and EL. The EL spectrum reveals a broad emission band covering the range from 420 to 800 nm, and the emissions causing this white luminescence were identified.

Zinc oxide nanorods/polymer hybrid heterojunctions for white light emitting diodes

International Nuclear Information System (INIS)

Willander, M; Nur, O; Zaman, S; Zainelabdin, A; Bano, N; Hussain, I

2011-01-01

Zinc oxide (ZnO) with its deep level defect emission covering the whole visible spectrum holds promise for the development of intrinsic white lighting sources with no need of using phosphors for light conversion. ZnO nanorods (NRs) grown on flexible plastic as substrate using a low temperature approach (down to 50 0 C) were combined with different organic semiconductors to form hybrid junction. White electroluminescence (EL) was observed from these hybrid junctions. The configuration used for the hybrid white light emitting diodes (LEDs) consists of two-layers of polymers on the flexible plastic with ZnO NRs on the top. The inorganic/organic hybrid heterojunction has been fabricated by spin coating the p-type polymer poly (3,4-ethylenedioxythiophene) poly(styrenesulfonate) (PEDOT : PSS) for hole injection with an ionization potential of 5.1 eV and poly(9, 9-dioctylfluorene) (PFO) is used as blue emitting material with a bandgap of 3.3 eV. ZnO NRs are grown on top of the organic layers. Two other configurations were also fabricated; these are using a single MEH PPV (red-emitting polymer) instead of the PFO and the third configuration was obtained from a blend of the PFO and the MEH PPV. The white LEDs were characterized by scanning electron microscope, x-ray diffraction (XRD), current-voltage (I-V) characteristics, room temperature photoluminescence (PL) and EL. The EL spectrum reveals a broad emission band covering the range from 420 to 800 nm, and the emissions causing this white luminescence were identified.

Thermal, optical, and electrical engineering of an innovative tunable white LED light engine

Science.gov (United States)

Trivellin, Nicola; Meneghini, Matteo; Ferretti, Marco; Barbisan, Diego; Dal Lago, Matteo; Meneghesso, Gaudenzio; Zanoni, Enrico

2014-02-01

Color temperature, intensity and blue spectrum of the light affects the ganglion receptors in human brain stimulating the human nervous system. With this work we review different methods for obtaining tunable light emission spectra and propose an innovative white LED lighting system. By an in depth study of the thermal, electrical and optical characteristics of GaN and GaP based compound semiconductors for optoelectronics a specific tunable spectra has been designed. The proposed tunable white LED system is able to achieve high CRI (above 95) in a large CCT range (3000 - 5000K).

Evaluation of anogenital injuries using white and UV-light among adult volunteers following consensual sexual intercourse.

Science.gov (United States)

Joki-Erkkilä, Minna; Rainio, Juha; Huhtala, Heini; Salonen, Aki; Karhunen, Pekka J

2014-09-01

New clinical forensic examination techniques for sexual assaults have not been introduced over the last few decades. We evaluated the benefit of ultraviolet light compared to white light for detecting minor anogenital injuries and scars, following consensual sexual intercourse among adult volunteers. A prospective study comparing female genital findings utilising white and ultraviolet light. A colposcopy with photographic documentation was used. Personal invitation to healthcare students, hospital employees or acquaintances to volunteer for a gynecological examination, with a focus on clinical forensic aspects. Eighty-eight adult female volunteers were recruited for the study. The examination was performed after consensual intercourse. Age ranged from 20 to 52 years (median 26.5 years). Presence of acute findings and scars in the genital area using white and UV-light. Acute genital injury rate was 14.8% under white light colposcopy and 23.0% using UV light. Submucosal hemorrhages in the genital area were documented significantly better under UV-light than white light (14.9% vs. 6.8%; p=0.016), whereas petechiaes (4.5%) and abrasions (2.3%) were detected using either method. UV-light revealed significantly more often delivery-associated genital scars compared to white light (39.8% vs. 31.8%; p=0.016). Furthermore, 10 out of 31 (33.3%) women had no residual anogenital skin or mucosal surface findings, despite a prior episiotomy or rupture of the vaginal outlet wall during delivery, supporting its enormous ability to heal even after major trauma. UV-light may provide additional value for the evaluation of physical findings in clinical forensic examinations after sexual assault, and is especially useful in detecting otherwise invisible early submucosal hemorrhages and scars. Copyright © 2014 Elsevier Ireland Ltd. All rights reserved.

Invariable optical properties of phosphor-free white light-emitting diode under electrical stress

International Nuclear Information System (INIS)

Hao, Long; Hao, Fang; Sheng-Li, Qi; Li-Wen, Sang; Wen-Yu, Cao; Jian, Yan; Jun-Jing, Deng; Zhi-Jian, Yang; Guo-Yi, Zhang

2010-01-01

This paper reports that a dual-wavelength white light-emitting diode is fabricated by using a metal-organic chemical vapor deposition method. Through a 200-hours' current stress, the reverse leakage current of this light-emitting diode increases with the aging time, but the optical properties remained unchanged despite the enhanced reverse leakage current. Transmission electron microscopy and cathodeluminescence images show that indium atoms were assembled in and around V-shape pits with various compositions, which can be ascribed to the emitted white light. Evolution of cathodeluminescence intensities under electron irradiation is also performed. Combining cathodeluminescence intensities under electron irradiation and above results, the increase of leakage channels and crystalline quality degradation are realized. Although leakage channels increase with aging, potential fluctuation caused by indium aggregation can effectively avoid the impact of leakage channels. Indium aggregation can be attributed to the mechanism of preventing optical degradation in phosphor-free white light-emitting diode. (condensed matter: electronic structure, electrical, magnetic, and optical properties)

GATEWAY Report Brief: Tunable-White Lighting at the ACC Care Center

Energy Technology Data Exchange (ETDEWEB)

None, None

2016-09-30

Summary of a GATEWAY program report that documented the performance of tunable-white LED lighting systems installed in several spaces within the ACC Care Center, a senior-care facility in Sacramento, CA. The project results included energy savings and improved lighting quality, as well as other possible health-related benefits that may have been attributable, at least in part, to the lighting changes.

Flat super-continuum generation based on normal dispersion nonlinear photonic crystal fibre

DEFF Research Database (Denmark)

Chow, K.K.; Takushima, Y.; Lin, C.

2006-01-01

Flat super-continuum generation spanning over the whole telecommunication band using a passively modelocked fibre laser source at 1550 nm together with a dispersion-flattened nonlinear photoinc crystal fibre is demonstrated. Since the pulses propagate in the normal dispersion regime of the fibre...

Mid-infrared supercontinuum generation spanning more than 11 μm in a chalcogenide step-index fiber

DEFF Research Database (Denmark)

Petersen, Christian Rosenberg; Møller, Uffe Visbech; Kubat, Irnis

2015-01-01

Supercontinuum generation covering an ultra-broad spectrum from 1.5-11.7μm and 1.4-13.3μm is experimentally demonstrated by pumping an 85mm chalcogenide step-index fiber with 100fs pulses at a wavelength of 4.5μm and 6.3μm, respectively.......Supercontinuum generation covering an ultra-broad spectrum from 1.5-11.7μm and 1.4-13.3μm is experimentally demonstrated by pumping an 85mm chalcogenide step-index fiber with 100fs pulses at a wavelength of 4.5μm and 6.3μm, respectively....

Flat Supercontinuum Generation within the Telecommunication Wave Bands in a Photonic Crystal Fiber with Central Holes

International Nuclear Information System (INIS)

Han Ying; Hou Lan-Tian; Zhou Gui-Yao; Xia Chang-Ming; Wang Wei; Wang Chao; Hou Zhi-Yun; Yuan Jin-Hui

2012-01-01

Flat supercontinuum in the telecommunication wave bands of E+S+C is generated by coupling a train of femtosecond pulses generated by a mode-locked Ti:sapphire laser into the fundamental mode of a photonic crystal fiber with central holes fabricated in our lab. The pulse experiences the anomalous dispersion regime, and the soliton dynamic effect plays an important role in supercontinuum generation. The output spectrum in the wavelength range of 1360–1565 nm does not include significant ripples due to higher pump peak power, and the normalized intensity shows less fluctuation. (fundamental areas of phenomenology(including applications))

Tuning the white light spectrum of light emitting diode lamps to reduce attraction of nocturnal arthropods.

Science.gov (United States)

Longcore, Travis; Aldern, Hannah L; Eggers, John F; Flores, Steve; Franco, Lesly; Hirshfield-Yamanishi, Eric; Petrinec, Laina N; Yan, Wilson A; Barroso, André M

2015-05-05

Artificial lighting allows humans to be active at night, but has many unintended consequences, including interference with ecological processes, disruption of circadian rhythms and increased exposure to insect vectors of diseases. Although ultraviolet and blue light are usually most attractive to arthropods, degree of attraction varies among orders. With a focus on future indoor lighting applications, we manipulated the spectrum of white lamps to investigate the influence of spectral composition on number of arthropods attracted. We compared numbers of arthropods captured at three customizable light-emitting diode (LED) lamps (3510, 2704 and 2728 K), two commercial LED lamps (2700 K), two commercial compact fluorescent lamps (CFLs; 2700 K) and a control. We configured the three custom LEDs to minimize invertebrate attraction based on published attraction curves for honeybees and moths. Lamps were placed with pan traps at an urban and two rural study sites in Los Angeles, California. For all invertebrate orders combined, our custom LED configurations were less attractive than the commercial LED lamps or CFLs of similar colour temperatures. Thus, adjusting spectral composition of white light to minimize attracting nocturnal arthropods is feasible; not all lights with the same colour temperature are equally attractive to arthropods. © 2015 The Author(s) Published by the Royal Society. All rights reserved.

Broadband mid-infrared supercontinuum generation in novel As2Se3-As2Se2 S step-index fibers

Science.gov (United States)

Wang, Yingying; Dai, Shixun; Han, Xin; Zhang, Peiqing; Liu, Yongxing; Wang, Xunsi; Sun, Shaochao

2018-03-01

We experimentally demonstrate the mid-infrared supercontinuum generation in a chalcogenide step-index fiber consisting of an As2Se3 core and an As2Se2 S cladding. The fiber with the core diameter of 21 μm was fabricated through the rod-in-tube technique and fiber-drawing process. The effect of pump wavelength, fiber length, and pump power on the spectral bandwidth and output power of the supercontinuum spectra generated from the fiber pumped by the ultrashort pulses of ∼ 150 fs with a repetition rate of 1000 Hz was systematically investigated. When pumping a 12-cm-long fiber at a wavelength of 6 . 5 μm with 14 mW pump laser power, a broadband supercontinuum spanning from 2 . 0 μm to 12 . 7 μm with an output power of 300 μW was obtained.

Highly efficient phosphor-converted white organic light-emitting diodes with moderate microcavity and light-recycling filters.

Science.gov (United States)

Cho, Sang-Hwan; Oh, Jeong Rok; Park, Hoo Keun; Kim, Hyoung Kun; Lee, Yong-Hee; Lee, Jae-Gab; Do, Young Rag

2010-01-18

We demonstrate the combined effects of a microcavity structure and light-recycling filters (LRFs) on the forward electrical efficiency of phosphor-converted white organic light-emitting diodes (pc-WOLEDs). The introduction of a single pair of low- and high-index layers (SiO(2)/TiO(2)) improves the blue emission from blue OLED and the insertion of blue-passing and yellow-reflecting LRFs enhances the forward yellow emission from the YAG:Ce(3+) phosphors layers. The enhancement of the luminous efficacy of the forward white emission is 1.92 times that of a conventional pc-WOLED with color coordinates of (0.34, 0.34) and a correlated color temperature of about 4800 K.

Nanopatterned yttrium aluminum garnet phosphor incorporated film for high-brightness GaN-based white light emitting diodes

International Nuclear Information System (INIS)

Cho, Joong-yeon; Park, Sang-Jun; Ahn, Jinho; Lee, Heon

2014-01-01

In this study, we fabricated high-brightness white light emitting diodes (LEDs) by developing a nanopatterned yttrium aluminum garnet (YAG) phosphor-incorporated film. White light can be obtained by mixing blue light from a GaN-based LED and yellow light of the YAG phosphor-incorporated film. If white light sources can be fabricated by exciting proper yellow phosphor using blue light, then these sources can be used instead of the conventional fluorescent lamps with a UV source, for backlighting of displays. In this work, a moth-eye structure was formed on the YAG phosphor-incorporated film by direct spin-on glass (SOG) printing. The moth-eye structures have been investigated to improve light transmittance in various optoelectronic devices, including photovoltaic solar cells, light emitting diodes, and displays, because of their anti-reflection property. Direct SOG printing, which is a simple, easy, and relatively inexpensive process, can be used to fabricate nanoscale structures. After direct SOG printing, the moth-eye structure with a diameter of 220 nm was formed uniformly on the YAG phosphor-incorporated film. As a result of moth-eye patterning on the YAG phosphor-incorporated film, the light output power of a white LED with a patterned YAG phosphor-incorporated film increased to up to 13% higher than that of a white LED with a non-patterned film. - Highlights: • GaN-based high-brightness white LED was prepared using patterned YAG phosphor-incorporated films. • Direct hydrogen silsesquioxane printing was used to form moth-eye patterns on the YAG films. • The electroluminescence intensity of the white LED was enhanced by up to 14.9%

Nanopatterned yttrium aluminum garnet phosphor incorporated film for high-brightness GaN-based white light emitting diodes

Energy Technology Data Exchange (ETDEWEB)

Cho, Joong-yeon; Park, Sang-Jun [Department of Materials Science and Engineering, Korea University, Seoul 136-713 (Korea, Republic of); Ahn, Jinho, E-mail: jhahn@hanyang.ac.kr [Department of Material Science and Engineering, Hanyang University, Seoul 133-791 (Korea, Republic of); Lee, Heon, E-mail: heonlee@korea.ac.kr [Department of Materials Science and Engineering, Korea University, Seoul 136-713 (Korea, Republic of)

2014-11-03

In this study, we fabricated high-brightness white light emitting diodes (LEDs) by developing a nanopatterned yttrium aluminum garnet (YAG) phosphor-incorporated film. White light can be obtained by mixing blue light from a GaN-based LED and yellow light of the YAG phosphor-incorporated film. If white light sources can be fabricated by exciting proper yellow phosphor using blue light, then these sources can be used instead of the conventional fluorescent lamps with a UV source, for backlighting of displays. In this work, a moth-eye structure was formed on the YAG phosphor-incorporated film by direct spin-on glass (SOG) printing. The moth-eye structures have been investigated to improve light transmittance in various optoelectronic devices, including photovoltaic solar cells, light emitting diodes, and displays, because of their anti-reflection property. Direct SOG printing, which is a simple, easy, and relatively inexpensive process, can be used to fabricate nanoscale structures. After direct SOG printing, the moth-eye structure with a diameter of 220 nm was formed uniformly on the YAG phosphor-incorporated film. As a result of moth-eye patterning on the YAG phosphor-incorporated film, the light output power of a white LED with a patterned YAG phosphor-incorporated film increased to up to 13% higher than that of a white LED with a non-patterned film. - Highlights: • GaN-based high-brightness white LED was prepared using patterned YAG phosphor-incorporated films. • Direct hydrogen silsesquioxane printing was used to form moth-eye patterns on the YAG films. • The electroluminescence intensity of the white LED was enhanced by up to 14.9%.

Mid-infrared fiber-coupled supercontinuum spectroscopic imaging using a tapered chalcogenide photonic crystal fiber

Science.gov (United States)

Rosenberg Petersen, Christian; Prtljaga, Nikola; Farries, Mark; Ward, Jon; Napier, Bruce; Lloyd, Gavin Rhys; Nallala, Jayakrupakar; Stone, Nick; Bang, Ole

2018-02-01

We present the first demonstration of mid-infrared spectroscopic imaging of human tissue using a fiber-coupled supercontinuum source spanning from 2-7.5 μm. The supercontinuum was generated in a tapered large mode area chalcogenide photonic crystal fiber in order to obtain broad bandwidth, high average power, and single-mode output for good imaging properties. Tissue imaging was demonstrated in transmission by raster scanning over a sub-mm region of paraffinized colon tissue on CaF2 substrate, and the signal was measured using a fiber-coupled grating spectrometer. This demonstration has shown that we can distinguish between epithelial and surrounding connective tissues within a paraffinized section of colon tissue by imaging at discrete wavelengths related to distinct chemical absorption features.

White polymer light-emitting diode based on polymer blending

International Nuclear Information System (INIS)

Lee, Yong Kyun; Kwon, Soon Kab; Kim, Jun Young; Park, Tae Jin; Song, Dae Ho; Kwon, Jang Hyuk; Choo, Dong Jun; Jang, Jin; Jin, Jae Kyu; You, Hong

2006-01-01

A series of white polymer light emitting devices have been fabricated by using a polymer blending system of polyfluorene-based blue and MEH-PPV red polymers. A device structure of ITO/PEDOT:PSS/polymer/LiF/Al was employed. The white polymer device exhibited a current efficiency of 4.33 cd/A (4,816 cd/m 2 , Q.E. = 1.9 %) and a maximum luminance of 21,430 cd/m 2 at 9.2 V. The CIE coordinates were (0.35, 0.37) at 5 V and (0.29, 0.30) at 9 V.

White-light emission from porous-silicon-aluminium Schottky junctions

International Nuclear Information System (INIS)

Masini, G.; La Monica, S.; Maiello, G.

1996-01-01

Porous-silicon-based white-light-emitting devices are presented. The fabrication process on different substrates is described. The peculiarities of technological steps for device fabrication (porous-silicon formation and aluminium treatment) are underlined. Doping profile of the porous layer, current-voltage characteristics, time response, lifetime tests and electroluminescence emission spectrum of the device are presented. A model for electrical behaviour of Al/porous silicon Schottky junction is presented. Electroluminescence spectrum of the presented devices showed strong similarities with white emission from crystalline silicon junctions in the breakdown region

Effect of initial chirp on near-infrared supercontinuum generation by a nanosecond pulse in a nonlinear fiber amplifier

International Nuclear Information System (INIS)

Song Rui; Hou Jing; Wang Ze-Feng; Lu Qi-Sheng; Xiao Rui

2013-01-01

Theoretical and experimental research on the effect of initial chirp on near-infrared supercontinuum generation by a nanosecond pulse in a nonlinear fiber amplifier is carried out. The complex Ginzburg—Landau equation is used to simulate the propagation of the pulse in the fiber amplifier and the results show that pulses with negative initial chirp produce the widest supercontinuum and pulses with positive initial chirp produce the narrowest supercontinuum when the central wavelength of the pump lies in the normal dispersion region of the gain fiber. A self-made line width narrowing system is utilized to control the initial chirp of the nanosecond pump pulse and a four-stage master oscillator power amplifier configuration is adopted to produce a high power near-infrared suppercontinuum. The experimental results are in good agreement with simulations which can provide some guidance on further optimization of the system in future work. (electromagnetism, optics, acoustics, heat transfer, classical mechanics, and fluid dynamics)

Semiconductive 3-D haloplumbate framework hybrids with high color rendering index white-light emission.

Science.gov (United States)

Wang, Guan-E; Xu, Gang; Wang, Ming-Sheng; Cai, Li-Zhen; Li, Wen-Hua; Guo, Guo-Cong

2015-12-01

Single-component white light materials may create great opportunities for novel conventional lighting applications and display systems; however, their reported color rendering index (CRI) values, one of the key parameters for lighting, are less than 90, which does not satisfy the demand of color-critical upmarket applications, such as photography, cinematography, and art galleries. In this work, two semiconductive chloroplumbate (chloride anion of lead(ii)) hybrids, obtained using a new inorganic-organic hybrid strategy, show unprecedented 3-D inorganic framework structures and white-light-emitting properties with high CRI values around 90, one of which shows the highest value to date.

Controlled light emission from white organic light-emitting devices with a single blue-emitting host and multiple fluorescent dopants

International Nuclear Information System (INIS)

Chin, Byung Doo; Kim, Jai Kyeong; Park, O Ok

2007-01-01

In this work, we fabricated white organic light-emitting devices (WOLEDs) containing a layered light-emitting region composed of a single blue-emitting host and different fluorescent dopant materials. The effects of varying the dye-doping ratio and emitting layer thickness on the efficiency, lifetime, spectral voltage-dependence and white balance were investigated for devices with a blue/orange stacked layer structure. Addition of a blue host layer doped with a green-emitting dopant, to give a blue/green/orange emitter, resulted in a broadband white spectrum without the need for a charge-blocking interlayer. The composition of blue, green and orange dopants in the host and the thickness of each emitting layer were optimized, resulting in a device efficiency of 9-11 cd A -1 even at a high brightness of 10 000 cd m -2 (achieved at a bias voltage of less than 9 V) with an emission spectrum suitable for lighting applications

Adjusting White OLEDs with Yellow Light Emission Phosphor Dye and Ultrathin NPB Layer Structure

Directory of Open Access Journals (Sweden)

Jun Wang

2013-01-01

Full Text Available High efficiency white organic light emission devices were demonstrated with phosphor material dye bis[2-(4-tertbutylphenylbenzothiazolato-N,C2′]iridium (acetylacetonate and ultrathin layer structure. The ultra thin layer be composed of 4,4′-bis[N-1-naphthyl-N-phenyl-amino]biphenyl (NPB or 4,4′-N,N′-dicarbazole-biphenyl : NPB mixed layer with blue light emission. The emission spectra of devices could be adjusted by different phosphor doping concentrations and ultra thin layer structure. Warm white light emitting device could be obtained with 5 wt% doping concentration and power efficiency of 9.93 lm/W at 5 V. Pure white light with Commission Internationale de l'Eclairage (CIE coordinates of (0.33, 0.30 and external quantum efficiency of 4.49% could be achieved with ultra thin layer device structure and 3 wt% phosphor doped device.

Wide-band fanned-out supercontinuum source covering O-, E-, S-, C-, L- and U-bands

Science.gov (United States)

Ahmad, H.; Latif, A. A.; Awang, N. A.; Zulkifli, M. Z.; Thambiratnam, K.; Ghani, Z. A.; Harun, S. W.

2012-10-01

A wide-band supercontinuum source generated by mode-locked pulses injected into a Highly Non-Linear Fiber (HNLF) is proposed and demonstrated. A 49 cm long Bismuth-Erbium Doped Fiber (Bi-EDF) pumped by two 1480 nm laser diodes acts as the active gain medium for a ring fiber laser, from which mode-locked pulses are obtained using the Non-Polarization Rotation (NPR) technique. The mode-locked pulses are then injected into a 100 m long HLNF with a dispersion of 0.15 ps/nm km at 1550 nm to generate a supercontinuum spectrum spanning from 1340 nm to more than 1680 nm with a pulse width of 0.08 ps and an average power of -17 dBm. The supercontinuum spectrum is sliced using a 24 channel Arrayed Waveguide Grating (AWG) with a channel spacing of 100 GHz to obtain a fanned-out laser output covering the O-, E-, S-, C-, L- and U-bands. The lasing wavelengths obtained have an average pulse width of 9 ps with only minor fluctuations and a mode-locked repetition rate of 40 MHz, and is sufficiently stable to be used in a variety of sensing and communication applications, most notably as cost-effective sources for Fiber-to-the-Home (FTTH) networks.

High-efficient and brightness white organic light-emitting diodes operated at low bias voltage

Science.gov (United States)

Zhang, Lei; Yu, Junsheng; Yuan, Kai; Jian, Yadong

2010-10-01

White organic light-emitting diodes (OLEDs) used for display application and lighting need to possess high efficiency, high brightness, and low driving voltage. In this work, white OLEDs consisted of ambipolar 9,10-bis 2-naphthyl anthracene (ADN) as a host of blue light-emitting layer (EML) doped with tetrabutyleperlene (TBPe) and a thin codoped layer consisted of N, N'-bis(naphthalen-1-yl)-N,N'-bis(phenyl)-benzidine (NPB) as a host of yellow light-emitting layer doped with 4-(dicyanomethylene)-2-tert-butyl-6-(1,1,7,7-tetramethyljulolidin-4-yl-vinyl)-4H-pyran (DCJTB) were investigated. With appropriate tuning in the film thickness, position, and dopant concentration of the co-doped layer, a white OLED with a luminance yield of 10.02 cd/A with the CIE coordinates of (0.29, 0.33) has been achieved at a bias voltage of 9 V and a luminance level of over 10,000 cd/m2. By introducing the PIN structure with both HIL and bis(10- hydroxybenzo-quinolinato)-beryllium (BeBq2) ETL, the power efficiency of white OLED was improved.

Tunable and white light emitting AlPO4 mesoporous glass by design of inorganic/organic luminescent species

Directory of Open Access Journals (Sweden)

Jin He

2015-04-01

Full Text Available The realization of tunable and white light emitting sources employed by UV-LED with single-host phosphors has been an exciting development in the search for high luminous efficiency and excellent color rendering index white-light source. A tunable and white light emitting mesoporous glass was prepared by utilizing both inorganic/organic (Europium/coumarin luminescent species in the meso-structure. The tunable and white light emission was deliberately designed by CIE calculation based on the individual emission spectra, which was realized by tailoring the emission of Eu2+/Eu3+ ions and coumarin 535 in sol-gel AlPO4 mesoporous glass. This simple and versatile procedure is not limited in the combination of rare earth and organic dye and is therefore extendable to other luminescent species in meso-structure for color-tunable efficient solid-state lighting sources.

Flexible white phosphorescent organic light emitting diodes based on multilayered graphene/PEDOT:PSS transparent conducting film

Energy Technology Data Exchange (ETDEWEB)

Wu, Xiaoxiao; Li, Fushan, E-mail: fushanli@hotmail.com; Wu, Wei; Guo, Tailiang, E-mail: gtl_fzu@hotmail.com

2014-03-01

Highlights: • A double-layered graphene/PEDOT:PSS film was fabricated by spray-coating. • A white flexible phosphorescent OLED was fabricated based on this film. • The white flexible OLED presented pure white light emission. • The flexible OLEDs showed a stable white emission during bending test. - Abstract: A double-layered graphene/poly(3,4-ethylenedioxythiophene):poly(styrenesulfonate) (PEDOT:PSS) conductive film was prepared, in which the PEDOT:PSS layer was obtained by using spray-coating technique. A flexible white phosphorescent organic light-emitting devices based on the graphene/PEDOT:PSS conductive film was fabricated. Phosphorescent material tris(2-phenylpyridine) iridium (Ir(ppy){sub 3}) and the fluorescent dye 5,6,11,12-tetraphenylnapthacene (Rubrene) were co-doped into 4,4′-N,N′-dicarbazole-biphenyl (CBP) host. N,N′-diphenyl-N,N′-bis(1-naphthyl)-(1,1′-biphenyl)-4,4′-diamine (NPB) and 4,7-diphenyl-1,10-phenanthroline (Bphen) were used as hole-transporting and electron-transporting layer, respectively, and 4,4′-bis(2,2′-diphenylvinyl)-1,1′-biphenyl (DPVBi) was used as blue light-emitting layer. The device presented pure white light emission with a Commission Internationale De I’Eclairage coordinates of (0.31, 0.33) and exhibited an excellent light-emitting stability during the bending cycle test with a radius of curvature of 10 mm.

Flexible white phosphorescent organic light emitting diodes based on multilayered graphene/PEDOT:PSS transparent conducting film

International Nuclear Information System (INIS)

Wu, Xiaoxiao; Li, Fushan; Wu, Wei; Guo, Tailiang

2014-01-01

Highlights: • A double-layered graphene/PEDOT:PSS film was fabricated by spray-coating. • A white flexible phosphorescent OLED was fabricated based on this film. • The white flexible OLED presented pure white light emission. • The flexible OLEDs showed a stable white emission during bending test. - Abstract: A double-layered graphene/poly(3,4-ethylenedioxythiophene):poly(styrenesulfonate) (PEDOT:PSS) conductive film was prepared, in which the PEDOT:PSS layer was obtained by using spray-coating technique. A flexible white phosphorescent organic light-emitting devices based on the graphene/PEDOT:PSS conductive film was fabricated. Phosphorescent material tris(2-phenylpyridine) iridium (Ir(ppy) 3 ) and the fluorescent dye 5,6,11,12-tetraphenylnapthacene (Rubrene) were co-doped into 4,4′-N,N′-dicarbazole-biphenyl (CBP) host. N,N′-diphenyl-N,N′-bis(1-naphthyl)-(1,1′-biphenyl)-4,4′-diamine (NPB) and 4,7-diphenyl-1,10-phenanthroline (Bphen) were used as hole-transporting and electron-transporting layer, respectively, and 4,4′-bis(2,2′-diphenylvinyl)-1,1′-biphenyl (DPVBi) was used as blue light-emitting layer. The device presented pure white light emission with a Commission Internationale De I’Eclairage coordinates of (0.31, 0.33) and exhibited an excellent light-emitting stability during the bending cycle test with a radius of curvature of 10 mm

High efficient white organic light emitting diodes

Energy Technology Data Exchange (ETDEWEB)

Seidel, Stefan; Krause, Ralf [Department of Materials Science VI, University of Erlangen-Nuremberg (Germany); Siemens AG, CT MM 1, Erlangen (Germany); Kozlowski, Fryderyk; Schmid, Guenter; Hunze, Arvid [Siemens AG, CT MM 1, Erlangen (Germany); Winnacker, Albrecht [Department of Materials Science VI, University of Erlangen-Nuremberg (Germany)

2007-07-01

Due to the rapid progress in the last years the performance of organic light emitting diodes (OLEDs) has reached a level where general lighting presents a most interesting application target. We demonstrate, how the color coordinates of the emission spectrum can be adjusted using a combinatorial evaporation tool to lie on the desired black body curve representing cold and warm white, respectively. The evaluation includes phosphorescent and fluorescent dye approaches to optimize lifetime and efficiency, simultaneously. Detailed results are presented with respect to variation of layer thicknesses and dopant concentrations of each layer within the OLED stack. The most promising approach contains phosphorescent red and green dyes combined with a fluorescent blue one as blue phosphorescent dopants are not yet stable enough to achieve long lifetimes.

Effects of noise and parameter deviations in a bichromatic Raman white light cavity

International Nuclear Information System (INIS)

Sun Qingqing; Zubairy, M. Suhail; Shahriar, M. Selim

2010-01-01

We analyze the effects of noise and parameter deviations in a bichromatic Raman type white light cavity, with potential applications in precision measurements. The results show that the dispersion variation induced by parameter deviation can be controlled with an accuracy of 10 -4 . The laser phase noise decreases the dispersion magnitude while the amplitude noise increases it. Although we can always adjust the parameters to satisfy the white light condition, both types of noise make the cavity transmission curve uneven.

Single-phased CaAl2Si2O8:Tm3+, Dy3+ white-light phosphors under ultraviolet excitation

International Nuclear Information System (INIS)

Yang, Penghui; Yu, Xue; Xu, Xuhui; Jiang, Tingming; Yu, Hongling; Zhou, Dacheng; Yang, Zhengwen; Song, Zhiguo; Qiu, Jianbei

2013-01-01

A novel white-light-emitting phosphor CaAl 2 Si 2 O 8 :Tm, Dy was synthesized in ambient atmosphere by solid-state reaction. The energy transfer from Tm 3+ to Dy 3+ ions via a dipole–quadrupole reaction was observed and investigated. Upon UV excitation, white light emission was achieved by integrating a blue emission band located at 455 nm and an orange one located at 574 nm attributed to Tm 3+ and Dy 3+ ions, respectively. In addition, the energy-transfer efficiency and critical distance were calculated. Results suggested that the phosphor might be promising as a single-phased white-light-emitting phosphor for UV white-light LED. - Graphical abstract: The results indicate the existence of energy transfer from Tm 3+ to Dy 3+ . By tuning the concentration of Dy 3+ , single-phased white light can be realized. - Highlights: ► Energy transfer from Tm 3+ to Dy 3+ was investigated. ► Color tunable from blue to white can be achieved. ► White light can be realized in CaAl 2 Si 2 O 8 :Tm 3+ , Dy 3+ phosphor

Generation and Applications of High Average Power Mid-IR Supercontinuum in Chalcogenide Fibers

OpenAIRE

Petersen, Christian Rosenberg

2016-01-01

Mid-infrared supercontinuum with up to 54.8 mW average power, and maximum bandwidth of 1.77-8.66 μm is demonstrated as a result of pumping tapered chalcogenide photonic crystal fibers with a MHz parametric source at 4 μm

Fish freshness estimation using eye image processing under white and UV lightings

Science.gov (United States)

Kanamori, Katsuhiro; Shirataki, Yuri; Liao, Qiuhong; Ogawa, Yuichi; Suzuki, Tetsuhito; Kondo, Naoshi

2017-05-01

A non-destructive method of estimating the freshness of fish is required for appropriate price setting and food safety. In particular, for determining the possibility of eating raw fish (sashimi), freshness estimation is critical. We studied such an estimation method by capturing images of fish eyes and performing image processing using the temporal changes of the luminance of pupil and iris. To detect subtle non-visible changes of these features, we used UV (375 nm) light illumination in addition to visible white light illumination. Polarization and two-channel LED techniques were used to remove strong specular reflection from the cornea of the eye and from clear-plastic wrap used to cover the fish to maintain humidity. Pupil and iris regions were automatically detected separately by image processing after the specular reflection removal process, and two types of eye contrast were defined as the ratio of mean and median pixel values of each region. Experiments using 16 Japanese dace (Tribolodon hakonensis) at 23° and 85% humidity for 24 hours were performed. The eye contrast of raw fish increase non-linearly in the initial period and then decreased; however, that of frozen-thawed fish decreased linearly throughout 24 hours, regardless of the lighting. Interestingly, the eye contrast using UV light showed a higher correlation with time than that using white light only in the case of raw fish within the early 6- hour period postmortem. These results show the possibility of estimating fish freshness in the initial stage when fish are eaten raw using white and UV lightings.

High luminous flux from single crystal phosphor-converted laser-based white lighting system

KAUST Repository

Cantore, Michael

2015-12-14

The efficiency droop of light emitting diodes (LEDs) with increasing current density limits the amount of light emitted per wafer area. Since low current densities are required for high efficiency operation, many LED die are needed for high power white light illumination systems. In contrast, the carrier density of laser diodes (LDs) clamps at threshold, so the efficiency of LDs does not droop above threshold and high efficiencies can be achieved at very high current densities. The use of a high power blue GaN-based LD coupled with a single crystal Ce-doped yttrium aluminum garnet (YAG:Ce) sample was investigated for white light illumination applications. Under CW operation, a single phosphor-converted LD (pc-LD) die produced a peak luminous efficacy of 86.7 lm/W at 1.4 A and 4.24 V and a peak luminous flux of 1100 lm at 3.0 A and 4.85 V with a luminous efficacy of 75.6 lm/W. Simulations of a pc-LD confirm that the single crystal YAG:Ce sample did not experience thermal quenching at peak LD operating efficiency. These results show that a single pc-LD die is capable of emitting enough luminous flux for use in a high power white light illumination system.

Efficient polymer white-light-emitting diodes with a single-emission layer of fluorescent polymer blend

International Nuclear Information System (INIS)

Niu Qiaoli; Xu Yunhua; Jiang Jiaxing; Peng Junbiao; Cao Yong

2007-01-01

Efficient polymer white-light-emitting diodes (WPLEDs) have been fabricated with a single layer of fluorescent polymer blend. The device structure consists of ITO/PEDOT/PVK/emissive layer/Ba/Al. The emissive layer is a blend of poly(9,9-dioctylfluorene) (PFO), phenyl-substituted PPV derivative (P-PPV) and a copolymer of 9,9-dioctylfluorene and 4,7-di(4-hexylthien-2-yl)-2,1,3-benzothiadiazole (PFO-DHTBT), which, respectively, emits blue, green and red light. The emission of pure and efficient white light was implemented by tuning the blend weight ratio of PFO: P-PPV: PFO-DHTBT to 96:4:0.4. The maximum current efficiency and luminance are, respectively, 7.6 cd/A at 6.7 V and 11930 cd/m 2 at 11.2 V. The CIE coordinates of white-light emission were stable with the drive voltages

Efficient white organic light-emitting diodes based on an orange iridium phosphorescent complex

International Nuclear Information System (INIS)

Chen Ping; Zhao Li; Duan Yu; Zhao Yi; Xie Wenfa; Xie Guohua; Liu Shiyong; Zhang Liying; Li Bin

2011-01-01

Stable and efficient white light emission is obtained by mixing blue fluorescence and orange phosphorescence. The introduction of double exciton blocking layers brings about well confinement of both charge-carriers and excitons in the emission layer. By systematically adjusting blue fluorescent and orange phosphorescent emission layers thickness, carriers in emission zone are balanced, and electrically generated excitons can be efficiently utilized. One white device with power efficiency of 14.4 lm/W at 100 cd/m 2 has excellently stable spectra. The improvement of performance is attributed to efficient utilization of the excitons and more balance of charge-carriers in emission layer. - Highlights: → Stable and efficient white light emission is obtained by mixing blue fluorescence and orange phosphorescence. → White device has power efficiency of 14.4 and 10.1 lm/W obtained at 100 and 1000 cd/m 2 , respectively. → White device has excellently stable spectra over a wide range of luminance. → Singlet and triplet excitons are sufficiently utilized by fluorescent and phosphorescent materials.

Color improvement of white-light through Mn-enhancing yellow-green emission of SrSi2O2N2:Eu phosphor for white light emitting diodes

International Nuclear Information System (INIS)

Fei Qinni; Liu Yanhua; Gu Tiecheng; Wang Dajian

2011-01-01

Photoluminescence (PL) enhancement of SrSi 2 O 2 N 2 :Eu and the resultant color improvement of white-light were investigated via co-doping Mn with Eu. We observed that a unique absorption of host lattice of SrSi 2 O 2 N 2 and its visible band emission peaked at around ∼550 nm for SrSi 2 O 2 N 2 :Mn 2+ in the wavelength range of 450-600 nm. This highly eye-sensitive ∼550 nm-peaked band emission of SrSi 2 O 2 N 2 doped with Mn 2+ happens to overlap the 535 nm-peaked band emission of SrSi 2 O 2 N 2 doped with Eu 2+ , resulting in an intensified photoluminescence in a maximum by 355%. By combining this as-prepared Mn intensified SrSi 2 O 2 N 2 :Eu phosphor with blue InGaN chip, the quality of white-light was improved to 93.3% for color rendering index and 3584 K for correlated color temperature. - Research highlights: Photoluminescence enhancement and resultant color improvement of SrSi 2 O 2 N 2 : Eu can be adjusted via co-doping Mn with Eu. The band emission peaked at ∼550 for Mn2+ overlaps that at ∼535 nm for Eu 2+ . A white-light with 93.3% for CRI and 3584 K for CCT is achieved.

Color optimization of conjugated-polymer/InGaN hybrid white light emitting diodes by incomplete energy transfer

International Nuclear Information System (INIS)

Chang, Chi-Jung; Lai, Chun-Feng; Madhusudhana Reddy, P.; Chen, Yung-Lin; Chiou, Wei-Yung; Chang, Shinn-Jen

2015-01-01

By using the wavelength conversion method, white light emitting diodes (WLEDs) were produced by applying mixtures of polysiloxane and fluorescent polymers on InGaN based light emitting diodes. UV curable organic–inorganic hybrid materials with high refractive index (1.561), compromised optical, thermal and mechanical properties was used as encapsulants. Red light emitting fluorescent FABD polymer (with 9,9-dioctylfluorene (F), anthracene (A) and 2,1,3-benzothiadiazole (B), and 4,7-bis(2-thienyl)-2,1,3-benzothiadiazole (D) repeating units) and green light emitting fluorescent FAB polymer were used as wavelength converters. The encapsulant/fluorescent polymer mixture and InGaN produce the white light by incomplete energy transfer mechanism. WLEDs with high color rendering index (CRI, about 93), and tunable correlated color temperature (CCT) properties can be produced by controlling the composition and chemical structures of encapsulating polymer and fluorescent polymer in hybrid materials, offering cool-white and neutral-white LEDs. - Highlights: • Highly efficient white light-emitting diodes (WLEDs) were produced. • Conjugated-polymer/InGaN hybrid WLEDs by incomplete energy transfer mechanism. • WLEDs with high color-rendering index and tunable correlated color temperature. • Polysiloxane encapsulant with superior optical, mechanical and thermal properties

Electrochemical characterization of Si in tetra-methyl ammonium hydroxide (TMAH) and TMAH:Triton-X-100 solutions under white light effects

Science.gov (United States)

Conway, Elizabeth M.; Cunnane, Vincent J.

2002-03-01

An experimental study of the electrochemical characteristics of the silicon/tetra-methyl ammonium hydroxide (TMAH) junction under dark and white light conditions are investigated for both n- and p-type Si. The presence of Triton-X-100 (TX100) in the TMAH solution under white light conditions is also studied. Cyclic voltammetry (CV) and ex situ atomic force microscopy (AFM) are employed to study the white light effects on the etching characteristics of silicon in TMAH and TMAH:TX100. It was found that the passivation peak potential shifted significantly for both n- and p-type Si under white light conditions. The positions of the flatband potential for n- and p-type Si were predicted by CV under illumination. Finally, etch rate studies and preliminary surface roughness measurements were performed on p(100) Si in TMAH under both dark and white light conditions. These latter studies concluded that a reduction in the vertical surface roughness occurred in the presence of white light.

Two-octave mid-infrared supercontinuum generation in As-Se suspended core fibers

DEFF Research Database (Denmark)

Møller, Uffe Visbech; Petersen, Christian Rosenberg; Kubat, Irnis

2015-01-01

A more than two-octave mid-infrared supercontinuum with an average output power of 15.6 mW covering 1.7-7.5 μm (1,333-5,900 cm-1) is generated in a low-loss As38Se62 suspended core fiber with core diameter of 4.5 μm....

White emitting CdS quantum dot nanoluminophores hybridized on near-ultraviolet LEDs for high-quality white light generation and tuning

International Nuclear Information System (INIS)

Nizamoglu, Sedat; Mutlugun, Evren; Akyuz, Ozgun; Perkgoz, Nihan Kosku; Demir, Hilmi Volkan; Liebscher, Lydia; Sapra, Sameer; Gaponik, Nikolai; Eychmueller, Alexander

2008-01-01

To generate white light using semiconductor nanocrystal (NC) quantum dots integrated on light emitting diodes (LEDs), multiple hybrid device parameters (emission wavelengths of the NCs and the excitation platform, order of the NCs with different sizes, amount of the different types of NCs, etc) need to be carefully designed and properly implemented. In this study, we introduce and demonstrate white LEDs based on simple device hybridization using only a single type of white emitting CdS quantum dot nanoluminophores on near-ultraviolet LEDs. Here we present their design, synthesis-growth, fabrication and characterization. With these hybrid devices, we achieve high color rendering index (>70), despite using only a single NC type. Furthermore, we conveniently tune their photometric properties including the chromaticity coordinates, correlated color temperature, and color rendering index with the number of hybridized nanoluminophores in a controlled manner

Improvement of white organic light emitting diode performances by an annealing process

International Nuclear Information System (INIS)

Sepeai, Suhaila; Salleh, Muhamad Mat; Yahaya, Muhammad; Umar, Akrajas Ali

2009-01-01

White organic light emitting diode (OLED) devices with the structure ITO/PHF:rubrene/Al, in which PHF (poly(9,9-di-n-hexylfluorenyl-2,7-diyl)) is used as blue light emitting host and rubrene (5,6,11,12-tetraphenylnapthacene) as an orange dye dopant, have been fabricated. Indium tin oxide (ITO) coated-glass and aluminium were used as anode and cathode, respectively. The devices were fabricated with various rubrene-dopant to obtain a white light emission. The OLED device that composed of several concentrations of rubrene-doped PHF film was prepared in this study. It was found that the concentration of rubrene in the PHF-rubrene thin film matrix plays a key role in producing the white color emission. In a typical result, the device composed of 0.06 wt.% rubrene-dopant produced the white light emission with the Commission Internationale de L'Eclairage (CIE) coordinate of (0.30,0.33). The turn-on voltage and the brightness were found to be as low as 14.0 V and as high as 6540 cd/m 2 , respectively. The annealing technique at relatively low temperature (50 o C, 100 o C, and 150 o C) was then used to optimize the performance of the device. In a typical result, the turn-on voltage of the device could be successfully reduced and the brightness could be increased using the annealing technique. At an optimum condition, for example, annealed at 150 o C, the turn-on voltage as low as 8.0 V and the brightness as high as 9040 cd/m 2 were obtained. The mechanism for the improvement of the device performance upon annealing will be discussed.

White- and blue-light-emitting dysprosium(III) and terbium(III)-doped gadolinium titanate phosphors.

Science.gov (United States)

Antić, Ž; Kuzman, S; Đorđević, V; Dramićanin, M D; Thundat, T

2017-06-01

Here we report the synthesis and structural, morphological, and photoluminescence analysis of white- and blue-light-emitting Dy 3 + - and Tm 3 + -doped Gd 2 Ti 2 O 7 nanophosphors. Single-phase cubic Gd 2 Ti 2 O 7 nanopowders consist of compact, dense aggregates of nanoparticles with an average size of ~25 nm for Dy 3 + -doped and ~50 nm for Tm 3 + -doped samples. The photoluminescence results indicated that ultraviolet (UV) light excitation of the Dy 3 + -doped sample resulted in direct generation of white light, while a dominant yellow emission was obtained under blue-light excitation. Intense blue light was obtained for Tm 3 + -doped Gd 2 Ti 2 O 7 under UV excitation suggesting that this material could be used as a blue phosphor. Copyright © 2016 John Wiley & Sons, Ltd.

White organic light-emitting diodes based on electroplex from polyvinyl carbazole and carbazole oligomers blends

International Nuclear Information System (INIS)

Fei-Peng, Chen; Bin, Xu; Wen-Jing, Tian; Zu-Jin, Zhao; Ping, Lü; Chan, Im

2010-01-01

White organic light-emitting diodes with a blue emitting material fluorene-centred ethylene-liked carbazole oligomer (Cz6F) doped into polyvinyl carbazole (PVK) as the single light-emitting layer are reported. The optical properties of Cz6F, PVK, and PVK:Cz6F blends are studied. Single and double layer devices are fabricated by using PVK: Cz6F blends, and the device with the configuration of indium tin oxide (ITO)/PVK:Cz6F/tris(8-hydroxyquinolinate)aluminium (Alq 3 )/LiF/A1 exhibits white light emission with Commission Internationale de l'Éclairage chromaticity coordinates of (0.30, 0.33) and a brightness of 402 cd/m 2 . The investigation reveals that the white light is composed of a blue–green emission originating from the excimer of Cz6F molecules and a red emission from an electroplex from the PVK:Cz6F blend films

White organic light-emitting diodes based on electroplex from polyvinyl carbazole and carbazole oligomers blends

Science.gov (United States)

Chen, Fei-Peng; Xu, Bin; Zhao, Zu-Jin; Tian, Wen-Jing; Lü, Ping; Im, Chan

2010-03-01

White organic light-emitting diodes with a blue emitting material fluorene-centred ethylene-liked carbazole oligomer (Cz6F) doped into polyvinyl carbazole (PVK) as the single light-emitting layer are reported. The optical properties of Cz6F, PVK, and PVK:Cz6F blends are studied. Single and double layer devices are fabricated by using PVK: Cz6F blends, and the device with the configuration of indium tin oxide (ITO)/PVK:Cz6F/tris(8-hydroxyquinolinate)aluminium (Alq3)/LiF/A1 exhibits white light emission with Commission Internationale de l'Éclairage chromaticity coordinates of (0.30, 0.33) and a brightness of 402 cd/m2. The investigation reveals that the white light is composed of a blue-green emission originating from the excimer of Cz6F molecules and a red emission from an electroplex from the PVK:Cz6F blend films.

Broadening of white-light continuum by filamentation in BK7 glass at its zero-dispersion point

International Nuclear Information System (INIS)

Jiang, Jiaming; Zhong, Yue; Zheng, Yinghui; Zeng, Zhinan; Ge, Xiaochun; Li, Ruxin

2015-01-01

Broadening of white-light continuum is observed by filamentation of near-infrared femtosecond laser pulses with peak power exceeding the megawatt level in BK7 glass with the presence of the zero-dispersion point. The simulated results show that, due to the low dispersion at the zero-dispersion point, the broadening of white-light continuum can be wider and the filament can persist in propagating stably longer distance. - Highlights: • We observed the white-light continuum by filamentation at the zero-dispersion point. • Peak power significantly exceeding the critical value of self-focusing was used. • Wider spectral broadening was obtained around the zero-dispersion point

Effect of pulse width on near-infrared supercontinuum generation in nonlinear fiber amplifier

Science.gov (United States)

Song, Rui; Lei, Cheng-Min; Chen, Sheng-Ping; Wang, Ze-Feng; Hou, Jing

2015-08-01

The effect of pulse width on near-infrared supercontinuum generation in nonlinear fiber amplifier is investigated theoretically and experimentally. The complex Ginzburg-Landau equation and adaptive split-step Fourier method are used to simulate the propagation of pulses with different pulse widths in the fiber amplifier, and the results show that a longer pulse is more profitable in near-infrared supercontinuum generation if the central wavelength of the input laser lies in the normal dispersion region of the gain fiber. A four-stage master oscillator power amplifier configuration is adopted and the output spectra under picosecond and nanosecond input pulses are compared with each other. The experimental results are in good accordance with the simulations which can provide some guidance for further optimization of the system. Project supported by the National Natural Science Foundation of China (Grant Nos. 11404404 and 11274385) and the Outstanding Youth Fund Project of Hunan Province and the Fund of Innovation of National University of Defense Technology, China (Grant No. B120701).

Sculpting light for new biophotonics applications

DEFF Research Database (Denmark)

Glückstad, Jesper; Palima, Darwin; Villangca, Mark Jayson

illumination, optical phase encryption, and recently in contemporary biophotonics applications such as for real-time parallel twophoton optogenetics and neurophotonics [3]. Our most recent GPC light sculpting developments will be presented. These include both static and dynamic GPC Light Shapers where lasers......Generalized Phase Contrast (GPC) is a power efficient approach for generating speckle-free contiguous optical distributions using spatial phaseonly light modulation. GPC has been demonstrated in a variety of applications such as optical micro-manipulation [1], active microscopy [2], structured...... have to be actively shaped into particular light patterns [4]. We show the potential of GPC for biomedical and multispectral applications where we demonstrate phase-only light shaping of a supercontinuum laser over most of its visible wavelength range [5]....

The spectral analysis and threshold limits of quasi-supercontinuum self-assembled quantum dot interband lasers

KAUST Repository

Tan, Cheeloon; Wang, Yang; Djie, Hery Susanto; Ooi, Boon S.

2009-01-01

This paper presents a theoretical model to explain the quasi-supercontinuum interband emission from InGaAs/GaAs self-assembled semiconductor quantum dot lasers by accounting for both inhomogeneous and homogeneous optical gain broadening

Mercury in canned tuna: white versus light and temporal variation

International Nuclear Information System (INIS)

Burger, Joanna; Gochfeld, Michael

2004-01-01

There are abundant data and advisories for mercury levels in wild fish, but far fewer for commercial fish that compose a large majority of the fish most people eat. Until recently, relatively little attention has been devoted to examining mercury in canned tuna, despite its great importance in human diets. There is substantial media coverage of the benefits and risk from fish consumption, but few peer-reviewed data on canned tuna, the most commonly consumed fish in the United States. In this paper, we examine the levels of total mercury in canned tuna obtained from a New Jersey grocery store from 1998 to 2003, looking for temporal consistency within this data set and particularly for comparison with the Food and Drug Administration's 1991 study. We analyzed 168 cans individually for total mercury. All values are reported as parts per million (=μg/g) on a wet weight basis. In a subset of samples analyzed for total and inorganic mercury, the inorganic mercury was below detection levels; hence at least 89% of the mercury can be considered methylmercury. We found that white-style tuna had significantly more total mercury (mean 0.407 ppm) than light-style tuna (mean 0.118 ppm), presumably reflecting that 'white' tuna is albacore, a species relatively larger than the skipjack tuna, which is commonly available as 'light' or 'chunk light'. The maximum mercury in a can was 0.997 ppm, but 25% of white tuna samples exceeded 0.5 ppm. Data suggest a slight increase in levels since 1991, and mercury levels were significantly higher in 2001 than in other years. The mean level of mercury in white tuna (mean 0.407 ppm) was significantly higher than the mean value of 0.17 ppm currently used by the U.S. Food and Drug Administration (FDA) in its risk assessment and public information. There were no significant differences in mercury levels in tuna packed in oil compared to water. Draining contents had no effect on mercury levels, and the fluid, both oil and water, contained little

Optimal nitrogen and phosphorus codoping carbon dots towards white light-emitting device

Energy Technology Data Exchange (ETDEWEB)

Zhang, Feng; Wang, Yaling; Miao, Yanqin; Yang, Yongzhen, E-mail: yyztyut@126.com, E-mail: liuxuguang@tyut.edu.cn [Key Laboratory of Interface Science and Engineering in Advanced Materials, Taiyuan University of Technology, Ministry of Education, Taiyuan 030024 (China); Research Center on Advanced Materials Science and Technology, Taiyuan University of Technology, Taiyuan 030024 (China); He, Yuheng; Liu, Xuguang, E-mail: yyztyut@126.com, E-mail: liuxuguang@tyut.edu.cn [Key Laboratory of Interface Science and Engineering in Advanced Materials, Taiyuan University of Technology, Ministry of Education, Taiyuan 030024 (China); College of Chemistry and Chemical Engineering, Taiyuan University of Technology, Taiyuan 030024 (China)

2016-08-22

Through a one-step fast microwave-assisted approach, nitrogen and phosphorus co-doped carbon dots (N,P-CDs) were synthesized using ammonium citrate (AC) as a carbon source and phosphates as additive reagent. Under the condition of an optimal reaction time of 140 s, the influence of additive with different N and P content on fluorescent performance of N,P-CDs was further explored. It was concluded that high nitrogen content and moderate phosphorus content are necessary for obtaining high quantum yield (QY) N,P-CDs, among which the TAP-CDs (CDs synthesized using ammonium phosphate as additive reagent) show high quantum yield (QY) of 62% and red-green-blue (RGB) spectral composition of 51.67%. Besides, the TAP-CDs exhibit satisfying thermal stability within 180 °C. By virtue of good optical and thermal properties of TAP-CDs, a white light-emitting device (LED) was fabricated by combining ultraviolet chip with TAP-CDs as phosphor. The white LED emits bright warm-white light with the CIE chromaticity coordinate of (0.38, 0.35) and the corresponding color temperature (CCT) of 4450 K, indicating the potential of TAP-CDs phosphor in white LED.

Accelerated rogue waves generated by soliton fusion at the advanced stage of supercontinuum formation in photonic-crystal fibers.

Science.gov (United States)

Driben, Rodislav; Babushkin, Ihar

2012-12-15

Soliton fusion is a fascinating and delicate phenomenon that manifests itself in optical fibers in case of interaction between copropagating solitons with small temporal and wavelength separation. We show that the mechanism of acceleration of a trailing soliton by dispersive waves radiated from the preceding one provides necessary conditions for soliton fusion at the advanced stage of supercontinuum generation in photonic-crystal fibers. As a result of fusion, large-intensity robust light structures arise and propagate over significant distances. In the presence of small random noise the delicate condition for the effective fusion between solitons can easily be broken, making the fusion-induced giant waves a rare statistical event. Thus oblong-shaped giant accelerated waves become excellent candidates for optical rogue waves.

Improvement of white organic light emitting diode performances by an annealing process

Energy Technology Data Exchange (ETDEWEB)

Sepeai, Suhaila, E-mail: suhaila_sepeai@yahoo.co [Solar Energy Research Institute, Universiti Kebangsaan Malaysia, 43600 UKM Bangi Selangor (Malaysia); Salleh, Muhamad Mat, E-mail: mms@pkrisc.cc.ukm.m [Institute Of Microengineering And Nanoelectronic, Universiti Kebangsaan Malaysia, 43600 UKM Bangi Selangor (Malaysia); Yahaya, Muhammad; Umar, Akrajas Ali [Institute Of Microengineering And Nanoelectronic, Universiti Kebangsaan Malaysia, 43600 UKM Bangi Selangor (Malaysia)

2009-06-30

White organic light emitting diode (OLED) devices with the structure ITO/PHF:rubrene/Al, in which PHF (poly(9,9-di-n-hexylfluorenyl-2,7-diyl)) is used as blue light emitting host and rubrene (5,6,11,12-tetraphenylnapthacene) as an orange dye dopant, have been fabricated. Indium tin oxide (ITO) coated-glass and aluminium were used as anode and cathode, respectively. The devices were fabricated with various rubrene-dopant to obtain a white light emission. The OLED device that composed of several concentrations of rubrene-doped PHF film was prepared in this study. It was found that the concentration of rubrene in the PHF-rubrene thin film matrix plays a key role in producing the white color emission. In a typical result, the device composed of 0.06 wt.% rubrene-dopant produced the white light emission with the Commission Internationale de L'Eclairage (CIE) coordinate of (0.30,0.33). The turn-on voltage and the brightness were found to be as low as 14.0 V and as high as 6540 cd/m{sup 2}, respectively. The annealing technique at relatively low temperature (50 {sup o}C, 100 {sup o}C, and 150 {sup o}C) was then used to optimize the performance of the device. In a typical result, the turn-on voltage of the device could be successfully reduced and the brightness could be increased using the annealing technique. At an optimum condition, for example, annealed at 150 {sup o}C, the turn-on voltage as low as 8.0 V and the brightness as high as 9040 cd/m{sup 2} were obtained. The mechanism for the improvement of the device performance upon annealing will be discussed.

Signal-to-noise limitations in white light holography

Science.gov (United States)

Ribak, Erez; Breckinridge, James B.; Roddier, Claude; Roddier, Francois

1988-01-01

A simple derivation is given for the SNR in images reconstructed from incoherent holograms. Dependence is shown to be on the hologram SNR, object complexity, and the number of pixels in the detector. Reconstruction of involved objects becomes possible with high-dynamic-range detectors such as CCDs. White-light holograms have been produced by means of a rotational shear interferometer combined with a chromatic corrector. A digital inverse transform recreated the object.

Color-converted remote phosphor prototype of a multiwavelength excitable borosilicate glass for white light-emitting diodes

International Nuclear Information System (INIS)

Tian Hua; Qiu Kun; Song Jun; Wang Da-Jian; Liu Ji-Wen

2012-01-01

We report a unique red light-emitting Eu-doped borosilicate glass to convert color for warm white light-emitting diodes. This glass can be excited from 394 nm-peaked near ultraviolet light, 466 nm-peaked blue light, to 534 nm-peaked green light to emit the desired red light with an excellent transmission in the wavelength range of 400–700 nm which makes this glass suitable for color conversion without a great cost of luminous power loss. In particular, when assembling this glass for commercial white light-emitting diodes, the tested results show that the color rendering index is improved to 84 with a loss of luminous power by 12 percent at average, making this variety of glass promising for inorganic “remote-phosphor” color conversion

A white organic light emitting diode based on anthracene-triphenylamine derivatives

Science.gov (United States)

Jiang, Quan; Qu, Jianjun; Yu, Junsheng; Tao, Silu; Gan, Yuanyuan; Jiang, Yadong

2010-10-01

White organic lighting-diode (WOLED) can be used as flat light sources, backlights for liquid crystal displays and full color displays. Recently, a research mainstream of white OLED is to develop the novel materials and optimize the structure of devices. In this work a WOLED with a structure of ITO/NPB/PAA/Alq3: x% rubrene/Alq3/Mg: Ag, was fabricated. The device has two light-emitting layers. NPB is used as a hole transport layer, PAA as a blue emitting layer, Alq3: rubrene host-guest system as a yellow emitting layer, and Alq3 close to the cathode as an electron transport layer. In the experiment, the doping concentration of rubrene was optimized. WOLED 1 with 4% rubrene achieved a maximum luminous efficiency of 1.80 lm/W, a maximum luminance of 3926 cd/m2 and CIE coordinates of (0.374, 0.341) .WOLED 2 with 2% rubrene achieved a maximum luminous efficiency of 0.65 lm/W, a maximum luminance of 7495cd/m2 and CIE coordinates of (0.365,0.365).

White light emission from exciplex using tris-(8-hydroxyquinoline)aluminum as chromaticity-tuning layer

International Nuclear Information System (INIS)

Feng, Jing; Li, Feng; Gao, Wenbao; Liu, Shiyong; Liu, Yu; Wang, Yue

2001-01-01

We demonstrate efficient organic white light-emitting devices (LEDs), using N,N prime-diphenyl-N,N prime-bis(1-naphthyl) - (1,1 prime-biphenyl)-4,4 prime-diamine (NPB) as the hole-transporting layer, 1,6-bis(2-hydroxyphenyl)pyridine boron complex [(dppy)BF] as the emitting layer, tris-(8-hydroxyquinoline)aluminum (Alq) as the electron-transporting and chromaticity-tuning layer. The white light comes from exciplex emission at the solid-state interface between (dppy)BF and NPB in addition to the exciton emission from NPB and (dppy)BF, respectively. The chromaticity of white emission can be tuned by adjusting the thickness of the Alq layer. The white LEDs with an Alq thickness of 15 nm exhibit a maximum luminescence of 2000 cd/m2 and efficiency of 0.58 lm/W, and the Commission Internationale De l'Eclairage coordinates of resulting emission vary from (0.29,0.33) to (0.31,0.35) with increasing forward bias from 10 to 25 V. The region is very close to the equienergy white point (0.33,0.33). [copyright] 2001 American Institute of Physics

Color Degradation of Textiles with Natural Dyes and of Blue Scale Standards Exposed to White LED Lamps:Evaluation of White LED Lamps for Effectiveness as Museum Lighting

Science.gov (United States)

Ishii, Mie; Moriyama, Takayoshi; Toda, Masahiro; Kohmoto, Kohtaro; Saito, Masako

White light-emitting diodes (LED) are well suited for museum lighting because they emit neither UV nor IR radiation, which damage artifacts. The color degradation of natural dyes and blue scale standards (JIS L 0841) by white LED lamps are examined, and the performance of white LED lamps for museum lighting is evaluated. Blue scale standard grades 1-6 and silk fabrics dyed with 22 types of natural dyes classified as mid to highly responsive in a CIE technical report (CIE157:2004) were exposed to five types of white LED lamps using different luminescence methods and color temperatures. Color changes were measured at each 15000 lx·hr (500 lx at fabric surface × 300 hr) interval ten times. The accumulated exposure totaled 150000 lx·hr. The data on conventional white LED lamps and previously reported white fluorescent (W) and museum fluorescent (NU) lamps was evaluated. All the white LED lamps showed lower fading rates compared with a W lamp on a blue scale grade 1. The fading rate of natural dyes in total was the same between an NU lamp (3000 K) and a white LED lamp (2869 K). However, yellow natural dyes showed higher fading rates with the white LED lamp. This tendency is due to the high power characteristic of the LED lamp around 400-500 nm, which possibly contributes to the photo-fading action on the dyes. The most faded yellow dyes were Ukon (Curcuma longa L.) and Kihada (Phellodendron amurense Rupr.), and these are frequently used in historic artifacts such as kimono, wood-block prints, and scrolls. From a conservation point of view, we need to continue research on white LED lamps for use in museum lighting.

Tunable light emission and similarities with garnet structure of Ce-doped LSCAS glass for white-light devices

Energy Technology Data Exchange (ETDEWEB)

Andrade, L.H.C., E-mail: luishca@uems.br [Grupo de Espectroscopia Optica e Fototermica, Universidade Estadual de Mato Grosso do Sul - UEMS, C.P. 351, Dourados, MS (Brazil); Lima, S.M. [Grupo de Espectroscopia Optica e Fototermica, Universidade Estadual de Mato Grosso do Sul - UEMS, C.P. 351, Dourados, MS (Brazil); Baesso, M.L.; Novatski, A.; Rohling, J.H. [Grupo de Estudos de Fenomenos Fototermicos, Departamento de Fisica, Universidade Estadual de Maringa, Av. Colombo 5790, 87020-900 Maringa, PR (Brazil); Guyot, Y.; Boulon, G. [Laboratoire de Physico-Chimie des Materiaux Luminescents, Universite Claude Bernard Lyon 1, UMR 5620 CNRS, 69622 Villeurbanne (France)

2012-01-05

Highlights: > Ce{sup 3+}-doped LSCAS glass exhibits broad, simultaneously blue and yellow emissions under UV excitation. > In this phosphor is possible to continuously tune the emission, covering the entire visible spectrum. > The ability to change the color temperature in accordance to the occasion is a feature of this glass system. - Abstract: In this paper, we report results concerning tunable light emission and color temperature in cerium-doped low-silica-calcium-alumino-silicate (LSCAS) glass for smart white-light devices. Spectroscopic results, analyzed using the CIE 1931 x-y chromatic diagram, show that this glass presents two broad emission bands centered at 475 and 540 nm, whose intensities can be tuned by the excitation wavelength. Moreover, the same emission can be achieved from a color temperature range from 3200 to 10,000 K, with a color-rendering index (CRI) of around 75% obtained by changing the optical path length of the sample. Our new phosphor LSCAS glass, which is a unique system that exhibits tunable yellow emission, combines all qualities for white-light devices.

Method for improving the spectral flatness of the supercontinuum at 1.55 μm in tapered microstructured optical fibers

International Nuclear Information System (INIS)

Vukovic, N.; Broderick, N. G. R.

2010-01-01

We propose a method for enhancing the flatness of a supercontinuum centered at 1.55 μm by the use of specially designed tapered microstructured optical fibers (MOFs). Based on the procedure presented one can determine the linear taper profile parameters and the optimum launching conditions needed to achieve the broadest supercontinuum spectra (SC) and the best spectra flatness. We quantify the maximally broad and flat SC using the calculated standard deviation of the spectra at the required wavelength range and show that it is possible to obtain significantly better results than those obtained by using an untapered fiber.

Method for improving the spectral flatness of the supercontinuum at 1.55 {mu}m in tapered microstructured optical fibers

Energy Technology Data Exchange (ETDEWEB)

Vukovic, N; Broderick, N G. R. [Optoelectronics Research Centre, University of Southampton, Southampton SO17 1BJ (United Kingdom)

2010-10-15

We propose a method for enhancing the flatness of a supercontinuum centered at 1.55 {mu}m by the use of specially designed tapered microstructured optical fibers (MOFs). Based on the procedure presented one can determine the linear taper profile parameters and the optimum launching conditions needed to achieve the broadest supercontinuum spectra (SC) and the best spectra flatness. We quantify the maximally broad and flat SC using the calculated standard deviation of the spectra at the required wavelength range and show that it is possible to obtain significantly better results than those obtained by using an untapered fiber.

White light generation using CdSe/ZnS core-shell nanocrystals hybridized with InGaN/GaN light emitting diodes

International Nuclear Information System (INIS)

Nizamoglu, S; Ozel, T; Sari, E; Demir, H V

2007-01-01

We introduce white light generation using CdSe/ZnS core-shell nanocrystals of single, dual, triple and quadruple combinations hybridized with InGaN/GaN LEDs. Such hybridization of different nanocrystal combinations provides the ability to conveniently adjust white light parameters including the tristimulus coordinates (x,y), correlated colour temperature (T c ) and colour rending index (R a ). We present the design, growth, fabrication and characterization of our white hybrid nanocrystal-LEDs that incorporate combinations of (1) yellow nanocrystals (λ PL = 580 nm) on a blue LED (λ EL = 440 nm) with (x,y) = (0.37,0.25), T c = 2692 K and R a 14.69; (2) cyan and red nanocrystals (λ PL = 500 and 620 nm) on a blue LED (λ EL = 440 nm) with (x,y) = (0.37,0.28), T c = 3246 K and R a = 19.65; (3) green, yellow and red nanocrystals (λ PL = 540, 580 and 620 nm) on a blue LED (λ EL = 452 nm) with (x,y) = (0.30,0.28), T c = 7521 K and R a = 40.95; and (4) cyan, green, yellow and red nanocrystals (λ PL = 500, 540, 580 and 620 nm) on a blue LED (λ EL = 452 nm) with (x,y) = (0.24,0.33), T c = 11 171 K and R a 71.07. These hybrid white light sources hold promise for future lighting and display applications with their highly adjustable properties

A development optical course based on optical fiber white light interference

Science.gov (United States)

Jiang, Haili; Sun, Qiuhua; Zhao, Yancheng; Li, Qingbo

2017-08-01

The Michelson interferometer is a very important instrument in optical part for college physics teaching. But most students only know the instrument itself and don't know how to use it in practical engineering problems. A case about optical fiber white light interference based on engineering practice was introduced in the optical teaching of college physics and then designed a development course of university physical optics part. This system based on low-coherence white light interferometric technology can be used to measure distribution strain or temperature. It also could be used in the case of temperature compensation mode.This teaching design can use the knowledge transfer rule to enable students to apply the basic knowledge in the university physics to the new knowledge domain, which can promote the students' ability of using scientific methods to solve complex engineering problems.

Signal-to-noise limitations in white light holography.

Science.gov (United States)

Ribak, E; Roddier, C; Roddier, F; Breckinridge, J B

1988-03-15

A simple derivation is given for the signal-to-noise ratio (SNR) in images reconstructed from incoherent holograms. Dependence is shown to be on the hologram SNR, object complexity, and the number of pixels in the detector. Reconstruction of involved objects becomes possible with high dynamic range detectors such as charge coupled devices. We have produced such white light holograms by means of a rotational shear interferometer combined with a chromatic corrector. A digital inverse transform recreated the object.

Broadband upconversion imaging around 4 µm using an all-fiber supercontinuum source

DEFF Research Database (Denmark)

Huot, Laurent; Moselund, Peter M.; Leick, Lasse

2017-01-01

. The infrared signal is passed through a sample and then focused into a bulk AgGaS2 crystal and subsequently mixed with a synchronous mixing signal at 1550 nm extracted from the pump laser of the supercontinuum. Through sum frequency generation, an upconverted signal ranging from 1030 nm to 1155 nm is generated...... and acquired using an InGaAs camera....

White light emission from Er2O3 nano-powder excited by infrared radiation

Science.gov (United States)

Tabanli, Sevcan; Eryurek, Gonul; Di Bartolo, Baldassare

2017-07-01

Phosphors of Er2O3 nano-crystalline powders were synthesized by the thermal decomposition method. The structural properties of the nano-powders were investigated with XRD and HRTEM measurements. The cubic phase with a = 10.540 Å was the only phase observed. The average crystalline sizes and the widths of the grain size distribution curves were determined to be 27.2, 18.7 and 9.7 nm, respectively. The spectroscopic properties of the Er2O3 nano-powder were studied by measuring the luminescence, decay and rise patterns under 808 and 975 nm diode laser excitations. A peculiar effect of the pressure was observed since an optically active ion (Er) is part of the complex and not a dopant. A broad band of the white light emission combined with blue, green and red up-conversion emission bands of Er3+ ions were observed at 0.03 mbar pressure under both excitation wavelengths. Only, an intense broad band white light emission was observed from these nanocrystals at atmospheric pressure. Rising patterns show that the white light intensity reaches its maximum value more rapidly under 975 nm excitation although it decays slower than that of 808 nm excitation. The color quality parameters such as the color coordinate (CRI), correlated color temperature and the color rendering index were found to vary with both the excitation wavelength and the ambient pressure indicating that these nanocrystals could be considered good white light emitting source under the infrared excitations.

White polymer light-emitting diodes based on star-shaped polymers with an orange dendritic phosphorescent core.

Science.gov (United States)

Zhu, Minrong; Li, Yanhu; Cao, Xiaosong; Jiang, Bei; Wu, Hongbin; Qin, Jingui; Cao, Yong; Yang, Chuluo

2014-12-01

A series of new star-shaped polymers with a triphenylamine-based iridium(III) dendritic complex as the orange-emitting core and poly(9,9-dihexylfluorene) (PFH) chains as the blue-emitting arms is developed towards white polymer light-emitting diodes (WPLEDs). By fine-tuning the content of the orange phosphor, partial energy transfer and charge trapping from the blue backbone to the orange core is realized to achieve white light emission. Single-layer WPLEDs with the configuration of ITO (indium-tin oxide)/poly(3,4-ethylenedioxythiophene):poly(styrenesulfonate) (PEDOT:PSS)/polymer/CsF/Al exhibit a maximum current efficiency of 1.69 cd A(-1) and CIE coordinates of (0.35, 0.33), which is very close to the pure white-light point of (0.33, 0.33). To the best of our knowledge, this is the first report on star-shaped white-emitting single polymers that simultaneously consist of fluorescent and phosphorescent species. © 2014 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

Measurement of the influence of dispersion on white-light interferometry

Czech Academy of Sciences Publication Activity Database

Pavlíček, Pavel; Soubusta, Jan

2004-01-01

Roč. 43, č. 4 (2004), s. 766-770 ISSN 0003-6935 R&D Projects: GA MŠk LN00A015 Institutional research plan: CEZ:AV0Z1010921 Keywords : white-light interferometry * height profile * smooth surface Subject RIV: BH - Optics, Masers, Lasers Impact factor: 1.799, year: 2004

Laser Based Phosphor Converted Solid State White Light Emitters

Science.gov (United States)

Cantore, Michael

Artificial lighting and as a consequence the ability to be productive when the sun does not shine may be a profound achievement in society that is largely taken for granted. As concerns arise due to our dependence on energy sources with finite lifespan or environmentally negative effects, efforts to reduce energy consumption and create clean renewable alternatives has become highly valued. In the scope of artificial lighting, the use of incandescent lamps has shifted to more efficient light sources. Fluorescent lighting made the first big gains in efficiency over incandescent lamps with peak efficiency for mature designs reaching luminous efficacy of approximately 90 lm/W; more than three times as efficient as an incandescent lamp. Lamps based on light emitting diodes (LEDs) which can produce light at even greater efficiency, color quality and without the potential for hazardous chemical release from lamp failure. There is a significant challenge with LED based light sources. Their peak efficiency occurs at low current densities and then droops as the current density increases. Laser diodes (LDs) do not suffer from decreasing efficiency due to increased current. An alternative solid state light source using LDs has potential to make further gains in efficiency as well as allow novel illuminant designs which may be impractical or even impossible even with LED or other conventional sources. While similar to LEDS, the use of LDs does present new challenges largely due to the increased optical power density which must be accommodated in optics and phosphor materials. Single crystal YAG:Ce has been shown to be capable of enduring this more extreme operating environment while retaining the optical and fluorescing qualities desired for use as a wavelength converter in phosphor converted LD based white emitting systems. The incorporation of this single crystal phosphor in a system with a commercial laser diode with peak wall plug efficiency of 31% resulted in emission of

Newly patented process enables low-cost solution for increasing white light spectrum of LEDs

Science.gov (United States)

Spanard, Jan-Marie

2017-10-01

A newly patented process for completing the spectral light array emitted by LED bulbs provides a low-cost method for producing better human centered lighting (HCL). This process uses non-luminescent colorant filters, filling out the jagged LED spectral emission into a full, white light array. While LED bulbs have the distinct economic advantages of using less energy, producing less heat and lasting years longer than traditional incandescent bulbs, the persistent metameric failure of LED bulbs has resulted in slower, and sometimes reluctant, adoption of LED lighting by the residential, retail and architectural markets. Adding missing wavelengths to LED generated bulbs via colorant filters increases the aesthetic appeal of the light by decreasing current levels of metameric failure, reducing the `flatness', `harshness', and `dullness' of LED generated light reported by consumers. LED phosphor-converted light can be successfully tuned to "whiter" white light with selective color filtering using permanent, durable transparent pigments. These transparent pigments are selectively applied in combination with existing manufacturing technologies and utilized as a final color-tuning step in bulb design. The quantity of emitted light chosen for color filtering can be adjusted from 1% to 100% of emitted light, creating a custom balance of light quantity with light quality. This invention recognizes that "better light" is frequently chosen over "more light" in the consumer marketplace.

White-Light Emission and Structural Distortion in New Corrugated Two-Dimensional Lead Bromide Perovskites.

Science.gov (United States)

Mao, Lingling; Wu, Yilei; Stoumpos, Constantinos C; Wasielewski, Michael R; Kanatzidis, Mercouri G

2017-03-29

Hybrid inorganic-organic perovskites are developing rapidly as high performance semiconductors. Recently, two-dimensional (2D) perovskites were found to have white-light, broadband emission in the visible range that was attributed mainly to the role of self-trapped excitons (STEs). Here, we describe three new 2D lead bromide perovskites incorporating a series of bifunctional ammonium dications as templates which also emit white light: (1) α-(DMEN)PbBr 4 (DMEN = 2-(dimethylamino)ethylamine), which adopts a unique corrugated layered structure in space group Pbca with unit cell a = 18.901(4) Å, b = 11.782(2) Å, and c = 23.680(5) Å; (2) (DMAPA)PbBr 4 (DMAPA = 3-(dimethylamino)-1-propylamine), which crystallizes in P2 1 /c with a = 10.717(2) Å, b = 11.735(2) Å, c = 12.127(2) Å, and β = 111.53(3)°; and (3) (DMABA)PbBr 4 (DMABA = 4-dimethylaminobutylamine), which adopts Aba2 with a = 41.685(8) Å, b = 23.962(5) Å, and c = 12.000(2) Å. Photoluminescence (PL) studies show a correlation between the distortion of the "PbBr 6 " octahedron in the 2D layer and the broadening of PL emission, with the most distorted structure having the broadest emission (183 nm full width at half-maximum) and longest lifetime (τ avg = 1.39 ns). The most distorted member α-(DMEN)PbBr 4 exhibits white-light emission with a color rendering index (CRI) of 73 which is similar to a fluorescent light source and correlated color temperature (CCT) of 7863 K, producing "cold" white light.

Monolithic Inorganic ZnO/GaN Semiconductors Heterojunction White Light-Emitting Diodes.

Science.gov (United States)

Jeong, Seonghoon; Oh, Seung Kyu; Ryou, Jae-Hyun; Ahn, Kwang-Soon; Song, Keun Man; Kim, Hyunsoo

2018-01-31

Monolithic light-emitting diodes (LEDs) that can generate white color at the one-chip level without the wavelength conversion through packaged phosphors or chip integration for photon recycling are of particular importance to produce compact, cost-competitive, and smart lighting sources. In this study, monolithic white LEDs were developed based on ZnO/GaN semiconductor heterojunctions. The electroluminescence (EL) wavelength of the ZnO/GaN heterojunction could be tuned by a post-thermal annealing process, causing the generation of an interfacial Ga 2 O 3 layer. Ultraviolet, violet-bluish, and greenish-yellow broad bands were observed from n-ZnO/p-GaN without an interfacial layer, whereas a strong greenish-yellow band emission was the only one observed from that with an interfacial layer. By controlled integration of ZnO/GaN heterojunctions with different postannealing conditions, monolithic white LED was demonstrated with color coordinates in the range (0.3534, 0.3710)-(0.4197, 0.4080) and color temperatures of 4778-3349 K in the Commission Internationale de l'Eclairage 1931 chromaticity diagram. Furthermore, the monolithic white LED produced approximately 2.1 times higher optical output power than a conventional ZnO/GaN heterojunction due to the carrier confinement effect at the Ga 2 O 3 /n-ZnO interface.

White light emission from organic-inorganic hererostructure devices by using CdSe quantum dots as emitting layer

International Nuclear Information System (INIS)

Tang Aiwei; Teng Feng; Gao Yinhao; Li Dan; Zhao Suling; Liang Chunjun; Wang Yongsheng

2007-01-01

In this paper, white light emission was obtained from organic-inorganic heterostructure devices by using CdSe quantum dots as emitting layer, in which CdSe quantum dots were synthesized via a colloidal chemical approach by using CdO and Se powder as precursors. Photoluminescence of CdSe quantum dots demonstrated a white emission with a full wavelength at half maximum (FWHM) of about 200 nm under ambient conditions, and the white emission could be observed in both multilayer device ITO/PEDOT:PSS/CdSe/BCP/Alq 3 /Al and single-layer device: ITO/PEDOT:PSS/CdSe/Al. The broad emission was attributed to the inhomogeneous broadening. The CIE coordinates of the multilayer device were x=0.35 and y=0.40. The white-light-emitting diodes with CdSe quantum dots as the emitting layer are potentially useful in lighting applications

Picosecond pulse generated supercontinuum as a stable seed for OPCPA

Czech Academy of Sciences Publication Activity Database

Indra, Lukáš; Batysta, František; Hříbek, Petr; Novák, Jakub; Hubka, Zbyněk; Green, Jonathan T.; Antipenkov, Roman; Boge, Robert; Naylon, Jack A.; Bakule, Pavel; Rus, Bedřich

2017-01-01

Roč. 42, č. 4 (2017), s. 843-846 ISSN 0146-9592 R&D Projects: GA MŠk LQ1606; GA MŠk EF15_008/0000162 Grant - others:ELI Beamlines(XE) CZ.02.1.01/0.0/0.0/15_008/0000162 Institutional support: RVO:68378271 Keywords : supercontinuum generation * ultrafast lasers * ultrafast nonlinear optics * thin-disk amplifier * repetition-rate Subject RIV: BH - Optics, Masers, Lasers OBOR OECD: Optics (including laser optics and quantum optics) Impact factor: 3.416, year: 2016

Two Octaves Supercontinuum Generation in Lead-Bismuth Glass Based Photonic Crystal Fiber

Directory of Open Access Journals (Sweden)

Ryszard Buczynski

2014-06-01

Full Text Available In this paper we report a two octave spanning supercontinuum generation in a bandwidth of 700–3000 nm in a single-mode photonic crystal fiber made of lead-bismuth-gallate glass. To our knowledge this is the broadest supercontinuum reported in heavy metal oxide glass based fibers. The fiber was fabricated using an in-house synthesized glass with optimized nonlinear, rheological and transmission properties in the range of 500–4800 nm. The photonic cladding consists of 8 rings of air holes. The fiber has a zero dispersion wavelength (ZDW at 1460 nm. Its dispersion is determined mainly by the first ring of holes in the cladding with a relative hole size of 0.73. Relative hole size of the remaining seven rings is 0.54, which allows single mode performance of the fiber in the infrared range and reduces attenuation of the fundamental mode. The fiber is pumped into anomalous dispersion with 150 fs pulses at 1540 nm. Observed spectrum of 700–3000 nm was generated in 2 cm of fiber with pulse energy below 4 nJ. A flatness of 5 dB was observed in 950–2500 nm range.

Synthesis and Electroluminescent Property of New Orange Iridium Compounds for Flexible White Organic Light Emitting Diodes.

Science.gov (United States)

Lee, Ho Won; Jeong, Hyunjin; Kim, Young Kwan; Ha, Yunkyoung

2015-10-01

Recently, white organic light-emitting diodes (OLEDs) have aroused considerable attention because they have the potential of next-generation flexible displays and white illuminated applications. White OLED applications are particularly heading to the industry but they have still many problems both materials and manufacturing. Therefore, we proposed that the new iridium compounds of orange emitters could be demonstrated and also applied to flexible white OLEDs for verification of potential. First, we demonstrated the chemical properties of new orange iridium compounds. Secondly, conventional two kinds of white phosphorescent OLEDs were fabricated by following devices; indium-tin oxide coated glass substrate/4,4'-bis[N-(napthyl)-N-phenylamino]biphenyl/N,N'-dicarbazolyl-3,5-benzene doped with blue and new iridium compounds for orange emitting 8 wt%/1,3,5-tris[N-phenylbenzimidazole-2-yl]benzene/lithium quinolate/aluminum. In addition, we fabricated white OLEDs using these emitters to verify the potential on flexible substrate. Therefore, this work could be proposed that white light applications can be applied and could be extended to additional research on flexible applications.

Testing the stationarity of white dwarf light-curves

International Nuclear Information System (INIS)

Molnar, L; Kollath, Z; Plachy, E; Paparo, M

2009-01-01

Long period white dwarfs show changes in their frequency spectra from one observing season to another, i.e. their light-curves cannot be considered as stationary multiperiodic variations on long timescales. However, due to the complex frequency spectra of these stars and the narrow frequency spacing, it is still unknown, what the shortest time scale is, where real physical modulation exists. We present tests on artificial data, resembling the observations, using time-frequency distributions (TFDs), Fourier-analysis and the analytical signal method.

Electroplex emission at PVK/Bphen interface for application in white organic light-emitting diodes

International Nuclear Information System (INIS)

Wen Liang; Li Fushan; Xie Jiangxing; Wu Chaoxing; Zheng Yong; Chen Dongling; Xu Sheng; Guo Tailiang; Qu Bo; Chen Zhijian; Gong Qihuang

2011-01-01

White organic light-emitting diode (WOLED) with a structure of ITO/poly(N-vinylcarbazole) (PVK)/4,7-diphenyl-1, 10-phenanthroline (Bphen)/tris(8-hydroxyquinoline)aluminum (Alq 3 )/LiF/Al has been fabricated via the thermal evaporation technique. The electroluminescence (EL) spectrum of the as-fabricated WOLED covers from 380 to 700 nm of the visible light region with a wide blue emission from PVK and an interesting new red emission. The red emission at 613 nm in EL spectra of the WOLED was attributed to electroplex emission at PVK/Bphen interface since it was not observed in photoluminescence spectra. The WOLED showed a Commission International De l'Eclairage coordinate of (0.31, 0.32), which is very close to the standard white coordinate (0.33, 0.33). - Highlights: → A white organic light-emitting diode was fabricated by vacuum deposition. → A new red emission at 613 nm was observed in the electroluminescence spectra. → Red emission comes from electroplex instead of exciplex at PVK/Bphen interface. → The device has a CIE coordinate of (0.31, 0.32).

Novel green-emitting Na2CaPO4F:Eu2+ phosphors for near-ultraviolet white light-emitting diodes

International Nuclear Information System (INIS)

Huang, Chien-Hao; Chen, Yen-Chi; Kuo, Te-Wen; Chen, Teng-Ming

2011-01-01

In this study, green-emitting Na 2 CaPO 4 F:Eu 2+ phosphors were synthesized by solid-state reactions. The excitation spectra of the phosphors showed a broad hump between 250 and 450 nm; the spectra match well with the near-ultraviolet (NUV) emission spectra of light-emitting diodes (LEDs). The emission spectrum showed an intense broad emission band centered at 506 nm. White LEDs were fabricated by integrating a 390 nm NUV chip comprising blue-emitting BaMgAl 10 O 17 :Eu 2+ , green-emitting Na 2 CaPO 4 F:0.02 Eu 2+ , and red-emitting CaAlSiN 3 :Eu 2+ phosphors into a single package; the white LEDs exhibited white light with a correlated color temperature of 5540 K, a color-rendering index of 90.75, and color coordinates (0.332, 0.365) close to those of ideal white light. - Highlights: → Novel green-emitting Na 2 CaPO 4 F:Eu 2+ phosphors were synthesized by solid-state reactions in this research. → White LEDs were fabricated by integrating a 390 nm NUV chip comprising blue-emitting BaMgAl 10 O 17 :Eu 2+ , green-emitting Na 2 CaPO 4 F:0.02Eu 2+ , and red-emitting CaAlSiN 3 :Eu 2+ phosphors into a single package. → The white LEDs exhibited white light with a correlated color temperature of 5540 K, a color-rendering index of 90.75, and color coordinates (0.332, 0.365) close to those of ideal white light.

Medium pressure mercury discharge for use as an intense white light source

International Nuclear Information System (INIS)

Kitsinelis, S; Devonshire, R; Stone, D A; Tozer, R C

2005-01-01

In this paper, we demonstrate the possibilities that exist in developing a high brightness white light source. The lamp employs mercury at a few Torr and is operated with short pulses of the order of 1 μs at a frequency of 10 kHz. The emission spectrum is atomic in nature and the white light is the outcome of a relative enhancement of the mercury yellow lines at 577 and 579 nm with respect to the rest of the visible lines, which shifts the colour coordinates of the source towards the black body locus of the chromaticity diagram. The pulse operation of a lamp containing mercury at a vapour pressure of 20 Torr offers a greater near-UV and visible output compared to a phosphor-uncoated, low-pressure pulsed compact mercury discharge

Suppressed speckle contrast of blue light emission out of white lamp with phosphors excited by blue laser diodes for high-brightness lighting applications

Science.gov (United States)

Kinoshita, Junichi; Ikeda, Yoshihisa; Takeda, Yuji; Ueno, Misaki; Kawasaki, Yoji; Matsuba, Yoshiaki; Heike, Atsushi

2012-11-01

The speckle contrast of blue light emission out of high-brightness white lamps using phosphors excited by InGaN/GaN blue laser diodes is evaluated as a measure of coherence. As a result, speckle contrast of as low as 1.7%, the same level as a blue light emitting diode, is obtained. This implies that the original blue laser light can be converted into incoherent light through lamp structures without any dynamic mechanisms. This unique speckle-free performance is considered to be realized by multiple scattering inside the lamp structure, the multi-longitudinal mode operation of the blue laser diodes, and the use of multiple laser diodes. Such almost-incoherent white lamps can be applied for general lighting without any nuisance of speckle noise and should be categorized as lamps rather than lasers in terms of laser safety regulation.

Simple single-emitting layer hybrid white organic light emitting with high color stability

Science.gov (United States)

Nguyen, C.; Lu, Z. H.

2017-10-01

Simultaneously achieving a high efficiency and color quality at luminance levels required for solid-state lighting has been difficult for white organic light emitting diodes (OLEDs). Single-emitting layer (SEL) white OLEDs, in particular, exhibit a significant tradeoff between efficiency and color stability. Furthermore, despite the simplicity of SEL white OLEDs being its main advantage, the reported device structures are often complicated by the use of multiple blocking layers. In this paper, we report a highly simplified three-layered white OLED that achieves a low turn-on voltage of 2.7 V, an external quantum efficiency of 18.9% and power efficiency of 30 lm/W at 1000 cd/cm2. This simple white OLED also shows good color quality with a color rendering index of 75, CIE coordinates (0.42, 0.46), and little color shifting at high luminance. The device consists of a SEL sandwiched between a hole transport layer and an electron transport layer. The SEL comprises a thermally activated delayer fluorescent molecule having dual functions as a blue emitter and as a host for other lower energy emitters. The improved color stability and efficiency in such a simple device structure is explained as due to the elimination of significant energy barriers at various organic-organic interfaces in the traditional devices having multiple blocking layers.

Donor doping process and white light generation in CaMoO4 powders with multivalence Pr codoping

International Nuclear Information System (INIS)

Zhu Fang; Xiao Zhisong; Zhang Feng; Yan Lu; Huang Anping

2011-01-01

Both trivalent praseodymium (Pr 3+ ) and quadrivalent praseodymium (Pr 4+ ) were doped in molybdate powders. Visible emission from matrix was enhanced by multivalent Pr codoping. It was proposed that Pr 3+ ions was donor and supplied quasi-free electron when Pr 3+ took place the Pr 4+ sites. The result showed that multivalence codoping would be an effective way to enhance emission of CaMoO 4 . White light can be generated from Ca 0.98 Pr 0.02 MoO 4 powder via combination of broadband emissions originated from CaMoO 4 matrix and radiative transition of Pr 3+ . It showed warm white light with T c of 3450 K that implies promising application in white light emitting diodes (LEDs).

Human Adolescent Phase Response Curves to Bright White Light.

Science.gov (United States)

Crowley, Stephanie J; Eastman, Charmane I

2017-08-01

Older adolescents are particularly vulnerable to circadian misalignment and sleep restriction, primarily due to early school start times. Light can shift the circadian system and could help attenuate circadian misalignment; however, a phase response curve (PRC) to determine the optimal time for receiving light and avoiding light is not available for adolescents. We constructed light PRCs for late pubertal to postpubertal adolescents aged 14 to 17 years. Participants completed 2 counterbalanced 5-day laboratory sessions after 8 or 9 days of scheduled sleep at home. Each session included phase assessments to measure the dim light melatonin onset (DLMO) before and after 3 days of free-running through an ultradian light-dark (wake-sleep) cycle (2 h dim [~20 lux] light, 2 h dark). In one session, intermittent bright white light (~5000 lux; four 20-min exposures) was alternated with 10 min of dim room light once per day for 3 consecutive days. The time of light varied among participants to cover the 24-h day. For each individual, the phase shift to bright light was corrected for the free-run derived from the other laboratory session with no bright light. One PRC showed phase shifts in response to light start time relative to the DLMO and another relative to home sleep. Phase delay shifts occurred around the hours corresponding to home bedtime. Phase advances occurred during the hours surrounding wake time and later in the afternoon. The transition from delays to advances occurred at the midpoint of home sleep. The adolescent PRCs presented here provide a valuable tool to time bright light in adolescents.

Energy transfer and colour tunability in UV light induced Tm3+/Tb3+/Eu3+: ZnB glasses generating white light emission.

Science.gov (United States)

Naresh, V; Gupta, Kiran; Parthasaradhi Reddy, C; Ham, Byoung S

2017-03-15

A promising energy transfer (Tm 3+ →Tb 3+ →Eu 3+ ) approach is brought forward to generate white light emission under ultraviolet (UV) light excitation for solid state lightening. Tm 3+ /Tb 3+ /Eu 3+ ions are combinedly doped in zinc borate glass system in view of understanding energy transfer process resulting in white light emission. Zinc borate (host) glass displayed optical and luminescence properties due to formation of Zn(II) x -[O(-II)] y centres in the ZnB glass matrix. At 360nm (UV) excitation, triply doped Tm 3+ /Tb 3+ /Eu 3+ : ZnB glasses simultaneously shown their characteristic emission bands in blue (454nm: 1 D 2 → 3 F 4 ), green (547nm: 5 D 4 → 7 F 5 ) and red (616nm: 5 D 0 → 7 F 2 ) regions. In triple ions doped glasses, energy transfer dynamics is discussed in terms of Forster-Dexter theory, excitation & emission profiles, lifetime curves and from partial energy level diagram of three ions. The role of Tb 3+ in ET from Tm 3+ →Eu 3+ was discussed using branch model. From emission decay analysis, energy transfer probability (P) and efficiency (η) were evaluated. Colour tunability from blue to white on varying (Tb 3+ , Eu 3+ ) content is demonstrated from Commission Internationale de L'Eclairage (CIE) chromaticity coordinates. Based on chromaticity coordinates, other colour related parameters like correlated colour temperature (CCT) and colour purity are also computed for the studied glass samples. An appropriate blending of such combination of rare earth ions could show better suitability as potential candidates in achieving multi-colour and warm/cold white light emission for white LEDs application in the field of solid state lightening. Copyright © 2016 Elsevier B.V. All rights reserved.

White organic light-emitting diodes with 9, 10-bis (2-naphthyl) anthracene

International Nuclear Information System (INIS)

Guan Yunxia; Niu Lianbin

2009-01-01

White organic light-emitting diodes were fabricated by 9, 10-bis (2-naphthyl) anthracene (ADN) doped with Rubrene with a structure of ITO/copper phthalocyanine (CuPc) / NPB /ADN: Rubrene /Alq 3 /CsF/Mg:Ag/Ag. Multilayer organic devices using AND and Rubrene as an emitting layer produced white emissions with good chromaticity and luminous efficiency as high as 5.93 cd/A. This performance can be explained by Foerster energy transfer from the blue-emitting host to the orange-emitting dopant.

Introduction of Red-Green-Blue Fluorescent Dyes into a Metal-Organic Framework for Tunable White Light Emission.

Science.gov (United States)

Wen, Yuehong; Sheng, Tianlu; Zhu, Xiaoquan; Zhuo, Chao; Su, Shaodong; Li, Haoran; Hu, Shengmin; Zhu, Qi-Long; Wu, Xintao

2017-10-01

The unique features of the metal-organic frameworks (MOFs), including ultrahigh porosities and surface areas, tunable pores, endow the MOFs with special utilizations as host matrices. In this work, various neutral and ionic guest dye molecules, such as fluorescent brighteners, coumarin derivatives, 4-(dicyanomethylene)-2-methyl-6-(p-dimethylaminostyryl)-4H-pyran (DCM), and 4-(p-dimethylaminostyryl)-1-methylpyridinium (DSM), are encapsulated in a neutral MOF, yielding novel blue-, green-, and red-phosphors, respectively. Furthermore, this study introduces the red-, green-, and blue-emitting dyes into a MOF together for the first time, producing white-light materials with nearly ideal Commission International ed'Eclairage (CIE) coordinates, high color-rendering index values (up to 92%) and quantum yields (up to 26%), and moderate correlated color temperature values. The white light is tunable by changing the content or type of the three dye guests, or the excitation wavelength. Significantly, the introduction of blue-emitting guests in the methodology makes the available MOF host more extensive, and the final white-light output more tunable and high-quality. Such strategy can be widely adopted to design and prepare white-light-emitting materials. © 2017 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

Solution processed, white emitting tandem organic light-emitting diodes with inverted device architecture.

Science.gov (United States)

Höfle, Stefan; Schienle, Alexander; Bernhard, Christoph; Bruns, Michael; Lemmer, Uli; Colsmann, Alexander

2014-08-13

Fully solution processed monochromatic and white-light emitting tandem or multi-photon polymer OLEDs with an inverted device architecture have been realized by employing WO3 /PEDOT:PSS/ZnO/PEI charge carrier generation layers. The luminance of the sub-OLEDs adds up in the stacked device indicating multi-photon emission. The white OLEDs exhibit a CRI of 75. © 2014 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

White light generation tuned by dual hybridization of nanocrystals and conjugated polymers

International Nuclear Information System (INIS)

Demir, Hilmi Volkan; Nizamoglu, Sedat; Ozel, Tuncay; Mutlugun, Evren; Huyal, Ilkem Ozge; Sari, Emre; Holder, Elisabeth; Tian Nan

2007-01-01

Dual hybridization of highly fluorescent conjugated polymers and highly luminescent nanocrystals (NCs) is developed and demonstrated in multiple combinations for controlled white light generation with high color rendering index (CRI) (> 80) for the first time. The generated white light is tuned using layer-by-layer assembly of CdSe/ZnS core-shell NCs closely packed on polyfluorene, hybridized on near-UV emitting nitride-based light emitting diodes (LEDs). The design, synthesis, growth, fabrication and characterization of these hybrid inorganic-organic white LEDs are presented. The following experimental realizations are reported: (i) layer-by-layer hybridization of yellow NCs (λ PL =580 nm) and blue polyfluorene (λ PL =439 nm) with tristimulus coordinates of (x, y)=(0.31, 0.27), correlated color temperature of T c =6962 K and CRI of R a =53.4; (ii) layer-by-layer assembly of yellow and green NCs (λ PL =580 and 540 nm) and blue polyfluorene (λ PL =439 nm) with (x, y)=(0.23, 0.30), T c =14395 K and R a =65.7; and (iii) layer-by-layer deposition of yellow, green and red NCs (λ PL =580, 540 and 620 nm) and blue polyfluorene (λ PL =439 nm) with (x, y)=(0.38, 0.39), T c =4052 K and R a = 83.0. The CRI is demonstrated to be well controlled and significantly improved by increasing multi-chromaticity of the NC and polymer emitters

Multispectral digital lensless holographic microscopy: from femtosecond laser to white light LED

International Nuclear Information System (INIS)

Garcia-Sucerquia, J

2015-01-01

The use of femtosecond laser radiation and super bright white LED in digital lensless holographic microscopy is presented. For the ultrafast laser radiation two different configurations of operation of the microscope are presented and the dissimilar performance of each one analyzed. The microscope operating with a super bright white light LED in combination with optical filters shows very competitive performance as it is compared with more expensive optical sources. The broadband emission of both radiation sources allows the multispectral imaging of biological samples to obtain spectral responses and/or full color images of the microscopic specimens; sections of the head of a Drosophila melanogaster fly are imaged in this contribution. The simple, solid, compact, lightweight, and reliable architecture of digital lensless holographic microscopy operating with broadband light sources to image biological specimens exhibiting micrometer-sized details is evaluated in the present contribution. (paper)

Simulataneous Formation of InGaN Nanostructures with Varying Shapes for White Light Source Applications

KAUST Repository

Gasim, Anwar A.; Bhattacharya, Pallab K.; Cha, Dong Kyu; Ng, Tien Khee; Ooi, Boon S.

2012-01-01

Varying shapes of InGaN nanostructures were simultaneously formed on silicon epitaxially. The nanowires and nanomushrooms emit violet-blue light, and broad yellow-orange-red luminescence, respectively. The combination of which is promising for white light emission.

Control of a White Organic Light Emitting Diode emission parameters using a single doped RGB active layer

Energy Technology Data Exchange (ETDEWEB)

Pereira, D. [Departamento de Ciência dos Materiais e i3N – Instituto de Nanoestruturas, Nanomodelação e Nanofabricação, Faculdade de Ciências e Tecnologia, Universidade Nova de Lisboa, Campus da Caparica, 2829-516 Caparica (Portugal); Pinto, A.; Califórnia, A.; Gomes, J. [CeNTI – Centro de Nanotecnologia, Materiais Técnicos, Funcionais e Inteligentes, Rua Fernando Mesquita 2785, 4760-034 Vila Nova de Famalicão (Portugal); Pereira, L., E-mail: luiz@ua.pt [Departmento de Física e i3N – Instituto de Nanoestruturas, Nanomodelação e Nanofabricação, Universidade de Aveiro, 3810-193 Aveiro (Portugal)

2016-09-15

Highlights: • A simple WOLED for Solid State Lighting is proposed with high color stability. • Energy transfer and electroluminescence dynamics of a single RGB layer for WOLEDs. • White shade modulation and stability over large emitting areas and applied voltages. - Abstract: Solid State Lighting technologies based on Organic Light Emitting Diodes, became an interesting focus due to their unique properties. The use of a unique RGB active layer for white emission, although simple in theory, shows difficulty to stabilize both CIE coordinates and color modulation. In this work, a WOLED using a simple RGB layer, was developed achieving a high color stability and shade modulation. The RGB matrix comprises a blue host material NPB, doped with two guests, a green (Coumarin 153) and a red (DCM1) in low concentrations. The RGB layer carrier dynamics allows for the white emission in low device complexity and high stability. This was also shown independent of the white shade, obtained through small changes in the red dopant resulting in devices ranging from warm to cool white i.e. an easy color tuning. A detailed analysis of the opto-electrical behavior is made.

Control of a White Organic Light Emitting Diode emission parameters using a single doped RGB active layer

International Nuclear Information System (INIS)

Pereira, D.; Pinto, A.; Califórnia, A.; Gomes, J.; Pereira, L.

2016-01-01

Highlights: • A simple WOLED for Solid State Lighting is proposed with high color stability. • Energy transfer and electroluminescence dynamics of a single RGB layer for WOLEDs. • White shade modulation and stability over large emitting areas and applied voltages. - Abstract: Solid State Lighting technologies based on Organic Light Emitting Diodes, became an interesting focus due to their unique properties. The use of a unique RGB active layer for white emission, although simple in theory, shows difficulty to stabilize both CIE coordinates and color modulation. In this work, a WOLED using a simple RGB layer, was developed achieving a high color stability and shade modulation. The RGB matrix comprises a blue host material NPB, doped with two guests, a green (Coumarin 153) and a red (DCM1) in low concentrations. The RGB layer carrier dynamics allows for the white emission in low device complexity and high stability. This was also shown independent of the white shade, obtained through small changes in the red dopant resulting in devices ranging from warm to cool white i.e. an easy color tuning. A detailed analysis of the opto-electrical behavior is made.

Low driving voltage blue, green, yellow, red and white organic light-emitting diodes with a simply double light-emitting structure.

Science.gov (United States)

Zhang, Zhensong; Yue, Shouzhen; Wu, Yukun; Yan, Pingrui; Wu, Qingyang; Qu, Dalong; Liu, Shiyong; Zhao, Yi

2014-01-27

Low driving voltage blue, green, yellow, red and white phosphorescent organic light-emitting diodes (OLEDs) with a common simply double emitting layer (D-EML) structure are investigated. Our OLEDs without any out-coupling schemes as well as n-doping strategies show low driving voltage, e.g. white OLED, respectively. This work demonstrates that the low driving voltages and high efficiencies can be simultaneously realized with a common simply D-EML structure.

Preliminary measurement performance evaluation of a new white light interferometer for cylindrical surfaces

International Nuclear Information System (INIS)

Albertazzi, Armando Jr; Pont, Alex Dal

2005-01-01

This paper introduces a new design of a white light interferometer, suitable for measurement of cylindrical or quasi-cylindrical parts. A high precision 45 deg. conical mirror is used to direct collimated light radially, making it possible to measure in true cylindrical coordinates. The image of the measurand, distorted by the conical mirror, is projected in a high resolution digital camera. A mapping algorithm is used to reconstruct the cylindrical geometry from the distorted image. The rest of the interferometer is quite similar to a conventional white light interferometer: A flat reference mirror is scanned through the measurement range while an algorithm is searching for the maximum contrast position of the interference pattern. The performance evaluation of a configuration suitable for measurement of external cylindrical surfaces is also presented in this paper. A master cylinder was used as reference. Uncertainties of about 1.0 μm were found at the present stage of development

Simple process of hybrid white quantum dot/organic light-emitting diodes by using quantum dot plate and fluorescence

Science.gov (United States)

Lee, Ho Won; Lee, Ki-Heon; Lee, Jae Woo; Kim, Jong-Hoon; Yang, Heesun; Kim, Young Kwan

2015-02-01

In this work, the simple process of hybrid quantum dot (QD)/organic light-emitting diode (OLED) was proposed to apply a white illumination light by using QD plate and organic fluorescence. Conventional blue fluorescent OLEDs were firstly fabricated and then QD plates of various concentrations, which can be controlled of UV-vis absorption and photoluminescence spectrum, were attached under glass substrate of completed blue devices. The suggested process indicates that we could fabricate the white device through very simple process without any deposition of orange or red organic emitters. Therefore, this work would be demonstrated that the potential simple process for white applications can be applied and also can be extended to additional research on light applications.

Fabrication of Si/ZnS radial nanowire heterojunction arrays for white light emitting devices on Si substrates.

Science.gov (United States)

Katiyar, Ajit K; Sinha, Arun Kumar; Manna, Santanu; Ray, Samit K

2014-09-10

Well-separated Si/ZnS radial nanowire heterojunction-based light-emitting devices have been fabricated on large-area substrates by depositing n-ZnS film on p-type nanoporous Si nanowire templates. Vertically oriented porous Si nanowires on p-Si substrates have been grown by metal-assisted chemical etching catalyzed using Au nanoparticles. Isolated Si nanowires with needle-shaped arrays have been made by KOH treatment before ZnS deposition. Electrically driven efficient white light emission from radial heterojunction arrays has been achieved under a low forward bias condition. The observed white light emission is attributed to blue and green emission from the defect-related radiative transition of ZnS and Si/ZnS interface, respectively, while the red arises from the porous surface of the Si nanowire core. The observed white light emission from the Si/ZnS nanowire heterojunction could open up the new possibility to integrate Si-based optical sources on a large scale.

White organic light-emitting diodes with 9, 10-bis (2-naphthyl) anthracene

Energy Technology Data Exchange (ETDEWEB)

Guan Yunxia; Niu Lianbin [Key Laboratory of Optical Engineering, College of Physics and Information Technology, Chongqing Normal University, Chongqing 400047 (China)], E-mail: gyxybsy@126.com, E-mail: niulb03@126.com

2009-03-01

White organic light-emitting diodes were fabricated by 9, 10-bis (2-naphthyl) anthracene (ADN) doped with Rubrene with a structure of ITO/copper phthalocyanine (CuPc) / NPB /ADN: Rubrene /Alq{sub 3} /CsF/Mg:Ag/Ag. Multilayer organic devices using AND and Rubrene as an emitting layer produced white emissions with good chromaticity and luminous efficiency as high as 5.93 cd/A. This performance can be explained by Foerster energy transfer from the blue-emitting host to the orange-emitting dopant.

Generation of Langmuir wave supercontinuum by phase-preserving equilibration of plasmons with irreversible wave-particle interaction

Science.gov (United States)

Eiichirou, Kawamori

2018-04-01

We report the observation of supercontinuum of Langmuir plasma waves, that exhibits broad power spectrum having significant spatio-temporal coherence grown from a monochromatic seed-wave, in one-dimensional particle-in-cell simulations. The Langmuir wave supercontinuum (LWSC) is formed when the seed wave excites side-band fields efficiently by the modulational instabilities. Its identification is achieved by the use of the tricoherence analysis, which detects four wave mixings (FWMs) of plasmons (plasma wave quanta), and evaluation of the first order coherence, which is a measure of temporal coherence, of the wave electric fields. The irreversible evolution to the coherent LWSC from the seed wave is realized by the wave-particle interactions causing stochastic electron motions in the phase space and the coherence of LWSC is maintained by the phase-preserving FWMs of plasmons. The LWSC corresponds to a quasi Bernstein-Greene-Kruskal mode.

Modulation of the photoluminescence in carbon dots through surface modification: from mechanism to white light-emitting diodes

Science.gov (United States)

Zhu, Jinyang; Shao, He; Bai, Xue; Zhai, Yue; Zhu, Yongsheng; Chen, Xu; Pan, Gencai; Dong, Biao; Xu, Lin; Zhang, Hanzhuang; Song, Hongwei

2018-06-01

Carbon dots (CDs) have emerged as a new type of fluorescent material because of their unique optical advantages, such as high photoluminescence quantum yields (QYs), excellent photo-stability, excitation-dependent emissions, and low toxicity. However, the photoluminescence mechanism for CDs remains unclear, which limits their further practical application. Here, CDs were synthesized via a solvothermal route from citric acid and urea. Through the oxidation and reduction treatment of pristine CDs, the origin of the photoluminescence and the involved mechanism were revealed. We found that the blue/green/red emissions originated from three diverse emitting states, i.e. the intrinsic state, and C=O- and C=N-related surface states, respectively. Based on the as-prepared CDs, a pH sensor depending on the radiometric luminescence detection was developed. Furthermore, we constructed CD/PVP (PVP, polyvinylpyrrolidone) composite films, which exhibited white light emission with photoluminescence QYs of 15.3%. The white light emission with different correlated color temperatures (CCTs), from 4807 K to 3319 K, was obtained by simply changing the amount of PVP solution. Benefiting from the white light-emitting solid-state films, single-component white light-emitting diodes were fabricated with an average color rendering index value (Ra) of 80.0, luminous efficiency of 10.2 lm W‑1, and good working stability, thus indicating a promising potential for practical lighting applications.

Novel coherent supercontinuum light sources based on all-normal dispersion fibers

Energy Technology Data Exchange (ETDEWEB)

Heidt, Alexander

2011-07-05

The concept of broadband coherent supercontinuum (SC) generation in all-normal dispersion (ANDi) fibers in the near-infrared, visible and ultraviolet (UV) spectral regions is introduced and investigated in detail. In numerical studies, explicit design criteria are established for ANDi photonic crystal fiber (PCF) designs that allow the generation of flat and smooth ultrabroad spectral profiles without significant fine structure and with excellent stability and coherence properties. The key benefit of SC generation in ANDi fibers is the conservation of a single ultrashort pulse in the time domain with smooth and recompressible phase distribution. In the numerical investigation of the SC generation dynamics self-phase modulation and optical wave breaking are identified as the dominant nonlinear effects responsible for the nonlinear spectral broadening. It is further demonstrated that coherence properties, spectral bandwidth and temporal compressibility are independent of input pulse duration for constant peak power. The numerical predictions are in excellent agreement with experimental results obtained in two realizations of ANDi PCF optimized for the near-infrared and visible spectral region. In these experiments, the broadest SC spectrum generated in the normal dispersion regime of an optical fiber to date is achieved. The exceptional temporal properties of the generated SC pulses are verified experimentally and their applicability for the time-resolved study of molecular dynamics in ultrafast transient absorption spectroscopy is demonstrated. In an additional nonlinear pulse compression experiment, the SC pulses obtained in a short piece of ANDi PCF could be temporally recompressed to sub-two cycle durations by linear chirp compensation. Numerical simulations show that even shorter pulse durations with excellent quality can be achieved by full phase compensation. The concept is further extended into the UV spectral regime by considering tapered optical fibers with

Four-Parameter white blood cell differential counting based on light scattering measurements

NARCIS (Netherlands)

Terstappen, Leonardus Wendelinus Mathias Marie; de Grooth, B.G.; Visscher, K.; Kouterik, F.A.; Greve, Jan

1988-01-01

Measurement of the depolarized orthogonal light scattering in flow cytometry enables one to discriminate human eosinephilic granulocytes from neutrophilic granulocytes. We use this method to perform a four-parameter differential white blood cell analysis. A simple flow cytometer was built equipped

Effects of doping parameters on the CIE value of flexible white organic light emitting diodes

Energy Technology Data Exchange (ETDEWEB)

Juang Fuhshyang; Lin Mingyein; Yang Chanyi [Institute of Electro-Optical and Materials Science, National Huwei University of Science and Technology, Huwei, Yunlin (Taiwan); Tsai Yusheng [Department of Electro-Optics Engineering, National Huwei University of Science and Technology, Huwei, Yunlin (Taiwan); Lin, David [Windell Corporation, 1F, No. 9, Kung-Yen 7 Road, Industrial Zone, Taichung (Taiwan); Wang Wentunn; Shen Chaiyuan [Electronics Research and Service Organization, Industrial Technology Research Institute, 195 Chung Hsing Rd., Sec. 4 Chu Tung, Hsin Chu (Taiwan)

2004-09-01

Red dopants were doped in different emitters, blue and green, respectively, to fabricate white organic light emitting diodes on flexible substrates. The competitive emission between blue and red emitters with various doped-zones was studied. When the DCJT doped zone was located far away from the hole-injection layer, both the blue and red color can be emitted. An appropriate red-dopant position in the device enhanced the green emission from 8-hydroxyquinoline aluminum (Alq3) which was combined with the red and blue emission to generate a white light. Finally, a white emission with the CIE value, (0.30, 0.32), independent of the applied voltage, was obtained with the optimum doped width and location. (copyright 2004 WILEY-VCH Verlag GmbH and Co. KGaA, Weinheim) (orig.)

Real and virtual propagation dynamics of angular accelerating white light beams

CSIR Research Space (South Africa)

Vetter, C

2017-08-01

Full Text Available light modulators. References and links 1. H. Rubinsztein-Dunlop, A. Forbes, M. Berry, M. Dennis, D. L. Andrews, M. Mansuripur, C. Denz, C. Alpmann, P. Banzer, T. Bauer, E. Karimi, L. Marrucci, M. Padgett, M. Ritsch-Marte, N.M. Litchinitser, N. P. Bigelow...–678 (2008). 16. N. K. Efremidis and D. N. Christodoulides, “Abruptly autofocusing waves,” Opt. Lett. 35, 4045–4047 (2010). 17. R. Steiger, S. Bernet, and M. Ritsch-Marte, “Slm-based off-axis fourier filtering in microscopy with white light illumination,” Opt...

4-Gbit/s visible light communication link based on 16-QAM OFDM transmission over remote phosphor-film converted white light by using blue laser diode

KAUST Repository

Duran Retamal, Jose Ramon

2015-12-21

Visible Light Communication (VLC) as a new technology for ultrahigh-speed communication is still limited when using slow modulation light-emitting diode (LED). Alternatively, we present a 4-Gbit/s VLC system using coherent blue-laser diode (LD) via 16-quadrature amplitude modulation orthogonal frequency division multiplexing. By changing the composition and the optical-configuration of a remote phosphor-film the generated white light is tuned from cool day to neutral, and the bit error rate is optimized from 1.9 × 10-2 to 2.8 × 10-5 in a blue filter-free link due to enhanced blue light transmission in forward direction. Briefly, blue-LD is an alternative to LED for generating white light and boosting the data rate of VLC. © 2015 Optical Society of America.

4-Gbit/s visible light communication link based on 16-QAM OFDM transmission over remote phosphor-film converted white light by using blue laser diode

KAUST Repository

Duran Retamal, Jose Ramon; Oubei, Hassan M.; Janjua, Bilal; Chi, Yu-Chieh; Wang, Huai-Yung; Tsai, Cheng-Ting; Ng, Tien Khee; Hsieh, Dan-Hua; Kuo, Hao-Chung; Alouini, Mohamed-Slim; He, Jr-Hau; Lin, Gong-Ru; Ooi, Boon S.

2015-01-01

Visible Light Communication (VLC) as a new technology for ultrahigh-speed communication is still limited when using slow modulation light-emitting diode (LED). Alternatively, we present a 4-Gbit/s VLC system using coherent blue-laser diode (LD) via 16-quadrature amplitude modulation orthogonal frequency division multiplexing. By changing the composition and the optical-configuration of a remote phosphor-film the generated white light is tuned from cool day to neutral, and the bit error rate is optimized from 1.9 × 10-2 to 2.8 × 10-5 in a blue filter-free link due to enhanced blue light transmission in forward direction. Briefly, blue-LD is an alternative to LED for generating white light and boosting the data rate of VLC. © 2015 Optical Society of America.

Development of Advanced Manufacturing Methods for Warm White LEDs for General Lighting

Energy Technology Data Exchange (ETDEWEB)

Deshpande, Anirudha; Kolodin, Boris; Jacob, Cherian; Chowdhury, Ashfaqul; Kuenzler, Glenn; Sater, Karen; Aesram, Danny; Glaettli, Steven; Gallagher, Brian; Langer, Paul; Setlur, Anant; Beers, Bill

2012-03-31

GE Lighting Solutions will develop precise and efficient manufacturing techniques for the “remote phosphor” platform of warm-white LED products. In volume, this will be demonstrated to drive significant materials, labor and capital productivity to achieve a maximum possible 53% reduction in overall cost. In addition, the typical total color variation for these white LEDs in production will be well within the ANSI bins and as low as a 4-step MacAdam ellipse centered on the black body curve. Achievement of both of these objectives will be demonstrated while meeting a performance target of > 75 lm/W for a warm-white LED and a reliability target of <30% lumen drop / <2-step MacAdam ellipse shift, estimated over 50,000 hrs.

White organic light-emitting devices incorporating nanoparticles of II-VI semiconductors

International Nuclear Information System (INIS)

Ahn, Jin H; Bertoni, Cristina; Dunn, Steve; Wang, Changsheng; Talapin, Dmitri V; Gaponik, Nikolai; Eychmueller, Alexander; Hua Yulin; Bryce, Martin R; Petty, Michael C

2007-01-01

A blue-green fluorescent organic dye and red-emitting nanoparticles, based on II-VI semiconductors, have been used together in the fabrication of white organic light-emitting devices. In this work, the materials were combined in two different ways: in the form of a blend, and as separate layers deposited on the opposite sides of the substrate. The blended-layer structure provided purer white emission. However, this device also exhibited a number of disadvantages, namely a high drive voltage, a low efficiency and some colour instability. These problems could be avoided by using a device structure that was fabricated using separate dye and nanoparticle layers

Color Rendering Index Thermal Stability Improvement of Glass-Based Phosphor-Converted White Light-Emitting Diodes for Solid-State Lighting

Directory of Open Access Journals (Sweden)

Chun-Chin Tsai

2014-01-01

Full Text Available High color rendering index performance has been required for phosphor-converted warm-white light-emitting diodes (PC-WWLEDs in lighting industry. The characteristics of low-temperature fabricated phosphor (yellow: Ce3+:YAG, green: Tb3+:YAG, and red: CaAlClSiN3:Eu2+ doped glass were presented for applications to high color rendering index warm-white-light-emitting diodes. Color coordinates (x, y = (0.36, 0.29, quantum yield (QY = 55.6%, color rending index (CRI = 85.3, and correlated color temperature (CCT = 3923 K were characterized. Glass-based PC-WWLEDs was found able to maintain good thermal stability for long-time high-temperature operation. QY decay, CRI remenance, and chromaticity shift were also analyzed for glass- and silicone-based high-power PC-WLEDs by thermal aging at 150°C and 250°C for industrial test standard’s aging time 1008 hours. Better than the silicone’s, thermal stability of glass-based PC-WLEDs has been improved. The resulted high color rendering index (CRI glass phosphor potentially can be used as a phosphor layer for high-performance and low-cost PC-WLEDs used in next-generation indoor solid-state lighting applications.

White light generation tuned by dual hybridization of nanocrystals and conjugated polymers

Energy Technology Data Exchange (ETDEWEB)

Demir, Hilmi Volkan [Devices and Sensors Group and Nanotechnology Research Center, Bilkent University, Ankara 06800 (Turkey); Nizamoglu, Sedat [Devices and Sensors Group and Nanotechnology Research Center, Bilkent University, Ankara 06800 (Turkey); Ozel, Tuncay [Devices and Sensors Group and Nanotechnology Research Center, Bilkent University, Ankara 06800 (Turkey); Mutlugun, Evren [Devices and Sensors Group and Nanotechnology Research Center, Bilkent University, Ankara 06800 (Turkey); Huyal, Ilkem Ozge [Devices and Sensors Group and Nanotechnology Research Center, Bilkent University, Ankara 06800 (Turkey); Sari, Emre [Devices and Sensors Group and Nanotechnology Research Center, Bilkent University, Ankara 06800 (Turkey); Holder, Elisabeth [Functional Polymers Group and Institute of Polymer Technology, University of Wuppertal, Gaussstrasse 20, D-42097 Wuppertal (Germany); Tian Nan [Functional Polymers Group and Institute of Polymer Technology, University of Wuppertal, Gaussstrasse 20, D-42097 Wuppertal (Germany)

2007-10-15

Dual hybridization of highly fluorescent conjugated polymers and highly luminescent nanocrystals (NCs) is developed and demonstrated in multiple combinations for controlled white light generation with high color rendering index (CRI) (> 80) for the first time. The generated white light is tuned using layer-by-layer assembly of CdSe/ZnS core-shell NCs closely packed on polyfluorene, hybridized on near-UV emitting nitride-based light emitting diodes (LEDs). The design, synthesis, growth, fabrication and characterization of these hybrid inorganic-organic white LEDs are presented. The following experimental realizations are reported: (i) layer-by-layer hybridization of yellow NCs ({lambda}{sub PL}=580 nm) and blue polyfluorene ({lambda}{sub PL}=439 nm) with tristimulus coordinates of (x, y)=(0.31, 0.27), correlated color temperature of T{sub c}=6962 K and CRI of R{sub a}=53.4; (ii) layer-by-layer assembly of yellow and green NCs ({lambda}{sub PL}=580 and 540 nm) and blue polyfluorene ({lambda}{sub PL}=439 nm) with (x, y)=(0.23, 0.30), T{sub c}=14395 K and R{sub a}=65.7; and (iii) layer-by-layer deposition of yellow, green and red NCs ({lambda}{sub PL}=580, 540 and 620 nm) and blue polyfluorene ({lambda}{sub PL}=439 nm) with (x, y)=(0.38, 0.39), T{sub c}=4052 K and R{sub a}= 83.0. The CRI is demonstrated to be well controlled and significantly improved by increasing multi-chromaticity of the NC and polymer emitters.

White electroluminescence from ZnO nanorods/p-GaN heterojunction light-emitting diodes under reverse bias

International Nuclear Information System (INIS)

Zhang, Lichun; Li, Qingshan; Qu, Chong; Zhang, Zhongjun; Huang, Ruizhi; Zhao, Fengzhou

2013-01-01

Heterojunction light-emitting diodes (LEDs) based on arrays of ZnO nanorods were fabricated on p-GaN films by the hydrothermal method. Without any phosphors, white-light electroluminescence (EL) from ZnO nanorods/p-GaN heterojunction LEDs operated at reverse breakdown bias was observed. The EL spectra are composed of an ultraviolet (UV) emission centered at 382 nm, a blue light located at 431 nm and a broadband yellow–green light at around 547 nm, which originated from band-edge emission in ZnO, the Mg acceptor levels in p-GaN and the deep-level states near the ZnO/GaN interface, respectively. The chromaticity coordinates of EL spectrum are very close to the (0.333, 0.333) of standard white light. The origin of these emissions has been discussed and the tunneling effect in the interface is probably the mechanism to explain EL emission. (paper)

High power, ultra-broadband supercontinuum source based on highly GeO2 doped silica fiber

DEFF Research Database (Denmark)

Jain, Deepak; Sidharthan, Raghuraman; Moselund, Peter M.

2017-01-01

We demonstrate a 74 mol % GeO2 doped fiber for mid-infrared supercontinuum generation. Experiments ensure a highest output power for a broadest spectrum from 700nm to 3200nm from this fiber, while being pumped by a broadband 4 stage Erbium fiber based MOPA. The effect of repetition rate of pump...

Polaron Self-localization in White-light Emitting Hybrid Perovskites

OpenAIRE

Cortecchia, Daniele; Yin, Jun; Bruno, Annalisa; Lo, Shu-Zee Alencious; Gurzadyan, Gagik G.; Mhaisalkar, Subodh; Brédas, Jean-Luc; Soci, Cesare

2016-01-01

Two-dimensional (2D) perovskites with general formula $APbX_4$ are attracting increasing interest as solution processable, white-light emissive materials. Recent studies have shown that their broadband emission is related to the formation of intra-gap color centers; however, the nature and dynamics of the emissive species have remained elusive. Here we show that the broadband photoluminescence of the 2D perovskites $(EDBE)PbCl_4$ and $(EDBE)PbBr_4$ stems from the localization of small polaron...

Microwave-assisted one-step synthesis of white light-emitting carbon dot suspensions

Science.gov (United States)

Vanessa, Hinterberger; Wenshuo, Wang; Cornelia, Damm; Simon, Wawra; Martin, Thoma; Wolfgang, Peukert

2018-06-01

In this contribution, we demonstrate that an aqueous solution with adjustable fluorescent color, including white light emission, can be achieved by a rapid one-step microwave synthesis method resulting in a mixture of blue-emitting carbon dots (CDs) and the yellow-emitting 2,3-diaminophenazine (DAP). Aqueous mixtures of o-phenylene-diamine (oPD) and citric acid (CA) are used as precursors. The resulting product structures are analyzed by FT-IR and NMR spectroscopy and the size of the resulting CDs is determined by atomic force microscopy to be 1.1 ± 0.3 nm. The synthesized solution exhibits two fluorescence emission peaks at 430 and 560 nm, which were found to originate from the CDs and DAP, respectively. The intensity ratio of both fluorescence peaks depends on pH, which is driven by the protonation state of DAP. In consequence, the fluorescence emission color of the CD solution can be tuned precisely and reproducibly from blue to white to yellow by careful control of the pH. Finally, at a pH level of 5.4, at which there is equal blue and yellow emission intensity, a white light emitting solution can be successfully produced in a very fast and simple synthesis procedure.

Low-intensity blue-enriched white light (750 lux) and standard bright light (10 000 lux) are equally effective in treating SAD. A randomized controlled study

NARCIS (Netherlands)

Meesters, Ybe; Dekker, Vera; Schlangen, Luc J. M.; Bos, Elske H.; Ruiter, Martine J.

2011-01-01

Background: Photoreceptor cells containing melanopsin play a role in the phase-shifting effects of short-wavelength light. In a previous study, we compared the standard light treatment (SLT) of SAD with treatment using short-wavelength blue-enriched white light (BLT). Both treatments used the same

Nonlinearity-tailored fiber laser technology for low-noise, ultra-wideband tunable femtosecond light generation

DEFF Research Database (Denmark)

Liu, Xiaomin; Lægsgaard, Jesper; Iegorov, Roman

2017-01-01

supercontinuum, taking advantage of a simpler fiber technology: a fixed-wavelength pump laser pulse is converted into a spectrally very broadband output, from which the required resulting wavelength is then optically filtered. Unfortunately, this process is associated with an inherently poor noise figure, which...... often precludes many realistic applications of such supercontinuum sources. Here, we show that by adding only one passive optical element—a tapered photonic crystal fiber—to a fixed-wavelength femtosecond laser, one can in a very simple manner resonantly convert the laser emission wavelength......The emission wavelength of a laser is physically predetermined by the gain medium used.Consequently,arbitrary wavelength generation is a fundamental challenge in the science of light. Present solutions include optical parametric generation, requiring complex optical setups and spectrally sliced...

White Light Generation and Anisotropic Damage in Gold Films near Percolation Threshold

DEFF Research Database (Denmark)

Novikov, Sergey M.; Frydendahl, Christian; Beermann, Jonas

2017-01-01

in vanishingly small gaps between gold islands in thin films near the electrically determined percolation threshold. Optical explorations using two-photon luminescence (TPL) and near-field microscopies reveals supercubic TPL power dependencies with white-light spectra, establishing unequivocally...... that the strongest TPL signals are generated close to the percolation threshold films, and occurrence of extremely confined (similar to 30 nm) and strongly enhanced (similar to 100 times) fields at the illumination wavelength. For linearly polarized and sufficiently powerful light, we observe pronounced optical...

4.5 W supercontinuum generation from 1017 to 3438 nm in an all-solid fluorotellurite fiber

Science.gov (United States)

Jia, Zhixu; Yao, Chuanfei; Jia, Shijie; Wang, Fang; Wang, Shunbin; Zhao, Zhipeng; Qin, Guanshi; Ohishi, Yasutake; Qin, Weiping

2017-06-01

All-solid fluorotellurite fibers are fabricated by using a rod-in-tube method. The core and cladding materials are TeO2-BaF2-Y2O3 (TBY) and AlF3-based glasses, respectively. Since the refractive index (˜1.46) of AlF3-based glass is much lower than that (˜1.84) of TBY glass, the zero-dispersion-wavelength of the fabricated fiber can be tuned from 2145 to 1507 nm by varying the fiber core diameter from 50 to 3 μm. By using a 0.6 m long all-solid fluorotellurite fiber with a core diameter of ˜7 μm as the nonlinear medium and a 2 μm femtosecond fiber laser as the pump source, 4.5 W supercontinuum (SC) generation from 1017 to 3438 nm is obtained for a launched pump power of ˜10.48 W. The corresponding optical-to-optical conversion efficiency is about 42.9%. In addition, no any damage of the fluorotellurite fiber is observed during the operation of the above SC light source. Our results show that all-solid fluorotellurite fibers are promising nonlinear media for constructing high power mid-infrared SC light sources.

White-light-emitting diode based on a single-layer polymer

Science.gov (United States)

Wang, B. Z.; Zhang, X. P.; Liu, H. M.

2013-05-01

A broad-band light-emitting diode was achieved in a single-layer device based on pure poly(9,9'-dioctylfluorene-co-bis-N,N'-(4-butylphenyl)-bis-N,N'-phenyl-1,4-phenylenediamine) (PFB). Electromer emission was observed in the red with a center wavelength of about 620 nm in electroluminescence (EL) spectrum. This kind of emission exhibits strong dependence on the thickness of the PFB layer, so that the shape of the EL spectrum may be adjusted through changing the thickness of the active polymer layer to balance between the intrinsic PFB emission in the blue and the electromer emission in the red. Thus, white light emission may be achieved from such a single-layer single-material diode.

Ultrabroad linewidth orange-emitting nanowires LED for high CRI laser-based white lighting and gigahertz communications

KAUST Repository

Janjua, Bilal

2016-08-10

Group-III-nitride laser diode (LD)-based solid-state lighting device has been demonstrated to be droop-free compared to light-emitting diodes (LEDs), and highly energy-efficient compared to that of the traditional incandescent and fluorescent white light systems. The YAG:Ce3+ phosphor used in LD-based solid-state lighting, however, is associated with rapid degradation issue. An alternate phosphor/LD architecture, which is capable of sustaining high temperature, high power density, while still intensity- and bandwidth-tunable for high color-quality remained unexplored. In this paper, we present for the first time, the proof-of-concept of the generation of high-quality white light using an InGaN-based orange nanowires (NWs) LED grown on silicon, in conjunction with a blue LD, and in place of the compound-phosphor. By changing the relative intensities of the ultrabroad linewidth orange and narrow-linewidth blue components, our LED/LD device architecture achieved correlated color temperature (CCT) ranging from 3000 K to above 6000K with color rendering index (CRI) values reaching 83.1, a value unsurpassed by the YAG-phosphor/blue-LD counterpart. The white-light wireless communications was implemented using the blue LD through on-off keying (OOK) modulation to obtain a data rate of 1.06 Gbps. We therefore achieved the best of both worlds when orange-emitting NWs LED are utilized as “active-phosphor”, while blue LD is used for both color mixing and optical wireless communications.

Optimizing white light luminescence in Dy3+-doped Lu3Ga5O12 nano-garnets

International Nuclear Information System (INIS)

Haritha, P.; Linganna, K.; Venkatramu, V.; Martín, I. R.; Monteseguro, V.; Rodríguez-Mendoza, U. R.; Babu, P.; León-Luis, S. F.; Jayasankar, C. K.; Lavín, V.

2014-01-01

Trivalent dysprosium-doped Lu 3 Ga 5 O 12 nano-garnets have been prepared by sol-gel method and characterized by X-ray powder diffraction, high-resolution transmission electron microscopy, dynamic light scattering, and laser excited spectroscopy. Under a cw 457 nm laser excitation, the white luminescence properties of Lu 3 Ga 5 O 12 nano-garnets have been studied as a function of the optically active Dy 3+ ion concentration and at low temperature. Decay curves for the 4 F 9/2 level of Dy 3+ ion exhibit non-exponential nature for all the Dy 3+ concentrations, which have been well-fitted to a generalized energy transfer model for a quadrupole-quadrupole interaction between Dy 3+ ions without diffusion. From these data, a simple rate-equations model can be applied to predict that intense white luminescence could be obtained from 1.8 mol% Dy 3+ ions-doped nano-garnets, which is in good agreement with experimental results. Chromaticity color coordinates and correlated color temperatures have been determined as a function of temperature and are found to be within the white light region for all Dy 3+ concentrations. These results indicate that 2.0 mol% Dy 3+ ions doped nano-garnet could be useful for white light emitting device applications

White light spectral interferometer for measuring dispersion in the visible-near infrared

Science.gov (United States)

Arosa, Yago; Rodríguez Fernández, Carlos Damian; Algnamat, Bilal S.; López-Lago, Elena; de la Fuente, Raul

2017-08-01

We have designed a spectrally resolved interferometer to measure the refractive index of transparent samples over a wide spectral band from 400 to 1550 nm. The measuring device consists of a Michelson interferometer whose output is analyzed by means of three fiber spectrometers. The first one is a homemade prism spectrometer, which obtains the interferogram produced by the sample over 400 to 1050 nm; the second one is a homemade transmission grating spectrometer thought to measure the interferogram in the near infrared spectral band from 950 to 1550 nm; the last one is a commercial Czerny-Turner spectrometer used to make high precision measurements of the displacement between the Michelson mirrors also using white light interferometry. The whole system is illuminated by a white light source with an emission spectrum similar to black body. We have tested the instrument with solid and liquids samples achieving accuracy to the fourth decimal on the refractive index after fitting it to a Cauchy formula

Capturing triplet emission in white organic light emitting devices

Energy Technology Data Exchange (ETDEWEB)

Singh, Jai [Faculty of EHSE, School of Engineering and IT, B-purple-12, Charles Darwin University, Darwin, NT 0909 (Australia)

2011-08-15

The state-of-the art in the white organic light emitting devices (WOLEDs) is reviewed for further developments with a view to enhance the capture of triplet emission. In particular, applying the new exciton-spin-orbit-photon interaction operator as a perturbation, rates of spontaneous emission are calculated in a few phosphorescent materials and compared with experimental results. For iridium based phosphorescent materials the rates agree quite well with the experimental results. (Copyright copyright 2011 WILEY-VCH Verlag GmbH and Co. KGaA, Weinheim)

Supercontinuum generation in silicon nanowire embedded photonic crystal fibers with different core geometries

Science.gov (United States)

Abdosllam, M. Abobaker; Gunasundari, E.; Senthilnathan, K.; Sivabalan, S.; Nakkeeran, K.; Ramesh Babu, P.

2014-07-01

We design various silicon nanowire embedded photonic crystal fibers (SN-PCFs) with different core geometries, namely, circular, rectangular and elliptical using finite element method. Further, we study the optical properties such as group velocity dispersion (GVD), third order dispersion (TOD) of x and y-polarized modes and effective nonlinearity for a wavelength range from 0.8 to 1.6 μm. The proposed structure exhibits almost flat GVD (0.8 to 1.2 μm wavelength), zero GVD (≍ 1.31 μm) and small TOD (0.00069 ps3/m) at 1.1 μm wavelength and high nonlinearity (2916 W-1m-1) at 0.8 μm wavelength for a 300 nm core diameter of circular core SN-PCF. Besides, we have been able to demonstrate the supercontinuum for the different core geometries at 1.3 μm wavelength with a less input power of 25 W for the input pulse of 20 fs. The numerical simulation results reveal that the proposed circular core SN-PCF could generate the supercontinuum of wider bandwidth (900 nm) compared to that from rest of the geometries. This enhanced bandwidth turns out to be a boon for optical coherence tomography (OCT) system.

Color-tunable and stable-efficiency white organic light-emitting diode fabricated with fluorescent-phosphorescent emission layers

International Nuclear Information System (INIS)

Yang, Su-Hua; Shih, Po-Jen; Wu, Wen-Jie; Huang, Yi-Hua

2013-01-01

White organic light emitting diodes (OLEDs) were fabricated for color-tunable lighting applications. Fluorescent and phosphorescent hybrid emission layers (EMLs) were used to enhance the luminance and stability of the devices, which have blue-EML/CBP interlayer/green-EML/phosphorescent-sensitized-EML/red-EML structures. The influence of the composition and structure of the EMLs on the electroluminescence properties of the devices were investigated from the viewpoint of their emission spectra. The possible exciton harvesting, diffusion, transport, and annihilation processes occurring in the EMLs were also evaluated. A maximum luminance intensity of 7400 cd/m 2 and a highly stable current efficiency of 3.2 cd/A were obtained. Good color tunability was achieved for the white OLEDs; the chromatic coordinates linearly shifted from pure white (0.300, 0.398) to cold white (0.261, 0.367) when the applied voltage was varied from 10 to 14 V. -- Highlights: • Exciton harvesting, diffusion, transport, and annihilation processes were evaluated. • The electroluminescence properties were investigated from the viewpoint of the emission spectra. • Good color tunability and stable-efficiency were achieved for the white OLEDs

Measuring the Dispersion in Laser Cavity Mirrors using White-Light Interferometry

Science.gov (United States)

2008-03-01

mirrors. Two AlGaInP (aluminum gallium indium phosphide ) diode lasers are aligned such that one is polarized vertically while one is polarized...linear crystals, where the index of refraction depends on beam intensity. Short pulses with high peak intensities are well 14 suited to induce the...MEASURING THE DISPERSION OF LASER CAVITY MIRRORS USING WHITE-LIGHT INTERFEROMETRY THESIS Allison S

Enhancement of sensitivity and bandwidth of gravitational wave detectors using fast-light-based white light cavities

International Nuclear Information System (INIS)

Salit, M; Shahriar, M S

2010-01-01

The effect of gravitational waves (GWs) has been observed indirectly, by monitoring the change in the orbital frequency of neutron stars in a binary system as they lose energy via gravitational radiation. However, GWs have not yet been observed directly. The initial LIGO apparatus has not yet observed GWs. The advanced LIGO (AdLIGO) will use a combination of improved techniques in order to increase the sensitivity. Along with power recycling and a higher power laser source, the AdLIGO will employ signal recycling (SR). While SR would increase sensitivity, it would also reduce the bandwidth significantly. Previously, we and others have investigated, theoretically and experimentally, the feasibility of using a fast-light-based white light cavity (WLC) to circumvent this constraint. However, in the previous work, it was not clear how one would incorporate the white light cavity effect. Here, we first develop a general model for Michelson-interferometer-based GW detectors that can be easily adapted to include the effects of incorporating a WLC into the design. We then describe a concrete design of a WLC constructed as a compound mirror, to replace the signal recycling mirror. This design is simple, robust, completely non-invasive, and can be added to the AdLIGO system without changing any other optical elements. We show a choice of parameters for which the signal sensitivity as well as the bandwidth are enhanced significantly over what is planned for the AdLIGO, covering the entire spectrum of interest for gravitational waves

Limits of computational white-light holography

International Nuclear Information System (INIS)

Mader, Sebastian; Kozacki, Tomasz; Tompkin, Wayne

2013-01-01

Recently, computational holograms are being used in applications, where previously conventional holograms were applied. Compared to conventional holography, computational holography is based on imaging of virtual objects instead of real objects, which renders them somewhat more flexibility. Here, computational holograms are calculated based on the superposition of point sources, which are placed at the mesh vertices of arbitrary 3D models. The computed holograms have full parallax and exhibit a problem in viewing that we have called g hosting , which is linked to the viewing of computational holograms based on 3D models close to the image plane. Experimental white-light reconstruction of these holograms showed significant blurring, which is explained here based on simulations of the lateral as well as the axial resolution of a point image with respect to the source spectrum and image distance. In accordance with these simulations, an upper limit of the distance to the image plane is determined, which ensures high quality imaging.

White light scanner-based repeatability of 3-dimensional digitizing of silicon rubber abutment teeth impressions.

Science.gov (United States)

Jeon, Jin-Hun; Lee, Kyung-Tak; Kim, Hae-Young; Kim, Ji-Hwan; Kim, Woong-Chul

2013-11-01

The aim of this study was to evaluate the repeatability of the digitizing of silicon rubber impressions of abutment teeth by using a white light scanner and compare differences in repeatability between different abutment teeth types. Silicon rubber impressions of a canine, premolar, and molar tooth were each digitized 8 times using a white light scanner, and 3D surface models were created using the point clouds. The size of any discrepancy between each model and the corresponding reference tooth were measured, and the distribution of these values was analyzed by an inspection software (PowerInspect 2012, Delcamplc., Birmingham, UK). Absolute values of discrepancies were analyzed by the Kruskal-Wallis test and multiple comparisons (α=.05). The discrepancy between the impressions for the canine, premolar, and molar teeth were 6.3 µm (95% confidence interval [CI], 5.4-7.2), 6.4 µm (95% CI, 5.3-7.6), and 8.9 µm (95% CI, 8.2-9.5), respectively. The discrepancy of the molar tooth impression was significantly higher than that of other tooth types. The largest variation (as mean [SD]) in discrepancies was seen in the premolar tooth impression scans: 26.7 µm (95% CI, 19.7-33.8); followed by canine and molar teeth impressions, 16.3 µm (95% CI, 15.3-17.3), and 14.0 µm (95% CI, 12.3-15.7), respectively. The repeatability of the digitizing abutment teeth's silicon rubber impressions by using a white light scanner was improved compared to that with a laser scanner, showing only a low mean discrepancy between 6.3 µm and 8.9 µm, which was in an clinically acceptable range. Premolar impression with a long and narrow shape showed a significantly larger discrepancy than canine and molar impressions. Further work is needed to increase the digitizing performance of the white light scanner for deep and slender impressions.

Strong white light emission from a processed porous silicon and its photoluminescence mechanism

International Nuclear Information System (INIS)

Karacali, T.; Cicek, K.

2011-01-01

We have prepared various porous silicon (PS) structures with different surface conditions (any combination of oxidation, carbonization as well as thermal annealing) to increase the intensity of photoluminescence (PL) spectrum in the visible range. Strong white light (similar to day-light) emission was achieved by carrying out thermal annealing at 1100 deg. C after surface modification with 1-decene of anodic oxidized PS structures. Temperature-dependent PL measurements were first performed by gradually increasing the sample temperature from 10 to 300 K inside a cryostat. Then, we analyzed the measured spectrum of all prepared samples. After the analysis, we note that throughout entire measured spectrum, only two main peaks corresponding to blue and green-orange emission lines (which can be interpreted by quantum size effect and/or configuration coordinate model) were seem to be predominant for all temperature range. To further reveal and analysis these peaks, finally, measured data were inputted into the formula of activation energy of thermal excitation. We found that activation energies of blue and green-orange lines were approximately 49.3 and 44.6 meV, respectively. - Highlights: →Light emitting devices based on silicon technology are of great interest in illumination and display applications. → We have achieved strong white light (similar to day-light) emission from porous silicon. → The most important impact of carbonization on porous silicon and post annealing is the enhancement of room temperature luminescence.

Hybrid Structure White Organic Light Emitting Diode for Enhanced Efficiency by Varied Doping Rate.

Science.gov (United States)

Kim, Dong-Eun; Kang, Min-Jae; Park, Gwang-Ryeol; Kim, Nam-Kyu; Lee, Burm-Jong; Kwon, Young-Soo; Shin, Hoon-Kyu

2016-03-01

Novel materials based on Zn(HPB)2 and Ir-complexes were synthesized as blue or red emitters, respectively. White organic light emitting diodes were fabricated using the Zn(HPB)2 as a blue emitting layer, Ir-complexes as a red emitting layer and Alq3 as a green emitting layer. The obtained experimental results, were based on white OLEDs fabricated using double emission layers of Zn(HPB)2 and Alq3:Ir-complexes. The doping rate of the Ir-complexes was varied at 0.4%, 0.6%, 0.8% and 1.0%. When the doping rate of the Alq3:Ir-complexes was 0.6%, a white emission was achieved. The Commission Internationale de l'Eclairage coordinates of the device's white emission were (0.316, 0.331) at an applied voltage of 10.75 V.

White light emission and effect of annealing on the Ho3+–Yb3+ codoped BaCa2Al8O15 phosphor

International Nuclear Information System (INIS)

Kumari, Astha; Rai, Vineet Kumar

2015-01-01

Graphical abstract: The upconversion emission spectra of the Ho 3+ /Yb 3+ doped/codoped BaCa 2 Al 8 O 15 phosphors with different doping concentrations of Ho 3+ /Yb 3+ ions along with UC emission spectrum of the white light emitting phosphor annealed at 800 °C. - Highlights: • BaCa 2 Al 8 O 15 phosphors codoped with Ho 3+ –Yb 3+ have been prepared by combustion method. • Phosphor annealed at 800 °C, illuminate an intense white light upon NIR excitation. • The sample annealed at higher temperatures emits in the pure green region. • The colour emitted persists in the white region even at high pump power density. • Developed phosphor is suitable for making upconverters and WLEDs. - Abstract: The BaCa 2 Al 8 O 15 (BCAO) phosphors codoped with suitable Ho 3+ –Yb 3+ dopant concentration prepared by combustion method illuminate an intense white light upon near infrared diode laser excitation. The structural analysis of the phosphors and the detection of impurity contents have been performed by using the X-Ray Diffraction, FESEM and FTIR analysis. The purity of white light emitted from the sample has been confirmed by the CIE chromaticity diagram. Also, the white light emitted from the sample persists with the variation of pump power density. The phosphors emit upconversion (UC) emission bands in the blue, green and red region (three primary colours required for white light emission) along with one more band in the near infrared region of the electromagnetic spectrum. On annealing the white light emitting sample at higher temperatures, the sample starts to emit green colour and also the intensity of green and red UC emission bands get enhanced largely.

A white organic light emitting diode with improved stability

International Nuclear Information System (INIS)

Zhang Zhilin; Jiang Xueyin; Zhu Wenqing; Zhang Buxin; Xu Shaohong

2001-01-01

A white organic light emitting diode (OLED) has been constructed by employing a new blue material and a red dye directly doped in the blue emitting layer. For comparison, another white cell with a blocking layer has also been made. The configurations of the devices are ITO/CuPc/NPB/JBEM(P):DCJT/Alq/MgAg (device 1) and ITO/CuPc/NPB/TPBi:DCJT/Alq/MgAg (device 2) where copper phthalocyanine (CuPc) is the buffer layer, N,N'-bis-(1-naphthyl)-N,N'-diphenyl-1.1'bipheny1-4-4'-diamine (NPB) is the hole transporting layer, 9,10-bis(3'5'-diaryl)phenyl anthracene doped with perylene (JBEM(P)) is the new blue emitting material, N,arylbenzimidazoles (TPBi) is the hole blocking layer, tris(8-quinolinolato)aluminium complex (Alq) is the electron transporting layer, and DCJT is a red dye. A stable and current independent white OLED has been obtained in device 1, which has a maximum luminance of 14 850 cd m -2 , an efficiency of 2.88 Lm W -1 , Commission Internationale de l'Eclairage coordinates of x=0.32, y=0.38 between 4-200 mA cm -2 , and a half lifetime of 2860 h at the starting luminance of 100 cd m -2 . Device 1 has a stability more than 50 times better than that of device 2. (author)

Steering and filtering white light with resonant waveguide gratings

Science.gov (United States)

Quaranta, Giorgio; Basset, Guillaume; Martin, Olivier J. F.; Gallinet, Benjamin

2017-08-01

A novel thin-film single-layer structure based on resonant waveguide gratings (RWGs) allows to engineer selective color filtering and steering of white light. The unit cell of the structure consists of two adjacent finite-length and cross-talking RWGs, where the former acts as in-coupler and the latter acts as out-coupler. The structure is made by only one nano-imprint lithography replication and one thin film layer deposition, making it fully compatible with up-scalable fabrication processes. We characterize a fabricated optical security element designed to work with the flash and the camera of a smartphone in off-axis light steering configuration, where the pattern is revealed only by placing the smartphone in the proper position. Widespread applications are foreseen in a variety of fields, such as multifocal or monochromatic lenses, solar cells, biosensors, security devices and seethrough optical combiners for near-eye displays.

Red, green, blue and white light upconversion emission in Yb3+/Tm3+/Ho3+ co-doped tellurite glasses

International Nuclear Information System (INIS)

Desirena, H; De la Rosa, E; Meza, O; Salas, P

2011-01-01

Several Yb 3+ /Tm 3+ /Ho 3+ co-doped transparent TeO 2 -ZnO-Na 2 O-Yb 2 O 3 -Ho 2 O 3 -Tm 2 O 3 glasses were prepared and luminescence properties were characterized. Simultaneous red, green and blue (RGB) emission were obtained after excitation at 970 nm. Colour emission was tuned from multicolour to white light with colour coordinate (0.32, 0.33) matching very well with the white reference (0.33, 0.33). Changes in colour emission were obtained by varying the intensity ratios between RGB bands that are strongly concentration dependent because of the interaction of co-dopants. The colour tunability, high quality of white light and high intensity of the emitted signal make these transparent glasses excellent candidates for applications in solid-state lighting.

Attraction of Rhagoletis indifferens (Diptera: Tephitidae) to white light in the presence and absence of ammonia

Science.gov (United States)

Attraction of tephritid fruit flies to light and its role in fly biology and management has received little attention. Here, the objective was to show that western cherry fruit fly, Rhagoletis indifferens Curran (Diptera: Tephritidae), is attracted to white light in the presence and absence of ammo...

Generation of a mid-infrared broadband polarized supercontinuum in As2Se3 photonic crystal fibers

International Nuclear Information System (INIS)

Wang Xiao-Yan; Li Shu-Guang; Liu Shuo; Yin Guo-Bing; Li Jian-She

2012-01-01

A simplified structure of birefringent chalcogenide As 2 Se 3 photonic crystal fiber (PCF) is designed. Properties of birefringence, polarization extinction ratio, chromatic dispersion, nonlinear coefficient, and transmission are studied by using the multipole method, the finite-difference beam propagation method, and the adaptive split-step Fourier method. Considering that the zero dispersion wavelength of our proposed fiber is about 4 μm, we have analysed the mechanism of spectral broadening in PCFs with different pitches in detail, with femtosecond pulses at a wavelength of 4 μm as the pump pulses. Especially, mid-infrared broadband polarized supercontinuums are obtained in a 3-cm PCF with an optimal pitch of 2 μm. Their spectral width at −20 dB reaches up to 12 μm. In the birefringent PCF, we find that the supercontinuum generation changes with the pump alignment angle. Research results show that no coupling between eigenpolarization modes are observed at the maximum average power (i.e., 37 mW), which indicates that the polarization state is well maintained. (electromagnetism, optics, acoustics, heat transfer, classical mechanics, and fluid dynamics)

Highly-nonlinear polarization-maintaining As2Se3-based photonic quasi-crystal fiber for supercontinuum generation

Science.gov (United States)

Zhao, Tongtong; Lian, Zhenggang; Benson, Trevor; Wang, Xin; Zhang, Wan; Lou, Shuqin

2017-11-01

We propose an As2Se3-based photonic quasi-crystal fiber (PQF) with high nonlinearity and birefringence. By optimizing the structure parameters, a nonlinear coefficient up to 2079 W-1km-1 can be achieved at the wavelength of 2 μm; the birefringence reaches up to the order of 10-2 due to the introduction of large circular air holes in the cladding. Using an optical pulse with a peak power of 6 kW, a pulse width of 150 fs, and a central wavelength of 2.94 μm as the pump pulse, a mid-infrared polarized supercontinuum is obtained by using a 15 mm long PQF. The spectral width for x- and y-polarizations covers 1 μm-10.2 μm and 1 μm-12.5 μm, respectively. The polarization state can be well maintained when the incident angle of the input pulse changes within ±2°. The proposed PQF, with high nonlinear coefficient and birefringence, has potential applications in mid-infrared polarization-maintaining supercontinuum generation.

Suppression of Hydrogen Emission in an X-class White-light Solar Flare

Energy Technology Data Exchange (ETDEWEB)

Procházka, Ondrej; Milligan, Ryan O.; Mathioudakis, Mihalis [Astrophysics Research Centre, Queen’s University Belfast, Northern Ireland (United Kingdom); Allred, Joel C. [NASA Goddard Space Flight Center, Greenbelt, MD 20771 (United States); Kowalski, Adam F. [Department of Astrophysical and Planetary Sciences, University of Colorado Boulder, 2000 Colorado Avenue, Boulder, CO 80305 (United States); Kotrč, Pavel, E-mail: oprochazka01@qub.ac.uk [Astronomical Institute, The Czech Academy of Sciences, 25165 Ondřejov (Czech Republic)

2017-03-01

We present unique NUV observations of a well-observed X-class flare from NOAA 12087 obtained at the Ondřejov Observatory. The flare shows a strong white-light continuum but no detectable emission in the higher Balmer and Lyman lines. Reuven Ramaty High-Energy Solar Spectroscopic Imager and Fermi observations indicate an extremely hard X-ray spectrum and γ -ray emission. We use the RADYN radiative hydrodynamic code to perform two types of simulations: one where an energy of 3 × 10{sup 11} erg cm{sup −2} s{sup −1} is deposited by an electron beam with a spectral index of ≈3, and a second where the same energy is applied directly to the photosphere. The combination of observations and simulations allows us to conclude that the white-light emission and the suppression or complete lack of hydrogen emission lines is best explained by a model where the dominant energy deposition layer is located in the lower layers of the solar atmosphere, rather than the chromosphere.

Single-mode pumped high air-fill fraction photonic crystal fiber taper for high-power deep-blue supercontinuum sources

DEFF Research Database (Denmark)

Sørensen, Simon Toft; Larsen, Casper; Jakobsen, Christian

2014-01-01

Dispersion control with axially nonuniform photonic crystal fibers (PCFs) permits supercontinuum (SC) generation into the deep-blue from an ytterbium pump laser. In this Letter, we exploit the full degrees of freedom afforded by PCFs to fabricate a fiber with longitudinally increasing air-fill fr...

Potential tunable white-emitting phosphor LiSr4(BO3)3:Ce3+, Eu2+ for ultraviolet light-emitting diodes

International Nuclear Information System (INIS)

Wang Qian; Deng Degang; Hua Youjie; Huang Lihui; Wang Huanping; Zhao Shilong; Jia Guohua; Li Chenxia; Xu Shiqing

2012-01-01

A novel Ce 3+ /Eu 2+ co-activated LiSr 4 (BO 3 ) 3 phosphor has been synthesized by traditional solid-state reaction. The samples could display varied color emission from blue towards white and ultimately to yellow under the excitation of ultraviolet (UV) light with the appropriate adjustment of the relative proportion of Ce 3+ /Eu 2+ . The resonance-type energy transfer mechanism from Ce 3+ to Eu 2+ in LiSr 4 (BO 3 ) 3 :Ce 3+ , Eu 2+ phosphors is dominant by electric dipole–dipole interaction, and the critical distance is calculated to be about 29.14 Å by the spectra overlap method. White light was observed from LiSr 4 (BO 3 ) 3 :mCe 3+ , nEu 2+ phosphors with chromaticity coordinates (0.34, 0.30) upon 350 nm excitation. The LiSr 4 (BO 3 ) 3 :Ce 3+ , Eu 2+ phosphor has potential applications as an UV radiation-converting phosphor for white light-emitting diodes. - Highlights: ► White light was observed from the novel phosphor with chromaticity coordinate (0.34, 0.30). ► Resonant energy transfer between Ce 3+ and Eu 2+ occurs in the novel phosphor. ► This novel phosphor has potential applications as a UV-driven light-emitting phosphor.

Single-phased white-light-emitting Sr3NaLa(PO4)3F: Eu2+,Mn2+ phosphor via energy transfer

International Nuclear Information System (INIS)

Shanshan, Hu; Wanjun, Tang

2014-01-01

Single-phased white-light-emitting Sr 3 NaLa(PO 4 ) 3 F:Eu 2+ ,Mn 2+ phosphor is synthesized via the combustion-assisted synthesis technique. Upon excitation of 344 nm ultraviolet (UV) light, two intense broad bands have clearly been obtained due to the allowed 5d–4f transition of Eu 2+ and the forbidden 4 T 1 − 6 A 1 transition of Mn 2+ , respectively. As a result of fine-tuning of the emission composition of the Eu 2+ and Mn 2+ ions, white-light emission can be realized by combining the emission of Eu 2+ and Mn 2+ in a single host lattice under UV light excitation. The obtained phosphor exhibits a strong excitation band between 250 and 420 nm, matching well with the dominant emission band of a UV light-emitting-diode (LED) chip, which could be a promising candidate for UV-converting white-light-emitting diodes (LEDs). -- Highlights: • Single-phased Sr 3 NaLa(PO 4 ) 3 F:Eu 2+ ,Mn 2+ phosphors are synthesized. • Sr 3 NaLa(PO 4 ) 3 F:Eu 2+ ,Mn 2+ shows a blue emission band and a yellow emission band. • White-emitting can be obtained by tuning the compositions of the Eu 2+ and Mn 2+

White-light Detection for Nanoparticle Sizing with the TSI Ultrafine Condensation Particle Counter

International Nuclear Information System (INIS)

Dick, William D.; McMurry, Peter H.; Weber, Rodney J.; Quant, Frederick R.

2000-01-01

Several of the most common methods for measuring nanoparticle size distributions employ the ultrafine condensation particle counter (UCPC) for detection purposes. Among these methods, the pulse height analysis (PHA) technique, in which the optical response of the UCPC detector is related to initial particle diameter in the 3-10 nm range, prevails in applications where fast sampling is required or for which concentrations of nanoparticles are frequently very low. With the PHA technique, white light is required for particle illumination in order to obtain a monotonic relationship between initial particle diameter and optical response (pulse height). However, the popular, commercially available TSI Model 3025A UCPC employs a laser for particle detection. Here, we report on a novel white-light detection system developed for the 3025A UCPC that involves minimal alteration to the instrument and preserves normal counting operation. Performance is illustrated with pulse height spectra produced by differential mobility analyzer (DMA) - generated calibration aerosols in the 3-50 nm range

Highly efficient phosphorescent blue and white organic light-emitting devices with simplified architectures

Energy Technology Data Exchange (ETDEWEB)

Chang, Chih-Hao, E-mail: chc@saturn.yzu.edu.tw [Department of Photonics Engineering, Yuan Ze University, Chung-Li, Taiwan 32003 (China); Ding, Yong-Shung; Hsieh, Po-Wei; Chang, Chien-Ping; Lin, Wei-Chieh [Department of Photonics Engineering, Yuan Ze University, Chung-Li, Taiwan 32003 (China); Chang, Hsin-Hua, E-mail: hhua3@mail.vnu.edu.tw [Department of Electro-Optical Engineering, Vanung University, Chung-Li, Taiwan 32061 (China)

2011-09-01

Blue phosphorescent organic light-emitting devices (PhOLEDs) with quantum efficiency close to the theoretical maximum were achieved by utilizing a double-layer architecture. Two wide-triplet-gap materials, 1,3-bis(9-carbazolyl)benzene and 1,3,5-tri[(3-pyridyl)-phen-3-yl]benzene, were employed in the emitting and electron-transport layers respectively. The opposite carrier-transport characteristics of these two materials were leveraged to define the exciton formation zone and thus increase the probability of recombination. The efficiency at practical luminance (100 cd/m{sup 2}) was as high as 20.8%, 47.7 cd/A and 31.2 lm/W, respectively. Furthermore, based on the design concept of this simplified architecture, efficient warmish-white PhOLEDs were developed. Such two-component white organic light-emitting devices exhibited rather stable colors over a wide brightness range and yielded electroluminescence efficiencies of 15.3%, 33.3 cd/A, and 22.7 lm/W in the forward directions.

Highly efficient phosphorescent blue and white organic light-emitting devices with simplified architectures

International Nuclear Information System (INIS)

Chang, Chih-Hao; Ding, Yong-Shung; Hsieh, Po-Wei; Chang, Chien-Ping; Lin, Wei-Chieh; Chang, Hsin-Hua

2011-01-01

Blue phosphorescent organic light-emitting devices (PhOLEDs) with quantum efficiency close to the theoretical maximum were achieved by utilizing a double-layer architecture. Two wide-triplet-gap materials, 1,3-bis(9-carbazolyl)benzene and 1,3,5-tri[(3-pyridyl)-phen-3-yl]benzene, were employed in the emitting and electron-transport layers respectively. The opposite carrier-transport characteristics of these two materials were leveraged to define the exciton formation zone and thus increase the probability of recombination. The efficiency at practical luminance (100 cd/m 2 ) was as high as 20.8%, 47.7 cd/A and 31.2 lm/W, respectively. Furthermore, based on the design concept of this simplified architecture, efficient warmish-white PhOLEDs were developed. Such two-component white organic light-emitting devices exhibited rather stable colors over a wide brightness range and yielded electroluminescence efficiencies of 15.3%, 33.3 cd/A, and 22.7 lm/W in the forward directions.

Improvements of phosphorescent white OLEDs performance for lighting application.

Science.gov (United States)

Lee, Jonghee; Chu, Hye Yong; Lee, Jeong-Ik; Song, Ki-Im; Lee, Su Jin

2008-10-01

We developed white OLED device with high power efficiency, in which blue and orange phosphorescent emitters were used. By introduction of multi-functional interlayer which has partial doping of orange dopant inside EBL, we report WOLEDs with peak external efficiencies up to (14.1% EQE, 31.3 Im/W) without light out-coupling technique. At 1000 cd/m2, the performance achieved was 11.9% EQE, 18.7 Im/W with CIE = (0.39, 0.44). We also found that WOLED performances are related with doping ratio of the orange dopant that was inserted inside EBL.

Eu/Tb ions co-doped white light luminescence Y2O3 phosphors

International Nuclear Information System (INIS)

Tu Dong; Liang Yujun; Liu Rong; Li Daoyi

2011-01-01

Y 2 O 3 :Eu 3+ , Tb 3+ phosphors with white emission are prepared with different doping concentration of Eu 3+ and Tb 3+ ions and synthesizing temperatures from 750 to 950 deg. C by the co-precipitation method. The resulted phosphors were characterized by X-ray diffraction (XRD) and photoluminescence (PL) spectroscopy. The results of XRD indicate that the crystallinity of the synthesized samples increases with enhancing the firing temperature. The photoluminescence spectra indicate the Eu 3+ and Tb 3+ co-doped Y 2 O 3 phosphors show five main emission peaks: three at 590, 611 and 629 nm originate from Eu 3+ and two at 481 and 541 nm originate from Tb 3+ , under excitation of 250-320 nm irradition. The white light luminescence color could be changed by varying the excitation wavelength. Different concentrations of Eu 3+ and Tb 3+ ions were induced into the Y 2 O 3 lattice and the energy transfer from Tb 3+ →Eu 3+ ions in these phosphors was found. The Commission International de l'Eclairage (CIE) chromaticity shows that the Y 2 O 3 :Eu 3+ , Tb 3+ phosphors can obtain an intense white emission. - Highlights: → Novel phosphors Y 2 O 3 :Eu 3+ , Tb 3+ have been synthesized by co-precipitation method. → Samples emit white light with excellent color coordinates under UV excitation. → Luminescence color could be changed by varying the excitation wavelength. → Energy transfer from Tb 3+ →Eu 3+ ions in these phosphors was found.

Gigabit-per-second white light-based visible light communication using near-ultraviolet laser diode and red-, green-, and blue-emitting phosphors

KAUST Repository

Lee, Changmin; Shen, Chao; Cozzan, Clayton; Farrell, Robert M.; Speck, James S.; Nakamura, Shuji; Ooi, Boon S.; DenBaars, Steven P.

2017-01-01

Data communication based on white light generated using a near-ultraviolet (NUV) laser diode (LD) pumping red-, green-, and blue-emitting (RGB) phosphors was demonstrated for the first time. A III-nitride laser diode (LD) on a semipolar (2021

Highly Stable, All-fiber, High Power ZBLAN Supercontinuum Source Reaching 4.75 µm used for Nanosecond mid-IR Spectroscopy

DEFF Research Database (Denmark)

Moselund, Peter M.; Petersen, Christian; Leick, Lasse

2013-01-01

We demonstrate compact all-fiber mid-IR supercontinuum generation up to 4.75 μm with 1.2 W output power during hundreds of hours. This source is applied to upconversion spectroscopy using the energy corresponding to a single pulse....

The effect of blue-enriched white light on cognitive performances and sleepiness of night-shift workers: A field study.

Science.gov (United States)

Motamedzadeh, Majid; Golmohammadi, Rostam; Kazemi, Reza; Heidarimoghadam, Rashid

2017-08-01

Night-shift works are basically accompanied by reduced cognitive performance, sleepiness, and higher possibility for human error and related incidents. It is therefore crucial to improve individuals' performance and alertness in sensitive places like industries' control room with the ultimate goal of increasing efficiency and reducing the number of possible incidents. Previous research has indicated that blue light is a critical cue for entraining circadian rhythm. As a result, the present study was an attempt to investigate whether blue-enriched white light illumination was a practical strategy to decrease sleepiness and improve cognitive performance during night shifts. The study, which adopted a before-after interventional design, was conducted among 30 control room staff members of petrochemical industry. After baseline assessments under existing lighting conditions, every participant was exposed to two new lighting conditions (namely, 17,000K and 6500K blue-enriched white light), each lasting for a week. Assessments were conducted again at the end of these treatments. In order to measure the subjective sleepiness, Karolinska Sleepiness Scale (KSS) was utilized. Subjects also performed the Conners' Continuous Performance Test II (CPT-II) and 1-back test in order to gauge their cognitive performance, and melatonin assessment was carried out using salivary and Eliza technique. The data was analyzed using two-way repeated measure ANOVA. The results indicated that, compared to normal lighting conditions, participants' sleepiness and melatonin rhythm significantly declined when they were exposed to blue-enriched white light. Furthermore, the experimental condition had a significant effect on the reduction of working memory errors. It also decreased omission errors and the reaction time during the sustained attention task. Thus, using blue-enriched white light may be a proper ergonomic strategy for improving performance and alertness, especially during night, in

White top-emitting organic light-emitting diodes using one-emissive layer of the DCJTB doped DPVBi layer

Energy Technology Data Exchange (ETDEWEB)

Kim, M.S.; Jeong, C.H.; Lim, J.T. [Department of Advanced Materials Science and Engineering, Sungkyunkwan University, Suwon, Gyonggi-Do, 440-746 (Korea, Republic of); Yeom, G.Y. [Department of Advanced Materials Science and Engineering, Sungkyunkwan University, Suwon, Gyonggi-Do, 440-746 (Korea, Republic of); The National Program for Tera-level Devices, Hawolgok-dong, Sungbuk-gu, Seoul, 136-791 (Korea, Republic of)], E-mail: gyyeom@skku.edu

2008-04-01

White top-emitting organic light-emitting diodes (TEOLEDs) composed of one doped emissive layer which emits two-wavelength light though the radiative recombination were fabricated. As the emissive layer, 4,4-bis(2,2-diphenylethen-1-yl)biphenyl (DPVBi) was used as the host material and 4-(dicyanomethylene)-2-tert-butyl-6-(1,1,7,7-tetramethyljulolidyl-9-enyl) -4H-pyran (DCJTB) was added as the dopant material. By optimizing the DCJTB concentration (1.2%) and the thickness of the DPVBi layer (30 nm), the intensity ratio of the two wavelengths could be adjusted for balanced white light emission. By using the device composed of glass/Ag (100 nm)/ITO (90 nm)/2-TNATA (60 nm)/NPB (15 nm)/DPVBi:DCJTB (1.2%, 30 nm)/Alq{sub 3} (20 nm)/Li (1.0 nm)/Al (2.0 nm)/Ag (20 nm)/ITO (63 nm)/SiO{sub 2} (42 nm), the Commission Internationale d'Eclairage (CIE) chromaticity coordinate of (0.32, 0.34) close to the ideal white color CIE coordinate could be obtained at 100 cd/m{sup 2}.

White LEDs as broad spectrum light sources for spectrophotometry: demonstration in the visible spectrum range in a diode-array spectrophotometric detector.

Science.gov (United States)

Piasecki, Tomasz; Breadmore, Michael C; Macka, Mirek

2010-11-01

Although traditional lamps, such as deuterium lamps, are suitable for bench-top instrumentation, their compatibility with the requirements of modern miniaturized instrumentation is limited. This study investigates the option of utilizing solid-state light source technology, namely white LEDs, as a broad band spectrum source for spectrophotometry. Several white light LEDs of both RGB and white phosphorus have been characterized in terms of their emission spectra and energy output and a white phosphorus Luxeon LED was then chosen for demonstration as a light source for visible-spectrum spectrophotometry conducted in CE. The Luxeon LED was fixed onto the base of a dismounted deuterium (D(2) ) lamp so that the light-emitting spot was geometrically positioned exactly where the light-emitting spot of the original D(2) lamp is placed. In this manner, the detector of a commercial CE instrument equipped with a DAD was not modified in any way. As the detector hardware and electronics remained the same, the change of the deuterium lamp for the Luxeon white LED allowed a direct comparison of their performances. Several anionic dyes as model analytes with absorption maxima between 450 and 600 nm were separated by CE in an electrolyte of 0.01 mol/L sodium tetraborate. The absorbance baseline noise as the key parameter was 5 × lower for the white LED lamp, showing clearly superior performance to the deuterium lamp in the available, i.e. visible part of the spectrum. Copyright © 2010 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

Novel Low Cost Organic Vapor Jet Printing of Striped High Efficiency Phosphorescent OLEDs for White Lighting

Energy Technology Data Exchange (ETDEWEB)

Mike Hack

2008-12-31

In this program, Universal Display Corporation and University of Michigan proposed to integrate three innovative concepts to meet the DOE's Solid State Lighting (SSL) goals: (1) high-efficiency phosphorescent organic light emitting device (PHOLED{trademark}) technology, (2) a white lighting design that is based on a series of red, green and blue OLED stripes, and (3) the use of a novel cost-effective, high rate, mask-less deposition process called organic vapor jet printing (OVJP). Our PHOLED technology offers up to four-times higher power efficiency than other OLED approaches for general lighting. We believe that one of the most promising approaches to maximizing the efficiency of OLED lighting sources is to produce stripes of the three primary colors at such a pitch (200-500 {mu}m) that they appear as a uniform white light to an observer greater than 1 meter (m) away from the illumination source. Earlier work from a SBIR Phase 1 entitled 'White Illumination Sources Using Striped Phosphorescent OLEDs' suggests that stripe widths of less than 500 {mu}m appear uniform from a distance of 1m without the need for an external diffuser. In this program, we intend to combine continued advances in this PHOLED technology with the striped RGB lighting design to demonstrate a high-efficiency, white lighting source. Using this background technology, the team has focused on developing and demonstrating the novel cost-effective OVJP process to fabricate these high-efficiency white PHOLED light sources. Because this groundbreaking OVJP process is a direct printing approach that enables the OLED stripes to be printed without a shadow mask, OVJP offers very high material utilization and high throughput without the costs and wastage associated with a shadow mask (i.e. the waste of material that deposits on the shadow mask itself). As a direct printing technique, OVJP also has the potential to offer ultra-high deposition rates (> 1,000 Angstroms/second) for any size or

Noise analysis of the measurement of group delay in Fourier white-light interferometric cross correlation

International Nuclear Information System (INIS)

Laude, Vincent

2002-01-01

The problem of noise analysis in measuring the group delay introduced by a dispersive optical element by use of white-light interferometric cross correlation is investigated. Two noise types, detection noise and position noise, are specifically analyzed. Detection noise is shown to be highly sensitive to the spectral content of the white-light source at the frequency considered and to the temporal acquisition window. Position noise, which arises from the finite accuracy of the measurement of the scanning mirror's position, can severely damage the estimation of the group delay. Such is shown to be the case for fast Fourier transform-based estimation algorithms. A new algorithm that is insensitive to scanning delay errors is proposed, and subfemtosecond accuracy is obtained without any postprocessing

Tandem white organic light-emitting diodes adopting a C60:rubrene charge generation layer

International Nuclear Information System (INIS)

Bi Wen-Tao; Wu Xiao-Ming; Hua Yu-Lin; Sun Jin-E; Xiao Zhi-Hui; Wang Li; Yin Shou-Gen

2014-01-01

Organic bulk heterojunction fullerence (C 60 ) doped 5, 6, 11, 12-tetraphenylnaphthacene (rubrene) as the high quality charge generation layer (CGL) with high transparency and superior charge generating capability for tandem organic light emitting diodes (OLEDs) is developed. This CGL shows excellent optical transparency about 90%, which can reduce the optical interference effect formed in tandem OLEDs. There is a stable white light emission including 468 nm and 500 nm peaks from the blue emitting layer and 620 nm peak from the red emitting layer in tandem white OLEDs. A high efficiency of about 17.4 cd/A and CIE coordinates of (0.40, 0.35) at 100 cd/m 2 and (0.36, 0.34) at 1000 cd/m 2 have been demonstrated by employing the developed CGL, respectively. (condensed matter: electronic structure, electrical, magnetic, and optical properties)

Third-order gap plasmon based metasurfaces for visible light

DEFF Research Database (Denmark)

Deshpande, Rucha Anil; Pors, Anders; Bozhevolnyi, Sergey I.

2017-01-01

with different dimensions, to operate as a polarization beam splitter for linearly polarized light. The fabricated polarization beam splitter is characterized using a super-continuum light source at normal light incidence and found to exhibit a polarization contrast ratio of up to 40 dB near the design...... of the performance of polarization beam splitters based on third-order GSP resonance as well as other potential applications of the suggested approach....... by an optically thick gold film are calculated for the operation wavelength of 633 nm. Exploiting the occurrence of the third-order GSP resonance for nanobricks having their lengths close to 300 nm, we design the phase-gradient metasurface, representing an array of (450 x 2250 nm2) supercells made of 5 nanobricks...

Host-free, yellow phosphorescent material in white organic light-emitting diodes

Energy Technology Data Exchange (ETDEWEB)

Lee, Meng-Ting; Chu, Miao-Tsai; Lin, Jin-Sheng; Tseng, Mei-Rurng, E-mail: osolomio.ac89g@nctu.edu.t [Material and Chemical Research Laboratories, Industrial Technology Research Institute (ITRI), Hsinchu, Taiwan 310 (China)

2010-11-10

A white organic light-emitting diode (WOLED) with a high power efficiency has been demonstrated by dispersing a host-free, yellow phosphorescent material in between double blue phosphorescent emitters. The device performance achieved a comparable value to that of using a complicated host-guest doping system to form the yellow emitter in WOLEDs. Based on this device concept as well as the molecular engineering of blue phosphorescent host material and light-extraction film, a WOLED with a power efficiency of 65 lm W{sup -1} at a practical brightness of 1000 cd m{sup -2} with Commission Internationale d'Echariage coordinates (CIE{sub x,y}) of (0.37, 0.47) was achieved. (fast track communication)

Origin of colour stability in blue/orange/blue stacked phosphorescent white organic light-emitting diodes

International Nuclear Information System (INIS)

Kim, Sung Hyun; Jang, Jyongsik; Yook, Kyoung Soo; Lee, Jun Yeob

2009-01-01

The origin of colour stability in phosphorescent white organic light-emitting diodes (PHWOLEDs) with a blue/orange/blue stacked emitting structure was studied by monitoring the change in a recombination zone. A balanced recombination zone shift between the blue and the orange light-emitting layers was found to be responsible for the colour stability in the blue/orange/blue stacked PHWOLEDs.

White Polymer Light-Emitting Diodes Based on Exciplex Electroluminescence from Polymer Blends and a Single Polymer.

Science.gov (United States)

Liang, Junfei; Zhao, Sen; Jiang, Xiao-Fang; Guo, Ting; Yip, Hin-Lap; Ying, Lei; Huang, Fei; Yang, Wei; Cao, Yong

2016-03-09

In this Article, we designed and synthesized a series of polyfluorene derivatives, which consist of the electron-rich 4,4'-(9-alkyl-carbazole-3,6-diyl)bis(N,N-diphenylaniline) (TPA-Cz) in the side chain and the electron-deficient dibenzothiophene-5,5-dioxide (SO) unit in the main chain. The resulting copolymer PF-T25 that did not comprise the SO unit exhibited blue light-emission with the Commission Internationale de L'Eclairage coordinates of (0.16, 0.10). However, by physically blending PF-T25 with a blue light-emitting SO-based oligomer, a novel low-energy emission correlated to exciplex emerged due to the appropriate energy level alignment of TPA-Cz and the SO-based oligomers, which showed extended exciton lifetime as confirmed by time-resolved photoluminescent spectroscopy. The low-energy emission was also identified in copolymers consisting of SO unit in the main chain, which can effectively compensate for the high-energy emission to produce binary white light-emission. Polymer light-emitting diodes based on the exciplex-type single greenish-white polymer exhibit the peak luminous efficiency of 2.34 cd A(-1) and the maximum brightness of 12 410 cd m(-2), with Commission Internationale de L'Eclairage color coordinates (0.27, 0.39). The device based on such polymer showed much better electroluminescent stability than those based on blending films. These observations indicated that developing a single polymer with the generated exciplex emission can be a novel and effective molecular design strategy toward highly stable and efficient white polymer light-emitting diodes.

Efficient white organic light emitting devices with dual emitting layers

International Nuclear Information System (INIS)

Wu Yaoshan; Hwang Shiaowen; Chen Hsianhung; Lee Mengting; Shen Wenjian; Chen, C.H.

2005-01-01

In this paper, a new white organic light-emitting device (OLED) with the structure of indium tin oxide / CF x / 1,4-bis[N-(1-naphthyl)-N'-phenylamino]-biphenyl (NPB) (30 nm)/NPB: 2,8-di(t-butyl)-5,11-di[4-(t-butyl)phenyl]-6,12-diphenylnaphthacene (20 nm; 1.6 %) / 2-methyl-9,10-di(2-naphthyl) anthracene: p-bis(p-N,N-di-phenyl-aminostyryl)benzene (40 nm, 3%) / aluminum tris(8-hydroxyquinoline) (20 nm) / LiF (1 nm) / Al (200 nm) has been investigated. The device showed white emission with a high-luminous yield of 9.75 cd/A at 20 mA/cm 2 , but its Commission Internationale de l'Eclairage chromaticity coordinates appeared to change from (0.34, 0.42) at 6 mA/cm2 to (0.27, 0.37) at 200 mA/cm 2 due to the shift of recombination zone. The change of color with drive current was suppressed by introduction of an electron-blocking layer of NPB along with a hole-blocking layer of aluminum (III) bis(2-methyl-8-quinolinato)4-phenylphenolato to the white OLED which successfully confined the recombination site and achieved a luminous yield of 9.9 cd/A at 20 mA/cm 2

Efficient non-doped phosphorescent orange, blue and white organic light-emitting devices

Science.gov (United States)

Yin, Yongming; Yu, Jing; Cao, Hongtao; Zhang, Letian; Sun, Haizhu; Xie, Wenfa

2014-10-01

Efficient phosphorescent orange, blue and white organic light-emitting devices (OLEDs) with non-doped emissive layers were successfully fabricated. Conventional blue phosphorescent emitters bis [4,6-di-fluorophenyl]-pyridinato-N,C2'] picolinate (Firpic) and Bis(2,4-difluorophenylpyridinato) (Fir6) were adopted to fabricate non-doped blue OLEDs, which exhibited maximum current efficiency of 7.6 and 4.6 cd/A for Firpic and Fir6 based devices, respectively. Non-doped orange OLED was fabricated utilizing the newly reported phosphorescent material iridium (III) (pbi)2Ir(biq), of which manifested maximum current and power efficiency of 8.2 cd/A and 7.8 lm/W. The non-doped white OLEDs were achieved by simply combining Firpic or Fir6 with a 2-nm (pbi)2Ir(biq). The maximum current and power efficiency of the Firpic and (pbi)2Ir(biq) based white OLED were 14.8 cd/A and 17.9 lm/W.

Development of Key Technologies for White Lighting Based on Light-Emitting Diodes (LEDs)

Energy Technology Data Exchange (ETDEWEB)

Werner Goetz; Bill Imler; James Kim; Junko Kobayashi; Andrew Kim; Mike Krames; Rick Mann; Gerd Mueller-Mach; Anneli Munkholm; Jonathan Wierer

2004-03-31

This program was organized to focus on materials development issues critical to the acceleration of solid-state lighting, and was split into three major thrust areas: (1) study of dislocation density reduction for GaN grown on sapphire using 'cantilever epitaxy', and the impact of dislocation density on the performance of state-of-the-art high-power LEDs; (2) the evaluation of in situ techniques for monitoring gas phase chemistry and the properties of GaN-based layers during metal-organic vapor phase epitaxy (MOCVD), and (3) feasibility for using semiconductor nanoparticles ('quantum dots') for the down-conversion of blue or ultraviolet light to generate white light. The program included a partnership between Lumileds Lighting (epitaxy and device fabrication for high power LEDs) and Sandia National Laboratories (cantilever epitaxy, gas phase chemistry, and quantum dot synthesis). Key findings included: (1) cantilever epitaxy can provide dislocation density reduction comparable to that of more complicated approaches, but all in one epitaxial growth step; however, further improvements are required to realize significant gains in LED performance at high drive currents, (2) in situ tools can provide detailed knowledge about gas phase chemistry, and can be used to monitor and control epitaxial layer composition and temperature to provide improved yields (e.g., a fivefold increase in color targeting is demonstrated for 540nm LEDs), and (3) quantum efficiency for quantum dots is improved and maintained up to 70% in epoxy thin films, but further work is necessary to increase densification (absorption) and robustness before practical application to LEDs.

Generation of White Light from Dysprosium-Doped Strontium Aluminate Phosphor by a Solid-State Reaction Method

Science.gov (United States)

Sahu, Ishwar Prasad; Bisen, D. P.; Brahme, N.; Tamrakar, Raunak Kumar

2016-04-01

A single-host lattice, white light-emitting SrAl2O4:Dy3+ phosphor was synthesized by a solid-state reaction method. The crystal structure of prepared SrAl2O4:Dy3+ phosphor was in a monoclinic phase with space group P21. The chemical composition of the sintered SrAl2O4:Dy3+ phosphor was confirmed by the energy dispersive x-ray spectroscopy technique. Under ultra-violet excitation, the characteristic emissions of Dy3+ are peaking at 475 nm, 573 nm and 660 nm, originating from the transitions of 4F9/2 → 6H15/2, 4F9/2 →&!nbsp; 6H13/2 and 4F9/2 → 6H11/2 in the 4f9 configuration of Dy3+ ions. Commission International de I'Eclairage color coordinates of SrAl2O4:Dy3+ are suitable for white light-emitting phosphor. In order to investigate the suitability of the samples as white color light sources for industrial uses, correlated color temperature (CCT) and color rendering index (CRI) values were calculated. Values of CCT and CRI were found well within the defined acceptable range. Mechanoluminescence (ML) intensity of SrAl2O4:Dy3+ phosphor increased linearly with increasing impact velocity of the moving piston. Thus, the present investigation indicates piezo-electricity was responsible for producing ML in sintered SrAl2O4:Dy3+ phosphor. Decay rates of the exponential decaying period of the ML curves do not change significantly with impact velocity. The photoluminescence and ML results suggest that the synthesized SrAl2O4:Dy3+ phosphor was useful for the white light-emitting diodes and stress sensor respectively.

Electrical aging effect of ZnS based quantum dots for white light-emitting diodes

Science.gov (United States)

Kim, Yohan; Ippen, Christian; Greco, Tonino; Jang, Ilwan; Park, Sungkyu; Oh, Min Suk; Han, Chul Jong; Lee, Jeongno; Wedel, Armin; Kim, Jiwan

2014-03-01

The present work reports cadmium-free colloidal ZnS:Al quantum dot (QD) based white quantum dot light-emitting diodes (QD-LEDs). The device was fabricated with a structure of ITO/PEDOT:PSS/PVK/QDs/TPBi/LiF/Al using synthesized ZnS:Al QDs which has 393 nm of peak wavelength and sub peaks in visible wavelength. White emission with high color rending index (CRI) was achieved by the combination of blue emission from PVK and ZnS:Al QDs, electroplex emission at the interface between PVK and ZnS:Al QDs, and Al traps/defects emission, which are controlled by electrical aging effect. The characteristic of our device shows the potential for spectrum tunable and Cd-free white QD-LEDs in the near future.

Bidirectional reflectance distribution function of Spectralon white reflectance standard illuminated by incoherent unpolarized and plane-polarized light.

Science.gov (United States)

Bhandari, Anak; Hamre, Børge; Frette, Øvynd; Zhao, Lu; Stamnes, Jakob J; Kildemo, Morten

2011-06-01

A Lambert surface would appear equally bright from all observation directions regardless of the illumination direction. However, the reflection from a randomly scattering object generally has directional variation, which can be described in terms of the bidirectional reflectance distribution function (BRDF). We measured the BRDF of a Spectralon white reflectance standard for incoherent illumination at 405 and 680 nm with unpolarized and plane-polarized light from different directions of incidence. Our measurements show deviations of the BRDF for the Spectralon white reflectance standard from that of a Lambertian reflector that depend both on the angle of incidence and the polarization states of the incident light and detected light. The non-Lambertian reflection characteristics were found to increase more toward the direction of specular reflection as the angle of incidence gets larger.

Molecular-scale simulation of electroluminescence in a multilayer white organic light-emitting diode

DEFF Research Database (Denmark)

Mesta, Murat; Carvelli, Marco; de Vries, Rein J

2013-01-01

we show that it is feasible to carry out Monte Carlo simulations including all of these molecular-scale processes for a hybrid multilayer organic light-emitting diode combining red and green phosphorescent layers with a blue fluorescent layer. The simulated current density and emission profile......In multilayer white organic light-emitting diodes the electronic processes in the various layers--injection and motion of charges as well as generation, diffusion and radiative decay of excitons--should be concerted such that efficient, stable and colour-balanced electroluminescence can occur. Here...

Combination of carbon dot and polymer dot phosphors for white light-emitting diodes.

Science.gov (United States)

Sun, Chun; Zhang, Yu; Sun, Kai; Reckmeier, Claas; Zhang, Tieqiang; Zhang, XiaoYu; Zhao, Jun; Wu, Changfeng; Yu, William W; Rogach, Andrey L

2015-07-28

We realized white light-emitting diodes with high color rendering index (85-96) and widely variable color temperatures (2805-7786 K) by combining three phosphors based on carbon dots and polymer dots, whose solid-state photoluminescence self-quenching was efficiently suppressed within a polyvinyl pyrrolidone matrix. All three phosphors exhibited dominant absorption in the UV spectral region, which ensured the weak reabsorption and no energy transfer crosstalk. The WLEDs showed excellent color stability against the increasing current because of the similar response of the tricolor phosphors to the UV light variation.

Highly efficient white top-emitting organic light-emitting diodes with forward directed light emission

Energy Technology Data Exchange (ETDEWEB)

Freitag, Patricia; Reineke, Sebastian; Furno, Mauro; Luessem, Bjoern; Leo, Karl [Institut fuer Angewandte Photophysik, TU Dresden (Germany)

2010-07-01

The demand for highly efficient and energy saving illumination has increased considerably during the last decades. Organic light emitting diodes (OLEDs) are promising candidates for future lighting technologies. They offer high efficiency along with excellent color quality, allowing substantially lower power consumption than traditional illuminants. Recently, especially top-emitting devices have attracted high interest due to their compatibility with opaque substrates like metal sheets. In this contribution, we demonstrate top-emitting OLEDs with white emission spectra employing a multilayer hybrid cavity structure with two highly efficient phosphorescent emitter materials for orange-red (Ir(MDQ)2(acac)) and green (Ir(ppy)3) emission as well as the stable fluorescent blue emitter TBPe. To improve the OLED performance and modify the color quality, two different electron blocking layers and anode material combinations are tested. Compared to Lambertian emission, our devices show considerably enhanced forward emission, which is preferred for most lighting applications. Besides broadband emission and angle independent emission maxima, power efficiencies of 13.3 lm/W at 3 V and external quantum efficiencies of 5.3% are achieved. The emission shows excellent CIE coordinates of (0.420,0.407) at approx. 1000 cd/m{sup 2} and color rendering indices up to 77.

Accuracy of 3D white light scanning of abutment teeth impressions: evaluation of trueness and precision.

Science.gov (United States)

Jeon, Jin-Hun; Kim, Hae-Young; Kim, Ji-Hwan; Kim, Woong-Chul

2014-12-01

This study aimed to evaluate the accuracy of digitizing dental impressions of abutment teeth using a white light scanner and to compare the findings among teeth types. To assess precision, impressions of the canine, premolar, and molar prepared to receive all-ceramic crowns were repeatedly scanned to obtain five sets of 3-D data (STL files). Point clouds were compared and error sizes were measured (n=10 per type). Next, to evaluate trueness, impressions of teeth were rotated by 10°-20° and scanned. The obtained data were compared with the first set of data for precision assessment, and the error sizes were measured (n=5 per type). The Kruskal-Wallis test was performed to evaluate precision and trueness among three teeth types, and post-hoc comparisons were performed using the Mann-Whitney U test with Bonferroni correction (α=.05). Precision discrepancies for the canine, premolar, and molar were 3.7 µm, 3.2 µm, and 7.3 µm, respectively, indicating the poorest precision for the molar (Pimpressions of abutment teeth using a white light scanner was assessed to be a highly accurate method and provided discrepancy values in a clinically acceptable range. Further study is needed to improve digitizing performance of white light scanning in axial wall.

Students' Conceptions on White Light and Implications for Teaching and Learning about Colour

Science.gov (United States)

Haagen-Schützenhöfer, Claudia

2017-01-01

The quality of learning processes is mainly determined by the extent to which students' conceptions are addressed and thus conceptual change is triggered. Colour phenomena are a topic within initial instruction of optics which is challenging. A physically adequate concept of white light is crucial for being able to grasp the processes underlying…

Color selectivity of surface-plasmon holograms illuminated with white light.

Science.gov (United States)

Ozaki, Miyu; Kato, Jun-ichi; Kawata, Satoshi

2013-09-20

By using the optical frequency dependence of surface-plasmon polaritons, color images can be reconstructed from holograms illuminated with white light. We report details on the color selectivity of the color holograms. The selectivity is tuned by the thickness of a dielectric film covering a plasmonic metal film. When the dielectric is SiO(2) and the metal is silver, the appropriate thicknesses are 25 and 55 nm, respectively. In terms of spatial color uniformity, holograms made of silver-film corrugations are better than holograms recorded on photographic film on a flat silver surface.

Molecular Beam Epitaxy-Grown InGaN Nanomushrooms and Nanowires for White Light Source Applications

KAUST Repository

Gasim, Anwar A.; Bhattacharya, Pallab K.; Cha, Dong Kyu; Ng, Tien Khee; Ooi, Boon S.

2012-01-01

We report the observation of coexisting InGaN nanomushrooms and nanowires grown via MBE. Photoluminescence characterization shows that the nanostructures emit yellow and blue light, respectively. The combined emission is promising for white-LEDs.

Supercontinuum generation in optimized photonic crystal fiber at 1.3 μm for optical coherence tomography

Directory of Open Access Journals (Sweden)

Ferhat M. L.

2016-01-01

Full Text Available In this paper, we have designed a high nonlinear photonic crystal fiber (HN-PCF based on square-lattice geometry with the zero dispersion wavelength (ZDW around 1300 nm. The exploitation of different nonlinear mechanisms in the pulse propagation allows supercontinuum generation, which is used to enhance the axial resolution of the optical coherence tomography (OCT systems. First mechanism demonstrated is the soliton self-compression, we came up to realize pulse compression of 28.4 fs around 1300 nm by the generation of solitons of different orders to obtain ultrashort pulses of about 4 fs pulses in a PCF length of 66cm, then, we improved the pulse compression until 1.2 fs in a PCF length of 26 cm.The exploitation of the interplay between many nonlinear effects as self-phase modulation, intrapulse Raman scattering and self-steepening as second mechanism allows a generation of supercontinuum with a spectral bandwith of SBW=260 nm. The obtained spectral bandwidth could contribute to enhance the OCwith OCT imaging axial resolution which can be evaluated to 2.8 μm in air, working at 1.3 μm center wavelength which is widely used in several fields.

Semipolar GaN-based laser diodes for Gbit/s white lighting communication: devices to systems

KAUST Repository

Lee, Changmin; Shen, Chao; Farrell, Robert M.; Nakamura, Shuji; Ooi, Boon S.; Bowers, John E.; DenBaars, Steven P.; Speck, James S.; Cozzan, Clayton; Alyamani, Ahmed Y.

2018-01-01

diodes than the conventional c-plane counterparts. In addition, we demonstrate the first novel white lighting communication system by using our near-ultraviolet (NUV) LDs and pumping red-, green-, and blueemitting phosphors. This system satisfies both

Study on constant-step stress accelerated life tests in white organic light-emitting diodes.

Science.gov (United States)

Zhang, J P; Liu, C; Chen, X; Cheng, G L; Zhou, A X

2014-11-01

In order to obtain reliability information for a white organic light-emitting diode (OLED), two constant and one step stress tests were conducted with its working current increased. The Weibull function was applied to describe the OLED life distribution, and the maximum likelihood estimation (MLE) and its iterative flow chart were used to calculate shape and scale parameters. Furthermore, the accelerated life equation was determined using the least squares method, a Kolmogorov-Smirnov test was performed to assess if the white OLED life follows a Weibull distribution, and self-developed software was used to predict the average and the median lifetimes of the OLED. The numerical results indicate that white OLED life conforms to a Weibull distribution, and that the accelerated life equation completely satisfies the inverse power law. The estimated life of a white OLED may provide significant guidelines for its manufacturers and customers. Copyright © 2014 John Wiley & Sons, Ltd.

Health-friendly high-quality white light using violet-green-red laser and InGaN nanowires-based true yellow nanowires light-emitting diodes

KAUST Repository

Janjua, Bilal

2017-02-16

White light based on blue laser - YAG: Ce phosphor has the advantage of implementing solid-state lighting and optical wireless communications combined-functionalities in a single lamp. However, the blue light was found to disrupt melatonin production, and therefore the human circadian rhythm in general; while the yellow phosphor is susceptible to degradation by laser irradiation and also lack tunability in color rendering index (CRI). In this investigation, by using a violet laser, which has 50% less impact on circadian response, as compared to blue light, and an InGaN-quantum-disks nanowires-based light-emitting diode (NWs-LED), we address both issues simultaneously. The white light is therefore generated using violet-green-red lasers, in conjunction with a yellow NWs-LED realized using molecular beam epitaxy technique, on titanium-coated silicon substrates. Unlike the conventional quantum-well-based LED, the NWs-LED showed efficiency-droop free behavior up to 9.8 A/cm with peak output power of 400 μW. A low turn-on voltage of ∼2.1 V was attributed to the formation of conducting titanium nitride layer at NWs nucleation site and improved fabrication process in the presence of relatively uniform height distribution. The 3D quantum confinement and the reduced band bending improve carriers-wavefunctions overlap, resulting in an IQE of ∼39 %. By changing the relative intensities of the individual color components, CRI of >85 was achieved with tunable correlated color temperature (CCT), thus covering the desired room lighting conditions. Our architecture provides important considerations in designing smart solid-state lighting while addressing the harmful effect of blue light.

Health-friendly high-quality white light using violet-green-red laser and InGaN nanowires-based true yellow nanowires light-emitting diodes

Science.gov (United States)

Janjua, Bilal; Ng, Tien K.; Zhao, Chao; Anjum, Dalaver H.; Prabaswara, Aditya; Consiglio, Giuseppe Bernardo; Shen, Chao; Ooi, Boon S.

2017-02-01

White light based on blue laser - YAG: Ce3+ phosphor has the advantage of implementing solid-state lighting and optical wireless communications combined-functionalities in a single lamp. However, the blue light was found to disrupt melatonin production, and therefore the human circadian rhythm in general; while the yellow phosphor is susceptible to degradation by laser irradiation and also lack tunability in color rendering index (CRI). In this investigation, by using a violet laser, which has 50% less impact on circadian response, as compared to blue light, and an InGaN-quantum-disks nanowires-based light-emitting diode (NWs-LED), we address both issues simultaneously. The white light is therefore generated using violet-green-red lasers, in conjunction with a yellow NWs-LED realized using molecular beam epitaxy technique, on titanium-coated silicon substrates. Unlike the conventional quantum-well-based LED, the NWs-LED showed efficiency-droop free behavior up to 9.8 A/cm2 with peak output power of 400 μW. A low turn-on voltage of 2.1 V was attributed to the formation of conducting titanium nitride layer at NWs nucleation site and improved fabrication process in the presence of relatively uniform height distribution. The 3D quantum confinement and the reduced band bending improve carriers-wavefunctions overlap, resulting in an IQE of 39 %. By changing the relative intensities of the individual color components, CRI of >85 was achieved with tunable correlated color temperature (CCT), thus covering the desired room lighting conditions. Our architecture provides important considerations in designing smart solid-state lighting while addressing the harmful effect of blue light.

White organic light-emitting diodes based on doped and ultrathin Rubrene layer

Science.gov (United States)

Li, Yi; Jiang, Yadong; Wen, Wen; Yu, Junsheng

2010-10-01

Based on a yellow fluorescent dye of 5, 6, 11, 12-tetraphenylnaphthacene (Rubrene), WOLEDs were fabricated, with doping structure and ultrathin layer structure utilized in the devices. By doping Rubrene into blue-emitting N,N'-bis-(1- naphthyl)-N,N'-biphenyl-1,1'-biphenyl-4,4'-diamine (NPB), the device with a structure of indium-tin-oxide (ITO)/NPB (40 nm)/NPB:Rubrene (0.25 wt%, 7 nm)/2,9-dimethyl-4,7-diphenyl-1,10-phenanthroline (BCP) (30 nm)/Mg:Ag exhibited a warm white light with Commissions Internationale De L'Eclairage (CIE) coordinates of (0.38, 0.41) at 12 V. The electroluminescent spectrum of the OLED consisted of blue and yellow fluorescent emissions, the intensity of blue emission increased gradually relative to the orange emission with increasing voltage. This is mainly due to the recombination zone shifted towards the anode side as the transmission rate of electrons grows faster than that of holes under higher bias voltage. A maximum luminance of 7300 cd/m2 and a maximum power efficiency of 0.57 lm/W were achieved. Comparatively, by utilizing ultrathin dopant layer, the device with a structure of ITO/NPB (40 nm)/Rubrene (0.3 nm)/NPB (7 nm)/BCP (30 nm)/Mg:Ag achieved a low turn-on voltage of 3 V and a more stable white light. The peaks of EL spectra located at 430 and 560 nm corresponding to the CIE coordinates of (0.32, 0.32) under bias voltage ranging from 5 to 15 V. A maximum luminance of 5630 cd/m2 and a maximum power efficiency of 0.6 lm/W were achieved. The balanced spectra were attributed to the stable confining of charge carriers and exciton by the thin emitting layers. Hence, with simple device structure and fabricating process, the device with ultrathin layer achieved low turn-on voltage, stable white light emitting and higher power efficiency.

Efficient textured colour conversion layer of a down-converted white organic light-emitting diode by transfer imprinting

International Nuclear Information System (INIS)

Zhu, Wenqing; Xiao, Teng; Qian, Bingjie; Sun, Liangliang

2015-01-01

In this paper, we demonstrated an efficient textured colour conversion layer (CCL) of a down-converted white organic light-emitting diode (WOLED), which was fabricated by a very simple transfer imprinting method based on silicon wafer. The textured CCL not only helped to extract wave-guided light in the device, but also had an outstanding performance in enhancing the colour conversion rate, which was 1.75 times greater than that of flat CCL. Compared to flat CCL, the lower-doped textured CCL produced better white emission and higher efficiency simultaneously. Moreover, the WOLED with textured CCL also exhibited good colour stability at various voltages. (paper)

Tailored white light emission in Eu3+/Dy3+ doped tellurite glass phosphors containing Al3+ ions

Science.gov (United States)

Walas, Michalina; Piotrowski, Patryk; Lewandowski, Tomasz; Synak, Anna; Łapiński, Marcin; Sadowski, Wojciech; Kościelska, Barbara

2018-05-01

Tellurite glass systems modified by addition of aluminum fluoride AlF3 have been successfully synthesized as host matrices for optically active rare earth ions RE3+ (RE3+ = Eu3+, Dy3+). Samples with different Eu3+ to Dy3+ molar ratio have been studied in order to determine possibility of white light emission via UV excitation. Structural investigations confirmed amorphous character of materials whereas spectroscopic studies brought more insight into glass network's nature. FTIR results shown presence of two features related to tellurite glass matrix (in 490-935 cm-1 spectral region) and another one (940-1250 cm-1) due to aluminum addition. Especially, Al-O and Te-O-Al bonds of AlO4 tetrahedrons have been found. AlO4 units are considered as glass formers that improve network's strength and thermal resistivity against devitrification. Based on XPS studies of Al3+ photoelectron band the existence of Al-O and also Al-F bonds have been examined. Moreover, signals originating from Eu3+ and Dy3+ have been found confirming their valence state. Luminescence results revealed possibility of simultaneous UV excitation of Eu3+ and Dy3+ ions. Excitation with λexc = 390 and 393 nm resulted in white light generation starting from warm white to neutral and cool white depending on Eu3+ concentration and used excitation wavelength. Additionally, increase of decay lifetime of Eu3+ induced by Al3+ presence have been revealed based on luminescence decay analysis. Thus, tellurite glass systems modified by AlF3 and doped with Eu3+/Dy3+ may be considered as promising candidates for white light emitting sources.

Warm White Light-Emitting Diodes Based on a Novel Orange Cationic Iridium(III) Complex.

Science.gov (United States)

Tang, Huaijun; Meng, Guoyun; Chen, Zeyu; Wang, Kaimin; Zhou, Qiang; Wang, Zhengliang

2017-06-16

A novel orange cationic iridium(III) complex [(TPTA)₂Ir(dPPOA)]PF₆ (TPTA: 3,4,5-triphenyl-4 H -1,2,4-triazole, dPPOA: N,N-diphenyl-4-(5-(pyridin-2-yl)-1,3,4-oxadiazol-2-yl)aniline) was synthesized and used as a phosphor in light-emitting diodes (LEDs). [(TPTA)₂Ir(dPPOA)]PF₆ has high thermal stability with a decomposition temperature ( T d ) of 375 °C, and its relative emission intensity at 100 °C is 88.8% of that at 25°C. When only [(TPTA)₂Ir(dPPOA)]PF₆ was used as a phosphor at 6.0 wt % in silicone and excited by a blue GaN (GaN: gallium nitride) chip (450 nm), an orange LED was obtained. A white LED fabricated by a blue GaN chip (450 nm) and only yellow phosphor Y₃Al₅O 12 :Ce 3+ (YAG:Ce) (1.0 wt % in silicone) emitted cold white light, its CIE (CIE: Commission International de I'Eclairage ) value was (0.32, 0.33), color rendering index (CRI) was 72.2, correlated color temperature (CCT) was 6877 K, and luminous efficiency ( η L ) was 128.5 lm∙W -1 . Such a cold white LED became a neutral white LED when [(TPTA)₂Ir(dPPOA)]PF₆ was added at 0.5 wt %; its corresponding CIE value was (0.35, 0.33), CRI was 78.4, CCT was 4896 K, and η L was 85.2 lm∙W -1 . It further became a warm white LED when [(TPTA)₂Ir(dPPOA)]PF₆ was added at 1.0 wt %; its corresponding CIE value was (0.39, 0.36), CRI was 80.2, CCT was 3473 K, and η L was 46.1 lm∙W -1 . The results show that [(TPTA)₂Ir(dPPOA)]PF₆ is a promising phosphor candidate for fabricating warm white LEDs.

Efficient white organic light-emitting devices based on blue, orange, red phosphorescent dyes

International Nuclear Information System (INIS)

Chen Ping; Duan Yu; Xie Wenfa; Zhao Yi; Hou Jingying; Liu Shiyong; Zhang Liying; Li Bin

2009-01-01

We demonstrate efficient white organic light-emitting devices (WOLEDs) based on an orange phosphorescent iridium complex bis(2-(2-fluorphenyl)-1,3-benzothiozolato-N, C 2' )iridium(acetylacetonate) in combination with blue phosphorescent dye bis[(4, 6-difluorophenyl)-pyridinato-N,C 2 )](picolinato) Ir(III) and red phosphorescent dye bis[1-(phenyl)isoquinoline] iridium (III) acetylanetonate. By introducing a thin layer of 4, 7-diphenyl-1,10-phenanthroline between blue and red emission layers, the diffusion of excitons is confined and white light can be obtained. WOLEDs with the interlayer all have a higher colour rendering index (>82) than the device without it (76). One device has the maximum current efficiency of 17.6 cd A -1 and a maximum luminance of 39 050 cd m -2 . The power efficiency is 8.7 lm W -1 at 100 cd m -2 . Furthermore, the device has good colour stability and the CIE coordinates just change from (0.394, 0.425) to (0.390, 0.426) with the luminance increasing from 630 to 4200 cd m -2 .

Gigabit-per-second white light-based visible light communication using near-ultraviolet laser diode and red-, green-, and blue-emitting phosphors

KAUST Repository

Lee, Changmin

2017-07-12

Data communication based on white light generated using a near-ultraviolet (NUV) laser diode (LD) pumping red-, green-, and blue-emitting (RGB) phosphors was demonstrated for the first time. A III-nitride laser diode (LD) on a semipolar (2021) substrate emitting at 410 nm was used for the transmitter. The measured modulation bandwidth of the LD was 1 GHz, which was limited by the avalanche photodetector. The emission from the NUV LD and the RGB phosphor combination measured a color rendering index (CRI) of 79 and correlated color temperature (CCT) of 4050 K, indicating promise of this approach for creating high quality white lighting. Using this configuration, data was successfully transmitted at a rate of more than 1 Gbps. This NUV laser-based system is expected to have lower background noise from sunlight at the LD emission wavelength than a system that uses a blue LD due to the rapid fall off in intensity of the solar spectrum in the NUV spectral region.

Gigabit-per-second white light-based visible light communication using near-ultraviolet laser diode and red-, green-, and blue-emitting phosphors.

Science.gov (United States)

Lee, Changmin; Shen, Chao; Cozzan, Clayton; Farrell, Robert M; Speck, James S; Nakamura, Shuji; Ooi, Boon S; DenBaars, Steven P

2017-07-24

Data communication based on white light generated using a near-ultraviolet (NUV) laser diode (LD) pumping red-, green-, and blue-emitting (RGB) phosphors was demonstrated for the first time. A III-nitride laser diode (LD) on a semipolar (2021¯)  substrate emitting at 410 nm was used for the transmitter. The measured modulation bandwidth of the LD was 1 GHz, which was limited by the avalanche photodetector. The emission from the NUV LD and the RGB phosphor combination measured a color rendering index (CRI) of 79 and correlated color temperature (CCT) of 4050 K, indicating promise of this approach for creating high quality white lighting. Using this configuration, data was successfully transmitted at a rate of more than 1 Gbps. This NUV laser-based system is expected to have lower background noise from sunlight at the LD emission wavelength than a system that uses a blue LD due to the rapid fall off in intensity of the solar spectrum in the NUV spectral region.

Quantitative Light Fluorescence (QLF and Polarized White Light (PWL assessments of dental fluorosis in an epidemiological setting

Directory of Open Access Journals (Sweden)

Pretty Iain A

2012-05-01

Full Text Available Abstract Background To determine if a novel dual camera imaging system employing both polarized white light (PWL and quantitative light induced fluorescence imaging (QLF is appropriate for measuring enamel fluorosis in an epidemiological setting. The use of remote and objective scoring systems is of importance in fluorosis assessments due to the potential risk of examiner bias using clinical methods. Methods Subjects were recruited from a panel previously characterized for fluorosis and caries to ensure a range of fluorosis presentation. A total of 164 children, aged 11 years (±1.3 participated following consent. Each child was examined using the novel imaging system, a traditional digital SLR camera, and clinically using the Dean’s and Thylstrup and Fejerskov (TF Indices on the upper central and lateral incisors. Polarized white light and SLR images were scored for both Dean’s and TF indices by raters and fluorescence images were automatically scored using software. Results Data from 164 children were available with a good distribution of fluorosis severity. The automated software analysis of QLF images demonstrated significant correlations with the clinical examinations for both Dean’s and TF index. Agreement (measured by weighted Kappa’s between examiners scoring clinically, from polarized photographs and from SLR images ranged from 0.56 to 0.92. Conclusions The study suggests that the use of a digital imaging system to capture images for either automated software analysis, or remote assessment by raters is suitable for epidemiological work. The use of recorded images enables study archiving, assessment by multiple examiners, remote assessment and objectivity due to the blinding of subject status.

Development of White-Light Emitting Active Layers in Nitride Based Heterostructures for Phosphorless Solid State Lighting

Energy Technology Data Exchange (ETDEWEB)

Jan Talbot; Kailash Mishra

2007-12-31

This report provides a summary of research activities carried out at the University of California, San Diego and Central Research of OSRAM SYLVANIA in Beverly, MA partially supported by a research contract from US Department of Energy, DE-FC26-04NT422274. The main objective of this project was to develop III-V nitrides activated by rare earth ions, RE{sup 3+}, which could eliminate the need for phosphors in nitride-based solid state light sources. The main idea was to convert electron-hole pairs injected into the active layer in a LED die to white light directly through transitions within the energy levels of the 4f{sup n}-manifold of RE{sup 3+}. We focused on the following materials: Eu{sup 3+}(red), Tb{sup 3+}(green), Er{sup 3+}(green), Dy{sup 3+}(yellow) and Tm{sup 3+}(blue) in AlN, GaN and alloys of AlN and GaN. Our strategy was to explore candidate materials in powder form first, and then study their behavior in thin films. Thin films of these materials were to be deposited on sapphire substrates using pulsed laser deposition (PLD) and metal organic vapor phase epitaxy (MOVPE). The photo- and cathode-luminescence measurements of these materials were used to investigate their suitability for white light generation. The project proceeded along this route with minor modifications needed to produce better materials and to expedite our progress towards the final goal. The project made the following accomplishments: (1) red emission from Eu{sup 3+}, green from Tb{sup 3+}, yellow from Dy{sup 3+} and blue from Tm{sup 3+} in AlN powders; (2) red emission from Eu{sup 3+} and green emission from Tb{sup 3+} in GaN powder; (3) red emission from Eu{sup 3+} in alloys of GaN and AlN; (4) green emission from Tb{sup 3+} in GaN thin films by PLD; (5) red emission from Eu{sup 3+} and Tb{sup 3+} in GaN thin films deposited by MOVPE; (6) energy transfer from host to RE{sup 3+}; (7) energy transfer from Tb{sup 3+} to Eu{sup 3+} in AlN powders; (8) emission from AlN powder samples

Efficient white organic light emitting devices with dual emitting layers

Energy Technology Data Exchange (ETDEWEB)

Wu Yaoshan [Department of Applied Chemistry, National Chiao Tung University, Hsinchu, Taiwan, 30050 (China); Hwang Shiaowen [Display Institute, Microelectronics and Information Systems Research Center, National Chiao Tung University, Hsinchu, Taiwan, 30050 (China)]. E-mail: jesse@faculty.nctu.edu.tw; Chen Hsianhung [Department of Applied Chemistry, National Chiao Tung University, Hsinchu, Taiwan, 30050 (China); Lee Mengting [Department of Applied Chemistry, National Chiao Tung University, Hsinchu, Taiwan, 30050 (China); Shen Wenjian [Department of Applied Chemistry, National Chiao Tung University, Hsinchu, Taiwan, 30050 (China); Chen, C.H. [Display Institute, Microelectronics and Information Systems Research Center, National Chiao Tung University, Hsinchu, Taiwan, 30050 (China)

2005-09-22

In this paper, a new white organic light-emitting device (OLED) with the structure of indium tin oxide / CF {sub x} / 1,4-bis[N-(1-naphthyl)-N'-phenylamino]-biphenyl (NPB) (30 nm)/NPB: 2,8-di(t-butyl)-5,11-di[4-(t-butyl)phenyl]-6,12-diphenylnaphthacene (20 nm; 1.6 %) / 2-methyl-9,10-di(2-naphthyl) anthracene: p-bis(p-N,N-di-phenyl-aminostyryl)benzene (40 nm, 3%) / aluminum tris(8-hydroxyquinoline) (20 nm) / LiF (1 nm) / Al (200 nm) has been investigated. The device showed white emission with a high-luminous yield of 9.75 cd/A at 20 mA/cm{sup 2}, but its Commission Internationale de l'Eclairage chromaticity coordinates appeared to change from (0.34, 0.42) at 6 mA/cm2 to (0.27, 0.37) at 200 mA/cm{sup 2} due to the shift of recombination zone. The change of color with drive current was suppressed by introduction of an electron-blocking layer of NPB along with a hole-blocking layer of aluminum (III) bis(2-methyl-8-quinolinato)4-phenylphenolato to the white OLED which successfully confined the recombination site and achieved a luminous yield of 9.9 cd/A at 20 mA/cm{sup 2}.

Organic light-emitting diodes with direct contact-printed red, green, blue, and white light-emitting layers

Science.gov (United States)

Chen, Sun-Zen; Peng, Shiang-Hau; Ting, Tzu-Yu; Wu, Po-Shien; Lin, Chun-Hao; Chang, Chin-Yeh; Shyue, Jing-Jong; Jou, Jwo-Huei

2012-10-01

We demonstrate the feasibility of using direct contact-printing in the fabrication of monochromatic and polychromatic organic light-emitting diodes (OLEDs). Bright devices with red, green, blue, and white contact-printed light-emitting layers with a respective maximum luminance of 29 000, 29 000, 4000, and 18 000 cd/m2 were obtained with sound film integrity by blending a polymeric host into a molecular host. For the red OLED as example, the maximum luminance was decreased from 29 000 to 5000 cd/m2 as only the polymeric host was used, or decreased to 7000 cd/m2 as only the molecular host was used. The markedly improved device performance achieved in the devices with blended hosts may be attributed to the employed polymeric host that contributed a good film-forming character, and the molecular host that contributed a good electroluminescence character.

EMISSION HEIGHT AND TEMPERATURE DISTRIBUTION OF WHITE-LIGHT EMISSION OBSERVED BY HINODE/SOT FROM THE 2012 JANUARY 27 X-CLASS SOLAR FLARE

International Nuclear Information System (INIS)

Watanabe, Kyoko; Shimizu, Toshifumi; Masuda, Satoshi; Ichimoto, Kiyoshi; Ohno, Masanori

2013-01-01

White-light emissions were observed from an X1.7 class solar flare on 2012 January 27, using three continuum bands (red, green, and blue) of the Solar Optical Telescope on board the Hinode satellite. This event occurred near the solar limb, and so differences in the locations of the various emissions are consistent with differences in heights above the photosphere of the various emission sources. Under this interpretation, our observations are consistent with the white-light emissions occurring at the lowest levels of where the Ca II H emission occurs. Moreover, the centers of the source regions of the red, green, and blue wavelengths of the white-light emissions are significantly displaced from each other, suggesting that those respective emissions are emanating from progressively lower heights in the solar atmosphere. The temperature distribution was also calculated from the white-light data, and we found the lower-layer emission to have a higher temperature. This indicates that high-energy particles penetrated down to near the photosphere, and deposited heat into the ambient lower layers of the atmosphere

2 Gbit/s data transmission from an unfiltered laser-based phosphor-converted white lighting communication system

KAUST Repository

Lee, Changmin; Shen, Chao; Oubei, Hassan M.; Cantore, Michael; Janjua, Bilal; Ng, Tien Khee; Farrell, Robert M.; El-Desouki, Munir M.; Speck, James S.; Nakamura, Shuji; Ooi, Boon S.; DenBaars, Steven P.

2015-01-01

We demonstrate data transmission of unfiltered white light generated by direct modulation of a blue gallium nitride (GaN) laser diode (LD) exciting YAG:Ce phosphors. 1.1 GHz of modulation bandwidth was measured without a limitation from the slow 3.8 MHz phosphor response. A high data transmission rate of 2 Gbit/s was achieved without an optical blue-filter using a non-return-to-zero on-off keying (NRZ-OOK) modulation scheme. The measured bit error rate (BER) of 3.50 × 10−3 was less than the forward error correction (FEC) limit of 3.8 × 10−3. The generated white light exhibits CIE 1931 chromaticity coordinates of (0.3628, 0.4310) with a color rendering index (CRI) of 58 and a correlated color temperature (CCT) of 4740 K when the LD was operated at 300 mA. The demonstrated laser-based lighting system can be used simultaneously for indoor broadband access and illumination applications with good color stability.

2 Gbit/s data transmission from an unfiltered laser-based phosphor-converted white lighting communication system

KAUST Repository

Lee, Changmin

2015-11-05

We demonstrate data transmission of unfiltered white light generated by direct modulation of a blue gallium nitride (GaN) laser diode (LD) exciting YAG:Ce phosphors. 1.1 GHz of modulation bandwidth was measured without a limitation from the slow 3.8 MHz phosphor response. A high data transmission rate of 2 Gbit/s was achieved without an optical blue-filter using a non-return-to-zero on-off keying (NRZ-OOK) modulation scheme. The measured bit error rate (BER) of 3.50 × 10−3 was less than the forward error correction (FEC) limit of 3.8 × 10−3. The generated white light exhibits CIE 1931 chromaticity coordinates of (0.3628, 0.4310) with a color rendering index (CRI) of 58 and a correlated color temperature (CCT) of 4740 K when the LD was operated at 300 mA. The demonstrated laser-based lighting system can be used simultaneously for indoor broadband access and illumination applications with good color stability.

Nonlinear polarization dynamics in a weakly birefringent all-normal dispersion photonic crystal fiber : toward a practical coherent fiber supercontinuum laser

DEFF Research Database (Denmark)

Tu, Haohua; Liu, Yuan; Liu, Xiaomin

2012-01-01

Dispersion-flattened dispersion-decreased all-normal dispersion (DFDD-ANDi) photonic crystal fibers have been identified as promising candidates for high-spectral-power coherent supercontinuum (SC) generation. However, the effects of the unintentional birefringence of the fibers on the SC generat...... of polarization-maintaining DFDD-ANDi fibers to avoid these adverse effects in pursuing a practical coherent fiber SC laser.......Dispersion-flattened dispersion-decreased all-normal dispersion (DFDD-ANDi) photonic crystal fibers have been identified as promising candidates for high-spectral-power coherent supercontinuum (SC) generation. However, the effects of the unintentional birefringence of the fibers on the SC...... generation have been ignored. This birefringence is widely present in nonlinear non-polarization maintaining fibers with a typical core size of 2 µm, presumably due to the structural symmetry breaks introduced in the fiber drawing process. We find that an intrinsic form-birefringence on the order of 10...

Adaptive Lighting Design – Staged Experiences of Light

DEFF Research Database (Denmark)

Petersen, Kjell Yngve; Søndergaard, Karin

in ways that meaningfully adapt. In the two installations, two different aspects are at play. In White Cube, the light colours are balanced. In White Box, the light follows the movements of the people in the space. In situations with several people occupying the same space, social relations become......Adaptive Lighting Design – Staged Experiences of Light The two installations, White Cube and White Box, enable experience-based studies as a form of perceptual activity, wherein lighting conditions are examined in a dialectical exchange between the system and the people participating. Adaptive...... lighting is based on a partial automation of the possibilities to adjust the colour tone and brightness levels of light in order to adapt to people’s needs and desires. Software can be seen to bear a communicative aesthetic, where the relation of user situations and the design intentions are controlled...

Power scaling of supercontinuum seeded megahertz-repetition rate optical parametric chirped pulse amplifiers.

Science.gov (United States)

Riedel, R; Stephanides, A; Prandolini, M J; Gronloh, B; Jungbluth, B; Mans, T; Tavella, F

2014-03-15

Optical parametric chirped-pulse amplifiers with high average power are possible with novel high-power Yb:YAG amplifiers with kW-level output powers. We demonstrate a compact wavelength-tunable sub-30-fs amplifier with 11.4 W average power with 20.7% pump-to-signal conversion efficiency. For parametric amplification, a beta-barium borate crystal is pumped by a 140 W, 1 ps Yb:YAG InnoSlab amplifier at 3.25 MHz repetition rate. The broadband seed is generated via supercontinuum generation in a YAG crystal.

High-efficiency tris(8-hydroxyquinoline)aluminum (Alq3) complexes for organic white-light-emitting diodes and solid-state lighting.

Science.gov (United States)

Pérez-Bolívar, César; Takizawa, Shin-ya; Nishimura, Go; Montes, Victor A; Anzenbacher, Pavel

2011-08-08

Combinations of electron-withdrawing and -donating substituents on the 8-hydroxyquinoline ligand of the tris(8-hydroxyquinoline)aluminum (Alq(3)) complexes allow for control of the HOMO and LUMO energies and the HOMO-LUMO gap responsible for emission from the complexes. Here, we present a systematic study on tuning the emission and electroluminescence (EL) from Alq(3) complexes from the green to blue region. In this study, we explored the combination of electron-donating substituents on C4 and C6. Compounds 1-6 displayed the emission tuning between 478 and 526 nm, and fluorescence quantum yield between 0.15 and 0.57. The compounds 2-6 were used as emitters and hosts in organic light-emitting diodes (OLEDs). The highest OLED external quantum efficiency (EQE) observed was 4.6%, which is among the highest observed for Alq(3) complexes. Also, the compounds 3-5 were used as hosts for red phosphorescent dopants to obtain white light-emitting diodes (WOLED). The WOLEDs displayed high efficiency (EQE up to 19%) and high white color purity (color rendering index (CRI≈85). Copyright © 2011 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

Photoluminescence properties of white light emitting La2O3:Dy3+ nanocrystals

Science.gov (United States)

Reenabati Devi, Konsam; Dorendrajit Singh, Shougaijam; David Singh, Th.

2018-01-01

White light emitting nanocrystalline La2O3:Dy3+ phosphors with different concentration (0.5-2 at.%) were synthesized by simple precipitation method. X-ray diffraction (XRD) pattern indicates all the samples crystallizes in the hexagonal phase. Average crystallite sizes of the samples calculated from XRD data were found to be in the range of 20-55 nm. Transmission electron microscopy, selected area electron diffraction, energy dispersive analysis of X-ray and photoluminescence (PL) of the samples are also reported. Strong PL excitation peak due to charge transfer band was observed at 230 nm. Photoluminescence emission peaks observed at 486 and 575 nm were probably attributed to 4F9/2-6H15/2 and 4F9/2-6H13/2 of Dy3+ ions respectively. Optimum luminescence intensity is found at 1 at.% Dy3+ doped La2O3 sample. Further, Commission Internationale de l'é clairage (CIE, 1931) co-ordinates and correlated color temperature (CCT) of the doped sample were calculated to investigate the phosphors' performance and technical applicability of the emitted light respectively. CCT of the 0.5 and 1 at.% samples is 5894 K (white light), within the range of vertical daylight, which makes the synthesised samples promising nanophosphor and may find application in simulating vertical daylight of the Sun.

Enabling Lambertian-Like Warm White Organic Light-Emitting Diodes with a Yellow Phosphor Embedded Flexible Film

Directory of Open Access Journals (Sweden)

Cheng-Chang Chen

2014-01-01

Full Text Available We demonstrate in this report a new constructive method of fabricating white organic light-emitting devices (OLEDs with a flexible plastic film embedded with yellow phosphor. The flexible film is composed of polydimethylsiloxane (PDMS and fabricated by using spin coating followed by peeling technology. From the results, the resultant electroluminescent spectrum shows the white OLED to have chromatic coordinates of 0.38 and 0.54 and correlated color temperature of 4200 K. The warm white OLED exhibits the yield of 10.3 cd/A and the luminous power efficiency of 5.4 lm/W at a luminance of 1000 cd/m2. A desirable Lambertian-like far-field pattern is detected from the white OLEDs with the yellow phosphor containing PDMS film. This method is simple, reproducible, and cost-effective, proving to be a highly feasible approach to realize white OLED.

Lambertian white top-emitting organic light emitting device with carbon nanotube cathode

Science.gov (United States)

Freitag, P.; Zakhidov, Al. A.; Luessem, B.; Zakhidov, A. A.; Leo, K.

2012-12-01

We demonstrate that white organic light emitting devices (OLEDs) with top carbon nanotube (CNT) electrodes show almost no microcavity effect and exhibit essentially Lambertian emission. CNT top electrodes were applied by direct lamination of multiwall CNT sheets onto white small molecule OLED stack. The devices show an external quantum efficiency of 1.5% and high color rendering index of 70. Due to elimination of the cavity effect, the devices show good color stability for different viewing angles. Thus, CNT electrodes are a viable alternative to thin semitransparent metallic films, where the strong cavity effect causes spectral shift and non-Lambertian angular dependence. Our method of the device fabrication is simple yet effective and compatible with virtually any small molecule organic semiconductor stack. It is also compatible with flexible substrates and roll-to-roll fabrication.

Topology of White Stars in Relativistic Fragmentation of Light Nuclei

CERN Document Server

Andreeva, N P; Vokal, S; Vokalova, A; Gaitinov, A Sh; Gerassimov, S G; Goncharova, L A; Dronov, V A; Zarubin, P I; Zarubina, I G; Kovalenko, A D; Kravchakova, A; Larionova, V G; Levitskaja, O V; Lepehin, F G; Malakhov, A I; Moiseenko, A A; Orlova, G I; Peresadko, N G; Polukhina, N G; Rukojatkin, P A; Rusakova, V V; Salmanova, N A; Sarkisian, V R; Simonov, B B; Stan, E; Stanoeva, R; Chernyavsky, M M; Haidue, M; Kharlamov, S P; Tsakov, I; Shchedrina, T V

2004-01-01

In the present paper, experimental observation of the multifragmentation processes of light relativistic nuclei carried out by means of emulsions are reviewed. Events of the type of "white stars" in which the dissociation of relativistic nuclei is not accompanied by the production of mesons and the target-nucleus fragments are considered. A distinctive feature of the charge topology in the dissociation of the Ne, Mg, Si and S nuclei is an almost total suppression of the binary splitting of nuclei to fragments with charges higher than 2. The growth of the nuclear fragmentation degree is revealed in an increase in the multiplicity of singly and doubly charged fragments with decreasing charge of the main non-excited part of the fragmenting nucleus. The processes of dissociation of stable Li, Be, B, C, N, and O isotopes to charged fragments were used to study special features of the formation of systems consisting of the lightest nuclei - alpha, d and t. Clustering of the 3He nucleus can be detected in "white sta...

Phase extracting algorithms analysis in the white-light spectral interferometry

Science.gov (United States)

Guo, Tong; Li, Bingtong; Li, Minghui; Chen, Jinping; Fu, Xing; Hu, Xiaotang

2018-01-01

As an optical testing method, white-light spectral interferometry has the characteristics of non-contact, high precision. The phase information can be obtained by analyzing the spectral interference signal of the tested sample, and then the absolute distance is calculated. Fourier transform method, temporal phase-shifting method, spatial phase-shifting method and envelope method can be used to extract the phase information of the spectral interference signal. In this paper, the performance of four methods to extract phase information is simulated and analyzed by using the ideal spectral interference signal. It turns out that temporal phase-shifting method has the performance of high precision, the results of Fourier transform method and envelop method are distorted at the edge of the signal, and spatial phase-shifting method has the worst precision. Adding different levels of white noise to the ideal signal, temporal phase-shifting method is most accurate, while Fourier transform method and envelope method are relatively poor. Finally, the absolute distance measurement experiment is carried out on the constructed test system, and the results are consistent with the simulation ones.

A novel single-phase white phosphor NaBaBO{sub 3}:Dy{sup 3+},K{sup +} for near-UV white light-emitting diodes

Energy Technology Data Exchange (ETDEWEB)

Zheng, Jianghui; Cheng, Qijin; Wu, Jieyang; Cui, Xin; Chen, Rong; Chen, Wenzhi [School of Energy Research, Xiamen University, Xiamen 361005 (China); Chen, Chao, E-mail: cchen@xmu.edu.cn [School of Energy Research, Xiamen University, Xiamen 361005 (China); School of Physics and Mechanical & Electrical Engineering, Xiamen University, Xiamen, 361005 (China)

2016-01-15

Highlights: • A white phosphor NaBaBO{sub 3}:Dy{sup 3+},K{sup +} with CIE coordinate (0.301, 0.308) was synthesized. • The optimum doping concentration of Dy{sup 3+} ions was found. • The effect and mechanism of K{sup +} ion as a charge compensator were discussed. • Temperature-dependent PL property of NaBaBO{sub 3}:Dy{sup 3+},K{sup +} was studied. • PL decay and quantum efficiency behaviors of the samples were investigated. - Abstract: A novel Dy{sup 3+}-doped NaBaBO{sub 3} white-emitting phosphor has been prepared by high temperature solid-state reaction method. The phase structure and luminescence properties of NaBaBO{sub 3}:Dy{sup 3+},K{sup +} samples were investigated. Photoluminescence results show that the as-prepared samples could be effectively excited by near-ultraviolet (NUV) light and generate white light emission due to the {sup 4}F{sub 9/2} → {sup 6}H{sub 15/2} (blue) transition and {sup 4}F{sub 9/2} → {sup 6}H{sub 13/2} (yellow) transition of Dy{sup 3+} ions, respectively. The optimum doping concentration of Dy{sup 3+} ions in the NaBaBO{sub 3} host was determined to be 5.0 mol% and the CIE chromaticity of the sample was determined to be (0.301, 0.308). Moreover, the mechanism of K{sup +} ion as a charge compensator on the improvement of photoluminescence property and the effect of temperature on the photoluminescence property of NaBaBO{sub 3}:Dy{sup 3+},K{sup +} were investigated. Furthermore, photoluminescence decay and quantum efficiency behaviors of NaBaBO{sub 3}:Dy{sup 3+},K{sup +} were also studied. The present work demonstrates that the NaBaBO{sub 3}:Dy{sup 3+},K{sup +} phosphor is a potential candidate for NUV white light emitting diodes.

A simple white noise analysis of neuronal light responses.

Science.gov (United States)

Chichilnisky, E J

2001-05-01

A white noise technique is presented for estimating the response properties of spiking visual system neurons. The technique is simple, robust, efficient and well suited to simultaneous recordings from multiple neurons. It provides a complete and easily interpretable model of light responses even for neurons that display a common form of response nonlinearity that precludes classical linear systems analysis. A theoretical justification of the technique is presented that relies only on elementary linear algebra and statistics. Implementation is described with examples. The technique and the underlying model of neural responses are validated using recordings from retinal ganglion cells, and in principle are applicable to other neurons. Advantages and disadvantages of the technique relative to classical approaches are discussed.

Energy Transfer between Conjugated Colloidal Ga2O3 and CdSe/CdS Core/Shell Nanocrystals for White Light Emitting Applications

Directory of Open Access Journals (Sweden)

Paul C. Stanish

2016-02-01

Full Text Available Developing solid state materials capable of generating homogeneous white light in an energy efficient and resource-sustainable way is central to the design of new and improved devices for various lighting applications. Most currently-used phosphors depend on strategically important rare earth elements, and rely on a multicomponent approach, which produces sub-optimal quality white light. Here, we report the design and preparation of a colloidal white-light emitting nanocrystal conjugate. This conjugate is obtained by linking colloidal Ga2O3 and II–VI nanocrystals in the solution phase with a short bifunctional organic molecule (thioglycolic acid. The two types of nanocrystals are electronically coupled by Förster resonance energy transfer owing to the short separation between Ga2O3 (energy donor and core/shell CdSe/CdS (energy acceptor nanocrystals, and the spectral overlap between the photoluminescence of the donor and the absorption of the acceptor. Using steady state and time-resolved photoluminescence spectroscopies, we quantified the contribution of the energy transfer to the photoluminescence spectral power distribution and the corresponding chromaticity of this nanocrystal conjugate. Quantitative understanding of this new system allows for tuning of the emission color and the design of quasi-single white light emitting inorganic phosphors without the use of rare-earth elements.

Energy Transfer between Conjugated Colloidal Ga2O3 and CdSe/CdS Core/Shell Nanocrystals for White Light Emitting Applications

Science.gov (United States)

Stanish, Paul C.; Radovanovic, Pavle V.

2016-01-01

Developing solid state materials capable of generating homogeneous white light in an energy efficient and resource-sustainable way is central to the design of new and improved devices for various lighting applications. Most currently-used phosphors depend on strategically important rare earth elements, and rely on a multicomponent approach, which produces sub-optimal quality white light. Here, we report the design and preparation of a colloidal white-light emitting nanocrystal conjugate. This conjugate is obtained by linking colloidal Ga2O3 and II–VI nanocrystals in the solution phase with a short bifunctional organic molecule (thioglycolic acid). The two types of nanocrystals are electronically coupled by Förster resonance energy transfer owing to the short separation between Ga2O3 (energy donor) and core/shell CdSe/CdS (energy acceptor) nanocrystals, and the spectral overlap between the photoluminescence of the donor and the absorption of the acceptor. Using steady state and time-resolved photoluminescence spectroscopies, we quantified the contribution of the energy transfer to the photoluminescence spectral power distribution and the corresponding chromaticity of this nanocrystal conjugate. Quantitative understanding of this new system allows for tuning of the emission color and the design of quasi-single white light emitting inorganic phosphors without the use of rare-earth elements. PMID:28344289

Fifty shades of white: how white feather brightness differs among species

Science.gov (United States)

Igic, Branislav; D'Alba, Liliana; Shawkey, Matthew D.

2018-04-01

White colouration is a common and important component of animal visual signalling and camouflage, but how and why it varies across species is poorly understood. White is produced by wavelength-independent and diffuse scattering of light by the internal structures of materials, where the degree of brightness is related to the amount of light scattered. Here, we investigated the morphological basis of brightness differences among unpigmented pennaceous regions of white body feathers across 61 bird species. Using phylogenetically controlled comparisons of reflectance and morphometric measurements, we show that brighter white feathers had larger and internally more complex barbs than duller white feathers. Higher brightness was also associated with more closely packed barbs and barbules, thicker and longer barbules, and rounder and less hollow barbs. Larger species tended to have brighter white feathers than smaller species because they had thicker and more complex barbs, but aquatic species were not significantly brighter than terrestrial species. As similar light scattering principals affect the brightness of chromatic signals, not just white colours, these findings help broaden our general understanding of the mechanisms that affect plumage brightness. Future studies should examine how feather layering on a bird's body contributes to differences between brightness of white plumage patches within and across species.

Ultrathin nondoped emissive layers for efficient and simple monochrome and white organic light-emitting diodes.

Science.gov (United States)

Zhao, Yongbiao; Chen, Jiangshan; Ma, Dongge

2013-02-01

In this paper, highly efficient and simple monochrome blue, green, orange, and red organic light emitting diodes (OLEDs) based on ultrathin nondoped emissive layers (EMLs) have been reported. The ultrathin nondoped EML was constructed by introducing a 0.1 nm thin layer of pure phosphorescent dyes between a hole transporting layer and an electron transporting layer. The maximum external quantum efficiencies (EQEs) reached 17.1%, 20.9%, 17.3%, and 19.2% for blue, green, orange, and red monochrome OLEDs, respectively, indicating the universality of the ultrathin nondoped EML for most phosphorescent dyes. On the basis of this, simple white OLED structures are also demonstrated. The demonstrated complementary blue/orange, three primary blue/green/red, and four color blue/green/orange/red white OLEDs show high efficiency and good white emission, indicating the advantage of ultrathin nondoped EMLs on constructing simple and efficient white OLEDs.

True Yellow Light-Emitting Diodes as Phosphor for Tunable Color-Rendering Index Laser-Based White Light

KAUST Repository

Janjua, Bilal; Ng, Tien Khee; Zhao, Chao; Prabaswara, Aditya; Consiglio, Giuseppe Bernardo; Priante, Davide; Shen, Chao; Elafandy, Rami T.; Anjum, Dalaver H.; Alhamoud, Abdullah A.; Alatawi, Abdullah A.; Yang, Yang; Alyamani, Ahmed Y.; El-Desouki, Munir M.; Ooi, Boon S.

2016-01-01

An urgent challenge for the lighting research community is the lack of efficient optical devices emitting in between 500 and 600 nm, resulting in the “green-yellow gap”. In particular, true green (∼555 nm) and true yellow (∼590 nm), along with blue and red, constitute four technologically important colors. The III-nitride material system, being the most promising choice of platform to bridge this gap, still suffers from high dislocation density and poor crystal quality in realizing high-power, efficient devices. Particularly, the high polarization fields in the active region of such 2D quantum confined structures prevent efficient recombination of carriers. Here we demonstrate a true yellow nanowire (NW) light emitting diode (LED) with peak emission of 588 nm at 29.5 A/cm2 (75 mA in a 0.5 × 0.5 mm2 device) and a low turn-on voltage of ∼2.5 V, while having an internal quantum efficiency of 39%, and without “efficiency droop” up to an injection current density of 29.5 A/cm2. By mixing yellow light from a NW LED in reflective configuration with that of a red, green, and blue laser diode (LD), white light with a correlated color temperature of ∼6000 K and color-rendering index of 87.7 was achieved. The nitride-NW-based device offers a robust, long-term stability for realizing yellow light emitters for tunable color-rendering index solid-state lighting, on a scalable, low-cost, foundry-compatible titanium/silicon substrate, suitable for industry uptake.

True Yellow Light-Emitting Diodes as Phosphor for Tunable Color-Rendering Index Laser-Based White Light

KAUST Repository

Janjua, Bilal

2016-10-11

An urgent challenge for the lighting research community is the lack of efficient optical devices emitting in between 500 and 600 nm, resulting in the “green-yellow gap”. In particular, true green (∼555 nm) and true yellow (∼590 nm), along with blue and red, constitute four technologically important colors. The III-nitride material system, being the most promising choice of platform to bridge this gap, still suffers from high dislocation density and poor crystal quality in realizing high-power, efficient devices. Particularly, the high polarization fields in the active region of such 2D quantum confined structures prevent efficient recombination of carriers. Here we demonstrate a true yellow nanowire (NW) light emitting diode (LED) with peak emission of 588 nm at 29.5 A/cm2 (75 mA in a 0.5 × 0.5 mm2 device) and a low turn-on voltage of ∼2.5 V, while having an internal quantum efficiency of 39%, and without “efficiency droop” up to an injection current density of 29.5 A/cm2. By mixing yellow light from a NW LED in reflective configuration with that of a red, green, and blue laser diode (LD), white light with a correlated color temperature of ∼6000 K and color-rendering index of 87.7 was achieved. The nitride-NW-based device offers a robust, long-term stability for realizing yellow light emitters for tunable color-rendering index solid-state lighting, on a scalable, low-cost, foundry-compatible titanium/silicon substrate, suitable for industry uptake.

ITO/metal/ITO anode for efficient transparent white organic light-emitting diodes

Science.gov (United States)

Joo, Chul Woong; Lee, Jonghee; Sung, Woo Jin; Moon, Jaehyun; Cho, Nam Sung; Chu, Hye Yong; Lee, Jeong-Ik

2015-02-01

We report on the characteristics of enhanced and balanced white-light emission of transparent organic light emitting diodes (TOLEDs) by introducing anode that has a stack structure of ITO/metal/ITO (IMI). We have investigated an anode that has a stack structure of IMI. IMI anodes are typically composed of a thin Ag layer (˜15 nm) sandwiched between two ITO layers (˜50 nm). By inserting an Ag layer it was possible to achieve sheet resistance lower than 3 Ω/sq. and transmittance of 86% at a wavelength of 550 nm. The Ag insert can act as a reflective component. With its counterpart, a transparent cathode made of a thin Ag layer (˜15 nm), micro-cavities (MC) can be effectively induced in the OLED, leading to improved performance. Using an IMI anode, it was possible to significantly increase the current efficiencies. The current efficiencies of the top and the bottom of the IMI TOLED increased to 23.0 and 15.6 cd/A, respectively, while those of the white TOLED with the ITO anode were 20.7 and 5.1 cd/A, respectively. A 30% enhancement in the overall current efficiency was achieved by taking advantage of the MC effect and the low sheet resistance.

Multiregion, multigroup collision probability method with white boundary condition for light water reactor thermalization calculations

International Nuclear Information System (INIS)

Ozgener, B.; Ozgener, H.A.

2005-01-01

A multiregion, multigroup collision probability method with white boundary condition is developed for thermalization calculations of light water moderated reactors. Hydrogen scatterings are treated by Nelkin's kernel while scatterings from other nuclei are assumed to obey the free-gas scattering kernel. The isotropic return (white) boundary condition is applied directly by using the appropriate collision probabilities. Comparisons with alternate numerical methods show the validity of the present formulation. Comparisons with some experimental results indicate that the present formulation is capable of calculating disadvantage factors which are closer to the experimental results than alternative methods

Using interlayer step-wise triplet transfer to achieve an efficient white organic light-emitting diode with high color-stability

Energy Technology Data Exchange (ETDEWEB)

Wang, Qi [State Key Laboratory of Polymer Physics and Chemistry, Changchun Institute of Applied Chemistry, Chinese Academy of Sciences, Changchun, Jilin 130022 (China); Department of Electrical Engineering and Computer Sciences, College of Engineering, South Dakota State University, Brookings, South Dakota 57007 (United States); Ma, Dongge, E-mail: mdg1014@ciac.jl.cn; Ding, Junqiao; Wang, Lixiang [State Key Laboratory of Polymer Physics and Chemistry, Changchun Institute of Applied Chemistry, Chinese Academy of Sciences, Changchun, Jilin 130022 (China); Leo, Karl [Tech. Univ. Dresden, Inst. Angew. Photophys., D-01062 Dresden (Germany); Qiao, Qiquan [Department of Electrical Engineering and Computer Sciences, College of Engineering, South Dakota State University, Brookings, South Dakota 57007 (United States); Jia, Huiping; Gnade, Bruce E. [Department of Materials Science and Engineering and Erik Jonsson School of Engineering and Computer Science, University of Texas at Dallas, Richardson, Texas 75083 (United States)

2014-05-12

An efficient phosphorescent white organic light emitting-diode with a red-green-blue tri-emitting-layer structure is reported. The host of the red dopant possesses a lower triplet-energy than the green dye. An interlayer step-wise triplet transfer via blue dye → green dye → red host → red dye is achieved. This mechanism allows an efficient triplet harvesting by the three dopants, thus maintaining a balanced white light and reducing energy loss. Moreover, the color stability of the device is improved significantly. The white device not only achieves a peak external quantum efficiency of 21.1 ± 0.8% and power efficiency of 37.5 ± 1.4 lm/W but shows no color shift over a wide range of voltages.

Generation of an XUV supercontinuum by optimization of the angle between polarization planes of two linearly polarized pulses in a multicycle two-color laser field

International Nuclear Information System (INIS)

Yao Jinping; Zeng Bin; Fu Yuxi; Chu Wei; Ni Jielei; Li Yao; Xiong Hui; Xu Han; Cheng Ya; Xu Zhizhan; Liu Xiaojun; Chen, J.

2010-01-01

We theoretically investigate the high-order harmonic generation (HHG) in helium using a two-color laser field synthesized by an intense 25-fs laser pulse at 800 nm and a relatively weak ∼43-fs laser pulse at 1400 nm. When the polarization between the two pulses is arranged at an angle of ∼73 deg., supercontinuum spectra are dramatically broadened to 180 eV, which is sufficient to support an isolated ∼73-as pulse without any phase compensation. The physical mechanisms behind the phenomenon are well explained in terms of quantum and classical analyses. Furthermore, in the long-pulse regime, this method of extending the supercontinuum spectrum shows the significant advantage over previous two-color HHG schemes.

Monte Carlo analysis of a control technique for a tunable white lighting system

DEFF Research Database (Denmark)

Chakrabarti, Maumita; Thorseth, Anders; Jepsen, Jørgen

2017-01-01

A simulated colour control mechanism for a multi-coloured LED lighting system is presented. The system achieves adjustable and stable white light output and allows for system-to-system reproducibility after application of the control mechanism. The control unit works using a pre-calibrated lookup...... table for an experimentally realized system, with a calibrated tristimulus colour sensor. A Monte Carlo simulation is used to examine the system performance concerning the variation of luminous flux and chromaticity of the light output. The inputs to the Monte Carlo simulation, are variations of the LED...... peak wavelength, the LED rated luminous flux bin, the influence of the operating conditions, ambient temperature, driving current, and the spectral response of the colour sensor. The system performance is investigated by evaluating the outputs from the Monte Carlo simulation. The outputs show...

Output blue light evaluation for phosphor based smart white LED wafer level packages.

Science.gov (United States)

Kolahdouz, Zahra; Rostamian, Ali; Kolahdouz, Mohammadreza; Ma, Teng; van Zeijl, Henk; Zhang, Kouchi

2016-02-22

This study presents a blue light detector for evaluating the output light of phosphor based white LED package. It is composed of a silicon stripe-shaped photodiode designed and implemented in a 2 μm BiCMOS process which can be used for wafer level integration of different passive and active devices all in just 5 lithography steps. The final device shows a high selectivity to blue light. The maximum responsivity at 480 nm is matched with the target blue LED illumination. The designed structure have better responsivity compared to simple photodiode structure due to reducing the effect of dead layer formation close to the surface because of implantation. It has also a two-fold increase in the responsivity and quantum efficiency compared to previously similar published sensors.

A novel orange emissive phosphor SrWO4:Sm3+ for white light-emitting diodes

International Nuclear Information System (INIS)

Ju Zhenghua; Wei Ruiping; Ma Jingxin; Pang Chaoran; Liu Weisheng

2010-01-01

Research highlights: → A novel orange emissive phosphor SrWO 4 :Sm 3+ was firstly reported. → The optics properties of Sm 3+ -doped SrWO 4 phosphor were successfully discussed. → The temperature-dependent luminescence indicates the phosphor exhibits a small thermal-quenching property. → The phosphor is a potential candidate as orange-emitting component for white LED. - Abstract: A novel orange emissive phosphor, Sm 3+ -doped SrWO 4 , was synthesized by high temperature solid-state reaction in air atmosphere. The excitation spectra show that the phosphors can be efficiently excited by ultraviolet and near-ultraviolet light, the optimized concentration is 4 mol%. Three emission peaks locate at 562, 596 and 642 nm, corresponding to CIE chromaticity coordinates of (x = 0.54, y = 0.46), which indicates the orange light emitting. The decay curves are well fitted with triple-exponential decay models. The quantum yield of the Sr 0.96 Sm 0.04 WO 4 phosphor is about 70.65% under excitation of 377 nm. Furthermore, the temperature-dependent luminescence indicates the phosphor exhibits a small thermal-quenching property. So the phosphor is able to be applied to UV-LED chip-based white light-emitting diodes.

Efficient Color-Stable Inverted White Organic Light-Emitting Diodes with Outcoupling-Enhanced ZnO Layer.

Science.gov (United States)

Zhao, Xin-Dong; Li, Yan-Qing; Xiang, Heng-Yang; Zhang, Yi-Bo; Chen, Jing-De; Xu, Lu-Hai; Tang, Jian-Xin

2017-01-25

Inverted organic light-emitting diode (OLED) has attracted extensive attention due to the demand in active-matrix OLED display panels as its geometry enables the direct connection with n-channel transistor backplane on the substrate. One key challenge of high-performance inverted OLED is an efficient electron-injection layer with superior electrical and optical properties to match the indium tin oxide cathode on substrate. We here propose a synergistic electron-injection architecture using surface modification of ZnO layer to simultaneously promote electron injection into organic emitter and enhance out-coupling of waveguided light. An efficient inverted white OLED is realized by introducing the nanoimprinted aperiodic nanostructure of ZnO for broadband and angle-independent light out-coupling and inserting an n-type doped interlayer for energy level tuning and injection barrier lowering. As a result, the optimized inverted white OLEDs have an external quantum efficiency of 42.4% and a power efficiency of 85.4 lm W 1- , which are accompanied by the superiority of angular color stability over the visible wavelength range. Our results may inspire a promising approach to fabricate high-efficiency inverted OLEDs for large-scale display panels.

Single component Mn-doped perovskite-related CsPb2ClxBr5-x nanoplatelets with a record white light quantum yield of 49%: a new single layer color conversion material for light-emitting diodes.

Science.gov (United States)

Wu, Hao; Xu, Shuhong; Shao, Haibao; Li, Lang; Cui, Yiping; Wang, Chunlei

2017-11-09

Single component nanocrystals (NCs) with white fluorescence are promising single layer color conversion media for white light-emitting diodes (LED) because the undesirable changes of chromaticity coordinates for the mixture of blue, green and red emitting NCs can be avoided. However, their practical applications have been hindered by the relative low photoluminescence (PL) quantum yield (QY) for traditional semiconductor NCs. Though Mn-doped perovskite nanocube is a potential candidate, it has been unable to realize a white-light emission to date. In this work, the synthesis of Mn-doped 2D perovskite-related CsPb 2 Cl x Br 5-x nanoplatelets with a pure white emission from a single component is reported. Unlike Mn-doped perovskite nanocubes with insufficient energy transfer efficiency, the current reported Mn-doped 2D perovskite-related CsPb 2 Cl x Br 5-x nanoplatelets show a 10 times higher energy transfer efficiency from perovskite to Mn impurities at the required emission wavelengths (about 450 nm for perovskite emission and 580 nm for Mn emission). As a result, the Mn/perovskite dual emission intensity ratio surprisingly elevates from less than 0.25 in case of Mn-doped nanocubes to 0.99 in the current Mn-doped CsPb 2 Cl x Br 5-x nanoplatelets, giving rise to a pure white light emission with Commission Internationale de l'Eclairage (CIE) color coordinates of (0.35, 0.32). More importantly, the highest PL QY for Mn-doped perovskite-related CsPb 2 Cl x Br 5-x nanoplatelets is up to 49%, which is a new record for white-emitting nanocrystals with single component. These highly luminescent nanoplatelets can be blended with polystyrene (PS) without changing the white light emission but dramatically improving perovskite stability. The perovskite-PS composites are available not only as a good solution processable coating material for assembling LED, but also as a superior conversion material for achieving white light LED with a single conversion layer.

Reduction of chromatic aberration influences in vertical scanning white-light interferometry

International Nuclear Information System (INIS)

Lehmann, Peter; Kühnhold, Peter; Xie, Weichang

2014-01-01

Vertical scanning white-light interferometry (SWLI) is a well-established method that is widely used in high precision surface topography measurement. However, SWLI results show characteristic slope-dependent errors due to dispersion effects and lateral chromatic aberrations of the optical imaging system. In this paper, we present methods to characterize these systematic errors related to dispersion and lateral colour. Lateral colour leads to field-dependent systematic discrepancies of the topography data obtained from the envelope position of a low-coherence interference signal and the data resulting from its interference phase. Hence, an erroneous fringe order obtained from the envelope position leads to a 2π phase jump and thus to a so-called ghost step in the measured topography. Our first approach to solve this problem is based on the measurement of a surface standard of well-known geometry. By comparison of measurement results related to the envelope position and the phase of SWLI signals, the systematic error is estimated and a numerical error compensation method is proposed. Both experimental and simulation results confirm the validity of this numerical method. In addition, using an improved design of a white-light Michelson interferometer we demonstrate experimentally that lateral chromatic aberrations and dispersion influences can be reduced also in a physical way. In this context, a conventional long working distance microscope objective is used which was not originally designed for a Michelson interference microscope. (paper)

Can 3D light localization be reached in ‘white paint’?

International Nuclear Information System (INIS)

Sperling, T; Schertel, L; Aubry, G J; Maret, G; Ackermann, M; Aegerter, C M

2016-01-01

When waves scatter multiple times in 3D random media, a disorder driven phase transition from diffusion to localization may occur (Anderson 1958 Phys. Rev. 109 1492–505; Abrahams et al 1979 Phys. Rev. Lett. 42 673–6). In ‘The question of classical localization: a theory of white paint?’ Anderson suggested the possibility to observe light localization in TiO 2 samples (Anderson 1985 Phil. Mag. B 52 505–9). We recently claimed the observation of localization effects measuring photon time of flight (ToF) distributions (Störzer et al 2006 Phys. Rev. Lett. 96 063904) and evaluating transmission profiles (TPs) (Sperling et al 2013 Nat. Photonics 7 48–52) in such TiO 2 samples. Here we present a careful study of the long time tail of ToF distributions and the long time behavior of the TP width for very thin samples and different turbidities that questions the localization interpretation. We further show new data that allow an alternative consistent explanation of these previous data by a fluorescence process. An adapted diffusion model including an appropriate exponential fluorescence decay accounts for the shape of the ToF distributions and the TP width. These observations question whether the strong localization regime can be reached with visible light scattering in polydisperse TiO 2 samples, since the disorder parameter can hardly be increased any further in such a ‘white paint’ material. (paper)

[White organic light emitting device with dyestuff DCJTB blended in polymer].

Science.gov (United States)

Zhang, Yan-Fei; Xu, Zheng; Zhang, Fu-Jun; Wang, Yong; Zhao, Su-Ling

2008-04-01

The Alq3 and DCJTB were blended with poly (N-vinylcarbazole) (PVK) in different weight ratios and spin coated into films. Multilayer devices with the light emitting layer PVK : Alq3 : DCJTB were fabricated, and their structure was ITO/ PVK : Alq3 : DCJTB/ BCP/Alq3/LiF/Al in which BCP and Alq3 were employed as the hole-blocking and electron-transporting layers respectively, PVK is the blue light-emitting as well as hole-transporting layer. The mass proportion of PVK relative to Alq3 was tuned while the quality ratio of PVK to DCJTB remained (100 : 1). Finally, fairly pure and stabile white emission was achieved when PVK : Alq3 : DCJTB was 100 : 5 : 1. The CIE coordinate was (0.33, 0.36) at 14 V, which is very stable at various biases (10-14 V).

The dynamic characteristics and linewidth enhancement factor of quasi-supercontinuum self-assembled quantum dot lasers

KAUST Repository

Tan, Cheeloon

2009-09-01

The theoretical analysis of optical gain and chirp characteristics of a semiconductor quantum dot (Qdot) broadband laser is presented. The model based on population rate equations, has been developed to investigate the multiple states lasing or quasi-supercontinuum lasing in InGaAs/GaAs Qdot laser. The model takes into account factors such as Qdot size fluctuation, finite carrier lifetime in each confined energy states, wetting layer induced nonconfined states and the presence of continuum states. Hence, calculation of the linewidth enhancement factor together with the variation of optical gain and index change across the spectrum of interest becomes critical to yield a basic understanding on the limitation of this new class of lasers. Such findings are important for the design of a practical single broadband laser diode for applications in low coherence interferometry sensing and optical fiber communications. Calculation results show that the linewidth enhancement factor from the ground state of broadband Qdot lasers (α ∼ 3) is slightly larger but in the same order of magnitude as compared to that of conventional Qdot lasers. The gain spectrum of the quasi-supercontinuum lasing system exhibits almost twice the bandwidth than conventional lasers but with comparable material differential gain (∼ 10-16 cm2) and material differential refractive index (∼ 10sup>-20 cm3 ) near current threshold. © 2009 IEEE.

The dynamic characteristics and linewidth enhancement factor of quasi-supercontinuum self-assembled quantum dot lasers

KAUST Repository

Tan, Cheeloon; Wang, Yang; Djie, Hery Susanto; Ooi, Boon S.

2009-01-01

The theoretical analysis of optical gain and chirp characteristics of a semiconductor quantum dot (Qdot) broadband laser is presented. The model based on population rate equations, has been developed to investigate the multiple states lasing or quasi-supercontinuum lasing in InGaAs/GaAs Qdot laser. The model takes into account factors such as Qdot size fluctuation, finite carrier lifetime in each confined energy states, wetting layer induced nonconfined states and the presence of continuum states. Hence, calculation of the linewidth enhancement factor together with the variation of optical gain and index change across the spectrum of interest becomes critical to yield a basic understanding on the limitation of this new class of lasers. Such findings are important for the design of a practical single broadband laser diode for applications in low coherence interferometry sensing and optical fiber communications. Calculation results show that the linewidth enhancement factor from the ground state of broadband Qdot lasers (α ∼ 3) is slightly larger but in the same order of magnitude as compared to that of conventional Qdot lasers. The gain spectrum of the quasi-supercontinuum lasing system exhibits almost twice the bandwidth than conventional lasers but with comparable material differential gain (∼ 10-16 cm2) and material differential refractive index (∼ 10sup>-20 cm3 ) near current threshold. © 2009 IEEE.

Design of a High-Power White Light Source with Colloidal Quantum Dots and Non-Rare-Earth Phosphors

Science.gov (United States)

Bicanic, Kristopher T.

This thesis describes the design process of a high-power white light source, using novel phosphor and colloidal quantum dot materials. To incorporate multiple light emitters, we generalized and extended a down-converting layer model. We employed a phosphor mixture comprising of YAG:Ce and K2TiF 6:Mn4+ powders to illustrate the effectiveness of the model. By incorporating experimental photophysical results from the phosphors and colloidal quantum dots, we modeled our system and chose the design suitable for high-power applications. We report a reduction in the correlated color temperature by 600K for phosphor and quantum dot systems, enabling the creation of a warm white light emission at power densities up to 5 kW/cm 2. Furthermore, at this high-power, their emission achieves the digital cinema initiative (DCI) requirements with a luminescence efficacy improvement up to 32% over the stand-alone ceramic YAG:Ce phosphor.

White light emission from an exciplex interface with a single emitting layer (Conference Presentation)

Science.gov (United States)

Bernal, Wilson; Perez-Gutierrez, Enrique; Agular, Andres; Barbosa G, J. Oracio C.; Maldonado, Jose L.; Meneses-Nava, Marco Antonio; Rodriguez Rivera, Mario A.; Rodriguez, Braulio

2017-02-01

Efficient solid state lighting devices based in inorganic emissive materials are now available in the market meanwhile for organic emissive materials still a lot of research work is in its way. [1,2] In this work a new organic emissive material based on carbazole, N-(4-Ethynylphenyl) carba-zole-d4 (6-d4), is used as electron-acceptor and commercial PEDOT:PSS as the electron-donor to obtain white emission. Besides the HOMO-LUMO levels of materials the white emission showed dependence on the films thicknesses and applied voltages. In here it is reported that by diminishing the thickness of the PEDOT:PSS layer, from 60 to 35 nm, and by keeping the derivative carbazole layer constant at 100 nm the electro-luminescence (EL) changed from emissive exciton states to the mixture of emissive exciton and exciplex states. [3] For the former thicknesses no white light was obtained meanwhile for the later the EL spectra broadened due to the emission of exciplex states. Under this condition, the best-achieved CIE coordinate was (0.31,0.33) with a driving voltage of 8 V. To lower the driving voltage of the devices a thin film of LiF was added between the derivative of carbazol and cathode but the CIE coordinates changed. The best CIE coordinates for this case were (0.29, 0.34) and (0.32, 0.37) with driving voltage of about 6.5 V. Acknowledgments: CeMie-Sol/27 (Mexico) 207450 References [1] Timothy L Dawson, Society of Dyers and Colourists, Color. Technol., 126, 1-10 (2010), doi: 10.1111/j.1478-4408.2010.00220.x [2] G. M. Farinola, R. Ragni, Journal of Solid State Lighting, 2:9 (2015), doi: 10.1186/s40539-015-0028-7. [3] E. Angioni, et al, J. Mater. Chem. C, 2016, 4, 3851, doi: 10.1039/c6tc00750c.

Smart design to resolve spectral overlapping of phosphor-in-glass for high-powered remote-type white light-emitting devices.

Science.gov (United States)

Lee, Jin Seok; Arunkumar, P; Kim, Sunghoon; Lee, In Jae; Lee, Hyungeui; Im, Won Bin

2014-02-15

The white light-emitting diode (WLED) is a state-of-the-art solid state technology, which has replaced conventional lighting systems due to its reduced energy consumption, its reliability, and long life. However, the WLED presents acute challenges in device engineering, due to its lack of color purity, efficacy, and thermal stability of the lighting devices. The prime cause for inadequacies in color purity and luminous efficiency is the spectral overlapping of red components with yellow/green emissions when generating white light by pumping a blue InGaN chip with yellow YAG:Ce³⁺ phosphor, where red phosphor is included, to compensate for deficiencies in the red region. An innovative strategy was formulated to resolve this spectral overlapping by alternatively arranging phosphor-in-glass (PiG) through cutting and reassembling the commercial red CaAlSiN₃:Eu²⁺ and green Lu₃Al₅O₁₂:Ce³⁺ PiG. PiGs were fabricated using glass frits with a low softening temperature of 600°C, which exhibited excellent thermal stability and high transparency, improving life time even at an operating temperature of 200°C. This strategy overcomes the spectral overlapping issue more efficiently than the randomly mixed and patented stacking design of multiple phosphors for a remote-type WLED. The protocol for the current design of PiG possesses excellent thermal and chemical stability with high luminous efficiency and color purity is an attempt to make smarter solid state lighting for high-powered remote-type white light-emitting devices.

Prevention of the appearance of light-struck taste in white wine = Prevenzione della comparsa del gusto di luce nel vino bianco

OpenAIRE

Fracassetti, D.; Gabrielli, M.; Encinas, J.; Manara, M.; Pellegrino, L.; Tirelli, A.

2016-01-01

The light-struck taste is a defect of bottled white wine due to the light exposure and involving the riboflavin (RF), as a photosensitizer, and methionine. The reaction pathways lead to the formation of volatile sulfur compounds, methanethiol and dimethyldisulphide, conferring cabbage-like aromas. The development of this defect is limited at low RF concentrations. In this study, the yeast-mediated release of RF, RF degradation kinetics in model solution and white wine, and RF removal by using...

All-photonic drying and sintering process via flash white light combined with deep-UV and near-infrared irradiation for highly conductive copper nano-ink

Science.gov (United States)

Hwang, Hyun-Jun; Oh, Kyung-Hwan; Kim, Hak-Sung

2016-01-01

We developed an ultra-high speed photonic sintering method involving flash white light (FWL) combined with near infrared (NIR) and deep UV light irradiation to produce highly conductive copper nano-ink film. Flash white light irradiation energy and the power of NIR/deep UV were optimized to obtain high conductivity Cu films. Several microscopic and spectroscopic characterization techniques such as scanning electron microscopy (SEM), a x-ray diffraction (XRD), and Fourier-transform infrared (FT-IR) spectroscopy were employed to characterize the Cu nano-films. Optimally sintered Cu nano-ink films produced using a deep UV-assisted flash white light sintering technique had the lowest resistivity (7.62 μΩ·cm), which was only 4.5-fold higher than that of bulk Cu film (1.68 μΩ•cm). PMID:26806215

Semipolar GaN-based laser diodes for Gbit/s white lighting communication: devices to systems

KAUST Repository

Lee, Changmin

2018-02-23

We report the high-speed performance of semipolar GaN ridge laser diodes at 410 nm and the dynamic characteristics including differential gain, damping, and the intrinsic maximum bandwidth. To the best of our knowledge, the achieved modulation bandwidth of 6.8 GHz is the highest reported value in the blue-violet spectrum. The calculated differential gain of ~3 x 10-16 cm2, which is a critical factor in high-speed modulation, proved theoretical predictions of higher gain in semipolar GaN laser diodes than the conventional c-plane counterparts. In addition, we demonstrate the first novel white lighting communication system by using our near-ultraviolet (NUV) LDs and pumping red-, green-, and blueemitting phosphors. This system satisfies both purposes of high-speed communication and high-quality white light illumination. A high data rate of 1.5 Gbit/s using on-off keying (OOK) modulation together with a high color rendering index (CRI) of 80 has been measured.

Radio and white-light observations of coronal transients

International Nuclear Information System (INIS)

Dulk, G.A.

1980-01-01

Optical, radio and X-ray evidence of violent mass motions in the corona has existed for some years but only recently have the form, nature, frequency and implication of the transients become obvious. The author reviews the observed properties of coronal transients, concentrating on the white-light and radio manifestations. The classification according to speeds seems to be meaningful, with the slow transients having thermal emissions at radio wavelengths and the fast ones non-thermal. The possible mechanisms involved in the radio bursts are discussed and the estimates of various forms of energy are reviewed. It appears that the magnetic energy transported from the Sun by the transient exceeds that of any other form, and that magnetic forces dominate in the dynamics of the motions. The conversion of magnetic energy into mechanical energy, by expansion of the fields, provides a possible driving force for the coronal and interplanetary shock waves. (Auth.)

Theoretical characterization of a class of orange dopants for white-light-emitting single polymers

International Nuclear Information System (INIS)

Hu, Bo; Yao, Chan; Wang, Qingwei; Zhang, Hao; Yu, Jiankang

2012-01-01

New single-polymer white electroluminescent systems containing two individual emission species − polyfluorene as a blue host and 2,1,3-benzothiadiazole(BTD) derivative as an orange dopant − have been designed and investigated on the basis of the quantum chemical calculations. Calculations show that the change of chemical composition along the backbone in BTD-based derivative yields modifications to the electronic and optical properties. Furthermore, by introducing electron-donating groups [−CH 3 , –OCH 3 , and –NH 2 ] on terminal N,N-disubstituted amino groups, desirable orange emission can be obtained and may be further combined with polyfluorene to form white light. Also, we estimate the reorganization energies upon cation or anion formation as one of the important parameters of mobility with the charge hopping model to determine whether the molecular structural changes may improve the hole/electron transport. The electrostatic surface potentials are finally taken into account to evaluate stability. -- Graphical abstract: New single-polymer white electroluminescent systems containing two individual emission species − polyfluorene as a blue host and 2,1,3-benzothiadiazole(BTD) derivative as an orange dopant − have been designed and investigated on the basis of the quantum chemical calculations. Highlights: ► The change of chemical composition along the backbone yields modifications to the electronic and optical properties. ► Introducing [–CH 3 , –OCH 3 , and –NH 2 ] on terminal N,N-disubstituted amino groups, desirable orange emission can be obtained. ► Desirable orange emission may be further combined with polyfluorene to form white light. ► Designed BTD-based derivatives can function as good hole or ambipolar transport materials in the OLEDs. ► According to the calculated electrostatic surface potentials, OMC-PZ has better stability than that of OMC-PZT.

Highly efficient white organic light-emitting devices consisting of undoped ultrathin yellow phosphorescent layer

Energy Technology Data Exchange (ETDEWEB)

Liu, Shengqiang [State Key Laboratory of Electronic Thin Films and Integrated Devices, School of Optoelectronic Information, University of Electronic Science and Technology of China (UESTC), Chengdu 610054 (China); Yu, Junsheng, E-mail: jsyu@uestc.edu.cn [State Key Laboratory of Electronic Thin Films and Integrated Devices, School of Optoelectronic Information, University of Electronic Science and Technology of China (UESTC), Chengdu 610054 (China); Ma, Zhu; Zhao, Juan [State Key Laboratory of Electronic Thin Films and Integrated Devices, School of Optoelectronic Information, University of Electronic Science and Technology of China (UESTC), Chengdu 610054 (China)

2013-02-15

High-efficiency white organic light-emitting devices (WOLEDs) based on an undoped ultrathin yellow light-emitting layer and a doped blue light-emitting layer were demonstrated. While the thickness of blue light-emitting layer, formed by doping a charge-trapping phosphor, iridium(III) bis(4 Prime ,6 Prime -difluorophenylpyridinato)tetrakis(1-pyrazolyl)borate (FIr6) in a wide bandgap host, was kept constant, the thickness of neat yellow emissive layer of novel phosphorescent material, bis[2-(4-tertbutylphenyl)benzothiazolato-N,C{sup 2 Prime }]iridium (acetylacetonate) [(t-bt){sub 2}Ir(acac)] was varied to optimize the device performance. The optimized device exhibited maximum luminance, current efficiency and power efficiency of 24,000 cd/m{sup 2} (at 15.2 V), 79.0 cd/A (at 1550 cd/m{sup 2}) and 40.5 lm/W (at 1000 cd/m{sup 2}), respectively. Besides, the white-light emission covered a wide range of visible spectrum, and the Commission Internationale de l'Eclairage coordinates were (0.32, 0.38) with a color temperature of 5800 K at 8 V. Moreover, high external quantum efficiency was also obtained in the high-efficiency WOLEDs. The performance enhancement was attributed to the proper thickness of (t-bt){sub 2}Ir(acac) layer that enabled adequate current density and enough phosphorescent dye to trap electrons. - Highlights: Black-Right-Pointing-Pointer Highly efficient WOLEDs based on two complementary layers were fabricated. Black-Right-Pointing-Pointer The yellow emissive layer was formed by utilizing undoping system. Black-Right-Pointing-Pointer The blue emissive layer was made by host-guest doping system. Black-Right-Pointing-Pointer The thickness of the yellow emissive layer was varied to make device optimization. Black-Right-Pointing-Pointer The optimized device achieved high power efficiency of 40.5 lm/W.

Activation of anthocyanin synthesis genes by white light in eggplant hypocotyl tissues, and identification of an inducible P-450 cDNA

International Nuclear Information System (INIS)

Toguri, T.; Umemoto, N.; Kobayashi, O.; Ohtani, T.

1993-01-01

Eggplant seedlings (Solanum melongena) grown under red light irradiation showed a normal morphology with green, fully expanded cotyledons. When the seedlings grown under red light were irradiated with ultraviolet-containing white light, anthocyanin synthesis was induced in the hypocotyl tissues, especially when a UV light supplement was added. The accumulation of pigments was closely associated with the expression of genes involved in flavonoid synthesis. These genes include chalcone synthase (CHS) and dihydroflavonol 4-reductase (DFR). Using subtracted probes, which had been enriched for the accumulated mRNA, one white light-responsive cDNA was identified as being a P450 gene by comparison with database sequences. The maximal amino acid homology this cDNA had with other P450s was 36%. This was with CYP71 from avocado (Persea americana). Thus it represents a new P-450 family, which has been named CYP75. The mRNA of this gene was localized in the hypocotyl tissues of eggplant seedlings, which had been white light-irradiated. The transcript was accumulated by changing the light source, as in the case of other flavonoid biosynthesis genes. In delphinidin producing petunia plants, the mRNAs corresponding to the eggplant P-450 and flavonoid biosynthesis genes such as CHS and DFR were most abundant during the mid stage of flower bud development, but could not be detected in leaf tissues. These results suggest that this P-450 gene encodes a hydroxylating enzyme involved in flavonoid biosynthesis. (author)

Optical efficiency enhancement in white organic light-emitting diode display with high color gamut using patterned quantum dot film and long pass filter

Science.gov (United States)

Kim, Hyo-Jun; Shin, Min-Ho; Kim, Young-Joo

2016-08-01

A new structure for white organic light-emitting diode (OLED) displays with a patterned quantum dot (QD) film and a long pass filter (LPF) was proposed and evaluated to realize both a high color gamut and high optical efficiency. Since optical efficiency is a critical parameter in white OLED displays with a high color gamut, a red or green QD film as a color-converting component and an LPF as a light-recycling component are introduced to be adjusted via the characteristics of a color filter (CF). Compared with a conventional white OLED without both a QD film and the LPF, it was confirmed experimentally that the optical powers of red and green light in a new white OLED display were increased by 54.1 and 24.7% using a 30 wt % red QD film and a 20 wt % green QD film with the LPF, respectively. In addition, the white OLED with both a QD film and the LPF resulted in an increase in the color gamut from 98 to 107% (NTSC x,y ratio) due to the narrow emission linewidth of the QDs.

Influence of white light illumination on the performance of a-IGZO thin film transistor under positive gate-bias stress

Science.gov (United States)

Tang, Lan-Feng; Yu, Guang; Lu, Hai; Wu, Chen-Fei; Qian, Hui-Min; Zhou, Dong; Zhang, Rong; Zheng, You-Dou; Huang, Xiao-Ming

2015-08-01

The influence of white light illumination on the stability of an amorphous InGaZnO thin film transistor is investigated in this work. Under prolonged positive gate bias stress, the device illuminated by white light exhibits smaller positive threshold voltage shift than the device stressed under dark. There are simultaneous degradations of field-effect mobility for both stressed devices, which follows a similar trend to that of the threshold voltage shift. The reduced threshold voltage shift under illumination is explained by a competition between bias-induced interface carrier trapping effect and photon-induced carrier detrapping effect. It is further found that white light illumination could even excite and release trapped carriers originally exiting at the device interface before positive gate bias stress, so that the threshold voltage could recover to an even lower value than that in an equilibrium state. The effect of photo-excitation of oxygen vacancies within the a-IGZO film is also discussed. Project supported by the State Key Program for Basic Research of China (Grant Nos. 2011CB301900 and 2011CB922100) and the Priority Academic Program Development of Jiangsu Higher Education Institutions, China.

Combination of highly nonlinear fiber, an optical bandpass filter, and a Fabry-Perot filter to improve the signal-to-noise ratio of a supercontinuum continuous-wave optical source.

Science.gov (United States)

Nan, Yinbo; Huo, Li; Lou, Caiyun

2005-05-20

We present a theoretical study of a supercontinuum (SC) continuous-wave (cw) optical source generation in highly nonlinear fiber and its noise properties through numerical simulations based on the nonlinear Schrödinger equation. Fluctuations of pump pulses generate substructures between the longitudinal modes that result in the generation of white noise and then in degradation of coherence and in a decrease of the modulation depths and the signal-to-noise ratio (SNR). A scheme for improvement of the SNR of a multiwavelength cw optical source based on a SC by use of the combination of a highly nonlinear fiber (HNLF), an optical bandpass filter, and a Fabry-Perot (FP) filter is presented. Numerical simulations show that the improvement in modulation depth is relative to the HNLF's length, the 3-dB bandwidth of the optical bandpass filter, and the reflection ratio of the FP filter and that the average improvement in modulation depth is 13.7 dB under specified conditions.

Versatile silicon-waveguide supercontinuum for coherent mid-infrared spectroscopy

Science.gov (United States)

Nader, Nima; Maser, Daniel L.; Cruz, Flavio C.; Kowligy, Abijith; Timmers, Henry; Chiles, Jeff; Fredrick, Connor; Westly, Daron A.; Nam, Sae Woo; Mirin, Richard P.; Shainline, Jeffrey M.; Diddams, Scott

2018-03-01

Laser frequency combs, with their unique combination of precisely defined spectral lines and broad bandwidth, are a powerful tool for basic and applied spectroscopy. Here, we report offset-free, mid-infrared frequency combs and dual-comb spectroscopy through supercontinuum generation in silicon-on-sapphire waveguides. We leverage robust fabrication and geometrical dispersion engineering of nanophotonic waveguides for multi-band, coherent frequency combs spanning 70 THz in the mid-infrared (2.5 μm-6.2 μm). Precise waveguide fabrication provides significant spectral broadening with engineered spectra targeted at specific mid-infrared bands. We characterize the relative-intensity-noise of different bands and show that the measured levels do not pose any limitation for spectroscopy applications. Additionally, we use the fabricated photonic devices to demonstrate dual-comb spectroscopy of a carbonyl sulfide gas sample at 5 μm. This work forms the technological basis for applications such as point sensors for fundamental spectroscopy, atmospheric chemistry, trace and hazardous gas detection, and biological microscopy.

Hole-Size Increasing PCFs for Blue-Extended Supercontinuum Generation

DEFF Research Database (Denmark)

Sørensen, Simon Toft; Larsen, Casper; Jakobsen, C.

2013-01-01

into the deep-blue in a single mode PCF with varying hole-size and pitch fabricated directly at the draw-tower. The PCFs in this work are fabricated by increasing the pressure on the air holes during the drawing. However, this process alone will lead to an undesirable structure where both the relative hole......Supercontinuum (SC) sources with spectra extending into the deep-blue region below 400 nm are highly desirable in areas such as fluorescent microscopy [1]. Tapering of photonic crystal fibers (PCFs) with high air-fill fractions has proven an effective way of extending the spectra into the deep...... wavelength spectral edge to wavelengths in the deep-blue or even UV. Previous reports on blue-extended SC generation were typically achieved in tapered PCFs where the air-hole structure was preserved [1-4], i.e. the relative hole-size constant. However, such PCFs with high air-fill fractions are inevitably...

Versatile silicon-waveguide supercontinuum for coherent mid-infrared spectroscopy

Directory of Open Access Journals (Sweden)

Nima Nader

2018-03-01

Full Text Available Laser frequency combs, with their unique combination of precisely defined spectral lines and broad bandwidth, are a powerful tool for basic and applied spectroscopy. Here, we report offset-free, mid-infrared frequency combs and dual-comb spectroscopy through supercontinuum generation in silicon-on-sapphire waveguides. We leverage robust fabrication and geometrical dispersion engineering of nanophotonic waveguides for multi-band, coherent frequency combs spanning 70 THz in the mid-infrared (2.5 μm–6.2 μm. Precise waveguide fabrication provides significant spectral broadening with engineered spectra targeted at specific mid-infrared bands. We characterize the relative-intensity-noise of different bands and show that the measured levels do not pose any limitation for spectroscopy applications. Additionally, we use the fabricated photonic devices to demonstrate dual-comb spectroscopy of a carbonyl sulfide gas sample at 5 μm. This work forms the technological basis for applications such as point sensors for fundamental spectroscopy, atmospheric chemistry, trace and hazardous gas detection, and biological microscopy.

White light emission and effect of annealing on the Ho{sup 3+}–Yb{sup 3+} codoped BaCa{sub 2}Al{sub 8}O{sub 15} phosphor

Energy Technology Data Exchange (ETDEWEB)

Kumari, Astha; Rai, Vineet Kumar, E-mail: vineetkrrai@yahoo.co.in

2015-12-15

Graphical abstract: The upconversion emission spectra of the Ho{sup 3+}/Yb{sup 3+} doped/codoped BaCa{sub 2}Al{sub 8}O{sub 15} phosphors with different doping concentrations of Ho{sup 3+}/Yb{sup 3+} ions along with UC emission spectrum of the white light emitting phosphor annealed at 800 °C. - Highlights: • BaCa{sub 2}Al{sub 8}O{sub 15} phosphors codoped with Ho{sup 3+}–Yb{sup 3+} have been prepared by combustion method. • Phosphor annealed at 800 °C, illuminate an intense white light upon NIR excitation. • The sample annealed at higher temperatures emits in the pure green region. • The colour emitted persists in the white region even at high pump power density. • Developed phosphor is suitable for making upconverters and WLEDs. - Abstract: The BaCa{sub 2}Al{sub 8}O{sub 15} (BCAO) phosphors codoped with suitable Ho{sup 3+}–Yb{sup 3+} dopant concentration prepared by combustion method illuminate an intense white light upon near infrared diode laser excitation. The structural analysis of the phosphors and the detection of impurity contents have been performed by using the X-Ray Diffraction, FESEM and FTIR analysis. The purity of white light emitted from the sample has been confirmed by the CIE chromaticity diagram. Also, the white light emitted from the sample persists with the variation of pump power density. The phosphors emit upconversion (UC) emission bands in the blue, green and red region (three primary colours required for white light emission) along with one more band in the near infrared region of the electromagnetic spectrum. On annealing the white light emitting sample at higher temperatures, the sample starts to emit green colour and also the intensity of green and red UC emission bands get enhanced largely.

Enhancement of white-light-emission from single-phase Sr5(PO4)3F:Eu(2+),Mn(2+) phosphors for near-UV white LEDs.

Science.gov (United States)

Feng, Yaomiao; Huang, Jinping; Liu, Lili; Liu, Jie; Yu, Xibin

2015-09-07

A series of single-phase broadband white-light-emitting Sr5(PO4)3F:Eu(2+),Mn(2+) phosphors were prepared by a solid state reaction. The luminescence property, and the crystal and electronic structures of the fluorophosphates were studied by photoluminescence analysis, XRD Rietveld refinement and density functional theory calculation (DFT), respectively. Under near ultraviolet excitation in the 250 to 430 nm wavelength range, the phosphors exhibit two emission bands centered at 440 and 556 nm, caused by the Eu(2+) and Mn(2+) ions. By altering the relative ratios of Eu(2+) and Mn(2+) in the compounds, the emission color could be modulated from blue to white. The efficient energy transfer from the Eu(2+) to Mn(2+) ions could be ascribed to the well crystallized host lattice and the facile substitution of Eu(2+) and Mn(2+) for Sr(2+) sites due to similar ionic radii. A series of fluxes were investigated to improve the photoluminescence intensity. When KCl was used as flux in the synthesis, the photoluminescence intensity of Sr5(PO4)3F:Eu(2+),Mn(2+) was enhanced by 85% compared with no fluxes added. These results demonstrate that the single-phase Sr5(PO4)3F:Eu(2+),Mn(2+) with enhanced luminescence efficiency could be promising as a near UV-convertible direct white-light-emitting phosphor for WLED applications.

Prevention of the appearance of light-struck taste in white wine / Prevenzione della comparsa del gusto di luce nel vino bianco

Directory of Open Access Journals (Sweden)

Fracassetti Daniela

2016-01-01

Full Text Available The light-struck taste is a defect of bottled white wine due to the light exposure and involving the riboflavin (RF, as a photosensitizer, and methionine. The reaction pathways lead to the formation of volatile sulfur compounds, methanethiol and dimethyldisulphide, conferring cabbage-like aromas. The development of this defect is limited at low RF concentrations. In this study, the yeast-mediated release of RF, RF degradation kinetics in model solution and white wine, and RF removal by using insoluble adjuvants were investigated. The results showed the RF release was a strain-dependent property and the fermentation rate did not affect the RF synthesis. The RF degradation followed a 1st order kinetic in both model solution and white wine in which the degradation rate was halved. Among the adjuvants tested, bentonite and active charcoal were the most effective in RF removal and higher concentrations were needed for effectively treating white wine. The selection of low RF-producing yeasts and the treatment with active charcoal could represent useful tools to avoid the white wine spoilage during the shelf-life.

Broadband sensitized white light emission of g-C_3N_4/Y_2MoO_6:Eu"3"+ composite phosphor under near ultraviolet excitation

International Nuclear Information System (INIS)

Han, Bing; Xue, Yongfei; Li, Pengju; Zhang, Jingtao; Zhang, Jie; Shi, Hengzhen

2015-01-01

The g-C_3N_4/Y_2MoO_6:Eu"3"+ composite phosphors were synthesized and characterized by X-ray diffraction, Fourier transform-infrared spectroscopy, ultraviolet visible diffuse reflection spectra, photoluminescence spectra and luminescence decay curves. Under the excitation of 360 nm near ultraviolet light, these composite phosphors show tunable emission from blue to red region, in which white light emission can be obtained in term of appropriate quality proportion of Y_2MoO_6:Eu"3"+ relative to g-C_3N_4/Y_2MoO_6:Eu"3"+. In addition, the emission color can be also dependent on the excitation wavelength in g-C_3N_4/Y_2MoO_6:Eu"3"+ composite phosphor. - Graphical abstract: Under the excitation of 360 nm near ultraviolet light, the g-C_3N_4/Y_2MoO_6:Eu"3"+ composite phosphors show tunable emission from blue to red region, in which white light emission can be obtained. - Highlights: • The g-C3N4/Y2MoO6:Eu"3"+ composite phosphors were synthesized and characterized. • White light emission was realized in the g-C3N4/Y2MoO6:Eu"3"+ composites under UV excitation. • A novel idea to realize the broadband sensitized white light emission in phosphors was provided.

Progress in characterizing the multidimensional color quality properties of white LED light sources

Science.gov (United States)

Teunissen, Kees; Hoelen, Christoph

2016-03-01

With the introduction of solid state light sources, the variety in emission spectra is almost unlimited. However, the set of standardized parameters to characterize a white LED light source, such as correlated color temperature (CCT) and CIE general color rendering index (Ra), is known to be limited and insufficient for describing perceived differences between light sources. Several characterization methods have been proposed over the past decades, but their contribution to perceived color quality has not always been validated. To gain more insight in the relevant characteristics of the emission spectra for specific applications, we have conducted a perception experiment to rate the attractiveness of three sets of objects, including fresh food, packaging materials and skin tones. The objects were illuminated with seven different combinations of Red, Green, Blue, Amber and White LEDs, all with the same CCT and illumination level, but with differences in Ra and color saturation. The results show that, in general, object attractiveness does not correlate well with Ra, but shows a positive correlation with saturation increase for two out of three applications. There is no clear relation between saturation and skin tone attractiveness, partly due to differences in preference between males and females. A relative gamut area index (Ga) represents the average change in saturation and a complementary color vector graphic shows the direction and magnitude of chromatic differences for the eight CIE-1974 test-color samples. Together with the CIE general color rendering index (Ra) they provide useful information for designing and optimizing application specific emission spectra.

Fabrication of a white-light-emitting organic LED adopting the two-wavelength method by using new DPVBi derivatives and an analysis of its characteristics

International Nuclear Information System (INIS)

Oh, Hwan-Sool; Cho, Jae-Young; Yoon, Seok-Beom; Kang, Myung-Koo

2004-01-01

The white-light emission of the two-wavelength method was represented by the processes of compounding new DPVBi derivatives, methyl-DPVT and nitro-DPVT, from the blue-emitting material DPVBi, after which blue light was emitted from nitro-DPVT and orange light was emitted by doping methyl-DPVT as a host material with Rubrene as a guest material. The basic structure of the fabricated organic white-light-emitting organic light-emitting device (OLED) was glass/ITO/NPB(150 A)/nitro-DPVT(100 A)/methyl-DPVT:Rubrene [2.0 wt%]/BCP(70 A)/Alq 3 (150 A)/Al(600 A).We evaluated the characteristics by varying the thickness of the methyl-DPVT:Rubrene layer from 100 A to 90 A to 80 A to 60 A and obtained nearly-pure white light in the Commission Internationale de l'Eclairage (CIE) coordinates (0.3175, 0.3338) in the case where the methyl-DPVT:Rubrene layer was 60-A thick. It turned out that the device remained stable against voltage changes, the turn-on voltage was 3.5 V, the light-emitting turn-on voltage was 4 V, and the external quantum efficiency was more than 0.5 % for all injection currents.

Clean Cities Strategic Planning White Paper: Light Duty Vehicle Fuel Economy

Energy Technology Data Exchange (ETDEWEB)

Saulsbury, Bo [Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States); Hopson, Dr Janet L [Univ. of Tennessee, Knoxville, TN (United States); Greene, David [Univ. of Tennessee, Knoxville, TN (United States); Gibson, Robert [Univ. of Tennessee, Knoxville, TN (United States)

2015-04-01

Increasing the energy efficiency of motor vehicles is critical to achieving national energy goals of reduced petroleum dependence, protecting the global climate, and promoting continued economic prosperity. Even with fuel economy and greenhouse gas emissions standards and various economic incentives for clean and efficient vehicles, providing reliable and accurate fuel economy information to the public is important to achieving these goals. This white paper reviews the current status of light-duty vehicle fuel economy in the United States and the role of the Department of Energy (DOE) Clean Cities Program in disseminating fuel economy information to the public.

InP/ZnS nanocrystals for colour conversion in white light emitting diodes

DEFF Research Database (Denmark)

Shirazi, Roza

In this work a comprehensive study of a colloidal InP/ZnS nanocrystals (NC) as the colour conversion material for white light emitting diodes (WLED) is shown. Studied nanocrystals were synthesised by wet chemistry using one pot, hot injection method. A quantum efficiency (QE) of photoluminescence......, radiative and non-radiative recombination rates were determined and QE of 63% for the population of NCs that emit light was derived. A search for source of exciton losses in bright nanocrystals temperature resolved TRPL was studied and it revealed carrier trapping most likely at core-shell interface as well...... as at the surface and which competes with bright and dark exciton states. A presence of long-lived dark excitons and trapped charges lead to strong Auger recombination at high (relative to the trapping times) excitation. A colour conversion efficiency of the nanocrystals upon light absorption and in a process...

Blue-Light Therapy following Mild Traumatic Brain Injury: Effects on White Matter Water Diffusion in the Brain

Directory of Open Access Journals (Sweden)

Sahil Bajaj

2017-11-01

Full Text Available Mild traumatic brain injury (mTBI is a common and often inconspicuous wound that is frequently associated with chronic low-grade symptoms and cognitive dysfunction. Previous evidence suggests that daily blue wavelength light therapy may be effective at reducing fatigue and improving sleep in patients recovering from mTBI. However, the effects of light therapy on recovering brain structure remain unexplored. In this study, we analyzed white matter diffusion properties, including generalized fractional anisotropy, and the quantity of water diffusion in isotropic (i.e., isotropic diffusion and anisotropic fashion (i.e., quantitative anisotropy, QA for fibers crossing 11 brain areas known to be significantly affected following mTBI. Specifically, we investigated how 6 weeks of daily morning blue light exposure therapy (compared to an amber-light placebo condition impacted changes in white matter diffusion in individuals with mTBI. We observed a significant impact of the blue light treatment (relative to the placebo on the amount of water diffusion (QA for multiple brain areas, including the corpus callosum, anterior corona radiata, and thalamus. Moreover, many of these changes were associated with improvements in sleep latency and delayed memory. These findings suggest that blue wavelength light exposure may serve as one of the potential non-pharmacological treatments for facilitating structural and functional recovery following mTBI; they also support the use of QA as a reliable neuro-biomarker for mTBI therapies.

Al/WO{sub 3}/Au as the interconnecting layer for efficient tandem white organic light-emitting diodes

Energy Technology Data Exchange (ETDEWEB)

Zhang Hongmei; Dai Yanfeng; Ma Dongge [State Key Laboratory of Polymer Physics and Chemistry, Changchun Institute of Applied Chemistry, Chinese Academy of Sciences, Graduate School of Chinese Academy of Sciences, Changchun 130022 (China)], E-mail: mdg1014@ciac.jl.cn

2008-05-21

White light emission from tandem organic light-emitting diodes consisting of blue and red light units separated by a transparent interconnecting layer of Al/WO{sub 3}/Au has been realized. The devices have a structure of indium-tin-oxide (ITO)/molybdenum oxide (MoO{sub 3}) (8 nm)/N, N'-di(naphthalene-1-yl)-N, N'-diphenyl-benzidine (NPB)(100 nm)/p-bis(p-N,N-diphenyl-aminostyryl)benzene) (DSA-ph):2-methyl-9,10-di(2-naphthyl) anthracene (MADN)(40 nm)/tris(8-hydroxylquinoline) aluminium (Alq{sub 3}) (10 nm)/LiF(1 nm)/Al(2 nm)/WO{sub 3}(3 nm)/Au(16 nm)/MoO{sub 3}(5 nm)/NPB(60 nm)/Alq{sub 3}: 4-(dicyanomethylene)-2-t-butyl-6-(1,1,7,7- tetramethyljulolidyl-9-enyl)-4H-pyran (DCJTB)(30 nm)/Alq{sub 3}(30 nm)/LiF(1 nm)/Al(150 nm). It can be seen that a stable white light emission, including 461 and 491 nm peaks from DSA-ph and 620 nm peak from DCJTB, with Commission International De L'Eclairage chromaticity coordinates from (0.35, 0.33) at 8 V to (0.37, 0.30) at 12 V was obtained. The current efficiency and brightness of the white devices are basically equal to the sum of the blue unit and red unit devices. The maximum brightness reached 20 700 cd m{sup -2} at a bias of 23 V, and the maximum current efficiency was 9.1 cd A{sup -1} at a current density of 0.41 mA cm{sup -2}. (fast track communication)

White organic light emitting diodes

Energy Technology Data Exchange (ETDEWEB)

Rosenow, Thomas Conrad

2011-03-22

Three approaches were taken in order to achieve reproducible and highly efficient white OLEDs with excellent colour quality. The first approach is based on the triplet harvesting concept. Otherwise unused triplet excitons are transferred from a fluorescent to a phosphorescent emitter with a smaller triplet energy. Because a blue emitter allowing for triplet transfer to a phosphorescent green emitter was not available, a model system for a three-colour white OLED was developed and investigated. This model device consists of the fluorescent blue emitter 4P-NPD and the phosphorescent emitters Ir(dhfpy){sub 2}acac and Ir(MDQ){sub 2}acac emitting in the yellow and red region, respectively. Here, it was shown that both phosphorescent emitters are excited by triplet diffusion and not by direct charge carrier recombination. The second approach is based on a hybrid white OLED with a single emission layer. This layer is a combination of a fluorescent blue and two phosphorescent emitters in a common matrix material. Because of the above mentioned lack of a blue emitter, which allows for triplet transfer to a green phosphorescent emitter, the concentrations of all emitters were chosen in a way that exciton transfer between the emitters was suppressed. The result is a non-radiative recombination of triplet excitons on the fluorescent blue emitter and an accordingly low quantum efficiency. However, a remarkable colour stability against varying brightness was achieved with this OLED. The most successful approach is based on a stacked OLED. Here, the concept of triplet harvesting is limited to triplet transfer between a fluorescent blue and a phosphorescent red emitter. The resulting spectral gap is filled by a full phosphorescent unit comprising the emission of a green and a yellow emitter, which is stacked on top of the triplet harvesting OLED. By individually optimising both units, it was possible to reach lighting relevant luminous efficacies up to {eta}{sub {nu}}=33 lm/W at

Radio and white-light observations of coronal transients

Science.gov (United States)

Dulk, G. A.

1980-01-01

Optical, radio and X-ray evidence of violent mass motions in the corona has existed for some years but only recently have the form, nature, frequency and implication of the transients become obvious. In this paper the observed properties of coronal transients are reviewed, with concentration on the white-light and radio manifestations. The classification according to speeds seems to be meaningful, with the slow transients having thermal emissions at radio wavelengths and the fast ones nonthermal. The possible mechanisms involved in the radio bursts are then discussed and estimates of various forms of energy are reviewed. It appears that the magnetic energy transported from the sun by the transient exceeds that of any other form, and that magnetic forces dominate in the dynamics of the motions. The conversion of magnetic energy into mechanical energy, by expansion of the field, provides a possible driving force for the coronal and interplanetary shock waves.

Ultrabroad linewidth orange-emitting nanowires LED for high CRI laser-based white lighting and gigahertz communications

KAUST Repository

Janjua, Bilal; Ng, Tien Khee; Zhao, Chao; Oubei, Hassan M.; Shen, Chao; Prabaswara, Aditya; Alias, Mohd Sharizal; Alhamoud, Abdullah Ali; Alatawi, Abdullah Awaad; Albadri, Abdulrahman M.; Alyamani, Ahmed Y.; El-Desouki, Munir M.; Ooi, Boon S.

2016-01-01

intensity- and bandwidth-tunable for high color-quality remained unexplored. In this paper, we present for the first time, the proof-of-concept of the generation of high-quality white light using an InGaN-based orange nanowires (NWs) LED grown on silicon

Fabrication of white light-emitting diodes based on UV light-emitting diodes with conjugated polymers-(CdSe/ZnS) quantum dots as hybrid phosphors.

Science.gov (United States)

Jung, Hyunchul; Chung, Wonkeun; Lee, Chang Hun; Kim, Sung Hyun

2012-07-01

White light-emitting diodes (LEDs) were fabricated using GaN-based 380-nm UV LEDs precoated with the composite of blue-emitting polymer (poly[(9,9-dihexylfluorenyl-2,7-diyl)-alt-co-(2-methoxy-5-{2-ethylhexyloxy)-1 ,4-phenylene)]), yellow green-emitting polymer (poly[(9,9-dioctylfluorenyl-2,7-diyl)-co-(1,4-benzo-{2,1',3}-thiadiazole)]), and 605-nm red-emitting quantum dots (QDs). CdSe cores were obtained by solvothermal route using CdO, Se precursors and ZnS shells were synthesized by using diethylzinc, and hexamethyldisilathiane precursors. The optical properties of CdSe/ZnS QDs were characterized by UV-visible and photoluminescence (PL) spectra. The structural data and composition of the QDs were transmission electron microscopy (TEM), and EDX technique. The quantum yield and size of the QDs were 58.7% and about 6.7 nm, respectively. Three-band white light was generated by hybridizing blue (430 nm), green (535 nm), and red (605 nm) emission. The color-rendering index (CRI) of the device was extremely improved by introducing the QDs. The CIE-1931 chromaticity coordinate, color temperature, and CRI of a white LED at 20 mA were (0.379, 0.368), 3969 K, and 90, respectively.

Morning sleep inertia in alertness and performance: effect of cognitive domain and white light conditions.

Directory of Open Access Journals (Sweden)

Nayantara Santhi

Full Text Available The transition from sleep to wakefulness entails a temporary period of reduced alertness and impaired performance known as sleep inertia. The extent to which its severity varies with task and cognitive processes remains unclear. We examined sleep inertia in alertness, attention, working memory and cognitive throughput with the Karolinska Sleepiness Scale (KSS, the Psychomotor Vigilance Task (PVT, n-back and add tasks, respectively. The tasks were administered 2 hours before bedtime and at regular intervals for four hours, starting immediately after awakening in the morning, in eleven participants, in a four-way cross-over laboratory design. We also investigated whether exposure to Blue-Enhanced or Bright Blue-Enhanced white light would reduce sleep inertia. Alertness and all cognitive processes were impaired immediately upon awakening (p<0.01. However, alertness and sustained attention were more affected than cognitive throughput and working memory. Moreover, speed was more affected than accuracy of responses. The light conditions had no differential effect on performance except in the 3-back task (p<0.01, where response times (RT at the end of four hours in the two Blue-Enhanced white light conditions were faster (200 ms than at wake time. We conclude that the effect of sleep inertia varies with cognitive domain and that it's spectral/intensity response to light is different from that of sleepiness. That is, just increasing blue-wavelength in light may not be sufficient to reduce sleep inertia. These findings have implications for critical professions like medicine, law-enforcement etc., in which, personnel routinely wake up from night-time sleep to respond to emergency situations.

White-light full-field OCT resolution improvement by image sensor colour balance adjustment: numerical simulation

International Nuclear Information System (INIS)

Kalyanov, A L; Lychagov, V V; Ryabukho, V P; Smirnov, I V

2012-01-01

The possibility of improving white-light full-field optical coherence tomography (OCT) resolution by image sensor colour balance tuning is shown numerically. We calculated the full-width at half-maximum (FWHM) of a coherence pulse registered by a silicon colour image sensor under various colour balance settings. The calculations were made for both a halogen lamp and white LED sources. The results show that the interference pulse width can be reduced by the proper choice of colour balance coefficients. The reduction is up to 18%, as compared with a colour image sensor with regular settings, and up to 20%, as compared with a monochrome sensor. (paper)

Effect of Annealing Time of YAG:Ce3+ Phosphor on White Light Chromaticity Values

Science.gov (United States)

Abd, Husnen R.; Hassan, Z.; Ahmed, Naser M.; Almessiere, Munirah Abdullah; Omar, A. F.; Alsultany, Forat H.; Sabah, Fayroz A.; Osman, Ummu Shuhada

2018-02-01

Yttrium and aluminium nitrate phosphors doped with cerium nitrate and mixed with urea (fuel) are prepared by using microwave-induced combustion synthesis according to the formula Y(3-0.06)Al5O12:0.06Ce3+ (YAG:Ce3+) to produce white light emitting diodes by conversion from blue indium gallium nitride-light emitting diode chips. The sintering time with fixed temperature (1050°C) for phosphor powder was optimized and found to be 5 h. The crystallinity, structure, chemical composition, luminescent properties with varying currents densities and chromaticity were characterized by x-ray diffraction, field emission-scanning electron microscopy, transmission electron microscopy, energy dispersive spectroscopy, photoluminescence emission, electroluminescence and standard CIE 1931 chromaticity diagram, respectively. The energy levels of Ce3+ in YAG were discussed based on its absorption and excitation spectra. The results show that the obtained YAG:Ce3+ phosphor sintered for 5 h has good crystallinity with pure phase, low agglomerate with spherical shaped particles and strong yellow emission, offering cool-white LED with tuneable correlated color temperature and a good color rendering index compared to those prepared by sintering for 2 h and as-prepared phosphor powders.

Wideband perfect coherent absorber based on white-light cavity

Science.gov (United States)

Kotlicki, Omer; Scheuer, Jacob

2015-03-01

Coherent Perfect Absorbers (CPAs) are optical cavities which can be described as time-reversed lasers where light waves that enter the cavity, coherently interfere and react with the intra-cavity losses to yield perfect absorption. In contrast to lasers, which benefit from high coherency and narrow spectral linewidths, for absorbers these properties are often undesirable as absorption at a single frequency is highly susceptible to spectral noise and inappropriate for most practical applications. Recently, a new class of cavities, characterized by a spectrally wide resonance has been proposed. Such resonators, often referred to as White Light Cavities (WLCs), include an intra-cavity superluminal phase element, designed to provide a phase response with a slope that is opposite in sign and equal in magnitude to that of light propagation through the empty cavity. Consequently, the resonance phase condition in WLCs is satisfied over a band of frequencies providing a spectrally wide resonance. WLCs have drawn much attention due to their attractiveness for various applications such as ultra-sensitive sensors and optical buffering components. Nevertheless, WLCs exhibit inherent losses that are often undesirable. Here we introduce a simple wideband CPA device that is based on the WLC concept along with a complete analytical analysis. We present analytical and FDTD simulations of a practical, highly compact (12µm), Silicon based WLC-CPA that exhibits a flat and wide absorption profile (40nm) and demonstrate its usefulness as an optical pulse terminator (>35db isolation) and an all optical modulator that span the entire C-Band and exhibit high immunity to spectral noise.

Highly efficient and stable white organic light emitting diode base on double recombination zones of phosphorescent blue/orange emitters.

Science.gov (United States)

Lee, Seok Jae; Koo, Ja Ryong; Lim, Dong Hwan; Park, Hye Rim; Kim, Young Kwan; Ha, Yunkyoung

2011-08-01

We demonstrated efficient and stable white phosphorescent organic light-emitting diodes (OLEDs) with double-emitting layers (D-EMLs), which were comprised of two emissive layers with a hole transport-type host of N,N'-dicarbazolyl-3,5-benzene (mCP) and a electron transport-type host of 2,2',2"-(1,3,5-benzenetryl)tris(1-phenyl)-1H-benzimidazol (TPBi) with blue/orange emitters, respectively. We fabricated two type white devices with single emitting layer (S-EML) and D-EML of orange emitter, maintaining double recombination zone of blue emitter. In addition, the device architecture was developed to confine excitons inside the D-EMLs and to manage triplet excitons by controlling the charge injection. As a result, light-emitting performances of white OLED with D-EMLs were improved and showed the steady CIE coordinates compared to that with S-EML of orange emitter, which demonstrated the maximum luminous efficiency and external quantum efficiency were 21.38 cd/A and 11.09%. It also showed the stable white emission with CIE(x,y) coordinates from (x = 0.36, y = 0.37) at 6 V to (x = 0.33, y = 0.38) at 12 V.

Simultaneous multi-wavelength ultraviolet excited single-phase white light emitting phosphor Ba1-x(Zr,Ti)Si3O9:xEu

Science.gov (United States)

Zhou, Zhenzhen; Liu, Guanghui; Ni, Jia; Liu, Wanlu; Liu, Qian

2018-05-01

A kind of novel compound Ba1-x(Zr,Ti)Si3O9:xEu simultaneously activated by different-valence Eu2+ and Eu3+ ions has been successfully synthesized. The existence of Ti4+-O2- charge transfer (CT) transitions in Ba1-xZrSi3O9:xEu is proved by the photoluminescence spectra and first principle calculations, and the Ti4+ ions come from the impurities in commercial ZrO2 raw materials. Under the excitation of multi-wavelength ultraviolet radiation (λEX = 392, 260, 180 nm), Ba1-xZrSi3O9:xEu (x = 0.15) can directly emit nearly white light. The coexistence of multiple luminescent centers and the energy transfer among Zr4+-O2- CT state, Ti4+-O2- CT state, Eu2+ and Eu3+ ions play important roles in the white light emission. Ba1-xZrSi3O9:xEu (x = 0.15) has good thermal stability, in particular, the intensity of emission spectrum (λEX = 392 nm) at 150 °C is ∼96% of that at room temperature. In general, the multi-wavelength ultraviolet-excited single-phase white light emitting phosphor Ba1-x(Zr,Ti)Si3O9:xEu possesses a promise for applications in white light emitting diodes (WLEDs), agriculture, medicine and other photonic fields.

Gain-switched all-fiber lasers and quasi-continuous wave supercontinuum generation

DEFF Research Database (Denmark)

Larsen, Casper

The extreme broadening phenomenon of supercontinuum (SC) generation in optical fibers is the basis of SC laser sources. These sources have numerous applications in areas, such as spectroscopy and microscopy due to the unique combination of extremely broad spectral bandwidths, high spectral power...... densities, and high spatial coherence. In this work the feasibility of applying gain-switched all-fiber lasers to SC generation is investigated. It is motivated by the simplicity of the architecture and the ability to scale the optical output power of such fiber lasers. The physics of fiber lasers......-switching of fiber lasers with a variety of different configurations are carried out. The peak power, pulse duration, bandwidth, and scaling with repetition rate are thoroughly described. General guidelines are submitted to enable designing of gainswitched fiber lasers with specifically tailored properties...

Non-doped white organic light-emitting diodes based on aggregation-induced emission

Energy Technology Data Exchange (ETDEWEB)

Chen Shuming; Kwok, Hoi Sing [Center for Display Research, Department of Electronic and Computer Engineering, Hong Kong University of Science and Technology, Clear Water Bay, Kowloon (Hong Kong); Zhao Zujin; Tang, Ben Zhong, E-mail: eekwok@ust.h [Department of Chemistry, Hong Kong University of Science and Technology, Clear Water Bay, Kowloon (Hong Kong)

2010-03-10

Non-doped white organic light-emitting diodes (WOLEDs) based on newly synthesized bluish-green light-emitting material 1,3,6,8-tetrakis [4-(1,2,2-triphenylvinyl)phenyl]pyrene (TTPEPy) and red light-emitting material 4-(4-(1,2,2-triphenylvinyl)phenyl)-7-(5-(4-(1,2,2-triphenylvinyl) phenyl)thiophen-2-yl)benzo[c][1,2,5]thiadiazole (BTPETTD) have been demonstrated. A maximum efficiency of 7.4 cd A{sup -1}, 4 lm W{sup -1} and brightness of 18 000 cd m{sup -2} have been achieved by employing 3 nm thick 4, 4'-bis [N-(1-naphthyl-1-)-N-phenyl-amino]- biphenyl (NPB) as an electron-blocking layer. The WOLEDs exhibit a high colour rendering index of 90 and moderate colour stability with 1931 Commision International de L'Eclairage coordinates changing from (0.41, 0.41) to (0.38, 0.40) over a wide range of driving voltages. Moreover, the non-doped WOLEDs enjoy a reduced efficiency roll-off due to their nature of aggregation-induced emission.

Non-doped white organic light-emitting diodes based on aggregation-induced emission

International Nuclear Information System (INIS)

Chen Shuming; Kwok, Hoi Sing; Zhao Zujin; Tang, Ben Zhong

2010-01-01

Non-doped white organic light-emitting diodes (WOLEDs) based on newly synthesized bluish-green light-emitting material 1,3,6,8-tetrakis [4-(1,2,2-triphenylvinyl)phenyl]pyrene (TTPEPy) and red light-emitting material 4-(4-(1,2,2-triphenylvinyl)phenyl)-7-(5-(4-(1,2,2-triphenylvinyl) phenyl)thiophen-2-yl)benzo[c][1,2,5]thiadiazole (BTPETTD) have been demonstrated. A maximum efficiency of 7.4 cd A -1 , 4 lm W -1 and brightness of 18 000 cd m -2 have been achieved by employing 3 nm thick 4, 4'-bis [N-(1-naphthyl-1-)-N-phenyl-amino]- biphenyl (NPB) as an electron-blocking layer. The WOLEDs exhibit a high colour rendering index of 90 and moderate colour stability with 1931 Commision International de L'Eclairage coordinates changing from (0.41, 0.41) to (0.38, 0.40) over a wide range of driving voltages. Moreover, the non-doped WOLEDs enjoy a reduced efficiency roll-off due to their nature of aggregation-induced emission.

Synthesis and up-conversion white light emission of RE{sup 3+}-doped lutetium oxide nanocubes as a single compound

Energy Technology Data Exchange (ETDEWEB)

Hu Shanshan [School of Chemistry and Chemical Engineering, Southwest University, Chongqing 400715 (China); Yang Jun, E-mail: jyang@swu.edu.cn [School of Chemistry and Chemical Engineering, Southwest University, Chongqing 400715 (China); Li Chunxia [State Key Laboratory of Rare Earth Resource Utilization, Changchun Institute of Applied Chemistry, Chinese Academy of Sciences, Changchun 130022 (China); Lin Jun, E-mail: jlin@ciac.jl.cn [State Key Laboratory of Rare Earth Resource Utilization, Changchun Institute of Applied Chemistry, Chinese Academy of Sciences, Changchun 130022 (China)

2012-04-16

Highlights: Black-Right-Pointing-Pointer Uniform and dispersive cubic precursor can be synthesized by sample hydrothermal process. Black-Right-Pointing-Pointer Hydrothermal precursor could transform to Lu{sub 2}O{sub 3}:RE{sup 3+} with its original cubic morphology. Black-Right-Pointing-Pointer Nearly equal intensities of blue, green, and red emissions under single 980 nm laser. Black-Right-Pointing-Pointer Lu{sub 2}O{sub 3}:RE{sup 3+} show bright white light emission, clearly visible to the naked eyes. Black-Right-Pointing-Pointer Chromaticity coordinate is very close to the standard equal energy white light illuminate. - Abstract: Uniform and dispersive Lu{sub 2}O{sub 3}:Yb{sup 3+}/Er{sup 3+}/Tm{sup 3+} nanocubes have been successfully synthesized by hydrothermal process with subsequent calcination at 900 Degree-Sign C. The as-formed RE{sup 3+}-doped lutetium oxide precursor via the hydrothermal process, as a template, could transform to RE{sup 3+}-doped Lu{sub 2}O{sub 3} with their original cubic morphology and slight shrinkage in the size after post-annealing process. The formation mechanism for the lutetium oxide precursor cubes has been proposed. Under single wavelength diode laser excitation of 980 nm, the as-obtained Lu{sub 2}O{sub 3}:3%Yb{sup 3+}/0.5%Er{sup 3+}/0.3%Tm{sup 3+} nanocubes show nearly equal intensities of blue (Tm{sup 3+}: {sup 1}G{sub 4} {yields} {sup 3}H{sub 6}), green (Er{sup 3+}: ({sup 2}H{sub 11/2}, {sup 4}S{sub 3/2}) {yields} {sup 4}I{sub 15/2}), and red (Er{sup 3+}: {sup 4}F{sub 9/2} {yields} {sup 4}I{sub 15/2}) emissions, which produces bright white light emission, clearly visible to the naked eyes. The main pathways to populate the upper emitting states come from the energy-transfer processes from Yb{sup 3+} to Tm{sup 3+}/Er{sup 3+}, respectively. The chromaticity coordinate of the Lu{sub 2}O{sub 3}:3%Yb{sup 3+}/0.5%Er{sup 3+}/0.3%Tm{sup 3+} sample is calculated to be about x = 0.3403 and y = 0.3169, which falls exactly within the

White emission from organic light-emitting diodes with a super-thin BCP layer

International Nuclear Information System (INIS)

Hao Jingang; Deng Zhenbo; Yang Shengyi

2007-01-01

We report a method to achieve white emission from organic light-emitting diodes (OLEDs) in which a super-thin (3 nm) hole blocking layer, 2,9-dimethyl-4,7-diphenyl-1,10-phenanthroline (BCP), was inserted between electron-transport layer 8-hydroxyquinoline aluminum (Alq 3 ) and 4-(dicyanomethylene)-2-t-butyl-6(1,1,7,7-tetramethyljulolidyl-9-enyl) -4H-pyran (DCJTB) doped poly-vinlycarbazole (PVK) layer. The BCP layer can not only confine exciton in the emitting layer but also control energy transfer proportion from PVK to Alq 3 and then from Alq 3 to DCJTB through BCP layer. In this way, pure white emission with CIE coordinate of (0.32, 0.32) was obtained and it was voltage independent. The brightness reached 270 cd/m 2 at 18 V with an efficiency of 0.166 cd/A

Effects of supplementary lighting by natural light for growth of Brassica chinensis

Science.gov (United States)

Yeh, Shih-Chuan; Lee, Hui-Ping; Kao, Shih-Tse; Lu, Ju-Lin

2016-04-01

This paper present a model of cultivated chamber with supplementary natural colour light. We investigate the effects of supplementary natural red light and natural blue light on growth of Brassica chinensis under natural white light illumination. After 4 weeks of supplementary colour light treatment, the experiment results shown that the weight of fresh leaf were not affected by supplementary natural blue light. However, those Brassica chinensis were cultivated in the chambers with supplementary natural red light obtained a significant increasing of fresh weight of leaf under both white light illuminate models. The combination of natural white light with supplementary natural red light illumination will be benefits in growth for cultivation and energy saving.

Studies of redox active silicalite-2 and the development of stable white-light phosphors

Science.gov (United States)

Lita, Adrian

Mn-silicalite-2 was synthesized at high pH using the molecular cluster, Mn12O12(O2CCH3)16 as a Mn Source. No precipitation of manganese hydroxide was observed with this cluster even with the use of tetrabutylammonium hydroxide as a templating agent. This synthetic approach resulted in the incorporation of up to 2.5 mol % Mn into the silicalite-2 with direct substitution into the framework verified by a linear relationship between unit cell volume and loading. The Mn is reduced to Mn(II) during hydrothermal synthesis and incorporated into the silicalite-2 framework during calcination at 500°C. Further calcination at 750°C does not affect the crystallinity but oxidizes essentially all of the Mn(II) to Mn(III). Cr(IV) substituted silicalite-2 was generated by reduction of Cr(VI)-silicalite-2 lattice sites at in a CO atmosphere. The reduction process, Reduction at high pressures was found to give almost complete conversion of the Cr(VI) sites to Cr(IV). As generated, the Cr(IV) sites do not reoxidize to Cr(VI) under ambient conditions or in the presence of oxidants under reaction conditions. We report the development of new class solid-state white-light phosphors based on stable nanoparticle-silica glass composites. These materials are made from the incorporating of CdSe nanoparticles into a silica Sol-gel solution. Once it gelled and aged the materials are calcined at 500°C under oxygen. The solid that results are robust with a bright white luminescence (20%) under UV excitation that gives virtually pure white light with coordinates of (0.34, 0.36) on the CIE 1931 chromaticity diagram and, more importantly, the emission envelope coincides nearly identically with the scotopic eye response function. The white-light phosphors have a scotopic/phtopic ratio of 2.56, indicating that these phosphors will be perceived as a particularly efficient illumination source in a dark environment thereby being more energy efficient. The emission comes from a distribution of

Transparent organic light-emitting diodes with balanced white emission by minimizing waveguide and surface plasmonic loss.

Science.gov (United States)

Zhang, Yi-Bo; Ou, Qing-Dong; Li, Yan-Qing; Chen, Jing-De; Zhao, Xin-Dong; Wei, Jian; Xie, Zhong-Zhi; Tang, Jian-Xin

2017-07-10

It is challenging in realizing high-performance transparent organic light-emitting diodes (OLEDs) with symmetrical light emission to both sides. Herein, an efficient transparent OLED with highly balanced white emission to both sides is demonstrated by integrating quasi-periodic nanostructures into the organic emitter and the metal-dielectric composite top electrode, which can simultaneously suppressing waveguide and surface plasmonic loss. The power efficiency and external quantum efficiency are raised to 83.5 lm W -1 and 38.8%, respectively, along with a bi-directional luminance ratio of 1.26. The proposed scheme provides a facile route for extending application scope of transparent OLEDs for future transparent displays and lightings.

White light emitting diode as potential replacement of tungsten-halogen lamp for visible spectroscopy system: a case study in the measurement of mango qualities

Science.gov (United States)

Chiong, W. L.; Omar, A. F.

2017-07-01

Non-destructive technique based on visible (VIS) spectroscopy using light emitting diode (LED) as lighting was used for evaluation of the internal quality of mango fruit. The objective of this study was to investigate feasibility of white LED as lighting in spectroscopic instrumentation to predict the acidity and soluble solids content of intact Sala Mango. The reflectance spectra of the mango samples were obtained and measured in the visible range (400-700 nm) using VIS spectroscopy illuminated under different white LEDs and tungsten-halogen lamp (pro lamp). Regression models were developed by multiple linear regression to establish the relationship between spectra and internal quality. Direct calibration transfer procedure was then applied between master and slave lighting to check on the acidity prediction results after transfer. Determination of mango acidity under white LED lighting was successfully performed through VIS spectroscopy using multiple linear regression but otherwise for soluble solids content. Satisfactory results were obtained for calibration transfer between LEDs with different correlated colour temperature indicated this technique was successfully used in spectroscopy measurement between two similar light sources in prediction of internal quality of mango.

White light emitting diode as potential replacement of tungsten-halogen lamp for visible spectroscopy system: a case study in the measurement of mango qualities

International Nuclear Information System (INIS)

Chiong, W.L.; Omar, A.F.

2017-01-01

Non-destructive technique based on visible (VIS) spectroscopy using light emitting diode (LED) as lighting was used for evaluation of the internal quality of mango fruit. The objective of this study was to investigate feasibility of white LED as lighting in spectroscopic instrumentation to predict the acidity and soluble solids content of intact Sala Mango. The reflectance spectra of the mango samples were obtained and measured in the visible range (400–700 nm) using VIS spectroscopy illuminated under different white LEDs and tungsten-halogen lamp (pro lamp). Regression models were developed by multiple linear regression to establish the relationship between spectra and internal quality. Direct calibration transfer procedure was then applied between master and slave lighting to check on the acidity prediction results after transfer. Determination of mango acidity under white LED lighting was successfully performed through VIS spectroscopy using multiple linear regression but otherwise for soluble solids content. Satisfactory results were obtained for calibration transfer between LEDs with different correlated colour temperature indicated this technique was successfully used in spectroscopy measurement between two similar light sources in prediction of internal quality of mango.

Enhanced efficiency in single-host white organic light-emitting diode by triplet exciton conversion

International Nuclear Information System (INIS)

Wu, Qingyang; Zhang, Shiming; Yue, Shouzhen; Zhang, Zhensong; Xie, Guohua; Zhao, Yi; Liu, Shiyong

2013-01-01

The authors observe that the external quantum efficiency (EQE) of the Iridium (III) bis(4-phenylthieno [3,2-c]pyridinato-N,C 2′ )acetylacetonate (PO-01) based yellow organic light-emitting diode (OLED) is significantly increased by uniformly co-doping Iridium (III)bis[(4,6-difluorophenyl)-pyridinato-N,C 2− ] (FIrpic) and PO-01 into the same wide band-gap host of N,N ′ -dicarbazolyl-3, 5-benzene (mCP). Detailed investigation indicates that the efficiency enhancement is ascribed to effective triplet exciton gathering by FIrpic, followed by energy transfer to PO-01. Compared to the control device, which has maximum EQE of 10.5%, an improved maximum EQE of 13.2% is obtained in the optimization white device based on FIrpic and PO-01 emission according to this principle. This work makes it easier for a single host white OLED to simultaneously harvest high efficiency in both blue and yellow units. Comprehensive experimental results show that this phenomenon can also be found and utilized in other popular hosts to realize more efficient white devices. -- Highlights: • This work makes easier for a single host white OLED to harvest high efficiency in both blue and yellow units. • Efficiency enhancement is ascribed to effective triplet exciton gathering by FIrpic, followed by energy transfer to PO-01. • This phenomenon can also be found and utilized in other popular hosts to realize more efficient white devices

Enhanced efficiency in single-host white organic light-emitting diode by triplet exciton conversion

Energy Technology Data Exchange (ETDEWEB)

Wu, Qingyang, E-mail: wqy1527@163.com [State Key laboratory on Integrated Optoelectronics, College of Electronic Science and Engineering, Jilin University, Changchun 130012 (China); Zhang, Shiming [State Key laboratory on Integrated Optoelectronics, College of Electronic Science and Engineering, Jilin University, Changchun 130012 (China); Département of Chemical Engineering, École Polytechnique de Montréal, Montréal, Québec, Canada H3C3J7 (Canada); Yue, Shouzhen; Zhang, Zhensong [State Key laboratory on Integrated Optoelectronics, College of Electronic Science and Engineering, Jilin University, Changchun 130012 (China); Xie, Guohua [Institut für Angewandte Photophysik, Technische Universtität Dresden, Dresden 01062 (Germany); Zhao, Yi; Liu, Shiyong [State Key laboratory on Integrated Optoelectronics, College of Electronic Science and Engineering, Jilin University, Changchun 130012 (China)

2013-11-15

The authors observe that the external quantum efficiency (EQE) of the Iridium (III) bis(4-phenylthieno [3,2-c]pyridinato-N,C{sup 2′})acetylacetonate (PO-01) based yellow organic light-emitting diode (OLED) is significantly increased by uniformly co-doping Iridium (III)bis[(4,6-difluorophenyl)-pyridinato-N,C{sup 2−}] (FIrpic) and PO-01 into the same wide band-gap host of N,N{sup ′}-dicarbazolyl-3, 5-benzene (mCP). Detailed investigation indicates that the efficiency enhancement is ascribed to effective triplet exciton gathering by FIrpic, followed by energy transfer to PO-01. Compared to the control device, which has maximum EQE of 10.5%, an improved maximum EQE of 13.2% is obtained in the optimization white device based on FIrpic and PO-01 emission according to this principle. This work makes it easier for a single host white OLED to simultaneously harvest high efficiency in both blue and yellow units. Comprehensive experimental results show that this phenomenon can also be found and utilized in other popular hosts to realize more efficient white devices. -- Highlights: • This work makes easier for a single host white OLED to harvest high efficiency in both blue and yellow units. • Efficiency enhancement is ascribed to effective triplet exciton gathering by FIrpic, followed by energy transfer to PO-01. • This phenomenon can also be found and utilized in other popular hosts to realize more efficient white devices.

Aligned energy-level design for decreasing operation voltage of tandem white organic light-emitting diodes

International Nuclear Information System (INIS)

Chang, Chih-Hao; Wu, Zih-Jyun; Liang, Yi-Hu; Chang, Yu-Shuo; Chiu, Chuan-Hao; Tai, Cheng-Wei; Chang, Hsin-Hua

2013-01-01

In general, organic light-emitting devices (OLEDs) need to operate at higher current density levels to ensure an ample light flux. However, stressed operation will result in poor performance and limited device lifetime. Recently, a tandem structure has been proposed as a pivotal technique to meet the stringent lighting requirements for OLED commercialization, with a research focus on decreasing the concomitant higher operation voltage. Driving two connected emission units (EMUs) in a tandem structure often requires more than twice the driving voltage for a single EMU. This study investigates bipolar host materials and their effective employment in fabricating tandem white phosphorescent OLEDs (PhOLEDs). In addition, the design of a mechanism to align the energy level between the hole transport layer/emitting layer is shown to effectively mitigate operational voltages. In sharp contrast to devices using a unipolar host material, we demonstrate that the turn-on voltage of blue PhOLEDs could be decreased from 3.8 V to 2.7 V through utilizing a bipolar host. Furthermore, applying the proposed techniques to tandem white PhOLEDs produces a luminance of 10 3 cd/m 2 by a 10.1 V driving voltage. - Highlights: • The matched energy level between the hole transport/emitting layer lowers voltages. • Multiple conduction dopants were used to investigate charge generation layer. • Two-color emitters were used to quantify the charge generation strength

Investigations of white light emitting europium doped zinc oxide nanoparticles

International Nuclear Information System (INIS)

Ashtaputre, S S; Nojima, A; Marathe, S K; Matsumura, D; Ohta, T; Tiwari, R; Dey, G K; Kulkarni, S K

2008-01-01

Europium doped zinc oxide nanoparticles have been synthesized using a chemical route. The amount of doped europium was varied which shows the changes in the photoluminescence (PL) intensity. The post synthesis annealing effect on the properties of ZnO nanoparticles has also been investigated. In general, PL is broad and a white light is emitted which originates from ZnO and the intra-4f transitions of Eu 3+ ions. The x-ray diffraction patterns do not show any Eu-related peaks for as-synthesized ZnO nanoparticles as well as for annealed samples. X-ray absorption spectroscopy reveals that europium ions are present on the surface of the core of ZnO and inside the shell of zinc hydroxide [Zn(OH 2 )] after annealing

White organic light-emitting diodes with 4 nm metal electrode

Science.gov (United States)

Lenk, Simone; Schwab, Tobias; Schubert, Sylvio; Müller-Meskamp, Lars; Leo, Karl; Gather, Malte C.; Reineke, Sebastian

2015-10-01

We investigate metal layers with a thickness of only a few nanometers as anode replacement for indium tin oxide (ITO) in white organic light-emitting diodes (OLEDs). The ultrathin metal electrodes prove to be an excellent alternative that can, with regard to the angular dependence and efficiency of the OLED devices, outperform the ITO reference. Furthermore, unlike ITO, the thin composite metal electrodes are readily compatible with demanding architectures (e.g., top-emission or transparent OLEDs, device unit stacking, etc.) and flexible substrates. Here, we compare the sheet resistance of both types of electrodes on polyethylene terephthalate for different bending radii. The electrical performance of ITO breaks down at a radius of 10 mm, while the metal electrode remains intact even at radii smaller than 1 mm.