WorldWideScience

Sample records for subaqueous basaltic glasses

  1. Hardness of basaltic glass-ceramics

    DEFF Research Database (Denmark)

    Jensen, Martin; Smedskjær, Morten Mattrup; Estrup, Maja

    2009-01-01

    The dependence of the hardness of basaltic glass-ceramics on their degree of crystallisation has been explored by means of differential scanning calorimetry, optical microscopy, x-ray diffraction, and Vickers indentation. Different degrees of crystallisation in the basaltic glasses were achieved...... by varying the temperature of heat treatment. The predominant crystalline phase in the glass was identified as augite. It was found that the hardness of the glass phase decreased slightly with an increase in the degree of crystallisation, while that of the augite phase drastically decreased....

  2. Structural relaxation in annealed hyperquenched basaltic glasses

    DEFF Research Database (Denmark)

    Guo, Xiaoju; Mauro, John C.; Potuzak, M.

    2012-01-01

    The enthalpy relaxation behavior of hyperquenched (HQ) and annealed hyperquenched (AHQ) basaltic glass is investigated through calorimetric measurements. The results reveal a common onset temperature of the glass transition for all the HQ and AHQ glasses under study, indicating that the primary...... relaxation is activated at the same temperature regardless of the initial departure from equilibrium. The analysis of secondary relaxation at different annealing temperatures provides insights into the enthalpy recovery of HQ glasses....

  3. Preparation of basalt-based glass ceramics

    Directory of Open Access Journals (Sweden)

    MIHOVIL LOGAR

    2003-06-01

    Full Text Available Local and conventional raw materials–massive basalt from the Vrelo locality on Kopaonik mountain–have been used as starting materials to test their suitability for the production of glass-ceramics. Crystallization phenomena of glasses of the fused basalt rocks were studied by X-ray phase analysis, optical microscopy and other techniques. Various heat treatments were used, and their influences, on controlling the microstructures and properties of the products were studied with the aim of developing high strength glass-ceramic materials. Diopside CaMg(SiO32 and hypersthene ((Mg,FeSiO3 were identifies as the crystalline phases. The final products contained considerable amounts of a glassy phase. The crystalline size was in range of 8–480 mm with plate or needle shape. Microhardness, crashing strength and wears resistence of the glass-ceramics ranged from 6.5–7.5, from 2000–6300 kg/cm2 and from 0.1–0.2 g/cm, respectively.

  4. Alteration of basaltic glasses from the Central Indian Ocean

    Digital Repository Service at National Institute of Oceanography (India)

    Iyer, S.D.

    Textural, mineralogical and compositional characteristics of basaltic glasses from the Central Indian Ocean show them to be altered to varying extents through their interaction with the seawater, resulting in the formation of palagonite. The major...

  5. Mechanical Characterization of Basalt and Glass Fiber Epoxy Composite Tube

    OpenAIRE

    Lapena, Mauro Henrique; Marinucci, Gerson

    2017-01-01

    The application of basalt fibers are possible in many areas thanks to its multiple and good properties. It exhibits excellent resistance to alkalis, similar to glass fiber, at a much lower cost than carbon and aramid fibers. In the present paper, a comparative study on mechanical properties of basalt and E-glass fiber composites was performed. Results of apparent hoop tensile strength test of ring specimens cut from tubes and the interlaminar shear stress (ILSS) test are presented. Tensile te...

  6. Behaviour of rare earth elements, as natural analogues of transuranium elements, during weathering of basaltic glasses

    International Nuclear Information System (INIS)

    Daux, V.; Crovisier, J.L.; Petit, J.C.

    1991-01-01

    Subglacial basaltic glasses from Iceland have been studied in order to investigate REE behaviour low-temperature weathering. Just as actinides accumulate in the hydrated superficial corrosion layer of borosilicate glasses, REEs are found to be enriched in the natural corrosion layer of basaltic glasses (palagonite). However, this enrichment is only relative for basaltic glasses [fr

  7. Dissolution of basaltic glass in seawater: Mechanism and rate

    International Nuclear Information System (INIS)

    Crovisier, J.L.; Honnorez, J.; Eberhart, J.P.

    1987-01-01

    Basaltic glasses are considered as natural analogues for nuclear waste glasses. Thermodynamic computer codes used to evaluate long term behavior of both nuclear waste and basaltic glasses require the knowledge of the dissolution mechanism of the glass network. The paper presents the results of a series of experiments designed to study the structure and chemical composition of alteration layers formed on the surface of artificial tholeiitic glass altered in artificial seawater. Experiments were performed at 60 degree C, 1 bar and 350 bars in non-renewed conditions. A natural sample from Palagonia (Sicily) has been studied by electron microscopy and comparison between natural and experimental palagonitic layers is made. The behavior of dissolved silica during experiments, and both the structure and the chemical composition of the palagonitic layers, indicate that they form by precipitation of secondary minerals from solution after a total breakdown of the glassy network, i.e., congruent dissolution of the glass. Hence the dissolution equation necessary for thermodynamic modelling of basaltic glass dissolution in seawater at low temperature must be written as a simple stoichiometric process. These experiments indicate that the transformation of glass to palagonitic material is not isovolumetric. Hence it is preferable to use Fe or Ti as conservative elements for chemical budget calculations

  8. water alteration processes and kinetics of basaltic glasses, natural analogue of nuclear glasses

    International Nuclear Information System (INIS)

    Techer, I.; Advocat, Th.; Vernaz, E.; Lancelot, J.R.; Liotard, J.M.

    1997-01-01

    Dissolution experiments of a basaltic glass were carried out at 90 deg C for different reaction progresses. The initial dissolution rate was compared with values obtained for rhyolitic glass and the R7T7 nuclear glass. The activation energy was also determined by computing literature data. The results provide similar reactional mechanism for basaltic and nuclear glasses. Dissolution rates measured under saturation conditions were compared to theoretical dissolution rates. These ones were calculated using two kinetic models: the first rate equation is the Grambow's law which only takes into account ortho-silica acid activity; the second rate equation was proposed by Daux et al., where silica and aluminum are combined to formulate the affinity. The comparison between experimental and theoretical results point out that these two models are not appropriate to describe the alteration kinetic of basaltic glasses. (authors)

  9. A new basaltic glass microanalytical reference material for multiple techniques

    Science.gov (United States)

    Wilson, Steve; Koenig, Alan; Lowers, Heather

    2012-01-01

    The U.S. Geological Survey (USGS) has been producing reference materials since the 1950s. Over 50 materials have been developed to cover bulk rock, sediment, and soils for the geological community. These materials are used globally in geochemistry, environmental, and analytical laboratories that perform bulk chemistry and/or microanalysis for instrument calibration and quality assurance testing. To answer the growing demand for higher spatial resolution and sensitivity, there is a need to create a new generation of microanalytical reference materials suitable for a variety of techniques, such as scanning electron microscopy/X-ray spectrometry (SEM/EDS), electron probe microanalysis (EPMA), laser ablation inductively coupled mass spectrometry (LA-ICP-MS), and secondary ion mass spectrometry (SIMS). As such, the microanalytical reference material (MRM) needs to be stable under the beam, be homogeneous at scales of better than 10–25 micrometers for the major to ultra-trace element level, and contain all of the analytes (elements or isotopes) of interest. Previous development of basaltic glasses intended for LA-ICP-MS has resulted in a synthetic basaltic matrix series of glasses (USGS GS-series) and a natural basalt series of glasses (BCR-1G, BHVO-2G, and NKT-1G). These materials have been useful for the LA-ICP-MS community but were not originally intended for use by the electron or ion beam community. A material developed from start to finish with intended use in multiple microanalytical instruments would be useful for inter-laboratory and inter-instrument platform comparisons. This article summarizes the experiments undertaken to produce a basalt glass reference material suitable for distribution as a multiple-technique round robin material. The goal of the analytical work presented here is to demonstrate that the elemental homogeneity of the new glass is acceptable for its use as a reference material. Because the round robin exercise is still underway, only

  10. Environmental resistance and mechanical performance of basalt and glass fibers

    International Nuclear Information System (INIS)

    Wei Bin; Cao Hailin; Song Shenhua

    2010-01-01

    The treated basalt and glass fibers with sodium hydroxide and hydrochloric acid solutions for different times were analyzed, respectively. This paper summarized the mass loss ratio and the strength maintenance ratios of the fibers after treatment. The fibers' surface corrosion morphologies were characterized using scanning electron microscopy and their compositions were detected using energy dispersive X-ray spectroscopy. The acid resistance was much better than the alkali resistance for the basalt fibers. Nevertheless, for the glass fibers the situation is different: the acid resistance was almost the same as the alkali resistance. Among the two types of aqueous environments evaluated, the alkali solution is the most aggressive to the fibers' surface. The possible corrosion mechanisms are revealed.

  11. Basaltic glass alteration in confined media: analogy with nuclear glass in geological disposal conditions

    International Nuclear Information System (INIS)

    Parruzot, Benjamin

    2014-01-01

    This dissertation concerns basaltic glass alteration mechanisms and rates. Through a better understanding of the processes controlling the basaltic glass durability, this thesis attempts to establish a link between laboratory studies and volcanic glass alteration in natural environment. The methodology used here is similar to the one used for nuclear glasses. Thus, we measured for the first time the residual alteration rate of basaltic glasses. Protective effect of the alteration film is clearly established. Moreover, synthetic glass representativeness is evaluated through a study focused on the effect of iron oxidation degree on the glass structure and leaching properties. A minor effect of Fe II on the forward rate and a negligible effect on the residual rate are shown. The residual rate is extrapolated at 5 C and compared to the mean alteration rate of natural samples of ages ranging from 1900 to 10 7 years. Non-zeolitized natural glasses follow this linear tendency, suggesting a control of the long-term rate by clayey secondary phase precipitation. Natural environments are open environments: a parametric study was performed in order to quantify the water flow rate effect on chemical composition of the alteration layer. When applied to two natural samples, the obtained laws provide coherent results. It seems possible to unify the descriptive approach from the study of natural environments to the mechanistic approach developed at the laboratory. The next step will consist in developing a model to transpose these results to nuclear glasses. (author) [fr

  12. Carbon and its isotopes in mid-oceanic basaltic glasses

    International Nuclear Information System (INIS)

    Des Marais, D.J.

    1984-01-01

    Three carbon components are evident in eleven analyzed mid-oceanic basalts: carbon on sample surfaces (resembling adsorbed gases, organic matter, or other non-magmatic carbon species acquired by the glasses subsequent to their eruption), mantle carbon dioxide in vesicles, and mantle carbon dissolved in the glasses. The combustion technique employed recovered only reduced sulfur, all of which appears to be indigenous to the glasses. The dissolved carbon concentration (measured in vesicle-free glass) increases with the eruption depth of the spreading ridge, and is consistent with earlier data which show that magma carbon solubility increases with pressure. The total glass carbon content (dissolved plus vesicular carbon) may be controlled by the depth of the shallowest ridge magma chamber. Carbon isotopic fractionation accompanies magma degassing; vesicle CO 2 is about 3.8per mille enriched in 13 C, relative to dissolved carbon. Despite this fractionation, delta 13 Csub(PDB) values for all spreading ridge glasses lie within the range -5.6 and -7.5, and the delta 13 Csub(PDB) of mantle carbon likely lies between -5 and -7. The carbon abundances and delta 13 Csub(PDB) values of Kilauea East Rift glasses apparently are influences by the differentiation and movement of magma within that Hawaiian volcano. Using 3 He and carbon data for submarine hydrothermal fluids, the present-day mid-oceanic ridge mantle carbon flux is estimated very roughly to be about 1.0 x 10 13 g C/yr. Such a flux requires 8 Gyr to accumulate the earth's present crustal carbon inventory. (orig.)

  13. Noble gas and carbon isotopes in Mariana Trough basalt glasses

    International Nuclear Information System (INIS)

    Bernard, M.; Jambon, A.; Gamo, T.; Nishio, Y.; Sano, Y.

    1998-01-01

    Noble gas elemental and isotopic compositions have been measured as well as the abundance of C and its isotopic ratios in 11 glasses from submarine pillow basalts collected from the Mariana Trough. The 3 He/ 4 He ratios of 8.22 and 8.51 R atm of samples dredged from the central Mariana Trough (similar18N) agree well with that of the Mid-Ocean Ridge Basalt (MORB) glasses (8.4±0.3 R atm ), whereas a mean ratio of 8.06±0.35 R atm in samples from the northern Mariana Trough (similar20N) is slightly lower than those of MORB. One sample shows apparent excess of 20 Ne and 21 Ne relative to atmospheric Ne, suggesting incorporation of solar-type Ne in the magma source. There is a positive correlation between 3 He/ 4 He and 40 Ar/ 36 Ar ratios, which may be explained by mixing between MORB-type and atmospheric noble gases. Excess 129 Xe is observed in the sample which also shows 20 Ne and 21 Ne excesses. Observed δ 13 C values of similar20N samples vary from -3.76 per thousand to -2.80 per thousand, and appear higher than those of MORB, and the corresponding CO 2 / 3 He ratios are higher than those of MARA samples at similar18N, suggesting C contribution from the subducted slab. (Copyright (c) 1998 Elsevier Science B.V., Amsterdam. All rights reserved.)

  14. Smectite Formation from Basaltic Glass Under Acidic Conditions on Mars

    Science.gov (United States)

    Peretyazhko, T. S.; Sutter, B.; Morris, R. V.; Agresti, D. G.; Le, L.; Ming, D. W.

    2015-01-01

    Massive deposits of phyllosilicates of the smectite group, including Mg/Fe-smectite, have been identified in Mars's ancient Noachian terrain. The observed smectite is hypothesized to form through aqueous alteration of basaltic crust under neutral to alkaline pH conditions. These pH conditions and the presence of a CO2-rich atmosphere suggested for ancient Mars were favorable for the formation of large carbonate deposits. However, the detection of large-scale carbonate deposits is limited on Mars. We hypothesized that smectite deposits may have formed under acidic conditions that prevented carbonate precipitation. In this work we investigated formation of saponite at a pH of approximately 4 from Mars-analogue synthetic Adirondack basaltic glass of composition similar to Adirondack class rocks located at Gusev crater. Hydrothermal (200º Centigrade) 14 day experiments were performed with and without 10 millimoles Fe(II) or Mg under anoxic condition [hereafter denoted as anoxic_Fe, anoxic_Mg and anoxic (no addition of Fe(II) or Mg)] and under oxic condition [hereafter denoted as oxic (no addition of Fe(II) or Mg)]. Characterization and formation conditions of the synthesized saponite provided insight into the possible geochemical conditions required for saponite formation on Mars.

  15. Potential for microbial oxidation of ferrous iron in basaltic glass.

    Science.gov (United States)

    Xiong, Mai Yia; Shelobolina, Evgenya S; Roden, Eric E

    2015-05-01

    Basaltic glass (BG) is an amorphous ferrous iron [Fe(II)]-containing material present in basaltic rocks, which are abundant on rocky planets such as Earth and Mars. Previous research has suggested that Fe(II) in BG can serve as an energy source for chemolithotrophic microbial metabolism, which has important ramifications for potential past and present microbial life on Mars. However, to date there has been no direct demonstration of microbially catalyzed oxidation of Fe(II) in BG. In this study, three different culture systems were used to investigate the potential for microbial oxidation of Fe(II) in BG, including (1) the chemolithoautotrophic Fe(II)-oxidizing, nitrate-reducing "Straub culture"; (2) the mixotrophic Fe(II)-oxidizing, nitrate-reducing organism Desulfitobacterium frappieri strain G2; and (3) indigenous microorganisms from a streambed Fe seep in Wisconsin. The BG employed consisted of clay and silt-sized particles of freshly quenched lava from the TEB flow in Kilauea, Hawaii. Soluble Fe(II) or chemically reduced NAu-2 smectite (RS) were employed as positive controls to verify Fe(II) oxidation activity in the culture systems. All three systems demonstrated oxidation of soluble Fe(II) and/or structural Fe(II) in RS, whereas no oxidation of Fe(II) in BG material was observed. The inability of the Straub culture to oxidize Fe(II) in BG was particularly surprising, as this culture can oxidize other insoluble Fe(II)-bearing minerals such as biotite, magnetite, and siderite. Although the reason for the resistance of the BG toward enzymatic oxidation remains unknown, it seems possible that the absence of distinct crystal faces or edge sites in the amorphous glass renders the material resistant to such attack. These findings have implications with regard to the idea that Fe(II)-Si-rich phases in basalt rocks could provide a basis for chemolithotrophic microbial life on Mars, specifically in neutral-pH environments where acid-promoted mineral dissolution and

  16. Alteration of basaltic glass in Iceland as a natural analogue for nuclear waste glasses

    International Nuclear Information System (INIS)

    Crovisier, J.L.; Advocat, T.; Fritz, B.; Petit, J.C.

    1989-01-01

    The authors describe the longer term geochemical consequences of basaltic glass dissolution in fresh water at 0 0 C calculated with the computer code DISSOL. The clay minerals were represented by an ideal solid solution model (CISSFIT) able to describe variations in chemical composition of a clay phase in response to variations of the solution chemistry. The predicted mineral phases were iron hydroxides followed by kaolinite, TOT clays, chabazite and clinoptilolite. These results are in reasonably good agreement with experimental results and observations of altered subglacial hyaloclastites from Iceland. The formation of secondary products are mainly controlled by thermodynamic constraints. Kinetic effects, such as diffusion in the near glass surface are not important

  17. Development and characterization of basalt-glass ceramics for the immobilization of transuranic wastes

    International Nuclear Information System (INIS)

    Lokken, R.O.; Chick, L.A.; Thomas, L.E.

    1982-09-01

    Basalt-based waste forms were developed for the immobilization of transuranic (TRU) contaminated wastes. The specific waste studied is a 3:1 blend of process sludge and incinerator ash. Various amounts of TRU blended waste were melted with Pomona basalt powder. The vitreous products were subjected to a variety of heat treatment conditions to form glass ceramics. The total crystallinity of the glass ceramic, ranging from 20 to 45 wt %, was moderately dependent on composition and heat treatment conditions. Three parent glasses and four glass ceramics with varied composition and heat treatment were produced for detailed phase characterization and leaching. Both parent glasses and glass ceramics were mainly composed of a continuous, glassy matrix phase. This glass matrix entered into solution during leaching in both types of materials. The Fe-Ti rich dispersed glass phase was not significantly degraded by leaching. The glass ceramics, however, exhibited four to ten times less elemental releases during leaching than the parent glasses. The glass ceramic matrix probably contains higher Fe and Na and lower Ca and Mg relative to the parent glass matrix. The crystallization of augite in the glass ceramics is believed to contribute to the improved leach rates. Leach rates of the basalt glass ceramic are compared to those of other TRU nuclear waste forms containing 239 Pu

  18. Comparison of mechanical properties and structural changes of continous basalt and glass fibres at elevated temperatures

    Czech Academy of Sciences Publication Activity Database

    Černý, Martin; Glogar, Petr; Goliáš, V.; Hruška, J.; Jakeš, P.; Sucharda, Zbyněk; Vávrová, I.

    2007-01-01

    Roč. 51, č. 2 (2007), s. 82-88 ISSN 0862-5468 R&D Projects: GA ČR GA106/05/0817 Institutional research plan: CEZ:AV0Z30460519 Keywords : basalt fibre * glass fibre * tensile properties Subject RIV: JH - Ceramics, Fire-Resistant Materials and Glass Impact factor: 0.488, year: 2007

  19. Basaltic glasses from Iceland and the deep sea: Natural analogues to borosilicate nuclear waste-form glass

    International Nuclear Information System (INIS)

    Jercinovic, M.J.; Ewing, R.C.

    1987-12-01

    The report provides a detailed analysis of the alteration process and products for natural basaltic glasses. Information of specific applicability to the JSS project include: * The identification of typical alteration products which should be expected during the long-term corrosion process of low-silica glasses. The leached layers contain a relatively high proportion of crystalline phases, mostly in the form of smectite-type clays. Channels through the layer provide immediate access of solutions to the fresh glass/alteration layer interface. Thus, glasses are not 'protected' from further corrosion by the surface layer. * Corrosion proceeds with two rates - an initial rate in silica-undersaturated environments and a long-term rate in silica-saturated environments. This demonstrates that there is no unexpected change in corrosion rate over long periods of time. The long-term corrosion rate is consistent with that of borosilicate glasses. * Precipitation of silica-containing phases can result in increased alteration of the glass as manifested by greater alteration layer thicknesses. This emphasizes the importance of being able to predict which phases form during the reaction sequence. * For natural basaltic glasses the flow rate of water and surface area of exposed glass are critical parameters in minimizing glass alteration over long periods of time. The long-term stability of basalt glasses is enhanced when silica concentrations in solution are increased. In summary, there is considerable agreement between corrosion phenomena observed for borosilicate glasses in the laboratory and those observed for natural basalt glasses of great age. (With 121 refs.) (authors)

  20. Behavior of 99Tc in doped-glass/basalt hydrothermal interaction tests

    International Nuclear Information System (INIS)

    Coles, D.G.; Apted, M.J.

    1984-01-01

    The release of polyvalent radionuclides from a nuclear waste repository located in basalt may be sensitively related to the redox potential (Eh) imposed by the basalt. A series of tests are reported here, evaluating the effect of basalt on the concentrations of 99 Tc released into solution from a borosilicate glass waste form. Crushed PNL 76-68 glass, doped with 0.7 mg 99 Tc/g glass, was reacted with reference basalt groundwater under oxic hydrothermal conditions in a sampling autoclave, both alone and in the presence of crushed basalt. The steady state fluid concentrations of 99 Tc and various table species were determined from samples obtained at the test conditions of 200 0 C, 30 MPa, and a initial solution to solid mass ratio of 10 for both tests. In the glass + groundwater test, the 99 Tc concentration rose rapidly to about 50 mg/L after only 200 hr of run time and remained at a value between 50 and 60 mg/L throughout the duration of the test. For the basalt + glass + groundwater test, the 99 Tc concentration rose to an initial value of about 2.5 mg/L. At about 700 hr, the 99 Tc concentration began to drop rapidly until a value near the analytical detection limit (approximately 0.005 mg/L) was reached after a test duration of 1400 hr. It is concluded that the presence of basalt in these hydrothermal experiments reduces the concentration of 99 Tc in solution by nearly four orders of magnitude, probably by control of solution Eh and subsequent precipitation of a solid containing a reduced form of technetium. Reaction mechanisms are discussed that can account for these observations. 17 references, 1 figure

  1. Crystallization behaviors and seal application of basalt based glass-ceramics

    Science.gov (United States)

    Ateş, A.; Önen, U.; Ercenk, E.; Yılmaz, Ş.

    2017-02-01

    Basalt based glass-ceramics were prepared by conventional melt-quenching technique and subsequently converted to glass-ceramics by a controlled nucleation and crystallization process. Glass materials were obtained by melt at 1500°C and quenched in cold water. The powder materials were made by milling and spin coating. The powders were applied on the 430 stainless steel interconnector material, and heat treatment was carried out. The interface characteristics between the glass-ceramic layer and interconnector were investigated by using X-ray diffraction analysis (XRD) and scanning electron microscopy (SEM). The results showed that the basalt base glass-ceramic sealant material exhibited promising properties to use for SOFC.

  2. Influences of chemical aging on the surface morphology and crystallization behavior of basaltic glass fibers

    DEFF Research Database (Denmark)

    Lund, Majbritt Deichgræber; Yue, Yuanzheng

    2008-01-01

    The impact of aging in high humidity and water on the surface morphology and crystallization behavior of basaltic glass fibers has been studied using scanning electron microscopy, transmission electron microscopy, calorimetry and X-ray diffraction. The results show that interaction between...... the fibers and the surrounding media (high humidity or water at 70 C) leads to chemical changes strongly affecting the surface morphology. The crystallization peak temperature of the basaltic glass fibers are increased without changing the onset temperature, this may be caused by a chemical depletion...

  3. A Brillouin scattering study of hydrous basaltic glasses: the effect of H2O on their elastic behavior and implications for the densities of basaltic melts

    Science.gov (United States)

    Wu, Lei; Yang, De-Bin; Liu, Jun-Xiu; Hu, Bo; Xie, Hong-Sen; Li, Fang-Fei; Yu, Yang; Xu, Wen-Liang; Gao, Chun-Xiao

    2017-06-01

    Hydrous basalt glasses with water contents of 0-6.82% were synthesized using a multi-anvil press at 1.0-2.0 GPa and 1200-1400 °C. The starting materials were natural Mesozoic basalts from the eastern North China Craton (NCC). Their sound velocities and elastic properties were measured by Brillouin scattering spectroscopy. The longitudinal ( V P) and shear ( V S) wave velocities decreased with increasing water content. Increasing the synthesis pressure resulted in the glass becoming denser, and finally led to an increase in V P. As the degree of depolymerization increased, the V P, V S, and shear and bulk moduli of the hydrous basalt glasses decreased, whereas the adiabatic compressibility increased. The partial molar volumes of water (ν) under ambient conditions were independent of composition, having values of 11.6 ± 0.8, 10.9 ± 0.6 and 11.5 ± 0.5 cm3/mol for the FX (Feixian), FW (Fuxin), and SHT (Sihetun) basalt glasses, respectively. However, the {{V}_{{{{H}}_{{2}}}{O}}} values measured at elevated temperatures and pressures are increasing with increasing temperature or decreasing pressure. The contrasting densities of these hydrous basalt melts with those previously reported for mid-ocean ridge basalt and preliminary reference Earth model data indicate that hydrous basalt melts may not maintain gravitational stability at the base of the upper mantle.

  4. Effect of Crystallisation Degree on Hardness of Basaltic Glass-Ceramics

    DEFF Research Database (Denmark)

    Jensen, Martin; Smedskjær, Morten Mattrup; Yue, Yuanzheng

    The dependence of hardness of basaltic glass-ceramics on their crystallisation degree has been explored by means of differential scanning calorimetry, optical microscopy, X-ray diffraction, and Vickers indentation. Different degrees of crystallisation in the basaltic glasses have been obtained...... by varying the temperature of heat treatment. The change of the relative degree of crystallisation with the heat treatment temperature can be described by an empirical model established in this work. The predominant crystalline phase in the glass has been identified as the pyroxene augite. The hardness...... principle calculations. It is found that the hardness of the glass phase decreases slightly with an increase in the degree of crystallisation, while that of the augite phase drastically decreases....

  5. Study of crystallization of a basalt glass; Estudo de cristalizacao de um vidro de basalto

    Energy Technology Data Exchange (ETDEWEB)

    Nishimura, Fernando Takahiro; Hashizume, Camila Mina; Toffoli, Samuel Marcio, E-mail: toffoli@usp.b [Universidade de Sao Paulo (EP/USP), SP (Brazil). Escola Politecnica. Dept. de Engenharia Metalurgica e de Materiais

    2009-07-01

    Basalt vitreous ceramics posses industrial importance by presenting high mechanical resistance to the abrasion. It was studied the obtention and the crystallization of a glass obtained from a basalt of Campinas, Sao Paulo, Brazil, aiming to develop a material with great abrasive resistance. Fusions were made at 1400 deg Celsius in electrical oven and in alumina crucible, of fine residues of basalt mining. The obtained glass was treated in a crystallization temperature of 880 deg Celsius, determined by DSC, by various time of treatment. The present main crystalline phases, detected by XRD, were the magnesium-ferrite (MgFe{sub 2}O{sub 4}) and the diopsid Ca(Mg,Fe,Al)(Si,Al){sub 2}O{sub 6}. Analysing the density by the Archimedes methodology and the DRX it was possible to follow the crystallization kinetic up.

  6. Degradation of basalt fibre and glass fibre/epoxy resin composites in seawater

    International Nuclear Information System (INIS)

    Wei Bin; Cao Hailin; Song Shenhua

    2011-01-01

    Research highlights: → BFRP degradation process in seawater environment was first investigated. → The mass gain change includes two effects: absorption and extraction. → The interfacial adhesion of BFRP is bigger than GFRP. → After treated, the bending strength of BFRP is lower than GFRP. → Reducing the Fe 2+ in the basalt fibre could lead to a higher stability of BFRP. - Abstract: Epoxy resins reinforced, respectively, by basalt fibres and glass fibres were treated with a seawater solution for different periods of time. Both the mass gain ratio and the strength maintenance ratio of the composites were examined after the treatment. The fracture surfaces were characterized using scanning electron microscopy. The tensile and bending strengths of the seawater treated samples showed a decreasing trend with treating time. In general, the anti-seawater corrosion property of the basalt fibre reinforced composites was almost the same as that of the glass fibre reinforced ones. Based on the experimental results, possible corrosion mechanisms were explored, indicating that an effective lowering of the Fe 2+ content in the basalt fibre could lead to a higher stability for the basalt fibre reinforced composites in a seawater environment.

  7. Impact of iron chelators on short-term dissolution of basaltic glass

    Science.gov (United States)

    Perez, Anne; Rossano, Stéphanie; Trcera, Nicolas; Verney-Carron, Aurélie; Huguenot, David; van Hullebusch, Eric D.; Catillon, Gilles; Razafitianamaharavo, Angelina; Guyot, François

    2015-08-01

    Although microorganisms seem to play an important role in the alteration processes of basaltic glasses in solution, the elementary mechanisms involved remain unclear in particular with regard to the role of organic ligands excreted by the cells. Two glasses, one with Fe and one without Fe were synthesized to model basaltic glass compositions. Fe in the glass was mostly Fe(III) for enhancing interaction with siderophores, yet with small but significant amounts of Fe(II) (between 10% and 30% of iron). The prepared samples were submitted to abiotic alteration experiments in buffered (pH 6.4) diluted solutions of metal-specific ligands, namely oxalic acid (OA, 10 mM), desferrioxamine (DFA, 1 mM) or 2,2‧-bipyridyl (BPI, 1 mM). Element release from the glass into the solution after short term alteration (maximum 1 week) was measured by ICP-OES, and normalized mass losses and relative release ratios (with respect to Si) were evaluated for each element in each experimental condition. The presence of organic ligands had a significant effect on the dissolution of both glasses. Trivalent metals chelators (OA, DFA) impacted on the release of Fe3+ and Al3+, and thus on the global dissolution of both glasses, enhancing all release rates and dissolution stoichiometry (release rates were increased up to 7 times for Al or Fe). As expected, the mostly divalent metal chelator BPI interacted preferentially with Ca2+, Mg2+ and Fe2+. This study thus allows to highlight the central roles of iron and aluminium in interaction with some organic ligands in the alteration processes of basaltic glasses. It thus provides a step toward understanding the biological contribution of this fundamental geological process.

  8. Green glass vitrophyre 78526 - An impact of very low-Ti mare basalt composition

    Science.gov (United States)

    Warner, R. D.; Taylor, G. J.; Kiel, K.; Planner, H. H.; Nehru, C. E.; Ma, M.-S.; Schmitt, R. A.

    1978-01-01

    Rake sample 78526 is an 8.77 g rock consisting primarily of vitrophyric pale green glass with subordinate mineral and lithic relics. Petrographic and compositional evidence leads to the following conclusions: (1) the bulk composition represents that of a mixture formed by impact melting of at least two different textural and compositional varieties of VLT mare basalt that are now present in the rock as lithic relics and a poorly defined low-Ti mare basalt component observed in thin section only in the form of isolated mineral relics; (2) the admixed VLT mare basalts had REE abundances lower than those found in other mare basalts (but probably higher than emerald green glass) and REE patterns showing significant enrichment of the heavy relative to light REE's, suggesting that they were derived by comparatively high degrees of partial melting of a clinopyroxene-rich source region; and (3) the impact melt supercooled to produce the vitrophyre, with rather sharply contrasting textural domains present in the vitrophyre resulting from differences in nucleation kinetics and degrees of supercooling in various portions of the sample.

  9. U-Pb, Sm-Nd and Rb-Sr systematics of mid-ocean ridge basalt glasses

    Energy Technology Data Exchange (ETDEWEB)

    Cohen, R S; Evensen, N M; Hamilton, P J; O' Nions, R K [Columbia Univ., Palisades, NY (USA). Lamont-Doherty Geological Observatory

    1980-01-10

    The measurement of Pb, Nd and Sr isotopes in basalt glasses from mid-ocean ridges reveals correlations in isotope parameters which have important implications for the differentiation history of the mantle.

  10. Evidence for microbial activity at the glass-alteration interface in oceanic basalts

    Science.gov (United States)

    Torsvik, Terje; Furnes, Harald; Muehlenbachs, Karlis; Thorseth, Ingunn H.; Tumyr, Ole

    1998-10-01

    A detailed microbiological and geochemical study related to the alteration of basaltic glass of pillow lavas from the oceanic crust recovered from Hole 896A on the Costa Rica Rift (penetrating 290 m into the volcanic basement) has been carried out. A number of independent observations, pointing to the influence of microbes, may be summarized as follows: (1) Alteration textures are reminiscent of microbes in terms of form and shape. (2) Altered material contains appreciable amounts of C, N and K, and the N/C ratios are comparable to those of nitrogen-starved bacteria. (3) Samples stained with a dye (DAPI) that binds specifically to nucleic acids show the presence of DNA in the altered glass. Further, staining with fluorescent labeled oligonucleotide probes that hybridize specifically to 16S-ribosomal RNA of bacteria and archaea demonstrate their presence in the altered part of the glass. (4) Disseminated carbonate in the glassy margin of the majority of pillows shows δ 13C values, significantly lower than that of fresh basalt, also suggests biological activity. The majority of the samples have δ 18O values indicating temperatures of 20-100°C, which is in the range of mesophilic and thermophilic micro-organisms.

  11. Regulation of arsenic mobility on basaltic glass surfaces by speciation and pH.

    Science.gov (United States)

    Sigfusson, Bergur; Meharg, Andrew A; Gislason, Sigurdur R

    2008-12-01

    The importance of geothermal energy as a source for electricity generation and district heating has increased over recent decades. Arsenic can be a significant constituent of the geothermal fluids pumped to the surface during power generation. Dissolved As exists in different oxidation states, mainly as As(III) and As(V), and the charge of individual species varies with pH. Basaltic glass is one of the most important rock types in many high-temperature geothermal fields. Static batch and dynamic column experiments were combined to generate and validate sorption coefficients for As(III) and As(V) in contact with basaltic glass at pH 3-10. Validation was carried out by two empirical kinetic models and a surface complexation model (SCM). The SCM provided a better fit to the experimental column data than kinetic models at high pH values. However, in certain circumstances, an adequate estimation of As transport in the column could not be attained without incorporation of kinetic reactions. The varying mobility with pH was due to the combined effects of the variable charge of the basaltic glass with the pH point of zero charge at 6.8 and the individual As species as pH shifted, respectively. The mobility of As(III) decreased with increasing pH. The opposite was true for As(V), being nearly immobile at pH 3 to being highly mobile at pH 10. Incorporation of appropriate sorption constants, based on the measured pH and Eh of geothermal fluids, into regional groundwater-flow models should allow prediction of the As(III) and As(V) transport from geothermal systems to adjacent drinking water sources and ecosystems.

  12. Estimate of long-term dissolution rate of basaltic glass. A case study on Mt. Fuji area

    Energy Technology Data Exchange (ETDEWEB)

    Shikazono, Naotatsu; Takino, Akitsugu [Keio Univ., Environmental Geochemistry, Tokyo (Japan)

    2002-03-01

    Bulk compositional, mineralogical and physical properties of weathered basaltic ash soil ('Andisol') derived mainly from Mt. Fuji were studied. Mineralogical studies revealed that the dominant primary material and weathering products are volcanic glass, allophane and halloysite and the sequence of weathering is volcanic glass {yields} allophane {yields} 10A halloysite {yields} 7A halloysite. X-ray fluorescence analysis indicates that the relative elemental mobilities during the weathering is Na, Ca>K>Mg>P>Si>Ti, Fe>Al>Mn. The trends of soilwater chemistry (H{sub 4}SiO{sub 4} concentration) with depth were calculated based on dissolution - precipitation kinetics - fluid flow coupling model. In order to calculate the trends, the data on present-day annual rainfall, solubility of basalt glass, porosity and specific weight of soil, deposition rate of volcanic ash and grain size of volcanic glass were used. The calculated results were compared with analytical trends of soilwater chemistry. From this comparison the dissolution rate constant of basalt glass was estimated to be 10{sup -9.4} - 10{sup -9.2} (mole Si m{sup -2} s{sup -1}). This value is consistent with previous experimental dissolution rate constant of basalt glass reported in the literature. (author)

  13. Estimate of long-term dissolution rate of basaltic glass. A case study on Mt. Fuji area

    International Nuclear Information System (INIS)

    Shikazono, Naotatsu; Takino, Akitsugu

    2002-01-01

    Bulk compositional, mineralogical and physical properties of weathered basaltic ash soil ('Andisol') derived mainly from Mt. Fuji were studied. Mineralogical studies revealed that the dominant primary material and weathering products are volcanic glass, allophane and halloysite and the sequence of weathering is volcanic glass → allophane → 10A halloysite → 7A halloysite. X-ray fluorescence analysis indicates that the relative elemental mobilities during the weathering is Na, Ca>K>Mg>P>Si>Ti, Fe>Al>Mn. The trends of soilwater chemistry (H 4 SiO 4 concentration) with depth were calculated based on dissolution - precipitation kinetics - fluid flow coupling model. In order to calculate the trends, the data on present-day annual rainfall, solubility of basalt glass, porosity and specific weight of soil, deposition rate of volcanic ash and grain size of volcanic glass were used. The calculated results were compared with analytical trends of soilwater chemistry. From this comparison the dissolution rate constant of basalt glass was estimated to be 10 -9.4 - 10 -9.2 (mole Si m -2 s -1 ). This value is consistent with previous experimental dissolution rate constant of basalt glass reported in the literature. (author)

  14. Comparative experimental study of dynamic compressive strength of mortar with glass and basalt fibres

    Directory of Open Access Journals (Sweden)

    Kruszka Leopold

    2015-01-01

    Full Text Available Specimen reinforced with glass and basalt fibers were prepared using Standard Portland cement (CEM I, 52.5 R as prescribed by EN 197-1 and standard sand, in accordance with EN 196-1. From this cementitious mixture, a reference cement mortar without fibers was first prepared. Compressive strength, modulus of elasticity, and mod of fracture were determined for all specimens. Static and dynamic properties were investigated using Instron testing machine and split Hopkinson pressure bar, respectively. Content of the glass fibers in the mortar does not influence the fracture stress at static loading conditions in a clearly observed way. Moreover at dynamic range 5% content of the fiber results in a significant drop of fracture stress. Analysis of the basalt fibers influence on the fracture stress shows that optimal content of this reinforcement is equal to 3% for both static and dynamic loading conditions. Further increase of the fiber share gives the opposite effect, i.e. drop of the fracture stress.

  15. Comparative experimental study of dynamic compressive strength of mortar with glass and basalt fibres

    Science.gov (United States)

    Kruszka, Leopold; Moćko, Wojciech; Fenu, Luigi; Cadoni, Ezio

    2015-09-01

    Specimen reinforced with glass and basalt fibers were prepared using Standard Portland cement (CEM I, 52.5 R as prescribed by EN 197-1) and standard sand, in accordance with EN 196-1. From this cementitious mixture, a reference cement mortar without fibers was first prepared. Compressive strength, modulus of elasticity, and mod of fracture were determined for all specimens. Static and dynamic properties were investigated using Instron testing machine and split Hopkinson pressure bar, respectively. Content of the glass fibers in the mortar does not influence the fracture stress at static loading conditions in a clearly observed way. Moreover at dynamic range 5% content of the fiber results in a significant drop of fracture stress. Analysis of the basalt fibers influence on the fracture stress shows that optimal content of this reinforcement is equal to 3% for both static and dynamic loading conditions. Further increase of the fiber share gives the opposite effect, i.e. drop of the fracture stress.

  16. Augite-anorthite glass-ceramics from residues of basalt quarry and ceramic wastes

    Directory of Open Access Journals (Sweden)

    Gamal A. Khater

    2015-06-01

    Full Text Available Dark brown glasses were prepared from residues of basalt quarries and wastes of ceramic factories. Addition of CaF2, Cr2O3 and their mixture CaF2-Cr2O3 were used as nucleation catalysts. Generally, structures with augite and anorthite as major phases and small amount of magnetite and olivine phases were developed through the crystallization process. In the samples heat treated at 900 °C the dominant phase is augite, whereas the content of anorthite usually overcomes the augite at higher temperature (1100 °C. Fine to medium homogenous microstructures were detected in the prepared glass-ceramic samples. The coefficient of thermal expansion and microhardness measurements of the glass-ceramic samples were from 6.16×10-6 to 8.96×10-6 °C-1 (in the 20–500 °C and 5.58 to 7.16 GP, respectively.

  17. The Origin of Nanoscopic Grooving on Vesicle Walls in Submarine Basaltic Glass: Implications for Nanotechnology

    Directory of Open Access Journals (Sweden)

    Jason E. French

    2009-01-01

    Full Text Available Dendritic networks of nanoscopic grooves measuring 50–75 nm wide by <50 nm deep occur on the walls of vesicles in the glassy margins of mid-ocean ridge pillow basalts worldwide. Until now, their exact origin and significance have remained unclear. Here we document examples of such grooved patterns on vesicle walls in rocks from beneath the North Atlantic Ocean, and give a fluid mechanical explanation for how they formed. According to this model, individual nanogrooves represent frozen viscous fingers of magmatic fluid that were injected into a thin spheroidal shell of hot glass surrounding each vesicle. The driving mechanism for this process is provided by previous numerical predictions of tangential tensile stress around some vesicles in glassy rocks upon cooling through the glass transition. The self-assembling nature of the dendritic nanogrooves, their small size, and overall complexity in form, are interesting from the standpoint of exploring new applications in the field of nanotechnology. Replicating such structures in the laboratory would compete with state-of-the-art nanolithography techniques, both in terms of pattern complexity and size, which would be useful in the fabrication of a variety of grooved nanodevices. Dendritic nanogrooving in SiO2 glass might be employed in the manufacturing of integrated circuits.

  18. Hydrotalcite formed by alteration of R7T7 nuclear waste glass and basaltic glass in salt brine at 190 degrees C

    International Nuclear Information System (INIS)

    Abdelouas, A.; Crovisier, J.L.; Lutze, W.; Mueller, R.; Bernotat, W.

    1994-01-01

    The R7T7 and synthetic basaltic glasses were submitted to corrosion in a saline MgCl 2 dominated solution at 190 degrees C. For both glasses, the early alteration product is a hydrotalcite-like compound in which HPO 4 2- , SO 4 2- and Cl - substitutes to CO 3 2- . The measured d 003 spacing is 7.68 angstrom for the hydrotalcite formed from R7T7 glass and 7.62 angstrom for the hydrotalcite formed from basaltic glass which reflect the high aluminium content. Chemical microanalyses show that the hydrotalcite is subsequently covered by a silica-rich gel which evolves into saponite after few months

  19. Basaltic scorias from Romania - complex building material us for concrete, glazing tiles, ceramic glazes, glass ceramics, mineral wool

    Energy Technology Data Exchange (ETDEWEB)

    Marica, S.; Cetean, V. [PROCEMA S.A., Bucharest (Romania)

    2002-07-01

    The most spectacular deposit of basaltic scoria from Romania is the Heghes Hill from Racos, locality situated in the central part of country. This deposit emerged as grains of various dimensions, as volcanic ash with specific porosity up to 30% and vacuolar basaltic rocks. All types of basaltic scorias have specific vacuolar appearance, red- brick or blackish - grey coloured, scoria textures and similar chemical composition with others basalts of the world. The physical and mechanical characteristics determined included the scorias in the Heghes Hill in the following categories : light rocks (2,98 g/ dmc), porous(11,04%), similar to expanded slag, slightly absorbing rocks (3,86%), with low compression strengths (1700 daN/cmp). Basaltic scoria from Heghes is a very good row material for the manufacture of concrete, for obtain decorative cutting tiles glazing with ceramic and basaltic glazes (up to 40%) varied the range of colours and for obtaining glass ceramic, mineral wool, crushing sand for road maintenance, heat -insulating bricks and shid -proof material. (orig.)

  20. Phosphorus Adsorption and Desorption Properties of Minnesota Basalt Lunar Simulant and Lunar Glass Simulant

    Science.gov (United States)

    Sutter, Brad; Hossner, Lloyd R.; Ming, Douglas W.

    1996-01-01

    Phosphorus (P) adsorption and desorption characteristics of Minnesota Basalt Lunar Simulant (MBLS) and Lunar Glass Simulant (LGS) were evaluated. Results of P interactions with lunar simulants indicated that mineral and glass components adsorbed between 50 and 70% of the applied P and that between 85 and 100% of the applied P was desorbed. The Extended Freundlich equation best described the adsorption data (r(sup 2) = 0.92), whereas the Raven/Hossner equation best described the desorption data ((r(sup 2) = 0.97). Kinetic desorption results indicated that MBLS and LGS released most of their P within 15 h. The expanded Elovich equation fit the data best at shorter times while t/Q(sub DT) equation had a better fit at longer times. These results indicate that P does not strongly adsorb to the two simulants and that any P that was adsorbed was readily desorbed in the presence of anion exchange resin. This work suggests that multiple small applications of P (10-20 mg P/kg) should be added to the simulants to ensure adequate solution P for plant uptake and efficient use of P fertilizer.

  1. The effects of stacking sequence and thermal cycling on the flexural properties of laminate composites of aluminium-epoxy/basalt-glass fibres

    Science.gov (United States)

    Abdollahi Azghan, Mehdi; Eslami-Farsani, Reza

    2018-02-01

    The current study aimed at investigating the effects of different stacking sequences and thermal cycling on the flexural properties of fibre metal laminates (FMLs). FMLs were composed of two aluminium alloy 2024-T3 sheets and epoxy polymer-matrix composites that have four layers of basalt and/or glass fibres with five different stacking sequences. For FML samples the thermal cycle time was about 6 min for temperature cycles from 25 °C to 115 °C. Flexural properties of samples evaluated after 55 thermal cycles and compared to non-exposed samples. Surface modification of aluminium performed by electrochemical treatment (anodizing) method and aluminium surfaces have been examined by scanning electron microscopy (SEM). Also, the flexural failure mechanisms investigated by the optical microscope study of fractured surfaces. SEM images indicated that the porosity of the aluminium surface increased after anodizing process. The findings of the present study showed that flexural modulus were maximum for basalt fibres based FML, minimum for glass fibres based FML while basalt/glass fibres based FML lies between them. Due to change in the failure mechanism of basalt/glass fibres based FMLs that have glass fibres at outer layer of the polymer composite, the flexural strength of this FML is lower than glass and basalt fibres based FML. After thermal cycling, due to the good thermal properties of basalt fibres, flexural properties of basalt fibres based FML structures decreased less than other composites.

  2. Structural Iron (II) of Basaltic Glass as an Energy Source for Zetaproteobacteria in an Abyssal Plain Environment, Off the Mid Atlantic Ridge.

    Science.gov (United States)

    Henri, Pauline A; Rommevaux-Jestin, Céline; Lesongeur, Françoise; Mumford, Adam; Emerson, David; Godfroy, Anne; Ménez, Bénédicte

    2015-01-01

    To explore the capability of basaltic glass to support the growth of chemosynthetic microorganisms, complementary in situ and in vitro colonization experiments were performed. Microbial colonizers containing synthetic tholeitic basaltic glasses, either enriched in reduced or oxidized iron, were deployed off-axis from the Mid Atlantic Ridge on surface sediments of the abyssal plain (35°N; 29°W). In situ microbial colonization was assessed by sequencing of the 16S rRNA gene and basaltic glass alteration was characterized using Scanning Electron Microscopy, micro-X-ray Absorption Near Edge Structure at the Fe-K-edge and Raman microspectroscopy. The colonized surface of the reduced basaltic glass was covered by a rind of alteration made of iron-oxides trapped in a palagonite-like structure with thicknesses up to 150 μm. The relative abundance of the associated microbial community was dominated (39% of all reads) by a single operational taxonomic unit (OTU) that shared 92% identity with the iron-oxidizer Mariprofundus ferrooxydans PV-1. Conversely, the oxidized basaltic glass showed the absence of iron-oxides enriched surface deposits and correspondingly there was a lack of known iron-oxidizing bacteria in the inventoried diversity. In vitro, a similar reduced basaltic glass was incubated in artificial seawater with a pure culture of the iron-oxidizing M. ferrooxydans DIS-1 for 2 weeks, without any additional nutrients or minerals. Confocal Laser Scanning Microscopy revealed that the glass surface was covered by twisted stalks characteristic of this iron-oxidizing Zetaproteobacteria. This result supported findings of the in situ experiments indicating that the Fe(II) present in the basalt was the energy source for the growth of representatives of Zetaproteobacteria in both the abyssal plain and the in vitro experiment. In accordance, the surface alteration rind observed on the reduced basaltic glass incubated in situ could at least partly result from their activity.

  3. Alteration of Basaltic Glass to Mg/Fe-Smectite under Acidic Conditions: A Potential Smectite Formation Mechanism on Mars

    Science.gov (United States)

    Peretyazhko, Tanya; Sutter, Brad; Ming, Douglas W.

    2014-01-01

    Phyllosilicates of the smectite group including Mg- and Fe-saponite and Fe(III)-rich nontronite have been identified on Mars. Smectites are believed to be formed under neutral to alkaline conditions that prevailed on early Mars. This hypothesis is supported by the observation of smectite and carbonate deposits in Noachian terrain on Mars. However, smectite may have formed under mildly acidic conditions. Abundant smectite formations have been detected as layered deposits hundreds of meters thick in intracrater depositional fans and plains sediments, while no large deposits of carbonates are found. Development of mildly acidic conditions at early Mars might allow formation of smectite but inhibit widespread carbonate precipitation. Little is known regarding the mechanisms of smectite formation from basaltic glass under acidic conditions. The objective of this study was to test a hypothesis that Mars-analogue basaltic glass alters to smectite minerals under acidic conditions (pH 4). The effects of Mg and Fe concentrations and temperature on smectite formation from basaltic glass were evaluated. Phyllosilicate synthesis was performed in batch reactors (Parr acid digestion vessel) under reducing hydrothermal conditions at 200 C and 100 C. Synthetic basaltic glass with a composition similar to that of the Gusev crater rock Adirondack (Ground surface APXS measurement) was used in these experiments. Basaltic glass was prepared by melting and quenching procedures. X-ray diffraction (XRD) analysis indicated that the synthesized glass was composed of olivine, magnetite and X-ray amorphous phase. Samples were prepared by mixing 250 mg Adirondack with 0.1 M acetic acid (final pH 4). In order to study influence of Mg concentration on smectite formation, experiments were performed with addition of 0, 1 and 10 mM MgCl2. After 1, 7 and 14 day incubations the solution composition was analyzed by Inductively Coupled Plasma Mass Spectrometry (ICP-MS) and the altered glass and formed

  4. Glass and mineral chemistry of northern central Indian ridge basalts: Compositional diversity and petrogenetic significance

    Digital Repository Service at National Institute of Oceanography (India)

    Ray, Dwijesh; Banerjee, R.; Iyer, S.D.; Basavalingu, B.; Mukhopadhyay, S.

    -88)), diopside (Wo sub(45-51), En sub(25-37), Fs sub14-24)), and titanomagnetite (FeO sub(t) approx. 63.5 wt% and Ti0 sub(2) approx. 22.69 wt%). The whole-rock composition of these basalts has similar Mg [mole Mg/mole(Mg+Fe sup(2+))] (VT basalt: approx. 0...

  5. Physical volcanology of the mafic segment of the subaqueous New Senator caldera, Abitibi greenstone belt, Quebec, Canada

    International Nuclear Information System (INIS)

    Moore, Lyndsay N; Mueller, Wulf U

    2008-01-01

    Archean calderas provide valuable insight into internal geometries of subaqueous calderas. The New Senator caldera, Abitibi greenstone belt, Canada, is an Archean example of a subaqueous nested caldera with a basal stratigraphy dominated by gabbro-diorite dykes and sills, ponded magmas and basalt and andesite lava flows. The aim of our study is to focus on the use of physical volcanology to differentiate between the various mafic units found at the base of the New Senator caldera. Differentiation between these various mafic units is important from an exploration point of view because in modern subaqueous summit calders (e.g. Axial Seamount) margins of ponded magmas are often sites of VMS formation.

  6. Physical volcanology of the mafic segment of the subaqueous New Senator caldera, Abitibi greenstone belt, Quebec, Canada

    Energy Technology Data Exchange (ETDEWEB)

    Moore, Lyndsay N; Mueller, Wulf U [Universite du Quebec a Chicoutimi, 555 boul. du l' Universite, Chicoutimi, Quebec, G7H2B1 (Canada)], E-mail: lyndsay.moore@uqac.ca

    2008-10-01

    Archean calderas provide valuable insight into internal geometries of subaqueous calderas. The New Senator caldera, Abitibi greenstone belt, Canada, is an Archean example of a subaqueous nested caldera with a basal stratigraphy dominated by gabbro-diorite dykes and sills, ponded magmas and basalt and andesite lava flows. The aim of our study is to focus on the use of physical volcanology to differentiate between the various mafic units found at the base of the New Senator caldera. Differentiation between these various mafic units is important from an exploration point of view because in modern subaqueous summit calders (e.g. Axial Seamount) margins of ponded magmas are often sites of VMS formation.

  7. Natural fumarolic alteration of fluorapatite, olivine, and basaltic glass, and implications for habitable environments on Mars.

    Science.gov (United States)

    Hausrath, Elisabeth M; Tschauner, Oliver

    2013-11-01

    Fumaroles represent a very important potential habitat on Mars because they contain water and nutrients. Global deposition of volcanic sulfate aerosols may also have been an important soil-forming process affecting large areas of Mars. Here we identify alteration from the Senator fumarole, northwest Nevada, USA, and in low-temperature environments near the fumarole to help interpret fumarolic and acid vapor alteration of rocks and soils on Mars. We analyzed soil samples and fluorapatite, olivine, and basaltic glass placed at and near the fumarole in in situ mineral alteration experiments designed to measure weathering under natural field conditions. Using synchrotron X-ray diffraction, we clearly observe hydroxyl-carbonate-bearing fluorapatite as a fumarolic alteration product of the original material, fluorapatite. The composition of apatites as well as secondary phosphates has been previously used to infer magmatic conditions as well as fumarolic conditions on Mars. To our knowledge, the observations reported here represent the first documented instance of formation of hydroxyl-carbonate-bearing apatite from fluorapatite in a field experiment. Retreat of olivine surfaces, as well as abundant NH4-containing minerals, was also characteristic of fumarolic alteration. In contrast, alteration in the nearby low-temperature environment resulted in formation of large pits on olivine surfaces, which were clearly distinguishable from the fumarolic alteration. Raman signatures of some fumarolically impacted surfaces are consistent with detection of the biological molecules chlorophyll and scytenomin, potentially useful biosignatures. Observations of altered minerals on Mars may therefore help identify the environment of formation and understand the aqueous history and potential habitability of that planet.

  8. 230Th/238U and 226Ra/230Th fractionation in young basaltic glasses from the East Pacific Rise

    International Nuclear Information System (INIS)

    Reinitz, I.; Turekian, K.K.

    1989-01-01

    Mid-ocean ridge basalt (MORB) glasses treated to remove manganese and iron oxyhydroxide coatings containing U and Th decay chain nuclides sequestered from the ambient aqueous environment show little fractionation of ( 230 Th) from ( 238 U), but extensive enrichment of ( 226 Ra) over ( 230 Th). Chronometry based on ( 230 Th)-( 238 U) disequilibrium yields a mean age of 151,000 ± 55,000 (2σ) years ago for Th-U fractionation, from a source region with Th/U (atom ratio) = 1.58 ± 0.43 (2σ). ( 226 Ra) excesses over ( 230 Th) indicate an enrichment event more recent than the fractionation of Th from U. ( 226 Ra/ 230 Th) correlates well with K/U, providing a rough means of estimating the age since eruption of MORB glasses. (orig.)

  9. Tracking the Depleted Mantle Signature in Melt Inclusions and Residual Glass of Basaltic Martian Shergottites using Secondary Ionization Mass Spectrometry

    Science.gov (United States)

    Peters, Timothy J.; Simon, Justin I.; Jones, John H.; Usui, Tomohiro; Economos, Rita C.; Schmitt, Axel K.; McKeegan, Kevin D.

    2013-01-01

    Trace element abundances of depleted shergottite magmas recorded by olivine-hosted melt inclusions (MI) and interstitial mesostasis glass were measured using the Cameca ims-1270 ion microprobe. Two meteorites: Tissint, an olivine-­phyric basaltic shergottite which fell over Morocco July 18th 2001; and the Antarctic meteorite Yamato 980459 (Y98), an olivine-phyric basaltic shergottite with abundant glassy mesostasis have been studied. Chondrite-­normalized REE patterns for MI in Tissint and Y98 are characteristically LREE depleted and, within analytical uncertainty, parallel those of their respective whole rock composition; supporting each meteorite to represent a melt composition that has experienced closed-­system crystallization. REE profiles for mesostasis glass in Y98 lie about an order of magnitude higher than those from the MI; with REE profiles for Tissint MI falling in between. Y98 MI have the highest average Sm/Nd and Y/Ce ratios, reflecting their LREE depletion and further supporting Y98 as one of our best samples to probe the depleted shergotitte mantle. In general, Zr/Nb ratios overlap between Y98 and Tissint MI, Ce/Nb ratios overlap between Y98 MI and mesostasis glass, and Sm/Nd ratios overlap between Y98 mesostasis glass and Tissint MI. These features support similar sources for both, but with subtle geochemical differences that may reflect different melting conditions or fractionation paths during ascent from the mantle. Interestingly, the REE patterns for both Y98 bulk and MI analyses display a flattening of the LREE that suggests a crustal contribution to the Y98 parent melt. This observation has important implications for the origins of depleted and enriched shergottites.

  10. Dynamic strength of cylindrical fiber-glass shells and basalt plastic shells under multiple explosive loading

    Science.gov (United States)

    Syrunin, M. A.; Fedorenko, A. G.

    2006-08-01

    We have shown experimentally that, for cylindrical shells made of oriented fiberglass platic and basalt plastic there exists a critical level of deformations, at which a structure sustains a given number of explosions from the inside. The magnitude of critical deformation for cylindrical fiberglass shells depends linearly on the logarithm of the number of loads that cause failure. For a given type of fiberglass, there is a limiting level of explosive action, at which the number of loads that do not lead to failure can be sufficiently large (more than ˜ 102). This level is attained under loads, which are an order of magnitude lower than the limiting loads under a single explosive action. Basalt plastic shells can be repeatedly used even at the loads, which cause deformation by ˜ 30-50% lower than the safe value ˜ 3.3.5% at single loading.

  11. Nitrogen Concentrations and Isotopic Compositions of Seafloor-Altered Terrestrial Basaltic Glass: Implications for Astrobiology

    Science.gov (United States)

    Banerjee, N.R.; Izawa, M.R.M.; Kobayashi, K.; Lazzeri, K.; Ranieri, L.A.; Nakamura, E.

    2018-01-01

    Abstract Observed enrichments of N (and the δ15N of this N) in volcanic glasses altered on Earth's modern and ancient seafloor are relevant in considerations of modern global N subduction fluxes and ancient life on Earth, and similarly altered glasses on Mars and other extraterrestrial bodies could serve as valuable tracers of biogeochemical processes. Palagonitized glasses and whole-rock samples of volcanic rocks on the modern seafloor (ODP Site 1256D) contain 3–18 ppm N with δ15Nair values of up to +4.5‰. Variably altered glasses from Mesozoic ophiolites (Troodos, Cyprus; Stonyford volcanics, USA) contain 2–53 ppm N with δ15N of −6.3 to +7‰. All of the more altered glasses have N concentrations higher than those of fresh volcanic glass (for MORB, smectite, illite) in both the palagonitized cracks and the microtubules. These phyllosilicates (particularly illite), and possibly also zeolites, are the likely hosts for N in these glasses. Key Words: Nitrogen—Nitrogen isotope—Palagonite—Volcanic glass—Mars. Astrobiology 18, 330–342. PMID:29106312

  12. Noble gases in basalt glasses from a Mid-Atlantic Ridge topographic high at 14deg N - geodynamic consequences

    International Nuclear Information System (INIS)

    Staudacher, T.; Sarda, P.; Richardson, S.H.; Allegre, C.J.; Sagna, I.; Dmitriev, L.V.

    1989-01-01

    We present a complete noble gas study of mid-oceanic ridge basalt glasses (MORB) from a small ridge segment, centered on an along-strike topographic elevation of the Mid-Atlantic Ridge at about 14deg N. We have found the highest 40 Ar/ 36 Ar ratio ever observed for a MORB glass, i.e. 28,150±330 for sample 2ΠD40, correlated with high 129 Xe/ 130 Xe ratios and the highest noble gas concentrations in a so-called popping-rock, labeled 2ΠD43. The latter sample displays a 4 He/ 40 Ar * ratio of 2.0-2.7, which is close to the production ratio in the mantle due to the radioactive decay of U, Th and K. Hence, this sample probably best represents the elemental noble gas ratios in the mantle, from which we have computed the 4 He concentration in the mantle source of MORB to be 1.5x10 -5 cm 3 STP g -1 . High 4 He/ 3 He ratios in two of the samples from the summit of the topographic high indicate the presence of a U, Th-rich component in the mantle source, possibly old subducted oceanic crust and/or sediments, which could originate in the so-called mesosphere boundary layer. (orig.)

  13. Mineralogical textural and compositional data on the alteration of basaltic glass from Kilauea, Hawaii to 300 degrees C: Insights to the corrosion of a borosilicate glass waste-form

    International Nuclear Information System (INIS)

    Smith, D.K.

    1990-01-01

    Mineralogical, textural and compositional data accompanying greenschist facies metamorphism (to 300 degrees C) of basalts of the East Rift Zone (ERZ), Kilauea, Hawaii may be evaluated relative to published and experimental results for the surface corrosion of borosilicate glass. The ERZ alteration sequence is dominated by intermittent palagonite, interlayered smectite-chlorite, chlorite, and actinolite-epidote-anhydrite. Alteration is best developed in fractures and vesicles where surface reaction layers root on the glass matrix forming rinds in excess of 100 microns thick. Fractures control fluid circulation and the alteration sequence. Proximal to the glass surface, palagonite, Fe-Ti oxides and clays replace fresh glass as the surface reaction layer migrates inwards; away from the surface, amphibole, anhydrite, quartz and calcite crystallize from hydrothermal fluids in contact with the glass. The texture and composition of basaltic glass surfaces are similar to those of a SRL-165 glass leached statically for sixty days at 150 degrees C. While the ERZ reservoir is a complex open system, conservative comparisons between the alteration of ERZ and synthetic borosilicate glass are warranted. 31 refs., 2 figs

  14. Mechanical characterisation of hybrid composite laminates based on basalt fibres in combination with flax, hemp and glass fibres manufactured by vacuum infusion

    International Nuclear Information System (INIS)

    Petrucci, R.; Santulli, C.; Puglia, D.; Sarasini, F.; Torre, L.; Kenny, J.M.

    2013-01-01

    Highlights: ► For the first time, hybrid laminates with three different fibres were produced. ► Concerns are confirmed on the brittleness of hybrid laminates with basalt fibre core. ► An optimal configuration (FHB) for flexural properties was singled out. ► Differences between tensile and flexural properties of hybrids were identified. ► In general, the specific mechanical properties of the hybrids are quite high. - Abstract: This work concerns the production by vacuum infusion and the comparison of the properties of different hybrid composite laminates, based on basalt fibre composites as the inner core, and using also glass, flax and hemp fibre laminates to produce symmetrical configurations, all of them with a 21–23% fibre volume, in an epoxy resin. The laminates have been subjected to tensile, three-point flexural and interlaminar shear strength tests and their fracture surfaces have been characterised by scanning electron microscopy. The mechanical performance of all the hybrid laminates appears superior to pure hemp and flax fibre reinforced laminates and inferior to basalt fibre laminates. Among the hybrids, the best properties are offered by those obtained by adding glass and flax to basalt fibre reinforced laminates. Scanning electron microscopy (SEM) observation of hybrid laminates showed the diffuse presence of fibre pull-out in hemp and flax fibre reinforced layers and a general trend of brittle failure

  15. Experimental seawater-basaltic glass interaction at 50°C: Study of early developed phases by electron microscopy and X-ray photoelectron spectrometry

    Science.gov (United States)

    Crovisier, J. L.; Thomassin, J. H.; Juteau, T.; Eberhart, J. P.; Touray, J. C.; Baillif, P.

    1983-03-01

    Experiments on seawater-basaltic glass interaction were made using a particulary high seawater-basaltic glass ratio (14.5 g/cm 2; weight ratio: 50). A layered alteration skin is observed at the glass surface, while the variations in the composition of the seawater are imperceptible. Three zones of different composition and structure are distinguished: 1) An external zone, the composition of which evolved to saponite. 2) A median zone of hydrotalcite-like hydroxycarbonate (Mg 6Al 2CO 3(OH) 164H 2O). 3) An internal zone, between glass and hydroxycarbonates, richer in Fe and in Mg and in which a 10 Å interval is observed (by dark field examination) compatible with a TOT type clay mineral. The composition of this zone indicates a mixing of poorly crystalline products. The principal chemical exchanges between glass and solution are the release of Ca in solution and the contribution of Mg and CO 2 from seawater to form hydroxycarbonates, which are considered precursors of phyllosilicates. Comparison with natural phenomena (palagonitization) is made.

  16. Can Plant-Based Natural Flax Replace Basalt and E-Glass for Fiber-Reinforced Polymer Tubular Energy Absorbers? A Comparative Study on Quasi-Static Axial Crushing

    Directory of Open Access Journals (Sweden)

    Libo Yan

    2017-12-01

    Full Text Available Using plant-based natural fibers to substitute glass fibers as reinforcement of composite materials is of particular interest due to their economic, technical, and environmental significance. One potential application of plant-based natural fiber reinforced polymer (FRP composites is in automotive engineering as crushable energy absorbers. Current study experimentally investigated and compared the energy absorption efficiency of plant-based natural flax, mineral-based basalt, and glass FRP (GFRP composite tubular energy absorbers subjected to quasi-static axial crushing. The effects of number of flax fabric layer, the use of foam filler and the type of fiber materials on the crashworthiness characteristics, and energy absorption capacities were discussed. In addition, the failure mechanisms of the hollow and foam-filled flax, basalt, and GFRP tubes in quasi-static axial crushing were analyzed and compared. The test results showed that the energy absorption capabilities of both hollow and foam-filled energy absorbers made of flax were superior to the corresponding energy absorbers made of basalt and were close to energy absorbers made of glass. This study, therefore, indicated that flax fiber has the great potential to be suitable replacement of basalt and glass fibers for crushable energy absorber application.

  17. Formation of Fe/mg Smectite Under Acidic Conditions from Synthetic Adirondack Basaltic Glass: an Analog to Fe/mg Smectite Formation on Mars

    Science.gov (United States)

    Sutter, B.; Peretyazhko, T.; Morris, R. V.; Ming, D. W.

    2014-01-01

    Smectite has been detected as layered material hundreds of meters thick, in intracrater depositional fans, in plains sediments, and deposits at depth on Mars. If early Mars hosted a dense CO2 atmosphere, then extensive carbonate should have formed in the neutral/alkaline conditions expected for smectite formation. However, large carbonate deposits on Mars have not been discovered. Instead of neutral to moderately alkaline conditions, early Mars may have experienced mildly acidic conditions that allowed for Fe/Mg smectite formation but prevented widespread carbonate formation. The objective of this work is to demonstrate that Fe(II)/Mg saponite and nontronite can form in mildly acidic solutions (e.g., pH 4). Synthetic basaltic glass (Smectite was confirmed as the phyllosilicate after treatments with glycerol and KCl and heating to 550 C. Trioctahedral saponite was confirmed by the presence of a 4.58 to 4.63 Angstroms (02l) and 1.54Angstroms (060) peaks. Saponite concentration was highest, as indicated by XRD peak intensity, in the 10 mM Mg treatment followed by the 0 mM and then 10 mM Fe(II) treatments. This order of sapontite concentration suggests that Fe(II) additions may have a role in slowing the kinetics of saponite formation relative to the other treatments. Nontronite synthesis was attempted by exposing Adirondack basaltic glass to pH 4 oxic solutions (without N2 purge) at 200 C for 14 days. X-ray diffraction analysis indicated that mixtures of trioctahedral (saponite) and dioctahedral (nontronite) may have formed in these experiments based on the 02l and 060 peaks. Moessbauer analysis coupled with future experiments are planned to verify if nontronite can be formed under mildly acidic and oxic conditions. Results of this work demonstrate that acidic conditions could have occurred on an early Mars, which allowed for smectite formation but inhibited carbonate formation.

  18. Crustal accretion along the global mid-ocean ridge system based on basaltic glass and olivine-hosted melt inclusion compositions

    Science.gov (United States)

    Wanless, V. D.; Behn, M. D.

    2015-12-01

    The depth and distribution of crystallization at mid-ocean ridges controls the overall architecture of the oceanic crust, influences hydrothermal circulation, and determines geothermal gradients in the crust and uppermost mantle. Despite this, there is no overall consensus on how crystallization is distributed within the crust/upper mantle or how this varies with spreading rate. Here, we examine crustal accretion at mid-ocean ridges by combining crystallization pressures calculated from major element barometers on mid-ocean ridge basalt (MORB) glasses with vapor-saturation pressures from melt inclusions to produce a detailed map of crystallization depths and distributions along the global ridge system. We calculate pressures of crystallization from >11,500 MORB glasses from the global ridge system using two established major element barometers (1,2). Additionally, we use vapor-saturation pressures from >400 olivine-hosted melt inclusions from five ridges with variable spreading rates to constrain pressures and distributions of crystallization along the global ridge system. We show that (i) crystallization depths from MORB glasses increase and become less focused with decreasing spreading rate, (ii) maximum glass pressures are greater than the maximum melt inclusion pressure, which indicates that the melt inclusions do not record the deepest crystallization at mid-ocean ridges, and (iii) crystallization occurs in the lower crust/upper mantle at all ridges, indicating accretion is distributed throughout the crust at all spreading rates, including those with a steady-state magma lens. Finally, we suggest that the remarkably similar maximum vapor-saturation pressures (~ 3000 bars) in melt inclusion from all spreading rates reflects the CO2 content of the depleted upper mantle feeding the global mid-ocean ridge system. (1) Michael, P. & W. Cornell (1998), Journal of Geophysical Research, 103(B8), 18325-18356; (2) Herzberg, C. (2004), Journal of Petrology, 45(12), 2389.

  19. Sub-aqueous sulfur volcanos at Waiotapu, New Zealand

    Energy Technology Data Exchange (ETDEWEB)

    Grimes, S.; Rickard, D. [University of Wales, Cardiff (United Kingdom). Dept. of Earth Sciences; Browne, P.; Simmons, S. [University of Auckland (New Zealand). Geothermal Institute and Geology Dept.; Jull, T. [University of Arizona, Tucson (United States). AMS Facility

    1999-12-01

    Exhumed, sub-aqueous sulfur mounds occur in the Waiotapu geothermal area, New Zealand. The extinct mounds are < 2 m high and composed of small (< 0.5 cm) hollow spheres, and occasional teardrop-shaped globules. They are located within a drained valley that until recently was connected to Lake Whangioterangi. They were formed a maximum of 820 {+-} 80 years BP as a result of the rapid sub-aqueous deposition of sulfur globules, formed when fumarolic gases discharged through molten sulfur pools. Similar globules are now being formed by the discharge of fumarolic gases through a sub-aqueous molten sulfur pool in Lake Whangioterangi. (author)

  20. Apollo 15 yellow-brown volcanic glass: Chemistry and petrogenetic relations to green volcanic glass and olivine-normative mare basalts

    Energy Technology Data Exchange (ETDEWEB)

    Hughes, S.S.; Schmitt, R.A.; (Oregon State Univ., Corvallis (USA)); Delano, J.W. (State Univ. of New York, Albany (USA))

    1988-10-01

    Apollo 15 yellow-brown glass is one of twenty-five, high Mg, primary magmas emplaced on the lunar surface in pyroclastic eruptions. Forty spherules of this glass were individually analyzed by electron microprobe and INAA for major- and trace-elements. The abundances demonstrate that this primary magma was produced by partial melting of differentiated cumulates in the lunar mantle. Models are developed to explain the possible source-regions of several Apollo 15 and Apollo 12 low-Ti mare magmas as being products of hybridization involving three ancient differentiated components of a primordial lunar magma ocean: (a) early olivine {plus minus} orthopyroxene cumulates; (b) late-stage clinopyroxene + pigeonite + ilmenite + plagioclase cumulates; and (c) late-stage inter-cumulus liquid.

  1. Petrology of offshore basalts of Bombay harbour area, west coast of India

    Digital Repository Service at National Institute of Oceanography (India)

    Karisiddaiah, S.M.

    glass are conspicuous. The chemical data indicate that the basalts are tholeiitic. Secondary minerals encountered support the view that the basalts are spilitised. Basalts of this area show affinities to both continental and oceanic types especially...

  2. Subaqueous early eruptive phase of the late Aptian Rajmahal volcanism, India: Evidence from volcaniclastic rocks, bentonite, black shales, and oolite

    Directory of Open Access Journals (Sweden)

    Naresh C. Ghose

    2017-07-01

    Full Text Available The late Aptian (118–115 Ma continental flood basalts of the Rajmahal Volcanic Province (RVP are part of the Kerguelen Large Igneous Province, and constitute the uppermost part of the Gondwana Supergroup on the eastern Indian shield margin. The lower one-third of the Rajmahal volcanic succession contains thin layers of plant fossil-rich inter-trappean sedimentary rocks with pyroclasts, bentonite, grey and black shale/mudstone and oolite, whereas the upper two-thirds consist of sub-aerial fine-grained aphyric basalts with no inter-trappean material. At the eastern margin and the north-central sector of the RVP, the volcanics in the lower part include rhyolites and dacites overlain by enstatite-bearing basalts and enstatite-andesites. The pyroclastic rocks are largely felsic in composition, and comprise ignimbrite as well as coarse-grained tuff with lithic clasts, and tuff breccia with bombs, lapilli and ash that indicate explosive eruption of viscous rhyolitic magma. The rhyolites/dacites (>68 wt.% are separated from the andesites (<60 wt.% by a gap in silica content indicating their formation through upper crustal anatexis with only heat supplied by the basaltic magma. On the other hand, partially melted siltstone xenoliths in enstatite-bearing basalts suggest that the enstatite-andesites originated through mixing of the upper crust with basaltic magma, crystallizing orthopyroxene at a pressure-temperature of ∼3 kb/1150 °C. In contrast, the northwestern sector of the RVP is devoid of felsic-intermediate rocks, and the volcaniclastic rocks are predominantly mafic (basaltic in composition. Here, the presence of fine-grained tuffs, tuff breccia containing sideromelane shards and quenched texture, welded tuff breccia, peperite, shale/mudstone and oolite substantiates a subaqueous environment. Based on these observations, we conclude that the early phase of Rajmahal volcanism occurred under predominantly subaqueous conditions. The presence

  3. Subaqueous non-vesicular to poorly-vesicular shards: hydroclastic fragmentation on seamounts and summit calderas

    Science.gov (United States)

    Mueller, W. U.; Dingwell, D. B.; Downey, W. S.; Mastin, L. G.

    2008-12-01

    Recognizing pyroclastic deposits that originate directly from magmatic and phreatomagmatic explosions in a subaqueous setting is based upon sedimentary structures, such as massive, stratified, and graded beds as well as (pyro)clast size. Ideally such deposits form ordered fining-and thinning-upward sequences. Pumice, scoria, glass shards, euhedral and broken crystals, and lithic fragments are constituents that support an explosive heritage. Recent deep-sea ROV and submersible dives have retrieved non-vesicular to vesicle- poor, mm-scale, mafic shards in 5-15 cm-thick massive and/or graded (stratified) deposits, for which a subaqueous explosive origin has been inferred. These sheet hyaloclastites with variable shard shapes were first documented on Seamount 6 as deep-sea Limu O Pele at water depths > 1000 m. We identified in Seamount 6 samples equant to blocky shards with angular to subrounded terminations, but also subordinate hair-like and contorted glassy filaments, warped shards and irregular shards. Shards display internal laminations (flow-banding?) and have local perlitic fractures. Bubble wall shards derived from scoria burst were rare. In combination with all the above and a poor shard vesicularity (tubes and ponded magma in depths > 1000 m. We envision that hydrostatic pressure commensurate with water depth played a significant role. The deposits can be readily explained by a hydroclastic process whereby fragmentation occurred at the milli-second (Limu) to second scale (hyaloclastite). Hence, hyperquenched glass shards or thread-like glass filaments need not require magmatic explosivity. Constant surface interaction between aphyric, low-viscosity, high temperature, magma-lava at depth with seawater causes fragmentation (granulation) that can generate such delicate shards. The transfer of heat to the ambient medium, seawater, favours turbulent convection causing strong water movement that strips glassy rinds and lofts the fine-grained shards and Limu O Pele

  4. Petrochemistry and origin of basalt breccia from Ban Sap Sawat area, Wichian Buri, Phetchabun, central Thailand

    Directory of Open Access Journals (Sweden)

    Phisit Limtrakun

    2013-08-01

    Full Text Available Thailand is usually considered to be controlled by escape tectonics associated with India-Asia collision during theLate Cenozoic, and basaltic volcanism took place in this extensional period. This volcanism generated both subaqueous andsubaerial lava flows with tholeiitic to alkalic basaltic magma. The subaqueous eruptions represented by the studied WichianBuri basalts, Ban Sap Sawat in particular, are constituted by two main types of volcanic lithofacies, including lava flows andbasalt breccias. The lava flows are commonly porphyritic with olivine and plagioclase phenocrysts and microphenocrysts,and are uncommonly seriate textured. The basalt breccias are strongly vitrophyric texture with olivine and plagioclasephenocrysts and microphenocrysts. Chemical analyses indicate that both lava flows and basalt breccias have similar geochemical compositions, signifying that they were solidified from the same magma. Their chondrite normalized REE patternsand N-MORB normalized patterns are closely analogous to the Early to Middle Miocene tholeiites from central Sinkhote-Alinand Sakhalin, northeastern margin of the Eurasian continent which were erupted in a continental rift environment. The originfor the Wichian Buri basalts show similarity of lava flows and basalt breccias, in terms of petrography and chemical compositions, signifying that they have been formed from the same continental within-plate, transitional tholeiitic magma.

  5. Comparison of estimated and experimental subaqueous seed transport.

    Science.gov (United States)

    Scott Markwith; David Leigh

    2011-01-01

    We compare the estimates from the relative bed stability (RBS) equation that indicates incipient bed movement, and the inertial settling (‘Impact’) law and Wu and Wang (2006) settling velocity equations that indicate suspended particle movement, to flume and settling velocity observations to confirm the utility of the equations for subaqueous hydrochory analyses, and...

  6. A Classification of Clay-Rich Subaqueous Density Flow Structures

    NARCIS (Netherlands)

    Hermidas, N.; Eggenhuisen, Joris T.; Jacinto, Ricardo Silva; Luthi, S.M.; Toth, Ferenc; Pohl, Florian

    2018-01-01

    This study presents a classification for subaqueous clay-laden sediment gravity flows. A series of laboratory flume experiments were performed using 9%, 15%, and 21% sediment mixture concentrations composed of sand, silt, clay, and tap water, on varying bed slopes of 6°, 8°, and 9.5°, and with

  7. Glasses

    DEFF Research Database (Denmark)

    Dyre, Jeppe

    2004-01-01

    The temperature dependence of the viscosity of most glassforming liquids is known to depart significantly from the classical Arrhenius behaviour of simple fluids. The discovery of an unexpected correlation between the extent of this departure and the Poisson ratio of the resulting glass could lead...... to new understanding of glass ageing and viscous liquid dynamics....

  8. Are Deltaic Subaqueous Clinothems One-Highstand Affairs?

    Science.gov (United States)

    Giosan, L.; Clift, P.; Henstock, T.; Ponton, C.; Limmer, D. R.

    2009-12-01

    Clinothems are basic building blocks of continental shelves, whether modern or ancient. In many cases large delta-building rivers directly construct subaqueous clinothems on the shelf that are offset offshore from the delta coast. Assuming that the sediment flux to the shelf and the sediment redistributing processes are suitable for subaqueous clinothem development, the evolution of any subaqueous clinothems depends primarily on the availability of accommodation space. As the eustatic sea level varies with the volume of global ice, one primary mechanism of creating accommodation space on shelves is erosion during lowstands. We discuss here possible mechanisms for clinothems to survive erosion during lowstands by examining new data from the Indus delta shelf offshore Pakistan. Theoretical considerations based on estimates of the relative importance of wave energy vs. fluvial sediment delivery suggest that the Indus delta should develop a mid-shelf subaqueous clinothem. Instead, the Indus shelf exhibits a compound clinoform morphology. A shallow delta front clinoform extends along the entire delta coast from the shoreline to the 10-25 m water depth. New seismic data confirm that a mid-shelf clinothem developed between 30 and 90 m water depth extending over 100 km offshore east of the Indus canyon but less than 30 km west of the canyon. The advanced position of the eastern mid-shelf clinothem might reflect either a prolonged sediment delivery from the Indus River in that area compared to the shelf west of the canyon or the presence of a relict pre-Holocene mid-shelf delta.

  9. Experimental research on continuous basalt fiber and basalt-fibers-reinforced polymers

    Science.gov (United States)

    Zhang, Xueyi; Zou, Guangping; Shen, Zhiqiang

    2008-11-01

    The interest for continuous basalt fibers and reinforced polymers has recently grown because of its low price and rich natural resource. Basalt fiber was one type of high performance inorganic fibers which were made from natural basalt by the method of melt extraction. This paper discusses basic mechanical properties of basalt fiber. The other work in this paper was to conduct tensile testing of continuous basalt fiber-reinforced polymer rod. Tensile strength and stress-strain curve were obtained in this testing. The strength of rod was fairly equal to rod of E-glass fibers and weaker than rod of carbon fibers. Surface of crack of rod was studied. An investigation of fracture mechanism between matrix and fiber was analyzed by SEM (Scanning electron microscopy) method. A poor adhesion between the matrix and fibers was also shown for composites analyzing SEM photos. The promising tensile properties of the presented basalt fibers composites have shown their great potential as alternative classical composites.

  10. Implications of one-year basalt weathering/reactivity study for a basalt repository environment

    International Nuclear Information System (INIS)

    Pine, G.L.; Jantzen, C.M.

    1987-03-01

    The Savannah River Laboratory is testing the performance of the Defense Waste Processing Facility glass under conditions representing potential repository environments. For a basalt repository, one of the important issues is how rapidly reducing conditions are re-established after placement of the waste. The objective of this study was to examine the factors affecting the reactivity of the basalt. Construction of a nuclear waste repository in basalt will temporarily perturb the groundwater conditions, creating more oxidizing (air-saturated) conditions than an undisturbed repository system. Reducing conditions can be beneficial to the performance of waste glass and canisters, and may limit the transport of certain radionuclides. The Basalt Waste Isolation Project intends to use a backfill containing crushed basalt to re-establish the reducing conditions of the groundwater. The reactivity of the basalt has been found to be minimal once the fresh crushed surfaces have been weathered and the reactive intergranular glass component has been leached, e.g., by long-term surface storage. Crushing of the basalt for pneumatic emplacement of the backfill should, therefore, occur shortly before placement in the repository. This backfill must contain a minimum of 5 percent reactive fines (<100 mesh), to rapidly achieve reducing conditions. 23 refs., 21 figs., 18 tabs

  11. Hydrothermal evolution of repository groundwaters in basalt

    International Nuclear Information System (INIS)

    Apps, J.A.

    1984-01-01

    Groundwaters in the near field of a radioactive waste repository in basalt will change their chemical composition in response to reactions with the basalt. These reactions will be promoted by the heat generated by the decaying waste. It is important to predict both the rate and the extent of these reactions, and the secondary minerals produced, because the alteration process controls the chemical environment affecting the corrosion of the canister, the solubility and complexation of migrating radionuclides, the reactivity of the alteration products to radionuclides sorption, and the porosity and permeability of the host rock. A comprehensive review of the literature leads to the preliminary finding that hydrothermally altering basalts in geothermal regions such as Iceland lead to a secondary mineralogy and groundwater composition similar to that expected to surround a repository. Furthermore, laboratory experiments replicating the alteration conditions approximate those observed in the field and expected in a repository. Preliminary estimates were made of the rate of hydration and devitrification of basaltic glass and the zero-order dissolution rate of basaltic materials. The rates were compared with those for rhyolitic glasses and silicate minerals. Preliminary calculations made of mixed process alteration kinetics, involving pore diffusion and surface reaction suggest that at temperatures greater than 150 0 C, alteration proceeds so rapidly as to become pervasive in normally fractured basalt exposed to higher temperatures in the field. 70 references

  12. Density of basalt core from Hilo drill hole, Hawaii

    Science.gov (United States)

    Moore, J.G.

    2001-01-01

    Density measurements of 1600 samples of core from 889 to 3097 m depth below sea level in the Hawaii Scientific Drilling Program hole near Hilo, Hawaii show marked differences between the basaltic rock types and help define stratigraphy in the hole. Water-saturated densities of subaerial lava flows (occurring above 1079 m depth) have the broadest range because of the large density variation within a single lava flow. Water-saturated densities commonly range from 2.0 to 3.0 with an average of 2.55 ?? 0.24 g/cc. Dikes and sills range from 2.8 to 3.1 g/cc). Densities of hyaloclastite commonly range from 2.3 to 2.7, with an overall average of about 2.5 g/cc. The low-density of most hyaloclastite is due primarily to palagonitization of abundant glass and presence of secondary minerals in the interstices between fragments. Four principal zones of pillow lava, separated by hyaloclastite, occur in the drill core. The shallowest (1983-2136 m) is paradoxically the densest, averaging 3.01 ?? 0.10 g/cc. The second (2234-2470 m) is decidedly the lightest, averaging 2.67 ?? 0.13 g/cc. The third (2640-2790 m) and fourth (2918-bottom at 3097 m) are high, averaging 2.89 ?? 0.17 and 2.97 ?? 0.08 g/cc, respectively. The first pillow zone includes degassed pillows i.e. lava erupted on land that flowed into the sea. These pillows are poor in vesicles, because the subaerial, one-atmosphere vesicles were compressed when the flow descended to deeper water and higher pressure. The second (low-density, non-degassed) pillow zone is the most vesicle-rich, apparently because it was erupted subaqueously at a shallow depth. The higher densities of the third and fourth zones result from a low vesicularity of only a few percent and an olivine content averaging more than 5% for the third zone and about 10% for the fourth zone. The uppermost hyaloclastite extending about 400 m below the bottom of the subaerial basalt is poorly cemented and absorbs up to 6 wt% of water when immersed. Progressing

  13. Study on basalt fiber parameters affecting fiber-reinforced mortar

    Science.gov (United States)

    Orlov, A. A.; Chernykh, T. N.; Sashina, A. V.; Bogusevich, D. V.

    2015-01-01

    This article considers the effect of different dosages and diameters of basalt fibers on tensile strength increase during bending of fiberboard-reinforced mortar samples. The optimal dosages of fiber, providing maximum strength in bending are revealed. The durability of basalt fiber in an environment of cement, by means of microscopic analysis of samples of fibers and fiberboard-reinforced mortar long-term tests is examined. The article also compares the behavior of basalt fiber in the cement stone environment to a glass one and reveals that the basalt fiber is not subject to destruction.

  14. Asymmetric Effects of Subaerial and Subaqueous Basement Slopes on Self-Similar Morphology of Prograding Deltas

    Science.gov (United States)

    Lai, Steven Yueh Jen; Hsiao, Yung-Tai; Wu, Fu-Chun

    2017-12-01

    Deltas form over basements of various slope configurations. While the morphodynamics of prograding deltas over single-slope basements have been studied previously, our understanding of delta progradation over segmented basements is still limited. Here we use experimental and analytical approaches to investigate the deltaic morphologies developing over two-slope basements with unequal subaerial and subaqueous slopes. For each case considered, the scaled profiles of the evolving delta collapse to a single profile for constant water and sediment influxes, allowing us to use the analytical self-similar profiles to investigate the individual effects of subaerial/subaqueous slopes. Individually varying the subaerial/subaqueous slopes exerts asymmetric effects on the morphologies. Increasing the subaerial slope advances the entire delta; increasing the subaqueous slope advances the upstream boundary of the topset yet causes the downstream boundary to retreat. The delta front exhibits a first-retreat-then-advance migrating trend with increasing subaqueous slope. A decrease in subaerial topset length is always accompanied by an increase in subaqueous volume fraction, no matter which segment is steepened. Applications are presented for estimating shoreline retreat caused by steepening of basement slopes, and estimating subaqueous volume and delta front using the observed topset length. The results may have implications for real-world delta systems subjected to upstream tectonic uplift and/or downstream subsidence. Both scenarios would exhibit reduced topset lengths, which are indicative of the accompanied increases in subaqueous volume and signal tectonic uplift and/or subsidence that are at play. We highlight herein the importance of geometric controls on partitioning of sediment between subaerial and subaqueous delta components.

  15. Aqueous corrosion of silicate glasses. Analogy between volcanic glasses and the French nuclear waste glass R7T7

    International Nuclear Information System (INIS)

    Goldschmidt, F.

    1991-01-01

    The behaviour of borosilicate glasses upon aqueous corrosion is controlled for long periods of time (>10,000 years) by processes which are not directly accessible by means of laboratory experiments. The analogical approach consists here to compare leaching performances between the french nuclear waste glass R7T7 and natural volcanic glasses, basaltic and rhyolitic ones. The three glasses were leached in the same conditions; open system, 90 deg C, initial pH of 9.7. Basaltic and R7T7 glasses having the same kinetic of dissolution, the basaltic glass was chosen as the best analogue. (author). refs., figs., tabs

  16. Particle transport in subaqueous eruptions: An experimental investigation

    Science.gov (United States)

    Verolino, A.; White, J. D. L.; Zimanowski, B.

    2018-01-01

    Subaqueous volcanic eruptions are natural events common under the world's oceans. Here we report results from bench-scale underwater explosions that entrain and eject particles into a water tank. Our aim was to examine how particles are transferred to the water column and begin to sediment from it, and to visualize and interpret evolution of the 'eruption' cloud. Understanding particle transfer to water is a key requirement for using deposit characteristics to infer behaviour and evolution of an underwater eruption. For the experiments here, we used compressed argon to force different types of particles, under known driving pressures, into water within a container, and recorded the results at 1 MPx/frame and 1000 fps. Three types of runs were completed: (1) particles within water were driven into a water-filled container; (2) dry particles were driven into water; (3) dry particles were driven into air at atmospheric pressure. Across the range of particles used for all subaqueous runs, we observed: a) initial doming, b) a main expansion of decompressing gas, and c) a phase of necking, when a forced plume separated from the driving jet. Phase c did not take place for the subaerial runs. A key observation is that none of the subaqueous explosions produced a single, simple, open cavity; in all cases, multiphase mixtures of gas bubbles, particles and water were formed. Explosions in which the expanding argon ejects particles in air, analogous to delivery of particles created in an explosion, produce jets and forced plumes that release particles into the tank more readily than do those in which particles in water are driven into the tank. The latter runs mimic propulsion of an existing vent slurry by an explosion. Explosions with different particle types also yielded differences in behaviour controlled primarily by particle mass, particle density, and particle-population homogeneity. Particles were quickly delivered into the water column during plume rise following

  17. Feldspar basalts in lunar soil and the nature of the lunar continents

    Science.gov (United States)

    Reid, A. M.; Ridley, W. I.; Harmon, R. S.; Warner, J.; Brett, R.; Jakes, P.; Brown, R. W.

    1974-01-01

    It is found that 25% on the Apollo-14 glasses have the same composition as the glasses in two samples taken from the Luna-16 column. The compositions are equivalent to feldspar basalt and anorthosite gabbro, and are similar to the feldspar basalts identified from Surveyor-7 analysis for lunar continents.

  18. Evidence for Microbial Activity in ~3.5 Ga Pillow Basalts From the Barberton Greenstone Belt, South Africa

    Science.gov (United States)

    Muehlenbachs, K.; Banerjee, N. R.; Furnes, H.; Staudigel, H.; de Wit, M.

    2004-05-01

    We have discovered biosignatures in the formerly glassy rims of pillow lavas from the Mesoarchean Barberton Greenstone Belt (BGB) in South Africa. Over the last decade, bioalteration of basaltic glass in pillow lavas and volcaniclastic rocks has been well documented from in-situ oceanic crust and well-preserved Phanerozoic ophiolites. Much of the debate regarding the biogenicity of purported microfossils of early life centers on the interpretation of the host rocks' protoliths. To date, most protoliths have been interpreted to be of sedimentary origin. Some workers have proposed alternate origins for these substrates, including hydrothermal and even volcanic derivation, to cast doubt on their putative biogenicity. Hence studies documenting evidence for early life have proven to be controversial. Here we document evidence for microbial activity in ~3.5 Ga subaqueous volcanic rocks that represent a new, unambiguous geological setting in the search for early life on Earth. The BGB magmatic sequence is dominated by mafic to ultramafic pillow lavas, sheet flows, and intrusions interpreted to represent 3480- to 3220-million-year-old oceanic crust and island arc assemblages. The BGB pillow lavas are exceptionally well-preserved and represent unequivocal evidence that these rocks were erupted in a subaqueous environment. The formerly glassy rims of the BGB pillow lavas contain micron-sized, microbially generated, tubular structures consisting of titanite. These structures are interpreted to have formed during microbial etching of the originally glassy pillow rims and were subsequently mineralized by titanite during greenschist facies seafloor hydrothermal alteration. Overlapping metamorphic and magmatic dates from the pillow lavas suggest this process occurred soon after eruption of the pillow lavas on the seafloor. X-ray mapping has revealed the presence of carbon along the margins of the tubular structures. Disseminated carbonates within the microbially altered BGB

  19. Vapor deposition in basaltic stalactites, Kilauea, Hawaii

    Science.gov (United States)

    Baird, A. K.; Mohrig, D. C.; Welday, E. E.

    Basaltic stalacties suspended from the ceiling of a large lava tube at Kilauea, Hawaii, have totally enclosed vesicles whose walls are covered with euhedral FeTi oxide and silicate crystals. The walls of the vesicles and the exterior surfaces of stalactites are Fe and Ti enriched and Si depleted compared to common basalt. Minerals in vesicles have surface ornamentations on crystal faces which include alkali-enriched, aluminosilicate glass(?) hemispheres. No sulfide-, chloride-, fluoride-, phosphate- or carbonate-bearing minerals are present. Minerals in the stalactites must have formed by deposition from an iron oxide-rich vapor phase produced by the partial melting and vaporization of wall rocks in the tube.

  20. Naming Lunar Mare Basalts: Quo Vadimus Redux

    Science.gov (United States)

    Ryder, G.

    1999-01-01

    Nearly a decade ago, I noted that the nomenclature of lunar mare basalts was inconsistent, complicated, and arcane. I suggested that this reflected both the limitations of our understanding of the basalts, and the piecemeal progression made in lunar science by the nature of the Apollo missions. Although the word "classification" is commonly attached to various schemes of mare basalt nomenclature, there is still no classification of mare basalts that has any fundamental grounding. We remain basically at a classification of the first kind in the terms of Shand; that is, things have names. Quoting John Stuart Mill, Shand discussed classification of the second kind: "The ends of scientific classification are best answered when the objects are formed into groups respecting which a greater number of propositions can be made, and those propositions more important than could be made respecting any other groups into which the same things could be distributed." Here I repeat some of the main contents of my discussion from a decade ago, and add a further discussion based on events of the last decade. A necessary first step of sample studies that aims to understand lunar mare basalt processes is to associate samples with one another as members of the same igneous event, such as a single eruption lava flow, or differentiation event. This has been fairly successful, and discrete suites have been identified at all mare sites, members that are eruptively related to each other but not to members of other suites. These eruptive members have been given site-specific labels, e.g., Luna24 VLT, Apollo 11 hi-K, A12 olivine basalts, and Apollo 15 Green Glass C. This is classification of the first kind, but is not a useful classification of any other kind. At a minimum, a classification is inclusive (all objects have a place) and exclusive (all objects have only one place). The answer to "How should rocks be classified?" is far from trivial, for it demands a fundamental choice about nature

  1. Sensitivity of Depth-Integrated Satellite Lidar to Subaqueous Scattering

    Directory of Open Access Journals (Sweden)

    Michael F. Jasinski

    2011-07-01

    Full Text Available A method is presented for estimating subaqueous integrated backscatter using near-nadir viewing satellite lidar. The algorithm takes into account specular reflection of laser light, laser scattering by wind-generated foam as well as sun glint and solar scattering from foam. The formulation is insensitive to the estimate of wind speed but sensitive to the estimate of transmittance used in the atmospheric correction. As a case study, CALIOP data over Tampa Bay were compared to MODIS 645 nm remote sensing reflectance, which previously has been shown to be nearly linearly related to turbidity. The results indicate good correlation on nearly all CALIOP cloud-free dates during the period 2006 through 2007, particularly those with relatively high atmospheric transmittance. The correlation decreases when data are composited over all dates but is still statistically significant, a possible indication of variability in the biogeochemical composition in the water. Overall, the favorable results show promise for the application of satellite lidar integrated backscatter in providing information about subsurface backscatter properties, which can be extracted using appropriate models.

  2. Hydraulics of subaqueous ash flows as deduced from their deposits

    Science.gov (United States)

    Doronzo, Domenico M.; Dellino, Pierfrancesco

    2012-09-01

    Subaqueous ash flows are gravity currents consisting of a mixture of sea water and ash particles. Also called volcaniclastic turbidity currents (VTCs), they can be generated because of remobilization of pyroclastic fall deposits, which are emplaced into the sea around a volcanic island, as well as far away, during an explosive eruption. The VTC upper part is the turbulent transport system for the flow, whereas the viscous basal one is the depositional system. Typical sequences of VTC deposits are characterized by cross-laminations, planar and convolute laminations, and massive beds, which reflect the stratified nature of the flow. Here, the analysis of some VTC hydraulic parameters is presented in order to depict flow behavior and sedimentation during deposition. A reverse engineering approach is proposed, which consists of calculating hydraulic parameters by starting from deposit features. The calculated values show that a VTC is homogeneously-turbulent for most of the thickness, but is viscous at its base. First, cross-laminations are directly acquired over the rough pre-existing seafloor, then planar or convolute laminations aggrade over the newly formed substrate. Finally, fine-grained suspended particles gently settle and cap the flow deposit.

  3. Additive Construction using Basalt Regolith Fines

    Science.gov (United States)

    Mueller, Robert P.; Sibille, Laurent; Hintze, Paul E.; Lippitt, Thomas C.; Mantovani, James G.; Nugent, Matthew W.; Townsend, Ivan I.

    2014-01-01

    Planetary surfaces are often covered in regolith (crushed rock), whose geologic origin is largely basalt. The lunar surface is made of small-particulate regolith and areas of boulders located in the vicinity of craters. Regolith composition also varies with location, reflecting the local bedrock geology and the nature and efficiency of the micrometeorite-impact processes. In the lowland mare areas (suitable for habitation), the regolith is composed of small granules (20 - 100 microns average size) of mare basalt and volcanic glass. Impacting micrometeorites may cause local melting, and the formation of larger glassy particles, and this regolith may contain 10-80% glass. Studies of lunar regolith are traditionally conducted with lunar regolith simulant (reconstructed soil with compositions patterned after the lunar samples returned by Apollo). The NASA Kennedy Space Center (KSC) Granular Mechanics & Regolith Operations (GMRO) lab has identified a low fidelity but economical geo-technical simulant designated as Black Point-1 (BP-1). It was found at the site of the Arizona Desert Research and Technology Studies (RATS) analog field test site at the Black Point lava flow in adjacent basalt quarry spoil mounds. This paper summarizes activities at KSC regarding the utilization of BP-1 basalt regolith and comparative work with lunar basalt simulant JSC-1A as a building material for robotic additive construction of large structures. In an effort to reduce the import or in-situ fabrication of binder additives, we focused this work on in-situ processing of regolith for construction in a single-step process after its excavation. High-temperature melting of regolith involves techniques used in glassmaking and casting (with melts of lower density and higher viscosity than those of metals), producing basaltic glass with high durability and low abrasive wear. Most Lunar simulants melt at temperatures above 1100 C, although melt processing of terrestrial regolith at 1500 C is not

  4. Subaqueous geology and a filling model for Crater Lake, Oregon

    Science.gov (United States)

    Nathenson, M.; Bacon, C.R.; Ramsey, D.W.

    2007-01-01

    Results of a detailed bathymetric survey of Crater Lake conducted in 2000, combined with previous results of submersible and dredge sampling, form the basis for a geologic map of the lake floor and a model for the filling of Crater Lake with water. The most prominent landforms beneath the surface of Crater Lake are andesite volcanoes that were active as the lake was filling with water, following caldera collapse during the climactic eruption of Mount Mazama 7700 cal. yr B.P. The Wizard Island volcano is the largest and probably was active longest, ceasing eruptions when the lake was 80 m lower than present. East of Wizard Island is the central platform volcano and related lava flow fields on the caldera floor. Merriam Cone is a symmetrical andesitic volcano that apparently was constructed subaqueously during the same period as the Wizard Island and central platform volcanoes. The youngest postcaldera volcanic feature is a small rhyodacite dome on the east flank of the Wizard Island edifice that dates from 4800 cal. yr B.P. The bathymetry also yields information on bedrock outcrops and talus/debris slopes of the caldera walls. Gravity flows transport sediment from wall sources to the deep basins of the lake. Several debris-avalanche deposits, containing blocks up to 280 m long, are present on the caldera floor and occur below major embayments in the caldera walls. Geothermal phenomena on the lake floor are bacterial mats, pools of solute-rich warm water, and fossil subaqueous hot spring deposits. Lake level is maintained by a balance between precipitation and inflow versus evaporation and leakage. High-resolution bathymetry reveals a series of up to nine drowned beaches in the upper 30 m of the lake that we propose reflect stillstands subsequent to filling of Crater Lake. A prominent wave-cut platform between 4 m depth and present lake level that commonly is up to 40 m wide suggests that the surface of Crater Lake has been at this elevation for a very long time

  5. Crystal Stratigraphy of Two Basalts from Apollo 16: Unique Crystallization of Picritic Basalt 606063,10-16 and Very-Low-Titanium Basalt 65703,9-13

    Science.gov (United States)

    Donohue, P. H.; Neal, C. R.; Stevens, R. E.; Zeigler, R. A.

    2014-01-01

    A geochemical survey of Apollo 16 regolith fragments found five basaltic samples from among hundreds of 2-4 mm regolith fragments of the Apollo 16 site. These included a high-Ti vitrophyric basalt (60603,10-16) and one very-low-titanium (VLT) crystalline basalt (65703,9-13). Apollo 16 was the only highlands sample return mission distant from the maria (approx. 200 km). Identification of basaltic samples at the site not from the ancient regolith breccia indicates input of material via lateral transport by post-basin impacts. The presence of basaltic rocklets and glass at the site is not unprecedented and is required to satisfy mass-balance constraints of regolith compositions. However, preliminary characterization of olivine and plagioclase crystal size distributions indicated the sample textures were distinct from other known mare basalts, and instead had affinities to impact melt textures. Impact melt textures can appear qualitatively similar to pristine basalts, and quantitative analysis is required to distinguish between the two in thin section. The crystal stratigraphy method is a powerful tool in studying of igneous systems, utilizing geochemical analyses across minerals and textural analyses of phases. In particular, trace element signatures can aid in determining the ultimate origin of these samples and variations document subtle changes occurring during their petrogenesis.

  6. High alkali-resistant basalt fiber for reinforcing concrete

    International Nuclear Information System (INIS)

    Lipatov, Ya.V.; Gutnikov, S.I.; Manylov, M.S.; Zhukovskaya, E.S.; Lazoryak, B.I.

    2015-01-01

    Highlights: • Doping of basalt fiber with ZrSiO 4 increased its alkali resistance. • Alkali treatment results in formation of protective surface layer on fibers. • Morphology and chemical composition of surface layer were investigated. • Mechanical properties of fibers were analyzed by a Weibull distribution. • Zirconia doped basalt fibers demonstrate high performance in concrete. - Abstract: Basalt glasses and fibers with zirconia content in the range from 0 to 7 wt% were obtained using ZrSiO 4 as a zirconium source. Weight loss and tensile strength loss of fibers after refluxing in alkali solution were determined. Basalt fiber with 5.7 wt% ZrO 2 had the best alkali resistance properties. Alkali treatment results in formation of protective surface layer on fibers. Morphology and chemical composition of surface layer were investigated. It was shown that alkali resistance of zirconia doped basalt fibers is caused by insoluble compounds of Zr 4+ , Fe 3+ and Mg 2+ in corrosion layer. Mechanical properties of initial and leached fibers were evaluated by a Weibull distribution. The properties of basalt fibers with ZrSiO 4 were compared with AR-glass fibers. The performance of concrete with obtained fibers was investigated

  7. Grain-size sorting and slope failure in experimental subaqueous grain flows

    NARCIS (Netherlands)

    Kleinhans, M.G.; Asch, Th.W.J. van

    2005-01-01

    Grain-size sorting in subaqueous grain flows of a continuous range of grain sizes is studied experimentally with three mixtures. The observed pattern is a combination of stratification and gradual segregation. The stratification is caused by kinematic sieving in the grain flow. The segregation is

  8. Basalt woven fiber reinforced vinylester composites: Flexural and electrical properties

    International Nuclear Information System (INIS)

    Carmisciano, Salvatore; Rosa, Igor Maria De; Sarasini, Fabrizio; Tamburrano, Alessio; Valente, Marco

    2011-01-01

    A preliminary comparative study of basalt and E-glass woven fabric reinforced composites was performed. The fabrics were characterized by the same weave pattern and the laminates tested by the same fiber volume fraction. Results of the flexural and interlaminar characterization are reported. Basalt fiber composites showed higher flexural modulus and apparent interlaminar shear strength (ILSS) in comparison with E-glass ones but also a lower flexural strength and similar electrical properties. With this fiber volume fraction, scanning electron microscopy (SEM) analysis of the fractured surfaces enabled a better understanding both of the failure modes involved and of points of concern. Nevertheless, the results of this study seem promising in view of a full exploitation of basalt fibers as reinforcement in polymer matrix composites (PMCs).

  9. Petrology of basalts from Loihi Seamount, Hawaii

    Science.gov (United States)

    Hawkins, James; Melchior, John

    1983-12-01

    Loihi Seamount is the southeasternmost active volcano of the Emperor-Hawaii linear volcanic chain. It comprises a spectrum of basalt compositional varieties including basanite, alkali basalt, transitional basalt and tholeiite. Samples from four dredge collections made on Scripps Institution of Oceanography Benthic Expedition in October 1982 are tholeiite. The samples include highly vesicular, olivine-rich basalt and dense glass-rich pillow fragments containing olivine and augite phenocrysts. Both quartz-normative and olivine-normative tholeiites are present. Minor and trace element data indicate relatively high abundances of low partition coefficient elements (e.g., Ti, K, P. Rb, Ba, Zr) and suggest that the samples were derived by relatively small to moderate extent of partial melting, of an undepleted mantle source. Olivine composition, MgO, Cr and Ni abundances, and Mg/(Mg+Fe), are typical of moderately fractionated to relatively unfractionated "primary" magmas. The variations in chemistry between samples cannot be adequately explained by low-pressure fractional crystallization but can be satisfied by minor variations in extent of melting if a homogeneous source is postulated. Alternatively, a heterogeneous source with variable abundances of certain trace elements, or mixing of liquids, may have been involved. Data for 3He/ 4He, presented in a separate paper, implies a mantle plume origin for the helium composition of the Loihi samples. There is little variation in the helium isotope ratio for samples having different compositions and textures. The helium data are not distinctive enough to unequivocally separate the magma sources for the tholeiitic rocks from the other rock types such as Loihi alkalic basalts and the whole source region for Loihi may have a nearly uniform helium compositions even though other element abundances may be variable. Complex petrologic processes including variable melting, fractional crystallization and magma mixing may have blurred

  10. Nuclear waste package materials testing report: basaltic and tuffaceous environments

    International Nuclear Information System (INIS)

    Bradley, D.J.; Coles, D.G.; Hodges, F.N.; McVay, G.L.; Westerman, R.E.

    1983-03-01

    The disposal of high-level nuclear wastes in underground repositories in the continental United States requires the development of a waste package that will contain radionuclides for a time period commensurate with performance criteria, which may be up to 1000 years. This report addresses materials testing in support of a waste package for a basalt (Hanford, Washington) or a tuff (Nevada Test Site) repository. The materials investigated in this testing effort were: sodium and calcium bentonites and mixtures with sand or basalt as a backfill; iron and titanium-based alloys as structural barriers; and borosilicate waste glass PNL 76-68 as a waste form. The testing also incorporated site-specific rock media and ground waters: Reference Umtanum Entablature-1 basalt and reference basalt ground water, Bullfrog tuff and NTS J-13 well water. The results of the testing are discussed in four major categories: Backfill Materials: emphasizing water migration, radionuclide migration, physical property and long-term stability studies. Structural Barriers: emphasizing uniform corrosion, irradiation-corrosion, and environmental-mechanical testing. Waste Form Release Characteristics: emphasizing ground water, sample surface area/solution volume ratio, and gamma radiolysis effects. Component Compatibility: emphasizing solution/rock, glass/rock, glass/structural barrier, and glass/backfill interaction tests. This area also includes sensitivity testing to determine primary parameters to be studied, and the results of systems tests where more than two waste package components were combined during a single test

  11. Basalt stratigraphy - Pasco Basin

    International Nuclear Information System (INIS)

    Waters, A.C.; Myers, C.W.; Brown, D.J.; Ledgerwood, R.K.

    1979-10-01

    The geologic history of the Pasco Basin is sketched. Study of the stratigraphy of the area involved a number of techniques including major-element chemistry, paleomagnetic investigations, borehole logging, and other geophysical survey methods. Grande Ronde basalt accumulation in the Pasco Basin is described. An illustrative log response is shown. 1 figure

  12. Basalt fiber reinforced polymer composites: Processing and properties

    Science.gov (United States)

    Liu, Qiang

    A high efficiency rig was designed and built for in-plane permeability measurement of fabric materials. A new data derivation procedure to acquire the flow fluid pattern in the experiment was developed. The measurement results of the in-plane permeability for basalt twill 31 fabric material showed that a high correlation exists between the two principal permeability values for this fabric at 35% fiber volume fraction. This may be the most important scientific contribution made in this thesis. The results from radial measurements corresponded quite well with those from Unidirectional (UD) measurements, which is a well-established technique. No significant differences in mechanical properties were found between basalt fabric reinforced polymer composites and glass composites reinforced by a fabric of similar weave pattern. Aging results indicate that the interfacial region in basalt composites may be more vulnerable to environmental damage than that in glass composites. However, the basalt/epoxy interface may have been more durable than the glass/epoxy interface in tension-tension fatigue because the basalt composites have significantly longer fatigue life. In this thesis, chapter I reviews the literature on fiber reinforced polymer composites, with concentration on permeability measurement, mechanical properties and durability. Chapter II discusses the design of the new rig for in-plane permeability measurement, the new derivation procedure for monitoring of the fluid flow pattern, and the permeability measurement results. Chapter III compares the mechanical properties and durability between basalt fiber and glass fiber reinforced polymer composites. Lastly, chapter IV gives some suggestions and recommendations for future work.

  13. Ultra-high chlorine in submarine Kı̄lauea glasses: Evidence for direct assimilation of brine by magma

    Science.gov (United States)

    Coombs, Michelle L.; Sisson, Thomas W.; Kimura, Jun-Ichi

    2004-01-01

    Basaltic glass grains from the submarine south flank of Kı̄lauea, Hawai′i, have Cl concentrations of 0.01–1.68 wt%, the latter being the highest Cl content yet recorded for a Hawaiian glass. The high-Cl glass grains are products of brine assimilation by tholeiite magma. The glasses are grains in a sandstone clast from bedded breccias draping the southwestern margin of Kı̄lauea’s submarine midslope bench. The clast contains two distinct suites of glass grains: abundant degassed tholeiites, perhaps derived from subaerial lavas of Mauna Loa that shattered upon ocean entry, and a smaller population of Kea-type tholeiite (n=17 analyzed) that erupted subaqueously, based on elevated S (780–1050 ppm), H2O (0.42–1.27 wt%), and CO2 (1000 ppm, six >5000 ppm, and two grains have >10 000 ppm dissolved Cl. Abundances of H2O, Na2O, K2O, and several trace elements increase regularly with Cl concentration, and we estimate that Cl enrichment was due to up to 13 wt% addition of a brine consisting of 78% H2O (wt), 13% Cl, 4.4% Na, 2.6% K, 2.6% Ca, 620 ppm Ba, 360 ppm Sr, 65 ppm Rb, and 7 ppm Pb. The large amounts of brine addition argue against bulk assimilation of low-porosity brine-bearing rock. The brine’s composition is appropriate for a seawater-derived hydrothermal fluid that reacted with basaltic wall rocks at T>100°C, losing Mg and S and gaining K, Ca, Rb, Ba, Sr, and Pb, followed by phase separation near 500°C and ∼50 MPa (5 km below sea level at hydrostatic pressure). Brine was assimilated at or near the depth it formed, as estimated on petrologic grounds, but under lithostatic conditions. The highest extents of assimilation either forced volatile saturation of the magma or enriched already coexisting magmatic vapor in H2O. Possible mechanisms for assimilation are: (1) forcible injection of brine into magma during bursting of overpressured pockets heated by new dikes, or (2) intrusion of magma into lenses or sills occupied by trapped brine.

  14. Basalt Fiber for Volcanic Slag Lightweight Aggregate Concrete Research on the Impact of Performance

    Science.gov (United States)

    Xiao, Li-guang; Li, Gen-zhuang

    2018-03-01

    In order to study the effect of basalt fiber on the mechanical properties and durability of volcanic slag lightweight aggregate concrete, the experimental study on the flexural strength, compressive strength and freeze-thaw resistance of volcanic slag concrete with different basalt fiber content were carried out, the basalt fiber was surface treated with NaOH and water glass, the results show that the surface treatment of basalt fiber can significantly improve the mechanical properties, durability and other properties of volcanic slag lightweight aggregate concrete.

  15. Natural analogues of nuclear waste glass corrosion

    International Nuclear Information System (INIS)

    Abrajano, T.A. Jr.; Ebert, W.L.; Luo, J.S.

    1999-01-01

    This report reviews and summarizes studies performed to characterize the products and processes involved in the corrosion of natural glasses. Studies are also reviewed and evaluated on how well the corrosion of natural glasses in natural environments serves as an analogue for the corrosion of high-level radioactive waste glasses in an engineered geologic disposal system. A wide range of natural and experimental corrosion studies has been performed on three major groups of natural glasses: tektite, obsidian, and basalt. Studies of the corrosion of natural glass attempt to characterize both the nature of alteration products and the reaction kinetics. Information available on natural glass was then compared to corresponding information on the corrosion of nuclear waste glasses, specifically to resolve two key questions: (1) whether one or more natural glasses behave similarly to nuclear waste glasses in laboratory tests, and (2) how these similarities can be used to support projections of the long-term corrosion of nuclear waste glasses. The corrosion behavior of basaltic glasses was most similar to that of nuclear waste glasses, but the corrosion of tektite and obsidian glasses involves certain processes that also occur during the corrosion of nuclear waste glasses. The reactions and processes that control basalt glass dissolution are similar to those that are important in nuclear waste glass dissolution. The key reaction of the overall corrosion mechanism is network hydrolysis, which eventually breaks down the glass network structure that remains after the initial ion-exchange and diffusion processes. This review also highlights some unresolved issues related to the application of an analogue approach to predicting long-term behavior of nuclear waste glass corrosion, such as discrepancies between experimental and field-based estimates of kinetic parameters for basaltic glasses

  16. Natural analogues of nuclear waste glass corrosion.

    Energy Technology Data Exchange (ETDEWEB)

    Abrajano, T.A. Jr.; Ebert, W.L.; Luo, J.S.

    1999-01-06

    This report reviews and summarizes studies performed to characterize the products and processes involved in the corrosion of natural glasses. Studies are also reviewed and evaluated on how well the corrosion of natural glasses in natural environments serves as an analogue for the corrosion of high-level radioactive waste glasses in an engineered geologic disposal system. A wide range of natural and experimental corrosion studies has been performed on three major groups of natural glasses: tektite, obsidian, and basalt. Studies of the corrosion of natural glass attempt to characterize both the nature of alteration products and the reaction kinetics. Information available on natural glass was then compared to corresponding information on the corrosion of nuclear waste glasses, specifically to resolve two key questions: (1) whether one or more natural glasses behave similarly to nuclear waste glasses in laboratory tests, and (2) how these similarities can be used to support projections of the long-term corrosion of nuclear waste glasses. The corrosion behavior of basaltic glasses was most similar to that of nuclear waste glasses, but the corrosion of tektite and obsidian glasses involves certain processes that also occur during the corrosion of nuclear waste glasses. The reactions and processes that control basalt glass dissolution are similar to those that are important in nuclear waste glass dissolution. The key reaction of the overall corrosion mechanism is network hydrolysis, which eventually breaks down the glass network structure that remains after the initial ion-exchange and diffusion processes. This review also highlights some unresolved issues related to the application of an analogue approach to predicting long-term behavior of nuclear waste glass corrosion, such as discrepancies between experimental and field-based estimates of kinetic parameters for basaltic glasses.

  17. Pedological Studies of Subaqueous Soils as a Contribution to the Protection of Seagrass Meadows in Brazil

    Directory of Open Access Journals (Sweden)

    Gabriel Nuto Nóbrega

    2018-02-01

    Full Text Available ABSTRACT: Seagrass meadows are considered one of the most important and valuable ecosystems on the planet, but also one of the most threatened. Missing knowledge about their existence and their subtidal nature are the main reasons for the lack of information about seagrass soils, especially in Brazil and other tropical areas. This study discussed the paradoxical lack of information about subaqueous soils, with a view to stimulate research on soil properties of seagrass meadows. This short communication provides information about the ecosystem and first descriptions of seagrass soils along the Brazilian Coast, marked by gleyzation, sulfidization, salinization, paludization, solonization, and classified as Gleissolos tiomórficos. Pedological studies on these ecosystems provide useful tools for their management, protection, and restoration. Thus, it is fundamental that soil scientists increase their knowledge about subaqueous soils, not only as a contribution to the Brazilian Soil Classification System, but for the conservation of these ecosystems.

  18. Carbon Sequestration in Olivine and Basalt Powder Packed Beds.

    Science.gov (United States)

    Xiong, Wei; Wells, Rachel K; Giammar, Daniel E

    2017-02-21

    Fractures and pores in basalt could provide substantial pore volume and surface area of reactive minerals for carbonate mineral formation in geologic carbon sequestration. In many fractures solute transport will be limited to diffusion, and opposing chemical gradients that form as a result of concentration differences can lead to spatial distribution of silicate mineral dissolution and carbonate mineral precipitation. Glass tubes packed with grains of olivine or basalt with different grain sizes and compositions were used to explore the identity and spatial distribution of carbonate minerals that form in dead-end one-dimensional diffusion-limited zones that are connected to a larger reservoir of water in equilibrium with 100 bar CO 2 at 100 °C. Magnesite formed in experiments with olivine, and Mg- and Ca-bearing siderite formed in experiments with flood basalt. The spatial distribution of carbonates varied between powder packed beds with different powder sizes. Packed beds of basalt powder with large specific surface areas sequestered more carbon per unit basalt mass than powder with low surface area. The spatial location and extent of carbonate mineral formation can influence the overall ability of fractured basalt to sequester carbon.

  19. Hydrothermal waste package interactions with methane-containing basalt groundwater

    International Nuclear Information System (INIS)

    McGrail, B.P.

    1984-01-01

    Hydrothermal waste package interaction tests were conducted with a mixture of crushed glass, basalt, and steel in methane-containing synthetic basalt groundwater. In the absence of gamma radiolysis, methane was found to have little influence on the corrosion behavior of the waste package constituents. Under gamma radiolysis, methane was found to significantly lower the solution oxidation potential when compared to identical tests without methane. In addition, colloidal hydrocarbon polymers that have been produced under the irradiation conditions of these experiments were not formed. The presence of the waste package constituents apparently inhibited the formation of the polymers. However, the mechanism which prevented their formation was not determined

  20. Natural analogue study of volcanic glass

    International Nuclear Information System (INIS)

    Arai, T.; Yusa, Y.; Sasaki, N.; Tsunoda, N.; Takano, H.

    1989-02-01

    A considerable range in alteration rates of basaltic glasses in various environments has been reported in previous studies. However, these studies paid only cursory attention to the environmental conditions under which the glass had been altered. In this study, the alteration of basaltic glasses was investigated and the environmental conditions and the alteration rate were discussed. Two sample ages were represented: 280 years and 2800 years. Basaltic glasses and their alteration layers were analyzed by electron probe microanalyzer (EMPA) and the thickness of the alteration layers were measured by scanning electron microscope (SEM). The ground water collected near the sampling point of Zunazawa Scoria (2800 years) and the pore water of both samples were analyzed. The alteration temperature and flow rate of water are estimated to be about 13degC and 0.2 l/cm 2 /y respectively on the basis of meteorological data. The alteration layers of young aged basaltic glasses in freshwater conditions are similar to those of leached borosilicate glasses. The alteration rates of these basaltic glasses are estimated to be several μm/1000y. The elemental concentrations in the ground water can be roughly explained as the result of leaching of the glasses. (author)

  1. The role of residual (undegassed) and environmental waters in pyroclastic volcanic glass in nature and experiments (Invited)

    Science.gov (United States)

    Bindeman, I. N.; Seligman, A. N.; Nolan, G. S.; Lundstrom, C.; Martin, E.; Lowenstern, J. B.; Palandri, J. L.

    2013-12-01

    The advent and calibration of the Thermal Combustion Element Analyzer (TCEA) continuous flow system coupled with the large-radius mass spectrometer, at the University of Oregon, permits precise (×0.02 wt.% H2O, ×1-3‰ D/H) measurements in 1-10 mg of volcanic glass (0.1 wt.% H2O requires ~10 mg glass). This is a 10-100 time reduction in sample size over previous methods, which permits the targeting of small amounts of the freshest concentrate. In combination with the FTIR, we use the TCEA to research problems involving the mechanisms and timescales of volcanic ash hydration on both natural and laboratory timescales using isotopically-labeled water, D/H-H2O pathways of volcanic degassing, water content and D/H in recently erupted volcanic ash, and the mechanisms of tephra-hydration by isotopically-distinct rain and glacial meltwaters. The talk will review new results: 1) Water content determined by FTIR (OH and H2O) and TCEA give excellent correspondence for basaltic and rhyolitic glasses, including FTIR measurements for irregular ash particles mixed in equal proportion with KBr and molded into pellets. 2) Nominally-anhydrous (hydrated ash (4 wt.% water) leads to neglegeable δD exchange, signifying nearly zero-fractionation upon loss of predominantly H2Omol water. 5) Glacial vs. intergacial water can be recognized in hydrated glasses. 6) Subaqueous perlites from Yellowstone have an onion-skin distribution of water with water-poor cores, as determined by the scanning FTIR technique. 7) Thermal diffusion experiments achieve up to a 144‰ range in δD across a 300-600°C temperature change; this has implications for explaining natural variations in δD in high temperature environments due to high diffusivity of hydrogen. 8) We report results of δ18O in extracted water in glass and discuss isotopic offsets due to incomplete oxygen extraction from OH groups. 9) We apply these methods to submarine glasses, and degassing tephra products of the same eruption.

  2. Investigation on mechanical properties of basalt composite fabrics (experiment study)

    Science.gov (United States)

    Talebi Mazraehshahi, H.; Zamani, H.

    2010-06-01

    To fully appreciate the role and application of composite materials to structures, correct understanding of mechanical behaviors required for selection of optimum material. Fabric reinforced composites are composed of a matrix that is reinforced with pliable fabric, glass fabric is most popular reinforcement for different application specially in aircraft structure, although other fabric material are also used. At this study new fabric material called basalt with epoxy resin introduced and mechanical behaviors of this material investigated from view point of testing. For this study two type of fabric with different thickness used. Comparison between this composite reinforcement with popular reinforcement as carbon, glass, kevlar performed. To determine mechanical properties of epoxy based basalt fabric following test procedure performed : 1). Tensile testing according to ASTM D3039 in 0° and 90° direction to find ultimate strength in tension and shear, modulus of elasticity, elangation and ultimate strain. 2). Compression testing according to EN 2850 ultimate compression strength and maximum deformation under compression loading. 3). Shear testing according to ASTM D3518-94 to find in plane shear response of polymer matrix composites materials. 4). Predict flexural properties of sandwich construction which manufactured from basalt facing with PVC foam core according to ASTM C393-94. Material strength properties must be based on enough tests of material to meet the test procedure specifications [1]. For this reason six specimens were manufactured for testing and the tests were performed on them using an INSTRON machine model 5582. In the study, the effect of percent of resin in basalt reinforced composite was investigated. Also the weights of the ballast based composites with different percent of resin were measured with conventional composites. As the weight is an important parameter in aerospace industry when the designer wants to replace one material with

  3. Investigation on mechanical properties of basalt composite fabrics (experiment study

    Directory of Open Access Journals (Sweden)

    Talebi Mazraehshahi H.

    2010-06-01

    Full Text Available To fully appreciate the role and application of composite materials to structures, correct understanding of mechanical behaviors required for selection of optimum material. Fabric reinforced composites are composed of a matrix that is reinforced with pliable fabric, glass fabric is most popular reinforcement for different application specially in aircraft structure, although other fabric material are also used. At this study new fabric material called basalt with epoxy resin introduced and mechanical behaviors of this material investigated from view point of testing. For this study two type of fabric with different thickness used. Comparison between this composite reinforcement with popular reinforcement as carbon, glass, kevlar performed. To determine mechanical properties of epoxy based basalt fabric following test procedure performed : 1. Tensile testing according to ASTM D3039 in 0° and 90° direction to find ultimate strength in tension and shear, modulus of elasticity, elangation and ultimate strain. 2. Compression testing according to EN 2850 ultimate compression strength and maximum deformation under compression loading. 3. Shear testing according to ASTM D3518-94 to find in plane shear response of polymer matrix composites materials. 4. Predict flexural properties of sandwich construction which manufactured from basalt facing with PVC foam core according to ASTM C393-94. Material strength properties must be based on enough tests of material to meet the test procedure specifications [1]. For this reason six specimens were manufactured for testing and the tests were performed on them using an INSTRON machine model 5582. In the study, the effect of percent of resin in basalt reinforced composite was investigated. Also the weights of the ballast based composites with different percent of resin were measured with conventional composites. As the weight is an important parameter in aerospace industry when the designer wants to replace one

  4. Mars weathering analogs - Secondary mineralization in Antarctic basalts

    Science.gov (United States)

    Berkley, J. L.

    1982-01-01

    Alkalic basalt samples from Ross Island, Antarctica, are evaluated as terrestrial analogs to weathered surface materials on Mars. Secondary alteration in the rocks is limited to pneumatolytic oxidation of igneous minerals and glass, rare groundmass clay and zeolite mineralization, and hydrothermal minerals coating fractures and vesicle surfaces. Hydrothermal mineral assemblages consist mainly of K-feldspar, zeolites (phillipsite and chabazite), calcite, and anhydrite. Low alteration rates are attributed to cold and dry environmental factors common to both Antarctica and Mars. It is noted that mechanical weathering (aeolian abrasion) of Martian equivalents to present Antarctic basalts would yield minor hydrothermal minerals and local surface fines composed of primary igneous minerals and glass but would produce few hydrous products, such as palagonite, clay or micas. It is thought that leaching of hydrothermal vein minerals by migrating fluids and redeposition in duricrust deposits may represent an alternate process for incorporating secondary minerals of volcanic origin into Martian surface fines.

  5. Petrology of dune sand derived from basalt on the Ka'u Desert, Hawaii

    Science.gov (United States)

    Gooding, J. L.

    1982-01-01

    Dune sand from the Ka'u Desert, southwest flank of Kilauea volcano, Hawaii, is moderately well-sorted (median = 1.60 Phi, deviation = 0.60, skewness = 0.25, kurtosis = 0.68) and composed mostly of frosted subangular particles of basalt glass ('unfractionated' olivine-normative tholeitte), olivine, lithic fragments (subophitic and intersertal basalts; magnetite-ilmenite-rich basalts), reticular basalt glass, magnetite, ilmenite, and plagioclase, in approximately that order of abundance. Quantitative lithological comparison of the dune sand with sand-sized ash from the Keanakakoi Formation supports suggestions that the dune sand was derived largely from Keanakakoi ash. The dune sand is too well sorted to have been emplaced in its present form by base-surge but could have evolved by post-eruption reworking of the ash.

  6. Reference waste form, basalts, and ground water systems for waste interaction studies

    Energy Technology Data Exchange (ETDEWEB)

    Deju, R.A.; Ledgerwood, R.K.; Long, P.E.

    1978-09-01

    This report summarizes the type of waste form, basalt, and ground water compositions to be used in theoretical and experimental models of the geochemical environment to be simulated in studying a typical basalt repository. Waste forms to be used in the experiments include, and are limited to, glass, supercalcine, and spent unreprocessed fuel. Reference basalts selected for study include the Pomona member and the Umtanum Unit, Shwana Member, of the Columbia River Basalt Group. In addition, a sample of the Basalt International Geochemical Standard (BCR-1) will be used for cross-comparison purposes. The representative water to be used is of a sodium bicarbonate composition as determined from results of analyses of deep ground waters underlying the Hanford Site. 12 figures, 13 tables.

  7. Reference waste form, basalts, and ground water systems for waste interaction studies

    International Nuclear Information System (INIS)

    Deju, R.A.; Ledgerwood, R.K.; Long, P.E.

    1978-09-01

    This report summarizes the type of waste form, basalt, and ground water compositions to be used in theoretical and experimental models of the geochemical environment to be simulated in studying a typical basalt repository. Waste forms to be used in the experiments include, and are limited to, glass, supercalcine, and spent unreprocessed fuel. Reference basalts selected for study include the Pomona member and the Umtanum Unit, Shwana Member, of the Columbia River Basalt Group. In addition, a sample of the Basalt International Geochemical Standard (BCR-1) will be used for cross-comparison purposes. The representative water to be used is of a sodium bicarbonate composition as determined from results of analyses of deep ground waters underlying the Hanford Site. 12 figures, 13 tables

  8. Glasses, ceramics, and composites from lunar materials

    Science.gov (United States)

    Beall, George H.

    1992-01-01

    A variety of useful silicate materials can be synthesized from lunar rocks and soils. The simplest to manufacture are glasses and glass-ceramics. Glass fibers can be drawn from a variety of basaltic glasses. Glass articles formed from titania-rich basalts are capable of fine-grained internal crystallization, with resulting strength and abrasion resistance allowing their wide application in construction. Specialty glass-ceramics and fiber-reinforced composites would rely on chemical separation of magnesium silicates and aluminosilicates as well as oxides titania and alumina. Polycrystalline enstatite with induced lamellar twinning has high fracture toughness, while cordierite glass-ceramics combine excellent thermal shock resistance with high flexural strengths. If sapphire or rutile whiskers can be made, composites of even better mechanical properties are envisioned.

  9. Modern sedimentation and morphology of the subaqueous Mekong Delta, Southern Vietnam

    Science.gov (United States)

    Unverricht, Daniel; Szczuciński, Witold; Stattegger, Karl; Jagodziński, Robert; Le, Xuan Thuyen; Kwong, Laval Liong Wee

    2013-11-01

    The Mekong River Delta is among the Asian mega-deltas and is influenced by various factors including tides (meso-tidal system), waves, coastal currents, monsoon-driven river discharge and human impact (agriculture, fishing, sand dredging, tourism). The present study aims to document the seafloor relief, sediment distribution and sediment accumulation rates to interpret modern sediment transport directions and main sedimentation processes in the subaqueous Mekong Delta. The major results of this investigation include the detection of two delta fronts 200 km apart, one at the mouth of the Bassac River (the biggest branch of the Mekong Delta) and the other around Cape Ca Mau (most south-western end of the Mekong Delta). Additionally, a large channel system runs in the subaqueous delta platform parallel to the shore and between the two fronts. The sediment accumulation rates vary greatly according to the location in the subaqueous delta and have reached up to 10 cm/yr for the last century. A cluster analysis of surface sediment samples revealed two different sediment types within the delta including a well-sorted sandy sediment and a poorly sorted, silty sediment. In addition, a third end member with medium to coarse sand characterised the distant parts of the delta at the transition to the open shelf. The increase of organic matter and carbonate content to the bottom set area and other sedimentary features such as shell fragments, foraminiferas and concretions of palaeo-soils that do not occur in delta sediments, supported grain size-based classification. Beginning in front of the Bassac River mouth, sedimentary pattern indicates clockwise sediment transport alongshore in the western direction to a broad topset area and the delta front around Cape Ca Mau. Our results clearly show the large lateral variability of the subaqueous Mekong Delta that is further complicated by strong monsoon-driven seasonality. River, tidal and wave forcing vary at local and seasonal scales

  10. Moessbauer Studies of Volhynian Basalts

    International Nuclear Information System (INIS)

    Bakun-Czubarow, N.; Milczarski, J.; Galazka-Friedman, J.; Szlachta, K.; Forder, S.

    2011-01-01

    The Volhynian basalts studied belong to the effusive-tuffogenic Volhynian Series (Slawatycze Series in Poland), being the large Ediacaran continental igneous province, that covers an area of 200 000 km 2 in the western margin of East European Craton. The series is underlain by the Cryogenian terrigenous Polesie Series with doleritic sills and dikes. The Volhynian Series consists of the rock beds belonging to the three volcanic cycles with different ratios of flood basalts to pyroclastics. The aim of the study was recognition of primary and secondary Fe-bearing minerals, particularly Fe- and Fe-Ti oxides as well as determination of iron oxidation state, that is an important tool in the search for native copper deposits in these rocks. For Moessbauer studies the following rock samples were chosen: the Polesie Series dolerites, the Volhynian Series basalts from the Ukrainian quarries and drill-holes, e.g. from the Volodymir Volhynskaya drilling hole; the Slawatycze Series basalts from Kaplonosy drill-hole in Poland. In the Kaplonosy basalts the content of magnetite decreases with depth, which may be caused by magma differentiation due to fractional crystallization, when Mg content decreases as Ti and Fe - increases in basic magma. In the Kaplonosy basalts the Fe 2+ /Fe 3+ ratio increases with depth, which points to the increase of iron oxidation with the progress of basaltic magma differentiation. (authors)

  11. FOAM CONCRETE REINFORCEMENT BY BASALT FIBRES

    Directory of Open Access Journals (Sweden)

    Zhukov Aleksey Dmitrievich

    2012-10-01

    Full Text Available The authors demonstrate that the foam concrete performance can be improved by dispersed reinforcement, including methods that involve basalt fibres. They address the results of the foam concrete modeling technology and assess the importance of technology-related parameters. Reinforcement efficiency criteria are also provided in the article. Dispersed reinforcement improves the plasticity of the concrete mix and reduces the settlement crack formation rate. Conventional reinforcement that involves metal laths and rods demonstrates its limited application in the production of concrete used for thermal insulation and structural purposes. Dispersed reinforcement is preferable. This technology contemplates the infusion of fibres into porous mixes. Metal, polymeric, basalt and glass fibres are used as reinforcing components. It has been identified that products reinforced by polypropylene fibres demonstrate substantial abradability and deformability rates even under the influence of minor tensile stresses due to the low adhesion strength of polypropylene in the cement matrix. The objective of the research was to develop the type of polypropylene of D500 grade that would demonstrate the operating properties similar to those of Hebel and Ytong polypropylenes. Dispersed reinforcement was performed by the basalt fibre. This project contemplates an autoclave-free technology to optimize the consumption of electricity. Dispersed reinforcement is aimed at the reduction of the block settlement in the course of hardening at early stages of their operation, the improvement of their strength and other operating properties. Reduction in the humidity rate of the mix is based on the plasticizing properties of fibres, as well as the application of the dry mineralization method. Selection of optimal parameters of the process-related technology was performed with the help of G-BAT-2011 Software, developed at Moscow State University of Civil Engineering. The authors also

  12. Contributions of vitreous natural analogs to the investigation of long-term nuclear glass behavior

    International Nuclear Information System (INIS)

    Techer, I.

    1999-01-01

    This study assesses the extend of the analogy between the alteration behavior in water and in a moist clay environment of aluminosilicate volcanic glass and alumino-borosilicate nuclear containment glass. Basaltic glass alteration in water initially occurs by hydrolysis processes with an activation energy on the order of 73 kJ.mol -1 . As the reaction progresses, the alteration rate drops by over four orders of magnitude from the initial rate r 0 , The alteration kinetics are not governed by the alteration solution chemistry alone, the glass alteration film appears to have a major role as a diffusion barrier limiting the transfer of reaction species and products. All these aspects highlight the behavioral analogy between basaltic glass and nuclear borosilicate glass in aqueous media. Conversely, the alteration reaction of obsidian-type volcanic glass involves other mechanisms than those governing the dissolution of borosilicate glass. Basaltic glass alteration is also examined in the presence of a clay environmental material, in a study of the natural basaltic glass and argillaceous pelites system of the Salagou basin in southern France, in an approach combining mineralogical, chemical and isotopic data to assess the interactions between a basaltic glass and the argillaceous pelites. Laboratory leach test results with basaltic glass and measured data for the Salagou glass in its natural environment are modeled using a code implementing a kinetic law coupling diffusive transfer of dissolved silica with a reaction affinity law. (author)

  13. Nuclear microprobe analysis of carbon within glass inclusions and volcanic materials

    International Nuclear Information System (INIS)

    Metrich, N.; Mosbah, M.; Trocellier, P.; Clocchiatti, R.

    1986-01-01

    Microanalysis possibilities have been explored to determine light element concentrations within glasses (melt inclusions and basaltic glass fragments) and volcanic phenocrysts. In the first step, C was examined. The study of different spectral interferences lead to calculated detection limits of 40 μg/g for basaltic glasses and 50 μg/g for olivine crystals. The C contents of all investigated specimens range from 40 μg/g (the detection limit) to 6800 μg/g. Heterogeneities were revealed within glass inclusions. Measurements show obvious concentration profiles in basaltic glass samples. Our results agree with previous published data and are reliable. Accuracy of measurements is about 20%. 12 refs

  14. Elaboration of vitreous and vitrocrystalline basalt materials containing simulated radioactive ash wastes. Study of some physical properties and leaching behaviour

    International Nuclear Information System (INIS)

    Lebeau, M.J.

    1988-01-01

    This work is a preliminary study of a matrix for containment of incinerator ashes. Basalt presents a good capacity for ash incorporation (up to 50%), glasses obtained are homogeneous and the low viscosity at 1300 0 C allows an industrial preparation. Vitrocrystalline products have a dendritic texture which can be controlled by cooling rate and are composed of magnesioferrite, pyroxene, plagioclase and vitreous fraction depending on the filling material ratio. Uranium and thorium, for actinide simulation in ashes, are localized in the glass. Glass leaching decrease with ash content and the alteration film presents a better retention of some elements, such as uranium and thorium. Vitrocrystalline materials are less leachable than glasses. Interesting possibilities are shown for use of basalt as filling material in underground storage, since basalt decrease glass deterioration [fr

  15. Subaqueous rhyolite block lavas in the Miocene Ushikiri Formation, Shimane Peninsula, SW Japan

    Science.gov (United States)

    Kano, Kazuhiko; Takeuchi, Keiji; Yamamoto, Takahiro; Hoshizumi, Hideo

    1991-06-01

    A rhyolite mass of the Miocene Ushikiri Formation in the western part of the Shimane Peninsula, SW Japan, is a small subaqueous edifice about 600 m high and 4 km wide, formed at water depths between 200 and 1000 m. It consists mainly of three relatively flat, lava-flow units 50-300 m in maximum thickness, each of which includes lobes and their polyhedral fragments. The lava lobes are poorly to well vesiculated, glassy to microcrystalline and flow-banded and -folded. Compared with mafic pillows, they are large, having thick, quenched and brecciated, glassy crusts because of their high viscosity, surface tension and thermal conductivity. Their surfaces disintegrate into polyhedral fragments and grade into massive volcanic breccia. The massive volcanic breccia composed of the lobe fragments is poorly sorted and covered with stratified volcanic breccia of the same rock type. The rhyolite lavas commonly bifurcate in a manner similar to mafic pillow lavas. However, they are highly silicic with 1-5 vol.% phenocrysts and have elongated vesicles and flow-folds, implying that they were visco-plastic during flowage. Their surface features are similar to those of subaerial block lava. With respect to rheological and morphological features, they are subaqueous equivalents of block lava.

  16. Impact of water and sediment discharges on subaqueous delta evolution in Yangtze Estuary from 1950 to 2010

    Directory of Open Access Journals (Sweden)

    Yun-ping Yang

    2014-07-01

    Full Text Available In order to determine how the subaqueous delta evolution depends on the water and sediment processes in the Yangtze Estuary, the amounts of water and sediment discharged into the estuary were studied. The results show that, during the period from 1950 to 2010, there was no significant change in the annual water discharge, and the multi-annual mean water discharge increased in dry seasons and decreased in flood seasons. However, the annual sediment discharge and the multi-annual mean sediment discharge in flood and dry seasons took on a decreasing trend, and the intra-annual distribution of water and sediment discharges tended to be uniform. The evolution process from deposition to erosion occurred at the −10 m and −20 m isobaths of the subaqueous delta. The enhanced annual water and sediment discharges had a silting-up effect on the delta, and the effect of sediment was greater than that of water. Based on data analysis, empirical curves were built to present the relationships between the water and sediment discharges over a year or in dry and flood seasons and the erosion/deposition rates in typical regions of the subaqueous delta, whose evolution followed the pattern of silting in flood seasons and scouring in dry seasons. Notably, the Three Gorges Dam has changed the distribution processes of water and sediment discharges, and the dam's regulating and reserving functions can benefit the subaqueous delta deposition when the annual water and sediment discharges are not affected.

  17. The evolution of a subaqueous delta in the Anthropocene: A stratigraphic investigation of the Brazos River delta, TX USA

    Science.gov (United States)

    Carlin, Joseph A.; Dellapenna, Timothy M.

    2015-12-01

    Globally, deltas are increasingly threatened by anthropogenic activities. As a result, deltas now evolve through the combined effects of natural and human-induced processes occurring throughout the fluvial-deltaic system. The Brazos River delta, located along the Texas coast in the northwestern Gulf of Mexico, and its watershed have been impacted by direct and indirect human activities since the late 19th century. This provides an opportunity to investigate how such alterations have shaped the evolution of a delta in the Anthropocene, a time when humans are drivers of geological change. Historic alteration to the delta and watershed include extensive agricultural activity, jetty construction at the mouth in the late 1890s, mouth diversion ~10 km to the southwest in 1929, and reservoir construction throughout the early and mid 20th Century. Three subaerial deltaic geometries provided the framework to connect subaerial deltaic responses, to the anthropogenic alterations, to the resulting stratigraphic characteristics observed in the subaqueous delta. This study utilized high-resolution geophysical data (swath bathymetry, side scan sonar, CHIRP subbottom profiling) on the subaqueous delta to investigate the subaqueous delta stratigraphy and infer the processes that shaped the deltaic record over time. The results showed distinct areas across the subaqueous delta that were dominated by erosion and deposition. Erosional areas corresponded to earlier growth phase depocenters being exposed at the surface, while the depositional areas corresponded to areas with the most recent growth phase depocenter overlying the earlier depocenters. These results highlight that the subaqueous depocenter has migrated westward over time, consistent with the observed changes to the subaerial delta. Additionally, the data showed that evidence for these past growth phases and depocenters may be preserved within the subaqueous delta, even after subaerial portions of the delta returned to pre

  18. Production of continuous glass fiber using lunar simulant

    Science.gov (United States)

    Tucker, Dennis S.; Ethridge, Edwin C.; Curreri, Peter A.

    1991-01-01

    The processing parameters and mechanical properties of glass fibers pulled from simulated lunar basalt are tested. The simulant was prepared using a plasma technique. The composition is representative of a low titanium mare basalt (Apollo sample 10084). Lunar gravity experiments are to be performed utilizing parabolic aircraft free-fall maneuvers which yield 30 seconds of 1/6-g per maneuver.

  19. Changes to subaqueous delta bathymetry following a high river flow event, Wax Lake Delta, LA, USA

    Science.gov (United States)

    Whaling, A. R.; Shaw, J.

    2017-12-01

    Sediment transport capacity is increased during high river flow (flood) events which are characterized by discharges that exceed the 15 year median daily statistic. The Wax Lake Delta (WLD) in coastal Louisiana has experienced 19 of these high flow events in the past 20 years, yet the depositional patterns of single floods are rarely measured in a field-scale deltaic setting. We characterize flood deposition and erosion patterns on the subaqueous portion of the WLD by differencing two Digital Elevation Models (DEMs) constructed from bathymetric surveys before and after the third largest flood in the WLD's recorded history. The total suspended sediment discharge for the 496 day inter-survey period was 2.14x107 cubic meters measured 21 km upstream of the delta apex. The difference map showed 1.06x107 cubic meters of sediment was deposited and 8.2x106 cubic meters was eroded, yielding 2.40x106 cubic meters of net deposition in the survey area ( 79.7 km2 ). Therefore the average deposition rate was 0.061 mm/day. Channel planform remained relatively unchanged for five out of six distributary passes however Gadwall Pass experienced a maximum channel displacement of 166 m ( 1 channel width) measured from the thalweg centerline. Channel tip extension was negligible. In addition, channel displacement was not concentrated at any portion along the channel centerline. Maximum erosion occurred within channel margins and increased upstream whereas maximum deposition occurred immediately outside the channel margins. Sediment eroded from the survey area was either subsequently re-deposited or transported out of the system. Our results show that up to 77.4% of deposition in the survey area originated from sediment eroded during the flood. Surprisingly, only 11.2% of the total suspended sediment discharge was retained in the subaqueous portion of the delta after the flood. We conclude that a high flow event does not produce channel progradation. Rather, high flow causes delta

  20. Biologically mediated dissolution of volcanic glass in seawater

    NARCIS (Netherlands)

    Staudigel, H; Yayanos, A; Chastain, R; Davies, G.T.; Verdurmen, E.A Th; Schiffmann, P; Bourcier, R; de Baar, H.J.W.

    1998-01-01

    We studied the effects of biological mediation on the dissolution of basaltic glass in seawater. Experiments with typical seawater microbial populations were contrasted with a sterile control, and reactions were monitored chemically and isotopically. Biologically mediated experiments produce twice

  1. Elastic Anisotropy of Basalt

    Science.gov (United States)

    Becker, K.; Shapiro, S.; Stanchits, S.; Dresen, G.; Kaselow, A.; Vinciguerra, S.

    2005-12-01

    Elastic properties of rocks are sensitive to changes of the in-situ stress and damage state. In particular, seismic velocities are strongly affected by stress-induced formation and deformation of cracks or shear-enhanced pore collapse. The effect of stress on seismic velocities as a result of pore space deformation in isotropic rock at isostatic compression may be expressed by the equation: A+K*P-B*exp (-D*P) (1), where P=Pc-Pp is the effective pressure, the pure difference between confining pressure and pore pressure. The parameter A, K, B and D describe material constants determined using experimental data. The physical meaning of the parameters is given by Shapiro (2003, in Geophysics Vol.68(Nr.2)). Parameter D is related to the stress sensitivity of the rock. A similar relation was derived by Shapiro and Kaselow (2005, in Geophysics in press) for weak anisotropic rocks under arbitrary load. They describe the stress dependent anisotropy in terms of Thomson's (1986, in Geophysics, Vol. 51(Nr.10)) anisotropy parameters ɛ and γ as a function of stress in the case of an initially isotropic rock: ɛ ∝ E2-E3, γ ∝ E3-E2 (2) with Ei=exp (D*Pi). The exponential terms Ei are controlled by the effective stress components Pi. To test this relation, we have conducted a series of triaxial compression tests on dry samples of initially isotropic Etnean Basalt in a servo-controlled MTS loading frame equipped with a pressure cell. Confining pressure was 60, 40 and 20 MPa. Samples were 5 cm in diameter and 10 cm in length. Elastic anisotropy was induced by axial compression of the samples through opening and growth of microcracks predominantly oriented parallel to the sample axis. Ultrasonic P- and S- wave velocities were monitored parallel and normal to the sample axis by an array of 20 piezoceramic transducers glued to the surface. Preamplified full waveform signals were stored in two 12 channel transient recorders. According to equation 2 the anisotropy parameters are

  2. Subaqueous ice-contact fans: Depositional systems characterised by highly aggradational supercritical flow conditions

    Science.gov (United States)

    Lang, Joerg; Winsemann, Jutta

    2015-04-01

    Subaqueous ice-contact fans are deposited by high-energy plane-wall jets from subglacial conduits into standing water bodies. Highly aggradational conditions during flow expansion and deceleration allow for the preservation of bedforms related to supercritical flows, which are commonly considered rare in the depositional record. We present field examples from gravelly and sandy subaqueous ice-contact fan successions, which indicate that deposition by supercritical flows might be considered as a characteristic feature of these depositional systems. The studied successions were deposited in deep ice-dammed lakes, which formed along the margins of the Middle Pleistocene Scandinavian ice sheets across Northern Germany. The gravel-rich subaqueous fan deposits are dominated by large scour-fills (up to 25 m wide and 3 m) deep and deposits of turbulent hyperconcentrated flows, which are partly attributed to supercritical flow conditions (Winsemann et al., 2009). Scours (up to 4.5 m wide and 0.9 m deep) infilled by gravelly backsets are observed above laterally extensive erosional surfaces and are interpreted as deposits of cyclic steps. Laterally discontinuous beds of low-angle cross-stratified gravel are interpreted as antidune deposits. Downflow and up-section the gravel-rich deposits pass into sand-rich successions, which include deposits of chutes-and-pools, breaking antidunes, stationary antidunes and humpback dunes (Lang and Winsemann, 2013). Deposits of chutes-and-pools and breaking antidunes are characterised by scour-fills (up to 4 m wide and 1.2 m deep) comprising backsets or gently dipping sigmoidal foresets. Stationary antidune deposits consist of laterally extensive sinusoidal waveforms with long wavelengths (1-12 m) and low amplitudes (0.1-0.5 m), which formed under quasi-steady flows at the lower limit of the supercritical flow stage and high rates of sedimentation. Humpback dunes are characterised by divergent sigmoidal foresets and are interpreted as

  3. Soil organic matter degradation and enzymatic profiles of intertidal and subaqueous soils

    Science.gov (United States)

    Ferronato, Chiara; Marinari, Sara; Bello, Diana; Vianello, Gilmo; Trasar-Cepeda, Carmen; Vittori Antisari, Livia

    2017-04-01

    The interest on intertidal and subaqueous soils has recently arisen because of the climate changes forecasts. The preservation of these habitats represents an important challenge for the future of humanity, because these systems represent an important global C sink since soil organic matter (SOM) on intertidal and subaqueous soils undergoes very slow degradation rates due to oxygen limitation. Publications on SOM cycle in saltmarshes are very scarce because of the difficulties involved on those studies i.e. the interaction of many abiotic and biotic factors (e.g., redox changes, water and bio-turbation processes, etc) and stressors (e.g., salinity and anoxia). However, saltmarshes constitute an unique natural system to observe the influence of anoxic conditions on SOM degradation, because the tide fluctuations on the soil surface allow the formation of provisionally or permanently submerged soils. With the aim to investigate the quality of SOM in subaqueous soils, triplicates of subaqueous soils (SASs), intertidal soils (ITSs) and terrestrial soils (TESs) were collected in the saltmarshes of the Baiona Lagoon (Northern Italy) and classified according to their pedogenetic horizons. The SOM quality on each soil horizon was investigated by quantifying SOM, total and water-soluble organic carbon (TOC, WSC) and microbial biomass carbon (MBC). Given the contribution of soil enzymes to the degradation of SOM, some enzymatic assays were also performed. Thereafter, soil classification and humus morpho-functional classification were used to join together similar soil profiles to facilitate the description and discussion of results. Soils were ranked as Aquent or Wassent Entisols, with an A/AC/C pedosequence. SOM, TOC and MBC were statistically higher in A than in AC and C horizons. Among the A horizons, ITSs were those showing the highest values for these parameters (11% TOC, 1.6 mg kg-1 MBC, 0.9 mg kg-1 WSC). These results, combined with the morpho-functional classification

  4. Review of glass ceramic waste forms

    International Nuclear Information System (INIS)

    Rusin, J.M.

    1981-01-01

    Glass ceramics are being considered for the immobilization of nuclear wastes to obtain a waste form with improved properties relative to glasses. Improved impact resistance, decreased thermal expansion, and increased leach resistance are possible. In addition to improved properties, the spontaneous devitrification exhibited in some waste-containing glasses can be avoided by the controlled crystallization after melting in the glass-ceramic process. The majority of the glass-ceramic development for nuclear wastes has been conducted at the Hahn-Meitner Institute (HMI) in Germany. Two of their products, a celsian-based (BaAl 3 Si 2 O 8 ) and a fresnoite-based (Ba 2 TiSi 2 O 8 ) glass ceramic, have been studied at Pacific Northwest Laboratory (PNL). A basalt-based glass ceramic primarily containing diopsidic augite (CaMgSi 2 O 6 ) has been developed at PNL. This glass ceramic is of interest since it would be in near equilibrium with a basalt repository. Studies at the Power Reactor and Nuclear Fuel Development Corporation (PNC) in Japan have favored a glass-ceramic product based upon diopside (CaMgSi 2 O 6 ). Compositions, processing conditions, and product characterization of typical commercial and nuclear waste glass ceramics are discussed. In general, glass-ceramic waste forms can offer improved strength and decreased thermal expansion. Due to typcially large residual glass phases of up to 50%, there may be little improvement in leach resistance

  5. Sulfur release from the Columbia River Basalts and other flood lava eruptions constrained by a model of sulfide saturation

    Science.gov (United States)

    Blake, S.; Self, S.; Sharma, K.; Sephton, S.

    2010-11-01

    A very likely cause of widespread environmental impacts of flood basalt eruptions is the emission of sulfur, chlorine, and possibly fluorine from the erupting magma. We present new data on the S contents of rare glass inclusions and matrix glasses preserved in quenched lava selvages from lava fields of the Columbia River Basalt Group (CRBG; Ginkgo, Sand Hollow and Sentinel Gap flows, Wanapum Basalt Formation). We compare these results with published data from Neral and Jawar Formation lavas (Deccan Traps, India) and the Roza flow (CRBG). CRBG glass inclusions have up to 2000 ppm S and 15-16 wt.% FeO total. By contrast, the Deccan examples have about 1400 ppm S and 10 wt.% FeO total. Several of the glass inclusions are partly degassed, indicating entrapment during magma rise, and matrix glasses are typically more evolved than glass inclusions due to small amounts of in situ crystallization. Using only the highest S inclusions and taking account of the effect of in situ crystallization and degassing on the S content of the residual matrix glasses indicates S yields of about 0.07 to 0.1 wt.% from Deccan eruptions and about 0.15 wt.% from Wanapum (CRBG) eruptions. The pre-eruptive S contents of these magmas correlate with weight% FeO total in the same way as undegassed sulfide-saturated mid-ocean ridge basalts. Using oceanic basalts to define a sulfide saturation line, and data on S contents of degassed basalts, we propose an equation to estimate the weight% S yield (ΔS) from initially sulfide-saturated basalt liquid without the need to find well-preserved, rare, undegassed glass inclusions and matrix glasses: ΔS=(0.01418×FeO-0.06381)±0.02635. This compares well with independent estimates derived from the petrologic method by taking the difference in S concentration of glass inclusions and matrix glass. Applying our method to the aphyric Grande Ronde Basalts of the CRBG implies a total yield of about 1000 Gt SO 2 delivered into the Miocene atmosphere in

  6. A study on the crushing behavior of basalt fiber reinforced composite structures

    Science.gov (United States)

    Pandian, A.; Veerasimman, A. P.; Vairavan, M.; Francisco, C.; Sultan, M. T. H.

    2016-10-01

    The crushing behavior and energy absorption capacity of basalt fiber reinforced hollow square structure composites are studied under axial compression. Using the hand layup technique, basalt fiber reinforced composites were fabricated using general purpose (GP) polyester resin with the help of wooden square shaped mould of varying height (100 mm, 150 mm and 200 mm). For comparison, similar specimens of glass fiber reinforced polymer composites were also fabricated and tested. Axial compression load is applied over the top end of the specimen with cross head speed as 2 mm/min using Universal Testing Machine (UTM). From the experimental results, the load-deformation characteristics of both glass fiber and basalt fiber composites were investigated. Crashworthiness and mode of collapse for the composites were determined from load-deformation curve, and they were then compared to each other in terms of their crushing behaviors.

  7. Structural Analysis of Basalt Fiber Reinforced Plastic Wind Turbine Blade

    Directory of Open Access Journals (Sweden)

    Mengal Ali Nawaz

    2014-07-01

    Full Text Available In this study, Basalt fiber reinforced plastic (BFRP wind turbine blade was analyzed and compared with Glass fiber reinforced plastic blade (GFRP. Finite element analysis (FEA of blade was carried out using ANSYS. Data for FEA was obtained by using rule of mixture. The shell element in ANSYS was used to simulate the wind turbine blade and to conduct its strength analysis. The structural analysis and comparison of blade deformations proved that BFRP wind turbine blade has better strength compared to GFRP wind turbine blade.

  8. Research of mountain rocks of Georgia for using in glass materials industry

    International Nuclear Information System (INIS)

    Gabunia, L.; Gabunia, N.; Jakhva, N.; Napetvaridze, Ts.; Alibegashvili, M.

    2009-01-01

    The article presents the results of the research of mountain rocks of Georgia in various peaces of basalts, andesite, andesite-basalt porphyry and trachite deposits in order to be used in the industry of fiber, glass-crystal materials and fasade decorative tiles. The prospects of basalt and andesite-basalt porphyry use in the industry of fiber materials in the form of monocomponents has been stated. The technology of obtaining of wear resistant, chemically stable and colored glass-crystal on the basis of andesit and trachyte, has been worked out and approved in industry. (author)

  9. Volcanic glasses, their origins and alteration processes

    Science.gov (United States)

    Friedman, I.; Long, W.

    1984-01-01

    Natural glass can be formed by volcanic processes, lightning (fulgarites) burning coal, and by meteorite impact. By far the most common process is volcanic - basically the glass is rapidly chilled molten rock. All natural glasses are thermodynamically unstable and tend to alter chemically or to crystallize. The rate of these processes is determined by the chemical composition of the magma. The hot and fluid basaltic melts have a structure that allows for rapid crystal growth, and seldom forms glass selvages greater than a few centimeters thick, even when the melt is rapidly cooled by extrusion in the deep sea. In contrast the cooler and very viscous rhyolitic magmas can yield bodies of glass that are tens of meters thick. These highly polymerized magmas have a high silica content - often 71-77% SiO2. Their high viscosity inhibits diffusive crystal growth. Basalt glass in sea water forms an alteration zone called palagonite whose thickness increases linearly with time. The rate of diffusion of water into rhyolitic glass, which follows the relationship - thickness = k (time) 1 2, has been determined as a function of the glass composition and temperature. Increased SiO2 increases the rate, whereas increased CaO, MgO and H2O decrease the rate. The activation energy of water diffusion varies from about 19 to 22 kcal/mol. for the glasses studied. The diffusion of alkali out of rhyolite glass occurs simultaneously with water diffusion into the glass. The rate of devitrification of rhyolitic glass is a function of the glass viscosity, which in turn is a function of water content and temperature. Although all of the aforementioned processes tend to destroy natural glasses, the slow rates of these processes, particularly for rhyolitic glass, has allowed samples of glass to persist for 60 million years. ?? 1984.

  10. Diversity of life in ocean floor basalt

    Science.gov (United States)

    Thorseth, I. H.; Torsvik, T.; Torsvik, V.; Daae, F. L.; Pedersen, R. B.

    2001-12-01

    Electron microscopy and biomolecular methods have been used to describe and identify microbial communities inhabiting the glassy margins of ocean floor basalts. The investigated samples were collected from a neovolcanic ridge and from older, sediment-covered lava flows in the rift valley of the Knipovich Ridge at a water depth around 3500 m and an ambient seawater temperature of -0.7°C. Successive stages from incipient microbial colonisation, to well-developed biofilms occur on fracture surfaces in the glassy margins. Observed microbial morphologies are various filamentous, coccoidal, oval, rod-shaped and stalked forms. Etch marks in the fresh glass, with form and size resembling the attached microbes, are common. Precipitation of alteration products around microbes has developed hollow subspherical and filamentous structures. These precipitates are often enriched in Fe and Mn. The presence of branching and twisted stalks that resemble those of the iron-oxidising Gallionella, indicate that reduced iron may be utilised in an energy metabolic process. Analysis of 16S-rRNA gene sequences from microbes present in the rock samples, show that the bacterial population inhabiting these samples cluster within the γ- and ɛ-Proteobacteria and the Cytophaga/Flexibacter/Bacteroides subdivision of the Bacteria, while the Archaea all belong to the Crenarchaeota kingdom. This microbial population appears to be characteristic for the rock and their closest relatives have previously been reported from cold marine waters in the Arctic and Antarctic, deep-sea sediments and hydrothermal environments.

  11. A high-frequency sonar for profiling small-scale subaqueous bedforms

    Science.gov (United States)

    Dingler, J.R.; Boylls, J.C.; Lowe, R.L.

    1977-01-01

    A high-resolution ultrasonic profiler has been developed which permits both laboratory and field studies of small-scale subaqueous bedforms. The device uses a 2.5-cm diameter piezoelectric ceramic crystal pulsed at a frequency of 4.5 MHz to obtain vertical accuracy and resolution of at least 1 mm. Compared to other small-scale profiling methods, this ultrasonic technique profiles the bottom more accurately and more rapidly without disturbing the bedforms. These characteristics are vital in wave-dominated nearshore zones where oscillatory flow and low visibility for the most part have stymied detailed bedform studies. In the laboratory the transducer is mounted directly to an instrument carriage. For field work the transducer housing is mounted in a 2 m long aluminum frame which is situated and operated by scuba divers. Observations using the device include ripple geometry and migration, the suspension height of sand during sheet flow, and long-term erosion/deposition at a point. ?? 1977.

  12. Properties of composite laminates based on basalt fibers with epoxidized vegetable oils

    International Nuclear Information System (INIS)

    Samper, M.D.; Petrucci, R.; Sanchez-Nacher, L.; Balart, R.; Kenny, J.M.

    2015-01-01

    Highlights: • New environmentally friendly composites from biobased epoxies and basalt fibers. • Improved performance with conventional silane treatment on basalt fabrics. • Composites with excellent appearance due to basalt shiny brown color. • Potential applications as substitute of glass fiber reinforced composites in engineering design. • Processing with conventional resin transfer molding (RTM) techniques. - Abstract: This paper deals with the development of polymeric materials derived from epoxidized vegetable oils which have been used in the manufacture of laminated composite materials with basalt fabrics. Epoxidized linseed oil (ELO) and epoxidized soybean oil (ESBO) were used as biobased matrices. The basalt fabrics were modified with amino-silane and glycidyl-silane to increase fiber–matrix interactions. The curing behavior of both resins was evaluated by differential scanning calorimetry (DSC) and oscillatory rheometry (OR). The evaluation of mechanical properties was made by tensile, flexural and Charpy tests. The extent of the fiber–matrix interactions among interface was evaluated by scanning electron microscopy (SEM). The obtained results revealed that surface modification of basalt fibers with glycidyl-silane clearly improves the mechanical properties of the composites. The use of the ELO resin as matrix for composite laminates improved substantially the mechanical performance compared to composites made with ESBO

  13. Dissolution and secondary mineral precipitation in basalts due to reactions with carbonic acid

    Science.gov (United States)

    Kanakiya, Shreya; Adam, Ludmila; Esteban, Lionel; Rowe, Michael C.; Shane, Phil

    2017-06-01

    One of the leading hydrothermal alteration processes in volcanic environments is when rock-forming minerals with high concentrations of iron, magnesium, and calcium react with CO2 and water to form carbonate minerals. This is used to the advantage of geologic sequestration of anthropogenic CO2. Here we experimentally investigate how mineral carbonation processes alter the rock microstructure due to CO2-water-rock interactions. In order to characterize these changes, CO2-water-rock alteration in Auckland Volcanic Field young basalts (less than 0.3 Ma) is studied before and after a 140 day reaction period. We investigate how whole core basalts with similar geochemistry but different porosity, permeability, pore geometry, and volcanic glass content alter due to CO2-water-rock reactions. Ankerite and aluminosilicate minerals precipitate as secondary phases in the pore space. However, rock dissolution mechanisms are found to dominate this secondary mineral precipitation resulting in an increase in porosity and decrease in rigidity of all samples. The basalt with the highest initial porosity and volcanic glass volume shows the most secondary mineral precipitation. At the same time, this sample exhibits the greatest increase in porosity and permeability, and a decrease in rock rigidity post reaction. For the measured samples, we observe a correlation between volcanic glass volume and rock porosity increase due to rock-fluid reactions. We believe this study can help understand the dynamic rock-fluid interactions when monitoring field scale CO2 sequestration projects in basalts.

  14. Estimation of the geological age of oceanic basalts by track method

    International Nuclear Information System (INIS)

    Komarov, A.N.; Krylov, A.Ya.

    1977-01-01

    The method is described of the determination of the thermostability of tracks applied to oceanic basalts and the comparison is carried out of age values obtained for the same samples by the track method and by the potassium-argon method. The obtained results allow to consider that the track method is quite practicable for the dating of oceanic basalts on the condition that natural annealing of a part of tracks of the spontaneous uranium fission is taken into accout. For glasses of the other origin - tektites - such approach results in the agreement of the obtained values with the results of potassium-argon method

  15. Strengthening of reinforced concrete beams with basalt-based FRP sheets: An analytical assessment

    International Nuclear Information System (INIS)

    Nerilli, Francesca; Vairo, Giuseppe

    2016-01-01

    In this paper the effectiveness of the flexural strengthening of RC beams through basalt fiber-reinforced sheets is investigated. The non-linear flexural response of RC beams strengthened with FRP composites applied at the traction side is described via an analytical formulation. Validation results and some comparative analyses confirm soundness and consistency of the proposed approach, and highlight the good mechanical performances (in terms of strength and ductility enhancement of the beam) produced by basalt-based reinforcements in comparison with traditional glass or carbon FRPs.

  16. Strengthening of reinforced concrete beams with basalt-based FRP sheets: An analytical assessment

    Energy Technology Data Exchange (ETDEWEB)

    Nerilli, Francesca [Unicusano - Università degli Studi Niccolò Cusano Telematica Roma, 00166 Rome (Italy); Vairo, Giuseppe [Università degli Studi di Roma “Tor Vergata”- (DICII), 00133 Rome (Italy)

    2016-06-08

    In this paper the effectiveness of the flexural strengthening of RC beams through basalt fiber-reinforced sheets is investigated. The non-linear flexural response of RC beams strengthened with FRP composites applied at the traction side is described via an analytical formulation. Validation results and some comparative analyses confirm soundness and consistency of the proposed approach, and highlight the good mechanical performances (in terms of strength and ductility enhancement of the beam) produced by basalt-based reinforcements in comparison with traditional glass or carbon FRPs.

  17. Strengthening of reinforced concrete beams with basalt-based FRP sheets: An analytical assessment

    Science.gov (United States)

    Nerilli, Francesca; Vairo, Giuseppe

    2016-06-01

    In this paper the effectiveness of the flexural strengthening of RC beams through basalt fiber-reinforced sheets is investigated. The non-linear flexural response of RC beams strengthened with FRP composites applied at the traction side is described via an analytical formulation. Validation results and some comparative analyses confirm soundness and consistency of the proposed approach, and highlight the good mechanical performances (in terms of strength and ductility enhancement of the beam) produced by basalt-based reinforcements in comparison with traditional glass or carbon FRPs.

  18. Detection of structural heterogeneity of glass melts

    DEFF Research Database (Denmark)

    Yue, Yuanzheng

    2004-01-01

    The structural heterogeneity of both supercooled liquid and molten states of silicate has been studied using calorimetric method. The objects of this study are basaltic glasses and liquids. Two experimental approaches are taken to detect the structural heterogeneity of the liquids. One is the hyp......The structural heterogeneity of both supercooled liquid and molten states of silicate has been studied using calorimetric method. The objects of this study are basaltic glasses and liquids. Two experimental approaches are taken to detect the structural heterogeneity of the liquids. One...... is the hyperquench-anneal-calorimetric scan approach, by which the structural information of a basaltic supercooled liquid and three binary silicate liquids is acquired. Another is the calorimetrically repeated up- and downscanning approach, by which the structural heterogeneity, the intermediate range order...... is discussed. The ordered structure of glass melts above the liquidus temperature is indirectly characterized by use of X-ray diffraction method. The new approaches are of importance for monitoring the glass melting and forming process and for improving the physical properties of glasses and glass fibers....

  19. Subseafloor basalts as fungal habitats

    Science.gov (United States)

    Ivarsson, M.; Bengtson, S.

    2013-12-01

    The oceanic crust makes up the largest potential habitat for life on Earth, yet next to nothing is known about the abundance, diversity and ecology of its biosphere. Our understanding of the deep biosphere of subseafloor crust is, with a few exceptions, based on a fossil record. Surprisingly, a majority of the fossilized microorganisms have been interpreted or recently re-interpreted as remnants of fungi rather than prokaryotes. Even though this might be due to a bias in fossilization the presence of fungi in these settings can not be neglected. We have examined fossilized microorganisms in drilled basalt samples collected at the Emperor Seamounts in the Pacific Ocean. Synchrotron-radiation X-ray tomography microscopy (SRXTM) studies has revealed a complex morphology and internal structure that corresponds to characteristic fungal morphology. Chitin was detected in the fossilized hyphae, which is another strong argument in favour of a fungal interpretation. Chitin is absent in prokaryotes but a substantial constituent in fungal cell walls. The fungal colonies consist of both hyphae and yeast-like growth states as well as resting structures and possible fruit bodies, thus, the fungi exist in vital colonies in subseafloor basalts. The fungi have also been involved in extensive weathering of secondary mineralisations. In terrestrial environments fungi are known as an important geobiological agent that promotes mineral weathering and decomposition of organic matter, and they occur in vital symbiosis with other microorganisms. It is probable to assume that fungi would play a similar role in subseafloor basalts and have great impact on the ecology and on biogeochemical cycles in such environments.

  20. Thermodynamic model of natural, medieval and nuclear waste glass durability

    International Nuclear Information System (INIS)

    Jantzen, C.M.; Plodinec, M.J.

    1983-01-01

    A thermodynamic model of glass durability based on hydration of structural units has been applied to natural glass, medieval window glasses, and glasses containing nuclear waste. The relative durability predicted from the calculated thermodynamics correlates directly with the experimentally observed release of structural silicon in the leaching solution in short-term laboratory tests. By choosing natural glasses and ancient glasses whose long-term performance is known, and which bracket the durability of waste glasses, the long-term stability of nuclear waste glasses can be interpolated among these materials. The current Savannah River defense waste glass formulation is as durable as natural basalt from the Hanford Reservation (10 6 years old). The thermodynamic hydration energy is shown to be related to the bond energetics of the glass. 69 references, 2 figures, 1 table

  1. A magnetic record of heavy metal pollution in the Yangtze River subaqueous delta

    Energy Technology Data Exchange (ETDEWEB)

    Dong, Chenyin [State Key Laboratory of Estuarine and Coastal Research, East China Normal University, Shanghai 200062 (China); Zhang, Weiguo, E-mail: wgzhang@sklec.ecnu.edu.cn [State Key Laboratory of Estuarine and Coastal Research, East China Normal University, Shanghai 200062 (China); Ma, Honglei [State Key Laboratory of Estuarine and Coastal Research, East China Normal University, Shanghai 200062 (China); Feng, Huan [Department of Earth and Environmental Studies, Montclair State University, NJ 07043 (United States); Lu, Honghua [Department of Geography, College of Resources and Environmental Science, East China Normal University, Shanghai 200241 (China); Dong, Yan [State Key Laboratory of Estuarine and Coastal Research, East China Normal University, Shanghai 200062 (China); Institute of Geographic Engineering Technology, School of Geographical Science, Nantong University, Nantong 226007 (China); Yu, Lizhong [State Key Laboratory of Estuarine and Coastal Research, East China Normal University, Shanghai 200062 (China)

    2014-04-01

    The rapid industrial development in the Yangtze River watershed over the last several decades has drawn great attention with respect to heavy metal pollution to the Yangtze River estuary and nearby coastal areas. In this study, a 236 cm long sediment core was retrieved from the Yangtze River subaqueous delta (122°36′ E, 31°00′ N) in 2008 and analyzed for magnetic properties and geochemical compositions to investigate heavy metal pollution history. The activity of {sup 137}Cs peaked at depth 140 cm, with a broad plateau between 120 cm and 140 cm, suggesting an average sedimentation rate of 3.11 cm yr{sup −1} for the upper 140 cm layer. Magnetic susceptibility (χ), saturation isothermal remanent magnetization (SIRM), anhysteretic remanent magnetization (χ{sub ARM}) and heavy metal enrichment factors (EF) all showed an upward increase trend above depth 140 cm, suggesting that increased ferrimagnetic mineral concentration was accompanied by heavy metal enrichment in the sediment. Geochemical and granolumetric analyses showed that sediment sources and particle sizes played minor roles in the variations of magnetic properties. The effect of diagenesis, which can lead to the selective removal of magnetic minerals, was noticeable in the lower part of the core (140–236 cm). Co-variation between magnetic properties (χ, SIRM and χ{sub ARM}) and EF of Cu and Pb suggests that the elevated ferrimagnetic mineral concentration can be used as an indicator of heavy metal pollution in the reconstruction of environmental changes in estuarine and coastal settings. - Highlights: • Magnetic parameters can be used as heavy metal pollution proxy. • Heavy metal contents in the Yangtze River estuary increase since the 1960s. • Heavy metal pollution is largely driven by population growth in the catchment.

  2. A magnetic record of heavy metal pollution in the Yangtze River subaqueous delta.

    Science.gov (United States)

    Dong, Chenyin; Zhang, Weiguo; Ma, Honglei; Feng, Huan; Lu, Honghua; Dong, Yan; Yu, Lizhong

    2014-04-01

    The rapid industrial development in the Yangtze River watershed over the last several decades has drawn great attention with respect to heavy metal pollution to the Yangtze River estuary and nearby coastal areas. In this study, a 236 cm long sediment core was retrieved from the Yangtze River subaqueous delta (122°36' E, 31°00' N) in 2008 and analyzed for magnetic properties and geochemical compositions to investigate heavy metal pollution history. The activity of (137)Cs peaked at depth 140 cm, with a broad plateau between 120 cm and 140 cm, suggesting an average sedimentation rate of 3.11 cm yr(-1) for the upper 140 cm layer. Magnetic susceptibility (χ), saturation isothermal remanent magnetization (SIRM), anhysteretic remanent magnetization (χARM) and heavy metal enrichment factors (EF) all showed an upward increase trend above depth 140 cm, suggesting that increased ferrimagnetic mineral concentration was accompanied by heavy metal enrichment in the sediment. Geochemical and granolumetric analyses showed that sediment sources and particle sizes played minor roles in the variations of magnetic properties. The effect of diagenesis, which can lead to the selective removal of magnetic minerals, was noticeable in the lower part of the core (140-236 cm). Co-variation between magnetic properties (χ, SIRM and χARM) and EF of Cu and Pb suggests that the elevated ferrimagnetic mineral concentration can be used as an indicator of heavy metal pollution in the reconstruction of environmental changes in estuarine and coastal settings. Copyright © 2014. Published by Elsevier B.V.

  3. A magnetic record of heavy metal pollution in the Yangtze River subaqueous delta

    International Nuclear Information System (INIS)

    Dong, Chenyin; Zhang, Weiguo; Ma, Honglei; Feng, Huan; Lu, Honghua; Dong, Yan; Yu, Lizhong

    2014-01-01

    The rapid industrial development in the Yangtze River watershed over the last several decades has drawn great attention with respect to heavy metal pollution to the Yangtze River estuary and nearby coastal areas. In this study, a 236 cm long sediment core was retrieved from the Yangtze River subaqueous delta (122°36′ E, 31°00′ N) in 2008 and analyzed for magnetic properties and geochemical compositions to investigate heavy metal pollution history. The activity of 137 Cs peaked at depth 140 cm, with a broad plateau between 120 cm and 140 cm, suggesting an average sedimentation rate of 3.11 cm yr −1 for the upper 140 cm layer. Magnetic susceptibility (χ), saturation isothermal remanent magnetization (SIRM), anhysteretic remanent magnetization (χ ARM ) and heavy metal enrichment factors (EF) all showed an upward increase trend above depth 140 cm, suggesting that increased ferrimagnetic mineral concentration was accompanied by heavy metal enrichment in the sediment. Geochemical and granolumetric analyses showed that sediment sources and particle sizes played minor roles in the variations of magnetic properties. The effect of diagenesis, which can lead to the selective removal of magnetic minerals, was noticeable in the lower part of the core (140–236 cm). Co-variation between magnetic properties (χ, SIRM and χ ARM ) and EF of Cu and Pb suggests that the elevated ferrimagnetic mineral concentration can be used as an indicator of heavy metal pollution in the reconstruction of environmental changes in estuarine and coastal settings. - Highlights: • Magnetic parameters can be used as heavy metal pollution proxy. • Heavy metal contents in the Yangtze River estuary increase since the 1960s. • Heavy metal pollution is largely driven by population growth in the catchment

  4. Impacts of Declining Mississippi River Sediment Load on Subaqueous Delta Front Sedimentation and Geomorphology

    Science.gov (United States)

    Maloney, J. M.; Bentley, S. J.; Xu, K.; Georgiou, I. Y.; Miner, M. D.

    2016-02-01

    The Mississippi River delta system is undergoing unprecedented changes due to the effects of climate change and anthropogenic alterations to the river and its delta. Since the 1950s, the suspended sediment load of the Mississippi River has decreased by approximately 50% due to the construction of >50,000 dams in the Mississippi basin. The impact of this decreased sediment load has been observed in subaerial environments, but the impact on sedimentation and geomorphology of the subaqueous delta front has yet to be examined. To identify historic trends in sedimentation patterns, we compiled bathymetric datasets, including historical charts, industry and academic surveys, and NOAA data, collected between 1764 and 2009. Sedimentation rates are variable across the delta front, but are highest near the mouth of Southwest Pass, which carries the largest percentage of Mississippi River flow and sediment into the Gulf of Mexico. The progradation rate of Southwest Pass (measured at the 10 m depth contour) has slowed from 67 m/yr between 1764 and 1940 to 26 m/yr between 1940 and 1979, with evidence of further deceleration from 1979-2009. Decreased rates of progradation are also observed at South Pass and Pass A Loutre, with the 10 m contour retreating at rates >20 m/yr at both passes. Advancement of the delta front also decelerated in deeper water (15-90 m) offshore from Southwest Pass. In this area, from 1940-1979, depth contours advanced seaward 30 m/yr, but rates declined from 1979-2005. Furthermore, over the same area, the sediment accumulation rate decreased by 81% for the same period. The Mississippi River delta front appears to be entering a phase of decline, which will likely be accelerated by future upstream management practices. This decline has implications for offshore ecosystems, biogeochemical cycling, pollutant dispersal, mudflow hazard, and the continued use of the delta as an economic and population center.

  5. Assessing subaqueous mudslide hazard on the Mississippi River delta front, Part 2: Insights revealed through high-resolution geophysical surveying

    Science.gov (United States)

    Obelcz, J.; Xu, K.; Bentley, S. J.; Georgiou, I. Y.; Maloney, J. M.; Miner, M. D.; Hanegan, K.; Keller, G.

    2014-12-01

    The northern Gulf of Mexico, including the subaqueous Mississippi River delta front (MRDF), has been productive for oil and gas development since the early 1900s. In 1969 cyclic seafloor wave loading associated with the passage of Hurricane Camille triggered subaqueous mudflows across the MRDF, destroying several offshore oil platforms. This incident spurred geophysical and geotechnical studies of the MRDF, which found that the delta front is prone to mass failures on gentle gradients (gas production, and (3) the frequent passage of tropical cyclones. In June 2014, a geophysical pilot study was conducted 8 km southwest of Southwest Pass, the distributary that currently receives the largest fraction of Mississippi River sediment supply. The resultant dataset encompasses 216 km of subbottom Chirp seismic profiles and a 60 km2 grid of bathymetry and sidescan data. Preliminary interpretation of these data shows the survey area can be classified into four primary sedimentary facies: mudflow gullies, mudflow lobes, undisturbed prodelta, and undisturbed delta front. Subbottom profiles reveal extensive biogenic gas from 20 to about 80 m water depths on the delta front; sidescan data show a variety of bottleneck slides, mudflow gullies and mudflow noses. Previous studies have attempted to constrain the periodicity and magnitude of subaqueous mudslides on the MRDF. However, large age gaps and varied resolution between datasets result in ambiguity regarding the cause and magnitude of observed bathymetric changes. We present high-temporal resolution MRDF bathymetric variations from 2005 (post Hurricane Katrina), 2009 (relatively quiescent storm period), and 2014 (post 2011 Mississippi River flood). These data yield better magnitude and timing estimates of mass movements. This exercise represents a first step towards (1) assembling a comprehensive geologic dataset upon which future MRDF geohazard assessments can be founded, and (2) understanding the dynamics of a massive

  6. Field-trip guide to subaqueous volcaniclastic facies in the Ancestral Cascades arc in southern Washington State—The Ohanapecosh Formation and Wildcat Creek beds

    Science.gov (United States)

    Jutzeler, Martin; McPhie, Jocelyn

    2017-06-27

    Partly situated in the idyllic Mount Rainier National Park, this field trip visits exceptional examples of Oligocene subaqueous volcaniclastic successions in continental basins adjacent to the Ancestral Cascades arc. The >800-m-thick Ohanapecosh Formation (32–26 Ma) and the >300-m-thick Wildcat Creek (27 Ma) beds record similar sedimentation processes from various volcanic sources. Both show evidence of below-wave-base deposition, and voluminous accumulation of volcaniclastic facies from subaqueous density currents and suspension settling. Eruption-fed facies include deposits from pyroclastic flows that crossed the shoreline, from tephra fallout over water, and from probable Surtseyan eruptions, whereas re-sedimented facies comprise subaqueous density currents and debris flow deposits.

  7. Basaltic cannibalism at Thrihnukagigur volcano, Iceland

    Science.gov (United States)

    Hudak, M. R.; Feineman, M. D.; La Femina, P. C.; Geirsson, H.

    2014-12-01

    Magmatic assimilation of felsic continental crust is a well-documented, relatively common phenomenon. The extent to which basaltic crust is assimilated by magmas, on the other hand, is not well known. Basaltic cannibalism, or the wholesale incorporation of basaltic crustal material into a basaltic magma, is thought to be uncommon because basalt requires more energy than higher silica rocks to melt. Basaltic materials that are unconsolidated, poorly crystalline, or palagonitized may be more easily ingested than fully crystallized massive basalt, thus allowing basaltic cannibalism to occur. Thrihnukagigur volcano, SW Iceland, offers a unique exposure of a buried cinder cone within its evacuated conduit, 100 m below the main vent. The unconsolidated tephra is cross-cut by a NNE-trending dike, which runs across the ceiling of this cave to a vent that produced lava and tephra during the ~4 Ka fissure eruption. Preliminary petrographic and laser ablation inductively coupled mass spectrometry (LA-ICP-MS) analyses indicate that there are two populations of plagioclase present in the system - Population One is stubby (aspect ratio 2.1), subhedral to euhedral, and has much higher Ba/Sr ratios. Population One crystals are observed in the cinder cone, dike, and surface lavas, whereas Population Two crystals are observed only in the dike and surface lavas. This suggests that a magma crystallizing a single elongate population of plagioclase intruded the cinder cone and rapidly assimilated the tephra, incorporating the stubbier population of phenocrysts. This conceptual model for basaltic cannibalism is supported by field observations of large-scale erosion upward into the tephra, which is coated by magma flow-back indicating that magma was involved in the thermal etching. While the unique exposure at Thrihnukagigur makes it an exceptional place to investigate basaltic cannibalism, we suggest that it is not limited to this volcanic system. Rather it is a process that likely

  8. Leaching behavior of glass ceramic nuclear waste forms

    International Nuclear Information System (INIS)

    Lokken, R.O.

    1981-11-01

    Glass ceramic waste forms have been investigated as alternatives to borosilicate glasses for the immobilization of high-level radioactive waste at Pacific Northwest Laboratory (PNL). Three glass ceramic systems were investigated, including basalt, celsian, and fresnoite, each containing 20 wt % simulated high-level waste calcine. Static leach tests were performed on seven glass ceramic materials and one parent glass (before recrystallization). Samples were leached at 90 0 C for 3 to 28 days in deionized water and silicate water. The results, expressed in normalized elemental mass loss, (g/m 2 ), show comparable releases from celsian and fresnoite glass ceramics. Basalt glass ceramics demonstrated the lowest normalized elemental losses with a nominal release less than 2 g/m 2 when leached in polypropylene containers. The releases from basalt glass ceramics when leached in silicate water were nearly identical with those in deionized water. The overall leachability of celsian and fresnoite glass ceramics was improved when silicate water was used as the leachant

  9. Subseafloor basalts as fungal habitats

    Directory of Open Access Journals (Sweden)

    M. Ivarsson

    2012-09-01

    Full Text Available The oceanic crust is believed to host the largest potential habitat for microbial life on Earth, yet, still we lack substantial information about the abundance, diversity, and consequence of its biosphere. The last two decades have involved major research accomplishments within this field and a change in view of the ocean crust and its potential to harbour life. Here fossilised fungal colonies in subseafloor basalts are reported from three different seamounts in the Pacific Ocean. The fungal colonies consist of various characteristic structures interpreted as fungal hyphae, fruit bodies and spores. The fungal hyphae are well preserved with morphological characteristics such as hyphal walls, septa, thallic conidiogenesis, and hyphal tips with hyphal vesicles within. The fruit bodies consist of large (∼50–200 µm in diameter body-like structures with a defined outer membrane and an interior filled with calcite. The fruit bodies have at some stage been emptied of their contents of spores and filled by carbonate-forming fluids. A few fruit bodies not filled by calcite and with spores still within support this interpretation. Spore-like structures (ranging from a few µm to ∼20 µm in diameter are also observed outside of the fruit bodies and in some cases concentrated to openings in the membrane of the fruit bodies. The hyphae, fruit bodies and spores are all closely associated with a crust lining the vein walls that probably represent a mineralized biofilm. The results support a fungal presence in deep subseafloor basalts and indicate that such habitats were vital between ∼81 and 48 Ma.

  10. Contributions of vitreous natural analogs to the investigation of long-term nuclear glass behavior; Apports des analogues naturels vitreux a la validation des codes de prediction du comportement a long terme des verres nucleaires

    Energy Technology Data Exchange (ETDEWEB)

    Techer, I

    1999-07-01

    This study assesses the extend of the analogy between the alteration behavior in water and in a moist clay environment of aluminosilicate volcanic glass and alumino-borosilicate nuclear containment glass. Basaltic glass alteration in water initially occurs by hydrolysis processes with an activation energy on the order of 73 kJ.mol{sup -1}. As the reaction progresses, the alteration rate drops by over four orders of magnitude from the initial rate r{sub 0}, The alteration kinetics are not governed by the alteration solution chemistry alone, the glass alteration film appears to have a major role as a diffusion barrier limiting the transfer of reaction species and products. All these aspects highlight the behavioral analogy between basaltic glass and nuclear borosilicate glass in aqueous media. Conversely, the alteration reaction of obsidian-type volcanic glass involves other mechanisms than those governing the dissolution of borosilicate glass. Basaltic glass alteration is also examined in the presence of a clay environmental material, in a study of the natural basaltic glass and argillaceous pelites system of the Salagou basin in southern France, in an approach combining mineralogical, chemical and isotopic data to assess the interactions between a basaltic glass and the argillaceous pelites. Laboratory leach test results with basaltic glass and measured data for the Salagou glass in its natural environment are modeled using a code implementing a kinetic law coupling diffusive transfer of dissolved silica with a reaction affinity law. (author)

  11. Recent coarsening of sediments on the southern Yangtze subaqueous delta front: A response to river damming

    Science.gov (United States)

    Yang, H. F.; Yang, S. L.; Meng, Y.; Xu, K. H.; Luo, X. X.; Wu, C. S.; Shi, B. W.

    2018-03-01

    After more than 50,000 dams were built in the Yangtze basin, especially the Three Gorges Dam (TGD) in 2003, the sediment discharge to the East China Sea decreased from 470 Mt/yr before dams to the current level of 140 Mt/yr. The delta sediment's response to this decline has interested many researchers. Based on a dataset of repeated samplings at 44 stations in this study, we compared the surficial sediment grain sizes in the southern Yangtze subaqueous delta front for two periods: pre-TGD (1982) and post-TGD (2012). External factors of the Yangtze River, including water discharge, sediment discharge and suspended sediment grain size, were analysed, as well as wind speed, tidal range and wave height of the coastal ocean. We found that the average median size of the sediments in the delta front coarsened from 8.0 μm in 1982 to 15.4 μm in 2012. This coarsening was accompanied by a decrease of clay components, better sorting and more positive skewness. Moreover, the delta morphology in the study area changed from an overall accretion of 1.0 cm/yr to an erosion of - 0.6 cm/yr. At the same time, the riverine sediment discharge decreased by 70%, and the riverine suspended sediment grain size increased from 8.4 μm to 10.5 μm. The annual wind speed and wave height slightly increased by 2% and 3%, respectively, and the tidal range showed no change trend. Considering the increased wind speed and wave height, there was no evidence that the capability of the China Coastal Current to transport sediment southward has declined in recent years. The sediment coarsening in the Yangtze delta front was thus mainly attributed to the delta's transition from accumulation to erosion which was originally generated by river damming. These findings have important implications for sediment change in many large deltaic systems due to worldwide human impacts.

  12. A Classification of Subaqueous Density Flows Based on Transformations From Proximal to Distal Regions

    Science.gov (United States)

    Hermidas, Navid; Eggenhuisen, Joris; Luthi, Stefan; Silva Jacinto, Ricardo; Toth, Ferenc; Pohl, Florian

    2017-04-01

    Transformations of a subaqueous density flow from proximal to distal regions are investigated. A classification of these transformations based on the state of the free shear and boundary layers and existence of a plug layer during transition from a debris flow to a turbidity current is presented. A connection between the emplaced deposit by the flow and the relevant flow type is drawn through the results obtained from a series of laboratory flume experiments. These were performed using 9%, 15%, and 21% sediment mixture concentrations composed of sand, silt, clay, and tap water, on varying bed slopes of 6°, 8°, and 9.5°, and with discharge rates of 10[m3/h] and 15[m3/h]. Stress-controlled rheometry experiments were performed on the mixtures to obtain apparent viscosity data. A classification was developed based on the imposed flow conditions, where a cohesive flow may fall within one of five distinct flow types: 1) a cohesive plug flow (PF) with a laminar free shear and boundary layers, 2) a top transitional plug flow (TTPF) containing a turbulent free shear layer, a plug layer, and a laminar boundary layer, 3) a complete transitional plug flow (CTPF) consisting of a turbulent free shear and boundary layers and a plug, 4) a transitional turbidity current (TTC) with a turbulent free shear layer and a laminar boundary layer, and, 5) a completely turbulent turbidity current (TC). During the experiments, flow type PF resulted in en masse deposition of a thick uniform ungraded muddy sand mixture, which was emplaced once the yield stress overcame the gravitational forces within the tail region of the flow. Flow type TTPF resulted in deposition of a thin ungraded basal clean sand layer during the run. This layer was covered by a muddy sand deposit from the tail. Flow type TTC did not deposit any sediment during the run. A uniform muddy sand mixture was emplaced by the tail of the flow. Flow type TC resulted in deposition of poorly sorted massive bottom sand layer. This

  13. Tachylyte in Cenozoic basaltic lavas from the Czech Republic and Iceland: contrasting compositional trends

    Czech Academy of Sciences Publication Activity Database

    Ulrych, Jaromír; Krmíček, Lukáš; Teschner, C.; Řanda, Zdeněk; Skála, Roman; Jonášová, Šárka; Fediuk, F.; Adamovič, Jiří; Pokorný, R.

    2017-01-01

    Roč. 111, č. 5 (2017), s. 761-775 ISSN 0930-0708 Institutional support: RVO:67985831 ; RVO:61389005 Keywords : basaltic glass * chemical composition * major genetic types * mineral composition * rift-related volcanites * Sr-Nd isotopes Subject RIV: DB - Geology ; Mineralogy; CB - Analytical Chemistry, Separation (UJF-V) OBOR OECD: Mineralogy; Analytical chemistry (UJF-V) Impact factor: 1.236, year: 2016

  14. Glass sealing

    Energy Technology Data Exchange (ETDEWEB)

    Brow, R.K.; Kovacic, L.; Chambers, R.S. [Sandia National Labs., Albuquerque, NM (United States)

    1996-04-01

    Hernetic glass sealing technologies developed for weapons component applications can be utilized for the design and manufacture of fuel cells. Design and processing of of a seal are optimized through an integrated approach based on glass composition research, finite element analysis, and sealing process definition. Glass sealing procedures are selected to accommodate the limits imposed by glass composition and predicted calculations.

  15. Electrochromic Glasses.

    Science.gov (United States)

    1980-07-31

    this glass and that dipole-dipole correlations contribute to the "ferroelectric-like" character of this amorphous system. The TeO2 -W03 glasses can only...shows the dielectric constant and Fig. I(b) glass from pure TeO2 ot pure WO. In addition, glass the tan 8 of the WO glass as a function of temperature... glasses containing WO, in various glass forming nitworks of LifO-B1O0, Na:O-BzO,, and TeO2 were prepared from reagent grade oxides at 800 C - 9SO C in

  16. Subaqueous hot springs in Köyceğiz Lake, Dalyan Channel and Fethiye-Göcek Bay (SW Turkey): Locations, chemistry and origins

    KAUST Repository

    Avşar, Ö zgü r; Avsar, Ulas; Arslan, Şebnem; Kurtuluş, Bedri; Niedermann, Samuel; Gü leç , Nilgü n

    2017-01-01

    In this study, horizontal temperature measurements along organized grids have been used to detect subaqueous hot springs. The study area, located in the southwest of Turkey and comprised of Köyceğiz Lake, Dalyan Channel and Fethiye-Göcek Bay

  17. Hydrothermal waste package interactions with methane-containing basalt groundwater

    International Nuclear Information System (INIS)

    McGrail, B.P.

    1984-11-01

    Hydrothermal waste package interaction tests with methane-containing synthetic basalt groundwater have shown that in the absence of gamma radiolysis, methane has little influence on the glass dissolution rate. Gamma radiolysis tests at fluxes of 5.5 x 10 5 and 4.4 x 10 4 R/hr showed that methane-saturated groundwater was more reducing than identical experiments where Ar was substituted for CH 4 . Dissolved methane, therefore, may be beneficial to the waste package in limiting the solubility of redox sensitive radionuclides such a 99 Tc. Hydrocarbon polymers known to form under the irradiation conditions of these tests were not produced. The presence of the waste package constituents apparently inhibited the formation of the polymers, however, the mechanism which prevented their formation was not determined

  18. Geologic structure of the eastern mare basins. [lunar basalts

    Science.gov (United States)

    Dehon, R. A.; Waskom, J. D.

    1976-01-01

    The thickness of mare basalts in the eastern maria are estimated and isopachs of the basalts are constructed. Sub-basalt basin floor topography is determined, and correlations of topographic variations of the surface with variations in basalt thickness or basin floor topography are investigated.

  19. The Origin of Noble Gas Isotopic Heterogeneity in Icelandic Basalts

    Science.gov (United States)

    Dixon, E. T.; Honda, M.; McDougall, I.

    2001-01-01

    Two models for generation of heterogeneous He, Ne and Ar isotopic ratios in Icelandic basalts are evaluated using a mixing model and the observed noble gas elemental ratios in Icelandic basalts,Ocean island Basalt (OIBs) and Mid-Ocean Ridge Basalt (MORBs). Additional information is contained in the original extended abstract.

  20. Basalt waste added to Portland cement

    Directory of Open Access Journals (Sweden)

    Thiago Melanda Mendes

    2016-08-01

    Full Text Available Portland cement is widely used as a building material and more than 4.3 billion tons were produced in 2014, with increasing environmental impacts by this industry, mainly through CO2 emissions and consumption of non-removable raw materials. Several by-products have been used as raw materials or fuels to reduce environmental impacts. Basaltic waste collected by filters was employed as a mineral mixture to Portland cement and two fractions were tested. The compression strength of mortars was measured after 7 days and Scanning Electron Microscopy (SEM and Electron Diffraction Scattering (EDS were carried out on Portland cement paste with the basaltic residue. Gains in compression strength were observed for mixtures containing 2.5 wt.% of basaltic residue. Hydration products observed on surface of basaltic particles show the nucleation effect of mineral mixtures. Clinker substitution by mineral mixtures reduces CO2 emission per ton of Portland cement.

  1. Geochemistry of 1.9 Ga MORB- and OIB-like basalts from the Amisk collage, Flin Flon Belt, Canada: Evidence for an intra-oceanic origin

    Science.gov (United States)

    Stern, Richard A.; Syme, Eric C.; Lucas, Stephen B.

    1995-08-01

    Subaqueously-erupted basalts that occur in kilometre-scale allochthons within the 1.9 Ga Flin Flon Belt, Canada, appear to have been generated at oceanic ridges and possibly oceanic plateaus, remote from Archean cratons. The ocean-floor basalts fall into two categories: (1) N-type, resembling N-MORBs and Mariana-type back-arc basin basalts (depleted to flat REE patterns, high Zr/Nb, variable Th/Nb, and initial ɛNd = + 3.3 to + 5.4); (2) E-type, resembling transitional and plume MORBs (slightly enriched REE patterns, lower Zr/Nb, initial ɛNd = +3.1 to +4.5). In the largest and best-studied allochthon, the Elbow-Athapapuskow 'assemblage,' mixing between depleted (N-MORB) and enriched (OIB) sources or melts, coupled with variable addition of a subduction LILE component, can explain the chemical variations in the basalts. Zircon U-Pb dates of 1904 ± Ma for a syn-volcanic diabase sill and 1901 +6/-5 Ma for a gabbro-peridotite cumulate complex demonstrate that crystallization of the 'ocean-floor' basalts overlapped with, in part, eruption of the tectonically juxtaposed 1.90-1.88 Ga arc volcanic rocks. The Elbow-Athapapuskow allochthon is interpreted as back-arc basin crust that developed simultaneously with Flin Flon arc magmatism. Subaerially erupted basalts that chemically resemble tholeiitic OIBs (8-14% MgO, relative HREE depletion, initial ɛ Nd = +2.2 to +3.4) occur in tectonic contact with the Elbow-Athapapuskow assemblage. The OIBs may have been generated by deeper (garnet residue) melting of enriched mantle tapped during extension in the Elbow-Athapapuskow back-arc basin, and were possibly erupted onto a remnant arc. Deeper mantle melting is also indicated by the presence of the LREE-enriched oceanic plateau-like basalts of the Sandy Bay assemblage. The back-arc, 01B, and plateau volcanic assemblages were jux-taposed against ca. 1.9 Ga arc assemblages in a Philippines-like intraoceanic accretionary complex by 1.87 Ga.

  2. Glass consistency and glass performance

    International Nuclear Information System (INIS)

    Plodinec, M.J.; Ramsey, W.G.

    1994-01-01

    Glass produced by the Defense Waste Processing Facility (DWPF) will have to consistently be more durable than a benchmark glass (evaluated using a short-term leach test), with high confidence. The DWPF has developed a Glass Product Control Program to comply with this specification. However, it is not clear what relevance product consistency has on long-term glass performance. In this report, the authors show that DWPF glass, produced in compliance with this specification, can be expected to effectively limit the release of soluble radionuclides to natural environments. However, the release of insoluble radionuclides to the environment will be limited by their solubility, and not glass durability

  3. Colloidal glasses

    Indian Academy of Sciences (India)

    First page Back Continue Last page Overview Graphics. Colloidal glasses. Glassy state is attained when system fails to reach equilibrium due to crowding of constituent particles. In molecular glasses, glassy state is reached by rapidly lowering the temperature. In colloidal glasses, glassy state is reached by increasing the ...

  4. Silicate glasses

    International Nuclear Information System (INIS)

    Lutze, W.

    1988-01-01

    Vitrification of liquid high-level radioactive wastes has received the greatest attention, world-wide, compared to any other HLW solidification process. The waste form is a borosilicate-based glass. The production of phosphate-based glass has been abandoned in the western world. Only in the Soviet Union are phosphate-based glasses still being developed. Vitrification techniques, equipment and processes and their remote operation have been developed and studied for almost thirty years and have reached a high degree of technical maturity. Industrial demonstration of the vitrification process has been in progress since 1978. This chapter is a survey of world-wide research and development efforts in nuclear waste glasses and its production technology. The principal glasses considered are silicate glasses which contain boron, i.e., borosilicate glasses

  5. Iron metal production in silicate melts through the direct reduction of Fe/II/ by Ti/III/, Cr/II/, and Eu/II/. [in lunar basalts

    Science.gov (United States)

    Schreiber, H. D.; Balazs, G. B.; Shaffer, A. P.; Jamison, P. L.

    1982-01-01

    The production of metallic iron in silicate melts by chemical reactions of Ti(3+), Cr(2+), and Eu(2+) with Fe(2+) is demonstrated under experimental conditions in a simplified basaltic liquid. These reactions form a basis for interpreting the role of isochemical valency exchange models in explanations for the reduced nature of lunar basalts. The redox couples are individually investigated in the silicate melt to ascertain reference redox ratios that are independent of mutual interactions. These studies also provide calibrations of spectral absorptions of the Fe(2+) and Ti(2+) species in these glasses. Subsequent spectrophotometric analyses of Fe(2+) and Ti(2+) in glasses doped with both iron and titanium and of Fe(2+) in glasses doped with either iron and chromium or iron and europium ascertain the degree of mutual interactions in these dual-doped glasses.

  6. Isotopic signature of Madeira basaltic magmatism

    International Nuclear Information System (INIS)

    Kogarko, L.N.; Karpenko, S.F.; Bibikova, E.V.; Mato, Zh.

    2000-01-01

    Chemical composition of the basalts of Madeira Island is studied. To assess the isotopic sources of magmatism the Pb-Sr, Sm-Nd, U-Th-Pb systems were investigated in a number of basalts. It is shown that the island's rocks are characterized by the mostly deplet sources in relation to Pb-Sr and Sm-Nd systems ( 87 Sr/ 86 Sr - 0.70282-0.70292, 143 Nd/ 144 Nd - 0.52303-0.51314). Isotopic composition of lead testifies that the magmatism reservoir is some enriched. It is concluded that the magmatism of Madeira Island is a new example of world ocean island's volcanism [ru

  7. Antifriction basalt-plastics based on polypropylene

    Science.gov (United States)

    Bashtannik, P. I.; Ovcharenko, V. G.

    1997-05-01

    A study is made of the dependence of the mechanical and friction-engineering properties of polypropylene reinforced with basalt fibers on the viscosity of the polymer matrix. It is established that the main factors that determine the mechanical properties of the plastics are the quality of impregnation of the fibers by the binder and the residual length of the reinforcing filler in the composite after extrusion and injection molding. The material that was developed has a low friction coefficient and low rate of wear within a relatively brood range of friction conditions. The basalt-plastics can be used in the rubbing parts of machines and mechanisms subjected to dry friction.

  8. Immiscible iron- and silica-rich melt in basalt petrogenesis documented in the Skaergaard intrusion

    DEFF Research Database (Denmark)

    Jakobsen, Jakob Kløve; Veksler, Ilya; Tegner, Christian

    2005-01-01

    colored type contains 30.9 6 4.2 wt% FeOt and 40.7 6 3.6 wt% SiO2, whereas the light colored type contains 8.6 6 5.9 wt% FeOt and 65.6 6 7.3 wt% SiO2. Similar light colored melt inclusions in olivine and fine grained dark and light colored interstitial pockets also give evidence of crystallization from......Silicate liquid immiscibility in basalt petrogenesis is a contentious issue. Immiscible iron and silica-rich liquids were reported in melt inclusions of lunar basalt and in groundmass glasses of terrestrial volcanics. In fully crystallized plutonic rocks, however, silicate liquid immiscibility has...

  9. Evaluation of thermobarometry for spinel lherzolite fragments in alkali basalts

    Science.gov (United States)

    Ozawa, Kazuhito; Youbi, Nasrrddine; Boumehdi, Moulay Ahmed; McKenzie, Dan; Nagahara, Hiroko

    2017-04-01

    various method of estimation of ascent rate of mantle fragments in kimberlite and alkali basalt; one based on fluid dynamics of transportation of entrapped fragments by giving the maximum size and viscosity of magma as a minimum estimate (Spera, 1980) and the other by coupling depth of fragment residence before the entrapment in a magma and time scale of heating by the magma. The depth of entrapment, however, is the least known parameter for spinel lherzolite. Because of nearly adiabatic ascent of magmas loaded with solid fragments, all the fragments underwent the same heating and decompression history with difference in entrapment depth and thus heating duration, from which the depth of their residence just before the extraction may be estimated if ascent rate is known. Therefore, extent of chemical and textural modification induced by heating and decompression may provide independent test for pressure estimation. We have used several reactions for this purpose: (1) Mg-Fe exchange reaction between spinel and olivine (Ozawa, 1983; 1984), (2) Ca zoning in olivine (Takahashi, 1980), (3) partial dissolution of clinopyroxene, (4) partial dissolution of spinel, and (5) formation of melt frozen as glass, which is related to (3) and (4). The depth of melt generation is constrained to be deeper than 70km by modeling the trace element compositions of the host magmas using the methods of McKenzie and O'Nions (1991) and data from El Azzouzi et al. (2010). The host magmas can be produced by melting the convecting upper mantle without requirement of any input from the continental lithosphere. This is consistent with the positive gravity anomalies in the NW Africa showing shallow upwelling in this region allowing decompressional melting owing to the thinner lithosphere in the Middle Atlas.

  10. Recycle Glass in Foam Glass Production

    DEFF Research Database (Denmark)

    Petersen, Rasmus Rosenlund; König, Jakob; Yue, Yuanzheng

    The foam glass industry turn recycle glass into heat insulating building materials. The foaming process is relative insensitive to impurities in the recycle glass. It is therefore considered to play an important role in future glass recycling. We show and discuss trends of use of recycled glasses...... in foam glass industry and the supply sources and capacity of recycle glass....

  11. Increased corrosion resistance of basalt reinforced cement compositions with nanosilica

    Directory of Open Access Journals (Sweden)

    URKHANOVA Larisa Alekseevna

    2014-08-01

    Full Text Available Disperse fiber reinforcement is used to improve deformation and shrinkage characteristics, flexural strength of concrete. Basalt roving and thin staple fiber are often used as mineral fibers. The paper considers the problems of using thin basalt fiber produced by centrifugal-blow method. Evaluation of the corrosion resistance of basalt fiber as part of the cement matrix was performed. Nanodispersed silica produced by electron beam accelerator was used to increase corrosion resistance of basalt fiber.

  12. Investigation of Basalt Woven Fabrics for Military Applications

    Science.gov (United States)

    2011-11-01

    investigates the use of basalt fibers in a composite along with SC-15 epoxy resin for ballistic protection. Basalt fibers are not known as a ballistic...material but rather as a structural one. Even though basalt fibers are not expected to outperform some of the higher ballistic performing materials...such as the aramid and polyethylene fibers ; however, due to the lower manufacturing costs, basalt fibers are an interesting alternative. The objective

  13. Pressure grouting of fractured basalt flows

    International Nuclear Information System (INIS)

    Shaw, P.; Weidner, J.; Phillips, S.; Alexander, J.

    1996-04-01

    This report describes a field trial of pressure grouting in basalt and the results of subsequent coring and permeability measurement activities. The objective was to show that the hydraulic conductivity of fractured basalt bedrock can be significantly reduced by pressure injection of cementitious materials. The effectiveness of the pressure grout procedure was evaluated by measuring the change in the hydraulic conductivity of the bedrock. The extent of grout penetration was established by analyzing postgrout injection drilling chips for the presence of a tracer in the grout and also by examining cores of the treated basalt. Downhole radar mapping was used to establish major lava flow patterns and follow water movement during a surface infiltration test. A site called Box Canyon, which is located northwest of the INEL, was chosen for this study due to the similarity of this surface outcrop geology to that of the underlying bedrock fracture system found at the Radioactive Waste Management Complex. This study showed that hydraulic conductivity of basalt can be reduced through pressure grouting of cementitious material

  14. Site identification presentation: Basalt Waste Isolation Project

    International Nuclear Information System (INIS)

    1979-11-01

    The final step in the site identification process for the Basalt Waste Isolation Project is described. The candidate sites are identified. The site identification methodology is presented. The general objectives which must be met in selecting the final site are listed. Considerations used in the screening process are also listed. Summary tables of the guidelines used are included

  15. Giant Plagioclase Basalts, eruption rate versus time

    Indian Academy of Sciences (India)

    R.Narasimhan(krishtel emaging) 1461 1996 Oct 15 13:05:22

    I found the GPB lavas to be very interest- ing because in some ... by Venkatesan et al (1993) and thus in a way validates my approach. ... and age calculation of lavas from phenocrysts. Keywords. Deccan Trap; Giant Plagioclase Basalts; eruption duration. Proc. Indian Acad. Sci. (Earth Planet. Sci.), 111, No. 4, December ...

  16. Pressure grouting of fractured basalt flows

    Energy Technology Data Exchange (ETDEWEB)

    Shaw, P.; Weidner, J.; Phillips, S.; Alexander, J.

    1996-04-01

    This report describes a field trial of pressure grouting in basalt and the results of subsequent coring and permeability measurement activities. The objective was to show that the hydraulic conductivity of fractured basalt bedrock can be significantly reduced by pressure injection of cementitious materials. The effectiveness of the pressure grout procedure was evaluated by measuring the change in the hydraulic conductivity of the bedrock. The extent of grout penetration was established by analyzing postgrout injection drilling chips for the presence of a tracer in the grout and also by examining cores of the treated basalt. Downhole radar mapping was used to establish major lava flow patterns and follow water movement during a surface infiltration test. A site called Box Canyon, which is located northwest of the INEL, was chosen for this study due to the similarity of this surface outcrop geology to that of the underlying bedrock fracture system found at the Radioactive Waste Management Complex. This study showed that hydraulic conductivity of basalt can be reduced through pressure grouting of cementitious material.

  17. Petrography of basalts from the Carlsberg ridge

    Digital Repository Service at National Institute of Oceanography (India)

    Banerjee, R.; Iyer, S.D.

    Petrographic characteristics of basalts collected from a segment of the Carlsberg Ridge (lat. 3 degrees 35'N to 3 degrees 41'N; long. 64 degrees 05'E to 64 degrees 09'E) show typical pillow lava zonations with variable concentrations of plagioclase...

  18. Effects of Basalt Fibres on Mechanical Properties of Concrete

    Directory of Open Access Journals (Sweden)

    El-Gelani A. M.

    2018-01-01

    Full Text Available This paper presents the results of an experimental program carried out to investigate the effects of Basalt Fibre Reinforced Polymers (BFRP on some fundamental mechanical properties of concrete. Basalt fibres are formed by heating crushed basalt rocks and funnelling the molten basalt through a spinneret to form basalt filaments. This type of fibres have not been widely used till recently. Two commercially available chopped basalt fibres products with different aspect ratios were investigated, which are dry basalt (GeoTech Fibre and basalt pre-soaked in an epoxy resin (GeoTech Matrix .The experimental work included compression tests on 96 cylinders made of multiple batches of concrete with varying amounts of basalt fibre additives of the two mentioned types, along with control batches containing no fibres. Furthermore, flexural tests on 24 prisms were carries out to measure the modulus of rupture, in addition to 30 prisms for average residual strength test. Results of the research indicated that use of basalt fibres has insignificant effects on compressive strength of plain concrete, where the increase in strength did not exceed about 5%. On the other hand, results suggest that the use of basalt fibres may increase the compressive strength of concrete containing fly as up top 40%. The rupture strength was increased also by 8% to 28% depending on mix and fibre types and contents. Finally, there was no clear correlation between the average residual strength and ratios of basalt fibres mixed with the different concrete batches.

  19. Geochemical characteristics of the Jos-Plateau Basalts, North ...

    African Journals Online (AJOL)

    The Jos Plateau basalts, present Zr/Nb ratios (2.4-3.0) comparable to those of the alkali basalts of the lower Benue valley, and of the Cameroon volcanic line, suggesting that they were possibly derived from the same mantle source. Keywords: Jos Plateau, alkali basalt, mantle, partial melting, incompatible elements.

  20. Subaqueous hot springs in Köyceğiz Lake, Dalyan Channel and Fethiye-Göcek Bay (SW Turkey): Locations, chemistry and origins

    Science.gov (United States)

    Avşar, Özgür; Avşar, Ulaş; Arslan, Şebnem; Kurtuluş, Bedri; Niedermann, Samuel; Güleç, Nilgün

    2017-10-01

    In this study, horizontal temperature measurements along organized grids have been used to detect subaqueous hot springs. The study area, located in the southwest of Turkey and comprised of Köyceğiz Lake, Dalyan Channel and Fethiye-Göcek Bay, was scanned by measuring temperatures horizontally, 2-3 m above the bottom of the lake or sea. After analyzing the temperature data along the grids, the locations with anomalous temperature values were detected, and divers headed here for further verification. Accordingly, among these anomalies, the divers confirmed seven of them as subaqueous hot springs. Three of these hot springs are located in the Köyceğiz Lake, three of them are located in the Dalyan Channel and one hot spring is located in the Fethiye-Göcek Bay. At the locations where temperature anomalies were detected, the divers collected samples directly from the subaqueous hot spring using a syringe-type sampler. We evaluated these water samples together with samples collected from hot and cold springs on land and from local rivers, lakes and the sea, with an aim to generate a conceptual hydrogeochemical model of the geothermal system in the study area. This model predicts that rainwater precipitating in the highlands percolates through fractures and faults into the deeper parts of the Earth's crust, here it is heated and ascends through the sea bottom via buried faults. Pervious carbonate nappes that are underlain and overlain by impervious rocks create a confined aquifer. The southern boundary of the Carbonate-Marmaris nappes is buried under alluvium and/or sea/lake water bodies and this phenomenon determines whether hot springs occur on land or subaqueous. The chemical and isotopic properties of the hot springs point to seawater mixing at deep levels. Thus, the mixing most probably occurs while the water is ascending through the faults and fractures. The gas geochemistry results reveal that the lowest mantle He contributions occur in the samples from K

  1. Subaqueous hot springs in Köyceğiz Lake, Dalyan Channel and Fethiye-Göcek Bay (SW Turkey): Locations, chemistry and origins

    KAUST Repository

    Avşar, Özgür

    2017-08-07

    In this study, horizontal temperature measurements along organized grids have been used to detect subaqueous hot springs. The study area, located in the southwest of Turkey and comprised of Köyceğiz Lake, Dalyan Channel and Fethiye-Göcek Bay, was scanned by measuring temperatures horizontally, 2–3m above the bottom of the lake or sea. After analyzing the temperature data along the grids, the locations with anomalous temperature values were detected, and divers headed here for further verification. Accordingly, among these anomalies, the divers confirmed seven of them as subaqueous hot springs. Three of these hot springs are located in the Köyceğiz Lake, three of them are located in the Dalyan Channel and one hot spring is located in the Fethiye-Göcek Bay. At the locations where temperature anomalies were detected, the divers collected samples directly from the subaqueous hot spring using a syringe-type sampler. We evaluated these water samples together with samples collected from hot and cold springs on land and from local rivers, lakes and the sea, with an aim to generate a conceptual hydrogeochemical model of the geothermal system in the study area. This model predicts that rainwater precipitating in the highlands percolates through fractures and faults into the deeper parts of the Earth\\'s crust, here it is heated and ascends through the sea bottom via buried faults. Pervious carbonate nappes that are underlain and overlain by impervious rocks create a confined aquifer. The southern boundary of the Carbonate-Marmaris nappes is buried under alluvium and/or sea/lake water bodies and this phenomenon determines whether hot springs occur on land or subaqueous. The chemical and isotopic properties of the hot springs point to seawater mixing at deep levels. Thus, the mixing most probably occurs while the water is ascending through the faults and fractures. The gas geochemistry results reveal that the lowest mantle He contributions occur in the samples from K

  2. Parental magmas of Mare Fecunditatis - Evidence from pristine glasses

    International Nuclear Information System (INIS)

    Jin, Y.; Taylor, L.A.

    1990-01-01

    Results are presented on the petrography and electron microprobe analyses of 14 discrete glass beads from the Luna 16 core sample (21036,15) from Mare Fecunditatis regolith, that were previously characterized as representing pristine glasses. Compared to Apollo pristine glasses analyzed by Delano (1986), the Luna 16 pristine glasses have higher CaO and Al2O3 contents but lower MgO and Ni. On the basis of their contents of MgO, FeO, Al2O3, and CaO, these pristine glasses could be divided into two groups, A and B. It is suggested that at least two parental magmas are needed to explain the chemical variations among these glasses. The Group B glasses appear to represent primitive parental magma that evolved by olivine fractionation to the compositions of the Luna 16 aluminous mare basalts, whereas the Group A volcanic glasses may represent an unusual new basalt magma type that contains a high plagioclase component. 14 refs

  3. Cosmos & Glass

    DEFF Research Database (Denmark)

    Beim, Anne

    1996-01-01

    The article unfolds the architectural visions of glass by Bruno Taut. It refers to inspirations by Paul Sheerbart and litterature and the Crystal Chain, also it analyses the tectonic univers that can be found in the glass pavillion for the Werkbund exposition in Cologne....

  4. Glass Glimpsed

    DEFF Research Database (Denmark)

    Lock, Charles

    2015-01-01

    Glass in poetry as it reflects the viewer and as its power of reflection are both reduced and enhanced by technology.......Glass in poetry as it reflects the viewer and as its power of reflection are both reduced and enhanced by technology....

  5. Spin glasses

    CERN Document Server

    Bovier, Anton

    2007-01-01

    Spin glass theory is going through a stunning period of progress while finding exciting new applications in areas beyond theoretical physics, in particular in combinatorics and computer science. This collection of state-of-the-art review papers written by leading experts in the field covers the topic from a wide variety of angles. The topics covered are mean field spin glasses, including a pedagogical account of Talagrand's proof of the Parisi solution, short range spin glasses, emphasizing the open problem of the relevance of the mean-field theory for lattice models, and the dynamics of spin glasses, in particular the problem of ageing in mean field models. The book will serve as a concise introduction to the state of the art of spin glass theory, usefull to both graduate students and young researchers, as well as to anyone curious to know what is going on in this exciting area of mathematical physics.

  6. Use of natural and archaeological analogs to validate long - term behaviour of HLW glass in geological disposal conditions

    International Nuclear Information System (INIS)

    Gin, S.; Verney-Carron, A.; Libourel, G.

    2008-01-01

    Some old basaltic and Roman glasses have been studied in order to validate the predictive models developed for assessing the long-term behaviour of nuclear glass in geological repository conditions. Leaching behaviour of basaltic glass altered in both laboratory and natural environment conditions allows to validate the key mechanisms that control glass dissolution kinetics and the order of magnitude of glass packages lifetime In a stable clayey formation (French reference concept for a geological disposal of high level waste). The study of Roman glass blocks (with the same geometry as nuclear glass package) altered during 1800 years in a marine environment gives new insight on the basic mechanisms involved in confined media (fractures and small cracks). Results show the importance of the coupling between transport of reactive species and chemical reactions. This study, still in progress, would allow to validate the modelling of such a complex system. (author)

  7. Basaltic substrate composition affects microbial community development and acts as a source of nutrients in the deep biosphere

    Science.gov (United States)

    Bailey, B.; Sudek, L.; Templeton, A.; Staudigel, H.; Tebo, B.; Moyer, C.; Davis, R.

    2006-12-01

    Studies of the oceanic crust over the past decade have revealed that in spite of the oligotrophic nature of this environment, a diverse biosphere is present in the upper 1 km of basaltic crust. The key energy source in this setting may be the high content of transistion metals (Fe, Mn) found in the basaltic glass, but in order to discover the role of Fe and Mn in the deep biosphere, we must first determine which microbes are present and how they attain the necessary metabolites for proliferation. Our work contributes to both questions through the use of molecular microbiology techniques and the exposure of specifically designed substrates on the ocean floor. Loihi Seamount off the southeast coast of the Big Island of Hawai'i provides a unique laboratory for the study of distribution and population of microbial communities associated with iron rich environments on the ocean floor. Iron oxide flocculent material (floc) dominates the direct and diffuse hydrothermal venting areas on Loihi which makes it a prime target for understanding the role of iron in biological systems in the deep biosphere. We collected iron oxide floc and basaltic glass from pillow basalts around several hydrothermal vents on the crater rim, within the pit crater Pele's Pit, and from deep off of the southern rift zone of Loihi using the HURL PISCES IV/V submersibles. We also deployed basaltic glass sand amended with various nutrients (phosphate, oxidized and reduced iron, manganese) and recovered them in subsequent years to determine how substrate composition affects community structure. We extracted DNA from both rock and iron flocs and used t-RFLP to obtain a genetic fingerprint of the microbial communities associated with each substrate. From olivine and tholeiitic basalt enrichments, it appears that substrate composition strongly influences microbial colonization and subsequent community development even when deployed in the same conditions. Culturing efforts have yielded several iron

  8. Study of the alteration of the Vatnajokull volcanic glasses (Iceland). Mechanisms and situation at low temperature

    International Nuclear Information System (INIS)

    Le Gal, X.

    1999-01-01

    Volcanic glasses have been considered for several years to be good analogues of nuclear glasses. The main objective of this study is to look at the long term behaviour of natural glasses subjected to meteoric alteration. Basaltic hyalo-clasts, essentially from Hengill, Husafell and Vatnajokull, in Iceland, were studied. These glasses, ranging from 0.09 to 4 My in age, and altered by meteoric water, are surrounded by alteration layers. In the youngest samples ( 18 O measurements indicate, major modification of the initial glass structure during gel formation. Chemical budgets show that elements are not completely retained by alteration products in such geological environments. (author)

  9. Influence of microorganisms on the alteration of glasses

    International Nuclear Information System (INIS)

    Besnainou, B.; Libert, M.F.

    1997-01-01

    Under specific conditions, microorganisms may enhance the alteration process of basaltic glass. However bacterial activity in the near field of a glass container would be possible only in environmental conditions provide nutrients and energetic substrates for bacterial growth. Depending of these conditions, microorganisms can: - modify the pH or the medium, - consume or produce soluble organic acids. To qualify the long term behaviour of glass, in presence of microorganisms, a qualitative and quantitative estimation of microbial activity potentialities and their consequences is needed. This must be achieved in studying the availability of the chemical species in the environment. (authors)

  10. Basalts of the Khodzhirbulak Suite and Assessment their Feasibility for Basalt Fiber (Surkhantau Mountains, Southwestern Shoots of the Hissar Ridge

    Directory of Open Access Journals (Sweden)

    N. M. Khakberdyev

    2017-06-01

    Full Text Available The results of preliminary assessment of basalt of the Khodzhirbulakskoy Suite of Surkhantau Mountains for the basalt fiber production are presented. According to petrographic study, the rocks are described as basalts of amygdaloidal structure. On the base of content of the amount of glassy form and nodular calcite, three groups of basalts were identified. The inverse relationship between the bulk content of the volcanic rock and the content of calcite: the greater volume of volcanic rocks, the less content of calcite, and vice versa. The basalt material demonstrates average pH module of 3.52.

  11. Circumventing shallow air contamination in Mid Ocean Ridge Basalts

    Science.gov (United States)

    Mukhopadhyay, Sujoy; Parai, Rita; Tucker, Jonathan; Middleton, Jennifer; Langmuir, Charles

    2016-04-01

    Noble gases in mantle-derived basalts provide a rich portrait of mantle degassing and surface-interior volatile exchange. However, the ubiquity of shallow-level air contamination frequently obscures the mantle noble gas signal. In a majority of samples, shallow air contamination dominates the noble gas budget. As a result, reconstructing the variability in heavy noble gas mantle source compositions and inferring the history of deep recycling of atmospheric noble gases is difficult. For example, in the gas-rich popping rock 2ΠD43, 129Xe/130Xe ratios reach 7.7±0.23 in individual step-crushes, but the bulk composition of the sample is close to air (129Xe/130Xe of 6.7). Here, we present results from experiments designed to elucidate the source of shallow air contamination in MORBs. Step-crushes were carried out to measure He, Ne, Ar and Xe isotopic compositions on two aliquots of a depleted popping glass that was dredged from between the Kane and Atlantis Fracture Zones of the Mid-Atlantic Ridge in May 2012. One aliquot was sealed in ultrapure N2 after dredge retrieval, while the other aliquot was left exposed to air for 3.5 years. The bulk 20Ne/22Ne and 129Xe/130Xe ratios measured in the aliquot bottled in ultrapure N2 are 12.3 and 7.6, respectively, and are nearly identical to the estimated mantle source values. On the other hand, step crushes in the aliquot left exposed to air for several years show Ne isotopic compositions that are shifted towards air, with a bulk 20Ne/22Ne of 11.5; the bulk 129Xe/130Xe, however, was close to 7.6. These results indicate that lighter noble gases exchange more efficiently between the bubbles trapped in basalt glass and air, suggesting a diffusive or kinetic mechanism for the incorporation of the shallow air contamination. Importantly, in Ne-Ar or Ar-Xe space, step-crushes from the bottled aliquot display a trend that can be easily fit with a simple two-component hyperbolic mixing between mantle and atmosphere noble gases. Step

  12. Technical program plan, Basalt Waste Isolation Project

    International Nuclear Information System (INIS)

    1979-12-01

    The Basalt Waste Isolation Project (BWIP) program as administered by the DOE's Richland Operations Office and Rockwell Hanford Operations is described. The objectives, scope and scientific technologies are discussed. The work breakdown structure of the project includes: project management and support, systems integration, geosciences, hydrology, engineered barriers, test facility design and construction, engineering testing, repository studies, and schedules. The budget of the program including operating and capital cost control is also included

  13. Gamma radiolysis effects on basalt groundwater

    International Nuclear Information System (INIS)

    Gray, W.J.

    1983-10-01

    Gamma radiolysis of basalt groundwater containing 700 ppM methane produces a milky liquid that is a suspension of fine particles of a high molecular weight hydrocarbon somewhat like polyethylene. The ability of these polymers to chelate with, or otherwise sorb, metal ions from aqueous solution was measured using Cu +2 as a representative cation. Values in the range 0.3 to 0.8 millimoles of Cu per liter of solution were found. 5 references, 2 figures, 2 tables

  14. Off-gassing induced tracer release from molten basalt pools

    International Nuclear Information System (INIS)

    Cronenberg, A.W.; Callow, R.A.

    1994-01-01

    Two in situ vitrification (ISV) field tests were conducted at the Idaho National Engineering Laboratory (INEL) during the summer of 1990 to assess ISV suitability for long-term stabilization of buried waste that contains transuranic and other radionuclide contaminants. The ISV process uses electrical resistance heating to melt buried waste and soil in place, which upon cooldown and resolidification fixes the waste into a vitrified (glass-like) form. In these two ISV field tests, small quantities of rare-earth oxides (tracers DY 2 O 3 , Yb 2 O 3 , and Tb 4 O 7 ) were placed in the test pits to simulate the presence of plutonium oxides and assess plutonium retention/release behavior. The analysis presented in this report indicates that dissolution of tracer oxides into basaltic melts can be expected with subsequent tracer molecular or microparticle carry-off by escaping gas bubbles, which is similar to adsorptive bubble separation and ion flotation processes employed in the chemical industry to separate dilute heavy species from liquids under gas sparging conditions. Gaseous bubble escape from the melt surface and associated aerosolization is believed to be responsible for small quantities of tracer ejection from the melt surface to the cover hood and off-gas collection system. Methods of controlling off-gassing during ISV would be expected to improve the overall retention of such heavy oxide contaminants during melting/vitrification of buried waste

  15. Possible solar noble-gas component in Hawaiian basalts

    Energy Technology Data Exchange (ETDEWEB)

    Honda, Masahiko; McDougall, I.; Patterson, D.B.; Doulgeris, A. (Australian National Univ., Canberra (Australia). Research School of Earth Sciences); Clague, D.A. (Geological Survey, Menlo Park, CA (USA))

    1991-01-10

    The noble-gas elemental and isotopic composition in the Earth is significantly different from that of the present atmosphere, and provides an important clue to the origin and history of the Earth and its atmosphere. Possible candidates for the noble-gas composition of the primordial Earth include a solar-like component, a planetary-like component (as observed in primitive meteorites) and a component similar in composition to the present atmosphere. In an attempt to identify the contributions of such components, we have measured isotope ratios of helium and neon in fresh basaltic glasses dredged from Loihi seamount and the East Rift Zone of Kilauea. We find a systematic enrichment in {sup 20}Ne and {sup 21}Ne relative to {sup 22}Ne, compared with atmospheric neon. The helium and neon isotope signatures observed in our samples can be explained by mixing of solar, present atmospheric, radiogenic and nucleogenic components. These data suggest that the noble-gas isotopic composition of the mantle source of the Hawaiian plume is different from that of the present atmosphere, and that it includes a significant solar-like component. We infer that this component was acquired during the formation of the Earth. (author).

  16. Iron isotopic systematics of oceanic basalts

    Science.gov (United States)

    Teng, Fang-Zhen; Dauphas, Nicolas; Huang, Shichun; Marty, Bernard

    2013-04-01

    The iron isotopic compositions of 93 well-characterized basalts from geochemically and geologically diverse mid-ocean ridge segments, oceanic islands and back arc basins were measured. Forty-three MORBs have homogeneous Fe isotopic composition, with δ56Fe ranging from +0.07‰ to +0.14‰ and an average of +0.105 ± 0.006‰ (2SD/√n, n = 43, MSWD = 1.9). Three back arc basin basalts have similar δ56Fe to MORBs. By contrast, OIBs are slightly heterogeneous with δ56Fe ranging from +0.05‰ to +0.14‰ in samples from Koolau and Loihi, Hawaii, and from +0.09‰ to +0.18‰ in samples from the Society Islands and Cook-Austral chain, French Polynesia. Overall, oceanic basalts are isotopically heavier than mantle peridotite and pyroxenite xenoliths, reflecting Fe isotope fractionation during partial melting of the mantle. Iron isotopic variations in OIBs mainly reflect Fe isotope fractionation during fractional crystallization of olivine and pyroxene, enhanced by source heterogeneity in Koolau samples.

  17. AEGIS methodology demonstration: case example in basalt

    International Nuclear Information System (INIS)

    Dove, F.H.

    1982-01-01

    The AEGIS technology has been successfully demonstrated. For the same data, similar unpublished results have been obtained by RHO and INTERA Environmental Consultants, Inc. for contaminant transport. In addition to establishing the utility of computer codes and assessment methodology, the AEGIS technology demonstration in basalt has also produced some practical guidance for future field data gathering programs. The results of this basalt demonstration indicate that the geohydrologic systems separating the nuclear waste from the natural biosphere discharge site mitigate the consequences of the postulated fault intersection event. This analysis suggests that the basalt system satisfies the 1000- and 10,000-yr proposed standards for release to the accessible environment (limited release of 129 I and 14 C). The reader should be cautioned, however, that the results are valid only for one particular set of parameters and one postulated release scenario. A complete sensitivity analysis must be performed to evaluate the range of effects that might be observed under different release conditions and for the different range in parameters

  18. Hydrologic modeling of the Columbia Plateau basalts

    International Nuclear Information System (INIS)

    Dove, F.H.; Cole, C.R.; Bond, F.W.; Zimmerman, D.A.

    1982-09-01

    The Office of Nuclear Waste Isolation (ONWI) directed the Assessment of Effectiveness of Geologic Isolation Systems (AEGIS) Program to conduct a technology demonstration of current performance assessment techniques for the Department of Energy (DOE) as applied to a nuclear waste repository in the Columbia Plateau Basalts. Hypothetical repository coordinates were selected for an actual geographical setting on the Hanford Reservation in the state of Washington. Published hydrologic and geologic data used in the analyses were gathered in 1979 or earlier. The hydrologic simulation was divided into three major parts: (1) aquifer recharge calculations, (2) a regional hydrologic model, and (3) a local hydrologic model of the Pasco Basin. The presentation discusses the regional model. An estimate of the amount of water transmitted through the groundwater system was required to bound the transmissivity values and to estimate the transmissivity distributions for the deeper basalts. The multiple layer two-dimensional Variable Thickness Transient (VTT) code was selected as appropriate for the amount of data available and for the conditions existing in the regional systems. This model uses a finite difference formulation to represent the partial differential flow equation. The regional study area as defined for the VTT model was divided into 55 by 55 square pattern with each grid 5 kilometers on a side. The regional system was modeled as a held potential surface layer and two underlying basalt layers. The regional model established the boundary conditions for the hydrologic model the Pasco Basin

  19. GLASS BOX

    National Research Council Canada - National Science Library

    Curtis, Laura

    2008-01-01

    The goals of this effort were to develop Glass Box capabilities to allow for the capturing of analyst activities and the associated data resources, track and log the results of automated processing...

  20. Giant Subaqueous Pyroclastic-Flow Deposits Revealed: Sedimentological Revision of the Holocene Outcrops of Izu-Oshima Island, Japan

    Science.gov (United States)

    Hemmi, R.; Yoshida, S.; Nemoto, Y.; Kotake, N.

    2010-12-01

    The early-to-middle Holocene outcrops of Izu-Oshima island, 100 km SSW of Tokyo, comprise sand- to gravel-size pyroclasts, and exhibit undulating layered structures, with each wavelet typically measuring 5-10 m high. These outcrops were traditionally interpreted as exemplary subaerial "ash-fall" deposits in volcanology textbooks (e.g. Schmincke 2006). Our detailed sedimentological analyses, however, have revealed that it is of pyroclastic density-current origin, the majority of which formed in shallow-marine settings. The present study focuses on the outcrops along the western coast of the Island, where the three-dimensional architecture of the outcrops is superbly exposed, and the existing archaeological framework provides a reliable chronostratigraphic control. The outcrops contain abundant compound bedforms, where small bedforms (dunes/antidunes) occur within the larger bedforms. The compound bedforms exhibit four-fold hierarchy (ranks 1 to 4), and bedforms for each scale display dominantly upstream-accreting geometry. The largest scale (Rank 1) of these bedforms show wavy parallel-bedding geometry (each wavelet typically measuring 5-10 m high and 50-100 m wide). We interpreted the large-scale architecture as sediment waves (gigantic antidunes) similar to the one reported from the shallow-marine deposits associated with AD 79 Mt. Vesuvius eruptions (Milia et al. 2008). Moreover, we have identified crustacean burrows and other trace fossils indicative of a nearshore shallow-marine environment. The pervasive occurrence of these fossils throughout the outcrops and abundant water-escape structures also suggests their subaqueous origin. On the other hand, evidence of subaerial deposition (e.g., paleosols and rootlets) or subaerial reworking (e.g., lahar) is absent, except for some spots on several regional unconformities that divide 10’s-m-thick sediment-wave deposits. On some of these unconformities, ribbon- to fan-shaped lava and/or ancient human-dwelling sites

  1. Making rhyolite in a basalt crucible

    Science.gov (United States)

    Eichelberger, John

    2016-04-01

    Iceland has long attracted the attention of those concerned with the origin of rhyolitic magmas and indeed of granitic continental crust, because it presents no alternative for such magmas other than deriving them from a basaltic source. Hydrothermally altered basalt has been identified as the progenitor. The fact that rhyolite erupts as pure liquid requires a process of melt-crustal separation that is highly efficient despite the high viscosity of rhyolite melt. Volcanoes in Iceland are foci of basaltic magma injection along the divergent plate boundary. Repeated injection produces remelting, digestion, and sometimes expulsion or lateral withdrawal of material resulting in a caldera, a "crucible" holding down-dropped and interlayered lava flows, tephras, and injected sills. Once melting of this charge begins, a great deal of heat is absorbed in the phase change. Just 1% change in crystallinity per degree gives a melt-present body an effective heat capacity >5 times the subsolidus case. Temperature is thus buffered at the solidus and melt composition at rhyolite. Basalt inputs are episodic ("fires") so likely the resulting generation of rhyolite by melting is too. If frequent enough to offset cooling between events, rhyolite melt extractions will accumulate as a rhyolite magma reservoir rather than as discrete crystallized sills. Evidently, such magma bodies can survive multiple firings without themselves erupting, as the 1875 eruption of Askja Caldera of 0.3 km3 of rhyolite equilibrated at 2-km depth without previous leakage over a ten-millennium period and the surprise discovery of rhyolite magma at 2-km depth in Krafla suggest. Water is required for melting; otherwise melting cannot begin at a temperature lower than that of the heat source. Because the solubility of water in melt is pressure-dependent and almost zero at surface pressure, there must be a minimum depth at which basalt-induced melting can occur and a rhyolite reservoir sustained. In practice, the

  2. Submarine Flood Basalt Eruptions and Flows of Ontong Java Plateau, Nauru Basin and East Mariana Basin

    Science.gov (United States)

    Michael, P. J.; Trowbridge, S. R.; Zhang, J.; Johnson, A. L.

    2016-12-01

    The preservation of fresh basalt glasses from the submarine Cretaceous Ontong Java Plateau (OJP), Earth's largest LIP, has allowed correlation of precise lava compositions over 100s of km, as well as determination of eruption depths using dissolved H2O and CO2 contents. Low dissolved H2O in glasses shows that H2O in the mantle source is low [1,2], suggesting mantle temperatures are high. Very high dissolved Cl indicates that magmas interacted extensively with brines. The near total absence of vesicles in OJP glasses contrasts sharply with MORB, and suggests that OJP lavas were saturated or undersaturated with CO2 when they were emplaced, in contrast to MORB that are often oversaturated. The lavas likely remained liquid for a longer period of time so that they degassed to equilibrium levels of dissolved CO2 andlost all bubbles. Very precise major and trace element analyses of glasses, uncomplicated by crystals or alteration, show how lavas within and between widely-spaced drill holes could be related. For example, glasses from Sites 1185B and 1186A, which are about 200 km apart, are compositionally identical within precise limits and must have erupted from the same well-mixed magma chamber. They erupted at about the same depth, but 1186A has a corrected basement depth that is >700m deeper. With a slope of 0.3°, this suggests a flow distance >130km. The eruption depths for glasses from East Mariana and Nauru Basins are similar to those of 1185B and 1186A on OJP, even though their reconstructed basement depths are about 2000 m deeper. It suggests that the plateau lavas flowed into the basins. Similarly, eruption depths in Hole 807C are 3040m for Kwaimbaita lavas but are 1110m [1,2] for Singgalo lavas that directly overlie them. It is unlikely that plateau uplift and subsidence accounts for the observed eruption depths. All of these observations are best explained by very large-volume eruptions whose lavas traveled for long distances, up to 100s of km, into deeper

  3. Magnetostratigraphy of the Grande Ronde Basalt Pasco Basin, Washington

    International Nuclear Information System (INIS)

    Packer, D.R.; Petty, M.H.

    1979-01-01

    The paleomagnetic measurements of samples from the holes sampled have shown that there are four magnetic correlation lines, between adjacent flows in holes that have distinctly different mean stratigraphic inclinations, and two magnetic polarity boundaries that can be used for magnetic correlation in the Grande Ronde Basalt in the Pasco Basin. The results of paleomagnetic measurements of samples from the Wanapum Basalt and Saddle Mountains Basalt indicate that the potential for magnetostratigraphic correlation in these sequences is also good

  4. Increased corrosion resistance of basalt reinforced cement compositions with nanosilica

    OpenAIRE

    URKHANOVA Larisa Alekseevna; LKHASARANOV Solbon Aleksandrovich; ROZINA Victoria Yevgenievna; BUYANTUEV Sergey Lubsanovich; BARDAKHANOV Sergey Prokopievich

    2014-01-01

    Disperse fiber reinforcement is used to improve deformation and shrinkage characteristics, flexural strength of concrete. Basalt roving and thin staple fiber are often used as mineral fibers. The paper considers the problems of using thin basalt fiber produced by centrifugal-blow method. Evaluation of the corrosion resistance of basalt fiber as part of the cement matrix was performed. Nanodispersed silica produced by electron beam accelerator was used to increase corrosion resistance of ba...

  5. Glass compositions

    Energy Technology Data Exchange (ETDEWEB)

    France, P W

    1985-05-30

    A fluoride glass for use in the production of optical fibres has an enhanced D/H ratio, preferably such that OD:OH is at least 9:1. In the example, such a glass is prepared by treating with D/sub 2/O a melt comprising 51.53 mole per cent ZrF/sub 4/, 20.47 mole per cent BaF/sub 2/, 5.27 mole per cent LaF/sub 3/, 3.24 mole per cent AlF/sub 3/, and 19.49 mole per cent LiF.

  6. Descriptive summary of the Grande Ronde Basalt type section, Columbia River Basalt Group

    International Nuclear Information System (INIS)

    Camp, V.E.; Price, S.M.; Reidel, S.P.

    1978-10-01

    The Grande Ronde Basalt type section, located in extreme southeastern Washington, was measured, sampled, and characterized. The section is 800 meters thick and is comprised of 35 Grande Ronde Basalt flows. These flows are divisible into 3 magnetostratiographic units termed, in ascending order, the R 1 , the N 1 , and the R 2 . The R 1 unit is represented by 13 reversely polarized flows; the N 1 unit, by 13 normally polarized flows; and the R 2 , by 9 reversely polarized flows. Chemically, the Grande Ronde Basalt flows are divided into 2 major groups, termed A and B. The compositions of the lower 9 flows, members of Group A, are similar to either the high-Mg Grande Ronde chemical type, the high-Ti Grande Ronde chemical type, or the Pomona chemical type. The compositions of the upper 25 flows, members of Group B, are predominantly similar to the low-Mg Grande Ronde chemical type. Petrographically, the Grande Ronde Basalt flows are generally fine grained and aphyric, and have a intergranular or intersertal micro-texture. Major mineral phases include plagioclase (An/sub 40-60/) and augite; minor mineral phases include pigeonite, orthopyroxene, ilmenite, titanomagnetite, and olivine. Group A flows generally contain more olivine and less pigeonite than do Group B flows. 6 figures, 6 tables

  7. Environmental implication of subaqueous lava flows from a continental Large Igneous Province: Examples from the Moroccan Central Atlantic Magmatic Province (CAMP)

    Science.gov (United States)

    El Ghilani, S.; Youbi, N.; Madeira, J.; Chellai, E. H.; López-Galindo, A.; Martins, L.; Mata, J.

    2017-03-01

    The Late Triassic-Early Jurassic volcanic sequence of the Central Atlantic Magmatic Province (CAMP) of Morocco is classically subdivided into four stratigraphic units: the Lower, Middle, Upper and Recurrent Formations separated by intercalated sediments deposited during short hiatuses in volcanic activity. Although corresponding to a Large Igneous Province formed in continental environment, it contains subaqueous lava flows, including dominant pillowed flows but also occasional sheet flows. We present a study of the morphology, structure and morphometry of subaqueous lava flows from three sections located at the Marrakech High-Atlas (regions of Aït-Ourir, Jbel Imzar and Oued Lhar-Herissane), as well as an analysis of the sediments, in order to characterize them and to understand their environmental meaning. The analysis of clays by the diffraction method X-ray revealed the presence of illite, mica, phengite, céladonite, talc and small amounts of quartz, hematite, calcite and feldspar, as well as two pairs of interbedded irregular (chlorite Smectite/chlorite-Mica). Fibrous minerals such as sepiolite and palygorskite were not detected. The peperite of Herissane region (Central High Atlas) provided an excellent overview on the factors favoring the magma-sediment interaction. These are the products of a mixture of unconsolidated or poorly consolidated sediments, low permeability with a low viscosity magma. The attempt of dating palynology proved unfortunately without results.

  8. Emplacement of Columbia River flood basalt

    Science.gov (United States)

    Reidel, Stephen P.

    1998-11-01

    Evidence is examined for the emplacement of the Umatilla, Wilbur Creek, and the Asotin Members of Columbia River Basalt Group. These flows erupted in the eastern part of the Columbia Plateau during the waning phases of volcanism. The Umatilla Member consists of two flows in the Lewiston basin area and southwestern Columbia Plateau. These flows mixed to form one flow in the central Columbia Plateau. The composition of the younger flow is preserved in the center and the composition of the older flow is at the top and bottom. There is a complete gradation between the two. Flows of the Wilbur Creek and Asotin Members erupted individually in the eastern Columbia Plateau and also mixed together in the central Columbia Plateau. Comparison of the emplacement patterns to intraflow structures and textures of the flows suggests that very little time elapsed between eruptions. In addition, the amount of crust that formed on the earlier flows prior to mixing also suggests rapid emplacement. Calculations of volumetric flow rates through constrictions in channels suggest emplacement times of weeks to months under fast laminar flow for all three members. A new model for the emplacement of Columbia River Basalt Group flows is proposed that suggests rapid eruption and emplacement for the main part of the flow and slower emplacement along the margins as the of the flow margin expands.

  9. Commercial nuclear waste repository in basalt

    International Nuclear Information System (INIS)

    Hardy, M.P.; Patricio, J.G.; Heley, W.H.

    1980-06-01

    The Basalt Waste Isolation Project (BWIP) is an ongoing research and engineering effort being conducted by Rockwell Hanford Operations (Rockwell), which is under contract to the US Department of Energy. The objectives of this program are to assess the feasibility of and to provide the technology needed to design and construct a licensed commercial nuclear waste repository in the deep basalt formations underlying the Hanford Site. An extensive preconceptual design effort was undertaken during 1979 to develop a feasible concept that could serve as a reference design for both surface and underground facilities. The preconceptual design utilized existing technology to the greatest extent possible to offer a system design that could be utilized in establishing schedule and cost baseline data, recommend alternatives that require additional study, and develop basic design requirements that would allow evolution of the design process prior to the existence of legislated criteria. This paper provides a description of the concept developed for the subsurface aspects of this nuclear waste repository

  10. Degassing of reduced carbon from planetary basalts.

    Science.gov (United States)

    Wetzel, Diane T; Rutherford, Malcolm J; Jacobsen, Steven D; Hauri, Erik H; Saal, Alberto E

    2013-05-14

    Degassing of planetary interiors through surface volcanism plays an important role in the evolution of planetary bodies and atmospheres. On Earth, carbon dioxide and water are the primary volatile species in magmas. However, little is known about the speciation and degassing of carbon in magmas formed on other planets (i.e., Moon, Mars, Mercury), where the mantle oxidation state [oxygen fugacity (fO2)] is different from that of the Earth. Using experiments on a lunar basalt composition, we confirm that carbon dissolves as carbonate at an fO2 higher than -0.55 relative to the iron wustite oxygen buffer (IW-0.55), whereas at a lower fO2, we discover that carbon is present mainly as iron pentacarbonyl and in smaller amounts as methane in the melt. The transition of carbon speciation in mantle-derived melts at fO2 less than IW-0.55 is associated with a decrease in carbon solubility by a factor of 2. Thus, the fO2 controls carbon speciation and solubility in mantle-derived melts even more than previous data indicate, and the degassing of reduced carbon from Fe-rich basalts on planetary bodies would produce methane-bearing, CO-rich early atmospheres with a strong greenhouse potential.

  11. Hydrogeology of the basalts in the Uruguayan NW

    International Nuclear Information System (INIS)

    Hausman, A.; Fernandez, A.

    1967-01-01

    This work is about the hydrogeological aspects in the NW Uruguayan basaltic area. The results of this research are the main geological, morphological and hydrogeological aspects of the area as well as the characteristics and the color of the basalt and sandstones

  12. Influence of basalt/groundwater interactions on radionuclide migration

    International Nuclear Information System (INIS)

    Vandegrift, G.F.

    1984-01-01

    The work presented here is a partial summary of the experimental results obtained in the Laboratory Analog Program. Two aspects of this effort are (1) the interaction between simulated basaltic groundwater and basalt fissures that were either freshly cleaved or laboratory altered by hydrothermal treatment with the simulated groundwater and (2) the effect of this interaction on radionuclide migration through these basalt fissures. The following conclusions of this study bear heavily on the predicted safety of a basalt repository: Sorption properties of freshly fissured basalt and naturally aged basalt are quite different for different chemical species. Analog experiments predict that aged basalt would be an effective retarder of cesium, but would be much less so for actinide elements. Distribution ratios measured from batch experiments with finely ground rock samples (presenting unaltered rock surfaces) are not a reliable means of predicting radionuclide migration in geological repositories. As the near-repository area is resaturated by groundwater, its ability to retard actinide migration will be degraded with time. Disturbing the natural flow of groundwater through the repository area by constructing and backfilling the repository will modify the composition of groundwater. This modified groundwater is likely to interact with and to modify naturally aged basalt surfaces downstream from the repository

  13. Constructibility issues associated with a nuclear waste repository in basalt

    International Nuclear Information System (INIS)

    Turner, D.A.

    1981-01-01

    This report contains the text and slide reproductions of a speech on nuclear waste disposal in basalt. The presentation addresses the layout of repository access shafts and subsurface facilities resulting from the conceptual design of a nuclear repository in basalt. The constructibility issues that must be resolved prior to construction are described

  14. Use of basaltic waste as red ceramic raw material

    Directory of Open Access Journals (Sweden)

    T. M. Mendes

    Full Text Available Abstract Nowadays, environmental codes restrict the emission of particulate matters, which result in these residues being collected by plant filters. This basaltic waste came from construction aggregate plants located in the Metropolitan Region of Londrina (State of Paraná, Brazil. Initially, the basaltic waste was submitted to sieving (< 75 μm and the powder obtained was characterized in terms of density and particle size distribution. The plasticity of ceramic mass containing 0%, 10%, 20%, 30%, 40% and 50% of basaltic waste was measured by Atterberg method. The chemical composition of ceramic formulations containing 0% and 20% of basaltic waste was determined by X-ray fluorescence. The prismatic samples were molded by extrusion and fired at 850 °C. The specimens were also tested to determine density, water absorption, drying and firing shrinkages, flexural strength, and Young's modulus. Microstructure evaluation was conducted by scanning electron microscopy, X-ray diffraction, and mercury intrusion porosimetry. Basaltic powder has similar physical and chemical characteristics when compared to other raw materials, and contributes to ceramic processing by reducing drying and firing shrinkage. Mechanical performance of mixtures containing basaltic powder is equivalent to mixtures without waste. Microstructural aspects such as pore size distribution were modified by basaltic powder; albite phase related to basaltic powder was identified by X-ray diffraction.

  15. Glass: Rotary Electric Glass Furnace

    Energy Technology Data Exchange (ETDEWEB)

    Recca, L.

    1999-01-29

    Compared to conventional gas-fired furnaces, the new rotary electric furnace will increase energy efficiency while significantly reducing air emissions, product turnaround time, and labor costs. As this informative new fact sheet explains, the thousand different types of glass optical blanks produced for the photonics industry are used for lasers, telescopes, cameras, lights, and many other products.

  16. Hydrothermal interactions of cesium and strontium phases from spent unreprocessed fuel with basalt phases and basalts

    International Nuclear Information System (INIS)

    Komarneni, S.; Scheetz, B.E.; McCarthy, G.J.; Coons, W.E.

    1980-03-01

    This investigation is a segment of an extensive research program aimed at investigating the feasibility of long-term, subsurface storage of commercial nuclear waste. Specifically, it is anticipated that the waste will be housed in a repository mined from the basalt formations which lie beneath the Hanford Site. The elements monitored during the present experiments were Cs and Sr. These two elements represent significant biohazards if released from a repository and are the major heat producing radionuclides present in commercial radioactive waste. Several Cs phases and/or solutions were reacted with either isolated basalt phases or bulk-rock basalt, and the resulting solids and solutions were analyzed. The hydrothermal reactivity of SrZrO 3 , which is believed to be a probable host for Sr in SFE was investigated. While so far no evidence exists which indicates that Sr is present in a water soluble phase in spent fuel elements (SFE), detailed investigation of a potential hazard is warranted. This investigation has determined that some Cs compounds likely to be stable components of spent fuel (i.e., CsOH, Cs 2 MoO 4 , Cs 2 U 2 O 7 ) have significant hydrothermal solubilities. These solubilities are greatly decreased in the presence of basalt and/or basalt minerals. The decrease in the amount of Cs in solution results from reactions which form pollucite and/or CsAlSiO 4 , with the production of pollucite exceeding that of CsAlSiO 4 . Dissolution of β-Cs 2 U 2 O 7 implies solubilizing a uranium species to an undetermined extent. The production of schoepite (UO 3 .3H 2 O) during some experiments containing basalt phases, indicates a tendency to oxidize U 4+ to U 6+ . When diopside (nominally CaMgSi 2 O 6 ) and β-Cs 2 U 2 O 7 were hydrothermally reacted, at 300 0 C both UO 2 and UO 3 .3H 2 O were produced. Experiments on SrZrO 3 show it to be an unreactive phase

  17. Hydrothermal interactions of cesium and strontium phases from spent unreprocessed fuel with basalt phases and basalts

    Energy Technology Data Exchange (ETDEWEB)

    Komarneni, S.; Scheetz, B.E.; McCarthy, G.J.; Coons, W.E.

    1980-03-01

    This investigation is a segment of an extensive research program aimed at investigating the feasibility of long-term, subsurface storage of commercial nuclear waste. Specifically, it is anticipated that the waste will be housed in a repository mined from the basalt formations which lie beneath the Hanford Site. The elements monitored during the present experiments were Cs and Sr. These two elements represent significant biohazards if released from a repository and are the major heat producing radionuclides present in commercial radioactive waste. Several Cs phases and/or solutions were reacted with either isolated basalt phases or bulk-rock basalt, and the resulting solids and solutions were analyzed. The hydrothermal reactivity of SrZrO/sub 3/, which is believed to be a probable host for Sr in SFE was investigated. While so far no evidence exists which indicates that Sr is present in a water soluble phase in spent fuel elements (SFE), detailed investigation of a potential hazard is warranted. This investigation has determined that some Cs compounds likely to be stable components of spent fuel (i.e., CsOH, Cs/sub 2/MoO/sub 4/, Cs/sub 2/U/sub 2/O/sub 7/) have significant hydrothermal solubilities. These solubilities are greatly decreased in the presence of basalt and/or basalt minerals. The decrease in the amount of Cs in solution results from reactions which form pollucite and/or CsAlSiO/sub 4/, with the production of pollucite exceeding that of CsAlSiO/sub 4/. Dissolution of ..beta..-Cs/sub 2/U/sub 2/O/sub 7/ implies solubilizing a uranium species to an undetermined extent. The production of schoepite (UO/sub 3/.3H/sub 2/O) during some experiments containing basalt phases, indicates a tendency to oxidize U/sup 4 +/ to U/sup 6 +/. When diopside (nominally CaMgSi/sub 2/O/sub 6/) and ..beta..-Cs/sub 2/U/sub 2/O/sub 7/ were hydrothermally reacted, at 300/sup 0/C both UO/sub 2/ and UO/sub 3/.3H/sub 2/O were produced. Results of experiments on SrZrO/sub 3/ show it to be

  18. [Determination of Total Iron and Fe2+ in Basalt].

    Science.gov (United States)

    Liu, Jian-xun; Chen, Mei-rong; Jian, Zheng-guo; Wu, Gang; Wu, Zhi-shen

    2015-08-01

    Basalt is the raw material of basalt fiber. The content of FeO and Fe2O3 has a great impact on the properties of basalt fibers. ICP-OES and dichromate method were used to test total Fe and Fe(2+) in basalt. Suitable instrument parameters and analysis lines of Fe were chosen for ICP-OES. The relative standard deviation (RSD) of ICP-OES is 2.2%, and the recovery is in the range of 98%~101%. The method shows simple, rapid and highly accurate for determination of total Fe and Fe(2+) in basalt. The RSD of ICP-OES and dichromate method is 0.42% and 1.4%, respectively.

  19. Effect of combined extrusion parameters on mechanical properties of basalt fiber-reinforced plastics based on polypropylene

    Science.gov (United States)

    Bashtannik, P. I.; Ovcharenko, V. G.; Boot, Yu. A.

    1997-11-01

    Basalt fibers are efficient reinforcing fillers for polypropylene because they increase both the mechanical and the tribotechnical properties of composites. Basalt fibers can compete with traditional fillers (glass and asbestos fibers) of polypropylene with respect to technological, economic, and toxic properties. The effect of technological parameters of producing polypropylene-based basalt fiber-reinforced plastics (BFRPs) by combined extrusion on their mechanical properties has been investigated. The extrusion temperature was found to be the main parameter determining the mechanical properties of the BFRPs. With temperature growth from 180 to 240°C, the residual length of the basalt fibers in the composite, as well as the adhesive strength of the polymer-fiber system, increased, while the composite defectiveness decreased. The tensile strength and elastic modulus increased from 35 to 42 MPa and 3.2 to 4.2 GPa, respectively. At the same time, the growth in composite solidity led to its higher brittleness. Thus, a higher temperature of extrusion allows us to produce materials which can be subjected to tensile and bending loads, while the materials produced at a lower temperature of extrusion are impact stable. The effect of the gap size between the extruder body and moving disks on the mechanical properties of the BFRPs is less significant than that of temperature. An increase of the gap size from 2 to 8 mm improves the impregnation quality of the fibers, but the extruder productivity diminishes. The possibility of controling the properties of reinforced polypropylene by varying the technological parameters of combined extrusion is shown. The polypropylene-based BFRPs produced by the proposed method surpass the properties of glass and asbestos fiber-reinforced plastics.

  20. Glass-crystalline materials for active waste incorporation

    International Nuclear Information System (INIS)

    Kulichenko, V.V.; Krylova, N.V.; Vlasov, V.I.; Polyakov, A.S.

    1979-01-01

    This paper presents the results of investigations into the possibility and conditions for using glass-crystalline materials for the incorporation of radionuclides. Materials of a cast pyroxene type that are obtained by smelting calcined wastes with acid blast furnace slags are described. A study was also made of materials of a basalt type prepared from wastes with and without alkali metal salt. Changes in the structure and properties of materials in the process of storage at different temperatures have been studied

  1. Conversion of radioactive ferrocyanide compounds to immobile glasses

    International Nuclear Information System (INIS)

    Schulz, W.W.; Dressen, A.L.

    1977-01-01

    Complex radioactive ferrocyanide compounds result from the scavenging of cesium from waste products produced in the chemical reprocessing of nuclear fuel. These ferrocyanides, in accordance with this process, are converted to an immobile glass, resistant to leaching by water, by fusion together with sodium carbonate and a mixture of (a) basalt and boron trioxide (B 2 O 3 ) or (b) silica (SiO 2 ) and lime (CaO). 7 claims

  2. JSS project phase 4: Experimental and modelling studies of HLW glass dissolution in repository environments

    International Nuclear Information System (INIS)

    1987-10-01

    A goal of the JSS project was to develop a scientific basis for understanding the effects of waste package components, groundwater chemistry, and other repository conditions on glass dissolution behaviour, and to develop and refine a model for the processes governing glass dissolution. The fourth phase of the project, which was performed by the Hahn-Meitner-Institut, Berlin, FRG, dealt specifically with model development and application. Phase 4 also adressed whether basaltic glasses could serve as natural analogues for nuclear waste glasses, thus providing a means to test the capability of the model for long-term predictions. Additional experiments were performed in order to complete the data base necessary to model interactions between the glass and bentonite and between glass and steel corrosion products. More data on temperature, S/V, and pH dependence of the glass/water reaction were also collected. In this report, the data acquired during phase 4 are presented and discussed. (orig./DG)

  3. Bubble Formation in Basalt-like Melts

    DEFF Research Database (Denmark)

    Jensen, Martin; Keding, Ralf; Yue, Yuanzheng

    2011-01-01

    and their diameter. The variation in melting temperature has little influence on the overall bubble volume. However, the size distribution of the bubbles varies with the melting temperature. When the melt is slowly cooled, the bubble volume increases, implying decreased solubility of the gaseous species. Mass...... spectroscopy analysis of gases liberated during heating of the glass reveals that small bubbles contain predominantly CH4, CO and CO2, whereas large bubbles bear N2, SO2 and H2S. The methodology utilised in this work can, besides mapping the bubbles in a glass, be applied to shed light on the sources of bubble...

  4. Basalt alteration and basalt-waste interaction in the Pasco Basin of Washington State. Final report

    International Nuclear Information System (INIS)

    Benson, L.V.; Carnahan, C.L.; Apps, J.A.; Mouton, C.A.; Corrigan, D.J.; Frisch, C.J.; Shomura, L.K.

    1978-09-01

    A study was conducted to determine the nature of the minerals which coat vesicle and fracture surfaces in the Grande Ronde Basalt Formation, simulate the mass transfer which led to their precipitation, and predict the mass transfer associated with the dissolution of spent unreprocessed fuel (SURF). Scanning electron microscopy (SEM), petrographic, x-ray diffraction (XRD), and electron microprobe (EMP) analyses have been made on a series of samples taken from 1100 ft (335.3 m) of core from core hole DC2. Preliminary simulations of the mass transfer associated with basalt dissolution in a thermodynamically closed system have been accomplished. In addition two mass transfer codes have been modified to facilitate data base changes. Thermochemical data for uranium and plutonium have been collected and converted to standard state conditions. These data will be critically evaluated and input to the mass transfer data base in the near future

  5. Nitrate glass

    International Nuclear Information System (INIS)

    Kirilenko, I.A.; Vinogradov, E.E.

    1977-01-01

    Experimental evidence on behaviour of nitrate glasses is reviewed in terms of relationships between the presence of water in vitrescent nitrate systems and the properties of the systems. The glasses considered belong to systems of Mg(NO 3 ) 2 - Nd(NO 3 ) 3 ; Hg(NO 3 ) 2 -Nd(NO 3 ) 3 ; NaNO 3 -Mg(NO 3 ) 2 -Nd(NO 3 ) 3 ; M-Zn(NO 3 ) 3 , where M is a mixture of 20% mass NaNO 3 and 80% mass Mg(NO 3 ) 2 , and Zn is a rare earth ion. Nitrate glass is shown to be a product of dehydration. Vitrification may be regarded as a resusl of formation of molecular complexes in the chain due to hydrogen bonds of two types, i.e. water-water, or water-nicrate group. Chain formation, along with low melting points of the nitrates, hinder crystallization of nitrate melts. Provided there is enough water, this results in vitrification

  6. Alteration of national glass in radioactive waste repository host rocks: A conceptional review

    International Nuclear Information System (INIS)

    Apps, J.A.

    1987-01-01

    The storage of high-level radioactive wastes in host rocks containing natural glass has potential chemical advantages, especially if the initial waste temperatures are as high as 250 0 C. However, it is not certain how natural glasses will decompose when exposed to an aqueous phase in a repository environment. The hydration and devitrification of both rhyolitic and natural basaltic natural glasses are reviewed in the context of hypothetical thermodynamic phase relations, infrared spectroscopic data and laboratory studies of synthetic glasses exposed to steam. The findings are compared with field observations and laboratory studies of hydrating and devitrifying natural glasses. The peculiarities of the dependence of hydration and devitrification behavior on compositional variation is noted. There is substantial circumstantial evidence to support the belief that rhyolitic glasses differ from basaltic glasses in their thermodynamic stability and their lattice structure, and that this is manifested by a tendency of the former to hydrate rather than devitrify when exposed to water. Further research remains to be done to confirm the differences in glass structure, and to determine both physically and chemically dependent properties of natural glasses as a function of composition

  7. Conversion of Hanford salt cake to glass: laboratory studies

    International Nuclear Information System (INIS)

    Schulz, W.W.; Dressen, A.L.; Hobbick, C.W.; Kupfer, M.J.

    1976-05-01

    Approximately 140 million liters of solid salt cake (mainly NaNO 3 ), produced by evaporation of aged, alkaline high-level wastes, will be stored in underground tanks when the present Hanford Waste Management Program is completed in the early 1980's. These solid wastes can be converted to silicate-based glasses by melting them either at 1200 to 1300 0 C with appropriate amounts of sand and lime (soda-lime formulation) or at 1000 to 1100 0 C with appropriate amounts of Columbia River basalt and B 2 O 3 (basalt formulation). Both formulations yield dense, immobile glasses of low water leachability (10 -7 to 10 -6 g cm -2 day -1 ) suitable for terminal storage. The soda-lime formulation is presently preferred over the basalt formulation because it can accommodate more salt cake (50 wt percent versus 30 to 40 wt percent) while yielding a glass whose volume is 10 to 20 percent less than the volume of the salt cake in the melt charge

  8. Strontium stable isotope behaviour accompanying basalt weathering

    Science.gov (United States)

    Burton, K. W.; Parkinson, I. J.; Gíslason, S. G. R.

    2016-12-01

    The strontium (Sr) stable isotope composition of rivers is strongly controlled by the balance of carbonate to silicate weathering (Krabbenhöft et al. 2010; Pearce et al. 2015). However, rivers draining silicate catchments possess distinctly heavier Sr stable isotope values than their bedrock compositions, pointing to significant fractionation during weathering. Some have argued for preferential release of heavy Sr from primary phases during chemical weathering, others for the formation of secondary weathering minerals that incorporate light isotopes. This study presents high-precision double-spike Sr stable isotope data for soils, rivers, ground waters and estuarine waters from Iceland, reflecting both natural weathering and societal impacts on those environments. The bedrock in Iceland is dominantly basaltic, d88/86Sr ≈ +0.27, extending to lighter values for rhyolites. Geothermal waters range from basaltic Sr stable compositions to those akin to seawater. Soil pore waters reflect a balance of input from primary mineral weathering, precipitation and litter recycling and removal into secondary phases and vegetation. Rivers and ground waters possess a wide range of d88/86Sr compositions from +0.101 to +0.858. Elemental and isotope data indicate that this fractionation primarily results from the formation or dissolution of secondary zeolite (d88/86Sr ≈ +0.10), but also carbonate (d88/86Sr ≈ +0.22) and sometimes anhydrite (d88/86Sr ≈ -0.73), driving the residual waters to heavier or lighter values, respectively. Estuarine waters largely reflect mixing with seawater, but are also be affected by adsorption onto particulates, again driving water to heavy values. Overall, these data indicate that the stability and nature of secondary weathering phases, exerts a strong control on the Sr stable isotope composition of silicate rivers. [1] Krabbenhöft et al. (2010) Geochim. Cosmochim. Acta 74, 4097-4109. [2] Pearce et al. (2015) Geochim. Cosmochim. Acta 157, 125-146.

  9. Strength and Fractography of Glass Wool Fibres

    DEFF Research Database (Denmark)

    Lund, Majbritt Deichgræber; Yue, Yuanzheng

      Glass wool fibres (GWFs) are produced using the cascade spinning process. The lengths of the fibers range from 1 to 4 cm, whereas the diameters range from 4 and 10 mm. GWFs are widely used as insulation material due to their excellent heat and sound isolation effect, chemical durability, and high...... between fracture strength (sf) and mirror radius (r), i.e., sf = A*r, is confirmed for all the GWFs studied. The materials constant, A, (mirror constant) is found to be 2.4 ~ 2.7 MPam½ for basaltic wool and 2.0 MPam½ for E-glass wool, which is similar to the value reported in the literature for different...

  10. BASALT A: Basaltic Terrains in Idaho and Hawaii as Planetary Analogs for Mars Geology and Astrobiology

    Science.gov (United States)

    Hughes, Scott S.; Haberle, Christopher W.; Nawotniak, Shannon E. Kobs; Sehlke, Alexander; Garry, W. Brent; Elphic, Richard C.; Payler, Sam J.; Stevens, Adam H.; Cockell, Charles S.; Brady, Allyson L.; hide

    2018-01-01

    Assessments of field research target regions are described within two notably basaltic geologic provinces as Earth analogs to Mars. Regions within the eastern Snake River Plain of Idaho and the Big Island of Hawaii, USA, provinces that represent analogs of present-day and early Mars, respectively, were evaluated on the basis of geologic settings, rock lithology and geochemistry, rock alteration, and climate. Each of these factors provide rationale for the selection of specific targets for field research in five analog target regions: (1) Big Craters and (2) Highway lava flows at Craters of the Moon National Monument and Preserve, Idaho; and (3) Mauna Ulu low shield, (4) Kilauea Iki lava lake and (5) Kilauea caldera in the Kilauea Volcano summit region and the East Rift Zone of Hawaii. Our evaluation of compositional and textural differences, as well as the effects of syn- and post-eruptive rock alteration, shows that the basaltic terrains in Idaho and Hawaii provide a way to characterize the geology and major geologic substrates that host biological activity of relevance to Mars exploration. This work provides the foundation to better understand the scientific questions related to the habitability of basaltic terrains, the rationale behind selecting analog field targets, and their applicability as analogs to Mars.

  11. Geomicrobiology of the Ocean Crust: The Phylogenetic Diversity, Abundance, and Distribution of Microbial Communities Inhabiting Basalt and Implications for Rock Alteration Processes

    Science.gov (United States)

    2007-06-01

    experimental study of the dissolution rates of basaltic glass as a function of aqueous Al, Si and oxalic acid concentration at 25 C and pH = 3 and 11...and hydrothermal vents. Furthermore, these communities may contribute to the elemental cycling of Fe, S, Mn, N, and C in this environment. The...2004; Schippers and Neretin, 2006; Teske, 2006) and mid- to high-temperature hydrothermal systems (Cowen et al., 1999; Nakagawa et al., 2004; Nercessian

  12. Simulated high-level waste-basalt interaction experiments. Annual progress report, October 1, 1977--September 30, 1978

    International Nuclear Information System (INIS)

    Scheetz, B.E.; Smith, D.K.; Barnes, M.W.; Komarneni, S.; Stull, L.M.; Smith, C.A.

    1978-11-01

    Reconnaissance experiments suggested that the observed reactivity of calcine and glass as 300 0 C would be anticipated at lower temperatures but only after longer times of hydrothermal treatment. Long-duration experiments at 100 0 and 300 0 C were initiated to determine the time dependence of the alterations at lower temperatures. The reconnaissance experiments also suggested that equilibrium conditions were not yet achieved in these closed system experiments. Glass was observed to alter readily with the formation of acmite-augite pyroxene; a uranyl silicate, weeksite; and a rare-earth slicate-phosphate hydroxyapatite. Nearly all of the B, ca. 70% of the Mo and ca. 50% of the Na in the original glass were dissolved. A simulated reduced SURF (spent unreprocessed fuel) was utilized in hydrothermal experiments. Analyses of the solutions confirmed that soluble fission products phases were leached from the UO 2 matrix and all of the alkali metals were leached from the SURF. In the presence of basalt, however, the released alkalis react with aluminosilicates and are removed from solution. Individual phases believed to be present in SURF have been hydrothermally treated, with the reference basalts and with major primary and secondary minerals. Cs(OH), Cs 2 MoO 4 and Cs 2 U 2 O 7 were used as potential cesium phases. In some cases as much as 99.9% of the cesium can be removed from solution by interacting with the rocks and minerals to form pollucite. The interaction of strontium zirconate under hydrothermal conditions with the above rock and basalt minerals indicates that in all cases 99.9% of the available strontium is retained in the strontium zirconate or as alteration products. 11 figures, 8 tables

  13. The Thickness and Volume of Young Basalts Within Mare Imbrium

    Science.gov (United States)

    Chen, Yuan; Li, Chunlai; Ren, Xin; Liu, Jianjun; Wu, Yunzhao; Lu, Yu; Cai, Wei; Zhang, Xunyu

    2018-02-01

    Basaltic volcanism is one of the most important geologic processes of the Moon. Research on the thickness and volume of late-stage basalts of Mare Imbrium helps better understand the source of lunar volcanism and eruption styles. Based on whether apparent flow fronts exist or not, the late-stage basalts within Mare Imbrium were divided into two groups, namely, Upper Eratosthenian basalts (UEm) and Lower Eratosthenian basalts (LEm). Employing the topographic profile analysis method for UEm and the crater excavation technique for LEm, we studied the thickness and distribution of Eratosthenian basalts in Mare Imbrium. For the UEm units, their thicknesses were estimated to be 16-34 (±2) m with several layers of individual lava ( 8-13 m) inside. The estimated thickness of LEm units was 14-45(±1) m, with a trend of reducing thickness from north to south. The measured thickness of late-stage basalts around the Chang'E-3 landing site ( 37 ± 1 m) was quite close to the results acquired by the lunar penetrating radar carried on board the Yutu Rover ( 35 m). The total volume of the late-stage basalts in Mare Imbrium was calculated to be 8,671 (±320) km3, which is 4 times lower than that of Schaber's estimation ( 4 × 104 km3). Our results indicate that the actual volume is much lower than previous estimates of the final stage of the late basaltic eruption of Mare Imbrium. Together, the area flux and transport distance of the lava flows gradually decreased with time. These results suggest that late-stage volcanic evolution of the Moon might be revised.

  14. Influence of pyrolysis temperature on fracture response in SiOC based composites reinforced by basalt woven fabric

    Czech Academy of Sciences Publication Activity Database

    Chlup, Zdeněk; Černý, Martin; Strachota, Adam; Sucharda, Zbyněk; Halasová, Martina; Dlouhý, Ivo

    2014-01-01

    Roč. 34, č. 14 (2014), s. 3389-3398 ISSN 0955-2219 R&D Projects: GA ČR GAP107/12/2445; GA MŠk(CZ) ED1.1.00/02.0068 Institutional support: RVO:68081723 ; RVO:67985891 ; RVO:61389013 Keywords : Fracture behaviour * CMCs * Pyrolysis * Basalt fibre * Polysiloxane Subject RIV: JL - Materials Fatigue, Friction Mechanics; JI - Composite Materials (USMH-B); JH - Ceramics, Fire-Resistant Materials and Glass (UMCH-V) Impact factor: 2.947, year: 2014

  15. Coupled penetrometer, MBES and ADCP assessments of tidal variations of the surface sediment layer along active subaqueous dunes, Danish Wadden Sea

    DEFF Research Database (Denmark)

    Stark, Nina; Hanff, Henrik; Svenson, Christian

    2011-01-01

    In-situ geotechnical measurements of surface sediments were carried out along large subaqueous dunes in the Knudedyb tidal inlet channel in the DanishWadden Sea using a small free-falling penetrometer. Vertical profiles showed a typical stratification pattern with a resolution of ~1 cm depicting...... a thin surface layer of low sediment strength and a stiffer substratum below (quasi-static bearing capacity equivalent: 1–3 kPa in the top layer, 20–140 kPa in the underlying sediment; thickness of the top layer ca. 5–8 cm). Observed variations in the thickness and strength of the surface layer during...... a tidal cycle were compared to mean current velocities (measured using an acoustic Doppler current profiler, ADCP), high-resolution bathymetry (based on multibeam echo sounding, MBES) and qualitative estimates of suspended sediment distributions in the water column (estimated from ADCP backscatter...

  16. Simulating the structure of gypsum composites using pulverized basalt waste

    Directory of Open Access Journals (Sweden)

    Buryanov Аleksandr

    2017-01-01

    Full Text Available This paper examines the possibility of simulating the structure of gypsum composite modified with basalt dust waste to make materials and products based on it. Structural simulating of the topological space in gypsum modified composite by optimizing its grain-size composition highly improves its physical and mechanical properties. Strength and density tests have confirmed the results of the simulation. The properties of modified gypsum materials are improved by obtaining of denser particle packing in the presence of hemihydrate of finely dispersed basalt and plasticizer particles in the system, and by engaging basalt waste in the structuring process of modified gypsum stone.

  17. Basaltic volcanic episodes of the Yucca Mountain region

    International Nuclear Information System (INIS)

    Crowe, B.M.

    1990-01-01

    The purpose of this paper is to summarize briefly the distribution and geologic characteristics of basaltic volcanism in the Yucca Mountain region during the last 10--12 Ma. This interval largely postdates the major period of silicic volcanism and coincides with and postdates the timing of major extensional faulting in the region. Field and geochronologic data for the basaltic rocks define two distinct episodes. The patterns in the volume and spatial distribution of these basaltic volcanic episodes in the central and southern part of the SNVF are used as a basis for forecasting potential future volcanic activity in vicinity of Yucca Mountain. 33 refs., 2 figs

  18. Property and process correlations for iron-enriched basalt waste forms

    International Nuclear Information System (INIS)

    Grandy, J.D.; Eddy, T.L.; Anderson, G.L.

    1993-02-01

    Correlations of thermodynamic properties and process parameters of high-temperature slag for a range of compositions of iron-enriched basalt are presented. The quantification of the properties of this complex mixture can assist in the design and monitoring of high-temperature melting systems for the treatment of radioactive and hazardous wastes at the Idaho National Engineering Laboratory. The buried and stored wastes at the INEL Radioactive Waste Management Complex have a similar composition to iron-enriched basalt after oxidation of organics. The properties correlated are the viscosity, electrical conductivity, refractory corrosion, and recrystallization temperature. The correlations are expressed as a function of input waste-soil mixture composition, alkali concentration, and slag temperature. An application to determine the effect of alkali flux on slag temperature, leach rate, and volume reduction is presented. Though the correlations are for mixtures of soil and waste with average transuranic-contaminated waste compositions, it appears that good approximations for other waste streams and glass-ceramic waste forms can be obtained because of similarities in composition

  19. Radiogenic isotopes in enriched mid-ocean ridge basalts from Explorer Ridge, northeast Pacific Ocean

    Science.gov (United States)

    Cousens, Brian; Weis, Dominique; Constantin, Marc; Scott, Steve

    2017-09-01

    Extreme gradients in topography related to variations in magma supply are observed on the Southern Explorer Ridge (SER), part of the northern Juan de Fuca ridge system. We report radiogenic isotope (Pb, Sr, Nd, Hf) and geochemical data for twenty-four basalt whole-rock and glass samples collected from the length of the SER and from Explorer Deep, a rift to the north of the SER. Lavas from the SER form a north-south geochemical gradient, dominated by E-MORB at the northern axial high, and range from T-MORB to N-MORB towards the southern deepest part of the ridge. Linear relationships between incompatible element ratios and isotopic ratios in MORB along the ridge are consistent with mixing of magmas beneath the ridge to generate the geographic gradient from E- to N-MORB. The E-MORB have high Sr and Pb, and low Nd and Hf isotopic ratios, typical of enriched mantle that includes a FOZO or HIMU isotopic component. The West Valley and Endeavour segments of the northern Juan de Fuca ridge also include this isotopic component, but the proportion of the FOZO or HIMU component is more extreme in the SER basalts. The FOZO or HIMU component may be garnet-bearing peridotite, or a garnet pyroxenite embedded in peridotite. Recycled garnet pyroxenite better explains the very shallow SER axial high, high Nb/La and La/Sm, and the ;enriched; isotopic compositions.

  20. Melt rock components in KREEPy breccia 15205: Petrography and mineral chemistry of KREEP basalts and quartz-normative mare basalts

    Science.gov (United States)

    Shervais, John W.; Vetter, Scott K.

    1993-05-01

    Many current models for the origin of lunar highland rocks feature as an essential component the assimilation of KREEPy material by primitive magmas parental to the Mg-rich suite and alkali suite plutonic rocks. Similar models have also been proposed for the origin of various mare basalt suites. However, any model which considers assimilation of KREEP an important petrologic process must sooner-or-later deal with the question: what is KREEP? Because pristine KREEP basalts are rare, and most known samples are small (e.g., 15382/15386), the geochemical variability of KREEP basalts is poorly known. Other KREEP compositions which are commonly used in these models include the hypothetical 'high-K KREEP' component of Warren and Wasson, which is derived from Apollo 14 soil data, and the 'superKREEP' quartz-monzodiorite 15405. Lunar breccia 15205 is a polymict regolith breccia that consists of approximately 20% KREEP basalt clasts and 20% quartz-normative basalt clasts in a KREEP-rich matrix. Bulk rock mixing calculations show that this sample comprises about 84% KREEP. The clasts range up to 1 cm in size, but most are considerably smaller. The primary aim is to characterize pristine KREEP basalts petrographically, to establish the range in chemical compositions of KREEP basalts, and to test models that were proposed for their origin. In addition, we may be able to extend the compositional range recognized in the quartz-normative basalt suite and cast some light on its origin as well. Preliminary whole rock geochemical data on the KREEP basalts are presented in a companion paper by M.M. Lindstrom and co-workers. Concentration is on petrography and mineral chemistry of these clasts, and the implications these data have for the origin of the different melt rock suites.

  1. Interaction of groundwater and fresh basalt fissure surfaces and its effect on the migration of actinides

    International Nuclear Information System (INIS)

    Vandegrift, G.F.; Bowers, D.L.; Gerding, T.J.; Fried, S.M.; Wilbur, C.K.; Seitz, M.G.

    1983-01-01

    Experiments are being performed at Argonne National Laboratory (ANL): (1) to identify interactions of radionuclides and repository components that effect nuclide migration, and (2) to assess changes in nuclide migration caused by modifications expected upon aging of the waste, clay backfill, and rock. The experiments are conducted with radioactive borosilicate glass, bentonite and mechanically fissured basalt rock in flowing water analogous to their configuration in a breach of a nuclear waste repository. Changes undergone by the groundwater as it passed through the fissure include: (1) drop in pH from 10 to 8, (2) loss of suspended particulate, and (3) loss of dissolved/suspended U, Np, and Pu. These effects, also studied as functions of radiation dose and of laboratory aging of the repository components, are related to the predicted long-term performance of a nuclear waste repository

  2. Engineered barrier development for a nuclear waste repository in basalt

    International Nuclear Information System (INIS)

    Smith, M.J.

    1980-05-01

    The BWIP Engineered Barrier Program has been developed to provide an integrated approach to the development of site-specific Engineered Barrier assemblages for a repository located in basalt. The goal of this program is to specify engineered and natural barriers which will ensure that nuclear and non-radioactive hazardous materials emplaced in a repository in basalt do not exceed acceptable rates of release to the biosphere. A wide range of analytical and experimental activities related to the basalt repository environment, waste package environment, waste/barrier/rock interactions, and barrier performance assessment provide the basis for selection of systems capable of meeting licensing requirements. Work has concentrated on specifying and testing natural and man-made materials which can be used to plug boreholes in basalt and which can be used as multiple barriers to surround nuclear waste forms and containers. The Engineered Barriers Program is divided into two major activities: multiple barrier studies and borehole plugging. 8 figures, 4 tables

  3. Geochemical characterization of oceanic basalts using artificial neural network

    Digital Repository Service at National Institute of Oceanography (India)

    Das, P.; Iyer, S.D.

    method is specifically needed to identify the OFB as normal (N-MORB), enriched (E-MORB) and ocean island basalts (OIB). Artificial Neural Network (ANN) technique as a supervised Learning Vector Quantisation (LVQ) is applied to identify the inherent...

  4. A note on incipient spilitisation of central Indian basin basalts

    Digital Repository Service at National Institute of Oceanography (India)

    Karisiddaiah, S.M.; Iyer, S.D.

    Rocks dredged in the vicinity of the 79 degrees E fracture zone, in the Central Indian Basin, are sub-alkaline basalts, which are regarded as precursors to spilites. The minerals identified are mainly albitic plagioclase, augite, olivine, and less...

  5. [Comparative carcinogenic properties of basalt fiber and chrysotile-asbestos].

    Science.gov (United States)

    Nikitina, O V; Kogan, F M; Vanchugova, N N; Frash, V N

    1989-01-01

    In order to eliminate asbestos adverse effect on workers' health it was necessary to use mineral rayon, primarily basalt fibre, instead of asbestos. During a chronic experiment on animals the oncogenicity of 2 kinds of basalt fibre was studied compared to chrysotile asbestos. The dust dose of 25 mg was twice administered by intraperitonial route. All types of dust induced the onset of intraperitonial mesotheliomas but neoplasm rates were significantly lower in the groups exposed to basalt fibre. There was no credible data on the differences between the groups exposed to various types of basalt fibre. Since the latter produced some oncogenic effect, it was necessary to develop a complex of antidust measures, fully corresponding to the measures adopted for carcinogenic dusts.

  6. Trace Element Abundances in Eucrite Basalts: Enrichment or Depletion?

    Science.gov (United States)

    Castle, N. R.

    2018-05-01

    It is not clear how incompatible trace element (ITE) variation in eucrite basalts originated. Here, mechanisms for relative ITE enrichment or depletion are experimentally evaluated in an attempt to reconcile the Stannern and main group eucrites.

  7. Glass forms for immobilization of Hanford wastes

    International Nuclear Information System (INIS)

    Schulz, W.W.; Dressen, A.L.; Hobbick, C.W.; Babad, H.

    1975-03-01

    Approximately 140 million liters of solid salt cake (mainly NaNO 3 ), produced by evaporation of aged alkaline high-level liquid wastes, will be stored in underground tanks when the present Hanford Waste Management Program is completed in the early 1980's. At this time also, large volumes of various other solid radioactive wastes (sludges, excavated Pu-contaminated soil, and doubly encapsulated 137 CsCl and 90 SrF 2 ) will be stored on the Hanford Reservation. All these solid wastes can be converted to immobile silicate and aluminosilicate glasses of low water leachability by melting them at 1100 0 to 1400 0 C with appropriate amounts of basalt (or sand) and other glass-formers such as B 2 O 3 or CaO. Reviewed in this paper are formulations and other melt conditions used successfully in batch tests to make glasses from actual and synthetic wastes; leachability and other properties of these glasses show them to be satisfactory vehicles for immobilization of the Hanford wastes. (U.S.)

  8. Chemical magnetization when determining Thellier paleointensity experiments in oceanic basalts

    Science.gov (United States)

    Tselebrovskiy, Alexey; Maksimochkin, Valery

    2017-04-01

    The natural remanent magnetization (NRM) of oceanic basalts selected in the rift zones of the Mid-Atlantic Ridge (MAR) and the Red Sea has been explored. Laboratory simulation shows that the thermoremanent magnetization and chemical remanent magnetization (CRM) in oceanic basalts may be separated by using Tellier-Coe experiment. It was found that the rate of CRM destruction is about four times lower than the rate of the partial thermoremanent magnetization formation in Thellier cycles. The blocking temperatures spectrum of chemical component shifted toward higher temperatures in comparison with the spectrum of primary thermoremanent magnetization. It was revealed that the contribution of the chemical components in the NRM increases with the age of oceanic basalts determined with the analysis of the anomalous geomagnetic field (AGF) and spreading theory. CRM is less than 10% at the basalts aged 0.2 million years, less than 50% at basalts aged 0.35 million years, from 60 to 80% at basalts aged 1 million years [1]. Geomagnetic field paleointensity (Hpl) has been determined through the remanent magnetization of basalt samples of different ages related to Brunhes, Matuyama and Gauss periods of the geomagnetic field polarity. The value of the Hpl determined by basalts of the southern segment of MAR is ranged from 17.5 to 42.5 A/m, by the Reykjanes Ridge basalts — from 20.3 to 44 A/m, by the Bouvet Ridge basalts — from 21.7 to 34.1 A/m. VADM values calculated from these data are in good agreement with the international paleointensity database [2] and PISO-1500 model [3]. Literature 1. Maksimochkin V., Tselebrovskiy A., (2015) The influence of the chemical magnetization of oceanic basalts on determining the geomagnetic field paleointensity by the thellier method, moscow university physics bulletin, 70(6):566-576, 2. Perrin, M., E. Schnepp, and V. Shcherbakov (1998), Update of the paleointensity database, Eos Trans. AGU, 79, 198. 3. Channell JET, Xuan C, Hodell DA (2009

  9. Magnesium-rich Basalts on Mercury

    Science.gov (United States)

    Martel, L. M. V.

    2013-05-01

    X-ray and gamma-ray spectrometers on NASA's MESSENGER spacecraft are making key measurements regarding the composition and properties of the surface of Mercury, allowing researchers to more clearly decipher the planet's formation and geologic history. The origin of the igneous rocks in the crust of Mercury is the focus of recent research by Karen Stockstill-Cahill and Tim McCoy (National Museum of Natural History, Smithsonian Institution), along with Larry Nittler and Shoshana Weider (Carnegie Institution of Washington) and Steven Hauck II (Case Western Reserve University). Using the well-known MELTS computer code Stockstill-Cahill and coauthors worked with MESSENGER-derived and rock-analog compositions to constrain petrologic models of the lavas that erupted on the surface of Mercury. Rock analogs included a partial melt of the Indarch meteorite and a range of Mg-rich terrestrial rocks. Their work shows the lavas on Mercury are most similar to terrestrial magnesian basalt (with lowered FeO content). The implications of the modeling are that Mg-rich lavas came from high-temperature sources in Mercury's mantle and erupted at high temperature with exceptionally low viscosity into thinly bedded and laterally extensive flows, concepts open to further evaluation by laboratory experiments and by geologic mapping of Mercury's surface using MESSENGER's imaging system and laser altimeter to document flow features and dimensions.

  10. Basalt FRP Spike Repairing of Wood Beams

    Directory of Open Access Journals (Sweden)

    Luca Righetti

    2015-08-01

    Full Text Available This article describes aspects within an experimental program aimed at improving the structural performance of cracked solid fir-wood beams repaired with Basalt Fiber Reinforced Polymer (BFRP spikes. Fir wood is characterized by its low density, low compression strength, and high level of defects, and it is likely to distort when dried and tends to fail under tension due to the presence of cracks, knots, or grain deviation. The proposed repair technique consists of the insertion of BFRP spikes into timber beams to restore the continuity of cracked sections. The experimental efforts deal with the evaluation of the bending strength and deformation properties of 24 timber beams. An artificially simulated cracking was produced by cutting the wood beams in half or notching. The obtained results for the repaired beams were compared with those of solid undamaged and damaged beams, and increases of beam capacity, bending strength and of modulus of elasticity, and analysis of failure modes was discussed. For notched beams, the application of the BFRP spikes was able to restore the original bending capacity of undamaged beams, while only a small part of the original capacity was recovered for beams that were cut in half.

  11. A SIMS study of lunar 'komatiitic glasses' - Trace element characteristics and possible origin

    Science.gov (United States)

    Shearer, C. K.; Papike, J. J.; Galbreath, K. C.; Wentworth, S. J.; Shimizu, N.

    1990-01-01

    In Apollo 16 regolith breccias, Wentworth and McKay (1988) identified a suite of minute (less than 120 microns) 'komatiitic glass beads'. The wide major element compositional range, and ultra-Mg-prime character of the glasses suggest a variety of possible origins from complex impact processes to complex volcanic processes involving rather unusual and primitive magmatism. The extent of trace element depletion or enrichment in these glasses appears to be correlated to the siderophile character of the element (ionization potential or experimentally determined silicate melt/Fe metal partition coefficients. The ultra-Mg-prime glasses are depleted in Co relative to a bulk Moon Mg/Co exhibited by many lunar samples (volcanic glasses, basalts, regolith breccia, estimated upper mantle). The low Co and high incompatible element concentrations diminish the possibility that these glasses are a product of lunar komatiitic volcanism or impact, excavation, and melting of a very high Mg-prime plutonic unit.

  12. Radiolytic hydrogen production in the subseafloor basaltic aquifer

    Directory of Open Access Journals (Sweden)

    Mary E Dzaugis

    2016-02-01

    Full Text Available Hydrogen (H2 is produced in geological settings by dissociation of water due to radiation from radioactive decay of naturally occurring uranium (238U, 235U, thorium (232Th and potassium (40K. To quantify the potential significance of radiolytic H2 as an electron donor for microbes within the South Pacific subseafloor basaltic aquifer, we use radionuclide concentrations of 43 basalt samples from IODP Expedition 329 to calculate radiolytic H2 production rates in basement fractures. The samples are from three sites with very different basement ages and a wide range of alteration types. U, Th and K concentrations vary by up to an order of magnitude from sample to sample at each site. Comparison of our samples to each other and to the results of previous studies of unaltered East Pacific Rise basalt suggests that significant variations in radionuclide concentrations are due to differences in initial (unaltered basalt concentrations (which can vary between eruptive events and post-emplacement alteration. In our samples, there is no clear relationship between alteration type and calculated radiolytic yields. Local maxima in U, Th, and K produce hotspots of H2 production, causing calculated radiolytic rates to differ by up to a factor of 80 from sample to sample. Fracture width also greatly influences H2 production, where microfractures are hotspots for radiolytic H2 production. For example, H2 production rates normalized to water volume are 190 times higher in 1 μm wide fractures than in fractures that are 10 cm wide. To assess the importance of water radiolysis for microbial communities in subseafloor basaltic aquifers, we compare electron transfer rates from radiolysis to rates from iron oxidation in subseafloor basalt. Radiolysis appears likely to be a more important electron donor source than iron oxidation in old (>10 Ma basement basalt. Radiolytic H2 production in the volume of water adjacent to a square cm of the most radioactive SPG basalt may

  13. Geochemistry of the Potassic Basalts from the Bufumbira Volcanic ...

    African Journals Online (AJOL)

    The various basalts are low in SiO2 wt %, Al2O3 wt % and Na2O wt % but high in MgO wt %, TiO2 wt %, CaO wt %, K2O wt % with K2O/Na2O = 1.08 to 2.07. These are potassic belonging to the kamafugite series. Plots discriminate two geochemical trends corresponding to the picritic and clinopyroxene rich basalts.

  14. Improving iron-enriched basalt with additions of ZrO2 and TiO2

    International Nuclear Information System (INIS)

    Reimann, G.A.; Kong, P.C.

    1993-06-01

    The iron-enriched basalt (IEB) waste form, developed at the Idaho National Engineering Laboratory a decade ago, was modified to IEB4 by adding sufficient ZrO 2 and TiO 2 to develop crystals of zirconolite upon cooling, in addition to the crystals that normally form in a cooling basalt. Zirconolite (CaZrTi 2 O 7 ) is an extremely leach-resistant mineral with a strong affinity for actinides. Zirconolite crystals containing uranium and thorium have been found that have endured more than 2 billion years of natural processes. On this basis, zirconolite was considered to be an ideal host crystal for the actinides contained in transuranic (TRU)-contaminated wastes. Crystals of zirconolite were developed in laboratory melts of IEB4 that contained 5% each of ZrO 2 and TiO 2 and that were slow-cooled in the 1200--1000 degrees C range. When actinide surrogates were added to IEB4, these oxides were incorporated into the crystals of zirconolite rather than precipitating in the residual glass phase. Zirconolite crystals developed in IEB4 should stabilize and immobilize the dilute TRUs in heterogeneous, buried low-level wastes as effectively as this same phase does in the various formulations of Synroc used for the more concentrated TRUs encountered in high-level wastes. Synroc requires hot-pressing equipment, while IEB4 precipitates zirconolite from a cooling basaltic melt

  15. Improving iron-enriched basalt with additions of ZrO{sub 2} and TiO{sub 2}

    Energy Technology Data Exchange (ETDEWEB)

    Reimann, G.A.; Kong, P.C.

    1993-06-01

    The iron-enriched basalt (IEB) waste form, developed at the Idaho National Engineering Laboratory a decade ago, was modified to IEB4 by adding sufficient ZrO{sub 2} and TiO{sub 2} to develop crystals of zirconolite upon cooling, in addition to the crystals that normally form in a cooling basalt. Zirconolite (CaZrTi{sub 2}O{sub 7}) is an extremely leach-resistant mineral with a strong affinity for actinides. Zirconolite crystals containing uranium and thorium have been found that have endured more than 2 billion years of natural processes. On this basis, zirconolite was considered to be an ideal host crystal for the actinides contained in transuranic (TRU)-contaminated wastes. Crystals of zirconolite were developed in laboratory melts of IEB4 that contained 5% each of ZrO{sub 2} and TiO{sub 2} and that were slow-cooled in the 1200--1000{degrees}C range. When actinide surrogates were added to IEB4, these oxides were incorporated into the crystals of zirconolite rather than precipitating in the residual glass phase. Zirconolite crystals developed in IEB4 should stabilize and immobilize the dilute TRUs in heterogeneous, buried low-level wastes as effectively as this same phase does in the various formulations of Synroc used for the more concentrated TRUs encountered in high-level wastes. Synroc requires hot-pressing equipment, while IEB4 precipitates zirconolite from a cooling basaltic melt.

  16. Tools and techniques for developing tephra stratigraphies in lake cores: A case study from the basaltic Auckland Volcanic Field, New Zealand

    Science.gov (United States)

    Hopkins, Jenni L.; Millet, Marc-Alban; Timm, Christian; Wilson, Colin J. N.; Leonard, Graham S.; Palin, J. Michael; Neil, Helen

    2015-09-01

    Probabilistic hazard forecasting for a volcanic region relies on understanding and reconstructing the eruptive record (derived potentially from proximal as well as distal volcanoes). Tephrostratigraphy is commonly used as a reconstructive tool by cross-correlating tephra deposits to create a stratigraphic framework that can be used to assess magnitude-frequency relationships for eruptive histories. When applied to widespread rhyolitic deposits, tephra identifications and correlations have been successful; however, the identification and correlation of basaltic tephras are more problematic. Here, using tephras in drill cores from six maars in the Auckland Volcanic Field (AVF), New Zealand, we show how X-ray density scanning coupled with magnetic susceptibility analysis can be used to accurately and reliably identify basaltic glass shard-bearing horizons in lacustrine sediments and which, when combined with the major and trace element signatures of the tephras, can be used to distinguish primary from reworked layers. After reliably identifying primary vs. reworked basaltic horizons within the cores, we detail an improved method for cross-core correlation based on stratigraphy and geochemical fingerprinting. We present major and trace element data for individual glass shards from 57 separate basaltic horizons identified within the cores. Our results suggest that in cases where major element compositions (SiO2, CaO, Al2O3, FeO, MgO) do not provide unambiguous correlations, trace elements (e.g. La, Gd, Yb, Zr, Nb, Nd) and trace element ratios (e.g. [La/Yb]N, [Gd/Yb]N, [Zr/Yb]N) are successful in improving the compositional distinction between the AVF basaltic tephra horizons, thereby allowing an improved eruptive history of the AVF to be reconstructed.

  17. CRYSTALLIZATION IN MULTICOMPONENT GLASSES

    Energy Technology Data Exchange (ETDEWEB)

    KRUGER AA; HRMA PR

    2009-10-08

    In glass processing situations involving glass crystallization, various crystalline forms nucleate, grow, and dissolve, typically in a nonuniform temperature field of molten glass subjected to convection. Nuclear waste glasses are remarkable examples of multicomponent vitrified mixtures involving partial crystallization. In the glass melter, crystals form and dissolve during batch-to-glass conversion, melter processing, and product cooling. Crystals often agglomerate and sink, and they may settle at the melter bottom. Within the body of cooling glass, multiple phases crystallize in a non-uniform time-dependent temperature field. Self-organizing periodic distribution (the Liesegnang effect) is common. Various crystallization phenomena that occur in glass making are reviewed.

  18. Crystallization In Multicomponent Glasses

    International Nuclear Information System (INIS)

    Kruger, A.A.; Hrma, P.R.

    2009-01-01

    In glass processing situations involving glass crystallization, various crystalline forms nucleate, grow, and dissolve, typically in a nonuniform temperature field of molten glass subjected to convection. Nuclear waste glasses are remarkable examples of multicomponent vitrified mixtures involving partial crystallization. In the glass melter, crystals form and dissolve during batch-to-glass conversion, melter processing, and product cooling. Crystals often agglomerate and sink, and they may settle at the melter bottom. Within the body of cooling glass, multiple phases crystallize in a non-uniform time-dependent temperature field. Self-organizing periodic distribution (the Liesegnang effect) is common. Various crystallization phenomena that occur in glass making are reviewed.

  19. Historical volcanic eruptions in the Canary Islands, tephra composition, and insights into the crystal cargo of basaltic magmas

    Science.gov (United States)

    Longpre, M. A.; Muller, J.; Beaudry, P.; Andronikides, A.; Felpeto, A.

    2017-12-01

    Since the 16th century, at least 13 volcanic eruptions have occurred in the Canary Islands that formed monogenetic cinder cones and lava flow fields: 2 on Lanzarote, 4 on Tenerife, 6 on La Palma, and 1 on the submarine flank of El Hierro. Here we present a comprehensive new dataset of tephra composition for all 13 eruptions, comprising major and trace element data for bulk rocks and matrix glasses, as well as vesicularity and crystallinity measurements. In addition, we compile available volcanological and petrological information for specific eruptions, including estimates of lava flow area and volume. All lapilli samples show a vesicularity of 40-50 vol% and a vesicle-free crystallinity (crystals ≥ 250 µm) of 5-15 vol%. Modal mineralogy varies significantly between samples, typically consisting of olivine ± clinopyroxene ± Fe-Ti oxide ± plagioclase ± amphibole in different proportions. All but 2 tephras have basanite-tephrite bulk rock compositions. Lapilli from vents of the AD 1730-1736 Timanfaya eruption, Lanzarote, largely are basaltic, whereas the AD 1798 Chahorra eruption, Tenerife, produced phonotephrite tephra. These results are in agreement with published bulk lava flow data. Unsurprisingly, glass compositions are more evolved than bulk rocks and MgOglass is weakly positively correlated to MgObulk (MgOglass = 0.30*MgObulk + 2.11, R2 = 0.54). Both bulk rocks and glasses show strikingly similar multi-element diagram patterns, with strong enrichment relative to the bulk-silicate Earth and marked positive Nb and Ta and negative Pb anomalies — typical for ocean island basalts. Glass/bulk rock elemental ratios reveal systematic differences between samples that relate to their mineralogy; for example, Lanzarote tephras that lack significant clinopyroxene and Fe-Ti oxide crystals have higher Scglass/Scbulk and Vglass/Vbulk than Tenerife, La Palma and El Hierro samples that typically contain these minerals. Among all elements, K and P display the greatest

  20. Summary of INEL research on the iron-enriched basalt waste form

    International Nuclear Information System (INIS)

    Reimann, G.A.; Grandy, J.D.; Eddy, T.L.; Anderson, G.L.

    1992-01-01

    This report summarizes the knowledge base on the iron-enriched basalt (IEB) waste form developed at the Idaho National Engineering Laboratory (INEL) during 1979--1982. The results presented discuss the applicability of IEB in converting retrieved transuranic (TRU) waste from INEL's Radioactive Waste Management Complex (RWMC) into a vitreous/ceramic (glassy/rock) stable waste form suitable for permanent disposal in an appropriate repository, such as the Waste Isolation Pilot Plant (WIPP) in New Mexico. Borosilicate glass (BSG), the approved high-level waste form, appears unsuited for this application. Melting the average waste-soil mix from the RWMC produces the IEB composition and attempting to convert IEB to the BSG composition would require additions of substantial B 2 0 3 , Na, and SiO 2 (glass frit). IEB requires processing temperatures of 1400 to 1600 degrees C, depending upon the waste composition. Production of the IEB waste form, using Joule heated melters, has proved difficult in the past because of electrode and refractory corrosion problems associated with the high temperature melts. Higher temperature electric melters (arc and plasma) are available to produce this final waste form. Past research focused on extensive slag property measurements, waste form leachability tests, mechanical, composition, and microstructure evaluations, as well as a host of experiments to improve production of the waste form. Past INEL studies indicated that the IEB glass-ceramic is a material that will accommodate and stabilize a wide range of heterogeneous waste materials, including long lived radionuclides and scrap metals, while maintaining a superior level of chemical and physical performance characteristics. Controlled cooling of the molten IEB and subsequent heat treatment will produce a glass-ceramic waste form with superior leach resistance

  1. Recycling of Glass

    DEFF Research Database (Denmark)

    Christensen, Thomas Højlund; Damgaard, Anders

    2011-01-01

    Glass is used for many purposes, but in the waste system glass is predominantly found in terms of beverage and food containers with a relatively short lifetime before ending up in the waste. Furthermore there is a large amount of flat glass used in building materials which also ends up in the waste...... system; this glass though has a long lifetime before ending up in the waste. Altogether these product types add up to 82% of the production of the European glass industry (IPCC, 2001). Recycling of glass in terms of cleaning and refilling of bottles as well as the use of broken glass in the production...... of new glass containers is well established in the glass industry. This chapter describes briefly howglass is produced and howwaste glass is recycled in the industry. Quality requirements and use of recycled products are discussed, as are the resource and environmental issues of glass recycling....

  2. Icelandic basaltic geothermal field: A natural analog for nuclear waste isolation in basalt

    International Nuclear Information System (INIS)

    Ulmer, G.C.; Grandstaff, D.E.

    1984-01-01

    Analog studies of Icelandic geothermal fields have shown that the design of nuclear waste repositories in basalt can benefit by comparison to the data base already available from the development of these geothermal fields. A high degree of similarity exists between these two systems: their petrology, groundwater geochemistry, mineral solubilities, hydrologic parameters, temperature ranges, water-rock redox equilibria, hydrothermal pH values, and secondary mineralogies all show considerable overlap in the range of values. The experimentally-simulated hydrothermal studies of the basaltic nuclear waste repository rocks have, at this time, produced a data base that receives a strong confirmation from the Icelandic analog. Furthermore, the Icelandic analog should eventually be employed to extrapolate into higher and lower temperatures, into longer time-base chemical comparisons, and into more realistic mineral deposition studies, than have been possible in the laboratory evaluations of the nuclear waste repository designs. This eventual use of the Icelandic analog will require cooperative work with the Icelandic Geological Survey. 46 refs., 4 figs., 2 tabs

  3. Geomechanical rock properties of a basaltic volcano

    Directory of Open Access Journals (Sweden)

    Lauren N Schaefer

    2015-06-01

    Full Text Available In volcanic regions, reliable estimates of mechanical properties for specific volcanic events such as cyclic inflation-deflation cycles by magmatic intrusions, thermal stressing, and high temperatures are crucial for building accurate models of volcanic phenomena. This study focuses on the challenge of characterizing volcanic materials for the numerical analyses of such events. To do this, we evaluated the physical (porosity, permeability and mechanical (strength properties of basaltic rocks at Pacaya Volcano (Guatemala through a variety of laboratory experiments, including: room temperature, high temperature (935 °C, and cyclically-loaded uniaxial compressive strength tests on as-collected and thermally-treated rock samples. Knowledge of the material response to such varied stressing conditions is necessary to analyze potential hazards at Pacaya, whose persistent activity has led to 13 evacuations of towns near the volcano since 1987. The rocks show a non-linear relationship between permeability and porosity, which relates to the importance of the crack network connecting the vesicles in these rocks. Here we show that strength not only decreases with porosity and permeability, but also with prolonged stressing (i.e., at lower strain rates and upon cooling. Complimentary tests in which cyclic episodes of thermal or load stressing showed no systematic weakening of the material on the scale of our experiments. Most importantly, we show the extremely heterogeneous nature of volcanic edifices that arise from differences in porosity and permeability of the local lithologies, the limited lateral extent of lava flows, and the scars of previous collapse events. Input of these process-specific rock behaviors into slope stability and deformation models can change the resultant hazard analysis. We anticipate that an increased parameterization of rock properties will improve mitigation power.

  4. Complex layering of the Orange Mountain Basalt: New Jersey, USA

    Science.gov (United States)

    Puffer, John H.; Block, Karin A.; Steiner, Jeffrey C.; Laskowich, Chris

    2018-06-01

    The Orange Mountain Basalt of New Jersey is a Mesozoic formation consisting of three units: a single lower inflated sheet lobe about 70 m thick (OMB1), a middle pillow basalt about 10 to 20 m thick (OMB2), and an upper compound pahoehoe flow about 20 to 40 m thick (OMB3). The Orange Mountain Basalt is part of the Central Atlantic Magmatic Province. Quarry and road-cut exposures of OMB1 near Paterson, New Jersey, display some unusual layering that is the focus of this study. OMB1 exposures displays the typical upper crust, core, and basal crust layers of sheet lobes but throughout the Patterson area also display distinct light gray layers of microvesicular basalt mineralized with albite directly over the basal crust and under the upper crust. The lower microvesicular layer is associated with mega-vesicular diapirs. We propose that the upper and lower microvesicular layers were composed of viscous crust that was suddenly quenched before it could devolatilize immediately before the solidification of the core. During initial cooling, the bottom of the basal layer was mineralized with high concentrations of calcite and albite during a high-temperature hydrothermal event. Subsequent albitization, as well as zeolite, prehnite, and calcite precipitation events, occurred during burial and circulation of basin brine heated by recurring Palisades magmatism below the Orange Mountain Basalt. Some of the events experienced by the Orange Mountain Basalt are unusual and place constraints on the fluid dynamics of thick flood basalt flows in general. The late penetration of vesicular diapirs through the entire thickness of the flow interior constrains its viscosity and solidification history.

  5. Surface oxidization-reduction reactions in Columbia Plateau basalts

    International Nuclear Information System (INIS)

    White, A.F.; Yee, A.

    1984-01-01

    Results are presented which define principal oxidation-reduction reactions expected between ground water and iron in the Umtanum and Cohassett basalt flows of south central Washington. Data include kinetics of aqueous iron speciation, rates of O 2 uptake and nature of oxyhydroxide precipitates. Such data are important in predicting behavior of radionuclides in basalt aquifers including determination of valence states, speciation, solubility, sorption, and coprecipitation on iron oxyhydroxide substrates and colloids. Analyses of the basalt by XPS indicates that ferrous iron is oxidized to ferric iron on the surface and that the total iron decreases as a function of pH during experimental weathering. Iron oxyhydroxide phases did not form surface coating on basalt surfaces but rather nucleated as separate plases in solution. No significant increases in Cs or Sr sorption were observed with increased weathering of the basalt. Concurrent increases in Fe(II) and decreases in Fe(III) in slightly to moderately acid solutions indicated continued oxidization of ferrous iron in the basalt. At neutral to basic pH, Fe(II) was strongly sorbed onto the basalt surface (Kd = 6.5 x 10 -3 1 x m 2 ) resulting in low dissolved concentrations even under anoxic conditions. The rate of O 2 uptake increased with decreasing pH. Diffusion rates (-- 10 -14 cm 2 x s -1 ), calculated using a one-dimensional analytical model, indicate grain boundary diffusion. Comparisons of Eh values calculated by Pt electrode, dissolved O 2 and Fe(II)/Fe(III) measurements showed considerable divergence, with the ferric-ferrous couple being the preferred method of estimating Eh

  6. Spin glasses

    International Nuclear Information System (INIS)

    Mookerjee, Abhijit

    1976-01-01

    ''Spin glasses'', are entire class of magnetic alloys of moderate dilution, in which the magnetic atoms are far enough apart to be unlike the pure metal, but close enough so that the indirect exchange energy between them (mediated by the s-d interaction between local moments and conduction electrons) dominates all other energies. Characteristic critical phenomena displayed such as freezing of spin orientation at 'Tsub(c)' and spreading of magnetic ordering, are pointed out. Anomalous behaviour, associated with these critical phenomena, as reflected in : (i) Moessbauer spectroscopy giving hyperfine splitting at Tsub(c), (ii) maxima in susceptibility and remanent magnetism, (iii) thermopower maxima and change in slope, (iv) Characteristic cusp in susceptibility and its removal by very small magnetic fields, and (v) conductivity-resistivity measurements, are discussed. Theoretical developments aimed at explaining these phenomena, in particular, the ideas from percolation and localisation theories, and the approach based on the gellations of polymers, are discussed. Finally, a new approach based on renormalisation group in disordered systems is also briefly mentioned. (K.B.)

  7. Immobilization of transuranic sludge in glass-ceramic materials

    International Nuclear Information System (INIS)

    Welch, J.M.; Schuman, R.P.; Flinn, J.E.

    1982-03-01

    Studies were performed to determine the effectiveness of glass-ceramic waste forms, particularly iron-enriched basalt, for immobilizing transuranic waste sludges from the Rocky Flats plant operations. Two sludges were used in the study - one was nonradioactive and the other contained approx. 2200 dps/mg of 241 Am. The glass-ceramic waste forms were produced from laboratory-scale melting operations with subsequent controlled cooling. The waste forms were examined to assess the microstructures which resulted from systematically varied compositions and controlled cooling sequences. Leach tests in deionized water were performed on small monolithic specimens of the various glass-ceramic materials. The test results showed a rather strong temperature dependence for leach rates. Also, for some of these materials, marked differences in the 241 Am leaching behavior were seen in measurements obtained on acidified versus neutral aliquots of the spent leachates. 8 figures, 12 tables

  8. Preliminary Hydrogeologic Characterization Results from the Wallula Basalt Pilot Study

    Energy Technology Data Exchange (ETDEWEB)

    B.P. McGrail; E. C. Sullivan; F. A. Spane; D. H. Bacon; G. Hund; P. D. Thorne; C. J. Thompson; S. P. Reidel; F. S. Colwell

    2009-12-01

    The DOE's Big Sky Regional Carbon Sequestration Partnership has completed drilling the first continental flood basalt sequestration pilot borehole to a total depth (TD) of 4,110 feet on the Boise White Paper Mill property at Wallula, Washington. Site suitability was assessed prior to drilling by the 2007-2008 acquisition, processing and analysis of a four-mile, five-line three component seismic swath, which was processed as a single data-dense line. Analysis of the seismic survey data indicated a composite basalt formation thickness of {approx}8,000 feet and absence of major geologic structures (i.e., faults) along the line imaged by the seismic swath. Drilling of Wallula pilot borehole was initiated on January 13, 2009 and reached TD on April 6, 2009. Based on characterization results obtained during drilling, three basalt breccia zones were identified between the depth interval of 2,716 and 2,910 feet, as being suitable injection reservoir for a subsequent CO2 injection pilot study. The targeted injection reservoir lies stratigraphically below the massive Umtanum Member of the Grande Ronde Basalt, whose flow-interior section possesses regionally recognized low-permeability characteristics. The identified composite injection zone reservoir provides a unique and attractive opportunity to scientifically study the reservoir behavior of three inter-connected reservoir intervals below primary and secondary caprock confining zones. Drill cuttings, wireline geophysical logs, and 31one-inch diameter rotary sidewall cores provided geologic data for characterization of rock properties. XRF analyses of selected rock samples provided geochemical characterizations of the rocks and stratigraphic control for the basalt flows encountered by the Wallula pilot borehole. Based on the geochemical results, the pilot borehole was terminated in the Wapshilla Ridge 1 flow of the Grande Ronde Basalt Formation. Detailed hydrologic test characterizations of 12 basalt interflow

  9. 3D architecture of cyclic-step and antidune deposits in glacigenic subaqueous fan and delta settings: Integrating outcrop and ground-penetrating radar data

    Science.gov (United States)

    Lang, Jörg; Sievers, Julian; Loewer, Markus; Igel, Jan; Winsemann, Jutta

    2017-12-01

    Bedforms related to supercritical flows are increasingly recognised as important constituents of many depositional environments, but outcrop studies are commonly hampered by long bedform wavelengths and complex three-dimensional geometries. We combined outcrop-based facies analysis with ground-penetrating radar (GPR) surveys to analyse the 3D facies architecture of subaqueous ice-contact fan and glacifluvial delta deposits. The studied sedimentary systems were deposited at the margins of the Middle Pleistocene Scandinavian ice sheets in Northern Germany. Glacifluvial Gilbert-type deltas are characterised by steeply dipping foreset beds, comprising cyclic-step deposits, which alternate with antidune deposits. Deposits of cyclic steps consist of lenticular scours infilled by backset cross-stratified pebbly sand and gravel. The GPR sections show that the scour fills form trains along the delta foresets, which can locally be traced for up to 15 m. Perpendicular and oblique to palaeoflow direction, these deposits appear as troughs with concentric or low-angle cross-stratified infills. Downflow transitions from scour fills into sheet-like low-angle cross-stratified or sinusoidally stratified pebbly sand, deposited by antidunes, are common. Cyclic steps and antidunes were deposited by sustained and surge-type supercritical density flows, which were related to hyperpycnal flows, triggered by major meltwater discharge or slope-failure events. Subaqueous ice-contact fan deposits include deposits of progradational scour fills, isolated hydraulic jumps, antidunes and (humpback) dunes. The gravel-rich fan succession consists of vertical stacks of laterally amalgamated pseudo-sheets, indicating deposition by pulses of waning supercritical flows under high aggradation rates. The GPR sections reveal the large-scale architecture of the sand-rich fan succession, which is characterised by lobe elements with basal erosional surfaces associated with scours filled with backsets related

  10. Diffusion of hydrous species in model basaltic melt

    Science.gov (United States)

    Zhang, Li; Guo, Xuan; Wang, Qinxia; Ding, Jiale; Ni, Huaiwei

    2017-10-01

    Water diffusion in Fe-free model basaltic melt with up to 2 wt% H2O was investigated at 1658-1846 K and 1 GPa in piston-cylinder apparatus using both hydration and diffusion couple techniques. Diffusion profiles measured by FTIR are consistent with a model in which both molecular H2O (H2Om) and hydroxyl (OH) contribute to water diffusion. OH diffusivity is roughly 13% of H2Om diffusivity, showing little dependence on temperature or water concentration. Water diffusion is dominated by the motion of OH until total H2O (H2Ot) concentration reaches 1 wt%. The dependence of apparent H2Ot diffusivity on H2Ot concentration appears to be overestimated by a previous study on MORB melt, but H2Ot diffusivity at 1 wt% H2Ot in basaltic melt is still greater than those in rhyolitic to andesitic melts. The appreciable contribution of OH to water diffusion in basaltic melt can be explained by enhanced mobility of OH, probably associated with the development of free hydroxyl bonded with network-modifying cations, as well as higher OH concentration. Calculation based on the Nernst-Einstein equation demonstrates that OH may serve as an effective charge carrier in hydrous basaltic melt, which could partly account for the previously observed strong influence of water on electrical conductivity of basaltic melt.

  11. Stratigraphy of Oceanus Procellarum basalts - Sources and styles of emplacement

    Science.gov (United States)

    Whitford-Stark, J. L.; Head, J. W., III

    1980-01-01

    The basaltic fill of Oceanus Procellarum has been formally subdivided into four lithostratigraphic formations: The Repsold Formation, the Telemann Formation, the Hermann Formation, and the Sharp Formation. The Repsold Formation is composed of high-Ti basalts and pyroclastic deposits with an estimated age of 3.75 + or - 0.05 b.y. and an estimated volume of about 2.1 x 10 to the 5th cu km. This is overlain by the Telemann Formation composed of very low-Ti basalts and pyroclastic deposits with an estimated age of 3.6 + or - 0.2 b.y. and a volume of 4.2 x 10 to the 5th cu km. The Hermann Formation, composed of intermediate basalts with an estimated age of 3.3 + or - 0.3 b.y., represents the next youngest unit with an estimated volume of 2.2 x 10 to the 5th cu km. The youngest materials in Procellarum are the medium-to-high-Ti basalts comprising the Sharp Formation with an estimated age of 2.7 + or - 0.7 b.y. and a volume of 1.8 x 10 to the 4th cu km.

  12. Similar microbial communities found on two distant seafloor basalts

    Directory of Open Access Journals (Sweden)

    Esther eSinger

    2015-12-01

    Full Text Available The oceanic crust forms two thirds of the Earth’s surface and hosts a large phylogenetic and functional diversity of microorganisms. While advances have been made in the sedimentary realm, our understanding of the igneous rock portion as a microbial habitat has remained limited. We present the first comparative metagenomic microbial community analysis from ocean floor basalt environments at the Lō’ihi Seamount, Hawai’i, and the East Pacific Rise (EPR (9˚N. Phylogenetic analysis indicates the presence of a total of 43 bacterial and archaeal mono-phyletic groups, dominated by Alpha- and Gammaproteobacteria, as well as Thaumarchaeota. Functional gene analysis suggests that these Thaumarchaeota play an important role in ammonium oxidation on seafloor basalts. In addition to ammonium oxidation, the seafloor basalt habitat reveals a wide spectrum of other metabolic potentials, including CO2 fixation, denitrification, dissimilatory sulfate reduction, and sulfur oxidation. Basalt communities from Lō’ihi and the EPR show considerable metabolic and phylogenetic overlap down to the genus level despite geographic distance and slightly different seafloor basalt mineralogy.

  13. Anomalous density and elastic properties of basalt at high pressure: Reevaluating of the effect of melt fraction on seismic velocity in the Earth's crust and upper mantle

    Science.gov (United States)

    Clark, Alisha N.; Lesher, Charles E.; Jacobsen, Steven D.; Wang, Yanbin

    2016-06-01

    Independent measurements of the volumetric and elastic properties of Columbia River basalt glass were made up to 5.5 GPa by high-pressure X-ray microtomography and GHz-ultrasonic interferometry, respectively. The Columbia River basalt displays P and S wave velocity minima at 4.5 and 5 GPa, respectively, violating Birch's law. These data constrain the pressure dependence of the density and elastic moduli at high pressure, which cannot be modeled through usual equations of state nor determined by stepwise integrating the bulk sound velocity as is common practice. We propose a systematic variation in compression behavior of silicate glasses that is dependent on the degree of polymerization and arises from the flexibility of the aluminosilicate network. This behavior likely persists into the liquid state for basaltic melts resulting in weak pressure dependence for P wave velocities perhaps to depths of the transition zone. Modeling the effect of partial melt on P wave velocity reductions suggests that melt fraction determined by seismic velocity variations may be significantly overestimated in the crust and upper mantle.

  14. Thermal history of Hawaiian pāhoehoe lava crusts at the glass transition: implications for flow rheology and emplacement

    Science.gov (United States)

    Gottsmann, Joachim; Harris, Andrew J. L.; Dingwell, Donald B.

    2004-12-01

    We have investigated the thermal history of glassy pāhoehoe crusts across their glass transition. Ten different samples obtained between 1993 and 2003 from the active flow field of the Pu'u 'O'o-Kupaianaha eruption on Hawaii (USA) have been analysed using relaxation geospeedometry. This method employs differential scanning calorimetry to quantify the enthalpic relaxation of the glass to monitor the natural time-temperature (t-T) path followed by the melt during cooling across its glass transition. Cooling rates across the glass transition interval (at 1000- 900 K) have been found to vary between 8 and 140 K/min. The associated glass transition temperatures are up to 400 K, lower than previously anticipated by others. Melt viscosities at the glass transition for these crusts range from 10 9.4 to 10 10.7 Pa s. We have compared the t-T paths quantified via relaxation geospeedometry with those obtained from direct measurements on the active flow field. The calorimetrically determined cooling rates are consistent with either simple cooling from eruption temperatures to temperatures below the glass transition or more complex cooling paths, including periods of reheating and short-term annealing within the glass transition interval. By quantifying the relaxation times associated with these contrasting cooling histories, we show that secondary vesiculation of pāhoehoe flow crusts may be favoured by complex, nonlinear t-T paths within the glass transition. These constraints also allow us to evaluate the time scales associated with the crystallisation and inflation of flow lobes at the glass transition for different pāhoehoe lava flow types. Our results provide important quantifications of rheological parameters at the lower temperature range of viscoelastic deformation in basaltic lava flows. As such, the results may be helpful in refining models for the generation of continental flood basalt flows, as well as models of basaltic lava flow propagation for hazard

  15. High water content in primitive continental flood basalts.

    Science.gov (United States)

    Xia, Qun-Ke; Bi, Yao; Li, Pei; Tian, Wei; Wei, Xun; Chen, Han-Lin

    2016-05-04

    As the main constituent of large igneous provinces, the generation of continental flood basalts (CFB) that are characterized by huge eruption volume (>10(5) km(3)) within short time span (primitive CFB in the early Permian Tarim large igneous province (NW China), using the H2O content of ten early-formed clinopyroxene (cpx) crystals that recorded the composition of the primitive Tarim basaltic melts and the partition coefficient of H2O between cpx and basaltic melt. The arc-like H2O content (4.82 ± 1.00 wt.%) provides the first clear evidence that H2O plays an important role in the generation of CFB.

  16. Corrosion phase formation on container alloys in basalt repository environments

    International Nuclear Information System (INIS)

    Johnston, R.G.; Anantatmula, R.P.; Lutton, J.M.; Rivera, C.L.

    1986-01-01

    The Basalt Waste Isolation Project is evaluating the suitability of basalt in southeastern Washington State as a possible location for a nuclear waste repository. The performance of the waste package, which includes the waste form, container, and surrounding packing material, will be affected by the stability of container alloys in the repository environment. Primary corrosion phases and altered packing material containing metals leached from the container may also influence subsequent reactions between the waste form and repository environment. Copper- and iron-based alloys were tested at 50 0 to 300 0 C in an air/steam environment and in pressure vessels in ground-water-saturated basalt-bentonite packing material. Reaction phases formed on the alloys were identified and corrosion rates were measured. Changes in adhering packing material were also evaluated. The observed reactions and their possible effects on container alloy durability in the repository are discussed

  17. Regional basalt hydrology of the Columbia Plateau in Washington

    International Nuclear Information System (INIS)

    Tanaka, H.; Barrett, G.; Wildrick, L.

    1979-10-01

    This study is part of the Basalt Waste Isolation Project, operated for the US Department of Energy by Rockwell Hanford Operations. The overall purpose of the study is to assess locations within the Columbia River Basalt Group beneath the Hanford Site in south-central Washington suitable for a geologic repository for radioactive waste. This hydrologic study was made to describe the hydrologic characteristics of the basalt units of the Columbia Plateau. This was done by comprehensive data compilation, data interpretation and analysis. Data are presented in the form of maps and tables suitable as input information about the regional hydrology for possible future analysis by computer models. The report includes: an introduction; basic data; interpretation which covers stratigraphic trend surface, water levels, transmissivity and storage of aquifers, recharge, discharge, flow, subbasins, cross sections, references and appendix of record of wells

  18. Corrosion and tribological properties of basalt fiber reinforced composite materials

    Science.gov (United States)

    Ha, Jin Cheol; Kim, Yun-Hae; Lee, Myeong-Hoon; Moon, Kyung-Man; Park, Se-Ho

    2015-03-01

    This experiment has examined the corrosion and tribological properties of basalt fiber reinforced composite materials. There were slight changes of weight after the occurring of corrosion based on time and H2SO4 concentration, but in general, the weight increased. It is assumed that this happens due to the basalt fiber precipitate. Prior to the corrosion, friction-wear behavior showed irregular patterns compared to metallic materials, and when it was compared with the behavior after the corrosion, the coefficient of friction was 2 to 3 times greater. The coefficient of friction of all test specimen ranged from 0.1 to 0.2. Such a result has proven that the basalt fiber, similar to the resin rubber, shows regular patterns regardless of time and H2SO4 concentration because of the space made between resins and reinforced materials.

  19. A simple way to constrain the stoichiometry of secondary smectites upon aqueous glass alteration

    International Nuclear Information System (INIS)

    Thien, Bruno M.J.

    2014-01-01

    Highlights: • Si/Al of different glasses were compared to Si/Al of associated secondary smectites. • Si/Al of secondary smectite is nearly equal to Si/Al of parent glass. • This is a simple way which can help to constrain smectite composition. • Accurate smectite composition cannot be measured in many cases. - Abstract: The comparison of the stoichiometry of several nuclear waste glasses and basaltic glasses with their associated secondary smectites evidenced that Si/Al ratios of secondary smectites are nearly equal to the Si/Al ratios of parent glasses. This information may be very useful in constraining secondary smectites structure and stoichiometry in cases where other identification methods are difficult to apply

  20. On causal links between flood basalts and continental breakup

    Science.gov (United States)

    Courtillot, V.; Jaupart, C.; Manighetti, I.; Tapponnier, P.; Besse, J.

    1999-03-01

    Temporal coincidence between continental flood basalts and breakup has been noted for almost three decades. Eight major continental flood basalts have been produced over the last 300 Ma. The most recent, the Ethiopian traps, erupted in about 1 Myr at 30 Ma. Rifting in the Red Sea and Gulf of Aden, and possibly East African rift started at about the same time. A second trap-like episode occurred around 2 Ma and formation of true oceanic crust is due in the next few Myr. We find similar relationships for the 60 Ma Greenland traps and opening of the North Atlantic, 65 Ma Deccan traps and opening of the NW Indian Ocean, 132 Ma Parana traps and South Atlantic, 184 Ma Karoo traps and SW Indian Ocean, and 200 Ma Central Atlantic Margin flood basalts and opening of the Central Atlantic Ocean. The 250 Ma Siberian and 258 Ma Emeishan traps seem to correlate with major, if aborted, phases of rifting. Rifting asymmetry, apparent triple junctions and rift propagation (towards the flood basalt area) are common features that may, together with the relative timings of flood basalt, seaward dipping reflector and oceanic crust production, depend on a number of plume- and lithosphere- related factors. We propose a mixed scenario of `active/passive' rifting to account for these observations. In all cases, an active component (a plume and resulting flood basalt) is a pre-requisite for the breakup of a major oceanic basin. But rifting must be allowed by plate-boundary forces and is influenced by pre-existing heterogeneities in lithospheric structure. The best example is the Atlantic Ocean, whose large-scale geometry with three large basins was imposed by the impact points of three mantle plumes.

  1. Technetium and neptunium reactions in basalt/groundwater systems

    International Nuclear Information System (INIS)

    Meyer, R.E.; Arnold, W.D.; Kelmers, A.D.; Kessler, J.H.; Clark, R.J.; Johnson, J.S. Jr.; Young, G.C.; Case, F.I.; Westmoreland, C.G.

    1985-01-01

    Sorption isotherms and apparent concentration limits for Tc(VII) and Np(V) for a variety of groundwater/basalt systems were determined using Grande Ronde basalt samples representative of the Hanford Site candidate high-level waste repository. Under oxic redox conditions (air present), little or no sorption of technetium was observed; neptunium exhibited low to moderate sorption ratios. Under anoxic redox conditions (oxygen-free), low to moderate sorption of technetium was often observed, but the extent of sorption was highly dependent upon the groundwater composition and the method of pretreatment (if any) of the basalt. Sorption isotherms for technetium under reducing redox conditions (hydrazine added) indicate an apparent concentration limit of approximately 10 -6 mol/l Tc. No apparent concentration limit was found for neptunium for concentrations in groundwater up to 10 -6 mol/l and 8 x 10 -7 mol/l under oxic and reducing (hydrazine added) redox conditions, respectively. Valence control and valence analysis experiments suggest that the sorption or precipitation of Tc and Np from groundwater in the presence of basalt may result from a heterogeneous reaction occurring on the surface of the basalt. One of the critical factors of this reduction reaction appears to be the accessibility of the reactive ferrous iron component of the basalt. The laboratory simulation of groundwater redox conditions representative of the repository environment through the use of solution phase redox reagents is of questionable validity, and information obtained by such experimental methods may not be defensible for site performance assessment calculations. Anoxic experiments conducted in an argon-filled glove box appear better suited for the laboratory simulation of in situ redox conditions. 15 references, 6 figures

  2. Technetium and neptunium reactions in basalt/groundwater systems

    International Nuclear Information System (INIS)

    Meyer, R.E.; Arnold, W.D.; Kelmers, A.D.; Kessler, J.H.; Clark, R.J.; Johnson, J.S. Jr.; Young, G.C.; Case, F.I.; Westmoreland, C.G.; Florida State Univ., Tallahassee)

    1984-01-01

    Sorption isotherms and apparent concentration limits for Tc(VII) and Np(V) for a variety of groundwater/basalt systems were determined using Grande Ronde basalt samples representative of the Hanford Site candidate high-level waste repository. Under oxic redox conditions (air present), little or no sorption of technetium was observed; neptunium exhibited low to moderate sorption ratios. Under anoxic redox conditions (oxygen-free), low to moderate sorption of technetium was often observed, but the extent of sorption was highly dependent upon the groundwater composition and the method of pretreatment (if any) of the basalt. Sorption isotherms for technetium under reducing redox conditions (hydrazine added) indicate an apparent concentration limit of approximately 10 -6 mol/L Tc. No apparent concentration limit was found for neptunium for concentrations in groundwater up to approx. 10 -6 mol/L and 8 x 10 -7 mol/L under oxic and reducing (hydrazine added) redox conditions, respectively. Valence control and valence analysis experiments suggest that the sorption or precipitation of Tc and Np from groundwater in the presence of basalt may result from a heterogeneous reaction occurring on the surface of the basalt. One of the critical factors of this reduction reaction appears to be the accessibility of the reactive ferrous iron component of the basalt. The laboratory simulation of groundwater redox conditions representative of the repository environment through the use of solution phase redox reagents is of questionable validity, and information obtained by such experimental methods may not be defensible for site performance assessment calculations. Anoxic experiments conducted in an argon-filled glove box appear better suited for the laboratory simulation of in situ redox conditions. 15 refs., 6 tabs

  3. Distribution and stratigraphy of basaltic units in Maria Tranquillitatis and Fecunditatis: A Clementine perspective

    Science.gov (United States)

    Rajmon, D.; Spudis, P.

    2004-01-01

    Maria Tranquillitatis and Fecunditatis have been mapped based on Clementine image mosaics and derived iron and titanium maps. Impact craters served as stratigraphic probes enabling better delineation of compositionally different basaltic units, determining the distribution of subsurface basalts, and providing estimates of total basalt thickness and the thickness of the surface units. Collected data indicate that volcanism in these maria started with the eruption of low-Ti basalts and evolved toward medium- and high-Ti basalts. Some of the high-Ti basalts in Mare Tranquillitatis began erupting early and were contemporaneous with the low- and medium-Ti basalts; these units form the oldest units exposed on the mare surface. Mare Tranquillitatis is mostly covered with high- Ti basalts. In Mare Fecunditatis, the volume of erupting basalts clearly decreased as the Ti content increased, and the high-Ti basalts occur as a few patches on the mare surface. The basalt in both maria is on the order of several hundred meters thick and locally may be as thick as 1600 m. The new basalt thickness estimates generally fall within the range set by earlier studies, although locally differ. The medium- to high-Ti basalts exposed at the surfaces of both maria are meters to tens of meters thick.

  4. Retention of aqueous {sup 226}Ra fluxes from a sub-aqueous mill tailings disposal at the Bois Noirs site (Loire, France)

    Energy Technology Data Exchange (ETDEWEB)

    Courbet, Christelle; Simonucci, Caroline; Dauzeres, Alexandre; Matray, Jean-Michel [French Institute for Radiation protection and Nuclear Safety - IRSN, Radiation Protection Division - PRP, Nuclear Waste and Geosphere Department - DGE, SRTG/LETIS, B.P. 17, 92262 Fontenay-Aux-Roses (France); Bassot, Sylvain [French Institute for Radiation protection and Nuclear Safety - IRSN, Radiation Protection Division - PRP, Nuclear Waste and Geosphere Department - DGE, SRTG/LAME, B.P. 17, 92262 Fontenay-Aux-Roses (France); Mangeret, Arnaud [French Institute for Radiation protection and Nuclear Safety - IRSN, Radiation Protection Division - PRP, Nuclear Waste and Geosphere Department - DGE, SEDRAN/BRN, B.P. 17, 92262 Fontenay-Aux-Roses (France)

    2013-07-01

    This study focuses on a sub-aqueous mill tailings disposal site located in France (Bois Noirs) where 1.3 million tons of uranium mill sludge (fine tailings fraction < 50 μm) have been disposed since the 60's in a man-made pond below 4 meters of water maintained artificially by a rock-fill dam. A significant attenuation of aqueous {sup 226}Ra activity is observed in ground waters. This paper presents the preliminary modeling work performed for evaluating the role of water-rock interactions on aqueous {sup 226}Ra attenuation through the dam. This modeling attempt, assuming thermodynamic equilibrium, aims at checking the hydrochemical conceptual model developed in a previous study, in which Ra retention through the dam was assumed to most likely result from sorption onto metallic oxide-hydroxides. A 2D coupled reactive transport model was conceived to test this hypothesis over time and identify the measurements required to verify its consistency over the long term. (authors)

  5. Fluid Lensing, Applications to High-Resolution 3D Subaqueous Imaging & Automated Remote Biosphere Assessment from Airborne and Space-borne Platforms

    Science.gov (United States)

    Chirayath, V.

    2014-12-01

    Fluid Lensing is a theoretical model and algorithm I present for fluid-optical interactions in turbulent flows as well as two-fluid surface boundaries that, when coupled with an unique computer vision and image-processing pipeline, may be used to significantly enhance the angular resolution of a remote sensing optical system with applicability to high-resolution 3D imaging of subaqueous regions and through turbulent fluid flows. This novel remote sensing technology has recently been implemented on a quadcopter-based UAS for imaging shallow benthic systems to create the first dataset of a biosphere with unprecedented sub-cm-level imagery in 3D over areas as large as 15 square kilometers. Perturbed two-fluid boundaries with different refractive indices, such as the surface between the ocean and air, may be exploited for use as lensing elements for imaging targets on either side of the interface with enhanced angular resolution. I present theoretical developments behind Fluid Lensing and experimental results from its recent implementation for the Reactive Reefs project to image shallow reef ecosystems at cm scales. Preliminary results from petabyte-scale aerial survey efforts using Fluid Lensing to image at-risk coral reefs in American Samoa (August, 2013) show broad applicability to large-scale automated species identification, morphology studies and reef ecosystem characterization for shallow marine environments and terrestrial biospheres, of crucial importance to understanding climate change's impact on coastal zones, global oxygen production and carbon sequestration.

  6. Halogen degassing during ascent and eruption of water-poor basaltic magma

    Science.gov (United States)

    Edmonds, M.; Gerlach, T.M.; Herd, Richard A.

    2009-01-01

    A study of volcanic gas composition and matrix glass volatile concentrations has allowed a model for halogen degassing to be formulated for K??lauea Volcano, Hawai'i. Volcanic gases emitted during 2004-2005 were characterised by a molar SO2/HCl of 10-64, with a mean of 33; and a molar HF/HCl of 0-5, with a mean of 1.0 (from approximately 2500 measurements). The HF/HCl ratio was more variable than the SO2/HCl ratio, and the two correlate weakly. Variations in ratio took place over rapid timescales (seconds). Matrix glasses of Pele's tears erupted in 2006 have a mean S, Cl and F content of 67, 85 and 173??ppm respectively, but are associated with a large range in S/F. A model is developed that describes the open system degassing of halogens from parental magmas, using the glass data from this study, previously published results and parameterisation of sulphur degassing from previous work. The results illustrate that halogen degassing takes place at pressures of < 1??MPa, equivalent to < ~ 35??m in the conduit. Fluid-melt partition coefficients for Cl and F are low (< 1.5); F only degasses appreciably at < 0.1??MPa above atmospheric pressure, virtually at the top of the magma column. This model reproduces the volcanic gas data and other observations of volcanic activity well and is consistent with other studies of halogen degassing from basaltic magmas. The model suggests that variation in volcanic gas halogen ratios is caused by exsolution and gas-melt separation at low pressures in the conduit. There is no evidence that either diffusive fractionation or near-vent chemical reactions involving halogens is important in the system, although these processes cannot be ruled out. The fluxes of HCl and HF from K??lauea during 2004-5 were ~ 25 and 12??t/d respectively. ?? 2008 Elsevier B.V.

  7. Feasibility of storing radioactive wastes in Columbia River basalts

    International Nuclear Information System (INIS)

    Deju, R.A.

    1976-01-01

    In 1968 Atlantic Richfield Hanford Company initiated a study to assess the feasibility of final geologic storage of Hanford defense, radioactive waste in deep caverns constructed in the Columbia River flood basalts. The project, which included geologic studies, hydrologic tests, heat flow analysis, compatibility analysis, and tectonic studies, was suspended in 1972 before completion of interpretive work. In 1976 the interpretation and documentation were completed. These data may be valuable in qualifying the Columbia River flood basalts as a viable medium for final geologic storage of commercial radioactive waste. The findings to date are summarized, and the proposed future work is presented

  8. Friction Joint Between Basalt-Reinforced Composite and Aluminum

    DEFF Research Database (Denmark)

    Costache, Andrei; Glejbøl, Kristian; Sivebæk, Ion Marius

    2015-01-01

    The purpose of this study was to anchor basalt-reinforced polymers in an aluminum grip using dry friction. Dry friction clamping is considered the optimal solution for post-mounting of load-bearing terminations on composite structures. A new test method is presented for characterizing the frictio......The purpose of this study was to anchor basalt-reinforced polymers in an aluminum grip using dry friction. Dry friction clamping is considered the optimal solution for post-mounting of load-bearing terminations on composite structures. A new test method is presented for characterizing...

  9. lead glass brick

    CERN Multimedia

    When you look through the glass at a picture behind, the picture appears raised up because light is slowed down in the dense glass. It is this density (4.06 gcm-3) that makes lead glass attractive to physicists. The refractive index of the glass is 1.708 at 400nm (violet light), meaning that light travels in the glass at about 58% its normal speed. At CERN, the OPAL detector uses some 12000 blocks of glass like this to measure particle energies.

  10. Experimental study of the Mg and Sr isotopic evolution of seawater interacting with basalt between 150 and 300 ° C.

    Science.gov (United States)

    Voigt, Martin; Pearce, Christopher R.; Oelkers, Eric H.

    2016-04-01

    The chemical exchange of material between seawater and the oceanic crust plays a major role in marine geochemical cycles [1]. Isotopic signatures provide an important means of tracing elemental transfer in hydrothermal environments, yet only a limited amount of experimental data on the extent of isotopic fractionation under these conditions is currently available. This study consequently investigated the extent of δ26/24Mg and 87Sr/86Sr isotopic variation during a seawater-basalt interaction experiments at 150, 250 and 290 ° C. A suite of closed system experiments were run for several months at each temperature under saturated water pressure, using either crystalline or glassy basalt as the starting material and a water/rock ratio of 10 or 25. Our results demonstrate that the dissolution of basaltic material in hydrothermal environments occurs at the same time as the precipitation of alteration minerals (mainly smectite and anhydrite), which is consistent with results from similar studies in the past (e.g. [2]). As expected, the rate of reaction using crystalline basalt was slower than with basaltic glass, and both sample types reacted faster at higher temperatures. The 87Sr/86Sr composition of the experimental fluids decreased from the initial seawater value (0.70916) towards the lower basaltic signature during the experiments (0.70317), demonstrating the progressive release of Sr during basalt dissolution. Magnesium was steadily removed from the fluid via the precipitation of clay minerals, with the residual fluids having progressively lighter δ26/24Mg compositions. The mean Mg isotope fractionation factor (αsolid-solution) observed at 250 oC was 1.0005±0.0002, supporting low-temperature evidence that clay minerals preferentially incorporate isotopically heavy magnesium [3]. These experiments provide quantitative information on the extent of Mg isotopic fractionation between fluids and secondary silicate minerals in hydrothermal systems, and demonstrate the

  11. Characterization of fibers as rockwool for insulation obtained from canary islands basalts

    Directory of Open Access Journals (Sweden)

    Cáceres, J. M.

    1996-06-01

    Full Text Available Glass fibers in the shape of wool were obtained at laboratory scale from three samples of basaltic rocks from the Tenerife Island. The rockwool is widely used as thermal and acoustical insulation. The ability of these rocks to be fiberized was studied by means of the viscosity curves and can be quite improved by adding calcium and magnesium. The experimental fibers obtained from the rocks directly or mixed with either CaCO3 or CaMg(CO32 ye characterized in terms of chemical composition, microstructure and thermal and mechanical properties. These properties were compared with the ones determined for four commercial samples of rockcwool, founding that they are very close. This gives good prospects to these fibers from Canarian basalts as insulation material.

    Se ha obtenido fibra de vidrio en forma de lana, a escala de laboratorio, a partir de tres muestras de rocas basálticas de la Isla de Tenerife. La lana de roca se emplea extensamente como aislamiento térmico y acústico. La aptitud de estas rocas para su fibrado, estudiada mediante las curvas de viscosidad, mejora considerablemente con la adición de calcio y magnesio. Las fibras experimentales, obtenidas tanto a partir de las rocas directamente, como mezcladas en diferentes proporciones con CaCO3 o CaMg(CO32, se han caracterizado en lo referente a la composición química, la microestructura y propiedades térmicas y mecánicas. Así mismo, se han comparado estas propiedades con las determinadas para cuatro muestras comerciales de lana de roca, permitiendo comprobar que son bastante semejantes, lo que hace prever unas buenas cualidades para estas fibras de basaltos canarios en aplicaciones de aislamiento térmico y acústico.

  12. Preliminary feasibility study on storage of radioactive wastes in Columbia River basalts. Volume II

    Energy Technology Data Exchange (ETDEWEB)

    ,

    1976-11-01

    Volume II comprises four appendices: analytical data and sample locations for basalt flow type localities; Analytical data and sample locations for measured field sections in Yakima basalts; core hole lithology and analytical data; and geophysical logs. (LK)

  13. Mobilization of manganese by basalt associated Mn(II)-oxidizing bacteria from the Indian Ridge System

    Digital Repository Service at National Institute of Oceanography (India)

    Sujith, P.P.; Mourya, B.S.; Krishnamurthi, S.; Meena, R.M.; LokaBharathi, P.A.

    The Indian Ridge System basalt bearing Mn-oxide coatings had todorokite as the major and birnesite as the minor mineral. We posit that microorganisms associated with these basalts participate in the oxidation of Mn and contribute to mineral...

  14. Petrographical indicators of petrogenesis: Examples from Central Indian Ocean Basin basalts

    Digital Repository Service at National Institute of Oceanography (India)

    Mislankar, P.G.; Iyer, S.D.

    Petrographical features of the Central Indian Basin (CIOB) basalts were studied to understand their genetic significance. The fresh basaltic pillows show three textural zones from the top glassy (zone A) through the intermediate (zone B...

  15. Use of solar power for the production of basalt-based mineral fibers

    International Nuclear Information System (INIS)

    Gulamova, D. D.; Shevchenko, V. P.; Tokunov, S. G.; Kim, R. B.

    2012-01-01

    The possibility of obtaining basalt mineral fibers using concentrating solar power and melt-quench technique is shown. The microstructure and physicochemical properties of basalt fibers are analyzed. (author)

  16. Extreme incompatibility of helium during mantle melting: Evidence from undegassed mid-ocean ridge basalts

    Science.gov (United States)

    Graham, David W.; Michael, Peter J.; Shea, Thomas

    2016-11-01

    We report total helium concentrations (vesicles + glass) for a suite of thirteen ultradepleted mid-ocean ridge basalts (UD-MORBs) that were previously studied for volatile contents (CO2, H2O) plus major and trace elements. The selected basalts are undersaturated in CO2 + H2O at their depths of eruption and represent rare cases of undegassed MORBs. Sample localities from the Atlantic (2), Indian (1) and Pacific (7) Oceans collectively show excellent linear correlations (r2 = 0.75- 0.92) between the concentrations of helium and the highly incompatible elements C, K, Rb, Ba, Nb, Th and U. Three basalts from Gakkel Ridge in the Arctic were also studied but show anomalous behavior marked by excess lithophile trace element abundances. In the Atlantic-Pacific-Indian suite, incompatible element concentrations vary by factors of 3-4.3, while helium concentration varies by a factor of 13. The strong correlations between the concentrations of helium and incompatible elements are explained by helium behavior as the most incompatible element during mantle melting. Partial melting of an ultradepleted mantle source, formed as a residue of earlier melt extraction, accounts for the observed concentrations. The earlier melting event involved removal of a small degree melt (∼1%) at low but non-zero porosity (0.01-0.5%), leading to a small amount of melt retention that strongly leveraged the incompatible element budget of the ultradepleted mantle source. Equilibrium melting models that produce the range of trace element and helium concentrations from this source require a bulk solid/melt distribution coefficient for helium that is lower than that for other incompatible elements by about a factor of ten. Alternatively, the bulk solid/melt distribution coefficient for helium could be similar to or even larger than that for other incompatible elements, but the much larger diffusivity of helium in peridotite leads to its more effective incompatibility and efficient extraction from a

  17. Glass and nuclear wastes

    International Nuclear Information System (INIS)

    Sombret, C.

    1982-10-01

    Glass shows interesting technical and economical properties for long term storage of solidified radioactive wastes by vitrification or embedding. Glass composition, vitrification processes, stability under irradiation, thermal stability and aqueous corrosion are studied [fr

  18. Microstructuring of glasses

    CERN Document Server

    Hülsenberg, Dagmar; Bismarck, Alexander

    2008-01-01

    As microstructured glass becomes increasingly important for microsystems technology, the main application fields include micro-fluidic systems, micro-analysis systems, sensors, micro-actuators and implants. And, because glass has quite distinct properties from silicon, PMMA and metals, applications exist where only glass devices meet the requirements. The main advantages of glass derive from its amorphous nature, the precondition for its - theoretically - direction-independent geometric structurability. Microstructuring of Glasses deals with the amorphous state, various glass compositions and their properties, the interactions between glasses and the electromagnetic waves used to modify it. Also treated in detail are methods for influencing the geometrical microstructure of glasses by mechanical, chemical, thermal, optical, and electrical treatment, and the methods and equipment required to produce actual microdevices.

  19. Bonding Properties of Basalt Fiber and Strength Reduction According to Fiber Orientation

    OpenAIRE

    Choi, Jeong-Il; Lee, Bang

    2015-01-01

    The basalt fiber is a promising reinforcing fiber because it has a relatively higher tensile strength and a density similar to that of a concrete matrix as well as no corrosion possibility. This study investigated experimentally the bonding properties of basalt fiber with cementitious material as well as the effect of fiber orientation on the tensile strength of basalt fiber for evaluating basalt fiber?s suitability as a reinforcing fiber. Single fiber pullout tests were performed and then th...

  20. Measurement of optical glasses

    International Nuclear Information System (INIS)

    Nicolau-Rebigan, S.

    1978-11-01

    The possibilities of measurement of the optical glasses parameters needed in building optical devices especially in lasers devices are presented. In the first chapter the general features of the main optical glasses as well as the modalities of obtaining them are given. Chapter two defines the optical glass parameters, and the third chapter describes the measuring methods of the optical glass parameters. Finally, the conclusions which point out the utilization of this paper are presented. (author)

  1. Flame-resistant pure and hybrid woven fabrics from basalt

    Science.gov (United States)

    Jamshaid, H.; Mishra, R.; Militky, J.

    2017-10-01

    This work has been formulated to investigate the burning behavior of different type of fabrics. The main concentration is to see how long the fabric resists after it catches the fire and the propagation of fire can be reduced by using flame resistant fiber i.e basalt. Basalt fiber is an environmental friendly material with low input, high output, low energy consumption and less emission. The goal of present investigations is to show the dependence of fabric flammability on its structure parameters i.e weave type, blend type etc. Fabric weaves have strong effect on flammability properties. Plain weave has the lowest burning rate as the density of the plain weave fabric is more and the structure is tight which gives less chances of flame passing through the fabric. Thermal stability is evaluated with TGA of all hybrid and nonhybrid fabrics and compared. The thermal stability of the basalt fiber is excellent. When comparing thermal analysis curves for hybrid samples it demonstrates that thermal stability of the samples containing basalt is much higher than the non- hybrid samples. Percentage weight loss is less in hybrid samples as compared to non-hybrid samples. The effectiveness of hybridization on samples may be indicated by substantial lowering of the decomposition mass. Correlation was made between flammability with the infrared radiations (IR)

  2. Age of the youngest Palaeogene flood basalts in East Greenland

    DEFF Research Database (Denmark)

    Heilmann-Clausen, C.; Piasecki, Stefan; Abrahamsen, Niels

    2008-01-01

    results, this constrains the termination of the East Greenland Paleogene Igneous Province to the Early-Middle Eocene transition (nannoplankton chronozones NP13-NP14/earliest NP15). This is 6-8 Ma younger than according to previous biostratigraphic age assignments. The new data show that flood basalt...

  3. Genetic aspects of basalts from the Carlsberg Ridge

    Digital Repository Service at National Institute of Oceanography (India)

    Banerjee, R.; Iyer, S.D.

    of the CR rocks are sparse. The bulk chemical, mineral chemical and ore mineralization aspects of the dredged basalts from a segment of the CR (at 3°37¢N, 64°57¢E) are synthesized to indicate the influence of fractional crystallization coupled with magma...

  4. Gas adsorption on crushed quartz and basalt. [in vacuum

    Science.gov (United States)

    Barker, C.; Torkelson, B. E.

    1975-01-01

    The new surfaces generated by crushing rocks and minerals adsorb gases. Different gases are adsorbed to different extents so that both the total amount and composition of the released gases are changed. This affects the interpretation of the composition of the gases obtained by vacuum crushing lunar basalts, meteorites and minerals with fluid inclusions.

  5. Petrology of spinel lherzolite xenoliths in alkali basalts from Liri ...

    African Journals Online (AJOL)

    Al2O3), and Al-rich spinel occur in alkali basalts from Liri, South of the ... these spinel lherzolite xenoliths are reported, along with the analyses of ...... erupted in the Liri region. .... and temperatures with controlled activities of water, carbon.

  6. Petrography and chemistry of basalts from the Carlsberg ridge

    Digital Repository Service at National Institute of Oceanography (India)

    Banerjee, R.; Iyer, S.D.

    interior through a variolitic zone. The silica-alkalies relation show these basalts to be of sub-alkaline nature. Variable normative compositions and Mg number, increase in alkali index, differences in Al2O3/CaO and FeO/MgO ratios, variable trace element...

  7. Assesment of Alkali Resistance of Basalt Used as Concrete Aggregates

    Directory of Open Access Journals (Sweden)

    al-Swaidani Aref M.

    2015-11-01

    Full Text Available The objective of this paper is to report a part of an ongoing research on the influence of using crushed basalt as aggregates on one of durability-related properties of concrete (i.e. alkali-silica reaction which is the most common form of Alkali-Aggregate Reaction. Alkali resistance has been assessed through several methods specified in the American Standards. Results of petrographic examination, chemical test (ASTM C289 and accelerated mortar bar test (ASTM C1260 have particularly been reported. In addition, the weight change and compressive strength of 28 days cured concrete containing basaltic aggregates were also reported after 90 days of exposure to 10% NaOH solution. Dolomite aggregate were used in the latter test for comparison. The experimental results revealed that basaltic rocks quarried from As-Swaida’a region were suitable for production of aggregates for concrete. According to the test results, the studied basalt aggregates can be classified as innocuous with regard to alkali-silica reaction. Further, the 10% sodium hydroxide attack did not affect the compressive strength of concrete.

  8. Basalt Waste Isolation Project. Annual report, fiscal year 1979

    International Nuclear Information System (INIS)

    1979-11-01

    This project is aimed at examining the feasibility and providing the technology to design and construct a radwaste repository in basalt formations beneath and within the Hanford Site. The project is divided into seven areas: systems integration, geosciences, hydrologic studies, engineered barriers, near-surface test facility, engineering testing, and repository engineering. This annual report summarizes key investigations in these seven areas

  9. Evaluation of basalt flows as a waste isolation media

    International Nuclear Information System (INIS)

    Deju, R.A.

    1978-01-01

    Activities in basalt waste isolation programs in the Columbia River basin are reported. Work during the period is summarized for the overall program which is divided into systems integration, geology, hydrology, engineered barriers studies, engineering testing, and the construction of a near-surface test facility

  10. Nature and composition of interbedded marine basaltic pumice in the

    Indian Academy of Sciences (India)

    Home; Journals; Journal of Earth System Science; Volume 126; Issue 2. Nature and composition of interbedded marine basaltic pumice in the ~52–50 Ma Vastan lignite sequence, western India: Implication for Early Eocene MORB volcanism offshore Arabian Sea. Sarajit Sensarma Hukam Singh R S Rana Debajyoti Paul ...

  11. Fire performance of basalt FRP mesh reinforced HPC thin plates

    DEFF Research Database (Denmark)

    Hulin, Thomas; Hodicky, Kamil; Schmidt, Jacob Wittrup

    2013-01-01

    An experimental program was carried out to investigate the influence of basalt FRP (BFRP) reinforcing mesh on the fire behaviour of thin high performance concrete (HPC) plates applied to sandwich elements. Samples with BFRP mesh were compared to samples with no mesh, samples with steel mesh...

  12. Hydrologic testing methodology and results from deep basalt boreholes

    International Nuclear Information System (INIS)

    Strait, S.R.; Spane, F.A.; Jackson, R.L.; Pidcoe, W.W.

    1982-05-01

    The objective of the hydrologic field-testing program is to provide data for characterization of the groundwater systems wihin the Pasco Basin that are significant to understanding waste isolation. The effort is directed toward characterizing the areal and vertical distributions of hydraulic head, hydraulic properties, and hydrochemistry. Data obtained from these studies provide input for numerical modeling of groundwater flow and solute transport. These models are then used for evaluating potential waste migration as a function of space and time. The groundwater system beneath the Hanford Site and surrounding area consists of a thick, accordantly layered sequence of basalt flows and associated sedimentary interbed that primarily occur in the upper part of the Columbia River basalt. Permeable horizons of the sequence are associated with the interbeds and the interflow zones within the basalt. The columnar interiors of a flow act as low-permeability aquitards, separating the more-permeable interflows or interbeds. This paper discusses the hydrologic field-gathering activities, specifically, field-testing methodology and test results from deep basalt boreholes

  13. Heat resistance study of basalt fiber material via mechanical tests

    Science.gov (United States)

    Gao, Y. Q.; Jia, C.; Meng, L.; Li, X. H.

    2017-12-01

    This paper focuses on the study of the relationship between the fracture strength of basalt rovings and temperature. Strong stretching performance of the rovings has been tested after the treatment at fixed temperatures but different heating time and then the fracture strength of the rovings exposed to the heating at different temperatures and cooled in different modes investigated. Finally, the fracture strength of the basalt material after the heat treatment was studied. The results showed that the room-temperature strength tends to decrease with an increase of the heat treatment time at 250 °C, but it has the local maximum after 2h heating. And the basalt rovings strength increased after the heat treatment up to 200 °C. It was 16.7 percent higher than the original strength. The strength depends not only on the temperature and duration of the heating, but also on the cooling mode. The value of the strength measured after cold water cooling was less by 6.3% compared with an ambient air cooling mode. The room-temperature breaking strength of the rovings heated at 200 °C and 100 °C for 2 hours each increased by about 14.6% with respect to unpretreated basalt rovings.

  14. Depleted basaltic lavas from the proto-Iceland plume, Central East Greenland

    DEFF Research Database (Denmark)

    Waight, Tod Earle; Baker, Joel A.

    2012-01-01

    New geochemical and isotopic data are presented for volumetrically minor, depleted low-Ti basalts that occur in the Plateau Basalt succession of central East Greenland (CEG), formed during the initial stages of opening of the North Atlantic at 55 Ma. The basalts have MORB-like geochemistry (e.g. ...

  15. Geochemical study of young basalts in East Azerbaijan (Northwest of Iran

    Directory of Open Access Journals (Sweden)

    Nasir Amel

    2016-12-01

    Full Text Available The young basalts in East Azerbaijan are placed in West Alborz – Azerbaijan zone. Volcanic activities have extended from the Pliocene to the Quaternary by eruption from fracture systems and faults. Rocks under study are olivine-basalt and trachybasalts. The main minerals are olivine, pyroxene, plagioclase set in glassy or microcrystalline matrix and olivine are present as phenocryst. The textures in the studied rocks are mainly hyaloporphyric, hyalomicrolitic and porphyritic. Trace elements and rare earth elements on spider diagrams have high LREE/HREE ratio. Rare earth elements on diagram display negative slope indicating alkaline nature for the basalts under study. As it may be observed, on tectonic diagrams, the Marand basalts are placed on Island Arc basalt (IAB field, whereas the Ahar, Heris, Kalaibar and Miyaneh basalts are classified as Ocean Island Basalts (OIB and finally the basalts of Sohrol area are plotted on continental rift Basalt (CRB field. The Marand and Sohrol basalts were likely originated from lithospheric - astenospheric mantle with 2 to 5 % partial melting whereas, the Ahar, Heris and Kalaibar basalts having same source experienced 1-2% partial melting rate and the Miyaneh basalts possibly produced from lithospheric mantle with 10-20% partial melting rate pointing to shallow depth of mantle and the higher rate of melting. Based on tectonic setting diagrams, all the rocks studied are plotted in post collisional environments.

  16. Mechanically reinforced glass beams

    DEFF Research Database (Denmark)

    Nielsen, Jens Henrik; Olesen, John Forbes

    2007-01-01

    laminated float glass beam is constructed and tested in four-point bending. The beam consist of 4 layers of glass laminated together with a slack steel band glued onto the bottom face of the beam. The glass parts of the tested beams are \\SI{1700}{mm} long and \\SI{100}{mm} high, and the total width of one...

  17. Role of groundwater oxidation potential and radiolysis on waste glass performance in crystalline repository environments

    International Nuclear Information System (INIS)

    Jantzen, C.M.; Bibler, N.E.

    1985-01-01

    Laboratory experiments have shown that groundwater conditions in a Stripa granite repository will be as reducing as those in a basalt repository. The final oxidation potential (Eh) at 70 0 C for Stripa groundwater deaerated and equilibrated with crystalline granite was -0.45V. In contrast, the oxidation potential at 60 0 C for Grande Ronde groundwater equilibrated with basalt was -0.40V. The reducing groundwater conditions were found to slightly decrease the time-dependent release of soluble components from the waste glass. Spectrophotometric analysis of the equilibrated groundwaters indicated the presence of Fe 2+ confirming that the Fe 2+ /Fe 3+ couple is controlling the oxidation potential. It was also shown that in the alkaline pH regime of these groundwaters the iron species are primarily associated with x-ray amorphous precipitates in the groundwater. Gamma radiolysis in the absence of waste glass and in the absence of oxygen further reduces the oxidation potential of both granitic and basaltic groundwaters. The effect is more pronounced in the basaltic groundwater. The mechanism for this decrease is under investigation but appears related to the reactive amorphous precipitate. The results of these tests suggest that H 2 may not escape from the repository system as postulated and that radiolysis may not cause the groundwaters to become oxidizing in a crystalline repository when abundant Fe 2+ species are present. 23 refs., 3 figs., 3 tabs

  18. New high pressure experiments on sulfide saturation of high-FeO∗ basalts with variable TiO2 contents - Implications for the sulfur inventory of the lunar interior

    Science.gov (United States)

    Ding, Shuo; Hough, Taylor; Dasgupta, Rajdeep

    2018-02-01

    picritic glasses, mare basalts, to young lunar meteorites vary from 2600 to 4800 ppm for basalt equilibration with a pure FeS melt and from 1400 to 2600 ppm for basalt equilibration with a Fe-rich sulfide melt containing 30 wt.% Ni. The measured S contents in these proposed near-primary lunar magmas are lower than the predicted SCSS at the conditions of their last equilibration with the lunar mantle, indicating no sulfide retention in the lunar mantle source during partial melting. Sulfide exhaustion during partial melting in the lunar mantle also supports the notion that the bulk silicate moon is depleted in highly siderophile elements. Based on the measured S contents and the estimated degree of melting, the estimated S contents for the mantle source of A15 green glass and A15 mare basalts is 10-23 ppm; for A17 orange glass is 25-62 ppm, for A12 mare basalts is 27-92 ppm, and for A11 basalt is 35-120 ppm. Consideration of SCSS decrease due to the presence of Ni in the sulfide melt does not change these mantle S abundance estimates for <30 wt.% Ni in the sulfide. The inferred S contents suggest that the lunar mantle is heterogeneous in terms of S. Although variable among different groups, the inferred S abundance of up to 120 ppm in the lunar mantle falls near the lower end of the S content of the depleted terrestrial mantle such as the MORB source.

  19. Influence of microorganisms on the alteration of glasses; Influence des microorganismes sur l'alteration des verres

    Energy Technology Data Exchange (ETDEWEB)

    Besnainou, B; Libert, M F [CEA Cadarache, 13 - Saint Paul lez Durance (France). Dept. d' Entreposage et de Stockage des Dechets

    1997-07-01

    Under specific conditions, microorganisms may enhance the alteration process of basaltic glass. However bacterial activity in the near field of a glass container would be possible only in environmental conditions provide nutrients and energetic substrates for bacterial growth. Depending of these conditions, microorganisms can: - modify the pH or the medium, - consume or produce soluble organic acids. To qualify the long term behaviour of glass, in presence of microorganisms, a qualitative and quantitative estimation of microbial activity potentialities and their consequences is needed. This must be achieved in studying the availability of the chemical species in the environment. (authors)

  20. Fluoride glass fiber optics

    CERN Document Server

    Aggarwal, Ishwar D

    1991-01-01

    Fluoride Glass Fiber Optics reviews the fundamental aspects of fluoride glasses. This book is divided into nine chapters. Chapter 1 discusses the wide range of fluoride glasses with an emphasis on fluorozirconate-based compositions. The structure of simple fluoride systems, such as BaF2 binary glass is elaborated in Chapter 2. The third chapter covers the intrinsic transparency of fluoride glasses from the UV to the IR, with particular emphasis on the multiphonon edge and electronic edge. The next three chapters are devoted to ultra-low loss optical fibers, reviewing methods for purifying and

  1. Multiple Glass Ceilings

    OpenAIRE

    Russo, Giovanni; Hassink, Wolter

    2011-01-01

    Both vertical (between job levels) and horizontal (within job levels) mobility can be sources of wage growth. We find that the glass ceiling operates at both margins. The unexplained part of the wage gap grows across job levels (glass ceiling at the vertical margin) and across the deciles of the intra-job-level wage distribution (glass ceiling at the horizontal margin). This implies that women face many glass ceilings, one for each job level above the second, and that the glass ceiling is a p...

  2. Homogeneity of Inorganic Glasses

    DEFF Research Database (Denmark)

    Jensen, Martin; Zhang, L.; Keding, Ralf

    2011-01-01

    Homogeneity of glasses is a key factor determining their physical and chemical properties and overall quality. However, quantification of the homogeneity of a variety of glasses is still a challenge for glass scientists and technologists. Here, we show a simple approach by which the homogeneity...... of different glass products can be quantified and ranked. This approach is based on determination of both the optical intensity and dimension of the striations in glasses. These two characteristic values areobtained using the image processing method established recently. The logarithmic ratio between...

  3. The role of natural glasses as analogues in projecting the long-term alteration of high-level nuclear waste glasses: Part 1

    International Nuclear Information System (INIS)

    Mazer, J.J.

    1993-01-01

    The common observation of glasses persisting in natural environments for long periods of time (up to tens of millions of years) provides compelling evidence that these materials can be kinetically stable in a variety of subsurface environments. This paper reviews how natural and historical synthesized glasses can be employed as natural analogues for understanding and projecting the long-term alteration of high-level nuclear waste glasses. The corrosion of basaltic glass results in many of the same alteration features found in laboratory testing of the corrosion of high-level radioactive waste glasses. Evidence has also been found indicating similarities in the rate controlling processes, such as the effects of silica concentration on corrosion in groundwater and in laboratory leachates. Naturally altered rhyolitic glasses and tektites provide additional evidence that can be used to constrain estimates of long-term waste glass alteration. When reacted under conditions where water is plentiful, the corrosion for these glasses is dominated by network hydrolysis, while the corrosion is dominated by molecular water diffusion and secondary mineral formation under conditions where water contact is intermittent or where water is relatively scarce. Synthesized glasses that have been naturally altered result in alkali-depleted alteration features that are similar to those found for natural glasses and for nuclear waste glasses. The characteristics of these alteration features appear to be dependent on the alteration conditions which affect the dominant reaction processes during weathering. In all cases, care must be taken to ensure that the information being provided by natural analogues is related to nuclear waste glass corrosion in a clear and meaningful way

  4. Deposits related to supercritical flows in glacifluvial deltas and subaqueous ice-contact fans: Integrating facies analysis and ground-penetrating radar

    Science.gov (United States)

    Lang, Joerg; Sievers, Julian; Loewer, Markus; Igel, Jan; Winsemann, Jutta

    2017-04-01

    Bedforms related to supercritical flows have recently received much interest and the understanding of flow morphodynamics and depositional processes has been greatly advanced. However, outcrop studies of these bedforms are commonly hampered by their long wavelengths. Therefore, we combined outcrop-based facies analysis with extensive ground-penetrating radar (GPR) measurements. Different GPR antennas (200, 400 and 1500 MHz) were utilised to measure both long profiles and densely spaced grids in order to map the large-scale facies architecture and image the three-dimensional geometry of the deposits. The studied delta and subaqueous ice-contact fan successions were deposited within ice-dammed lakes, which formed along the margins of the Middle Pleistocene Scandinavian ice sheets across Northern Germany. These glacilacustrine depositional systems are characterised by high aggradation rates due to the rapid expansion and deceleration of high-energy sediment-laden flows, favouring the preservation of bedforms related to supercritical flows. In flow direction, delta foresets commonly display lenticular scours, which are 2 to 6 m wide and 0.15 to 0.5 m deep. Characteristically, scours are filled by upslope dipping backsets, consisting of pebbly sand. In a few cases, massive and deformed strata were observed, passing upflow into backsets. Across flow, scours are 2 to 3 m wide and typically display a concentric infill. The scour fills are commonly associated with subhorizontally or sinusoidal stratified pebbly sand. These facies types are interpreted as deposits of cyclic steps and antidunes, respectively, representing deposition from supercritical density flows, which formed during high meltwater discharge events or regressive slope failures (Winsemann et al., in review). The GPR-sections show that the scour fills form trains along the delta foresets, which can be traced for up to 15 m. The studied subaqueous ice-contact fan succession relates to the zone of flow

  5. Leach behavior of high-level borosilicate glasses under deep geological environment

    International Nuclear Information System (INIS)

    Kim, Seung Soo; Chun, Kwan Sik; Park, Hyun Soo

    1998-02-01

    This report presents an overview of the activities in high-level radioactive waste glass which is considered as the most practicable form of waste, and also is intended to be used in the disposal of national high-level radioactive waste in future. Leach theory of waste glass and the leach effects of ground water, metal barrier, buffer materials and rocks on the waste glass were reviewed. The leach of waste glass was affected by various factors such as composition, pH and Eh of ground water, temperature, pressure, radiation and humic acid. The crystallization, crack, weathering and the formation of altered phases of waste glass which is expected to occur in real disposal site were reviewed. The results of leaching in laboratory and in-situ were compared. The behaviors of radioactive elements leached from waste glass and the use of basalt glass for the long-term natural analogue of waste glass were also written in this report. The appraisal of durability of borosilicate waste glass as a waste media was performed from the known results of leach test and international in-situ tests were introduced. (author). 134 refs., 15 tabs., 24 figs

  6. Cotectic proportions of olivine and spinel in olivine-tholeiitic basalt and evaluation of pre-eruptive processes

    Science.gov (United States)

    Roeder, Peter; Gofton, Emma; Thornber, Carl

    2006-01-01

    The volume %, distribution, texture and composition of coexisting olivine, Cr-spinel and glass has been determined in quenched lava samples from Hawaii, Iceland and mid-oceanic ridges. The volume ratio of olivine to spinel varies from 60 to 2800 and samples with >0·02% spinel have a volume ratio of olivine to spinel of approximately 100. A plot of wt % MgO vs ppm Cr for natural and experimental basaltic glasses suggests that the general trend of the glasses can be explained by the crystallization of a cotectic ratio of olivine to spinel of about 100. One group of samples has an olivine to spinel ratio of approximately 100, with skeletal olivine phenocrysts and small (within olivine phenocrysts is thought to be due to skeletal olivine phenocrysts coming into physical contact with spinel by synneusis during the chaotic conditions of ascent and extrusion. A second group of samples tend to have large olivine phenocrysts relatively free of included spinel, a few large (>100 μm) spinel crystals that show evidence of two stages of growth, and a volume ratio of olivine to spinel of 100 to well over 1000. The olivine and spinel in this group have crystallized more slowly with little physical interaction, and show evidence that they have accumulated in a magma chamber.

  7. Mobility of Ra-226 and Heavy Metals (U, Th and Pb) from Pyritic Uranium Mine Tailings under Sub-aqueous Disposal Conditions - 59283

    International Nuclear Information System (INIS)

    Dave, Nand K.

    2012-01-01

    All uranium mines in the Elliot Lake uranium mining district of north-central Ontario, Canada, have been closed due to low ore grade and prevailing market conditions. A majority of the waste management facilities have been rehabilitated and decommissioned with in-situ shallow water covers to minimize sulphide oxidation, and hence acid generation and release of metal enriched effluents. Laboratory lysimeter studies were undertaken to evaluate the leaching characteristics and mobility of Ra-226 and other heavy metals (U, Th and Pb) from pyritic uranium mine tailings under sub-aqueous disposal conditions for assessing the long-term radiological stability of such waste repositories. The experiments were conducted using three types of un-oxidized tailings: fine, coarse and gypsum depleted mill total tailings. Shallow water covers of depth ∼ 0.3 m were established using natural lake water. The leaching characteristics of radium and other major and trace metals were determined by monitoring both surface and pore water qualities as a function of time. The results showed that Ra-226 was leached from surface of the submerged tailings and released to both surface water and shallow zone pore water during initial low sulphate ion concentration of the surface water cover in all three cases. The release of Ra-226 was further enhanced with the onset of weak acidic conditions in the surface water covers of both coarse and gypsum depleted mill total tailings. With additional acid generation and increasing sulphate and iron concentrations, the dissolved Ra-226 concentrations in the water covers of these tailings gradually decreased back to low levels. Pb was also leached and mobilized with the development of moderate acidic conditions at the surface of the submerged coarse and gypsum deplete tailings. No leaching of U and Th was observed. (authors)

  8. Leaching of glass

    International Nuclear Information System (INIS)

    Hench, L.L.

    1977-01-01

    Understanding surface compositional profiles of glasses over a range of 0-2000 A with a variety of analytical instruments shows that five general types of glass surfaces exist. The surface character of a glass article depends upon bulk composition and environmental history during which surface dealkalization, film formation, and network dissolution can occur. Environmental-surface interactions generally result in complex compositional profiles of all the constituents in a glass. Durable glasses almost always develop a stable surface film which has a higher concentration of network formers than the bulk composition. Compositional effects that are used to improve glass durability usually improve the stability of the surface films. Durability tests or service conditions that lead to film destruction are especially severe for the most silicate glasses. 43 references

  9. Architecture and emplacement of flood basalt flow fields: case studies from the Columbia River Basalt Group, NW USA

    Science.gov (United States)

    Vye-Brown, C.; Self, S.; Barry, T. L.

    2013-03-01

    The physical features and morphologies of collections of lava bodies emplaced during single eruptions (known as flow fields) can be used to understand flood basalt emplacement mechanisms. Characteristics and internal features of lava lobes and whole flow field morphologies result from the forward propagation, radial spread, and cooling of individual lobes and are used as a tool to understand the architecture of extensive flood basalt lavas. The features of three flood basalt flow fields from the Columbia River Basalt Group are presented, including the Palouse Falls flow field, a small (8,890 km2, ˜190 km3) unit by common flood basalt proportions, and visualized in three dimensions. The architecture of the Palouse Falls flow field is compared to the complex Ginkgo and more extensive Sand Hollow flow fields to investigate the degree to which simple emplacement models represent the style, as well as the spatial and temporal developments, of flow fields. Evidence from each flow field supports emplacement by inflation as the predominant mechanism producing thick lobes. Inflation enables existing lobes to transmit lava to form new lobes, thus extending the advance and spread of lava flow fields. Minimum emplacement timescales calculated for each flow field are 19.3 years for Palouse Falls, 8.3 years for Ginkgo, and 16.9 years for Sand Hollow. Simple flow fields can be traced from vent to distal areas and an emplacement sequence visualized, but those with multiple-layered lobes present a degree of complexity that make lava pathways and emplacement sequences more difficult to identify.

  10. Miocene Basaltic Lava Flows and Dikes of the Intervening Area Between Picture Gorge and Steens Basalt of the CRBG, Eastern Oregon

    Science.gov (United States)

    Cahoon, E. B.; Streck, M. J.

    2016-12-01

    Mid-Miocene basaltic lavas and dikes are exposed in the area between the southern extent of the Picture Gorge Basalt (PGB) and the northern extent of Steens Basalt in a wide corridor of the Malheur National Forest, eastern Oregon. An approximate mid-Miocene age of sampled basaltic units is indicated by stratigraphic relationships to the 16 Ma Dinner Creek Tuff. Lavas provide an opportunity to extend and/or revise distribution areas of either CRBG unit and explore the petrologic transition between them. The PGB and the Steens Basalt largely represent geochemically distinct tholeiitic units of the CRBG; although each unit displays internal complexity. Lavas of PGB are relatively primitive (MgO 5-9 wt.%) while Steens Basalt ranges in MgO from >9 to 3 wt.% but both units are commonly coarsely porphyritic. Conversely, Steens Basalt compositions are on average more enriched in highly incompatible elements (e.g. Rb, Th) and relatively enriched in the lesser incompatible elements (e.g. Y, Yb) compared to the Picture Gorge basalts. These compositional signatures produce inclined and flat patterns on mantle-normalized incompatible trace element plots but with similar troughs and spikes, respectively. New compositional data from our study area indicate basaltic lavas can be assigned as PGB lava flows and dikes, and also to a compositional group chemically distinct between Steens Basalt and PGB. Distribution of lava flows with PGB composition extend this CRBG unit significantly south/southeast closing the exposure gap between PGB and Steens Basalt. We await data that match Steens Basalt compositions but basaltic lavas with petrographic features akin to Steens Basalt have been identified in the study area. Lavas of the transitional unit share characteristics with Upper Steens and Picture Gorge basalt types, but identify a new seemingly unique composition. This composition is slightly more depleted in the lesser incompatible elements (i.e. steeper pattern) on mantle normalized

  11. Origins of chemical diversity of back-arc basin basalts: a segment-scale study of the Eastern Lau Spreading Center

    OpenAIRE

    Bézos, Antoine; Escrig, Stéphane; Langmuir, Charles H.; Michael, Peter J.; Asimow, Paul D.

    2009-01-01

    We report major, trace, and volatile element data on basaltic glasses from the northernmost segment of the Eastern Lau Spreading Center (ELSC1) in the Lau back-arc basin to further test and constrain models of back-arc volcanism. The zero-age samples come from 47 precisely collected stations from an 85 km length spreading center. The chemical data covary similarly to other back-arc systems but with tighter correlations and well-developed spatial systematics. We confirm a correlation between v...

  12. Hydrovolcanic and Hydrothermal Biomediated Mineral Growth in Basaltic Tuff, Surtsey Volcano, Iceland

    Science.gov (United States)

    Jackson, M. D.; Couper, S.; Ivarsson, M.; Stan, C. V.; Tamura, N.; Miyagi, L. M.; Moore, J. G.

    2017-12-01

    Fine-scale analyses of hydroclasts in 1979 Surtsey basaltic tuff drill core provide new methods for examining hydrovolcanic and hydrothermal magma-rock influences on biomediated alteration in palagonitized submarine tephra. Synchrotron source X-ray microdiffraction and microfluorescence studies from Advanced Light Source beamline 12.3.2, epifluorescent UVA illumination microscopy, S/TEM EDX compositional analyses, and Raman spectroscopy define diverse nanocrystalline clay mineral structures at 137.9 m depth (93.8 °C (1980)) and 102.6 m depth (141.3 °C (1980)). At 137.9 m, olivine contains endolithic microborings; vermicular microstructures in altered glass contain nontronite exhibiting crystallographic preferred orientation; and 75-150 µm sub-circular microstructures in altered glass contain Al-tobermorite, a calcium-silicate-hydrate with 11.3 Å interlayer spacing, zeolite, and epifluorescent, thread-like structures. At 102.6 m depth, concentrically-layered microstructures occur in altered glass and altered olivine. These have nontronite crystallographic preferred orientations that rotate around a longitudinal axis commonly occupied by a 10-80 µm long, epifluorescent thread-like structure. Pronounced carbon concentrations detected by S/TEM EDX trace layer boundaries. First-order Raman bands at 1370 cm-1 (disorder-related) and at 1580 cm-1 (order-related), and second-order bands at 2500-3300 cm-1 (overtone scattering) detect degraded organic carbonaceous matter, a strong indication of biological origin. Sub-circular nanostructures in altered glass at 137.9 m depth show similar spectra. Borehole fluid temperatures at 102.6 m, 141.3 °C in 1980, exceeded 130 °C, the assumed limit for growth of microorganisms, however. Previous analyses suggest an early low temperature episode in submarine deposits, prior to development of a hydrothermal system driven by 1964-1967 magmatic intrusions. The abundant traces of biomediated nanocrystalline clay mineral growth validate

  13. Surface modification of basalt with silane coupling agent on asphalt mixture moisture damage

    Energy Technology Data Exchange (ETDEWEB)

    Min, Yahong; Fang, Ying; Huang, Xiaojun; Zhu, Yinhui; Li, Wensheng [College of Chemistry and Chemical Engineering, Hunan University, Changsha, 410082 (China); Yuan, Jianmin [College of Materials Engineering, Hunan University, Changsha, 410082 (China); Tan, Ligang [College of Mechanical and Vehicle Engineering, Hunan University, Changsha, 410082 (China); Wang, Shuangyin [State Key Laboratory of Chem/Bio-Sensing and Chemometrics, College of Chemistry and Chemical Engineering, Hunan University, Changsha, 410082 (China); Wu, Zhenjun, E-mail: wooawt@163.com [College of Chemistry and Chemical Engineering, Hunan University, Changsha, 410082 (China)

    2015-08-15

    Graphical abstract: - Highlights: • A new silane coupling agent was synthesized based on KH570. • Basalt surface was modified using the new silane coupling agent. • Chemical bond between basalt and the new silane coupling agent was formed. • Asphalt mixture which used modified basalt show superior water stability. - Abstract: A new silane coupling agent was synthesized based on γ-(methacryloyloxy) propyltrimethoxysilane (KH570). The surface of basalt rocks was modified by KH570 and the new silane coupling agent (NSCA), and the interfacial interaction between silane coupling agent and basalt was also studied. Fourier transform infrared (FTIR) spectroscopy and X-ray photoelectron spectroscopy (XPS) analysis showed that the silane coupling agent molecule bound strongly with basalt rocks. Scanning electronic microscopy (SEM) observation showed that a thin layer of coupling agent was formed on the surface of modified basalt. The boiling test and immersion Marshall test confirmed that the moisture sensitivity of basalt modified with the new silane coupling agent increased more significantly than that untreated and treated with KH570. The Retained Marshall Strength of basalt modified with the new coupling agent increased from 71.74% to 87.79% compared with untreated basalt. The results indicated that the new silane coupling agent played an important role in improving the interfacial performance between basalt and asphalt.

  14. Basalt characterization by means of nuclear and electrical well logging techniques. Case study from Southern Syria

    International Nuclear Information System (INIS)

    Asfahani, Jamal

    2011-01-01

    Nuclear well logging, including natural gamma ray, density, and neutron-porosity techniques are used with electrical well logging of long and short normal techniques to characterize the basaltic areas largely extended in Southern Syria. Statistical analysis approach with the threshold concept has been adapted for such characterization, where four kinds of basalt have been identified: very hard basalt, hard basalt, fractured basalt, and basalt alteration products. The spectrometric gamma technique has also been applied on the retrieved rock samples in order to determine the radioactive content (eU, eTh, and K%) of the basaltic section in the study area. No radioactive anomalies have been detected, the radioactive values are normal and in the expected range.

  15. Kinetics of iron redox reaction in silicate melts: A high temperature Xanes study on an alkali basalt

    Energy Technology Data Exchange (ETDEWEB)

    Cochain, B; Neuville, D R; Roux, J; Strukelj, E; Richet, P [Physique des Mineraux et Magmas, Geochimie-Cosmochimie, CNRS-IPGP, 4 place Jussieu, 75005 Paris (France); Ligny, D de [Universite Claude Bernard Lyon 1, LPCML, F-69622 Villeurbanne (France); Baudelet, F, E-mail: cochain@ipgp.jussieu.f [Synchrotron SOLEIL, L' Orme des Merisiers, Saint Aubin (France)

    2009-11-15

    In Earth and Materials sciences, iron is the most important transition element. Glass and melt properties are strongly affected by iron content and redox state with the consequence that some properties (i.e. viscosity, heat capacity, crystallization...) depend not only on the amounts of Fe{sup 2+} and Fe{sup 3+}, but also on the coordination state of these ions. In this work we investigate iron redox reactions through XANES experiments at the K-edge of iron. Using a high-temperature heating device, pre-edge of XANES spectra exhibits definite advantages to make in-situ measurements and to determine the evolution of redox state with time, temperature and composition of synthetic silicate melts. In this study, new kinetics measurements are presented for a basalt melt from the 31,000-BC eruption of the Puy de Lemptegy Volcano in France. These measurements have been made between 773 K and at superliquidus temperatures up to 1923 K.

  16. Kinetics of iron redox reaction in silicate melts: A high temperature Xanes study on an alkali basalt

    International Nuclear Information System (INIS)

    Cochain, B; Neuville, D R; Roux, J; Strukelj, E; Richet, P; Ligny, D de; Baudelet, F

    2009-01-01

    In Earth and Materials sciences, iron is the most important transition element. Glass and melt properties are strongly affected by iron content and redox state with the consequence that some properties (i.e. viscosity, heat capacity, crystallization...) depend not only on the amounts of Fe 2+ and Fe 3+ , but also on the coordination state of these ions. In this work we investigate iron redox reactions through XANES experiments at the K-edge of iron. Using a high-temperature heating device, pre-edge of XANES spectra exhibits definite advantages to make in-situ measurements and to determine the evolution of redox state with time, temperature and composition of synthetic silicate melts. In this study, new kinetics measurements are presented for a basalt melt from the 31,000-BC eruption of the Puy de Lemptegy Volcano in France. These measurements have been made between 773 K and at superliquidus temperatures up to 1923 K.

  17. Basaltic rocks analyzed by the Spirit rover in Gusev crater

    Science.gov (United States)

    McSween, H.Y.; Arvidson, R. E.; Bell, J.F.; Blaney, D.; Cabrol, N.A.; Christensen, P.R.; Clark, B. C.; Crisp, J.A.; Crumpler, L.S.; Des Marias, D.J.; Farmer, J.D.; Gellert, Ralf; Ghosh, A.; Gorevan, S.; Graff, T.; Grant, J.; Haskin, L.A.; Herkenhoff, K. E.; Johnson, J. R.; Jolliff, B.L.; Klingelhoefer, G.; Knudson, A.T.; McLennan, S.; Milam, K.A.; Moersch, J.E.; Morris, R.V.; Rieder, R.; Ruff, S.W.; De Souza, P.A.; Squyres, S. W.; Wanke, H.; Wang, A.; Wyatt, M.B.; Yen, A.; Zipfel, J.

    2004-01-01

    The Spirit landing site in Gusev Crater on Mars contains dark, fine-grained, vesicular rocks interpreted as lavas. Pancam and Mini-Thermal Emission Spectrometer (Mini-TES) spectra suggest that all of these rocks are similar but have variable coatings and dust mantles. Magnified images of brushed and abraded rock surfaces show alteration rinds and veins. Rock interiors contain ???25% megacrysts. Chemical analyses of rocks by the Alpha Particle X-ray Spectrometer are consistent with picritic basalts, containing normative olivine, pyroxenes, plagioclase, and accessory FeTi oxides. Mo??ssbauer, Pancam, and Mini-TES spectra confirm the presence of olivine, magnetite, and probably pyroxene. These basalts extend the known range of rock compositions composing the martian crust.

  18. Petrogeochemistry of Mesozoic basaltic volcanics in Daqingshan area

    International Nuclear Information System (INIS)

    Li Xiaoguang; Li Ziying; Wei Sanyuan; Qi Da'neng

    2009-01-01

    Through the discussion on petrogeochemistry of Later Mesozoic basaltic volcanics in Daqingshan Basin in Manzhouli area, combined with field observation and the predecessors' study, its magma evolution,genesis and diagenetic structural environment are discussed, and some suggestion are provided for the further work. Basaltic magma in this area is believed to be derived from mantle with incompatible elements which were later participated by some crustal materials. It is a partially melting product of mantle by early metasomatized fluid under lithosphere extension. Through petrogeochemical analysis of the volcanics and the contrast to the adjacent uranium-producing volcanics, it is concluded that this region has structural environment to form magma evolution series which are more favorable for volcanic hydrothermal-type uranium and polymetallic mineralization. (authors)

  19. Americium migration in basalt and implications to repository risk analysis

    International Nuclear Information System (INIS)

    Rickert, P.G.

    1980-01-01

    Experiments were performed with americium as a minor component in groundwater. Batch adsorption, migration through column, and filtration experiments were performed. It was determined in batch experiments that americium is strongly adsorbed from solution. It was determined with filtration experiments that large percentages of the americium concentrations suspended by the contact solutions in batch experiments and suspended by the infiltrating groundwater in migration experiments were associated with particulate. Filtration was determined to be the primary mode of removal of americium from infiltrating groundwater in a column of granulated basalt (20 to 50 mesh) and an intact core of permeable basalt. Fractionally, 0.46 and 0.22 of the americium component in the infiltrating groundwater was transported through the column and core respectively. In view of these filtration and migration experiment results, the concept of K/sub d/ in the chromatographic sense is meaningless for predicting americium migration in bedrock by groundwater transport at near neutral pH

  20. Quaternary basaltic volcanism in the Payenia volcanic province, Argentina

    DEFF Research Database (Denmark)

    Søager, Nina

    primitive basalts and trachybasalts but also more evolved samples from the retroarc region and the larger volcanoes Payún Matrú and Payún Liso are presented. The samples cover a broad range of compositions from intraplate lavas similar to ocean island basalts to arc andesites. A common feature found...... are isotopically similar to the Andean Southern Volcanic Zone arc rocks and their mantle source possibly resembled the source of South Atlantic N-MORB prior to addition of fluids and melts from the subduction channel. However, it must have been more enriched than the estimates of depleted upper mantle from...... the lithosphere is thinnest and possibly in areas of elevated mantle temperatures. The pyroxenite melts formed at deeper levels react with the surrounding peridotite and thereby changes composition leading to eruption of melts which experienced variable degrees of melt-peridotite interaction. This can presumably...

  1. Basalt-trachybasalt samples in Gale Crater, Mars

    International Nuclear Information System (INIS)

    Edwards, Peter H.; Anderson, Ryan B.; Dyar, Darby

    2017-01-01

    The ChemCam instrument on the Mars Science Laboratory (MSL) rover, Curiosity, observed numerous igneous float rocks and conglomerate clasts, reported previously. A new statistical analysis of single-laser-shot spectra of igneous targets observed by ChemCam shows a strong peak at ~55 wt% SiO 2 and 6 wt% total alkalis, with a minor secondary maximum at 47–51 wt% SiO 2 and lower alkali content. The centers of these distributions, together with the rock textures, indicate that many of the ChemCam igneous targets are trachybasalts, Mg# = 27 but with a secondary concentration of basaltic material, with a focus of compositions around Mg# = 54. We suggest that all of these igneous rocks resulted from low-pressure, olivine-dominated fractionation of Adirondack (MER) class-type basalt compositions. This magmatism has subalkaline, tholeiitic affinities. The similarity of the basalt endmember to much of the Gale sediment compositions in the first 1000 sols of the MSL mission suggests that this type of Fe-rich, relatively low-Mg#, olivine tholeiite is the dominant constituent of the Gale catchment that is the source material for the fine-grained sediments in Gale. The similarity to many Gusev igneous compositions suggests that it is a major constituent of ancient Martian magmas, and distinct from the shergottite parental melts thought to be associated with Tharsis and the Northern Lowlands. Finally, the Gale Crater catchment sampled a mixture of this tholeiitic basalt along with alkaline igneous material, together giving some analogies to terrestrial intraplate magmatic provinces.

  2. Basaltic Shergottite NWA 856: Differentiation of a Martian Magma

    Science.gov (United States)

    Ferdous, J.; Brandon, A. D.; Peslier, A. H.; Pirotte, Z.

    2016-01-01

    NWA 856 or Djel Ibone, is a basaltic shergottite discovered as a single stone of 320 g in South Morocco in April, 2001. This meteorite is fresh, i.e. shows minimal terrestrial weathering for a desert find. No shergottite discovered in North Africa can be paired with NWA 856. The purpose of this study is to constrain its crystallization history using textural observations, crystallization sequence modeling and in-situ trace element analysis in order to understand differentiation in shergottite magmatic systems.

  3. Rock mass deformation properties of closely jointed basalt

    International Nuclear Information System (INIS)

    Kim, K.; Cramer, M.L.

    1982-12-01

    The deformational behavior of the Columbia River basalt is being investigated as part of a comprehensive site characterization program intended to determine the feasibility of constructing a nuclear waste repository in basalt at Hanford, Washington. Direct field measurements were conducted in a 2-m cube of basalt to obtain truly representative rock mass deformation properties. Load was applied to the test block in three orthogonal directions through the use of flat jacks in two perpendicular planes and a cable anchor system in the third. This configuration allowed the block to be placed in a simulated triaxial stress state at stress levels up to 12.5 MPa. The deformation at the center of the test block was monitored through the use of an optical measurement system developed for this project. The results indicate that the vertically oriented columnar joints have a significant influence on the deformation behavior of the basalt. The modulus in the direction parallel to the column axis was approx. 30 GPa, while the modulus value perpendicular to the columns was approx. 20 GPa. Laboratory measurements of intact specimens taken from this area yielded a value of 80 GPa with no indication of anisotropy. Hysteresis was observed in all loading cycles, but was distinctly more pronounced perpendicular to the column axis, indicative of significant joint displacement in this direction. The results of this test represent the first true rock mass modulus data obtained in closely jointed rock on a large scale. These measurement methods have eliminated many of the ambiguities associated with borehole jacking and surface measurement techniques

  4. Identification of key radionuclides in a nuclear waste repository in basalt

    International Nuclear Information System (INIS)

    Barney, G.S.; Wood, B.J.

    1980-05-01

    Radionuclides were identified which appear to pose the greatest potential hazard to man during long-term storage of nuclear waste in a repository mined in the Columbia Plateau basalt formation. The criteria used to select key radionuclides were as follows: quantity of radionuclide in stored waste; biological toxicity; leach rate of the wastes into groundwater; and transport rate via groundwater flow. The waste forms were assumed to be either unreprocessed spent fuel or borosilicate glass containing reprocessed high-level waste. The nuclear waste composition was assumed to be that from a light water reactor. Radionuclides were ranked according to quantity, toxicity, and release rate from the repository. These rankings were combined to obtain a single list of key radionuclides. The ten most important radionuclides in order of decreasing hazard are: 99 Tc, 129 I, 237 Np, 226 Ra, 107 Pd, 230 Th, 210 Pb, 126 Sn, 79 Se, and 242 Pu. Safety assessment studies and the design of engineered barriers should concentrate on containment of radionuclides in this list

  5. Interim reclamation report, Basalt Waste Isolation project: Boreholes, 1989

    International Nuclear Information System (INIS)

    Brandt, C.A.; Rickard, W.H. Jr.; Hefty, M.G.

    1990-03-01

    In 1968, a program was started to assess the feasibility of storing Hanford Site defense waste in deep caverns constructed in basalt. This program was expanded in 1976 to include investigations of the Hanford Site as a potential location for a mined commercial nuclear waste repository. An extensive site characterization program was begun to determine the feasibility of using the basalts beneath the Hanford Site for the repository. Site research focused primarily on determining the direction and speed of groundwater movement, the uniformity of basalt layers, and tectonic stability. Some 98 boreholes were sited, drilled, deepened, or modified by BWIP between 1977 and 1988 to test the geologic properties of the Site. On December 22, 1987, President Reagan signed into law the Nuclear Waste Policy Amendments Act of 1987, which effectively stopped all repository-related activities except reclamation of disturbed lands at the Hanford Site. This report describes the development of the reclamation program for the BWIP boreholes, its implementation, and preliminary estimates of its success. The goal of the reclamation program is to return sites disturbed by the repository program as nearly as practicable to their original conditions using native plant species. 48 refs., 28 figs., 14 tabs

  6. The Age of Rift-Related Basalts in East Antarctica

    Science.gov (United States)

    Leitchenkov, G. L.; Belyatsky, B. V.; Kaminsky, V. D.

    2018-01-01

    The Lambert Rift, which is a large intracontinental rift zone in East Antarctica, developed over a long period of geological time, beginning from the Late Paleozoic, and its evolution was accompanied by magmatic activity. The latest manifestation of magmatism is eruption of alkaline olivine-leucite basalts on the western side of the Lambert Rift; Rb-Sr dating referred its time to the Middle Eocene, although its genesis remained vague. In order to solve this problem, we found geochronometer minerals in basaltic samples and 68 apatite grains appeared to be suitable for analysis. Their ages and ages of host basalts, determined by the U-Pb local method on the SIMS SHRIMP-II, were significantly different (323 ± 31 Ma) from those assumed earlier. This age corresponds to the earliest stage of crustal extension in East Antarctica and to most of Gondwana. The new data crucially change the ideas about the evolution of Lambert Rift and demonstrate the ambiguity of K-Ar dates of the alkali effusive formed under long-term rifting.

  7. Basalt Waste Isolation Project. Annual report, fiscal year 1980

    International Nuclear Information System (INIS)

    1980-11-01

    During this fiscal year the information available in the fields of geology and hydrology of the Columbia Plateau was consolidated and two reports were issued summarizing this information. In addition, the information on engineered barriers was consolidated and a report summarizing the research to date on waste package development and design of borehole seals was prepared. The waste package studies, when combined with the hydrologic integration, revealed that even under extreme disruptive conditions, a repository in basalt with appropriately designed waste packages can serve as an excellent barrier for containment of radionuclides for the long periods of time required for waste isolation. On July 1, 1980, the first two heater tests at the Near-Surface Test Facility were started and have been successfully operated to this date. The papers on the Near-Surface Test Facility section of this report present the results of the equipment installed and the preliminary results of the testing. In October 1979, the US Department of Energy selected the joint venture of Kaiser Engineers/Parsons Brinckerhoff Quade and Douglas, Inc., to be the architect-engineer to produce a conceptual design of a repository in basalt. During the year, this design has progressed and concept selection has now been completed. This annual report presents a summary of the highlights of the work completed during fiscal year 1980. It is intended to supplement and summarize the nearly 200 papers and reports that have been distributed to date as a part of the Basalt Waste Isolation Project studies

  8. Characterization of iron-enriched synthetic basalt for transuranic containment

    International Nuclear Information System (INIS)

    Flinn, J.E.; Henslee, S.P.; Kelsey, P.V.; Tallman, R.L.; Welch, J.M.

    1980-01-01

    In the slagging pyrolytic incineration process, combustibles are burned and noncombustibles, including metals, are oxidized into a molten , an electromelter, where the molten slag, with further processing conducted in a heated tundish, e.g. is allowed to homogenize (within a reasonable time period) and then cast into large, cylindrical metal containers. Analyses of Idaho National Engineering Laboratory waste slags show them similar in composition and appearance to natural basalts, but rich in iron. The electromelt process and the resulting iron-rich castings offer great promise for rendering nuclear waste into a stable form. The process offers great flexibility with regard to both compositional variation of the incoming waste and the high rates at which the waste can be introduced and cast. The cast product, a fine-grained basalt-like material, shows excellent homogeneity with little or no reaction to the steel containment. The preliminary mechanical and chemical durability data show the form to have adequate containment properties for TRU waste. However, work presently underway to improve these properties through additives and controlled cooling cycles has greatly enhanced the durability of the waste form. Furthermore, recent evidence indicates that divalent iron (Fe 2+ ) included in the crystalline phases of granites and basalts imparts a resistance to leaching of uranium and other actinide ions

  9. Fractography of glass

    CERN Document Server

    Tressler, Richard

    1994-01-01

    As the first major reference on glass fractography, contributors to this volume offer a comprehensive account of the fracture of glass as well as various fracture surface topography Contributors discuss optical fibers, glass containers, and flatglass fractography In addition, papers explore fracture origins; the growth of the original flaws of defects; and macroscopic fracture patterns from which fracture patterns evolve This volume is complete with photographs and schematics

  10. Diamond turning of glass

    Energy Technology Data Exchange (ETDEWEB)

    Blackley, W.S.; Scattergood, R.O.

    1988-12-01

    A new research initiative will be undertaken to investigate the critical cutting depth concepts for single point diamond turning of brittle, amorphous materials. Inorganic glasses and a brittle, thermoset polymer (organic glass) are the principal candidate materials. Interrupted cutting tests similar to those done in earlier research are Ge and Si crystals will be made to obtain critical depth values as a function of machining parameters. The results will provide systematic data with which to assess machining performance on glasses and amorphous materials

  11. Glass to contain wastes

    International Nuclear Information System (INIS)

    Moncouyoux, M.; Jacquet-Francillon, M.

    1994-01-01

    Here are the tables and figures presented during the conference on the glass to confine high level radioactive wastes: definition, fabrication, storage and disposal. The composition of glasses are detailed, their properties and the vitrification proceeding. The behaviour of these glasses in front of water, irradiation and heat are shown. The characteristics of parcels are given according to the radiation protection rule, ALARA principle, the concept of multi-barriers and the geological stability

  12. Glass microspheres for brachytherapy

    International Nuclear Information System (INIS)

    Prado, Miguel O.; Prastalo, Simon; Blaumann, Herman; Longhino, Juan M.; Repetto Llamazares, A.H.V.

    2007-01-01

    We developed the capacity to produce glass microspheres containing in their structure one or more radioactive isotopes useful for brachytherapy. We studied the various facts related with their production: (Rare earth) alumino silicate glass making, glass characterization, microspheres production, nuclear activation through (n,γ) nuclear reactions, mechanical characterization before and after irradiation. Corrosion tests in simulated human plasma and mechanical properties characterization were done before and after irradiation. (author) [es

  13. Silicate glasses. Chapter 1

    International Nuclear Information System (INIS)

    Lutze, W.

    1988-01-01

    This chapter is a survey of world-wide research and development efforts in nuclear waste glasses and its production technology. The principal glasses considered are silicate glasses which contain boron, i.e. borosilicate glass. A historical overview of waste form development programs in nine countries is followed by a summary of the design criteria for borosilicate glass compositions glass compositions. In the sections on glass properties the waste form is characterized in terms of potential alterations under the influence of heat, thermal gradients, radiation, aqueous solutions and combinations thereof. The topics are phase transformations, mechanical properties, radiation effects and chemical durability. The results from studies of volcanic glasses, as natural analogues for borosilicate nuclear waste glasses in order to verify predictions obtained from short-term tests in the laboratory, have been compiled in a special section on natural analogues. A special section on advanced vitrification techniques summarizes the various actual and potential processing schemes and describes the facilities. The literature has been considered until 1985. (author). 430 refs.; 68 figs.; 29 tabs

  14. Glass and vitrification

    International Nuclear Information System (INIS)

    Barton, J.L.; Vacher, R.; Moncouyoux, J.P.; Vernaz, E.

    1997-01-01

    Most glasses used as materials are oxides glasses that are produced by a quick quench of a liquid. Glasses are characterized by the absence of periodicity in the atomic arrangements, they do not have symmetries and do not present order over a long distance. This series of 4 short articles present: 1) the properties of glass and its industrial story, 2) the glass structure, 3) a forty years long story of glass as dies used to confine wastes and 4) the methodology used to study the behaviour of glass over very long periods of time. This methodology is based on 5 steps: 1) define and specify the material to study (the prediction of long term alteration of a material is nonsense unless you know well its initial properties), 2) identify all the alteration processes that are likely to happen, determine their kinetics and the influence of environmental parameters, 3) develop mathematical models in order to simulate long-term behaviour of glasses, 4) determine the release rates of the radionuclides confined in the glass, and 5) validate data and models, it is not possible to expect a complete validation of a model that will be extrapolated over tens of thousands of years, nevertheless some ways of validation can lead to a satisfactory level of confidence taking into account reasonable uncertainties. (A.C.)

  15. Strontium isotopic and trace element geochemistry of the saddle mountains and Grande Ronde Basalts of the Columbia River Basalt Group

    International Nuclear Information System (INIS)

    Nelson, D.O.

    1980-01-01

    The Columbia River Basalt (CRB) group displays significant variations in major and trace element and Sr isotopic compositions. These compositions reflect complex and variable origins for the CRB magmas. Among the most varied is the Saddle Mountains Basalt (SMB) in which Sr ratios vary from 0.7078 to 0.7147 +- 0.002. The higher ratios reflect contamination through consistent correlations with major element compositions. Modeling suggests contamination by assimilation of 4.4 to 9.4 wt % of radiogenic crustal rocks. High delta 18 O values (up to +7.68 per mil) support the model. Age and field relations suggest that the contamination flowrocks are not the result of progressive contamination of a single magma, but rather reflect the contamination of independent magmas during this ascent

  16. On the potential for CO2 mineral storage in continental flood basalts – PHREEQC batch- and 1D diffusion–reaction simulations

    Directory of Open Access Journals (Sweden)

    Van Pham Thi

    2012-06-01

    Full Text Available Abstract Continental flood basalts (CFB are considered as potential CO2 storage sites because of their high reactivity and abundant divalent metal ions that can potentially trap carbon for geological timescales. Moreover, laterally extensive CFB are found in many place in the world within reasonable distances from major CO2 point emission sources. Based on the mineral and glass composition of the Columbia River Basalt (CRB we estimated the potential of CFB to store CO2 in secondary carbonates. We simulated the system using kinetic dependent dissolution of primary basalt-minerals (pyroxene, feldspar and glass and the local equilibrium assumption for secondary phases (weathering products. The simulations were divided into closed-system batch simulations at a constant CO2 pressure of 100 bar with sensitivity studies of temperature and reactive surface area, an evaluation of the reactivity of H2O in scCO2, and finally 1D reactive diffusion simulations giving reactivity at CO2 pressures varying from 0 to 100 bar. Although the uncertainty in reactive surface area and corresponding reaction rates are large, we have estimated the potential for CO2 mineral storage and identified factors that control the maximum extent of carbonation. The simulations showed that formation of carbonates from basalt at 40 C may be limited to the formation of siderite and possibly FeMg carbonates. Calcium was largely consumed by zeolite and oxide instead of forming carbonates. At higher temperatures (60 – 100 C, magnesite is suggested to form together with siderite and ankerite. The maximum potential of CO2 stored as solid carbonates, if CO2 is supplied to the reactions unlimited, is shown to depend on the availability of pore space as the hydration and carbonation reactions increase the solid volume and clog the pore space. For systems such as in the scCO2 phase with limited amount of water, the total carbonation potential is limited by the amount of water present

  17. A comparison of the performance of nuclear waste glasses by modeling

    International Nuclear Information System (INIS)

    Grambow, B.; Strachan, D.M.

    1988-01-01

    A model selected for the licensing process must be based on a physical and chemical understanding of the glass corrosion mechanism. The purpose of this paper is to show that a dissolution/precipitation model can be used to better understand the effects of various system variables on glass dissolution. The application and validation of this model are also discussed. A dissolution/precipitation model developed appears applicable to experiments with a wide range of solution compositions as well as to more complex systems, such as the bentonite/glass/water system the steel corrosion product/glass/water system, or the dissolution of natural basalt glass in a geologic environment. This model is based on solution chemistry and transition state theory. The theoretical background of this model is discussed elsewhere and is used to describe the dissolution behavior of three nuclear waste glasses. These glasses were selected because they represent a wide range of behavior and, therefore, could be used to illustrate the capabilities of the dissolution/precipitation model. The effects of parameters, such as temperature and starting solution composition, on the dissolution behavior of glass are also discussed. 27 refs., 10 figs., 1 tab

  18. Prokaryotic diversity, distribution, and insights into their role in biogeochemical cycling in marine basalts and gabbros

    Science.gov (United States)

    Mason, O. U.; di Meo-Savoie, C. A.; Nakagawa, T.; van Nostrand, J. D.; Rosner, M.; Maruyama, A.; Zhou, J.; Fisk, M. R.; Giovannoni, S. J.

    2008-12-01

    Oceanic crust covers nearly 70% of the Earth's surface, of which, the upper, sediment layer is estimated to harbor substantial microbial biomass. Marine crust, however, extends several kilometers beyond this surficial layer, and includes the basalt and gabbro layers. The microbial diversity in basalts is well characterized, yet metabolic diversity is unknown. To date, the microflora associated with gabbros, including microbial and metabolic diversity has not been reported. In our analyses basaltic and gabbroic endoliths were analyzed using terminal restriction fragment length polymorphism, cloning and sequencing, and microarray analysis of functional genes. Our results suggest that despite nearly identical chemical compositions of basalt and gabbro the associated microflora did not overlap. Basalt samples harbor a surprising diversity of seemingly cosmopolitan microorganisms, some of which appear to be basalt specialists. Conversely, gabbros have a low diversity of endoliths, none of which appear to be specifically adapted to the gabbroic environment. Microarray analysis (GeoChip) was used to assay for functional gene diversity in basalts and gabbros. In basalt genes coding for previously unreported processes such as carbon fixation, methane-oxidation, methanogenesis, and nitrogen fixation were present, suggesting that basalts harbor previously unrecognized metabolic diversity. Similar processes were observed in gabbroic samples, yet metabolic inference from phylogenetic relationships of gabbroic endoliths with other microorganisms, suggests that hydrocarbon oxidation is the prevailing metabolism in this environment. Our analyses revealed that the basalt and gabbro layers harbor microorganisms with the genetic potential to significantly impact biogeochemical cycling in the lithosphere and overlying hydrosphere.

  19. Assessing Eruption Column Height in Ancient Flood Basalt Eruptions

    Science.gov (United States)

    Glaze, Lori S.; Self, Stephen; Schmidt, Anja; Hunter, Stephen J.

    2015-01-01

    A buoyant plume model is used to explore the ability of flood basalt eruptions to inject climate-relevant gases into the stratosphere. An example from the 1986 Izu-Oshima basaltic fissure eruption validates the model's ability to reproduce the observed maximum plume heights of 12-16 km above sea level, sustained above fire-fountains. The model predicts maximum plume heights of 13-17 km for source widths of between 4-16 m when 32% (by mass) of the erupted magma is fragmented and involved in the buoyant plume (effective volatile content of 6 wt%). Assuming that the Miocene-age Roza eruption (part of the Columbia River Basalt Group) sustained fire-fountains of similar height to Izu-Oshima (1.6 km above the vent), we show that the Roza eruption could have sustained buoyant ash and gas plumes that extended into the stratosphere at approximately 45 deg N. Assuming 5 km long active fissure segments and 9000 Mt of SO2 released during explosive phases over a 10-15 year duration, the approximately 180 km of known Roza fissure length could have supported approximately 36 explosive events/phases, each with a duration of 3-4 days. Each 5 km fissure segment could have emitted 62 Mt of SO2 per day into the stratosphere while actively fountaining, the equivalent of about three 1991 Mount Pinatubo eruptions per day. Each fissure segment could have had one to several vents, which subsequently produced lava without significant fountaining for a longer period within the decades-long eruption. Sensitivity of plume rise height to ancient atmospheric conditions is explored. Although eruptions in the Deccan Traps (approximately 66 Ma) may have generated buoyant plumes that rose to altitudes in excess of 18 km, they may not have reached the stratosphere because the tropopause was substantially higher in the late Cretaceous. Our results indicate that some flood basalt eruptions, such as Roza, were capable of repeatedly injecting large masses of SO2 into the stratosphere. Thus sustained

  20. Characterization of glass and glass ceramic nuclear waste forms

    International Nuclear Information System (INIS)

    Lutze, W.; Borchardt, J.; De, A.K.

    1979-01-01

    Characteristics of solidified nuclear waste forms, glass and glass ceramic compositions and the properties (composition, thermal stability, crystallization, phase behavior, chemical stability, mechanical stability, and radiation effects) of glasses and glass ceramics are discussed. The preparation of glass ceramics may be an optional step for proposed vitrification plants if tailored glasses are used. Glass ceramics exhibit some improved properties with respect to glasses. The overall leach resistance is similar to that of glasses. An increased leach resistance may become effective for single radionuclides being hosted in highly insoluble crystal phases mainly when higher melting temperatures are applicable in order to get more leach resistant residual glass phases. The development of glass ceramic is going on. The technological feasibility is still to be demonstrated. The potential gain of stability when using glass ceramics qualifies the material as an alternative nuclear waste form

  1. In-situ subaqueous capping of mercury-contaminated sediments in a fresh-water aquatic system, Part I—Bench-scale microcosm study to assess methylmercury production

    International Nuclear Information System (INIS)

    Randall, Paul M.; Fimmen, Ryan; Lal, Vivek; Darlington, Ramona

    2013-01-01

    Bench-scale microcosm experiments were designed to provide a better understanding of the potential for Hg methylation in sediments from an aquatic environment. Experiments were conducted to examine the function of sulfate concentration, lactate concentration, the presence/absence of an aqueous inorganic Hg spike, and the presence/absence of inoculums of Desulfovibrio desulfuricans, a strain of sulfate-reducing bacteria (SRB) commonly found in the natural sediments of aquatic environments. Incubations were analyzed for both the rate and extent of (methylmercury) MeHg production. Methylation rates were estimated by analyzing MeHg and Hg after 2, 7, 14, 28, and 42 days. The production of metabolic byproducts, including dissolved gases as a proxy for metabolic utilization of carbon substrate, was also monitored. In all treatments amended with lactate, sulfate, Hg, and SRB, MeHg was produced (37 ng/g-sediment dry weight) after only 48 h of incubation and reached a maximum sediment concentration of 127 ng/g-sediment dry weight after the 42 day incubation period. Aqueous phase production of MeHg was observed to be 10 ng/L after 2 day, reaching a maximum observed concentration of 32.8 ng/L after 14 days, and declining to 10.8 ng/L at the end of the incubation period (42 day). The results of this study further demonstrates that, in the presence of an organic carbon substrate, sulfate, and the appropriate consortia of microorganisms, sedimentary Hg will be transformed into MeHg through bacterial metabolism. Further, this study provided the basis for evaluation of an in-situ subaqueous capping strategy that may limit (or potentially enhance) MeHg production. -- Highlights: • Hg methylation by SRB is limited by the depletion of sulfate and carbon. • Hg methylation is sensitive to competition by methanogens for carbon substrate. • In high lactate environment, all lactate was utilized in the microcosms within seven days. • In the absence of adequate metabolic fuel, Me

  2. In-situ subaqueous capping of mercury-contaminated sediments in a fresh-water aquatic system, Part I—Bench-scale microcosm study to assess methylmercury production

    Energy Technology Data Exchange (ETDEWEB)

    Randall, Paul M., E-mail: randall.paul@epa.gov [U.S. Environmental Protection Agency, Office of Research and Development, National Risk Management Research Laboratory, 26 W. Martin Luther King Drive, Cincinnati, OH 45268 (United States); Fimmen, Ryan [Geosyntec Consultants, 150 E. Wilson Bridge Road, Suite 232, Worthington, OH 43085 (United States); Lal, Vivek; Darlington, Ramona [Battelle, 505 King Ave., Columbus, OH 43201 (United States)

    2013-08-15

    Bench-scale microcosm experiments were designed to provide a better understanding of the potential for Hg methylation in sediments from an aquatic environment. Experiments were conducted to examine the function of sulfate concentration, lactate concentration, the presence/absence of an aqueous inorganic Hg spike, and the presence/absence of inoculums of Desulfovibrio desulfuricans, a strain of sulfate-reducing bacteria (SRB) commonly found in the natural sediments of aquatic environments. Incubations were analyzed for both the rate and extent of (methylmercury) MeHg production. Methylation rates were estimated by analyzing MeHg and Hg after 2, 7, 14, 28, and 42 days. The production of metabolic byproducts, including dissolved gases as a proxy for metabolic utilization of carbon substrate, was also monitored. In all treatments amended with lactate, sulfate, Hg, and SRB, MeHg was produced (37 ng/g-sediment dry weight) after only 48 h of incubation and reached a maximum sediment concentration of 127 ng/g-sediment dry weight after the 42 day incubation period. Aqueous phase production of MeHg was observed to be 10 ng/L after 2 day, reaching a maximum observed concentration of 32.8 ng/L after 14 days, and declining to 10.8 ng/L at the end of the incubation period (42 day). The results of this study further demonstrates that, in the presence of an organic carbon substrate, sulfate, and the appropriate consortia of microorganisms, sedimentary Hg will be transformed into MeHg through bacterial metabolism. Further, this study provided the basis for evaluation of an in-situ subaqueous capping strategy that may limit (or potentially enhance) MeHg production. -- Highlights: • Hg methylation by SRB is limited by the depletion of sulfate and carbon. • Hg methylation is sensitive to competition by methanogens for carbon substrate. • In high lactate environment, all lactate was utilized in the microcosms within seven days. • In the absence of adequate metabolic fuel, Me

  3. Relaxations in spin glasses: Similarities and differences from ordinary glasses

    International Nuclear Information System (INIS)

    Ngai, K.L.; Rajagopal, A.K.; Huang, C.Y.

    1984-01-01

    Relaxation phenomena have become a major concern in the physics of spin glasses. There are certain resemblances of these relaxation properties to those of ordinary glasses. In this work, we compare the relaxation properties of spin glasses near the freezing temperature with those of glasses near the glass transition temperature. There are similarities between the two types of glasses. Moreover, the relaxation properties of many glasses and spin glasses are in conformity with two coupled ''universality'' relations predicted by a recent model of relaxations in condensed matter

  4. Evaluation of Structural Cellular Glass

    Science.gov (United States)

    Adams, M. A.; Zwissler, J. G.

    1984-01-01

    Preliminary design information presented. First report discusses state of structural-cellular-glass programs as of June 1979. Second report gives further details of program to develop improved cellular glasses and to characterize properties of glasses and commercially available materials.

  5. Electric glass capturing markets

    Energy Technology Data Exchange (ETDEWEB)

    Wikman, K.; Wikstroem, T.

    1996-11-01

    Electric glass has found its place on the construction market. In public buildings, electrically heatable windows are becoming the leading option for large glass walls. Studies on detached houses, both new and renovated, show that floor heating combined with electrically heatable windowpanes is the best choice with respect to resident`s comfort. (orig.)

  6. Radioresistance of inorganic glasses

    International Nuclear Information System (INIS)

    Vorob'ev, A.A.; Zavadovskaya, E.K.; Fedorov, B.V.; Starodubtsev, V.A.

    1977-01-01

    Regularities are considered in the variation of properties of glass due to irradiations. On the basis of previous theoretical statements and experimental investigations, it is inferred that the irradiation resistance of glasses of the same type, synthesis conditions, content of impurities and amount of imperfections, is a function of the ''element-oxygen'' bond energy. The irradiation resistance depends on the number and the nature of glass structure imperfections. The averaged level of bonding forces is indicative of the glass formation temperature; the imperfections in glasses are formed in structure elements whose amount predominates as compared to the others. Electric charges which accumulate on the crack surface tend to increase its size, thus lessening even further the electric strength of the dielectric. The greater the irradiation time, the greater the number of irradiation imperfections causing a drop in the electric strength of glass. When choosing a glass for service in a radiation field, it is necessary to select those of a highest temperature of glass formation and with a least amount of imperfections

  7. Nucleation in ZBLAN glasses

    NARCIS (Netherlands)

    de Leede, G.L.A.; Waal, de H.

    1989-01-01

    Nucleation rates were detd. in a ZrF4-BaF2-NaF-LaF3-AlF3 glass (ZBLAN) using an optical method. The results were compared with a similar glass having a slightly different compn. The difference in the nucleation rate is explained by classical nucleation theory using calcd. free-energy differences

  8. UTILIZATION OF BASALT FIBERS AS A RAW MATERIAL FOR CLAY CERAMIC PRODUCTION

    Directory of Open Access Journals (Sweden)

    Supawan Vichaphund

    2016-03-01

    Full Text Available This research aimed to investigate the possibility of utilization basalt fibers as a raw material for ceramic production. Both quartz and feldspar were replaced partially or entirely by basalt fiber in the range of 10-25 wt%. The mixture of ceramic powders and basalt fibers were uniaxially pressed and sintered at temperatures between 1000 and 1200°C for 1 h. The substitution of basalt fibers in ceramic compositions demonstrated the positive effect on the physical and mechanical properties. The addition of basalt fibers in an appropriate amount enhance the densification and reduce sintering temperature of clay-based ceramics (CB-0 from 1200 to 1150°C. The highest density and strength were 2.40 g/cm³ and 116 MPa, respectively, when replacing feldspar and quartz with basalt up to 20 wt% (CB-20 and sintering at 1150°C.

  9. Mechanical relaxation in glasses

    International Nuclear Information System (INIS)

    Hiki, Y.

    2004-01-01

    The basic properties of glasses and the characteristics of mechanical relaxation in glasses were briefly reviewed, and then our studies concerned were presented. Experimental methods adopted were viscosity, internal friction, ultrasonic attenuation, and Brillouin scattering measurements. The specimens used were several kinds of inorganic, organic, and metallic glasses. The measurements were mainly carried out from the room temperature up to the glass transition temperature, and the relaxation time was determined as a function of temperature. The 'double relaxation' composed of two Arrhenius-type relaxations was observed in many materials. In both relaxations, the 'compensation effect' showing a correlation of the pre-exponential factor and the activation energy was observed. These results were explained by considering the 'complex relaxation' due to cooperative motions of atoms or group of atoms. Values of activation energy near the glass transition determined by the various experimental methods were compared with each other

  10. Polymorphism in glasses

    International Nuclear Information System (INIS)

    Landa, L.M.; Nikolaeva, I.N.

    1979-01-01

    To defect phase interfaces and spasmodic properties change, the inhomogeneity and the second radiation effects in quartz glass, metamict phase and intermediate states have been investigated. When irradiating with fast neutrons the transformation of quartz glass - metamict phase occurs completely. The transformation is completed at 2x10 20 part./cm 2 dose. Thermal treatment not only increases the number of inhomogeneities but also results in increasing quartz glass density. Annealing transforms the metamict phase into common quartz glass at 1400 K. The fact, that thermal treatment results in the complete transformation of metamict phase into quartz glass, and the inverse transformation occurs only partially, is quite regular, as the metamict phase has a lesser entropy and is a more ordered state. It is shown that different amorphous phases of a chemical composition have different structures and properties, that there are interfaces between them, and the transformation from one state to another in microvolumes is realized spasmodically and requires expenditure of energy

  11. Glass leaching performance

    International Nuclear Information System (INIS)

    Chick, L.A.; Turcotte, R.P.

    1983-05-01

    Current understanding of the leaching performance of high-level nuclear waste (HLW) glass is summarized. The empirical model of waste glass leaching behavior developed shows that at high water flow rates the glass leach rate is kinetically limited to a maximum value. At intermediate water flow rates, leaching is limited by the solution concentration of silica and decreases with decreasing water flow rates. Release of soluble elements is controlled by silica dissolution because silica forms the binding network of the glass. At low water flow rates, mass loss rates reach values controlled by formation rates of alteration minerals, or by diffusion of dissolution products through essentially stagnant water. The parameters reviewed with respect to their quantifiable influence on leaching behavior include temperature, pH, leachant composition, glass composition, thermal history, and radiation. Of these, temperature is most important since the rate of mass loss approximately doubles with each 10 0 C increase in dilute solutions. The pH has small effects within the 4 to 10 range. The chemical composition of the leachant is most important with regard to its influence on alteration product formation. Glass composition exhibits the largest effects at high flow rates where improved glasses leach from ten to thirty times slower than glass 76 to 68. The effects of the thermal history (devitrification) of the glass are not likely to be significant. Radiation effects are important primarily in that radiolysis can potentially drive pH values to less than 4. Radiation damage to the glass causes insignificant changes in leaching performance

  12. Methods of simulating low redox potential (Eh) for a basalt repository

    International Nuclear Information System (INIS)

    Jantzen, C.M.

    1983-01-01

    Basalt groundwaters have inherently low redox potentials, approximately -0.4V, which can be measured with platinum electrodes, but are difficult to reproduce during leaching experiments. In the presence of deionized water, crushed basalt reaches the measured Eh-pH values of a basalt repository. Other waste package components, such as iron, will interact with groundwater in different ways under oxic or anoxic conditions since the presence of any redox active solid will affect the groundwater Eh. 26 references, 4 figures

  13. Engineered barrier development for a nuclear waste repository in basalt: an integration of current knowledge

    International Nuclear Information System (INIS)

    Smith, M.J.

    1980-05-01

    This document represents a compilation of data and interpretive studies conducted as part of the engineered barriers program of the Basalt Waste Isolation Project. The overall objective of these studies is to provide information on barrier system designs, emplacement and isolation techniques, and chemical reactions expected in a nuclear waste repository located in the basalts underlying the Hanford Site within the state of Washington. Backfills, waste-basalt interactions, sorption, borehole plugging, etc., are among the topics discussed

  14. Engineered barrier development for a nuclear waste repository in basalt: an integration of current knowledge

    Energy Technology Data Exchange (ETDEWEB)

    Smith, M.J.

    1980-05-01

    This document represents a compilation of data and interpretive studies conducted as part of the engineered barriers program of the Basalt Waste Isolation Project. The overall objective of these studies is to provide information on barrier system designs, emplacement and isolation techniques, and chemical reactions expected in a nuclear waste repository located in the basalts underlying the Hanford Site within the state of Washington. Backfills, waste-basalt interactions, sorption, borehole plugging, etc., are among the topics discussed.

  15. The hardness of synthetic products obtained from cooled and crystallized basaltic melts (in Romanian)

    OpenAIRE

    Daniela Ogrean

    2001-01-01

    The Hardness of Synthetic Products Obtained from Cooled and Crystallized Basaltic Melts. Hardness is one of the main properties of the products obtained from cooled and crystallized basaltic melts under a controlled thermal regime. It influences the abrasion tear resistance of the resulted material. The microhardness measurements on the samples (bricks, boards, gutters, armour plates, tubes) indicated Vickers hardness value between 757–926 for the materials obtained from Şanovita basalts (Tim...

  16. Rb-Sr and Sm-Nd chronology and genealogy of mare basalts from the Sea of Tranquility

    Science.gov (United States)

    Papanastassiou, D. A.; Depaolo, D. J.; Wasserburg, G. J.

    1977-01-01

    Rb-Sr and Sm-Nd ages of two Apollo 11 mare basalts, high-K basalt 10072 and low-K basalt 10062, are reported. Rb-Sr, Sm-Nd, and Ar-40-Ar-39 ages are in good agreement and indicate an extensive time interval for filling of the Sea of Tranquility, presumably by thin lava flows, in agreement with similar observations for the Ocean of Storms. Initial Sr and Nd isotopic compositions on Apollo 11 basalts reveal at least two parent sources producing basalts. The Sm-Nd isotopic data demonstrate that low-K and high-Ti basalts from Apollo 11 and 17 derived from distinct reservoirs, while low-Ti Apollo 15 mare basalt sources have Sm/Nd similar to the sources of Apollo 11 basalts. Groupings of mare basalt based on Ti content and on isotopic data do not coincide.

  17. Geology of the Sabie River Basalt Formation in the Southern Kruger National Park

    Directory of Open Access Journals (Sweden)

    R.J. Sweeney

    1986-11-01

    Full Text Available The Sabie River Basalt Formation (SRBF in the central Lebombo is a virtually continuous sequence of basaltic lavas some 2 500 m thick that was erupted 200 - 179 Ma ago. Flows are dominantly pahoehoe in character and vary from 2 m to 20 m in thickness. Dolerite dykes cross-cutting the basalt sequence probably represent feeders to this considerable volcanic event. Volcanological features observed within the SRBF are described. Two chemically distinct basaltic magma types are recognised, the simultaneous eruption of which presents an intriguing geochemical problem as to their origins.

  18. Radiation shielding properties of a novel cement–basalt mixture for nuclear energy applications

    Energy Technology Data Exchange (ETDEWEB)

    Ipbüker, Cagatay; Nulk, Helena; Gulik, Volodymyr [University of Tartu, Institute of Physics (Estonia); Biland, Alex [HHK Technologies, Houston (United States); Tkaczyk, Alan Henry, E-mail: alan@ut.ee [University of Tartu, Institute of Physics (Estonia)

    2015-04-01

    Highlights: • Basalt fiber is a relatively cheap material that can be used as reinforcement. • Gamma-ray attenuation remains relatively stable with addition of basalt fiber. • Neutron attenuation remains relatively stable with addition of basalt fiber. • Cement–basalt mixture has a good potential for use in nuclear energy applications. - Abstract: The radiation shielding properties of a new proposed building material, a novel cement–basalt fiber mixture (CBM), are investigated. The authors analyze the possibility of this material to be a viable substitute to outgoing materials in nuclear energy applications, which will lead to a further sustained development of nuclear energy in the future. This computational study involves four types of concrete with various amounts of basalt fiber in them. The gamma-ray shielding characteristics of proposed CBM material are investigated with the help of WinXCom program, whereas the neutron shielding characteristics are computed by the Serpent code. For gamma-ray shielding, we find that the attenuation coefficients of concretes with basalt fibers are not notably influenced by the addition of fibers. For neutron shielding, additional basalt fiber in mixture presents negligible effect on neutron radiation shielding. With respect to radiation shielding, it can be concluded that basalt fibers have good potential as an addition to heavyweight concrete for nuclear energy applications.

  19. Basalt fiber manufacturing technology and the possibility of its use in dentistry

    International Nuclear Information System (INIS)

    Karavaeva, E; Rogozhnikov, A; Nikitin, V; Cherepennikov, Yu; Lysakov, A

    2015-01-01

    The article touches upon the technology of basalt fiber manufacturing and prospects of its use in dental practice. Two kinds of construction using basalt fiber have been proposed. The first one is a splinting construction for mobile teeth and the second one is the reinforced base for removable plate-denture. The work presents the results of the investigation of physical and mechanical properties of the constructions based on basalt fiber. It also describes the aspects of biomechanical modeling of such constructions in the ANSYS software package. The results of the investigation have proved that applying constructions using basalt fiber is highly promising for prosthetic dentistry practice. (paper)

  20. Basalt fiber manufacturing technology and the possibility of its use in dentistry

    Science.gov (United States)

    Karavaeva, E.; Rogozhnikov, A.; Nikitin, V.; Cherepennikov, Yu; Lysakov, A.

    2015-11-01

    The article touches upon the technology of basalt fiber manufacturing and prospects of its use in dental practice. Two kinds of construction using basalt fiber have been proposed. The first one is a splinting construction for mobile teeth and the second one is the reinforced base for removable plate-denture. The work presents the results of the investigation of physical and mechanical properties of the constructions based on basalt fiber. It also describes the aspects of biomechanical modeling of such constructions in the ANSYS software package. The results of the investigation have proved that applying constructions using basalt fiber is highly promising for prosthetic dentistry practice.

  1. Radiation shielding properties of a novel cement–basalt mixture for nuclear energy applications

    International Nuclear Information System (INIS)

    Ipbüker, Cagatay; Nulk, Helena; Gulik, Volodymyr; Biland, Alex; Tkaczyk, Alan Henry

    2015-01-01

    Highlights: • Basalt fiber is a relatively cheap material that can be used as reinforcement. • Gamma-ray attenuation remains relatively stable with addition of basalt fiber. • Neutron attenuation remains relatively stable with addition of basalt fiber. • Cement–basalt mixture has a good potential for use in nuclear energy applications. - Abstract: The radiation shielding properties of a new proposed building material, a novel cement–basalt fiber mixture (CBM), are investigated. The authors analyze the possibility of this material to be a viable substitute to outgoing materials in nuclear energy applications, which will lead to a further sustained development of nuclear energy in the future. This computational study involves four types of concrete with various amounts of basalt fiber in them. The gamma-ray shielding characteristics of proposed CBM material are investigated with the help of WinXCom program, whereas the neutron shielding characteristics are computed by the Serpent code. For gamma-ray shielding, we find that the attenuation coefficients of concretes with basalt fibers are not notably influenced by the addition of fibers. For neutron shielding, additional basalt fiber in mixture presents negligible effect on neutron radiation shielding. With respect to radiation shielding, it can be concluded that basalt fibers have good potential as an addition to heavyweight concrete for nuclear energy applications

  2. Nuclear waste repository in basalt: preconceptual design guidelines

    International Nuclear Information System (INIS)

    1979-06-01

    The development of the basalt waste isolation program parallels the growing need for permanent, environmentally safe, and secure means to store nuclear wastes. The repository will be located within the Columbia Plateau basalt formations where these ends can be met and radiological waste can be stored. These wastes will be stored such that the wastes may be retrieved from storage for a period after placement. After the retrieval period, the storage locations will be prepared for terminal storage. The terminal storage requirements will include decommissioning provisions. The facility boundaries will encompass no more than several square miles of land which will be above a subsurface area where the geologic makeup is primarily deep basaltic rock. The repository will receive, from an encapsulation site(s), nuclear waste in the form of canisters (not more than 18.5 feet x 16 inches in diameter) and containers (55-gallon drums). Canisters will contain spent fuel (after an interim 5-year storage period), solidified high-level wastes (HLW), or intermediate-level wastes (ILW). The containers (drums) will package the low-level transuranic wastes (LL-TRU). The storage capacity of the repository will be expanded in a time-phased program which will require that subsurface development (repository expansion) be conducted concurrently with waste storage operations. The repository will be designed to store the nuclear waste generated within the predictable future and to allow for reasonable expansion. The development and assurance of safe waste isolation is of paramount importance. All activities will be dedicated to the protection of public health and the environment. The repository will be licensed by the US Nuclear Regulatory Commission (NRC). Extensive efforts will be made to assure selection of a suitable site which will provide adequate isolation

  3. Nuclear waste repository in basalt: preconceptual design guidelines

    Energy Technology Data Exchange (ETDEWEB)

    1979-06-01

    The development of the basalt waste isolation program parallels the growing need for permanent, environmentally safe, and secure means to store nuclear wastes. The repository will be located within the Columbia Plateau basalt formations where these ends can be met and radiological waste can be stored. These wastes will be stored such that the wastes may be retrieved from storage for a period after placement. After the retrieval period, the storage locations will be prepared for terminal storage. The terminal storage requirements will include decommissioning provisions. The facility boundaries will encompass no more than several square miles of land which will be above a subsurface area where the geologic makeup is primarily deep basaltic rock. The repository will receive, from an encapsulation site(s), nuclear waste in the form of canisters (not more than 18.5 feet x 16 inches in diameter) and containers (55-gallon drums). Canisters will contain spent fuel (after an interim 5-year storage period), solidified high-level wastes (HLW), or intermediate-level wastes (ILW). The containers (drums) will package the low-level transuranic wastes (LL-TRU). The storage capacity of the repository will be expanded in a time-phased program which will require that subsurface development (repository expansion) be conducted concurrently with waste storage operations. The repository will be designed to store the nuclear waste generated within the predictable future and to allow for reasonable expansion. The development and assurance of safe waste isolation is of paramount importance. All activities will be dedicated to the protection of public health and the environment. The repository will be licensed by the US Nuclear Regulatory Commission (NRC). Extensive efforts will be made to assure selection of a suitable site which will provide adequate isolation.

  4. Contrasted glass-whole rock compositions and phenocryst re-distribution, IPOD Sites 417 and 418

    Science.gov (United States)

    Staudigel, H.; Bryan, W. B.

    1982-01-01

    Major element composition ranges of closely associated basalt glass-whole rock pairs from individual small cooling units approach the total known range of basalt glass and whole rock compositions at IPOD sites 417 and 418. The whole rock samples fall into two groups: one is depleted in MgO and distinctly enriched in plagioclase but has lost some olivine and/or pyroxene relative to its corresponding glass; and the other is enriched in MgO and in phenocrysts of olivine and pyroxene as well as plagioclase compared to its corresponding glass. By analogy with observed phenocryst distributions in lava pillows, tubes, and dikes, and with some theoretical studies, we infer that bulk rock compositions are strongly affected by phenocryst redistribution due to gravity settling, flotation, and dynamic sorting after eruption, although specific models are not well constrained by the one-dimensional geometry of drill core. Compositional trends or groupings in whole rock data resulting from such late-stage processes should not be confused with more fundamental compositional effects produced in deep chambers or during partial melting.

  5. Basalt features observed in outcrops, cores, borehole video imagery and geophysical logs, and basalt hydrogeologic study at the Idaho National Engineering Laboratory, Eastern Idaho

    International Nuclear Information System (INIS)

    Bennecke, W.M.

    1996-10-01

    A study was undertaken to examine permeable zones identified in boreholes open to the underlying basalt and to describe the vertical cross flows present in the boreholes. To understand the permeable zones in the boreholes detailed descriptions and measurements of three outcrops in the Snake River Plain, three cores at the Idaho Chemical Processing Plant (ICPP) at the INEL, and over fifty borehole TV logs from the INEL were carried out. Based on the observations made on the three outcrops an idealized basalt lava flow model was generated that used a set of nomenclature that would be standard for the basalt lava flows studied. An upper vesicular zone, a sometimes absent columnar zone, central zone, and lower vesicular zone make up the basalt lava flow model. The overall distinction between the different zones are based on the vesicle shape size, vesicularity, and fractures present. The results of the studies also indicated that the basalt lava flows at the INEL are distal to medial facies pahoehoe lava flows with close fitting contacts. The most permeable zones identified in these basalts are fractured vesiculated portions of the top of the lava flow, the columnar areas, and basalt-flow contacts in order of importance. This was determined from impeller flowmeter logging at the INEL. Having this information a detailed stratigraphy of individual basalt lava flows and the corresponding permeable units were generated. From this it was concluded that groundwater flow at the ICPP prefers to travel along thin basalt lava flows or flow-units. Flow direction and velocity of intrawell flows detected by flowmeter is controlled by a nearby pumping well

  6. Sentinel Gap basalt reacted in a temperature gradient

    International Nuclear Information System (INIS)

    Charles, R.W.; Bayhurst, G.K.

    1983-01-01

    Six basalt prisms were reacted in a controlled temperature gradient hydrothermal circulation system for two months. The prisms were centered at 72, 119, 161, 209, 270, and 310 0 C. Total pressure was 1/3 kbar. All prisms showed large weight loss: 5.5% to 14.9%. The matrix micropegmatite and natural nontronitic alteration reacted readily to clays at all temperatures. The first four prisms were coated with a calcium smectite, and the last two prisms were covered with discrete patches of potassium-rich phengite and alkali feldspar. The results indicated that clays may act as adsorbers of various ions

  7. Sentinel Gap basalt reacted in a temperature gradient

    International Nuclear Information System (INIS)

    Charles, R.W.; Bayhurst, G.K.

    1982-01-01

    Six basalt prisms were reacted in a controlled temperature gradient hydrothermal circulation system for two months. The prisms are centered at 72, 119, 161, 209, 270, and 310 0 C. Total pressure is 1/3 kbar. All prisms show large weight loss: 5.5% to 14.9%. The matrix micropegmatite and natural nontronitic alteration readily reacts to clays at all temperatures. The first four prisms are coated with a Ca-smectite while the last two prisms are covered with discrete patches of K rich phengite and alkali feldspar. The clays may act as adsorbers of various ions

  8. Environmental issue identification for the Basalt Waste Isolation Project

    International Nuclear Information System (INIS)

    Carrell, D.J.; Jones, K.A.

    1980-04-01

    A preliminary evaluation of environmental issues is provided in this report. It contains summary of the thought process that was used during the area characterization studies for a geological repository for high-level radioactive wastes. Environmental issues are discussed separately for construction, operation, and long term isolation aspects of a repository in basalt. During construction the primary environmental concerns are public perception and water resources; intermediate concerns are air quality, ecosystems, physical resources, and cultural and social resources. During operation, the primary environmental issues concern the transport of radioactive materials and physical resources. Long term environmental issues envolve water resources and borehole plugging

  9. Basalt Waste Isolation Project exploratory shaft site: Final reclamation report

    International Nuclear Information System (INIS)

    Brandt, C.A.; Rickard, W.H. Jr.

    1990-06-01

    The restoration of areas disturbed by activities of the Basalt Waste Isolation Project (BWIP) constitutes a unique operation at the US Department of Energy's (DOE) Hanford Site, both from the standpoint of restoration objectives and the time frame for accomplishing these objectives. The BWIP reclamation program comprises three separate projects: borehole reclamation, Near Surface Test Facility (NSTF) reclamation, and Exploratory Shaft Facility (ESF) reclamation. The main focus of this report is on determining the success of the revegetation effort 1 year after work was completed. This report also provides a brief overview of the ESF reclamation program. 21 refs., 7 figs., 14 tabs

  10. Penetration of molten core materials into basaltic and limestone concrete

    International Nuclear Information System (INIS)

    Sutherland, H.J.

    1978-01-01

    In conjunction with the small-scale, melt-concrete interaction tests being conducted at Sandia Laboratories, an acoustic technique has been used to monitor the penetration of molten core materials into basaltic and limestone concrete. Real time plots of the position of the melt/concrete interface have been obtained, and they illustrate that the initial penetration rate of the melt may be of the order of 80 mm/min. Phenomena deduced by the technique include a non-wetted melt/concrete interface

  11. Hydrologic bibliography of the Columbia River basalts in Washington

    International Nuclear Information System (INIS)

    Tanaka, H.H.; Wildrick, L.

    1978-07-01

    This bibliography is part of the hydrologic data compilation effort of the Columbia Plateau Hydrology Study, Rockwell Hanford Operations' Waste Isolation Program. It includes references on both surface and subsurface hydrology directly or indirectly related to the Washington State portion of the Columbia River basalts. A comprehensive, annotated bibliography of the Pasco Basin (including the Hanford site) hydrology has been prepared for Rockwell Hanford Operations under the Pasco Basin Hydrology Study. In order to avoid unnecessary duplication, no effort was made to include a complete list of bibliographic references on Hanford in this volume

  12. Melt density and the average composition of basalt

    Science.gov (United States)

    Stolper, E.; Walker, D.

    1980-01-01

    Densities of residual liquids produced by low pressure fractionation of olivine-rich melts pass through a minimum when pyroxene and plagioclase joint the crystallization sequence. The observation that erupted basalt compositions cluster around the degree of fractionation from picritic liquids corresponding to the density minimum in the liquid line of descent may thus suggest that the earth's crust imposes a density fiber on the liquids that pass through it, favoring the eruption of the light liquids at the density minimum over the eruption of denser more fractionated and less fractionated liquids.

  13. Thermal Conductivity of Foam Glass

    DEFF Research Database (Denmark)

    Petersen, Rasmus Rosenlund; König, Jakob; Yue, Yuanzheng

    Due to the increased focus on energy savings and waste recycling foam glass materials have gained increased attention. The production process of foam glass is a potential low-cost recycle option for challenging waste, e.g. CRT glass and industrial waste (fly ash and slags). Foam glass is used...... as thermal insulating material in building and chemical industry. The large volume of gas (porosity 90 – 95%) is the main reason of the low thermal conductivity of the foam glass. If gases with lower thermal conductivity compared to air are entrapped in the glass melt, the derived foam glass will contain...... only closed pores and its overall thermal conductivity will be much lower than that of the foam glass with open pores. In this work we have prepared foam glass using different types of recycled glasses and different kinds of foaming agents. This enabled the formation of foam glasses having gas cells...

  14. Effect of different glasses in glass bonded zeolite

    International Nuclear Information System (INIS)

    Lewis, M.A.; Ackerman, J.P.; Verma, S.

    1995-01-01

    A mineral waste form has been developed for chloride waste salt generated during the pyrochemical treatment of spent nuclear fuel. The waste form consists of salt-occluded zeolite powders bound within a glass matrix. The zeolite contains the salt and immobilizes the fission products. The zeolite powders are hot pressed to form a mechanically stable, durable glass bonded zeolite. Further development of glass bonded zeolite as a waste form requires an understanding of the interaction between the glass and the zeolite. Properties of the glass that enhance binding and durability of the glass bonded zeolite need to be identified. Three types of glass, boroaluminosilicate, soda-lime silicate, and high silica glasses, have a range of properties and are now being investigated. Each glass was hot pressed by itself and with an equal amount of zeolite. MCC-1 leach tests were run on both. Soda-lime silicate and high silica glasses did not give a durable glass bonded zeolite. Boroaluminosilicate glasses rich in alkaline earths did bind the zeolite and gave a durable glass bonded zeolite. Scanning electron micrographs suggest that the boroaluminosilicate glasses wetted the zeolite powders better than the other glasses. Development of the glass bonded zeolite as a waste form for chloride waste salt is continuing

  15. Oxynitride glasses: a review

    Energy Technology Data Exchange (ETDEWEB)

    Garcia, A.R.; Clausell, C.; Barba, A.

    2016-07-01

    Oxynitride glasses are special types of silicates or silicoaluminates which have been the object of many studies over the last forty years. They can be prepared by means of various complex methods, leading to variable levels of nitrogen incorporation, though in all cases giving limited transparency in the visible range. More recently, a new family of oxynitride glasses incorporating fluorine has been investigated. This paper outlines the effect of composition, in particular nitrogen and fluorine content, on properties such as glass transition temperature, hardness, Young's modulus, compactness and molar volume. (Author)

  16. Orbital glass in HTSC

    International Nuclear Information System (INIS)

    Kusmartsev, F.V.

    1992-10-01

    The physical reasons why the orbital glass may exist in granular high-temperature superconductors and the existing experimental data appeared recently are discussed. The orbital glass is characterized by the coexistence of the orbital paramagnetic state with the superconducting state and occurs at small magnetic fields H c0 c1 . The transition in orbital glass arises at the critical field H c0 which is inversely proportional to the surface cross-area S of an average grain. In connection with theoretical predictions the possible experiments are proposed. (author). 10 refs

  17. Bioactive glasses and glass-ceramics

    Directory of Open Access Journals (Sweden)

    de Aza, P. N.

    2007-04-01

    Full Text Available Since the late 1960´s, a great interest in the use of bioceramic materials for biomedical applications has been developed. In a previous paper, the authors reviewed crystalline bioceramic materials “sensus stricto”, it is to say, those ceramic materials, constituted for non-metallic inorganic compounds, crystallines and consolidates by thermal treatment of powders at high temperature. In the present review, the authors deal with those called bioactive glasses and glassceramics. Although all of them are also obtained by thermal treatment at high temperature, the first are amorphous and the second are obtained by devitrification of a glass, although the vitreous phase normally prevails on the crystalline phases. After an introduction to the concept of bioactive materials, a short historical review of the bioactive glasses development is made. Its preparation, reactivity in physiological media, mechanism of bonding to living tissues and mechanical strength of the bone-implant interface is also reported. Next, the concept of glass-ceramic and the way of its preparation are exposed. The composition, physicochemical properties and biological behaviour of the principal types of bioactive glasses and glass-ceramic materials: Bioglass®, Ceravital®, Cerabone®, Ilmaplant® and Bioverit® are also reviewed. Finally, a short review on the bioactive-glass coatings and bioactive-composites and most common uses of bioactive-glasses and glass-ceramics are carried out too.

    Desde finales de los años sesenta, se ha despertado un gran interés por el uso de los materiales biocerámicos para aplicaciones biomédicas. En un trabajo previo, los autores hicieron una revisión de los denominados materiales biocerámicos cristalinos en sentido estricto, es decir, de aquellos materiales, constituidos por compuestos inorgánicos no metálicos, cristalinos y consolidados mediante tratamientos térmicos a altas temperaturas. En el presente trabajo, los autores

  18. Quality of the ground water in basalt of the Columbia River group, Washington, Oregon, and Idaho

    Science.gov (United States)

    Newcomb, Reuben Clair

    1972-01-01

    The ground water within the 50,000-square-mile area of the layered basalt of the Columbia River Group is a generally uniform bicarbonate water having calcium and sodium in nearly equal amounts as the principal cations. water contains a relatively large amount of silica. The 525 chemical analyses indicate that the prevalent ground water is of two related kinds--a calcium and a sodium water. The sodium water is more common beneath the floors of the main synclinal valleys; the calcium water, elsewhere. In addition to the prevalent type, five special types form a small part of the ground water; four of these are natural and one is artificial. The four natural special types are: (1) calcium sodium chloride waters that rise from underlying sedimentary rocks west of the Cascade Range, (2) mineralized water at or near warm or hot springs, (3) water having unusual ion concentrations, especially of chloride, near sedimentary rocks intercalated at the edges of the basalt, and (4) more mineralized water near one locality of excess carbon dioxide. The one artificial kind of special ground water has resulted from unintentional artificial recharge incidental to irrigation in parts of central Washington. The solids dissolved in the ground water have been picked up on the surface, within the overburden, and from minerals and glasses within the basalt. Evidence for the removal of ions from solution is confined to calcium and magnesium, only small amounts of which are present in some of the sodium-rich water. Minor constituents, such as the heavy metals, alkali metals, and alkali earths, occur in the ground water in trace, or small, amounts. The natural radioactivity of the ground waters is very low. Except for a few of the saline calcium sodium chloride waters and a few occurrences of excessive nitrate, the ground water generally meets the common standards of water good for most ordinary uses, but some of it can be improved by treatment. The water is clear and colorless and has a

  19. Reaction of water with a simulated high-level nuclear waste glass at 3000C, 300 bars

    International Nuclear Information System (INIS)

    McCarthy, G.J.; Scheetz, B.E.; Komarneni, S.; Smith, D.K.

    1978-01-01

    The hydrothermal stability of high-level nuclear wastes is an important consideration in establishing waste form acceptance criteria for a geological repository in basalt. A detailed examination of the stability of a typical simulated high-level waste glass and pressurized water at 300 0 C in a closed system has shown that extensive reaction occurred within a few weeks. The water acted first as a catalyst-solvent in devitrification of the glass and in dissolution, transport, and recrystallization of some of its constituents, and, second, as a reactant in forming hydrated and hydroxylated phases. This reaction with water resulted in the conversion of a solid shard of glass into a fragmented and partially dispersed mass of crystalline and noncrystalline material plus dissolved species within two weeks. The major crystalline reaction products were found to be analogs of naturally occurring minerals: (Cs,Na,Rb) 2 (UO 2 ) 2 .(Si 2 O 5 ) 3 .4H 2 O (weeksite) and a series of pyroxene-structure phases, (Na,Ca) (Fe,Zn,Ti)Si 2 O 6 (acmite, acmite--augites). Weeksite, however, is not expected to have long-term stability in the basalt environment. Much of the Na and Mo, and almost all of the B, in the original glass was identified in the product solutions. Of the elements or analogs of long-lived, hazardous radionuclides studied in this work, only Cs was observed in these solutions in substantial amounts. Although the comparatively rapid and extensive reactions at 300 0 C would appear to require that an acceptable glass would have low waste and heat loading, it is suggested that there is good potential for favorable glass--basalt--water hydrothermal interactions. Favorable interactions would mean that, in the event of a hydrothermal incident, the interaction products would be more stable than the original waste form and would remain in the immediate repository

  20. Experimental assessment of borehole wall drilling damage in basaltic rocks

    International Nuclear Information System (INIS)

    Fuenkajorn, K.; Daemen, J.J.K.

    1986-06-01

    Ring tension tests, permeability tests, and microscopic fracture studies have been performed to investigate the borehole damage induced at low confining pressure by three drilling techniques (diamond, percussion and rotary). Specimens are drilled with three hole sizes (38, 76, and 102 mm diameter) in Pomona basalt and Grande basaltic andesite. The damaged zone is characterized in terms of fractures and fracture patterns around the hole, and in terms of tensile strength reduction of the rock around the holes. Experimental results show that the thickness of the damaged zone around the hole ranges from 0.0 to 1.7 mm. A larger drill bit induces more wall damage than does a smaller one. Different drilling techniques show different damage characteristics (intensity and distribution). Damage characteristics are governed not only by drilling parameters (bit size, weight on bit, rotational speed, diamond radius, and energy), but also by properties of the rock. The weaker rock tends to show more intense damage than does the stronger one. Cracks within grains or cleavage fractures are predominant in slightly coarser grained rock (larger than 0.5 mm grain size) while intergranular cracks are predominant in very fine grained rock (smaller than 0.01 mm grain size). The damaged zones play no significant role in the flow path around a borehole plug

  1. The Disruption of Tephra Fall Deposits by Basaltic Lava Flows

    Science.gov (United States)

    Brown, R. J.; Thordarson, T.; Self, S.; Blake, S.

    2010-12-01

    Complex physical and stratigraphic relationships between lava and proximal tephra fall deposits around vents of the Roza Member in the Columbia River Basalt Province, (CRBP), USA, illustrate how basaltic lavas can disrupt, dissect (spatially and temporally) and alter tephra fall deposits. Thin pahoehoe lobes and sheet lobes occur intercalated with tephra deposits and provide evidence for synchronous effusive and explosive activity. Tephra that accumulated on the tops of inflating pahoehoe flows became disrupted by tumuli, which dissected the overlying sheet into a series of mounds. During inflation of subjacent tumuli tephra percolated down into the clefts and rubble at the top of the lava, and in some cases came into contact with lava hot enough to thermally alter it. Lava breakouts from the tumuli intruded up through the overlying tephra deposit and fed pahoehoe flows that spread across the surface of the aggrading tephra fall deposit. Non-welded scoria fall deposits were compacted and welded to a depth of ~50 cm underneath thick sheet lobes. These processes, deduced from the field relationships, have resulted in considerable stratigraphic complexity in proximal regions. We also demonstrate that, when the advance of lava and the fallout of tephra are synchronous, the contacts of some tephra sheets can be diachronous across their extent. The net effect is to reduce the usefulness of pyroclastic deposits in reconstructing eruption dynamics.

  2. Network topology of olivine-basalt partial melts

    Science.gov (United States)

    Skemer, Philip; Chaney, Molly M.; Emmerich, Adrienne L.; Miller, Kevin J.; Zhu, Wen-lu

    2017-07-01

    The microstructural relationship between melt and solid grains in partially molten rocks influences many physical properties, including permeability, rheology, electrical conductivity and seismic wave speeds. In this study, the connectivity of melt networks in the olivine-basalt system is explored using a systematic survey of 3-D X-ray microtomographic data. Experimentally synthesized samples with 2 and 5 vol.% melt are analysed as a series of melt tubules intersecting at nodes. Each node is characterized by a coordination number (CN), which is the number of melt tubules that intersect at that location. Statistically representative volumes are described by coordination number distributions (CND). Polyhedral grains can be packed in many configurations yielding different CNDs, however widely accepted theory predicts that systems with small dihedral angles, such as olivine-basalt, should exhibit a predominant CN of four. In this study, melt objects are identified with CN = 2-8, however more than 50 per cent are CN = 4, providing experimental verification of this theoretical prediction. A conceptual model that considers the role of heterogeneity in local grain size and melt fraction is proposed to explain the formation of nodes with CN ≠ 4. Correctly identifying the melt network topology is essential to understanding the relationship between permeability and porosity, and hence the transport properties of partial molten mantle rocks.

  3. Characterization and recognition of intraflow structures, Grande Ronde Basalt

    International Nuclear Information System (INIS)

    Long, P.E.

    1978-09-01

    This investigation was carried out as part of a feasibility study for long-term storage of nuclear waste at depth in the Pasco Basin. Three general types of intraflow structures were found at Sentinel Gap: flows with stubby, irregular columns that lack a well-developed entablature; flows consisting of multiple tiers of largely entablature-type columns; and flows with a well-developed colonnade and entablature showing a sharp break between the two. Certain features occur locally in all three types of intraflow structures: variations in fracture morphology, primary platey fracture zones, pillow-palagonite zones, and tectonically induced zones of closely spaced fractures. Fractures in each of the three types of flows were logged both at the surface and in core from Core Hole DH-5, and petrographic textures of basalt sampled from surface exposures were examined. The textures of the basalt correlate with the intraflow structures and provide a technique for identifying flows as to their general type of intraflow structure, locating internal contacts between intraflow structures and possibly estimating fracture density within flows. Fracture logging, on the other hand, does not accurately delimit intraflow structures

  4. Design approaches for access plugs in a basalt repository

    International Nuclear Information System (INIS)

    O'Rourke, J.; Allirot, D.; O'Connor, K.

    1982-01-01

    This paper describes research, laboratory testing, and analytical approaches taken toward the development of designs for sealing boreholes, shafts, and tunnels penetrating from ground surface to a deep, mined nuclear waste repository in basalt. A material selection process leading to identification of preferred sealing materials is discussed, and the laboratory testing program to define the geochemical and geotechnical performance of these materials is described. Analysis of the environmental conditions in the Columbia Plateau basalt flows leads to identification of tentative design criteria for plug systems. These design criteria include performance of the plug as a hydraulic barrier and as a radionuclide barrier. An important problem for effective performance of a plug system as a hydraulic barrier is shown to be a potentially disturbed zone surrounding the excavation in the stressed and jointed host rock. An idealized one-dimensional numerical model is described for analyzing the performance of the plug as a barrier to radionuclide transport. The preliminary analyses led to the conclusion that the composition and dimensions of practical candidate plugs can satisfy both hydraulic and radionuclide barrier criteria. Examples of candidate designs are shown for boreholes, shafts, and tunnels. 9 references, 6 figures, 6 tables

  5. The microbial habitability of weathered volcanic glass inferred from continuous sensing techniques.

    Science.gov (United States)

    Bagshaw, Elizabeth A; Cockell, Charles S; Magan, Naresh; Wadham, Jemma L; Venugopalan, T; Sun, Tong; Mowlem, Matt; Croxford, Anthony J

    2011-09-01

    Basaltic glasses (hyaloclastite) are a widespread habitat for life in volcanic environments, yet their interior physical conditions are poorly characterized. We investigated the characteristics of exposed weathered basaltic glass from a surface outcrop in Iceland, using microprobes capable of continuous sensing, to determine whether the physical conditions in the rock interior are hospitable to microbial life. The material provided thermal protection from freeze-thaw and rapid temperature fluctuations, similar to data reported for other rock types. Water activity experiments showed that at moisture contents less than 13% wet weight, the glass and its weathering product, palagonite, had a water activity below levels suitable for bacterial growth. In pore spaces, however, these higher moisture conditions might be maintained for many days after a precipitation event. Gas exchange between the rock interior and exterior was rapid (< 10 min) when the rocks were dry, but when saturated with water, equilibration took many hours. During this period, we demonstrated the potential for low oxygen conditions within the rock caused by respiratory stimulation of the heterotrophic community within. These conditions might exist within subglacial environments during the formation of the rocks or in micro-environments in the interior of exposed rocks. The experiments showed that microbial communities at the site studied here could potentially be active for 39% of the year, if the depth of the community within the outcrop maintains a balance between access to liquid water and adequate protection from freezing. In the absence of precipitation, the interior of weathered basaltic glass is an extreme and life-limiting environment for microorganisms on Earth and other planets.

  6. Fun with Singing Wine Glasses

    Science.gov (United States)

    Boone, Christine; Galloway, Melodie; Ruiz, Michael J.

    2018-01-01

    A fun activity is presented using singing wine glasses for introductory physics students. Students tune a white wine glass and a red wine glass to as many semitones as possible by filling the glasses with the appropriate amounts of water. A smart phone app is used to measure the frequencies of equal-temperament tones. Then plots of frequency…

  7. Waste glass weathering

    International Nuclear Information System (INIS)

    Bates, J.K.; Buck, E.C.

    1994-01-01

    The weathering of glass is reviewed by examining processes that affect the reaction of commercial, historical, natural, and nuclear waste glass under conditions of contact with humid air and slowly dripping water, which may lead to immersion in nearly static solution. Radionuclide release data from weathered glass under conditions that may exist in an unsaturated environment are presented and compared to release under standard leaching conditions. While the comparison between the release under weathering and leaching conditions is not exact, due to variability of reaction in humid air, evidence is presented of radionuclide release under a variety of conditions. These results suggest that both the amount and form of radionuclide release can be affected by the weathering of glass

  8. Super ionic conductive glass

    Science.gov (United States)

    Susman, S.; Volin, K.J.

    Described is an ionically conducting glass for use as a solid electrolyte in a power or secondary cell containing an alkali metal-containing anode and a cathode separated by an alkali metal ion conducting glass having an ionic transference number of unity and the general formula: A/sub 1 + x/D/sub 2-x/3/Si/sub x/P/sub 3 - x/O/sub 12 - 2x/3/, wherein A is a network modifier for the glass and is an alkali metal of the anode, D is an intermediate for the glass and is selected from the class consisting of Zr, Ti, Ge, Al, Sb, Be, and Zn and X is in the range of from 2.25 to 3.0. Of the alkali metals, Na and Li are preferred and of the intermediate, Zr, Ti and Ge are preferred.

  9. Phosphate glasses, containing nitrogen

    International Nuclear Information System (INIS)

    Lisitsyna, E.A.; Khalilev, V.D.; Koryavin, A.A.; Goncharova, L.N.

    1987-01-01

    Possibilities of nitrogen-containing glass synthesis by the introduction into the charge of ammonium salts, as well as aluminium nitride, are studied. Zinc alumoyttrium phosphate glass (mol. %) Zn(PO 3 ) 2 - 4O, Al(PO 3 ) 3 - 3O, Y(PO 3 ) 3 -3O is suggested as a matrix. It is shown that the effect of amide and imide groups on the properties of the glass is less noticeable than the effect of nitride groups. Direct introduction of nitride constituent was realized using AlN, but aluminium introduction was taken into account so that the oxide was subtracted. The attempt to introduce more than 2.5 mass % of nitrogen into initial matrix by aluminium nitride has failed due to repeated restoration of glass with amorphous phosphorus isolation

  10. Material interactions relating to long-term geologic disposal of nuclear waste glass

    International Nuclear Information System (INIS)

    Bibler, N.E.; Jantzen, C.M.

    1986-01-01

    This review paper systematizes the additional interactions that materials in a geologic repository will impose on the borosilicate glass waste form-groundwater interactions. These materials are the steel canister that holds the glass, the steel overpack over the canister, backfill materials that may be used, and last, the repository host rock. The repository geologies reviewed are tuff, salt, basalt, and granite. The interactions emphasized are those appropriate to conditions expected after repository closure, e.g., oxic vs anoxic conditions. Whenever possible, the effect of radiation from the waste form on the interaction(s) is examined. The interactions are evaluated based on their effect on the release and speciation of various elements including radionuclides from the glass. Repository relevant interactions testing that requires further study before long-term predictions can be made are noted. 62 refs

  11. Assessment of the alteration of R7T7-type glass according to storage conditions

    International Nuclear Information System (INIS)

    Jollivet, P.; Minet, Y.; Nicolas, M.; Vernaz, E.

    1997-01-01

    The PREDIVER code was used to estimate the influence of the major parameters of a geological repository site on the alteration oh a high-level vitrified waste package. The kinetic law of glass alteration is based on a deviation concerning saturation with respect to silicic acid. Glass alteration is governed by the coefficient of silicon diffusion in the interstitial water of the gel layer and by the leachate renewal rate (i.e. the flow rate in the repository) if it is of very low magnitude. The effects of other parameters are much less significant. When applied to the alteration of natural basalts, the PREDIVER code overestimates glass alteration, indicating that transport limitations slow down the alteration processes over a long time period. (authors)

  12. Baseline LAW Glass Formulation Testing

    International Nuclear Information System (INIS)

    Kruger, Albert A.; Mooers, Cavin; Bazemore, Gina; Pegg, Ian L.; Hight, Kenneth; Lai, Shan Tao; Buechele, Andrew; Rielley, Elizabeth; Gan, Hao; Muller, Isabelle S.; Cecil, Richard

    2013-01-01

    The major objective of the baseline glass formulation work was to develop and select glass formulations that are compliant with contractual and processing requirements for each of the LAW waste streams. Other objectives of the work included preparation and characterization of glasses with respect to the properties of interest, optimization of sulfate loading in the glasses, evaluation of ability to achieve waste loading limits, testing to demonstrate compatibility of glass melts with melter materials of construction, development of glass formulations to support ILAW qualification activities, and identification of glass formulation issues with respect to contract specifications and processing requirements

  13. Heck and Heckle Seamounts, northeast Pacific Ocean: High extrusion rates of primitive and highly depleted mid-ocean ridge basalt on off-ridge seamounts

    Science.gov (United States)

    Leybourne, M. I.; van Wagoner, N. A.

    1991-09-01

    We analyzed, petrographically and chemically, basalt from eight dredge hauls from the Heck and Heckle seamounts, northeast Pacific Ocean. Major elements were determined for mineral, glass, and whole rock samples, and trace and rare earth elements were determined for glass and whole rock samples. The dredge hauls included hyaloclastites and fragments from sheet flows and pillows. The clinkery fragments are interpreted to be deformed sheet flow tops, characteristic of high effusion rates. The hyaloclastites recovered are reworked deposits, as indicated by the wide compositional range of the glass shards, abundance of clay and calcite matrix, and bedding. Most rocks are aphyric, but the analyzed plagioclase and olivine phenocrysts and microcrysts are equilibrium compositions and show minor compositional zonation (up to 7.5% An, chains have a limited range of incompatible element ratios, whereas the adjacent West Valley Segment of the Juan de Fuca Ridge is highly heterogeneous. In contrast, lavas from the East Pacific near-ridge seamounts exhibit a wider range of incompatible element ratios than do the adjacent East Pacific Rise basalts. On the West Valley Segment, magma supply is less robust associated with lower spreading rates compared to the East Pacific Rise at 10°N. In contrast, at fast spreading centers robust melting produces a mixed mantle signature in axial lavas, while suppressed melting at the seamounts reveals the heterogeneities. We suggest that at some spreading ridges, more fertile portions of the mantle are preferentially melted such that the outwelled portions of the mantle tapped by the seamounts are more depleted.

  14. Derivation of Apollo 14 High-Al Basalts at Discrete Times: Rb-Sr Isotopic Constraints

    Science.gov (United States)

    Hui. Hejiu; Neal, Clive, R.; Shih, Chi-Yu; Nyquist, Laurence E.

    2012-01-01

    Pristine Apollo 14 (A-14) high-Al basalts represent the oldest volcanic deposits returned from the Moon [1,2] and are relatively enriched in Al2O3 (>11 wt%) compared to other mare basalts (7-11 wt%). Literature Rb-Sr isotopic data suggest there are at least three different eruption episodes for the A-14 high-Al basalts spanning the age range approx.4.3 Ga to approx.3.95 Ga [1,3]. Therefore, the high-Al basalts may record lunar mantle evolution between the formation of lunar crust (approx.4.4 Ga) and the main basin-filling mare volcanism (groups [5,6], and then regrouped into three with a possible fourth comprising 14072 based on the whole-rock incompatible trace element (ITE) ratios and Rb-Sr radiometric ages [7]. However, Rb-Sr ages of these basalts from different laboratories may not be consistent with each other because of the use of different 87Rb decay constants [8] and different isochron derivation methods over the last four decades. This study involved a literature search for Rb-Sr isotopic data previously reported for the high-Al basalts. With the re-calculated Rb-Sr radiometric ages, eruption episodes of A-14 high-Al basalts were determined, and their petrogenesis was investigated in light of the "new" Rb-Sr isotopic data and published trace element abundances of these basalts.

  15. Conceptual model for regional radionuclide transport from a basalt repository site. Final draft, technical memorandum

    Energy Technology Data Exchange (ETDEWEB)

    Walton, W.C.; Voorhees, M.L.; Prickett, T.A.

    1980-05-23

    This technical memorandum was prepared to: (1) describe a typical basalt radionuclide repository site, (2) describe geologic and hydrologic processes associated with regional radionuclide transport in basalts, (3) define the parameters required to model regional radionuclide transport from a basalt repository site, and (4) develop a ''conceptual model'' of radionuclide transport from a basalt repository site. In a general hydrological sense, basalts may be described as layered sequences of aquifers and aquitards. The Columbia River Basalt, centered near the semi-arid Pasco Basin, is considered by many to be typical basalt repository host rock. Detailed description of the flow system including flow velocities with high-low hydraulic conductivity sequences are not possible with existing data. However, according to theory, waste-transport routes are ultimately towards the Columbia River and the lengths of flow paths from the repository to the biosphere may be relatively short. There are many physical, chemical, thermal, and nuclear processes with associated parameters that together determine the possible pattern of radionuclide migration in basalts and surrounding formations. Brief process descriptions and associated parameter lists are provided. Emphasis has been placed on the use of the distribution coefficient in simulating ion exchange. The use of the distribution coefficient approach is limited because it takes into account only relatively fast mass transfer processes. In general, knowledge of hydrogeochemical processes is primitive.

  16. Prokaryotic diversity, distribution, and insights into their role in biogeochemical cycling in marine basalts

    Energy Technology Data Exchange (ETDEWEB)

    Mason, Olivia U.; Di Meo-Savoie, Carol A.; Van Nostrand, Joy D.; Zhou, Jizhong; Fisk, Martin R.; Giovannoni, Stephen J.

    2008-09-30

    We used molecular techniques to analyze basalts of varying ages that were collected from the East Pacific Rise, 9 oN, from the rift axis of the Juan de Fuca Ridge, and from neighboring seamounts. Cluster analysis of 16S rDNA Terminal Restriction Fragment Polymorphism data revealed that basalt endoliths are distinct from seawater and that communities clustered, to some degree, based on the age of the host rock. This age-based clustering suggests that alteration processes may affect community structure. Cloning and sequencing of bacterial and archaeal 16S rRNA genes revealed twelve different phyla and sub-phyla associated with basalts. These include the Gemmatimonadetes, Nitrospirae, the candidate phylum SBR1093 in the c, andin the Archaea Marine Benthic Group B, none of which have been previously reported in basalts. We delineated novel ocean crust clades in the gamma-Proteobacteria, Planctomycetes, and Actinobacteria that are composed entirely of basalt associated microflora, and may represent basalt ecotypes. Finally, microarray analysis of functional genes in basalt revealed that genes coding for previously unreported processes such as carbon fixation, methane-oxidation, methanogenesis, and nitrogen fixation are present, suggesting that basalts harbor previously unrecognized metabolic diversity. These novel processes could exert a profound influence on ocean chemistry.

  17. High-Ti type N-MORB parentage of basalts from the south Andaman ...

    Indian Academy of Sciences (India)

    R. Narasimhan (Krishtel eMaging) 1461 1996 Oct 15 13:05:22

    by Irvine and Baragar (1971) or MacDonald and. Katsura (1964) were not included here because of the considerable uncertainty that exists in such a classification scheme (see Sheth et al 2002 for more explanation). The Andaman ophiolite samples are mainly basalts (20 samples), with some basaltic andesites.

  18. Effect of basalt, silica sand and fly ash on the mechanical properties ...

    Indian Academy of Sciences (India)

    2018-05-17

    May 17, 2018 ... For this, we first manufactured binary PCs of epoxy/basalt ... Keywords. Polymer concrete; mechanical strength; mixture design; fly ash; silica sand; basalt. 1. .... To reduce the production cost of PCs, it is necessary to minimize ...

  19. Conceptual model for regional radionuclide transport from a basalt repository site. Final draft, technical memorandum

    International Nuclear Information System (INIS)

    Walton, W.C.; Voorhees, M.L.; Prickett, T.A.

    1980-01-01

    This technical memorandum was prepared to: (1) describe a typical basalt radionuclide repository site, (2) describe geologic and hydrologic processes associated with regional radionuclide transport in basalts, (3) define the parameters required to model regional radionuclide transport from a basalt repository site, and (4) develop a ''conceptual model'' of radionuclide transport from a basalt repository site. In a general hydrological sense, basalts may be described as layered sequences of aquifers and aquitards. The Columbia River Basalt, centered near the semi-arid Pasco Basin, is considered by many to be typical basalt repository host rock. Detailed description of the flow system including flow velocities with high-low hydraulic conductivity sequences are not possible with existing data. However, according to theory, waste-transport routes are ultimately towards the Columbia River and the lengths of flow paths from the repository to the biosphere may be relatively short. There are many physical, chemical, thermal, and nuclear processes with associated parameters that together determine the possible pattern of radionuclide migration in basalts and surrounding formations. Brief process descriptions and associated parameter lists are provided. Emphasis has been placed on the use of the distribution coefficient in simulating ion exchange. The use of the distribution coefficient approach is limited because it takes into account only relatively fast mass transfer processes. In general, knowledge of hydrogeochemical processes is primitive

  20. From mantle roots to surface eruptions: Cenozoic and Mesozoic continental basaltic magmatism

    Czech Academy of Sciences Publication Activity Database

    Kämpf, H.; Németh, K.; Puziewicz, J.; Mrlina, Jan; Geissler, W.H.

    2015-01-01

    Roč. 104, č. 8 (2015), s. 1909-1912 ISSN 1437-3254 Institutional support: RVO:67985530 Keywords : continental basaltic volcanism * BASALT 2013 conference * Cenozoic * Mesozoic Subject RIV: DC - Siesmology, Volcanology, Earth Structure Impact factor: 2.133, year: 2015

  1. Post-Columbia River Basalt Group stratigraphy and map compilation of the Columbia Plateau, Oregon

    International Nuclear Information System (INIS)

    Farooqui, S.M.; Bunker, R.C.; Thoms, R.E.; Clayton, D.C.; Bela, J.L.

    1981-01-01

    This report presents the results of reconnaissance mapping of sedimentary deposits and volcanic rocks overlying the Columbia River Basalt. The project area covers parts of the Dalles, Pendleton, Grangeville, Baker, Canyon City, and Bend. The mapping was done to provide stratigraphic data on the sedimentary deposits and volcanic rocks overlying the Columbia River Basalt Group. 160 refs., 16 figs., 1 tab

  2. Wastes based glasses and glass-ceramics

    Directory of Open Access Journals (Sweden)

    Barbieri, L.

    2001-12-01

    Full Text Available Actually, the inertization, recovery and valorisation of the wastes coming from municipal and industrial processes are the most important goals from the environmental and economical point of view. An alternative technology capable to overcome the problem of the dishomogeneity of the raw material chemical composition is the vitrification process that is able to increase the homogeneity and the constancy of the chemical composition of the system and to modulate the properties in order to address the reutilization of the waste. Moreover, the glasses obtained subjected to different controlled thermal treatments, can be transformed in semy-cristalline material (named glass-ceramics with improved properties with respect to the parent amorphous materials. In this review the tailoring, preparation and characterization of glasses and glass-ceramics obtained starting from municipal incinerator grate ash, coal and steel fly ashes and glass cullet are described.

    Realmente la inertización, recuperación y valorización de residuos que proceden de los procesos de incineración de residuos municipales y de residuos industriales son metas importantes desde el punto de vista ambiental y económico. Una tecnología alternativa capaz de superar el problema de la heterogeneidad de la composición química de los materiales de partida es el proceso de la vitrificación que es capaz de aumentar la homogeneidad y la constancia de la composición química del sistema y modular las propiedades a fin de la reutilización del residuo. En este artículo se presentan los resultados de vitrificación en que los vidrios fueron sometidos a tratamientos térmicos controlados diferentes, de manera que se transforman en materiales semicristalinos (también denominados vitrocerámicos con mejores propiedades respecto a los materiales amorfos originales. En esta revisión se muestra el diseño, preparación y caracterización de vidrios y vitrocerámicos partiendo de

  3. Magmatic evolution of the fresh basalts from the Ridge axis near Egaria Fracture Zone, Central Indian Ridge

    Digital Repository Service at National Institute of Oceanography (India)

    Mudholkar, A.V.

    was run through a computer programme of the least square and mass balance calculations for understanding the evolutionary path by differentiating minerals present in these basalts. The results indicate that the basalts under study represent a set...

  4. Correlation between compressive strength and ultrasonic pulse velocity of high strength concrete incorporating chopped basalt fibre

    Science.gov (United States)

    Shafiq, Nasir; Fadhilnuruddin, Muhd; Elshekh, Ali Elheber Ahmed; Fathi, Ahmed

    2015-07-01

    Ultrasonic pulse velocity (UPV), is considered as the most important test for non-destructive techniques that are used to evaluate the mechanical characteristics of high strength concrete (HSC). The relationship between the compressive strength of HSC containing chopped basalt fibre stands (CBSF) and UPV was investigated. The concrete specimens were prepared using a different ratio of CBSF as internal strengthening materials. The compressive strength measurements were conducted at the sample ages of 3, 7, 28, 56 and 90 days; whilst, the ultrasonic pulse velocity was measured at 28 days. The result of HSC's compressive strength with the chopped basalt fibre did not show any improvement; instead, it was decreased. The UPV of the chopped basalt fibre reinforced concrete has been found to be less than that of the control mix for each addition ratio of the basalt fibre. A relationship plot is gained between the cube compressive strength for HSC and UPV with various amounts of chopped basalt fibres.

  5. Influence of surface modified basalt fiber on strength of cinder lightweight aggregate concrete

    Science.gov (United States)

    Xiao, Liguang; Li, Jiheng; Liu, Qingshun

    2017-12-01

    In order to improve the bonding and bridging effect between volcanic slag lightweight aggregate concrete cement and basalt fiber, The basalt fiber was subjected to etching and roughening treatment by NaOH solution, and the surface of the basalt fiber was treated with a mixture of sodium silicate and micro-silica powder. The influence of modified basalt fiber on the strength of volcanic slag lightweight aggregate concrete was systematically studied. The experimental results show that the modified basalt fiber volcanic slag lightweight aggregate concrete has a flexural strength increased by 47%, the compressive strength is improved by 16% and the toughness is increased by 27% compared with that of the non-fiber.

  6. Using ESEM to analyze the microscopic property of basalt fiber reinforced asphalt concrete

    Directory of Open Access Journals (Sweden)

    Chunmei Gao

    2018-07-01

    Full Text Available The basalt fiber staggered distribution in the asphalt concrete matrix and the bonding situation between asphalt are analyzed by images collected using field emission environmental scanning electron microscope (ESEM test equipment. The results show that bonding of the fiber and the asphalt binder is very good and there is a strong binding force of chemical bonding connections between the two; the lipophilicity of basalt fiber is very good, the wrapped cover ability of asphalt for fiber is very strong; basalt fiber forms the local space network structure in the asphalt concrete matrix, effectively overcome the relative slip between the particles, connect the damaged parts into a whole; basalt fiber across internal micropores, and the internal defects in material can be remedied. At the same time, crack resistance mechanism of the fiber to internal micro cracks is qualitatively explained according to the magnitude of the stress intensity factor Kf. Keywords: Road engineering, Asphalt concrete, Basalt fiber, Microscopic analysis

  7. DWPF GLASS BEADS AND GLASS FRIT TRANSPORT DEMONSTRATION

    Energy Technology Data Exchange (ETDEWEB)

    Adamson, D; Bradley Pickenheim, B

    2008-11-24

    DWPF is considering replacing irregularly shaped glass frit with spherical glass beads in the Slurry Mix Evaporator (SME) process to decrease the yield stress of the melter feed (a non-Newtonian Bingham Plastic). Pilot-scale testing was conducted on spherical glass beads and glass frit to determine how well the glass beads would transfer when compared to the glass frit. Process Engineering Development designed and constructed the test apparatus to aid in the understanding and impacts that spherical glass beads may have on the existing DWPF Frit Transfer System. Testing was conducted to determine if the lines would plug with the glass beads and the glass frit slurry and what is required to unplug the lines. The flow loop consisted of vertical and horizontal runs of clear PVC piping, similar in geometry to the existing system. Two different batches of glass slurry were tested: a batch of 50 wt% spherical glass beads and a batch of 50 wt% glass frit in process water. No chemicals such as formic acid was used in slurry, only water and glass formers. The glass beads used for this testing were commercially available borosilicate glass of mesh size -100+200. The glass frit was Frit 418 obtained from DWPF and is nominally -45+200 mesh. The spherical glass beads did not have a negative impact on the frit transfer system. The transferring of the spherical glass beads was much easier than the glass frit. It was difficult to create a plug with glass bead slurry in the pilot transfer system. When a small plug occurred from setting overnight with the spherical glass beads, the plug was easy to displace using only the pump. In the case of creating a man made plug in a vertical line, by filling the line with spherical glass beads and allowing the slurry to settle for days, the plug was easy to remove by using flush water. The glass frit proved to be much more difficult to transfer when compared to the spherical glass beads. The glass frit impacted the transfer system to the point

  8. Optimized Synthesis of Foam Glass from Recycled CRT Panel Glass

    DEFF Research Database (Denmark)

    Petersen, Rasmus Rosenlund; König, Jakob; Yue, Yuanzheng

    Most of the panel glass from cathode ray tubes (CRTs) is landfilled today. Instead of landfilling, the panel glass can be turned into new environment-friendly foam glass. Low density foam glass is an effective heat insulating material and can be produced just by using recycle glass and foaming...... additives. In this work we recycle the CRT panel glass to synthesize the foam glass as a crucial component of building and insulating materials. The synthesis conditions such as foaming temperature, duration, glass particle size, type and concentrations of foaming agents, and so on are optimized...... by performing systematic experiments. In particular, the concentration of foaming agents is an important parameter that influences the size of bubbles and the distribution of bubbles throughout the sample. The foam glasses are characterised regarding density and open/closed porosity. Differential scanning...

  9. DWPF GLASS BEADS AND GLASS FRIT TRANSPORT DEMONSTRATION

    International Nuclear Information System (INIS)

    Adamson, D.; Pickenheim, Bradley

    2008-01-01

    DWPF is considering replacing irregularly shaped glass frit with spherical glass beads in the Slurry Mix Evaporator (SME) process to decrease the yield stress of the melter feed (a non-Newtonian Bingham Plastic). Pilot-scale testing was conducted on spherical glass beads and glass frit to determine how well the glass beads would transfer when compared to the glass frit. Process Engineering Development designed and constructed the test apparatus to aid in the understanding and impacts that spherical glass beads may have on the existing DWPF Frit Transfer System. Testing was conducted to determine if the lines would plug with the glass beads and the glass frit slurry and what is required to unplug the lines. The flow loop consisted of vertical and horizontal runs of clear PVC piping, similar in geometry to the existing system. Two different batches of glass slurry were tested: a batch of 50 wt% spherical glass beads and a batch of 50 wt% glass frit in process water. No chemicals such as formic acid was used in slurry, only water and glass formers. The glass beads used for this testing were commercially available borosilicate glass of mesh size -100+200. The glass frit was Frit 418 obtained from DWPF and is nominally -45+200 mesh. The spherical glass beads did not have a negative impact on the frit transfer system. The transferring of the spherical glass beads was much easier than the glass frit. It was difficult to create a plug with glass bead slurry in the pilot transfer system. When a small plug occurred from setting overnight with the spherical glass beads, the plug was easy to displace using only the pump. In the case of creating a man made plug in a vertical line, by filling the line with spherical glass beads and allowing the slurry to settle for days, the plug was easy to remove by using flush water. The glass frit proved to be much more difficult to transfer when compared to the spherical glass beads. The glass frit impacted the transfer system to the point

  10. Short-circuiting magma differentiation from basalt straight to rhyolite?

    Science.gov (United States)

    Ruprecht, P.; Winslow, H.

    2017-12-01

    Silicic magmas are the product of varying degrees of crystal fractionation and crustal assimilation/melting. Both processes lead to differentiation that is step-wise rather than continuous for example during melt separation from a crystal mush (Dufek and Bachmann, 2010). However, differentiation is rarely efficient enough to evolve directly from a basaltic to a rhyolitic magma. At Volcán Puyehue-Cordón Caulle, Chile, the magma series is dominated by crystal fractionation where mixing trends between primitive and felsic end members in the bulk rock compositions are almost absent (e.g. P, FeO, TiO2 vs. SiO2). How effective fraction is in this magmatic system is not well-known. The 2011-12 eruption at Cordón Caulle provides new constraints that rhyolitic melts may be derived directly from a basaltic mush. Minor, but ubiquitous mafic, crystal-rich enclaves co-erupted with the predominantly rhyolitic near-aphyric magma. These enclaves are among the most primitive compositions erupted at Puyehue-Cordón Caulle and geochemically resemble closely basaltic magmas that are >10 ka old (Singer et al. 2008) and that have been identified as a parental tholeiitic mantle-derived magma (Schmidt and Jagoutz, 2017) for the Southern Andean Volcanic Zone. The vesiculated nature, the presence of a microlite-rich groundmass, and a lack of a Eu anomaly in these encalves suggest that they represent recharge magma/mush rather than sub-solidus cumulates and therefore have potentially a direct petrogenetic link to the erupted rhyolites. Our results indicate that under some conditions crystal fractionation can be very effective and the presence of rhyolitic magmas does not require an extensive polybaric plumbing system. Instead, primitive mantle-derived magmas source directly evolved magmas. In the case, of the magma system beneath Puyehue-Cordón Caulle, which had three historic rhyolitic eruptions (1921-22, 1960, 2011-12) these results raise the question whether rhyolite magma extraction

  11. Constraining Path-Dependent Processes During Basalt-CO2 Interactions with Observations From Flow-Through and Batch Experiments

    Science.gov (United States)

    Thomas, D.; Garing, C.; Zahasky, C.; Harrison, A. L.; Bird, D. K.; Benson, S. M.; Oelkers, E. H.; Maher, K.

    2017-12-01

    Predicting the timing and magnitude of CO2 storage in basaltic rocks relies partly on quantifying the dependence of reactivity on flow path and mineral distribution. Flow-through experiments that use intact cores are advantageous because the spatial heterogeneity of pore space and reactive phases is preserved. Combining aqueous geochemical analyses and petrologic characterization with non-destructive imaging techniques (e.g. micro-computed tomography) constrains the relationship between irreversible reactions, pore connectivity and accessible surface area. Our work enhances these capabilities by dynamically imaging flow through vesicular basalts with Positron Emission Tomography (PET) scanning. PET highlights the path a fluid takes by detecting photons produced during radioactive decay of an injected radiotracer (FDG). We have performed single-phase, CO2-saturated flow-through experiments with basaltic core from Iceland at CO2 sequestration conditions (50 °C; 76-90 bar Ptot). Constant flow rate and continuous pressure measurements at the inlet and outlet of the core constrain permeability. We monitor geochemical evolution through cation and anion analysis of outlet fluid sampled periodically. Before and after reaction, we perform PET scans and characterize the core using micro-CT. The PET scans indicate a discrete, localized flow path that appears to be a micro-crack connecting vesicles, suggesting that vesicle-lining minerals are immediately accessible and important reactants. Rapid increases in aqueous cation concentration, pH and HCO3- indicate that the rock reacts nearly immediately after CO2 injection. After 24 hours the solute release decreases, which may reflect a transition to reaction with phases with slower kinetic dissolution rates (e.g. zeolites and glasses to feldspar), a decrease in available reactive surface area or precipitation. We have performed batch experiments using crushed material of the same rock to elucidate the effect of flow path

  12. Evaluation of aging and hydration in natural volcanic glass: magnetic property variations during artificial aging and hydration experiments

    Science.gov (United States)

    Bowles, J. A.; Patiman, A.

    2017-12-01

    The recorded geomagnetic field intensity is a function of magnetic mineralogy, grain size, and mineral concentration as well as material stability in nature and during laboratory experiments. Fresh, unhydrated, volcanic glasses are recognized as a nearly ideal natural material for use in paleointensity experiments because they contain the requisite single domain to pseudo-single-domain magnetic particles. Although alteration of magnetic mineralogy can be monitored during the experiments, it is unclear how mineralogy and hence magnetization might change with age as the metastable glass structure relaxes and/or the glass becomes hydrated. Bulk magnetic properties as a function of age show no clear trend, even over hundreds of millions of years. This may be due to the fact that even in fresh, unhydrated glass, there are small-scale differences in magnetic properties due to variation cooling rate or composition variations. Therefore, in order to better understand how magnetic mineralogy evolves with time and hydration, we conducted artificial aging and hydration experiments on fresh, unhydrated rhyolitic (South Deadman Creek, California, 650-yr) and basaltic (Axial Seamount, 2011) end-member glasses. Here, we present the results of artificial aging and hydration experiments. Elevated temperatures accelerate the glass relaxation process in a way that relaxation time decreases with increasing temperature. Aged samples are dry-annealed at 200, 300 and 400 °C for up to 240 days. A second set of samples are hydrated under pressure at 300°C and 450°C. In all cases, isothermal remanent magnetization (IRM) acquisition is monitored to assess changes in the coercivity spectrum and saturation IRM. Preliminary aging results show that in basaltic and rhyolitic glass there is one main peak coercivity at 150 mT and 35 mT, respectively. An increasing sIRM and decreasing peak coercivity trend is observed in basaltic glass whereas no trend is shown in the rhyolitic glass in both

  13. Micro-XANES Determination Fe Speciation in Natural Basalts at Mantle-Relevant fO2

    Science.gov (United States)

    Fischer, R.; Cottrell, E.; Lanzirotti, A.; Kelley, K. A.

    2007-12-01

    We demonstrate that the oxidation state of iron (Fe3+/ΣFe) can be determined with a precision of ±0.02 (10% relative) on natural basalt glasses at mantle-relevant fO2 using Fe K-edge X-ray absorption near edge structure (XANES) spectroscopy. This is equivalent to ±0.25 log unit resolution relative to the QFM buffer. Precise determination of the oxidation state over this narrow range (Fe3+/ΣFe=0.06-0.30) and at low fO2 (down to QFM-2) relies on appropriate standards, high spectral resolution, and highly reproducible methods for extracting the pre-edge centroid position. We equilibrated natural tholeiite powder in a CO/CO2 gas mixing furnace at 1350°C from QFM-3 to QFM+2 to create six glasses of known Fe3+/ΣFe, independently determined by Mössbauer spectroscopy. XANES spectra were collected at station X26A at NSLS, Brookhaven Natl. Lab, in fluorescence mode (9 element Ge array detector) using both Si(111) and Si(311) monochromators. Generally, the energy position of the 1s→3d (pre-edge) transition centroid is the most sensitive monitor of Fe oxidation state using XANES. For the mixture of Fe oxidation states in these glasses and the resulting coordination geometries, the pre-edge spectra are best defined by two multiple 3d crystal field transitions. The Si(311) monochromator, with higher energy resolution, substantially improved spectral resolution for the 1s→3d transition. Dwell times of 5s at 0.1eV intervals across the pre-edge region yielded spectra with the 1s→3d transition peaks clearly resolved. The pre-edge centroid position is highly sensitive to the background subtraction and peak fitting procedures. Differences in fitting models result in small but significant differences in the calculated peak area of each pre-edge multiplet, and the relative contribution of each peak to the calculated centroid. We assessed several schemes and obtained robust centroid positions by simultaneously fitting the background with a damped harmonic oscillator (DHO

  14. Interim reclamation report: Basalt Waste Isolation Project exploration shaft site

    International Nuclear Information System (INIS)

    Brandt, C.A.; Rickard, W.H. Jr.; Hefty, M.G.

    1990-02-01

    In 1968, a program was started to assess the feasibility of storing Hanford Site defense waste in deep caverns constructed in basalt. This program was expanded in 1976 to include investigations of the Hanford Site as a potential location for a mined commercial nuclear waste repository. Extensive studies of the geotechnical aspects of the site were undertaken, including preparations for drilling a large diameter Exploratory Shaft. This report describes the development of the reclamation program for the Exploratory Shaft Facility, its implementation, and preliminary estimates of its success. The goal of the reclamation program is to return sites disturbed by the repository program as nearly as practicable to their original conditions using native plant species. 43 refs., 19 figs., 9 tabs

  15. Monitoring and sampling perched ground water in a basaltic terrain

    International Nuclear Information System (INIS)

    Hubbell, J.M.

    1990-01-01

    Perched ground water zones can provide significant information on water and contaminant movement. This paper presents information about perched ground water obtained from drilling and monitoring at a hazardous and radioactive waste disposal site at the Idaho National Engineering Laboratory. Six of forty-five wells drilled at the Radioactive Waste Management Complex have detected perched water in basalts above sedimentary interbeds. This paper describes the distribution and characteristics of perched ground water. It discusses perched water below the surficial sediments in wells at the RWMC, the characteristics of chemical constituents found in perched water, the implications for contaminant transport in the unsaturated zone of water, and the lateral extent of perched water. Recommendations are made to increase the probability of detecting and sampling low yield perched water zones. 6 refs., 6 figs., 2 tabs

  16. Continental crustal formation and recycling: Evidence from oceanic basalts

    Science.gov (United States)

    Saunders, A. D.; Tarney, J.; Norry, M. J.

    1988-01-01

    Despite the wealth of geochemical data for subduction-related magma types, and the clear importance of such magmas in the creation of continental crust, there is still no concensus about the relative magnitudes of crustal creation versus crustal destruction (i.e., recycling of crust into the mantle). The role of subducted sediment in the formation of the arc magmas is now well documented; but what proportion of sediment is taken into the deeper mantle? Integrated isotopic and trace element studies of magmas erupted far from presently active subduction zones, in particular basaltic rocks erupted in the ocean basins, are providing important information about the role of crustal recycling. By identifying potential chemical tracers, it is impossible to monitor the effects of crustal recycling, and produce models predicting the mass of material recycled into the mantle throughout long periods of geological time.

  17. Geoscience parameter data base handbook: granites and basalts

    Energy Technology Data Exchange (ETDEWEB)

    1979-12-01

    The Department of Energy has the responsibility for selecting and constructing Federal repositories for radioactive waste. The Nuclear Regulatory Commission must license such repositories prior to construction. The basic requirement in the geologic disposal of radioactive waste is stated as: placement in a geologic host whereby the radioactive waste is not in mechanical, thermal or chemical equilibrium with the object of preventing physical or chemical migration of radionuclides into the biosphere or hydrosphere in hazardous concentration (USGS, 1977). The object of this report is to document the known geologic parameters of large granite and basalt occurrences in the coterminous United States, for future evaluation in the selection and licensing of radioactive waste repositories. The description of the characteristics of certain potential igneous hosts has been limited to existing data pertaining to the general geologic character, geomechanics, and hydrology of identified occurrences. A description of the geochemistry is the subject of a separate report.

  18. Geoscience parameter data base handbook: granites and basalts

    International Nuclear Information System (INIS)

    1979-12-01

    The Department of Energy has the responsibility for selecting and constructing Federal repositories for radioactive waste. The Nuclear Regulatory Commission must license such repositories prior to construction. The basic requirement in the geologic disposal of radioactive waste is stated as: placement in a geologic host whereby the radioactive waste is not in mechanical, thermal or chemical equilibrium with the object of preventing physical or chemical migration of radionuclides into the biosphere or hydrosphere in hazardous concentration (USGS, 1977). The object of this report is to document the known geologic parameters of large granite and basalt occurrences in the coterminous United States, for future evaluation in the selection and licensing of radioactive waste repositories. The description of the characteristics of certain potential igneous hosts has been limited to existing data pertaining to the general geologic character, geomechanics, and hydrology of identified occurrences. A description of the geochemistry is the subject of a separate report

  19. Nuclear waste repository in basalt: a design description

    International Nuclear Information System (INIS)

    Ritchie, J.S.; Schmidt, B.

    1982-01-01

    The conceptual design of a nuclear waste repository in basalt is described. Nuclear waste packages are placed in holes drilled into the floor of tunnels at a depth of 3700 ft. About 100 miles of tunnels are required to receive 35,000 packages. Five shafts bring waste packages, ventilation air, excavated rock, personnel, material, and services to and from the subsurface. The most important surface facility is the waste handling building, located over the waste handling shaft, where waste is received and packaged for storage. Two independent ventilation systems are provided to avoid potential contamination of spaces that do not contain nuclear waste. Because of the high temperatures at depth, an elaborate air chilling system is provided. Because the waste packages deliver a considerable amount of heat energy to the rock mass, particular attention is paid to heat transfer and thermal stress studies. 3 references, 31 figures, 3 tables

  20. Basalt fiber reinforced porous aggregates-geopolymer based cellular material

    Science.gov (United States)

    Luo, Xin; Xu, Jin-Yu; Li, Weimin

    2015-09-01

    Basalt fiber reinforced porous aggregates-geopolymer based cellular material (BFRPGCM) was prepared. The stress-strain curve has been worked out. The ideal energy-absorbing efficiency has been analyzed and the application prospect has been explored. The results show the following: fiber reinforced cellular material has successively sized pore structures; the stress-strain curve has two stages: elastic stage and yielding plateau stage; the greatest value of the ideal energy-absorbing efficiency of BFRPGCM is 89.11%, which suggests BFRPGCM has excellent energy-absorbing property. Thus, it can be seen that BFRPGCM is easy and simple to make, has high plasticity, low density and excellent energy-absorbing features. So, BFRPGCM is a promising energy-absorbing material used especially in civil defense engineering.

  1. Nuclear waste glass corrosion mechanisms

    International Nuclear Information System (INIS)

    Jantzen, C.M.

    1987-04-01

    Dissolution of nuclear waste glass occurs by corrosion mechanisms similar to those of other solids, e.g., metallurgical and mineralogic systems. Metallurgical phenomena such as active corrosion, passivation and immunity have been observed to be a function of the glass composition and the solution pH. Hydration thermodynamics was used to quantify the role of glass composition and its effect on the solution pH during dissolution. A wide compositional range of natural, lunar, medieval, and nuclear waste glasses, as well as some glass-ceramics were investigated. The factors observed to affect dissolution in deionized water are pertinent to the dissolution of glass in natural environments such as the groundwaters anticipated to interact with nuclear waste glass in a geologic repository. The effects of imposed pH and oxidation potential (Eh) conditions existing in natural environments on glass dissolution is described in the context of Pourbaix diagrams, pH potential diagrams, for glass

  2. Mars on Earth: Analog basaltic soils and particulates from Lonar Crater, India, include Deccan soil, shocked soil, reworked lithic and glassy ejecta, and both shocked and unshocked baked zones

    Science.gov (United States)

    Wright, S. P.

    2017-12-01

    "There is no perfect analog for Mars on Earth" [first line of Hipkin et al. (2013) Icarus, 261-267]. However, fieldwork and corresponding sample analyses from laboratory instrumentation (to proxy field instruments) has resulted in the finding of unique analog materials that suggest that detailed investigations of Lonar Crater, India would be beneficial to the goals of the Mars Program. These are briefly described below as Analog Processes, Materials, and Fieldwork. Analog Processes: The geologic history of Lonar Crater emulates localities on Mars with 1.) flood basaltic volcanism with interlayer development of 2.) baked zones or "boles" and 3.) soil formation. Of six flows, the lower three are aqueously altered by groundwater to produce a range of 4.) alteration products described below. The impact event 570 ka produced a range of 5.) impactites including shocked baked zones, shocked soils, and altered basalt shocked to a range of shock pressures [Kieffer et al., 1976]. Analog Materials: 65 Ma Deccan basalt contains augite and labradorite. Baked zones are higher in hematite and other iron oxides. Soil consists of calcite and organic matter. Several basalts with secondary alteration are listed here and these mirror alteration on Mars: hematite, chlorite, serpentine, zeolite, and palagonite, with varying combinations of these with primary igneous minerals. All of these materials (#1 through 4 above) are shocked to a range of shocked pressures to produce maskelynite, flowing plagioclase glass, vesiculated plagioclase glass, and complete impact melts. Shocked soils contain schlieren calcite amidst comminuted grains of augite, labradorite, and these glasses. Shocked baked zones unsurprisingly have a petrographic texture similar to hornfels, another product of contact metamorphism. Analog Fieldwork: The ejecta consists of two layers: 8 m of lithic breccia with unshocked and fractured basalts under a 1 m suevite consisting of all ranges of shock pressure described above

  3. SRL in-situ tests in the United Kingdom: Part 2, Surface analyses of SRS waste glass buried for one and two years in limestone at Ballidon, UK

    International Nuclear Information System (INIS)

    Namboodri, C.G. Jr.; Wicks, G.G.

    1991-01-01

    A multiphase experimental program to assess and understand waste glass behavior under a wide range of conditions has been in progress at the Savannah River Laboratory (SRL) for over a decade. An important part of this experimental effort is to assess the effects of repository relevant conditions on performance of SRS waste glass, in both controlled laboratory tests, as well as in actual field experiments. In laboratory test, SRS waste glass, simulated and in many cases also fully radioactive, has been tested in environments of salt, basalt, shale, granite, clay and tuff. In field experiments, there are four joint international programs being conducted in four different countries, involving burial of SRS simulated waste glass in granite, limestone, clay and salt geologies. This report discusses the SRS waste glass studies in limestone at Ballidon, UK

  4. Electrical properties of phosphate glasses

    International Nuclear Information System (INIS)

    Mogus-Milankovic, A; Santic, A; Reis, S T; Day, D E

    2009-01-01

    Investigation of the electrical properties of phosphate glasses where transition metal oxide such as iron oxide is the network former and network modifier is presented. Phosphate glasses containing iron are electronically conducting glasses where the polaronic conduction is due to the electron hopping from low to high iron valence state. The identification of structural defects caused by ion/polaron migration, the analysis of dipolar states and electrical conductivity in iron phosphate glasses containing various alkali and mixed alkali ions was performed on the basis of the impedance spectroscopy (IS). The changes in electrical conductivity from as-quenched phosphate glass to fully crystallized glass (glass-ceramics) by IS are analyzed. A change in the characteristic features of IS follows the changes in glass and crystallized glass network. Using IS, the contribution of glass matrix, crystallized grains and grain boundary to the total electrical conductivity for iron phosphate glasses was analyzed. It was shown that decrease in conductivity is caused by discontinuities in the conduction pathways as a result of the disruption of crystalline network where two or more crystalline phases are formed. Also, phosphate-based glasses offer a unique range of biomaterials, as they form direct chemical bonding with hard/soft tissue. The surface charges of bioactive glasses are recognized to be the most important factors in determining biological responses. The improved bioactivity of the bioactive glasses as a result of the effects of the surface charges generated by electrical polarization is discussed.

  5. The Fe/Mn constraint on precursors of basaltic achondrites

    Science.gov (United States)

    Delaney, Jeremy S.; Boesenberg, Joseph S.

    1993-01-01

    Most achondritic meteorites have Fe/Mn ratios that are lower than those of carbonaceous chondrites and of course are lower than the solar system abundance ratio of these elements. Models of the origin of achondritic assemblages must, therefore, account for these ratios. Fe/Mn ratios are suggested to be distinctive for samples from each achondrite parent body and for the Earth and Moon, but the correspondence between the Fe/Mn systematics of achondrites and chondritic precursors is unclear. Most models of achondrite genesis involve magmatic differentiation of chondritic precursors. The Fe/Mn difference between achondrites and chondrites is particularly significant since Fe and Mn are geochemically similar elements with similar partitioning behavior in familiar magmatic systems and are generally coupled during crystal-liquid fractionation. In contrast, however, Mn is more volatile than Fe in a nebular setting. Variation of Fe/Mn ratios based on the relative volatility of these elements in the early nebula provides a constraint for models by which the basaltic achondrites (with Fe/Mn ratios approximately = 25-50) are derived from mixtures of nebular components that were enriched in volatile components such as Mn. However, such volatile enriched components have not been identified in chondrites. When the abundance in achondrites of elements of similar volatility is examined, anomalies appear. For example, Na is massively depleted in basaltic achondrites when compared to Mn. These anomalies might be explained using current models but the alternative hypothesis, that Fe/Mn ratio is controlled not by nebular volatility constraints, but by planetary differentiation should be explored.

  6. Repository site definition in basalt: Pasco Basin, Washington

    International Nuclear Information System (INIS)

    Guzowski, R.V.; Nimick, F.B.; Muller, A.B.

    1982-03-01

    Discussion of the regional setting, geology, hydrology, and geochemistry of the Pasco Basin are included in this report. Pasco basin is a structural and topographic basin of approximately 2000 mi 2 (5180 km 2 ) located within the Yakima Fold Belt Subprovince of the Columbia Plateau. The stratigraphic sequence within the basin consists of an undetermined thickness of lower Miocene and younger flood basalts with interbedded and overlying sedimentary units. This sequence rests upon a basement of probably diverse rock types that may range in age from precambrian through early Tertiary. Although a large amount of information is available on the hydrology of the unconfined aquifer system, ground-water flow within the basin is, in general, poorly understood. Recharge areas for the Mabton interbed and the Saddle Mountains Formation are the highlands surrounding the basin with the flow for these units toward Gable Butte - Gable Mountain and Lake Wallula. Gable Butte - Gable Mountain probably is a ground-water sink, although the vertical flow direction in this zone is uncertain. The amount of upward vertical leakage from the Saddle Mountains Formation into the overlying sediments or to the Columbia River is unknown. Units underlying the Mabton interbed may have a flow scheme similar to those higher units or a flow scheme dominated by interbasin flow. Upward vertical leakage either throughout the basin, dominantly to the Columbia River, or dominantly to Lake Wallula has been proposed for the discharge of the lower units. None of these proposals is verified. The lateral and vertical distribution of major and minor ions in solution, Eh and pH, and ion exchange between basalt and ground-water are not well defined for the basin. Changes in the redox potential from the level of the subsurface facility to the higher stratigraphic levels along with the numerous other factors influencing K/sub d/, result in a poor understanding of the retardation process

  7. Repository site definition in basalt: Pasco Basin, Washington

    Energy Technology Data Exchange (ETDEWEB)

    Guzowski, R.V.; Nimick, F.B.; Muller, A.B.

    1982-03-01

    Discussion of the regional setting, geology, hydrology, and geochemistry of the Pasco Basin are included in this report. Pasco basin is a structural and topographic basin of approximately 2000 mi/sup 2/ (5180 km/sup 2/) located within the Yakima Fold Belt Subprovince of the Columbia Plateau. The stratigraphic sequence within the basin consists of an undetermined thickness of lower Miocene and younger flood basalts with interbedded and overlying sedimentary units. This sequence rests upon a basement of probably diverse rock types that may range in age from precambrian through early Tertiary. Although a large amount of information is available on the hydrology of the unconfined aquifer system, ground-water flow within the basin is, in general, poorly understood. Recharge areas for the Mabton interbed and the Saddle Mountains Formation are the highlands surrounding the basin with the flow for these units toward Gable Butte - Gable Mountain and Lake Wallula. Gable Butte - Gable Mountain probably is a ground-water sink, although the vertical flow direction in this zone is uncertain. The amount of upward vertical leakage from the Saddle Mountains Formation into the overlying sediments or to the Columbia River is unknown. Units underlying the Mabton interbed may have a flow scheme similar to those higher units or a flow scheme dominated by interbasin flow. Upward vertical leakage either throughout the basin, dominantly to the Columbia River, or dominantly to Lake Wallula has been proposed for the discharge of the lower units. None of these proposals is verified. The lateral and vertical distribution of major and minor ions in solution, Eh and pH, and ion exchange between basalt and ground-water are not well defined for the basin. Changes in the redox potential from the level of the subsurface facility to the higher stratigraphic levels along with the numerous other factors influencing K/sub d/, result in a poor understanding of the retardation process.

  8. The Influence of Topographic Obstacles on Basaltic Lava Flow Morphologies

    Science.gov (United States)

    von Meerscheidt, H. C.; Brand, B. D.; deWet, A. P.; Bleacher, J. E.; Hamilton, C. W.; Samuels, R.

    2014-12-01

    Smooth pāhoehoe and jagged ´áā represent two end-members of a textural spectrum that reflects the emplacement characteristics of basaltic lava flows. However, many additional textures (e.g., rubbly and slabby pāhoehoe) reflect a range of different process due to lava flow dynamics or interaction with topography. Unfortunately the influence of topography on the distribution of textures in basaltic lava flows is not well-understood. The 18 ± 1.0 ka Twin Craters lava flow in the Zuni-Bandera field (New Mexico, USA) provides an excellent site to study the morphological changes of a lava flow that encountered topographic obstacles. The flow field is 0.2-3.8 km wide with a prominent central tube system that intersects and wraps around a 1000 m long ridge, oriented perpendicular to flow. Upstream of the ridge, the flow has low-relief inflation features extending out and around the ridge. This area includes mildly to heavily disrupted pāhoehoe with interdispersed agglutinated masses, irregularly shaped rubble and lava balls. Breakouts of ´áā and collapse features are also common. These observations suggest crustal disruption due to flow-thickening upstream from the ridge and the movement of lava out and around the obstacle. While the ridge influenced the path of the tube, which wraps around the southern end of the ridge, the series of collapse features and breakouts of ´áā along the tube system are more likely a result of changes in flux throughout the tube system because these features are found both upstream and downstream of the obstacle. This work demonstrates that topography can significantly influence the formation history and surface disruption of a flow field, and in some cases the influence of topography can be separated from the influences of changes in flux along a tube system.

  9. Sulfur degassing due to contact metamorphism during flood basalt eruptions

    Science.gov (United States)

    Yallup, Christine; Edmonds, Marie; Turchyn, Alexandra V.

    2013-11-01

    We present a study aimed at quantifying the potential for generating sulfur-rich gas emissions from the devolatilization of sediments accompanying sill emplacement during flood basalt eruptions. The potential contribution of sulfur-rich gases from sediments might augment substantially the magma-derived sulfur gases and hence impact regional and global climate. We demonstrate, from a detailed outcrop-scale study, that sulfur and total organic carbon have been devolatilized from shales immediately surrounding a 3-m thick dolerite sill on the Isle of Skye, Scotland. Localized partial melting occurred within a few centimetres of the contact in the shale, generating melt-filled cracks. Pyrite decomposed on heating within 80 cm of the contact, generating sulfur-rich gases (a mixture of H2S and SO2) and pyrrhotite. The pyrrhotite shows 32S enrichment, due to loss of 34S-enriched SO2. Further decomposition and oxidation of pyrrhotite resulted in hematite and/or magnetite within a few cm of the contact. Iron sulfates were produced during retrogressive cooling and oxidation within 20 cm of the contact. Decarbonation of the sediments due to heating is also observed, particularly along the upper contact of the sill, where increasing δ13C is consistent with loss of methane gas. The geochemical and mineralogical features observed in the shales are consistent with a short-lived intrusion, emplaced in desulfurization, as well as decarbonation, of shales adjacent to an igneous intrusion. The liberated fluids, rich in sulfur and carbon, are likely to be focused along regions of low pore fluid pressure along the margins of the sill. The sulfur gases liberated from the sediments would have augmented the sulfur dioxide (and hydrogen sulfide) yield of the eruption substantially, had they reached the surface. This enhancement of the magmatic sulfur budget has important implications for the climate impact of large flood basalt eruptions that erupt through thick, volatile-rich sedimentary

  10. Tracking Hadean processes in modern basalts with 142-Neodymium

    Science.gov (United States)

    Horan, M. F.; Carlson, R. W.; Walker, R. J.; Jackson, M.; Garçon, M.; Norman, M.

    2018-02-01

    The short-lived 146Sm→142 Nd isotope system (t1/2 = 103 Ma) provides constraints on the timing and processes of terrestrial silicate fractionation during the early Hadean. Although some Archean terranes preserve variability in 142Nd/144Nd, no anomalies have been resolved previously in young rocks. This study provides high precision 142Nd/144Nd data on a suite of ocean island basalts from Samoa and Hawaii previously shown to have variable depletions in 182W/184W that are inversely correlated with 3He/4He ratios. Improved analytical techniques and multiple replicate analyses of Nd show a variation in μ142 Nd values between -1.3 and +2.7 in the suite, relative to the JNdi standard. Given the reproducibility of the standard (±2.9 ppm, 2 SD), two Samoan samples exhibit resolved variability in their 142Nd/144Nd ratios outside of their 95% confidence intervals, suggesting minor variability in the Samoan hotspot. One sample from Samoa has a higher μ142 Nd of +2.7, outside the 95% confidence interval (±1.0 ppm) of the average of the JNdi standard. Limited, but resolved, variation in 142Nd/144Nd within the suite suggests the preservation of early Hadean silicate differentiation in the sources of at least some basalts from Samoa. Larger variations of 182W/184W and 3He/4He ratios in the same samples suggest that metal-silicate separation and mantle outgassing left a more persistent imprint on the accessible mantle compared to 142Nd/144Nd ratios which are impacted by early silicate differentiation.

  11. Theory of glass

    International Nuclear Information System (INIS)

    Rivier, N.

    1985-01-01

    The physical properties of glass are direct consequences of its non-crystalline structure. The structure is described from a topological point of view, since topology is the only geometry surviving non-crystallinity, i.e. absence of metric and trivial space group. This fact has two main consequences: the overall homogeneity of glass is a gauge symmetry, and the only extended, structurally stable constituents are odd lines (or 2π-disclinations in the elastic continuum limit). A gauge theory of glass, based on odd lines as sources of frozen-in strain, can explain those properties of glasses which are both specific to, and universal in amorphous solids: low-temperature excitations, and relaxation at high temperatures. The methods of statistical mechanics can be applied to give a minimal description of amorphous structures in statistical equilibrium. Criteria for statistical equilibrium of the structure and detailed balance are given, together with structural equations of state, which turn out to be well-known empirically among botanists and metallurgists. This review is based on lectures given in 1984 in Niteroi. It contains five parts: I - Structure, from a topological viewpoint; II - gauge invariance; III - Tunneling modes; IV - Supercooled liquid and the glass transitions; V - Statistical crystallography. (Author) [pt

  12. Sol-Gel Glasses

    Science.gov (United States)

    Mukherjee, S. P.

    1985-01-01

    Multicomponent homogeneous, ultrapure noncrystalline gels/gel derived glasses are promising batch materials for the containerless glass melting experiments in microgravity. Hence, ultrapure, homogeneous gel precursors could be used to: (1) investigate the effect of the container induced nucleation on the glass forming ability of marginally glass forming compositions; and (2) investigate the influence of gravity on the phase separation and coarsening behavior of gel derived glasses in the liquid-liquid immiscibility zone of the nonsilicate systems having a high density phase. The structure and crystallization behavior of gels in the SiO2-GeO2 as a function of gel chemistry and thermal treatment were investigated. As are the chemical principles involved in the distribution of a second network former in silica gel matrix being investigated. The procedures for synthesizing noncrystalline gels/gel-monoliths in the SiO2-GeO2, GeO2-PbO systems were developed. Preliminary investigations on the levitation and thermal treatment of germania silicate gel-monoliths in the Pressure Facility Acoustic Levitator were done.

  13. Application of the final flotation waste for obtaining the glass-ceramic materials

    Directory of Open Access Journals (Sweden)

    Cocić Mira

    2017-01-01

    Full Text Available This work describes the investigation of the final flotation waste (FFW, originating from the RTB Bor Company (Serbia, as the main component for the production of glass-ceramic materials. The glass-ceramics was synthesized by the sintering of FFW, mixtures of FFW with basalt (10%, 20%, and 40%, and mixtures of FFW with tuff (20% and 40%. The sintering was conducted at the different temperatures and with the different time duration in order to find the optimal composition and conditions for crystallization. The increase of temperature, from 1100 to 1480°C, and sintering time, from 4 to 6h resulted in a higher content of hematite crystal in the obtained glass-ceramic (up to 44%. The glass-ceramics sintered from pure FFW (1080°C/36h has good mechanical properties, such as high propagation speed (4500 m/s and hardness (10800 MPa, as well as very good thermal stability. The glass-ceramics obtained from mixtures shows weaker mechanical properties compared to that obtained from pure FFW. The mixtures of FFW with tuff have a significantly lower bulk density compared to other obtained glass-ceramics. Our results indicate that FFW can be applied as a basis for obtaining the construction materials. [Project of the Serbian Ministry of Education, Science and Technological Development, Grant no. 176010: Composition, genesis, application, and contribution to the environmental sustainability

  14. Contribution of electron microscopy to the study of alteration layers formed on the surface of glasses

    International Nuclear Information System (INIS)

    Crovisier, J.L.; Eberhart, J.P.

    1985-01-01

    In order to understand the whole process of glass corrosion in aqueous solutions, the analysis of the reagent must be completed by a study of the actual alteration layers on the glass surface. Transmission electron microscopy on ultramicrotomic thin sections turns out to be a most suitable tool to achieve this. It enables to supplement the conventional methods of surface investigation, such as A.E.S., ESCA, IRRS, SIMS. Two examples are given. The first deals with a (SiO 2 -CaO-Na 2 O-P 2 O 5 )- glass leached in a buffer solution of tris-hydromethyl-aminomethane at 40 0 C. The major feature is ion exchange within a residual porous glass, followed by the precipitation of hydroxyapatite. In the second example, a basaltic glass is altered in sea-water at 50 0 C. The glass constituents are dissolved simultaneously and the alteration layer is a precipitate of crystalline and amorphous phases which have reached their saturation level [fr

  15. Materials interactions relating to long-term geologic disposal of nuclear waste glass

    International Nuclear Information System (INIS)

    Bibler, N.E.; Jantzen, C.M.

    1987-01-01

    In the geologic disposal of nuclear waste glass, the glass will eventually interact with groundwater in the repository system. Interactions can also occur between the glass and other waste package materials that are present. These include the steel canister that holds the glass, the metal overpack over the canister, backfill materials that may be used, and the repository host rock. This review paper systematizes the additional interactions that materials in the waste package will impose on the borosilicate glass waste form-groundwater interactions. The repository geologies reviewed are tuff, salt, basalt, and granite. The interactions emphasized are those appropriate to conditions expected after repository closure, e.g. oxic vs anoxic conditions. Whenever possible, the effect of radiation from the waste form on the interactions is examined. The interactions are evaluated based on their effect on the release and speciation of various elements including radionuclides from the glass. It is noted when further tests of repository interactions are needed before long-term predictions can be made. 63 references, 1 table

  16. Ion exchange for glass strengthening

    International Nuclear Information System (INIS)

    Gy, Rene

    2008-01-01

    This paper presents a short overview of silicate glass strengthening by exchange of alkali ions in a molten salt, below the glass transition temperature (chemical tempering). The physics of alkali inter-diffusion is briefly explained and the main parameters of the process, which control the glass reinforcement, are reviewed. Methods for characterizing the obtained residual stress state and the strengthening are described, along with the simplified modelling of the stress build-up. The fragmentation of chemically tempered glass is discussed. The concept of engineered stress profile glass is presented, and finally, the effect of glass and salt compositions is overviewed

  17. Probability encoding of hydrologic parameters for basalt. Elicitation of expert opinions from a panel of three basalt waste isolation project staff hydrologists

    International Nuclear Information System (INIS)

    Runchal, A.K.; Merkhofer, M.W.; Olmsted, E.; Davis, J.D.

    1984-11-01

    The present study implemented a probability encoding method to estimate the probability distributions of selected hydrologic variables for the Cohassett basalt flow top and flow interior, and the anisotropy ratio of the interior of the Cohassett basalt flow beneath the Hanford Site. Site-speciic data for these hydrologic parameters are currently inadequate for the purpose of preliminary assessment of candidate repository performance. However, this information is required to complete preliminary performance assessment studies. Rockwell chose a probability encoding method developed by SRI International to generate credible and auditable estimates of the probability distributions of effective porosity and hydraulic conductivity anisotropy. The results indicate significant differences of opinion among the experts. This was especially true of the values of the effective porosity of the Cohassett basalt flow interior for which estimates differ by more than five orders of magnitude. The experts are in greater agreement about the values of effective porosity of the Cohassett basalt flow top; their estimates for this variable are generally within one to two orders of magnitiude of each other. For anisotropy ratio, the expert estimates are generally within two or three orders of magnitude of each other. Based on this study, the Rockwell hydrologists estimate the effective porosity of the Cohassett basalt flow top to be generally higher than do the independent experts. For the effective porosity of the Cohassett basalt flow top, the estimates of the Rockwell hydrologists indicate a smaller uncertainty than do the estimates of the independent experts. On the other hand, for the effective porosity and anisotropy ratio of the Cohassett basalt flow interior, the estimates of the Rockwell hydrologists indicate a larger uncertainty than do the estimates of the independent experts

  18. Perspectives on spin glasses

    CERN Document Server

    Contucci, Pierluigi

    2013-01-01

    Presenting and developing the theory of spin glasses as a prototype for complex systems, this book is a rigorous and up-to-date introduction to their properties. The book combines a mathematical description with a physical insight of spin glass models. Topics covered include the physical origins of those models and their treatment with replica theory; mathematical properties like correlation inequalities and their use in the thermodynamic limit theory; main exact solutions of the mean field models and their probabilistic structures; and the theory of the structural properties of the spin glass phase such as stochastic stability and the overlap identities. Finally, a detailed account is given of the recent numerical simulation results and properties, including overlap equivalence, ultrametricity and decay of correlations. The book is ideal for mathematical physicists and probabilists working in disordered systems.

  19. Waste glass melting stages

    International Nuclear Information System (INIS)

    Anderson, L.D.; Dennis, T.; Elliott, M.L.; Hrma, P.

    1994-01-01

    Three simulated nuclear waste glass feeds, consisting of dried waste and glass frit, were heat treated for 1 hour in a gradient furnace at temperatures ranging from approximately 600 degrees C to 1000 degrees C. Simulated melter feeds from the Hanford Waste Vitrification Plant (HWVP), the Defense Waste Processing Facility (DWPF), and Kernforschungszentru Karlsruhe (KfK) in Germany were used. The samples were thin sectioned and examined by optical microscopy to investigate the stages of the conversion from feed to glass. Various phenomena were seen, such as frit softening, bubble formation, foaming, bubble motion and removal, convective mixing, and homogenization. The behavior of different feeds was similar, although the degree of gas generation and melt homogenization varied. 2 refs., 8 tabs

  20. Waste glass melting stages

    International Nuclear Information System (INIS)

    Anderson, L.D.; Dennis, T.; Elliott, M.L.; Hrma, P.

    1993-04-01

    Three different simulated nuclear waste glass feeds, consisting of dried waste and glass frit, were heat treated for 1 hour in a gradient furnace at temperatures ranging from approximately 600 degrees C--1000 degrees C. Simulated melter feeds from the Hanford Waste Vitrification Plant (HWVP), the Defense Waste Processing Facility (DWPF), and Kernforschungszentrum Karlsruhe (KfK) in Germany were used. The samples were thin-sectioned and examined by optical microscopy to investigate the stages of the conversion from feed to glass. Various phenomena were seen, such as frit softening, bubble formation, foaming, bubble motion and removal, convective mixing, and homogenization. Behavior of different feeds was similar, although the degree of gas generation and melt homogenization varied

  1. Role of groundwater oxidation potential and radiolysis on waste glass performance in crystalline repository environments

    International Nuclear Information System (INIS)

    Jantzen, C.M.; Bibler, N.E.

    1986-01-01

    Laboratory experiments have shown that groundwater conditions in a granite repository will be as reducing as those in a basalt repository. Chemical analysis of the reduced groundwaters confirmed that the Fe 2+ /Fe 3+ couple controls the oxidation potential (Eh). The reducing groundwater conditions were found to decrease the time-dependent release of soluble elements (Li and B) from the waste glass. However, due to the lower solubility of multivalent elements released from the glass when the groundwaters are reducing, these elements have significantly lower concentrations in the leachates. Gamma radiolysis reduced the oxidation potential of both granitic and basaltic groundwater in the absence of both waste glass and oxygen. This occurred in tests at atmospheric pressure where H 2 could have escaped from the solution. The mechanism for this decrease in Eh is under investigation but appears related to the reactive amorphous precipitate in both groundwaters. The results of these tests suggest that radiolysis may not cause the groundwaters to become oxidizing in a crystalline repository when abundant Fe 2+ species are present

  2. Using physical properties of molten glass to estimate glass composition

    International Nuclear Information System (INIS)

    Choi, Kwan Sik; Yang, Kyoung Hwa; Park, Jong Kil

    1997-01-01

    A vitrification process is under development in KEPRI for the treatment of low-and medium-level radioactive waste. Although the project is for developing and building Vitrification Pilot Plant in Korea, one of KEPRI's concerns is the quality control of the vitrified glass. This paper discusses a methodology for the estimation of glass composition by on-line measurement of molten glass properties, which could be applied to the plant for real-time quality control of the glass product. By remotely measuring viscosity and density of the molten glass, the glass characteristics such as composition can be estimated and eventually controlled. For this purpose, using the database of glass composition vs. physical properties in isothermal three-component system of SiO 2 -Na 2 O-B 2 O 3 , a software TERNARY has been developed which determines the glass composition by using two known physical properties (e.g. density and viscosity)

  3. Application of the iron-enriched basalt waste form for immobilizing commercial transuranic waste

    International Nuclear Information System (INIS)

    Owen, D.E.

    1981-08-01

    The principal sources of commercial transuranic (TRU) waste in the United States are identified. The physical and chemical nature of the wastes from these sources are discussed. The fabrication technique and properties of iron-enriched basalt, a rock-like waste form developed for immobilizing defense TRU wastes, are discussed. The application of iron-enriched basalt to commercial TRU wastes is discussed. Review of commercial TRU wastes from mixed-oxide fuel fabrication, light water reactor fuel reprocessing, and miscellaneous medical, research, and industrial sources, indicates that iron-enriched basalt is suitable for most types of commercial TRU wastes. Noncombustible TRU wastes are dissolved in the high temperature, oxidizing iron-enriched basalt melt. Combustible TRU wastes are immobilized in iron-enriched basalt by incinerating the wastes and adding the TRU-bearing ash to the melt. Casting and controlled cooling of the melt produces a devitrified, rock-like iron-enriched basalt monolith. Recommendations are given for testing the applicability of iron-enriched basalt to commercial TRU wastes

  4. Stratigraphic imaging of sub-basalt sediments using waveform tomography of wide-angle seismic data

    Science.gov (United States)

    Sain, K.; Gao, F.; Pratt, G.; Zelt, C. A.

    2003-12-01

    The oil industry is interested in imaging the fine structures of sedimentary formations masked below basalt flows for commercial exploration of hydrocarbons. Seismic exploration of sediments hidden below high-velocity basalt cover is a difficult problem because near-vertical reflection data are contaminated with multiples, converted waves and scattering noise generated by interbeds, breccia and vesicles within the basalt. The noise becomes less prominent as the source-receiver offset increases, and the signals carrying sub-surface information stand out at the wide-angle range. The tomography of first arrival traveltime data can provide little information about the underlying low-velocity sediments. Traveltime inversion of wide-angle seismic data including both first arrivals and identifiable wide-angle reflected phases has been an important tool in the delineation of the large-scale velocity structure of sub-basalt sediments, although it lacks the small-scale velocity details. Here we apply 2-D full-waveform inversion ("waveform tomography") to wide-angle seismic data with a view to extracting the small-scale stratigraphic features of sedimentary formations. Results from both synthetic data, generated for a realistic earth model, and field dataset from the basalt covered Saurashtra peninsula, India, will be presented. This approach has potential to delineate thin sedimentary layers hidden below thick basalt cover also, and may serve as a powerful tool to image sedimentary basins, where they are covered by high-velocity materials like basalts, salts, carbonates, etc. in various parts of the world.

  5. Microseismic monitoring of columnar jointed basalt fracture activity: a trial at the Baihetan Hydropower Station, China

    Science.gov (United States)

    Chen, Bing-Rui; Li, Qing-Peng; Feng, Xia-Ting; Xiao, Ya-Xun; Feng, Guang-Liang; Hu, Lian-Xing

    2014-10-01

    Severe stress release has occurred to the surrounding rocks of the typically columnar jointed basalt after excavation at the Baihetan Hydropower Station, Jinsha River, China, where cracking, collapse, and other types of failure may take place occasionally due to relaxation fracture. In order to understand the relaxation fracture characteristics of the columnar jointed basalt in the entire excavation process at the diversion tunnel of the Baihetan Hydropower Station, real-time microseismic monitoring tests were performed. First, the applicability of a geophone and accelerometer was analyzed in the columnar jointed basalt tunnel, and the results show that the accelerometer was more applicable to the cracking monitoring of the columnar jointed basalt. Next, the waveform characteristics of the microseismic signals were analyzed, and the microseismic signals were identified as follows: rock fracture signal, drilling signal, electrical signal, heavy vehicle passing signal, and blast signal. Then, the attenuation characteristics of the microseismic signals in the columnar jointed basalt tunnel were studied, as well as the types and characteristics of the columnar jointed basalt fracture. Finally, location analysis was conducted on the strong rock fracture events, in which four or more sensors were triggered, to obtain the temporal and spatial evolution characteristics and laws of the columnar jointed basalt relaxation fracture after excavation. The test results are not only of important reference value to the excavation and support of diversion tunnel at the Baihetan Hydropower Station, but also of great referential significance and value to the conduction of similar tests.

  6. Elevation of surficial sediment/basalt contact in the Subsurface Disposal Area, Idaho National Engineering Laboratory

    International Nuclear Information System (INIS)

    Hubbell, J.M.

    1993-01-01

    The elevation of the surficial sediment/basalt contact at the Subsurface Disposal Area (SDA), within the Radioactive Waste Management Complex (RWMC) is presented to provide a data base for future remedial actions at this site. About 1,300 elevation data from published and unpublished reports, maps, and surveyors notes were compiled to generate maps and cross-sections of the surficial sediment/basalt contact. In general, an east to west trending depression exists in the south central portion of the SDA with basalt closer to land surface on the northern and southern boundaries of the SDA. The lowest elevation of the surficial sediment/basalt contact is 4,979 ft and the greatest is land surface at 5,012 ft. The median elevation of the sediment/basalt interface is 4,994 ft. The median depth to basalt in the SDA is 16 ft if land surface elevation is assumed to be 5,010 ft. The depth from land surface to the sediment/basalt interface ranges from 24 ft in the southeast corner of the SDA to less than 3 ft at the north-central boundary of the SDA

  7. Radionuclide sorption kinetics and column sorption studies with Columbia River basalts

    International Nuclear Information System (INIS)

    Barney, G.S.

    1983-09-01

    The kinetics of radionuclide sorption and desorption reactions in basalt-groundwater systems were evaluated at 60 degrees C using a batch equilibration method. It was found that many sorption reactions on surfaces of fresh (unaltered) basalt from the Umtanum and Cohassett flows are slow. Some reactions require more than 50 days to reach a steady state. Sorption of neptunium and uranium in oxidizing (air saturated) groundwater appears to be controlled by slow reduction of these elements by the basalt surfaces. The resulting lower oxidation states are more strongly sorbed. Technetium and selenium, which are anionic under oxidizing conditions, are not measurably sorbed on fresh basalt surfaces, but are slightly sorbed on the altered surfaces of flow top basalt. Under reducing conditions, where the groundwater contains dilute hydrazine, sorption is faster for neptunium, uranium, technetium, selenium, and lead. Plutonium sorption rates were not affected by the groundwater Eh. It was shown that radium was precipitated rather than sorbed under the conditions of these experiments. Umtanum flow top material sorbed radionuclides much faster than fresh basalt surfaces due to its greater surface area and cation exchange capacity. Desorption rates for plutonium, uranium, neptunium, technetium, and selenium were generally much less than sorption rates (especially for reducing conditions). These radionuclides are irreversibly sorbed on the basalts. 25 refs., 20 figs., 19 tabs

  8. Bonding Properties of Basalt Fiber and Strength Reduction According to Fiber Orientation

    Directory of Open Access Journals (Sweden)

    Jeong-Il Choi

    2015-09-01

    Full Text Available The basalt fiber is a promising reinforcing fiber because it has a relatively higher tensile strength and a density similar to that of a concrete matrix as well as no corrosion possibility. This study investigated experimentally the bonding properties of basalt fiber with cementitious material as well as the effect of fiber orientation on the tensile strength of basalt fiber for evaluating basalt fiber’s suitability as a reinforcing fiber. Single fiber pullout tests were performed and then the tensile strength of fiber was measured according to fiber orientation. The test results showed that basalt fiber has a strong chemical bond with the cementitious matrix, 1.88 times higher than that of polyvinyl alcohol fibers with it. However, other properties of basalt fiber such as slip-hardening coefficient and strength reduction coefficient were worse than PVA and polyethylene fibers in terms of fiber bridging capacity. Theoretical fiber-bridging curves showed that the basalt fiber reinforcing system has a higher cracking strength than the PVA fiber reinforcing system, but the reinforcing system showed softening behavior after cracking.

  9. Bonding Properties of Basalt Fiber and Strength Reduction According to Fiber Orientation.

    Science.gov (United States)

    Choi, Jeong-Il; Lee, Bang Yeon

    2015-09-30

    The basalt fiber is a promising reinforcing fiber because it has a relatively higher tensile strength and a density similar to that of a concrete matrix as well as no corrosion possibility. This study investigated experimentally the bonding properties of basalt fiber with cementitious material as well as the effect of fiber orientation on the tensile strength of basalt fiber for evaluating basalt fiber's suitability as a reinforcing fiber. Single fiber pullout tests were performed and then the tensile strength of fiber was measured according to fiber orientation. The test results showed that basalt fiber has a strong chemical bond with the cementitious matrix, 1.88 times higher than that of polyvinyl alcohol fibers with it. However, other properties of basalt fiber such as slip-hardening coefficient and strength reduction coefficient were worse than PVA and polyethylene fibers in terms of fiber bridging capacity. Theoretical fiber-bridging curves showed that the basalt fiber reinforcing system has a higher cracking strength than the PVA fiber reinforcing system, but the reinforcing system showed softening behavior after cracking.

  10. Superductile bulk metallic glass

    International Nuclear Information System (INIS)

    Yao, K.F.; Ruan, F.; Yang, Y.Q.; Chen, N.

    2006-01-01

    Usually, monolithic bulk metallic glasses undergo inhomogeneous plastic deformation and exhibit poor ductility (<2%) at room temperature. We report a newly developed Pd-Si binary bulk metallic glass, which exhibits a uniform plastic deformation and a large plastic engineering strain of 82% and a plastic true strain of 170%, together with initial strain hardening, slight strain softening and final strain hardening characteristics. The uniform shear deformation and the ultrahigh plasticity are mainly attributed to strain hardening, which results from the nanoscale inhomogeneity due to liquid phase separation. The formed nanoscale inhomogeneity will hinder, deflect, and bifurcate the propagation of shear bands

  11. Uranium distribution and age pattern of some deep-sea basalts from the Entrecasteaux area, South-western Pacific: a fission-track analysis

    International Nuclear Information System (INIS)

    Selo, M.; Storzer, D.

    1981-01-01

    The eight glass samples analysed by means of the fission-track method were recovered from deep-sea dredge sites 314D, 316D, 323D and 325D in the SW Pacific. The bulk uranium contents of the fresh remnants of unweathered glasses range between 51 ppb and 108 ppb. One glass from site 316D with a U-content of 227 ppb might be part of a dike intrusion. The basalts from all four sites are altered to various extents. Ambient temperatures prevailing during these alteration processes are estimated to have been 1 to 5 0 C at sites 314D and 325D; about 10 0 C at site 323D; but 40 to 110 0 C at site 316D. The measured fission-track ages of sites 314D, 323D and 325D scatter between 34 Ma in the north and 20 Ma in the south. At site 316D, they are exceedingly low, being from 4.4 to =< 0.7 Ma. All these ages are thermally lowered and required correction. The ages corrected for thermally induced partial track-loss are given. From these ages and the site positions, a spreading rate is deduced for the northern part of the North Loyalty Plateau, which comes close to values estimated for slow-spreading ridges. (author)

  12. Basalt generation at the Apollo 12 site. Part 2: Source heterogeneity, multiple melts, and crustal contamination

    Science.gov (United States)

    Neal, Clive R.; Hacker, Matthew D.; Snyder, Gregory A.; Taylor, Lawrence A.; Liu, Yun-Gang; Schmitt, Roman A.

    1994-01-01

    The petrogenesis of Apollo 12 mare basalts has been examined with emphasis on trace-element ratios and abundances. Vitrophyric basalts were used as parental compositions for the modeling, and proportions of fractionating phases were determined using the MAGFOX prograqm of Longhi (1991). Crystal fractionation processes within crustal and sub-crustal magma chambers are evaluated as a function of pressure. Knowledge of the fractionating phases allows trace-element variations to be considered as either source related or as a product of post-magma-generation processes. For the ilmenite and olivine basalts, trace-element variations are inherited from the source, but the pigeonite basalt data have been interpreted with open-system evolution processes through crustal assimilation. Three groups of basalts have been examined: (1) Pigeonite basalts-produced by the assimilation of lunar crustal material by a parental melt (up to 3% assimilation and 10% crystal fractionation, with an 'r' value of 0.3). (2) Ilmenite basalts-produced by variable degrees of partial melting (4-8%) of a source of olivine, pigeonite, augite, and plagioclase, brought together by overturn of the Lunar Magma Ocean (LMO) cumulate pile. After generation, which did not exhaust any of the minerals in the source, these melts experienced closed-system crystal fractionation/accumulation. (3) Olivine basalts-produced by variable degrees of partial melting (5-10%) of a source of olivine, pigeonite, and augite. After generation, again without exhausting any of the minerals in the source, these melts evolved through crystal accumulation. The evolved liquid counterparts of these cumulates have not been sampled. The source compositions for the ilmenite and olivine basalts were calculated by assuming that the vitrophyric compositions were primary and the magmas were produced by non-modal batch melting. Although the magnitude is unclear, evaluation of these source regions indicates that both be composed of early- and

  13. The Fe-Rich Clay Microsystems in Basalt-Komatiite Lavas: Importance of Fe-Smectites for Pre-Biotic Molecule Catalysis During the Hadean Eon

    Science.gov (United States)

    Meunier, Alain; Petit, Sabine; Cockell, Charles S.; El Albani, Abderrazzak; Beaufort, Daniel

    2010-06-01

    During the Hadean to early Archean period (4.5-3.5 Ga), the surface of the Earth’s crust was predominantly composed of basalt and komatiite lavas. The conditions imposed by the chemical composition of these rocks favoured the crystallization of Fe-Mg clays rather than that of Al-rich ones (montmorillonite). Fe-Mg clays were formed inside chemical microsystems through sea weathering or hydrothermal alteration, and for the most part, through post-magmatic processes. Indeed, at the end of the cooling stage, Fe-Mg clays precipitated directly from the residual liquid which concentrated in the voids remaining in the crystal framework of the mafic-ultramafic lavas. Nontronite-celadonite and chlorite-saponite covered all the solid surfaces (crystals, glass) and are associated with tiny pyroxene and apatite crystals forming the so-called “mesostasis”. The mesostasis was scattered in the lava body as micro-settings tens of micrometres wide. Thus, every square metre of basalt or komatiite rocks was punctuated by myriads of clay-rich patches, each of them potentially behaving as a single chemical reactor which could concentrate the organics diluted in the ocean water. Considering the high catalytic potentiality of clays, and particularly those of the Fe-rich ones (electron exchangers), it is probable that large parts of the surface of the young Earth participated in the synthesis of prebiotic molecules during the Hadean to early Archean period through innumerable clay-rich micro-settings in the massive parts and the altered surfaces of komatiite and basaltic lavas. This leads us to suggest that Fe,Mg-clays should be preferred to Al-rich ones (montmorillonite) to conduct experiments for the synthesis and the polymerisation of prebiotic molecules.

  14. The compatibility of basalt and MgO with liquid sodium

    International Nuclear Information System (INIS)

    Jung, J.; Runge, H.

    1984-01-01

    The interaction of commercially available basalt and MgO-ceramics with liquid sodium has been investigated up to 900 0 C. The two basalt qualities even reacted with sodium at low temperatures and short exposure times. Some inserted MgO-ceramics exhibited the expected good sodium compatibility even at 900 0 C for 100 hours. The reaction mechanisms, the volume changes and the mass balance are discussed. In the thermal shock experiments, the basaltic materials were totally disintegrated while the MgO-qualities remained compact. (author)

  15. Chemical differences between small subsamples of Apollo 15 olivine-normative basalts

    Science.gov (United States)

    Shervais, J. W.; Vetter, S. K.; Lindstrom, M. M.

    1990-01-01

    Results are presented on the chemical and petrological characterization of nine samples of an Apollo 15 mare basalt suite. The results show that all nine samples are low-silica olivine normative basalts (ONBs) similar to those described earlier for low-silica ONBs from Apollo 15 site. The samples were found to vary in texture and grain size, from fine-grained intergranular or subophitic basalts to coarse-grained granular 'microgabbros'. Several displayed macroscopic heterogeneity. Variation diagrams show that the overall trend of the data is consistent with the fractionation of olivine (plus minor Cr-spinel) from a high-MgO parent magma.

  16. Experimental Study on Unconfined Compressive Strength of Basalt Fiber Reinforced Clay Soil

    OpenAIRE

    Gao, Lei; Hu, Guohui; Xu, Nan; Fu, Junyi; Xiang, Chao; Yang, Chen

    2015-01-01

    In order to study the mechanism and effect of basalt fiber reinforced clay soil, a series of unconfined compressive strength tests conducted on clay soil reinforced with basalt fiber have been performed under the condition of optimum water content and maximum dry density. Both the content and length of basalt fiber are considered in this paper. When the effect of content is studied, the 12 mm long fibers are dispersed into clay soil at different contents of 0.05%, 0.1%, 0.15%, 0.20%, 0.25%, 0...

  17. Comparison of mechanical and tribotechnical properties of UHMWPE reinforced with basalt fibers and particles

    Science.gov (United States)

    Panin, S. V.; Kornienko, L. A.; Alexenko, V. O.; Qitao, Huang; Ivanova, L. R.

    2016-11-01

    Mechanical and tribotechnical properties of UHMWPE composites reinforced with basalt fibers and particles under dry sliding friction and abrasion were investigated. It is shown that adding of the basalt particles provides higher wear resistance under the dry sliding friction while at abrasion filling by the basalt fibers is more efficient since the wear resistance of the reinforced UHMWPE composites is by 3.7 times higher in contrast with the neat polymer. Wear mechanisms of the polymeric UHMWPE composites under various types of wear are discussed.

  18. Aging in a Structural Glass

    OpenAIRE

    Kob, Walter; Barrat, Jean-Louis

    1998-01-01

    We discuss the relaxation dynamics of a simple structural glass which has been quenched below its glass transition temperature. We demonstrate that time correlation functions show strong aging effects and investigate in what way the fluctuation dissipation theorem is violated.

  19. Foam Glass for Construction Materials

    DEFF Research Database (Denmark)

    Petersen, Rasmus Rosenlund

    2016-01-01

    Foaming is commonly achieved by adding foaming agents such as metal oxides or metal carbonates to glass powder. At elevated temperature, the glass melt becomes viscous and the foaming agents decompose or react to form gas, causing a foamy glass melt. Subsequent cooling to room temperature, result...... in a solid foam glass. The foam glass industry employs a range of different melt precursors and foaming agents. Recycle glass is key melt precursors. Many parameters influence the foaming process and optimising the foaming conditions is very time consuming. The most challenging and attractive goal is to make...... low density foam glass for thermal insulation applications. In this thesis, it is argued that the use of metal carbonates as foaming agents is not suitable for low density foam glass. A reaction mechanism is proposed to justify this result. Furthermore, an in situ method is developed to optimise...

  20. Draft site characterization analysis of the site characterization report for the Basalt Waste Isolation Project, Hanford, Washington site. Appendices E through W

    International Nuclear Information System (INIS)

    1983-03-01

    Volume 2 contains Appendices E through W: potential for large-scale pump tests in the Grande Ronde; review of hydrochemical characterization related to flow system interpretation in Hanford basalts; limitations of packer-testing for head evaluation in Hanford basalts; hydrogeologic data integration for conceptual groundwater flow models; drilling mud effects on hydrogeologic testing; site issue analyses related to the nature at the present groundwater system at the Hanford site, Washington; structural and stratigraphic characteristics related to groundwater flow at the Hanford site, Washington; seismic hazard and some examples of hazard studies at Hanford; earthquake swarms in the Columbia Plateau; seismic ground motion at depth; failure modes for the metallic waste package component; degradation mechanisms of borosilicate glass; transport and retardation of radionuclides in the waste package; determination and interpretation of redox conditions and changes in underground high-level repositories; determination and interpretation of sorption data applied to radionuclide migration in underground repositories; solubility of radionuclide compounds presented in the BWIP site characterization report; and release rate from engineered system

  1. Study of rhyolitic glasses alteration in contact with natural brines (Bolivia). Application to the study of the long-term behaviour of the R7T7 nuclear glass

    International Nuclear Information System (INIS)

    Abdelouas, A.

    1996-01-01

    The purpose of this work is to complement an experimental program on the R7T7 nuclear waste glass alteration in brines at 190 deg C in Germany by the analysis of the structure and the chemical composition of the alteration layers, and to study the alteration of rhyolitic glasses in natural brines from Bolivia as analogue for nuclear waste glasses disposed in salt formations. Alteration experiments with the R7T7 and basaltic glasses and obsidian in MgCl 2 -CaCl 2 -saturated brine at 190 deg. C were also conducted in order to study the influence of the glass composition on the nature of the secondary phases. The experiments with the R7T7 glass in three salt brines, saturated respectively in MgCl 2 , MgCl 2 -CaCl 2 and NaCl, showed that the solubilities of most radionuclides are controlled by the secondary phases. Nd, La, and Pr are trapped in powellite, Ce in cerianite, U in coffinite, and Sr is partially immobilized in barite. These phases are stable for more than one year. There is a good similarity between the secondary phases formed experimentally on volcanic glasses and the R7T7 glass altered in MgCl 2 -CaCl 2 -saturated brine. The abundance of Mg in solution permits the formation of similar magnesian clays on the glass samples independently of the nature of the initial glasses. These results support the use of volcanic glasses alteration patterns in Mg-rich solutions to understand the long-term behavior of nuclear waste glasses and to evaluate the stability of the secondary phases. The study of the sediments of Uyuni (Bolivia) showed that the corrosion rate of the rhyolitic glass in brines at 10 deg. C is 12 to 30 time lower than those of rhyolitic glasses altered in high dilute conditions. The low alteration rate of rhyolitic glasses in brines and the formation of secondary phases such as smectite, barite and cerianite (also formed during the experimental alteration of the R7T7 glass), permit us to expect the low alteration of nuclear waste glasses at long

  2. Petrological, magnetic and chemical properties of basalt dredged from an abyssal hill in the North-east pacific

    Science.gov (United States)

    Luyendyk, B.P.; Engel, C.G.

    1969-01-01

    OVER the years, samples of basalt from the oceanic crust have been taken mainly from seamounts, fracture zones and ridge and rise crests1-6, and rarely from the vast fields of abyssal hills which cover a large part of the deep-sea floor. The basalt sampled from the deeper regions of the oceanic crust (for example, on fault scarps) is a distinct variety of tholeiitic basalt, while alkali basalt is restricted to the volcanic edifices4. Oceanic tholeiitic basalt differs from alkali basalt and continental tholeiite chiefly in having a relatively low percentage of K2O (0.2 weight per cent)4. Some authors have speculated that this type of tholeiitic basalt is the major extrusion from the upper mantle and constitutes the predominant rock type in the upper oceanic crust. ?? 1969 Nature Publishing Group.

  3. Glass ceilings of professionalisation.

    Science.gov (United States)

    Stott, Dawn L

    2016-04-01

    The term glass ceiling is a political term often used to describe an unbreakable barrier that isnot visible with the human eye, but it keeps minorities from rising up i.e. it is a barrier to minoritygroups, in the past (and sometimes still) for women, that stops them from achieving theirtrue potential.

  4. What Glass Ceiling?

    Science.gov (United States)

    Lynch, Michael; Post, Katherine

    1996-01-01

    A recent study drawing on data from the Census Bureau and the Bureau of Labor Statistics suggests that the wage gap between men and women has virtually disappeared, and that the so-called "glass ceiling" results more from age and qualifications than from explicit discrimination. (SLD)

  5. Metallic glasses: structural models

    International Nuclear Information System (INIS)

    Nassif, E.

    1984-01-01

    The aim of this work is to give a summary of the attempts made up to the present in order to discribe by structural models the atomic arrangement in metallic glasses, showing also why the structure factors and atomic distribution functions cannot be always experimentally determined with a reasonable accuracy. (M.W.O.) [pt

  6. Microchips on glass

    NARCIS (Netherlands)

    Nanver, L.; De Vreede, L.; Keulemans, M.

    2007-01-01

    Microchips on glass. What about a mobile phone that uses a single microchip to receive all the available frequency bands, plus extras such as television, gps, and Internet access? Or, in due time, see-though implants that will monitor your state of health, and equipment that will let you see through

  7. Glass as matter

    DEFF Research Database (Denmark)

    Beim, Anne

    2000-01-01

    Refraiming the Moderns - Substitute Windows and Glass. In general terms, the seminar has contributed to the growing interest in the problems concerning the restoration of Modern Movement architecture. More particularly, it has of course drawn our attention to modern windows, which are increasingly...

  8. Glass ... current issues

    International Nuclear Information System (INIS)

    Wright, A.F.; Dupuy, J.

    1985-01-01

    The objectives of the School were twofold. Firstly to inform participants of actual and developing technological applications of glassy materials in which fundamental science makes a strong contribution, and secondly to bring together scientists from the widely different backgrounds of glass science and technology to promote mutual understanding and collaboration. (orig.)

  9. Stained Glass and Flu

    Centers for Disease Control (CDC) Podcasts

    2017-02-01

    Dr. Robert Webster, an Emeritus member of the Department of Infectious Diseases at St. Jude Children's Research Hospital, discusses his cover art story on stained glass and influenza.  Created: 2/1/2017 by National Center for Emerging and Zoonotic Infectious Diseases (NCEZID).   Date Released: 2/1/2017.

  10. Glasses and nuclear waste vitrification

    International Nuclear Information System (INIS)

    Ojovan, Michael I.

    2012-01-01

    Glass is an amorphous solid material which behaves like an isotropic crystal. Atomic structure of glass lacks long-range order but possesses short and most probably medium range order. Compared to crystalline materials of the same composition glasses are metastable materials however crystallisation processes are kinetically impeded within times which typically exceed the age of universe. The physical and chemical durability of glasses combined with their high tolerance to compositional changes makes glasses irreplaceable when hazardous waste needs immobilisation for safe long-term storage, transportation and consequent disposal. Immobilisation of radioactive waste in glassy materials using vitrification has been used successfully for several decades. Nuclear waste vitrification is attractive because of its flexibility, the large number of elements which can be incorporated in the glass, its high corrosion durability and the reduced volume of the resulting wasteform. Vitrification involves melting of waste materials with glass-forming additives so that the final vitreous product incorporates the waste contaminants in its macro- and micro-structure. Hazardous waste constituents are immobilised either by direct incorporation into the glass structure or by encapsulation when the final glassy material can be in form of a glass composite material. Both borosilicate and phosphate glasses are currently used to immobilise nuclear wastes. In addition to relatively homogeneous glasses novel glass composite materials are used to immobilise problematic waste streams. (author)

  11. Multicomponent diffusion in basaltic melts at 1350 °C

    Science.gov (United States)

    Guo, Chenghuan; Zhang, Youxue

    2018-05-01

    Nine successful diffusion couple experiments were conducted in an 8-component SiO2-TiO2-Al2O3-FeO-MgO-CaO-Na2O-K2O system at ∼1350 °C and at 1 GPa, to study multicomponent diffusion in basaltic melts. At least 3 traverses were measured to obtain diffusion profiles for each experiment. Multicomponent diffusion matrix at 1350 °C was obtained by simultaneously fitting diffusion profiles of diffusion couple experiments. Furthermore, in order to better constrain the diffusion matrix and reconcile mineral dissolution data, mineral dissolution experiments in the literature and diffusion couple experiments from this study, were fit together. All features of diffusion profiles in both diffusion couple and mineral dissolution experiments were well reproduced by the diffusion matrix. Diffusion mechanism is inferred from eigenvectors of the diffusion matrix, and it shows that the diffusive exchange between network-formers SiO2 and Al2O3 is the slowest, the exchange of SiO2 with other oxide components is the second slowest with an eigenvalue that is only ∼10% larger, then the exchange between divalent oxide components and all the other oxide components is the third slowest with an eigenvalue that is twice the smallest eigenvalue, then the exchange of FeO + K2O with all the other oxide components is the fourth slowest with an eigenvalue that is 5 times the smallest eigenvalue, then the exchange of MgO with FeO + CaO is the third fastest with an eigenvalue that is 6.3 times the smallest eigenvalue, then the exchange of CaO + K2O with all the other oxide components is the second fastest with an eigenvalue that is 7.5 times the smallest eigenvalue, and the exchange of Na2O with all other oxide components is the fastest with an eigenvalue that is 31 times the smallest eigenvalue. The slowest and fastest eigenvectors are consistent with those for simpler systems in most literature. The obtained diffusion matrix was successfully applied to predict diffusion profiles during

  12. Petrogenesis of basalt-trachyte lavas from Olmoti Crater, Tanzania

    Science.gov (United States)

    Mollel, Godwin F.; Swisher, Carl C., III; McHenry, Lindsay J.; Feigenson, Mark D.; Carr, Michael J.

    2009-08-01

    Olmoti Crater is part of the Plio-Pleistocene Ngorongoro Volcanic Highland (NVH) in northern Tanzania to the south of Gregory Rift. The Gregory Rift is part of the eastern branch of the East African Rift System (EARS) that stretches some 4000 km from the Read Sea and Gulf of Aden in the north to the Zambezi River in Mozambique. Here, we (1) characterize the chemistry and mineral compositions of lavas from Olmoti Crater, (2) determine the age and duration of Olmoti volcanic activity through 40Ar/ 39Ar dating of Olmoti Crater wall lavas and (3) determine the genesis of Olmoti lavas and the relationship to other NVH and EARS volcanics and (4) their correlation with volcanics in the Olduvai and Laetoli stratigraphic sequences. Olmoti lavas collected from the lower part of the exposed crater wall section (OLS) range from basalt to trachyandesite whereas the upper part of the section (OUS) is trachytic. Petrography and major and trace element data reflect a very low degree partial melt origin for the Olmoti lavas, presumably of peridotite, followed by extensive fractionation. The 87Sr/ 86Sr data overlap whereas Nd and Pb isotope data are distinct between OLS and OUS samples. Interpretation of the isotope data suggests mixing of enriched mantle (EM I) with high-μ-like reservoirs, consistent with the model of Bell and Blenkinsop [Bell, K., Blenkinsop, J., 1987. Nd and Sr isotopic compositions of East African carbonatites: implications for mantle heterogeneity. Geology 5, 99-102] for East African carbonatite lavas. The isotope ratios are within the range of values defined by Oceanic Island Basalt (OIB) globally and moderate normalized Tb/Yb ratios (2.3-1.6) in these lavas suggest melting in the lithospheric mantle consistent with other studies in the region. 40Ar/ 39Ar incremental-heating analyses of matrix and anorthoclase separates from Olmoti OLS and OUS lavas indicate that volcanic activity was short in duration, lasting ˜200 kyr from 2.01 ± 0.03 Ma to 1.80 ± 0

  13. Apollo 12 ropy glasses revisited

    Science.gov (United States)

    Wentworth, S. J.; Mckay, D. S.; Lindstrom, D. J.; Basu, A.; Martinez, R. R.; Bogard, D. D.; Garrison, D. H.

    1994-01-01

    We analyzed ropy glasses from Apollo 12 soils 12032 and 12033 by a variety of techniques including SEM/EDX, electron microprobe analysis, INAA, and Ar-39-Ar-40 age dating. The ropy glasses have potassium rare earth elements phosphorous (KREEP)-like compositions different from those of local Apollo 12 mare soils; it is likely that the ropy glasses are of exotic origin. Mixing calculations indicate that the ropy glasses formed from a liquid enriched in KREEP and that the ropy glass liquid also contained a significant amount of mare material. The presence of solar Ar and a trace of regolith-derived glass within the ropy glasses are evidence that the ropy glasses contain a small regolith component. Anorthosite and crystalline breccia (KREEP) clasts occur in some ropy glasses. We also found within these glasses clasts of felsite (fine-grained granitic fragments) very similar in texture and composition to the larger Apollo 12 felsites, which have a Ar-39-Ar-40 degassing age of 800 +/- 15 Ma. Measurements of 39-Ar-40-Ar in 12032 ropy glass indicate that it was degassed at the same time as the large felsite although the ropy glass was not completely degassed. The ropy glasses and felsites, therefore, probably came from the same source. Most early investigators suggested that the Apollo 12 ropy glasses were part of the ejecta deposited at the Apollo 12 site from the Copernicus impact. Our new data reinforce this model. If these ropy glasses are from Copernicus, they provide new clues to the nature of the target material at the Copernicus site, a part of the Moon that has not been sampled directly.

  14. Spectroscopy of olivine basalts using FieldSpec and ASTER data: A ...

    Indian Academy of Sciences (India)

    Several volcanic episodes occurred during Early- to Late-. Cretaceous are ... produce a new scene that has the best of orig- ... developed from an olivine basalt parent magma, ..... Marcelino E, Formaggio A and Maeda E 2009 Landslide.

  15. Mineral chemistry of Carlsberg Ridge basalts at 3 degrees 35'- 3 degrees 41' N

    Digital Repository Service at National Institute of Oceanography (India)

    Iyer, S.D.; Banerjee, R.

    (approximately 91 mole %) are few and rarely zoned. The composition of plagioclase and olivine indicate low pressure equilibrium crystallization. The basalts were probably derived through fractional crystallization at shallow depths under low partial melting...

  16. Characterization and Distribution of Lunar Mare Basalt Types Using Remote Sensing Techniques. Ph.D. Thesis

    Science.gov (United States)

    Pieters, C.

    1977-01-01

    The types of basal to be found on the moon were identified using reflectance spectra from a variety of lunar mare surfaces and craters as well as geochemical interpretations of laboratory measurements of reflectance from lunar, terrestrial, and meteoritic samples. Findings indicate that major basaltic units are not represented in lunar sample collections. The existence of late stage high titanium basalts is confirmed. All maria contain lateral variations of compositionally heterogenous basalts; some are vertically inhomogenous with distinctly different subsurface composition. Some basalt types are spectrally gradational, suggesting minor variations in composition. Mineral components of unsampled units can be defined if spectra are obtained with sufficient spectral coverage (.3 to 2.5 micron m) and spatial resolution (approximating .5 km).

  17. Pb isotope evidence for contributions from different Iceland mantle components to Palaeogene East Greenland flood basalts

    DEFF Research Database (Denmark)

    Peate, David; Stecher, Ole

    2003-01-01

    We present new Pb isotope data on 21 samples of break-up-related flood basalts (56–54 Ma) from the Blosseville Kyst region of East Greenland. These samples show a considerable range in isotopic composition (206Pb/204Pb 17.6 to 19.3) that broadly correlates with compositional type. The ‘low-Ti’ type...... in the selected samples. Uncontaminated Palaeogene East Greenland flood basalts appear to have sampled the same broad range in mantle compositions seen in Recent Iceland basalts. In contrast to the peripheral lava suites from the British Isles and Southeast Greenland, where the inferred uncontaminated magmas have...... to the most radiogenic values found in recent Icelandic basalts. Furthermore, the main volume of lavas in East Greenland is displaced away from the NAEM towards this radiogenic Pb component. Thus, this ‘Iceland radiogenic Pb end-member’ component was a significant contributor to the break-up-related magmatism...

  18. Basalt microlapilli in deep sea sediments of Indian Ocean in the vicinity of Vityaz fracture zone

    Digital Repository Service at National Institute of Oceanography (India)

    Nath, B.N.; Iyer, S.D.

    Two cores recovered from the flanks of Mid-India oceanic ridge in the vicinity of Vityaz fracture zone consist of discrete pyroclastic layers at various depths. These layers are composed of coarse-grained, angular basaltic microlapilli in which...

  19. The hardness of synthetic products obtained from cooled and crystallized basaltic melts (in Romanian

    Directory of Open Access Journals (Sweden)

    Daniela Ogrean

    2001-04-01

    Full Text Available The Hardness of Synthetic Products Obtained from Cooled and Crystallized Basaltic Melts. Hardness is one of the main properties of the products obtained from cooled and crystallized basaltic melts under a controlled thermal regime. It influences the abrasion tear resistance of the resulted material. The microhardness measurements on the samples (bricks, boards, gutters, armour plates, tubes indicated Vickers hardness value between 757–926 for the materials obtained from Şanovita basalts (Timiş district and between 539–958 respectively, in case of the Racoş basalts (Braşov district. There is a certain variation of the hardness within the same sample, in various measurement points, within the theoretical limits of the hardnesses of the pyroxenes and that of the spinels.

  20. A note on sulphide-oxide mineralisation in Carlsberg Ridge basalts

    Digital Repository Service at National Institute of Oceanography (India)

    Banerjee, R.; Iyer, S.D.

    Pillow basalts from the Carlsberg Ridge at 3 degrees 35'N contain disseminated chalcopyrite, pyrite, and magnetite. The euhedral shape of the pyrite grains indicate them to be early formed and grown unobstructed while magnetite occurs as skeletal...