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Sample records for superalloys descriptive note

  1. NOTES ON TRICHOFERUS ARENBERGERI WITH DESCRIPTION OF MALE (COLEOPTERA, CERAMBYCIDAE

    Directory of Open Access Journals (Sweden)

    Alessandro B. Biscaccianti

    2008-04-01

    Full Text Available Trichoferus arenbergeri is a poorly known endemic species of Sardinia, described upon three females. Description of the male and the species’ biology is given in this paper, together with short notes on its habitat. The relationships between this species, T. fasciculatus and T. spartii are also briefly discussed.

  2. Notes on Japanese Rhizocephala, with description of two new species

    NARCIS (Netherlands)

    Boschma, H.

    1935-01-01

    The following notes are based upon material of parasites on two Crustaceans from Japan, viz., Pachygrapsus crassipes Randall and Petrolisthes japonicus de Haan 1). Each of these two species may be infested by two different species of Rhizocephala: on Pachygrapsus crassipes occur the parasites Saccul

  3. Immigrant fertility in Sweden, 2000-2011: A descriptive note

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    Lotta Persson

    2014-03-01

    Full Text Available Background: Modern Scandinavian population registers provide excellent data sources that allow a user to quickly gain an impression of the level of fertility and its structure across subpopulations. This may also allow the analyst to check a feature of the much-cited disruption hypothesis, at least in part. Objective: The purpose of this note is to exploit this potential to give an overview of the structure of recent total fertility after immigration to Sweden from various groups of sending countries, separately for males and females. In the process we demonstrate to what extent the post-migration fertility compensation which is part of the fertility disruption hypothesis is fulfilled in our study population. Due to the nature of our data we have refrained from studying fertility before migration. Methods: Based on data from a combination of two Swedish administrative registers (the Historic Population Register and the Multi-Generation Register that cover both men and women in the entire population for the years 2000-2011, we compute and plot TFR-like age-cumulated fertility levels, specific for years since immigration, for six groups of sending countries, separately for men and women. Results: We find that the post-migration fertility compensation specified as part of the fertility disruption hypothesis is visibly confirmed in our Swedish study population for female European immigrants from non-EU countries and for female immigrants from non-European countries with a low or medium UN Human Development Index, but not so for other female immigrants, i.e. not for those who come from a Nordic country or from a non-Nordic EU country, and not for female immigrants from a non-European country with a high Human Development Index, including the United States. We find mild but less conclusive evidence for the same feature for males. Conclusions: This shows that at least as far as post-migration fertility compensation is concerned, the disruption

  4. The characteristic of deformability and quantitative description of the microstructure of hot-deformed Ni-Fe superalloy

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    Ducki K. J.

    2017-03-01

    Full Text Available The paper presents the results of research concerning the influence of hot plastic working parameters on the deformability and microstructure of a Ni-Fe superalloy. The research was performed on a torsion plastometer in the range of temperatures of 900-1150°C, at a strain rates 0.1 and 1.0 s-1. Plastic properties of the alloy were characterized by the worked out flow curves and the temperature relationships of flow stress and strain limit. The structural inspections were performed on microsections taken from plastometric samples after so-called “freezing”. The stereological parameters as the recrystallized grain size, inhomogenity and grain shape have been determined. Functional relations between the Zener-Hollomon parameter and the maximum yield stress and the average grain area have been developed and the activation energy for hot working has been estimated.

  5. Application of Rapidly Solidified Superalloys.

    Science.gov (United States)

    1977-11-01

    those described earlier. It was noted, however, that the conventional lype stlperalloys (as evidenced in MAR M2(W, AF2-1DA and MAR M247 alloys, the...Activation Energy For Matrix Creep in MAR MAX() Alloy....................... I I *v 7o- SUMMARY This program is being conducted for the purpose of applying...can be achieved in superalloy powder materials for optimization of mechanical properties above I., Tm. MAR M200 alloy powder, processed and reacted in

  6. Systematyc notes and a Detailed description of Opuntia ficus-indica (L) Mill. (CACTACEAE)

    OpenAIRE

    J. Antonio Reyes-Agüero; J. Rogelio Aguirre-Rivera; Hernández, Héctor M.

    2005-01-01

    Opuntia ficus-indica is the cactus species with the highest economic importance worldwide. It is cultivated for its fruits, forage, or as host of the cochineal insect, but only in México their young cladodes are consumed as vegetables. The main goals of this study were: a) to integrate systematic notes about its common nomenclature, origin, reproductive biology and ploidy levels of O. ficus-indica; b) to present a complete botanical description based on specimens collected in north-central Mé...

  7. "Sitting on pins and needles": characterization of symptom descriptions in clinical notes".

    Science.gov (United States)

    Forbush, Tyler B; Gundlapalli, Adi V; Palmer, Miland N; Shen, Shuying; South, Brett R; Divita, Guy; Carter, Marjorie; Redd, Andrew; Butler, Jorie M; Samore, Matthew

    2013-01-01

    Patients report their symptoms and subjective experiences in their own words. These expressions may be clinically meaningful yet are difficult to capture using automated methods. We annotated subjective symptom expressions in 750 clinical notes from the Veterans Affairs EHR. Within each document, subjective symptom expressions were compared to mentions of symptoms in clinical terms and to the assigned ICD-9-CM codes for the encounter. A total of 543 subjective symptom expressions were identified, of which 66.5% were categorized as mental/behavioral experiences and 33.5% somatic experiences. Only two subjective expressions were coded using ICD-9-CM. Subjective expressions were restated in semantically related clinical terms in 246 (45.3%) instances. Nearly one third (31%) of subjective expressions were not coded or restated in standard terminology. The results highlight the diversity of symptom descriptions and the opportunities to further develop natural language processing to extract symptom expressions that are unobtainable by other automated methods.

  8. Superalloy Lattice Block Structures

    Science.gov (United States)

    Nathal, M. V.; Whittenberger, J. D.; Hebsur, M. G.; Kantzos, P. T.; Krause, D. L.

    2004-01-01

    Initial investigations of investment cast superalloy lattice block suggest that this technology will yield a low cost approach to utilize the high temperature strength and environmental resistance of superalloys in lightweight, damage tolerant structural configurations. Work to date has demonstrated that relatively large superalloy lattice block panels can be successfully investment cast from both IN-718 and Mar-M247. These castings exhibited mechanical properties consistent with the strength of the same superalloys measured from more conventional castings. The lattice block structure also accommodates significant deformation without failure, and is defect tolerant in fatigue. The potential of lattice block structures opens new opportunities for the use of superalloys in future generations of aircraft applications that demand strength and environmental resistance at elevated temperatures along with low weight.

  9. Taxonomic notes on some Polyglyptini: descriptions of new genus and new species (Homoptera, Membracidae, Smiliinae

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    Albino M. Sakakibara

    1996-01-01

    Full Text Available Taxonomic notes on some Polyglyptini; descriptions of new genus and new species (Homoptera, Membracidae, Smiliinae. The genera Hemiptycha Germar, Metheisa Fowler, Maturnaria Metcalf, Aphetea Fowler, Dioclophara Kirkaldy, and Phormophora Stål, are redescribed; Creonus, gen.n. (type species: Maturna lloydi Funkhouser, 1914, and Aphetea robustula, sp.n. (from Bolivia, are described. Some nomenclatural changes are introduced, as follow: - Hemiptycha Germar, 1833 = Polyrhyssa Stål, 1869, syn.n.: - Hemiptycha cultrata (Coquebert, 1801, comb.n., = Polyglyptodes flavocostatus Haviland, 1925, syn.n., = Polyrhyssa cultrata maculata Fonseca, 1942, syn.n. - Hemiptycha obtecta (Fabricius, 1803 = Hille herbicola Haviland, 1925, syn.n. - Maturnaria ephippigera (Fairmaire, 1846 = Publilia tumulata Buckton, 1903, syn.n., = Metheisa fowleri Funkhouser, 1927, syn.n. - Creonus lloydi (Funkhouser, 1914, comb.n. - Aphetea parvula (Fabricius, 1803, comb.n., = Aphetea affinis Haviland, 1925, syn.n. - Dioclophara Kirkaldy, 1904 = lncolea Goding, 1926, syn.n. - Dioclophara viridula (Fairmaire, 1846 = Maturna multilineata Fonseca, 1942, syn.n. - Dioclophara variegata (Goding, 1926, comb.n. = lncolea viridis Goding, 1926, syn.n. - Phormophora maura (Fabricius, 1803 = Darnis dorsata Fabricius, 1803, syn.n.

  10. Note on the occurrence of a rare palaemonid prawn, Palaemonsewelli (Kemp, 1925) in South Vietnam, with its description (Decapoda: Caridea)

    NARCIS (Netherlands)

    Xuân, Ng.V.

    2000-01-01

    A rare palaemonid prawn Palaemon sewelli (Kemp, 1925) was found in abundance in a shallow and flat coastal region of southeastern Vietnam, at a depth of 4-9 m. This is the first record of the species from Vietnam. A description of the two colour morphs of the freshly collected specimens and notes on

  11. Notes on Neotropical Eumeninae, with the description of a new species of Pachodynerus de Saussure (Hymenoptera, Vespidae

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    Marcel Gustavo Hermes

    2013-06-01

    Full Text Available Notes on Neotropical Eumeninae, with the description of a new species of Pachodynerus de Saussure (Hymenoptera, Vespidae. Taxonomic information on Neotropical Eumeninae is provided. A new species, Pachodynerus fessatus sp. nov. is described from southeastern São Paulo, Brazil. Additional material of Pachodynerus sericeus (Fox was examined, representing the first further specimens after the original description and including the previously unknown male. The examination of new material of the genus Stenonartonia adds some new distribution records and shows some previously unrecorded individual variation for some species. The males of Stenonartonia guaraya Garcete-Barrett and Stenonartonia rejectoides Garcete-Barrett are described for the first time.

  12. A note on the translation of conceptual data models into description logics: disjointness and covering assumptions

    CSIR Research Space (South Africa)

    Casini, G

    2012-10-01

    Full Text Available possibilities for conceptual data modeling. It also raises the question of how existing conceptual models using ER, UML or ORM could be translated into Description Logics (DLs), a family of logics that have proved to be particularly appropriate for formalizing...

  13. Fragments of musicalliturgical codices in Spain: notes for and historiography and a proposal of description

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    David Andrés Fernández

    2017-07-01

    Full Text Available From the Middle Ages, several circumstances have caused the destruction of liturgical manuscripts with music and their reutilisation. The remaining fragments are proof of what once was part of the Western written culture, therefore these primary sources provide insight into diverse aspects of our history. In Spain, some researchers have identified and studied those fragments, particulary the musico-liturgical ones. This article shows a historiographic review on the field, and propose, based on this review, a form for description which can be used as a model in their analysis, and serve as well as fields in a potential database in Spanish language. As a result, the information on the topic has been updated, and an accurate, and detailed descriptive-template has been addressed to the more accepted standards.

  14. Description and biological notes of the first species of Xenos (Strepsiptera:Stylopidae) parasitic in Polistes carnifex F. (Hymenoptera:Vespidae) in Mexico

    DEFF Research Database (Denmark)

    Kathirithamby, J.; Hughes, David P.

    2006-01-01

    A description and biological notes on the first species of Xenos (X. hamiltoni) (Strepsiptera: Stylopidae) parasitic in Polistes carnifex F. from Mexico is given. A list of Strepsiptera and their hosts from Mexico is provided.......A description and biological notes on the first species of Xenos (X. hamiltoni) (Strepsiptera: Stylopidae) parasitic in Polistes carnifex F. from Mexico is given. A list of Strepsiptera and their hosts from Mexico is provided....

  15. Review of the genus Ommatoiulus in Andalusia, Spain (Diplopoda: Julida) with description of ten new species and notes on a remarkable gonopod structure, the fovea

    DEFF Research Database (Denmark)

    Akkari, Nesrine; Enghoff, Henrik

    2012-01-01

    Schubart, 1959, is a junior synonym of Omnmatoiulus ilicis (Brölemann, 1896), n.syn. Full descriptions and diagnostic notes are provided for all the species with accounts on their distributions, habitats, and notes discussing their taxonomy. A dichotomous identification key, based on gonopod structures...

  16. Taxonomic notes on the genus Auranus (Opiliones, Laniatores, Stygnidae), with description of two new species.

    Science.gov (United States)

    Colmenares, Pío A; Porto, Willians; Tourinho, Ana Lúcia

    2016-04-12

    Among the Amazonian families of harvestmen the members of Stygnidae are better known due to the recent revision of the family and efforts of specialists describing new taxa in the last few years. Species of Amazonian genus Auranus Mello-Leitão, 1941, have been collected in several inventories that were carried out in different locations of the Amazon basin. In this paper we provide a new diagnosis for Auranus, and the description of two new species: Auranus leonidas sp. nov. and Auranus xerxes sp. nov. from the Brazilian states of Roraima and Amazonas, respectively. We also offer complementary genital descriptions of Auranus hehu Pinto-da-Rocha & Tourinho 2012, Auranus parvus Mello-Leitão, 1941, and Auranus tepui Pinto-da-Rocha & Tourinho 2012. Five species are recognized in Auranus, including the two new species described in this paper. The lamina parva modified into a calyx is proposed as putative synapomorphy for the genus Auranus. Therefore, A. hoeferscovitorum, which does not possess this character, is removed from Auranus. Instead we propose for it the new combination Verrucastygnus hoeferscovitorum comb. nov. We also provide a key to the males of Auranus, and a map with the distribution for all species examined in this work.

  17. Taxonomic note and description of new species of Fissocantharis Pic from China (Coleoptera, Cantharidae).

    Science.gov (United States)

    Yang, Yuxia; Su, Junyan; Yang, Xingke

    2014-01-01

    Two new species of Fissocantharis Pic are described, Fissocantharisbifoveatus sp. n. (CHINA: Yunnan) and Fissocantharisacuticollis sp. n. (CHINA: Zhejiang, Fujian, Guangdong, Hunan). Fissocantharispieli (Pic, 1937) is redescribed and Fissocanthariskontumensis Wittmer, 1989 is provided with a supplementary description. Fissocantharisshanensis (Wittmer, 1997) is synonymized with Fissocanthariskontumensis. For the above four species, illustrations of male genitalia are provided, for the latter three also photos of female genitalia and abdominal sternites VIII, and for the new species photos of male habitus and antennae are presented. Additionally, the specific name of Fissocanthariswittmeri (Y. Yang et X. Yang, 2009), preoccupied by Fissocanthariswittmeri (Kazantsev, 2007), is replaced by Fissocanthariswalteri Y. Yang et X. Yang, nom. n. And Fissocanthariswittmeri (Kazantsev, 2007) is found to be a junior objective synonym of Fissocantharisdenominata (Wittmer, 1997).

  18. Advanced superalloy airfoils

    Energy Technology Data Exchange (ETDEWEB)

    Gell, M.; Duhl, D.N.; Gupta, D.K.; Sheffler, K.D.

    1987-07-01

    Single-crystal superalloy technology for gas-turbine blades has combined the design of alloys for exclusive use in single-crystal form with advancements in directional solidification, in order to manufacture single-crystal castings with complex internal cooling passages. To these improvements have been incorporated metallic and ceramic coatings that further extend high temperature capabilities. The directional solidification of single-crystal turbine alloys requires total control of the thermal environment, using large vacuum furnaces capable of casting up to 30 blades at a time. All modern coatings involve the enrichment of the superalloy surface with elements that promote the formation and retention of alumina, which precludes further oxidation. 15 references.

  19. Powder-metallurgy superalloy strengthened by a secondary gamma phase.

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    Kotval, P. S.

    1971-01-01

    Description of experiments in which prealloyed powders of superalloy compositions were consolidated by extrusion after the strengthening by precipitation of a body-centered tetragonal gamma secondary Ni3 Ta phase. Thin foil electron microscopy showed that the mechanical properties of the resultant powder-metallurgy product were correlated with its microstructure. The product exhibited high strength at 1200 F without loss of ductility, after thermomechanical treatment and aging.

  20. Rediscovery of Tetranychus abacae Baker & Pritchard, additional description and notes on South American spider mites (Acari, Prostigmata, Tetranychidae

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    Carlos H.W Flechtmann

    1996-01-01

    Full Text Available The rediscovery of Tetranychus abacae Baker & Pritchard, 1962 is reported and additional description and drawings presented. New host and distribution records for 19 species of spider mites (Tctranychidae in South America are given.

  1. Notes on the frugivorous fruit fly (Diptera: Tephritidae fauna of western Africa, with description of a new Dacus species

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    Kim F.M. Goodger

    2013-07-01

    Full Text Available The species richness of the frugivorous fruit fly fauna of western African (in particular of Ivory Coast, Ghana, Togo, Benin and Nigeria is discussed. The diversity is compared at a national level and between the ecoregions within the national boundaries of the study area. A new species, Dacus goergeni sp. nov. is described and additional taxonomic notes are presented.

  2. Description of the larva of Tetragonoderus (Crossonychus) variegatus Dejean, 1829 (Coleoptera: Carabidae: Cyclosomini) with notes on biology.

    Science.gov (United States)

    Santos, Guilherme Ide Marques Dos

    2015-06-16

    A late instar of the Tetragonoderus (Crossonychus) variegatus Dejean, 1829 larva is described for the first time, and is compared with its first instar, with the larva of another Tetragonoderus species, and with the larva of one Cyclicus species. Habitus and important structures of the larva are illustrated, as well the adult's membranous wings. Some aspects of the natural history of the larva and adult are also noted.

  3. Notes on the genus Psathyrella-VIII. Description of and key to the European species of section Hydrophilae

    NARCIS (Netherlands)

    Kits van Waveren, E.

    1982-01-01

    A description of and key to twelve species of Psathyrella section Hydrophilea (Romagn.) ex Sing. emend. Kits van Wav. is given. These species are: P. hydrophila, P. hydrophiloides (spec. nov., = Drosophila pilulaeformis ss. Kühn. & Romagn.), P. laevissima, P. subpapillata (comb. nov.), P. fragrans

  4. Revision of the Neotropical genus Eschatocerus Mayr (Hymenoptera, Cynipidae, Eschatocerini) with biological notes and the first description of the terminal larva.

    Science.gov (United States)

    Nieves-Aldrey, José Luis; San Blas, Germán

    2015-09-02

    The gall wasp genus Eschatocerus (Hymenoptera, Cynipidae, Eschatocerini), a cynipid genus of gall inducers on Prosopis and Acacia species (Fabaceae), endemic to southern South America, is revised. Complete descriptions of the external morphology of the genus and its three known species, illustrated with scanning electron photographs, are given for the first time, and an updated key for the identification of the species is provided. The biology of the species of Eschatocerus and their galls is described. Host plant associations are given, and the terminal larva of Eschatocerus niger is described for the first time. Preliminary notes on the inquiline and parasitoid community associated with the galls of Eschatocerus species are also given.

  5. Description of the male of Eburella pinima Martins and notes on the geographical distribution of Eburodacrys aenigma Galileo & Martins and Eburodacrys lanei Zajciw (Coleoptera, Cerambycidae

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    Juan Pablo Botero

    2013-12-01

    Full Text Available Description of the male of Eburella pinima Martins and notes on the geographical distribution of Eburodacrys aenigma Galileo & Martins and Eburodacrys lanei Zajciw (Coleoptera, Cerambycidae. The male of Eburella pinima Martins, 1997 is described and illustrated for the first time. Information on Eburodacrys aenigma Galileo & Martins, 2006, previously known only from the female holotype, which lacked locality label, is herein complemented. This species is recorded from Brazil and the male is depicted for the first time. The geographical distribution of Eburodacrys lanei Zajciw, 1958 is further restricted here as some previous records are confirmed to result from misidentifications of E. aenigma.

  6. Description and biological notes of the first species of Xenos (Strepsiptera:Stylopidae) parasitic in Polistes carnifex F. (Hymenoptera:Vespidae) in Mexico

    DEFF Research Database (Denmark)

    Kathirithamby, J.; Hughes, David P.

    2006-01-01

    A description and biological notes on the first species of Xenos (X. hamiltoni) (Strepsiptera: Stylopidae) parasitic in Polistes carnifex F. from Mexico is given. A list of Strepsiptera and their hosts from Mexico is provided....

  7. SHI Changxu: China's Superalloy Hero

    Institute of Scientific and Technical Information of China (English)

    XIN Ling

    2011-01-01

    Prof.Shi Changxu (Chang-hsu Shih), laureate of the State Top Scientific and Technological Award for 2010, is regarded as a pioneer in the development of superalloys in China and a world-class master of materials science with excellent leadership and strategic insights.In the 1960s, he and his colleagues worked out the first generation air-cooled nickel-based superalloy turbine blades for domestic fighter aircrafts which greatly enhanced the aeroengines' performance.Via the effective control of trace elements, he developed the low segregation technology to reduce the segregation of superalloys, for which the International Union of Materials Research Societies honored him with the "Innovations in Real Materials Award" in 1998.He advocated and promoted the research and development of carbon fibers and magnesium alloys in China as well as the establishment of the Chinese Academy of Engineering.Today, 30 years after retirement, Prof.Shi still works every day in his office to read latest research results, write advisory proposals and meet young visitors to give them his best support.

  8. SUPERALLOYS: AN INTRODUCTION WITH THERMAL ANALYSIS ...

    African Journals Online (AJOL)

    2015-09-01

    Sep 1, 2015 ... another precipitation strengthened nickel base superalloy, has a very good strength at ... Keywords: Superalloys; Phase reactions; Differential Thermal Analysis; Latent heat of ... high-temperature strength and creep resistance. ... Borides, a relatively low density of boride particles formed when boron ...

  9. Notes on Neotropical Proconiini (Hemiptera: Cicadellidae: Cicadellinae: VII: First detailed description of the female genitalia of a Diestostemma species

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    Gabriel Mejdalani

    2010-10-01

    Full Text Available Diestostemma Amyot & Serville, 1843 is a diverse sharpshooter genus with 32 species. A description and illustrations of Diestostemma nasutum Schmidt, 1910 are provided. The species, previously known from Ecuador, is newly recorded from Colombia. Both the male and female genitalia are described for the first time. This is the first detailed description of the female genitalia of a Diestostemma species. Diestostemma nasutum can be distinguished from the other species of the genus by the following features of the aedeagus: shaft with the distal third distinctly curved dorsally; base of basiventral aedeagal process with a lobe directed anteriorly; and basiventral aedeagal process bifurcated on its basal portion. The style of D. nasutum, whose apical portion is broad, distinctly curved inward, and with the apex subtruncate, is also quite distinctive. We compared the female genitalia of D. nasutum with those of other Proconiini genera. Our results confirm the perception that the female genitalia in this tribe can be a source of useful taxonomic characters.

  10. Quantitative evaluation of carbides in nickel-base superalloy MAR-M247

    Science.gov (United States)

    Szczotok, A.

    2011-05-01

    It has been established that carbides in superalloys serve three functions. Fine carbides precipitated in the matrix give strengthening results. Carbides also can tie up certain elements that would otherwise promote phase instability during service. Grain boundary carbides prevent or retard grain-boundary sliding and strengthen the grain boundary, which depends significantly on carbide shape, size and distribution. Various types of carbides are possible, depending on superalloy composition and processing. In the paper optical and scanning electron microscopy investigations of carbides occurring in specimens of the polycrystalline nickel-base superalloy MAR-M247 were carried out. Conditions of carbides revealing and microstructure images acquisition have been described. Taking into consideration distribution and morphology of the carbides in matrix a method of quantitative description of Chinese script-like and blocky primary carbides on the basis of image analysis was proposed.

  11. Notes on some sertulariid hydroids (Cnidaria: Hydrozoa from the tropical western Pacific, with descriptions of nine new species

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    Horia R. Galea

    2016-08-01

    Full Text Available Forty-three species of sertulariid hydroids (Cnidaria: Hydrozoa: Sertulariidae, collected from the tropical western Pacific (Taiwan, Philippines, New Caledonia, French Polynesia, Vanuatu, Fiji, Tonga, Solomon Islands during various expeditions of the French Tropical Deep-Sea Benthos program, are discussed. Of these, nine are new to science: Gonaxia nova sp. nov., G. plumularioides sp. nov., Sertularella folliformis sp. nov., Se. plicata sp. nov., Se. pseudocatena sp. nov., Se. splendida sp. nov., Se. tronconica sp. nov., Se. tubulosa sp. nov., and Symplectoscyphus paucicatillus sp. nov. The subspecies Symplectoscyphus johnstoni (Gray, 1843 tropicus Vervoort, 1993 is raised to species but, in order to avoid the secondary homonymy with Sy. tropicus (Hartlaub, 1901, the replacement name, Sy. fasciculatus nom. nov., is introduced. The male and female gonothecae of Diphasia cristata Billard, 1920, the male gonothecae of Gonaxia elegans Vervoort, 1993, as well as the female gonothecae of Salacia macer Vervoort & Watson, 2003, are described for the first time. Additional notes on the morphology of several other species are provided. All taxa are illustrated, in most cases using figures drawn at the same scale, so as to highlight the differences between related species.

  12. The first record of Litargus tetraspilotus (Coleoptera, Mycetophagidae in Brazil, with biological notes and complementary description of the species

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    Julianne Milléo

    2011-06-01

    Full Text Available Litargus tetraspilotus LeConte, 1856 was collected feeding on Oidium sp. (Fungi, Ascomycota, Erysiphaceae associated with fruit trees. This is the first time L. tetraspilotus is recorded in Brazil, totaling three species of Mycetophagidae for this country. This study aims to provide a complementary description of this species based on new characters and to present information on its life cycle under laboratory conditions and fluctuation in population in the field. During the period of inventories between July 2004 and August 2006, about every fifteen days, a total of 565 specimens of L. tetraspilotus were collected, with the highest abundance found on citrus plants, with values differing significantly between the two years. The population levels differed between the seasons; spring had the greatest abundance and autumn the least. There was a significant positive correlation of L. tetraspilotus abundance with rainfall and relative humidity. Mycetophagidae, as well as other mycophagous families of Brazilian coleopterans, are barely studied, warranting further future studies of their bioecology and systematics.

  13. Electrodeposition on Superalloy Substrates: a Review

    Science.gov (United States)

    Allahyarzadeh, M. H.; Aliofkhazraei, M.; Rouhaghdam, A. Sabour

    2016-02-01

    The present paper reviews various types of coatings, including platinum, platinum alloys, palladium, ruthenium, iridium, nickel, nickel alloys and composite coatings, on superalloy substrates using electrodeposition method. Attempts were carried out to represent an overall view of plating conditions and electrolyte and highlight the importance of the layer regarding to the performance of high-temperature coatings applied on superalloys, which is extensively used on gas-turbine components.

  14. Ni-based superalloys for turbine discs

    Science.gov (United States)

    Furrer, David; Fecht, Hans

    1999-01-01

    Superalloys have been developed for specific, specialized properties and applications. One of the main applications for nickel-based superalloys is gas-turbine-engine disc components for land-based power generation and aircraft propulsion. Turbine engines create harsh environments for materials due to the high operating temperatures and stress levels. Hence, as described in this article, many alloys used in the high-temperature turbine sections of these engines are very complex and highly optimized.

  15. Taxonomy of freshwater sponges of Maharashtra, India, with illustrated descriptions and notes on ecology and habitats (Porifera: Spongillida: Spongillidae).

    Science.gov (United States)

    Jakhalekar, Shriraj S; Ghate, Hemant V

    2016-10-10

    We present additional taxonomic descriptions, with Scanning Electron Microscopy (SEM) illustrations, field observations documented by colour photographs, and notes on habitats and ecology of Corvospongilla ultima (Annandale), Eunapius crassissimus (Annandale), Stratospongilla bombayensis (Carter), S. gravelyi (Annandale) and S. indica (Annandale) from recent sponge collections made in western Maharashtra, India. Stratospongilla gravelyi is rediscovered after a century, and along with it, C. ultima and S. indica are illustrated with SEM images for the first time, unequivocally differentiating these two species. Additional taxonomic, ecological data and illustrations of Corvospongilla lapidosa (Annandale), Dosilia plumosa (Carter), Ephydatia meyeni (Carter), Eunapius carteri (Bowerbank) and Radiospongilla cerebellata (Bowerbank) are also provided to supplement the previously published SEM illustrations. All ten spongillid species treated here were originally described from India and three of them are known to be endemic to the Indian region. Present study is the first re-examination of these Indian spongillid species using SEM, providing greater resolution of their important taxonomic characters and careful documentation of their habitats.

  16. RESEARCH ON REFRACTORY SUPERALLOYS IN THE HTM 21 PROJECT

    Institute of Scientific and Technical Information of China (English)

    Y.F.Gu; Y.Yamabe-Mitarai; C.Huang; H.Harada

    2005-01-01

    It was proposed that a new class of alloys based on platinum group metals (PGMs) were called refractory superalloys.These refractory superalloys have an fcc and LI2 coherent two-phase structure (similar to that of Ni-based superalloys), high melting temperatures and good potential as structural materials used at temperatures up to 1800℃.Our recent results on the microstructure evolution, deformation and fracture behavior of some of these refracotry superalloys, especial Ir- and Rh-base refractory superalloys were reported.

  17. New knowledge about 'white spots' in superalloys

    Energy Technology Data Exchange (ETDEWEB)

    Jackman, L.A. (Teledyne Allvac, Monroe, N.C. (United States)); Maurer, G.E. (Special Metals Corp., New Hartford, N.Y. (United States)); Widge, S. (Carpenter Technology Corp., Reading, PA (United States))

    1993-05-01

    In April 1991, the first in a series of workshops was held to discuss ways in which the gas turbine industry could better understand defects in nickel-base superalloys. The group's primary objective was to better define, and expand knowledge about, segregation in superalloys such as Alloy 718 and Waspaloy,with emphasis on light-etching areas referred to as solute-lean defects or 'white spots'. This 'White Spots Committee' formed four subcommittees to focus efforts on classification, inspection, mechanisms, and mechanical properties. Completion of the tasks that these subcommittees have undertaken should greatly improve the gas turbine industry's understanding of the physical and mechanical nature of white spots. The primary purpose of this article is to formalize the characterization and classification of white spots in high-strength superalloys so that the metallurgical community can begin to use a common vocabulary when referring to them. An overview of formation mechanisms is presented along with a brief description of detection methods. Also discussed are preliminary test results, which should help shed light on the effects of solute-lean microstructures on tensile and fatigue properties. Although white spots are not limited to any single superalloy or class of superalloy, Alloy 718 is emphasized because it is so widely used, and because its relatively large solidus-liquidus temperature interval ([approximately]75 C, 135 F) and high niobium content ([approximately]5.3% Nb) make it prone to segregation. Three distinct types of white spots have been identified and named by the committee: discrete, dendritic, and solidification white spots.

  18. Chemical driving force for rafting in superalloys

    CSIR Research Space (South Africa)

    Nabarro, FRN

    1997-08-15

    Full Text Available The author provides a brief overview of the chemical driving forces for rafting in superalloys. Until recently, all theories of the driving force for rafting have considered the compositions of the two phases to be fixed, although accepting...

  19. SUPERALLOYS: AN INTRODUCTION WITH THERMAL ANALYSIS

    Directory of Open Access Journals (Sweden)

    S. S. Raza

    2015-09-01

    Full Text Available Nickel based superalloys are commonly used materials in the aero industry and more specifically in the hot section of aero engines. These nickel and nickel iron based superalloys are precipitation strengthened alloys with a face centered cubic gamma matrix. Alloy 718, Allvac 718Plus and Waspaloy have been of great interest in the present study. Alloy 718 is a precipitation strengthened nickel-iron based alloy having gamma double prime phase (Ni3Nb as a main strengthening phase up to 650 °C. Waspaloy, another precipitation strengthened nickel base superalloy, has a very good strength at temperatures up to ~750 °C whereas Allvac 718Plus is a newly developed nickel based precipitation strengthened superalloy which retains good mechanical properties at up to ~700 °C. These three alloys were investigated in terms of how their respective solidification process reveals upon cooling.Latent heat of soloidification has been estimated for all three alloys. Differential thermal analyses (DTA have been used to approach the task. It was seen that Waspaloy has the smallest solidification range whereas Allvac 718Plus has the largest solidification interval in comparison. 

  20. A New Polycrystalline Co-Ni Superalloy

    Science.gov (United States)

    Knop, M.; Mulvey, P.; Ismail, F.; Radecka, A.; Rahman, K. M.; Lindley, T. C.; Shollock, B. A.; Hardy, M. C.; Moody, M. P.; Martin, T. L.; Bagot, P. A. J.; Dye, D.

    2014-12-01

    In 2006, a new-ordered L12 phase, Co3(Al,W), was discovered that can form coherently in a face-centered cubic (fcc) A1 Co matrix. Since then, a community has developed that is attempting to take these alloys forward into practical applications in gas turbines. A new candidate polycrystalline Co-Ni γ/ γ' superalloy, V208C, is presented that has the nominal composition 36Co-35Ni-15Cr-10Al-3W-1Ta (at.%). The alloy was produced by conventional powder metallurgy superalloy methods. After forging, a γ' fraction of ~56% and a secondary γ' size of 88 nm were obtained, with a grain size of 2.5 μm. The solvus temperature was 1000°C. The density was found to be 8.52 g cm-3, which is similar to existing Ni alloys with this level of γ'. The alloy showed the flow stress anomaly and a yield strength of 920 MPa at room temperature and 820 MPa at 800°C, similar to that of Mar-M247. These values are significantly higher than those found for either conventional solution and carbide-strengthened Co alloys or the γ/ γ' Co superalloys presented in the literature thus far. The oxidation resistance, with a mass gain of 0.08 mg cm-2 in 100 h at 800°C, is also comparable with that of existing high-temperature Ni superalloys. These results suggest that Co-based and Co-Ni superalloys may hold some promise for the future in gas turbine applications.

  1. Development of Wrought Superalloy in China

    Directory of Open Access Journals (Sweden)

    DU Jinhui

    2016-06-01

    Full Text Available Wrought superalloy development in China was reviewed in recent ten years. The achievement of basic research and development of industrial manufacture technologies were systematically described from the aspects of new alloys, new technologies of hot deformation. New alloys include: new disc materials 718Plus, GH4720Li and GH4065 alloy, combustion chamber alloy GH3230, and GH4706 alloy for gas turbine engines. New technologies include: ERS-CDS new technology of easy segregation materials, multi upsetting-drawing for improving the microstructure uniformity of bars, slow cooling and multi-cycle thermomechanical treatment for increasing hot plasticity of hard-to-work alloys. Finally, the further development of wrought superalloys was prospected.

  2. Thermal fatigue behavior of K465 superalloy

    Institute of Scientific and Technical Information of China (English)

    YANG Jinxia; ZHENG Qi; SUN Xiaofeng; GUAN Hengrong; HU Zhuangqi

    2006-01-01

    The thermal fatigue behavior of K465 superalloy was investigated at the peak temperature of 1050℃. By scanning electron microscopy (SEM) and optical microscopy, the main crack length was observed and measured. The initiation sites of the tested alloys are different in as-cast (named as K465) and solution heat treatment (named as SK465) conditions.In K465 alloy, most thermal fatigue cracks nucleate at (Nb,W,Ti)C carbides. In SK465 alloy, thermal fatigue cracks initiate in interdendritic regions, MC-type carbides and some interfaces. Thermal fatigue cracks propagate in transdendritic mode,and M6C-type carbides could retard thermal fatigue crack growth for SK465 superalloy.

  3. High-temperature protective coatings on superalloys

    Institute of Scientific and Technical Information of China (English)

    刘培生; 梁开明; 周宏余

    2002-01-01

    Protective coatings are essential for superalloys to serve as blades of gas turb ines at high temperatures, and they primarily include aluminide coating, MCrAlY overlay coating, thermal barrier coating and microcrystalline coating. In this paper, all these high-temperature coatings are reviewed as well as their preparing techniques. Based on the most application and the main failure way, the importance is then presented for further deepgoing study on the high-temperature oxidation law of aluminide coatings.

  4. Recent breakthroughs in nickel base superalloys

    OpenAIRE

    Honnorat, Y.

    1993-01-01

    Meanwhile the considerable amount of results acquired since more than sixty years in the study of this class of materials, the pre-eminence of nickel base superalloys in the gas turbine engineering, which is a domain in constant evolution, drives the significant progresses accomplished along the five last years. The knowledge, each day more precisely known, of the working conditions of the parts, the continuous increase of the computer capacity and the progressive sophistication of the design...

  5. Development of Wrought Superalloy in China

    OpenAIRE

    DU Jinhui; ZHAO Guangpu; Deng, Qun; LÜ Xudong; ZHANG Beijiang

    2016-01-01

    Wrought superalloy development in China was reviewed in recent ten years. The achievement of basic research and development of industrial manufacture technologies were systematically described from the aspects of new alloys, new technologies of hot deformation. New alloys include: new disc materials 718Plus, GH4720Li and GH4065 alloy, combustion chamber alloy GH3230, and GH4706 alloy for gas turbine engines. New technologies include: ERS-CDS new technology of easy segregation materials, multi...

  6. Effects of helium impurities on superalloys

    Energy Technology Data Exchange (ETDEWEB)

    Selle, J.E.

    1977-07-01

    A review of the literature on the effects of helium impurities on superalloys at elevated temperatures was undertaken. The actual effects of these impurities vary depending on the alloy, composition of the gas atmosphere, and temperature. In general, exposure in helium produces significant but not catastrophic changes in the structure and properties of the alloys. The effects of these treatments on the structure, creep, fatigue, and mechanical properties of the various alloys are reviewed and discussed. Suggestions for future work are presented.

  7. Barrier Coatings for Refractory Metals and Superalloys

    Energy Technology Data Exchange (ETDEWEB)

    SM Sabol; BT Randall; JD Edington; CJ Larkin; BJ Close

    2006-02-23

    In the closed working fluid loop of the proposed Prometheus space nuclear power plant (SNPP), there is the potential for reaction of core and plant structural materials with gas phase impurities and gas phase transport of interstitial elements between superalloy and refractory metal alloy components during service. Primary concerns are surface oxidation, interstitial embrittlement of refractory metals and decarburization of superalloys. In parallel with kinetic investigations, this letter evaluates the ability of potential coatings to prevent or impede communication between reactor and plant components. Key coating requirements are identified and current technology coating materials are reviewed relative to these requirements. Candidate coatings are identified for future evaluation based on current knowledge of design parameters and anticipated environment. Coatings were identified for superalloys and refractory metals to provide diffusion barriers to interstitial transport and act as reactive barriers to potential oxidation. Due to their high stability at low oxygen potential, alumina formers are most promising for oxidation protection given the anticipated coolant gas chemistry. A sublayer of iridium is recommended to provide inherent diffusion resistance to interstitials. Based on specific base metal selection, a thin film substrate--coating interdiffusion barrier layer may be necessary to meet mission life.

  8. Thermomechanical fatigue in single crystal superalloys

    Directory of Open Access Journals (Sweden)

    Moverare Johan J.

    2014-01-01

    Full Text Available Thermomechanical fatigue (TMF is a mechanism of deformation which is growing in importance due to the efficiency of modern cooling systems and the manner in which turbines and associated turbomachinery are now being operated. Unfortunately, at the present time, relatively little research has been carried out particularly on TMF of single crystal (SX superalloys, probably because the testing is significantly more challenging than the more standard creep and low cycle fatigue (LCF cases; the scarcity and relative expense of the material are additional factors. In this paper, the authors summarise their experiences on the TMF testing of SX superalloys, built up over several years. Emphasis is placed upon describing: (i the nature of the testing method, the challenges involved in ensuring that an given testing methodology is representative of engine conditions (ii the behaviour of a typical Re-containing second generation alloy such as CMSX-4, and its differing performance in out-of-phase/in-phase loading and crystallographic orientation and (iii the differences in behaviour displayed by the Re-containing alloys and new Re-free variants such as STAL15. It is demonstrated that the Re-containing superalloys are prone to different degradation mechanisms involving for example microtwinning, TCP precipitation and recrystallisation. The performance of STAL15 is not too inferior to alloys such as CMSX-4, suggesting that creep resistance itself does not correlate strongly with resistance to TMF. The implications for alloy design efforts are discussed.

  9. Development of a Refractory High Entropy Superalloy

    Directory of Open Access Journals (Sweden)

    Oleg N. Senkov

    2016-03-01

    Full Text Available Microstructure, phase composition and mechanical properties of a refractory high entropy superalloy, AlMo0.5NbTa0.5TiZr, are reported in this work. The alloy consists of a nano-scale mixture of two phases produced by the decomposition from a high temperature body-centered cubic (BCC phase. The first phase is present in the form of cuboidal-shaped nano-precipitates aligned in rows along <100>-type directions, has a disordered BCC crystal structure with the lattice parameter a1 = 326.9 ± 0.5 pm and is rich in Mo, Nb and Ta. The second phase is present in the form of channels between the cuboidal nano-precipitates, has an ordered B2 crystal structure with the lattice parameter a2 = 330.4 ± 0.5 pm and is rich in Al, Ti and Zr. Both phases are coherent and have the same crystallographic orientation within the former grains. The formation of this modulated nano-phase structure is discussed in the framework of nucleation-and-growth and spinodal decomposition mechanisms. The yield strength of this refractory high entropy superalloy is superior to the yield strength of Ni-based superalloys in the temperature range of 20 °C to 1200 °C.

  10. Effect of Zr addition on precipitates in K4169 superalloy

    National Research Council Canada - National Science Library

    Li Yamin Liu Hongjun Liu Jie Wang Zhipeng Hao Yuan

    2012-01-01

    In order to investigate the effect of Zr addition on the precipitations of K4169 superalloy, a manual electric arc furnace was used to prepare the superalloy with different Zr addition from 0.03wt.% to 0.07wt...

  11. 75 FR 67100 - Superalloy Degassed Chromium From Japan

    Science.gov (United States)

    2010-11-01

    ... COMMISSION Superalloy Degassed Chromium From Japan AGENCY: United States International Trade Commission... chromium from Japan. SUMMARY: The Commission hereby gives notice that it has instituted a review pursuant... revocation of the antidumping duty order on superalloy degassed chromium from Japan would be likely to lead...

  12. Mesene Doubleday (Lepidoptera: Riodinidae) from Parque Nacional da Serra do Divisor, Acre, Brazil, with taxonomic notes and the description of a new species.

    Science.gov (United States)

    Dolibaina, Diego Rodrigo; Dias, Fernando Maia Silva; Siewert, Ricardo Russo; Mielke, Olaf Hermann Hendrik; Casagrande, Mirna Martins

    2016-10-17

    The species of Mesene Doubleday, 1847 collected at the Parque Nacional da Serra do Divisor, Acre, Brazil (PNSD) are listed and supplemented by taxonomic and behavioral notes. In total, 30 specimens were collected, representing seven species including one new: M. monostigma monostigma (Erichson, [1849]), M. nepticula stigmosa Stichel, 1910, M. eupteryx Bates, 1868 stat. rest., M. paraena Bates, 1868, M. epaphus pyrrha Bates, 1868, M. leucophrys Bates, 1868, and M. gracielae sp. nov. The following notes on the taxonomy of Mesene are proposed: M. eupteryx Bates, 1868 stat. rest. is recognized as a valid species, M. epaphus sertata Stichel, 1910 syn. nov. is a new synonym of M. epaphus pyrrha Bates, 1868, and M. lecointrei P. Jauffret & J. Jauffret, 2008 syn. nov. is a new synonym of M. philonis Hewitson, 1874. Mesene margaretta (White, 1843), M. philonis and M. nola are recognized as closely related. Species encountered at the PNSD are illustrated, including the genitalia of males and females, when available.

  13. Response to Discussion of "Investigation of Oxide Bifilms in Investment Cast Superalloy IN100 Part I and II"

    Science.gov (United States)

    Kaplan, M. A.; Fuchs, G. E.

    2017-10-01

    In his most recent letter (Campbell in Met Trans A, 2017), Professor Campbell provides additional comments on Kaplan and Fuchs papers "Oxides Bifilms in Superalloy: IN100, Parts I and II (Met Trans A 47A:2346-2361, 2016; Met Trans A 47A:2362-2375, 2016) and on their response to his initial comments (Met Trans A 47A:3806-3809, 2016). In this recent submission, Campbell provides some very interesting thoughts on why bifilms were not observed by Kaplan and Fuchs and creates a new theory for the formation of defects referred to as bifilms. However, Campbell again provides no evidence to substantiate the presence of bifilms in Ni-base superalloys or his newly theorized mechanism. The vast majority of Campbell's comments are based solely on the re-interpretation of the photomicrographs and the data reported in the literature, including those presented by Kaplan and Fuchs (Met Trans A 47A:2346-2361, 2016; Met Trans A 47A:2362-2375, 2016). Campbell claims that bifilms are present throughout Ni-base superalloys, even though no one else has reported the presence of bifilms in Ni-base superalloys. In re-interpreting the data and images, Campbell ignores the extensive surface characterization results reported by Kaplan and Fuchs (Met Trans A 47A:2346-2361, 2016; Met Trans A 47A:2362-2375, 2016) that clearly indicate that there are no oxide films or bifilms on the fracture surfaces examined. Please note that this discussion of Campbell's most recent letter will be limited to Ni-base superalloys, since that is the subject of the research reported by Kaplan and Fuchs.

  14. Descriptions of the Structure and Ordering of Language in the Mod 2 Kindergarten Stories. Technical Note No. 2-72-34.

    Science.gov (United States)

    Fiege-Kollman, Laila

    A detailed description of the syntax in the Southwest Regional Laboratory (SWRL) Mod 2 Kindergarten stories is presented to aid in the formulation of comprehension assessment and instruction. The lexicon and surface structures of the sentences appearing in the stories were classified and tabled in terms of types of elements and functions. The new…

  15. Review of palaeozygopleurid gastropods (Palaeozygopleuridae, Gastropoda) from Devonian strata of the Perunica microplate (Bohemia), with a re-evaluation of their stratigraphic distribution, notes on their ontogeny, and descriptions of new taxa.

    Science.gov (United States)

    Frýda, Jiři; Ferrová, Lenka; Frýdová, Barbora

    2013-01-01

    Review of all species of the family Palaeozygopleuridae Horný, 1955 (Gastropoda) known from the Perunica microplate (Bohemia) is presented with a description of three new species, Palaeozygopleura lukesi sp. nov., Cimrmaniela sveraki gen. et sp. nov. and Cimrmaniela smoljaki gen. et sp. nov. The stratigraphic distributions of the most of Bohemian palaeozygopleurid species are either corrected or refined, based on new records or modern stratigraphic studies. A complete list of the geographic occurrences of all known palaeozygopleurid gastropods from the Perunica microplate is also given together with notes on their ontogeny.

  16. Description of a new species of Apterotoxitiades Adlbauer, 2008 (Cerambycidae, Dorcasominae, Apatophyseini and the female of A. vivesi Adlbauer, 2008, with notes on the biology of the genus

    Directory of Open Access Journals (Sweden)

    Karl Adlbauer

    2015-02-01

    Full Text Available Following the description of the Apatophyseini genus Apterotoxitiades Adlbauer, 2008 (Cerambycidae: Dorcasominae from South Africa, a new species has now been discovered in the eastern Drakensberg range of the country. The holotype female is here described as A. aspinosus Björnstad, sp. n. Also, a new small series collected at Hogsback, in the Amathole range, has allowed the description of the previously unknown female of the type species, A. vivesi Adlbauer, 2008. Both species are high altitude dwellers, occurring above 1300 m asl and their habitat consists mainly of mountain grassland interspersed with mistbelt forest pockets. All specimens were recorded in the austral winter to early spring, when these mountain ranges are occasionally covered in snow and night temperature plummet below 0 °C. They appear to be nocturnal and their complete lack of wings indicates a remarkable adaptation to cold conditions at high altitude.

  17. Notes sur les limaces 2. Description d’une espèce nouvelle de Gigantomilax provenant des environs de Kouldja (Chine)

    NARCIS (Netherlands)

    Regteren Altena, van C.O.

    1954-01-01

    Parmi les limaces non-identifiées du Musée Zoologique d’Amsterdam, que M. le Professeur Dr. H. Engel et Mme. W. S. S. van der Feen née van Benthem Jutting ont bien voulu me permettre d’étudier, il se trouvait une espèce nouvelle dont je donne ci-après la description. Gigantomilax (Turcomilax) iliens

  18. Annotated checklist of the Blennidus subgenus Agraphoderus species from Peru with description of B. bombonensis n. sp. and synonymic notes (Coleoptera: Carabidae: Pterostichinae).

    Science.gov (United States)

    Allegro, Gianni; Giachino, Pier Mauro

    2015-01-01

    Forty species belonging to the subgenus Agraphoderus of Blennidus have been recorded so far from Peru. An annotated checklist is provided with information about their type locality, distribution and habitat. The nomenclature of each species is also provided, together with some notes on their systematic status. Blennidus bombonensis n. sp. from Cerro de Pasco is described; Blennidus pseudangularis nomen novum for Ogmopleura angularis Straneo, 1993 (nec Straneo, 1985) is proposed and the following synonymies are stated: Blennidus pseudangularis Allegro & Giachino, nomen novum = Blennidus rectangulus (Straneo, 1993) syn. nov.; Ogmopleura minor Straneo, 1993 = Blennidus rectangulus (Straneo, 1993) syn. nov. Type specimens of most species are illustrated, as well as male genitalia. Finally, a revised key to all the Agraphoderus species from Peru is provided.

  19. Low-Cobalt Powder-Metallurgy Superalloy

    Science.gov (United States)

    Harf, F. H.

    1986-01-01

    Highly-stressed jet-engine parts made with less cobalt. Udimet 700* (or equivalent) is common nickel-based superalloy used in hot sections of jet engines for many years. This alloy, while normally used in wrought condition, also gas-atomized into prealloyed powder-metallurgy (PM) product. Product can be consolidated by hot isostatically pressing (HIPPM condition) and formed into parts such as turbine disk. Such jet-engine disks "see" both high stresses and temperatures to 1,400 degrees F (760 degrees C).

  20. Conditions Of Directional Solidification Affect Superalloy

    Science.gov (United States)

    Schmidt, D. D.; Alter, W. S.; Hamilton, W. D.; Parr, R. A.

    1992-01-01

    Report describes experiments to determine effects of gradient of temperature and rate of solidification on microstructure and fatigue properties of nickel-based superalloy MAR-M246(Hf). Enhancement of properties extends lifespans of objects, including turbo-pump blades of Space Shuttle Main Engines. Results indicate significant improvements in fatigue properties derived through manipulation of parameters of directional solidification. Particularly MAR-M246(Hf) for turbine blades contains small, well-dispersed blocky carbide and microstructure with small distances between dendrite arms, and without eutectic phase.

  1. Low Melt Height Solidification of Superalloys

    Science.gov (United States)

    Montakhab, Mehdi; Bacak, Mert; Balikci, Ercan

    2016-06-01

    Effect of a reduced melt height in the directional solidification of a superalloy has been investigated by two methods: vertical Bridgman (VB) and vertical Bridgman with a submerged baffle (VBSB). The latter is a relatively new technique and provides a reduced melt height ahead of the solidifying interface. A low melt height leads to a larger primary dendrite arm spacing but a lower mushy length, melt-back transition length, and porosity. The VBSB technique yields up to 38 pct reduction in the porosity. This may improve a component's mechanical strength especially in a creep-fatigue type dynamic loading.

  2. Stress rupture properties of GH4169 superalloy

    Directory of Open Access Journals (Sweden)

    Xudong Lu

    2014-04-01

    Full Text Available GH4169 alloy is a nickel-based superalloy extensively used in the aircraft engine industry because of its excellent mechanical properties and good fabrication ability. The mechanical properties of the GH4169 at high temperature, rupture stress under severe condition deserves a close attention. In this paper, the creep rupture of the GH4169 alloy under constant load and different temperatures from 550 °C to 700 °C conditions is systematically evaluated and major impact factors in the stress rupture behavior are analyzed. Furthermore, an improving method for the alloy stress rupture is proposed.

  3. A New Approach of Designing Superalloys for Low Density

    Science.gov (United States)

    MacKay, Rebecca A.; Gabb, Timothy P.; Smialek, James L.; Nathal, Michael V.

    2010-01-01

    New low-density single-crystal (LDS) alloy, have bee. developed for turbine blade applications, which have the potential for significant improvements in the thrust-to-weight ratio over current production superalloys. An innovative alloying strategy was wed to achieve alloy density reductions, high-temperature creep resistance, microstructural stability, and cyclic oxidation resistance. The alloy design relies on molybdenum as a potent. lower-density solid-solution strengthener in the nickel-based superalloy. Low alloy density was also achieved with modest rhenium levels tmd the absence of tungsten. Microstructural, physical mechanical, and environmental testing demonstrated the feasibility of this new LDS superalloy design.

  4. The genus Macrostemum Kolenati 1859 (Trichoptera: Hydropsychidae) in the Neotropical Region: Description of two new species, taxonomic notes, distributional records and key to males.

    Science.gov (United States)

    França, Diogo; Paprocki, Henrique; Calor, Adolfo R

    2013-01-01

    The genus Macrostemum Kolenati contains 105. described species, with 15 valid species in the Neotropical region. The Adults are recognized principally by wing membranes strongly marked with dark and light colors. The Neotropical species Of Macrostemum were described based on the wing colors patterns and body morphology. In this paper we present a taxonomic study of the Neotropical species, descriptions of two new species from Brazil, distributional records and a key to males. The male of Macrostemum negrense Flint 1978 is described for the first time, Names of three Neotropical species, M. ramosum (Navás 1916), M. trigramma (Navás 1916), and M. triste (Navás 1916) are designated nomina dubia.

  5. Notes on Electronic Lexicography

    CERN Document Server

    Parvanov, Yavor

    2011-01-01

    These notes are a continuation of topics covered by V. Selegej in his article "Electronic Dictionaries and Computational lexicography". How can an electronic dictionary have as its object the description of closely related languages? Obviously, such a question allows multiple answers.

  6. The Lasioseius phytoseioides species group (Acari: Blattisociidae): new characterisation, description of a new species, complementary notes on seven described species and a taxonomic key for the group.

    Science.gov (United States)

    De Moraes, Gilberto J; Abo-Shnaf, Reham I A; Pérez-Madruga, Yanebis; Sánchez, Leocadia; Karmakar, Krishna; Ho, Chyi-Chen

    2015-06-26

    The Lasioseius phytoseioides species group was first characterised over 50 years ago. Two species of this group, Lasioseius chaudhrii (Wu & Wang) and Lasioseius parberlesei Bhattacharyya, have been considered potentially effective as biological control agents of pest mites of the family Tarsonemidae on rice (Oryza sativa L.) in Asia. A new characterisation of the species group is presented, taking into account a new species here described, Lasioseius piracicabensis Moraes & Pérez-Madruga n. sp., as well as other species mostly described since the first characterisation of the group. The main characteristics of the included species are the reduced number of dorsal idiosomal setae, including the absence of j1 and z1; antiaxial surface of fixed cheliceral digit with a subterminal pointed process; and males with broad lateral expansion of the peritrematic shield in the region between coxae II-III, bearing a pore and a lyrifissure. Complementary notes are presented for Lasioseius annandalei Bhattacharyya & Bhattacharyya, Lasioseius chaudhrii (Wu & Wang), Lasioseius parberlesei Bhattacharyya, L. phytoseioides Chant, Lasioseius punjabensis Bhattacharyya & Sanyal, Lasioseius terrestris Menon & Ghai and Lasioseius youcefi Athias-Henriot. New synonymies are proposed and possible misidentifications in the literature are discussed. A dichotomous key is presented to help the identification of the species of the group, and the distribution of the species is summarised.

  7. Misfit in Inconel-Type Superalloy

    Directory of Open Access Journals (Sweden)

    Pavel Strunz

    2013-01-01

    Full Text Available An important parameter for the characterization of microstructural changes in nickel base superalloys is the misfit - the relative difference between lattice parameters of γ matrix and γ′ precipitates. The misfit in IN738LC superalloy was examined at POLDI time-of-flight (TOF neutron diffractometer both at room temperature and in situ at elevated temperatures using a high-temperature furnace. A careful out-of-furnace measurement yielded the lattice parameters of both γ and γ′ phase at room temperature (aγ=3.58611(10 Å, aγ′=3.58857(17 Å as well as the misfit (equal to 6.9(6×10-4. The in situ measurement at elevated temperatures provided the temperature dependence of the lattice parameters of γ (up to 1120°C and γ′ (up to 1000°C. Using these data, the evolution of the misfit with temperature was calculated. The misfit decreases with increasing temperature until it reaches zero value at a temperature around 800°C. Above 800°C, it becomes negative.

  8. Rediscovery and redescription of Coenagrion persicum (Lohmann 1993) with description of the female, and some notes on habitat selection (Odonata: Coenagrionidae).

    Science.gov (United States)

    Schneider, Thomas; Ikemeyer, Dietmar; Ferreira, Sónia; Müller, Ole

    2016-04-18

    Coenagrion persicum was described by Heinrich Lohmann in 1993 on the basis of a single male and two larvae captured in 1937 by E.W. Kaiser in Lorestãn Province (W-Iran). In June 2015 two of the authors (TS and DI) rediscovered individual-rich populations of this species in two Iranian provinces (Lorestãn and Esfahãn). We could confirm the structural differences of the male appendages between C. persicum and C. pulchellum based on a larger number of specimens than in the original description. The structural differences from C. pulchellum in females and their phenotypic variation pattern is described. Coenagrion persicum and C. pulchellum are also genetically distinct regarding two nDNA gene fragments: arginine methyltransferase (PRMT) and phosphoglucose isomerase (PGI). In contrast with C. pulchellum, C. persicum prefers small springs and running waters with rich herbal vegetation. Our faunistic data indicate that the species is present in the mountains between 1800 m and 2300 m a.s.l.. The species seems to be restricted to W-Iran, where it co-occurs with other rheophilic species.

  9. Modelling and simulation of superalloys. Book of abstracts

    Energy Technology Data Exchange (ETDEWEB)

    Rogal, Jutta; Hammerschmidt, Thomas; Drautz, Ralf (eds.)

    2014-07-01

    Superalloys are multi-component materials with complex microstructures that offer unique properties for high-temperature applications. The complexity of the superalloy materials makes it particularly challenging to obtain fundamental insight into their behaviour from the atomic structure to turbine blades. Recent advances in modelling and simulation of superalloys contribute to a better understanding and prediction of materials properties and therefore offer guidance for the development of new alloys. This workshop will give an overview of recent progress in modelling and simulation of materials for superalloys, with a focus on single crystal Ni-base and Co-base alloys. Topics will include electronic structure methods, atomistic simulations, microstructure modelling and modelling of microstructural evolution, solidification and process simulation as well as the modelling of phase stability and thermodynamics.

  10. Taxonomical and nomenclatural notes on Centaurea: A proposal of classification, a description of new sections and subsections, and a species list of the redefined section Centaurea

    Directory of Open Access Journals (Sweden)

    Hilpold, A.

    2014-12-01

    Full Text Available In this paper, we summarize the results of our long-date research on the genus Centaurea. The first part of the paper deals with the overall classification of the genus, which we propose to divide into three subgenera: subgenus Centaurea, subgenus Cyanus and subgenus Lopholoma. The second part of this publication gives a recopilation of the species of the redefined section Centaurea, a group that includes former sections Acrolophus (sect. Centaurea s. str., Phalolepis and Willkommia, together with taxonomical, geographical, ecological and karyological considerations. Finally, new descriptions or nomenclatural combinations are proposed to correlate nomenclature to the new classification: a new combination (sect. Acrocentron subsect. Chamaecyanus is proposed in subgenus Lopholoma; three new sections (sects. Akamantis, Cnicus, and Hyerapolitanae are described in subgenus Centaurea; two subsections (subsects. Phalolepis and Willkommia in sect. Centaurea; and three subsections (subsects. Exarata, Jacea, and Subtilis in sect. Phrygia.En este trabajo presentamos los resultados de nuestras investigaciones de larga fecha en el género Centaurea. La primera parte del trabajo trata de la clasificación del género, que proponemos dividir en tres subgéneros: subgénero Centaurea, subgénero Cyanus y subgénero Lopholoma. La segunda parte es una recopilación de las especies de la redefinida sección Centaurea, que incluye las antiguas secciones Acrolophus (sect. Centaurea s. str., Phalolepis y Willkommia, junto con consideraciones geográficas, ecológicas y cariológicas. Por último, proponemos nuevas secciones, subsecciones y combinaciones para correlacionar nomenclatura y clasificación: proponemos una nueva (sect. Acrocentron subsect. Chamaecyanus en el subgénero Lopholoma; se describen tres secciones nuevas (sects. Akamantis, Cnicus y Hyerapolitanae en el subgénero Centaurea; dos subsecciones (subsects. Phalolepis and Willkommia en la secci

  11. A new approach to develop complicated superalloy castings

    Institute of Scientific and Technical Information of China (English)

    WU Jian-tao; FENG Di; LI Jun-tao; KONG Sheng-guo; PEI Zhong-ye

    2006-01-01

    An integrative computer aided investment casting (CAIC) technology for making complicated superalloy castings was described. Key processes of CAIC were discussed including the choice of SLS (Selectively Laser Sinterihg)materials, sintering parameters, solidification simulation and gating and risering system optimization. Using CAIC process,many large-sized quality superalloy castings with complicated shape and thin wall have been produced successfully and economically in Central Iron & steel Research Institute (CISRI).

  12. A new approach to develop complicated superalloy castings

    Directory of Open Access Journals (Sweden)

    WU Jian-tao

    2006-05-01

    Full Text Available An integrative computer aided investment casting (CAIC technology for making complicated superalloy castings was described. Key processes of CAIC were discussed including the choice of SLS (Selectively Laser Sintering materials, sintering parameters, solidification simulation and gating and risering system optimization. Using CAIC process, many large-sized quality superalloy castings with complicated shape and thin wall have been produced successfully and economically in Central Iron & steel Research Institute (CISRI.

  13. Hot deformation behavior of FGH96 superalloys

    Institute of Scientific and Technical Information of China (English)

    Jiantao Liu; Guoquan Liu; Benfu Hu; Yuepeng Song; Ziran Qin; Yiwen Zhang

    2006-01-01

    The hot deformation behavior of FGH96 superalloys at 1070-1170℃ and 5×10-4-2×10-1 s-1 were investigated by means of the isothermal compression tests at a Gleeble-1500 thermal mechanical simulator. The results show that dynamic recovery acts as the main softening mechanism below 2×10-3 s-1, whereas dynamic recrystallization acts as the main softening mechanism above 2×10-3 s-1during deformation; the temperature increase caused by the deformation and the corresponding softening stress is negligible; the thermal-mechanical constitutive model to describe the hot deformation behavior is given, and the value of the apparent deformation activation energy (Qdef) is determined to be 354.93 kJ/mol.

  14. Creep Behaviour of Modified Mar-247 Superalloy

    Directory of Open Access Journals (Sweden)

    Cieśla M.

    2016-06-01

    Full Text Available The paper presents the results of analysis of creep behaviour in short term creep tests of cast MAR-247 nickel-based superalloy samples made using various modification techniques and heat treatment. The accelerated creep tests were performed under temperature of 982 °C and the axial stresses of σ = 150 MPa (variant I and 200 MPa (variant II. The creep behaviour was analysed based on: creep durability (creep rupture life, steady-state creep rate and morphological parameters of macro- and microstructure. It was observed that the grain size determines the creep durability in case of test conditions used in variant I, durability of coarse-grained samples was significantly higher.

  15. Hardening anisotropy of {gamma}/{gamma}{prime} superalloy single crystals. 1: Experimental estimates at 650 C from a homogeneous analysis

    Energy Technology Data Exchange (ETDEWEB)

    Hoinard, G.; Estevez, R.; Franciosi, P. [Univ. Paris Nord, Villetaneuse (France)

    1995-04-01

    The hardening anisotropy, in quasi static loading, of {gamma}/{gamma}{prime} superalloy single crystals is experimentally investigated and analyzed according to a description of crystal hardening at the dislocation density and interaction scale, and regardless of the two-phase nature of the material. A matrix of hardening coefficients is estimated from monotonous and sequential loadings at 650 C on <001>, <011>, <111> oriented samples of two different alloys with similar compositions and structures. This hardening analysis distinguishes three types of slip systems all having the <110> type slip direction: octahedral systems with an easy or an uneasy dislocation motion direction, and cubic systems. The estimated interactions between these system pairs separate, within each of the three system groups, a coplanar (including self interaction) coefficient with a non coplanar one. As a whole, the superalloy single crystal hardening anisotropy at this medium temperature comes out comparable to one of the most anisotropic pure f.c.c. metals, mainly because of the hardening asymmetry on the octahedral systems. If the asymmetry is averaged, the remaining anisotropy falls down to the anisotropy level of high stacking fault energy f.c.c. metals. These quantitative estimates are limited by the questionable assumption of homogeneous behavior for such a two-phase crystal structure. Analyses accounting for both the crystalline structure and the two-phase nature of these superalloys will be the purpose of the forthcoming Part 2.

  16. Notes on Piezoelectricity

    Energy Technology Data Exchange (ETDEWEB)

    Redondo, Antonio [Los Alamos National Lab. (LANL), Los Alamos, NM (United States)

    2016-02-03

    These notes provide a pedagogical discussion of the physics of piezoelectricity. The exposition starts with a brief analysis of the classical (continuum) theory of piezoelectric phenomena in solids. The main subject of the notes is, however, a quantum mechanical analysis. We first derive the Frohlich Hamiltonian as part of the description of the electron-phonon interaction. The results of this analysis are then employed to derive the equations of piezoelectricity. A couple of examples with the zinc blende and and wurtzite structures are presented at the end

  17. Project Notes

    Science.gov (United States)

    School Science Review, 1978

    1978-01-01

    Presents sixteen project notes developed by pupils of Chipping Norton School and Bristol Grammar School, in the United Kingdom. These Projects include eight biology A-level projects and eight Chemistry A-level projects. (HM)

  18. Safety Note

    CERN Multimedia

    SC Secretariat

    2004-01-01

    Please note that the Safety Note no 29 (NS 29) entitled 'Fire Prevention for Insulating Core (Sandwich) Panel Structures for Inside Use Guidelines for Selection, Installation and Use' is available on the web at the following url: https://edms.cern.ch/document/475438/LAST_RELEASED Paper copies can also be obtained from the SC Unit secretariat, e-mail : sc.secretariat@cern.ch SC Secretariat

  19. Hot Corrosion of Coated Single Crystal Superalloys

    Energy Technology Data Exchange (ETDEWEB)

    Simms, N. J.; Encinas-Oropesa, A.; Nicholls, J.R. [Cranfield University, Power Generation Technology Centre, Cranfield, Beds, MK43 0AL (United Kingdom)

    2004-07-01

    Gas turbines are at the heart of many modern power systems, with combined cycle power generation utilising natural gas being an effective way of reducing environmental emissions compared to conventional pulverized coal fired plants. The development of gas turbine technology has been focused on increasing its efficiency. However, the lives of the hot gas path components within these gas turbines are also critical to the viability of the power systems. Single crystal superalloys have been developed for use with clean fuel/air but are now being used in industrial gas turbines that may need to run with dirtier fuel/air. Indeed, gas turbine based power systems are being evaluated in which solid fuels (e.g. coal and/or biomass) are gasified to produce fuel gases, which introduces the potential for significant corrosive and erosive damage to gas turbine blades and vanes. The performance of these materials, with coatings, has to be determined before they can be used with confidence in dirtier fuel environments. This paper reports results from a series of laboratory tests carried out using the 'deposit replenishment' technique to investigate the sensitivity of candidate materials to exposure conditions anticipated in such gas turbines. The materials investigated have included CMSX-4 and SC{sup 2}-B (both bare and with Pt-Al and Amdry 997 coatings) as well as conventional nickel based superalloys such as IN738LC for comparison. The exposure conditions within the laboratory tests have covered ranges of SO{sub x} (50 and 500 vpm) and HCl (0 and 500 vpm) in air, as well as 4/1 (Na/K){sub 2}SO{sub 4} deposits, with deposition fluxes of 1.5, 5 and 15 {mu}g/cm{sup 2}/h, for periods of up to 500 hours at 700 and 900 deg. C. Data on the performance of materials has been obtained using dimensional metrology: pre-exposure contact measurements and post-exposure measurements of features on polished cross-sections. These measurement methods allow distributions of damage data to

  20. SAFETY NOTES

    CERN Document Server

    TIS Secretariat

    2001-01-01

    Please note that the revisions of safety notes no 3 (NS 3 Rev. 2) and no 24 (NS 24 REV.) entitled respectively 'FIRE PREVENTION FOR ENCLOSED SPACES IN LARGE HALLS' and 'REMOVING UNBURIED ELV AND LVA ELECTRIC CONDUITS' are available on the web at the following urls: http://edmsoraweb.cern.ch:8001/cedar/doc.download?document_id=322811&version=1&filename=version_francaise.pdf http://edmsoraweb.cern.ch:8001/cedar/doc.download?document_id=322861&version=2&filename=version_francaise.pdf Paper copies can also be obtained from the TIS Divisional Secretariat, email tis.secretariat@cern.ch

  1. Advanced Ni base superalloys for small gas turbines

    Energy Technology Data Exchange (ETDEWEB)

    Wahl, J.B.; Harris, K.

    2011-07-15

    Nickel base superalloy materials have extensive applications in the hot turbine section of aero and industrial gas turbine engines. They provide a unique combination of characteristics suitable for higher temperature strength and durability requirements and are also applicable to small turbine and missile engines. Specific considerations pertinent to selection of superalloys for small gas turbine engines include not only overall mechanical properties, but also the changes in properties over time due to operation, reduction in properties for thin wall applications compared to thick section database values, alloy density and the effect on disc and shaft alloy selection, and always, material/component costs. Nickel base superalloys were first introduced into military gas turbine engines during the Second World War and the technology has advanced dramatically since that time, including conventionally cast equiax (EQ) alloys, directionally solidified (DS) and single crystal (SX) cast components. This paper discusses the characteristics and applications of each casting technology.

  2. Deformation Behavior of Hot Isostatic Pressing FGH96 Superalloy

    Institute of Scientific and Technical Information of China (English)

    LIU Yuhong; LI Fuguo; YU Hongbo

    2006-01-01

    The deformation behavior of hot isostatic pressing (HIP) FGH96 superalloy was characterized in the temperature range of 1 000-1 100 ℃ and strain rate range of 0. 001-0.1 s-1 using hot compression testing. The flow curves of HIP FGH96 superalloy during hot deformation was analyzed systematically. The results show that deformation temperature, strain rate and strain are the main influence factors on flow stress of HIP FGH96 superalloy during hot deformation. The flow stress displays a peak at a critical strain and then decreases with further increase in strain. For a given strain, the flow stress decreases with the increase of deformation temperature, and increases with the increase of strain rate. A mathematical model of these flow curves was established through regression analysis and taking the strain as a modification factor. The calculated stress values agree well with the experimental values.

  3. Editors’ Notes

    Institute of Scientific and Technical Information of China (English)

    2007-01-01

    This volume contains three parts; symposium, articles, and notes. People’ s Assessor System is an assessor system with Chinese unique character. From the perspective of its historical development and function in reality, it is different from both the jury system of the common law system and the assessor system of the civil law system. Its making and development varied with the contemporary po-

  4. Editor's note

    Science.gov (United States)

    Umapathy, Siva

    2017-01-01

    This is an editor's note related to the publication 'Biologically active and thermally stable polymeric Schiff base and its metal polychelates: Their synthesis and spectral aspects' by Raza Rasool and Sumaiya Hasnain, which appeared in Spectrochimica Acta Part A: Molecular and Biomolecular Spectroscopy 148 (2015) 435-443.

  5. Please note

    CERN Multimedia

    2006-01-01

    Members of the personnel are invited to take note that only parcels corresponding to official orders or contracts will be handled at CERN. Individuals are not authorised to have private merchandise delivered to them at CERN and private deliveries will not be accepted by the Goods Reception services. Thank you for your understanding. (Version française la semaine prochaine.)

  6. Biology Notes.

    Science.gov (United States)

    School Science Review, 1984

    1984-01-01

    Presents information on the teaching of nutrition (including new information relating to many current O-level syllabi) and part 16 of a reading list for A- and S-level biology. Also includes a note on using earthworms as a source of material for teaching meiosis. (JN)

  7. Editorial note

    Directory of Open Access Journals (Sweden)

    Tore Ahlbäck

    2012-01-01

    Full Text Available Editorial note of Scripta Instituti Donneriani Aboensis, vol. 24, Post-Secular Religious Practices, based on papers read at the symposium on Post-Secular Practices held at Åbo/Turku, Finland, on 15-17 June 2011.

  8. Editor's Notes.

    Science.gov (United States)

    Smetana, Judith G.

    1994-01-01

    Introduces the articles in this journal issue, noting the burgeoning interest in the roots of parental beliefs, values, and goals. Highlights thematic continuities among the otherwise diverse research approaches presented, for example, synthesis of different theoretical perspectives of parent beliefs, or the context in which parental beliefs…

  9. Evaluation of powder metallurgy superalloy disk materials

    Science.gov (United States)

    Evans, D. J.

    1975-01-01

    A program was conducted to develop nickel-base superalloy disk material using prealloyed powder metallurgy techniques. The program included fabrication of test specimens and subscale turbine disks from four different prealloyed powders (NASA-TRW-VIA, AF2-1DA, Mar-M-432 and MERL 80). Based on evaluation of these specimens and disks, two alloys (AF2-1DA and Mar-M-432) were selected for scale-up evaluation. Using fabricating experience gained in the subscale turbine disk effort, test specimens and full scale turbine disks were formed from the selected alloys. These specimens and disks were then subjected to a rigorous test program to evaluate their physical properties and determine their suitability for use in advanced performance turbine engines. A major objective of the program was to develop processes which would yield alloy properties that would be repeatable in producing jet engine disks from the same powder metallurgy alloys. The feasibility of manufacturing full scale gas turbine engine disks by thermomechanical processing of pre-alloyed metal powders was demonstrated. AF2-1DA was shown to possess tensile and creep-rupture properties in excess of those of Astroloy, one of the highest temperature capability disk alloys now in production. It was determined that metallographic evaluation after post-HIP elevated temperature exposure should be used to verify the effectiveness of consolidation of hot isostatically pressed billets.

  10. Metallurgical optimisation of PM superalloy N19

    Directory of Open Access Journals (Sweden)

    Locq Didier

    2014-01-01

    Full Text Available Microstructures of the new PM superalloy N19 have been investigated for various heat treatments in order to reach the best compromise between static strength and cyclic resistance. One subsolvus and several supersolvus heat treatments were applied to produce fine (7 μm and medium (25 μm grain sizes, respectively. The alloy is shown to be quite sensitive to the cooling conditions after solutioning as the γ′ hardening precipitates, both secondary and tertiary, have a direct influence on mechanical properties. Two cooling conditions after solutioning produce a high crack propagation resistance at 650 °C with dwell time cycles, which is one of the basic requirements. The low cycle fatigue behaviour appears to be correlated to the grain size, which determines the origin of crack initiation (from ceramic inclusions or not. The other mechanical properties (tensile, creep remain above target levels. Despite the medium size grain microstructure in the supersolvus condition, a high level of mechanical strength is observed in N19 at elevated temperature. It is understood that further improvement in properties can be achieved by developing coarse grain microstructures.

  11. Metallurgical modelling of superalloy disc isothermal forgings

    Science.gov (United States)

    Evans, R. W.

    1988-08-01

    The metallurgical structure of superalloy aeroengine disc forgings is a complex function of the forging operation parameters and the post forging heat treatment. It is often desirable to obtain certain specific structures in parts of the disc which are, for instance, resistant to crack propagation and this has traditionally been accomplished by means of a series of production trials. This expensive and time consuming procedure can be considerably shortened if the development of microstructure during the forging can be accurately modelled by a suitable computer code. Described here is such a model and its use in the design of isothermal forged components. The model discribed is a fully thermally coupled viscoplasticity finite element algorithm. It treats nodal velocities as the basic unknowns and both the mesh geometry and the various metallurgical structural terms are updated by a single step Euler scheme. Facilities are available for ensuring that surface nodes follow die shapes after impingement, that flow is incompressible and that suitable surface friction forces are applied. Throughout the whole forging process (which may involve the re-meshing of severely distorted elements), the metallurgical history of elements is retained so that the effects of subsequent heat treatments can be assessed.

  12. Lubrication in Hot Tube Extrusion of Superalloys and Ti Alloys

    Institute of Scientific and Technical Information of China (English)

    2001-01-01

    Tubular products made of superalloys and titanium alloys usually work in high temperature environment and applied heavy loading. Hot extrusion is the best technology to form tubular billets with fine microstructures and good mechanical properties. Lubrication is one of the key techniques in hot extrusion, glass lubricants are most suitable for hot extrusion. Lubrication technique in hot extrusion is dealt with in this paper, the lubrication principle of hot tube extrusion is presented. Experiments of glass lubricated backward tube extrusion of titanium alloys and forward tube extrusion of superalloys are also discussed.

  13. Solidification microstructure of directionally solidified superalloy under high temperature gradient

    Institute of Scientific and Technical Information of China (English)

    2012-01-01

    The effect of solidification rate on the microstructure development of nickel-based superalloy under the temperature gradient of 500 K·cm-1 was studied. The results show that, with the increase of directional solidification rate from 50 to 800 μm·s-1, both the primary and the secondary dendrite arm spacings of the alloy decrease gradually, and the dendrite morphologies transform from coarse dendrite to superfine dendrite. The sizes of all precipitates in the superalloy decrease gradually. The morphology of ...

  14. Recrystallizaiton Behavior of Directionally Solidified DZ4 Superalloy

    Institute of Scientific and Technical Information of China (English)

    Li Yun-ju; Zhang Wei-fang; Tao Chun-hu

    2004-01-01

    This article investigated effects of degrees of deformation, heat treatment temperatures and holding times on the recrystallization behavior of directionally solidified DZ4 superalloy. The results showed that, recrystallization of DZ4 superalloy could take place during solution heat treatment after certain degrees of cold work and depths of recrystallization increased with increasing degrees of deformation and heat treatment temperature. At the temperature below γ' solvus,prolonged holding times did not play an important role in improving recrystallization depths. Moreover, prevention measures for recrystallization of directionally solidified blades were given.

  15. Application note :

    Energy Technology Data Exchange (ETDEWEB)

    Russo, Thomas V.

    2013-08-01

    The development of the XyceTM Parallel Electronic Simulator has focused entirely on the creation of a fast, scalable simulation tool, and has not included any schematic capture or data visualization tools. This application note will describe how to use the open source schematic capture tool gschem and its associated netlist creation tool gnetlist to create basic circuit designs for Xyce, and how to access advanced features of Xyce that are not directly supported by either gschem or gnetlist.

  16. Continuous Extraction of Nickel from Superalloy Scraps Using Zinc Circulation

    Science.gov (United States)

    Yagi, Ryohei; Okabe, Toru H.

    2017-02-01

    A novel technique for the continuous extraction of nickel (Ni) from Ni-based superalloy scraps using molten zinc (Zn) has been proposed, and its feasibility was experimentally demonstrated. The newly developed approach allows for extraction of Ni metal directly from superalloy scraps with simultaneous separation of the Zn from the resulting Zn-Ni alloy. The optimal conditions for the extraction of Ni and separation of valuable elements such as rhenium (Re), tantalum (Ta), and tungsten (W) were determined by varying major process parameters including the reaction time and configuration of the reaction chamber. The proposed method has been successfully utilized for the production of the superalloy containing 62.8 mass pct of Ni and 15.5 mass pct of refractory metals (Re, W, and Ta). Under certain conditions, 41 pct of the Ni contained in the superalloy could be extracted at 1173 K (900 °C) over 48 hours, producing an alloy containing 84.0 mass pct of Ni and 0.2 mass pct of the refractory metals.

  17. Deformation, fatigue and fracture behavior of two cast anisotropic superalloys

    Science.gov (United States)

    Milligan, Walter W.; Huron, Eric S.; Antolovich, Stephen D.

    1987-01-01

    Tensile and low cycle fatigue (LCF) tests were conducted on two cast anisotropic superalloys. The effects of temperature, strain rate and stress range were investigated. Deformation behavior was extensively characterized and modeled. LCF and fracture behavior were studied and correlated with deformation behavior.

  18. Nickel-Based Superalloy Resists Embrittlement by Hydrogen

    Science.gov (United States)

    Lee, Jonathan; Chen, PoShou

    2008-01-01

    A nickel-based superalloy that resists embrittlement by hydrogen more strongly than does nickel alloy 718 has been developed. Nickel alloy 718 is the most widely used superalloy. It has excellent strength and resistance to corrosion as well as acceptably high ductility, and is recognized as the best alloy for many high-temperature applications. However, nickel alloy 718 is susceptible to embrittlement by hydrogen and to delayed failure and reduced tensile properties in gaseous hydrogen. The greater resistance of the present nickel-based superalloy to adverse effects of hydrogen makes this alloy a superior alternative to nickel alloy 718 for applications that involve production, transfer, and storage of hydrogen, thereby potentially contributing to the commercial viability of hydrogen as a clean-burning fuel. The table shows the composition of the present improved nickel-based superalloy in comparison with that of nickel alloy 718. This composition was chosen to obtain high resistance to embrittlement by hydrogen while maintaining high strength and exceptional resistance to oxidation and corrosion. The most novel property of this alloy is that it resists embrittlement by hydrogen while retaining tensile strength greater than 175 kpsi (greater than 1.2 GPa). This alloy exhibits a tensile elongation of more than 20 percent in hydrogen at a pressure of 5 kpsi (approximately equal to 34 MPa) without loss of ductility. This amount of elongation corresponds to 50 percent more ductility than that exhibited by nickel alloy 718 under the same test conditions.

  19. 76 FR 8773 - Superalloy Degassed Chromium From Japan

    Science.gov (United States)

    2011-02-15

    ... From the Federal Register Online via the Government Publishing Office INTERNATIONAL TRADE COMMISSION Superalloy Degassed Chromium From Japan AGENCY: United States International Trade Commission... Japan would be likely to lead to continuation or recurrence of material injury. On December 22, 2010...

  20. Revision Notes

    CERN Document Server

    Matthewson, Siobhan; Debbadi, Margaret

    2012-01-01

    Revision Notes: CCEA ICT for GCSE has been written by experienced teachers and examiners so that you can be confident that it covers only the facts and ideas you will be expected to recall and use in the exam. - Essential facts are carefully organised to make revising easier. - Exams tips show you how to avoid losing marks and get the best grade. - Check your understanding questions support you in the run-up to the exams, with answers provided free online at www.hodderplus.co.uk. This book will help you plan and pace your revision to suit your learning needs and can be integrated with other re

  1. Automated Identification and Characterization of Secondary & Tertiary gamma’ Precipitates in Nickel-Based Superalloys (PREPRINT)

    Science.gov (United States)

    2010-01-01

    METHODOLOGY A nickel-based superalloy sample (Rene88DT) was cut from a forged disc developed under a Defense Advanced Research Projects Agency funded...AFRL-RX-WP-TP-2010-4064 AUTOMATED IDENTIFICATION AND CHARACTERIZATION OF SECONDARY & TERTIARY γ’ PRECIPITATES IN NICKEL-BASED SUPERALLOYS ...AUTOMATED IDENTIFICATION AND CHARACTERIZATION OF SECONDARY & TERTIARY γ’ PRECIPITATES IN NICKEL-BASED SUPERALLOYS (PREPRINT) 5a. CONTRACT NUMBER In

  2. Lecture Notes

    DEFF Research Database (Denmark)

    Bak, Thomas

    information sources such as vision, hearing and balance are combined to determine position and plan a path to a goal. While the concept of data fusion is not new, the emergence of new sensors, advanced processing techniques, and improved processing hardware make real-time fusion of data increasingly possible....... Despite advances in electronic components, however, developing data processing applications such as automatic guidance systems has proved difficult. Systems that are in direct contact and interact with the real world, require reliable and accurate information about their environment. This information......This note discusses multi-sensor fusion. Through sensor fusion we may combine readings from different sensors, remove inconsistencies and combine the information into one coherent structure. This kind of processing is a fundamental feature of all animal and human navigation, where multiple...

  3. Effect of Electromagnetic Stirring on the Quality of K417 Superalloy Ingots

    Institute of Scientific and Technical Information of China (English)

    Jin; Wenzhong; Li; Tingju; Yin; Guomao

    2007-01-01

    The effect of electromagnetic stirring on the inner quality of K417 superalloy ingots is studied with EPMA and optical microscope.The results show that while an electromagnetic stirring with 50Hz frequency and 80A current is imposed,the equiax crystals of K417 superalloy ingots can be effectively refined and increased,and the central shrinkage porosity and the dendritic segregation of K417 superalloy ingots are greatly reduced,so the inner quality of K417 superalloy ingots is obviously improved.

  4. Recent trends in superalloys research for critical aero-engine components

    Energy Technology Data Exchange (ETDEWEB)

    Remy, Luc [Mine ParisTech, CNRS UMR 7633, 91 - Evry (France). Centre des Materiaux; Guedou, Jean-Yves [Snecma Safran Group, Moissy-Cramayel (France). Materials and Processes Dept.

    2010-07-01

    This paper is a brief survey of common research activity on superalloys for aero-engines between Snecma and Mines ParisTech Centre des Materiaux during recent years. First in disks applications, the development of new powder metallurgy superalloys is shown. Then grain boundary engineering is investigated in a wrought superalloy. Secondly, design oriented research on single crystals blades is shown: a damage model for low cycle fatigue is used for life prediction when cracks initiated at casting pores. The methodology developed for assessing coating life is illustrated for thermal barrier coating deposited on AMI single crystal superalloy. (orig.)

  5. Note & Recensioni

    Directory of Open Access Journals (Sweden)

    2014-12-01

    Full Text Available VolumiVito Campanelli, Web Aesthetics. How Digital Media Affect Culture and Society; Id., Remix It Yourself. Analisi socio-estetica delle forme comunicative del Web [Emanuele Crescimanno] • Jean-François Bordron, Image et vérité. Essais sur les dimensions iconiques de la connaissance [Veronica Estay Stange] • Stéphane Dumas, Les peaux créatrices – Esthétique de la sécrétion [Marc-Vincent Howlett]NoteQuidam veritatis effectus. A proposito di A Plea for Balance in Philosophy. Essays in honour of Paolo Parrini [Fabrizio Desideri] • A Single Face to Capture the Whole World: Literary Shapes and Shadows. An Interview With Tolm Coibin [Fabrizia Abbate] •Convegno Le sensible a l’oeuvre: savoirs du corps entre esthetique et neurosciences, Parigi, 15 Maggio 2014 [Jessica Murano] 

  6. Editorial Note

    Science.gov (United States)

    van der Meer, F.; Ommen Kloeke, E.

    2015-07-01

    With this editorial note we would like to update you on the performance of the International Journal of Applied Earth Observation and Geoinformation (JAG) and inform you about changes that have been made to the composition of the editorial team. Our Journal publishes original papers that apply earth observation data for the management of natural resources and the environment. Environmental issues include biodiversity, land degradation, industrial pollution and natural hazards such as earthquakes, floods and landslides. As such the scope is broad and ranges from conceptual and more fundamental work on earth observation and geospatial sciences to the more problem-solving type of work. When I took over the role of Editor-in-Chief in 2012, I together with the Publisher set myself the mission to position JAG in the top-3 of the remote sensing and GIS journals. To do so we strived at attracting high quality and high impact papers to the journal and to reduce the review turnover time to make JAG a more attractive medium for publications. What has been achieved? Have we reached our ambitions? We can say that: The submissions have increased over the years with over 23% for the last 12 months. Naturally not all may lead to more papers, but at least a portion of the additional submissions should lead to a growth in journal content and quality.

  7. Broaching Performance of Superalloy GH4169 Based on FEM

    Institute of Scientific and Technical Information of China (English)

    Xiangwei Kong; Bin Li; Zhibo Jin; Wenran Geng

    2011-01-01

    The nickel-based superalloy GH4169 is an important material for high temperature applications in the aerospace industry. However, due to its poor machinability, GH4169 is hard to be cut and generates saw-tooth chips during high speed machining, which could significantly affect the dynamic cutting force, cutting temperature fluctuation, tool life, and the surface integrity of the parts. In this paper, the saw-tooth chip formation mechanism of superalloy GH4169 was investigated by the elasto-viscoplastic finite element method (FEM). Using the finite element software of ABAQUS/Explicit, the deformation of the part during high speed machining was simulated. The effective plastic strain, the temperature field, the stress distribution, and the cutting force were analyzed to determine the influence of the cutting parameters on the saw-tooth chip formation. The study on broaching performance has great effect on selecting suitable machining parameters and improving tool life.

  8. Feasibility Study for Casting of High Temperature Refractory Superalloy Composites

    Science.gov (United States)

    Lee, Jonathan A.

    1998-01-01

    Abstract This study investigated the feasibility of using conventional casting technique to fabricate refractory wires reinforced superalloy composites. These composites were being developed for advanced rocket engine turbine blades and other high temperature applications operating up to 2000 F. Several types of refractory metal wires such as W- Th, W-Re, Mo-Hf-C and W-HF-C reinforced waspaloy were experimentally cast and heat treated at 2000 F up to 48 hrs. Scanning electron microscope analysis was conducted in regions adjacent to the wire-matrix interface to determine the reaction zone and chemical compatibility resulting from material interdiffusion. It was concluded that fabrication using conventional casting may be feasible because the wire-matrix reaction zone thickness was comparable to similar composites produced by arc-sprayed monotape with hot isostatic pressing technique, Moreover, it was also found that the chemical compatibility could be improved significantly through a slight modification of the superalloy matrix compositions.

  9. Surface modification, microstructure and mechanical properties of investment cast superalloy

    OpenAIRE

    M. Zielińska; Kubiak, K.; J. Sieniawski

    2009-01-01

    Purpose: The aim of this work is to determine physical and chemical properties of cobalt aluminate (CoAl2O4) modifiers produced by different companies and the influence of different types of modifiers on the grain size, the microstructure and mechanical properties of high temperature creep resisting superalloy René 77.Design/methodology/approach: The first stage of the research work took over the investigations of physical and chemical properties of cobalt aluminate manufactured by three diff...

  10. Potential of Metal-Matrix Composites as Superalloy Substitutes

    Science.gov (United States)

    1984-04-01

    Engine Construction. Towards a Cycle without Loss: Cobalt in the Aircraft Industry. Gas Turbine Engine Design Considerations as Related to Alloys of...Developments to Reduce Strategic Materials Usage. Practical Implications of the Use of Alumlnlde Coatings for the Corrosion Protection of Superalloys in Gas ...Aaroapatlalas (ONERA) BP72, 92)22 Chatlllon, Cadax, Franca ABSTRACT ’The potential of metal-matrlx coaposltas aa qaa- turbina blada material« has

  11. Constitutive Equation of Superalloy In718 in Hammer Forging Process

    Institute of Scientific and Technical Information of China (English)

    2001-01-01

    A constitutive equation reflecting the flow behavior ofSuperalloy In718 during the counter-blow hammer forging process was developed in terms of the relationship of flow stress and hot-deformation parameters, such as strain, strain rate, and deformation temperature. A new simplified approach for the complex multi-pass stress-strain curves has been attempted. The simulation curves calculated by constitutive equation are consistent with the experimental data.

  12. Interfacial dislocation motion and interactions in single-crystal superalloys

    Energy Technology Data Exchange (ETDEWEB)

    Liu, B. [Lawrence Livermore National Lab. (LLNL), Livermore, CA (United States); Raabe, D. [Max Planck Inst. fur Eisenforshung. Dusseldorf (Germany); Roters, F. [Max Planck Inst. fur Eisenforshung. Dusseldorf (Germany); Arsenlis, A. [Lawrence Livermore National Lab. (LLNL), Livermore, CA (United States)

    2014-10-01

    The early stage of high-temperature low-stress creep in single-crystal superalloys is characterized by the rapid development of interfacial dislocation networks. Although interfacial motion and dynamic recovery of these dislocation networks have long been expected to control the subsequent creep behavior, direct observation and hence in-depth understanding of such processes has not been achieved. Incorporating recent developments of discrete dislocation dynamics models, we simulate interfacial dislocation motion in the channel structures of single-crystal superalloys, and investigate how interfacial dislocation motion and dynamic recovery are affected by interfacial dislocation interactions and lattice misfit. Different types of dislocation interactions are considered: self, collinear, coplanar, Lomer junction, glissile junction, and Hirth junction. The simulation results show that strong dynamic recovery occurs due to the short-range reactions of collinear annihilation and Lomer junction formation. The misfit stress is found to induce and accelerate dynamic recovery of interfacial dislocation networks involving self-interaction and Hirth junction formation, but slow down the steady interfacial motion of coplanar and glissile junction forming dislocation networks. The insights gained from these simulations on high-temperature low-stress creep of single-crystal superalloys are also discussed.

  13. Phase transformation strengthening of high-temperature superalloys

    Science.gov (United States)

    Smith, T. M.; Esser, B. D.; Antolin, N.; Carlsson, A.; Williams, R. E. A.; Wessman, A.; Hanlon, T.; Fraser, H. L.; Windl, W.; McComb, D. W.; Mills, M. J.

    2016-11-01

    Decades of research has been focused on improving the high-temperature properties of nickel-based superalloys, an essential class of materials used in the hot section of jet turbine engines, allowing increased engine efficiency and reduced CO2 emissions. Here we introduce a new `phase-transformation strengthening' mechanism that resists high-temperature creep deformation in nickel-based superalloys, where specific alloying elements inhibit the deleterious deformation mode of nanotwinning at temperatures above 700 °C. Ultra-high-resolution structure and composition analysis via scanning transmission electron microscopy, combined with density functional theory calculations, reveals that a superalloy with higher concentrations of the elements titanium, tantalum and niobium encourage a shear-induced solid-state transformation from the γ' to η phase along stacking faults in γ' precipitates, which would normally be the precursors of deformation twins. This nanoscale η phase creates a low-energy structure that inhibits thickening of stacking faults into twins, leading to significant improvement in creep properties.

  14. Property Enrichment of Aged Nickel Base Superalloy Supercast 247A

    Directory of Open Access Journals (Sweden)

    Lavakumar Avala

    2013-12-01

    Full Text Available The commercial nickel-base superalloy Supercast 247A can be used for applications in which is required high mechanical strength and corrosion resistance at elevated temperatures, such as turbine blades and automotive turbocharger rotors. The mechanical properties are totally connected to the morphology, size and distribution of γ' phase and carbides. In order to improve the mechanical properties, the material is subjected to solution and aging heat treatment, to raise the volume fraction of γ' phase in the matrix and to form carbides at grain boundaries. In the present study the Supercast 247A superalloy was remelted and cast to obtain the desired polycrystalline test bars by controlling casting parameters, followed by the investigation of precipitation morphology and mechanical properties with respect to solution treatment and aging treatment. The experimental results show that by well controlled casting parameters the Supercast 247A owns excellent castability to form a superalloy with fine grain structure, resistance to indentation as well as superior strength.

  15. Processing-structure characterization of rheocast IN-100 superalloy

    Science.gov (United States)

    Cheng, Jung-Jen Allen; Apelian, Diran; Doherty, Roger D.

    1986-11-01

    The rheocasting solidification process has been applied in the production of IN-100 nickel base superalloy. A high vacuum furnace for rheocasting superalloys was used to rheocast ingots under different processing conditions. Processing variables which were evaluated include stirring speed, isothermal stirring time, and volume fraction solid during isothermal stirring. Ingots, furnace cooled at the same rate but without stirring, were also examined for comparison with the rheocast ingots. A detailed microstructural examination was made of the resultant microstructure both on furnace cooling after stirring and on reheating to the isothermal stirring temperature followed by water quenching. Rheocasting yielded fine-grained structures, where the extent of microsegregatiori, the variation in macrostructure, and the solidification-induced porosity were found to be reduced in comparison to the unstirred ingot. The grain size and nonuniformity in the as-cast ingot were reduced by increasing the stirring speed, isothermal stirring time, or the volume fraction solid during stirring. The degree of the microsegregation decreased significantly with increasing volume fraction solid. Grain boundaries, both with and without solute enrichment, were found in the rosette-like solid particles after rheocasting, lending support to the Vogel-Cantor-Doherty model of rheocasting based on the formation of grain boundaries by strain-induced recrystallization and by sintering. It is clear from these results that the microstructure of this superalloy was significantly improved by rheocasting. Improved mechanical properties were also found and will be reported separately.

  16. Gas metal arc welding in refurbishment of cobalt base superalloys

    Science.gov (United States)

    Shahriary, M. S.; Miladi Gorji, Y.; Kolagar, A. M.

    2017-01-01

    Refurbishments of superalloys which are used in manufacturing gas turbine hot components usually consists of removing cracks and other defects by blending and then repair welding in order to reconstruct damaged area. In this study, the effects of welding parameters on repair of FSX-414 superalloy, as the most applicable cobalt base superalloy in order to manufacture gas turbine nozzles, by use of Gas Metal Arc Welding (GMAW) technic were investigated. Results then were compared by Gas Tungsten Arc Welding (GTAW). Metallographic and SEM studies of the microstructure of the weld and HAZ showed that there are no noticeable defects in the microstructure by use of GMAW. Also, chemical analysis and morphologies of carbide in both methods are similar. Hardness profile of the GM AW structure then also compared with GTAW and no noticeable difference was observed between the profiles. Also, proper tensile properties, compared with GTAW, can be achieved by use of optimum parameters that can be obtained by examining the current and welding speed. Tensile properties of optimized condition of the GMAW then were compared with GTAW. It was seen that the room and high temperature tensile properties of the GMAW structure is very similar and results confirmed that changing the technic did not have any significant influence on the properties.

  17. NASA and Superalloys: A Customer, a Participant, and a Referee

    Science.gov (United States)

    Nathal, Michael V.

    2008-01-01

    NASA has had a long history of research and development in the field of superalloys. These efforts have continued today, where the latest advancements in turbine disk and blade technologies are being developed Although NASA does support military flight systems, it s predominant role is in supporting civilian air transportation systems, and thus has goals for improving fuel efficiency, emissions, noise, and safety of today s aircraft. NASA has traditionally served several distinct but complimentary roles as participants in multi-disciplinary research teams, as customers who fund research and development efforts at industry and universities, and as referees who can address broad issues that affect the entire aeronautics community. Because of our longer range viewpoint, we can take on higher risk, higher reward research topics. NASA can also serve as an intermediary between the basic research performed primarily at universities and the development efforts emphasized by industry. By interacting with individual companies, NASA can identify areas of general interest and problems common to a large portion of the aeronautics community, and devise programs aimed at solving these problems. In space missions, NASA is a direct customer responsible for developing vehicles. In the case of the Space Shuttle, NASA has worked with various contractors to design and build numerous components out of superalloys. Another fascinating area for the use of superalloys is in power systems for long life applications in space. Potential missions include providing electric power for deep space missions, surface rovers, including lunar and Mars, and stationary power generators on the lunar surface.

  18. The Mechanical Properties of Candidate Superalloys for a Hybrid Turbine Disk

    Science.gov (United States)

    Gabb, Timothy P.; MacKay, Rebecca A.; Draper, Susan L.; Sudbrack, Chantal K.; Nathal, Michael V.

    2013-01-01

    The mechanical properties of several cast blade superalloys and one powder metallurgy disk superalloy were assessed for potential use in a dual alloy hybrid disk concept of joined dissimilar bore and web materials. Grain size was varied for each superalloy class. Tensile, creep, fatigue, and notch fatigue tests were performed at 704 to 815 degC. Typical microstructures and failure modes were determined. Preferred materials were then selected for future study as the bore and rim alloys in this hybrid disk concept. Powder metallurgy superalloy LSHR at 15 micron grain size and single crystal superalloy LDS-1101+Hf were selected for further study, and future work is recommended to develop the hybrid disk concept.

  19. Effects of returns on composition, microstructure and mechanical properties of GH4169 superalloy

    Directory of Open Access Journals (Sweden)

    Yong-liang Pu

    2017-07-01

    Full Text Available To recycle the returned alloy effectively, effects of returns proportion on alloy composition, microstructure and compression properties of superalloy GH4169 were studied by means of scanning electron microscopy (SEM, energy dispersive spectroscopy (EDS and thermal-mechanical simulator. The results show that returns addition has no significant effect on the main alloy elements content and the principle precipitates, but increases the volume fraction of Al2O3 inclusions, resulting in the increase of oxygen level of GH4169 alloy. Returns addition does not change the elastic and plastic deformation process at room temperature or at 1,150 °C, but high returns proportion GH4169 alloy shows improved compression strength and yield strength. The alloy with 100% returns shows a maximum compression strength 1,153.45 MPa at room temperature, while the alloy with 80% returns has a maximum value 69.3 MPa at 1,150 °C. Returns addition increases fluctuation range and reduces the stability of yield strength and compression strength of GH4169 alloy at room temperature. It is noted that the volume fraction and the size of Al2O3, and the fraction of Laves phase reach their maximum values in the GH4169 alloy with 60% returns, which exhibits maximum yield strength of 516.65 MPa at room temperature and 62.17 MPa at 1,150 °C.

  20. Re-description of Daphnia (Ctenodaphnia from lakes in the Khumbu Region, Nepalese Himalayas, with the erection of a new species, Daphnia himalaya, and a note on an intersex individual

    Directory of Open Access Journals (Sweden)

    Dinora Carolina PEÑALVA-ARANA

    2006-08-01

    Full Text Available We present here a detailed description of Ctenodaphnia-type Daphnia specimens collected from lakes in the Nepalese Himalayas between 1994 and 2004, including mature females and adult males. The specimens examined share certain diagnostic traits with Daphnia tibetana (Sars 1903, and others with Daphnia fusca (Gurney 1906. A re-appraisal of their previous synonymy with D. fusca and a comparison with all published descriptions of similar species from the region indicate that they represent a new species named here as Daphnia himalaya. The chance discovery of a sex intergrade of the same species allowed a description of the secondary sexual characteristics in this interesting and rare intermediate state to be reported, and its possible ecological implications to be discussed, as well.

  1. Microstructural evolution and castability prediction in newly designed modern third-generation nickel-based superalloys

    Science.gov (United States)

    Naffakh-Moosavy, Homam

    2016-05-01

    The present research aims to establish a quantitative relation between microstructure and chemical composition (i.e., Ti, Al, and Nb) of newly designed nickel-based superalloys. This research attempts to identify an optimum microstructure at which the minimum quantities of γ/γ' and γ/γ″ compounds are achieved and the best castability is predicted. The results demonstrate that the highest quantity of intermetallic eutectics (i.e., 41.5wt%) is formed at 9.8wt% (Ti + Al). A significant quantity of intermetallics formed in superalloy 1 (with a composition of γ - 9.8wt% (Ti + Al)), which can deteriorate its castability. The type and morphology of the eutectics changed and the amount considerably decreased with decreasing Ti + Al content in superalloy 2 (with a composition of γ - 7.6wt% (Ti + Al), 1.5wt% Nb). Thus, it is predicted that the castability would improve for superalloy 2. The same trend was observed for superalloy 4 (with a composition of γ - 3.7wt% (Ti + Al), 4.4wt% Nb). This means that the amount of Laves increases with increasing Nb (to 4.4wt%) and decreasing Ti + Al (to 3.7wt%) in superalloy 4. The best castability was predicted for superalloy 3 (with a composition of γ - 5.7wt% (Ti + Al), 2.8wt% Nb).

  2. Innovative technologies for powder metallurgy-based disk superalloys: Progress and proposal

    Science.gov (United States)

    Chong-Lin, Jia; Chang-Chun, Ge; Qing-Zhi, Yan

    2016-02-01

    Powder metallurgy (PM) superalloys are an important class of high temperature structural materials, key to the rotating components of aero engines. In the purview of the present challenges associated with PM superalloys, two novel approaches namely, powder preparation and the innovative spray-forming technique (for making turbine disk) are proposed and studied. Subsequently, advanced technologies like electrode-induction-melting gas atomization (EIGA), and spark-plasma discharge spheroidization (SPDS) are introduced, for ceramic-free superalloy powders. Presently, new processing routes are sought after for preparing finer and cleaner raw powders for disk superalloys. The progress of research in spray-formed PM superalloys is first summarized in detail. The spray-formed superalloy disks specifically exhibit excellent mechanical properties. This paper reviews the recent progress in innovative technologies for PM superalloys, with an emphasis on new ideas and approaches, central to the innovation driving techniques like powder processing and spray forming. Project supported by the National Natural Science Foundation of China (Grant Nos. 50974016 and 50071014).

  3. Hot deformation behavior of delta-processed superalloy 718

    Energy Technology Data Exchange (ETDEWEB)

    Wang, Y., E-mail: wangyanhit@yahoo.cn [State Key Laboratory of Powder Metallurgy, Central South University, Changsha 410083 (China); School of Aeronautics and Astronautics, Central South University, Changsha 410083 (China); Shao, W.Z.; Zhen, L.; Zhang, B.Y. [School of Materials Science and Engineering, Harbin Institute of Technology, Harbin 150001 (China)

    2011-03-25

    Research highlights: {yields} The peak stress for hot deformation can be described by the Z parameter. {yields} The grain size of DRX was inversely proportional to the Z parameter. {yields} The dissolution of {delta} phases was greatly accelerated under hot deformation. {yields}The {delta} phase stimulated nucleation can serve as the main DRX mechanism. - Abstract: Flow stress behavior and microstructures during hot compression of delta-processed superalloy 718 at temperatures from 950 to 1100 deg. C with strain rates of 10{sup -3} to 1 s{sup -1} were investigated by optical microscopy (OM), electron backscatter diffraction (EBSD) technique and transmission electron microscopy (TEM). The relationship between the peak stress and the deformation conditions can be expressed by a hyperbolic-sine type equation. The activation energy for the delta-processed superalloy 718 is determined to be 467 kJ/mol. The change of the dominant deformation mechanisms leads to the decrease of stress exponent and the increase of activation energy with increasing temperature. The dynamically recrystallized grain size is inversely proportional to the Zener-Hollomon (Z) parameter. It is found that the dissolution rate of {delta} phases under hot deformation conditions is much faster than that under static conditions. Dislocation, vacancy and curvature play important roles in the dissolution of {delta} phases. The main nucleation mechanisms of dynamic recrystallization (DRX) for the delta-processed superalloy 718 include the bulging of original grain boundaries and the {delta} phase stimulated DRX nucleation, which is closely related to the dissolution behavior of {delta} phases under certain deformation conditions.

  4. Pulsed laser-assisted machining of Inconel 718 superalloy

    Science.gov (United States)

    Azhdari Tadavani, Soheila; Shoja Razavi, Reza; Vafaei, Reza

    2017-01-01

    Nickel-based superalloys including Inconel 718(IN718) are widely used in aerospace industries due to their superior high temperature strength, toughness, and corrosion resistance. These alloys are difficult to machine mainly because of their low thermal conductivity and high work hardening rate, which cause steep temperature gradient and high cutting forces at the tool edge. The application of laser assisted machining is the subject of many new researches since shear forces; surface coarsening and tool wear are reduced. The aim of this investigation was to evaluate laser assisted machining behavior of a 718 Inconel superalloy from the view point of machining specific energy, surface roughness, tool wear and chip appearance. Experimental apparatuses used included optical and scanning electron microscopy, spark emission spectroscopy, and EDS analysis. The results indicated that increasing the temperature to about 540 °C just ahead of primary shear zone, can result in 35% reduction of machining specific energy, in comparison with conventional machining. Furthermore, surface coarsening and tool wear were reduced by 22% and 23% respectively. Flank wear was the main deteriorating factor on cutting tools during laser assisted machining. SEM micrographs indicated that increase in temperature has no noticeable effect on finished workpiece surface. Analysis of variance obtained from regression analysis indicated that frequency of laser beam has the most influential effect on temperature. The optimum conditions for laser assisted machining of 718 superalloy is suggested as follows: 80 Hz frequency, 400 W power, 24 m/min cutting speed, and 0.052 mm/rev feed rate along with 540 °C temperature, 2.51 J/mm2 machining specific energy and 130 N cutting force.

  5. Fatigue Behavior and Deformation Mechanisms in Inconel 718 Superalloy Investigated

    Science.gov (United States)

    2005-01-01

    The nickel-base superalloy Inconel 718 (IN 718) is used as a structural material for a variety of components in the space shuttle main engine (SSME) and accounts for more than half of the total weight of this engine. IN 718 is the bill-of-material for the pressure vessels of nickel-hydrogen batteries for the space station. In the case of the space shuttle main engine, structural components are typically subjected to startup and shutdown load transients and occasional overloads in addition to high-frequency vibratory loads from routine operation. The nickel-hydrogen battery cells are prooftested before service and are subjected to fluctuating pressure loads during operation. In both of these applications, the structural material is subjected to a monotonic load initially, which is subsequently followed by fatigue. To assess the life of these structural components, it is necessary to determine the influence of a prior monotonic load on the subsequent fatigue life of the superalloy. An insight into the underlying deformation and damage mechanisms is also required to properly account for the interaction between the prior monotonic load and the subsequent fatigue loading. An experimental investigation was conducted to establish the effect of prior monotonic straining on the subsequent fatigue behavior of wrought, double-aged, IN 718 at room temperature. First, monotonic strain tests and fully-reversed, strain-controlled fatigue tests were conducted on uniform-gage-section IN 718 specimens. Next, fully reversed fatigue tests were conducted under strain control on specimens that were monotonically strained in tension. Results from this investigation indicated that prior monotonic straining reduced the fatigue resistance of the superalloy particularly at the lowest strain range. Some of the tested specimens were sectioned and examined by transmission electron microscopy to reveal typical microstructures as well as the active deformation and damage mechanisms under each of

  6. MICROSTRUCTURE AND MECHANICAL PROPERTIES OF NOVEL 718 SUPERALLOY

    Institute of Scientific and Technical Information of China (English)

    J.H. Du; X.D. Lü; J.L. Qu; Q. Deng; J.Y. Zhuang; Z.Y. Zhong

    2006-01-01

    Recently, a novel 718 superalloy with remarkable structural stability at 680℃ has been designed and fabricated by CISRI (Central Iron and Steel Research Institute) etc. Phase identification of novel 718 alloy under the above-mentioned heat-treatment condition was performed using optical microscopy (OM), scanning electron microscopy (SEM), and transmission electron microscopy (TEM). Results show that the novel 718 alloy has outstanding structural stability at 680℃. The novel 718alloy possess excellent structural stability and good mechanical properties, which is attributed to y-phase strengthening and also to the specific sandwich structure of the γ′ + γ" strengthening phase.

  7. Lecture Notes and Exercises for Course 21240 (Basic Analytical Chemistry)

    DEFF Research Database (Denmark)

    1999-01-01

    The publication contains notes dealing with difficult topics in analytical chemistry (cfr. Course Descriptions, DTU), relevant exercises as well as final examination problems from the last years.......The publication contains notes dealing with difficult topics in analytical chemistry (cfr. Course Descriptions, DTU), relevant exercises as well as final examination problems from the last years....

  8. Lecture Notes and Exercises for Course 21240 (Basic Analytical Chemistry)

    DEFF Research Database (Denmark)

    1998-01-01

    The publication contains notes dealing with difficult topics in analytical chemistry (cfr. Course Descriptions, DTU), relevant exercises as well as final examination problems from the last years.......The publication contains notes dealing with difficult topics in analytical chemistry (cfr. Course Descriptions, DTU), relevant exercises as well as final examination problems from the last years....

  9. Lecture Notes and Exercises for Course 21240 (Basic Analyttical Chemistry)

    DEFF Research Database (Denmark)

    1997-01-01

    The publication contains notes dealing with difficult topics in the field (cfr. Course Descriptions, DTU), relevant exercises as well as final examination problems from the last years.......The publication contains notes dealing with difficult topics in the field (cfr. Course Descriptions, DTU), relevant exercises as well as final examination problems from the last years....

  10. Effect of high temperature deformation on the structure of Ni based superalloy

    Directory of Open Access Journals (Sweden)

    A. Nowotnik

    2008-04-01

    Full Text Available Purpose: A study on the hot deformation behaviour and dynamic structural processes (dynamic precipitation operating during deformation at elevated temperatures of nickel based superalloy was presented.Design/methodology/approach: Compression tests were carried out on precipitations hardenable nickel based superalloy of Inconel 718 at constant true strain rates of 10-4, 4x10-4s-1 within a temperature range of 720-1150°C. True stress-true strain curves and microstructure analysis of hot deformed alloy were described. Microstructure examination has been carried out on the compressed samples of Inconel 718 alloy using an optical microscope - Nikon 300 and in the scanning electron microscope HITACHI S-3400 (SEM in a conventional back-scattered electron mode on polished sections etched with Marble’s solution.Findings: Structural observations of deformed at high temperatures, previously solution treated Inconel alloy revealed non uniform deformation effects. Distribution of molybdenum-rich carbides was found to be affected by localized flow within the investigated strain range at relatively low deformation temperatures 720 - 850°C. Microstructural examination of the alloy also shown that shear banding, cavities growth and intergranular cracks penetrating through the whole grains were responsible for decrease in the flow stress at temperature of 720, 800 and 850°C and a specimen fracture at larger strains. On the basis of received flow stress values activation energy of a high-temperature deformation process was estimated. Mathematical dependences (σpl -T and σpl - and compression data were used to determine material’s constants. These constants allowed to derive a formula that describes the relationship between strain rate ( ε, deformation temperature (T and flow stress σpl.Research limitations/implications: Even though, the light optical microstructure observation of deformed samples revealed some effects of heterogeneous distribution of

  11. Description of new species of Stenaelurillus Simon, 1886 from the Western Ghats of India with the redescription of Stenaelurillus lesserti Reimoser, 1934 and notes on mating plug in the genus (Arachnida, Araneae, Salticidae

    Directory of Open Access Journals (Sweden)

    Pothalil A. Sebastian

    2015-03-01

    Full Text Available A new species of the jumping spider genus Stenaelurillus Simon, 1886, S. albus sp. n., is described from the Western Ghats of India, one of the biodiversity hotspots of the world. Detailed morphological descriptions, diagnostic features and illustrations of copulatory organs of both sexes are given. Detailed redescription, diagnosis and illustration of S. lesserti Reimoser, 1934 are provided. The occurrence of a mating plug in the genus is reported.

  12. Effect of Zr addition on precipitates in K4169 superalloy

    Directory of Open Access Journals (Sweden)

    Liu Jie

    2012-02-01

    Full Text Available In order to investigate the effect of Zr addition on the precipitations of K4169 superalloy, a manual electric arc furnace was used to prepare the superalloy with different Zr addition from 0.03wt.% to 0.07wt%. After standard heat treatment and long-time aging, the microstructures of the alloys were observed using XRD, SEM and TEM. The results show that Zr not only inhibits the precipitation of Laves phase at the grain boundary, but also significantly promotes the precipitation of earlobe-like γ′and γ″ phases. After long time aging at 680 ℃ for 500 h, the γ″phase grows up obviously and forms a γ′/γ′′clad microstructure when the Zr addition is 0.03 wt.%. A large number of fine orbed γ′particles precipitate in the grains and some γ″phase transforms to disk-like δ phase when the Zr addition increases to 0.05wt.%. The nano-polycrystalline γ′phase precipitates in the grains and there is a little δ phase when the Zr addition is 0.07wt.%. As the Zr addition increases, the amount of Laves phase at the grain boundary decreases at first, and then increases and forms flaky morphology.

  13. Recrystallization of Single Crystal Nickel-Based Superalloy

    Institute of Scientific and Technical Information of China (English)

    ZHANG Bing; TAO Chun-hu; LU Xin; LIU Chang-kui; HU Chun-yan; BAI Ming-yuan

    2009-01-01

    A series of experiments of investigating the recrystallization of single crystal DD3 superalloy were carried out. The threshold temperature for recrystallization and the effect of annealing temperature on recrystaUization were studied. The results show that the threshold temperature for recrystallization of the shot-peened DD3 samples is be-tween 1 000 ℃ and 1 050℃ under the condition of annealing for 2 h, and the recrystallization depth increases with the rise of the annealing temperature. Below 1 150 ℃, the recrystallization depth increases slowly with the tempera-ture climbing, while above 1 150 ℃, the recrystallization depth increases quickly with the rise of the temperature. The solution of the γ' phase is a critical factor of the recrystallization behavior of DD3 superalloy. In addition, the ki-netics and microstructural evolution of recrystallization at 1 200 ℃ were also studied. It is found that the recrystalli-zation progresses rapidly at 1 200℃ through the growth of fully developed recrystallized grains, and the recrystalli-zation process on the shot-peened surface is similar to that of wrought materials, including nucleation of reerystalliza-tion, growth of new grains into the matrix, and growth of new grains by swallowing up each other.

  14. Microstructural studies of carbides in MAR-M247 nickel-based superalloy

    Science.gov (United States)

    Szczotok, A.; Rodak, K.

    2012-05-01

    Carbides play an important role in the strengthening of microstructures of nickel-based superalloys. Grain boundary carbides prevent or retard grain-boundary sliding and make the grain boundary stronger. Carbides can also tie up certain elements that would otherwise promote phase instability during service. Various types of carbides are possible in the microstructure of nickel-based superalloys, depending on the superalloy composition and processing. In this paper, scanning electron and scanning transmission electron microscopy studies of carbides occurring in the microstructure of polycrystalline MAR-M247 nickel-based superalloy were carried out. In the present work, MC and M23C6 carbides in the MAR-M247 microstructure were examined.

  15. High temperature cyclic oxidation and hot corrosion behaviours of superalloys at 900°C

    Indian Academy of Sciences (India)

    Subhash Kamal; R Jayaganthan; S Prakash

    2010-06-01

    Oxidation and hot corrosion are serious problems in aircraft, marine, industrial, and land-base gas turbines. It is because of the usage of wide range of fuels coupled with increased operating temperatures, which leads to the degradation of turbine engines. To obviate these problems, superalloys, viz. Superni 75, Superni 718 and Superfer 800H superalloys (Midhani grade), are the prominent materials for the high temperature applications. It is very essential to investigate the degradation mechanism of superalloys due to oxidation and hot corrosion and substantiate the role of alloying elements for the formation of protective oxide films over the surface of the superalloys. Therefore, the present work investigates the oxidation and hot corrosion behaviour of superalloys exposed to air and molten salt (Na2SO4–60% V2O5) environment, respectively, at 900°C under cyclic conditions. The weight change measurements made on the superalloys during the experiments are used to determine the kinetics of oxidation and hot corrosion. X-ray diffraction (XRD), X-ray mapping and field emission scanning electron microscope (FESEM, FEI, Quanta 200F company) with EDAX Genesis software attachment, made in Czech Republic are used to characterize the corroded products of the superalloys. It is observed that the formation of scale rich in Cr2O3, NiO and spinel NiCr2O4 has contributed for the better oxidation and hot corrosion resistance of Superni 75; whereas relatively lesser hot corrosion resistance of Superfer 800H is due to the formation of non-protective oxides of iron and sulphides of iron and nickel. The parabolic rate constants calculated for the superalloys show that the corrosion rate is minimum in air as compared to molten salt environment.

  16. Additional thermal fatigue data on nickel- and cobalt-base superalloys, part 1

    Science.gov (United States)

    Howes, M. A. H.

    1973-01-01

    The fluidized bed technique was used to measure the relative thermal fatigue resistance of twenty-one superalloys. Among the thirty-six variations of composition, solidification method, and surface protection the cycles to cracking differed by two to three orders of magnitude. Some alloys suffered serious weight losses and oxidation. Thermal fatigue data, oxidation, and dimensional changes are reported. The types of superalloys are identified.

  17. Superalloys 1984; Proceedings of the Fifth International Symposium, Champion, PA, October 7-11, 1984

    Energy Technology Data Exchange (ETDEWEB)

    Radavich, J.F.; Gell, M.; Kortovich, C.S.; Bricknell, R.H.; Kent, W.B.

    1984-01-01

    The papers presented in this volume provide an overview of original research, development, and applications work on iron, cobalt, and nickel superalloys intended for elevated temperature usage. Topics discussed include polycrystalline castings and properties; directionally solidified and single crystal alloys and properties; powder processing, properties, and products; and advances in processing. The discussion also covers new alloys and alloying effects as well as the environmental behavior of superalloys and fracture mechanics.

  18. A Method of Stray Grain Suppression for Single-Crystal Superalloy During Seed Melt-Back

    Science.gov (United States)

    Xuan, Weidong; Lan, Jian; Liu, Huan; Li, Chuanjun; Zhong, Yunbo; Ren, Xingfu; Li, Xi; Cao, Guanghui; Ren, Zhongming

    2016-12-01

    The suppression of stray grains during seed melt-back of single-crystal superalloy through thermal resistance technique has been investigated based on both experimental observations and numerical simulation. The results indicate that the introduction of thermal resistance layer significantly suppresses the stray grain formation of single-crystal superalloy. Based on both theoretical analysis and numerical simulation, above results should be attributed to the decrease of radial heat transfer of sample in the thermal resistance layer.

  19. Gamma Prime Morphology and Creep Properties of Nickel Based Superalloys With Platinum Group Metal Additions (Preprint)

    Science.gov (United States)

    2008-04-01

    creep resistance. Polycrystalline superalloy MAR - M247 can sustain a creep rate of 10-8 s-1 at 982°C at a stress of 172 MPa [44], while the alloys...Nathal, R.D. Maier, and L.J. Ebert, “The Influence of Cobalt on the Tensile and Stress Rupture Properties of the Nickel-Base Superalloy MAR - M247 ,” Metallurgical Transactions A, 13 (A) (1982), 1767-1774.           10

  20. THE ROLE OF NIOBIUM IN NICKEL-BASED SUPERALLOYS AND CHARACTERIZATION OF PM ALLOY EP741NP

    Institute of Scientific and Technical Information of China (English)

    T. Carneiro; J. Radavich; D. Furrer

    2005-01-01

    The role of niobium in nickel-based superalloys is reviewed. The importance of niobium as a strengthener is discussed. New developments in nickel-based superalloys are also briefly mentioned, including some results that show improved resistance to sulfidation by niobium. Research results from a current program on the role of niobium in the Russian powder metallurgy alloy EP741NP are presented. Future research plans on the role of niobium in superalloys are also discussed.

  1. A Coupled Creep-Plasticity Model for Residual Stress Relaxation of a Shot-Peened Nickel-Base Superalloy

    Science.gov (United States)

    2007-05-01

    Superalloys for Turbine Discs ,” Journal of the Minerals, Metals & Materials Society (JOM), January 1999, pp. 14-17. 48. Fecht, H., and Furrer, D...Processing of Nickel-Base Superalloys for Turbine Engine Disc Applications,” Advanced Engineering Materials, Vol. 2, No. 12, 2000, pp. 777-787. 49...and McLean, M. “Tension-Compression creep asymmetry in a turbine disc superalloy : roles of internal stress and thermal ageing,” Acta Materialia, 52

  2. A Coupled Creep Plasticity Model for Residual Stress Relaxation of a Shot Peened Nickel-Base Superalloy (Postprint)

    Science.gov (United States)

    2008-09-01

    McLean, M. “Tension- Compression creep asymmetry in a turbine disc superalloy : roles of internal stress and thermal ageing,” Acta Materialia, 52, 2004...AFRL-RX-WP-TP-2009-4156 A COUPLED CREEP PLASTICITY MODEL FOR RESIDUAL STRESS RELAXATION OF A SHOT PEENED NICKEL-BASE SUPERALLOY (POSTPRINT...SUBTITLE A COUPLED CREEP PLASTICITY MODEL FOR RESIDUAL STRESS RELAXATION OF A SHOT PEENED NICKEL-BASE SUPERALLOY (POSTPRINT) 5a. CONTRACT NUMBER

  3. Characterization of oxide scales to evaluate high temperature oxidation behavior of Ni-20Cr coated superalloys

    Energy Technology Data Exchange (ETDEWEB)

    Singh, H. [Mechanical Engineering Department, BBSB Engineering College, Fatehgarh Sahib 140407 (India)], E-mail: hnr97@yahoo.com; Puri, D.; Prakash, S. [Metallurgical and Materials Engineering Department, Indian Institute of Technology Roorkee, Roorkee 247 667 (India); Maiti, Rabindranath [Central Research Facilities, Indian Institute of Technology Kharaghpur, Kharaghpur (India)

    2007-08-25

    Modern thermal spray processes such as plasma spraying are usually considered to deposit high-chromium, nickel-chromium coatings onto the superalloys to enhance their high temperature oxidation resistance. The purpose of these coatings is to form long-lasting oxidation protective scales. In the current investigation, Ni-20Cr alloy powder was deposited on three Ni-base superalloys; Superni 75, Superni 600 and Superni 601 by shrouded plasma spray process. Oxidation kinetics was established for the uncoated as well as the coated superalloys in air at 900 deg. C under cyclic conditions for 50 cycles by thermogravimetric technique. Each cycle consisted of 1 h heating followed by 20 min of cooling in air. All the coated superalloys nearly followed the parabolic rate law of oxidation. X-ray diffraction (XRD) and scanning electron microscopy/energy dispersive X-ray (SEM/EDAX) techniques were used to characterise the oxide scales. The coating was found to be successful in maintaining its integrity with the superalloy substrates in all the cases. The oxide scales formed on the oxidized coated superalloys were found to be intact and spallation-free in general. The XRD analysis revealed the presence of phase like NiO, Cr{sub 2}O{sub 3} and NiCr{sub 2}O{sub 4} in the oxide scales. The XRD results were further supported by the SEM/EDAX analyses.

  4. Sport and Exercise Biomechanics (Bios Instant Notes)

    OpenAIRE

    Paul Grimshaw; Adrian Lees; Neil Fowler; Adrian Burden

    2007-01-01

    DESCRIPTION Instant Notes on Sport and Exercise Biomechanics provides a broad overview of the fundamental concepts in exercise and sport biomechanics. PURPOSE The book aims to provide instant notes on essential information about biomechanics, and is designed to help undergraduate students to grasp the corresponding subjects in physical effort rapidly and easily. AUDIENCE The book provides a useful resource for undergraduate and graduate students as a fundamental reference book. For the resear...

  5. Simulation of oxidation-nitridation-induced microstructural degradation in a cracked Ni-based superalloy at high temperature

    Directory of Open Access Journals (Sweden)

    Yuan Kang

    2014-01-01

    Full Text Available In turbine engines, high temperature components made of superalloys may crack in a creep process during service. With the inward flux of the gases, e.g. oxygen and nitrogen, along those cracks, the microstructure of the superalloy substrate nearby the cracks may degrade by internal oxidation and nitridation. The aim of this study is to investigate and simulate the oxidation-nitridation-induced microstructural degradation in superalloys by taking a variant of Ni-based superalloy IN-792 as a sample. After the creep testing of the superalloy in air, the microstructures on the cross section of the superalloy were analysed in a scanning electron microscope, equipped with energy/wavelength dispersive systems. Internal oxidation and nitridation, presenting by Al/Ti oxides and nitrides, were observed under a porous and even cracked Cr-oxide scale which was formed on the superalloy surface or along the creep cracks connecting the superalloy surface. Meanwhile, the reinforcing γ′ precipitates were depleted. Such oxidation-nitridation-induced microstructural degradation was simulated by using an oxidation-diffusion model, focusing the diffusion of the alloying elements in metallic phases of the superalloy.

  6. Morphological and molecular descriptions of Moniliformis saudi sp. n. (Acanthocephala: Moniliformidae) from the desert hedgehog, Paraechinus aethiopicus (Ehrenberg) in Saudi Arabia, with a key to species and notes on histopathology.

    Science.gov (United States)

    Amin, Omar M; Heckmann, Richard A; Osama, Mohammed; Evans, R Paul

    2016-04-26

    A new acanthocepohalan species, Moniliformis saudi sp. n. is described from the desert hedgehog, Paraechinus aethiopicus (Ehrenberg), in central Saudi Arabia. Fourteen other valid species of Moniliformis Travassos, 1915 are recognised. The new species of Moniliformis is distinguished by having a small proboscis (315-520 µm long and 130-208 µm wide) with two apical pores, 14 rows of 8 hooks each and small hooks, thre largest being 25-31 µm long anteriorly. Distinguishing features are incorporated in a dichotomous key to the species of Moniliformis. The description is augmented by scanning electron microscopical (SEM) observation and DNA analysis of nuclear (18S rRNA) and mitochondrial (cytochrome oxidase subunit 1; cox1) gene sequences. Attached worms cause extensive damage to the immediate area of attachment in the host intestine. This includes tissue necrosis and blood loss due to damage to capillary beds. Worms also obstruct essential absorbing surfaces.

  7. Oxidation and emittance of superalloys in heat shield applications

    Science.gov (United States)

    Wiedemann, K. E.; Clark, R. K.; Unnam, J.

    1986-01-01

    Recently developed superalloys that form alumina coatings have a high potential for heat shield applications for advanced aerospace vehicles at temperatures above 1095C. Both INCOLOY alloy MA 956 (of the Inco Alloys International, Inc.), an iron-base oxide-dispersion-strengthened alloy, and CABOT alloy No. 214 (of the Cabot Corporation), an alumina-forming nickel-chromium alloy, have good oxidation resistance and good elevated temperature strength. The oxidation resistance of both alloys has been attributed to the formation of a thin alumina layer (alpha-Al2O3) at the surface. Emittance and oxidation data were obtained for simulated Space Shuttle reentry conditions using a hypersonic arc-heated wind tunnel. The surface oxides and substrate alloys were characterized using X-ray diffraction and scanning and transmission electron microscopy with an energy-dispersive X-ray analysis unit. The mass loss and emittance characteristics of the two alloys are discussed.

  8. Laser engineered net shaping of Co-based superalloys

    Institute of Scientific and Technical Information of China (English)

    XUE Chun-fang; DAI Yao; TIAN Xin-li

    2006-01-01

    Laser engineered net shaping(LENS) process was investigated using Co-based superalloy powder with a high power continuous wave CO2 laser. Thin wall part with smooth surface was obtained by LENS of layer-by-layer deposition of the powder materials. This thin wall sample was tested for metallographic examinations, micro-hardness, X-ray diffraction and mechanical property test. Microstructural results show that the layers possess rapid solidification microstructural feature, fine dendritic crystal and M7C3-type carbides (essentially chromium-rich carbide) dispersed in the γ(Co,Cr) phase matrix. Dendrite spacing as well as the solidification mode can be controlled through control process parameters. In addition, this microstructural feature of the as-formed Co-base sample leads to an evident hardening and a superior tensile strength and toughness.

  9. Phase transformations and microstructure of IN-713C nickel superalloy

    Directory of Open Access Journals (Sweden)

    F. Binczyk

    2009-04-01

    Full Text Available The study presents the results of investigations of phase transformations taking place during melting and solidification and ofmicrostructural examinations carried out on the family of IN 713C nickel superalloys. Examinations were carried out by the method ofthermal analysis (ATD and differential scanning calorimetry (DSC. It has been concluded that the method of thermal analysis (ATDenables more precise assessment of the precipitation of the primary phases of a low value of the solidification enthalpy. The advantage ofDSC is the possibility of determination of the value of the heat (enthalpy of phase transformations during alloy melting and solidification. The measured parameters of Tlik and Tsol are comparable for both methods. Microstructural examinations have confirmed the phenomena accompanying phase transformations, i.e. the precipitation of primary carbides, the solidification of y' phase matrix and carbide eutectic, and the formation of y’ phase in solid state.

  10. N18, powder metallurgy superalloy for disks: Development and applications

    Energy Technology Data Exchange (ETDEWEB)

    Guedou, J.Y.; Lautridou, J.C.; Honnorat, Y. (SNECMA, Evry (France). Materials and Processes Dept.)

    1993-08-01

    The preliminary industrial development of a powder metallurgy (PM) superalloy, designated N18, for disk applications has been completed. This alloy exhibits good overall mechanical properties after appropriate processing of the material. These properties have been measured on both isothermally forged and extruded billets, as well as on specimens cut from actual parts. The temperature capability of the alloy is about 700 C for long-term applications and approximately 750 C for short-term use because of microstructural instability. Further improvements in creep and crack propagation properties, without significant reduction in tensile strength, are possible through appropriate thermomechanical processing, which results in a large controlled grain size. Spin pit tests on subscale disks have confirmed that the N18 alloy has a higher resistance than PM Astrology and is therefore an excellent alloy for modern turbine disk applications.

  11. The characteristics of serrated flow in superalloy IN738LC

    Energy Technology Data Exchange (ETDEWEB)

    Sharghi-Moshtaghin, Reza [Department of Materials Science and Engineering, Sharif University of Technology, Azadi Avenue, Tehran (Iran, Islamic Republic of); Department of Materials Science and Engineering, Case Western Reserve University, Cleveland, OH 44106 (United States)], E-mail: rxs270@case.edu; Asgari, Sirous [Department of Materials Science and Engineering, Sharif University of Technology, Azadi Avenue, Tehran (Iran, Islamic Republic of)

    2008-07-15

    Serrated flow was investigated in superalloy IN738LC, a nickel-base {gamma}' age-hardened alloy. In this material serrated flow appeared between 350 and 450 deg. C and strain rate of (8.77 x 10{sup -5} to 8.77 x 10{sup -3}) s{sup -1}. Activation energy for this process was calculated to be 0.69-0.86 eV which is in good agreement with the values reported for similar alloys. Results show that the diffusion rate of substitutional solute atoms at this temperature range is too low to cause this effect. This suggests that the interaction of solute atoms and moving dislocation is responsible for the observed serrated flow in this alloy.

  12. Supersolidus Liquid Phase Sintering Modeling of Inconel 718 Superalloy

    Science.gov (United States)

    Levasseur, David; Brochu, Mathieu

    2016-02-01

    Powder metallurgy of Inconel 718 superalloy is advantageous as a near-net shape process for complex parts to reduce the buy-to-fly ratio and machining cost. However, sintering Inconel 718 requires the assistance of supersolidus liquid formation to achieve near full density and involves the risk of distortion at high temperatures. The present work is focused on modeling the onset of sintering and distortion as a function of temperature, grain size, and part geometry for Inconel 718. Using experimental sintering results and data available in the literature, the supersolidus liquid phase sintering of Inconel 718 was modeled. The model was used to define a processing window where part distortion would be avoided.

  13. Macro- and microhardness of IN-713C nickel superalloy constituents

    Directory of Open Access Journals (Sweden)

    F. Binczyk

    2009-10-01

    Full Text Available The results of investigations of the effect of modification and cooling rate on the macrohardness of castings and microhardness of phase constituents in IN-713C nickel superalloy were described. As an inoculant, cobalt aluminate CoAl2O4 in composition with aluminium powder and colloidal silica was used. Changes in the cooling rate were obtained using a cast stepped test piece with steps of 6, 11 and 17 mm thickness. Macrohardness of the cast test piece steps was measured by Brinell technique, while Vickers method was used to measure the microhardness of γ and γ’ phases present in the alloy matrix, as well as the hardness of eutectic carbide precipitates.A significant effect of the cooling rate and modification treatment on the results of the measurements was stated, and difficulties in performing correctly the microhardness measurements due to the precipitates dimensions, especially after the modification treatment, were highlighted.

  14. Creep curve modelling of a conventionally cast nickel base superalloy

    Energy Technology Data Exchange (ETDEWEB)

    Lupinc, V.; Maldini, M. [CNR - IENI, Milan (Italy); Poggio, E.; Vacchieri, E. [Ansaldo Energia S.p.A., Genoa (Italy)

    2010-07-01

    Constant load creep tests on Rene 80, a nickel base superalloy for gas turbine blade application, were run in the temperature interval 800-950 C with applied stresses producing rupture times up to 1000 h. Creep curves are generally dominated by a long accelerating/tertiary creep that follows a relatively small decelerating/primary creep. No steady state stage has been observed. Analysis of the creep curves has shown that a single damage parameter can describe the long accelerating/tertiary state in the explored temperature range. The damage appears to be dependent on the accumulated creep strain and, as a first approximation, independent on the applied stress and temperature. The whole creep curve, primary and tertiary stages, has been modelled by a simple set of coupled differential equations obtained using the formalism of the Continuum Damage Mechanics. The proposed set of equations has an analytical solution, strain vs. time, for creep curves at constant temperature and stress. (orig.)

  15. STABILITY ANALYSIS OF RADIAL TURNING PROCESS FOR SUPERALLOYS

    Directory of Open Access Journals (Sweden)

    Alberto JIMÉNEZ

    2017-07-01

    Full Text Available Stability detection in machining processes is an essential component for the design of efficient machining processes. Automatic methods are able to determine when instability is happening and prevent possible machine failures. In this work a variety of methods are proposed for detecting stability anomalies based on the measured forces in the radial turning process of superalloys. Two different methods are proposed to determine instabilities. Each one is tested on real data obtained in the machining of Waspalloy, Haynes 282 and Inconel 718. Experimental data, in both Conventional and High Pressure Coolant (HPC environments, are set in four different states depending on materials grain size and Hard-ness (LGA, LGS, SGA and SGS. Results reveal that PCA method is useful for visualization of the process and detection of anomalies in online processes.

  16. SUPERPLASTICITY AND DIFFUSION BONDING OF IN718 SUPERALLOY

    Institute of Scientific and Technical Information of China (English)

    2007-01-01

    The superplasticity and diffusion bonding of IN718 superalloy were studied in this article. The strain rate sensitivity index m was obtained at different temperatures and various initial strain rates using the tensile speed mutation method; m reached its maximum value 0.53 at an initial strain rate of 1 ×10-4s-1 at 1253K. The diffusion bonding parameters, including the bonding temperature T,pressure p, and time t, affected the mechanism of joints. When the bonded specimen with 25μm thick nickel foil interlayer was tensile at room temperature, the shear fracture of the joints with nickel foil interlayer took place at the IN718 part. Microstructure study was carried out with the bonded samples. The microstructure shows an excellent bonding at the interfaces. The optimum parameters for the diffusion bonding are: T= 1273-1323K, p = 20-30MPa, t = 45-60min.

  17. Tensile Strain Hardening Behavior and Fractography of Superalloy GH39

    Directory of Open Access Journals (Sweden)

    WANG Hui

    2016-10-01

    Full Text Available The strain hardening behaviour and fractography of superalloy GH39 was investigated by tensile test at different strain rates. Results indicate that strain hardening behaviours are different during the deformation process. True stress-strain curve obeys the Hollomon relationship partly. The strain hardening exponentn in this stage is constant in the initial plastic stage. However, the value of n increased with true strain ε increasing when true strain is between 0.014 and 0.13. A lot of deformation twinning can be found, the twins and dislocations worked together to increase the value of n. The strain hardening exponent is increased lightly with the strain rate increasing, SEM observations show that in the case of low strain rate, the fracture mode is typical ductile, but there is a tendency from ductile to brittle fracture with increasing the strain rate.

  18. High Temperature Oxidation and Corrosion Properties of High Entropy Superalloys

    Directory of Open Access Journals (Sweden)

    Te-Kang Tsao

    2016-02-01

    Full Text Available The present work investigates the high temperature oxidation and corrosion behaviour of high entropy superalloys (HESA. A high content of various solutes in HESA leads to formation of complex oxides, however the Cr and Al activities of HESA are sufficient to promote protective chromia or alumina formation on the surface. By comparing the oxidation and corrosion resistances of a Ni-based superalloy—CM247LC, Al2O3-forming HESA can possess comparable oxidation resistance at 1100 °C, and Cr2O3-forming HESA can exhibit superior resistance against hot corrosion at 900 °C. This work has demonstrated the potential of HESA to maintain surface stability in oxidizing and corrosive environments.

  19. SWMM news and notes

    Science.gov (United States)

    Stormwater management modelers now have a new publication:Storm Water Management Modelling News and Notes. SWMM News and Notes features articles concerning new developments and research in the stormwater field, as well as new product reviews, dissertations, and books.

  20. Isothermal Oxidation Comparison of Three Ni-Based Superalloys

    Science.gov (United States)

    Mallikarjuna, H. T.; Richards, N. L.; Caley, W. F.

    2017-05-01

    Ni-based superalloys are used for high-temperature components of gas turbines in both industrial and aerospace applications due to their ability to maintain dimensional stability under conditions of high stress and strain. The oxidation resistance of these alloys often dictates their service lifetime. This study focuses on the isothermal oxidation behavior of three Ni-based superalloys, namely, polycrystalline cast IN738LC, single-crystal N5, and a ternary Ni-Fe-Cr (TAS) powder metallurgy alloy. The isothermal oxidation tests were conducted at 900 °C in the static air up to 1000 h, and the specific aspects studied were the oxidation behavior of these chromia-forming and alumina-forming alloys that are used extensively in industry. In particular, the behavior of oxide scale growth and subsurface changes were analyzed in detail using various techniques such as SEM, EDS, and AFM. From the isothermal oxidation kinetics, the oxidation rate constant, k p, was calculated for each alloy and found to be; k p = 2.79 × 10-6 mg2 cm-4 s-1 for IN738LC, k p = 1.42 × 10-7 mg2 cm-4 s-1 for N5 and k p = 1.62 × 10-7 mg2 cm-4 s-1 for TAS. Based on a microstructural analysis, IN738LC exhibited a continuous dense outer scale of Cr2O3 and discontinuous inner scale of Al2O3, whereas N5 and TAS showed a dense outer scale of Al2O3 alone. The results suggested that the N5 and PM-TAS alloys are more oxidation resistant than the IN738LC under these conditions.

  1. Descriptive Research

    DEFF Research Database (Denmark)

    Wigram, Anthony Lewis

    2003-01-01

    Descriptive research is described by Lathom-Radocy and Radocy (1995) to include Survey research, ex post facto research, case studies and developmental studies. Descriptive research also includes a review of the literature in order to provide both quantitative and qualitative evidence of the effect...... starts will allow effect size calculations to be made in order to evaluate effect over time. Given the difficulties in undertaking controlled experimental studies in the creative arts therapies, descriptive research methods offer a way of quantifying effect through descriptive statistical analysis...

  2. The Improvement of Oxidation Resistance of a Re-Based Diffusion Barrier/Ni–Al Coating on the Single-Crystal Ni-Based TMS-82+ Superalloy

    NARCIS (Netherlands)

    Wu, Y.; Wang, Y.M.; Song, G.M.; Li, X.W.

    2011-01-01

    Oxidation behavior of a Re-based diffusion barrier/Ni–Al coated single-crystal (SC) Ni-based TMS-82+ superalloy was studied to compare with those of the base and Ni–Al coated superalloys under cyclic air at 1150 °C for 200 h. The base superalloy showed a negative mass gain due to extensive oxide spa

  3. A description of Echinorhynchus baeri Kostylew, 1928 (Acanthocephala: Echinorhynchidae from Salmo trutta in Turkey, with notes on synonymy, geographical origins, geological history, molecular profile, and X-ray microanalysis

    Directory of Open Access Journals (Sweden)

    Amin Omar M.

    2016-01-01

    Full Text Available A population of Echinorhynchus baeri Kostylew, 1928 with 18–24 rows of 8–10 proboscis hooks each and long fusiform eggs measuring 95–110 × 18–22 μm collected from Salmo trutta (Salmonidae in a branch of the Murat River in Turkey is described and specimens are designated as neotype. Specimens of two similar populations of E. baeri (E. baeri Kostylew, 1928 and E. sevani Dinnik, 1932 were previously described from Salmo ischchan in Lake Sevan, Armenia. Waters of Lake Sevan and the Murat River were previously joined during the Middle Miocene-Pliocene. The two populations from Lake Sevan and ours from Turkey had identical morphology and size eggs. The proboscis armature and eggs, among other features of our Turkish specimens, proved intermediate between E. baeri and E. sevani, thus eliminating the significance of the described differences between these two species and confirming their synonymy with priority to Echinorhynchus baeri (junior synonym: Echinorhynchus sevani Dinnik, 1932. Echinorhynchus baeri is apparently a highly variable species. The two descriptions from Lake Sevan did not include features or illustrations of females, except for references to trunk and egg size but the eggs were illustrated. Complete morphometric comparisons are made and females of the Turkish material are described for the first time. DNA sequencing (mitochondrial cytochrome oxidase subunit I gene; nuclear 18S rRNA gene results from two available E. baeri individuals were equivocal. New features to the Acanthocephala include the presence of rootless uncalcified apical proboscis hooks studied with X-ray microanalysis.

  4. Description of a new species of skate of the genus Malacoraja Stehmann, 1970: the first species from the southwestern Atlantic Ocean, with notes on generic monophyly and composition (Chondrichthyes: Rajidae

    Directory of Open Access Journals (Sweden)

    Marcelo R. de Carvalho

    Full Text Available The first report of a western South Atlantic soft skate, genus Malacoraja Stehmann, 1970, is described as Malacoraja obscura, new species, from the southeastern Brazilian continental slope off the states of Espírito Santo and Rio de Janeiro, in depths ranging from 808-1105 m. The new species is known from five specimens and is distinguished from congeners by its unique dorsal coloration with small, faded white spots on disc and pelvic fins, by retaining in larger specimens an irregular row of thorns along dorsal midline of tail (extending from tail base to two-thirds of tail length in 680 mm total length female, and by presenting a ventral tail midline devoid of small denticles only at base (naked region not extending posterior to pelvic fin rear margin. Further diagnostic characters in combination include the lack of scapular thorns in larger specimens, elevated number of tooth rows (64/62 tooth rows in subadult male of 505 mm TL, and 76/74 in large female of 680 mm TL and vertebrae (27-28 Vtr, 68-75 Vprd, ventral disc and tail with a uniform dark brown coloration, paired postventral fenestrae on scapulocoracoid, enlarged posterior postventral fenestra, circular foramen magnum and paired internal carotid foramina on braincase floor. Adult males were unavailable for study, but an anatomical description of M. obscura, n. sp., is provided. Comparisons are made with all known material of M. kreffti, literature accounts of M. senta, and with abundant material of South African M. spinacidermis; M. obscura, n. sp., most closely resembles M. spinacidermis from the eastern South Atlantic in squamation, coloration and size. Malacoraja is monophyletic due to its unique squamation and rostral appendices, and apparently comprises two species-groups, one for M. obscura and M. spinacidermis, and the other for M. kreffti and M. senta, but clarification of species-level relationships must await more anatomical information, particularly of the latter two

  5. A note on the projection of appositives

    NARCIS (Netherlands)

    Nouwen, Rick

    2014-01-01

    This article offers a thorough examination of the scopal properties of (mainly nominal) appositives. It is often descriptively noted that apposition is scopeless in the sense that its content escapes the scope of any operators that occur in the sentence the appositive is anchored in. I focus on exce

  6. KAWA lecture notes on complex hyperbolic geometry

    OpenAIRE

    Rousseau, Erwan

    2016-01-01

    These lecture notes are based on a mini-course given at the fifth KAWA Winter School on March 24-29, 2014 at CIRM, Marseille. They provide an introduction to hyperbolicity of complex algebraic varieties namely the geometry of entire curves, and a description of some recent developments.

  7. Description of the immature stages of Sigara (Tropocorixa jensenhaarupi (Hemiptera: Heteroptera: Corixidae: Corixini, with ecological notes Descripción de los estadios larvales de Sigara (Tropocorixa jensenhaarupi (Heteroptera: Corixidae, con notas acerca de su ecología

    Directory of Open Access Journals (Sweden)

    María Cecilia Melo

    2011-03-01

    Full Text Available Sigara (Tropocorixa jensenhaarupi Jaczewski is the smallest species of the subgenus ranging from 4.2-4.7 mm, and it is characterized by the absence of a strigil, the small and narrow genital capsule with a short hypandrium in males, and the shape of the abdominal tergite VII in females. This species is endemic to the Patagonian subregion (Andean region in Argentina. A monthly sampling study was performed during a year in northern Mendoza, and additional material was collected in southern Mendoza, more precisely from Bañado Carilauquen in the Llancanelo Lake Reserve (Malargüe Department. Since little is known about the ecological requirements of S. (T. jensenhaarupi, herein we describe its habitat, the environmental conditions and its association with other macroinvertebrates. Also, we provide a morphological description of larval stages, and provide new records of this species.Sigara (Tropocorixa jensenhaarupi Jaczewski es la especie más pequeña del subgénero (4.2-4.7 mm, y se caracteriza por la ausencia de estrigilo, la cápsula genital masculina pequeña y angosta con el hipandro corto, y la forma característica del tergito abdominal VII en las hembras. Esta especie es endémica de la subregión Patagónica (región Andina en Argentina. Se realizaron muestreos mensuales durante un año en el norte de la provincia de Mendoza, material adicional fue recolectado en el sur de la provincia, más precisamente en el Bañado Carilauquen en la Reserva Laguna Llancanelo (Departamento de Malargüe. Poco se conoce acerca de los requerimientos ecológicos de S. (T. jensenhaarupi, por lo que en este trabajo describimos su hábitat, las condiciones ambientales y su asociación con otros macroinvertebrados. Además, describimos los estadios larvales y damos nuevos registros de esta especie.

  8. Superalloy Lattice Block Developed for Use in Lightweight, High-Temperature Structures

    Science.gov (United States)

    Hebsur, Mohan G.; Whittenberger, J. Daniel; Krause, David L.

    2003-01-01

    Successful development of advanced gas turbine engines for aircraft will require lightweight, high-temperature components. Currently titanium-aluminum- (TiAl) based alloys are envisioned for such applications because of their lower density (4 g/cm3) in comparison to superalloys (8.5 g/cm3), which have been utilized for hot turbine engine parts for over 50 years. However, a recently developed concept (lattice block) by JAMCORP, Inc., of Willmington, Massachusetts, would allow lightweight, high-temperature structures to be directly fabricated from superalloys and, thus, take advantage of their well-known, characterized properties. In its simplest state, lattice block is composed of thin ligaments arranged in a three dimensional triangulated trusslike configuration that forms a structurally rigid panel. Because lattice block can be fabricated by casting, correctly sized hardware is produced with little or no machining; thus very low cost manufacturing is possible. Together, the NASA Glenn Research Center and JAMCORP have extended their lattice block methodology for lower melting materials, such as Al alloys, to demonstrate that investment casting of superalloy lattice block is possible. This effort required advances in lattice block pattern design and assembly, higher temperature mold materials and mold fabrication technology, and foundry practice suitable for superalloys (ref. 1). Lattice block panels have been cast from two different Ni-base superalloys: IN 718, which is the most commonly utilized superalloy and retains its strength up to 650 C; and MAR M247, which possesses excellent mechanical properties to at least 1100 C. In addition to the open-cell lattice block geometry, same-sized lattice block panels containing a thin (1-mm-thick) solid face on one side have also been cast from both superalloys. The elevated-temperature mechanical properties of the open cell and face-sheeted superalloy lattice block panels are currently being examined, and the

  9. Influence of Short-time Oxidation on Corrosion Properties of Directionally Solidified Superalloys with Different Orientations

    Directory of Open Access Journals (Sweden)

    MA Luo-ning

    2016-07-01

    Full Text Available In order to investigate the corrosion performance on intersecting and longitudinal surfaces of unoxidized and oxidized directionally solidified superalloys, Ni-base directionally solidified superalloy DZ125 and Co-base directionally solidified superalloy DZ40M were selected. Oxidation behavior on both alloys with different orientations was investigated at 1050℃ at different times, simulating the oxidation process of vanes or blades in service; subsequent electrochemical performance in 3.5%NaCl aqueous solution was studied on two orientations of unoxidized and oxidized alloys, simulating the corrosion process of superalloy during downtime. The results show that grain boundaries and sub-boundaries of directionally solidified superalloys are susceptible to corrosion and thus longitudinal surface with lower area fraction of grain boundaries has higher corrosion resistance. Compared to intersecting surface of alloys, the structure of grain boundaries of longitudinal surface is less conducive to diffusion and thus the oxidation rate on longitudinal surface is lower. Formation of oxide layers on alloys after short-time oxidation provides protective effect and enhances the corrosion resistance.

  10. Microstructural Stability and Hot Deformation of γ- γ'- δ Ni-Base Superalloys

    Science.gov (United States)

    Detrois, Martin; Helmink, Randolph C.; Tin, Sammy

    2014-11-01

    Nickel-base superalloys exhibit excellent high-temperature mechanical and physical properties and remain the first choice for structural components in advanced gas turbine engines for the aerospace propulsion and power generation applications. In response to the increasing demand for more efficient solutions and tighter requirements linked to gas turbine technologies, the properties of nickel-base superalloys can be improved by modification of their thermo-mechanical and/or compositional attributes. Recent investigations have revealed the potential use of ternary eutectic γ- γ'- δ Ni-base superalloys in advanced gas turbines due to high temperature mechanical properties that are comparable to state-of-the-art polycrystalline Ni-base superalloys. With properties largely dependent on microstructural strengthening mechanisms, both the composition and thermo-mechanical processing parameters of this novel class of alloys need to be optimized concurrently. The hot deformation characteristics of four γ- γ'- δ Ni-base superalloys with varying levels of Nb were evaluated at temperatures and strain rates between 1353 K and 1433 K (1080 °C and 1160 °C) and 0.01 to 0.001/s, respectively. Evidence of dislocation-based plasticity was observed following deformation at low temperatures and high strain rates, while high temperatures and low strain rates promoted superplasticity in these alloys. The extent of the microstructural changes and the magnitude of the cavitation damage which occurred during deformation was found to vary as a function of the alloy composition.

  11. Study of phase transformations in CMSX-6 and CMSX-8 superalloys

    Science.gov (United States)

    Szczotok, Agnieszka; Wierzbicka-Miernik, Anna

    2014-09-01

    Nickel-based superalloys are extensively used mainly in the aircraft and aeronautic industry, particularly in the hottest parts of engines or turbo-reactors. The phase reactions occurring in these heat-resistant materials play a crucial role in many aspects of the processing and service of the highly alloyed materials. Cast Ni-based superalloys are obtained in a complex way and their structure is complicated. Differential scanning calorimetry (DSC) technique was applied for determination of temperature ranges of the phase transformations occurring in the CMSX-6 and CMSX-8 superalloys during heating/cooling processes. Thermophysical properties, including temperatures of the phase transformation, are the critical input parameters in mathematical models of solidification and casting of metallic materials. The literature data concerning phase transformations and performance of the heat treatment for CMSX-6 and CMSX-8 are incomplete and ambiguous. DSC results accompanied by scanning electron microscopy characterization of microstructure of CMSX-6 and CMSX-8 superalloy was applied. The present study will improve the understanding of the fundamental mechanisms of phase transformations of single-crystal nickel-based superalloys.

  12. Microstructural analysis of laser weld fusion zone in Haynes 282 superalloy

    Energy Technology Data Exchange (ETDEWEB)

    Osoba, L.O. [Department of Mechanical and Manufacturing Engineering, University of Manitoba, Winnipeg, Manitoba, R3T 5V6 (Canada); Ding, R.G. [Department of Metallurgy and Materials Engineering, University of Birmingham, Birmingham B15 2TT (United Kingdom); Ojo, O.A., E-mail: ojo@cc.umanitoba.ca [Department of Mechanical and Manufacturing Engineering, University of Manitoba, Winnipeg, Manitoba, R3T 5V6 (Canada)

    2012-03-15

    Analytical electron microscopy and spectroscopy analyses of the fusion zone (FZ) microstructure in autogenous laser beam welded Haynes 282 (HY 282) superalloy were performed. The micro-segregation patterns observed in the FZ indicate that Co, Cr and Al exhibited a nearly uniform distribution between the dendrite core and interdendritic regions while Ti and Mo were rejected into the interdendritic liquid during the weld solidification. Transmission electron diffraction analysis and energy dispersive X-ray microanalysis revealed the second phase particles formed along the FZ interdendritic region to be Ti-Mo rich MC-type carbide particles. Weld FZ solidification cracking, which is sometimes associated with the formation of {gamma}-{gamma}' eutectic in {gamma}' precipitation strengthened nickel-base superalloys, was not observed in the HY 282 superalloy. Modified primary solidification path due to carbon addition in the newly developed superalloy is used to explain preclusion of weld FZ solidification cracking in the material. - Highlights: Black-Right-Pointing-Pointer A newly developed superalloy was welded by CO{sub 2} laser beam joining technique. Black-Right-Pointing-Pointer Electron microscopy characterization of the weld microstructure was performed. Black-Right-Pointing-Pointer Identified interdendritic microconstituents consist of MC-type carbides. Black-Right-Pointing-Pointer Modification of primary solidification path is used to explain cracking resistance.

  13. Environmental effects of microstructure stability on nickel-base superalloys

    Energy Technology Data Exchange (ETDEWEB)

    Sah, In Jin

    2011-02-15

    Next generation nuclear reactor VHTR (Very High Temperature gas-cooled Reactor) wants to achieve higher thermal efficiency and hydrogen production. IHX (Intermediate Heat eXchanger) will be exposed to the highest temperature condition among lots of structural components. Solid-solution hardening nickel-base superalloys Alloy 617 and Haynes 230 are expected to use for this applications. Studies on oxidation test and time dependent deformation at 900 .deg. C were conducted before. This study is focused on the microstructure evolution and mechanical properties at other temperature ranges. Furthermore, considering heat treatment history especially cooling rate effects on microstructure evolution, those of two superalloys are cooled down to room temperature by air and furnace. Materials behavior at intermediation temperature ranges from 600-900 .deg. C and diffusion bonding condition (1150 .deg. C) were evaluated. Vicker's hardness test and small-size tensile test were carried out for each specimen at room temperature. Hardness number and tensile strength were higher than any other temperature condition at 700 .deg. C due to gamma prime phases for Alloy 617. As the aluminum contents of Haynes 230 is far less than Alloy 617, there is no big difference for Haynes 230 at intermediate temperature ranges. The value of mechanical property of alloys at 1150 .deg. C air cooling condition was severely decreased and fully ductile fracture was detected for both alloys. On the other hand, the values showed the tendency of return to the intermediate temperature ranges when the specimen was slowly cooled down. Characteristic precipitates along the grain boundaries were detected. There was no other singularity up to 700 .deg. C for Alloy 617. However, lots of tiny M{sub 23}C{sub 6} type carbide were formed after 800 .deg. C heat treatment, and those of carbide got bigger and bigger as the heat treatment temperature increased up to 900 .deg. C. For diffusion bonding temperature

  14. Characterization of fatigue mechanisms in nickel-based superalloys

    Science.gov (United States)

    Yablinsky, Clarissa A.

    Ni-based superalloys are important for turbine engine airfoil applications. Historically, creep has been the main failure mode and thus creep mechanisms have been the subject of numerous studies. However, modern airfoil designs maintain cooler temperatures, and consequently creep is no longer the primary failure mode. Rather, in the cooled components, experience and experimental studies have shown that fatigue is the life-limiting factor. The changing cause of failure highlighted the need for a comprehensive study of fatigue deformation mechanisms. Information about crack propagation and the associated deformation mechanisms has allowed appropriate design changes based on fatigue as a life-limiting factor. The focus of the study will be on a monocrystalline Ni-based superalloy, Rene N5, which is currently used for airfoils. Compact tension specimens were tested under cyclic loading conditions to determine the influence of microstructure and material properties on crack propagation and fatigue failure. The crack growth rate as a function of temperature, environment, frequency, and crystallographic orientation was determined. High resolution scanning electron microscopy was used to examine the fracture surface on length scales from nano to macro. Deformation mechanisms in the plastic zone ahead of the crack tip and within the plastic wake of the crack were studied using TEM and FIB techniques. Environment and frequency seem to have a larger effect on fatigue crack growth rates and threshold stress intensity factor ranges, while temperature and orientation effects are present, but not as dramatic. In the normal blade orientation, (001)[100], mode I crack propagation was prevalent, with mode II crack propagation found at higher DeltaK values. Interdendritic particles appear to be slowing crack growth rates in the threshold region of specimens tested in air. Microstructural analysis showed no change in gamma' precipitate size or morphology with temperature or stress

  15. Notes on the distribution of Maesa velutina Mez (Myrsinaceae - a rare and endemic plant from India

    Directory of Open Access Journals (Sweden)

    M.M. Sardesai

    2011-04-01

    Full Text Available The present paper deals with a note on the relocation of Maesa velutina Mez, in Maharashtra state. Notes on distribution, ecology and a short description are provided for the taxon.

  16. Tensile Properties and Deformation Characteristics of a Ni-Fe-Base Superalloy for Steam Boiler Applications

    Science.gov (United States)

    Zhong, Zhihong; Gu, Yuefeng; Yuan, Yong; Shi, Zhan

    2014-01-01

    Ni-Fe-base superalloys due to their good manufacturability and low cost are the proper candidates for boiler materials in advanced power plants. The major concerns with Ni-Fe-base superalloys are the insufficient mechanical properties at elevated temperatures. In this paper, tensile properties, deformation, and fracture characteristics of a Ni-Fe-base superalloy primarily strengthened by γ' precipitates have been investigated from room temperature to 1073 K (800 °C). The results showed a gradual decrease in the strength up to about 973 K (700 °C) followed by a rapid drop above this temperature and a ductility minimum at around 973 K (700 °C). The fracture surfaces were studied using scanning electron microscopy and the deformation mechanisms were determined by the observation of deformed microstructures using transmission electron microscopy. An attempt has been made to correlate the tensile properties and fracture characteristics at different temperatures with the observed deformation mechanisms.

  17. A comparative study of the corrosion resistance of incoloy MA 956 and PM 2000 superalloys

    Directory of Open Access Journals (Sweden)

    Maysa Terada

    2010-12-01

    Full Text Available Austenitic stainless steels, titanium and cobalt alloys are widely used as biomaterials. However, new medical devices require innovative materials with specific properties, depending on their application. The magnetic properties are among the properties of interest for some biomedical applications. However, due to the interaction of magnetic materials with Magnetic Resonance Image equipments they might used only as not fixed implants or for medical devices. The ferromagnetic superalloys, Incoloy MA 956 and PM 2000, produced by mechanical alloying, have similar chemical composition, high corrosion resistance and are used in high temperature applications. In this study, the corrosion resistance of these two ferritic superalloys was compared in a phosphate buffer solution. The electrochemical results showed that both superalloys are passive in this solution and the PM 2000 present a more protective passive film on it associated to higher impedances than the MA 956.

  18. Influence of Processing Parameters on Granularity Distribution of Superalloy Powders during PREP

    Institute of Scientific and Technical Information of China (English)

    Huanming CHEN; Benfu HU; Yiwen ZHANG; Huiying LI; Quanmao YU

    2003-01-01

    In order to investigate the influence of processing parameters on the granularity distribution of superalloy powders during the atomization of plasma rotating electrode processing (PREP), in this paper FGH95 superalloy powders is prepared under different processing conditions by PREP and the influence of PREP processing parameters on the granularity distribution of FGH95 superalloy powders is discussed based on fractal geometry theory. The results show that with the increase of rotating velocity of the self-consuming electrode, the fractal dimension of the granularity distribution increases linearly, which results in the increase of the proportion of smaller powders. The change of interval between plasma gun and the self-consuming electrode has a little effect on the granularity distribution, also the fractal dimension of the granularity distribution changed a little correspondingly.

  19. The Microstructure Stability of Precipitation Strengthened Medium to High Entropy Superalloys

    Science.gov (United States)

    Tsao, Te-Kang; Yeh, An-Chou; Murakami, Hideyuki

    2017-05-01

    Medium and high entropy superalloys based on the Ni-Co-Fe system with strengthening L12 γ' precipitates have been developed. The present study has shown that by controlling the elemental partitioning between γ/γ', thermal stability of γ' can be enhanced in the high entropy γ matrix. Most importantly, high entropy superalloys exhibit stable γ-γ' microstructures with no TCP phases after long-term exposure at elevated temperatures. Therefore, a new alloy design space for stable γ-γ' microstructure has been presented. Furthermore, due to relatively high content of Fe and Ti, their raw materials cost and alloy density can potentially be lower than those of conventional superalloys.

  20. Alloying effects of refractory elements in the dislocation of Ni-based single crystal superalloys

    Directory of Open Access Journals (Sweden)

    Shiyu Ma

    2016-12-01

    Full Text Available The alloying effects of W, Cr and Re in the [100] (010 edge dislocation cores (EDC of Ni-based single crystal superalloys are investigated using first-principles based on the density functional theory (DFT. The binding energy, Mulliken orbital population, density of states, charge density and radial distribution functions are discussed, respectively. It is clearly demonstrated that the addition of refractory elements improves the stability of the EDC systems. In addition, they can form tougher bonds with their nearest neighbour (NN Ni atoms, which enhance the mechanical properties of the Ni-based single crystal superalloys. Through comparative analysis, Cr-doped system has lower binding energy, and Cr atom has evident effect to improve the systemic stability. However, Re atom has the stronger alloying effect in Ni-based single crystal superalloys, much more effectively hindering dislocation motion than W and Cr atoms.

  1. New approach for assessing the weldability of precipitation-strengthened nickel-base superalloys

    Institute of Scientific and Technical Information of China (English)

    Homam Naff akh Moosavy; Mohammad-Reza Aboutalebi; Seyed Hossein Seyedein; Meisam Khodabakhshi; Carlo Mapelli

    2013-01-01

    A new procedure was proposed for evaluating the weldability of nickel-base superalloys. The theory is on the basis of two microstructural patterns. In pattern I, the weld microstructure exhibits severe alloying segregation, many low-melting eutectic structures, and low weldability. The weld requires a weaker etchant and a shorter time for etching. In pattern II, the weld microstructure displays less alloying segregation, low quantity of eutectic structures, and high weldability. The weld needs a stronger etchant and a longer time for etching. Five superalloys containing diff erent amounts of Nb and Ti were designed to verify the patterns. After welding operations, the welds were etched by four etchants with diff erent corrosivities. The weldability was determined by TG-DSC measurements. The metallography and weldability results confirmed the theoretic patterns. Finally, the etchant corrosivity and etching time were proposed as new criteria to evaluate the weldability of nickel-base superalloys.

  2. New approach for assessing the weldability of precipitation-strengthened nickel-base superalloys

    Science.gov (United States)

    Moosavy, Homam Naffakh; Aboutalebi, Mohammad-Reza; Seyedein, Seyed Hossein; Khodabakhshi, Meisam; Mapelli, Carlo

    2013-12-01

    A new procedure was proposed for evaluating the weldability of nickel-base superalloys. The theory is on the basis of two microstructural patterns. In pattern I, the weld microstructure exhibits severe alloying segregation, many low-melting eutectic structures, and low weldability. The weld requires a weaker etchant and a shorter time for etching. In pattern II, the weld microstructure displays less alloying segregation, low quantity of eutectic structures, and high weldability. The weld needs a stronger etchant and a longer time for etching. Five superalloys containing different amounts of Nb and Ti were designed to verify the patterns. After welding operations, the welds were etched by four etchants with different corrosivities. The weldability was determined by TG-DSC measurements. The metallography and weldability results confirmed the theoretic patterns. Finally, the etchant corrosivity and etching time were proposed as new criteria to evaluate the weldability of nickel-base superalloys.

  3. Natural orifice translumenal endoscopic surgery (NOTES): current status and challenges

    Institute of Scientific and Technical Information of China (English)

    ZHANG Xiu-li; YANG Yun-sheng; SUN Gang; GUO Ming-zhou

    2010-01-01

    Objective To give a conceptual description of natural orifice translumenal endoscopic surgery (NOTES), review theearly efforts in the NOTES field, and discuss its challenges and limitations.Data sources The data were retrieved mainly from publications listed in MEDLINE, PubMed and China WanfangDatabase from 2005 to 2009. The search term was "NOTES". Study selection The articles involved in the "NOTES" study were selected and the review articles were excluded from the comparison. Results A marked increase in quantity in articles was shown each year for NOTES studies from 2006 to 2009. Animalexperiments with "NOTES" have been carried out in China from 2007, and two independent "NOTES" procedures onhumans were reported in 2009. Conclusion Although still in its infancy, the "NOTES" procedure is promising as another type of minimally invasivesurgery and favorable alternative to current interventions.

  4. Mechanical properties and development of supersolvus heat treated new nickel base superalloy AD730TM

    Directory of Open Access Journals (Sweden)

    Devaux A.

    2014-01-01

    Full Text Available The enhancement of efficiency in power generation gas turbine requires the development of new superalloys capable of withstanding higher temperatures. The development of AD730TM superalloy was achieved to provide to this new cast & wrought (C&W superalloy a higher combination between mechanical properties, microstructural stability and cost than that of other C&W superalloys with a temperature capability up to 750 ∘C. Supersolvus heat-treatment of AD730TM was studied to improve the creep properties of fine grain AD730TM superalloy which were not high enough to reach the foreseen conditions of future power generation gas turbine disks. Firstly, the grain growth was studied to select the supersolvus temperature 1120 ∘C and to obtain a homogeneous coarse grain microstructure. Then, various supersolvus heat-treatments with different cycles were tested and applied on a forged pancake with a section representative of power generation gas turbine disk. The average grain size was evaluated to be close to 200 μm for all heat-treatments. Tensile, creep, fatigue and fatigue crack growth tests were performed to compare the various heat-treatments. FEG-SEM examinations were also realized to discuss the relationships between heat-treatment, intragranular gamma prime precipitation and mechanical properties. Finally, a comparison made with other supersolvus heat treated C&W superalloys shows that AD730TM properties obtained with coarse grain microstructure are at the expected level and enable applications for power generation gas turbine discs.

  5. Crystallographic, Microstructural, and Mechanical Characterization of Dynamically Processed EP741NP Superalloy

    Science.gov (United States)

    Sharma, A. D.; Sharma, A. K.; Thakur, N.

    2016-08-01

    Considerable progress has been made for the solidification of metal powders with improved properties by using varieties of metallurgical methods. However, solidification of superalloy powders offers many difficulties under traditional processes. This article outlines an extensive program being undertaken to produce monoliths of superalloys with enhanced microstructural and mechanical properties. EP741NP superalloy has been subjected to explosive shock wave loading to obtain uniform and crack-free monoliths. An axisymmetric cylindrical configuration with a plastic explosive of high-detonation velocity has been used to consolidate the superalloy powder nearer to its theoretical density (~98 pct). By careful design of experiments, detonation velocity has been measured vis-à-vis compaction of metal powders in a single-shot experiment by employing instrumented detonics. The shock-processed specimens characterized for phase, lattice parameter, and structural variation by X-ray diffraction technique show intact crystalline structure. Results obtained from Williamson-Hall method indicate small micro-strain (2.8 × 10-3) and decreased crystallite size. Energy-dispersive spectroscopy suggests no segregation within the specimens. Scanning electron microscopy shows fracture-less and micro-cracks/void-free compacts of superalloy indicating satisfactory sub-structural strength. Indentation experiments with variable loads (1.96 N and 2.94 N) performed on the shock-processed specimen cut along transverse section show high order of Vicker's micro-hardness value up to 486 H v. The tensile and compressive strengths of the superalloy monoliths cut along the consolidation axes have been found to be 824 and 834 MPa, respectively.

  6. A Review on Inertia and Linear Friction Welding of Ni-Based Superalloys

    Science.gov (United States)

    Chamanfar, Ahmad; Jahazi, Mohammad; Cormier, Jonathan

    2015-04-01

    Inertia and linear friction welding are being increasingly used for near-net-shape manufacturing of high-value materials in aerospace and power generation gas turbines because of providing a better quality joint and offering many advantages over conventional fusion welding and mechanical joining techniques. In this paper, the published works up-to-date on inertia and linear friction welding of Ni-based superalloys are reviewed with the objective to make clarifications on discrepancies and uncertainties reported in literature regarding issues related to these two friction welding processes as well as microstructure, texture, and mechanical properties of the Ni-based superalloy weldments. Initially, the chemical composition and microstructure of Ni-based superalloys that contribute to the quality of the joint are reviewed briefly. Then, problems related to fusion welding of these alloys are addressed with due consideration of inertia and linear friction welding as alternative techniques. The fundamentals of inertia and linear friction welding processes are analyzed next with emphasis on the bonding mechanisms and evolution of temperature and strain rate across the weld interface. Microstructural features, texture development, residual stresses, and mechanical properties of similar and dissimilar polycrystalline and single crystal Ni-based superalloy weldments are discussed next. Then, application of inertia and linear friction welding for joining Ni-based superalloys and related advantages over fusion welding, mechanical joining, and machining are explained briefly. Finally, present scientific and technological challenges facing inertia and linear friction welding of Ni-based superalloys including those related to modeling of these processes are addressed.

  7. Sticky-Note Murals

    Science.gov (United States)

    Sands, Ian

    2011-01-01

    In this article, the author describes a sticky-note mural project that originated from his desire to incorporate contemporary materials into his assignments as well as to inspire collaboration between students. The process takes much more than sticking sticky notes to the wall. It takes critical thinking skills and teamwork to design and complete…

  8. What is the role of rhenium in single crystal superalloys?

    Directory of Open Access Journals (Sweden)

    Mottura Alessandro

    2014-01-01

    Full Text Available Rhenium plays a critical role in single-crystal superalloys –its addition to first generation alloys improves creep life by a factor of at least two, with further benefits for fatigue performance. Its use in alloys such as PWA1484, CMSX-4 and Rene N5 is now widespread, and many in this community regard Re as the “magic dust”. In this paper, the latest thinking concerning the origins of the “rhenium-effect” is presented. We start by reviewing the hypothesis that rhenium clusters represent barriers to dislocation motion. Recent atom probe tomography experiments have shown that Re may instead form a solid solution with Ni at low concentrations (< 7 at.%. Density functional theory calculations indicate that, in the solid solution, short range ordering of Re may be expected. Finally, Re has been shown to diffuse slowly in the γ-Ni phase. Calculations using a semi-analytical dislocation climb/glide model based upon the work of McLean and Dyson have been used to rationalise the composition-dependence of creep deformation in these materials. All evidence points to two important factors: (i the preferred partitioning of Re to the γ phase, where dislocation activity preferentially occurs during the tertiary creep regime and (ii a retardation effect on dislocation segments at γ/γ′ interfaces, which require non-conservative climb and thus an associated vacancy flux.

  9. High Temperature Deformation Mechanisms in a DLD Nickel Superalloy

    Directory of Open Access Journals (Sweden)

    Sean Davies

    2017-04-01

    Full Text Available The realisation of employing Additive Layer Manufacturing (ALM technologies to produce components in the aerospace industry is significantly increasing. This can be attributed to their ability to offer the near-net shape fabrication of fully dense components with a high potential for geometrical optimisation, all of which contribute to subsequent reductions in material wastage and component weight. However, the influence of this manufacturing route on the properties of aerospace alloys must first be fully understood before being actively applied in-service. Specimens from the nickel superalloy C263 have been manufactured using Powder Bed Direct Laser Deposition (PB-DLD, each with unique post-processing conditions. These variables include two build orientations, vertical and horizontal, and two different heat treatments. The effects of build orientation and post-process heat treatments on the materials’ mechanical properties have been assessed with the Small Punch Tensile (SPT test technique, a practical test method given the limited availability of PB-DLD consolidated material. SPT testing was also conducted on a cast C263 variant to compare with PB-DLD derivatives. At both room and elevated temperature conditions, differences in mechanical performances arose between each material variant. This was found to be instigated by microstructural variations exposed through microscopic and Energy Dispersive X-ray Spectroscopy (EDS analysis. SPT results were also compared with available uniaxial tensile data in terms of SPT peak and yield load against uniaxial ultimate tensile and yield strength.

  10. Structural Performance of Inconel 625 Superalloy Brazed Joints

    Science.gov (United States)

    Chen, Jianqiang; Demers, Vincent; Cadotte, Eve-Line; Turner, Daniel; Bocher, Philippe

    2016-12-01

    The purpose of this work was to investigate tensile and fatigue behaviors of Inconel 625 superalloy brazed joints after transient liquid-phase bonding process. Brazing was performed in a vacuum furnace using a nickel-based filler metal in a form of paste to join wrought Inconel 625 plates. Mechanical tests were carried out on single-lap joints under various lap distance-to-thickness ratios. The fatigue crack initiation and crack growth modes were examined via metallographic analysis, and the effect of local stress on fatigue life was assessed by finite element simulations. The fatigue results show that fatigue strength and endurance limit increase with overlap distance, leading to a relatively large scatter of results. Fatigue cracks nucleated in the high-stressed region of the weld fillets from brittle eutectic phases or from internal brazing cavities. The present work proposes to rationalize the results by using the local stress at the brazing fillet. When using this local stress, all fatigue-obtained results find themselves on a single S-N curve, providing a design curve for any joint configuration in fatigue solicitation.

  11. Laser repairing surface crack of Ni-based superalloy components

    Institute of Scientific and Technical Information of China (English)

    王忠柯; 叶和清; 许德胜; 黄索逸

    2001-01-01

    Surface crack of components of the cast nickel-base superalloy was repaired with twin laser beams under proper technological conditions. One laser beam was used to melt the substrate material of crack, and the other to fill in powder material to the crack region. The experimental results show that the surface crack with the width of 0.1~0.3mm could be repaired under the laser power of 3kW and the scanning speed of 6~8mm/s. The repaired deepness of crack region is below 6.5mm. The microstructure of repaired region is the cellular crystal, columnar crystal dendrite crystal from the transition region to the top filled layer. The phases in repaired region mainly consisted of supersaturated α-Co with plenty of Ni, some Cr and Al, Cr23C6, Co2B, Co-Ni-Mo, Ni4B3, TiSi and VSi. The hardness of filled layer in repaired region ranged from HV0.2450 to HV0.2500, and the hardness decreases gradually from the filled layer to joined zone.

  12. Characterization of a Rapidly Solidified Iron-Based Superalloy

    Science.gov (United States)

    Smugeresky, J. E.

    1982-09-01

    Rapidly-solidified powders of an iron-based superalloy were characterized before and after consolidation by hot isostatic pressing. Powders made by inert gas atomization were compared to powders made by centrifugal atomization. Although many of the powder characteristics were similar, the microstructures were not. The inert gas atomized powder structure is cellular while the centrifugally atomized powder structure is dendritic. In general the finer powder particles have the finer micro-structure with the effect more noticeable in centrifugally atomized powders. After consolidation, the differences in microstructure are more dependent on the consolidation temperature and post-consolidation heat treatment than in the powder type or size. Higher consolidation temperatures and/or post-consolidation heat treatment will result in transformation of the as-solidified microstructures. The transformed microstructure and the mechanical properties can in some cases be related to the as-solidified structure. Heat treatment is needed to obtain mechanical properties equivalent to those of ingot metallurgy processed material.

  13. Friction Freeform Fabrication of Superalloy Inconel 718: Prospects and Problems

    Science.gov (United States)

    Dilip, J. J. S.; Janaki Ram, G. D.

    2013-12-01

    Friction Freeform Fabrication is a new solid-state additive manufacturing process. The present investigation reports a detailed study on the prospects of this process for additive part fabrication in superalloy Inconel 718. Using a rotary friction welding machine and employing alloy 718 consumable rods in solution treated condition, cylindrical-shaped multi-layer friction deposits (10 mm diameter) were successfully produced. In the as-deposited condition, the deposits showed very fine grain size with no grain boundary δ phase. The deposits responded well to direct aging and showed satisfactory room-temperature tensile properties. However, their stress rupture performance was unsatisfactory because of their layered microstructure with very fine grain size and no grain boundary δ phase. The problem was overcome by heat treating the deposits first at 1353 K (1080 °C) (for increasing the grain size) and then at 1223 K (950 °C) (for precipitating the δ phase). Overall, the current study shows that Friction Freeform Fabrication is a very useful process for additive part fabrication in alloy 718.

  14. Properties of GH4169 Superalloy Characterized by Nonlinear Ultrasonic Waves

    Directory of Open Access Journals (Sweden)

    Hongjuan Yan

    2015-01-01

    Full Text Available The nonlinear wave motion equation is solved by the perturbation method. The nonlinear ultrasonic coefficients β and δ are related to the fundamental and harmonic amplitudes. The nonlinear ultrasonic testing system is used to detect received signals during tensile testing and bending fatigue testing of GH4169 superalloy. The results show that the curves of nonlinear ultrasonic parameters as a function of tensile stress or fatigue life are approximately saddle. There are two stages in relationship curves of relative nonlinear coefficients β′ and δ′ versus stress and fatigue life. The relative nonlinear coefficients β′ and δ′ increase with tensile stress when tensile stress is lower than 65.8% of the yield strength, and they decrease with tensile stress when tensile stress is higher than 65.8% of the yield strength. The nonlinear coefficients have the extreme values at 53.3% of fatigue life. For the second order relative nonlinear coefficient β′, there is good agreement between the experimental data and the comprehensive model. For the third order relative nonlinear coefficient δ′, however, the experiment data does not accord with the theoretical model.

  15. ISOTHERMAL AND THERMOMECHANICAL FATIGUE OF A NICKEL-BASE SUPERALLOY

    Directory of Open Access Journals (Sweden)

    Carlos Carvalho Engler-Pinto Júnior

    2014-06-01

    Full Text Available Thermal gradients arising during transient regimes of start-up and shutdown operations produce a complex thermal and mechanical fatigue loading which limits the life of turbine blades and other engine components operating at high temperatures. More accurate and reliable assessment under non-isothermal fatigue becomes therefore mandatory. This paper investigates the nickel base superalloy CM 247LC-DS under isothermal low cycle fatigue (LCF and thermomechanical fatigue (TMF. Test temperatures range from 600°C to 1,000°C. The behavior of the alloy is strongly affected by the temperature variation, especially in the 800°C-1,000°C range. The Ramberg-Osgood equation fits very well the observed isothermal behavior for the whole temperature range. The simplified non-isothermal stress-strain model based on linear plasticity proposed to represent the thermo-mechanical fatigue behavior was able to reproduce the observed behavior for both in-phase and out-of-phase TMF cycling.

  16. Temperature Dependent Cyclic Deformation Mechanisms in Haynes 188 Superalloy

    Science.gov (United States)

    Rao, K. Bhanu Sankara; Castelli, Michael G.; Allen, Gorden P.; Ellis, John R.

    1995-01-01

    The cyclic deformation behavior of a wrought cobalt-base superalloy, Haynes 188, has been investigated over a range of temperatures between 25 and 1000 C under isothermal and in-phase thermomechanical fatigue (TMF) conditions. Constant mechanical strain rates (epsilon-dot) of 10(exp -3)/s and 10(exp -4)/s were examined with a fully reversed strain range of 0.8%. Particular attention was given to the effects of dynamic strain aging (DSA) on the stress-strain response and low cycle fatigue life. A correlation between cyclic deformation behavior and microstructural substructure was made through detailed transmission electron microscopy. Although DSA was found to occur over a wide temperature range between approximately 300 and 750 C the microstructural characteristics and the deformation mechanisms responsible for DSA varied considerably and were dependent upon temperature. In general, the operation of DSA processes led to a maximum of the cyclic stress amplitude at 650 C and was accompanied by pronounced planar slip, relatively high dislocation density, and the generation of stacking faults. DSA was evidenced through a combination of phenomena, including serrated yielding, an inverse dependence of the maximum cyclic hardening with epsilon-dot, and an instantaneous inverse epsilon-dot sensitivity verified by specialized epsilon-dot -change tests. The TMF cyclic hardening behavior of the alloy appeared to be dictated by the substructural changes occuring at the maximum temperature in the TMF cycle.

  17. Microstructure stability: Optimisation of 263 Ni-based superalloy

    Directory of Open Access Journals (Sweden)

    Crozet Coraline

    2014-01-01

    Full Text Available To reduce CO2 emissions on coal-fired power plant, A-ultra supercritical (A-USC power plant whose steam conditions exceed 700 °C are being developed. At these elevated temperatures, the use of Ni-base superalloys becomes necessary. In this context and within the European project NextGenPower, focus is made on commercial Nimonic C-263 as a candidate material for turbine rotors. Nimonic C-263 is known to have low sensitivity to segregation, high workability and high weldability which are major properties for the manufacture of large shafts. Long-term creep strength is also required for this application and unfortunately Nimonic C-263 shows η-phase precipitation after long-time exposure between 700 °C–900 °C which is detrimental for long-term creep properties. The composition of Nimonic C-263 was thus optimised to overcome the formation of η-phase. Trial tests were made in order to study the effect of hardening contribution elements on microstructural and mechanical properties. Then, a 500 mm diameter forged rotor was made from optimised 263 alloy and shows promising properties.

  18. Kinetics of Grain Growth in 718 Ni-Base Superalloy

    Directory of Open Access Journals (Sweden)

    Huda Z.

    2014-10-01

    Full Text Available The Haynes® 718 Ni-base superalloy has been investigated by use of modern material characterization, metallographic and heat treatment equipment. Grain growth annealing experiments at temperatures in the range of 1050 – 1200 oC (1323–1473K for time durations in the range of 20 min-22h have been conducted. The kinetic equations and an Arrhenius-type equation have been applied to compute the grain-growth exponent n and the activation energy for grain growth, Qg, for the investigated alloy. The grain growth exponent, n, was computed to be in the range of 0.066-0.206; and the n values have been critically discussed in relation to the literature. The activation energy for grain growth, Qg, for the investigated alloy has been computed to be around 440 kJ/mol; and the Qg data for the investigated alloy has been compared with other metals and alloys and ceramics; and critically analyzed in relation to our results.

  19. FATIGUE CRACK PROPAGATION OF Ni-BASE SUPERALLOYS

    Institute of Scientific and Technical Information of China (English)

    X.B.Liu; L.Z.Ma; K.M.Chang; E.Barbero

    2005-01-01

    Time-dependent Fatigue Crack Propagation (FCP) behaviors of five Ni-base superalloys were investigated at various temperatures under fatigue with various holding times and sustained loading conditions.The new concept of damage zone is defined and employed to evaluate the alloys' resistance to hold-time FCP.A special testing procedure is designed to get the maximum damage zone of the alloys.Udimet 720 and Waspaloy show shorter damage zones than alloys 706 and 718.The fractographical analyses show that the fracture surfaces of the specimens under hold-time fatigue conditions are mixtures with intergranular and transgranular modes.As the extension of holding time per cycle, the portion of intergranular fracture increases.The effects of loading stress intensity, temperature, holding time, alloy chemistry, and alloy microstructure on damage zone and the crack growth behaviors are studied.Hold-time usually increases the alloy's FCP rate, but there are few exemptions.For instance, the steady state hold-time FCP rate of Waspaloy at 760℃ is lower than that without hold-time.The beneficial effect of hold-time was attributed to the creep caused stress relaxation during the hold-time.

  20. Anisotropy of nickel-base superalloy single crystals

    Science.gov (United States)

    Mackay, R. A.; Maier, R. D.; Dreshfield, R. L.

    1980-01-01

    The effects of crystal orientation on the mechanical properties of single crystals of the nickel-based superalloy Mar-M247 are investigated. Tensile tests at temperatures from 23 to 1093 C and stress rupture tests at temperatures from 760 to 1038 C were performed for 52 single crystals at various orientations. During tensile testing between 23 and 760 C, single crystals with high Schmid factors were found to be favorably oriented for slip and to exhibit lower strength and higher ductility than those with low Schmid factors. Crystals which required large rotations to become oriented for cross slip were observed to have the shortest stress rupture lives at 760 C, while those which required little or no rotation had the longest lives. In addition, stereographic triangles obtained for Mar-M247 and Mar-M200 single crystals reveal that crystals with orientations near the -111 had the highest lives, those near the 001 had high lives, and those near the 011 had low lives.

  1. Microstructural and Chemical Rejuvenation of a Ni-Based Superalloy

    Science.gov (United States)

    Yao, Zhiqi; Degnan, Craig C.; Jepson, Mark A. E.; Thomson, Rachel C.

    2016-10-01

    The microstructural evolution of the Ni-based superalloy CMSX-4 including the change in gamma prime morphology, size, and distribution after high-temperature degradation and subsequent rejuvenation heat treatments has been examined using field emission gun scanning electron microscopy and transmission electron microscopy. In this paper, it is shown that there are significant differences in the size of the `channels' between gamma prime particles, the degree of rafting, and the size of tertiary gamma prime particles in each of the different microstructural conditions studied. Chemical analysis has been carried out to compare rejuvenated and pre-service samples after the same subsequent degradation procedure. The results indicate that although the microstructures of pre-service and rejuvenated samples are similar, chemical differences are more pronounced in the rejuvenated samples, suggesting that chemical segregation from partitioning of the elements was not completely eliminated through the applied rejuvenation heat treatment. A number of modified rejuvenation heat treatment trials were carried out to reduce the chemical segregation prior to creep testing. The creep test results suggest that chemical segregation has an immeasurable influence on the short-term mechanical properties under the test conditions used here, indicating that further work is required to fully understand the suitability of specific rejuvenation heat treatments and their role in the extension of component life in power plant applications.

  2. Fatigue crack propagation in turbine disks of EI698 superalloy

    Directory of Open Access Journals (Sweden)

    A.A. Shanyavskiy

    2013-04-01

    Full Text Available In-service fatigue cracking of turbine disks of EI698 superalloy is discussed based on crack growth analyses. In the bolt joint for disks to shaft connecting there is high level of stress-state, which directed to earlier in-disks fatigue crack origination in low-cycle-fatigue regime. Fracture surface pattern such as fatigue striations were used for their spacing measurement and crack growth duration estimating. Developed disk tests on a special bench by the equivalent program to in-service cyclic loads have allowed discovering one-to-one correlation between fatigue striation spacing and crack increment in one flight. Number of fatigue striations and beach-marks calculations permitted to estimate crack growth period for the different stages of in-service disks cracking. Equivalent stress level for in-service cracked disks was calculated and compared with stress-level in-tested disks under stress equivalent program to in-service operated cyclic loads. Based on this result non-destructive inspection intervals were discussed and recommended for in-service disks in dependence on number of their flights at the moment of developed inspection to exclude in-flight disks fast fracture.

  3. Anisotropy of nickel-base superalloy single crystals

    Science.gov (United States)

    Mackay, R. A.; Maier, R. D.; Dreshfield, R. L.

    1980-01-01

    The effects of crystal orientation on the mechanical properties of single crystals of the nickel-based superalloy Mar-M247 are investigated. Tensile tests at temperatures from 23 to 1093 C and stress rupture tests at temperatures from 760 to 1038 C were performed for 52 single crystals at various orientations. During tensile testing between 23 and 760 C, single crystals with high Schmid factors were found to be favorably oriented for slip and to exhibit lower strength and higher ductility than those with low Schmid factors. Crystals which required large rotations to become oriented for cross slip were observed to have the shortest stress rupture lives at 760 C, while those which required little or no rotation had the longest lives. In addition, stereographic triangles obtained for Mar-M247 and Mar-M200 single crystals reveal that crystals with orientations near the -111 had the highest lives, those near the 001 had high lives, and those near the 011 had low lives.

  4. Microstructural and Chemical Rejuvenation of a Ni-Based Superalloy

    Science.gov (United States)

    Yao, Zhiqi; Degnan, Craig C.; Jepson, Mark A. E.; Thomson, Rachel C.

    2016-12-01

    The microstructural evolution of the Ni-based superalloy CMSX-4 including the change in gamma prime morphology, size, and distribution after high-temperature degradation and subsequent rejuvenation heat treatments has been examined using field emission gun scanning electron microscopy and transmission electron microscopy. In this paper, it is shown that there are significant differences in the size of the `channels' between gamma prime particles, the degree of rafting, and the size of tertiary gamma prime particles in each of the different microstructural conditions studied. Chemical analysis has been carried out to compare rejuvenated and pre-service samples after the same subsequent degradation procedure. The results indicate that although the microstructures of pre-service and rejuvenated samples are similar, chemical differences are more pronounced in the rejuvenated samples, suggesting that chemical segregation from partitioning of the elements was not completely eliminated through the applied rejuvenation heat treatment. A number of modified rejuvenation heat treatment trials were carried out to reduce the chemical segregation prior to creep testing. The creep test results suggest that chemical segregation has an immeasurable influence on the short-term mechanical properties under the test conditions used here, indicating that further work is required to fully understand the suitability of specific rejuvenation heat treatments and their role in the extension of component life in power plant applications.

  5. Notch Fatigue Strength of a PM Disk Superalloy

    Science.gov (United States)

    Gayda, John; Gabb, Timothy P.; Telesman, Jack

    2007-01-01

    New powder metallurgy (PM) disk superalloys, such as ME3, LSHR, and Alloy 10, have been developed in recent years which enable rim temperatures in turbine disk applications to approach 1300 F. Before these alloys can be utilized at 1300 F their long term durability must be ensured. One of the key requirements for disk rims is notch fatigue strength. This issue is extremely important and is a direct result of the blade attachment geometry employed at the disk rim. Further, the imposition of a dwell at maximum load, associated with take off and landing, can also affect notch fatigue strength. For these reasons a study has been undertaken to assess the notch dwell fatigue strength of a modern PM disk alloy through spin pit evaluation of a prototypical disk. The first element of this program involves screening potential heat treatments with respect to notch fatigue strength at 1300 F utilizing a conventional notch fatigue specimen with a stress concentration factor (K(sub t)) of 2 and a 90 sec dwell at peak load. The results of this effort are reported in this paper including the downselect of an optimal heat treatment, from a notch fatigue standpoint.

  6. Numerical analysis on solidification process and heat transfer of FGH95 superalloy droplets during PREP

    Institute of Scientific and Technical Information of China (English)

    Huanming Chen; Benfu Hu; Yiwen Zhang; Quanmao Yu; Huiying Li

    2003-01-01

    In order to understand the relation between microstructure of superalloy powders and its solidification progress, the processing parameters are optimized during plasma rotating electrode processing (PREP). It was predicted from the results that the droplet velocities, droplet temperature, and fractional solidification with flight time about FGH95 superalloy droplet have been carried out based on Newtonian heat transfer formulation coupled with the classical heterogeneous nucleation and the specific solidification process. It has been found that the droplet dynamic and thermal behavior is strongly affected by the distribution of droplet diameters,the proportion of cooling atmosphere, but is relatively unaffected by the droplet superheat.

  7. Enhanced Corrosion Resistance of a Transient Liquid Phase Bonded Nickel-Based Superalloy

    Science.gov (United States)

    Adebajo, O. J.; Ojo, O. A.

    2017-01-01

    Electrochemical analysis of corrosion performance of a transient liquid phase (TLP) bonded nickel-based superalloy was performed. The TLP bonding process resulted in significant reduction in corrosion resistance due to the formation of non-equilibrium solidification reaction micro-constituents within the joint region. The corrosion resistance degradation is completely eliminated through a new application of composite interlayer that had been previously considered unusable for joining single-crystal superalloys. The effectiveness of the new approach becomes more pronounced as the severity of environment increases.

  8. Microstructural Investigations and Modelling of Interdiffusion between MCrAlY Coating and IN738 Superalloy

    DEFF Research Database (Denmark)

    Dahl, Kristian Vinter; Hald, John

    2006-01-01

    Interdiffusion at the interface between a Co-36.5Ni-17.5Cr-8Al-0.5Y, MCrAlY coating and the underlying IN738 superalloy was studied in a large matrix of specimens isothermally heat treated for up to 12,000 hours at temperatures 875°C, 925°C or 950°C. Microstructural investigations and calculated...... phase fraction diagrams show that a precipitate free zone forms between the coating and superalloy and grows with time. Measured composition profiles across the interface were compared with modelled results obtained using the finite difference software DICTRA. The simulated results were able...

  9. Effect of Phosphorus on Microstructure and High Temperature Properties of a Cast Ni-base Superalloy

    Institute of Scientific and Technical Information of China (English)

    2002-01-01

    Effect of phosphorus on the microstructure and high temperature properties of a cast Ni-base superalloy M963 has been investigated. SEM observation and EDS analysis showed that P was mostly enriched in the interdendritic region, and the P-rich phase was formed in the front position of finally solidified eutectics in high P doped alloys. It was found that the P-rich phase, as preferred initiation and propagation site of cracks, could aggravate the fracture process at high temperature in high P doped alloys. Consequently, high P addition would reduce remarkably the ductility and creep life of M963 superalloy at high temperature.

  10. SOLIDIFICATION OF NICKEL-BASED SINGLE CRYSTAL SUPERALLOY BY ELECTRIC FIELD

    Institute of Scientific and Technical Information of China (English)

    Y.S. Yang; X.H. Feng; G.F. Cheng; Y.J. Li; Z.Q. Hu

    2005-01-01

    The crystal growth of a nickel-based single crystal superalloy DD3 was researched via controlled directional solidification under the action of a DC electric field. The cellular or dendrite spacing of the single crystal superalloy is refined and microsegregation of alloying elements Al,Ti, Mo and W, is reduced by the electric field. The electric field decreases the interface stability and reduces the critical growth rate of the cellular-dendritic translation because of Thomson effect and Joule heating. The precipitation of the γ' phase is more uniform and the size of the γ'phase is smaller with the electric field than that without the electric field.

  11. High temperature thermal diffusivity of nickel-based superalloys and intermetallic compounds

    OpenAIRE

    Hazotte, A.; Perrot, B.; Archambault, P

    1993-01-01

    By means of an installation developed in our laboratory, we measured the thermal diffusivity (α) as a function of temperature for several single and polycrystal nickel-based superalloys as well as for different intermetallic compounds with a L12 (Ni3Al, Ni3Si, Ni3Ge, Ni3Fe, Zr3Al, Co3Ti), L10 (TiAl) or B2 (NiAl) structure. In the case of nickel-based superalloys, the experiments pointed out an unexpected but reproductible slope change in the α=f(T) curves at about 750°C, which is not explaine...

  12. An overview of the measurements of thermophysical properties and some results on molten superalloys and semiconductors

    Science.gov (United States)

    Taylor, R. E.

    1993-01-01

    This presentation consists of two parts: comments on the results of measurements on thermophysical properties based on the paper, 'Things Mother Never Taught Me (About Thermophysical Properties of Solids)' and results of thermophysical property measurements on selected solid and molten semiconductors and a proprietary superalloy. The first part may be considered as a tutorial for those involved in using or procuring thermophysical property data. The second part is presented as illustrations of what has been accomplished on molten materials at the Thermophysical Properties Research Laboratory (TPRL). The materials include Ge, PbTe, PbSnTe, HgCdTe and a superalloy.

  13. Analyzing Sound Waves Produced by Musical Notes & Chords.

    Science.gov (United States)

    Cassidy, Michael

    This project description is designed to show how graphing calculators and calculator-based laboratories (CBL) can be used to explore topics in the physics of sound. The activities address topics such as sound waves, musical notes, and chords. Teaching notes, calculator instructions, and blackline masters are included. (MM)

  14. Descriptive Research

    DEFF Research Database (Denmark)

    Wigram, Anthony Lewis

    2003-01-01

    Descriptive research is described by Lathom-Radocy and Radocy (1995) to include Survey research, ex post facto research, case studies and developmental studies. Descriptive research also includes a review of the literature in order to provide both quantitative and qualitative evidence of the effect...... of music therapy with a specific population (Gold, Voracek & Wigram, Wigram, 2002). The collection of such evidence, through surveys of the literature and documentation of music therapy studies that show effect with a specified population are becoming increasingly important in order to underpin music...

  15. Grouping Notes Through Nodes

    DEFF Research Database (Denmark)

    Dove, Graham; Abildgaard, Sille Julie Jøhnk; Biskjær, Michael Mose

    The Post-ItTM note is a frequently used, and yet seldom studied, design material. We investigate the functions Post-ItTM notes serve when providing cognitive support for creative design team practice. Our investigation considers the ways in which Post-ItTM notes function as design externalisations......, both individually and when grouped, and their role in categorisation in semantic long-term memory. To do this, we adopt a multimodal analytical approach focusing on interaction between humans, and between humans and artefacts, alongside language. We discuss in detail examples of four different...

  16. Physicians’ progress notes

    DEFF Research Database (Denmark)

    Bansler, Jørgen P.; Havn, Erling C.; Mønsted, Troels

    2013-01-01

    care, they have not dealt specifically with the role, structure, and content of the progress notes. As a consequence, CSCW research has not yet taken fully into account the fact that progress notes are coordinative artifacts of a rather special kind, an open-ended chain of prose texts, written...... sequentially by cooperating physicians for their own use as well as for that of their colleagues. We argue that progress notes are the core of the medical record, in that they marshal and summarize the overwhelming amount of data that is available in the modern hospital environment, and that their narrative...

  17. Notes on the genus Digitaria, with descriptions of new species

    NARCIS (Netherlands)

    Henrard, J.Th.

    1934-01-01

    Some years ago I had the opportunity to study more extensively a very interesting group of grasses, belonging to what is now accepted as a distinct genus, the genus Digitaria, formerly belonging as a subgenus to the genus Panicum. As to living plants of this group I was familiar with two european sp

  18. The Effect of Forging Variables on the Supersolvus Heat-Treatment Response of Powder-Metallurgy Nickel-Base Superalloys

    Science.gov (United States)

    2014-12-01

    AFRL-RX-WP-JA-2015-0160 THE EFFECT OF FORGING VARIABLES ON THE SUPERSOLVUS HEAT-TREATMENT RESPONSE OF POWDER-METALLURGY NICKEL -BASE SUPERALLOYS...POWDER-METALLURGY NICKEL - BASE SUPERALLOYS (POSTPRINT) 5a. CONTRACT NUMBER In-house 5b. GRANT NUMBER 5c. PROGRAM ELEMENT NUMBER 62102F 6. AUTHOR...of Powder-Metallurgy Nickel -Base Superalloys S.L. SEMIATIN, J.M. SHANK, A.R. SHIVELEY, W.M. SAURBER, E.F. GAUSSA, and A.L. PILCHAK The effect of

  19. Evaluation of Characteristics of Non-Metallic Inclusions in P/M Ni-Base Superalloy by Automatic Image Analysis

    Institute of Scientific and Technical Information of China (English)

    Li; Xinggang; Ge; Changchun; Shen; Weiping

    2007-01-01

    Non-metallic inclusions,especially the large ones,within P/M Ni-base superalloy have a major influence on fatigue characteristics,but are not directly measurable by routine inspection.In this paper,a method,automatic image analysis,is proposed for estimation of the content,size and amount of non-metallic inclusions in superalloy.The methodology for the practical application of this method is described and the factors affecting the precision of the estimation are discussed.In the experiment,the characteristics of the non-metallic inclusions in Ni-base P/M superalloy are analyzed.

  20. NCEP Internal Office Notes

    Data.gov (United States)

    National Oceanic and Atmospheric Administration, Department of Commerce — The National Centers for Environmental Prediction (NCEP) and its predecessors have produced internal publications, known as Office Notes, since the mid-1950's. In...

  1. Walrus parts collection notes

    Data.gov (United States)

    US Fish and Wildlife Service, Department of the Interior — The attached field diary notes provide documentation of walrus parts collection activities which occurred in the Nome and surrounding area during the periods of May...

  2. Seed collection notes

    Data.gov (United States)

    US Fish and Wildlife Service, Department of the Interior — This document contains tables, lists, and notes related to tallgrass prairie seed collection on Neal Smith National Wildlife Refuge in 1992.

  3. Physicians’ Progress Notes

    DEFF Research Database (Denmark)

    Bansler, Jørgen; Havn, Erling C.; Mønsted, Troels

    2013-01-01

    This paper examines physicians’ progress notes, an artifact that, in spite of its obvious importance in the coordination of cooperative work in clinical settings, has not been subjected to systematic study under CSCW auspices. While several studies have addressed the role of the medical record...... in patient care, they have not dealt specifically with the role, structure, and content of the progress notes. As a consequence, CSCW research has not yet taken fully into account the fact that progress notes are coordinative artifacts of a rather special kind, an open-ended chain of prose texts, written...... sequentially by cooperating physicians for their own use as well as for that of their colleagues. We argue that progress notes are the core of the medical record, in that they marshal and summarize the overwhelming amount of data that is available in the modern hospital environment, and that their narrative...

  4. Development of a database for the prediction of phases in Pt-based Superalloys: Cr-Pt-Ru

    Institute of Scientific and Technical Information of China (English)

    A. Watson; L.A. Cornish; R. Süss

    2006-01-01

    Work has been ongoing in building a thermodynamic database for the prediction of phase equilibria in Pt-based superalloys. The alloys are being developed for high temperature applications in aggressive environments. The database will aid the design of alloys by enabling the calculation of the composition and proportions of phases present in alloys of differ ent compositions. In order to extend this database, a preliminary assessment of the Cr-Pt-Ru system has been undertaken,using a combination of Pandat and MTDATA software. As a first step, it was necessary to provide thermodynamic models for the three associated binary systems. Owing to a lack of thermodynamic information for these systems, the binary assessments were based on phase diagrams available in the literature. Using recent experimental phase equilibria data for the ternary system, a preliminary assessment of the Cr-Pt-Ru system has been produced. In this preliminary assessment, simplified models were employed for the L12 and sigma phases with a view to extending the descriptions as new experimental information becomes available.

  5. Analytical dynamics course notes

    CERN Document Server

    Lindenbaum, Samuel D

    1994-01-01

    This book comprises a set of lecture notes on rational mechanics, for part of the graduate physics curriculum, delivered by the late Prof. Shirley L. Quimby during his tenure at Columbia University, New York. The notes contain proofs of basic theorems, derivations of formulae and amplification of observations, as well as the presentation and solution of illustrative problems. Collateral readings from more than 50 source references are indicated at appropriate places in the text.

  6. Hot Deformation Characteristics for a Nickel-base Superalloy GH742y

    Institute of Scientific and Technical Information of China (English)

    Fuwei Kang; Jianfei Sun; Guoqing Zhang; Zhou Li

    2009-01-01

    The hot deformation characteristics of as-cast nickel-base superalloy GH742y after hot isostatic pressing (HIP)(hereafter referred to as-cast alloy) have been investigated by hot compression tests in the temperature range of 1050 to 1140℃, strain rate range of 0.01 s-1 to 10 s-1 and strain range of 35% to 50% by means of Gleeble-3500 thermal mechanical simulator.The results show that the as-cast alloy exhibits the poor deformability, and shows wedge-shaped cracking beyond the strain of 35%.At strain rates less than 1.0 s-1,the stress-strain curves exhibit nearly steady-state behavior, while at strain rate of 10 s-1, a yield drop and serrated yielding occur.The activation energy values developed on the basis of the experimental data are divided into three domains.The first domain appears at lower strain rate (≤1.0 s-1) and lower temperature (≤1080℃), with the lowest mean value of activation energy about 261.4 kJ/mol.The second domain appears at the same strain rate as the first domain, but higher temperature (>1080℃), with the intermediate mean value of activation energy about 328.8 kJ/mol.The third domain appears at higher strain rate (10 s-1) and temperature range of 1050 to 1140℃, with the largest mean value of activation energy about 605.05 kJ/mol.Three different constitutive equations are established in corresponding to domains.Microstructural observations in the third domain reveal non-uniform dynamic recrystallization (DRX) of homogeneous γ phase, which leads to the poor deformability and the highest Q value.In contrast, microstructures in the first domain show fully DRX of homogeneous γ phase, leading to the better deformability and the lowest Q value.It is noted that the grain size increases with the increment of strain rate or temperature.These results suggest that bulk metal working of this material may be carried out in the first domain where fully DRX of γ homogeneous occurred.

  7. Time-incremental creep–fatigue damage rule for single crystal Ni-base superalloys

    NARCIS (Netherlands)

    Tinga, T.; Brekelmans, W.A.M.; Geers, M.G.D.

    2009-01-01

    In the present paper a damage model for single crystal Ni-base superalloys is proposed that integrates time-dependent and cyclic damage into a generally applicable time-incremental damage rule. A criterion based on the Orowan stress is introduced to detect slip reversal on the microscopic level and

  8. Recovery of Nickel from Nickel-Based Superalloy Scraps by Utilizing Molten Zinc

    Science.gov (United States)

    Yagi, Ryohei; Okabe, Toru H.

    2017-02-01

    With the purpose of developing a new process for recycling nickel (Ni) directly from superalloy scraps, a fundamental study on the extraction and separation of Ni was carried out using molten zinc (Zn) as the extraction medium. In order to examine the reaction between molten Zn and the Ni-based superalloy, superalloy samples and Zn shots were heated at 1173 K (900 °C) for 6 hours. After heating, the superalloy samples fully reacted with Zn and dissolved in molten Zn. The Zn-alloyed sample obtained by slow cooling consisted of two separated upper and lower phases. In the upper part of the sample, only Zn and the Zn-Ni alloys were found; in the lower part, an intermetallic alloy consisting of refractory metals such as rhenium (Re) and tantalum (Ta) was found. This result shows that Ni and refractory metals contained in the scrap can be separated by utilizing the density differences between the Zn-Ni alloy and the refractory metals in molten Zn. Vacuum treatment of the upper part of the Zn-alloyed sample at 1173 K (900 °C) reduced the concentration of Zn in the sample from 97.0 to 0.4 mass pct. After Zn removal, a Ni alloy containing Ni with a purity of 85.3 to 86.1 mass pct and negligible quantities (scraps without the consumption of Zn or the generation of toxic wastes solutions.

  9. US/Japan Seminar on Superalloys Held at Susono, Japan on 7-11 December 1984.

    Science.gov (United States)

    2014-09-26

    University of Technology) STRENGTH AND PHASE STABILITY OF Ni Al INTERMETALLIC COMPOUNDS -TOWARD ALLOY DESIGN OF SUPERALLOYS- Y. Mishima , T. Suzuki (Tokyo...Kawasaki Heavy Industries, Technical Institute Nishiyama, Yukio Kawasaki Heavy Industries, Technical Institute Tanaka, Shoji Kawasaki Steel, Research...Technology Matsuo, Takashi Tokyo Institute of Technology Mishima , Yoshinao Tokyo Institute of Technology Takeyama, Masao Tokyo Institute of

  10. Freckle Defect Formation near the Casting Interfaces of Directionally Solidified Superalloys

    Directory of Open Access Journals (Sweden)

    Jianping Hong

    2016-11-01

    Full Text Available Freckle defects usually appear on the surface of castings and industrial ingots during the directional solidification process and most of them are located near the interface between the shell mold and superalloys. Ceramic cores create more interfaces in the directionally solidified (DS and single crystal (SX hollow turbine blades. In order to investigate the location of freckle occurrence in superalloys, superalloy CM247 LC was directionally solidified in an industrial-sized Bridgman furnace. Instead of ceramic cores, Alumina tubes were used inside of the casting specimens. It was found that freckles occur not only on the casting external surfaces, but also appear near the internal interfaces between the ceramic core and superalloys. Meanwhile, the size, initial position, and area of freckle were investigated in various diameters of the specimens. The initial position of the freckle chain reduces when the diameter of the rods increase. Freckle area follows a linear relationship in various diameters and the average freckle fraction is 1.1% of cross sectional area of casting specimens. The flow of liquid metal near the interfaces was stronger than that in the interdendritic region in the mushy zone, and explained why freckle tends to occur on the outer or inner surfaces of castings. This new phenomenon suggests that freckles are more likely to occur on the outer or inner surfaces of the hollow turbine blades.

  11. Use of atomic force microscopy to quantify slip irreversibility in a nickel-base superalloy

    Energy Technology Data Exchange (ETDEWEB)

    Risbet, M.; Feaugas, X.; Guillemer-Neel, C.; Clavel, M

    2003-09-15

    Atomic force microscopy was used to study the evolution of surface deformation during cyclic loading in a nickel-base superalloy. Cyclic slip irreversibility has been investigated using quantitative evaluation of extrusion heights and inter-band spacing. This approach is applied to formulate a microscopic crack initiation law, compared to a classical Manson-Coffin relationship.

  12. Combustion Synthesis of NiAl and In-situ Joining to Ni-based Superalloy

    Institute of Scientific and Technical Information of China (English)

    2001-01-01

    Combustion synthesis is used as a joining technology to join Ni-based superalloys with in-situ synthesized NiAl filler. The synthesis mechanism is discussed. The microstructure of the joints is investigated and the joint strength is also evaluated by tensile testing.

  13. Cube slip and non-Schmid effects in single crystal Ni-base superalloys

    NARCIS (Netherlands)

    Tinga, T.; Brekelmans, W.A.M.; Geers, M.G.D.

    2010-01-01

    An advanced constitutive model incorporating two specific aspects of Ni-base superalloy deformation behaviour is proposed. Several deformation mechanisms are active in these two-phase materials. In the matrix phase, cube slip plays an important role in the orientation dependence of the material. Mor

  14. Directional coarsening in nickel-base superalloys and its effect on the mechanical properties

    NARCIS (Netherlands)

    Tinga, T.; Brekelmans, W.A.M.; Geers, M.G.D.

    2009-01-01

    During high temperature loading, the regular microstructure of nickel-base superalloys consisting of a γ-matrix (Ni) containing a large volume fraction of γ′-particles (Ni3Al) degrades. The cubic precipitates coarsen and elongate in a direction normal to the applied stress in a process called raftin

  15. Alloy Design Challenge: Development of Low Density Superalloys for Turbine Blade Applications

    Science.gov (United States)

    MacKay, Rebecca A.; Gabb, Timothy P.; Smialek, James L.; Nathal, Michael V.

    2009-01-01

    New low density single crystal (LDS) alloys have been developed for turbine blade applications, which have the potential for significant improvements in the thrust to weight ratio over current production alloys. An innovative alloying strategy was identified to achieve high temperature creep resistance, alloy density reductions, microstructural stability, and cyclic oxidation resistance. The approach relies on the use of molybdenum (Mo) as a potent solid solution strengthener for the nickel (Ni)-base superalloy; Mo has a density much closer to Ni than other refractory elements, such as rhenium (Re) or tungsten (W). A host of testing and microstructural examinations was conducted on the superalloy single crystals, including creep rupture testing, microstructural stability, cyclic oxidation, and hot corrosion. The paper will provide an overview of the single crystal properties that were generated in this new superalloy design space. The paper will also demonstrate the feasibility of this innovative approach of low density single crystal superalloy design. It will be shown that the best LDS alloy possesses the best attributes of three generations of single crystal alloys: the low density of first-generation single crystal alloys, the excellent oxidation resistance of second-generation single crystal alloys, and a creep strength which exceeds that of second and third generation alloys.

  16. Mechanisms of High Temperature/Low Stress Creep of Ni-Based Superalloy Single Crystals

    Energy Technology Data Exchange (ETDEWEB)

    Michael J. Mills

    2009-03-05

    Cast nickel-based superalloys are used for blades in land-based, energy conversion and powerplant applications, as well as in aircraft gas turbines operating at temperatures up to 1100 C, where creep is one of the life-limiting factors. Creep of superalloy single crystals has been extensively studied over the last several decades. Surprisingly, only recently has work focused specifically on the dislocation mechanisms that govern high temperature and low stress creep. Nevertheless, the perpetual goal of better engine efficiency demands that the creep mechanisms operative in this regime be fully understood in order to develop alloys and microstructures with improved high temperature capability. At present, the micro-mechanisms controlling creep before and after rafting (the microstructure evolution typical of high temperature creep) has occurred have yet to be identified and modeled, particularly for [001] oriented single crystals. This crystal orientation is most interesting technologically since it exhibits the highest creep strength. The major goal of the program entitled ''Mechanisms of High Temperature/Low Stress Creep of Ni-Based Superalloy Single Crystals'' (DOE Grant DE-FG02-04ER46137) has been to elucidate these creep mechanisms in cast nickel-based superalloys. We have utilized a combination of detailed microstructure and dislocation substructure analysis combined with the development of a novel phase-field model for microstructure evolution.

  17. Refractory porcelain enamel passive-thermal-control coating for high-temperature superalloys

    Science.gov (United States)

    Levin, H.; Auker, B. H.; Gardos, M. N.

    1973-01-01

    Study was conducted to match thermal expansion coefficients thereby preventing enamels from cracking. Report discusses various enamel coatings that are applied to two different high-temperature superalloys. Study may be of interest to manufacturers of chemical equipment, furnaces, and metal components intended for high-temperature applications.

  18. Effect of Yttrium on High Temperature Oxidation Resistance of a Directionally Solidified Superalloy

    Institute of Scientific and Technical Information of China (English)

    宋立国; 李树索; 郑运荣; 韩雅芳

    2004-01-01

    The effect of rare earth element yttrium on the high temperature oxidation resistance of a directionally solidified Ni-base superalloy was studied with scanning electron microscopy(SEM), energy dispersive spectrum(EDS)and X-ray diffraction(XRD)techniques. The results show that the oxidation resistance of the alloy is substantially improved by adding proper amount of yttrium.

  19. Design and characterization of novel precipitation hardenable high Cr Ni-based superalloys

    DEFF Research Database (Denmark)

    Bihlet, Uffe; Dahl, Kristian Vinter; Somers, Marcel A. J.

    2012-01-01

    Among the Ni-based superalloys, Alloy 718 stands apart with the ability to be precipitation hardened after welding, by the slow formation of nano-scale γ’’ (Ni3Nb) particles. This slow formation gives it a very low crack susceptibility, which has made it widely applied since its introduction...

  20. A study of microstructural characteristics of Ni-based superalloys at high temperatures

    Science.gov (United States)

    Lal, Ravindra B.; Aggarwal, M. D.

    1990-01-01

    The microstructural characteristics of the Ni-based superalloy MAR-M245(Hf) which is used in manufacturing the components of the Space Shuttle main engine are studied. These superalloys need optimum heat treatment to get the best results. To find out the optimum heat treatment, the techniques of differential thermal analysis (DTA) and the optical photomicrographs were utilized. In the first phase, the existing experimental equipment like cutting, grinding/polishing machines and metallurgical microscope were set up to cut/polish and take the photomicrographs. In the beginning of the project a Perkin Elmer differential thermal analyzer DTA1700 along with a temperature programmed and the needed computer interface was procured and made operational. In the second year a Leitz Metallux-3 hot state research microscope was also procured and installed for in-situ observation of the superalloy samples. The hot stage when tested for the first time alloyed the thermocouple with the Tantalum heating element and has now been installed. Samples of MAR-M246(Hf), MAR-M247, Waspaloy, Udimet-41, CMSX-3, and CMSX-3 (Polycrystalline and single crystals) were studied using a differential thermal analyzer and the results are reported. Photomicrographs of the Ni-based superalloy MAR-M246 (Hf) were recorded before and after heat treatment at certain temperatures. More heat treatments need to be done before a final inference can be reached.

  1. Investigation of nickel- and cobalt-based superalloys with protective coatings

    Science.gov (United States)

    Veksler, Yu. G.; Mal'tseva, L. A.; Pastukhov, M. V.

    2015-03-01

    The structure and composition of the surface layers of MAR-M247 and MAR-M509 superalloys are studied after the formation of protective coatings by gas-circulation aluminizing and a high-energy ion-plasma technology.

  2. Modeling cast IN-738 superalloy gas tungsten arc welds

    Energy Technology Data Exchange (ETDEWEB)

    Bonifaz, E.A. [Department of Mechanical and Manufacturing Engineering, University of Manitoba, E2-327F EITC, Winnipeg, Man., R3T 5V6 (Canada); Universidad San Francisco de Quito, Casilla Postal: 17-12-841 Circulo de Cumbaya, Quito (Ecuador)], E-mail: bonifaz@cc.umanitoba.ca; Richards, N.L. [Department of Mechanical and Manufacturing Engineering, University of Manitoba, E2-327F EITC, Winnipeg, Man., R3T 5V6 (Canada)], E-mail: nrichar@cc.umanitoba.ca

    2009-04-15

    A three-dimensional finite-element thermal model has been developed to generate weld profiles, and to analyze transient heat flow, thermal gradients and thermal cycles in cast IN-738 superalloy gas tungsten arc welds. Outputs of the model (cooling rates, the thermal gradient G and the growth rate R) were used to describe solidification structures found around the weld pool for three different welding speeds at constant heat input. Calculations around the weld pool indicate that the cooling rate increases from the fusion line to the centerline at all welding speeds. It was also observed that the cooling rate (G x R) and the ratio G/R fall with welding speed. For instance, as the welding speed is increased, the cooling rates at the centerline, fusion line and penetration depth decrease. Moreover, it was observed that as the power and welding speed both increase (but keeping the heat input constant), the weld pool becomes wider and more elongated, shifting from circular to elliptical shaped. The calculations were performed using ABAQUS FE code on the basis of a time-increment Lagrangian formulation. The heat source represented by a moving Gaussian power density distribution is applied over the top surface of the specimen during a period of time that depends on the welding speed. Temperature-dependent material properties and the effect of forced convection due to the flow of the shielding gas are included in the model. Numerically predicted sizes of the melt-pool zone and dendrite secondary arm spacing induced by the gas tungsten arc welding process are also given.

  3. Deformation modeling and constitutive modeling for anisotropic superalloys

    Science.gov (United States)

    Milligan, Walter W.; Antolovich, Stephen D.

    1989-01-01

    A study of deformation mechanisms in the single crystal superalloy PWA 1480 was conducted. Monotonic and cyclic tests were conducted from 20 to 1093 C. Both (001) and near-(123) crystals were tested, at strain rates of 0.5 and 50 percent/minute. The deformation behavior could be grouped into two temperature regimes: low temperatures, below 760 C; and high temperatures, above 820 to 950 C depending on the strain rate. At low temperatures, the mechanical behavior was very anisotropic. An orientation dependent CRSS, a tension-compression asymmetry, and anisotropic strain hardening were all observed. The material was deformed by planar octahedral slip. The anisotropic properties were correlated with the ease of cube cross-slip, as well as the number of active slip systems. At high temperatures, the material was isotropic, and deformed by homogeneous gamma by-pass. It was found that the temperature dependence of the formation of superlattice-intrinsic stacking faults was responsible for the local minimum in the CRSS of this alloy at 400 C. It was proposed that the cube cross-slip process must be reversible. This was used to explain the reversible tension-compression asymmetry, and was used to study models of cross-slip. As a result, the cross-slip model proposed by Paidar, Pope and Vitek was found to be consistent with the proposed slip reversibility. The results were related to anisotropic viscoplastic constitutive models. The model proposed by Walter and Jordan was found to be capable of modeling all aspects of the material anisotropy. Temperature and strain rate boundaries for the model were proposed, and guidelines for numerical experiments were proposed.

  4. Microstructural aspects of fatigue in Ni-base superalloys.

    Science.gov (United States)

    Antolovich, Stephen D

    2015-03-28

    Nickel-base superalloys are primarily used as components in jet engines and land-based turbines. While compositionally complex, they are microstructurally simple, consisting of small (50-1000 nm diameter), ordered, coherent Ni(3)(Al,Ti)-type L1(2) or Ni(3)Nb-type DO(22) precipitates (called γ(') and γ(''), respectively) embedded in an FCC substitutional solid solution consisting primarily of Ni and other elements which confer desired properties depending upon the application. The grain size may vary from as small as 2 μm for powder metallurgy alloys used in discs to single crystals the actual size of the component for turbine blades. The fatigue behaviour depends upon the microstructure, deformation mode, environment and cycle time. In many cases, it can be controlled or modified through small changes in composition which may dramatically change the mechanism of damage accumulation and the fatigue life. In this paper, the fundamental microstructural, compositional, environmental and deformation mode factors which affect fatigue behaviour are critically reviewed. Connections are made across a range of studies to provide more insight. Modern approaches are pointed out in which the wealth of available microstructural, deformation and damage information is used for computerized life prediction. The paper ends with a discussion of the very important and highly practical subject of thermo-mechanical fatigue (TMF). It is shown that physics-based modelling leads to significantly improved life prediction. Suggestions are made for moving forward on the critical subject of TMF life prediction in notched components. © 2015 The Author(s) Published by the Royal Society. All rights reserved.

  5. Fabrication and Optimization of Ni Superalloy Inconel 600 Microtruss Materials

    Science.gov (United States)

    Devatha Venkatesh, Balaji

    Microtruss materials are multifunctional cellular hybrids composed of an interconnected arrangement of internal struts that can offer enhanced strength and stiffness at low densities. This study looks at the potential of Ni-based superalloys as microtruss materials. The potential of using the in-situ plastic strain imparted during stretch forming to grain boundary engineer the internal struts of Inconel 600 (IN600) cellular hybrids was also explored. In order to examine this question, a combination of experimental and finite element (FE) methods were employed. The non-uniform plastic deformation imparted to the microtruss struts during fabrication was modeled by FE and the local changes in grain boundary character in the fabricated trusses were mapped by electron backscattered diffraction. This study also examined the distribution of plastic strain over the microtruss architecture. A mechanical press with various pin geometries was employed to experimentally validate the FE models. Standard pin geometry results in substantially non-uniform plastic strain, which limits the maximum formability of the starting sheet material. Importantly, pins designed with tapers and spheres were shown to impart plastic strain along the entire length of the microtruss. This opened up possibility of new design strategies for facilitating grain boundary engineering over the entire truss. It may also present opportunities for enhancing the energy absorption performance of microtruss materials. Finally, this study examined the mechanical properties of IN600 microtrusses, in particular focusing on the significance of strut end constraints in determining the overall mechanical performance. While it is straightforward to analytically determine the inelastic buckling resistance of plastically deformed struts, there is no simple way to determine the rotational end constraint of the struts deformed to varying truss angles. It was seen that end constraint rigidity k could be determined using a

  6. Thermomechanical fatigue crack growth in a cast polycrystalline superalloy

    Directory of Open Access Journals (Sweden)

    Moverare Johan J.

    2014-01-01

    Full Text Available Thermomechanical fatigue (TMF crack growth testing has been performed on the polycrystalline superalloy IN792. All tests were conducted in mechanical strain control in the temperature range between 100 and 750 °C. The influence of in-phase (IP and out-of-phase (OP TMF cycles was investigated as well as the influence of applying extended dwell times (up to 6 hours at the maximum temperature. The crack growth rates were also evaluated based on linear elastic fracture mechanics and described as a function of the stress intensity factor KI. Without dwell time at the maximum temperature, the crack growth rates are generally higher for the OP-TMF cycle compared to the IP-TMF cycle, when equivalent nominal strain ranges are compared. However, due to the fact that the tests were conducted in mechanical strain control, the stress response is very different for the IP and OP cycles. Also the crack closure level differs significantly between the cycle types. By taking the stress response into account and comparing the crack growth rates for equivalent effective stress intensity factor rages ΔKeff defined as Kmax − Kclosure, very similar crack growth rates were actually noticed independent of whether an IP or OP cycle were used. While the introduction of a 6 hour dwell time significantly increased the crack growth rates for the IP-TMF cycle, a decrease in crack growth rates versus ΔKeff were actually seen for the OP-TMF cycle. The fracture behaviour during the different test conditions has been investigated using scanning electron microscopy.

  7. Compositional Effects on Nickel-Base Superalloy Single Crystal Microstructures

    Science.gov (United States)

    MacKay, Rebecca A.; Gabb, Timothy P.; Garg,Anita; Rogers, Richard B.; Nathal, Michael V.

    2012-01-01

    Fourteen nickel-base superalloy single crystals containing 0 to 5 wt% chromium (Cr), 0 to 11 wt% cobalt (Co), 6 to 12 wt% molybdenum (Mo), 0 to 4 wt% rhenium (Re), and fixed amounts of aluminum (Al) and tantalum (Ta) were examined to determine the effect of bulk composition on basic microstructural parameters, including gamma' solvus, gamma' volume fraction, volume fraction of topologically close-packed (TCP) phases, phase chemistries, and gamma - gamma'. lattice mismatch. Regression models were developed to describe the influence of bulk alloy composition on the microstructural parameters and were compared to predictions by a commercially available software tool that used computational thermodynamics. Co produced the largest change in gamma' solvus over the wide compositional range used in this study, and Mo produced the largest effect on the gamma lattice parameter and the gamma - gamma' lattice mismatch over its compositional range, although Re had a very potent influence on all microstructural parameters investigated. Changing the Cr, Co, Mo, and Re contents in the bulk alloy had a significant impact on their concentrations in the gamma matrix and, to a smaller extent, in the gamma' phase. The gamma phase chemistries exhibited strong temperature dependencies that were influenced by the gamma and gamma' volume fractions. A computational thermodynamic modeling tool significantly underpredicted gamma' solvus temperatures and grossly overpredicted the amount of TCP phase at 982 C. Furthermore, the predictions by the software tool for the gamma - gamma' lattice mismatch were typically of the wrong sign and magnitude, but predictions could be improved if TCP formation was suspended within the software program. However, the statistical regression models provided excellent estimations of the microstructural parameters based on bulk alloy composition, thereby demonstrating their usefulness.

  8. Microstructural analysis of weld cracking in 718 Plus superalloy

    Science.gov (United States)

    Vishwakarma, Krutika

    Allvac 718RTM PLUS(TM) (718 Plus) is a new Ni-base superalloy developed to be used in land and aero gas turbine applications. 718 Plus was developed to have high temperature properties superior to its baseline superalloy Inconel 718, while maintaining its workability. Besides its high temperature properties superior to Inconel 718, limited information exists about its physical metallurgy or weldability. This project studied the microstructure and electron beam welding response of this new superalloy in two selected pre-weld heat treated conditions. To further understand the effect of minor alloying elements on its weldability, two versions of 718 Plus with varying concentrations of boron and phosphorus, HC 49 with higher B and P and HC 20 with normal B and P, were also studied. Finally, the weldability of 718 Plus alloys was compared to that of Inconel 718 and Waspaloy under similar welding conditions. Hot rolled wrought plates of Inconel 718, Waspaloy and 718 Plus alloys were supplied by ALLVAC Inc. 12.7 mm x 12.7 mm x 101.6 mm sections were cut normal to the rolling direction of the plates and were subjected to their recommended respective solution heat treatments, viz., 950°C for 1 hour for 718 Plus alloys and Inconel 718 and 1020°C for 1 hour for Waspaloy. 718 Plus alloys and Inconel 718 were also examined after another solution heat treatment at 1050°C for 1 hour. All the heat treatments were followed by water quenching. Thorough microstructural characterization before and after welding was carried out using optical microscopy, analytical scanning electron microscopy, electron microprobe analysis and analytical transmission electron microscopy. In addition, Secondary Ion Mass Spectrometer (SIMS) was used to study the grain boundary segregation in the two 718 Plus alloys. Interestingly, the microstructure of 718 Plus alloy, in the heat treated conditions it was studied, was very similar to that of Inconel 718 despite of the considerable difference in their

  9. Development of advanced P/M Ni-base superalloys for turbine disks

    Directory of Open Access Journals (Sweden)

    Garibov Genrikh S.

    2014-01-01

    Full Text Available In the process of evolution of powder metallurgy in Russia the task permanently formulated was the following: to improve strength properties of P/M superalloys without application of additional complex HIPed blanks deformation operation. On the other hand development of a turbine disk material structure to ensure an improvement in aircraft engine performance requires the use of special HIP and heat treatment conditions. To ensure maximum strength properties of disk materials it is necessary to form a structure which would have optimum size of solid solution grains, γ′-phases and carbides. Along with that heating of the material up to a temperature determined by solvus of an alloy ensures a stable and reproducible level of mechanical properties of the disks. The above-said can be illustrated by successful mastering of new complex-alloyed VVP-class superalloys with the use of powder size − 100 μm. Application of special HIP and heat treatment conditions for these superalloys to obtain the desired grain size and the strengthening γ′-phase precipitates allowed a noticeable improvement in ultimate tensile strength and yield strength up to ≥1600 MPa and ≥1200 MPa respectively. 100 hrs rupture strength at 650 ∘C and 750 ∘C was improved up to 1140 MPa and 750 MPa respectively. P/M VVP nickel-base superalloys offer higher characteristics in comparison with many superalloys designed for the same purposes. HIPed disc compacts manufactured from PREP-powder have a homogeneous micro- and macrostructure, a stable level of mechanical properties.

  10. Solid solution strengthening and diffusion in nickel- and cobalt-based superalloys

    Energy Technology Data Exchange (ETDEWEB)

    Rehman, Hamad ur

    2016-07-01

    Nickel and cobalt-based superalloys with a γ-γ{sup '} microstructure are known for their excellent creep resistance at high temperatures. Their microstructure is engineered using different alloying elements, that partition either to the fcc γ matrix or to the ordered γ{sup '} phase. In the present work the effect of alloying elements on their segregation behaviour in nickel-based superalloys, diffusion in cobalt-based superalloys and the temperature dependent solid solution strengthening in nickel-based alloys is investigated. The effect of dendritic segregation on the local mechanical properties of individual phases in the as-cast, heat treated and creep deformed state of a nickel-based superalloy is investigated. The local chemical composition is characterized using Electron Probe Micro Analysis and then correlated with the mechanical properties of individual phases using nanoindentation. Furthermore, the temperature dependant solid solution hardening contribution of Ta, W and Re towards fcc nickel is studied. The room temperature hardening is determined by a diffusion couple approach using nanoindentation and energy dispersive X-ray analysis for relating hardness to the chemical composition. The high temperature properties are determined using compression strain rate jump tests. The results show that at lower temperatures, the solute size is prevalent and the elements with the largest size difference with nickel, induce the greatest hardening consistent with a classical solid solution strengthening theory. At higher temperatures, the solutes interact with the dislocations such that the slowest diffusing solute poses maximal resistance to dislocation glide and climb. Lastly, the diffusion of different technically relevant solutes in fcc cobalt is investigated using diffusion couples. The results show that the large atoms diffuse faster in cobalt-based superalloys similar to their nickel-based counterparts.

  11. Characterization and Modeling of Residual Stress and Cold Work Evolution in PM Nickel Base Disk Superalloy Project

    Data.gov (United States)

    National Aeronautics and Space Administration — Powder metal (PM) superalloys used for critical compressor and turbine disk applications are prone to fatigue failures in stress concentration features such as holes...

  12. Structure and composition of higher-rhenium-content superalloy based on La-alloyed Ni-Al-Cr

    Energy Technology Data Exchange (ETDEWEB)

    Kozlov, Eduard V.; Koneva, Nina A. [Tomsk State University of Architecture and Building, Tomsk, 634003 (Russian Federation); Nikonenko, Elena L., E-mail: vilatomsk@mail.ru [Tomsk State University of Architecture and Building, Tomsk, 634003 (Russian Federation); National Research Tomsk Polytechnic University, Tomsk, 634050 (Russian Federation); Popova, Natalya A.; Fedorischeva, Marina V. [Tomsk State University of Architecture and Building, Tomsk, 634003 (Russian Federation); Institute of Strength Physics and Materials Science SB RAS, Tomsk, 634055 (Russian Federation)

    2015-10-27

    The paper presents the transmission and scanning electronic microscope investigations of Ni-Al-Cr superalloy alloyed with additional Re and La elements. This superalloy is obtained by a directional solidification method. It is shown that such additional elements as Re and La result in formation of new phases in Ni-Al-Cr accompanied by considerable modifications of quasi-cuboid structure in its γ’-phase.

  13. Lecture Notes and Guidance for Course 21220 (Non-aqueous Inorganic Chemistry)

    DEFF Research Database (Denmark)

    1998-01-01

    The lecture notes contain the theoretical as well as the practical background material necessary for mastering the special laboratory techniques used in non-aqueous inorganic chemistry (cfr. Course Descriptions, DTU).......The lecture notes contain the theoretical as well as the practical background material necessary for mastering the special laboratory techniques used in non-aqueous inorganic chemistry (cfr. Course Descriptions, DTU)....

  14. Lecture Notes and Guidance for Course 21220 (Non-aqueous Inorganic Chemistry)

    DEFF Research Database (Denmark)

    1998-01-01

    The lecture notes contain the theoretical as well as the practical background material necessary for mastering the special laboratory techniques used in non-aqueous inorganic chemistry (cfr. Course Descriptions, DTU).......The lecture notes contain the theoretical as well as the practical background material necessary for mastering the special laboratory techniques used in non-aqueous inorganic chemistry (cfr. Course Descriptions, DTU)....

  15. Design of Ni-base superalloys and MCrAlY coatings from first-principles and computational thermodynamics

    Science.gov (United States)

    Liu, Xuan

    This thesis explores the thermodynamics of Ni-base superalloys and metallic coatings used in the protection of these alloys. First, a thermodynamic description of the Nb-Re binary system is developed by means of the CALculation of PHAse Diagrams (CALPHAD) method supplemented by first-principles calculations based on density functional theory (DFT) and experimental data in the literature. In addition to terminal solution phases in the Nb-Re system, there are two intermetallic phases, sigma (sigma) and chi (chi), all modeled with sublattice models. Special quasi-random structures (SQS) are employed to mimic the random mixing of the bcc, hcp, and fcc solid solution phases from first-principles. Finite temperature thermodynamic properties of end-members and dilute mixing in each sublattice of the complex sigma and chi phases are predicted from first-principles calculations and the Debye-Gruneisen model. The utility of the Debye-Gruneisen model is then investigated with respect to its fitting parameter known as the scaling factor, and it is found that the prediction of finite-temperature properties can be improved by modification of this factor. This scaling factor is studied using bcc, fcc, hcp systems and the Mg-Zn binary system due to the abundance of thermodynamic data. Predicted Debye temperatures (thetaD), using a calculated scaling factor, show good agreement with experiments and improvements over the scaling factor derived by Moruzzi et al. Finite-temperature thermodynamic properties of intermetallics are investigated to show the efficiency and improved accuracy of the calculated scaling factor. However, for the intermetallic Mg2Zn11, the Debye-Gruneisen model cannot account for anomalous lattice dynamics at low temperatures. The calculated scaling factor is then used throughout the present work for finite-temperature predictions. Another missing piece of the literature includes the thermodynamics of Al-Co-Cr-Ni bond coat system used in the protection of

  16. Cyclic Oxidation of High Mo, Reduced Density Superalloys

    Directory of Open Access Journals (Sweden)

    James L. Smialek

    2015-11-01

    Full Text Available Cyclic oxidation was characterized as part of a statistically designed, 12-alloy compositional study of 2nd generation single crystal superalloys as part of a broader study to co-optimize density, creep strength, and cyclic oxidation. The primary modification was a replacement of 5 wt. % W by 7% or 12% Mo for density reductions of 2%–7%. Compositions at two levels of Mo, Cr, Co, and Re were produced, along with a midpoint composition. Initially, polycrystalline vacuum induction samples were screened in 1100 °C cyclic furnace tests using 1 h cycles for 200 h. The behavior was primarily delimited by Cr content, producing final weight changes of −40 mg/cm2 to −10 mg/cm2 for 0% Cr alloys and −2 mg/cm2 to +1 mg/cm2 for 5% Cr alloys. Accordingly, a multiple linear regression fit yielded an equation showing a strong positive Cr effect and lesser negative effects of Co and Mo. The results for 5% Cr alloys compare well to −1 mg/cm2, and +0.5 mg/cm2 for Rene′ N4 and Rene′ N5 (or Rene′ N6, respectively. Scale phases commonly identified were Al2O3, NiAl2O4, NiTa2O6, and NiO, with (Ni,CoMoO4 found only on the least resistant alloys having 0% Cr and 12% Mo. Scale microstructures were complex and reflected variations in the regional spallation history. Large faceted NiO grains and fine NiTa2O6 particles distributed along NiAl2O4 grain boundaries were typical distinctive features. NiMoO4 formation, decomposition, and volatility occurred for a few high Mo compositions. A creep, density, phase stability, and oxidation balanced 5% Cr, 10% Co, 7% Mo, and 3% Re alloy was selected to be taken forward for more extensive evaluations in single crystal form.

  17. Design of a biomimetic self-healing superalloy composite

    Science.gov (United States)

    Files, Bradley Steven

    1997-10-01

    Use of systems engineering concepts to design technologically advanced materials has allowed ambitious goals of self-healing alloys to be realized. Shape memory alloy reinforcements are embedded in an alloy matrix to demonstrate concepts of stable crack growth and matrix crack closure. Computer methods are used to design thermodynamically compatible iron-based alloys using bio-inspired concepts of crack bridging and self-healing. Feasibility of crack closure and stable crack growth is shown in a prototype system with a Sn-Bi matrix and TiNi fibers. Design of Fe-Ni-Co-Ti-Al alloys using thermodynamic models to determine stabilities and phase equilibria allows for a methodical system designing compatible multicomponent alloys for composite systems. Final alloy computations for this project led to the alloy Fe-27.6Ni-18.2Co-4.1Ti-1.6Al as a compatible shape memory a with a 650sp°C 90 minute heat treatment leading to martensite and austenite start temperatures (Msbs and Asbs) near room temperature. Thin slices of this alloy were able to fully recover at least 5% strain upon unloading heating. Composites made from the designed shape memory alloy and a compatible Fe-based B2 matrix were used to test self-healing concepts in the superalloy system. Diffusion couple experiments verified thermodynamic compatibility between matrix and reinforcement alloys at the solution treatment temperature of 1100sp°C. Concepts of stable crack growth and crack bridging were demonstrated in the composite, leading to enhanced toughness of the brittle matrix. However, healing behavior in this system was limited by intergranular fracture of the reinforcement alloy. It is believed that use of rapidly solidified powders could eliminate intergranular fracture, leading to greatly enhanced properties of toughening and healing. Crack clamping and stable crack growth were achieved in a feasibility study using a Sn-Bi matrix reinforced with TiNi fibers. Tensile specimens with less than 1% fibers

  18. Writing a Condolence Note

    Science.gov (United States)

    ... notes provide us with ways to convey our love and friendship to others at times when they have the greatest need for what we have to offer. When such times arise, give it your best. Share this: Twitter Facebook Google Search for: Choosing a Hospice: 16 Questions ...

  19. Obituaries and biographical notes

    NARCIS (Netherlands)

    NN,

    1967-01-01

    Baehni, Ch. (1906-1964) R. Weibel, l’Oeuvre scientifique de Charles Baehni. Trav. Soc. Bot. Genève 8 (1966) 18-21. — Obituary and concise bibliography. Banks & Solander E.W. Groves, Notes on the botanical specimens collected by Banks and Solander on Cook’s first voyage, together with an itinerary of

  20. Notes on Linguistics, 1990.

    Science.gov (United States)

    Notes on Linguistics, 1990

    1990-01-01

    This document consists of the four issues of "Notes on Linguistics" published during 1990. Articles in the four issues include: "The Indians Do Say Ugh-Ugh" (Howard W. Law); "Constraints of Relevance, A Key to Particle Typology" (Regina Blass); "Whatever Happened to Me? (An Objective Case Study)" (Aretta…

  1. Nursing Students' Perceptions of Anecdotal Notes as Formative Feedback.

    Science.gov (United States)

    Quance, Margaret Ann

    2016-08-24

    Anecdotal notes are a method of providing formative feedback to nursing students following clinical experiences. The extant literature on anecdotal notes is written only from the educator perspective, focusing on rationale for and methods of production, rather than on evaluation of effectiveness. A retrospective descriptive study was carried out with a cohort of 283 third year baccalaureate nursing students to explore their perceptions of anecdotal notes as effective formative feedback. The majority of students valued verbal as well as anecdotal note feedback. They preferred to receive feedback before the next learning experience. Students found the quality of feedback varied by instructor. The anecdotal note process was found to meet identified formative feedback requirements as well as the nursing program's requirement for transparency of evaluation and due process. It is necessary to provide professional development to clinical nurse educators to assist them develop high quality formative feedback using anecdotal notes.

  2. Denmark country note 2016

    DEFF Research Database (Denmark)

    Bloksgaard, Lotte; Rostgaard, Tine

    2016-01-01

    policy. As well as policies, it provides information on publications and research. The review is based on country notes from each participating country. Each country note follows a standard format: details of different types of leave; the relationship between leave policy and early childhood education...... and care policy; recent policy developments; information on take-up of leave; recent publications and current research projects. The review also includes definitions of the main types of leave policies; and cross-country comparisons. These comparative overviews cover: each main type of leave; total leave...... available; the relationship between leave and ECEC entitlements; policy changes and developments since the previous review; publications since the previous review; and ongoing research in participating countries. The 2016 review includes one new country: Korea. Altogether, it covers 39 countries...

  3. Denmark country note

    DEFF Research Database (Denmark)

    Bloksgaard, Lotte; Rostgaard, Tine

    2014-01-01

    parents; and early childhood education and care policy. As well as policies, it provides information on publications and research. The review is based on country notes from each participating country. Each country note follows a standard format: details of different types of leave; the relationship...... between leave policy and early childhood education and care policy; recent policy developments; information on take-up of leave; recent publications and current research projects. The review also includes definitions of the main types of leave policies; and cross-country comparisons. These comparative...... overviews cover: each main type of leave; total leave available; the relationship between leave and ECEC entitlements; policy changes and developments since the previous review; publications since the previous review; and ongoing research in participating countries. The 2014 review includes one new country...

  4. Thermophysical and structural study of IN 792-5A nickel based superalloy

    Directory of Open Access Journals (Sweden)

    S. Zlá

    2012-01-01

    Full Text Available The presented paper deals with study of phase transformations temperatures of nickel based superalloy IN 792-5A with application of DTA – method and use of experimental laboratory system for simultaneous thermal analysis SETARAM Setsys 18TM. Samples taken from as-received state of superalloy were heated with controlled ramp rates (1, 5, 10 and 20 °C•min-1 and immediately after melting they were cooled with the same controlled ramp rate. The samples before and after DTA-analysis were also subjected to the phase analysis with use of scanning electron microscopy on the microprobe (JCXA 733 equipped with energy dispersive analyser EDAX (EDAM 3.

  5. Rafting in single crystal nickel-base superalloys — An overview

    Indian Academy of Sciences (India)

    M Kamaraj

    2003-02-01

    Currently nickel-base single crystal (SX) superalloys are considered for the manufacture of critical components such as turbine blades, vanes etc., for aircraft engines as well as land-based power generation applications. Microstructure and high temperature mechanical properties are the major factors controlling the performance of SX superalloys. Rafting is an important phenomenon in these alloys which occurs during high temperature creep. It is essential to understand the rafting mechanism, and its characteristics on high temperature properties before considering the advanced applications. In this review article, the thermodynamic driving force for rafting with and without stress is explained. The nature and influence of rafting on creep properties including pre-rafted conditions are discussed. In addition, the effect of stress state on $\\gamma /\\gamma'$ rafting, kinetics and morphological evolution are discussed with the recent experimental results.

  6. QUANTITATIVE METALOGRAPHY OF HEAT TREATED ŽS6K SUPERALLOY

    Directory of Open Access Journals (Sweden)

    Juraj Belan

    2012-02-01

    Full Text Available Alloy ŽS6K is former USSR superalloy used in DV – 2 jet engine. It is used for turbine rotor blade and whole cast small sized rotors with working temperature up to 800 ÷ 1050°C. This alloy was evaluated after annealing at 800 °C/ 10 and followed by cooling with various rate, presented with cooling in water, oil and air. Cooling rates, represented by various cooling mediums, have a significant influence on diffusion processes, which are going in structure. Methods of quantitative metallography (Image Analyzer software NIS – Elements for carbides evaluation, measuring of secondary dendrite arm spacing and coherent testing grid for gama' - phase evaluation are used for evaluation of structural characteristics on experimental material – Ni base superalloy ŽS6K.

  7. QUANTITATIVE METALOGRAPHY OF HEAT TREATED ŽS6K SUPERALLOY

    Directory of Open Access Journals (Sweden)

    Juraj Belan

    2011-09-01

    Full Text Available Alloy ŽS6K is former USSR superalloy used in DV – 2 jet engine. It is used for turbine rotor blade and whole cast small sized rotors with working temperature up to 800 ÷ 1050°C. This alloy was evaluated after annealing at 800 °C/ 10 and followed by cooling with various rate, presented with cooling in water, oil and air. Cooling rates, represented by various cooling mediums, have a significant influence on diffusion processes, which are going in structure. Methods of quantitative metallography (Image Analyzer software NIS – Elements for carbides evaluation, measuring of secondary dendrite arm spacing and coherent testing grid for gama' - phase evaluation are used for evaluation of structural characteristics on experimental material – Ni base superalloy ŽS6K.

  8. Oxidation Resistance: One Barrier to Moving Beyond Ni-Base Superalloys

    Energy Technology Data Exchange (ETDEWEB)

    Pint, Bruce A [ORNL; Distefano, James R [ORNL; Wright, Ian G [ORNL

    2006-01-01

    The implementation of new high-temperature materials is often hampered by their lack of oxidation or environmental resistance. This failing is one of the strongest barriers to moving beyond Ni-base superalloys for many commercial applications. In practice, usable high-temperature alloys have at least reasonable oxidation resistance, but the current generation of single-crystal Ni-base superalloys has sufficient oxidation resistance that optimized versions can be used without a metallic bond coating and only an oxygen-transparent ceramic coating for thermal protection. The material development process often centers around mechanical properties, while oxidation resistance, along with other realities, is given minor attention. For many applications, the assumption that an oxidation-resistant coating can be used to protect a substrate is seriously flawed, as coatings often do not provide sufficient reliability for critical components. Examples of oxidation problems are given for currently used materials and materials classes with critical oxidation resistance problems.

  9. Effect of boron addition on the microstructure and stress-rupture properties of directionally solidified superalloys

    Institute of Scientific and Technical Information of China (English)

    Bao-ping Wu; Lin-han Li; Jian-tao Wu; Zhen Wang; Yan-bin Wang; Xing-fu Chen; Jian-xin Dong; Jun-tao Li

    2014-01-01

    This study is focused on the effect of boron addition, in the range of 0.0007wt% to 0.03wt%, on the microstructure and stress-rupture properties of a directionally solidified superalloy. With increasing boron content in the as-cast alloys, there is an increase in the fraction of theγ′/γ eutectic and block borides precipitate around theγ′/γ eutectic. At a high boron content of 0.03wt%, there is precipitation of lamellar borides. Upon heat treatment, fine block borides tend to precipitate at grain boundaries with increasing boron content. Overall, the rupture life of the directionally solidified superalloy is significantly improved with the addition of nominal content of boron. However, the rupture life decreases when the boron content exceeds 0.03wt%.

  10. Calorimetric examination of mixtures for modification of nickel and cobalt superalloys

    Directory of Open Access Journals (Sweden)

    F. Binczyk

    2009-04-01

    Full Text Available The study presents the results of thermodynamic calculations and calorimetric examination of thermal reactions taking place at hightemperatures between the nanoparticle inoculants and metallic constituents of nickel and cobalt superalloys. The calculations andmeasurements were made for different compositions, containing cobalt aluminate CoAl2O4, cobalt oxide CoO*Co2O3, zircon flourZrSi2O4, powdered and metallic Al, powdered Ti, and IN-713C alloy. The obtained results have indicated the possibility of using certainmixtures as potential inoculating additives for the volume modification of nickel and cobalt superalloys. A characteristic feature of these alloys is the formation of a detrimental structure containing very large columnar crystal, present even in castings of a very high solidification rate. It has been proved that the inoculant most effective in the formation of the structure of equiaxial grains is the inoculant based on cobalt aluminate, colloidal silica and powdered aluminium.

  11. STUDY OF THE MECHANICAL PROPERTIES OF INCONEL 718 SUPERALLOY AFTER HOT TENSILE TESTS

    Directory of Open Access Journals (Sweden)

    Tarcila Sugahara

    2014-10-01

    Full Text Available This research work investigated some important mechanical properties of Inconel 718 superalloy using hot tensile tests like conventional yield strength to 0.2% strain (σe , ultimate strength (σr , and specific elongation (εu . Samples were strained to failure at temperatures of 600°C, 650°C, 700°C, 750°C, 800°C and 850°C and strain rate of 0.5 mm/min (2 × 10–4 s–1 according to ASTM E-8. The results showed higher values σe of yield strength at 700°C, this anomalous behavior can be attributed to the presence of hardening precipitates as observed in the TTT diagram of superalloy Inconel 718. Examination of the sample’s surfaces tensile fracture showed that with increasing temperature test the actuating mechanism changes from intergranular fracture to coalescence of the microcavities.

  12. Processing and Microstructural Evolution of Superalloy Inconel 718 during Hot Tube Extrusion

    Institute of Scientific and Technical Information of China (English)

    Shihong ZHANG; Zhongtang WANG; Bing QIAO; Yi XU; Tingfeng XU

    2005-01-01

    The processing parameters of tube extrusion for superalloy Inconel 718 (IN 718), such as slug temperature, tools temperature, choice of lubricant, extrusion ratio and extrusion speed, were determined by experiment in this paper. An appropriate temperature range recommended for the slug is 1080~1120℃, and the temperature range recommended for the tools is 350~500℃. The microstructural evolution of superalloy IN 718 during tube extrusion was analyzed.With the increase of the deformation the cross crystal grains were slightly refined. While the vertical crystal grain is elongated evidently and the tensile strength increased along the axial rake. Glass lubricants have to be spread on the slug surface after being heated to 150~200℃, vegetable oil or animal oil can be used as the lubricant on the surface of the tools to reduce the extrusion force remarkably.

  13. Cyclic Oxidation and Hot Corrosion of NiCrY-Coated Disk Superalloys

    Science.gov (United States)

    Gabb, Timothy P.; Miller, Robert A.; Sudbrack, Chantal K.; Draper, Susan L.; Nesbitt, James A.; Rogers, Richard B.; Telesman, Ignacy; Ngo, Vanda; Healy, Jonathan

    2016-01-01

    Powder metallurgy disk superalloys have been designed for higher engine operating temperatures through improvement of their strength and creep resistance. Yet, increasing disk application temperatures to 704 degrees Centigrade and higher could enhance oxidation and activate hot corrosion in harmful environments. Protective coatings could be necessary to mitigate such attack. Cylindrical coated specimens of disk superalloys LSHR and ME3 were subjected to thermal cycling to produce cyclic oxidation in air at a maximum temperature of 760 degrees Centigrade. The effects of substrate roughness and coating thickness on coating integrity after cyclic oxidation were considered. Selected coated samples that had cyclic oxidation were then subjected to accelerated hot corrosion tests. This cyclic oxidation did not impair the coating's resistance to subsequent hot corrosion pitting attack.

  14. XPS surface analysis of chemical and ion nitred Ni-base superalloys

    Energy Technology Data Exchange (ETDEWEB)

    Cappelli, E.; Nistico' , N.; Giunta, G.; Musicanti, M.; Bovaro, A.; Visconti, A. (Eniricerche, Monterotondo (Italy) Soliveri SpA, Caravaggio (Italy) Vacuum SpA, Trezzano S.N. (Italy))

    This paper reports on an investigation of the possibility of inducing surface modifications in a nickel base superalloy through different nitride treatment methods analogous to conventional hardening processes for steels. The aim was to confer, to the external surface of the superalloy, chemical and mechanical characteristics such as to make possible the nucleation and growth of a follow-up layer of a ceramic material (chemical vapour deposited TiN). The idea was to obtain good materials adhesion characterized by optimum properties - elastic modulus, thermal expansion, crystal structure, morphology, etc. The treatments led to significant increases in surface hardness and positively influenced both the nucleation process and TiN growth, as well as, substrate and coating adhesion. Results of x-ray photoelectron spectroscopy, XPS, of the surface and internal layers, together with microstructural examinations (SEM- EDX, XRD), evidenced the presence of nitrogen and the formation of nitrides (CrN and TiN) responsible for the induced modifications.

  15. Retention of Compressive Residual Stresses Introduced by Shot Peening in a Powder Metal Disk Superalloy

    Science.gov (United States)

    Gabb, Timothy P.; Danetti, Andrew; Draper, Susan L.; Locci, Ivan E.; Telesman, Jack

    2016-01-01

    The fatigue lives of disk superalloys can be increased by shot peening their surfaces, to induce compressive residual stresses near the surface that impede cracking there. As disk application temperatures increase for improved efficiency, the persistence of these beneficial stresses could be impaired, especially with continued fatigue cycling. The objective of this work was to study the retention of residual stresses introduced by shot peening, when subjected to fatigue and high temperatures. Fatigue specimens of powder metallurgy processed nickel-base disk superalloy ME3 were prepared with consistent processing and heat treatment. They were then shot peened using varied conditions. Strain-controlled fatigue cycles were run at room temperature and 704 C, to allow re-assessment of residual stresses.

  16. Fabrication of directional solidification components of nickel-base superalloys by laser metal forming

    Institute of Scientific and Technical Information of China (English)

    Liping Feng; Weidong Huang; Darong Chen; Xin Lin; Haiou Yang

    2004-01-01

    Straight plates, hollow columns, ear-like blade tips, twist plates with directional solidification microstructure made of Rene 95 superalloys were successfully fabricated on Nickel-base superalloy and DD3 substrates, respectively. The processing conditions for production of the parts with corresponding shapes were obtained. The fabrication precision was high and the components were compact. The solidification microstructure of the parts was analyzed by optical microscopy. The results show that the solidification microstructure is composed of columnar dendrites, by epitaxial growth onto the directional solidification substrates. The crystallography orientation of the parts was parallel to that of the substrates. The primary arm spacing was about 10 μm, which is in the range of superfine dendrites, and the secondary arm was small or even degenerated. It is concluded that the laser metal forming technique provides a method to manufacture directional solidification components.

  17. Microstructure-property relationships in directionally solidified single-crystal nickel-base superalloys

    Science.gov (United States)

    Mackay, Rebecca A.; Nathal, Michael V.

    1988-01-01

    This paper discusses some of the microstructural features which influence the creep properties of directionally solidified and single-crystal nickel-base superalloys. Gamma prime precipitate size and morphology, gamma-gamma (prime) lattice mismatch, phase instability, alloy composition, and processing variations are among the factors considered. Recent experimental results are reviewed and related to the operative deformation mechanisms and to the corresponding mechanical properties. Special emphasis is placed on the creep behavior of single-crystal superalloys at high temperatures, where directional gamma (prime) coarsening is prominent, and at lower temperatures, where gamma (prime) coarsening rates are significantly reduced. It can be seen that very subtle changes in microstructural features can have profound effects on the subsequent properties of these materials.

  18. Grain Boundary Engineering the Mechanical Properties of Allvac 718Plus(Trademark) Superalloy

    Science.gov (United States)

    Gabb, Timothy P.; Telesman, Jack; Garg, Anita; Lin, Peter; Provenzano, virgil; Heard, Robert; Miller, Herbert M.

    2010-01-01

    Grain Boundary Engineering can enhance the population of structurally-ordered "low S" Coincidence Site Lattice (CSL) grain boundaries in the microstructure. In some alloys, these "special" grain boundaries have been reported to improve overall resistance to corrosion, oxidation, and creep resistance. Such improvements could be quite beneficial for superalloys, especially in conditions which encourage damage and cracking at grain boundaries. Therefore, the effects of GBE processing on high-temperature mechanical properties of the cast and wrought superalloy Allvac 718Plus (Allvac ATI) were screened. Bar sections were subjected to varied GBE processing, and then consistently heat treated, machined, and tested at 650 C. Creep, tensile stress relaxation, and dwell fatigue crack growth tests were performed. The influences of GBE processing on microstructure, mechanical properties, and associated failure modes are discussed.

  19. Microstructure of the Nickel-Base Superalloy CMSX-4 Fabricated by Selective Electron Beam Melting

    Science.gov (United States)

    Ramsperger, Markus; Singer, Robert F.; Körner, Carolin

    2016-03-01

    Powder bed-based additive manufacturing (AM) processes are characterized by very high-temperature gradients and solidification rates. These conditions lead to microstructures orders of magnitude smaller than in conventional casting processes. Especially in the field of high performance alloys, like nickel-base superalloys, this opens new opportunities for homogenization and alloy development. Nevertheless, the high susceptibility to cracking of precipitation-hardenable superalloys is a challenge for AM. In this study, electron beam-based AM is used to fabricate samples from gas-atomized pre-alloyed CMSX-4 powder. The influence of the processing strategy on crack formation is investigated. The samples are characterized by optical and SEM microscopy and analyzed by microprobe analysis. Differential scanning calorimetry is used to demonstrate the effect of the fine microstructure on characteristic temperatures. In addition, in situ heat treatment effects are investigated.

  20. Optimizing the heat treatment of Ni-based superalloy turbine discs

    Science.gov (United States)

    Furrer, D. U.; Shankar, R.; White, C.

    2003-03-01

    The heat-treatment processes for nickel-based superalloys continue to change due to the development of new alloys, new requirements, and subsequent new manufacturing facilities. Nickel-based superalloys are continuing to evolve to meet emerging applications, while new alloys are also being introduced for advanced applications. These new materials are also being optimized for numerous mechanical and physical properties, making the selection of heat-treatment parameters increasingly challenging. New processing facilities and methods are also being implemented to allow tailoring of heat-treating parameters to meet these new challenges. For example, the Ladish SuperCooler technology allows engineering and control of all aspects of the heat-treatment process for nickel-based components, resulting in never-before possible disc properties.

  1. High Temperature Spin Testing of a Superalloy Disk With a Dual Grain Structure

    Science.gov (United States)

    Gayda, John; Kantzos, Pete

    2002-01-01

    Comparative spin tests were run on superalloy disks at an elevated temperature to determine the benefits of a DMHT disk, with a fine grain bore and coarse grain rim, versus a traditional subsolvus disk with a fine grain structure in the bore and rim. The results of these tests showed that the DMHT disk exhibited significantly lower growth at 1500 F. Further, the results of these tests could be accurately predicted using a 2D viscoelastic finite element analysis. These results indicate DMHT technology can be used to extend disk operating temperatures when compared to traditional subsolvus heat treatment options for superalloy disks. However, additional research is required to ensure the safe operation of a DMHT disk under more realistic engine operating conditions. This includes testing to determine the burst margin and cyclic capability of DMHT disks in a spin pit, at a minimum, and ultimately running an engine test with a DMHT disk.

  2. Development of superalloys for 1700 C ultra-efficient gas turbines

    Energy Technology Data Exchange (ETDEWEB)

    Harada, Hiroshi [National Institute for Materials Science, Tsukuba, Ibaraki (Japan). High Temperature Materials Center

    2010-07-01

    Mitigation of global warming is one of the most outstanding issues for the humankind. The Japanese government announced that it will reduce its greenhouse gas emissions by 25% from the 1990 level by 2020 as a medium-term goal. One of the promising approaches to achieving this is to improve the efficiency of thermal power plants emitting one-third of total CO{sub 2} gas in Japan. The key to improving the thermal efficiency is high temperature materials with excellent temperature capabilities allowing higher inlet gas temperatures. In this context, new single crystal superalloys for turbine blades and vanes, new coatings and turbine disk superalloys have been successfully developed for various gas turbine applications, typically 1700 C ultra-efficient gas turbines for next generation combine cycle power plants. (orig.)

  3. DENDRITE REFINING AND EUTECTIC TRANSFORMATION BEHAVIOR OF NICKEL-BASE SINGLE CRYSTAL (NBSC) SUPERALLOY

    Institute of Scientific and Technical Information of China (English)

    1998-01-01

    Because of the low temperature gradient and growth rate, the microstructure of the conventional single crystal superalloy made by HRS processing is coarse dendrite with well developed sidebranches and has serious segregation. With the help of the high temperature gradient directional solidification equipment (HGDS), the solidification cooling rate is greatly increased. Study on microstructure of the Ni-base single crystal superalloy solidified at much higher cooling rate shows that the dendrite arm spacing is highly refined, of which the primary dendrite arm spacing can be made to be 38μm, just as 1/10 as that by conventional HRS processing. With the increase of the cooling rate, the amount of the eutectic increases and then decreases. In the superfine columnar dendrite, the amount of γ/γ′eutectic is much fewer and its size is very small. This is useful to homogenize the microsegregation and improve the property of the material.

  4. Cyclic Oxidation and Hot Corrosion of NiCrY-Coated Disk Superalloy

    Science.gov (United States)

    Gabb, Tim; Miller, R. A.; Sudbrack, C. K.; Draper, S. L.; Nesbitt, J.; Telesman, J.; Ngo, V.; Healy, J.

    2015-01-01

    Powder metallurgy disk superalloys have been designed for higher engine operating temperatures through improvement of their strength and creep resistance. Yet, increasing disk application temperatures to 704 C and higher could enhance oxidation and activate hot corrosion in harmful environments. Protective coatings could be necessary to mitigate such attack. Cylindrical coated specimens of disk superalloys LSHR and ME3 were subjected to thermal cycling to produce cyclic oxidation in air at a maximum temperature of 760 C. The effects of substrate roughness and coating thickness on coating integrity after cyclic oxidation were considered. Selected coated samples that had cyclic oxidation were then subjected to accelerated hot corrosion tests. The effects of this cyclic oxidation on resistance to subsequent hot corrosion attack were examined.

  5. A study of microstructural characteristics and differential thermal analysis of Ni-based superalloys

    Science.gov (United States)

    Aggarwal, M. D.; Lal, R. B.; Oyekenu, Samuel A.; Parr, Richard; Gentz, Stephen

    1989-01-01

    The objective of this work is to correlate the mechanical properties of the Ni-based superalloy MAR M246(Hf) used in the Space Shuttle Main Engine with its structural characteristics by systematic study of optical photomicrographs and differential thermal analysis. The authors developed a method of predicting the liquidus and solidus temperature of various nickel based superalloys (MAR-M247, Waspaloy, Udimet-41, polycrystalline and single crystals of CMSX-2 and CMSX-3) and comparing the predictions with the experimental differential thermal analysis (DTA) curves using Perkin-Elmer DTA 1700. The method of predicting these temperatures is based on the additive effect of the components dissolved in nickel. The results were compared with the experimental values.

  6. Susceptibility to Hot Cracking and Weldment Heat Treatment of Haynes 230 Superalloy

    Institute of Scientific and Technical Information of China (English)

    C.M.Cheng; C.P.Chou; I.K.Lee; I.C.Kuo

    2006-01-01

    This study investigates the susceptibility of hot cracking and weldment heat treatment of Haynes 230 superalloy.The Varestriant test was conducted to evaluate this susceptibility. Welding was performed by gas tungsten arc welding(GTAW)and plasma arc welding(PAW)with stress relief heat treatment and solid solution heat treatment. A tensile test is then performed to measure the changes in the mechanical properties of the heattreated material. The results indicate that the number of thermal cycles does not affect the susceptibility of Haynes 230 superalloy to hot cracking. However, it does increase the strain. In weldment of heat treatment,stress relief annealing increases the yield strength and tensile strength of the welded parts. The section of the tensile specimens shows fibrous fractures on the welded parts, regardless of whether they are heat-treated.

  7. Computer Aided Design of Ni-Based Single Crystal Superalloy for Industrial Gas Turbine Blades

    Science.gov (United States)

    Wei, Xianping; Gong, Xiufang; Yang, Gongxian; Wang, Haiwei; Li, Haisong; Chen, Xueda; Gao, Zhenhuan; Xu, Yongfeng; Yang, Ming

    The influence of molybdenum, tungsten and cobalt on stress-rupture properties of single crystal superalloy PWA1483 has been investigated using the simulated calculation of JMatPro software which ha s been widely used to develop single crystal superalloy, and the effect of alloying element on the stability of strengthening phase has been revealed by using the Thermo-Calc software. Those properties calculation results showed that the increasing of alloy content could facilitate the precipitation of TCP phases and increase the lattice misfit between γ and γ' phase, and the effect of molybdenum, tantalum was the strongest and that of cobalt was the weakest. Then the chemical composition was optimized, and the selected compositions showed excellent microstructure stability and stress-rupture properties by the confirmation of d-electrons concept and software calculation.

  8. Notes sur les Limaces

    NARCIS (Netherlands)

    Regteren, van C.O.

    1964-01-01

    9. DESCRIPTION D'UNE NOUVELLE ESPÈ CE DE DEROCERAS DES ENVIRONS DE GRENADE 1) Même pour celui qui ne dispose pas d'une voiture, la ville de Grenade est un magnifique centre d'excursions. Les trams et autobus permettent au naturaliste de sortir de la ville en toutes directions et de commencer ses pro

  9. Notes sur les Limaces

    NARCIS (Netherlands)

    Regteren, van C.O.

    1964-01-01

    9. DESCRIPTION D'UNE NOUVELLE ESPÈ CE DE DEROCERAS DES ENVIRONS DE GRENADE 1) Même pour celui qui ne dispose pas d'une voiture, la ville de Grenade est un magnifique centre d'excursions. Les trams et autobus permettent au naturaliste de sortir de la ville en toutes directions et de commencer ses

  10. Effect of Grinding Temperatures on the Surface Integrity of a Nickel-based Superalloy

    Institute of Scientific and Technical Information of China (English)

    2002-01-01

    An experimental study was carried out to investigat e the influence of temperatures on workpiece surface integrity in surface grinding of a cast nickel-based superalloy with alumina abrasive wheels. Temperatur e response at the wheel-workpiece interface was measured using a grindable foil /workpiece thermocouple. Specimens with different grinding temperatures were obt ained through changing grinding conditions including depth of cut, workpiece fee d speed, and coolant supply. Changes in surface roughnes...

  11. Calorimetric examination of mixtures for modification of nickel and cobalt superalloys

    OpenAIRE

    F. Binczyk; J. Sleziona; R. Przeliorz

    2009-01-01

    The study presents the results of thermodynamic calculations and calorimetric examination of thermal reactions taking place at hightemperatures between the nanoparticle inoculants and metallic constituents of nickel and cobalt superalloys. The calculations andmeasurements were made for different compositions, containing cobalt aluminate CoAl2O4, cobalt oxide CoO*Co2O3, zircon flourZrSi2O4, powdered and metallic Al, powdered Ti, and IN-713C alloy. The obtained results have indicated the possib...

  12. Stem-EDX and FIB-SEM Tomography of ALLVAC 718Plus Superalloy

    Directory of Open Access Journals (Sweden)

    Kruk A.

    2016-06-01

    Full Text Available Allvac 718Plus (718Plus is a high strength, corrosion resistant nickel- based superalloy used for application in power generation, aeronautics and aerospace industry. The 718Plus microstructure consists of a γ matrix with γ’-Ni3(Al,Ti and some δ- Ni3Nb phases as well as lamellar particles (η-Ni3Ti, η*-Ni6AlNb or Ni6(Al,TiNb precipitated at the grain boundaries.

  13. Computational and Experimental Design of Fe-Based Superalloys for Elevated-Temperature Applications

    Energy Technology Data Exchange (ETDEWEB)

    Liaw, Peter K. [Univ. of Tennessee, Knoxville, TN (United States); Fine, Morris E. [Northwestern Univ., Evanston, IL (United States); Ghosh, Gautam [Northwestern Univ., Evanston, IL (United States); Asta, Mark D. [Univ. of California, Berkeley, CA (United States); Liu, Chain T. [Auburn Univ., AL (United States); Sun, Zhiqian [Univ. of Tennessee, Knoxville, TN (United States); Huang, Shenyan [Univ. of Tennessee, Knoxville, TN (United States); Teng, Zhenke [Univ. of Tennessee, Knoxville, TN (United States); Wang, Gongyao [Univ. of Tennessee, Knoxville, TN (United States)

    2012-04-13

    Analogous to nickel-based superalloys, Fe-based superalloys, which are strengthened by coherent B2- type precipitates are proposed for elevated-temperature applications. During the period of this project, a series of ferritic superalloys have been designed and fabricated by methods of vacuum-arc melting and vacuum-induction melting. Nano-scale precipitates were characterized by atom-probe tomography, ultrasmall- angle X-ray scattering, and transmission-electron microscopy. A duplex distribution of precipitates was found. It seems that ferritic superalloys are susceptible to brittle fracture. Systematic endeavors have been devoted to understanding and resolving the problem. Factors, such as hot rolling, precipitate volume fractions, alloy compositions, precipitate sizes and inter-particle spacings, and hyperfine cooling precipitates, have been investigated. In order to understand the underlying relationship between the microstructure and creep behavior of ferric alloys at elevated temperatures, in-situ neutron studies have been carried out. Based on the current result, it seems that the major role of β' with a 16%-volume fraction in strengthening ferritic alloys is not load sharing but interactions with dislocations. The oxidation behavior of one ferritic alloy, FBB8 (Fe-6.5Al-10Ni-10Cr-3.4Mo-0.25Zr-0.005B, weight percent), was studied in dry air. It is found that it possesses superior oxidation resistance at 1,023 and 1,123 K, compared with other creep-resistant ferritic steels [T91 (modified 9Cr-1Mo, weight percent) and P92 (9Cr-1.8W-0.5Mo, weight percent)]. At the same time, the calculation of the interfacial energies between the -iron and B2-type intermetallics (CoAl, FeAl, and NiAl) has been conducted.

  14. HIGH-TEMPERATURE LOW CYCLE FATIGUE BEHAVIOR OFNICKEL BASE SUPERALLOY GH536

    Institute of Scientific and Technical Information of China (English)

    M. Zhao; L.Y. Xu; K.S. Zhang; B.Y. Yang

    2001-01-01

    Low cycle fatigue tests on nickel base superalloy GH536 were performed at 600. 700and 800°C. The strain-life and cyclic stress-strain relationship were given at various temperatures. The change in fatigue life behavior and fatigue parameters with temperature increasing was discussed. At low and intermediate total strain amplitudes,the fatigue life was found to decrease with increasing temperature.``

  15. Interdiffusion between Ni-based superalloy and MCrAlY coating

    DEFF Research Database (Denmark)

    Dahl, Kristian Vinter; Hald, John; Horsewell, Andy

    2006-01-01

    Interdiffusion at the interface between a Co-36.5Ni-17.5Cr-8Al-0.5Y, MCrAlY coating and the underlying IN738 superalloy was studied in a large matrix of specimens isothermally heat treated for up to 12,000 hours at temperatures 875oC, 925oC or 950oC. Modelled results using the finite difference...

  16. Solution heat-treatment of Nb-modified MAR-M247 superalloy

    Energy Technology Data Exchange (ETDEWEB)

    Soares Azevedo e Silva, Paulo Ricardo, E-mail: paulori@alunos.eel.usp.br [Universidade de Sao Paulo (USP), Escola de Engenharia de Lorena (EEL), Departamento de Engenharia de Materiais DEMAR, Polo Urbo-Industrial Gleba AI-6, Caixa Postal 116, 12600-970, Lorena, Sao Paulo (Brazil); Baldan, Renato, E-mail: renato@ppgem.eel.usp.br [Universidade de Sao Paulo (USP), Escola de Engenharia de Lorena (EEL), Departamento de Engenharia de Materiais DEMAR, Polo Urbo-Industrial Gleba AI-6, Caixa Postal 116, 12600-970, Lorena, Sao Paulo (Brazil); Nunes, Carlos Angelo, E-mail: cnunes@demar.eel.usp.br [Universidade de Sao Paulo (USP), Escola de Engenharia de Lorena (EEL), Departamento de Engenharia de Materiais DEMAR, Polo Urbo-Industrial Gleba AI-6, Caixa Postal 116, 12600-970, Lorena, Sao Paulo (Brazil); Carvalho Coelho, Gilberto, E-mail: coelho@demar.eel.usp.br [Universidade de Sao Paulo (USP), Escola de Engenharia de Lorena (EEL), Departamento de Engenharia de Materiais DEMAR, Polo Urbo-Industrial Gleba AI-6, Caixa Postal 116, 12600-970, Lorena, Sao Paulo (Brazil); UniFoa, Centro Universitario de Volta Redonda, Nucleo de Pesquisa, Campus Tres Pocos, Avenida Paulo Erlei Alves Abrantes, 1325, Bairro Tres Pocos, 27240-560, Volta Redonda, Rio de Janeiro (Brazil); and others

    2013-01-15

    MAR-M247 superalloy has excellent mechanical properties and good oxidation resistance at elevated temperatures. Niobium is an element known as {gamma} Prime phase hardener in nickel-based superalloys, besides promoting homogeneous distribution of MC carbides. This work is inserted in a project that aims to evaluate the total replacement of tantalum by niobium atoms in MAR-M247 superalloy (10.2 Co, 10.2 W, 8.5Cr, 5.6 Al, 1.6 Nb, 1.4 Hf, 1.1 Ti, 0.7 Mo, 0.15 C, 0.06 Zr, 0.015 B, Ni balance-wt.%). Based on microstructural characterizations (SEM and FEG-SEM, both with EDS) of the as-cast material and heat-treated materials as well as utilizing Thermocalc simulations and experiments of differential thermal analysis (DTA), heat-treatment at 1260 Degree-Sign C for 8 h was chosen as an ideal condition for the solution of Nb-modified MAR-M247 superalloy. The hardness of as-cast and ideally solution treated materials was 390 {+-} 14 HV and 415 {+-} 6 HV, respectively. - Highlights: Black-Right-Pointing-Pointer DTA and microstructure of MAR-M247(Nb) showed a good agreement with Thermocalc. Black-Right-Pointing-Pointer An ideal condition for solution heat-treatment of MAR-M247(Nb) is 1260 Degree-Sign C for 8 h. Black-Right-Pointing-Pointer It was an observed evidence of incipient melting in samples heat-treated at 1280 Degree-Sign C.

  17. Misorientation related microstructure at the grain boundary in a nickel-based single crystal superalloy

    Energy Technology Data Exchange (ETDEWEB)

    Huang, Ming; Zhuo, Longchao [National Center for Electron Microscopy in Beijing, School of Materials Science and Engineering, The State Key Laboratory of New Ceramics and Fine Processing, Laboratory of Advanced Materials (MOE), Tsinghua University, Beijing 100084 (China); Liu, Zhanli [Applied Mechanics Lab, School of Aerospace, Tsinghua University, Beijing 100084 (China); Lu, Xiaogang [School of Materials Science and Engineering, Shanghai University, Shanghai (China); Shi, Zhenxue; Li, Jiarong [Science and Technology on Advanced High Temperature Structural Materials Laboratory, Beijing Institute of Aeronautical Materials, Beijing 100095 (China); Zhu, Jing, E-mail: jzhu@mail.tsinghua.edu.cn [National Center for Electron Microscopy in Beijing, School of Materials Science and Engineering, The State Key Laboratory of New Ceramics and Fine Processing, Laboratory of Advanced Materials (MOE), Tsinghua University, Beijing 100084 (China)

    2015-07-29

    The mechanical properties of nickel-based single crystal superalloys deteriorate with increasing misorientation, thus the finished product rate of the casting of single crystal turbine airfoils may be reduced due to the formation of grain boundaries especially when the misorientation angle exceeds to some extent. To this day, evolution of the microstructures at the grain boundaries with misorientation and the relationship between the microstructures and the mechanical properties are still unclear. In this work a detailed characterization of the misorientation related microstructure at the grain boundary in DD6 single crystal superalloy has been carried out using scanning electron microscopy (SEM) and transmission electron microscopy (TEM) techniques; the elemental distribution at the grain boundaries has been analyzed by energy dispersive (EDS) X-ray mapping; and the effect of precipitation of μ phases at the grain boundary on the mechanical property has been evaluated by finite element calculation. It is shown that the proportion of γ phase at the grain boundaries decreases, while the proportion of γ′ phase at the grain boundaries increases with increasing misorientation; the μ phase is precipitated at the grain boundaries when the misorientation angle exceeds about 10° and thus it could lead to a dramatic deterioration of the mechanical properties, as well as that the enrichment of Re and W gradually disappears as the misorientation angle increases. All these factors may result in the degradation of the mechanical properties at the grain boundaries as the misorientation increases. Furthermore, the finite element calculation confirms that precipitation of μ phases at the grain boundary is responsible for the significant deterioration of the mechanical properties when the misorientation exceeds about 10°. This work provides a physical imaging of the microstructure for understanding the relationship between the mechanical properties and the misorientation

  18. Interdiffusion between Ni-based superalloy and MCrAlY coating

    DEFF Research Database (Denmark)

    Dahl, Kristian Vinter; Hald, John; Horsewell, Andy

    2006-01-01

    Interdiffusion at the interface between a Co-36.5Ni-17.5Cr-8Al-0.5Y, MCrAlY coating and the underlying IN738 superalloy was studied in a large matrix of specimens isothermally heat treated for up to 12,000 hours at temperatures 875oC, 925oC or 950oC. Modelled results using the finite difference...

  19. Development of advanced P/M Ni-base superalloys for turbine disks

    OpenAIRE

    Garibov Genrikh S.; Grits Nina M.; Vostrikov Alexey V.; Fedorenko Yelizaveta A.; Volkov Alexander M.

    2014-01-01

    In the process of evolution of powder metallurgy in Russia the task permanently formulated was the following: to improve strength properties of P/M superalloys without application of additional complex HIPed blanks deformation operation. On the other hand development of a turbine disk material structure to ensure an improvement in aircraft engine performance requires the use of special HIP and heat treatment conditions. To ensure maximum strength properties of disk materials it is necessary t...

  20. Microstructurally sensitive crack nucleation around inclusions in powder metallurgy nickel based superalloys

    OpenAIRE

    Jiang, J; Yang, J; Zhang, T.; J Zou; Wang,Y.,; Dunne, F.P.E.; Britton, T. B.

    2016-01-01

    ? 2016 Acta Materialia Inc.Nickel-based superalloys are used in high strength, high-value applications, such as gas turbine discs in aero engines. In these applications the integrity of the disc is critical and therefore understanding crack initiation mechanisms is of high importance. With an increasing trend towards powder metallurgy routes for discs, sometimes unwanted non-metallic inclusions are introduced during manufacture. These inclusions vary in size from ?10??m to 200??m which is com...

  1. First principles calculations of the site substitution behavior in gamma prime phase in nickel based superalloys

    Science.gov (United States)

    Chaudhari, Mrunalkumar

    Nickel based superalloys have superior high temperature mechanical strength, corrosion and creep resistance in harsh environments and found applications in the hot sections as turbine blades and turbine discs in jet engines and gas generator turbines in the aerospace and energy industries. The efficiency of these turbine engines depends on the turbine inlet temperature, which is determined by the high temperature strength and behavior of these superalloys. The microstructure of nickel based superalloys usually contains coherently precipitated gamma prime (gamma') Ni3Al phase within the random solid solution of the gamma (gamma) matrix, with the gamma' phase being the strengthening phase of the superalloys. How the alloying elements partition into the gamma and gamma' phases and especially in the site occupancy behaviors in the strengthening gamma' phases play a critical role in their high temperature mechanical behaviors. The goal of this dissertation is to study the site substitution behavior of the major alloying elements including Cr, Co and Ti through first principles based calculations. Site substitution energies have been calculated using the anti-site formation, the standard defect formation formalism, and the vacancy formation based formalism. Elements such as Cr and Ti were found to show strong preference for Al sublattice, whereas Co was found to have a compositionally dependent site preference. In addition, the interaction energies between Cr-Cr, Co-Co, Ti-Ti and Cr-Co atoms have also been determined. Along with the charge transfer, chemical bonding and alloy chemistry associated with the substitutions has been investigated by examining the charge density distributions and electronic density of states to explain the chemical nature of the site substitution. Results show that Cr and Co atoms prefer to be close by on either Al sublattice or on a Ni-Al mixed lattice, suggesting a potential tendency of Cr and Co segregation in the gamma' phase.

  2. Factors affecting the corrosion fatigue life in nickel based superalloys for disc applications

    OpenAIRE

    Rosier Hollie; Perkins Karen; Girling Andrew; Leggett Jonathan; Gibson Grant

    2014-01-01

    The nickel based superalloy 720Li is employed in the gas turbine due to its mechanical performance at elevated temperature. A comprehensive assessment of the materials behaviour under representative service conditions is reported to address the drive for ever increasing temperatures and more arduous environmental exposure. Fatigue experiments have been performed in an air and air/SOx environment at 700 ∘C containing a mixed salt as a contaminant. There is an intimate relationship between loca...

  3. Use of Precious Metal-Modifed Nickel-Base Superalloys for Thin Gage Applications (Preprint)

    Science.gov (United States)

    2011-04-01

    Historically, sandwich construction MTPS (outer surface-Alloy 617 nickel-base superalloy honeycomb core and face sheets; inner surface titanium alloy honeycomb ...National Aeronautics and Space Administration ( NASA ) X-33 vehicle2, a wedged-shaped subscale prototype of a reusable launch vehicle4 designed by...MTPS, materials under consideration must be very thin, 0.17 mm-0.25 mm for a typical face sheet and 0.05mm-0.10 mm for honeycomb core. One

  4. Development of the recovery technology for nickel superalloy blades of the aircraft engine by laser cladding

    Science.gov (United States)

    Bykovskiy, D. P.; Petrovskiy, V. N.; Polskiy, V. I.; Chirikov, S. N.; Dzhumaev, P. S.

    2016-09-01

    Development of cladding modes was performed with a superalloy nickel based powder on a flat substrate from material identical to compressor and turbine blades. Cross sections were made, and a visual inspection of the shape and the quality of the clad track as well as themetallographic analysis were performed. Microhardness of the deposition zone, chemical composition of the base, cladded metals, and the heat affected zone were determined.

  5. Crystallographic, microstructure and mechanical characteristics of dynamically processed IN718 superalloy

    Energy Technology Data Exchange (ETDEWEB)

    Sharma, A.D., E-mail: ads.hpu@gmail.com [Department of Physics, Himachal Pradesh University, Shimla 171005 (India); Sharma, A.K. [Terminal Ballistics Research Laboratory, Chandigarh 160030 (India); Thakur, N. [Department of Physics, Himachal Pradesh University, Shimla 171005 (India)

    2014-06-01

    Highlights: • Measurement of detonation velocity and compaction of powder are achieved together. • A plastic explosive detonation results into dense compacts without grain-growth. • We have studied crystallographic, micromechanical and microstructural features. • The results show no segregation within the compacts. • Density (98%), microhardness (470 ± 3)H{sub v}, microstrain (0.3%), UTS (806 MPa) are obtained. - Abstract: Dynamic consolidation of IN718 superalloy powder without grain-growth and negligible density gradient is accomplished through explosively generated shock wave loading. The compaction of powder and measurement of detonation velocity are achieved successfully in a single-shot experiment by employing instrumented detonics. A plastic explosive having a detonation velocity of the order of 7.1 km/s in a direct proximity with superalloy powder is used for the consolidation process. The compacted specimens are examined for structural, microstructure and mechanical characteristics. X-ray diffraction (XRD) study suggests intact crystalline structure of the compacts. A small micro-strain (0.26%) is observed by using Williamson–Hall method. Wavelength dispersive spectroscopy indicates no segregation within the shock processed superalloy compacted specimens. The monoliths investigated for fractography by using field emission scanning electron microscopy (FE-SEM) show original dendritic structure accompanied by re-solidified molten regions across the interparticle boundaries. Depth-sensing indentations (at 1.96 N) on compacted specimens show excellent micro-hardness of the order of (470 ± 3)H{sub v}. Tensile and compressive strengths of the superalloy monolith are observed to be 806 and 822 MPa, respectively.

  6. Predicting the onset of rafting of c 0 precipitates by channel deformation in a Ni superalloy

    OpenAIRE

    Ratel-Ramond, Nicolas; Calderon, H. A.; MORI, T.; Withers, Philip J.

    2010-01-01

    Abstract The growth or shrinkage, normal to {001}, of the interfaces between the ? matrix and cuboidal ?' precipitates is examined for a Ni-base superalloy, by considering the force acting on the interfaces. The force is produced by the precipitate coherency misfit and the stress produced by plastic deformation in channels of the ? matrix. A simple expression, which directly addresses the origin of the surface force, is given. The plastic deformation within the initially activ...

  7. Feasibility of Electrochemical Deposition of Nickel/Silicon Carbide Fibers Composites over Nickel Superalloys

    Science.gov (United States)

    Ambrosio, E. P.; Abdul Karim, M. R.; Pavese, M.; Biamino, S.; Badini, C.; Fino, P.

    2017-02-01

    Nickel superalloys are typical materials used for the hot parts of engines in aircraft and space vehicles. They are very important in this field as they offer high-temperature mechanical strength together with a good resistance to oxidation and corrosion. Due to high-temperature buckling phenomena, reinforcement of the nickel superalloy might be needed to increase stiffness. For this reason, it was thought to investigate the possibility of producing composite materials that might improve properties of the metal at high temperature. The composite material was produced by using electrochemical deposition method in which a composite with nickel matrix and long silicon carbide fibers was deposited over the nickel superalloy. The substrate was Inconel 718, and monofilament continuous silicon carbide fibers were chosen as reinforcement. Chemical compatibility was studied between Inconel 718 and the reinforcing fibers, with fibers both in an uncoated condition, and coated with carbon or carbon/titanium diboride. Both theoretical calculations and experiments were conducted, which suggested the use of a carbon coating over the fibers and a buffer layer of nickel to avoid unwanted reactions between the substrate and silicon carbide. Deposition was then performed, and this demonstrated the practical feasibility of the process. Yield strength was measured to detect the onset of interface debonding between the substrate and the composite layer.

  8. Study of Flow Softening Mechanisms of a Nickel-Based Superalloy With Δ Phase

    Directory of Open Access Journals (Sweden)

    Lin Y.C.

    2016-09-01

    Full Text Available The flow softening behaviors of a nickel-based superalloy with δ phase are investigated by hot compression tests over wide ranges of deformation temperature and strain rate. Electron backscattered diffraction (EBSD, optical microscopy (OM, and scanning electron microscopy (SEM are employed to study the flow softening mechanisms of the studied superalloy. It is found that the flow softening behaviors of the studied superalloy are sensitive to deformation temperature and strain rate. At high strain rate and low deformation temperature, the obvious flow softening behaviors occur. With the increase of deformation temperature or decrease of strain rate, the flow softening degree becomes weaken. At high strain rate (1s−1, the flow softening is mostly induced by the plastic deformation heating and flow localization. However, at low strain rate domains (0.001-0.01s−1, the effects of deformation heating on flow softening are slight. Moreover, the flow softening at low strain rates is mainly induced by the discontinuous dynamic recrystallization and the dissolution of δ phase (Ni3Nb.

  9. Computational and experimental observations of welds in third-generation nickel-based superalloys

    Science.gov (United States)

    Naffakh-Moosavy, Homam

    2016-02-01

    The purpose of the present study is to introduce the weld quantitative solidification paths in the newly designed third-generation superalloys. The research has been conducted using both computational and experimental approaches. The model used the Scheil solidification relations to correlate the partitioning elements with their effects on the solidification paths. Accordingly, the k values were calculated for all the participating elements in the superalloy welds. The results of model demonstrated that these were very close to unity for austenite former elements, i.e. Ni, Co, Cr and Fe, while the other elements such as Ti, Nb and Mo displayed a significant tendency for segregation. The mathematical equations were calculated for weld solidification paths of superalloys. In all the welds, a remarkable segregation behaviour was observed, especially for Nb and Ti. The solidification path equations predicted type and amount of secondary phases. The solidification paths were compared with eutectic reactions ?, and ?, on the basis of the Ni-Ti-C and Ni-Nb-C ternary phase diagrams. Both the experimental measurements and microstructural observations of eutectics exhibited an appropriate accordance with the solidification paths obtained by model calculations.

  10. Constitutive behavior and processing maps of low-expansion GH909 superalloy

    Science.gov (United States)

    Yao, Zhi-hao; Wu, Shao-cong; Dong, Jian-xin; Yu, Qiu-ying; Zhang, Mai-cang; Han, Guang-wei

    2017-04-01

    The hot deformation behavior of GH909 superalloy was studied systematically using isothermal hot compression tests in a temperature range of 960 to 1040°C and at strain rates from 0.02 to 10 s-1 with a height reduction as large as 70%. The relations considering flow stress, temperature, and strain rate were evaluated via power-law, hyperbolic sine, and exponential constitutive equations under different strain conditions. An exponential equation was found to be the most appropriate for process modeling. The processing maps for the superalloy were constructed for strains of 0.2, 0.4, 0.6, and 0.8 on the basis of the dynamic material model, and a total processing map that includes all the investigated strains was proposed. Metallurgical instabilities in the instability domain mainly located at higher strain rates manifested as adiabatic shear bands and cracking. The stability domain occurred at 960-1040°C and at strain rates less than 0.2 s-1; these conditions are recommended for optimum hot working of GH909 superalloy.

  11. Microstructural response to heat affected zone cracking of prewelding heat-treated Inconel 939 superalloy

    Energy Technology Data Exchange (ETDEWEB)

    Gonzalez, M.A., E-mail: mgonzalez@comimsa.com.mx [Facultad de Ingenieria Mecanica y Electrica (FIME-UANL), Av. Universidad s/n. Ciudad Universitaria, C.P.66451 San Nicolas de los Garza, N.L. (Mexico); Martinez, D.I., E-mail: dorairma@yahoo.com [Facultad de Ingenieria Mecanica y Electrica (FIME-UANL), Av. Universidad s/n. Ciudad Universitaria, C.P.66451 San Nicolas de los Garza, N.L. (Mexico); Perez, A., E-mail: betinperez@hotmail.com [Facultad de Ingenieria Mecanica y Electrica (FIME-UANL), Av. Universidad s/n. Ciudad Universitaria, C.P.66451 San Nicolas de los Garza, N.L. (Mexico); Guajardo, H., E-mail: hguajardo@frisa.com [FRISA Aerospace, S.A. de C.V., Valentin G. Rivero No. 200, Col. Los Trevino, C.P. 66150, Santa Caterina N.L. (Mexico); Garza, A., E-mail: agarza@comimsa.com [Corporacion Mexicana de Investigacion en Materiales S.A. de C.V. (COMIMSA), Ciencia y Tecnologia No.790, Saltillo 400, C.P. 25295 Saltillo Coah. (Mexico)

    2011-12-15

    The microstructural response to cracking in the heat-affected zone (HAZ) of a nickel-based IN 939 superalloy after prewelding heat treatments (PWHT) was investigated. The PWHT specimens showed two different microstructures: 1) spherical ordered {gamma} Prime precipitates (357-442 nm), with blocky MC and discreet M{sub 23}C{sub 6} carbides dispersed within the coarse dendrites and in the interdendritic regions; and 2) ordered {gamma} Prime precipitates in 'ogdoadically' diced cube shapes and coarse MC carbides within the dendrites and in the interdendritic regions. After being tungsten inert gas welded (TIG) applying low heat input, welding speed and using a more ductile filler alloy, specimens with microstructures consisting of spherical {gamma} Prime precipitate particles and dispersed discreet MC carbides along the grain boundaries, displayed a considerably improved weldability due to a strong reduction of the intergranular HAZ cracking associated with the liquation microfissuring phenomena. - Highlights: Black-Right-Pointing-Pointer Homogeneous microstructures of {gamma} Prime spheroids and discreet MC carbides of Ni base superalloys through preweld heat treatments. Black-Right-Pointing-Pointer {gamma} Prime spheroids and discreet MC carbides reduce the intergranular HAZ liquation and microfissuring of Nickel base superalloys. Black-Right-Pointing-Pointer Microstructure {gamma} Prime spheroids and discreet blocky type MC carbides, capable to relax the stress generated during weld cooling. Black-Right-Pointing-Pointer Low welding heat input welding speeds and ductile filler alloys reduce the HAZ cracking susceptibility.

  12. Molecular dynamics study of mosaic structure in the Ni-based single-crystal superalloy

    Institute of Scientific and Technical Information of China (English)

    Zhu Tao; Wang Chong-Yu

    2006-01-01

    The mosaic structure in a Ni-based single-crystal superalloy is simulated by molecular dynamics using a potential employed in a modified analytic embedded atom method. From the calculated results we find that a closed three dimensional misfit dislocation network, with index of {100} and the side length of the mesh 89.6(A), is formed around a cuboidal γ' precipitate. Comparing the simulation results of the different mosaic models, we find that the side length of the mesh only depends on the lattice parameters of the γ and γ' phases as well as the γ/γ' interface direction, but is independent of the size and number of the cuboidal γ' precipitate. The density of dislocations is inversely proportional to the size of the cuboidal γ' precipitate, i.e. the amount of the dislocation is proportional to the total area of the γ/γ' interface, which may be used to explain the relation between the amount of the fine γ' particles and the creep rupture life of the superalloy. In addition, the closed three-dimensional networks assembled with the misfit dislocations can play a significant role in improving the mechanical properties of superalloys.

  13. Phase transformation and segregation to lattice defects in Ni-base superalloys.

    Science.gov (United States)

    Blavette, Didier; Cadel, Emmanuel; Pareige, Cristelle; Deconihout, Bernard; Caron, Pierre

    2007-12-01

    Nanostructural features of nickel-base superalloys as revealed by atom probe field ion microscopy (APFIM) and atom probe tomography (APT) are reviewed. The more salient information provided by these techniques is discussed through an almost exhaustive analysis of literature over the last 30 years. Atom probe techniques are shown to be able to measure the composition of tiny gamma' precipitates, a few nanometers in size, and to reveal chemical order within these precipitates. Phase separation kinetics in model NiCrAl alloys was investigated with both 3DAP and Monte-Carlo simulation. Results are shown to be in good agreement. Plane by plane analysis of {001} planes of Ni(3)Al-type gamma' phase makes it possible to estimate the degree of order as well as the preferential sites of various addition elements (Ti, Cr, Co, W, Ta, Re, Ru, etc.) included in superalloys. Clustering effects of Re in the gamma solid solution were also exhibited. Due to its ultrahigh depth resolution, the microchemistry of interfaces and grain boundaries can be characterized on an atomic scale. Grain boundaries in Astroloy or N18 superalloys were found to be enriched in B, Mo, and Cr and Al depleted.

  14. Welding Metallurgy of Nickel-Based Superalloys for Power Plant Construction

    Science.gov (United States)

    Tung, David C.

    Increasing the steam temperature and pressure in coal-fired power plants is a perpetual goal driven by the pursuit of increasing thermal cycle efficiency and reducing fuel consumption and emissions. The next target steam operating conditions, which are 760°C (1400°F) and 35 MPa (5000 psi) are known as Advanced Ultra Supercritical (AUSC), and can reduce CO2 emissions up to 13% but this cannot be achieved with traditional power plant construction materials. The use of precipitation-strengthened Nickel-based alloys (superalloys) is required for components which will experience the highest operating temperatures. The leading candidate superalloys for power plant construction are alloys 740H, 282, and 617. Superalloys have excellent elevated temperature properties due to careful microstructural design which is achieved through very specific heat treatments, often requiring solution annealing or homogenization at temperatures of 1100 °C or higher. A series of postweld heat treatments was investigated and it was found that homogenization steps before aging had no noticeable effect on weld metal microhardness, however; there were clear improvements in weld metal homogeneity. The full abstract can be viewed in the document itself.

  15. Modeling microstructure evolution in the delta process forging of superalloy IN718 turbine discs

    Science.gov (United States)

    Zhang, Haiyan; Zhang, Shihong; Cheng, Ming; Zhao, Zhong

    2013-05-01

    The microstructure development in the Delta Process (DP) forging of Superalloy IN718 turbine discs were predicted using the combined approach of axisymmetric finite element simulation and modeling for the dynamic recrystallization and grain growth. In order to establish the deformation constitutive equation and dynamic recrystallization models for the DP process of Superalloy IN718, the isothermal compression tests were carried out in the temperature range 950 to 1010 °C and strain rates range 0.001 to0.1s-1. Moreover, the isothermal heat treatment tests after hot deformation were conducted in the temperature range 950 to 1040°C to generate the grain growth model. The experimental results indicated the existence of the δ phase could make the activation energy of deformation increase. Furthermore, the existence of the δ phase could stimulate the occurrence of dynamic recrystallization, and the grain growth was restrained due to the pinning effect of δ phase. The predicted grain size and its distribution in the DP forging of Superalloy IN718 turbine discs were compared with the actual microstructures deformed by the hot die forging. It was found that the forging with uniform fine grains could be obtained by the application of DP process to the forging of the turbine disk, in which the alloy was pre-precipitated δ phase after the baiting in the original process.

  16. Investigation of Oxide Bifilms in Investment Cast Superalloy IN100: Part II. Characterization

    Science.gov (United States)

    Kaplan, Max A.; Fuchs, Gerhard E.

    2016-05-01

    Oxide bifilms are a proposed casting inclusion reported to have been observed in vacuum investment cast polycrystalline Ni-based superalloys. Ongoing research seeks to determine if current superalloy casting practices can result in the formation of oxide bifilms, and subsequently if it is possible to observe and characterize this phenomenon. The effect of casting atmosphere, turbulence, filtering, hot isostatic pressing, and heat treatment has been investigated to identify the critical parameters that have been reported to result in bifilm formation in Ni-based superalloy IN100. Scanning Auger microscopy (SAM), scanning electron microscopy (SEM), and high-resolution transmission electron microscopy (HR-TEM) were utilized to characterize samples from each casting condition. In situ ultrahigh vacuum Auger fractography did not indicate the presence of bifilms on the fracture behavior of IN100 in any processing condition. SAM analysis identified a sulfur-enriched monolayer on the surface of dendritic casting porosity, and identified heterogeneous Ti oxycarbide inclusions in air cast IN100. SEM analysis also indicated the presence of Ti oxycarbide inclusions in air cast IN100, and determined that these inclusion structures consist of fine blocky external M(Ti, Mo)C carbide enveloping an internal core of alumina. HR-TEM analysis indicated that none of the oxycarbide inclusion interfaces exist as discontinuous unbound interfaces, and that the internal alumina core is an ultra-fine polycrystalline structure.

  17. Study on Application of Grey Prediction Model in Superalloy MAR-247 Machining

    Directory of Open Access Journals (Sweden)

    Chen Shao-Hsien

    2015-01-01

    Full Text Available Superalloy MAR-247 is mainly applied in the space industry and die industry. With its characteristics of mechanical property, fatigue resistance, and high temperature corrosion resistance, therefore, it is mainly applied in machine parts of high temperature and corrosion resistance, such as turbine blades and rotor of the aeroengine and turbine assembly in the nuclear power plant. However, considering that its properties of high strength, low thermal conductivity, being difficult to soften, and work hardening may reduce the life of cutting-tool and weaken the surface accuracy, the study provided minimizing experiment occurring during milling process for superalloy material. As a statistical approach used to analyse experiment data, this study used GM(1,1 in the grey prediction model to conduct simulation and then predict and analyze its characteristics based on the experimental data, focusing on the tool life and surface accuracy. Moreover, with the superalloy machining parameters of the current effective application improved grey prediction model, it can decrease the errors, extend the tool life, and improve the prediction precision of surface accuracy.

  18. Figures of Merit Software: Description, User's Guide, Installation Notes, Versions Description, and License Agreement

    Science.gov (United States)

    hoelzer, H. D.; Fourroux, K. A.; Rickman, D. L.; Schrader, C. M.

    2011-01-01

    Figures of Merit (FoMs) and the FoM software provide a method for quantitatively evaluating the quality of a regolith simulant by comparing the simulant to a reference material. FoMs may be used for comparing a simulant to actual regolith material, specification by stating the value a simulant s FoMs must attain to be suitable for a given application and comparing simulants from different vendors or production runs. FoMs may even be used to compare different simulants to each other. A single FoM is conceptually an algorithm that computes a single number for quantifying the similarity or difference of a single characteristic of a simulant material and a reference material and provides a clear measure of how well a simulant and reference material match or compare. FoMs have been constructed to lie between zero and 1, with zero indicating a poor or no match and 1 indicating a perfect match. FoMs are defined for modal composition, particle size distribution, particle shape distribution, (aspect ratio and angularity), and density. This TM covers the mathematics, use, installation, and licensing for the existing FoM code in detail.

  19. A note on

    Directory of Open Access Journals (Sweden)

    Lie-Fern Hsu

    2012-10-01

    Full Text Available Wee et al. (2007 developed an optimal inventory model. In this technical note, we point out a contradiction between Wee et al.'s model and their assumption. A corrected model is developed based on their assumption. Numerical examples show that in terms of the two decision variables, there is a significant difference between the corrected model and Wee et al.'s model. The results also show that that the penalty of using Wee et al.'s model can be significant under certain situations.

  20. OpenLabNotes

    DEFF Research Database (Denmark)

    List, Markus; Franz, Michael; Tan, Qihua

    2015-01-01

    the longevity of the providers. Turning towards free alternatives, however, raises questions about data protection, which are not sufficiently addressed by available solutions. To serve as legal documents, ELNs must prevent scientific fraud through technical means such as digital signatures. It would also......LabFramework, a powerful and flexible laboratory information management system. In contrast to comparable solutions, it allows to protect the intellectual property of its users by offering data protection with digital signatures. OpenLabNotes effectively Closes the gap between research documentation and sample management...

  1. MISCELLANEOUS BOTANICAL NOTES 2

    Directory of Open Access Journals (Sweden)

    A.J.G.H KOSTERMANS

    2014-01-01

    Full Text Available 1.   Durio  cupreus Ridley is considered to  represent a  distinct  species.2.   Durio wyatt-smithii Kosterm. is reported from Borneo.3.   Machilus nervosa Merr. represents Meliosma bontoeensis Merr.4.   Beilschmiedia brassii Allen represents Vavaea brassii (Allen Kosterm.5.   The author of the generic name Heritiera is Aiton.6.   Heritiera macrophylla (non Wall. Merr. is conspecific with H. ungus-tata Pierre.7.   Some specimens from N. Celebes, attributed formerly to H. sylvatica Merr., belong to H. arafurensis Kosterm.8.   Additional note on Heritiera littoralis Ait. and H. macrophylla Wall, ex Kurz.9.   Heritiera   montana   Kosterm.,   nov.   spec,   from   New   Guinea   and H. khidii Kosterm., nov. spec, from Northern Siam.10.   Additional note on Heritiera, novoguineensis Kosterm. and H. pereo-riacea Kosterm. and an undescribed species.11.   Heritiera acuminata Wall, ex Kurz represents a distinct species.12.   Heritiera  solomonensis  Kosterm.,  nov.  spec,  from the  Solomon  Isl.13.   A note on Firmiana bracteata A. DC.14.   Firmiana fulgens (Wall, ex King  Corner is based on a mixtum com-positum and has been the source of constant confusion. For the element, which occurs in Malaysia a new name is coined: F. malayana Kosterm. It does not occur in Tenasserim.15.   A revised bibliography of Firmiana colorata R. Br., F. pallens Stearn and F. malayana Kosterm. is presented.16.   Additional note on Firmiana hainanensis Kosterm.17.   Firmiana kerrii (Craib Kosterm., comb, nov., based on Sterculia kerrii Craib.18.   Additional specimens of Firmiana papuana Mildbr.19.   Cryptocarya hintonii Allen is referred to Primus as Primus hintonii (Allen  Kosterm.20.   Beilschmiedia wallichiana (G. Don   Kosterm., based on Sideroxylon wallichianum, G. Don, is described. Formerly it was relegated to Litsea by Kurz.21.   New species in Lauraceae: Beilschmiedia aborensis Kosterm., B

  2. Notes on functional analysis

    CERN Document Server

    Bhatia, Rajendra

    2009-01-01

    These notes are a record of a one semester course on Functional Analysis given by the author to second year Master of Statistics students at the Indian Statistical Institute, New Delhi. Students taking this course have a strong background in real analysis, linear algebra, measure theory and probability, and the course proceeds rapidly from the definition of a normed linear space to the spectral theorem for bounded selfadjoint operators in a Hilbert space. The book is organised as twenty six lectures, each corresponding to a ninety minute class session. This may be helpful to teachers planning a course on this topic. Well prepared students can read it on their own.

  3. Investigation of Creep Feed Grinding Parameters and Heat treatment Effects on the Nickel-base Superalloys

    Institute of Scientific and Technical Information of China (English)

    Hasan Jamshidi; Sayed Ali Sadough Vanini; Alireza Attari

    2004-01-01

    The Nickel base Superalloys are the most famous complicated and useable of Superalloys to make hot zone components of the gas turbines. The complicated dimensional tolerances, specially at the root of the blade show importance of grinding processes at the production of blades root. The prediction of the effect of machining parameters on the soundness of component surface strengthening for reaching to a suitable surface finishing and avoiding from crack formation at the work part during machining operation often is not easy and feasible so needs to more industrial investigation.This research is about frame 5 blade designed by GE and made from Superalloy IN738LC has been investigated. The formation of a plastically deformed and heat affected zone during grinding of Superalloy IN738LC with a high depth of cut but slow work speed (creep feed grinding) was investigated. Parameters such as work speed, depth of cut and radial dressing speed have been considered as variables and their effects have been studied. During experimental performed, the voltage and current of motor measured and power and special energy calculated.Some samples heat-treated (of the 1176℃ for 1 hr under neutral argon gas and cooling rate of 15℃/min up to 537℃ and then air cooling) to study grains recrystallization. Other samples have been created from the roots of blades and then coated by Nickel to measure boundary layer micro-hardness. The results show that increasing work speed leads to increasing the use power. Increasing the depth of cut, by increasing material removal rate, and the radial dressing speed, by decreasing power, lead to decreasing special energy. The temperature created by grinding lead to decreasing plastic deformation and boundary layer formation. When the radial dressing speed changes from 1 to 0.6 μm/rev and other parameters are kept unchanged the roughness of surface increases and the special energy decreases. Sufficient dressing is very essential in limiting the width

  4. Oxidation behavior of Ni(Co)CrAlYHf(Si) coatings on DS superalloy at 1 150 ℃

    Institute of Scientific and Technical Information of China (English)

    HUANG Zhao-hui; TAN Yong-ning; ZHAO Xi-hong; LI Jian-ping; ZHANG Qiang

    2006-01-01

    Two Ni(Co)CrAlY coatings were deposited by EB-PVD method on a DS superalloy of Ni-Al-Cr-Co-W-Mo-Ta-Hf system. SEM, XEDS and XRD were used to study the oxidation behavior of the coatings. The two coatings show a good protection for the DS superalloy. The results of the isothermal oxidation test at 1 150 ℃ for 100 h show that the oxidation tendency obeys the parabolic law, and the oxidation rate constant Kp of the coated specimens decreases to about 1/3 of that for the bare superalloy. After oxidation, a continuous alumina-based scale is formed at the surfaces of the coated samples. Y2O3, NiO and SiO2 are also detectable in the oxide scale. A large number of Al in the coating is consumed due to high-temperature diffusion and oxidation reactions, and the NiAl phases in the coating are almost completely transformed to Ni3Al phases. For the Hf-bearing coating, some HfO2 particles exist at the interface between the coating and the substrate. Although internal oxidation occurs, the coating still shows a good adhesion with the superalloy substrate even after oxidation for 100 h. For the bare DS superalloy, after 100 h oxidation at 1 150 ℃, only discontinuous alumina-based oxide particles exist on the surface. Oxide spallation occurs for the bare alloy.

  5. Lecture notes on 2-dimensional defect TQFT

    CERN Document Server

    Carqueville, Nils

    2016-01-01

    These notes offer an introduction to the functorial and algebraic description of 2-dimensional topological quantum field theories `with defects', assuming only superficial familiarity with closed TQFTs in terms of commutative Frobenius algebras. The generalisation of this relation is a construction of pivotal 2-categories from defect TQFTs. We review this construction in detail, flanked by a range of examples. Furthermore we explain how open/closed TQFTs are equivalent to Calabi-Yau categories and the Cardy condition, and how to extract such data from pivotal 2-categories.

  6. Notes on quantum groups

    Energy Technology Data Exchange (ETDEWEB)

    Pressley, A.; Chari, V. (King' s Coll., London (UK). Dept. of Mathematics Tata Inst. of Fundamental Research, Bombay (India). School of Mathematics)

    1990-12-01

    The authors presents an introduction to quantum groups defined as a deformation of the universal enveloping algebra of a Lie algebra. After the description of Hopf algebras with some examples the approach of Drinfel'd and Jimbo is described, where the quantization of a Lie algebra represents a Hopf algebra, defined over the algebra of formal power series in an indetermined h. The authors show that this approach arises from a r-matrix, which satisfies the classical Yang-Baxter equation. As example quantum sl{sub 2} is considered. Furthermore the approaches of Manin and Woroniwicz and the R-matrix approach are described. (HSI).

  7. Experimental Design for Evaluation of Co-extruded Refractory Metal/Nickel Base Superalloy Joints

    Energy Technology Data Exchange (ETDEWEB)

    ME Petrichek

    2005-12-16

    a critical thickness (0.0005 in.). A diffusion barrier that exceeded this thickness would likely fail. The joint fabrication method must therefore mechanically bond the two materials causing little or no interdiffusion upon formation. Co-extrusion fits this description since it forms a mechanical joint between two materials by using heat and pressure. The two materials to be extruded are first assembled and sealed within a co-extrusion billet which is subsequently heated and then extruded through a die. For a production application, once the joint is formed, it is dejacketed to remove the outer canister. The remaining piece consists of two materials bonded together with a thin diffusion barrier. Therefore, the long-term stability of the joint is determined primarily by the kinetics of interdiffusion reaction between the two materials. An experimental design for co-extrusion of refractory metals and nickel-based superalloys was developed to evaluate this joining process and determine the long-term stability of the joints.

  8. Encoded Archival Description as a Halfway Technology

    Science.gov (United States)

    Dow, Elizabeth H.

    2009-01-01

    In the mid 1990s, Encoded Archival Description (EAD) appeared as a revolutionary technology for publishing archival finding aids on the Web. The author explores whether or not, given the advent of Web 2.0, the archival community should abandon EAD and look for something to replace it. (Contains 18 notes.)

  9. Effect of Re Addition and Withdrawal Rate on the Solidification Behavior of Directionally Solidified Superalloy AM3

    Institute of Scientific and Technical Information of China (English)

    F.Long; Y.S.Yoo; S.M.Seo; T.Jin; Z.Q.Hu; C.Y.Jo

    2011-01-01

    The influence of Re addition and withdrawal rate on the solidification behavior of the first generation single crystal superalloy AM3 was investigated by directional solidification and quenching experiments. The primary dendrite arm spacing and eutectic volume fraction were measured from directionally solidified superalloy AM3 with different Re contents. It is found that the primary dendrite arm spacing is determined by the withdrawal rate, and Re does not influence on the value. The eutectic fraction increases with increasing Re addition. Partition coefficients of alloying elements were investigated with energy-dispersive X-ray spectrometry (EDS) analysis. The data was submitted to a statistical treatment to establish the solidification path, and the partition coefficients were measured by fitting the curve with a modified Scheil formula. It is shown that the addition of Re results in bigger microsegregation of alloying elements in directionally solidified AM3 superalloy.

  10. Evaluation of hot corrosion behaviour of HVOF sprayed NiCrAl coating on superalloys at 900 deg. C

    Energy Technology Data Exchange (ETDEWEB)

    Mahesh, R.A. [Department of Metallurgical and Materials Engineering, Indian Institute of Technology Roorkee, IIT Roorkee Campus, Roorkee 247667, Uttarakhand (India); Jayaganthan, R. [Department of Metallurgical and Materials Engineering, Indian Institute of Technology Roorkee, IIT Roorkee Campus, Roorkee 247667, Uttarakhand (India)], E-mail: rjayafmt@iitr.ernet.in; Prakash, S. [Department of Metallurgical and Materials Engineering, Indian Institute of Technology Roorkee, IIT Roorkee Campus, Roorkee 247667, Uttarakhand (India)

    2008-10-15

    In the present investigation, NiCrAl coating was deposited on Ni- and Fe-based superalloy substrates by using high velocity oxy-fuel (HVOF) process to study the hot corrosion behaviour in molten salt (Na{sub 2}SO{sub 4}-60% V{sub 2}O{sub 5}) environment at 900 deg. C under cyclic conditions. The mass gain measurements were performed after each cycle to establish the kinetics of corrosion using thermogravimetric technique. X-ray diffraction (XRD), scanning electron microscopy/energy dispersive spectroscopic analysis (SEM/EDS) and X-ray mapping techniques were used to analyse the corrosion products. The bare superalloys experienced higher weight gain. The NiCrAl-coated Superni 750 alloy (SN 750) provided a better protection among the coated superalloys investigated. The formation of oxides and spinels of nickel, chromium and aluminum may be contributing better resistance to hot corrosion.

  11. High-Temperature Oxidation Behavior of Two Nickel-Based Superalloys Produced by Metal Injection Molding for Aero Engine Applications

    Science.gov (United States)

    Albert, Benedikt; Völkl, Rainer; Glatzel, Uwe

    2014-09-01

    For different high-temperature applications like aero engines or turbochargers, metal injection molding (MIM) of superalloys is an interesting processing alternative. For operation at high temperatures, oxidation behavior of superalloys produced by MIM needs to match the standard of cast or forged material. The oxidation behavior of nickel-based superalloys Inconel 713 and MAR-M247 in the temperature interval from 1073 K to 1373 K (800 °C to 1100 °C) is investigated and compared to cast material. Weight gain is measured discontinuously at different oxidation temperatures and times. Analysis of oxidized samples is done via SEM and EDX-measurements. MIM samples exhibit homogeneous oxide layers with a thickness up to 4 µm. After processing by MIM, Inconel 713 exhibits lower weight gain and thinner oxide layers than MAR-M247.

  12. Note e Recensioni

    Directory of Open Access Journals (Sweden)

    a cura di Mariagrazia Portera

    2013-12-01

    Full Text Available Volumi Winfried Menninghaus, La promessa della bellezza, [Fabrizio Desideri, p. 272] • David Rothenberg, Survival of the Beautiful. Art, Science and Evolution [Danae Crocchiola, p. 274] • Lev Manovich, Software Takes Command [Angela Maiello, p. 277]. Note Method in Aesthetics: Philosophy, Evolution and the Cognitive Sciences [Aaron Meskin, Matthew Kieran, Gregory Currie, p. 280] • L’Abitare possibile. Estetica, Architettura e New Media, Ravello, Auditorium Oscar Niemeyer, 28-30 maggio 2013 [Sara Matetich, p. 282] • Copenhagen Summer School in Phenomenology and Philosophy of Mind, University of Copenhagen, 12-16 Agosto 2013 [Raoul Frauenfelder, p. 289] • Ciò che è vivo e ciò che è morto nell’estetica di Archibald Ali- son. Nota a margine del convegno: Neoestetica ed emozione. Archibald Alison e l’estetica con- temporanea, Palermo, 4-5 ottobre 2013 [Giuseppe Pucci, p. 294

  13. The mechanisms and temperature dependence of superlattice stacking fault formation in the single-crystal superalloy PWA 1480

    Science.gov (United States)

    Milligan, Walter W.; Antolovich, Stephen D.

    1991-01-01

    The mechanism of the formation of superlattice staking faults in the single-crystal nickel-base superalloy PWA 1480 was investigated by observing deformation microstructures in the superalloy single crystals in the temperature range 20-1100 C. Results showed that, in addition to superlattice stacking faults observed after slow strain rate deformation at temperatures from 700 to 950 C, a high-density of superlattice staking faults formed after deformation at 200 C and below. The mechanisms of fault formation, which are different in the high- and the low-temperature regimes, are discussed.

  14. Solidification Behavior and Segregation of Re-containing Cast Ni-base Superalloy with Different Cr Content

    Institute of Scientific and Technical Information of China (English)

    Xiurong Guan; Enze Liu; Zhi Zheng; Yongsi Yu; Jian Tong; Yuchun Zhai

    2011-01-01

    The effect of chromium (Cr) on solidification and segregation behavior of Re-containing cast Ni-base superalloys was investigated by optical microscopy (OM), scanning electron microscopy (SEM) and electronic probe micro analysis (EPMA). The results show that Cr has significant effect on solidification and segregation behavior of Re-containing cast Ni-base superalloys. The liquidus and solidus of alloy decrease with increasing Cr in alloys. The segregation coefficient (K) of Mo increases and that of W and Re decreases gradually with increasing Cr element.

  15. The hot-deformability and quantitative description of the microstructure of hot-deformed Fe-Ni superalloy

    Energy Technology Data Exchange (ETDEWEB)

    Ducki, K J; Rodak, K, E-mail: kazimierz.ducki@polsl.pl [Department of Materials Science, Silesian University of Technology, Krasinskiego 8, 40-019 Katowice (Poland)

    2011-05-15

    The paper presents the results of research concerning the influence of hot plastic forming parameters on the deformability and structure of a Fe-Ni austenitic alloy. The research was performed on a torsion plastometer in the range of temperatures of 900-1150 deg. C, at a strain rate 0.1 and 1.0 s{sup -1}. Plastic properties of the alloy were characterized by the worked out flow curves and the temperature relationships of flow stress and strain limit. The structural inspections were performed on microsections taken from plastometric samples after so called {sup f}reezing{sup .} The stereological parameters as the recrystallized grain size, inhomogenity and grain shape have been determined. Functional relations between the Zener-Hollomon parameter and the peak stress and the mean grain size have been developed and the activation energy of the hot plastic deformation has been estimated. The examination of substructure on TEM allowed the calculation of structural parameters: the average subgrain area and the mean dislocation density. A detailed investigation has shown that the substructure is inhomogeneous, consists of dense dislocation walls, subgrains and recrystallized regions.

  16. 3-sheet structure of Inconel 718 superalloy processed by LBW/SPF and its load response

    Institute of Scientific and Technical Information of China (English)

    2009-01-01

    The 3-sheet structure of Inconel 718 superalloy will be used in flying vehicles as heat resisting and shielding structure due to its lightweight, high strength and stiffness. The 3-sheet structure of Inconel 718 superalloy processed by LBW/SPF (laser beam welding/superplastic forming) technology exhibited good configuration and uniform thickness distribution. The LBW parameters for 3-sheet structure were as follows: Pulse frequency was 32 Hz, impulse duration 3 ms, peak power per pulse 4500 W, and welding speed 180 mm/min. The SPF parameters were as follows: Temperature T=965 ℃, forming pressure P=4.2 MPa, and forming time t=130 min. The microstructure in weld fusion zone was consti- tuted of austenite dendritics and Laves phase precipitated in interdendritics. After the SPF process, austenite dendritics in the weld fusion became coarser and most of Laves phases were dissolved and turned into δ precipitated phase, but a few of Laves phases were still reserved. And Nb concentration in dendritics increased to 5.42% compared to 2.82% in as-weld condition. Weld metal Vickers-hardness increased from 331.63 in as-weld condition to 391.74 in post-SPF condition which was closed to the base material Vickers-hardness of post-SPF. Grain size of base material grew slightly and an amount of precipitated phase appeared in the base material undergoing SPF process. The tensile test results of base material showed that tensile strength increased obviously and the ductility decreased slightly after SPF process. Load response test results indicated that the 3-sheet structure possessed good resistance to compression and bending load. Accordingly, the LBW/SPF technology is an appropriate forming technique for the 3-sheet structure of Inconel 718 superalloy.

  17. 3-sheet structure of Inconel 718 superalloy processed by LBW/SPF and its load response

    Institute of Scientific and Technical Information of China (English)

    QU FengSeng; ZHANG KaiFeng

    2009-01-01

    The 3-sheet structure of Inconel 718 superalloy will be used in flying vehicles as heat resisting and shielding structure due to its lightweight,high strength and stiffness.The 3-sheet structure of Inconel 718 superalloy processed by LBW/SPF(laser beam welding/superplastic forming)technology exhibited good configuration and uniform thickness distribution.The LBW parameters for 3-sheet structure were as follows:Pulse frequency was 32 Hz,impulse duration 3 ms,peak power per pulse 4500 W,and welding speed 180 mm/min.The SPF parameters were as follows:Temperature T=965℃,forming pressure P=-4.2 MPa,and forming time t=130 min.The microstructure in weld fusion zone was constituted of austenite dendritics and Laves phase precipitated in interdendritics.After the SPF process,austenite dendritics in the weld fusion became coarser and most of Laves phases were dissolved and turned into δprecipitated phase,but a few of Laves phases were still reserved.And Nb concentration in dendritics increased to 5.42% compared to 2.82% in as-weld condition.Weld metal Vickers-hardness increased from 331.63 in as-weld condition to 391.74 in post-SPF condition which was closed to the base material Vickers-hardness of post-SPF.Grain size of base material grew slightly and an amount of precipitated phase appeared in the base material undergoing SPF process.The tensile test results of base material showed that tensile strength increased obviously and the ductility decreased slightly after SPF process.Load response test results indicated that the 3-sheet structure possessed good resistance to compression and bending load.Accordingly,the LBW/SPF technology is an appropriate forming technique for the 3-sheet structure of inconel 718 superalloy.

  18. Notes for Contributors

    Institute of Scientific and Technical Information of China (English)

    2012-01-01

    The Chinese Journal of Chemical Engineering is the official journal of the Chemical Industry and Engineering Society of China and published by the Chemical Industry Press. The aim of the journal is to develop the international exchange of scientific and technical information in the field of chemical engineering. Submission of Papers All papers will be submitted on line, http://www.cjche.com.cn Conditions of Publication It is a condition of publication that manuscripts submitted to CJChE have not been published and will not be submitted or published elsewhere in English or any other language, without the written consent of the publisher. All manuscripts are reviewed by referees and the decision to accept them for publication is made by the editors. Authors are solely respon- sible for the accuracy and suitability of their contributions. Types of Contribution All manuscripts with significant research results in the areas of chemi- cal engineering and its application are welcome. Four types of papers appear in this journal: Re- search Papers, Research Notes, Reviews and Perspectives. All papers will class according to subject: (1) Fluid Dynamics and Transport Phenomena; (2) Separation Science and Engineering; (3) Catalysis, Kinetics and Reaction Engineering; (4) Process Systems Engineering and Process Safety; (5) Chemical Engineering Thermodynamics; (6) Bio- technology and Bioengineering; (7) Energy, Resources and Environmental Technology; (8) Mate- rials and Product Engineering.

  19. Comparison of measured and calculated thermophysical properties of nickel super-alloys

    Directory of Open Access Journals (Sweden)

    A. Kalup

    2016-07-01

    Full Text Available Three real grades of nickel super-alloys (IN 713LC, IN 738LC and IN 792-5A were investigated and values of temperatures of phase transformations and latent heats of melting were obtained. All investigated quantities are very important for thermodynamic and kinetic modelling. Moreover, these data are also valuable for a lot of software used for technological processes modelling. Experimental values were obtained using Differential Thermal Analysis (DTA measurements. Calculations were performed using Thermo-Calc 3.1 software with the use of three different databases (SSOL5, TTNI8 and TCNI6. Comparison and discussion of experimental and calculated data was performed.

  20. Processing and characterization of Nickel-base superalloy micro-components and films for MEMS applications

    Science.gov (United States)

    Burns, Devin E.

    Microelectromechanical (MEMS) devices are not capable of withstanding harsh operating environments, which may include high temperatures, pressures and corrosive agents. Ni-base superalloys have been used successfully in the hot stages of jet turbine engines despite the presence of these conditions. In my thesis work, I developed two techniques compatible with micro-processing methods to produce Ni-base superalloy micro-components for MEMS applications. The mechanical properties of these materials were accessed at room and elevated temperatures. Microstructural studies were performed, linking microstructural features to mechanical properties. The first technique modified LIGA Ni (LIGA is a German acronym for lithography, electroplating and molding) microtensile specimens using a vapor phase aluminization process. A subsequent homogenization heat treatment produced a two phase Ni-Ni3A1 microstructure characteristic of modern Ni-base superalloys. Al composition was used to tailor both the precipitate size and volume fraction. Aluminized LIGA Ni micro-components exhibited room temperature yield and ultimate strengths 3 to 4 times LIGA Ni micro-components subject to the same heat treatment. The second technique involved sputtering a commercial Ni-base superalloy, Haynes 718, to produce thick sputtered foils (up to 20 gam) on silicon and brass substrates. The as-deposited foils were nanocrystalline solid solutions with chemical compositions similar to the bulk material. Foils subject to ageing heat treatments exhibited unique precipitation mechanisms and good thermal stability. Strengths as high as 750 MPa at 700°C were observed with several percent ductility. This is a significant improvement over state of the art metallic MEMS materials. Furthermore, a new high temperature microtensile testing technique was developed. The technique embeds a displacement based force sensor into the hot zone of a furnace. This arrangement ensures temperature uniformity during testing

  1. Nucleation mechanisms of dynamic recrystallization in Inconel 625 superalloy deformed with different strain rates

    Institute of Scientific and Technical Information of China (English)

    2012-01-01

    The effects of strain rates on the hot working characteristics and nucleation mechanisms of dynamic recrystallization (DRX) were studied by optical microscopy and electron backscatter diffraction (EBSD) technique. Hot compression tests were conducted using a Gleeble-1500 simulator at a true strain of 0.7 in the temperature range of 1000 to 1150 °C and strain rate range of 0.01 to 10.00 s-1. It is found that the size and volume fraction of the DRX grains in hot-deformed Inconel 625 superalloy firstly decreas...

  2. Effects of recrystallization on the low cycle fatigue behavior of directionally solidified superalloy DZ40M

    Institute of Scientific and Technical Information of China (English)

    ZHAO Yang; WANG Lei; LI Hongyun; YU Teng; LIU Yang

    2008-01-01

    The effects of recrystallization on low cycle fatigue behavior were investigated on directionally solidified Co-base superalloy DZAOM.Optical microscopy and SEM were used to examine the mierostructure and fracture surface of the specimens.The mechanical testing results demonstrated that the low cycle fatigue property of DZ40M significantly decreased with the partial reerystallization.Fatigue cracks initiate near the carbides and the grain boundaries with slip-bands.Both the fatigue crack initiation and propagation can be accelerated with the occurrences of recrystallized grain boundaries.

  3. Nucleation mechanism of a nickel-base superalloy during dynamic recrystallization

    Institute of Scientific and Technical Information of China (English)

    Shuai WANG; Lei WANG; Yang LIU; Guohua XU; Beijiang ZHANG; Guangpu ZHAO

    2011-01-01

    Hot compression test was carried out at 1000 ℃ to investigate the dynamic recrystallization nucleation mechanism of a nickel-base superalloy.It was found that the bulging of original grain boundaries was inhibited by carbides and deformation twins at the boundaries.Recrystallized nuclei evolved from the subgrains of dislocation reconfiguration along original grain boundaries,and the growth of the potential nuclei was carried out by the coalescence of subgrains.The necklace structure of recrystallized grains along original grain boundaries was attributed to the strain gradient from grain boundary to grain interior.

  4. Computational Design of Creep-Resistant Alloys and Experimental Validation in Ferritic Superalloys

    Energy Technology Data Exchange (ETDEWEB)

    Liaw, Peter

    2014-12-31

    A new class of ferritic superalloys containing B2-type zones inside parent L21-type precipitates in a disordered solid-solution matrix, also known as a hierarchical-precipitate strengthened ferritic alloy (HPSFA), has been developed for high-temperature structural applications in fossil-energy power plants. These alloys were designed by the addition of the Ti element into a previously-studied NiAl-strengthened ferritic alloy (denoted as FBB8 in this study). In the present research, systematic investigations, including advanced experimental techniques, first-principles calculations, and numerical simulations, have been integrated and conducted to characterize the complex microstructures and excellent creep resistance of HPSFAs. The experimental techniques include transmission-electron microscopy, scanningtransmission- electron microscopy, neutron diffraction, and atom-probe tomography, which provide detailed microstructural information of HPSFAs. Systematic tension/compression creep tests revealed that HPSFAs exhibit the superior creep resistance, compared with the FBB8 and conventional ferritic steels (i.e., the creep rates of HPSFAs are about 4 orders of magnitude slower than the FBB8 and conventional ferritic steels.) First-principles calculations include interfacial free energies, anti-phase boundary (APB) free energies, elastic constants, and impurity diffusivities in Fe. Combined with kinetic Monte- Carlo simulations of interdiffusion coefficients, and the integration of computational thermodynamics and kinetics, these calculations provide great understanding of thermodynamic and mechanical properties of HPSFAs. In addition to the systematic experimental approach and first-principles calculations, a series of numerical tools and algorithms, which assist in the optimization of creep properties of ferritic superalloys, are utilized and developed. These numerical simulation results are compared with the available experimental data and previous first

  5. Phase transformation and liquid density redistribution during solidification of Ni-based superalloy Inconel 718

    Directory of Open Access Journals (Sweden)

    Wang Ling

    2012-08-01

    Full Text Available The influences of chemical segregation and phase transformation on liquid density variation during solidification of Ni-based supperalloy Inconel 718 were investigated using SEM and EDS. It was found that significant segregation in liquid prompts high Nb phase to precipitate directly from liquid, which results in the redistribution of alloy elements and liquid density in their vicinity. The term “inter-precipitate liquid density” is therefore proposed and this concept should be applied to determine the solidification behavior of superalloy Inconel 718.

  6. High Temperature Oxidation and Electrochemical Studies on Novel Co-Base Superalloys

    OpenAIRE

    Klein, Leonhard

    2013-01-01

    Isothermal oxidation in air was carried out on novel γ'-strengthened Cobalt-base superalloys of the system Co–Al–W–B. After fast initial oxide formation, a multi-layered structure establishes, consisting of an outer cobalt oxide layer, a middle spinel-containing layer, and an inner Al2O3-rich region. Ion diffusion in outward direction is hindered by the development of Al2O3, that can be either present as a continuous and protective layer or as a discontinuous Al2O3-rich area without comparabl...

  7. Analysis of the solidified structure of rheocast and VADER processed nickel-base superalloy

    Science.gov (United States)

    Apelian, D.; Cheng, J.-J. A.

    1986-01-01

    Conventional 'ingot' processing of highly alloyed compositions results in a cast product which suffers from extensive macrosegregation, hot tears, and heterogeneities. By controlling the solidification journey, one can produce a fine grained cast product. This is achieved by manipulating the melt in the mushy zone. Rheocasting and vacuum arc double electrode remelting (VADER) are two such technologies where the melt is processed in the mushy zone. IN-100, a nickel based superalloy, was rheocast as well as VADER processed. The resultant cast structures are analyzed, compared and discussed both onmicro- and macrostructural levels. The effect of the rheocast processing variables (stirring seed, time and temperature) on the cast microstructure are also discussed.

  8. Precipitation in Powder Metallurgy, Nickel Base Superalloys: Review of Modeling Approach and Formulation of Engineering (Postprint)

    Science.gov (United States)

    2016-12-01

    such as those of interest here, the work of Campbell et al. [60] and Semiatin et al. [50] suggests that Cr diffusion is rate limiting in γ-γ...the work of Campbell et al. [60]. In addition, w(f ) was taken from the research of Voorhees and Glicksman [20], and σ was assumed to be 23 mJ/m2 per...2104) Alloying-element loss during high-temperature processing of a nickel-base superalloy. Metall Mater Trans A 45:962–979 60. Campbell CE, Zhao JC

  9. Creep, Fatigue and Environmental Interactions and Their Effect on Crack Growth in Superalloys

    Science.gov (United States)

    Telesman, J.; Gabb, T. P.; Ghosn, L. J.; Smith, T.

    2017-01-01

    Complex interactions of creep/fatigue/environment control dwell fatigue crack growth (DFCG) in superalloys. Crack tip stress relaxation during dwells significantly changes the crack driving force and influence DFCG. Linear Elastic Fracture Mechanics, Kmax, parameter unsuitable for correlating DFCG behavior due to extensive visco-plastic deformation. Magnitude of remaining crack tip axial stresses controls DFCG resistance due to the brittle-intergranular nature of the crack growth process. Proposed a new empirical parameter, Ksrf, which incorporates visco-plastic evolution of the magnitude of remaining crack tip stresses. Previous work performed at 704C, extend the work to 760C.

  10. Metallurgical instabilities during the high temperature low cycle fatigue of nickel-base superalloys

    Science.gov (United States)

    Antolovich, S. D.; Jayaraman, N.

    1983-01-01

    An investigation is made of the microstructural instabilities that affect the high temperature low cycle fatigue (LCF) life of nickel-base superalloys. Crack initiation processes, provoked by the formation of carbides and the coarsening of the grains of the material at high temperatures are discussed. Experimental results are examined, and it is concluded that LCF behavior can be understood more fully only if details of the material and its dynamic behavior at high temperatures are considered. The effects of high stress, dislocation debris, and increasing environmental damage on the life of the alloy are discussed.

  11. Effects of secondary precipitation on recrystallization in Co-base superalloy DZ40M

    Institute of Scientific and Technical Information of China (English)

    ZHAO Yang; WANG Lei; YU Teng; SONG Xiu

    2006-01-01

    A series of experimental studies were conducted on the recrystallization of directionally solidified cobalt-base superalloy DZ40M. It is found that the secondary M23C6 precipitation influences the size and shape of the recrystal grains. When the annealing temperature is below 1 473 K, a large amount of the fine secondary M23C6 precipitations are distributed around the primary carbides, and such carbides impede the movement of grain boundary because the effect, the size and shape of recrystal grains become irregularly. When the temperature exceeds 1 473 K, the recrystal grains grow rapidly due to the dissolved secondary M23C6 precipitation.

  12. Surface Modification Concepts for Enhancement of the High-Temperature Corrosion Resistance of Gas Turbine Superalloys,

    Science.gov (United States)

    1980-12-01

    in the Marine Environment, 1974, NTIS-MCIC-75-27. 23. Restall , J.E., Metallurgia, 1979, Nov., 676. 24. Coward, G.W. and Boone, D.H., Oxidation of...J.C. and Ault, G.M., 3rd Int. Symposium on Superalloys; Metall. and Manufacture, 1976, AIHE. 31. Restall , J.E., Institute of Metals/CAPA/ICT...a function of time for various alloys and coatings (after Restall [23]). TEMPERATURE, 0C 300 400 600 800 1000 A K =C(Ni) X P12 /C(NiQ0) 10-20 ED E N0

  13. Analysis of Grain Boundary Character in a Fine-Grained Nickel-Based Superalloy 718

    Science.gov (United States)

    Araujo, L. S.; dos Santos, D. S.; Godet, S.; Dille, J.; Pinto, A. L.; de Almeida, L. H.

    2014-11-01

    In the current work, sheets of superalloy 718 were processed via thermomechanical route by hot and cold rolling, followed by annealing below the δ phase solvus temperature and precipitation hardening to optimum strength. Grain boundary character distribution throughout the processing was mapped via EBSD and its evolution discussed. The results show that it is possible to process the alloy to a fine grain size obtaining concomitantly a considerably high proportion of special boundaries Σ3, Σ9, and Σ27. The precipitation of δ phase presented a strong grain refining role, without significantly impairing the twinning mechanism and, consequently, the Σ3, Σ9, and Σ27 boundary formations.

  14. Preparation, Structure and Mechanical Properties of Nickel Based Porous Spherical Superalloy

    Institute of Scientific and Technical Information of China (English)

    MI Guo-fa; LI Hong-yu; LIU Xiang-yu; WANG Kuang-fei

    2009-01-01

    The porous superalloy materials with hollow spherical pores were fabricated by using metal powder sintering process.The scanning electron microscope (SEM) observation was applied to the test samples and it revealed that the pores of the porous material exhibited a uniform distribution and the apet;tures were of same size in principle.The sintering necks appeared between adjacent particles on metal skeleton after sintering.The mechanical properties of the test samples were analyzed and the result showed that this kind of materials possessed excellent energy absorption capability,and the compression resistance decreased with increasing the porosity and aperture.

  15. Numerical Simulation of Vacuum Heat Treatment Thermal Hysteresis Time of GH4169 Superalloy Workpiece

    Institute of Scientific and Technical Information of China (English)

    WANGMing-wei; ZHANGLi-wen; JIANGGuo-dong; ZHANGFan-yun; LiChen-hui; ZHANGLi-sheng; ZHANGZun-li

    2004-01-01

    A nonlinear finite element model of vacuum heat treatment process was developed. In this model, influence of many factors, such as nonlinear heat radiation, temperature-dependent thermal physical properties of material are considered. The temperature field of GH4169 alloy workpiece during vacuum heat treatment process was calculated using finite element software MSC.Marc, and the thermal hysteresis time of the workpiece was predicted. An experiment of vacuum heat treatment of GH4169 superalloy workpiece was carried out to verify the calculation. The experimental results of temperature profile agree well with the simulated results. This work lays a theoretical foundation for optimizing technical parameter of vacuum heat treatment process.

  16. Homogenization kinetics of a nickel-based superalloy produced by powder bed fusion laser sintering

    Energy Technology Data Exchange (ETDEWEB)

    Zhang, Fan; Levine, Lyle E.; Allen, Andrew J.; Campbell, Carelyn E.; Lass, Eric A.; Cheruvathur, Sudha; Stoudt, Mark R.; Williams, Maureen E.; Idell, Yaakov

    2017-04-01

    Additively manufactured (AM) metal components often exhibit fine dendritic microstructures and elemental segregation due to the initial rapid solidification and subsequent melting and cooling during the build process, which without homogenization would adversely affect materials performance. In this letter, we report in situ observation of the homogenization kinetics of an AM nickel-based superalloy using synchrotron small angle X-ray scattering. The identified kinetic time scale is in good agreement with thermodynamic diffusion simulation predictions using microstructural dimensions acquired by ex situ scanning electron microscopy. These findings could serve as a recipe for predicting, observing, and validating homogenization treatments in AM materials.

  17. Primary and secondary dendrite spacing of Ni-based superalloy single crystals

    Directory of Open Access Journals (Sweden)

    SLOBODANKA KOSTIC

    2009-01-01

    Full Text Available Ni-based superalloy single crystals were grown by different methods (gradient method and Bridgman technique with spontaneous nucleation and with seed. In all crystal growth experiments using the Bridgman technique, the temperature gradient along the vertical furnace axes was constant (G = 33.5 °C/cm. The obtained single crystals were cut, mechanical and chemical polished, and chemically etched. Using a metallographic microscope, the spacing of the primary and secondary dendrites was investigated. The dendrite arm spacing (DAS was determined using a Quantimet 500 MC. The obtained results are discussed and compared with published data.

  18. Inertia Friction Welding of Dissimilar Superalloys Mar-M247 and LSHR

    Science.gov (United States)

    Senkov, Oleg N.; Mahaffey, David W.; Semiatin, S. Lee; Woodward, Christopher

    2014-11-01

    The solid state inertia friction welding (IFW) process was used for the first time to join two dissimilar Ni-based superalloys, LSHR, a powder metallurgy alloy, and Mar-M247, a directionally solidified alloy. Extensive studies of the microstructure, phase composition, re-distribution of the alloying elements between the welded alloys, microhardness, and welding defects were conducted at different distances from the weld interface, and the results were correlated with the loading and friction conditions during IFW. Possible reasons leading to the formation of the welding defects were discussed and directions for the further improvement of the quality of the IFW of these two dissimilar alloys were outlined.

  19. Characterization of Casting Defects in Typical Castings of a Directionally Solidified Superalloy

    Science.gov (United States)

    1979-08-01

    used to evaluate grain misorientation effects in D.S. MAR - M247 superalloy (17). Scatter of this nature has been observed previously in equiaxed cast...found associated with the fracture surfaces In the previous study on tje effect of off-axis grain growth on cylindrical cast bars of D.S. MAR - M247 , 1800...significant that no instances of failures associated with emergent grains were observed in the MAR - M247 study. In the present investigation of PWA 1422, no

  20. Evaluation of Heat Checking and Washout of Heat Resistant Superalloys and Coatings for Die inserts

    Energy Technology Data Exchange (ETDEWEB)

    David Schwam; John F. Wallace; Yulong Zhu; Edward Courtright; Harold Adkins

    2005-01-30

    This project had two main objectives: (1) To design, fabricate and run a full size test for evaluating soldering and washout in die insert materials. This test utilizes the unique capabilities of the 350 Ton Squeeze Casting machine available in the Case Meal Casting Laboratory. Apply the test to evaluate resistance of die materials and coating, including heat resistant alloys to soldering and washout damage. (2) To evaluate materials and coatings, including heat resistant superalloys, for use as inserts in die casting of aluminum alloys.

  1. Investigation of delamination mechanisms during a laser drilling on a cobalt-base superalloy

    OpenAIRE

    Girardot, Jérémie; Schneider, Matthieu; Berthe, Laurent; FAVIER, Véronique

    2013-01-01

    International audience; Temperatures in the high pressure chamber of aircraft engines are continuously increasing to improve the engine efficiency. As a result, constitutive materials such as cobalt and nickel-base superalloys need to be thermally protected. The first protection is a ceramic thermal barrier coating (TBC) cast on all the hot gas-exposed structure. The second protection is provided by a cool air layer realized by the use of a thousand of drills on the parts where a cool air is flo...

  2. Notes on Musa rubra Kurz (Musaceae and reduction of M. laterita Cheesman as conspecific

    Directory of Open Access Journals (Sweden)

    Alfred Joe

    2016-03-01

    Full Text Available Notes on taxonomic identity and history of M. rubra is provided and lectotype is designated here. Detailed description, photographs and illustration are provided for easy identification. M. laterita is treated as conspecific to M. rubra.

  3. Calculation notes that support accident scenario and consequence of the evaporator dump

    Energy Technology Data Exchange (ETDEWEB)

    Crowe, R.D., Westinghouse Hanford

    1996-09-09

    The purpose of this calculation note is to provide the basis for evaporator dump consequence for the Tank Farm Safety Analysis Report (FSAR). Evaporator Dump scenario is developed and details and description of the analysis methods are provided.

  4. Cobalt-based superalloy layers deposited on X38CrMoV5 steel base metal by explosion cladding process

    OpenAIRE

    Langlois, Laurent; Bigot, Régis; ETTAQI, Saïd

    2008-01-01

    International audience; A grade 25 cobalt-based superalloy in the form of a sheet 5 mm in thickness and a steel substrate of type X38CrMoV5 are joined by explosion cladding. The macrostructure and microstructure of the interface and of the co-based superalloy layers are studied. The interface presents the form of wavelets with a period of 1000 µm and an amplitude of 250 µm. The superalloy grains are deformed during the cladding process with several slip systems appearing. Near to the interfac...

  5. Online Class Size, Note Reading, Note Writing and Collaborative Discourse

    Science.gov (United States)

    Qiu, Mingzhu; Hewitt, Jim; Brett, Clare

    2012-01-01

    Researchers have long recognized class size as affecting students' performance in face-to-face contexts. However, few studies have examined the effects of class size on exact reading and writing loads in online graduate-level courses. This mixed-methods study examined relationships among class size, note reading, note writing, and collaborative…

  6. Notes in Colombian Herpetology, II Notes in Colombian Herpetology, II

    Directory of Open Access Journals (Sweden)

    Dunn Emmett Reid

    1944-03-01

    Full Text Available The Lizard Genus Echinosaura (Teiidae in Colombia / Notes on the habits of the Tadpole-Carrying Frog Hyloxalus granuliventris / A New Marsupian Frog (Gastrotheca from Colombia The Lizard Genus Echinosaura (Teiidae in Colombia / Notes on the habits of the Tadpole-Carrying Frog Hyloxalus granuliventris / A New Marsupian Frog (Gastrotheca from Colombia.

  7. Online Class Size, Note Reading, Note Writing and Collaborative Discourse

    Science.gov (United States)

    Qiu, Mingzhu; Hewitt, Jim; Brett, Clare

    2012-01-01

    Researchers have long recognized class size as affecting students' performance in face-to-face contexts. However, few studies have examined the effects of class size on exact reading and writing loads in online graduate-level courses. This mixed-methods study examined relationships among class size, note reading, note writing, and collaborative…

  8. Effect of residual elements on high performance nickel base superalloys for gas turbines and strategies for manufacture

    Indian Academy of Sciences (India)

    O P Sinha; M Chatterjee; V V R S Sarma; S N Jha

    2005-07-01

    The need for better gas turbine operating efficiency and reliability has resulted in tightening of specification and acceptance standards. It has been realized that some elements even at trace level, can have disastrous effect on high temperature properties. The present paper highlights the adverse effect of tramp elements and strategies that should be adopted to produce high purity superalloys.

  9. Microstress evolution during in situ loading of a superalloy containing high volume fraction of {gamma}{sup '} phase

    Energy Technology Data Exchange (ETDEWEB)

    Ma, S.; Rangaswamy, P.; Majumdar, B.S

    2003-03-03

    Pulsed neutron diffraction under in situ mechanical loading was used to monitor microstrain evolution in individual phases of a polycrystalline {gamma}/{gamma}{sup '} superalloy, CM 247 LC. The load partitioning and yielding of differently oriented grains and phases were evaluated. The critical resolved shear stresses of individual phases were obtained and are compared with dislocation models.

  10. Hot corrosion resistance of high-velocity oxyfuel sprayed coatings on a nickel-base superalloy in molten salt environment

    Science.gov (United States)

    Sidhu, T. S.; Prakash, S.; Agrawal, R. D.

    2006-09-01

    No alloy is immune to hot corrosion attack indefinitely. Coatings can extend the lives of substrate materials used at higher temperatures in corrosive environments by forming protective oxides layers that are reasonably effective for long-term applications. This article is concerned with studying the performance of high-velocity oxyfuel (HVOF) sprayed NiCrBSi, Cr3C2-NiCr, Ni-20Cr, and Stellite-6 coatings on a nickel-base superalloy at 900 °C in the molten salt (Na2SO4-60% V2O5) environment under cyclic oxidation conditions. The thermogravimetric technique was used to establish kinetics of corrosion. Optical microscope, x-ray diffraction, scanning electron microscopy/electron dispersive analysis by x-ray (SEM/EDAX), and electron probe microanalysis (EPMA) techniques were used to characterize the as-sprayed coatings and corrosion products. The bare superalloy suffered somewhat accelerated corrosion in the given environmental conditions. whereas hot corrosion resistance of all the coated superalloys was found to be better. Among the coating studied, Ni-20Cr coated superalloy imparted maximum hot corrosion resistance, whereas Stellite-6 coated indicated minimum resistance. The hot corrosion resistance of all the coatings may be attributed to the formation of oxides and spinels of nickel, chromium, or cobalt.

  11. Modeling Long-term Creep Performance for Welded Nickel-base Superalloy Structures for Power Generation Systems

    Energy Technology Data Exchange (ETDEWEB)

    Shen, Chen [GE Global Research, NIskayuna, NY (United States); Gupta, Vipul [GE Global Research, NIskayuna, NY (United States); Huang, Shenyan [GE Global Research, NIskayuna, NY (United States); Soare, Monica [GE Global Research, NIskayuna, NY (United States); Zhao, Pengyang [GE Global Research, NIskayuna, NY (United States); Wang, Yunzhi [GE Global Research, NIskayuna, NY (United States)

    2017-02-28

    The goal of this project is to model long-term creep performance for nickel-base superalloy weldments in high temperature power generation systems. The project uses physics-based modeling methodologies and algorithms for predicting alloy properties in heterogeneous material structures. The modeling methodology will be demonstrated on a gas turbine combustor liner weldment of Haynes 282 precipitate-strengthened nickel-base superalloy. The major developments are: (1) microstructure-property relationships under creep conditions and microstructure characterization (2) modeling inhomogeneous microstructure in superalloy weld (3) modeling mesoscale plastic deformation in superalloy weld and (4) a constitutive creep model that accounts for weld and base metal microstructure and their long term evolution. The developed modeling technology is aimed to provide a more efficient and accurate assessment of a material’s long-term performance compared with current testing and extrapolation methods. This modeling technology will also accelerate development and qualification of new materials in advanced power generation systems. This document is a final technical report for the project, covering efforts conducted from October 2014 to December 2016.

  12. Grain Boundary Engineering of a Low Stacking Fault Energy Ni-based Superalloy

    Science.gov (United States)

    McCarley, Joshua; Helmink, Randolph; Goetz, Robert; Tin, Sammy

    2017-04-01

    The effects of thermo-mechanical processing parameters on the resulting microstructure of an experimental Nickel-based superalloy containing 24 wt pct Co were investigated. Hot compression tests were performed at temperatures ranging from 1293 K to 1373 K (1020 to 1100 °C) and strain rates ranging from 0.0005 to 0.1/s. The mechanically deformed samples were also subject to annealing treatments at sub-solvus 1388 K (1115 °C) and super-solvus 1413 K (1140 °C) temperatures. This investigation sought to quantify and subsequently understand the behavior and evolution of both the grain boundary structure and length fraction of Σ3 twin boundaries in the low stacking fault energy superalloy. Over the range of deformation parameters investigated, the corresponding deformation mechanism map revealed that dynamic recrystallization or dynamic recovery was dominant. These conditions largely promoted post-deformation grain refinement and the formation of annealing twins following annealing. Samples deformed at strain rates of 0.0005 and 0.001/s at 1333 K and 1373 K (1060 °C and 1100 °C) exhibited extensive grain boundary sliding/rotation associated with superplastic flow. Upon annealing, deformation conditions that resulted predominately in superplastic flow were found to provide negligible enhancement of twin boundaries and produced little to no post-deformation grain refinement.

  13. High-temperature γ (FCC/γ′ (L12 Co-Al-W based superalloys

    Directory of Open Access Journals (Sweden)

    Knop Matthias

    2014-01-01

    Full Text Available Interim results from the development of a polycrystalline Co-Al-W based superalloy are presented. Cr has been added to provide oxidation resistance and Ni has then been added to widen and stabilise the γ′ phase field. The alloy presented has a solvus of 1010 °C and a density of 8.7 g cm−3. The room temperature flow stress is over 1000 MPa and this reduces dramatically above 800 °C. The flow stress anomaly is observed. A microstructure with both ∼ 50 nm γ′ produced on cooling and larger 100–200 nm γ′ can be obtained. Isothermal oxidation at 800 °C in air for 200 h gave a mass gain of 0.96 mg cm−2. After hot deformation in the 650–850 °C temperature range, both anti phase boundaries (APBs and stacking faults could be observed. An APB energy of 71 mJ m−2 was measured, which is comparable to that found in commercial nickel superalloys.

  14. Processing maps for Fe–24Ni–11Cr–3Ti–1Mo superalloy

    Indian Academy of Sciences (India)

    Cai Dayong; Zhang Chunling; Tang Zhiguo; Dong Haifeng; Wang Peng

    2011-06-01

    Hot deformation characteristics of a Fe-base superalloy were studied at various temperatures from 1000–1200°C under strain rates from 0.001–1 s-1 using hot compression tests. Processing maps for hot working are developed on the basis of the variations of efficiency of power dissipation with temperature and strain rate and interpreted by a dynamic materials model. Hot deformation equation was given to characterize the dependence of peak stress on deformation temperature and strain rate. Hot deformation apparent activation energy of the Fe–24Ni–11Cr–1Mo–3Ti superalloy was determined to be about 499 kJ/mol. The processing maps obtained in a strain range of 0.1–0.7 were essentially similar, indicating that strain has no significant influence on it. The processing maps exhibited a clear domain with a maximum of about 40–48% at about 1150°C and 0.001 s-1.

  15. Grain Boundary Engineering of a Low Stacking Fault Energy Ni-based Superalloy

    Science.gov (United States)

    McCarley, Joshua; Helmink, Randolph; Goetz, Robert; Tin, Sammy

    2017-02-01

    The effects of thermo-mechanical processing parameters on the resulting microstructure of an experimental Nickel-based superalloy containing 24 wt pct Co were investigated. Hot compression tests were performed at temperatures ranging from 1293 K to 1373 K (1020 to 1100 °C) and strain rates ranging from 0.0005 to 0.1/s. The mechanically deformed samples were also subject to annealing treatments at sub-solvus 1388 K (1115 °C) and super-solvus 1413 K (1140 °C) temperatures. This investigation sought to quantify and subsequently understand the behavior and evolution of both the grain boundary structure and length fraction of Σ3 twin boundaries in the low stacking fault energy superalloy. Over the range of deformation parameters investigated, the corresponding deformation mechanism map revealed that dynamic recrystallization or dynamic recovery was dominant. These conditions largely promoted post-deformation grain refinement and the formation of annealing twins following annealing. Samples deformed at strain rates of 0.0005 and 0.001/s at 1333 K and 1373 K (1060 °C and 1100 °C) exhibited extensive grain boundary sliding/rotation associated with superplastic flow. Upon annealing, deformation conditions that resulted predominately in superplastic flow were found to provide negligible enhancement of twin boundaries and produced little to no post-deformation grain refinement.

  16. Structure property characterization of rheocast and VADER processed IN-100 superalloy

    Energy Technology Data Exchange (ETDEWEB)

    Cheng, J.J.A.

    1985-01-01

    Two recent solidification processes were applied in production of IN-100 nickel-base superalloy: rheocasting and Vacuum ARc Double Electrode Remelting (VADER). A high vacuum furnace for rheocasting superalloys was built and was used to rheocast ingots under different processing conditions. Processing variables evaluated include stirring speed, isothermal stirring time and volume fraction solid during isothermal stirring. VADER processed IN-100 was purchased from Special Metals Corp. As-cast ingots were subjected to various thermal treatments including hot isostatic pressing and heat treatment. As-cast and thermally treated materials were characterized using optical and scanning electron microscopy and microprobe analysis. Both rheocasting and VADER-processed materials yield fine and equiaxed spherical structures, where the extent of macrosegregation is lesser in comparison to conventionally produced ingot material. In rheocasting, the formation of nondendritic structures is discussed further on the basis of the model of dendrite arm fragmentation. At a constant cooling rate, the grain size and macrosegregation of the as-cast ingot is reduced by increasing the stirring speed, isothermal stirring time or the volume fraction solid during solidification, however, stirring speed has a more pronounced effect on grain refinement and macro-scale chemical homogeneity than the other two variables. The degree of the microsegregation decreases with increasing volume fraction solid and/or isothermal stirring time.

  17. Prediction of recrystallisation in single crystal nickel-based superalloys during investment casting

    Directory of Open Access Journals (Sweden)

    Panwisawas Chinnapat

    2014-01-01

    Full Text Available Production of gas turbines for jet propulsion and power generation requires the manufacture of turbine blades from single crystal nickel-based superalloys, most typically using investment casting. During the necessary subsequent solution heat treatment, the formation of recrystallised grains can occur. The introduction of grain boundaries into a single crystal component is potentially detrimental to performance, and therefore manufacturing processes and/or component geometries should be designed to prevent their occurrence. If the boundaries have very low strength, they can degrade the creep and fatigue properties. The root cause for recrystallisation is microscale plasticity caused by differential thermal contraction of metal, mould and core; when the plastic deformation is sufficiently large, recrystallisation takes place. In this work, numerical and thermo-mechanical modelling is carried out, with the aim of establishing computational methods by which recrystallisation during the heat treatment of single crystal nickel-based superalloys can be predicted and prevented prior to their occurrence. Elasto-plastic law is used to predict the plastic strain necessary for recrystallisation. The modelling result shows that recrystallisation is most likely to occur following 1.5–2.5% plastic strain applied at temperatures between 1000 ∘C and 1300 ∘C; this is validated with tensile tests at these elevated temperatures. This emphasises that high temperature deformation is more damaging than low temperature deformation.

  18. Effect of Ce+ Ion Implantation upon Oxidation Resistance of Superalloy K38G

    Institute of Scientific and Technical Information of China (English)

    Qian Yuhai; Li Meishuan; Duo Shuwang; Zhao Youming

    2005-01-01

    The oxidation behavior (isothermal and cyclic oxidation) of cast superalloy K38G and the effect of Ce+ ion implantation with dose of 1×1017 ions/cm2 upon its oxidation resistance at 900 and 1000 ℃ in air were investigated. Meanwhile, the influence of Ce+ implantation on oxidation behavior of K38G with pre-oxide scale at 1000 ℃ in air was compared. The pre-oxidation was performed at 1000 ℃ in static air for 0.25 and 1.5 h, respectively. It is shown that the homogeneous external mixture oxide of rutile TiO2+Cr2O3 and non-continuous internal oxide of Al2O3 are formed during the oxidation procedure in all the cases. The isothermal oxidation resistance and the cracking or spallation resistance of superalloy K38G implanted with Ce+ by both of the two different implantation ways are not improved notably. This may be attributed to the mixed oxide composition characteristics and the blocking effect differences of Ce+ segregation along the oxide grain boundaries on the transport process for different diffusing ions.

  19. High Temperature Degradation of Powder-processed Ni-based Superalloy

    Directory of Open Access Journals (Sweden)

    Natália Luptáková

    2015-05-01

    Full Text Available The aim of present work is to study the high temperature degradation of the powder-processed polycrystalline superalloy Ni-15Cr-18Co-4Al-3.5Ti-5Mo. This superalloy has been applied as material for grips of a creep machine. The material was exposed at 1100 °C for about 10 days at 10 MPa stress. During the creep test occurred unacceptable creep deformation of grips as well as severe surface oxidation with scales peeling off. Three types of the microstructure were observed in the studied alloy: (i unexposed state; (ii heat treated (annealing - 10 min/1200 °C and (iii after using as a part of the equipment of the creep machine during the creep test. It is shown that the microstructure degradation resulting from the revealed γ´ phase fcc Ni3(Al,Ti particles preferentially created at the grain boundaries of the samples after performing creep tests affects mechanical properties of the alloy and represents a significant contribution to all degradation processes affecting performance and service life of the creep machine grips. Based on investigation and obtained results, the given material is not recommended to be used for grips of creep machine at temperatures above 1000 °C.

  20. Enhancing the Oxidation Performance of Wrought Ni-Base Superalloy by Minor Additions of Active Elements

    Science.gov (United States)

    Tawancy, H. M.

    2016-12-01

    We show that the oxidation performance of Cr2O3-forming superalloy based upon the Ni-Cr-W system is significantly improved by the presence of minor concentrations of La, Si and Mn, which outweigh the detrimental effect of high W concentration in the alloy. Although Cr2O3 is known to transform into volatile CrO3 at temperatures ≥950 °C, the respective protection is extended to temperatures reaching 1150 °C, which has also been correlated with the beneficial effects of La, Si and Mn. During high-temperature oxidation, an inner protective La- and Si-modified layer of α-Cr2O3 in contact with the superalloy substrate is developed and shielded by an outermost layer of MnCr2O4. The distribution of La and Si in the inner oxide layer has been characterized down to the scale of transmission electron microscopy, and the possible mechanisms underlying their beneficial effects are elucidated.

  1. Fatigue Resistance of the Grain Size Transition Zone in a Dual Microstructure Superalloy Disk

    Science.gov (United States)

    Gabb, T. P.; Kantzos, P. T.; Telesman, J.; Gayda, J.; Sudbrack, C. K.; Palsa, B. S.

    2010-01-01

    Mechanical property requirements vary with location in nickel-based superalloy disks. To maximize the associated mechanical properties, heat treatment methods have been developed for producing tailored microstructures. In this study, a specialized heat treatment method was applied to produce varying grain microstructures from the bore to the rim portions of a powder metallurgy processed nickel-based superalloy disk. The bore of the contoured disk consisted of fine grains to maximize strength and fatigue resistance at lower temperatures. The rim microstructure of the disk consisted of coarse grains for maximum resistance to creep and dwell crack growth at high temperatures up to 704 C. However, the fatigue resistance of the grain size transition zone was unclear, and needed to be evaluated. This zone was located as a band in the disk web between the bore and rim. Specimens were extracted parallel and transverse to the transition zone, and multiple fatigue tests were performed at 427 and 704 C. Mean fatigue lives were lower at 427 C than for 704 C. Specimen failures often initiated at relatively large grains, which failed on crystallographic facets. Grain size distributions were characterized in the specimens, and related to the grains initiating failures as well as location within the transition zone. Fatigue life decreased with increasing maximum grain size. Correspondingly, mean fatigue resistance of the transition zone was slightly higher than that of the rim, but lower than that of the bore. The scatter in limited tests of replicates was comparable for all transition zone locations examined.

  2. Degradation of nonmodified and rhodium modified aluminide coating deposited on CMSX 4 superalloy.

    Science.gov (United States)

    Zagula-Yavorska, Maryana; Wierzbińska, Małgorzata; Gancarczyk, Kamil; Sieniawski, Jan

    2016-07-01

    The Ni-base superalloy CMSX 4 used in the turbine blades of aircraft engines was coated with rhodium layer (0.5-μm thick). Next coated CMSX 4 superalloy was aluminized by the CVD method. The rhodium modified aluminide coating and nonmodified aluminide coating were oxidized at 1100°C at the air atmosphere. The rhodium modified aluminide coating showed about twice better oxidation resistance than the nonmodified one. The spallation equal 62% of the total area was observed on the surface of the nonmodified coating whereas only 36% spallation area was observed on the surface of the rhodium modified aluminide coating after the oxidation test. The oxide layer formed on the surface of the nonmodified coating was composed of nonprotective (Ni,Cr)Al2 O4 and (Ni,Cr)O phases. Aluminium in the coating reacts with oxygen, forming a protective α-Al2 O3 oxide on the surface of the rhodium modified aluminide coating. When the oxide cracks and spalls due to oxidation, additional aluminium from the coating diffuses to the surface to form the oxide. The presence of protective Al2 O3 oxide on the surface of the rhodium modified aluminide coating slows coating degradation. Therefore, rhodium modified aluminide coating has better oxidation resistance than the nonmodified one.

  3. Mapping single-crystal dendritic microstructure and defects in nickel-base superalloys with synchrotron radiation

    Energy Technology Data Exchange (ETDEWEB)

    Husseini, Naji S. [Applied Physics Program, University of Michigan, Ann Arbor, MI 48109 (United States)], E-mail: najihuss@umich.edu; Kumah, Divine P. [Applied Physics Program, University of Michigan, Ann Arbor, MI 48109 (United States); Yi, Jian Z.; Torbet, Christopher J. [Department of Materials Science and Engineering, University of Michigan, Ann Arbor, MI 48109 (United States); Arms, Dohn A.; Dufresne, Eric M. [Advanced Photon Source, Argonne National Laboratory, Argonne, IL 60439 (United States); Pollock, Tresa M.; Wayne Jones, J. [Department of Materials Science and Engineering, University of Michigan, Ann Arbor, MI 48109 (United States); Clarke, Roy [Applied Physics Program, University of Michigan, Ann Arbor, MI 48109 (United States)

    2008-10-15

    Solidification of single-crystal nickel-base superalloys introduces large-scale segregation of constituent elements and defects such as dislocations and mosaicity. By exploiting the energy tunability and interference capabilities of high-brilliance X-ray radiation, key structural features of the dendritic single crystals were mapped over large areas. Interference and diffraction of synchrotron X-rays revealed significant misorientations between individual dendrites in the as-solidified state. For the first time this mosaic structure was quantified for an array of dendrites and correlated with the density of 'grown-in' dislocations whose density ranged from 10{sup 7} to 10{sup 8} cm{sup -2}. Absorption contrast permitted simultaneous mapping of the distribution of refractory metal additives (e.g. rhenium and tungsten), which segregated preferentially to the dendrite cores with a linear composition gradient toward the interdendritic regions. The results demonstrate that synchrotron X-ray imaging is promising for in situ studies of single-crystal structure and defects in nickel-base superalloys.

  4. Influence of Ta content on hot corrosion behaviour of a directionally solidified nickel base superalloy

    Energy Technology Data Exchange (ETDEWEB)

    Han, F.F. [Superalloy Division, Institute of Metal Research, Chinese Academy of Sciences, 72 Wenhua Road, Shenyang 110016 (China); Chang, J.X., E-mail: jxchang11s@imr.ac.cn [Superalloy Division, Institute of Metal Research, Chinese Academy of Sciences, 72 Wenhua Road, Shenyang 110016 (China); Li, H.; Lou, L.H. [Superalloy Division, Institute of Metal Research, Chinese Academy of Sciences, 72 Wenhua Road, Shenyang 110016 (China); Zhang, J. [Superalloy Division, Institute of Metal Research, Chinese Academy of Sciences, 72 Wenhua Road, Shenyang 110016 (China); Shenyang National Laboratory for Materials Science, Institute of Metal Research, Chinese Academy of Sciences, 72 Wenhua Road, Shenyang 110016 (China)

    2015-01-15

    Highlights: • Three nickel-base superalloys containing different Ta content were subjected to Na{sub 2}SO{sub 4}-induced hot corrosion. • Ta improved the hot corrosion resistance. • Ta decreased the diffusion rate of alloying elements. • Ta promoted the formation of (Cr, Ti)TaO{sub 4} layer. - Abstract: Hot corrosion behaviour of a directionally solidified nickel base superalloy with different tantalum (Ta) addition in fused sodium sulphate (Na{sub 2}SO{sub 4}) under an oxidizing atmosphere at 900 °C has been studied. It was shown that the hot corrosion resistance was improved by increasing of Ta content. The hot corrosion kinetics of the alloy with lower Ta content deviated from parabolic law after 60 h corrosion test, whereas the corrosion kinetics of the alloy with high Ta content followed the parabolic law before 60 h and with less mass change afterwards. A detailed microstructure study using scanning electron microscopy (SEM) equipped with an energy dispersive spectroscopy (EDS), transmission electron microscopy (TEM) and X-ray diffraction (XRD) was performed to investigate the corrosion products and mechanisms. The beneficial effect of Ta was found to be resulted from a Ta-enriched (Cr, Ti)TaO{sub 4} layer inside the corrosion scale, which led to the retarding of the element diffusion so as to decrease the hot corrosion kinetics.

  5. An experimental study on quasi-CW fibre laser drilling of nickel superalloy

    Science.gov (United States)

    Marimuthu, S.; Antar, M.; Dunleavey, J.; Chantzis, D.; Darlington, W.; Hayward, P.

    2017-09-01

    Laser drilling of metals and alloys is extensively used in modern manufacturing industries to produce holes of various size and shape. Currently, most laser drilling of aerospace nickel superalloys is performed using Nd:YAG laser. Over the years, many attempts were made to increase the productivity of Nd:YAG lasers drilling process, but with little success. This paper investigates the fundamental aspects of millisecond-pulsed-Quasi-CW-fibre laser drilling of aerospace nickel superalloy. The main investigation concentrates on understanding the Quasi-CW-fibre laser parameters on trepanning laser drilled hole quality and speed. The principal findings are based on controlling the recast layer, oxide layer, hole surface characteristic and fatigue performance of the laser drilled samples. The results showed that the high average power of the quasi-CW-fibre lasers can be effectively used to achieve increased trepanning drilling speed without undermining the drilling quality, which is not feasible with a free-space Nd:YAG laser. Also, low peak power and high frequency (of quasi-CW-fibre laser) can be effectively used to produce better laser drilled holes than the high peak power and low frequency, which is common with the traditional millisecond Nd:YAG drilling processes. Recast layer thickness of around 30 μm can be achieved with a trepanning speed of up to 500 mm/min with single orbit Quasi-CW fibre laser drilling of 0.75 mm hole over 5 mm thick material.

  6. Technology of laser repair welding of nickel superalloy inner flaps of jet engine

    Directory of Open Access Journals (Sweden)

    A. Klimpel

    2011-07-01

    Full Text Available Purpose: of this paper: work out laser welding repair technology of cracked MIG 29 jet engine inner flaps made of cast nickel superalloy ŻS-3DK (ЖС-3ДК, Russian designation.Design/methodology/approach: The study were based on the analysis of laser HPDL powder INCONEL 625 welding of nickel superalloy using wide range of welding parameters to provide highest quality repair welds.Findings: Study of automatic welding technologies GTA, PTA and laser HPDL has shown that just laser welding can provide high quality repair welds. In order to establish the properties of welded joints repair cracks in the inner flap HPDL laser, studied the hardness, mechanical properties and erosive wear resistance.Research limitations/implications: It was found that only laser HPDL welding can provide high quality repair welds.Practical implications: The technology can be applied for repair cracked MIG 29 jet engine inner flaps.Originality/value: Repairing cracked MIG 29 jet engine inner flaps.

  7. Microstructural characteristics and mechanical properties of HVOF sprayed NiCrAl coating on superalloys

    Energy Technology Data Exchange (ETDEWEB)

    Mahesh, R.A. [Department of Metallurgical and Materials Engineering, Indian Institute of Technology Roorkee, Roorkee 247667 (India); Jayaganthan, R. [Department of Metallurgical and Materials Engineering, Indian Institute of Technology Roorkee, Roorkee 247667 (India)], E-mail: rjayafmt@iitr.ernet.in; Prakash, S. [Department of Metallurgical and Materials Engineering, Indian Institute of Technology Roorkee, Roorkee 247667 (India)

    2009-01-22

    High velocity oxy-fuel (HVOF) process sprayed NiCrAl coatings on superalloys were characterized by various techniques such as optical microscopy, X-ray diffraction (XRD) and scanning electron microscopy/energy dispersive spectroscopic analysis (SEM/EDS) to render an insight into their microstrucural features and assess its suitability for high temperature corrosion resistance applications. The as sprayed coatings were found to be dense with splat like layered morphology. The XRD analysis of the coating showed the presence of Ni (fcc) as a prominent phase with Cr and Al as minor phases. The porosity of the coatings was calculated from its optical micrographs and found to be less than 1.7%. The measured hardness and average bond strength of the coatings were found to be in the range of 278-351 Hv and 59 MPa, respectively. The observed microstructral characteristics, higher bond strength, and hardness of HVOF sprayed NiCrAl coating show that it may act as an effective barrier to provide high temperature protection to the superalloys.

  8. Microstructure Modeling of a Ni-Fe-Based Superalloy During the Rotary Forging Process

    Science.gov (United States)

    Loyda, A.; Hernández-Muñoz, G. M.; Reyes, L. A.; Zambrano-Robledo, P.

    2016-06-01

    The microstructure evolution of Ni-Fe superalloys has a great influence on the mechanical behavior during service conditions. The rotary forging process offers an alternative to conventional bulk forming processes where the parts can be rotary forged with a fraction of the force commonly needed by conventional forging techniques. In this investigation, a numerical modeling of microstructure evolution for design and optimization of the hot forging operations has been used to manufacture a heat-resistant nickel-based superalloy. An Avrami model was implemented into finite element commercial platform DEFORM 3D to evaluate the average grain size and recrystallization during the rotary forging process. The simulations were carried out considering three initial temperatures, 980, 1000, and 1050 °C, to obtain the microstructure behavior after rotary forging. The final average grain size of one case was validated by comparing with results of previous experimental work of disk forging operation. This investigation was aimed to explore the influence of the rotary forging process on microstructure evolution in order to obtain a homogenous and refined grain size in the final component.

  9. MICROMECHANICS OF THE DAMAGE-INDUCED CELLULAR MICROSTRUCTURE IN SINGLE CRYSTAL Ni-BASED SUPERALLOYS

    Institute of Scientific and Technical Information of China (English)

    M.Sakaguchi; M.Okazaki

    2004-01-01

    An analytical method to investigate the morphological evolution of the cellular microstructure is explored and proposed. The method is essentially based on the Eshelby's micromechanics theory, and it is extended so as to be applied for a material system containing inclusions with high volume fraction, by employing the average stress field approximation by Mori and Tanaka. The proposed method enables us to discuss a stable shape of precipitate in the material system, which must be influenced by many factors: e.g., volume fraction of precipitate; Young's modulus ratio and lattice misfit between matrix and precipitate; external stress field in multiaxial state; and heterogeneity of plastic strain between matrix and precipitate. A series of numerical calculations were summarized on stable shape maps. The application of the method to predict the γ' rafting in superalloys during creep showed that the heterogeneity of plastic strain between matrix and precipitates may play a significant role in the shape stability of the precipitate. Furthermore, it was shown that the method was successfully applied to estimate the morphology of the cellular microstructure formed in CMSX-4single crystal Ni-based superalloy.

  10. Effect of Heat Treatment Process on Microstructure and Fatigue Behavior of a Nickel-Base Superalloy

    Directory of Open Access Journals (Sweden)

    Peng Zhang

    2015-09-01

    Full Text Available The study of fatigue behaviors for nickel-base superalloys is very significant because fatigue damage results in serious consequences. In this paper, two kinds of heat treatment procedures (Pro.I and Pro.II were taken to investigate the effect of heat treatment on microstructures and fatigue behaviors of a nickel-base superalloy. Fatigue behaviors were studied through total strain controlled mode at 650 °C. Manson-Coffin relationship and three-parameter power function were used to predict fatigue life. A good link between the cyclic/fatigue behavior and microscopic studies was established. The cyclic deformation mechanism and fatigue mechanism were discussed. The results show that the fatigue resistance significantly drops with the increase of total strain amplitudes. Manson-Coffin relationship can well predict the fatigue life for total strain amplitude from 0.5% to 0.8%. The fatigue resistance is related with heat treatment procedures. The fatigue resistance performance of Pro.I is better than that of Pro.II. The cyclic stress response behaviors are closely related to the changes of the strain amplitudes. The peak stress of the alloy gradually increases with the increase of total strain amplitudes. The main fracture mechanism is inhomogeneous deformation and the different interactions between dislocations and γ′ precipitates.

  11. Effect of HIP Combined with RHT Process on Creep Damage of DZ125 Superalloy

    Directory of Open Access Journals (Sweden)

    WANG Tian-you

    2017-02-01

    Full Text Available Four different processes of hot isostatic pressing (HIP combined with rejuvenation heat treatments (RHT were adopted to reveal the microstructural evolution of creep damaged DZ125 specimens, finally the mechanical properties were evaluated.The results show that both γ' precipitate degeneration and creep cavities for the creep damaged DZ125 superalloy are found after the pre-endurance damage test.However, the carbided compositions from MC type to M23C6 type or M6C type has not been observed for DZ125.In addition, it is found that the HIP temperature play a dominant role in the cavity healing process for the damaged specimens. The concentrically oriented γ' rafting structure and the incipient melting are observed at 1200℃ and 1250℃ respectively.Meanwhile, it is found that the appropriate HIP schedule adopted can effectively avoid the internal recrystallization for the directionally solidified nickel-based superalloy DZ125. The appropriate HIP schedule combined with RHT process can successfully restore the microstructure induced by creep damage and recover the degraded micro-hardness to the original one, in addition improve the creep rupture life.

  12. Influence of cooling rate on y'morphology in cast Ni – base superalloy

    Directory of Open Access Journals (Sweden)

    J. Belan

    2009-04-01

    Full Text Available The Ni – base superalloys, which are combined an unique physical and mechanical properties, are used in aircraft industry for productionof aero engine most stressed parts, as are turbine blades. From this reason a dendrite arm spacing, carbides size and distribution, morphology,number and value of y'- phase are very important structural characteristics for blade lifetime prediction as well as aero engine its self. In this article are used methods of quantitative metallography (software LUCIA for carbides evaluation, measuring of secondary dendrite arm spacing and coherent testing grid for y' - phase evaluation for evaluation of structural characteristics mentioned above on experimental material – Ni base superalloy ŽS6K. The high temperature effect represented here by heat treatment at 800°C followed with holding time about 10 hours, and cooling rate, here represented by three various cooling mediums as water, air, and oil, on structural characteristics and application of quantitative methods evaluation are presented in this paper.

  13. The cyclic oxidation behavior of the single crystal TMS-82+ superalloy in humidified air

    Energy Technology Data Exchange (ETDEWEB)

    Wu, Y. [School of Materials Science and Engineering, Shanghai, Institute of Technology, Shanghai (China); Research Group of Interface Control Engineering, Graduate School of Engineering, Hokkaido University, Sapporo (Japan); Narita, T. [Research Group of Interface Control Engineering, Graduate School of Engineering, Hokkaido University, Sapporo (Japan)

    2009-10-15

    The cyclic oxidation behavior of a single crystal Ni-based superalloy TMS-82+ was studied at 800 and 900 C for 200 h in water vapor (air plus 15% H{sub 2}O). Regardless of the exposure temperature, time-dependence of the growth rate of the scale for the superalloy was fitted by a subparabolic relationship. The oxidation rate was enhanced with increase in exposure temperature, which was evidenced by a higher mass gain and thicker scale. The oxides on the specimen at 800 C consisted of (Ni,Co)O, CrTaO{sub 4}, AlTaO{sub 4}, Cr{sub 2}O{sub 3}, and {theta}-Al{sub 2}O{sub 3}, whereas for the specimen exposed at 900 C, spinels of NiCr{sub 2}O{sub 4} and (Ni,Co)Al{sub 2}O{sub 4} as well as {alpha}-Al{sub 2}O{sub 3} were observed. An innermost dense {alpha}-Al{sub 2}O{sub 3} layer was responsible for a stable growth rate of the scale after the initial rapid oxidation. (Abstract Copyright [2009], Wiley Periodicals, Inc.)

  14. Methodology of Ni-base Superalloy Development for VHTR using Design of Experiments and Thermodynamic Calculation

    Energy Technology Data Exchange (ETDEWEB)

    Kim, Sungwoo; Kim, Dongjin [Korea Atomic Energy Research Institute, Daejeon (Korea, Republic of)

    2013-03-15

    This work is concerning a methodology of Ni-base superalloy development for a very high temperature gas-cooled reactor(VHTR) using design of experiments(DOE) and thermodynamic calculations. Total 32 sets of the Ni-base superalloys with various chemical compositions were formulated based on a fractional factorial design of DOE, and the thermodynamic stability of topologically close-packed(TCP) phases of those alloys was calculated by using the THERMO-CALC software. From the statistical evaluation of the effect of the chemical composition on the formation of TCP phase up to a temperature of 950 .deg. C, which should be suppressed for prolonged service life when it used as the structural components of VHTR, 16 sets were selected for further calculation of the mechanical properties. Considering the yield and ultimate tensile strengths of the selected alloys estimated by using the JMATPRO software, the optimized chemical composition of the alloys for VHTR application, especially intermediate heat exchanger, was proposed for a succeeding experimental study.

  15. Solution and Aging of MAR-M246 Nickel-Based Superalloy

    Science.gov (United States)

    Baldan, Renato; da Silva, Antonio Augusto Araújo Pinto; Nunes, Carlos Angelo; Couto, Antonio Augusto; Gabriel, Sinara Borborema; Alkmin, Luciano Braga

    2017-02-01

    Solution and aging heat-treatments play a key role for the application of the superalloys. The aim of this work is to evaluate the microstructure of the MAR-M246 nickel-based superalloy solutioned at 1200 and 1250 °C for 330 min and aged at 780, 880 and 980 °C for 5, 20 and 80 h. The γ' solvus, solidus and liquidus temperatures were calculated with the aid of the JMatPro software (Ni database). The as-cast and heat-treated samples were characterized by SEM/EDS and SEM-FEG. The γ' size precipitated in the aged samples was measured and compared with JMatPro simulations. The results have shown that the sample solutioned at 1250 °C for 330 min showed a very homogeneous γ matrix with carbides and cubic γ' precipitates uniformly distributed. The mean γ' size of aged samples at 780 and 880 °C for 5, 20 and 80 h did not present significant differences when compared to the solutioned sample. However, a significant increasing in the γ' particles was observed at 980 °C, evidenced by the large mean size of these particles after 80 h of aging heat-treatment.

  16. Designing Nanoscale Precipitates in Novel Cobalt-based Superalloys to Improve Creep Resistance and Operating Temperature

    Energy Technology Data Exchange (ETDEWEB)

    Dunand, David C. [Northwestern Univ., Evanston, IL (United States); Seidman, David N. [Northwestern Univ., Evanston, IL (United States); Wolverton, Christopher [Northwestern Univ., Evanston, IL (United States); Saal, James E. [Northwestern Univ., Evanston, IL (United States); Bocchini, Peter J. [Northwestern Univ., Evanston, IL (United States); Sauza, Daniel J. [Northwestern Univ., Evanston, IL (United States)

    2014-10-01

    High-temperature structural alloys for aerospace and energy applications have long been dominated by Ni-base superalloys, whose strength and creep resistance can be attributed to microstructures consisting of a large volume fraction of ordered (L12) γ'-precipitates embedded in a disordered’(f.c.c.) γ-matrix. These alloys exhibit excellent mechanical behavior and thermal stability, but after decades of incremental improvement are nearing the theoretical limit of their operating temperatures. Conventional Co-base superalloys are solid-solution or carbide strengthened; although they see industrial use, these alloys are restricted to lower-stress applications because the absence of an ordered intermetallic phase places an upper limit on their mechanical performance. In 2006, a γ+γ' microstructure with ordered precipitates analogous to (L12) Ni3Al was first identified in the Co-Al-W ternary system, allowing, for the first time, the development of Co-base alloys with the potential to meet or even exceed the elevated-temperature performance of their Ni-base counterparts. The potential design space for these alloys is complex: the most advanced Ni-base superalloys may contain as many as 8-10 minor alloying additions, each with a specified purpose such as raising the γ' solvus temperature or improving creep strength. Our work has focused on assessing the effects of alloying additions on microstructure and mechanical behavior of γ'-strengthened Co-base alloys in an effort to lay the foundations for understanding this emerging alloy system. Investigation of the size, morphology, and composition of γ' and other relevant phases is investigated utilizing scanning electron microscopy (SEM) and 3-D picosecond ultraviolet local electrode atom probe tomography (APT). Microhardness, compressive yield stress at ambient and elevated temperatures, and compressive high-temperature creep measurements are employed to

  17. High temperature properties of polycrystalline γ{sup '}-strengthened cobalt-base superalloys; Hochtemperatureigenschaften polykristalliner γ{sup '}-gehaerteter Kobaltbasis-Superlegierungen

    Energy Technology Data Exchange (ETDEWEB)

    Bauer, Alexander

    2016-07-01

    The recent discovery of a stable γ{sup '}-phase in Co-based superalloys opened up a pathway for the development of a new high temperature material class, which is similar in microstructure and properties to the modern γ{sup '}-hardened Ni-based superalloys. In this work, the first attempt was done to check the influence of several for Ni-based superalloys typical alloying elements on the properties of the new Co-based superalloys. It became clear that the basic characteristics of the first experimental alloys are similar to those of the γ{sup '}-hardened Ni-based alloys. The results of the multinary experimental alloys show that, based on the insight gained so far, targeted alloy development is possible. These materials have the potential to be used as disc materials in turbines.

  18. The synchronous improvement of strength and plasticity (SISP) in new Ni-Co based disc superalloys by controling stacking fault energy

    OpenAIRE

    Xu, H.; Zhang, Z.J.; P Zhang; Cui, C. Y.; Jin, T; Zhang, Z. F.

    2017-01-01

    It is a great challenge to improve the strength of disc superalloys without great loss of plasticity together since the microstructures benefiting the strength always do not avail the plasticity. Interestingly, this study shows that the trade-off relationship between strength and plasticity can be broken through decreasing stacking fault energy (SFE) in newly developed Ni-Co based disc superalloys. Axial tensile tests in the temperature range of 25 to 725??C were carried out in these alloys w...

  19. Guidelines for Description

    NARCIS (Netherlands)

    Links, P.; Horsman, Peter; Kühnel, Karsten; Priddy, M.; Reijnhoudt, Linda; Merenmies, Mark

    2013-01-01

    The Guidelines follow the conceptual metadata model (deliverable 17.2). They include guidelines for description of collection-holding institutions, document collections, organisations, personalities, events, camps and ghettos. As much as possible the guidelines comply with the descriptive standards

  20. Lecture notes on quantum statistics

    NARCIS (Netherlands)

    Gill, R.D.

    2001-01-01

    These notes are meant to form the material for an introductory course on quantum statistics at the graduate level aimed at mathematical statisticians and probabilists No background in physics quantum or otherwise is required They are still far from complete

  1. SAFETY INSTRUCTION AND SAFETY NOTE

    CERN Multimedia

    TIS Secretariat

    2002-01-01

    Please note that the SAFETY INSTRUCTION N0 49 (IS 49) and the SAFETY NOTE N0 28 (NS 28) entitled respectively 'AVOIDING CHEMICAL POLLUTION OF WATER' and 'CERN EXHIBITIONS - FIRE PRECAUTIONS' are available on the web at the following urls: http://edms.cern.ch/document/335814 and http://edms.cern.ch/document/335861 Paper copies can also be obtained from the TIS Divisional Secretariat, email: TIS.Secretariat@cern.ch

  2. Mechanical properties of white layers formed by different machining processes on nickel-based superalloy

    Science.gov (United States)

    Proust, Edouard

    Nickel-based superalloys are widely used in the aerospace industry in the production of turbine discs and blades because of their good mechanical properties and great corrosion resistance at high temperature. Although very useful, these alloys are hard to machine. Their structure is responsible for rapid wear of cutting tools. Moreover, under certain machining conditions, near-surface regions of the material undergo a phase transformation resulting in the formation of a thin layer called "white etching layer" at the surface of the machined workpiece. Because turbine discs are safety critical components, no defects can be tolerated on the workpiece. Therefore, efforts should be made to ensure that this white etching layer can't influence the operating life of the workpiece and make its operation unsafe. Even if the existence of the white etching layer is well known, its mechanical properties have never been assessed in detail. In this thesis, we present a study of the mechanical (hardness and Young's modulus) and microstructural properties of white etching layers formed at the surface of nickel-based superalloy IN100 turbine discs fabricated by different machining processes. This work aims at evaluating the impact of the machining process and of fatigue on the properties of the white etching layers under study. The originality of this study primarily lies in the employed characterization technique. Using nanoindentation has allowed us to very precisely assess the variations of both the hardness and the Young's modulus along the white etching layers. Also, the use of a sophisticated indentation system has enabled the acquisition of very precise surface images of the samples and therefore to study the microstructure of the white etching layers. This research has demonstrated that the mechanical and microstructural properties of the white etching layers are closely linked to the machining conditions of the material. Therefore, our study will help researchers gain a

  3. Changes in the microstructure occurring during the creep of single crystal nickel-base superalloys

    Energy Technology Data Exchange (ETDEWEB)

    Henderson, P.; Komenda, J. [Institutet foer Metallforskning, Stockholm (Sweden)

    1996-12-01

    Nickel-base superalloy single crystal components are now being introduced into industrial gas turbines as first row turbine blades report and in the future methods of remaining life assessment will be required. In this report an introduction to single crystal alloys is given and the effects of service exposure and principles of remaining life assessment of nickel-base superalloys have been reviewed. During creep (in cast Ni-base superalloys) cavities appear at grain boundaries and shape changes occur in the {gamma}` particles. Interrupted and full length creep tests have been performed at 750 and 950 deg C on the Ni-base single crystal alloy CMSX-4 and the resulting changes in microstructure have been quantified using a wide variety of parameters. The solidification process results in interdendritic porosity and the {gamma}` particles are initially cuboidal in shape. At 750 deg C no changes in the particles or porosity could be detected. At 950 deg C the volume fraction and number per sq.mm of measured cavities increased during creep. The smallest cavities measured by optical microscopy were 2-3 {mu}m in diameter, which was the limit of resolution of the system. The increase in cavity numbers is caused by the growth of cavities originally under 2 {mu}m. At 950 deg C the {gamma}` particles coalesced during creep to form a network of rafts, containing isolated plates of matrix and the volume percent of {gamma}` increased from ca 50 to ca 75%. The rafts reached their maximum length before 2% strain, but continued to thicken throughout the test. Although of different dimensions, the aspect ratio (length-to-width ratio as measured by the intersection of chords) of the {gamma}` rafts and the matrix plates were similar at the same levels of strain, reaching a maximum before 2% strain. These changes at 950 deg C were strain- and not time-dependent. Based on these findings, a way forward for the remaining life assessment of single crystal components has been proposed.

  4. SPORT AND EXERCISE BIOMECHANICS (BIOS INSTANT NOTES

    Directory of Open Access Journals (Sweden)

    Paul Grimshaw

    2007-06-01

    Full Text Available DESCRIPTION Instant Notes on Sport and Exercise Biomechanics provides a broad overview of the fundamental concepts in exercise and sport biomechanics. PURPOSE The book aims to provide instant notes on essential information about biomechanics, and is designed to help undergraduate students to grasp the corresponding subjects in physical effort rapidly and easily. AUDIENCE The book provides a useful resource for undergraduate and graduate students as a fundamental reference book. For the researcher and lecturer it would be a starting point to plan and prepare more detailed experimental designs or lecture and/or laboratory classes in the field of exercise and sport biomechanics. It would also be interest to anyone who wonders the concepts like momentum possessed, whole body angular momentum, opposite parallel forces, superman position, parabolic flight path, joint/normal reaction force, etc. FEATURES This textbook is divided into following sections from A to F: kinematics of motion, kinetics of linear motion, kinetics of angular motion, special topics, applications and measurement techniques, respectively. In sub-sections the kinematics of motion are reviewed in detail, outlining the physics of motion. Furthermore, the discussions of mechanical characteristics of motion, the mechanisms of injury, and the analysis of the sport technique provide a source of valuable information for both students and lecturers in appropriate fields. ASSESSMENT This book is an important reading for biomechanics students, teachers and even researchers as well as anyone interested in understanding motion.

  5. Morphological evolution of γ′ phase in K465 superalloy during thermal fatigue

    Institute of Scientific and Technical Information of China (English)

    YANG Jin-xia; ZHENG Qi; SUN Xiao-feng; GUAN Heng-rong; HU Zhuang-qi

    2006-01-01

    The alternative heating/cooling cycles(thermal fatigue)of K465 superalloy were carried out. The specimens were held at 1 050 ℃ for 300 s, then quenched into 20 ℃ recycling water for 10 s as a cycle. During thermal fatigue, γ′ precipitates changed typically from cubical to irregular shape after 10 cycles, to complex configuration after 20 cycles and raft-like shape after 30 cycles. The very fine γ′ particles precipitated inter the original γ′ particles. The elastic energy dominated morphological evolution of large γ′ precipitates, and the thermal stress induced the directional growth of precipitates that minimized the total energy of the system, and the nucleation theory controlled the formation of fine γ′ precipitate. The results show that the volume fraction of γ′ precipitates is increased with the increase of heating/cooling cycles, which improves the mechanical property of this alloy.

  6. Influence of Processing Parameters on Grain Size Evolution of a Forged Superalloy

    Science.gov (United States)

    Reyes, L. A.; Páramo, P.; Salas Zamarripa, A.; de la Garza, M.; Guerrero-Mata, M. P.

    2016-01-01

    The microstructure evolution of nickel-based superalloys has a great influence on the mechanical behavior during service conditions. Microstructure modification and the effect of process variables such as forging temperature, die-speed, and tool heating were evaluated after hot die forging of a heat-resistant nickel-based alloy. Forging sequences in a temperature range from 1253 to 1323 K were considered through experimental trials. An Avrami model was applied using finite element data to evaluate the average grain size and recrystallization at different evolution zones. It was observed that sequential forging at final temperatures below 1273 K provided greater grain refinement through time-dependent recrystallization phenomena. This investigation was aim to explore the influence of forging parameters on grain size evolution in order to design a fully homogenous and refined microstructure after hot die forging.

  7. Tensile and fracture behavior of DZ951 Ni-base superalloy

    Institute of Scientific and Technical Information of China (English)

    CHU Zhao-kuang; YU Jin-jiang; SUN Xiao-feng; ZHAO Nai-ren; GUAN Heng-rong; HU Zhuang-qi

    2006-01-01

    The tensile and fracture behavior of DZ951 directionally solidified Ni-base superalloy was studied in the temperature range of 20-1 100 ℃. The fracture mode was examined by scanning electron microscopy. The results show the experimental temperature has no significant effect on the tensile strengths, which are greater than 1 000 MPa from room temperature to 800 ℃. The yield strength reaches its maximum (970 MPa) at 800 ℃. When the experimental temperature is higher than 800 ℃, the tensile and yield strengths decrease evidently and the ductility increases remarkably. The fractograph of fracture surface for the tensile specimen at room temperature shows a dimple-ductile fracture mode. The fractograph from 600 to 800 ℃ shows a slide fracture mode. The fractograph from 900 to 1 100 ℃ exhibits a creep rupture mode with uneven deformation.

  8. Dynamic precipitation of nickel-based superalloys undergoing severe deformation below the solvus temperature

    Energy Technology Data Exchange (ETDEWEB)

    Nowotnik, Andrzej; Rokicki, Pawel; Mrowka-Nowotnik, Grazyna; Sieniawski, Jan [Rzeszow Univ. of Technology (Poland). Dept. of Material Science

    2015-07-15

    The authors performed uniaxial compression tests of nickel-based superalloys: single crystal CMSX-4, also precipitation hardened; Inconel 718 and X750, at temperatures below the γ' solvus, in order to study the effect of temperature and strain rate on their flow stress and microstructural development. On the basis of the obtained flow stress values, the activation energy of a high-temperature deformation process was estimated. Microstructural observations of the deformed samples at high temperatures, previously solution heat treated and aged CMSX-4 and Inconel alloys revealed non-uniform deformation effects. Distribution of either molybdenum- or niobium-rich carbides was found to be affected by localized flow within the investigated strain range at relatively low deformation temperatures, 720-850 C. Microstructural examination of the alloys also showed that shear banding and cavity growth were responsible for the decrease in flow stress and a specimen fracture at larger strains.

  9. Technology of High-speed Direct Laser Deposition from Ni-based Superalloys

    Science.gov (United States)

    Klimova-Korsmik, Olga; Turichin, Gleb; Zemlyakov, Evgeniy; Babkin, Konstantin; Petrovsky, Pavel; Travyanov, Andrey

    Recently, additive manufacturing is the one of most perspective technologies; it can replace conventional methods of casting and subsequent time-consuming machining. One of the most interesting additive technologies - high-speed direct laser deposition (HSDLD) allows realizing heterophase process during the manufacturing, which there is process takes place with a partial melting of powder. This is particularly important for materials, which are sensitive to strong fluctuations of temperature treatment regimes, like nickel base alloys with high content of gamma prime phase. This alloys are interested for many industrial areas, mostly there are used in engine systems, aircraft and shipbuilding, aeronautics. Heating and cooling rates during the producing process determine structure and affect on its properties. Using HSDLD process it possible to make a products from Ni superalloys with ultrafine microstructure and satisfactory mechanical characteristics without special subsequent heatreatment.

  10. Microstructure Evolution of a Single Crystal Nickel-Base Superalloy During Heat Treatment and Creep

    Institute of Scientific and Technical Information of China (English)

    YANG Da-yun,JIN Tao; ZHAO Nai-ren; WANG ZHi-hui; SUN Xiao-feng; GUAN Heng-rong; HU Zhuang-qi

    2004-01-01

    Microstructure evolution of a single crystal nickel-base superalloy during heat treatment and tensile creep at1010℃ and 248 MPa for 30h was observed and analyzed. Internal stresses because of lattice mismatch between γ and γphase provided the driving force for γ shape evolution during heat treatment. More than 65 vol. % distorted cubic γ phase keeping coherency with the γ matrix precipitated after solution at 1295 ℃ for 32h. The shape of γ phase was perfectly cubic with increasing precipitate size during the two-step aging treatment. Due to the applied stress and internal stress field the continuous γ-γ lamellar structure perpendicular to the applied stress was formed after 30h tensile creep.

  11. Optimality analysis of multiplex A-TIG welding flux for nickel-base superalloy

    Institute of Scientific and Technical Information of China (English)

    Fan Chenglei; Yang Chunli; Liang Yingchun; Lin Sanbao; Yu Xiang

    2007-01-01

    Orthogonal experiment is employed to study a new kind of multiplex flux for nickel-base superalloy. This activated TIG welding flux is composed of NaF, MgF2 and CaF2, and their proportion is 5:4:1. Compared with conventional TIG welding, the penetration increases 164% by the action of the flux. Tensile test result indicates that the fracture strength of the mixed flux A-TIG weld bead is higher than base metal, and it increases along with the decrement of the welding current. The average extensibility of the weldment is beyond 100%, which means perfect ductility. Metallographs elucidate that there exist lots of deep and evenly distributed dimples on the fracture section of weld bead while on that of base metal there only exists a few shallow dimples and massive tearing ridge.

  12. Effect of Deforming Temperature and Strain on Abnormal Grain Growth of Extruded FGH96 Superalloy

    Directory of Open Access Journals (Sweden)

    WANG Chaoyuan

    2016-10-01

    Full Text Available Based on the experiments of isothermal forging wedge-shaped samples, Deform-3D numerical simulation software was used to confirm the strain distribution in the wedge-shaped samples. The effect of deforming temperature and strain on abnormal grain growth(AGG in extruded FGH96 superalloy was examined. It is found that when the forging speed is 0.04 mm/s,the critical AGG occurring temperature is 1100℃,and the critical strain is 2%.AGG does not occur within 1000-1070℃,but still shows the feature of ‘critical strain’,and the region with strain of 5%-10% has the largest average grain size.AGG can be avoided and the uniform fine grains can be gained when the strain is not less than 15%.

  13. Yielding and deformation behavior of the single crystal superalloy PWA 1480

    Science.gov (United States)

    Milligan, Walter W.; Antolovich, Stephen D.

    1987-01-01

    Interrupted tensile tests were conducted to fixed plastic strain levels in 100 ordered single crystals of the nickel based superalloy PWA 1480. Testing was done in the range of 20 to 1093 C, at strain rate of 0.5 and 50 percent/min. The yield strength was constant from 20 to 760 C, above which the strength dropped rapidly and became a strong function of strain rate. The high temperature data were represented very well by an Arrhenius type equation, which resulted in three distinct temperature regimes. The deformation substructures were grouped in the same three regimes, indicating that there was a fundamental relationship between the deformation mechanisms and activation energies. Models of the yielding process were considered, and it was found that no currently available model was fully applicable to this alloy. It was also demonstrated that the initial deformation mechanism (during yielding) was frequently different from that which would be inferred by examining specimens which were tested to failure.

  14. The effect of microstructure on the fatigue behavior of Ni base superalloys

    Science.gov (United States)

    Antolovich, S. D.; Jayaraman, N.

    1983-01-01

    Nickel-base superalloys are used in jet engine components such as disks, turbine blades, and vanes. Improvements in the fatigue behavior will allow the life to be extended or the payloads to be increased. The first part of the present investigation deals primarily with the effects of microstructural variations on the fatigue crack propagation (FCP) behavior of nickel-base alloys, while the second part is concerned with low-cycle fatigue (LCF) behavior of Ni base systems. Waspaloy at low temperature is considered, taking into account material heat treatment and test procedures, a composite plot of Waspaloy FCP data, Paris law fatigue crack propagation constants, monotonic tensile data, and overload FCP test results for Waspaloy. It is found that the FCP and overload behavior of nickel-base alloys may be markedly improved by heat treating. Attention is given to effects of cyclic deformation on microstructure and substructure, environmental damage, and an environmental/deformation model of high temperature LCF.

  15. Modeling of Thermal Expansion Coefficients of Ni-Based Superalloys Using Artificial Neural Network

    Science.gov (United States)

    Bano, Nafisa; Nganbe, Michel

    2013-04-01

    The objective of this work is to model the thermal expansion coefficients of various Ni-based superalloys used in gas turbine components. The thermal expansion coefficient is described as a function of temperature, chemical composition including Ni, Cr, Co, Mo, W, Ta, Nb, Al, Ti, B, Zr, and C contents as well as heat treatment including solutionizing and aging. Experimental values are well described and their relative changes well correlated by the model. Because gas turbine engine components operate under severe loading conditions and at high and varying temperatures, the prediction of their thermal expansion coefficient is crucial. The model developed in this work can be useful for design optimizations for minimizing thermo-mechanical stresses between the base alloys and potential protective coatings or adjacent components. It can substantially contribute to improve the performance and service life of gas turbine components.

  16. Isothermal oxidation behavior of cast Ni-base superalloy K44

    Institute of Scientific and Technical Information of China (English)

    LI Yun; LIU Xue-gui; GUO Jian-ting; YUAN Chao; YANG Hong-cai

    2006-01-01

    The oxidation behavior of a cast Ni-base superalloy K44 in air at 850-1 000 ℃ for l00 h was studied. The scales on the surface were determined by SEM and EPMA equipped with an EDXS. The results show that oxidation kinetics obey the parabolic law from which the values of activation energy Qp1=221.1 kJ/mol and Qp2=247.6 kJ/mol are estimated. The oxidation scales are composed of loose outer layer of TiO2/TiO-Cr2O3 and a small amount of NiCr2O4 and NiA12O4, compact intermediate layer Cr2O3, and precipitate of internal oxides A12O3.

  17. Evaluation of Heat Capacity and Resistance to Cyclic Oxidation of Nickel Superalloys

    Directory of Open Access Journals (Sweden)

    Przeliorz R.

    2014-08-01

    Full Text Available Paper presents the results of evaluation of heat resistance and specific heat capacity of MAR-M-200, MAR-M-247 and Rene 80 nickel superalloys. Heat resistance was evaluated using cyclic method. Every cycle included heating in 1100°C for 23 hours and cooling for 1 hour in air. Microstructure of the scale was observed using electron microscope. Specific heat capacity was measured using DSC calorimeter. It was found that under conditions of cyclically changing temperature alloy MAR-M-247 exhibits highest heat resistance. Formed oxide scale is heterophasic mixture of alloying elements, under which an internal oxidation zone was present. MAR-M-200 alloy has higher specific heat capacity compared to MAR-M-247. For tested alloys in the temperature range from 550°C to 800°C precipitation processes (γ′, γ″ are probably occurring, resulting in a sudden increase in the observed heat capacity.

  18. Retrieval results on various properties of superalloy using Data-Free-Way`. Joint research

    Energy Technology Data Exchange (ETDEWEB)

    Kaji, Yoshiyuki; Tsuji, Hirokazu; Sakino, Takao [Department of Nuclear Energy System, Tokai Research Establishment, Japan Atomic Energy Research Institute, Tokai, Ibaraki (Japan)] [and others

    1999-02-01

    The pilot system on the distributed database for advanced nuclear materials named `Data-Free-Way` was constructed under the collaboration of National Research Institute for Metals, Japan Atomic Energy Research Institute, and Power Reactor and Nuclear Fuel Development Corporation during fiscal years from 1990 through 1994. In order to make the system more substantial, the second stage collaborative research activity in which the main objective was to develop the utilization techniques for `Data-Free-Way` was initiated in 1995 among three above-mentioned organizations and Japan Science and Technology Corporation, which newly joined this program. In the second stage collaborative research activity, some trials of attractive utilization of the system focused on the issues relating to various properties of superalloy were performed by using the PC on the Internet. In future each organization will update the system for improving the interface of the system and enrich the stored data with debugging. (author)

  19. Nucleation and growth of precipitates in a Ni-based superalloy

    Energy Technology Data Exchange (ETDEWEB)

    Petkov, M.P.; Lynn, K.G. [Washington State Univ., Pullman, WA (United States). Dept. of Physics; Somoza, A. [IFIMAT, Univ. Nacional del Centro de la Provincia de Buenos Aires, Tandil (Argentina); Comision de Investigaciones Cientificas de la Provincia de Buenos Aires, La Plata (Argentina); Santos, G. [IFIMAT, Univ. Nacional del Centro de la Provincia de Buenos Aires, Tandil (Argentina)

    2001-07-01

    A study of the early stages of precipitation of the {gamma}'-phase in the commercial Ni-base superalloy Inconel X-750 is presented. Precipitation was induced by artificial aging heat treatments at 700 C during different times ranging up to 10{sup 4} min. Positron lifetime spectroscopy experiments, following the microstructural evolution, revealed a very complicated process of nucleation and growth of the second-phase particles, involving solute clustering and solute segregation. ''Frozen frames'' of the evolution process, chosen on the basis of the lifetime results, were studied by coincidence Doppler technique, which sheds information on the electronic and chemical environment around the positron trapping site. (orig.)

  20. On the precipitation sequence in a Ni-based superalloy: A Coincidence Doppler Broadening study

    Energy Technology Data Exchange (ETDEWEB)

    Macchi, C.E. [IFIMAT, UNCentro and CONICET, Pinto 399, B7000GHG Tandil (Argentina); Somoza, A. [IFIMAT, UNCentro and CICPBA, Pinto 399, B7000GHG Tandil (Argentina); Santos, G. [NIECyT, UNCentro, Pinto 399, B7000GHG Tandil (Argentina); Petkov, M. [Jet Propulsion Lab, California Institute of Technology, Pasadena, CA 91109 (United States); Lynn, K.G. [Department of Physics, Washington State University, Pullman WA 99164-2814 (United States)

    2007-07-01

    The precipitation sequence at 700 C of the Ni{sub 3}(Ti,Al)-type ordered {gamma}' phase in the commercial nickel-based superalloy Inconel X-750 was investigated using Coincidence Doppler Broadening (CDB) technique. The results obtained are discussed in terms of positron annihilation in two well-defined states: one corresponding to the matrix ({gamma} phase) and a second related to the {gamma}' precipitates. Between these two aging stages, CDB distributions corresponding to selected intermediate aging treatments could be presented exactly, within the experimental scatter, as a linear combination of the {gamma} and {gamma}' signatures. (copyright 2007 WILEY-VCH Verlag GmbH and Co. KGaA, Weinheim) (orig.)

  1. Hot corrosion behavior of the spray-formed nickel-based superalloy

    Science.gov (United States)

    Xia, Min; Gu, Tian-Fu; Jia, Chong-Lin; Ge, Chang-Chun

    2016-12-01

    An investigation of low temperature hot corrosion is carried out on a spray-formed nickel-based superalloy FGH100 pre-coated with Na2SO4-NaCl at 700 °C for 100 h. Mass gain measurement, x-ray diffraction, scanning electron microscopy, and energy dispersive x-ray spectroscopy are used to study the corrosion behavior. Results reveal that corrosion behavior follows a sequence, that is, first rapidly proceeding, then gradually slowing down, and finally forming an outer layer composed of different types of oxides and an inner layer mainly comprised of sulfides. In-depth analysis reveals that the hot corrosion of FGH100 is a combined effect of oxidation-sulfidation and transfer of oxides.

  2. The effects of thermomechanical history on the microstructure of a nickel-base superalloy during forging

    Energy Technology Data Exchange (ETDEWEB)

    Gardner, S., E-mail: 485354@swansea.ac.uk [College of Engineering, Bay Campus, Swansea University, Swansea SA1 8EN (United Kingdom); Li, W. [Rolls-Royce plc, PO Box 31, Derby DE24 8BJ (United Kingdom); Coleman, M. [College of Engineering, Bay Campus, Swansea University, Swansea SA1 8EN (United Kingdom); Johnston, R., E-mail: r.johnston@swansea.ac.uk [College of Engineering, Bay Campus, Swansea University, Swansea SA1 8EN (United Kingdom)

    2016-06-21

    The effect of thermo-mechanical history on hot compression behaviour and resulting microstructures of a nickel base superalloy is presented. Hot compression tests were carried out on HAYNES® 282® specimens to varying strains from 0.1 to 0.8. Both single pass and multi-pass tests were completed. 60 min inter-pass times were utilized to accurately replicate industrial forging practices. The effect of dynamic, metadynamic and static recrystallization during inter-pass times on flow stress was investigated. The resulting microstructures were analysed using scanning electron, optical microscopy and EBSD to relate grain size and homogeneity with flow stress data. The study showed a negligible difference between multi-pass and single pass tests for strain increments above 0.2. Therefore, when modelling similar low strain and strain rate forging processes in HAYNES® 282®, previous forging steps can be ignored.

  3. Temperature dependence of gamma-gamma prime lattice mismatch in nickel-base superalloys

    Science.gov (United States)

    Nathal, M. V.; Mackay, R. A.; Garlick, R. G.

    1985-01-01

    High temperature X-ray diffraction techniques were used to determine the gamma-gamma prime lattice mismatch of three different nickel-base superalloys at temperatures between 18 and 1000 C. The measurements were performed on oriented single-crystal disks which had been aged to produce a semicoherent gamma-gamma prime structure. The thermal expansion of the lattice parameters of the gamma and gamma-prime phases was described by a second-order polynomial expression. The expansion of the gamma-prime phase was consistently smaller than that of the gamma phase, which caused the lattice mismatch to become more negative at higher temperatures. It was also shown that high values of lattice mismatch resulted in increased rates of directional gamma-prime coarsening during elevated temperature creep exposure.

  4. The development of directional coarsening of the gamma-prime precipitate in superalloy single crystals

    Science.gov (United States)

    Mackay, R. A.; Ebert, L. J.

    1983-01-01

    A study has been made of the kinetics of the directional coarsening of the gamma-prime precipitates in Ni-5.8Al-14.6Mo-6.2Ta single crystals during creep at 982 C. In this alloy, which is characterized by a large negative lattice misfit between the gamma-prime precipitate and the gamma matrix, the formation of gamma-prime rafts begins during primary creep, and the rafts grow in length as the deformation proceeds into steady-state creep. After that, the length of the rafts stabilizes. The thickness of the rafts remains constant from primary up to tertiary creep. The directional coarsening behavior of the alloy studied is similar to that of a more conventional single-crystal superalloy having a substantially smaller negative misfit.

  5. Analysis of gamma prime shape changes in a single crystal Ni-base superalloy

    Science.gov (United States)

    Gayda, J.; Mackay, R. A.

    1989-01-01

    The microstructural evolution of a commercial single crystal superalloy, NASAIR 100, is analyzed using the existing high-temperature lattice mismatch data and high-temperature moduli obtained from tests on single crystals of gamma and gamma prime. A multiparticle analysis of the microstructural evolution is performed using a novel microstructural lattice simulation technique, MCFET. Under a uniaxial stress, a regular array of gamma prime particles in the simulated microstructure is predicted to coalesce and form a plate morphology, with the broad faces of the plates and stress axis perpendicular in tension but parallel in compression. These results are consistent with changes in gamma prime shape observed in NASAIR 100 following creep testing at 1000 C.

  6. Determination of thermophysical and structural properties of nickel super-alloy

    Directory of Open Access Journals (Sweden)

    S. Zlá

    2015-10-01

    Full Text Available In this work the differential thermal analysis (DTA was selected for the study of 718Plus super-alloy. Particular attention was paid to determination of the phase transformation temperatures (liquidus, γ´ precipitation temperature, etc.. Almost at all temperatures of samples an undercooling was observed. Shifting of almost all temperatures was observed in the heating/cooling mode towards higher values with an increasing rate of heating, lower values with the increasing cooling rate. On the basis of DTA and structural analysis it may be stated that development of phase transformations will probably correspond to the following scheme: melting → γ phase; melting → γ + MC (NbC, TiC; melting + MC → γ + Laves + σ; γ → γ´ (γ´´.

  7. Fouling and the inhibition of salt corrosion. [hot corrosion of superalloys

    Science.gov (United States)

    Deadmore, D. L.; Lowell, C. E.

    1980-01-01

    In an attempt to reduce fouling while retaining the beneficial effects of alkaline earth inhibitors on the hot corrosion of superalloys, the use of both additives and the intermittent application of the inhibitors were evaluated. Additions of alkaline earth compounds to combustion gases containing sodium sulfate were shown to inhibit hot corrosion. However, sulfate deposits can lead to turbine fouling in service. For that reason, dual additives and intermittant inhibitor applications were evaluated to reduce such deposit formation. Silicon in conjunction with varium showed some promise. Total deposition was apparently reduced while the inhibition of hot corrosion by barium was unimpaired. The intermittant application of the inhibitor was found to be more effective and controllable.

  8. Recent Advances in Creep Modelling of the Nickel Base Superalloy, Alloy 720Li

    Directory of Open Access Journals (Sweden)

    Steve Williams

    2013-03-01

    Full Text Available Recent work in the creep field has indicated that the traditional methodologies involving power law equations are not sufficient to describe wide ranging creep behaviour. More recent approaches such as the Wilshire equations however, have shown promise in a wide range of materials, particularly in extrapolation of short term results to long term predictions. In the aerospace industry however, long term creep behaviour is not critical and more focus is required on the prediction of times to specific creep strains. The current paper illustrates the capability of the Wilshire equations to recreate full creep curves in a modern nickel superalloy. Furthermore, a finite-element model based on this method has been shown to accurately predict stress relaxation behaviour allowing more accurate component lifing.

  9. Development of superalloys by powder metallurgy for use at 1000 - 1400 F

    Science.gov (United States)

    Calhoun, C. D.

    1971-01-01

    Consolidated powders of four nickel-base superalloys were studied for potential application as compressor and turbine discs in jet engines. All of the alloys were based on the Rene' 95 chemistry. Three of these had variations in carbon and A12O3 contents, and the fourth alloy was chemically modified to a higher volume fraction. The A12O3 was added by preoxidation of the powders prior to extrusion. Various levels of four experimental factors (1) alloy composition, (2) grain size, (3) thermomechanical processing, and (4) room temperature deformation plus final age were evaluated by tensile and stress rupture testing at 1200 F. Various levels of the four factors were assumed in order to construct the statistically-designed experiment, but the actual levels investigated were established in preliminary studies that preceded the statistical process development study.

  10. Factors affecting the corrosion fatigue life in nickel based superalloys for disc applications

    Directory of Open Access Journals (Sweden)

    Rosier Hollie

    2014-01-01

    Full Text Available The nickel based superalloy 720Li is employed in the gas turbine due to its mechanical performance at elevated temperature. A comprehensive assessment of the materials behaviour under representative service conditions is reported to address the drive for ever increasing temperatures and more arduous environmental exposure. Fatigue experiments have been performed in an air and air/SOx environment at 700 ∘C containing a mixed salt as a contaminant. There is an intimate relationship between local salt level (flux, stress level and stress state, i.e. static or cyclic. The interaction with these variables with the work hardened layer present on the surface of all tested specimens as a result of the shot peening process directly affects the crack initiation process. If specific conditions of environment and stress are achieved, a significant reduction in fatigue life is observed.

  11. Inclusion size effect on the fatigue crack propagation mechanism and fracture mechanics of a superalloy

    Science.gov (United States)

    Denda, Takeshi; Bretz, Perter L.; Tien, John K.

    1992-02-01

    Low cycle fatigue life of nickel-base superalloys is enhanced as a consequence of inclusion reduction in the melt process; however, the functional dependencies between fatigue characteristics and inclusions have not been well investigated. In this study, the propagation mechanism of the fatigue crack initiated from inclusions is examined in fine-grained IN718, which is a representative turbine disc material for jet engines. There is a faceted-striated crack transition on the fracture surfaces. This faceted-striated transition also appears in the da/dN vs crack length curves. It is observed that the faceted crack propagation time can be more than 50 pct of total lifetime in the low cycle fatigue test. The significance of inclusion size effect is explained on the premise that the faceted fatigue crack propagation time scales with the inclusion size, which is taken as the initial crack length. A predictive protocol for determining inclusion size effect is given.

  12. High temperature creep properties of directionally solidified CM-247LC Ni-based superalloy

    Energy Technology Data Exchange (ETDEWEB)

    Chiou, Mau-Sheng [Department of Materials Science and Engineering, I-Shou University, Kaohsiung 840, Taiwan (China); Jian, Sheng-Rui, E-mail: srjian@gmail.com [Department of Materials Science and Engineering, I-Shou University, Kaohsiung 840, Taiwan (China); Yeh, An-Chou [Department of Materials Science and Engineering, National Tsing Hua University, Hsinchu 300, Taiwan (China); Kuo, Chen-Ming [Department of Mechanical and Automation Engineering, I-Shou University, Kaohsiung 840, Taiwan (China); Juang, Jenh-Yih [Department of Electrophysics, National Chiao Tung University, Hsinchu 300, Taiwan (China)

    2016-02-08

    This study explores the effects of cooling rate after solution heat treatment on the high temperature/low stress (982 °C/200 MPa) creep properties of CM-247LC Nickel base superalloy. Cooling rate was controlled by blowing argon gas, air cooling, and furnace cooling, which, in turn, gave rise to corresponding cooling rates (from 1260 °C to 800 °C) of 18.7, 7.4, and 0.19 °C/s, respectively. The results indicated that higher cooling rate from the solution heat treatment temperature led to finer γ′ precipitates and much improved tertiary creep as well as rupture life time in high-temperature creep test. The microstructural analyses using both scanning electron microscopy (SEM) and transmission electron microscopy (TEM) revealed that finer γ′ precipitates and narrower γ channel width could result in denser rafting structure which might have hindered the climb of dislocations across the precipitates rafts.

  13. Formation of Minor Phases in a Nickel-Based Disk Superalloy

    Science.gov (United States)

    Gabb, T. P.; Garg, A.; Miller, D. R.; Sudbrack, C. K.; Hull, D. R.; Johnson, D.; Rogers, R. B.; Gayda, J.; Semiatin, S. L.

    2012-01-01

    The minor phases of powder metallurgy disk superalloy LSHR were studied. Samples were consistently heat treated at three different temperatures for long times to approximate equilibrium. Additional heat treatments were also performed for shorter times, to then assess non-equilibrium conditions. Minor phases including MC carbides, M23C6 carbides, M3B2 borides, and sigma were identified. Their transformation temperatures, lattice parameters, compositions, average sizes and total area fractions were determined, and compared to estimates of an existing phase prediction software package. Parameters measured at equilibrium sometimes agreed reasonably well with software model estimates, with potential for further improvements. Results for shorter times representing non-equilibrium indicated significant potential for further extension of the software to such conditions, which are more commonly observed during heat treatments and service at high temperatures for disk applications.

  14. Effects of Thermal Exposure on Structures of DD6 Single Crystal Superalloy with Thermal Barrier Coatings

    Directory of Open Access Journals (Sweden)

    DONG Jianmin

    2016-10-01

    Full Text Available In order to investigate the effect of water grit-blasting and high temperature thermal exposure on the microstructures of DD6 alloy with TBCs, DD6 single crystal superalloy specimens were water grit-blasted with 0.3 MPa pressure, then the specimens were coated with thermal barrier coatings by electron beam physical vapor deposition (EB-PVD. Specimens with TBCs were exposed at 1100℃ for 50 and 100 hours in the air respectively, and then these specimens were subjected to stress-rupture tests under the condition of 1100℃/130 MPa. The results show that grit-blasting doesn't lead into the recrystallization, thermal exposure can induce element interdiffusion between the bond coat and alloy substrate, the residual stress and element diffusion lead into the changes of γ' phase coarsing direction. After stress rupture tests, the secondary reaction zone emerges into a local area.

  15. Oxidation and thermal fatigue of EB-PVD thermal barrier coatings on tube superalloy substrate

    Institute of Scientific and Technical Information of China (English)

    GAO Yu; ZHANG Chun-xia; ZHOU Chun-gen; GONG Sheng-kai; XU Hui-bin

    2006-01-01

    Two-layer structure thermal barrier coatings (TBCs) (NiCoCrAlY (bond coat)+(6%-8%, mass fraction) Y2O3-stabilized ZrO2(YSZ top coat)) were deposited by electron beam physical vapor deposition (EB-PVD) on tube superalloy substrates. The samples were investigated by isothermal oxidation and thermal shock tests. It is found that the mass gains of the substrate with and without TBCs are 0.165 and 7.34 mg/cm2, respectively. So the TBCs system is a suitable protection for the substrate. In thermal shock tests the vertical cracks initiate at the top coat and grow into the bond coat, causing the oxidation of the bond coat along the cracks. Failure of the TBCs system occurs by the spallation of the YSZ from the bond coat, and some micro-cracks are found at the location where the fragment of the YSZ top coat spalled from.

  16. Development of a Nickel-base Cast Superalloy with High Strength and Superior Creep Properties

    Institute of Scientific and Technical Information of China (English)

    Jieshan HOU; Jianting GUO; Lanzhang ZHOU; Zhijun LI

    2005-01-01

    Derived from Russian alloy CHS88U, six experimental Ni-base alloys named as A to F in the Ni-Cr-Co-W-Ti-Al-Hf system are designed, evaluated and processed. One of these alloys, F, shows excellent high temperature tensile strength and ductility with superior creep rupture properties. As predicted by using modeling tools such as PHACOM and NEW PHACOMP, there is hardly the tendency for formation of topologically close-packed phase (TCP) phase in alloy F. Furthermore, through microstructural observation, it is also found that no TCP phase is formed in alloy F after long-time exposure at high temperature. So alloy F has well balance of phase stability and mechanical properties in view of application for gas turbines. It is proved that d-electron approach can be applied for design and development of nickel-base superalloys for gas turbine application.

  17. Desulphurization during VIM Refining Ni-base Superalloy using CaO Crucible

    Institute of Scientific and Technical Information of China (English)

    2003-01-01

    The variation of S content during VIM refining Ni-base superalloy using CaO crucible was stud[ed. It was foundthat the desulphurization process could not be carried out by only using CaO crucible. The role of Al additionto desulphurization was also studied. Combining with the results of XRD and composition analysis of the CaOcrucible, the mechanism of desulphurization was proposed. Thermodynamical calculation about the reaction betweenthe interface of CaO crucible and liquid metal has been discussed. This work indicated that under proper refiningtechnology the S content in the liquid Ni-base alloy could be reduced from 3×10-5 to 2×10-6~4×10-6.

  18. Structure-property effects of tantalum additions to nickel-base superalloys

    Science.gov (United States)

    Heckel, R. W.; Pletka, B. J.; Koss, D. A.; Jackson, M. R.

    1982-01-01

    The characterization of the effect of Ta on the structure of Ni base superalloys, the determination of the effects of Ta (structure) variations on the mechanical, thermal, and oxidation behavior, and the identification of alloying elements which have potential as substitutes for Ta are investigated. Mar M247 type alloys are emphasized; nominal and analyzed compositions of ten alloys under study are given. X-ray and composition analysis are being used to determine the partitioning of alloying elements between gamma, gamma primes, and MC (cubic) as a function of Ta content. The diffusional interactions of the Mar M247-type alloys with as cast beta + gamma alloys are studied to determine the effects of Ta on alloy/coating degradation.

  19. Study on the hot corrosion behavior of a cast Ni-base superalloy

    Energy Technology Data Exchange (ETDEWEB)

    Wang, W.; Guo, J.T.; Zhang, J.; Yuan, C.; Zhou, L.Z.; Hu, Z.Q. [Chinese Academy of Sciences, Shenyang (China). Inst. of Metal Research

    2010-07-01

    Hot corrosion behavior of Nickel-base cast superalloy K447 in 90% Na{sub 2}SO{sub 4} + 10% NaCl melting salt at 850 C and 900 C was studied. The hot corrosion kinetic of the alloy follows parabolic rate law under the experimental conditions. The external layer is mainly Cr{sub 2}O{sub 3} scale which is protective to the alloy, the intermediate layer is the Ti-rich phase, and the internal layer is mainly the international oxides and sulfides. With increased corrosion time and temperature, the oxide scales are gradually dissolved in the molten salt and then precipitate as a thick and non-protective scale. Chlorides cause the formation of volatile species, which makes the oxide scale disintegrate and break off. The corrosion kinetics and morphology examinations tend to support the basic dissolution model for hot corrosion mechanisms. (orig.)

  20. Low Cycle and Thermo-Mechanical Fatigue of Friction Welded Dissimilar Superalloys Joint

    Science.gov (United States)

    Sakaguchi, Motoki; Sano, Atsushi; Tran, Tra Hung; Okazaki, Masakazu; Sekihara, Masaru

    The high temperature strengths of the dissimilar friction welded superalloys joint between the cast polycrystalline Mar-M247 and the forged IN718 alloys have been investigated under low cycle and thermo-mechanical fatigue loadings, in comparison with those of the base metals. The experiments showed that the lives of the dissimilar joints were significantly influenced by the test conditions and loading modes. Not only the lives themselves but also the failure positions and mechanisms were sensitive to the loading mode. The fracture behaviors depending on the loading modes and test conditions were discussed, based on the macroscopic elastic follow-up mechanism and the microstructural inhomogeneity in the friction weld joint.

  1. Oxidation assisted intergranular cracking under loading at dynamic strain aging temperatures in Inconel 718 superalloy

    Energy Technology Data Exchange (ETDEWEB)

    Rezende, M.C., E-mail: monica_crezende@hotmail.com [Universidade Federal do Rio de Janeiro, Departamento de Engenharia Metalúrgica e de Materiais, C.P. 68505, Rio de Janeiro 21945-970 (Brazil); Araújo, L.S.; Gabriel, S.B. [Universidade Federal do Rio de Janeiro, Departamento de Engenharia Metalúrgica e de Materiais, C.P. 68505, Rio de Janeiro 21945-970 (Brazil); Dille, J. [Université Libre de Bruxelles, 4MAT Department, Av. F. Roosevelt 50, C.P. 194/03, Brussels (Belgium); Almeida, L.H. de [Universidade Federal do Rio de Janeiro, Departamento de Engenharia Metalúrgica e de Materiais, C.P. 68505, Rio de Janeiro 21945-970 (Brazil)

    2015-09-15

    Highlights: • Mechanical properties are controlled by DSA, precipitation hardening and OAIC. • Between 600 and 700 °C the critical strain for serrations increases with temperature. • This is related to the consumption of matrix elements (especially Nb: for γ′ and γ″). • A reduction in ductility occurs (related to the OAIC) when the DSA is no longer effective. • This reduction is accompanied by an increase in intergranular brittle fracture. - Abstract: It is well established that 718 superalloy exhibits brittle intergranular cracking when deformed under tension at temperatures above 600 °C. This embrittlement effect is related with grain boundary penetration by oxygen (Oxygen Assisted Intergranular Cracking – OAIC). Simultaneously, impacting on its mechanical properties, the precipitation of coherent γ′ and γ″ phases occur above 650 °C and Dynamic Strain Aging (DSA) occurs in the temperature range between 200 and 800 °C. Although literature indicates that OAIC is the mechanism that controls mechanical properties at high temperatures, its interactions with DSA and precipitation are still under discussion. The objective of this work is to investigate the interactions between the embrittlement phenomena (OAIC and DSA) and the hardening mechanism of γ′ and γ″ precipitation on the mechanical properties of an annealed 718 superalloy. Tensile tests were performed at a strain rate of 3.2 × 10{sup −4} s{sup −1} under secondary vacuum, in temperatures ranging from 200 to 800 °C. Fracture surfaces were observed by scanning electron microscopy (SEM) and precipitation by transmission electron microscopy (TEM). The effect of DSA and precipitation on the strength and of OAIC on the ductility was verified.

  2. Microstructural evolution of directionally solidified DZ125 superalloy castings with different solidification methods

    Directory of Open Access Journals (Sweden)

    Ge Bingming

    2013-01-01

    Full Text Available The properties of Ni-base superalloy castings are closely related to the uniformity of their as-cast microstructure, and different solidification methods have serious effect on microstructural uniformity. In this paper, the influences of high rate solidification (HRS process (with or without superheating and liquid metal cooling (LMC process on the microstructure of DZ125 superalloy were investigated. Blade-shape castings were solidified at rates of 40 μm·s-1 to 110 μm·s-1 using HRS process and a comparative experiment was carried out at a rate of 70 μm·s-1 by LMC process. The optical microscope (OM, scanning electron microscope (SEM were used to observe the microstructure and the grain size was analyzed using electron back scattered diffraction (EBSD technique. Results show that for the castings by either HRS or LMC process, the primary dendrite arm spacing and size of γ' precipitates decrease with increasing the withdrawal rate; the dendrites and γ' precipitates at the upper section of the blade are coarser than those in the middle, especially for the HRS castings without high superheating technique. When the withdrawal rate is 70 μm·s-1, the castings by HRS with high superheating technique have the smallest PDAS with fine γ' precipitates; while the size distribution of γ' precipitates is more homogenous in LMC castings, and the number of larger grains in LMC castings is smaller than that in the HRS castings. Moreover, high superheating technique yields smaller grains in the castings. Both the LMC method and HRS with high superheating technique can be used to prepare castings with reduced maximum grain size.

  3. Influence of composition on microstructural parameters of single crystal nickel-base superalloys

    Energy Technology Data Exchange (ETDEWEB)

    MacKay, R.A., E-mail: Rebecca.A.MacKay@nasa.gov [NASA Glenn Research Center, 21000 Brookpark Rd., Cleveland, Ohio 44135 (United States); Gabb, T.P. [NASA Glenn Research Center, 21000 Brookpark Rd., Cleveland, Ohio 44135 (United States); Garg, A. [NASA Glenn Research Center, 21000 Brookpark Rd., Cleveland, Ohio 44135 (United States); University of Toledo, 2801 W. Bancroft, Toledo, Ohio 43606 (United States); Rogers, R.B.; Nathal, M.V. [NASA Glenn Research Center, 21000 Brookpark Rd., Cleveland, Ohio 44135 (United States)

    2012-08-15

    Fourteen nickel-base superalloy single crystals containing a range of chromium (Cr), cobalt (Co), molybdenum (Mo), and rhenium (Re) levels, and fixed amounts of aluminum (Al) and tantalum (Ta), were examined to determine the effect of bulk composition on basic microstructural parameters, including {gamma} Prime solvus, {gamma} Prime volume fraction, topologically close-packed (TCP) phases, {gamma} and {gamma} Prime phase chemistries, and {gamma}-{gamma} Prime lattice mismatch. Regression models describing the influence of bulk alloy composition on each of the microstructural parameters were developed and compared to predictions by a commercially-available software tool that used computational thermodynamics. Co produced the largest change in {gamma} Prime solvus over the wide compositional range explored and Mo produced the biggest effect on the {gamma} lattice parameter over its range, although Re had a very potent influence on all microstructural parameters investigated. Changing the Cr, Co, Mo, and Re contents in the bulk alloy had an impact on their concentrations in the {gamma} matrix and to a smaller extent in the {gamma} Prime phase. The software tool under-predicted {gamma} Prime solvus temperatures and {gamma} Prime volume fractions, and over-predicted TCP phase volume fractions at 982 Degree-Sign C. However, the statistical regression models provided excellent estimations of the microstructural parameters and demonstrated the usefulness of such formulas. - Highlights: Black-Right-Pointing-Pointer Effects of Cr, Co, Mo, and Re on microstructure in new low density superalloys Black-Right-Pointing-Pointer Co produced a large change in {gamma} Prime solvus; Mo had a large effect on lattice mismatch. Black-Right-Pointing-Pointer Re exhibited very potent influence on all microstructural parameters was investigated. Black-Right-Pointing-Pointer {gamma} and {gamma} Prime phase chemistries both varied with temperature and alloy composition. Black

  4. Creep and residual mechanical properties of cast superalloys and oxide dispersion strengthened alloys

    Science.gov (United States)

    Whittenberger, J. D.

    1981-01-01

    Tensile, stress-rupture, creep, and residual tensile properties after creep testing were determined for two typical cast superalloys and four advanced oxide dispersion strengthened (ODS) alloys. The superalloys examined included the nickel-base alloy B-1900 and the cobalt-base alloy MAR-M509. The nickel-base ODS MA-757 (Ni-16CR-4Al-0.6Y2O3 and the iron-base ODS alloy MA-956 (Fe-20Cr-5Al-0.8Y2O3) were extensively studied, while limited testing was conducted on the ODS nickel-base alloys STCA (Ni-16Cr-4.5Al-2Y2O3) with a without Ta and YD-NiCrAl (Ni-16Cr-5Al-2Y2O3). Elevated temperature testing was conducted from 114 to 1477 K except for STCA and YD-NiCrAl alloys, which were only tested at 1366 K. The residual tensile properties of B-1900 and MAR-M509 are not reduced by prior creep testing (strains at least up to 1 percent), while the room temperature tensile properties of ODS nickel-base alloys can be reduced by small amounts of prior creep strain (less than 0.5 percent). The iron-base ODS alloy MA-956 does not appear to be susceptible to creep degradation at least up to strains of about 0.25 percent. However, MA-956 exhibits unusual creep behavior which apparently involves crack nucleation and growth.

  5. Environment assisted crack growth in nickel-base superalloys at elevated temperature

    Science.gov (United States)

    Evans, Jeffrey Lee

    The environmental effect on the fatigue crack growth rate of Ni-base superalloys at elevated temperature was evaluated in this study. A set of crack growth tests was performed on the turbine disk alloy ME3 at 704°C (1300°F) in vacuum and in air at 0 and 10 second hold times using two microstructures developed with two different cooling rates from the solution heat treat temperature. Fatigue crack growth tests were also conducted at 25°C (77°F) with the two microstructures. Also, a set of oxidation experiments was conducted in order to evaluate the high temperature oxidation behavior of ME3. The microstructure was analyzed and the main differences between the two cooling rates were in the amounts of minor phase particles and size of secondary gamma prime particles. The crack growth rate results suggest that there is no measurable effect of environment or microstructure at room temperature. For the tests conducted in air at elevated temperature, both hold time and microstructural effects were evident. A coupling effect was also observed between the microstructure and the environment. The samples that were slow cooled, and had larger secondary gamma prime particles, had slower crack growth rates and less intergranular fracture in air than the fast cooled samples. A possible explanation for this would be excess free chromium available along grain boundaries due to its low solubility in gamma prime, providing for greater oxidation resistance. An elevated temperature fatigue crack growth rate model for Ni-base superalloys is also proposed.

  6. LCF- and LCF/HCF-behaviour of the superalloy MAR-M247LC

    Energy Technology Data Exchange (ETDEWEB)

    Gelmedin, Domnin; Lang, Karl-Heinz [Karlsruhe Institute of Technology (KIT), Karlsruhe (Germany). Inst. fuer Werkstoffkunde I

    2010-07-01

    The fatigue behaviour of the Nickel-base superalloy Mar-M247LC was investigated at 650 C in air environment under total strain control. Pure low cycle fatigue (LCF) loading, pure high cycle fatigue (HCF) loading and superimposed LCF/HCF loading were realised. In LCF tests with a strain ratio of zero and a hold time of 60 seconds the cyclic deformation and the lifetime behaviour was investigated. The dependence of the fatigue limit on the mean strain was estimated in HCF tests at a frequency of 60 Hz using an ultimate number of cycles of ten million. Finally the influence of superimposed HCF and LCF loadings was examined. At high total strain ranges of the HCF loading the lifetime of the superalloy as reduced about more than one magnitude compared to the lifetime under pure LCF loading. With decreasing HCF loadings the reduction of the lifetime decreases. This life time reduction can be explained by the interaction of the LCF and the superimposed HCF loading. Crack initiation and first crack propagation is predominantly induced by the LCF loading. After reaching an adequate long fatigue crack length the superimposed HCF loading contributes considerably to the crack growth. This contribution can be determined evaluating the distance between the LCF marking lines which form on the fracture surface. The higher the superimposed HCF loading was the longer the distance between the LCF marking lines and the lower the crack length were when first LCF marking lines could be recognized. On the basis of this cognition the life time under superimposed LCF/HCF loading was modelled using a model basing on fracture mechanics. (orig.)

  7. Solutioning and Aging of MAR-M247 Nickel-Based Superalloy

    Science.gov (United States)

    Baldan, Renato; da Rocha, Rafaela Lisboa Pereira; Tomasiello, Rafael Bogado; Nunes, Carlos Angelo; da Silva Costa, Alex Matos; Barboza, Miguel Justino Ribeiro; Coelho, Gilberto Carvalho; Rosenthal, Ruben

    2013-09-01

    Despite the existence of previous studies on the heat treatment of the MAR-M247 superalloy, there is a lack of microstructural characterization data that support the heat-treatment conditions that are proposed in this study. Thus, the aim of this study is to investigate the changes in microstructure that occur in this alloy when subjected to different solutioning and aging heat treatments. Thermodynamic calculations and differential thermal analysis guided the experimental design and the analysis of experimental results. The MAR-M247 superalloy was produced via vacuum induction melting and investment casting. The samples were solutioned between 1185 and 1270 °C and aged between 770 and 980 °C. The as-cast and heat-treated samples were characterized using scanning electron microscopy in backscattered electron and secondary electron modes. Thermodynamic calculations have shown that the minimum solutioning temperature is approximately 1220 °C, occurring in a γ + MC + MB2 three-phase field (M = metal). The samples were solutioned at 1250 °C for 310 min before aging heat treatment. During solutioning the carbide composition is the MC phase shifts to higher hafnium (Hf) and lower tantalum (Ta) content, which is in agreement with the thermodynamics calculations. After solutioning, residual aluminum (Al) segregation leads to the formation of large γ' particles in certain regions of the material following one-step aging heat treatment at 770 and 870 °C. However, a nearly uniform size distribution of γ' particles was observed after aging at 980 °C as well as after double aging heat treatment at 980 °C for 300 min + 870 °C for 1200 min.

  8. Aging of a New Niobium-Modified MAR-M247 Nickel-Based Superalloy

    Science.gov (United States)

    Baldan, Renato; Azevedo e Silva, Paulo Ricardo Soares; Nunes, Carlos Angelo; Coelho, Gilberto Carvalho

    2013-08-01

    MAR-M247 is a nickel-based superalloy that contains 3 wt.% Ta (weight percent of tantalum). Considering the chemical similarity between tantalum and niobium (Nb) and the lower cost of Nb, a modified MAR-M247 superalloy was produced with total replacement of Ta by Nb in this work. The samples were previously solutioned at 1260°C for 8 h and then aged at different times (between 5 and 80 h) and temperatures (between 780 and 980°C). The microstructures of the aged samples were characterized with a scanning electron microscope (SEM and FEG-SEM, both with EDS). Simulations of the MC carbide and γ' fraction and the Ta and Nb content in both MC carbide and γ' phase were performed with Thermo-Calc software (TT_Ni8 database) and simulations of the γ' growth rate and γ' mean diameter were performed with JMatPro software. MC carbide with high Hf content was observed in all the aged samples, in agreement with thermodynamic simulation results. The equilibrium γ' fraction decreases from 67 mol.% at 780°C to 52 mol.% at 980°C. Good agreement between the calculated and experimentally determined γ' particle size was also found. The growth rate of γ' at 980°C is about 8 times higher than that at 780°C and 3 times higher than that at 880°C. The hardness values do not change considerably after aging at 780 and 880°C. However, these values decrease significantly after aging at 980°C.

  9. The influence of gamma prime on the recrystallization of an oxide dispersion strengthened superalloy - MA 6000E

    Science.gov (United States)

    Hotzler, R. K.; Glasgow, T. K.

    1982-01-01

    The requirement of large, recrystallized, highly elongated grains is of primary importance to the development of suitable high temperature properties in oxide dispersion strengthened-superalloys. In the present study the recrystallization behavior of MA 6000E, a recently developed Y2O3 strengthened superalloy produced by mechanical alloying, was examined using transmission and replication microscopy. Gradient and isothermal annealing treatments were applied to extruded and hot rolled products. It was found that conversion from a very fine (0.2 micron) grain structure to a coarse (approximately 10 mm) grain structure is controlled by the dissolution of the gamma prime phase, while grain shape was controlled primarily by the thermal gradient. The fine uniform oxide dispersion appeared to have only a secondary influence in determining the grain shape as columnar grains could be grown transverse to the working direction by appropriate application of the thermal gradient.

  10. On Post-Weld Heat Treatment of a Single Crystal Nickel-Based Superalloy Joint by Linear Friction Welding

    Directory of Open Access Journals (Sweden)

    T. J. Ma

    2015-09-01

    Full Text Available Three types of post-weld heat treatment (PWHT, i.e. solution treatment + primary aging + secondary aging (I, secondary aging (II, and primary aging + secondary aging (III, were applied to a single crystal nickel-based superalloy joint made with linear friction welding (LFW. The results show that the grains in the thermomechanically affected zone (TMAZ coarsen seriously and the primary γ' phase in the TMAZ precipitates unevenly after PWHT I. The primary γ' phase in the TMAZ and weld zone (WZ precipitates insufficiently and fine granular secondary γ' phase is observed in the matrix after PWHT II. After PWHT III, the primary γ' phase precipitates more sufficiently and evenly compared to PWHTs I and II. Moreover, the grains in the TMAZ have not coarsened seriously and fine granular secondary γ' phase is not found after PWHT III. PWHT III seems more suitable to the LFWed single crystal nickel-based superalloy joints when performing PWHT.

  11. Comparative Investigation of the Downward and Upward Directionally Solidified Single-Crystal Blades of Superalloy CMSX-4

    Science.gov (United States)

    Wang, Fu; Ma, Dexin; Bogner, Samuel; Bührig-Polaczek, Andreas

    2016-05-01

    Single-crystal blades of Ni-base superalloys CMSX-4 have been directionally solidified using the downward directional solidification (DWDS) process. The possible benefits of the process were comparatively evaluated with respect to the Bridgman process' results. The DWDS process exhibits good capabilities for casting the single-crystal components. The thermal gradients of this process are approximately seven times higher than those of the Bridgman process. It provides more advantages for solidifying the single-crystal superalloy blades by reducing the casting defects, refining the microstructure, decreasing the size of the γ/ γ' eutectic pools, refining the γ' precipitates, alleviating the degree of the microsegregation, and minimizing the size and volume fraction of the micropores.

  12. The influence of heat treatment on properties of cold rolled alloyed steel and nickel superalloys sheets used in aircraft industry

    Science.gov (United States)

    Zaba, K.; Dul, I.; Puchlerska, S.

    2017-02-01

    Superalloys based on nickel and selected steels are widely used in the aerospace industry, because of their excellent mechanical properties, heat resistance and creep resistance. Metal sheets of these materials are plastically deformed and applied, inter alia, to critical components of aircraft engines. Due to their chemical composition these materials are hardly deformable. There are various methods to improve the formability of these materials, including plastic deformation at an elevated or high temperature, or a suitable heat treatment before forming process. The paper presents results of the metal sheets testing after heat treatment. For the research, sheets of two types of nickel superalloys type Inconel and of three types of steel were chosen. The materials were subjected to multivariate heat treatment at different temperature range and time. After this step, mechanical properties were examined according to the metal sheet rolling direction. The results were compared and the optimal type of pre-trial softening heat treatment for each of the materials was determined.

  13. Age-hardening and precipitation phenomena in the Inconel-713C superalloy studied by means of positron lifetime spectroscopy

    Energy Technology Data Exchange (ETDEWEB)

    Somoza, A.; Santos, G.; Ges, A. [Buenos Aires Univ. Nacional (Argentina). Facultad de Ciencias Exactas y Naturales; Versaci, R.; Plazaola, F.

    1999-07-16

    Specimens of the commercial superalloy Inconel-713C were heat treated by using isothermal artificial ageing treatments in order to obtain information on the process of precipitation of the {gamma}'-phase which is an intermetallic compound with a composition of Ni{sub 3}(Al, Ti) having a L1{sub 2}-ordered structure. The experimental information was basically obtained by means of positron lifetime spectroscopy and Vickers microhardness. In some specific cases, transmission electron microscopy was also used. From the positron results it was possible to analyze the influence of the homogenization and quenching procedures on the microstructure and to follow the coarsening of the smallest {gamma}'-particles during the very early stage of artificial ageing at 950 C. For long ageing times, when the overageing condition of the superalloy was clearly observed by a hardness decrease, the positron lifetime evolution reaches a stable maximum value and different annihilation mechanisms were discussed. (orig.)

  14. Resource-saving technologies of making advanced cast and deformable superalloys with allowance for processing all types of wastes

    Science.gov (United States)

    Kablov, E. N.; Sidorov, V. V.; Kablov, D. E.; Min, P. G.; Rigin, V. E.

    2016-12-01

    The results of thermodynamic analysis of the vacuum-melt-ceramic system and experimental investigations of using up to 100% wastes during vacuum-induction melting are presented. An important role of rare-earth and alkaline-earth metals and heat treatment is shown for effective refining of a melt from impurities and gases. As a result, a resource-saving technology of making advanced cast and deformable nickel superalloys is developed with allowance for processing all types of wastes, including off-grade wastes. The developed technology of refining wastes under vacuum makes it possible to manufacture the alloys that fully meet the requirements of alloy specifications from 100% wastes. This technology is now used for the mass production of nickel superalloys in a research complex at FGUP VIAM.

  15. The Microstructure of RR1000 Nickel-Base Superalloy: The FIB-SEM Dual-Beam Approach

    Science.gov (United States)

    Croxall, S. A.; Hardy, M. C.; Stone, H. J.; Midgley, P. A.

    Nickel-base superalloys are aerospace materials that exhibit exceptional mechanical properties and corrosion resistance at very high temperatures. RR1000 is used in discs in gas turbine engines, where temperatures reach in excess of 650°C with high mechanical stresses. Study of the microstructure at the micron and sub-micron level has conventionally been undertaken using scanning electron microscope images, often meaning the underlying 3D microstructure can be inferred only with additional knowledge. Using a dual-beam workstation, we are able to interrogate directly the 3D microstructure using a serial sectioning approach. The 3D data set, typically (10µm)3 in volume, reveals microstructural detail with lateral resolution of circa 8nm and a depth resolution dictated by the slice thickness, typically 50nm. Morphological and volumetric analysis of the 3D reconstruction of RR1000 superalloy reveals microstructural details hitherto unseen.

  16. Automated detection and characterization of microstructural features: application to eutectic particles in single crystal Ni-based superalloys

    Science.gov (United States)

    Tschopp, M. A.; Groeber, M. A.; Fahringer, R.; Simmons, J. P.; Rosenberger, A. H.; Woodward, C.

    2010-03-01

    Serial sectioning methods continue to produce an abundant amount of image data for quantifying the three-dimensional nature of material microstructures. Here, we discuss a methodology to automate detecting and characterizing eutectic particles taken from serial images of a production turbine blade made of a heat-treated single crystal Ni-based superalloy (PWA 1484). This method includes two important steps for unassisted eutectic particle characterization: automatically identifying a seed point within each particle and segmenting the particle using a region growing algorithm with an automated stop point. Once detected, the segmented eutectic particles are used to calculate microstructural statistics for characterizing and reconstructing statistically representative synthetic microstructures for single crystal Ni-based superalloys. The significance of this work is its ability to automate characterization for analysing the 3D nature of eutectic particles.

  17. Some notes on taxonomic methodology

    NARCIS (Netherlands)

    Hammen, van der L.

    1986-01-01

    The present paper constitutes an introduction to taxonomic methodology. After an analysis of taxonomic practice, and a brief survey of kinds of attributes, the paper deals with observation, description, comparison, arrangement and classification, hypothesis construction, deduction, model, experiment

  18. Lecture Notes: Approximate Molecular Orbital Theory

    DEFF Research Database (Denmark)

    Spanget-Larsen, Jens

    2015-01-01

    Lecture Notes for the introductory course "Quantum Chemistry & Spectroscopy" (Dept. Science, Roskilde University)......Lecture Notes for the introductory course "Quantum Chemistry & Spectroscopy" (Dept. Science, Roskilde University)...

  19. Oxide-assisted crack growth in hold-time low-cycle-fatigue of single-crystal superalloys

    Directory of Open Access Journals (Sweden)

    Suzuki Akane

    2014-01-01

    Full Text Available Compressive hold-time low-cycle fatigue is one of the important damage modes in Ni-based superalloy hot-gas path components. In strain controlled LCF, the compressive hold typically degrades fatigue life significantly due to creep relaxation and the resultant generation of tensile stress upon returning to zero strain. Crack initiation typically occurs on the surface, and therefore, the cracks are covered with layers of oxides. Recent finite element modeling based on experimental observations has indicated that the in-plane compressive stress in the alumina layer formed on the surface of the bond coat assists rumpling and, eventually, leads to initiation of cracks. The stress in the oxide layer continues to assist crack extension by pushing the alumina layer along the crack front during the compressive hold. In-situ measurements of the growth strains of alumina were performed using high energy synchrotron X-rays at Argonne National Lab. Specimens of single-crystal superalloys with and without aluminide coatings were statically pre-oxidized to form a layer of alumina at 1093 and 982 ∘C. For the in-situ synchrotron measurements, the specimens were heated up to the pre-oxidation temperatures with a heater. The alumina layers on both bare and coated specimens show compressive in-plane strains at both temperatures. The oxide strains on the superalloys showed dependency on temperature; on the other hand, the oxide strains in the aluminide coatings were insensitive to temperature. The magnitude of the compressive strains was larger on the superalloys than the ones on the aluminide coatings.

  20. Damage in nickel base superalloy: Influence of local parameters measured by electron backscattered diffraction and atomic force microscopy

    Energy Technology Data Exchange (ETDEWEB)

    Risbet, M. [Laboratoire Roberval, UMR 6253 UTC-CNRS, Universite de Technologie de Compiegne, BP 20529-60205 Compiegne cedex (France)], E-mail: marion.risbet@utc.fr; Feaugas, X. [Laboratoire d' Etude des Materiaux en Milieux Agressifs, EA 3127, Universite de La Rochelle, 17000 La Rochelle cedex (France); Guillemer-Neel, C. [Laboratoire de Technologies Innovantes, EA 3899, IUT Genie Mecanique d' Amiens, 80025 Amiens Cedex (France); Clavel, M. [Laboratoire Mecanique des Sols, Structures et Materiaux, UMR 8579 CNRS, Ecole Centrale Paris, 92295 Chatenay-Malabry Cedex (France)

    2009-03-15

    The low-cycle fatigue behaviour of a nickel-based superalloy has been investigated with regard to its surface damage features. This alloy endures localized plastic deformation confined in slip bands emerging as extrusions. The correlations between damage, grain orientation, the Schmid factor of slip systems and the height of extrusions have been questioned. It is proved here that reaching a critical height value is not a sufficient condition for an extrusion to induce the apparition of a transgranular crack.

  1. Effect of a Transverse Magnetic Field on Stray Grain Formation of Ni-Based Single Crystal Superalloy During Directional Solidification

    Science.gov (United States)

    Xuan, Weidong; Liu, Huan; Lan, Jian; Li, Chuanjun; Zhong, Yunbo; Li, Xi; Cao, Guanghui; Ren, Zhongming

    2016-08-01

    The effect of a transverse magnetic field on stray grain formation during directional solidification of superalloy was investigated. Experimental results indicated that the transverse magnetic field effectively suppressed the stray grain formation on the side the primary dendrite diverges from the mold wall. Moreover, the quenched experimental results indicated that the solid/liquid interface shape was obviously changed in a transverse magnetic field. The effect of a transverse magnetic field on stray grain formation was discussed.

  2. Crack initiation and propagation induced by inclusions in a nickel-base P/M superalloy under fatigue load

    Institute of Scientific and Technical Information of China (English)

    ZENG Yanping; ZHANG Maicang; DONG Jianxin; ZHANG Lina; XIE Xishan

    2005-01-01

    In situ fatigue tests in special designed SEM were conducted to trace the whole process of crack initiation and propagation till to fracture in nickel-base P/M superalloy seeded inclusions. The experimental results show that non-metallic inclusions can induce crack initiation. When the inclusion size is larger than the critical one, the crack can propagate as the main crack that induces the specimen to fracture. As a result, the LCF life of the specimen decreases.

  3. Effects of cobalt concentration on the relative resistance to octahedral and cube slip in nickle-base superalloys

    Science.gov (United States)

    Bobeck, Gene E.; Miner, R. V.

    1988-01-01

    Compression yielding tests were performed at 760 C on crystals of the Ni base superalloys Rene 150 and a modified MAR-M247, both having two different Co concentrations. For both alloy bases, increasing Co concentration was shown to decrease the critical resolved shear stress for octahedral slip, but to have little effect on that for cube slip. The results suggest that decreasing complex stacking fault energy in the gamma-prime with increasing Co could account for the observed effects.

  4. Effect of solidification parameters on the secondary dendrite arm spacing in MAR M-247 superalloy determined by a novel approach

    OpenAIRE

    Milenkovic S.; Rahimian M.; Sabirov I.; Maestro L.

    2014-01-01

    The effect of solidification parameters on the secondary dendrite arm spacing in a MAR-M247 Ni-based superalloy has been studied by a novel approach, based on physical simulation of melting/solidification experiment with a constant cooling rate and variable temperature gradient. The applied experimental method proved to be efficient as it yielded a spread of microstructures corresponding to a range of well controlled solidification rates in a single melting/solidification experiment. In addit...

  5. Technical note on drainage systems

    DEFF Research Database (Denmark)

    Bentzen, Thomas Ruby

    This technical note will present simple but widely used methods for the design of drainage systems. The note will primarily deal with surface water (rainwater) which on a satisfactorily way should be transport into the drainage system. Traditional two types of sewer systems exist: A combined system......’s not major different than described below - just remember to include this contribution for combined systems where the surface water (rain) and sewage are carried in the same pipes in the system and change some of the parameters for failure allowance (this will be elaborated further later on). The technical...

  6. Note

    DEFF Research Database (Denmark)

    Kullman, Mikael; Campillo, Javier; Dahlquist, Erik

    2016-01-01

    , innovative, behavioural and structural capacities of European medium-sized cities in their transition towards Energy Smart Cities. The variation of strengths and weaknesses of cities’ capabilities as well as practices and tools for enhancing energy efficient performance of urban energy systems were......Globally, more than 50% of all people are living in cities today. Enhancing sustainability and efficiency of urban energy systems is thus of high priority for global sustainable development. The European research project PLEEC (Planning for Energy Efficient Cities) focuses on technological...

  7. Interdiffusion behavior between NiAlHf coating and Ni-based single crystal superalloy with different crystal orientations

    Energy Technology Data Exchange (ETDEWEB)

    Wang, Ruili; Gong, Xueyuan [School of Materials Science and Engineering, Beihang University (BUAA), No. 37, Xueyuan Road, Beijing 100191 (China); Peng, Hui [School of Materials Science and Engineering, Beihang University (BUAA), No. 37, Xueyuan Road, Beijing 100191 (China); Beijing Key Laboratory for Advanced Functional Material and Thin Film Technology, Beihang University (BUAA), No. 37, Xueyuan Road, Beijing 100191 (China); Key Laboratory of Aerospace Materials and Performance (Ministry of Education), Beihang University (BUAA), No. 37, Xueyuan Road, Beijing 100191 (China); Ma, Yue, E-mail: mayue@buaa.edu.cn [School of Materials Science and Engineering, Beihang University (BUAA), No. 37, Xueyuan Road, Beijing 100191 (China); Beijing Key Laboratory for Advanced Functional Material and Thin Film Technology, Beihang University (BUAA), No. 37, Xueyuan Road, Beijing 100191 (China); Key Laboratory of Aerospace Materials and Performance (Ministry of Education), Beihang University (BUAA), No. 37, Xueyuan Road, Beijing 100191 (China); Guo, Hongbo, E-mail: guo.hongbo@buaa.edu.cn [School of Materials Science and Engineering, Beihang University (BUAA), No. 37, Xueyuan Road, Beijing 100191 (China); Beijing Key Laboratory for Advanced Functional Material and Thin Film Technology, Beihang University (BUAA), No. 37, Xueyuan Road, Beijing 100191 (China); Key Laboratory of Aerospace Materials and Performance (Ministry of Education), Beihang University (BUAA), No. 37, Xueyuan Road, Beijing 100191 (China)

    2015-01-30

    Highlights: • The interdiffusion behavior between the NiAlHf coating and the superalloy substrate was influenced by the crystal orientation of the substrate alloy. • The structure of TCP phases formed in SRZ and IDZ was studied. • Studying the effect of orientation crystal of substrate on the formation of SRZ. - Abstract: NiAlHf coatings were deposited onto Ni-based single crystal (SC) superalloy with different crystal orientations by electron beam physical vapor deposition (EB-PVD). The effects of the crystal orientations of the superalloy substrate on inter-diffusion behavior between the substrate and the NiAlHf coating were investigated. Substrate diffusion zone (SDZ) containing needle-like μ phases and interdiffusion zone (IDZ) mainly consisting of the ellipsoidal and rod-like μ phases were formed in the SC alloy after heat-treatment 10 h at 1100 °C. The thickness of secondary reaction zone (SRZ) formed in the SC alloy with (0 1 1) crystal orientation is about 14 μm after 50 h heat-treatment at 1100 °C, which is relatively thicker than that in the SC alloy with (0 0 1) crystal orientation, whereas the IDZ revealed similar thickness.

  8. Slow Strain Rate Tensile Testing to Assess the Ability of Superalloys to Resist Environment-Assisted Intergranular Cracking

    Science.gov (United States)

    Gabb, Timothy P.; Telesman, Jack; Banik, Anthony; McDevitt, Erin

    2014-01-01

    Intergranular fatigue crack initiation and growth due to environmental degradation, especially at notched features, can often limit the fatigue life of disk superalloys at high temperatures. For clear comparisons, the effects of alloy composition on cracking in air needs to be understood and compared separately from variables associated with notches and cracks such as effective stress concentration, plastic flow, stress relaxation, and stress redistribution. The objective of this study was to attempt using simple tensile tests of specimens with uniform gage sections to compare the effects of varied alloy composition on environment-assisted cracking of several powder metal and cast and wrought superalloys including ME3, LSHR, Udimet 720, ATI 718Plus alloy, Haynes 282, and Inconel 740. Slow and fast strain-rate tensile tests were found to be a useful tool to compare propensities for intergranular surface crack initiation and growth. The effects of composition and heat treatment on tensile fracture strain and associated failure modes were compared. Environment interactions were determined to often limit ductility, by promoting intergranular surface cracking. The response of various superalloys and heat treatments to slow strain rate tensile testing varied substantially, showing that composition and microstructure can significantly influence environmental resistance to cracking.

  9. Oxidation behavior and mechanism of powder metallurgy Rene95 nickel based superalloy between 800 and 1000 deg. C

    Energy Technology Data Exchange (ETDEWEB)

    Zheng Lei, E-mail: zhenglei_ustb@sina.com [School of Materials Science and Engineering, University of Science and Technology Beijing, Beijing 10083 (China); Zhang Maicang; Dong Jianxin [School of Materials Science and Engineering, University of Science and Technology Beijing, Beijing 10083 (China)

    2010-10-01

    The oxidation behaviors of powder metallurgy (PM) Rene95 Ni-based superalloy in the temperature range of 800-1000 deg. C are investigated in air by virtue of isothermal oxidation testing, X-ray diffraction, scanning electron microscopy and energy dispersive X-ray spectroscopy. The results show that the oxidation kinetics follows a square power law as the time extends at each temperature. The oxidation layers are detected to be composed of Cr{sub 2}O{sub 3}, TiO{sub 2} and a small amount of NiCr{sub 2}O{sub 4}. The cross-sectional morphologies indicate that the oxidation layer consists of three parts: Cr-rich oxide layer, Cr and Ti duplex oxide layer, and oxidation affected zone. Theoretical analyses of oxidation kinetics and thicknesses of oxidation layers confirm that the activation energy of oxidation of PM Rene95 superalloy is 165.32 kJ mol{sup -1} and the oxidation process is controlled by diffusions of oxygen, Cr, and Ti. Accordingly, a diffusion-controlled mechanism is suggested to understand the oxidation behaviors of PM Rene95 superalloy at elevated temperatures.

  10. A Note on Hamiltonian Graphs

    Science.gov (United States)

    Skurnick, Ronald; Davi, Charles; Skurnick, Mia

    2005-01-01

    Since 1952, several well-known graph theorists have proven numerous results regarding Hamiltonian graphs. In fact, many elementary graph theory textbooks contain the theorems of Ore, Bondy and Chvatal, Chvatal and Erdos, Posa, and Dirac, to name a few. In this note, the authors state and prove some propositions of their own concerning Hamiltonian…

  11. EUCAST technical note on posaconazole

    NARCIS (Netherlands)

    Arendrup, M.C.; Cuenca-Estrella, M.; Donnelly, J.P.; Hope, W.; Lass-Florl, C.; Rodriguez-Tudela, J.L.

    2011-01-01

    The European Committee on Antimicrobial Susceptibility Testing-Subcommittee on Antifungal Susceptibility Testing (EUCAST-AFST) has determined breakpoints for posaconazole for Candida spp. This Technical Note is based on the EUCAST posaconazole rationale document (available on the EUCAST website: htt

  12. Churchill on Stalin: A note.

    NARCIS (Netherlands)

    Ellman, M.J.

    2006-01-01

    The purpose of this note is to draw attention to two limitations of Churchill's war memoirs as a source of accurate information about Stalin, his views ans actions. they concern, first Stalin's alleged remarks in 1942 about collectivisation, and second Stalin's allleged response to Churchill's propo

  13. Applied Fluid Mechanics. Lecture Notes.

    Science.gov (United States)

    Gregg, Newton D.

    This set of lecture notes is used as a supplemental text for the teaching of fluid dynamics, as one component of a thermodynamics course for engineering technologists. The major text for the course covered basic fluids concepts such as pressure, mass flow, and specific weight. The objective of this document was to present additional fluids…

  14. Notes on absolute Hodge classes

    CERN Document Server

    Charles, François

    2011-01-01

    We survey the theory of absolute Hodge classes. The notes include a full proof of Deligne's theorem on absolute Hodge classes on abelian varieties as well as a discussion of other topics, such as the field of definition of Hodge loci and the Kuga-Satake construction.

  15. A brief note regarding randomization.

    Science.gov (United States)

    Senn, Stephen

    2013-01-01

    This note argues, contrary to claims in this journal, that the possible existence of indefinitely many causal factors does not invalidate randomization. The effect of such factors has to be bounded by outcome, and since inference is based on a ratio of between-treatment-group to within-treatment-group variation, randomization remains valid.

  16. Churchill on Stalin: A note.

    NARCIS (Netherlands)

    Ellman, M.J.

    2006-01-01

    The purpose of this note is to draw attention to two limitations of Churchill's war memoirs as a source of accurate information about Stalin, his views ans actions. they concern, first Stalin's alleged remarks in 1942 about collectivisation, and second Stalin's allleged response to Churchill's propo

  17. A Note on Hurwitzian Numbers

    NARCIS (Netherlands)

    Kraaikamp, C.; Hartono, Y.

    2002-01-01

    In this note Hurwitzian numbers are defined for the nearest integer, and backward continued fraction expansions, and Nakada's $\\alpha$-expansions. It is shown that the set of Hurwitzian numbers for these continued fractions coincides with the classical set of such numbers.

  18. Applied Fluid Mechanics. Lecture Notes.

    Science.gov (United States)

    Gregg, Newton D.

    This set of lecture notes is used as a supplemental text for the teaching of fluid dynamics, as one component of a thermodynamics course for engineering technologists. The major text for the course covered basic fluids concepts such as pressure, mass flow, and specific weight. The objective of this document was to present additional fluids…

  19. Lecture Notes on Multigrid Methods

    Energy Technology Data Exchange (ETDEWEB)

    Vassilevski, P S

    2010-06-28

    The Lecture Notes are primarily based on a sequence of lectures given by the author while been a Fulbright scholar at 'St. Kliment Ohridski' University of Sofia, Sofia, Bulgaria during the winter semester of 2009-2010 academic year. The notes are somewhat expanded version of the actual one semester class he taught there. The material covered is slightly modified and adapted version of similar topics covered in the author's monograph 'Multilevel Block-Factorization Preconditioners' published in 2008 by Springer. The author tried to keep the notes as self-contained as possible. That is why the lecture notes begin with some basic introductory matrix-vector linear algebra, numerical PDEs (finite element) facts emphasizing the relations between functions in finite dimensional spaces and their coefficient vectors and respective norms. Then, some additional facts on the implementation of finite elements based on relation tables using the popular compressed sparse row (CSR) format are given. Also, typical condition number estimates of stiffness and mass matrices, the global matrix assembly from local element matrices are given as well. Finally, some basic introductory facts about stationary iterative methods, such as Gauss-Seidel and its symmetrized version are presented. The introductory material ends up with the smoothing property of the classical iterative methods and the main definition of two-grid iterative methods. From here on, the second part of the notes begins which deals with the various aspects of the principal TG and the numerous versions of the MG cycles. At the end, in part III, we briefly introduce algebraic versions of MG referred to as AMG, focusing on classes of AMG specialized for finite element matrices.

  20. The effects of Mg microaddition on the mechanical behavior and fracture mechanism of MAR-M247 superalloy at elevated temperatures

    Science.gov (United States)

    Bor, H. Y.; Chao, C. G.; Ma, C. Y.

    1999-03-01

    The effects of microadditions of Mg on the mechanical behavior and fracture mechanism of MAR-M247 superalloy were investigated in this study. The microstructural observations and image analysis showed that a Mg microaddition ranging from 30 to 80 ppm significantly changed the primary MC carbide characteristics and inhibited the scriptlike carbide formation. After a 80 ppm Mg addition, the elongation measured at 1172 K increased over 3 times found that for the Mg-free MAR-M247 superalloy. The creep life and rupture elongation of the MAR-M247 superalloy with 80 ppm Mg was also improved up to 3 to 5 times that of the alloy without Mg during a 1033 K/724 MPa creep test. The fracture analyses demonstrated that cracks were mainly initiated and propagated at the interface of scriptlike MC carbides in the Mg-free MAR-M247 superalloy at elevated temperatures. The Mg microaddition effectively refined and spheroidized these coarse carbides so that a change in the crack initiation occurred from the carbide/matrix interface to that along the γ-γ' eutectic. Interfacial analysis using Auger electron spectroscopy illustrated that Mg segregated to the interface of the MC carbide/matrix, causing a change in the morphology and interfacial behavior of the carbides. This improvement contributed to a prolonged rupture life and upgraded the moderate temperature ductility of the MAR-M247 superalloy.

  1. Job descriptions made easy.

    Science.gov (United States)

    Miller, Larry

    2014-01-01

    The act of writing a job description can be a daunting and difficult task for many managers. This article focuses on the key concepts of What, How, and Measureable Results as they relate to an employee's job duties. When the answers to these three elements are articulated, they define the core responsibilities of any job that form the basis for an effective job description.

  2. Description logics of context

    CSIR Research Space (South Africa)

    Klarman, S

    2013-05-01

    Full Text Available We introduce Description Logics of Context (DLCs) - an extension of Description Logics (DLs) for context-based reasoning. Our approach descends from J. McCarthy's tradition of treating contexts as formal objects over which one can quantify...

  3. Descriptive set theory

    CERN Document Server

    Moschovakis, YN

    1987-01-01

    Now available in paperback, this monograph is a self-contained exposition of the main results and methods of descriptive set theory. It develops all the necessary background material from logic and recursion theory, and treats both classical descriptive set theory and the effective theory developed by logicians.

  4. Note---Naive Diversification and Portfolio Risk---A Note

    OpenAIRE

    Ron Bird; Mark Tippett

    1986-01-01

    A number of authors have used the portfolio standard deviation to model the risk reduction advantages of naive diversification. Other authors have pointed out that when risk is modelled by the portfolio's variance the modelling process becomes much simpler and is computationally more efficient. In this note we derive an exact parametric relationship between portfolio standard deviation and size and thus highlight the dangers of using the standard deviation in conjunction with O.L.S. regressio...

  5. A note on conversational interruptions A note on conversational interruptions

    OpenAIRE

    Anthony F. Deyes

    2008-01-01

    In their seminal article, Sacks, Schegloff and Jefferson (1974) examine procedures for turn-taking in conversation. Sometimes, they note, a s peaker will select who has the next turn, but more frequently a "self-select" system operates, whereby the participants in a conversation themselves determine when they wish to speak. But how, ask Sacks, Schegloff and Jefferson, do the interlocutors secure a turn in the ongoing flow of another speaker's utterance? To answer this question the author...

  6. 32 CFR 806b.5 - Personal notes.

    Science.gov (United States)

    2010-07-01

    ... 32 National Defense 6 2010-07-01 2010-07-01 false Personal notes. 806b.5 Section 806b.5 National... Overview of the Privacy Act Program § 806b.5 Personal notes. The Privacy Act does not apply to personal notes on individuals used as memory aids. Personal notes may become Privacy Act records if they...

  7. Kindergarten Quantum Mechanics lectures notes

    CERN Document Server

    Coecke, B

    2005-01-01

    These lecture notes survey some joint work with Samson Abramsky as it was presented by me at several conferences in the summer of 2005. It concerns `doing quantum mechanics using only pictures of lines, squares, triangles and diamonds'. This picture calculus can be seen as a very substantial extension of Dirac's notation, and has a purely algebraic counterpart in terms of so-called Strongly Compact Closed Categories (introduced by Abramsky and I in quant-ph/0402130 and [4]) which subsumes my Logic of Entanglement quant-ph/0402014. For a survey on the `what', the `why' and the `hows' I refer to a previous set of lecture notes quant-ph/0506132. In a last section we provide some pointers to the body of technical literature on the subject.

  8. Grain boundary engineering of powder-processed Ni-base superalloy RR1000

    Science.gov (United States)

    Detrois, Martin

    Grain boundary engineering (GBE) has been used to improve the properties of various polycrystalline materials by optimization of their grain boundary network. Traditional processing routes for GBE often require multiple iterations of cold work followed by short annealing cycles where each iteration imparts a modest increase in the fraction of special grain boundaries. Multiple iterations are then required to achieve sufficiently high fractions (>50%) that result in the improved properties. Thus, this GBE approach is not suitable for the fabrication of large, complex-shaped structures and leads to added manufacturing lead time and cost. In this investigation, the Ni-base superalloy RR1000 used as turbine discs in gas turbine engines manufactured by Rolls-Royce, was considered for GBE using alternative processing routes more suitable to the forging of Ni-base superalloy components. A preliminary study of the effects of hot deformation parameters closer to typical industrial processing revealed that the length fraction of Sigma3 boundaries increased from 35% to 52% following a single deformation/anneal cycle. Deformation parameters that resulted in strain accommodation via superplastic flow did not enhance the formation of Sigma3 boundaries upon annealing. Whereas deformation parameters that resulted in a dominant dislocation-based plasticity flow mechanism promoted the formation of annealing twins. Using misorientation maps and by estimating the stored strain energy from deformation, equations for the length fraction and density of Sigma3 boundaries were generated for high-temperature GBE of RR1000. The grain boundary characters obtained via high-temperature deformation, however, are less ideal than those resulting from traditional cold rolling. The underlying mechanisms responsible for the formation of Sigma3n boundaries during high-temperature GBE were further investigated. A larger starting grain size prior to deformation was found to be unfavorable to the

  9. Effect of Slag on Titanium, Silicon, and Aluminum Contents in Superalloy During Electroslag Remelting

    Science.gov (United States)

    Jiang, Zhou-Hua; Hou, Dong; Dong, Yan-Wu; Cao, Yu-Long; Cao, Hai-Bo; Gong, Wei

    2016-04-01

    Many factors influence the chemical composition in electroslag remelting (ESR) steel, including atmosphere in crucible, melting rate, slag composition, deoxidation, and so on. Fluoride-based slag, which is exposed to liquid metal directly, influences the chemical composition of ESR ingots to a large extent. The present paper focuses on the effect of slag on the titanium, silicon, and aluminum contents in ingots based on the interaction of the slag and metal. In present work, superalloy of GH8825 and several slags containing different CaO contents have been employed for investigating the effect of slag on titanium, silicon, and aluminum contents in an electrical resistance furnace under argon atmosphere. Results indicate that the higher CaO content in slag has better capacity for avoiding loss of titanium caused by the reaction of titanium with silica in slag, especially in case of remelting superalloy with high titanium and low silicon content. The CaO has a great effect on the activities of TiO2, SiO2, and Al2O3. Thermodynamic analysis is applied to investigate the CaO behavior. Based on the ion and molecule coexistence theory of slag, activity model is established to calculate the activities of components containing titanium, silicon, and aluminum elements in a six-component slag consisting of CaO-CaF2-Al2O3-SiO2-TiO2-MgO. The components containing titanium, silicon, and aluminum in slag are mainly CaO·TiO2, 2CaO·SiO2, CaO·SiO2, CaO·Al2O3, and MgO·Al2O3. With the increase of CaO mass fraction in slag, the activity coefficient of SiO2 decreases significantly, whereas slightly change happens for Al2O3. As a result, the lg ({{γ_{{{{SiO}}2 }} } {/ {{{γ_{{{{SiO}}2 }} } {γ_{{{{TiO}}2 }} }}} {γ_{{{{TiO}}2 }} }}) decreases with increasing CaO content, which is better for preventing loss of titanium caused by the reaction of titanium with silica in slag. The slag with high CaO and appropriate TiO2 content is suitable for electroslag remelting of GH8825.

  10. Hall coefficient measurement for residual stress assessment in precipitation hardened IN718 nickel-base superalloy

    Science.gov (United States)

    Velicheti, Dheeraj; Nagy, Peter B.; Hassan, Waled

    2017-02-01

    We investigated the feasibility of residual stress assessment based on Hall coefficient measurements in precipitation hardened IN718 nickel-base superalloy. As a first step, we studied the influence of microstructural variations on the galvanomagnetic properties of IN718 nickel-base superalloy. We found that the Hall coefficient of IN718 increases from ≈ 8.0×10-11 m3/C in its fully annealed state of 15 HRC Rockwell hardness to ≈ 9.4×10-11 m3/C in its fully hardened state of 45 HRC. We also studied the influence of cold work, i.e., plastic deformation, at room temperature and found that cold work had negligible effect on the Hall coefficient of fully annealed IN718, but significantly reduced it in hardened states of the material. For example, measurements conducted on fully hardened IN718 specimens showed that the Hall coefficient decreased more or less linearly with cold work from its peak value of ≈ 9.4×10-11 m3/C in its intact state to ≈ 9.0×10-11 m3/C in its most deformed state of 22% plastic strain. We also studied the influence of applied stress and found that elastic strain significantly increases the Hall coefficient of IN718 regardless of the state of hardening. The relative sensitivity of the Hall coefficient to elastic strain was measured as a unitless gauge factor K that is defined as the ratio of the relative change of the Hall coefficient ΔRH/RH divided by the axial strain ɛ = σ/E, where σ is the applied uniaxial stress and E is the Young's modulus of the material. We determined that the galvanomagnetic gauge factor of IN718 is κ ≈ 2.6 - 2.9 depending on the hardness level. Besides the fairly high value of the gauge factor, it is important that it is positive, which means that compressive stress in surface-treated components decreases the Hall coefficient in a similar way as plastic deformation does, therefore the unfortunate cancellation that occurs in fully hardened IN718 in the case of electric conductivity measurements will not

  11. Near-surface residual stresses and microstructural changes after turning of a nickel-based superalloy

    Energy Technology Data Exchange (ETDEWEB)

    Schlauer, Christian

    2003-07-01

    Nickel-based superalloys are precipitation hardened alloys with complex compositions. They are used in aircraft engines and land-based gas turbines in load bearing structural components that are exposed to high temperatures. Failure mechanisms in this environment are high and low cycle fatigue, creep, and corrosion. During manufacturing, residual stresses are often introduced into the material due to inhomogeneous plastic deformations, both intentionally and unintentionally. One such manufacturing process is metal cutting, which introduces residual stresses in the surface layer. The stress state in the near-surface zone of components is of special interest as the surface often experiences peak loads and cracks have their starting point there. In this thesis, near-surface residual stress distributions and microstructural changes are studied in the nickel-based superalloy Inconel 718 for two different turning operations, face grooving and facing. Process variables are in both cases cutting speed and feed that have been varied between (10 and 1200) m/min and (0.01 and 0.5) mm, respectively. The first turning technique face grooving, which gives cutting conditions similar to orthogonal cutting, showed a clear dependency of the residual stresses on the cutting speed. The tensile stress at the surface, the maximum compressive stress below the surface, and the thickness of the affected layer increase with increasing cutting speed. The tensile stresses are constrained to a thin surface layer and compressive residual stresses below the surface dominate the depth profile of the residual stresses. Only at low cutting speed, residual stresses were largely avoided. The second turning technique facing confirmed the dependency of the residual stresses on the cutting speed and revealed a similar dependency on the feed. Microstructural investigations of near-surface cross-sections by means of transmission electron microscopy showed a zone where the grains had undergone plastic

  12. Notes on modeling and simulation

    Energy Technology Data Exchange (ETDEWEB)

    Redondo, Antonio [Los Alamos National Lab. (LANL), Los Alamos, NM (United States)

    2017-03-10

    These notes present a high-level overview of how modeling and simulation are carried out by practitioners. The discussion is of a general nature; no specific techniques are examined but the activities associated with all modeling and simulation approaches are briefly addressed. There is also a discussion of validation and verification and, at the end, a section on why modeling and simulation are useful.

  13. Recognizing Exponential Growth. Classroom Notes

    Science.gov (United States)

    Dobbs, David E.

    2004-01-01

    Two heuristic and three rigorous arguments are given for the fact that functions of the form Ce[kx], with C an arbitrary constant, are the only solutions of the equation dy/dx=ky where k is constant. Various of the proofs in this self-contained note could find classroom use in a first-year calculus course, an introductory course on differential…

  14. Lecture Notes on Differential Forms

    OpenAIRE

    2016-01-01

    This is a series of lecture notes, with embedded problems, aimed at students studying differential topology. Many revered texts, such as Spivak's "Calculus on Manifolds" and Guillemin and Pollack's "Differential Topology" introduce forms by first working through properties of alternating tensors. Unfortunately, many students get bogged down with the whole notion of tensors and never get to the punch lines: Stokes' Theorem, de Rham cohomology, Poincare duality, and the realization of various t...

  15. Notes on instrumentation and control

    CERN Document Server

    Roy, G J

    2013-01-01

    Notes on Instrumentation and Control presents topics on pressure (i.e., U-tube manometers and elastic type gauges), temperature (i.e. glass thermometer, bi-metallic strip thermometer, filled system thermometer, vapor pressure thermometer), level, and flow measuring devices. The book describes other miscellaneous instruments, signal transmitting devices, supply and control systems, and monitoring systems. The theory of automatic control and semi-conductor devices are also considered. Marine engineers will find the book useful.

  16. Recognizing Exponential Growth. Classroom Notes

    Science.gov (United States)

    Dobbs, David E.

    2004-01-01

    Two heuristic and three rigorous arguments are given for the fact that functions of the form Ce[kx], with C an arbitrary constant, are the only solutions of the equation dy/dx=ky where k is constant. Various of the proofs in this self-contained note could find classroom use in a first-year calculus course, an introductory course on differential…

  17. Notes on Malay Compositae III

    NARCIS (Netherlands)

    Koster, Joséphine Th.

    1952-01-01

    Among a small collection of Compositae collected in Sumbawa by R. Blomberg, 1941, a new Vernonia was detected. The description follows here. Vernonia sumbavensis Koster, nov. spec. — sectio Claotrachelus (Zoll. et Mor.) Koster (Fig. 1 a—e) — Herba, 60 cm alta, e basi caules plures virgatos, subteret

  18. Lecture Notes on Data Communications,

    Science.gov (United States)

    1981-07-01

    data. - Other Networks - including: SITA, Satnet, Packet Radio network. ( Logica ] ARPAnet. Arpanet was one of the ear’liest packet switched networks... Logica "Packet Switching Report", Logica Ltd, Sept 1978. 0 A good summary of packet switching with descriptions of CCITT X series recommendations... Logica Ltd. National Computing Centre Publications, 1978. .Schwartz "Information Transmission, Modulation and Noise", Mischa Schwartz, Polytechnic

  19. The synchronous improvement of strength and plasticity (SISP) in new Ni-Co based disc superalloys by controling stacking fault energy.

    Science.gov (United States)

    Xu, H; Zhang, Z J; Zhang, P; Cui, C Y; Jin, T; Zhang, Z F

    2017-08-14

    It is a great challenge to improve the strength of disc superalloys without great loss of plasticity together since the microstructures benefiting the strength always do not avail the plasticity. Interestingly, this study shows that the trade-off relationship between strength and plasticity can be broken through decreasing stacking fault energy (SFE) in newly developed Ni-Co based disc superalloys. Axial tensile tests in the temperature range of 25 to 725 °C were carried out in these alloys with Co content ranging from 5% to 23% (wt.%). It is found that the ultimate tensile strength (UTS) and uniform elongation (UE) are improved synchronously when microtwinning is activated by decreasing the SFE at 650 and 725 °C. In contrast, only UTS is improved when stacking fault (SF) dominates the plastic deformation at 25 and 400 °C. These results may be helpful for designing advanced disc superalloys with relatively excellent strength and plasticity simultaneously.

  20. Descrição do girino de Lysapsus laevis (Parker, com notas sobre o ambiente, hábitos e desenvolvimento (Anura, Hylidae, Pseudinae Description of the tadpole of Lysapsus laevis (Parker, with notes on the habitat, habits, and development (Anura, Hylidae, Pseudinae

    Directory of Open Access Journals (Sweden)

    Ulisses Caramaschi

    2004-09-01

    Full Text Available O girino de Lysapsus laevis (Parker, 1935 é descrito e figurado, com base em exemplares coletados na Vila Surumu, Estado de Roraima, Brasil. No estágio 37, o girino possui 61,4 mm de comprimento total; corpo triangular em vista lateral, ovóide em vistas dorsal e ventral, correspondendo a 28% do comprimento total; olhos laterais, parcialmente visíveis em vistas dorsal e ventral; disco oral ânteroventral, pequeno; fórmula dentária, 2(2/3(1; espiráculo curto, sinistro; tubo anal longo, largo, direito, mediano; em vida, dorso do corpo verde, ventre branco iridescente; musculatura caudal e nadadeiras verdes; terço anterior da nadadeira caudal e tubo anal com manchas irregulares iridescentes; metade distal da cauda cinza a cinza escuro; íris bronze. Notas sobre o ambiente, hábitos e desenvolvimento são apresentadas.The tadpole of Lysapsus laevis (Parker, 1935 is described and figured, based on specimens from Vila Surumu, State of Roraima, northern Brazil. In stage 37, the tadpole attains 61.4 mm in total length; body triangular in lateral view, ovoid in dorsal and ventral views, corresponding to 28% of the total length; eyes lateral, partially visible in dorsal and ventral views; oral disc anteroventral, small; labial tooth row formula, 2(2/3(1; spiracle short, sinistral; anal tube large, wide, medium; in life, dorsum of body green, venter iridescent white; caudal musculature and fins green; anterior third of caudal fin and anal tube with irregular iridescent stains; distal half of tail gray to dark gray; iris bronze. Notes on the habitat, habits, and development are provided.