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Sample records for superconducting y-ba-cu-o films

  1. Y-Ba-Cu-O superconducting film on oxidized silicon

    International Nuclear Information System (INIS)

    Gupta, R.P.; Khokle, W.S.; Dubey, R.C.; Singhal, S.; Nagpal, K.C.; Rao, G.S.T.; Jain, J.D.

    1988-01-01

    We report thick superconducting films of Y-Ba-Cu-O on oxidized silicon substrates. The critical temperatures for onset and zero resistance are 96 and 77 K, respectively. X-ray diffraction analysis predicts 1, 2, 3 composition and orthorhombic phase of the film

  2. Y-Ba-Cu-O superconducting thin films by simultaneous or sequential evaporation

    International Nuclear Information System (INIS)

    Mogro-Campero, A.; Hunt, B.D.; Turner, L.G.; Burrell, M.C.; Balz, W.E.

    1988-01-01

    Superconducting thin films of Y-Ba-Cu-O near the 1:2:3 stoichiometry were produced by simultaneous (coevaporation) and sequential (multilayer) evaporation in the same evaporator. The best film obtained on yttria-stabilized zirconia (YSZ) had a superconducting onset temperature of 104 K, a midpoint T/sub c/ of 92 K, and zero resistance at T≤74 K. Stoichiometry was deduced by inductively coupled plasma emission spectroscopy, and elemental depth profiles were obtained by x-ray photoelectron spectroscopy. Film stoichiometry changes only near the film/substrate boundary for films on YSZ. Films on Si/SiO 2 were not superconducting; depth profiling shows severe changes of film composition with depth. A major theme of this work is process reproducibility, which was found to be poor for coevaporation but improved considerably for sequential evaporation

  3. The complex ac susceptibility of superconducting Y-Ba-CuO thin film and bulk samples

    International Nuclear Information System (INIS)

    Lobotka, P.; Goemoery, F.

    1988-01-01

    Complex ac susceptibility measurements as function of temperature on Y-Ba-CuO superconductors are reported. A strong dependence of the susceptibility curves on the ac field magnitude and little influence of the superimposed dc field are observed on both, thin film and bulk samples. The susceptibilities of these materials are frequency independent in the range 30 to 7200 Hz what demonstrates the negligible role of eddy currents. A second peak in the imaginary part of susceptibility is observed in the bulk sample at higher levels of ac field. This implies the existence of another component in the sample with higher T c and lower losses. (author)

  4. Reduced thermal budget processing of Y--Ba--Cu--O high temperature superconducting thin films by metalorganic chemical vapor deposition

    International Nuclear Information System (INIS)

    Singh, R.; Sinha, S.; Hsu, N.J.; Ng, J.T.C.; Chou, P.; Thakur, R.P.S.; Narayan, J.

    1991-01-01

    Metalorganic chemical vapor deposition (MOCVD) has the potential of emerging as a viable technique to fabricate ribbons, tapes, coated wires, and the deposition of films of high temperature superconductors, and related materials. As a reduced thermal budget processing technique, rapid isothermal processing (RIP) based on incoherent radiation as the source of energy can be usefully coupled to conventional MOCVD. In this paper we report on the deposition and characterization of high quality superconducting thin films of Y--Ba--Cu--O (YBCO) on MgO and SrTiO 3 substrates by RIP assisted MOCVD. By using a mixture of N 2 O and O 2 as the oxygen source films deposited initially at 600 degree C for 1 min and then at 740 degree C for 30 min are primarily c-axis oriented and with zero resistance being observed at 84 and 89 K for MgO and SrTiO 3 substrates, respectively. The zero magnetic field current densities at 77 K for MgO and SrTiO 3 substrates are 1.2x10 6 and 1.5x10 6 A/cm 2 , respectively. It is envisaged that high energy photons from the incoherent light source and the use of a mixture of N 2 O and O 2 as the oxygen source, assist chemical reactions and lower overall thermal budget for processing of these films

  5. Growth and applications of superconducting Y-Ba-Cu-O thin films

    International Nuclear Information System (INIS)

    Pinto, R.

    1991-01-01

    This paper attempt to highlight the important PVD techniques such as evaporation, sputtering, ion beam deposition and excimer laser ablation for the preparation of superconducting YBaCuO thin films. Since enormous amount of work has been published over the last few years, this review is not comprehensive even in PVD techniques. In the area of applications for electronics, thin film appear to be much more promising than bulk high T c superconductors. Already high J c values in the region of 4 x 10 6 A cm -2 have been realized in thin films. Resonators and transmission lines have been fabricated using 123 films showing a transmission loss significantly lower than that of copper at 77 degrees K at X-band frequencies. This review will discuss some of the important electronic applications feasible with 123 films

  6. Experimental evidence for vortex-glass superconductivity in Y-Ba-Cu-O

    International Nuclear Information System (INIS)

    Koch, R.H.; Foglietti, V.; Gallagher, W.J.; Koren, G.; Gupta, A.; Fisher, M.P.A.

    1989-01-01

    We demonstrate experimentally the existence of a continuous phase transition between a normal and a true superconducting phase (with zero linear resistivity) in epitaxial films of Y-Ba-Cu-O in strong magnetic fields fields, H much-gt H c1 . The nonlinear I-V curves show scaling behavior near the transition and the relevant critical exponents are extracted. These exponents are consistent with values expected for freezing into a superconducting vortex-glass phase

  7. A-axis oriented superconductive YBCO thin films. Growth mechanism on MgO substrate. [Y-Ba-Cu-O

    Energy Technology Data Exchange (ETDEWEB)

    Hamet, J F; Mercey, B; Hervieu, M; Poullain, G; Raveau, B [Centre de Materiaux Supraconducteurs, CRISMAT-ISMRa, 14 - Caen (France)

    1992-08-01

    The growth mechanism of a-axis oriented YBCO thin films has been studied by TEM. At 650degC, a disordered cubic perovskite is first formed with a[sub p]parallela[sub MgO], then a strained tetragonal a-axis oriented perovskite is observed, with c=3a[sub p], slightly misoriented with respect to MgO and showing a marquetry-like contrast. At 750degC, a [1anti 10] axis oriented perovskite is formed whose lattice exhibits a rotation with respect to MgO lattice, but also a tilting of the [CuO[sub 2

  8. Thickness-dependent radiative properties of Y-Ba-Cu-O thin films

    International Nuclear Information System (INIS)

    Phelan, P.E.; Chen, G.; Tien, C.L.

    1991-01-01

    Some applications of high-temperature superconductors where their thermal radiative behavior is important, such as bolometers, optically-triggered switches and gates, and space-cooled electronics, required the superconductor to be in the form of a very thin film whose radiative behavior cannot be adequately represented by a semi-infinite analysis. Two properties of particular importance are the film absorptance and the combined film/substrate absorptance, which are crucial to the operation of many devices. This paper reports on calculations of the absorptance of superconducting-state Y-Ba-Cu-O films on MgO substrates which suggest that for film thicknesses less than about 50 nm, a decrease in the film thickness leads to an increase in both the film absorptance and the film/substrate absorptance. Furthermore, the film absorptance is maximum at some optimal value of film thickness. Assuming the film to be a smooth, continuous slab with a refractive index equal to that of the bulk Y-Ba-Cu-O is verified, at least in the normal state and for films as thin as 35 nm, by room-temperature reflectance and transmittance measurements

  9. Critical current properties in superconducting melt processed Y-Ba-Cu-O

    International Nuclear Information System (INIS)

    Matsushita, Teruo

    1993-01-01

    The critical current density in bulk superconducting Y-Ba-Cu-O has been remarkably improved by employing the so-called melt process. However, its value is still far below those reported in single-crystalline thin films. Important key factors that determine the critical current density are the flux pinning mechanism and defective structures such as cracks or weak links. In this article, these factors in melt-processed Y-Ba-Cu-O are argued from various measurements of the critical current density on the microstructure dependence, the magnetic field dependence, the temperature dependence, the history effect, the longitudinal field effect and the imaginary ac susceptibility. As for the pinning mechanism, it is concluded that the dominant pinning centers in the high temperature region around 77 K are normal 211 (Y 2 BaCuO 5 ) particles, while small defects such as lattice defects or oxygen deficiencies seem to be dominant in the lower temperature region. It is suggested that much finer normal particles should be introduced in order to improve the critical current density especially at higher temperatures. From the rapid decrease of the critical current density with elevating temperature below 30 K, some kind of weak links are considered to still remain in these materials. However, the observed critical current density did not depend on the history of application of the magnetic field and a large enhancement of the critical current density was observed in the longitudinal field geometry at 4.2 K. These results suggest that the weak links in these materials are of much different kind from those at large angle grain boundaries in sintered polycrystalline materials. From the X-ray diffraction measurements, a domain structure of a mean domain size of about 100 μm was found. These domain boundaries may cause weak links in melt-processed Y-Ba-Cu-O. It is also shown that the typical size of channels of flowing current can be obtained by the imaginary ac susceptibility

  10. Y-Ba-Cu-O thin films as high speed IR detectors

    International Nuclear Information System (INIS)

    Kwok, H.S.; Zheng, J.P.; Ying, Q.Y.

    1990-01-01

    Y-Ba-Cu-O thin film infrared detectors were fabricated and studied with various lasers. Operation of the detector in both the bolometric and nonbolometric modes was investigated at 10 microns with a CO2 laser. In the bolometric mode, the detectivity of the detector at 90 K was 2.1 x 10 to the 8th cm sq rt Hz/W with a response time of 15 microsec, corresponding to a bandwidth of 70 KHz. The speed of the detector in the nonbolometric mode was much faster and was beyond the instrument resolution. With a picosecond N2 laser, the output showed an instrument limited duration of 2 ns. The detectivity could not be determined in the nonbolometric mode due to the extremely low noise. The superconducting film quality is critical to the performance of these detectors. 27 refs

  11. Sequential Ar-O2 sputtering of Y2O3, BaF2, and CuO targets for preparation of Y-Ba-Cu-O superconducting films without wet-O2 annealing

    International Nuclear Information System (INIS)

    Bhushan, M.; Strauss, A.J.; Finn, M.C.

    1989-01-01

    Superconducting Y-Ba-Cu-O (YBCO) films have been prepared by ex situ O 2 annealing of multilayer films deposited on yttria-stabilized zirconia substrates by sequential rf diode sputtering of Y 2 O 3 , BaF 2 , and CuO targets, all of which are chemically stable. If sputtering is performed in an Ar ambient, the as-deposited films contain sufficient F to require its removal by annealing in wet O 2 at about 800 degree C or above before the superconducting YBCO phase can be formed by annealing in dry O 2 . However, sputtering in an Ar-O 2 ambient greatly reduces the F content, making it possible to obtain the superconducting phase by annealing in dry O 2 only. If the ambient contains about 20% O 2 , films with T c (R=0)>85 K can be prepared without wet-O 2 annealing. The Ar-O 2 process therefore has the potential for in situ preparation of superconducting YBCO films

  12. Superconductivity in the U(Th)-Y-Ba-Cu-O systems

    International Nuclear Information System (INIS)

    Qin Qizong; He Adi; Jia Weijie; Ma Lidun; Cheng Huansheng; Hua Zhongyi

    1989-01-01

    High T c superconductivity has been observed both resistively and magnetically in the new U(Th)-Y-Ba-Cu-O systems. The zero resistance temperature of the three samples with nominal composition of U 0.1 Y 1.1 Ba 0.8 Cu O 4-z , U 0.15 Y 1.05 Ba 0.8 Cu 4-z and Th 0.3 Y 0.8 Ba 0.8 Cu 4-z is 87K, 79K and 74K, respectively. The result of ac magnetic susceptibility measurement implies that the superconducting state is realized in the U-doped samples below 90K. The stoichimetry of the U-Y-Ba-Cu O superconductors has the aid of Rutherford backscattering and nuclear reaction 16 O(d, p) 17 O. The analytical results show that the 'real composition' of somples may be different from that of the nomial composition. The X ray diffraction analysis of the U-Y-Ba-Cu-O system shows that none of the peaks can be fitted to the uranium oxides and the other raw materiale structure, and its pattern may be attributed to new multiple phases with structure different from the known singlephase superconducting oxides

  13. Synthesis of high-oxidation Y-Ba-Cu-O phases in superoxygenated thin films

    Science.gov (United States)

    Zhang, H.; Gauquelin, N.; McMahon, C.; Hawthorn, D. G.; Botton, G. A.; Wei, J. Y. T.

    2018-03-01

    It is known that solid-state reaction in high-pressure oxygen can stabilize high-oxidation phases of Y-Ba-Cu-O superconductors in powder form. We extend this superoxygenation concept of synthesis to thin films which, due to their large surface-to-volume ratio, are more reactive thermodynamically. Epitaxial thin films of YBa2Cu3O7 -δ grown by pulsed laser deposition are annealed at up to 700 atm O2 and 900 ∘C , in conjunction with Cu enrichment by solid-state diffusion. The films show the clear formation of Y2Ba4Cu7O15 -δ and Y2Ba4Cu8O16 as well as regions of YBa2Cu5O9 -δ and YBa2Cu6O10 -δ phases, according to scanning transmission electron microscopy, x-ray diffraction, and x-ray absorption spectroscopy. Similarly annealed YBa2Cu3O7 -δ powders show no phase conversion. Our results demonstrate a route of synthesis towards discovering more complex phases of cuprates and other superconducting oxides.

  14. Thickness Dependence of Magnetic Relaxation and E-J Characteristics in Superconducting (Gd-Y)-Ba-Cu-O Films with Strong Vortex Pinning

    Energy Technology Data Exchange (ETDEWEB)

    Polat, Ozgur [ORNL; Sinclair IV, John W [ORNL; Zuev, Yuri L [ORNL; Thompson, James R [ORNL; Christen, David K [ORNL; Cook, Sylvester W [ORNL; Kumar, Dhananjay [ORNL; Chen, Y [SuperPower Incorporated, Schenectady, New York; Selvamanickam, V. [SuperPower Incorporated, Schenectady, New York

    2011-01-01

    The dependence of the critical current density Jc on temperature, magnetic field, and film thickness has been investigated in (Gd-Y)BaCu-oxide materials of 0.7, 1.4, and 2.8 m thickness. Generally, the Jc decreases with film thickness at investigated temperatures and magnetic fields. The nature and strength of the pinning centers for vortices have been identified through angular and temperature measurements, respectively. These films do not exhibit c-axis correlated vortex pinning, but do have correlated defects oriented near the ab-planes. For all film thicknesses studied, strong pinning dominates at most temperatures. The vortex dynamics were investigated through magnetic relaxation studies in the temperature range of 5 77 K in 1 T and 3 T applied magnetic fields, H || surface-normal. The creep rate S is thickness dependent at high temperatures, implying that the pinning energy is also thickness dependent. Maley analyses of the relaxation data show an inverse power law variation for the effective pinning energy Ueff ~ (J0/J) . Finally, the electric field-current density (E-J) characteristics were determined over a wide range of dissipation by combining experimental results from transport, swept field magnetometry (VSM), and Superconducting Quantum Interference Device (SQUID) magnetometry. We develop a self-consistent model of the combined experimental results, leading to an estimation of the critical current density Jc0(T) in the absence of flux creep.

  15. A superconducting conveyer system using multiple bulk Y-Ba-Cu-O superconductors and permanent magnets

    Science.gov (United States)

    Kinoshita, T.; Koshizuka, N.; Nagashima, K.; Murakami, M.

    Developments of non-contact superconducting devices like superconducting magnetic levitation transfer and superconducting flywheel energy storage system have been performed based on the interactions between bulk Y-Ba-Cu-O superconductors and permanent magnets, in that the superconductors can stably be levitated without any active control. The performances of noncontact superconducting devices are dependent on the interaction forces like attractive forces and stiffness. In the present study, we constructed a non-contact conveyer for which the guide rails were prepared by attaching many Fe-Nd-B magnets onto an iron base plate. Along the translational direction, all the magnets were arranged as to face the same pole, and furthermore their inter-distance was made as small as possible. The guide rail has three magnet rows, for which the magnets were glued on the iron plate such that adjacent magnet rows have opposite poles like NSN. At the center row, the magnetic field at zero gap reached 0.61T, while the field strengths of two rows on the side edges were only 0.48T due to magnetic interactions among permanent magnets. We then prepared a cryogenic box made with FRP that can store several bulk Y-Ba-Cu-O superconductors 25 mm in diameter cooled by liquid nitrogen. It was found that the levitation forces and stiffness increased with increasing the number of bulk superconductors installed in the box, although the levitation force per unit bulk were almost the same. We also confirmed that these forces are dependent on the configuration of bulk superconductors.

  16. Composition changes in sputter deposition of Y-Ba-Cu-O films

    International Nuclear Information System (INIS)

    Hoshi, Y.; Naoe, M.

    1989-01-01

    The authors discuss the mechanism of the composition change in sputter deposition of Y-BA-Cu-O film from YBa 2 Cu 3 O 7-chi target investigated by means of a rf planar magnetron sputtering apparatus. Film composition changes significantly with not only substrate temperature Ts and sputtering gas pressure, but also substrate position. Lack of Cu and Ba content is significant in the film deposited at the substrate position just above the erosion area of the sputtering target. Suppression of bombardment of the substrate surface by negative ions emitted from the target and substrate is effective in increasing Cu and Ba content in the film. These results indicate not only that the sticking probability of the sputtered particles changes with Ts and incident particle energy, but also that high energy particle bombardment of the substrate surface plays an important role in the change of the film composition

  17. Experimental study of the plasma fluorination of Y-Ba-Cu-O thin films

    CERN Document Server

    Li Qi; Ji Zheng Ming; Feng Yi Jun; Kang Lin; Yang Sen Zu; Wu Pei Heng; Wang Xiao Shu; Ye Yuda

    2002-01-01

    The authors have experimentally studied the surface modifications of Y-Ba-Cu-O (YBCO) thin films using CF sub 4 plasma. The intensity of the plasma fluorination was controlled by changing the biasing voltage and the time of the plasma treatment. Microstructural analyses reveal that the oxygen content of the YBCO thin films was changed. Transport measurements of sufficient fluorinated YBCO films imply that the films changed totally into an oxygen-deficient semi-conducting state. From these experimental results, the authors believe that plasma fluorination is quite a useful method to form controllable a thin barrier layer in fabricating interface engineered junctions and to form a stable narrow weak-link region in fabricating planar superconductor-normal-superconductor junctions

  18. Surface impedance of epitaxial films Y-Ba-Cu-O in short wave region of range millimetric

    International Nuclear Information System (INIS)

    Vojnovskij, I.V.; Pustyl'nik, O.D.; Boguslavskij, Yu.M.; Shapovalov, A.P.

    1992-01-01

    Epitaxial Y-Ba-Cu-O films on MgO substrate with perfect crystal structure are obtained due to nonaxial magnetron HF-spraying. Temperature dependence of the surface impedance of the films within 66 and 134 GHz frequency is studied. The obtained value of residual surface resistance within 134 GHz frequency (60 mohm) confirms high quality of the films

  19. Superconductivity above 90K in the Y-Ba-Cu-O compound system

    International Nuclear Information System (INIS)

    Paterno, G.; Balestrino, G.; Barbanera, S.

    1987-01-01

    Preliminary results on high Tc superconductors are reported. One of Y-Ba-Cu-O compound system has been fabricated. The temperature dependence of the resistance has been determined. The critical temperature of the samples annealed in Oxygen atmosphere is well above the normal boiling point of liquid nitrogen

  20. Fractal formation of a Y-Ba-Cu-O thin film on SrTiO3

    International Nuclear Information System (INIS)

    Chow, L.; Chen, J.; Desai, V.; Sundaram, K.; Arora, S.

    1989-01-01

    Fractal formation has been observed after thermal annealing of the rf-sputtered Y-Ba-Cu-O thin film on SrTiO 3 substrate. Through energy-dispersive x-ray analysis, it was found that the composition of the fractal was YBa 2 Cu 3 O x and the surrounding film composition wasY 2 Ba 2 Cu 3 O x . The fractal dimensions D ranging from 1.26 to 1.65 were obtained using the standard sandbox method with different thresholds

  1. Reduced thermal budget processing of Y-Ba-Cu-O films by rapid isothermal processing assisted metalorganic chemical vapor deposition

    International Nuclear Information System (INIS)

    Singh, R.; Sinha, S.; Hsu, N.J.; Ng, J.T.C.; Chou, P.; Thakur, R.P.S.; Narayan, J.

    1991-01-01

    Metalorganic chemical vapor deposition (MOCVD) has the potential of emerging as a viable technique to fabricate ribbons, tapes, coated wires, and the deposition of films of high-temperature superconductors, and related materials. As a reduced thermal budget processing technique, rapid isothermal processing (RIP) based on incoherent radiation as the source of energy can be usefully coupled to conventional MOCVD. In this paper we report on the deposition and characterization of high quality superconducting thin films of Y-Ba-Cu-O (YBCO) on yttrium stabilized zirconia substrates by RIP assisted MOCVD. Using O 2 gas as the source of oxygen, YBCO films deposited initially at 600 degree C for 1 min and at 745 degree C for 25 min followed by deposition at 780 degree C for 45 s are primarily c-axis oriented and zero resistance is observed at 89--90 K. The zero magnetic field current density at 53 and 77 K are 1.2x10 6 and 3x10 5 A/cm 2 , respectively. By using a mixture of N 2 O and O 2 as the oxygen source substrate temperature was further reduced in the deposition of YBCO films. The films deposited initially at 600 degree C for 1 min and than at 720 degree C for 30 min are c-axis oriented and with zero resistance being observed at 91 K. The zero magnetic field current densities at 53 and 77 K are 3.4x10 6 and 1.2x10 6 A/cm 2 , respectively. To the best of our knowledge this is the highest value of critical current density, J c for films deposited by MOCVD at a substrate temperature as low as 720 degree C. It is envisioned that high energy photons from the incoherent light source and the use of a mixture of N 2 O and O 2 as the oxygen source, assist chemical reactions and lower overall thermal budget for processing of these films

  2. The microscopic twins and their crystal phase in the high Tc Y-Ba-Cu-O and Dy-Ba-Cu-O superconductive ceramics

    International Nuclear Information System (INIS)

    Zu, Z.J.; Chen, Y.L.

    1988-01-01

    Most consider that the structure of Y-Ba- Cu-O and Dy-Ba-Cu-O stable superconductive crystals with high Tc is associated with the right-angled phase. The superconductivity is closely connected with the right-angled character of the crystalline texture; the better the right- angled character, the better the superconductivity. From statistical investigations of examples the authors have discovered that most of the Y-Ba-Cu-O and Dy-Ba-Cu-O superconductivity with high Tc ceramic crystals is in the monoclinic phase, which, consists of microscopic, lamellar, single twins. The long-columnar grains consisting of lamellar twin slabs show the optical characteristics of right-angled phase. The microscopic twinning and grain morphologies are summarized in this paper

  3. Flux flow and flux creep in thick films of YBCO. [Y-Ba-Cu-O

    Energy Technology Data Exchange (ETDEWEB)

    Rickets, J.; Vinen, W.F.; Abell, J.S.; Shields, T.C. (Superconductivity Research Group, Univ. of Birmingham (United Kingdom))

    1991-12-01

    The results are described of new experiments designed to study flux creep and flux flow along a single flux percolation path in thick films of YBCO. The flux flow regime is studied by a four-point resistive technique using pulsed currents, and the flux creep regime by observing the rate at which flux enters a superconducting loop in parallel with the resistance that is associated with the flux percolation path. (orig.).

  4. Submillimeter and microwave residual losses in epitaxial films of Y-Ba-Cu-O and Tl-Ca-Ba-Cu-O

    International Nuclear Information System (INIS)

    Miller, D.; Richards, P.L.; Eom, C.B.; Geballe, T.H.; Etemad, S.; Inam, A.; Venkatesan, T.; Martens, J.S.; Lee, W.Y.

    1992-12-01

    We have used a novel bolometric technique and a resonant technique to obtain accurate submillimeter and microwave residual loss data for epitaxial thin films of YBa 2 Cu 3 O 7 , Tl 2 Ca 2 Ba 2 Cu 3 O 10 and Tl 2 CaBa 2 Cu 2 O 8 . For all films we obtain good agreement between the submillimeter and microwave data, with the residual losses in both the Y-Ba-Cu-O and Tl-Ca-Ba-Cu-O films scaling approximately as frequency squared below ∼ 1 THz. We are able to fit the losses in the Y-Ba-Cu-O films to a two fluid and a weakly coupled grain model for the a-b planeconductivity, in good agreement with results from a Kramers-Kronig analysis of the loss data

  5. DC Magnetron sputtering of Y-Ba-Cu-O thin films

    International Nuclear Information System (INIS)

    Larsson, Gunnar.

    1990-01-01

    I have been studying dc magnetron sputtering of thin film YBa 2 Cu 3 O 6+x , one of the recently discovered high- temperatures superconductors. In the introduction a brief review of the subjects sputtering and superconductivity is given. Since partial pressure measurements, especially for oxygen, have been important in the work I include a short description of the operating principles of mass spectroscopy. Experimental results in addition to what is given in the papers concerning plasma are presented in an appendix at the end of the introduction. (au)

  6. Slow voltage oscillations in Ag-doped superconducting Y-Ba-Cu-O

    International Nuclear Information System (INIS)

    Altinkok, A.; Yetis, H.; Kilic, K.; Kilic, A.; Olutas, M.

    2008-01-01

    The time effects in Ag-doped YBa 2 Cu 3 O 7-x sample (YBCO/Ag) were examined by means of transport relaxation measurements (V-t curves). At well-defined values of transport current (I), temperature (T) and external magnetic field (H), an abrupt rise in sample voltage was observed at the early stage of the relaxation process. After reducing the initial current to a finite value, the sample voltage levels off within a very short time. The rapid voltage drops seen in V-t curves were attributed to the rapid dynamic reorganization of flux lines traversing the sample edges. These observations were also interpreted as an indication of doping of YBCO with Ag and easy suppression of superconducting order parameter due to the presence of Ag. In addition, we investigated the influence of bidirectional square wave (BSW) current on the evolution of V-t curves at different temperatures and external magnetic fields. It was observed that a nonlinear response seen in V-t curves to BSW current with sufficiently short periods or sufficiently low amplitude reflects itself as regular sinusoidal- type voltage oscillations, which were discussed mainly in terms of the dynamic competition between pinning and depinning

  7. Slow voltage oscillations in Ag-doped superconducting Y-Ba-Cu-O

    Energy Technology Data Exchange (ETDEWEB)

    Altinkok, A. [Abant Izzet Baysal University, Department of Physics, Turgut Gulez Research Laboratory, 14280 Bolu (Turkey)], E-mail: altinkok_a@ibu.edu.tr; Yetis, H.; Kilic, K.; Kilic, A.; Olutas, M. [Abant Izzet Baysal University, Department of Physics, Turgut Gulez Research Laboratory, 14280 Bolu (Turkey)

    2008-09-15

    The time effects in Ag-doped YBa{sub 2}Cu{sub 3}O{sub 7-x} sample (YBCO/Ag) were examined by means of transport relaxation measurements (V-t curves). At well-defined values of transport current (I), temperature (T) and external magnetic field (H), an abrupt rise in sample voltage was observed at the early stage of the relaxation process. After reducing the initial current to a finite value, the sample voltage levels off within a very short time. The rapid voltage drops seen in V-t curves were attributed to the rapid dynamic reorganization of flux lines traversing the sample edges. These observations were also interpreted as an indication of doping of YBCO with Ag and easy suppression of superconducting order parameter due to the presence of Ag. In addition, we investigated the influence of bidirectional square wave (BSW) current on the evolution of V-t curves at different temperatures and external magnetic fields. It was observed that a nonlinear response seen in V-t curves to BSW current with sufficiently short periods or sufficiently low amplitude reflects itself as regular sinusoidal- type voltage oscillations, which were discussed mainly in terms of the dynamic competition between pinning and depinning.

  8. Exponential temperature dependence of the critical transport current in Y-Ba-Cu-O thin films

    International Nuclear Information System (INIS)

    Yom, S.S.; Hahn, T.S.; Kim, Y.H.; Chu, H.; Choi, S.S.

    1989-01-01

    We have measured the critical currents in rf-sputtered YBa 2 Cu 3 O/sub 7-x/ thin films deposited on polycrystalline yttria-stabilized zirconia substrates as a function of temperature down to 10 K. The dependence of the granular films at low temperature indicated exponential behavior which is similar to the superconductor-normal metal-superconductor (S-N-S) type tunneling junctions. For the films with a grain size of approximately 1 μm, we observed two exponential decay constants, which suggest that Josephson junctions limiting the transport critical current are possible both at the grain boundaries and at twin boundaries

  9. Magnetic properties of laser deposited films of Y-Ba-Cu-O

    Energy Technology Data Exchange (ETDEWEB)

    McGuire, T.R.; Dimos, D.; Gupta, A.; Koren, G.; Laibowitz, R.B. (IBM Research Division, T. J. Watson Research Center, P. O. Box 218, Yorktown Heights, New York 10598 (USA))

    1990-05-01

    Films of YBa{sub 2}Cu{sub 3}O{sub 7{minus}{ital x}} prepared by laser ablation deposition show epitaxial growth on (100) SrTiO{sub 3} substrates with the {ital c} axis perpendicular to the plane of the film. With the magnetic field ({ital H}) parallel to the {ital c} axis, critical currents of up to 40 MA/cm{sup 2} from magnetization measurements are obtained. With {ital H} perpendicular to the {ital c} axis, various magnetization measurements with field cooling in 40 kOe indicated strong pinning effects with a calculated critical current density significantly higher than that observed in the parallel field configuration.

  10. The XRD Study of the Effect of Slight Change in Structure on the Superconductivity of Y-Ba-Cu-O System Material

    Science.gov (United States)

    Huaqin, Wang; Shiyuan, Zhang; Tongzheng, Jin; Shiying, Han; Dirong, Qiu; Hao, Wang; Ningsheng, Zhou

    In this paper the differences in diffraction intensities from some crystal planes in the X-ray diffraction patterns of high Tc Y-Ba-Cu-O system superconductors prepared by different processing conditions and the difference among various structure cells in references are interpreted using computer fitting. The results suggest that there exists two structure cells in the single phase YBa2Cu3O7-x samples. Both structure cells have the same crystal symmetry and almost the same lattice parameters, a=3.821Å, b=3.892Å and c=11.676Å, but the different distortion degree of Cu2-O plane. According to EPR spectra measured on the same samples, it is considered that the improvement of superconductivity for the samples prepared by two-step annealing in flowing oxygen may be related to concentration of the structure cell with more serious distortion on the Cu2-O plane.

  11. The improvement of the superconducting Y-Ba-Cu-O magnet characteristics through shape recovery strain of Fe-Mn-Si alloys

    International Nuclear Information System (INIS)

    Shimpo, Y.; Seki, H.; Wongsatanawarid, A.; Taniguchi, S.; Maruyama, T.; Kurita, T.; Murakami, M.

    2010-01-01

    Since bulk Y-Ba-Cu-O superconductors are brittle ceramics, reinforcement of mechanical properties is important for practical applications. It has been reported that bulk Y-Ba-Cu-O can be reinforced with Al or Fe based alloy ring, in that compression force acts on bulk Y-Ba-Cu-O due to a difference in thermal expansion coefficients. However, the shrinkage of the metal ring was not so large, and therefore careful adjustment of the circumference of the bulk and the metal rings was necessary. In this study, we employed Fe-Mn-Si shape memory alloy rings to reinforce bulk Y-Ba-Cu-O. The advantage of the shape memory alloy is that the shrinkage can take place on heating, and furthermore, the alloy shrinks and compresses the bulk body on cooling. Bulk Y-Ba-Cu-O superconductor 22.8 mm in diameter was inserted in a Fe-Mn-Si ring 23.0 mm in inner diameter at room temperature. Beforehand, the Fe-Mn-Si ring was expanded by 12% strain at room temperature. Then the composite was heated to 673 K. At room temperature, the Fe-Mn-Si ring firmly gripped the bulk superconductor. We then measured trapped fields before and after the ring reinforcement, and found that the trapped field was improved through the treatment.

  12. Fabrication of Y-Ba-Cu-O (123) cuprate superconducting system and study of their electrical and structural properties

    International Nuclear Information System (INIS)

    Ahmed, F.; Hossain, M.K.; Sultana, H.R.; Abdul Hossain, M.; Khan, A.H.

    2005-08-01

    We know that in the YBa 2 Cu 3 O 6+x superconducting system transition temperature T c is highly dependent on the oxygen content in the compound. So, in order to fabricate superconducting YBa 2 Cu 3 O 6+x material under oxygen flow we have fabricated a tube furnace. Superconducting YBa 2 Cu 3 O 7-δ compounds were synthesized by the solid state reaction method. Different pressure for the pellet formation, different sintering and annealing conditions in air or in oxygen atmosphere were carried out to study the effect on the formation of superconducting phase. Samples were characterized by dc electrical resistance and X-ray diffraction. Superconducting Y 1-x Ca x Ba 2 Cu 3 O 7-δ compounds are now under investigation. (author)

  13. Parametric interactions in high-Tc superconducting step edge junctions at X-band. [Y-Ba-Cu-O

    Energy Technology Data Exchange (ETDEWEB)

    Kain, A.Z. (TRW Space and Tech. Group, Redondo Beach, CA (United States)); Fetterman, H.R. (Electrical Engineering Dept., Univ. of California at Los Angeles (United States))

    1993-04-20

    We have fabricated and tested both single junctions and series arrays of YBCO step edge junctions for four photon parametric effects at X band as a first step in developing a parametric amplifier at 60 GHz. The series array of 25 junctions at 10.3 Ghz shows a 10 dB increase in reflected signal power as the pump power is increased, while the single junction at 12.2 GHz indicates a 2 dB change. The reflected power at the characteristic idler frequency of 2[omega][sub p]-[omega][sub s] is evidence of true Josephson junction parametric interaction. We are currently investigating the use of thallium based films at 60 GHz which offer a broader range of operating temperatures than does YBCO. Our design for a parametric amplifier at V band is a combination of microstrip based series arrays of junctions and an antipodal finline transition. (orig.)

  14. Integrated-circuit microwave detector based on granular high-Tc thin films. [Y-Ba-Cu-O

    Energy Technology Data Exchange (ETDEWEB)

    Drobinin, A.V.; Lutovinov, V.S.; Starostenko, I.V. (Moscow Inst. of Radioengineering, Electronics and Automation, (MIREA), Moscow (USSR))

    1991-12-01

    A highly sensitive integrative-circuit microwave detector based on granular High-Tc film has been designed. All matching circuits and High-Tc microbridge are located on the same substrate. The voltage responsivity 10{sup 3} V/W has been found at 65 K and frequency 5 GHz. Different modes of microwave detection have been observed: bolometric response near Tc in high-quality films, rectification mode caused by an array of weak links dominating in low-quality films, detection caused by nonlinear magnetic flux motion. (orig.).

  15. The effect of nano-size ZrO2 powder addition on the microstructure and superconducting properties of single-domain Y-Ba-Cu-O bulk superconductors

    International Nuclear Information System (INIS)

    Iida, K; Babu, N H; Reddy, E S; Shi, Y-H; Cardwell, D A

    2005-01-01

    The effect of nano-size ZrO 2 powder addition on the microstructure and superconducting properties of Y-Ba-Cu-O single grain bulk superconductors has been investigated. Significant pushing phenomena of Y 2 BaCuO 5 (Y-211) particles, particularly in the c growth sector, were observed even with a small amount of ZrO 2 added to the precursor powder. An increase in Y-211 particle pushing was observed with increasing ZrO 2 content, leading to an inhomogeneous bulk microstructure. In addition, a growth cycle consisting of a Y-211 free layer-porous narrow layer-Y-211 high concentration layer was observed for samples prepared with 0.25 wt% ZrO 2 in both the a and c growth sectors. The extent of the growth of single grain Y-Ba-Cu-O (YBCO) decreased with increasing ZrO 2 content due to increased pushing of Y-211 particles towards molten liquid. The superconducting transition temperature, T c , of the ZrO 2 containing YBCO samples was sharp but depressed slightly (by up to 1 K) compared with an undoped YBCO grain, indicating a relative insensitivity of T c to ZrO 2 content. Finally, the sensitivity of critical current density, J c , to applied magnetic field in large grain bulk YBCO containing ZrO 2 was observed to depend critically on position due to the inhomogeneous sample microstructure

  16. Synthesis and studies of Y-Ba-Cu-O high temperature superconductor prepared by sol-gel method

    International Nuclear Information System (INIS)

    Grigoryan, S.G.; Manukyan, A.L.; Hayrapetyan, A.G.; Arzumanyan, A.M.; Rashidyan, L.H.; Mkrtichyan, N.Y.; Mkrtchyan, A.A.; Kurginyan, K.A.; Trozyan, A.H.; Vardanyan, R.S.

    2004-01-01

    The method of preparation of Y-Ba-Cu-O high temperature superconducting materials by sol-gel processing technique both for powders and thin films are described. All these methods are based on using yttrium alkoxides as precursors, which are not ready available reagents, besides the majority of these methods use copper alkoxides, which show low solubility in organic solvents, moreover they are very sensitive to hydrolysis in air. The new method of preparation of Y-Ba-Cu-O ceramic materials by sol-gel processing technique based on new and convenient precursors stable in air, having high compatibility with each other is offered. Basic scientific and technological issues related to the synthesis of bulk materials, their structure and electrical conductivity are discussed

  17. Fatigue and retention in ferroelectric Y-Ba-Cu-O/Pb-Zr-Ti-O/Y-Ba-Cu-O heterostructures

    Science.gov (United States)

    Ramesh, R.; Chan, W. K.; Wilkens, B.; Gilchrist, H.; Sands, T.; Tarascon, J. M.; Keramidas, V. G.; Fork, D. K.; Lee, J.; Safari, A.

    1992-09-01

    Fatigue and retention characteristics of ferroelectric lead zirconate titanate thin films grown with Y-Ba-Cu-O(YBCO) thin-film top and bottom electrodes are found to be far superior to those obtained with conventional Pt top electrodes. The heterostructures reported here have been grown in situ by pulsed laser deposition on yttria-stabilized ZrO2 buffer [100] Si and on [001] LaAlO3. Both the a- and c-axis orientations of the YBCO lattice have been used as electrodes. They were prepared using suitable changes in growth conditions.

  18. Critical state in the Y-Ba-Cu-O ceramics

    International Nuclear Information System (INIS)

    Artemov, A.N.; Grishin, A.M.; Korenivskii, V.N.; Ulyanov, A.N.; Khokhlov, V.A.

    1990-01-01

    This paper reports on the temperature and field dependences of the Y-Ba-Cu-O ceramics susceptibility studied both experimentally and theoretically. These dependence have been used to reconstruct the temperature dependence of the critical current (j c (T) = j c (O)(1 - T/T c1 ) 3/2 , J c (O) = 340 A/cm 2 , T c1 = 94.6 K) and the distribution of the granules with respect to the superconducting transition temperature (with the maximum at T c2 = 95.3 K and ΔT = 1.1 K). Within the critical state concept diamagnetic response of the granular superconductors at fundamental and multiple frequencies has been calculated. The calculation results are in good agreement with the experimentally obtained susceptibility dependences and explain the different dependences of the diamagnetic response on the magnitude of the d.c. field and the amplitude of a.c. field

  19. Influence of Zr and Ce doping on electromagnetic properties of (Gd,Y)-Ba-Cu-O superconducting tapes fabricated by metal organic chemical vapor deposition

    International Nuclear Information System (INIS)

    Selvamanickam, V.; Chen, Y.; Xie, J.; Zhang, Y.; Guevara, A.; Kesgin, I.; Majkic, G.; Martchevsky, M.

    2009-01-01

    (Gd,Y)Ba 2 Cu 3 O x tapes have been fabricated by metal organic chemical vapor deposition (MOCVD) with Zr-doping levels of 0-15 mol.% and Ce doping levels of 0-10 mol.% in 0.4 μm thick films. The critical current density (J c ) of Zr-doped samples at 77 K, 1 T applied in the orientation of H -parallel c is found to increase with Zr content and shows a maximum at 7.5% Zr doping. The 7.5% Zr-doped sample exhibits a critical current density (J c ) of 0.95 MA/cm 2 at H -parallel c which is more than 70% higher than the J c of the undoped sample. The peak in J c at H -parallel c is 83% of that at H -parallel a-b in the 7.5% Zr-doped sample which is more than twice as that in the undoped sample. Superconducting transition temperature (T c ) values as high as about 89 K have been achieved in samples even with 15% Zr and 10% Ce. Ce-doped samples with and without Ba compensation are found to exhibit substantially different J c values as well as angular dependence characteristics.

  20. Influence of Zr and Ce doping on electromagnetic properties of (Gd,Y)-Ba-Cu-O superconducting tapes fabricated by metal organic chemical vapor deposition

    Energy Technology Data Exchange (ETDEWEB)

    Selvamanickam, V., E-mail: selva@uh.ed [Department of Mechanical Engineering and Texas Center for Superconductivity, University of Houston, 4800 Calhoun Rd., Houston, TX 77204-4006 (United States); Chen, Y.; Xie, J. [SuperPower Inc., 450 Duane Ave., Schenectady, NY 12304 (United States); Zhang, Y.; Guevara, A.; Kesgin, I.; Majkic, G. [Department of Mechanical Engineering and Texas Center for Superconductivity, University of Houston, 4800 Calhoun Rd., Houston, TX 77204-4006 (United States); Martchevsky, M. [SuperPower Inc., 450 Duane Ave., Schenectady, NY 12304 (United States)

    2009-12-01

    (Gd,Y)Ba{sub 2}Cu{sub 3}O{sub x} tapes have been fabricated by metal organic chemical vapor deposition (MOCVD) with Zr-doping levels of 0-15 mol.% and Ce doping levels of 0-10 mol.% in 0.4 mum thick films. The critical current density (J{sub c}) of Zr-doped samples at 77 K, 1 T applied in the orientation of H -parallel c is found to increase with Zr content and shows a maximum at 7.5% Zr doping. The 7.5% Zr-doped sample exhibits a critical current density (J{sub c}) of 0.95 MA/cm{sup 2} at H -parallel c which is more than 70% higher than the J{sub c} of the undoped sample. The peak in J{sub c} at H -parallel c is 83% of that at H -parallel a-b in the 7.5% Zr-doped sample which is more than twice as that in the undoped sample. Superconducting transition temperature (T{sub c}) values as high as about 89 K have been achieved in samples even with 15% Zr and 10% Ce. Ce-doped samples with and without Ba compensation are found to exhibit substantially different J{sub c} values as well as angular dependence characteristics.

  1. Numerical analysis of transport phenomena in Y-Ba-Cu-O melt during growth of superconducting crystal Y123 by Czochralski method

    Science.gov (United States)

    Szmyd, J. S.; Suzuki, K.

    2003-10-01

    In 1993, at the Superconductivity Research Laboratory (SRL), International Superconductivity Technology Centre (ISTEC), in Tokyo, continuous growth of large single crystals of YBa 2Cu 3O 7- x (Y123) was achieved by the application of a modified Czochralski method. This paper presents the numerical computations of the flow, thermal and Y concentration fields in the Ba-Cu-O melt for Y123 single crystal growth by this modified method. The finite volume method was used to calculate the fluid flow, heat transfer and yttrium distribution in the melt with staggered numerical grid. The flow in the melt was modelled as an incompressible Newtonian and Boussinesque fluid. Calculations are presented for a combined flow regime of buoyancy-driven natural convection and crystal-rotation-driven forced convection.

  2. Effect of shock pressure on the structure and superconducting properties of Y-Ba-Cu-O in explosively fabricated bulk metal-matrix composites

    Science.gov (United States)

    Murr, L. E.; Niou, C. S.; Pradhan-Advani, M.

    1991-01-01

    While it is now well established that copper-oxide-based power, or virtually any other ceramic superconductor powder, can be consolidated and encapsulated within a metal matrix by explosive consolidation, the erratic superconductivity following fabrication has posed a major problem for bulk applications. The nature of this behavior was found to arise from microstructural damage created in the shock wave front, and the residual degradation in superconductivity was demonstrated to be directly related to the peak shock pressure. The explosively fabricated or shock loaded YBa2Cu3Ox examples exhibit drastically altered rho (or R) - T curves. The deterioration in superconductivity is even more noticeable in the measurement of ac magnetic susceptibility and flux exclusion or shielding fraction which is also reduced in proportion to increasing peak shock pressure. The high frequency surface resistance (in the GHz range) is also correspondingly compromised in explosively fabricated, bulk metal-matrix composites based on YBa2Cu3O7. Transmission electron microscopy (including lattice imaging techniques) is being applied in an effort to elucidate the fundamental (microstructural) nature of the shock-induced degradation of superconductivity and normal state conductivity. One focus of TEM observations has assumed that oxygen displaced from b-chains rather than oxygen-vacancy disorder in the basal plane of oxygen deficient YBa2Cu3Ox may be a prime mechanism. Shock-wave displaced oxygen may also be locked into new positions or interstitial clusters or chemically bound to displaced metal (possibly copper) atoms to form precipitates, or such displacements may cause the equivalent of local lattice cell changes as a result of stoichiometric changes. While the shock-induced suppression of T(sub c) is not desirable in the explosive fabrication of bulk metal-matrix superconductors, it may be turned into an advantage if the atomic-scale distortion can be understood and controlled as local

  3. Structural instabilities in superconductor Y-Ba-Cu-O studied by positron annihilation

    International Nuclear Information System (INIS)

    Wang Shaojie; Li Xiaohua; Chen Yilong; Li Shiqing; Feng Guohua; Wang Zhu; Chen Ang; Li Biaorong

    1989-01-01

    The positron lifetime and Doppler broadening were measured as a function of temperature between 100K and 300K for Y-Ba-Cu-O superconductor. There are anomalous changes in the positron lifetimes and S parameters near 130K and 260K which imply that some phase transitions related to superconductivity happenned there. The results were discussed in terms of the lattice instabilities which may caused by the ordering readjustment of oxygen vacancies

  4. Jc enhancement by La-Al-O doping in Y-Ba-Cu-O films both in self-field and under magnetic field

    DEFF Research Database (Denmark)

    Xu, Yan; Suo, Hong-Li; Yue, Zhao

    2016-01-01

    a good epitaxial growth relationship with LAO. Compared with a pure YBCO film, the Jc value of a 5.0% LAO-doped sample is enhanced more than three times in self-field 77 K and seven times at 77 K and 1.5 T, respectively. These results indicate that LAO doping can effectively enhance the Jc of YBCO films...... toward YBCO. A series of YBCO films with different LAO doping contents was fabricated on LAO single-crystal substrates by metal organic deposition. We observed by X-ray diffractometer measurements and scanning electron microscopy observations that although a large amount of LAO is added, YBCO still keeps...

  5. Microstructures and precipitates in laser-ablated YBCO thin films on SrTiO[sub 3] (110). [Y-Ba-Cu-O

    Energy Technology Data Exchange (ETDEWEB)

    Catana, A. (IBM Research Div., Zurich Research Lab., Rueschlikon (Switzerland)); Rossel, C. (IBM Research Div., Zurich Research Lab., Rueschlikon (Switzerland)); Perrin, A. (Lab. de Chimie du Solide et Inorganique Moleculaire, Univ. de Rennes 1, 35 (France)); Guilloux-Viry, M. (Lab. de Chimie du Solide et Inorganique Moleculaire, Univ. de Rennes 1, 35 (France)); Thivet, C. (Lab. de Chimie du Solide et Inorganique Moleculaire, Univ. de Rennes 1, 35 (France))

    1993-05-10

    Thin YBCO films ([proportional to] 100 nm) have been deposited by laser ablation on SrTiO[sub 3] (110) substrates. Microstructural investigations have been performed by scanning tunneling and high-resolution electron microscopy. The results show that the surface corrugation is related to the growth of twisted YBCO domains that nucleate at the film/substrate interface. The twist is characterized by a 90 rotation of YBCO around the 100 and/or 010 axes, which results in [l brace]013[r brace] and/or [l brace]103[r brace] planes parallel to the substrate surface. Precipitates belonging to Y[sub 2]O[sub 3] are densely distributed on the film surface. No such second phases have been identified inside the YBCO films. The orientational relationship between precipitates and film is such that the lattice mismatch is minimized in the interface planes. A large number of precipitates grow from the film surface outwards. This phenomenon can be explained on the basis of lattice matching arguments and favorable growth kinetics. (orig.)

  6. Specific Effects of Oxygen Molecule and Plasma on Thin-Film Growth of Y-Ba-Cu-O and Bi-Sr-(Ca)-Cu-O Systems

    Science.gov (United States)

    Endo, Tamio; Horie, Munehiro; Hirate, Naoki; Itoh, Katsutoshi; Yamada, Satoshi; Tada, Masaki; Itoh, Ken-ichi; Sugiyama, Morihiro; Sano, Shinji; Watabe, Kinji

    1998-07-01

    Thin films of a-oriented YBa2Cu3Ox (YBCO), Ca-doped c-oriented Bi2(Sr,Ca)2CuOx and nondoped c-oriented Bi2Sr2CuOx (Bi2201) were prepared at low temperatures by ion beam sputtering with supply of oxygen molecules or plasma. The plasma enhances crystal growth of the a-YBCO and Ca-doped Bi2201 phases. This can be interpreted in terms of their higher surface energies. The growth and quality of nondoped Bi2201 are improved with the supply of oxygen molecules. This particular result could be interpreted by the collision process between the oxygen molecules and the sputtered particles.

  7. Superconducting oxide thin films by ion beam sputtering

    International Nuclear Information System (INIS)

    Kobrin, P.H.; DeNatale, J.F.; Housley, R.M.; Flintoff, J.F.; Harker, A.B.

    1987-01-01

    Superconducting thin films of ternary copper oxides from the Y-Ba-Cu-O and La-Sr-Cu-O systems have been deposited by ion beam sputtering of ceramic targets. Crystallographic orientation of the polycrystalline films has been shown to vary with substrate identity, deposition temperature and annealing temperature. The onset of the superconductive transition occurs near 90K in the Y-Ba-Cu-O system. Fe impurities of < 0.2% have been found to inhibit the superconducting transition, probably by migrating to the grain boundaries

  8. Dielectric relaxations in non-metallic materials related to Y-Ba-Cu-O superconductors

    Energy Technology Data Exchange (ETDEWEB)

    Bennani, H.; Pilet, J.C. (Lab. Instrumentation, Rennes-1 Univ., 35 (France)); Guilloux-Viry, M.; Perrin, C.; Perrin, A.; Sergent, M. (Lab. de Chimie Minerale B, C.N.R.S., 35 - Rennes (France))

    1990-10-15

    In relation with high Tc superconducting material studies, dielectric measurements have been carried out, in the frequency range 10 Hz - 100 kHz, on two powdered compounds belonging to the Y-Ba-Cu-O system. The non-metallic tetragonal phases YBa{sub 2}Cu{sub 3}O{sub 6+x} exhibit dielectric relaxations: for the studied samples (x<0.4) the activation energy U is observed in the range 0.5superconducting thin films for high frequency applications. (orig.).

  9. Controlled levitation of Y-Ba-Cu-O bulk superconductors and energy minimum analysis; Y-Ba-Cu-O baruku chodendotai no fujo to enerugi kaiseki

    Energy Technology Data Exchange (ETDEWEB)

    Magashima, K. [Railway Technical Research Institute, Tokyo (Japan); Iwasa, Y. [Francis Bitter Magnet Laboratory, Canbridge (United States); Sawa, K. [keio University, Tokyo (Japan); Murakami, M. [Superconductivity research Laboratory, Tokyo (Japan)

    1999-11-25

    The levitation of bulk Y-Ba-Cu-O superconductors can be controlled using a Bi-Sr-Ca-Cu-O (Bi2223) superconducting electromagnet. It was found that stable levitation without tilting could be obtained only when the sample trapped a certain amount of fields, the minimum of which depended on the external field and sample dimensions. We employed a novel analysis method for levitation based on the total energy balance, which is much simpler than the force method and could be applied to understanding general levitation behavior. Numerical analyses thus developed showed that stable levitation of superconductors with large dimensions cen only be achieved when the induced currents can flow with three-dimensional freedom. (author)

  10. Effect of oxygen on the properties of Y-Ba-CuO ceramics

    International Nuclear Information System (INIS)

    Nemoshkalenko, V.V.; Ivanov, M.A.; Klimenko, G.A.

    1988-01-01

    The samples of Y-Ba-CuO ceramics 60x60x60 mm 3 in size were synthesized and investigated with provision for their impurity content, crystallography, superconductive and magnetic properties. The conditions of low temperature thermal treatments, as compared to the sintering ones, are offered that result in degradation of superconductive properties due to partial oxygen removal and their subsequent recovery. The mechanism of copper spin-paramagnetism growth in oxygen-deficient samples is discussed. The intensity of narrow (∼ 3 mrad half-width) component observed in the angular distribution of annihilation photons of partially de-oxygenized sample is found to increase in a constant magnetic field, suggesting the formation of positronium-like states. The intense CuOEH + 2 emission line is shown to be present in the spectra of superconductive samples, while it is absent in the non-superconductive state

  11. Thermochemical investigations into the system Y-Ba-Cu-O

    International Nuclear Information System (INIS)

    Neuschuetz, D.; Zimmermann, E.; Hack, K.; Boudene, A.; Mohammad, A.

    1992-01-01

    For a consistent thermodynamic description of the quaternary system Y-Ba-Cu-O, the binary and ternary subsystems must be known. The metallic binaries and the ternary system Y-Ba-Cu have been evaluated by the authors. Discrepancies within the Cu-O system made a thorough experimental re-investigation necessary, leading to a new consistent thermodynamic data set for copper-oxygen which can now serve as a basis for the description of phase equilibria of all high temperature superconductors. Extensive experimental work on the ternaries Y-Cu-O and Ba-Cu-O, which are oxygen partial pressure dependent, revealed liquid phases down to 790degC. The ternary Y-Ba-O could be described more easily on the basis of literature values and present experimental results, because it does not contain any liquid phases at relevant temperatures. The representation of the quaternary Y-Ba-Cu-O is complicated both by its dependence on the oxygen potential and the existence of liquid oxide phases. In contrast to common practice, the present investigations had to start from Cu-free Ba-Y-O in order to avoid unknown liquid phases in the experiments. The present results being insufficient for a complete description of the quaternary system, the work is being continued within an EC joint research project. (orig.) With 84 refs., 8 tabs., 47 figs [de

  12. Effect of iron doping on Y-Ba-Cu-O

    International Nuclear Information System (INIS)

    Abd Halim Shaari; Mansor Hashim; Sidek Hj Abd Aziz; Laily Rafiah Abdullah

    1991-01-01

    Study on the effect of iron doping at different values of doping percentage (0.00< x<0.06) and hence the influence of magnetic iron on Y-Ba-Cu-O superconductor has been carried out. The conventional technique of sintering is used in preparing the ceramic materials. The crystal structure and their lattice parameters are determined from X-ray diffraction measurements. Observation on the dependence of resistance on temperature is made between room temperature to the boiling point of liquid nitrogen, using four-probe techniques. Magnetisation properties namely the Meissner Effect is also observed by levitating a small piece of permanent magnet on the cooled sample. The X-ray diffraction data show that the phase transitions have been observed; from orthorhombic to tetragonal when the iron doping exceeded ∼0.02. Transition temperature, Tc decrease from ∼87.7K to ∼83K. Meissner Effect is observed for sample doped up to 2% only

  13. I-V curves of Y-Ba-Cu-O microbridges in the flux flow regime

    International Nuclear Information System (INIS)

    Kalisky, B.; Wolfus, Y.; Yeshurun, Y.; Koren, G.; Huebener, R.P.

    2004-01-01

    We report on measurements of I-V curves in microbridges of thin Y-Ba-Cu-O films of different thickness, in the presence of external magnetic fields up to 6 T. A discontinuity is observed at a critical voltage, V*, in the flux flow regime, reflecting an electronic instability, as predicted by Larkin and Ovchinnikov (LO), and in agreement with results reported by Doettinger et al. [Phys. Rev. Let. 73 (1994) 1691]. The critical voltage, V*, and the flux flow resistance, R 0 , in the limit V→0, are calculated by fitting the data to the LO model. We find that the vortex critical velocity, v*, at the instability, derived from V*, decreases with magnetic field and film thickness. These results, not predicted by the LO theory, reflect the dependence of the (spatially averaged) quasiparticle energy relaxation rate on magnetic field and film thickness

  14. Point-contact electron tunneling into the high-Tc superconductor Y-Ba-Cu-O

    Science.gov (United States)

    Kirk, M. D.; Smith, D. P. E.; Mitzi, D. B.; Sun, J. Z.; Webb, D. J.

    1987-06-01

    Results are reported from a study of electron tunneling into bulk samples of the new high-Tc superconductor Y-Ba-Cu-O using point-contact tunneling. Based on a superconductive tunneling interpretation, the results show exceptionally large energy gaps in these materials (roughly 2Delta = 100 MeV), implying 2Delta/kBTc = about 13. Similar values were found for La-Sr-Cu-O. The structure in the I-V curves is also similar to that seen in La-Sr-Cu-O. From the asymmetries observed in the I-V characteristics, it is inferred that the natural tunneling barrier on this material is of the Schottky type.

  15. Strongly enhanced vortex pinning from 4 to 77 K in magnetic fields up to 31 T in 15 mol.% Zr-added (Gd, Y)-Ba-Cu-O superconducting tapes

    OpenAIRE

    A. Xu; L. Delgado; N. Khatri; Y. Liu; V. Selvamanickam; D. Abraimov; J. Jaroszynski; F. Kametani; D. C. Larbalestier

    2014-01-01

    Applications of REBCO coated conductors are now being developed for a very wide range of temperatures and magnetic fields and it is not yet clear whether vortex pinning strategies aimed for high temperature, low field operation are equally valid at lower temperatures and higher fields. A detailed characterization of the superconducting properties of a 15 mol. % Zr-added REBCO thin film made by metal organic chemical vapor deposition, from 4.2 to 77 K under magnetic fields up to 31 T is presen...

  16. Strongly enhanced vortex pinning from 4 to 77 K in magnetic fields up to 31 T in 15 mol.% Zr-added (Gd, Y)-Ba-Cu-O superconducting tapes

    Energy Technology Data Exchange (ETDEWEB)

    Xu, A; Delgado, L; Khatri, N; Liu, Y; Selvamanickam, V; Abraimov, D; Jaroszynski, J; Kametani, F; Larbalestier, DC

    2014-04-01

    Applications of REBCO coated conductors are now being developed for a very wide range of temperatures and magnetic fields and it is not yet clear whether vortex pinning strategies aimed for high temperature, low field operation are equally valid at lower temperatures and higher fields. A detailed characterization of the superconducting properties of a 15 mol.% Zr-added REBCO thin film made by metal organic chemical vapor deposition, from 4.2 to 77 K under magnetic fields up to 31 T is presented in this article. Even at a such high level of Zr addition, T-c depression has been avoided (T-c = 91 K), while at the same time an exceptionally high irreversibility field H-irr approximate to 14.8 T at 77 K and a remarkably high vortex pinning force density F-p approximate to 1.7 TN/m(3) at 4.2 K have been achieved. We ascribe the excellent pinning performance at high temperatures to the high density (equivalent vortex matching field similar to 7 T) of self-assembled BZO nanorods, while the low temperature pinning force is enhanced by large additional pinning which we ascribe to strain-induced point defects induced in the REBCO matrix by the BZO nanorods. Our results suggest even more room for further performance enhancement of commercial REBCO coated conductors and point the way to REBCO coil applications at liquid nitrogen temperatures since the critical current density J(c)(H//c) characteristic at 77 K are now almost identical to those of fully optimized Nb-Ti at 4 K. (C) 2014 Author(s).

  17. Strongly enhanced vortex pinning from 4 to 77 K in magnetic fields up to 31 T in 15 mol.% Zr-added (Gd, Y-Ba-Cu-O superconducting tapes

    Directory of Open Access Journals (Sweden)

    A. Xu

    2014-04-01

    Full Text Available Applications of REBCO coated conductors are now being developed for a very wide range of temperatures and magnetic fields and it is not yet clear whether vortex pinning strategies aimed for high temperature, low field operation are equally valid at lower temperatures and higher fields. A detailed characterization of the superconducting properties of a 15 mol. % Zr-added REBCO thin film made by metal organic chemical vapor deposition, from 4.2 to 77 K under magnetic fields up to 31 T is presented in this article. Even at a such high level of Zr addition, Tc depression has been avoided (Tc = 91 K, while at the same time an exceptionally high irreversibility field Hirr ≈ 14.8 T at 77 K and a remarkably high vortex pinning force density Fp ≈ 1.7 TN/m3 at 4.2 K have been achieved. We ascribe the excellent pinning performance at high temperatures to the high density (equivalent vortex matching field ∼7 T of self-assembled BZO nanorods, while the low temperature pinning force is enhanced by large additional pinning which we ascribe to strain-induced point defects induced in the REBCO matrix by the BZO nanorods. Our results suggest even more room for further performance enhancement of commercial REBCO coated conductors and point the way to REBCO coil applications at liquid nitrogen temperatures since the critical current density Jc(H//c characteristic at 77 K are now almost identical to those of fully optimized Nb-Ti at 4 K.

  18. Characterization of the microwave properties of superconducting films with high transition temperature

    International Nuclear Information System (INIS)

    Richter, W.; Klinger, M.; Daginnus, M.

    1989-01-01

    In the meantime high quality Y-Ba-Cu-O thin films were produced. The latest results show, that its surface resistances are clearly lower than the values of copper, measured at a temperature of 77 K and up to frequencies of 86 GHz. This examination had the aim to produce high-T c films with a simple and low cost method, to use them as transmission lines at frequencies up to 30 GHz and above. A screen printing process was investigated, and high-T c thick films were fabricated on several substrates. Superconducting transition temperatures up to 80 K (dc zero resistance) were obtained. The films showed no complete magnetic shielding, and its microwave surface resistances were clearly higher than that ones for copper. The a. c. Josephson effect was proved with granular structures of bulk Y-Ba-Cu-O material and with screen printed thick films. Because of its high surface resistances, these thick films are unsuitable for the use as transmission lines at high frequencies. However, the a.c. Josephson effect can be used to manufacture microwave sensors in bulk Y-Ba-Cu-O and screen printed films of Y-Ba-Cu-O, which have a favourable geometric structure. (orig.) With 16 refs., 2 tabs., 24 figs [de

  19. Superconducting materials at temperature higher than liquid nitrogen of the YBaCuO type. Materiaux supraconducteurs jusqu'a des temperatures superieures a celles de l'azote liquide, appartenant au systeme Y-Ba-Cu-O

    Energy Technology Data Exchange (ETDEWEB)

    Gupta, R; Gegnier, P; Truchot, P

    1990-02-09

    The invention concerns new superconducting materials with the formula Zr{sub x} Hf{sub y} Ti{sub z} Y{sub 1-x-y-z} Ba{sub 2}Cu{sub 3}O{sub 7-{delta}} where 0

  20. Temperature dependence of the magnetic anisotropy of metallic Y-Ba-Cu-O single crystals in the normal phase

    International Nuclear Information System (INIS)

    Miljak, M.; Zlatic, V.; Kos, I.; Aviani, I.; Hamzic, A.; Collin, G.

    1990-01-01

    The magnetic anisotropy measurements of metallic Y-Ba-Cu-O compounds in the normal phase reveal a temperature-dependent diamagnetic component of the susceptibility that increases with decreasing temperature. The temperature variation of the susceptibility anisotropy and its total change do not seem to be much affected by the presence of the superconductivity at some lower temperature and could not be accounted for by superconducting fluctuations. Rather, the data remind one of the behavior of some quasi-two-dimensional metals with anisotropic Fermi surfaces, reflecting the properties of the low-energy excitations in the normal phase. The anisotropy measurements above the bulk superconducting transition temperature T c reveal the nonlinear effects, which are due to the onset of superconductivity in disconnected grains. The existence of a two-step transition, typical for granular superconductors, should be taken into consideration if the normal-phase susceptibility data are compared with the theoretical predictions in the vicinity of T c

  1. Reversible axial-strain effect in Y-Ba-Cu-O coated conductors

    Energy Technology Data Exchange (ETDEWEB)

    Cheggour, N [National Institute of Standards and Technology, Boulder, CO 80305 (United States); Ekin, J W [National Institute of Standards and Technology, Boulder, CO 80305 (United States); Thieme, C L H [American Superconductor Corporation, Westborough, MA 01581 (United States); Xie, Y-Y [SuperPower Incorporated, Schenectady, NY 12304 (United States); Selvamanickam, V [SuperPower Incorporated, Schenectady, NY 12304 (United States); Feenstra, R [Oak Ridge National Laboratory, Oak Ridge, TN 37831 (United States)

    2005-12-15

    The recently discovered reversible strain effect in Y-Ba-Cu-O (YBCO) coated conductors contrasts with the general understanding that the effect of strain on the critical-current density J{sub c} in practical high-temperature superconductors is determined only by crack formation in the ceramic component. Instead of having a constant J{sub c} as a function of strain before an irreversible drop when cracks form in the superconductor, J{sub c} in YBCO coated conductors can decrease or increase reversibly with strain over a significant strain range up to an irreversible strain limit. This reversible effect is present in samples fabricated either with rolling-assisted biaxially textured Ni-W substrates or with ion-beam-assisted deposition on Hastalloy substrates. The reversibility of J{sub c} with strain is observed for thin as well as thick YBCO films, and at two very different temperatures (76 and 4 K). The reversible effect is dependent on temperature and magnetic field, thus indicating its intrinsic nature. We also report an enhancement of the irreversible strain limit {epsilon}{sub irr} where the reversible strain effect ends and YBCO cracking starts. The value of {epsilon}{sub irr} increases from about 0.4% to more than 0.5% when YBCO coated conductors are fabricated with an additional Cu protection layer.

  2. Reversible axial-strain effect in Y-Ba-Cu-O coated conductors

    International Nuclear Information System (INIS)

    Cheggour, N; Ekin, J W; Thieme, C L H; Xie, Y-Y; Selvamanickam, V; Feenstra, R

    2005-01-01

    The recently discovered reversible strain effect in Y-Ba-Cu-O (YBCO) coated conductors contrasts with the general understanding that the effect of strain on the critical-current density J c in practical high-temperature superconductors is determined only by crack formation in the ceramic component. Instead of having a constant J c as a function of strain before an irreversible drop when cracks form in the superconductor, J c in YBCO coated conductors can decrease or increase reversibly with strain over a significant strain range up to an irreversible strain limit. This reversible effect is present in samples fabricated either with rolling-assisted biaxially textured Ni-W substrates or with ion-beam-assisted deposition on Hastalloy substrates. The reversibility of J c with strain is observed for thin as well as thick YBCO films, and at two very different temperatures (76 and 4 K). The reversible effect is dependent on temperature and magnetic field, thus indicating its intrinsic nature. We also report an enhancement of the irreversible strain limit ε irr where the reversible strain effect ends and YBCO cracking starts. The value of ε irr increases from about 0.4% to more than 0.5% when YBCO coated conductors are fabricated with an additional Cu protection layer

  3. Magnetic levitation and stiffness in melt-textured Y-Ba-Cu-O

    International Nuclear Information System (INIS)

    Hull, J.R.; Mulcahy, T.M.; Salama, K.; Selvamanickam, V.; Weinberger, B.R.; Lynds, L.

    1992-01-01

    Magnetic levitation and stiffness have been measured in several systems composed of a permanent magnet elastically suspended above a stationary melt-textured sample of Y-Ba-Cu-O. The levitation force and vertical stiffness have been calculated on the basis of magnetization measurements of the same system, and the calculated results showed excellent agreement with the experimental measurements. Based on the force and magnetization measurements, it is predicted that the same Y-Ba-Cu-O material configured in a geometry suitable for magnetic bearings could produce a levitation pressure of 100--400 kPa at 20 K

  4. Stoichiometric analysis of Y-Ba-Cu-O superconductors using deuterons

    International Nuclear Information System (INIS)

    Tang, S.M.; Ong, T.H.; Tan, M.G.; Loh, K.K.; Sow, C.H.; Yuan, B.; Orlic, I.

    1993-01-01

    In principle, deuteron irradiation can be used for a complete stoichiometric analysis of Y-Ba-Cu-O superconductors. The contents of all the four chemical constituents can be determined by simultaneous detection of the 0.871 MeV prompt gamma rays from the 16 O(d, pγ) 17 O * reaction and of the characteristic X-rays produced by DIXE (deuteron induced X-ray emission). In this paper we present the approach taken and the results obtained in exploring the applicability of this technique for accurate quantitative determinations of the chemical constituents of bulk Y-Ba-Cu-O superconductors. (orig.)

  5. Josephson magnetization of Y--Ba--Cu--O superconductors near the critical temperature

    International Nuclear Information System (INIS)

    Ivanchenko, Y.M.; Lisyansky, A.A.; Tsindlekht, M.I.

    1991-01-01

    Experimental and theoretical data for the rectifying properties in a ceramic Y--Ba--Cu--O cylindrical sample are presented. A sample is subjected to the influence of a very small perturbation just to have the linear rectifying regime. Theoretical analysis using the Josephson medium concept gives qualitative agreement with the observed experimental results

  6. Point-contact electron tunneling into the high-T/sub c/ superconductor Y-Ba-Cu-O

    International Nuclear Information System (INIS)

    Kirk, M.D.; Smith, D.P.E.; Mitzi, D.B.

    1987-01-01

    We report results of a study of electron tunneling into bulk samples of the new high-T/sub c/ superconductor Y-Ba-Cu-O using point-contact tunneling. Based on a superconductive tunneling interpretation, the results show exceptionally large energy gaps in these materials (roughly 2Δ = 100 meV), implying 2Δ/k/sub C/T/sub c/--13. Similar values were found previously by us for La-Sr-Cu-O. We also see Structure in the I-V curves similar to that seen in La-Sr-Cu-O. On the basis of the asymmetries observed in the I-V characteristics, we believe that the natural tunneling barrier on this material is of the Schottky type

  7. Flux motion in Y-Ba-Cu-O bulk superconductors during pulse field magnetization

    International Nuclear Information System (INIS)

    Yoshizawa, K; Nariki, S; Sakai, N; Murakami, M; Hirabayasi, I; Takizawa, T

    2004-01-01

    We have studied the relationship between the magnetization and temperature change in Y-Ba-Cu-O bulk superconductor during pulse field magnetization (PFM). The flux motion was monitored using both Hall sensors and pick-up coils that are placed on a surface of a Y-Ba-Cu-O disc having dimensions of 15 mm in diameter and 0.95 mm in thickness. The peak value of the field was varied from 0.2 to 0.8 T. The effect of the static bias field was also studied in the range of 0-3 T. The temperature of the sample surface was measured using a resistance temperature sensor. The temperature increased with the magnitude of the applied pulsed magnetic field, and the amount of temperature rise decreased with increasing static bias field

  8. Investigation into Y-Ba-Cu-O samples by neutron scattering methods and other particles

    International Nuclear Information System (INIS)

    Lebedev, V.T.; Evmenenko, G.A.; Sibilev, A.I.; Lebedev, V.M.; Churin, S.A.

    1997-01-01

    The combination of surface-sensitive microanalysis and neutron small angle diffraction analysis as applied to a Y-Ba-Cu-O ceramic rod permits determining the composition by oxygen and heavy elements. The determination of chemical composition was accomplished as in initial ceramics so in a crystal and in transition areas. The ceramic region of the sample is shown to be nonuniform and to have a well developed granular surface [ru

  9. Preparation and characterization of Y-BA-CU-O based superconductors of varying stoichiometries

    International Nuclear Information System (INIS)

    Sarmago, R.V.

    1989-01-01

    Variations on the Y-Ba-Cu-O system were done for each element. The X-ray diffraction pattern of each variation were studied and compared. Resistance measurements for the Y=1.2 and 1.4 samples showed a complete disappearance of electrical resistance at 88K. Infrared spectrum for the different variations showed a growth or disappearance of an absorption peak near 1460 cm -1 depending on the concentration. (Auth.). 7 refs.; 12 figs.; 2 tabs

  10. High critical currents in Y-Ba-Cu-O superconductors

    International Nuclear Information System (INIS)

    Jin, S.; Tiefel, T.H.; Sherwood, R.C.; Davis, M.E.; van Dover, R.B.; Kammlott, G.W.; Fastnacht, R.A.; Keith, H.D.

    1988-01-01

    Melt-textured growth of polycrystalline YBa 2 Cu 3 O 7 √/sub δ/ superconductor using directional solidification created an essentially 100% dense structure consisting of long, needle- or plate-shaped crystals preferentially aligned parallel to the a-b conduction plane. The new microstructure, which completely replaces the previous granular and random structure in the sintered precursor, exhibits dramatically improved transport J/sub c/ values at 77 K of ∼17 000 Acm 2 in zero field and ∼4000 Acm 2 at H = 1 T (as compared to ∼500 and ∼1 Acm 2 , respectively, for the as-sintered structure), with the severe field dependence of J/sub c/ (''weak-link'' problem) no longer evident in the new melt-textured material. The improvement in J/sub c/ is attributed to the combined effects of densification, alignment of crystals, and formation of cleaner grain boundaries. Microstructure and distribution of various phases present in the melt-textured material are discussed in relation to the superconducting properties

  11. Development of Y-Ba-Cu-O Superconductors for Magnetic Bearings

    Science.gov (United States)

    Selvamanickam, V.; Pfaffenbach, K.; Sokolowski, R. S.; Zhang, Y.; Salama, K.

    1996-01-01

    The material requirements, material manufacturing and magnetic properties that are relevant to fabrication of High Temperature Superconductor (HTS) magnetic bearings have been discussed. It is found that the seeded-melt-texturing method can be used to fabricate the single domain material that is required to achieve the best magnetic properties. Trapped-field mapping has been used as a non-destructive tool to determine the single-domain nature of the HTS material and quantity of the HTS disks. Both the trapped field and the levitation force of the Y-Ba-Cu-O disks are found to be strongly sensitive to the oxygen content.

  12. Synthesis, rheology and forming of Y-Ba-Cu-O ceramics

    International Nuclear Information System (INIS)

    Green, T.M.

    1993-07-01

    A chemical synthesis route is discussed which results in a low- temperature precursor to Y-Ba-Cu-O ceramics; it is based on use of molten Ba(OH) 2 ·8H 2 O flux. Two different chemical systems have been examined; the first one, based on nitrate salts, has been demonstrated to be a viable precursor material for tape casting and extrusion; the second, made from acetate salts, has been used for powder synthesis and extrusion. Rheology of pastes shows that their flow may be fit to either Bingham Plastic or Hershel- Bulkley models. Yield stress is controlled in both pastes by volume fraction solids. Viscosity also follows solids loading in the paste. Shear thinning is controlled by colloidal nature of precursor. The paste has colloidal microstructure. Comparison of concentric cylinder rheometry and piston extrusion rheometry shows order of magnitude differences in yield stress, resulting from the test method and paste dilation

  13. Formation of layered microstructure in the Y-Ba-Cu-O and Bi-Sr-Ca-Cu-O superconductors

    International Nuclear Information System (INIS)

    Jin, S.; Kammlott, G.W.; Tiefel, T.H.; Chen, S.K.

    1992-01-01

    The layered grain microstructure is essential for overcoming the weak link problem and ensuring high transport critical currents in the cuprate superconductors. In this paper we discuss the processing and the mechanisms for layer information in Y-Ba-Cu-O and Bi-Sr-Ca-Cu-O. In melt-processed Y-Ba-Cu-O, sympathetic nucleation on previously nucleated YBa 2 Cu 3 O 7-δ plates during solidification appears to be dominant mechanism for the formation of parallel plate-shaped grains. In the Y-Ba-Cu-O and Bi-Sr-Ca-Cu-O ribbons, the interface reaction between the superconductor layer and the silvers substrate seems to be the main mechanism for the c-axis texturing of the layered grains. The drastically different critical current behavior in the c-axis textured Y-Ba-Cu-O and Bi-Sr-Ca-Cu-O ribbons is discussed in terms of possible differences in the nature of the twist and tilt grain boundaries. (orig.)

  14. Thermochemical measurements and assessment of the phase diagrams in the system Y-Ba-Cu-O

    International Nuclear Information System (INIS)

    Boudene, A.; Mohammad, A.

    1996-01-01

    The aim of this project was to provide a self-consistent set of Gibbs energy data for all phases in the system Y-Ba-Cu-O. Experimental thermochemical investigations by differential thermal analysis (DTA), thermogravimetry (TG), electromotive force measurements (EMF), oxygen coulometric titration (OCT), drop and solution calorimetry, and conventional phase analysis (annealing, quenching, and X-ray diffraction [XRD]) as well as ab initio calculations of interaction energies for the 123 phase have been carried out. The experimental information (phase equilibria, heat capacity, enthalpies of formation, oxygen partial pressures, and so forth) has been used in computer-based assessments of the Gibbs energies. These data have been employed to generate phase diagrams by way of equilibrium computations. All binary and ternary subsystems have been fully assessed. For the quaternary system a dataset covering the subsolidus range has been derived. Applications of the data to practical questions, such as the production of 123 superconductors by an MOCVD process, the producibility of metallic precursors, and the oxidation of a copper-enriched stoichiometric oxide precursor, are demonstrated

  15. Effect of Barium-Precursors on Reaction Kinetics in Y-Ba-Cu-O System

    Institute of Scientific and Technical Information of China (English)

    2001-01-01

    The reactions of stoichiometric Y2O3, CuO, and different Ba salts or oxides (BaCO3, Ba(NO3)2, BaO2, BaCuO2) for forming various compounds in the Y-Ba-Cu-O system (i.e., YBa2Cu3O7-δ, BaCuO2, Y2BaCuO5 and Y2Cu2O5) were systematically investigated by thermal analysis and X-ray diffractometry. The relevant activation energies were calculated from thermogravimetric data. It is found that the reaction pathway significantly depends on the thermal stability of the Ba precursors. Binary BaO-CuO phases form at low temperature (650~700 ℃) when in presence of easy-to-decompose Ba precursors, and then slowly transform to ternary compounds. On the contrary, when Ba ions are released at temperature higher than 900 ℃, ternary phases form directly from the components.

  16. Enhanced and uniform in-field performance in long (Gd, Y)-Ba-Cu-O tapes with zirconium doping fabricated by metal-organic chemical vapor deposition

    International Nuclear Information System (INIS)

    Selvamanickam, V; Guevara, A; Zhang, Y; Kesgin, I; Xie, Y; Carota, G; Chen, Y; Dackow, J; Zhang, Y; Zuev, Y; Cantoni, C; Goyal, A; Coulter, J; Civale, L

    2010-01-01

    The influence of Zr doping in (Gd, Y)-Ba-Cu-O ((Gd, Y)BCO) tapes made by metal-organic chemical vapor deposition has been studied with a specific objective of uniform and reproducible enhancement in in-field critical current (I c ) over long lengths. 50 m long tapes with 7.5 and 10 at.% Zr doping in 1 μm thick (Gd, Y)BCO films have been found to exhibit a sharply enhanced peak in I c in the orientation of field parallel to the c-axis and retain 28% of their self-field I c value at 77 K and 1 T. BaZrO 3 (BZO) nanocolumn density in the cross-sectional microstructure was found to increase with increasing Zr addition. The end segments of the 50 m long tapes were found to display nearly identical angular dependence of critical current at 77 K and 1 T, indicative of the uniformity in in-field performance over this length. A 610 m long tape was fabricated with 10% Zr doping and a 130 m segment showed a 3.2% uniformity in critical current measured every meter in the orientation of B || c-axis. A retention factor of 36% of the zero-field I c value measured at 0.52 T over the 130 m is consistent with that obtained in short samples.

  17. Enhanced and uniform in-field performance in long (Gd, Y)-Ba-Cu-O tapes with zirconium doping fabricated by metal-organic chemical vapor deposition

    Energy Technology Data Exchange (ETDEWEB)

    Selvamanickam, V; Guevara, A; Zhang, Y; Kesgin, I [Texas Center for Superconductivity and Department of Mechanical Engineering, University of Houston, Houston, TX 77059 (United States); Xie, Y; Carota, G; Chen, Y; Dackow, J [SuperPower Incorporated, 450 Duane Avenue Schenectady, NY 12304 (United States); Zhang, Y; Zuev, Y; Cantoni, C; Goyal, A [Oak Ridge National Laboratory, Oak Ridge, TN 37831 (United States); Coulter, J; Civale, L [Los Alamos National Laboratory, Los Alamos, NM 87545 (United States)

    2010-01-15

    The influence of Zr doping in (Gd, Y)-Ba-Cu-O ((Gd, Y)BCO) tapes made by metal-organic chemical vapor deposition has been studied with a specific objective of uniform and reproducible enhancement in in-field critical current (I{sub c}) over long lengths. 50 m long tapes with 7.5 and 10 at.% Zr doping in 1 {mu}m thick (Gd, Y)BCO films have been found to exhibit a sharply enhanced peak in I{sub c} in the orientation of field parallel to the c-axis and retain 28% of their self-field I{sub c} value at 77 K and 1 T. BaZrO{sub 3} (BZO) nanocolumn density in the cross-sectional microstructure was found to increase with increasing Zr addition. The end segments of the 50 m long tapes were found to display nearly identical angular dependence of critical current at 77 K and 1 T, indicative of the uniformity in in-field performance over this length. A 610 m long tape was fabricated with 10% Zr doping and a 130 m segment showed a 3.2% uniformity in critical current measured every meter in the orientation of B || c-axis. A retention factor of 36% of the zero-field I{sub c} value measured at 0.52 T over the 130 m is consistent with that obtained in short samples.

  18. Enhanced and Uniform in-Field Performance in Long (Gd,Y)-Ba-Cu-O Tapes with Zirconium Doping Fabricated by Metal Organic Chemical Vapor Deposition

    Energy Technology Data Exchange (ETDEWEB)

    Selvamanickam, V. [SuperPower Incorporated, Schenectady, New York; Guevara, A. [University of Houston, Houston; Zhang, Y. [University of Houston, Houston; Kesign, I. [University of Houston, Houston; Xie, Y. Y. [SuperPower Incorporated, Schenectady, New York; Carota, G. [SuperPower Incorporated, Schenectady, New York; Chen, Y. [SuperPower Incorporated, Schenectady, New York; Dackow, J. [SuperPower Incorporated, Schenectady, New York; Zhang, Yifei [ORNL; Zuev, Yuri L [ORNL; Cantoni, Claudia [ORNL; Goyal, Amit [ORNL; Coulter, J. [Los Alamos National Laboratory (LANL); Civale, L. [Los Alamos National Laboratory (LANL)

    2010-01-01

    The influence of Zr doping in (Gd, Y)-Ba-Cu-O ((Gd, Y)BCO) tapes made by metal-organic chemical vapor deposition has been studied with a specific objective of uniform and reproducible enhancement in in-field critical current (I{sub c}) over long lengths. 50 m long tapes with 7.5 and 10 at.% Zr doping in 1 {mu}m thick (Gd, Y)BCO films have been found to exhibit a sharply enhanced peak in I{sub c} in the orientation of field parallel to the c-axis and retain 28% of their self-field I{sub c} value at 77 K and 1 T. BaZrO{sub 3} (BZO) nanocolumn density in the cross-sectional microstructure was found to increase with increasing Zr addition. The end segments of the 50 m long tapes were found to display nearly identical angular dependence of critical current at 77 K and 1 T, indicative of the uniformity in in-field performance over this length. A 610 m long tape was fabricated with 10% Zr doping and a 130 m segment showed a 3.2% uniformity in critical current measured every meter in the orientation of {beta} {parallel} c-axis. A retention factor of 36% of the zero-field I{sub c} value measured at 0.52 T over the 130 m is consistent with that obtained in short samples.

  19. Comparative analysis of the physical properties of Y-Ba-Cu-O when substituting Ce and Nd in place of Y

    International Nuclear Information System (INIS)

    Lee, Jong Rok; Jhung, Byung Doo; Woo, Chang Woong

    1996-01-01

    The physical properties of the superconductors Y 1-x Ce x Ba 2 Cu 3 O 7-y and Y 1-x Nd x Ba 2 Cu 3 O 7-y made by the solid-state reaction method were carefully examined after substituting Ce and Nd (x=0.03, x=0.07) in place of Y in high-temperature superconducting Y-Ba-Cu-O oxides. X-ray diffraction patterns confirmed that all samples had orthorhombic structures. However, the transition temperature turn Tc was 83 K for x=0.03 in sample 1, 84 K for x=0.07 in sample 1 and 88 K for both x=0.03 and x=0.07 in sample 2. (author) An emissive probe was designed and manufactured to measure the floating and the space potentials of a plasma in the wake region. The 'floating potential method', among various schemes, was used for the measurement and analysis. To generate the wake, a plane artificial satellite with a circular shape was introduced into a simply discharged argon plasma without a magnetic field. Potentials along the radial direction in and out of the wake region of the artificial satellite were measured, and the plasma parameters were compared in both regions. In the wake region, the floating potential was higher than that out of the wake; the space potential was approximately equal to that out of the wake; when a positive voltage was applied to the artificial satellite, the floating and the space potentials were lower than those out of the wake; and when a negative voltage was applied to the artificial satellite, the floating potential was higher and the space potential was lower than the corresponding potentials out of the wake. (author)

  20. Factors influencing the critical current of Y-Ba-Cu-O superconductor

    International Nuclear Information System (INIS)

    Shi Kexin; Ding Shiying; Yu Zheng; Yan Jialie; Gao Peng

    1990-01-01

    Effects of doping V on the superconducting oxide YBa 2 Cu 3-x V x O y have been studied. It was found that when x≤0.6, there is a decrease, in the superconducting phase ratio of volume to the size of grain and an increase in J c , mass density and hardness of the samples, whereas the sample synthesis conditions, critical temperature T c and superconducting phase structure are not sensitive to the x values. These suggest that the impurity V stays mainly on the grain boundaries and can improve the connection between the grains considerably. In certain cases, it is more important to improve the grain connection than to increase the superconducting phase ratio

  1. ESR, SIMS and TEMF of an Y-Ba-Cu-O superconductor

    Science.gov (United States)

    Kirschner, I.; Giber, J.; Halasz, I.

    1995-01-01

    Superconducting transition comes into being between 92 K and 82 K in the samples having a Meissner's state value of 68 vol. percent. The main material content has an orthorhombic unit cell of Y1Ba2Cu408 accompanied by low quantity CuO and a sporadic phase. A proof of anisotropic superconductivity, an unusually high Cu ion concentration and a temperature dependent transition of charge carriers have been observed.

  2. On characteristic voltage of the high Tc superconductor. [Y-Ba-Cu-O

    Energy Technology Data Exchange (ETDEWEB)

    Vasiliev, B V; Uchaikin, S V [Joint Inst. for Nuclear Research, Low Temperature Physics Dept., Dubna (USSR)

    1991-12-01

    The critical currents and normal resistances of the small bridges from yttrium-based high-Tc superconducting ceramics have been measured. The characteristic voltage of these bridges was found to be approximately 20{mu}V. This effect can be explained if between the ceramic grains there are contacts of an order of one crystalline cell in size. (orig.).

  3. Structural changes between 100 and 300 K of the high-Tc superconductor Y-Ba-Cu-O studied by positron annihilation

    International Nuclear Information System (INIS)

    Wang, S.J.; Li, X.H.; Chen, Y.L.; Li, S.Q.; Fong, G.H.; Wang, Z.

    1989-01-01

    The structural changes of the high-T c superconductor Y-Ba-Cu-O between 100 and 300 K are studied by positron lifetime and Doppler broadening measurements as a function of temperature. There are anomalous changes in the positron lifetimes and Doppler broadening S-parameters near 130 and 260 K, which is consistent with some reported experimental results. These anomalies may be caused by the lattice instabilities, such as the ordering readjustment of oxygen vacancies. (author)

  4. Experimental studies of effect of high current pulse electron and carbon ion beams on high temperature Y-Ba-Cu-O, Bi-Ca-Sr-Cu-O superconductors

    International Nuclear Information System (INIS)

    Korenev, S.A.; Sikolenko, V.V.; Chernakova, A.

    1989-01-01

    This work shows the results of the experiment on the effect of high current electron and carbon ion pulse beams irradiation on High-T c superconductors Y-Ba-Cu-O and Bi-Ca-Cu-O in vacuum (P∼5x10 -5 torr). The parameters of electron beam used in the experiment were: E∼100-300 keV, j e ∼10-1000 A/cm 2 , τ) p ∼300ns. The parameters of carbon ions used in the experiment were: E∼100-300keV j i ∼1-60A/cm, τ p ∼300ns. Experiments had shown the threshold electron beam power density for surface melting in adiabatic heat condition for Y-Ba-Cu-O ceramics up to P 0 >or approx. 10 7 W/cm 2 , and for Bi-Ca-Sr-Cu-O ceramics up to P 0 ∼4x10 6 W/cm 2 . Increasing of critical current in ∼2 times was observed in samples with a melting surface layer. The integral resistance of Y-Ba-Cu-O and Bi-Ca-Sr-Cu-O decreased in ∼2-2.5 times for electron beam irradiated samples and in ∼1.25-1.8 times for ion irradiated samples. Amorphization did not take place and stoichiometry remained after such irradiation. 6 refs.; 2 figs.; 1 tab

  5. investigation of Y-Ba-Cu-O type superconductors in pulsed ultrahigh magnetic fields

    International Nuclear Information System (INIS)

    Pavlovskii, A.I.; Tatsenko, O.M.; Platonov, V.V.; Voronov, S.A.; Kolokolchikov, N.P.; Markevtsev, I.M.; Deryugin, Y.N.; Druzhinin, V.V.; Shcherbak, Y.P.

    1990-01-01

    In this paper a possibility of microelectronic technique devices creation based on high-temperature superconductors (HTS) as well as HTS using in heavy-current electronic and, in particular, in electrical energy storage, radio-frequency accelerators and transmission lines, superconducting solenoids is considered. Critical current I c and upper critical magnetic field H c2 are key parameters defining engineering feasibility of HTS. H c2 measurement near the temperature of a superconducting transition doesn't present any difficulties, but extrapolation of H c2 (T) dependence to a low-temperature region owing to thermal activation processes gives uncertainties in H c2 (OK) value equal to 150-300 T. Prediction of H c2 (OK) values from H c1 data hindered, since the first critical field is greatly defined by the samples inhomogeneous macrostructure. It has been shown that H c2 (4.2 K) > 60 T, this is a threshold magnetic field obtained in undestructable pulsed solenoids

  6. Preparation and characterization of Y-Ba-Cu-O-F superconductors

    Energy Technology Data Exchange (ETDEWEB)

    Yokoyama, Yuko; Okumura, Tomoyuki; Sugise, Ryoji; Matsubara, Toshiya; Koshizuka, Naoki; Hirabayashi, Masayuki; Terada, Norio; Ihara, Hideo

    1988-04-01

    Samples were prepared by powder composition method which uses fluoride for annealing and by the method which anneals YBa/sub 2/Cu/sub 3/O/sub x/ in fluorine to elucidate fluorine substitution effects on the superconducting properties of YBa/sub 2/Cu/sub 3/O/sub/x/F/sub/y/. Their structures, magnetic properties and electrical conductivities were investigated. The samples were prepared with the appropriate mixture of BaCO/sub 3/, Y/sub 2/O/sub 3/, CuO, and fluoride such as CuF/sub 2/. Since the samples had strong peaks of BaF/sub 2/ phase together with the perovskite phase in the X-ray diffraction patterns, it was difficult to obtain information on the fluorine substitution effects on the physical properties. Next, the samples were prepared by annealing YBa/sub 2/CuO/sub/x/ sintred pellets and CoF/sub 3/ powder in a sealed quartz tube. In this case, the diffraction patterns showed that the crystalline state of the samples was a single phase of the orthorohombic perovskite structure. The behaviors against the changes in magnetic field and temperature can be considered to be substantially identical. It is hard to consider that the fluorine substitution will play a direct role in attaining higher Tc. (6 figs, 2 refs)

  7. High temperature superconducting films by rf magnetron sputtering

    International Nuclear Information System (INIS)

    Kadin, A.M.; Ballentine, P.H.

    1989-01-01

    The authors have produced sputtered films of Y-Ba-Cu-O and Bi-Sr-Ca-Cu-O by rf magnetron sputtering from an oxide target consisting of loose reacted powder. The use of a large 8-inch stoichiometric target in the magnetron mode permits films located above the central region to be free of negative-ion resputtering effects, and hence yields reproducible, uniform stoichiometric compositions for a wide range of substrate temperatures. Superconducting YBCO films have been obtained either by sputtering at low temperatures followed by an 850 0 C oxygen anneal, or alternatively by depositing onto substrates heated to ∼600 - 650 0 C and cooling in oxygen. Films prepared by the former method on cubic zirconia substrate consist of randomly oriented crystallites with zero resistance above 83 K. Those deposited on zirconia at medium temperatures without the high-temperature anneal contain smooth partially oriented crystallites, with a slightly depressed T/sub c/ ∼75K. Finally, superconducting films have been deposited on MgO using a BiSrCaCu/sub 2/O/sub x/ powder target

  8. Superconductivity applications for infrared and microwave devices; Proceedings of the Meeting, Orlando, FL, Apr. 19, 20, 1990

    Science.gov (United States)

    Bhasin, Kul B.; Heinen, Vernon O.

    1990-10-01

    Various papers on superconductivity applications for IR and microwave devices are presented. The individual topics addressed include: pulsed laser deposition of Tl-Ca-Ba-Cu-O films, patterning of high-Tc superconducting thin films on Si substrates, IR spectra and the energy gap in thin film YBa2Cu3O(7-delta), high-temperature superconducting thin film microwave circuits, novel filter implementation utilizing HTS materials, high-temperature superconductor antenna investigations, high-Tc superconducting IR detectors, high-Tc superconducting IR detectors from Y-Ba-Cu-O thin films, Y-Ba-Cu0-O thin films as high-speed IR detectors, fabrication of a high-Tc superconducting bolometer, transition-edge microbolometer, photoresponse of YBa2Cu3O(7-delta) granular and epitaxial superconducting thin films, fast IR response of YBCO thin films, kinetic inductance effects in high-Tc microstrip circuits at microwave frequencies.

  9. Accurate determination of the composition of Y-Ba-Cu-O superconductor by spectrophotometry, gravimetry and flame AAS

    International Nuclear Information System (INIS)

    Bruneel, E; Verbauwhede, D; Vyver, D Van de; Schaubroeck, J; Hoste, S; Driessche, I Van

    2005-01-01

    A procedure for the accurate analytical determination of yttrium, barium and copper in an YBa 2 Cu 3 O x superconductor is described. After dissolution of the material the concentration of Y and Cu was spectrophotometrically determined as an Y-Arsenazo III and a Cu-Nitroso-R-salt complex, respectively. Ba was determined either gravimetrically as BaCrO 4 , after precipitation using a K 2 CrO 4 solution or using flame atomic absorption spectroscopy (AAS). An accuracy better than 0.7% and a coefficient of variation better then 1.2% are obtained. It is illustrated that this analytical procedure can be used to determine the composition of a bulk superconducting YBa 2 Cu 3 O x sample. For determination of Ba in thin films we suggest the use of flame AAS, with an accuracy of 0.03% and a coefficient of variation of 1.7%

  10. Accurate determination of the composition of Y-Ba-Cu-O superconductor by spectrophotometry, gravimetry and flame AAS

    Energy Technology Data Exchange (ETDEWEB)

    Bruneel, E [Department of Inorganic and Physical Chemistry, Ghent University, Krijgslaan 281(S3), 9000 Ghent (Belgium); Verbauwhede, D [Department of Inorganic and Physical Chemistry, Ghent University, Krijgslaan 281(S3), 9000 Ghent (Belgium); Vyver, D Van de [Department of Inorganic and Physical Chemistry, Ghent University, Krijgslaan 281(S3), 9000 Ghent (Belgium); Schaubroeck, J [Departement Industriele Wetenschappen, Hogeschool Gent, Schoonmeerstraat 52 9000 Ghent (Belgium); Hoste, S [Department of Inorganic and Physical Chemistry, Ghent University, Krijgslaan 281(S3), 9000 Ghent (Belgium); Driessche, I Van [Department of Inorganic and Physical Chemistry, Ghent University, Krijgslaan 281(S3), 9000 Ghent (Belgium)

    2005-06-01

    A procedure for the accurate analytical determination of yttrium, barium and copper in an YBa{sub 2}Cu{sub 3}O{sub x} superconductor is described. After dissolution of the material the concentration of Y and Cu was spectrophotometrically determined as an Y-Arsenazo III and a Cu-Nitroso-R-salt complex, respectively. Ba was determined either gravimetrically as BaCrO{sub 4}, after precipitation using a K{sub 2}CrO{sub 4} solution or using flame atomic absorption spectroscopy (AAS). An accuracy better than 0.7% and a coefficient of variation better then 1.2% are obtained. It is illustrated that this analytical procedure can be used to determine the composition of a bulk superconducting YBa{sub 2}Cu{sub 3}O{sub x} sample. For determination of Ba in thin films we suggest the use of flame AAS, with an accuracy of 0.03% and a coefficient of variation of 1.7%.

  11. Synthesis, structure and properties of novel epoxy and rubber-modified epoxy impregnated Y-Ba-Cu-O superconductors

    International Nuclear Information System (INIS)

    Low, I.M.; Lim, F.W.; Chisholm, W.

    1992-01-01

    This paper reports the synthesis, structure and properties of novel YBa 2 Cu 3 O 6+x (123) - polymer composites. The polymers used were epoxy and rubber-modified epoxy resins. Superconducting composites with good strength, toughness, hardness and chemical resistance have been successfully fabricated. The presence of polymer(s) does not appear to affect the superconducting (T c ) of about 90 K. Levitation experiments show that the height (z) of the levitating magnet depends on sample thickness, and mass and pole strength of the magnet. A simple image force model best describes the observed dependence of z on the mass and pole strength. Atomic absorption and pH measurements in the corrosion study show that the polymer coating provides an impermeable barrier to the ingress of solvents and a concomitant resistance to phase decomposition. 12 refs., 2 tabs., 5 figs

  12. Fabrication and properties of Y-Ba-Cu-O high Tc superconductor by upset-forging method

    International Nuclear Information System (INIS)

    Chang, Ho Jung; Kang, Kae Myung; Song, Jin Tae

    1990-01-01

    YBa 2 Cu 3 O 7-x oxide superconductors was fabricated by sintering process and upset-forging method, respectively, and microstructures and conduction properties were compared. There was no difference in crystal structure the (001) x-ray reflection presumably due to preferred crystal orientation of the YBa 2 Cu 3 O 7-x superconductor. Furthermore, the grain size of the 123-phase increased as the reduction ratio became larger during the upset-forging. The critical temperature for zero resistivity of both samples was almost the same, i.e., about 90K. These results have demonstrated the potential of producing YBa 2 Cu 3 O 7-x superconducting wire or tape effectively using a upset-forging method. The critical current density of the upset-forged sample, however, was lower than that of the sintered one, which fact might be ascribed to microcrack formation during fast upset-forging. (Author)

  13. Oriented grained Y-Ba-Cu-O superconductors having high critical currents and method for producing same

    International Nuclear Information System (INIS)

    Salama, K.; Selvamanickam, V.

    1990-01-01

    This patent describes a process for preparing a superconducting metal oxide complex. It comprises: mixing solid compounds containing Y, Ba, Cu and O in amounts appropriate to yield the formula Y 1 Ba 2 Cu 3 O 6 + δ wherein δ has a number value of from about 0.1 to about 1.0; heating the solid compounds in air to a temperature between about 920 degrees C. to about 960 degrees C. for a time sufficient to react the compounds in the solid state quenching the solid state reaction product to ambient temperature in air; compacting the mixture into a solid mass; sintering the solid mass; heating the solid mass; rapidly cooling the mass to a temperature between about 1,020 degrees to about 1,040 degrees C. and then cooling the mass to a steady temperature between about 20 degrees C. to 40 degrees C. below its melting point at a rate of approximately 1 degrees C./hour; maintaining the mass at the steady temperature for a time sufficient for the entire mass to resolidify; cooling the resolidified mass in air from the steady temperature to approximately 550 degrees C. to 650 degrees C. at the rate of approximately 60 degrees C. per hour; additionally cooling the resolidified mass to about 380 degrees C. to about 420 degrees C. at the rate of approximately 30 degrees C. per hour in air; and annealing the resolidified mass

  14. Broad Temperature Pinning Study of 15 mol.% Zr-Added (Gd, Y)-Ba-Cu-O MOCVD Coated Conductors

    Energy Technology Data Exchange (ETDEWEB)

    Xu, AX; Khatri, N; Liu, YH; Majkic, G; Galstyan, E; Selvamanickam, V; Chen, YM; Lei, CH; Abraimov, D; Hu, XB; Jaroszynski, J; Larbalestier, D

    2015-06-01

    BaZrO3 (BZO) nanocolumns have long been shown to be very effective for raising the pinning force F-p of REBa2Cu3Ox (REBCO, where RE = rare earth) films at high temperatures and recently at low temperatures too. We have successfully incorporated a high density of BZO nanorods into metal organic chemical vapor deposited (MOCVD) REBCO coated conductors via Zr addition. We found that, compared to the 7.5% Zr-added coated conductor, dense BZO nanorod arrays in the 15% Zr-added conductor are effective over the whole temperature range from 77 K down to 4.2 K. We attribute the substantially enhanced J(c) at 30 K to the weak uncorrelated pinning as well as the strong correlated pinning. Meanwhile, by tripling the REBCO layer thickness to similar to 2.8 mu m, the engineering critical current density J(e) at 30 K exceeds J(e) of optimized Nb-Ti wires at 4.2 K.

  15. Superconductivity applications for infrared and microwave devices II; Proceedings of the Meeting, Orlando, FL, Apr. 4, 5, 1991

    Science.gov (United States)

    Heinen, Vernon O.; Bhasin, Kul B.

    Topics discussed include thin-film technology, microwave transmission lines and resonators, microwave devices and circuits, infrared detectors and bolometers, and superconducting junctions. Papers are presented on possible enhancement in bolometric response using free-standing film of YBa2Cu3O(x), aging and surface instability in high-Tc superconductors, epitaxial Tl2Ba2CaCu2O8 thin films on LaAlO3 and their microwave device properties, the performance of stripline resonators using sputtered YBCO films, and a coplanar waveguide microwave filter of YBa2Cu3O7. Attention is also given to the performance characteristics of Y-Ba-Cu-O microwave superconducting detectors, high-Tc bolometer developments for planetary missions, infrared detectors from YBaCuO thin films, high-temperature superconductor junction technology, and submillimeter receiver components using superconducting tunnel junctions. (For individual items see A93-27244 to A93-27248)

  16. Thermochemical properties of oxides in Y-Ba-Cu-O, Sr-Bi-O, Cu-Nb-O, Sr-Cu-O, Ca-Cu-O, Cu-O and Hg-Ba-Ca-Cu-O systems

    International Nuclear Information System (INIS)

    Moiseev, G.K.; Vatolin, N.A.; Il'inykh, N.I.

    2000-01-01

    Thermochemical properties (ΔH 0 298 , S 0 298 , H 0 298 -H 0 0 , C p (T), C p at T>T melt ) of complex oxides in Y-Ba-Cu-O, Sr-Bi-O, Cu-Nb-O, Sr-Cu-O, Ca-Cu-O, Cu-O and Hg-Ba-Ca-Cu-O systems obtained with application of calculation methods are presented. Nonexperimental methods of estimation, revision and correction of standard formation enthalpies of inorganic compounds are described [ru

  17. Superconducting properties of magnetron sputtered high T/sub c/ thin films containing oxide compounds of yttrium, bismuth, or thallium

    International Nuclear Information System (INIS)

    Kang, J.H.; Kampwirth, R.T.; Gray, K.E.

    1989-01-01

    The authors have used multiple source magnetron sputtering to prepare thin films of Y-Ba-Cu-O, Bi-Ca-Sr-Cu-O, and Tl-Ca-Ba-Cu-O on (100) SrTiO/sub 3/, (100) MgO, and ZrO/sub 2/-9%Y/sub 2/O/sub 3/ substrates. Y-Ba-Cu-O films grow best on SrTiO/sub 3/ with mostly an a-axis orientation. Stoichiometry, particularly the Ba/Ca ratio must be within 2% of the correct value to obtain narrow ΔT/sub c/ transitions. Conversely the 80K phase of Bi-Ca-Sr-Cu-O films grows best on MgO substrates and has a predominant c-axis orientation. The requirements on composition are less stringent, however, the annealing temperature must be held within a narrow around 865 0 C to obtain the best films. The best films of Tl-Ca-Ba-Cu-O compounds are grown on (100) oriented and polycrystalline ZrO/sub 2/ substrates. The highest transition temperature, T/sub c0/, where the resistance goes zero is about 114K in the Tl/sub 2/Ba/sub 2/Ca/sub 2/Cu/sub 3/O/sub x/ phase and 100-105K in Tl/sub 2/Ba/sub 2/Ca/sub 1/Cu/sub 2/O/sub x/ and Tl/sub 1/Ba/sub 2/Ca/sub 2/Cu/sub 3/O/sub x/ phase samples. The upper critical field measurements show high anisotropies in the critical field slopes (≥70 for Tl-Ba-Ca-Cu-O compounds and ∼15 for Bi-Sr-Ca-Cu-O compounds), as might be expected from highly oriented materials. The authors compare the preparation conditions and superconducting properties, including T/sub c/, ΔT/sub c/, dB/sub c2//dT (parallel and perpendicular to film surface), of all three compounds

  18. A study on the development of high-Tc superconducting wire

    International Nuclear Information System (INIS)

    Won, Dong Yeon; Chang, In Soon; Lee, Jong Min; Um, Tae Yoon; Hong, Kyae Won; Lee, Ho Jin; Lee, Hee Kwun; Kim, Chan Joong; Park, Soon Dong; Kim, Woo Gon; Kim, Ki Baek; Kwon, Sun Chil

    1992-10-01

    On this study Y-Ba-Cu-O was prepared by partial melt process and superconducting wire was fabricated by powder-in-tube method. First, mechancial properties, electrical properties, microstructure and oxygen diffusion behavior were observed. Second, through fabricated superconducting wire, conceptual design, composition and plasticity of filament superconducting wire were investigated. (Author)

  19. Superconducting microstrip antennas: An experimental comparison of two feeding methods

    International Nuclear Information System (INIS)

    Richard, M.A.; Claspy, P.C.; Bhasin, K.B.

    1993-01-01

    The recent discovery of high-temperature superconductors (HTS's) has generated a substantial amount of interest in microstrip antenna applications. However, the high permittivity of substrates compatible with HTS causes difficulty in feeding such antennas because of the high patch edge impedance. In this paper, two methods for feeding HTS microstrip antennas at K and Ka-band are examined. Superconducting microstrip antennas that are directly coupled and gap-coupled to a microstrip transmission line have been designed and fabricated on lanthanum aluminate substrates using Y-Ba-Cu-O superconducting thin films. Measurements from these antennas, including input impedance, bandwidth, efficiency, and patterns, are presented and compared with published models. The measured results demonstrate that usable antennas can be constructed using either of these architectures, although the antennas suffer from narrow bandwidths. In each case, the HTS antenna shows a substantial improvement over an identical antenna made with normal metals

  20. Di- and tri-carboxylic-acid-based etches for processing high temperature superconducting thin films and related materials

    International Nuclear Information System (INIS)

    Ginley, D.S.; Barr, L.; Ashby, C.I.H.; Plut, T.A.; Urea, D.; Siegal, M.P.; Martens, J.S.; Johansson, M.E.

    1994-01-01

    The development of passive and active electronics from high-temperature superconducting thin films depends on the development of process technology capable of producing appropriate feature sizes without degrading the key superconducting properties. We present a new class of chelating etches based on di- and tri-carboxylic acids that are compatible with positive photoresists and can produce sub-micron feature sizes while typically producing increases the microwave surface resistance at 94 GHz by less than 10%. This simple etching process works well for both the Y--Ba--Cu--O and Tl--Ba--Ca--Cu--O systems. In addition, we demonstrate that the use of chelating etches with an activator such as HF allows the etching of related oxides such as LaAlO 3 , which is a key substrate material, and Pb(Zr 0.53 Ti 0.47 )O 3 (PZT) which is a key ferroelectric material for HTS and other applications such as nonvolatile memories

  1. Preparation of textured high Tc superconducting films by CVD using halides on technical substrates with appropriate buffer layers. Final report

    International Nuclear Information System (INIS)

    Selbmann, D.; Balarin, M.; Klosowski, J.

    1993-01-01

    On the basis of a thermodynamical calculation of the system Y-Ba-Cu-O-Hal-C-H, Hal = I, Br, Cl the deposition conditions of the 123-phase and the other phases in this system was investigated. For the practical applications a reaction temperature higher 850 C and an oxidizer excesse higher 5 . 10 3 is necessary in order to deposit halid- and carbon free layers. A new Aerosol-CVD-process has been developed, which allows the reproducible preparation of superconducting YBa 2 Cu 3 O 7 thin films. The process uses a solution source of Y-, Ba-, Cu-bromide dissolved in suitable organic solvents. With the process the films consisting of the 123-phase, however the content of other phases is too high. With this composition it is not possible to deposit textured layers. This behaviour is due to flow technical problems. In order to avoid the formation of oxides in the evaporator it is necessary to mix the oxidizer directly near the substrate. Therefore the development of a new reactor and a process optimization is necessary. (orig.) [de

  2. High temperature superconductor thin films

    International Nuclear Information System (INIS)

    Correra, L.

    1992-01-01

    Interdisciplinary research on superconducting oxides is the main focus of the contributors in this volume. Several aspects of the thin film field from fundamental properties to applications are examined. Interesting results for the Bi system are also reviewed. The 132 papers, including 8 invited, report mainly on the 1-2-3 system, indicating that the Y-Ba-Cu-O and related compounds are still the most intensively studied materials in this field. The volume attests to the significant progress that has been made in this field, as well as reporting on the challenging problems that still remain to be solved. The papers are presented in five chapters, subsequently on properties, film growth and processing, substrates and multilayers, structural characterization, and applications

  3. Computer simulation of scattered ion and sputtered species effects in ion beam sputter-deposition of high temperature superconducting thin films

    International Nuclear Information System (INIS)

    Krauss, A.R.; Auciello, O.

    1992-01-01

    Ion beam sputter-deposition is a technique currently used by many groups to produce single and multicomponent thin films. This technique provides several advantages over other deposition methods, which include the capability for yielding higher film density, accurate stoichiometry control, and smooth surfaces. However, the relatively high kinetic energies associated with ion beam sputtering also lead to difficulties if the process is not properly controlled. Computer simulations have been performed to determine net deposition rates, as well as the secondary erosion, lattice damage, and gas implantation in the films, associated with primary ions scattered from elemental Y, Ba and Cu targets used to produce high temperature superconducting Y-Ba-Cu-O films. The simulations were performed using the TRIM code for different ion masses and kinetic energies, and different deposition geometries. Results are presented for primary beams of Ar + , Kr + and Xe + incident on Ba and Cu targets at 0 degrees and 45 degrees with respect to the surface normal, with the substrate positioned at 0 degrees and 45 degrees. The calculations indicate that the target composition, mass and kinetic energy of the primary beam, angle of incidence on the target, and position and orientation of the substrate affect the film damage and trapped primary beam gas by up to 5 orders of magnitude

  4. Thin film production of ceramic high-Tc-superconductors (targets)

    International Nuclear Information System (INIS)

    1992-01-01

    Presently high-quality thin superconducting films having high T c 's may prepared by the sputtering technique. However, a large-area coating is required for an industrial application. One requirement is the availability of sputter targets with controlled and reproducible properties. By means of basic experiments with respect to powder processing, shaping and the densification process superconducting targets up to 200 mm in diameter were prepared in the Y-Ba-Cu-O- system. Additionally, targets from other systems with different geometries (e.g. ring targets) were prepared. These targets were submitted to the project partners as well as to other institutes and companies. During the course of this project the foundations for an industrial-type coating of large-area substrates were elaborated. (orig.). 9 refs., 5 tabs., 15 figs [de

  5. Raman studies of reactive DC-magnetron sputtered thin films of YBaCuO on MgO

    International Nuclear Information System (INIS)

    Sheng, K.C.; Lee, S.J.; Shen, Y.H.; Wang, X.K.; Rippert, E.D.; Van Duyne, R.P.; Ketterson, J.B.; Chang, R.P.H.

    1989-01-01

    Raman spectroscopy was employed to study Y-Ba-Cu-O films prepared by multilayer, reactive sputtering from separate Y, Cu, and Ba 0.5 Cu 0.5 targets. A set of films having the composition Y x Ba 2 Cu y O z with 0.7 c (R=0), ranging from 25 to 90 K was studied with the Raman technique. The correlation between Raman data and critical temperature, T c , was investigated. This technique provides important information concerning the film crystallinity, homogeneity, and impurity content (including other phases) which is useful in judging the quality of high T c superconducting films. We also found that the rapid thermal annealing process is a very efficient way to reduce chemical reactions between the film and the substrate

  6. Phase compatibilities of YBa2Cu3O(9-delta) type structure in quintenary systems Y-Ba-Cu-O-X (impurity)

    Science.gov (United States)

    Karen, P.; Fjellvag, H.; Kjekshus, A.

    1990-01-01

    Electrical transport properties of the oxidic high T(sub c) superconductors are significantly affected by the presence of minor amounts of various elements adventing as impurities, e.g., from the chemical environment during manufacturing. YBa2Cu3O(9-delta) is prone to an extinction of the superconductivity on (partial) substitution of all four elemental components. E.g., Pr (for Y), La (for Ba), Zn (for Cu) or peroxygroup (for O) substituents will alter some of the superconductivity preconditions, like mixed valence state in Cu3O7/O(9-delta) network or structural distortion of the network. Although various pseudoternary chemical equilibrium phase diagrams of the Y(O)-Ba(O)-Cu(O) system now are available, no consensus is generally shown, however, this is partly due to lack of compatible definitions of the equilibrium conditions. Less information is available about the phase compatibilities in the appropriate quaternary phase diagram (including oxygen) and virtually no information exists about any pentenary phase diagrams (including one impurity). Unfortunately, complexity of such systems, stemming both from number of quaternary or pentenary compounds and from visualizing the five-component phase system, limits this presentation to more or less close surroundings of the YBa2Cu3O(9-delta) type phase in appropriate pseudoquaternary or pseudopseudoternary diagrams, involving Y-Ba-Cu and O, O-CO2, alkaline metals, Mg and alkaline earths, and Sc and most of the 3-d and 4-f elements. The systems were investigated by means of x ray diffraction, neutron diffraction and chemical analytical methods on samples prepared by sol-gel technique from citrates. The superconductivity was characterized by measuring the diamagnetic susceptibility by SQUID.

  7. Normal-state transport parameters of epitaxial thin films of YBa2Cu3O/sub 7-//sub δ/

    International Nuclear Information System (INIS)

    Stormer, H.L.; Levi, A.F.J.; Baldwin, K.W.; Anzlowar, M.; Boebinger, G.S.

    1988-01-01

    We report on a striking correlation in the electrical transport behavior of very high-quality (j/sub c/∼3.4 x 10 6 A/cm 2 at T = 77 K) epitaxial thin films of high-T/sub c/ Y-Ba-Cu-O in the normal state. With increasing superconducting performance, as characterized by the transition temperature, transition-temperature width, and critical current density, the resistivity rho, and the Hall coefficient R/sub H/, both assume remarkably simple temperature dependences rho = αT and R/sub H//sup -1/ = βT leading to a Hall mobility μ/sub H/proportionalT/sup -2/. The magnetoresistance at 10 T is less than Δrho/rho<10/sup -3/. We discuss an extreme two-carrier model to assess the T dependence of R/sub H/. .AE

  8. Optically activated high Tc superconducting microbolometer

    International Nuclear Information System (INIS)

    Yefremenko, V; Gordiyenko, E; Shustakova, G; Bader, S D; Karapetrov, G; Novosad, V

    2006-01-01

    A laser beam, precisely focused on the patterned superconducting structure, was used to nucleate a resistive area that is sensitive to external thermal effects. The electron beam lithography and wet chemical etching were applied as pattern transfer processes in epitaxial Y-Ba-Cu-O films. Two different sensor designs were tested: (i) 3 millimeters long and 40 micrometers wide stripe and (ii) 1.25 millimeters long, and 50 micron wide meander -like structure. It is shown experimentally that scanning the laser beam along the stripe leads to physical displacement of the sensitive area and, therefore may be used as a basis for imaging over a broad spectral range. For example, patterning the superconducting film into a meander structure is equivalent to a two-dimensional detector array. In additional to the simplicity of the detector fabrication sequence (one step mask transfer), a clear advantage of this approach is the simplicity of the read-out process: an image is formed by registering the signal with only two electrical terminals. The proposed approach can be extended for imaging over a wide spectral range

  9. Superconducting Electronic Film Structures

    Science.gov (United States)

    1991-02-14

    Segmuller, A., Cooper, E.I., Chisholm, M.F., Gupta, A. Shinde, S., and Laibowitz, R.B. Lanthanum gallate substrates for epitaxial high-T superconducting thin...M. F. Chisholm, A. Gupta, S. Shinde, and R. B. Laibowitz, " Lanthanum Gallate Substrates for Epitaxial High-T c Superconducting Thin Films," Appl...G. Forrester and J. Talvacchio, " Lanthanum Copper Oxide Buffer Layers for Growth of High-T c Superconductor Films," Disclosure No. RDS 90-065, filed

  10. Superconducting thin films

    International Nuclear Information System (INIS)

    Hebard, A.F.; Vandenberg, J.M.

    1982-01-01

    This invention relates to granular metal and metal oxide superconducting films formed by ion beam sputter deposition. Illustratively, the films comprise irregularly shaped, randomly oriented, small lead grains interspersed in an insulating lead oxide matrix. The films are hillock-resistant when subjected to thermal cycling and exhibit unusual josephson-type switching characteristics. Depending on the oxygen content, a film may behave in a manner similar to that of a plurality of series connected josephson junctions, or the film may have a voltage difference in a direction parallel to a major surface of the film that is capable of being switched from zero voltage difference to a finite voltage difference in response to a current larger than the critical current

  11. Superconductivity and ceramic superconductors II; Proceedings of the Symposium, Orlando, FL, Nov. 12-15, 1990. Ceramic transactions. Vol. 18

    International Nuclear Information System (INIS)

    Nair, K.M.; Balachandran, U.; Chiang, Y.-M.; Bhalla, A.S.

    1991-01-01

    The present symposium on superconductivity and ceramic superconductors discusses fundamentals and general principles, powder processing and properties, fabrication and properties, and device reliability and applications. Attention is given to phase formation in the Tl-Ca-Ba-Cu-O system, comparative defect studies in La2CuO4 and La2NiO4, solid solution and defect behavior in high Tc oxides, oxygen ion transport and disorder in cuprates, and Sr-free Bi-Ln-Ca-Cu-O superconductors. Topics addressed include the preparation of superconductor Y-Ba-Cu-O powder by single-step calcining in air, low-temperature synthesis of YBa2Cu3O(7-x), synthesis of high-phase purity ceramic oxide superconductors by the xerogel method, and the preparation and characterization of the BYa2Cu4O8 superconductor. Also discussed are optical studies of humidity-based corrosion effects on thin film and bulk ceramic YBa2Cu3O(7-delta), thermomechanical processing of YBa2Cu3O(x)/Ag sheathed wires, and the expansion of high-Tc superconducting ceramics

  12. Magnetic and electronic properties of YBa sub 2 Cu sub 3 O sub x (6. 5Y-Ba-Cu-O

    Energy Technology Data Exchange (ETDEWEB)

    Puempin, B.; Keller, H.; Kuendig, W.; Savic, I.M.; Schneider, J.W.; Simmler, H.; Zimmermann, P. (Physik-Inst., Univ. Zurich (Switzerland)); Kaldis, E.; Rusiecki, S. (Lab. fuer Festkoerperphysik, ETH Zurich (Switzerland)); Rossel, C. (IBM Research Div., Zurich Research Lab., Rueschlikon (Switzerland)); Forgan, E.M. (School of Physics and Space Research, Univ. of Birmingham (UK))

    1990-10-15

    A systematic study of the local magnetic field distribution p(B) in the perovskite-type superconductor YBa{sub 2}Cu{sub 3}O{sub x} is presented. Special attention is given to the second moment <{Delta}B{sup 2}> of p(B) which is closely related to the superconducting carrier density n{sub s} and the effective mass m{sup *} of the superconducting carriers. The influence of temperature, anisotropy and hole doping are investigated in detail. It is found that the temperature dependence of the magnetic penetration depth in YBa{sub 2}Cu{sub 3}O{sub x} is in agreement with conventional s-wave pairing and suggests strong coupling. The anisotropic behavior of p(B) is well described by a theory for uniaxial type II superconductors, with an anisotropy ratio {gamma}{approx equal}5(1). Moreover, the zero-temperature values {lambda}{sub ab}(0)=130(10) nm and {lambda}{sub c}(0){approx equal}500-800 nm (penetration depth for screening currents flowing in the ab-planes and along the c-axis, respectively) were extracted from our data. {mu}SR experiments performed on oxygen deficient samples indicate that the structural and electronic properties of YBa{sub 2}Cu{sub 3}O{sub x} are strongly correlated via the oxygen content x. (orig.).

  13. The effect of oxidant on resputtering of Bi from Bi-Sr-Ca-Cu-O films

    Science.gov (United States)

    Grace, J. M.; McDonald, D. B.; Reiten, M. T.; Olson, J.; Kampwirth, R. T.; Gray, K. E.

    1991-09-01

    The type and partial pressure of oxidant mixed with argon can affect the selective resputtering of Bi in composite-target, magnetron-sputtered Bi-Sr-Ca-Cu-O films. Comparative studies using oxygen and ozone show that ozone is a more potent oxidant, as well as a more potent source of resputterers, than is oxygen. Severe resputtering from ozone is significantly reduced by a -40 V potential on the sample block. We suggest that oxygen causes resputtering by forming O2(+)p , which interacts with the target to produce energetic O(-). In contrast, ozone may form lower-energy O(-) by electron impact in the dark space. Negative oxygen ions from the target itself may be responsible for a background resputtering effect. Our results and those found for Y-Ba-Cu-O by others are comparable. Bi in Bi-Sr-Ca-Cu-O behaves as Ba in Y-Ba-Cu-O, with regard to selective resputtering; furthermore, the response of Sr, Ca, and Cu to oxygen in sputtered Bi-Sr-Ca-Cu-O is similar to what is observed for Cu in Y-Ba-Cu-O.

  14. Selective resputtering of bismuth in sputtered Bi-Sr-Ca-Cu-O films

    Science.gov (United States)

    Grace, J. M.; McDonald, D. B.; Reiten, M. T.; Olson, J.; Kampwirth, R. T.; Gray, K. E.

    1991-10-01

    We present studies using a dc magnetron in an on-axis configuration to sputter Bi-Sr-Ca-Cu-O films from a composite target. These studies show that bismuth can be preferentially resputtered. The influence of ozone, molecular oxygen, and total pressure on the resputtering of bismuth is investigated and discussed. Ozone, in low concentrations, can dramatically affect the degree of resputtering. By comparing the effects of molecular oxygen and ozone, some insight is gained regarding the possible mechanisms of negative ion formation in the magnetron environment. Based on our results we suggest that molecular oxygen can bring about resputtering primarily by forming O+2, which collides with the target to produce energetic negative oxygen ions. In contrast, ozone may form negative ions by electron impact in the dark space above the target, giving rise to lower-energy negative ions, which can traverse the plasma unneutralized and can be stopped with an applied bias on the sample block. With no added oxidant, negative oxygen ions from the target oxygen may dominate the background resputtering. Similarity is found between our results and those for similar studies on Y-Ba-Cu-O by other workers. Bismuth in Bi-Sr-Ca-Cu-O behaves as barium in Y-Ba-Cu-O with regards to preferential resputtering; furthermore, the response of strontium, calcium, and copper to oxygen in sputtered Bi-Sr-Ca-Cu-O is similar to what is observed for copper in Y-Ba-Cu-O.

  15. Effect of oxidant on resputtering of Bi from Bi--Sr--Ca--Cu--O films

    International Nuclear Information System (INIS)

    Grace, J.M.; McDonald, D.B.; Reiten, M.T.; Olson, J.; Kampwirth, R.T.; Gray, K.E.

    1992-01-01

    The type and partial pressure of oxidant mixed with argon can affect the selective sputtering of Bi in composite-target, magnetron-sputtered Bi--Sr--Ca--Cu--O films. Comparative studies using oxygen and ozone show that ozone is a more potent oxidant, as well as a more potent source of resputterers than is oxygen. Severe resputtering from ozone is significantly reduced by a -40 V potential on the sample block. We suggest that oxygen causes resputtering by forming O + 2 , which interacts with the target to produce energetic O - . In contrast, ozone may form lower-energy O - by electron impact in the dark space. Negative oxygen ions from the target itself may be responsible for a background resputtering effect. Our results and those found for Y--Ba--Cu--O by others are comparable. Bi in Bi--Sr--Ca--Cu--O behaves as Ba in Y--Ba--Cu--O, with regard to selective resputtering; furthermore, the response of Sr, Ca, and Cu to oxygen in sputtered Bi--Sr--Ca--Cu--O is similar to what is observed for Cu in Y--Ba--Cu--O

  16. Selective resputtering of bismuth in sputtered Bi-Sr-Ca-Cu-O films

    International Nuclear Information System (INIS)

    Grace, J.M.; McDonald, D.B.; Reiten, M.T.; Olson, J.; Kampwirth, R.T.; Gray, K.E.

    1991-01-01

    We present studies using a dc magnetron in an on-axis configuration to sputter Bi-Sr-Ca-Cu-O films from a composite target. These studies show that bismuth can be preferentially resputtered. The influence of ozone, molecular oxygen, and total pressure on the resputtering of bismuth is investigated and discussed. Ozone, in low concentrations, can dramatically affect the degree of resputtering. By comparing the effects of molecular oxygen and ozone, some insight is gained regarding the possible mechanisms of negative ion formation in the magnetron environment. Based on our results we suggest that molecular oxygen can bring about resputtering primarily by forming O + 2 , which collides with the target to produce energetic negative oxygen ions. In contrast, ozone may form negative ions by electron impact in the dark space above the target, giving rise to lower-energy negative ions, which can traverse the plasma unneutralized and can be stopped with an applied bias on the sample block. With no added oxidant, negative oxygen ions from the target oxygen may dominate the background resputtering. Similarity is found between our results and those for similar studies on Y-Ba-Cu-O by other workers. Bismuth in Bi-Sr-Ca-Cu-O behaves as barium in Y-Ba-Cu-O with regards to preferential resputtering; furthermore, the response of strontium, calcium, and copper to oxygen in sputtered Bi-Sr-Ca-Cu-O is similar to what is observed for copper in Y-Ba-Cu-O

  17. Mechanical loss measurements on Y-Ba-Cu-O superconductors

    International Nuclear Information System (INIS)

    Weller, M.

    1993-01-01

    In YBa 2 Cu 3 O 7-x ceramics mechanical loss (internal friction) maxima are observed over a wide range of temperatures which may be assigned to the following temperature regimes: I (50-110 K), II (200 - 250 K), III (500 K), and IV (850-950 K) (peak temperatures for 1 Hz). Maximum I consists of three submaxima, IA (62 K), IB (74 K), and IC (45 K). These maxima are examined here in detail, especially their dependence on oxygen content. Maximum IB is restricted to the orthorhombic phase, maximum IA decreases continuously with oxygen deficiency and is absent for x = 1, maximum IC appears within a narrow composition range in the tetragonal phase (x ≥ 0.7). All maxima are governed by thermally activated atomic jumps (as indicated by their frequency shift) with the following relaxation parameters: IA: H = 0.12 8 eV, τ ∞ 6.8x10 -12 s; IB: H = 0.18 0 eV, τ ∞ = 1.0x10 -13 s; IC: H 0.08 eV; τ ∞ = 1.6x10 -10 s. The results are discussed in connection with a comprehensive compilation of literature data on loss maxima I. Several atomic models proposed so far are presented and discussed. Models based on jumps of oxygen via vacancies are considered as less probable since it is now fairly well established that loss maximum III is connected with oxygen diffusion. Indication that maxima IA and IB are connected with hopping of holes (polarons) is presented. (orig.)

  18. High-temperature superconducting oxide synthesis and the chemical doping of the Cu-O planes

    International Nuclear Information System (INIS)

    Tarascon, J.M.; Barboux, P.; Bagley, B.G.; Greene, L.H.; McKinnon, W.R.; Hull, G.W.

    1987-01-01

    Different synthesis techniques for the preparation of dense superconducting ceramics are discussed, and a sol-gel process is shown to be very promising. The effect of oxygen content, and the effect of substitution of Ni and Zn for copper, on the structural, transport and superconducting properties of the La-Sr-Cu-O and Y-Ba-Cu-O systems are presented. The authors find that substitution on the copper sites destroys T/sub c/ in the La-Sr-Cu-O system and decreases it in the Y-Ba-Cu-O system, and this effect is insensitive as to whether the 3d metal is magnetic (Ni) or diamagnetic (Zn). A detailed study of the YBa/sub 2/Cu/sub 3/O/sub 7-y/ system as a function of oxygen content (y) shows that superconductivity can be destroyed in these materials by the removal of oxygen and restored by reinjecting oxygen; either thermally at 500 0 C or at temperatures (80 0 C) compatible with device processing by means of a novel plasma oxidation process. Of scientific interest, the plasma process induces bulk superconductivity in the undoped La/sub 2/CuO/sub 4/

  19. Superconducting oxypnictide thin films

    Energy Technology Data Exchange (ETDEWEB)

    Reisner, Andreas; Kidszun, Martin; Reich, Elke; Holzapfel, Bernhard; Schultz, Ludwig; Haindl, Silvia [IFW Dresden, Institute of Metallic Materials (Germany); Thersleff, Thomas [Uppsala University, Angstrom Laboratory (Sweden)

    2012-07-01

    We present an overview on the oxypnictide thin film preparation. So far, only LaAlO{sub 3} (001) single crystalline substrates provided a successful growth using pulsed laser deposition in combination with a post annealing process. Further experiments on the in-situ deposition will be reported. The structure of the films was investigated by X-ray diffractometry and transmission electron microscopy. Transport properties were measured with different applied fields to obtain a magnetic phase diagram for this new type of superconductor.

  20. Electrical resistivity measurements in superconducting ceramics

    International Nuclear Information System (INIS)

    Muccillo, R.; Bressiani, A.H.A.; Muccillo, E.N.S.; Bressiani, J.C.

    1988-01-01

    Electrical resistivity measurements have been done in (Y, Ba, Cu, O) - and (Y, A1, Ba, Cu, O) - based superconducting ceramics. The sintered specimens were prepared by applying gold electrodes and winding on the non-metalized part with a copper strip to be immersed in liquid nitrogen for cooling. The resistivity measurements have been done by the four-probe method. A copper-constantan or chromel-alumel thermocouple inserted between the specimen and the copper cold finger has been used for the determination of the critical temperature T c . Details of the experimental set-up and resistivity versus temperature plots in the LNT-RT range for the superconducting ceramics are the major contributions of this communication. (author) [pt

  1. Electrical resistivity measurements in superconducting ceramics

    International Nuclear Information System (INIS)

    Muccillo, R.; Bressiani, A.H.A.; Muccillo, E.N.S.; Bressian, J.C.

    1988-01-01

    Electrical resistivity measurements have been done in (Y,Ba,Cu,O)- and (Y,Al,Ba,Cu,O)-based superconducting ceramics. The sintered specimens were prepared by applying gold electrodes and winding on the non-metalized part with a copper strip to be immersed in liquid nitrogen for cooling. The resistivity measurements have been done by the four-probe method. A copper constantan or chromel-alumel thermocouple inserted between the specimen and the copper cold finger has been used for the determination of the critical temperature T c . Details of the experimental set-up and resistivity versus temperature plots in the LNT-RT range for the superconducting ceramics are the major contributions of this communication. (author) [pt

  2. Review of thin film superconductivity

    International Nuclear Information System (INIS)

    Kihlstrom, K.E.

    1989-01-01

    Advances in thin film superconductivity are critical to the success of many proposed applications. The authors review several of the prominent techniques currently used to produce thin films of the high temperature superconductors including electron beam co-deposition, sputtering (both multiple and composite source configurations) and laser ablation. The authors look at the relevant parameters for each and evaluate the advantages and disadvantages of each technique. In addition, promising work on in situ oxidation is discussed. Also addressed are efforts to find optimum substrate materials and substrate buffer layers for various applications. The current state of the art for T c , J c and H c2 is presented for the yttrium, bismuth, and thallium compounds

  3. Fabrication of thick superconducting films by decantation

    Directory of Open Access Journals (Sweden)

    Julián Betancourt M.

    1991-07-01

    Full Text Available We have found superconducting behavior in thick films fabricated by decantation. In this paper we present the experimental method and results obtained using commercial copper substrates.

  4. Enhanced critical currents in (Gd,Y)Ba2Cu3Ox superconducting tapes with high levels of Zr addition

    Energy Technology Data Exchange (ETDEWEB)

    Selvamanickam, V; Chen, Y; Shi, T; Liu, Y; Khatri, ND; Liu, J; Yao, Y; Xiong, X; Lei, C; Soloveichik, S; Galstyan, E; Majkic, G

    2013-01-21

    The critical current and structural properties of (Gd,Y)BaCuO tapes made by metal organic chemical vapor deposition (MOCVD) with Zr addition levels up to 30 at.% have been investigated. The reduction in critical current beyond the previously optimized Zr addition level of 7.5 at.% was found to be due to structural deterioration of the (Gd,Y)Ba2Cu3Ox film. By a modified MOCVD process,enhanced critical current densities have been achieved with high levels of Zr addition,including 3.83 MA cm(-2) in 15 at.% Zr- added 1.1 mu m thick film at 77 K in zero magnetic field. Critical currents as high as 1072 A/ 12 mm have been reached in (Gd,Y) BaCuO tapes with 15 at.% Zr addition at 30 K in a field of 3 T applied perpendicular to the tape,corresponding to a pinning force value of 268 GN m(-3). The enhanced critical currents achievable with a high density of nanoscale defects by employing high levels of second- phase additions enable the performance targets needed for the use of HTS tapes in coil applications involving high magnetic fields at temperatures below 50 K to be met.

  5. Enhanced critical currents in (Gd,Y)Ba2Cu3Ox superconducting tapes with high levels of Zr addition

    International Nuclear Information System (INIS)

    Selvamanickam, V; Shi, T; Liu, Y; Khatri, N D; Liu, J; Yao, Y; Galstyan, E; Majkic, G; Chen, Y; Xiong, X; Lei, C; Soloveichik, S

    2013-01-01

    The critical current and structural properties of (Gd,Y)BaCuO tapes made by metal organic chemical vapor deposition (MOCVD) with Zr addition levels up to 30 at.% have been investigated. The reduction in critical current beyond the previously optimized Zr addition level of 7.5 at.% was found to be due to structural deterioration of the (Gd,Y)Ba 2 Cu 3 O x film. By a modified MOCVD process, enhanced critical current densities have been achieved with high levels of Zr addition, including 3.83 MA cm −2 in 15 at.% Zr-added 1.1 μm thick film at 77 K in zero magnetic field. Critical currents as high as 1072 A/12 mm have been reached in (Gd,Y)BaCuO tapes with 15 at.% Zr addition at 30 K in a field of 3 T applied perpendicular to the tape, corresponding to a pinning force value of 268 GN m −3 . The enhanced critical currents achievable with a high density of nanoscale defects by employing high levels of second-phase additions enable the performance targets needed for the use of HTS tapes in coil applications involving high magnetic fields at temperatures below 50 K to be met. (paper)

  6. Thermal propagation and stability in superconducting films

    International Nuclear Information System (INIS)

    Gray, K.E.; Kampwirth, R.T.; Zasadzinski, J.F.; Ducharme, S.P.

    1983-01-01

    Thermal propagation and stable hot spots (normal domains) are studied in various high Tsub(c) superconducting films (Nb 3 Sn, Nb, NbN and Nb 3 Ge). A new energy balance is shown to give reasonable quantitative agreement of the dependence of the propagation velocity on the length of short normal domains. The steady state (zero velocity) measurements indicate the existence of two distinct situations for films on high thermal conductivity (sapphire) substrates. For low power per unit area the film and substrate have the same temperature, and the thermal properties of the substrate dominate. However, for higher power densities in short hot spots, the coupling is relatively weak and the thermal properties of the film alone are important. Here a connection is made between the critical current stability of superconducting films and a critical hot spot size for thermal propagation. As a result efficient heat removal is shown to dominate the stabilisation of superconducting films. The strong and weak coupling situations also lead to modifications of the models for propagation velocities on sapphire substrates. Self-healing of hot spots and other phenomena in superconducting film are explained. The potential use of the thermal propagation model in applications of superconductors, especially switches is discussed. (author)

  7. Spray pyrolysis process for preparing superconductive films

    International Nuclear Information System (INIS)

    Hsu, H.M.; Yee, I.Y.

    1991-01-01

    This paper describes a spray pyrolysis method for preparing thin superconductive film. It comprises: preparing a spray pyrolysis solution comprising Bi,Sr,Ca and Cu metals in a solvent; heating a substrate to a first temperature; spraying the solution onto the heated substrate to form a film thereon; heating the film and substrate to a second temperature of about 700 degrees-825 degrees C, the second temperature being higher than the first temperature; heating the film and substrate to a third temperature of about 870 degrees-890 degrees C to melt the film; once the film and substrate reach the third temperature, further heat treating the film and substrate; cooling the film and substrate to ambient temperature. This patent also describes a spray pyrolysis method for preparing thin superconductive films. It comprises: preparing a spray pyrolysis solution comprising Bi, Ca and Cu metals and fluxing agent in a solvent; heating a substrate to a first temperature; spraying the solution onto the heated substrate to form a film thereon; heating the film and substrate to a second temperature about 700 degrees-825 degrees C, the second temperature being higher than the first temperature; heating the film and substrate at a third temperature about 840 degrees-860 degrees C; and cooling the film and substrate to ambient temperature

  8. Use of high-temperature superconducting films in superconducting bearings

    International Nuclear Information System (INIS)

    Cansiz, A.

    1999-01-01

    We have investigated the effect of high-temperature superconductor (HTS) films deposited on substrates that are placed above bulk HTSs in an attempt to reduce rotational drag in superconducting bearings composed of a permanent magnet levitated above the film/bulk HTS combination. According to the critical state model, hysteresis energy loss is inversely proportional to critical current density, J c , and because HTS films typically have much higher J c than that of bulk HTS, the film/bulk combination was expected to reduce rotational losses by at least one order of magnitude in the coefficient of fiction, which in turn is a measure of the hysteresis losses. We measured rotational losses of a superconducting bearing in a vacuum chamber and compared the losses with and without a film present. The experimental results showed that contrary to expectation, the rotational losses are increased by the film. These results are discussed in terms of flux drag through the film, as well as of the critical state model

  9. Switching, storage, and erasure effects in a superconducting thin film

    International Nuclear Information System (INIS)

    Testardi, L.R.

    1976-01-01

    Thin niobium films can be switched from a superconducting to a resistive state permanently by application of a short electrical pulse. Application of a short pulse of opposite polarity returns the film to the superconducting state

  10. Laser patterning of superconducting oxide films

    International Nuclear Information System (INIS)

    Gupta, A.; Hussey, B.W.; Koren, G.; Cooper, E.I.; Jagannathan, R.

    1988-01-01

    The focused output of an argon ion laser (514.5 nm) has been used for wiring superconducting lines of Y/sub 1/Ba/sub 2/CU/sub 3/O/sub 7-δ/ using films prepared from nitrate and trifluoroacetate solution precursors. A stoichiometric solution of the precursors is sprayed or spun on to the substrate to form a film. The film is patterned by irradiating in selected areas to convert the irradiated layers to an intermediate oxide or fluoride state, the nonirradiated areas being unchanged. The nonirradiated areas are then dissolved away, leaving a pattern of the oxide or fluoride material. This patterned layer is converted to the superconducting 1-2-3 oxide in a subsequent annealing step. Maskless patterning of superconducting films has also been demonstrated by laser-assisted etching of the films in aqueous KOH solution. Although superconductivity is destroyed when the films are placed in solution, it can be restored after a brief anneal in oxygen

  11. RE-Ba-Cu-O for high functional superconducting permanent magnet

    International Nuclear Information System (INIS)

    Yoo, S.I.; Higuchi, T.; Sakai, N.; Murakami, M.; Fujimoto, H.

    1998-01-01

    Among various potential applications of melt-textured RE-Ba-Cu-O (REBCO, RE: rare earth elements) superconductors, we have examined the bulk application as the superconducting permanent magnet, especially for the magnetically-levitated (MAGLEV) train. Compared with Y-Ba-Cu-O (YBCO), oxygen-controlled melt-growth (OCMG)-processed LREBCO (LRE: light rare earth elements) bulk superconductors are more promising for this application because of larger critical current density (J c ) values in high field and higher irreversibility field (B irr ) within the range of the liquid nitrogen refrigeration (63-77 K), implying that even higher trapped fields (B t ) are achievable in principle. In this paper, material requirements of superconducting bulks for the MAGLEV train are first presented and then processing aspects for the fabrication of good LREBCO bulks are described. (orig.)

  12. Magnetization Controlled Superconductivity in a Film with Magnetic Dots

    International Nuclear Information System (INIS)

    Lyuksyutov, I.F.; Pokrovsky, V.; Pokrovsky, V.

    1998-01-01

    We consider a superconducting film with a magnetic dots array (MDA) placed upon it. Magnetic moments of the dots are normal to the film and strong enough to create vortices in the superconducting film. Magnetic interaction between dots is negligible. Zero-field cooling leads to random magnetization of the MDA well above the superconducting temperature. With this cooling, the film is in a resistive state below the (expected) superconducting transition. Paradoxically, when field cooled, the film with MDA can be superconducting. copyright 1998 The American Physical Society

  13. Excessive current in wide superconducting films

    International Nuclear Information System (INIS)

    Volotskaya, V.G.; Sivakov, A.G.; Turutanov, O.G.

    1986-01-01

    The resistive state of a wide long film due to superconductivity destruction by current is studied. The voltage-independent excess current I 0 is observed on I-V curves at high transport currents. The two-dimensional image of the current-carrying sample obtained by laser scanning technique in this current range indicates that the whole film is in the resistive state. The current I 0 is measured as a function of magnetic field and SHF power

  14. Superconducting and structural properties of plasma sprayed YBaCuO layers deposited on metallic substrates

    NARCIS (Netherlands)

    Hemmes, Herman K.; Jäger, D; Smithers, M.A.; Smithers, M.; van der Veer, J.; van der Veer, J.M.; Stover, D.; Rogalla, Horst

    1993-01-01

    The properties of plasma sprayed Y-Ba-Cu-O coatings deposited on metallic substrates are studied. Stainless steel, nickel steels and pure nickel are used as substrate. Y-Ba-Cu-O deposited on stainless steel and nickel steel reacts with the substrate. This interaction can be suppressed by using an

  15. Geometrical resonance effects in thin superconducting films

    International Nuclear Information System (INIS)

    Nedellec, P.

    1977-01-01

    Electron tunneling density of states measurements on thick and clear superconducting films (S 1 ) backed by films in the normal or superconducting state (S 2 ) show geometrical resonance effects associated with the spatial variation of Δ(x), the pair potential, near the interface S 1 -S 2 . The present understanding of this so-called 'Tomasch effect' is described. The dispersion relation and the nature of excitations in the superconducting state are introduced. It is shown that the introduction of Green functions give a general description of the superconducting state. The notion of Andreev scattering at the S 1 -S 2 interface is presented and connect the geometrical resonance effects to interference process between excitations. The different physical parameters involved are defined and used in the discussion of some experimental results: the variation of the period in energy with the superconducting thickness is connected to the renormalized group velocity of excitations traveling perpendicular to the film. The role of the barrier potential at the interface on the Tomasch effect is described. The main results discussed are: the decrease of the amplitude of the Tomasch structures with energy is due to the loss of the mixed electron-hole character of the superconducting excitations far away from the Fermi level; the variation of the pair potential at the interface is directly related to the amplitude of the oscillations; the tunneling selectivity is an important parameter as the amplitude as well as the phase of the oscillations are modified depending on the value of the selectivity; the phase of the Tomasch oscillations is different for an abrupt change of Δ at the interface and for a smooth variation. An ambiguity arises due to the interplay between these parameters. Finally, some experiments, which illustrate clearly the predicted effects are described [fr

  16. Ferromagnetic film on a superconducting substrate

    Energy Technology Data Exchange (ETDEWEB)

    Bulaevskii, L. N.; Chudnovsky, E. M.

    2001-01-01

    We study the equilibrium domain structure and magnetic flux around a ferromagnetic film with perpendicular magnetization M{sub 0} on a superconducting (SC) substrate. At 4{pi}M{sub 0}film, l, scales as (l/4{pi}{lambda}{sub L})=(l{sub N}/4{pi}{lambda}{sub L}){sup 2/3} with the domain width on a normal (nonsuperconducting) substrate, l{sub N}/4{pi}{lambda}{sub L}>>1; {lambda}{sub L} being the London penetration length.

  17. Ferromagnetic film on a superconducting substrate

    International Nuclear Information System (INIS)

    Bulaevskii, L. N.; Chudnovsky, E. M.

    2001-01-01

    We study the equilibrium domain structure and magnetic flux around a ferromagnetic film with perpendicular magnetization M 0 on a superconducting (SC) substrate. At 4πM 0 c1 the SC is in the Meissner state and the equilibrium domain width in the film, l, scales as (l/4πλ L )=(l N /4πλ L ) 2/3 with the domain width on a normal (nonsuperconducting) substrate, l N /4πλ L >>1; λ L being the London penetration length

  18. Modern high-temperature superconductivity

    International Nuclear Information System (INIS)

    Ching Wu Chu

    1988-01-01

    Ever since the discovery of superconductivity in 1911, its unusual scientific challenge and great technological potential have been recognized. For the past three-quarters of a century, superconductivity has done well on the science front. This is because sueprconductivity is interesting not only just in its own right but also in its ability to act as a probe to many exciting nonsuperconducting phenomena. For instance, it has continued to provide bases for vigorous activities in condensed matter science. Among the more recent examples are heavy-fermion systems and organic superconductors. During this same period of time, superconductivity has also performed admirably in the applied area. Many ideas have been conceived and tested, making use of the unique characteristics of superconductivity - zero resistivity, quantum interference phenomena, and the Meissner effect. In fact, it was not until late January 1987 that it became possible to achieve superconductivity with the mere use of liquid nitrogen - which is plentiful, cheap, efficient, and easy to handle - following the discovery of supercondictivity above 90 K in Y-Ba-Cu-O, the first genuine quaternary superconductor. Superconductivity above 90 K poses scientific and technological challenges not previously encountered: no existing theories can adequately describe superconductivity above 40 K and no known techniques can economically process the materials for full-scale applications. In this paper, therefore, the author recalls a few events leading to the discovery of the new class of quaternary compounds with a superconducting transition temperature T c in the 90 K range, describes the current experimental status of high-temperature superconductivity and, finally, discusses the prospect of very-high-temperature superconductivity, i.e., with a T c substantially higher than 100 K. 97 refs., 7 figs

  19. Superconducting films of YBaCuO

    International Nuclear Information System (INIS)

    Coelho, A.L.

    1991-01-01

    Thick films of YBa 2 Cu 3 O 7 - x have been prepared on alumina and YSZ (Yttria-stabilized zirconia) substrates by the screen printing technique. Several experimental conditions have been studied, for instance: sintering time, temperature, thickness and atmosphere annealed. The resulting films have been characterized by X-ray diffraction, AC electrical resistance, AC susceptibility and scanning electron microscopy. The surface and cross-section have been observed with an optical microscope. The X-ray diffraction patterns have been compared with a typical pattern and that has indicated the good quality of the samples. AC resistance and its temperature dependence have been measured in the standard four-probe configuration. Films thickness has been estimated in the scanning electron microscope. This technique has been suitable for production of high T c superconducting films being a simple and inexpensive method. (author)

  20. Superconductivity in disordered thin films

    International Nuclear Information System (INIS)

    Ramakrishnan, T.V.

    1989-01-01

    The physics of low-dimensional systems has developed in a remarkable way over the last decade and has accelerated over the last few years, in particular because of the discovery of the new high temperature superconductors. The new developments started more than fifteen years ago with the discovery of the unexpected quasi-one-dimensional character of the TTF-TCNQ. Since then the field of conducting quasi-one-dimensional organic system have been rapidly growing. Parallel to the experimental work there has been an important theoretical development of great conceptual importance, such as charge density waves, soliton-like excitations, fractional charges, new symmetry properties etc. A new field of fundamental importance was the discovery of the Quantum Hall Effect in 1980. This field is still expanding with new experimental and theoretical discoveries. In 1986, then, came the totally unexpected discovery of high temperature superconductivity which started an explosive development. The three areas just mentioned formed the main themes of the Symposium. They do not in any way exhaust the progress in low-dimensional physics. We should mention the recent important development with both two-dimensional and one-dimensional and even zero-dimensional structures (quantum dots). The physics of mesoscopic systems is another important area where the low dimensionality is a key feature. Because of the small format of this Symposium we could unfortunately not cover these areas

  1. Ferromagnetic Film on a Superconducting Substrate

    OpenAIRE

    Bulaevskii, L. N.; Chudnovsky, E. M.

    2000-01-01

    We study the equilibrium domain structure and magnetic flux around a ferromagnetic (FM) film with perpendicular magnetization M_0 on a superconducting (SC) substrate. At 4{\\pi}M_0> 1. Here \\lambda_L is the London penetration length. For 4{\\pi}M_0 > H_{c1} and l_{N} in excess of about 35 {\\lambda}_{L}, the domains are connected by SC vortices. We argue that pinning of vortices by magnetic domains in FM/SC multilayers can provide high critical currents.

  2. Critical currents in multilayered superconducting films

    International Nuclear Information System (INIS)

    Raffy, Helene

    1977-01-01

    The superconducting critical currents Isub(c) were measured as a function of magnetic field H and temperature T, on multilayered films. These films consist of alternating layers of two different superconductors S 1 and S 2 being a weaker superconductor acting as a flux pinning barrier region. A strong anisotropy was observed between the two situations where the magnetic field H is applied parallel or perpendicular to the layers. In the case discussed, there is a peak effect in the curves Isub(c)H well defined at the highest temperatures, and disappearing at low temperatures. The anisotropy of the critical current at constant field presents a maximum at a temperature T* close to the critical temperature Tsub(c 2 ) of S 2 [fr

  3. Superconducting properties of iron chalcogenide thin films

    Directory of Open Access Journals (Sweden)

    Paolo Mele

    2012-01-01

    Full Text Available Iron chalcogenides, binary FeSe, FeTe and ternary FeTexSe1−x, FeTexS1−x and FeTe:Ox, are the simplest compounds amongst the recently discovered iron-based superconductors. Thin films of iron chalcogenides present many attractive features that are covered in this review, such as: (i easy fabrication and epitaxial growth on common single-crystal substrates; (ii strong enhancement of superconducting transition temperature with respect to the bulk parent compounds (in FeTe0.5Se0.5, zero-resistance transition temperature Tc0bulk = 13.5 K, but Tc0film = 19 K on LaAlO3 substrate; (iii high critical current density (Jc ~ 0.5 ×106 A cm2 at 4.2 K and 0 T for FeTe0.5Se0.5 film deposited on CaF2, and similar values on flexible metallic substrates (Hastelloy tapes buffered by ion-beam assisted deposition with a weak dependence on magnetic field; (iv high upper critical field (~50 T for FeTe0.5Se0.5, Bc2(0, with a low anisotropy, γ ~ 2. These highlights explain why thin films of iron chalcogenides have been widely studied in recent years and are considered as promising materials for applications requiring high magnetic fields (20–50 T and low temperatures (2–10 K.

  4. Strong correlation between Jc(T, H||c) and Jc(77 K, 3 T||c) in Zr-added (Gd, Y)BaCuO coated conductors at temperatures from 77 down to 20 K and fields up to 9 T

    International Nuclear Information System (INIS)

    Xu, A; Delgado, L; Heydari Gharahcheshmeh, M; Khatri, N; Liu, Y; Selvamanickam, V

    2015-01-01

    We have conducted a critical current density J c (T, H) study over a wide temperature T from 77 down to 20 K and a magnetic field H up to 9 T on more than 50 ∼ 0.9 μm-thick REBa 2 Cu 3 O 7−δ (RE = rare earth) thin films containing different concentrations of BaZrO 3 (BZO). We found that, independent of the composition, there is a linear correlation between J c (77 K, 3 T||c) and J c (T, H||c) at T down to 20 K and H up to 9 T. Moreover, J c (77 K, 3 T||c) is also linearly correlated to J c (T, H||ab) below 40 K. We ascribed this linear correlation to the dominant pinning source of BZO nanorods, which act as a strong correlated pinning at T above ∼30 K and provide weak uncorrelated point pins at lower temperatures. Our result emphasizes that J c (77 K, 3 T||c) is a key metric for metal-organic chemical vapor deposited REBa 2 Cu 3 O 7−δ coated conductors. (fast track communication)

  5. Disappearance of superconductivity and critical resistance in thin indium films

    International Nuclear Information System (INIS)

    Okuma, Satoshi; Nishida, Nobuhiko

    1991-01-01

    In thin granular films composed of two-dimensionally coupled indium particles, we have studied influences of average particle sizes anti d on the superconducting transition. For films with anti d=280A and 224A, superconducting transition temperature stays almost constant with increasing the sheet resistance R n in the normal state, while for a film with anti d=140A, it decreases linearly with R n . This means that the system changes to a dirty superconductor by reducing anti d. With further increasing R n , superconductivity disappears when R n exceeds the value R c of order h/4e 2 , which seems to correlate with anti d. (orig.)

  6. Fluctuation conductivity of thin superconductive vanadium films

    International Nuclear Information System (INIS)

    Dmitrenko, I.M.; Sidorenko, A.S.; Fogel, N.Y.

    1982-01-01

    Resistive transitions into the superconductive state are studied in thin [d >T/sub c/ the experimental data on the excess conductivity of the films agree qualitatively and quantitively with Aslamazov--Larkin theory. There is no Maki--Thompson contribution to fluctuation conductivity. Near T/sub c/ the excess conductivity sigma' changes exponentially with temperature in accordance with the predictions of the theory of the critical fluctuations of the order parameter. The values of the effective charge carrier mass defined from data on sigma' for the low fluctuation and critical fluctuation regions differ markedly. This difference is within the spread of effective masses for various charge carrier groups already known for vanadium. Causes of the difference in resistive behavior for the regions T >T/sub c/ are considered

  7. Comment on ``Ferromagnetic film on a superconducting substrate''

    Science.gov (United States)

    Sonin, E. B.

    2002-10-01

    A superconducting substrate is not able to shrink drastically domains in a ferromagnetic film, contrary to the prediction of Bulaevskii and Chudnovsky. This is shown on the basis of the exact solution for the stripe domain structure.

  8. Properties of superconducting thin-film microbridges

    International Nuclear Information System (INIS)

    Pei, S.S.

    1978-01-01

    This work reports investigations upon the dependences of critical current and current phase relation on the dimensions of a superconducting thin-film microbridge. A model has been developed upon the Volkov's hyperbolic bridges and the Zaitsev's boundary conditions to calculate the spatial variation of the order parameter for given bridge dimensions. The results indicate that the rigid boundary conditions are good approximations to narrow bridges (W much less than L) only. The critical current density of the bridge has been calculated also as a function of the bridge dimensions. It is found that the critical current density of small bridges is enhanced above its mean field critical value due to the proximity effects of the banks. Very good agreement is found between the calculated enhancement of the critical current density and the experimental results. Direct measurements have been made on the current phase relation of indium bridges with width smaller than 0.6 μm. The difficulties due to the extra phase shifts from the series thin film electrodes are overcome by a specially designed double loop configuration which has an extra low effective inductance. It is found that the current phase relation of small bridges (W,L, xi, the results agree with the predictions of rigid boundary calculations as expected by our model

  9. Analytical control of HTSC chemical composition of Y-Ba-Cu-O system

    International Nuclear Information System (INIS)

    Rojzenblat, E.M.; Kuchkina, E.D.; Bondarenko, S.K.; Ivanova, K.P.; Prisedskij, V.V.

    1989-01-01

    Methods for determining the cation composition and oxygen nonstoichiometry of YBa 2 Cu 3 O 6+δ superconductors are developed. Barium is determined in the form of BaSO 4 by the gravimetric method. Yttrium is determined using complexometry at pH=5.5 with a xylenol orange indicator in the presence of unithiol. Copper is determined using iodometry. Depending on conditions of analysis, it provides to determine both the total copper content in the sample and its oxygen nonstoichiometry. The method for determining the composition and structure of the studied ceramics according to the analysis of gas evolution from specimens during their dissolution in acids is described. The method of X-ray fluorescence analysis of ceramics cation composition is developed as well

  10. Positron annihilation study on Y-Ba-Cu-O high Tc superconductors

    International Nuclear Information System (INIS)

    Balogh, A.G.; Liszkay, L.; Molnar, B.; Puff, W.

    1987-08-01

    First positron annihilation measurements are reported on high T c superconductor YBa 2 Cu 3 O 7-x . The lifetime and Doppler broadening spectra show a slight but significant change about 240K suggesting a deviation from the normal structure far above 90K where the resistance falls to zero. (author)

  11. Development of Y-BA-CU-O Coated Conductor Using Metal Organic Chemical Vapor Deposition

    National Research Council Canada - National Science Library

    Selvamanickam, V

    2003-01-01

    .... The program includes a study of the a) influence of MOCVD processing conditions such as the flow rate of precursor vapors, precursor vaporization temperatures, oxygen partial pressure, reactor pressure, and the deposition temperature...

  12. Magnetic penetration depth δ o and critical current density in Y-BA-Cu-O crystals

    International Nuclear Information System (INIS)

    Zavaritsky, N.V.; Zavaritsky, V.N.

    1989-01-01

    Magnetic penetration depthδ o ∼1.03 10 - 5 cm and critical current density (j c = 0.5 divided-by 1 x 10 5 A/cm 2 at T/T ∼0.98) are determined from low-field do magnetization measurements on Y 1 Ba 2 Cu 3 O 7 - crystals

  13. NbN thin films for superconducting radio frequency cavities

    Science.gov (United States)

    Roach, W. M.; Skuza, J. R.; Beringer, D. B.; Li, Z.; Clavero, C.; Lukaszew, R. A.

    2012-12-01

    NbN thin films have the potential to be incorporated into radio frequency cavities in a multilayer coating to overcome the fundamental field gradient limit of 50 MV m-1 for the bulk niobium based technology that is currently implemented in particle accelerators. In addition to having a larger critical field value than bulk niobium, NbN films develop smoother surfaces which are optimal for cavity performance and lead to fewer losses. Here, we present a study on the correlation of film deposition parameters, surface morphology, microstructure, transport properties and superconducting properties of NbN thin films. We have achieved films with bulk-like lattice parameters and superconducting transition temperatures. These NbN films have a lower surface roughness than similarly grown niobium films of comparable thickness. The potential application of NbN thin films in accelerator cavities is discussed.

  14. NbN thin films for superconducting radio frequency cavities

    International Nuclear Information System (INIS)

    Roach, W M; Clavero, C; Lukaszew, R A; Skuza, J R; Beringer, D B; Li, Z

    2012-01-01

    NbN thin films have the potential to be incorporated into radio frequency cavities in a multilayer coating to overcome the fundamental field gradient limit of 50 MV m −1 for the bulk niobium based technology that is currently implemented in particle accelerators. In addition to having a larger critical field value than bulk niobium, NbN films develop smoother surfaces which are optimal for cavity performance and lead to fewer losses. Here, we present a study on the correlation of film deposition parameters, surface morphology, microstructure, transport properties and superconducting properties of NbN thin films. We have achieved films with bulk-like lattice parameters and superconducting transition temperatures. These NbN films have a lower surface roughness than similarly grown niobium films of comparable thickness. The potential application of NbN thin films in accelerator cavities is discussed. (paper)

  15. Superconducting properties of clustered PbBi films

    International Nuclear Information System (INIS)

    Lobb, C.J.; Tinkham, M.; Klapwijk, T.M.; Smith, A.D.; Harvard Univ., Cambridge, MA

    1981-01-01

    Superconducting films with high resistance/square have been widely studied as a model of the Kosterlitz-Thouless transition. We show that the behavior of high R clean films near the thickness at which electrical conduction begins is dominated by a few paths across the film and thus should not be interpreted as a Kosterlitz-Thouless transition. Instead, this behavior is consistent with a simple percolation model for the connectivity fluctuations across the film. (orig.)

  16. Intrinsic and experimental quasiparticle recombination times in superconducting films

    International Nuclear Information System (INIS)

    Eisenmenger, W.; Lassmann, K.; Trumpp, H.J.; Krauss, R.

    1977-01-01

    Experimental quasiparticle recombination lifetime data for superconducting Al, Sn, and Pb films are compared with calculations based on a ray acoustic model taking account of the film thickness dependence of the reabsorption of recombination phonons. Information on the true or intrinsic quasiparticle recombination lifetime obtained from these and other data is discussed. (orig.) [de

  17. Preparation of YBCO superconducting films by spray pyrolysis method

    International Nuclear Information System (INIS)

    Mora Alonso, M.; Leyva Fabelo, A.; Rubio Frias, E.; Pupo Gonzalez, I.; Lopez Sanchez, D.

    1994-01-01

    The methodology for the preparation of YBCO superconducting films on Zr 2O (Y) substrates by spray pyrolysis method is reported. The transition temperature of these films is superior than the boiling temperature of liquid 2N . Other critical parameters are similar to those reported by other authors using the same technique

  18. Realization of superconductive films by screen printing

    International Nuclear Information System (INIS)

    Baudry, H.

    1988-01-01

    Screen printing is a promising method to manufacture superconductive lines making use of superconductive ceramics. An ink has been realized with YBa 2 Cu 3 0 7-x' and the process conditions defined by thermal analysis. A superconductive transition is observed after screen printing on MgO. The firing of the layer is made at 920 0 C followed by a reoxidation step at 420 0 C. The silver electrical contacts are also screen printed [fr

  19. Magnetic Field Enhanced Superconductivity in Epitaxial Thin Film WTe2.

    Science.gov (United States)

    Asaba, Tomoya; Wang, Yongjie; Li, Gang; Xiang, Ziji; Tinsman, Colin; Chen, Lu; Zhou, Shangnan; Zhao, Songrui; Laleyan, David; Li, Yi; Mi, Zetian; Li, Lu

    2018-04-25

    In conventional superconductors an external magnetic field generally suppresses superconductivity. This results from a simple thermodynamic competition of the superconducting and magnetic free energies. In this study, we report the unconventional features in the superconducting epitaxial thin film tungsten telluride (WTe 2 ). Measuring the electrical transport properties of Molecular Beam Epitaxy (MBE) grown WTe 2 thin films with a high precision rotation stage, we map the upper critical field H c2 at different temperatures T. We observe the superconducting transition temperature T c is enhanced by in-plane magnetic fields. The upper critical field H c2 is observed to establish an unconventional non-monotonic dependence on temperature. We suggest that this unconventional feature is due to the lifting of inversion symmetry, which leads to the enhancement of H c2 in Ising superconductors.

  20. Pulsed laser deposition and characterisation of thin superconducting films

    Energy Technology Data Exchange (ETDEWEB)

    Morone, A [CNR, zona industriale di Tito Scalo, Potenza (Italy). Istituto per i Materiali Speciali

    1996-09-01

    Same concepts on pulsed laser deposition of thin films will be discussed and same examples of high transition temperature (HTc) BiSrCaCuO (BISCO) and low transition temperature NbN/MgO/NbN multilayers will be presented. X-ray and others characterizations of these films will be reported and discussed. Electrical properties of superconducting thin films will be realized as a function of structural and morphological aspect.

  1. Micropatterned superconducting film circuitry for operation in hybrid quantum devices

    International Nuclear Information System (INIS)

    Bothner, Daniel

    2013-01-01

    This thesis discusses three aspects of the arduous way towards hybrid quantum systems consisting of superconducting circuits and ensembles of ultracold paramagnetic atoms. In the first part of the thesis, superconducting coplanar microwave resonators as used for quantum information processing with superconducting qubits are investigated in magnetic fields. In the second part of the thesis integrated atom chips are designed and fabricated, which offer the possibility to trap an ensemble of ultracold atoms close to a superconducting coplanar resonator on that chip. In the third and last part of the thesis, unconventional disordered and quasiperiodic arrangements of microfabricated holes (antidots) in superconducting films are patterned and investigated with respect to the impact of the arrangement on the superconductor transport properties in magnetic fields.

  2. New Fast Response Thin Film-Based Superconducting Quench Detectors

    CERN Document Server

    Dudarev, A; van de Camp, W; Ravaioli, E; Teixeira, A; ten Kate, H H J

    2014-01-01

    Quench detection on superconducting bus bars and other devices with a low normal zone propagation velocity and low voltage build-up is quite difficult with conventional quench detection techniques. Currently, on ATLAS superconducting bus bar sections, superconducting quench detectors (SQD) are mounted to detect quench events. A first version of the SQD essentially consists of an insulated superconducting wire glued to a superconducting bus line or windings, which in the case of a quench rapidly builds up a relatively high resistance that can be easily and quietly detected. We now introduce a new generation of drastically improved SQDs. The new version makes the detection of quenches simpler, more reliable, and much faster. Instead of a superconducting wire, now a superconducting thin film is used. The layout of the sensor shows a meander like pattern that is etched out of a copper coated 25 mu m thick film of Nb-Ti glued in between layers of Kapton. Since the sensor is now much smaller and thinner, it is easi...

  3. Quenching of superconductivity in disordered thin films by phase fluctuations

    International Nuclear Information System (INIS)

    Hebard, A.F.; Palaanen, M.A.

    1992-01-01

    The amplitude Ψ 0 and phase Φ of the superconducting order parameter in thin-film systems are affected differently by disorder and dimensionality. With increasing disorder superconducting long range order is quenched in sufficiently thin films by physical processes driven by phase fluctuations. This occurs at both the zero-field vortex-antivortex unbinding transition and at the zero-temperature magnetic-field-tuned superconducting-insulating transition. At both of these transitions Ψ 0 is finite and constant, vanishing only when temperature, disorder, and/or magnetic field are increased further. Experimental results on amorphous-composite InO x films are presented to illustrate these points and appropriate comparisons are made to other experimental systems. (orig.)

  4. Synthesis of high-temperature superconducting oxides and chemical alloying in Cu-O planes

    International Nuclear Information System (INIS)

    Tarascon, J.M.; Barboux, P.; Bagley, B.G.; Green, L.H.; Mckinnon, W.R.; Hull, G.W.

    1988-01-01

    Some methods for synthesis permitting to fabricate dense superconducting ceramics are considered. The Zole-Hell method is the most perspective one among them. Effect of oxygen content in a sample and copper substitution for nickel and zinc on structural, transition and superconducting properties of samples of the La-Sr-Cu-O(1) and Y-Ba-Cu-O(2) systems is studied. Copper substitution is established to suppress superconductivity in system 1 and to decrease T c in system 2, and this effect doesn't depend on the fact whether the substituting 3d-metal is magnetic (nickel) or diamagnetic (zinc). Detailed study of YBa 2 Cu 3 O 7-y properties as a function of oxygen content has shown that superconductivty in this composition can be suppressed as a result of oxygen removal and it can be reduced with its interoduction. The possibility to prepare nonalloyed La 2 CuO 4 in superconducting state as a result of plasma treatment comprises a scientific interest. 27 refs.; 5 figs.; 1 tab

  5. Microwave Josephson generation in thin film superconducting bridges

    International Nuclear Information System (INIS)

    Gubankov, V.N.; Koshelets, V.P.; Ovsyannikov, G.A.

    1975-01-01

    Thin-film bridges have some advantage over other types of superconducting weak links: good definition of electromagnetic parameters and of weak region geometry. Up to now Josephson properties of bridges have been investigated by using indirect methods (the effect of magnetic field on the critical current I 0 , the bridge behavior in a microwave field, etc.). Direct experimental observation of Josephson radiation from autonomous thin film bridges is reported. Microwave radiation in tin bridges of 'variable' thickness has been investigated where the thickness of the film forming the bridge is far less than the thickness of the bank films. (Auth.)

  6. Nb3Ge superconductive films grown with nitrogen

    International Nuclear Information System (INIS)

    Sigsbee, R.A.

    1978-01-01

    A superconductive film of Nb 3 Ge is produced by providing within a vacuum chamber a heated substrate and sources of niobium and germanium, reducing the pressure within the chamber to a residual pressure no greater than about 10 -5 mm Hg, introducing nitrogen into the resulting evacuated chamber in controlled amounts and vaporizing the niobium and germanium to deposit a film of Nb 3 Ge on the heated substrate

  7. Tunneling probe of fluctuating superconductivity in disordered thin films

    Science.gov (United States)

    Dentelski, David; Frydman, Aviad; Shimshoni, Efrat; Dalla Torre, Emanuele G.

    2018-03-01

    Disordered thin films close to the superconductor-insulator phase transition (SIT) hold the key to understanding quantum phase transition in strongly correlated materials. The SIT is governed by superconducting quantum fluctuations, which can be revealed, for example, by tunneling measurements. These experiments detect a spectral gap, accompanied by suppressed coherence peaks, on both sides of the transition. Here we describe the insulating side in terms of a fluctuating superconducting field with finite-range correlations. We perform a controlled diagrammatic resummation and derive analytic expressions for the tunneling differential conductance. We find that short-range superconducting fluctuations suppress the coherence peaks even in the presence of long-range correlations. Our approach offers a quantitative description of existing measurements on disordered thin films and accounts for tunneling spectra with suppressed coherence peaks.

  8. Spatial characterization of the edge barrier in wide superconducting films

    Science.gov (United States)

    Sivakov, A. G.; Turutanov, O. G.; Kolinko, A. E.; Pokhila, A. S.

    2018-03-01

    The current-induced destruction of superconductivity is discussed in wide superconducting thin films, whose width is greater than the magnetic field penetration depth, in weak magnetic fields. Particular attention is paid to the role of the boundary potential barrier (the Bin-Livingston barrier) in critical state formation and detection of the edge responsible for this critical state with different mutual orientations of external perpendicular magnetic field and transport current. Critical and resistive states of the film were visualized using the space-resolving low-temperature laser scanning microscopy (LTLSM) method, which enables detection of critical current-determining areas on the film edges. Based on these observations, a simple technique was developed for investigation of the critical state separately at each film edge, and for the estimation of residual magnetic fields in cryostats. The proposed method only requires recording of the current-voltage characteristics of the film in a weak magnetic field, thus circumventing the need for complex LTLSM techniques. Information thus obtained is particularly important for interpretation of studies of superconducting film single-photon light emission detectors.

  9. Size and dimensionality effects in superconducting Mo thin films

    International Nuclear Information System (INIS)

    Fabrega, L; Gil, O; Camon, A; Parra-BorderIas, M; Fernandez-MartInez, I; Costa-Kraemer, J L; Briones, F; Sese, J; Gonzalez-Arrabal, R

    2011-01-01

    Molybdenum is a low T c , type I superconductor whose fundamental properties are poorly known. Its importance as an essential constituent of new high performance radiation detectors, the so-called transition edge sensors (TESs) calls for better characterization of this superconductor, especially in thin film form. Here we report on a study of the basic superconducting features of Mo thin films as a function of their thickness. The resistivity is found to rise and the critical temperature decreases on decreasing film thickness, as expected. More relevant, the critical fields along and perpendicular to the film plane are markedly different, thickness dependent and much larger than the thermodynamic critical field of Mo bulk. These results are consistent with a picture of type II 2D superconducting films, and allow estimates of the fundamental superconducting lengths of Mo. The role of morphology in determining the 2D and type II character of the otherwise type I molybdenum is discussed. The possible consequences of this behaviour on the performance of radiation detectors are also addressed.

  10. Pulsed laser deposition of high Tc superconducting thin films

    International Nuclear Information System (INIS)

    Singh, R.K.; Narayan, J.

    1990-01-01

    This paper reports on the pulsed laser evaporation (PLE) technique for deposition of thin films characterized by a number of unique properties. Based on the experimental characteristics, a theoretical model is developed which considers the formation and anisotropic three dimensional expansion of the laser generated plasma. This model explains most of the experimental features observed in PLE. We have also employed the PLE technique for in-situ fabrication of YBa 2 Cu 3 O 7 superconducting thin films on different substrates in the temperature range of 500--650 degrees C. At temperatures below 600 degrees C, a biased interposing ring between the substrate and the target was found to significantly improve the superconducting properties. The minimum ion channeling yields were between 3--3.5% for films deposited on (100) SrTiO 3 and (100) LaAlO 3 substrates

  11. A Method for Suppressing Superconductivity of Thin Films

    Science.gov (United States)

    Suppula, Tarmo; Pekola, Jukka; Kauppinen, Juha

    2003-03-01

    We have developed a method for suppressing superconductivity of thin films. Thin stripes of cobalt grown by e-gun evaporation and patterned by e-beam lithography were placed in the vicinity of aluminium thin film structures. The cobalt stripes were magnetized at 4.2 K with a superconducting coil and the remanence suppressed superconductivity of the Al stripe at temperatures down to 50 mK at least. The magnetization remained in thermal cycling and in a longer storage at room temperature. Motivation for this work is the Coulomb Blockade Thermometer(CBT)^1 which has to be in a normal state to operate. The CBT sensor contains aluminium which is superconducting at temperatures below 1.4 K. An external magnetic field is not always available or acceptable in cryostats. A small grain of permanent magnet mounted to the sensor is another solution, but suspicious if the sensor is put in strong magnetic fields or if "zero field" environment is required. We have shown that suitably patterned and magnetized Co stripes in the vicinity of tunnel junctions of the CBT can solve this problem. The amount of magnetic material in the sensor, as well as the stray field, is very small. This technique may be useful in other low temperature thin film devices also. 1) Product of Nanoway Ltd.

  12. THz spectroscopy on superconducting NbN thin films

    Energy Technology Data Exchange (ETDEWEB)

    Daschke, Lena; Pracht, Uwe S.; Dressel, Martin; Scheffler, Marc [1. Physikalisches Institut, Universitaet Stuttgart (Germany); Ilin, Konstantin S.; Siegel, Michael [Institut fuer Mikro- und Nanoelektronische Systeme, Karlsruher Institut fuer Technologie (Germany)

    2015-07-01

    Epitaxial thin-film niobium nitride (NbN) is a conventional BCS superconductor. In presence of strong disorder, however, electronic inhomogeneities appear, which is not fully understood yet. To obtain a better insight into the physics of such disordered materials, studies on model systems such as structurally tailored films might be useful. Furthermore, disordered NbN films are used for single-photon detection devices, whose proper performance depends on a profound understanding of the superconducting properties. The studied NbN films have a T{sub c} ranging from 10 to 15 K and the superconducting energy gap is easily accessible with THz spectroscopy (0.4 - 5.6 meV). We investigate thin films of NbN sputtered on a sapphire substrate. With a Mach-Zehnder interferometer we measure the amplitude and phase shift of radiation transmitted through the thin-film sample. From there we can determine the real and imaginary parts of the optical conductivity. These results give information about the energy gap, Cooper pair density, and quasiparticle dynamics, including the temperature evolution of these quantities. We found that a film with 10 nm thickness roughly follows the BCS behavior, as expected. We will present results of our measurements on several different NbN samples.

  13. Superconducting parameters of polycrystalline niobium films

    International Nuclear Information System (INIS)

    Kandyba, P.E.; Kolesnikov, D.P.; Tkachev, V.A.

    1978-01-01

    The niobium semi-crystalline films, having a thickness of 200-5,050 A have been studied. The films have been produced by the electron-beam evaporation in the oilless vacuum and by the ionic plasma spraying with diode and triode methods. Determined have been the coherence length, the magnetic field penetration depth and the Ginsburg-andau parameter. An attempt is made to determine the electron states density of the Fermi surface

  14. Vortex variable range hopping in a conventional superconducting film

    Science.gov (United States)

    Percher, Ilana M.; Volotsenko, Irina; Frydman, Aviad; Shklovskii, Boris I.; Goldman, Allen M.

    2017-12-01

    The behavior of a disordered amorphous thin film of superconducting indium oxide has been studied as a function of temperature and magnetic field applied perpendicular to its plane. A superconductor-insulator transition has been observed, though the isotherms do not cross at a single point. The curves of resistance versus temperature on the putative superconducting side of this transition, where the resistance decreases with decreasing temperature, obey two-dimensional Mott variable-range hopping of vortices over wide ranges of temperature and resistance. To estimate the parameters of hopping, the film is modeled as a granular system and the hopping of vortices is treated in a manner analogous to hopping of charges. The reason the long-range interaction between vortices over the range of magnetic fields investigated does not lead to a stronger variation of resistance with temperature than that of two-dimensional Mott variable-range hopping remains unresolved.

  15. Two-dimensional superconductivity in ultrathin disordered thin films

    International Nuclear Information System (INIS)

    Beasley, M.R.

    1992-01-01

    The status of the understanding of two-dimensional superconductivity in ultrathin, disordered thin films is reviewed. The different consequences of microscopic versus macroscopic disorder are stressed. It is shown that microscopic disorder leads to a rapid suppression of the mean-field transition temperature. The consequences of macroscopic disorder are not well understood, but a universal behavior of the zero-bias resistance as a function of field and temperature has been observed. (orig.)

  16. Vortex imaging in superconducting films by scanning Hall probe microscopy

    International Nuclear Information System (INIS)

    Oral, A.; Bending, S.J.; Humphreys, R.G.

    1996-01-01

    The authors have used a low noise Scanning Hall Probe Microscope (SHPM) to study vortex structures in superconducting films. The microscope has high magnetic field (∼2.9 x 10 -8 T/√Hz at 77K) and spatial resolution, ∼0.85 μm. Magnetic field profiles of single vortices in High T c YBa 2 Cu 3 O 7-δ thin films have been successfully measured and the microscopic penetration depth of the superconductor has been extracted as a function of temperature. Flux penetration into the superconductor has been imaged in real time (∼8s/frame)

  17. RF Characterization of Niobium Films for Superconducting Cavities

    CERN Document Server

    Aull† , S; Doebert, S; Junginger, T; Ehiasarian, AP; Knobloch, J; Terenziani, G

    2013-01-01

    The surface resistance RS of superconductors shows a complex dependence on the external parameters such as temperature, frequency or radio-frequency (RF) field. The Quadrupole Resonator modes of 400, 800 and 1200 MHz allow measurements at actual operating frequencies of superconducting cavities. Niobium films on copper substrates have several advantages over bulk niobium cavities. HIPIMS (High-power impulse magnetron sputtering) is a promising technique to increase the quality and therefore the performance of niobium films. This contribution will introduce CERNs recently developed HIPIMS coating apparatus. Moreover, first results of niobium coated copper samples will be presented, revealing the dominant loss mechanisms.

  18. Fractional flux excitations and flux creep in a superconducting film

    International Nuclear Information System (INIS)

    Lyuksyutov, I.F.

    1995-01-01

    We consider the transport properties of a modulated superconducting film in a magnetic field parallel to the film. Modulation can be either intrinsic, due to the layered structure of the high-T c superconductors, or artificial, e.g. due to thickness modulation. This system has an infinite set ( >) of pinned phases. In the pinned phase the excitation of flux loops with a fractional number of flux quanta by the applied current j results in flux creep with a generated voltage V ∝ exp[-jo/j[. (orig.)

  19. Contrasting dynamic spin susceptibility models and their relation to high-temperature superconductivity

    International Nuclear Information System (INIS)

    Schuettler, H.; Norman, M.R.

    1996-01-01

    We compare the normal-state resistivities ρ and the critical temperatures T c for superconducting d x 2 -y 2 pairing due to antiferromagnetic (AF) spin fluctuation exchange in the context of two phenomenological dynamical spin susceptibility models for the cuprate high-T c materials, one based on fits to NMR data on Y-Ba-Cu-O (YBCO) proposed by Millis, Monien, and Pines (MMP) and Monthoux and Pines (MP), and the other based on fits to neutron scattering data on YBCO proposed by Radtke, Ullah, Levin, and Norman (RULN). Assuming comparable electronic bandwidths and resistivities in both models, we show that the RULN model gives a much lower d-wave T c (approx-lt 20 K) than the MMP model (with T c ∼100 K). We demonstrate that these profound differences in the T c close-quote s arise from fundamental differences in the spectral weight distributions of the two model susceptibilities at high (>100 meV) frequencies and are not primarily caused by differences in the calculational techniques employed by MP and RULN. Further neutron scattering experiments, to explore the spectral weight distribution at all wave vectors over a sufficiently large excitation energy range, will thus be of crucial importance to resolve the question whether AF spin fluctuation exchange can provide a viable mechanism to account for high-T c superconductivity. Limitations of the Migdal-Eliashberg approach in such models will be discussed. copyright 1996 The American Physical Society

  20. Local imaging of magnetic flux in superconducting thin films

    Energy Technology Data Exchange (ETDEWEB)

    Shapoval, Tetyana

    2010-01-26

    Local studies of magnetic flux line (vortex) distribution in superconducting thin films and their pinning by natural and artificial defects have been performed using low-temperature magnetic force microscopy (LT-MFM). Taken a 100 nm thin NbN film as an example, the depinning of vortices from natural defects under the influence of the force that the MFM tip exerts on the individual vortex was visualized and the local pinning force was estimated. The good agreement of these results with global transport measurements demonstrates that MFM is a powerful and reliable method to probe the local variation of the pinning landscape. Furthermore, it was demonstrated that the presence of an ordered array of 1-{mu}m-sized ferromagnetic permalloy dots being in a magneticvortex state underneath the Nb film significantly influences the natural pinning landscape of the superconductor leading to commensurate pinning effects. This strong pinning exceeds the repulsive interaction between the superconducting vortices and allows vortex clusters to be located at each dot. Additionally, for industrially applicable YBa{sub 2}Cu{sub 3}O{sub 7-{delta}} thin films the main question discussed was the possibility of a direct correlation between vortices and artificial defects as well as vortex imaging on rough as-prepared thin films. Since the surface roughness (droplets, precipitates) causes a severe problem to the scanning MFM tip, a nanoscale wedge polishing technique that allows to overcome this problem was developed. Mounting the sample under a defined small angle results in a smooth surface and a monotonic thickness reduction of the film along the length of the sample. It provides a continuous insight from the film surface down to the substrate with surface sensitive scanning techniques. (orig.)

  1. Local imaging of magnetic flux in superconducting thin films

    International Nuclear Information System (INIS)

    Shapoval, Tetyana

    2010-01-01

    Local studies of magnetic flux line (vortex) distribution in superconducting thin films and their pinning by natural and artificial defects have been performed using low-temperature magnetic force microscopy (LT-MFM). Taken a 100 nm thin NbN film as an example, the depinning of vortices from natural defects under the influence of the force that the MFM tip exerts on the individual vortex was visualized and the local pinning force was estimated. The good agreement of these results with global transport measurements demonstrates that MFM is a powerful and reliable method to probe the local variation of the pinning landscape. Furthermore, it was demonstrated that the presence of an ordered array of 1-μm-sized ferromagnetic permalloy dots being in a magneticvortex state underneath the Nb film significantly influences the natural pinning landscape of the superconductor leading to commensurate pinning effects. This strong pinning exceeds the repulsive interaction between the superconducting vortices and allows vortex clusters to be located at each dot. Additionally, for industrially applicable YBa 2 Cu 3 O 7-δ thin films the main question discussed was the possibility of a direct correlation between vortices and artificial defects as well as vortex imaging on rough as-prepared thin films. Since the surface roughness (droplets, precipitates) causes a severe problem to the scanning MFM tip, a nanoscale wedge polishing technique that allows to overcome this problem was developed. Mounting the sample under a defined small angle results in a smooth surface and a monotonic thickness reduction of the film along the length of the sample. It provides a continuous insight from the film surface down to the substrate with surface sensitive scanning techniques. (orig.)

  2. Quasi-One-Dimensional Intermittent Flux Behavior in Superconducting Films

    Directory of Open Access Journals (Sweden)

    A. J. Qviller

    2012-01-01

    Full Text Available Intermittent filamentary dynamics of the vortex matter in superconductors is found in films of YBa_{2}Cu_{3}O_{7-δ} deposited on tilted substrates. Deposition of this material on such substrates creates parallel channels of easy flux penetration when a magnetic field is applied perpendicular to the film. As the applied field is gradually increased, magneto-optical imaging reveals that flux penetrates via numerous quasi-one-dimensional jumps. The distribution of flux avalanche sizes follows a power law, and data collapse is obtained by finite-size scaling, with the depth of the flux front used as crossover length. The intermittent behavior shows no threshold value in the applied field, in contrast to conventional flux jumping. The results strongly suggest that the quasi-one-dimensional flux jumps are of a different nature than the thermomagnetic dendritic (branching avalanches that are commonly found in superconducting films.

  3. Hall effect of K-doped superconducting thin films

    Energy Technology Data Exchange (ETDEWEB)

    Son, Eunseon; Lee, Nam Hoon; Kang, Won Nam [Dept. of physics, Sungkyunkwan University, Suwon (Korea, Republic of); Hwang, Tae Jong; Kim, Dong Ho [Dept. of physics, Yeungnam University, Gyeongsan(Korea, Republic of)

    2013-09-15

    We have studied Hall effect for potassium (K)-doped BaFe{sub 2}As{sub 2}superconducting thin films by analyzing the relation between the longitudinal resistivity (ρ{sub xy}) and the Hall resistivity (ρ{sub xy}). The thin films used in this study were fabricated on Al{sub O3} (000l) substrates by using an ex-situ pulsed laser deposition (PLD) technique under a high-vacuum condition of ∼10{sup -6} Torr. The samples showed the high superconducting transition temperatures (T{sub C}) of ∼40 K. The ρ{sub xx} and ρ{sub xy}the for K-doped BaFeAs{sub 2} thin films were measured by using a physical property measurement system (PPMS) with a temperature sweep (T-sweep) mode at an applied current density of 100 A/cm{sup 2} and at magnetic fields from 0 up to 9 T. We report the T-sweep results of the ρ{sub xx} and the ρ{sub xy} to investigate Hall scaling behavior on the basis of the relation of ρ{sub xy} = A(ρ{sub xy}){sup β}. The ρ{sub xx} values are 3.0 ± 0.2 in the c-axis-oriented K-doped BaFeAs{sub 2} thin films, whereas the thin films with various oriented-directions like a polycrystal showed slightly lower β than that of c-axis-oriented thin films. Interestingly, the β value is decreased with increasing magnetic fields.

  4. Quantitative MFM on superconducting thin films

    Energy Technology Data Exchange (ETDEWEB)

    Stopfel, Henry; Vock, Silvia; Shapoval, Tetyana; Neu, Volker; Wolff, Ulrike; Haindl, Silvia; Engelmann, Jan; Schaefer, Rudolf; Holzapfel, Bernhard; Schultz, Ludwig [IFW Dresden, Institute for Metallic Material (Germany); Inosov, Dmytro S. [Max Planck Institute for Solid State Research, Stuttgart (Germany)

    2012-07-01

    Quantitative interpretation of magnetic force microscopy (MFM) data is a challenge, because the measured signal is a convolution between the magnetization of the tip and the stray field emanated by the sample. It was established theoretically that the field distribution just above the surface of the superconductor can be well approximated by the stray field of a magnetic monopole. The description of the MFM tip, however, needs a second approximation. The temperature-dependent vortex-distribution images on a NbN thin film were fitted using two different tip models. Firstly, the magnetic tip was assumed to be a monopole that leads to the simple monopole-monopole model for the tip-sample interaction force. Performing a 2D fitting of the data with this model, we extracted λ, Δ and the vortex pinning force. Secondly, a geometrical model was applied to calculate the tip-transfer-function of the MFM tip using the numerical BEM method.

  5. Nano-engineered pinning centres in YBCO superconducting films

    Energy Technology Data Exchange (ETDEWEB)

    Crisan, A., E-mail: adrian.crisan@infim.ro [National Institute for Materials Physics Bucharest, 105 bis Atomistilor Str., 077125 Magurele (Romania); School of Metallurgy and Materials, University of Birmingham, Edgbaston, B15 2TT Birmingham (United Kingdom); Dang, V.S. [School of Metallurgy and Materials, University of Birmingham, Edgbaston, B15 2TT Birmingham (United Kingdom); Nano and Energy Center, VNU Hanoi University of Science, 334 Nguyen Trai, Thanh Xuan, Hanoi (Viet Nam); Mikheenko, P. [School of Metallurgy and Materials, University of Birmingham, Edgbaston, B15 2TT Birmingham (United Kingdom); Department of Physics, University of Oslo, P.O. Box 1048 Blindern, N-0316 Oslo (Norway)

    2017-02-15

    Highlights: • Power applications of YBCO films/coated conductors in technological relevant magnetic fields requires nano-engineered pinning centre. • Three approaches have been proposed: substrate decoration, quasi-multilayers, and targets with secondary phase nano-inclusions. • Combination of all three approaches greatly increased critical current in YBCO films. • Bulk pinning force, pinning potential, and critical current density are estimated and discussed in relation with the type and strength of pinning centres related to the defects evidenced by Transmission Electron Microscopy. - Abstract: For practical applications of superconducting materials in applied magnetic fields, artificial pinning centres in addition to natural ones are required to oppose the Lorentz force. These pinning centres are actually various types of defects in the superconductor matrix. The pinning centres can be categorised on their dimension (volume, surface or point) and on their character (normal cores or Δκ cores). Different samples have been produced by Pulsed Laser Deposition, with various thicknesses, temperatures and nanostructured additions to the superconducting matrix. They have been characterized by SQUID Magnetic Properties Measurement System and Physical Properties Measurement System, as well as by Transmission Electron Microscopy (TEM). Correlations between pinning architecture, TEM images, and critical currents at various fields and field orientations will be shown for a large number of YBa{sub 2}Cu{sub 3}O{sub x} films with various types and architectures of artificial pinning centres.

  6. Superconducting properties of Pb82Bi18 films controlled by ferromagnetic nanowire arrays

    International Nuclear Information System (INIS)

    Ye Zuxin; Lyuksyutov, Igor F; Wu Wenhao; Naugle, Donald G

    2011-01-01

    The superconducting properties of Pb 82 Bi 18 alloy films deposited on ferromagnetic nanowire arrays have been investigated. Ferromagnetic Co or Ni nanowires are first electroplated into the columnar pores of anodic aluminum oxide (AAO) membranes. Superconducting Pb 82 Bi 18 films are then quench condensed onto the polished surface of the AAO membranes filled with magnetic nanowires. A strong dependence of the Pb 82 Bi 18 superconducting properties on the ratio of the superconducting film thickness to the magnetic nanowire diameter and material variety was observed.

  7. Superconducting properties of Pb82Bi18 films controlled by ferromagnetic nanowire arrays

    Science.gov (United States)

    Ye, Zuxin; Lyuksyutov, Igor F.; Wu, Wenhao; Naugle, Donald G.

    2011-02-01

    The superconducting properties of Pb82Bi18 alloy films deposited on ferromagnetic nanowire arrays have been investigated. Ferromagnetic Co or Ni nanowires are first electroplated into the columnar pores of anodic aluminum oxide (AAO) membranes. Superconducting Pb82Bi18 films are then quench condensed onto the polished surface of the AAO membranes filled with magnetic nanowires. A strong dependence of the Pb82Bi18 superconducting properties on the ratio of the superconducting film thickness to the magnetic nanowire diameter and material variety was observed.

  8. Superconducting Properties of Lead-Bismuth Films Controlled by Ferromagnetic Nanowire Arrays

    Science.gov (United States)

    Ye, Zuxin; Lyuksyutov, Igor F.; Wu, Wenhao; Naugle, Donald G.

    2011-03-01

    Superconducting properties of lead-bismuth (82% Pb and 18% Bi) alloy films deposited on ferromagnetic nanowire arrays have been investigated. Ferromagnetic Co or Ni nanowires are first electroplated into the columnar pores of anodic aluminum oxide (AAO) membranes. Superconducting Pb 82 Bi 18 films are then quench-condensed onto the polished surface of the AAO membranes filled with magnetic nanowires. A strong dependence of the Pb 82 Bi 18 superconducting properties on the ratio of the superconducting film thickness to the magnetic nanowire diameter and the material variety was observed.

  9. Enhanced pinning in superconducting thin films with graded pinning landscapes

    Science.gov (United States)

    Motta, M.; Colauto, F.; Ortiz, W. A.; Fritzsche, J.; Cuppens, J.; Gillijns, W.; Moshchalkov, V. V.; Johansen, T. H.; Sanchez, A.; Silhanek, A. V.

    2013-05-01

    A graded distribution of antidots in superconducting a-Mo79Ge21 thin films has been investigated by magnetization and magneto-optical imaging measurements. The pinning landscape has maximum density at the sample border, decreasing linearly towards the center. Its overall performance is noticeably superior than that for a sample with uniformly distributed antidots: For high temperatures and low fields, the critical current is enhanced, whereas the region of thermomagnetic instabilities in the field-temperature diagram is significantly suppressed. These findings confirm the relevance of graded landscapes on the enhancement of pinning efficiency, as recently predicted by Misko and Nori [Phys. Rev. B 85, 184506 (2012)].

  10. Josephson soliton oscillators in a superconducting thin film resonator

    DEFF Research Database (Denmark)

    Holm, J.; Mygind, Jesper; Pedersen, Niels Falsig

    1993-01-01

    Josephson soliton oscillators integrated in a resonator consisting of two closely spaced coplanar superconducting microstrips have been investigated experimentally. Pairs of long 1-D Josephson junctions with a current density of about 1000 A/cm2 were made using the Nb-AlOx-Nb trilayer technique....... Different modes of half-wave resonances in the thin-film structure impose different magnetic field configurations at the boundaries of the junctions. The DC I-V characteristic shows zero-field steps with a number of resonator-induced steps. These structures are compared to RF-induced steps generated...

  11. Specific feature of critical fields of inhomogeneous superconducting films

    International Nuclear Information System (INIS)

    Glazman, L.I.; Dmitrenko, I.M.; Kolin'ko, A.E.; Pokhila, A.S.; Fogel', N.Ya.; Cherkasova, V.G.

    1988-01-01

    Experimental studies on thin vanadium films (d=250-400 A) have revealed anomaly in the temperature dependence of the upper critical field H cparallel (T), when H is parallel to the sample plane. At certain temperature T 0 the dependence H cparallel 2 (T) has a sharp kink separating two linear portions. The anomalous behaviour of H cparallel (T) of thin V films can be accounted for assuming the film separation into two parallel layers having different parameters (critical temperature T c , coherence length ξ, thickness d). At temperatures above and lower T 0 the dependence H cparallel (T) is mainly dependent on the characteristics of only one layer. The kink in the dependence H cparallel 2 (T) is due to a jump-like transition of the superconducting nucleus from one layer to the other at T c . The anomalous behaviour of the dependence H cparallel (T) is also observed in sandwiches consisting of two identical films separated with a high (about 30 A) dielectric interlayer; however, the transition from one linear portion to the other is smooth. In the case of identical films a specific crossover occurs if at T-T c the critical field H cparallel (T) coinsides with that for the layer of doubled thickness, then at lowering temperature H cparallel (T) asymptotically approaches the critical field of one layer. The calculation within the model described provides a good description for the experimental results

  12. Imaging of current distributions in superconducting thin film structures

    International Nuclear Information System (INIS)

    Doenitz, D.

    2006-01-01

    Local analysis plays an important role in many fields of scientific research. However, imaging methods are not very common in the investigation of superconductors. For more than 20 years, Low Temperature Scanning Electron Microscopy (LTSEM) has been successfully used at the University of Tuebingen for studying of condensed matter phenomena, especially of superconductivity. In this thesis LTSEM was used for imaging current distributions in different superconducting thin film structures: - Imaging of current distributions in Josephson junctions with ferromagnetic interlayer, also known as SIFS junctions, showed inhomogeneous current transport over the junctions which directly led to an improvement in the fabrication process. An investigation of improved samples showed a very homogeneous current distribution without any trace of magnetic domains. Either such domains were not present or too small for imaging with the LTSEM. - An investigation of Nb/YBCO zigzag Josephson junctions yielded important information on signal formation in the LTSEM both for Josephson junctions in the short and in the long limit. Using a reference junction our signal formation model could be verified, thus confirming earlier results on short zigzag junctions. These results, which could be reproduced in this work, support the theory of d-wave symmetry in the superconducting order parameter of YBCO. Furthermore, investigations of the quasiparticle tunneling in the zigzag junctions showed the existence of Andreev bound states, which is another indication of the d-wave symmetry in YBCO. - The LTSEM study of Hot Electron Bolometers (HEB) allowed the first successful imaging of a stable 'Hot Spot', a self-heating region in HEB structures. Moreover, the electron beam was used to induce an - otherwise unstable - hot spot. Both investigations yielded information on the homogeneity of the samples. - An entirely new method of imaging the current distribution in superconducting interference devices

  13. Thin Film Approaches to the SRF Cavity Problem: Fabrication and Characterization of Superconducting Thin Films

    Science.gov (United States)

    Beringer, Douglas B.

    Superconducting Radio Frequency (SRF) cavities are responsible for the acceleration of charged particles to relativistic velocities in most modern linear accelerators, such as those employed at high-energy research facilities like Thomas Jefferson National Laboratory's CEBAF and the LHC at CERN. Recognizing SRF as primarily a surface phenomenon enables the possibility of applying thin films to the interior surface of SRF cavities, opening a formidable tool chest of opportunities by combining and designing materials that offer greater benefit. Thus, while improvements in radio frequency cavity design and refinements in cavity processing techniques have improved accelerator performance and efficiency - 1.5 GHz bulk niobium SRF cavities have achieved accelerating gradients in excess of 35 MV/m - there exist fundamental material bounds in bulk superconductors limiting the maximally sustained accelerating field gradient (approximately 45 MV/m for Niobium) where inevitable thermodynamic breakdown occurs. With state of the art niobium based cavity design fast approaching these theoretical limits, novel material innovations must be sought in order to realize next generation SRF cavities. One proposed method to improve SRF performance is to utilize thin film superconducting-insulating-superconducting (SIS) multilayer structures to effectively magnetically screen a bulk superconducting layer such that it can operate at higher field gradients before suffering critically detrimental SRF losses. This dissertation focuses on the production and characterization of thin film superconductors for such SIS layers for radio-frequency applications.

  14. Thin Film Approaches to the SRF Cavity Problem Fabrication and Characterization of Superconducting Thin Films

    Energy Technology Data Exchange (ETDEWEB)

    Beringer, Douglas [College of William and Mary, Williamsburg, VA (United States)

    2017-08-01

    Superconducting Radio Frequency (SRF) cavities are responsible for the acceleration of charged particles to relativistic velocities in most modern linear accelerators, such as those employed at high-energy research facilities like Thomas Jefferson National Laboratory’s CEBAF and the LHC at CERN. Recognizing SRF as primarily a surface phenomenon enables the possibility of applying thin films to the interior surface of SRF cavities, opening a formidable tool chest of opportunities by combining and designing materials that offer greater performance benefit. Thus, while improvements in radio frequency cavity design and refinements in cavity processing techniques have improved accelerator performance and efficiency – 1.5 GHz bulk niobium SRF cavities have achieved accelerating gradients in excess of 35 MV/m – there exist fundamental material bounds in bulk superconductors limiting the maximally sustained accelerating field gradient (≈ 45 MV/m for Nb) where inevitable thermodynamic breakdown occurs. With state of the art Nb based cavity design fast approaching these theoretical limits, novel material innovations must be sought in order to realize next generation SRF cavities. One proposed method to improve SRF performance is to utilize thin film superconducting-insulating-superconducting (SIS) multilayer structures to effectively magnetically screen a bulk superconducting layer such that it can operate at higher field gradients before suffering critically detrimental SRF losses. This dissertation focuses on the production and characterization of thin film superconductors for such SIS layers for radio frequency applications. Correlated studies on structure, surface morphology and superconducting properties of epitaxial Nb and MgB2 thin films are presented.

  15. YBa2Cu3O(7-x) based superconducting thin films by multitarget sputtering

    International Nuclear Information System (INIS)

    Bouteloup, E.; Mercey, B.; Poullain, G.; Brousse, T.; Murray, H.; Raveau, B.

    1990-01-01

    This paper reports a new technique to prepare superconducting YBa 2 Cu 3 O (7-x) thin films. The multitarget sputtering apparatus described below allows the simultaneous and reproducible production of numerous films with a metallic composition close to Y 17% Ba 33% Cu 50% . Superconducting films (R = 0) at 80 K have been produced on polycrystalline zirconia substrates after a high temperature annealing [fr

  16. The low-temperature, high-magnetic-field critical current characteristics of Zr-added (Gd, Y)Ba2Cu3Ox superconducting tapes

    Energy Technology Data Exchange (ETDEWEB)

    Selvamanickam, V; Yao, Y; Chen, Y; Shi, T; Liu, Y; Khatri, ND; Liu, J; Lei, C; Galstyan, E; Majkic, G

    2012-10-26

    Critical current performances of state-of-the-art Zr-added (Gd, Y)BaCuO tapes have been investigated over a temperature range of 20-77 K, in magnetic fields up to 9 T and over a wide angular range of magnetic field orientations. The peak in critical current that is commonly observed in the field orientation perpendicular to the tape in BaZrO3 (BZO) containing superconducting tapes is found to vanish at 30 K in magnetic fields at 1-9 T. While the critical current of 15% Zr-added tapes was about 40% lower than that of 7.5% Zr-added tapes at 77 K, the pinning force values of the former were found to be 18-23% higher than those of the latter in the temperature range of 20-40 K and in magnetic fields of 3-5 T. The results from this study emphasize the importance of optimization of coated conductor fabrication processes for optimum performance not just in low magnetic fields at 77 K but also at the operating conditions of low temperatures and high magnetic fields that are of interest, especially for rotating superconducting machinery applications.

  17. The low-temperature, high-magnetic-field critical current characteristics of Zr-added (Gd,Y)Ba2Cu3Ox superconducting tapes

    International Nuclear Information System (INIS)

    Selvamanickam, V; Yao, Y; Shi, T; Liu, Y; Khatri, N D; Liu, J; Galstyan, E; Majkic, G; Chen, Y; Lei, C

    2012-01-01

    Critical current performances of state-of-the-art Zr-added (Gd, Y)BaCuO tapes have been investigated over a temperature range of 20–77 K, in magnetic fields up to 9 T and over a wide angular range of magnetic field orientations. The peak in critical current that is commonly observed in the field orientation perpendicular to the tape in BaZrO 3 (BZO) containing superconducting tapes is found to vanish at 30 K in magnetic fields at 1–9 T. While the critical current of 15% Zr-added tapes was about 40% lower than that of 7.5% Zr-added tapes at 77 K, the pinning force values of the former were found to be 18–23% higher than those of the latter in the temperature range of 20–40 K and in magnetic fields of 3–5 T. The results from this study emphasize the importance of optimization of coated conductor fabrication processes for optimum performance not just in low magnetic fields at 77 K but also at the operating conditions of low temperatures and high magnetic fields that are of interest, especially for rotating superconducting machinery applications. (paper)

  18. Microwaves absorption in superconducting materials

    International Nuclear Information System (INIS)

    Biasi, R.S. de; Fernandes, A.A.R.; Pereira, R.F.R.

    1989-01-01

    Microwaves absorption measures in two superconductors ceramics systems, Y-Ba-Cu-O and Bi-Sr-Ca-Cu-O are compared with similars datas obtained in the same band of temperature by a conventional method, mutual inductance. The results suggest that the microwaves absorption can be used as single and non-destructive method for investigating the properties of ceramics superconductors. (C.G.C.) [pt

  19. The relationship between magnetisation and hysteresis of critical current in sintered YBCO. [Y-Ba-Cu-O

    Energy Technology Data Exchange (ETDEWEB)

    Jones, A R; Blunt, F J; Campbell, A M [Research Centre in Superconductivity, Univ. of Cambridge (United Kingdom); Doyle, R A [Dept. of Physics, Univ. of Witwatersrand (South Africa)

    1992-06-10

    Measurements are reported of transport critical current and magnetisation on the same samples of YBCO for three different orientations with respect to applied magnetic field. The predictions made by the model of Evetts and Glowacki for the hysteresis observed in J{sub c} were investigated and found to be in qualitative agreement with the results. However, attempts to relate the hysteresis to the magnetisation by assuming that J{sub c} is a unique function of the internal field H = H{sub 0}-nM were unsuccessful. The value of n is found to be much larger than any demagnetising factor and varies widely with both field and geometry. (orig.).

  20. Measurements on Subscale Y-Ba-Cu-O Racetrack Coils at 77 K and Self-Field

    Energy Technology Data Exchange (ETDEWEB)

    Wang, X.; Caspi, S.; Cheng, D. W.; Dietderich, D. R.; Felice, H.; Ferracin, P.; Godeke, A.; Joseph, J. M.; Lizarazo, J.; Prestemon, S. O.; Sabbi, G.

    2009-10-19

    YBa{sub 2}Cu{sub 3}O{sub 7-{delta}} (YBCO) tapes carry significant amount of current at fields beyond the limit of Nb-based conductors. This makes the YBCO tapes a possible conductor candidate for insert magnets to increase the bore field of Nb{sub 3}Sn high-field dipoles. As an initial step of the YBCO insert technology development, two subscale racetrack coils were wound using Kapton-insulated commercial YBCO tapes. Both coils had two layers; one had 3 turns in each layer and the other 10 turns. The coils were supported by G10 side rails and waxed strips and not impregnated. The critical current of the coils was measured at 77 K and self-field. A 2D model considering the magnetic-field dependence of the critical current was used to estimate the expected critical current. The measured results show that both coils reached 80%-95% of the expected values, indicating the feasibility of the design concept and fabrication process.

  1. Process parameters, orientation, and functional properties of melt-processed bulk Y-Ba-Cu-O superconductors

    International Nuclear Information System (INIS)

    Zakharchenko, I.V.; Terryll, K.M.; Rao, K.V.; Balachandran, U.

    1995-03-01

    This study compared the microstructure, texturing, and functional properties (critical currents) of YBa 2 Cu 3 O 7-x -based bulk pellets that were prepared by the quench-melt-growth-process (QMGP), melt-textured growth (MTG), and conventional solid-state reaction (SSR) approaches. Using two X-ray diffraction (XRD) methods, θ-2θ, and rocking curves, the authors found that the individual grains of two melt-processed pellets exhibited remarkable preferred orientational alignment (best rocking curve width = 3.2 degree). However, the direction of the preferred orientation among the grains was random. Among the three types of bulk materials studied, the QMGP sample was found to have the best J c values, ∼ 4,500 A/cm 2 at 77 K in a field of 2 kG, as determined from SQUID magnetic data

  2. The nature of transport critical current hysteresis in HTSC: magnetic fields and high pressures. [Y-Ba-Cu-O

    Energy Technology Data Exchange (ETDEWEB)

    Svistunov, V M; Yachenko, A.I. d' ; Tarenkov, V Yu [Donetsk Physico-Technical Inst., Ukrainian SSR (USSR)

    1991-12-01

    It was found that pressure has a strong influence on the critical current hysteresis loop of ceramics at H {proportional to} 10 kOe. The phenomenon is attributed to the critical current hysteresis of separate Josephson contacts and is due to the Abrikosov vortex density gradient within granules. The gradient defines both the sign and the value of the pinning current, whereas the sign of Meissner reversible surfaces current component is determined by the external field H direction. As a result the critical current of Josephson contacts defined by the total surface value depends on the magnetic prehistory of a sample. (orig.).

  3. Superconductivity

    International Nuclear Information System (INIS)

    2007-01-01

    During 2007, a large amount of the work was centred on the ITER project and related tasks. The activities based on low-temperature superconducting (LTS) materials included the manufacture and qualification of ITER full-size conductors under relevant operating conditions, the design of conductors and magnets for the JT-60SA tokamak and the manufacture of the conductors for the European dipole facility. A preliminary study was also performed to develop a new test facility at ENEA in order to test long-length ITER or DEMO full-size conductors. Several studies on different superconducting materials were also started to create a more complete database of superconductor properties, and also for use in magnet design. In this context, an extensive measurement campaign on transport and magnetic properties was carried out on commercially available NbTi strands. Work was started on characterising MgB 2 wire and bulk samples to optimise their performance. In addition, an intense experimental study was started to clarify the effect of mechanical loads on the transport properties of multi-filamentary Nb 3 Sn strands with twisted or untwisted superconducting filaments. The experimental activity on high-temperature superconducting (HTS) materials was mainly focussed on the development and characterisation of YBa 2 Cu 3 O 7-X (YBCO) based coated conductors. Several characteristics regarding YBCO deposition, current transport performance and tape manufacture were investigated. In the framework of chemical approaches for YBCO film growth, a new method, developed in collaboration with the Technical University of Cluj-Napoca (TUCN), Romania, was studied to obtain YBCO film via chemical solution deposition, which modifies the well-assessed metallic organic deposition trifluoroacetate (MOD-TFA) approach. The results are promising in terms of critical current and film thickness values. YBCO properties in films with artificially added pinning sites were characterised in collaboration with

  4. The elastic limit of vortex movement in superconducting thin films

    International Nuclear Information System (INIS)

    Doyle, R.A.; Kumar, D.; Pullan, P.; Gross, R.; Campbell, A.M.; Blamire, M.G.; Somekh, R.E.; Evetts, J.E.

    1993-01-01

    Here we report four point ac transport FD measurements on epitaxial YBCO films and also polycrystalline NbTa films. Considerable efforts have recently been put into investigating low T c systems (11) in order to model high Tc materials in which the pinning and other properties are less easily controlled by microstructural modification and in which the parameter values are less well known. Moreover no reports exist of the FD behaviour of low T c thin film systems. In the case of the YBCO films, the results will be seen to be able to be reconciled with IP effects due to the superconducting CuO layers. In the case of the NbTa films, the results are in agreement with extrinsic pinning expected from the columnar defects (grain boundaries) observed in microstructural (SEM) studies (11). The data on all samples suggests core pinning in both (high Κ) systems. Features in the FD curves of the YBCO system when the field is carefully applied parallel to the planes occur at distances corresponding to the interlayer spacing providing direct evidence for IP. The technique also offers the possibility of investigating the frequency dependence of the effect as well as looking for curvature in the FD response below the onset of dissipation in the resistive component. The former study should be able to separate resistive from hysteretic (Bean) type losses whereas the latter might expose information about the shape of the pinning wells in addition to their sizes. These are discussed briefly here but will form the basis of further more detailed study. It will be argued that the FD technique is a powerful approach for investigation of the mixed state, allowing information to be extracted which is unavailable from other techniques. (orig.)

  5. Superconducting niobium nitride films deposited by unbalanced magnetron sputtering

    Energy Technology Data Exchange (ETDEWEB)

    Olaya, J.J. [Departamento de Ingenieria Mecanica y Mecatronica, Universidad Nacional de Colombia, Ciudad Universitaria, Carrera 30 Numero 45-03, Bogota (Colombia); Huerta, L. [Instituto de Investigaciones en Materiales, Universidad Nacional Autonoma de Mexico, Circuito exterior s/n, CU Coyoacan, Mexico D.F. 04510 (Mexico); Rodil, S.E. [Instituto de Investigaciones en Materiales, Universidad Nacional Autonoma de Mexico, Circuito exterior s/n, CU Coyoacan, Mexico D.F. 04510 (Mexico)], E-mail: ser42@iim.unam.mx; Escamilla, R. [Instituto de Investigaciones en Materiales, Universidad Nacional Autonoma de Mexico, Circuito exterior s/n, CU Coyoacan, Mexico D.F. 04510 (Mexico)

    2008-10-01

    Niobium nitride (NbN) thin films were deposited under different configurations of the magnetic field using a magnetron sputtering system. The magnetic field configuration varied from balanced to unbalanced leading to different growth conditions and film properties. The aim of the paper was to identify correlations between deposition conditions, film properties and the electrical properties, specially the superconductive critical temperature (T{sub C}). The results suggested that there is a critical deposition condition, having an optimum ion-atom arrival ratio that promotes a well ordered and textured nanocrystalline structure (cubic phase) with the minimum residual stress and only under this condition a high critical temperature (16K) was obtained. Lower T{sub C} values around 12K were obtained for the NbN samples having a lower degree of structural perfection and texture, and a larger fraction of intergranular voids. On the other hand, analysis of valence-band spectra showed that the contribution of the Nb 4d states remained essentially constant while the higher T{sub C} was correlated to a higher contribution of the N 2p states.

  6. Superconducting niobium nitride films deposited by unbalanced magnetron sputtering

    International Nuclear Information System (INIS)

    Olaya, J.J.; Huerta, L.; Rodil, S.E.; Escamilla, R.

    2008-01-01

    Niobium nitride (NbN) thin films were deposited under different configurations of the magnetic field using a magnetron sputtering system. The magnetic field configuration varied from balanced to unbalanced leading to different growth conditions and film properties. The aim of the paper was to identify correlations between deposition conditions, film properties and the electrical properties, specially the superconductive critical temperature (T C ). The results suggested that there is a critical deposition condition, having an optimum ion-atom arrival ratio that promotes a well ordered and textured nanocrystalline structure (cubic phase) with the minimum residual stress and only under this condition a high critical temperature (16K) was obtained. Lower T C values around 12K were obtained for the NbN samples having a lower degree of structural perfection and texture, and a larger fraction of intergranular voids. On the other hand, analysis of valence-band spectra showed that the contribution of the Nb 4d states remained essentially constant while the higher T C was correlated to a higher contribution of the N 2p states

  7. Superconductivity of a Sn film controlled by an array of Co nanowires

    Science.gov (United States)

    Wei, Z.; Ye, Z.; Rathnayaka, K. D. D.; Lyuksyutov, I. F.; Wu, W.; Naugle, D. G.

    2012-09-01

    Superconducting properties of a hybrid structure composed of ferromagnetic Co nanowire arrays and a superconducting Sn film have been investigated. Ordered Co nanowires arrays with 60 nm, 150 nm and 200 nm diameter were electroplated into the pores of self organized Anodic Aluminum Oxide (AAO) membranes. Hysteretic dependence of the Sn film superconducting properties on applied magnetic field and critical current enhancement at moderate fields has been observed. This behavior strongly depends on the ratio of the Sn film thickness to the Co nanowire diameter.

  8. Superconductivity of a Sn film controlled by an array of Co nanowires

    International Nuclear Information System (INIS)

    Wei, Z.; Ye, Z.; Rathnayaka, K.D.D.; Lyuksyutov, I.F.; Wu, W.; Naugle, D.G.

    2012-01-01

    Superconducting properties of a hybrid structure composed of ferromagnetic Co nanowire arrays and a superconducting Sn film have been investigated. Ordered Co nanowires arrays with 60 nm, 150 nm and 200 nm diameter were electroplated into the pores of self organized Anodic Aluminum Oxide (AAO) membranes. Hysteretic dependence of the Sn film superconducting properties on applied magnetic field and critical current enhancement at moderate fields has been observed. This behavior strongly depends on the ratio of the Sn film thickness to the Co nanowire diameter.

  9. Stoichiometry and superconductive properties of YBaCuO films deposited by spray pyrolysis

    International Nuclear Information System (INIS)

    Conde-Gallardo, A.; Falcony, C.; Ortiz, A.

    1994-01-01

    The dependence of the stoichiometry and the superconducting characteristics of YBaCuO films deposited by spray pyrolysis on the spraying solution composition and the deposition conditions is reported. It has been found that a proper optimization of the starting materials concentration in the spraying solution results in superconducting films with zero resistance temperature of 91 K and a transition to superconducting state within a 3 K range. X-ray diffraction and resistance vs temperature measurements have been used to monitor the crystal composition and the conductive characteristics of the films as a function of the spraying solution composition and the deposition parameters

  10. Loss mechanisms in superconducting thin film microwave resonators

    Energy Technology Data Exchange (ETDEWEB)

    Goetz, Jan, E-mail: jan.goetz@wmi.badw.de; Haeberlein, Max; Wulschner, Friedrich; Zollitsch, Christoph W.; Meier, Sebastian; Fischer, Michael; Fedorov, Kirill G.; Menzel, Edwin P. [Walther-Meißner-Institut, Bayerische Akademie der Wissenschaften, 85748 Garching (Germany); Physik-Department, Technische Universität München, 85748 Garching (Germany); Deppe, Frank; Eder, Peter; Xie, Edwar; Gross, Rudolf, E-mail: rudolf.gross@wmi.badw.de [Walther-Meißner-Institut, Bayerische Akademie der Wissenschaften, 85748 Garching (Germany); Physik-Department, Technische Universität München, 85748 Garching (Germany); Nanosystems Initiative Munich (NIM), Schellingstraße 4, 80799 München (Germany); Marx, Achim [Walther-Meißner-Institut, Bayerische Akademie der Wissenschaften, 85748 Garching (Germany)

    2016-01-07

    We present a systematic analysis of the internal losses of superconducting coplanar waveguide microwave resonators based on niobium thin films on silicon substrates. In particular, we investigate losses introduced by Nb/Al interfaces in the center conductor, which is important for experiments where Al based Josephson junctions are integrated into Nb based circuits. We find that these interfaces can be a strong source for two-level state (TLS) losses, when the interfaces are not positioned at current nodes of the resonator. In addition to TLS losses, for resonators including Al, quasiparticle losses become relevant above 200 mK. Finally, we investigate how losses generated by eddy currents in conductive material on the backside of the substrate can be minimized by using thick enough substrates or metals with high conductivity on the substrate backside.

  11. Studies of the Superconducting Transition in the Mo/Au-Bilayer Thin Films

    Science.gov (United States)

    Sadleir, John; Smith, Stephen; Iyomoto, naoko; Bandler, Simon; Chervenak, Jay; Brown, Ari; Brekowsky, Regis; Kilbourne, Caroline; Robinson, Ian

    2007-01-01

    At NASA Goddard, microcalorimeter arrays using superconducting transition edge sensor thermometers (TESs) are under development for high energy resolution X-ray astrophysics applications. We report on our studies of the superconducting transition in our Mo/Au-bilayer TES films including: low current measurements of the superconducting bilayer's resistance transition versus temperature on pixels with different normal metal absorber attachment designs and measured temperature scaling of the critical current and critical magnetic field.

  12. Growth of YBCO superconducting thin films on CaF sub 2 buffered silicon

    CERN Document Server

    Bhagwat, S S; Patil, J M; Shirodkar, V S

    2000-01-01

    CaF sub 2 films were grown on silicon using the neutral cluster beam deposition technique. These films were highly crystalline and c-axis oriented. Superconducting YBCO thin films were grown on the Ca F sub 2 buffered silicon using the laser ablation technique. These films showed T sub c (onset) at 90 K and Tc(zero) at 86 K. X-ray diffraction analysis showed that the YBCO films were also oriented along the c-axis.

  13. Superconductivity

    International Nuclear Information System (INIS)

    Taylor, A.W.B.; Noakes, G.R.

    1981-01-01

    This book is an elementray introduction into superconductivity. The topics are the superconducting state, the magnetic properties of superconductors, type I superconductors, type II superconductors and a chapter on the superconductivity theory. (WL)

  14. Comparison of water degradation of YBaCuO superconducting films made from different structures

    International Nuclear Information System (INIS)

    Chang, C.; Tsai, J.A.

    1988-01-01

    Immersion of YBaCuO superconducting films in water has shown a large difference in degradation between structures with and without silver. For the structures containing silver layers and depositing at a high temperature, superconducting films with zero resistance at 87 K remain superconductive at 77 K after 5 h immersion in water, with an increase in room-temperature film resistance by a factor of 4; the contact resistance remains low after 60 h of immersion, allowing the measurement at low temperatures. For the structures containing no silver and depositing at room temperature, the contact resistance rapidly increases with immersion times, making the measurement at 77 K difficult after 5 min of immersion. Changes in the sharpness of the superconductive transition, and structures of the films due to the water immersion are also compared

  15. High-Tc Superconducting Thick-Film Spiral Magnet: Development and Characterization of a Single Spiral Module

    National Research Council Canada - National Science Library

    McGinnis, W

    1997-01-01

    The objective of this project was to make characterized and numerically model prototype modules of a new type of superconducting electromagnet based on stacked spirals of superconducting thick films...

  16. Magnetic shield effect simulation of superconducting film shield covering directly coupled HTS dc-SQUID magnetometer

    International Nuclear Information System (INIS)

    Terauchi, N.; Noguchi, S.; Igarashi, H.

    2011-01-01

    A superconducting film shield over a SQUID ring improves the robustness of the SQUID with respect to magnetic noise. Supercurrent in the SQUID magnetometer and the superconducting film shield were simulated. The superconducting film shield reduces the influence of the external magnetic field on the SQUID ring. An HTS SQUID is a high sensitive magnetic sensor. In recent years, the HTS SQUID is widely used in various applications. In some applications, high robustness with respect to magnetic noise is required to realize stable operation at outside of a magnetic shielding room. The target of this paper is a directly coupled HTS dc-SQUID magnetometer. To enhance the robustness of the SQUID magnetometer, use of a superconducting thin film shield has been proposed. The magnetic field directly penetrating the SQUID ring causes the change of the critical current of Josephson junction, and then the SQUID magnetometer transitions into inoperative state. In order to confirm the magnetic shield effect of the superconducting film shield, electromagnetic field simulation with 3D edge finite element method was performed. To simulate the high temperature superconductor, E-J characteristics and c-axis anisotropy are considered. To evaluate the effect of the superconducting film shield, an external magnetic field which is supposed to be a magnetic noise is applied. From the simulation results, the time transition of the magnetic flux penetrating the SQUID ring is investigated and the effect of the superconducting film shield is confirmed. The amplitude of the magnetic flux penetrating the SQUID ring can be reduced to about one-sixth since the superconducting film shield prevents the magnetic noise from directly penetrating the SQUID ring.

  17. High quality superconducting titanium nitride thin film growth using infrared pulsed laser deposition

    Science.gov (United States)

    Torgovkin, A.; Chaudhuri, S.; Ruhtinas, A.; Lahtinen, M.; Sajavaara, T.; Maasilta, I. J.

    2018-05-01

    Superconducting titanium nitride (TiN) thin films were deposited on magnesium oxide, sapphire and silicon nitride substrates at 700 °C, using a pulsed laser deposition (PLD) technique, where infrared (1064 nm) pulses from a solid-state laser were used for the ablation from a titanium target in a nitrogen atmosphere. Structural studies performed with x-ray diffraction showed the best epitaxial crystallinity for films deposited on MgO. In the best films, superconducting transition temperatures, T C, as high as 4.8 K were observed, higher than in most previous superconducting TiN thin films deposited with reactive sputtering. A room temperature resistivity down to ∼17 μΩ cm and residual resistivity ratio up to 3 were observed in the best films, approaching reported single crystal film values, demonstrating that PLD is a good alternative to reactive sputtering for superconducting TiN film deposition. For less than ideal samples, the suppression of the film properties were correlated mostly with the unintended incorporation of oxygen (5–10 at%) in the film, and for high oxygen content films, vacuum annealing was also shown to increase the T C. On the other hand, superconducting properties were surprisingly insensitive to the nitrogen content, with high quality films achieved even in the highly nitrogen rich, Ti:N = 40/60 limit. Measures to limit oxygen exposure during deposition must be taken to guarantee the best superconducting film properties, a fact that needs to be taken into account with other deposition methods, as well.

  18. Textured YBCO films grown on wires: application to superconducting cables

    International Nuclear Information System (INIS)

    Dechoux, N; Jiménez, C; Chaudouët, P; Rapenne, L; Sarigiannidou, E; Robaut, F; Petit, S; Garaudée, S; Porcar, L; Soubeyroux, J L; Odier, P; Bruzek, C E; Decroux, M

    2012-01-01

    Efforts to fabricate superconducting wires made of YBa 2 Cu 3 O 7 (YBCO) on La 2 Zr 2 O 7 (LZO) buffered and biaxially textured Ni-5 at.%W (NiW) are described. Wires were manually shaped from LZO buffered NiW tapes. Different diameters were produced: 1.5, 2 and 3 mm. The wires were further covered with YBCO grown by metal organic chemical vapor deposition (MOCVD). We developed an original device in which the round substrate undergoes an alternated rotation of 180° around its axis in addition to a reel-to-reel translation. This new approach allows covering the whole circumference of the wire with a YBCO layer. This was confirmed by energy dispersive x-ray spectroscopy (EDX) analysis coupled to a scanning electron microscope (SEM). For all wire diameters, the YBCO layer thickness varied from 300 to 450 nm, and the cationic composition was respected. Electron backscattering diffraction (EBSD) measurements were performed directly on an as-deposited wire without surface preparation allowing the investigation of the crystalline quality of the film surface. Combining EBSD with XRD results we show that YBCO grows epitaxially on the LZO buffered NiW wires. For the first time, superconductive behaviors have been detected on round substrates in both the rolling and circular direction. J c reached 0.3 MA cm −2 as measured at 77 K by transport and third-harmonic detection. Those preliminary results confirm the effectiveness of the MOCVD for complex geometries, especially for YBCO deposition on small diameter wires. This approach opens huge perspectives for the elaboration of a new generation of YBCO-based round conductors. (paper)

  19. Effect of localized electron states on superconductivity of ultrathin beryllium films

    International Nuclear Information System (INIS)

    Tutov, V.I.; Semenenko, E.E.

    1988-01-01

    A wide spectrum of distortions is induced in ultrathin beryllium films of thickness less than 10 A, which are responsible for the system transition from the strong localization state completely suppressing superconductivity (in this case R □ of the layer reaches 97600 Ohm) to the weak localization stae coexisting with superconductivity at comparatively high T c (5 K). The resistance per square R □ of the films decreases more than by an order of magnitude. The superconductivity with T c =1.7 K occurs at rather strong localization, when R □ of the layer is 34000 Ohm

  20. Interface-Induced Zeeman-Protected Superconductivity in Ultrathin Crystalline Lead Films

    Directory of Open Access Journals (Sweden)

    Yi Liu

    2018-04-01

    Full Text Available Two-dimensional (2D superconducting systems are of great importance for exploring exotic quantum physics. The recent development of fabrication techniques has stimulated studies of high-quality single-crystalline 2D superconductors, where intrinsic properties give rise to unprecedented physical phenomena. Here, we report the observation of Zeeman-type spin-orbit interaction protected superconductivity (Zeeman-protected superconductivity in 4-monolayer (ML to 6-ML crystalline Pb films grown on striped incommensurate Pb layers on Si(111 substrates by molecular beam epitaxy. An anomalously large in-plane critical field far beyond the Pauli limit is detected, which can be attributed to the Zeeman-protected superconductivity due to the in-plane inversion symmetry breaking at the interface. Our work demonstrates that, in superconducting heterostructures, the interface can induce Zeeman-type spin-orbit interactions and modulate the superconductivity.

  1. Interface-Induced Zeeman-Protected Superconductivity in Ultrathin Crystalline Lead Films

    Science.gov (United States)

    Liu, Yi; Wang, Ziqiao; Zhang, Xuefeng; Liu, Chaofei; Liu, Yongjie; Zhou, Zhimou; Wang, Junfeng; Wang, Qingyan; Liu, Yanzhao; Xi, Chuanying; Tian, Mingliang; Liu, Haiwen; Feng, Ji; Xie, X. C.; Wang, Jian

    2018-04-01

    Two-dimensional (2D) superconducting systems are of great importance for exploring exotic quantum physics. The recent development of fabrication techniques has stimulated studies of high-quality single-crystalline 2D superconductors, where intrinsic properties give rise to unprecedented physical phenomena. Here, we report the observation of Zeeman-type spin-orbit interaction protected superconductivity (Zeeman-protected superconductivity) in 4-monolayer (ML) to 6-ML crystalline Pb films grown on striped incommensurate Pb layers on Si(111) substrates by molecular beam epitaxy. An anomalously large in-plane critical field far beyond the Pauli limit is detected, which can be attributed to the Zeeman-protected superconductivity due to the in-plane inversion symmetry breaking at the interface. Our work demonstrates that, in superconducting heterostructures, the interface can induce Zeeman-type spin-orbit interactions and modulate the superconductivity.

  2. Superconductivity

    CERN Document Server

    Poole, Charles P; Farach, Horacio A

    1995-01-01

    Superconductivity covers the nature of the phenomenon of superconductivity. The book discusses the fundamental principles of superconductivity; the essential features of the superconducting state-the phenomena of zero resistance and perfect diamagnetism; and the properties of the various classes of superconductors, including the organics, the buckministerfullerenes, and the precursors to the cuprates. The text also describes superconductivity from the viewpoint of thermodynamics and provides expressions for the free energy; the Ginzburg-Landau and BCS theories; and the structures of the high

  3. Resputtering-induced chemical inhomogeneity during the growth of high Tc superconductor thin films

    International Nuclear Information System (INIS)

    Ismat Shah, S.

    1991-01-01

    High T c films belonging to Y-Ba-Cu-O, Bi-Sr-Ca-Cu-O and Tl-Ba-Ca-Cu-O systems have been fabricated by reactive sputtering of single targets in a planar magnetron and Ar+O 2 sputtering atmosphere. Although it was possible to deposit films of correct composition, resputtering related composition variation was a problem. The key to obtaining correct chemistry was a proper control of the deposition parameters. The pressure and oxygen content of the sputtering gas were found to be the most critical parameters. Results of the variation of these parameters on the cation chemistry are presented in this paper. Results from Monte-Carlo simulation of the sputtering process are also presented showing that low pressure and oxygen content of the sputtering gas result in a higher yield of energetic reflected neutrals which can cause compositional variation in the film mainly due to preferential sputtering of the growing film. The effect was particularly noticeable directly underneath the target. The energetic particle bombardment can be controlled by using moderately high pressures and low oxygen concentration in the gas. (author). 11 refs., 7 figs

  4. Terahertz detectors using hot-electrons in superconducting films

    Energy Technology Data Exchange (ETDEWEB)

    Semenov, A. [DLR, Inst. of Planetary Research, Berlin (Germany)

    2007-07-01

    Recently the terahertz gap has been recognized as a prospective spectral range for radioastronomy as well as for material and security studies. Implementation of terahertz technology in these fields requires further improvement of instruments and their major subcomponents. Physical phenomena associated with the local and homogeneous non-equilibrium electron sates in thin superconducting films offer numerous possibilities for the development of terahertz and infrared detectors. Depending on the nature of the resistive state and the operation regime, a variety of detector can be realized. They are e.g. direct bolometric or kinetic inductance detectors, heterodyne mixers or photon counters. Operation principles and physical limitations of these devices will be discussed. Two examples of the detector development made in cooperation between the German Aerospace Center, the University of Karlsruhe and PTB, Berlin will be presented. The energy resolving single-photon detector with an almost fundamentally limited energy resolution of 0.6 eV at 6.5 K for photons with wavelengths from 400 nm to 2500 nm and the heterodyne mixer quasioptically coupled to radiation in the frequency range from 0.8 THz to 5 THz and providing a noise temperature of less then ten times the quantum limit. The mixers will be implemented in the terahertz radar for security screening (TERASEC) and in the heterodyne receiver of the stratospheric observatory SOFIA. (orig.)

  5. Superconducting properties of In-Ge mixture films

    International Nuclear Information System (INIS)

    Gerber, A.; Deutscher, G.

    1987-01-01

    We report on measurements of the perpendicular H/sub c//sub perpendicular/ and parallel H/sub c//sub X/ upper critical fields of superconducting In-Ge mixture films in a wide range of In concentrations. The resistivities of the samples varied from about 10 μΩX, corresponding to high In concentration, up to about 1300 μΩ cm, corresponding to an In concentration close to the percolation threshold of the system. The critical temperatures of the samples in a zero external field have also been studied. For high metal concentrations the results have been analyzed and found to fit the predictions of the dirty limit for type-II superconductors. Near the threshold, however, where the normal-state resistivity goes to infinity, the critical fields saturate to a finite value. This result is in accordance with the prediction of percolation theory in the anomalous diffusion regime. As the threshold is approached the anisotropy ratio decreases to a constant value of 1.2 from its homogeneous type-II limit 1.69

  6. Generation of coherent electromagnetic radiation by superconducting films at nitrogen temperatures

    CERN Document Server

    Lykov, A N

    2001-01-01

    One detected generation of coherent electromagnetic radiation by GdBa sub 2 Cu sub 3 O sub 7 sub - sub x superconducting films within 1-10 MHz range at temperature of liquid nitrogen boiling. This type generation is caused by synchronization realized due to the feedback of abrupt changes of the Abrikosov's vortices produced by the external low-frequency magnetic field. Possibility to reach more intensive radiation due to increase of the area of superconducting film, as well as, via increase of amplitude and of frequency of electromagnetic field exciting a vortex system in films is the most important advantage of the given technique of generation

  7. Degradation of superconducting Nb/NbN films by atmospheric oxidation

    Energy Technology Data Exchange (ETDEWEB)

    Henry, Michael David; Wolfley, Steven L.; Young, Travis Ryan; Monson, Todd; Pearce, Charles Joseph; Lewis, Rupert M.; Clark, Blythe; Brunke, Lyle Brent; Missert, Nancy A.

    2017-03-01

    Niobium and niobium nitride thin films are transitioning from fundamental research toward wafer scale manufacturing with technology drivers that include superconducting circuits and electronics, optical single photon detectors, logic, and memory. Successful microfabrication requires precise control over the properties of sputtered superconducting films, including oxidation. Previous work has demonstrated the mechanism in oxidation of Nb and how film structure could have deleterious effects upon the superconducting properties. This study provides an examination of atmospheric oxidation of NbN films. By examination of the room temperature sheet resistance of NbN bulk oxidation was identified and confirmed by secondary ion mass spectrometry. As a result, Meissner magnetic measurements confirmed the bulk oxidation not observed with simple cryogenic resistivity measurements.

  8. Deposition of superconducting (Cu, C)-Ba-O films by pulsed laser deposition at moderate temperature

    International Nuclear Information System (INIS)

    Yamamoto, Tetsuro; Kikunaga, Kazuya; Obara, Kozo; Terada, Norio; Kikuchi, Naoto; Tanaka, Yasumoto; Tokiwa, Kazuyasu; Watanabe, Tsuneo; Sundaresan, Athinarayanan; Shipra

    2007-01-01

    Superconducting (Cu, C)-Ba-O thin films have been epitaxially grown on (100) SrTiO 3 at a low growth temperature of 500-600 deg. C by pulsed laser deposition. The dependences of their crystallinity and transport properties on preparation conditions have been investigated in order to clarify the dominant parameters for carbon incorporation and the emergence of superconductivity. It has been revealed that the CO 3 content in the films increases with increasing both the parameters of partial pressure of CO 2 during film growth and those of growth rate and enhancement of superconducting properties. The present study has also revealed that the structural and superconducting properties of the (Cu, C)-Ba-O films are seriously deteriorated by the irradiation of energetic particles during deposition. Suppression of the radiation damage is another key for a high and uniform superconducting transition. By these optimizations, a superconducting onset temperature above 50 K and a zero-resistance temperature above 40 K have been realized

  9. Superconductivity

    International Nuclear Information System (INIS)

    Langone, J.

    1989-01-01

    This book explains the theoretical background of superconductivity. Includes discussion of electricity, material fabrication, maglev trains, the superconducting supercollider, and Japanese-US competition. The authors reports the latest discoveries

  10. Superconductivity

    International Nuclear Information System (INIS)

    Onnes, H.K.

    1988-01-01

    The author traces the development of superconductivity from 1911 to 1986. Some of the areas he explores are the Meissner Effect, theoretical developments, experimental developments, engineering achievements, research in superconducting magnets, and research in superconducting electronics. The article also mentions applications shown to be technically feasible, but not yet commercialized. High-temperature superconductivity may provide enough leverage to bring these applications to the marketplace

  11. Characterization of superconducting thin films by infrared reflection

    International Nuclear Information System (INIS)

    Gervais, F.

    1988-01-01

    Infrared reflectivity spectroscopy is shown to be a powerful tool to characterize the new high-Tc oxide superconductors since it gives information about the superconducting gap, phonons, plasmon and possibly low-energy electronic excitations such as excitons, information relevant to understand the mechanism of superconductivity [fr

  12. A review of basic phenomena and techniques for sputter-deposition of high temperature superconducting films

    Energy Technology Data Exchange (ETDEWEB)

    Auciello, O. (Microelectronics Center of North Carolina, Research Triangle Park, NC (USA) North Carolina State Univ., Raleigh, NC (USA). Dept. of Materials Science and Engineering); Ameen, M.S.; Kingon, A.I.; Lichtenwalner, D.J. (North Carolina State Univ., Raleigh, NC (USA). Dept. of Materials Science and Engineering); Krauss, A.R. (Argonne National Lab., IL (USA))

    1990-01-01

    The processes involved in plasma and ion beam sputter-deposition of high temperature superconducting thin films are critically reviewed. Recent advances in the development of these techniques are discussed in relation to basic physical phenomena, specific to each technique, which must be understood before high quality films can be produced. Control of film composition is a major issue in sputter-deposition of multicomponent materials. Low temperature processing of films is a common goal for each technique, particularly in relation to integrating high temperature superconducting films with the current microelectronics technology. It has been understood for some time that for Y{sub 1}Ba{sub 2}Cu{sub 3}O{sub 7} deposition, the most intensely studied high-{Tc} compound, incorporation of sufficient oxygen into the film during deposition is necessary to produce as-deposited superconducting films at relatively substrate temperatures. Recent results have shown that with the use of suitable buffer layers, high quality Y{sub 1}Ba{sub 2}Cu{sub 3}O{sub 7} sputtered films can be obtained on Si substrates without the need for post-deposition anneal processing. This review is mainly focussed on issues related to sputter-deposition of Y{sub 1}Ba{sub 2}Cu{sub 3}O{sub 7} thin films, although representative results concerning the bismuth and thallium based compounds are included. 143 refs., 11 figs.

  13. Superconductivity

    International Nuclear Information System (INIS)

    Andersen, N.H.; Mortensen, K.

    1988-12-01

    This report contains lecture notes of the basic lectures presented at the 1st Topsoee Summer School on Superconductivity held at Risoe National Laboratory, June 20-24, 1988. The following lecture notes are included: L.M. Falicov: 'Superconductivity: Phenomenology', A. Bohr and O. Ulfbeck: 'Quantal structure of superconductivity. Gauge angle', G. Aeppli: 'Muons, neutrons and superconductivity', N.F. Pedersen: 'The Josephson junction', C. Michel: 'Physicochemistry of high-T c superconductors', C. Laverick and J.K. Hulm: 'Manufacturing and application of superconducting wires', J. Clarke: 'SQUID concepts and systems'. (orig.) With 10 tabs., 128 figs., 219 refs

  14. High-frequency properties of superconducting Y-Ba-Cu-oxide thin films

    International Nuclear Information System (INIS)

    Ramakrishnan, E.S.; Su, M.; Howng, W.

    1992-01-01

    rf and microwave properties of superconducting YBa 2 Cu 3 O 7-x thin films were measured and analyzed using a coplanar resonator structure. The films were developed by sequential electron-beam evaporation of the metals followed by postanneal processing. dc properties of the films were obtained from resistance-temperature and current-voltage measurements to evaluate the transition temperature and current densities. High-frequency properties were measured from 70 to 10 K and in the frequency range 1--3 GHz to determine the film characteristics as compared to pure copper films on the same substrates

  15. Superconductivity

    International Nuclear Information System (INIS)

    Palmieri, V.

    1990-01-01

    This paper reports on superconductivity the absence of electrical resistance has always fascinated the mind of researchers with a promise of applications unachievable by conventional technologies. Since its discovery superconductivity has been posing many questions and challenges to solid state physics, quantum mechanics, chemistry and material science. Simulations arrived to superconductivity from particle physics, astrophysic, electronics, electrical engineering and so on. In seventy-five years the original promises of superconductivity were going to become reality: a microscopical theory gave to superconductivity the cloth of the science and the level of technological advances was getting higher and higher. High field superconducting magnets became commercially available, superconducting electronic devices were invented, high field accelerating gradients were obtained in superconductive cavities and superconducting particle detectors were under study. Other improvements came in a quiet progression when a tornado brought a revolution in the field: new materials had been discovered and superconductivity, from being a phenomenon relegated to the liquid Helium temperatures, became achievable over the liquid Nitrogen temperature. All the physics and the technological implications under superconductivity have to be considered ab initio

  16. Superconductivity

    CERN Document Server

    Thomas, D B

    1974-01-01

    A short general review is presented of the progress made in applied superconductivity as a result of work performed in connection with the high-energy physics program in Europe. The phenomenon of superconductivity and properties of superconductors of Types I and II are outlined. The main body of the paper deals with the development of niobium-titanium superconducting magnets and of radio-frequency superconducting cavities and accelerating structures. Examples of applications in and for high-energy physics experiments are given, including the large superconducting magnet for the Big European Bubble Chamber, prototype synchrotron magnets for the Super Proton Synchrotron, superconducting d.c. beam line magnets, and superconducting RF cavities for use in various laboratories. (0 refs).

  17. Effect of point disorder on superconducting properties of ultrathin epitaxial NbN films

    International Nuclear Information System (INIS)

    Jesudasan, John; Bagwe, Vivas; Mondal, Mintu; Chand, Madhavi; Kamlapure, Anand; Pai, S.P.; Raychaudhuri, Pratap; Mishra, Archana

    2009-01-01

    We synthesized homogeneously disordered epitaxial NbN films on MgO(100) substrates using reactive dc magnetron sputtering. The disorder of the films is characterized by the Loffe-Regel parameter k F I. The superconducting properties are studied through transport, ac-susceptibility measurements and electron tunneling. The superconducting transition temperature is studied as a function of thickness for films of different disorder. In the case of the less disordered film, there is a smooth decrease in T c with decreasing thickness but for the more disordered film, the T c shows a sharp decrease to zero at a threshold thickness. The superconducting energy gap is studied via planar tunnel junctions. It is found that for the less disordered films, the temperature dependence of the gap follows the BCS variation but for the more disordered ones, there is a significant deviation from the BCS curve, and the gap remains finite at T c indicating that the superconducting transition is either governed by phase fluctuations or a first order phase transition. (author)

  18. Ultrathin NbN Films for Superconducting Single-Photon Detectors

    International Nuclear Information System (INIS)

    Slysz, W.; Guziewicz, M.; Borysiewicz, M.

    2011-01-01

    We present our research on fabrication and structural and transport characterization of ultrathin superconducting NbN layers deposited on both single-crystal Al 2 O 3 and Si wafers, and SiO 2 and Si 3 N 4 buffer layers grown directly on Si wafers. The thicknesses of our films varied from 6 nm to 50 nm and they were grown using reactive RF magnetron sputtering on substrates maintained at the temperature 850 o C. We have performed extensive morphology characterization of our films using the X-ray diffraction method and atomic force microscopy, and related the results to the type of the substrate used for the film deposition. Our transport measurements showed that even the thinnest, 6 nm thick NbN films had the superconducting critical temperature of 10-12 K, which was increased to 14 K for thicker films. (author)

  19. Misfit dislocations and phase transformations in high-T sub c superconducting films

    CERN Document Server

    Gutkin, M Y

    2002-01-01

    A theoretical model is suggested that describes the effects of misfit stresses on defect structures, phase content and critical transition temperature T sub c in high-T sub c superconducting films. The focus is placed on the exemplary case of YBaCuO films deposited onto LaSrAlO sub 4 substrates. It is theoretically revealed here that misfit stresses are capable of inducing phase transformations controlled by the generation of misfit dislocations in growing cuprate films. These transformations, in the framework of the suggested model, account for experimental data on the influence of the film thickness on phase content and critical temperature T sub c of superconducting cuprate films, reported in the literature. The potential role of stress-assisted phase transformations in suppression of critical current density across grain boundaries in high-T sub c superconductors is briefly discussed.

  20. Infrared refractive index of thin YBa2Cu3O7 superconducting films

    International Nuclear Information System (INIS)

    Zhang, Z.M.; Choi, B.I.; Le, T.A.; Flik, M.I.; Siegal, M.P.; Phillips, J.M.

    1992-01-01

    This work investigates whether thin-film optics with a constant refractive index can be applied to high-T c superconducting thin films. The reflectance and transmittance of YBa 2 Cu 3 O 7 films on LaAlO 3 substrates are measured using a Fourier-transform infrared spectrometer at wavelengths from 1 to 100 μm at room temperature. The reflectance of these superconducting films at 10K in the wavelength region from 2.5 to 25 μm is measured using a cryogenic reflectance accessory. The film thickness varies from 10 to 200 nm. By modeling the frequency-dependent complex conductivity in the normal and superconducting states and applying electromagnetic-wave theory, the complex refractive index of YBa 2 Cu 3 O 7 films is obtained with a fitting technique. It is found that a thickness-independent refractive index can be applied even to a 25nm film, and average values of the spectral refractive index for film thicknesses between 25 and 200 nm are recommended for engineering applications

  1. A novel selenization technique for fabrication of superconducting FeSex thin film

    International Nuclear Information System (INIS)

    Chai Qinglin; Tu Hailing; Hua Zhiqiang; Wang Lei; Qu Fei

    2011-01-01

    A novel selenization technique was applied to prepare superconducting FeSe x films with pre-set FeS films. The combination of reactive sputtering deposition with elemental diffusion technique would extend to prepare films of other iron-based superconductors. The results of transport measurement got close or greater than that of previous reports. T c,onset and T c,0 got to 10.2 K and 4 K respectively. We believe that increase of the content of Fe 7 Se 8 could not only reduce T c but also slow down the decline of resistivity. A combinative method with reactive sputtering deposition and selenization technique was applied to prepare superconducting FeSe x films on LaAlO 3 substrates successfully. The influence of selenizing temperature on film components was studied. FeSe 0.96 and FeSe films had similar and good performances in transport measurement but little difference in magnetic property. The critical onset temperature got to 11.2 K and T c,0 got to 4 K approximately. X-ray diffraction, energy dispersive spectroscopy and scanning electron microscopy were used to analyze the ratio of constituents and morphology of several selenized films. FeSe x film had a porous structure on surface and no well preferred orientation, which were confirmed to have little influence on superconducting properties.

  2. Bi-Sr-Ca-Cu-O superconducting thin films: theory and experiment

    Energy Technology Data Exchange (ETDEWEB)

    Yavuz, M [Department of Mechanical Engineering and Mechatronics Engineering Program, University of Waterloo, Waterloo, Ontario N2L 3G1 (Canada); Boybay, M S [Department of Mechanical Engineering and Mechatronics Engineering Program, University of Waterloo, Waterloo, Ontario N2L 3G1 (Canada); Elbuken, C [Department of Mechanical Engineering and Mechatronics Engineering Program, University of Waterloo, Waterloo, Ontario N2L 3G1 (Canada); Andrews, M J [Los Alamos National Lab, PO Box 1663, Mail Stop B 296, Los Alamos, NM 87545 (United States); Hu, C R [Department of Physics, Texas A and M University, College Station, Texas 77843 (United States); Ross, J H [Department of Physics, Texas A and M University, College Station, Texas 77843 (United States)

    2006-06-01

    The interest of this paper centers on fabrication and characterization and modeling of vortices in high temperature superconducting thin films. As a first step, the magnetic vertices of the superconducting matrix were modeled. As a second, Bi-Sr-Ca-Cu-O thin films were grown using Pulsed Laser Ablation (PLD) on single crystal MgO substrates as magnetic templates for the potential use for Nano and Microelectronic circuits, and were characterized by x-ray diffraction, electron, and atomic force microscopy. The third step (future work) will be observation and pinning of these vortices using Bitter decoration.

  3. Superconductivity

    International Nuclear Information System (INIS)

    Kakani, S.L.; Kakani, Shubhra

    2007-01-01

    The monograph provides readable introduction to the basics of superconductivity for beginners and experimentalists. For theorists, the monograph provides nice and brief description of the broad spectrum of experimental properties, theoretical concepts with all details, which theorists should learn, and provides a sound basis for students interested in studying superconducting theory at the microscopic level. Special chapter on the theory of high-temperature superconductivity in cuprates is devoted

  4. Superconducting TlCa2Ba2Cu3O9 thick films

    International Nuclear Information System (INIS)

    1994-01-01

    GE Corporate Research and Development's (GE-CRD) program to develop the two-zone silver addition (TZSA) process for fabricating superconducting films of TlCa 2 Ba 2 Cu 3 O 9 has activities in the areas of (1) precursor preparation, (2) the thallium oxide vapor process, (3) the effects of post-synthesis annealing ambient and temperature on superconducting properties, (4) the influence of film stoichiometry and composition on superconducting properties, (5) microstructure and film growth mechanism, (6) the preparation of thicker films, (7) the fabrication of films on flexible substrates, and (8) process scale-up. As part of its effort under the ANL Pilot Center Agreement, GE-CRD has supplied to ANL a complete two-zone furnace, has provided consultation on its use and on the planning of experiments, has processed ANL samples in GE's furnaces to help define optimum process conditions, and has provided precursor and finished films as requested. These contributions are described more fully in the descriptions of the work performed at ANL presented elsewhere in this report. Under the Pilot Center Agreement work at GE-CRD has been directed toward the optimization of the TZSA process with emphasis on (A) process improvement, (B) effects of silver content on film properties, (C) the relationship between microstructure and J c , and (D) toward the assessment of the compatibility of silver substrates with the process chemistry

  5. Preparation and characterization of high-Tc superconducting thin films with high critical current densities

    International Nuclear Information System (INIS)

    Vase, P.

    1991-08-01

    The project was carried out in relation to possible cable and electronics applications of high-T c materials. Laser ablation was used as the deposition technique because of its stoichiometry conservation. Films were made in the YBa 2 Cu 3 O 7 compound due to its relatively simple stoichiometry compared to other High-T c compounds. Much attention was paid to the critical current density. A very high critical current density was reached. By using texture analysis by X-ray diffraction, it was found that films with high critical current densities were epitaxial, while films with low critical current densities contained several crystalline orientations. Four techniques for patterning the films were used - photo lithography and wet etch, laser ablation lithography, laser writing and electron beam lithography and ion milling. Sub-micron patterning has been demonstrated without degradation of the superconducting properties. The achieved patterning resolution is sufficient for preparation of many superconducting components. (AB)

  6. Niobium thin film deposition studies on copper surfaces for superconducting radio frequency cavity applications

    Energy Technology Data Exchange (ETDEWEB)

    W. M. Roach, D. B. Beringer, J. R. Skuza, W. A. Oliver, C. Clavero, C. E. Reece, R. A. Lukaszew

    2012-06-01

    Thin film coatings have the potential to increase both the thermal efficiency and accelerating gradient in superconducting radio frequency accelerator cavities. However, before this potential can be realized, systematic studies on structure-property correlations in these thin films need to be carried out since the reduced geometry, combined with specific growth parameters, can modify the physical properties of the materials when compared to their bulk form. Here, we present our systematic studies of Nb thin films deposited onto Cu surfaces to clarify possible reasons for the limited success that this process exhibited in previous attempts. We compare these films with Nb grown on other surfaces. In particular, we study the crystal structure and surface morphology and their effect on superconducting properties, such as critical temperature and lower critical field. We found that higher deposition temperature leads to a sharper critical temperature transition, but also to increased roughness indicating that there are competing mechanisms that must be considered for further optimization.

  7. Niobium thin film deposition studies on copper surfaces for superconducting radio frequency cavity applications

    International Nuclear Information System (INIS)

    Roach, W.M.; Beringer, D.B.; Skuza, J.R.; Oliver, W.A.; Clavero, C.; Reece, C.E.; Lukaszew, R.A.

    2012-01-01

    Thin film coatings have the potential to increase both the thermal efficiency and accelerating gradient in superconducting radio frequency accelerator cavities. However, before this potential can be realized, systematic studies on structure-property correlations in these thin films need to be carried out since the reduced geometry, combined with specific growth parameters, can modify the physical properties of the materials when compared to their bulk form. Here, we present our systematic studies of Nb thin films deposited onto Cu surfaces to clarify possible reasons for the limited success that this process exhibited in previous attempts. We compare these films with Nb grown on other surfaces. In particular, we study the crystal structure and surface morphology and their effect on superconducting properties, such as critical temperature and lower critical field. We found that higher deposition temperature leads to a sharper critical temperature transition, but also to increased roughness indicating that there are competing mechanisms that must be considered for further optimization.

  8. Plasma-enhanced chemical vapor deposition for YBCO film fabrication of superconducting fault-current limiter

    Energy Technology Data Exchange (ETDEWEB)

    Jun, Byung Hyuk; Kim, Chan Joong

    2006-05-15

    Since the high-temperature superconductor of oxide type was founded, many researches and efforts have been performed for finding its application field. The YBCO superconducting film fabricated on economic metal substrate with uniform critical current density is considered as superconducting fault-current limiter (SFCL). There are physical and chemical processes to fabricate superconductor film, and it is understood that the chemical methods are more economic to deposit large area. Among them, chemical vapor deposition (CVD) is a promising deposition method in obtaining film uniformity. To solve the problems due to the high deposition temperature of thermal CVD, plasma-enhanced chemical vapor deposition (PECVD) is suggested. This report describes the principle and fabrication trend of SFCL, example of YBCO film deposition by PECVD method, and principle of plasma deposition.

  9. Atomic oxygen effect on the in situ growth of stoichiometric YBa2Cu3O7 - delta epitaxial films by facing targets 90° off-axis radiofrequency magnetron sputtering

    Science.gov (United States)

    Oya, Gin-ichiro; Diao, Chien Chen; Imai, Syozo; Uzawa, Takaaki; Sawada, Yasuji; Sugai, Tokuko; Nakajima, Kensuke; Yamashita, Tsutomu

    1995-06-01

    (110)- and (103)-oriented almost stoichiometric YBa2Cu3O7-δ (YBCO) films have been grown epitaxially on hot SrTiO3 (110) substrates using a 90° off-axis rf magnetron sputtering technique, for fabrication of vertical sandwich-type YBCO/insulator/YBCO or YBCO/normal metal/YBCO Josephson junctions utilizing the high-quality YBCO films. The YBCO epitaxial films with high transition temperatures Tc of ˜90 K have been deposited in situ only under the conditions of substrate temperatures Ts of ˜650-˜700 °C and oxygen partial pressure PO2 of ˜5×10-3-˜10×10-3 Torr, which are in close proximity to the critical stability/decomposition line for YBa2Cu3O6 in the ordinary Y-Ba-Cu-O phase diagram. Using a quadrupole mass spectrometer, a high density of atomic oxygen has directly been observed to be efficiently produced in the sputter glow discharge under the above optimum conditions of PO2. This atomic oxygen has played a key role in promoting the formation of the perovskite structure and the epitaxial growth of the YBCO films. Furthermore, Shapiro steps have successfully been observed for a Nb-YBCO point-contact junction, which is made by pressing a Nb needle on a surface-etched YBCO epitaxial film, under 525.4 GHz submillimeter-wave irradiation.

  10. Superconductivity

    International Nuclear Information System (INIS)

    Caruana, C.M.

    1988-01-01

    Despite reports of new, high-temperature superconductive materials almost every day, participants at the First Congress on Superconductivity do not anticipate commercial applications with these materials soon. What many do envision is the discovery of superconducting materials that can function at much warmer, perhaps even room temperatures. Others hope superconductivity will usher in a new age of technology as semiconductors and transistors did. This article reviews what the speakers had to say at the four-day congress held in Houston last February. Several speakers voiced concern that the Reagan administration's apparent lack of interest in funding superconductivity research while other countries, notably Japan, continue to pour money into research and development could hamper America's international competitiveness

  11. Niobium thin film deposition studies on copper surfaces for superconducting radio frequency cavity applications

    OpenAIRE

    W. M. Roach; D. B. Beringer; J. R. Skuza; W. A. Oliver; C. Clavero; C. E. Reece; R. A. Lukaszew

    2012-01-01

    Thin film coatings have the potential to increase both the thermal efficiency and accelerating gradient in superconducting radio frequency accelerator cavities. However, before this potential can be realized, systematic studies on structure-property correlations in these thin films need to be carried out since the reduced geometry, combined with specific growth parameters, can modify the physical properties of the materials when compared to their bulk form. Here, we present our systematic stu...

  12. Direct Observation of High-Temperature Superconductivity in One-Unit-Cell FeSe Films

    International Nuclear Information System (INIS)

    Zhang Wen-Hao; Zhang Jin-Song; Li Fang-Sen; Guo Ming-Hua; Ding Hao; Tang Chen-Jia; Wang Qing-Yan; He Ke; Ji Shuai-Hua; Chen Xi; Sun Yi; Zhao Yan-Fei; Xing Ying; Wang Hui-Chao; Zhang Hui-Min; Peng Jun-Ping; Li Zhi; Wang Meng; Fujita Takeshi; Hirata Akihiko

    2014-01-01

    We prepared one-unit-cell (1-UC) thick FeSe films on insulating SrTiO 3 substrates with non-superconducting FeTe protection layers by molecular beam epitaxy for ex situ studies. By direct transport and magnetic measurements, we provide definitive evidence for high temperature superconductivity in the 1-UC FeSe films with an onset T C above 40 K and an extremely large critical current density J C ∼1.7×10 6 A/cm 2 at 2 K, which are much higher than T C ∼8 K and J C ∼10 4 A/cm 2 for bulk FeSe, respectively. Our work may pave the way to enhancing and tailoring superconductivity by interface engineering. (express letter)

  13. Superconducting thin films of Bi-Sr-Ca-Cu-O by laser ablation

    Science.gov (United States)

    Bedekar, M. M.; Safari, A.; Wilber, W.

    1992-11-01

    Superconducting thin films of Bi-Sr-Ca-Cu-O have been deposited by KrF excimer laser ablation. The best in situ films showed a Tc onset of 110 K and a Tc(0) of 76 K. A study of the laser plume revealed the presence of two distinct regimes. The forward directed component increased with fluence and the film composition was stoichiometric in this region. This is in agreement with the results on the 123 system by Venkatesan et al. [1]. The film properties were found to be critically dependent on the substrate temperature and temperatures close to melting gave rise to 2212 and 2223 phases. At lower temperatures, 2201 and amorphous phases were obtained. The film morphology and superconducting properties were a function of the target to substrate distance and the oxygen pressure during deposition and cooling. An increase in the target to substrate distance led to a deterioration of the properties due to the energy consideration for the formation of 2212 and 2223 phases. The best films were obtained using cooling pressures of 700 Torr. The microwave surface resistance of the films measured at 35 GHz dropped below that of copper at 30 K. Film growth was studied using X-ray diffraction and STM/AFM. This work is a discussion of the role of the different variables on the film properties.

  14. Final report: High current capacity high temperature superconducting film based tape for high field magnets

    International Nuclear Information System (INIS)

    Ying Xin

    2000-01-01

    The primary goal of the program was to establish the process parameters for the continuous deposition of high quality, superconducting YBCO films on one meter lengths of buffered RABiTS tape using MOCVD and to characterize the potential utility of the resulting tapes in high field magnet applications

  15. Development of Strontium Titanate Thin films on Technical Substrates for Superconducting Coated Conductors

    DEFF Research Database (Denmark)

    Pallewatta, Pallewatta G A P; Yue, Zhao; Grivel, Jean-Claude

    2012-01-01

    SrTiO3 is a widely studied perovskite material due to its advantages as a template for high temperature superconducting tapes. Heteroepitaxial SrTiO3 thin films were deposited on Ni/W tapes using dip-coating in a precursor solution followed by drying and annealing under reducing conditions. Nearl...

  16. Vortex pinning in superconducting Nb thin films deposited on nanoporous alumina templates

    DEFF Research Database (Denmark)

    Vinckx, W.; Vanacken, J.; Moshchalkov, V.V.

    2006-01-01

    We present a study of magnetization and transport properties of superconducting Nb thin films deposited on nanoporous aluminium oxide templates. Periodic oscillations in the critical temperature vs. field, matching effects in fields up to 700 mT and strongly enhanced critical currents were observed...

  17. Electric field dependence of excess electrical conductivity below transition temperature in thin superconducting lead films

    Energy Technology Data Exchange (ETDEWEB)

    Ashwini Kumar, P K; Duggal, V P [Delhi Univ. (India). Dept. of Physics and Astrophysics

    1976-01-26

    Results of measurements of the electric field dependence of the excess electrical conductivity are reported in thin superconducting lead films below the transition temperature. It is observed that the normal state sheet resistance has some effect on the nonlinearity but the theory of Yamaji still fits well to the experimental data.

  18. Superconductivity in volumetric and film ceramics Bi-Sr-Ca-Cu-O

    International Nuclear Information System (INIS)

    Sukhanov, A.A.; Ozmanyan, Kh.R.; Sandomirskij, B.B.

    1988-01-01

    A superconducting transition with T c0 =82-95 K and T c (R=0)=82-72 K was observed in volumetric and film Bi(Sr 1-x Ca x ) 2 Cu 3 O y samples obtained by solid-phase reaction. Temperature dependences of resistance critical current and magnetic susceptibility are measured

  19. Superconductivity in Bi-Sr-Ca-Cu-O bulk and film ceramics

    Energy Technology Data Exchange (ETDEWEB)

    Sukhanov, A A; Ozmanian, KH R; Sandomirskii, B B

    1988-07-01

    A superconducting transition with Tc0 = 82-95 K and Tc(R = 0) = 82-72 K was observed in Bi(Sr/1-x/Ca/x/)2Cu3O(y) bulk and film specimens obtained via a solid-phase reaction. Temperature dependences of the resistance, critical current, and magnetic susceptibility were measured.

  20. Superconductivity effects near metal-insulator transition in granular idnium films

    International Nuclear Information System (INIS)

    Belevtsev, B.I.; Komnik, Yu.F.; Fomin, A.V.

    1986-01-01

    The influence of granules superconductivity on the electric properties of granular indium films is investigated under the conditions of partial or full granular localization of electrons. At temperatures below 5 K a minimum of electric resistance and negative magnetoresistance are revealed which are attributed to the competition of hopping conductivity and Josephson intergranular tunneling of electrons

  1. Buffer layers for REBCO films for use in superconducting devices

    Science.gov (United States)

    Goyal, Amit; Wee, Sung-Hun

    2014-06-10

    A superconducting article includes a substrate having a biaxially textured surface. A biaxially textured buffer layer, which can be a cap layer, is supported by the substrate. The buffer layer includes a double perovskite of the formula A.sub.2B'B''O.sub.6, where A is rare earth or alkaline earth metal and B' and B'' are different transition metal cations. A biaxially textured superconductor layer is deposited so as to be supported by the buffer layer. A method of making a superconducting article is also disclosed.

  2. Evolution of superconducting properties with disorder in epitaxial NbN films

    International Nuclear Information System (INIS)

    Chockalingam, S P; Chand, Madhavi; Jesudasan, John; Raychaudhuri, Pratap; Tripathi, Vikram

    2009-01-01

    NbN is a conventional BCS superconductor in which disorder can be tuned from moderately clean limit to dirty limit without affecting its epitaxial nature. We studied the superconducting properties of epitaxial NbN films of different disorder characterized by k F l ranging from 8.77 to 2.56 through the transport measurements. Using reactive magnetron sputtering NbN films of different disorder are deposited by varying the sputtering power and amount of N 2 in Ar:N 2 mixture of sputtering gas. The disorder parameter k F l is obtained from the carrier density (n) and the resistivity (ρ) of the films. NbN films with higher disorder have lower transition temperature (T c ) and larger resistivity which decreases with decreasing disorder. The carrier density determined from Hall measurements show that highly disordered films have lower carrier density and vice versa. Our studies show that NbN is a good system to investigate the effects of disorder on superconductivity where the superconducting properties evolve with the disorder in thin films.

  3. Microwave effective surface impedance of structures including a high-Tc superconducting film

    International Nuclear Information System (INIS)

    Hartemann, P.

    1992-01-01

    The microwave effective surface impedances of different stacks made of high-temperature superconducting films, dielectric materials and bulk normal metals were computed. The calculations were based on the two-fluid model of superconductors and the conventional transmission line theory. These effective impedances are compared to the calculated intrinsic surface impedances of the stacked superconducting films. The considered superconducting material has been the oxide YBa 2 Cu 3 O 7 epitaxially grown on crystalline substrates (MgO, LaAlO 3 , SrTiO 3 ), the film thickness ranging from a few nm to 1μm. Discrepancies between the effective surface resistances or reactances and the corresponding intrinsic values were determined at 10 GHz for non resonant or resonant structures. At resonance the surface resistance discrepancy exhibits a sharp peak which reaches 10 4 or more in relative value according to the geometry and the used materials. Obviously the effective surface reactance shows also huge variations about the resonance and may be negative. Moreover geometries allowing to obtain an effective resistance smaller than the film intrinsic value have been found. The effects of the resonance phenomenon on the electromagnetic wave reflectivity and reflection phase shift are investigated. Therefore the reported theoretical results demonstrate that the effective surface impedance of YBCO films with a thickness smaller than 500 nm can be very different from the intrinsic film impedance according to the structures. (Author). 3 refs., 10 figs., 2 tabs

  4. Stationary states and dynamics of superconducting thin films

    DEFF Research Database (Denmark)

    Ögren, Magnus; Sørensen, Mads Peter; Pedersen, Niels Falsig

    can handle complex geometries also in a three-dimensional superconducting structure. To include external currents in our modelling we discuss the role of the boundary conditions for the external magnetic field [4]. Finally we show results for the pinning of vortices with controlled impurities....

  5. Superconductivity

    CERN Document Server

    Ketterson, John B

    2008-01-01

    Conceived as the definitive reference in a classic and important field of modern physics, this extensive and comprehensive handbook systematically reviews the basic physics, theory and recent advances in the field of superconductivity. Leading researchers, including Nobel laureates, describe the state-of-the-art in conventional and unconventional superconductors at a particularly opportune time, as new experimental techniques and field-theoretical methods have emerged. In addition to full-coverage of novel materials and underlying mechanisms, the handbook reflects continued intense research into electron-phone based superconductivity. Considerable attention is devoted to high-Tc superconductivity, novel superconductivity, including triplet pairing in the ruthenates, novel superconductors, such as heavy-Fermion metals and organic materials, and also granular superconductors. What’s more, several contributions address superconductors with impurities and nanostructured superconductors. Important new results on...

  6. Response of fractal penetration of magnetic flux to disorder landscape in superconducting films

    Science.gov (United States)

    Ye, Zuxin; Li, Qiang; Si, W. D.; Suenaga, M.; Solovyov, V. F.; Johnson, P. D.

    2005-10-01

    Magnetic flux front and induction contours in superconducting YBa2Cu3O7-δ films with defect size stilde ξ (superconducting coherence length) and s≫ξ are studied by magneto-optical imaging. Robust self-affine spatial correlation was observed using scaling analysis in the small pinning disorder-dominated ( stilde ξ) films. The roughness exponent α was determined to be ˜0.66 , independent of numbers of defects (or the film thickness). When the disorder landscape also included a distribution of large defects (s≫ξ) , the flux front and induction contours exhibited self-similarity, with a fractal dimension D determined to be ˜1.33 using the box-counting method. The remarkably different flux penetration patterns were shown to be the manifestation of self-organized criticality at different length scales.

  7. Molecular-Beam Epitaxially Grown MgB2 Thin Films and Superconducting Tunnel Junctions

    Directory of Open Access Journals (Sweden)

    Jean-Baptiste Laloë

    2011-01-01

    Full Text Available Since the discovery of its superconducting properties in 2001, magnesium diboride has generated terrific scientific and engineering research interest around the world. With a of 39 K and two superconducting gaps, MgB2 has great promise from the fundamental point of view, as well as immediate applications. Several techniques for thin film deposition and heterojunction formation have been established, each with its own advantages and drawbacks. Here, we will present a brief overview of research based on MgB2 thin films grown by molecular beam epitaxy coevaporation of Mg and B. The films are smooth and highly crystalline, and the technique allows for virtually any heterostructure to be formed, including all-MgB2 tunnel junctions. Such devices have been characterized, with both quasiparticle and Josephson tunneling reported. MgB2 remains a material of great potential for a multitude of further characterization and exploration research projects and applications.

  8. Structural and superconducting properties of sputter-deposited niobium films for applications in RF accelerating cavities

    CERN Document Server

    Peck, M A

    2000-01-01

    The present work presents the results of a systematic study of superconducting and structural properties of niobium films sputter deposited onto the inner walls of radiofrequency copper resonators. The measured superconducting quantities include the surface resistance, the critical temperature, the penetration depth and the upper and lower critical fields. In addition to films grown with different discharge gases (Xe, Kr, Ar, Ne and Ar-Ne mixtures) and to films grown on substrates prepared under different conditions, the study also includes massive niobium cavities. The surface resistance is analysed in terms of its dependence on the temperature and on the rf field amplitude and, when possible, compared to theoretical predictions. In general, good agreement with BCS theory is observed. All experimental results are presented in the form of a simple, but adequate parameterisation. The residual resistance is observed to be essentially uncorrelated with the other variables, but strongly dependent on the macroscop...

  9. The growth of large-area superconducting YBa2Cu3O7-x thin films by pulsed laser ablation

    International Nuclear Information System (INIS)

    Lai, H.C.; Chang, C.M.; Lin, R.J.; Liu, R.S.

    1996-01-01

    In-situ growth of 2-in. diameter superconducting YBa 2 Cu 3 O 7-x (YBCO) thin films using an excimer KrF pulsed laser has been studied. Films with critical transition temperature (T c,0 ) of 89±1 K and critical current density (J c,77K ) in excess of 1 x 10 6 A cm -2 have been prepared routinely. Uniformity in film thickness of below ±15% and film composition of ±5% have been measured. The effects of gas nozzle geometry and target evolution during ablation on the superconducting properties and surface morphology of YBCO thin films have also been investigated. (orig.)

  10. Temperature dependence of the experimental penetration depth of superconducting thin films

    International Nuclear Information System (INIS)

    Fink, H.J.; Gruenfeld, V.; Pastawski, H.

    1982-01-01

    Experimental magnetic field penetration depths delta(t,d,H) of the stable and superheated Meissner state were calculated as a function of temperature for various applied magnetic fields and various film thicknesses for two cases: (1) lambda(t)/d<< kappa→infinity and (2) kappa< or approx. =2lambda(t)/d (lambda is the Ginzburg-Landau penetration depth, d is the film thickness, kappa is the GL parameter). The results of the first case should be a useful tool for obtaining lambda(0) of amorphous superconducting thin films

  11. Raman scattering diagnostics of YBa2Cu3Ox high temperature superconducting films

    International Nuclear Information System (INIS)

    Bagratashvili, V.N.; Burimov, V.N.; Denisov, V.N.

    1988-01-01

    Superconducting YBa 2 Cu 3 O x films produced by laser spraying of ceramic material are investigated by light Raman scattering (LCS). It is shown that using LCS it is possible to obtain data on phase composition and prevailing film orientation and to find optical conditions for their synthesis. The LCS method feature consists in a possibility of non-destructive remote control and high space resolution (several microns). Experimental results have shown that the best parameters (the highest T c and the narrowest Δ T c interval) are typical of films with prevailing orientation of 0 xy crystallite plane parallel to the surface

  12. Lanthanum gallate substrates for epitaxial high-temperature superconducting thin films

    International Nuclear Information System (INIS)

    Sandstrom, R.L.; Giess, E.A.; Gallagher, W.J.; Segmueller, A.; Cooper, E.I.; Chisholm, M.F.; Gupta, A.; Shinde, S.; Laibowitz, R.B.

    1988-01-01

    We demonstrate that lanthanum gallate (LaGaO 3 ) has considerable potential as an electronic substrate material for high-temperature superconducting films. It provides a good lattice and thermal expansion match to YBa 2 Cu 3 O/sub 7-//sub x/, can be grown in large crystal sizes, is compatible with high-temperature film processing, and has a reasonably low dielectric constant (ε≅25) and low dielectric losses. Epitaxial YBa 2 Cu 3 O/sub 7-//sub x/ films grown on LaGaO 3 single-crystal substrates by three techniques have zero resistance between 87 and 91 K

  13. Lanthanum gallate substrates for epitaxial high-temperature superconducting thin films

    Science.gov (United States)

    Sandstrom, R. L.; Giess, E. A.; Gallagher, W. J.; Segmuller, A.; Cooper, E. I.

    1988-11-01

    It is demonstrated that lanthanum gallate (LaGaO3) has considerable potential as an electronic substrate material for high-temperature superconducting films. It provides a good lattice and thermal expansion match to YBa2Cu3O(7-x), can be grown in large crystal sizes, is compatible with high-temperature film processing, and has a reasonably low dielectric constant and low dielectric losses. Epitaxial YBa2Cu3O(7-x) films grown on LaGaO3 single-crystal substrates by three techniques have zero resistance between 87 and 91 K.

  14. Influence of reversible epitactical stress on the electronic properties of thin superconducting films

    International Nuclear Information System (INIS)

    Trommler, Sascha

    2014-01-01

    In this thesis new stress techniques are applied on thin superconducting (La,Sr) 2 CuO 4 and BaFe 1.8 Co 0.2 As 2 films. At one hand piezoelectric substrates are applied, which make a biaxial stress of the thin film deposed there possible, whereby the lattice parameters of the substrate are altered by an electric field. At the other hand on the base of flexible substrates by means of a bending experiment a uniaxial lattice deformation of thin film is realized.

  15. Superconducting Film Flux Transformer for a Sensor of a Weak Magnetic Field

    International Nuclear Information System (INIS)

    Ichkitidze, L; Mironyuk, A

    2012-01-01

    The object of study is a superconducting film flux transformer in the form of a square shaped loop with the tapering operative strip used in a sensor of a weak magnetic field. The magnetosensitive film element based on the giant magnetoresistance effect is overlapped with the tapering operative strip of the flux transformer; it is separated from the latter by the insulator film. It is shown that the topological nanostructuring of the operative strip of the flux transformer increases its gain factor by one or more orders of magnitude, i.e. increases its efficiency, which leads to a significant improvement of important parameters of a magnetic-field sensor.

  16. Frustrated magnetic response of a superconducting Nb film with a square lattice of columnar defects

    Energy Technology Data Exchange (ETDEWEB)

    Zadorosny, R; Ortiz, W A [Grupo de Supercondutividade e Magnetismo, Departamento de Fisica, Universidade Federal de Sao Carlos, Sao Carlos, SP (Brazil); Lepienski, C M [Universidade Federal do Parana, Departamento de Fisica, Curitiba, PR (Brazil); Patino, E; Blamire, M G [Department of Materials Science, University of Cambridge, Pembroke Street, Cambridge CB2 3QZ (United Kingdom)], E-mail: rafazad@df.ufscar.br

    2008-02-01

    The magnetic response of a superconducting system presenting a frustrated state is investigated. The system is a superconducting film with mechanically pierced columns, cooled in a field which is then removed. Frustration originates from the competition between return flux of a dipole - created by flux trapped in the empty columns - and flux exclusion by the surrounding superconductor in the Meissner state. The system resolves the incompatibility among conflicting constraints, leading to frustration, by eliminating return flux, which is possibly assimilated by nearby columns, as manifested by a sudden reduction of the magnetic moment on the decreasing field branch of the hysteresis loop.

  17. Frustrated magnetic response of a superconducting Nb film with a square lattice of columnar defects

    International Nuclear Information System (INIS)

    Zadorosny, R; Ortiz, W A; Lepienski, C M; Patino, E; Blamire, M G

    2008-01-01

    The magnetic response of a superconducting system presenting a frustrated state is investigated. The system is a superconducting film with mechanically pierced columns, cooled in a field which is then removed. Frustration originates from the competition between return flux of a dipole - created by flux trapped in the empty columns - and flux exclusion by the surrounding superconductor in the Meissner state. The system resolves the incompatibility among conflicting constraints, leading to frustration, by eliminating return flux, which is possibly assimilated by nearby columns, as manifested by a sudden reduction of the magnetic moment on the decreasing field branch of the hysteresis loop

  18. Collective-pinning properties of superconducting a-NbxGe and a-MoxSi films

    International Nuclear Information System (INIS)

    Woerdenweber, R.

    1987-01-01

    This thesis describes a study of superconducting flux pinning in amorphous NbGe and MoSi films of various compositions and thickness. Amorphous NbGe and MoSi alloys belong to the weak-coupling type-II superconductors in the extreme dirty limit. This feature enables to determine several important superconducting parameters from well-known theoretical expressions. It is also responsible for the weak pinning, which is necessary to observe the two-dimensional collective pinning properties according to the Larkin-Ovchinnikov theory. (Auth.)

  19. Vortex loops in the critical Casimir effect in superfluid and superconducting films

    International Nuclear Information System (INIS)

    Williams, Gary A.

    2004-01-01

    Vortex-loop renormalization techniques are used to calculate the magnitude of the critical Casimir forces in superfluid and superconducting thin films. The force is found to become appreciable when the size of the thermally excited vortex loops is comparable to the film thickness, and the results for T c are found to match very well with perturbative renormalization-group theories that can only be carried out for T>T c . In helium films the Casimir force leads to a change in the film thickness close to T c that has been observed experimentally. A similar effect is predicted to occur near the transition temperature of high-T c superconducting films, which is also a vortex-loop phase transition. In this case the Casimir force takes the form of a voltage difference that will appear at the junction between a thin film and a bulk sample. Estimates show that this voltage can be appreciable (tens of microvolts), and it may be possible to observe the effect by measuring the voltage across two Josephson tunnel junctions to the film and to the bulk, using a SQUID voltmeter

  20. Quasi-one-dimensional intermittent flux behavior in superconducting films

    DEFF Research Database (Denmark)

    Qviller, A. J.; Yurchenko, V. V.; Galperin, Y. M.

    2012-01-01

    Intermittent filamentary dynamics of the vortex matter in superconductors is found in films of YBa2Cu3O7-δ deposited on tilted substrates. Deposition of this material on such substrates creates parallel channels of easy flux penetration when a magnetic field is applied perpendicular to the film. ...

  1. Influence of ion beam mixing on the growth of high temperature oxide superconducting thin film

    International Nuclear Information System (INIS)

    Bordes, N.; Rollett, A.D.; Cohen, M.R.; Nastasi, M.

    1989-01-01

    The superconducting properties of high temperature superconductor thin films are dependent on the quality of the substrate used to grow these films. In order to maximize the lattice matching between the superconducting film and the substrate, we have used a YBa 2 Cu 3 O 7 thin film deposited on left-angle 100 right-angle SrTiO 3 as a template. The first film was prepared by coevaporation of Y, BaF 2 and Cu on left-angle 100 right-angle SrTiO 3 , followed by an anneal in ''wet'' oxygen at 850 degree C. This film showed a sharp transition at about 90 K. A thicker layer of about 5000 A was then deposited on top of this first 2000 angstrom film, using the same procedure. After the post anneal at 850 degree C, the transition took place at 80 K and no epitaxy of the second film was observed. Ion beam mixing at 400 degree C, using 400 keV O ions was done at the interface of the two films (the second one being not annealed). After the post anneal, the film displayed an improved Tc at 90K. Moreover, epitaxy was shown to take place from the interface SrTiO 3 -123 film towards the surface and was dependent of the dose. These results will be discussed from the data obtained from Rutherford backscattering spectroscopy (RBS) combined with channeling experiments, x-ray diffraction (XRD) and scanning electron microscopy (SEM) observations. 8 refs., 2 figs., 2 tabs

  2. Application of High-Temperature Superconducting Thin-Film Devices to Electro-Optical and Electronic Warfare Systems

    Science.gov (United States)

    1990-02-01

    superconducting dispersive (chirp) delay line. Bt currents (IB 1 and 1B 2) control states of write junctions (gates 1 and 2). (Counter) clockwise currents...Gavaler, and "S. A. Reihle, "Superconductive Convolver with June- A. I. Braginski, "Optical Response of Epitaxial Films tion Ring Nlixers," IELT Trans

  3. Disorder and fluctuations in superconducting YBa2Cu3O6.9 films

    International Nuclear Information System (INIS)

    Gauzzi, A.

    1993-01-01

    We have developed the technique of ion-beam sputtering to grow thin (∼ 100 nm) superconducting YBa 2 Cu 3 O 6.9 (YBCO) films. We demonstrate that this technique is suitable for the in-situ deposition at low temperatures ( o C) of uniform films over large areas (≤30 cm 2 ). We found that preferential sputtering effects disappear if low-power ions-beams are used, thus enabling the control of the 1:2:3 composition by using a single stoichiometric target. We have found that the disorder in the crystal, introduced by too high or too low growth temperatures, affects strikingly both, the superconducting and the transport properties of the films. We report evidence that disorder on the atomic scale plays a role equivalent to oxygen doping. The similarity observed between the effects of crystal disorder in our films and the effects of oxygen depletion or Co-doping reported in the literature suggests that the disorder affects mainly the CuO chains. This implies that the local order of the chains controls not only the superconducting properties, as already established in the literature, but also the transport of the carriers in the normal state. Finally, we have investigated the local character of the superconducting state of YBCO by studying the paraconductivity in our films. We have found no indication of critical fluctuations at temperatures ≥5 mK above the zero-resistance critical temperature. Our analysis indicates that the spectrum of mean-field fluctuations is dominated by short-wavelength components and is affected by disorder. As a consequence, the temperature dependence of the critical exponents becomes complex and deviates from the universal predictions of conventional theories. We have explained quantitatively our experimental data and clarified the controversy existing in the literature by using a three-dimensional cut-off approach applied to the Lorentzian spectrum of the Ginzburg-Landau theory. (author) figs., tabs., refs

  4. Anomalous magnetism of superconducting Mg-doped InN film

    Directory of Open Access Journals (Sweden)

    P. H. Chang

    2016-02-01

    Full Text Available We report on the Meissner effect of Mg-doped InN film with superconducting transition onset temperature Tc,onset of 5 K. Mg-doped InN is magnetically ordered and exhibits a simultaneous first-order magnetic and electric transition near 50 K. Its behavior is similar to that of iron-based superconductors. A strong correlation is proposed to exist between structural distortion and superconductivity when Mg is doped into InN. The suppression of magnetic ordering close to Tc by doping is further demonstrated by anisotropic magnetoresistance and M-H measurements. The findings suggest that the superconducting mechanism in the system may not be conventional BCS.

  5. Superconductivity of Rock-Salt Structure LaO Epitaxial Thin Film.

    Science.gov (United States)

    Kaminaga, Kenichi; Oka, Daichi; Hasegawa, Tetsuya; Fukumura, Tomoteru

    2018-06-06

    We report a superconducting transition in a LaO epitaxial thin film with the superconducting transition onset temperature ( T c ) at around 5 K. This T c is higher than those of other lanthanum monochalcogenides and opposite to their chemical trend: T c = 0.84, 1.02, and 1.48 K for LaX (X = S, Se, Te), respectively. The carrier control resulted in a dome-shaped T c as a function of electron carrier density. In addition, the T c was significantly sensitive to epitaxial strain in spite of the highly symmetric crystal structure. This rock-salt superconducting LaO could be a building block to design novel superlattice superconductors.

  6. Related electrical, superconducting and structural characteristics of low temperature indium films

    International Nuclear Information System (INIS)

    Belevtsev, B.I.; Pilipenko, V.V.; Yatsuk, L.Ya.

    1981-01-01

    Reported are results of a complex study of electrical, superconducting and structural properties of indium films vacuum evaporated onto a liquid helium-cooled substrate. Structural electron diffraction investigations gave a better insight into the general features of the annealing during the warming-up of cold-deposited films. It is found that the annealing of indium films to about 80 to 100 K entails an irreversible growth of interplanar separations due to decreasing inhomogeneous microstresses. As the films are warmed from 100 to 300 K, the principal annealing processes are determined by crystallite growth and development of dominating orientation. The changes in the residual resistance and in Tsub(c) with warming the cold-deported films are explained on the base of structural data obtained. In particular, a direct relationship is revealed between the crystallite size and Tsub(c) [ru

  7. Electro-physical properties of superconducting ceramic thick film prepared by partial melting method.

    Science.gov (United States)

    Lee, Sang Heon

    2013-05-01

    BiSrCaCuO superconductor thick films were prepared at several curing temperatures, and their electro-physical properties were determined to find an optimum fabrication conditions. Critical temperatures of the superconductors were decreased with increasing melting temperature, which was related to the amount of equilibrium phases of the superconducting materials with temperature. The critical temperature of BiSrCaCuO bulk and thick film superconductors were 107 K and 96 K, respectively. The variation of susceptibility of the superconductor thick film formed at 950 degrees C had multi-step-type curve for 70 G externally applied field, whereas, a superconductor thick film formed at 885 degrees C had a single step-type curve like a bulk BiSrCaCuO ceramic superconductor in the temperature-susceptibility curves. A partial melting at 865 degrees C is one of optimum conditions for making a superconductor thick film with a relatively homogeneous phase.

  8. Superconductivity

    CERN Document Server

    Poole, Charles P; Creswick, Richard J; Prozorov, Ruslan

    2014-01-01

    Superconductivity, Third Edition is an encyclopedic treatment of all aspects of the subject, from classic materials to fullerenes. Emphasis is on balanced coverage, with a comprehensive reference list and significant graphics from all areas of the published literature. Widely used theoretical approaches are explained in detail. Topics of special interest include high temperature superconductors, spectroscopy, critical states, transport properties, and tunneling. This book covers the whole field of superconductivity from both the theoretical and the experimental point of view. This third edition features extensive revisions throughout, and new chapters on second critical field and iron based superconductors.

  9. Direct growth of superconducting NdFeAs(O,F) thin films by MBE

    Energy Technology Data Exchange (ETDEWEB)

    Chihara, Masashi, E-mail: chihara@iku.xtal.nagoya-u.ac.jp [Department of Crystalline Materials Science, Nagoya University, Chikusa-ku, Nagoya 464-8603 (Japan); Sumiya, Naoki; Arai, Kenta [Department of Crystalline Materials Science, Nagoya University, Chikusa-ku, Nagoya 464-8603 (Japan); Ichinose, Ataru; Tsukada, Ichiro [Central Research Institute of Electric Power Industry, Yokosuka-shi, Kanagawa 240-0101 (Japan); Hatano, Takafumi; Iida, Kazumasa; Ikuta, Hiroshi [Department of Crystalline Materials Science, Nagoya University, Chikusa-ku, Nagoya 464-8603 (Japan)

    2015-11-15

    Highlights: • Highly textured NdFeAs(O,F) thin films were obtained by a direct growth method. • Enhancing the migration was crucial to realize the direct growth. • The critical current density exceeded 3 MA/cm{sup 2} at self-field and 1 MA/cm{sup 2} at 9 T. • A two-dimensional growth was confirmed by the observation of surface morphology. - Abstract: We report on the growth of NdFeAs(O,F) superconducting thin films by molecular beam epitaxy without having a NdOF secondary layer that was necessary for fluorine doping in our previous studies. The key to realizing the direct growth of a superconducting film was the enhancement of migration of the raw materials on the substrate, which was accomplished by two steps. Firstly, we increased the growth temperature that improved the crystalline quality of parent NdFeAsO thin films. Secondly, the atmosphere in the chamber during the growth was improved by changing the crucible material of the Fe source cell. Highly textured NdFeAs(O,F) thin films with critical temperatures up to 50 K were obtained, and terraces were observed by atomic force microscope, indicating a two-dimensional growth. However, precipitates were also found on the surface, which suggests that enhancing further the migration is necessary for obtaining a NdFeAs(O,F) thin film with a better quality.

  10. Quasi-one-dimensional intermittent flux behavior in superconducting films

    OpenAIRE

    Qviller, A. J.; Yurchenko, V. V.; Galperin, Y. M.; Vestgården, J. I.; Mozhaev, Peter; Hansen, Jørn Bindslev; Johansen, T. H.

    2012-01-01

    Intermittent filamentary dynamics of the vortex matter in superconductors is found in films of YBa_{2}Cu_{3}O_{7-δ} deposited on tilted substrates. Deposition of this material on such substrates creates parallel channels of easy flux penetration when a magnetic field is applied perpendicular to the film. As the applied field is gradually increased, magneto-optical imaging reveals that flux penetrates via numerous quasi-one-dimensional jumps. The distribution of flux avalanche sizes follows a ...

  11. Lead-doped electron-beam-deposited Bi-Sr-Ca-Cu-O superconducting thin films

    Energy Technology Data Exchange (ETDEWEB)

    Agnihotry, S.A.; Saini, K.K.; Kant, C.; Sharma, C.P.; Ekbote, S.N.; Asthana, P.; Nagpal, K.C.; Chandra, S. (National Physical Lab., New Delhi (India))

    1991-03-20

    Superconducting thin films of the lead-doped Bi-Sr-Ca-Cu-O system have been prepared on (100) single-crystal SrTiO{sub 3} substrates by an electron beam deposition technique using a single sintered pellet as the evaporation source. As-deposited films are amorphous and non-superconducting; post-deposition annealing at an optimized temperature in air has been found to result in crystalline and superconducting films. The superconducting characteristics of the films have been observed to be sensitive not only to the duration and temperature of post-deposition annealing but also to the lead content and the sintering parameters for the pellet to be used as the evaporation source. A pellet with nominal composition Bi{sub 3}Pb{sub 1}Sr{sub 3}Ca{sub 3}Cu{sub 4}O{sub y} that had been sintered for 200 h zero resistivity Tc{sup 0}=112 K. However, films deposited using such a pellet as the evaporation source had Tc{sup 0} {approx equal} 73-78 K, as had the films deposited from a pellet without any lead. We investigated systematically films deposited from pellets with more lead and sintered for different durations. It is evident from these investigations that pellets with nominal composition Bi{sub 3}Pb{sub 2}Sr{sub 3}Ca{sub 3}Cu{sub 4}O{sub y}, i.e. with an excess of lead, and sintered for about 75 h when used as the evaporation source yield films with Tc{sup 0} {approx equal} 100 K when annealed between 835 and 840deg C for an optimized long duration. The films are characterized by X-ray diffraction and energy-dispersive spectroscopy techniques and have been found to be highly c axis oriented. The effect of lead in promoting a high Tc{sup 0}=110 K phase seems to be similar to that in bulk ceramics. (orig.).

  12. Ultrasensitive interplay between ferromagnetism and superconductivity in NbGd composite thin films

    Science.gov (United States)

    Bawa, Ambika; Gupta, Anurag; Singh, Sandeep; Awana, V. P. S.; Sahoo, Sangeeta

    2016-01-01

    A model binary hybrid system composed of a randomly distributed rare-earth ferromagnetic (Gd) part embedded in an s-wave superconducting (Nb) matrix is being manufactured to study the interplay between competing superconducting and ferromagnetic order parameters. The normal metallic to superconducting phase transition appears to be very sensitive to the magnetic counterpart and the modulation of the superconducing properties follow closely to the Abrikosov-Gor’kov (AG) theory of magnetic impurity induced pair breaking mechanism. A critical concentration of Gd is obtained for the studied NbGd based composite films (CFs) above which superconductivity disappears. Besides, a magnetic ordering resembling the paramagnetic Meissner effect (PME) appears in DC magnetization measurements at temperatures close to the superconducting transition temperature. The positive magnetization related to the PME emerges upon doping Nb with Gd. The temperature dependent resistance measurements evolve in a similar fashion with the concentration of Gd as that with an external magnetic field and in both the cases, the transition curves accompany several intermediate features indicating the traces of magnetism originated either from Gd or from the external field. Finally, the signatures of magnetism appear evidently in the magnetization and transport measurements for the CFs with very low (<1 at.%) doping of Gd.

  13. Ultrathin NbN film superconducting single-photon detector array

    International Nuclear Information System (INIS)

    Smirnov, K; Korneev, A; Minaeva, O; Divochiy, A; Tarkhov, M; Ryabchun, S; Seleznev, V; Kaurova, N; Voronov, B; Gol'tsman, G; Polonsky, S

    2007-01-01

    We report on the fabrication process of the 2 x 2 superconducting single-photon detector (SSPD) array. The SSPD array is made from ultrathin NbN film and is operated at liquid helium temperatures. Each detector is a nanowire-based structure patterned by electron beam lithography process. The advances in fabrication technology allowed us to produce highly uniform strips and preserve superconducting properties of the unpatterned film. SSPD exhibit up to 30% quantum efficiency in near infrared and up to 1% at 5-μm wavelength. Due to 120 MHz counting rate and 18 ps jitter, the time-domain multiplexing read-out is proposed for large scale SSPD arrays. Single-pixel SSPD has already found a practical application in non-invasive testing of semiconductor very-large scale integrated circuits. The SSPD significantly outperformed traditional single-photon counting avalanche diodes

  14. Structure and superconducting properties of Nb-Zr alloy films made by a high-rate sputtering

    International Nuclear Information System (INIS)

    Sekine, Hisashi; Inoue, Kiyoshi; Tachikawa, Kyoji

    1978-01-01

    Superconducting Nb-Zr alloy films have been prepared by a continuous high-rate sputtering on tantalum substrates. A deposition rate of 330 nm/min has been attained. The compositional profile in the Nb-Zr film is quite uniform and the film has nearly the same composition as that of the target. The films deposited in a pure argon atmosphere show a columnar structure grown perpendicular to the substrate. The grain size strongly depends on the substrate temperature. The phase transformations in the Nb-Zr film become more apparent and the structure becomes closer to the equilibrium state as the film is deposited in higher atmosphere pressures and/or at lower target voltages. The superconducting transition temperature T sub(c) of the films is about the same as that of bulk samples. The dependence of T sub(c) on the substrate temperature is explainable on the phase transformations in the film. Critical current density J sub(c) and its anisotropy is closely related to the grain structure of the film. Grain boundaries seem to act as the most predominant flux pinning centers in the films. Effects of oxygen in the sputtering atmosphere on the structure and superconducting properties of the Nb-Zr films have been also investigated. Oxygen significantly decreases the grain size of the film. Oxygen increases J sub(c) but decreases T sub(c) of the film. (auth.)

  15. Structure of high-Tc superconducting tetragonal Ba2YCu2.856Al0.04O6.76 at 298 and 120 K

    International Nuclear Information System (INIS)

    Sato, S.

    1989-01-01

    It was found by chemical analysis that a slight amount of aluminium existed as an impurity in the crystals of the Y-Ba-Cu-O system whose structure was determined by Sato, Nakada, Kohara and Oda. Occupancies of atoms in 1(a) [the Cu(1) site] were 0.856(5) Cu, 0.04 Al and 0.104 vacancy. (orig.)

  16. Preparation and analysis of superconducting Nb-Ge films

    International Nuclear Information System (INIS)

    Testardi, L.R.; Meek, R.L.; Poate, J.M.; Royer, W.A.; Storm, A.R.; Wernick, J.H.

    1975-01-01

    The dependences of T/subc/, resistivity, resistance ratio, and structure on chemical composition and sputtering conditions for Nb-Ge films have been studied. The chemical composition, impurity content, and x-ray structure were obtained using Rutherford backscattering, nuclear techniques, and x-ray diffraction. Although T/subc/ varies with composition, it is not found to be critically dependent upon exact stoichiometry; the Nb/Ge ratios vary by approx. 13% (2.6 to 3) for films with approx. 23-K onsets and by approx. 40% (2.2 to 3.3) for films with approx. 20-K onsets. For compositions similar to the bulk, the films have comparitively much higher T/subc/'s and smaller lattice parameters. X-ray results show the films to contain predominately A-15 phase (except for Nb/Ge less-than or equal to 2.5) with lattice parameters varying from 5.15 A for Nb-rich low-T/subc/ films to 5.12 A for Ge-rich films. Several percent of oxygen and carbon occur in low-T/subc/ amorphous films deposited at 650 degreeC but this is considerably reduced in high-T/subc/ films made simultaneously at approx. 750 degreeC. No argon was found and the nitrogen content was generally less than 1%. No correlation of high T/subc/'s and impurities was found. The optimum deposition temperature and resistivity are lowest, and the resistance ratio highest for Nb/Ge ratios somewhat below 3/1. A simple correlation of T/subc/ and resistance ratio is reported which is largely independent of all sputtering conditions and composition and which suggests that slightly higher T/subc/'s may be possible. Negative bias was found to be detrimental to T/subc/ while positive bias had relatively little effect. Magnetic-field-assisted sputtering led to significant increases in the sputtering rate and the optimum deposition temperature

  17. Far-infrared electrodynamics of thin superconducting NbN film in magnetic fields

    Czech Academy of Sciences Publication Activity Database

    Šindler, Michal; Tesař, Roman; Koláček, Jan; Szabó, P.; Samuely, P.; Hašková, V.; Kadlec, Christelle; Kadlec, Filip; Kužel, Petr

    2014-01-01

    Roč. 27, č. 5 (2014), 1-8 ISSN 0953-2048 R&D Projects: GA ČR(CZ) GAP204/11/0015; GA MŠk(CZ) LD14060 Institutional support: RVO:68378271 Keywords : superconductivity * thin films * scanning tunneling spectroscopy * time-domain terahertz spectroscopy Subject RIV: BM - Solid Matter Physics ; Magnetism Impact factor: 2.325, year: 2014

  18. Superconductivity in volumetric and film ceramics Bi-Sr-Ca-Cu-O

    Energy Technology Data Exchange (ETDEWEB)

    Sukhanov, A A; Ozmanyan, Kh R; Sandomirskij, B B

    1988-07-10

    A superconducting transition with T/sub c0/=82-95 K and T/sub c/(R=0)=82-72 K was observed in volumetric and film Bi(Sr/sub 1-x/Ca/sub x/)/sub 2/Cu/sub 3/O/sub y/ samples obtained by solid-phase reaction. Temperature dependences of resistance critical current and magnetic susceptibility are measured.

  19. High current densities in superconducting films from magnetization

    International Nuclear Information System (INIS)

    McGuire, T.R.; Gupta, A.; Koren, G.; Gross, R.

    1990-01-01

    Epitaxial thin films of YBa 2 Cu 3 O 7-x made by laser ablation have the CuO planes parallel to the film surface. In the CuO planes critical currents of J C ∼40 x 10 6 amps/cm 2 are found at 5K in zero field. Multi-layered films with Gd replacing Y each .01μm in thickness have J C nearly 140 x 10 6 amps/cm 2 . This higher value is perhaps due to additional point defects. Perpendicular to the CuO planes magnetization studies indicate strong pinning effects attributed to the CuO planes acting as barriers to flux motion

  20. Model of vortex dynamics in superconducting films in two-coil measurements of the coherence length

    Science.gov (United States)

    Lemberger, Thomas; Loh, Yen Lee

    In two-coil measurements on superconducting films, a magnetic field from a small coil is applied to the center of the film. When the amplitude of the ac field is increased, the film undergoes a transition from the ``Meissner'' state to a state with vortices and antivortices. Ultimately, the vortex density matches the applied magnetic field and field screening is negligible. Experimentally, the field at the transition is related to the superconducting coherence length, although a full theory of the relationship is lacking. We show that the mutual inductance between drive and pickup coils, on opposite sides of the film, as a function of ac field amplitude is well-described by a phenomenological model in which vortices and antivortices appear together in the film at the radius where the induced supercurrent is strongest, and then they move through a landscape of moderately strong vortex pinning sites. Work at OSU supported by DOE-Basic Energy Sciences through Grant No. FG02-08ER46533.

  1. Depth profiling of superconducting thin films using rare gas ion sputtering with laser postionization

    International Nuclear Information System (INIS)

    Pallix, J.B.; Becker, C.H.; Missert, N.; Char, K.; Hammond, R.H.

    1988-01-01

    Surface analysis by laser ionization (SALI) has been used to examine a high-T/sub c/ superconducting thin film of nominal composition YBa 2 Cu 3 O 7 deposited on SrTiO 3 (100) by reactive magnetron sputtering. The main focus of this work was to probe the compositional uniformity and the impurity content throughout the 1800 A thick film having critical current densities of 1 to 2 x 10 6 A/cm 2 . SALI depth profiles show this film to be more uniform than thicker films (∼1 μm, prepared by electron beam codeposition) which were studied previously, yet the data show that some additional (non-superconducting) phases derived from Y, Ba, Cu, and O are still present. These additional phases are studied by monitoring the atomic and diatomic-oxide photoion profiles and also the depth profiles of various clusters (e.g. Y 2 O 2 + , Y 2 O 3 + , Y 3 O 4 + , Ba 2 O + , Ba 2 O 2 + , BaCu + , BaCuO + , YBaO 2 + , YSrO 2 + , etc.). A variety of impurities are observed to occur throughout the film including rather large concentrations of Sr. Hydroxides, F, Cl, and CO/sub x/ are evident particularly in the sample's near surface region (the top ∼100 A)

  2. Depth profiling of superconducting thin films using rare gas ion sputtering with laser postionization

    Science.gov (United States)

    Pallix, J. B.; Becker, C. H.; Missert, N.; Char, K.; Hammond, R. H.

    1988-02-01

    Surface analysis by laser ionization (SALI) has been used to examine a high-Tc superconducting thin film of nominal composition YBa2Cu3O7 deposited on SrTiO3 (100) by reactive magnetron sputtering. The main focus of this work was to probe the compositional uniformity and the impurity content throughout the 1800 Å thick film having critical current densities of 1 to 2×106 A/cm2. SALI depth profiles show this film to be more uniform than thicker films (˜1 μm, prepared by electron beam codeposition) which were studied previously, yet the data show that some additional (non-superconducting) phases derived from Y, Ba, Cu, and O are still present. These additional phases are studied by monitoring the atomic and diatomic-oxide photoion profiles and also the depth profiles of various clusters (e.g. Y2O2+, Y2O3+, Y3O4+, Ba2O+, Ba2O2+, BaCu+, BaCuO+, YBaO2+, YSrO2+, etc.). A variety of impurities are observed to occur throughout the film including rather large concentrations of Sr. Hydroxides, F, Cl, and COx are evident particularly in the sample's near surface region (the top ˜100 Å).

  3. Thin film metrology and microwave loss characterization of indium and aluminum/indium superconducting planar resonators

    Science.gov (United States)

    McRae, C. R. H.; Béjanin, J. H.; Earnest, C. T.; McConkey, T. G.; Rinehart, J. R.; Deimert, C.; Thomas, J. P.; Wasilewski, Z. R.; Mariantoni, M.

    2018-05-01

    Scalable architectures characterized by quantum bits (qubits) with low error rates are essential to the development of a practical quantum computer. In the superconducting quantum computing implementation, understanding and minimizing material losses are crucial to the improvement of qubit performance. A new material that has recently received particular attention is indium, a low-temperature superconductor that can be used to bond pairs of chips containing standard aluminum-based qubit circuitry. In this work, we characterize microwave loss in indium and aluminum/indium thin films on silicon substrates by measuring superconducting coplanar waveguide resonators and estimating the main loss parameters at powers down to the sub-photon regime and at temperatures between 10 and 450 mK. We compare films deposited by thermal evaporation, sputtering, and molecular beam epitaxy. We study the effects of heating in a vacuum and ambient atmospheric pressure as well as the effects of pre-deposition wafer cleaning using hydrofluoric acid. The microwave measurements are supported by thin film metrology including secondary-ion mass spectrometry. For thermally evaporated and sputtered films, we find that two-level state are the dominant loss mechanism at low photon number and temperature, with a loss tangent due to native indium oxide of ˜ 5 × 10 - 5 . The molecular beam epitaxial films show evidence of the formation of a substantial indium-silicon eutectic layer, which leads to a drastic degradation in resonator performance.

  4. Enhanced superconductivity and superconductor to insulator transition in nano-crystalline molybdenum thin films

    Energy Technology Data Exchange (ETDEWEB)

    Sharma, Shilpam; Amaladass, E.P. [Condensed Matter Physics Division, Materials Science Group, Indira Gandhi Centre for Atomic Research, Kalpakkam 603102 (India); Sharma, Neha [Surface & Nanoscience Division, Materials Science Group, Indira Gandhi Centre for Atomic Research, Kalpakkam 603102 (India); Harimohan, V. [Condensed Matter Physics Division, Materials Science Group, Indira Gandhi Centre for Atomic Research, Kalpakkam 603102 (India); Amirthapandian, S. [Materials Physics Division, Materials Science Group, Indira Gandhi Centre for Atomic Research, Kalpakkam 603102 (India); Mani, Awadhesh, E-mail: mani@igcar.gov.in [Condensed Matter Physics Division, Materials Science Group, Indira Gandhi Centre for Atomic Research, Kalpakkam 603102 (India)

    2017-06-01

    Disorder driven superconductor to insulator transition via intermediate metallic regime is reported in nano-crystalline thin films of molybdenum. The nano-structured thin films have been deposited at room temperature using DC magnetron sputtering at different argon pressures. The grain size has been tuned using deposition pressure as the sole control parameter. A variation of particle sizes, room temperature resistivity and superconducting transition has been studied as a function of deposition pressure. The nano-crystalline molybdenum thin films are found to have large carrier concentration but very low mobility and electronic mean free path. Hall and conductivity measurements have been used to understand the effect of disorder on the carrier density and mobilities. Ioffe-Regel parameter is shown to correlate with the continuous metal-insulator transition in our samples. - Highlights: • Thin films of molybdenum using DC sputtering have been deposited on glass. • Argon background pressure during sputtering was used to tune the crystallite sizes of films. • Correlation in deposition pressure, disorder and particle sizes has been observed. • Disorder tuned superconductor to insulator transition along with an intermediate metallic phase has been observed. • Enhancement of superconducting transition temperature and a dome shaped T{sub C} vs. deposition pressure phase diagram has been observed.

  5. Bi--Sr--Ca--Cu--O superconducting films fabricated using metal alkoxides

    International Nuclear Information System (INIS)

    Katayama, S.; Sekine, M.

    1991-01-01

    Superconducting films in the Bi--Sr--Ca--Cu--O systems were made using metal alkoxides. To prepare a dip-coating solution using a mixed alkoxide solution, insoluble Cu and Bi alkoxides were dissolved by modification with 2-dimethylaminoethanol and formation of a double alkoxide, respectively. Formation of the double alkoxides of Bi with Ca or Sr was confirmed using FT-IR and 1 H-NMR. Bi--Sr--Ca--Cu--O films on yttria-stabilized ZrO 2 and single crystal MgO(100) substrates were made using this solution. The films were closely oriented along the c-axis perpendicular to the substrate. The film on MgO(100) fired at 850 degree C for 48 h showed two resistance drops around 115 and 85 K, corresponding to the high-T c and low-T c phases, respectively, and zero resistance at 72 K

  6. Thermal coupling effect on the vortex dynamics of superconducting thin films: time-dependent Ginzburg–Landau simulations

    Science.gov (United States)

    Jing, Ze; Yong, Huadong; Zhou, Youhe

    2018-05-01

    In this paper, vortex dynamics of superconducting thin films are numerically investigated by the generalized time-dependent Ginzburg–Landau (TDGL) theory. Interactions between vortex motion and the motion induced energy dissipation is considered by solving the coupled TDGL equation and the heat diffusion equation. It is found that thermal coupling has significant effects on the vortex dynamics of superconducting thin films. Branching in the vortex penetration path originates from the coupling between vortex motion and the motion induced energy dissipation. In addition, the environment temperature, the magnetic field ramp rate and the geometry of the superconducting film also greatly influence the vortex dynamic behaviors. Our results provide new insights into the dynamics of superconducting vortices, and give a mesoscopic understanding on the channeling and branching of vortex penetration paths during flux avalanches.

  7. Contactless determination of critical current density of superconducting films

    Czech Academy of Sciences Publication Activity Database

    Janů, Zdeněk; Švindrych, Zdeněk; Baničová, L.

    2012-01-01

    Roč. 22, č. 3 (2012), "9500804-1"-"9500804-4" ISSN 1051-8223 R&D Projects: GA MŠk(CZ) ME10069 Institutional research plan: CEZ:AV0Z10100520 Keywords : ac susceptibility * critical state * thin films Subject RIV: BM - Solid Matter Physics ; Magnetism Impact factor: 1.199, year: 2012

  8. Superconductivity

    International Nuclear Information System (INIS)

    Narlikar, A.V.

    1993-01-01

    Amongst the numerous scientific discoveries that the 20th century has to its credit, superconductivity stands out as an exceptional example of having retained its original dynamism and excitement even for more than 80 years after its discovery. It has proved itself to be a rich field by continually offering frontal challenges in both research and applications. Indeed, one finds that a majority of internationally renowned condensed matter theorists, at some point of their career, have found excitement in working in this important area. Superconductivity presents a unique example of having fetched Nobel awards as many as four times to date, and yet, interestingly enough, the field still remains open for new insights and discoveries which could undeniably be of immense technological value. 1 fig

  9. Superconducting thin films of Bi-Sr-Ca-Cu-O by laser ablation

    International Nuclear Information System (INIS)

    Bedekar, M.M.

    1992-01-01

    The discovery of a new class of copper oxide superconductors has led to the development of three major systems that exhibit superconducting properties. The Bi-Sr-Ca-Cu-O superconductors offer intrinsic advantages due to the high T c , chemical inertness and tolerance for a range of compositions. However, thin film research on these materials has progressed more slowly than the other cuprate systems. This dissertation examines the film growth, by laser ablation, of the Bi-Sr-Ca-Cu-O superconductors and the effect of the deposition parameters such as the laser target interaction, substrate temperature, target to substrate distance, deposition and cooling pressure, target type and processing and the substrate type. CO 2 laser ablation was shown to give rise to a non-stoichiometric material transfer due to the low fluences and long pulse lengths. In situ superconducting thin films with T c(0) 's of 76 K could be deposited using the KrF laser at substrate temperatures of 5 degrees C to 20 degrees C below phases. Lower temperatures gave rise to a mixture of 2201 and glassy phases. An increase in the target to substrate distance led to a deterioration of the electrical and structural properties of the films due to a decrease in the energy for film formation. A maximum in T c(0) was observed at 450 mtorr as the deposition pressure was varied between 200 to 700 mtorr. Optimum oxygen incorporation could be achieved by cooling the films in high oxygen pressures and the best films were obtained with 700 torr cooling pressure. The oxygen deficiency of the hot pressed targets led to inferior properties compared to the conventionally sintered targets. The microwave surface resistance of the films measured at 35 GHz showed an onset at 80 K and dropped below that of copper at 30 K. The study of the laser ablation process in this system revealed the presence of a stoichiometric forward directed component and a diffuse evaporation component

  10. Upper critical magnetic field of superconducting films with magnetic impurities

    International Nuclear Information System (INIS)

    Lemberger, T.R.

    1978-01-01

    The upper critical magnetic field, H/sub c2/(T), of In-Mn and Pb-Mn alloy films was measured. H/sub c2/ was determined from the resistance of the films. The results were compared with the theory of Fulde and Maki. This theory assumes that the electron-phonon coupling is weak, and that the interaction between the impurity spins and the conduction electron spins is weak. The theory predicts that the pair-breaking effect of the magnetic impurities is temperature-independent, and that the pair-breaking effects of the magnetic impurities and the applied magnetic field are additive. Furthermore, it predicts explicitly the temperature dependence of H/sub c2/. The temperature dependence of H/sub c2/ for the In-Mn alloy films is well described by the Fulde-Maki theory, despite the moderately strong electron-phonon coupling and the strong interaction between the impurity spins and the conduction electron spins. The temperature dependence of H/sub c2/ for the Pb-Mn alloy films is not well described by the Fulde-Maki theory, probably due to the strong electron-phonon coupling in Pb. However, even without a quantitatively correct theory, one can conclude from the Pb-Mn data that the pair-breaking effect of the magnetic impurities is temperature independent, and that the pair-breaking effects of the magnetic impurities and the applied magnetic field are additive. For some of the Pb-Mn alloy films, there was a region of positive curvature in H/sub c2/(T) near the zero-field transition temperature. This positive curvature is not understood

  11. Superconductivity

    International Nuclear Information System (INIS)

    Anon.

    1988-01-01

    This book profiles the research activity of 42 companies in the superconductivity field, worldwide. It forms a unique and comprehensive directory to this emerging technology. For each research site, it details the various projects in progress, analyzes the level of activity, pinpoints applications and R and D areas, reviews strategies and provides complete contact information. It lists key individuals, offers international comparisons of government funding, reviews market forecasts and development timetables and features a bibliography of selected articles on the subject

  12. Superconductivity

    International Nuclear Information System (INIS)

    Buller, L.; Carrillo, F.; Dietert, R.; Kotziapashis, A.

    1989-01-01

    Superconductors are materials which combine the property of zero electric resistance with the capability to exclude any adjacent magnetic field. This leads to many large scale applications such as the much publicized levitating train, generation of magnetic fields in MHD electric generators, and special medical diagnostic equipment. On a smaller-scale, superconductive materials could replace existing resistive connectors and decrease signal delays by reducing the RLC time constants. Thus, a computer could operate at much higher speeds, and consequently at lower power levels which would reduce the need for heat removal and allow closer spacing of circuitry. Although technical advances and proposed applications are constantly being published, it should be recognized that superconductivity is a slowly developing technology. It has taken scientists almost eighty years to learn what they now know about this material and its function. The present paper provides an overview of the historical development of superconductivity and describes some of the potential applications for this new technology as it pertains to the electronics industry

  13. Thin Film Technology of High-Critical-Temperature Superconducting Electronics.

    Science.gov (United States)

    1985-12-11

    ANALISIS OF THIN-FILM SUPERCONDUCTORS J. Talvacchio, M. A. Janocko, J. R. Gavaler, and A...in the areas of substrate preparation, niobum nitride, nlobium-tin, and molybdenum-rhenium. AN INTEGRATED DEPOSITION AND ANALISI - FACILITT The four...mobility low (64). The voids are separating 1-3 nm clusters of dense deposit. At low deposition temperatures this microstructure will persist near

  14. Fermion analogy for layered superconducting films in parallel magnetic field

    International Nuclear Information System (INIS)

    Rodriguez, J.P.

    1997-01-01

    The equivalence between the Lawrence-Doniach model for films of extreme type-II layered superconductors and a generalization of the back-scattering model for spin-(1/2) electrons in one dimension is demonstrated. This fermion analogy is then exploited to obtain an anomalous H parallel -1 tail for the parallel equilibrium magnetization of the minimal double-layer case in the limit of high parallel magnetic fields H parallel for temperatures in the critical regime. (orig.)

  15. Anisotrophic currents and flux jumps in high-T-c superconducting films with self-organized arrays of planar defects

    DEFF Research Database (Denmark)

    Yurchenko, V.V.; Qviller, A.J.; Mozhaev, P.B.

    2010-01-01

    Regular arrays of planar defects with a period of a few nanometers can be introduced in superconducting YBa2Cu3O7-delta (YBCO) thin films by depositing them on vicinal (also called miscut or tilted) substrates. This results in the anisotropy of critical currents flowing in the plane of the film. ...

  16. Probing the local microwave properties of superconducting thin films by a scanning microwave near-field microscope

    CERN Document Server

    Wu, L Y; Wang, K L; Jiang, T; Kang, L; Yang, S Z; Wu, P H

    2002-01-01

    In this paper, we present our approach to probe the local microwave properties of superconducting thin films by using the microwave near-field scanning technique. We have employed a coaxial cavity together with a niobium tip as the probe and established a scanning sample stage cooled by liquid nitrogen to study thin film devices at low temperature in our scanning microwave near-field microscope. Nondestructive images have been obtained on the inhomogeneity of the YBaCuO superconducting thin films at microwave frequency. We believe that these results would be helpful in evaluating the microwave performance of the devices.

  17. Analysis of influence of buffer layers on microwave propagation through high-temperature superconducting thin films

    International Nuclear Information System (INIS)

    Ceremuga, J.; Barton, M.; Miranda, F.

    1994-01-01

    Methods of analysis of microwave propagation through superconducting thin films with buffer layers on dielectric substrates have been discussed. Expressions describing the transmission coefficient S 21 through the structure and the complex conductivity sigma of a superconductor in an analytical form have been derived. The derived equations are valid for microwave propagation in waveguides as well as in free space with relevant definition of impedances. Using the obtained solutions, the influences of buffer layers' parameters (thickness, relative permittivity and loss tangent) on the transmission coefficient has been investigated using MATLAB. Simulations have been performed for 10 GHz transmission through YBa 2 Cu 3 O 7 films on sapphire with SrTiO 3 and CeO 2 buffer layers and on silicon with CaF 2 and YSZ buffer layers. To illustrate the simulations, measurements of the transmission through YBCO film on sapphire with SrTiO 3 buffer layer have been performed. It has been shown that even lossy buffer layers have very little impact (smaller than 1% in magnitude and 0.3% in phase) on the transmission coefficient through superconducting thin films, providing their thickness is below 10 mu m. (author)

  18. Measurement of the magnetic penetration depth in p-doped superconducting diamond films

    Energy Technology Data Exchange (ETDEWEB)

    Fuchs, Lorenz; Brunner, Markus C.P.; Schneider, Ina; Kronfeldner, Klaus [University of Regensburg (Germany); Bousquet, Jessica; Bustarret, Etienne; Strunk, Christoph [Institut Neel, Grenoble (France)

    2016-07-01

    Boron-doped diamond becomes superconducting once a critical doping concentration of 4.5 x 10{sup 20} cm{sup -3} is reached. Mutual inductance measurements with a two-coil setup have been performed to determine the magnetic penetration depth λ(T), which is a measure for the superfluid stiffnes θ ∝ 1/λ{sup 2}(T). Two superconducting p-doped diamond films with thicknesses of 145 nm and 345 nm were investigated. At low temperatures these values agree reasonably with the values expected within BCS-theory using T{sub c}, carrier density and mean free path determined from electric transport measurements. Magnetic penetration depths of 3.7 μm for the thinner and 2.6 μm for the thicker film have been found. λ decreases and accordingly θ increases with increasing film thickness. On the other hand, the superfluid stiffness drops by a factor of 2 or even more at T{sub c}/2, i.e., much faster than expected from BCS-theory, but remains finite between T{sub c}/2 < T < T{sub c}. At present it is unclear, whether this behavior results from the proliferation of phase fluctuations already far below T{sub c} or from a spatial inhomogeneity of the films.

  19. Niobium thin film deposition studies on copper surfaces for superconducting radio frequency cavity applications

    Directory of Open Access Journals (Sweden)

    W. M. Roach

    2012-06-01

    Full Text Available Thin film coatings have the potential to increase both the thermal efficiency and accelerating gradient in superconducting radio frequency accelerator cavities. However, before this potential can be realized, systematic studies on structure-property correlations in these thin films need to be carried out since the reduced geometry, combined with specific growth parameters, can modify the physical properties of the materials when compared to their bulk form. Here, we present our systematic studies of Nb thin films deposited onto Cu surfaces to clarify possible reasons for the limited success that this process exhibited in previous attempts. We compare these films with Nb grown on other surfaces. In particular, we study the crystal structure and surface morphology and their effect on superconducting properties, such as critical temperature and lower critical field. We found that higher deposition temperature leads to a sharper critical temperature transition, but also to increased roughness indicating that there are competing mechanisms that must be considered for further optimization.

  20. Superconductivity in transparent zinc-doped In2O3 films having low carrier density

    Directory of Open Access Journals (Sweden)

    Kazumasa Makise, Nobuhito Kokubo, Satoshi Takada, Takashi Yamaguti, Syunsuke Ogura, Kazumasa Yamada, Bunjyu Shinozaki, Koki Yano, Kazuyoshi Inoue and Hiroaki Nakamura

    2008-01-01

    Full Text Available Thin polycrystalline zinc-doped indium oxide (In2O3–ZnO films were prepared by post-annealing amorphous films with various weight concentrations x of ZnO in the range 0≤x ≤0.06. We have studied the dependences of the resistivity ρ and Hall coefficient on temperature T and magnetic field H in the range 0.5≤T ≤300 K, H≤6 Tfor 350 nm films annealed in air. Films with 0≤x≤0.03 show the superconducting resistive transition. The transition temperature Tc is below 3.3 K and the carrier density n is about 1025–1026 m−3. The annealed In2O3–ZnO films were examined by transmission electron microscopy and x-ray diffraction analysis revealing that the crystallinity of the films depends on the annealing time. We studied the upper critical magnetic field Hc2 (T for the film with x = 0.01. From the slope of dHc2 /dT, we obtain the coherence length ξ (0 ≈ 10 nm at T = 0 K and a coefficient of electronic heat capacity that is small compared with those of other oxide materials.

  1. Bibliography of high-T/sub c/ superconducting films

    International Nuclear Information System (INIS)

    Talvacchio, J.

    1989-01-01

    This document represents an effort to make bibliographic information on high-T/sub c/ superconductor films available to those who cannot access the on-line database at the Westinghouse R and D Center. The database contains a growing list of references -- approaching 5000 -- each of which is identified by a set of two-letter keywords. The database is used the same way as as INSPEC's, but its fixed set of standard keywords enables the user to obtain a complete list of references on keyworded topics. Since a single keyword (or search term) such as ''sputtering'' creates a bibliography that is too long for practical use, the database is used most effectively by combining a series of keywords using Boolean algebra to identify a handful of relevant references. The structure of this document is intended to present the subset of papers concerning high-T/sub c/ films (725 papers) in a compact format as a substitute for on-line searches. Rather than listing separate bibliographies for each of the 185 keywords, a single list of all the references is contained in Section 6, and indices based on the keywords are contained in Sections 3--5. This report is a true bibliography and does not contain any informative text. 725 refs

  2. The effects of Fe2O3 nanoparticles on MgB2 superconducting thin films

    International Nuclear Information System (INIS)

    Koparan, E.T.; Sidorenko, A.; Yanmaz, E.

    2013-01-01

    Full text: Since the discovery of superconductivity in binary MgB 2 compounds, extensive studies have been carried out because of its excellent properties for technological applications, such as high transition temperature (T c = 39 K), high upper critical field (H c2 ), high critical current density (J c ). Thin films are important for fundamental research as well as technological applications of any functional materials. Technological applications primarily depend on critical current density. The strong field dependence of J c for MgB 2 necessitates an enhancement in flux pinning performance in order to improve values in high magnetic fields. An effective way to improve the flux pinning is to introduce flux pinning centers into MgB 2 through a dopant having size comparable to the coherence length of MgB 2 . In this study, MgB 2 film with a thickness of about 600 nm was deposited on the MgO (100) single crystal substrate using a 'two-step' synthesis technique. Firstly, deposition of boron thin film was carried out by rf magnetron sputtering on MgO substrates and followed by a post deposition annealing at 850 degrees Celsius in magnesium vapour. In order to investigate the effect of Fe 2 O 3 nanoparticles on the structural and magnetic properties of films, MgB 2 films were coated with different concentrations of Fe 2 O 3 nanoparticles by a spin coating process. The effects of different concentrations of ferromagnetic Fe 2 O 3 nanoparticles on superconducting properties of obtained films were carried out by using structural (XRD, SEM, AFM), electrical (R-T) and magnetization (M-H, M-T and AC Susceptibility) measurements. It was calculated that anisotropic coefficient was about γ = 1.2 and coherence length of 5 nm for the uncoated film. As a result of coherence length, the appropriate diameters of Fe 2 O 3 nanoparticles were found to be 10 nm, indicating that these nanoparticles served as the pinning centers. Based on the data obtained from this study, it can be

  3. The growth and characterisation of YBa2Cu3O7-δ superconducting thin films

    International Nuclear Information System (INIS)

    McCurry, M.P.

    1999-02-01

    The normal state properties of YBa 2 Cu 3 O 7-δ (YBCO) are not completely understood. It is known that the oxygen doping play a large part in determining these properties. The optical conductivity of a series of c-axis YBCO thin films was investigated in this thesis. The films were grown on (100) MgO substrates using a pulsed laser deposition (PLD) system and characterised using X-ray diffraction, atomic force microscopy and resistance-temperature measurements. The optimum parameters for c-axis YBCO thin film growth were determined by systematically varying the main deposition parameters. The best quality films had a transition temperature T c ∼ 88K, with a transition width ∼ 1-2K. Critical current densities of J c ∼ 10 7 Acm -2 were obtained. Substrate and target morphology affected the quality of the films. a-axis YBCO films were grown using a PrBa 2 Cu 3 O 7 (PBCO) film as a template for growth. The choice of target and substrate were again important, with a smooth substrate essential for the multi-layering. T c ∼ 83K and J c ∼ 10 6 Acm -2 were the best values obtained. These values compare with data published on the 'best' YBCO films deposited by PLD. A series of c-axis films was controllably under-doped using an ex-situ annealing process. The as-grown films were assumed to be optimally doped with δ ∼ 0.05. Doping levels in the 'metallic' region, 0.05 -2 mbar. Another tetragonal film was obtained by cooling it after deposition in a nitrogen atmosphere. Neither had a superconducting transition; the c-axes of both films were elongated. The films could be successfully re-doped with oxygen, with a subsequent return to optimal values of T c and c-axis lattice parameter. The dielectric function of optimally doped and under-doped c-axis YBCO films was determined using the attenuated total reflection (ATR) technique. This data was obtained at a fixed frequency of 2984 cm -1 , (0.366eV), at temperatures ranging from 300K to 80K. The data was analysed in

  4. High-temperature superconductors induced by ion implantation. Final report

    International Nuclear Information System (INIS)

    Greenwald, A.C.; Johnson, E.

    1988-08-01

    High dose oxygen ion implantation (10 to the 17th power ions per sq. cm.) at elevated temperatures (300 C) has been shown to adjust the critical temperature of gamma-Y-Ba-Cu-O and Bi-Ca-Sr-Cu-O materials. These results are in marked contrast to earlier work which showed complete destruction of superconducting properties for similar radiation doses, and marked reduction in superconducting properties at one-tenth this dose in the 1-2-3- compound only. Experiments also showed that the superconducting materials can be patterned into conducting and nonconducting areas without etching by ion implantation, allowing maintenance of planar geometries required for microcircuit fabrication. Experiments on deposition of thin films of high temperature superconductors for use with the ion implantation experiments showed that ion beam sputtering from a single target could achieve the correct stoichiometry. Variations of composition with ion beam energy and angle of sputtered ions were studied

  5. Compositional analysis of YBaCuO superconducting films with ion beam analysis techniques

    International Nuclear Information System (INIS)

    Jones, S.; Timmers, H.; Ophel, T.R.; Elliman, R.G.

    1999-01-01

    High-T c YBa x Cu y O 7-δ superconducting films are being developed for applications such as superconducting quantum interference devices. The carrier concentration, critical current density J c and critical temperature T c of these films depend sensitively on the oxygen content . Stoichiometry, uniformity with depth, homogeneity across the sample and film thickness are also important quantities for their characterisation. It has been shown, for example, that the stoichiometry of the metallic elements affects the growth characteristics and surface morphology of the films. With the deposit ion techniques used, reproducibility of film properties is difficult. The characterisation of YBa x Cu y O 7-δ films with ion beam analysis techniques is complex. Whereas the three metallic elements can be detected with helium beams and Rutherford Backscattering (RBS), the oxygen signal is generally obscured by that from substrate elements. It can be better detected using resonant backscattering with 3.04MeV 4 He ions or nuclear reaction analysis. Elastic Recoil Detection (ERD) with high-energetic (1MeV/amu), heavy beams (Z > 120), enables all elements to be detected and separated in a single experiment. It is well established that ion bombardment induces vacancies in the oxygen sub-lattice, driving the material to change from crystalline to amorphous, the latter phase having a reduced oxygen content. In previous heavy ion ERD measurements of YBa x Cu yO z films with 200MeV 127 I beams, the opaque films became transparent in the beam spot area, indicative of the amorphous phase. The accuracy of the oxygen measurement is therefore questionable. Indeed, using Raman spectroscopy, distortions of the crystalline structure above a fluence of 5 x 10 11 ion/cm 2 and for higher doses some signatures of a reduction in oxygen content have been observed for such beams. It appears therefore that a correct determination of the oxygen content requires either a drastic reduction in fluence or a

  6. Electron scattering rate in epitaxial YBa2Cu3O7 superconducting films

    Science.gov (United States)

    Flik, M. I.; Zhang, Z. M.; Goodson, K. E.; Siegal, M. P.; Phillips, Julia M.

    1992-09-01

    This work determines the electron scattering rate in the a-b plane of epitaxial YBa2Cu3O7 films using two techniques. Infrared spectroscopy yields the scattering rate at temperatures of 10, 78, and 300 K by fitting reflectance data using thin-film optics and a model for the free-carrier conductivity. The scattering rate is also obtained using kinetic theory and an extrapolation of normal-state electrical resistivity data to superconducting temperatures based on the Bloch theory for the phonon-limited electrical resistivity of metals. The scattering rates determined using both techniques are in agreement and show that the electron mean free path in the a-b plane of YBa2Cu3O7 superconducting films is three to four times the coherence length. Hence YBa2Cu3O7 is pure but not in the extreme pure limit. An average defect interaction range of 4 nm is obtained using the defect density resulting from flux-pinning considerations.

  7. Niobium Nitride Thin Films and Multilayers for Superconducting Radio Frequency Cavities

    Science.gov (United States)

    Roach, William; Beringer, Douglas; Li, Zhaozhu; Clavero, Cesar; Lukaszew, Rosa

    2013-03-01

    Niobium nitride in thin film form has been considered for a number of applications including multi-layered coatings onto superconducting radio frequency cavities which have been proposed to overcome the fundamental accelerating gradient limit of ~50 MV/m in niobium based accelerators. In order to fulfill the latter application, the selected superconductor's thermodynamic critical field, HC, must be larger than that of niobium and separated from the Nb surface by an insulating layer in order to shield the Nb cavity from field penetration and thus allow higher field gradients. Thus, for the successful implementation of such multilayered stack it is important to consider not just the materials inherent properties but also how these properties may be affected in thin film geometry and also by the specific deposition techniques used. Here, we show the results of our correlated study of structure and superconducting properties in niobium nitride thin films and discuss the shielding exhibited in NbN/MgO/Nb multilayer samples beyond the lower critical field of Nb for the first time. This work was funded by the Defense Threat Reduction Agency (HDTRA-10-1-0072).

  8. Magnetic force acting on a magnetic dipole over a superconducting thin film

    International Nuclear Information System (INIS)

    Wei, J.C.; Chen, J.L.; Horng, L.; Yang, T.J.

    1996-01-01

    The magnetostatic interaction energy and corresponding magnetic force acting on a magnetic point dipole placed above a type-II thin superconducting film in the mixed state with a single vortex are calculated using electromagnetics coupled with the London theory of superconductivity. If a vortex is trapped by a circular defect of radius b 1, where a is the separation between the dipole and the thin film, the only difference between two results is in the cutoff length, i.e., in the case of a circular defect the only difference in the critical position calculation is the cutoff at radius b rather than at coherence length ξ. The pinning force of a single vortex by a circular defect is also calculated. Further, we investigate the conditions of the vortex creation for various cases (including the first, second, and third vortices) for a free of pinning center in the examining region. It is found that the creation of a new single vortex in the thin film causes an abrupt change in vertical levitation force: the force changed discontinuously. copyright 1996 The American Physical Society

  9. Reactive diffusion and superconductivity of Nb3Al multilayer films

    International Nuclear Information System (INIS)

    Vandenberg, J.M.; Hong, M.; Hamm, R.A.; Gurvitch, M.

    1985-01-01

    Thin films of A15 Nb 3 Al have been prepared by reactive diffusion of sputter-deposited Nb/Al multilayers. The diffusion reactions were studied by in situ annealing x-ray diffraction in the temperature range 50--950 0 C. Initially the Nb and Al sublayers react to form the phase NbAl 3 . This interface reaction prevents the formation of the sigma-phase Nb 2 Al, frequently found as a second phase in A15 Nb 3 Al materials; NbAl 3 reacts with the remaining Nb to form the A15 phase. The highest T/sub c/, 16.2 K measured resistively and 15.2 K inductively, was found in a Nb/Al multilayer with an A15 cell parameter a 0 = 5.195 A which corresponds to approx.20 at. % Al. From a comparison with previous investigations of the T/sub c/ dependence on Al concentration and A15 cell parameter, it is concluded that a small amount of the A15 phase has a higher composition of 22--23 at. % Al

  10. Superconductivity in Na{sub 1-x}CoO{sub 2}.yH{sub 2}O thin films

    Energy Technology Data Exchange (ETDEWEB)

    Hildebrandt, Sandra; Komissinkiy, Philipp; Alff, Lambert [Institute for Materials Science, TU Darmstadt (Germany); Fritsch, Ingo; Habermeier, Hanns-Ulrich [Max-Planck-Institute for Solid State Research, Stuttgart (Germany); Lemmens, Peter [Institute for Condensed Matter Physics, TU Braunschweig (Germany)

    2010-07-01

    Sodium cobaltate (Na{sub 1-x}CoO{sub 2}) is a novel material with thermoelectric behavior, charge and spin ordered states dependent on the sodium content in the composition. A superconducting phase was found in water intercalated sodium cobaltate (Na{sub 1-x}CoO{sub 2}.yH{sub 2}O) with x=0.65-0.7 and y=0.9-1.3. The pairing state is still under debate, but there are some indications for a spin-triplet or p-wave superconducting pairing state. First films of Na{sub 1-x}CoO{sub 2}.yH{sub 2}O with a superconducting transition temperature near 5 K have been successfully grown. Here we report on thin films of Na{sub 1-x}CoO{sub 2} grown by pulsed laser deposition technique. The deposition parameters, sodium deintercalation and water intercalation conditions are tuned in order to obtain the superconducting phase. The instability of this phase might be an indication for triplet superconductivity, which is known to be affected strongly by impurities and defects.This observation is in agreement with the fact that so far also no superconducting thin films of the most famous triplet superconductor Sr{sub 2}RuO{sub 4} have been reported.

  11. The use of cubic Nd-Ba-Cu-O seeds to create θ[100], 900-θ[100], and θ[001] tilt Y-Ba-Cu-O grain boundaries

    International Nuclear Information System (INIS)

    Field, M. B.

    1998-01-01

    Using seeding techniques to control the orientation of grains, we have been able to create a wide variety of YBa 2 Cu 3 O 6+x , grain boundaries. In addition to five domain samples with 90 degree[100] twist and tilt grain boundaries, we have now developed a method to produce grain boundaries in the same sample that have the misorientations θ[001] tilt, θ[100] tilt, and 90 degree ∼ θ[100], where the disorientation angle θ is fully controllable. We will demonstrate how these boundaries can be synthesized, give experimental evidence via polarized light microscopy and electron backscatter patterns (EBSP) that the intended grain boundaries were indeed formed, and discuss the importance of these boundaries in future grain boundary studies

  12. Oxygen potentials and phase equilibria of the quaternary Y-Ba-Cu-O system in the region involving the YBa2Cu3O7-x phase

    International Nuclear Information System (INIS)

    Fitzner, K.; Musbah, O.; Hsieh Kerchang; Zhang Minxian; Chang, Y.A.

    1993-01-01

    The equilibrium oxygen potentials of four-phase equilibria (counting only the condensed phases) in the CuO-Cu 2 O-BaCuO 2 -Y 2 BaCuO 5 (211)-YBa 2 Cu 3 O 7-x (123) phase region were determined using the following solid-oxide electrolyte e.m.f. cell: Pt10Rh, air (psub(O 2 )=0.21 atm) vertical stroke ZrO 2 +Y 2 O 3 vertical stroke mixtures of oxides, Pt. The oxide mixtures whose oxygen potentials were measured were CuO-Cu 2 O-211-123, CuO-Cu 2 O-BaCuO 2 -123, Cu 2 O-BaCuO 2 -211-123 and CuO-BaCuO 2 -211-123. The phase in some of the mixtures were identified by X-ray diffraction. These data were analyzed and are presented using stability diagrams, i.e., oxygen potential as a function of the reciprocal of the temperature. Extrapolation of these data for the four four-phase equilibra to high temperatures yields a metastable five-phase equilibrium, i.e., 123=CuO+Cu 2 O+BaCuO 2 +211, at ∼1243 K (970 ) and log psub(O 2 ) ∼ -1.21 (psub(O 2 )∼0.062 atm). (orig.)

  13. Study of physical and chemical properties of Y-Ba-Cu-O ceramic specimens treated with temperature-electric domains for the texture formation

    International Nuclear Information System (INIS)

    Khirnyj, V.F.; Seminozhenko, V.P.; Zagoskin, V.T.

    1995-01-01

    Study of temperature-electric domain (TED) behaviour is conducted and physico-chemical properties of specimens treated by moving TED are investigated. According to the data obtained, texture does not appear during such a treatment. To reduce v of TED the specimen is placed to a longitudinal magnetic field. TED stop at H=0.4 T and V=3.2 V is observed when the direction of the north magnetic pole coincides with the point of the positive electrode junction. Domain movement rate, at which texture occurrence is possible, is achieved by means of magnetic field intensity H variation. 10 refs.; 3 figs.; 1 tab

  14. Compatibilities of YBa2Cu3O(9-delta) type phase in quintenary systems Y-Ba-Cu-O-X (impurity)

    Science.gov (United States)

    Karen, P.; Braaten, O.; Fjellvag, H.; Kjekshus, A.

    1991-01-01

    Isothermal phase diagrams at various oxygen pressures were studied by powder diffraction and chemical analytical methods. The components, Y, Ba, Cu, and O (specifically O2, O2-, and O2 sup 2-) are treated, together with C (specifically CO2 and CO2 sup 2-), alkaline metals, Mg, alkaline earths, Sc, 3-d and 4-f elements. Effects of the substitutions at the structural sites of YBa2Cu3O(9-delta) on T sub c are discussed with respect to changes in crystallochemical characteristics of the substituted phase and to the nature of the substituents.

  15. Compatibilities of YBa2Cu3O(9-delta)-type phase in quintenary systems Y-Ba-Cu-O-X (impurity)

    International Nuclear Information System (INIS)

    Karen, P.; Braaten, O.; Fjellvag, H.; Kjekshus, A.

    1991-01-01

    Isothermal phase diagrams at various oxygen pressures were studied by powder diffraction and chemical analytical methods. The components, Y, Ba, Cu, and O (specifically O2, O2-, and O2 sup 2-) are treated, together with C (specifically CO2 and CO2 sup 2-), alkaline metals, Mg, alkaline earths, Sc, 3-d and 4-f elements. Effects of the substitutions at the structural sites of YBa2Cu3O(9-delta) on T sub c are discussed with respect to changes in crystallochemical characteristics of the substituted phase and to the nature of the substituents

  16. The influence of the addition of depleted uranium on particle pushing in melt-processed, bulk Y-Ba-Cu-O

    International Nuclear Information System (INIS)

    Diko, P; Zmorayova, K; Babu, N Hari; Krabbes, G; Cardwell, D A

    2004-01-01

    The microstructure of single-grain, melt-processed (MP) YBa 2 Cu 3 O 7 /Y 2 BaCuO 5 (Y-123/Y-211) samples (YBCO) containing varying amounts of depleted uranium (DU) and Pt has been studied. Only partial refinement of the Y-211 particle size was observed in Pt-free samples, which generally contained both small and large Y-211 particles. Small Y-211 particles in these samples are pushed extensively in the c-growth sector (c-GS) and all Y-211 particles (small and large) coarsen with the distance from the seed and with increasing DU concentration. Samples fabricated with Pt contained only very fine Y-211 particles, which were generally pushed strongly in the c-GS. In this case the size of the Y-211 particles did not vary significantly with distance from the seed. U- and U/Pt-containing sub-micron sized particles present in the melt-processed YBCO microstructure were not pushed during solidification, although their arrangement within the structure of the sample was influenced clearly by the growth process. The so-called cyclic growth was observed in the c-GS at the highest DU concentration (0.8 wt%). In these samples, this growth pattern is associated with the formation of a liquid phase rich in U and Y at the growth front. The cyclic growth mechanism was modified by the addition of Pt. Crystals of Y 2 Ba 4 UCuO x with Ba 3 YUO x phase inclusions were observed to be present in the U/Y-rich melt

  17. Effect of different uranium compounds on the properties of U-Pt-Y-Ba-O double-perovskite pinning centres in textured Y-Ba-Cu-O superconductor

    Energy Technology Data Exchange (ETDEWEB)

    Sawh, Ravi-Persad; Weinstein, Roy; Parks, Drew; Gandini, Alberto [Beam Particle Dynamics Laboratories, University of Houston, Houston, TX 77204-5005 (United States); Department of Physics, University of Houston, Houston, TX 77204-5005 (United States); Texas Center for Superconductivity and Advanced Materials, University of Houston, Houston, TX 77204-5005 (United States)

    2005-02-01

    An experiment was performed to test the effect of different uranium compounds on the properties of chemical pinning centres. UO{sub 2}, UO{sub 3}, and UO{sub 4}{center_dot}2H{sub 2}O wereadmixed to Y 123+Pt, and textured. Tests of J{sub c} via measurements of trapped field (B{sub trap}) indicate a clear dependence of B{sub trap} on the U compound admixed to create the pinning centres. In all three cases there is a monotonic increase in B{sub trap} as the mass (M{sub U}) of U is increased. However, the magnitude of the increase in B{sub trap} depends on the admixed U compound. The highest increase in B{sub trap} is measured in samples doped with UO{sub 4}{center_dot}2H{sub 2}O, and the lowest is obtained in samples doped with UO{sub 2}. Microstructure studies indicate that the composition of the U-rich pinning deposits is the same in all three cases, i.e. all are the previously identified (U{sub 0.6}Pt{sub 0.4})Y Ba{sub 2}O{sub 6} compound. The primary difference among the three types of samples is that the size of the U-Pt-Y-Ba-O pinning deposits depends on the admixed U compound. While all are in the nanometre domain, the diameter of these deposits was markedly larger in UO{sub 2} doped samples than in UO{sub 3} doped samples, and smallest in UO{sub 4}{center_dot}2H{sub 2}O doped samples. Because some form of poisoning limits the amount of U that can be added to create pinning centres, to M{sub U} {approx}1 wt%, smaller deposits result in a greater number of pinning centres. We conclude that UO{sub 4}{center_dot}2H{sub 2}O is more effective than either UO{sub 3} or UO{sub 2} in the formation of U-Pt-Y-Ba-O pinning centres because of diminished pinning centre size, and consequent increase in pinning centre density.

  18. Equilibrium vortex structures of type-II/1 superconducting films with washboard pinning landscapes

    Science.gov (United States)

    Wei, C. A.; Xu, X. B.; Xu, X. N.; Wang, Z. H.; Gu, M.

    2018-05-01

    We numerically study the equilibrium vortex structures of type-II/1 superconducting films with a periodic quasi-one-dimensional corrugated substrate. We show as a function of substrate period and pinning strength that, the vortex system displays a variety of vortex phases including arrays consisted of vortex clumps with different morphologies, ordered vortex stripes parallel and perpendicular to pinning troughs, and ordered one-dimensional vortex chains. Our simulations are helpful in understanding the structural modulations for extensive systems with both competing interactions and competing periodicities.

  19. Energy gap and surface structure of superconducting diamond films probed by scanning tunneling microscopy

    International Nuclear Information System (INIS)

    Nishizaki, Terukazu; Takano, Yoshihiko; Nagao, Masanori; Takenouchi, Tomohiro; Kawarada, Hiroshi; Kobayashi, Norio

    2007-01-01

    We have performed scanning tunneling microscopy/spectroscopy (STM/STS) experiments on (1 1 1)-oriented epitaxial films of heavily boron-doped diamond at T = 0.47 K. The STM topography shows two kinds of atomic structures: a hydrogenated 1 x 1 structure, C(1 1 1)1 x 1:H, and an amorphous structure. On the C(1 1 1)1 x 1:H region, the tunneling spectra show superconducting property with the energy gap Δ = 0.83 meV. The obtained gap ratio 2Δ/k B T c = 3.57 is consistent with the weak-coupling BCS theory

  20. Commensurate vortex configurations in thin superconducting films nanostructured by square lattice of magnetic dots

    Energy Technology Data Exchange (ETDEWEB)

    Milosevic, M.V.; Peeters, F.M

    2004-05-01

    Within the phenomenological Ginzburg-Landau (GL) theory, we investigate the vortex structure of a thin superconducting film (SC) with a regular matrix of ferromagnetic dots (FD) deposited on top of it. The vortex pinning properties of such a magnetic lattice are studied, and the field polarity dependent votex pinning is observed. The exact vortex configuration depends on the size of the magnetic dots, their polarity, periodicity of the FD-rooster and the properties of the SC expressed through the effective Ginzburg-Landau parameter {kappa}*.

  1. Commensurate vortex configurations in thin superconducting films nanostructured by square lattice of magnetic dots

    International Nuclear Information System (INIS)

    Milosevic, M.V.; Peeters, F.M.

    2004-01-01

    Within the phenomenological Ginzburg-Landau (GL) theory, we investigate the vortex structure of a thin superconducting film (SC) with a regular matrix of ferromagnetic dots (FD) deposited on top of it. The vortex pinning properties of such a magnetic lattice are studied, and the field polarity dependent votex pinning is observed. The exact vortex configuration depends on the size of the magnetic dots, their polarity, periodicity of the FD-rooster and the properties of the SC expressed through the effective Ginzburg-Landau parameter κ*

  2. Critical region of a type II superconducting film near Hsub(c2): rational approximants

    International Nuclear Information System (INIS)

    Ruggeri, G.J.

    1979-01-01

    The high-temperature perturbative expansions for the thermal quantities of a type II superconducting film are extrapolated to the critical region near Hsub(c2) by means of new rational approximants of the Pade type. The new approximants are forced to reproduce the leading correction to the flux lattice contribution on the low-temperature side of the transition. Compared to those previously considered in the literature: (i) the mutual consistency of the approximants is improved; and (ii) they are nearer to the exact solution of the zero-dimensional Landau-Ginsburg model. (author)

  3. Growth of epitaxial Ba2YCu3O(7-delta) thin films and control of their superconducting properties

    International Nuclear Information System (INIS)

    Siegal, M.P.; Phillips, J.M.

    1992-01-01

    The relationship is experimentally defined between the superconducting behavior of Ba2YCu3O(7-delta) (BYCO) films and their structural characteristics. The BYCO films are grown on LaAlO3 100-plane by coevaporating BaF2, Y, and Cu followed by ex situ annealing, and the crystalline quality is tested by Rutherford backscattering ion channeling. SEM is employed to study film morphology, and several techniques are used to measure the transition temperature (Tc), critical current density (Jc), and the penetration length. It is found that point defects and dislocations decrease as the high-temperature stage (Ta) increases; crevices, pinholes, and microcracks are also noted which are related to specific values of Tc, Ta, and penetration length. The results of the present experiments indicate that the material properties of superconducting materials should be examined closely to distinguish between pure superconducting behavior and characteristics related to material structure. 21 refs

  4. Epitaxial YBa2Cu3O7 films on rolled-textured metals for high temperature superconducting applications

    International Nuclear Information System (INIS)

    Norton, D.P.; Park, C.; Prouteau, C.

    1998-04-01

    The epitaxial growth of high temperature superconducting (HTS) films on rolled-textured metal represents a viable approach for long-length superconducting tapes. Epitaxial, 0.5 microm thick YBa 2 Cu 3 O 7 (YBCO) films with critical current densities, J c , greater than 1 MA/cm 2 have been realized on rolled-textured (001) Ni tapes with yttria-stabilized zirconia (YSZ)/CeO 2 oxide buffer layers. This paper describes the synthesis using pulsed-laser deposition (PLD) of epitaxial oxide buffer layers on biaxially-textured metal that comprise the so-called rolling-assisted biaxially-textured substrates (RABiTs trademark). The properties of the buffer and YBa 2 Cu 3 O 7 films on rolled-textured Ni are discussed, with emphasis given to the crystallographic and microstructural properties that determine the superconducting properties of these multilayer structures

  5. Effects of argon implantation and vacuum annealing of the superconducting properties of single-crystal niobium films

    International Nuclear Information System (INIS)

    Zakirov, R.M.; Kuznetsov, V.P.; Shermergor, T.D.

    1980-01-01

    Characteristics of superconducting transition (Tsub(K), Hsub(perpendicular)) of monocrystalline niobium films on sapphire, irradiated by 35 keV Ar ions within 0.62x10 15 -5.6x10 16 ion/cm 2 dose range, are investigated. Introduction of argon atoms results in Tsub(K) decrease of films and rhosub(n), Hsub(perpendicular 0) and dHsub(perpendicular)/dT increase due to reduction of free path length of electrons. Shown is an essential difference in the behaviour of superconducting parameters of irradiated monocrystalline niobium films and films with niobium, dassol ved in the niobium lattice. Introduction of oxygen has been carried out by annealing of films in vacuum after their heating in the air

  6. Superconducting thin films of YBa2Cu3O7-x

    International Nuclear Information System (INIS)

    Hudner, J.

    1993-01-01

    Thin films of the high temperature superconductor YBa 2 Cu 3 O 7-x (YBCO) are of significance in fundamental studies of oxide superconductors and for prospected electronic applications based on superconductors operating at liquid nitrogen temperatures (T= 77 K). Synthesis of YBCO thin films is complex and a large part of this thesis has been devoted to the elaboration of various techniques in forming YBCO thin films. A general observation was that synthesis of YBCO films exhibiting high zero-resistivity temperatures temperatures (T c ) ≥ 88 K and elevated critical current densities (J c ) ≥ 10 6 A/cm 2 at 77 K was possible under widely different conditions of film growth. For the BaF 2 -based method, various substrate materials were investigated. Among perovskite related substrates with low losses in the high frequency regime, LaA10 3 was found to yield YBCO films exhibiting the highest quality electrical properties. A study of YBCO film interaction with sapphire substrates was performed. It was suggested that the YBCO film on sapphire consists of weakly coupled superconducting grains. Compositional effects of Y, BA and Cu for MOCVD-YBCO films were examined with respect to morphology, structure, resistivity, as susceptibility and J c (T). High T c :s and J c :s were observed for an anomalous large compositional range of Cu in off-compositional YBCO films. This was shown to be related to the formation of Cu-rich precipitates embedded within a c-Axis oriented stoichiometric YBCO film matrix. Thermal critical current behavior at zero field in thin films of YBCO fabricated by various methods has been studied by three techniques: transport measurements on patterned microbridges, dc magnetization hysteresis loops using the Bean model and non-linear ac susceptibility analysis. Absolute critical current values obtained form the two former techniques when measured on the same YBCO film were observed to differ about a factor of two. The feasibility of non-linear ac

  7. Characterization of 3-dimensional superconductive thin film components for gravitational experiments in space

    Energy Technology Data Exchange (ETDEWEB)

    Hechler, S.; Nawrodt, R.; Nietzsche, S.; Vodel, W.; Seidel, P. [Friedrich-Schiller-Univ. Jena (Germany). Inst. fuer Festkoerperphysik; Dittus, H. [ZARM, Univ. Bremen (Germany); Loeffler, F. [Physikalisch-Technische Bundesanstalt, Braunschweig (Germany)

    2007-07-01

    Superconducting quantum interference devices (SQUIDs) are used for high precise gravitational experiments. One of the most impressive experiments is the satellite test of the equivalence principle (STEP) of NASA/ESA. The STEP mission aims to prove a possible violation of Einstein's equivalence principle at an extreme level of accuracy of 1 part in 10{sup 18} in space. In this contribution we present an automatically working measurement equipment to characterize 3-dimensional superconducting thin film components like i.e. pick-up coils and test masses for STEP. The characterization is done by measurements of the transition temperature between the normal and the superconducting state using a special built anti-cryostat. Above all the setup was designed for use in normal LHe transport Dewars. The sample chamber has a volume of 150 cm{sup 3} and can be fully temperature controlled over a range from 4.2 K to 300 K with a resolution of better then 100 mK. (orig.)

  8. Application of a phenomenological model for the surface impedance in high temperature superconducting films

    International Nuclear Information System (INIS)

    Mosquera, A.S.; Landinez Tellez, D.A.; Roa-Rojas, J.

    2007-01-01

    We report the application of a phenomenological model for the microwave surface impedance in high temperature superconducting films. This model is based on the modified two-fluid model, in which the real and imaginary parts of the surface impedance use the modelling parameter γ. This is responsible for the superconducting and normal charge carrier density and is used for the description of the temperature dependence of the London penetration depth λ L (T) including λ L (0). The relaxation time model also uses the γ parameter in combination with the residual resistance parameter α. The parameter δ 1 1 , γ, α, and δ 2 . The parameter δ 2 n (T) is a result of the competition between the increase of the relaxation time and the decrease of the normal charge-carrier density. We applied this model to analyze experimental results of MgB 2 , YBa 2 Cu 3 O 7-δ and GdBa 2 Cu 3 O 7-δ superconducting material. (copyright 2007 WILEY-VCH Verlag GmbH and Co. KGaA, Weinheim) (orig.)

  9. Angular dependence of the irreversible magnetization of YBa2Cu3O7 superconducting thin films

    International Nuclear Information System (INIS)

    Thrane, B.P.; Schlenker, C.; Dumas, J.; Buder, R.

    1996-01-01

    YBa 2 Cu 3 O 7 superconducting thin films have been studied by magnetization measurements in oblique fields up to 0.8 T both at low temperature and at temperatures close to T c . Both components of magnetization parallel and perpendicular to the applied field could be measured with two pairs of crossed detection coils. In all cases the magnetization is found to be perpendicular to the film plane. This is due to the self-field effects related to the thin-film geometry which force the critical currents to circulate along the film plane. At low temperature the properties are found to depend only on the component of the applied magnetic field perpendicular to this plane, as expected in the situation where demagnetizing field effects are dominant. However, at temperatures close to T c the critical currents and therefore the pinning are found to increase when the applied field approaches the film plane. This is attributed to the effect of intrinsic pinning which may be related to the kink structure of the vortices in oblique fields. copyright 1996 The American Physical Society

  10. Construction of sputtering system and preparation of high temperature superconducting thin films

    International Nuclear Information System (INIS)

    Kaynak, E.

    2000-01-01

    The preparation of high T c superconducting thin film is important both for the understanding of fundamental behaviours of these materials and for the investigations on the usefulness of technological applications. High quality thin films can be prepared by various kinds of techniques being used today. Among these, sputtering is the most preferred one. The primary aim of this work is the construction of a r. f. and c. magnetron sputtering system. For this goal, a magnetron sputtering system was designed and constructed having powers up to 500W (r.f.) and 1KW (d.c.) that enables to deposit thin films of various kinds of materials: metals, ceramics and magnetic materials. The temperature dependence of the electrical resistance of the films was investigated by using four-point probe method. The zero resistance and the transition with of the films were measured as 80-85 K, and 2-9 K, respectively. The A.C. susceptibility experiments were done by utilising the system that was designed and constructed. The applied field dependence of the real and imaginary components of the susceptibility that were measured between the 77-120 K temperature interval and at a fixed frequency was investigated

  11. A low energy muon spin rotation and point contact tunneling study of niobium films prepared for superconducting cavities

    Science.gov (United States)

    Junginger, Tobias; Calatroni, S.; Sublet, A.; Terenziani, G.; Prokscha, T.; Salman, Z.; Suter, A.; Proslier, T.; Zasadzinski, J.

    2017-12-01

    Point contact tunneling and low energy muon spin rotation are used to probe, on the same samples, the surface superconducting properties of micrometer thick niobium films deposited onto copper substrates using different sputtering techniques: diode, dc magnetron and HIPIMS. The combined results are compared to radio-frequency tests performances of RF cavities made with the same processes. Degraded surface superconducting properties are found to correlate to lower quality factors and stronger Q-slope. In addition, both techniques find evidence for surface paramagnetism on all samples and particularly on Nb films prepared by HIPIMS.

  12. Imaging of current distributions in superconducting thin film structures; Abbildung von Stromverteilungen in supraleitenden Duennfilmstrukturen

    Energy Technology Data Exchange (ETDEWEB)

    Doenitz, D.

    2006-10-31

    Local analysis plays an important role in many fields of scientific research. However, imaging methods are not very common in the investigation of superconductors. For more than 20 years, Low Temperature Scanning Electron Microscopy (LTSEM) has been successfully used at the University of Tuebingen for studying of condensed matter phenomena, especially of superconductivity. In this thesis LTSEM was used for imaging current distributions in different superconducting thin film structures: - Imaging of current distributions in Josephson junctions with ferromagnetic interlayer, also known as SIFS junctions, showed inhomogeneous current transport over the junctions which directly led to an improvement in the fabrication process. An investigation of improved samples showed a very homogeneous current distribution without any trace of magnetic domains. Either such domains were not present or too small for imaging with the LTSEM. - An investigation of Nb/YBCO zigzag Josephson junctions yielded important information on signal formation in the LTSEM both for Josephson junctions in the short and in the long limit. Using a reference junction our signal formation model could be verified, thus confirming earlier results on short zigzag junctions. These results, which could be reproduced in this work, support the theory of d-wave symmetry in the superconducting order parameter of YBCO. Furthermore, investigations of the quasiparticle tunneling in the zigzag junctions showed the existence of Andreev bound states, which is another indication of the d-wave symmetry in YBCO. - The LTSEM study of Hot Electron Bolometers (HEB) allowed the first successful imaging of a stable 'Hot Spot', a self-heating region in HEB structures. Moreover, the electron beam was used to induce an - otherwise unstable - hot spot. Both investigations yielded information on the homogeneity of the samples. - An entirely new method of imaging the current distribution in superconducting interference

  13. Superconducting Bi-Sr-Ca-Cu-O thin films from metallo-organic complexes

    International Nuclear Information System (INIS)

    Gruber, H.; Krautz, E.; Fritzer, H.P.; Popitsch, A.

    1991-01-01

    Thin films in the Bi-Sr-Ca-Cu-O system are produced by decomposition of organic precursor compounds containing different metallo-organic complexes. The superconducting phase identified is Bi 2 Sr 2 CaCu 2 O 8+x on (100)-MgO single crystal substrates, polycrystalline Au- and Ag-ribbons and Bi 2 Sr 2 Ca 2 Cu 3 O 10+x on Ag-ribbons. For the 2212-phase a zero resistance temperature of 79 K is found. The 2223-samples on Ag-ribbons show a broad transition at 110 K with a zero resistance at 85 K. SEM and EDX are used for the detection of the microstructure and composition of the prepared films. (orig.)

  14. Gold nanocrystals in high-temperature superconducting films: Creation of pinning patterns of choice

    Energy Technology Data Exchange (ETDEWEB)

    Katzer, Christian; Michalowski, Peter; Schmidl, Frank; Seidel, Paul [Institut fuer Festkoerperphysik, Friedrich-Schiller-Universitaet Jena, 07743 Jena (Germany); Stahl, Claudia; Treiber, Sebastian; Schuetz, Gisela [Max-Planck-Institut fuer Intelligente Systeme, Heisenbergstrasse 3, 70569 Stuttgart (Germany); Christiani, Georg [Max-Planck-Institut fuer Festkoerperforschung, Heisenbergstrasse 1, 70569 Stuttgart (Germany); Albrecht, Joachim [Hochschule Aalen, Beethovenstrasse 1, 73430 Aalen (Germany)

    2013-07-01

    Many superconducting thin film devices require a spatially resolved current carrying capability due to different boundary conditions. On the one hand, the critical current density and the pinning of flux lines respectively should be high to reduce flux noise in the antenna regions of gradiometers; on the other hand, the critical current density of the Josephson junctions itself must not be too high to ensure a proper functionality. We report that adding gold nanoparticles during the preparation process of epitaxial YBa{sub 2}Cu{sub 3}O{sub 7-δ} thin films offers the possibility of creating spatially varying flux pinning properties, thus allowing to locally enhance the critical current density up to a factor of two. Magneto-optical investigations as well as transport measurements will be presented, indicating that an Au particle induced modification of the YBCO pinning properties allows the engineering of the critical current landscape on the sub-micrometre scale.

  15. Magnetofingerprints of superconducting films: Vortex dynamics and mesoscopic-scale disorder

    International Nuclear Information System (INIS)

    Nowak, E.R.; Israeloff, N.E.; Goldman, A.M.

    1994-01-01

    The variations of voltage and voltage noise with magnetic field in c-axis-oriented DyBa 2 Cu 3 O 7-δ thin films exhibit reproducible, microstructure-dependent ''magnetofingerprints'' (MF's). The MF's can be scrambled with the reversal of the direction of the Lorentz force on field-induced vortices. Analysis of the noise suggests a strong dependence of the local free-energy landscape on vortex density similar to global frustration effects found in periodic superconducting networks. Above fields which roughly match vortex separation with mesoscopic-scale disorder in the films the noise and the fine structure of the MF's are suppressed, suggesting a crossover to a more weakly pinned vortex-liquid regime

  16. Specific heat measurement set-up for quench condensed thin superconducting films.

    Science.gov (United States)

    Poran, Shachaf; Molina-Ruiz, Manel; Gérardin, Anne; Frydman, Aviad; Bourgeois, Olivier

    2014-05-01

    We present a set-up designed for the measurement of specific heat of very thin or ultra-thin quench condensed superconducting films. In an ultra-high vacuum chamber, materials of interest can be thermally evaporated directly on a silicon membrane regulated in temperature from 1.4 K to 10 K. On this membrane, a heater and a thermometer are lithographically fabricated, allowing the measurement of heat capacity of the quench condensed layers. This apparatus permits the simultaneous thermal and electrical characterization of successively deposited layers in situ without exposing the deposited materials to room temperature or atmospheric conditions, both being irreversibly harmful to the samples. This system can be used to study specific heat signatures of phase transitions through the superconductor to insulator transition of quench condensed films.

  17. Ginzburg-Landau theory and the superconducting transition in thin, amorphous bismuth films

    International Nuclear Information System (INIS)

    Van Vechten, D.

    1979-01-01

    The Aslamasov-Larkin (AL) theory can be derived from a classical treatment of the conductivity due to short-lived statistical fluctuations into the superconducting state if one truncates the Ginzburg-Landau free energy density expression to read F[psi] = α 0 vertical barpsi vertical bar 2 + c 0 vertical bar del psi vertical bar 2 , where psi is the superconducting order parameter. The next largest term in the GL free energy is (b/2) (vertical bar psi vertical bar 2 ) 2 and is conventionally interpreted as representing the energy associated with interactions between the fluctuations. My dissertation consists of the calculation of the effect of this term on the fluctuation conductivity in three different approximations and the comparison of my predictions to the data of R.E. Glover III and M.K. Chien on thin amorphous bismuth films. The first approximation calculates the contribution to the fluctuations' self energy of the ''tadpole'' diagrams. This approximation yields a 4 parameter equation. Its fits were particularly outstanding for the films deposited on quartz or roughened glass substrates and only for two smooth glass substrates were there non-isolated data points that were not fit at the lowest temperatures measured. (The equation runs into trouble for these films at approximately R(T)/R/sub o/ =.08.) The values of the theoretical equation's fitting parameters were determined by a least squares method and turns out to depend on film thickness in the manner predicted by the theory. The next calculation improves the self energy approximation by including all the ''ring'' diagrams

  18. Superconductivity

    Energy Technology Data Exchange (ETDEWEB)

    Batistoni, Paola; De Marco, Francesco; Pieroni, Leonardo [ed.

    2005-07-01

    Research on superconductivity at ENEA is mainly devoted to projects related to the ITER magnet system. In this framework, ENEA has been strongly involved in the design, manufacturing and test campaigns of the ITER toroidal field model coil (TFMC), which reached a world record in operating current (up to 80 kA). Further to this result, the activities in 2004 were devoted to optimising the ITER conductor performance. ENEA participated in the tasks launched by EFDA to define and produce industrial-scale advanced Nb3Sn strand to be used in manufacturing the ITER high-field central solenoid (CS) and toroidal field (TF) magnets. As well as contributing to the design of the new strand and the final conductor layout, ENEA will also perform characterisation tests, addressing in particular the influence of mechanical stress on the Nb3Sn performance. As a member of the international ITER-magnet testing group, ENEA plays a central role in the measurement campaigns and data analyses for each ITER-related conductor and coil. The next phase in the R and D of the ITER magnets will be their mechanical characterisation in order to define the fabrication route of the coils and structures. During 2004 the cryogenic measurement campaign on the Large Hadron Collider (LHC) by-pass diode stacks was completed. As the diode-test activity was the only LHC contract to be finished on schedule, the 'Centre Europeenne pour la Recherche Nucleaire' (CERN) asked ENEA to participate in an international tender for the cold check of the current leads for the LHC magnets. The contract was obtained, and during 2004, the experimental setup was designed and realised and the data acquisition system was developed. The measurement campaign was successfully started at the end of 2004 and will be completed in 2006.

  19. Stability of Tl-Ba-Ca-Cu-O Superconducting Thin Films

    Energy Technology Data Exchange (ETDEWEB)

    Siegal, M.P.; Overmyer, D.L.; Venturini, E.L.; Padilla, R.R.; Provencio, P.N.

    1999-08-23

    We report the stability of TlBa{sub 2}CaCu{sub 2}O{sub 7} (Tl-1212) and Tl{sub 2}Ba{sub 2}CaCu{sub 2}O{sub 8} (T1-2212) thin films and by inference, the stability of TlBa{sub 2}Ca{sub 2}Cu{sub 3}O{sub 9} (Tl-1223) and Tl{sub 2}Ba{sub 2}Ca{sub 2}Cu{sub 3}O{sub 10} (Tl-2223) thin films, under a variety of conditions. In general, we observe that the stability behavior of the single Tl-O layer materials (Tl-1212 and Tl-1223)are similar and the double Tl-O layer materials (Tl-2212 and Tl-2223) are similar. All films are stable with repeated thermal cycling to cryogenic temperatures. Films are also stable in acetone and methanol. Moisture degrades film quality rapidly, especially in the form of vapor. Tl-1212 is more sensitive to vapor than Tl-2212. These materials are stable to high temperatures in either N{sub 2}, similar to vacuum for the cuprates, and O{sub 2} ambients. While total degradation of properties (superconducting and structural) occur at the same temperatures for all phases, 600 C in N{sub 2} and 700 C in O{sub 2}, the onset of degradation occurs at somewhat lower temperatures for Tl-1212 than for Tl-2212 films. In all cases, sample degradation is associated with Tl depletion from the films.

  20. Nanoscale wedge polishing of superconducting thin films-an easy way to obtain depth dependent information by surface analysis techniques

    International Nuclear Information System (INIS)

    Shapoval, T; Engel, S; Gruendlich, M; Meier, D; Backen, E; Neu, V; Holzapfel, B; Schultz, L

    2008-01-01

    A mechanical wedge polishing procedure that offers a simple, cost-effective and rapid way to look into the depth of a thin film with different surface-sensitive scanning techniques has been developed. As an example of its wide applicability, this method was utilized for the investigation of two differently prepared superconducting YBa 2 Cu 3 O 7-δ thin films: an Hf-doped film prepared by chemical solution deposition and an undoped film grown by pulsed laser deposition. Upon polishing, the roughness of the samples was reduced to less than 5 nm (peak-to-valley) without influencing the superconducting properties of the films. Thus, nanoscale polishing opens up a unique possibility for microscopic studies with various surface-sensitive techniques. We demonstrate the successful imaging of flux lines by low temperature magnetic force microscopy after polishing a formerly rough as-prepared film. By applying the wedge polishing procedure to the Hf-doped sample, high resolution electron backscattering diffraction investigations reveal the homogeneous distribution of non-superconducting BaHfO 3 nanoparticles in the whole volume of the film

  1. New method of synthesis and physical properties of thick superconducting Er-123 films

    International Nuclear Information System (INIS)

    Muralidhar, M.; Sakai, N.; Machi, T.; Miyajiri, T.; Hirabayashi, I.; Tanaka, S.

    2008-01-01

    We have developed a low-cost, short time manufacturing process using a novel method, starting from a mixture of Er 2 BaO 4 , BaCuO 2 , and CuO, with an excess of Er at expense of Ba. Several micrometers thick films were prepared by the screen-printing technique, spreading the mixture paste on silver substrates, processed then in Ar-1% O 2 atmosphere. Using a double-step annealing process, we obtained good quality Er-123 thick films on silver substrates, with T c (onset) 92 K. Formation of large flat grains was observed by scanning electron microscope. According to XRD analysis, the films were preferentially c-axis oriented. The magnetic (induced), self-field J c measured at 77 K was above 32 kA/cm 2 . We observed a strong dependence of the transport current, I c , on the grain size. The maximum I c at 77 K as high as 10 A was observed in the sample with the average grain size around 40 μm. The present results indicate that our technology, enabling preparation of large-area superconducting thick films on Ag-based substrates in short processing times, is relatively cheap and appropriate for utilization in long-length RE-123 silver sheath wire production for commercial applications

  2. Quasi-two-dimensional superconductivity in wurtzite-structured InN films

    International Nuclear Information System (INIS)

    Ling, D.C.; Cheng, J.H.; Lo, Y.Y.; Du, C.H.; Chiu, A.P.; Chang, P.H.; Chang, C.A.

    2007-01-01

    C-axis oriented InN films with wurtzite structure were grown on sapphire(0001) substrate by MOCVD method. Superconductivity with transition onset temperature T c,onset around 3.5 K has been characterized by magnetotransport measurements in fields up to 9 Tesla for films with carrier concentration in the range of 1 x 10 19 cm -3 to 7 x 10 20 cm -3 . Among them, the film with a nitridation buffer layer has the highest zero-resistance temperature T c0 of 2 K. The normal-state magnetoresistance follows Kohler's rule ΔR/R∝(H/R) 2 , indicating that there is a single species of charge carrier with single scattering time at all points on the Fermi surface. The extrapolated value of zero-temperature upper critical field H c2 ab (0) and H c2 c (0) is estimated to be 5900 G and 2800 G, respectively, giving rise to the anisotropy parameter γ about 2.1. The angular dependence of the upper critical field is in good agreement with the behavior predicted by Lawrence-Doniach model in the two-dimensional (2D) limit strongly suggesting that the InN film is a quasi-2D superconductor. (copyright 2007 WILEY-VCH Verlag GmbH and Co. KGaA, Weinheim) (orig.)

  3. Roughness analysis applied to niobium thin films grown on MgO(001) surfaces for superconducting radio frequency cavity applications

    OpenAIRE

    D. B. Beringer; W. M. Roach; C. Clavero; C. E. Reece; R. A. Lukaszew

    2013-01-01

    This paper describes surface studies to address roughness issues inherent to thin film coatings deposited onto superconducting radio frequency (SRF) cavities. This is particularly relevant for multilayered thin film coatings that are being considered as a possible scheme to overcome technical issues and to surpass the fundamental limit of ∼50  MV/m accelerating gradient achievable with bulk niobium. In 2006, a model by Gurevich [Appl. Phys. Lett. 88, 012511 (2006)APPLAB0003-695110.1063/1.2162...

  4. Femtosecond optical detection of quasiparticle dynamics in high-Tc YBa2Cu3O7-δ superconducting thin films

    International Nuclear Information System (INIS)

    Han, S.G.; Vardeny, Z.V.; Wong, K.S.; Symko, O.G.; Koren, G.

    1990-01-01

    Femtosecond dynamics of photogenerated quasiparticles in YBa 2 Cu 3 O 7-δ superconducting thin films shows, at T≤T c , two main electronic processes: (i) quasiparticle avalanche production during hot-carrier thermalization, which takes about 300 fsec; (ii) recombination of quasiparticles to form Cooper pairs, which is completed within 5 psec. In contrastr, nonsuperconducting epitaxial films such as PrBa 2 Cu 2 O 7 and YBa 2 Cu 3 O 6 show regular picosecond electronic response

  5. In-situ deposition of YBCO high-Tc superconducting thin films by MOCVD and PE-MOCVD

    International Nuclear Information System (INIS)

    Zhao, J.; Noh, D.W.; Chern, C.; Li, Y.Q.; Norris, P.E.; Kear, B.; Gallois, B.

    1991-01-01

    Metal-Organic Chemical Vapor Deposition (MOCVD) offers the advantages of a high degree of compositional control, adaptability for large scale production, and the potential for low temperature fabrication. The capability of operating at high oxygen partial pressure is particularly suitable for in situ formation of high temperature superconducting (HTSC) films. Yttrium barium copper oxide (YBCO) thin films having a sharp zero-resistance transition with T(sub c) greater than 90 K and J(sub c) of approximately 10(exp 4) A on YSZ have been prepared, in situ, at a substrate temperature of about 800 C. Moreover, the ability to form oxide films at low temperature is very desirable for device applications of HTSC materials. Such a process would permit the deposition of high quality HTSC films with a smooth surface on a variety of substrates. Highly c-axis oriented, dense, scratch resistant, superconducting YBCO thin films with mirror-like surfaces have been prepared, in situ, at a reduced substrate temperature as low as 570 C by a remote microwave-plasma enhanced metal-organic chemical vapor deposition (PE-MOCVD) process. Nitrous oxide was used as a reactant gas to generate active oxidizing species. This process, for the first time, allows the formation of YBCO thin films with the orthorhombic superconducting phase in the as-deposited state. The as-deposited films grown by PE-MOCVD show attainment of zero resistance at 72 K with a transition width of about 5 K. MOCVD was carried out in a commercial production scale reactor with the capability of uniform deposition over 100 sq cm per growth run. Preliminary results indicate that PE-MOCVD is a very attractive thin film deposition process for superconducting device technology

  6. Y1Ba2Cu3O(7-delta) thin film dc SQUIDs (superconducting quantum interference device)

    Science.gov (United States)

    Racah, Daniel

    1991-03-01

    Direct current superconducting quantum interferometers (SQUIDs) based on HTSC thin films have been measured and characterized. The thin films used were of different quality: (1) Granular films on Sapphire substrates, prepared either by e-gun evaporation, by laser ablation or by MOCVD (metal oxide chemical vapor deposition), (2) Epitaxial films on MgO substrates. Modulations of the voltage on the SQUIDs as a function of the applied flux have been observed in a wide range of temperatures. The nature of the modulation was found to be strongly dependent on the morphology of the film and on its critical current. The SQUIDs based on granular films were relatively noisy, hysteretic and with a complicated V-phi shape. Those devices based on low quality (lowIc) granular films could be measured only at low temperatures (much lower than 77 K). While those of higher quality (granular films with high Ic) could be measured near to the superconductive transition. The SQUID based on high quality epitaxial film was measured near Tc and showed an anomalous, time dependent behavior.

  7. Laser writing of superconducting patterns on YBa2Cu3Ox films

    International Nuclear Information System (INIS)

    Dye, R.C.; Muenchausen, R.E.; Nogar, N.S.; Mukherjee, A.; Brueck, S.R.J.

    1990-01-01

    A novel process for the direct laser writing of thin-film high T c patterns is demonstrated. The process consists of deposition of a high quality film (308 nm laser ablation from a YBa 2 Cu 3 O x target with a 750 degree C substrate temperature and a 150 mTorr O 2 ambient), annealing in an inert atmosphere (Ar at 400 degree C for 5--20 min) to reduce the oxygen content and depress or eliminate the superconducting transition temperature, and direct-write laser heating (1.06 μm at ∼0.5 kW/cm 2 for ∼5 min) in an oxygen atmosphere at ∼590 Torr to selectively regenerate the high T c material. rf eddy current and four-point resistivity probe results confirm this process for both SrTiO 3 and LaAlO 3 substrates. Scanning electron micrographs indicate that this is a very mild processing sequence with no observable changes in film morphology

  8. Study of the surface resistance of superconducting niobium films at 1.5 GHz

    CERN Document Server

    Benvenuti, Cristoforo; Campisi, I E; Darriulat, Pierre; Peck, M A; Russo, R; Valente, A M

    1999-01-01

    A systematic study of superconducting properties of niobium films sputtered on the inner wall of radiofrequency cavities is presented. The measured quantities include in particular the response to 1.5 GHz microwaves, the critical temperature, the penetration depth and the magnetic penetration field. In addition to films grown in different gas discharges (Xe, Kr, Ar and Ar/Ne mixtures) and to films grown on substrates prepared under different conditions, the study also includes bulk niobium cavities. The surface resistance is analysed in terms of its dependence on temperature, on RF field and, when relevant, on the density of trapped fluxons. A simple parameterisation is found to give a good fit to the data. Once allowance for the presence of impurities and defects is made by means of a single parameter, the electron mean free path, good agreement with BCS theory is observed. The fluxon-induced losses are studied in detail and their dependence on RF field, on temperature and on the density of trapped fluxons i...

  9. Studies of superconductors using a low-temperature, high-field scanning tunneling microscope

    International Nuclear Information System (INIS)

    Kirtley, J.R.; Feenstra, R.M.; Fein, A.P.

    1988-01-01

    We have developed a scanning tunneling microscope (STM) capable of operating at temperatures as low as 0.4 K and fields as high as 8 T. We have used this STM to study the energy gap of the high-T/sub c/ superconductors La--Sr--Cu--O and Y--Ba--Cu--O. We find that the reduced gap for these oxide superconductors falls in the range 3<2Δ/k/sub B/T/sub c/<7, for polycrystalline, single-crystal, and thin-film samples. We have also simultaneously imaged the surface topography and superconducting energy gap for thin films of the granular superconductor NbN. We occasionally see regions with smaller best-fit gaps that correlate with surface topographical features, but have been unable so far to image flux vortices

  10. A study on the superconducting properties of YBa2Cu9-xNbxOy thin films

    International Nuclear Information System (INIS)

    Srinivas, S.; Bhatnagar, A.K.; Pinto, R.

    1994-01-01

    Effect of niobium substitution at the copper site in YBa 2 Cu 9 O 7-x was studied in thin film form. The films were deposited by laser ablation technique using the targets of the YBa 2 Cu 3-x Nb x O y where x = 0.0, 0.025, 0.05, 0.1, 0.2, 0.4, 0.8 and 1.0 under identical deposition conditions on SrTiO 9 substrates. Films were characterized by XRD, resistivity, I-V and J c measurements. Films made from x = 0.025 and 0.05 concentrations of Nb substituted targets showed relatively improved superconducting properties compared to that of undoped films. The best 7 realized for x = 0.025 Nb concentration was 1.8 x 10 σ A/cm 2 and for 0.05 Nb concentration it was 3.2x10 σ A/cm 2 at 77K. However, degradation of the superconducting properties, with the increase of x ≥ 0.1 Nb concentration and drastic suppression and complete loss of superconductivity was noticed for x ≥ 0.4. The growth of impurity phase YBa 2 NbO 6 for x = 0.1 and above of Nb concentration was noticed from XRD patterns. However, the site occupancy of Nb could not be confirmed from these studies

  11. Composite vortex ordering in superconducting films with arrays of blind holes

    International Nuclear Information System (INIS)

    Berdiyorov, G R; Milosevic, M V; Peeters, F M

    2009-01-01

    The pinning properties of a superconducting thin film with a square array of blind holes are studied using the nonlinear Ginzburg-Landau theory. Although blind holes provide a weaker pinning potential than holes (also called antidots), several novel vortex structures are predicted for different size and thickness of the blind holes. Orientational dimer and trimer vortex states as well as concentric vortex shells can nucleate in the blind holes. In addition, we predict the stabilization of giant vortices that may be located both in the pinning centers and/or at the interstitial sites, as well as the combination of giant vortices with sets of individual vortices. For large blind holes, local vortex shell structures inside the blind holes may transfer their symmetry to interstitial vortices as well. The subtle interplay of shell formation and traditional Abrikosov vortex lattices inside the blind holes is also studied for different numbers of trapped vortices.

  12. Vortex lattice in effective type-I superconducting films with periodic arrays of submicron holes

    International Nuclear Information System (INIS)

    Berdiyorov, G.R.; Milosevic, M.V.; Peeters, F.M.

    2006-01-01

    The vortex matter and related phenomena in superconducting films with periodic arrays of microholes (antidots) are studied within the nonlinear Ginzburg-Landau (GL) theory. By varying the GL parameter κ, the vortex-vortex interaction is fine tuned, from repulsive to attractive behavior. This interaction is of crucial importance for equilibrium vortex structures, the saturation number of the antidots, and the related quantities, such as critical current. Due to vortex attraction in effectively type-I samples, the giant-vortex state becomes energetically favorable (contrary to the type-II behavior). For the same reason, the number of vortices which can be captured by antidots, increases with decreasing κ. As a result, for given magnetic field, the critical current is larger for effectively type-I superconductors than in conventional type-II cases

  13. Anisotropic behaviour of transmission through thin superconducting NbN film in parallel magnetic field

    Energy Technology Data Exchange (ETDEWEB)

    Šindler, M., E-mail: sindler@fzu.cz [Institute of Physics ASCR, v. v. i., Cukrovarnická 10, CZ-162 53 Praha 6 (Czech Republic); Tesař, R. [Institute of Physics ASCR, v. v. i., Cukrovarnická 10, CZ-162 53 Praha 6 (Czech Republic); Faculty of Mathematics and Physics, Charles University, Ke Karlovu 3, CZ-121 16 Praha (Czech Republic); Koláček, J. [Institute of Physics ASCR, v. v. i., Cukrovarnická 10, CZ-162 53 Praha 6 (Czech Republic); Skrbek, L. [Faculty of Mathematics and Physics, Charles University, Ke Karlovu 3, CZ-121 16 Praha (Czech Republic)

    2017-02-15

    Highlights: • Transmission through thin NbN film in parallel magnetic field exhibits strong anisotropic behaviour in the terahertz range. • Response for a polarisation parallel with the applied field is given as weighted sum of superconducting and normal state contributions. • Effective medium approach fails to describe response for linear polarisation perpendicular to the applied magnetic field. - Abstract: Transmission of terahertz waves through a thin layer of the superconductor NbN deposited on an anisotropic R-cut sapphire substrate is studied as a function of temperature in a magnetic field oriented parallel with the sample. A significant difference is found between transmitted intensities of beams linearly polarised parallel with and perpendicular to the direction of applied magnetic field.

  14. Microwave surface resistance of YBa2Cu3O/sub 6.9/ superconducting films

    International Nuclear Information System (INIS)

    Martens, J.S.; Beyer, J.B.; Ginley, D.S.

    1988-01-01

    The microwave surface resistance of an YBa 2 Cu 3 O/sub 6.9/ superconducting thick film was measured over the range 7.0--16.7 GHz at 77 K. This was done by placing a sample in a TE 01 /sub n/ wavemeter cavity and observing the change in selectivity of the cavity. The material's surface resistance is of the same order of magnitude as that of silver at 77 K from 8 to 12 GHz and improves about another order at 4.2 K. The power-law behavior of surface resistance with frequency is probably close to quadratic. This is similar to the behavior of low critical temperature superconductors

  15. Anisotropic response of the moving vortex lattice in superconducting Mo(1-x)Gex amorphous films

    International Nuclear Information System (INIS)

    Dolz, M.I.; Shalóm, D.E.; Pastoriza, H.; López, D.O.

    2012-01-01

    We have performed magnetic susceptibility measurements in Mo 1-x Ge x amorphous thin films biased with an electrical current using anisotropic coils. We tested the symmetry of the vortex response changing the relative orientation between the bias current and the susceptibility coils. We found a region in the DC current-temperature phase diagram where the dynamical vortex structures behave anisotropically. In this region the shielding capability of the superconducting currents measured by the susceptibility coils is less effective along the direction of vortex motion compared to the transverse direction. This anisotropic response is found in the same region where the peak effect in the critical current is developed. On rising temperature the isotropic behavior is recovered.

  16. Electron mean free path dependence of the critical currents and the pair-breaking limit in superconducting films

    International Nuclear Information System (INIS)

    Fedorov, N.; Rinderer, L.

    1977-01-01

    We have studied the current-induced breakdown of superconductivity in wide (100--980 μm) and thin (0.25--0.98 μm) films of tin. It is shown that the current at which the resistance of the sample begins to rise rapidly in the process of the destruction of superconductivity by a current can be fairly well associated with the theoretical value of the pair-breaking current in the Ginzburg-Landau phenomenological approach (I/sub c//sup G L/). This effect is observed over a rather wide temperature region (up to ΔTapprox.0.7 K), depending on the electron mean free path in the films. The values of the critical currents outside the above-mentioned region correlate qualitatively with those determined by inhomogeneities of the films as proposed by Larkin and Ovchinnikov

  17. Transport in reversibly laser-modified YBa2Cu3O/sub 7-//sub x/ superconducting thin films

    International Nuclear Information System (INIS)

    Krchnavek, R.R.; Chan, S.; Rogers, C.T.; De Rosa, F.; Kelly, M.K.; Miceli, P.F.; Allen, S.J.

    1989-01-01

    A focused argon ion laser beam in a controlled ambient is used to modify the transport properties of superconducting YBa 2 Cu 3 O/sub 7-//sub x/ thin films. The laser-modified region shows a sharp transition temperature (T/sub c/≅76 K) that is reduced from the unmodified regions of the film (T/sub c/≅87 K). In situ monitoring of the room-temperature electrical resistance is used to control the laser processing and prevent formation of the semiconducting phase. The original properties of the superconducting film can be recovered by plasma oxidation indicating that the laser-induced phase is oxygen deficient

  18. Quantum and superconducting fluctuations effects in disordered Nb 1- xTa x thin films above Tc

    Science.gov (United States)

    Giannouri, M.; Papastaikoudis, C.

    1999-05-01

    Disordered Nb 1- xTa x thin films are prepared with e-gun coevaporation. The influence of the β-phase of tantalum in the critical temperature Tc is observed as a function of the substrate temperature. The measurements of transverse magnetoresistance at various isothermals are interpreted in terms of weak-localization and superconducting fluctuations. From the fitting procedure, the phase breaking rate τφ-1 and the Larkin parameter βL are estimated as a function of temperature. Conclusions about the dominant inelastic scattering mechanisms at various temperature regions as well as for the dominant mechanism of superconducting fluctuations near the transition temperature are extracted.

  19. Surface characterization of superconductive Nd1Ba2Cu3Oy thin films using scanning probe microscopes

    International Nuclear Information System (INIS)

    Ting, W.; Badaye, M.; Itti, R.; Morishita, T.; Koshizuka, N.; Tanaka, S.

    1996-01-01

    Recently, superconductive Nd 1 Ba 2 Cu 3 O y (Nd123) thin films with high superconducting transition temperature (T c ) have been successfully fabricated at the authors institute employing the standard laser ablation method. In this paper, they report parts of the results of surface characterization of the Nd123 thin films using an ultrahigh vacuum scanning tunneling microscope/spectroscopy (UHV-STM/STS) and an atomic force microscope (AFM) system operated in air. Clear spiral pattern is observed on the surfaces of Nd123 thin films by STM and AFM, suggesting that films are formed by two-dimensional island growth mode at the final growing stage. Contour plots of the spirals show that the step heights of the spirals are not always the integer or half integer numbers of the c-axis parameter of the structure. This implies that the surface natural termination layer of the films may not be unique. Surface atomic images of the as-prepared Nd123 thin films are obtained employing both STM and AFM. STS measurements show that most of the surfaces are semiconductive, or sometimes even metallic. The results of STS measurements together with the fact that they are able to see the surface atomic images using scanning probe microscopes suggest that exposure to air does not cause serious degradation to the as-prepared surfaces of Nd123 thin films

  20. Parallel critical magnetic fields of superconducting hyperthin films of vanadium and technetium

    International Nuclear Information System (INIS)

    Teplov, A.A.; Mikheeva, M.N.

    1980-01-01

    The nature of limiting parallel magnetic fields Hsub(c parallel) destroying a superconducting state in films of vanadium and technetium is found out. A dependence of Hsub(c parallel) on the thickness of films up to d approximately 60 A is studied. The |dHsub(c parallel)sup(2)/dT|sub(Tsub(c)) derivative, which increases in the region of large d with the increase of 1/d and achieves the maximum va;ue at d approximately 100 A, was determined, using the experimental data. For the most thin films this derivative tends to drop (the value of the derivative changes from 16 up to 20.00 kOe 2 /k and for technetium and from 4 up to 2100 kOe 2 /k for vanadium). Such stop at |dHsub(c11)sup(2)/ dT|sub(Tsub(c)) growth during the decrease of d is not explained in the framework of the theory taking into account only orbital effects. An account of the additional paramagnetic effect (spin effects) leads to a good agreement of the experiment with the theory in the whole range of thicknesses for vanadium. For technetium films in the d range <=110 A the value of Hsub(c parallel) exceeds several times Hsub(c parallel) calculated with provision of spin effects. For d approximately 80 A and d approximately 55 A this increase achieves the triple value. This effect is explained qualitatively by the spin-orbital scattering appearing with the increase of the atomic number

  1. New possibility of magnetic ripple shielding for specific heat measurements in hybrid magnets

    NARCIS (Netherlands)

    Tarnawski, Z.; Meulen, der, H. van; Franse, J.J.M.; Kadowaki, K.; Veenhuizen, P.A.; Klaasse, J.

    1988-01-01

    A test of the new high Tc superconducting materials for magnetic ripple shielding has been carried out. It was found that magnetic ripples of 0.0009 T (peak-to-peak) in the frequency range below 20 kHz can be completely shielded in high static fields by a 2 mm thick Y-Ba-Cu-O screen.

  2. Two concepts of introducing thin-film superconductivity in Ge and Si by use of Ga-ion implantation

    Energy Technology Data Exchange (ETDEWEB)

    Skrotzki, Richard [Dresden High Magnetic Field Laboratory (HLD) and Institute of Ion Beam Physics and Materials Research, Helmholtz-Zentrum Dresden-Rossendorf (HZDR), Dresden (Germany); Department of Chemistry and Food Chemistry, TU Dresden (Germany); Herrmannsdoerfer, Thomas; Fiedler, Jan; Heera, Viton; Voelskow, Matthias; Muecklich, Arndt; Schmidt, Bernd; Skorupa, Wolfgang; Helm, Manfred; Wosnitza, Joachim [Dresden High Magnetic Field Laboratory (HLD) and Institute of Ion Beam Physics and Materials Research, Helmholtz-Zentrum Dresden-Rossendorf (HZDR), Dresden (Germany)

    2012-07-01

    We report on two unconventional routes of embedding superconducting nanolayers in a semiconducting environment. Ion implantation and subsequent annealing have been used for preparation of superconducting thin-films of Ga-doped germanium (Ge:Ga) as well as 10 nm thin amorphous Ga-rich layers in silicon (Si:Ga). Structural investigations by means of XTEM, EDX, RBS/C, and SIMS have been performed in addition to low-temperature electrical transport and magnetization measurements. Regarding Ge:Ga, we unravel the evolution of T{sub c} with charge-carrier concentration while for Si:Ga recently implemented microstructuring renders critical-current densities or more than 50 kA/cm{sup 2}. Combined with a superconducting onset at around 10 K, this calls for on-chip application in novel heterostructured devices.

  3. Topological Magnon Bands and Unconventional Superconductivity in Pyrochlore Iridate Thin Films

    Science.gov (United States)

    Laurell, Pontus; Fiete, Gregory A.

    2017-04-01

    We theoretically study the magnetic properties of pyrochlore iridate bilayer and trilayer thin films grown along the [111] direction using a strong coupling approach. We find the ground state magnetic configurations on a mean field level and carry out a spin-wave analysis about them. In the trilayer case the ground state is found to be the all-in-all-out (AIAO) state, whereas the bilayer has a deformed AIAO state. For all parameters of the spin-orbit coupled Hamiltonian we study, the lowest magnon band in the trilayer case has a nonzero Chern number. In the bilayer case we also find a parameter range with nonzero Chern numbers. We calculate the magnon Hall response for both geometries, finding a striking sign change as a function of temperature. Using a slave-boson mean-field theory we study the doping of the trilayer system and discover an unconventional time-reversal symmetry broken d +i d superconducting state. Our study complements prior work in the weak coupling limit and suggests that the [111] grown thin film pyrochlore iridates are a promising candidate for topological properties and unconventional orders.

  4. Topological Magnon Bands and Unconventional Superconductivity in Pyrochlore Iridate Thin Films.

    Science.gov (United States)

    Laurell, Pontus; Fiete, Gregory A

    2017-04-28

    We theoretically study the magnetic properties of pyrochlore iridate bilayer and trilayer thin films grown along the [111] direction using a strong coupling approach. We find the ground state magnetic configurations on a mean field level and carry out a spin-wave analysis about them. In the trilayer case the ground state is found to be the all-in-all-out (AIAO) state, whereas the bilayer has a deformed AIAO state. For all parameters of the spin-orbit coupled Hamiltonian we study, the lowest magnon band in the trilayer case has a nonzero Chern number. In the bilayer case we also find a parameter range with nonzero Chern numbers. We calculate the magnon Hall response for both geometries, finding a striking sign change as a function of temperature. Using a slave-boson mean-field theory we study the doping of the trilayer system and discover an unconventional time-reversal symmetry broken d+id superconducting state. Our study complements prior work in the weak coupling limit and suggests that the [111] grown thin film pyrochlore iridates are a promising candidate for topological properties and unconventional orders.

  5. Influence of annealing atmosphere on structural and superconducting properties of MgB{sub 2} thin films

    Energy Technology Data Exchange (ETDEWEB)

    Gregor, M., E-mail: gregor@fmph.uniba.sk; Plecenik, T.; Sobota, R.; Brndiarova, J.; Roch, T.; Satrapinskyy, L.; Kus, P.; Plecenik, A.

    2014-09-01

    Highlights: • Superconducting MgB{sub 2} thin film were deposited by co-deposition using the thermal and e-beam evaporation. • Ex situ annealing process was done using various atmospheres. • Influence of annealing atmosphere and temperature on superconducting and structural properties were studied. • Possible mechanisms of the formation and crystallization of MgB{sub 2} thin film are discussed. - Abstract: Influence of an ex situ annealing temperature and atmosphere on chemical composition and structural and superconducting properties of MgB{sub 2} thin films deposited by vacuum evaporation has been investigated. The annealing has been done in Ar, N{sub 2} and Ar + 5%H{sub 2} atmospheres at pressure of 700 Pa and temperature varying from 700 to 800 °C. It has been shown that annealing in Ar and N{sub 2} atmosphere at 700–800 °C produces relatively thick MgO layer on the surface of the films, while creation of such layer is highly reduced if the annealing is done in reducing Ar + 5%H{sub 2} atmosphere. The XPS and XRD results suggest that the MgO layer prevents out-diffusion of Mg from the film during the annealing, what assures better stoichiometry of the films as well as creation of larger MgB{sub 2} grains. The films with the highest amount of MgO on the surface, annealed in nitrogen atmosphere, thus paradoxically exhibited the highest critical temperature of T{sub c0} = 34.8 K with very sharp transition width of 0.1 K.

  6. Superconducting Fluctuations above T c and pair breaking parameters of two dimensional Niobium Nitride Films

    Science.gov (United States)

    Shinozaki, B.; Ezaki, S.; Odou, T.; Makise, K.; Asano, T.

    2018-03-01

    Transport properties have been investigated for the epitaxial superconducting NbN thin films. We analysed the excess conductance σ’ ≡ σ(T) - σN by the sum of the Aslamazov-Larkin (AL) and Maki-Thompson (MT) terms for thermal fluctuations above T c, where the σN ≡1/R sq N is the normal state sheet conductance. We have found that the theoretical expression σ’theo (T) = σ’AL (T) + σ’MT (T,δ) can be well fitted to σ’exp (T) with use of the suitable value of the pair breaking parameter δ in the MT term relating to the inelastic scattering rate 1/τin(T) as δ = πħ/8k B Tτin. The rate 1/τin(T) given by the sum of 1/τfluc(T), 1/τe-e(T) and 1/τe-ph (T) is determined from the analysis of the magneto-conductance Δσ = σ(H) – σ(0) by the sum of AL, MT and the localization terms, where the first, second and third terms correspond to the rate due to the superconducting fluctuation effect, electron-electron and electron-phonon interactions, respectively. The R sq N dependence of δ is expressed by δ = δ0 + αR sq N, where the first term δ0 due to 1/τe-ph (T) and the second term due to the sum of 1/τfluc(T) and 1/τe-e(T). Although we obtained a reasonable value of Debye temperature ΘD ≈630 K from the δ0, the magnitude of the α is about 5 times larger than the theoretical value.

  7. Relations between structural and superconducting properties of bulk and thin film high-Tc materials

    International Nuclear Information System (INIS)

    Hessel Andersen, N.

    1994-06-01

    The structural ordering of oxygen deficient and Co-doped YBCO (YBa 2 Cu 3-y Co y O 6+x ) have been studied experimentally, and by computer simulations of the oxygen ordering in the basal plane of the structure. The calculations are based on the two-dimensional ASYNNNI model and its modifications. Good agreement is established between the ASYNNNI calculations and the experimentally observed structural properties of the double cell ortho-II structure and the oxygen disordering process from Co-doping into the basal plane. A model that relates the superconducting transition temperature T c (x) of undoped YBCO and T c (y) of Co-doped YBCO to the formation of specific domains of the two orthorhombic ordered oxygen phases, ortho-I and ortho-II, shows a close agreement with experimental T c (x) and T c (y) data of samples prepared under equilibrium conditions. The structural changes as a result of metal ion substitutions and oxidation/reduction processes have been studied by neutron powder diffraction in Pb 2 Sr 2 Ln 1-x Ca x Cu 3 O 8+y (Ln = Y and Ho), Nd 1.85 Ce 0.15 CuO 4+y , and chemically oxidized La 2-x Sr x CuO 4+y 2 Cu 3-y Al y O 6+x (y 2 Cu 3 O 6+x and Bi 2 Sr 2 CaCu 2 O 8+x thin films deposited on SrTiO 3 (001), MgO (001), LaAlO 3 (001), and NdGaO 3 (001) substrates has been studied by x-ray diffraction, TEM and RBS, and the structural ordering has been analysed in relation to their superconducting properties. (au) (30 ills., 29 refs.)

  8. Imaging the electron-boson coupling in superconducting FeSe films using a scanning tunneling microscope.

    Science.gov (United States)

    Song, Can-Li; Wang, Yi-Lin; Jiang, Ye-Ping; Li, Zhi; Wang, Lili; He, Ke; Chen, Xi; Hoffman, Jennifer E; Ma, Xu-Cun; Xue, Qi-Kun

    2014-02-07

    Scanning tunneling spectroscopy has been used to reveal signatures of a bosonic mode in the local quasiparticle density of states of superconducting FeSe films. The mode appears below Tc as a "dip-hump" feature at energy Ω∼4.7kBTc beyond the superconducting gap Δ. Spectra on strained regions of the FeSe films reveal simultaneous decreases in Δ and Ω. This contrasts with all previous reports on other high-Tc superconductors, where Δ locally anticorrelates with Ω. A local strong coupling model is found to reconcile the discrepancy well, and to provide a unified picture of the electron-boson coupling in unconventional superconductors.

  9. Plasma-assisted MOCVD growth of superconducting NbN thin films using Nb dialkylamide and Nb alkylimide precursors

    International Nuclear Information System (INIS)

    Liu Xiang; Ott, A.W.; Chang, R.P.H.; Babcok, J.R.; Belot, J.A.; Metz, M.V.; Marks, T.J.; Lane, M.A.; Kannewurf, C.R.

    2001-01-01

    The first example of the use of metal-organic precursors for depositing NbN superconducting thin films is described. The study, which employed niobium(IV) and niobium(V) pulsed source precursors and hydrazine plasma as the nitrogen source, indicates that T c is highly dependent on the lattice parameters and level of oxygen impurities, which are in turn governed by growth and post-deposition annealing temperatures. (orig.)

  10. Interpretation of transmission through type II superconducting thin film on dielectric substrate as observed by laser thermal spectroscopy

    Czech Academy of Sciences Publication Activity Database

    Šindler, Michal; Tesař, Roman; Koláček, Jan; Skrbek, L.

    2012-01-01

    Roč. 483, DEC (2012), s. 127-135 ISSN 0921-4534 R&D Projects: GA ČR(CZ) GAP204/11/0015 Grant - others:European Science Foundation(XE) NES, 2007 - 2012 Institutional research plan: CEZ:AV0Z10100521 Keywords : far- infrared transmission * NbN * superconducting film * vortices * terahertz waves Subject RIV: BM - Solid Matter Physics ; Magnetism Impact factor: 0.718, year: 2012

  11. Observation of weakly adsorbed oxygen on Y5Ba6Cu11Oy

    International Nuclear Information System (INIS)

    Kao, Sendjaja; Ng, K.Y.S.

    1992-01-01

    In the Y-Ba-Cu-O compound, several investigators have observed superconductivity-like phenomena at higher temperatures, some even reaching zero resistance at 250 K. Huang et al. reported an observation of sharp resistivity drops, at least four orders of magnitude at ca. 230 K, in one annealed sample of Eu 1 Ba 2 Cu 3 O 6+x . But the resistance drop disappeared after thermal cycling, although the correlated magnetic anomalies observed in their magnetic measurements persisted for many thermal cycles. Recently, Chen et al reported that the superconductivity-like transition at a temperature above 200 K in their mixed-phase YBaCuO persisted for 29 thermal cycles. The samples were treated by a low-temperature (50-70C) oxygenation process and enclosed in oxygen environment during electrical and magnetic measurements. They also found that this higher-temperature transition could not survive thermal cycling when the sample was in helium atmosphere. The role oxygen plays in their observations is not clear, but they speculated that weakly bonded oxygen atom/atoms are responsible for the high-temperature phase. This observation of T c > 200 K in oxygen environment is recently confirmed by Schonberger et al. in highly oriented multiphase Y-Ba-Cu-O thin film. Here, the authors observed, for the first time, adsorption of weakly bonded oxygen at low temperature (≤250C) by a Y 5 Ba 6 Cu 11 O y sample, using thermogravimetric analysis. The resulting oxygen enriched phase in the surface layers may be attributed to the observation of a superconductivity-like transition at above 200 K

  12. Layer-by-layer deposition of superconducting Sr-Ca-Cu-O films by the spray pyrolysis technique

    International Nuclear Information System (INIS)

    Pawar, S.H.; Pawaskar, P.N.; Ubale, M.J.; Kulkarni, S.B.

    1995-01-01

    Layer-by-layer deposition of Sr-Ca-Cu-O films has been carried out using the spray pyrolysis technique. Reagent-grade nitrates of strontium, calcium and copper were used to prepare starting solutions for spray pyrolysis. A two-step procedure was used for every layer of the constituents in the sequence Sr-Cu-Ca-Cu-Sr: first, deposition onto silver substrate at 350 C, then firing at T≥450 C, both at atmospheric pressure. The films were 2-3 μm thick and showed adequate adhesion to the substrate. The films were then characterised by studying their electron micrographs, X-ray diffraction patterns and electrical resistivity. The films showed superconductivity below 104 K. ((orig.))

  13. Low-frequency noise in high-Tc superconducting thick films

    International Nuclear Information System (INIS)

    Aponte, J.M.; Gutierrez, G.; Octavio, M.

    1990-01-01

    In this paper experimental results on the resistance noise in thick films of YBa 2 Cu 3 O 7-δ in the vicinity of the superconducting transition are reported. The measurements were performed in samples with broad resistive transitions and in the frequency range from 1Hz to 100 Hz. The power spectral density S v /V 2 of the excess noise is obtained by subtracting the current-independent background noise from the total measured noise. The authors observed that at the transition, the magnitude of S v /V 2 rises above its level at room temperature exhibiting peaks at the same temperatures at which R -1 dR/dT has maxima. The authors performed measurements of S v /V 2 as a function of the current through the sample and the authors found that it diverges as the critical current is approached from above and that it is zero below the critical current. This transition is found to be described quite well by a percolation model

  14. Quantum dynamics of small Josephson junctions: an application to superconductivity in granular films

    International Nuclear Information System (INIS)

    Fisher, M.P.A.

    1986-01-01

    This thesis is devoted to a study of the quantum dynamics of small Josephson junctions. Of interest are those features of the junction's behavior which depend explicitly on the quantum mechanical nature of the phase difference phi between the superconductors. In Chapters I and II several calculations are described which focus on the junction's DC resistance. A fully quantum mechanical Hamiltonian is employed that incorporates the dissipative effects due to the unpaired electrons by coupling to a bath of harmonic oscillators. It is shown that the model exhibits a novel zero temperature phase transition as a function of the strength of the dissipation. In the low dissipation regime the phase is free to tunnel quantum mechanically and the junction's resistance is finite; in response to an external current, tunnelling induces successive 2π phase slips leading to a finite voltage state. In contrast, in the high dissipation regime, tunnelling is suppressed and the junction behaves as a superconductor carrying current with no resistive losses. In Chapters III and IV, these results are applied in an attempt to explain the recent observation that in ultra thin Sn films there is apparently a universal normal state sheet resistance above which superconductivity cannot be established

  15. Phonon-induced enhancement of the energy gap and critical current of superconducting aluminum films

    International Nuclear Information System (INIS)

    Seligson, D.; Clarke, J.

    1983-01-01

    Enhancements of the energy gap Δ and the critical current I/sub c/ have been induced in thin superconducting aluminum films near the transition temperature T/sub c/ by pulses of phonons at approximately 9 GHz. In terms of the change in temperature Vertical BardeltaT/T/sub c/Vertical Bar necessary to produce the same enhancement in equilibrium, the gap enhancement increased smoothly with phonon power at fixed temperature and decreasing temperature at fixed phonon power; however, very close to T/sub c/ the enhancement rolled off. At relatively low phonon powers, the data were in good agreement with the theory of Eckern, Schmid, Schmutz, and Schoen, but at higher power levels the data fell markedly below the predictions of the theory. The critical-current enhancements in terms of Vertical BardeltaT/T/sub c/Vertical Bar were always larger than the gap enhancements at the same temperature and phonon power. At fixed phonon power the critical-current enhancements were nearly independent of temperature, except very close to T/sub c/ where the enhancement became small. The inclusion of the nonequilibrium quasiparticle distribution and the kinetic energy of the supercurrent in the theory relating the critical-current enhancement to the gap enhancement did not resolve the discrepancies between the two enhancements. It appears likely that there is an additional mechanism for critical-current enhancement that has not yet been identified

  16. Depairing critical current achieved in superconducting thin films with through-thickness arrays of artificial pinning centers

    International Nuclear Information System (INIS)

    Dinner, Rafael B; Wimbush, Stuart C; MacManus-Driscoll, Judith L; Blamire, Mark G; Robinson, Adam P

    2011-01-01

    Large area arrays of through-thickness nanoscale pores have been milled into superconducting Nb thin films via a process utilizing anodized aluminum oxide thin film templates. These pores act as artificial flux pinning centers, increasing the superconducting critical current, J c , of the Nb films. By optimizing the process conditions including anodization time, pore size and milling time, J c values approaching and in some cases matching the Ginzburg-Landau depairing current of 30 MA cm -2 at 5 K have been achieved-a J c enhancement over as-deposited films of more than 50 times. In the field dependence of J c , a matching field corresponding to the areal pore density has also been clearly observed. The effect of backfilling the pores with magnetic material has then been investigated. While backfilling with Co has been successfully achieved, the effect of the magnetic material on J c has been found to be largely detrimental compared to voids, although a distinct influence of the magnetic material in producing a hysteretic J c versus applied field behavior has been observed. This behavior has been tested for compatibility with currently proposed models of magnetic pinning and found to be most closely explained by a model describing the magnetic attraction between the flux vortices and the magnetic inclusions.

  17. Roughness analysis applied to niobium thin films grown on MgO(001) surfaces for superconducting radio frequency cavity applications

    Science.gov (United States)

    Beringer, D. B.; Roach, W. M.; Clavero, C.; Reece, C. E.; Lukaszew, R. A.

    2013-02-01

    This paper describes surface studies to address roughness issues inherent to thin film coatings deposited onto superconducting radio frequency (SRF) cavities. This is particularly relevant for multilayered thin film coatings that are being considered as a possible scheme to overcome technical issues and to surpass the fundamental limit of ˜50MV/m accelerating gradient achievable with bulk niobium. In 2006, a model by Gurevich [Appl. Phys. Lett. 88, 012511 (2006)APPLAB0003-695110.1063/1.2162264] was proposed to overcome this limit that involves coating superconducting layers separated by insulating ones onto the inner walls of the cavities. Thus, we have undertaken a systematic effort to understand the dynamic evolution of the Nb surface under specific deposition thin film conditions onto an insulating surface in order to explore the feasibility of the proposed model. We examine and compare the morphology from two distinct Nb/MgO series, each with its own epitaxial registry, at very low growth rates and closely examine the dynamical scaling of the surface features during growth. Further, we apply analysis techniques such as power spectral density to the specific problem of thin film growth and roughness evolution to qualify the set of deposition conditions that lead to successful SRF coatings.

  18. Roughness analysis applied to niobium thin films grown on MgO(001 surfaces for superconducting radio frequency cavity applications

    Directory of Open Access Journals (Sweden)

    D. B. Beringer

    2013-02-01

    Full Text Available This paper describes surface studies to address roughness issues inherent to thin film coatings deposited onto superconducting radio frequency (SRF cavities. This is particularly relevant for multilayered thin film coatings that are being considered as a possible scheme to overcome technical issues and to surpass the fundamental limit of ∼50  MV/m accelerating gradient achievable with bulk niobium. In 2006, a model by Gurevich [Appl. Phys. Lett. 88, 012511 (2006APPLAB0003-695110.1063/1.2162264] was proposed to overcome this limit that involves coating superconducting layers separated by insulating ones onto the inner walls of the cavities. Thus, we have undertaken a systematic effort to understand the dynamic evolution of the Nb surface under specific deposition thin film conditions onto an insulating surface in order to explore the feasibility of the proposed model. We examine and compare the morphology from two distinct Nb/MgO series, each with its own epitaxial registry, at very low growth rates and closely examine the dynamical scaling of the surface features during growth. Further, we apply analysis techniques such as power spectral density to the specific problem of thin film growth and roughness evolution to qualify the set of deposition conditions that lead to successful SRF coatings.

  19. Roughness analysis applied to niobium thin films grown on MgO(001) surfaces for superconducting radio frequency cavity applications

    Energy Technology Data Exchange (ETDEWEB)

    Beringer, D. B. [College of William and Mary, Williamsburg, VA (United States). Dept. of Physics; Roach, W. M. [College of William and Mary, Williamsburg, VA (United States). Dept. of Applied Science; Clavero, C. [College of William and Mary, Williamsburg, VA (United States). Dept. of Applied Science; Reece, C. E. [Thomas Jefferson National Accelerator Facility (TJNAF), Newport News, VA (United States); Lukaszew, R. A. [College of William and Mary, Williamsburg, VA (United States). Dept. of Physics; College of William and Mary, Williamsburg, VA (United States). Dept. of Applied Science

    2013-02-05

    This paper describes surface studies to address roughness issues inherent to thin film coatings deposited onto superconducting radio frequency (SRF) cavities. This is particularly relevant for multilayered thin film coatings that are being considered as a possible scheme to overcome technical issues and to surpass the fundamental limit of ~500 MV/m accelerating gradient achievable with bulk niobium. In 2006, a model by Gurevich [ Appl. Phys. Lett. 88 012511 (2006)] was proposed to overcome this limit that involves coating superconducting layers separated by insulating ones onto the inner walls of the cavities. Thus, we have undertaken a systematic effort to understand the dynamic evolution of the Nb surface under specific deposition thin film conditions onto an insulating surface in order to explore the feasibility of the proposed model. We examine and compare the morphology from two distinct Nb/MgO series, each with its own epitaxial registry, at very low growth rates and closely examine the dynamical scaling of the surface features during growth. Further, we apply analysis techniques such as power spectral density to the specific problem of thin film growth and roughness evolution to qualify the set of deposition conditions that lead to successful SRF coatings.

  20. Quantification of oxygen and carbon in high Tc superconducting films by (α,α) elastic resonance technique

    International Nuclear Information System (INIS)

    Vizkelethy, G.; Revesz, P.

    1993-01-01

    The quantification of oxygen and carbon in high-temperature (T c ) superconducting oxide thin films was made by employing elastic resonance in He backscattering analysis. A method combining the oxygen resonance technique and channeling was presented for measuring the nature of the oxygen disorder near the surface and the interface in a YBCO superconducting film grown on an MgO substrate. The oxygen resonance technique was used to quantify the oxygen profiling in the metal/YBCO contacts, showing that Zr and Nb act as sinks to oxygen from YBCO films and are oxidized in the forms Zr/ZrO 2 /YBCO/MgO and Nb 0.2 O/YBCO/MgO after annealing in a vacuum at 350 o C. We combined the carbon and oxygen resonances to determine the carbon contamination and oxygen concentration changes on the YBCO surface after coating and baking the photoresist. Residual carbon on the surface and a thin layer of oxygen depletion near the YBCO surface have been observed. The residual carbon in Bi 2 Sr 2 CaCu 2 O 8 films made by the decomposition of metallo-organic precursors was quantified using carbon resonance. (author)

  1. Optimization of cathodic arc deposition and pulsed plasma melting techniques for growing smooth superconducting Pb photoemissive films for SRF injectors

    Science.gov (United States)

    Nietubyć, Robert; Lorkiewicz, Jerzy; Sekutowicz, Jacek; Smedley, John; Kosińska, Anna

    2018-05-01

    Superconducting photoinjectors have a potential to be the optimal solution for moderate and high current cw operating free electron lasers. For this application, a superconducting lead (Pb) cathode has been proposed to simplify the cathode integration into a 1.3 GHz, TESLA-type, 1.6-cell long purely superconducting gun cavity. In the proposed design, a lead film several micrometres thick is deposited onto a niobium plug attached to the cavity back wall. Traditional lead deposition techniques usually produce very non-uniform emission surfaces and often result in a poor adhesion of the layer. A pulsed plasma melting procedure reducing the non-uniformity of the lead photocathodes is presented. In order to determine the parameters optimal for this procedure, heat transfer from plasma to the film was first modelled to evaluate melting front penetration range and liquid state duration. The obtained results were verified by surface inspection of witness samples. The optimal procedure was used to prepare a photocathode plug, which was then tested in an electron gun. The quantum efficiency and the value of cavity quality factor have been found to satisfy the requirements for an injector of the European-XFEL facility.

  2. Vortex pinning vs superconducting wire network: origin of periodic oscillations induced by applied magnetic fields in superconducting films with arrays of nanomagnets

    International Nuclear Information System (INIS)

    Gomez, A; Del Valle, J; Gonzalez, E M; Vicent, J L; Chiliotte, C E; Carreira, S J; Bekeris, V; Prieto, J L; Schuller, Ivan K

    2014-01-01

    Hybrid magnetic arrays embedded in superconducting films are ideal systems to study the competition between different physical (such as the coherence length) and structural length scales such as are available in artificially produced structures. This interplay leads to oscillation in many magnetically dependent superconducting properties such as the critical currents, resistivity and magnetization. These effects are generally analyzed using two distinct models based on vortex pinning or wire network. In this work, we show that for magnetic dot arrays, as opposed to antidot (i.e. holes) arrays, vortex pinning is the main mechanism for field induced oscillations in resistance R(H), critical current I c (H), magnetization M(H) and ac-susceptibility χ ac (H) in a broad temperature range. Due to the coherence length divergence at T c , a crossover to wire network behaviour is experimentally found. While pinning occurs in a wide temperature range up to T c , wire network behaviour is only present in a very narrow temperature window close to T c . In this temperature interval, contributions from both mechanisms are operational but can be experimentally distinguished. (papers)

  3. Effect of processing conditions and methods on residual stress in CeO2 buffer layers and YBCO superconducting films

    International Nuclear Information System (INIS)

    Xiong Jie; Qin Wenfeng; Cui Xumei; Tao Bowan; Tang Jinlong; Li Yanrong

    2006-01-01

    CeO 2 layers have been fabricated by pulsed laser deposition (PLD) technique on (1 1 0 2) sapphire substrate. Microstructure of CeO 2 layers is characterized by X-ray diffraction as functions of substrate temperature. The effects of the substrate temperature on the residual stress have been studied. The results show that residual stress in CeO 2 film decreased with increasing substrate temperature, not the same development tendency as that of thermal stress. This means that the thermal stress is only a fraction of the residual stress. Moreover, YBCO superconducting films were prepared by direct current (DC) sputtering and pulsed laser deposition (PLD) technique. The residual stress and thermal stress of both YBCO films were measured. PLD processing apparently generated higher intrinsic compressive stresses in comparison to DC sputtering

  4. Electronic components with yttrium- and bismuth-based high-Tc superconductors

    International Nuclear Information System (INIS)

    Daginnus, M.; Guettler, B.

    1992-01-01

    This project investigates the fabrication of microwave components by use of high-Tc superconductors. Detailed descriptions are given of the manufacturing and use of active Y-Ba-Cu-O components. The surface resistance of thin films used in high-quality passive microwave components such as resonators and filters is measured and optimized. (orig./MM) [de

  5. Soft X-ray angle-resolved photoemission spectroscopy of heavily boron-doped superconducting diamond films

    Directory of Open Access Journals (Sweden)

    T. Yokoya, T. Nakamura, T. Matushita, T. Muro, H. Okazaki, M. Arita, K. Shimada, H. Namatame, M. Taniguchi, Y. Takano, M. Nagao, T. Takenouchi, H. Kawarada and T. Oguchi

    2006-01-01

    Full Text Available We have performed soft X-ray angle-resolved photoemission spectroscopy (SXARPES of microwave plasma-assisted chemical vapor deposition diamond films with different B concentrations in order to study the origin of the metallic behavior of superconducting diamond. SXARPES results clearly show valence band dispersions with a bandwidth of ~23 eV and with a top of the valence band at gamma point in the Brillouin zone, which are consistent with the calculated valence band dispersions of pure diamond. Boron concentration-dependent band dispersions near the Fermi level (EF exhibit a systematic shift of EF, indicating depopulation of electrons due to hole doping. These SXARPES results indicate that diamond bands retain for heavy boron doping and holes in the diamond band are responsible for the metallic states leading to superconductivity at low temperature. A high-resolution photoemission spectroscopy spectrum near EF of a heavily boron-doped diamond superconductor is also presented.

  6. Dopant rearrangement and superconductivity in Bi2Sr2-xLaxCuO6 thin films under annealing

    International Nuclear Information System (INIS)

    Cancellieri, C; Lin, P H; Ariosa, D; Pavuna, D

    2007-01-01

    By combining x-ray diffraction (XRD), x-ray photoemission spectroscopy (XPS) and AC susceptibility measurements we investigate the evolution of structural and superconducting properties of La-doped Bi-2201 thin films grown by pulsed laser deposition (PLD) under different annealing conditions. We find that the main effect of oxygen annealing is to improve the crystal coherence by enabling La cation migration to the Sr sites. This activates the desired hole doping. Short-time Ar annealing removes the interstitial oxygen between the BiO layers, fine adjusting the effective hole doping. The superconducting critical temperature is consequently enhanced. However, longer annealings result in phase separation and segregation of the homologous compound Bi-1201. We attribute this effect to the loss of Bi during the annealing

  7. Interaction of a laser beam with a target. Application to the fabrication of granular superconducting films

    International Nuclear Information System (INIS)

    Desserre, Jacques.

    1974-01-01

    The aim was to prepare a superconductor of high T(c). First are given the different simplified theories (BCS, Mac Millan) whereby the critical temperature of a superconductor can be calculated, with a view to its optimization. A material and a preparation technique were chosen on the basis of these theories. The method uses phenomena which occur during the interaction of a coherent pulsed light beam, emitted by a laser, with the surface of a metallic or nonmetallic target. Different theoretical models of this interaction are proposed. Special attention is paid to complex targets (alloys, compounds) and the construction of a model describing the vaporization of a compound is suggested. By a suitable choice of laser, based on the energy emission profile and the value of the energy supplied, congruent vaporization of the target is possible. The technique was applied to the preparation of thin layers by condensation onto a substrate of the vapor and the plasma emitted during the interaction. The deposits generally have the same structure as the bulk compound used as target while the atomic composition of the film may be slightly different. Thin layers of Ni 3 Mn, CdTe, ZnC, HfC were prepared in this way without treatment of the deposits after condensation. Simultaneous vaporization of the compound ReBe 22 in the bulk state gave filaments made up of small grains (20A), identical in composition with the target. The beryllium α phase (compact hexagonal) was identified but the electron diffraction study showed the existence of several other phases of unknown structure. The superconducting properties changed with time [fr

  8. Cation disorder and gas phase equilibrium in an YBa 2Cu 3O 7- x superconducting thin film

    Science.gov (United States)

    Shin, Dong Chan; Ki Park, Yong; Park, Jong-Chul; Kang, Suk-Joong L.; Yong Yoon, Duk

    1997-02-01

    YBa 2Cu 3O 7- x superconducting thin films have been grown by in situ off-axis rf sputtering with varying oxygen pressure, Ba/Y ratio in a target, and deposition temperature. With decreasing oxygen pressure, increasing Ba/Y ratio, increasing deposition temperature, the critical temperature of the thin films decreased and the c-axis length increased. The property change of films with the variation of deposition variables has been explained by a gas phase equilibrium of the oxidation reaction of Ba and Y. Applying Le Chatelier's principle to the oxidation reaction, we were able to predict the relation of deposition variables and the resultant properties of thin films; the prediction was in good agreement with the experimental results. From the relation between the three deposition variables and gas phase equilibrium, a 3-dimensional processing diagram was introduced. This diagram has shown that the optimum deposition condition of YBa 2Cu 3O 7- x thin films is not a fixed point but can be varied. The gas phase equilibrium can also be applied to the explanation of previous results that good quality films were obtained at low deposition temperature using active species, such as O, O 3, and O 2+.

  9. Growth of superconducting MgB2 films by pulsed-laser deposition using a Nd-YAG laser

    International Nuclear Information System (INIS)

    Badica, P; Togano, K; Awaji, S; Watanabe, K

    2006-01-01

    Thin films of MgB 2 on r-cut Al 2 O 3 substrates have been grown by pulsed-laser deposition (PLD) using a Nd-YAG laser (fourth harmonic-266 nm) instead of the popular KrF excimer laser. The growth window to obtain superconducting films is laser energy 350-450 mJ and vacuum pressure with Ar-buffer gas of 1-8/10 Pa (initial background vacuum 0.5-1 x 10 -3 Pa). Films were deposited at room temperature and post-annealed in situ and ex situ at temperatures of 500-780 0 C and up to 1 h. Films are randomly oriented with maximum critical temperature (offset of resistive transition) of 27 K. SEM/TEM/EDS investigations show that they are mainly composed of small sphere-like particles (≤20 nm), and contain oxygen and some carbon, uniformly distributed in the flat matrix, but the amount of Mg and/or oxygen is higher in the aggregates-droplets (100-1000 nm) observed on the surface of the film's matrix. Some aspects of the processing control and dependences on film characteristics are discussed. The technique is promising for future development of coated conductors

  10. Measurements of the surface impedance and the ac critical field of superconducting thin tin films at 10 GHz

    International Nuclear Information System (INIS)

    Spencer, G.L.

    1976-01-01

    The surface impedances and ac critical fields of superconducting thin tin films were studied. These experiments were performed using a superconducting frequency stabilized microwave cavity of high Q. Measurements of the power losses in the cavity and the center frequency of the cavity were used to determine the surface impedance and the critical field of a thin film sample placed in the cavity. In this case a theoretical treatment based on a model proposed by I.O. Kulik was used to fit the data. The general agreement between the modified Kulik treatment and the data, obtained in this experiment, was substantial. The second method was to modify the thin film data to correspond to a bulk situation. This modification was accomplished by taking into account the measuring techniques used and the geometric consideration inherent in the experiment. The comparison between the modified experimental data and calculations obtained from the Mattis-Bardeen bulk model was generally very good. One aspect of the results which was not explained was the presence of a slight increase in the surface resistance in the vicinity of the transition temperature. The critical field measurements were compared to the (1 - (T/T/sub c/)/sup 1/2) dependence predicted by Bardeen. If it is assumed that substantial microwave heating took place in the sample near T/sub c/, then remarkable agreement with the Bardeen model can be reached

  11. Two-dimensional superconducting state of monolayer Pb films grown on GaAs(110) in a strong parallel magnetic field.

    Science.gov (United States)

    Sekihara, Takayuki; Masutomi, Ryuichi; Okamoto, Tohru

    2013-08-02

    Two-dimensional (2D) superconductivity was studied by magnetotransport measurements on single-atomic-layer Pb films on a cleaved GaAs(110) surface. The superconducting transition temperature shows only a weak dependence on the parallel magnetic field up to 14T, which is higher than the Pauli paramagnetic limit. Furthermore, the perpendicular-magnetic-field dependence of the sheet resistance is almost independent of the presence of the parallel field component. These results are explained in terms of an inhomogeneous superconducting state predicted for 2D metals with a large Rashba spin splitting.

  12. Interface-enhanced high-temperature superconductivity in single-unit-cell FeT e1 -xS ex films on SrTi O3

    Science.gov (United States)

    Li, Fangsen; Ding, Hao; Tang, Chenjia; Peng, Junping; Zhang, Qinghua; Zhang, Wenhao; Zhou, Guanyu; Zhang, Ding; Song, Can-Li; He, Ke; Ji, Shuaihua; Chen, Xi; Gu, Lin; Wang, Lili; Ma, Xu-Cun; Xue, Qi-Kun

    2015-06-01

    Recently discovered high-temperature superconductivity in single-unit-cell (UC) FeSe films on SrTi O3 (STO) substrate has stimulated tremendous research interest, both experimental and theoretical. Whether this scenario could be extended to other superconductors is vital in both identifying the enhanced superconductivity mechanism and further raising the critical transition temperature (Tc). Here we successfully prepared single-UC FeT e1 -xS ex(0.1 ≤x ≤0.6 ) films on STO substrates by molecular beam epitaxy and observed U -shaped superconducting gaps (Δ ) up to ˜16.5 meV , nearly ten times the gap value (Δ ˜1.7 meV ) of the optimally doped bulk FeT e0 .6S e0 .4 single crystal (Tc˜14.5 K ). No superconducting gap has been observed on the second UC and thicker FeT e1 -xS ex films at 5.7 K, indicating the important role of the interface. This interface-enhanced high-temperature superconductivity is further confirmed by ex situ transport measurements, which revealed an onset superconducting transition temperature above 40 K, nearly two times higher than that of the optimally doped bulk FeT e0 .6S e0 .4 single crystal. This work demonstrates that interface engineering is a feasible way to discover alternative superconductors with higher Tc.

  13. Effects of high-energy proton irradiation on the superconducting properties of Fe(Se,Te) thin films

    Science.gov (United States)

    Sylva, G.; Bellingeri, E.; Ferdeghini, C.; Martinelli, A.; Pallecchi, I.; Pellegrino, L.; Putti, M.; Ghigo, G.; Gozzelino, L.; Torsello, D.; Grimaldi, G.; Leo, A.; Nigro, A.; Braccini, V.

    2018-05-01

    In this paper we explore the effects of 3.5 MeV proton irradiation on Fe(Se,Te) thin films grown on CaF2. In particular, we carry out an experimental investigation with different irradiation fluences up to 7.30 · 1016 cm‑2 and different proton implantation depths, in order to clarify whether and to what extent the critical current is enhanced or suppressed, what are the effects of irradiation on the critical temperature, resistivity, and critical magnetic fields, and finally what is the role played by the substrate in this context. We find that the effect of irradiation on superconducting properties is generally small compared to the case of other iron-based superconductors. The irradiation effect is more evident on the critical current density Jc, while it is minor on the transition temperature Tc, normal state resistivity ρ, and on the upper critical field Hc2 up to the highest fluences explored in this work. In more detail, our analysis shows that when protons implant in the substrate far from the superconducting film, the critical current can be enhanced up to 50% of the pristine value at 7 T and 12 K; meanwhile, there is no appreciable effect on critical temperature and critical fields together with a slight decrease in resistivity. On the contrary, when the implantation layer is closer to the film–substrate interface, both critical current and temperature show a decrease accompanied by an enhancement of the resistivity and lattice strain. This result evidences that possible modifications induced by irradiation in the substrate may affect the superconducting properties of the film via lattice strain. The robustness of the Fe(Se,Te) system to irradiation-induced damage makes it a promising compound for the fabrication of magnets in high-energy accelerators.

  14. Superconducting nanowire single photon detectors fabricated from an amorphous Mo0.75Ge0.25 thin film

    International Nuclear Information System (INIS)

    Verma, V. B.; Lita, A. E.; Vissers, M. R.; Marsili, F.; Pappas, D. P.; Mirin, R. P.; Nam, S. W.

    2014-01-01

    We present the characteristics of superconducting nanowire single photon detectors (SNSPDs) fabricated from amorphous Mo 0.75 Ge 0.25 thin-films. Fabricated devices show a saturation of the internal detection efficiency at temperatures below 1 K, with system dark count rates below 500 cps. Operation in a closed-cycle cryocooler at 2.5 K is possible with system detection efficiencies exceeding 20% for SNSPDs which have not been optimized for high detection efficiency. Jitter is observed to vary between 69 ps at 250 mK and 187 ps at 2.5 K using room temperature amplifiers.

  15. Structural and superconducting properties of epitaxial Fe{sub 1+y}Se{sub 1-x}Te{sub x} thin films

    Energy Technology Data Exchange (ETDEWEB)

    Richter, Stefan; Yuan, Feifei; Grinenko, Vadim; Huehne, Ruben [Institute for Metallic Materials, IFW Dresden (Germany); Sala, Alberto; Putti, Marina [Dipartimento di Fisica, Universita di Genova (Italy)

    2015-07-01

    The iron based superconductor Fe(Se,Te) is in the center of much ongoing research. The reason for this is on the one hand its simple crystal structure, that consists only of stacked Fe(Se,Te) layers so that structural and superconducting properties can be connected more easily, on the other hand FeSe itself shows a high sensibility for strain and changes in stoichiometry and can have potentially very high critical temperatures under hydrostatic pressure or in monolayers. We investigate epitaxial thin films of Fe{sub 1+y}Se{sub 1-x}Te{sub x} grown by pulsed laser deposition on different single crystalline substrates. A high crystalline quality and a superconducting transition of up to about 20 K can be achieved using optimized deposition parameters. The influence of growth conditions, Te-doping, film thickness and post growth oxygen treatment on the structural and superconducting properties on these films will be presented in detail.

  16. Magnetic field dependence of the superconducting proximity effect in a two atomic layer thin metallic film

    Energy Technology Data Exchange (ETDEWEB)

    Caminale, Michael; Leon Vanegas, Augusto A.; Stepniak, Agnieszka; Oka, Hirofumi; Fischer, Jeison A.; Sander, Dirk; Kirschner, Juergen [Max-Planck-Institut fuer Mikrostrukturphysik, Halle (Germany)

    2015-07-01

    The intriguing possibility to induce superconductivity in a metal, in direct contact with a superconductor, is under renewed interest for applications and for fundamental aspects. The underlying phenomenon is commonly known as proximity effect. In this work we exploit the high spatial resolution of scanning tunneling spectroscopy at sub-K temperatures and in magnetic fields. We probe the differential conductance along a line from a superconducting 9 ML high Pb nanoisland into the surrounding two layer thin Pb/Ag wetting layer on a Si(111) substrate. A gap in the differential conductance indicates superconductivity of the Pb island. We observe an induced gap in the wetting layer, which decays with increasing distance from the Pb island. This proximity length is 21 nm at 0.38 K and 0 T. We find a non-trivial dependence of the proximity length on magnetic field. Surprisingly, we find that the magnetic field does not affect the induced superconductivity up to 0.3 T. However, larger fields of 0.6 T suppress superconductivity in the wetting layer, where the Pb island still remains superconducting. We discuss the unexpected robustness of induced superconductivity in view of the high electronic diffusivity in the metallic wetting layer.

  17. Enhanced flux pinning properties in superconducting YBa{sub 2}Cu{sub 3}O{sub 7−z} films by a novel chemical doping approach

    Energy Technology Data Exchange (ETDEWEB)

    Wang, W.T., E-mail: wtwang@swjtu.edu.cn [Key Laboratory of Magnetic Levitation and Maglev Trains (Ministry of Education of China), Superconductivity R and D Center (SRDC), Southwest Jiaotong University, Mail Stop 165, Chengdu, Sichuan 610031 (China); Pu, M.H.; Lei, M.; Zhang, H.; Wang, Z. [Key Laboratory of Magnetic Levitation and Maglev Trains (Ministry of Education of China), Superconductivity R and D Center (SRDC), Southwest Jiaotong University, Mail Stop 165, Chengdu, Sichuan 610031 (China); Zhang, H. [Department of Physics, Peking University, Beijing 100871 (China); Cheng, C.H. [Key Laboratory of Magnetic Levitation and Maglev Trains (Ministry of Education of China), Superconductivity R and D Center (SRDC), Southwest Jiaotong University, Mail Stop 165, Chengdu, Sichuan 610031 (China); Superconductivity Research Group, School of Materials Science and Engineering, University of New South Wale, Sydney, 2052 NSW (Australia); Zhao, Y., E-mail: yzhao@swjtu.edu.cn [Key Laboratory of Magnetic Levitation and Maglev Trains (Ministry of Education of China), Superconductivity R and D Center (SRDC), Southwest Jiaotong University, Mail Stop 165, Chengdu, Sichuan 610031 (China); Superconductivity Research Group, School of Materials Science and Engineering, University of New South Wale, Sydney, 2052 NSW (Australia)

    2013-10-15

    Highlights: • Pure and Co-doped YBCO films were prepared by newly-developed chemical method. • The doped films have much denser and smoother surface microstructures. • Significantly enhanced fux-pinning properties have been obtained for dilute Co-doped flm. -- Abstract: Pure and cobalt-doped superconducting YBa{sub 2}Cu{sub 3}O{sub 7−z} (YBCO) films were prepared on (0 0 l) LaAlO{sub 3} substrate by a newly developed polymer-assisted metal organic deposition method. The cobalt-doped YBCO films display much denser and smoother surface microstructures and the superconducting transition temperature T{sub c} spans a small range of 1.7 K with the doping levels. Significantly enhanced flux-pinning properties have been obtained for dilute cobalt-doped film. This may be attributed to the good grain connections and the effective flux pinning centers introduced by cobalt doping.

  18. Enhanced flux pinning properties in superconducting YBa2Cu3O7−z films by a novel chemical doping approach

    International Nuclear Information System (INIS)

    Wang, W.T.; Pu, M.H.; Lei, M.; Zhang, H.; Wang, Z.; Zhang, H.; Cheng, C.H.; Zhao, Y.

    2013-01-01

    Highlights: • Pure and Co-doped YBCO films were prepared by newly-developed chemical method. • The doped films have much denser and smoother surface microstructures. • Significantly enhanced fux-pinning properties have been obtained for dilute Co-doped flm. -- Abstract: Pure and cobalt-doped superconducting YBa 2 Cu 3 O 7−z (YBCO) films were prepared on (0 0 l) LaAlO 3 substrate by a newly developed polymer-assisted metal organic deposition method. The cobalt-doped YBCO films display much denser and smoother surface microstructures and the superconducting transition temperature T c spans a small range of 1.7 K with the doping levels. Significantly enhanced flux-pinning properties have been obtained for dilute cobalt-doped film. This may be attributed to the good grain connections and the effective flux pinning centers introduced by cobalt doping

  19. Effects of α-particle beam irradiation on superconducting properties of thin film MgB2 superconductors

    Energy Technology Data Exchange (ETDEWEB)

    Kim, Sang Bum; Duong, Pham van; Ha, Dong Hyup; Oh, Young Hoon; Kang, Won Nam; Chai, Jong Seo [Sungkunkwan Univeversity, Suwon (Korea, Republic of); Hong, Seung Pyo; Kim, Ran Young [Kore Institute of Radiological and Medical Science, Seoul (Korea, Republic of)

    2016-06-15

    Superconducting properties of thin film MgB2 superconductors irradiated with 45 MeV α-particle beam were studied. After the irradiation, enhancement of the critical current density and pinning force was observed, scaling close to strong pinning formula. Double logarithmic plots of the maximum pinning force density with irreversible magnetic field show a power law behavior close to carbon-doped MgB2 film or polycrystals. Variation of normalized pinning force density in the reduced magnetic field suggests scaling formulas for strong pinning mechanism like planar defects. We also observed a rapid decay of critical current density as the vortex lattice constant decreases, due to the strong interaction between vortices and increasing magnetic field.

  20. Ion implantation in superconducting niobium and Nb3 Sn thin films: adjustment of Josephson microbridges and SQUID devices

    International Nuclear Information System (INIS)

    Robic, J.Y.; Piaguet, J.; Duret, D.; Veler, J.C.; Veran, J.L.; Zenatti, D.

    1978-01-01

    The principles of operation of Josephson junctions and SQUIDS are resumed. An ion implantation technique for the adjustment of the critical current is presented. High quality superconducting thin films were obtained by electron gun evaporation of niobium on heated substrates. Polycrystalline Nb 3 Sn was made by annealing (1000 K, 10 -6 Torr) a multilayer structure of successively evaporated niobium and thin films. Selected ions (helium, neon, argon) were implanted at doses ranging from 10 13 to 10 17 cm -2 . After implantation the critical temperature, the critical current and the normal resistivity were measured on special photoetched geometries. The variations of these electrical properties depend on the nuclear energy loss. The critical temperature of Nb 3 Sn is decreased by ion implantation and can be increased again by a new annealing. The parameters of the ion implantation were defined in order to obtain a critical temperature slightly higher than the operating temperature. The geometries of the microbridges and the implanted areas where then chosen to obtain appropriate criticals currents (approximately 10 μA) at the operating temperature. The obtained microbridges were used as junction elements in superconducting quantum interference devices (SQUID)

  1. Tunability of resonance frequencies in a superconducting microwave resonator by using SrTiO sub 3 ferroelectric films

    CERN Document Server

    Sok, J; Lee, E H

    1998-01-01

    An applied dc voltage varies the dielectric constant of ferroelectric SrTiO sub 3 films. A tuning mechanism for superconducting microwave resonators was realized by using the variation in the dielectric constant of SrTiO sub 3 films. In order to estimate the values of the capacitance, C, and the loss tangent, tan delta, of SrTiO sub 3 ferroelectric capacitors, we used high-temperature superconducting microwave resonators which were composed of two ports, two poles, and dc bias circuits at the zero-field points. SrTiO sub 3 ferroelectric capacitors successfully controlled the resonant frequency of the resonator. Resonant frequencies of 3.98 GHz and 4.20 GHz were measured at bias voltages of 0 V and 50 V which correspond to capacitance values of 0.94 pF and 0.7pF, respectively. The values of the loss tangent, tan delta sub e sub f sub f , obtained in this measurements, were about 0.01.

  2. Superconducting transistor

    International Nuclear Information System (INIS)

    Gray, K.E.

    1978-01-01

    A three film superconducting tunneling device, analogous to a semiconductor transistor, is presented, including a theoretical description and experimental results showing a current gain of four. Much larger current gains are shown to be feasible. Such a development is particularly interesting because of its novelty and the striking analogies with the semiconductor junction transistor

  3. The effects of H+ implants on YBa2Cu3O7 superconducting materials

    International Nuclear Information System (INIS)

    Luo Chenglin; Pan Guoqiang; Han Ming; Wang Guanghou

    1993-09-01

    The variations of microstructure and electrical properties of Y-Ba-Cu O with and without H + implantation have been studied by scanning electron microscope, X-ray diffraction and IR spectrum techniques. The results have shown that these variations are directly relative to the intrinsic quality of YBa 2 Cu 3 O 7 . Microstructural change is responsible for the variations of electrical properties of YBa 2 Cu 3 O 7 superconductor. The Cu H bond formed by H + implanted into YBa 2 Cu 3 O 7 is not a key factor for these variations

  4. Structural and superconducting characteristics of YBa2Cu3O7 films grown by fluorine-free metal-organic deposition route

    DEFF Research Database (Denmark)

    Zhao, Yue; Chu, Jingyuan; Qureishy, Thomas

    2018-01-01

    Microstructure and superconducting performance of YBa2Cu3O7 (YBCO) films deposited on LaAlO3 single crystal (LAO) substrates by a fluorine-free metal-organic deposition (FF-MOD) technique, have been studied by means of X-ray reciprocal space mapping (RSM), cross-sectional transmission electron mi...... external magnetic field at 77 K. This work offers an in-depth insight into the correlation between the microstructure and superconductivity in the MOD YBCO films.......Microstructure and superconducting performance of YBa2Cu3O7 (YBCO) films deposited on LaAlO3 single crystal (LAO) substrates by a fluorine-free metal-organic deposition (FF-MOD) technique, have been studied by means of X-ray reciprocal space mapping (RSM), cross-sectional transmission electron....... It is suggested that associated partial dislocations formed at the boundary between the stacking faults and YBCO matrix act as strong linear (or dot) pinning centers. These structural characteristics are well in line with the better superconducting performance of the low fluorine-MOD film, in particular under...

  5. Characterization of superconducting thin films deposited by laser ablation. Caracterisation de films minces supraconducteurs deposes par ablation laser

    Energy Technology Data Exchange (ETDEWEB)

    Sentis, M; Delaporte, P [I.M.F.M., 13 - Marseille (FR); Gerri, M; Marine, W [Aix-Marseille-2 Univ., 13-Marseille (FR). Centre Universitaire de Luminy

    1991-05-01

    Thin films of YBa{sub 2}Cu{sub 3}O{sub 7} are deposited by laser ablation on MgO and YSZ substrates. Deposits by infrared (I.R.) Nd: YAG are non stoechiometric. The films having the best superconductor qualities are deposited by ablation with an excimer U.V. laser ({lambda} = 308 nm). These films are epitaxiated with the c axis perpendicular to the substrate. The film quality depends on the substrate temperature, oxygen pressure and cooling speed.

  6. Growth and characterization of high-Tc Y1Ba2Cu3O7-x superconducting thin films by chemical vapor deposition

    International Nuclear Information System (INIS)

    Feng, A.

    1992-01-01

    In chapter I, the current status of high-Tc superconductors (especially Y 1 Ba 2 Cu 3 O 7-x ), their microstructures and their unique physical properties are reviewed. An introduction to the potential and importance of those high-Tc superconductors in practical applications, especially for the application of YBCO thin films in microelectronics, is given. A general description of the common YBCO thin film fabrication and characterization techniques is also presented in this first chapter. Chapter II describes a new CVD process, temperature-controlled chemical vapor deposition (TC-CVD) for the growth of YBCO superconducting thin films on substrates of practical importance, such as sapphire (Al 2 O 3 ) and on substrates of lattice matched perovskite-type single crystals, such as LaAlO 3 . In order to verify the viability of this new CVD process the qualities of YBCO superconducting thin films were examined by various characterization methods, such as resistivity vs. temperature (R vs. T), scanning electron microscopy (SEM), X-ray diffraction (XRD), and magnetic susceptibility (x) measurements. Chapter III deals with the effect of substrate temperature on the properties of YBCO thin films made by TC-CVD. The principle objective of this study is to raise the transition temperature and critical current densities of CVD YBCO superconducting thin films. Understanding the relations between YBCO film growth process and varying substrate temperatures proved to be crucial in reaching this goal. The authors present the characterization results of YBCO thin films produced by different temperature schemes, to illustrate the importance of varying substrate temperature during the film growth. In chapter IV, the Rutherford backscattering (RBS) channeling technique is described. They have used RBS channeling to characterize the epitaxial YBCO thin film's crystallinity and lattice alignment. Transmission electron microscopy studies are also included

  7. Superconductive B-doped nanocrystalline diamond thin films: Electrical transport and Raman spectra

    Czech Academy of Sciences Publication Activity Database

    Nesládek, M.; Tromson, D.; Mer, Ch.; Bergonzo, P.; Hubík, Pavel; Mareš, Jiří J.

    2006-01-01

    Roč. 88, č. 23 (2006), 232111/1-232111/3 ISSN 0003-6951 R&D Projects: GA ČR(CZ) GA202/06/0040 Institutional research plan: CEZ:AV0Z10100521 Keywords : nanocrystalline diamond * superconductivity * magnetoresistance * Raman spectroscopy * Fano resonance Subject RIV: BM - Solid Matter Physics ; Magnetism Impact factor: 3.977, year: 2006

  8. Far-infrared transmission of a superconducting NbN film

    Czech Academy of Sciences Publication Activity Database

    Šindler, M.; Tesař, Roman; Koláček, Jan; Skrbek, L.; Šimša, Zdeněk

    2010-01-01

    Roč. 81, č. 18 (2010), 184529/1-184529/5 ISSN 1098-0121 R&D Projects: GA ČR GA202/08/0326 Institutional research plan: CEZ:AV0Z10100521 Keywords : superconductivity * BCS theory * terahertz radiation Subject RIV: BM - Solid Matter Physics ; Magnetism Impact factor: 3.772, year: 2010

  9. Energy band theory of heterometal superposed film and relevant comments on superconductivity in heterometal systems

    International Nuclear Information System (INIS)

    Zhang, L.; Yin, D.

    1981-08-01

    A method for calculating the electronic structure of a heterogeneous metal-metal interface is discussed. It combines a series of well-defined interface plane-wave orbitals and the muffin-tin orbitals. The problem of high-Tsub(c) superconductivity in systems containing metal-metal interfaces and the related problem in compounds is addressed

  10. Role of grain size in superconducting boron-doped nanocrystalline diamond thin films grown by CVD

    Czech Academy of Sciences Publication Activity Database

    Zhang, G.; Janssens, S.D.; Vanacken, J.; Timmermans, M.; Vacík, Jiří; Ataklti, G.W.; Decelle, W.; Gillijns, W.; Goderis, B.; Haenen, K.; Wagner, P.; Moshchalkov, V.V.

    2011-01-01

    Roč. 84, č. 21 (2011), 214517/1-214517/10 ISSN 1098-0121 Institutional research plan: CEZ:AV0Z10480505 Keywords : Nanocrystalline diamond * Superconducting transition Subject RIV: BM - Solid Matter Physics ; Magnetism Impact factor: 3.691, year: 2011

  11. The HIE-ISOLDE Superconducting Cavities: Surface Treatment and Niobium Thin Film Coating

    CERN Document Server

    Lanza, G; Ferreira, L M A; Gustafsson, A E; Pasini, M; Trilhe, P; Palmieri, V

    2010-01-01

    CERN has designed and prepared new facilities for the surface treatment and niobium sputter coating of the HIE-ISOLDE superconducting cavities. We describe here the design choices, as well as the results of the first surface treatments and test coatings.

  12. Observation of weak superconductivity in electrons localized on a film surface

    International Nuclear Information System (INIS)

    Fogel', N.Y.; Kolin'ko, A.E.

    1984-01-01

    We have observed anomalous abrupt resistance changes in thick vanadium films [d>>xi(T)]. We have also observed a number of anomalies in the H--T phase diagrams for these films; these anomalies are most clearly seen when the field is parallel to, or at low angles of incidence with respect to, the film surface. We explain our results by assuming that there are two different electron systems present in the film. One of them is composed of electrons localized near a natural planar defect, the film surface. This subsystem is characterized by extremely small values of the critical current

  13. Exploring the performance of thin-film superconducting multilayers as kinetic inductance detectors for low-frequency detection

    Science.gov (United States)

    Zhao, Songyuan; Goldie, D. J.; Withington, S.; Thomas, C. N.

    2018-01-01

    We have solved numerically the diffusive Usadel equations that describe the spatially varying superconducting proximity effect in Ti-Al thin-film bi- and trilayers with thickness values that are suitable for kinetic inductance detectors (KIDs) to operate as photon detectors with detection thresholds in the frequency range of 50-90 GHz. Using Nam’s extension of the Mattis-Bardeen calculation of the superconductor complex conductivity, we show how to calculate the surface impedance for the spatially varying case, and hence the surface impedance quality factor. In addition, we calculate energy-and spatially-averaged quasiparticle lifetimes at temperatures well-below the transition temperature and compare to calculation in Al. Our results for the pair-breaking threshold demonstrate differences between bilayers and trilayers with the same total film thicknesses. We also predict high quality factors and long multilayer-averaged quasiparticle recombination times compared to thin-film Al. Our calculations give a route for designing KIDs to operate in this scientifically-important frequency regime.

  14. Lanthanide gallate perovskite-type substrates for epitaxial, high-Tc superconducting Ba2YCu3O7-δ films

    International Nuclear Information System (INIS)

    Giess, E.A.; Sandstrom, R.L.; Gallagher, W.J.; Gupta, A.; Shinde, S.L.; Cook, R.F.; Cooper, E.L.; O'Sullivan, E.M.J.; Roldan, J.M.; Segmuller, A.D.; Angilello, J.

    1990-01-01

    This paper reports on the use of lanthanide gallate perovskite-type substrates for the deposition of epitaxial, high-T c superconducting Ba 2 YCu 3 O 7-δ (BYCO) films. They were also found to have moderate dielectric constants (∼25 compared to ∼ 277 for SrTiO 3 ). This study was undertaken to further explore the use of LaGaO 3 , NdGaO 3 , SrTiO 3 , MgO, and Y-stabilized ZrO 2 substrates, prepared from single-crystal joules grown by several suppliers using the Czochralski method. Films were prepared by cylindrical magnetron sputtering and laser ablation. Substrate evaluations included measurement of dielectric constant and loss, thermal expansion, and mechanical hardness and toughness. In addition to their moderate dielectric constants, they were found to have satisfactory mechanical properties, except for the twinning tendency of LaGaO 3 . Lattice mismatch strains were calculated for orthorhombic BYCO films on a number of substrates. NdGaO 3 was found to have the best lattice match with BYCO, and is now available twin-free

  15. Anisotrophic currents and flux jumps in high-Tc superconducting films with self-organized arrays of planar defects

    International Nuclear Information System (INIS)

    Yurchenko, V.V.; Qviller, A.J.; Mozhaev, P.B.; Mozhaeva, J.E.; Hansen, J.B.; Jacobsen, C.S.; Kotelyanskii, I.M.; Pan, A.V.; Johansen, T.H.

    2010-01-01

    Regular arrays of planar defects with a period of a few nanometers can be introduced in superconducting YBa 2 Cu 3 O 7-δ (YBCO) thin films by depositing them on vicinal (also called miscut or tilted) substrates. This results in the anisotropy of critical currents flowing in the plane of the film. We present results of real-time magneto-optical imaging (MOI) of magnetic flux distribution and dynamics in a series of YBCO thin films deposited on NdGaO 3 substrates with different miscut angles θ. MOI allows reconstructing the current flow profiles. From the angle formed between domains with different directions of the current flow we determine the anisotropy parameter of the in-plane current, as well as its field and temperature dependences. The artificially introduced defects also have a dramatic effect on the dynamics of the flux propagation: for 10 o o the magnetic flux propagates along the easy channels intermittently, i.e. in a form of flux jumps. This behavior is indicative of thermo-magnetic instability in superconductors, but we argue that this effect can be of a different nature.

  16. Crystallinity and superconductivity of as-grown MgB2 thin films with AlN buffer layers

    International Nuclear Information System (INIS)

    Tsujimoto, K.; Shimakage, H.; Wang, Z.; Kaya, N.

    2005-01-01

    The effects of aluminum nitride (AlN) buffer layers on the superconducting properties of MgB 2 thin film were investigated. The AlN buffer layers and as-grown MgB 2 thin films were deposited in situ using the multiple-target sputtering system. The best depositing condition for the AlN/MgB 2 bi-layer occurred when the AlN was deposited on c-cut sapphire substrates at 290 deg. C. The crystallinity of the AlN/MgB 2 bi-layer was studied using the XRD φ-scan and it showed that AlN and MgB 2 had the same in-plane alignment rotated at an angle of 30 deg. as compared to c-cut sapphire. The critical temperature of the MgB 2 film was 29.8 K and the resistivity was 50.0 μΩ cm at 40 K

  17. Effect of substituted rare earth element in (Yb1-xNd x)Ba2Cu3O y thin film on growth orientation and superconducting properties

    International Nuclear Information System (INIS)

    Honda, R.; Ichino, Y.; Yoshida, Y.; Takai, Y.; Matsumoto, K.; Ichinose, A.; Kita, R.; Mukaida, M.; Horii, S.

    2005-01-01

    We studied the orientation and superconducting properties in (Yb 1-x Nd x )Ba 2 Cu 3 O y (Yb/Nd123) thin films as a function of Yb/Nd composition ratio x. As a results, we needed so high oxygen pressure as to increase x for obtaining the c-axis oriented films. J c -B curves in the Yb/Nd123 thin films were superior to that in YBa 2 Cu 3 O y thin film. Since a RE fluctuation in a composition in the Yb/Nd123 thin films was observed with TEM-EDX, we speculated the pinning centers in the Yb/Nd123 thin films were strongly affected by the RE fluctuation

  18. Growth orientation and superconducting properties of YBa2Cu3O7-δ films prepared by the low-fluorine sol-gel process

    International Nuclear Information System (INIS)

    Lei Li; Zhao Gaoyang; Xu Hui; Zhao Juanjuan

    2010-01-01

    YBa 2 Cu 3 O 7-δ (YBCO) films were deposited on (100)-oriented LaAlO 3 (LAO) single crystal substrates by the dip-coating process using low-fluorine solution. Their microstructures were characterized with the aid of X-ray diffractometry, scanning electron microscopy and high-resolution transmission electron microscopy. Their superconducting properties were measured by the standard four-probe method. The experiment results show that the film obtained under high enough humidity conditions exhibits better c-axis texture and superconducting properties than the film under a relatively low humidity conditions. Based on the classical nucleation and chemical reaction thermodynamics theory, the underlying crystalline and growth mechanisms of YBCO films under certain humidity conditions are explained in combination with our experimental results. It is suggested that the unreacted intermediate phases such as BaF 2 and CuO aggregated in the YBCO grain boundary will cause lattice distortion in the YBCO matrix and further induce the formation of a-axis oriented YBCO grains as crystallization proceeds. Therefore, it is believed that the relative content of water vapor within the heat-treatment atmosphere plays quite an important role in the preparation of c-axis oriented YBCO film with good superconducting properties. (semiconductor materials)

  19. Anisotropic response of the moving vortex lattice in superconducting Mo{sub (1-x)}Ge{sub x} amorphous films

    Energy Technology Data Exchange (ETDEWEB)

    Dolz, M.I., E-mail: mdolz@unsl.edu.ar [Centro Atomico Bariloche, CONICET, San Carlos de Bariloche, R8402AGP Rio Negro (Argentina); Shalom, D.E.; Pastoriza, H. [Centro Atomico Bariloche, CONICET, San Carlos de Bariloche, R8402AGP Rio Negro (Argentina); Lopez, D.O. [Center for Nanoscale Materials, Argonne National Laboratory, 9700 South Cass Av., Argonne, IL 60439 (United States)

    2012-03-15

    We have performed magnetic susceptibility measurements in Mo{sub 1-x}Ge{sub x} amorphous thin films biased with an electrical current using anisotropic coils. We tested the symmetry of the vortex response changing the relative orientation between the bias current and the susceptibility coils. We found a region in the DC current-temperature phase diagram where the dynamical vortex structures behave anisotropically. In this region the shielding capability of the superconducting currents measured by the susceptibility coils is less effective along the direction of vortex motion compared to the transverse direction. This anisotropic response is found in the same region where the peak effect in the critical current is developed. On rising temperature the isotropic behavior is recovered.

  20. High field properties of superconducting BaFe{sub 2-x}Ni{sub x}As{sub 2} thin films

    Energy Technology Data Exchange (ETDEWEB)

    Richter, Stefan [Institute for Metallic Materials, IFW Dresden (Germany); Technical University Dresden (Germany); Kurth, Fritz; Grinenko, Vadim; Nielsch, Kornelius; Huehne, Ruben [Institute for Metallic Materials, IFW Dresden (Germany); Iida, Kazumasa [Nagoya University (Japan); Pervakov, Kirill [Russian Academy of Sciences (Russian Federation); Tarantini, Chiara; Jaroszynski, Jan [National High Magnetic Field Laboratory (United States); Pukenas, Aurimas; Skrotzki, Werner [Technical University Dresden (Germany)

    2016-07-01

    Fe based superconductors combine the advantages of cuprates (high upper critical field) with the small Hc{sub 2} anisotropy of classic low temperature superconductors, which makes them suitable candidates for high field applications. The study of Fe-based superconducting thin films is one crucial step to explore this potential in more detail. We present results for epitaxial BaFe{sub 2-x}Ni{sub x}As{sub 2} thin films, which have been successfully grown for the first time using pulsed laser deposition. Superconducting transition temperatures of up to 19 K have been realized in slightly overdoped films, which is in good agreement with results obtained for single crystals. The behavior of the upper critical field and critical current density has been measured in high magnetic fields up to 35 T. The results will be correlated to the observed microstructure and compared to high field data for single crystals with similar composition.

  1. The impedance of inductive superconducting fault current limiters operating with stacks of thin film Y123/Au washers or bulk Bi2223 rings as secondaries

    International Nuclear Information System (INIS)

    Fernandez, J A Lorenzo; Osorio, M R; Toimil, P; Ferro, G; Blanch, M; Veira, J A; Vidal, F

    2006-01-01

    Inductive fault current limiters operating with stacks of various small superconducting elements acting as secondaries were studied. The stacks consist of Y 1 Ba 2 Cu 3 O 7-δ thin film washers or Bi 1.8 Pb 0.26 Sr 2 Ca 2 Cu 3 O 10+x bulk rings. A central result of our work is an experimental demonstration that the limiting capability of the device is strongly reduced when several bulk rings are stacked, whereas it remains almost unchanged for thin film washers. The use of thin films should therefore allow us to build more efficient high power inductive limiters based on stacks of small washers

  2. Preparation of high quality superconducting thin MgB2 films for electronics

    International Nuclear Information System (INIS)

    Surdu, Andrei; Zdravkov, Vladimir; Sidorenko, Anatolie; Rossolenko, Anna; Ryazanov, Valerii; Bdikin, Igor; Kroemer, Oliver; Nold, Eberhard; Koch, Thomas; Schimmel, Thomas

    2007-01-01

    In this work we report the growth of high-Tc MgB 2 smooth films which are prepared in a two-step process: 1) deposition of the precursor films and 2) their annealing in Mg vapor with a specially designed, reusable reactor. Our method opens perspectives for the use of MgB 2 films in microelectronics, especially for high-frequency applications. (authors)

  3. First-Principles Study of Superconductivity in Ultra- thin Pb Films

    Science.gov (United States)

    Noffsinger, Jesse; Cohen, Marvin L.

    2010-03-01

    Recently, superconductivity in ultrathin layered Pb has been confirmed in samples with as few as two atomic layers [S. Qin, J. Kim, Q. Niu, and C.-K. Shih, Science 2009]. Interestingly, the prototypical strong-coupling superconductor exhibits different Tc's for differing surface reconstructions in samples with only two monolayers. Additionally, Tc is seen to oscillate as the number of atomic layers is increased. Using first principles techniques based on Wannier functions, we analyze the electronic structure, lattice dynamics and electron-phonon coupling for varying thicknesses and surface reconstructions of layered Pb. We discuss results as they relate to superconductivity in the bulk, for which accurate calculations of superconducting properties can be compared to experiment [W. L. McMillan and J.M. Rowell, PRL 1965]. This work was supported by National Science Foundation Grant No. DMR07-05941, the U.S. Department of Energy under Contract No. DE-AC02-05CH11231. Computational resources have been provided by the Lawrencium computational cluster resource provided by the IT Division at the Lawrence Berkeley National Laboratory (Supported by the Director, Office of Science, Office of Basic Energy Sciences, of the U.S. Department of Energy under Contract No. DE-AC02-05CH11231)

  4. Effect of substrate on excess electrical conductivity in thin superconducting lead films above the transition temperature

    Energy Technology Data Exchange (ETDEWEB)

    Ashwini Kumar, P K

    1976-03-01

    Measurements were made on Pb films grown directly on to glass and Pb films grown on glass precoated with LiF to investigate the effect of the substrate on thermodynamic fluctuations of Cooper pairs. A change in the substrate appears to alter the strength of the pair breaking mechanism. 17 references.

  5. Measurement setup for the magnetic penetration depth and superfluid stiffness in thin superconducting films

    Energy Technology Data Exchange (ETDEWEB)

    Fuchs, Lorenz; Brunner, Markus Christopher Paul; Schneider, Ina; Kronfeldner, Klaus; Strunk, Christoph [Institute for exp. and appl. Physics, University of Regensburg (Germany); Bousquet, Jessica; Bustarret, Etienne [Institut NEEL, Grenoble (France)

    2015-07-01

    A mutual inductance measurement setup has been established in order to determine the magnetic penetration depths of thin film superconductors. By measuring the variation of the mutual inductance M, the temperature dependent penetration depth can be evaluated. The setup has been characterized using thin aluminum and niobium films as a reference. Temperature dependence of λ of B-doped diamond films is determined down to 0.3 K and compared with theoretical expectations. The impact of the doping ratio B/C and film thickness on λ and T{sub c} is investigated. Correlation between the film impedance σ = σ{sub 1} - i σ{sub 2} and λ is examined.

  6. Bulk and thick films of the superconducting phase YBa2Cu3O7/sub -//sub y/ made by controlled precipitation and sol-gel processes

    International Nuclear Information System (INIS)

    Barboux, P.; Tarascon, J.M.; Greene, L.H.; Hull, G.W.; Bagley, B.G.

    1988-01-01

    The synthesis of high-temperature superconducting oxides using solution chemistry has been investigated and physical properties are compared to ceramics obtained by conventional solid-state reactions. We report on controlled precipitation and sol-gel processes, both of which produce materials with particle sizes smaller than 5 μm. We find that the superconducting properties of the high T/sub c/ ceramics are affected by their manner of preparation, such that the transitions are slightly lower in temperature, but sharper, for samples made by solution rather than solid-state chemistry. The ability to prepare stable viscous gels provides an opportunity for obtaining large areas of superconducting coatings. For thick films on alumina or silicon substrates, contamination from the substrate is shown to be a problem. Finally, we observe that the sol-gel process lowers the synthesis temperature by 100 0 C.ing,

  7. Incorporation of self-organised gold nano crystals in YBa{sub 2}Cu{sub 3}O{sub 7-{delta}} thin films: Modification of superconducting properties

    Energy Technology Data Exchange (ETDEWEB)

    Katzer, Christian; Michalowski, Peter; Westerhausen, Markus; Koch, Stefanie; Schmidl, Frank; Seidel, Paul [Institut fuer Festkoerperphysik, Friedrich-Schiller-Universitaet Jena, Helmholtzweg 5, 07743 Jena (Germany); Treiber, Sebastian [Max-Planck-Institut fuer Intelligente Systeme, Heisenbergstrasse 3, 70569 Stuttgart (Germany); Albrecht, Joachim [Hochschule Aalen, Beethovenstrasse 1, 73430 Aalen (Germany)

    2012-07-01

    Using pulsed laser deposition we are able to fabricate and examine Yttrium-Barium-Copper-Oxide (YBCO) thin films of high quality. A particular point of interest thereby is the influence of a pre-deposited gold layer with a well-defined film thickness. During the growth of the YBCO thin film the intermediate gold layer self assembles into crystalline nano particles, which modify the growth conditions and hence the physical properties of the growing YBCO. We report on the modification of structural and superconducting properties of our YBCO thin films (such as rocking curve widths, critical temperature T{sub c} and critical current density j{sub c}) comparing conventional to Au added YBCO. The temperature dependence of the critical current density thereby was determined using transport measurements as well as magneto-optical measurements. Furthermore investigations of the flux noise of our gold modified YBCO films are presented.

  8. Magnetic resonance in spin glasses, superconductivity of thin aluminum films and models for transport properties of one dimensional systems

    International Nuclear Information System (INIS)

    Elliott, J.H.

    1983-01-01

    This thesis reports on three separate investigations in solid state physics. The first is electron paramagnetic resonance in the spin glass Ag:Mn. EPR measurements were performed at two resonance frequencies, concentrating on temperatures above the glass transition temperature. The measured linewidth appears to diverge at T/sub g/ for low resonance frequencies. These results will be compared with recently proposed phenomenological and microscopic theories. The second topic reported in this thesis is the superconducting transition of thin aluminum films. These films were investigated as a function of grain size and thickness. The transition temperature was enhanced over the bulk value, in agreement with many previous investigations of granular aluminum. The third topic reported in this thesis is an extension of the variable rate hopping theory applied in one dimension to N-ME-Qn(TCNQ) 2 . This model is a classical one used to explain both the dc and ac electrical conductivity of organic conductors. The temperature dependence of the model does not agree with experiment at low temperatures. Tunneling has been added to the hopping. This increases the conductivity at low temperatures, and results in excellent agreement with the experimental conductivity over the measured temperature range. The model also predicts that the frequency dependence of the conductivity varies as ω/sup .5/ at low frequencies. This long time tail prediction agrees with the measured dielectric constant of N-Me-iso-Qn(TCNQ) 2

  9. Thin-film superconducting rings in the critical state: the mixed boundary value approach

    Science.gov (United States)

    Brambilla, Roberto; Grilli, Francesco

    2015-02-01

    In this paper, we describe the critical state of a thin superconducting ring (and of a perfectly conducting ring as a limiting case) as a mixed boundary value problem. The disc is characterized by a three-part boundary division of the positive real axis, so this work is an extension of the procedure used in a previous work of ours for describing superconducting discs and strips, which are characterized by a two-part boundary division of the real axis. Here, we present the mathematical tools to solve this kind of problems—the Erdélyi-Kober operators—in a frame that can be immediately used. Contrary to the two-part problems considered in our previous work, three-part problems do not generally have analytical solutions and the numerical work takes on a significant heaviness. Nevertheless, this work is remunerated by three clear advantages: firstly, all the cases are afforded in the same way, without the necessity of any brilliant invention or ability; secondly, in the case of superconducting rings, the penetration of the magnetic field in the internal/external rims is a result of the method itself and does not have to be imposed, as it is commonly done with other methods presented in the literature; thirdly, the method can be extended to investigate even more complex cases (four-part problems). In this paper, we consider the cases of rings in uniform field and with transport current, with or without flux trapping in the hole and the case without net current, corresponding to a cut ring (washer), as used in some SQUID applications.

  10. Magnetic field and temperature dependence of the critical vortex velocity in type-II superconducting films

    Energy Technology Data Exchange (ETDEWEB)

    Grimaldi, G; Leo, A; Cirillo, C; Attanasio, C; Nigro, A; Pace, S [CNR-INFM Laboratorio Regionale SuperMat, Via Salvador Allende, I-84081 Baronissi (Italy)], E-mail: grimaldi@sa.infn.it

    2009-06-24

    We study the vortex dynamics in the instability regime induced by high dissipative states well above the critical current in Nb superconducting strips. The magnetic field and temperature behavior of the critical vortex velocity corresponding to the observed dynamic instability is ascribed to intrinsic non-equilibrium phenomena. The Larkin-Ovchinnikov (LO) theory of electronic instability in high velocity vortex motion has been applied to interpret the temperature dependence of the critical vortex velocity. The magnetic field dependence of the vortex critical velocity shows new features in the low-field regime not predicted by LO.

  11. Determination of the magnetic penetration depth in a superconducting Pb film

    International Nuclear Information System (INIS)

    Brisbois, J.; Silhanek, A. V.; Raes, B.; Van de Vondel, J.; Moshchalkov, V. V.

    2014-01-01

    By means of scanning Hall probe microscopy technique, we accurately map the magnetic field pattern produced by Meissner screening currents in a thin superconducting Pb stripe. The obtained field profile allows us to quantitatively estimate the Pearl length Λ without the need of pre-calibrating the Hall sensor. This fact contrasts with the information acquired through the spatial field dependence of an individual flux quantum where the scanning height and the magnetic penetration depth combine in a single inseparable parameter. The derived London penetration depth λ L coincides with the values previously reported for bulk Pb once the kinetic suppression of the order parameter is properly taken into account

  12. Transport measurements on superconducting YBa2Cu3O7-δ thin film lines

    International Nuclear Information System (INIS)

    Moeckly, B.H.; Lathrop, D.K.; Redinbo, G.F.; Russek, S.E.; Buhrman, R.A.

    1990-01-01

    Critical current densities, magnetic field response, and microwave response have been measured for laser ablated YBa 2 Cu 3 O 7-δ thin film lines on MgO and SrTiO 3 substrates. Films on SrTiO 3 have critical current densities > 1 x 10 6 A/cm 2 at 77 K and show uniform transport properties in lines of all sizes. Films on MgO have critical current densities which range between 10 2 and 10 6 A/cm 2 at 77 K and show considerable variation from device to device on the same chip. Narrow lines on MgO with low critical current densities show Josephson weak link structure which includes RSJ-like IV curves, microwave induced constant voltage steps, and a high sensitivity to magnetic field. The presence of the Josephson weak links if correlated with small amounts of misaligned grains in film on MgO

  13. Robust control problems of vortex dynamics in superconducting films with Ginzburg-Landau complex systems

    OpenAIRE

    Belmiloudi, Aziz

    2006-01-01

    We formulate and study robust control problems for a two-dimensional time-dependent Ginzburg-Landau model with Robin boundary conditions on phase-field parameter, which describes the phase transitions taking place in superconductor films with variable thickness. The objective of such study is to control the motion of vortices in the superconductor films by taking into account the influence of noises in data. Firstly, we introduce the perturbation problem of the nonlinear ...

  14. Magnetic study of superconductivity in YBa2Cu3O7-x thin films

    International Nuclear Information System (INIS)

    McGuire, T.R.; Gupta, A.; Koren, G.; Laibowitz, R.B.; Dimos, D.

    1989-01-01

    Magnetic and transport measurements on 0.3 micron thick films of YBa 2 Cu 3 O 7 - x made by a laser ablation technique show critical current densities of up to 40X10 6 amps/cm 2 . At 77K the transport data gives J c ∼5x10 6 amps/cm 2 while magnetic data is 40 % lower. Comparison is made with evaporated films

  15. Analysis of transmittance properties in 1D hybrid dielectric photonic crystal containing superconducting thin films

    Science.gov (United States)

    Soltani, Osswa; Zaghdoudi, Jihene; Kanzari, Mounir

    2018-06-01

    By means of two fluid model and transfer matrix method (TMM), we investigate theoretically the transmittance properties of a defective hybrid dielectric-dielectric photonic crystal that contains a superconducting material as a defect layer. The considered hybrid photonic structure is: H(LH) 7(HLSLH) P H(LH) 7 , where H is the high refractive index dielectric, L is the low refractive index dielectric, S is the superconducting material and P is the repetitive number. The results show that the variation of the number and the positions of the transmissions modes depend strongly on the repetitive number P, the temperature T and the thickness of the layer S. An improvement of the spectral response is obtained with the exponential gradation of layer thicknesses dj =d0 + βejα , where d0 is the initial thickness of the layer j, α and β are two particular constants for each material. In addition, the effect of the incident angle for both transverse electric (TE) and transverse magnetic (TM) polarizations on the transmittance spectrum is discussed. As a result, we propose a tunable narrow stop-band polychromatic filter that covers the visible wavelength.

  16. Superconducting spin valves based on epitaxial Fe/V-hybrid thin film heterostructures

    Energy Technology Data Exchange (ETDEWEB)

    Nowak, Gregor

    2010-12-10

    This study presents a systematic investigation of the SSV effect in FM/SC/FM and FM/N/FM/SC heterostructures. Before investigating the actual SSV effect, we first pre-analyzed structural, magnetic and superconducting properties of the Fe/V system. In these preliminary studies we demonstrated, that epitaxial Fe/V heterostructures of superior crystalline quality can be grown by DC sputter deposition. With a Fe/V interface thickness of only one monolayer, the chemical separation of the Fe and V layers is extremely sharp. Moreover, the magnetic investigation showed that from thicknesses of two Fe(001) monolayers on the Fe layers in the superlattice possess a magnetic moment. Furthermore, we demonstrated the interlayer exchange coupling as oscillatory function of the V interlayer thickness. The investigations of the superconducting parameters of the Fe/V system revealed a non-monotonic T{sub S} vs. d{sub Fe} dependence in sample series (1). This observation proves the presence of the FM/SC proximity effect. The studies of various heterostructures of the design AFM/FM/SC/FM revealed a strong counteracting influence on the SSV effect, the stray field effect. The sample containing Fe{sub 25}V{sub 75} alloy layers, has the highest ratio of Cooper pair coherence length and superconductor thickness (ξ{sub S})/(d{sub S}), and its superconducting transition temperature is comparable to the sample with Fe{sub 35}V{sub 65} alloy layers. Nevertheless, the SSV effect in sample Fe{sub 25}V{sub 75} with alloy layers is much smaller than in sample with Fe{sub 35}V{sub 65} alloy layers. For a high-performance superconducting spin valve based on a FM1/SC/FM2 heterostructure at least four parameters have to be optimized simultaneously. 1. The magnetic domain size in FM1 and FM2 has to be as large as possible in order to reduce the stray field effect resulting from magnetization components in the FM domain walls perpendicular to the SC layer. 2. When using ferromagnetic alloys as

  17. The relationship between open volume defects and deposition conditions of superconducting thin-film YBa sub 2 Cu sub 3 O sub 7 sub - sub x

    CERN Document Server

    Zhou, X Y; Jiang, H; Bauer-Kugelmann, W; Duffy, J A; Koegel, G; Triftshaeuser, W

    1997-01-01

    The relationship between the open volume defects and the deposition conditions of superconducting thin-film YBa sub 2 Cu sub 3 O sub 7 sub - sub x was studied by the position lifetime technique. Using a low-energy pulsed positron system, positron lifetime as a function of implantation energy was measured on epitaxial superconducting thin-film YBa sub 2 Cu sub 3 O sub 7 sub - sub x deposited on yttrium stabilized cubic zirconia substrates (YSZ) with pulsed laser deposition in a partial pressure of air under different conditions. The results show that the type of open volume defect is independent of deposition conditions such as the substrate temperature, T sub s , and the air pressure, P sub a. The defect concentration increases with decreasing T sub s and increasing P sub a. (author). Letter-to-the-editor

  18. Coulomb-Gas scaling law for a superconducting Bi(2+y)Sr(2-x-y)La(x)CuO(6+delta) thin films in magnetic fields

    Science.gov (United States)

    Zhang; Deltour; Zhao

    2000-10-16

    The electrical transport properties of epitaxial superconducting Bi(2+y)Sr(2-x-y)La(x)CuO(6+delta) thin films have been studied in magnetic fields. Using a modified Coulomb-gas scaling law, we can fit all the magnetic field dependent low resistance data with a universal scaling curve, which allows us to determine a relation between the activation energy of the thermally activated flux flow resistance and the characteristic temperature scaling parameters.

  19. Stability of Tl-Ba-Ca-Cu-O superconducting thin films

    International Nuclear Information System (INIS)

    Siegal, M. P.; Overmyer, D. L.; Venturini, E. L.; Padilla, R. R.; Provencio, P. N.

    1999-01-01

    We report the stability of TlBa 2 CaCu 2 O 7 and Tl 2 Ba 2 CaCu 2 O 8 on LaAlO 3 (100) epitaxial thin films, under a variety of conditions. All films are stable in acetone and methanol and with repeated thermal cycling to cryogenic temperatures. Moisture, especially vapor, degrades film quality rapidly. These materials are stable to high temperatures in either N 2 or O 2 ambients. While total degradation, resulting from Tl depletion, occurs at the same temperatures for both phases, 600 degree sign C in N 2 and 700 degree sign C in O 2 , the onset of degradation occurs at somewhat lower temperatures for TlBa 2 CaCu 2 O 7 than for Tl 2 Ba 2 CaCu 2 O 8 . (c) 1999 Materials Research Society

  20. Superconducting Mercury-Based Cuprate Films with a Zero-Resistance Transition Temperature of 124 Kelvin

    Science.gov (United States)

    Tsuei, C. C.; Gupta, A.; Trafas, G.; Mitzi, D.

    1994-03-01

    The synthesis of high-quality films of the recently discovered mercury-based cuprate films with high transition temperatures has been plagued by problems such as the air sensitivity of the cuprate precursor and the volatility of Hg and HgO. These processing difficulties have been circumvented by a technique of atomic-scale mixing of the HgO and cuprate precursors, use of a protective cap layer, and annealing in an appropriate Hg and O_2 environment. With this procedure, a zero-resistance transition temperature as high as 124 kelvin in c axis-oriented epitaxial HgBa_2CaCu_2O6+δ films has been achieved.

  1. Superconducting mercury-based cuprate films with a zero-resistance transition temperature of 124 Kelvin.

    Science.gov (United States)

    Tsuei, C C; Gupta, A; Trafas, G; Mitzi, D

    1994-03-04

    The synthesis of high-quality films of the recently discovered mercury-based cuprate films with high transition temperatures has been plagued by problems such as the air sensitivity of the cuprate precursor and the volatility of Hg and HgO. These processing difficulties have been circumvented by a technique of atomic-scale mixing of the HgO and cuprate precursors, use of a protective cap layer, and annealing in an appropriate Hg and O(2) environment. With this procedure, a zero-resistance transition temperature as high as 124 kelvin in c axis-oriented epitaxial HgBa(2)CaCu(2)O(6+delta) films has been achieved.

  2. An all-field-range description of the critical current density in superconducting YBCO films

    International Nuclear Information System (INIS)

    Golovchanskiy, I A; Pan, A V; Shcherbakova, O V; Fedoseev, S A; Dou, S X

    2011-01-01

    A new critical current density (J c ) model for high-quality YBCO (YBa 2 Cu 3 O 7 ) thin films has been proposed, combining thermally activated flux creep with a vortex pinning potential for columnar defects. The pinning for thermally activated vortices has been described as strong pinning on chains of individual edge dislocations that form low-angle domain boundaries in high-quality YBCO thin films. The model yields an adequate description of the J c behaviour over the whole applied field range, as verified by direct measurements of J c in YBCO thin films grown by pulsed-laser deposition. It also indicates that the effective pinning landscape changes under the influence of the external conditions. Remarkably, the pinning potential obtained from the model is consistent with the values obtained for columnar defects, which confirms the validity of the overall approach.

  3. Femtosecond optical detection of quasiparticle dynamics in high- T sub c YBa sub 2 Cu sub 3 O sub 7 minus. delta. superconducting thin films

    Energy Technology Data Exchange (ETDEWEB)

    Han, S.G.; Vardeny, Z.V.; Wong, K.S.; Symko, O.G. (Department of Physics, University of Utah, Salt Lake City, UT (USA)); Koren, G. (Department of Physics, Technion, 32000 Haifa (Israel))

    1990-11-19

    Femtosecond dynamics of photogenerated quasiparticles in YBa{sub 2}Cu{sub 3}O{sub 7-{delta}} superconducting thin films shows, at {ital T}{le}{ital T}{sub {ital c}}, two main electronic processes: (i) quasiparticle avalanche production during hot-carrier thermalization, which takes about 300 fsec; (ii) recombination of quasiparticles to form Cooper pairs, which is completed within 5 psec. In contrastr, nonsuperconducting epitaxial films such as PrBa{sub 2}Cu{sub 2}O{sub 7} and YBa{sub 2}Cu{sub 3}O{sub 6} show regular picosecond electronic response.

  4. Detecting properties of thin film superconducting bridges made of YBa2Cu3O7-x

    International Nuclear Information System (INIS)

    Kulikov, V.A.; Matveets, L.V.; Serebryakov, A.Yu.; Laptev, V.N.; Makhov, V.I.; Emel'yanenkov, D.G.; Inkin, Yu.N.

    1989-01-01

    Results of study of detecting properties of thin film YBa 2 Cu 3 O 7-x bridges, subjected to the effect of 8 mm SHF-radiation are presented. The transition temperatures of bridges were equal to 80-85 K. Current-voltage characteristics and response dependences of bridges with 67, 150 and 425 Ω resistances were measured. It is shown that thin film bridges of YBa 2 Cu 3 O 7-x , representing the system of weak bonds, demonstrate nonstationary Josephson effect and synchronization of weak bonds in bridge volume

  5. Giant flux jumps through a thin superconducting Nb film in a vortex free region

    International Nuclear Information System (INIS)

    Tsindlekht, M.I.; Genkin, V.M.; Felner, I.; Zeides, F.; Katz, N.; Gazi, Š.; Chromik, Š.

    2016-01-01

    Highlights: Giant magnetic flux jumps into thin-walled cylinder were measured using peak up coil method in a swept magnetic field. Magnetic moment jumps were observed in magnetic fields lower and above Hc1. - Abstract: We measure the dynamics of magnetic field penetration into thin-walled superconducting niobium cylinders. It is shown that magnetic field penetrates through the wall of a cylinder in a series of giant jumps with amplitude 1 - 2 mT and duration of less than a microsecond in a wide range of magnetic fields, including the vortex free region. Surprisingly, the jumps take place when the total current in the wall, not the current density, exceeds a critical value. In addition, there are small jumps and/or smooth penetration, but their contribution reaches only ≃ 20 % of the total penetrating flux. The number of jumps decreases with increased temperature. Thermomagnetic instabilities cannot explain the experimental observations.

  6. Giant flux jumps through a thin superconducting Nb film in a vortex free region

    Energy Technology Data Exchange (ETDEWEB)

    Tsindlekht, M.I., E-mail: mtsindl@vms.huji.ac.il [The Racah Institute of Physics, The Hebrew University of Jerusalem, Jerusalem 91904 (Israel); Genkin, V.M.; Felner, I.; Zeides, F.; Katz, N. [The Racah Institute of Physics, The Hebrew University of Jerusalem, Jerusalem 91904 (Israel); Gazi, Š.; Chromik, Š. [The Institute of Electrical Engineering SAS, Dúbravská cesta 9, 84104 Bratislava (Slovakia)

    2016-10-15

    Highlights: Giant magnetic flux jumps into thin-walled cylinder were measured using peak up coil method in a swept magnetic field. Magnetic moment jumps were observed in magnetic fields lower and above Hc1. - Abstract: We measure the dynamics of magnetic field penetration into thin-walled superconducting niobium cylinders. It is shown that magnetic field penetrates through the wall of a cylinder in a series of giant jumps with amplitude 1 - 2 mT and duration of less than a microsecond in a wide range of magnetic fields, including the vortex free region. Surprisingly, the jumps take place when the total current in the wall, not the current density, exceeds a critical value. In addition, there are small jumps and/or smooth penetration, but their contribution reaches only ≃ 20 % of the total penetrating flux. The number of jumps decreases with increased temperature. Thermomagnetic instabilities cannot explain the experimental observations.

  7. Magnetic and superconductivity studies on (In{sub 1−x}Fe{sub x}){sub 2}O{sub 3} thin films

    Energy Technology Data Exchange (ETDEWEB)

    Sai Krishna, N. [Thin Films Laboratory, School of Advanced Sciences, VIT University, Vellore 632 014, Tamil Nadu (India); Kaleemulla, S., E-mail: skaleemulla@gmail.com [Thin Films Laboratory, School of Advanced Sciences, VIT University, Vellore 632 014, Tamil Nadu (India); Amarendra, G. [Materials Science Group, Indira Gandhi Centre for Atomic Research, Kalpakkam 603 102, Tamil Nadu (India); UGC-DAE-CSR, Kalpakkam Node, Kokilamedu 603 104, Tamil Nadu (India); Madhusudhana Rao, N.; Krishnamoorthi, C.; Rigana Begam, M. [Thin Films Laboratory, School of Advanced Sciences, VIT University, Vellore 632 014, Tamil Nadu (India); Omkaram, I. [Department of Electronics and Radio Engineering, Kyung Hee University, Yongin-si Gyeonggi-do 446-701 (Korea, Republic of); Sreekantha Reddy, D. [Department of Physics and Sungkyunkwan Advanced Institute of Nanotechnology (SAINT), Sungkyunkwan University, Suwon 440-746 (Korea, Republic of)

    2015-07-15

    Highlights: • Fe doped In{sub 2}O{sub 3} thin films deposited using electron beam evaporation technique. • Characterization of the samples using XRD, SEM, EDAX, AES, Raman spectroscopy, FT-IR, VSM and magnetoresistance. • All Fe doped In{sub 2}O{sub 3} thin films exhibited the cubic structure of In{sub 2}O{sub 3}. • Pure and Fe doped In{sub 2}O{sub 3} samples exhibited room temperature ferromagnetism and superconductivity at 2 K. - Abstract: Magnetic, magnetoresistivity and superconductivity studies were carried out on (In{sub 1−x}Fe{sub x}){sub 2}O{sub 3} (x = 0.00, 0.03, 0.05 and 0.07) thin films (2D structures) grown on glass substrate by electron beam evaporation technique at 350 °C. The films have an average size of 120 nm particles. All the samples shown soft ferromagnetic hysteresis loops at room temperature and saturation magnetization increased with iron dopant concentration. Observed magnetization could be best interpreted by F-center mediated magnetic exchange interaction in the samples. Temperature dependent resistivity of the sample (x = 0.00 and 0.07) showed metallic behavior down to very low temperatures and superconductivity at 2 K for undoped In{sub 2}O{sub 3} whereas the In{sub 1.86}Fe{sub 0.14}O{sub 3} sample shows superconductivity below 2 K in the absence of magnetic fields. The reduction in transition temperature was attributed to increase electrical disorder with iron doping. Both samples showed positive magnetoresistivity (MR) in superconducting state due to increase of resistivity resulting from breaking of superconducting Cooper pairs upon application of magnetic field. In addition, both the samples show feeble negative MR in normal electrical state. The observed MR in normal state is not due to spin polarized tunneling instead it is due to suppression of scattering of charge carrier by single occupied localized states.

  8. Search for superconductivity in ion-implanted Pb-Ge films

    International Nuclear Information System (INIS)

    Zawislak, F.C.; Bernas, H.; Mendoza-Zelis, L.; Travers, A.; Chaumont, J.; Dumoulin, L.

    1980-01-01

    We have studied the dose and the temperature dependence of the resistivity in thin coevaporated films (500-600 A) of Pbsub(0.3) Gesub(0.7) and Pbsub(0.7) Gesub(0.3) implanted at 6K with up to 2x10 15 Ge/cm 2 of 90 and 140 keV. The composition and uniformity of the films were controlled via in situ Rutherford backscattering (RBS) measurements, as functions of the implanted dose and the annealing temperature. The following results were obtained: a) a sharp Tsub(c) very close to the Tsub(c) of pure Pb was measured for the Pbsub(0.7) Gesub(0.3) film and no change in Tsub(c) was observed as a function of dose; b) for the Pbsub(0.3)Gesub(0.7) film the Tsub(c) decreased from about 6.8K before implantation to about 3.5 K after implantation of 2x10 15 ions/cm 2 ; c) the RBS spectra revealed that the alloy homogeneity was larger implantation at 6 K than before implantation and that precipitation for Pb occured during annealing

  9. Pinning enhancement in MgB2 superconducting thin films by ...

    Indian Academy of Sciences (India)

    The magnetic field dependence of the critical current density Jc was calculated from the M–H loops and magnetic field dependence of ... MgB2 thin film; Fe2O3 nanoparticles; critical current density; r-plane Al2O3 substrate. 1. Introduction. The discovery of ... It was thought that from these cal- culations, one can choose an ...

  10. Microwave surface resistance of bulk YBa2Cu3O6+x material

    Science.gov (United States)

    Fathy, A.; Kalokitis, D.; Belohoubek, E.; Sundar, H. G. K.; Safari, A.

    1988-10-01

    Superconducting Y-Ba-Cu-O samples were prepared by conventional solid-state reaction. The microwave surface resistance of 1:2:3 compound superconductor material was measured in a special disk resonator structure at 10 GHz. At liquid-nitrogen temperatures the microwave surface resistance is comparable to that of Au. At lower temperature (~10 K) the surface resistance is an order of magnitude lower than that of Au at the same temperature.

  11. Untitled

    Indian Academy of Sciences (India)

    Another important problem concerns the inert container. We discuss below some results on single-crystal growth of superconducting cuprate phases in the systems La-Sr-Cu-O, Y-Ba-Cu-O and Bi-Sr-Ca-Cu-O. 2. La-(Sr)-Cu-O system. The state diagrams of the systems La2O-CuO, La-Sr.CuO-CuO (Hidaka et all. 1987; Oka ...

  12. Superconducting quantum electronics

    International Nuclear Information System (INIS)

    Kose, V.

    1989-01-01

    This book reviews recent accomplishments, presents new results and discusses possible future developments of superconducting quantum electronics and high T c superconductivity. The three main parts of the book deal with fundamentals, sensitive detectors, and precision metrology. New results reported include: correct equivalent circuits modelling superconducting electronic devices; exact solution of the Mattis-Bardeen equations describing various experiments for thin films; complete theoretical description and experimental results for a new broad band spectrum analyzer; a new Josephson junction potentiometer allowing tracing of unknown voltage ratios back to well-known frequency ratios; and fast superconducting SQUID shift registers enabling the production of calculable noise power spectra in the microwave region

  13. A study on the superconducting properties of YBa{sub 2}Cu{sub 9-x}Nb{sub x}O{sup y} thin films

    Energy Technology Data Exchange (ETDEWEB)

    Srinivas, S.; Bhatnagar, A.K. [Univ. of Hyderabad (India); Pinto, R. [Solid State Electronics Group, Bombay (India)] [and others

    1994-12-31

    Effect of niobium substitution at the copper site in YBa{sub 2}Cu{sub 9}O{sub 7-x} was studied in thin film form. The films were deposited by laser ablation technique using the targets of the YBa{sub 2}Cu{sub 3-x}Nb{sub x}O{sub y} where x = 0.0, 0.025, 0.05, 0.1, 0.2, 0.4, 0.8 and 1.0 under identical deposition conditions on SrTiO{sub 9} <100> substrates. Films were characterized by XRD, resistivity, I-V and J{sub c} measurements. Films made from x = 0.025 and 0.05 concentrations of Nb substituted targets showed relatively improved superconducting properties compared to that of undoped films. The best 7 realized for x = 0.025 Nb concentration was 1.8 x 10{sup {sigma}} A/cm{sup 2} and for 0.05 Nb concentration it was 3.2x10{sup {sigma}} A/cm{sup 2} at 77K. However, degradation of the superconducting properties, with the increase of x {ge} 0.1 Nb concentration and drastic suppression and complete loss of superconductivity was noticed for x {ge} 0.4. The growth of impurity phase YBa{sub 2}NbO{sub 6} for x = 0.1 and above of Nb concentration was noticed from XRD patterns. However, the site occupancy of Nb could not be confirmed from these studies.

  14. Departure from BCS response in photoexcited superconducting NbN films observed by terahertz spectroscopy

    Czech Academy of Sciences Publication Activity Database

    Šindler, Michal; Kadlec, Christelle; Kužel, Petr; Il'in, K.; Siegel, M.; Němec, Hynek

    2018-01-01

    Roč. 97, č. 5 (2018), s. 1-5, č. článku 054507. ISSN 2469-9950 R&D Projects: GA ČR GA17-04412S Institutional support: RVO:68378271 Keywords : terahertz spectroscopy * NbN thin films * superconductors Subject RIV: BM - Solid Matter Physics ; Magnetism OBOR OECD: Condensed matter physics (including formerly solid state physics, supercond.) Impact factor: 3.836, year: 2016

  15. Anisotropic behaviour of transmission through thin superconducting NbN film in parallel magnetic field

    Czech Academy of Sciences Publication Activity Database

    Šindler, Michal; Tesař, Karel; Koláček, Jan; Skrbek, L.

    2017-01-01

    Roč. 533, Feb (2017), s. 154-157 ISSN 0921-4534 R&D Projects: GA MŠk(CZ) LD14060 Institutional support: RVO:68378271 Keywords : far-infrared transmission * NbN * ssuperconducting film * vortices * terahertz waves * parallel magnetic field Subject RIV: BM - Solid Matter Physics ; Magnetism OBOR OECD: Condensed matter physics (including formerly solid state physics, supercond.) Impact factor: 1.404, year: 2016

  16. Stability of Tl-Ba-Ca-Cu-O superconducting thin films

    Energy Technology Data Exchange (ETDEWEB)

    Siegal, M. P. [Sandia National Laboratories, Albuquerque, New Mexico 87185-1421 (United States); Overmyer, D. L. [Sandia National Laboratories, Albuquerque, New Mexico 87185-1421 (United States); Venturini, E. L. [Sandia National Laboratories, Albuquerque, New Mexico 87185-1421 (United States); Padilla, R. R. [Sandia National Laboratories, Albuquerque, New Mexico 87185-1421 (United States); Provencio, P. N. [Sandia National Laboratories, Albuquerque, New Mexico 87185-1421 (United States)

    1999-12-01

    We report the stability of TlBa{sub 2}CaCu{sub 2}O{sub 7} and Tl{sub 2}Ba{sub 2}CaCu{sub 2}O{sub 8} on LaAlO{sub 3}(100) epitaxial thin films, under a variety of conditions. All films are stable in acetone and methanol and with repeated thermal cycling to cryogenic temperatures. Moisture, especially vapor, degrades film quality rapidly. These materials are stable to high temperatures in either N{sub 2} or O{sub 2} ambients. While total degradation, resulting from Tl depletion, occurs at the same temperatures for both phases, 600 degree sign C in N{sub 2} and 700 degree sign C in O{sub 2}, the onset of degradation occurs at somewhat lower temperatures for TlBa{sub 2}CaCu{sub 2}O{sub 7} than for Tl{sub 2}Ba{sub 2}CaCu{sub 2}O{sub 8}. (c) 1999 Materials Research Society.

  17. Smooth surfaces in very thin GdBa{sub 2}Cu{sub 3}O{sub 7−δ} films for application in superconducting tunnel junctions

    Energy Technology Data Exchange (ETDEWEB)

    Navarro, H., E-mail: henrynavarro@cab.cnea.gov.ar [Instituto Balseiro, Universidad Nacional de Cuyo & CNEA, 8400 Bariloche (Argentina); Centro Atómico Bariloche, Comisión Nacional de Energía Atómica. Av. Bustillo 9500, 8400 San Carlos de Bariloche (Argentina); Sirena, M. [Instituto Balseiro, Universidad Nacional de Cuyo & CNEA, 8400 Bariloche (Argentina); Centro Atómico Bariloche, Comisión Nacional de Energía Atómica. Av. Bustillo 9500, 8400 San Carlos de Bariloche (Argentina); Kim, Jeehoon [Department of Physics, Pohang University of Science and Technology, Pohang (Korea, Republic of); CALDES, Institute for Basic Science, Pohang (Korea, Republic of); Haberkorn, N. [Instituto Balseiro, Universidad Nacional de Cuyo & CNEA, 8400 Bariloche (Argentina); Centro Atómico Bariloche, Comisión Nacional de Energía Atómica. Av. Bustillo 9500, 8400 San Carlos de Bariloche (Argentina)

    2015-03-15

    Highlights: • A detailed study of the morphological properties of GdBa{sub 2}Cu{sub 3}O{sub 7−δ} thin films was realized. • The inclusion of a very thin SrTiO{sub 3} buffer layer modifies the surface of the SrTiO{sub 3} substrates. • The inclusion of the buffer layer suppress the three dimensional nucleation in the GdBa{sub 2}Cu{sub 3}O{sub 7−δ} film. • GdBa{sub 2}Cu{sub 3}O{sub 7−δ} films with large areas free of topological defects and T{sub c} close to liquid nitrogen can be obtained. - Abstract: This paper provides a systematic analysis of the morphology and the superconducting critical temperature obtained in very thin GdBa{sub 2}Cu{sub 3}O{sub 7−δ} films grown on (0 0 1) SrTiO{sub 3} substrates by DC sputtering. We find that the use of a very thin SrTiO{sub 3} buffer layer (≈2 nm) modify the nucleation of GdBa{sub 2}Cu{sub 3}O{sub 7−δ} on the surface of the substrate reducing the formation of 3 dimensional clusters. Our results demonstrate that 16 nm thick GdBa{sub 2}Cu{sub 3}O{sub 7−δ} films with an average root-mean-square (RMS) smaller than 1 nm and large surface areas (up 10 μm{sup 2}) free of 3 dimensional topological defects can be obtained. In films thinner than 24 nm the onset (zero resistance) of superconducting transition of the films is reduced, being close to liquid nitrogen. This fact can be associated with stress reducing the orthorhombicity and slightly drop in oxygen stoichiometry.

  18. Smooth surfaces in very thin GdBa2Cu3O7−δ films for application in superconducting tunnel junctions

    International Nuclear Information System (INIS)

    Navarro, H.; Sirena, M.; Kim, Jeehoon; Haberkorn, N.

    2015-01-01

    Highlights: • A detailed study of the morphological properties of GdBa 2 Cu 3 O 7−δ thin films was realized. • The inclusion of a very thin SrTiO 3 buffer layer modifies the surface of the SrTiO 3 substrates. • The inclusion of the buffer layer suppress the three dimensional nucleation in the GdBa 2 Cu 3 O 7−δ film. • GdBa 2 Cu 3 O 7−δ films with large areas free of topological defects and T c close to liquid nitrogen can be obtained. - Abstract: This paper provides a systematic analysis of the morphology and the superconducting critical temperature obtained in very thin GdBa 2 Cu 3 O 7−δ films grown on (0 0 1) SrTiO 3 substrates by DC sputtering. We find that the use of a very thin SrTiO 3 buffer layer (≈2 nm) modify the nucleation of GdBa 2 Cu 3 O 7−δ on the surface of the substrate reducing the formation of 3 dimensional clusters. Our results demonstrate that 16 nm thick GdBa 2 Cu 3 O 7−δ films with an average root-mean-square (RMS) smaller than 1 nm and large surface areas (up 10 μm 2 ) free of 3 dimensional topological defects can be obtained. In films thinner than 24 nm the onset (zero resistance) of superconducting transition of the films is reduced, being close to liquid nitrogen. This fact can be associated with stress reducing the orthorhombicity and slightly drop in oxygen stoichiometry

  19. Positron annihilation studies on high temperature superconductors

    International Nuclear Information System (INIS)

    Sundar, C.S.; Bharathi, A.

    1991-01-01

    The results of positron annihilation measurements as a function of temperature, across Tc, in a variety of high temperature superconductors such as Y-Ba-Cu-O (Y1237), Y-Ba-Cu-O (Y1248), Bi-Sr-Ca-Cu-O, Tl-Ba-Ca-Cu-O, Ba-K-Bi-O and Nd-Ce-Cu-O are presented. It is shown that the variation of annihilation parameters in the superconducting state is correlated with the diposition of the positron density distribution with respect to the superconducting CuO planes. An increase in positron lifetime is observed below Tc when the positrons probe the CuO planes whereas a decrease in lifetime is observed when the positron density overlaps predominantly with the apical oxygen atom. With this correlation, the different temperature variation of annihilation parameters, seen in the various high temperature superconductors, is understood in terms of a local charge transfer from the planar oxygen atom to the apical oxygen atom. The significance of these results in the context of various theoretical models of high temperature superconductivity is discussed. In addition, the application of positron annihilation spectroscopy to the study of oxygen defects in the Y-Ba-Cu-O, Bi-Sr-Ca-Cu-O and Nd-Ce-Cu-O is presented. (author). 53 refs., 17 figs., 2 tabs

  20. Laser activated superconducting switch

    International Nuclear Information System (INIS)

    Wolf, A.A.

    1976-01-01

    A superconducting switch or bistable device is described consisting of a superconductor in a cryogen maintaining a temperature just below the transition temperature, having a window of the proper optical frequency band for passing a laser beam which may impinge on the superconductor when desired. The frequency of the laser is equal to or greater than the optical absorption frequency of the superconducting material and is consistent with the ratio of the gap energy of the switch material to Planck's constant, to cause depairing of electrons, and thereby normalize the superconductor. Some embodiments comprise first and second superconducting metals. Other embodiments feature the two superconducting metals separated by a thin film insulator through which the superconducting electrons tunnel during superconductivity

  1. Spin-on Bi4Sr3Ca3Cu4O16μ/sub x/ superconducting thin films from citrate precursors

    International Nuclear Information System (INIS)

    Furcone, S.L.; Chiang, Y.

    1988-01-01

    Thin films in the Bi-Sr-Ca-Cu-O system have been synthesized from homogeneous liquid citrate precursors by a spin-coating and pyrolysis method. Films prepared on SrTiO 3 substrates of [100] orientation show strongly textured orientations with the c axis of the predominant Bi 4 Sr 3 Ca 3 Cu 4 O 16 μ/sub x/ phase normal to the film plane. In a single coating and firing, crack-free films of 0.2--0.5 μm thickness are obtained. For films fired to peak temperatures of 850--875 0 C, linearly decreasing resistance with temperature is observed, with rho (300 K)∼460 μΩ cm and rho (300 K)rho (100 K)∼2.4. Clear onsets of superconductivity are observed at 90--100 K, with occasional films showing smaller resistant drops at 110--120 K. For all films, T/sub c/ (R = 0) occurs in the range 70--75 K. High critical current densities at 4.2 K of 5--8 x 10 5 Acm 2 are measured by direct transport

  2. Influence of substrate type on transport properties of superconducting FeSe0.5Te0.5 thin films

    International Nuclear Information System (INIS)

    Yuan, Feifei; Shi, Zhixiang; Iida, Kazumasa; Langer, Marco; Hänisch, Jens; Hühne, Ruben; Schultz, Ludwig; Ichinose, Ataru; Tsukada, Ichiro; Sala, Alberto; Putti, Marina

    2015-01-01

    FeSe 0.5 Te 0.5 thin films were grown by pulsed laser deposition on CaF 2 , LaAlO 3 and MgO substrates and structurally and electro-magnetically characterized in order to study the influence of the substrate on their transport properties. The in-plane lattice mismatch between FeSe 0.5 Te 0.5 bulk and the substrate shows no influence on the lattice parameters of the films, whereas the type of substrate affects the crystalline quality of the films and, therefore, the superconducting properties. The film on MgO showed an extra peak in the angular dependence of critical current density J c (θ) at θ = 180° (H||c), which arises from c-axis defects as confirmed by transmission electron microscopy. In contrast, no J c (θ) peaks for H||c were observed in films on CaF 2 and LaAlO 3 . J c (θ) can be scaled successfully for both films without c-axis correlated defects by the anisotropic Ginzburg–Landau approach with appropriate anisotropy ratio γ J . The scaling parameter γ J is decreasing with decreasing temperature, which is different from what we observed in FeSe 0.5 Te 0.5 films on Fe-buffered MgO substrates. (paper)

  3. Electronic Instability at High Flux-Flow Velocities in High-Tc Superconducting Films

    DEFF Research Database (Denmark)

    Doettinger, S. G.; Huebener, R. P.; Gerdemann, R.

    1994-01-01

    At high flux-flow velocities in type-II superconductors the nonequilibrium distribution of the quasiparticles leads to an electronic instability and an aburpt switching into a state with higher electric resistivity, as predicted by Larkin and Ovchinnikow (LO). We report the first obervation...... of this effect in a high-temperature superconductor, namely in epitaxial c-axis oriented films of YBa(2)Cu3O(7)-(delta). Using the LO therory, we have extracted from out results the inelastic quasiparticle scattering rare tau(in)(-1), which strongly decreases with decreasing temperature below T-c...

  4. Observation of magnetic flux generated spontaneously during a rapid quench of superconducting films

    International Nuclear Information System (INIS)

    Maniv, A.; Polturak, E.; Koren, G.

    2003-01-01

    We report observations of spontaneous formation of magnetic flux lines during a rapid quench of YBa 2 Cu 3 O 7-δ films through T c . This effect is predicted according to the Kibble-Zurek mechanism of creation of topological defects of the order parameter during a symmetry-breaking phase transition. Our previous experiment, at a quench rate of 20 K/s, gave null results. In the present experiment, the quench rate was increased to >10 8 K/s. The amount of spontaneous flux increases weakly with the cooling rate

  5. Electron tunneling into superconducting indium and lead films containing the magnetic impurity manganese

    International Nuclear Information System (INIS)

    Tsang, J.K.

    1980-01-01

    Tunneling measurements of quench-condensed In-Mn and Pb-Mn alloy films were made. The results were compared with Shiba's theory of superconductors containing magnetic impurities. The localized excited impurity states predicted by Shiba's theory were observed in both alloys. In addition to s-wave scattering, it was necessary to include p- and d-wave scattering of the conduction electrons in the theory in order to explain the experimental data. Partial agreement between the theory and the experimental data was obtained using phase shifts from band calculations by A.B. Kunz. The results on In-Mn also agree with thermal conductivity data

  6. Analysis of process parameters in the laser deposition of YBa{sub 2}Cu{sub 3}O{sub 7} superconducting films by using SVR

    Energy Technology Data Exchange (ETDEWEB)

    Cai, C.Z., E-mail: caiczh@gmail.com [Department of Applied Physics, Chongqing University, Chongqing 401331 (China); Xiao, T.T. [Department of Applied Physics, Chongqing University, Chongqing 401331 (China); Science and Technology on Plasma Physics Laboratory, Research Center of Laser Fusion, CAEP, P.O. Box 919-988, Mianyang 621900 (China); Tang, J.L.; Huang, S.J. [Department of Applied Physics, Chongqing University, Chongqing 401331 (China)

    2013-10-15

    Highlights: • Proposed new ideas and strategies to improve energy storage density for SMES system. • One is to increase the effective current density in the superconducting coils. • Another is to optimize the configuration of the SMES coil. • A new conceive of energy compression is also proposed. -- Abstract: There are several process parameters in the growth of YBa{sub 2}Cu{sub 3}O{sub 7} superconducting films by using pulsed laser deposition (PLD). The relationship between the response and process parameters is highly nonlinear and quite complicated. It is very valuable to quantitatively estimate the response under different deposition parameters. In this study, according to an experimental data set on the superconducting transition temperature (T{sub c}) and relative resistance ratio (r{sub R}) of 17 samples of YBa{sub 2}Cu{sub 3}O{sub 7} films deposited under various parameters, the support vector regression (SVR) combined with particle swarm optimization (PSO), was proposed to predict the T{sub c} and r{sub R} for YBa{sub 2}Cu{sub 3}O{sub 7} films. The prediction performance of SVR was compared with that of multiple regression analysis (MRA) models. The results strongly support that the generalization ability of SVR model consistently surpasses that of MRA via leave-one-out cross validation (LOOCV). The mean absolute percentage errors for T{sub c} and r{sub R} are 0.37% and 1.51% respectively via LOOCV test of SVR. Sensitivity analysis discovered the most sensitive parameters affecting the T{sub c} and r{sub R}. This study suggests that the established SVR model can be used to accurately foresee the T{sub c} and r{sub R}. And it can be used to optimizing the deposition parameters in the development of YBa{sub 2}Cu{sub 3}O{sub 7} films via PLD.

  7. Growth of superconducting Bi/sub 2/Sr/sub 2/CaCu/sub 2/O/sub 8+//sub x/ films on alumina, silicon, and fused quartz

    International Nuclear Information System (INIS)

    Hung, L.S.; Agostinelli, J.A.; Paz-Pujalt, G.R.; Mir, J.M.

    1988-01-01

    Interactions between superconducting Bi/sub 2/Sr/sub 2/CaCu/sub 2/O/sub 8+//sub x/ films and substrates were investigated by ion backscattering, x-ray diffraction, and four-point probe resistivity measurements. During annealing at temperatures above- 800 /sup 0/C, Bi/sub 2/Sr/sub 2/CaCu/sub 2/ oxide films rapidly reacted with alumina, Si, Si covered with SiO/sub 2/, and quartz, resulting in catastrophic failure. Zr-based barrier layers were used to minimize film-substrate interactions. When a single ZrO/sub 2/ layer was interposed between the superconducting oxide film and the underlying substrate, the Bi/sub 2/Sr/sub 2/CaCu/sub 2/ oxide films showed a large-grained polycrystalline microstructure and exhibited the orthorhombic structure. Films on sapphire showed transitions to the superconducting state beginning near 100 K with zero resistance achieved at 70 K. Films on Si and thermally grown SiO/sub 2/ showed a similar drop in resistance around 95 K, whereas the transition was broad and the zero resistance state was not reached. For films on quartz, high thermal stress caused cracking of the superconducting oxide film. Best results were achieved using a barrier composed of a Zr-Si-O mixed layer underneath ZrO/sub 2/. In this case, the films grown on Si and quartz were uniform and showed the onset to superconductivity at 95 K, attaining zero resistance at 70 K

  8. Enhancement of the superconducting properties of TlBa2CaCu2O7+δ thin films via postannealing

    International Nuclear Information System (INIS)

    Siegal, M.P.; Venturini, E.L.; Newcomer, P.P.; Morosin, B.; Overmyer, D.L.; Dominguez, F.; Dunn, R.

    1995-01-01

    The superconducting properties of TlBa 2 CaCu 2 O 7+δ (Tl-1212) films are greatly enhanced by annealing in unreactive ambients such as nitrogen at temperatures ranging from T a =250--600 degree C. The transition temperature, T c , of these Tl-1212 films as-grown in oxygen is 70 K. Annealing for 1 h at 250 degree C elevates T c above 90 K. T c further increases and sharpens for T a =600 degree C. In addition, subtle changes occur in the microstructure correlating with improved critical current density. These results indicate that Tl-1212 films may be of greater relevance for electronics applications than previously believed. copyright 1995 American Institute of Physics

  9. A 350 mK, 9 T scanning tunneling microscope for the study of superconducting thin films on insulating substrates and single crystals.

    Science.gov (United States)

    Kamlapure, Anand; Saraswat, Garima; Ganguli, Somesh Chandra; Bagwe, Vivas; Raychaudhuri, Pratap; Pai, Subash P

    2013-12-01

    We report the construction and performance of a low temperature, high field scanning tunneling microscope (STM) operating down to 350 mK and in magnetic fields up to 9 T, with thin film deposition and in situ single crystal cleaving capabilities. The main focus lies on the simple design of STM head and a sample holder design that allows us to get spectroscopic data on superconducting thin films grown in situ on insulating substrates. Other design details on sample transport, sample preparation chamber, and vibration isolation schemes are also described. We demonstrate the capability of our instrument through the atomic resolution imaging and spectroscopy on NbSe2 single crystal and spectroscopic maps obtained on homogeneously disordered NbN thin film.

  10. Heteroepitaxial growth of strained multilayer superconducting thin films of Nd1.83Ce0.17CuOx/YBa2Cu3O7-δ

    International Nuclear Information System (INIS)

    Gupta, A.; Gross, R.; Olsson, E.; Segmueller, A.; Koren, G.; Tsuei, C.C.

    1990-01-01

    Heteroepitaxial growth of strained multilayer thin films of YBa 2 Cu 3 O 7-δ /Nd 1.83 Ce 0.17 CuO x by pulsed-laser deposition is reported. The coherency strain results in biaxial compression of the tetragonal Nd 1.83 Ce 0.17 CuO x layers, whereas the biaxial tension in the YBa 2 Cu 3 O 7-δ layers removes the orthorhombic distortion and makes the unit cell isotropic in the basal plane (a=b). Depending on their oxygen content, either the YBa 2 Cu 3 O 7-δ or the Nd 1.83 Ce 0.17 CuO x layers are superconducting in these multilayers. The strain-induced structural modification has a significant influence on the superconducting transition temperature of the YBa 2 Cu 3 O 7-δ layers

  11. Magneto-optic observation of anomalous Meissner current flow in superconducting thin films with slits

    International Nuclear Information System (INIS)

    Baziljevich, M.; Johansen, T.H.; Bratsberg, H.; Shen, Y.; Vase, P.

    1996-01-01

    Slits patterned into a YBa 2 Cu 3 O 7-δ thin film were observed to obstruct Meissner sheet currents leading to an imbalance in the local Meissner screening properties. The new phenomenon was studied with magneto-optic imaging where twin lobes of opposite flux polarity were seen to form near the slits and inside the Meissner region. The lobe closest to the sample edge is always polarized opposite to the applied field. At weak fields, the anomalous flux generation is reversible. At higher fields, but still sufficiently small to keep the vortex penetration front away from the slits, the anomalous current starts nucleating flux lines which become trapped when the field is removed. copyright 1996 American Institute of Physics

  12. Interplay of dendritic avalanches and gradual flux penetration in superconducting MgB2 films

    International Nuclear Information System (INIS)

    Shantsev, D V; Goa, P E; Barkov, F L; Johansen, T H; Kang, W N; Lee, S I

    2003-01-01

    Magneto-optical imaging was used to study a zero-field-cooled MgB 2 film at 9.6 K where in a slowly increasing field the flux penetrates by an abrupt formation of large dendritic structures. Simultaneously, a gradual flux penetration takes place, eventually covering the dendrites, and a detailed analysis of this process is reported. We find an anomalously high gradient of the flux density across a dendrite branch, and a peak value that decreases as the applied field increases. This unexpected behaviour is reproduced by flux creep simulations based on the non-local field-current relation in the perpendicular geometry. The simulations also provide indirect evidence that flux dendrites are formed at an elevated local temperature, consistent with a thermo-magnetic mechanism of the instability

  13. Charge Berezinskii-Kosterlitz-Thouless transition in superconducting NbTiN films

    Energy Technology Data Exchange (ETDEWEB)

    Mironov, Alexey Yu.; Silevitch, Daniel M.; Proslier, Thomas; Postolova, Svetlana V.; Burdastyh, Maria V.; Gutakovskii, Anton K.; Rosenbaum, Thomas F.; Vinokur, Valerii V.; Baturina, Tatyana I.

    2018-03-06

    Three decades after the prediction of charge-vortex duality in the critical vicinity of the two-dimensional superconductor-insulator transition (SIT), one of the fundamental implications of this duality-the charge Berezinskii-Kosterlitz-Thouless (BKT) transition that should occur on the insulating side of the SIT-has remained unobserved. The dual picture of the process points to the existence of a superinsulating state endowed with zero conductance at finite temperature. Here, we report the observation of the charge BKT transition on the insulating side of the SIT in 10 nm thick NbTiN films, identified by the BKT critical behavior of the temperature and magnetic field dependent resistance, and map out the magnetic-field dependence of the critical temperature of the charge BKT transition. Finally, we ascertain the effects of the finite electrostatic screening length and its divergence at the magnetic field-tuned approach to the superconductor-insulator transition.

  14. Contribution of nuclear microanalysis and of 18O tracer technique to study the oxygen sublattice in high Tc superconducting thin films

    International Nuclear Information System (INIS)

    Siejka, J.

    1994-01-01

    At first a short review of IBA contribution to the determination of composition and structure, including phonon properties of high T c superconducting oxides is presented. In the second part, IBA contribution to the elucidation of the mechanisms of thin film growth is presented. The emphasis is on the complementarity of IBA, Raman spectroscopy and XRD techniques to characterize thin films of high T c superconducting oxides. In the third part, some recent results related mainly to YBaCuO films grown on (100) oriented single crystalline bulk materials (MgO, LaAlO 3 , SrTiO 3 ) is discussed. In these experiments, IBA, XRD and Raman spectroscopies were used to study the oxygen content in a series of YBaCuO films prepared in different conditions of pressure and temperature. In the case of c-axis oriented films a good agreement between these three methods was found for the films cooled down at high oxygen pressure and a significant disagreement for the films cooled down at low oxygen pressure, showing structures with anomalous c-axis parameter. In the case of a-axis oriented films grown on SrTiO 3 substrates it was found that the low T c values (∼ 70-80 K) are not correlated with the oxygen content but rather with a disorder in the oxygen sublattice. The disorder in the oxygen sublattice was studied using the 16 O(α, α) 16 O resonance in random and channeling geometry. These results are correlated with the data provided by Raman spectroscopy. The 18 O tracer technique was used to estimate the diffusion coefficient in the a-axis oriented YBaCuO films showing a huge anisotropy of the 18 O labelling. Combining Raman and IBA techniques, the selective 18 O labelling of the CuO chain-planes was evidenced. The defects in the 18 O enriched CuO chain-planes were studied using the 18 O(p, α) 15 N nuclear resonant reaction in random and channeling geometries. Some preliminary results related to roughness of YBaCuO films are also discussed. The physical implications of these

  15. The I{sub c}(H)-T{sub c}(H) phase boundary of superconducting Nb thin films with periodic and quasiperiodic antidot arrays

    Energy Technology Data Exchange (ETDEWEB)

    Bothner, D.; Kemmler, M.; Cozma, R.; Kleiner, R.; Koelle, D. [Physikalisches Institut and Center for Collective Quantum Phenomena, Universitaet Tuebingen (Germany); Misko, V.; Peeters, F. [Departement Fysica, Universiteit Antwerpen (Belgium); Nori, F. [Advanced Science Institute, RIKEN (Japan)

    2011-07-01

    The magnetic field dependent critical current I{sub c}(H) of superconducting thin films with artificial defects strongly depends on the symmetry of the defect arrangement. Likewise the critical temperature T{sub c}(H) of superconducting wire networks is heavily influenced by the symmetry of the system. Here we present experimental data on the I{sub c}(H)-T{sub c}(H) phase boundary of Nb thin films with artificial defect lattices of different symmetries. For this purpose we fabricated 60 nm thick Nb films with antidots in periodic (triangular) and five different quasiperiodic arrangements. The parameters of the antidot arrays were varied to investigate the influence of antidot diameter and array density. Experiments were performed with high temperature stability ({delta}T<1 mK) at 0.5{<=}T/T{sub c}{<=}1. From the I-V-characteristics at variable H and T we extract I{sub c}(H) and T{sub c}(H) for different voltage and resistance criteria. The experimental data for the critical current density are compared with results from numerical molecular dynamics simulations.

  16. Josephson junction in superconducting oxides thick films. Jonction Josephson en couche epaisse d'oxydes supraconducteurs

    Energy Technology Data Exchange (ETDEWEB)

    Gunther, C; Monfort, Y; Lam Chok Sing, M; Bloyet, D; Brousse, T; Provost, J; Raveau, B [Institut des Sciences de la Matiere du Rayonnement, 14 - Caen (FR)

    1992-02-01

    Constrictions engraved in YBaCuO thick films fabricated by screen printing on YSZ substrate (J{sub c} > 3 000 A/cm{sup 2} at 77 K) have been studied. Microwave irradiation of the devices at LN{sub 2} showed distinct Shapiro steps demonstrating the presence intrinsic Josephson junctions. The latter have an I{sub c}(T) dependence fitting (1 - T/T{sub c}){sup 2} characteristic of SNS junctions. Furthermore, dc SQUID effects have also been observed with a peak-to-peak response {approx equal} 0.2 {mu}V and with a magnetic field periodicity extending through several hundred of {phi}{sub o}. An energy resolution close to 3 x 10{sup -29} J/Hz is estimated for our constriction operating in the white noise frequency range (f > 50 Hz) at 77 K. This sensitivity is adequate to use this flux sensor in many applications: geomagnetism, magnetocardiology,... 19 refs; 7 figs.

  17. Strong field-matching effects in superconducting YBa2Cu3O7-δ films with vortex energy landscapes engineered via masked ion irradiation

    Science.gov (United States)

    Swiecicki, I.; Ulysse, C.; Wolf, T.; Bernard, R.; Bergeal, N.; Briatico, J.; Faini, G.; Lesueur, J.; Villegas, Javier E.

    2012-06-01

    We have developed a masked ion irradiation technique to engineer the energy landscape for vortices in oxide superconductors. This approach associates the possibility to design the landscape geometry at the nanoscale with the unique capability to adjust the depth of the energy wells for vortices. This enabled us to unveil the key role of vortex channeling in modulating the amplitude of the field matching effects with the artificial energy landscape, and to make the latter govern flux dynamics over an unusually wide range of temperatures and applied fields for high-temperature superconducting films.

  18. Influence of laser sputtering parameters on orientation of cerium oxide buffer layer on sapphire and properties of YBa2Cu3Ox superconducting film

    International Nuclear Information System (INIS)

    Mozhaev, P.B.; Ovsyannikov, G.A.; Skov, J.L.

    1999-01-01

    Effect of laser sputtering parameters on crystalline properties of CeO 2 buffer layers grown on (1102) orientation sapphire substrate and on properties of YBa 2 Cu 3 O x superconducting thin films was studied. It was shown that depending on the sputtering conditions one might observe growth of CeO 2 (100) and (111) orientations. Varying heater temperature, chamber pressure and density of laser ray energy on the target one managed to obtain mono-oriented buffer layer of the desired orientation [ru

  19. Preparation of YBCO on YSZ layers deposited on silicon and sapphire by MOCVD: influence of the intermediate layer on the quality of the superconducting film

    International Nuclear Information System (INIS)

    Garcia, G.; Casado, J.; Llibre, J.; Doudkowski, M.; Santiso, J.; Figueras, A.; Schamm, S.; Dorignac, D.; Grigis, C.; Aguilo, M.

    1995-01-01

    YSZ buffer layers were deposited on silicon and sapphire by MOCVD. The layers deposited on silicon were highly oriented along [100] direction without in-plane orientation, probably because the existence of the SiO 2 amorphous interlayer. In contrast, epitaxial YSZ was obtained on (1-102) sapphire showing an in-plane texture defined by the following relationships: (100) YSZ // (1-102) sapphire and (110) YSZ // (01-12) sapphire. Subsequently, YBCO films were deposited on YSZ by MOCVD. Structural, morphological and electrical characterization of the superconducting layers were correlated with the in-plane texture of the buffer layers. (orig.)

  20. Proposal for the award of a contract for the supply of polyimide film for cable and ground insulation of the LHC superconducting magnets

    CERN Document Server

    1999-01-01

    This document concerns the award of a contract for the supply of up to 79 tonnes of polyimide film, of three different types, for cable and ground insulation of the LHC superconducting magnets. A call for tenders (IT-2679/LHC/LHC) was sent on 21 September 1999 to two firms in Japan and one firm in the USA. By the closing date, CERN had received three tenders. The Finance Committee is invited to agree to the negotiation of a contract with the firm KANEKA (JP), the lowest bidder, for the supply of 79 tonnes of polyimide film of three different types for an amount of 5 425 541 USD (8 123 284 Swiss francs) for the polyimide film produced in the USA, not subject to revision, and 725 726 546 Japanese yen (10 109 020 Swiss francs) for the polyimide film produced in Japan, not subject to revision, with an option for the supply of up to 20% additional polyimide film of each type, for an amount of 1 085 108 USD (1 624 657 Swiss francs) and 145 145 309 Japanese yen (2 021 804 Swiss francs) respectively, not subject to r...