WorldWideScience

Sample records for sulfide emissions abatement

  1. Pricing emission permits in the absence of abatement

    International Nuclear Information System (INIS)

    Hintermann, Beat

    2012-01-01

    If emissions are stochastic and firms are unable to control them through abatement, the cap in a permit market may be exceeded, or not be reached. I derive a binary options pricing formula that expresses the permit price as a function of the penalty for noncompliance and the probability of an exceeded cap under the assumption of no abatement. I apply my model to the EU ETS, where the rapid introduction of the market made it difficult for firms to adjust their production technology in time for the first phase. The model fits the data well, implying that the permit price may have been driven by firms hedging against stochastic emissions.

  2. Pollution Emissions, Environmental Policy, and Marginal Abatement Costs.

    Science.gov (United States)

    He, Ling-Yun; Ou, Jia-Jia

    2017-12-05

    Pollution emissions impose serious social negative externalities, especially in terms of public health. To reduce pollution emissions cost-effectively, the marginal abatement costs (MACs) of pollution emissions must be determined. Since the industrial sectors are the essential pillars of China's economic growth, as well as leading energy consumers and sulfur dioxide (SO₂) emitters, estimating MACs of SO₂ emissions at the industrial level can provide valuable information for all abatement efforts. This paper tries to address the critical and essential issue in pollution abatement: How do we determine the MACs of pollution emissions in China? This paper first quantifies the SO₂ emission contribution of different industrial sectors in the Chinese economy by an Input-Output method and then estimates MACs of SO₂ for industrial sectors at the national level, provincial level, and sectoral level by the shadow price theory. Our results show that six sectors (e.g., the Mining and Washing of Coal sector) should be covered in the Chinese pollution emission trading system. We have also found that the lowest SO₂ shadow price is 2000 Yuan/ton at the national level, and that shadow prices should be set differently at the provincial level. Our empirical study has several important policy implications, e.g., the estimated MACs may be used as a pricing benchmark through emission allowance allocation. In this paper, the MACs of industrial sectors are calculated from the national, provincial and sectoral levels; therefore, we provide an efficient framework to track the complex relationship between sectors and provinces.

  3. Potential Cost-Effective Opportunities for Methane Emission Abatement

    Energy Technology Data Exchange (ETDEWEB)

    Warner, Ethan [Joint Inst. for Strategic Energy Analysis, Golden, CO (United States); Steinberg, Daniel [Joint Inst. for Strategic Energy Analysis, Golden, CO (United States); Hodson, Elke [U.S. Department of Energy, Washington, DC (United States); Heath, Garvin [Joint Inst. for Strategic Energy Analysis, Golden, CO (United States)

    2015-08-01

    The energy sector was responsible for approximately 84% of carbon dioxide equivalent (CO2e) greenhouse gas (GHG) emissions in the U.S. in 2012 (EPA 2014a). Methane is the second most important GHG, contributing 9% of total U.S. CO2e emissions. A large portion of those methane emissions result from energy production and use; the natural gas, coal, and oil industries produce approximately 39% of anthropogenic methane emissions in the U.S. As a result, fossil-fuel systems have been consistently identified as high priority sectors to contribute to U.S. GHG reduction goals (White House 2015). Only two studies have recently attempted to quantify the abatement potential and cost associated with the breadth of opportunities to reduce GHG emissions within natural gas, oil, and coal supply chains in the United States, namely the U.S. Environmental Protection Agency (EPA) (2013a) and ICF (2014). EPA, in its 2013 analysis, estimated the marginal cost of abatement for non-CO2 GHG emissions from the natural gas, oil, and coal supply chains for multiple regions globally, including the United States. Building on this work, ICF International (ICF) (2014) provided an update and re-analysis of the potential opportunities in U.S. natural gas and oil systems. In this report we synthesize these previously published estimates as well as incorporate additional data provided by ICF to provide a comprehensive national analysis of methane abatement opportunities and their associated costs across the natural gas, oil, and coal supply chains. Results are presented as a suite of marginal abatement cost curves (MACCs), which depict the total potential and cost of reducing emissions through different abatement measures. We report results by sector (natural gas, oil, and coal) and by supply chain segment - production, gathering and boosting, processing, transmission and storage, or distribution - to facilitate identification of which sectors and supply chain

  4. Particulate emission abatement for Krakow boiler houses

    Energy Technology Data Exchange (ETDEWEB)

    Wysk, R.

    1995-12-31

    Among the many strategies for improving air quality in Krakow, one possible method is to adapt new and improved emission control technology. This project focuses on such a strategy. In order to reduce dust emissions from coal-fueled boilers, a new device called a Core Separator has been introduced in several boiler house applications. This advanced technology has been successfully demonstrated in Poland and several commercial units are now in operation. Particulate emissions from the Core Separator are typically 3 to 5 times lower than those from the best cyclone collectors. It can easily meet the new standard for dust emissions which will be in effect in Poland after 1997. The Core Separator is a completely inertial collector and is based on a unique recirculation method. It can effectively remove dust particles below 10 microns in diameter, the so-called PM-10 emissions. Its performance approaches that of fabric filters, but without the attendant cost and maintenance. It is well-suited to the industrial size boilers located in Krakow. Core Separators are now being marketed and sold by EcoInstal, one of the leading environmental firms in Poland, through a cooperative agreement with LSR Technologies.

  5. Particulate Emission Abatement for Krakow Boilerhouses

    International Nuclear Information System (INIS)

    Hucko, R.E.

    1997-01-01

    Environmental clean-up and pollution control are considered the foremost national priorities in Poland. The target of this cleanup is the Polish coal industry, which supplies the fuel to generate over 78% of Poland's primary energy production. This project addresses the problem of airborne dust and uncontrolled particulate emissions from boilerhouses, which represent a large fraction of the total in Poland. In Krakow alone, there are more than 2,000 uncontrolled boilers accounting for about half the total fuel use. The large number of low-capacity boilers poses both technical and economic challenges, since the cost of control equipment is a significant factor in the reduction of emissions. A new concept in dust collection, called a Core Separator, is proposed for this important application. The Core Separator is an advanced technology developed through research sponsored by the Department of Energy. It utilizes a highly efficient collector, which functions on the principle of inertial separation. The system is able to control fine particulate matter, as in the PMIO regulations, which limit the emission of dust particles below 10 microns in diameter. Its dust removal performance has been shown to be comparable to that of a medium-efficiency electrostatic precipitator (ESP). Yet, its cost is substantially lower than that of either an ESP or fabric filter. While the Core Separator achieves high efficiency, its power consumption is just slightly higher than that of a cyclone. It functions dry and without the aid of energy-consuming enhancements. It is simple, reliable, and unlike the ESP and fabric filter, easy to maintain. This combination of features make it ideal for the small boiler market in the City of Krakow. A highly qualified team has been assembled to execute this project. LSR Technologies, Inc., a technology-based company located in Acton, Massachusetts, is the developer of the Core Separator and holder of its patent rights. LSR has sold several of these

  6. Particulate Emission Abatement for Krakow Boilerhouses

    International Nuclear Information System (INIS)

    Hucko, R.E.

    1997-01-01

    Environmental clean-up and pollution control are considered the foremost national priorities in Poland. The target of this cleanup is the Polish coal industry, which supplies the fuel to generate over 78% of Poland's primary energy production. This project addresses the problem of airborne dust and uncontrolled particulate emissions from boilerhouses, which represent a large fraction of the total in Poland. In Krakow alone, there are more than 2,000 uncontrolled boilers accounting for about half the total fuel use. The large number of low-capacity boilers poses both technical and economic challenges, since the cost of control equipment is a significant factor in the reduction of emissions. A new concept in dust collection, called a Core Separator, is proposed for this important application. The Core Separator is an advanced technology developed through research sponsored by the Department of Energy. It utilizes a highly efficient collector, which functions on the principle of inertial separation. The system is able to control fine particulate matter, as in the PMIO regulations, which limit the emission of dust particles below 10 microns in diameter. Its dust removal performance has been shown to be comparable to that of a medium-efficiency electrostatic precipitator (ESP). Yet, its cost is substantially lower than that of either an ESP or fabric filter. While the Core Separator achieves high efficiency, its power consumption is just slightly higher than that of a cyclone. It functions dry and without the aid of energy-consuming enhancements. It is simple, reliable, and unlike the ESP and fabric filter, easy to maintain. This combination of features make it ideal for the small boiler market in the City of Krakow. A highly qualified team has been assembled to execute this project. LSR Technologies, Inc., a technology-based company located in Acton, Massachusetts, is the developer of the Core Separator and holder of its patent rights. LSR has sold several of these

  7. PARTICULATE EMISSION ABATEMENT FOR KRAKOW BOILERHOUSES

    Energy Technology Data Exchange (ETDEWEB)

    Bruce H. Easom; Leo A, Smolensky; S. Ronald Wysk; Jan Surowka; Miroslaw Litke; Jacek Ginter

    1998-09-30

    A U.S./Polish Bilateral Steering Committee (BSC) and the Department of Energy (DOE) selected LSR Technologies, Inc. as a contractor to participate in the Krakow Clean Fuels and Energy Efficiency Program. The objective of this program was the formation of business ventures between U.S. and Polish firms to provide equipment and services to reduce air emissions in the city of Krakow. A cooperative agreement was entered into by DOE and LSR to begin work in April 1994 involving implementation of particulate control technology called a Core Separator{trademark} for coal-fueled boilerhouses in the city. The major work tasks included: (1) conducting a market analysis, (2) completion of a formal marketing plan, (3) obtaining patent protection within Poland, (4) selecting a manufacturing partner, and (5) completing a demonstration unit and commercial installations. In addition to work performed by LSR Technologies, key contributors to this project were (1) the Polish Foundation for Energy Efficiency (FEWE), a non-profit consulting organization specializing in energy and environmental-related technologies, and (2) EcoInstal, a privately held Polish company serving the air pollution control market. As the project concluded in late 1998, five (5) Core Separator{trademark} installations had been implemented in the city of Krakow, while about 40 others were completed in other regions of Poland.

  8. Tradeable emission permit in Dutch acidification abatement policy

    Energy Technology Data Exchange (ETDEWEB)

    Ruyssenaars, P; Sliggers, J [Ministry of Environment (Netherlands)

    1996-12-31

    Target groups as well as the government are under the spell of economic instruments as part of environmental policy. Under this heading fall (regulatory) taxes and tradeable emission permits (VER). Of the two, VER, particularly, receive a lot of attention. From the target groups, because the flexibility of VER means working cost-effectively, which could lead to cost savings. From the government, because it can have more faith in the viability of emission ceilings, and has less need to pass detailed legislation. The latter conforms nicely to the philosophy `government at arm`s length`. The Ministry of Environment has had a study made on the feasibility of VER in the context of the acidification abatement policy in the Netherlands. The development and implementation of policy concerning acidification abatement is at an advanced stage, with deposition targets already set for 2000 and 2010 (2400 and 1400 acid equivalents/ha/year, respectively, averaged for afforested areas). From these, also emission reduction targets per target group are deduced, which can be used in a VER system. The main starting point of the study was to gain more insight into the practical aspects of VER. One important question is what form a VER system for the Netherlands should have to take. Also, an investigation was made into the activities which are necessary to introduce a VER system as well as the time, manpower and money these activities entail

  9. Tradeable emission permit in Dutch acidification abatement policy

    Energy Technology Data Exchange (ETDEWEB)

    Ruyssenaars, P.; Sliggers, J. [Ministry of Environment (Netherlands)

    1995-12-31

    Target groups as well as the government are under the spell of economic instruments as part of environmental policy. Under this heading fall (regulatory) taxes and tradeable emission permits (VER). Of the two, VER, particularly, receive a lot of attention. From the target groups, because the flexibility of VER means working cost-effectively, which could lead to cost savings. From the government, because it can have more faith in the viability of emission ceilings, and has less need to pass detailed legislation. The latter conforms nicely to the philosophy `government at arm`s length`. The Ministry of Environment has had a study made on the feasibility of VER in the context of the acidification abatement policy in the Netherlands. The development and implementation of policy concerning acidification abatement is at an advanced stage, with deposition targets already set for 2000 and 2010 (2400 and 1400 acid equivalents/ha/year, respectively, averaged for afforested areas). From these, also emission reduction targets per target group are deduced, which can be used in a VER system. The main starting point of the study was to gain more insight into the practical aspects of VER. One important question is what form a VER system for the Netherlands should have to take. Also, an investigation was made into the activities which are necessary to introduce a VER system as well as the time, manpower and money these activities entail

  10. Emissions leakage and subsidies for pollution abatement. Pay the polluter or the supplier of the remedy?

    Energy Technology Data Exchange (ETDEWEB)

    Fischer, Carolyn; Greaker, Mads; Rosendahl, Knut Einar

    2012-07-01

    Asymmetric regulation of a global pollutant between countries can alter the competitiveness of industries and lead to emissions leakage. For most types of pollution, abatement technologies are available for firms to produce with lower emissions. However, the suppliers of those technologies tend to be less than perfectly competitive, particularly when both emissions regulations and advanced technologies are new. In this context of twin market failures, we consider the relative effects and desirability of subsidies for abatement technology. We find a more robust recommendation for upstream subsidies than for downstream subsidies. Downstream subsidies tend to increase global abatement technology prices, reduce pollution abatement abroad and increase emission leakage. On the contrary, upstream subsidies reduce abatement technology prices, and hence also emissions leakage.(Author)

  11. CO2 emissions abatement and geologic sequestration - industrial innovations and stakes - status of researches in progress

    International Nuclear Information System (INIS)

    2005-01-01

    This colloquium was jointly organized by the French institute of petroleum (IFP), the French agency of environmental and energy mastery (Ademe) and the geological and mining research office (BRGM). This press kit makes a status of the advances made in CO 2 emissions abatement and geological sequestration: technological advances of CO 2 capture and sequestration, geological reservoir dimensioning with respect to the problem scale, duration of such an interim solution, CO 2 emissions abatement potentialities of geological sequestration, regulatory, economical and financial implications, international stakes of greenhouse gas emissions. This press kit comprises a press release about the IFP-Ademe-BRGM colloquium, a slide presentation about CO 2 abatement and sequestration, and four papers: a joint IFP-Ademe-BRGM press conference, IFP's answers to CO 2 emissions abatement, Ademe's actions in CO 2 abatement and sequestration, and BRGM's experience in CO 2 sequestration and climatic change expertise. (J.S.)

  12. Solar energy and the abatement of atmospheric emissions

    International Nuclear Information System (INIS)

    Mirasgedis, S.; Diakoulaki, D.; Assimacopoulos, D.

    1996-01-01

    In spite of the fact that solar energy is a ''clean'' energy form, gaseous pollutants are emitted during the manufacturing of the systems necessary for its utilisation. An attempt is made in this paper to estimate the level of atmospheric pollutants emitted during the successive stages which make up the manufacture process for solar water heating (SWH) systems, and to evaluate these results in comparison with the respective pollutant emission levels attributed to the generation of electricity in Greece's conventional power plants. As energy consumption is recognised as the main source of atmospheric pollution, a Life Cycle Analysis (LCA) method was applied, focusing on the most energy-consuming stages of the SWH system production process. The conclusions of the analysis indicate that the emissions of gaseous pollutants associated with the utilisation of solar energy are considerably lower than those caused by the production of electricity in conventional systems, thereby substantiating that solar energy utilisation can make a notable contribution to the abatement of atmospheric pollution. (author)

  13. Future needs for ship emission abatement and technical measures

    Directory of Open Access Journals (Sweden)

    Teresa ANTES

    2013-01-01

    Full Text Available The International Maritime Organization (IMO has revised air pollution regulations in MARPOL Annex VI. In 2012 Emission Control Areas (ECA will limit fuel sulphur content to 1% and from 2015 to 0.1%. NOx emissions based on ships engine speed are also reduced for new vessels (2012 & 2016. Facing this legislation, ship owners have the alternative either to operate ships with costly low-sulphur fuels, or to keep using HFO but together with a gas cleaning equipment at the ship stack in order to reduce the rejected amount of SO2 gas in the atmosphere. To achieve this requirement, research and development organizations came out with proposing a solution that uses a device for cleaning exhaust gas of marine diesel engines. The paper presents a short communication about the DEECON project, which aim is to create a novel on-board after-treatment unit more advanced than any currently available. Each sub-unit of the system will be optimized to remove a specific primary pollutant. In particular, the technology within the DEECON system is based on novel or improved abatement techniques for reducing SOx, NOx, Particulate Matter (PM, CO and Volatile Organic Compounds (VOC. Some of these technologies are completely new for the maritime sector and they will represent a breakthrough in the reduction of the atmospheric emissions of ships, moving forward the performance of exhaust gas cleaning systems and fostering and anticipating the adoption of future and tighter regulatory requirements. In addition, an after-treatment strategy enables the possible adoption of alternative fuels, which often have their own emissions characteristics.

  14. Greenhouse Gas and Ammonia Emissions from Different Stages of Liquid Manure Management Chains: Abatement Options and Emission Interactions.

    Science.gov (United States)

    Mohankumar Sajeev, Erangu Purath; Winiwarter, Wilfried; Amon, Barbara

    2018-01-01

    Farm livestock manure is an important source of ammonia and greenhouse gases. Concerns over the environmental impact of emissions from manure management have resulted in research efforts focusing on emission abatement. However, questions regarding the successful abatement of manure-related emissions remain. This study uses a meta-analytical approach comprising 89 peer-reviewed studies to quantify emission reduction potentials of abatement options for liquid manure management chains from cattle and pigs. Analyses of emission reductions highlight the importance of accounting for interactions between emissions. Only three out of the eight abatement options considered (frequent removal of manure, anaerobic digesters, and manure acidification) reduced ammonia (3-60%), nitrous oxide (21-55%), and methane (29-74%) emissions simultaneously, whereas in all other cases, tradeoffs were identified. The results demonstrate that a shift from single-stage emission abatement options towards a whole-chain perspective is vital in reducing overall emissions along the manure management chain. The study also identifies some key elements like proper clustering, reporting of influencing factors, and explicitly describing assumptions associated with abatement options that can reduce variability in emission reduction estimates. Prioritization of abatement options according to their functioning can help to determine low-risk emission reduction options, specifically options that alter manure characteristics (e.g., reduced protein diets, anaerobic digestion, or slurry acidification). These insights supported by comprehensive emission measurement studies can help improve the effectiveness of emission abatement and harmonize strategies aimed at reducing air pollution and climate change simultaneously. Copyright © by the American Society of Agronomy, Crop Science Society of America, and Soil Science Society of America, Inc.

  15. Emission abatement: Untangling the impacts of the EU ETS and the economic crisis

    International Nuclear Information System (INIS)

    Bel, Germà; Joseph, Stephan

    2015-01-01

    In this study we use historical emission data from installations under the European Union Emissions Trading System (EU ETS) to evaluate the impact of this policy on greenhouse gas emissions during the first two trading phases (2005–2012). As such the analysis seeks to disentangle two causes of emission abatement: that attributable to the EU ETS and that attributable to the economic crisis that hit the EU in 2008/09. To do so, we use a dynamic panel data approach. Our results suggest that, by far, the biggest share of abatement was attributable to the effects of the economic crisis. This finding has serious implications for future policy adjustments affecting core elements of the EU ETS, including the distribution of EU emission allowances. - Highlights: • We untangle the effects of the EU ETS from those of the economic crisis on industrial emission abatement. • The empirical analysis uses verified emission data instead of estimated emission data. • Abatement of emissions in EU in the last years has been mainly due to the impact of the economic crisis. • Low level of abatement attributable to the EU ETS suggests that important changes must be made in environmental policy

  16. A Pedagogical Note on Modeling the Economic Benefit of Emissions Abatement vs. the Economic Harm from Emissions

    OpenAIRE

    Christopher S. Decker

    2012-01-01

    The number of undergraduate-level textbooks on environmental economics has increased in recent years, but the textbook treatment of optimal emissions (abatement) varies markedly from textbook to textbook. In particular, there is no consensus as to whether to model the economic “bad” (i.e. emissions) or the economic “good” (abatement). This inconsistency can lead to some needless confusion for students introduced to environmental economics for the first time, particularly those students outsid...

  17. Reactive Precipitation of Anhydrous Alkali Sulfide Nanocrystals with Concomitant Abatement of Hydrogen Sulfide and Cogeneration of Hydrogen.

    Science.gov (United States)

    Li, Xuemin; Zhao, Yangzhi; Brennan, Alice; McCeig, Miranda; Wolden, Colin A; Yang, Yongan

    2017-07-21

    Anhydrous alkali sulfide (M 2 S, M=Li or Na) nanocrystals (NCs) are important materials central to the development of next generation cathodes and solid-state electrolytes for advanced batteries, but not commercially available at present. This work reports an innovative method to directly synthesize M 2 S NCs through alcohol-mediated reactions between alkali metals and hydrogen sulfide (H 2 S). In the first step, the alkali metal is complexed with alcohol in solution, forming metal alkoxide (ROM) and releasing hydrogen (H 2 ). Next, H 2 S is bubbled through the ROM solution, where both chemicals are completely consumed to produce phase-pure M 2 S NC precipitates and regenerate alcohol that can be recycled. The M 2 S NCs morphology may be tuned through the choice of the alcohol and solvent. Both synthetic steps are thermodynamically favorable (ΔG m o <-100 kJ mol -1 ), proceeding rapidly to completion at ambient temperature with almost 100 % atom efficiency. The net result, H 2 S+2 m→M 2 S+H 2 , makes good use of a hazardous chemical (H 2 S) and delivers two value-added products that naturally phase separate for easy recovery. This scalable approach provides an energy-efficient and environmentally benign solution to the production of nanostructured materials required in emerging battery technologies. © 2017 Wiley-VCH Verlag GmbH & Co. KGaA, Weinheim.

  18. Sulphur dioxide and nitrogen oxides in industrial waste gases: emission, legislation and abatement

    International Nuclear Information System (INIS)

    Velzen, D. van

    1991-01-01

    Contains the proceedings of a Eurocourse held in Ispra in September 1990 concerning SO 2 and NO x emission, abatement and legislation. Aspects covered include: emission sources and quantities; atmospheric chemistry and dispersion of pollutants; European Community air pollution legislation; air pollution control technologies; costs of desulphurization and denoxing; and the situation in the USA and Japan. Individual papers are abstracted separately

  19. The effect of carbon tax on carbon emission abatement and GDP: a case study

    Science.gov (United States)

    Liu, Xiao; Leung, Yee; Xu, Yuan; Yung, Linda Chor Wing

    2017-10-01

    Carbon tax has been advocated as an effective economic instrument for the abatement of CO2 emission by various countries, including China, the world's biggest carbon emission country. However, carbon emission abatement cannot be done while ignoring the impact on economic growth. A delicate balance needs to be achieved between the two to find an appropriate pathway for sustainable development. This paper applies a multi-objective optimization approach to analyze the impact of levying carbon tax on the energy-intensive sectors of Guangdong province in China under the constraint of emission reduction target. This approach allows us to evaluate carbon emission minimization while maximizing GDP. For policy analysis, we construct five scenarios for evaluation and optimal choice. The results of the analysis show that a lower initial carbon tax rate is not necessarily better, and that a carbon tax is an effective means to reduce CO2 emissions while maintaining a certain level of GDP growth.

  20. The emission abatement policy paradox in Australia: evidence from energy-emission nexus.

    Science.gov (United States)

    Ahmed, Khalid; Ozturk, Ilhan

    2016-09-01

    This paper attempts to investigate the emissions embodied in Australia's economic growth and disaggregate primary energy sources used for electricity production. Using time series data over the period of 1990-2012, the ARDL bounds test approach to cointegration technique is applied to test the long-run association among the underlying variables. The regression results validate the long-run equilibrium relationship among all vectors and confirm that CO2 emissions, economic growth, and disaggregate primary energy consumption impact each other in the long-run path. Afterwards, the long- and short-run analyses are conducted using error correction model. The results show that economic growth, coal, oil, gas, and hydro energy sources have positive and statistically significant impact on CO2 emissions both in long and short run, with an exception of renewables which has negative impact only in the long run. The results conclude that Australia faces wide gap between emission abatement policies and targets. The country still relies on emission intensive fossil fuels (i.e., coal and oil) to meet the indigenous electricity demand.

  1. Ammonia emissions from livestock industries in Canada: Feasibility of abatement strategies

    International Nuclear Information System (INIS)

    Carew, Richard

    2010-01-01

    An updated national ammonia (NH 3 ) emissions inventory was employed to study the relationship between NH 3 emissions and livestock industries in Canada. Emissions from animal agriculture accounted for 322 kilotonnes (kt) or 64% of Canadian NH 3 emissions in 2002. Cattle and swine accounted for the bulk of livestock emissions. The provinces of Alberta, Ontario, Quebec, and Saskatchewan accounted for 28.1%, 22.0%, 18.7%, and 13.1% of total livestock emissions, respectively. Emissions from Ontario and Quebec were attributed to the intensive production of dairy, hogs and poultry. Dairy cattle emissions per hectolitre of milk were higher in Ontario and Quebec than in other provinces, while swine emissions per livestock unit were higher than either beef or dairy cattle. A review of the abatement literature indicated diet manipulation to improve N efficiency and land spreading methods are very effective techniques to lower NH 3 emissions. Future research is required to evaluate the feasibility of biofilters and feces/urine separation methods. - Livestock NH 3 emissions are higher in areas characterized by intensive livestock production with diet manipulation and land spreading offering the greatest potential for NH 3 abatement options.

  2. Optimal Coordination Strategy of Regional Vertical Emission Abatement Collaboration in a Low-Carbon Environment

    Directory of Open Access Journals (Sweden)

    Daming You

    2018-02-01

    Full Text Available This study introduces a time factor into a low-carbon context, and supposes the contamination control state of local government and the ability of polluting enterprise to abate emissions as linear increasing functions in a regional low-carbon emission abatement cooperation chain. The local government effectuates and upholds the low-carbon development within the jurisdiction that is primarily seeking to transform regional economic development modes, while the polluting enterprise abates the amounts of emitted carbon in the entire period of product through simplifying production, facilitating decontamination, and adopting production technology, thus leading to less contamination. On that basis, we infer that the coordinated joint carbon reduction model and two decentralization contracts expound the dynamic coordination strategy for a regional cooperation chain in terms of vertical carbon abatement. Furthermore, feedback equilibrium strategies that are concerned with several diverse conditions are compared and analyzed. The main results show that a collaborative centralized contract is able to promote the regional low-carbon cooperation chain in order to achieve a win–win situation in both economic and environmental performance. Additionally, the optimal profits of the entire regional low-carbon cooperation channel under an integration scenario evidently outstrip that of two non-collaborative decentralization schemes. Eventually, the validity of the conclusions is verified with a case description and numerical simulation, and the sensitivity of the relevant parameters is analyzed in order to lay a theoretical foundation and thus facilitate the sustainable development of a regional low-carbon environment.

  3. Freer markets and the abatement of carbon emissions. The electricity-generating sector in India

    International Nuclear Information System (INIS)

    Khanna, Madhu; Zilberman, David

    1999-01-01

    This paper develops a framework to explore the implications of trade and domestic policy distortions for the magnitude of carbon emissions and for the welfare costs of abating these emissions. An application to the electricity-generating sector in India shows that economic policy reforms can also be effective environmental policy instruments and reduce carbon emissions even in the absence of an emissions tax. This reduction in emissions is accompanied by an increase in domestic welfare, an increase in electricity output, and conservation of coal. Coordinating trade and domestic policy reform with an emissions tax policy reduces emissions further, while leading to gains in welfare that are greater than those under an emissions tax policy alone

  4. Abatement of CO2 emissions in the European Union

    International Nuclear Information System (INIS)

    Lesourne, J.; Keppler, J.H.; Jaureguy-Naudin, Maite; Smeers, Yves; Bouttes, Jean-Paul; Trochet, Jean-Michel; Dassa, Francois; Neuhoff, Karsten

    2008-01-01

    This first monograph of the Ifri program on European Governance and Geopolitics of Energy is devoted to the control of carbon dioxide emissions within the European Union. Since it is almost unanimously accepted that Greenhouse Gas emissions constitute the main cause of the observed increase of the world average temperature, the system implemented by the European Union to limit and decrease the CO 2 emissions is a significant pillar of the EU energy policy, the two others being the acceptance by the Member States of long-term commitments (for instance on the future share of renewable energy sources in their energy balance sheet) and the establishment of an internal market for electricity and gas. Though simple in principle, the European Union Greenhouse Gas Emission Trading Scheme (EU ETS) is in fact rather complex, and only experts really understand its merits and its deficiencies. These deficiencies are real and will have to be corrected in the future for the system to be effective. At this moment, when the 2005-2007 trial phase of the EU ETS is ending, the monograph has the purpose to stimulate the discussion between experts and to enable all those interested in the topic to understand the issues and to take part in the public debates on the subject. The monograph contains five papers: - 'An Overview of the CO 2 Emission Control System in the European Union' by Jacques Lesourne and Maite Jaureguy-Naudin. - 'Description and Assessment of EU CO 2 Regulations' by Yves Smeers. - 'Assessment of EU CO 2 Regulations' by Jean-Paul Bouttes, Jean-Michel Trochet and Francois Dassa. - 'Investment in Low Carbon Technologies, Policies for the Power Sector' by Karsten Neuhoff. - 'Lessons Learned from the 2005-2007 Trial Phase of the EU Emission Trading System' by Jan Horst Keppler

  5. Are renewables portfolio standards cost-effective emission abatement policy?

    Science.gov (United States)

    Dobesova, Katerina; Apt, Jay; Lave, Lester B

    2005-11-15

    Renewables portfolio standards (RPS) could be an important policy instrument for 3P and 4P control. We examine the costs of renewable power, accounting for the federal production tax credit, the market value of a renewable credit, and the value of producing electricity without emissions of SO2, NOx, mercury, and CO2. We focus on Texas, which has a large RPS and is the largest U.S. electricity producer and one of the largest emitters of pollutants and CO2. We estimate the private and social costs of wind generation in an RPS compared with the current cost of fossil generation, accounting for the pollution and CO2 emissions. We find that society paid about 5.7 cent/kWh more for wind power, counting the additional generation, transmission, intermittency, and other costs. The higher cost includes credits amounting to 1.1 cent/kWh in reduced SO2, NOx, and Hg emissions. These pollution reductions and lower CO2 emissions could be attained at about the same cost using pulverized coal (PC) or natural gas combined cycle (NGCC) plants with carbon capture and sequestration (CCS); the reductions could be obtained more cheaply with an integrated coal gasification combined cycle (IGCC) plant with CCS.

  6. Carbon Emissions Abatement Cost in China: Provincial Panel Data Analysis

    Directory of Open Access Journals (Sweden)

    Jianjun Wang

    2014-05-01

    Full Text Available This paper employs the quadratic directional output distance function to derive shadow prices of China’s aggregate carbon emissions at the province level between 1997 and 2010. The empirical results indicate that the national weighted average shadow price presents an “N-shape” curve across the sample period, experiencing the initial phase of growth followed by a phase of deterioration, and then a further increase. This change trend implies that the cost of carbon emissions reduction is increasing. In addition, the shadow price varies significantly across provinces, which means that China should uphold the principal of “common but differentiated responsibilities” in regional carbon emissions reduction. Generally, the shadow price of the east provinces with high economic development is markedly higher than that of the west provinces with low economic development. The OLS regression results indicate that the shadow price positively connected with the regional economic development levels. Moreover, an inflection point exists in the relation curve between the shadow price and GDP per capita, that is, the increase rate of the shadow price becomes small when the GDP per capita is less than 18.1 thousand Yuan, while it becomes large when the GDP per capita surpasses 18.1 thousand Yuan. With the economic growth, the cost of carbon emissions reduction would be significantly increased. The empirical results can provide more insight for policymakers.

  7. Adoption of Emissions Abating Technologies by U.S. Electricity Producing Firms Under the SO2 Emission Allowance Market

    Science.gov (United States)

    Creamer, Gregorio Bernardo

    The objective of this research is to determine the adaptation strategies that coal-based, electricity producing firms in the United States utilize to comply with the emission control regulations imposed by the SO2 Emissions Allowance Market created by the Clean Air Act Amendment of 1990, and the effect of market conditions on the decision making process. In particular, I take into consideration (1) the existence of carbon contracts for the provision of coal that may a affect coal prices at the plant level, and (2) local and geographical conditions, as well as political arrangements that may encourage firms to adopt strategies that appear socially less efficient. As the electricity producing sector is a regulated sector, firms do not necessarily behave in a way that maximizes the welfare of society when reacting to environmental regulations. In other words, profit maximization actions taken by the firm do not necessarily translate into utility maximization for society. Therefore, the environmental regulator has to direct firms into adopting strategies that are socially efficient, i.e., that maximize utility. The SO 2 permit market is an instrument that allows each firm to reduce marginal emissions abatement costs according to their own production conditions and abatement costs. Companies will be driven to opt for a cost-minimizing emissions abatement strategy or a combination of abatement strategies when adapting to new environmental regulations or markets. Firms may adopt one or more of the following strategies to reduce abatement costs while meeting the emission constraints imposed by the SO2 Emissions Allowance Market: (1) continue with business as usual on the production site while buying SO2 permits to comply with environmental regulations, (2) switch to higher quality, lower sulfur coal inputs that will generate less SO2 emissions, or (3) adopting new emissions abating technologies. A utility optimization condition is that the marginal value of each input

  8. Abatement and mitigation of carbon dioxide emissions from power generation

    International Nuclear Information System (INIS)

    Freund, P.; Audus, H.

    1998-01-01

    Current understanding of the world's climate indicates that human-induced changes are occurring and may be sufficient in magnitude to require preventative action, such as limiting atmospheric concentrations of greenhouse gases. The main anthropogenic greenhouse gas is carbon dioxide and its largest source is combustion of fossil fuels for power generation. Many different technologies can be used for reducing emissions, as well as increasing the removal of CO 2 from the atmosphere through enhancement of natural sinks, such as by forestry. Some of these options are available today and could be implemented at relatively little overall cost. For example, improving energy efficiency and switching from high carbon fuels to low carbon fuels, if suitable supplies are available. These can achieve significant reductions in CO 2 emissions. Introduction of renewable sources of energy or nuclear power to displace fossil fuels would achieve deep reductions in emissions if applied widely. However, to avoid disruptive changes, it will also be necessary to find ways of continuing to use fossil fuels but with much less emissions. Capture and storage of CO 2 is a technology which could deliver deep reductions in emissions from fossil fuels. In this paper, methods of removing CO 2 from the flue gas streams of coal and gas-fired power plants are examined, considering both plant as built today as well as possible future variants. Methods of CO 2 storage are also discussed. The results on capture and storage of CO 2 are put into perspective by comparison with studies of the large-scale application of forestry for sequestering atmospheric CO 2 , and also large-scale use of renewable energy sources, in this case growth and harvesting of woody biomass for power generation. Each of these options has different characteristics, providing a range of choices of ways of tackling climate change

  9. Abatement of emissions from small-scale combustion of biofuels

    International Nuclear Information System (INIS)

    Cowburn, D.A.; Holtham, R.D.

    1999-01-01

    This report summarises the findings of a study examining the feasibility of designing a free-standing stove for heating a room using a downburning combustion system with air introduced above the bed of the fire to minimise the deposition of tar on the glass door of the stove. Details of the construction and operation of the appliance and the testing methods are given. Emission measurements, modeling, and work on pre-production of the prototype and production model stoves are reported. A paper on the development of low smoke stoves for domestic wood use is presented in an appendix. (UK)

  10. Payback Period for Emissions Abatement Alternatives: Role of Regulation and Fuel Prices

    DEFF Research Database (Denmark)

    Zis, Thalis; Angeloudis, Panagiotis; Bell, Michael G. H.

    2016-01-01

    As of January 2015, the new maximum limit of fuel sulfur content for ships sailing within emission control areas has been reduced to 0.1%. A critical decision for ship owners in advance of the new limits was the selection of an abatement method that complies with the regulations. Two main options...... exist: investing in scrubber systems that remove sulfur dioxide emissions from the exhaust and switching to low-sulfur fuel when sailing in regulated waters. The first option would involve significant capital costs, while the latter would lead to operating cost increases because of the higher price...

  11. China’s regional industrial energy efficiency and carbon emissions abatement costs

    International Nuclear Information System (INIS)

    Wang, Ke; Wei, Yi-Ming

    2014-01-01

    Graphical abstract: Major cities in eight economy-geography regions of China. - Highlights: • Industrial energy and emissions efficiency were evaluated for China’s major cities. • Shadow prices of CO 2 emissions were estimated for China’s major cities. • Efficiency increase potentials on energy utilization and CO 2 emissions are 19% and 17%. • N-shaped EKC exists between levels of CO 2 emissions efficiency and income. • Average industrial CO 2 emissions abatement cost for China’s major cities is 45 US$. - Abstract: Evaluating the energy and emissions efficiency, measuring the energy saving and emissions reduction potential, and estimating the carbon price in China at the regional level are considered a crucial way to identify the regional efficiency levels and efficiency promotion potentials, as well as to explore the marginal abatement costs of carbon emissions in China. This study applies a newly developed Data Envelopment Analysis (DEA) based method to evaluate the regional energy and emissions efficiencies and the energy saving and emissions reduction potentials of the industrial sector of 30 Chinese major cities during 2006–2010. In addition, the CO 2 shadow prices, i.e., the marginal abatement costs of CO 2 emissions from industrial sector of these cities are estimated during the same period. The main findings are: (i) The coast area cities have the highest total factor industrial energy and emissions efficiency, but efficiency of the west area cities are lowest, and there is statistically significant efficiency difference between these cities. (ii) Economically well-developed cities evidence higher efficiency, and there is still obviously unbalanced and inequitable growth in the nationwide industrial development of China. (iii) Fortunately, the energy utilization and CO 2 emissions efficiency gaps among different Chinese cities were decreasing since 2006, and the problem of inequitable nationwide development has started to mitigate. (iv

  12. Development and testing of technical measures for the abatement of PM10 emissions from poultry housings

    Energy Technology Data Exchange (ETDEWEB)

    Ogink, N.W.M.; Aarnink, A.J.A.; Mosquera, J.; Winkel, A. [Wageningen UR Livestock Research, Wageningen (Netherlands)

    2010-07-01

    In order to comply with the European Union's ambient air quality standards, the Netherlands must reduce emissions of PM10. As a contributor to PM10, the poultry industry must implement mitigation measures before 2012. An extensive research and development program was launched in 2008 to provide abatement technology for broiler and layer houses. This paper presented results from studies carried out in 2008 and 2009 by Wageningen UR Livestock Research. The supply industry and poultry farmers participated in the study in which different methods and approaches were examined, including bedding material, light schedules, oil spraying systems, ionization systems, water scrubbers, combined scrubbers, electrostatic filters, and dry filters. Most methods were first tested and optimized in small units at an experimental poultry facility Lelystad. Several methods were validated in a next step on poultry farms, where PM10 emissions were measured to establish official emission factors. The oil spraying system and ionization system were tested in broiler houses and are nearing implementation. Reductions in PM10 emissions by different methods ranged from no effect to levels of 60 per cent. An outlook on adequate dust abatement measures for poultry housings was also provided.

  13. Energy-saving behavior and marginal abatement cost for household CO2 emissions

    International Nuclear Information System (INIS)

    Hamamoto, Mitsutsugu

    2013-01-01

    This paper attempts to measure consumers' perceived net benefits (or net costs) of energy-saving measures in using energy-consuming durable goods. Using the estimated net costs and the volume of CO 2 reduced by the measures, a marginal abatement cost (MAC) curve for the average household's CO 2 emissions is produced. An analysis using the curve suggests that in order to provide households with an incentive to take actions that can lead to CO 2 emission reductions in using energy-consuming durables, a high level of carbon price is needed. In addition, a regression analysis reveals that the net benefits of the measures are larger for households that put a higher priority on energy saving, for those living in detached houses, for those with a smaller number of persons living together, and for those with less income. The result of the analysis using the MAC curve may suggest that promoting energy-saving behavior will require not only a policy to provide economic incentives but also interventions to influence psychological factors of household behavior. - Highlights: • Consumers' perceived net costs of energy-saving measures in using energy-consuming durables are measured. • Using the estimated net costs, a marginal abatement cost (MAC) curve for the average household's CO 2 emissions is produced. • A high carbon price is needed in order to provide households with an incentive to take actions for energy-savings. • Households' attributes affecting their energy-saving behavior are revealed by a regression analysis

  14. Economic and game-theoretical analysis of CO{sub 2} emission abatement

    Energy Technology Data Exchange (ETDEWEB)

    Tahvonen, O. [Helsinki School of Economics, Helsinki (Finland)

    1996-12-31

    Current decisions on greenhouse gas emissions may have effects on human well being for centuries. This project has aimed to extend the economic models designed for analyzing this particular issue. A closely related topic follows from the fact that emitting CO{sub 2} can be interpreted as a utilization of a free access resource, i.e., when countries gain from utilizing cheap fossil fuels (relative to noncarbon energy sources), the possible loss any country suffers from climate change is only a negligible fraction of the total loss of all countries. Thus, from a global point of view, the incentives for an individual country to abate emissions is low. Economic understanding of these problems calls for dynamic game-theoretical models

  15. Economic and game-theoretical analysis of CO{sub 2} emission abatement

    Energy Technology Data Exchange (ETDEWEB)

    Tahvonen, O [Helsinki School of Economics, Helsinki (Finland)

    1997-12-31

    Current decisions on greenhouse gas emissions may have effects on human well being for centuries. This project has aimed to extend the economic models designed for analyzing this particular issue. A closely related topic follows from the fact that emitting CO{sub 2} can be interpreted as a utilization of a free access resource, i.e., when countries gain from utilizing cheap fossil fuels (relative to noncarbon energy sources), the possible loss any country suffers from climate change is only a negligible fraction of the total loss of all countries. Thus, from a global point of view, the incentives for an individual country to abate emissions is low. Economic understanding of these problems calls for dynamic game-theoretical models

  16. Abatement of atmospheric emissions in North America: Progress to date and promise for the future

    International Nuclear Information System (INIS)

    Ellis, E.C.; Erbes, R.E.; Grott, J.K.

    1990-01-01

    Much progress has been made in acidic rain abatement in North America. This progress is examined with a focus on man-made emissions of sulfur dioxide and nitrogen oxides that contribute to acidic deposition. A review of US historical trends of SO 2 and nitrogen oxides emissions since 1900 and projections of future emissions through the end of this century shoe emissions of SO 2 decreasing from a peak in 1970 of 29 Tg/yr to about 26 Tg/yr, but nitrogen oxides emissions continuing an upward trend to about 25 Tg/yr. In Canada, SO 2 , NO and NO 2 emissions are less than 20% of those in the US, and the trends are similar, with SO 2 showing future decreases and NO and NO 2 continuing to increase. Future industry in North America is expected to emit much lower levels of SO 2 , NO, and NO 2 . Technology is also available to limit nitrogen oxides emissions from future motor vehicles. Recent acidic deposition legislation in the US Congress to reduce electric utility and industrial emissions of SO 2 by 9 to 13 Tg/yr is reviewed. The estimates of the cost to implement the proposals range from $2 billion to $23 billion over a 5-year period. Retrofitting existing utility and industrial boilers for maximum SO 2 , NO, and NO 2 reduction carries the highest price tag. Several environmental policy options are explored for preventing emission increases and also promoting decreases in future emissions of SO 2 , NO, and NO 2 in North America. Focus on nitrogen oxides emissions may be critical because population growth could cause significant increases in NO and NO 2 from motor vehicle use

  17. A Study on Portfolio of Domestic Policies and Measures for GHG emission Abatement

    Energy Technology Data Exchange (ETDEWEB)

    Lim, J.K. [Korea Energy Economics Institute, Euiwang (Korea)

    2001-11-01

    After the climate change negotiation reaches an agreement in COP7, the next main issue to be addressed is the way of involvement of developing countries in emission abatement commitments and the development of domestic policies and measures to achieve GHG emission reduction target. Many Annex I countries have developed and implemented policies and measures to achieve its quantified GHG emission reduction target. The purpose of this paper is to propose a portfolio of policies and measures, that is, which policies and measures Korea will have to take in preparing future commitment for GHG emission reduction as well as in strengthening mitigation of climate change. Various policies and measures can be used, such as regulations, economic instruments, and covenants, etc., but it is desirable to implement them in some portfolio, taking advantage of their characteristics. Among the possible policies and measures, this study found that economic instruments such as carbon tax and domestic emissions trading have attracted considerable interest recently due to their cost effectiveness. This study also found that, in practice, many developed countries have used these policy instruments in achieving their quantified GHG emission reduction target. In order to develop a portfolio of policies and measures, the comprehension of the features of each policy and measure and the synergetic reconciliation with other objectives than climate change is important. (author). 82 refs., 11 figs., 31 tabs.

  18. Efficiency and abatement costs of energy-related CO2 emissions in China: A slacks-based efficiency measure

    International Nuclear Information System (INIS)

    Choi, Yongrok; Zhang, Ning; Zhou, P.

    2012-01-01

    Highlights: ► We employ a slacks-based DEA model to estimate the energy efficiency and shadow prices of CO 2 emissions in China. ► The empirical study shows that China was not performing CO 2 -efficiently. ► The average of estimated shadow prices of CO 2 emissions is about $7.2. -- Abstract: This paper uses nonparametric efficiency analysis technique to estimate the energy efficiency, potential emission reductions and marginal abatement costs of energy-related CO 2 emissions in China. We employ a non-radial slacks-based data envelopment analysis (DEA) model for estimating the potential reductions and efficiency of CO 2 emissions for China. The dual model of the slacks-based DEA model is then used to estimate the marginal abatement costs of CO 2 emissions. An empirical study based on China’s panel data (2001–2010) is carried out and some policy implications are also discussed.

  19. Hexane abatement and spore emission control in a fungal biofilter-photoreactor hybrid unit

    Energy Technology Data Exchange (ETDEWEB)

    Saucedo-Lucero, J.O. [Department of Chemical Engineering and Environmental Technology, University of Valladolid, Dr. Mergelina s/n, 47011 Valladolid (Spain); IPICyT, Instituto Potosino de Investigación Científica y Tecnológica, División de Ciencias Ambientales, Camino a la Presa San José No. 2055, C.P., 78216 San Luis Potosí (Mexico); Quijano, G. [Department of Chemical Engineering and Environmental Technology, University of Valladolid, Dr. Mergelina s/n, 47011 Valladolid (Spain); Arriaga, S. [IPICyT, Instituto Potosino de Investigación Científica y Tecnológica, División de Ciencias Ambientales, Camino a la Presa San José No. 2055, C.P., 78216 San Luis Potosí (Mexico); Muñoz, R., E-mail: mutora@iq.uva.es [Department of Chemical Engineering and Environmental Technology, University of Valladolid, Dr. Mergelina s/n, 47011 Valladolid (Spain)

    2014-07-15

    Highlights: • A fungal biofilter/photoreactor was evaluated in terms of hexane and spore removal. • Biofilter supported elimination capacities of ≈35 g m{sup −3} h{sup −1} and CO{sub 2} yields of ≈75%. • The photocatalytic process slightly boosted the hexane abatement performance. • Biofilter emitted fungal spores at concentrations of 2.4 × 10{sup 3}–9.0 × 10{sup 4} CFU m{sup −3}. • Photo-assisted post-treatments resulted in spore deactivation efficiencies of 98%. - Abstract: The performance of a fungal perlite-based biofilter coupled to a post-treatment photoreactor was evaluated over 234 days in terms of n-hexane removal, emission and deactivation of fungal spores. The biofilter and photoreactor were operated at gas residence times of 1.20 and 0.14 min, respectively, and a hexane loading rate of 115 ± 5 g m{sup −3} h{sup −1}. Steady n-hexane elimination capacities of 30–40 g m{sup −3} h{sup −1} were achieved, concomitantly with pollutant mineralization efficiencies of 60–90%. No significant influence of biofilter irrigation frequency or irrigation nitrogen concentration on hexane abatement was recorded. Photolysis did not support an efficient hexane post-treatment likely due to the short EBRT applied in the photoreactor, while overall hexane removal and mineralization enhancements of 25% were recorded when the irradiated photoreactor was packed with ZnO-impregnated perlite. However, a rapid catalyst deactivation was observed, which required a periodic reactivation every 48 h. Biofilter irrigation every 3 days supported fungal spore emissions at concentrations ranging from 2.4 × 10{sup 3} to 9.0 × 10{sup 4} CFU m{sup −3}. Finally, spore deactivation efficiencies of ≈98% were recorded for the photolytic and photocatalytic post-treatment processes. This study confirmed the potential of photo-assisted post-treatment processes to mitigate the emission of hazardous fungal spores and boost the abatement performance of

  20. Exploring the limits for CO2 emission abatement in the EU power and industry sectors—Awaiting a breakthrough

    International Nuclear Information System (INIS)

    Rootzén, Johan; Johnsson, Filip

    2013-01-01

    This study assesses the prospects for presently available abatement technologies to achieve significant reductions in CO 2 emissions from large stationary sources of CO 2 in the EU up to year 2050. The study covers power generation, petroleum refining, iron and steel, and cement production. By simulating capital stock turnover, scenarios that assume future developments in the technology stock, energy intensities, fuel and production mixes, and the resulting CO 2 emissions were generated for each sector. The results confirm that the EU goal for reductions in Greenhouse Gas Emission in the sectors covered by the EU Emission Trading System, i.e., 21% reduction by 2020 as compared to the levels in 2005, is attainable with the abatement measures that are already available. However, despite the optimism regarding the potential for, and implementation of, available abatement strategies within current production processes, our results indicate that the power and industrial sectors will fail to comply with more stringent reduction targets in both the medium term (2030) and long term (2050). Deliberate exclusion from the analysis of mitigation technologies that are still in the early phases of development (e.g., CO 2 capture and storage) provides an indirect measure of the requirements for novel low-carbon technologies and production processes. - Highlights: • Explore the limits for CO 2 emission abatement within current production processes. • Analysis of scenarios for CO 2 emissions from EU power and industrial sectors 2010–2050. • Short-term (2020) emission targets are attainable with available abatement measures. • Fail to comply with more stringent reduction targets in the long term (2050). • Efforts to develop new low-carbon production processes need to be accelerated

  1. Integrated cost-effectiveness analysis of greenhouse gas emission abatement. The case of Finland

    Energy Technology Data Exchange (ETDEWEB)

    Lehtilae, A.; Tuhkanen, S. [VTT Energy, Espoo (Finland). Energy Systems

    1999-11-01

    In Finland greenhouse gas emissions are expected to increase during the next decades due to economic growth, particularly in the energy intensive industrial sectors. The role of these industries is very central in the national economy. The emission control according to the Kyoto Protocol will therefore be quite difficult and costly. The study analyses the cost-effectiveness of different technical options for reducing the emissions of carbon dioxide, methane, and nitrous oxide in Finland. The analysis is performed with the help of a comprehensive energy system model for Finland, which has been extended to cover all major sources of methane and nitrous oxide emissions in the energy sector, industry, waste management and agriculture. The focus being on technical options, no consideration is given to possible policy measures, emission trading or joint implementation in the study. Under the boundary conditions given for the development of the Finnish energy economy, cost-effective technical measures in the energy system include increases in the use of wood biomass, natural gas and wind energy, increases in the contribution of CHP to the power supply, and intensified energy conservation in all end-use sectors. Additional cost-effective measures are landfill gas recovery, utilisation of the combustible fraction of waste and catalytic conversion of N{sub 2}O in nitric acid production. With baseline assumptions, the direct annual costs of emission abatement are calculated to be about 2000 MFIM (330 M{epsilon}) in 2010. The marginal costs are estimated to be about 230 FIM (40 {epsilon}) per tonne of CO{sub 2}-equivalent in 2010. The cost curie derived from the analysis could be used in further analyses concerning emissions trading. (orig.) 109 refs. SIHTI Research Programme

  2. Carbon Abatement and Emissions Associated with the Gasification of Walnut Shells for Bioenergy and Biochar Production.

    Science.gov (United States)

    Pujol Pereira, Engil Isadora; Suddick, Emma C; Six, Johan

    2016-01-01

    By converting biomass residue to biochar, we could generate power cleanly and sequester carbon resulting in overall greenhouse gas emissions (GHG) savings when compared to typical fossil fuel usage and waste disposal. We estimated the carbon dioxide (CO2) abatements and emissions associated to the concurrent production of bioenergy and biochar through biomass gasification in an organic walnut farm and processing facility in California, USA. We accounted for (i) avoided-CO2 emissions from displaced grid electricity by bioenergy; (ii) CO2 emissions from farm machinery used for soil amendment of biochar; (iii) CO2 sequestered in the soil through stable biochar-C; and (iv) direct CO2 and nitrous oxide (N2O) emissions from soil. The objective of these assessments was to pinpoint where the largest C offsets can be expected in the bioenergy-biochar chain. We found that energy production from gasification resulted in 91.8% of total C offsets, followed by stable biochar-C (8.2% of total C sinks), offsetting a total of 107.7 kg CO2-C eq Mg-1 feedstock. At the field scale, we monitored gas fluxes from soils for 29 months (180 individual observations) following field management and precipitation events in addition to weekly measurements within three growing seasons and two tree dormancy periods. We compared four treatments: control, biochar, compost, and biochar combined with compost. Biochar alone or in combination with compost did not alter total N2O and CO2 emissions from soils, indicating that under the conditions of this study, biochar-prompted C offsets may not be expected from the mitigation of direct soil GHG emissions. However, this study revealed a case where a large environmental benefit was given by the waste-to-bioenergy treatment, addressing farm level challenges such as waste management, renewable energy generation, and C sequestration.

  3. Carbon Abatement and Emissions Associated with the Gasification of Walnut Shells for Bioenergy and Biochar Production.

    Directory of Open Access Journals (Sweden)

    Engil Isadora Pujol Pereira

    Full Text Available By converting biomass residue to biochar, we could generate power cleanly and sequester carbon resulting in overall greenhouse gas emissions (GHG savings when compared to typical fossil fuel usage and waste disposal. We estimated the carbon dioxide (CO2 abatements and emissions associated to the concurrent production of bioenergy and biochar through biomass gasification in an organic walnut farm and processing facility in California, USA. We accounted for (i avoided-CO2 emissions from displaced grid electricity by bioenergy; (ii CO2 emissions from farm machinery used for soil amendment of biochar; (iii CO2 sequestered in the soil through stable biochar-C; and (iv direct CO2 and nitrous oxide (N2O emissions from soil. The objective of these assessments was to pinpoint where the largest C offsets can be expected in the bioenergy-biochar chain. We found that energy production from gasification resulted in 91.8% of total C offsets, followed by stable biochar-C (8.2% of total C sinks, offsetting a total of 107.7 kg CO2-C eq Mg-1 feedstock. At the field scale, we monitored gas fluxes from soils for 29 months (180 individual observations following field management and precipitation events in addition to weekly measurements within three growing seasons and two tree dormancy periods. We compared four treatments: control, biochar, compost, and biochar combined with compost. Biochar alone or in combination with compost did not alter total N2O and CO2 emissions from soils, indicating that under the conditions of this study, biochar-prompted C offsets may not be expected from the mitigation of direct soil GHG emissions. However, this study revealed a case where a large environmental benefit was given by the waste-to-bioenergy treatment, addressing farm level challenges such as waste management, renewable energy generation, and C sequestration.

  4. Energy-saving and emission-abatement potential of Chinese coal-fired power enterprise: A non-parametric analysis

    International Nuclear Information System (INIS)

    Wei, Chu; Löschel, Andreas; Liu, Bing

    2015-01-01

    In the context of soaring demand for electricity, mitigating and controlling greenhouse gas emissions is a great challenge for China's power sector. Increasing attention has been placed on the evaluation of energy efficiency and CO 2 abatement potential in the power sector. However, studies at the micro-level are relatively rare due to serious data limitations. This study uses the 2004 and 2008 Census data of Zhejiang province to construct a non-parametric frontier in order to assess the abatement space of energy and associated CO 2 emission from China's coal-fired power enterprises. A Weighted Russell Directional Distance Function (WRDDF) is applied to construct an energy-saving potential index and a CO 2 emission-abatement potential index. Both indicators depict the inefficiency level in terms of energy utilization and CO 2 emissions of electric power plants. Our results show a substantial variation of energy-saving potential and CO 2 abatement potential among enterprises. We find that large power enterprises are less efficient in 2004, but become more efficient than smaller enterprises in 2008. State-owned enterprises (SOE) are not significantly different in 2008 from 2004, but perform better than their non-SOE counterparts in 2008. This change in performance for large enterprises and SOE might be driven by the “top-1000 Enterprise Energy Conservation Action” that was implemented in 2006. - Highlights: • Energy-saving potential and CO 2 abatement-potential for Chinese power enterprise are evaluated. • The potential to curb energy and emission shows great variation and dynamic changes. • Large enterprise is less efficient than small enterprise in 2004, but more efficient in 2008. • The state-owned enterprise performs better than non-state-owned enterprise in 2008

  5. Household Solar Photovoltaics: Supplier of Marginal Abatement, or Primary Source of Low-Emission Power?

    Directory of Open Access Journals (Sweden)

    Graham Palmer

    2013-03-01

    Full Text Available With declining system costs and assuming a short energy payback period, photovoltaics (PV should, at face value, be able to make a meaningful contribution to reducing the emission intensity of Australia’s electricity system. However, solar is an intermittent power source and households remain completely dependent on a “less than green” electricity grid for reliable electricity. Further, much of the energy impact of PV occurs outside of the conventional boundaries of PV life-cycle analyses (LCA. This paper examines these competing observations and explores the broader impacts of a high penetration of household PV using Melbourne, Victoria as a reference. It concludes that in a grid dominated by unsequestered coal and gas, PV provides a legitimate source of emission abatement at high, but declining costs, with the potential for network and peak demand support. It may be technically possible to integrate a high penetration of PV, but the economic and energy cost of accommodating high-penetration PV erodes much of the benefits. Future developments in PV, storage, and integration technologies may allow PV to take on a greater long term role, but in the time horizon usually discussed in climate policy, a large-scale expansion of household PV may hinder rather than assist deep cuts to the emission intensity of Australia’s electricity system.

  6. Examining Dimethyl Sulfide Emissions in California's San Joaquin Valley

    Science.gov (United States)

    Huber, D.; Hughes, S.; Blake, D. R.

    2017-12-01

    Dimethyl Sulfide (DMS) is a sulfur-containing compound that leads to the formation of aerosols which can lead to the formation of haze and fog. Whole air samples were collected on board the NASA C-23 Sherpa aircraft during the 2017 Student Airborne Research Program (SARP) over dairies and agricultural fields in the San Joaquin Valley. Analysis of the samples indicate average DMS concentrations of 23 ± 9 pptv, with a maximum concentration of 49 pptv. When compared with DMS concentrations from previous SARP missions (2009-2016), 2017 by far had the highest frequency of elevated DMS in this region. For this study, agricultural productivity of this region was analyzed to determine whether land use could be contributing to the elevated DMS. Top down and bottom up analysis of agriculture and dairies were used to determine emission rates of DMS in the San Joaquin Valley. Correlations to methane and ethanol were used to determine that DMS emissions were strongly linked to dairies, and resulted in R2 values of 0.61 and 0.43, respectively. These values indicate a strong correlation between dairies and DMS emissions. Combined with NOAA HySPLIT back trajectory data and analysis of ground air samples, results suggest that the contribution of dairies to annual DMS emissions in the San Joaquin Valley exceeds those from corn and alfalfa production.

  7. Managing Risk Aversion for Low-Carbon Supply Chains with Emission Abatement Outsourcing.

    Science.gov (United States)

    Wang, Qinpeng; He, Longfei

    2018-02-21

    Reducing carbon emissions, including emission abatement outsourcing at the supply-chain level, is becoming a significant but challenging problem in practice. Confronting this challenge, we therefore break down the practice to focus on a low-carbon supply chain consisting of one supplier, one manufacturer and one third-party emission-reducing contractor. The contractor offers a carbon reduction service to the manufacturer. In view of the increasing proportion of Greenhouse Gases (GHG) emissions and absence of carbon reduction policies in developing countries, we adopt the prospect of consumers' low-carbon preferences to capture the demand sensitivity on carbon emission. By exploiting the Mean-Variance (MV) model, we develop a supply chain game model considering risk aversion. Comparing the supply chain performances of the cases under risk neutrality and risk aversion, we investigate the impact of the risk aversion of the supplier and the manufacturer on the low-carbon supply chain performances, respectively. We show that the risk aversion of chain members will not influence the relationship underlain by the profit-sharing contract between the manufacturer and contractor, whereas they may extend the supplier's concerning range. Although the manufacturer's risk aversion has a positive impact on the wholesale price, interestingly, the supplier's impact on the wholesale price is negative. Furthermore, we propose a contract to coordinate the risk-averse low-carbon supply chain by tuning the aversion levels of the supplier and the manufacturer, respectively. Through numerical study, we draw on managerial insights for industrial practitioners to adopt a low carbon strategy potentially by managing the risk attitudes along the supply chain channel.

  8. Managing Risk Aversion for Low-Carbon Supply Chains with Emission Abatement Outsourcing

    Science.gov (United States)

    Wang, Qinpeng; He, Longfei

    2018-01-01

    Reducing carbon emissions, including emission abatement outsourcing at the supply-chain level, is becoming a significant but challenging problem in practice. Confronting this challenge, we therefore break down the practice to focus on a low-carbon supply chain consisting of one supplier, one manufacturer and one third-party emission-reducing contractor. The contractor offers a carbon reduction service to the manufacturer. In view of the increasing proportion of Greenhouse Gases (GHG) emissions and absence of carbon reduction policies in developing countries, we adopt the prospect of consumers’ low-carbon preferences to capture the demand sensitivity on carbon emission. By exploiting the Mean-Variance (MV) model, we develop a supply chain game model considering risk aversion. Comparing the supply chain performances of the cases under risk neutrality and risk aversion, we investigate the impact of the risk aversion of the supplier and the manufacturer on the low-carbon supply chain performances, respectively. We show that the risk aversion of chain members will not influence the relationship underlain by the profit-sharing contract between the manufacturer and contractor, whereas they may extend the supplier’s concerning range. Although the manufacturer’s risk aversion has a positive impact on the wholesale price, interestingly, the supplier’s impact on the wholesale price is negative. Furthermore, we propose a contract to coordinate the risk-averse low-carbon supply chain by tuning the aversion levels of the supplier and the manufacturer, respectively. Through numerical study, we draw on managerial insights for industrial practitioners to adopt a low carbon strategy potentially by managing the risk attitudes along the supply chain channel. PMID:29466281

  9. Managing Risk Aversion for Low-Carbon Supply Chains with Emission Abatement Outsourcing

    Directory of Open Access Journals (Sweden)

    Qinpeng Wang

    2018-02-01

    Full Text Available Reducing carbon emissions, including emission abatement outsourcing at the supply-chain level, is becoming a significant but challenging problem in practice. Confronting this challenge, we therefore break down the practice to focus on a low-carbon supply chain consisting of one supplier, one manufacturer and one third-party emission-reducing contractor. The contractor offers a carbon reduction service to the manufacturer. In view of the increasing proportion of Greenhouse Gases (GHG emissions and absence of carbon reduction policies in developing countries, we adopt the prospect of consumers’ low-carbon preferences to capture the demand sensitivity on carbon emission. By exploiting the Mean-Variance (MV model, we develop a supply chain game model considering risk aversion. Comparing the supply chain performances of the cases under risk neutrality and risk aversion, we investigate the impact of the risk aversion of the supplier and the manufacturer on the low-carbon supply chain performances, respectively. We show that the risk aversion of chain members will not influence the relationship underlain by the profit-sharing contract between the manufacturer and contractor, whereas they may extend the supplier’s concerning range. Although the manufacturer’s risk aversion has a positive impact on the wholesale price, interestingly, the supplier’s impact on the wholesale price is negative. Furthermore, we propose a contract to coordinate the risk-averse low-carbon supply chain by tuning the aversion levels of the supplier and the manufacturer, respectively. Through numerical study, we draw on managerial insights for industrial practitioners to adopt a low carbon strategy potentially by managing the risk attitudes along the supply chain channel.

  10. Particulate matter emission from livestock houses: measurement methods, emission levels and abatement systems

    NARCIS (Netherlands)

    Winkel, Albert

    2016-01-01

    Animal houses are extremely dusty environments. Airborne particulate matter (PM) poses a health threat not only to the farmer and the animals, but, as a result of emissions from ventilation systems, also to residents living in livestock farming areas. In relation to this problem, the objectives

  11. System-wide and Superemitter Policy Options for the Abatement of Methane Emissions from the U.S. Natural Gas System

    Science.gov (United States)

    Mayfield, E. N.; Robinson, A. L.; Cohon, J. L.

    2017-12-01

    This work assesses trade-offs between system-wide and superemitter policy options for reducing methane emissions from compressor stations in the U.S. transmission and storage system. Leveraging recently collected national emissions and activity data sets, we developed a new process-based emissions model implemented in a Monte Carlo simulation framework to estimate emissions for each component and facility in the system. We find that approximately 83% of emissions, given the existing suite of technologies, have the potential to be abated, with only a few emission categories comprising a majority of emissions. We then formulate optimization models to determine optimal abatement strategies. Most emissions across the system (approximately 80%) are efficient to abate, resulting in net benefits ranging from 160M to 1.2B annually across the system. The private cost burden is minimal under standard and tax instruments, and if firms market the abated natural gas, private net benefits may be generated. Superemitter policies, namely, those that target the highest emitting facilities, may reduce the private cost burden and achieve high emission reductions, especially if emissions across facilities are highly skewed. However, detection across all facilities is necessary regardless of the policy option and there are nontrivial net benefits resulting from abatement of relatively low-emitting sources.

  12. Global gridded anthropogenic emissions inventory of carbonyl sulfide

    Science.gov (United States)

    Zumkehr, Andrew; Hilton, Tim W.; Whelan, Mary; Smith, Steve; Kuai, Le; Worden, John; Campbell, J. Elliott

    2018-06-01

    Atmospheric carbonyl sulfide (COS or OCS) is the most abundant sulfur containing gas in the troposphere and is an atmospheric tracer for the carbon cycle. Gridded inventories of global anthropogenic COS are used for interpreting global COS measurements. However, previous gridded anthropogenic data are a climatological estimate based on input data that is over three decades old and are not representative of current conditions. Here we develop a new gridded data set of global anthropogenic COS sources that includes more source sectors than previously available and uses the most current emissions factors and industry activity data as input. Additionally, the inventory is provided as annually varying estimates from years 1980-2012 and employs a source specific spatial scaling procedure. We estimate a global source in year 2012 of 406 Gg S y-1 (range of 223-586 Gg S y-1), which is highly concentrated in China and is twice as large as the previous gridded inventory. Our large upward revision in the bottom-up estimate of the source is consistent with a recent top-down estimate based on air-monitoring and Antarctic firn data. Furthermore, our inventory time trends, including a decline in the 1990's and growth after the year 2000, are qualitatively consistent with trends in atmospheric data. Finally, similarities between the spatial distribution in this inventory and remote sensing data suggest that the anthropogenic source could potentially play a role in explaining a missing source in the global COS budget.

  13. Modelling road dust emission abatement measures using the NORTRIP model: Vehicle speed and studded tyre reduction

    Science.gov (United States)

    Norman, M.; Sundvor, I.; Denby, B. R.; Johansson, C.; Gustafsson, M.; Blomqvist, G.; Janhäll, S.

    2016-06-01

    Road dust emissions in Nordic countries still remain a significant contributor to PM10 concentrations mainly due to the use of studded tyres. A number of measures have been introduced in these countries in order to reduce road dust emissions. These include speed reductions, reductions in studded tyre use, dust binding and road cleaning. Implementation of such measures can be costly and some confidence in the impact of the measures is required to weigh the costs against the benefits. Modelling tools are thus required that can predict the impact of these measures. In this paper the NORTRIP road dust emission model is used to simulate real world abatement measures that have been carried out in Oslo and Stockholm. In Oslo both vehicle speed and studded tyre share reductions occurred over a period from 2004 to 2006 on a major arterial road, RV4. In Stockholm a studded tyre ban on Hornsgatan in 2010 saw a significant reduction in studded tyre share together with a reduction in traffic volume. The model is found to correctly simulate the impact of these measures on the PM10 concentrations when compared to available kerbside measurement data. Importantly meteorology can have a significant impact on the concentrations through both surface and dispersion conditions. The first year after the implementation of the speed reduction on RV4 was much drier than the previous year, resulting in higher mean concentrations than expected. The following year was much wetter with significant rain and snow fall leading to wet or frozen road surfaces for 83% of the four month study period. This significantly reduced the net PM10 concentrations, by 58%, compared to the expected values if meteorological conditions had been similar to the previous years. In the years following the studded tyre ban on Hornsgatan road wear production through studded tyres decreased by 72%, due to a combination of reduced traffic volume and reduced studded tyre share. However, after accounting for exhaust

  14. Energy use, efficiency gains and emission abatement in transitional industrialised economies. Poland and the Baltic states

    Energy Technology Data Exchange (ETDEWEB)

    Salay, Juergen

    1999-05-01

    with lower sulphur and ash content. Because of higher coal prices and the introduction of hard budget constraints, power plants improved their generation efficiency, which also contributed to the reduction of emissions. After 1994, the decline in SO{sub 2} emissions has continued thanks to the installation of pollution abatement equipment. The final article (Article 6) analyses the conversion of small boilers for heat production from fossil to biomass fuels. It compares the results of six boiler conversion projects in the Baltic states with seven projects in Russia and the Czech Republic. The results show that the conversions in the Baltic states reduced the fuel cost of heat production and achieved cost-effective reductions of SO{sub 2} and carbon dioxide (CO{sub 2}). It also resulted in transfer of technology and know-how, less dependence on imported fuels and the creation of local markets for biofuels 73 refs, 3 figs, 1 tab

  15. Effects of Local Greenhouse Gas Abatement Strategies on Air Pollutant Emissions and on Health in Kuopio, Finland

    Directory of Open Access Journals (Sweden)

    Arja Asikainen

    2017-06-01

    Full Text Available Implementation of greenhouse gas (GHG abatement strategies often ends up as the responsibility of municipal action rather than national policies. Impacts of local GHG reduction measures were investigated in the EU FP7 funded project Urban Reduction of Greenhouse Gas Emissions in China and Europe (URGENCHE. Kuopio in Finland was one of the case study cities. The assessed reduction measures were (1 increased use of biomass in local heat and power cogeneration plant, (2 energy efficiency improvements of residences, (3 increased biofuel use in traffic, and (4 increased small scale combustion of wood for residential heating. Impact assessment compared the 2010 baseline with a 2020 BAU (business as usual scenario and a 2020 CO2 interventions scenario. Changes in emissions were assessed for CO2, particulate matter (PM2.5 and PM10, NOx, and SO2, and respective impacts were assessed for PM2.5 ambient concentrations and health effects. The assessed measures would reduce the local CO2 emissions in the Kuopio urban area by over 50% and local emissions of PM2.5 would clearly decrease. However, the annual average ambient PM2.5 concentration would decrease by just 4%. Thus, only marginal population level health benefits would be achieved with these assumed local CO2 abatement actions.

  16. Examination of the conditions of a broadening of the general tax for polluting activities to the intermediate energy consumptions. Incentive mechanisms for the abatement of greenhouse gas emissions

    International Nuclear Information System (INIS)

    Bureau, D.

    2000-05-01

    Among the various existing incentive mechanisms for the abatement of greenhouse gas emissions, like the pollution regulations and the financial help for energy mastery, this document analyzes the conditions of efficiency of the negotiated voluntary agreements and of the tradable emission quotas and their articulation with the fiscality. (J.S.)

  17. Cold excitation and determination of hydrogen sulfide by dielectric barrier discharge molecular emission spectrometry.

    Science.gov (United States)

    Wu, Zhongchen; Jiang, Jie; Li, Na

    2015-11-01

    A low-temperature microplasma generated in a dielectric barrier discharge (DBD) was used as a radiation source for the excitation of hydrogen sulfide and its determination by molecular emission spectrometry (MES). The excitation/emission chamber was enclosed to eliminate spectral interference from ambient air. The spectral emission lines of hydrogen sulfide were clearly discriminated from the background spectrum, and the emission line at 365.06 nm was selected for parameter optimization and quantitative analysis. The S(2-) ions in aqueous samples were reacted with acid to generate hydrogen sulfide and then determined. The experimental parameters affecting the determination of hydrogen sulfide and S(2-) were optimized. The limits of detection were 1.4 mg m(-3) for H2S and 11.2 mg L(-1) for S(2-). The repeatability of the method was satisfactory, as the RSD values were 2.3% for H2S and 1.8% for S(2-). The enclosed DBD-MES system was demonstrated to be a useful tool for the determination of hydrogen sulfide in gas samples and S(2-) in aqueous samples. Copyright © 2015 Elsevier B.V. All rights reserved.

  18. Development of novel and sensitive methods for the determination of sulfide in aqueous samples by hydrogen sulfide generation-inductively coupled plasma-atomic emission spectroscopy.

    Science.gov (United States)

    Colon, M; Todolí, J L; Hidalgo, M; Iglesias, M

    2008-02-25

    Two new, simple and accurate methods for the determination of sulfide (S(2-)) at low levels (microgL(-1)) in aqueous samples were developed. The generation of hydrogen sulfide (H(2)S) took place in a coil where sulfide reacted with hydrochloric acid. The resulting H(2)S was then introduced as a vapor into an inductively coupled plasma-atomic emission spectrometer (ICP-AES) and sulfur emission intensity was measured at 180.669nm. In comparison to when aqueous sulfide was introduced, the introduction of sulfur as H(2)S enhanced the sulfur signal emission. By setting a gas separator at the end of the reaction coil, reduced sulfur species in the form of H(2)S were removed from the water matrix, thus, interferences could be avoided. Alternatively, the gas separator was replaced by a nebulizer/spray chamber combination to introduce the sample matrix and reagents into the plasma. This methodology allowed the determination of both sulfide and sulfate in aqueous samples. For both methods the linear response was found to range from 5microgL(-1) to 25mgL(-1) of sulfide. Detection limits of 5microgL(-1) and 6microgL(-1) were obtained with and without the gas separator, respectively. These new methods were evaluated by comparison to the standard potentiometric method and were successfully applied to the analysis of reduced sulfur species in environmental waters.

  19. Korea's emission trading scheme and policy design issues to achieve market-efficiency and abatement targets

    International Nuclear Information System (INIS)

    Park, Hojeong; Hong, Won Kyung

    2014-01-01

    In 2008, the government of Republic of Korea (Korea) announced the national abatement target aiming at 30% reductions from the Business-as-Usual projections by 2020. Accordingly, the Emission Trading Scheme (ETS) will be implemented from 2015 onwards. As ETS performance substantially depends on the structural design, it is critically important to examine the details of Korean ETS for the achievement of cost effectiveness and concurrent development of an active emission trading market. This paper addresses several policy design issues for this purpose. After providing an overview on the current framework of Korean ETS, we propose ways to achieve flexibility, consistency and market efficiency of the program in consideration of the preexisting policies. Issues in policy design are discussed by focusing on allowance allocation, market stabilization measures and price mechanism in the emission and energy markets in Korea. This paper will serve as a practical guideline for establishing sustainable and market-efficient Korean ETS that can be compatible with the international standards as in the EU ETS. - Highlights: • Emission Trading Scheme (ETS) will be implemented from 2015 in Korea to reduce CO 2 . • ETS performance substantially depends on structural design. • We provide policy overview on the current framework of Korean ETS. • Several policy design issues are discussed for developing policy consistency. • We focus on allowance allocation, allowance reserve and market stabilization measures

  20. Recyclables Valorisation as the Best Strategy for Achieving Landfill CO2e Emissions Abatement from Domestic Waste: Game Theory

    Directory of Open Access Journals (Sweden)

    Paul Taboada-González

    2017-07-01

    Full Text Available Various nations in the world have developed technologies and strategies for appropriate waste disposal, and to abate waste generation and greenhouse gasses. Alternatives like recovering materials can help, but they require reliable information to improve planning and management. This study quantifies the Carbon dioxide (CO2 emissions produced by the lack of valorisation of materials in a Mexican city. Two waste characterisations in a lower-class neighbourhood were carried out. For the CO2 emission estimation, two scenarios were considered. DEFRA emission factors for waste treatment processes were used. Waste generation was 0.64 kg/capita/day in the first study, and 0.50 kg/capita/day in the second. The CO2eq emissions of collected waste in the neighbourhood were estimated at 1824 kg for 2013 (0.20 kg/capita/day and 1636 kg for 2015 (0.19 kg/capita/day. The behaviour of solid waste management in the city can be explained by the “prisoner’s dilemma” model, studied in game theory, which is ideally suited to analysing situations affected by multiple agents, but requires an accurate understanding of solid waste actors and social implications.

  1. Abatement cost of GHG emissions for wood-based electricity and ethanol at production and consumption levels.

    Directory of Open Access Journals (Sweden)

    Puneet Dwivedi

    Full Text Available Woody feedstocks will play a critical role in meeting the demand for biomass-based energy products in the US. We developed an integrated model using comparable system boundaries and common set of assumptions to ascertain unit cost and greenhouse gas (GHG intensity of electricity and ethanol derived from slash pine (Pinus elliottii at the production and consumption levels by considering existing automobile technologies. We also calculated abatement cost of greenhouse gas (GHG emissions with respect to comparable energy products derived from fossil fuels. The production cost of electricity derived using wood chips was at least cheaper by 1 ¢ MJ-1 over electricity derived from wood pellets. The production cost of ethanol without any income from cogenerated electricity was costlier by about 0.7 ¢ MJ-1 than ethanol with income from cogenerated electricity. The production cost of electricity derived from wood chips was cheaper by at least 0.7 ¢ MJ-1 than the energy equivalent cost of ethanol produced in presence of cogenerated electricity. The cost of using ethanol as a fuel in a flex-fuel vehicle was at least higher by 6 ¢ km-1 than a comparable electric vehicle. The GHG intensity of per km distance traveled in a flex-fuel vehicle was greater or lower than an electric vehicle running on electricity derived from wood chips depending on presence and absence of GHG credits related with co-generated electricity. A carbon tax of at least $7 Mg CO2e-1 and $30 Mg CO2e-1 is needed to promote wood-based electricity and ethanol production in the US, respectively. The range of abatement cost of GHG emissions is significantly dependent on the harvest age and selected baseline especially for electricity generation.

  2. Projections of multi-gas emissions and carbon sinks, and marginal abatement cost functions modelling for land-use related sources

    NARCIS (Netherlands)

    Graveland C; Bouwman AF; Vries B de; Eickhout B; Strengers BJ; MNV

    2003-01-01

    This report presents estimates of the costs of abatement of greenhouse gas emissions associated with landfills as a source of methane (CH4), sewage as a source of methane and nitrous oxide (CH4 and N2O, respectively) and carbon (C) sequestration in forest plantations. This is done in the form of

  3. Ammonia, hydrogen sulfide, carbon dioxide and particulate matter emissions from California high-rise layer houses

    Science.gov (United States)

    Lin, X.-J.; Cortus, E. L.; Zhang, R.; Jiang, S.; Heber, A. J.

    2012-01-01

    Ammonia and hydrogen sulfide are hazardous substances that are regulated by the U.S. Environmental Protection Agency through community right-to-know legislation (EPCRA, EPA, 2011). The emissions of ammonia and hydrogen sulfide from large commercial layer facilities are of concern to legislators and nearby neighbors. Particulate matter (PM 10 and PM 2.5) released from layer houses are two of seven criteria pollutants for which EPA has set National Ambient Air Quality Standards as required by the Clean Air Act. Therefore, it is important to quantify the baseline emissions of these pollutants. The emissions of ammonia, hydrogen sulfide, carbon dioxide and PM from two California high-rise layer houses were monitored for two years from October 2007 to October 2009. Each house had 32,500 caged laying hens. The monitoring site was setup in compliance with a U.S. EPA-approved quality assurance project plan. The results showed the average daily mean emission rates of ammonia, hydrogen sulfide and carbon dioxide were 0.95 ± 0.67 (standard deviation) g d -1 bird -1, 1.27 ± 0.78 mg d -1 bird -1 and 91.4 ± 16.5 g d -1 bird -1, respectively. The average daily mean emission rates of PM 2.5, PM 10 and total suspended particulate (TSP) were 5.9 ± 12.6, 33.4 ± 27.4, and 78.0 ± 42.7 mg d -1 bird -1, respectively. It was observed that ammonia emission rates in summer were lower than in winter because the high airflow stabilized the manure by drying it. The reductions due to lower moisture content were greater than the increases due to higher temperature. However, PM 10 emission rates in summer were higher than in winter because the drier conditions coupled with higher internal air velocities increased PM 10 release from feathers, feed and manure.

  4. Abatement Costs vs. Compliance Costs in Multi-Period Emissions Trading - The Firms' Perspective

    OpenAIRE

    Bode, Sven

    2003-01-01

    Greenhouse gas emission trading has become more and more important in the context of climate change. Recently, a discussion on trading on entity (i.e. company) level has started. Emitters likely to be obliged to participate have argued for an initial allocation of the emission rights free of charge. I analyse the implication of such an allocation based on historical emissions and on benchmarks in multi-period emission trading. Different allocation rules for successive periods are applied, nam...

  5. Sulfur Emissions, Abatement Technologies and Related Costs for Europe in the RAINS Model Database

    OpenAIRE

    Cofala, J.; Syri, S.

    1998-01-01

    This paper describes the part of the Regional Pollution Information and Simulation (RAINS) model dealing with the potential and costs controlling emissions of sulfur dioxide. The paper describes the selected aggregation level of the emission generating activities and reviews the major options for controlling SO2 emissions. An algorithm for estimating emission control costs is presented. The cost calculation distinguishes 'general'(i.e., valid for all countries) and 'country-specific' paramete...

  6. Joint Optimal Production Planning for Complex Supply Chains Constrained by Carbon Emission Abatement Policies

    OpenAIRE

    He, Longfei; Xu, Zhaoguang; Niu, Zhanwen

    2014-01-01

    We focus on the joint production planning of complex supply chains facing stochastic demands and being constrained by carbon emission reduction policies. We pick two typical carbon emission reduction policies to research how emission regulation influences the profit and carbon footprint of a typical supply chain. We use the input-output model to capture the interrelated demand link between an arbitrary pair of two nodes in scenarios without or with carbon emission constraints. We design optim...

  7. Final Report on Testing of Off-Gas Treatment Technologies for Abatement of Atmospheric Emissions of Chlorinated Volatile Organic Compounds

    International Nuclear Information System (INIS)

    Jarosch, T.R.; Haselow, J.S.; Rossabi, J.; Burdick, S.A.; Raymond, R.; Young, J.E.; Lombard, K.H.

    1995-01-01

    The purpose of this report is to summarize the results of the program for off-gas treatment of atmospheric emissions of chlorinated volatile organic compounds (CVOCs), in particular trichloroethylene (TCE) and perchloroethylene (PCE). This program was funded through the Department of Energy Office of Technology Development's VOC's in Non-Arid Soils Integrated Demonstration (VNID). The off-gas treatment program was initiated after testing of in-situ air stripping with horizontal wells was completed (Looney et al., 1991). That successful test expectedly produced atmospheric emissions of CVOCs that were unabated. It was decided after that test that an off-gas treatment is an integral portion of remediation of CVOC contamination in groundwater and soil but also because several technologies were being developed across the United States to mitigate CVOC emissions. A single platform for testing off-gas treatment technologies would facilitate cost effective evaluation of the emerging technologies. Another motivation for the program is that many CVOCs will be regulated under the Clean Air Act Amendments of 1990 and are already regulated by many state regulatory programs. Additionally, compounds such as TCE and PCE are pervasive subsurface environmental contaminants, and, as a result, a small improvement in terms of abatement efficiency or cost will significantly reduce CVOC discharges to the environment as well as costs to United States government and industry

  8. Australia's Greenhouse Challenge is a positive step towards abatement of gas emissions

    International Nuclear Information System (INIS)

    Anon.

    1997-01-01

    Australian industry has responded favourably to the Federal Government's Greenhouse Clallenge Program (GCP) which has focused on curbing greenhouse gas emission from the manufacturing, mining and energy sector. It is a carefully shaped program which prompts companies and groups to thoroughly review their individual operations and identify areas where credible new or addition emission control can be employed. There are now 42 companies and associations that have signed agreements in GCP. Together they account for some 15 % of Australia's total greenhouse gas emissions. It is expected that by 2000 the emission increase will be cut to 7 % and the total emissions cut by 16 million tonnes for the 42 companies concerned

  9. Joint Optimal Production Planning for Complex Supply Chains Constrained by Carbon Emission Abatement Policies

    Directory of Open Access Journals (Sweden)

    Longfei He

    2014-01-01

    Full Text Available We focus on the joint production planning of complex supply chains facing stochastic demands and being constrained by carbon emission reduction policies. We pick two typical carbon emission reduction policies to research how emission regulation influences the profit and carbon footprint of a typical supply chain. We use the input-output model to capture the interrelated demand link between an arbitrary pair of two nodes in scenarios without or with carbon emission constraints. We design optimization algorithm to obtain joint optimal production quantities combination for maximizing overall profit under regulatory policies, respectively. Furthermore, numerical studies by featuring exponentially distributed demand compare systemwide performances in various scenarios. We build the “carbon emission elasticity of profit (CEEP” index as a metric to evaluate the impact of regulatory policies on both chainwide emissions and profit. Our results manifest that by facilitating the mandatory emission cap in proper installation within the network one can balance well effective emission reduction and associated acceptable profit loss. The outcome that CEEP index when implementing Carbon emission tax is elastic implies that the scale of profit loss is greater than that of emission reduction, which shows that this policy is less effective than mandatory cap from industry standpoint at least.

  10. Abatement of CO2 emissions by way of enhancing the efficiency of nuclear power plants

    International Nuclear Information System (INIS)

    Kienle, F.

    1995-01-01

    Contributing about one third of the overall electricity supplied by the public utilities in 1994, nuclear power as in the previous years has been one of the major pillars of electricity supply in Germany. The approx. 150 billion kWh generated by the nuclear power plants represent reliable electricity supply around the clock, and free of CO 2 emissions, or SO 2 emissions, or NO x . Comparing nuclear generation with the electricity output contributed by conventional power plants in Germany, nuclear generation can also be expressed in terms of emissions avoided, which in 1994 meant: almost 150 million tons of CO 2 , equivalent to about 16 % of the aggregate annual CO 2 emissions; 110.000 tons of SO 2 , equivalent to about 11 % of aggregate annual SO 2 emissions; 125.000 tons of NO x , equivalent to 5 % of aggregate, annual NO x emissions. (orig.) [de

  11. CO2 emissions abatement in the Nordic carbon-intensive industry – An end-game in sight?

    International Nuclear Information System (INIS)

    Rootzén, Johan; Johnsson, Filip

    2015-01-01

    Analysing different future trajectories of technological developments we assess the prospects for Nordic carbon-intensive industries to significantly reduce direct CO 2 emissions in the period 2010–2050. This analysis covers petroleum refining, integrated iron and steel production, and cement manufacturing in the four largest Nordic countries of Denmark, Finland, Norway, and Sweden. Our results show that the implementation of currently available abatement measures will not be enough to meet the ambitious emissions reduction targets envisaged for the Year 2050. We show how an extensive deployment of CCS (carbon capture and storage) could result in emissions reductions that are in line with such targets. However, large-scale introduction of CCS would come at a significant price in terms of energy use and the associated flows of captured CO 2 would place high requirements on timely planning of infrastructure for the transportation and storage of CO 2 . Further the assessment highlights the importance of, especially in the absence of successful deployment of CO 2 capture, encouraging increased use of biomass in the cement and integrated iron and steel industries, and of promoting the utilisation of alternative raw materials in cement manufacturing to complement efforts to improve energy efficiency. - Highlights: • Scenarios exploring the potential for reducing CO 2 emissions in Nordic industry. • Current measures not sufficient to comply with stringent emission reduction targets. • CCS enables carbon-intensive industries to comply with stringent reduction targets. • CCS would come at a high price in terms of energy use. • Without CO 2 capture increased use of biomass and alternative raw materials vital

  12. Air Treatment Techniques for Abatement of Emissions from Intensive Livestock Production

    OpenAIRE

    Melse, R.W.; Ogink, N.W.M.; Rulkens, W.H.

    2009-01-01

    Intensive livestock production is connected with a number of environmental effects, including emissions of ammonia (NH3), greenhouse gases (CH4 and N2O), odour, and particulate matter (PM10 and PM2.5). Possible strategies for emission reduction include feed management, adaptation of housing design, and, in case of mechanically ventilated animal houses, the application of end-of-pipe air treatment, viz acid scrubbers and bioscrubbers. Air treatment techniques can achieve very high emission red...

  13. Global EDGAR v4.1 emissions of air pollutants: analysis of impacts of emissions abatement in industry and road transport on regional and global scale

    Science.gov (United States)

    Janssens-Maenhout, G.; Olivier, J. G.; Doering, U. M.; van Aardenne, J.; Monni, S.; Pagliari, V.; Peters, J. A.

    2010-12-01

    The new version v4.1 of the Emission Database for Global Atmospheric Research (EDGAR) compiled by JRC and PBL provides independent estimates of the global anthropogenic emissions and emission trends of precursors of tropospheric ozone (CO, NMVOC, NOx) and acidifying substances (NOx, NH3, SO2) for the period 1970-2005. All emissions are detailed at country level consistently using the same technology-based methodology, combining activity data (international statistics) from publicly available sources and to the extent possible emission factors as recommended by the EMEP/EEA air pollutant emission inventory guidebook. By using high resolution global grid maps per source category of area sources and point sources, we also compiled datasets with annual emissions on a 0.1x0.1 degree grid, as input for atmospheric models. We provide full and up-to-date inventories per country, also for developing countries. Moreover, the time series back in time to 1970 provides for the trends in official national inventories a historic perspective. As part of our objective to contribute to more reliable inventories by providing a reference emissions database for emission scenarios, inventory comparisons and for atmospheric modellers, we strive to transparently document all data sources used and assumptions made where data was missing, in particular for assumptions made on the shares of technologies where relevant. Technology mixes per country or region were taken from other data sources (such as the Platts database) or estimated using other sources or countries as proxy. The evolution in the adoption of technologies world-wide over the 35 years covered by EDGAR v4.1 will be illustrated for the power industry and the road transport sectors, in particular for Europe and the US. Similarly the regional and global impacts of implemented control measures and end-of pipe abatements will be illustrated by the examples of - NOx and SO2 end-of pipe abatements being implemented since the late

  14. Abatement of ammonia emissions from digested manure using gas-permeable membranes

    Science.gov (United States)

    A new strategy to avoid ammonia emissions from anaerobically digested swine manure was tested using the gas-permeable membrane process. Evaluation of the efficiency of ammonia recovery from digestate as well as mitigation of ammonia emissions to the atmosphere were carried out. Digestate was colle...

  15. Air Treatment Techniques for Abatement of Emissions from Intensive Livestock Production

    NARCIS (Netherlands)

    Melse, R.W.; Ogink, N.W.M.; Rulkens, W.H.

    2009-01-01

    Intensive livestock production is connected with a number of environmental effects, including emissions of ammonia (NH3), greenhouse gases (CH4 and N2O), odour, and particulate matter (PM10 and PM2.5). Possible strategies for emission reduction include feed management, adaptation of housing design,

  16. U.S. Coast Guard pollution abatement program - Two-stroke cycle outboard engine emissions

    Science.gov (United States)

    1975-09-01

    This report documents the results of emissions tests performed on three old and two new outboard engines. Tests of the emissions were made before and after water contact. Older engines were tested in as-received condition, tuned to factory specificat...

  17. CO{sub 2} emissions abatement and geologic sequestration - industrial innovations and stakes - status of researches in progress; Reduction des emissions et stockage geologique du CO{sub 2} - innovation et enjeux industriels - le point des recherches en cours

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    2005-07-01

    This colloquium was jointly organized by the French institute of petroleum (IFP), the French agency of environmental and energy mastery (Ademe) and the geological and mining research office (BRGM). This press kit makes a status of the advances made in CO{sub 2} emissions abatement and geological sequestration: technological advances of CO{sub 2} capture and sequestration, geological reservoir dimensioning with respect to the problem scale, duration of such an interim solution, CO{sub 2} emissions abatement potentialities of geological sequestration, regulatory, economical and financial implications, international stakes of greenhouse gas emissions. This press kit comprises a press release about the IFP-Ademe-BRGM colloquium, a slide presentation about CO{sub 2} abatement and sequestration, and four papers: a joint IFP-Ademe-BRGM press conference, IFP's answers to CO{sub 2} emissions abatement, Ademe's actions in CO{sub 2} abatement and sequestration, and BRGM's experience in CO{sub 2} sequestration and climatic change expertise. (J.S.)

  18. Air treatment techniques for abatement of emissions from intensive livestock production

    NARCIS (Netherlands)

    Melse, R.W.

    2009-01-01

    Keywords: Air treatment; Scrubber; Bioscrubber; Biofilter; Biotrickling filter; Ammonia; NH3; Odour; Livestock production; Animal husbandry; Pig; Poultry.

    Intensive livestock production is connected with a number of environmental effects, including emissions of ammonia (NH3), greenhouse

  19. Air treatment techniques for abatement of emissions from intensive livestock production

    OpenAIRE

    Melse, R.W.

    2009-01-01

    Keywords: Air treatment; Scrubber; Bioscrubber; Biofilter; Biotrickling filter; Ammonia; NH3; Odour; Livestock production; Animal husbandry; Pig; Poultry. Intensive livestock production is connected with a number of environmental effects, including emissions of ammonia (NH3), greenhouse gases (CH4 and N2O), odour, and particulate matter (PM10 and PM2.5). Possible strategies for emission reduction from animal houses include feed management, adaptation of housing design, and the application o...

  20. Abatement of CO{sub 2} emissions in the European Union

    Energy Technology Data Exchange (ETDEWEB)

    Lesourne, J.; Keppler, J.H.; Jaureguy-Naudin, Maite; Smeers, Yves; Bouttes, Jean-Paul; Trochet, Jean-Michel; Dassa, Francois; Neuhoff, Karsten

    2008-07-01

    This first monograph of the Ifri program on European Governance and Geopolitics of Energy is devoted to the control of carbon dioxide emissions within the European Union. Since it is almost unanimously accepted that Greenhouse Gas emissions constitute the main cause of the observed increase of the world average temperature, the system implemented by the European Union to limit and decrease the CO{sub 2} emissions is a significant pillar of the EU energy policy, the two others being the acceptance by the Member States of long-term commitments (for instance on the future share of renewable energy sources in their energy balance sheet) and the establishment of an internal market for electricity and gas. Though simple in principle, the European Union Greenhouse Gas Emission Trading Scheme (EU ETS) is in fact rather complex, and only experts really understand its merits and its deficiencies. These deficiencies are real and will have to be corrected in the future for the system to be effective. At this moment, when the 2005-2007 trial phase of the EU ETS is ending, the monograph has the purpose to stimulate the discussion between experts and to enable all those interested in the topic to understand the issues and to take part in the public debates on the subject. The monograph contains five papers: - 'An Overview of the CO{sub 2} Emission Control System in the European Union' by Jacques Lesourne and Maite Jaureguy-Naudin. - 'Description and Assessment of EU CO{sub 2} Regulations' by Yves Smeers. - 'Assessment of EU CO{sub 2} Regulations' by Jean-Paul Bouttes, Jean-Michel Trochet and Francois Dassa. - 'Investment in Low Carbon Technologies, Policies for the Power Sector' by Karsten Neuhoff. - 'Lessons Learned from the 2005-2007 Trial Phase of the EU Emission Trading System' by Jan Horst Keppler

  1. Development of novel and sensitive methods for the determination of sulfide in aqueous samples by hydrogen sulfide generation-inductively coupled plasma-atomic emission spectroscopy

    Energy Technology Data Exchange (ETDEWEB)

    Colon, M. [Department of Chemistry, University of Girona, Campus Montilivi, 17071 Girona (Spain); Departamento de Quimica Analitica, Nutricion y Bromatologia, University of Alicante, 03080 Alicante (Spain); Todoli, J.L. [Departamento de Quimica Analitica, Nutricion y Bromatologia, University of Alicante, 03080 Alicante (Spain); Hidalgo, M. [Department of Chemistry, University of Girona, Campus Montilivi, 17071 Girona (Spain); Iglesias, M. [Department of Chemistry, University of Girona, Campus Montilivi, 17071 Girona (Spain)], E-mail: monica.iglesias@udg.es

    2008-02-25

    Two new, simple and accurate methods for the determination of sulfide (S{sup 2-}) at low levels ({mu}g L{sup -1}) in aqueous samples were developed. The generation of hydrogen sulfide (H{sub 2}S) took place in a coil where sulfide reacted with hydrochloric acid. The resulting H{sub 2}S was then introduced as a vapor into an inductively coupled plasma-atomic emission spectrometer (ICP-AES) and sulfur emission intensity was measured at 180.669 nm. In comparison to when aqueous sulfide was introduced, the introduction of sulfur as H{sub 2}S enhanced the sulfur signal emission. By setting a gas separator at the end of the reaction coil, reduced sulfur species in the form of H{sub 2}S were removed from the water matrix, thus, interferences could be avoided. Alternatively, the gas separator was replaced by a nebulizer/spray chamber combination to introduce the sample matrix and reagents into the plasma. This methodology allowed the determination of both sulfide and sulfate in aqueous samples. For both methods the linear response was found to range from 5 {mu}g L{sup -1} to 25 mg L{sup -1} of sulfide. Detection limits of 5 {mu}g L{sup -1} and 6 {mu}g L{sup -1} were obtained with and without the gas separator, respectively. These new methods were evaluated by comparison to the standard potentiometric method and were successfully applied to the analysis of reduced sulfur species in environmental waters.

  2. Consequences of new scientific findings for future abatement of ammonia emissions

    NARCIS (Netherlands)

    Erisman, J.W.; Monteny, G.J.

    1998-01-01

    Several studies have shown that the estimated decreases in emissions of ammonia in the Netherlands are overestimated. Results obtained from recent research on the so-called compensation point of ammonia in intensive farming areas, research in areas affected with swine fever, and research on

  3. An evaluation of the effect of greenhouse gas accounting methods on a marginal abatement cost curve for Irish agricultural greenhouse gas emissions

    International Nuclear Information System (INIS)

    O’Brien, Donal; Shalloo, Laurence; Crosson, Paul; Donnellan, Trevor; Farrelly, Niall; Finnan, John; Hanrahan, Kevin; Lalor, Stan; Lanigan, Gary; Thorne, Fiona; Schulte, Rogier

    2014-01-01

    Highlights: • Improving productivity was the most effective strategy to reduce emissions and costs. • The accounting methods disagreed on the total abatement potential of mitigation measures. • Thus, it may be difficult to convince farmers to adopt certain abatement measures. • Domestic offsetting and consumption based accounting are options to overcome current methodological issues. - Abstract: Marginal abatement cost curve (MACC) analysis allows the evaluation of strategies to reduce agricultural greenhouse gas (GHG) emissions relative to some reference scenario and encompasses their costs or benefits. A popular approach to quantify the potential to abate national agricultural emissions is the Intergovernmental Panel on Climate Change guidelines for national GHG inventories (IPCC-NI method). This methodology is the standard for assessing compliance with binding national GHG reduction targets and uses a sector based framework to attribute emissions. There is however an alternative to the IPCC-NI method, known as life cycle assessment (LCA), which is the preferred method to assess the GHG intensity of food production (kg of GHG/unit of food). The purpose of this study was to compare the effect of using the IPCC-NI and LCA methodologies when completing a MACC analysis of national agricultural GHG emissions. The MACC was applied to the Irish agricultural sector and mitigation measures were only constrained by the biophysical environment. The reference scenario chosen assumed that the 2020 growth targets set by the Irish agricultural industry would be achieved. The comparison of methodologies showed that only 1.1 Mt of the annual GHG abatement potential that can be achieved at zero or negative cost could be attributed to agricultural sector using the IPCC-NI method, which was only 44% of the zero or negative cost abatement potential attributed to the sector using the LCA method. The difference between methodologies was because the IPCC-NI method attributes the

  4. A two-period model of emission abatement and allowance banking under uncertainty

    International Nuclear Information System (INIS)

    Hanson, D.A.

    1991-01-01

    This paper deals with the effects of uncertainty and risk aversion on market outcomes for SO 2 emission allowance prices and on electric utility compliance choices. The 1990 Clean Air Act Amendments (CAAA) provide about twice as many SO 2 allowances to be issued per year in Phase I (1995--1999) than in Phase II. Also, considering the scrubber incentives in Phase I, there is likely to be substantial emission banking for use in Phase II. Allowance prices may increase over time at a rate less than the return on alternative investments with allowances being banked only by risk averse electric utilities. Speculators are likely to be willing to set allowances in forward markets, which will lower current market prices of allowances relative to a situation with only risk averse utilities in the market. The Argonne Utility Simulation Model (ARGUS2) is being revised to incorporate the provisions of the CAAA acid rain title and to simulate SO 2 allowance prices, compliance choices, capacity expansion, system dispatch, fuel use, and emissions using a unit level data base and alternative scenario assumptions

  5. Social impact of air pollution abatement. Societal cost benefit analysis of possible National Emission Ceilings

    International Nuclear Information System (INIS)

    Doenszelmann, C.E.P.; De Bruyn, S.M.; Korteland, M.H.; De Jong, F.; Sevenster, M.N.; Briene, M.; Wienhoven, M.; Bovens, J.

    2008-07-01

    In 2008, the European Commission will launch new proposals for revision of the NEC guideline (2001/81/EG) in which new emission ceilings are proposed for the year 2020. In order to determine which stand the Netherlands should take during the negotiations, the Dutch Ministry of Economic Affairs (also on behalf of the Ministry of Agriculture, Nature and Food Quality) asked CE Delft and Ecorys to conduct a societal cost benefit analysis in collaboration with the Environmental Assessment Agency. This report describes the results of the analysis of two alternative NEC targets for 2020. [mk] [nl

  6. Broadband filters for abatement of spontaneous emission in circuit quantum electrodynamics

    Energy Technology Data Exchange (ETDEWEB)

    Bronn, Nicholas T., E-mail: ntbronn@us.ibm.com; Hertzberg, Jared B.; Córcoles, Antonio D.; Gambetta, Jay M.; Chow, Jerry M. [IBM T.J. Watson Research Center, 1101 Kitchawan Road, Yorktown Heights, New York 10598 (United States); Liu, Yanbing; Houck, Andrew A. [Department of Electrical Engineering, Princeton University, Princeton, New Jersey 08544 (United States)

    2015-10-26

    The ability to perform fast, high-fidelity readout of quantum bits (qubits) is essential to the goal of building a quantum computer. However, coupling a fast measurement channel to a superconducting qubit typically also speeds up its relaxation via spontaneous emission. Here, we use impedance engineering to design a filter by which photons may easily leave the resonator at the cavity frequency but not at the qubit frequency. We implement this broadband filter in both an on-chip and off-chip configuration.

  7. Emissions reduction in the UK: accommodating waste production from sulphur abatement systems

    Energy Technology Data Exchange (ETDEWEB)

    Crofts, C. (British Coal, London (UK). Operational Research Executive)

    1990-01-01

    Concern for the atmosphere environment has resulted in EC legislation limiting sulphur dioxide emissions. The emission limits are being met by the installation of flue gas desulphurisation and advanced coal combustion systems, which produce large quantities of waste for utilisation or disposal. There are now environmental, economic and regulatory reasons for industry to provide comprehensive assessment of waste disposal/utilisation issues during the design stage of a project. This paper considers the management of waste produced from the limestone/gypsum and spray dry FGD processes, and from advanced coal combustion equipment. The assessment shows that environmentally acceptable methods of disposal and utilisation can be identified for these wastes. It is expected that a substantial proportion of FGD gypsum will be utilized in the manufacture of plasterboard, bag plaster and cement. There may also be opportunities for utilisation of spray dry waste and waste from advanced coal combustion systems in structural and agricultural applications. Landfill would be an appropriate form of disposal for the wastes considered in this paper, but utilisation options offer environmentally superior alternatives to disposal justifying further research. 19 refs., 3 figs.

  8. Employing a CGE model in analysing the environmental and economy-wide impacts of CO2 emission abatement policies in Malaysia.

    Science.gov (United States)

    Yahoo, Masoud; Othman, Jamal

    2017-04-15

    The impact of global warming has received much international attention in recent decades. To meet climate-change mitigation targets, environmental policy instruments have been designed to transform the way goods and services are produced as well as alter consumption patterns. The government of Malaysia is strongly committed to reducing CO 2 gas emissions as a proportion of GDP by 40% from 2005 levels by the year 2020. This study evaluates the economy-wide impacts of implementing two different types of CO 2 emission abatement policies in Malaysia using market-based (imposing a carbon tax) and command-and-control mechanism (sectoral emission standards). The policy simulations conducted involve the removal of the subsidy on petroleum products by the government. A carbon emission tax in conjunction with the revenue neutrality assumption is seen to be more effective than a command-and-control policy as it provides a double dividend. This is apparent as changes in consumption patterns lead to welfare enhancements while contributing to reductions in CO 2 emissions. The simulation results show that the production of renewable energies is stepped up when the imposition of carbon tax and removal of the subsidy is augmented by revenue recycling. This study provides an economy-wide assessment that compares two important tools for assisting environment policy makers evaluate carbon emission abatement initiatives in Malaysia. Copyright © 2017 Elsevier B.V. All rights reserved.

  9. Combined borax and tannin treatment of stored dairy manure to reduce bacterial populations and hydrogen sulfide emissions

    Science.gov (United States)

    Background: Anaerobic digestion of organic residues in stored livestock manure is associated with the production of odors and emissions. Hydrogen sulfide (H2S) is one such emission that can reach hazardous levels during manure storage and handling, posing a risk to both farmers and livestock. New te...

  10. Renewable biocatalyst for swine manure treatment and mitigation of odorous VOCs, ammonia and hydrogen sulfide emissions: Review

    Science.gov (United States)

    Comprehensive control of odors, hydrogen sulfide (H2S), ammonia (NH3), and greenhouse gas (GHG) emissions associated with swine production is a critical need. The objective of this paper is to review the use of soybean peroxidase (SBP) and peroxides as a manure additive to mitigate emissions of odor...

  11. Catalytic oxidation of chlorinated volatile organic compounds, dichloromethane and perchloroethylene. New knowledge for the industrial CVOC emission abatement

    Energy Technology Data Exchange (ETDEWEB)

    Pitkaeaho, S.

    2013-09-01

    The releases of chlorinated volatile organic compounds (CVOCs) are controlled by strict regulations setting high demands for the abatement systems. Low temperature catalytic oxidation is a viable technology to economically destroy these often refractory emissions. Catalysts applied in the oxidation of CVOCs should be highly active and selective but also maintain a high resistance towards deactivation. In this study, a total of 33 different {gamma}-Al{sub 2}O{sub 3} containing metallic monoliths were studied in dichloromethane (DCM) and 25 of them in perchloroethylene (PCE) oxidation. The active compounds used were Pt, Pd, Rh or V{sub 2}O{sub 5} alone or as mixtures. The catalysts were divided into three different testing sets: industrial, CVOC and research catalysts. ICP-OES, physisorption, chemisorption, XRD, UV-vis DRS, isotopic oxygen exchange, IC, NH{sub 3}-TPD, H{sub 2}-TPR and FESEM-EDS were used to characterise the catalysts. Screening of the industrial catalysts revealed that the addition of V{sub 2}O{sub 5} improved the performance of the catalyst. DCM abatement was easily affected by the addition of VOC or water, but the effect on the PCE oxidation was only minor. Based on these screening tests, a set of CVOC catalysts were developed and installed into an industrial incinerator. The comparison between the laboratory and industrial scale studies showed that DCM oxidation in an industrial incinerator could be predicted relatively well. Instead, PCE was always seen to be oxidised far better in an industrial unit indicating that the transient oxidation conditions are beneficial for the PCE oxidation. Before starting the experiments with research catalysts, the water feed was optimised to 1.5 wt.%. Besides enhancing the HCl yields, water improved the DCM and PCE conversions. In the absence of oxygen, i.e. during destructive adsorption, the presence of water was seen to have an even more pronounced effect on the HCl formation and on the catalysts

  12. Health costs caused by oil extraction air emissions and the benefits from abatement: the case of Kazakhstan

    International Nuclear Information System (INIS)

    Netalieva, Indira; Wesseler, Justus; Heijman, Wim

    2005-01-01

    The methodology and results of a cost-benefit analysis of air quality control during oil production in the Caspian Region in Kazakhstan are presented. The benefits are defined as the decrease in health costs from reduced air pollution. The health costs are the income losses which depend on the attributes of illness (duration and number of symptoms) and on respondents' characteristics such as age, education, and gender. The results are obtained by comparing two cities, one with a high rate of pollution due to oil extraction, Atyrau, and the other, Astana, without. The incremental health costs for Atyrau caused by the oil production industry are estimated to be at least 5.1 million USD per year. The annual benefits of investments into abatement technologies are at least five times higher than the virtual annual abatement costs of about 0.46 million USD

  13. Borax and Octabor Treatment of Stored Swine Manure: Reduction in Hydrogen Sulfide Emissions and Phytotoxicity to Agronomic Crops

    Science.gov (United States)

    Gaseous emissions from stored manure have become environmental and health issues for humans and animals as the livestock industry becomes specialized and concentrated. Of particular concern is hydrogen sulfide, which is being targeted for regulatory control in concentrated animal farm operations. ...

  14. Borax and octabor treatment of stored swine manure to reduce sulfate reducing bacteria and hydrogen sulfide emissions

    Science.gov (United States)

    Odorous gas emissions from stored swine manure are becoming serious environmental and health issues as the livestock industry becomes more specialized, concentrated, and industrialized. These nuisance gasses include hydrogen sulfide (H2S), ammonia, and methane, which are produced as a result of ana...

  15. Land use efficiency: anticipating future demand for land-sector greenhouse gas emissions abatement and managing trade-offs with agriculture, water, and biodiversity.

    Science.gov (United States)

    Bryan, Brett A; Crossman, Neville D; Nolan, Martin; Li, Jing; Navarro, Javier; Connor, Jeffery D

    2015-11-01

    Competition for land is increasing, and policy needs to ensure the efficient supply of multiple ecosystem services from land systems. We modelled the spatially explicit potential future supply of ecosystem services in Australia's intensive agricultural land in response to carbon markets under four global outlooks from 2013 to 2050. We assessed the productive efficiency of greenhouse gas emissions abatement, agricultural production, water resources, and biodiversity services and compared these to production possibility frontiers (PPFs). While interacting commodity markets and carbon markets produced efficient outcomes for agricultural production and emissions abatement, more efficient outcomes were possible for water resources and biodiversity services due to weak price signals. However, when only two objectives were considered as per typical efficiency assessments, efficiency improvements involved significant unintended trade-offs for the other objectives and incurred substantial opportunity costs. Considering multiple objectives simultaneously enabled the identification of land use arrangements that were efficient over multiple ecosystem services. Efficient land use arrangements could be selected that meet society's preferences for ecosystem service provision from land by adjusting the metric used to combine multiple services. To effectively manage competition for land via land use efficiency, market incentives are needed that effectively price multiple ecosystem services. © 2015 John Wiley & Sons Ltd.

  16. Methane emissions abatement by multi-ion-exchanged zeolite A prepared from both commercial-grade zeolite and coal fly ash.

    Science.gov (United States)

    Hui, K S; Chao, C Y H

    2008-10-01

    The performance of multimetal-(Cu, Cr, Zn, Ni, and Co)-ion-exchanged zeolite A prepared from both a commercial-grade sample and one produced from coal fly ash in methane emissions abatement was evaluated in this study. The ion-exchange process was used to load the metal ions in zeolite A samples. The methane conversion efficiency by the samples was studied under various parameters including the amount of metal loading (7.3-19.4 wt%), reaction temperature (25-500 degrees C), space velocity (8400-41 900 h(-1)), and methane concentration (0.5-3.2 vol %). At 500 degrees C, the original commercial-grade zeolite A catalyzed 3% of the methane only, whereas the addition of different percentages of metals in the sample enhanced the methane conversion efficiency by 40-85%. Greater methane conversion was observed by increasing the percentage of metals added to the zeolite even though the BET surface area of the zeolite consequently decreased. Higher percentage methane conversion over the multi-ion-exchanged samples was observed at lower space velocities indicating the importance of the mass diffusion of reactants and products in the zeolite. Compared to the multi-ion-exchanged zeolite A prepared from the commercial-grade zeolite, the one produced from coal fly ash demonstrated similar performances in methane emissions abatement, showing the potential use of this low cost recycled material in gaseous pollutant treatment.

  17. Noncondensable hydrogen sulfide incineration with brine scrubbing air emissions control system

    International Nuclear Information System (INIS)

    Goddard, W.B.; Goddard, C.B.; McClain, D.W.

    1990-01-01

    This paper reports on the technical and institutional feasibility of incinerating hydrogen sulfide (H2S) contained in geothermal noncondensable gases, and the use of geothermal brine for sulfur dioxide scrubbing and absorption as an Air Emissions Control System (AECS), for geothermal power plant, that have been documented through engineering analysis in the Phase I grant study funded through the California Department of Health Services (DOHS), Hazardous Materials Reduction Grant Program and hosted by California Energy Company (CECI). Grant funding for Phase II now has been approved to proceed with the project through the pilot plant design phase. This innovative AECS does not necessitate the use of hazardous materials or produce hazardous wastes. Cost savings were documented compared to injection pump operation or conventional AECS without the use of hazardous materials. The phase II project is to design, improve, research and develop a source reduction demonstration pilot plant geothermal noncondensable H2S incineration AECS

  18. Effectiveness of urease inhibition on the abatement of ammonia, nitrous oxide and nitric oxide emissions in a non-irrigated Mediterranean barley field.

    Science.gov (United States)

    Abalos, Diego; Sanz-Cobena, Alberto; Misselbrook, Thomas; Vallejo, Antonio

    2012-09-01

    Urea is considered the cheapest and most commonly used form of inorganic N fertilizer worldwide. However, its use is associated with emissions of ammonia (NH(3)), nitrous oxide (N(2)O) and nitric oxide (NO), which have both economic and environmental impact. Urease activity inhibitors have been proposed as a means to reduce NH(3) emissions, although limited information exists about their effect on N(2)O and NO emissions. In this context, a field experiment was carried out with a barley crop (Hordeum vulgare L.) under Mediterranean conditions to test the effectiveness of the urease inhibitor N-(n-butyl) thiophosphoric triamide (NBPT) on reducing these gaseous N losses from surface applied urea. Crop yield, soil mineral N concentrations, dissolved organic carbon (DOC), denitrification potential, NH(3), N(2)O and NO fluxes were measured during the growing season. The inclusion of the inhibitor reduced NH(3) emissions in the 30 d following urea application by 58% and net N(2)O and NO emissions in the 95 d following urea application by 86% and 88%, respectively. NBPT addition also increased grain yield by 5% and N uptake by 6%, although neither increase was statistically significant. Under the experimental conditions presented here, these results demonstrate the potential of the urease inhibitor NBPT in abating NH(3), N(2)O and NO emissions from arable soils fertilized with urea, slowing urea hydrolysis and releasing lower concentrations of NH(4)(+) to the upper soil layer. Copyright © 2012 Elsevier Ltd. All rights reserved.

  19. Potential impact on air pollution from ambitious national CO2 emission abatement strategies in the Nordic countries – environmental links between the UNFCCC and the UNECE – CLRTAP

    International Nuclear Information System (INIS)

    Åström, Stefan; Tohka, Antti; Bak, Jesper; Lindblad, Maria; Arnell, Jenny

    2013-01-01

    This article presents results from a meta-study of Nordic low carbon dioxide (CO 2 ) emission scenarios. The focus of the study was to explore possible environmental impacts if selected Nordic low CO 2 emission scenarios were achieved by 2020. The impacts of concern were climate change, acidification, eutrophication and human health. Results from this study indicate that large scale reduction of CO 2 emissions by 2020 in a Nordic energy system requires large scale penetration of technical measures and structural changes. The environmental improvements achieved would most often facilitate achievement of air pollution targets as well as post-Kyoto targets for greenhouse gas (GHG) emissions. All scenarios do, however, not imply co-benefits between air pollution and CO 2 emission reductions and the net impact on climate change could be smaller than anticipated. A conclusion is that co-benefits and risks for trade-offs between air quality and climate change should be emphasised in the development of low-CO 2 energy and emission strategies. - Highlights: ► CO 2 abatement strategies differ in impact on environment, human health and climate. ► Bio fuel CO 2 strategies can imply smaller climate and environmental benefits. ► Nordic ‘clean’ electricity export can give environmental benefits if replacing coal.

  20. Abatement cost of SF6 emissions from medium voltage switchgear. Validation of recent studies for the European Commission

    Energy Technology Data Exchange (ETDEWEB)

    Benner, J.; Van Lieshout, M.; Croezen, H.

    2012-05-15

    Sulphur hexafluoride (SF6) is a gas with applications including use as an insulator and switching medium in medium voltage (MV) switchgear. While having certain unique properties, it is also a greenhouse gas, with a 22,800 times greater impact than CO2 and an atmospheric lifetime of over 3,000 years. Although the use of SF6 in MV switchgear can be avoided, according to recent studies for the European Commission, the abatement costs are high. This study validates the calculated cost levels as well as the general feasibility of determining a fixed cost figure for this purpose. This analysis yields a result which differs from the earlier studies, particularly with respect to the cost aspect, but also in other areas. CE Delft concludes that for the majority of applications cost-effective SF6-free options are available, leading to abatement costs for the use of SF6 in MV switchgear that range from - 40 to 0 euro/tCO2 eq., for all types of switchgear, with voltage levels below 25 kV and situated on relatively dry locations.

  1. Optimal strategies for VOC emission abatement produced by solvent evaporation. The Italian case study; Strategie ottimali per la riduzione delle emissioni di composti organici volatili da uso di solventi: il caso italiano

    Energy Technology Data Exchange (ETDEWEB)

    Vetrella, G.; Cirillo, M.C. [ENEA, Centro Ricerche Casaccia, Rome (Italy). Dipt. Ambiente

    1998-07-01

    This work analyses technologies and costs of VOC (volatile organic compounds) abatement in the activities which belong to the solvent evaporation sector, and then it singles out the most successful strategies from the costs point of view to reduce the sector emissions on the base of fixed abatement objectives. The Italian case is discussed. [Italian] Il lavoro analizza tecnologie e costi di abbattimento dei COV (composti organici volatili) nel settore evaporazione solventi, e individua la strategia piu' efficace dal punto di vista dei costi per ridurre le emissioni del settore sulla base di prefissati obiettivi di abbattimento. Analizza la situazione italiana.

  2. Volcanic sulfur degassing and the role of sulfides in controlling volcanic metal emissions

    Science.gov (United States)

    Edmonds, M.; Liu, E.

    2017-12-01

    Volcanoes emit prodigious quantities of sulfur and metals, their behaviour inextricably linked through pre-eruptive sulfide systematics and through degassing and speciation in the volcanic plume. Fundamental differences exist in the metal output of ocean island versus arc volcanoes, with volcanoes in Hawaii and Iceland outgassing large fluxes of gaseous and particulate chalcophiles; and arc volcanoes' plumes, in contrast, enriched in Zn, Cu, Tl and Pb. Metals and metalloids partition into a magmatic vapor phase from silicate melt at crustal pressures. Their abundance in magmatic vapor is influenced strongly by sulfide saturation and by the composition of the magmatic vapor phase, particularly with respect to chloride. These factors are highly dependent on tectonic setting. Metal outgassing is controlled by magma water content and redox: deep saturation in vapor and minimal sulfide in arc basalts yields metal-rich vapor; shallow degassing and resorption of sulfides feeds the metal content of volcanic gas in ocean islands. We present a detailed study of the sulfide systematics of the products of the 2014-2015 Holuhraun basaltic fissure eruption (Bárðarbunga volcanic system, Iceland) to illustrate the interplay between late water and sulfur outgassing; sulfide saturation and breakdown; and metal partitioning into a vapor phase. Sulfide globules, representing quenched droplets of an immiscible sulfide liquid, are preserved within erupted tephra. Sulfide globules in rapidly quenched tephra are preserved within both matrix glass and as inclusions in crystals. The stereologically-corrected 3D size distribution of sulfide globules ranges from importance in supplying sulfur and metals to the atmosphere during eruption.

  3. Production of volatiles by the red seaweed Gelidium arbuscula (Rhodophyta): emission of ethylene and dimethyl sulfide.

    Science.gov (United States)

    Garcia-Jimenez, Pilar; Brito-Romano, Olegario; Robaina, Rafael R

    2013-08-01

    The effects of different light conditions and exogenous ethylene on the emission of volatile compounds from the alga Gelidium arbuscula Bory de Saint-Vincent were studied. Special emphasis was placed on the possibility that the emission of ethylene and dimethyl sulfide (DMS) are related through the action of dimethylsulfoniopropionate (DMSP) lyase. The conversion of DMSP to DMS and acrylate, which is catalyzed by DMSP lyase, can indirectly support the synthesis of ethylene through the transformation of acrylate to ethylene. After mimicking the desiccation of G. arbuscula thalli experienced during low tides, the volatile compounds emitted were trapped in the headspace of 2 mL glass vials for 1 h. Two methods based on gas chromatography/mass spectrometry revealed that the range of organic volatile compounds released was affected by abiotic factors, such as the availability and spectral quality of light, salinity, and exogenous ethylene. Amines and methyl alkyl compounds were produced after exposure to white light and darkness but not after exposure to exogenous ethylene or red light. Volatiles potentially associated with the oxidation of fatty acids, such as alkenes and low-molecular-weight oxygenated compounds, accumu-lated after exposure to exogenous ethylene and red light. Ethylene was produced in all treatments, especially after exposure to exogenous ethylene. Levels of DMS, the most abundant sulfur-compound that was emitted in all of the conditions tested, did not increase after incubation with ethylene. Thus, although DMSP lyase is active in G. arbuscula, it is unlikely to contribute to ethylene synthesis. The generation of ethylene and DMS do not appear to be coordinated in G. arbuscula. © 2013 Phycological Society of America.

  4. Attribution of atmospheric sulfur dioxide over the English Channel to dimethyl sulfide and changing ship emissions

    Science.gov (United States)

    Yang, Mingxi; Bell, Thomas G.; Hopkins, Frances E.; Smyth, Timothy J.

    2016-04-01

    Atmospheric sulfur dioxide (SO2) was measured continuously from the Penlee Point Atmospheric Observatory (PPAO) near Plymouth, United Kingdom, between May 2014 and November 2015. This coastal site is exposed to marine air across a wide wind sector. The predominant southwesterly winds carry relatively clean background Atlantic air. In contrast, air from the southeast is heavily influenced by exhaust plumes from ships in the English Channel as well as near Plymouth Sound. A new International Maritime Organization (IMO) regulation came into force in January 2015 to reduce the maximum allowed sulfur content in ships' fuel 10-fold in sulfur emission control areas such as the English Channel. Our observations suggest a 3-fold reduction in ship-emitted SO2 from 2014 to 2015. Apparent fuel sulfur content calculated from coincidental SO2 and carbon dioxide (CO2) peaks from local ship plumes show a high level of compliance to the IMO regulation (> 95 %) in both years (˜ 70 % of ships in 2014 were already emitting at levels below the 2015 cap). Dimethyl sulfide (DMS) is an important source of atmospheric SO2 even in this semi-polluted region. The relative contribution of DMS oxidation to the SO2 burden over the English Channel increased from about one-third in 2014 to about one-half in 2015 due to the reduction in ship sulfur emissions. Our diel analysis suggests that SO2 is removed from the marine atmospheric boundary layer in about half a day, with dry deposition to the ocean accounting for a quarter of the total loss.

  5. Abatement Technologies for Volatile Organic Compounds in Emissions from Biofuel Driers; Reningsteknik foer organiska aemnen i utslaepp till luft vid biobraensletorkning

    Energy Technology Data Exchange (ETDEWEB)

    Nielsen, Karin; Ehrstedt, Thomas [Sycon Energikonsult AB, Malmoe (Sweden)

    2000-06-01

    This report is a part of a program at Vaermeforsk called Drying of Biofuels and deals with abatement technologies for volatile organic compounds (VOC) in biofuel drier emissions. The report gives an account of the amount of organic matter in wood and in drying gases and also of different abatement technologies for VOC. Processes from about 20 contractors are briefly described. The conclusions from this work are that thermal or catalytic oxidizing technologies in connection with regenerative heat recovery seems to be the most suitable technique for this application. Both technologies should give a degree of purification above 95 %. The purification cost for a typical case has been estimated to about 22 SEK per kg removed organic matter in both cases. The investment cost is higher for the catalytic oxidizer (6-20 MSEK for a 60.000 Nm{sup 3} /h catalytic plant compared to 4-6,5 MSEK for a thermal plant) but the fuel cost is lower. Condensation is a usable technique but it suffers from bad degree of purification. By using a wet electrostatic precipitator (WESP) the degree of purification can be enhanced but it will still be lower than for the oxidizers. Adsorption and absorption are not suitable for gases at high temperatures containing several different organic compounds at low concentrations, which is the case in biofuel drying. This means high purification costs and low degree of purification. Other technologies that have been found less suitable are biological purification and membrane technology. World-wide there are a few reference plants based on thermal oxidizing in connection with biofuel drying. Otherwise the experiences are very limited. According to this, tests in pilot plant scale are recommended before investment in a full-scale plant for biofuel driers.

  6. Game Theoretic Analysis of Carbon Emission Abatement in Fashion Supply Chains Considering Vertical Incentives and Channel Structures

    Directory of Open Access Journals (Sweden)

    Longfei He

    2015-04-01

    Full Text Available We study an emission-dependent dyadic fashion supply chain made up of a supplier and a manufacturer, both of which can reduce their own component/product emissions to serve the carbon-footprint sensitive consumers. With Carbon Tax regulation, we consider four scenarios resulting from two ways in form of adopting transfer price contract and/or introducing third-party emission-reduction service (TPERS to enhance the efficiency of systematic emission reductions. We refine four models from these corresponding scenarios, which in turn constitute a decision-making framework composed of determining vertical incentives and choosing supply chain structures. By exploiting Stackelberg games in all models, we compare their emission reduction efficiencies and profitability for each pair of settings. Theoretic analysis and numerical studies show that adopting vertical transfer payment schemes can definitely benefit channel carbon footprint reduction and Pareto improvement of supply chain profitability, regardless of whether the emission-reduction service exists or not. However, whether introducing TPERS or not is heavily depending on systematic parameters when the transfer payment incentive is adopted there. We also provide insights on the sensitivity of carbon tax parameters with respect to the supply chain performance, overall carbon emission reduction, vertical incentive and TPERS adopting decision-makings.

  7. Examination of the conditions of a broadening of the general tax for polluting activities to the intermediate energy consumptions. Incentive mechanisms for the abatement of greenhouse gas emissions; Examen des conditions d'un elargissement de la TGAP aux consommations intermediaires d'energie. Mecanismes incitatifs a la reduction des emissions de gaz a effet de serre

    Energy Technology Data Exchange (ETDEWEB)

    Bureau, D

    2000-05-15

    Among the various existing incentive mechanisms for the abatement of greenhouse gas emissions, like the pollution regulations and the financial help for energy mastery, this document analyzes the conditions of efficiency of the negotiated voluntary agreements and of the tradable emission quotas and their articulation with the fiscality. (J.S.)

  8. Examination of the conditions of a broadening of the general tax for polluting activities to the intermediate energy consumptions. Incentive mechanisms for the abatement of greenhouse gas emissions; Examen des conditions d'un elargissement de la TGAP aux consommations intermediaires d'energie. Mecanismes incitatifs a la reduction des emissions de gaz a effet de serre

    Energy Technology Data Exchange (ETDEWEB)

    Bureau, D

    2000-05-15

    Among the various existing incentive mechanisms for the abatement of greenhouse gas emissions, like the pollution regulations and the financial help for energy mastery, this document analyzes the conditions of efficiency of the negotiated voluntary agreements and of the tradable emission quotas and their articulation with the fiscality. (J.S.)

  9. U.S. Coast Guard Pollution Abatement Program : A Preliminary Report on the Emissions Testing of Boat Diesel Engines

    Science.gov (United States)

    1973-11-01

    The exhaust emission concentrations from three GM6-71's and a Cummins VT-350 diesel engines were measured on a dynamometer as a function of engine load. The GM6-71 engines were newly rebuilt by the Coast Guard; the Cummins Engine was in used conditio...

  10. Greenhouse-Gas Emissions and Abatement Costs of Nuclear, Fossil and Alternative Energy Options from a Life-Circle Perspective. Working paper

    International Nuclear Information System (INIS)

    Fritsche, U.R.

    2007-03-01

    As the issue of nuclear risks in its various forms - from radiation released during uranium mining to severe reactor accidents, and leakage from fuel reprocessing and repositories for spent fuel - is beyond the scope of this paper, we concentrate the following analysis on the more recent issues for which a scientifically reasonable range of data is available. In that respect, two arguments favouring nuclear electricity can be identified: It is allegedly free of CO2, and it is allegedly low cost. In this paper, we address both, presenting results of life-cycle cost and emission analyses of energy systems with respect to current technologies. We discuss the results with respect to other findings in the literature, and also indicate the cost-effectiveness of CO2 abatement in the electricity sector. The scientific work from which this paper draws was sponsored by a variety of sources, including the German Federal Ministry for Environment, Nature Protection, and Nuclear Safety (BMU), German Federal Ministry for Research and Education (BMBF), The Federal Environment Agency of Germany (UBA). (orig./GL)

  11. Soil emission and uptake of carbonyl sulfide at a temperate mountain grassland

    Science.gov (United States)

    Kitz, Florian; Hammerle, Albin; Laterza, Tamara; Spielmann, Felix M.; Wohlfahrt, Georg

    2016-04-01

    Flux partitioning, i.e. inferring gross primary productivity (GPP) and ecosystem respiration from the measured net ecosystem carbon dioxide (CO2) exchange, is one uncertainty in modelling the carbon cycle and in times where robust models are needed to assess future global changes a persistent problem. A promising new approach is to derive GPP by measuring carbonyl sulfide (COS), the most abundant sulfur-containing trace gas in the atmosphere, with a mean concentration of about 500 pptv in the troposphere. This is possible because COS and CO2 enter the leaf via a similar pathway and are processed by the same enzyme (carbonic anhydrase). A prerequisite to use COS as a proxy for canopy photosynthesis is a robust estimation of COS sources and sinks in an ecosystem. Past studies described soils either as a sink or source, depending on properties like soil temperature and soil water content. The main aim of this study was to quantify the soil COS exchange and its drivers of a temperate mountain grassland in order to aid the use of COS as tracer for canopy CO2 and water vapor exchange. We conducted a field campaign with a Quantum cascade laser at a temperate mountain grassland to estimate the soil COS fluxes under ambient conditions and while simulating a drought. We used self-built fused silica (i.e. light-transparent) soil chambers to avoid COS emissions from built-in materials and to assess the impact of radiation. Vegetation was removed within the chambers, therefor more radiation reached the soil surface compared to natural conditions. This might be the reason for highly positive fluxes during daytime more similar to agricultural study sites. To further investigate this large soil COS source we conducted within canopy concentration measurements near the soil surface and still recorded fluxes confirming the soil as a COS source during daytime. Results from the drought experiment suggested a strong impact of incoming radiation on soil COS fluxes followed by soil

  12. Developing a savanna burning emissions abatement methodology for tussock grasslands in high rainfall regions of northern Australia

    Directory of Open Access Journals (Sweden)

    Jeremy Russell-Smith

    2014-06-01

    Full Text Available Fire-prone tropical savanna and grassland systems are a significant source of atmospheric emissions of greenhouse gases.  In recent years, substantial research has been directed towards developing accounting methodologies for savanna burning emissions to be applied in Australia’s National Greenhouse Gas Inventory, as well as for commercial carbon trading purposes.  That work has focused on woody savanna systems.  Here, we extend the methodological approach to include tussock grasslands and associated Melaleuca-dominated open woodlands (<10% foliage cover in higher rainfall (>1,000 mm/annum regions of northern Australia.  Field assessments under dry season conditions focused on deriving fuel accumulation, fire patchiness and combustion relationships for key fuel types: fine fuels − grass and litter; coarse woody fuels − twigs <6 mm diameter; heavy woody fuels − >6 mm diameter; and shrubs.  In contrast with previous savanna burning assessments, fire treatments undertaken under early dry season burning conditions resulted in negligible patchiness and very substantial consumption of fine fuels.  In effect, burning in the early dry season provides no benefits in greenhouse gas emissions and emissions reductions in tussock grasslands can be achieved only through reducing the extent of burning.  The practical implications of reduced burning in higher rainfall northern Australian grassland systems are discussed, indicating that there are significant constraints, including infrastructural, cultural and woody thickening issues.  Similar opportunities and constraints are observed in other international contexts, but especially project implementation challenges associated with legislative, political and governance issues.

  13. Interim report on testing of off-gas treatment technologies for abatement of atmospheric emissions of chlorinated volatile organic compounds

    International Nuclear Information System (INIS)

    Haselow, J.S.; Jarosch, T.R.; Rossabi, J.; Burdick, S.; Lombard, K.

    1993-12-01

    The purpose of this report is to briefly summarize the results to date of the off-gas treatment program for atmospheric emissions of chlorinated volatile organic compounds (CVOCs), in particular trichloroethylene (TCE) and perchloroethylene (PCE). This program is part of the Department of Energy's Office of Technology Development's Integrated Demonstration for Treatment of Organics in Soil and Water at a Non-Arid Site. The off-gas treatment program was initiated after testing of in-situ air stripping with horizontal wells was completed. That successful test expectedly produced atmospheric emissions of CVOCs that were unabated. It was decided after that test that an off-gas treatment program would complement the Integrated Demonstration not only because off-gas treatment is an integral portion of remediation of CVOC contamination in groundwater and soil but also because several technologies were being developed across the US to mitigate CVOC emissions. A single platform for testing off-gas treatment technologies would facilitate systematic and unbiased evaluation of the emerging technologies

  14. Thoughts on abatement and adaptation

    International Nuclear Information System (INIS)

    Revelle, R.R.

    1991-01-01

    A number of questions having to do with the themes of abatement and adaptation are discussed. Under the first rubric are questions of future concentrations of radiatively active trace gases, the linkage of these gases with greenhouse warming, and other environmental problems. Also examined in the abatement context are opportunities to reduce fossil fuel use and therefore the emission of greenhouse gases, and the likelihood that natural forest expansion may provide an opportunity to control the rate of carbon dioxide (CO2) accumulation in the atmosphere. Also discussed are the possible effects of greenhouse warming on agriculture in the United States and in the developing world. Finally, some suggestions are given on capturing and retaining interest in greenhouse warming on the part of the decision making public

  15. Abatement of global warming gas emissions from semiconductor manufacturing processes by non-thermal plasma-catalyst systems

    Energy Technology Data Exchange (ETDEWEB)

    Chang, J-S.; Urashima, K. [McMaster Univ., McIARS and Dept. Eng. Phys., Hamilton, Ontario (Canada)

    2009-07-01

    Emission of various hazardous air pollutants (HAPs) and greenhouse gases including perfluoro-compounds (PFCs) from semiconductor industries may cause significant impact on human health and the global environment, has attracted much public attention. In this paper, an application of nonthermal plasma-adsorbent system for a removal of PFCs emission from semiconductor process flue gases is experimentally investigated. The non-thermal plasma reactor used is the ferro-electric packed-bed type barrier discharge plasma and adsorbent reactor used is Zeolite bed reactor. The results show that for a simulated semiconductor process flue gas with C{sub 2}F{sub 6} (2000ppm)/ CF{sub 4}(1000ppm)/ N{sub 2}O(1000ppm)/ N{sub 2}/ Air mixture, 54% of C{sub 2}F{sub 6} and 32% of CF{sub 4} were decomposed by the plasma reactor and 100% of C{sub 2}F{sub 6} and 98% of CF{sub 4} were removed by plasma reactor/Zeolite adsorbent hybrid system. For a simulated semiconductor process flue gas with NF{sub 3} (2000ppm)/ SiF{sub 4}(1000ppm)/ N{sub 2}O(200ppm)/ N{sub 2}/ Air mixture, 92% of NF{sub 3} and 32% of SiF{sub 4} were decomposed by the plasma reactor and total (100%) removal of the pollutant gases was achieved by plasma reactor/Zeolite adsorbent hybrid system. (author)

  16. Abatement of global warming gas emissions from semiconductor manufacturing processes by non-thermal plasma-catalyst systems

    International Nuclear Information System (INIS)

    Chang, J-S.; Urashima, K.

    2009-01-01

    Emission of various hazardous air pollutants (HAPs) and greenhouse gases including perfluoro-compounds (PFCs) from semiconductor industries may cause significant impact on human health and the global environment, has attracted much public attention. In this paper, an application of nonthermal plasma-adsorbent system for a removal of PFCs emission from semiconductor process flue gases is experimentally investigated. The non-thermal plasma reactor used is the ferro-electric packed-bed type barrier discharge plasma and adsorbent reactor used is Zeolite bed reactor. The results show that for a simulated semiconductor process flue gas with C 2 F 6 (2000ppm)/ CF 4 (1000ppm)/ N 2 O(1000ppm)/ N 2 / Air mixture, 54% of C 2 F 6 and 32% of CF 4 were decomposed by the plasma reactor and 100% of C 2 F 6 and 98% of CF 4 were removed by plasma reactor/Zeolite adsorbent hybrid system. For a simulated semiconductor process flue gas with NF 3 (2000ppm)/ SiF 4 (1000ppm)/ N 2 O(200ppm)/ N 2 / Air mixture, 92% of NF 3 and 32% of SiF 4 were decomposed by the plasma reactor and total (100%) removal of the pollutant gases was achieved by plasma reactor/Zeolite adsorbent hybrid system. (author)

  17. Custo marginal de abatimento de emissões de gases de efeito estufa na recuperação da pastagem = Marginal abatement cost of greenhouse gases emissions in pasture recovery

    Directory of Open Access Journals (Sweden)

    Willian Jun Kimura

    2016-10-01

    financing with the Low Carbon Agriculture Program credit line, using the marginal abatement cost tool. To achieve the proposed goals, financial data from the Center for Advanced Studies in Applied Economics and the Brazilian Confederation of Agriculture and Livestock was used, as well as emissions data from the Intergovernmental Panel on Climate Change and Low Carbon Agriculture Plan in order to simulate an annual net costs and net emissions of current and abatement technologies, represented respectively by a low-tech livestock and a livestock in recovered pasture. The financial and emissions figures of a livestock in a recovered pasture were more favorable in comparison to low-tech livestock. Taking into consideration these two factors, the marginal abatement cost is - R$ 24.72 per tCO2 equivalent. In other words, for each ton of equivalent carbon dioxide mitigated by pasture recovery, the farmer has a financial gain of R$ 24.72 than keeping low-tech livestock. Thus, from a financial and environmental perspective, pasture recovery has shown to be a practice which allows a sustainable increase in food production.

  18. MECHANISTIC STUDIES AND DESIGN OF HIGHLY ACTIVE CUPRATE CATALYSTS FOR THE DIRECT DECOMPOSITION AND SELECTIVE REDUCTION OF NITRIC OXIDE AND HYDROCARBONS TO NITROGEN FOR ABATEMENT OF STACK EMISSIONS

    Energy Technology Data Exchange (ETDEWEB)

    None

    1998-04-30

    A flow trough type catalytic reactor system was adequately modified for NO related catalytic and adsorption measurements, including the on-line connection of a digital chemiluminescent NO-NO{sub x} analyzer to the reactor outlet system. Moreover, we have largely completed the installation of an FTIR coupled catalytic system containing a HTEC cell for high temperature DRIFT studies. Three different barium cuprate samples, Ba{sub 2}CuO{sub 3}, BaCuO{sub 2}, and Ba{sub 2}Cu{sub 3}O{sub 5} were synthesized and characterized by powder XRD for catalytic tests. Prior to catalytic studies over these cuprates, a new, liquid indium based supported molten metal catalyst (In-SMMC) was tested in the reduction of NO by various reductants. In the presence of excess O{sub 2} and H{sub 2}O, the In-SMMC proved to be more active for the selective catalytic reduction (SCR) of NO to N{sub 2} by ethanol than most other catalysts. Using C{sub 1}-C{sub 3} alcohols as reductants, self sustained periodic oscillations observed in the NO{sub x} concentrations of reactor effluents indicated the first time that radical intermediates can be involved in the SCR of NO by alcohols. Further, In-SMMC is the only effective and water tolerant SCR catalyst reported thus far which contains SiO{sub 2} support. Thus, this novel catalyst opens up a promising new alternative for developing an effective and durable catalyst for NO{sub x} abatement in stack emission.

  19. Carbon dioxide abatement as a differential game

    International Nuclear Information System (INIS)

    Tahvonen, O.

    1993-01-01

    The report combines predictions on greenhouse warming, CO 2 abatement costs and adaptation costs in a differential game framework. The specified model makes it possible to solve the payoffs of the subgame perfect solution of a two state variable nonautonomous problem with N unequal countries. Abatement cost parameters are calibrated with a global energy sector model and climate parameters are based on empirical time series. Simulation suggests that the backstop technology assumption in the abatement cost model may imply drastic cuts in optimal emission levels. Compared to the Nash noncooperative equilibrium a pareto optimal agreement is found to be beneficial for developing countries but more costly for the industrial world. Given the present damage estimates, the losses due to an emission stabilizing agreement may be 400 times higher than maximum potential gains from cooperation

  20. Combination of borax and quebracho condensed tannins treatment to reduce hydrogen sulfide, ammonia and greenhouse gas emissions from stored swine manure

    Science.gov (United States)

    Livestock producers are acutely aware for the need to reduce gaseous emissions from stored livestock waste and have been trying to identify new technologies to address the chronic problem. Besides the malodor issue, toxic gases emitted from stored livestock manure, especially hydrogen sulfide (H2S)...

  1. Unmodified versus caustics-impregnated carbons for control of hydrogen sulfide emissions from sewage treatment plants

    Energy Technology Data Exchange (ETDEWEB)

    Bandosz, T.J.; Bagreev, A.; Adib, F.; Turk, A.

    2000-03-15

    Unmodified and caustic-impregnated carbons were compared as adsorbents for hydrogen sulfide in the North River Water Pollution Control Plant in New York City over a period of 2 years. The carbons were characterized using accelerated H{sub 2}S breakthrough capacity tests, sorption of nitrogen, potentiometric titration, and thermal analysis. The accelerated laboratory tests indicate that the initial capacity of caustic-impregnated carbons exceeds that of unmodified carbon, but the nature of real-life challenge streams, particularly their lower H{sub 2}S concentrations, nullifies this advantage. As the caustic content of the impregnated carbon is consumed, the situation reverses, and the unmodified carbon becomes more effective. When the concentration of H{sub 2}S is low, the developed surface area and pore volume along with the affinity to retain water create a favorable environment for dissociative adsorption of hydrogen sulfide and its oxidation to elemental sulfur, S{sup 4+}, and S{sup 6+}. In the case of the caustic carbon, the catalytic impact of the carbon surface is limited, and its good performance lasts only while active base is present. The results also show the significant differences in performance of unmodified carbons due to combined effects of their porosity and surface chemistry.

  2. HFC-23 (CHF3 emission trend response to HCFC-22 (CHClF2 production and recent HFC-23 emission abatement measures

    Directory of Open Access Journals (Sweden)

    R. G. Prinn

    2010-08-01

    Full Text Available HFC-23 (also known as CHF3, fluoroform or trifluoromethane is a potent greenhouse gas (GHG, with a global warming potential (GWP of 14 800 for a 100-year time horizon. It is an unavoidable by-product of HCFC-22 (CHClF2, chlorodifluoromethane production. HCFC-22, an ozone depleting substance (ODS, is used extensively in commercial refrigeration and air conditioning, in the extruded polystyrene (XPS foam industries (dispersive applications and also as a feedstock in fluoropolymer manufacture (a non-dispersive use. Aside from small markets in specialty uses, HFC-23 has historically been considered a waste gas that was, and often still is, simply vented to the atmosphere. Efforts have been made in the past two decades to reduce HFC-23 emissions, including destruction (incineration in facilities in developing countries under the United Nations Framework Convention on Climate Change's (UNFCCC Clean Development Mechanism (CDM, and by process optimization and/or voluntary incineration by most producers in developed countries. We present observations of lower-tropospheric mole fractions of HFC-23 measured by "Medusa" GC/MSD instruments from ambient air sampled in situ at the Advanced Global Atmospheric Gases Experiment (AGAGE network of five remote sites (2007–2009 and in Cape Grim air archive (CGAA samples (1978–2009 from Tasmania, Australia. These observations are used with the AGAGE 2-D atmospheric 12-box model and an inverse method to produce model mole fractions and a "top-down" HFC-23 emission history. The model 2009 annual mean global lower-tropospheric background abundance is 22.6 (±0.2 pmol mol−1. The derived HFC-23 emissions show a "plateau" during 1997–2003, followed by a rapid ~50% increase to a peak of 15.0 (+1.3/−1.2 Gg/yr in 2006. Following this peak, emissions of HFC-23 declined rapidly to 8.6 (+0.9/−1.0 Gg/yr in 2009, the lowest annual emission of the past 15 years. We derive a 1990–2008 "bottom-up" HFC-23 emission history

  3. Marginal abatement cost curves for NOx incorporating both controls and alternative measures

    Science.gov (United States)

    A marginal abatement cost curve (MACC) traces out the efficient marginal abatement cost level for any aggregate emissions target when a least cost approach is implemented. In order for it to represent the efficient MAC level, all abatement opportunities across all sectors and loc...

  4. Emission of hydrogen sulfide (H2S) at a waterfall in a sewer: study of main factors affecting H2S emission and modeling approaches.

    Science.gov (United States)

    Jung, Daniel; Hatrait, Laetitia; Gouello, Julien; Ponthieux, Arnaud; Parez, Vincent; Renner, Christophe

    2017-11-01

    Hydrogen sulfide (H 2 S) represents one of the main odorant gases emitted from sewer networks. A mathematical model can be a fast and low-cost tool for estimating its emission. This study investigates two approaches to modeling H 2 S gas transfer at a waterfall in a discharge manhole. The first approach is based on an adaptation of oxygen models for H 2 S emission at a waterfall and the second consists of a new model. An experimental set-up and a statistical data analysis allowed the main factors affecting H 2 S emission to be studied. A new model of the emission kinetics was developed using linear regression and taking into account H 2 S liquid concentration, waterfall height and fluid velocity at the outlet pipe of a rising main. Its prediction interval was estimated by the residual standard deviation (15.6%) up to a rate of 2.3 g H 2 S·h -1 . Finally, data coming from four sampling campaigns on sewer networks were used to perform simulations and compare predictions of all developed models.

  5. Emission of hydrogen sulfide by leaf tissue in response to L-cysteine

    International Nuclear Information System (INIS)

    Sekiya, J.; Schmidt, A.; Wilson, L.G.; Filner, P.

    1982-01-01

    Leaf discs and detached leaves exposed to L-cysteine emitted a volatile sulfur compound which was proven by gas chromatography to be H 2 S. This phenomenon was demonstrated in all nine species tested (Cucumis sativus, Cucurbita pepo, Nicotiana tabacum, Coleus blumei, Beta vulgaris, Phaseolus vulgaris, Medicago sativa, Hordeum vulgare, and Gossypium hirsutum). The emission of volatile sulfur by cucumber leaves occurred in the dark at a similar rate to that in the light. The emission of leaf discs reached the maximal rate, more than 40 picomoles per minute per square centimeter, 2 to 4 hours after starting exposure to L-cysteine; then it decreased. In the case of detached leaves, the maximum occurred 5 to 10 h after starting exposure. The average emission rate of H 2 S during the first 4 hours from leaf discs of cucurbits in response to 10 millimolar L-cysteine, was usually more than 40 picomoles per minute per square centimeter, i.e. 0.24 micromoles per hour per square decimeter. Leaf discs exposed to 1 millimolar L-cysteine emitted only 2% as much as did the discs exposed to 10 millimolar L-cysteine. The emission from leaf discs and from detached leaves lasted for at least 5 and 15 hours, respectively. However, several hours after the maximal emission, injury of the leaves, manifested as chlorosis, was evident. H 2 S emission was a specific consequence of exposure to L-cysteine; neither D-cysteine nor L-cysteine elicited H 2 S emission. Aminooxyacetic acid, an inhibitor of pyridoxal phosphate dependent enzymes, inhibited the emission. In a cell free system from cucumber leaves, H 2 S formation and its release occurred in response to L-cysteine. Feeding experiments with [ 35 S]t-cysteine showed that most of the sulfur in H 2 S was derived from sulfur in the L-cysteine supplied

  6. Abatement of CO{sub 2} emissions: IFP's solutions; Reduction des emissions de CO{sub 2}: les solutions IFP

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    2003-07-01

    In a context of increasing energy consumption and world economic growth, the fight against greenhouse gases has become a major technological challenge for the coming years. The capture and sequestration of CO{sub 2} in the underground is a promising solution in terms of environmental impact, especially in places and sectors characterized by a strong concentration of CO{sub 2} emissions (power generation plants, big industries). However, such a solution requires important R and D efforts to reduce the costs and warrant the long-term reliability of the storage. The French institute of petroleum (IFP) will play an important role in the implementation of the geological sequestration. This press kit comprises 7 documents: a press release from November 4, 2003; a press conference with a series of slides presenting the stakes, solutions and actions proposed by the IFP in collaboration with several foreign partners (CO{sub 2} capture, storage in depleted hydrocarbon deposits, saline aquifers or abandoned coal seams, storage potential, reduction of costs); a summary of the stakes and solutions for CO{sub 2} sequestration in deep underground; a similar document presented at the Panorama 2003 colloquium; the CO{sub 2} constraint in France and in Europe (international consensus on climatic change, Kyoto protocol, European directive about tradable carbon permits, voluntary commitment of companies in the fight against greenhouse effects (AERES)); the European project Castor (CO{sub 2} from capture to storage); and the IFP brochure 'innovating for a sustainable development in the energy domain'. (J.S.)

  7. Mössbauer emission study on 57Co doped carbon-supported Ni and Ni-Mo sulfide hydrotreating catalysts : the influence of phosphorus on the structure

    NARCIS (Netherlands)

    Crajé, M.W.J.; Beer, de V.H.J.; Kraan, van der A.M.

    1991-01-01

    In the present study it is demonstrated that Mössbauer emission spectroscopy (MES) can generate information on the various Ni phases present in sulfided Ni containing catalysts when a small amount of 57Co is used as a probe for Ni.Application of MES to 57Co:Ni(4.5)Mo(8.0)/C and 57Co:Ni(5.6)/C

  8. Selenium Sulfide

    Science.gov (United States)

    Selenium sulfide, an anti-infective agent, relieves itching and flaking of the scalp and removes the dry, ... Selenium sulfide comes in a lotion and is usually applied as a shampoo. As a shampoo, selenium ...

  9. Implications of sea-ice biogeochemistry for oceanic production and emissions of dimethyl sulfide in the Arctic

    Directory of Open Access Journals (Sweden)

    H. Hayashida

    2017-06-01

    Full Text Available Sea ice represents an additional oceanic source of the climatically active gas dimethyl sulfide (DMS for the Arctic atmosphere. To what extent this source contributes to the dynamics of summertime Arctic clouds is, however, not known due to scarcity of field measurements. In this study, we developed a coupled sea ice–ocean ecosystem–sulfur cycle model to investigate the potential impact of bottom-ice DMS and its precursor dimethylsulfoniopropionate (DMSP on the oceanic production and emissions of DMS in the Arctic. The results of the 1-D model simulation were compared with field data collected during May and June of 2010 in Resolute Passage. Our results reproduced the accumulation of DMS and DMSP in the bottom ice during the development of an ice algal bloom. The release of these sulfur species took place predominantly during the earlier phase of the melt period, resulting in an increase of DMS and DMSP in the underlying water column prior to the onset of an under-ice phytoplankton bloom. Production and removal rates of processes considered in the model are analyzed to identify the processes dominating the budgets of DMS and DMSP both in the bottom ice and the underlying water column. When openings in the ice were taken into account, the simulated sea–air DMS flux during the melt period was dominated by episodic spikes of up to 8.1 µmol m−2 d−1. Further model simulations were conducted to assess the effects of the incorporation of sea-ice biogeochemistry on DMS production and emissions, as well as the sensitivity of our results to changes of uncertain model parameters of the sea-ice sulfur cycle. The results highlight the importance of taking into account both the sea-ice sulfur cycle and ecosystem in the flux estimates of oceanic DMS near the ice margins and identify key uncertainties in processes and rates that should be better constrained by new observations.

  10. Heterogeneous condensation for submicronic particles abatement

    OpenAIRE

    Tammaro, Marco

    2010-01-01

    It is now well established that the emission of sub-micrometric particulate matter entrained in flue gases of industry and vehicles exhausts, is one of the most critical treats for human health because of the toxicological effects of ultrafine particles on the respiratory system and their ability to cross alveoli’s membranes reaching the circulatory system too. Albeit this scenario, the traditional particle abatement devices are mainly designed and optimised to treat particles larger tha...

  11. Assessment of risks for elevated NOx emissions of diesel vehicles outside the boundaries of RDE. Identifying relevant driving and vehicle conditions and possible abatement measures

    NARCIS (Netherlands)

    Mensch, P. van; Cuelenaere, R.F.A.; Ligterink, N.E.

    2017-01-01

    With RDE (Real Driving Emissions) legislation a new chapter in emission testing has started for light-duty vehicles. RDE legislation poses new and more complex engineering targets for manufacturers. The expectation is that RDE will bring major improvements in the emission performance of LD vehicles

  12. Efficient air pollution abatement for regions in China

    Energy Technology Data Exchange (ETDEWEB)

    Hu, J.L. [National Chiao Tung University, Taipei (Taiwan). Inst. for Business & Management

    2006-08-15

    This paper computes the efficient air pollution abatement ratios of 30 regions in China during the period 1996-2002. Three air emissions (SO{sub 2}, soot and dust) are considered. Data envelopment analysis (DEA) with a single output (real GDP) and five inputs (labour, real capital stock, SO{sub 2}, dust and soot emissions) is used to compute the target emissions of each region for each year. The efficient abatement ratios of each region in each year are then obtained by dividing the target emission by the actual emission of an air pollutant. Our major findings are: 1. The eastern area is the most efficient region with respect to SO{sub 2}, soot and dust emissions in every year during the research period. 2. The eastern, central and western areas have the lowest, medium and highest 1996-2002 average target abatement ratios of SO, (22.09%, 42.23% and 57.58%), soot (26.19%, 56.34% and 66.37%) and dust (15.20%, 29.09% and 40.59%), respectively. 3. These results are consistent with the Environmental Kuznets Curve (EKC) theory, whereby a more developed area will use environmental goods more efficiently than a less developed area. 4. Compared to dust emission, the average target abatement ratios for SO{sub 2} and soot emissions (as direct outcomes of burning coal) are relatively much higher for all three areas.

  13. Biological nitrate transport in sediments on the Peruvian margin mitigates benthic sulfide emissions and drives pelagic N loss during stagnation events

    Science.gov (United States)

    Dale, A. W.; Sommer, S.; Lomnitz, U.; Bourbonnais, A.; Wallmann, K.

    2016-06-01

    Benthic N cycling in the Peruvian oxygen minimum zone (OMZ) was investigated at ten stations along 12 °S from the middle shelf (74 m) to the upper slope (1024 m) using in situ flux measurements, sediment biogeochemistry and modeling. Middle shelf sediments were covered by mats of the filamentous bacteria Thioploca spp. and contained a large 'hidden' pool of nitrate that was not detectable in the porewater. This was attributed to a biological nitrate reservoir stored within the bacteria to oxidize sulfide during 'dissimilatory nitrate reduction to ammonium' (DNRA). The extremely high rates of DNRA on the shelf (15.6 mmol m-2 d-1 of N), determined using an empirical steady-state model, could easily supply all the ammonium requirements for anammox in the water column. The model further showed that denitrification by foraminifera may account for 90% of N2 production at the lower edge of the OMZ. At the time of sampling, dissolved oxygen was below detection limit down to 400 m and the water body overlying the shelf had stagnated, resulting in complete depletion of nitrate and nitrite. A decrease in the biological nitrate pool was observed on the shelf during fieldwork concomitant with a rise in porewater sulfide levels in surface sediments to 2 mM. Using a non-steady state model to simulate this natural anoxia experiment, these observations were shown to be consistent with Thioploca surviving on a dwindling intracellular nitrate reservoir to survive the stagnation period. The model shows that sediments hosting Thioploca are able to maintain high ammonium fluxes for many weeks following stagnation, potentially sustaining pelagic N loss by anammox. In contrast, sulfide emissions remain low, reducing the economic risk to the Peruvian fishery by toxic sulfide plume development.

  14. On the cost-effective abatement of CO2-options taking consumer behaviour into account

    International Nuclear Information System (INIS)

    Wietschel, M.; Rentz, O.

    1995-01-01

    The current ecopolitical discussion focusses on the greenhouse effect and the consequent political aim to abate anthropogenic CO 2 emissions. Studies on individual measures for CO 2 abatement and on the development of efficient abatement strategies are already at hand. There is one aspect, however, that has hardly been dealt with as yet: If CO 2 abatement suceeds as it is planned by the Federal Government, then energy and prices will rise considerably, and this will curb the demand for energy. Any efficient abatement strategy must take this into account. The article presents a new concept for energy-emission models that takes consumer behaviour into account and discusses efficient CO 2 abatement strategies following from the application of such models. (orig.) [de

  15. Environmental Abatement and Intergenerational Distribution

    NARCIS (Netherlands)

    Bovenberg, A.L.; Heijdra, B.J.

    1998-01-01

    This paper employs an overlapping generations model to explore the impact of public abatement on private investment and the intergenerational distribution of welfare. Whereas public abatement benefits old generations in terms of non-environmental welfare, future generations gain most in terms of

  16. Biological abatement of cellulase inhibitors

    Science.gov (United States)

    Bio-abatement uses a fungus to metabolize and remove fermentation inhibitors. To determine whether bio-abatement could alleviate enzyme inhibitor effects observed in biomass liquors after pretreatment, corn stover at 10% (w/v) solids was pretreated with either dilute acid or liquid hot water. The ...

  17. Reaction of hydrogen sulfide with oxygen in the presence of sulfite

    Energy Technology Data Exchange (ETDEWEB)

    Weres, O.; Tsao, L.

    1983-01-14

    Commonly, abatement of hydrogen sulfide emission from a geothermal powerplant requires that hydrogen sulfide dissolved in the cooling water be eliminated by chemical reaction. Oxidation by atmospheric oxygen is the preferred reaction, but requires a suitable catalyst. Nickel is the most potent and thereby cheapest catalyst for this purpose. One mg/L nickel in the cooling water would allow 99% removal of hydrogen sulfide to be attained. A major drawback of catalytic air oxidation is that colloidal sulfur is a major reaction product; this causes rapid sludge accumulation and deposition of sulfur scale. We studied the kinetics and product distribution of the reaction of hydrogen sulfide with oxygen, catalyzed by nickel. Adding sodium sulfite to the solution completely suppresses formation of colloidal sulfur by converting it to thiosulfate. The oxidation reaction is an autocatalytic, free radical chain reaction. A rate expression for this reaction and a detailed reaction mechanism were developed. Nickel catalyzes the chain initiation step, and polysulfidoradical ions propagate the chains. Several complexes of iron and cobalt were also studied. Iron citrate and iron N-hydroxyEDTA are the most effective iron based catalysts. Uncomplexed cobalt is as effective as nickel, but forms a precipitate of cobalt oxysulfide and is too expensive for practical use. 33 figures, 9 tables.

  18. Reaction of Hydrogen Sulfide with Oxygen in the Presence ofSulfite

    Energy Technology Data Exchange (ETDEWEB)

    Weres, Oleh; Tsao, Leon

    1983-01-01

    Commonly, abatement of hydrogen sulfide emissions from a geothermal powerplant requires that hydrogen sulfide dissolved in the cooling water be eliminated by chemical reaction. Oxidation by atmospheric oxygen is the preferred reaction, but requires a suitable catalyst. Nickel is the most potent and thereby cheapest catalyst for this purpose. One Mg/L nickel in the cooling water would allow 99% removal of hydrogen sulfide to be attained. A major drawback of catalytic air oxidation is that colloidal sulfur is a major reaction product; this causes rapid sludge accumulation and deposition of sulfur scale. The authors studied the kinetics and product distribution of the reaction of hydrogen sulfide with oxygen, catalyzed by nickel. Adding sodium sulfite to the solution completely suppresses formation of colloidal sulfur by converting it to thiosulfate. The oxidation reaction is an autocatalytic, free radical chain reaction. A rate expression for this reaction and a detailed reaction mechanism were developed. Nickel catalyzes the chain initiation step, and polysulfidoradical ions propagate the chains. Several complexes of iron and cobalt were also studied. Iron citrate and iron N-hydroxyEDT are the most effective iron based catalysts. Uncomplexed cobalt is as effective as nickel, but forms a precipitate of cobalt oxysulfide and is too expensive for practical use.

  19. Marginal Abatement Cost of CO2 in China Based on Directional Distance Function: An Industry Perspective

    Directory of Open Access Journals (Sweden)

    Bowen Xiao

    2017-01-01

    Full Text Available Industrial sectors account for around 70% of the total energy-related CO2 emissions in China. It is of great importance to measure the potential for CO2 emissions reduction and calculate the carbon price in industrial sectors covered in the Emissions Trading Scheme and carbon tax. This paper employs the directional distance function to calculate the marginal abatement costs of CO2 emissions during 2005–2011 and makes a comparative analysis between our study and the relevant literature. Our empirical results show that the marginal abatement costs vary greatly from industry to industry: high marginal abatement costs occur in industries with low carbon intensity, and vice versa. In the application of the marginal abatement cost, the abatement distribution scheme with minimum cost is established under different abatement targets. The conclusions of abatement distribution scheme indicate that those heavy industries with low MACs and high carbon intensity should take more responsibility for emissions reduction and vice versa. Finally, the policy implications for marginal abatement cost are provided.

  20. Sulfide Precipitation in Wastewater at Short Timescales

    DEFF Research Database (Denmark)

    Kiilerich, Bruno; van de Ven, Wilbert; Nielsen, Asbjørn Haaning

    2017-01-01

    Abatement of sulfides in sewer systems using iron salts is a widely used strategy. When dosing at the end of a pumping main, the reaction kinetics of sulfide precipitation becomes important. Traditionally the reaction has been assumed to be rapid or even instantaneous. This work shows that this i......Abatement of sulfides in sewer systems using iron salts is a widely used strategy. When dosing at the end of a pumping main, the reaction kinetics of sulfide precipitation becomes important. Traditionally the reaction has been assumed to be rapid or even instantaneous. This work shows...... that this is not the case for sulfide precipitation by ferric iron. Instead, the reaction time was found to be on a timescale where it must be considered when performing end-of-pipe treatment. For real wastewaters at pH 7, a stoichiometric ratio around 14 mol Fe(II) (mol S(−II))−1 was obtained after 1.5 s, while the ratio...

  1. Measurements of environmental policy for air pollution abatement

    International Nuclear Information System (INIS)

    Friedrich, R.

    1993-01-01

    The first part of the study goes into the determination of efficient strategies for the reduction of air pollutants. The developed method is not only derived theoretically but is tested with the concrete example of emissions sources of a German state. The second part goes into the question what the government can do in order to attain that air pollution abatement measures recognized as being efficient will be put into practice. As market economy mechanisms have advantages over central state planning in the allocation of economic resources the question arises if not also for environmental protection market economy tools may contribute to an improvement of the efficiency of air pollution abatement. Therefore the suitability of different tools of environmental policy for the realization of efficient air pollution abatement is investigated and evaluated. This is again not done abstractly but with existing emission sources. (orig./HSCH). 32 figs., 12 tabs [de

  2. The Effect of Chemical Amendments Used for Phosphorus Abatement on Greenhouse Gas and Ammonia Emissions from Dairy Cattle Slurry: Synergies and Pollution Swapping.

    Directory of Open Access Journals (Sweden)

    Raymond B Brennan

    Full Text Available Land application of cattle slurry can result in incidental and chronic phosphorus (P loss to waterbodies, leading to eutrophication. Chemical amendment of slurry has been proposed as a management practice, allowing slurry nutrients to remain available to plants whilst mitigating P losses in runoff. The effectiveness of amendments is well understood but their impacts on other loss pathways (so-called 'pollution swapping' potential and therefore the feasibility of using such amendments has not been examined to date. The aim of this laboratory scale study was to determine how the chemical amendment of slurry affects losses of NH3, CH4, N2O, and CO2. Alum, FeCl2, Polyaluminium chloride (PAC- and biochar reduced NH3 emissions by 92, 54, 65 and 77% compared to the slurry control, while lime increased emissions by 114%. Cumulative N2O emissions of cattle slurry increased when amended with alum and FeCl2 by 202% and 154% compared to the slurry only treatment. Lime, PAC and biochar resulted in a reduction of 44, 29 and 63% in cumulative N2O loss compared to the slurry only treatment. Addition of amendments to slurry did not significantly affect soil CO2 release during the study while CH4 emissions followed a similar trend for all of the amended slurries applied, with an initial increase in losses followed by a rapid decrease for the duration of the study. All of the amendments examined reduced the initial peak in CH4 emissions compared to the slurry only treatment. There was no significant effect of slurry amendments on global warming potential (GWP caused by slurry land application, with the exception of biochar. After considering pollution swapping in conjunction with amendment effectiveness, the amendments recommended for further field study are PAC, alum and lime. This study has also shown that biochar has potential to reduce GHG losses arising from slurry application.

  3. The Effect of Chemical Amendments Used for Phosphorus Abatement on Greenhouse Gas and Ammonia Emissions from Dairy Cattle Slurry: Synergies and Pollution Swapping.

    Science.gov (United States)

    Brennan, Raymond B; Healy, Mark G; Fenton, Owen; Lanigan, Gary J

    2015-01-01

    Land application of cattle slurry can result in incidental and chronic phosphorus (P) loss to waterbodies, leading to eutrophication. Chemical amendment of slurry has been proposed as a management practice, allowing slurry nutrients to remain available to plants whilst mitigating P losses in runoff. The effectiveness of amendments is well understood but their impacts on other loss pathways (so-called 'pollution swapping' potential) and therefore the feasibility of using such amendments has not been examined to date. The aim of this laboratory scale study was to determine how the chemical amendment of slurry affects losses of NH3, CH4, N2O, and CO2. Alum, FeCl2, Polyaluminium chloride (PAC)- and biochar reduced NH3 emissions by 92, 54, 65 and 77% compared to the slurry control, while lime increased emissions by 114%. Cumulative N2O emissions of cattle slurry increased when amended with alum and FeCl2 by 202% and 154% compared to the slurry only treatment. Lime, PAC and biochar resulted in a reduction of 44, 29 and 63% in cumulative N2O loss compared to the slurry only treatment. Addition of amendments to slurry did not significantly affect soil CO2 release during the study while CH4 emissions followed a similar trend for all of the amended slurries applied, with an initial increase in losses followed by a rapid decrease for the duration of the study. All of the amendments examined reduced the initial peak in CH4 emissions compared to the slurry only treatment. There was no significant effect of slurry amendments on global warming potential (GWP) caused by slurry land application, with the exception of biochar. After considering pollution swapping in conjunction with amendment effectiveness, the amendments recommended for further field study are PAC, alum and lime. This study has also shown that biochar has potential to reduce GHG losses arising from slurry application.

  4. Greenhouse-Gas Emissions and Abatement Costs of Nuclear, Fossil and Alternative Energy Options from a Life-Circle Perspective. Working paper; Treibhausgasemissionen und Vermeidungskosten der nuklearen, fossilen und erneuerbaren Strombereitstellung. Arbeitspapier

    Energy Technology Data Exchange (ETDEWEB)

    Fritsche, U.R.

    2007-03-15

    As the issue of nuclear risks in its various forms - from radiation released during uranium mining to severe reactor accidents, and leakage from fuel reprocessing and repositories for spent fuel - is beyond the scope of this paper, we concentrate the following analysis on the more recent issues for which a scientifically reasonable range of data is available. In that respect, two arguments favouring nuclear electricity can be identified: It is allegedly free of CO2, and it is allegedly low cost. In this paper, we address both, presenting results of life-cycle cost and emission analyses of energy systems with respect to current technologies. We discuss the results with respect to other findings in the literature, and also indicate the cost-effectiveness of CO2 abatement in the electricity sector. The scientific work from which this paper draws was sponsored by a variety of sources, including the German Federal Ministry for Environment, Nature Protection, and Nuclear Safety (BMU), German Federal Ministry for Research and Education (BMBF), The Federal Environment Agency of Germany (UBA). (orig./GL)

  5. Biological abatement of cellulase inhibitors.

    Science.gov (United States)

    Cao, Guangli; Ximenes, Eduardo; Nichols, Nancy N; Zhang, Leyu; Ladisch, Michael

    2013-10-01

    Removal of enzyme inhibitors released during lignocellulose pretreatment is essential for economically feasible biofuel production. We tested bio-abatement to mitigate enzyme inhibitor effects observed in corn stover liquors after pretreatment with either dilute acid or liquid hot water at 10% (w/v) solids. Bio-abatement of liquors was followed by enzymatic hydrolysis of cellulose. To distinguish between inhibitor effects on enzymes and recalcitrance of the substrate, pretreated corn stover solids were removed and replaced with 1% (w/v) Solka Floc. Cellulose conversion in the presence of bio-abated liquors from dilute acid pretreatment was 8.6% (0.1x enzyme) and 16% (1x enzyme) higher than control (non-abated) samples. In the presence of bio-abated liquor from liquid hot water pretreated corn stover, 10% (0.1x enzyme) and 13% (1x enzyme) higher cellulose conversion was obtained compared to control. Bio-abatement yielded improved enzyme hydrolysis in the same range as that obtained using a chemical (overliming) method for mitigating inhibitors. Copyright © 2013 Elsevier Ltd. All rights reserved.

  6. Energy and GHG abatement cost curves

    Energy Technology Data Exchange (ETDEWEB)

    Alvarenga, Rafael [BHP Billiton Base Metals (Australia)

    2010-07-01

    Global warming due to various reasons but especially to emission of green house gases (GHGs) has become a cause for serious concern. This paper discusses the steps taken by BHP Billiton to reduce energy consumption and GHG emissions using cost curves. According to forecasts, global warming is expected to impact Chile badly and the rise in temperature could be between 1 and more than 5 degrees Celsius. Mining in Chile consumes a lot of energy, particularly electricity. Total energy and electricity consumption in 2007 was 13 and 36 % respectively. BHP base metals developed a set of abatement cost curves for energy and GHG in Chile and these are shown in figures. The methodology for the curves consisted of consultant visits to each mine operation. The study also includes mass energy balance and feasibility maps. The paper concludes that it is important to evaluate the potential for reducing emissions and energy and their associated costs.

  7. Gridded anthropogenic emissions inventory and atmospheric transport of carbonyl sulfide in the U.S.: U.S. Anthropogenic COS Source and Transport

    Energy Technology Data Exchange (ETDEWEB)

    Zumkehr, Andrew [Sierra Nevada Research Institute, University of California, Merced California USA; Hilton, Timothy W. [Sierra Nevada Research Institute, University of California, Merced California USA; Whelan, Mary [Sierra Nevada Research Institute, University of California, Merced California USA; Smith, Steve [Joint Global Change Research Institute, PNNL, College Park Maryland USA; Campbell, J. Elliott [Sierra Nevada Research Institute, University of California, Merced California USA

    2017-02-21

    Carbonyl sulfide (COS or OCS), the most abundant sulfur containing gas in the troposphere, has recently emerged as a potentially important atmospheric tracer for the carbon cycle. Atmospheric inverse modeling studies may be able to use existing tower, airborne, and satellite observations of COS to infer information about photosynthesis. However, such analysis relies on gridded anthropogenic COS source estimates that are largely based on industry activity data from over three decades ago. Here we use updated emission factor data and industry activity data to develop a gridded inventory with a 0.1 degree resolution for the U.S. domain. The inventory includes the primary anthropogenic COS sources including direct emissions from the coal and aluminum industries as well as indirect sources from industrial carbon disulfide emissions. Compared to the previously published inventory, we found that the total anthropogenic source (direct and indirect) is 47% smaller. Using this new gridded inventory to drive the STEM/WRF atmospheric transport model, we found that the anthropogenic contribution to COS variation in the troposphere is small relative to the biosphere influence, which is encouraging of carbon cycle applications in this region. Additional anthropogenic sectors with highly uncertain emission factors require further field measurements.

  8. Pilot-scale testing of renewable biocatalyst for swine manure treatment and mitigation of odorous VOCs, ammonia and hydrogen sulfide emissions

    Science.gov (United States)

    Maurer, Devin L.; Koziel, Jacek A.; Bruning, Kelsey; Parker, David B.

    2017-02-01

    Comprehensive control of odors, hydrogen sulfide (H2S), ammonia (NH3), and greenhouse gas (GHG) emissions associated with swine production is a critical need. A pilot-scale experiment was conducted to evaluate surface-applied soybean peroxidase (SBP) and calcium peroxide (CaO2) as a manure additive to mitigate emissions of odorous volatile organic compounds (VOC) including dimethyl disulfide/methanethiol (DMDS/MT), dimethyl trisulfide, n-butyric acid, valeric acid, isovaleric acid, p-cresol, indole, and skatole. The secondary impact on emissions of NH3, H2S, and GHG was also measured. The SBP was tested at four treatments (2.28-45.7 kg/m2 manure) with CaO2 (4.2% by weight of SBP) over 137 days. Significant reductions in VOC emissions were observed: DMDS/MT (36.2%-84.7%), p-cresol (53.1%-89.5%), and skatole (63.2%-92.5%). There was a corresponding significant reduction in NH3 (14.6%-67.6%), and significant increases in the greenhouse gases CH4 (32.7%-232%) and CO2 (20.8%-124%). The remaining emissions (including N2O) were not statistically different. At a cost relative to 0.8% of a marketed hog it appears that SBP/CaO2 treatment could be a promising option at the lowest (2.28 kg/m2) treatment rate for reducing odorous gas and NH3 emissions at swine operations, and field-scale testing is warranted.

  9. Farm-scale testing of soybean peroxidase and calcium peroxide for surficial swine manure treatment and mitigation of odorous VOCs, ammonia and hydrogen sulfide emissions

    Science.gov (United States)

    Maurer, Devin L.; Koziel, Jacek A.; Bruning, Kelsey; Parker, David B.

    2017-10-01

    The swine industry, regulatory agencies, and the public are interested in farm-tested methods for controlling gaseous emissions from swine barns. In earlier lab- and pilot-scale studies, a renewable catalyst consisting of soybean peroxidase (SBP) mixed with calcium peroxide (CaO2) was found to be effective in mitigating gaseous emissions from swine manure. Thus, a farm-scale experiment was conducted at the university's 178-pig, shallow-pit, mechanically-ventilated swine barn to evaluate SBP/CaO2 as a surficial manure pit additive under field conditions. The SBP was applied once at the beginning of the 42-day experiment at an application rate of 2.28 kg m-2 with 4.2% CaO2 added by weight. Gas samples were collected from the primary barn exhaust fans. As compared to the control, significant reductions in gaseous emissions were observed for ammonia (NH3, 21.7%), hydrogen sulfide (H2S, 79.7%), n-butyric acid (37.2%), valeric acid (47.7%), isovaleric acid (39.3%), indole (31.2%), and skatole (43.5%). Emissions of dimethyl disulfide/methanethiol (DMDS/MT) increased by 30.6%. Emissions of p-cresol were reduced by 14.4% but were not statistically significant. There were no significant changes to the greenhouse gas (GHG) emissions of methane (CH4), carbon dioxide (CO2) and nitrous oxide (N2O). The total (material + labor) treatment cost was 2.62 per marketed pig, equivalent to 1.5% of the pig market price. The cost of CaO2 catalyst was ∼60% of materials cost. The cost of soybean hulls (SBP source) was 0.60 per marketed pig, i.e., only 40% of materials cost.

  10. Dynamics of carbon abatement in the Second Generation Model

    International Nuclear Information System (INIS)

    Sands, Ronald D.

    2004-01-01

    The Second Generation Model (SGM) is a collection of computable-general-equilibrium models developed for analysis of policies to reduce greenhouse gas emissions. Behavior of the Second Generation Model, with respect to changes in carbon prices, can be summarized using marginal abatement cost curves. Marginal abatement costs vary over time, as capital stocks adjust to a new set of prices, and across countries, depending in part on the mix of fuels in the existing energy system. This paper documents the production structure in SGM, marginal abatement cost curves derived from SGM with constant-carbon-price experiments, an application to several Energy Modeling Forum scenarios, and a methodology for including carbon capture and disposal in SGM

  11. Environmental and Economic Assessment of Electrothermal Swing Adsorption of Air Emissions from Sheet-Foam Production Compared to Conventional Abatement Techniques.

    Science.gov (United States)

    Johnsen, David L; Emamipour, Hamidreza; Guest, Jeremy S; Rood, Mark J

    2016-02-02

    A life-cycle assessment (LCA) and cost analysis are presented comparing the environmental and economic impacts of using regenerative thermal oxidizer (RTO), granular activated carbon (GAC), and activated carbon fiber cloth (ACFC) systems to treat gaseous emissions from sheet-foam production. The ACFC system has the lowest operational energy consumption (i.e., 19.2, 8.7, and 3.4 TJ/year at a full-scale facility for RTO, GAC, and ACFC systems, respectively). The GAC system has the smallest environmental impacts across most impact categories for the use of electricity from select states in the United States that produce sheet foam. Monte Carlo simulations indicate the GAC and ACFC systems perform similarly (within one standard deviation) for seven of nine environmental impact categories considered and have lower impacts than the RTO for every category for the use of natural gas to produce electricity. The GAC and ACFC systems recover adequate isobutane to pay for themselves through chemical-consumption offsets, whereas the net present value of the RTO is $4.1 M (20 years, $0.001/m(3) treated). The adsorption systems are more environmentally and economically competitive than the RTO due to recovered isobutane for the production process and are recommended for resource recovery from (and treatment of) sheet-foam-production exhaust gas. Research targets for these adsorption systems should focus on increasing adsorptive capacity and saturation of GAC systems and decreasing electricity and N2 consumption of ACFC systems.

  12. New school radon abatement systems

    International Nuclear Information System (INIS)

    Simon, R.F.; Maniscalco, P.J.

    1990-01-01

    This paper describes the methods used to develop a state-of-the-art Radon Abatement system: all aspects of design and implementation from proper sizing radon ventilation ductwork (RVD) in relationship to the amount of free air available in sub-slab aggregate, review of electrical systems with their monitoring devices from the very basic to the more sophisticated type of installation, review abatement designs for their durability and application as well as methods and techniques. Building codes will also be reviewed for commercial construction applications, spot-lighting the usage of specific materials and techniques and their impact on the industry

  13. Economic restructuring in Eastern Europe and acid rain abatement strategies

    International Nuclear Information System (INIS)

    Amann, Markus; Klaassen, Ger; Schoepp, Wolfgang; Soerensen, Lene; Hordijk, Leen

    1992-01-01

    Acid rain abatement strategies in Europe are currently being discussed in view of the expiration of the Helsinki Protocol on SO 2 emission reduction. The changing energy situation in Eastern European countries is expected to have an influence on the deposition pattern in Europe. The paper presents a consistent energy scenario for Eastern European countries and compares optimal strategies to reduce SO 2 emissions. These strategies are based on runs with the RAINS model in which environmental targets have been set based on critical loads for sulphur. The analysis shows that economic restructuring and efficiency improvements in Eastern European countries, as well as in Western Europe, may result in significantly lower sulphur abatement costs. Potential assistance to Eastern Europe to guarantee desired environmental standards in Western countries should therefore focus not only on providing emission control devices but also on the success of the economic transition process. (author)

  14. UNEP greenhouse gas abatement costing studies

    Energy Technology Data Exchange (ETDEWEB)

    Shakespeare Maya, R. (Southern Centre for Energy and Environment (Zimbabwe)); Muguti, E. (Ministry of Transport and Energy. Department of Energy (Zimbabwe)); Fenhann, J.; Morthorst, P.E. (Risoe National Laboratory. Systems Analysis Department (Denmark))

    1992-08-01

    The UNEP (United Nations Environment Programme) programme of Greenhouse Gas Abatement Costing Studies is intended to clarify the economic issues involved in assessing the costs of limiting emissions of greenhouse gases and to propose approaches to comparable costing studies. Phase 1 of the Zimbabwe country study describes the current energy situation in Zimbabwe related to the national economy, energy supply and demand and amounts of greenhouse gas emissions. Factors regarding the geography, (including a map illustrating the degree and character of land degradation by erosion) population, politics, international relations, land-use and management of the energy sector are dealt with in detail and the text is illustrated with data compiled from the study. It is estimated that Zimbabwe consumed 270.4 Tj of energy during 1988 and emitted 21.7 tonnes of carbon dioxide. An emission intensity of 80.2 tonnes/Tj for the whole economy and 63.6 tonnes/Tj for electric power generation alone was calculated. Forecasting for the year 2020 estimated carbon dioxide emission intensities of 73.5 tonnes/Tj for the whole economy and 43.7 tonnes for power generation. Net carbon dioxide emissions are predicted to be 30-42 tonnes during 2020. (AB).

  15. UNEP greenhouse gas abatement costing studies

    International Nuclear Information System (INIS)

    Shakespeare Maya, R.; Muguti, E.; Fenhann, J.; Morthorst, P.E.

    1992-08-01

    The UNEP (United Nations Environment Programme) programme of Greenhouse Gas Abatement Costing Studies is intended to clarify the economic issues involved in assessing the costs of limiting emissions of greenhouse gases and to propose approaches to comparable costing studies. Phase 1 of the Zimbabwe country study describes the current energy situation in Zimbabwe related to the national economy, energy supply and demand and amounts of greenhouse gas emissions. Factors regarding the geography, (including a map illustrating the degree and character of land degradation by erosion) population, politics, international relations, land-use and management of the energy sector are dealt with in detail and the text is illustrated with data compiled from the study. It is estimated that Zimbabwe consumed 270.4 Tj of energy during 1988 and emitted 21.7 tonnes of carbon dioxide. An emission intensity of 80.2 tonnes/Tj for the whole economy and 63.6 tonnes/Tj for electric power generation alone was calculated. Forecasting for the year 2020 estimated carbon dioxide emission intensities of 73.5 tonnes/Tj for the whole economy and 43.7 tonnes for power generation. Net carbon dioxide emissions are predicted to be 30-42 tonnes during 2020. (AB)

  16. Regional differences in China's CO2 abatement cost

    International Nuclear Information System (INIS)

    He, Xiaoping

    2015-01-01

    Under a framework of output distance function with multiple outputs, the study discusses the carbon abatement cost at provincial and regional levels in China, using the shadow price analysis. The findings show that the abatement cost, reflecting the marginal opportunity cost of carbon reduction, varies greatly among the provinces. On average, the abatement cost of the eastern region was much higher than that of the mid-western region during the observed period. The findings provide evidence that the carbon prices in the current ETS pilots have been much lower than desired levels, implying inefficiency of the markets. The wide range of the abatement cost estimates supports that the equi-marginal principle does not hold for the regulations on carbon pollution at regional levels. The regional cost differences indicate the huge potential for China to minimize the total abatement cost with policy instruments that may motive the emissions moving from areas of low abatement cost to where the abatement cost is higher. For a few undeveloped provinces that are environmentally fragile and have high abatement cost, supplementary measures will be needed to reduce the negative impact of carbon cutbacks on the poor to the minimum. - Highlights: • The marginal abatement cost of CO 2 is defined by the shadow price measure. • A linear programming model based on distance function is established. • Marginal abatement costs at provincial level are empirical investigated. • The abatement cost varies across provinces and regions in China. • The findings provide evidence that the current ETS pilots are inefficient

  17. Particulate emission abatement for Krakow boiler houses

    International Nuclear Information System (INIS)

    Wysk, S.R.; Surowka, J.

    1995-01-01

    Environmental clean-up and pollution control are considered top priorities in Poland. The magnitude of environmental problems and public awareness of it has forced the Polish government to implement more aggressive regulatory controls. The extent of this condition has in fact prompted the government to designate pollution control a a top priority for foreign investment. During the past five years, Poland has also made significant progress in reorienting its central-planned economy to one based on open market principals. Efforts to decentralize has led to the privatization of many government-owned businesses with a concomitant shift in buying decisions to privately-owned enterprises. This movement toward privatizing the economy along with cleaning and protecting the environment has created numerous business opportunities for both Polish and foreign companies. As a result, there has been a drastic downsizing of large formerly state-owned companies. And, new startups and small businesses have become the main hope in reviving the Polish economy

  18. Particulate emission abatement for Krakow boiler houses

    Energy Technology Data Exchange (ETDEWEB)

    Wysk, S.R. [LSR Technologies, Inc., Acton, MA (United States); Surowka, J. [Polish Foundation for Energy Efficiency, Katowice (Poland)

    1995-11-01

    Environmental clean-up and pollution control are considered top priorities in Poland. The magnitude of environmental problems and public awareness of it has forced the Polish government to implement more aggressive regulatory controls. The extent of this condition has in fact prompted the government to designate pollution control a a top priority for foreign investment. During the past five years, Poland has also made significant progress in reorienting its central-planned economy to one based on open market principals. Efforts to decentralize has led to the privatization of many government-owned businesses with a concomitant shift in buying decisions to privately-owned enterprises. This movement toward privatizing the economy along with cleaning and protecting the environment has created numerous business opportunities for both Polish and foreign companies. As a result, there has been a drastic downsizing of large formerly state-owned companies. And, new startups and small businesses have become the main hope in reviving the Polish economy.

  19. The nitrogen abatement cost in wetlands

    International Nuclear Information System (INIS)

    Bystroem, Olof

    1998-01-01

    The costs of abating agricultural nitrogen pollution in wetlands are estimated. By linking costs for construction of wetlands to the denitrification capacity of wetlands, an abatement cost function can be formed. A construction-cost function and a denitrification function for wetlands is estimated empirically. This paper establishes a link between abatement costs and the nitrogen load on wetlands. Since abatement costs fluctuate with nitrogen load, ignoring this link results in incorrect estimates of abatement costs. The results demonstrate that wetlands have the capacity to provide low cost abatement of nitrogen compounds in runoff. For the Kattegatt region in Sweden, marginal abatement costs for wetlands are shown to be lower than costs of land use changing measures, such as extended land under fallow or cultivation of fuel woods, but higher than the marginal costs of reducing nitrogen fertilizer

  20. Optimal strategies for the abatement of gaseous air pollutant emissions produced by human mobility. The Rome case study; Strategie ottimali per la riduzione delle emissioni di inquinanti gassosi prodotte dalla mobilita' urbana. Un'applicazione al caso di Roma

    Energy Technology Data Exchange (ETDEWEB)

    Santostefano, S.; Cirillo, M.C. [ENEA, Centro Ricerche Casaccia, Rome (Italy). Dipt. Ambiente

    1999-07-01

    In this paper a cost-effectiveness of gaseous vehicular emission reduction has been carried out for human mobility, over the transport network in Rome: in other words, once a reduction target of total emissions has been fixed for each pollutant, the most efficient abatement measures from a technical-economic point of view are selected. The optimization problem has been formalized considering linear functions both for the objective function and for constrains, i.e. within the classic linear programming framework, the objective being that of finding the diversion of present vehicular traffic to alternative technologies with lower emissions at minimum costs. A set of transport alternative measures has been considered and emission abatement cost minimization has been assumed as an objective function; specified abatements for CO (Carbon monoxide), NO{sub x} (nitrogen oxides) and VOC (Volatile Organic Compounds) emissions have been introduced as constraints to the problem, expressed as reduction rates of estimated present emissions in the considered area. Model results show the distribution of present transportation capacity among possible alternatives for different hypothesis of emission reduction rates (reduction of 25%, 50%, 75%, 85% of present emissions and maximum feasible reduction within the specified constraints), and related costs. [Italian] In questo rapporto e' stata condotta un'analisi costi-efficacia relativa alla riduzione delle emissioni gassose veicolari dovute alla mobilita' urbana sulla rete di trasporto di Roma: in altre parole, fissata una quota di abbattimento delle emissioni complessive per ogni inquinante, sono state individuate le misure piu' efficienti dal punto di vista tecnico-economico che permettono di perseguire la riduzione prefissata. Il problema di ottimizzazione e' stato formalizzato definendo sia la funzione obiettivo che i relativi vincoli come funzioni lineari, e quindi nell'ambito della programmazione

  1. Marginal abatement cost curves in general equilibrium: The influence of world energy prices

    International Nuclear Information System (INIS)

    Klepper, Gernot; Peterson, Sonja

    2006-01-01

    Marginal abatement cost curves (MACCs) are a favorite instrument to analyze international emissions trading. This paper focuses on the question of how to define MACCs in a general equilibrium context where the global abatement level influences energy prices and in turn national MACCs. We discuss the mechanisms theoretically and then use the CGE model DART for quantitative simulations. The result is, that changes in energy prices resulting from different global abatement levels do indeed affect national MACCs. Also, we compare different possibilities of defining MACCs-of which some are robust against changes in energy prices while others vary considerably. (author)

  2. Nuclear Power Generation and CO2 Abatement Scenarios in Taiwan

    OpenAIRE

    Chang-Bin Huang; Fu-Kuang Ko

    2009-01-01

    Taiwan was the first country in Asia to announce "Nuclear-Free Homeland" in 2002. In 2008, the new government released the Sustainable Energy Policy Guidelines to lower the nationwide CO2 emissions some time between 2016 and 2020 back to the level of year 2008, further abatement of CO2 emissions is planed in year 2025 when CO2 emissions will decrease to the level of year 2000. Besides, under consideration of the issues of energy, environment and economics (3E), the new go...

  3. Marginal abatement cost curves for NOx that account for ...

    Science.gov (United States)

    A marginal abatement cost curve (MACC) traces out the relationship between the quantity of pollution abated and the marginal cost of abating each additional unit. In the context of air quality management, MACCs typically are developed by sorting end-of-pipe controls by their respective cost effectiveness. Alternative measures, such as renewable electricity, energy efficiency, and fuel switching (RE/EE/FS), are not considered as it is difficult to quantify their abatement potential. In this paper, we demonstrate the use of an energy system model to develop a MACC for nitrogen oxides (NOx) that incorporates both end-of-pipe controls and these alternative measures. We decompose the MACC by sector, and evaluate the cost-effectiveness of RE/EE/FS relative to end-of-pipe controls. RE/EE/FS are shown to produce considerable emission reductions after end-of-pipe controls have been exhausted. Furthermore, some RE/EE/FS are shown to be cost-competitive with end-of-pipe controls. Demonstrate how the MARKAL energy system model can be used to evaluate the potential role of renewable electricity, energy efficiency and fuel switching (RE/EE/FS) in achieving NOx reductions. For this particular analysis, we show that RE/EE/FSs are able to increase the quantity of NOx reductions available for a particular marginal cost (ranging from $5k per ton to $40k per ton) by approximately 50%.

  4. UNEP greenhouse gas abatement costing studies

    International Nuclear Information System (INIS)

    Maya, R.S.; Nziramasanga, N.; Muguti, E.; Fenhann, J.

    1993-10-01

    The aim was to assess options and cost of reducing emissions of greenhouse gases (with emphasis on carbon dioxide) from human activity in Zimbabwe. A brief description of the country's economy and energy sector, policy and pricing and regulations is given and substantial data related to the country's economy, technology, energy consumption, emission and fuel prices are presented. The energy demand in households and for other sectors in Zimbabwe are assessed, and documented in the case of the former. The reference scenarios on energy demand and supply assess greenhouse gas emissions under conditions whereby the present economic growth trends predominate. Energy efficiency improvements are discussed. Abatement technology options are stated as afforestation for carbon sequestration, more efficient coal-fired industrial boilers, extended use of hydroelectricity, prepayment electric meters, minimum tillage, optimization of coal-fired tobacco barns, industrial power factor correction equipment, domestic biogas digesters, solar water heating systems, time switches in electric geysers, optimization of industrial furnaces, photovoltaic water pumps, production of ammonia from coal for fertilizing purposes, and recovery of coke oven gases for use in thermal power generation. (AB)

  5. Relative Greenhouse Gas Abatement Cost Competitiveness of Biofuels in Germany

    Directory of Open Access Journals (Sweden)

    Markus Millinger

    2018-03-01

    Full Text Available Transport biofuels derived from biogenic material are used for substituting fossil fuels, thereby abating greenhouse gas (GHG emissions. Numerous competing conversion options exist to produce biofuels, with differing GHG emissions and costs. In this paper, the analysis and modeling of the long-term development of GHG abatement and relative GHG abatement cost competitiveness between crop-based biofuels in Germany are carried out. Presently dominant conventional biofuels and advanced liquid biofuels were found not to be competitive compared to the substantially higher yielding options available: sugar beet-based ethanol for the short- to medium-term least-cost option and substitute natural gas (SNG for the medium to long term. The competitiveness of SNG was found to depend highly on the emissions development of the power mix. Silage maize-based biomethane was found competitive on a land area basis, but not on an energetic basis. Due to land limitations, as well as cost and GHG uncertainty, a stronger focus on the land use of crop-based biofuels should be laid out in policy.

  6. Prospective life cycle carbon abatement for pyrolysis biochar systems in the UK

    International Nuclear Information System (INIS)

    Hammond, Jim; Shackley, Simon; Sohi, Saran; Brownsort, Peter

    2011-01-01

    Life cycle assessment (LCA) of slow pyrolysis biochar systems (PBS) in the UK for small, medium and large scale process chains and ten feedstocks was performed, assessing carbon abatement and electricity production. Pyrolysis biochar systems appear to offer greater carbon abatement than other bioenergy systems. Carbon abatement of 0.7-1.3 t CO 2 equivalent per oven dry tonne of feedstock processed was found. In terms of delivered energy, medium to large scale PBS abates 1.4-1.9 t CO 2 e/MWh, which compares to average carbon emissions of 0.05-0.30 t CO 2 e/MWh for other bioenergy systems. The largest contribution to PBS carbon abatement is from the feedstock carbon stabilised in biochar (40-50%), followed by the less certain indirect effects of biochar in the soil (25-40%)-mainly due to increase in soil organic carbon levels. Change in soil organic carbon levels was found to be a key sensitivity. Electricity production off-setting emissions from fossil fuels accounted for 10-25% of carbon abatement. The LCA suggests that provided 43% of the carbon in the biochar remains stable, PBS will out-perform direct combustion of biomass at 33% efficiency in terms of carbon abatement, even if there is no beneficial effect upon soil organic carbon levels from biochar application. - Research highlights: → Biochar systems offer greater carbon abatement than combustion or gasification. → Carbon abatement of 0.7-1.4t CO 2 e/dry tonne of feedstock processed was found. → Change in soil organic carbon stocks induced by biochar is the key sensitivity. → Biochar systems produce less electricity then combustion or gasification.

  7. Marginal abatement cost curve for nitrogen oxides incorporating controls, renewable electricity, energy efficiency, and fuel switching.

    Science.gov (United States)

    Loughlin, Daniel H; Macpherson, Alexander J; Kaufman, Katherine R; Keaveny, Brian N

    2017-10-01

    A marginal abatement cost curve (MACC) traces out the relationship between the quantity of pollution abated and the marginal cost of abating each additional unit. In the context of air quality management, MACCs are typically developed by sorting control technologies by their relative cost-effectiveness. Other potentially important abatement measures such as renewable electricity, energy efficiency, and fuel switching (RE/EE/FS) are often not incorporated into MACCs, as it is difficult to quantify their costs and abatement potential. In this paper, a U.S. energy system model is used to develop a MACC for nitrogen oxides (NO x ) that incorporates both traditional controls and these additional measures. The MACC is decomposed by sector, and the relative cost-effectiveness of RE/EE/FS and traditional controls are compared. RE/EE/FS are shown to have the potential to increase emission reductions beyond what is possible when applying traditional controls alone. Furthermore, a portion of RE/EE/FS appear to be cost-competitive with traditional controls. Renewable electricity, energy efficiency, and fuel switching can be cost-competitive with traditional air pollutant controls for abating air pollutant emissions. The application of renewable electricity, energy efficiency, and fuel switching is also shown to have the potential to increase emission reductions beyond what is possible when applying traditional controls alone.

  8. How large a carbon tax is justified by the secondary benefits of CO2 abatement?

    International Nuclear Information System (INIS)

    Ekins, Paul

    1996-01-01

    The combustion of fossil fuels emits a range of damaging pollutants, the emissions of which are reduced if fossil fuel use is reduced in order to achieve CO 2 abatement. These reductions are termed the secondary benefits of such abatement. The paper reviews estimates of the size of these benefits at current levels of emissions of the relevant pollutants. Although the estimates are few and uncertain, their mid-range suggests that the secondary benefits are of the same order of magnitude as the gross costs of medium to high levels of CO 2 abatement, and are substantially larger than the (equally uncertain) estimates of the primary benefits of CO 2 abatement, except where these benefits derive from consideration of damages from unabated global warming in the very long term. The paper then reviews these calculations in the light of the limits on SO 2 emissions mandated by the Second Sulphur Protocol (SSP). It finds that the secondary benefits from abating SO 2 alone beyond the limits of the SSP still provide a substantial offset to the costs of a carbon tax. The paper concludes that the existence of significant secondary benefits greatly reinforces the economic case for an aggressive policy of CO 2 abatement

  9. Estimating the National Carbon Abatement Potential of City Policies: A Data- Driven Approach

    Energy Technology Data Exchange (ETDEWEB)

    Eric O’Shaughnessy, Jenny Heeter, David Keyser, Pieter Gagnon, and Alexandra Aznar

    2016-10-01

    Cities are increasingly taking actions such as building code enforcement, urban planning, and public transit expansion to reduce emissions of carbon dioxide in their communities and municipal operations. However, many cities lack the quantitative information needed to estimate policy impacts and prioritize city actions in terms of carbon abatement potential and cost effectiveness. This report fills this research gap by providing methodologies to assess the carbon abatement potential of a variety of city actions. The methodologies are applied to an energy use data set of 23,458 cities compiled for the U.S. Department of Energy’s City Energy Profile tool. The analysis estimates the national carbon abatement potential of the most commonly implemented actions in six specific policy areas. The results of this analysis suggest that, in aggregate, cities could reduce nationwide carbon emissions by about 210 million metric tons of carbon dioxide (MMT CO2) per year in a "moderate abatement scenario" by 2035 and 480 MMT CO2/year in a "high abatement scenario" by 2035 through these common actions typically within a city’s control in the six policy areas. The aggregate carbon abatement potential of these specific areas equates to a reduction of 3%-7% relative to 2013 U.S. emissions. At the city level, the results suggest the average city could reduce carbon emissions by 7% (moderate) to 19% (high) relative to current city-level emissions. City carbon abatement potential is sensitive to national and state policies that affect the carbon intensity of electricity and transportation. Specifically, the U.S. Clean Power Plan and further renewable energy cost reductions could reduce city carbon emissions overall, helping cities achieve their carbon reduction goals.

  10. Environmental Pollution Prevention, Control and Abatement

    Science.gov (United States)

    1977-08-30

    AD-A271 117 fDATE August 30. 1977 ASD (ORA&L) Department of Defense Instruction SUBJECT: Environmental Pollution Prevention, Control and Abatement...Ensure that any funds appropriated and apportioned for the prevention, control, and abatement of environmental pollution are not used for any other...77 References (a) Executive Order 11752, "Prevention, Control, and Abatement of Environmental Pollution at Federal Facilities," December 19, 1973 (b

  11. UNEP greenhouse gas abatement costing studies

    International Nuclear Information System (INIS)

    Morthorst, P.E.; Grohnheit, P.E.

    1992-04-01

    The project initiated by the United Nations Environment Programme aims to clarify some economic issues involved in greenhouse gas limitation by carrying out comparative studies of various nations. The programme should contribute to the establishment of a consistent methodological framework for making cost assessments of greenhouse gas abatement and help to support countries in the process of establishing national and international agreements on actions to combat climate change. The publication gives a survey of Danish energy demand and supply, emissions and current energy policy issues and reviews existing studies of carbon dioxide reductions. This includes the overall national environmental policy and the plan of action for the transport sector. Conclusions are that there seems to be a long-term potential for significant reduction of CO 2 emission by 10-15% by 2010 with no additional costs, a 50% reduction will cost DKK 25-50 per kg reduced CO 2 . The most promising options include increased use of cogeneration of heat and electricity, and electricity conservation in households, services and in industry. Economic growth is forecast as ca. 2.7% and energy prices for oil products should increase by ca. 4.8%. A 40% reduction of CO 2 emission in the year 2005 would increase costs by 1-2%, and a reduction of two thirds of present emission should be possible at no additional cost compared to the reference cases. There is general agreement that a reduction of carbon dioxide emission of 15-30% by 2005-10 should involve no additional costs to society. (AB) (11 refs.)

  12. Regional Marginal Abatement Cost Curves for NOx

    Data.gov (United States)

    U.S. Environmental Protection Agency — Data underlying the figures included in the manuscript "Marginal abatement cost curve for NOx incorporating controls, renewable electricity, energy efficiency and...

  13. Maryland Cleaning & Abatement Services Corp. Information Sheet

    Science.gov (United States)

    Maryland Cleaning & Abatement Services Corp. (the Company) is located in Baltimore, Maryland. The settlement involves renovation activities conducted at property constructed prior to 1978, located in Baltimore, Maryland.

  14. Marginal abatement cost curves for policy recommendation – A method for energy system analysis

    International Nuclear Information System (INIS)

    Tomaschek, Jan

    2015-01-01

    The transport sector is seen as one of the key factors for driving future energy consumption and greenhouse gas (GHG) emissions. In order to rank possible measures marginal abatement cost curves have become a tool to graphically represent the relationship between abatement costs and emission reduction. This paper demonstrates how to derive marginal abatement cost curves for well-to-wheel GHG emissions of the transport sector considering the full energy provision chain and the interlinkages and interdependencies within the energy system. Presented marginal abatement cost curves visualize substitution effects between measures for different marginal mitigation costs. The analysis makes use of an application of the energy system model generator TIMES for South Africa (TIMES-GEECO). For the example of Gauteng province, this study exemplary shows that the transport sector is not the first sector to address for cost-efficient reduction of GHG emissions. However, the analysis also demonstrates that several options are available to mitigate transport related GHG emissions at comparable low marginal abatement costs. This methodology can be transferred to other economic sectors as well as to other regions in the world to derive cost-efficient GHG reduction strategies

  15. Direct crowding out, optimal taxation and pollution abatement

    Energy Technology Data Exchange (ETDEWEB)

    Van der Ploeg, Frederick [FEE, University of Amsterdam, Amsterdam (Netherlands); Bovenberg, A. Lans [CentER, Tilburg University, Tilburg (Netherlands)

    1993-05-01

    The interactions between direct crowding out, the provision of public goods, optimal taxation and environmental policy are explored. Greener preferences induce a larger tax rate by raising the non-distortionary level of the tax rate. If the marginal productivity of public abatement diminishes rapidly environmental quality improves mainly through a fall in economic activity and emissions. In this case, public consumption increases which crowds out labour supply and private consumption. However, if environmental policy is very effective public consumption falls in order to make room for public abatement. In this case, if labour supply is inelastic with respect to the after-tax wage and direct crowding in is strong, labour supply and economic activity may expand. 1 fig., 7 refs.

  16. Technical efficiency and CO2 abatement policies in the Dutch glasshouse industry

    NARCIS (Netherlands)

    Oude Lansink, A.G.J.M.

    2003-01-01

    This paper develops a short-run microeconomic simulation model of the Dutch glasshouse industry in order to investigate the relation between technical efficiency and marginal abatement costs of CO2 emission. The model is also used to determine the effects of an emission tax and systems of tradable

  17. Impact of policies and measures devoted to the abatement of greenhouse gas emissions; L'impact des politiques et mesures destinees a reduire les emissions de gaz a effet de serre

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    2002-07-01

    This document is the proceedings of the 7. session of the series of conferences on energy policies jointly organized by the general commission of national development and the general direction of energy and raw materials (DGEMP). A first part is devoted to the presentation of the report entitled 'greenhouse effect: economic modeling and public decision'. This report presents the work carried out for the building of a reference scenario for the evaluation of the expected impact of policies and measures on the evolution of CO{sub 2} emissions. A second part gives some comments about the cost-benefit impacts of environmental policies and the last part summarizes the interventions of some of the participants during the debates. (J.S.)

  18. Marginal abatement cost curves and the optimal timing of mitigation measures

    International Nuclear Information System (INIS)

    Vogt-Schilb, Adrien; Hallegatte, Stéphane

    2014-01-01

    Decision makers facing abatement targets need to decide which abatement measures to implement, and in which order. Measure-explicit marginal abatement cost curves depict the cost and abating potential of available mitigation options. Using a simple intertemporal optimization model, we demonstrate why this information is not sufficient to design emission reduction strategies. Because the measures required to achieve ambitious emission reductions cannot be implemented overnight, the optimal strategy to reach a short-term target depends on longer-term targets. For instance, the best strategy to achieve European's −20% by 2020 target may be to implement some expensive, high-potential, and long-to-implement options required to meet the −75% by 2050 target. Using just the cheapest abatement options to reach the 2020 target can create a carbon-intensive lock-in and make the 2050 target too expensive to reach. Designing mitigation policies requires information on the speed at which various measures to curb greenhouse gas emissions can be implemented, in addition to the information on the costs and potential of such measures provided by marginal abatement cost curves. - Highlights: • Classification of existing Marginal Abatement Cost Curves (MACC). • MACCs do not provide separated data on the speed at which measures can be implemented. • Optimal measures to reach a short-term target depend on longer-term targets. • Unique carbon price or aggregated emission-reduction target may be insufficient. • Room for short-term sectoral policies if agents are myopic or governments cannot commit

  19. Improving pure red upconversion emission of Co-doped Y{sub 2}O{sub 3}:Yb{sup 3+}–Er{sup 3+} nanocrystals with a combination of sodium sulfide and surfactant Pluronic-F127

    Energy Technology Data Exchange (ETDEWEB)

    López-Luke, T., E-mail: tzarara@cio.mx [Centro de Investigaciones en Óptica, A.P. 1-948, León, Gto. 37160, México (Mexico); De la Rosa, E., E-mail: elder@cio.mx [Centro de Investigaciones en Óptica, A.P. 1-948, León, Gto. 37160, México (Mexico); Campos Villalobos, I. [Centro de Investigaciones en Óptica, A.P. 1-948, León, Gto. 37160, México (Mexico); Rodriguez, R.A. [Universidad de Guadalajara, Unidad Lagos, Lagos de Moreno, Jal. 47460, México (Mexico); Ángles-Chávez, C. [Instituto Mexicano del Petróleo, Cd. México, D.F. 07730, México (Mexico); Salas, P. [Centro de Física Aplicada y Tecnología Avanzada, Universidad Nacional Autónoma de México, A.P. 1-1010, Querétaro, Qro. 76000, México (Mexico); Wheeler, Damon A.; Zhang, J.Z. [Department of Chemistry and Biochemistry, University of California, Santa Cruz, CA 95064 (United States)

    2014-01-15

    Nanocrystals of Y{sub 2}O{sub 3}:Yb{sup 3+}–Er{sup 3+} (2:1 mol% Yb{sup 3+}:Er{sup 3+}) were prepared by a novel precipitation technique using Na{sub 2}S and Pluronic-F127 (PF127) surfactant. Crystal structure, particle size, red emission intensity and fluorescence decay lifetimes were determined using microscopy and spectroscopy techniques. TEM analysis indicates that the average particle size ranged from 40 to 70 nm. The nanocrystals showed a strong red emission band centered at 663 nm after excitation at 970 nm. The upconverted signal intensity was improved 250% with an optimum concentration of Na{sub 2}S (0.48 M) and PF127 (0.1 mM). The improvement was explained in terms of the reduction of surface contaminants as well as the cubic crystalline phase of the parent Y{sub 2}O{sub 3} material. Interestingly, the formation of sulfates (SO{sub 4}{sup 2−}) is faster than that of O–H, which is responsible for quenching the red and green emissions. The results suggest that Na{sub 2}S and PF127 are good candidates for surface passivation, especially when used in conjunction. The preparation of Y{sub 2}O{sub 3}:Yb{sup 3+}–Er{sup 3+} using Na{sub 2}S with strong red emission band was produced at a lower cost than that of other sulfuration processes. -- Highlights: • . • Strong red emission band centered at 663 nm was obtained after excitation at 970 nm. • Yb-Er codoped Y2O3 nanocrystals with average size ranging from 40 to 70 nm. • Improvement of the red emission in Y2O3:Yb-Er nanocrystals by the introduction of sodium sulfide and pluronic. • Passivation of nanocrystal surface with sodium sulfide and pluoronic.

  20. On the fair division of greenhouse gas abatement cost

    Energy Technology Data Exchange (ETDEWEB)

    Boehringer, Christoph [University of Oldenburg, Department of Economics, Ammerlaender Heerstrasse 114-118, D-26111 Oldenburg (Germany); Centre for European Economic Research (ZEW), Mannheim (Germany); Helm, Carsten [Darmstadt University of Technology, Department of Law and Economics, Marktplatz 15, D-64283 Darmstadt (Germany)

    2008-05-15

    This paper introduces a solution for the fair division of emission reduction costs in the climate change regime. Our primary focus is on the fair division of efficiency gains that arise from exchanging the initial allocation of emission entitlements, rather than the initial allocation itself. We propose to complement the competitive Walrasian solution with welfare bounds, the ethical justification of which rests on commonality of ownership. Simulations with an intertemporal computable general equilibrium model illustrate the relevance of such welfare bounds. For a wide range of initial allocations of emission entitlements - including an equal per capita allocation - we find that developing countries should be fully compensated for their emission abatement efforts, but should not receive any further transfers. (author)

  1. Climate and air quality-driven scenarios of ozone and aerosol precursor abatement

    International Nuclear Information System (INIS)

    Rypdal, Kristin; Rive, Nathan; Berntsen, Terje; Fagerli, Hilde; Klimont, Zbigniew; Mideksa, Torben K.; Fuglestvedt, Jan S.

    2009-01-01

    In addition to causing domestic and regional environmental effects, many air pollutants contribute to radiative forcing (RF) of the climate system. However, climate effects are not considered when cost-effective abatement targets for these pollutants are established, nor are they included in current international climate agreements. We construct air pollution abatement scenarios in 2030 which target cost-effective reductions in RF in the EU, USA, and China and compare these to abatement scenarios which instead target regional ozone effects and particulate matter concentrations. Our analysis covers emissions of PM (fine, black carbon and organic carbon), SO 2 , NO x , CH 4 , VOCs, and CO. We find that the effect synergies are strong for PM/BC, VOC, CO and CH 4 . While an air quality strategy targeted at reducing ozone will also reduce RF, this will not be the case for a strategy targeting particulate matter. Abatement in China dominates RF reduction, but there are cheap abatement options also available in the EU and USA. The justification for international cooperation on air quality issues is underlined when the co-benefits of reduced RF are considered. Some species, most importantly SO 2 , contribute a negative forcing on climate. We suggest that given current knowledge, NO x and SO 2 should be ignored in RF-targeted abatement policies.

  2. SULFIDE MINERALS IN SEDIMENTS

    Science.gov (United States)

    The formation processes of metal sulfides in sediments, especially iron sulfides, have been the subjects of intense scientific research because of linkages to the global biogeochemical cycles of iron, sulfur, carbon, and oxygen. Transition metal sulfides (e.g., NiS, CuS, ZnS, Cd...

  3. Nitrous Oxide Formation and Destruction by Industrial No Abatement Techniques Including Scr Emissions des protoxides d'azote par des techniques industrielles d'abattement de NO y compris le SCR

    Directory of Open Access Journals (Sweden)

    De Soete G. G.

    2006-11-01

    Full Text Available Systematic investigations on N2O emission from full scale stationary combustion units, equipped with primary or secondary NO control techniques, are scarce or inexistent. Recent results obtained from laboratory scale studies are presented, from which it appears that fuel staging, selective non catalytic NO reduction with ammonia and selective catalytic NO reduction in the presence of ammonia, should be considered as potential sources of nitrous oxide emission enhancement. For the two mentioned gas phase NO abatement techniques (fuel staging and NCSR, this N2O emission enhancement is clearly linked with a decrease of the temperature, a result that might have been expected from the known gas phase reactions of N2O formation and destruction. Production of N2O from NCSR is more important than from fuel staging, and increases with ammonia concentration; this probably is related to the fact that ammonia yields N2O precursors (NH, NH2 readily by its decomposition. Separate injection of pure NO or NH3 suggests that N2O is a product of the interaction of those two reactants, whereas NO also is formed as a primary ammonia decomposition product in the presence of oxygen. A kinetic investigation of N2O formation from SCR has been made. It is shown that catalytic decomposition of neat ammonia yields both NO and N2O, the former as a primary product (from adsorbed ammonia and solid bound oxygen, the latter as a secondary product (from NO and adsorbed ammonia. Both NO and N2O subsequently undergo catalytic decomposition. In the presence of molecular oxygen, another NO formation (from O2 and adsorbed ammonia manifests itself at somewhat higher temperatures, creating the well known optimum temperature window . Comparative tests conducted on a number of metal oxides, tend to show that high efficiency for NO decomposition is often related to high production of N2O within the temperature window . On ne dispose actuellement pas encore de résultats d

  4. Abatement costs of post-Kyoto climate regimes

    International Nuclear Information System (INIS)

    Elzen, Michel den; Lucas, Paul; Vuuren, Detlef van

    2005-01-01

    This article analyses the abatement costs of three post-Kyoto regimes for differentiating commitments compatible with stabilising atmospheric greenhouse gases concentrations at 550 ppmv CO 2 equivalent in 2100. The three regimes explored are: (1) the Multi-Stage approach assumes a gradual increase in the number of Parties involved who are adopting either emission intensity or reductions targets; (2) the Brazilian Proposal approach, i.e. the allocation or reductions based on countries' contribution to temperature increase; (3) Contraction and Convergence, with full participation in convergence of per capita emission allowances. In 2050, the global costs increase up to about 1% of the world GDP, ranging from 0.5% to 1.5%, depending on baseline scenario and marginal abatement costs. Four groups of regions can be identified on the basis of similar costs (expressed as the percentage of GDP). These are: (1) OECD regions with average costs; (2) FSU, the Middle East and Latin America with high costs; (3) South-East Asia and East Asia (incl. China) with low costs; and (4) South Asia (incl. India) and Africa with net gains from emissions trading for most regimes. The Brazilian Proposal approach gives the highest costs for groups 1 and 2. The distribution of costs for the Contraction and Convergence approach highly depends on the convergence year. The Multi-Stage approach and Contraction and Convergence (convergence year 2050) seem to result in relatively the most even distribution of costs amongst all Parties

  5. Estimating the National Carbon Abatement Potential of City Policies: A Data-Driven Approach

    Energy Technology Data Exchange (ETDEWEB)

    O' Shaughnessy, Eric [National Renewable Energy Lab. (NREL), Golden, CO (United States); Heeter, Jenny [National Renewable Energy Lab. (NREL), Golden, CO (United States); Keyser, David [National Renewable Energy Lab. (NREL), Golden, CO (United States); Gagnon, Pieter [National Renewable Energy Lab. (NREL), Golden, CO (United States); Aznar, Alexandra [National Renewable Energy Lab. (NREL), Golden, CO (United States)

    2016-10-01

    Cities are increasingly taking actions such as building code enforcement, urban planning, and public transit expansion to reduce emissions of carbon dioxide in their communities and municipal operations. However, many cities lack the quantitative information needed to estimate policy impacts and prioritize city actions in terms of carbon abatement potential and cost effectiveness. This report fills this research gap by providing methodologies to assess the carbon abatement potential of a variety of city actions. The methodologies are applied to an energy use data set of 23,458 cities compiled for the U.S. Department of Energy City Energy Profile tool. The analysis develops a national estimate of the carbon abatement potential of realizable city actions in six specific policy areas encompassing the most commonly implemented city actions. The results of this analysis suggest that, in aggregate, cities could reduce nationwide carbon emissions by about 210 million metric tons of carbon dioxide (MMT CO2) per year in a 'moderate abatement scenario' by 2035 and 480 MMT CO2/year in a 'high abatement scenario' by 2035 through these common actions typically within a city's control in the six policy areas. The aggregate carbon abatement potential of these specific areas equates to a reduction of 3%-7% relative to 2013 U.S. emissions. At the city level, the results suggest the average city could reduce carbon emissions by 7% (moderate) to 19% (high) relative to current city-level emissions. In the context of U.S. climate commitments under the 21st session of the Conference of the Parties (COP21), the estimated national abatement potential of the city actions analyzed in this report equates to about 15%-35% of the remaining carbon abatement necessary to achieve the U.S. COP21 target. Additional city actions outside the scope of this report, such as community choice aggregation (city-level purchasing of renewable energy), zero energy districts, and multi

  6. Assessing the effects of noise abatement measures on health risks: A case study in Istanbul

    International Nuclear Information System (INIS)

    Ongel, Aybike; Sezgin, Fatih

    2016-01-01

    In recent decades, noise pollution caused by industrialization and increased motorization has become a major concern around the world because of its adverse effects on human well-being. Therefore, transportation agencies have been implementing noise abatement measures in order to reduce road traffic noise. However, limited attention is given to noise in environmental assessment of road transportation systems. This paper presents a framework for a health impact assessment model for road transportation noise emissions. The model allows noise impacts to be addressed with the health effects of air pollutant and greenhouse gas emissions from road transportation. The health damages assessed in the model include annoyance, sleep disturbance, and cardiovascular disease in terms of acute myocardial infarction. The model was applied in a case study in Istanbul in order to evaluate the change in health risks from the implementation of noise abatement strategies. The noise abatement strategies evaluated include altering pavement surfaces in order to absorb noise and introducing speed limits. It was shown that significant improvements in health risks can be achieved using open graded pavement surfaces and introducing speed limits on highways. - Highlights: • Transportation noise has a significant effect on health. • Noise should be included in the environmental assessment of transportation systems. • Traffic noise abatement measures include noise reducing pavements and speed limits. • Noise abatement measures help reduce the health risks of transportation noise. • Speed limit reduction on uncongested roads is an effective way to reduce health risks.

  7. Assessing the effects of noise abatement measures on health risks: A case study in Istanbul

    Energy Technology Data Exchange (ETDEWEB)

    Ongel, Aybike, E-mail: aybike.ongel@eng.bahcesehir.edu.tr [Bahcesehir University, Department of Civil Engineering, Istanbul 34353 (Turkey); Sezgin, Fatih, E-mail: fatih.sezgin@ibb.gov.tr [Istanbul Metropolitan Municipality, Environmental Protection Agency, Istanbul 34169 (Turkey)

    2016-01-15

    In recent decades, noise pollution caused by industrialization and increased motorization has become a major concern around the world because of its adverse effects on human well-being. Therefore, transportation agencies have been implementing noise abatement measures in order to reduce road traffic noise. However, limited attention is given to noise in environmental assessment of road transportation systems. This paper presents a framework for a health impact assessment model for road transportation noise emissions. The model allows noise impacts to be addressed with the health effects of air pollutant and greenhouse gas emissions from road transportation. The health damages assessed in the model include annoyance, sleep disturbance, and cardiovascular disease in terms of acute myocardial infarction. The model was applied in a case study in Istanbul in order to evaluate the change in health risks from the implementation of noise abatement strategies. The noise abatement strategies evaluated include altering pavement surfaces in order to absorb noise and introducing speed limits. It was shown that significant improvements in health risks can be achieved using open graded pavement surfaces and introducing speed limits on highways. - Highlights: • Transportation noise has a significant effect on health. • Noise should be included in the environmental assessment of transportation systems. • Traffic noise abatement measures include noise reducing pavements and speed limits. • Noise abatement measures help reduce the health risks of transportation noise. • Speed limit reduction on uncongested roads is an effective way to reduce health risks.

  8. Working Group 'Air pollution abatement' of the University of Stuttgart -ALS. Annual report 1990

    International Nuclear Information System (INIS)

    1991-01-01

    Despite considerable efforts for air pollution abatement - examples are here desulphurization and nitrogen removal in power and large combustion plants as well as catalytic converters for automobiles there are still many problems to solve. Many small and medium-size companies still have to reduce production-related pollutant emissions, traffic still is a major source of pollutants. Air pollution abatement in the new Federal states and other Eastern European countries is a particularly urgent task and reductions of CO 2 emissions from energy production processes with fossil fuels are not least a great challenge. Apart from industry, legislation and administration especially science is called upon to find solutions to these problems. The university of Stuttgart takes up the challenge. Numerous institutes - 17 of 8 faculties -united in the working group ''air pollution abatement'' of the university of Stuttgart which carries out in interdisciplinary cooperation research work in the area of air pollution abatement. In this annual report activities of individual member states institutes in the area of air pollution abatement (fields of study, current research projects, cooperations and publications in 1991) as well as joint projects are presented. (orig./KW) [de

  9. Niobium(V) saponite clay for the catalytic oxidative abatement of chemical warfare agents.

    Science.gov (United States)

    Carniato, Fabio; Bisio, Chiara; Psaro, Rinaldo; Marchese, Leonardo; Guidotti, Matteo

    2014-09-15

    A Nb(V)-containing saponite clay was designed to selectively transform toxic organosulfur chemical warfare agents (CWAs) under extremely mild conditions into nontoxic products with reduced environmental impact. Thanks to the insertion of Nb(V) sites within the saponite framework, a bifunctional catalyst with strong oxidizing and acid properties was obtained. Remarkable activity and high selectivity were observed for the oxidative abatement of (2-chloroethyl)ethyl sulfide (CEES), a simulant of sulfur mustard, at room temperature with aqueous hydrogen peroxide. This performance was significantly better compared to a conventional commercial decontamination powder. © 2014 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

  10. Control of hydrogen sulfide emission from geothermal power plants. Volume III. Final report: demonstration plant equipment descriptions, test plan, and operating instructions

    Energy Technology Data Exchange (ETDEWEB)

    Brown, F.C.; Harvey, W.W.; Warren, R.B.

    1977-01-01

    The elements of the final, detailed design of the demonstration plant for the copper sulfate process for the removal of hydrogen sulfide from geothermal steam are summarized. Descriptions are given of all items of equipment in sufficient detail that they can serve as purchase specifications. The process and mechanical design criteria which were used to develop the specifications, and the process descriptions and material and energy balance bases to which the design criteria were applied are included. (MHR)

  11. The Copenhagen Accord: abatement costs and carbon prices resulting from the submissions

    International Nuclear Information System (INIS)

    Elzen, Michel G.J. den; Hof, Andries F.; Mendoza Beltran, Angelica; Grassi, Giacomo; Roelfsema, Mark; Ruijven, Bas van; Vliet, Jasper van; Vuuren, Detlef P. van

    2011-01-01

    As part of the Copenhagen Accord, individual countries have submitted greenhouse gas reduction proposals for the year 2020. This paper analyses the implications for emission reductions, the carbon price, and abatement costs of these submissions. The submissions of the Annex I (industrialised) countries are estimated to lead to a total reduction target of 12-18% below 1990 levels. The submissions of the seven major emerging economies are estimated to lead to an 11-14% reduction below baseline emissions, depending on international (financial) support. Global abatement costs in 2020 are estimated at about USD 60-100 billion, assuming that at least two-thirds of Annex I emission reduction targets need to be achieved domestically. The largest share of these costs are incurred by Annex I countries, although the costs as share of GDP are similar for Annex I as a group and the seven emerging economies as a group, even when assuming substantial international transfers from Annex I countries to the emerging economies to finance their abatement costs. If the restriction of achieving two-thirds of the emission reduction target domestically is abandoned, it would more than double the international carbon price and at the same time reduce global abatement costs by almost 25%.

  12. Valuation of marginal CO2 abatement options for electric power plants in Korea

    International Nuclear Information System (INIS)

    Park, Hojeong; Lim, Jaekyu

    2009-01-01

    The electricity generation sector in Korea is under pressure to mitigate greenhouse gases as directed by the Kyoto Protocol. The principal compliance options for power companies under the cap-and-trade include the application of direct CO 2 emission abatement and the procurement of emission allowances. The objective of this paper is to provide an analytical framework for assessing the cost-effectiveness of these options. We attempt to derive the marginal abatement cost for CO 2 using the output distance function and analyze the relative advantages of emission allowance procurement option as compared to direct abatement option. Real-option approach is adopted to incorporate emission allowance price uncertainty. Empirical result shows the marginal abatement cost with an average of Euro 14.04/ton CO 2 for fossil-fueled power plants and confirms the existence of substantial cost heterogeneity among plants which is sufficient to achieve trading gains in allowance market. The comparison of two options enables us to identify the optimal position of the compliance for each plant. Sensitivity analyses are also presented with regard to several key parameters including the initial allowance prices and interest rate. The result of this paper may help Korean power plants to prepare for upcoming regulations targeted toward the reduction of domestic greenhouse gases.

  13. Asia least-cost greenhouse gas abatement strategy identification and assessment of mitigation options for the energy sector

    International Nuclear Information System (INIS)

    Gupta, Sujata; Bhandari, Preety

    1998-01-01

    The focus of the presentation was on greenhouse gas mitigation options for the energy sector for India. Results from the Asia Least-cost Greenhouse gas Abatement Strategies (ALGAS) project were presented. The presentation comprised of a review of the sources of greenhouse gases, the optimisation model, ie the Markal model, used for determining the least-cost options, discussion of the results from the baseline and the abatement scenarios. The second half of the presentation focussed on a multi-criteria assessment of the abatement options using the Analytical Hierarchical Process (AHP) model. The emissions of all greenhouse gases, for India, are estimated to be 986.3 Tg of carbon dioxide equivalent for 1990. The energy sector accounted for 58 percent of the total emissions and over 90 percent of the CO2 emissions. Net emissions form land use change and forestry were zero. (au)

  14. Purification of hydrogen sulfide

    International Nuclear Information System (INIS)

    Tsao, U.

    1978-01-01

    A process is described for purifying a hydrogen sulfide gas stream containing carbon dioxide, comprising (a) passing the gas stream through a bed of solid hydrated lime to form calcium hydrosulfide and calcium carbonate and (b) regenerating hydrogen sulfide from said calcium hydrosulfide by reacting the calcium hydrosulfide with additional carbon dioxide. The process is especially applicable for use in a heavy water recovery process wherein deuterium is concentrated from a feed water containing carbon dioxide by absorption and stripping using hydrogen sulfide as a circulating medium, and the hydrogen sulfide absorbs a small quantity of carbon dioxide along with deuterium in each circulation

  15. Air-water transfer of hydrogen sulfide

    DEFF Research Database (Denmark)

    Yongsiri, C.; Vollertsen, J.; Rasmussen, M. R.

    2004-01-01

    The emissions process of hydrogen sulfide was studied to quantify air–water transfer of hydrogen sulfide in sewer networks. Hydrogen sulfide transfer across the air–water interface was investigated at different turbulence levels (expressed in terms of the Froude number) and pH using batch...... experiments. By means of the overall mass–transfer coefficient (KLa), the transfer coefficient of hydrogen sulfide (KLaH2S), referring to total sulfide, was correlated to that of oxygen (KLaO2) (i.e., the reaeration coefficient). Results demonstrate that both turbulence and pH in the water phase play...... a significant role for KLaH2S. An exponential expression is a suitable representation for the relationship between KLaH2S and the Froude number at all pH values studied (4.5 to 8.0). Because of the dissociation of hydrogen sulfide, KLaH2S increased with decreasing pH at a constant turbulence level. Relative...

  16. Ammonia abatement by slurry acidification

    DEFF Research Database (Denmark)

    Petersen, Søren O.; Hutchings, Nicholas John; Hafner, Sasha D.

    2016-01-01

    sections with 30-32 pigs with or without daily adjustment of slurry pH to below 6. Ammonia losses from reference sections with untreated slurry were between 9.5 and 12.4% of N excreted, and from sections with acidified slurry between 3.1 and 6.2%. Acidification reduced total emissions of NH3 by 66 and 71......% in spring and autumn experiments, and by 44% in the summer experiment. Regression models were used to investigate sources and controls of NH3 emissions. There was a strong relationship between NH3 emissions and ventilation rate during spring and autumn, but less so during summer where ventilation rates were...

  17. Greenhouse gas abatement in Senegal. A case study of least-cost options

    International Nuclear Information System (INIS)

    Amous, S.; Revet, D.; Sokona, Y.

    1994-01-01

    The first stage of the study was to make a preliminary inventory of greenhouse gas (GHG) emissions for the base year 1988. Following this seven no regret technical options for emission reduction were investigated and the costs calculated, allowing the identification of three least-cost options. The three least-cost options must be implemented first because of their negative costs. The economic benefits of both abatement scenarios are characterized by a negative global cost whatever the discount rate is. (author)

  18. GAC as a method for radon abatement

    International Nuclear Information System (INIS)

    Martin, R.D.; Smith, K.A.

    1990-01-01

    Perhaps one of the most mysterious abatement procedures is that of the remediation of waterborne radon contamination in residential structures. Many mitigators have been led to believe that the use of GAC as an abatement technique is in appropriate due to the potential creation of a hazardous waste disposal problem. This paper sheds light on the use of GAC as a true alternative to costly aeration mitigation techniques, and can be used as a resource tool for mitigators who need to understand the limits of activity surrounding GAC, and what, if any, shielding may be needed for the protection of residential occupants

  19. The role of abatement costs in GHG permit allocations : a global reduction scenario with the World-MARKAL model

    International Nuclear Information System (INIS)

    Vaillancourt, K.; Kanudia, A.

    2004-01-01

    The World-MARKAL model was used to examine a permit trading system to stabilize greenhouse gas emissions. The model considered the participation of all countries, including developing countries. Allocation schemes aimed at fair distribution of net abatement costs among world regions were proposed. The net abatement costs for each region are good indicators of where more abatement measures are needed. Equity issues relative to permit allocations and burden sharing were also presented along with the allocation methodology. The gross abatement costs before permit trading were calculated for each region. The main advantages and disadvantages of this approach were listed. It was concluded that permit allocation schemes based on cost distribution make it possible to obtain solutions with equalized net costs per gross domestic product for all regions. 30 refs., 6 tabs., 3 figs

  20. Abatement of malodorants from pesticide factory in dielectric barrier discharges

    International Nuclear Information System (INIS)

    Chen Jie; Yang Jiantao; Pan Hua; Su Qingfa; Liu Yamin; Shi Yao

    2010-01-01

    Traditional odor control methods are limitative technically and economically for the abatement of odor from pesticide factory due to its toxicity and complicated composition. Non-thermal plasma (NTP) methods, typically characterized by high removal efficiency, energy yields and good economy, offer possible alternative solutions. This paper provides laboratory scale experimental data on the removal of simulated odors from pesticide factory with various humidity (0-0.8 vol%) and oxygen contents (0-21%) by a dielectric barrier discharge (DBD) reactor. Peak voltage and initial dimethylamine (DML) concentration are important factors that influence the DML removal efficiency and energy yield. The conversion of DML of 761 mg/m 3 reaches 100% at a peak voltage of 41.25 kV. Under the experiment conditions, the conversion of DML increases with an increase of oxygen contents. And the highest DML conversion was achieved with the gas stream containing 0.3% water. Simultaneously, the concentration of O 3 and OH radical in reactor was measured. Higher conversion, higher energy yield and fewer byproducts were found in mixed odor (DML + dimethyl sulfide (DMS)) treatment than that in single odor treatment. The energy yield is promoted from 2.13 to 5.20 mg/kJ.

  1. Infectious disease risk in asbestos abatement workers.

    Science.gov (United States)

    Lange, John H; Mastrangelo, Giuseppe; Cegolon, Luca

    2012-08-16

    The current literature reports increased infectious disease occurrence in various construction occupations, as an important contributor to morbidity and mortality arising from employment.These observations should be expanded to asbestos abatement workers, as the abatement can create an environment favorable for bacterial, viral and fungal infections. Asbestos abatement work employs activities resulting in cuts, blisters and abrasions to the skin, work in a dirty environment and exposure to dust, mists and fumes.Furthermore, this population exhibits a high smoking rate which increases the risk of chronic obstructive pulmonary disease and respiratory infections.In addition, these workers also commonly employ respirators, which can accumulate dirt and debris magnifying exposure to microbes. Use of respirators and related types of personal protective equipment, especially if shared and in the close environment experienced by workers, may enhance communicability of these agents, including viruses. Abatement workers need to be provided with information on hazards and targeted by appropriate health education to reduce the infection risk. Epidemiological studies to investigate this risk in asbestos removers are recommended.

  2. Hanford Tank Farm Vapors Abatement Technology and Vendor Proposals Assessment

    International Nuclear Information System (INIS)

    Burns, H. H.; Farrar, M. E.; Fink, S. D.

    2016-01-01

    Suspected chemical vapor releases from the Hanford nuclear waste tank system pose concerns for worker exposure. Washington River Protection Solutions (WRPS) contracted the Savannah River National Laboratory (SRNL) to explore abatement technologies and strategies to remediate the vapors emitted through the ventilation system. In response, SRNL conducted an evaluation of technologies to abate, or reduce, vapor emissions to below 10% of the recognized occupational exposure limits (OELs). The evaluation included a review of published literature and a broadly communicated Request for Information to commercial vendors through a Federal Business Opportunities (Fed Biz Opps) web posting. In addition, SRNL conducted a workshop and post-workshop conference calls with interested suppliers (vendors) to assess proposals of relevant technologies. This report reviews applicable technologies and summarizes the approaches proposed by the vendors who participated in the workshop and teleconference interviews. In addition, the report evaluates the estimated performance of the individual technologies for the various classes of chemical compounds present in the Hanford Chemicals of Potential Concern (COPCs) list. Similarly, the report provides a relative evaluation of the vendor proposed approaches against criteria of: technical feasibility (and maturity), design features, operational considerations, secondary waste generation, safety/regulatory, and cost / schedule. These rough order-of-magnitude (ROM) cost estimates are intended to provide a comparison basis between technologies and are not intended to be actual project estimates.

  3. Hanford Tank Farm Vapors Abatement Technology and Vendor Proposals Assessment

    Energy Technology Data Exchange (ETDEWEB)

    Burns, H. H. [Savannah River Site (SRS), Aiken, SC (United States). Savannah River National Lab. (SRNL); Farrar, M. E. [Savannah River Site (SRS), Aiken, SC (United States). Savannah River National Lab. (SRNL); Fink, S. D. [Savannah River Site (SRS), Aiken, SC (United States). Savannah River National Lab. (SRNL)

    2016-09-20

    Suspected chemical vapor releases from the Hanford nuclear waste tank system pose concerns for worker exposure. Washington River Protection Solutions (WRPS) contracted the Savannah River National Laboratory (SRNL) to explore abatement technologies and strategies to remediate the vapors emitted through the ventilation system. In response, SRNL conducted an evaluation of technologies to abate, or reduce, vapor emissions to below 10% of the recognized occupational exposure limits (OELs). The evaluation included a review of published literature and a broadly communicated Request for Information to commercial vendors through a Federal Business Opportunities (Fed Biz Opps) web posting. In addition, SRNL conducted a workshop and post-workshop conference calls with interested suppliers (vendors) to assess proposals of relevant technologies. This report reviews applicable technologies and summarizes the approaches proposed by the vendors who participated in the workshop and teleconference interviews. In addition, the report evaluates the estimated performance of the individual technologies for the various classes of chemical compounds present in the Hanford Chemicals of Potential Concern (COPCs) list. Similarly, the report provides a relative evaluation of the vendor proposed approaches against criteria of: technical feasibility (and maturity), design features, operational considerations, secondary waste generation, safety/regulatory, and cost / schedule. These rough order-of-magnitude (ROM) cost estimates are intended to provide a comparison basis between technologies and are not intended to be actual project estimates.

  4. 76 FR 67650 - Migratory Bird Permits; Abatement Regulations

    Science.gov (United States)

    2011-11-02

    ... and suggestions on migratory bird permit regulations for a permit to use raptors (birds of prey) in abatement activities. Abatement means the use of trained raptors to flush, scare (haze), or take birds or... for a specific permit authorizing the use of raptors in abatement activities (76 FR 39368). The...

  5. How can French agriculture contribute to reducing greenhouse gas emissions? Abatement potential and cost of ten technical measures. Summary of the study report conducted by INRA on behalf of ADEME, MAAF and MEDDE

    International Nuclear Information System (INIS)

    Pellerin, Sylvain; Bamiere, Laure; Savini, Isabelle; Pardon, Lenaic; Chemineau, Philippe; Schmitt, Bertrand; Angers, D.; Beline, F.; Benoit, M.; Butault, J.P.; Chenu, C.; Colnenne-David, C.; De Cara, S.; Delame, N.; Doreau, M.; Dupraz, P.; Faverdin, P.; Garcia-Launay, F.; Hassouna, M.; Henault, C.; Jeuffroy, M.H.; Klumpp, K.; Metay, A.; Moran, D.; Recous, S.; Samson, E.

    2013-07-01

    The agricultural industry produces nearly one-fifth of France's greenhouse gas emissions (GHGs). But it also has a strong potential for carbon sequestration. ADEME and the French Ministries for Agriculture and the Environment asked INRA to carry out a study on French agriculture to develop and analyse various measures on farming practices that could boost carbon sequestration and minimise GHGs. There are four key ways agriculture can be a part of the solution of reducing GHG emissions: Lower emissions of nitrous oxide (N 2 O, a powerful GHG released during fertiliser processing or manure spreading) and methane (CH 4 , a GHG that comes mostly from livestock); Increase carbon sequestration in soil and biomass; Reduce energy use and produce energy from biomass (agro-fuels or biogas, which lower emissions as substitutes for fossil fuels); Produce materials from biomass. The study specified that eligible measures be based on farming practices that farmers have a say in changing, lead to reductions affecting commercial farms at least in part, do not require major changes to the production system and do not reduce yields by more than 10%. For each of the chosen measures, the study analysed the potential emissions reductions and gains versus tradeoffs for farmers if implemented. The ten measures are centered around nitrogen management (nitrogen fertilizer, pulses), practices that help increase carbon sequestration in soil and biomass (fallow land, agro-forestry, intermediate crops and inter-cropping, pasture management), animal feed (rations that minimise nitrogen excretion or methane production) and the production and consumption of energy by farming (methanation, fossil fuel economies). The study highlights a strong potential for the agricultural sector to reduce emissions through these measures. According to the experts' calculations, if all ten were adopted, France could achieve a cumulative annual reduction of 32 million tons of CO 2 equivalent by 2030. However, only

  6. CO2 Abatement In The Iron And Steel Industry

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    2012-01-15

    The iron and steel industry is the largest industrial source of CO2 emissions due to the energy intensity of steel production, its reliance on carbon-based fuels and reductants, and the large volume of steel produced -- over 1414 Mt in 2010. With the growing concern over climate change, steel makers are faced with the challenge of finding ways of lowering CO2 emissions without seriously undermining process efficiency or considerably adding to costs. This report examines ways of abating CO2 emissions from raw materials preparation (coking, sintering and pelletising plants) through to the production of liquid steel in basic oxygen furnaces and electric arc furnaces. Direct reduction and smelting reduction processes are covered, as well as iron making in a blast furnace. A range of technologies and measures exist for lowering CO2 emissions including minimising energy consumption and improving energy efficiency, changing to a fuel and/or reducing agent with a lower CO2 emission factor (such as wood charcoal), and capturing the CO2 and storing it underground. Significant CO2 reductions can be achieved by combining a number of the available technologies. If carbon capture and storage is fitted than steel plants could become near zero emitters of CO2.

  7. Emmission trading in EU law. The EU emission trading directive as a new tool in European air pollution abatement policy; Emissionshandel im Gemeinschaftsrecht. Die EG-Emissionshandelsrichtlinie als neues Instrument europaeischer Klimaschutzpolitik

    Energy Technology Data Exchange (ETDEWEB)

    Kerth, Y.

    2004-07-01

    The publication investigates in how far the EU followed up its voiced political intentions to reduce air pollution by legal actions. The climate protection tools of the EU are investigated both from a historical and a structural view. After this analysis of the status quo, the new EU emission trading system is analyzed in detail because of its innovative character. (orig.)

  8. Evaluation of aluminum sulfate (alum) as a feedlot surface amendment to reduce ammonia, hydrogen sulfide, and greenhouse gas emissions from beef feedlots

    Science.gov (United States)

    Ammonia (NH3) and greenhouse gas (GHG) emissions from concentrated feeding operations are a concern. The poultry industry has successfully used aluminum sulfate (Alum) as a litter amendment to reduce NH3 emissions from poultry barns. Alum has not been eval­uated for similar uses on cattle feedlot su...

  9. Mesostructured metal germanium sulfides

    Energy Technology Data Exchange (ETDEWEB)

    MacLachlan, M.J.; Coombs, N.; Bedard, R.L.; White, S.; Thompson, L.K.; Ozin, G.A.

    1999-12-29

    A new class of mesostructured metal germanium sulfide materials has been prepared and characterized. The synthesis, via supramolecular assembly of well-defined germanium sulfide anionic cluster precursors and transition-metal cations in formamide, represents a new strategy for the formation of this class of solids. A variety of techniques were employed to examine the structure and composition of the materials. Structurally, the material is best described as a periodic mesostructured metal sulfide-based coordination framework akin to periodic hexagonal mesoporous silica, MCM-41. At the molecular scale, the materials strongly resemble microstructured metal germanium sulfides, in which the structure of the [Ge{sub 4}S{sub 10}]{sup 4{minus}} cluster building-blocks are intact and linked via {mu}-S-M-S bonds. Evidence for a metal-metal bond in mesostructured Cu/Ge{sub 4}S{sub 10} is also provided.

  10. The timing of biological carbon sequestration and carbon abatement in the energy sector under optimal strategies against climate risks

    International Nuclear Information System (INIS)

    Gitz, V.; Hourcade, J.Ch.; Ciais, Ph.

    2005-10-01

    This paper addresses the timing of the use of biological carbon sequestration and its capacity to alleviate the carbon constraint on the energy sector. We constructed a stochastic optimal control model balancing the costs of fossil emission abatement, the opportunity costs of lands allocated to afforestation, and the costs of uncertain climate damages. We show that a minor part of the sequestration potential should start immediately as a 'brake', slowing down both the rate of growth of concentrations and the rate of abatement in the energy sector. thus increasing the option value of the emission trajectories. But, most of the potential is put in reserve to be used as a 'safety valve' after the resolution of uncertainty, if a higher and faster decarbonization is required: sequestration cuts off the peaks of costs of fossil abatement and postpones the pivoting of the energy system by up to two decades. (authors)

  11. Selection of Sustainable Technology for VOC Abatement in an Industry: An Integrated AHP-QFD Approach

    Science.gov (United States)

    Gupta, Alok Kumar; Modi, Bharat A.

    2018-04-01

    Volatile organic compounds (VOCs) are universally present in global atmospheric pollutants. These VOCs are responsible for photo chemical reaction in atmosphere leading to serious harmful effects on human health and environment. VOCs are produced from both natural and man-made sources and may have good commercial value if it can be utilized as alternate fuel. As per data from US EPA, 15% of total VOC emissions are generated from surface coating industry but VOC concentration and exhaust air volume varies to a great extent and is dependent on processes used by industry. Various technologies are available for abatement of VOCs. Physical, Chemical and Biological technologies are available to remove VOCs by either recovery or destruction with many advantages and limitations. With growing environmental awareness and considering the resource limitations of medium and small scale industries, requirement of a tool for selecting appropriate techno economically viable solution for removal of VOCs from industrial process exhaust is envisaged. The aim of the present study is to provide management a tool to determine the overall effect of implementation of VOC abatement technology on business performance and VOC emissions. The primary purpose of this work is to outline a methodology to rate various VOC abatement technologies with respect to the constraint of meeting current and foreseeable future regulatory requirements, operational flexibility and Over All Economics Parameters considering conservation of energy. In this paper an integrated approach has been proposed to select most appropriate abatement technology strategically. Analytical hierarchy process and Quality function deployment have been integrated for Techno-commercial evaluation. A case study on selection of VOC abatement technology for a leading aluminium foil surface coating, lamination and printing facility using this methodology is presented in this study.

  12. Solubility Measurements and Modeling of Zinc, Lead and Iron Sulfides at High Temperatures and High Pressures

    DEFF Research Database (Denmark)

    Carolina Figueroa Murcia, Diana; Fosbøl, Philip Loldrup; Thomsen, Kaj

    Solubility measurements of sulfides in aqueous solutions are necessary to understand the behaviour of these scaling minerals in geothermal and oil reservoirs. The low solubility levels of Zinc Sulfide (ZnS), Lead Sulfide (PbS) and Iron Sulfide (FeS) make the solubility measurements a challenging...... oxygen atmosphere to avoid the risk of oxidation of sulfide minerals. The solution is kept in an equilibrium cell at constant temperature and pressure with continuous stirring. The concentration of Zn2+, Pb2+, Fe2+ and S2- are measured using Inductively Coupled Plasma Optical Emission spectrometry (ICP...

  13. Human health risks associated with asbestos abatement.

    Science.gov (United States)

    Chrostowski, P C; Foster, S A; Anderson, E L

    1991-09-01

    Upperbound lifetime excess cancer risks were calculated for activities associated with asbestos abatement using a risk assessment framework developed for EPA's Superfund program. It was found that removals were associated with cancer risks to workers which were often greater than the commonly accepted cancer risk of 1 x 10(-6), although lower than occupational exposure limits associated with risks of 1 x 10(-3). Removals had little effect in reducing risk to school populations. Risks to teachers and students in school buildings containing asbestos were approximately the same as risks associated with exposure to ambient asbestos by the general public and were below the levels typically of concern to regulatory agencies. During abatement, however, there were increased risks to both workers and nearby individuals. Careless, everyday building maintenance generated the greatest risk to workers followed by removals and encapsulation. If asbestos abatement was judged by the risk criteria applied to EPA's Superfund program, the no-action alternative would likely be selected in preference to removal in a majority of cases. These conclusions should only be interpreted within the context of an overall asbestos risk management program, which includes consideration of specific fiber types and sizes, sampling and analytical limitations, physical condition of asbestos-containing material, episodic peak exposures, and the number of people potentially exposed.

  14. Vienna international airport noise abatement

    Directory of Open Access Journals (Sweden)

    Heidelinde Jelinek-Nigitz

    2016-03-01

    sensitization of the population, bring the issue of aircraft noise emission into the increased interest of the stakeholder of an airport. The study compares the extent of the subjective perceived and the actual noise emissions’ change over the last years.

  15. Emissions of ammonia, carbon dioxide, and hydrogen sulfide from swine wastewater during and after acidification treatment: effect of pH, mixing and aeration

    DEFF Research Database (Denmark)

    Dai, Xiao-Rong; Blanes-Vidal, Victoria

    2013-01-01

    setup consisting of nine dynamic flux chambers. Three pH levels (pH = 6.0, pH = 5.8 and pH = 5.5), combined with short-term aeration and venting (with an inert gas) treatments were studied. Acidification reduced average NH(3) emissions from swine slurry stored after acidification treatment compared...... to emissions during storage of non-acidified slurry. The reduction were 50%, 62% and 77% when pH was reduce to 6.0, 5.8 and 5.5, respectively. However, it had no significant effect on average CO(2) and H(2)S emissions during storage of slurry after acidification. Aeration of the slurry for 30 min had no effect...

  16. Renewable energy and CO_2 abatement in Italy

    International Nuclear Information System (INIS)

    Marcantonini, Claudio; Valero, Vanessa

    2017-01-01

    In order to combat global warming, Italy has committed to reduce its CO_2 emissions. To this end, it has significantly encouraged renewable energy development through a variety of support schemes, ranging from green certificates to feed-in and premium tariffs. As a result, the production of electricity from renewable energy sources, in particular from solar and wind energy, has risen considerably over the past years. In this paper we review the Italian support schemes for wind and solar energy and estimate the cost of abating CO_2 emissions by generating electricity from these two sources of energy for the period 2008–2011. The results show that the average costs for wind were around 165 €/tCO_2. For solar, they were much higher, around 1000 €/tCO_2, as solar energy received much higher remunerations than wind energy. These costs were much higher than in Germany. This was due to the differences between the level of incentives and the different power systems. - Highlights: • We estimate the cost of reducing CO_2 emissions by wind and solar energy in Italy in 2008–2011. • The average costs for wind were around 165 €/tCO_2. • The average costs for solar were much higher, around 1000 €/tCO_2. • Those costs were much higher than in Germany. • This was due to the differences in the levels of incentives and to the different power systems.

  17. Integrated assessment of energy efficiency technologies and CO_2 abatement cost curves in China’s road passenger car sector

    International Nuclear Information System (INIS)

    Peng, Bin-Bin; Fan, Ying; Xu, Jin-Hua

    2016-01-01

    Highlights: • Energy efficiency technologies in Chinese passenger cars are classified in detail. • CO_2-reduction potential and abatement cost are analyzed for technology bundles. • Marginal abatement cost curve is established from both micro and macro perspectives. • Spark ignition, diesel and hybrid electric vehicle paths should be firstly promoted. • Technology promotion should start from the area of taxies and high-performance cars. - Abstract: Road transport is one of the main sources of energy consumption and CO_2 emissions. It is essential to conserve energy and reduce emissions by promoting energy efficiency technologies (EETs) in this sector. This study first identifies EETs for the passenger cars and then classifies them into various technology bundles. It then analyzes the CO_2-reduction potentials and emissions abatement costs of 55 type-path, 246 type-path-technology, and 465 type-path-subtechnology bundles from micro-vehicular and macro-industrial perspectives during 2010–2030, based on which marginal abatement cost (MAC) curve for China’s road passenger car sector is established. Results show that the cumulative CO_2-reduction potential of EETs on passenger cars in China during 2010–2030 is about 2698.8 Mt, but only 4% is cost-effective. The EETs with low emissions abatement costs are mainly available in the spark ignition (SI), diesel, and hybrid electric vehicle (HEV) paths on the taxis and high-performance cars, and also in the transmission, vehicle body and SI technologies on the private cars, which could be promoted at present. The technologies with large emissions reduction potential are mainly available in the plug-in hybrid electric vehicle (PHEV) and electric vehicle (EV) paths, which would be the main channels for reducing carbon emissions in the long run.

  18. NOx Abatement Pilot Plant 90-day test results report

    International Nuclear Information System (INIS)

    McCray, J.A.; Boardman, R.D.

    1991-01-01

    High-level radioactive liquid wastes produced during nuclear fuel reprocessing at the Idaho Chemical Processing Plant are calcined in the New Waste Calcining Facility (NWCF) to provide both volume reduction and a more stable waste form. Because a large component of the HLW is nitric acid, high levels of oxides of nitrogen (NO x ) are produced in the process and discharged to the environment via the calciner off-gas. The NO x abatement program is required by the new Fuel Processing Restoration (FPR) project permit to construct to reduce NO x emissions from the NWCF. Extensive research and development has indicated that the selective catalytic reduction (SCR) process is the most promising technology for treating the NWCF off-gas. Pilot plant tests were performed to determine the compatibility of the SCR process with actual NWCF off-gas. Test results indicate that the SCR process is a viable method for abating the NO x from the NWCF off-gas. Reduction efficiencies over 95% can be obtained, with minimal amounts of ammonia slip, provided favorable operating conditions exist. Two reactors operated with series flow will provide optimum reduction capabilities. Typical operation should be performed with a first reactor stage gas space velocity of 20,000 hr -1 and an inlet temperature of 320 degrees C. The first stage exhaust NO x concentration will then dictate the parameter settings for the second stage. Operation should always strive for a peak reactor temperature of 520 degrees C in both reactors, with minimal NH 3 slip from the second reactor. Frequent fluctuations in the NWCF off-gas NO x concentration will require a full-scale reduction facility that is versatile and quick-responding. Sudden changes in NWCF off-gas NO x concentrations will require quick detection and immediate response to avoid reactor bed over-heating and/or excessive ammonia slip

  19. Sulfide oxidation in a biofilter

    DEFF Research Database (Denmark)

    Pedersen, Claus Lunde; Dezhao, Liu; Hansen, Michael Jørgen

    Observed hydrogen sulfide uptake rates in a biofilter treating waste air from a pig farm were too high to be explained within conventional limits of sulfide solubility, diffusion in a biofilm and bacterial metabolism. Clone libraries of 16S and 18S rRNA genes from the biofilter found no sulfide...... higher hydrogen sulfide uptake followed by oxidation catalyzed by iron-containing enzymes such as cytochrome c oxidase in a process uncoupled from energy conservation....

  20. Sulfide oxidation in a biofilter

    DEFF Research Database (Denmark)

    Pedersen, Claus Lunde; Liu, Dezhao; Hansen, Michael Jørgen

    2012-01-01

    Observed hydrogen sulfide uptake rates in a biofilter treating waste air from a pig farm were too high to be explained within conventional limits of sulfide solubility, diffusion in a biofilm and bacterial metabolism. Clone libraries of 16S and 18S rRNA genes from the biofilter found no sulfide...... higher hydrogen sulfide uptake followed by oxidation catalyzed by iron-containing enzymes such as cytochrome c oxidase in a process uncoupled from energy conservation....

  1. Uncertainty quantification of CO2 emission reduction for maritime shipping

    International Nuclear Information System (INIS)

    Yuan, Jun; Ng, Szu Hui; Sou, Weng Sut

    2016-01-01

    The International Maritime Organization (IMO) has recently proposed several operational and technical measures to improve shipping efficiency and reduce the greenhouse gases (GHG) emissions. The abatement potentials estimated for these measures have been further used by many organizations to project future GHG emission reductions and plot Marginal Abatement Cost Curves (MACC). However, the abatement potentials estimated for many of these measures can be highly uncertain as many of these measures are new, with limited sea trial information. Furthermore, the abatements obtained are highly dependent on ocean conditions, trading routes and sailing patterns. When the estimated abatement potentials are used for projections, these ‘input’ uncertainties are often not clearly displayed or accounted for, which can lead to overly optimistic or pessimistic outlooks. In this paper, we propose a methodology to systematically quantify and account for these input uncertainties on the overall abatement potential forecasts. We further propose improvements to MACCs to better reflect the uncertainties in marginal abatement costs and total emissions. This approach provides a fuller and more accurate picture of abatement forecasts and potential reductions achievable, and will be useful to policy makers and decision makers in the shipping industry to better assess the cost effective measures for CO 2 emission reduction. - Highlights: • We propose a systematic method to quantify uncertainty in emission reduction. • Marginal abatement cost curves are improved to better reflect the uncertainties. • Percentage reduction probability is given to determine emission reduction target. • The methodology is applied to a case study on maritime shipping.

  2. CFD modeling of a UV-LED photocatalytic odor abatement process in a continuous reactor

    International Nuclear Information System (INIS)

    Wang, Zimeng; Liu, Jing; Dai, Yuancan; Dong, Weiyang; Zhang, Shicheng; Chen, Jianmin

    2012-01-01

    Highlights: ► A CFD model is developed for a UV-LED based photocatalytic deodorization reactor. ► Radiation field model and Langmuir–Hinshelwood kinetics are integrated in the model. ► The model can predict the pollutant concentration profile and the reactor performance. ► LED distance is predicted to be a critical parameter in photocatalytic reactor design. - Abstract: This paper presents a model study of a UV light-emitting-diode (UV-LED) based photocatalytic odor abatement process. It integrated computational fluid dynamics (CFD) modeling of the gas flow in the reactor with LED-array radiation field calculation and Langmuir–Hinshelwood reaction kinetics. It was applied to simulate the photocatalytic degradation of dimethyl sulfide (DMS) in a UV-LED reactor based on experimentally determined chemical kinetic parameters. A non-linear power law relating reaction rate to irradiation intensity was adopted. The model could predict the steady state DMS concentration profiles by calculating the advection, diffusion and Langmuir–Hinshelwood reaction kinetics. By affecting the radiation intensity and uniformity, the position of the LED array relative to the catalyst appeared to be a critical parameter determining DMS removal efficiency. Too small distances might yield low quantum efficiency and consequently poor abatement performance. This study provided an example of LED-based photocatalytic process modeling and gave insights into the optimization of light source design for photocatalytic applications.

  3. Directed technical change and the adoption of CO2 abatement technology. The case of CO2 capture and storage

    International Nuclear Information System (INIS)

    Otto, Vincent M.; Reilly, John

    2008-01-01

    This paper studies the cost-effectiveness of combining traditional environmental policy, such as CO 2 -trading schemes, and technology policy that has aims of reducing the cost and speeding the adoption of CO 2 abatement technology. For this purpose, we develop a dynamic general equilibrium model that captures empirical links between CO 2 emissions associated with energy use, directed technical change and the economy. We specify CO 2 capture and storage (CCS) as a discrete CO 2 abatement technology. We find that combining CO 2 -trading schemes with an adoption subsidy is the most effective instrument to induce adoption of the CCS technology. Such a subsidy directly improves the competitiveness of the CCS technology by compensating for its markup over the cost of conventional electricity. Yet, introducing R and D subsidies throughout the entire economy leads to faster adoption of the CCS technology as well and in addition can be cost-effective in achieving the abatement target. (author)

  4. Titanocene sulfide chemistry

    Czech Academy of Sciences Publication Activity Database

    Horáček, Michal

    2016-01-01

    Roč. 314, MAY 2016 (2016), s. 83-102 ISSN 0010-8545 R&D Projects: GA ČR(CZ) GAP207/12/2368 Institutional support: RVO:61388955 Keywords : titanocene sulfide chemistry * photolysis * titanocene hydrosulfides Ti-(SH)n Subject RIV: CF - Physical ; Theoretical Chemistry Impact factor: 13.324, year: 2016

  5. Electron transfer to sulfides:

    International Nuclear Information System (INIS)

    Meneses, Ana Belen; Antonello, Sabrina; Arevalo, Maria Carmen; Maran, Flavio

    2005-01-01

    The problem of characterizing the steps associated with the dissociative reduction of sulfides has been addressed. The electrochemical reduction of diphenylmethyl para-methoxyphenyl sulfide in N,N-dimethylformamide, on both glassy carbon and mercury electrodes, was chosen as a test system. The electrode process involves the slow heterogeneous outer-sphere electron transfer to the sulfide, the fast cleavage of the C-S bond, the reduction of the ensuing carbon radical, and the self-protonation triggered by the generation of the strong base Ph 2 CH - . The latter reaction is rather slow, in agreement with the large intrinsic barriers characterizing proton transfers between CH-acids and carbon bases. The dissociative reduction was studied in the presence of an exogenous acid. The results, obtained by convolution analysis, point to a stepwise DET mechanism in which the ET step is accompanied by rather large reorganization energy. Similar results were obtained on both electrode materials. Analysis of the heterogeneous electron transfer and associated C-S bond cleavage indicate that the reduction of this and other sulfides lies between the stepwise dissociative electron transfers leading to the formation of stiff π* radical anions and those going through the intermediacy of loose σ* radical anions

  6. Acid dispersion abatement: the use of flue gas desulphurisation in the UK

    Energy Technology Data Exchange (ETDEWEB)

    Longhurst, J.W.S.; Health, B.A.; Gibber, D.C. [Manchester Metropolitan University, Manchester (United Kingdom). Atmospheric Research and Information Centre, Dept. of Environmental and Geographical Sciences

    1995-12-31

    This paper reviews and evaluates the development of the UK flue gas desulphurisation (FGD) programme. This programme on establishment in 1986 represented a planned and coherent approach to acid deposition abatement which would progressively reduce emissions whilst maintaining the UK`s coal fired power generation capacity. It was anticipated that at least 12000 MW of electricity generating plant would be retrofitted with FGD. The programme has effectively been abandoned in favour of market based approach to emission control which sets the targets to be achieved but not the means. As a consequence the retrofitted capacity in 1995 is just 6000 MW. 17 refs., 1 tab.

  7. Efficiency, equity or disagreement? The economics of international carbon abatement negotiations

    International Nuclear Information System (INIS)

    Mabey, N.; Smith, C.

    1995-01-01

    The current international effort to reduce greenhouse gas emissions, as embodied in the Framework Convention on Climate Change, is often criticized as inefficient by economists because it uses uniform targets instead of more theoretically efficient instruments such as international taxes. However, the effectiveness of any international treaty in producing environmental benefits is not wholly dependent on its economic efficiency but also on its political stability and the ability to accurately monitor and enforce its conditions. Stability depends on the magnitude and distribution of costs and benefits between countries which have heterogeneous economies, environmental damages, trading partners and abatement costs. The distribution of costs between countries will also depend on the type of policy instrument used to coordinate international abatement efforts. This paper analyses trade-offs that must be made when negotiating international agreements in order to balance the need for administrative convenience and economic efficiency with the realization that any agreement is better than no agreement

  8. Pollution abatement and nature protection, fraud and trickery

    International Nuclear Information System (INIS)

    Roeder, W.

    1993-01-01

    The present general interpretation of pollution abatement as a necessary vehicle for the preservation and protection of the earth we live on is called in question by arguments which maintain that pollution abatement is an instrument used by the rich countries, especially by the U.S.A., to reduce the developing countries' population. (HP) [de

  9. 76 FR 39368 - Migratory Bird Permits; Abatement Regulations

    Science.gov (United States)

    2011-07-06

    ... promulgating migratory bird permit regulations for a permit to use raptors (birds of prey) in abatement activities. Abatement means the use of trained raptors to flush, scare (haze), or take birds or other...). Background In response to public interest in the use of trained raptors to haze (scare) depredating and other...

  10. Ex-ante evaluation of EU ETS during 2013–2030: EU-internal abatement

    International Nuclear Information System (INIS)

    Hu, Jing; Crijns-Graus, Wina; Lam, Long; Gilbert, Alyssa

    2015-01-01

    This study investigates CO 2 emission reduction within the EU resulting from the Emissions Trading Scheme (ETS) up to 2030. This is performed by constructing a baseline scenario without the ETS and assessing the impacts of the ETS, as currently designed. The results indicate that the ETS will start to impact emissions primarily after 2025 due to the prevalence of a sizable allowance surplus. The impact of approved (i.e. back-loading and 2.2% linear reduction factor (LRF)) and proposed (i.e. market stability reserve (MSR)) policy interventions and the inclusion of aviation, could accelerate the exhaustion of surplus and increase emission reductions during the investigated period. However, these measures would be insufficient to restore the scarcity of allowances and the corresponding carbon price before the start of ETS Phase IV, and the effectiveness of EU-internal abatement cannot be guaranteed until 2023. The effectiveness could be further reduced in the case of the economic shocks or the exclusion of international aviation. To restore the scarcity of allowances, other reform options are necessary. This paper extends the reasoning for the early removal of the back-loaded 900 Mtonne allowances by 2020 and broadening the scope of ETS to other sectors with potential high demand for allowances. - Highlights: • Quantification of CO 2 emission abatement in the EU resulting from the ETS up to 2030. • The impact of policy interventions and the inclusion of aviation is quantified. • The effectiveness of EU ETS in EU-internal abatement is limited until 2023

  11. Application of Primary Abatement Technology for Reduction of N2O Emmision in Petrokemija Nitric Acid Production

    Directory of Open Access Journals (Sweden)

    Ćosić, L.

    2013-01-01

    Full Text Available Industrial nitric acid production by oxidation of gaseous ammonia with Ostwald procedure produces an unwanted by-product – colorless nitrous oxide, N2O. As emission of N2O represents a very serious problem due of its huge contribution to global warming, certain measures focused on its maximum reduction should be undertaken. Minimization of N2O emission in nitric acid production can be achieved in different parts of the process flow, depending on the applied available technologies. For the abatement of N2O emissions in Petrokemija's nitric acid production processes from the list of the best available technologies chosen were primary and secondary abatement technologies. The mentioned ensures reduction of N2O by use of improved selective heterogeneous catalysts in the step of gaseous ammonia oxidation. Precious metals in the shape of gauzes are used as selective heterogeneous catalyst in primary technology, while in the case of secondary technology the Fe2 O3 catalyst on Al2O3 support in the shape of spherical pellets is chosen. Shown is the application of primary technology for the abatement of N2O in both nitric acid production facilities and their comparison with classical heterogeneous catalyst and preparation for the installation of secondary selective catalyst. N2O emissions with the application of primary technology in both production facilities were reduced from 12 kg of N2O to 7 kg of N2O per ton of pure HNO3. With the primary reduction in N2O emissions the foundation was established for further reduction with the secondary technology to the final value of 0.7 kg of N2O per ton of pure HNO3, which represents mass concentration in the tail gas below 200 mg m-3 (at n. c.. With the applied technologies for the abatement of N2O emissions in Petrokemija's nitric acid production the future prescribed emission limit value will be satisfied.

  12. The economics of soil C sequestration and agricultural emissions abatement

    Science.gov (United States)

    Alexander, P.; Paustian, K.; Smith, P.; Moran, D.

    2015-04-01

    Carbon is a critical component of soil vitality and is crucial to our ability to produce food. Carbon sequestered in soils also provides a further regulating ecosystem service, valued as the avoided damage from global climate change. We consider the demand and supply attributes that underpin and constrain the emergence of a market value for this vital global ecosystem service: markets being what economists regard as the most efficient institutions for allocating scarce resources to the supply and consumption of valuable goods. This paper considers how a potentially large global supply of soil carbon sequestration is reduced by economic and behavioural constraints that impinge on the emergence of markets, and alternative public policies that can efficiently transact demand for the service from private and public sector agents. In essence, this is a case of significant market failure. In the design of alternative policy options, we consider whether soil carbon mitigation is actually cost-effective relative to other measures in agriculture and elsewhere in the economy, and the nature of behavioural incentives that hinder policy options. We suggest that reducing the cost and uncertainties of mitigation through soil-based measures is crucial for improving uptake. Monitoring and auditing processes will also be required to eventually facilitate wide-scale adoption of these measures.

  13. Cogeneration plant noise: Environmental impacts and abatement

    International Nuclear Information System (INIS)

    De Renzio, M.; Ciocca, B.

    1991-01-01

    In Italy, ever increasing attention to environmental problems has led to legislation requiring cogeneration plant owners to perform environmental impact assessments in order to determine plant conformity with pollution laws. This paper, based on an in-depth analysis of physics fundamentals relevant to the nature and effects of noise, examines the principal sources of noise in industrial cogeneration plants and the intensity and range of the effects of this noise on the local environment. A review is then made of the different methods of noise pollution abatement (e.g., heat and corrosion resistant silencers for gas turbines, varying types and thicknesses of acoustic insulation placed in specific locations) that can be effectively applied to cogeneration plant equipment and housing

  14. Application of cheaper materials in pollution abatement

    International Nuclear Information System (INIS)

    Hasany, S.M.

    1997-01-01

    Industrial effluents and waste water bearing toxic metal ions and hazardous organic substances including phenols and dyes need to be treated to remove such harmful materials before their safe disposal into biosphere. For this purpose a number of cheaper and waste materials like onion skin, bagasse pith, maize ob, groundnut husk, saw dust, wood, fugal and biomass, biogas waste slurry, lignite, wool fiber, fly ash, blast furnace sludge peat and charcoal, natural clays, sands and minerals, bone and glass have been used. some of these materials can also be employed to decontaminate fresh water containing these harmful substances present in very low concentrations. These cheaper materials have been reviewed and examples have been cited mostly from the recent literature. the optimal conditions for the removal of hazardous substances including metal ions form solutions utilizing these waste materials have also been given. These low cost materials have been proven to be very effective in the spheres of pollution abatement and environmental studies. (author)

  15. Achieving CO2 reductions in Colombia: Effects of carbon taxes and abatement targets

    International Nuclear Information System (INIS)

    Calderón, Silvia; Alvarez, Andrés Camilo; Loboguerrero, Ana María; Arango, Santiago; Calvin, Katherine; Kober, Tom; Daenzer, Kathryn; Fisher-Vanden, Karen

    2016-01-01

    In this paper we investigate CO 2 emission scenarios for Colombia and the effects of implementing carbon taxes and abatement targets on the energy system. By comparing baseline and policy scenario results from two integrated assessment partial equilibrium models TIAM-ECN and GCAM and two general equilibrium models Phoenix and MEG4C, we provide an indication of future developments and dynamics in the Colombian energy system. Currently, the carbon intensity of the energy system in Colombia is low compared to other countries in Latin America. However, this trend may change given the projected rapid growth of the economy and the potential increase in the use of carbon-based technologies. Climate policy in Colombia is under development and has yet to consider economic instruments such as taxes and abatement targets. This paper shows how taxes or abatement targets can achieve significant CO 2 reductions in Colombia. Though abatement may be achieved through different pathways, taxes and targets promote the entry of cleaner energy sources into the market and reduce final energy demand through energy efficiency improvements and other demand-side responses. The electric power sector plays an important role in achieving CO 2 emission reductions in Colombia, through the increase of hydropower, the introduction of wind technologies, and the deployment of biomass, coal and natural gas with CO 2 capture and storage (CCS). Uncertainty over the prevailing mitigation pathway reinforces the importance of climate policy to guide sectors toward low-carbon technologies. This paper also assesses the economy-wide implications of mitigation policies such as potential losses in GDP and consumption. An assessment of the legal, institutional, social and environmental barriers to economy-wide mitigation policies is critical yet beyond the scope of this paper. - Highlights: • Four energy and economy-wide models under carbon mitigation scenarios are compared. • Baseline results show that CO

  16. Essays on the economics of energy markets. Security of supply and greenhouse gas abatement

    International Nuclear Information System (INIS)

    Dieckhoener, Caroline

    2013-01-01

    determined by investment decisions and significantly affect the level of greenhouse gas emissions. Major investment decisions of households concern investments in heating systems and in dwelling insulation. The investment decision of heterogenous households is not strictly driven by monetary objectives but also by non-monetary preferences. Hence, understanding household behavior is crucial for the development of targeted policies in greenhouse gas abatement. In the third paper of the thesis, micro-economic greenhouse gas abatement curves are derived theoretically and numerically by applying the dynamic microsimulation model (DIscrHEat) for the residential heating market, which integrates a discrete choice estimation of household behavior by using data on actual heating choices. The last paper is a panel data analysis of the effectiveness of subsidies on residential investments in energy efficiency and on energy consumption applying a differences-in-differences-in-differences approach.

  17. Essays on the economics of energy markets. Security of supply and greenhouse gas abatement

    Energy Technology Data Exchange (ETDEWEB)

    Dieckhoener, Caroline

    2013-02-01

    determined by investment decisions and significantly affect the level of greenhouse gas emissions. Major investment decisions of households concern investments in heating systems and in dwelling insulation. The investment decision of heterogenous households is not strictly driven by monetary objectives but also by non-monetary preferences. Hence, understanding household behavior is crucial for the development of targeted policies in greenhouse gas abatement. In the third paper of the thesis, micro-economic greenhouse gas abatement curves are derived theoretically and numerically by applying the dynamic microsimulation model (DIscrHEat) for the residential heating market, which integrates a discrete choice estimation of household behavior by using data on actual heating choices. The last paper is a panel data analysis of the effectiveness of subsidies on residential investments in energy efficiency and on energy consumption applying a differences-in-differences-in-differences approach.

  18. FUEL/CARBON PRICE VS. ABATEMENT TECHNOLOGY IN FREIGHT TRANSPORT

    Directory of Open Access Journals (Sweden)

    Eugen Ferdinand Spangenberg

    2017-12-01

    Full Text Available The current situation is the exponential increase in greenhouse gases (GHG, which is mainly caused by industrial and transport activities. The recent Paris agreement in 2015 (Framework Convention on Climate Change COP21, UNFCCC made it clear to everyone that CO2 emissions are to be limited in all areas of life. Alternative fuels with a lower environmental impact than carbon (CO2 emissions are hard to find if the overall footprint is to be taken into account. Nevertheless, there are some fuels that have less impact on climate change. One the other hand, the production of biofuels is a controversial matter, although it is a viable alternative to emissions reduction. CNG or LNG-powered vehicles are also better in terms of environmental pollution, but are hardly better with regard to CO2 impact when a Life Cycle Assessment (LCA is carried out. LNG (liquid natural gas, for example, is the future fuel in the maritime sector because of the stricter environmental regulations (SOx,NOx in the shipping industry. The battery-powered vehicle is another example of an environmentally friendly solution. The afore-mentioned measures can be considered as “abatement“ necessary in order to limit CO2 impact. The study shows that there are significant differences in the environmental impact between transport systems and the corresponding drive-system or associated energy base. The polluter should pay, which is a common basic principle in economic research. The Emission Trading Scheme (ETS has been introduced in order to ensure a reduction in CO2 output – emissions come with a price tag. An overall view is necessary, both en-vironmental and economic impact must be reconciled (cf. Spangenberg - TQI. The future viability of the transport system as we know it may change significantly over time if new environmental requirements or e.g. CO2 taxes or ETS are introduced in the freight sector. The abatement of CO2 should be effected primarily through technological

  19. Environmental innovation and the cost of pollution abatement revisited

    Energy Technology Data Exchange (ETDEWEB)

    Brechet, Thierry [Center for Operations Research and Econometrics, Chair Lhoist Berghmans in Environmental Economics and Management, Louvain School of Management, Universite catholique de Louvain, Voie du Roman Pays 34, B-1348 Louvain-la-Neuve (Belgium); Jouvet, Pierre-Andre [EconomiX, Universite de Nanterre (France); Center for Operations Research and Econometrics, Universite catholique de Louvain (Belgium)

    2008-04-01

    It is widely assumed in the literature that environmental innovation reduces the marginal cost of pollution abatement. In this paper we show that this is not necessarily the case and we provide some unexpected outcomes. (author)

  20. Inferring Carbon Abatement Costs in Electricity Markets: A Revealed Preference Approach using the Shale Revolution

    OpenAIRE

    Joseph A. Cullen; Erin T. Mansur

    2014-01-01

    This paper examines how much carbon emissions from the electricity industry would decrease in response to a carbon price. We show how both carbon prices and cheap natural gas reduce, in a nearly identical manner, the historic cost advantage of coal-fired power plants. The shale revolution has resulted in unprecedented variation in natural gas prices that we use to estimate the short-run price elasticity of abatement. Our estimates imply that a price of $10 ($60) per ton of carbon dioxide woul...

  1. Sulfamethoxazole abatement by photo-Fenton

    International Nuclear Information System (INIS)

    Gonzalez, Oscar; Sans, Carme; Esplugas, Santiago

    2007-01-01

    The objective of this work was to study the abatement of 200 mg L -1 sulfamethoxazole (SMX) solution by means of photo-Fenton process. Biodegradability of the treated solutions was followed by the ratio biochemical oxygen demand at five days/chemical oxygen demand (BOD 5 /COD) and toxicity by Microtox[reg] and inhibition tests. Experiments with different initial concentration of H 2 O 2 were carried out. The initial amount of Fe 2+ and pH of the solution were set at 10 mg L -1 and 2.8 respectively. The temperature of the reactor was kept constant in all the experiments (25 ± 0.8 deg. C). Photo-Fenton process is thought to be a successful treatment step to improve the biodegradability of wastewater containing SMX. The complete antibiotic removal was achieved for a H 2 O 2 dose over 300 mg L -1 . Biodegradability (BOD 5 /COD) rose from zero (SMX solution) to values higher than 0.3 (treated solutions). Toxicity and inhibition tests pointed out in the same direction: oxidized intermediates for initial H 2 O 2 dose over 300 mg L -1 showed no toxicity effects on pure bacteria and no inhibition on activated sludge activity

  2. Macro economic linkages and impacts. Technical and fiscal options in GHG abatement

    International Nuclear Information System (INIS)

    Backus, G.; Barker, T.

    1995-01-01

    This paper discusses some of the main macro economic linkages and feedbacks associated with policies for GHG abatement. The linkages in a global model are described when OECD carbon taxes or alternatively OECD/OPEC joint action raises world oil prices with a smaller OECD carbon tax. The results give a world perspective on the GHG abatement problem. The paper continues with a discussion of the linkages and feedbacks associated with three options: demand-side management (DSM), mainly to improve end-use energy efficiency, reductions in subsidies of fossil fuel production and use, and investment in renewable energy supplies, specifically in energy forestry and associated infrastructure. It concludes that DSM and investment in renewables are unlikely on their own to bring about reduction in GHG emissions, and that new supplies may even lead to increased emissions by driving down the price of energy. However, reductions in emissions may be compatible with increased efficiency and development, as well as with improvements in the quality of the local environment and in rural living, with the new supplies replacing fossil fuel supplies, provided that real fossil fuel prices are increased via removal of subsidies and if required carbon taxes. (au) 15 refs

  3. Fighting against VOC emissions; Lutter contre les emissions de COV

    Energy Technology Data Exchange (ETDEWEB)

    Fanlo, J.L. [Ecole des Mines d' Ales, 30 (France); Puech, G. [APAVE, 75 - Paris (France); Patoux, R. [Rhodia Rhoditech (France)] [and others

    2001-12-01

    This document brings together 15 testimonies of experts about the processes used in the industry for the abatement of volatile organic compound (VOC) emissions. The different points approached concern: the first industrial experiments of fight against VOC emissions, how to audit the facilities, how to make a diagnosis, to hierarchized and to measure continuously VOC emissions, how to anticipate the explosion risks linked with VOC treatment processes, the techniques of VOC abatement at the source implemented by industrialists, the implementation of an emission mastery scheme by Crow Cork and Seal company, the implementation of a solvent management plan by Turbomeca company and of a paints strategy by Renault car-making company, the combination of VOC abatement techniques implemented by industrialists, the classification of destruction and recovery processes: the experience feedback of Sanofi Synthelabo and of Air Liquide companies, the combination of upstream and downstream techniques implemented by Pechiney Rhenalu, Ashland Polyester and Quebecor companies. (J.S.)

  4. Economic aspects of air pollution abatement. Air pollution abatement recommended for economic reasons; Oekonomische Aspekte des Klimaschutzes. Gerade aus oekonomischer Sicht ist Klimaschutz sinnvoll

    Energy Technology Data Exchange (ETDEWEB)

    Jasper, J.; Serger, H. [Hannover Univ. (Germany). Lehrstuhl fuer Mikrooekonomik

    2005-07-01

    Climate change is not only dangerous but also expensive. On the other hand, air pollution abatement measures are costly as well. Scientists of the Microeconomics Department investigated how air pollution abatement and cost efficiency can best be combined. (orig.)

  5. Sulfide Mineral Surfaces

    International Nuclear Information System (INIS)

    Rosso, Kevin M.; Vaughan, David J.

    2006-01-01

    The past twenty years or so have seen dramatic development of the experimental and theoretical tools available to study the surfaces of solids at the molecular (?atomic resolution?) scale. On the experimental side, two areas of development well illustrate these advances. The first concerns the high intensity photon sources associated with synchrotron radiation; these have both greatly improved the surface sensitivity and spatial resolution of already established surface spectroscopic and diffraction methods, and enabled the development of new methods for studying surfaces. The second centers on the scanning probe microscopy (SPM) techniques initially developed in the 1980's with the first scanning tunneling microscope (STM) and atomic force microscope (AFM) experiments. The direct 'observation' of individual atoms at surfaces made possible with these methods has truly revolutionized surface science. On the theoretical side, the availability of high performance computers coupled with advances in computational modeling has provided powerful new tools to complement the advances in experiment. Particularly important have been the quantum mechanics based computational approaches such as density functional theory (DFT), which can now be easily used to calculate the equilibrium crystal structures of solids and surfaces from first principles, and to provide insights into their electronic structure. In this chapter, we review current knowledge of sulfide mineral surfaces, beginning with an overview of the principles relevant to the study of the surfaces of all crystalline solids. This includes the thermodynamics of surfaces, the atomic structure of surfaces (surface crystallography and structural stability, adjustments of atoms at the surface through relaxation or reconstruction, surface defects) and the electronic structure of surfaces. We then discuss examples where specific crystal surfaces have been studied, with the main sulfide minerals organized by structure type

  6. Sulfide Mineral Surfaces

    Energy Technology Data Exchange (ETDEWEB)

    Rosso, Kevin M.; Vaughan, David J.

    2006-08-01

    The past twenty years or so have seen dramatic development of the experimental and theoretical tools available to study the surfaces of solids at the molecular (?atomic resolution?) scale. On the experimental side, two areas of development well illustrate these advances. The first concerns the high intensity photon sources associated with synchrotron radiation; these have both greatly improved the surface sensitivity and spatial resolution of already established surface spectroscopic and diffraction methods, and enabled the development of new methods for studying surfaces. The second centers on the scanning probe microscopy (SPM) techniques initially developed in the 1980's with the first scanning tunneling microscope (STM) and atomic force microscope (AFM) experiments. The direct 'observation' of individual atoms at surfaces made possible with these methods has truly revolutionized surface science. On the theoretical side, the availability of high performance computers coupled with advances in computational modeling has provided powerful new tools to complement the advances in experiment. Particularly important have been the quantum mechanics based computational approaches such as density functional theory (DFT), which can now be easily used to calculate the equilibrium crystal structures of solids and surfaces from first principles, and to provide insights into their electronic structure. In this chapter, we review current knowledge of sulfide mineral surfaces, beginning with an overview of the principles relevant to the study of the surfaces of all crystalline solids. This includes the thermodynamics of surfaces, the atomic structure of surfaces (surface crystallography and structural stability, adjustments of atoms at the surface through relaxation or reconstruction, surface defects) and the electronic structure of surfaces. We then discuss examples where specific crystal surfaces have been studied, with the main sulfide minerals organized by

  7. Strategic partitioning of emissions allowances in the EU ETS

    Energy Technology Data Exchange (ETDEWEB)

    Boehringer, Christoph (Carl von Ossietzky Univ. Oldenburg (Germany)); Rosendahl, Knut Einar (Research Dept., Statistics Norway, Oslo (Norway))

    2008-07-01

    The EU ETS opens up for strategic partitioning of emissions allowances by the Member States. In this paper we examine the potential effects of such strategic behavior on quota prices and abatement costs. We show that although marginal abatement costs in the sectors outside the EU ETS become quite differentiated, the effects on the quota price and total abatement costs are small. More abatement, however, takes place in the old Member States that are importers of allowances, compared to the cost-effective outcome. Single countries can nevertheless significantly affect the outcome of the EU ETS by exploiting their market power

  8. R and D levers for an abatement of industrial CO{sub 2} emissions by 2030 in the building industry sector; Leviers R and D pour une reduction des emissions industrielles de CO{sub 2} a l'echeance de 2030 dans le secteur du batiment

    Energy Technology Data Exchange (ETDEWEB)

    Capmas, A.

    2006-03-15

    This document presents in a series of transparencies: the regulatory framework of CO{sub 2} emissions (Kyoto protocol, CO{sub 2} trading market), the CO{sub 2} emissions in the cement industry and the actions implemented to limit them (energy conservation, fuel substitution, recycling of by-products from other industries), the life cycle analysis in the building industry (construction stage and entire life of the building), the energy saving potentialities in existing buildings (double-glazing, mineral wools, space heating system, thermal inertia, insulation etc..), the use of the thermal inertia of concrete and cement to save energy, and some examples of implementation in municipal buildings. (J.S.)

  9. Bayesian Learning and the Regulation of Greenhouse Gas Emissions

    OpenAIRE

    Karp, Larry; Zhang, Jiangfeng

    2001-01-01

    We study the importance of anticipated learning - about both environmental damages and abatement costs - in determining the level and the method of controlling greenhouse gas emissions. We also compare active learning, passive learning, and parameter uncertainty without learning. Current beliefs about damages and abatement costs have an important effect on the optimal level of emissions, However, the optimal level of emissions is not sensitive either to the possibility of learning about damag...

  10. A Methodology for Constructing Marginal Abatement Cost Curves for Climate Action in Cities

    Directory of Open Access Journals (Sweden)

    Nadine Ibrahim

    2016-03-01

    Full Text Available As drivers of climate action, cities are taking measures to reduce greenhouse gas (GHG emissions, which if left unabated pose a challenge to meeting long-term climate targets. The economics of climate action needs to be at the forefront of climate dialogue to prioritize investments among competing mitigation measures. A marginal abatement cost (MAC curve is an effective visualization of climate action that initiates a technical and economic discussion of the cost-effectiveness and abatement potential of such actions among local leaders, policy makers, and climate experts. More commonly demonstrated for countries, MAC curves need to be developed for cities because of their heterogeneity, which vary in their urban activities, energy supply, infrastructure stock, and commuting patterns. The methodology for constructing bottom-up MAC curves for cities is presented for technologies that offer fuel switching and/or energy efficiencies, while considering technology lifetimes, city-specific electricity and fuel prices, and emission intensities. Resulting MAC curves are unique to every city, and chart the pathway towards low-carbon growth by prioritizing measures based on cost-effectiveness. A case study of Toronto’s climate targets demonstrates the prioritization of select technologies. Leveraging MAC curves to support climate programs enables cities to strategically invest in financing climate action and designing incentives.

  11. Energy consumption and energy-saving potential analysis of pollutant abatement systems in a 1000MW coal-fired power plant.

    Science.gov (United States)

    Yang, Hang; Zhang, Yongxin; Zheng, Chenghang; Wu, Xuecheng; Chen, Linghong; Gao, Xiang; Fu, Joshua S

    2018-05-10

    The pollutant abatement systems are widely applied in the coal-fired power sector and the energy consumption was considered an important part of the auxiliary power. An energy consumption analysis and assessment model of pollutant abatement systems in a power unit was developed based on the dynamic parameters and technology. The energy consumption of pollutant abatement systems in a 1000 MW coal-fired power unit which meet the ultra-low emission limits and the factors of operating parameters including unit load and inlet concentration of pollutants on the operating power were analyzed. The results show that the total power consumption of the pollutant abatement systems accounted for 1.27% of the gross power generation during the monitoring period. The WFGD system consumed 67% of the rate while the SCR and ESP systems consumed 8.9% and 24.1%. The power consumption rate of pollutant abatement systems decreased with the increase of unit load and increased with the increase of the inlet concentration of pollutants. The operation adjustment was also an effective method to increase the energy efficiency. For example, the operation adjustment of slurry circulation pumps could promote the energy-saving operation of WFGD system. Implication Statement The application of pollutant abatement technologies increases the internal energy consumption of the power plant, which will lead to an increase of power generation costs. The real-time energy consumption of the different pollutant abatement systems in a typical power unit is analyzed based on the dynamic operating data. Further, the influence of different operating parameters on the operating power of the system and the possible energy-saving potential are analyzed.

  12. Mechanochemical reduction of copper sulfide

    DEFF Research Database (Denmark)

    Balaz, P.; Takacs, L.; Jiang, Jianzhong

    2002-01-01

    The mechanochemical reduction of copper sulfide with iron was induced in a Fritsch P-6 planetary mill, using WC vial filled with argon and WC balls. Samples milled for specific intervals were analyzed by XRD and Mossbauer spectroscopy. Most of the reaction takes place during the first 10 min...... of milling and only FeS and Cu are found after 60 min. The main chemical process is accompanied by phase transformations of the sulfide phases as a result of milling. Djurleite partially transformed to chalcocite and a tetragonal copper sulfide phase before reduction. The cubic modification of FeS was formed...... first, transforming to hexagonal during the later stages of the process. The formation of off-stoichiometric phases and the release of some elemental sulfur by copper sulfide are also probable....

  13. LIGNOCELLULOSE NANOCOMPOSITE CONTAINING COPPER SULFIDE

    OpenAIRE

    Sanchi Nenkova; Peter Velev; Mirela Dragnevska; Diyana Nikolova; Kiril Dimitrov

    2011-01-01

    Copper sulfide-containing lignocellulose nanocomposites with improved electroconductivity were obtained. Two methods for preparing the copper sulfide lignocellulose nanocomposites were developed. An optimization of the parameters for obtaining of the nanocomposites with respect to obtaining improved electroconductivity, economy, and lower quantities and concentration of copper and sulfur ions in waste waters was conducted. The mechanisms and schemes of delaying and subsequent connection of co...

  14. How to encourage road noise abatement in Nordic municipalities

    DEFF Research Database (Denmark)

    Sørensen, Claus Hedegaard

    2008-01-01

    Road noise nuisance is a huge problem in the Nordic countries, and it seems diffi cult for Nordic countries to meet national targets for its reduction. One reason for this is the lack of municipal activities in the fi eld. Th us the research question that this article seeks to answer in relation...... to already existing residential areas and roads is: which conditions in the municipal organisation and its institutional environment contribute to making municipalities provide and implement noise abatement measures? Th e assumption is that three factors infl uence how the municipalities prioritize among...... political issues: the municipal organisation itself, the local institutional environment (citizens, business and NGOs), and the state and trans-municipal networks. A study of the anatomy of municipal road noise abatement policy shows that conditions for implementing road noise abatement in existing...

  15. Nitrous Oxide Abatement Coupled with Biopolymer Production As a Model GHG Biorefinery for Cost-Effective Climate Change Mitigation.

    Science.gov (United States)

    Frutos, Osvaldo D; Cortes, Irene; Cantera, Sara; Arnaiz, Esther; Lebrero, Raquel; Muñoz, Raúl

    2017-06-06

    N 2 O represents ∼6% of the global greenhouse gas emission inventory and the most important O 3 -depleting substance emitted in this 21st century. Despite its environmental relevance, little attention has been given to cost-effective and environmentally friendly N 2 O abatement methods. Here we examined, the potential of a bubble column (BCR) and an internal loop airlift (ALR) bioreactors of 2.3 L for the abatement of N 2 O from a nitric acid plant emission. The process was based on the biological reduction of N 2 O by Paracoccus denitrificans using methanol as a carbon/electron source. Two nitrogen limiting strategies were also tested for the coproduction of poly(3-hydroxybutyrate-co-3-hydroxyvalerate) (PHBV) coupled with N 2 O reduction. High N 2 O removal efficiencies (REs) (≈87%) together with a low PHBV cell accumulation were observed in both bioreactors in excess of nitrogen. However, PHBV contents of 38-64% were recorded under N limiting conditions along with N 2 O-REs of ≈57% and ≈84% in the ALR and BCR, respectively. Fluorescence in situ hybridization analyses showed that P. denitrificans was dominant (>50%) after 6 months of experimentation. The successful abatement of N 2 O concomitant with PHBV accumulation confirmed the potential of integrating biorefinery concepts into biological gas treatment for a cost-effective GHG mitigation.

  16. Considerations on abatement of SO2 pollution

    International Nuclear Information System (INIS)

    Ataman, E.

    1992-01-01

    The paper brings into focus the problems related to the SO 2 environmental pollution, to the emission standards, stress being laid on the possibilities of SO 2 emissions reduction resulting from the man-made stationary sources. A comparative estimation is made concerning the necessary investments for the desulfurization plants in accordance with the process employed and with the size of the boiler, as well as, of the operating costs brought about by desulfurization. The paper concludes with the prospects of flue gas reduction in thermal power plants. (author). 5 tabs., 21 refs

  17. Economic incentives for optimal sulfur abatement in Europe

    International Nuclear Information System (INIS)

    Halkos, G.E.

    1995-01-01

    This article reviews and develops theoretical and empirical representations of economic incentives for implementing pollution control strategies. A number of alternative economic instruments exist, which, if applied internationally, could encourage implementation of abatement strategies by counties. The article considers means of persuading countries to minimize abatement costs. A comparison between the pollution targets achieved by the imposition of a uniform charge rate and by differentiated charge rates is discussed, and empirical results are provided with associated conclusions. These results are compared with a simple standards setting in the form of critical loads, in order to assess empirically if economic instruments work better than regulations

  18. Luminescence in Sulfides: A Rich History and a Bright Future

    Directory of Open Access Journals (Sweden)

    Philippe F. Smet

    2010-04-01

    Full Text Available Sulfide-based luminescent materials have attracted a lot of attention for a wide range of photo-, cathodo- and electroluminescent applications. Upon doping with Ce3+ and Eu2+, the luminescence can be varied over the entire visible region by appropriately choosing the composition of the sulfide host. Main application areas are flat panel displays based on thin film electroluminescence, field emission displays and ZnS-based powder electroluminescence for backlights. For these applications, special attention is given to BaAl2S4:Eu, ZnS:Mn and ZnS:Cu. Recently, sulfide materials have regained interest due to their ability (in contrast to oxide materials to provide a broad band, Eu2+-based red emission for use as a color conversion material in white-light emitting diodes (LEDs. The potential application of rare-earth doped binary alkaline-earth sulfides, like CaS and SrS, thiogallates, thioaluminates and thiosilicates as conversion phosphors is discussed. Finally, this review concludes with the size-dependent luminescence in intrinsic colloidal quantum dots like PbS and CdS, and with the luminescence in doped nanoparticles.

  19. Estimating the financial risks of Andropogon gayanus to greenhouse gas abatement projects in northern Australia

    Science.gov (United States)

    Adams, Vanessa M.; Setterfield, Samantha A.

    2013-06-01

    Financial mechanisms such as offsets are one strategy to abate greenhouse gas emissions, and the carbon market is expanding with a growing demand for offset products. However, in the case of carbon offsets, if the carbon is released due to intentional or unintentional reversal through environmental events such as fire, the financial liability to replace lost offsets will likely fall on the provider. This liability may have implications for future participation in programmes, but common strategies such as buffer pool and insurance products can be used to minimize this liability. In order for these strategies to be effective, an understanding of the spatial and temporal distributions of expected reversals is needed. We use the case study of savanna burning, an approved greenhouse gas abatement methodology under the Carbon Farming Initiative in Australia, to examine potential risks to carbon markets in northern Australia and quantify the financial risks. We focus our analysis on the threat of Andropogon gayanus (gamba grass) to savanna burning due to its documented impacts of increased fuel loads and altered fire regimes. We assess the spatial and financial extent to which gamba grass poses a risk to savanna burning programmes in northern Australia. We find that 75% of the eligible area for savanna burning is spatially coincident with the high suitability range for gamba grass. Our analysis demonstrates that the presence of gamba grass seriously impacts the financial viability of savanna burning projects. For example, in order to recuperate the annual costs of controlling 1 ha of gamba grass infestation, 290 ha of land must be enrolled in annual carbon abatement credits. Our results show an immediate need to contain gamba grass to its current extent to avoid future spread into large expanses of land, which are currently profitable for savanna burning.

  20. Estimating the financial risks of Andropogon gayanus to greenhouse gas abatement projects in northern Australia

    International Nuclear Information System (INIS)

    Adams, Vanessa M; Setterfield, Samantha A

    2013-01-01

    Financial mechanisms such as offsets are one strategy to abate greenhouse gas emissions, and the carbon market is expanding with a growing demand for offset products. However, in the case of carbon offsets, if the carbon is released due to intentional or unintentional reversal through environmental events such as fire, the financial liability to replace lost offsets will likely fall on the provider. This liability may have implications for future participation in programmes, but common strategies such as buffer pool and insurance products can be used to minimize this liability. In order for these strategies to be effective, an understanding of the spatial and temporal distributions of expected reversals is needed. We use the case study of savanna burning, an approved greenhouse gas abatement methodology under the Carbon Farming Initiative in Australia, to examine potential risks to carbon markets in northern Australia and quantify the financial risks. We focus our analysis on the threat of Andropogon gayanus (gamba grass) to savanna burning due to its documented impacts of increased fuel loads and altered fire regimes. We assess the spatial and financial extent to which gamba grass poses a risk to savanna burning programmes in northern Australia. We find that 75% of the eligible area for savanna burning is spatially coincident with the high suitability range for gamba grass. Our analysis demonstrates that the presence of gamba grass seriously impacts the financial viability of savanna burning projects. For example, in order to recuperate the annual costs of controlling 1 ha of gamba grass infestation, 290 ha of land must be enrolled in annual carbon abatement credits. Our results show an immediate need to contain gamba grass to its current extent to avoid future spread into large expanses of land, which are currently profitable for savanna burning. (letter)

  1. Greenhouse gas abatement strategies for animal husbandry

    NARCIS (Netherlands)

    Monteny, G.J.; Bannink, A.; Chadwick, D.

    2006-01-01

    Agriculture contributes significantly to the anthropogenic emissions of non-CO2 greenhouse gases methane and nitrous oxide. In this paper, a review is presented of the agriculture related sources of methane and nitrous oxide, and of the main strategies for mitigation. The rumen is the most important

  2. The economics of greenhouse gas mitigation: Insights from illustrative global abatement scenarios modelling

    International Nuclear Information System (INIS)

    Gurney, Andrew; Ahammad, Helal; Ford, Melanie

    2009-01-01

    In this paper the Global Trade and Environment Model (GTEM) and MAGICC are used to simulate a number of global emission mitigation scenarios devised by the EMF 22 Transition Scenarios group in which radiative forcing goals and the architecture of developing economies' participation in hypothetical mitigation actions are varied. This paper presents a reference case of the world economy to 2100 and analyses some key regional and global results for the various global mitigation scenarios, including emission prices, emission levels, primary energy consumption and economic growth. Modelling results suggest that a transition to a low-carbon world would require a significant decarbonisation of electricity generation without necessarily cutting the electricity output in the long run. With the uptake of hybrids and non-fossil-fuel technologies, the transport sector could make an important contribution to global abatement of greenhouse gases. Furthermore, with substantial international mitigation efforts and uptake of low- and/or zero-emission technologies, the achievement of 3.7 W/m 2 and 4.5 W/m 2 radiative forcing targets by the end of the century could occur at emission prices of up to $550/t CO 2 -e. However, achieving the 2.6 W/m 2 (overshoot) radiative forcing target would require considerably higher emission prices and an immediate global mitigation action.

  3. Pollution abatement from road transport: cross-sectoral implications, climate co-benefits and behavioural change

    International Nuclear Information System (INIS)

    Oxley, T.; Elshkaki, A.; Kwiatkowski, L.; Castillo, A.; Scarbrough, T.; ApSimon, H.

    2012-01-01

    With the abatement potential of end-of-pipe technologies for road transport becoming increasingly marginal, and with greater emissions reductions still needed in order to reduce pollution, alternative strategies involving behavioural change and choices between fossil fuelled or low carbon vehicles becomes more important. The environmental requirements include local air quality objectives, meeting national emissions ceilings to limit transboundary effects, and to aspire to significant reductions in greenhouse gas emissions. In this paper we use the BRUTAL sub-model of the UK integrated Assessment Model (UKIAM) to investigate a selection of alternative strategies including downsizing of cars, switching from petrol to diesel, and the introduction of electric, bio-fuelled or hydrogen vehicles into the fleet, relative to a business-as-usual projection for 2020. Projected impacts upon air quality limit values, national emissions ceilings and CO 2 emissions are assessed in relation to local, national and international objectives. We discuss related life-cycle impacts, implications for infrastructure, and potential impacts upon emissions from other sectors in order to highlight the full potential implications of the different strategies within the context of changes resulting from other policy developments at different scales.

  4. Lanthanide complexes as luminogenic probes to measure sulfide levels in industrial samples

    International Nuclear Information System (INIS)

    Thorson, Megan K.; Ung, Phuc; Leaver, Franklin M.; Corbin, Teresa S.; Tuck, Kellie L.; Graham, Bim; Barrios, Amy M.

    2015-01-01

    A series of lanthanide-based, azide-appended complexes were investigated as hydrogen sulfide-sensitive probes. Europium complex 1 and Tb complex 3 both displayed a sulfide-dependent increase in luminescence, while Tb complex 2 displayed a decrease in luminescence upon exposure to NaHS. The utility of the complexes for monitoring sulfide levels in industrial oil and water samples was investigated. Complex 3 provided a sensitive measure of sulfide levels in petrochemical water samples (detection limit ∼ 250 nM), while complex 1 was capable of monitoring μM levels of sulfide in partially refined crude oil. - Highlights: • Lanthanide–azide based sulfide sensors were synthesized and characterized. • The probes have excitation and emission profiles compatible with sulfide-contaminated samples from the petrochemical industry. • A terbium-based probe was used to measure the sulfide concentration in oil refinery wastewater. • A europium-based probe had compatibility with partially refined crude oil samples.

  5. Lanthanide complexes as luminogenic probes to measure sulfide levels in industrial samples

    Energy Technology Data Exchange (ETDEWEB)

    Thorson, Megan K. [Department of Medicinal Chemistry, University of Utah College of Pharmacy, Salt Lake City, UT 84108 (United States); Ung, Phuc [Monash Institute of Pharmaceutical Sciences, Monash University, Victoria 3052 (Australia); Leaver, Franklin M. [Water & Energy Systems Technology, Inc., Kaysville, UT 84037 (United States); Corbin, Teresa S. [Quality Services Laboratory, Tesoro Refining and Marketing, Salt Lake City, UT 84103 (United States); Tuck, Kellie L., E-mail: kellie.tuck@monash.edu [School of Chemistry, Monash University, Victoria 3800 (Australia); Graham, Bim, E-mail: bim.graham@monash.edu [Monash Institute of Pharmaceutical Sciences, Monash University, Victoria 3052 (Australia); Barrios, Amy M., E-mail: amy.barrios@utah.edu [Department of Medicinal Chemistry, University of Utah College of Pharmacy, Salt Lake City, UT 84108 (United States)

    2015-10-08

    A series of lanthanide-based, azide-appended complexes were investigated as hydrogen sulfide-sensitive probes. Europium complex 1 and Tb complex 3 both displayed a sulfide-dependent increase in luminescence, while Tb complex 2 displayed a decrease in luminescence upon exposure to NaHS. The utility of the complexes for monitoring sulfide levels in industrial oil and water samples was investigated. Complex 3 provided a sensitive measure of sulfide levels in petrochemical water samples (detection limit ∼ 250 nM), while complex 1 was capable of monitoring μM levels of sulfide in partially refined crude oil. - Highlights: • Lanthanide–azide based sulfide sensors were synthesized and characterized. • The probes have excitation and emission profiles compatible with sulfide-contaminated samples from the petrochemical industry. • A terbium-based probe was used to measure the sulfide concentration in oil refinery wastewater. • A europium-based probe had compatibility with partially refined crude oil samples.

  6. Acid deposition. Origins, impacts and abatement strategies

    Energy Technology Data Exchange (ETDEWEB)

    Longhurst, J.W.S. (Manchester Polytechnic, Acid Rain Information Centre (United Kingdom). Dept. of Environmental and Geographical Studies) (ed.)

    1991-01-01

    The subject of acid deposition is one of the most important of our contemporary environmental problems. Presenting and discussing new data on the sources and effects of such deposition, this book seeks to assist in the definition of our future research requirements and policy developments. It is divided into four broad themes: Emissions, Chemistry and Deposition, Ecosystem Effects (freshwater, soils and forest systems), Effects on Structural Materials, and Mitigation, Control and Management. (orig.) With 130 figs.

  7. Concepts and measures for greenhouse gas abatement

    International Nuclear Information System (INIS)

    Lamprecht, F.

    1995-01-01

    On April 3 this year, the Hannover Fair will open, and at the same time in Berlin, the participants of the UN conference of the signatory states to the Climate Change Convention will enter the decisive phase of debates about concrete proposals and standards for giving life to the Convention and provide for practical application. Although the conference is not expected to achieve contractual commitments for reducing the CO 2 emissions, it has indeed prepared the ground for enhanced willingness to combat emissions, which is shown in initiatives such as the public commitment of German industry, to cut back CO 2 emissions by 20% until the year 2005, (1987 being taken as the reference year). Industry announced to achieve this goal by appropriate technology for enhancing the efficiency of power generating systems and energy utilization. The Hannover Fair is the right place to look for the required technology and equipment, and public utilities will even be offered comprehensive problem solutions for their supply services. (orig./UA) [de

  8. Gas Flaring, Environmental Pollution and Abatement Measures in ...

    African Journals Online (AJOL)

    The environmental impact of gas flaring on the oil bearing enclave of the Niger Delta, Nigeria, was examined with a view to evaluating the abatement measures put in place by the Federal government of Nigeria and the oil producing companies. Primary and secondary information and data were analyzed during the study.

  9. Energy balance and GHG-abatement cost of cassava utilization for fuel ethanol in Thailand

    International Nuclear Information System (INIS)

    Nguyen, Thu Lan Thi; Gheewala, Shabbir H.; Garivait, Savitri

    2007-01-01

    Since 2001, in order to enhance ethanol's cost competitiveness with gasoline, the Thai government has approved the exemption of excise tax imposed on ethanol, controlling the retail price of gasohol (a mixture of ethanol and gasoline at a ratio of 1:9) to be less than that of octane 95 gasoline, within a range not exceeding 1.5 baht a litre. The policy to promote ethanol for transport is being supported by its positive effects on energy security and climate change mitigation. An analysis of energy, greenhouse gas (GHG) balances and GHG abatement cost was done to evaluate fuel ethanol produced from cassava in Thailand. Positive energy balance of 22.4 MJ/L and net avoided GHG emission of 1.6 kg CO 2 eq./L found for cassava-based ethanol (CE) proved that it would be a good substitute for gasoline, effective in fossil energy saving and GHG reduction. With a GHG abatement cost of US$99 per tonne of CO 2 , CE is rather less cost effective than the many other climate strategies relevant to Thailand in the short term. Opportunities for improvements are discussed to make CE a reasonable option for national climate policy

  10. Chance-constrained/stochastic linear programming model for acid rain abatement. I. Complete colinearity and noncolinearity

    Energy Technology Data Exchange (ETDEWEB)

    Ellis, J H; McBean, E A; Farquhar, G J

    1985-01-01

    A Linear Programming model is presented for development of acid rain abatement strategies in eastern North America. For a system comprised of 235 large controllable point sources and 83 uncontrolled area sources, it determines the least-cost method of reducing SO/sub 2/ emissions to satisfy maximum wet sulfur deposition limits at 20 sensitive receptor locations. In this paper, the purely deterministic model is extended to a probabilistic form by incorporating the effects of meteorologic variability on the long-range pollutant transport processes. These processes are represented by source-receptor-specific transfer coefficients. Experiments for quantifying the spatial variability of transfer coefficients showed their distributions to be approximately lognormal with logarithmic standard deviations consistently about unity. Three methods of incorporating second-moment random variable uncertainty into the deterministic LP framework are described: Two-Stage Programming Under Uncertainty, Chance-Constrained Programming and Stochastic Linear Programming. A composite CCP-SLP model is developed which embodies the two-dimensional characteristics of transfer coefficient uncertainty. Two probabilistic formulations are described involving complete colinearity and complete noncolinearity for the transfer coefficient covariance-correlation structure. The completely colinear and noncolinear formulations are considered extreme bounds in a meteorologic sense and yield abatement strategies of largely didactic value. Such strategies can be characterized as having excessive costs and undesirable deposition results in the completely colinear case and absence of a clearly defined system risk level (other than expected-value) in the noncolinear formulation.

  11. Marginal abatement cost curves for NOx that account for renewable electricity, energy efficiency, and fuel switching

    Science.gov (United States)

    A marginal abatement cost curve (MACC) traces out the relationship between the quantity of pollution abated and the marginal cost of abating each additional unit. In the context of air quality management, MACCs typically are developed by sorting end-of-pipe controls by their resp...

  12. Marginal abatement cost curve for NOx incorporating controls, renewable electricity, energy efficiency and fuel switching

    Science.gov (United States)

    A marginal abatement cost curve (MACC) traces out the relationship between the quantity of pollution abated and the marginal cost of abating each additional unit. In the context of air quality management, MACCs typically are developed by sorting end-of-pipe controls by their rela...

  13. Marginal abatement cost curve for NOx incorporating controls, renewable electricity, energy efficiency and fuel switching

    Science.gov (United States)

    A marginal abatement cost curve (MACC) traces out the relationship between the quantity of pollution abated and the marginal cost of abating each additional unit. In the context of air quality management, MACCs typically are developed by sorting end-of-pipe controls by their resp...

  14. Greenhouse Gas Abatement with Distributed Generation in California's Commercial Buildings

    International Nuclear Information System (INIS)

    Stadler, Michael; Marnay, Chris; Cardoso, Goncalo; Megel, Olivier; Siddiqui, Afzal; Lai, Judy

    2009-01-01

    Lawrence Berkeley National Laboratory (LBL) is working with the California Energy Commission (CEC) to determine the role of distributed generation (DG) in greenhouse gas reductions. The impact of DG on large industrial sites is well known, and mostly, the potentials are already harvested. In contrast, little is known about the impact of DG on commercial buildings with peak electric loads ranging from 100 kW to 5 MW. We examine how DG with combined heat and power (CHP) may be implemented within the context of a cost minimizing microgrid that is able to adopt and operate various smart energy technologies, such as thermal and photovoltaic (PV) on-site generation, heat exchangers, solar thermal collectors, absorption chillers, and storage systems. We use a mixed-integer linear program (MILP) that has the minimization of a site's annual energy costs as objective. Using 138 representative commercial sites in California (CA) with existing tariff rates and technology data, we find the greenhouse gas reduction potential for California's commercial sector. This paper shows results from the ongoing research project and finished work from a two year U.S. Department of Energy research project. To show the impact of the different technologies on CO2 emissions, several sensitivity runs for different climate zones within CA with different technology performance expectations for 2020 were performed. The considered sites can contribute between 1 Mt/a and 1.8 Mt/a to the California Air Resources Board (CARB) goal of 6.7Mt/a CO2 abatement potential in 2020. Also, with lower PV and storage costs as well as consideration of a CO2 pricing scheme, our results indicate that PV and electric storage adoption can compete rather than supplement each other when the tariff structure and costs of electricity supply have been taken into consideration. To satisfy the site's objective of minimizing energy costs, the batteries will be charged also by CHP systems during off-peak and mid-peak hours and

  15. Technical opportunities to reduce global anthropogenic emissions of nitrous oxide

    Science.gov (United States)

    Winiwarter, Wilfried; Höglund-Isaksson, Lena; Klimont, Zbigniew; Schöpp, Wolfgang; Amann, Markus

    2018-01-01

    We describe a consistent framework developed to quantify current and future anthropogenic emissions of nitrous oxide and the available technical abatement options by source sector for 172 regions globally. About 65% of the current emissions derive from agricultural soils, 8% from waste, and 4% from the chemical industry. Low-cost abatement options are available in industry, wastewater, and agriculture, where they are limited to large industrial farms. We estimate that by 2030, emissions can be reduced by about 6% ±2% applying abatement options at a cost lower than 10 €/t CO2-eq. The largest abatement potential at higher marginal costs is available from agricultural soils, employing precision fertilizer application technology as well as chemical treatment of fertilizers to suppress conversion processes in soil (nitrification inhibitors). At marginal costs of up to 100 €/t CO2-eq, about 18% ±6% of baseline emissions can be removed and when considering all available options, the global abatement potential increases to about 26% ±9%. Due to expected future increase in activities driving nitrous oxide emissions, the limited technical abatement potential available means that even at full implementation of reduction measures by 2030, global emissions can be at most stabilized at the pre-2010 level. In order to achieve deeper reductions in emissions, considerable technological development will be required as well as non-technical options like adjusting human diets towards moderate animal protein consumption.

  16. Provincial carbon intensity abatement potential estimation in China: A PSO–GA-optimized multi-factor environmental learning curve method

    International Nuclear Information System (INIS)

    Yu, Shiwei; Zhang, Junjie; Zheng, Shuhong; Sun, Han

    2015-01-01

    This study aims to estimate carbon intensity abatement potential in China at the regional level by proposing a particle swarm optimization–genetic algorithm (PSO–GA) multivariate environmental learning curve estimation method. The model uses two independent variables, namely, per capita gross domestic product (GDP) and the proportion of the tertiary industry in GDP, to construct carbon intensity learning curves (CILCs), i.e., CO 2 emissions per unit of GDP, of 30 provinces in China. Instead of the traditional ordinary least squares (OLS) method, a PSO–GA intelligent optimization algorithm is used to optimize the coefficients of a learning curve. The carbon intensity abatement potentials of the 30 Chinese provinces are estimated via PSO–GA under the business-as-usual scenario. The estimation reveals the following results. (1) For most provinces, the abatement potentials from improving a unit of the proportion of the tertiary industry in GDP are higher than the potentials from raising a unit of per capita GDP. (2) The average potential of the 30 provinces in 2020 will be 37.6% based on the emission's level of 2005. The potentials of Jiangsu, Tianjin, Shandong, Beijing, and Heilongjiang are over 60%. Ningxia is the only province without intensity abatement potential. (3) The total carbon intensity in China weighted by the GDP shares of the 30 provinces will decline by 39.4% in 2020 compared with that in 2005. This intensity cannot achieve the 40%–45% carbon intensity reduction target set by the Chinese government. Additional mitigation policies should be developed to uncover the potentials of Ningxia and Inner Mongolia. In addition, the simulation accuracy of the CILCs optimized by PSO–GA is higher than that of the CILCs optimized by the traditional OLS method. - Highlights: • A PSO–GA-optimized multi-factor environmental learning curve method is proposed. • The carbon intensity abatement potentials of the 30 Chinese provinces are estimated by

  17. UNEP greenhouse gas abatement costing studies. Zimbabwe country study. Phase 1

    Energy Technology Data Exchange (ETDEWEB)

    Shakespeare Maya, R. [Southern Centre for Energy and Environment (Zimbabwe); Muguti, E. [Ministry of Transport and Energy. Department of Energy (Zimbabwe); Fenhann, J.; Morthorst, P.E. [Risoe National Laboratory. Systems Analysis Department (Denmark)

    1992-08-01

    The UNEP (United Nations Environment Programme) programme of Greenhouse Gas Abatement Costing Studies is intended to clarify the economic issues involved in assessing the costs of limiting emissions of greenhouse gases and to propose approaches to comparable costing studies. Phase 1 of the Zimbabwe country study describes the current energy situation in Zimbabwe related to the national economy, energy supply and demand and amounts of greenhouse gas emissions. Factors regarding the geography, (including a map illustrating the degree and character of land degradation by erosion) population, politics, international relations, land-use and management of the energy sector are dealt with in detail and the text is illustrated with data compiled from the study. It is estimated that Zimbabwe consumed 270.4 Tj of energy during 1988 and emitted 21.7 tonnes of carbon dioxide. An emission intensity of 80.2 tonnes/Tj for the whole economy and 63.6 tonnes/Tj for electric power generation alone was calculated. Forecasting for the year 2020 estimated carbon dioxide emission intensities of 73.5 tonnes/Tj for the whole economy and 43.7 tonnes for power generation. Net carbon dioxide emissions are predicted to be 30-42 tonnes during 2020. (AB).

  18. 40 CFR 205.52 - Vehicle noise emission standards.

    Science.gov (United States)

    2010-07-01

    ... 40 Protection of Environment 24 2010-07-01 2010-07-01 false Vehicle noise emission standards. 205... ABATEMENT PROGRAMS TRANSPORTATION EQUIPMENT NOISE EMISSION CONTROLS Medium and Heavy Trucks § 205.52 Vehicle noise emission standards. (a) Low Speed Noise Emission Standard. Vehicles which are manufactured after...

  19. A Reaction Involving Oxygen and Metal Sulfides.

    Science.gov (United States)

    Hill, William D. Jr.

    1986-01-01

    Describes a procedure for oxygen generation by thermal decomposition of potassium chlorate in presence of manganese dioxide, reacted with various sulfides. Provides a table of sample product yields for various sulfides. (JM)

  20. Sulfide-conducting solid electrolytes

    International Nuclear Information System (INIS)

    Kalinina, L.A.; Shirokova, G.I.; Murin, I.V.; Ushakova, Yu.N.; Fominykh, E.G.; Lyalina, M.Yu.

    2000-01-01

    Feasibility of sulfide transfer in phases on the basis of BaZrS 3 and MLn 2 S 4 ( M = Ca, Ba; Ln = La, Y, Tm, Nd, Sm, Pr) is considered. Solid solution regions on the basis of ternary compounds are determined. Systematic study of the phases is carried out making use of the methods of conductometry, emf in chemical concentration chains without/with transfer, potentiostatic chronoamperometry. Possible mechanism of defect formation during successive alloying of ternary sulfides by binary ones in suggested [ru

  1. Nanostructured metal sulfides for energy storage

    Science.gov (United States)

    Rui, Xianhong; Tan, Huiteng; Yan, Qingyu

    2014-08-01

    Advanced electrodes with a high energy density at high power are urgently needed for high-performance energy storage devices, including lithium-ion batteries (LIBs) and supercapacitors (SCs), to fulfil the requirements of future electrochemical power sources for applications such as in hybrid electric/plug-in-hybrid (HEV/PHEV) vehicles. Metal sulfides with unique physical and chemical properties, as well as high specific capacity/capacitance, which are typically multiple times higher than that of the carbon/graphite-based materials, are currently studied as promising electrode materials. However, the implementation of these sulfide electrodes in practical applications is hindered by their inferior rate performance and cycling stability. Nanostructures offering the advantages of high surface-to-volume ratios, favourable transport properties, and high freedom for the volume change upon ion insertion/extraction and other reactions, present an opportunity to build next-generation LIBs and SCs. Thus, the development of novel concepts in material research to achieve new nanostructures paves the way for improved electrochemical performance. Herein, we summarize recent advances in nanostructured metal sulfides, such as iron sulfides, copper sulfides, cobalt sulfides, nickel sulfides, manganese sulfides, molybdenum sulfides, tin sulfides, with zero-, one-, two-, and three-dimensional morphologies for LIB and SC applications. In addition, the recently emerged concept of incorporating conductive matrices, especially graphene, with metal sulfide nanomaterials will also be highlighted. Finally, some remarks are made on the challenges and perspectives for the future development of metal sulfide-based LIB and SC devices.

  2. 30 CFR 250.504 - Hydrogen sulfide.

    Science.gov (United States)

    2010-07-01

    ... 30 Mineral Resources 2 2010-07-01 2010-07-01 false Hydrogen sulfide. 250.504 Section 250.504... OPERATIONS IN THE OUTER CONTINENTAL SHELF Oil and Gas Well-Completion Operations § 250.504 Hydrogen sulfide. When a well-completion operation is conducted in zones known to contain hydrogen sulfide (H2S) or in...

  3. 30 CFR 250.808 - Hydrogen sulfide.

    Science.gov (United States)

    2010-07-01

    ... 30 Mineral Resources 2 2010-07-01 2010-07-01 false Hydrogen sulfide. 250.808 Section 250.808... OPERATIONS IN THE OUTER CONTINENTAL SHELF Oil and Gas Production Safety Systems § 250.808 Hydrogen sulfide. Production operations in zones known to contain hydrogen sulfide (H2S) or in zones where the presence of H2S...

  4. 30 CFR 250.604 - Hydrogen sulfide.

    Science.gov (United States)

    2010-07-01

    ... 30 Mineral Resources 2 2010-07-01 2010-07-01 false Hydrogen sulfide. 250.604 Section 250.604... OPERATIONS IN THE OUTER CONTINENTAL SHELF Oil and Gas Well-Workover Operations § 250.604 Hydrogen sulfide. When a well-workover operation is conducted in zones known to contain hydrogen sulfide (H2S) or in...

  5. Abatement of fluorinated compounds using a 2.45 GHz microwave plasma torch with a reverse vortex plasma reactor

    Energy Technology Data Exchange (ETDEWEB)

    Kim, J.H.; Cho, C.H.; Shin, D.H. [Plasma Technology Research Center, National Fusion Research Institute, 814-2 Oxikdo-dong, Gunsan-city, Jeollabuk-do (Korea, Republic of); Hong, Y.C., E-mail: ychong@nfri.re.kr [Plasma Technology Research Center, National Fusion Research Institute, 814-2 Oxikdo-dong, Gunsan-city, Jeollabuk-do (Korea, Republic of); Shin, Y.W. [Plasma Technology Research Center, National Fusion Research Institute, 814-2 Oxikdo-dong, Gunsan-city, Jeollabuk-do (Korea, Republic of); School of Advanced Green Energy and Environments, Handong Global University, Heunghae-eup, Buk-gu, Pohang-city, Gyeongbuk (Korea, Republic of)

    2015-08-30

    Highlights: • We developed a microwave plasma torch with reverse vortex reactor (RVR). • We calculated a volume fraction and temperature distribution of discharge gas and waste. • The performance of reverse vortex reactor increased from 29% to 43% than conventional vortex reactor. - Abstract: Abatement of fluorinated compounds (FCs) used in semiconductor and display industries has received an attention due to the increasingly stricter regulation on their emission. We have developed a 2.45 GHz microwave plasma torch with reverse vortex reactor (RVR). In order to design a reverse vortex plasma reactor, we calculated a volume fraction and temperature distribution of discharge gas and waste gas in RVR by ANSYS CFX of computational fluid dynamics (CFD) simulation code. Abatement experiments have been performed with respect to SF{sub 6}, NF{sub 3} by varying plasma power and N{sub 2} flow rates, and FCs concentration. Detailed experiments were conducted on the abatement of NF{sub 3} and SF{sub 6} in terms of destruction and removal efficiency (DRE) using Fourier transform infrared (FTIR). The DRE of 99.9% for NF{sub 3} was achieved without an additive gas at the N{sub 2} flow rate of 150 liter per minute (L/min) by applying a microwave power of 6 kW with RVR. Also, a DRE of SF{sub 6} was 99.99% at the N{sub 2} flow rate of 60 L/min using an applied microwave power of 6 kW. The performance of reverse vortex reactor increased about 43% of NF{sub 3} and 29% of SF{sub 6} abatements results definition by decomposition energy per liter more than conventional vortex reactor.

  6. Endogenous Technological Progress with Uncertainty and Carbon Abatement Polices

    Energy Technology Data Exchange (ETDEWEB)

    Cho, G.L. [Korea Energy Economics Institute, Euiwang (Korea)

    2001-11-01

    Most greenhouse gas abatement policy models tend to neglect a potentially important element that is relevant to the induced technology changes(ITC). These models that incorporate technological change treat such a change as autonomous, that is, unaffected by changes in prices brought about by policy reforms. However, climate change policies can create economic incentives to engage in more extensive R and D oriented toward the discovery of new production techniques that mitigate a reliance on convectional fuels, ultimately resulting in impacts on the policies themselves. In order to investigate the significance of induced technology for the attractiveness of abatement policies, this study develop the multi-sectoral dynamic CGE model by incorporating two characteristics of technological progress: the endogenous growth model with externality of technology in Romer (1986) and Lucas(1988) and the technological changes resulting from profit maximizing investment in R and D in Rebelo(1991) and Jones and Manuelli(1990). Furthermore, technological progress is affected by not only the economical factors but also the political and institutional system that cannot be captured in this model. This study considers such uncertainty in the technological progress as technology shock as in RBC school. This study shows that the presence of ITC implies lower costs of achieving a given abatement target in terms of the reduction cost per ton of carbon and GDP losses. The presence of ITC reduces the GDP losses by 0.9%p{approx}1.5%p compared with the absence of the ITC. As the abatement target is substantially high, R and D is reduced significantly even in the presence of ITC. Therefore, it is necessary to seriously consider the tax recycling for enhancing R and D investment, which minimizes the GDP losses. The reduction cost is highly sensitive to the uncertainty in technological progress. The technology shock leads the reduction cost to widely vary, in terms of standard deviation, 3

  7. Essays on carbon abatement and electricity markets

    Science.gov (United States)

    Taber, John Timothy

    In the first chapter of this dissertation, I study the effects of a number of policies which affect the electric grid using the SuperOPF, a full AC optimization/simulation framework with optimal investment developed at Cornell University. A 36-node model of the Northeast Power Coordinating Council is used to test policies that aim to reduce CO2, other emissions, or otherwise impact the operation of the electric grid: a base case, with no new environmental legislation; enactment of the Kerry-Lieberman CO2 allowance proposal in 2012; following Fukishima, a retirement of all US nuclear plants by 2022 with and without Kerry-Lieberman; marginal damages from SO2 and NOX emissions charged to coal, gas and oil-fired generation; plug-in hybrid electric vehicle load filling; wind incentives in place; and two cases which combine these. The cases suggest that alternative policies may have very different outcomes in terms of electricity prices, emissions, and health outcomes. In all cases, however, the optimal strategy for future investment is investment in new natural gas combined cycle plants. Policies can change how much new generation is built, whether other plants are built, or what types of plants are retired. The second chapter of my dissertation utilizes the SuperOPF and the model of the Northeast Power Coordinating Council to analyze the issue of carbon leakage. I analyze the effects of a regionally-limited carbon cap and trade program, the Regional Greenhouse Initiative (RGGI), when additional generating assets in non-affected states are included in the analysis. In the face of different carbon prices on generating assets in covered and non-covered states, generation is expected to shift from states bound by RGGI to states outside of RGGI. This carbon leakage may undermine some or all of the benefits of RGGI while simultaneously increasing prices for customers in the area. Even though carbon prices under RGGI are very low, some leakage is occurring, and this leakage

  8. Zeolite ZSM5 catalysts for abatement of nitrogen oxide

    Energy Technology Data Exchange (ETDEWEB)

    Ganemi, Bager

    1999-07-01

    Airborne pollutants from the combustion of fossil fuels are a global problem. Emission of nitrogen oxides (NO{sub x}) is increasing with the worldwide increase in the use of energy. Atmospheric and photochemical reactions link nitrogen oxides to hydrocarbons and tropospheric ozone. The emission of NO{sub x} has to be tackled urgently in order to limit the harmful effects of anthropogenic activity on the environment. The subject of this thesis is catalytic nitrogen oxide abatement through direct decomposition and reduction by methane over ion-exchanged zeolite ZSM5. The work covers catalytic conversion and surface intermediates, including correlations with the level of exchanged Cu{sup 2+} cations and Ni{sup 2+} or Pd{sup 2+} co-cations. Special attention is given to the aluminium content of the support and changes in structural parameters. It was found that NO{sub x} conversion over cation-exchanged ZSM5 is strongly influenced by the ion-exchange procedure and by the above material parameters. Characterization of Cu-ZSM5 reveals that approximately two molecules of water per Cu{sup 2+} ion desorb at temperatures between 150 and 350 Deg C, in addition to the conventional dehydration at lower temperatures. The desorbed water comes from the decomposition of Cu(OH){sub 2}. Decomposition of hydroxylated copper ions results in the formation Of Cu{sup 2+}-O-Cu{sup 2+} dimers, which are suggested to be the active sites for catalytic decomposition of NO. Acid sites are important for the dispersion of copper ions on the catalyst surface. Acid sites are also important for the interaction between copper species and the zeolite. Increased acidity leads to a stronger interaction between the exchanged cation and the framework, i.e. the exchanged cations become more resistant to mobility. The stronger bond between the exchanged cations and lattice oxygen also prevents dealumination of the catalyst and decreases the thermal expansion at higher temperatures. The temperature of

  9. STUDY OF HYDROGEN SULFIDE REMOVAL FROM GROUNDWATER

    Directory of Open Access Journals (Sweden)

    T. Lupascu

    2013-06-01

    Full Text Available The process of the hydrogen sulfide removal from the underground water of the Hancesti town has been investigated. By oxygen bubbling through the water containing hydrogen sulfide, from the Hancesti well tube, sulfur is deposited in the porous structure of studied catalysts, which decreases their catalytic activity. Concomitantly, the process of adsorption / oxidation of hydrogen sulfide to sulfate take place. The kinetic research of the hydrogen sulfide removal from the Hancesti underground water, after its treatment by hydrogen peroxide, proves greater efficiency than in the case of modified carbonic adsorbents. As a result of used treatment, hydrogen sulfide is completely oxidized to sulfates

  10. Investigation of nitrous oxide (N2O) abatement technologies. 2; Asanka chisso (N2O) no teigen taisaku ni kansuru chosa. 2

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    1997-03-01

    Emission amount of nitrous oxide (N2O) from anthropogenic sources is analyzed, and reduction effects by the abatement technologies are evaluated. The concentration of nitrous oxide in the atmosphere continues to increase and emissions from agricultural and ecosystem sources are drawing particular attention. For the emission of N2O in Japan, 8.28 Gg-N2O per year is emitted from fossil fuel combustion facilities, 6.95 from waste incineration facilities, 22.5 from transportation vehicles including automobiles, 26.7 from the chemical industry including establishments engaged in adipic acid production, 2.1 from sewage treatment facilities including septic tanks, 6.3 from farmland, and 7.1 from livestock excrement. For the N2O abatement technologies for different sources, fuel improvement, high temperature combustion, acceleration of reduction decomposition reaction, and development of catalysts are significant for the combustion technologies. In connection with N2O discharged in the process of adipic acid production, major businesses have internationally committed to up to 99% abatement of the N2O emissions by 1998. With regard to wastewater and sewage treatment facilities and septic tanks, improvement in COD/NO-N ratio, retention period, pH level, and reduction process is pointed out. 204 refs., 70 figs., 53 tabs.

  11. Literature review of acid forming emissions in livestock

    International Nuclear Information System (INIS)

    Prior, M.G.; Lopez, A.

    1992-01-01

    A review is presented of the effects of acid forming emissions such as sulfur and nitrogen oxides in livestock. Topics discussed include uptake of airborne pollutants, types of acid-forming pollutants, sources of sulfur-containing emissions, sour gas, and farm animal toxicity caused by carbon disulfide, carbonyl sulfide, ethyl sulfide, methyl sulfide, hydrogen sulfide, methylmercaptan, ethylmercaptan, propylmercaptan, nitrogen oxides, ozone, sulfur, and sulfur dioxide. A review is presented of field data including effects of emissions from gas plants, gas well blowouts, animal nutrition in west central Alberta, and experimental studies on goats and cows. 96 refs., 10 tabs

  12. Marginal abatement cost curves for Heavy Duty Vehicles. Background report

    Energy Technology Data Exchange (ETDEWEB)

    Schroten, A.; Warringa, G.; Bles, M.

    2012-09-15

    Cost curves were calculated for CO2 abatement technologies for Heavy Duty Vehicles. These curves were elaborated for eight different vehicle categories (six categories of truck and two subcategories), as well as for an 'average' truck and bus. Given that cost curves depend very much on underlying assumptions, the MACH model (Marginal Abatement Costs of Heavy duty vehicles) was developed. This model allows users to enter their own assumptions with respect to parameters like fuel prices and cost and lifetime of individual technologies, with the model then generating new cost curves for the various vehicle categories. This background report contains a description of the model and a summary of the results of several model runs.

  13. Enforcement of Intellectual Property, Pollution Abatement, and Directed Technical Change

    OpenAIRE

    Schaefer, Andreas

    2017-01-01

    We theoretically investigate the interaction between endogenous enforcement of intellectual property rights (IPRs) and tax-financed pollution abatement measures. IPRs affect dirty and clean intermediates alike such that higher IPR enforcement may promote the transition to the clean technology, if this technology is productive enough. If the green technology is relatively unproductive, higher IPRs promote the dirty technology while pollution is increasing. As households are due to subsistence ...

  14. Methane emission reduction: an application of FUND

    NARCIS (Netherlands)

    Tol, R.S.J.; Heintz, R.J.; Lammers, P.E.M.

    2003-01-01

    Methane is, after carbon dioxide, the most important anthropogenic greenhouse gas. Governments plan to abate methane emissions. A crude set of estimates of reduction costs is included in FUND, an integrated assessment model of climate change. In a cost-benefit analysis, methane emission reduction is

  15. Abate distribution and dengue control in rural Cambodia.

    Science.gov (United States)

    Khun, Sokrin; Manderson, Lenore H

    2007-02-01

    Sustainable public health and community collaboration and partnerships are essential for the effective elimination of vector breeding sites to prevent dengue fever. A prerequisite is that community members appreciate the importance of the infection, understand its transmission and preventive activities, and are able to translate such knowledge to action. In this paper, we draw on an ethnographic study of two villages in the eastern province of Kampong Cham, using data collected from qualitative research methods and entomological surveys to describe community knowledge of the vector, practices related to the reduction of breeding sources, and the effectiveness of temephos to control larvae. During the study period, temephos (distributed as Abate) was applied in water containers only in the rainy season, although these containers were also positive with larvae in the dry season. Discarded containers, ignored in terms of control activities, had twice the number of larvae as water storage containers. The continued reliance on Abate creates financial and technical problems, while its inappropriate distribution raises the possibility of larvicide resistance. Based on research findings, we argue that control strategies emphasizing the use of Abate should be reconsidered.

  16. The value of international cooperation for abating global climate change

    International Nuclear Information System (INIS)

    Hammitt, James K.; Adams, John L.

    1996-01-01

    Because abatement of global climate change is a public good, independent national actions may not produce the efficient quantity. Using a numerical integrated-assessment model, abatement costs and damages induced by climate change are compared at the cooperative and noncooperative solutions to a set of two-party dynamic games between the industrialized and developing countries. Games with perfect and imperfect information about climate and economic factors are considered. Across 144 games with perfect information, incorporating different values of climate and economic parameters, the noncooperative solution usually yields global benefits comparable to those of the cooperative solution. In about one-fifth of these games, however, a second noncooperative solution exists which yields none of the benefits of the cooperative solution. In a game with imperfect information, where the state of nature is uncertain in the first but known in the second of two periods, the expected benefits of the noncooperative solution are 98% of the expected benefits of the cooperative solution. In contrast to single-agent studies which show little cost to delaying abatement, the benefits of cooperation are usually lost if cooperation is delayed 20 years

  17. AC low-pressure plasmas generated by using annular-shaped electrodes for abatement of pollutants emitted during semiconductor manufacturing processes

    International Nuclear Information System (INIS)

    Hur, Min; Lee, Jae Ok; Song, Young Hoon

    2011-01-01

    A plasma abatement system operating at low pressures is set up with the aim of treating pollutants emitted by the semiconductor industry. The abatement device is characterized by using a tube-shaped reactor design and a bipolar alternating current, which allows an easy connection to pre-existing pipelines in the semiconductor industry and low installation cost, respectively. By using optical emission spectroscopy (OES) and Fourier transform infrared spectroscopy (FTIR), we analyzed the discharge characteristics and abatement efficiency with emphasis on the working pressure effect. In the case of CF 4 , the destruction and removal efficiency (DRE) is greatly reduced with increasing pressure. However, the pressure has a relatively small influence on the DRE for tetrakis(ethylmethylamino)zirconium (TEMAZ), which is significantly destroyed only with several hundred watts and without any liquefied byproducts. This difference is closely related to the spatial distribution of reactive species and to the chemical bond strengths of the pollutant's components. Finally, the applicability of the abatement device is discussed based on the experimental results.

  18. Mechanism design for refunding emissions payment

    Energy Technology Data Exchange (ETDEWEB)

    Hagem, Cathrine; Holtsmark, Bjart; Sterner, Thomas

    2012-07-01

    We analyze two mechanism designs for refunding emission payments to polluting firms; Output Based (OB) and Expenditure Based (EB) refunding. In both instruments, emissions fees are returned to the polluting industry, possibly making the policy more easily accepted by policymakers than a standard tax. The crucial difference between OB and EB is that the fees are refunded in proportion to output in the former, but in proportion to the firms' expenditure on abatement equipment in the latter. We show that to achieve a given abatement target, the fee level in the OB design exceeds the standard tax rate, whereas the fee level in the EB design is lower. Furthermore, the use of OB and EB refunding may lead to large differences in the distribution of costs across firms. Both designs do, strictly speaking, imply a cost-ineffective provision of abatement as firms put relatively too much effort into reducing emissions through abatement technology compared with emission reductions through reduced output. However, this may be seen as an advantage by policymakers if they seek to avoid activity reduction in the regulated sector. We provide some numerical illustrations based on abatement cost information from the Norwegian NOx fund.(Author)

  19. Fabrication and applications of copper sulfide (CuS) nanostructures

    Energy Technology Data Exchange (ETDEWEB)

    Shamraiz, Umair, E-mail: umairshamraiz@gmail.com; Hussain, Raja Azadar, E-mail: hussainazadar@gamil.com; Badshah, Amin, E-mail: aminbadshah@yahoo.com

    2016-06-15

    This review article presents different fabrication procedures (under the headlines of solvothermal routes, aerosol methods, solution methods and thermolysis), and applications (photocatalytic degradation, ablation of cancer cells, electrode material in lithium ion batteries and in gas sensing, organic solar cells, field emission properties, super capacitor applications, photoelectrochemical performance of QDSCs, photocatalytic reduction of organic pollutants, electrochemical bio sensing, enhanced PEC characteristics of pre-annealed CuS film electrodes) of copper sulfide (Covellite). - Highlights: • This review article presents the synthesis and applications of copper sulfide. • CuS has been used over the years for different applications in nanoscience. • Different synthetic protocols are followed for their preparation which help in the possible modifications in the morphology of CuS.

  20. Reaping the carbon rent: Abatement and overallocation profits in the European cement industry, insights from an LMDI decomposition analysis

    International Nuclear Information System (INIS)

    Branger, Frédéric; Quirion, Philippe

    2015-01-01

    We analyse variations of carbon emissions in the European cement industry from 1990 to 2012, at the European level (EU 27), and at the national level for six major producers (Germany, France, Spain, the United Kingdom, Italy and Poland). We apply a Log-Mean Divisia Index (LMDI) method, cross-referencing data from three databases: the Getting the Numbers Right (GNR) database developed by the Cement Sustainability Initiative, the European Union Transaction Log (EUTL), and the Eurostat International Trade database. Our decomposition method allows seven channels of emission change to be distinguished: activity, clinker trade, clinker share, alternative fuels, thermal and electrical energy efficiency, and electricity decarbonisation. We find that, apart from a slow trend of emission reductions coming from technological improvements (first from a decrease in the clinker share, then from an increase in alternative fuels), most of the emission change can be attributed to the activity effect. Using counterfactual scenarios, we estimate that the introduction of the EU ETS brought small but positive technological abatement (2.2% ± 1.3% between 2005 and 2012). Moreover, we find that the European cement industry has gained 3.5 billion Euros of “overallocation profits”, mostly due to the slowdown of production. - Highlights: • We analyse variations of carbon emissions in the European cement industry. • We apply a Log-Mean Divisia Index (LMDI) method. • Most of the emission changes can be attributed to the activity effect. • The EU ETS brought small but positive technological abatement. • The European cement industry has gained 3.5 billion Euros of “overallocation profits”

  1. Photocatalytic NO{sub x} abatement. Theory, applications, current research, and limitations

    Energy Technology Data Exchange (ETDEWEB)

    Bloh, Jonathan Z. [DECHEMA Research Institute, Frankfurt am Main (Germany)

    2017-01-15

    Nitrogen oxides are one of the major air pollutants that threaten our air quality and health. As a consequence, increasingly stricter regulations are in place forcing action to reduce the concentration of these dangerous compounds. Conventional methods of reducing the NO{sub x} pollution level are reducing the emission directly at the source or restrictive measures such as low emission zones. However, there are recent reports questioning the efficacy of the strategy to reduce ambient NO{sub x} levels solely by reducing their emissions and existing threshold values are still frequently exceeded in many European cities. Semiconductor photocatalysis presents an appealing alternative capable of removing NO{sub x} and other air pollutants from the air once they have already been released and dispersed. Recent field tests have shown that a reduction of a few percent in NO{sub x} values is possible with available photocatalysts. Current research focuses on further increasing the catalysts' efficacy as well as their selectivity to suppress the formation of undesired by-products. Especially using these improved materials, photocatalytic NO{sub x} abatement could prove a very valuable contributor to better air quality.

  2. Photocatalytic NO_x abatement. Theory, applications, current research, and limitations

    International Nuclear Information System (INIS)

    Bloh, Jonathan Z.

    2017-01-01

    Nitrogen oxides are one of the major air pollutants that threaten our air quality and health. As a consequence, increasingly stricter regulations are in place forcing action to reduce the concentration of these dangerous compounds. Conventional methods of reducing the NO_x pollution level are reducing the emission directly at the source or restrictive measures such as low emission zones. However, there are recent reports questioning the efficacy of the strategy to reduce ambient NO_x levels solely by reducing their emissions and existing threshold values are still frequently exceeded in many European cities. Semiconductor photocatalysis presents an appealing alternative capable of removing NO_x and other air pollutants from the air once they have already been released and dispersed. Recent field tests have shown that a reduction of a few percent in NO_x values is possible with available photocatalysts. Current research focuses on further increasing the catalysts' efficacy as well as their selectivity to suppress the formation of undesired by-products. Especially using these improved materials, photocatalytic NO_x abatement could prove a very valuable contributor to better air quality.

  3. LIGNOCELLULOSE NANOCOMPOSITE CONTAINING COPPER SULFIDE

    Directory of Open Access Journals (Sweden)

    Sanchi Nenkova

    2011-04-01

    Full Text Available Copper sulfide-containing lignocellulose nanocomposites with improved electroconductivity were obtained. Two methods for preparing the copper sulfide lignocellulose nanocomposites were developed. An optimization of the parameters for obtaining of the nanocomposites with respect to obtaining improved electroconductivity, economy, and lower quantities and concentration of copper and sulfur ions in waste waters was conducted. The mechanisms and schemes of delaying and subsequent connection of copper sulfides in the lignocellulosic matrix were investigated. The modification with a system of 2 components: cupric sulfate pentahydrate (CuSO4. 5H2O and sodium thiosulfate pentahydrate (Na2S2O3.5H2O for wood fibers is preferred. Optimal parameters were established for the process: 40 % of the reduction system; hydromodule M=1:6; and ratio of cupric sulfate pentahydrate:sodium thiosulfate pentahydrate = 1:2. The coordinative connection of copper ions with oxygen atoms of cellulose OH groups and aromatic nucleus in lignin macromolecule was observed.

  4. Chemical dissolution of sulfide minerals

    Science.gov (United States)

    Chao, T.T.; Sanzolone, R.F.

    1977-01-01

    Chemical dissolution treatments involving the use of aqua regia, 4 N HNO3, H2O2-ascorbic acid, oxalic acid, KClO3+HCl, and KClO3+HCl followed by 4 N HNO3 were applied to specimens of nine common sulfide minerals (galena, chalcopyrite, cinnabar, molybdenite, orpiment, pyrite, stibnite, sphalerite, and tetrahedrite) mixed individually with a clay loam soil. The resultant decrease in the total sulfur content of the mixture, as determined by using the Leco induction furnace, was used to evaluate the effectiveness of each chemical treatment. A combination of KClO3+HCl followed by 4 N HNO3 boiling gently for 20 min has been shown to be very effective in dissolving all the sulfide minerals. This treatment is recommended to dissolve metals residing in sulfide minerals admixed with secondary weathering products, as one step in a fractionation scheme whereby metals in soluble and adsorbed forms, and those associated with organic materials and secondary oxides, are first removed by other chemical extractants.

  5. Hydrogen sulfide in plants: from dissipation of excess sulfur to signaling molecule.

    Science.gov (United States)

    Calderwood, Alexander; Kopriva, Stanislav

    2014-09-15

    Sulfur is essential in all organisms for the synthesis of amino acids cysteine and methionine and as an active component of numerous co-factors and prosthetic groups. However, only plants, algae, fungi, and some prokaryotes are capable of using the abundant inorganic source of sulfur, sulfate. Plants take sulfate up, reduce it, and assimilate into organic compounds with cysteine being the first product of the pathway and a donor of reduced sulfur for synthesis of other S-containing compounds. Cysteine is formed in a reaction between sulfide, derived from reduction of sulfite and an activated amino acid acceptor, O-acetylserine. Sulfide is thus an important intermediate in sulfur metabolism, but numerous other functions in plants has been revealed. Hydrogen sulfide can serve as an alternative source of sulfur for plants, which may be significant in anaerobic conditions of waterlogged soils. On the other hand, emissions of hydrogen sulfide have been detected from many plant species. Since the amount of H2S discharged correlated with sulfate supply to the plants, the emissions were considered a mechanism for dissipation of excess sulfur. Significant hydrogen sulfide emissions were also observed in plants infected with pathogens, particularly with fungi. H2S thus seems to be part of the widely discussed sulfur-induced-resistance/sulfur-enhanced-defense. Recently, however, more evidence has emerged for a role for H2S in regulation and signaling. Sulfide stabilizes the cysteine synthase complex, increasing so the synthesis of its acceptor O-acetylserine. H2S has been implicating in regulation of plant stress response, particularly draught stress. There are more and more examples of processes regulated by H2S in plants being discovered, and hydrogen sulfide is emerging as an important signaling molecule, similar to its role in the animal and human world. How similar the functions, and homeostasis of H2S are in these diverse organisms, however, remains to be elucidated

  6. Greenhouse gas abatement cost curves of the residential heating market. A microeconomic approach

    International Nuclear Information System (INIS)

    Dieckhoener, Caroline; Hecking, Harald

    2012-01-01

    In this paper, we develop a microeconomic approach to deduce greenhouse gas abatement cost curves of the residential heating sector. By accounting for household behavior, we find that welfare-based abatement costs are generally higher than pure technical equipment costs. Our results are based on a microsimulation of private households' investment decision for heating systems until 2030. The households' investment behavior in the simulation is derived from a discrete choice estimation which allows investigating the welfare costs of different abatement policies in terms of the compensating variation and the excess burden. We simulate greenhouse gas abatements and welfare costs of carbon taxes and subsidies on heating system investments until 2030 to deduce abatement curves. Given utility maximizing households, our results suggest a carbon tax to be the welfare efficient policy. Assuming behavioral misperceptions instead, a subsidy on investments might have lower marginal greenhouse gas abatement costs than a carbon tax.

  7. Occurrence and abatement of volatile sulfur compounds during biogas production.

    Science.gov (United States)

    Andersson, Fräs Annika T; Karlsson, Anna; Svensson, Bo H; Ejlertsson, Jörgen

    2004-07-01

    Volatile sulfur compounds (VSCs) in biogas originating from a biogas production plant and from a municipal sewage water treatment plant were identified. Samples were taken at various stages of the biogas-producing process, including upgrading the gas to vehicle-fuel quality. Solid-phase microextraction was used for preconcentration of the VSCs, which were subsequently analyzed using gas chromatography in combination with mass spectrometry. Other volatile organic compounds present also were identified. The most commonly occurring VSCs in the biogas were hydrogen sulfide, carbonyl sulfide, methanethiol, dimethyl sulfide, and dimethyl disulfide, and hydrogen sulfide was not always the most abundant sulfur (S) compound. Besides VSCs, oxygenated organic compounds were commonly present (e.g., ketones, alcohols, and esters). The effect of adding iron chloride to the biogas reactor on the occurrence of VSCs also was investigated. It was found that additions of 500-g/m3 substrate gave an optimal removal of VSCs. Also, the use of a prefermentation step could reduce the amount of VSCs formed in the biogas process. Moreover, in the carbon dioxide scrubber used for upgrading the gas, VSCs were removed efficiently, leaving traces (ppbv levels). The scrubber also removed other organic compounds.

  8. Sulfide intrusion and detoxification in seagrasses ecosystems

    DEFF Research Database (Denmark)

    Hasler-Sheetal, Harald; Holmer, Marianne

    Sulfide intrusion in seagrasses represents a global threat to seagrasses and thereby an important parameter in resilience of seagrass ecosystems. In contrast seegrasses colonize and grow in hostile sediments, where they are constantly exposed to invasion of toxic gaseous sulfide. Remarkably little...... strategies of seagrasses to sustain sulfide intrusion. Using stable isotope tracing, scanning electron microscopy with x-ray analysis, tracing sulfur compounds combined with ecosystem parameters we found different spatial, intraspecific and interspecific strategies to cope with sulfidic sediments. 1...... not present in terrestrial plants at that level. Sulfide is not necessarily toxic but used as sulfur nutrition, presupposing healthy seagrass ecosystems that can support detoxification mechanisms. Presence or absence of those mechanisms determines susceptibility of seagrass ecosystems to sediment sulfide...

  9. Regulating a Polluting Oligopoly : Emission Tax or Voluntary Agreement ?

    OpenAIRE

    Mala David

    2003-01-01

    This paper compares, in a polluting oligopoly, an emission tax and a form of environmental policy called voluntary agreement (VA). There are here two ways of reducing pollution: output contraction and endof- pipe abatement. Given the imperfect competition, firms' reaction to the tax is sub-optimal. They reduce output excessively in order to raise the price and do not abate enough. The VA is a take-it-or-leaveit contract on abatement effort, offered to the firms with the threat of a tax. It ha...

  10. The UK market for gaseous emissions control equipment

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    2000-09-01

    The report analyses the changes in demand for gaseous emissions control equipment in the United Kingdom over the next 5 years. It discusses the factors affecting demand such as legislation reporting of environmental performance, and economic factors. It looks at environmental expenditure by UK industry. Markets are examined, for VOC abatement systems; thermal incinerators; adsorption equipment; catalytic oxidisers; absorption equipment; biological treatments; cryogenic equipment; SO{sub x} abatement equipment; wet FGD; wet dry FGD, dry scrubbers; NOx abatement systems; selective catalytic reduction; and selective non-catalytic reduction. Profiles are given of 16 leading suppliers.

  11. Climate modelling with endogenous technical change: Stochastic learning and optimal greenhouse gas abatement in the PAGE2002 model

    International Nuclear Information System (INIS)

    Alberth, Stephan; Hope, Chris

    2007-01-01

    This paper looks at the impact of ETC on the costs and benefits of different abatement strategies using a modified version of the PAGE2002 model. It was found that for most standard abatement paths there would be an initial 'learning investment' required that would substantially reduce the unit costs of CO 2 abatement as compared to a business as usual scenario. Furthermore, optimising an abatement program where ETC has been included leads to an increase in cost uncertainty during the period of widespread CO 2 abatements due to our lack of knowledge of the learning investments involved. Finally, the inclusion of ETC leads to a slightly deferred optimised abatement path followed by a rapid abatement program. Together, the results draw attention to the possibilities of 'uncovering uncertainty' through proactive abatements. 'Learning about learning' could become an important consideration for any plan to optimise future abatements

  12. Neutron diffraction investigations of the superionic conductors lithium sulfide and sodium sulfide

    International Nuclear Information System (INIS)

    Altorfer, F.

    1990-03-01

    Statics and dynamics of the superionic conductors lithium sulfide and sodium sulfide were investigated using the following experimental methods: elastic scattering on sodium sulfide powder in the temperature range 20 - 1000 C, elastic scattering on a lithium sulfide single crystal in the temperature range 20 - 700 C, inelastic scattering on a 7 Li 2 S single crystal at 10 K. 34 figs., 2 tabs., 10 refs

  13. Sustainable gasification–biochar systems? A case-study of rice-husk gasification in Cambodia, Part II: Field trial results, carbon abatement, economic assessment and conclusions

    International Nuclear Information System (INIS)

    Shackley, Simon; Carter, Sarah; Knowles, Tony; Middelink, Erik; Haefele, Stephan; Haszeldine, Stuart

    2012-01-01

    In part I we described the gasification technology and characterised the physio-chemical properties and environmental impacts of the rice husk char (RHC) by-product. In part II we present summary results from field trials using the RHC, and provide an estimate of the carbon abatement and economic evaluation of the system. Statistically significant yield increases are demonstrated for RHC addition in irrigated rice cultivation (33% increase in paddy rice yield for a 41.5 t (dry weight) RHC application per hectare). The carbon abatement from the RHC addition is approximately 0.42 t CO 2 t −1 rice husk; including energy generation from gasification this increases to ca. 0.86 tCO 2 t −1 . Assuming a carbon value of $5 t CO 2 t −1 , and agronomic value of $3 t −1 RHC based on the field trials, the economic value of the RHC varies from $9 t −1 (including only recalcitrant carbon) to $15 t −1 (including avoided emissions from energy production). We summarise results from parts I and II, concluding that the gasification–biochar system meets many of the criteria of sustainability, but requires better waste water management and more field trials to demonstrate repeatable agronomic efficacy of RHC application. - Highlights: ► Field trials show statistically significant rice yield increases using rice husk char (RHC). ► Carbon abatement of 0.42 t CO 2 t −1 rice husk from RHC production. ► Bioenergy generation via gasification gives carbon abatement of 0.44 t CO 2 t −1 husk. ► Total carbon abatement is therefore ca. 0.86 t CO 2 t −1 husk. ► Agronomic value from trials is $3 t −1 char; assuming $5 CO 2 t −1 , the total value of RHC is $9–$15 t −1 .

  14. Potential of electric discharge plasma methods in abatement of volatile organic compounds originating from the food industry.

    Science.gov (United States)

    Preis, S; Klauson, D; Gregor, A

    2013-01-15

    Increased volatile organic compounds emissions and commensurate tightening of applicable legislation mean that the development and application of effective, cost-efficient abatement methods are areas of growing concern. This paper reviews the last two decades' publications on organic vapour emissions from food processing, their sources, impacts and treatment methods. An overview of the latest developments in conventional air treatment methods is presented, followed by the main focus of the paper, non-thermal plasma technology. The results of the review suggest that non-thermal plasma technology, in its pulsed corona discharge configuration, is an emerging treatment method with potential for low-cost, effective abatement of a wide spectrum of organic air pollutants. It is found that the combination of plasma treatment with catalysis is a development trend that demonstrates considerable potential. The as yet relatively small number of plasma treatment applications is considered to be due to the novelty of pulsed electric discharge techniques and a lack of reliable pulse generators and reactors. Other issues acting as barriers to widespread adoption of the technique include the possible formation of stable oxidation by-products, residual ozone and nitrogen oxides, and sensitivity towards air humidity. Copyright © 2012 Elsevier Ltd. All rights reserved.

  15. Coupled Climate-Economy-Biosphere (CoCEB) model - Part 1: Abatement share and investment in low-carbon technologies

    Science.gov (United States)

    Ogutu, K. B. Z.; D'Andrea, F.; Ghil, M.; Nyandwi, C.; Manene, M. M.; Muthama, J. N.

    2015-04-01

    The Coupled Climate-Economy-Biosphere (CoCEB) model described herein takes an integrated assessment approach to simulating global change. By using an endogenous economic growth module with physical and human capital accumulation, this paper considers the sustainability of economic growth, as economic activity intensifies greenhouse gas emissions that in turn cause economic damage due to climate change. Different types of fossil fuels and different technologies produce different volumes of carbon dioxide in combustion. The shares of different fuels and their future evolution are not known. We assume that the dynamics of hydrocarbon-based energy share and their replacement with renewable energy sources in the global energy balance can be modeled into the 21st century by use of logistic functions. Various climate change mitigation policy measures are considered. While many integrated assessment models treat abatement costs merely as an unproductive loss of income, we consider abatement activities also as an investment in overall energy efficiency of the economy and decrease of overall carbon intensity of the energy system. The paper shows that these efforts help to reduce the volume of industrial carbon dioxide emissions, lower temperature deviations, and lead to positive effects in economic growth.

  16. Sulfidation behavior of Fe20Cr alloys

    International Nuclear Information System (INIS)

    Pillis, Marina Fuser

    2001-01-01

    Alloys for use in high temperature environments rely on the formation of an oxide layer for their protection. Normally, these protective oxides are Cr 2 O 3 , Al 2 O 3 and, some times, SiO 2 . Many industrial gaseous environments contain sulfur. Sulfides, formed in the presence of sulfur are thermodynamically less stable, have lower melting points and deviate much more stoichiometrically, compared to the corresponding oxides. The mechanism of sulfidation of various metals is as yet not clear, in spite of the concerted efforts during the last decade. To help address this situation, the sulfidation behavior of Fe20Cr has been studied as a function of compositional modifications and surface state of the alloy. The alloys Fe20Cr, Fe20Cr0.7Y, Fe20Cr5Al and Fe20Cr5Al0.6Y were prepared and three sets of sulfidation tests were carried out. In the first set, the alloys were sulfidized at 700 deg C and 800 deg C for 10h. In the second set, the alloys were pre-oxidized at 1000 deg C and then sulfidized at 800 deg C for up to 45h. In the third set of tests, the initial stages of sulfidation of the alloys was studied. All the tests were carried out in a thermobalance, in flowing H 2 /2%H 2 S, and the sulfidation behavior determined as mass change per unit area. Scanning electron microscopy coupled to energy dispersive spectroscopy and X-ray diffraction analysis were used to characterize the reaction products. The addition of Y and Al increased sulfidation resistance of Fe20Cr. The addition of Y altered the species that diffused predominantly during sulfide growth. It changed from predominant cationic diffusion to predominant anionic diffusion. The addition of Al caused an even greater increase in sulfidation resistance of Fe20Cr, with the parabolic rate constant decreasing by three orders of magnitude. Y addition to the FeCrAl alloy did not cause any appreciable alteration in sulfidation resistance. Pre-oxidation of the FeCrAl and FeCrAlY alloys resulted in an extended

  17. The public health relevance of air pollution abatement.

    Science.gov (United States)

    Künzli, N

    2002-07-01

    Assuming a causal relationship between current levels of air pollution and morbidity/mortality, it is crucial to estimate the public health relevance of the problem. The derivation of air pollution attributable cases faces inherent uncertainties and requires influential assumptions. Based on the results of the trinational impact assessment study of Austria, France, and Switzerland, where prudent estimates of the air pollution attributable cases (mortality, chronic bronchitis incidence, hospital admissions, acute bronchitis among children, restricted activity days, asthma attacks) have been made, influential uncertainties are quantified in this review. The public health impact of smoking, environmental tobacco smoke, and air pollution on the prevalence of chronic cough/phlegm are outlined. Despite all methodological caveats, impact assessment studies clearly suggest that public health largely benefits from better air quality. The studies are selective underestimates as they are strongly driven by mortality, but do not include full quantification of the impact on morbidity and their consequences on quality of life among the diseased and the caregivers. Air pollution abatement strategies are usually political in nature, targeting at polities, regulation and technology in mobile or stationary sources rather than at individuals. It is of note that key clean air strategies converge into abatement of climate change. In general, energy consumption is very closely related to both air pollution and greenhouse gases. The dominant causes of both problems are the excessive and inefficient combustion of fossil fuel. Thus, for many policy options, the benefit of air pollution abatement will go far beyond what prudent health-impact assessments may derive. From a climate change and air pollution perspective, improved energy efficiency and a strong and decisive departure from the "fossil fuel" combustion society is a science-based must. Health professionals must raise their voices

  18. How costly is mitigation of non-CO{sub 2} greenhouse gas emissions from agriculture? A meta-analysis

    Energy Technology Data Exchange (ETDEWEB)

    Vermont, Bruno; De Cara, Stephane [INRA, UMR 210 Economie Publique INRA-AgroParisTech, Thiverval-Grignon (France)

    2010-05-15

    This text reviews the assessments of marginal abatement costs of methane and nitrous oxide emissions from agriculture. We use agricultural emissions and the corresponding prices collected from 21 studies that have assessed abatement potentials and costs using various modeling approaches and assumptions. We first highlight the implications of the modeling approach for marginal abatement costs. Harmonized abatement rates for three emission prices (10, 20 and 50 EUR{sub 2005}/tCO{sub 2}eq) are regressed on variables that reflect various modeling assumptions and study characteristics. In a second step, the emission price is introduced as an explanatory variable. When controlling for a few key characteristics of the studies, the models explain an important share of the observed variability in abatement rates. The type of modeling approach is found to have a significant effect. In particular, we find that equilibrium models lead to higher abatement rates for a given price. The flexibility in nitrogen use and its effect on crop yields also plays a significant role in lowering marginal abatement costs. The results of the second step indicate that the price elasticity of the abatement rate is about 0.6. This estimate is found to be robust to several specifications and consistent with previous assessments covering other economic sectors. (author)

  19. Evaluation of methods for monitoring air concentrations of hydrogen sulfide

    Directory of Open Access Journals (Sweden)

    Katarzyna Janoszka

    2013-06-01

    Full Text Available The development of different branches of industry and a growing fossil fuels mining results in a considerable emission of by-products. Major air pollutants are: CO, CO₂, SO₂, SO₃, H₂S, nitrogen oxides, as well as compounds of an organic origin. The main aspects of this paper is to review and evaluate methods used for monitoring of hydrogen sulfide in the air. Different instrumental techniques were discussed, electrochemical, chromatographic and spectrophotometric (wet and dry, to select the method most suitable for monitoring low levels of hydrogen sulfide, close to its odor threshold. Based on the literature review the method for H₂S determination in the air, involving absorption in aqueous zinc acetate and reaction with N,N-dimethylo-p-phenylodiamine and FeCl₃, has been selected and preliminary verified. The adopted method allows for routine measurements of low concentration of hydrogen sulfide, close to its odor threshold in workplaces and ambient air. Med Pr 2013;64(3:449–454

  20. Carbon dioxide abatement in an empirical model of the Indian economy: an integration of micro and macro analysis

    International Nuclear Information System (INIS)

    Gupta, S.

    1995-01-01

    Global warming and associated climate change are the likely results of an enhanced greenhouse effect due to excessive emission of greenhouse gases. Carbon dioxide (CO 2 ) is the largest contributor to the greenhouse effect. The costs of stabilising or reducing CO 2 emissions are estimated by two types of models. Macro models based on aggregate macroeconomic relationships, study the macroeconomic impacts of and responses to different policies. These overestimate costs as technological responses are not adequately modelled. Micro models contain the necessary technical information to assess the abatement potential, but exclude indirect costs. In this study, a methodology for integrating the two approaches for developing countries is proposed and illustrated for India. The problems associated with modelling developing economies are recognized in the integrated model proposed. (Author)

  1. Costs of CO2 abatement in Egypt using both bottom-up and top-down approaches

    International Nuclear Information System (INIS)

    El Mahgary, Y.; Ibrahim, A.-F.; Shama, M.A.-F.

    1994-01-01

    Within the frame of UNEP's project on the Methodologies of Determining the Costs of Abatement of GHG emissions, a case study on Egypt was undertaken by the Technical Research Centre of Finland (VTT) in cooperation with the Egyptian Environment Affairs Authority (EEAA), together with an expert team from different Egyptian organizations. Both bottom-up and top-down approaches were used. Several measures/technologies, including energy conservation, fuel switching, use of renewable energy and material replacement, were considered to decrease CO 2 emissions. It was found that most of the measures were cost-effective, as a considerable potential for energy conservation exists in Egypt. The impact of energy conservation measures on the economy of the country was found to be positive using a macroeconomic model. (author)

  2. Kinetic studies of sulfide mineral oxidation and xanthate adsorption

    Science.gov (United States)

    Mendiratta, Neeraj K.

    2000-10-01

    Sulfide minerals are a major source of metals; however, certain sulfide minerals, such as pyrite and pyrrhotite, are less desirable. Froth flotation is a commonly used separation technique, which requires the use of several reagents to float and depress different sulfide minerals. Xanthate, a thiol collector, has gained immense usage in sulfide minerals flotation. However, some sulfides are naturally hydrophobic and may float without a collector. Iron sulfides, such as pyrite and pyrrhotite, are few of the most abundant minerals, yet economically insignificant. Their existence with other sulfide minerals leads to an inefficient separation process as well as environmental problems, such as acid mine drainage during mining and processing and SO 2 emissions during smelting process. A part of the present study is focused on understanding their behavior, which leads to undesired flotation and difficulties in separation. The major reasons for the undesired flotation are attributed to the collectorless hydrophobicity and the activation with heavy metal ions. To better understand the collectorless hydrophobicity of pyrite, Electrochemical Impedance Spectroscopy (EIS) of freshly fractured pyrite electrodes was used to study the oxidation and reduction of the mineral. The EIS results showed that the rate of reaction increases with oxidation and reduction. At moderate oxidizing potentials, the rate of reaction is too slow to replenish hydrophilic iron species leaving hydrophobic sulfur species on the surface. However, at higher potentials, iron species are replaced fast enough to depress its flotation. Effects of pH and polishing were also explored using EIS. Besides collectorless hydrophobicity, the activation of pyrrhotite with nickel ions and interaction with xanthate ions makes the separation more difficult. DETA and SO2 are commonly used as pyrrhotite depressants; however, the mechanism is not very well understood. Contact angle measurements, cyclic voltammetry and Tafel

  3. Human health cost of hydrogen sulfide air pollution from an oil and gas Field

    Directory of Open Access Journals (Sweden)

    Dinara Kenessary

    2017-06-01

    The reduction of hydrogen sulfide emissions into the air is recommended, as well as successive constant ambient air monitoring in future. Economic damage evaluation should be made mandatory, on a legal basis, whenever an industrial facility operation results in associated air pollution.

  4. Sulfide toxicity kinetics of a uasb reactor

    Directory of Open Access Journals (Sweden)

    D. R. Paula Jr.

    2009-12-01

    Full Text Available The effect of sulfide toxicity on kinetic parameters of anaerobic organic matter removal in a UASB (up-flow anaerobic sludge blanket reactor is presented. Two lab-scale UASB reactors (10.5 L were operated continuously during 12 months. The reactors were fed with synthetic wastes prepared daily using glucose, ammonium acetate, methanol and nutrient solution. One of the reactors also received increasing concentrations of sodium sulfide. For both reactors, the flow rate of 16 L.d-1 was held constant throughout the experiment, corresponding to a hydraulic retention time of 15.6 hours. The classic model for non-competitive sulfide inhibition was applied to the experimental data for determining the overall kinetic parameter of specific substrate utilization (q and the sulfide inhibition coefficient (Ki. The application of the kinetic parameters determined allows prediction of methanogenesis inhibition and thus the adoption of operating parameters to minimize sulfide toxicity in UASB reactors.

  5. Adolescents Exiting Homelessness over Two Years: The Risk Amplification and Abatement Model

    Science.gov (United States)

    Milburn, Norweeta G.; Rice, Eric; Rotheram-Borus, Mary Jane; Mallett, Shelley; Rosenthal, Doreen; Batterham, Phillip; May, Susanne J.; Witkin, Andrea; Duan, Naihua

    2009-01-01

    The Risk Amplification and Abatement Model (RAAM) demonstrates that negative contact with socializing agents amplify risk, while positive contact abates risk for homeless adolescents. To test this model, the likelihood of exiting homelessness and returning to familial housing at 2 years and stably exiting over time are examined with longitudinal…

  6. 75 FR 39820 - Procedures for Abatement of Highway Traffic Noise and Construction Noise

    Science.gov (United States)

    2010-07-13

    ...-2008-0114] RIN 2125-AF26 Procedures for Abatement of Highway Traffic Noise and Construction Noise... the Federal regulations on the Procedures for Abatement of Highway Traffic Noise and Construction Noise. The final rule clarifies and adds definitions, the applicability of this regulation, certain...

  7. PM sources in a highly industrialised area in the process of implementing PM abatement technology. Quantification and evolution.

    Science.gov (United States)

    Cruz Minguillón, María; Querol, Xavier; Alastuey, Andrés; Monfort, Eliseo; Vicente Miró, José

    2007-10-01

    Principal component analysis (PCA) coupled with a multilinear regression analysis (MLRA) was applied to PM(10) speciation data series (2002-2005) from four sampling sites in a highly industrialised area (ceramic production) in the process of implementing emission abatement technology. Five common factors with similar chemical profiles were identified at all the sites: mineral, regional background (influenced by the industrial estate located on the coast: an oil refinery and a power plant), sea spray, industrial 1 (manufacture and use of glaze components, including frit fusion) and road traffic. The contribution of the regional background differs slightly from site to site. The mineral factor, attributed to the sum of several sources (mainly the ceramic industry, but also with minor contributions from soil resuspension and African dust outbreaks) contributes between 9 and 11 microg m(-3) at all the sites. Source industrial 1 entails an increase in PM(10) levels between 4 and 5 microg m(-3) at the urban sites and 2 microg m(-3) at the suburban background site. However, after 2004, this source contributed less than 2 microg m(-3) at most sites, whereas the remaining sources did not show an upward or downward trend along the study period. This gradual decrease in the contribution of source industrial 1 coincides with the implementation of PM abatement technology in the frit fusion kilns of the area. This relationship enables us to assess the efficiency of the implementation of environmental technologies in terms of their impact on air quality.

  8. A bottom-up method to develop pollution abatement cost curves for coal-fired utility boilers

    International Nuclear Information System (INIS)

    Vijay, Samudra; DeCarolis, Joseph F.; Srivastava, Ravi K.

    2010-01-01

    This paper illustrates a new method to create supply curves for pollution abatement using boiler-level data that explicitly accounts for technology cost and performance. The Coal Utility Environmental Cost (CUECost) model is used to estimate retrofit costs for five different NO x control configurations on a large subset of the existing coal-fired, utility-owned boilers in the US. The resultant data are used to create technology-specific marginal abatement cost curves (MACCs) and also serve as input to an integer linear program, which minimizes system-wide control costs by finding the optimal distribution of NO x controls across the modeled boilers under an emission constraint. The result is a single optimized MACC that accounts for detailed, boiler-specific information related to NO x retrofits. Because the resultant MACCs do not take into account regional differences in air-quality standards or pre-existing NO x controls, the results should not be interpreted as a policy prescription. The general method as well as NO x -specific results presented here should be of significant value to modelers and policy analysts who must estimate the costs of pollution reduction.

  9. Regional and sectoral marginal abatement cost curves for NOx incorporating controls, renewable electricity, energy efficiency and fuel switching

    Science.gov (United States)

    A marginal abatement cost curve (MACC) traces out the relationship between the quantity of pollution abated and the marginal cost of abating each additional unit. In the context of air quality management, MACCs typically are developed by sorting end-of-pipe controls by their resp...

  10. Human health cost of hydrogen sulfide air pollution from an oil and gas Field.

    Science.gov (United States)

    Kenessary, Dinara; Kenessary, Almas; Kenessariyev, Ussen Ismailovich; Juszkiewicz, Konrad; Amrin, Meiram Kazievich; Erzhanova, Aya Eralovna

    2017-06-08

    Introduction and objective. The Karachaganak oil and gas condensate field (KOGCF), one of the largest in the world, located in the Republic of Kazakhstan (RoK) in Central Asia, is surrounded by 10 settlements with a total population of 9,000 people. Approximately73% of this population constantly mention a specific odour of rotten eggs in the air, typical for hydrogen sulfide (H2S) emissions, and the occurrence of low-level concentrations of hydrogen sulfide around certain industrial installations (esp. oil refineries) is a well known fact. Therefore, this study aimed at determining the impact on human health and the economic damage to the country due to H2S emissions. Materials and method. Dose-response dependency between H2S concentrations in the air and cardiovascular morbidity using multiple regression analysis was applied. Economic damage from morbidity was derived with a newly-developed method, with Kazakhstani peculiarities taken into account. Results.Hydrogen sulfide air pollution due to the KOGCF activity costs the state almost $60,000 per year. Moreover, this is the reason for a more than 40% rise incardiovascular morbidity in the region. Conclusion. The reduction of hydrogen sulfide emissions into the air is recommended, as well as successive constant ambient air monitoring in future. Economic damage evaluation should be made mandatory, on a legal basis, whenever an industrial facility operation results in associated air pollution.

  11. Sulfidation/oxidation resistant alloys

    International Nuclear Information System (INIS)

    Smith, G.D.; Tassen, C.S.

    1989-01-01

    The patent describes a nickel-base, high chromium alloy. It is characterized by excellent resistance to sulfidation and oxidation at elevated temperatures as high as 2000 degrees F. (1093 degrees C.) and higher, a stress-rupture life of about 200 hours or more at a temperature at least as high as 1800 degrees F. (990:0083 degrees C.) and under a stress of 2000 psi, good tensile strength and good ductility both at room and elevated temperature. The alloy consists essentially of about 27 to 35% chromium, about 2.5 to 5% aluminum, about 2.5 to about 6% iron, 0.5 to 2.5% columbium, up to 0.1% carbon, up to 1% each of titanium and zirconium, up to 0.05% cerium, up to 0.05% yttrium, up to 1% silicon, up to 1% manganese, and the balance nickel

  12. The economic impacts of emission reduction policies

    Energy Technology Data Exchange (ETDEWEB)

    Hanson, D.A.

    1992-07-01

    Environmental expenditures, or environmental tax revenues, e.g., carbon taxes are potentially significant components of the US macroeconomy. This paper presents a simple model of the role of environmental abatement expenditures and/or emission taxes from the viewpoint of economic efficiency, welfare and potential macroeconomic effects.

  13. The economic impacts of emission reduction policies

    Energy Technology Data Exchange (ETDEWEB)

    Hanson, D.A.

    1992-01-01

    Environmental expenditures, or environmental tax revenues, e.g., carbon taxes are potentially significant components of the US macroeconomy. This paper presents a simple model of the role of environmental abatement expenditures and/or emission taxes from the viewpoint of economic efficiency, welfare and potential macroeconomic effects.

  14. Iron-sulfide crystals in probe deposits

    DEFF Research Database (Denmark)

    Laursen, Karin; Frandsen, Flemming

    1998-01-01

    Iron-sulfides were observed in deposits collected on a probe inserted at the top of the furnace of a coal-fired power station in Denmark. The chemical composition of the iron-sulfides is equivalent to pyrrhotite (FeS). The pyrrhotites are present as crystals and, based on the shape of the crystals......: (1) impact of low viscous droplets of iron sulfide; and (2) sulfur diffusion. Previous research on the influence of pyrite on slagging focused on the decomposition of pyrite into pyrrhotite and especially on the oxidation stage of this product during impact on the heat transfer surfaces...

  15. Microbial control of hydrogen sulfide production

    Energy Technology Data Exchange (ETDEWEB)

    Montgomery, A.D.; Bhupathiraju, V.K.; Wofford, N.; McInerney, M.J. [Univ. of Oklahoma, Tulsa, OK (United States)] [and others

    1995-12-31

    A sulfide-resistant strain of Thiobacillus denitrificans, strain F, prevented the accumulation of sulfide by Desulfovibrio desulfuricans when both organisms were grown in liquid medium. The wild-type strain of T. denitrificans did not prevent the accumulation of sulfide produced by D. desulfuricans. Strain F also prevented the accumulation of sulfide by a mixed population of sulfate-reducing bacteria enriched from an oil field brine. Fermentation balances showed that strain F stoichiometrically oxidized the sulfide produced by D. desulfuricans and the oil field brine enrichment to sulfate. The ability of a strain F to control sulfide production in an experimental system of cores and formation water from the Redfield, Iowa, natural gas storage facility was also investigated. A stable, sulfide-producing biofilm was established in two separate core systems, one of which was inoculated with strain F while the other core system (control) was treated in an identical manner, but was not inoculated with strain F. When formation water with 10 mM acetate and 5 mM nitrate was injected into both core systems, the effluent sulfide concentrations in the control core system ranged from 200 to 460 {mu}M. In the test core system inoculated with strain F, the effluent sulfide concentrations were lower, ranging from 70 to 110 {mu}M. In order to determine whether strain F could control sulfide production under optimal conditions for sulfate-reducing bacteria, the electron donor was changed to lactate and inorganic nutrients (nitrogen and phosphate sources) were added to the formation water. When nutrient-supplemented formation water with 3.1 mM lactate and 10 mM nitrate was used, the effluent sulfide concentrations of the control core system initially increased to about 3,800 {mu}M, and then decreased to about 1,100 {mu}M after 5 weeks. However, in the test core system inoculated with strain F, the effluent sulfide concentrations were much lower, 160 to 330 {mu}M.

  16. Sulfide Intrusion and Detoxification in the Seagrass Zostera marina

    DEFF Research Database (Denmark)

    Hasler-Sheetal, Harald; Holmer, Marianne

    2015-01-01

    Gaseous sulfide intrusion into seagrasses growing in sulfidic sediments causes little or no harm to the plant, indicating the presence of an unknown sulfide tolerance or detoxification mechanism. We assessed such mechanism in the seagrass Zostera marina in the laboratory and in the field...... as sulfate throughout the plant. We conclude that avoidance of sulfide exposure by reoxidation of sulfide in the rhizosphere or aerenchyma and tolerance of sulfide intrusion by incorporation of sulfur in the plant are likely major survival strategies of seagrasses in sulfidic sediments....

  17. Reduced Insecticide Susceptibility in Aedes vexans (Diptera: Culicidae) Where Agricultural Pest Management Overlaps With Mosquito Abatement.

    Science.gov (United States)

    Dunbar, Mike W; Bachmann, Amanda; Varenhorst, Adam J

    2018-05-04

    Mosquito abatement programs in Midwestern communities frequently exist within landscapes dominated by agriculture. Although separately managed, both agricultural pests and mosquitoes are targeted by similar classes of insecticides. As a result, there is the potential for unintended insecticide exposure to mosquito populations from agricultural pest management. To determine the impact that agricultural management practices have on mosquito insecticide susceptibility we compared the mortality of Aedes vexans (Meigen; Diptera: Culicidae) between populations sampled from locations with and without mosquito abatement in South Dakota, a region dominated by agricultural production. Collection locations were either within towns with mosquito abatement programs (n = 2; Brookings and Sioux Falls, SD) or located > 16 km from towns with mosquito abatement programs (n = 2; areas near Harrold and Willow Lake, SD). WHO bioassays were used to test susceptibly of adults to differing insecticide classes relative to their respective controls; 1) an organochlorine (dieldrin 4%), 2) an organophosphate (malathion 5%), and 3) a pyrethroid (lambda-cyhalothrin 0.05%). Corrected mortality did not significantly differ between locations with or without abatement; however, when locations were analized by proportion of developed land within the surrounding landscape pyrethroid mortality was significantly lower where crop production dominated the surrounding landscape and mosquito abatement was present. These data suggest that agricultural pest management may incidentally contribute to reduced mosquito susceptibility where overlap between agricultural pest management and mosquito abatement exists. Decoupling insecticide classes used by both agricultural and public health pest management programs may be necessary to ensure continued efficacy of pest management tools.

  18. Abatement vs. treatment for efficient diffuse source water pollution management in terrestrial-marine systems.

    Science.gov (United States)

    Roebeling, P C; Cunha, M C; Arroja, L; van Grieken, M E

    2015-01-01

    Marine ecosystems are affected by water pollution originating from coastal catchments. The delivery of water pollutants can be reduced through water pollution abatement as well as water pollution treatment. Hence, sustainable economic development of coastal regions requires balancing of the marginal costs from water pollution abatement and/or treatment and the associated marginal benefits from marine resource appreciation. Water pollution delivery reduction costs are, however, not equal across abatement and treatment options. In this paper, an optimal control approach is developed and applied to explore welfare maximizing rates of water pollution abatement and/or treatment for efficient diffuse source water pollution management in terrestrial-marine systems. For the case of diffuse source dissolved inorganic nitrogen water pollution in the Tully-Murray region, Queensland, Australia, (agricultural) water pollution abatement cost, (wetland) water pollution treatment cost and marine benefit functions are determined to explore welfare maximizing rates of water pollution abatement and/or treatment. Considering partial (wetland) treatment costs and positive water quality improvement benefits, results show that welfare gains can be obtained, primarily, through diffuse source water pollution abatement (improved agricultural management practices) and, to a minor extent, through diffuse source water pollution treatment (wetland restoration).

  19. Changes in Dimethyl Sulfide Oceanic Distribution due to Climate Change

    Energy Technology Data Exchange (ETDEWEB)

    Cameron-Smith, P; Elliott, S; Maltrud, M; Erickson, D; Wingenter, O

    2011-02-16

    Dimethyl sulfide (DMS) is one of the major precursors for aerosols and cloud condensation nuclei in the marine boundary layer over much of the remote ocean. Here they report on coupled climate simulations with a state-of-the-art global ocean biogeochemical model for DMS distribution and fluxes using present-day and future atmospheric CO{sub 2} concentrations. They find changes in zonal averaged DMS flux to the atmosphere of over 150% in the Southern Ocean. This is due to concurrent sea ice changes and ocean ecosystem composition shifts caused by changes in temperature, mixing, nutrient, and light regimes. The largest changes occur in a region already sensitive to climate change, so any resultant local CLAW/Gaia feedback of DMS on clouds, and thus radiative forcing, will be particularly important. A comparison of these results to prior studies shows that increasing model complexity is associted with reduced DMS emissions at the equator and increased emissions at high latitudes.

  20. Modelling agro-forestry scenarios for ammonia abatement in the landscape

    International Nuclear Information System (INIS)

    Bealey, W J; Braban, C F; Famulari, D; Theobald, M R; Reis, S; Sutton, M A; Loubet, B; Reay, D S

    2014-01-01

    Ammonia emissions from livestock production can have negative impacts on nearby protected sites and ecosystems that are sensitive to eutrophication and acidification. Trees are effective scavengers of both gaseous and particulate pollutants from the atmosphere making tree belts potentially effective landscape features to support strategies aiming to reduce ammonia impacts. This research used the MODDAS-THETIS a coupled turbulence and deposition turbulence model, to examine the relationships between tree canopy structure and ammonia capture for three source types—animal housing, slurry lagoon, and livestock under a tree canopy. By altering the canopy length, leaf area index, leaf area density, and height of the canopy in the model the capture efficiencies varied substantially. A maximum of 27% of the emitted ammonia was captured by tree canopy for the animal housing source, for the slurry lagoon the maximum was 19%, while the livestock under trees attained a maximum of 60% recapture. Using agro-forestry systems of differing tree structures near ‘hot spots’ of ammonia in the landscape could provide an effective abatement option for the livestock industry that complements existing source reduction measures. (paper)

  1. Modeling for waste management associated with environmental-impact abatement under uncertainty.

    Science.gov (United States)

    Li, P; Li, Y P; Huang, G H; Zhang, J L

    2015-04-01

    Municipal solid waste (MSW) treatment can generate significant amounts of pollutants, and thus pose a risk on human health. Besides, in MSW management, various uncertainties exist in the related costs, impact factors, and objectives, which can affect the optimization processes and the decision schemes generated. In this study, a life cycle assessment-based interval-parameter programming (LCA-IPP) method is developed for MSW management associated with environmental-impact abatement under uncertainty. The LCA-IPP can effectively examine the environmental consequences based on a number of environmental impact categories (i.e., greenhouse gas equivalent, acid gas emissions, and respiratory inorganics), through analyzing each life cycle stage and/or major contributing process related to various MSW management activities. It can also tackle uncertainties existed in the related costs, impact factors, and objectives and expressed as interval numbers. Then, the LCA-IPP method is applied to MSW management for the City of Beijing, the capital of China, where energy consumptions and six environmental parameters [i.e., CO2, CO, CH4, NOX, SO2, inhalable particle (PM10)] are used as systematic tool to quantify environmental releases in entire life cycle stage of waste collection, transportation, treatment, and disposal of. Results associated with system cost, environmental impact, and the related policy implication are generated and analyzed. Results can help identify desired alternatives for managing MSW flows, which has advantages in providing compromised schemes under an integrated consideration of economic efficiency and environmental impact under uncertainty.

  2. Top-down or bottom-up modelling. An application to CO2 abatement

    International Nuclear Information System (INIS)

    Laroui, F.; Van Leeuwen, M.J.

    1995-06-01

    In four articles a comparison is made of bottom-up, or engineers'' models, and top-down models, which comprise macro-econometric models, computable general equilibrium models and also models in the system dynamics tradition. In the first article the history of economic modelling is outlined. In the second article the multi-sector macro-economic Computable General Equilibrium model for the Netherlands is described. It can be used to study the long-term effects of fiscal policy measures on economic and environmental indicators, in particular the effects on the level of CO2-emissions. The aim of article 3 is to describe the structure of the electricity supply industry in the UK and how it can be represented in a bottom-up sub-model within a more general E3 sectoral model of the UK economy. The objective of the last paper (4) is mainly a methodological discussion about integrating top-down and bottom-up models which can be used to assess CO2 abatement policies impacts on economic activity

  3. A meta-analysis of the greenhouse gas abatement of bioenergy factoring in land use changes.

    Science.gov (United States)

    El Akkari, M; Réchauchère, O; Bispo, A; Gabrielle, B; Makowski, D

    2018-06-04

    Non-food biomass production is developing rapidly to fuel the bioenergy sector and substitute dwindling fossil resources, which is likely to impact land-use patterns worldwide. Recent publications attempting to factor this effect into the climate mitigation potential of bioenergy chains have come to widely variable conclusions depending on their scope, data sources or methodology. Here, we conducted a first of its kind, systematic review of scientific literature on this topic and derived quantitative trends through a meta-analysis. We showed that second-generation biofuels and bioelectricity have a larger greenhouse gas (GHG) abatement potential than first generation biofuels, and stand the best chances (with a 80 to 90% probability range) of achieving a 50% reduction compared to fossil fuels. Conversely, directly converting forest ecosystems to produce bioenergy feedstock appeared as the worst-case scenario, systematically leading to negative GHG savings. On the other hand, converting grassland appeared to be a better option and entailed a 60% chance of halving GHG emissions compared to fossil energy sources. Since most climate mitigation scenarios assume still larger savings, it is critical to gain better insight into land-use change effects to provide a more realistic estimate of the mitigation potential associated with bioenergy.

  4. External costs from electricity generation of China up to 2030 in energy and abatement scenarios

    International Nuclear Information System (INIS)

    Zhang, Qingyu; Weili, Tian; Yumei, Wei; Yingxu, Chen

    2007-01-01

    This paper presents estimated external costs of electricity generation in China under different scenarios of long-term energy and environmental policies. Long-range Energy Alternatives Planning (LEAP) software is used to develop a simple model of electricity demand and to estimate gross electricity generation in China up to 2030 under these scenarios. Because external costs for unit of electricity from fossil fuel will vary in different government regulation periods, airborne pollutant external costs of SO 2 , NO x , PM 10 , and CO 2 from fired power plants are then estimated based on emission inventories and environmental cost for unit of pollutants, while external costs of non-fossil power generation are evaluated with external cost for unit of electricity. The developed model is run to study the impact of different energy efficiency and environmental abatement policy initiatives that would reduce total energy requirement and also reduce external costs of electricity generation. It is shown that external costs of electricity generation may reduce 24-55% with three energy policies scenarios and may further reduce by 20.9-26.7% with two environmental policies scenarios. The total reduction of external costs may reach 58.2%. (author)

  5. Pathways of low carbon transition at the lowest cost. Pathways of low carbon transition in France at the lowest cost - Dynamics and average abatement costs (MACC)

    International Nuclear Information System (INIS)

    Perrissin Fabert, Baptiste; Foussard, Alexis

    2016-11-01

    The objective to divide greenhouse gas emissions in France by a factor four by 2050 implies the mobilisation at the lowest cost of the whole set of known sources of reduction of emissions in all economic sectors. In this context, this report is based on a methodology (D-CAM in French for dynamics - average abatement costs, MACC in English for Medium Abatement Cost Curves) which relies on a theoretical business-as-usual scenario, on a database on the potential, rate of development, and cost of mobilizable sources, and on a dynamic model of cost minimisation. The MACC tool is used to explore, for each sector, scenarios of de-carbonation which allow objectives of reduction of greenhouse gas emissions to be reached at different time horizons. An aggregated approach of this tool modifies the distribution of efforts of emission reduction between sectors with respect to a sector-based approach. Thus, a macro-assessment of low carbon transition does not reveal any obvious over-cost with respect to the business-as-usual scenario. A second document is a Power Point presentation which contains the same information, curves and graphs

  6. Directed technical change and the adoption of CO{sub 2} abatement technology. The case of CO{sub 2} capture and storage

    Energy Technology Data Exchange (ETDEWEB)

    Otto, Vincent M.; Reilly, John [Joint Program on the Science and Policy of Global Change, Massachusetts Institute of Technology, 77 Massachusetts Avenue, Cambridge, MA 02139 (United States)

    2008-11-15

    This paper studies the cost-effectiveness of combining traditional environmental policy, such as CO{sub 2}-trading schemes, and technology policy that has aims of reducing the cost and speeding the adoption of CO{sub 2} abatement technology. For this purpose, we develop a dynamic general equilibrium model that captures empirical links between CO{sub 2} emissions associated with energy use, directed technical change and the economy. We specify CO{sub 2} capture and storage (CCS) as a discrete CO{sub 2} abatement technology. We find that combining CO{sub 2}-trading schemes with an adoption subsidy is the most effective instrument to induce adoption of the CCS technology. Such a subsidy directly improves the competitiveness of the CCS technology by compensating for its markup over the cost of conventional electricity. Yet, introducing R and D subsidies throughout the entire economy leads to faster adoption of the CCS technology as well and in addition can be cost-effective in achieving the abatement target. (author)

  7. Acidic Microenvironments in Waste Rock Characterized by Neutral Drainage: Bacteria–Mineral Interactions at Sulfide Surfaces

    Directory of Open Access Journals (Sweden)

    John W. Dockrey

    2014-03-01

    Full Text Available Microbial populations and microbe-mineral interactions were examined in waste rock characterized by neutral rock drainage (NRD. Samples of three primary sulfide-bearing waste rock types (i.e., marble-hornfels, intrusive, exoskarn were collected from field-scale experiments at the Antamina Cu–Zn–Mo mine, Peru. Microbial communities within all samples were dominated by neutrophilic thiosulfate oxidizing bacteria. However, acidophilic iron and sulfur oxidizers were present within intrusive waste rock characterized by bulk circumneutral pH drainage. The extensive development of microbially colonized porous Fe(III (oxyhydroxide and Fe(III (oxyhydroxysulfate precipitates was observed at sulfide-mineral surfaces during examination by field emission-scanning electron microscopy-energy dispersive X-ray spectroscopy (FE-SEM-EDS. Linear combination fitting of bulk extended X-ray absorption fine structure (EXAFS spectra for these precipitates indicated they were composed of schwertmannite [Fe8O8(OH6–4.5(SO41–1.75], lepidocrocite [γ-FeO(OH] and K-jarosite [KFe3(OH6(SO42]. The presence of schwertmannite and K-jarosite is indicative of the development of localized acidic microenvironments at sulfide-mineral surfaces. Extensive bacterial colonization of this porous layer and pitting of underlying sulfide-mineral surfaces suggests that acidic microenvironments can play an important role in sulfide-mineral oxidation under bulk circumneutral pH conditions. These findings have important implications for water quality management in NRD settings.

  8. Crossett Hydrogen Sulfide Air Sampling Report

    Science.gov (United States)

    This report summarizes the results of the EPA’s hydrogen sulfide air monitoring conducted along Georgia Pacific’s wastewater treatment system and in surrounding Crossett, AR, neighborhoods in 2017.

  9. Upper Blackstone Water Pollution Abatement District Chief Operator Recognized for Outstanding Service

    Science.gov (United States)

    Joseph Nowak, a resident of Ware Mass. and Chief Operator of the Upper Blackstone Water Pollution Abatement District (District) in Milbury, Mass., was honored by EPA with a 2016 Regional Wastewater Treatment Plant Operator of the Year Excellence Award.

  10. Cigar Lake project abatement of August 2008 inflow - a story of innovation and relentless teamwork

    International Nuclear Information System (INIS)

    Forbes, R.; Dixon, B.; King, C.; Dent, A.

    2010-01-01

    'Full text:' The presentation recounts the process of finding August 2008 inflow, as well as planning and executing the inflow abatement project. Brian Dixon will speak regarding locating the inflow, preparing the inflow abatement plan, and preparing the underground work site at the (underwater) 420 meter level. Craig King will speak regarding design, procurement, and installation of the grout bag barrier adjacent to the No. 1 Shaft at the underwater work site. April Dent will speak regarding the surface abatement drilling and backfilling/grouting, as well as the testing of the completed inflow abatement work. The team will discuss the innovative methods to locate the source of inflow and steps taken to remediate it. (author)

  11. Cigar Lake project abatement of August 2008 inflow - a story of innovation and relentless teamwork

    Energy Technology Data Exchange (ETDEWEB)

    Forbes, R.; Dixon, B.; King, C.; Dent, A., E-mail: brian_dixon@cameco.com [Cameco Corp., Cigar Lake Project, Saskatoon, SK (Canada)

    2010-07-01

    'Full text:' The presentation recounts the process of finding August 2008 inflow, as well as planning and executing the inflow abatement project. Brian Dixon will speak regarding locating the inflow, preparing the inflow abatement plan, and preparing the underground work site at the (underwater) 420 meter level. Craig King will speak regarding design, procurement, and installation of the grout bag barrier adjacent to the No. 1 Shaft at the underwater work site. April Dent will speak regarding the surface abatement drilling and backfilling/grouting, as well as the testing of the completed inflow abatement work. The team will discuss the innovative methods to locate the source of inflow and steps taken to remediate it. (author)

  12. Virtual Reality Platform Based Simulation System of Environmental Noise Abatement Research

    Science.gov (United States)

    Yijun, Liu; Yu, Fang; Xiaoman, He; Yongyou, Wang

    The general mathematic mode of computing noise abatement is commonly used for most project planning and appraisal of environmental noise abatement projects. However, the inconvenient and impracticable mode and algorithm usually cannot meet the real world computation and testing. Therefore, a more practicable abatement mode and algorithm (multiple noise sources with multiband under sound barriers) which had been applied to VR based simulation system. That implemented the function of real-time demonstrating noise scattering condition within 3D virtual space, furthermore, with sound barriers added in 3D scene, the effectiveness of denoise by sound barriers also can be demonstrated within this system. That provides a significant solution for environmental noise abatement projects as a whole.

  13. Continuous abatement of methane coupled with ectoine production by Methylomicrobium alcaliphilum 20Z in stirred tank reactors: A step further towards greenhouse gas biorefineries

    OpenAIRE

    Cantera, Sara; Lebrero Fernández, Raquel; Rodríguez, Elisa; García Encina, Pedro A.; Muñoz Torre, Raúl

    2017-01-01

    Producción Científica This study demonstrates for the first time the feasibility of producing ectoine (a high added value osmoprotectant intensively used in the cosmetic industry) during the continuous abatement of diluted emissions of methane by Methylomicrobium alcaliphilum 20Z in stirred tank reactors under non-sterile conditions. An increase in NaCl concentration in the cultivation broth from 3 to 6% increased the intra-cellular ectoine yield by a factor of 2 (from 16.5 to 37.4 mg ecto...

  14. Hydrogen sulfide can inhibit and enhance oxygenic photosynthesis in a cyanobacterium from sulfidic springs

    NARCIS (Netherlands)

    Klatt, Judith M.; Haas, Sebastian; Yilmaz, Pelin; de Beer, Dirk; Polerecky, Lubos

    We used microsensors to investigate the combinatory effect of hydrogen sulfide (H2S) and light on oxygenic photosynthesis in biofilms formed by a cyanobacterium from sulfidic springs. We found that photosynthesis was both positively and negatively affected by H2S: (i) H2S accelerated the recovery of

  15. Sulfide response analysis for sulfide control using a pS electrode in sulfate reducing bioreactors

    NARCIS (Netherlands)

    Villa Gomez, D.K.; Cassidy, J.; Keesman, K.J.; Sampaio, R.M.; Lens, P.N.L.

    2014-01-01

    Step changes in the organic loading rate (OLR) through variations in the influent chemical oxygen demand (CODin) concentration or in the hydraulic retention time (HRT) at constant COD/SO4 2- ratio (0.67) were applied to create sulfide responses for the design of a sulfide control in sulfate reducing

  16. Risk management for sulfur dioxide abatement under multiple uncertainties

    Science.gov (United States)

    Dai, C.; Sun, W.; Tan, Q.; Liu, Y.; Lu, W. T.; Guo, H. C.

    2016-03-01

    In this study, interval-parameter programming, two-stage stochastic programming (TSP), and conditional value-at-risk (CVaR) were incorporated into a general optimization framework, leading to an interval-parameter CVaR-based two-stage programming (ICTP) method. The ICTP method had several advantages: (i) its objective function simultaneously took expected cost and risk cost into consideration, and also used discrete random variables and discrete intervals to reflect uncertain properties; (ii) it quantitatively evaluated the right tail of distributions of random variables which could better calculate the risk of violated environmental standards; (iii) it was useful for helping decision makers to analyze the trade-offs between cost and risk; and (iv) it was effective to penalize the second-stage costs, as well as to capture the notion of risk in stochastic programming. The developed model was applied to sulfur dioxide abatement in an air quality management system. The results indicated that the ICTP method could be used for generating a series of air quality management schemes under different risk-aversion levels, for identifying desired air quality management strategies for decision makers, and for considering a proper balance between system economy and environmental quality.

  17. Transient Kinetic Analysis of Hydrogen Sulfide Oxidation Catalyzed by Human Sulfide Quinone Oxidoreductase*

    Science.gov (United States)

    Mishanina, Tatiana V.; Yadav, Pramod K.; Ballou, David P.; Banerjee, Ruma

    2015-01-01

    The first step in the mitochondrial sulfide oxidation pathway is catalyzed by sulfide quinone oxidoreductase (SQR), which belongs to the family of flavoprotein disulfide oxidoreductases. During the catalytic cycle, the flavin cofactor is intermittently reduced by sulfide and oxidized by ubiquinone, linking H2S oxidation to the electron transfer chain and to energy metabolism. Human SQR can use multiple thiophilic acceptors, including sulfide, sulfite, and glutathione, to form as products, hydrodisulfide, thiosulfate, and glutathione persulfide, respectively. In this study, we have used transient kinetics to examine the mechanism of the flavin reductive half-reaction and have determined the redox potential of the bound flavin to be −123 ± 7 mV. We observe formation of an unusually intense charge-transfer (CT) complex when the enzyme is exposed to sulfide and unexpectedly, when it is exposed to sulfite. In the canonical reaction, sulfide serves as the sulfur donor and sulfite serves as the acceptor, forming thiosulfate. We show that thiosulfate is also formed when sulfide is added to the sulfite-induced CT intermediate, representing a new mechanism for thiosulfate formation. The CT complex is formed at a kinetically competent rate by reaction with sulfide but not with sulfite. Our study indicates that sulfide addition to the active site disulfide is preferred under normal turnover conditions. However, under pathological conditions when sulfite concentrations are high, sulfite could compete with sulfide for addition to the active site disulfide, leading to attenuation of SQR activity and to an alternate route for thiosulfate formation. PMID:26318450

  18. Transient Kinetic Analysis of Hydrogen Sulfide Oxidation Catalyzed by Human Sulfide Quinone Oxidoreductase.

    Science.gov (United States)

    Mishanina, Tatiana V; Yadav, Pramod K; Ballou, David P; Banerjee, Ruma

    2015-10-09

    The first step in the mitochondrial sulfide oxidation pathway is catalyzed by sulfide quinone oxidoreductase (SQR), which belongs to the family of flavoprotein disulfide oxidoreductases. During the catalytic cycle, the flavin cofactor is intermittently reduced by sulfide and oxidized by ubiquinone, linking H2S oxidation to the electron transfer chain and to energy metabolism. Human SQR can use multiple thiophilic acceptors, including sulfide, sulfite, and glutathione, to form as products, hydrodisulfide, thiosulfate, and glutathione persulfide, respectively. In this study, we have used transient kinetics to examine the mechanism of the flavin reductive half-reaction and have determined the redox potential of the bound flavin to be -123 ± 7 mV. We observe formation of an unusually intense charge-transfer (CT) complex when the enzyme is exposed to sulfide and unexpectedly, when it is exposed to sulfite. In the canonical reaction, sulfide serves as the sulfur donor and sulfite serves as the acceptor, forming thiosulfate. We show that thiosulfate is also formed when sulfide is added to the sulfite-induced CT intermediate, representing a new mechanism for thiosulfate formation. The CT complex is formed at a kinetically competent rate by reaction with sulfide but not with sulfite. Our study indicates that sulfide addition to the active site disulfide is preferred under normal turnover conditions. However, under pathological conditions when sulfite concentrations are high, sulfite could compete with sulfide for addition to the active site disulfide, leading to attenuation of SQR activity and to an alternate route for thiosulfate formation. © 2015 by The American Society for Biochemistry and Molecular Biology, Inc.

  19. Experimental simulations of sulfide formation in the solar nebula.

    Science.gov (United States)

    Lauretta, D S; Lodders, K; Fegley, B

    1997-07-18

    Sulfurization of meteoritic metal in H2S-H2 gas produced three different sulfides: monosulfide solid solution [(Fe,Ni)1-xS], pentlandite [(Fe,Ni)9-xS8], and a phosphorus-rich sulfide. The composition of the remnant metal was unchanged. These results are contrary to theoretical predictions that sulfide formation in the solar nebula produced troilite (FeS) and enriched the remaining metal in nickel. The experimental sulfides are chemically and morphologically similar to sulfide grains in the matrix of the Alais (class CI) carbonaceous chondrite, suggesting that these meteoritic sulfides may be condensates from the solar nebula.

  20. Synthesis and structural studies of copper sulfide nanocrystals

    Directory of Open Access Journals (Sweden)

    Peter A. Ajibade

    Full Text Available We report the synthesis and structural studies of copper sulfide nanocrystals from copper(II dithiocarbamate single molecule precursors. The optical studies of the as-prepared copper sulfide nanoparticles were carried out using UV–Visible and photoluminescence spectroscopy. The absorption spectra show absorption band edges at 287 nm and exhibit considerable blue shift that could be ascribed to the quantum confinement effects as a result of the small crystallite sizes of the nanoparticles and the photoluminescence spectra show emission curves that are red shifted with respect to the absorption band edges. The structural studies were carried out using powder X-ray diffraction, transmission electron microscopy, scanning electron microscopy, energy dispersive X-ray spectroscopy and atomic force microscopy. The XRD patterns revealed the formation of hexagonal structure of covellite CuS with estimated crystallite sizes of 17.3–18.6 nm. The TEM images showed particles with almost spherical or rod shapes with average crystallite sizes of 3–9.8 nm. SEM images showed morphology with ball-like microsphere on the surfaces and EDS spectra confirmed the presence of CuS nanoparticles. Keywords: CuS, Dithiocarbamate, Nanoparticles, Electron microscopy, AFM

  1. Marginal abatement cost and carbon reduction potential outlook of key energy efficiency technologies in China's building sector to 2030

    International Nuclear Information System (INIS)

    Xiao, He; Wei, Qingpeng; Wang, Hailin

    2014-01-01

    China achieved an energy savings of 67.5 Mtce in the building sector at the end of the 11th Five-Year Plan and set a new target of 116 Mtce by the end of the 12th Five-Year Plan. In this paper, an improved bottom-up model is developed to assess the carbon abatement potential and marginal abatement cost (MAC) of 34 selected energy-saving technologies/measures for China's building sector. The total reduction potential is 499.8 million t-CO 2 by 2030. 4.8 Gt-CO 2 potential will be achieved cumulatively to 2030. By 2030, total primary energy consumption of Chinese building sector will rise continuously to 1343 Mtce in the reference scenario and 1114 Mtce in the carbon reduction scenario. Total carbon dioxide emission will rise to 2.39 Gt-CO 2 and 1.9 Gt-CO 2 in two scenarios separately. The average carbon abatement cost of the aforementioned technologies is 19.5 $/t-CO 2 . The analysis reveals that strengthening successfully energy-saving technologies is important, especially for the residential building sector. The central government's direct investments in such technologies should be reduced without imposing significant negative effects. - Highlights: • MAC of 34 energy-saving technologies of China's building sector is calculated. • Energy use and CO 2 emission of China's building sector by 2030 is forecasted. • The reference and the carbon reduction scenarios are compared

  2. How to globally reduce the greenhouse gas emissions from sewage systems?

    International Nuclear Information System (INIS)

    Batz, S. de; Bonardet, P.; Trouve, J.P.

    2007-01-01

    A reliable and exhaustive measurement of the global greenhouse gas emissions from a given sewage plant must be performed prior to the implementation of any abatement measure. The method presented in this paper takes into consideration both the direct emissions but also the indirect ones generated by the plant activity and identified using a life cycle-type approach. Three examples of projects or realizations are presented in this paper to illustrate the different means of abatement of greenhouse gas emissions from a sewage plant in a global way. The first example concerns a project of abatement of the electricity consumption of a plant for sludges and fats digestion and biogas valorization. A 85% global abatement of CO 2 emissions is obtained thanks to the substitution of the aerobic digestion process by an anaerobic one. The second example presents an optimization of the greenhouse gas emissions of the municipal sewage plant of Valenton (Paris region) thanks to a valorization of sludges as fertilizers and fuels and to the recovery of the process heat. The last example concerns the Seine-aval sewage plant which gathers several projects of improvement: setting up of a second biogas turbine, redesign of the heat loop, use of river transport for a significant abatement of greenhouse gas emissions. (J.S.)

  3. Understanding selected trace elements behavior in a coal-fired power plant in Malaysia for assessment of abatement technologies.

    Science.gov (United States)

    Mokhtar, Mutahharah M; Taib, Rozainee M; Hassim, Mimi H

    2014-08-01

    The Proposed New Environmental Quality (Clean Air) Regulation 201X (Draft), which replaces the Malaysia Environmental Quality (Clean Air) 1978, specifies limits to additional pollutants from power generation using fossil fuel. The new pollutants include Hg, HCl, and HF with limits of 0.03, 100, and 15 mg/N-m3 at 6% O2, respectively. These pollutants are normally present in very small concentrations (known as trace elements [TEs]), and hence are often neglected in environmental air quality monitoring in Malaysia. Following the enactment of the new regulation, it is now imperative to understand the TEs behavior and to assess the capability of the existing abatement technologies to comply with the new emission limits. This paper presents the comparison of TEs behavior of the most volatile (Hg, Cl, F) and less volatile (As, Be, Cd, Cr, Ni, Se, Pb) elements in subbituminous and bituminous coal and coal combustion products (CCP) (i.e., fly ash and bottom ash) from separate firing of subbituminous and bituminous coal in a coal-fired power plant in Malaysia. The effect of air pollution control devices configuration in removal of TEs was also investigated to evaluate the effectiveness of abatement technologies used in the plant. This study showed that subbituminous and bituminous coals and their CCPs have different TEs behavior. It is speculated that ash content could be a factor for such diverse behavior In addition, the type of coal and the concentrations of TEs in feed coal were to some extent influenced by the emission of TEs in flue gas. The electrostatic precipitator (ESP) and seawater flue gas desulfurization (FGD) used in the studied coal-fired power plant were found effective in removing TEs in particulate and vapor form, respectively, as well as complying with the new specified emission limits. Implications: Coals used by power plants in Peninsular Malaysia come from the same supplier (Tenaga Nasional Berhad Fuel Services), which is a subsidiary of the Malaysia

  4. Functional consortium for denitrifying sulfide removal process.

    Science.gov (United States)

    Chen, Chuan; Ren, Nanqi; Wang, Aijie; Liu, Lihong; Lee, Duu-Jong

    2010-03-01

    Denitrifying sulfide removal (DSR) process simultaneously converts sulfide, nitrate, and chemical oxygen demand from industrial wastewaters to elemental sulfur, nitrogen gas, and carbon dioxide, respectively. This investigation utilizes a dilution-to-extinction approach at 10(-2) to 10(-6) dilutions to elucidate the correlation between the composition of the microbial community and the DSR performance. In the original suspension and in 10(-2) dilution, the strains Stenotrophomonas sp., Thauera sp., and Azoarcus sp. are the heterotrophic denitrifiers and the strains Paracoccus sp. and Pseudomonas sp. are the sulfide-oxidizing denitrifers. The 10(-4) dilution is identified as the functional consortium for the present DSR system, which comprises two functional strains, Stenotrophomonas sp. strain Paracoccus sp. At 10(-6) dilution, all DSR performance was lost. The functions of the constituent cells in the DSR granules were discussed based on data obtained using the dilution-to-extinction approach.

  5. Production and Preservation of Sulfide Layering in Mercury's Magma Ocean

    Science.gov (United States)

    Boukare, C.-E.; Parman, S. W.; Parmentier, E. M.; Anzures, B. A.

    2018-05-01

    Mercury's magma ocean (MMO) would have been sulfur-rich. At some point during MMO solidification, it likely became sulfide saturated. Here we present physiochemical models exploring sulfide layer formation and stability.

  6. Acute inhalation toxicity of carbonyl sulfide

    Energy Technology Data Exchange (ETDEWEB)

    Benson, J.M.; Hahn, F.F.; Barr, E.B. [and others

    1995-12-01

    Carbonyl sulfide (COS), a colorless gas, is a side product of industrial procedures sure as coal hydrogenation and gasification. It is structurally related to and is a metabolite of carbon disulfide. COS is metabolized in the body by carbonic anhydrase to hydrogen sulfide (H{sub 2}S), which is thought to be responsible for COS toxicity. No threshold limit value for COS has been established. Results of these studies indicate COS (with an LC{sub 50} of 590 ppm) is slightly less acutely toxic than H{sub 2}S (LC{sub 50} of 440 ppm).

  7. Girdler-sulfide process physical properties

    International Nuclear Information System (INIS)

    Neuburg, H.J.; Atherley, J.F.; Walker, L.G.

    1977-05-01

    Physical properties of pure hydrogen sulfide and of gaseous and liquid solutions of the H 2 S-H 2 O system have been formulated. Tables for forty-nine different properties in the pressure and temperature range of interest to the Girdler-Sulfide (GS) process for heavy water production are given. All properties are presented in SI units. A computer program capable of calculating properties of the pure components as well as gaseous mixtures and liquid solutions at saturated and non-saturated conditions is included. (author)

  8. Use of biogenic sulfide for ZnS precipitation

    NARCIS (Netherlands)

    Esposito, G.; Veeken, A.; Weijma, J.; Lens, P.N.L.

    2006-01-01

    A 600 ml continuously stirred tank reactor was used to assess the performance of a zinc sulfide precipitation process using a biogenic sulfide solution (the effluent of a sulfate-reducing bioreactor) as sulfide source. In all experiments, a proportional-integral (PI) control algorithm was used to

  9. Emission trading and international competition: The impact of labor market rigidity on technology adoption and output

    International Nuclear Information System (INIS)

    Caparrós, Alejandro; Péreau, Jean-Christophe; Tazdaït, Tarik

    2013-01-01

    Emission trading systems have been proposed in different regions to reduce polluting emissions and are in use in the European Union for carbon dioxide emissions. One of the objectives of these systems is to encourage firms to adopt advanced abatement technologies. However, permits also create an incentive to reduce output, which may be seen as negative by policy makers. We analyze the impact of a rigid labour market on these two outcomes, showing the conditions necessary to avoid reductions in production while keeping the incentives to improve abatement technologies. The analysis is done for oligopolistic firms engaged in international rivalry. - Highlights: ► Emission trading reduces production and improves abatement technologies. ► Policy makers see the first outcome as negative and the second as positive. ► This paper studies the impact of market rigidity on these two outcomes. ► It shows conditions to avoid the first outcome and maintain or enhance the second

  10. Save water to save carbon and money: developing abatement costs for expanded greenhouse gas reduction portfolios.

    Science.gov (United States)

    Stokes, Jennifer R; Hendrickson, Thomas P; Horvath, Arpad

    2014-12-02

    The water-energy nexus is of growing interest for researchers and policy makers because the two critical resources are interdependent. Their provision and consumption contribute to climate change through the release of greenhouse gases (GHGs). This research considers the potential for conserving both energy and water resources by measuring the life-cycle economic efficiency of greenhouse gas reductions through the water loss control technologies of pressure management and leak management. These costs are compared to other GHG abatement technologies: lighting, building insulation, electricity generation, and passenger transportation. Each cost is calculated using a bottom-up approach where regional and temporal variations for three different California water utilities are applied to all alternatives. The costs and abatement potential for each technology are displayed on an environmental abatement cost curve. The results reveal that water loss control can reduce GHGs at lower cost than other technologies and well below California's expected carbon trading price floor. One utility with an energy-intensive water supply could abate 135,000 Mg of GHGs between 2014 and 2035 and save--rather than spend--more than $130/Mg using the water loss control strategies evaluated. Water loss control technologies therefore should be considered in GHG abatement portfolios for utilities and policy makers.

  11. Abatement of waste gases and water during the processes of semiconductor fabrication.

    Science.gov (United States)

    Wen, Rui-mei; Liang, Jun-wu

    2002-10-01

    The purpose of this article is to examine the methods and equipment for abating waste gases and water produced during the manufacture of semiconductor materials and devices. Three separating methods and equipment are used to control three different groups of electronic wastes. The first group includes arsine and phosphine emitted during the processes of semiconductor materials manufacture. The abatement procedure for this group of pollutants consists of adding iodates, cupric and manganese salts to a multiple shower tower (MST) structure. The second group includes pollutants containing arsenic, phosphorus, HF, HCl, NO2, and SO3 emitted during the manufacture of semiconductor materials and devices. The abatement procedure involves mixing oxidants and bases in an oval column with a separator in the middle. The third group consists of the ions of As, P and heavy metals contained in the waste water. The abatement procedure includes adding CaCO3 and ferric salts in a flocculation-sedimentation compact device equipment. Test results showed that all waste gases and water after the abatement procedures presented in this article passed the discharge standards set by the State Environmental Protection Administration of China.

  12. Modeling Sulfides, pH and Hydrogen Sulfide Gas in the Sewers of San Francisco

    DEFF Research Database (Denmark)

    Vollertsen, Jes; Revilla, Nohemy; Hvitved-Jacobsen, Thorkild

    2015-01-01

    An extensive measuring campaign targeted on sewer odor problems was undertaken in San Francisco. It was assessed whether a conceptual sewer process model could reproduce the measured concentrations of total sulfide in the wastewater and H2S gas in the sewer atmosphere, and to which degree...... such simulations have potential for further improving odor and sulfide management. The campaign covered measurement of wastewater sulfide by grab sampling and diurnal sampling, and H2S gas in the sewer atmosphere was logged. The tested model was based on the Wastewater Aerobic/Anaerobic Transformations in Sewers...... (WATS) sewer process concept, which never had been calibrated to such an extensive dataset. The study showed that the model was capable of reproducing the general levels of wastewater sulfide, wastewater pH, and sewer H2S gas. It could also reproduce the general variability of these parameters, albeit...

  13. Fluorinated Greenhouse Gases in Photovoltaic Module Manufacturing: Potential Emissions and Abatement Strategies

    NARCIS (Netherlands)

    Alsema, E.A.|info:eu-repo/dai/nl/073416258; de Wild-Schoten, M.J.; Fthenakis, V.M.; Agostinelli, G.; Dekkers, H.; Roth, K.; Kinzig, V.

    2007-01-01

    Some fluorinated gases (F-gases) which are used, or considered to be used, in crystalline silicon photovoltaic solar cell and film silicon module manufacturing have a very high global warming effect. CF4, C2F6, SF6 and NF3 have global warming potentials 7390, 12200, 22800 and 17200 times higher than

  14. A simulation study on the abatement of CO2 emissions by de-absorption with monoethanolamine.

    Science.gov (United States)

    Greer, T; Bedelbayev, A; Igreja, J M; Gomes, J F; Lie, B

    2010-01-01

    Because of the adverse effect of CO2 from fossil fuel combustion on the earth's ecosystems, the most cost-effective method for CO2 capture is an important area of research. The predominant process for CO2 capture currently employed by industry is chemical absorption in amine solutions. A dynamic model for the de-absorption process was developed with monoethanolamine (MEA) solution. Henry's law was used for modelling the vapour phase equilibrium of the CO2, and fugacity ratios calculated by the Peng-Robinson equation of state (EOS) were used for H2O, MEA, N2 and O2. Chemical reactions between CO2 and MEA were included in the model along with the enhancement factor for chemical absorption. Liquid and vapour energy balances were developed to calculate the liquid and vapour temperature, respectively.

  15. An Optimal Control Approach to Helicopter Noise and Emissions Abatement Terminal Procedures

    NARCIS (Netherlands)

    Hartjes, S.

    2015-01-01

    Civil aviation plays an irreplaceable role in the current global civilization. Even though the 2008 economic crisis has limited growth in the western world, it can only be expected that due to continuing development in the Far East, South America and Africa this role will increase further over the

  16. Application of Calcined Layered Double Hydroxides as Catalysts for Abatement of N2O Emissions

    Czech Academy of Sciences Publication Activity Database

    Obalová, L.; Kovanda, F.; Jirátová, Květa; Pacultová, K.; Lacný, Z.

    2008-01-01

    Roč. 73, 8-9 (2008), s. 1045-1060 ISSN 0010-0765 Institutional research plan: CEZ:AV0Z40720504 Keywords : nitrous oxide * catalytic decomposition * mixed oxides Subject RIV: CF - Physical ; Theoretical Chemistry Impact factor: 0.784, year: 2008

  17. Policies and strategies for meeting emission abatement targets in the UK electricity supply industry

    Energy Technology Data Exchange (ETDEWEB)

    Kyte, W S [Powergen, Solihull (United Kingdom)

    1994-12-31

    A new electricity industry structure was created in the UK on 31 March 1990 and this was launched into the private sector during 1990/91. This structure differs considerably from the public corporations that preceeded it. Public awareness of the environment has grown during this period and the newly privatised electricity supply industry is having to implement new pollution controls. Legislation increasingly comes from the European Commission and is interpreted by HM Inspectorate of Pollution having regard to Best Practicable Environmental Option (BPEO) and Best Available Technology Not Entailing Excessive Cost (BATNEEC). Issues of particular importance include acid rain, and global warming - especially CO{sub 2} reduction. 3 figs.

  18. Reaction between Hydrogen Sulfide and Limestone Calcines

    Czech Academy of Sciences Publication Activity Database

    Hartman, Miloslav; Svoboda, Karel; Trnka, Otakar; Čermák, Jiří

    2002-01-01

    Roč. 41, č. 10 (2002), s. 2392-2398 ISSN 0888-5885 R&D Projects: GA AV ČR IAA4072711; GA AV ČR IAA4072801 Keywords : hydrogen sulfide * limestone calcines * desulfurization Subject RIV: CI - Industrial Chemistry, Chemical Engineering Impact factor: 1.247, year: 2002

  19. Microaeration reduces hydrogen sulfide in biogas

    Science.gov (United States)

    Although there are a variety of biological and chemical treatments for removal of hydrogen sulfide (H2S) from biogas, all require some level of chemical or water inputs and maintenance. In practice, managing biogas H2S remains a significant challenge for agricultural digesters where labor and opera...

  20. Support Effect in Hydrodesulfurization over Ruthenium Sulfide

    Czech Academy of Sciences Publication Activity Database

    Gulková, Daniela; Kaluža, Luděk; Vít, Zdeněk; Zdražil, Miroslav

    2009-01-01

    Roč. 51, č. 2 (2009), s. 146-149 ISSN 1337-7027 R&D Projects: GA ČR GA104/06/0705 Institutional research plan: CEZ:AV0Z40720504 Keywords : ruthenium sulfide * hydrodesulfurization * support effect Subject RIV: CC - Organic Chemistry

  1. Monitoring sulfide and sulfate-reducing bacteria

    Energy Technology Data Exchange (ETDEWEB)

    Tanner, R.S.

    1995-12-31

    Simple yet precise and accurate methods for monitoring sulfate-reducing bacteria (SRB) and sulfide remain useful for the study of bacterial souring and corrosion. Test kits are available to measure sulfide in field samples. A more precise methylene blue sulfide assay for both field and laboratory studies is described here. Improved media, compared to that in API RP-38, for enumeration of SRB have been formulated. One of these, API-RST, contained cysteine (1.1 mM) as a reducing agent, which may be a confounding source of sulfide. While cysteine was required for rapid enumeration of SRB from environmental samples, the concentration of cysteine in medium could be reduced to 0.4 mM. It was also determined that elevated levels of yeast extract (>1 g/liter) could interfere with enumeration of SRB from environmental samples. The API-RST medium was modified to a RST-11 medium. Other changes in medium composition, in addition to reduction of cysteine, included reduction of the concentration of phosphate from 3.4 mM to 2.2 mM, reduction of the concentration of ferrous iron from 0.8 mM to 0.5 mM and preparation of a stock mineral solution to ease medium preparation. SRB from environmental samples could be enumerated in a week in this medium.

  2. Acid volatile sulfide (AVS)- a comment

    NARCIS (Netherlands)

    Meysman, F.J.R.; Middelburg, J.J.

    2005-01-01

    The review by Rickard and Morse (this volume) adequately summarizes our current understanding with respect to acid-volatile sulfides (AVS). At the same time, this review addresses some of the misunderstandings with regard to measurements and dynamics of this important sedimentary sulfur pool. In

  3. Carbon a support for sulfide catalysts

    NARCIS (Netherlands)

    Vissers, J.P.R.; Lensing, T.J.; Mercx, F.P.M.; Beer, de V.H.J.; Prins, R.

    1983-01-01

    Two types of carbon materials, carbon black composite and carbon covered alumina, were studied for-their use as support for sulfide catalysts. The following parameters were varied: type of carbon black, carbon coverage of the alumina and carbon pretreatment. Pore size distributions were determined

  4. Study on the sulfidation behavior of smithsonite

    International Nuclear Information System (INIS)

    Wu, Dandan; Wen, Shuming; Deng, Jiushuai; Liu, Jian; Mao, Yingbo

    2015-01-01

    Highlights: • Zeta potential showed that the pH IEP of smithsonite decreased from 7.7 to 6. • ICP test showed the gradual reduction of C S in the solution. • SEM showed that the mineral surface was partially changed to ZnS film. • XPS indicated that the presence of a characteristic signal peak of sulfur ions. - Abstract: Zinc extraction from low-grade mineral resources of oxidized zinc has recently become a focus of study. Sulfidation is an important process in oxidized ore flotation. In this study, the influence of sulfur ion adsorption on smithsonite surface was investigated with the use of zeta potential, inductively coupled plasma (ICP), scanning electron microscope (SEM), and X-ray photoelectron spectroscopic studies. Zeta potential measurements of sodium sulfide showed that sulfur ions were adsorbed onto the surface of pure smithsonite, as evidenced by the increased negative charge and the decrease in the pH IEP of smithsonite from 7.7 to 6 after sodium sulfide treatment. The ICP test revealed the gradual reduction in sulfur ion adsorption onto the surface of smithsonite in pulp sulfur. After 30 min of absorption, C S in the solution declined from 1000 × 10 −6 mol/L to 1.4 × 10 −6 mol/L. SEM results showed that the mineral surface was partially changed to ZnS film after sodium sulfide treatment, whereas EDS analysis results showed that 2% S is contained on the smithsonite surface. X-ray photoelectron spectroscopy results indicated the presence of a characteristic signal peak of sulfur ions after sulfidation. Sulfur concentration increased to 11.89%, whereas oxygen concentration decreased from 42.31% to 13.74%. Sulfur ions were not only present during chemical adsorption, but were also incorporated into the crystal lattices of minerals by the exchange reaction between S 2− and CO 3 2− ions

  5. An assessment of household electricity load curves and corresponding CO2 marginal abatement cost curves for Gujarat state, India

    International Nuclear Information System (INIS)

    Garg, Amit; Shukla, P.R.; Maheshwari, Jyoti; Upadhyay, Jigeesha

    2014-01-01

    Gujarat, a large industrialized state in India, consumed 67 TWh of electricity in 2009–10, besides experiencing a 4.5% demand–supply short-fall. Residential sector accounted for 15% of the total electricity consumption. We conducted load research survey across 21 cities and towns of the state to estimate residential electricity load curves, share of appliances by type and usage patterns for all types of household appliances at utility, geographic, appliance, income and end-use levels. The results indicate that a large scope exists for penetration of energy efficient devices in residential sector. Marginal Abatement Cost (MAC) curves for electricity and CO 2 were generated to analyze relative attractiveness of energy efficient appliance options. Results indicate that up to 7.9 TWh of electricity can be saved per year with 6.7 Mt-CO 2 emissions mitigation at negative or very low CO 2 prices of US$ 10/t-CO 2 . Despite such options existing, their penetration is not realized due to myriad barriers such as financial, institutional or awareness and therefore cannot be taken as baseline options for CO 2 emission mitigation regimes. - Highlights: • Residential sector provides focused mitigation opportunities. • Energy efficient space cooling is the main technology transition required. • Almost 26% residential load could be reduced by DSM measures. • Myriad barriers limit penetration of negative marginal cost efficient options

  6. Carbon abatement via treating the solid waste from the Australian olive industry in mobile pyrolysis units: LCA with uncertainty analysis.

    Science.gov (United States)

    El Hanandeh, Ali

    2013-04-01

    The olive oil industry in Australia has been growing at a rapid rate over the past decade. It is forecast to continue growing due to the steady increase in demand for olive oil and olive products in the local and regional market. However, the olive oil extraction process generates large amounts of solid waste called olive husk which is currently underutilized. This paper uses life-cycle methodology to analyse the carbon emission reduction potential of utilizing olive husk as a feedstock in a mobile pyrolysis unit. Four scenarios, based on different combinations of pyrolysis technologies (slow versus fast) and end-use of products (land application versus energy utilization), are constructed. The performance of each scenario under conditions of uncertainty was also investigated. The results show that all scenarios result in significant carbon emission abatement. Processing olive husk in mobile fast pyrolysis units and the utilization of bio-oil and biochar as substitutes for heavy fuel oil and coal is likely to realize a carbon offset greater than 32.3 Gg CO2-eq annually in 90% of the time. Likewise, more than 3.2 Gg-C (11.8 Gg CO2-eq) per year could be sequestered in the soil in the form of fixed carbon if slow mobile pyrolysis units were used to produce biochar.

  7. Broadening the Appeal of Marginal Abatement Cost Curves: Capturing Both Carbon Mitigation and Development Benefits of Clean Energy Technologies; Preprint

    Energy Technology Data Exchange (ETDEWEB)

    Cowlin, S.; Cochran, J.; Cox, S.; Davison, C.; van der Gaast, Y.

    2012-08-01

    Low emission development strategies (LEDS) articulate policies and implementation plans that enable countries to advance sustainable, climate-resilient development and private sector growth while significantly reducing the greenhouse gas (GHG) emissions traditionally associated with economic growth. In creating a LEDS, policy makers often have access to information on abatement potential and costs for clean energy technologies, but there is a scarcity of economy-wide approaches for evaluating and presenting information on other dimensions of importance to development, such as human welfare, poverty alleviation, and energy security. To address this shortcoming, this paper proposes a new tool for communicating development benefits to policy makers as part of a LEDS process. The purpose of this tool is two-fold: 1. Communicate development benefits associated with each clean energy-related intervention; 2. Facilitate decision-making on which combination of interventions best contributes to development goals. To pilot this tool, the authors created a visual using data on developmental impacts identified through the Technology Needs Assessment (TNA) project in Montenegro. The visual will then be revised to reflect new data established through the TNA that provides information on cost, GHG mitigation, as well as the range and magnitude of developmental impacts.

  8. Benefits from restoring wetlands for nitrogen abatement: A case study of Gotland

    International Nuclear Information System (INIS)

    Gren, I.M.

    1992-01-01

    The values of nitrogen abatement by measures involving restoration of wetlands, sewage treatment plants and agriculture are calculated and compared. The analytical results show that the value of wetlands is likely to exceed the values of other measures due to the multi-functionality of wetlands and their self-organizing ability. The multi-functionality implies that, in addition to nitrogen abatement, other outputs like buffering of water and biodiversity are produced and the self-organizing feature reduces the rate at which future values of outputs are discounted. According to the empirical results applied to Gotland, a Swedish island in the Baltic with high concentrations of nitrate in the ground water, the imputed value of wetlands exceeds the corresponding values of the other nitrogen abatement measures by several hundred per cent. 21 refs, 6 tabs

  9. Modeling and experimental validation of TCE abatement and ozone formation with non thermal plasma

    OpenAIRE

    Vandenbroucke, Arne; Aerts, Robby; Morent, Rino; De Geyter, Nathalie; Bogaerts, Annemie; Leys, Christophe

    2012-01-01

    In this study, the formation of ozone and the abatement of trichloroethylene (TCE) with non thermal plasma was experimentally and theoretically investigated. The model predicts that the ozone formation increases with the energy deposition and decreases with the relative humidity (RH) of the air, which is qualitatively in agreement with experimental data. For an energy deposition of 0.136 J/cm³, the abatement of 1000 ppm TCE in air with 5 % RH is dominated by atomic oxygen and to a lesser exte...

  10. 40 CFR Appendix I to Subparts D and E - Motorcycle Noise Emission Test Procedures [Note

    Science.gov (United States)

    2010-07-01

    ... 40 Protection of Environment 24 2010-07-01 2010-07-01 false Motorcycle Noise Emission Test... (CONTINUED) NOISE ABATEMENT PROGRAMS TRANSPORTATION EQUIPMENT NOISE EMISSION CONTROLS Motorcycles Recall of noncomplying motorcycles; relabeling of mislabeled motorcycles. Appendix I to Subparts D and E—Motorcycle Noise...

  11. 40 CFR 205.54-1 - Low speed sound emission test procedures.

    Science.gov (United States)

    2010-07-01

    ... 40 Protection of Environment 24 2010-07-01 2010-07-01 false Low speed sound emission test procedures. 205.54-1 Section 205.54-1 Protection of Environment ENVIRONMENTAL PROTECTION AGENCY (CONTINUED) NOISE ABATEMENT PROGRAMS TRANSPORTATION EQUIPMENT NOISE EMISSION CONTROLS Medium and Heavy Trucks § 205...

  12. National energy cost optimization and project implementation: Two different worlds?. Discussion paper in the framework of the UNEP Greenhouse Gas Abatement Costing Studies

    International Nuclear Information System (INIS)

    Van Harmelen, T.

    1994-08-01

    One of the main targets of the UNEP Greenhouse Gas Abatement Costing Study is combining the techno-economic and purely economic modelling approaches into one overall modelling methodology for greenhouse gas abatement costing studies. This type of models can be categorized as bottom-up models, since technology data on a very detailed level result in costs and emissions on a national level. In contrast with, but not necessarily in conflict with these models, macro-economists rely in general on macro-economic models which derive economic projections from aggregated national and sectorial economic data. These so called top-down models describe the complete national economy. Therefore the energy sector is modelled in a very aggregated way. Since the micro-economic and techno-economic approaches can be classified both as bottom-up approaches, it could be expected that mutual understanding exists. However, this is not true for all issues in this field. Techno-economical views and micro-economic views differ for instance on the implementation of options. This topic drew attention during the UNEP study, next to other items as techno-economic and macro-economic model assessments of the costs of CO 2 abatement. One of the most important implementation issues is the so-called negative cost (benefit) potential of energy saving options, which exists in the techno-economic view at this very moment, but which is not implemented yet. In the view of micro-economic analysis this potential does not exist, since options which are profitable would have been implemented according to presently adopted cost-benefit theory. Several aspects of this controversy have been discussed extensively elsewhere. In this paper the two visions are summarized and it is discussed whether it is fruitful to combine techno-economic and micro-economic approaches in an overall methodological framework. 1 tabs., 8 refs

  13. Catalytic abatement of nitrous oxide from nitric and production

    NARCIS (Netherlands)

    Oonk, J.

    1998-01-01

    Nitric acid production is identified as a main source of nitrous oxide. Options for emission reduction however are not available. TNO and Hydro Agri studied the technological and economic feasibility of catalytic decomposition of nitrous oxide in nitric acid tail-gases. Although in literature

  14. Equity effects of economic instruments for greenhouse gas abatement

    International Nuclear Information System (INIS)

    Harrison, D. Jr.

    1994-01-01

    This paper discusses the equity effects of using economic instruments--such as a carbon tax or carbon emissions trading program--to regulate greenhouse gas emissions. Determining these equity effects is more complicated than assessing overall costs and benefits, although some of the same issues arise. Among the key issues are the following: (1) benchmark for evaluating impacts of economic instruments (status quo or regulatory program that achieves the same emission reductions); (2) use of any government revenues collected, which are transfers overall but affect gains and losses; (3) time period (long-term or transitional impacts); and (4) groupings (income groups, sectors or regions). Empirical studies suggest that a national tax is regressive in the US but may be less so in other countries. The equity impacts of an international carbon tax or emissions trading program differ greatly depending upon the specific elements. The paper considers options to compensate or mitigate adverse effects to income groups, sectors, or regions of the world. Although impossible to avoid all losses to every group, it would be possible to avoid major equity effects if carbon taxes or carbon trading programs were used to control global warming

  15. Evaluating uncertain CO2 abatement over the very long term

    NARCIS (Netherlands)

    Gerlagh, R.; van der Zwaan, B.

    2012-01-01

    Climate change research with the economic methodology of cost–benefit analysis is challenging because of valuation and ethical issues associated with the long delays between CO2 emissions and much of their potential damages, typically of several centuries. The large uncertainties with which climate

  16. Water Pollution abatement programme, The Czech republic Pollution abatement analysis and strengthening of water resources management, Odra River Catchment, phase II

    OpenAIRE

    Dagestad, K.; Ratnaweera, H.; Ibrekk, H.O.; Hansen, J.H.; Tridlica, L.; Brezina, P.; Skacel, A.

    1995-01-01

    Odra river is extremely polluted by organic matter, nitrates, ammonia, phosphorus, bacteria, particles, heavy metals and other micro pollutants from municipalities, industries and agriculture. The poor water quality severely affects the ecology and represents a risk to human health. The water has a very limited value of use. This report presents an abatement programme with both technical and accompanying measures. In order to identify the major polluters several multi criteria analysis have b...

  17. Scenario analysis on CO2 emissions reduction potential in China's iron and steel industry

    International Nuclear Information System (INIS)

    Wang Ke; Wang Can; Lu Xuedu; Chen Jining

    2007-01-01

    The international climate community has begun to assess a range of possible options for strengthening the international climate change effort after 2012. Analysis of the potential for sector-based emissions reduction and relevant mitigation options will provide the necessary background information for the debate. In order to assess the CO 2 abatement potential of China's steel industry, a model was developed using LEAP software to generate 3 different CO 2 emission scenarios for the industry from 2000 to 2030. The abatement potentials of different scenarios were compared, and their respective feasibilities were assessed according to the cost information. High priority abatement measures were then identified. The results show that the average CO 2 abatement per year in the Recent Policy scenario and in the New Policy scenario, compared with the reference scenario, are 51 and 107 million tons, respectively. The corresponding total incremental costs are 9.34 and 80.95 billion dollars. It is concluded that there is great potential for CO 2 abatement in China's steel industry. Adjusting the structure of the industry and technological advancement will play an important role in emissions reduction. Successful implementation of current sustainable development policies and measures will result in CO 2 abatement at a low cost. However, to achieve higher levels of abatement, the cost will increase dramatically. In the near future, specific energy conservation technologies such as dry coke quenching, exhaust gas and heat recovery equipment will be of great significance. However, taking a long term perspective, emissions reduction will rely more on the adjustment of production processes and the application of more modern large scale plants. Advanced blast furnace technology will inevitably play an important role

  18. Green roofs as a means of pollution abatement

    International Nuclear Information System (INIS)

    Rowe, D. Bradley

    2011-01-01

    Green roofs involve growing vegetation on rooftops and are one tool that can help mitigate the negative effects of pollution. This review encompasses published research to date on how green roofs can help mitigate pollution, how green roof materials influence the magnitude of these benefits, and suggests future research directions. The discussion concentrates on how green roofs influence air pollution, carbon dioxide emissions, carbon sequestration, longevity of roofing membranes that result in fewer roofing materials in landfills, water quality of stormwater runoff, and noise pollution. Suggestions for future directions for research include plant selection, development of improved growing substrates, urban rooftop agriculture, water quality of runoff, supplemental irrigation, the use of grey water, air pollution, carbon sequestration, effects on human health, combining green roofs with complementary related technologies, and economics and policy issues. - Green roofs can help mitigate air pollution, carbon dioxide emissions, sequester carbon, conserve energy, reduce the urban heat island, and improve water quality.

  19. Ionization of oriented carbonyl sulfide molecules by intense circularly polarized laser pulses

    DEFF Research Database (Denmark)

    Dimitrovski, Darko; Abu-Samha, Mahmoud; Madsen, Lars Bojer

    2011-01-01

    We present combined experimental and theoretical results on strong-field ionization of oriented carbonyl sulfide molecules by circularly polarized laser pulses. The obtained molecular frame photoelectron angular distributions show pronounced asymmetries perpendicular to the direction of the molec......We present combined experimental and theoretical results on strong-field ionization of oriented carbonyl sulfide molecules by circularly polarized laser pulses. The obtained molecular frame photoelectron angular distributions show pronounced asymmetries perpendicular to the direction......-dimensionally-oriented polar molecules, in particular asymmetries in the emission direction of the photoelectrons. In the following article [Phys. Rev. A 83, 023406 (2011)] the focus is to understand strong-field ionization from three-dimensionally-oriented asymmetric top molecules, in particular the suppression of electron...

  20. Greenhouse gas emissions - a global challenge

    International Nuclear Information System (INIS)

    Aarebrot, Eivind; Langvik, Sveinung

    2000-01-01

    The article describes some greenhouse gas emission challenges in the Norwegian petroleum industry. Some of the conclusions are that the national taxation policies are insufficient and that international co-operation is essential in order to obtain significant pollution abatement. The mechanisms for this are not yet in place. Some possible measures are mentioned. The main solution to the problems internationally seems to be international co-operation projects generally with quota trade in order to meet the Kyoto agreement obligations

  1. Tobacco litter costs and public policy: a framework and methodology for considering the use of fees to offset abatement costs.

    Science.gov (United States)

    Schneider, John E; Peterson, N Andrew; Kiss, Noemi; Ebeid, Omar; Doyle, Alexis S

    2011-05-01

    Growing concern over the costs, environmental impact and safety of tobacco product litter (TPL) has prompted states and cities to undertake a variety of policy initiatives, of which litter abatement fees are part. The present work describes a framework and methodology for calculating TPL costs and abatement fees. Abatement is associated with four categories of costs: (1) mechanical and manual abatement from streets, sidewalks and public places, (2) mechanical and manual abatement from storm water and sewer treatment systems, (3) the costs associated with harm to the ecosystem and harm to industries dependent on clean and healthy ecosystems, and (4) the costs associated with direct harm to human health. The experiences of the City of San Francisco's recently proposed tobacco litter abatement fee serve as a case study. City and municipal TPL costs are incurred through manual and mechanical clean-up of surfaces and catchment areas. According to some studies, public litter abatement costs to US cities range from US$3 million to US$16 million. TPL typically comprises between 22% and 36% of all visible litter, implying that total public TPL direct abatement costs range from about US$0.5 million to US$6 million for a city the size of San Francisco. The costs of mitigating the negative externalities of TPL in a city the size of San Francisco can be offset by implementing a fee of approximately US$0.20 per pack. Tobacco litter abatement costs to cities can be substantial, even when the costs of potential environmental pollution and tourism effects are excluded. One public policy option to address tobacco litter is levying of fees on cigarettes sold. The methodology described here for calculating TPL costs and abatement fees may be useful to state and local authorities who are considering adoption of this policy initiative.

  2. Hydrogen sulfide concentration in Beaver Dam Creek

    International Nuclear Information System (INIS)

    Kiser, D.L.

    1979-01-01

    Concentration-time profiles calculated with LODIPS for various hypothetical releases of hydrogen sulfide from the heavy water extraction facility predict lethal conditions for swamp fish from releases as small as 568 kg discharged over a period of 30 minutes or from releases of 1818 kg discharged over a period of 6 hours or less. The necessary volatilization and oxidation coefficients for LODIPS were derived from field measurements following planned releases of H 2 S. Upsets in the operation of the wastewater strippers in the Girdler-Sulfide (GS) heavy water extraction facility in D Area have released significant amounts of dissolved H 2 S to Beaver Dam Creek. Because H 2 S is toxic to fish in concentrations as low as 1 mg/liter, the downstream environmental impact of H 2 S releases from D Area was evaluated

  3. Iron-sulfide redox flow batteries

    Science.gov (United States)

    Xia, Guan-Guang; Yang, Zhenguo; Li, Liyu; Kim, Soowhan; Liu, Jun; Graff, Gordon L

    2013-12-17

    Iron-sulfide redox flow battery (RFB) systems can be advantageous for energy storage, particularly when the electrolytes have pH values greater than 6. Such systems can exhibit excellent energy conversion efficiency and stability and can utilize low-cost materials that are relatively safer and more environmentally friendly. One example of an iron-sulfide RFB is characterized by a positive electrolyte that comprises Fe(III) and/or Fe(II) in a positive electrolyte supporting solution, a negative electrolyte that comprises S.sup.2- and/or S in a negative electrolyte supporting solution, and a membrane, or a separator, that separates the positive electrolyte and electrode from the negative electrolyte and electrode.

  4. Hydrogen sulfide prodrugs—a review

    Directory of Open Access Journals (Sweden)

    Yueqin Zheng

    2015-09-01

    Full Text Available Hydrogen sulfide (H2S is recognized as one of three gasotransmitters together with nitric oxide (NO and carbon monoxide (CO. As a signaling molecule, H2S plays an important role in physiology and shows great potential in pharmaceutical applications. Along this line, there is a need for the development of H2S prodrugs for various reasons. In this review, we summarize different H2S prodrugs, their chemical properties, and some of their potential therapeutic applications.

  5. Cost-effective analysis of carbon abatement options in China's electricity sector

    NARCIS (Netherlands)

    Zhang, Z.X.

    1998-01-01

    This article attempts to shed light on technological aspects of carbon abatement in China's power industry and is thus devoted to satisfying electricity planning requirements in the CO2 context. To that end, a technology-oriented dynamic optimization model for power system expansion planning has

  6. Collateral benefits and hidden hazards of soil arsenic during abatement assessment of residential lead hazards

    International Nuclear Information System (INIS)

    Elless, M.P.; Ferguson, B.W.; Bray, C.A.; Patch, S.; Mielke, H.; Blaylock, M.J.

    2008-01-01

    Abatement of soil-lead hazards may also reduce human exposure to other soil toxins, thereby achieving significant collateral benefits that are not accounted for today. This proposition was tested with the specific case of soil-arsenic, where 1726 residential soil samples were collected and analyzed for lead and arsenic. The study found that these two toxins coexisted in most samples, but their concentrations were weakly correlated, reflecting the differing sources for each toxin. Collateral benefits of 9% would be achieved during abatement of the lead-contaminated soils having elevated arsenic concentrations. However, a hidden hazard of 16% was observed by overlooking elevated arsenic concentrations in soils having lead concentrations not requiring abatement. This study recommends that soil samples collected under HUD programs should be collected from areas of lead and arsenic deposition and tested for arsenic as well as lead, and that soil abatement decisions consider soil-arsenic as well as soil-lead guidelines. - Coexistence of arsenic at elevated concentrations with lead in residential soils undergoing lead hazard assessment is often overlooked, providing either collateral benefits or hidden hazards

  7. The cost of carbon abatement through community forest management in Nepal Himalaya

    NARCIS (Netherlands)

    Karky, B.S.; Skutsch, Margaret

    2010-01-01

    This paper estimates the economic returns to carbon abatement through biological sequestration in community managed forest under future REDD policy, and compares these for three possible management scenarios. For the estimation, the research relies on forest inventory data together with other

  8. Developing a Metric for the Cost of Green House Gas Abatement

    Science.gov (United States)

    2017-02-28

    The authors introduce the levelized cost of carbon (LCC), a metric that can be used to evaluate MassDOT CO2 abatement projects in terms of their cost-effectiveness. The study presents ways in which the metric can be used to rank projects. The data ar...

  9. Non-thermal plasmas for non-catalytic and catalytic VOC abatement

    International Nuclear Information System (INIS)

    Vandenbroucke, Arne M.; Morent, Rino; De Geyter, Nathalie; Leys, Christophe

    2011-01-01

    Highlights: → We review the current status of catalytic and non-catalytic VOC abatement based on a vast number of research papers. → The underlying mechanisms of plasma-catalysis for VOC abatement are discussed. → Critical process parameters that determine the influent are discussed and compared. - Abstract: This paper reviews recent achievements and the current status of non-thermal plasma (NTP) technology for the abatement of volatile organic compounds (VOCs). Many reactor configurations have been developed to generate a NTP at atmospheric pressure. Therefore in this review article, the principles of generating NTPs are outlined. Further on, this paper is divided in two equally important parts: plasma-alone and plasma-catalytic systems. Combination of NTP with heterogeneous catalysis has attracted increased attention in order to overcome the weaknesses of plasma-alone systems. An overview is given of the present understanding of the mechanisms involved in plasma-catalytic processes. In both parts (plasma-alone systems and plasma-catalysis), literature on the abatement of VOCs is reviewed in close detail. Special attention is given to the influence of critical process parameters on the removal process.

  10. Guidelines for Assessment and Abatement of Asbestos-Containing Materials in Buildings.

    Science.gov (United States)

    Pielert, James H.; Mathey, Robert G.

    This report presents guidelines, based on available information, for the assessment and abatement of asbestos-containing materials in buildings. Section 1 provides background information on the history and use of asbestos-containing products in buildings, the characteristics of asbestos fibers, products and materials containing asbestos, and…

  11. Award for Distinguished Professional Contributions to Applied Research: Luciano L'Abate

    Science.gov (United States)

    American Psychologist, 2009

    2009-01-01

    Luciano L'Abate, recipient of the Award for Distinguished Professional Contributions to Applied Research, contributed to applied research through the introduction of the laboratory method in clinical psychology assessment and intervention, leading to the development of the first automated playroom, linking play therapy with research in child…

  12. Inefficient national environmental regulation as a signal of high abatement costs

    Energy Technology Data Exchange (ETDEWEB)

    Steiner, U.

    1997-12-31

    This paper analyses the importance of informational asymmetries in international environmental regulation by use of a game theoretic approach of signaling games. More specific it analysis whether it is possible for a government to try to extract higher compensation in an international unidirectoral environmental problem. This may be possible when the national environmental regulation carries a signal of the cost of the regulated industry. In this case the government e.g. by means of inefficient environmental regulation on a national level may try to signal high abatement costs. In spite of the fact that many international environmental problems seem to be solvable by the use of financial payments there are only few examples that compensation payment arrangements have been implemented. As many countries and especially many polluting firms possess better information about abatement costs than the countries that receive the pollution, it is worthwhile to include asymmetric information. Consequently, this paper analyses whether the introduction of asymmetric information about abatement costs may bring forward incentives to misrepresent the true abatement cost in order to capture more compensation. If these incentives turn out to be present, it may explain some of the suspicion against using financial payment in order to induce other countries to join an agreement. The analysis shows that it may indeed be the case that the expected gain from cheating is so large that it gives incentives to use an inefficient national environmental policy. (au) 13 refs.

  13. Sustainable noise abatement along motorways in Germany – an empirical study in the municipality Frasdorf (Bavaria

    Directory of Open Access Journals (Sweden)

    Jürgen Breuste

    2014-09-01

    Full Text Available As part of the planned expansion work of the motorway A8 between Rosenheim and Salzburg and the associated legal opportunity to develop new traffic noise protection measures, this study investigated properties of sustainable noise abatement in a community next to the A8. A two-stage empirical survey was conducted integrating a citizen and an expert Delphi survey. The results show that the noise from the motorway heavily affects the quality of life in health, economic and ecological respects. Sustainable noise abatement should take into consideration ecological and social aspects like landscape integration and contribution to local development due to the unique location of the municipality. Enclosed motorway canopies are particularly beneficial to meet these criteria. The costs for sustainable noise abatement measures should be weighted as less important; however, financial costs are crucial for the federal government due to the requirements of the Federal Pollution Control Act. Hence, residents and experts assume that noise barriers as the cheaper noise abatement measures will be implemented. However, the results of the study and the latest developments in the expansion plans suggest that the implementation of enclosed motorway canopies, which go beyond the legal requirements, is feasible through extensive citizen participation and community-specific planning.

  14. The costs of mitigating carbon emissions in China: findings from China MARKAL-MACRO modeling

    International Nuclear Information System (INIS)

    Chen Wenying

    2005-01-01

    In this paper MARKAL-MACRO, an integrated energy-environment-economy model, is used to generate China's reference scenario for future energy development and carbon emission through the year 2050. The results show that with great efforts on structure adjustment, energy efficiency improvement and energy substitution, China's primary energy consumption is expected to be 4818 Mtce and carbon emission 2394 MtC by 2050 with annual decrease rate of 3% for the carbon intensity per GDP during the period 2000-2050. On the basis of this reference scenario, China's marginal abatement cost curves of carbon for the year 2010, 2020 and 2030 are derived from the model, and the impacts of carbon emission abatement on GDP are also simulated. The results are compared with those from other sources. The research shows that the marginal abatement costs vary from 12US$/tC to 216US$/tC and the rates of GDP losses relative to reference range from 0.1% to 2.54% for the reduction rates between 5% and 45%. Both the marginal abatement costs and the rates of GDP losses further enlarge on condition that the maximum capacity of nuclear power is constrained to 240 GW or 160 GW by 2050. The paper concludes that China's costs of carbon abatement is rather high in case of carbon emissions are further cut beyond the reference scenario, and China's carbon abatement room is limited due to her coal-dominant energy resource characteristic. As economic development still remains the priority and per capita income as well as per capita carbon emission are far below the world average, it will be more realistic for China to make continuous contributions to combating global climate change by implementing sustainable development strategy domestically and playing an active role in the international carbon mitigation cooperation mechanisms rather than accepting a carbon emission ceiling

  15. Simultaneous removal of sulfide, nitrate and acetate: Kinetic modeling

    International Nuclear Information System (INIS)

    Wang Aijie; Liu Chunshuang; Ren Nanqi; Han Hongjun; Lee Duujong

    2010-01-01

    Biological removal of sulfide, nitrate and chemical oxygen demand (COD) simultaneously from industrial wastewaters to elementary sulfur (S 0 ), N 2 , and CO 2 , or named the denitrifying sulfide (DSR) process, is a cost effective and environmentally friendly treatment process for high strength sulfide and nitrate laden organic wastewater. Kinetic model for the DSR process was established for the first time on the basis of Activated Sludge Model No. 1 (ASM1). The DSR experiments were conducted at influent sulfide concentrations of 200-800 mg/L, whose results calibrate the model parameters. The model correlates well with the DSR process dynamics. By introducing the switch function and the inhibition function, the competition between autotrophic and heterotrophic denitrifiers is quantitatively described and the degree of inhibition of sulfide on heterotrophic denitrifiers is realized. The model output indicates that the DSR reactor can work well at 0.5 1000 mg/L influent sulfide, however, the DSR system will break down.

  16. Microaeration for hydrogen sulfide removal in UASB reactor.

    Science.gov (United States)

    Krayzelova, Lucie; Bartacek, Jan; Kolesarova, Nina; Jenicek, Pavel

    2014-11-01

    The removal of hydrogen sulfide from biogas by microaeration was studied in Up-flow Anaerobic Sludge Blanket (UASB) reactors treating synthetic brewery wastewater. A fully anaerobic UASB reactor served as a control while air was dosed into a microaerobic UASB reactor (UMSB). After a year of operation, sulfur balance was described in both reactors. In UASB, sulfur was mainly presented in the effluent as sulfide (49%) and in biogas as hydrogen sulfide (34%). In UMSB, 74% of sulfur was detected in the effluent (41% being sulfide and 33% being elemental sulfur), 10% accumulated in headspace as elemental sulfur and 9% escaped in biogas as hydrogen sulfide. The efficiency of hydrogen sulfide removal in UMSB was on average 73%. Microaeration did not cause any decrease in COD removal or methanogenic activity in UMSB and the elemental sulfur produced by microaeration did not accumulate in granular sludge. Copyright © 2014 Elsevier Ltd. All rights reserved.

  17. Reduction of produced elementary sulfur in denitrifying sulfide removal process.

    Science.gov (United States)

    Zhou, Xu; Liu, Lihong; Chen, Chuan; Ren, Nanqi; Wang, Aijie; Lee, Duu-Jong

    2011-05-01

    Denitrifying sulfide removal (DSR) processes simultaneously convert sulfide, nitrate, and chemical oxygen demand from industrial wastewater into elemental sulfur, dinitrogen gas, and carbon dioxide, respectively. The failure of a DSR process is signaled by high concentrations of sulfide in reactor effluent. Conventionally, DSR reactor failure is blamed for overcompetition for heterotroph to autotroph communities. This study indicates that the elementary sulfur produced by oxidizing sulfide that is a recoverable resource from sulfide-laden wastewaters can be reduced back to sulfide by sulfur-reducing Methanobacterium sp. The Methanobacterium sp. was stimulated with excess organic carbon (acetate) when nitrite was completely consumed by heterotrophic denitrifiers. Adjusting hydraulic retention time of a DSR reactor when nitrite is completely consumed provides an additional control variable for maximizing DSR performance.

  18. Study on the sulfidation behavior of smithsonite

    Energy Technology Data Exchange (ETDEWEB)

    Wu, Dandan; Wen, Shuming, E-mail: shmwen@126.com; Deng, Jiushuai, E-mail: dengshuai689@163.com; Liu, Jian; Mao, Yingbo

    2015-02-28

    Highlights: • Zeta potential showed that the pH{sub IEP} of smithsonite decreased from 7.7 to 6. • ICP test showed the gradual reduction of C{sub S} in the solution. • SEM showed that the mineral surface was partially changed to ZnS film. • XPS indicated that the presence of a characteristic signal peak of sulfur ions. - Abstract: Zinc extraction from low-grade mineral resources of oxidized zinc has recently become a focus of study. Sulfidation is an important process in oxidized ore flotation. In this study, the influence of sulfur ion adsorption on smithsonite surface was investigated with the use of zeta potential, inductively coupled plasma (ICP), scanning electron microscope (SEM), and X-ray photoelectron spectroscopic studies. Zeta potential measurements of sodium sulfide showed that sulfur ions were adsorbed onto the surface of pure smithsonite, as evidenced by the increased negative charge and the decrease in the pH{sub IEP} of smithsonite from 7.7 to 6 after sodium sulfide treatment. The ICP test revealed the gradual reduction in sulfur ion adsorption onto the surface of smithsonite in pulp sulfur. After 30 min of absorption, C{sub S} in the solution declined from 1000 × 10{sup −6} mol/L to 1.4 × 10{sup −6} mol/L. SEM results showed that the mineral surface was partially changed to ZnS film after sodium sulfide treatment, whereas EDS analysis results showed that 2% S is contained on the smithsonite surface. X-ray photoelectron spectroscopy results indicated the presence of a characteristic signal peak of sulfur ions after sulfidation. Sulfur concentration increased to 11.89%, whereas oxygen concentration decreased from 42.31% to 13.74%. Sulfur ions were not only present during chemical adsorption, but were also incorporated into the crystal lattices of minerals by the exchange reaction between S{sup 2−} and CO{sub 3}{sup 2−} ions.

  19. Nanostructured silver sulfide: synthesis of various forms and their application

    Science.gov (United States)

    Sadovnikov, S. I.; Rempel, A. A.; Gusev, A. I.

    2018-04-01

    The results of experimental studies on nanostructured silver sulfide are analyzed and generalized. The influence of small particle size on nonstoichiometry of silver sulfide is discussed. Methods for the synthesis of various forms of nanostructured Ag2S including nanopowders, stable colloidal solutions, quantum dots, core–shell nanoparticles and heteronanostructures are described. The advantages and drawbacks of different synthetic procedures are analyzed. Main fields of application of nanostructured silver sulfide are considered. The bibliography includes 184 references.

  20. Carbon abatement potential of solar home systems in India and their cost reduction due to carbon finance

    International Nuclear Information System (INIS)

    Chaurey, A.; Kandpal, T.C.

    2009-01-01

    About 78 million rural households in India reportedly lack access to grid electricity. About 67 million of them use kerosene for lighting. Government of India is promoting the use of solar home systems (SHS) as one of the options for meeting lighting requirements in households in remote and less inhabited villages. About 363,399 SHS were reportedly disseminated across the country by December 2007. Apart from meeting the basic lighting need of the households, SHS also help in abating the emissions of green house gases (GHGs) by directly displacing the use of kerosene in households that currently use it for lighting. This study has attempted at estimating the CO 2 mitigation potential of SHS in India by studying the potential for their diffusion and the appropriate baseline. Subsequently, the scope for cost reduction to the user due to carbon finance, if received, is also studied. It is found that carbon finance could reduce the effective burden of SHS to the user by 19% if carbon prices were $10/tCO 2 and no transaction costs were involved in getting the carbon revenues. These benefits are also estimated for scenarios where transaction costs are incurred by the project proponent in getting the carbon benefits

  1. When we don't know the costs or the benefits: adaptive strategies for abating climate change

    International Nuclear Information System (INIS)

    Lempert, R.J.; Schlesinger, M.E.; Bankes, S.C.

    1996-01-01

    Most quantitative studies of climate-change policy attempt to predict the greenhouse-gas reduction plan that will have the optimum balance of long-term costs and benefits. The authors find that the large uncertainties associated with the climate-change problem can make the policy prescriptions of this traditional approach unreliable. In this study the authors construct a large uncertainty space that includes the possibility of large and/or abrupt climate changes and/or of technology breakthroughs that radically reduce projected abatement costs. Computational experiments are used on a linked system of climate and economic models to compare the performance of a simple adaptive strategy - one that can make midcourse corrections based on observations of the climate and economic systems - and two commonly advocated 'best-estimate' policies based on different expectations about the long-term consequences of climate change. It was found that the 'Do-a-Little' and 'Emissions-Stabilization' best-estimate policies perform well in the respective regions of the uncertainty space where their estimates are valid, but can fail severely in those regions where their estimates are wrong. In contrast, the adaptive strategy can make midcourse corrections and avoid significant errors. While its success is no surprise, the adaptive-strategy approach provides an analytic framework to examine important policy and research issues that will likely arise as society adapts to climate change, which cannot be easily addressed in studies using best-estimate approaches. 44 refs., 15 figs., 3 tabs

  2. A sensitivity analysis of process design parameters, commodity prices and robustness on the economics of odour abatement technologies.

    Science.gov (United States)

    Estrada, José M; Kraakman, N J R Bart; Lebrero, Raquel; Muñoz, Raúl

    2012-01-01

    The sensitivity of the economics of the five most commonly applied odour abatement technologies (biofiltration, biotrickling filtration, activated carbon adsorption, chemical scrubbing and a hybrid technology consisting of a biotrickling filter coupled with carbon adsorption) towards design parameters and commodity prices was evaluated. Besides, the influence of the geographical location on the Net Present Value calculated for a 20 years lifespan (NPV20) of each technology and its robustness towards typical process fluctuations and operational upsets were also assessed. This comparative analysis showed that biological techniques present lower operating costs (up to 6 times) and lower sensitivity than their physical/chemical counterparts, with the packing material being the key parameter affecting their operating costs (40-50% of the total operating costs). The use of recycled or partially treated water (e.g. secondary effluent in wastewater treatment plants) offers an opportunity to significantly reduce costs in biological techniques. Physical/chemical technologies present a high sensitivity towards H2S concentration, which is an important drawback due to the fluctuating nature of malodorous emissions. The geographical analysis evidenced high NPV20 variations around the world for all the technologies evaluated, but despite the differences in wage and price levels, biofiltration and biotrickling filtration are always the most cost-efficient alternatives (NPV20). When, in an economical evaluation, the robustness is as relevant as the overall costs (NPV20), the hybrid technology would move up next to BTF as the most preferred technologies. Copyright © 2012 Elsevier Inc. All rights reserved.

  3. [Estimate the abatement rate of septic tank sewage outfall soil on nitrogen pollutants of typical farmer household sewage].

    Science.gov (United States)

    Zhou, Feng; Wang, Wen-Lin; Wang, Guo-Xiang; Ma, Jiu-Yuan; Wan, Yin-Jing; Tang, Xiao-Yan; Liang, Bin; Ji, Bin

    2013-10-01

    The surface soil on sewage outfall and effluent of farmer household septic tank were collected in situ from the typical region of plain river network areas in Taihu Lake Basin, and the typical rainfall (summer 30 mm . times-1, winter 5 mm times -1), temperature (summer 27 degrees C, winter 5 degrees C ) condition and pollutant load were artificial simulated by indoor simulation soil column experiments for estimating nitrogen abatement rate of rural sewage treated by the outfall soil and exploring the abatement rule in different seasons and weather process (7 days before the rain, 3 rainy days, 7 days after the rain). Results showed that: there was the significant difference (P 0. 05). Therefore, the TN, NH+4 -N abatement rate, NO-3 -N increase rate need to be divided by seasons, TN abatement rate, NO-3 -N increase rate of summer need to be divided by the weather process, which were 38.5% , - 25.0% , 46. 0% and 478. 1%, 913.8%, 382. 0% , before the rain, in rainy day, after the rain, respectively; while the NH+4 -N abatement rate of summer and the TN, NH+4 -N abatement rate, NO-3 -N increase rate of winter do not need to be divided by weather process, were 91.7% , 50.4% , 85.5% and 276.0% , respectively. In the summer, the TN abatement rate in different weather processes was not correlated with NH+4 -N abatement rate, but significantly negative correlated with NO-3 -N increase rate. In the winter, the stable accumulation of TN in soil was an important reason of the TN abatement rate which had no significant difference and kept a high level among different weather processes, and it was closely related to the stable accumulation of NH+4 -N in soil.

  4. Project 'European Research Center for Air Pollution Abatement Measures'

    International Nuclear Information System (INIS)

    1985-04-01

    During the 5-7th of March 1985 the first status report of the project 'European Research Center for Air Pollution Control Measures' took place in the Nuclear Research Center, Karlsruhe. Progress reports on the following topics assessment and analysis of the impacts of airborne pollutants on forest trees; distinction from other potential causes of recent forest dieback, research into atmospheric dispersion, conversion and deposition of airborne pollutants, development and optimization of industrial-technical processes to reduce or avoid emissions and providing instruments and making recommendations to the industrial and political sectors were presented. This volume is a collection of the work reported there. 42 papers were entered separately. (orig./MG) [de

  5. Carbon steel protection in G.S. (Girlder sulfide) plants. Iron sulfide scales formation conditions. Pt. 1

    International Nuclear Information System (INIS)

    Bruzzoni, P.; Burkart, A.L.; Garavaglia, R.N.

    1981-11-01

    An ASTM A 516 degree 60 carbon steel superficial protection technique submitted to a hydrogen-water sulfide corrosive medium at 2 MPa of pressure and 40-125 deg C forming on itself an iron sulfide layer was tested. Studies on pH influence, temperature, passivating mean characteristics and exposure time as well as the mechanical resistance of sulfide layers to erosion are included. (Author) [es

  6. Economic growth and carbon emission control

    Science.gov (United States)

    Zhang, Zhenyu

    The question about whether environmental improvement is compatible with continued economic growth remains unclear and requires further study in a specific context. This study intends to provide insight on the potential for carbon emissions control in the absence of international agreement, and connect the empirical analysis with theoretical framework. The Chinese electricity generation sector is used as a case study to demonstrate the problem. Both social planner and private problems are examined to derive the conditions that define the optimal level of production and pollution. The private problem will be demonstrated under the emission regulation using an emission tax, an input tax and an abatement subsidy respectively. The social optimal emission flow is imposed into the private problem. To provide tractable analytical results, a Cobb-Douglas type production function is used to describe the joint production process of the desired output and undesired output (i.e., electricity and emissions). A modified Hamiltonian approach is employed to solve the system and the steady state solutions are examined for policy implications. The theoretical analysis suggests that the ratio of emissions to desired output (refer to 'emission factor'), is a function of productive capital and other parameters. The finding of non-constant emission factor shows that reducing emissions without further cutting back the production of desired outputs is feasible under some circumstances. Rather than an ad hoc specification, the optimal conditions derived from our theoretical framework are used to examine the relationship between desired output and emission level. Data comes from the China Statistical Yearbook and China Electric Power Yearbook and provincial information of electricity generation for the year of 1993-2003 are used to estimate the Cobb-Douglas type joint production by the full information maximum likelihood (FIML) method. The empirical analysis shed light on the optimal

  7. 76 FR 64022 - Hydrogen Sulfide; Community Right-to-Know Toxic Chemical Release Reporting

    Science.gov (United States)

    2011-10-17

    ... Hydrogen Sulfide; Community Right-to-Know Toxic Chemical Release Reporting AGENCY: Environmental Protection Agency (EPA). ACTION: Lifting of Administrative Stay for Hydrogen Sulfide. SUMMARY: EPA is announcing... (EPCRA) section 313 toxic chemical release reporting requirements for hydrogen sulfide (Chemical...

  8. Abatement costs of soil conservation in China's Loess Plateau: balancing income with conservation in an agricultural system.

    Science.gov (United States)

    Hou, Lingling; Hoag, Dana L K; Keske, Catherine M H

    2015-02-01

    This study proposes the use of marginal abatement cost curves to calculate environmental damages of agricultural systems in China's Loess Plateau. Total system costs and revenues, management characteristics and pollution attributes are imputed into a directional output distance function, which is then used to determine shadow prices and abatement cost curves for soil and nitrogen loss. Marginal abatement costs curves are an effective way to compare economic and conservation tradeoffs when field-specific data are scarce. The results show that sustainable agricultural practices can balance soil conservation and agricultural production; land need not be retired, as is current policy. Published by Elsevier Ltd.

  9. 4th international exhaust gas and particulate emissions forum. Proceedings; 4. internationales FORUM Abgas- und Partikelemissionen. Beitraege

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    2006-07-01

    Lectures of the conference addressed the following topics: European and US American pollution regulations, particulate measuring systems, emission factors for vehicles, particulate emission abatement through simulation and optimization, selective catalytic reduction in heavy duty diesel trucks, filters, combustion properties, performance assessment, contribution of biofuels. (uke)

  10. Simulating the effect of forces pit ventilation on ammonia emission from naturally ventilated cow houses with CFD

    NARCIS (Netherlands)

    Sapounas, A.; Campen, J.B.; Smits, M.C.J.; Dooren, van H.J.C.

    2009-01-01

    Atmospheric NH3, mainly originates from agricultural sources, can cause serious environmental problems related to eutrophication and soil acidification. Emissions from dairy houses are 15% of total agricultural NH3 emissions. Due to open buildings, existing abatement options are limited. Pit air

  11. Optical Analysis of Iron-Doped Lead Sulfide Thin Films for Opto-Electronic Applications

    Science.gov (United States)

    Chidambara Kumar, K. N.; Khadeer Pasha, S. K.; Deshmukh, Kalim; Chidambaram, K.; Shakil Muhammad, G.

    Iron-doped lead sulfide thin films were deposited on glass substrates using successive ionic layer adsorption and reaction method (SILAR) at room temperature. The X-ray diffraction pattern of the film shows a well formed crystalline thin film with face-centered cubic structure along the preferential orientation (1 1 1). The lattice constant is determined using Nelson Riley plots. Using X-ray broadening, the crystallite size is determined by Scherrer formula. Morphology of the thin film was studied using a scanning electron microscope. The optical properties of the film were investigated using a UV-vis spectrophotometer. We observed an increase in the optical band gap from 2.45 to 3.03eV after doping iron in the lead sulfide thin film. The cutoff wavelength lies in the visible region, and hence the grown thin films can be used for optoelectronic and sensor applications. The results from the photoluminescence study show the emission at 500-720nm. The vibrating sample magnetometer measurements confirmed that the lead sulfide thin film becomes weakly ferromagnetic material after doping with iron.

  12. Iron sulfide crystal growth: a literature review

    International Nuclear Information System (INIS)

    Dewar, E.J.

    1977-04-01

    Iron pyrite (FeS 2 ) is often found on trays and in heat exchangers in Girdler-Sulfide (G.S.) plants used to extract D 2 O from fresh water. A critical review of the literature was made to find: (i) what is known about FeS 2 crystal growth; (ii) which techniques could be used to study FeS 2 crystal growth experimentally; (iii) potential chemical additives that could be used in trace amounts to poison FeS 2 crystals and reduce their growth rate in G.S. plants. (author)

  13. Sulfide geochronlogy along the Southwest Indian Ridge

    Science.gov (United States)

    Yang, W.; Tao, C.; Li, H.; Liang, J.; Liao, S.

    2017-12-01

    Dragon Flag and Duanqiao hydrothermal field is located between the Indomed and Gallieni fracture zones in the ultraslow-spreading Southwest Indian Ridge (SWIR). Ten subsamples from active and inactive vents of Dragon Flag hydrothermal field and twenty-eight subsamples from Duanqiao hydrothermal field were dated using the 230Th/238U method. Four main episodes of hydrothermal activity of Duanqiao were determined according to the restricted results: 68.9-84.3, 43.9-48.4, 25.3-34.8, and 0.7-17.3 kyrs. Hydrothermal activity of Duanqiao probably started about 84.3 (±0.5) kyrs ago and ceased about 0.737 (±0.023) kyrs ago. And sulfide samples from the nearby Dragon Flag filed at the same time and the results show that the ages of most sulfides from Dragon Flag field range from 1.496(±0.176) to 5.416 (±0.116) kyrs with the oldest age estimated at 15.997 (±0.155) kyrs Münch et al. (2001) reconstructed the evolution history of Mt. Jourdanne hydrothermal field. The age dating results indicate activity in two episodes, at 70-40 and 27-13 kyrs. The hydrothermal activity in Dragon Flag field is much more recent than that of Duanqiao or Mt. Jourdanne fields. The massive sulfides are younger than the sulfides from other hydrothermal fields such as Rainbow, Sonne and Ashadze-2. All these results suggest that hydrothermal activity of Dragon Flag field is much more recent than that of Duanqiao or Mt. Jourdanne fields. Mt. Jourdanne is situated on an axial volcanic ridge which has both volcanic and tectonic activity. This is necessary to develop the heat source and pathways for the fluid convection, which enables the hydrothermal circulation. Hydrothermal activity in Dragon Flag Field is located next to the detachment fault termination. The detachment fault system provides a pathway for hydrothermal convection. Such style of heat source can contribute to continuous hydrothermal activity for over 1000 years. Duanqiao field is located near the central volcano and there is a hot

  14. Hydrogen sulfide flux measurements from construction and demolition debris (C&D) landfills.

    Science.gov (United States)

    Eun, Sangho; Reinhart, Debra R; Cooper, C David; Townsend, Timothy G; Faour, Ayman

    2007-01-01

    Hydrogen sulfide (H2S) has been identified as a principal odorous component of gaseous emissions from construction and demolition debris (C&D) landfills. Although several studies have reported the ambient concentrations of H2S near C&D landfills, few studies have quantified emission rates of H2S. One of the most widely used techniques for measuring surface gas emission rates from landfills is the flux chamber method. Flux measurements using the flux chamber were performed at five different C&D landfills from April to August, 2003. The flux rates of H2S measured in this research were between 0.192 and 1.76 mg/(m2-d).

  15. Emission Trading under the Kyoto Protocol

    Energy Technology Data Exchange (ETDEWEB)

    Holtsmark, Bjart; Hagem, Cathrine

    1998-12-01

    This report discusses the potential gains from emission trading and raises some crucial questions. It shows that the total costs of the Kyoto Protocol could be reduced by about 95% through emission trading. Emission trading is an option also in the domestic arenas. The governments of the Annex B countries may allocate emission quotas to local enterprises as emission permits. Thus new markets for greenhouse gas emission quotas may emerge, domestically and internationally. It is emphasized that emission trading at the national and international levels must be discussed separately. The Nordic governments, for example, will find several good reasons for supporting emission trading at the international level if not necessarily domestically. The Nordic countries have already implemented domestic taxes on CO{sub 2} emissions and this tax policy could be sustained while these governments support and take part in emission trading at the international level.The report also considers a possible side effect of emission trading: free emission trading among Annex B countries could reduce the total abatement compared to a non-tradable policy as a consequence of the fact that some of the countries that are in transition to a market economy may be given emission limitations above their business-as-usual emissions. 40 refs., 7 figs., 4 tabs.

  16. International conventions on air pollution abatement. Implementation measures

    International Nuclear Information System (INIS)

    Adler, S.; Groza, L.

    1996-01-01

    The environmental protection, the pollution reduction, their positive direct and indirect effects, the energy efficiency increase in using fossil fuels have an important role on the environmental and energy policies, as well as on the long-term planning. The report presents, under the new legislative context, the general frame from the implementation of concrete actions to fulfill the commitments contained in different environmental conventions, in which Romania is or intends to be a part. In this context it is presented the national approach for the implementation of two conventions: the United Nations Framework Convention on Climate Change and the Long-Range Transboundary Air Pollution, this under the United Nations Economic Commission for Europe. The report presents the necessary measures to reduce the emissions of carbon, sulfur and nitrogen oxides taking into account the process of the Romanian integration in the European structure as well as the dynamic of the economic reform. Romania is aware that the necessary environmental activities (research, design, environmental investments etc.) must be financed from internal resources, the own resources of the polluting economic units, the central and local budgets. (author). 7 refs

  17. INHALATIONAL EXPOSURE TO CARBONYL SULFIDE (COS) PRODUCES BRAIN LESIONS AND ALTERED BRAINSTEM AUDITORY (BAER) AND SOMATOSENSORY (SEP) EVOKED POTENTIALS IN FISHCER 344N RATS.

    Science.gov (United States)

    Because of the amount of carbonyl sulfide (COS) emissions and the lack of toxicological data, COS was listed in the Clean Air Act of 1990 as a Hazardous Air Pollutant. In 1999 COS was nominated by the US EPA to the National Toxicology Program for additional toxicological investig...

  18. Removal of Hydrogen Sulfide from Septic Tank by Vermicomposting Bio Filter

    Directory of Open Access Journals (Sweden)

    Abdol Kazem Neisi

    2016-09-01

    Full Text Available Background & Aims of the Study: Hydrogen sulfide (H2S is a colorless and highly toxic, easily dissolved in water, flammable and explosive gas. Hydrogen sulfide gas is the main cause of odor emissions from municipal sewage plants. One method for removal of hydrogen sulfide gas is the use of biological systems, biofilter. The aim of this study was to survey removal hydrogen sulfide provide in septic tank by vermicomposting biofilter. Materials and Methods: In this study pilot-scale biofilter has been made of bed vermicompost and wood trash. To survey biofilter performance under real condition, the pilot installed in one wastewater pumping station of Ahwaz city, Iran. The study was carried out over 80 days. Inlet and outlet H2S concentration were measured on regular basis. To provide an optimal condition for bacterial growth, moisture was adjusted between 40% and 60% throughout the experiment. Results: Results showed that H2S concentration emitted from the pumping station during the study varied greatly between 33 and 54ppm .The maximum adsorption capacity of the biological bedding was recorded at 22.4 g/m3.hr and the mean efficiency of H2S removal account the startup time was 89.31% .The mean performance efficiency during the biological activity after the startup was recorded at 96.88%. Conclusion: use up biofilter with vermicompost bed and woodchip is an economic method for H2S removal of septic tanks. Removal efficiency of more than 96% is expected with this method.

  19. The timing of pollution abatement investments and the business cycle. An international comparison

    Energy Technology Data Exchange (ETDEWEB)

    Bouman, M. [Department of Economics, Faculty of Economics and Econometrics, University of Amsterdam, Amsterdam (Netherlands); Hofkes, M.W. [Department of Economics, Faculty of Economics and Econometrics, Vrije Universiteit Amsterdam, Amsterdam (Netherlands)

    1995-12-31

    A simple equilibrium business-cycle model for an economy with both clean- and dirty-producing plants is developed. The authors derive that the optimal timing of cleaning the production process is during a slowdown of the economy. Due to external effects and market failures the timing of pollution abatement investments is not expected to be optimal in the real world. We test the optimality of the timing of those investments with data for Germany, the Netherlands and the U.S.A. It appears that for more than 25 percent of the sectors pollution abatement investments show counter-cyclical behaviour, while in only one sector these investments are pro-cyclical. 1 tab., 3 appendices, 10 refs.

  20. Research on the application of active sound barriers for the transformer noise abatement

    Directory of Open Access Journals (Sweden)

    Hu Sheng

    2016-01-01

    Full Text Available Sound barriers are a type of measure most commonly used in the noise abatement of transformers. In the noise abatement project of substations, the design of sound barriers is restrained by the portal frames which are used to hold up outgoing lines from the main transformers, which impacts the noise reduction effect. If active sound barriers are utilized in these places, the noise diffraction of sound barriers can be effectively reduced. At a 110kV Substation, an experiment using a 15-channel active sound barrier has been carried out. The result of the experiment shows that the mean noise reduction value (MNRV of the noise measuring points at the substation boundary are 1.5 dB (A. The effect of the active noise control system is impacted by the layout of the active noise control system, the acoustic environment on site and the spectral characteristic of the target area.

  1. The timing of pollution abatement investments and the business cycle. An international comparison

    International Nuclear Information System (INIS)

    Bouman, M.; Hofkes, M.W.

    1995-01-01

    A simple equilibrium business-cycle model for an economy with both clean- and dirty-producing plants is developed. The authors derive that the optimal timing of cleaning the production process is during a slowdown of the economy. Due to external effects and market failures the timing of pollution abatement investments is not expected to be optimal in the real world. We test the optimality of the timing of those investments with data for Germany, the Netherlands and the U.S.A. It appears that for more than 25 percent of the sectors pollution abatement investments show counter-cyclical behaviour, while in only one sector these investments are pro-cyclical. 1 tab., 3 appendices, 10 refs

  2. Fluxo do transporte de suínos para abate no Estado de Mato Grosso

    OpenAIRE

    Pereira,Thuanny Lúcia; Corassa,Anderson

    2014-01-01

    Objetivou-se descrever o fluxo de suínos para abate produzidos no Estado de Mato Grosso entre os anos de 2008 e 2012. Foram utilizados dados de 9.426.729 suínos produzidos no Estado de Mato Grosso e transportados para abate de janeiro de 2008 a dezembro de 2012, no qual realizou-se análise descritiva das informações, com frequências de origem e destino; machos e fêmeas em função dos meses e anos e as distâncias percorridas. Observou-se crescimento no número de viagens e de suínos transportado...

  3. Microbial selenium sulfide reduction for selenium recovery from wastewater

    NARCIS (Netherlands)

    Hageman, S.P.W.; Weijden, van der R.D.; Stams, A.J.M.; Cappellen, van P.; Buisman, C.J.N.

    2017-01-01

    Microbial reduction of selenium sulfide (SeS2) is a key step in a new treatment process to recover selenium from selenate and selenite streams. In this process, selenate is first reduced to selenite, and subsequently selenite is reduced by sulfide and precipitates from the solution as SeS2. The

  4. Recent findings on sinks for sulfide in gravity sewer networks

    DEFF Research Database (Denmark)

    Nielsen, Asbjørn Haaning; Hvitved-Jacobsen, Thorkild; Vollertsen, Jes

    2006-01-01

    summarizes this newly obtained knowledge and emphasizes important implications of the findings. Model simulations of the in-sewer processes important for the sulfur cycle showed that sulfide oxidation in the wetted biofilm is typically the most important sink for dissolved sulfide in gravity sewers. However...

  5. Technetium behavior in sulfide and ferrous iron solutions

    International Nuclear Information System (INIS)

    Lee, S.Y.; Bondietti, E.A.

    1982-01-01

    Pertechnetate oxyanion ( 99 TcO 4- ), a potentially mobile species in leachate from a breached radioactive waste repository, was removed from a brine solution by precipitation with sulfide, iron, and ferrous sulfide at environmental pH's. Maghemite (ν-Fe 2 O 3 ) and geothite (α-FeOOH) were the dominant minerals in the precipitate obtained from the TcO 4- -ferrous iron reaction. The observation of small particle size and poor crystallinity of the minerals formed in the presence of Tc suggested that the Tc was incorporated into the mineral structure after reduction to a lower valence state. Amorphous ferrous sulfide, an initial phase precipitating in the TcO 4- -ferrous iron-sulfide reaction, was transformed to goethite and hematite (α-Fe 2 O 3 ) on aging. The black precipitate obtained from the TcO 4- -sulfide reaction was poorly crystallized technetium sulfide (Tc 2 S 7 ) which was insoluble in both acid and alkaline solution in the absence of strong oxidents. The results suggested that ferrous- and/or sulfide-bearing groundwaters and minerals in host rocks or backfill barriers could reduce the mobility of Tc through the formation of less-soluble Tc-bearing iron and/or sulfide minerals

  6. Sulfidation of carbon-supported iron oxide catalysts

    NARCIS (Netherlands)

    Ramselaar, W.L.T.M.; Hadders, R.H.; Gerkema, E.; Beer, de V.H.J.; Oers, van E.M.; Kraan, van der A.M.

    1989-01-01

    The sulfidation of carbon-supported iron oxide catalysts was studied by means of in-situ Mössbauer spectroscopy at temperatures down to 4.2 K. The catalysts were dried in two different ways and then sulfided in a flow of 10% H2S in H2 at temperatures between 293 and 773 K. Thiophene

  7. The Incidence of Local Water Pollution Abatement Expenditures: A Case Study of the Merrimack River Basin (1974)

    Science.gov (United States)

    Part I is an analysis of the determinants of local government expenditures on water pollution abatement facilities. Part II is an investigation of the incidence of costs and benefits of public environmental programs.

  8. Microwave-assisted hydrothermal synthesis of biocompatible silver sulfide nanoworms

    Science.gov (United States)

    Xing, Ruimin; Liu, Shanhu; Tian, Shufang

    2011-10-01

    In this study, silver sulfide nanoworms were prepared via a rapid microwave-assisted hydrothermal method by reacting silver nitrate and thioacetamide in the aqueous solution of the Bovine Serum Albumin (BSA) protein. The morphology, composition, and crystallinity of the nanoworms were characterized by field emission scanning electron microscopy (FESEM), X-ray powder diffraction (XRD), transmission electron microscopy (TEM), selected area electron diffraction (SAED), X-ray energy dispersive spectroscopy (EDS), and Fourier transform infrared (FTIR) spectroscopy. The results show that the nanoworms were assembled by multiple adjacent Ag2S nanoparticles and stabilized by a layer of BSA attached to their surface. The nanoworms have the sizes of about 50 nm in diameter and hundreds of nanometers in length. The analyses of high-resolution TEM and their correlative Fast Fourier Transform (FFT) indicate that the adjacent Ag2S nanoparticles grow by misoriented attachment at the connective interfaces to form the nanoworm structure. In vitro assays on the human cervical cancer cell line HeLa show that the nanoworms exhibit good biocompatibility due to the presence of BSA coating. This combination of features makes the nanoworms attractive and promising building blocks for advanced materials and devices.

  9. Population growth, energy consumption, pollution abatement - looking for the global consensus

    International Nuclear Information System (INIS)

    Czakainski, M.

    1993-01-01

    A new system of the world for solutions to the energy supply problem was damanded by the representatives of China and India at the Madrid congress of the World Energy Council. Drastic energy conservation measures were requested from the Western World. It is still a long way to go to a global consensus about energy consumption, pollution abatement and the protection of the climate. (DG) [de

  10. Socio-economic impact analysis: Centralia mine fire abatement alternatives. Draft report

    Energy Technology Data Exchange (ETDEWEB)

    1980-11-07

    The overall purpose of information contained in the following text is to document the likely social and economic impacts upon the Borough of Centralia through implementation of various mine fire abatement alternatives. Much of the data presented herein and utilized in preparing conclusions and recommendations have been derived from those individuals whose lives are now, or may eventually be, impacted by the underground mine fire.

  11. "'Advantage of Late-comer' in Abating Air-Pollution: Experience in East Asia" (in Japanese)

    OpenAIRE

    Toru Iwami

    2001-01-01

    From the early 1970s to the mid-1980s, air-pollution in Japan, in particular SO2 concentration, was remarkably improved. This is resulted from responses to growing civil protests: governmental regulation policy, on the one hand, and innovation of abating technology and energy efficiency, on the other hand. In Southeast Asian large cities, air-pollution is in better situation, despite their rapid economic growth, than their Japanese counterpart in the early 1970s. This is because their governm...

  12. Health and housing collaboration at LAST: the Philadelphia Lead Abatement Strike Team.

    OpenAIRE

    Campbell, Carla; Himmelsbach, Robert; Palermo, Peter; Tobin, Richard

    2005-01-01

    The Lead Abatement Strike Team (LAST) was developed in 2002 by the Philadelphia Department of Public Health (PDPH) in response to community concern about management of children with elevated blood lead levels (EBLLs). Fourteen hundred backlog properties (housing at least one child with EBLLs) were identified through inspection as having housing-based lead hazards for which no satisfactory environmental remediation (control of lead hazards) had been achieved. In the first two years of LAST, 83...

  13. 4-aminobutyrate aminotransferase (ABAT: genetic and pharmacological evidence for an involvement in gastro esophageal reflux disease.

    Directory of Open Access Journals (Sweden)

    Johan Jirholt

    Full Text Available Gastro-esophageal reflux disease (GERD is partly caused by genetic factors. The underlying susceptibility genes are currently unknown, with the exception of COL3A1. We used three independent GERD patient cohorts to identify GERD susceptibility genes. Thirty-six families, demonstrating dominant transmission of GERD were subjected to whole genome microsatellite genotyping and linkage analysis. Five linked regions were identified. Two families shared a linked region (LOD 3.9 and 2.0 on chromosome 16. We used two additional independent GERD patient cohorts, one consisting of 219 trios (affected child with parents and the other an adult GERD case control cohort consisting of 256 cases and 485 controls, to validate individual genes in the linked region through association analysis. Sixty six single nucleotide polymorphism (SNP markers distributed over the nine genes present in the linked region were genotyped in the independent GERD trio cohort. Transmission disequilibrium test analysis followed by multiple testing adjustments revealed a significant genetic association for one SNP located in an intron of the gene 4-aminobutyrate aminotransferase (ABAT (P(adj = 0.027. This association did not replicate in the adult case-control cohort, possibly due to the differences in ethnicity between the cohorts. Finally, using the selective ABAT inhibitor vigabatrin (γ-vinyl GABA in a dog study, we were able to show a reduction of transient lower esophageal sphincter relaxations (TLESRs by 57.3 ± 11.4 % (p = 0.007 and the reflux events from 3.1 ± 0.4 to 0.8 ± 0.4 (p = 0.007. Our results demonstrate the direct involvement of ABAT in pathways affecting lower esophageal sphincter (LES control and identifies ABAT as a genetic risk factor for GERD.

  14. 4-aminobutyrate aminotransferase (ABAT): genetic and pharmacological evidence for an involvement in gastro esophageal reflux disease.

    Science.gov (United States)

    Jirholt, Johan; Asling, Bengt; Hammond, Paul; Davidson, Geoffrey; Knutsson, Mikael; Walentinsson, Anna; Jensen, Jörgen M; Lehmann, Anders; Agreus, Lars; Lagerström-Fermer, Maria

    2011-04-28

    Gastro-esophageal reflux disease (GERD) is partly caused by genetic factors. The underlying susceptibility genes are currently unknown, with the exception of COL3A1. We used three independent GERD patient cohorts to identify GERD susceptibility genes. Thirty-six families, demonstrating dominant transmission of GERD were subjected to whole genome microsatellite genotyping and linkage analysis. Five linked regions were identified. Two families shared a linked region (LOD 3.9 and 2.0) on chromosome 16. We used two additional independent GERD patient cohorts, one consisting of 219 trios (affected child with parents) and the other an adult GERD case control cohort consisting of 256 cases and 485 controls, to validate individual genes in the linked region through association analysis. Sixty six single nucleotide polymorphism (SNP) markers distributed over the nine genes present in the linked region were genotyped in the independent GERD trio cohort. Transmission disequilibrium test analysis followed by multiple testing adjustments revealed a significant genetic association for one SNP located in an intron of the gene 4-aminobutyrate aminotransferase (ABAT) (P(adj) = 0.027). This association did not replicate in the adult case-control cohort, possibly due to the differences in ethnicity between the cohorts. Finally, using the selective ABAT inhibitor vigabatrin (γ-vinyl GABA) in a dog study, we were able to show a reduction of transient lower esophageal sphincter relaxations (TLESRs) by 57.3 ± 11.4 % (p = 0.007) and the reflux events from 3.1 ± 0.4 to 0.8 ± 0.4 (p = 0.007). Our results demonstrate the direct involvement of ABAT in pathways affecting lower esophageal sphincter (LES) control and identifies ABAT as a genetic risk factor for GERD.

  15. Influence of Water Salinity on Air Purification from Hydrogen Sulfide

    Directory of Open Access Journals (Sweden)

    Leybovych L.I.

    2015-12-01

    Full Text Available Mathematical modeling of «sliding» water drop motion in the air flow was performed in software package FlowVision. The result of mathematical modeling of water motion in a droplet with diameter 100 microns at the «sliding» velocity of 15 m/s is shown. It is established that hydrogen sulfide oxidation occurs at the surface of phases contact. The schematic diagram of the experimental setup for studying air purification from hydrogen sulfide is shown. The results of the experimental research of hydrogen sulfide oxidation by tap and distilled water are presented. The dependence determining the share of hydrogen sulfide oxidized at the surface of phases contact from the dimensionless initial concentration of hydrogen sulfide in the air has been obtained.

  16. Sulindac Sulfide, but Not Sulindac Sulfone, Inhibits Colorectal Cancer Growth

    Directory of Open Access Journals (Sweden)

    Christopher S. Williams

    1999-06-01

    Full Text Available Sulindac sulfide, a metabolite of the nonsteroidal antiinflammatory drug (NSAID sulindac sulfoxide, is effective at reducing tumor burden in both familial adenomatous polyposis patients and in animals with colorectal cancer. Another sulindac sulfoxide metabolite, sulindac sulfone, has been reported to have antitumor properties without inhibiting cyclooxygenase activity. Here we report the effect of sulindac sulfone treatment on the growth of colorectal carcinoma cells. We observed that sulindac sulfide or sulfone treatment of HCA-7 cells led to inhibition of prostaglandin E2 production. Both sulindac sulfide and sulfone inhibited HCA-7 and HCT-116 cell growth in vitro. Sulindac sulfone had no effect on the growth of either HCA-7 or HCT-116 xenografts, whereas the sulfide derivative inhibited HCA-7 growth in vivo. Both sulindac sulfide and sulfone inhibited colon carcinoma cell growth and prostaglandin production in vitro, but sulindac sulfone had no effect on the growth of colon cancer cell xenografts in nude mice.

  17. Oxidation and Precipitation of Sulfide in Sewer Networks

    DEFF Research Database (Denmark)

    Nielsen, A. H.

    risks and corrosion of concrete and metals. Most of the problems relate to the buildup of hydrogen sulfide in the atmosphere of sewer networks. In this respect, the processes of the sulfur cycle are of fundamental importance in ultimately determining the extent of such problems. This study focused...... calibrated and validated against field data. In the extension to the WATS model, sulfur transformations were described by six processes: 1. Sulfide production taking place in the biofilm and sediments covering the permanently wetted sewer walls; 2. Biological sulfide oxidation in the permanently wetted...... to the sewer atmosphere, potentially resulting in concrete corrosion. The extended WATS model represents a major improvement over previously developed models for prediction of sulfide buildup in sewer networks. Compared to such models, the major processes governing sulfide buildup in sewer networks...

  18. Kinetic Spectrophotometric Determination of Trace Amounts of Sulfide

    Energy Technology Data Exchange (ETDEWEB)

    Barzegar, Mohsen [Tarbiat Modarres University, Tehran (Iran, Islamic Republic of); Jabbari, Ali [K. N. Toosi University, Tehran (Iran, Islamic Republic of); Esmaeili, Majid [Razi University, Kermanshah (Iran, Islamic Republic of)

    2003-09-15

    A method for the determination of trace amount of sulfide based on the addition reaction of sulfide with methyl green at pH 7.5 and 25 .deg. C is described. The reaction is monitored spectrophotometrically by measuring the decrease in absorbance of the dyestuff at 637 nm by the initial rate and fixed time method. The calibration graph is linear in the range 30-1200 ppb. The theoretical limit of detection was 0.014 ppm. Seven replicate analysis of a sample solution containing 0.70 ppm sulfide gave a relative standard deviation of 1.5%. The interfering effects of various ions on sulfide determination have been reported and procedures for removal of interference have been described. The proposed method was applied successfully to the determination of sulfide in tap and wastewater samples.

  19. Kinetic Spectrophotometric Determination of Trace Amounts of Sulfide

    International Nuclear Information System (INIS)

    Barzegar, Mohsen; Jabbari, Ali; Esmaeili, Majid

    2003-01-01

    A method for the determination of trace amount of sulfide based on the addition reaction of sulfide with methyl green at pH 7.5 and 25 .deg. C is described. The reaction is monitored spectrophotometrically by measuring the decrease in absorbance of the dyestuff at 637 nm by the initial rate and fixed time method. The calibration graph is linear in the range 30-1200 ppb. The theoretical limit of detection was 0.014 ppm. Seven replicate analysis of a sample solution containing 0.70 ppm sulfide gave a relative standard deviation of 1.5%. The interfering effects of various ions on sulfide determination have been reported and procedures for removal of interference have been described. The proposed method was applied successfully to the determination of sulfide in tap and wastewater samples

  20. Electrochemical processes in macro and microfluidic cells for the abatement of chloroacetic acid from water

    International Nuclear Information System (INIS)

    Scialdone, O.; Corrado, E.; Galia, A.; Sirés, I.

    2014-01-01

    Highlights: • The electrochemical abatement of chloroacetic acid in water was studied. • The performance of both macro and microfluidic reactors was examined. • Cathodic reduction and anodic oxidation was studied in detail. • Mediated oxidation by electro-Fenton and active chlorine was carried out. • Anodic oxidation at BDD gave better performances. • Microfluidic reactors gave better performances compared to conventional cells. - Abstract: The remediation of solutions contaminated with monochloroacetic acid (CAA), which is one of the most resistant haloacetic acids (HAAs) to chemical degradation, dramatically depends on the adopted electrochemical approach: (i) CAA is only poorly oxidized either by homogeneous hydroxyl radical in electro-Fenton (EF), electrogenerated active chlorine or electro-oxidation on Pt anode; (ii) it is moderately abated by direct reduction on silver or compact graphite cathodes (from 30% in macro cells to 60% in the microfluidic devices); (iii) it is quantitatively removed by direct electro-oxidation on a boron-doped diamond (BDD) anode. The use of a microreactor enables operation in the absence of supporting electrolyte and drastically enhances the performance of the cathodic process. Simultaneously performing direct oxidation on BDD and reduction on graphite in a microfluidic cell yields the fastest CAA removal with 100% abatement at low current densities (∼5 mA cm −2 )

  1. Energy abatement in Chinese industry: Cost evaluation of regulation strategies and allocation alternatives

    International Nuclear Information System (INIS)

    Xia, X.H.; Chen, G.Q.

    2012-01-01

    For Chinese industry, the costs of different energy consumption abatement scenarios are evaluated by the method of directional distance function. These scenarios are based on the combinations of regulation strategies and allocation alternatives—the former are sectors and provinces, and the latter include the five principles of average, intensity share, absolute share, discriminatory absolute and discriminatory intensity. For all the scenarios, the quantitative impacts in terms of output potential loss are calculated and compared. Due to less output potential loss for all the allocation alternatives, the sector regulation strategy is shown to be more effective than the province regulation strategy. It is also demonstrated that, among all the scenarios considered, the sector regulation based on the intensity share principle and the province regulation based on the absolute share principle are the two optimal. The performances of energy abatement allocation of the 11th and 12th Five Year Plans of China are assessed against the simulated scenarios. - Highlights: ► The costs of different energy consumption abatement scenarios are evaluated for Chinese industry. ► The impacts on all entities under all allocation alternatives are calculated and compared. ► The optimal scenarios for the different strategies are identified. ► The performances of the 11th and 12th Five Year Plans are assessed.

  2. Water Resources Research Program. Abatement of malodors at diked, dredged-material disposal sites. Final report

    Energy Technology Data Exchange (ETDEWEB)

    Harrison, W.; Dravnieks, A.; Zussman, R.; Goltz, R.

    1976-06-01

    Samples of malodorous air and dredged material were collected at diked disposal sites at the following locations: Buffalo, NY; Milwaukee, WI; Mobile, AL; York Harbor, ME; Houston, TX; Detroit, MI; and Anacortes, WA; during the period July--October, 1975. Odorous compounds in the air samples were identified by gas chromatography/mass spectrometry, while the detection threshold, intensity, and character of the various odors were determined by experienced panelists using a dynamic, forced-choice-triangle olfactometer. Although significant problems with malodors were not observed beyond the disposal-area dikes during site visits, noteworthy odor episodes had occurred at some sites. An odor-abatement strategy is presented for handling the expected range of odor conditions at dredged-material disposal sites. Its aim is to reduce to an acceptable level the intensity of malodors in an affected community. The main steps in the strategy cover selection of the disposal site, site preparation, odor characterization of sediments to be dredged, malodor abatement during dredging and disposal operations, malodor abatement after filling of the disposal site, and the handling of malodor complaints.

  3. Considerations upon the possibility of abating the pollution produced by thermal power plants

    International Nuclear Information System (INIS)

    Ataman, Eleonora

    1992-01-01

    Thermal power plants using fossil fuels in conventional boilers are among the most important man-made stationary sources of pollutant release. A review of the present possibilities to abate the pollution, mainly by abatement of releases at stack is presented. At present the unique viable solution applicable in Romania thermopower stations appears to be the use of catalytic technology based on NO x selective reduction with ammonia. Investments for pollution abatement installations for intra- or post-combustion burning gases in classic boilers appear to be 1/4 and 1/3 of the cost of a new thermal power plant and the maintenance costs of de-pollution installations even when the resulting products are rendered profitable, the cost of KWh will raise. Replacement of classical boilers by circulating fluidized bed boilers would solve entirely the SO 2 and NO x release issue. Investments for such boilers are lower than those implied by a new classical boiler equipped with supplementary installations for the removal of intra- and post-combustion gases. The only remaining drawback is waste resulting desulfurization which is disposed at the dump. (author)

  4. Anoxic sulfide biooxidation using nitrite as electron acceptor

    International Nuclear Information System (INIS)

    Mahmood, Qaisar; Zheng Ping; Cai Jing; Wu Donglei; Hu, Baolan; Li Jinye

    2007-01-01

    Biotechnology can be used to assess the well being of ecosystems, transform pollutants into benign substances, generate biodegradable materials from renewable sources, and develop environmentally safe manufacturing and disposal processes. Simultaneous elimination of sulfide and nitrite from synthetic wastewaters was investigated using a bioreactor. A laboratory scale anoxic sulfide-oxidizing (ASO) reactor was operated for 135 days to evaluate the potential for volumetric loading rates, effect of hydraulic retention time (HRT) and substrate concentration on the process performance. The maximal sulfide and nitrite removal rates were achieved to be 13.82 and 16.311 kg/(m 3 day), respectively, at 0.10 day HRT. The process can endure high sulfide concentrations, as the sulfide removal percentage always remained higher than 88.97% with influent concentration up to 1920 mg/L. Incomplete sulfide oxidation took place due to lower consumed nitrite to sulfide ratios of 0.93. It also tolerated high nitrite concentration up to 2265.25 mg/L. The potential achieved by decreasing HRT at fixed substrate concentration is higher than that by increasing substrate concentration at fixed HRT. The process can bear short HRT of 0.10 day but careful operation is needed. Nitrite conversion was more sensitive to HRT than sulfide conversion when HRT was decreased from 1.50 to 0.08 day. Stoichiometric analyses and results of batch experiments show that major part of sulfide (89-90%) was reduced by nitrite while some autooxidation (10-11%) was resulted from presence of small quantities of dissolved oxygen in the influent wastewater. There was ammonia amassing in considerably high amounts in the bioreactor when the influent nitrite concentration reached above 2265.25 mg/L. High ammonia concentrations (200-550 mg/L) in the bioreactor contributed towards the overall inhibition of the process. Present biotechnology exhibits practical value with a high potential for simultaneous removal of nitrite

  5. Carbon steel protection in G.S. (Girlder sulfide) plants. Pressure influence on iron sulfide scales formation. Pt. 5

    International Nuclear Information System (INIS)

    Delfino, C.A.; Lires, O.A.; Rojo, E.A.

    1987-01-01

    In order to protect carbon steel towers and piping of Girlder sulfide (G.S.) experimental heavy water plants against corrosion produced by the action of aqueous solutions of hydrogen sulfide, a method, previously published, was developed. Carbon steel, exposed to saturated aqueous solutions of hydrogen sulfide, forms iron sulfide scales. In oxygen free solutions evolution of corrosion follows the sequence: mackinawite → cubic ferrous sulfide → troilite → pyrrotite → pyrite. Scales formed by pyrrotite-pyrite or pyrite are the most protective layers (these are obtained at 130 deg C, 2MPa, for periods of 14 days). Experiments, at 125 deg C and periods of 10-25 days, were performed in two different ways: 1- constant pressure operations at 0.5 and 1.1 MPa. 2- variable pressure operation between 0.3-1 MPa. In all cases pyrrotite-pyrite scales were obtained. (Author) [es

  6. Occupational exposure to hydrogen sulfide: management of hydrogen sulfide exposure victims (Preprint No. SA-5)

    International Nuclear Information System (INIS)

    Srivastava, P.P.

    1989-04-01

    National Institute of Occupational Safety and Health, U.S.A. has listed 73 industries with potential exposure to hydrogen sulphide. Though the toxicity of hydrogen sulfide is known to mankind since the beginning of seventeenth century the exact mode of its toxicity and effective therapeutic regimen remains unclear as yet. This paper presents current thoughts on the toxicity of this substance and a discussion on the role of various antidotes used in H 2 S poisoning. (autho r)

  7. Two colorimetric and ratiometric fluorescence probes for hydrogen sulfide based on AIE strategy of α-cyanostilbenes

    Science.gov (United States)

    Zhao, Baoying; Yang, Binsheng; Hu, Xiangquan; Liu, Bin

    2018-06-01

    Aggregation-induced emission (AIE) active fluorescent probes have attracted great potential in biological sensors. In this paper two cyanostilbene based fluorescence chemoprobe Cya-NO2 (1) and Cya-N3 (2) were developed and evaluated for the selective and sensitive detection of hydrogen sulfide (H2S). Both of these probes behave aggression-induced emission (AIE) activity which fluoresces in the red region with a large Stokes shift. They exhibit rapid response to H2S with enormous colorimetric and ratiometric fluorescent changes. They are readily employed for assessing intracellular H2S levels.

  8. Azo dye decolorization assisted by chemical and biogenic sulfide

    Energy Technology Data Exchange (ETDEWEB)

    Prato-Garcia, Dorian [Laboratory for Research on Advanced Processes for Water Treatment, Unidad Académica Juriquilla, Instituto de Ingeniería, Universidad Nacional Autónoma de México, Blvd. Juriquilla 3001, Querétaro 76230 (Mexico); Cervantes, Francisco J. [División de Ciencias Ambientales, Instituto Potosino de Investigación Científica y Tecnológica, Camino a la Presa de San José 2055, San Luis Potosí 78216 (Mexico); Buitrón, Germán, E-mail: gbuitronm@ii.unam.mx [Laboratory for Research on Advanced Processes for Water Treatment, Unidad Académica Juriquilla, Instituto de Ingeniería, Universidad Nacional Autónoma de México, Blvd. Juriquilla 3001, Querétaro 76230 (Mexico)

    2013-04-15

    Highlights: ► Azo dyes were reduced efficiently by chemical and biogenic sulfide. ► Biogenic sulfide was more efficient than chemical sulfide. ► There was no competition between dyes and sulfate for reducing equivalents. ► Aromatic amines barely affected the sulfate-reducing process. -- Abstract: The effectiveness of chemical and biogenic sulfide in decolorizing three sulfonated azo dyes and the robustness of a sulfate-reducing process for simultaneous decolorization and sulfate removal were evaluated. The results demonstrated that decolorization of azo dyes assisted by chemical sulfide and anthraquinone-2,6-disulfonate (AQDS) was effective. In the absence of AQDS, biogenic sulfide was more efficient than chemical sulfide for decolorizing the azo dyes. The performance of sulfate-reducing bacteria in attached-growth sequencing batch reactors suggested the absence of competition between the studied azo dyes and the sulfate-reducing process for the reducing equivalents. Additionally, the presence of chemical reduction by-products had an almost negligible effect on the sulfate removal rate, which was nearly constant (94%) after azo dye injection.

  9. Simultaneous removal of sulfide, nitrate and acetate: Kinetic modeling

    Energy Technology Data Exchange (ETDEWEB)

    Wang Aijie, E-mail: waj0578@hit.edu.cn [State Key Laboratory of Urban Water Resource and Environment, Harbin Institute of Technology (SKLUWRE, HIT), Harbin 150090 (China); Liu Chunshuang; Ren Nanqi; Han Hongjun [State Key Laboratory of Urban Water Resource and Environment, Harbin Institute of Technology (SKLUWRE, HIT), Harbin 150090 (China); Lee Duujong [State Key Laboratory of Urban Water Resource and Environment, Harbin Institute of Technology (SKLUWRE, HIT), Harbin 150090 (China); Department of Chemical Engineering, National Taiwan University, Taipei 10617, Taiwan (China)

    2010-06-15

    Biological removal of sulfide, nitrate and chemical oxygen demand (COD) simultaneously from industrial wastewaters to elementary sulfur (S{sup 0}), N{sub 2}, and CO{sub 2}, or named the denitrifying sulfide (DSR) process, is a cost effective and environmentally friendly treatment process for high strength sulfide and nitrate laden organic wastewater. Kinetic model for the DSR process was established for the first time on the basis of Activated Sludge Model No. 1 (ASM1). The DSR experiments were conducted at influent sulfide concentrations of 200-800 mg/L, whose results calibrate the model parameters. The model correlates well with the DSR process dynamics. By introducing the switch function and the inhibition function, the competition between autotrophic and heterotrophic denitrifiers is quantitatively described and the degree of inhibition of sulfide on heterotrophic denitrifiers is realized. The model output indicates that the DSR reactor can work well at 0.5 < C/S < 3.0 with influent sulfide concentration of 400-1000 mg/L. At >1000 mg/L influent sulfide, however, the DSR system will break down.

  10. Interactions among sulfide-oxidizing bacteria

    Science.gov (United States)

    Poplawski, R.

    1985-01-01

    The responses of different phototrophic bacteria in a competitive experimental system are studied, one in which primary factors such as H2S or light limited photometabolism. Two different types of bacteria shared one limited source of sulfide under specific conditions of light. The selection of a purple and a green sulfur bacteria and the cyanobacterium was based on their physiological similarity and also on the fact that they occur together in microbial mats. They all share anoxygenic photosynthesis, and are thus probably part of an evolutionary continuum of phototrophic organisms that runs from, strictly anaerobic physiology to the ability of some cyanobacteria to shift between anoxygenic bacterial style photosynthesis and the oxygenic kind typical of eukaryotes.

  11. Eelgrass fairy rings: sulfide as inhibiting agent

    DEFF Research Database (Denmark)

    Borum, Jens; Raun, Ane-Marie Løvendahl; Hasler-Sheetal, Harald

    2014-01-01

    specifically, for the apparent die- off of eelgrass shoots on the inner side of the rings. The fairy rings were up to 15 m in diameter consisting of 0.3- to 1-m-wide zones of sea grass shoots at densities of up to 1,200 shoots m−2 and rooted in an up to 10-cm-thick sediment layer. On the outer side, shoots...... expanded over the bare chalk plates. On the inner side, shoots were smaller, had lower absolute and specific leaf growth, shoot density was lower and the sediment eroded leaving the bare chalk with scattered boulders behind. Sediment organic matter and nutrients and tissue nutrient contents were...... substantial invasion of sulfide from the sediment. neither the clonal growth pattern of eelgrass, sediment burial of shoots, hydrodynamic forcing nor nutrient limitation could explain the ring-shaped pattern. We conclude that the most likely explanation must be found in invasion of eelgrass shoots by toxic...

  12. On the pelletizing of sulfide molybdenite concentrate

    International Nuclear Information System (INIS)

    Palant, A.A.

    2007-01-01

    Investigation results are discussed on the process of pelletizing with the use of various binders (water, syrup, sulfite-alcoholic residue and bentonite) for flotation sulfide molybdenite concentrate (∼84 % MoS 2 ) of the Mongolian deposit. It is established that with the use of syrup rather strong pellets (>300 g/p) of desired size (2-3 mm) can be obtained at a binder flowrate of 1 kg per 100 kg of concentrate. The main advantage of using syrup instead of bentonite lies in the fact that in this instance no depletion of a molybdenum calcine obtained by oxidizing roasting of raw ore takes place due to syrup complete burning out. This affects positively subsequent hydrometallurgical conversion because of decreasing molybdenum losses with waste cakes [ru

  13. Modulated structure calculated for superconducting hydrogen sulfide

    Energy Technology Data Exchange (ETDEWEB)

    Majumdar, Arnab; Tse, John S.; Yao, Yansun [Department of Physics and Engineering Physics, University of Saskatchewan, Saskatoon, SK (Canada)

    2017-09-11

    Compression of hydrogen sulfide using first principles metadynamics and molecular dynamics calculations revealed a modulated structure with high proton mobility which exhibits a diffraction pattern matching well with experiment. The structure consists of a sublattice of rectangular meandering SH{sup -} chains and molecular-like H{sub 3}S{sup +} stacked alternately in tetragonal and cubic slabs forming a long-period modulation. The novel structure offers a new perspective on the possible origin of the superconductivity at very high temperatures in which the conducting electrons in the SH chains are perturbed by the fluxional motions of the H{sub 3}S resulting in strong electron-phonon coupling. (copyright 2017 Wiley-VCH Verlag GmbH and Co. KGaA, Weinheim)

  14. Mechanism of hydrodenitrogenation on phosphides and sulfides.

    Science.gov (United States)

    Oyama, S Ted; Lee, Yong-Kul

    2005-02-17

    The mechanism of hydrodenitrogenation (HDN) of 2-methylpiperidine was studied over a silica-supported nickel phosphide catalyst (Ni2P/SiO2, Ni/P = 1/2) and a commercial Ni-Mo-S/Al2O3 catalyst in a three-phase trickle-bed reactor operated at 3.1 MPa and 450-600 K. Analysis of the product distribution as a function of contact time indicated that the reaction proceeded in both cases predominantly by a substitution mechanism, with a smaller contribution of an elimination mechanism. Fourier transform infrared spectroscopy (FTIR) of the 2-methylpiperidine indicated that at reaction conditions a piperidinium ion intermediate was formed on both the sulfide and the phosphide. It is concluded that the mechanism of HDN on nickel phosphide is very similar to that on sulfides. The mechanism on the nickel phosphide was also probed by comparing the reactivity of piperidine and several of its derivatives in the presence of 3000 ppm S. The relative elimination rates depended on the structure of the molecules, and followed the sequence: 4-methylpiperidine approximately piperidine > 3-methylpiperidine > 2,6-dimethylpiperidine > 2-methylpiperidine. [Chemical structure: see text] This order of reactivity was not dependent on the number of alpha-H or beta-H atoms in the molecules, ruling out their reaction through a single, simple mechanism. It is likely that the unhindered piperidine molecules reacted by an S(N)2 substitution process and the more hindered 2,6-dimethylpiperidine reacted by an E2 elimination process.

  15. New cyclic sulfides, garlicnins I2, M, N, and O, from Allium sativum.

    Science.gov (United States)

    Nohara, Toshihiro; Ono, Masateru; Nishioka, Naho; Masuda, Fuka; Fujiwara, Yukio; Ikeda, Tsuyoshi; Nakano, Daisuke; Kinjo, Junei

    2018-01-01

    One atypical thiolane-type sulfide, garlicnin I 2 (1), two 3,4-dimethylthiolane-type sulfides, garlicnins M (2) and N (3), and one thiabicyclic-type sulfide, garlicnin O (4), were isolated from the acetone extracts of Chinese garlic bulbs, Allium sativum and their structures were characterized. Hypothetical pathways for the production of the respective sulfides were discussed.

  16. Can China afford to commit itself an emissions cap? An economic and political analysis

    NARCIS (Netherlands)

    Zhang, ZX

    2000-01-01

    As the world's second largest carbon emitter, China has long been criticised as a 'free-rider' enjoying benefits from other countries' efforts to abate greenhouse gas emissions but not taking due responsibilities of its own. China has been singled out as one of the major targets at the subsequent

  17. FUTURE FOSSIL FUEL PRICE IMPACTS ON NDC ACHIEVEMENT; ESTIMATION OF GHG EMISSIONS AND MITIGATION COSTS

    Directory of Open Access Journals (Sweden)

    Yosuke Arino

    2017-12-01

    Full Text Available The Shale Revolution in the US, a supply-side innovation in oil and gas production, has been dramatically changing the world’s fossil fuel energy markets – leading to a decrease in oil, gas and coal prices. Some projections suggest that low fossil fuel prices might continue at least over the next few decades. Uncertainty in fossil fuel prices might affect the levels of emission reductions expected from submitted nationally determined contributions (NDCs and/or influence the difficulty of achieving the NDCs. This paper evaluated the impact of different (high, medium, and low fossil fuel prices, sustained through to 2050, on worldwide GHG emissions reductions and associated costs (mainly marginal abatement costs (MACs. Total global GHG emissions were estimated to be 57.5-61.5 GtCO2eq by 2030, with the range shown reflecting uncertainties about fossil fuel prices and the target levels of several NDCs (i.e., whether their upper or lower targets were adopted. It was found that lower fuel prices not only diminished the environmental effectiveness of global NDCs but also widened regional differences of marginal and total abatement costs, thereby generating more room for carbon leakage. One possible policy direction in terms of abatement efficiency, fairness and environmental effectiveness would be to require countries with low marginal and total abatement costs but having a major influence on global GHG emissions (such as China and India to increase their mitigation efforts, especially in a low-fuelprice world.

  18. Elevated dust emissions on the Colorado Plateau: Role of grazing vehicle disturbance, and increasing aridity

    Science.gov (United States)

    Dust from drylands are of major concern to human society. Dust deposition onto snowpacks can hasten melt rates, resulting in lowered inputs into major rivers. Blowing dust can result in traffic accidents, respiratory disease, and high economic costs. To abate dust emissions, it is necessary to exami...

  19. Optimization of the superconducting phase of hydrogen sulfide

    Science.gov (United States)

    Degtyarenko, N. N.; Masur, E. A.

    2015-12-01

    The electron and phonon spectra, as well as the densities of electron and phonon states of the SH3 phase and the stable orthorhombic structure of hydrogen sulfide SH2, are calculated for the pressure interval 100-225 GPa. It is found that the I4/ mmm phase can be responsible for the superconducting properties of metallic hydrogen sulfide along with the SH3 phase. Sequential stages for obtaining and conservation of the SH2 phase are proposed. The properties of two (SH2 and SH3) superconducting phases of hydrogen sulfide are compared.

  20. Process for scavenging hydrogen sulfide from hydrocarbon gases

    International Nuclear Information System (INIS)

    Fox, I.

    1981-01-01

    A process for scavenging hydrogen sulfide from hydrocarbon gases utilizes iron oxide particles of unique chemical and physical properties. These particles have large surface area, and are comprised substantially of amorphous Fe 2 O 3 containing a crystalline phase of Fe 2 O 3 , Fe 3 O 4 and combinations thereof. In scavenging hydrogen sulfide, the iron oxide particles are suspended in a liquid which enters into intimate mixing contact with hydrocarbon gases; the hydrogen sulfide is reacted at an exceptional rate and only acid-stable reaction products are formed. Thereafter, the sweetened hydrocarbon gases are collected

  1. Sulfidization of an aluminocobaltomolybdenum catalyst using the 35S radioisotope

    International Nuclear Information System (INIS)

    Isagulyants, G.V.; Greish, A.A.; Kogan, V.M.

    1987-01-01

    It has been established that in aluminocobaltomolybdenum catalyst sulfidized with elemental sulfur there are two types of sulfur, free and bound. The maximum amount of bound sulfur in ACM catalyst is 6.6 wt. %, which corresponds to practically complete sulfidation of the ACM catalyst. In the presence of hydrogen an equilibrium distribution of bound sulfur is achieved in a granule of ACM catalyst irrespective of the temperature of sulfidation. In a nitrogen atmosphere it is primarily the surface layers of the catalyst that are sulfured

  2. Sulfide Oxidation in the Anoxic Black-Sea Chemocline

    DEFF Research Database (Denmark)

    JØRGENSEN, BB; FOSSING, H.; WIRSEN, CO

    1991-01-01

    per day, occurred in anoxic water at the top of the sulfide zone concurrent with the highest rates of dark CO2 assimilation. The main soluble oxidized products of sulfide were thiosulfate (68-82%) and sulfate. Indirect evidence was presented for the formation of elemental sulfur which accumulated...... that the measured H2S oxidation rates were 4-fold higher than could be explained by the downward flux of organic carbon and too high to balance the availability of electron acceptors such as oxidized iron or manganese. A nitrate maximum at the lower boundary of the O2 zone did not extend down to the sulfide zone....

  3. Thermoelectric properties of non-stoichiometric lanthanum sulfides

    International Nuclear Information System (INIS)

    Shapiro, E.; Danielson, L.R.

    1983-01-01

    The lanthanum sulfides are promising candidate materials for high-efficiency thermoelectric applications at temperatures up to 1300 0 C. The nonstoichiometric lanthanum sulfides (LaS /SUB x/ , where 1.33 2 //rho/ can be chosen. The thermal conductivity remains approximately constant with stoichiometry, so a material with an optimum value of α 2 //rho/ should possess the optimum figure-of-merit. Data for the Seebeck coefficient and electrical resistivity of non-stoichiometric lanthanum sulfides is presented, together with structural properties of these materials

  4. Denitrifying sulfide removal process on high-salinity wastewaters.

    Science.gov (United States)

    Liu, Chunshuang; Zhao, Chaocheng; Wang, Aijie; Guo, Yadong; Lee, Duu-Jong

    2015-08-01

    Denitrifying sulfide removal (DSR) process comprising both heterotrophic and autotrophic denitrifiers can simultaneously convert nitrate, sulfide, and acetate into nitrogen gas, elemental sulfur (S(0)), and carbon dioxide, respectively. Sulfide- and nitrate-laden wastewaters at 2-35 g/L NaCl were treated by DSR process. A C/N ratio of 3:1 was proposed to maintain high S(0) conversion rate. The granular sludge with a compact structure and smooth outer surface was formed. The microbial communities of DSR consortium via high-throughput sequencing method suggested that salinity shifts the predominating heterotrophic denitrifiers at 10 g/L NaCl.

  5. Controllable Synthesis of Lindqvist Alkoxopolyoxovanadate Clusters as Heterogeneous Catalysts for Sulfoxidation of Sulfides.

    Science.gov (United States)

    Li, Ji-Kun; Dong, Jing; Wei, Chuan-Ping; Yang, Song; Chi, Ying-Nan; Xu, Yan-Qing; Hu, Chang-Wen

    2017-05-15

    Six alkoxohexavanadate-based Cu- or Co-POVs [Cu(dpa)(acac)(H 2 O)] 2 [V 6 O 13 (OMe) 6 ] (1), [Cu(phen)(acac)(MeOH)] 2 [V 6 O 13 (OMe) 6 ] (2), [Co(dpa)(acac) 2 ] 2 [V 6 O 13 (OMe) 6 ]·2MeOH (3), [Co(phen)(acac) 2 ] 2 [V 6 O 13 (OMe) 6 ] (4), [Cu(dpa)(acac)] 2 [V IV 2 V V 4 O 12 (OMe) 7 ] (5), and [Cu(dpa)(acac)(MeOH)] 2 [V IV 2 V V 4 O 11 (OMe) 8 ] (6) (POV = polyoxovanadate; dpa = 2,2'-dipyridine amine; phen = 1,10-phenanthroline; acac = acetylacetone anion) have been synthesized by controlling the reaction conditions and characterized by single-crystal X-ray diffraction and powder X-ray diffraction analyses, FT-IR spectroscopy, element analyses, and X-ray photoelectron spectroscopy. In compounds 1-4 and 6, Cu or Co complexes and alkoxohexavanadate anions are assembled through electrostatic interactions. Differently, in compound 5, seven-methoxo-substituted Lindqvist-type [V 6 O 12 (OMe) 7 ] 2- are bridged to Cu complex via terminal O atoms by coordination bonds. All compounds 1-6 exhibit excellent heterogeneous catalytic performance in oxidative desulfurization and CEES ((2-chloroethyl) ethyl sulfide, a sulfur mustard simulant) abatement with H 2 O 2 as oxidant. Among them, the catalytic activity of 6 [conv. of DBT (dibenzothiophene) up to 100% in 6 h; conv. of CEES reached 100% and selectivity of CEESO ((2-chloroethyl) ethyl sulfoxide) up to 85% after 4 h] outperforms others and can be reused without losing its activity.

  6. Use of sulfide-containing liquors for removing mercury from flue gases

    Science.gov (United States)

    Nolan, Paul S.; Downs, William; Bailey, Ralph T.; Vecci, Stanley J.

    2006-05-02

    A method and apparatus for reducing and removing mercury in industrial gases, such as a flue gas, produced by the combustion of fossil fuels, such as coal, adds sulfide ions to the flue gas as it passes through a scrubber. Ideally, the source of these sulfide ions may include at least one of: sulfidic waste water, kraft caustic liquor, kraft carbonate liquor, potassium sulfide, sodium sulfide, and thioacetamide. The sulfide ion source is introduced into the scrubbing liquor as an aqueous sulfide species. The scrubber may be either a wet or dry scrubber for flue gas desulfurization systems.

  7. Remediation of Sulfidic Wastewater by Aeration in the Presence of Ultrasonic Vibration

    Directory of Open Access Journals (Sweden)

    F. Ahmad

    2018-06-01

    Full Text Available In the current study, the aerial oxidation of sodium sulfide in the presence of ultrasonic vibration is investigated. Sulfide analysis was carried out by the methylene blue method. Sodium sulfide is oxidized to elemental sulfur in the presence of ultrasonic vibration. The influence of air flow rate, initial sodium sulfide concentration and ultrasonic vibration intensity on the oxidation of sodium sulfide was investigated. The rate law equation regarding the oxidation of sulfide was determined from the experimental data. The order of reaction with respect to sulfide and oxygen was found to be 0.36 and 0.67 respectively. The overall reaction followed nearly first order kinetics.

  8. Using the soil and water assessment tool to estimate dissolved inorganic nitrogen water pollution abatement cost functions in central portugal.

    Science.gov (United States)

    Roebeling, P C; Rocha, J; Nunes, J P; Fidélis, T; Alves, H; Fonseca, S

    2014-01-01

    Coastal aquatic ecosystems are increasingly affected by diffuse source nutrient water pollution from agricultural activities in coastal catchments, even though these ecosystems are important from a social, environmental and economic perspective. To warrant sustainable economic development of coastal regions, we need to balance marginal costs from coastal catchment water pollution abatement and associated marginal benefits from coastal resource appreciation. Diffuse-source water pollution abatement costs across agricultural sectors are not easily determined given the spatial heterogeneity in biophysical and agro-ecological conditions as well as the available range of best agricultural practices (BAPs) for water quality improvement. We demonstrate how the Soil and Water Assessment Tool (SWAT) can be used to estimate diffuse-source water pollution abatement cost functions across agricultural land use categories based on a stepwise adoption of identified BAPs for water quality improvement and corresponding SWAT-based estimates for agricultural production, agricultural incomes, and water pollution deliveries. Results for the case of dissolved inorganic nitrogen (DIN) surface water pollution by the key agricultural land use categories ("annual crops," "vineyards," and "mixed annual crops & vineyards") in the Vouga catchment in central Portugal show that no win-win agricultural practices are available within the assessed BAPs for DIN water quality improvement. Estimated abatement costs increase quadratically in the rate of water pollution abatement, with largest abatement costs for the "mixed annual crops & vineyards" land use category (between 41,900 and 51,900 € tDIN yr) and fairly similar abatement costs across the "vineyards" and "annual crops" land use categories (between 7300 and 15,200 € tDIN yr). Copyright © by the American Society of Agronomy, Crop Science Society of America, and Soil Science Society of America, Inc.

  9. Removals of aqueous sulfur dioxide and hydrogen sulfide using CeO2-NiAl-LDHs coating activated carbon and its mix with carbon nano-tubes

    KAUST Repository

    Li, Jing; Chen, Fangping; Jin, Guanping; Feng, Xiaoshuang; Li, Xiaoxuan

    2015-01-01

    Ce-doped NiAl/layered double hydroxide was coated at activated carbon by urea hydrolysis method (CeO2-NiAl-LDHs/AC) in one pot, which was characterized by X-ray diffraction, infrared spectra, field emission scanning electron microscope and electrochemical techniques. CeO2-NiAl-LDHs/AC shows good uptake for aqueous sulfur dioxide (483.09mg/g) and hydrogen sulfide (181.15mg/g), respectively at 25°C. Meanwhile, the electrochemical removals of aqueous sulfur dioxide and hydrogen sulfide were respectively investigated at the mix of CeO2-NiAl-LDHs/AC and carbon nano-tubes modified homed paraffin-impregnated electrode. Both sulfur dioxide and hydrogen sulfide could be effectively oxidized to sulfuric acid at 1.0V in alkaline aqueous solution. © 2015 Elsevier B.V.

  10. Removals of aqueous sulfur dioxide and hydrogen sulfide using CeO2-NiAl-LDHs coating activated carbon and its mix with carbon nano-tubes

    KAUST Repository

    Li, Jing

    2015-07-01

    Ce-doped NiAl/layered double hydroxide was coated at activated carbon by urea hydrolysis method (CeO2-NiAl-LDHs/AC) in one pot, which was characterized by X-ray diffraction, infrared spectra, field emission scanning electron microscope and electrochemical techniques. CeO2-NiAl-LDHs/AC shows good uptake for aqueous sulfur dioxide (483.09mg/g) and hydrogen sulfide (181.15mg/g), respectively at 25°C. Meanwhile, the electrochemical removals of aqueous sulfur dioxide and hydrogen sulfide were respectively investigated at the mix of CeO2-NiAl-LDHs/AC and carbon nano-tubes modified homed paraffin-impregnated electrode. Both sulfur dioxide and hydrogen sulfide could be effectively oxidized to sulfuric acid at 1.0V in alkaline aqueous solution. © 2015 Elsevier B.V.

  11. Light-emitting diodes based on nontoxic zinc-alloyed silver-indium-sulfide (AIZS) nanocrystals

    Science.gov (United States)

    Bhaumik, Saikat; Guchhait, Asim; Pal, Amlan J.

    2014-04-01

    We report solution-processed growth of zinc-alloyed silver-indium-sulfide (AIZS) nanocrystals followed by fabrication and characterization of light-emitting diodes (LEDs) based on such nanostructures. While growing the low dimensional crystals, we vary the ratio between the silver and zinc contents that in turn tunes the bandgap and correspondingly their photoluminescence (PL) emission. We also dope the AIZS nanocrystals with manganese, so that their PL emission, which appears due to a radiative transition between the d-states of the dopants, becomes invariant in energy when the diameter of the quantum dots or the dopant concentration in the nanostructures varies. The LEDs fabricated with such undoped and manganese-doped AIZS nanocrystals emit electroluminescence (EL) that matches the PL spectrum of the respective nanomaterial. The results demonstrate examples of quantum dot LEDs (QDLEDs) based on nontoxic AIZS nanocrystals.

  12. Enhanced sulfidation xanthate flotation of malachite using ammonium ions as activator

    OpenAIRE

    Dandan Wu; Wenhui Ma; Yingbo Mao; Jiushuai Deng; Shuming Wen

    2017-01-01

    In this study, ammonium ion was used to enhance the sulfidation flotation of malachite. The effect of ammonium ion on the sulfidation flotation of malachite was investigated using microflotation test, inductively coupled plasma (ICP) analysis, zeta potential measurements, and scanning electron microscope analysis (SEM). The results of microflotation test show that the addition of sodium sulfide and ammonium sulfate resulted in better sulfidation than the addition of sodium sulfide alone. The ...

  13. Price floors for emissions trading

    International Nuclear Information System (INIS)

    Wood, Peter John; Jotzo, Frank

    2011-01-01

    Price floors in greenhouse gas emissions trading schemes can guarantee minimum abatement efforts if prices are lower than expected, and they can help manage cost uncertainty, possibly as complements to price ceilings. Provisions for price floors are found in several recent legislative proposals for emissions trading. Implementation however has potential pitfalls. Possible mechanisms are government commitments to buy back permits, a reserve price at auction, or an extra fee or tax on acquittal of emissions permits. Our analysis of these alternatives shows that the fee approach has budgetary advantages and is more compatible with international permit trading than the alternatives. It can also be used to implement more general hybrid approaches to emissions pricing. - Research highlights: → Price floors for emissions trading schemes guarantee a minimum carbon price. → Price floors mean that emissions can be less than specified by the ETS cap. → We examine how price floors can relate to different policy objectives. → We compare different mechanisms for implementing a price floor. → We find that a mechanism where there is an extra tax or fee has advantages.

  14. Biofabrication of morphology improved cadmium sulfide nanoparticles using Shewanella oneidensis bacterial cells and ionic liquid: For toxicity against brain cancer cell lines.

    Science.gov (United States)

    Wang, Li; Chen, Siyuan; Ding, Yiming; Zhu, Qiang; Zhang, Nijia; Yu, Shuqing

    2018-01-01

    The present work determines the anticancer activity of bio-mediated synthesized cadmium sulfide nanoparticles using the ionic liquid and bacterial cells (Shewanella oneidensis). Bacterial cells have been exposed to be important resources that hold huge potential as ecofriendly, cost-effective, evading toxic of dangerous chemicals and the alternative of conventional physiochemical synthesis. The Shewanella oneidensis is an important kind of metal reducing bacterium, known as its special anaerobic respiratory and sulfate reducing capacity. The crystalline nature, phase purity and surface morphology of biosynthesized cadmium sulfide nanoparticles were analyzed by Fourier transform infrared spectroscopy, X-ray diffraction, Field emission scanning electron microscopy, Energy dispersive spectroscopy and Transmission electron microscopy. The use of imidazolium based ionic liquids as soft templating agent for controlling self-assembly and crystal growth direction of metal sulfide nanoparticles has also advanced as an important method. The microscopic techniques showed that the nanoparticles are designed on the nano form and have an excellent spherical morphology, due to the self-assembled mechanism of ionic liquid assistance. The antitumor efficiency of the cadmium sulfide nanoparticles was investigated against brain cancer cell lines using rat glioma cell lines. The effectively improved nano-crystalline and morphological structure of CdS nanoparticles in the presence of IL exhibit excellent cytotoxicity and dispersion ability on the cell shape is completely spread out showing a nice toxic environment against cancer cells. The cytotoxicity effect of cadmium sulfide nanoparticles was discussed with a diagrammatic representation. Copyright © 2017. Published by Elsevier B.V.

  15. Estimating asbestos abatement projects: Excellence or 'You said I missed what'?

    International Nuclear Information System (INIS)

    Frawley, R.F.

    1992-01-01

    Between 1900 and 1980, 30 million tons of asbestos were put in place. Because of the known health hazards and increasing federal, state, and local regulations, building owners are now facing the problem of asbestos abatement. There are 4 basic approaches to dealing with asbestos: (1) removal, (2) enclosure, (3) encapsulation, (4) deferred action in conjunction with a well defined operations and maintenance program. Once the full extent of the problem is determined, the decision can be made on which action or combination of actions to take and begin estimating the cost of the asbestos abatement project. There are no high-tech methods of asbestos removal. It is hot, wet, labor intensive work, the ways of removal are archaic. Removal means man power and man hours, labor is a big ticket item, and is an important factor in cost estimating. Become very familiar with the scope of the project and be sure to fully understand the depth of the asbestos problem. The products, supplies, tools, and in some cases, the machines are all disposable items. If one overlooks something or underestimates the time involved for removal, not only will one be way off on material, the labor costs will soar. Be very observant on walk throughs, notice everything. Be sure to get clear, accurate test results on material to be removed. Once all this is done, one can make a good take off with confidence. Finally, when in doubt always remember the 11th commandment of asbestos abatement cost-estimating 'If thou can't figure it out hor-ellipsis thou best figure it in.'

  16. Reforestation as a novel abatement and compliance measure for ground-level ozone

    Science.gov (United States)

    Kroeger, Timm; Escobedo, Francisco J.; Hernandez, José L.; Varela, Sebastián; Delphin, Sonia; Fisher, Jonathan R. B.; Waldron, Janice

    2014-01-01

    High ambient ozone (O3) concentrations are a widespread and persistent problem globally. Although studies have documented the role of forests in removing O3 and one of its precursors, nitrogen dioxide (NO2), the cost effectiveness of using peri-urban reforestation for O3 abatement purposes has not been examined. We develop a methodology that uses available air quality and meteorological data and simplified forest structure growth-mortality and dry deposition models to assess the performance of reforestation for O3 precursor abatement. We apply this methodology to identify the cost-effective design for a hypothetical 405-ha, peri-urban reforestation project in the Houston–Galveston–Brazoria O3 nonattainment area in Texas. The project would remove an estimated 310 tons of (t) O3 and 58 t NO2 total over 30 y. Given its location in a nitrogen oxide (NOx)-limited area, and using the range of Houston area O3 production efficiencies to convert forest O3 removal to its NOx equivalent, this is equivalent to 127–209 t of the regulated NOx. The cost of reforestation per ton of NOx abated compares favorably to that of additional conventional controls if no land costs are incurred, especially if carbon offsets are generated. Purchasing agricultural lands for reforestation removes this cost advantage, but this problem could be overcome through cost-share opportunities that exist due to the public and conservation benefits of reforestation. Our findings suggest that peri-urban reforestation should be considered in O3 control efforts in Houston, other US nonattainment areas, and areas with O3 pollution problems in other countries, wherever O3 formation is predominantly NOx limited. PMID:25201970

  17. Airborne exposure and soil levels associated with lead abatement of a steel tank.

    Science.gov (United States)

    Lange, John H

    2002-02-01

    This study reports on airborne exposure levels and soil concentrations of lead in regard to abatement of a steel structure (water tank). The tank was de-leaded by abrasive sand blasting. The ball of the tank had a lead surface level that exceeded the Environmental Protection Agency (EPA) definition of lead-based paint (LBP) (0.5% lead), but paint on stem and base was below this criterion. Personal and area airborne samples were collected during different activities of lead abatement of the tank. Summary results suggest during abrasive blasting of ball and stem/base personal exposure levels, as reported with arithmetic and geometric means, exceed the Occupational Safety and Health Administration (OSHA) permissible exposure limit (50 microg/m3). Highest personal exposure (occupational exposure) was associated with blasting of ball. Distribution of airborne and soil samples suggest non-normality and is best represented by a logarithmic form. Geometric standard deviations for air and soil lead support a non-normal distribution. Outlying values were found for personal and area air samples. Exposure levels associated with blasting stem/base section of tank support OSHA's policy requiring air monitoring of work at levels below the criterion established by EPA in identifying LBP. Area samples were statistically lower than personal samples associated with blasting ball and stem/base of tank. Exposure data suggest that workers performing abatement on steel structures have elevated lead exposure from surface lead. Respirator protection requirements are discussed. Soil lead concentration was suggested to decrease as distance increased from tank. Soil lead is suggested to be a result of deposition from LBP on tank surface. Minimal efforts were required to reduce average lead soil levels below EPA's upper acceptable criterion (1200 ppm Pb).

  18. Instrument for Airborne Measurement of Carbonyl Sulfide, Phase I

    Data.gov (United States)

    National Aeronautics and Space Administration — Southwest Sciences proposes to develop small, low power instrumentation for the real-time direct measurement of carbonyl sulfide (OCS) in the atmosphere, especially...

  19. New sulfide catalysts for the hydroliquefaction of coal

    NARCIS (Netherlands)

    Vissers, J.P.R.; Oers, van E.M.; Beer, de V.H.J.; Prins, R.

    1987-01-01

    Possibilities for the preparation of new metal sulfide catalyst systems based on carbon carriers having favourable textural and surface properties have been explored, and attention has been given to the characterization (structure) and evaluation (hydrosulfurization activity) of these catalysts. Two

  20. Formation of Copper Sulfide Precipitate in Solid Iron

    Science.gov (United States)

    Urata, Kentaro; Kobayashi, Yoshinao

    The growth rate of copper sulfide precipitates has been measured in low carbon steel samples such as Fe-0.3mass%Cu-0.03mass%S-0.1mass%C and Fe-0.1mass%Cu-0.01mass%S- 0.1mass%C. Heat-treatment of the samples was conducted at 1273, 1423 and 1573 K for 100 s - 14.4 ks for precipitation of copper sulfides and then the samples were observed by a scanning electron microscope and a transmission electron microscope to measure the diameter of copper sulfides precipitated in the samples. The growth rate of copper sulfide has been found to be well described by the Ostwald growth model, as follows: R\