The Biology of Heterotrophic N2-fixing Bacteria in Marine and Estuarine Waters

DEFF Research Database (Denmark)

Bentzon-Tilia, Mikkel

Biological nitrogen (N)2 fixation is of paramount importance for marine N cycling and for life in the oceans in general. It represents the sole mechanism by which microorganisms can channel inert atmospheric N2 gas into biomass and hence it may fuel a significant fraction of primary production...... heterotrophic isolates, this thesis aims at addressing these unknowns. It was found that heterotrophic diazotrophs were present and active in environments previously not associated with N2 fixation e.g. suboxic basins of the Baltic Sea and estuarine surface waters. In these environments they contributed...... with significant amounts fixed N2, suggesting that a reevaluation of the significance of N fixation in suboxic waters and estuarine coastal waters is warranted. It was also documented that heterotrophic diazotrophs could be enriched in culture based on their ability to utilize N2 as the sole N source...

Characteristics and chemical composition of ground water in Bara basin

Energy Technology Data Exchange (ETDEWEB)

Gibla, O A.M. [Sudan University of Science and Technology, College of Graduate Studies, Khartoum (Sudan)

2007-01-15

In this study analysis was carried for forty five ground water samples from different areas within Bara basin, fifteen solid samples, three locally produced salt samples and one mixed rocks sample. The rocks were brought from the underground during hand digging of wells. The study include areas Um-Galgie, Bara, Saatah Shambool, Um-Sadoun El-Shareef, EI-Dair, EI-Murra, Taybah, Um-sadoun EI-Nazir, EI-Hodied Shareef, Um-Nabeg, Um-Gazira, Magror, Ma'afa, El-Kheiran, Dameerat Abdu, Sharshar East, Sharshar West, El-Gaa'a Um-Safari, and El-Gaa'a Um EL-Gora. Physical characteristics of ground water samples were determined including pH, electrical conductivity, turbidity, and total dissolved solids, using pH-meter, conductivity-meter, and ultra- meter. Many other analytical techniques were used. Spectrophotometric analysis was used for determination of nitrate(NO{sub 3}''-''-), nitrite (No{sub 2}''-), ammonia-nitrogen (NH{sub 3}-N), fluoride(F), sulphide(S''-''-) and sulphate(SO{sub 4}''-''-) ions. Chloride (Cl''-) and total alkalinity(OH''-,CO{sub 3}''-''-,HCO{sub 3}''-) were determined titrametrically. X-ray diffraction technique was used for determination of chemical composition of solid samples (soils,salts and rocks). X-ray fluorescence technique was used to measure the concentration of some metals in the solid samples. Radioactivity was measured using gamma-spectrometry. Atomic absorption spectrometry was used for the measurement of cations concentration in ground water samples as well as soil samples, this include macro-cations: sodium (Na), potassium (K), calcium (Ca), magnesium (Mg) and micro cations (trace): Iron (Fe), manganese (Mn), chromium (Cr), cobalt (Co), nickel (Ni), copper (Cu), zinc (Zn), cadmium (Cd), silver (Ag), lead (Pb) and barium (Ba). The results obtained were statistically treated, using SPSS program, discussed and further future research was suggested. The analysis show general suitability of fresh ground water at section A and C samples from

Suspended solids moderate the degradation and sorption of waste water-derived pharmaceuticals in estuarine waters.

Science.gov (United States)

Aminot, Yann; Fuster, Laura; Pardon, Patrick; Le Menach, Karyn; Budzinski, Hélène

2018-01-15

This study focuses on the fate of pharmaceuticals discharged into an estuarine environment, particularly into the Turbidity Maximum Zone (TMZ). Batch experiments were set up to investigate the factors regulating the degradation of 53 selected pharmaceuticals. Treated effluents from Bordeaux city (France) were mixed with water from the estuarine Garonne River during 4weeks under 6 characterized conditions in order to assess the influence of suspended particulates, sterilization, untreated wastewater input and dilution on the degradation kinetics. Of the 53 pharmaceuticals monitored, 43 were quantified at the initial time. Only 7 exhibited a persistent behavior (e.g. carbamazepine, meprobamate) while biotic degradation was shown to be the main attenuation process for 38 molecules (e.g. abacavir, ibuprofen highly degradable). Degradation was significantly enhanced by increasing concentrations of suspended solids. A persistence index based on the half-lives of the compounds has been calculated for each of the 43 pharmaceuticals to provide a practical estimate of their relative stability. The stability of pharmaceuticals in estuarine environments is likely to be highly variable and attenuated primarily by changes in suspended solid concentration. Copyright © 2017 Elsevier B.V. All rights reserved.

Toxic pressure of herbicides on microalgae in Dutch estuarine and coastal waters

Science.gov (United States)

Booij, Petra; Sjollema, Sascha B.; van der Geest, Harm G.; Leonards, Pim E. G.; Lamoree, Marja H.; de Voogt, W. Pim; Admiraal, Wim; Laane, Remi W. P. M.; Vethaak, A. Dick

2015-08-01

For several decades now, there has been an increase in the sources and types of chemicals in estuarine and coastal waters as a consequence of anthropogenic activities. This has led to considerable concern about the effects of these chemicals on the marine food chain. The fact is that estuarine and coastal waters are the most productive ecosystems with high primary production by microalgae. The toxic pressure of specific phytotoxic chemicals now poses a major threat to these ecosystems. In a previous study, six herbicides (atrazine, diuron, irgarol, isoproturon, terbutryn and terbutylazine) were identified as the main contaminants affecting photosynthesis in marine microalgae. The purpose of this study is to investigate the toxic pressure of these herbicides in the Dutch estuarine and coastal waters in relation to the effective photosystem II efficiency (ΦPSII) in microalgae. Temporal and spatial variations in the concentrations of these herbicides were analyzed based on monitoring data. Additionally, a field study was carried out in which chemical analysis of water was performed and also a toxicity assessment using the Pulse Amplitude Modulation (PAM) fluorometry assay that measures ΦPSII. The toxic pressure on ΦPSII in microalgae has decreased with 55-82% from 2003 to 2012, with the Western Scheldt estuary showing the highest toxic pressure. By combining toxicity data from the PAM assay with chemical analysis of herbicide concentrations, we have identified diuron and terbutylazine as the main contributors to the toxic pressure on microalgae. Although direct effects are not expected, the toxic pressure is close to the 10% effect level in the PAM assay. A compliance check with the current environmental legislation of the European Union revealed that the quality standards are not sufficient to protect marine microalgae.

Development of an estuarine assessment scheme for the management of a highly urbanised catchment/estuary system, Sydney estuary, Australia.

Science.gov (United States)

Birch, G F; Gunns, T J; Chapman, D; Harrison, D

2016-05-01

As coastal populations increase, considerable pressures are exerted on estuarine environments. Recently, there has been a trend towards the development and use of estuarine assessment schemes as a decision support tool in the management of these environments. These schemes offer a method by which complex environmental data is converted into a readily understandable and communicable format for informed decision making and effective distribution of limited management resources. Reliability and effectiveness of these schemes are often limited due to a complex assessment framework, poor data management and use of ineffective environmental indicators. The current scheme aims to improve reliability in the reporting of estuarine condition by including a concise assessment framework, employing high-value indicators and, in a unique approach, employing fuzzy logic in indicator evaluation. Using Sydney estuary as a case study, each of the 15 sub-catchment/sub-estuary systems were assessed using the current scheme. Results identified that poor sediment quality was a significant issue in Blackwattle/Rozelle Bay, Iron Cove and Hen and Chicken Bay while poor water quality was of particular concern in Duck River, Homebush Bay and the Parramatta River. Overall results of the assessment scheme were used to prioritise the management of each sub-catchment/sub-estuary assessed with Blackwattle/Rozelle Bay, Homebush Bay, Iron Cove and Duck River considered to be in need of a high priority management response. A report card format, using letter grades, was employed to convey the results of the assessment in a readily understood manner to estuarine managers and members of the public. Letter grades also provide benchmarking and performance monitoring ability, allowing estuarine managers to set improvement targets and assesses the effectiveness of management strategies. The current assessment scheme provides an effective, integrated and consistent assessment of estuarine health and

Isolation of heterotrophic diazotrophic bacteria from estuarine surface waters.

Science.gov (United States)

Farnelid, Hanna; Harder, Jens; Bentzon-Tilia, Mikkel; Riemann, Lasse

2014-10-01

The wide distribution of diverse nitrogenase (nifH) genes affiliated with those of heterotrophic bacteria in marine and estuarine waters indicates ubiquity and an ecologically relevant role for heterotrophic N2 -fixers (diazotrophs) in aquatic nitrogen (N) cycling. However, the lack of cultivated representatives currently precludes an evaluation of their N2 -fixing capacity. In this study, microoxic or anoxic N-free media were inoculated with estuarine Baltic Sea surface water to select for N2 -fixers. After visible growth and isolation of single colonies on oxic plates or in anoxic agar tubes, nifH gene amplicons were obtained from 64 strains and nitrogenase activity, applying the acetylene reduction assay, was confirmed for 40 strains. Two strains, one Gammaproteobacterium affiliated with Pseudomonas and one Alphaproteobacterium affiliated with Rhodopseudomonas were shown to represent established members of the indigenous diazotrophic community in the Baltic Sea, with abundances of up to 7.9 × 10(4) and 4.7 × 10(4)  nifH copies l(-1) respectively. This study reports media for successful isolation of heterotrophic diazotrophs. The applied methodology and the obtained strains will facilitate future identification of factors controlling heterotrophic diazotrophic activity in aquatic environments, which is a prerequisite for understanding and evaluating their ecology and contribution to N cycling at local and regional scales. © 2013 Society for Applied Microbiology and John Wiley & Sons Ltd.

Disturbances to metal partitioning during toxicity testing of iron(II)-rich estuarine pore waters and whole sediments.

Science.gov (United States)

Simpson, Stuart L; Batley, Graeme E

2003-02-01

Metal partitioning is altered when suboxic estuarine sediments containing Fe(II)-rich pore waters are disturbed during collection, preparation, and toxicity testing. Experiments with model Fe(II)-rich pore waters demonstrated the rates at which adsorptive losses of Cd, Cu, Ni, Mn, Pb, and Zn occur upon exposure to air. Experiments with Zn-contaminated estuarine sediments demonstrated large and often unpredictable changes to metal partitioning during sediment storage, removal of organisms, and homogenization before testing. Small modifications to conditions, such as aeration of overlying waters, caused large changes to the metal partitioning. Disturbances caused by sediment collection required many weeks for reestablishment of equilibrium. Bioturbation by benthic organisms led to oxidation of pore-water Fe(II) and lower Zn fluxes because of the formation of Fe hydroxide precipitates that adsorb pore-water Zn. For five weeks after the addition of organisms to sediments, Zn fluxes increased slowly as the organisms established themselves in the sediments, indicating that the establishment of equilibrium was not rapid. The results are discussed in terms of the dynamic nature of suboxic, Fe(II)-rich estuarine sediments, how organisms perturb their environment, and the importance of understanding chemistry in toxicity testing with whole sediments or pore water. Recommendations are provided for the handling of sediments for toxicity testing.

Behavioral responses of the estuarine calanoid copepod Eurytemora affinis to sub-lethal concentrations of waterborne pollutants

International Nuclear Information System (INIS)

Michalec, François-Gaël; Holzner, Markus; Menu, Dominique; Hwang, Jiang-Shiou; Souissi, Sami

2013-01-01

Highlights: •We studied the effects of sub-lethal exposure to pollutants on Eurytemora affinis swimming behavior. •Nonylphenol, cadmium and polycyclic aromatic hydrocarbons caused hyperactivity. •Effects were observable within 30 min of exposure and persisted during a depuration period. •The response resembles an escape reaction allowing copepods to evade stressful conditions. -- Abstract: Estuarine waters contain a variety of chemicals which affect to various extents the behavior of aquatic organisms. Little is known, however, on the behavioral response of copepods. The present study shows the results of laboratory experiments investigating the immediate effects of sub-lethal concentrations of three commonly found contaminants on the three-dimensional swimming behavior of the estuarine calanoid copepod Eurytemora affinis. Nonylphenol at 2 μg L −1 , cadmium at 45 ng L −1 and a mixture of low to medium molecular weight polycyclic aromatic hydrocarbons at 40 ng L −1 all affected the swimming behavior of E. affinis adults, increasing both swimming speed and activity. In most cases, effects were observable within 30 min of exposure and persisted or faded during a period of depuration in uncontaminated water of similar duration. In ovigerous females exposed to Cd and PAHs, effects appeared to be more pronounced during the depuration period, suggesting that carrying ovisacs may impair recovery. We quantified differences in the distribution of swimming speed values by considering the relative frequencies of periods of break, slow and fast swimming and we observed a trend toward faster movements in the presence of pollutants. The degree of trajectory complexity, estimated through their fractal dimension, was unaffected by pollutants. Since both narcotic and non-narcotic pollutants induced hyperactivity, our results suggest that changes in behavior after a short-term exposure may be independent of the general mode of action of the chemicals. The increase in

Behavioral responses of the estuarine calanoid copepod Eurytemora affinis to sub-lethal concentrations of waterborne pollutants

Energy Technology Data Exchange (ETDEWEB)

Michalec, François-Gaël [Université Lille Nord de France, F-59000 Lille (France); USTL, LOG, Station Marine de Wimereux, F-62930 Wimereux (France); CNRS, UMR 8187, F-62930 Wimereux (France); National Taiwan Ocean University, Institute of Marine Biology, Keelung, Taiwan, ROC (China); Holzner, Markus [Institute of Environmental Engineering, ETH Zürich (Switzerland); Menu, Dominique [Université Lille Nord de France, F-59000 Lille (France); USTL, LOG, Station Marine de Wimereux, F-62930 Wimereux (France); CNRS, UMR 8187, F-62930 Wimereux (France); Hwang, Jiang-Shiou [National Taiwan Ocean University, Institute of Marine Biology, Keelung, Taiwan, ROC (China); Souissi, Sami, E-mail: sami.souissi@univ-lille1.fr [Université Lille Nord de France, F-59000 Lille (France); USTL, LOG, Station Marine de Wimereux, F-62930 Wimereux (France); CNRS, UMR 8187, F-62930 Wimereux (France)

2013-08-15

Highlights: •We studied the effects of sub-lethal exposure to pollutants on Eurytemora affinis swimming behavior. •Nonylphenol, cadmium and polycyclic aromatic hydrocarbons caused hyperactivity. •Effects were observable within 30 min of exposure and persisted during a depuration period. •The response resembles an escape reaction allowing copepods to evade stressful conditions. -- Abstract: Estuarine waters contain a variety of chemicals which affect to various extents the behavior of aquatic organisms. Little is known, however, on the behavioral response of copepods. The present study shows the results of laboratory experiments investigating the immediate effects of sub-lethal concentrations of three commonly found contaminants on the three-dimensional swimming behavior of the estuarine calanoid copepod Eurytemora affinis. Nonylphenol at 2 μg L{sup −1}, cadmium at 45 ng L{sup −1} and a mixture of low to medium molecular weight polycyclic aromatic hydrocarbons at 40 ng L{sup −1} all affected the swimming behavior of E. affinis adults, increasing both swimming speed and activity. In most cases, effects were observable within 30 min of exposure and persisted or faded during a period of depuration in uncontaminated water of similar duration. In ovigerous females exposed to Cd and PAHs, effects appeared to be more pronounced during the depuration period, suggesting that carrying ovisacs may impair recovery. We quantified differences in the distribution of swimming speed values by considering the relative frequencies of periods of break, slow and fast swimming and we observed a trend toward faster movements in the presence of pollutants. The degree of trajectory complexity, estimated through their fractal dimension, was unaffected by pollutants. Since both narcotic and non-narcotic pollutants induced hyperactivity, our results suggest that changes in behavior after a short-term exposure may be independent of the general mode of action of the chemicals. The

Ground Water in the Anchorage Area, Alaska--Meeting the Challenges of Ground-Water Sustainability

Science.gov (United States)

Moran, Edward H.; Galloway, Devin L.

2006-01-01

Ground water is an important component of Anchorage's water supply. During the 1970s and early 80s when ground water extracted from aquifers near Ship Creek was the principal source of supply, area-wide declines in ground-water levels resulted in near record low streamflows in Ship Creek. Since the importation of Eklutna Lake water in the late 1980s, ground-water use has been reduced and ground water has contributed 14-30 percent of the annual supply. As Anchorage grows, given the current constraints on the Eklutna Lake water availability, the increasing demand for water could place an increasing reliance on local ground-water resources. The sustainability of Anchorage's ground-water resources challenges stakeholders to develop a comprehensive water-resources management strategy.

Some analytic diagnostic models for transport processes in estuarine and coastal waters

International Nuclear Information System (INIS)

Suarez Antola, R.

2001-03-01

Advection and dispersion processes in estuarine and coastal waters are briefly reviewed. Beginning from the basic macroscopic equations of transport for a substance diluted or suspended in the considered body of water,several levels of filtering in time and space are described and applied to obtain suitable diagnostic mathematical models both with scale effects and gaussian.The solutions of the aforementioned models,for initial distributions and boundary conditions with enough symmetry,are discussed, as well as their applications to a parameter characterization of the transport properties of the receiving body of water

Ground water and energy

Energy Technology Data Exchange (ETDEWEB)

1980-11-01

This national workshop on ground water and energy was conceived by the US Department of Energy's Office of Environmental Assessments. Generally, OEA needed to know what data are available on ground water, what information is still needed, and how DOE can best utilize what has already been learned. The workshop focussed on three areas: (1) ground water supply; (2) conflicts and barriers to ground water use; and (3) alternatives or solutions to the various issues relating to ground water. (ACR)

The impact of channel capture on estuarine hydro-morphodynamics and water quality in the Amazon delta.

Science.gov (United States)

Silva Dos Santos, Eldo; Pinheiro Lopes, Paula Patrícia; da Silva Pereira, Hyrla Herondina; de Oliveira Nascimento, Otávio; Rennie, Colin David; da Silveira Lobo O'Reilly Sternberg, Leonel; Cavalcanti da Cunha, Alan

2018-05-15

Due to progressive erosion of the new Urucurituba Channel, the Amazon River has recently captured almost all discharge from the lower Araguari River (Amapá-AP, Brazil), which previously flowed directly to the Atlantic Ocean. These recent geomorphological changes have caused strong impacts on the landscape and hydrodynamic patterns near the Araguari River mouth, especially the alteration of the riverine drainage system and its water quality. Landsat images were used to assess the estuarine landscape morphodynamic, particularly the expansion of the Urucurituba Channel, 80km from the Araguari River mouth, chronicling its connection to the Amazon River. The results suggest that the Urucurituba developed by headward migration across the Amazon delta; this is perhaps the first observation of estuarine distributary network development by headward channel erosion. The rate of Urucurituba Channel width increase has been ≈5m/month since 2011, increasing drainage capacity of the channel. We also collected in situ hydrodynamic measurements and analyzed 17 water quality parameters. Having 2011 as baseline, the flowrate of Araguari River has been diverted by up to 98% through Urucurituba Channel, with substantial changes in net discharge recorded at 3 monitoring stations. Statistically significant differences in water quality (pEstuarine salinity and solids concentrations have increased. Overall, we demonstrate changes in landscape, hydrodynamics and water quality of the lower Araguari River. Copyright © 2017 Elsevier B.V. All rights reserved.

Analytical characterization of selective benthic flux components in estuarine and coastal waters

Science.gov (United States)

King, Jeffrey N.

2011-01-01

Benthic flux is the rate of flow across the bed of a water body, per unit area of bed. It is forced by component mechanisms, which interact. For example, pressure gradients across the bed, forced by tide, surface gravity waves, density gradients, bed–current interaction, turbulence, and terrestrial hydraulic gradients, drive an advective benthic flux of water and constituents between estuarine and coastal waters, and surficial aquifers. Other mechanisms also force benthic flux, such as chemical gradients, bioturbation, and dispersion. A suite of component mechanisms force a total benthic flux at any given location, where each member of the suite contributes a component benthic flux. Currently, the types and characteristics of component interactions are not fully understood. For example, components may interact linearly or nonlinearly, and the interaction may be constructive or destructive. Benthic flux is a surface water–groundwater interaction process. Its discharge component to a marine water body is referred to, in some literature, as submarine groundwater discharge. Benthic flux is important in characterizing water and constituent budgets of estuarine and coastal systems. Analytical models to characterize selective benthic flux components are reviewed. Specifically, these mechanisms are for the component associated with the groundwater tidal prism, and forced by surface gravity wave setup, surface gravity waves on a plane bed, and the terrestrial hydraulic gradient. Analytical models are applied to the Indian River Lagoon, Florida; Great South Bay, New York; and the South Atlantic Bight in South Carolina and portions of North Carolina.

Monitoring of labile copper and zinc in estuarine waters using cathodic stripping chronopotentiometry

International Nuclear Information System (INIS)

Berg, C.M.G.

1991-01-01

Cathodic stripping chronopotentiometry (CSC) is readily suitable for automation, and sensitivity is often not affected by variations in major ion concentration (salinity) or by the dissolved concentration of oxygen. So this technique is very suitable for automated monitoring of certain trace elements in natural waters, including estuarine waters. The suitability of CSC for monitoring is demonstrated by measuring the concentrations of copper and zinc in the Tamar estuary in-line and automatically. The measuring rate was approximately 90h -1 . The concentrations of zinc and copper in the Tamar estuary were shown to behave in agreement with the findings of previous studies; the labile metal concentrations increased in the turbidity maximum and decreased immediately after it (at higher salinities) as a result of particle scavenging; gradual increase was apparent at intermediate salinities as result of pore-water injection, and the metal concentrations followed a dilution pattern with seawater at high salinities. In-line measurements provided a detailed picture of metal behaviour in this estuary and elucidated local inputs. The sensitivity (down to approximately 5 nM Cu and 6 nM Zn) allows monitoring of copper and zinc at levels common in estuarine and coastal waters, but is insufficient to monitor these metals in uncontaminated seawater. (author). 22 refs.; 4 figs

Estuarine Facies Model Revisited: Conceptual Model of Estuarine Sediment Dynamics During Non-Equilibrium Conditions

Science.gov (United States)

Elliott, E. A.; Rodriguez, A. B.; McKee, B. A.

2017-12-01

Traditional models of estuarine systems show deposition occurs primarily within the central basin. There, accommodation space is high within the deep central valley, which is below regional wave base and where current energy is presumed to reach a relative minimum, promoting direct deposition of cohesive sediment and minimizing erosion. However, these models often reflect long-term (decadal-millennial) timescales, where accumulation rates are in relative equilibrium with the rate of relative sea-level rise, and lack the resolution to capture shorter term changes in sediment deposition and erosion within the central estuary. This work presents a conceptual model for estuarine sedimentation during non-equilibrium conditions, where high-energy inputs to the system reach a relative maximum in the central basin, resulting in temporary deposition and/or remobilization over sub-annual to annual timescales. As an example, we present a case study of Core Sound, NC, a lagoonal estuarine system where the regional base-level has been reached, and sediment deposition, resuspension and bypassing is largely a result of non-equilibrium, high-energy events. Utilizing a 465 cm-long sediment core from a mini-basin located between Core Sound and the continental shelf, a 40-year sub-annual chronology was developed for the system, with sediment accumulation rates (SAR) interpolated to a monthly basis over the 40-year record. This study links erosional processes in the estuary directly with sediment flux to the continental shelf, taking advantage of the highly efficient sediment trapping capability of the mini-basin. The SAR record indicates high variation in the estuarine sediment supply, with peaks in the SAR record at a recurrence interval of 1 year (+/- 0.25). This record has been compared to historical storm influence for the area. Through this multi-decadal record, sediment flushing events occur at a much more frequent interval than previously thought (i.e. annual rather than

Transitions in midwestern ground water law

International Nuclear Information System (INIS)

Bowman, J.A.; Clark, G.R.

1989-01-01

The evolution of ground-water law in eight states in the Midwest (Illinois, Indiana, Iowa, Michigan, Minnesota, Missouri, Ohio, and Wisconsin) is examined, and a review of transitions in ground-water doctrines is presented. Two underlying themes in changing ground-water management are communicated. First, ground-water law is evolving from private property rules of capture based on the absolute ownership doctrines to rules requiring conservation and sharing of ground water as a public resource. Second, in both courts and state legislatures, a proactive role of ground-water management is emerging, again, with an emphasis on sharing. Both of these trends are apparent in the Midwest. In the last decade midwestern states have (1) seen significant shifts in court decisions on ground-water use with greater recognition of the reciprocal or mutually dependent nature of ground-water rights, and (2) seen increased legislative development of comprehensive ground-water management statutes that emphasize the reciprocal liabilities of ground-water use. These trends are examined and ground-water management programs discussed for eight states in the Midwest

Water organic pollution and eutrophication influence soil microbial processes, increasing soil respiration of estuarine wetlands: site study in jiuduansha wetland.

Science.gov (United States)

Zhang, Yue; Wang, Lei; Hu, Yu; Xi, Xuefei; Tang, Yushu; Chen, Jinhai; Fu, Xiaohua; Sun, Ying

2015-01-01

Undisturbed natural wetlands are important carbon sinks due to their low soil respiration. When compared with inland alpine wetlands, estuarine wetlands in densely populated areas are subjected to great pressure associated with environmental pollution. However, the effects of water pollution and eutrophication on soil respiration of estuarine and their mechanism have still not been thoroughly investigated. In this study, two representative zones of a tidal wetland located in the upstream and downstream were investigated to determine the effects of water organic pollution and eutrophication on soil respiration of estuarine wetlands and its mechanism. The results showed that eutrophication, which is a result of there being an excess of nutrients including nitrogen and phosphorus, and organic pollutants in the water near Shang shoal located upstream were higher than in downstream Xia shoal. Due to the absorption and interception function of shoals, there to be more nitrogen, phosphorus and organic matter in Shang shoal soil than in Xia shoal. Abundant nitrogen, phosphorus and organic carbon input to soil of Shang shoal promoted reproduction and growth of some highly heterotrophic metabolic microorganisms such as β-Proteobacteria, γ-Proteobacteria and Acidobacteria which is not conducive to carbon sequestration. These results imply that the performance of pollutant interception and purification function of estuarine wetlands may weaken their carbon sequestration function to some extent.

Simulation of the Regional Ground-Water-Flow System and Ground-Water/Surface-Water Interaction in the Rock River Basin, Wisconsin

Science.gov (United States)

Juckem, Paul F.

2009-01-01

A regional, two-dimensional, areal ground-water-flow model was developed to simulate the ground-water-flow system and ground-water/surface-water interaction in the Rock River Basin. The model was developed by the U.S. Geological Survey (USGS), in cooperation with the Rock River Coalition. The objectives of the regional model were to improve understanding of the ground-water-flow system and to develop a tool suitable for evaluating the effects of potential regional water-management programs. The computer code GFLOW was used because of the ease with which the model can simulate ground-water/surface-water interactions, provide a framework for simulating regional ground-water-flow systems, and be refined in a stepwise fashion to incorporate new data and simulate ground-water-flow patterns at multiple scales. The ground-water-flow model described in this report simulates the major hydrogeologic features of the modeled area, including bedrock and surficial aquifers, ground-water/surface-water interactions, and ground-water withdrawals from high-capacity wells. The steady-state model treats the ground-water-flow system as a single layer with hydraulic conductivity and base elevation zones that reflect the distribution of lithologic groups above the Precambrian bedrock and a regionally significant confining unit, the Maquoketa Formation. In the eastern part of the Basin where the shale-rich Maquoketa Formation is present, deep ground-water flow in the sandstone aquifer below the Maquoketa Formation was not simulated directly, but flow into this aquifer was incorporated into the GFLOW model from previous work in southeastern Wisconsin. Recharge was constrained primarily by stream base-flow estimates and was applied uniformly within zones guided by regional infiltration estimates for soils. The model includes average ground-water withdrawals from 1997 to 2006 for municipal wells and from 1997 to 2005 for high-capacity irrigation, industrial, and commercial wells. In addition

An in situ postexposure feeding assay with Carcinus maenas for estuarine sediment-overlying water toxicity evaluations

International Nuclear Information System (INIS)

Moreira, Susana M.; Moreira-Santos, Matilde; Guilhermino, Lucia; Ribeiro, Rui

2006-01-01

This study developed and evaluated a short-term sublethal in situ toxicity assay for estuarine sediment-overlying waters, with the crab Carcinus maenas (L.) based on postexposure feeding. It consisted of a 48-h in situ exposure period followed by a short postexposure feeding period (30 min). A precise method for quantifying feeding, using the Polychaeta Hediste (Nereis) diversicolor Mueller as food source, was first developed. The sensitivity of the postexposure feeding response was verified by comparing it to that of lethality, upon cadmium exposure. The influence of environmental conditions prevailing during exposure (salinity, temperature, substrate, light regime, and food availability) on postexposure feeding was also addressed. The potential of this in situ assay was then investigated by deploying organisms at ten sites, located in reference and contaminated Portuguese estuaries. Organism recovery ranged between 90% and 100% and a significant postexposure feeding depression (16.3-72.7%) was observed at all contaminated sites relatively to references. - A new sub-lethal toxicity assay is presented for marine invertebrates

Ground-water travel time

International Nuclear Information System (INIS)

Bentley, H.; Grisak, G.

1985-01-01

The Containment and Isolation Working Group considered issues related to the postclosure behavior of repositories in crystalline rock. This working group was further divided into subgroups to consider the progress since the 1978 GAIN Symposium and identify research needs in the individual areas of regional ground-water flow, ground-water travel time, fractional release, and cumulative release. The analysis and findings of the Ground-Water Travel Time Subgroup are presented

Regional ground-water system

International Nuclear Information System (INIS)

Long, J.

1985-01-01

The Containment and Isolation Working Group considered issues related to the postclosure behavior of repositories in crystalline rock. This working group was further divided into subgroups to consider the progress since the 1978 GAIN Symposium and identify research needs in the individual areas of regional ground-water flow, ground-water travel time, fractional release, and cumulative release. The analysis and findings of the Ground-Water Regime Subgroup are presented

Simulation of ground-water flow and land subsidence in the Antelope Valley ground-water basin, California

Science.gov (United States)

Leighton, David A.; Phillips, Steven P.

2003-01-01

Antelope Valley, California, is a topographically closed basin in the western part of the Mojave Desert, about 50 miles northeast of Los Angeles. The Antelope Valley ground-water basin is about 940 square miles and is separated from the northern part of Antelope Valley by faults and low-lying hills. Prior to 1972, ground water provided more than 90 percent of the total water supply in the valley; since 1972, it has provided between 50 and 90 percent. Most ground-water pumping in the valley occurs in the Antelope Valley ground-water basin, which includes the rapidly growing cities of Lancaster and Palmdale. Ground-water-level declines of more than 200 feet in some parts of the ground-water basin have resulted in an increase in pumping lifts, reduced well efficiency, and land subsidence of more than 6 feet in some areas. Future urban growth and limits on the supply of imported water may continue to increase reliance on ground water. To better understand the ground-water flow system and to develop a tool to aid in effectively managing the water resources, a numerical model of ground-water flow and land subsidence in the Antelope Valley ground-water basin was developed using old and new geohydrologic information. The ground-water flow system consists of three aquifers: the upper, middle, and lower aquifers. The aquifers, which were identified on the basis of the hydrologic properties, age, and depth of the unconsolidated deposits, consist of gravel, sand, silt, and clay alluvial deposits and clay and silty clay lacustrine deposits. Prior to ground-water development in the valley, recharge was primarily the infiltration of runoff from the surrounding mountains. Ground water flowed from the recharge areas to discharge areas around the playas where it discharged either from the aquifer system as evapotranspiration or from springs. Partial barriers to horizontal ground-water flow, such as faults, have been identified in the ground-water basin. Water-level declines owing to

Imtechella halotolerans gen. nov., sp. nov., a member of the family Flavobacteriaceae isolated from estuarine water

Digital Repository Service at National Institute of Oceanography (India)

Surendra, V.; Bhawana, P.; Suresh, K.; Srinivas, T.N.R.; AnilKumar, P.

A novel Gram-negative, rod-shaped, non-motile, non-sporulating bacterium, designated strain K1 sup(T), was isolated from an estuarine water sample collected from Kochi, Kerala, India. Colonies on marine agar were circular, 2.0-2.5 mm in diameter...

Contamination of ground water, surface water, and soil, and evaluation of selected ground-water pumping alternatives in the Canal Creek area of Aberdeen Proving Ground, Maryland

Science.gov (United States)

Lorah, Michelle M.; Clark, Jeffrey S.

1996-01-01

Chemical manufacturing, munitions filling, and other military-support activities have resulted in the contamination of ground water, surface water, and soil in the Canal Creek area of Aberdeen Proving Ground, Maryland. Chlorinated volatile organic compounds, including 1,1,2,2-tetrachloroethane and trichloroethylene, are widespread ground-water contaminants in two aquifers that are composed of unconsolidated sand and gravel. Distribution and fate of chlorinated organic compounds in the ground water has been affected by the movement and dissolution of solvents in their dense immiscible phase and by microbial degradation under anaerobic conditions. Detection of volatile organic contaminants in adjacent surface water indicates that shallow contaminated ground water discharges to surface water. Semivolatile organic compounds, especially polycyclic aromatic hydrocarbons, are the most prevalent organic contaminants in soils. Various trace elements, such as arsenic, cadmium, lead, and zinc, were found in elevated concentrations in ground water, surface water, and soil. Simulations with a ground-water-flow model and particle tracker postprocessor show that, without remedial pumpage, the contaminants will eventually migrate to Canal Creek and Gunpowder River. Simulations indicate that remedial pumpage of 2.0 million gallons per day from existing wells is needed to capture all particles originating in the contaminant plumes. Simulated pumpage from offsite wells screened in a lower confined aquifer does not affect the flow of contaminated ground water in the Canal Creek area.

Interaction between continental and estuarine waters in the wetlands of the northern coastal plain of Samborombón Bay, Argentina

International Nuclear Information System (INIS)

Carol, Eleonora; Mas-Pla, Josep; Kruse, Eduardo

2013-01-01

Highlights: • Inland and estuarine water flows define wetland hydrology on the Samborombón Bay. • Hydrochemistry in shell-ridges and tidal plains is due to water–rock interaction. • Mixing, evaporation and halite dissolution determine salinity in marshes. • Water flow from the shell-ridges control the overall wetland water quality. • These wetlands are complex hydrological systems with vulnerable water resources. - Abstract: On the Samborombón Bay coastline, located in the Río de la Plata estuary in Buenos Aires province (Argentina), a complex hydrological system has developed at the interface between continental and estuarine water, where significant wetlands develop. The main hydrogeological units, namely the shell ridges, the tidal plain and the marsh areas, have been identified using geomorphological criteria. Water table, hydrochemical and isotopic data have been used to determine their hydrological features, as well as those of the streams and canals. Evaporation processes, in particular, have been considered when depicting chemical and isotopic changes in surface waters in streams and marsh areas. The shell ridges represent a hydrogeological unit in which rainwater is stored, constituting a lens-shaped freshwater aquifer. In this unit, just as in the tidal plain, carbonate dissolution and ion exchange are the main processes regulating water chemistry. On the other hand, in the marsh and surface waters, processes such as mixing with estuarine water and evaporation predominate. These processes control water fluxes and the salinity of the wetland areas and, consequently, their ability to preserve the existing biodiversity. This study shows the importance of knowledge of hydrochemical processes in any proposal concerning the management and preservation of this type of wetland

Ground Water and Climate Change

Science.gov (United States)

Taylor, Richard G.; Scanlon, Bridget; Doell, Petra; Rodell, Matt; van Beek, Rens; Wada, Yoshihide; Longuevergne, Laurent; Leblanc, Marc; Famiglietti, James S.; Edmunds, Mike;

Concentrations of stable elements and uranium in estuarine areas of Japan

International Nuclear Information System (INIS)

Takata, Hyoe; Aono, Tatsuo; Tagami, Keiko; Uchida, Shigeo

2008-01-01

The geochemistry of stable elements can be a good analogue for understanding the behavior of radionuclides in estuarine and coastal environments. In this study, the behavior of nutrients (NO 3 + NO 2 , PO 4 , Si(OH) 4 ), heavy metals, and U was observed in several estuarine and coastal waters of Japan. We also collected data on salinity, pH, and suspended particle matter (SPM). Nutrient concentrations followed conservative dilution lines in these estuaries, and concentrations of dissolved Fe decreased as salinity increased from 0 to 20. In general, most of the dissolved Fe in estuaries is in colloidal form. The behavior of dissolved Fe might reflect a loss of colloidal Fe through coagulation in this salinity range. Dissolved Co and Ni concentrations followed approximate dilution lines from the rivers to the seawater end-members, suggesting that they were quasi-conservative in these estuarine systems. A rapid increase in dissolved Cd concentrations was observed at low levels of salinity (<4). Estimated fluxes of dissolved Cd to the estuarine and coastal waters showed that the salt-induced desorption of Cd from particles constitutes a significant source of dissolved Cd in the estuarine and coastal waters. (author)

Move of ground water

International Nuclear Information System (INIS)

Kimura, Shigehiko

1983-01-01

As a ground water flow which is difficult to explain by Darcy's theory, there is stagnant water in strata, which moves by pumping and leads to land subsidence. This is now a major problem in Japan. Such move on an extensive scale has been investigated in detail by means of 3 H such as from rainfall in addition to ordinary measurement. The move of ground water is divided broadly into that in an unsaturated stratum from ground surface to water-table and that in a saturated stratum below the water-table. The course of the analyses made so far by 3 H contained in water, and the future trend of its usage are described. A flow model of regarding water as plastic fluid and its flow as channel assembly may be available for some flow mechanism which is not possible to explain with Darcy's theory. (Mori, K.)

Hydrogeology, simulated ground-water flow, and ground-water quality, Wright-Patterson Air Force Base, Ohio

Science.gov (United States)

Dumouchelle, D.H.; Schalk, C.W.; Rowe, G.L.; De Roche, J.T.

1993-01-01

Ground water is the primary source of water in the Wright-Patterson Air Force Base area. The aquifer consists of glacial sands and gravels that fill a buried bedrock-valley system. Consolidated rocks in the area consist of poorly permeable Ordovician shale of the Richmondian stage, in the upland areas, the Brassfield Limestone of Silurian age. The valleys are filled with glacial sediments of Wisconsinan age consisting of clay-rich tills and coarse-grained outwash deposits. Estimates of hydraulic conductivity of the shales based on results of displacement/recovery tests range from 0.0016 to 12 feet per day; estimates for the glacial sediments range from less than 1 foot per day to more than 1,000 feet per day. Ground water flow from the uplands towards the valleys and the major rivers in the region, the Great Miami and the Mad Rivers. Hydraulic-head data indicate that ground water flows between the bedrock and unconsolidated deposits. Data from a gain/loss study of the Mad River System and hydrographs from nearby wells reveal that the reach of the river next to Wright-Patterson Air Force Base is a ground-water discharge area. A steady-state, three-dimensional ground-water-flow model was developed to simulate ground-water flow in the region. The model contains three layers and encompasses about 100 square miles centered on Wright-Patterson Air Force Base. Ground water enters the modeled area primarily by river leakage and underflow at the model boundary. Ground water exits the modeled area primarily by flow through the valleys at the model boundaries and through production wells. A model sensitivity analysis involving systematic changes in values of hydrologic parameters in the model indicates that the model is most sensitive to decreases in riverbed conductance and vertical conductance between the upper two layers. The analysis also indicates that the contribution of water to the buried-valley aquifer from the bedrock that forms the valley walls is about 2 to 4

Ground-water sample collection and analysis plan for the ground-water surveillance project

International Nuclear Information System (INIS)

Bryce, R.W.; Evans, J.C.; Olsen, K.B.

1991-12-01

The Pacific Northwest Laboratory performs ground-water sampling activities at the US Department of Energy's (DOE's) Hanford Site in support of DOE's environmental surveillance responsibilities. The purpose of this document is to translate DOE's General Environmental Protection Program (DOE Order 5400.1) into a comprehensive ground-water sample collection and analysis plan for the Hanford Site. This sample collection and analysis plan sets forth the environmental surveillance objectives applicable to ground water, identifies the strategy for selecting sample collection locations, and lists the analyses to be performed to meet those objectives

Probing the ground state and zero-field cooled exchange bias by magnetoresistance measurement in Mn{sub 50}Ni{sub 41}Sn{sub 9} ribbon

Energy Technology Data Exchange (ETDEWEB)

Chen, Jiyun [Jiangsu Laboratory of Advanced Functional Materials, Department of Physics, Changshu Institute of Technology, Changshu 215500 (China); School of Materials Science and Engineering, China University of Mining & Technology, Xuzhou 221116 (China); Tu, Ruikang [Jiangsu Laboratory of Advanced Functional Materials, Department of Physics, Changshu Institute of Technology, Changshu 215500 (China); School of Materials Science and Engineering, Soochow University, Suzhou 215000 (China); Fang, Xiaoting [Jiangsu Laboratory of Advanced Functional Materials, Department of Physics, Changshu Institute of Technology, Changshu 215500 (China); Gu, Quanchao [Jiangsu Laboratory of Advanced Functional Materials, Department of Physics, Changshu Institute of Technology, Changshu 215500 (China); School of Materials Science and Engineering, Soochow University, Suzhou 215000 (China); Zhou, Yanying [Jiangsu Laboratory of Advanced Functional Materials, Department of Physics, Changshu Institute of Technology, Changshu 215500 (China); Cui, Rongjing [Department of Chemistry, Changshu Institute of Technology, Changshu 215500 (China); Han, Zhida, E-mail: han@cslg.edu.cn [Jiangsu Laboratory of Advanced Functional Materials, Department of Physics, Changshu Institute of Technology, Changshu 215500 (China); Zhang, Lei; Fang, Yong [Jiangsu Laboratory of Advanced Functional Materials, Department of Physics, Changshu Institute of Technology, Changshu 215500 (China); Qian, Bin, E-mail: njqb@cslg.edu.cn [Jiangsu Laboratory of Advanced Functional Materials, Department of Physics, Changshu Institute of Technology, Changshu 215500 (China); Zhang, Chengliang [School of Science, Jiangnan University, Wuxi 214122 (China); Jiang, Xuefan [Jiangsu Laboratory of Advanced Functional Materials, Department of Physics, Changshu Institute of Technology, Changshu 215500 (China)

2017-03-15

Recently, a new type of exchange bias (EB) after zero-field cooling has attracted considerable interest mainly in bulk magnetic competing systems. Here, we use a detailed magnetotransport investigation to probe the ground state and zero-field cooled EB (ZEB) in Mn{sub 50}Ni{sub 41}Sn{sub 9} ribbon. Both ZEB and field cooled EB were detected in magnetoresistance results consistent with magnetic measurement. A pure spin-glass ground state is proposed based on parabolic shape of low-field magnetoresistance combined with AC magnetization, memory effect. The appearance of ZEB is attributed to the field-induced nucleation and growth of ferromagnetic domains in the spin glass matrix forming unidirectional anisotropy at the interface. - Highlights: • Magnetoresistance was first used to probe the ground state and ZEB in Ni-Mn-based alloys. • A pure spin-glass ground state is proposed in Mn{sub 50}Ni{sub 41}Sn{sub 9} ribbon. • Field-induced nucleation and growth of ferromagnetic domains in SG results in ZEB.

Ground water and earthquakes

Energy Technology Data Exchange (ETDEWEB)

Ts' ai, T H

1977-11-01

Chinese folk wisdom has long seen a relationship between ground water and earthquakes. Before an earthquake there is often an unusual change in the ground water level and volume of flow. Changes in the amount of particulate matter in ground water as well as changes in color, bubbling, gas emission, and noises and geysers are also often observed before earthquakes. Analysis of these features can help predict earthquakes. Other factors unrelated to earthquakes can cause some of these changes, too. As a first step it is necessary to find sites which are sensitive to changes in ground stress to be used as sensor points for predicting earthquakes. The necessary features are described. Recording of seismic waves of earthquake aftershocks is also an important part of earthquake predictions.

SITE-94. Geochemical characterization of Simpevarp ground waters near the Aespoe Hard Rock Laboratory

Energy Technology Data Exchange (ETDEWEB)

Glynn, P D; Voss, C I [US Geological Survey, Reston, VA (United States)

1999-09-01

The present report analyzes the geochemical data in order to evaluate collection and interpretation techniques that will be used to site the repository and to assess its safety. Ground waters near the Aespoe Hard Rock Laboratory (HRL) may be grouped into five chemically and isotopically distinct water types, on the basis of their deuterium and chloride contents: 1) recent waters, 2) 5 g/L chloride waters, 3) deep waters, 4) seawater imprint waters, and 5) glacial melt waters. The sampled ground waters show a progressive change from a predominantly NaHCO{sub 3} composition at shallow depth to a CaCl{sub 2}-rich composition at depth. Despite the proximity of the Baltic, relatively few of the sampled ground waters contain any evidence of a seawater component. This finding, together with the rather shallow depths at which saline waters were found, indicates that Aespoe island is presently in a regional ground-water discharge area. The chemical and isotopic composition of the sampled waters also indicates that local recharge of dilute recent waters occurs only down to shallow depths (generally less than 100 in). The Aespoe ground waters are sulfidic and do not presently contain any dissolved oxygen. Measured E{sub H} values are generally near -300 mV, and on average are only about 50 mV lower than E{sub H} values calculated from the sulfide/sulfate couple. Maintenance of reducing conditions, such as presently found at the Aespoe HRL, is an important consideration in assessing the performance of nuclear waste disposal sites. Measurements of dissolved radon and of uranium concentrations in fracture-fill materials were used to calculate an average effective flow-wetted surface area of 3.1 m{sup 2} per liter of water for the Aespoe site. Estimation of flow-wetted surface areas is essential in determining the importance of matrix diffusion and surface sorption processes for radionuclide release calculations. The Rn calculation technique shows promise in helping narrow the

Salicylic acid determination in estuarine and riverine waters using hollow fiber liquid-phase microextraction and capillary zone electrophoresis.

Science.gov (United States)

da Silva, Gilmar Silvério; Lima, Diana L D; Esteves, Valdemar Inocêncio

2017-06-01

A low-cost methodology using hollow fiber liquid-phase microextraction (HF-LPME) and capillary zone electrophoresis (CZE) with UV-Vis detector was developed to analyze the salicylic acid (SA) in estuarine and riverine waters. The technique is easy-to-use and rapid, and demands little volume of organic solvent. The extraction was carried out using a polypropylene membrane supporting into octan-1-ol. HF-LPME under optimized conditions (donor solution sample pH 2, acceptor solution pH 14, sample volume 25 mL, fiber length 10 cm, acceptor volume 25 μL, extraction time 3 h and stirring speed 350 rpm) presented high enrichment factor (407 times) and good recovery in real water samples (from 88 to 110%). A limit of detection of 2.6 μg L -1 was achieved using CZE with UV-Vis detector as quantification method. The method was applied to direct quantification of SA in environmental complex estuarine and riverine water matrices.

Pathogenic bacteria associated with oysters (Crassostrea brasiliana) and estuarine water along the south coast of Brazil.

Science.gov (United States)

Ristori, Christiane A; Iaria, Sebastião T; Gelli, Dilma S; Rivera, Irma N G

2007-08-01

Oysters and estuarine water samples were collected monthly, from June 1998 to March 1999, in the Cananéia estuary, on the south coast of São Paulo, Brazil, and analyzed for bacterial hazards with and without depuration in filtered estuarine water. Aeromonas spp., Plesiomonas shigelloides, Vibrio cholerae O1, Vibrio parahaemolyticus, and Vibrio vulnificus were counted in oyster samples using the most probable number (MPN) and their presence verified in the surrounding estuarine water samples. The presence of Salmonella, Shigella, Escherichia coli O157:H7, and fecal coliforms counts were determined in oysters and in water samples too. Sixty percent of water samples contained fecal coliforms ranging from 200 CFU/100 ml and 100%, 30%, 20% and 10% were positive for V. parahaemolyticus, Salmonella, Aeromonas, and V. vulnificus in 5 l of water samples, respectively. In oyster samples, the fecal coliforms concentration ranged from or =2.4 x 10(3) MPN/g in 40% of untreated and from oyster samples and their concentration varied from 3.6 to > or =2.4 x 10(3) MPN/g. For the untreated oyster samples 80%, 70%, and 10% were positive for V. vulnificus (oyster samples 60%, 30%, and 0% of them contained the same bacteria, respectively. Escherichia coli O157:H7, Shigella spp., P. shigelloides, and V. cholerae O1 were not detected in any of the samples. Fecal indicators did not correlate with Vibrio presence (p>0.05), although the isolation of Aeromonas species had a positive correlation (p = 0.017). The results showed no correlation between temperature, salinity, and bacteria (p > 0.05). The comparison between bacterial concentration in treated and untreated oyster samples, showed that only Aeromonas was higher in untreated oyster samples (p = 0.039). This study contributes toward creating a more global understanding of food-borne bacterial pathogens. The presence and concentration of viable bacterial hazards in oysters and water surrounding areas was determined for the first time

Ground-Water Availability in the United States

Science.gov (United States)

Reilly, Thomas E.; Dennehy, Kevin F.; Alley, William M.; Cunningham, William L.

2008-01-01

Ground water is among the Nation's most important natural resources. It provides half our drinking water and is essential to the vitality of agriculture and industry, as well as to the health of rivers, wetlands, and estuaries throughout the country. Large-scale development of ground-water resources with accompanying declines in ground-water levels and other effects of pumping has led to concerns about the future availability of ground water to meet domestic, agricultural, industrial, and environmental needs. The challenges in determining ground-water availability are many. This report examines what is known about the Nation's ground-water availability and outlines a program of study by the U.S. Geological Survey Ground-Water Resources Program to improve our understanding of ground-water availability in major aquifers across the Nation. The approach is designed to provide useful regional information for State and local agencies who manage ground-water resources, while providing the building blocks for a national assessment. The report is written for a wide audience interested or involved in the management, protection, and sustainable use of the Nation's water resources.

Management of ground water using isotope techniques

International Nuclear Information System (INIS)

Romani, Saleem

2004-01-01

Ground water play a major role in national economy and sustenance of life and environment. Prevalent water crisis in India includes falling water table, water quality deterioration, water logging and salinity. Keeping in view the increasing thrust on groundwater resources and the present scenario of availability vis-a vis demand there is a need to reorient our approach to ground water management. The various ground water management options require proper understanding of ground water flow system. Isotopes are increasingly being applied in hydrogeological investigations as a supplementary tool for assessment of aquifer flow and transport characteristics. Isotope techniques coupled with conventional hydrogeological and hydrochemical methods can bring in greater accuracy in the conceptualization of hydrogeological control mechanism. The use of isotope techniques in following areas can certainly be of immense help in implementing various ground water management options in an efficient manner. viz.Interaction between the surface water - groundwater systems to plan conjunctive use of surface and ground water. Establishing hydraulic interconnections between the aquifers in a multi aquifer system. Depth of circulation of water and dating of ground water. Demarcating ground water recharge and discharge areas. Plan ground water development in coastal aquifers to avoid sea water ingress. Development of flood plain aquifer. (author)

Parameterization of the chlorophyll a-specific in vivo light absorption coefficient covering estuarine, coastal and oceanic waters

DEFF Research Database (Denmark)

Stæhr, P. A.; Markager, S.

2004-01-01

We evaluated models predicting the spectral chlorophyll-a (Chl a)-specific absorption coefficient (a*ph (¿)) from Chl a concentration [Chl a] on the basis of 465 phytoplankton absorption spectra collected in estuarine, coastal and oceanic waters. A power model on ln-transformed data provided...

Simplified estimation technique for organic contaminant transport in ground water

Energy Technology Data Exchange (ETDEWEB)

Piver, W T; Lindstrom, F T

1984-05-01

The analytical solution for one-dimensional dispersive-advective transport of a single solute in a saturated soil accompanied by adsorption onto soil surfaces and first-order reaction rate kinetics for degradation can be used to evaluate the suitability of potential sites for burial of organic chemicals. The technique can be used to the greatest advantage with organic chemicals that are present in ground waters in small amounts. The steady-state solution provides a rapid method for chemical landfill site evaluation because it contains the important variables that describe interactions between hydrodynamics and chemical transformation. With this solution, solute concentration, at a specified distance from the landfill site, is a function of the initial concentration and two dimensionless groups. In the first group, the relative weights of advective and dispersive variables are compared, and in the second group the relative weights of hydrodynamic and degradation variables are compared. The ratio of hydrodynamic to degradation variables can be rearranged and written as (a/sub L lambda)/(q/epsilon), where a/sub L/ is the dispersivity of the soil, lambda is the reaction rate constant, q is ground water flow velocity, and epsilon is the soil porosity. When this term has a value less than 0.01, the degradation process is occurring at such a slow rate relative to the hydrodynamics that it can be neglected. Under these conditions the site is unsuitable because the chemicals are unreactive, and concentrations in ground waters will change very slowly with distance away from the landfill site.

Fundamentals of estuarine physical oceanography

CERN Document Server

Bruner de Miranda, Luiz; Kjerfve, Björn; Castro Filho, Belmiro Mendes de

2017-01-01

This book provides an introduction to the complex system functions, variability and human interference in ecosystem between the continent and the ocean. It focuses on circulation, transport and mixing of estuarine and coastal water masses, which is ultimately related to an understanding of the hydrographic and hydrodynamic characteristics (salinity, temperature, density and circulation), mixing processes (advection and diffusion), transport timescales such as the residence time and the exposure time. In the area of physical oceanography, experiments using these water bodies as a natural laboratory and interpreting their circulation and mixing processes using theoretical and semi-theoretical knowledge are of fundamental importance. Small-scale physical models may also be used together with analytical and numerical models. The book highlights the fact that research and theory are interactive, and the results provide the fundamentals for the development of the estuarine research.

Water resources data for Virginia, water year 1991. Volume 2. Ground-water-level and ground-water-quality records. Water-data report (Annual), 1 October 1991-30 September 1992

International Nuclear Information System (INIS)

Prugh, B.J.; Powell, E.D.

1993-01-01

Water-resources data for the 1992 water year for Virginia consist of records of water levels and water quality of ground-water wells. The report (Volume 2. Ground-Water-Level and Ground-Water-Quality Records) contains water levels at 356 observation wells and water quality at 2 wells. Locations of these wells are given in the report

Seasonal Variability of Mesozooplankton Feeding Rates on Phytoplankton in Subtropical Coastal and Estuarine Waters

Directory of Open Access Journals (Sweden)

Mianrun Chen

2017-06-01

Full Text Available In order to understand how mesozooplankton assemblages influenced phytoplankton in coastal and estuarine waters, we carried out a monthly investigation on mesozooplankton composition at two contrasting stations of Hong Kong coastal and estuarine waters and simultaneously conducted bottle incubation feeding experiments. The assemblage of mesozooplankton was omnivorous at both stations with varying carnivory degree (the degree of feeding preference of protozoa and animal food to phytoplankton and the variations of carnivory degree were significantly associated with microzooplankton biomass (ciliates for the coastal station, both ciliates and dinoflagellates for the estuarine stations and physical environmental parameters (primarily salinity. High carnivory was primarily due to high composition of noctilucales, Corycaeus spp., Oithona spp. and Acartia spp. Results of feeding experiments showed that grazing impacts on phytoplankton ranged from −5.9 to 17.7%, while the mean impacts were just <4% at both stations. The impacts were size-dependent, by which mesozooplankton consumed around 9% of large-sized phytoplankton while indirectly caused an increase of 4% of small-sized phytoplankton. Mesozooplankton clearance rate on phytoplankton, calculated from the log response of chlorophyll a concentrations by the introduction of bulk grazers after 1-day incubation, was significantly reduced by increasing carnivory degree of the mesozooplankton assemblage. The mechanism for the reduction of mesozooplankton clearance rate with increasing carnivory degree was primarily due to less efficient of filtering feeding and stronger trophic cascades due to suppression of microzooplankton. The feeding rates of mesozooplankton on microzooplankton were not obtained in this study, but the trophic cascades indirectly induced by mesozooplankton carnivorous feeding can be observed by the negative clearance rate on small-sized phytoplankton. Overall, the main significance of

Pesticides in Ground Water

DEFF Research Database (Denmark)

Bjerg, Poul Løgstrup

1996-01-01

Review af: Jack E. Barbash & Elizabeth A. Resek (1996). Pesticides in Ground Water. Distribution trends and governing factors. Ann Arbor Press, Inc. Chelsea, Michigan. pp 588.......Review af: Jack E. Barbash & Elizabeth A. Resek (1996). Pesticides in Ground Water. Distribution trends and governing factors. Ann Arbor Press, Inc. Chelsea, Michigan. pp 588....

Water reform in Sub-Saharan Africa: what is the difference?

Science.gov (United States)

Van Koppen, Barbara

Since the early 1990s African governments took an active part in the global movement of water reform towards Integrated Water Resources Management (IWRM). The first step consisted primarily of assimilating the generic principles of IWRM. At this generic level, water reform in Sub-Saharan Africa seems quite similar to water reform elsewhere in the developed and developing world. However, in taking the second step of operationalizing generic principles into concrete actions on the ground, at least three salient differences between Sub-Saharan Africa and elsewhere emerged: (a) Africa’s relative abundance of water resources but its scarcity of economic means to harness available water resources; (b) the importance of agriculture and agricultural water development for economic growth and poverty eradication; and (c) the need for systems of water rights and financial resource mobilization that are separated and suit the African reality in which large water users are relatively few, while the bulk of water users are scattered smallholders. This paper discusses the early operationalization with regard to these three unique features and identifies lessons learnt.

National water summary 1986; Hydrologic events and ground-water quality

Science.gov (United States)

Moody, David W.; Carr, Jerry E.; Chase, Edith B.; Paulson, Richard W.

1988-01-01

Ground water is one of the most important natural resources of the United States and degradation of its quality could have a major effect on the welfare of the Nation. Currently (1985), ground water is the source of drinking water for 53 percent of the Nation's population and for more than 97 percent of its rural population. It is the source of about 40 percent of the Nation's public water supply, 33 percent of water for irrigation, and 17 percent of freshwater for selfsupplied industries.Ground water also is the source of about 40 percent of the average annual streamflow in the United States, although during long periods of little or no precipitation, ground-water discharges provide nearly all of the base streamflow. This hydraulic connection between aquifers and streams implies that if a persistent pollutant gets into an aquifer, it eventually could discharge into a stream.Information presented in the 1986 National Water Summary clearly shows that the United States has very large amounts of potable ground water available for use. Although naturally occurring constituents, such as nitrate, and human-induced substances, such as synthetic organic chemicals, frequently are detected in ground water, their concentrations usually do not exceed existing Federal or State standards or guidelines for maximum concentrations in drinking water.Troublesome contamination of ground water falls into two basic categories related to the source or sources of the contamination. Locally, high concentrations of a variety of toxic metals, organic chemicals, and petroleum products have been detected in ground water associated with point sources such as wastedisposal sites, storage-tank leaks, and hazardous chemical spills. These types of local problems commonly occur in densely populated urban areas and industrialized areas. Larger, multicounty areas also have been identified where contamination frequently is found in shallow wells. These areas generally are associated with broad

Water management, agriculture, and ground-water supplies

Science.gov (United States)

Nace, Raymond L.

1960-01-01

Encyclopedic data on world geography strikingly illustrate the drastic inequity in the distribution of the world's water supply. About 97 percent of the total volume of water is in the world's oceans. The area of continents and islands not under icecaps, glaciers, lakes, and inland seas is about 57.5 million square miles, of which 18 million (36 percent) is arid to semiarid. The total world supply of water is about 326.5 million cubic miles, of which about 317 million is in the oceans and about 9.4 million is in the land areas. Atmospheric moisture is equivalent to only about 3,100 cubic miles of water. The available and accessible supply of ground water in the United States is somewhat more than 53,000 cubic miles (about 180 billion acre ft). The amount of fresh water on the land areas of the world at any one time is roughly 30,300 cubic miles and more than a fourth of this is in large fresh-water lakes on the North American Continent. Annual recharge of ground water in the United States may average somewhat more than 1 billion acre-feet yearly, but the total volume of ground water in storage is equivalent to all the recharge in about the last 160 years. This accumulation of ground water is the nation's only reserve water resource, but already it is being withdrawn or mined on a large scale in a few areas. The principal withdrawals of water in the United States are for agriculture and industry. Only 7.4 percent of agricultural land is irrigated, however; so natural soil moisture is the principal source of agricultural water, and on that basis agriculture is incomparably the largest water user. In view of current forecasts of population and industrial expansion, new commitments of water for agriculture should be scrutinized very closely, and thorough justification should be required. The 17 Western States no longer contain all the large irrigation developments. Nearly 10 percent of the irrigated area is in States east of the western bloc, chiefly in several

Humic substances in ground waters

International Nuclear Information System (INIS)

Paxeus, N.; Allard, B.; Olofsson, U.; Bengtsson, M.

1986-01-01

The presence of naturally occurring complexing agents that may enhance the migration of disposed radionuclikes and thus facilitate their uptake by plantsis a problem associated with the underground disposal of radioactive wastes in bedrock. The main purpose of this work is to characterized humic substances from ground water and compare them with humic substances from surface water. The humic materials isolated from ground waters of a borehole in Fjaellveden (Sweden) were characterized by elemental and functional group analyses. Spectroscopic properties, molecular weight distributions as well as acid-base properties of the fulvic and humic fractions were also studied. The ground water humic substances were found to be quite similar in many respects (but not identical) to the Swedish surface water humics concentrated from the Goeta River but appeared to be quite different from the American ground water humics from Biscayne Florida Aquifer or Laramie Fox-Hills in Colorado. The physico-chemical properties of the isolated humic materials are discussed

Benthic infaunal community structuring in an acidified tropical estuarine system.

Science.gov (United States)

Hossain, M Belal; Marshall, David J

2014-01-01

Recent studies suggest that increasing ocean acidification (OA) should have strong direct and indirect influences on marine invertebrates. While most theory and application for OA is based on relatively physically-stable oceanic ecological systems, less is known about the effects of acidification on nearshore and estuarine systems. Here, we investigated the structuring of a benthic infaunal community in a tropical estuarine system, along a steep salinity and pH gradient, arising largely from acid-sulphate groundwater inflows (Sungai Brunei Estuary, Borneo, July 2011- June 2012). Preliminary data indicate that sediment pore-water salinity (range: 8.07 - 29.6 psu) declined towards the mainland in correspondence with the above-sediment estuarine water salinity (range: 3.58 - 31.2 psu), whereas the pore-water pH (range: 6.47- 7.72) was generally lower and less variable than the estuarine water pH (range: 5.78- 8.3), along the estuary. Of the thirty six species (taxa) recorded, the polychaetes Neanthes sp., Onuphis conchylega, Nereididae sp. and the amphipod Corophiidae sp., were numerically dominant. Calcified microcrustaceans (e.g., Cyclopoida sp. and Corophiidae sp.) were abundant at all stations and there was no clear distinction in distribution pattern along the estuarine between calcified and non-calcified groups. Species richness increased seawards, though abundance (density) showed no distinct directional trend. Diversity indices were generally positively correlated (Spearman's rank correlation) with salinity and pH (p 0.05). Three faunistic assemblages were distinguished: (1) nereid-cyclopoid-sabellid, (2) corophiid-capitellid and (3) onuphid- nereid-capitellid. These respectively associated with lower salinity/pH and a muddy bottom, low salinity/pH and a sandy bottom, and high salinity/pH and a sandy bottom. However, CCA suggested that species distribution and community structuring is more strongly influenced by sediment particle characteristics than by the

Pollutant infiltration and ground water management

International Nuclear Information System (INIS)

1993-01-01

Following a short overview of hazard potentials for ground water in Germany, this book, which was compiled by the technical committee of DVWK on ground water use, discusses the natural scientific bases of pollutant movement to and in ground water. It points out whether and to what extent soil/ground water systems can be protected from harmful influences, and indicates relative strategies. Two zones are distinguished: the unsaturated zone, where local defence and remedial measures are frequently possible, and the saturated zone. From the protective function of geological systems, which is always pollutant-specific, criteria are derived for judging the systems generally, or at least regarding entire classes of pollutants. Finally, the impact of the infiltration of pollutants into ground water on its use as drinking water is pointed out and an estimate of the cost of remedial measures is given. (orig.) [de

Phytoplankton blooms in estuarine and coastal waters: Seasonal patterns and key species

Science.gov (United States)

Carstensen, Jacob; Klais, Riina; Cloern, James E.

2015-01-01

Phytoplankton blooms are dynamic phenomena of great importance to the functioning of estuarine and coastal ecosystems. We analysed a unique (large) collection of phytoplankton monitoring data covering 86 coastal sites distributed over eight regions in North America and Europe, with the aim of investigating common patterns in the seasonal timing and species composition of the blooms. The spring bloom was the most common seasonal pattern across all regions, typically occurring early (February–March) at lower latitudes and later (April–May) at higher latitudes. Bloom frequency, defined as the probability of unusually high biomass, ranged from 5 to 35% between sites and followed no consistent patterns across gradients of latitude, temperature, salinity, water depth, stratification, tidal amplitude or nutrient concentrations. Blooms were mostly dominated by a single species, typically diatoms (58% of the blooms) and dinoflagellates (19%). Diatom-dominated spring blooms were a common feature in most systems, although dinoflagellate spring blooms were also observed in the Baltic Sea. Blooms dominated by chlorophytes and cyanobacteria were only common in low salinity waters and occurred mostly at higher temperatures. Key bloom species across the eight regions included the diatoms Cerataulina pelagica and Dactyliosolen fragilissimus and dinoflagellates Heterocapsa triquetra and Prorocentrum cordatum. Other frequent bloom-forming taxa were diatom genera Chaetoceros, Coscinodiscus, Skeletonema, and Thalassiosira. Our meta-analysis shows that these 86 estuarine-coastal sites function as diatom-producing systems, the timing of that production varies widely, and that bloom frequency is not associated with environmental factors measured in monitoring programs. We end with a perspective on the limitations of conclusions derived from meta-analyses of phytoplankton time series, and the grand challenges remaining to understand the wide range of bloom patterns and

Ground-water monitoring under RCRA

International Nuclear Information System (INIS)

Coalgate, J.

1993-11-01

In developing a regulatory strategy for the disposal of hazardous waste under the Resource Conservation and Recovery Act (RCRA), protection of ground-water resources was the primary goal of the Environmental Protection Agency (EPA). EPA's ground-water protection strategy seeks to minimize the potential for hazardous wastes and hazardous constituents in waste placed in land disposel units to migrate into the environment. This is achieved through liquids management (limiting the placement of liquid wastes in or on the land, requiring the use of liners beneath waste, installing leachate collection systems and run-on and run-off controls, and covering wastes at closure). Ground-water monitoring serves to detect any failure in EPA's liquids management strategy so that ground-water contamination can be detected and addressed as soon as possible

Death Valley regional ground-water flow system, Nevada and California -- hydrogeologic framework and transient ground-water flow model

Science.gov (United States)

Belcher, Wayne R.

2004-01-01

A numerical three-dimensional (3D) transient ground-water flow model of the Death Valley region was developed by the U.S. Geological Survey for the U.S. Department of Energy programs at the Nevada Test Site and at Yucca Mountain, Nevada. Decades of study of aspects of the ground-water flow system and previous less extensive ground-water flow models were incorporated and reevaluated together with new data to provide greater detail for the complex, digital model. A 3D digital hydrogeologic framework model (HFM) was developed from digital elevation models, geologic maps, borehole information, geologic and hydrogeologic cross sections, and other 3D models to represent the geometry of the hydrogeologic units (HGUs). Structural features, such as faults and fractures, that affect ground-water flow also were added. The HFM represents Precambrian and Paleozoic crystalline and sedimentary rocks, Mesozoic sedimentary rocks, Mesozoic to Cenozoic intrusive rocks, Cenozoic volcanic tuffs and lavas, and late Cenozoic sedimentary deposits of the Death Valley Regional Ground-Water Flow System (DVRFS) region in 27 HGUs. Information from a series of investigations was compiled to conceptualize and quantify hydrologic components of the ground-water flow system within the DVRFS model domain and to provide hydraulic-property and head-observation data used in the calibration of the transient-flow model. These studies reevaluated natural ground-water discharge occurring through evapotranspiration and spring flow; the history of ground-water pumping from 1913 through 1998; ground-water recharge simulated as net infiltration; model boundary inflows and outflows based on regional hydraulic gradients and water budgets of surrounding areas; hydraulic conductivity and its relation to depth; and water levels appropriate for regional simulation of prepumped and pumped conditions within the DVRFS model domain. Simulation results appropriate for the regional extent and scale of the model were

Ground-water problems in highway construction and maintenance

Science.gov (United States)

Rasmussen, W.C.; Haigler, L.B.

1953-01-01

This report discusses the occurrence of ground water in relation to certain problems in highway construction and maintenance. These problems are: the subdrainage of roads; quicksand; the arrest of soil creep in road cuts; the construction of lower and larger culverts necessitated by the farm-drainage program; the prevention of failure of bridge abutments and retaining walls; and the water-cement ratio of sub-water-table concrete. Although the highway problems and suggested solutions are of general interest, they are considered with special reference to the State of Delaware, in relation to the geology of that State. The new technique of soil stabilization by electroosmosis is reviewed in the hope that it might find application here in road work and pile setting, field application by the Germans and Russians is reviewed.

Chromatographic determination of nanomolar cyanate concentrations in estuarine and sea waters by precolumn fluorescence derivatization.

Science.gov (United States)

Widner, Brittany; Mulholland, Margaret R; Mopper, Kenneth

2013-07-16

Recent studies suggest that cyanate (OCN(-)) is a potentially important source of reduced nitrogen (N) available to support the growth of aquatic microbes and, thus, may play a role in aquatic N cycling. However, aquatic OCN(-) distributions have not been previously described because of the lack of a suitable assay for measuring OCN(-) concentrations in natural waters. Previous methods were designed to quantify OCN(-) in aqueous samples with much higher reduced N concentrations (micromolar levels) than those likely to be found in natural waters (nanomolar levels). We have developed a method to quantify OCN(-) in dilute, saline environments. In the method described here, OCN(-) in aqueous solution reacts with 2-aminobenzoic acid to produce a highly fluorescent derivative, 2,4-quinazolinedione, which is then quantified using high performance liquid chromatography. Derivatization conditions were optimized to simultaneously minimize the reagent blank and maximize 2,4-quinazolinedione formation (>90% reaction yield) in estuarine and seawater matrices. A limit of detection (LOD) of 0.4 nM was achieved with only minor matrix effects. We applied this method to measure OCN(-) concentrations in estuarine and seawater samples from the Chesapeake Bay and coastal waters from the mid-Atlantic region. OCN(-) concentrations ranged from 0.9 to 41 nM. We determined that OCN(-) concentrations were stable in 0.2 μm filtered seawater samples stored at -80 °C for up to nine months.

Field Evaluation Of Arsenic Transport Across The Ground-Water/Surface Water Interface: Ground-Water Discharge And Iron Oxide Precipitation

Science.gov (United States)

A field investigation was conducted to examine the distribution of arsenic in ground water, surface water, and sediments at a Superfund Site in the northeastern United States (see companion presentation by K. G. Scheckel et al). Ground-water discharge into the study area was cha...

DCERP Defense Coastal/Estuarine Research Program Workshop Proceedings

Science.gov (United States)

2005-02-01

regions (including submerged aquatic vegetation, macroalgae and microalgae) • Estuarine and riverine water column • Beach and dunes • Surf zone...following the activation of the new water treatment plant. Assess upstream and tributary contaminant contributions resulting in eutrophication problems...12 3.2 WATER QUALITY

Defense Coastal/Estuarine Research Program (DCERP)

Science.gov (United States)

2007-09-19

activities, splash points and Landing Craft Air Cushion (LCAC) operations) and non-military Base activities (e.g., sewage treatment , storm water runoff and...We will measure the metabolism of benthic microalgae, the water column, eelgrass, and any dominant macroalgae by developing series of photosynthesis...activities (storm water control and sewage treatment ). Defense Coastal/Estuarine Research Program (DCERP) Research Plan DCERP Research Plan 32 September 19

Comparative study of water reactivity with Mo{sub 2}O{sub y}{sup −} and W{sub 2}O{sub y}{sup −} clusters: A combined experimental and theoretical investigation

Energy Technology Data Exchange (ETDEWEB)

Ray, Manisha; Waller, Sarah E.; Saha, Arjun; Raghavachari, Krishnan; Jarrold, Caroline Chick, E-mail: cjarrold@indiana.edu [Department of Chemistry, Indiana University, Bloomington, Indiana 47405 (United States)

2014-09-14

A computational investigation of the Mo{sub 2}O{sub y}{sup −} + H{sub 2}O (y = 4, 5) reactions as well as a photoelectron spectroscopic probe of the deuterated Mo{sub 2}O{sub 6}D{sub 2}{sup −} product have been carried out to understand a puzzling question from a previous study: Why is the rate constant determined for the Mo{sub 2}O{sub 5}{sup −} + H{sub 2}O/D{sub 2}O reaction, the terminal reaction in the sequential oxidation of Mo{sub 2}O{sub y}{sup −} by water, higher than the W{sub 2}O{sub 5}{sup −} + H{sub 2}O/D{sub 2}O reaction? This disparity was intriguing because W{sub 3}O{sub y}{sup −} clusters were found to be more reactive toward water than their Mo{sub 3}O{sub y}{sup −} analogs. A comparison of molecular structures reveals that the lowest energy structure of Mo{sub 2}O{sub 5}{sup −} provides a less hindered water addition site than the W{sub 2}O{sub 5}{sup −} ground state structure. Several modes of water addition to the most stable molecular and electronic structures of Mo{sub 2}O{sub 4}{sup −} and Mo{sub 2}O{sub 5}{sup −} were explored computationally. The various modes are discussed and compared with previous computational studies on W{sub 2}O{sub y}{sup −} + H{sub 2}O reactions. Calculated free energy reaction profiles show lower barriers for the initial Mo{sub 2}O{sub y}{sup −} + H{sub 2}O addition, consistent with the higher observed rate constant. The terminal Mo{sub 2}O{sub y}{sup −} sequential oxidation product predicted computationally was verified by the anion photoelectron spectrum of Mo{sub 2}O{sub 6}D{sub 2}{sup −}. Based on the computational results, this anion is a trapped dihydroxide intermediate in the Mo{sub 2}O{sub 5}{sup −} + H{sub 2}O/D{sub 2}O → Mo{sub 2}O{sub 6}{sup −} + H{sub 2}/D{sub 2} reaction.

Three-phase solvent bar micro-extraction as an approach to silver ultra-traces speciation in estuarine water samples.

Science.gov (United States)

López-López, José Antonio; Herce-Sesa, Belén; Moreno, Carlos

2015-01-01

Silver ion inputs into the environment due to human activities have been increased in the last years because it has been used as a bactericide with application in medical, homecare and self-care products. In addition, it is toxic at low concentration for aquatic organisms. In estuarine waters, salinity and dissolved organic matter (DOM) regulate Ag(+) concentration by the formation of complexes as AgCln((n-1)-) and Ag-DOM. Difficulties of Ag(+) analysis in estuaries are associated to its low concentration level and interferences of sample matrix. Liquid and solid phase extraction methods have been used for speciation of silver in waters; however, miniaturized methods that offer a better environmental profile are desirable. Hollow fiber liquid phase micro-extraction (HFLPME) allows obtaining higher pre-concentration factors with a reduction of waste generation. Notwithstanding, some operational improvements are needed to permit their use as a routine method that can be afforded using a configuration of three-phase solvent bar micro-extraction (3PSBME). In this work, tri-isobutylphosphine sulphide (TIBPS) has been used as an extractant for Ag(+) pre-concentration in estuarine waters by 3PSBME. Under optimized conditions, Ag(+) has been pre-concentrated 60 times and the method presents a limit of detection of 1.53 ng L(-1). To evaluate which Ag species is transported by TIBPS, Cl(-) and DOM have been added to synthetic samples. As a result, a decrease in Ag pre-concentration efficiency after additions has been observed and quantified. Results showed that Ag(+) is selectively transported by TIBPS from estuarine water samples after comparison of the results with those obtained by the reference method of liquid extraction with APDC/DDDC. Copyright © 2014 Elsevier B.V. All rights reserved.

Focus on CSIR research in water resources: conservation planning for river and estuarine biodiversity in the Fish to Tsitsikamma water management area

CSIR Research Space (South Africa)

Roux, D

2007-08-01

Full Text Available for river and estuarine biodiversity in the Fish- to-Tsitsikamma water management area Project Aims To put in practice and refine, through a pilot study in the Eastern Cape Province, the policy and planning tools developed for systematic conservation... engagement in developing the technical approach to river prioritization and selection, as well as the reviewing of results to facilitate buy-in and ownership of the product. Project Description The Fish to Tsitsikamma Water Management Area is one...

Ground-Water Occurrence and Contribution to Streamflow, Northeast Maui, Hawaii

Science.gov (United States)

Gingerich, Stephen B.

1999-01-01

-elevation saturated zone. Total average daily ground-water discharge from the high-elevation saturated zone upstream of 1,200 feet altitude is greater than 38 million gallons per day, all of which is eventually removed from the streams by surface-water diversion systems. Perennial streamflow has been measured at altitudes greater than 3,000 feet in several of the streams. Discharge from the high-elevation saturated zone is persistent even during periods of little rainfall. The total average annual streamflow of the gaged streams east of Keanae Valley is about 109 million gallons per day at about 1,300 feet altitude. It is not possible to estimate the total average annual streamflow at the coast nor at higher altitudes. All of the base flow measured east of Keanae Valley represents ground-water discharge from the vertically extensive freshwater-lens system. Total average daily ground-water discharge to gaged streams upstream of 1,200 feet altitude is about 27 million gallons per day. About 19 million gallons per day of ground water discharges through the Kula and Hana Volcanics between about 500 feet and 1,300 feet altitude in the gaged stream sub-basins. About 13 million gallons per day of this discharge is in Hanawi Stream. The total ground-water discharge above 500 feet altitude in this part of the study area is greater than 56 million gallons per day.

Magnetic ground state of Ti{sub 1-x}Sc{sub x}Fe{sub 2} system

Energy Technology Data Exchange (ETDEWEB)

Saoudi, M.; Deportes, J.; Ouladdiaf, B. E-mail: ouladdiaf@ill.fr

2001-06-01

The magnetic ground states of the Laves phases Ti{sub 1-x}Sc{sub x}Fe{sub 2} system have been investigated by means of powder neutron diffraction and magnetisation techniques. For x=0.23, a transition is observed from a collinear ferromagnet along the c-axis to a canted one at T{sub f}=200 K. For x=0.27, 0.3, 0.33, an additional first-order transition is observed at T{sub t1}{approx}120 K accompanied by a large magnetovolume anomaly associated to a jump of the magnetic moment of the Fe atoms at the 2a site. The magnetic moment instability in a frustrated lattice should be considered to interpret this transition, although most of the other magnetic states can be discussed within Moriya's theory for itinerant electron systems with competing ferromagnetic and antiferromagnetic spin fluctuations.

Distribution of Fe in waters and bottom sediments of a small estuarine catchment, Pumicestone Region, southeast Queensland, Australia

International Nuclear Information System (INIS)

Liaghati, Tania; Cox, Malcolm E.; Preda, Micaela

2005-01-01

Dissolved and extractable iron concentrations in surface water, groundwater and bottom sediments were determined for Halls Creek, a small subtropical tidally influenced creek. Dissolved iron concentrations were much higher in fresh surface waters and groundwater compared to the estuarine water. In bottom sediments, iron minerals were determined by X-ray diffraction (XRD); of these, hematite (up to 11%) has formed by precipitation from iron-rich water in the freshwater section of the catchment. Pyrite was only identified in the estuarine reach and demonstrated several morphologies [identified by scanning electron microscopy (SEM)] including loosely and closely packed framboids, and the euhedral form. The forms of pyrite found in bottom sediments indicate in situ production and recrystallisation. In surface waters, pyrite was detected in suspended sediment; due to oxygen concentrations well above 50 μmol/l, it was concluded that framboids do not form in the water column, but are within resuspended bottom sediments or eroded from creek banks. The persistence of framboids in suspended sediments, where oxygen levels are relatively high, could be due to their silica and clay-rich coatings, which prevent a rapid oxidation of the pyrite. In addition to identifying processes of formation and transport of pyrite, this study has environmental significance, as this mineral is a potential source of bioavailable forms of iron, which can be a major nutrient supporting algal growth

Evaluation of Marsh/Estuarine Water Quality and Ecological Models: An Interim Guide

Science.gov (United States)

1982-01-01

benthic oxygen demand, benthic scour and deposition, photosynthesis and respiration of aquatic plants, and nitrification (Dobbins 1964; O’Connor 1967... photosynthesis , algal respiration, decom- position, and mixing processes play dominant roles, the understanding and characterization of significant pro...Adams, S. M. 1979. "A Mathematical Model of Trophic Dynamics in Estuarine Seagrass Communities," Marsh-Estuarine Systems Simulation, Dame, R. F., ed

Modeled ground water age distributions

Science.gov (United States)

Woolfenden, Linda R.; Ginn, Timothy R.

2009-01-01

The age of ground water in any given sample is a distributed quantity representing distributed provenance (in space and time) of the water. Conventional analysis of tracers such as unstable isotopes or anthropogenic chemical species gives discrete or binary measures of the presence of water of a given age. Modeled ground water age distributions provide a continuous measure of contributions from different recharge sources to aquifers. A numerical solution of the ground water age equation of Ginn (1999) was tested both on a hypothetical simplified one-dimensional flow system and under real world conditions. Results from these simulations yield the first continuous distributions of ground water age using this model. Complete age distributions as a function of one and two space dimensions were obtained from both numerical experiments. Simulations in the test problem produced mean ages that were consistent with the expected value at the end of the model domain for all dispersivity values tested, although the mean ages for the two highest dispersivity values deviated slightly from the expected value. Mean ages in the dispersionless case also were consistent with the expected mean ages throughout the physical model domain. Simulations under real world conditions for three dispersivity values resulted in decreasing mean age with increasing dispersivity. This likely is a consequence of an edge effect. However, simulations for all three dispersivity values tested were mass balanced and stable demonstrating that the solution of the ground water age equation can provide estimates of water mass density distributions over age under real world conditions.

GoM Coastal and Estuarine Biopsy Surveys

Data.gov (United States)

National Oceanic and Atmospheric Administration, Department of Commerce — Small vessel surveys are conducted within estuarine and nearshore coastal waters to collect tissue biopsy samples from bottlenose dolphins. Visual surveys are...

Ground water pollution through air pollutants

International Nuclear Information System (INIS)

Cichorowski, G.; Michel, B.; Versteegen, D.; Wettmann, R.

1989-01-01

The aim of the investigation is to determine the significance of air pollutants for ground water quality and ground water use. The report summarizes present knowledge and assesses statements with a view to potential ground water pollution from the air. In this context pollution paths, the spreading behaviour of pollutants, and 'cross points' with burden potentials from other pollutant sources are presented. (orig.) [de

An artificial water body provides habitat for an endangered estuarine seahorse species

Science.gov (United States)

Claassens, Louw

2016-10-01

Anthropogenic development, especially the transformation of natural habitats to artificial, is a growing concern within estuaries and coastal areas worldwide. Thesen Islands marina, an artificial water body, added 25 ha of new estuarine habitat to the Knysna Estuary in South Africa, home to the Knysna seahorse. This study aimed to answer: (I) Can an artificial water body provide suitable habitat for an endangered seahorse species? And if so (II) what characteristics of this new habitat are important in terms of seahorse utilization? Four major habitat types were identified within the marina canals: (I) artificial reno mattress (wire baskets filled with rocks); (II) Codium tenue beds; (III) mixed vegetation on sediment; and (IV) barren canal floor. Seahorses were found throughout the marina system with significantly higher densities within the reno mattress habitat. The artificial water body, therefore, has provided suitable habitat for Hippocampus capensis, a noteworthy finding in the current environment of coastal development and the increasing shift from natural to artificial.

Environmental parameters and antimicrobial susceptibility of enterobacteriaceae isolated from estuarine waters of São Vicente, São Paulo state, Brazil

Directory of Open Access Journals (Sweden)

N. G. G. S. Lourenço

2007-01-01

Full Text Available Diseases transmitted by water consists a serious public health problem and enterobacteria are the main group of microorganisms responsible for outbreaks in humans. Such pathogenic bacteria proliferate in water polluted by domestic and industrial sewage and reach the population through seawater contact. The aim of the present work was to study environmental parameters as well as to identify Enterobacteriaceae species and their antimicrobial susceptibility in water samples collected from the estuarine area of São Vicente city (São Paulo State, Brazil. Strains were identified by using traditional biochemical tests described in literature and antimicrobial susceptibility tests were carried out using the disk diffusion method. Out of 26 samples, Escherichia coli was the most frequent species (40.1%, followed by Citrobacter, Enterobacter and Klebsiella. The most effective drugs against the tested microorganisms were gentamycin, netilmicin, ciprofloxacin and cefepime. Since these bacteria are commonly found in seashore contaminated by sewage effluents, it can be concluded that estuarine waters of São Vicente are polluted and potentially capable of causing diseases and spreading pathogenic bacteria to human communities.

Hanford site ground water protection management plan

International Nuclear Information System (INIS)

1994-10-01

Ground water protection at the Hanford Site consists of preventative and remedial measures that are implemented in compliance with a variety of environmental regulations at local, state, and federal levels. These measures seek to ensure that the resource can sustain a broad range of beneficial uses. To effectively coordinate and ensure compliance with applicable regulations, the U.S. Department of Energy has issued DOE Order 5400.1 (DOE 1988a). This order requires all U.S. Department of Energy facilities to prepare separate ground water protection program descriptions and plans. This document describes the Ground Water Protection Management Plan (GPMP) for the Hanford Site located in the state of Washington. DOE Order 5400.1 specifies that the GPMP covers the following general topical areas: (1) documentation of the ground water regime; (2) design and implementation of a ground water monitoring program to support resource management and comply with applicable laws and regulations; (3) a management program for ground water protection and remediation; (4) a summary and identification of areas that may be contaminated with hazardous waste; (5) strategies for controlling hazardous waste sources; (6) a remedial action program; and (7) decontamination, decommissioning, and related remedial action requirements. Many of the above elements are currently covered by existing programs at the Hanford Site; thus, one of the primary purposes of this document is to provide a framework for coordination of existing ground water protection activities. The GPMP provides the ground water protection policy and strategies for ground water protection/management at the Hanford Site, as well as an implementation plan to improve coordination of site ground water activities

Measurement of radon concentration in water by means of {alpha}, {gamma} spectrometry. Radon concentration in ground and spring water in Hiroshima Prefecture

Energy Technology Data Exchange (ETDEWEB)

Shizuma, Kiyoshi [Hiroshima Univ. (Japan)

1997-02-01

Radon ({sup 222}Rn, T{sub 1/2}=3.8235{+-}0.0003d) is {alpha}-ray releasing nuclide, so that it can not be detected by {gamma}-ray measurement. But, the daughter nuclides {sup 214}Pb (T{sub 1/2}=26.8 min) and {sup 214}Bi (T{sub 1/2}=19.9 min) release {gamma}-ray, accordingly they are measured by Ge detector. Their radioactive equilibrium is kept in the closed vessel, because their half-lives are shorter than that of radon. We developed a measurement method of radon concentration by means of {gamma}-spectrometry. We applied this method to catch radon in the atmosphere by active carbon. The same principle can be applied to radon in water. Radon concentrations in the ground water were measured in 22 points in the Higashi-Hiroshima city and 82 points in the Hiroshima prefecture. The efficiencies of {gamma}-ray were determined. The radon concentration showed between 11 and 459 Bq/l and the average was 123 Bq/l. The high concentration of radon was distributed in the spring of granitic layer and higher concentration of radon were observed in the ground water of fault. (S.Y.)

Hanford Site ground-water surveillance for 1989

International Nuclear Information System (INIS)

Evans, J.C.; Bryce, R.W.; Bates, D.J.; Kemner, M.L.

1990-06-01

This annual report of ground-water surveillance activities provides discussions and listings of results for ground-water monitoring at the Hanford Site during 1989. The Pacific Northwest Laboratory (PNL) assesses the impacts of Hanford operations on the environment for the US Department of Energy (DOE). The impact Hanford operations has on ground water is evaluated through the Hanford Site Ground-Water Surveillance program. Five hundred and sixty-seven wells were sampled during 1989 for Hanford ground-water monitoring activities. This report contains a listing of analytical results for calendar year (CY) 1989 for species of importance as potential contaminants. 30 refs., 29 figs,. 4 tabs

Effect of thermal shock on developmental stages of estuarine fish. Final report

International Nuclear Information System (INIS)

Dean, J.M.

1978-12-01

Physiological data and ecological data show that the few estuarine spawners have a higher thermal tolerance in the embryonic and larval stages than do the freshwater, coastal, or oceanic spawning species. However, since all three groups (freshwater, estuarine, and oceanic spawners) occupy the estuary and coastal waters at different times of the year, knowledge of their physiology and ecology at different developmental or life cycle stages is critical for estuarine management decisions

Procedures for ground-water investigations

International Nuclear Information System (INIS)

1992-12-01

This manual was developed by the Pacific Northwest Laboratory (PNL) to document the procedures used to carry out and control the technical aspects of ground-water investigations at the PNL. Ground-water monitoring procedures are developed and used in accordance with the PNL Quality Assurance Program

Ground-water flow and ground- and surface-water interaction at the Weldon Spring quarry, St. Charles County, Missouri

International Nuclear Information System (INIS)

Imes, J.L.; Kleeschulte, M.J.

1997-01-01

Ground-water-level measurements to support remedial actions were made in 37 piezometers and 19 monitoring wells during a 19-month period to assess the potential for ground-water flow from an abandoned quarry to the nearby St. Charles County well field, which withdraws water from the base of the alluvial aquifer. From 1957 to 1966, low-level radioactive waste products from the Weldon Spring chemical plant were placed in the quarry a few hundred feet north of the Missouri River alluvial plain. Uranium-based contaminants subsequently were detected in alluvial ground water south of the quarry. During all but flood conditions, lateral ground-water flow in the bedrock from the quarry, as interpreted from water-table maps, generally is southwest toward Little Femme Osage Creek or south into the alluvial aquifer. After entering the alluvial aquifer, the ground water flows southeast to east toward a ground-water depression presumably produced by pumping at the St. Charles County well field. The depression position varies depending on the Missouri River stage and probably the number and location of active wells in the St. Charles County well field

Particulate organic matter in the coastal and estuarine waters of Goa and its relationship with phytoplankton production

Digital Repository Service at National Institute of Oceanography (India)

Verlecar, X.N.; Qasim, S.Z.

In the coastal and estuarine waters of Goa, particulate organic carbon (POC) varied from 0.52 to 2.51 mg l-1 and from 0.28 to 5.24 mg l-1 and particulate phosphorus (PP) varied from 0.71 to 5.18 mu g l-1 and from 0.78 to 20.34 mu g l-1, respectively...

Hanford Site ground-water monitoring for 1994

International Nuclear Information System (INIS)

Dresel, P.E.; Thorne, P.D.; Luttrell, S.P.

1995-08-01

This report presents the results of the Ground-Water Surveillance Project monitoring for calendar year 1994 on the Hanford Site, Washington. Hanford Site operations from 1943 onward produced large quantities of radiologic and chemical waste that have impacted ground-water quality on the Site. Monitoring of water levels and ground-water chemistry is performed to track the extent of contamination and trends in contaminant concentrations. The 1994 monitoring was also designed to identify emerging ground-water quality problems. The information obtained is used to verify compliance with applicable environmental regulations and to evaluate remedial actions. Data from other monitoring and characterization programs were incorporated to provide an integrated assessment of Site ground-water quality. Additional characterization of the Site's geologic setting and hydrology was performed to support the interpretation of contaminant distributions. Numerical modeling of sitewide ground-water flow also supported the overall project goals. Water-level monitoring was performed to evaluate ground-water flow directions, to track changes in water levels, and to relate such changes to changes in site disposal practices. Water levels over most of the Hanford Site continued to decline between June 1993 and June 1994. These declines are part of the continued response to the cessation of discharge to U Pond and other disposal facilities. The low permeability in this area which enhanced mounding of waste-water discharge has also slowed the response to the reduction of disposal

Hanford Site ground-water monitoring for 1994

Energy Technology Data Exchange (ETDEWEB)

Dresel, P.E.; Thorne, P.D.; Luttrell, S.P. [and others

1995-08-01

This report presents the results of the Ground-Water Surveillance Project monitoring for calendar year 1994 on the Hanford Site, Washington. Hanford Site operations from 1943 onward produced large quantities of radiologic and chemical waste that have impacted ground-water quality on the Site. Monitoring of water levels and ground-water chemistry is performed to track the extent of contamination and trends in contaminant concentrations. The 1994 monitoring was also designed to identify emerging ground-water quality problems. The information obtained is used to verify compliance with applicable environmental regulations and to evaluate remedial actions. Data from other monitoring and characterization programs were incorporated to provide an integrated assessment of Site ground-water quality. Additional characterization of the Site`s geologic setting and hydrology was performed to support the interpretation of contaminant distributions. Numerical modeling of sitewide ground-water flow also supported the overall project goals. Water-level monitoring was performed to evaluate ground-water flow directions, to track changes in water levels, and to relate such changes to changes in site disposal practices. Water levels over most of the Hanford Site continued to decline between June 1993 and June 1994. These declines are part of the continued response to the cessation of discharge to U Pond and other disposal facilities. The low permeability in this area which enhanced mounding of waste-water discharge has also slowed the response to the reduction of disposal.

Extraction Tools for Identification of Chemical Contaminants in Estuarine and Coastal Waters to Determine Toxic Pressure on Primary Producers

NARCIS (Netherlands)

Booij, P; Sjollema, S.B.; Leonards, P.E.G.; de Voogt, P.; Stroomberg, G.J.; Vethaak, A.D.; Lamoree, M.H.

2013-01-01

The extent to which chemical stressors affect primary producers in estuarine and coastal waters is largely unknown. However, given the large number of legacy pollutants and chemicals of emerging concern present in the environment, this is an important and relevant issue that requires further study.

Guide to North Dakota's ground-water resources

Science.gov (United States)

Paulson, Q.F.

1983-01-01

Ground water, the water we pump from the Earth through wells or that which flows naturally from springs, is one of North Dakota's most valuable resources. More than 60 percent of the people living in the State use ground water for one purpose of another. It is the only source of water for thousands of farm families and their livestock. Almost all smaller cities and villages depend solely on groudn water as a source of supply. Increasingly, ground water is being used to irrigate crops and grasslands (fig. 1) during protracted dry spells so common in North Dakota. During recent years there has been a rapid development of rural water ditribution systems in which thousands of farms and rurals residences are connected via underground pipeline to a single water source, usually wells pumping ground water.

Spatial and temporal variability in the otolith chemistry of the Brazilian snapper Lutjanus alexandrei from estuarine and coastal environments.

Science.gov (United States)

Aschenbrenner, A; Ferreira, B P; Rooker, J R

2016-07-01

Otolith chemistry of juvenile and adult individuals of the Brazilian snapper Lutjanus alexandrei was measured to assess the utility of natural markers for investigating individual movements. Individuals were collected over a 3-year period (2010-2012) along the north-eastern coast of Brazil from both estuarine (juvenile to sub-adult stages) and coastal (sub-adult to adult stages) areas. Six elements ((7) Li, (24) Mg, (55) Mn, (59) Co, (88) Sr and (137) Ba) were measured in sectioned otoliths of L. alexandrei using laser ablation inductively coupled plasma mass spectrometry (LA-ICPMS). Edge composition analysis indicated that element:Ca ratios in the otoliths of juvenile and sub-adult L. alexandrei from estuaries were not significantly different among the three consecutive years (2010, 2011 and 2012), suggesting that physicochemical conditions within the nursery area investigated were temporally stable. Similarly, apart from two elements (Ba and Co), element:Ca ratios for larger L. alexandrei inhabiting coastal waters were also similar. In contrast, otolith chemistry of similar sized L. alexandrei from estuarine and coastal areas was significantly different (based on recently accreted material). Otolith Mn:Ca and Ba:Ca were both significantly higher for L. alexandrei collected in estuaries compared to fish from adjacent coastal reefs, while the opposite trend was observed for Sr:Ca. Given the pronounced differences in otolith chemistry between estuarine and coastal areas, element:Ca transects were constructed from the core to margin of the otoliths for adults (age 7+ years) collected on reefs to determine the timing of movement (ontogenetic migration) from estuarine to coastal areas. Based on observed patterns of decline for both Mn:Ca and Ba:Ca, it appears that L. alexandrei begin the move to more coastal habitats (i.e. lower element:Ca ratios) after age 2 years. The patterns observed for this species highlight the importance of conserving connectivity between

Reassessment of Ground-Water Recharge and Simulated Ground-Water Availability for the Hawi Area of North Kohala, Hawaii

Science.gov (United States)

Oki, Delwyn S.

2002-01-01

An estimate of ground-water availability in the Hawi area of north Kohala, Hawaii, is needed to determine whether ground-water resources are adequate to meet future demand within the area and other areas to the south. For the Hawi area, estimated average annual recharge from infiltration of rainfall, fog drip, and irrigation is 37.5 million gallons per day from a daily water budget. Low and high annual recharge estimates for the Hawi area that incorporate estimated uncertainty are 19.9 and 55.4 million gallons per day, respectively. The recharge estimates from this study are lower than the recharge of 68.4 million gallons per day previously estimated from a monthly water budget. Three ground-water models, using the low, intermediate, and high recharge estimates (19.9, 37.5, and 55.4 million gallons per day, respectively), were developed for the Hawi area to simulate ground-water levels and discharges for the 1990?s. To assess potential ground-water availability, the numerical ground-water flow models were used to simulate the response of the freshwater-lens system to withdrawals at rates in excess of the average 1990?s withdrawal rates. Because of uncertainty in the recharge estimate, estimates of ground-water availability also are uncertain. Results from numerical simulations indicate that for appropriate well sites, depths, and withdrawal rates (1) for the low recharge estimate (19.9 million gallons per day) it may be possible to develop an additional 10 million gallons per day of fresh ground water from the Hawi area and maintain a freshwater-lens thickness of 160 feet near the withdrawal sites, (2) for the intermediate recharge estimate (37.5 million gallons per day) it may be possible to develop an additional 15 million gallons per day of fresh ground water from the Hawi area and maintain a freshwater-lens thickness of 190 feet near the withdrawal sites, and (3) for the high recharge estimate (55.4 million gallons per day) it may be possible to develop at

Ecology of Estuarine Macrobenthos

NARCIS (Netherlands)

Herman, P.M.J.; Middelburg, J.J.; Koppel, J. van de; Heip, C.H.R.

1999-01-01

Macrobenthos is an important component of estuarine ecosystems. Based on a cross-system comparison, we show that estuarine macrobenthos may directly process a significant portion of the system-wide primary production, and that estuarine macrobenthic biomass may be predicted from primary production

Ground-Water Hydrology and Projected Effects of Ground-Water Withdrawals in the Sevier Desert, Utah

OpenAIRE

United States Geological Survey

1983-01-01

The principal ground-water reservoir in the Sevier Desert is the unconsolidated basin fill. The fill has been divided generally into aquifers and confining beds, although there are no clearcut boundaries between these units--the primary aquifers are the shallow and deep artesian aquifers. Recharge to the ground-water reservoir is by infiltration of precipitation; seepage from streams, canals, reservoirs, and unconsumed irrigation water; and subsurface inflow from consolidated rocks in mount...

Investigation of ground water aquifer at Tlogorejo Site Karangawen District, Demak Regency, Central Java

International Nuclear Information System (INIS)

Lilik Subiantoro; Priyo Sularto; Slamet Sudarto

2009-01-01

Demak is one of regency are placed at north beach central Java. Some part of this area especially Tlogorejo site Karangawen have the problem of fresh water availability. Conditions of insufficient Standard Water have been recognized in some part of the region, those are Karangrowo area, Undaan District. The problem of clean water in this area is caused by sea water trapped in sedimentary material during sedimentation process, so the trapped ground water character is brine or brackish. One of the alternatives to overcome water problem is election or delineated of the prospect area for exploiting of ground water. Referring to those problems Pusbang Geologi Nuklir BATAN means to conduct investigation of ground water in some location which has problem of clean water. The ground investigation activity is to get information about the geology, hydrogeology and sub surface geophysical characteristic, which is needed to identification of ground water aquifer. To obtain those targets, conducted by topographic measurement in 1:5000 scale maps, measurement of soil radioactivity, geology and hydrogeology mapping, geo-electrical 2-D image measurement Base on observation, analysis, evaluation and discussion was identified the existence of potential confined aquifer that happened at the layer sand that is trapped in the in impermeable layer of clay, which is potential for confined aquifer. Potency of aquifer with the best condition from bad, there are placed on geophysical measurement is ''Sand Aquifer Layer-1'' are located at RB 1 (TLG-5), RB 2 (TLG-4) and RB 3 (TLG-22). Physical characterized of aquifer: resistivity 22-46 Ωm, the depth of surface water 110 to 146 meter. (author)

Arius kesslerl & Sciadeops troschelii (Pisces: Ariidae growth in floating net cages in estuarine waters of Buenventura Bay-Colombia

Directory of Open Access Journals (Sweden)

Efraín Alfonso Rubio

1999-07-01

Full Text Available Two species of estuary catfish the Arius kessleri (CoCoCo and the Sciadeops troschelii (Nato were held in floating net cages at varying densities in estuarine waters of Buenventura Bay-Colombia. After 120 days for the Cococo had weights of 84.1 g Y64 g with densities of 5 and 30 specimen/rn'. The growth average was 0.58-0.39 g/day; the net yield obtained vary from 0.35 to 1.16 Kg/m', the food conversion ratio vary from 3.3 to 5.0 and de survival rate vary from 86% to 100%. With the Nato we obtained weights of 164 and 184 g, beginning with weights of 41 and 108 g their growth average vary from 0.50 to 0.82 g/day. The net yield obtained vary from 0.58 to 0.75 Kg/m' and the survival rate vary from 83% to 100%. From these results we conclude that the two species of catfish studied are strong species but they do not offer good possibilities for fish farming in estuarine waters.

Hanford Site ground-water monitoring for 1993

International Nuclear Information System (INIS)

Dresel, P.E.; Luttrell, S.P.; Evans, J.C.

1994-09-01

This report presents the results of the Ground-Water Surveillance Project monitoring for calendar year 1993 on the Hanford Site, Washington. Hanford Site operations from 1943 onward produced large quantities of radiological and chemical waste that have impacted ground-water quality on the Site. Monitoring of water levels and ground-water chemistry is performed to track the extent of contamination and trends in contaminant concentrations. The 1993 monitoring was also designed to identify emerging ground-water quality problems. The information obtained is used to verify compliance with applicable environmental regulations and to evaluate remedial actions. Data from other monitoring and characterization programs were incorporated to provide an integrated assessment of Site ground-water quality. Additional characterization of the Site's geologic setting and hydrology was performed to support the interpretation of contaminant distributions. Numerical modeling of sitewide ground-water flow also supported the overall project goals. Water-level monitoring was performed to evaluate ground-water flow directions, to track changes in water levels, and to relate such changes to changes in site disposal practices. Water levels over most of the Hanford Site continued to decline between June 1992 and June 1993. The greatest declines occurred in the 200-West Area. These declines are part of the continued response to the cessation of discharge to U Pond and other disposal facilities. The low permeability in this area which enhanced mounding of waste-water discharge has also slowed the response to the reduction of disposal. Water levels remained nearly constant in the vicinity of B Pond, as a result of continued disposal to the pond. Water levels measured from wells in the unconfined aquifer north and east of the Columbia River indicate that the primary source of recharge is irrigation practices

Hanford Site ground-water monitoring for 1993

Energy Technology Data Exchange (ETDEWEB)

Dresel, P.E.; Luttrell, S.P.; Evans, J.C. [and others

1994-09-01

This report presents the results of the Ground-Water Surveillance Project monitoring for calendar year 1993 on the Hanford Site, Washington. Hanford Site operations from 1943 onward produced large quantities of radiological and chemical waste that have impacted ground-water quality on the Site. Monitoring of water levels and ground-water chemistry is performed to track the extent of contamination and trends in contaminant concentrations. The 1993 monitoring was also designed to identify emerging ground-water quality problems. The information obtained is used to verify compliance with applicable environmental regulations and to evaluate remedial actions. Data from other monitoring and characterization programs were incorporated to provide an integrated assessment of Site ground-water quality. Additional characterization of the Site`s geologic setting and hydrology was performed to support the interpretation of contaminant distributions. Numerical modeling of sitewide ground-water flow also supported the overall project goals. Water-level monitoring was performed to evaluate ground-water flow directions, to track changes in water levels, and to relate such changes to changes in site disposal practices. Water levels over most of the Hanford Site continued to decline between June 1992 and June 1993. The greatest declines occurred in the 200-West Area. These declines are part of the continued response to the cessation of discharge to U Pond and other disposal facilities. The low permeability in this area which enhanced mounding of waste-water discharge has also slowed the response to the reduction of disposal. Water levels remained nearly constant in the vicinity of B Pond, as a result of continued disposal to the pond. Water levels measured from wells in the unconfined aquifer north and east of the Columbia River indicate that the primary source of recharge is irrigation practices.

The capability of estuarine sediments to remove nitrogen: implications for drinking water resource in Yangtze Estuary.

Science.gov (United States)

Liu, Lin; Wang, Dongqi; Deng, Huanguang; Li, Yangjie; Chang, Siqi; Wu, Zhanlei; Yu, Lin; Hu, Yujie; Yu, Zhongjie; Chen, Zhenlou

2014-09-01

Water in the Yangtze Estuary is fresh most of the year because of the large discharge of Yangtze River. The Qingcaosha Reservoir built on the Changxing Island in the Yangtze Estuary is an estuarine reservoir for drinking water. Denitrification rate in the top 10 cm sediment of the intertidal marshes and bare mudflat of Yangtze Estuarine islands was measured by the acetylene inhibition method. Annual denitrification rate in the top 10 cm of sediment was 23.1 μmol m(-2) h(-1) in marshes (ranged from 7.5 to 42.1 μmol m(-2) h(-1)) and 15.1 μmol m(-2) h(-1) at the mudflat (ranged from 6.6 to 26.5 μmol m(-2) h(-1)). Annual average denitrification rate is higher at mashes than at mudflat, but without a significant difference (p = 0.084, paired t test.). Taking into account the vegetation and water area of the reservoir, a total 1.42 × 10(8) g N could be converted into nitrogen gas (N2) annually by the sediment, which is 97.7 % of the dissolved inorganic nitrogen input through precipitation. Denitrification in reservoir sediment can control the bioavailable nitrogen level of the water body. At the Yangtze estuary, denitrification primarily took place in the top 4 cm of sediment, and there was no significant spatial or temporal variation of denitrification during the year at the marshes and mudflat, which led to no single factor determining the denitrification process but the combined effects of the environmental factors, hydrologic condition, and wetland vegetation.

The Virginia Beach shallow ground-water study

Science.gov (United States)

Johnson, Henry M.

1999-01-01

IntroductionVirginia Beach is a rapidly growing city of more than 425,000 people. Sources of fresh water within the city, however, are limited. Prior to 1998, the Virginia Beach Public Utilities Department met the city's water needs by purchasing treated drinking water from the City of Norfolk. Because Norfolk had to meet its own requirements, the amount of water available to Virginia Beach was limited to about 30 million gallons per day (mgd) and even less during droughts. This water supply was supplemented with ground water from city-owned, community, and private wells. In many parts of the city, however, ground water cannot be used because of high concentrations of chloride, iron, and (or) sulfur, which give the water an unpleasant taste.In early 1998, a pipeline came on-line that can carry up to 45 mgd of water from Lake Gaston to Virginia Beach. The Gaston pipeline has alleviated concerns about water supply and quality for most residents living north of the "Green Line." These residents primarily use ground water only for small-scale domestic activities such as watering lawns, filling ponds and pools, and washing cars. City water and sewer services have been extended beyond the Green Line into the "Transition Area." Residents and businesses south of the Transition Area, however, continue to rely on ground water to meet most of their needs for potable and non-potable water. To help assure a continued, reliable supply of ground water, the U.S. Geological Survey (USGS), in cooperation with the City of Virginia Beach Public Utilities Department, has begun an assessment of the shallow ground-water resources underlying the City of Virginia Beach.

Effect of river discharge and geometry on tides and net water transport in an estuarine network, an idealized model applied to the Yangtze Estuary

NARCIS (Netherlands)

Alebregtse, N. C.|info:eu-repo/dai/nl/345704304; de Swart, H. E.|info:eu-repo/dai/nl/073449725

2016-01-01

Tidal propagation in, and division of net water transport over different channels in an estuarine network are analyzed using a newly developed idealized model. The water motion in this model is governed by the cross-sectionally averaged shallow water equations and is forced by tides at the seaward

Ground water

International Nuclear Information System (INIS)

Osmond, J.K.; Cowart, J.B.

1992-01-01

The great variations in concentrations and activity ratios of 234 U/ 238 U in ground waters and the features causing elemental and isotopic mobility in the hydrosphere are discussed. Fractionation processes and their application to hydrology and other environmental problems such as earthquake, groundwater and aquifer dating are described. (UK)

Urban stormwater - greywater management system for sustainable urban water management at sub-watershed level

Science.gov (United States)

Singh Arora, Amarpreet

2017-11-01

Urban water management involves urban water supply (import, treatment and distribution of water), urban wastewater management (collection, treatment and disposal of urban sewage) and urban storm water management. Declining groundwater tables, polluted and declining sources of water, water scarcity in urban areas, unsatisfactory urban water supply and sanitation situation, pollution of receiving water bodies (including the ground water), and urban floods have become the concerns and issues of sustainable urban water management. This paper proposes a model for urban stormwater and sewage management which addresses these concerns and issues of sustainable urban water management. This model proposes segregation of the sewage into black water and greywater, and urban sub-watershed level stormwater-greywater management systems. During dry weather this system will be handling only the greywater and making the latter available as reclaimed water for reuse in place of the fresh water supply. During wet weather, the system will be taking care of (collection and treatment) both the storm water and the greywater, and the excess of the treated water will be disposed off through groundwater recharging. Application of this model in the Patiala city, Punjab, INDIA for selected urban sub-watersheds has been tried. Information and background data required for the conceptualization and design of the sub-watershed level urban stormwater-greywater management system was collected and the system has been designed for one of the sub-watersheds in the Patiala city. In this paper, the model for sustainable urban water management and the design of the Sub-watershed level Urban Stormwater-Greywater Management System are described.

Linking soil DOC production rates and transport processes from landscapes to sub-basin scales

Science.gov (United States)

Tian, Y. Q.; Yu, Q.; Li, J.; Ye, C.

2014-12-01

Recent research rejects the traditional perspective that dissolved organic carbon (DOC) component in global carbon cycle are simply trivial, and in fact evidence demonstrates that lakes likely mediate carbon dynamics on a global scale. Riverine and estuarine carbon fluxes play a critical role in transporting and recycling carbon and nutrients, not only within watersheds but in their receiving waters. However, the underlying mechanisms that drive carbon fluxes, from land to rivers, lake and oceans, remain poorly understood. This presentation will report a research result of the scale-dependent DOC production rate in coastal watersheds and DOC transport processes in estuarine regions. We conducted a series of controlled experiments and field measurements for examining biogeochemical, biological, and geospatial variables that regulate downstream processing on global-relevant carbon fluxes. Results showed that increased temperatures and raised soil moistures accelerate decomposition rates of organic matter with significant variations between vegetation types. The measurements at meso-scale ecosystem demonstrated a good correlation to bulk concentration of DOC monitored in receiving waters at the outlets of sub-basins (R2 > 0.65). These field and experimental measurements improved the model of daily carbon exports through below-ground processes as a function of the organic matter content of surface soils, forest litter supply, and temperature. The study demonstrated a potential improvement in modeling the co-variance of CDOM and DOC with the unique terrestrial sources. This improvement indicated a significant promise for monitoring riverine and estuarine carbon flux from satellite images. The technical innovations include deployments of 1) mini-ecosystem (mesocosms) with soil as replicate controlled experiments for DOC production and leaching rates, and 2) aquatic mesocosms for co-variances of DOC and CDOM endmembers, and an instrumented incubation experiment for

Defense Coastal/Estuarine Research Program (DCERP) Strategic Plan

Science.gov (United States)

2007-09-01

availability to phytoplankton in the water column, as well as to benthic microalgae, macroalgae , and seagrasses in bottom waters (Gallegos et al., 2005...further another of MCBCL’s key management objectives for meeting the requirements of the CWA. How wetlands may be utilized for water treatment ...Regulations Appendix B Prioritized list of MCBCL’s conservation and water quality needs Defense Coastal/Estuarine Research Program (DCERP) Strategic

Effects of ocean acidification on single and mixed seagrass species meadows in estuarine waters of the Northern Gulf of Mexico

Science.gov (United States)

In an outdoor mesocosm, we tested the hypothesis that OA would benefit seagrasses in mesohaline waters of the Northern Gulf of Mexico in homo- and hetero- specific seagrass beds of Halodule wrightii and Ruppia maritima. In this estuarine environment, short-term increases in CO2 ...

Binding water to a PEG-linked flexible bichromophore: IR spectra of diphenoxyethane-(H{sub 2}O){sub n} clusters, n = 2-4

Energy Technology Data Exchange (ETDEWEB)

Walsh, Patrick S.; Buchanan, Evan G.; Gord, Joseph R.; Zwier, Timothy S., E-mail: zwier@purdue.edu [Department of Chemistry, Purdue University, 560 Oval Drive, West Lafayette, Indiana 47907-2084 (United States)

2015-04-21

The single-conformation infrared (IR) and ultraviolet (UV) spectroscopies of neutral 1,2-diphenoxyethane-(H{sub 2}O){sub n} clusters with n = 2-4 (labeled henceforth as 1:n) have been studied in a molecular beam using a combination of resonant two-photon ionization, IR-UV holeburning, and resonant ion-dip infrared (RIDIR) spectroscopies. Ground state RIDIR spectra in the OH and CH stretch regions were used to provide firm assignments for the structures of the clusters by comparing the experimental spectra with the predictions of calculations carried out at the density functional M05-2X/6-31+G(d) level of theory. At all sizes in this range, the water molecules form water clusters in which all water molecules engage in a single H-bonded network. Selective binding to the tgt monomer conformer of 1,2-diphenoxyethane (C{sub 6}H{sub 5}-O-CH{sub 2}-CH{sub 2}-O-C{sub 6}H{sub 5}, DPOE) occurs, since this conformer provides a binding pocket in which the two ether oxygens and two phenyl ring π clouds can be involved in stabilizing the water cluster. The 1:2 cluster incorporates a water dimer “chain” bound to DPOE much as it is in the 1:1 complex [E. G. Buchanan et al., J. Phys. Chem. Lett. 4, 1644 (2013)], with primary attachment via a double-donor water that bridges the ether oxygen of one phenoxy group and the π cloud of the other. Two conformers of the 1:3 cluster are observed and characterized, one that extends the water chain to a third molecule (1:3 chain) and the other incorporating a water trimer cycle (1:3 cycle). A cyclic water structure is also observed for the 1:4 cluster. These structural characterizations provide a necessary foundation for studies of the perturbations imposed on the two close-lying S{sub 1}/S{sub 2} excited states of DPOE considered in the adjoining paper [P. S. Walsh et al., J. Chem. Phys. 142, 154304 (2015)].

Estuarine turbidity, flushing, salinity, and circulation

Science.gov (United States)

Pritchard, D. W.

1972-01-01

The effects of estuarine turbidity, flushing, salinity, and circulation on the ecology of the Chesapeake Bay are discussed. The sources of fresh water, the variations in salinity, and the circulation patterns created by temperature and salinity changes are analyzed. The application of remote sensors for long term observation of water temperatures is described. The sources of sediment and the biological effects resulting from increased sediments and siltation are identified.

Modelling of the evolution of ground waters in a granite system at low temperature: the Stripa ground waters, Sweden

International Nuclear Information System (INIS)

Grimaud, D.; Michard, G.; Beaucaire, C.

1990-01-01

From chemical data on the Stripa ground waters we have tried to model the evolution of the chemical composition of a ground water in a granitic system at low temperature. The existence of two end-member ground water compositions made it possible first, to test the conventional model of a geothermal system according to which an overall equilibrium between the waters and a given mineral assemblage can be defined, and then to show that such a model could be extended to low temperatures (10 o C). Conversely, if we know the mineral assemblage, the equilibration temperature and the charge of the mobile ions (in this case, Cl), the composition of the solution is entirely fixed. In our model of the Stripa ground waters, the existence of two end-member ground water compositions can be explained by an evolution from a ''kaolinite-albite-laumontite'' equilibrium to a ''prehnite-albite-laumontite'' equilibrium, the latter requiring less Al than the former. We have also emphasized the importance of the Cl ion concentrations of the ground waters, because they can be considered as indicators of the degree of reaction progress between rock and water, thus determining the degree of equilibration of the system. (author)

Ground water

International Nuclear Information System (INIS)

Osmond, J.K.; Cowart, J.B.

1982-01-01

The subject is discussed under the headings: background and theory (introduction; fractionation in the hydrosphere; mobility factors; radioisotope evolution and aquifer classification; aquifer disequilibria and geochemical fronts); case studies (introduction; (a) conservative, and (b) non-conservative, behaviour); ground water dating applications (general requirements; radon and helium; radium isotopes; uranium isotopes). (U.K.)

Needs Assessment for the Use of NASA Remote Sensing Data in the Development and Implementation of Estuarine and Coastal Water Quality Standards

Science.gov (United States)

Spiering, Bruce; Underwood, Lauren; Ellis, Chris; Lehrter, John; Hagy, Jim; Schaeffer, Blake

2010-01-01

The goals of the project are to provide information from satellite remote sensing to support numeric nutrient criteria development and to determine data processing methods and data quality requirements to support nutrient criteria development and implementation. The approach is to identify water quality indicators that are used by decision makers to assess water quality and that are related to optical properties of the water; to develop remotely sensed data products based on algorithms relating remote sensing imagery to field-based observations of indicator values; to develop methods to assess estuarine water quality, including trends, spatial and temporal variability, and seasonality; and to develop tools to assist in the development and implementation of estuarine and coastal nutrient criteria. Additional slides present process, criteria development, typical data sources and analyses for criteria process, the power of remote sensing data for the process, examples from Pensacola Bay, spatial and temporal variability, pixel matchups, remote sensing validation, remote sensing in coastal waters, requirements for remotely sensed data products, and needs assessment. An additional presentation examines group engagement and information collection. Topics include needs assessment purpose and objectives, understanding water quality decision making, determining information requirements, and next steps.

Ground water currents: Developments in innovative ground water treatment, March 1994

Energy Technology Data Exchange (ETDEWEB)

Eilers, R.

1994-03-01

;Contents: Hydrodynamic cavitation oxidation destroys organics; Biosparging documented in fuel remediation study; Surfactant flushing research to remove organic liquids from aquifers; and Compilation of Ground-Water Models (a book review).

Minimal incorporation of Deepwater Horizon oil by estuarine filter feeders

International Nuclear Information System (INIS)

Fry, Brian; Anderson, Laurie C.

2014-01-01

Highlights: • Oil from the Deepwater Horizon oil spill entered Louisiana bays in mid-2010. • Oil was used minimally (<1%) in diets of mussels and barnacles. • Also, oil did not enhance planktonic respiration rates. • Use of oil carbon was relatively small in these productive estuarine food webs. - Abstract: Natural abundance carbon isotope analyses are sensitive tracers for fates and use of oil in aquatic environments. Use of oil carbon in estuarine food webs should lead to isotope values approaching those of oil itself, −27‰ for stable carbon isotopes reflecting oil origins and −1000‰ for carbon-14 reflecting oil age. To test for transfer of oil from the 2010 Deepwater Horizon spill into estuarine food webs, filter-feeding barnacles (Balanus sp.) and marsh mussels (Geukensia demissa) were collected from Louisiana estuaries near the site of the oil spill. Carbon-14 analyses of these animals from open waters and oiled marshes showed that oil use was <1% and near detection limits estimated at 0.3% oil incorporation. Respiration studies showed no evidence for enhanced microbial activity in bay waters. Results are consistent with low dietary impacts of oil for filter feeders and little overall impact on respiration in the productive Louisiana estuarine systems

Competing ground states in LuFe{sub 4}Ge{sub 2} tuned by external pressure

Energy Technology Data Exchange (ETDEWEB)

Ajeesh, Mukkattu Omanakuttan; Weber, Katharina; Reis, Ricardo dos; Geibel, Christoph; Nicklas, Michael [Max Planck Institute for Chemical Physics of Solids, Dresden (Germany)

2016-07-01

Tuning competing ground-state properties using external pressure has attracted much attention in current condensed matter research. This is due to the fact that exotic phenomena and unconventional phases occur in regions of competing energy scales. Here, we present an investigation on LuFe{sub 4}Ge{sub 2} by electrical resistivity experiments under external pressure in order to understand the interplay between competing ground states in a frustrated, itinerant magnetic system. At ambient pressure LuFe{sub 4}Ge{sub 2} orders antiferromagnetically below 32 K. The antiferromagnetic (AFM) transition is connected with a structural transition. We have established the temperature - pressure phase diagram: pressure suppresses the original antiferromagnetically ordered state to zero temperature at around 1.7 GPa. Upon further increasing pressure a new pressure-induced phase emerges. This phase exhibits a qualitatively different magnetoresistance compared with the AFM phase suggesting a different type of ordering than at lower pressures. Furthermore, above 1.5 GPa we find a metamagnetic transition at higher magnetic fields. The onset of this phase shifts to lower fields with increasing pressure. Further studies to understand the nature of the new phases are on the way.

Technology Transfer Opportunities: Automated Ground-Water Monitoring

Science.gov (United States)

Smith, Kirk P.; Granato, Gregory E.

1997-01-01

Introduction A new automated ground-water monitoring system developed by the U.S. Geological Survey (USGS) measures and records values of selected water-quality properties and constituents using protocols approved for manual sampling. Prototypes using the automated process have demonstrated the ability to increase the quantity and quality of data collected and have shown the potential for reducing labor and material costs for ground-water quality data collection. Automation of water-quality monitoring systems in the field, in laboratories, and in industry have increased data density and utility while reducing operating costs. Uses for an automated ground-water monitoring system include, (but are not limited to) monitoring ground-water quality for research, monitoring known or potential contaminant sites, such as near landfills, underground storage tanks, or other facilities where potential contaminants are stored, and as an early warning system monitoring groundwater quality near public water-supply wells.

Ground-Water Protection and Monitoring Program

Energy Technology Data Exchange (ETDEWEB)

Dresel, P.E.

1995-06-01

This section of the 1994 Hanford Site Environmental Report summarizes the ground-water protection and monitoring program strategy for the Hanford Site in 1994. Two of the key elements of this strategy are to (1) protect the unconfined aquifer from further contamination, and (2) conduct a monitoring program to provide early warning when contamination of ground water does occur. The monitoring program at Hanford is designed to document the distribution and movement of existing ground-water contamination and provides a historical baseline for evaluating current and future risk from exposure to the contamination and for deciding on remedial action options.

Ground-Water Protection and Monitoring Program

International Nuclear Information System (INIS)

Dresel, P.E.

1995-01-01

This section of the 1994 Hanford Site Environmental Report summarizes the ground-water protection and monitoring program strategy for the Hanford Site in 1994. Two of the key elements of this strategy are to (1) protect the unconfined aquifer from further contamination, and (2) conduct a monitoring program to provide early warning when contamination of ground water does occur. The monitoring program at Hanford is designed to document the distribution and movement of existing ground-water contamination and provides a historical baseline for evaluating current and future risk from exposure to the contamination and for deciding on remedial action options

Structural instability and ground state of the U{sub 2}Mo compound

Energy Technology Data Exchange (ETDEWEB)

Losada, E.L., E-mail: losada@cab.cnea.gov.ar [SIM" 3, Centro Atómico Bariloche, Comisión Nacional de Energía Atómica (Argentina); Garcés, J.E. [Gerencia de Investigación y Aplicaciones Nucleares, Comisión Nacional de Energía Atómica (Argentina)

2015-11-15

This work reports on the structural instability at T = 0 °K of the U{sub 2}Mo compound in the C11{sub b} structure under the distortion related to the C{sub 66} elastic constant. The electronic properties of U{sub 2}Mo such as density of states (DOS), bands and Fermi surface (FS) are studied to understand the source of the instability. The C11{sub b} structure can be interpreted as formed by parallel linear chains along the z-directions each one composed of successive U–Mo–U blocks. Hybridization due to electronic interactions inside the U–Mo–U blocks is slightly modified under the D{sub 6} distortion. The change in distance between chains modifies the U–U interaction and produces a split of f-states. The distorted structure is stabilized by a decrease in energy of the hybridized states, mainly between d-Mo and f-U states, together with the f-band split. Consequently, an induced Peierls distortion is produced in U{sub 2}Mo due to the D{sub 6} distortion. It is important to note that the results of this work indicate that the structure of the ground state of the U{sub 2}Mo compound is not the assumed C11{sub b} structure. It is suggested for the ground state a structure with hexagonal symmetry (P6 #168), ∼0.1 mRy below the energy of the recently proposed Pmmn structure. - Highlights: • Structural instability of the C11b compound due to the D6 deformation. • Induced Peierls distortion due to the D6 deformation. • Distorted structure is stabilized by hybridization and split of f-Uranium state. • P6 (#168) suggested ground state for the U{sub 2}Mo compound.

Comparison of the different methods for the recovery of suspended matter from estuarine waters: deposition, filtration and centrifugation

Energy Technology Data Exchange (ETDEWEB)

Etcheber, H; Jouanneau, J M

1980-12-01

The advantages and disadvantages of three methods used to recover heavy metals from estuarine waters are compared. Deposition, filtration, and centrifugation were used on samples from the Gironde estuary of France. Recovery by deposition is satisfactory in cases of flocculation and high turbidity. Centrifugation is reliable for the determination of several elements in zones of low turbidity. (12 references, 4 tables)

Water quality data collected by the the National Estuarine Research Reserve System's System-wide Monitoring Program (NERRS SWMP), 1996 - 1998 (NODC Accession 0000789)

Data.gov (United States)

National Oceanic and Atmospheric Administration, Department of Commerce — The National Estuarine Research Reserve System's System-wide Monitoring Program (NERRS SWMP) collected water quality data in 22 reserves in the United States and...

Tributyltin-resistant bacteria from estuarine and freshwater sediments.

Science.gov (United States)

Wuertz, S; Miller, C E; Pfister, R M; Cooney, J J

1991-01-01

Resistance to tributyltin (TBT) was examined in populations from TBT-polluted sediments and nonpolluted sediments from an estuary and from fresh water as well as in pure cultures isolated from those sediments. The 50% effective concentrations (EC50s) for populations were higher at a TBT-polluted freshwater site than at a site without TBT, suggesting that TBT selected for a TBT-resistant population. In contrast, EC50s were significantly lower for populations from a TBT-contaminated estuarine site than for those from a site without TBT, suggesting that other factors in addition to TBT determine whether populations become resistant. EC50s for populations from TBT-contaminated freshwater sediments were nearly 30 times higher than those for populations from TBT-contaminated estuarine sediments. We defined a TBT-resistant bacterium as one which grows on trypticase soy agar containing 8.4 microM TBT, a concentration which prevented the growth of 90% of the culturable bacteria from these sediments. The toxicity of TBT in laboratory media was influenced markedly by the composition of the medium and whether it was liquid or solid. Ten TBT-resistant isolates from estuarine sediments and 19 from freshwater sediments were identified to the genus level. Two isolates, each a Bacillus sp., may be the first gram-positive bacteria isolated from fresh water in the presence of a high concentration of TBT. There was a high incidence of resistance to heavy metals: metal resistance indices were 0.76 for estuarine isolates and 0.68 for freshwater isolates.(ABSTRACT TRUNCATED AT 250 WORDS) PMID:1746939

Ground-water conditions in Utah, spring of 1995

Science.gov (United States)

Allen, D.V.; Steiger, J.I.; Sory, J.D.; Garrett, R.B.; Burden, Carole B.; Danner, M.R.; Herbert, L.R.; Gerner, S.J.; Slaugh, B.A.; Swenson, R.L.; Howells, J.H.; Christiansen, H.K.; Bagley, A.D.

1995-01-01

This is the thirty-second in a series of annual reports that describe ground-water conditions in Utah. Reports in this series, published cooperatively by the U.S. Geological Survey and the Utah Department of Natural Resources, Division of Water Resources, provide data to enable interested parties to keep abreast of changing ground-water conditions.This report, like the others in the series, contains information on well construction, ground-water withdrawal from wells, water-level changes, related changes in precipitation and streamflow, and chemical quality of water. Supplementary data, such as maps showing water-level contours, are included in reports of this series only for those years or areas for which applicable data are available and are important to a discussion of changing ground-water conditions.This report includes individual discussions of selected significant areas of ground-water development in the State for calendar year 1994. Much of the reported data were collected by the U.S. Geological Survey in cooperation with the Utah Department of Natural Resources, Divisions of Water Rights and Water Resources.

Measuring CO <sub>2sub> and N <sub>2sub> O Mass Transfer into GAP-1 CO <sub>2sub> –Capture Solvents at Varied Water Loadings

Energy Technology Data Exchange (ETDEWEB)

Whyatt, Greg A.; Zwoster, Andy; Zheng, Feng; Perry, Robert J.; Wood, Benjamin R.; Spiry, Irina; Freeman, Charles J.; Heldebrant, David J.

2017-04-12

This paper investigates the CO<sub>2sub> and N<sub>2sub> O absorption behavior in the water-lean gamma amino propyl (GAP)-1/TEG solvent system using a wetted-wall contactor. Testing was performed on a blend of GAP-1 aminosilicone in triethylene glycol at varied water loadings in the solvent. Measurements were made with CO<sub>2sub> and N<sub>2sub> O at representative lean (0.04 mol CO<sub>2sub>/mol alkalinity), middle (0.13 mol CO<sub>2sub> /mol alkalinity) and rich (0.46 mol CO<sub>2sub> /mol alkalinity) solvent loadings at 0, 5, 10 and 15 wt% water loadings at 40, 60 and 80C° and N<sub>2sub> O at (0.08-0.09 mol CO<sub>2sub> /mol alkalinity) at 5 wt% water at 40, 60 and 80C°. CO<sub>2sub> flux was found to be non-linear with respect to log mean pressure driving force (LMPD). Liquid-film mass transfer coefficients (k'g) were calculated by subtracting the gas film resistance (determined from a correlation from literature) from the overall mass transfer measurement. The resulting k'g values for CO<sub>2sub> and N<sub>2sub> O in GAP-1/TEG mixtures were found to be higher than that of 5M aqueous monoethanolamine under comparable driving force albeit at higher solvent viscosities. The k'g values for CO<sub>2sub> were also found to decrease with increasing solvent water content and increase with a decrease in temperature. These observations indicate that mass transfer of CO<sub>2sub> in GAP-1/TEG is linked to the physical solubility of CO<sub>2sub> , which is higher in organic solvents compared to water. This paper expands on the understanding of the unique mass transfer behavior and kinetics of CO<sub>2sub> capture in water-lean solvents.

Basin scale management of surface and ground water

International Nuclear Information System (INIS)

Tracy, J.C.; Al-Sharif, M.

1993-01-01

An important element in the economic development of many regions of the Great Plains is the availability of a reliable water supply. Due to the highly variable nature of the climate through out much of the Great Plains region, non-controlled stream flow rates tend to be highly variable from year to year. Thus, the primary water supply has tended towards developing ground water aquifers. However, in regions where shallow ground water is extracted for use, there exists the potential for over drafting aquifers to the point of depleting hydraulically connected stream flows, which could adversely affect the water supply of downstream users. To prevent the potential conflict that can arise when a basin's water supply is being developed or to control the water extractions within a developed basin requires the ability to predict the effect that water extractions in one region will have on water extractions from either surface or ground water supplies else where in the basin. This requires the ability to simulate ground water levels and stream flows on a basin scale as affected by changes in water use, land use practices and climatic changes within the basin. The outline for such a basin scale surface water-ground water model has been presented in Tracy (1991) and Tracy and Koelliker (1992), and the outline for the mathematical programming statement to aid in determining the optimal allocation of water on a basin scale has been presented in Tracy and Al-Sharif (1992). This previous work has been combined into a computer based model with graphical output referred to as the LINOSA model and was developed as a decision support system for basin managers. This paper will present the application of the LINOSA surface-ground water management model to the Rattlesnake watershed basin that resides within Ground Water Management District Number 5 in south central Kansas

A Guide for Using the Transient Ground-Water Flow Model of the Death Valley Regional Ground-Water Flow System, Nevada and California

Energy Technology Data Exchange (ETDEWEB)

Joan B. Blainey; Claudia C. Faunt, and Mary C. Hill

2006-05-16

This report is a guide for executing numerical simulations with the transient ground-water flow model of the Death Valley regional ground-water flow system, Nevada and California using the U.S. Geological Survey modular finite-difference ground-water flow model, MODFLOW-2000. Model inputs, including observations of hydraulic head, discharge, and boundary flows, are summarized. Modification of the DVRFS transient ground-water model is discussed for two common uses of the Death Valley regional ground-water flow system model: predictive pumping scenarios that extend beyond the end of the model simulation period (1998), and model simulations with only steady-state conditions.

Ground-water conditions in Utah, spring of 1994

Science.gov (United States)

Allen, D.V.; Garrett, R.B.; Sory, J.D.; Burden, Carole B.; Danner, M.R.; Herbert, L.R.; Steiger, J.I.; ReMillard, M.D.; Slaugh, B.A.; Swenson, R.L.; Howells, J.H.; Christiansen, H.K.; Bagley, A.D.

1994-01-01

This is the thirty-first in a series of annual reports that describe ground-water conditions in Utah. Reports in this series, published cooperatively by the U.S. Geological Survey and the Utah Division of Water Resources, provide data to enable interested parties to keep abreast of changing ground-water conditions.This report, like the others in the series, contains information on well construction, ground-water withdrawal from wells, water-level changes, related changes in precipitation and streamflow, and chemical quality of water. Supplementary data, such as maps showing water-level contours, are included in reports of this series only for those years or areas for which applicable data are available and are important to a discussion of changing ground-water conditions.This report includes individual discussions of selected significant areas of ground-water development in the State for calendar year 1993. Water-level fluctuations and selected related data, however, are described from the spring of 1989 to the spring of 1994. Much of the data used in this report were collected by the U.S. Geological Survey in cooperation with the Divisions of Water Rights and Water Resources, Utah Department of Natural Resources.

Hanford Site ground-water monitoring for 1990

International Nuclear Information System (INIS)

Evans, J.C.; Bryce, R.W.; Bates, D.J.

1992-06-01

The Pacific Northwest Laboratory monitors ground-water quality across the Hanford Site for the US Department of Energy (DOE) to assess the impact of Site operations on the environment. Monitoring activities were conducted to determine the distribution of mobile radionuclides and identify chemicals present in ground water as a result of Site operations and whenever possible, relate the distribution of these constituents to Site operations. To comply with the Resource Conservation and Recovery Act, additional monitoring was conducted at individual waste sites by the Site Operating Contractor, Westinghouse Hanford Company (WHC), to assess the impact that specific facilities have had on ground-water quality. Six hundred and twenty-nine wells were sampled during 1990 by all Hanford ground-water monitoring activities

Diffusion Monte Carlo studies of MB-pol (H{sub 2}O){sub 2−6} and (D{sub 2}O){sub 2−6} clusters: Structures and binding energies

Energy Technology Data Exchange (ETDEWEB)

Mallory, Joel D.; Mandelshtam, Vladimir A. [Department of Chemistry, University of California, Irvine, California 92697 (United States)

2016-08-14

We employ the diffusion Monte Carlo (DMC) method in conjunction with the recently developed, ab initio-based MB-pol potential energy surface to characterize the ground states of small (H{sub 2}O){sub 2−6} clusters and their deuterated isotopomers. Observables, other than the ground state energies, are computed using the descendant weighting approach. Among those are various spatial correlation functions and relative isomer fractions. Interestingly, the ground states of all clusters considered in this study, except for the dimer, are delocalized over at least two conformations that differ by the orientation of one or more water monomers with the relative isomer populations being sensitive to the isotope substitution. Most remarkably, the ground state of the (H{sub 2}O){sub 6} hexamer is represented by four distinct cage structures, while that of (D{sub 2}O){sub 6} is dominated by the prism, i.e., the global minimum geometry, with a very small contribution from a prism-book geometry. In addition, for (H{sub 2}O){sub 6} and (D{sub 2}O){sub 6}, we performed DMC calculations to compute the ground states constrained to the cage and prism geometries. These calculations compared results for three different potentials, MB-pol, TTM3/F, and q-TIP4P/F.

Applications of MODIS Fluorescence Line Height Measurements to Monitor Water Quality Trends and Algal Bloom Activity in Coastal and Estuarine Waters

Science.gov (United States)

Fischer, A.; Ryan, J. P.; Moreno-Madriñán, M. J.

2012-12-01

Recent advances in satellite and airborne remote sensing, such as improvements in sensor and algorithm calibrations and atmospheric correction procedures have provided for increased coverage of remote-sensing, ocean color products for coastal regions. In particular, for the Moderate Resolution Imaging Spectrometer (MODIS), calibration updates, improved aerosol retrievals, and new aerosol models have led to improved atmospheric correction algorithms for turbid waters and have improved the retrieval of ocean-color. This has opened the way for studying coastal ocean phenomena and processes at finer spatial scales. Human population growth and changes in coastal management practices have brought about significant changes in the concentrations of organic and inorganic, particulate and dissolved substances entering the coastal ocean. There is increasing concern that these inputs have led to declines in water quality and increases in local concentrations of phytoplankton, which could result in harmful algal blooms. In two case studies we present improved and validated MODIS coastal observations of fluorescence line height (FLH) to: (1) assess trends in water quality for Tampa Bay, Florida; and (2) illustrate seasonal and annual variability of algal bloom activity in Monterey Bay, California, as well as document estuarine/riverine plume induced red tide events. In a comprehensive analysis of long term (2003-2011) in situ monitoring data and imagery from Tampa Bay, we assess the validity of the MODIS FLH product against chlorophyll-a and a suite of water quality parameters taken in a variety of conditions throughout this large, optically complex estuarine system. A systematic analysis of sampling sites throughout the bay illustrates that the correlations between FLH and in situ chlorophyll-a are influenced by water quality parameters of total nitrogen, total phosphorous, turbidity and biological oxygen demand. Sites that correlated well with satellite imagery were in depths

Shrimp farming in estuarine environment: Points to ponder

Digital Repository Service at National Institute of Oceanography (India)

Achuthankutty, C.T.

of the expansion has taken place around the estuarine area as it facilitates water exchange and waste disposal. In semi-intensive and extensive type of farming practices, use of different types of chemicals and antibiotics, artificial feeds, probiotics...

The role of SiO{sub 2} nanoparticles and ground granulated blast furnace slag admixtures on physical, thermal and mechanical properties of self compacting concrete

Energy Technology Data Exchange (ETDEWEB)

Nazari, Ali, E-mail: alinazari84@aut.ac.ir [Department of Technical and Engineering Sciences, Islamic Azad University (Saveh Branch), Felestin Sq., Saveh (Iran, Islamic Republic of); Riahi, Shadi [Department of Technical and Engineering Sciences, Islamic Azad University (Saveh Branch), Felestin Sq., Saveh (Iran, Islamic Republic of)

2011-02-25

Research highlights: {yields} Nanoparticles in concrete. {yields} Ground granulated blast furnace slag as concrete's binder. {yields} Mechanical properties of concrete specimens by non-traditional admixtures. - Abstract: In this work, strength assessments and percentage of water absorption of self compacting concrete containing ground granulated blast furnace slag and SiO{sub 2} nanoparticles as binder have been investigated. Portland cement was replaced by different amounts of ground granulated blast furnace slag and the properties of concrete specimens were investigated. Although it negatively impacts the physical and mechanical properties of concrete at early ages of curing, ground granulated blast furnace slag was found to improve the physical and mechanical properties of concrete up to 45 wt% at later ages. SiO{sub 2} nanoparticles with the average particle size of 15 nm were added partially to concrete with the optimum content of ground granulated blast furnace slag and physical and mechanical properties of the specimens were measured. SiO{sub 2} nanoparticle as a partial replacement of cement up to 3.0 wt% could accelerate C-S-H gel formation as a result of increased crystalline Ca(OH){sub 2} amount at the early ages and hence increase strength and improve the resistance to water permeability of concrete specimens. The increased SiO{sub 2} nanoparticles' content by more than 3.0 wt%, causes the reduced strength because of the decreased crystalline Ca(OH){sub 2} content required for C-S-H gel formation. Several empirical relationships have been presented to predict flexural and split tensile strength of the specimens by means of the corresponding compressive strength at a certain age of curing. Accelerated peak appearance in conduction calorimetry tests, more weight loss in thermogravimetric analysis and more rapid appearance of the peaks related to hydrated products in X-ray diffraction results, all indicate that SiO{sub 2} nanoparticles could

Predictive capabilities of a two-dimensional model in the ground water transport of radionuclides

International Nuclear Information System (INIS)

Gureghian, A.B.; Beskid, N.J.; Marmer, G.J.

1978-01-01

The discharge of low-level radioactive waste into tailings ponds is a potential source of ground water contamination. The estimation of the radiological hazards related to the ground water transport of radionuclides from tailings retention systems depends on reasonably accurate estimates of the movement of both water and solute. A two-dimensional mathematical model having predictive capability for ground water flow and solute transport has been developed. The flow equation has been solved under steady-state conditions and the mass transport equation under transient conditions. The simultaneous solution of both equations is achieved through the finite element technique using isoparametric elements, based on the Galerkin formulation. However, in contrast to the flow equation solution, the weighting functions used in the solution of the mass transport equation have a non-symmetric form. The predictive capability of the model is demonstrated using an idealized case based on analyses of field data obtained from the sites of operating uranium mills. The pH of the solution, which regulates the variation of the distribution coefficient (K/sub d/) in a particular site, appears to be the most important factor in the assessment of the rate of migration of the elements considered herein

Alternatives for ground water cleanup

National Research Council Canada - National Science Library

National Research Council Staff; Commission on Geosciences, Environment and Resources; Division on Earth and Life Studies; National Research Council; National Academy of Sciences

.... Yet recent studies question whether existing technologies can restore contaminated ground water to drinking water standards, which is the goal for most sites and the result expected by the public...

Ground-water monitoring and modeling at the Hanford Site

International Nuclear Information System (INIS)

Mitchell, P.J.; Freshley, M.D.

1987-01-01

The ground-water monitoring program at the Hanford Site in southeastern Washington State is continually evolving in response to changing operations at the site, changes in the ground-water flow system, movement of the constituents in the aquifers, and regulatory requirements. Sampling and analysis of ground water, along with ground-water flow and solute transport modeling are used to evaluate the movement and resulting distributions of radionuclides and hazardous chemical constituents in the unconfined aquifer. Evaluation of monitoring results, modeling, and information on waste management practices are being combined to continually improve the network of ground-water monitoring wells at the site

Ground-water monitoring and modeling at the Hanford Site

International Nuclear Information System (INIS)

Mitchell, P.J.; Freshley, M.D.

1987-01-01

The ground-water monitoring program at the Hanford Site in southeastern Washington State is continually evolving in response to changing operations at the site, changes in the ground-water flow system, movement of the constituents in the aquifers, and regulatory requirements. Sampling and analysis of ground water, along with ground-water flow and solute transport modeling are used ito evaluate the movement and resulting distributions of radionuclides and hazardous chemical constituents in the unconfined aquifer. Evaluation of monitoring results, modeling, and information on waste management practices are being combined to continually improve the network of ground-water monitoring wells at the site

Ground-water temperature of the Wyoming quadrangle in central Delaware : with application to ground-water-source heat pumps

Science.gov (United States)

Hodges, Arthur L.

1982-01-01

Ground-water temperature was measured during a one-year period (1980-81) in 20 wells in the Wyoming Quadrangle in central Delaware. Data from thermistors set at fixed depths in two wells were collected twice each week, and vertical temperature profiles of the remaining 18 wells were made monthly. Ground-water temperature at 8 feet below land surface in well Jc55-1 ranged from 45.0 degrees F in February to 70.1 degrees F in September. Temperature at 35 feet below land surface in the same well reached a minimum of 56.0 degrees F in August, and a maximum of 57.8 degrees F in February. Average annual temperature of ground water at 25 feet below land surface in all wells ranged from 54.6 degrees F to 57.8 degrees F. Variations of average temperature probably reflect the presence or absence of forestation in the recharge areas of the wells. Ground-water-source heat pumps supplied with water from wells 30 or more feet below land surface will operate more efficiently in both heating and cooling modes than those supplied with water from shallower depths. (USGS)

Short-time variations of the ground water level

International Nuclear Information System (INIS)

Nilsson, Lars Y.

1977-09-01

Investigations have demonstrated that the ground water level of aquifers in the Swedish bedrock shows shorttime variations without changing their water content. The ground water level is among other things affected by regular tidal movements occuring in the ''solid'' crust of the earth variations in the atmospheric pressure strong earthquakes occuring in different parts of the world These effects proves that the system of fissures in the bedrock are not stable and that the ground water flow is influenced by both water- and airfilled fissures

40 CFR 257.3-4 - Ground water.

Science.gov (United States)

2010-07-01

... 40 Protection of Environment 24 2010-07-01 2010-07-01 false Ground water. 257.3-4 Section 257.3-4... and Practices § 257.3-4 Ground water. (a) A facility or practice shall not contaminate an underground drinking water source beyond the solid waste boundary or beyond an alternative boundary specified in...

Ground-water protection activities of the US Nuclear Regulatory Commission

International Nuclear Information System (INIS)

1987-02-01

This report evaluates the internal consistency of NRC's ground-water protection programs. These programs have evolved consistently with growing public concerns about the significance of ground-water contamination and environmental impacts. Early NRC programs provided for protection of the public health and safety by minimizing releases of radionuclides. More recent programs have included provisions for minimizing releases of nonradiological constituents, mitigating environmental impacts, and correcting ground-water contamination. NRC's ground-water protection programs are categorized according to program areas, including nuclear materials and waste management (NMSS), nuclear reactor operation (NRR), confirmatory research and standards development (RES), inspection and enforcement (IE), and agreement state programs (SP). Based on analysis of existing ground-water protection programs within NRC, the interoffice Ground-water Protection Group has identified several inconsistencies between and within program areas. These inconsistencies include: (1) different definitions of the term ''ground-water,'' (2) variable regulation of nonradiological constituents in ground water, (3) different design periods for ground-water protection, and (4) different scopes and rigor of ground-water assessments. The second inconsistency stems from differences in statutory authority granted to the NRC. The third inconsistency is rationalized by recognizing differences in perceived risks associated with nuclear facilities. The Ground-water Protection Group will document its analysis of the remaining inconsistencies and make recommendations to reconcile or eliminate them in a subsequent report

Seasonal dynamics of the genus: Planktoniella Schutt in the estuarine waters of Indian Sundarbans.

Science.gov (United States)

Sekh, Sanoyaz; Biswas, Biswajit; Mandal, Manjushree; Sarkar, Neera Sen

2016-01-01

The study highlights the dynamics and morphological characteristics of the Genus Planktoniella Schutt. The two available species P. sol (Wallich) Schutt. and P. blanda (Schmidt) Syvertsen and Hasle are important components of the phytoplankton assemblage in the estuarine system of Indian Sundarbans and also marine systems elsewhere. The sampling sites for the purpose of this study include four different spots along a riverine stretch in the estuarine region adjacent to the Tiger Reserve in the Indian Sundarbans flowing into the Bay of Bengal. Integrated phytoplankton samples were preserved for the purpose from composite water samples from each site. The water samples were analysed in field for determining pH, temperature, salinity, conductivity, TDS, turbidity and DO and subsequent to treatment and processing, the samples were microscopically analysed in the laboratory. Significant negative correlation of cell count of both species found with respect to temperature and turbidity. P. sol versus temperature (significant at α = 0.01, p = 0.001) and P. blanda versus temperature (significant at α = 0.05, p = 0.037); P. sol versus turbidity (at α = 0.05, p = 0.019) and P. blanda versus turbidity (at α = 0.05, p = 0.019). Significant positive correlation found with respect to DO and as correlation between the two species themselves. A model has been generated for each of the two species with temperature, turbidity and DO as predictor variables and the two species of Planktoniella as response variables. The influence of other dominant phytoplankton in the samples has also been considered with Pearson correlation computed for each set of species.

Ground-water quality for Grainger County, Tennessee

Science.gov (United States)

Weaver, J.D.; Patel, A.R.; Hickey, A.C.

1994-01-01

The residents of Grainger County depend on ground water for many of their daily needs including personal consumption and crop irrigation. To address concerns associated with ground-water quality related to domestic use, the U.S. Geological Survey collected water samples from 35 wells throughout the county during the summer 1992. The water samples were analyzed to determine if pesticides, nutrients, bacteria, and other selected constituents were present in the ground water. Wells selected for the study were between 100 and 250 feet deep and yielded 10 to 50 gallons of water per minute. Laboratory analyses of the water found no organic pesticides at concentrations exceeding the primary maximum contaminant levels established by the State of Tennessee for wells used for public supply. However, fecal coliform bacteria were detected at concentrations exceeding the State's maximum contaminant level in water from 15 of the 35 wells sampled. Analyses also indicated several inorganic compounds were present in the water samples at concentrations exceeding the secondary maximum contaminant level.

Analytic game—theoretic approach to ground-water extraction

Science.gov (United States)

Loáiciga, Hugo A.

2004-09-01

The roles of cooperation and non-cooperation in the sustainable exploitation of a jointly used groundwater resource have been quantified mathematically using an analytical game-theoretic formulation. Cooperative equilibrium arises when ground-water users respect water-level constraints and consider mutual impacts, which allows them to derive economic benefits from ground-water indefinitely, that is, to achieve sustainability. This work shows that cooperative equilibrium can be obtained from the solution of a quadratic programming problem. For cooperative equilibrium to hold, however, enforcement must be effective. Otherwise, according to the commonized costs-privatized profits paradox, there is a natural tendency towards non-cooperation and non-sustainable aquifer mining, of which overdraft is a typical symptom. Non-cooperative behavior arises when at least one ground-water user neglects the externalities of his adopted ground-water pumping strategy. In this instance, water-level constraints may be violated in a relatively short time and the economic benefits from ground-water extraction fall below those obtained with cooperative aquifer use. One example illustrates the game theoretic approach of this work.

Ground Source Heat Pump Sub-Slab Heat Exchange Loop Performance in a Cold Climate

Energy Technology Data Exchange (ETDEWEB)

Mittereder, N.; Poerschke, A.

2013-11-01

This report presents a cold-climate project that examines an alternative approach to ground source heat pump (GSHP) ground loop design. The innovative ground loop design is an attempt to reduce the installed cost of the ground loop heat exchange portion of the system by containing the entire ground loop within the excavated location beneath the basement slab. Prior to the installation and operation of the sub-slab heat exchanger, energy modeling using TRNSYS software and concurrent design efforts were performed to determine the size and orientation of the system. One key parameter in the design is the installation of the GSHP in a low-load home, which considerably reduces the needed capacity of the ground loop heat exchanger. This report analyzes data from two cooling seasons and one heating season. Upon completion of the monitoring phase, measurements revealed that the initial TRNSYS simulated horizontal sub-slab ground loop heat exchanger fluid temperatures and heat transfer rates differed from the measured values. To determine the cause of this discrepancy, an updated model was developed utilizing a new TRNSYS subroutine for simulating sub-slab heat exchangers. Measurements of fluid temperature, soil temperature, and heat transfer were used to validate the updated model.

Development of a flow method for the determination of phosphate in estuarine and freshwaters-Comparison of flow cells in spectrophotometric sequential injection analysis

International Nuclear Information System (INIS)

Mesquita, Raquel B.R.; Ferreira, M. Teresa S.O.B.; Toth, Ildiko V.; Bordalo, Adriano A.; McKelvie, Ian D.; Rangel, Antonio O.S.S.

2011-01-01

Highlights: → Sequential injection determination of phosphate in estuarine and freshwaters. → Alternative spectrophotometric flow cells are compared. → Minimization of schlieren effect was assessed. → Proposed method can cope with wide salinity ranges. → Multi-reflective cell shows clear advantages. - Abstract: A sequential injection system with dual analytical line was developed and applied in the comparison of two different detection systems viz; a conventional spectrophotometer with a commercial flow cell, and a multi-reflective flow cell coupled with a photometric detector under the same experimental conditions. The study was based on the spectrophotometric determination of phosphate using the molybdenum-blue chemistry. The two alternative flow cells were compared in terms of their response to variation of sample salinity, susceptibility to interferences and to refractive index changes. The developed method was applied to the determination of phosphate in natural waters (estuarine, river, well and ground waters). The achieved detection limit (0.007 μM PO 4 3- ) is consistent with the requirement of the target water samples, and a wide quantification range (0.024-9.5 μM) was achieved using both detection systems.

76 FR 40338 - National Estuarine Research Reserve System

Science.gov (United States)

2011-07-08

... coastal issues of the reserve related to water quality (non-point source pollution), invasive species... Reserve System AGENCY: Estuarine Reserves Division, Office of Ocean and Coastal Resource Management.... ACTION: Notice of Approval and Availability for Revised Management Plans for ACE Basin, SC National...

Ground-water contribution to dose from past Hanford Operations

International Nuclear Information System (INIS)

Freshley, M.D.; Thorne, P.D.

1992-08-01

The Hanford Environmental Dose Reconstruction (HEDR) Project is being conducted to estimate radiation doses that populations and individuals could have received from Hanford Site operations from 1944 to the present. Four possible pathways by which radionuclides migrating in ground water on the Hanford Site could have reached the public have been identified: (1) through contaminated ground water migrating to the Columbia River; (2) through wells on or adjacent to the Hanford Site; (3) through wells next to the Columbia River downstream of Hanford that draw some or all of their water from the river (riparian wells); and (4) through atmospheric deposition resulting in contamination of a small watershed that, in turn, results in contamination of a shallow well or spring by transport in the ground water. These four pathways make up the ''ground-water pathway,'' which is the subject of this study. Assessment of the ground-water pathway was performed by (1) reviewing the existing extensive literature on ground water and ground-water monitoring at Hanford and (2) performing calculations to estimate radionuclide concentrations where no monitoring data were collected. Radiation doses that would result from exposure to these radionuclides were calculated

Simulation of Ground-Water Flow and Effects of Ground-Water Irrigation on Base Flow in the Elkhorn and Loup River Basins, Nebraska

Science.gov (United States)

Peterson, Steven M.; Stanton, Jennifer S.; Saunders, Amanda T.; Bradley, Jesse R.

2008-01-01

Irrigated agriculture is vital to the livelihood of communities in the Elkhorn and Loup River Basins in Nebraska, and ground water is used to irrigate most of the cropland. Concerns about the sustainability of ground-water and surface-water resources have prompted State and regional agencies to evaluate the cumulative effects of ground-water irrigation in this area. To facilitate understanding of the effects of ground-water irrigation, a numerical computer model was developed to simulate ground-water flow and assess the effects of ground-water irrigation (including ground-water withdrawals, hereinafter referred to as pumpage, and enhanced recharge) on stream base flow. The study area covers approximately 30,800 square miles, and includes the Elkhorn River Basin upstream from Norfolk, Nebraska, and the Loup River Basin upstream from Columbus, Nebraska. The water-table aquifer consists of Quaternary-age sands and gravels and Tertiary-age silts, sands, and gravels. The simulation was constructed using one layer with 2-mile by 2-mile cell size. Simulations were constructed to represent the ground-water system before 1940 and from 1940 through 2005, and to simulate hypothetical conditions from 2006 through 2045 or 2055. The first simulation represents steady-state conditions of the system before anthropogenic effects, and then simulates the effects of early surface-water development activities and recharge of water leaking from canals during 1895 to 1940. The first simulation ends at 1940 because before that time, very little pumpage for irrigation occurred, but after that time it became increasingly commonplace. The pre-1940 simulation was calibrated against measured water levels and estimated long-term base flow, and the 1940 through 2005 simulation was calibrated against measured water-level changes and estimated long-term base flow. The calibrated 1940 through 2005 simulation was used as the basis for analyzing hypothetical scenarios to evaluate the effects of

Evaluating data worth for ground-water management under uncertainty

Science.gov (United States)

Wagner, B.J.

1999-01-01

A decision framework is presented for assessing the value of ground-water sampling within the context of ground-water management under uncertainty. The framework couples two optimization models-a chance-constrained ground-water management model and an integer-programing sampling network design model-to identify optimal pumping and sampling strategies. The methodology consists of four steps: (1) The optimal ground-water management strategy for the present level of model uncertainty is determined using the chance-constrained management model; (2) for a specified data collection budget, the monitoring network design model identifies, prior to data collection, the sampling strategy that will minimize model uncertainty; (3) the optimal ground-water management strategy is recalculated on the basis of the projected model uncertainty after sampling; and (4) the worth of the monitoring strategy is assessed by comparing the value of the sample information-i.e., the projected reduction in management costs-with the cost of data collection. Steps 2-4 are repeated for a series of data collection budgets, producing a suite of management/monitoring alternatives, from which the best alternative can be selected. A hypothetical example demonstrates the methodology's ability to identify the ground-water sampling strategy with greatest net economic benefit for ground-water management.A decision framework is presented for assessing the value of ground-water sampling within the context of ground-water management under uncertainty. The framework couples two optimization models - a chance-constrained ground-water management model and an integer-programming sampling network design model - to identify optimal pumping and sampling strategies. The methodology consists of four steps: (1) The optimal ground-water management strategy for the present level of model uncertainty is determined using the chance-constrained management model; (2) for a specified data collection budget, the monitoring

Ground water in the Piedmont upland of central Maryland

Science.gov (United States)

Richardson, Claire A.

1982-01-01

This report, describing ground-water occurrence in a 130-square-mile area of the central Maryland Piedmont, was originally designed for use by the U.S. Environmental Protection Agency in replying to a request for designation of the aquifers to be the sole or principal source of ground water. However, the information contained in the report is pertinent to other crystalline-rock areas as well. The study area is underlain chiefly by crystalline rocks and partly by unaltered sandstones and siltstones. The ground water is derived from local precipitation and generally occurs under water-table conditions. Its movement is restricted by the lack of interconnected openings, and most ground water occurs within 300 feet of the land surface. Hydrographs indicate no long-term change in ground-water storage. A few wells yield more than 100 gallons per minute, but about 70 percent of 286 inventoried wells yield 10 gallons per minute or less; most specific capacities are less than 1.0 gallon per minute per foot. The ground-water quality is generally satisfactory without treatment, and there are no known widespread pollution problems. Estimated daily figures on ground-water use are as follows: 780,000 gallons for domestic purposes; 55,000, for commercial purposes; and 160,000, for public supply. Although part of the area is served by an existing surface-water supply and could be served by possible extension of it and of other public-supply water mains, much of the rural population is dependent on the ground water available from private wells tapping the single aquifer that underlies any given location. Neither the ground-water conditions nor this dependence on individual wells is unique to the study area, but, rather, applies to the entire Piedmont province.

Ground-water resources data for Baldwin County, Alabama

Science.gov (United States)

Robinson, James L.; Moreland, Richard S.; Clark, Amy E.

1996-01-01

Geologic and hydrologic data for 237 wells were collected, and water-levels in 223 wells in Baldwin and Escambia Counties were measured. Long-term water water-level data, available for many wells, indicate that ground-water levels in most of Baldwin County show no significant trends for the period of record. However, ground-water levels have declined in the general vicinity of Spanish Fort and Daphne, and ground-water levels in the Gulf Shores and Orange Beach areas are less than 5 feet above sea level in places. The quality of ground water generally is good, but problems with iron, sulfur, turbidity, and color occur. The water from most private wells in Baldwin County is used without treatment or filtration. Alabama public- health law requires that water from public-supply wells be chlorinated. Beyond that, the most common treatment of ground water by public-water suppliers in Baldwin County consists of pH adjustment, iron removal, and aeration. The transmissivity of the Miocene-Pliocene aquifer was determined at 10 locations in Baldwin County. Estimates of transmissivity ranged from 700 to 5,400 feet squared per day. In general, aquifer transmissivity was greatest in the southeastern part of the county, and least in the western part of the county near Mobile Bay. A storage coefficient of 1.5 x 10-3 was determined for the Miocene-Pliocene aquifer near Loxley.

Microbial degradation of pharmaceuticals in estuarine and coastal seawater

International Nuclear Information System (INIS)

Benotti, Mark J.; Brownawell, Bruce J.

2009-01-01

Microbial degradation rates were measured for 19 pharmaceuticals in estuarine and coastal surface water samples. Antipyrine, carbamazepine, cotinine, sulfamethoxazole, and trimethoprim were the most refractory (half-lives, t 1/2 = 35 to >100 days), making them excellent candidates for wastewater tracers. Nicotine, acetaminophen, and fluoxetine were labile across all treatments (t 1/2 = 0.68-11 days). Caffeine, diltiazem, and nifedipine were also and relatively labile in all but one of the treatments (t 1/2 = 3.5-13 days). Microbial degradation of caffeine was further confirmed by production 14 CO 2 . The fastest decay of non-refractory compounds was always observed in more sewage-affected Jamaica Bay waters. Degradation rates for the majority of these pharmaceuticals are much slower than reported rates for small biomolecules, such as glucose and amino acids. Batch sorption experiments indicate that removal of these soluble pharmaceuticals from the water column to sediments is a relatively insignificant removal process in these receiving waters. - Microbial degradation rates were measured for 19 structurally variable pharmaceuticals in wastewater-impacted estuarine and coastal seawater

Hydrogeology and water quality of the shallow ground-water system in eastern York County, Virginia. Water resources investigation

International Nuclear Information System (INIS)

1993-01-01

The report describes the hydrogeology and water quality of the shallow ground-water system in the eastern part of York County, Va. The report includes a discussion of (1) the aquifers and confining units, (2) the flow of ground water, and (3) the quality of ground water. The report is an evaluation of the shallow ground-water system and focuses on the first 200 ft of sediments below land surface. Historical water-level and water-quality data were not available for the study area; therefore, a network of observation wells was constructed for the study. Water levels were measured to provide an understanding of the flow of ground water through the multiaquifer system. Water samples were collected and analyzed for major inorganic constituents, nutrients, and metals. The report presents maps that show the regional distribution of chloride and iron concentrations. Summary statistics and graphical summaries of selected chemical constituents provide a general assessment of the ground-water quality

Green turtle (Chelonia mydas genetic diversity at Paranaguá Estuarine Complex feeding grounds in Brazil

Directory of Open Access Journals (Sweden)

Juliana Costa Jordão

2015-09-01

Full Text Available Sea turtles are marine reptiles that undertake long migrations through their life, with limited information regarding juvenile stages. Feeding grounds (FGs, where they spend most of their lives, are composed by individuals from different natal origins, known as mixed stock populations. The aim of this study was to assess genetic composition, natal origins and demographic history of juvenile green turtles (Chelonia mydas at the Paranaguá Estuarine Complex (PEC, Brazil, considered a Natural World Heritage site. Tissue samples of stranded animals were collected (n = 60, and 700 bp mitochondrial DNA sequences were generated and compared to shorter sequences from previously published studies. Global exact tests of differentiation revealed significant differences among PEC and the other FGs, except those at the South Atlantic Ocean. Green turtles at PEC present genetic signatures similar to those of nesting females from Ascension Island, Guinea Bissau and Aves Island/Surinam. Population expansion was evidenced to have occurred 20–25 kYA, reinforcing the hypothesis of recovery from Southern Atlantic refugia after the last Glacial Maximum. These results contribute to a better understanding of the dynamics of green turtle populations at a protected area by providing knowledge on the dispersion patterns and reinforcing the importance of the interconnectivity between nesting and foraging populations.

Macrophytes in estuarine gradients : Flow through flexible vegetation

NARCIS (Netherlands)

Dijkstra, J.T.

2012-01-01

Aquatic plants –or macrophytes- are an important part of coastal, estuarine and freshwater ecosystems worldwide, both from an ecological and an engineering viewpoint. Their meadows provide a wide range of ecosystem services: forming a physical protection of the shoreline, enhancing water quality and

The Validity Chlorophyll-a Estimation by Sun Induced Fluorescence in Estuarine Waters: An Analysis of Long-term (2003-2011) Water Quality Data from Tampa Bay, Florida (USA)

Science.gov (United States)

Moreno-Madrinan, Max Jacobo; Fischer, Andrew

2012-01-01

Satellite observation of phytoplankton concentration or chlorophyll-a is an important characteristic, critically integral to monitoring coastal water quality. However, the optical properties of estuarine and coastal waters are highly variable and complex and pose a great challenge for accurate analysis. Constituents such as suspended solids and dissolved organic matter and the overlapping and uncorrelated absorptions in the blue region of the spectrum renders the blue-green ratio algorithms for estimating chlorophyll-a inaccurate. Measurement of sun-induced chlorophyll fluorescence, on the other hand, which utilizes the near infrared portion of the electromagnetic spectrum, may provide a better estimate of phytoplankton concentrations. While modelling and laboratory studies have illustrated both the utility and limitations of satellite baseline algorithms based on the sun induced chlorophyll fluorescence signal, few have examined the empirical validity of these algorithms using a comprehensive long term in situ data set. In an unprecedented analysis of a long term (2003-2011) in situ monitoring data from Tampa Bay, Florida (USA), we assess the validity of the FLH product from the Moderate Resolution Imaging Spectrometer (MODIS) against chlorophyll ]a and a suite of water quality parameters taken in a variety of conditions throughout a large optically complex estuarine system. A systematic analysis of sampling sites throughout the bay is undertaken to understand how the relationship between FLH and in situ chlorophyll-a responds to varying conditions within the estuary including water depth, distance from shore and structures and eight water quality parameters. From the 39 station for which data was derived, 22 stations showed significant correlations when the FLH product was matched with in situ chlorophyll-alpha data. The correlations (r2) for individual stations within Tampa Bay ranged between 0.67 (n=28, pless than 0.01) and-0.457 (n=12, p=.016), indicating that

Development of a Ground Water Data Portal for Interoperable Data Exchange within the U.S. National Ground Water Monitoring Network and Beyond

Science.gov (United States)

Booth, N. L.; Brodaric, B.; Lucido, J. M.; Kuo, I.; Boisvert, E.; Cunningham, W. L.

2011-12-01

The need for a national groundwater monitoring network within the United States is profound and has been recognized by organizations outside government as a major data gap for managing ground-water resources. Our country's communities, industries, agriculture, energy production and critical ecosystems rely on water being available in adequate quantity and suitable quality. To meet this need the Subcommittee on Ground Water, established by the Federal Advisory Committee on Water Information, created a National Ground Water Monitoring Network (NGWMN) envisioned as a voluntary, integrated system of data collection, management and reporting that will provide the data needed to address present and future ground-water management questions raised by Congress, Federal, State and Tribal agencies and the public. The NGWMN Data Portal is the means by which policy makers, academics and the public will be able to access ground water data through one seamless web-based application from disparate data sources. Data systems in the United States exist at many organizational and geographic levels and differing vocabulary and data structures have prevented data sharing and reuse. The data portal will facilitate the retrieval of and access to groundwater data on an as-needed basis from multiple, dispersed data repositories allowing the data to continue to be housed and managed by the data provider while being accessible for the purposes of the national monitoring network. This work leverages Open Geospatial Consortium (OGC) data exchange standards and information models. To advance these standards for supporting the exchange of ground water information, an OGC Interoperability Experiment was organized among international participants from government, academia and the private sector. The experiment focused on ground water data exchange across the U.S. / Canadian border. WaterML2.0, an evolving international standard for water observations, encodes ground water levels and is exchanged

Evaluation of Ground Water Near Sidney, Western Nebraska, 2004-05

Science.gov (United States)

Steele, G.V.; Sibray, S.S.; Quandt, K.A.

2007-01-01

During times of drought, ground water in the Lodgepole Creek area around Sidney, western Nebraska, may be insufficient to yield adequate supplies to private and municipal wells. Alternate sources of water exist in the Cheyenne Tablelands north of the city, but these sources are limited in extent. In 2003, the U.S. Geological Survey and the South Platte Natural Resources District began a cooperative study to evaluate the ground water near Sidney. The 122-square-mile study area lies in the south-central part of Cheyenne County, with Lodgepole Creek and Sidney Draw occupying the southern and western parts of the study area and the Cheyenne Tablelands occupying most of the northern part of the study area. Twenty-nine monitoring wells were installed and then sampled in 2004 and 2005 for physical characteristics, nutrients, major ions, and stable isotopes. Some of the 29 sites also were sampled for ground-water age dating. Ground water is limited in extent in the tableland areas. Spring 2005 depths to ground water in the tableland areas ranged from 95 to 188 feet. Ground-water flow in the tableland areas primarily is northeasterly. South of a ground-water divide, ground-water flows southeasterly toward Lodgepole Creek Valley. Water samples from monitoring wells in the Ogallala Group were predominantly a calcium bicarbonate type, and those from monitoring wells in the Brule Formation were a sodium bicarbonate type. Water samples from monitoring wells open to the Brule sand were primarily a calcium bicarbonate type at shallow depths and a sodium bicarbonate type at deeper depths. Ground water in Lodgepole Creek Valley had a strong sodium signature, which likely results from most of the wells being open to the Brule. Concentrations of sodium and nitrate in ground-water samples from the Ogallala were significantly different than in water samples from the Brule and Brule sand. In addition, significant differences were seen in concentrations of calcium between water samples

Identification of technical guidance related to ground water monitoring

Energy Technology Data Exchange (ETDEWEB)

Vogelsberger, R.R.; Smith, E.D.; Broz, M.; Wright, J.C. Jr.

1987-05-01

Monitoring of ground water quality is a key element of ground water protection and is mandated by several federal and state laws concerned with water quality or waste management. Numerous regulatory guidance documents and technical reports discuss various aspects of ground water monitoring, but at present there is no single source of guidance on procedures and practices for ground water monitoring. This report is intended to assist US Department of Energy (DOE) officials and facility operating personnel in identifying sources of guidance for developing and implementing ground water monitoring programs that are technically sound and that comply with applicable regulations. Federal statutes and associated regulations were reviewed to identify requirements related to ground water monitoring, and over 160 documents on topics related to ground water monitoring were evaluated for their technical merit, their utility as guidance for regulatory compliance, and their relevance to DOE's needs. For each of 15 technical topics involved in ground water monitoring, the report presents (1) a review of federal regulatory requirements and representative state requirements, (2) brief descriptions of the contents and merits of available guidance documents and technical references, and (3) recommendations of the guidance documents or other technical resources that appear to be most appropriate for use in DOE's monitoring activities. The contents of the report are applicable to monitoring activities involving both radioactive and nonradioactive substances. The main sources of regulatory requirements considered in the report are the Atomic Energy Act (including the Uranium Mill Tailings Radiation Control Act), Resource Conservation and Recovery Act, Comprehensive Environmental Response, Compensation and Liability Act, Safe Drinking Water Act, Toxic Substances Control Act, and Federal Water Pollution Control Act.

Identification of technical guidance related to ground water monitoring

International Nuclear Information System (INIS)

Vogelsberger, R.R.; Smith, E.D.; Broz, M.; Wright, J.C. Jr.

1987-05-01

Monitoring of ground water quality is a key element of ground water protection and is mandated by several federal and state laws concerned with water quality or waste management. Numerous regulatory guidance documents and technical reports discuss various aspects of ground water monitoring, but at present there is no single source of guidance on procedures and practices for ground water monitoring. This report is intended to assist US Department of Energy (DOE) officials and facility operating personnel in identifying sources of guidance for developing and implementing ground water monitoring programs that are technically sound and that comply with applicable regulations. Federal statutes and associated regulations were reviewed to identify requirements related to ground water monitoring, and over 160 documents on topics related to ground water monitoring were evaluated for their technical merit, their utility as guidance for regulatory compliance, and their relevance to DOE's needs. For each of 15 technical topics involved in ground water monitoring, the report presents (1) a review of federal regulatory requirements and representative state requirements, (2) brief descriptions of the contents and merits of available guidance documents and technical references, and (3) recommendations of the guidance documents or other technical resources that appear to be most appropriate for use in DOE's monitoring activities. The contents of the report are applicable to monitoring activities involving both radioactive and nonradioactive substances. The main sources of regulatory requirements considered in the report are the Atomic Energy Act (including the Uranium Mill Tailings Radiation Control Act), Resource Conservation and Recovery Act, Comprehensive Environmental Response, Compensation and Liability Act, Safe Drinking Water Act, Toxic Substances Control Act, and Federal Water Pollution Control Act

Water quality, meteorological, and nutrient data collected by the the National Estuarine Research Reserve System's System-wide Monitoring Program (NERRS SWMP), 1994 - 2005 (NODC Accession 0019215)

Data.gov (United States)

National Oceanic and Atmospheric Administration, Department of Commerce — The National Estuarine Research Reserve System's System-wide Monitoring Program (NERRS SWMP) collected water quality, meteorological, and nutrient data in 25...

Biofouling growth in cold estuarine waters and evaluation of some chitosan and copper anti-fouling paints.

Science.gov (United States)

Pelletier, Emilien; Bonnet, Claudie; Lemarchand, Karine

2009-07-14

Ecological concerns about antifouling paints containing non-green tin and copper compounds have highlighted the need for environmentally friendly alternatives. We report here a field test conducted in estuarine waters over two months designed to evaluate the efficiency of a number of active natural and man-made chemical ingredients added into a silicon-polyurethane marine paint. Early steps of biofouling in cold seawater of the St. Lawrence Estuary (Canada) were observed. Analyses, including dry biomass, flow cytometry and spectrofluorimetry, demonstrated a short-term antibacterial action of chitosan-based paints although no significant anti-algal action was observed. Cuprous oxide paints were efficient against bacteria and algae invasion in the first two weeks, especially those with added organic biocides such as isothiazolone and copper pyrithione. However, the overall dry biomass and chlorophyll a content were similar for all chitosan-and copper-based paints after 63 days. Microscopic observations revealed variation in the highly diverse benthic diatom population including species Navicula, Melosira, Cocconeis, Nitshzcia, Fragilaria and Amphora. Results suggest no real long-term efficiency for tested antifouling paints and highlight a particular need for green antifouling ingredients that are active under northern estuarine conditions.

Biofouling Growth in Cold Estuarine Waters and Evaluation of Some Chitosan and Copper Anti-Fouling Paints

Directory of Open Access Journals (Sweden)

Karine Lemarchand

2009-07-01

Full Text Available Ecological concerns about antifouling paints containing non-green tin and copper compounds have highlighted the need for environmentally friendly alternatives. We report here a field test conducted in estuarine waters over two months designed to evaluate the efficiency of a number of active natural and man-made chemical ingredients added into a silicon-polyurethane marine paint. Early steps of biofouling in cold seawater of the St. Lawrence Estuary (Canada were observed. Analyses, including dry biomass, flow cytometry and spectrofluorimetry, demonstrated a short-term antibacterial action of chitosan-based paints although no significant anti-algal action was observed. Cuprous oxide paints were efficient against bacteria and algae invasion in the first two weeks, especially those with added organic biocides such as isothiazolone and copper pyrithione. However, the overall dry biomass and chlorophyll a content were similar for all chitosan- and copper-based paints after 63 days. Microscopic observations revealed variation in the highly diverse benthic diatom population including species Navicula, Melosira, Cocconeis, Nitshzcia, Fragilaria and Amphora. Results suggest no real long-term efficiency for tested antifouling paints and highlight a particular need for green antifouling ingredients that are active under northern estuarine conditions.

Ground-water hydraulics - A summary of lectures presented by John G. Ferris at short courses conducted by the Ground Water Branch, part 1, Theory

Science.gov (United States)

Knowles, D.B.

1955-01-01

The objective of the Ground Water Branch is to evaluate the occurrence, availability, and quality of ground water.  The science of ground-water hydrology is applied toward attaining that goal.  Although many ground-water investigations are of a qualitative nature, quantitative studies are necessarily an integral component of the complete evaluation of occurrence and availability.  The worth of an aquifer as a fully developed source of water depends largely on two inherent characteristics: its ability to store, and its ability to transmit water.  Furthermore, quantitative knowledge of these characteristics facilitates measurement of hydrologic entities such as recharge, leakage, evapotranspiration, etc.  It is recognized that these two characteristics, referred to as the coefficients of storage and transmissibility, generally provide the very foundation on which quantitative studies are constructed.  Within the science of ground-water hydrology, ground-water hydraulics methods are applied to determine these constats from field data.

Effects of changing irrigation practices on the ground-water hydrology of the Santa Isabel-Juana Diaz area, south central Puerto Rico

Science.gov (United States)

Ramos-Gines, Orlando

1994-01-01

Prior to 1930, the principal source of water for irrigation in the Santa Isabel-Juana Diaz area was surface water from outside the study area, which was delivered by a complex channel-pond system. Recharge from water applied to the fields, estimated to be 18.7 million of gallons per day, and discharge by ground-water flow to sea, estimated to be 17 million of gallons per day, were the major water- budget components prior to intensive development of the ground-water resources. Development of the ground-water resources after 1930 resulted in a substantial increase in irrigation, primarily furrow irrigation. The surface water supplied by the complex channel-pond system continued to be used and ground-water withdrawals increased sub- stantially. By 1966-68, ground-water recharge from irrigation water applied to the fields, estimated to be 37 million of gallons per day, and discharge by pumpage for irrigation, estimated to be 77 million of gallons per day, were the two major components of the ground-water budget. By 1987, drip irrigation had become the principal method of irrigation in the study area, and surface-water irrigation had, for the most part, been discontinued. The estimated aquifer recharge from irrigation water in 1987 was about 6.6 million of gallons per day, which occurred primarily in the remaining fields where furrow irrigation was still practiced. Although aquifer recharge had been reduced as a result of the conversion from furrow to drip irrigation, water levels in the aquifer were higher in 1987 than in 1968 because of the large reduction in ground-water withdrawals and subsequent recovery of ground-water levels.

IN-SITU BIOREMEDIATION OF CONTAMINATED GROUND WATER

Science.gov (United States)

This document is one in a series of Ground Water Issue papers which have been prepared in response to needs expressed by the Ground Water Forum. It is based on findings from the research community in concert with experience gained at sites undergoing remediation. the intent of th...

40 CFR 264.97 - General ground-water monitoring requirements.

Science.gov (United States)

2010-07-01

... has not been affected by leakage from a regulated unit; (i) A determination of background ground-water...) Represent the quality of ground water passing the point of compliance. (3) Allow for the detection of... elevation each time ground water is sampled. (g) In detection monitoring or where appropriate in compliance...

Preliminary Evidence for the Amplification of Global Warming in Shallow, Intertidal Estuarine Waters.

Directory of Open Access Journals (Sweden)

Autumn Oczkowski

Full Text Available Over the past 50 years, mean annual water temperature in northeastern U.S. estuaries has increased by approximately 1.2°C, with most of the warming recorded in the winter and early spring. A recent survey and synthesis of data from four locations in Southern Rhode Island has led us to hypothesize that this warming may be amplified in the shallow (<1 m, nearshore portions of these estuaries. While intertidal areas are not typically selected as locations for long-term monitoring, we compiled data from published literature, theses, and reports that suggest that enhanced warming may be occurring, perhaps at rates three times higher than deeper estuarine waters. Warmer spring waters may be one of the factors influencing biota residing in intertidal regions both in general as well as at our specific sites. We observed greater abundance of fish, and size of Menidia sp., in recent (2010-2012 seine surveys compared to similar collections in 1962. While any linkages are speculative and data are preliminary, taken together they suggest that shallow intertidal portions of estuaries may be important places to look for the effects of climate change.

Preliminary Evidence for the Amplification of Global Warming in Shallow, Intertidal Estuarine Waters.

Science.gov (United States)

Oczkowski, Autumn; McKinney, Richard; Ayvazian, Suzanne; Hanson, Alana; Wigand, Cathleen; Markham, Erin

2015-01-01

Over the past 50 years, mean annual water temperature in northeastern U.S. estuaries has increased by approximately 1.2°C, with most of the warming recorded in the winter and early spring. A recent survey and synthesis of data from four locations in Southern Rhode Island has led us to hypothesize that this warming may be amplified in the shallow (<1 m), nearshore portions of these estuaries. While intertidal areas are not typically selected as locations for long-term monitoring, we compiled data from published literature, theses, and reports that suggest that enhanced warming may be occurring, perhaps at rates three times higher than deeper estuarine waters. Warmer spring waters may be one of the factors influencing biota residing in intertidal regions both in general as well as at our specific sites. We observed greater abundance of fish, and size of Menidia sp., in recent (2010-2012) seine surveys compared to similar collections in 1962. While any linkages are speculative and data are preliminary, taken together they suggest that shallow intertidal portions of estuaries may be important places to look for the effects of climate change.

Ground-water contamination and legal controls in Michigan

Science.gov (United States)

Deutsch, Morris

1963-01-01

The great importance of the fresh ground-water resources of Michigan is evident because 90 percent of the rural and about 70 percent of the total population of the State exclusive of the Detroit metropolitan area are supplied from underground sources. The water-supply and public-health problems that have been caused by some cases of ground-water contamination in the State illustrate the necessity of protecting this vital resource.Manmade and natural contaminants, including many types of chemical and organic matter, have entered many of the numerous aquifers of the State. Aquifers have been contaminated by waste-laden liquids percolating from the surface or from the zone of aeration and by direct injection to the aquifer itself. Industrial and domestic wastes, septic tanks, leaking sewers, flood waters or other poor quality surface waters, mine waters, solids stored or spread at the surface, and even airborne wastes all have been sources of ground-water contamination in Michigan. In addition, naturally occurring saline waters have been induced into other aquifers by overpumping or unrestricted flow from artesian wells, possibly by dewatering operations, and by the deepening of surface stream channels. Vertical migration of saline waters through open holes from formations underlying various important aquifers also has spoiled some of the fresh ground waters in the State. In spite of the contamination that has occurred, however, the total amount of ground water that has been spoiled is only a small part of the total resource. Neither is the contamination so widespread as that of the surface streams of Michigan.Overall legal authority to control most types of ground-water contamination in the State has been assigned by the Michigan Legislature to the Water Resources Commission, although the Department of Conservation and the Health Department also exercise important water-pollution control functions. The Michigan Supreme Court, in an important case upholding the power

Ground-water reconnaissance of American Samoa

Science.gov (United States)

Davis, Daniel Arthur

1963-01-01

The principal islands of American Samoa are Tutuila, Aunuu, Ofu, Olosega, and Ta'u, which have a total area of about 72 square miles and a population of about 20,000. The mean annual rainfall is 150 to 200 inches. The islands are volcanic in origin and are composed of lava flows, dikes, tuff. and breccia, and minor amounts of talus, alluvium, and calcareous sand and gravel. Tutuila is a complex island formed of rocks erupted from five volcanoes. Aunuu is a tuff cone. Ofu, Olosega, and Ta'u are composed largely of thin-bedded lava flows. Much of the rock of Tutuila has low permeability, and most of the ground water is in high-level reservoirs that discharge at numerous small springs and seeps. The flow from a few springs and seeps is collected in short tunnels or in basins for village supply, but most villages obtain their water from streams. A large supply of basal ground water may underlie the Tafuna-Leone plain at about sea level in permeable lava flows. Small basal supplies may be in alluvial fill at the mouths of large valleys. Aunuu has small quantities of basal water in beach deposits of calcareous sand and gravel. Minor amounts of high-level ground-water flow from springs and seeps on Ofu, Olosega, and Ta'u. The generally permeable lava flows in the three islands contain substantial amounts of basal ground water that can be developed in coastal areas in wells dug to about sea level.

Sampling art for ground-water monitoring wells in nuclide migration

International Nuclear Information System (INIS)

Liu Wenyuan; Tu Guorong; Dang Haijun; Wang Xuhui; Ke Changfeng

2010-01-01

Ground-Water sampling is one of the key parts in field nuclide migration. The objective of ground-water sampling program is to obtain samples that are representative of formation-quality water. In this paper, the ground-water sampling standards and the developments of sampling devices are reviewed. We also designed the sampling study projects which include the sampling methods, sampling parameters and the elementary devise of two types of ground-Water sampling devices. (authors)

Chemistry and behaviour of B, Ca and Mg in interstitial waters of sediments from the coastal and estuarine regions of Mandovi river along the west coast of India

Digital Repository Service at National Institute of Oceanography (India)

Shirodkar, P.V.; SenGupta, R.

Interstitial waters of coastal and estuarine sediments show enrichment of B and Ca and a decrease in Mg. Increase in interstitial B in sediments is due to the downward diffusion from overlying water and release from solid phases by physicochemical...

Process induced sub-surface damage in mechanically ground silicon wafers

International Nuclear Information System (INIS)

Yang Yu; De Munck, Koen; Teixeira, Ricardo Cotrin; Swinnen, Bart; De Wolf, Ingrid; Verlinden, Bert

2008-01-01

Micro-Raman spectroscopy, scanning electron microcopy, atomic force microscopy and preferential etching were used to characterize the sub-surface damage induced by the rough and fine grinding steps used to make ultra-thin silicon wafers. The roughly and ultra-finely ground silicon wafers were examined on both the machined (1 0 0) planes and the cross-sectional (1 1 0) planes. They reveal similar multi-layer damage structures, consisting of amorphous, plastically deformed and elastically stressed layers. However, the thickness of each layer in the roughly ground sample is much higher than its counterpart layers in the ultra-finely ground sample. The residual stress after rough and ultra-fine grinding is in the range of several hundreds MPa and 30 MPa, respectively. In each case, the top amorphous layer is believed to be the result of sequential phase transformations (Si-I to Si-II to amorphous Si). These phase transformations correspond to a ductile grinding mechanism, which is dominating in ultra-fine grinding. On the other hand, in rough grinding, a mixed mechanism of ductile and brittle grinding causes multi-layer damage and sub-surface cracks

Benthic and pelagic pathways of methylmercury bioaccumulation in estuarine food webs of the northeast United States.

Directory of Open Access Journals (Sweden)

Celia Y Chen

Full Text Available Methylmercury (MeHg is a contaminant of global concern that bioaccumulates and bioamagnifies in marine food webs. Lower trophic level fauna are important conduits of MeHg from sediment and water to estuarine and coastal fish harvested for human consumption. However, the sources and pathways of MeHg to these coastal fisheries are poorly known particularly the potential for transfer of MeHg from the sediment to biotic compartments. Across a broad gradient of human land impacts, we analyzed MeHg concentrations in food webs at ten estuarine sites in the Northeast US (from the Hackensack Meadowlands, NJ to the Gulf of Maine. MeHg concentrations in water column particulate material, but not in sediments, were predictive of MeHg concentrations in fish (killifish and Atlantic silversides. Moreover, MeHg concentrations were higher in pelagic fauna than in benthic-feeding fauna suggesting that MeHg delivery to the water column from methylation sites from within or outside of the estuary may be an important driver of MeHg bioaccumulation in estuarine pelagic food webs. In contrast, bulk sediment MeHg concentrations were only predictive of concentrations of MeHg in the infaunal worms. Our results across a broad gradient of sites demonstrate that the pathways of MeHg to lower trophic level estuarine organisms are distinctly different between benthic deposit feeders and forage fish. Thus, even in systems with contaminated sediments, transfer of MeHg into estuarine food webs maybe driven more by the efficiency of processes that determine MeHg input and bioavailability in the water column.

Developing and implementing institutional controls for ground water remediation

International Nuclear Information System (INIS)

Ulland, L.M.; Cooper, M.G.

1995-01-01

The US DOE has initiated its Ground Water Project as the second phase of the Uranium Mill Tailings Remedial Action (UMTRA) Project authorized under the Uranium Mill Tailings Radiation Control Act (UMTRCA). In the Ground Water Project, the DOE must reduce risk from ground water contaminated by uranium mill processing activities at 24 inactive processing sites by meeting the US EPA standards. The UMTRCA also requires consistency with federal statutes such as the Resource Conservation and Recovery Act (RCRA). The use of institutional controls to reduce risk from contaminated ground water is one element of compliance with standards and the protection of public health and the environment. Institutional controls are active or passive measures that reduce exposure to risks by preventing intrusion or restricting direct access to an area, or restricting access to the contamination through secondary means. Because of inconsistent regulations and multi-party authorities for ground water management, the key to selecting and implementing effective institutional controls lies with developing a consensus between the parties responsible for ground water remediation; those with authority to implement, monitor, and maintain institutional controls; and those facing the risks from contaminated ground water. These parties must develop a consensus for an institutional control program that meets minimum regulatory requirements and protects public health and the environment. Developing consensus and implementing a successful institutional controls program was achieved by the DOE during the cleanup of uranium mill tailings. An effective institutional controls program can also be developed to protect against risks from contaminated ground water. Consensus building and information transmission are the critical elements of an institutional control program that protects human health and the environment from risks associated with ground water contamination

40 CFR 258.51 - Ground-water monitoring systems.

Science.gov (United States)

2010-07-01

... water that has not been affected by leakage from a unit. A determination of background quality may... that ensures detection of ground-water contamination in the uppermost aquifer. When physical obstacles... 40 Protection of Environment 24 2010-07-01 2010-07-01 false Ground-water monitoring systems. 258...

Carbon Stocks in Mangrove Ecosystems of Musi and Banyuasin Estuarine, South Sumatra Province (Stok Karbon Ekosistem Mangrove di Estuarin Musi dan Banyuasin, Provinsi Sumatera Selatan

Directory of Open Access Journals (Sweden)

Melki Melki

2014-09-01

Full Text Available Hutan mangrove di daerah estuari mampu menghasilkan stok karbon yang sangat besar sebagai daerah perlindungan dan pemulihan yang efektif sebagai strategi mitigasi perubahan iklim yang efektif. Pemilihan ekosistem pesisir dalam strategi mitigasi memerlukan kuantifikasi stok karbon untuk menghitung emisi atau penyerapan berdasarkan waktu. Penelitian ini menghitung stok karbon pada ekosistem Musi Estuari Waters (MEW dan Banyuasin Estuari Water (BEW, Provinsi Sumatera Selatan pada tipe vegetasi yang berbeda dan hubungan variabel lingkungan dengan stok karbon. Di tujuh lokasi dalam MEW dan BEW sampel vegetasi dan tanah. Hasil yang didapatkan adalah nilai yang lebih tinggi dari stok karbon di vegetasi dari lokasi III/MEW (7.600,92 mg.ha-1, stok karbon dalam tanah dari lokasi II/MEW (61.081,87 mg.ha-1 dan stok karbon di ekosistem dari lokasi II (64.548,54 mg.ha-1. Mangrove A. marina merupakan yang paling baik menyimpan stok carbon termasuk antara vegetasi dan tanah karena toleransi salinitas yang rendah. Kata kunci: mangrove, karbon, estuari, Musi, Banyuasin Mangrove forests in estuarines can have exceptionally large carbon stocks and their protection and restoration would constitute an effective mitigation strategy to climate change. Inclusion of coastal ecosystems in mitigation strategies require quantification of carbon stocks in order to calculate emissions or sequestration through time. This study quantified the ecosystem carbon stocks of the Musi Estuarine Waters (MEW and Banyuasin Estuarine Water (BEW, Province of South Sumatra into different vegetation types and examined relationships of environmental variables with carbon stocks. At seven sites within MEW and BEW of vegetation and soil samples. The results that the higher value of carbon stock in vegetation from Site III/MEW (7.600,92 mg.ha-1, the carbon stock in soil from Site II/MEW (61.081,87 mg.ha-1 and carbon stock in ecosystem from Site II (64.548,54 mg.ha-1. Mangrove of A. marina the

Uranium mineralization by ground water in sedimentary rocks, Japan

International Nuclear Information System (INIS)

Doi, K.; Hirono, S.; Sakamaki, Y.

1975-01-01

To solve the mechanism of uranium concentration in stratabound uranium deposits occurring in the basal part of Neogene sediments overlying granite basement, attention was paid to uranium leaching from weathered granite by circulating carbonated fissure waters, to effective adsorbents for fixing uranium from uraniferous ground waters, to structural features controlling the ground-water circulation, and other relevant factors. The evidence for uranium transportation by hydothermal solutions, including hot spring waters, is hard to observe. Conclusions are summarized as follows: Uranium in the deposits is supplied from surrounding source rocks, mostly from granite. Uranium is transported by circulating ground-water solutions. The uranium dissolved in ground water is fixed in minerals in various ways, the most important being adsorption by carbonaceous matter. Ore-grade uranium concentrated from very dilute solutions occurs by multiple repetition of a leaching-and-fixation cycle between minerals or adsorbents and circulating uraniferous ground water. Important factors for uranium mineralization are sufficient uranium, supplied mostly from granite, the existence of effective adsorbents such as carbonaceous matter in the host rocks, and favorable geological, geochemical, and geophysical environments. The last seem to require not only physical and chemical conditions but also correct flow and volume of ground water. (U.S.)

Extraction tools for identification of chemical contaminants in estuarine and coastal waters to determine toxic pressure on primary producers.

Science.gov (United States)

Booij, Petra; Sjollema, Sascha B; Leonards, Pim E G; de Voogt, Pim; Stroomberg, Gerard J; Vethaak, A Dick; Lamoree, Marja H

2013-09-01

The extent to which chemical stressors affect primary producers in estuarine and coastal waters is largely unknown. However, given the large number of legacy pollutants and chemicals of emerging concern present in the environment, this is an important and relevant issue that requires further study. The purpose of our study was to extract and identify compounds which are inhibitors of photosystem II activity in microalgae from estuarine and coastal waters. Field sampling was conducted in the Western Scheldt estuary (Hansweert, The Netherlands). We compared four different commonly used extraction methods: passive sampling with silicone rubber sheets, polar organic integrative samplers (POCIS) and spot water sampling using two different solid phase extraction (SPE) cartridges. Toxic effects of extracts prepared from spot water samples and passive samplers were determined in the Pulse Amplitude Modulation (PAM) fluorometry bioassay. With target chemical analysis using LC-MS and GC-MS, a set of PAHs, PCBs and pesticides was determined in field samples. These compound classes are listed as priority substances for the marine environment by the OSPAR convention. In addition, recovery experiments with both SPE cartridges were performed to evaluate the extraction suitability of these methods. Passive sampling using silicone rubber sheets and POCIS can be applied to determine compounds with different structures and polarities for further identification and determination of toxic pressure on primary producers. The added value of SPE lies in its suitability for quantitative analysis; calibration of passive samplers still needs further investigation for quantification of field concentrations of contaminants. Copyright © 2013 Elsevier Ltd. All rights reserved.

Soil and ground-water remediation techniques

International Nuclear Information System (INIS)

Beck, P.

1996-01-01

Urban areas typically contain numerous sites underlain by soils or ground waters which are contaminated to levels that exceed clean-up guidelines and are hazardous to public health. Contamination most commonly results from the disposal, careless use and spillage of chemicals, or the historic importation of contaminated fill onto properties undergoing redevelopment. Contaminants of concern in soil and ground water include: inorganic chemicals such as heavy metals; radioactive metals; salt and inorganic pesticides, and a range of organic chemicals included within petroleum fuels, coal tar products, PCB oils, chlorinated solvents, and pesticides. Dealing with contaminated sites is a major problem affecting all urban areas and a wide range of different remedial technologies are available. This chapter reviews the more commonly used methods for ground-water and soil remediation, paying particular regard to efficiency and applicability of specific treatments to different site conditions. (author). 43 refs., 1 tab., 27 figs

Hanford Site ground-water monitoring for 1991

International Nuclear Information System (INIS)

Evans, J.C.; Bryce, R.W.; Bates, D.J.

1992-10-01

The Pacific Northwest Laboratory (PNL) monitors the distribution of radionuclides and other hazardous materials in ground water at the Hanford Site for the US Department of Energy (DOE). This work is performed through the Ground-Water Surveillance Project and is designed to meet the requirements of DOE Order 5400.1 that apply to environmental surveillance and ground-water monitoring (DOE 1988). This annual report discusses results of ground-water monitoring at the Hanford Site during 1991. In addition to the general discussion, the following topics are discussed in detail: (1) carbon tetrachloride in the 200-West Area; (2) cyanide in and north of the 200-East and the 200-West areas; (3) hexavalent chromium contamination in the 100, 200, and 600 areas; (4) trichloroethylene in the vicinity of the Solid Waste Landfill, 100-F Area, and 300 Area; (5) nitrate across the Site; (6) tritium across the Site; and (7) other radionuclide contamination throughout the Site, including gross alpha, gross beta, cobalt-60, strontium-90, technetium-99, iodine-129, cesium-137, uranium, and plutonium

Natural isotope technique for the exploration and exploitation of ground water

International Nuclear Information System (INIS)

Zainal Abidin; Hudi Hastowo; Aang Hanafiah

2007-01-01

In line with the condition of climate and hydrology, Indonesia has a fast amount of aquifers which are sources of ground water. In several areas large number of springs occurred with small to large debits which is a sign of ground water potential. Ground water is a potential reservoir to be use at maximum for several purposes such as drinking water, industry and tourism. Large cities such as Jakarta, Bandung and others depend on ground water for their industries and hotels. The exploitation of ground water use has to be controlled and monitoring of a management system have to be done. Research carried out only on the exploitation of geophysics and hydrology showed that the amount of ground water reservoirs is not enough to be used when it comes to justification to explore it. Other parameters are still be needed which are the origins and dating of the ground water, these last two factors mentioned have to be taken into consideration in the system of conversion and balance of water. An alternative technology to determine the two factors mentioned in a short time is the natural isotope technique of 18 O, 2 H and 14 C. This technique is used to determine the origin of water, and isotope 14 C is carried out to determine the age of ground water. Isotopes 18 H and 2 H are stable isotopes in the form of water and is integrated in the hydrological cycle. Their specific concentrations in rain water at several elevations are used as fingerprints to locate the area of ground water supplement and its origin. Isotope 14 C is a natural radioactive isotope with a half-life of 5.730 years and is found in the hydrology cycle and enters the ground water system through CO 2 gas which is dissolved in water. 14 C isotope could determine the age of ground water and is also able to indicate the potential/amount of ground water. Studies of exploration and exploration monitoring of ground water should be an integrated study by geohydrology, geophysics and isotope and could be a solution of

Uranium isotopes in ground water as a prospecting technique

International Nuclear Information System (INIS)

Cowart, J.B.; Osmond, J.K.

1980-02-01

The isotopic concentrations of dissolved uranium were determined for 300 ground water samples near eight known uranium accumulations to see if new approaches to prospecting could be developed. It is concluded that a plot of 234 U/ 238 U activity ratio (A.R.) versus uranium concentration (C) can be used to identify redox fronts, to locate uranium accumulations, and to determine whether such accumulations are being augmented or depleted by contemporary aquifer/ground water conditions. In aquifers exhibiting flow-through hydrologic systems, up-dip ground water samples are characterized by high uranium concentration values (> 1 to 4 ppB) and down-dip samples by low uranium concentration values (less than 1 ppB). The boundary between these two regimes can usually be identified as a redox front on the basis of regional water chemistry and known uranium accumulations. Close proximity to uranium accumulations is usually indicated either by very high uranium concentrations in the ground water or by a combination of high concentration and high activity ratio values. Ground waters down-dip from such accumulations often exhibit low uranium concentration values but retain their high A.R. values. This serves as a regional indicator of possible uranium accumulations where conditions favor the continued augmentation of the deposit by precipitation from ground water. Where the accumulation is being dispersed and depleted by the ground water system, low A.R. values are observed. Results from the Gulf Coast District of Texas and the Wyoming districts are presented

Handling the decline of ground water using artificial recharge areas

Science.gov (United States)

Hidayatullah, Muhammad Shofi; Yoga, Kuncaraningrat Edi; Muslim, Dicky

2017-11-01

Jatinagor, a region with rapid growth cause increasing in water demand. The ground water surface in the observation area shows a decrease based on its potential. This deflation is mainly caused by the inequality between inputs and outputs of the ground water itself. The decrease of this ground water surface is also caused by the number of catchment areas that keeps decreasing. According to the data analysis of geology and hydrology, the condition of ground water in Jatinangor on 2015 had indicated a decrease compared to 2010. Nowadays, the longlivity of clean water can be ensure by the hydrogeology engineering, which is to construct an artificial recharge for ground water in use. The numerical method is aims to determine the number of ground water supply in Jatinangor. According to the research, the most suitable artificial recharge is in the form of a small dam located in the internment river. With the area of 209.000 m2, this dam will be able to contain 525 m3 runoff water with the intensity of maximum rainfall effectively 59,44 mm/hour. The increase of water volume generate by this artificial recharge, fulfilled the demand of clean water.

Speciation and transport of radionuclides in ground water

International Nuclear Information System (INIS)

Robertson, D.E.; Toste, A.P.; Abel, K.H.; Cowan, C.E.; Jenne, E.A.; Thomas, C.W.

1984-01-01

Studies of the chemical speciation of a number of radionuclides migrating in a slightly contaminated ground water plume are identifying the most mobile species and providing an opportunity to test and/or validate geochemical models of radionuclide transport in ground waters. Results to date have shown that most of the migrating radionuclides are present in anionic or nonionic forms. These include anionic forms of 55 Fe, 60 Co, /sup 99m/Tc, 106 Ru, 131 I, and nonionic forms of 63 Ni and 125 Sb. Strontium-70 and a small fraction of the mobile 60 Co are the only cationic radionuclides which have been detected moving in the ground water plume beyond 30 meters from the source. A comparison of the observed chemical forms with the predicted species calculated from modeling thermodynamic data and ground water chemical parameters has indicated a good agreement for most of the radioelements in the system, including Tc, Np, Cs, Sr, Ce, Ru, Sb, Zn, and Mn. The discrepancies between observed and calculated solutions species were noted for Fe, Co, Ni and I. Traces of Fe, Co, and Ni were observed to migrate in anionic or nonionic forms which the calculations failed to predict. These anionic/nonionic species may be organic complexes having enhanced mobility in ground waters. The radioiodine, for example, was shown to behave totally as an anion but further investigation revealed that 49-57% of this anionic iodine was organically bound. The ground water and aqueous extracts of trench sediments contain a wide variety of organic compounds, some of which could serve as complexing agents for the radionuclides. These results indicate the need for further research at a variety of field sites in defining precisely the chemical forms of the mobile radionuclide species, and in better understanding the role of dissolved organic materials in ground water transport of radionuclides

Assessing estuarine quality: A cost-effective in situ assay with amphipods.

Science.gov (United States)

Martinez-Haro, Monica; Acevedo, Pelayo; Pais-Costa, Antónia Juliana; Taggart, Mark A; Martins, Irene; Ribeiro, Rui; Marques, João Carlos

2016-05-01

In situ assays based on feeding depression can be powerful ecotoxicological tools that can link physiological organism-level responses to population and/or community-level effects. Amphipods are traditional target species for toxicity tests due to their high sensitivity to contaminants, availability in the field and ease of handling. However, cost-effective in situ assays based on feeding depression are not yet available for amphipods that inhabit estuarine ecosystems. The aim of this work was to assess a short-term in situ assay based on postexposure feeding rates on easily quantifiable food items with an estuarine amphipod. Experiments were carried out under laboratory conditions using juvenile Echinogammarus marinus as the target individual. When 60 Artemia franciscana nauplii (as prey) were provided per individual for a period of 30 min in dark conditions, feeding rates could be easily quantified. As an endpoint, postexposure feeding inhibition in E. marinus was more sensitive to cadmium contamination than mortality. Assay calibration under field conditions demonstrated the relevance of sediment particle size in explaining individual feeding rates in uncontaminated water bodies. An evaluation of the 48-h in situ bioassay based on postexposure feeding rates indicated that it is able to discriminate between unpolluted and polluted estuarine sites. Using the harmonized protocol described here, the in situ postexposure feeding assay with E. marinus was found to be a potentially useful, cost-effective tool for assessing estuarine sediment and water quality. Copyright © 2016 Elsevier Ltd. All rights reserved.

Evaluation of the ground-water resources of parts of Lancaster and Berks Counties, Pennsylvania

Science.gov (United States)

Gerhart, J.M.; Lazorchick, G.J.

1984-01-01

Secondary openings in bedrock are the avenues for virtually all ground-water flow in a 626-sqare-mile area in Lancaster and Berks Counties, Pennsylvania. The number, size, and interconnection of secondary openings are functions of lithology, depth, and topography. Ground water actively circulates to depths of 150 to 300 feet below land surface. Total average annual ground-water recharge for the area is 388 million gallons per day, most of which discharges to streams from local, unconfined flow systems. A digital ground-water flow model was developed to simulate unconfined flow under several different recharge and withdrawal scenarios. On the basis of lithologic and hydrologic differences, the modeled area was sub-divided into 22 hydrogeologic units. A finite-difference grid with rectangular blocks, each 2,015 by 2,332 feet, was used. The model was calibrated under steady-state and transient conditions. The steady-state calibration was used to determine hydraulic conductivities and stream leakage coefficients and the transient calibration was used to determine specific yields. The 22 hydrogeologic units fall into four general lithologies: Carbonate rocks, metamorphic rocks, Paleozoic sedimentary rocks, and Triassic sedimentary rocks. Average hydraulic conductivity ranges from about 8.8 feet per day in carbonate units to about .5 feet per day in metamorphic units. The Stonehenge Formation (limestone) has the greatest average hydraulic conductivity--85.2 feet per day in carbonate units to about 0.11 feet per day in the greatest gaining-strem leakage coefficient--16.81 feet per day. Specific yield ranges from 0.06 to 0.09 in carbonate units, and is 0.02 to 0.015, and 0.012 in metamorphic, Paleozoic sedimentary, and Triassic sedimentary units, respectively. Transient simulations were made to determine the effects of four different combinations of natural and artificial stresses. Natural aquifer conditions (no ground-water withdrawals) and actual aquifer conditions

Ground-Water System in the Chimacum Creek Basin and Surface Water/Ground Water Interaction in Chimacum and Tarboo Creeks and the Big and Little Quilcene Rivers, Eastern Jefferson County, Washington

Science.gov (United States)

Simonds, F. William; Longpre, Claire I.; Justin, Greg B.

2004-01-01

A detailed study of the ground-water system in the unconsolidated glacial deposits in the Chimacum Creek Basin and the interactions between surface water and ground water in four main drainage basins was conducted in eastern Jefferson County, Washington. The study will assist local watershed planners in assessing the status of the water resources and the potential effects of ground-water development on surface-water systems. A new surficial geologic map of the Chimacum Creek Basin and a series of hydrogeologic sections were developed by incorporating LIDAR imagery, existing map sources, and drillers' logs from 110 inventoried wells. The hydrogeologic framework outlined in the study will help characterize the occurrence of ground water in the unconsolidated glacial deposits and how it interacts with the surface-water system. Water levels measured throughout the study show that the altitude of the water table parallels the surface topography and ranges from 0 to 400 feet above the North American Vertical Datum of 1988 across the basin, and seasonal variations in precipitation due to natural cycles generally are on the order of 2 to 3 feet. Synoptic stream-discharge measurements and instream mini-piezometers and piezometers with nested temperature sensors provided additional data to refine the positions of gaining and losing reaches and delineate seasonal variations. Chimacum Creek generally gains water from the shallow ground-water system, except near the community of Chimacum where localized losses occur. In the lower portions of Chimacum Creek, gaining conditions dominate in the summer when creek stages are low and ground-water levels are high, and losing conditions dominate in the winter when creek stages are high relative to ground-water levels. In the Quilcene Bay area, three drainage basins were studied specifically to assess surface water/ground water interactions. The upper reaches of Tarboo Creek generally gain water from the shallow ground-water system

Nitrate Removal from Ground Water: A Review

Directory of Open Access Journals (Sweden)

Archna

2012-01-01

Full Text Available Nitrate contamination of ground water resources has increased in Asia, Europe, United States, and various other parts of the world. This trend has raised concern as nitrates cause methemoglobinemia and cancer. Several treatment processes can remove nitrates from water with varying degrees of efficiency, cost, and ease of operation. Available technical data, experience, and economics indicate that biological denitrification is more acceptable for nitrate removal than reverse osmosis and ion exchange. This paper reviews the developments in the field of nitrate removal processes which can be effectively used for denitrifying ground water as well as industrial water.

Implications of ground water chemistry and flow patterns for earthquake studies.

Science.gov (United States)

Guangcai, Wang; Zuochen, Zhang; Min, Wang; Cravotta, Charles A; Chenglong, Liu

2005-01-01

Ground water can facilitate earthquake development and respond physically and chemically to tectonism. Thus, an understanding of ground water circulation in seismically active regions is important for earthquake prediction. To investigate the roles of ground water in the development and prediction of earthquakes, geological and hydrogeological monitoring was conducted in a seismogenic area in the Yanhuai Basin, China. This study used isotopic and hydrogeochemical methods to characterize ground water samples from six hot springs and two cold springs. The hydrochemical data and associated geological and geophysical data were used to identify possible relations between ground water circulation and seismically active structural features. The data for delta18O, deltaD, tritium, and 14C indicate ground water from hot springs is of meteoric origin with subsurface residence times of 50 to 30,320 years. The reservoir temperature and circulation depths of the hot ground water are 57 degrees C to 160 degrees C and 1600 to 5000 m, respectively, as estimated by quartz and chalcedony geothermometers and the geothermal gradient. Various possible origins of noble gases dissolved in the ground water also were evaluated, indicating mantle and deep crust sources consistent with tectonically active segments. A hard intercalated stratum, where small to moderate earthquakes frequently originate, is present between a deep (10 to 20 km), high-electrical conductivity layer and the zone of active ground water circulation. The ground water anomalies are closely related to the structural peculiarity of each monitoring point. These results could have implications for ground water and seismic studies in other seismogenic areas.

Procedures for ground-water investigations

International Nuclear Information System (INIS)

1989-09-01

This manual was developed by the Pacific Northwest Laboratory (PNL) to document the procedures used to carry out and control the technical aspects of ground-water investigations at the PNL. Ground-water investigations are carried out to fulfill the requirements for the US Department of Energy (DOE) to meet the requirements of DOE Orders. Investigations are also performed for various clients to meet the requirements of the Resource Conservation and Recovery Act of 1976 (RCRA) and the Comprehensive Environmental Response, Compensation and Liability Act of 1980 (CERCLA). National standards including procedures published by the American Society for Testing and Materials (ASTM) and the US Geological Survey were utilized in developing the procedures contained in this manual

Demersal fishes and their distribution in estuarine waters of Mahakam Delta, East Kalimantan

Directory of Open Access Journals (Sweden)

IWAN SUYATNA

2010-10-01

Full Text Available Suyatna I, Bratawinata AA, Sidik AS, Ruchaemi A (2011 Demersal fishes and their distribution in estuarine waters of Mahakam Delta, East Kalimantan. Biodiversitas 12: 204-210. The study aimed (i to identify of the demersal fishes, (ii to analyze the diversity and (iii to determine their distribution. Surveys were carried out between August 2009 and January 2010 in Mahakam Delta, East Kalimantan. Data were analyzed using several indices of Shannon Weaver, Sympson, Margalef species richness, and Bray Curtis distance. The canonical correspondence analysis (CCA was also used to correlate between fish species and their environmental factors and to show the fish distribution. Sixty samplings were done using bottom-trawl at various water depths from one to fourty two meters to collect the data. Taxonomically, during the study, 10 orders, 61 families, 87 genera and 131 species of fish with 43340 individuals were identified. Among the families, Leiognathidae was the most important group of fish, they distributed throughout the depths. Meanwhile CCA showed that Leiognathidae and Sciaenidae were observed to be rich in the shallow water. Generally, index of Shannon Weaver, Sympson and Margalef species richness ranged between; 0.52 and 2.48; 0.11 and 0.82; 2.24 and 18.61 respectively. Bray Curtis distance indicated the significant difference of individual number of demersal fishes between shallow and deep waters.

Trace organic chemicals contamination in ground water recharge.

Science.gov (United States)

Díaz-Cruz, M Silvia; Barceló, Damià

2008-06-01

Population growth and unpredictable climate changes will pose high demands on water resources in the future. Even at present, surface water is certainly not enough to cope with the water requirement for agricultural, industrial, recreational and drinking purposes. In this context, the usage of ground water has become essential, therefore, their quality and quantity has to be carefully managed. Regarding quantity, artificial recharge can guarantee a sustainable level of ground water, whilst the strict quality control of the waters intended for recharge will minimize contamination of both the ground water and aquifer area. However, all water resources in the planet are threatened by multiple sources of contamination coming from the extended use of chemicals worldwide. In this respect, the environmental occurrence of organic micropollutants such as pesticides, pharmaceuticals, industrial chemicals and their metabolites has experienced fast growing interest. In this paper an overview of the priority and emerging organic micropollutants in the different source waters used for artificial aquifer recharge purposes and in the recovered water is presented. Besides, some considerations regarding fate and removal of such compounds are also addressed.

40 CFR 141.403 - Treatment technique requirements for ground water systems.

Science.gov (United States)

2010-07-01

... ground water systems. 141.403 Section 141.403 Protection of Environment ENVIRONMENTAL PROTECTION AGENCY (CONTINUED) WATER PROGRAMS (CONTINUED) NATIONAL PRIMARY DRINKING WATER REGULATIONS Ground Water Rule § 141... customer as follows: (i) Chemical disinfection—(A) Ground water systems serving greater than 3,300 people...

Geohydrological and environmental isotope observation of Sishen ground waters

International Nuclear Information System (INIS)

Verhagen, B.Th.; Dziembowski, Z.M.

1985-01-01

The dewatering of Sishen Mine in the northern Cape Province supplies good quality water for the mine and surrounding areas. Using various approaches, attempts are made to quantify the remaining storage of ground water. Geohydrological observations provide an estimate based on extrapolating the thickness of dewatered rock. Environmental isotope observations on various borehole outputs show contrasts between different ground-water bodies and their mixtures and allows for some extrapolations of observed trends. Indications are that previous estimates of storage, based on ground-water level changes, are conservative

Identification of sources and mechanisms of salt-water pollution ground-water quality

International Nuclear Information System (INIS)

Richter, B.C.; Dutton, A.R.; Kreitler, C.W.

1990-01-01

This book reports on salinization of soils and ground water that is widespread in the Concho River watershed and other semiarid areas in Texas and the United States. Using more than 1,200 chemical analyses of water samples, the authors were able to differentiate various salinization mechanisms by mapping salinity patterns and hydrochemical facies and by analyzing isotopic compositions and ionic ratios. Results revealed that in Runnels County evaporation of irrigation water and ground water is a major salinization mechanism, whereas to the west, in Irion and Tom Green Counties, saline water appears to be a natural mixture of subsurface brine and shallowly circulating meteoric water recharged in the Concho River watershed. The authors concluded that the occurrence of poor-quality ground water is not a recent or single-source phenomenon; it has been affected by terracing of farmland, by disposal of oil-field brines into surface pits, and by upward flow of brine from the Coleman Junction Formation via insufficiently plugged abandoned boreholes

Rapid extraction of uranium from sea water using Fe{sub 3}O{sub 4} and humic acid coated Fe{sub 3}O{sub 4} nanoparticles

Energy Technology Data Exchange (ETDEWEB)

Singhal, Pallavi, E-mail: psinghal@barc.gov.in [Homi Bhabha National Institute, Mumbai 400094 (India); Health Physics Division, Bhabha Atomic Research Centre, Mumbai 400085 (India); Jha, Sanjay K. [Homi Bhabha National Institute, Mumbai 400094 (India); Health Physics Division, Bhabha Atomic Research Centre, Mumbai 400085 (India); Pandey, Shailaja P. [Analytical Chemistry Division, Bhabha Atomic Research Centre, Mumbai 400085 (India); Neogy, Suman [Mechanical Metallurgy Division, Bhabha Atomic Research Centre, Mumbai 400085 (India)

2017-08-05

Highlights: • Uranium extraction using Fe{sub 3}O{sub 4} and HA coated Fe{sub 3}O{sub 4} NPs has been demonstrated. • Result indicates uranium extraction from both water and sea water matrix. • With increase in HA coating uranium extraction increases. • Fe{sub 3}O{sub 4}/HA 1 is the best material among synthesized one for uranium extraction. - Abstract: Uranium is one of the most toxic elements present in the environment and a number of methods have been developed for its extraction. Herein we have demonstrated a new method using magnetic nanoparticles (NPs) that can be used for uranium extraction from water and sea water matrix. Fe{sub 3}O{sub 4} and humic acid (HA) coated Fe{sub 3}O{sub 4} NPs with different amount of HA coating were synthesized and uranium sorption from water and sea water matrix was demonstrated. It was observed that sorption increases with increase in amount of HA coating. NPs settlement in presence of magnetic field was monitored where only bare Fe{sub 3}O{sub 4} and Fe{sub 3}O{sub 4}/HA 1 NPs settles while no settlement was observed for Fe{sub 3}O{sub 4}/HA 2 and Fe{sub 3}O{sub 4}/HA 3 NPs. Considering both sorption and particle separation from the matrix Fe{sub 3}O{sub 4}/HA 1 NPs are the best among synthesized ones with maximum sorption capacity of 10.5 mg of U/g of NPs. The results presented here reveal the exceptional potential of magnetic NPs and functionalized magnetic NPs for environmental remediation of uranium and to extract uranium from sea water on which to the best of our knowledge no report is available till now.

Estimating Natural Recharge in a Desert Environment Facing Increasing Ground-Water Demands

Science.gov (United States)

Nishikawa, T.; Izbicki, J. A.; Hevesi, J. A.; Martin, P.

2004-12-01

Ground water historically has been the sole source of water supply for the community of Joshua Tree in the Joshua Tree ground-water subbasin of the Morongo ground-water basin in the southern Mojave Desert. Joshua Basin Water District (JBWD) supplies water to the community from the underlying Joshua Tree ground-water subbasin, and ground-water withdrawals averaging about 960 acre-ft/yr have resulted in as much as 35 ft of drawdown. As growth continues in the desert, ground-water resources may need to be supplemented using imported water. To help meet future demands, JBWD plans to construct production wells in the adjacent Copper Mountain ground-water subbasin. To manage the ground-water resources and to identify future mitigating measures, a thorough understanding of the ground-water system is needed. To this end, field and numerical techniques were applied to determine the distribution and quantity of natural recharge. Field techniques included the installation of instrumented boreholes in selected washes and at a nearby control site. Numerical techniques included the use of a distributed-parameter watershed model and a ground-water flow model. The results from the field techniques indicated that as much as 70 acre-ft/yr of water infiltrated downward through the two principal washes during the study period (2001-3). The results from the watershed model indicated that the average annual recharge in the ground-water subbasins is about 160 acre-ft/yr. The results from the calibrated ground-water flow model indicated that the average annual recharge for the same area is about 125 acre-ft/yr. Although the field and numerical techniques were applied to different scales (local vs. large), all indicate that natural recharge in the Joshua Tree area is very limited; therefore, careful management of the limited ground-water resources is needed. Moreover, the calibrated model can now be used to estimate the effects of different water-management strategies on the ground-water

Ground water hydrology report: Revision 1, Attachment 3. Final

International Nuclear Information System (INIS)

1996-12-01

This report presents ground water hydrogeologic activities for the Maybell, Colorado, Uranium Mill Tailings Remedial Action Project site. The Department of Energy has characterized the hydrogeology, water quality, and water resources at the site and determined that the proposed remedial action would comply with the requirements of the EPA ground water protection standards

Isotope hydrology of ground waters of the Kalahari, Gordonia

International Nuclear Information System (INIS)

Verhagen, B.Th.

1985-01-01

Environmental isotope observations were conducted on ground waters from approximately 50 boreholes covering a substantial part of Gordonia. The quality of these waters ranges from fresh to saline. The observed isotope ratios cover a wide range of values, indicating varied hydrological conditions. The most important conclusions arrived at by this study are: 1. no important regional movement of ground water occurs at present; 2. there is widespread evidence of diffuse rainfall recharge; and 3. an important part of ground-water salinity is derived from the unsaturated zone, during such recharge

NMR Studies of the Vanadium Spin Dynamics and Spin Structure in LiV<sub>2sub>O>4sub>, CaV<sub>2sub>O>4sub>, and (Li<sub>xV>1-xsub>)>3sub>BO>5sub> (x ≈ 0.33, 0.40)

Energy Technology Data Exchange (ETDEWEB)

Zong, Xiaopeng [Iowa State Univ., Ames, IA (United States)

2007-01-01

Strong electron correlation is believed to be an essential and unifying factor in diverse properties of condensed matter systems. Ground states that can arise due to electron correlation effects include Mott insulators, heavy fermion, ferromagnetism and antiferromagnetism, spin glasses, and high-temperature superconductivity. The electronic systems in transition metal oxide compounds are often highly correlated. In this thesis, the author presents experimental studies on three strongly correlated vanadium oxide compounds: LiV<sub>2sub>O>4sub>, (Li<sub>xV>1-xsub>)>3sub>BO>5sub>, and CaV<sub>2sub>O>4sub>, which have completely different ground states.

Ground-water recharge in Fortymile Wash near Yucca Mountain, Nevada, 1992--1993

International Nuclear Information System (INIS)

Savard, C.S.

1994-01-01

Quantification of the ground-water recharge from streamflow in the Fortymile Wash watershed will contribute to regional ground-water studies. Regional ground-water studies are an important component in the studies evaluating the ground-water flow system as a barrier to the potential migration of radionuclides from the potential underground high-level nuclear waste repository. Knowledge gained in understanding the ground-water recharge mechanisms and pathways in the Pah Canyon area, which is 10 km to the northeast of Yucca Mountain, may transfer to Yucca site specific studies. The current data collection network in Fortymile Canyon does not permit quantification of ground-water recharge, however a qualitative understanding of ground-water recharge was developed from these data

Hydrogeology, Ground-Water-Age Dating, Water Quality, and Vulnerability of Ground Water to Contamination in a Part of the Whitewater Valley Aquifer System near Richmond, Indiana, 2002-2003

Science.gov (United States)

Buszka, Paul M.; Watson, Lee R.; Greeman, Theodore K.

2007-01-01

Assessments of the vulnerability to contamination of ground-water sources used by public-water systems, as mandated by the Federal Safe Drinking Water Act Amendments of 1996, commonly have involved qualitative evaluations based on existing information on the geologic and hydrologic setting. The U.S. Geological Survey National Water-Quality Assessment Program has identified ground-water-age dating; detailed water-quality analyses of nitrate, pesticides, trace elements, and wastewater-related organic compounds; and assessed natural processes that affect those constituents as potential, unique improvements to existing methods of qualitative vulnerability assessment. To evaluate the improvement from use of these methods, in 2002 and 2003, the U.S. Geological Survey, in cooperation with the City of Richmond, Indiana, compiled and interpreted hydrogeologic data and chemical analyses of water samples from seven wells in a part of the Whitewater Valley aquifer system in a former glacial valley near Richmond. This study investigated the application of ground-water-age dating, dissolved-gas analyses, and detailed water-quality analyses to quantitatively evaluate the vulnerability of ground water to contamination and to identify processes that affect the vulnerability to specific contaminants in an area of post-1972 greenfield development.

MODFLOW-2000, The U.S. Geological Survey Modular Ground-Water Model - User Guide to Modularization Concepts and the Ground-Water Flow Process

Science.gov (United States)

Harbaugh, Arlen W.; Banta, Edward R.; Hill, Mary C.; McDonald, Michael G.

2000-01-01

MODFLOW is a computer program that numerically solves the three-dimensional ground-water flow equation for a porous medium by using a finite-difference method. Although MODFLOW was designed to be easily enhanced, the design was oriented toward additions to the ground-water flow equation. Frequently there is a need to solve additional equations; for example, transport equations and equations for estimating parameter values that produce the closest match between model-calculated heads and flows and measured values. This report documents a new version of MODFLOW, called MODFLOW-2000, which is designed to accommodate the solution of equations in addition to the ground-water flow equation. This report is a user's manual. It contains an overview of the old and added design concepts, documents one new package, and contains input instructions for using the model to solve the ground-water flow equation.

An imminent human resource crisis in ground water hydrology?

Science.gov (United States)

Stephens, Daniel B

2009-01-01

Anecdotal evidence, mostly from the United States, suggests that it has become increasingly difficult to find well-trained, entry-level ground water hydrologists to fill open positions in consulting firms and regulatory agencies. The future prospects for filling positions that require training in ground water hydrology are assessed by considering three factors: the market, the numbers of qualified students entering colleges and universities, and the aging of the existing workforce. The environmental and water resources consulting industry has seen continuous albeit variable growth, and demand for environmental scientists and hydrologists is expected to increase significantly. Conversely, students' interest and their enrollment in hydrology and water resources programs have waned in recent years, and the interests of students within these departments have shifted away from ground water hydrology in some schools. This decrease in the numbers of U.S. students graduating in hydrology or emphasizing ground water hydrology is coinciding with the aging of and pending retirement of ground water scientists and engineers in the baby boomer generation. We need to both trigger the imagination of students at the elementary school level so that they later want to apply science and math and communicate the career opportunities in ground water hydrology to those high school and college graduates who have acquired the appropriate technical background. Because the success of a consulting firm, research organization, or regulatory agency is derived from the skills and judgment of the employees, human resources will be an increasingly more critical strategic issue for many years.

Documentation of the Santa Clara Valley regional ground-water/surface-water flow model, Santa Clara Valley, California

Science.gov (United States)

Hanson, R.T.; Li, Zhen; Faunt, C.C.

2004-01-01

The Santa Clara Valley is a long, narrow trough extending about 35 miles southeast from the southern end of San Francisco Bay where the regional alluvial-aquifer system has been a major source of water. Intensive agricultural and urban development throughout the 20th century and related ground-water development resulted in ground-water-level declines of more than 200 feet and land subsidence of as much as 12.7 feet between the early 1900s and the mid-1960s. Since the 1960s, Santa Clara Valley Water District has imported surface water to meet growing demands and reduce dependence on ground-water supplies. This importation of water has resulted in a sustained recovery of the ground-water flow system. To help support effective management of the ground-water resources, a regional ground-water/surface-water flow model was developed. This model simulates the flow of ground water and surface water, changes in ground-water storage, and related effects such as land subsidence. A numerical ground-water/surface-water flow model of the Santa Clara Valley subbasin of the Santa Clara Valley was developed as part of a cooperative investigation with the Santa Clara Valley Water District. The model better defines the geohydrologic framework of the regional flow system and better delineates the supply and demand components that affect the inflows to and outflows from the regional ground-water flow system. Development of the model includes revisions to the previous ground-water flow model that upgraded the temporal and spatial discretization, added source-specific inflows and outflows, simulated additional flow features such as land subsidence and multi-aquifer wellbore flow, and extended the period of simulation through September 1999. The transient-state model was calibrated to historical surface-water and ground-water data for the period 197099 and to historical subsidence for the period 198399. The regional ground-water flow system consists of multiple aquifers that are grouped

Investigation of mangrove macroalgae as biomonitors of estuarine metal contamination

Energy Technology Data Exchange (ETDEWEB)

Melville, Felicity [Department of Environmental Sciences/Institute of Water and Environmental Resource Management, University of Technology, Sydney, PO Box 123, Broadway NSW 2007 (Australia)], E-mail: f.melville@cqu.edu.au; Pulkownik, Alex [Department of Environmental Sciences/Institute of Water and Environmental Resource Management, University of Technology, Sydney, PO Box 123, Broadway NSW 2007 (Australia)

2007-11-15

This study examined the potential use of macroalgae epiphytic on mangrove aerial roots as biomonitors of estuarine contamination. The metal concentrations of macroalgae were investigated in four estuaries in the vicinity of Sydney, Australia, and compared to water and sediment metal concentrations over three seasonal surveys. Macroalgal metal concentrations (copper, zinc, cadmium, chromium, lead, nickel, manganese and iron) appeared to be more associated with sediment metal concentrations than water concentrations, suggesting they may be useful biomonitors of estuarine sediment contamination. Algae in the more contaminated estuaries generally contained higher metal concentrations. However, concentrations of iron, nickel and manganese appeared to be similar in the algae despite the varying sediment concentrations, while accumulation of copper, zinc, lead and chromium appeared to be associated with ambient environmental concentrations. The uptake of metals also varied among the different species, suggesting that algal parameters, such as morphology, may also influence metal uptake and accumulation.

Contamination of Ground Water Samples from Well Installations

DEFF Research Database (Denmark)

Grøn, Christian; Madsen, Jørgen Øgaard; Simonsen, Y.

1996-01-01

Leaching of a plasticizer, N-butylbenzenesulfonamide, from ground water multilevel sampling installations in nylon has been demonstrated. The leaching resulted in concentrations of DOC and apparent AOX, both comparable with those observed in landfill contaminated ground waters. It is concluded...... that nylon should not be used in studies of contamination with organic compounds....

Ground water quality evaluation in Beed city, Maharashtra, India ...

African Journals Online (AJOL)

A survey was undertaken to assess the quality of ground water in Beed district of Maharashtra taking both physico-chemical and bacteriological parameters into consideration. The present investigation is aimed to calculate Water Quality Index (WQI) of ground water and to assess the impact of pollutants due to agriculture ...

Geology and ground-water resources of the Douglas basin, Arizona, with a section on chemical quality of the ground water

Science.gov (United States)

Coates, Donald Robert; Cushman, R.L.; Hatchett, James Lawrence

1955-01-01

The Douglas basin is part of a large northwest-trending intermontane valley, known as the Sulphur Spring Valley, which lies in southeastern Arizona, and extends into northeastern Sonora, Mexico. Maturely dissected mountains rise abruptly from long alluvial slopes and culminate in peaks 3,000 to 4,000 feet above the valley floor, Bedrock in the mountain areas confines drainage on the east and west, and an arc of low hills to the north separates the basin from the Willcox basin of the Sulphur Spring Valley. Drainage of the 1,200 square miles in the Douglas basin is southward into Mexico through Whitewater Draw. The mountains include igneous, metamorphic, and sedimentary rocks ranging in age from pre-Cambrian to Tertiary, including Paleozoic and Mesozoic sedimentary rocks that total about 10,000 feet in thickness. The older rocks have been metamorphosed, and all the bedrock has been affected by igneous intrusion, largely in Mesozoic time, and by structural movements, largely in Cenozoic time and extending into the Quaternary period. By the early part of Cenozoic time the major structural features were formed, and mountain ranges had been uplifted above the valley trough along northwest-trending fault zones. Since that time the physiographic features have resulted through erosion of the mountain blocks and the deposition, in places, of more than 2,800 feet of unconsolidated rock debris in the valley. Ground-water supplies of the Douglas basin are developed largely in the saturated zone of the valley-fill sediments. The ground water in the valley fill occurs in thin lenses and strata of sand and gravel, which are interbedded with large thicknesses of silt and day. Scattered gypsum beds and extensive caliche deposits appear at the surface and occur within the valley fill at various depths. Although the valley-fill sediments are as much as 2,800 feet thick, the uppermost 300 feet or so are the most permeable. Ground water originates as precipitation in the mountain areas

Ground rubber: Sorption media for ground water containing benzene and O-xylene

International Nuclear Information System (INIS)

Kershaw, D.S.; Pamukcu, S.

1997-01-01

The purpose of the current study is to examine the ability of ground rubber to sorb benzene and O-xylene from water contained with aromatic hydrocarbons. The study consisted of running both batch and packed bed column tests to determine the sorption capacity, the required sorption equilibration time, and the flow through utilization efficiency of ground rubber under various contact times when exposed to water contaminated with various amounts of benzene or O-xylene. Initial batch test results indicate that ground rubber can attain equilibrium sorption capacities up to 1.3 or 8.2 mg of benzene or O-xylene, respectively, per gram of tire rubber at solution equilibrium concentrations of 10 mg/L. Packed bed column tests indicate that ground tire rubber has on the average a 40% utilization rate when a hydraulic residence time of 15 min is used. Possible future uses of round rubber as a sorption media could include, but are not limited to, the use of ground rubber as an aggregate in slurry cutoff walls that are in contact with petroleum products. Ground rubber could also be used as a sorption media in pump-and-treat methodologies or as a sorption media in in-situ reactive permeable barriers

An empirical assessment of near-source strong ground motion for a 6.6 m{sub b} (7.5 M{sub S}) earthquake in the Eastern United States

Energy Technology Data Exchange (ETDEWEB)

Campbell, Kenneth W

1984-06-01

To help assess the impact of the current U.S. Geological Survey position on the seismic safety of nuclear power plants in the Eastern United States (EUS), several techniques for estimating near-source strong ground motion for a Charleston size earthquake were evaluated. The techniques for estimating the near-source strong ground motion for a 6.6 m{sub b} (7.5 M{sub S}) in the Eastern United States which were assessed are methods based on site specific analyses, semi-theoretical scaling techniques, and intensity-based estimates. The first involves the statistical analysis of ground motion records from earthquakes and recording stations having the same general characteristics (earthquakes with magnitudes of 7.5 M{sub S} or larger, epicentral distances of 25 km or less, and sites of either soil or rock). Some recommendations for source and characterization scaling of the bias resulting primarily from an inadequate sample of near-source recordings from earthquakes of large magnitude are discussed. The second technique evaluated requires that semi-theoretical estimates of peak ground motion parameters for a 6.6 m{sub b} (7.5 M{sub S}) earthquake be obtained from scaling relations. Each relation uses a theoretical expression between peak acceleration magnitude and distance together with available strong motion data (majority coming from California) to develop a scaling relation appropriate for the Eastern United States. None of the existing ground motion models for the EUS include the potential effects of source or site characteristics. Adjustments to account for fault mechanisms, site topography, site geology, and the size and embedment of buildings are discussed. The final approach used relations between strong ground motion parameters and Modified Mercalli Intensity in conjunction with two methods to estimate peak parameters for a 6.6 m{sub s} (7.5 M{sub S}) earthquake. As with other techniques, adjustment of peak acceleration estimates are discussed. Each method

Water budget for SRP burial ground area

International Nuclear Information System (INIS)

Hubbard, J.E.; Emslie, R.H.

1984-01-01

Radionuclide migration from the SRP burial ground for solid low-level waste has been studied extensively. Most of the buried radionuclides are fixed on the soil and show negligible movement. The major exception is tritium, which when leached from the waste by percolating rainfall, forms tritiated water and moves with the groundwater. The presence of tritium has been useful in tracing groundwater flow paths to outcrop. A subsurface tritium plume moving from the southwest corner of the burial ground toward an outcrop near Four Mile Creek has been defined. Groundwater movement is so slow that much of the tritium decays before reaching the outcrop. The burial ground tritium plume defined to date is virtually all in the uppermost sediment layer, the Barnwell Formation. The purpose of the study reported in this memorandum was to investigate the hypothesis that deeper flow paths, capable of carrying substantial amounts of tritium, may exist in the vicinity of the burial ground. As a first step in seeking deeper flow paths, a water budget was constructed for the burial ground site. The water budget, a materials balance used by hydrologists, is expressed in annual area inches of rainfall. Components of the water budget for the burial ground area were analyzed to determine whether significant flow paths may exist below the tan clay. Mean annual precipitation was estimated as 47 inches, with evapotranspiration, run-off, and groundwater recharge estimated as 30, 2, and 15 inches, respectively. These estimates, when combined with groundwater discharge data, suggest that 5 inches of the groundwater recharge flow above the tan clay and that 10 inches flow below the tan clay. Therefore, two-thirds of the groundwater recharge appears to follow flow paths that are deeper than those previously found. 13 references, 10 figures, 5 tables

Modeling decadal timescale interactions between surface water and ground water in the central Everglades, Florida, USA

Science.gov (United States)

Harvey, Judson W.; Newlin, Jessica T.; Krupa, Steven L.

2006-04-01

Surface-water and ground-water flow are coupled in the central Everglades, although the remoteness of this system has hindered many previous attempts to quantify interactions between surface water and ground water. We modeled flow through a 43,000 ha basin in the central Everglades called Water Conservation Area 2A. The purpose of the model was to quantify recharge and discharge in the basin's vast interior areas. The presence and distribution of tritium in ground water was the principal constraint on the modeling, based on measurements in 25 research wells ranging in depth from 2 to 37 m. In addition to average characteristics of surface-water flow, the model parameters included depth of the layer of 'interactive' ground water that is actively exchanged with surface water, average residence time of interactive ground water, and the associated recharge and discharge fluxes across the wetland ground surface. Results indicated that only a relatively thin (8 m) layer of the 60 m deep surfical aquifer actively exchanges surface water and ground water on a decadal timescale. The calculated storage depth of interactive ground water was 3.1 m after adjustment for the porosity of peat and sandy limestone. Modeling of the tritium data yielded an average residence time of 90 years in interactive ground water, with associated recharge and discharge fluxes equal to 0.01 cm d -1. 3H/ 3He isotopic ratio measurements (which correct for effects of vertical mixing in the aquifer with deeper, tritium-dead water) were available from several wells, and these indicated an average residence time of 25 years, suggesting that residence time was overestimated using tritium measurements alone. Indeed, both residence time and storage depth would be expected to be overestimated due to vertical mixing. The estimate of recharge and discharge (0.01 cm d -1) that resulted from tritium modeling therefore is still considered reliable, because the ratio of residence time and storage depth (used to

Ground-water monitoring at the Hanford Site, January-December 1984

Energy Technology Data Exchange (ETDEWEB)

Cline, C.S.; Rieger, J.T.; Raymond, J.R.

1985-09-01

This program is designed to evaluate existing and potential pathways of exposure to radioactivity and hazardous chemicals from site operations. This document contains an evaluation of data collected during CY 1984. During 1984, 339 monitoring wells were sampled at various times for radioactive and nonradioactive constituents. Two of these constituents, specifically, tritium and nitrate, have been selected for detailed discussion in this report. Tritium and nitrate in the primary plumes originating from the 200 Areas continue to move generally eastward toward the Columbia River in the direction of ground-water flow. The movement within these plumes is indicated by changes in trends within the analytical data from the monitoring wells. No discernible impact on ground water has yet been observed from the start-up of the PUREX plant in December 1983. The shape of the present tritium plume is similar to those described in previous ground-water monitoring reports, although slight changes on the outer edges have been noted. Radiological impacts from two potential pathways for radionuclide transport in ground water to the environment are discussed in this report. The pathways are: (1) human consumption of ground water from onsite wells, and (2) seepage of ground water into the Columbia River. Concentrations of tritium in spring samples that were collected and analyzed in 1983, and in wells sampled adjacent to the Columbia River in 1984 confirmed that constituents in the ground water are entering the river via springs and subsurface flow. The primary areas where radionuclides enter the Columbia River via ground-water flow are the 100-N and 300 Areas and the shoreline adjacent to the Hanford Townsite. 44 refs., 25 figs., 11 tabs.

An inversion of the estuarine circulation by sluice water discharge and its impact on suspended sediment transport

Science.gov (United States)

Schulz, Kirstin; Gerkema, Theo

2018-01-01

The Wadden Sea is characterized by a complex topography of branching channels and intertidal flats, in which the interplay between fresh water discharges, wind forcing and the tidal current causes sediment transport rates and direction to be highly variable in space and time. During three field campaigns, indications of a negative estuarine circulation have been found in a channel adjacent to the coast in the Western Dutch Wadden Sea. Contrary to the classical picture of estuarine circulation, a periodic density stratification was observed that builds up during flood and breaks down during ebb. This can be related to a large freshwater source at the mouth of the channel, the sluice in Kornwerderzand. In this study, observations of this phenomenon are presented, and with the help of a numerical model the different drivers for residual suspended matter transport in this area, namely tidal asymmetries in the current velocity and the above mentioned periodic stratification, are investigated. It is found that the residual current in the area of interest points in ebb direction, caused by both the elongated ebb flow phase and the periodic stratification. On the contrary, the stronger flood currents cause a transport of suspended matter in flood direction. This transport is counteracted and therefore diminished by the effects of the sluice discharge.

Inputs and distributions of synthetic musk fragrances in an estuarine and coastal environment; a case study

International Nuclear Information System (INIS)

Sumner, Nicola R.; Guitart, Carlos; Fuentes, Gustavo; Readman, James W.

2010-01-01

Synthetic musks are ubiquitous contaminants in the environment. Compartmental distributions (dissolved, suspended particle associated and sedimentary) of the compounds throughout an axial estuarine transect and in coastal waters are reported. High concentrations of Galaxolide (HHCB) and Tonalide (AHTN) (987-2098 ng/L and 55-159 ng/L, respectively) were encountered in final effluent samples from sewage treatment plants (STPs) discharging into the Tamar and Plym Estuaries (UK), with lower concentrations of Celestolide (ADBI) (4-13 ng/L), Phantolide (AHMI) (6-9 ng/L), musk xylene (MX) (4-7 ng/L) and musk ketone (MK) (18-30 ng/L). Rapid dilution from the outfalls is demonstrated with resulting concentrations of HHCB spanning from 5 to 30 ng/L and those for AHTN from 3 to 15 ng/L. The other musks were generally not detected in the estuarine and coastal waters. The suspended particulate matter (SPM) and sedimentary profiles and compositions (HHCB:AHTN ratios) generally reflect the distribution in the water column with highest concentrations adjacent to sewage outfalls. - Synthetic musks were determined in coastal environmental compartments along an estuarine transect indicating their ubiquitous occurrence in transitional waters.

Inputs and distributions of synthetic musk fragrances in an estuarine and coastal environment; a case study

Energy Technology Data Exchange (ETDEWEB)

Sumner, Nicola R. [School of Earth, Ocean and Environmental Science, University of Plymouth, Drake Circus, Plymouth PL4 8AA (United Kingdom); Plymouth Marine Laboratory, Prospect Place, The Hoe, Plymouth PL1 3DH (United Kingdom); Guitart, Carlos, E-mail: guitart.carlos@gmail.co [Plymouth Marine Laboratory, Prospect Place, The Hoe, Plymouth PL1 3DH (United Kingdom); Fuentes, Gustavo [Instituto Universitario de Tecnologia del Mar (IUTEMAR), Fundacion La Salle de Ciencias Naturales, Margarita Island (Venezuela, Bolivarian Republic of); Readman, James W. [Plymouth Marine Laboratory, Prospect Place, The Hoe, Plymouth PL1 3DH (United Kingdom)

2010-01-15

Synthetic musks are ubiquitous contaminants in the environment. Compartmental distributions (dissolved, suspended particle associated and sedimentary) of the compounds throughout an axial estuarine transect and in coastal waters are reported. High concentrations of Galaxolide (HHCB) and Tonalide (AHTN) (987-2098 ng/L and 55-159 ng/L, respectively) were encountered in final effluent samples from sewage treatment plants (STPs) discharging into the Tamar and Plym Estuaries (UK), with lower concentrations of Celestolide (ADBI) (4-13 ng/L), Phantolide (AHMI) (6-9 ng/L), musk xylene (MX) (4-7 ng/L) and musk ketone (MK) (18-30 ng/L). Rapid dilution from the outfalls is demonstrated with resulting concentrations of HHCB spanning from 5 to 30 ng/L and those for AHTN from 3 to 15 ng/L. The other musks were generally not detected in the estuarine and coastal waters. The suspended particulate matter (SPM) and sedimentary profiles and compositions (HHCB:AHTN ratios) generally reflect the distribution in the water column with highest concentrations adjacent to sewage outfalls. - Synthetic musks were determined in coastal environmental compartments along an estuarine transect indicating their ubiquitous occurrence in transitional waters.

Geohydrology and ground-water quality beneath the 300 Area, Hanford Site, Washington

International Nuclear Information System (INIS)

Lindberg, J.W.; Bond, F.W.

1979-06-01

Ground water enters the 300 Area from the northwest, west, and southwest. However, throughout most of the 300 Area, the flow is to the east and southeast. Ground water flows to the northeast only in the southern portion of the 300 Area. Variations in level of the Columbia River affected the ground-water system by altering the level and shape of the 300 Area watertable. Large quantities of process waste water, when warmed during summer months by solar radiation or cooled during winter months by ambient air temperature, influenced the temperature of the ground water. Leaking pipes and the intentional discharge of waste water (or withdrawal of ground water) affected the ground-water system in the 300 Area. Water quality tests of Hanford ground water in and adjacent to the 300 Area showed that in the area of the Process Water Trenches and Sanitary Leaching Trenches, calcium, magnesium, sodium, bicarbonate, and sulfate ions are more dilute, and nitrate and chloride ions are more concentrated than in surrounding areas. Fluoride, uranium, and beta emitters are more concentrated in ground water along the bank of the Columbia River in the central and southern portions of the 300 Area and near the 340 Building. Test wells and routine ground-water sampling are adequate to point out contamination. The variable Thickness Transient (VTT) Model of ground-water flow in the unconfined aquifer underlying the 300 Area has been set up, calibrated, and verified. The Multicomponent Mass Transfer (MMT) Model of distribution of contaminants in the saturated regime under the 300 Area has been set up, calibrated, and tested

Questa baseline and pre-mining ground-water quality investigation. 5. Well installation, water-level data, and surface- and ground-water geochemistry in the Straight Creek drainage basin, Red River Valley, New Mexico, 2001-03

Science.gov (United States)

Naus, Cheryl A.; McCleskey, R. Blaine; Nordstrom, D. Kirk; Donohoe, Lisa C.; Hunt, Andrew G.; Paillet, Frederick L.; Morin, Roger H.; Verplanck, Philip L.

2005-01-01

The U.S. Geological Survey, in cooperation with the New Mexico Environment Department, is investigating the pre-mining ground-water chemistry at the Molycorp molybdenum mine in the Red River Valley, northern New Mexico. The primary approach is to determine the processes controlling ground-water chemistry at an unmined, off-site, proximal analog. The Straight Creek drainage basin, chosen for this purpose, consists of the same quartz-sericite-pyrite altered andesitic and rhyolitic volcanic rock of Tertiary age as the mine site. The weathered and rugged volcanic bedrock surface is overlain by heterogeneous debris-flow deposits that interfinger with alluvial deposits near the confluence of Straight Creek and the Red River. Pyritized rock in the upper part of the drainage basin is the source of acid rock drainage (pH 2.8-3.3) that infiltrates debris-flow deposits containing acidic ground water (pH 3.0-4.0) and bedrock containing water of circumneutral pH values (5.6-7.7). Eleven observation wells were installed in the Straight Creek drainage basin. The wells were completed in debris-flow deposits, bedrock, and interfingering debris-flow and Red River alluvial deposits. Chemical analyses of ground water from these wells, combined with chemical analyses of surface water, water-level data, and lithologic and geophysical logs, provided information used to develop an understanding of the processes contributing to the chemistry of ground water in the Straight Creek drainage basin. Surface- and ground-water samples were routinely collected for determination of total major cations and selected trace metals; dissolved major cations, selected trace metals, and rare-earth elements; anions and alkalinity; and dissolved-iron species. Rare-earth elements were determined on selected samples only. Samples were collected for determination of dissolved organic carbon, mercury, sulfur isotopic composition (34S and 18O of sulfate), and water isotopic composition (2H and 18O) during

Shallow ground-water conditions, Tom Green County, Texas

Science.gov (United States)

Lee, J.N.

1986-01-01

Most of the water needs of Tom Green County, Texas, are supplied by ground water; however, the city of San Angelo is supplied by surface water. Groundwater withdrawals during 1980 (latest year for which data are available) in Tom Green County totaled about 15,300 acre-feet, all derived from shallow aquifers. Shallow aquifers in this report refer to the ground-water system generally less than 400 feet deep that contains water with less than a 10,000 milligrams per liter concentration of dissolved solids; aquifers comprising this system include: The Leona, Comanche Peak, Trinity, Blaine, San Angelo, Choza, Bullwagon, Vale, Standpipe, and Arroyo aquifers.

Monitoring and sampling perched ground water in a basaltic terrain

International Nuclear Information System (INIS)

Hubbell, J.M.

1990-01-01

Perched ground water zones can provide significant information on water and contaminant movement. This paper presents information about perched ground water obtained from drilling and monitoring at a hazardous and radioactive waste disposal site at the Idaho National Engineering Laboratory. Six of forty-five wells drilled at the Radioactive Waste Management Complex have detected perched water in basalts above sedimentary interbeds. This paper describes the distribution and characteristics of perched ground water. It discusses perched water below the surficial sediments in wells at the RWMC, the characteristics of chemical constituents found in perched water, the implications for contaminant transport in the unsaturated zone of water, and the lateral extent of perched water. Recommendations are made to increase the probability of detecting and sampling low yield perched water zones. 6 refs., 6 figs., 2 tabs

Hydrochemical and Isotopic Assessment of Ground Water in Eastern Desert, Egypt

International Nuclear Information System (INIS)

Atiti, S.Y.; Ali, M.M.; Yousef, L.A.; Dessouki, H.A.

2011-01-01

The recharge rate is the most critical factor to ground water resources especially in semi- arid and arid areas. Fourteen representative ground water samples were collected from South Eastern Desert of Egypt and subjected to chemical and isotopic composition. The chemical data reported that, the alkalinity (ph) ranges between 6.5 and 8.5, the salinity of water ranges between 396 and 7874 ppm, sodium is the most dominant cation and chloride is the most dominant anion. The concentration of trace elements (Fe, Pb, Cd, Ni, Cu, Zn, and Mn) was analyzed to evaluate the suitability for drinking and irrigation. Uranium and thorium concentrations were found within the safe limit. Most of ground water was found suitable for drinking water, laundry, irrigation, building, industrial, livestock and poultry. The environmental stable isotopes (D and 18 O) and the radioactive isotope 3 H were evaluated for water samples of the investigated area to focus on the origin of the ground water, sources of recharging and the water rock interaction between aquifers and water. The isotopic compositions of these ground water samples indicated that, there are three different sources of recharge; paleo-water, local precipitation and rain water

Ground-water quality beneath solid-waste disposal sites at anchorage, Alaska

Science.gov (United States)

Zenone, Chester; Donaldson, D.E.; Grunwaldt, J.J.

1975-01-01

Studies at three solid-waste disposal sites in the Anchorage area suggest that differences in local geohydrologic conditions influence ground-water quality. A leachate was detected in ground water within and beneath two sites where the water table is very near land surface and refuse is deposited either at or below the water table in some parts of the filled areas. No leachate was detected in ground water beneath a third site where waste disposal is well above the local water table.

Ground-water pollution determined by boron isotope systematics

International Nuclear Information System (INIS)

Vengosh, A.; Kolodny, Y.; Spivack, A.J.

1998-01-01

Boron isotopic systematics as related to ground-water pollution is reviewed. We report isotopic results of contaminated ground water from the coastal aquifers of the Mediterranean in Israel, Cornia River in north-western Italy, and Salinas Valley, California. In addition, the B isotopic composition of synthetic B compounds used for detergents and fertilizers was investigated. Isotopic analyses were carried out by negative thermal ionization mass spectrometry. The investigated ground water revealed different contamination sources; underlying saline water of a marine origin in saline plumes in the Mediterranean coastal aquifer of Israel (δ 11 B=31.7 per mille to 49.9 per mille, B/Cl ratio ∼1.5x10 -3 ), mixing of fresh and sea water (25 per mille to 38 per mille, B/Cl∼7x10 -3 ) in saline water associated with salt-water intrusion to Salinas Valley, California, and a hydrothermal contribution (high B/Cl of ∼0.03, δ 11 B=2.4 per mille to 9.3 per mille) in ground water from Cornia River, Italy. The δ 11 B values of synthetic Na-borate products (-0.4 per mille to 7.5 per mille) overlap with those of natural Na-borate minerals (-0.9 per mille to 10.2 per mille). In contrast, the δ 11 B values of synthetic Ca-borate and Na/Ca borate products are significantly lower (-15 per mille to -12.1 per mille) and overlap with those of the natural Ca-borate minerals. We suggest that the original isotopic signature of the natural borate minerals is not modified during the manufacturing process of the synthetic products, and it is controlled by the crystal chemistry of borate minerals. The B concentrations in pristine ground-waters are generally low ( 11 B=39 per mille), salt-water intrusion and marine-derived brines (40 per mille to 60 per mille) are sharply different from hydrothermal fluids (δ 11 B=10 per mille to 10 per mille) and anthropogenic sources (sewage effluent: δ 11 B=0 per mille to 10 per mille; boron-fertilizer: δ 11 B=-15 per mille to 7 per mille). some

An assessment of landscape characteristics affecting estuarine nitrogen loading in an urban watershed.

Science.gov (United States)

Yang, Xiaojun

2012-02-01

Exploring the quantitative association between landscape characteristics and the ecological conditions of receiving waters has recently become an emerging area for eco-environmental research. While the landscape-water relationship research has largely targeted on inland aquatic systems, there has been an increasing need to develop methods and techniques that can better work with coastal and estuarine ecosystems. In this paper, we present a geospatial approach to examine the quantitative relationship between landscape characteristics and estuarine nitrogen loading in an urban watershed. The case study site is in the Pensacola estuarine drainage area, home of the city of Pensacola, Florida, USA, where vigorous urban sprawling has prompted growing concerns on the estuarine ecological health. Central to this research is a remote sensor image that has been used to extract land use/cover information and derive landscape metrics. Several significant landscape metrics are selected and spatially linked with the nitrogen loading data for the Pensacola bay area. Landscape metrics and nitrogen loading are summarized by equal overland flow-length rings, and their association is examined by using multivariate statistical analysis. And a stepwise model-building protocol is used for regression designs to help identify significant variables that can explain much of the variance in the nitrogen loading dataset. It is found that using landscape composition or spatial configuration alone can explain most of the nitrogen loading variability. Of all the regression models using metrics derived from a single land use/cover class as the independent variables, the one from the low density urban gives the highest adjusted R-square score, suggesting the impact of the watershed-wide urban sprawl upon this sensitive estuarine ecosystem. Measures towards the reduction of non-point source pollution from urban development are necessary in the area to protect the Pensacola bay ecosystem and its

Report of analyses for light hydrocarbons in ground water

International Nuclear Information System (INIS)

Dromgoole, E.L.

1982-04-01

This report contains on microfiche the results of analyses for methane, ethane, propane, and butane in 11,659 ground water samples collected in 47 western and three eastern 1 0 x 2 0 quadrangles of the National Topographic Map Series (Figures 1 and 2), along with a brief description of the analytical technique used and some simple, descriptive statistics. The ground water samples were collected as part of the National Uranium Resource Evaluation (NURE) hydrogeochemical and stream sediment reconnaissance. Further information on the ground water samples can be obtained by consulting the NURE data reports for the individual quadrangles. This information includes (1) measurements characterizing water samples (pH, conductivity, and alkalinity), (2) physical measurements, where applicable (water temperature, well description, and other measurements), and (3) elemental analyses

High efficient multifunctional Ag{sub 3}PO{sub 4} loaded hydroxyapatite nanowires for water treatment

Energy Technology Data Exchange (ETDEWEB)

Li, Yaling; Zhou, Hangyu; Zhu, Genxing [Center for Biomaterials and Biopathways, Department of Chemistry, Zhejiang University, Hangzhou (China); Shao, Changyu; Pan, Haihua; Xu, Xurong [Center for Biomaterials and Biopathways, Department of Chemistry, Zhejiang University, Hangzhou (China); Qiushi Academy for Advanced Studies, Zhejiang University (China); Tang, Ruikang, E-mail: rtang@zju.edu.cn [Center for Biomaterials and Biopathways, Department of Chemistry, Zhejiang University, Hangzhou (China); Qiushi Academy for Advanced Studies, Zhejiang University (China)

2015-12-15

Highlights: • The multifunctional Ag{sub 3}PO{sub 4} loaded hydroxyapatite (HAP) nanowires were synthesized via a facile in-situ precipitation method. • By optimizing the initial concentration of AgNO{sub 3}, the well-distributed Ag{sub 3}PO{sub 4}/HAP composites could be achieved. • The Ag{sub 3}PO{sub 4}/HAP composites showed excellent photocatalytic performance for the decomposition of dyes under visible light irradiation. • The maximum absorption capacity of the Ag{sub 3}PO{sub 4}/HAP composites for Pb(II) was 250 mg/g, approximately three times as that of pure HAP. • The Ag{sub 3}PO{sub 4}/HAP composites also exhibited excellent antibacterial activities even at relative low concentrations. - Abstract: Organic, inorganic, and biological pollutants are typical water contaminants and they seriously affect water quality. In this study, we suggested that a novel multifunctional Ag{sub 3}PO{sub 4} loaded hydroxyapatite (HAP) material can remove the typical pollutants from water. The Ag{sub 3}PO{sub 4}/HAP composites were synthesized facilely via in-situ precipitation of Ag{sub 3}PO{sub 4} on the pre-existing HAP nanowires. By optimizing the composition of Ag{sub 3}PO{sub 4} and HAP, the material could achieve an optimal photocatalytic activity to decompose rhodamine B (RhB), methyl orange (MO) and methylene blue (MB) under visible light irradiations with enhanced pH stability. Besides, the adsorption of Pb(II) on the Ag{sub 3}PO{sub 4}/HAP reached a maximum capacity of 250 mg/g and this value was approximately three times as that of pure HAP. Furthermore, the composite material exhibited excellent antibacterial activities towards gram-negative bacterium (Escherichia coli) and gram-positive bacterium (Stphylococcus aureus). The results highlighted the cooperative effect between Ag{sub 3}PO{sub 4} and hydroxyapatite (HAP). The simultaneous removals of dyes, toxic metal ions, and bacteria with a high efficiency followed an easy approach for the purification

North Inlet-Winyah Bay National Estuarine Research Reserve’s (NERR) Estuarine Surface Water Nutrient, Suspended Sediment, and Chlorophyll a Data for the North Inlet and Winyah Bay Estuaries, Georgetown, South Carolina: 2002-2004

Data.gov (United States)

Baruch Institute for Marine and Coastal Sciences, Univ of South Carolina — National Estuarine Research Reserve System The National Estuarine Research Reserve System was established by the Coastal Zone Management Act of 1972 (as amended) and...

Surface- and ground-water relations on the Portneuf river, and temporal changes in ground-water levels in the Portneuf Valley, Caribou and Bannock Counties, Idaho, 2001-02

Science.gov (United States)

Barton, Gary J.

2004-01-01

The State of Idaho and local water users are concerned that streamflow depletion in the Portneuf River in Caribou and Bannock Counties is linked to ground-water withdrawals for irrigated agriculture. A year-long field study during 2001 02 that focused on monitoring surface- and ground-water relations was conducted, in cooperation with the Idaho Department of Water Resources, to address some of the water-user concerns. The study area comprised a 10.2-mile reach of the Portneuf River downstream from the Chesterfield Reservoir in the broad Portneuf Valley (Portneuf River Valley reach) and a 20-mile reach of the Portneuf River in a narrow valley downstream from the Portneuf Valley (Pebble-Topaz reach). During the field study, the surface- and ground-water relations were dynamic. A losing river reach was delineated in the middle of the Portneuf River Valley reach, centered approximately 7.2 miles downstream from Chesterfield Reservoir. Two seepage studies conducted in the Portneuf Valley during regulated high flows showed that the length of the losing river reach increased from 2.6 to nearly 6 miles as the irrigation season progressed.Surface- and ground-water relations in the Portneuf Valley also were characterized from an analysis of specific conductance and temperature measurements. In a gaining reach, stratification of specific conductance and temperature across the channel of the Portneuf River was an indicator of ground water seeping into the river.An evolving method of using heat as a tracer to monitor surface- and ground-water relations was successfully conducted with thermistor arrays at four locations. Heat tracing monitored a gaining reach, where ground water was seeping into the river, and monitored a losing reach, where surface water was seeping down through the riverbed (also referred to as a conveyance loss), at two locations.Conveyance losses in the Portneuf River Valley reach were greatest, about 20 cubic feet per second, during the mid-summer regulated

Ground-Water Flow, 2004-07, and Water Quality, 1992-2007, in McBaine Bottoms, Columbia, Missouri

Science.gov (United States)

Smith, Brenda Joyce; Richards, Joseph M.

2008-01-01

The U.S. Geological Survey, in cooperation with the city of Columbia, Missouri, and the Missouri Department of Conservation, collected ground-water quality data, surface-water quality data, and water-level data in McBaine Bottoms, southwest of Columbia. McBaine Bottoms, adjacent to the Missouri River, is the location of the municipal-supply well field for the city of Columbia, the city of Columbia wastewater-treatment wetlands, and the Missouri Department of Conservation Eagle Bluffs Conservation Area. This report describes the ground-water flow and water quality of McBaine Bottoms and provides information to better understand the interaction between treated effluent from the wetlands used on the Eagle Bluffs Conservation Area and the water in the alluvial aquifer that is pumped from the city of Columbia municipal-supply well field. Changes in major chemical constituent concentrations have been detected at several sampling sites between pre- and post-effluent application data. Analysis of post-effluent data indicates substantial changes in calcium, potassium, sodium, chloride, and sulfate concentrations in ground water. These changes became apparent shortly after the beginning of the operation of the wastewater-treatment wetland in 1994 and the formation of the Eagle Bluffs Conservation Area, which uses the treated effluent as a water source for the management of migratory water fowl. The changes have continued throughout the 15 years of sample collection. The concentrations of these major chemical constituents are on the mixing continuum between pre-effluent ground water as one end member and the treated wastewater effluent as the other end member. For monitoring wells that had changes in major chemical constituent concentrations, the relative percentage of treated effluent in the ground water, assuming chloride is conservative, ranged from 6 to 88 percent. Twenty-two monitoring wells throughout McBaine Bottoms have been affected by effluent based on chloride

Theoretical aspects on the phenomenon of contamination of ground waters

International Nuclear Information System (INIS)

Echeverri, G.E.

1998-01-01

The phenomenon of contamination of ground waters and the destination of certain constituents of the water keep in mind diverse mechanisms of physical nature, chemistry and biological; in this work it is consigned in a concise way, the theoretical aspects of these topics, that is to say, the basic principles of the ground water hydraulics, the fundamental concepts of the physics of the movement and the chemistry of the ground water, as well as the equations that govern the phenomenon of contamination of the mass of water contained in the interstices of the floors and the rocks, broadly used in the mathematical modeling of the phenomenon

Pesticide and Water management alternatives to mitigate potential ground-water contamination for selected counties in Utah

OpenAIRE

Ehteshami, Majid; Requena, Antonio M.; Peralta, R. C.; Deer, Howard M.; Hill, Robert W.; Ranjha, Ahmad Yar

1990-01-01

Production of adequate supplies of food and fiber currently requires that pesticides be used to limit crop losses from insects, pathogens, weeds and other pests. Although pesticides are necessary in today's agriculture, they can be a serious problem if they reach and contaminate ground water, especially in places where drinking water needs are supplied from ground water. The relative reduction of potential ground-water contamination due to agricultural use of pesticides was analyzed for parti...

Ground-water surveillance at the Hanford Site for CY 1982

International Nuclear Information System (INIS)

Eddy, P.A.; Prater, L.S.; Rieger, J.T.

1983-06-01

Operations at the Hanford Site since 1944 have resulted in the discharge of large volumes of process cooling water and other waste waters to the ground. These effluents, which have reached the unconfined ground water, contain low levels of radioactive and chemical substances. The movement of these constituents in the unconfined ground water is monitored as part of the Ground-Water Surveillance Program. During 1982, 324 monitoring wells were sampled at various times for radioactive and chemical constituents. Tritium are the primary ones used to monitor the movement of the ground water. This report describes recent changes in the configuration of the tritium and nitrate plumes. The tritium plume continues to show increasing concentrations near the Columbia River. While it is mapped as having reached the Columbia River, its contribution to the river has not been distinguished from other sources at this time. The general plume configuration is much the same as in 1978, 1979, 1980, and 1981. The size of the nitrate plume appears stable. Concentrations of nitrate in the vicinity of the 100-H Area continue to be high as a result of past leaks from an evaporation facility

Geotechnics - the key to ground water protection

DEFF Research Database (Denmark)

Baumann, Jens; Foged, Niels; Jørgensen, Peter

2000-01-01

During the past 5 to 10 years research into ground water protection has proved that fractures in clay till may increase the hydraulic conductivity and herby the vulnerability of the ground water considerably. However, research has not identified a non-expensive and efficient method to map...... the fracture conditions of the various clay tills. Tests performed at the Danish Geotechnical Institute with large undisturbed columns of clay till show that there is a relation between the strength of the clay till and the hydraulic conductivity. Geotechnical methods may therefore be the key to determine...

Influence of surface mining on ground water (effects and possibilities of prevention)

Energy Technology Data Exchange (ETDEWEB)

Libicki, J

1977-01-01

This article analyzes the negative impact of surface mining on ground water. The effects of water depression on water supply for households and industry, and for vegetation and agriculture are evaluated. The negative impact of lowering the ground water level under various water conditions are analyzed: (1) vegetation is supplied with water only by rainfall, (2) vegetation is supplied with water in some seasons by rainfall and in some by ground water, and (3) vegetation uses ground water only. The impact of deteriorating water supply on forests is discussed. Problems connected with storage of waste materials in abandoned surface mines are also discussed. The influence of black coal ash and waste material from coal preparation plants on ground water is analyzed: penetration of some elements and chemical compounds to the ground water and its pollution. Some preventive measures are proposed: injection of grout in the bottom and walls of storage areas to reduce their permeability (organic resins can also be used but they are more expensive). The distance between injection boreholes should be 15 to 20 m. Covering the bottom of the storage area with plastic sheets can also be applied.

Insights on the Optical Properties of Estuarine DOM - Hydrological and Biological Influences.

Directory of Open Access Journals (Sweden)

Luísa Santos

Full Text Available Dissolved organic matter (DOM in estuaries derives from a diverse array of both allochthonous and autochthonous sources. In the estuarine system Ria de Aveiro (Portugal, the seasonality and the sources of the fraction of DOM that absorbs light (CDOM were inferred using its optical and fluorescence properties. CDOM parameters known to be affected by aromaticity and molecular weight were correlated with physical, chemical and meteorological parameters. Two sites, representative of the marine and brackish water zones of the estuary, and with different hydrological characteristics, were regularly surveyed along two years, in order to determine the major influences on CDOM properties. Terrestrial-derived compounds are the predominant source of CDOM in the estuary during almost all the year and the two estuarine zones presented distinct amounts, as well as absorbance and fluorescence characteristics. Freshwater inputs have major influence on the dynamics of CDOM in the estuary, in particular at the brackish water zone, where accounted for approximately 60% of CDOM variability. With a lower magnitude, the biological productivity also impacted the optical properties of CDOM, explaining about 15% of its variability. Therefore, climate changes related to seasonal and inter-annual variations of the precipitation amounts might impact the dynamics of CDOM significantly, influencing its photochemistry and the microbiological activities in estuarine systems.

Insights on the Optical Properties of Estuarine DOM - Hydrological and Biological Influences.

Science.gov (United States)

Santos, Luísa; Pinto, António; Filipe, Olga; Cunha, Ângela; Santos, Eduarda B H; Almeida, Adelaide

2016-01-01

Dissolved organic matter (DOM) in estuaries derives from a diverse array of both allochthonous and autochthonous sources. In the estuarine system Ria de Aveiro (Portugal), the seasonality and the sources of the fraction of DOM that absorbs light (CDOM) were inferred using its optical and fluorescence properties. CDOM parameters known to be affected by aromaticity and molecular weight were correlated with physical, chemical and meteorological parameters. Two sites, representative of the marine and brackish water zones of the estuary, and with different hydrological characteristics, were regularly surveyed along two years, in order to determine the major influences on CDOM properties. Terrestrial-derived compounds are the predominant source of CDOM in the estuary during almost all the year and the two estuarine zones presented distinct amounts, as well as absorbance and fluorescence characteristics. Freshwater inputs have major influence on the dynamics of CDOM in the estuary, in particular at the brackish water zone, where accounted for approximately 60% of CDOM variability. With a lower magnitude, the biological productivity also impacted the optical properties of CDOM, explaining about 15% of its variability. Therefore, climate changes related to seasonal and inter-annual variations of the precipitation amounts might impact the dynamics of CDOM significantly, influencing its photochemistry and the microbiological activities in estuarine systems.

Use of ground-water reservoirs for storage of surface water in the San Joaquin Valley, California

Science.gov (United States)

Davis, G.H.; Lofgren, B.E.; Mack, Seymour

1964-01-01

The San Joaquin Valley includes roughly the southern two-thirds of the Central Valley of California, extending 250 miles from Stockton on the north to Grapevine at the foot of the Tehachapi Mountains. The valley floor ranges in width from 25 miles near Bakersfield to about 55 miles near Visalia; it has a surface area of about 10,000 square miles. More than one-quarter of all the ground water pumped for irrigation in the United States is used in this highly productive valley. Withdrawal of ground water from storage by heavy pumping not only provides a needed irrigation water supply, but it also lowers the ground-water level and makes storage space available in which to conserve excess water during periods of heavy runoff. A storage capacity estimated to be 93 million acre-feet to a depth of 200 feet is available in this ground-water reservoir. This is about nine times the combined capacity of the existing and proposed surface-water reservoirs in the San Joaquin Valley under the California Water Plan. The landforms of the San Joaquin Valley include dissected uplands, low plains and fans, river flood plains and channels, and overflow lands and lake bottoms. Below the land surface, unconsolidated sediments derived from the surrounding mountain highlands extend downward for hundreds of feet. These unconsolidated deposits, consisting chiefly of alluvial deposits, but including some widespread lacustrine sediments, are the principal source of ground water in the valley. Ground water occurs under confined and unconfined conditions in the San Joaquin Valley. In much of the western, central, and southeastern parts of the valley, three distinct ground-water reservoirs are present. In downward succession these are 1) a body of unconfined and semiconfined fresh water in alluvial deposits of Recent, Pleistocene, and possibly later Pliocene age, overlying the Corcoran clay member of the Tulare formation; 2) a body of fresh water confined beneath the Corcoran clay member, which

Modelling the effect of hydrological change on estuarine health: An Australian Perspective. (Invited)

Science.gov (United States)

Bruce, L. C.; Adiyanti, S.; Ruibal, A. L.; Hipsey, M. R.

2013-12-01

Estuaries provide an important role in the filtering and transformation of carbon and nutrients from coastal catchments into the marine environment. Global trends including climate change, increased population, industrialization and agriculture have led to the rapid deterioration of estuarine ecosystems across the world. Within the Australian context, a particular concern is how changes to hydrological regimes, due to both water diversions and climate variability, are contributing to increased stress and consequent decline in estuarine health. In this study we report the modeling output of five Australian estuaries, each with different hydrological regimes and alternative management issues relating to altered hydrology: 1) The Yarra River estuary is a highly urbanized system, also receiving agriculturally derived nutrients, where the concern is the role of periodic hypoxia in reducing the assimilation capacity of nitrogen and thus increased risk of algal blooms forming in the coastal environment; 2) The upper Swan River estuary in Western Australia, which experiences persistent anoxia and hypoxia brought about by reduced flows has led to the commissioning of several oxygenation plants to alleviate stress on biodiversity and overall estuarine health; 3) The health of the Caboolture estuary in Queensland has deteriorated in the past decade with the aim of model development to quantify the various sources of surface and groundwater derived nutrients; 4) The construction of an additional channel to increase flushing in the Peel Harvey estuary in Western Australia was designed to control persistent harmful algal blooms; and 5) The Lower River Murray estuary experienced a prolonged drought that led to the development of acid sulfate soils and acid drainage deteriorating water quality. For these applications we applied 3-D hydrodynamic-biogeochemical models to determine underlying relationships between altered flow regimes, increased temperatures and the response of

Characteristics and landcover of estuarine boundaries: implications for the delineation of the South African estuarine functional zone

CSIR Research Space (South Africa)

Veldkornet, DA

2015-11-01

Full Text Available Zulu-Natal), cultivation has removed estuarine habitat. Although delineation of boundaries can be complicated by landcover changes, the estuarine lateral boundary in Cape estuaries could be identified based on sediment characteristics (moisture content, organic content...

Interactions between cement grouts and sulphate bearing ground water

International Nuclear Information System (INIS)

Walton, P.L.; Duerden, S.L.; Atkins, K.M.; Majumdar, A.J.

1989-01-01

The physical, chemical and mineralogical properties of mixtures of Ordinary Portland cement and blastfurnace slag or pulverized fuel ash, exposed to a sulphate-bearing ground water at different temperatures and pressures, were investigated in order to assess the long term durability of cements for encapsulating radioactive waste and backfilling a repository. The effect of the ground water on the chemical and mineralogical characteristics of the cements is minimal. Calcite and C-S-H are present in all the samples and are durable throughout the test. Dimensional changes in the cements during setting and curing may cause weaknesses in the materials which may increase the effects of a percolating ground water. (author)

Occurrence and use of an estuarine habitat by giant manta ray Manta birostris.

Science.gov (United States)

Medeiros, A M; Luiz, O J; Domit, C

2015-06-01

Based on the knowledge of local artisanal fishermen and on direct observations, this study presents evidence that the giant manta ray Manta birostris uses the Paranaguá estuarine complex in south Brazil, south-western Atlantic Ocean, in a predictable seasonal pattern. Behavioural observations suggest that the estuary can act as a nursery ground for M. birostris during the summer. © 2015 The Fisheries Society of the British Isles.

Assessment of Water Pollution in Tipparthy Revenue Sub-Division, Nalgonda (District, Andhra Pradesh, India

Directory of Open Access Journals (Sweden)

Medikondu Kishore

2010-01-01

Full Text Available A systematic study has been carried out to explore the physicochemical characteristics of drinking water sources of Tipparthy revenue sub-division, Nalgonda (District, Andhra Pradesh, India. Totally 49 water samples were collected from the different locations (22 villages of the study area including bore well, open well and hand pump water and analyzed for pH, EC, TDS, turbidity, total hardness, fluoride, chloride, nitrate, nitrite, sulphate, phosphates, calcium, magnesium, sodium, potassium, Iron and dissolved oxygen. On an average, in almost all the samples, one or the other chemical constituent was beyond the permissible limits it was also concluded that water sources in the study area not fit for potability. Sodium absorption ratio (SAR and water quality (WQI studies indicate water available from all sources not fit for irrigation also. The study indicates the need for periodic monitoring of ground water in the study area.

Water vapor concentration dependence and temperature dependence of Li mass loss from Li{sub 2}TiO{sub 3} with excess Li and Li{sub 4}SiO{sub 4}

Energy Technology Data Exchange (ETDEWEB)

Shimozori, Motoki [Interdisciplinary Graduate School of Engineering Science, Kyushu University, 6-1, Kasugakoen, Kasuga, Fukuoka 816-8580 (Japan); Katayama, Kazunari, E-mail: kadzu@nucl.kyushu-u.ac.jp [Interdisciplinary Graduate School of Engineering Science, Kyushu University, 6-1, Kasugakoen, Kasuga, Fukuoka 816-8580 (Japan); Hoshino, Tsuyoshi [Breeding Functional Materials Development Group, Department of Blanket Systems Research, Rokkasho Fusion Institute, Sector of Fusion Research and Development, Japan Atomic Energy Agency, 2-166 Obuch, Omotedate, Rokkasho-mura, Kamikita-gun, Aomori 039-3212 (Japan); Ushida, Hiroki; Yamamoto, Ryotaro; Fukada, Satoshi [Interdisciplinary Graduate School of Engineering Science, Kyushu University, 6-1, Kasugakoen, Kasuga, Fukuoka 816-8580 (Japan)

2015-10-15

Highlights: • Li mass loss from Li{sub 2.11}TiO{sub 3} increased proportionally to water vapor pressure. • Li mass loss from Li{sub 2.11}TiO{sub 3} at 600 °C was significantly smaller than expected. • Differences of Li mass loss behavior from Li{sub 2.11}TiO{sub 3} and Li{sub 4}SiO{sub 4} were shown. - Abstract: In this study, weight reduction of Li{sub 2}TiO{sub 3} with excess Li and Li{sub 4}SiO{sub 4} at elevated temperatures under hydrogen atmosphere or water vapor atmosphere was investigated. The Li mass loss for the Li{sub 2}TiO{sub 3} at 900 °C was 0.4 wt% under 1000 Pa H{sub 2} atmosphere and 1.5 wt% under 50 Pa H{sub 2}O atmosphere. The Li mass loss for the Li{sub 2}TiO{sub 3} increased proportionally to the water vapor pressure in the range from 50 to 200 Pa at 900 °C and increased with increasing temperature from 700 to 900 °C although Li mass loss at 600 °C was significantly smaller than expected. It was found that water vapor concentration dependence and temperature dependence of Li mass loss for the Li{sub 2}TiO{sub 3} and the Li{sub 4}SiO{sub 4} used in this work were quite different. Water vapor is released from the ceramic breeder materials into the purge gas due to desorption of adsorbed water and water formation reaction. The released water vapor possibly promotes Li mass loss with the formation of LiOH on the surface.

Reading Ground Water Levels with a Smartphone

Science.gov (United States)

van Overloop, Peter-Jules

2015-04-01

Most ground water levels in the world are measured manually. It requires employees of water management organizations to visit sites in the field and execute a measurement procedure that requires special tools and training. Once the measurement is done, the value is jotted down in a notebook and later, at the office, entered in a computer system. This procedure is slow and prone to human errors. A new development is the introduction of modern Information and Communication Technology to support this task and make it more efficient. Two innovations are introduced to measure and immediately store ground water levels. The first method is a measuring tape that gives a sound and light when it just touches the water in combination with an app on a smartphone with which a picture needs to be taken from the measuring tape. Using dedicated pattern recognition algorithms, the depth is read on the tape and it is verified if the light is on. The second method estimates the depth using a sound from the smartphone that is sent into the borehole and records the reflecting waves in the pipe. Both methods use gps-localization of the smartphone to store the depths in the right location in the central database, making the monitoring of ground water levels a real-time process that eliminates human errors.

Evaluation of arsenic and other physico-chemical parameters of surface and ground water of Jamshoro, Pakistan

Energy Technology Data Exchange (ETDEWEB)

Baig, Jameel Ahmed, E-mail: jab_mughal@yahoo.com [National Center of Excellence in Analytical Chemistry, University of Sindh, Jamshoro 76080 (Pakistan); Kazi, Tasneem Gul, E-mail: tgkazi@yahoo.com [National Center of Excellence in Analytical Chemistry, University of Sindh, Jamshoro 76080 (Pakistan); Arain, Muhammad Balal, E-mail: bilal_KU2004@yahoo.com [National Center of Excellence in Analytical Chemistry, University of Sindh, Jamshoro 76080 (Pakistan); Afridi, Hassan Imran, E-mail: hassanimranafridi@yahoo.com [National Center of Excellence in Analytical Chemistry, University of Sindh, Jamshoro 76080 (Pakistan); Kandhro, Ghulam Abbas, E-mail: gakandhro@yahoo.com [National Center of Excellence in Analytical Chemistry, University of Sindh, Jamshoro 76080 (Pakistan); Sarfraz, Raja Adil, E-mail: rajaadilsarfraz@yahoo.com [National Center of Excellence in Analytical Chemistry, University of Sindh, Jamshoro 76080 (Pakistan); Jamal, Muhammad Khan, E-mail: mkhanjamali@yahoo.com [Government Degree College Usta Muhammad, Balochistan 08300 (Pakistan); Shah, Abdul Qadir, E-mail: aqshah07@yahoo.com [National Center of Excellence in Analytical Chemistry, University of Sindh, Jamshoro 76080 (Pakistan)

2009-07-30

Arsenic contamination in water has caused severe health problems around the world. The purpose of this study was to evaluate the geological and anthropogenic aspects of As pollution in surface and groundwater resources of Jamshoro Sindh, Pakistan. Hydride generator atomic absorption spectrophotometry (HG-AAS) is employed for the determination of arsenic in water samples, with detection limit of 0.02 {mu}g l{sup -1}. Arsenic concentrations in surface and underground water range from 3.0 to 50.0, and 13 to 106 {mu}g l{sup -1}, respectively. In most of the water samples As levels exceeded the WHO provisional guideline values 10 {mu}g l{sup -1}. The high level of As in under study area may be due to widespread water logging from Indus river irrigation system which causes high saturation of salts in this semi-arid region and lead to enrichment of As in shallow groundwater. Among the physico-chemical parameters, electrical conductivity, Na{sup +}, K{sup +}, and SO{sub 4}{sup 2-} were found to be higher in surface and ground water, while elevated levels of Ca{sup 2+} and Cl{sup -} were detected only in ground water than WHO permissible limit. The high level of iron was observed in ground water, which is a possible source of As enrichment in the study area. The multivariate technique (cluster analysis) was used for the elucidation of high, medium and low As contaminated areas. It may be concluded that As originate from coal combustion at brick factories and power generation plants, and it was mobilized promotionally by the alkaline nature of the understudy groundwater samples.

Estuarine Ecosystem Engineering : Biogeomorphology in the estuarine intertidal

NARCIS (Netherlands)

Montserrat Trotsenburg, F.

2011-01-01

The aim of this thesis was to investigate how (macro)benthic organisms interact with the ecological functioning, erodibility and small- to medium-scale morphodynamics of estuarine intertidal sediment by modulating its composition and/or properties. In these interactions, scale is of great importance

Ground-water and geohydrologic conditions in Queens County, Long Island, New York

Science.gov (United States)

Soren, Julian

1971-01-01

Queens County is a heavily populated borough of New York City, at the western end of Long Island, N. Y., in which large amounts of ground water are used, mostly for public supply. Ground water, pumped from local aquifers, by privately owned water-supply companies, supplied the water needs of about 750,000 of the nearly 2 million residents of the county in 1967; the balance was supplied by New York City from surface sources outside the county in upstate New York. The county's aquifers consist of sand and gravel of Late Cretaceous and of Pleistocene ages, and the aquifers comprise a wedge-shaped ground-water reservoir lying on a southeastward-sloping floor of Precambrian(?) bedrock. Beds of clay and silt generally confine water in the deeper parts of the reservoir; water in the deeper aquifers ranges from poorly confined to well confined. Wisconsin-age glacial deposits in the uppermost part of the reservoir contain ground water under water-table conditions. Ground water pumpage averaged about 60 mgd (million gallons per day) in Queens County from about 1900 to 1967. Much of the water was used in adjacent Kings County, another borough of New York City, prior to 1950. The large ground-water withdrawal has resulted in a wide-spread and still-growing cone of depression in the water table, reflecting a loss of about 61 billion gallons of fresh water from storage. Significant drawdown of the water table probably began with rapid urbanization of Queens County in the 1920's. The county has been extensively paved, and storm and sanitary sewers divert water, which formerly entered the ground, to tidewater north and south of the county. Natural recharge to the aquifers has been reduced to about one half of the preurban rate and is below the withdrawal rate. Ground-water levels have declined more than 40. feet from the earliest-known levels, in 1903, to 1967, and the water table is below sea level in much of the county. The aquifers are being contaminated by the movement of

Environmental characteristics of the Mandovi-Zuari estuarine system in Goa

Science.gov (United States)

Qasim, S. Z.; Sen Gupta, R.

1981-11-01

Two rivers, the Mandovi and the Zuari, with their interconnecting canal, form an estuarine system in Goa on the west coast of India. Physical, chemical and biological features of this estuary are adapted to a seasonal rhythm induced by the annual cycle of the monsoon. Heavy precipitation and land runoff from June to September bring about large changes in temperature, salinity, flow pattern, dissolved oxygen and nutrients when the estuary becomes freshwater dominated. The monsoon season (July-September) is followed by a recovery period during the post-monsoon season (October-January) and thereafter a stable period of the pre-monsoon season (February-May) when the estuary becomes marine dominated. During the pre-monsoon (dry) season, the water in the estuarine system remains well mixed and the intrusion of salt water is felt as far as 65 km upstream in both the rivers; but during the monsoon season the rivers become stratified and a salt wedge is formed in each river which extends up to about 10 km upstream in the Mandovi and 12 km in the Zuari. The flow of the estuarine system is regulated by the entry of seawater with the incoming tide through Zuari which reaches Mandovi through the canal. The flow is reversed during the outgoing tide when the estuarine system is flushed. Dilution factors in both the estuaries are similar and vary from 1·2 to 8; highest values occur during the pre-monsoon season. Two shoals/sand bars occur permanently in Mandovi (Aguada Bay) close to a ramp-like inlet to the sea. This inlet poses no navigational problems for about 9 months during the dry season; but for a 3-month period during the monsoon, the waterway becomes hazardous and is closed to boat traffic. Heavy swell and intense wave activity lead to the transfer of sediments into the navigational inlet and the calm season brings the materials back to their original position with practically no overall change in the bathymetry of the bay. The oxygen cycle in the estuarine system is

Ground-water resources of Cambodia

Science.gov (United States)

Rasmussen, William Charles; Bradford, Gary M.

1977-01-01

available information is on the central lowlands and contiguous low plateaus, as the mountainous areas on the west and the high plateaus on the east are relatively unexplored with respect to their ground-water availability. No persistent artesian aquifer has been identified nor have any large potential ground-water sources been found .although much of the country yet remains to be explored by test drilling. Well irrigation for garden produce is feasible on a modest scale in many localities throughout Cambodia. It does not seem likely, however, that large-scale irrigation from wells will come about in the future. Ground water may be regarded as a widely available supplemental source to surface water for domestic, small-scale industrial, and irrigation use.

Ma'adim Vallis Estuarine Delta in Elysium Basin and Its Relevance as a Landing Site for Exobiology Exploration on Mars

Science.gov (United States)

Grin, E. A.; Cabrol, N. A.

1998-01-01

The debouche of Ma'adim Vallis in the Elysium Basin generated a transitional transported sediment structure, which planimetric shape is controlled by the enclosing topography of a deep reentrant gulf of the Basin into the highland. We defined it as an estuarine delta. The location and the importance of this estuarine delta is supported by the theoretical model of graded profile constructed for Ma'adim Vallis, and by two approaches: (i) the reconstruction of Ma'adim Vallis downstream course from Gusev to Elysium Basin, and (ii) the survey of the sediment deposit in the alleged estuary. The longitudinal graded profile of Ma'adim Vallis finds its base-level in the Elysium Basin, at a about 1000 m elevation, which is in agreement with the observed Basin shoreline. This model is supported by observational evidence of flow between the northern rim of Gusev crater, and the Elysium Basin shoreline. This downstream course of Ma'adim Vallis can be divided into three hydrogeologic regions. into three hydrogeologic regions. (a) The first region is a flooded plain (Zephiria Mensae), consisting in chaotic terrain formed by highland rocks, and disintegrated lava of the western flank of Apollinaris. Morphologic indicators of the flood process are: (1) the sediment deposit over the Gusev crater northern rim that reflects the overspilling of the crater-lake water through a 40-km wide gap provided by an ancient impact crater, (2) the tear-drop shaped feature on the northeastern flank of Apollinaris Patera, and (3) the chaotic terrain that suggest the emergence of ground water generated by the seepage of the crater lake through high-permeable broken rampart material. This underground water circulation sustained by the hydrostatic pressure of the crater-lake has likely generated a hydrothermal system in the volcanic environment of Apollinaris Patera. The stratigraphy of the flooded area is identified as Hesperian age, with occurrences of Noachian hilly individual features, and as

Water resources data, Iowa, water year 2001, Volume 2. surface water--Missouri River basin, and ground water

Science.gov (United States)

Nalley, G.M.; Gorman, J.G.; Goodrich, R.D.; Miller, V.E.; Turco, M.J.; Linhart, S.M.

2002-01-01

The Water Resources Division of the U.S. Geological Survey, in cooperation with State, county, municipal, and other Federal agencies, obtains a large amount of data pertaining to the water resources of Iowa each water year. These data, accumulated during many water years, constitute a valuable data base for developing an improved understanding of the water resources of the State. To make this data readily available to interested parties outside of the Geological Survey, the data is published annually in this report series entitled “Water Resources Data - Iowa” as part of the National Water Data System. Water resources data for water year 2001 for Iowa consists of records of stage, discharge, and water quality of streams; stage and contents of lakes and reservoirs; and water levels and water quality of ground water. This report, in two volumes, contains stage or discharge records for 132 gaging stations; stage records for 9 lakes and reservoirs; water-quality records for 4 gaging stations; sediment records for 13 gaging stations; and water levels for 163 ground-water observation wells. Also included are peak-flow data for 92 crest-stage partial-record stations, water-quality data from 86 municipal wells, and precipitation data collected at 6 gaging stations and 2 precipitation sites. Additional water data were collected at various sites not included in the systematic data-collection program, and are published here as miscellaneous measurements and analyses. These data represent that part of the National Water Data System operated by the U.S. Geological Survey and cooperating local, State, and Federal agencies in Iowa.Records of discharge or stage of streams, and contents or stage of lakes and reservoirs were first published in a series of U.S. Geological Survey water-supply papers entitled “Surface Water Supply of the United States.” Through September 30, 1960, these water-supply papers were published in an annual series; during 1961-65 and 1966-70, they

Effects of energy development on ground water quality: an overview and preliminary assessment

International Nuclear Information System (INIS)

Parker, W.M. III; Yin, S.C.L.; Davis, M.J.; Kutz, W.J.

1981-07-01

A preliminary national overview of the various effects on ground water quality likely to result from energy development. Based on estimates of present and projected energy-development activities, those regions of the country are identified where ground water quality has the potential for being adversely affected. The general causes of change in ground water quality are reviewed. Specific effects on ground water quality of selected energy technologies are discussed, and some case-history material is provided. A brief overview of pertinent legislation relating to the protection and management of ground water quality is presented. Six methodologies that have some value for assessing the potential effects on ground water quality of energy development activities are reviewed. A method of identifying regions in the 48 contiguous states where there is a potential for ground water quality problems is described and then applied

Estuarine Response to River Flow and Sea-Level Rise under Future Climate Change and Human Development

Energy Technology Data Exchange (ETDEWEB)

Yang, Zhaoqing; Wang, Taiping; Voisin, Nathalie; Copping, Andrea E.

2015-04-01

Understanding the response of river flow and estuarine hydrodynamics to climate change, land-use/land-cover change (LULC), and sea-level rise is essential to managing water resources and stress on living organisms under these changing conditions. This paper presents a modeling study using a watershed hydrology model and an estuarine hydrodynamic model, in a one-way coupling, to investigate the estuarine hydrodynamic response to sea-level rise and change in river flow due to the effect of future climate and LULC changes in the Snohomish River estuary, Washington, USA. A set of hydrodynamic variables, including salinity intrusion points, average water depth, and salinity of the inundated area, were used to quantify the estuarine response to river flow and sea-level rise. Model results suggest that salinity intrusion points in the Snohomish River estuary and the average salinity of the inundated areas are a nonlinear function of river flow, although the average water depth in the inundated area is approximately linear with river flow. Future climate changes will shift salinity intrusion points further upstream under low flow conditions and further downstream under high flow conditions. In contrast, under the future LULC change scenario, the salinity intrusion point will shift downstream under both low and high flow conditions, compared to present conditions. The model results also suggest that the average water depth in the inundated areas increases linearly with sea-level rise but at a slower rate, and the average salinity in the inundated areas increases linearly with sea-level rise; however, the response of salinity intrusion points in the river to sea-level rise is strongly nonlinear.

Temporal variation of uranium in ground water with conductivity

International Nuclear Information System (INIS)

Pulhani, Vandana; Chaudhury, Moushumi D.; Jha, S.K.; Tripathi, R.M.

2015-01-01

The concentration of uranium in drinking water sources is a matter of health concern since it has been proved to be chemo-toxic to humans. Uranium being a more soluble actinide is also very mobile in the environment. The effect of water quality parameters and their co-relation to uranium content in the water is an interesting study to understand and predict its behavior in ground water and subsequently to judge the hazard posed. Hence studies on spatial and temporal variation of uranium concentration with electrical conductivity, pH, total dissolved solids and salinity in ground water was carried out. (author)

Ground-based remote sensing of tropospheric water vapour isotopologues within the project MUSICA

Directory of Open Access Journals (Sweden)

M. Schneider

2012-12-01

Full Text Available Within the project MUSICA (MUlti-platform remote Sensing of Isotopologues for investigating the Cycle of Atmospheric water, long-term tropospheric water vapour isotopologue data records are provided for ten globally distributed ground-based mid-infrared remote sensing stations of the NDACC (Network for the Detection of Atmospheric Composition Change. We present a new method allowing for an extensive and straightforward characterisation of the complex nature of such isotopologue remote sensing datasets. We demonstrate that the MUSICA humidity profiles are representative for most of the troposphere with a vertical resolution ranging from about 2 km (in the lower troposphere to 8 km (in the upper troposphere and with an estimated precision of better than 10%. We find that the sensitivity with respect to the isotopologue composition is limited to the lower and middle troposphere, whereby we estimate a precision of about 30‰ for the ratio between the two isotopologues HD¹⁶O and H<sub>2sub>¹⁶O. The measurement noise, the applied atmospheric temperature profiles, the uncertainty in the spectral baseline, and the cross-dependence on humidity are the leading error sources. We introduce an a posteriori correction method of the cross-dependence on humidity, and we recommend applying it to isotopologue ratio remote sensing datasets in general. In addition, we present mid-infrared CO<sub>2sub> retrievals and use them for demonstrating the MUSICA network-wide data consistency. In order to indicate the potential of long-term isotopologue remote sensing data if provided with a well-documented quality, we present a climatology and compare it to simulations of an isotope incorporated AGCM (Atmospheric General Circulation Model. We identify differences in the multi-year mean and seasonal cycles that significantly exceed the estimated errors, thereby indicating deficits in the modeled atmospheric water cycle.

Polyacrylamide+Al{sub 2}(SO{sub 4}){sub 3} and polyacrylamide+CaO remove coliform bacteria and nutrients from swine wastewater

Energy Technology Data Exchange (ETDEWEB)

Entry, J.A.; Phillips, Ian; Stratton, Helen; Sojka, R.E

2003-03-01

Polyacrylamide mixture may be able to reduce run-off of enteric bacteria from animal wastes. - Animal wastes are a major contributor of nutrients and enteric microorganisms to surface water and ground water. Polyacrylamide (PAM) mixtures are an effective flocculent, and we hypothesized that they would reduce transport of microorganisms in flowing water. After waste water running at 60.0 l min{sup -1} flowed over PAM+Al{sub 2}(SO{sub 4}){sub 3}, or PAM+CaO in furrows, total coliform bacteria (TC) and fecal coliform bacteria (FC) were reduced by 30-50% at 1 and 50 m downstream of the treatments compared to the control. In a column study, PAM+Al{sub 2}(SO{sub 4}){sub 3}, and PAM+CaO applied to sandy, sandy loam, loam, and clay soils reduced NH{sub 4}{sup +} and ortho-P concentrations in leachate compared to the source waste water and the control. PAM+Al{sub 2}(SO{sub 4}){sub 3} and PAM+CaO applied to sandy, sandy loam and loam soils reduced both total and ortho-P, concentrations in leachate compared to the source wastewater and control treatment. In a field study, PAM+Al{sub 2}(SO{sub 4}){sub 3}, or PAM+CaO treatments did not consistently reduce NH{sub 4}{sup +}, NO{sub 3}{sup -}, ortho-P, and total P concentrations in wastewater flowing over any soil compared to inflow wastewater or the control treatment. With proper application PAM+ Al{sub 2}(SO{sub 4}){sub 3} and PAM+CaO may be able to reduce the numbers of enteric bacteria in slowly flowing wastewater running off animal confinement areas, reducing the amount of pollutants entering surface water and groundwater.

Volatile organic compounds in the nation's ground water and drinking-water supply wells

Science.gov (United States)

Zogorski, John S.; Carter, Janet M.; Ivahnenko, Tamara; Lapham, Wayne W.; Moran, Michael J.; Rowe, Barbara L.; Squillace, Paul J.; Toccalino, Patricia L.

2006-01-01

This national assessment of 55 volatile organic compounds (VOCs) in ground water gives emphasis to the occurrence of VOCs in aquifers that are used as an important supply of drinking water. In contrast to the monitoring of VOC contamination of ground water at point-source release sites, such as landfills and leaking underground storage tanks (LUSTs), our investigations of aquifers are designed as large-scale resource assessments that provide a general characterization of water-quality conditions. Nearly all of the aquifers included in this assessment have been identified as regionally extensive aquifers or aquifer systems. The assessment of ground water (Chapter 3) included analyses of about 3,500 water samples collected during 1985-2001 from various types of wells, representing almost 100 different aquifer studies. This is the first national assessment of the occurrence of a large number of VOCs with different uses, and the assessment addresses key questions about VOCs in aquifers. The assessment also provides a foundation for subsequent decadal assessments of the U.S. Geological Survey (USGS) National Water-Quality Assessment (NAWQA) Program to ascertain long-term trends of VOC occurrence in these aquifers.

18 CFR 430.19 - Ground water withdrawal metering, recording, and reporting.

Science.gov (United States)

2010-04-01

... 18 Conservation of Power and Water Resources 2 2010-04-01 2010-04-01 false Ground water withdrawal metering, recording, and reporting. 430.19 Section 430.19 Conservation of Power and Water Resources DELAWARE RIVER BASIN COMMISSION SPECIAL REGULATIONS GROUND WATER PROTECTION AREA: PENNSYLVANIA § 430.19...

Distinguishing natural hydrocarbons from anthropogenic contamination in ground water

International Nuclear Information System (INIS)

Lesage, S.; Xu, H.; Novakowski, K.S.

1997-01-01

Differentiation between natural and anthropogenic sources of ground-water contamination by petroleum hydrocarbons is necessary in areas where natural hydrocarbons may be present in the subsurface. Because of the similarity in composition between natural and refined petroleum, the use of statistical techniques to discern trends is required. In this study, both multivariate plotting techniques and principal component analysis were used to investigate the origin of hydrocarbons from a variety of study sites. Ground-water and gas samples were collected from the Niagara Falls area and from three gasoline stations where leaking underground storage tanks had been found. Although soil gas surveys are used to indicate the presence of hydrocarbons, they were not useful in differentiating between natural and anthropogenic sources of contamination in ground water. Propane and pentene were found to be the most useful chemical parameters in discriminating between the natural and anthropogenic sources. These chemicals are not usually measured in investigations of ground-water contamination, yet analysis can be conducted by most environmental laboratories using conventional methods

Atomic layer deposition of Al{sub 2}O{sub 3} and Al{sub 2}O{sub 3}/TiO{sub 2} barrier coatings to reduce the water vapour permeability of polyetheretherketone

Energy Technology Data Exchange (ETDEWEB)

Ahmadzada, Tamkin, E-mail: tahm4852@uni.sydney.edu.au [School of Aerospace, Mechanical and Mechatronic Engineering, University of Sydney, NSW 2006 (Australia); McKenzie, David R.; James, Natalie L.; Yin, Yongbai [School of Physics, University of Sydney, NSW 2006 (Australia); Li, Qing [School of Aerospace, Mechanical and Mechatronic Engineering, University of Sydney, NSW 2006 (Australia)

2015-09-30

We demonstrate significantly enhanced barrier properties of polyetheretherketone (PEEK) against water vapour penetration by depositing Al{sub 2}O{sub 3} or Al{sub 2}O{sub 3}/TiO{sub 2} nanofilms grown by atomic layer deposition (ALD). Nanoindentation analysis revealed good adhesion strength of a bilayer Al{sub 2}O{sub 3}/TiO{sub 2} coating to PEEK, while the single layer Al{sub 2}O{sub 3} coating displayed flaking and delamination. We identified three critical design parameters for achieving the optimum barrier properties of ALD Al{sub 2}O{sub 3}/TiO{sub 2} coatings on PEEK. These are a minimum total thickness dependent on the required water vapour transmission rate, the use of an Al{sub 2}O{sub 3}/TiO{sub 2} bilayer coating and the application of the coating to both sides of the PEEK film. Using these design parameters, we achieved a reduction in moisture permeability of PEEK of over two orders of magnitude while maintaining good adhesion strength of the polymer–thin film system. - Highlights: • Atomic layer deposition of Al{sub 2}O{sub 3}/TiO{sub 2} coatings reduced water vapour permeability. • Bilayer coatings reduced the permeability more than single layer coatings. • Bilayer coatings displayed higher adhesion strength than the single layer coatings. • Double-sided coatings performed better than single-sided coatings. • Correlation was found between total thickness and reduced water vapour permeability.

Use of tree-ring chemistry to document historical ground-water contamination events

Science.gov (United States)

Vroblesky, Don A.; Yanosky, Thomas M.

1990-01-01

The annual growth rings of tulip trees (Liriodendron tulipifera L.) appear to preserve a chemical record of ground-water contamination at a landfill in Maryland. Zones of elevated iron and chlorine concentrations in growth rings from trees immediately downgradient from the landfill are closely correlated temporally with activities in the landfill expected to generate iron and chloride contamination in the ground water. Successively later iron peaks in trees increasingly distant from the landfill along the general direction of ground-water flow imply movement of iron-contaminated ground water away from the landfill. The historical velocity of iron movement (2 to 9 m/yr) and chloride movement (at least 40 m/yr) in ground water at the site was estimated from element-concentration trends of trees at successive distances from the landfill. The tree-ring-derived chloride-transport velocity approximates the known ground-water velocity (30 to 80 m/yr). A minimum horizontal hydraulic conductivity (0.01 to .02 cm/s) calculated from chloride velocity agrees well with values derived from aquifer tests (about 0.07 cm/s) and from ground-water modeling results (0.009 to 0.04 cm/s).

Remediation of ground water containing volatile organic compounds and tritium

International Nuclear Information System (INIS)

Shukla, S.N.; Folsom, E.N.

1994-03-01

The Trailer 5475 (T-5475) East Taxi Strip Area at Lawrence Livermore National Laboratory (LLNL), Livermore, California was used as a taxi strip by the US Navy to taxi airplanes to the runway from 1942 to 1947. Solvents were used in some unpaved areas adjacent to the East Taxi Strip for cleaning airplanes. From 1953 through 1976, the area was used to store and treat liquid waste. From 1962 to 1976 ponds were constructed and used for evaporation of liquid waste. As a result, the ground water in this area contains volatile organic compounds (VOCs) and tritium. The ground water in this area is also known to contain hexavalent chromium that is probably naturally occurring. Therefore, LLNL has proposed ''pump-and-treat'' technology above grade in a completely closed loop system. The facility will be designed to remove the VOCs and hexavalent chromium, if any, from the ground water, and the treated ground water containing tritium will be reinjected where it will decay naturally in the subsurface. Ground water containing tritium will be reinjected into areas with equal or higher tritium concentrations to comply with California regulations

Ecotoxicology of bromoacetic acid on estuarine phytoplankton

International Nuclear Information System (INIS)

Gordon, Ana R.; Richardson, Tammi L.; Pinckney, James L.

2015-01-01

Bromoacetic acid is formed when effluent containing chlorine residuals react with humics in natural waters containing bromide. The objective of this research was to quantify the effects of bromoacetic acid on estuarine phytoplankton as a proxy for ecosystem productivity. Bioassays were used to measure the EC 50 for growth in cultured species and natural marine communities. Growth inhibition was estimated by changes in chlorophyll a concentrations measured by fluorometry and HPLC. The EC 50 s for cultured Thalassiosira pseudonana were 194 mg L −1 , 240 mg L −1 for Dunaliella tertiolecta and 209 mg L −1 for Rhodomonas salina. Natural phytoplankton communities were more sensitive to contamination with an EC 50 of 80 mg L −1 . Discriminant analysis suggested that bromoacetic acid additions cause an alteration of phytoplankton community structure with implications for higher trophic levels. A two-fold EC 50 decrease in mixed natural phytoplankton populations affirms the importance of field confirmation for establishing water quality criteria. - Highlights: • Bromoacetic acid exposure resulted in lethal impacts to estuarine phytoplankton. • Cultured phytoplankton were less sensitive to bromoacetic acid than natural communities. • Lab results should be confirmed with field experiments whenever possible. - The toxicology of haloacetic acids has been studied in freshwater ecosystems, and urbanization of the coastal zone is making effects in marine ecosystems equally relevant.

Assessment of natural radium isotopes and 222Rn in water samples from Cananeia-Iguape estuarine complex, Sao Paulo, Brazil

International Nuclear Information System (INIS)

Oliveira, Joselene de; Jesus, Sueli Carvalho de; Abrahao, Fernanda Franco; Santos, Glorivania Ferreira dos; Braga, Elisabete de Santis; Chiozzini, Vitor

2009-01-01

Radium isotopes and radon are among the most important natural radionuclides in the environment from both radioprotection and geo-hydrological points of view. These radionuclides are a powerful tool for studying coastal processes and have been used intensively as tracers of groundwater sources that discharge into the ocean. In this paper, naturally occurring radium isotopes and 222 Rn were determined to trace water exchange and SGD in Cananeia-Iguape estuarine complex, a shallow coastal plain estuary in southern Sao Paulo area. The research work was carried out during the first semester of 2009 and covered stations located both in Cananeia and Iguape outlets, as well as samples collected in Ribeira of Iguape River and groundwater. Activity concentrations of 226 Ra in estuarine waters from Cananeia outlet varied from 2.9 mBq L -1 to 4.7 mBq L -1 , while 228 Ra concentrations ranged from 22 mBq L -1 to 45 mBq L -1 . In Iguape outlet, activities of 226 Ra ranged from 1.6 mBq L -1 to 6.6 mBq L -1 ; 228 Ra varied from 13 mBq L -1 to 20 mBq L -1 . Activities of Ra were slightly higher in samples collected at 5 m depth than at the surface water level. Groundwater activity concentrations of 226 Ra ranged from 0.63 mBq L -1 to 12 mBq L -1 and for 228 Ra from 18 mBq L -1 to 39 mBq L -1 . In groundwater, the 228 Ra/ 226 Ra activity ratios varied from 3.3 to 31.7. 222 Rn activities in groundwater up to 747 Bq L -1 were observed. Increased nitrate contents were observed in groundwater samples collected in Cananeia and Comprida Island. (author)

Desert water harvesting to benefit wildlife: a simple, cheap, and durable sub-surface water harvester for remote locations.

Science.gov (United States)

Rice, William E

2004-12-01

A sub-surface desert water harvester was constructed in the sagebrush steppe habitat of south-central Idaho, U.S.A. The desert water harvester utilizes a buried micro-catchment and three buried storage tanks to augment water for wildlife during the dry season. In this region, mean annual precipitation (MAP) ranges between about 150-250 mm (6"-10"), 70% of which falls during the cold season, November to May. Mid-summer through early autumn, June through October, is the dry portion of the year. During this period, the sub-surface water harvester provides supplemental water for wildlife for 30-90 days, depending upon the precipitation that year. The desert water harvester is constructed with commonly available, "over the counter" materials. The micro-catchment is made of a square-shaped, 20 mL. "PERMALON" polyethylene pond liner (approximately 22.9 m x 22.9 m = 523 m2) buried at a depth of about 60 cm. A PVC pipe connects the harvester with two storage tanks and a drinking trough. The total capacity of the water harvester is about 4777 L (1262 U.S. gallons) which includes three underground storage tanks, a trough and pipes. The drinking trough is refined with an access ramp for birds and small animals. The technology is simple, cheap, and durable and can be adapted to other uses, e.g. drip irrigation, short-term water for small livestock, poultry farming etc. The desert water harvester can be used to concentrate and collect water from precipitation and run-off in semi-arid and arid regions. Water harvested in such a relatively small area will not impact the ground water table but it should help to grow small areas of crops or vegetables to aid villagers in self-sufficiency.

Transport of persistent organic pollutants by microplastics in estuarine conditions

Science.gov (United States)

Bakir, Adil; Rowland, Steven J.; Thompson, Richard C.

2014-03-01

Microplastics represent an increasing source of anthropogenic contamination in aquatic environments, where they may also act as scavengers and transporters of persistent organic pollutants. As estuaries are amongst the most productive aquatic systems, it is important to understand sorption behaviour and transport of persistent organic pollutants (POPs) by microplastics along estuarine gradients. The effects of salinity sorption equilibrium kinetics on the distribution coefficients (Kd) of phenanthrene (Phe) and 4,4‧-DDT, onto polyvinyl chloride (PVC) and onto polyethylene (PE) were therefore investigated. A salinity gradient representing freshwater, estuarine and marine conditions, with salinities corresponding to 0 (MilliQ water, 690 μS/cm), 8.8, 17.5, 26.3 and 35 was used. Salinity had no significant effect on the time required to reach equilibrium onto PVC or PE and neither did it affect desorption rates of contaminants from plastics. Although salinity had no effect on sorption capacity of Phe onto plastics, a slight decrease in sorption capacity was observed for DDT with salinity. Salinity had little effect on sorption behaviour and POP/plastic combination was shown to be a more important factor. Transport of Phe and DDT from riverine to brackish and marine waters by plastic is therefore likely to be much more dependent on the aqueous POP concentration than on salinity. The physical characteristics of the polymer and local environmental conditions (e.g. plastic density, particle residence time in estuaries) will affect the physical transport of contaminated plastics. A transport model of POPs by microplastics under estuarine conditions is proposed. Transport of Phe and DDT by PVC and PE from fresh and brackish water toward fully marine conditions was the most likely net direction for contaminant transport and followed the order: Phe-PE >> DDT-PVC = DDT-PE >> Phe-PVC.

Water quality, meteorological, and nutrient data collected by the the National Estuarine Research Reserve System's System-wide Monitoring Program (NERRS SWMP) from January 1, 1995 to August 1, 2011 (NODC Accession 0052765)

Data.gov (United States)

National Oceanic and Atmospheric Administration, Department of Commerce — The National Estuarine Research Reserve System's System-wide Monitoring Program (NERRS SWMP) collected water quality, meteorological, and nutrient data in 26...

Ground-water quality in the southeastern Sacramento Valley aquifer, California, 1996

Science.gov (United States)

Milby Dawson, Barbara J.

2001-01-01

In 1996, the U.S. Geological Survey sampled 29 domestic wells and 2 monitoring wells in the southeastern Sacramento Valley as part of the U.S. Geological Survey's National Water-Quality Assessment (NAWQA) Program. This area, designated as the NAWQA Sacramento subunit study area, was chosen because it had the largest amount of ground-water use in the Sacramento River Basin. The Sacramento subunit study area is about 4,400 square kilometers and includes intense agricultural and urban development. The wells sampled ranged from 14.9 to 79.2 meters deep. Ground-water samples from 31 wells were analyzed for 6 field measurements, 14 inorganic constituents, 6 nutrient constituents, organic carbon, 86 pesticides, 87 volatile organic compounds, tritium (hydrogen-3), radon-222, deuterium (hydrogen-2), and oxygen-18. Nitrate levels were lower than the 2000 drinking-water standards in all but one well, but many detections were in the range that indicated an effect by human activities on ground-water quality. Radon was detected in all wells, and was measured at levels above the proposed Federal 2000 maximum contaminant level in 90 percent of the wells. Five pesticides and one pesticide degradation product were detected in ground-water samples and concentrations were below 2000 drinking-water standards. All pesticides detected during this study have been used in the Sacramento Valley. Thirteen volatile organic compounds were detected in ground water. One detection of trichloroethene was above Federal 2000 drinking-water standards, and another, tetrachloromethane, was above California 1997 drinking-water standards; both occurred in a well that had eight volatile organic compound detections and is near a known source of ground-water contamination. Pesticides and volatile organic compounds were detected in agricultural and urban areas; both pesticides and volatile organic compounds were detected at a higher frequency in urban wells. Ground-water chemistry indicates that natural

Ground-water contamination at Wurtsmith Air Force Base, Michigan

Science.gov (United States)

Stark, J.R.; Cummings, T.R.; Twenter, F.R.

1983-01-01

A sand and gravel aquifer of glacial origin underlies Wurtsmith Air Force Base in northeastern lower Michigan. The aquifer overlies a thick clay layer at an average depth of 65 feet. The water table is about 10 feet below land surface in the western part of the Base and about 25 feet below land surface in the eastern part. A ground-water divide cuts diagonally across the Base from northwest to southeast. South of the divide, ground water flows to the Au Sable River; north of the divide, it flows to Van Etten Creek and Van Etten Lake. Mathematical models were used to aid in calculating rates of groundwater flow. Rates range from about 0.8 feet per day in the eastern part of the Base to about 0.3 feet per day in the western part. Models also were used as an aid in making decisions regarding purging of contaminated water from the aquifer. In 1977, trichloroethylene was detected in the Air Force Base water-supply system. It had leaked from a buried storage tank near Building 43 in the southeastern part of the Base and moved northeastward under the influence of the natural ground-water gradient and the pumping of Base water-supply wells. In the most highly contaminated part of the plume, concentrations are greater than 1,000 micrograms per liter. Current purge pumping is removing some of the trichloroethylene, and seems to have arrested its eastward movement. Pumping of additional purge wells could increase the rate of removal. Trichloroethylene has also been detected in ground water in the vicinity of the Base alert apron, where a plume from an unknown source extends northeastward off Base. A smaller, less well-defined area of contamination also occurs just north of the larger plume. Trichloroethylene, identified near the waste-treatment plant, seepage lagoons, and the northern landfill area, is related to activities and operations in these areas. Dichloroethylene and trichloroethylene occur in significant quantities westward of Building 43, upgradient from the major

Contamination of Ground Water Due To Landfill Leachate

OpenAIRE

M. V. S. Raju

2012-01-01

The present site under investigation at Ajitsingh Nagar in Vijayawada of Andhra Pradesh is initially a low lying area and used for disposing the urban solid waste for the last few years, through open dumping with out taking any measures to protect the Ground water against pollution. The present study has been taken up to measure the degree of pollution of ground water due to leachate produced in the landfill site. Bore holes were made at eight random locations ...

A strategy for improving pump and treat ground water remediation

International Nuclear Information System (INIS)

Hoffman, F.

1992-07-01

Established pump and treat ground water remediation has a reputation for being too expensive and time consuming, especially when cleanup standards are set at very low levels, e.g., 50 ft below ground surface) widespread ground water contamination. The perceived shortcomings of pump and treat result from the (1) tendency of most contaminants to sorb to formation materials, thus retarding contaminant removal; (2) geologic complexity, which requires detailed characterization for the design of optimal extraction systems within available resources; and (3) failure to apply dynamic well field management techniques. An alternative strategy for improving pump and treat ground water remediation consists of (1) detailed characterization of the geology, hydrology, and chemistry; (2) use of computer-aided data interpretation, data display, and decision support systems; (3) removal of sources, if possible; (4) initial design for plume containment and source remediation; (5) phased installation of the well field; (6) detailed monitoring of the remediation; (7) active ongoing re-evaluation of the operating well field, including redesign as appropriate (dynamic management); (8) re-injection of treated ground water to speed the flushing of contaminants; and (9) setting of appropriate cleanup levels or goals. Use of some or all of these techniques can dramatically reduce the time required to achieve cleanup goals and thus the cost of ground water remediation

Technical approach for the management of UMTRA ground water investigation-derived wastes

International Nuclear Information System (INIS)

1994-02-01

During characterization, remediation, or monitoring activities of the US Department of Energy's (DOE) Uranium Mill Tailings Remedial Action (UMTRA) Project, ground water samples are collected to assess the extent and amount of waterborne contamination that might have come from the mill tailings. This sampling sometimes occurs in contaminated areas where ground water quality has been degraded. Ground water sampling activities may result in field-generated wastes that must be disposed of in a manner protective of human health and the environment. During ground water sampling, appropriate measures must be taken to dispose of presampling purge water and well development water that is pumped to flush out any newly constructed wells. Additionally, pumping tests may produce thousands of gallons of potentially contaminated ground water that must be properly managed. In addition to the liquid wastes, there is the potential for bringing contaminated soils to the ground surface during the drilling and installation of water wells in areas where the subsurface soils may be contaminated. These soils must be properly managed as well. This paper addresses the general technical approach that the UMTRA Project will follow in managing field-generated wastes from well drilling, development, sampling, and testing. It will provide guidance for the preparation of Technical Assistance Contractor (TAC) Standard Operating Procedures (SOP) for the management and disposal of field-generated wastes from ground water monitoring and remediation activities

Estimated ground-water recharge from streamflow in Fortymile Wash near Yucca Mountain, Nevada

International Nuclear Information System (INIS)

Savard, C.S.

1998-01-01

The two purposes of this report are to qualitatively document ground-water recharge from stream-flow in Fortymile Wash during the period 1969--95 from previously unpublished ground-water levels in boreholes in Fortymile Canyon during 1982--91 and 1995, and to quantitatively estimate the long-term ground-water recharge rate from streamflow in Fortymile Wash for four reaches of Fortymile Wash (Fortymile Canyon, upper Jackass Flats, lower Jackass Flats, and Amargosa Desert). The long-term groundwater recharge rate was estimated from estimates of the volume of water available for infiltration, the volume of infiltration losses from streamflow, the ground-water recharge volume from infiltration losses, and an analysis of the different periods of data availability. The volume of water available for infiltration and ground-water recharge in the four reaches was estimated from known streamflow in ephemeral Fortymile Wash, which was measured at several gaging station locations. The volume of infiltration losses from streamflow for the four reaches was estimated from a streamflow volume loss factor applied to the estimated streamflows. the ground-water recharge volume was estimated from a linear relation between infiltration loss volume and ground-water recharge volume for each of the four reaches. Ground-water recharge rates were estimated for three different periods of data availability (1969--95, 1983--95, and 1992--95) and a long-term ground-water recharge rate estimated for each of the four reaches

Estimated ground-water recharge from streamflow in Fortymile Wash near Yucca Mountain, Nevada

Energy Technology Data Exchange (ETDEWEB)

Savard, C.S.

1998-10-01

The two purposes of this report are to qualitatively document ground-water recharge from stream-flow in Fortymile Wash during the period 1969--95 from previously unpublished ground-water levels in boreholes in Fortymile Canyon during 1982--91 and 1995, and to quantitatively estimate the long-term ground-water recharge rate from streamflow in Fortymile Wash for four reaches of Fortymile Wash (Fortymile Canyon, upper Jackass Flats, lower Jackass Flats, and Amargosa Desert). The long-term groundwater recharge rate was estimated from estimates of the volume of water available for infiltration, the volume of infiltration losses from streamflow, the ground-water recharge volume from infiltration losses, and an analysis of the different periods of data availability. The volume of water available for infiltration and ground-water recharge in the four reaches was estimated from known streamflow in ephemeral Fortymile Wash, which was measured at several gaging station locations. The volume of infiltration losses from streamflow for the four reaches was estimated from a streamflow volume loss factor applied to the estimated streamflows. the ground-water recharge volume was estimated from a linear relation between infiltration loss volume and ground-water recharge volume for each of the four reaches. Ground-water recharge rates were estimated for three different periods of data availability (1969--95, 1983--95, and 1992--95) and a long-term ground-water recharge rate estimated for each of the four reaches.

Work plan for ground water elevation data recorder/monitor well installation at Gunnison, Colorado

International Nuclear Information System (INIS)

1994-01-01

The purpose of this document is to describe the work that will be performed and the procedures that will be followed during installation of ground water monitor wells and ground water elevation data recorders (data loggers) at the Gunnison, Colorado, Uranium Mill Tailings Remedial Action (UMTRA) Project site. The monitor wells and data loggers will be used to gather required time-dependent data to investigate the interaction between ground water and surface water in the area. Data collection objectives (DCO) identify reasons for collecting data. The following are DCOs for the Gunnison ground water elevation data recorder/monitor well installation project: long-term continuous ground water level data and periodic ground water samples will be collected to better understand the relationship between surface and ground water at the site; water level and water quality data will eventually be used in future ground water modeling to more firmly establish boundary conditions in the vicinity of the Gunnison processing site; and modeling results will be used to demonstrate and document the potential remedial alternative of natural flushing

Ground Source Heat Pump Sub-Slab Heat Exchange Loop Performance in a Cold Climate

Energy Technology Data Exchange (ETDEWEB)

Mittereder, Nick [IBACOS, Inc., Pittsburgh, PA (United States); Poerschke, Andrew [IBACOS, Inc., Pittsburgh, PA (United States)

2013-11-01

This report presents a cold-climate project that examines an alternative approach to ground source heat pump (GSHP) ground loop design. The innovative ground loop design is an attempt to reduce the installed cost of the ground loop heat exchange portion of the system by containing the entire ground loop within the excavated location beneath the basement slab. Prior to the installation and operation of the sub-slab heat exchanger, energy modeling using TRNSYS software and concurrent design efforts were performed to determine the size and orientation of the system. One key parameter in the design is the installation of the GSHP in a low-load home, which considerably reduces the needed capacity of the ground loop heat exchanger. This report analyzes data from two cooling seasons and one heating season.

Some analytic diagnostic models for transport processes in estuarine and coastal waters; Algunos modelos analiticos de diagnostico para procesos de transporte en estuarios y aguas costeras

Energy Technology Data Exchange (ETDEWEB)

Suarez Antola, R [Industry Energy and Mining Ministry, National Direction of Nuclear Technology, Montevideo (Uruguay)

2001-03-01

Advection and dispersion processes in estuarine and coastal waters are briefly reviewed. Beginning from the basic macroscopic equations of transport for a substance diluted or suspended in the considered body of water,several levels of filtering in time and space are described and applied to obtain suitable diagnostic mathematical models both with scale effects and gaussian.The solutions of the aforementioned models,for initial distributions and boundary conditions with enough symmetry,are discussed, as well as their applications to a parameter characterization of the transport properties of the receiving body of water.

Ground-water quality assessment of the central Oklahoma Aquifer, Oklahoma; project description

Science.gov (United States)

Christenson, S.C.; Parkhurst, D.L.

1987-01-01

In April 1986, the U.S. Geological Survey began a pilot program to assess the quality of the Nation's surface-water and ground-water resources. The program, known as the National Water-Quality Assessment (NAWQA) program, is designed to acquire and interpret information about a variety of water-quality issues. The Central Oklahoma aquifer project is one of three ground-water pilot projects that have been started. The NAWQA program also incudes four surface-water pilot projects. The Central Oklahoma aquifer project, as part of the pilot NAWQA program, will develop and test methods for performing assessments of ground-water quality. The objectives of the Central Oklahoma aquifer assessment are: (1) To investigate regional ground-water quality throughout the aquifer in the manner consistent with the other pilot ground-water projects, emphasizing the occurrence and distribution of potentially toxic substances in ground water, including trace elements, organic compounds, and radioactive constituents; (2) to describe relations between ground-water quality, land use, hydrogeology, and other pertinent factors; and (3) to provide a general description of the location, nature, and possible causes of selected prevalent water-quality problems within the study unit; and (4) to describe the potential for water-quality degradation of ground-water zones within the study unit. The Central Oklahoma aquifer, which includes in descending order the Garber Sandstone and Wellington Formation, the Chase Group, the Council Grove Group, the Admire Group, and overlying alluvium and terrace deposits, underlies about 3,000 square miles of central Oklahoma and is used extensively for municipal, industrial, commercial, and domestic water supplies. The aquifer was selected for study by the NAWQA program because it is a major source for water supplies in central Oklahoma and because it has several known or suspected water-quality problems. Known problems include concentrations of arsenic, chromium

Insights on the Optical Properties of Estuarine DOM – Hydrological and Biological Influences

Science.gov (United States)

Santos, Luísa; Pinto, António; Filipe, Olga; Cunha, Ângela; Santos, Eduarda B. H.

2016-01-01

Dissolved organic matter (DOM) in estuaries derives from a diverse array of both allochthonous and autochthonous sources. In the estuarine system Ria de Aveiro (Portugal), the seasonality and the sources of the fraction of DOM that absorbs light (CDOM) were inferred using its optical and fluorescence properties. CDOM parameters known to be affected by aromaticity and molecular weight were correlated with physical, chemical and meteorological parameters. Two sites, representative of the marine and brackish water zones of the estuary, and with different hydrological characteristics, were regularly surveyed along two years, in order to determine the major influences on CDOM properties. Terrestrial-derived compounds are the predominant source of CDOM in the estuary during almost all the year and the two estuarine zones presented distinct amounts, as well as absorbance and fluorescence characteristics. Freshwater inputs have major influence on the dynamics of CDOM in the estuary, in particular at the brackish water zone, where accounted for approximately 60% of CDOM variability. With a lower magnitude, the biological productivity also impacted the optical properties of CDOM, explaining about 15% of its variability. Therefore, climate changes related to seasonal and inter-annual variations of the precipitation amounts might impact the dynamics of CDOM significantly, influencing its photochemistry and the microbiological activities in estuarine systems. PMID:27195702

Geology and ground-water resources of Goshen County, Wyoming; Chemical quality of the ground water

Science.gov (United States)

Rapp, J.R.; Visher, F.N.; Littleton, R.T.; Durum, W.H.

1957-01-01

Goshen County, which has an area of 2,186 square miles, lies in southeastern Wyoming. The purpose of this study was to evaluate the ground-water resources of the county by determining the character, thickness, and extent of the waterbearing materials; the source, occurrence, movement, quantity, and quality of the ground water; and the possibility of developing additional ground water. The rocks exposed in the area are sedimentary and range in age from Precambrian to Recent. A map that shows the areas of outcrop and a generalized section that summarizes the age, thickness, physical character, and water supply of these formations are included in the report. Owing to the great depths at which they lie beneath most of the county, the formations older than the Lance formation of Late Cretaceous age are not discussed in detail. The Lance formation, of Late Cretaceous age, which consists mainly of beds of fine-grained sandstone and shale, has a maximum thickness of about 1,400 feet. It yields water, which usually is under artesian pressure, to a large number of domestic and stock wells in the south-central part of the county. Tertiary rocks in the area include the Chadron and Brule formations of Oligocene age, the Arikaree formation of Miocene age, and channel deposits of Pliocene age. The Chadron formation is made up of two distinct units: a lower unit of highly variegated fluviatile deposits that has been found only in the report area; and an upper unit that is typical of the formation as it occurs in adjacent areas. The lower unit, which ranges in thickness from a knife edge to about 95 feet, is not known to yield water to wells, but its coarse-grained channel deposits probably would yield small quantities of water to wells. The upper unit, which ranges in thickness from a knife edge to about 150 feet, yields sufficient quantities of water for domestic and stock uses from channel deposits of sandstone under artesian pressure. The Brule formation, which is mainly a

MODELING NITRATE CONCENTRATION IN GROUND WATER USING REGRESSION AND NEURAL NETWORKS

OpenAIRE

Ramasamy, Nacha; Krishnan, Palaniappa; Bernard, John C.; Ritter, William F.

2003-01-01

Nitrate concentration in ground water is a major problem in specific agricultural areas. Using regression and neural networks, this study models nitrate concentration in ground water as a function of iron concentration in ground water, season and distance of the well from a poultry house. Results from both techniques are comparable and show that the distance of the well from a poultry house has a significant effect on nitrate concentration in groundwater.

Estimated Critical Conditions for UO(Sub 2)F(Sub 2)-H(Sub 2)O Systems in Fully Water-Reflected Spherical Geometry

Energy Technology Data Exchange (ETDEWEB)

Jordan, W.C.

1992-01-01

The purpose of this report is to document reference calculations performed using the SCALE-4.0 code system to determine the critical parameters of UO{sub 2}F{sub 2}-H{sub 2}O spheres. The calculations are an extension of those documented in ORNL/CSD/TM-284. Specifically, the data for low-enriched UO{sub 2}F{sub 2}-H{sub 2}O spheres have been extended to highly enriched uranium. These calculations, together with those reported in ORNL/CSD/TM-284, provide a consistent set of critical parameters (k{sub {infinity}}, volume, mass, mass of water) for UO{sub 2}F{sub 2} and water over the full range of enrichment and moderation ratio.

Estimated critical conditions for UO{sub 2}F{sub 2}--H{sub 2}O systems in fully water-reflected spherical geometry

Energy Technology Data Exchange (ETDEWEB)

Jordan, W.C.; Turner, J.C.

1992-12-01

The purpose of this report is to document reference calculations performed using the SCALE-4.0 code system to determine the critical parameters of UO{sub 2}F{sub 2}-H{sub 2}O spheres. The calculations are an extension of those documented in ORNL/CSD/TM-284. Specifically, the data for low-enriched UO{sub 2}F{sub 2}-H{sub 2}O spheres have been extended to highly enriched uranium. These calculations, together with those reported in ORNL/CSD/TM-284, provide a consistent set of critical parameters (k{sub {infinity}}, volume, mass, mass of water) for UO{sub 2}F{sub 2} and water over the full range of enrichment and moderation ratio.

Case study on ground water flow (8)

Energy Technology Data Exchange (ETDEWEB)

NONE

1999-02-01

The report comprises research activities made in fiscal year 1997 under the contract of Japan Nuclear Fuel Cycle Development Center and the main items are: (1) Evaluation of water permeability through discontinuous hard bedrock in deep strata in relevant with underground disposal of radioactive wastes, (2) Three dimensional analysis of permeated water in bedrock, including flow analysis in T ono district using neuro-network and modification of Evaporation Logging System, (3) Development of hydraulic tests and necessary equipment applicable to measurements of complex dielectric constants of contaminated soils using FUDR-V method, this giving information on soil component materials, (4) Investigation methods and modeling of hydraulics in deep strata, (5) Geological study of ground water using environmental isotopes such as {sup 14}C, {sup 36}Cl and {sup 4}He, particularly measurement of ages of ground water using an accelerator-mass spectrometer, and (6) Re-submerging phenomena affecting the long-term geological stability. (S. Ohno)

Case study on ground water flow (8)

International Nuclear Information System (INIS)

1999-02-01

The report comprises research activities made in fiscal year 1997 under the contract of Japan Nuclear Fuel Cycle Development Center and the main items are: (1) Evaluation of water permeability through discontinuous hard bedrock in deep strata in relevant with underground disposal of radioactive wastes, (2) Three dimensional analysis of permeated water in bedrock, including flow analysis in T ono district using neuro-network and modification of Evaporation Logging System, (3) Development of hydraulic tests and necessary equipment applicable to measurements of complex dielectric constants of contaminated soils using FUDR-V method, this giving information on soil component materials, (4) Investigation methods and modeling of hydraulics in deep strata, (5) Geological study of ground water using environmental isotopes such as 14 C, 36 Cl and 4 He, particularly measurement of ages of ground water using an accelerator-mass spectrometer, and (6) Re-submerging phenomena affecting the long-term geological stability. (S. Ohno)

Estimating the Ground Water Resources of Atoll Islands

Directory of Open Access Journals (Sweden)

Arne E. Olsen

2010-01-01

Full Text Available Ground water resources of atolls, already minimal due to the small surface area and low elevation of the islands, are also subject to recurring, and sometimes devastating, droughts. As ground water resources become the sole fresh water source when rain catchment supplies are exhausted, it is critical to assess current groundwater resources and predict their depletion during drought conditions. Several published models, both analytical and empirical, are available to estimate the steady-state freshwater lens thickness of small oceanic islands. None fully incorporates unique shallow geologic characteristics of atoll islands, and none incorporates time-dependent processes. In this paper, we provide a review of these models, and then present a simple algebraic model, derived from results of a comprehensive numerical modeling study of steady-state atoll island aquifer dynamics, to predict the ground water response to changes in recharge on atoll islands. The model provides an estimate thickness of the freshwater lens as a function of annual rainfall rate, island width, Thurber Discontinuity depth, upper aquifer hydraulic conductivity, presence or absence of a confining reef flat plate, and in the case of drought, time. Results compare favorably with published atoll island lens thickness observations. The algebraic model is incorporated into a spreadsheet interface for use by island water resources managers.

Dynamics of flood water infiltration and ground water recharge in hyperarid desert.

Science.gov (United States)

Dahan, Ofer; Tatarsky, Boaz; Enzel, Yehouda; Kulls, Christoph; Seely, Mary; Benito, Gererdo

2008-01-01

A study on flood water infiltration and ground water recharge of a shallow alluvial aquifer was conducted in the hyperarid section of the Kuiseb River, Namibia. The study site was selected to represent a typical desert ephemeral river. An instrumental setup allowed, for the first time, continuous monitoring of infiltration during a flood event through the channel bed and the entire vadose zone. The monitoring system included flexible time domain reflectometry probes that were designed to measure the temporal variation in vadose zone water content and instruments to concurrently measure the levels of flood and ground water. A sequence of five individual floods was monitored during the rainy season in early summer 2006. These newly generated data served to elucidate the dynamics of flood water infiltration. Each flood initiated an infiltration event which was expressed in wetting of the vadose zone followed by a measurable rise in the water table. The data enabled a direct calculation of the infiltration fluxes by various independent methods. The floods varied in their stages, peaks, and initial water contents. However, all floods produced very similar flux rates, suggesting that the recharge rates are less affected by the flood stages but rather controlled by flow duration and available aquifer storage under it. Large floods flood the stream channel terraces and promote the larger transmission losses. These, however, make only a negligible contribution to the recharge of the ground water. It is the flood duration within the active streambed, which may increase with flood magnitude that is important to the recharge process.

Algal stabilisation of estuarine sediments

International Nuclear Information System (INIS)

1992-01-01

The presence of benthic microalgae can increase the stability of intertidal sediments and influence sediment fluxes within an estuarine environment. Therefore the relative importance of algal stabilisation needs to be understood to help predict the effects of a tidal barrage. The biogenic stabilisation of intertidal estuarine sediments by epipelic diatom films and the macrophyte Vaucheria was studied at three sites on the Severn Estuary. The cohesive strength meter (CSM) was developed to measure surface critical shear stress with varied algal density. A number of techniques have been used to determine the general in situ erodibility of cohesive estuarine sediments. The measurements of sediment shear strength and critical erosion velocity were investigated. Field experiments were undertaken to investigate the effect of algae on binding sediments, and a predictive method for the assessment of sediment stabilisation by algal binding was developed. (author)

Ground-water solute transport modeling using a three-dimensional scaled model

International Nuclear Information System (INIS)

Crider, S.S.

1987-01-01

Scaled models are used extensively in current hydraulic research on sediment transport and solute dispersion in free surface flows (rivers, estuaries), but are neglected in current ground-water model research. Thus, an investigation was conducted to test the efficacy of a three-dimensional scaled model of solute transport in ground water. No previous results from such a model have been reported. Experiments performed on uniform scaled models indicated that some historical problems (e.g., construction and scaling difficulties; disproportionate capillary rise in model) were partly overcome by using simple model materials (sand, cement and water), by restricting model application to selective classes of problems, and by physically controlling the effect of the model capillary zone. Results from these tests were compared with mathematical models. Model scaling laws were derived for ground-water solute transport and used to build a three-dimensional scaled model of a ground-water tritium plume in a prototype aquifer on the Savannah River Plant near Aiken, South Carolina. Model results compared favorably with field data and with a numerical model. Scaled models are recommended as a useful additional tool for prediction of ground-water solute transport

Ground and excited state absorption of Ni{sup 2+} ions in MgAl{sub 2}O{sub 4}: Crystal field analysis

Energy Technology Data Exchange (ETDEWEB)

Brik, M.G. [Fukui Institute for Fundamental Chemistry, Kyoto University, 34-4 Takano Nishihiraki-cho, Sakyo-ku, Kyoto 606-8103 (Japan) and Department of Chemistry, School of Science and Technology, Kwansei Gakuin University, 2-1 Gakuen, Sanda, Hyogo 669-1337 (Japan)]. E-mail: brik@fukui.kyoto-u.ac.jp; Avram, N.M. [Department of Physics, West University of Timisoara, Bd. V. Parvan No. 4, 300223 Timisoara (Romania); Avram, C.N. [Department of Physics, West University of Timisoara, Bd. V. Parvan No. 4, 300223 Timisoara (Romania); Rudowicz, C. [Institute of Physics, Szczecin University of Technology, Al. Piastow 17, 70-310 Szczecin (Poland); Yeung, Y.Y. [Department of Mathematics, Science, Social Sciences and Technology, The Hong Kong Institute of Education, 10 Lo Ping Road, Tai Po, New Territories (Hong Kong); Gnutek, P. [Institute of Physics, Szczecin University of Technology, Al. Piastow 17, 70-310 Szczecin (Poland)

2007-04-25

The exchange charge model (ECM) of crystal field is utilized to provide the theoretical explanation of the ground state absorption and the excited state absorption observed for the octahedrally coordinated Ni{sup 2+} ions in the spinel MgAl{sub 2}O{sub 4}. The ECM enables modeling of the crystal field parameters (CFPs) for the impurity ions based on the crystal structure data of the host lattice. To ensure the reliability of the CFPs, the convergence of the CFP values with the increasing number of the coordination spheres taken into account in the ECM calculations is considered. The trigonal CFPs B{sub 2}{sup 0},B{sub 4}{sup 0}andB{sub 4}{sup -3} determined by the ECM, together with the appropriate Racah parameters B and C, serve as input to two crystal field analysis computer packages, which compute the energy level schemes within the whole 3d{sup 8} configuration. The cubic approximation utilizing only one CFP Dq is also discussed. Basic features of the ground and excited state absorption spectra observed for MgAl{sub 2}O{sub 4}:Ni{sup 2+} are satisfactorily explained by our crystal field analysis. In order to model the pressure dependence of the CFPs (and thus of the absorption spectra when relevant experimental data become available), the variation of the CFPs induced by possible distortions of the lattice due to, e.g. overall relaxation of the ions or accommodation of the impurity ions in the lattice, is studied. Analysis of the experimental absorption spectra enables us to evaluate also the Huang-Rhys parameter, the effective phonon energy, and the zero-phonon line position.

Three-dimensional semi-idealized model for estuarine turbidity maxima in tidally dominated estuaries

NARCIS (Netherlands)

Kumar, Mohit; Schuttelaars, Henk M.; Roos, Pieter C.

2017-01-01

We develop a three-dimensional idealized model that is specifically aimed at gaining insight in the physical mechanisms resulting in the formation of estuarine turbidity maxima in tidally dominated estuaries. First, the three-dimensional equations for water motion and suspended sediment

The management-retrieval code of the sub-library of atomic mass and characteristic constants for nuclear ground state

International Nuclear Information System (INIS)

Su Zongdi; Ma Lizhen

1994-01-01

The management code of the sub-library of atomic mass and characteristic constants for nuclear ground state (MCC) is used for displaying the basic information on the MCC sub-library on the screen, and retrieving the required data. The MCC data file contains the data of 4800 nuclides ranging from Z 0, A = 1 to Z = 122, A = 318. The MCC sub-library has been set up at Chinese Nuclear Data Center (CNDC), and has been used to provide the atomic masses and characteristic constants of nuclear ground states for the nuclear model calculation, nuclear data evaluations and other fields

Hybrid Genetic Algorithm - Local Search Method for Ground-Water Management

Science.gov (United States)

Chiu, Y.; Nishikawa, T.; Martin, P.

2008-12-01

Ground-water management problems commonly are formulated as a mixed-integer, non-linear programming problem (MINLP). Relying only on conventional gradient-search methods to solve the management problem is computationally fast; however, the methods may become trapped in a local optimum. Global-optimization schemes can identify the global optimum, but the convergence is very slow when the optimal solution approaches the global optimum. In this study, we developed a hybrid optimization scheme, which includes a genetic algorithm and a gradient-search method, to solve the MINLP. The genetic algorithm identifies a near- optimal solution, and the gradient search uses the near optimum to identify the global optimum. Our methodology is applied to a conjunctive-use project in the Warren ground-water basin, California. Hi- Desert Water District (HDWD), the primary water-manager in the basin, plans to construct a wastewater treatment plant to reduce future septic-tank effluent from reaching the ground-water system. The treated wastewater instead will recharge the ground-water basin via percolation ponds as part of a larger conjunctive-use strategy, subject to State regulations (e.g. minimum distances and travel times). HDWD wishes to identify the least-cost conjunctive-use strategies that control ground-water levels, meet regulations, and identify new production-well locations. As formulated, the MINLP objective is to minimize water-delivery costs subject to constraints including pump capacities, available recharge water, water-supply demand, water-level constraints, and potential new-well locations. The methodology was demonstrated by an enumerative search of the entire feasible solution and comparing the optimum solution with results from the branch-and-bound algorithm. The results also indicate that the hybrid method identifies the global optimum within an affordable computation time. Sensitivity analyses, which include testing different recharge-rate scenarios, pond

Noble Gases in Lakes and Ground Waters

OpenAIRE

Kipfer, Rolf; Aeschbach-Hertig, Werner; Peeters, Frank; Stute, Marvin

2002-01-01

In contrast to most other fields of noble gas geochemistry that mostly regard atmospheric noble gases as 'contamination,' air-derived noble gases make up the far largest and hence most important contribution to the noble gas abundance in meteoric waters, such as lakes and ground waters. Atmospheric noble gases enter the meteoric water cycle by gas partitioning during air / water exchange with the atmosphere. In lakes and oceans noble gases are exchanged with the free atmosphere at the surface...

Hydrogeologic setting, water budget, and preliminary analysis of ground-water exchange at Lake Starr, a seepage lake in Polk County, Florida

Science.gov (United States)

Swancar, Amy; Lee, T.M.; O'Hare, T. M.

2000-01-01

Lake Starr, a 134-acre seepage lake of multiple-sinkhole origin on the Lake Wales Ridge of central Florida, was the subject of a detailed water-budget study from August 1996 through July 1998. The study monitored the effects of hydrogeologic setting, climate, and ground-water pumping on the water budget and lake stage. The hydrogeologic setting of the Lake Starr basin differs markedly on the two sides of the lake. Ground water from the surficial aquifer system flows into the lake from the northwest side of the basin, and lake water leaks out to the surficial aquifer system on the southeast side of the basin. Lake Starr and the surrounding surficial aquifer system recharge the underlying Upper Floridan aquifer. The rate of recharge to the Upper Floridan aquifer is determined by the integrity of the intermediate confining unit and by the downward head gradient between the two aquifers. On the inflow side of the lake, the intermediate confining unit is more continuous, allowing ground water from the surficial aquifer system to flow laterally into the lake. Beneath the lake and on the southeast side of the basin, breaches in the intermediate confining unit enhance downward flow to the Upper Floridan aquifer, so that water flows both downward and laterally away from the lake through the ground-water flow system in these areas. An accurate water budget, including evaporation measured by the energy-budget method, was used to calculate net ground-water flow to the lake, and to do a preliminary analysis of the relation of net ground-water fluxes to other variables. Water budgets constructed over different timeframes provided insight on processes that affect ground-water interactions with Lake Starr. Weekly estimates of net ground-water flow provided evidence for the occurrence of transient inflows from the nearshore basin, as well as the short-term effects of head in the Upper Floridan aquifer on ground-water exchange with the lake. Monthly water budgets showed the effects

Anomalous Ground State of the Electrons in Nano-confined Water

Science.gov (United States)

2016-06-13

Anomalous ground state of the electrons in nano -confined water G. F. Reiter1*, Aniruddha Deb2*, Y. Sakurai3, M. Itou3, V. G. Krishnan4, S. J...electronic ground state of nano -confined water must be responsible for these anomalies but has so far not been investigated. We show here for the first time...using x-ray Compton scattering and a computational model, that the ground state configuration of the valence electrons in a particular nano

Summary appraisals of the Nation's ground-water resources; Texas Gulf region

Science.gov (United States)

Baker, E.T.; Wall, James Ray

1974-01-01

Ground water in the Texas-Gulf Region is a large and important resource that can provide a more significant percentage of the total water supply of the region. Total water requirements within the region are projected to rise sharply from 14 million acre-feet (17 cubic kilometres) in 1970 to nearly 26 million acre-feet (32.cubic kilometres) in 2020. About half of the water used in 1970 was ground water.

Hydro-geochemical and isotopic composition of ground water in Helwan area

Directory of Open Access Journals (Sweden)

W.M. Salem

2015-12-01

The environmental stable isotopes oxygen and hydrogen (18O, and deuterium were studied and used to identify the sources of recharge. The studied ground waters are enriched in D and 18O and the isotopic features suggest that most of the ground water recharged indirectly after evaporation prior to infiltration from irrigation return water as well as the contribution from Nile water.

Apparatus for ground water chemistry investigations in field caissons

International Nuclear Information System (INIS)

Cokal, E.J.; Stallings, E.; Walker, R.; Nyhan, J.W.; Polzer, W.L.; Essington, E.H.

1985-01-01

Los Alamos is currently in its second season of ground water chemistry and hydrology experimentation in a field facility that incorporates clusters of six, 3-meter-diameter by 6-meter-deep, soil-filled caissons and required ancillaries. Initial experience gained during the 1983 field season indicated the need for further development of the technology of this type of experimentation supporting hydrologic waste management research. Uniform field application of water/matrix solutions to the caisson, matrix and tracer solution blending/storage, and devices for ground water sampling are discussed

Quality of surface water and ground water in the proposed artificial-recharge project area, Rillito Creek basin, Tucson, Arizona, 1994

Science.gov (United States)

Tadayon, Saeid

1995-01-01

Controlled artificial recharge of surface runoff is being considered as a water-management technique to address the problem of ground-water overdraft. The planned use of recharge facilities in urban areas has caused concern about the quality of urban runoff to be recharged and the potential for ground-water contamination. The proposed recharge facility in Rillito Creek will utilize runoff entering a 1-mile reach of the Rillito Creek between Craycroft Road and Swan Road for infiltration and recharge purposes within the channel and excavated overbank areas. Physical and chemical data were collected from two surface-water and two ground-water sites in the study area in 1994. Analyses of surface-water samples were done to determine the occurrence and concentration of potential contaminants and to determine changes in quality since samples were collected during 1987-93. Analyses of ground-water samples were done to determine the variability of ground-water quality at the monitoring wells throughout the year and to determine changes in quality since samples were collected in 1989 and 1993. Surface-water samples were collected from Tanque Verde Creek at Sabino Canyon Road (streamflow-gaging station Tanque Verde Creek at Tucson, 09484500) and from Alamo Wash at Fort Lowell Road in September and May 1994, respectively. Ground-water samples were collected from monitoring wells (D- 13-14)26cbb2 and (D-13-14)26dcb2 in January, May, July, and October 1994. In surface water, calcium was the dominant cation, and bicarbonate was the dominant anion. In ground water, calcium and sodium were the dominant cations and bicarbonate was the dominant anion. Surface water in the area is soft, and ground water is moderately hard to hard. In surface water and ground water, nitrogen was found predominantly as nitrate. Concentrations of manganese in ground-water samples ranged from 60 to 230 micrograms per liter and exceeded the U.S. Environmental Protection Agency secondary maximum contaminant

Surface-Water, Water-Quality, and Ground-Water Assessment of the Municipio of Mayaguez, Puerto Rico, 1999-2002

Science.gov (United States)

Rodríguez-Martínez, Jesús; Santiago-Rivera, Luis; Guzman-Rios, Senen; Gómez-Gómez, Fernando; Oliveras-Feliciano, Mario L.

2004-01-01

five hydrogeologic terranes. This integrated database then was used to evaluate the ground-water potential of each hydrogeologic terrane. Lineament-trace analysis was used to help assess the ground-water development potential in the hydrogeologic terranes containing igneous rocks. Analyses suggest that areas with slopes greater than 15 degrees have relatively low ground-water development potential. The presence of fractures, independent of the topographic slope, may locally enhance the water-bearing properties in the hydrogeologic terranes containing igneous rocks. The results of this study indicate that induced streamflow generally is needed to sustain low to moderate ground-water withdrawal rates in the five hydrogeologic terranes. The ground-water flow systems in the hydrogeologic terranes are only able to sustain small withdrawal rates that rarely exceed 50 gallons per minute. Areas with a high density of fractures, as could be the case at the intersection of lineament traces in the upper parts of the Rio Ca?as and Rio Yaguez watersheds, are worthy of exploratory drilling for ground-water development.

MINTEQ, Geochemical Equilibria in Ground Water

International Nuclear Information System (INIS)

Krupka, K.M.

1990-01-01

1 - Description of program or function: MINTEQ is a geochemical program to model aqueous solutions and the interactions of aqueous solutions with hypothesized assemblages of solid phases. It was developed for the Environmental Protection Agency to perform the calculations necessary to simulate the contact of waste solutions with heterogeneous sediments or the interaction of ground water with solidified wastes. MINTEQ can calculate ion speciation/solubility, adsorption, oxidation-reduction, gas phase equilibria, and precipitation/dissolution of solid phases. MINTEQ can accept a finite mass for any solid considered for dissolution and will dissolve the specified solid phase only until its initial mass is exhausted. This ability enables MINTEQ to model flow-through systems. In these systems the masses of solid phases that precipitate at earlier pore volumes can be dissolved at later pore volumes according to thermodynamic constraints imposed by the solution composition and solid phases present. The ability to model these systems permits evaluation of the geochemistry of dissolved traced metals, such as low-level waste in shallow land burial sites. MINTEQ was designed to solve geochemical equilibria for systems composed of one kilogram of water, various amounts of material dissolved in solution, and any solid materials that are present. Systems modeled using MINTEQ can exchange energy and material (open systems) or just energy (closed systems) with the surrounding environment. Each system is composed of a number of phases. Every phase is a region with distinct composition and physically definable boundaries. All of the material in the aqueous solution forms one phase. The gas phase is composed of any gaseous material present, and structurally distinct solid forms a separate phase. 2 - Method of solution: MINTEQ applies the fundamental principles of thermodynamics to solve geochemical equilibria from a set of mass balance equations, one for each component. Because the

GSFLOW - Coupled Ground-Water and Surface-Water Flow Model Based on the Integration of the Precipitation-Runoff Modeling System (PRMS) and the Modular Ground-Water Flow Model (MODFLOW-2005)

Science.gov (United States)

Markstrom, Steven L.; Niswonger, Richard G.; Regan, R. Steven; Prudic, David E.; Barlow, Paul M.

2008-01-01

The need to assess the effects of variability in climate, biota, geology, and human activities on water availability and flow requires the development of models that couple two or more components of the hydrologic cycle. An integrated hydrologic model called GSFLOW (Ground-water and Surface-water FLOW) was developed to simulate coupled ground-water and surface-water resources. The new model is based on the integration of the U.S. Geological Survey Precipitation-Runoff Modeling System (PRMS) and the U.S. Geological Survey Modular Ground-Water Flow Model (MODFLOW). Additional model components were developed, and existing components were modified, to facilitate integration of the models. Methods were developed to route flow among the PRMS Hydrologic Response Units (HRUs) and between the HRUs and the MODFLOW finite-difference cells. This report describes the organization, concepts, design, and mathematical formulation of all GSFLOW model components. An important aspect of the integrated model design is its ability to conserve water mass and to provide comprehensive water budgets for a location of interest. This report includes descriptions of how water budgets are calculated for the integrated model and for individual model components. GSFLOW provides a robust modeling system for simulating flow through the hydrologic cycle, while allowing for future enhancements to incorporate other simulation techniques.

Hanford ground-water data base management guide and user's manual

International Nuclear Information System (INIS)

Mitchell, P.J.; Argo, R.S.; Bradymire, S.L.; Newbill, C.A.

1985-05-01

This management guide and user's manual is a working document for the computerized Hanford Ground-water Data Base maintained by the Geosciences Research and Engineering Department at Pacific Northwest Laboratory for the Hanford Ground-Water Surveillance Program. The program is managed by the Occupational and Environmental Protection Department for the US Department of Energy. The data base is maintained to provide rapid access to data that are rountinely collected from ground-water monitoring wells at the Hanford site. The data include water levels, sample analyses, geologic descriptions and well construction information of over 3000 existing or destroyed wells. These data are used to monitor water quality and for the evaluation of ground-water flow and pollutant transport problems. The management guide gives instructions for maintenance of the data base on the Digital Equipment Corporation PDP 11/70 Computer using the CIRMIS (Comprehensive Information Retrieval and Model Input Sequence) data base management software developed at Pacific Northwest Laboratory. Maintenance activities include inserting, modifying and deleting data, making back-up copies of the data base, and generating tables for annual monitoring reports. The user's guide includes instructions for running programs to retrieve the data in the form of listings of graphical plots. 3 refs

Colloid Detection in Natural Ground Water from Ruprechtov by Laser-Induced Breakdown Detection

Energy Technology Data Exchange (ETDEWEB)

Hauser, W.; Geckeis, H.; Goetz, R. [FZK - Inst. fuer Nukleare Entsorgung, Ka rlsruhe (Germany)]. e-mail: hauser@ine.fzk.de; Noseck, U. [Gesellschaft fuer Anlagen- und Reaktorsicherheit, D-38122 Braunschweig (Germany); Laciok, A. [Nuclear Research Inst. Rez plc, Waste and Environmental Management Dept., Husinec-Rez, PSC 250 68 (Czech Republic)

2007-06-15

A borehole ground water sampling system and a mobile laser-induced breakdown detection (LIBD) equipment for colloid detection combined with a geomonitoring unit have been applied to characterize the natural background colloid concentration in ground waters of the Ruprechtov natural analogue site (Czech Republic). Ground water has been sampled using steel cylinders. To minimize artifacts during ground water sampling the contact to atmospheric oxygen has been excluded. The ground water samples collected in this way are transported to the laboratory where they have been connected to a series of flow-through detection cells. Argon gas is used to press the ground water through these detection cells for colloid analysis (LIBD), pH, Eh, electrical conductivity and oxygen content. After the above mentioned analysis additional samples are taken for chemical analysis by ICP-AES, ICP-MS, IC- and DOC-detection. Our data obtained by in-situ- and laboratory- measurements point out that the natural colloid concentration found at the Ruprechtov site is a strong function of the ground water ionic strength. The LIBD determined natural background colloid concentrations found at Ruprechtov are compared with data of studies performed in Aespoe (Sweden) and Grimsel (Switzerland)

Ground-Water Nutrient Flux to Coastal Waters and Numerical Simulation of Wastewater Injection at Kihei, Maui, Hawaii

Science.gov (United States)

Hunt, Charles D.

2007-01-01

Water sampling and numerical modeling were used to estimate ground-water nutrient fluxes in the Kihei area of Maui, where growth of macroalgae (seaweed) on coral reefs raises ecologic concerns and accumulation on beaches has caused odor and removal problems. Fluxes and model results are highly approximate, first-order estimates because very few wells were sampled and there are few field data to constrain model calibration. Ground-water recharge was estimated to be 22.6 Mgal/d (million gallons per day) within a 73-square-mile area having a coastline length of 8 miles or 13 km (kilometers). Nearly all of the recharge discharges at the coast because ground-water withdrawals are small. Another 3.0 Mgal/d of tertiary-treated wastewater effluent is injected into the regional aquifer at a County treatment plant midway along the coast and about a mile from shore. The injection plume is 0.93 miles wide (1.5 km) at the shore, as estimated from a three-dimensional numerical ground-water model. Wastewater injected beneath the brackish ground-water lens rises buoyantly and spreads out at the top of the lens, diverting and mixing with ambient ground water. Ground water discharging from the core of the injection plume is less than 5 years old and is about 60 percent effluent at the shore, according to the model. Dissolved nitrogen and phosphorus concentrations in treated effluent were 7.33 and 1.72 milligrams per liter, roughly 6 and 26 times background concentrations at an upgradient well. Background nitrogen and phosphorus fluxes carried by ground water are 7.7 and 0.44 kg/d-km (kilograms per day per kilometer of coast). Injected wastewater fluxes distributed across the plume width are 55 and 13 kg/d-km nitrogen and phosphorus, roughly 7 and 30 times background flux. However, not all of the injected load reaches coastal waters because nutrients are naturally attenuated in the oxygen-depleted effluent plume. Water from a downgradient well reflects this attenuation and provides a

Detection of Ground Water Availability at Buhias Island, Sitaro Regency

Directory of Open Access Journals (Sweden)

Zetly E Tamod

2016-08-01

Full Text Available The study aims to detect ground water availability at Buhias Island, Siau Timur Selatan District, Sitaro Regency. The research method used the survey method by geoelectrical instrument based on subsurface rock resistivity as a geophysical exploration results with geoelectrical method of Wenner-Schlumberger configuration. Resistivity geoelectrical method is done by injecting a flow into the earth surface, then it is measured the potential difference. This study consists of 4 tracks in which each track is made the stretch model of soil layer on subsurface of ground.  Then, the exploration results were processed using software RES2DINV to look at the data of soil layer based on the value of resistivity (2D. Interpretation result of the track 1 to 4 concluded that there is a layer of ground water. State of dominant ground water contains the saline (brackish. Location of trajectory in the basin to the lowland areas is mostly mangrove swamp vegetation. That location is the junction between the results of the runoff of rainfall water that falls down from the hills with sea water. Bedrock as a constituent of rock layer formed from marine sediments that carry minerals salts.

Organic contamination of ground water at Gas Works Park, Seattle, Washington

International Nuclear Information System (INIS)

Turney, G.L.; Goerlitz, D.F.

1990-01-01

Gas Works Park, in Seattle, Washington, is located on the site of a coal and oil gasification plant that ceased operation in 1956. During operation, many types of wastes, including coal, tar, and oil, accumulated on-site. The park soil is currently (1986) contaminated with compounds such as polynuclear aromatic hydrocarbons, volatile organic compounds, trace metals, and cyanide. Analyses of water samples from a network of observation wells in the park indicate that these compounds are also present in the ground water. Polynuclear aromatic hydrocarbons and volatile organic compounds were identified in ground water samples in concentrations as large as 200 mg/L. Concentrations of organic compounds were largest where ground water was in contact with a non-aqueous phase liquid in the soil. Where no non-aqueous phase liquid was present, concentrations were much smaller, even if the ground water was in contact with contaminated soils. This condition is attributed to weathering processes in which soluble, low-molecular-weight organic compounds are preferentially dissolved from the non-aqueous phase liquid into the ground water. Where no non-aqueous phase liquid is present, only stained soils containing relatively insoluble, high-molecular-weight compounds remain. Concentrations of organic contaminants in the soils may still remain large

Organic contamination of ground water at Gas Works Park, Seattle, Washington

Science.gov (United States)

Turney, G.L.; Goerlitz, D.F.

1990-01-01

Gas Works Park, in Seattle, Washington, is located on the site of a coal and oil gasification plant that ceased operation in 1956. During operation, many types of wastes, including coal, tar, and oil, accumulated on-site. The park soil is currently (1986) contaminated with compounds such as polynuclear aromatic hydrocarbons, volatile organic compounds, trace metals, and cyanide. Analyses of water samples from a network of observation wells in the park indicate that these compounds are also present in the ground water. Polynuclear aromatic hydrocarbons and volatile organic compounds were identified in ground water samples in concentrations as large as 200 mg/L. Concentrations of organic compounds were largest where ground water was in contact with a non-aqueous phase liquid in the soil. Where no non-aqueous phase liquid was present, concentrations were much smaller, even if the ground water was in contact with contaminated soils. This condition is attributed to weathering processes in which soluble, low-molecular-weight organic compounds are preferentially dissolved from the non-aqueous phase liquid into the ground water. Where no non-aqueous phase liquid is present, only stained soils containing relatively insoluble, high-molecular-weight compounds remain. Concentrations of organic contaminants in the soils may still remain large.

Optimization of ground-water withdrawal in the lower Fox River communities, Wisconsin

Science.gov (United States)

Walker, J.F.; Saad, D.A.; Krohelski, J.T.

1998-01-01

Pumping from closely spaced wells in the Central Brown County area and the Fox Cities area near the north shore of Lake Winnebago has resulted in the formation of deep cones of depression in the vicinity of the two pumping centers. Water-level measurements indicate there has been a steady decline in water levels in the vicinity of these two pumping centers for the past 50 years. This report describes the use of ground-water optimization modeling to efficiently allocate the ground-water resources in the Lower Fox River Valley. A 3-dimensional ground-water flow model was used along with optimization techniques to determine the optimal withdrawal rates for a variety of management alternatives. The simulations were conducted separately for the Central Brown County area and the Fox Cities area. For all simulations, the objective of the optimization was to maximize total ground-water withdrawals. The results indicate that ground water can supply nearly all of the projected 2030 demand for Central Brown County municipalities if all of the wells are managed (including the city of Green Bay), 8 new wells are installed, and the water-levels are allowed to decline to 100 ft below the bottom of the confining unit. Ground water can supply nearly all of the projected 2030 demand for the Fox Cities if the municipalities in Central Brown County convert to surface water; if Central Brown County municipalities follow the optimized strategy described above, there will be a considerable shortfall of available ground water for the Fox Cities communities. Relaxing the water-level constraint in a few wells, however, would likely result in increased availability of water. In all cases examined, optimization alternatives result in a rebound of the steady-state water levels due to projected 2030 withdrawal rates to levels at or near the bottom of the confining unit, resulting in increased well capacity. Because the simulations are steady-state, if all of the conditions of the model remain

North Inlet-Winyah Bay National Estuarine Research Reserve's (NERR) Estuarine Water Quality Data for the North Inlet and Winyah Bay Estuaries, Georgetown, South Carolina: 1993-2002

Data.gov (United States)

Baruch Institute for Marine and Coastal Sciences, Univ of South Carolina — The North Inlet Estuary and the adjacent lower northeastern section of the Winyah Bay Estuary were designated as part of the National Estuarine Research Reserve...

Modeling the effects of longwall mining on the ground water system

International Nuclear Information System (INIS)

Matetic, R.J.; Liu, J.; Elsworth, D.

1995-01-01

The objective of this US Bureau of Mines hydrologic-subsidence investigation was to evaluate the effects of longwall mining on the local ground water regime through field monitoring and numerical modeling. Field data were obtained from multiple-position borehole extensometers (MPBXs) that were used to measure subsurface displacements. Survey monuments were installed to measure mining-induced surface deformations. Numerous drawdown and recovery tests were performed to characterized hydrologic properties of the overburden strata. Coreholes were drilled above the study area to determine lithologic and strength characteristics of the overburden strata using the rock samples collected. Electronic recorders were installed on all monitoring wells to continuously monitor ground water levels in coordination with mining of the longwall panels. A combined finite element model of the deformation of overlying strata, and its influence on ground water flow was used to define the change in local and regional water budgets. The predicted effects of the postmining ground water system determined by the model correlated well with field data collected from the fieldsite. Without an infiltration rate added to the model, a static decrease of 3.0 m (10 ft) in water level would occur due to mining of both longwall panels and if an infiltration rate was inputted in the model, no predicted long-term effects would occur to the ground water system

Identification of contaminants of concern in Hanford ground waters

International Nuclear Information System (INIS)

Sherwood, D.R.; Evans, J.C.; Bryce, R.W.

1990-01-01

More than 1,500 waste-disposal sites have been identified at the U.S. Department of Energy Hanford Site. At the request of the U.S. Environmental Protection Agency, these sites were aggregated into four administrative areas for listing on the National Priority List. Within the four aggregate areas, 646 inactive sites were selected for further evaluation using the Hazard Ranking System (HRS). Evaluation of inactive waste sites by HRS provided valuable insight to design a focused radiological- and hazardous-substance monitoring network. Hanford Site-wide ground-water monitoring was expanded to address not only radioactive constituents but also hazardous chemicals. The HRS scoring process considers the likelihood of ground-water contamination from past disposal practices at inactive waste sites. The network designed to monitor ground water at those facilities identified 129 I, 99 Tc, 90 Sr, uranium, chromium, carbon tetrachloride, and cyanide

Nutrient Enrichment in Estuaries from Discharge of Shallow Ground Water, Mt. Desert Island, Maine

Science.gov (United States)

Culbertson, Charles W.; Huntington, Thomas G.; Caldwell, James M.

2007-01-01

Nutrient enrichment from atmospheric deposition, agricultural activities, wildlife, and domestic sources is a concern at Acadia National Park because of the potential problem of water-quality degradation and eutrophication in its estuaries. Water-quality degradation has been observed at the Park?s Bass Harbor Marsh estuary but not in Northeast Creek estuary. Previous studies at Acadia National Park have estimated nutrient inputs to estuaries from atmospheric deposition and surface-water runoff, but the importance of shallow ground water that may contain nutrients derived from domestic or other sources is unknown. Northeast Creek and Bass Harbor Marsh estuaries were studied to (1) identify shallow ground-water seeps, (2) assess the chemistry of the water discharged from selected seeps, and (3) assess the chemistry of ground water in shallow ground-water hyporheic zones. The hyporheic zone is defined here as the region beneath and lateral to a stream bed, where there is mixing of shallow ground water and surface water. This study also provides baseline chemical data for ground water in selected bedrock monitoring wells and domestic wells on Mt. Desert Island. Water samples were analyzed for concentrations of nutrients, wastewater compounds, dissolved organic carbon, pH, dissolved oxygen, temperature and specific conductance. Samples from bedrock monitoring wells also were analyzed for alkalinity, major cations and anions, and trace metals. Shallow ground-water seeps to Northeast Creek and Bass Harbor Marsh estuaries at Acadia National Park were identified and georeferenced using aerial infrared digital imagery. Monitoring included the deployment of continuously recording temperature and specific conductance sensors in the seep discharge zone to access marine or freshwater signatures related to tidal flooding, gradient-driven shallow ground-water flow, or shallow subsurface flow related to precipitation events. Many potential shallow ground-water discharge zones were

Simulation of the fate of faecal bacteria in estuarine and coastal waters based on a fractionated sediment transport model

Science.gov (United States)

Yang, Chen; Liu, Ying

2017-08-01

A two-dimensional depth-integrated numerical model is refined in this paper to simulate the hydrodynamics, graded sediment transport process and the fate of faecal bacteria in estuarine and coastal waters. The sediment mixture is divided into several fractions according to the grain size. A bed evolution model is adopted to simulate the processes of the bed elevation change and sediment grain size sorting. The faecal bacteria transport equation includes enhanced source and sink terms to represent bacterial kinetic transformation and disappearance or reappearance due to sediment deposition or re-suspension. A novel partition ratio and dynamic decay rates of faecal bacteria are adopted in the numerical model. The model has been applied to the turbid water environment in the Bristol Channel and Severn estuary, UK. The predictions by the present model are compared with field data and those by non-fractionated model.

Sup(239,240)Pu in estuarine and shelf waters of the north-eastern United States

International Nuclear Information System (INIS)

Sholkovitz, E.R.; Mann, D.R.

1987-01-01

The distribution of sup(239,240)Pu between dissolved and particulate forms has been measured in four estuaries on the north-east coast of the United States (Connecticut River, Delaware Bay, Chesapeake Bay, and Mullica River). The data cover the whole salinity range from freshwater input to shelf waters at 3.5% and includes one profile from a nearly anoxic basin in the Chesapeake Bay. In the organic-rich Mullica River estuary, large-scale removal of riverine dissolved sup(239,240)Pu occurs at low salinities due to salt-induced coagulation, a mechanism analogous to that for iron and humic acids. Within the 0 to 2.5-3.5% zone in the other three estuaries, the activity of dissolved sup(239,240)Pu increases almost conservatively. The activities of particulate sup(239,240)Pu are highest in the more turbid waters of low salinity regime (0-1.5%), but become increasingly insignificant with respect to dissolved sup(239,240)Pu as salinities increase. At higher salinities corresponding to shelf water, there is a sharp increase in dissolved sup(239,240)Pu activity. The dissolved sup(239,240)Pu activity within each estuary appears to be inversely related to the flushing time of water. The sharp decrease in dissolved sup(239,240)Pu activities between shelf and estuarine waters appears to be driven by removal within the estuaries themselves rather than on the shelf. Dissolved sup(239,240)Pu activities are lower in the nearly-anoxic bottom waters of Chesapeake Bay indicating enhanced removal by redox transformation of Pu [i.e., Pu(V) to Pu(IV)]. (author)

Removal of diethyl phthalate from water solution by adsorption, photo-oxidation, ozonation and advanced oxidation process (UV/H{sub 2}O{sub 2}, O{sub 3}/H{sub 2}O{sub 2} and O{sub 3}/activated carbon)

Energy Technology Data Exchange (ETDEWEB)

Medellin-Castillo, Nahum A. [Centro de Investigacion y Estudios de Posgrado, Facultad de Ingenieria, Universidad Autonoma de San Luis Potosi, Av. Dr. M. Nava No.6, San Luis de Potosi, 78290 (Mexico); Ocampo-Perez, Raul [Centro de Investigacion y Estudios de Posgrado, Facultad de Ciencias Quimicas, Universidad Autonoma de San Luis Potosi, San Luis Potosi, 78290 (Mexico); Departamento de Quimica Inorganica, Facultad de Ciencias, Universidad de Granada, 18071, Granada (Spain); Leyva-Ramos, Roberto [Centro de Investigacion y Estudios de Posgrado, Facultad de Ciencias Quimicas, Universidad Autonoma de San Luis Potosi, San Luis Potosi, 78290 (Mexico); Sanchez-Polo, Manuel [Departamento de Quimica Inorganica, Facultad de Ciencias, Universidad de Granada, 18071, Granada (Spain); Rivera-Utrilla, Jose, E-mail: jrivera@ugr.es [Departamento de Quimica Inorganica, Facultad de Ciencias, Universidad de Granada, 18071, Granada (Spain); Mendez-Diaz, Jose D. [Departamento de Quimica Inorganica, Facultad de Ciencias, Universidad de Granada, 18071, Granada (Spain)

2013-01-01

The objective of this work was to compare the effectiveness of conventional technologies (adsorption on activated carbon, AC, and ozonation) and technologies based on advanced oxidation processes, AOPs, (UV/H{sub 2}O{sub 2}, O{sub 3}/AC, O{sub 3}/H{sub 2}O{sub 2}) to remove phthalates from aqueous solution (ultrapure water, surface water and wastewater). Diethyl phthalate (DEP) was chosen as a model pollutant because of its high water solubility (1080 mg/L at 293 K) and toxicity. The activated carbons showed a high adsorption capacity to adsorb DEP in aqueous solution (up to 858 mg/g), besides the adsorption mechanism of DEP on activated carbon is governed by dispersive interactions between {pi} electrons of its aromatic ring with {pi} electrons of the carbon graphene planes. The photodegration process showed that the pH solution does not significantly affect the degradation kinetics of DEP and the first-order kinetic model satisfactorily fitted the experimental data. It was observed that the rate of decomposition of DEP with the O{sub 3}/H{sub 2}O{sub 2} and O{sub 3}/AC systems is faster than that with only O{sub 3}. The technologies based on AOPs (UV/H{sub 2}O{sub 2}, O{sub 3}/H{sub 2}O{sub 2}, O{sub 3}/AC) significantly improve the degradation of DEP compared to conventional technologies (O{sub 3}, UV). AC adsorption, UV/H{sub 2}O{sub 2}, O{sub 3}/H{sub 2}O{sub 2}, and O{sub 3}/AC showed a high yield to remove DEP; however, the disadvantage of AC adsorption is its much longer time to reach maximum removal. The best system to treat water (ultrapure and natural) polluted with DEP is the O{sub 3}/AC one since it achieved the highest DEP degradation and TOC removal, as well as the lower water toxicity. -- Highlights: Black-Right-Pointing-Pointer Activated carbons showed a high adsorption capacity (up to 858 mg/g) to remove DEP. Black-Right-Pointing-Pointer The pH solution did not significantly affect the photodegradation kinetics of DEP. Black

The effect of the earth's rotation on ground water motion.

Science.gov (United States)

Loáiciga, Hugo A

2007-01-01

The average pore velocity of ground water according to Darcy's law is a function of the fluid pressure gradient and the gravitational force (per unit volume of ground water) and of aquifer properties. There is also an acceleration exerted on ground water that arises from the Earth's rotation. The magnitude and direction of this rotation-induced force are determined in exact mathematical form in this article. It is calculated that the gravitational force is at least 300 times larger than the largest rotation-induced force anywhere on Earth, the latter force being maximal along the equator and approximately equal to 34 N/m(3) there. This compares with a gravitational force of approximately 10(4) N/m(3).

Assessing interactions of hydrophilic nanoscale TiO{sub 2} with soil water

Energy Technology Data Exchange (ETDEWEB)

Priester, John H.; Ge, Yuan; Chang, Vivian [University of California, Santa Barbara, Bren School of Environmental Science and Management (United States); Stoimenov, Peter K. [University of California, Santa Barbara, Department of Chemistry and Biochemistry (United States); Schimel, Joshua P. [University of California, Santa Barbara, Earth Research Institute (United States); Stucky, Galen D. [University of California, Santa Barbara, UC Center for the Environmental Implications of Nanotechnology (United States); Holden, Patricia A., E-mail: holden@bren.ucsb.edu [University of California, Santa Barbara, Bren School of Environmental Science and Management (United States)

2013-09-15

The implications of manufactured nanoscale materials (MNMs) in unsaturated soil are mostly unknown. Owing to its widespread use, nanoscale (n) TiO{sub 2} is expected to enter soils where its accumulation could impact soil processes. Yet fundamental information is lacking regarding nTiO{sub 2} in situ wettability, i.e., interactions with soil water that relate to nTiO{sub 2} exposure and bioavailability. To probe nTiO{sub 2} interactions with soil water, we amended a natural soil with 20 mg per g of P25 nTiO{sub 2}, a high-production, hydrophilic MNM that, based on its small size (25 nm nominal), provides ample specific surface area (SSA) for water sorption. We then measured nTiO{sub 2}-amended soil SSA, and conducted a dynamic water vapor conditioning experiment. Early time-course water sorption into soil, with and without nTiO{sub 2}, was clearly diffusional. Over 9 months, soil water content asymptotically equilibrated. However, despite amending with nTiO{sub 2} levels that increased the soil SSA by 16 %, measured water sorption rates and endpoint soil water contents were mostly unchanged by P25 nTiO{sub 2}. Our results indicate that as-manufactured hydrophilic P25 nTiO{sub 2} was hydrophobic in soil, a finding relevant to nTiO{sub 2} bioavailability and transport.

Strong copper(II) species in estuarine and sea waters investigated by a method with high detection window.

Science.gov (United States)

Alberti, Giancarla; Biesuz, Raffaela; D'Agostino, Girolamo; Scarponi, Giuseppe; Pesavento, Maria

2007-02-15

The distribution of copper(II) in species of different stability in some estuarine and sea water samples (Adriatic Sea) was investigated by a method based on the sorption of the metal ion on a strongly sorbing resin, Chelex 100, whose sorbing properties have been previously characterized. From them, it is possible to predict very high values of detection windows at the considered conditions, for example side reaction coefficient as high as 10(10) at pH 7.5. Strong copper(II) species in equilibrium with Chelex 100 were detected, at concentration 2-20nM, with a reaction coefficient approximately 10(10.6) at pH 7.45 in sea water, strictly depending on the acidity. They represent 50-70% of the total metal ion and are the strongest copper(II) complexes found in sea water. Weak complexes too were detected in all the samples, with reaction coefficient lower than ca. 10(9) at the same pH. The method applied, named resin titration (RT), was described in a previous investigation, and is here modified in order to be carried out on oceanographic boat during a cruise in the Adriatic Sea.

Programmatic Environmental Impact Statement for the Uranium Mill Tailings Remedial Action Ground Water Project

International Nuclear Information System (INIS)

1993-09-01

Public concern regarding the potential human health and environmental effects from uranium mill tailings led Congress to pass the Uranium Mill Tailings Radiation Control Act (UMTRCA) (Public Law 95-604) in 1978. In the UMTRCA, Congress acknowledged the potentially harmful health effects associated with uranium mill tailings at 24 abandoned uranium mill processing sites needing remedial action. Uranium processing activities at most of the 24 mill processing sites resulted in the formation of contaminated ground water beneath and, in some cases, downgradient of the sites. This contaminated ground water often has elevated levels of hazardous constituents such as uranium and nitrate. The purpose of the Ground Water Project is to protect human health and the environment by meeting EPA-proposed standards in areas where ground water has been contaminated with constituents from UMTRA Project sites. A major first step in the UMTRA Ground Water Project is the preparation of this Programmatic Environmental Impact Statement (PEIS). This document analyzes potential impacts of the alternatives, including the proposed action. These alternatives are programmatic in that they are plans for conducting the UMTRA Ground Water Project. The alternatives do not address site-specific ground water compliance. This PEIS is a planning document that will provide a framework for conducting the Ground Water Project; assess the potential programmatic and environmental impacts of conducting the UMTRA Ground Water Project; provide a method for determining the site-specific ground water compliance strategies; and provide data and information that can be used to prepare site-specific environmental impacts analyses documents more efficiently

Application of isotopic techniques for study of ground water from karstic areas. 1. Origin of waters

International Nuclear Information System (INIS)

Feurdean, Victor; Feurdean, Lucia

2000-01-01

Environmental stable isotope method was used for study of ground water from karst of NE Dobrogea. Study area is in the vicinity of Danube Delta (declared in 1990 by UNESCO the Reserve of Biosphere) and presents scientific and ecological interest. Measurements of deuterium content of ground water show that waters are meteoric in origin, but at the same time the results showed that the water from two sampling points could not originate from local ground water and have their recharge area at high altitude and a considerable distance. According to the δD values the following categories of waters were established: - waters depleted in deuterium (δD 0 / 00 ) relative to δD values of surface and ground water in the geographic area from which they were collected. They represent most probably the intrusion of isotopically light water from high altitude sites (higher than 1000 m) through network of highly permeable karst channels. The discharge of this component of aquifer occurs both by conduct flow and by diffuse flow; - Waters tributaries to the Danube River (δD > -75 0 / 00 ) that have a small time variability of δD values; - Local infiltration waters, situated in the West side of the investigated area towards the continental platform of the Dobrogea (δD > -70 0 / 00 ). They present high time variability of δD values, due to distinct seasonal effects; - Waters originated in mixing processes between the waters with different isotopic content. The endmember one is heavier isotopic water that belongs to local recharged waters (local infiltration waters and waters tributary to Danube river) while the other endmember is the isotopically light water. (authors)

Liquid microjet - a new tool for environmental water quality monitoring?

International Nuclear Information System (INIS)

Holstein, W.; Buntine, M.

2001-01-01

Our ability to provide real-time, cost-effective and efficient technologies for water quality monitoring remains a critical global environmental research issue. Each year, ground and surface waterways around the world, the global marine environment and the especially-fragile interzonal estuarine ecosystems are being placed under severe stress due to ever-increasing levels of pollutants entering the earth's aquasphere. An almost revolutionary breakthrough in water quality monitoring would be achieved with the development of a real-time, broad-spectrum chemical analysis technology. In this article, a real-time mass spectrometric based water quality monitoring centre around in vacuo liquid microjet injection methodologies is presented

Dynamic estuarine plumes and fronts: importance to small fish and plankton in coastal waters of NSW, Australia

Science.gov (United States)

Kingsford, M. J.; Suthers, I. M.

1994-05-01

In 1990, low density estuarine plumes in the vicinity of Botany Bay, Australia, extended up to 11 km across a narrow continental shelf ( ca 25 km) on ebb tides. The shape and seaward extent of plumes varied according to a combination of state of the tide, freshwater input and the direction and intensity of coastal currents. Offshore plumes dissipated on the flood tide and fronts reformed at the entrance of Botany Bay. Major differences in the abundance and composition of ichthyoplankton and other zooplankton were found over a 400-800 m stretch of water encompassing waters of the plume, front and ocean on seven occasions. For example, highest abundances of the fishes Gobiidae, Sillaginidae, Gerreidae and Sparidae as well as barnacle larvae and fish eggs were found in plumes. Cross-shelf distribution patterns of zooplankton, therefore, are influenced by plumes. Distinct assemblages of plankters accumulated in fronts, e.g. fishes of the Mugilidae and Gonorynchidae and other zooplankters (e.g. Jaxea sp.). Accumulation in fronts was variable and may relate to variable convergence according to the tide. We argue that plumes provide a significant cue to larvae in coastal waters that an estuary is nearby. Moreover, although many larvae may be retained in the turbid waters of plumes associated with riverine input, larvae are potentially exported in surface waters on ebb tides.

Tributyltin-resistant bacteria from estuarine and freshwater sediments.

OpenAIRE

Wuertz, S; Miller, C E; Pfister, R M; Cooney, J J

1991-01-01

Resistance to tributyltin (TBT) was examined in populations from TBT-polluted sediments and nonpolluted sediments from an estuary and from fresh water as well as in pure cultures isolated from those sediments. The 50% effective concentrations (EC50s) for populations were higher at a TBT-polluted freshwater site than at a site without TBT, suggesting that TBT selected for a TBT-resistant population. In contrast, EC50s were significantly lower for populations from a TBT-contaminated estuarine s...

Hanford Ground-Water Data Base management guide

International Nuclear Information System (INIS)

Rieger, J.T.; Mitchell, P.J.; Muffett, D.M.; Fruland, R.M.; Moore, S.B.; Marshall, S.M.

1990-02-01

This guide describes the Hanford Ground-Water Data Base (HGWDB), a computerized data base used to store hydraulic head, sample analytical, temperature, geologic, and well-structure information for ground-water monitoring wells on the Hanford Site. These data are stored for the purpose of data retrieval for report generation and also for historical purposes. This guide is intended as an aid to the data base manager and the various staff authorized to enter and verify data, maintain the data base, and maintain the supporting software. This guide focuses on the structure of the HGWDB, providing a fairly detailed description of the programs, files, and parameters. Data-retrieval instructions for the general user of the HGWDB will be found in the HGWDB User's Manual. 6 figs

A source of ground water 222Rn around Tachikawa fault

International Nuclear Information System (INIS)

Saito, Masaaki; Takata, Sigeru

1994-01-01

Radon ( 222 Rn) concentration in ground water was characteristically high on the south-western zone divided by the Tachikawa fault, Tokyo. (1) The concentration did not increase with depth, and alluvium is thick on the zone. The source of radon was not considered as the updraft from base rock through the fault. Comparing the south-western zone with its surrounding zone, the followings were found. (2) The distribution of tritium concentration was supported that water had easily permeated into ground on the zone. (3) As the zone is located beside the Tama River and its alluvial fan center, the river water had likely affected. The source of radon on the zone would be 226 Ra in the aquifer soil. It can be presumed that the water of the Tama River had permeated into ground on the zone and had accumulated 226 Ra. (author)

Annotated bibliography on artificial recharge of ground water, 1955-67

Science.gov (United States)

Signor, Donald C.; Growitz, Douglas J.; Kam, William

1970-01-01

Artificial ground-water recharge has become more important as water use by agriculture, industry, and municipalities increases. Water management agencies are increasingly interested in potential use of recharge for pollution abatement, waste-water disposal, and re-use and reclamation of locally available supplies. Research projects and theoretical analyses of operational recharge systems show increased scientific emphasis on the practice. Overall ground-water basin management systems generally now contain considerations of artificial recharge, whether by direct or indirect methods. Artificial ground-water recharge is a means of conserving surface runoff for future use in places where it would otherwise be lost, of protecting ground-water basins from salt-water encroachment along coastal areas, and of storing and distributing imported water. The biblio-graphy emphasizes technology; however, annotations of articles on waste-water reclamation, ground-water management and ground-water basin management are included. Subjects closely related to artificial recharge, including colloidal flow through porous media, field or laboratory instrumentation, and waste disposal by deep well injection are included where they specifically relate to potential recharge problems. Where almost the same material has been published in several journals, all references are included on the assumption that some publications may be more readily available to interested persons than others. Other publications, especially those of foreign literature, provided abstracts that were used freely as time limitations precluded obtaining and annotating all materials. Abstracts taken from published sources are noted. These are: "Abstracts of North American Geology," U.S. Department of the Interior, Geological Survey; "Abstracts of Recent Published Material on Foil and Water Conservation," ARS-41 series, Agricultural F.esearch Service, U.S. Department of Agriculture; "Water and1 Water

Occurrence of estrogenic activities in second-grade surface water and ground water in the Yangtze River Delta, China

International Nuclear Information System (INIS)

Shi, Wei; Hu, Guanjiu; Chen, Sulan; Wei, Si; Cai, Xi; Chen, Bo; Feng, Jianfang; Hu, Xinxin; Wang, Xinru; Yu, Hongxia

2013-01-01

Second-grade surface water and ground water are considered as the commonly used cleanest water in the Yangtze River Delta, which supplies centralized drinking water and contains rare species. However, some synthetic chemicals with estrogenic disrupting activities are detectable. Estrogenic activities in the second-grade surface water and ground water were surveyed by a green monkey kidney fibroblast (CV-1) cell line based ER reporter gene assay. Qualitative and quantitative analysis were further conducted to identify the responsible compounds. Estrogen receptor (ER) agonist activities were present in 7 out of 16 surface water and all the ground water samples. Huaihe River and Yangtze River posed the highest toxicity potential. The highest equivalent (2.2 ng E 2 /L) is higher than the predicted no-effect-concentration (PNEC). Bisphenol A (BPA) contributes to greater than 50% of the total derived equivalents in surface water, and the risk potential in this region deserves more attention and further research. -- Highlights: •Estrogenic activities were present in second-grade surface water and ground water. •Most of the detected equivalents were higher than the predicted no-effect-concentration of E 2 . •ER-EQ 20–80 ranges showed that samples in Huaihe River and Yangtze River posed the highest toxicity. •Bisphenol A contributes to most of the instrumentally derived equivalents in surface water. -- Estrogenic activities were observed in second-grade surface water and ground water in Yangtze River Delta, and BPA was the responsible contaminant

Surface-water, water-quality, and ground-water assessment of the Municipio of Carolina, Puerto Rico, 1997-99

Science.gov (United States)

Rodríguez-Martínez, Jesús; Gómez-Gómez, Fernando; Santiago-Rivera, Luis; Oliveras-Feliciano, M. L.

2001-01-01

To meet the increasing need for a safe and adequate supply of water in the municipio of Carolina, an integrated surface-water, water-quality, and ground-water assessment of the area was conducted. The major results of this study and other important hydrologic and water-quality features were compiled in a Geographic Information System and are presented in two 1:30,000-scale map plates to facilitate interpretation and use of the diverse water-resources data. Because the supply of safe drinking water was a critical issue during recent dry periods, the surface-water assessment portion of this study focused on analysis of low-flow characteristics in local streams and rivers. Low-flow characteristics were evaluated for one continuous-record gaging station, based on graphical curve-fitting techniques and log-Pearson Type III frequency analysis. Estimates of low-flow characteristics for seven partial-record stations were generated using graphical-correlation techniques. Flow-duration characteristics were computed for the one continuous-record gaging station and were estimated for the partial-record stations using the relation curves developed from the low-flow study. Stream low-flow statistics document the general hydrology under current land and water use. Low-flow statistics may substantially change as a result of streamflow diversions for public supply, and an increase in ground-water development, waste-water discharges, and flood-control measures; the current analysis provides baseline information to evaluate these impacts and develop water budgets. A sanitary quality survey of streams utilized 29 sampling stations to evaluate the sanitary quality of about 87 miles of stream channels. River and stream samples were collected on two occasions during base-flow conditions and were analyzed for fecal coliform and fecal streptococcus. Bacteriological analyses indicate that a significant portion of the stream reaches within the municipio of Carolina may have fecal coliform

Spatial distribution and shell utilization in three sympatric hermit crabs at non-consolidated sublittoral of estuarine-bay complex in São Vicente, São Paulo, Brazil

OpenAIRE

Sant'Anna, Bruno S. [UNESP; Zangrande, Cilene M. [UNESP; Reigada, Álvaro L.D. [UNESP; Severino-Rodrigues, Evandro

2006-01-01

The objective of the present study was to characterize the spatial distribution and shell utilization of three hermit crab species in the estuarine-bay complex of São Vicente, São Paulo State, Brazil. Monthly samples were done throughout two years, in the non-consolidated sub-littoral at the estuarine-bay complex. The environmental factors, such as temperature, salinity and depth, were measured every month. The three hermit crab species, Clibanarius vittatus, Loxopagurus loxochelis and Isoche...

Ground cover influence on evaporation and stable water isotopes in soil water

Science.gov (United States)

Magdalena Warter, Maria; Jiménez-Rodríguez, Cesar D.; Coenders-Gerrits, Miriam; Teuling, Adriaan J. Ryan

2017-04-01

Forest ecosystems are characterized by complex structures which influence hydrological processes such as evaporation. The vertical stratification of the forest modifies the effect of the evaporation process due to the composition and local distribution of species within the forest. The evaluation of it will improve the understanding of evaporation in forest ecosystems. To determine the influence of forest understory on the fractionation front, four ground cover types were selected from the Speulderbos forest in the Netherlands. The native species of Thamariskmoss (Thuidium thamariscinum), Rough Stalked Feathermoss (Brachythecium rutabulum), and Haircapmoss (Polytrichum commune) as well as one type of litter made up of Douglas-Fir needles (Pseudotsuga menziesii) were used to analyse the rate of evaporation and changes on the isotopic concentration of the soil water on an in-situ basis in a controlled environment. Over a period of 4 weeks soil water content and atmospheric conditions were continuously measured, while the rainfall simulations were performed with different amounts and timings. The reference water added to the boxes keeps a stable composition along the trial period with a δ ^2H value of -42.59±1.15 \\permil} and δ 18O of -6.01±0.21 \\permil}. The evaporation front in the four ground covers is located between 5 and 10 cm depth and deuterium excess values are bigger than 5 \\permil. The litter layer of Douglas-Fir needles is the cover with higher fractionation in respect to the added water at 10 cm depth (δ ^2H: -29.79 \\permil), while the Haircapmoss keeps the lower fractionation rate at 5 cm and 10 cm (δ ^2H: -33.62 and δ ^2H: -35.34 \\permil). The differences showed by the soil water beneath the different ground covers depict the influence of ground cover on fractionation rates of the soil water, underlining the importance of the spatial heterogeneity of the evaporation front in the first 15 cm of soil.

Polyfluorinated chemicals in European surface waters, ground- and drinking waters

NARCIS (Netherlands)

Eschauzier, C.; de Voogt, P.; Brauch, H.-J.; Lange, F.T.; Knepper, T.P.; Lange, F.T.

2012-01-01

Polyfluorinated chemicals (PFCs), especially short chain fluorinated alkyl sulfonates and carboxylates, are ubiquitously found in the environment. This chapter aims at giving an overview of PFC concentrations found in European surface, ground- and drinking waters and their behavior during

Experimental and theoretical investigations on the inhibition of mild steel corrosion in the ground water medium using newly synthesised bipodal and tripodal imidazole derivatives

Energy Technology Data Exchange (ETDEWEB)

Gopi, D., E-mail: dhanaraj_gopi@yahoo.com [Department of Chemistry, Periyar University, Salem 636 011, Tamilnadu (India); Centre for Nanoscience and Nanotechnology, Periyar University, Salem 636 011, Tamilnadu (India); Sherif, El-Sayed M. [Center of Excellence for Research in Engineering Materials (CEREM), Advanced Manufacturing Institute, King Saud University, P.O. Box 800, Al-Riyadh 11421 (Saudi Arabia); Electrochemistry and Corrosion Laboratory, Department of Physical Chemistry, National Research Centre (NRC), Dokki, 12622 Cairo (Egypt); Surendiran, M. [Department of Chemistry, Periyar University, Salem 636 011, Tamilnadu (India); Jothi, M.; Kumaradhas, P. [Department of Physics, Periyar University, Salem 636 011, Tamilnadu (India); Kavitha, L. [Department of Physics, School of Basic and Applied Sciences, Central University of Tamilnadu, Thiruvarur 610 101, Tamilnadu (India)

2014-10-15

Two new imidazole derivatives, namely 1,4-bis(N-imidazolylmethyl)-2-5-dimethoxybenzene (BIDM) and 1,3,5-tris(N-imidazolylmethyl)-2,4,6-trimethoxybenzene (TITM), were synthesised and their effects on the inhibition of mild steel corrosion in ground water medium are reported. The study was carried out using gravimetric and electrochemical techniques in order to determine the corrosion inhibition efficiencies of the bipodal and tripodal structured imidazoles. Further, the quantum chemical calculations using density functional theory (DFT) gave a profound insight into the inhibitory action mechanism of BIDM and TITM and their calculation parameters, such as E{sub HOMO}, E{sub LUMO} and ΔE were in good agreement with the results of the experimental studies. BIDM and TITM exhibited lowest corrosion current densities of circa 7.5 μA cm{sup −2} and 4.1 μAcm{sup −2} at the optimum concentrations of 0.67 and 0.49 mM, respectively. All measurements thus confirmed that both BIDM and TITM behaved as good inhibitors for mild steel corrosion in ground water medium. - Highlights: • Synthesis of new imidazole derivatives-BIDM(bipodal) and TITM(tripodal) inhibitors. • Gravimetric analysis to investigate mild steel corrosion inhibition in ground water. • Electrochemical characterizations to substantiate results of weight loss method. • Quantum studies to analyse the chemical behavior, structure and substituent effect.

Questa baseline and pre-mining ground-water quality investigation. 14. Interpretation of ground-water geochemistry in catchments other than the Straight Creek catchment, Red River Valley, Taos County, New Mexico, 2002-2003

Science.gov (United States)

Nordstrom, D. Kirk; McCleskey, R. Blaine; Hunt, Andrew G.; Naus, Cheryl A.

2005-01-01

The U.S. Geological Survey, in cooperation with the New Mexico Environment Department, is investigating the pre-mining ground-water chemistry at the Molycorp molybdenum mine in the Red River Valley, New Mexico. The primary approach is to determine the processes controlling ground-water chemistry at an unmined, off-site but proximal analog. The Straight Creek catchment, chosen for this purpose, consists of the same Tertiary-age quartz-sericite-pyrite altered andesite and rhyolitic volcanics as the mine site. Straight Creek is about 5 kilometers east of the eastern boundary of the mine site. Both Straight Creek and the mine site are at approximately the same altitude, face south, and have the same climatic conditions. Thirteen wells in the proximal analog drainage catchment were sampled for ground-water chemistry. Eleven wells were installed for this study and two existing wells at the Advanced Waste-Water Treatment (AWWT) facility were included in this study. Eight wells were sampled outside the Straight Creek catchment: one each in the Hansen, Hottentot, and La Bobita debris fans, four in a well cluster in upper Capulin Canyon (three in alluvial deposits and one in bedrock), and an existing well at the U.S. Forest Service Questa Ranger Station in Red River alluvial deposits. Two surface waters from the Hansen Creek catchment and two from the Hottentot drainage catchment also were sampled for comparison to ground-water compositions. In this report, these samples are evaluated to determine if the geochemical interpretations from the Straight Creek ground-water geochemistry could be extended to other ground waters in the Red River Valley , including the mine site. Total-recoverable major cations and trace metals and dissolved major cations, selected trace metals, anions, alkalinity; and iron-redox species were determined for all surface- and ground-water samples. Rare-earth elements and low-level As, Bi, Mo, Rb, Re, Sb, Se, Te, Th, U, Tl, V, W, Y, and Zr were

Ground-water models: Validate or invalidate

Science.gov (United States)

Bredehoeft, J.D.; Konikow, Leonard F.

1993-01-01

The word validation has a clear meaning to both the scientific community and the general public. Within the scientific community the validation of scientific theory has been the subject of philosophical debate. The philosopher of science, Karl Popper, argued that scientific theory cannot be validated, only invalidated. Popper’s view is not the only opinion in this debate; however, many scientists today agree with Popper (including the authors). To the general public, proclaiming that a ground-water model is validated carries with it an aura of correctness that we do not believe many of us who model would claim. We can place all the caveats we wish, but the public has its own understanding of what the word implies. Using the word valid with respect to models misleads the public; verification carries with it similar connotations as far as the public is concerned. Our point is this: using the terms validation and verification are misleading, at best. These terms should be abandoned by the ground-water community.

Effects Disposal Condition and Ground Water to Leaching Rate of Radionuclides from Solidification Products

International Nuclear Information System (INIS)

Herlan Martono; Wati

2008-01-01

Effects disposal condition and ground water to leaching rate of radionuclides from solidification products have been studied. The aims of leaching test at laboratory to get the best composition of solidified products for continuous process or handling. The leaching rate of radionuclides from the many kinds of matrix from smallest to bigger are glass, thermosetting plastic, urea formaldehyde, asphalt, and cement. Glass for solidification of high level waste, thermosetting plastic and urea formaldehyde for solidification of low and intermediate waste, asphalt and cement for solidification of low and intermediate level waste. In shallow land burial, ground water rate is fast, debit is high, and high permeability, so the probability contact between solidification products and ground water is occur. The pH of ground water increasing leaching rate, but cation in the ground water retard leaching rate. Effects temperature radiation and radiolysis to solidification products is not occur. In the deep repository, ground water rate is slow, debit is small, and low permeability, so the probability contact between solidification products and ground water is very small. There are effect cooling time and distance between pits to rock temperature. Alfa radiation effects can be occur, but there is no contact between solidification products and ground water, so that there is not radiolysis. (author)

Combined ion exchange / biological denitrification for nitrate removal from ground water

NARCIS (Netherlands)

Hoek, van der J.P.

1988-01-01

This thesis deals with the development of a new process for nitrate removal from ground water. High nitrate concentrations in ground water are a result of fertilization in agriculture. According to a directive of the European Community the maximum admissible concentration of nitrate in

Hydrologic influence on redox dynamics in estuarine environments

Science.gov (United States)

Michael, H. A.; Kim, K. H.; Guimond, J. A.; Heiss, J.; Ullman, W. J.; Seyfferth, A.

2017-12-01

Redox conditions in coastal aquifers control reactions that impact nutrient cycling, contaminant release, and carbon budgets, with implications for water resources and ecosystem health. Hydrologic changes can shift redox boundaries and inputs of reactants, especially in dynamic coastal systems subject to fluctuations on tidal, lunar, and longer timescales. We present two examples of redox shifts in estuarine systems in Delaware, USA: a beach aquifer and a saltmarsh. Beach aquifers are biogeochemical hot spots due to mixing between fresh groundwater and infiltrating seawater. At Cape Henlopen, DE, geochemical measurements identified reactions in the intertidal aquifer that include cycling of carbon, nitrogen, iron, and sulfur. Measurements and modeling illustrate that redox potential as well as the locations of redox reactions shift on tidal to seasonal timescales and in response to changing beach and aquifer properties, impacting overall rates of reactions such as denitrification that reduces N loads to coastal waters. In the St. Jones National Estuarine Research Reserve, tidal fluctuations in channels cause periodic groundwater-surface water exchange, water table movement, and intermittent flooding that varies spatially across the saltmarsh. These changes create shifts in redox potential that are greatest near channels and in the top 20 cm of sediments. The magnitude of redox change depends on hydrologic setting (near channels or in marsh interior), hydrologic conditions (tidal stage, seasonal shifts), as well as prevalence of macropores created by crab burrows that change seasonally with crab activity. These shifts correspond to changes in porewater chemistry that have implications for nutrient cycling and carbon export to the ocean. Understanding hydrologic influence on redox geochemistry is critical for predicting how these systems and their ecosystem services may change in the future in response to anthropogenic and climate change.

Ground-water quality and geochemistry, Carson Desert, western Nevada

Science.gov (United States)

Lico, Michael S.; Seiler, R.L.

1994-01-01

Aquifers in the Carson Desert are the primary source of drinking water, which is highly variable in chemical composition. In the shallow basin-fill aquifers, water chemistyr varies from a dilute calcium bicarbonate-dominated water beneath the irrigated areas to a saline sodium chloride- dominated water beneath unirrigated areas. Water samples from the shallow aquifers commonly have dissolved solids, chloride, magnesium, sulfate, arsenic, and manganese concentrations that exceed State of Nevada drinking-water standards. Water in the intermediante basin-fill aquifers is a dilute sodium bicarbonate type in the Fallon area and a distinctly more saline sodium chloride type in the Soda Lake-Upsal Hogback area. Dissolved solids, chloride, arsenic, fluoride, and manganese concen- trations commonly exceed drinking-water standards. The basalt aquifer contains a dilute sodium bicarbonate chloride water. Arsenic concentrations exceed standards in all sampled wells. The concen- trations of major constituents in ground water beneath the southern Carson Desert are the result of evapotranspiration and natural geochemical reactions with minerals derived mostly from igneous rocks. Water with higher concentrations of iron and manganese is near thermodynamic equilibrium with siderite and rhodochrosite and indicates that these elements may be limited by the solubility of their respective carbonate minerals. Naturally occurring radionuclides (uranium and radon-222) are present in ground water from the Carson Desert in concen- tratons higher than proposed drinking-water standards. High uranium concentrations in the shallow aquifers may be caused by evaporative concentration and the release of uranium during dissolution of iron and manganese oxides or the oxidation of sedimentary organic matter that typically has elevated uranium concentrations. Ground water in the Carson Desert does not appear to have be contaminated by synthetic organic chemicals.

Sixth national outdoor action conference on aquifer restoration, ground water monitoring and geophysical methods

International Nuclear Information System (INIS)

Anon.

1992-01-01

The 1992 Outdoor Action Conference was comprised of three days of technical presentations, workshops, demonstrations, and an exhibition. The sessions were devoted to the following topics: Vadose Zone Monitoring Technology; Ground Water Monitoring Technology; Ground Water Sampling Technology; Soil and Ground Water Remediation; and Surface and Borehole Geophysics. The meeting was sponsored by the National Ground Water Association. These papers were published exactly as submitted, without technical and grammatical editing or peer review

Tunable surface wettability and water adhesion of Sb{sub 2}S{sub 3} micro-/nanorod films

Energy Technology Data Exchange (ETDEWEB)

Zhong, Xin; Zhao, Huiping [Key Laboratory for Green Chemical Process of Ministry of Education and Hubei Novel Reactor and Green Chemical Technology Key Laboratory, Wuhan Institute of Technology, Xiongchu Street, Wuhan 430073 (China); Yang, Hao, E-mail: hyangwit@hotmail.com [Key Laboratory for Green Chemical Process of Ministry of Education and Hubei Novel Reactor and Green Chemical Technology Key Laboratory, Wuhan Institute of Technology, Xiongchu Street, Wuhan 430073 (China); Liu, Yunling [State Key laboratory of Inorganic Synthesis and Preparative Chemistry, College of Chemistry, Jilin University, Changchun 130012 (China); Yan, Guoping [Key Laboratory for Green Chemical Process of Ministry of Education and Hubei Novel Reactor and Green Chemical Technology Key Laboratory, Wuhan Institute of Technology, Xiongchu Street, Wuhan 430073 (China); Chen, Rong, E-mail: rchenhku@hotmail.com [Key Laboratory for Green Chemical Process of Ministry of Education and Hubei Novel Reactor and Green Chemical Technology Key Laboratory, Wuhan Institute of Technology, Xiongchu Street, Wuhan 430073 (China)

2014-01-15

Antimony sulfide (Sb{sub 2}S{sub 3}) films were successfully prepared by spin coating Sb{sub 2}S{sub 3} micro-/nanorods with different sizes on glass slides, which was synthesized via a facile and rapid microwave irradiation method. The prepared Sb{sub 2}S{sub 3} micro-/nanorods and films were characterized by powder X-ray diffraction (XRD), scanning electron microscopy (SEM), atomic force microscopy (AFM) and water contact angle (CA). The as-prepared Sb{sub 2}S{sub 3} films exhibited different surface wettabilities ranging from superhydrophilicity to superhydrophobicity, which was strongly dependent on the diameter of Sb{sub 2}S{sub 3} micro-/nanorod. Sb{sub 2}S{sub 3} film made by nanorods possessed superhydrophobic surface and high water adhesive property. After surface modification with stearic acid, the superhydrophobic surface exhibited an excellent self-cleaning property owing to its low adhesive force. The clarification of three possible states including Wenzel's state, “Gecko” state and Cassie's state for Sb{sub 2}S{sub 3} film surfaces was also proposed to provide a better understanding of interesting surface phenomena on Sb{sub 2}S{sub 3} films.

The ground water chemical characteristics of Beishan area-the China's potential high level radioactive waste repository

International Nuclear Information System (INIS)

Yang Tianxiao; Guo Yonghai

2004-01-01

The ground water chemical characteristics have impact on nuclide migration in high level waste repository, so the study on the ground water chemical characteristics is an important aspect in site screening and characterization. The geochemical modeling of the reaction trend between ground water and solid phase, the water-rock interaction modeling of the formation and evolution of ground water chemistry, the modeling of the reaction between ground water and nuclear waste are all carried out in this paper to study the ground water chemical characteristics in Beishan area. The study illustrates that the ground water chemical characteristics in Beishan area is favorable to the disposal of high level nuclear waste and to prevent the nuclides migration. (author)

Thickness control in electrophoretic deposition of WO{sub 3} nanofiber thin films for solar water splitting

Energy Technology Data Exchange (ETDEWEB)

Fang, Yuanxing; Lee, Wei Cheat; Canciani, Giacomo E.; Draper, Thomas C.; Al-Bawi, Zainab F. [Department of Chemistry, School of Life Sciences, University of Sussex, Brighton BN1 9QJ (United Kingdom); Bedi, Jasbir S. [School of Public Health & Zoonoses, Guru Angad Dev Veterinary and Animal Sciences University, Ludhiana 141004 Punjab (India); Perry, Christopher C. [Division of Biochemistry, School of Medicine, Loma Linda University, Loma Linda, CA 92350 (United States); Chen, Qiao, E-mail: qiao.chen@sussex.ac.uk [Department of Chemistry, School of Life Sciences, University of Sussex, Brighton BN1 9QJ (United Kingdom)

2015-12-15

Graphical abstract: - Highlights: • A novel method combining electrospinning and electrophoretic deposition was established for the creation of nanostructured semiconductor thin films. • The created thin films displayed a high chemical stability with a controllable thickness. • The PEC water splitting performance of the thin films was optimized by fine-tuning the thickness of the films. • A maximum photoconversion efficiency was achieved by 18 μm nanofibrous thin films. - Abstract: Electrophoretic deposition (EPD) of ground electrospun WO{sub 3} nanofibers was applied to create photoanodes with controlled morphology for the application of photoelectrochemical (PEC) water splitting. The correlations between deposition parameters and film thicknesses were investigated with theoretical models to precisely control the morphology of the nanostructured porous thin film. The photoconversion efficiency was further optimized as a function of film thickness. A maximum photoconversion efficiency of 0.924% from electrospun WO{sub 3} nanofibers that EPD deposited on a substrate was achieved at a film thickness of 18 μm.

Draft programmatic environmental impact statement for the Uranium Mill Tailings Remedial Action Ground Water Project

International Nuclear Information System (INIS)

1995-04-01

The US Department of Energy (DOE) is responsible for performing remedial action to bring surface and ground water contaminant levels at 24 inactive uranium processing sites into compliance with the US Environmental Protection Agency (EPA) standards. DOE is accomplishing this through the Uranium Mill Tailings Remedial Action (UMTRA) Surface and Ground Water Projects. Remedial action will be conducted with the concurrence of the US Nuclear Regulatory Commission (NRC) and the full participation of affected states and Indian tribes. Uranium processing activities at most of 24 the inactive mill sites resulted in the contamination of ground water beneath and, in some cases, downgradient of the sites. This contaminated ground water often has elevated levels of constituents such as uranium and nitrate. The purpose of the UMTRA Ground Water Project is to eliminate, or reduce to acceptable levels, the potential health and the environmental consequences of milling activities by meeting the EPA standards in areas where ground water has been contaminated. The first step in the UMTRA Ground Water Project is the preparation of this programmatic environmental impact statement (PEIS). This document analyzes potential impacts of four programmatic alternatives, including the proposed action. The alternatives do not address site-specific ground water compliance strategies. Rather, the PEIS is a planning document that provides a framework for conducting the Ground Water Project; assesses the potential programmatic impacts of conducting the Ground Water Project; provides a method for determining the site-specific ground water compliance strategies; and provides data and information that can be used to prepare site-specific environmental impacts analyses more efficiently

Ground-Based Global Positioning System (GPS) Meteorology Integrated Precipitable Water Vapor (IPW)