The TPX Cryostat Conceptual Design

International Nuclear Information System (INIS)

Ravenscroft, D.; Posey, A.; Heitzenroeder, P.

1993-01-01

The TPX (Tokamak Physics Experiment) will be the first tokamak to employ both superconducting TF (toroidal field) and PF (poloidal field) magnets. Consequently, the entire device is located within an evacuated cryostat to provide the necessary thermal barrier between the ambient temperature test cell and the magnets that are cooled by supercritical liquid helium at 5 degrees K. This paper describes the cryostat design requirements, design concepts, and the cryostat fabrication and installation

Trial manufacture of liquid nitrogen cooling High Temperature Superconductivity Motor

International Nuclear Information System (INIS)

Sugimoto, H; Nishikawa, T; Tsuda, T; Hondou, Y; Akita, Y; Takeda, T; Okazaki, T; Ohashi, S; Yoshida, Y

2006-01-01

We present a new high temperature superconductivity (HTS) synchronous motor using the liquid nitrogen as the refrigerant in this paper. This motor is designed to be used as the propulsion motor in ship. Because we use the liquid nitrogen as the refrigerant, it is possible to simplify the cooling equipments in the motor. And in our design, we apply the axial flux type of motor to simplify the cryostat of the HTS wires used to make the field coils. Here, the fields using the bismuth HTS wire for the HTS coils are fixed. Moreover, the cores used in the fields are separated from cryostat, and the armature applies the core-less structure. According to various the electromagnetic field analysis results, the new motor was designed and produced. The diameter of the motor is 650mm, and the width of the motor is 360mm. The motor's rated output is 8.8kW at 100rpm, while the overload output is 44kW, and the maximum efficiency is 97.7%. Also, in order to further miniaturize the motor, other magnetic field analysis have been done when the high-current-density type HTS wire was used and the permendur was used instead of magnetic steel plates. In this case, the motor's rated output is 12kW, and the overload output is 60kW

Cryostat for TRISTAN superconducting cavity

International Nuclear Information System (INIS)

Mitsunobu, S.; Furuya, T.; Hara, K.

1990-01-01

Superconducting cavities generate rather high heat load of hundreds watts in one cryostat and have high sensitivity for pressure. We adopted usual pool-boiling type cooling for its stable pressure operation. Two 5-cell Nb cavities were installed in one flange type cryostat. Tuning mechanics actuated by a pulse-motor and a Piezo-electric element are set at outside of vacuum end flange. The design and performance of the cryostat for TRISTAN superconducting cavities are described. (author)

The First End-Cap Cryostat is being Tested at Cold

CERN Multimedia

Aleksa, M

The integration of the LAr end-cap detector wheels - one electromagnetic calorimeter wheel and two hadronic calorimeter wheels - was finished at the end of 2003 (see Fig. 1). Fig. 1: ECC cryostat after the insertion of the second hadronic end-cap wheel (Dec. 2003), and before the insertion of the forward calorimeter. After the insertion of the forward calorimeter, in summer 2004, the cryostat was closed and welded. Cool-down of the End-Cap C Cryostat: On Nov. 26, 2004, the cool-down of the cryostat started in B180 using forced convection of gaseous N2 in the heat exchangers and He gas in the cryostat (see Fig. 2). The cool-down speed during this time was on average 0.2K/h, hence arriving at a temperature of approximately 120K after about 6 weeks. The speed of the cool down was limited by stringent requirements on the temperature gradients in the detector wheels, which were established from mechanical constraints. The most severe limit was the maximum allowed temperature difference of 6K for the el...

Development of a cryostat for physics research

International Nuclear Information System (INIS)

Wang Futang

1995-01-01

The paper describes the structure and performances of a cryostat for physics research on hybrid magnet or water-cooled magnet. The cryostat can provide a wide temperature range from 1 K to room temperature. The temperature stability (above 4.2 K) is very convenient for replacing samples

Cryostat for superconducting radio-frequency cavity program at VECC Kolkata

International Nuclear Information System (INIS)

Mishra, S.K.; Bajirao, S.; Bhattacharya, S.; Nandi, C.; Bhattacharyya, T.K.; Som, S.; Pal, G.; Bhandari, R.K.

2012-01-01

A cryostat is being designed for testing superconducting radio frequency (SCRF) cavity. The cryostat has an inner helium vessel where the SCRF cavity will be immersed in a pool of liquid helium. A liquid nitrogen shield surrounds the liquid helium vessel. The liquid helium vessel and liquid nitrogen shield shall be enclosed inside a vacuum chamber to reduce heat load. Different designs for the test cryostat have been evaluated. The thickness of inner vessel, outer vessel, head and all the flanges for test cryostat have been calculated for external and internal pressure and for bolt load required for sealing. Garlock Helicoflex spring energized seal are planned to be used for sealing the flanges at 4.5 K. Thermal calculations have been carried out to access the heat leak in the designs. The paper presents the structural and thermal design of the test cryostat. (author)

Experiences on vacuum conditioning in the cryostat of KSTAR tokamak

Energy Technology Data Exchange (ETDEWEB)

Kim, Kwang Pyo, E-mail: kpkim@nfri.er.ke [National Fusion Research Institute, Daejeon (Korea, Republic of); Woo, I.S.; Chang, Y.B.; Kwag, S.W.; Song, N.H.; Bang, E.N.; Hong, J.S.; Chu, Y.; Park, K.R. [National Fusion Research Institute, Daejeon (Korea, Republic of)

2013-10-15

Highlights: ► The vacuum of the cryostat has been stably maintained during the KSTAR operation. ► The detected cold leak at the PF/CS coils and CS structure. ► The present helium leak makes no issue for the cryostat operation. -- Abstract: Korea Superconducting Tokamak Advanced Research (KSTAR) device has been successfully operated for the plasma experiment from KSTAR 1st campaign to 4th campaign. The main pumping system for the cryostat has to maintain the target pressure below 1.0 × 10{sup −4} mbar at room temperature and 1.0 × 10{sup −5} mbar at extremely low temperature for the plasma experiment against the air leak coming from ports of vessel and/or the helium leak from cooling loops in the cryostat. No leak has been detected at room temperature. Unexpectedly, the cold-leak appeared in the cryostat at temperature around 50 K during the cool-down in the KSTAR 2nd campaign. We carefully analyzed the characteristics of detected cold leak because it can cause the increase of the base pressure in the cryostat. After the cool-down, the leak detection was performed to locate the position and size of the leak by the pressurizing the loops. As a result, it is found that the cold leak was located at cooling loops for PF/CS coils and CS structure. Nevertheless, the vacuum inside the cryostat was well maintained below 6.0 × 10{sup −8} mbar during the entire operation period. The impact of the He-leak in present status on the plasma operation is negligible. However, we have found that the leak rate increases as a function of time. Therefore careful monitoring on cold-leak is an important technical issue for the operation of superconducting tokamak.

Thermal and flow considerations for the 80 K shield of the SSC magnet cryostats

International Nuclear Information System (INIS)

Abramovich, S.; Yuecel, A.; Demko, J.; Thirumaleshwar, M.

1994-01-01

The nominal temperatures in the SSC magnets range between 4.2 K in the superconducting coils and 300 K on the cryostat outer wall. To minimize the 4 K heat load, one thermal shield cooled by liquid and vapor nitrogen flows at 84 K, and another cooled by helium flow at 20 K are incorporated in the cryostat. Tubes attached to the shields serve as conduits for the cryogens. The liquid nitrogen tube in the cryostat is used for shield refrigeration and also for liquid distribution around the SSC rings. The second nitrogen line is used to return the vapor to the helium refrigerators for helium precooling. The nominal LN2 flow from a 4.3 km long cryogenic string (4 sections) to the surface is 64 g/s. The total liquid nitrogen consumption of approximately 5000 g/s will be supplied at one, two or more locations on the surface. The total heat load of the 80 K shield is estimated as 3.2 W/m: about 50% is composed of infrared radiation; the remaining 50% is by heat conduction through supports, vacuum barriers and other thermal connections between the shield and the 300 K outer wall. The required LN2 flow rate depends on the distribution and circulation schemes. The LN2 temperature will in turn vary depending on the flow rate and on the recooling method used. For example, with a massflow of 400 g/s of LN2 the temperature rises from 82 K to 86 K between two compact recoolers 1 km apart. This temperature is higher than desired. The temperature can be reduced by increasing the flow rate of the liquid or by using the continuous recooling scheme. This paper discusses some thermal problems caused by certain mechanical designs of the 80 K shield and the possible improvement by using continuous recooling. The authors present results of the 80 K shield temperature distribution analysis, the 20 K shield heat load augmentation resulting from the increased 80 K shield temperatures, the continuous nitrogen recooling scheme and some flow timing related analysis

HFE and Spherical Cryostats MC Study

International Nuclear Information System (INIS)

Brodsky, Jason P.

2016-01-01

The copper vessel containing the nEXO TPC is surrounded by a buffer of HFE, a liquid refrigerant with very low levels of radioactive element contamination. The HFE is contained within the cryostat's inner vessel, which is in turn inside the outer vessel. While some HFE may be necessary for stable cooling of nEXO, it is possible that using substantially more than necessary for thermal reasons will help reduce backgrounds originating in the cryostats. Using a larger amount of HFE is accomplished by making the cryostat vessels larger. By itself, increasing the cryostat size somewhat increases the background rate, as the thickness of the cryostat wall must increase at larger sizes. However, the additional space inside the cryostat will be filled with HFE which can absorb gamma rays headed for the TPC. As a result, increasing the HFE reduces the number of backgrounds reaching the TPC. The aim of this study was to determine the relationship between HFE thickness and background rate. Ultimately, this work should support choosing a cryostat and HFE size that satisfies nEXO's background budget. I have attempted to account for every consequence of changing the cryostat size, although naturally this remains a work in progress until a final design is achieved. At the moment, the scope of the study includes only the spherical cryostat design. This study concludes that increasing cryostat size reduces backgrounds, reaching neglible backgrounds originating from the cryostat at the largest sizes. It also shows that backgrounds originating from the inherent radioactivity of the HFE plateau quickly, so may be considered essentially fixed at any quantity of HFE.

Inside the ATLAS solenoid cryostat

CERN Multimedia

Claudia Marcelloni

2006-01-01

Scientists are seen working on the inside of the ATLAS cryostat, which will be used to cool liquid argon to 90 K in the electromagnetic calorimeter. Thin lead plates immersed in the cooled liquid will produce electromagnetic showers of particles when an electron, positron or photon enter the detector. This causes the argon to glow, allowing the initial particle energy to be measured.

Test of a cryogenic set-up for a 10 meter long liquid nitrogen cooled superconducting power cable

DEFF Research Database (Denmark)

Træholt, Chresten; Rasmussen, Carsten; Kühle (fratrådt), Anders Van Der Aa

2000-01-01

High temperature superconducting power cables may be cooled by a forced flow of sub-cooled liquid nitrogen. One way to do this is to circulate the liquid nitrogen (LN2) by means of a mechanical pump through the core of the cable and through a sub-cooler.Besides the cooling station, the cryogenics...... cable. We report on our experimental set-up for testing a 10 meter long high temperature superconducting cable with a critical current of 3.2 kA at 77K. The set-up consists of a custom designed cable end termination, current lead, coolant feed-through, liquid nitrogen closed loop circulation system...

Dual-stage trapped-flux magnet cryostat for measurements at high magnetic fields

Science.gov (United States)

Islam, Zahirul; Das, Ritesh K.; Weinstein, Roy

2015-04-14

A method and a dual-stage trapped-flux magnet cryostat apparatus are provided for implementing enhanced measurements at high magnetic fields. The dual-stage trapped-flux magnet cryostat system includes a trapped-flux magnet (TFM). A sample, for example, a single crystal, is adjustably positioned proximate to the surface of the TFM, using a translation stage such that the distance between the sample and the surface is selectively adjusted. A cryostat is provided with a first separate thermal stage provided for cooling the TFM and with a second separate thermal stage provided for cooling sample.

A new cryostat for precise temperature control

Science.gov (United States)

Dong, B.; Zhou, G.; Liu, L. Q.; Zhang, X.; Xiong, L. Y.; Li, Q.

2013-09-01

Gifford-McMahon (GM) cryocoolers are often used in cryostat as cold sources. It has advantages of simple structure and low operating cost as well as disadvantages of vibration and temperature oscillation, which are fatal for some applications that are very sensitive to temperature stability at low temperature. To solve the problem, a thermal analysis model which is used to simulate heat transfer in the cryostat is built and discussed. According to the analysis results, a cryostat that can provide variable temperature (4-20 K) for the accurate temperature control experiments is designed and manufactured. In this cryostat, a polytetrafluoroethylene (PTFE) sheet is used as a thermal damper to reduce the temperature oscillation, with which, the temperature oscillation of the sample cooling holder is less than 4 mK at the 20 K region.

A compact and versatile dynamic flow cryostat for photon science

Science.gov (United States)

van der Linden, Peter J. E. M.; Moretti Sala, Marco; Henriquet, Christian; Rossi, Matteo; Ohgushi, Kenya; Fauth, François; Simonelli, Laura; Marini, Carlo; Fraga, Edmundo; Murray, Claire; Potter, Jonathan; Krisch, Michael

2016-11-01

We have developed a helium gas flow cryostat for use on synchrotron tender to hard X-ray beamlines. Very efficient sample cooling is achieved because the sample is placed directly in the cooling helium flow on a removable sample holder. The cryostat is compact and easy to operate; samples can be changed in less than 5 min at any temperature. The cryostat has a temperature range of 2.5-325 K with temperature stability better than 0.1 K. The very wide optical angle and the ability to operate in any orientation mean that the cryostat can easily be adapted for different X-ray techniques. It is already in use on different beamlines at the European Synchrotron Radiation Facility (ESRF), ALBA Synchrotron Light Facility (ALBA), and Diamond Light Source (DLS) for inelastic X-ray scattering, powder diffraction, and X-ray absorption spectroscopy. Results obtained at these beamlines are presented here.

Specific cooling capacity of liquid nitrogen

Science.gov (United States)

Kilgore, R. A.; Adcock, J. B.

1977-01-01

The assumed cooling process and the method used to calculate the specific cooling capacity of liquid nitrogen are described, and the simple equation fitted to the calculated specific cooling capacity data, together with the graphical form calculated values of the specific cooling capacity of nitrogen for stagnation temperatures from saturation to 350 K and stagnation pressures from 1 to 10 atmospheres, are given.

A closed cycle-cryostat for high-field Moessbauer spectroscopy

International Nuclear Information System (INIS)

Janoschka, A; Schuenemann, V; Svenconis, G

2010-01-01

A closed cycle-cryostat coupled to a Moessbauer spectrometer has been installed at the University of Kaiserslautern and is in full operation since march 2007. The setup is equipped with a low vibrating two-stage pulse tube cooler and has a cool down time of 48 h. The sample can be top loaded without the need to shut off the refrigerator. With the static helium exchange gas in the variable temperature insert the sample may be cooled down from room temperature to 50 K within several hours. Dynamic exchange gas with external supply of gaseous helium is used to cool the sample down to 2 K. The superconducting self-shielding split-coil generates a magnetic field of up to 5 Tesla and a stray field of ca. 60 mT at the outer cryostat walls. Moessbauer measurements can be performed in perpendicular or parallel field orientations. The sample holder and the Moessbauer drive are rigidly connected to the cryostat. In this way a line width of the two inner α-Fe lines of 0.32 mm/s has been currently achieved.

A simple continuous flow cryostat for low temperature experiments in pile

International Nuclear Information System (INIS)

Yanagi, Hideharu; Tamura, Takaaki; Tabata, Yoneho

1978-01-01

A conventional liquid bath type cryostat connected with a helium refrigerator has been used for the irradiation at very low temperatures in a fast neutron source reactor, YAYOI. In order to start the experiments with the cryostat, it takes 4 to 6 hours to cool down and get ready for irradiation. Furthermore, it was not possible to transfer irradiated samples from the cryostat for irradiation to the other for measurements of electron spin resonance and resistivity, keeping the temperature of liquid helium. Accordingly a simple and convenient cryostat which is capable of providing a wide range of temperatures from liquid helium to 300K, as well as transferring samples with less complexity had been required. In this paper, the design and fabrication of a simple continuous flow cryostat to meet our requirements mentioned above is reported. Cooling time and the consumption rate of liquid helium during the operation at 4.2K under an output of the nuclear reactor of 500W are designed to be less than 30 minutes and less than 7 litres/hour, respectively. (author)

A simple continuous flow cryostat for low temperature experiments in pile

International Nuclear Information System (INIS)

Yanagi, Hideharu; Tamura, Takaaki; Tabata, Yoneho

1978-01-01

A conventional liquid bath type cryostat connected with a helium refrigerator has been used for the irradiation at very low temperatures in a fast neutron source reactor, YAYOI. In order to start the experiments with the cryostat, it takes 4 to 6 hours to cool down and get ready for irradiation. Furthermore, it was not possible to transfer irradiated samples from the cryostat for irradiation to the other for measurements of electron spin resonance and resistivity keeping the temperature of liquid helium. Accordingly a simple and convenient cryostat which is capable of providing a wide range of temperatures from liquid helium to 300K, as well as transfering samples with less complexity had been required. In this paper, the design and fabrication of a simple continuous flow cryostat to meet our requirements mentioned above is reported. Cooling time and the consumption rate of liquid helium during the operation at 4.2K under a output of the nuclear reactor of 500W are designed to be less than 30 minutes and less than 7 litres/hour, respectively. (author)

Cryostat for an well logging probe using a semiconductor detector

International Nuclear Information System (INIS)

Tapphorn, R.M.

1978-01-01

This invention proposes to construct an well logging tool of the type comprising a semiconductor radiation detector devoid of the defects usually observed. This aim is attained by means of a cryostat to cool a semiconductor radiation detector in a restricted space where the temperature is high. It includes a long box dimensioned to pass through a bore hole, a cryogenic chamber housed in the box, a vacuum chamber thermally insulating the cryogenic chamber and placed around it, a semiconductor radiation detector housed in the vacuum chamber in thermal contact with the cryogenic chamber and an active vacuum pump fitted in the box and connected to the vacuum chamber to maintain a vacuum in it. In an improved version, the vacuum pump is fitted outside the cryostat so that it operates independently of the temperature conditions in the cryostat. If the pump needs to be cooled to reduce the gas discharge, it can be fitted inside the cryostat and connected to the cryogenic chamber or a second cryostat can also be provided to cool the pump. The vacuum pump is designed to maintain the vacuum in the thermal insulation vacuum chamber at a desired figure, preferably 10 -4 Torr or under, in order to preserve the integrity of the thermal insulation layer around the cryogenic chamber and thereby extending the efficient operating period of the detector. The cryogenic material used is preferably of fusion resistant type such as Freon 22 [fr

Design of the Cryostat for HT-7U Superconducting Tokamak

Science.gov (United States)

Yu, Jie; Wu, Song-tao; Song, Yun-tao; Weng, Pei-de

2002-06-01

The cryostat of HT-7U tokamak is a large vacuum vessel surrounding the entire basic machine with a cylindrical shell, a dished top and a flat bottom. The main function of HT-7U cryostat is to provide a thermal barrier between an ambient temperature test hall and a liquid helium-cooled superconducting magnet. The loads applied to the cryostat are from sources of vacuum pressure, dead weight, seismic events and electromagnetic forces originated by eddy currents. It also provides feed-through penetrations for all the connecting elements inside and outside the cryostat. The main material selected for the cryostat is stainless steel 304L. The structural analyses including buckling for the cryostat vessel under the plasma operation condition have been carried out by using a finite element code. Stress analysis results show that the maximum stress intensity was below the allowable value. In this paper, the structural analyses and design of HT-7U cryostat are emphasized.

ATHENA X-IFU 300 K-50 mK cryochain demonstrator cryostat

Science.gov (United States)

Prouvé, T.; Duval, J. M.; Charles, I.; Yamasaki, N. Y.; Mitsuda, K.; Nakagawa, T.; Shinozaki, K.; Tokoku, C.; Yamamoto, R.; Minami, Y.; Le Du, M.; Andre, J.; Daniel, C.; Linder, M.

2018-01-01

In the framework of the ESA X-ray mission ATHENA, scheduled for launch in 2028, an ESA Core Technology Program (CTP) was started in 2016 to build a flight like cryostat demonstrator in parallel with the phase A studies of the ATHENA/X-IFU instrument [1,2]. As part of this CTP, called the Detector Cooling System (DCS), design, manufacturing and test of a cryostat including existing space coolers will be done. In addition to the validation of thermal performance, a Focal Plan Assembly (FPA) demonstrator using Transition Edge Sensors (TES) detector technology will be also integrated and its performance characterized versus the environment provided by the cryostat. This is a unique opportunity to validate many crucial issues of the cryogenic part of such a sensitive instrument. A dedicated activity within this CTP-DCS is the demonstration of the 300 K-50 mK cooling chain in a Ground System Equipment (GSE) cryostat. The studies are focused on the operation of the space coolers, which is made possible by the use of a ground cooler for cooling cryogenic shields and mechanical supports. Thanks to the modularity of the cryostat, several cooling chains could be tested. In the base line configuration described here, the low temperature stage is the CEA hybrid sorption/ADR 50 mK cooler with thermal interfaces at 4 K and 2 K. 4 K cooling is accomplished by a 4 K Joule-Thomson (JT) cryocooler and its Stirling precooler provided by JAXA. Regarding the 2 K stage, at first a 2 K JT from JAXA will be used. Alternatively, a 2 K JT cooler from RAL could replace the JAXA 2 K JT. In both cases new prototype(s) of a 2 K JT will be implemented, precooled by the EM 15 K pule tube cooler from Air Liquide. This test program is also the opportunity to validate the operation of the cryochain with respect to various requirements, such as time constant and temperature stabilities. This would bring us valuable inputs to integrate the cryochain in DCS cryostat or for the X-IFU phase A studies

On the operation of a cryostat for Ge(Li) detector

International Nuclear Information System (INIS)

Donde, A.L.; L'vov, A.N.

1974-01-01

Operating experience with cryostats for Ge(Li) detectors developed at the FTI of the Academy of Science of the Ukrainian SSR, and used in several laboratories for 5 years is reported. It is shown that the spectrometric properties of all cryostat-mounted detectors operating since 1969 have not been affected and up to now the detectors are operating successfully. Nitrogen consumption has not increased and is at a level of 0.5 l/d. During five-year continuous operation the cryostat pressure has varied from 6.10 -7 to 8.10 -6 torr

Quantitative study of sniffer leak rate and pressure drop leak rate of liquid nitrogen panels of SST-1 tokamak

Science.gov (United States)

Pathan, F. S.; Khan, Z.; Semwal, P.; Raval, D. C.; Joshi, K. S.; Thankey, P. L.; Dhanani, K. R.

2008-05-01

Steady State Super-conducting (SST-1) Tokamak is in commissioning stage at Institute for Plasma Research. Vacuum chamber of SST-1 Tokamak consists of 1) Vacuum vessel, an ultra high vacuum (UHV) chamber, 2) Cryostat, a high vacuum (HV) chamber. Cryostat encloses the liquid helium cooled super-conducting magnets (TF and PF), which require the thermal radiation protection against room temperature. Liquid nitrogen (LN2) cooled panels are used to provide thermal shield around super-conducting magnets. During operation, LN2 panels will be under pressurized condition and its surrounding (cryostat) will be at high vacuum. Hence, LN2 panels must have very low leak rate. This paper describes an experiment to study the behaviour of the leaks in LN2 panels during sniffer test and pressure drop test using helium gas.

Quantitative study of sniffer leak rate and pressure drop leak rate of liquid nitrogen panels of SST-1 tokamak

International Nuclear Information System (INIS)

Pathan, F S; Khan, Z; Semwal, P; Raval, D C; Joshi, K S; Thankey, P L; Dhanani, K R

2008-01-01

Steady State Super-conducting (SST-1) Tokamak is in commissioning stage at Institute for Plasma Research. Vacuum chamber of SST-1 Tokamak consists of 1) Vacuum vessel, an ultra high vacuum (UHV) chamber, 2) Cryostat, a high vacuum (HV) chamber. Cryostat encloses the liquid helium cooled super-conducting magnets (TF and PF), which require the thermal radiation protection against room temperature. Liquid nitrogen (LN2) cooled panels are used to provide thermal shield around super-conducting magnets. During operation, LN 2 panels will be under pressurized condition and its surrounding (cryostat) will be at high vacuum. Hence, LN 2 panels must have very low leak rate. This paper describes an experiment to study the behaviour of the leaks in LN 2 panels during sniffer test and pressure drop test using helium gas

An ATLAS inner detector end-cap is placed in its cryostat

CERN Multimedia

2007-01-01

The instrumentation housed inside the inner end-cap must be kept cool to avoid thermal noise. This cooling is achieved on ATLAS by placing the end-cap inside a liquid argon cryostat. The end-cap measures particles that are produced close to the direction of the beam pipe and would otherwise be missed.

Overview and status of ITER Cryostat manufacturing

Energy Technology Data Exchange (ETDEWEB)

Bhardwaj, Anil K., E-mail: anil.bhardwaj@iter-india.org [ITER-India, Institute For Plasma Research, A-29, GIDC Electronics Estate, Sector-25, Gandhinagar 382016 (India); Gupta, Girish; Prajapati, Rajnikant; Joshi, Vaibhav; Patel, Mitul; Bhavsar, Jagrut; More, Vipul; Jindal, Mukesh; Bhattacharya, Avik; Jogi, Gourav; Palaliya, Amit; Jha, Saroj; Pandey, Manish; Shukla, Dileep [ITER-India, Institute For Plasma Research, A-29, GIDC Electronics Estate, Sector-25, Gandhinagar 382016 (India); Iyer, Ganesh; Jadhav, Pandurang; Goyal, Dipesh; Desai, Anish [Larsen & Toubro Limited, Heavy Engineering, Hazira Manufacturing Complex, Gujarat (India); Sekachev, I.; Vitupier, Guillaume [ITER Organization, Route de Vinon sur Verdon – CS 90046, 13067 Saint Paul Lez Durance Cedex (France); and others

2016-11-01

Highlights: • Manufacturing status of one of the largest and the heaviest fully welded stainless steel vacuum chambers in the world (ITER Cryostat). • Overview of manufacturing stages and its segmentation. • Overview of manufacturing procedures and assembly and installation. - Abstract: One of ITER-India's commitments to the ITER Organization is procurement of the ITER Cryostat. It is a large vacuum vessel (∼29 m dia. and ∼29 m height), which is made up of 304/304 L dual marked stainless steel and has a total mass over 3500 t. The thickness of the vessel wall varies from 50 mm to 190 mm. It is one of the largest and the heaviest fully welded stainless steel vacuum chambers in the world which provides vacuum thermal insulation for the superconducting magnets operating at 4.5 K and for the thermal shield operating at 80 K. It also mechanically supports the magnet system along with the vacuum vessel (VV). The cryostat is designed and constructed according to ASME Section-VIII Division-2 with additional ITER Vacuum Handbook requirements and it is classified as protection important component (PIC-2). Manufacturing of cryostat segments is ongoing in India; sub-assembly of four major sections of the cryostat from the segments will be done at the ITER site in a temporary workshop building and the final assembly will be done in the pit of the tokamak building, the final location. The cryostat manufacturing contract has been awarded to Larsen and Toubro Limited in August 2012 after completion of design [4] and signing of Procurement Arrangement [1] with ITER Organization. Manufacturing of the cryostat was started in January 2014 after approval of the manufacturing drawings and procedures. The temporary workshop of 44 m × 110 m × 26 m in height has been completed in November 2014 at the ITER site with a 200 t crane installed. This paper gives an overview and the status of the cryostat manufacturing.

Thermoregulated Nitric Cryosystem for Cooling Gas-Filled Detectors of Ionizing Radiation

Directory of Open Access Journals (Sweden)

Zharkov I.P.

2015-09-01

Full Text Available Cryosystem for cooling and filling of gas-filled detectors of ionizing radiation with compressed inert gas on the basis of wide-nitrogen cryostat, which provides detetector temperature control in a range of 173 — 293 K and its stabilization with accuracy of ± 1°. The work was carried out within the Ukraine — NATO Program of Collaboration, Grant SfP #984655.

Development of the cryogenic system of AEgIS at CERN

Energy Technology Data Exchange (ETDEWEB)

Derking, J. H.; Bremer, J.; Burghart, G.; Doser, M.; Dudarev, A.; Haider, S. [Technology Department, CERN, Geneva 23, CH-1211 (Switzerland)

2014-01-29

The AEgIS (Antimatter Experiment: Gravity, Interferometry, Spectroscopy) experiment is located at the antiproton decelerator complex of CERN. The main goal of the experiment is to perform the first direct measurement of the Earth’s gravitational acceleration on antihydrogen atoms within 1% precision. The antihydrogen is produced in a cylindrical Penning trap by combining antiprotons with positrons. To reach the precision of 1%, the antihydrogen has to be cooled to 100 mK to reduce its random velocity. A dilution refrigerator is selected to deliver the necessary cooling capacity of 100 μW at 50 mK. The AEgIS cryogenic system basically consists of cryostats for a 1-T and for a 5-T superconducting magnet, a central region cryostat, a dilution refrigerator cryostat and a measurement cryostat with a Moiré deflectometer to measure the gravitational acceleration. In autumn 2012, the 1-T cryostat, 5-T cryostat and central region cryostat were assembled and commissioned. The apparatus is cooled down in eight days using 2500 L of liquid helium and liquid nitrogen. During operation, the average consumption of liquid helium is 150 L⋅day{sup −1} and of liquid nitrogen 5 L⋅day{sup −1}. The temperature sensors at the Penning traps measured 12 K to 18 K, which is higher than expected. Simulations show that this is caused by a bad thermalization of the trap wiring. The implementation of the sub-kelvin region is foreseen for mid-2015. The antihydrogen will be cooled down to 100 mK in an ultra-cold trap consisting of multiple high-voltage electrodes made of sapphire with gold plated electrode sectors.

Cryostat Design

Energy Technology Data Exchange (ETDEWEB)

Parma, V [European Organization for Nuclear Research, Geneva (Switzerland)

2014-07-01

This paper aims to give non-expert engineers and scientists working in the domain of accelerators a general introduction to the main disciplines and technologies involved in the design and construction of accelerator cryostats. Far from being an exhaustive coverage of these topics, an attempt is made to provide simple design and calculation rules for a preliminary design of cryostats. Recurrent reference is made to the Large Hadron Collider magnet cryostats, as most of the material presented is taken from their design and construction at CERN.

Thermal Performance of the LHC Short Straight Section Cryostat

CERN Document Server

Bergot, J B; Nielsen, L; Parma, Vittorio; Rohmig, P; Roy, E

2002-01-01

The LHC Short Straight Section (SSS) cryostat houses and thermally protects in vacuum the cold mass which contains a twin-aperture superconducting quadrupole magnet and superconducting corrector magnets operating at 1.9 K in superfluid helium. In addition to mechanical requirements, the cryostat is designed to minimize the heat in-leak from the ambient temperature to the cold mass. Mechanical components linking the cold mass to the vacuum vessel such as support posts and an insulation vacuum barrier are designed to have minimum heat conductivity with efficient thermalisations for heat interception. Heat in-leak by radiation is reduced by employing multilayer insulation wrapped around the cold mass and an actively cooled aluminium thermal shield. The recent commissioning and operation of two SSS prototypes in the LHC Test String 2 have given a first experimental validation of the thermal performance of the SSS cryostat in nominal operating conditions. Temperature sensors mounted in critical locations provide a...

Trapped field measurements on MgB{sub 2} bulk samples

Energy Technology Data Exchange (ETDEWEB)

Koblischka, Michael; Karwoth, Thomas; Zeng, XianLin; Hartmann, Uwe [Institute of Experimental Physics, Saarland University, P. O. Box 151150, D-66041 Saarbruecken (Germany); Berger, Kevin; Douine, Bruno [University of Lorraine, GREEN, 54506 Vandoeuvre-les-Nancy (France)

2016-07-01

Trapped field measurements were performed on bulk, polycrystalline MgB{sub 2} samples stemming from different sources with the emphasis to develop applications like superconducting permanent magnets ('supermagnets') and electric motors. We describe the setup for the trapped field measurements and the experimental procedure (field cooling, zero-field cooling, field sweep rates). The trapped field measurements were conducted using a cryocooling system to cool the bulk samples to the desired temperatures, and a low-loss cryostat equipped with a room-temperature bore and a maximum field of ±5 T was employed to provide the external magnetic field. The superconducting coil of this cryostat is operated using a bidirectional power supply. Various sweep rates of the external magnetic field ranging between 1 mT/s and 40 mT/s were used to generate the applied field. The measurements were performed with one sample and two samples stacked together. A maximum trapped field of 7 T was recorded. We discuss the results obtained and the problems arising due to flux jumping, which is often seen for the MgB{sub 2} samples cooled to temperatures below 10 K.

Subcooled Liquid Oxygen Cryostat for Magneto-Archimedes Particle Separation by Density

Science.gov (United States)

Hilton, D. K.; Celik, D.; Van Sciver, S. W.

2008-03-01

An instrument for the separation of particles by density (sorting) is being developed that uses the magneto-archimedes effect in liquid oxygen. With liquid oxygen strongly paramagnetic, the magneto-archimedes effect is an extension of diamagnetic levitation in the sense of increasing the effective buoyancy of a particle. The instrument will be able to separate ensembles of particles from 100 μm to 100 nm in size, and vertically map or mechanically deliver the separated particles. The instrument requires a column of liquid oxygen that is nearly isothermal, free of thermal convection, subcooled to prevent nucleate boiling, and supported against the strong magnetic field used. Thus, the unique cryostat design that meets these requirements is described in the present article. It consists in part of a column of liquid nitrogen below for cooling the liquid oxygen, with the liquid oxygen pressurized by helium gas to prevent nucleate boiling.

Dynamic deuteron polarization measurements performed in a new type of horizontal dilution cryostat

International Nuclear Information System (INIS)

Meyer, W.; Althoff, K.H.; Kaul, O.; Riechert, H.; Schilling, E.

1982-05-01

We have reached 31% deuteron polarization in D- ammonia (ND 3 ) and 27% in D- butanol (C 4 D 10 O). The dynamic polarization experiments were performed at a magnetic field of 2.5 T in a new type of horizontal dilution cryostat. This dilution cryostat, built for target asymmetry measurements with a photon beam, was developed with special regard to fast cool-down and easy loading of the target material. The cooling power is 5 mW at 0.2 K, 20 mW at 0.3 K and 34 mW at 0.4 K. Starting from room temperature the lowest temperature of 165 mK is reached in about 2 h including the loading of the target material. (orig.)

Design of a horizonal liquid helium cryostat for refrigerating a flying superconducting magnet in a wind tunnel

Science.gov (United States)

Wu, Y. Y.

1982-01-01

The design of a horizontal liquid helium cryostat for refrigerating a flying superconducting magnet in a wind tunnel is presented. The basic principles of magnetic suspension theory are described and theoretical calculations of the superconducting magnet are provided. The experimental results of the boil-off of liquid nitrogen and liquid helium in the cryostat are reported.

Commissioning of the 4 K Outer Cryostat for the CUORE Experiment

CERN Document Server

Ferri, E; Biassoni, M; Bucci, C; Ceruti, G; Chiarini, A; Clemenza, M; Cremonesi, O; Datskov, V; Dossena, S; Faverzani, M; Franceschi, M A; Gaigher, R; Gorla, P; Guetti, M; Ligi, C; Napolitano, T; Nucciotti, A; Pelosi, A; Perego, M; Previtali, E; Sisti, M; Taffarello, L; Terranova, F

2014-01-01

The Cryogenic Underground Observatory for Rare Events (CUORE) is a 1-ton scale bolometric experiment. The CUORE detector is an array of 988 TeO crystals arranged in a cylindrical, compact, and granular structure of 19 towers. These detectors will need a base temperature lower than 10 mK in order to meet the performance specifications. To cool the CUORE detector, a large cryogen free cryostat with five pulse tubes and one custom designed high power dilution refrigerator has been designed. The three vessels that form the outer shell of the CUORE cryostat were produced in 2012 and are now assembled in the Gran Sasso National Laboratories (LNGS). We report here the detailed description of the 4 K outer cryostat for the CUORE experiment together with the results of the validation tests done at the production site in 2012 and of the first commissioning to 4 K at LNGS in 2013.

Solutions for Liquid Nitrogen Pre-Cooling in Helium Refrigeration Cycles

CERN Document Server

Wagner, U

2000-01-01

Pre-cooling of helium by means of liquid nitrogen is the oldest and one of the most common process features used in helium liquefiers and refrigerators. Its two principle tasks are to allow or increase the rate of pure liquefaction, and to permit the initial cool-down of large masses to about 80 K. Several arrangements for the pre-cooling process are possible depending on the desired application. Each arrangement has its proper advantages and drawbacks. The aim of this paper is to review the possible process solutions for liquid nitrogen pre-cooling and their particularities.

Cryostat design case studies, principles and engineering

CERN Document Server

2016-01-01

This book enables the reader to learn the fundamental and applied aspects of practical cryostat design by examining previous design choices and resulting cryostat performance. Through a series of extended case studies the book presents an overview of existing cryostat design covering a wide range of cryostat types and applications, including the magnet cryostats that comprise the majority of the Large Hadron Collider at CERN, space-borne cryostats containing sensors operating below 1 K, and large cryogenic liquid storage vessels. It starts with an introductory section on the principles of cryostat design including practical data and equations. This section is followed by a series of case studies on existing cryostats, describing the specific requirements of the cryostat, the challenges involved and the design choices made along with the resulting performance of the cryostat. The cryostat examples used in the studies are chosen to cover a broad range of cryostat applications and the authors of each case are ...

Cryostatic stability equation

International Nuclear Information System (INIS)

Sydoriak, S.G.

1976-01-01

Although criteria for cryostatic stability of superconducting magnets cooled by pool boiling of liquid helium have been widely discussed the same cannot be said for magnets cooled by natural convection or forced flow boiling in channels. Boiling in narrow channels is shown to be qualitatively superior to pool boiling because the recovery heat flux equals the breakaway flux for narrow channels, whereas the two are markedly different in pool boiling. A second advantage of channel boiling is that it is well understood and calculable; pool peak nucleate boiling heat flux has been adequately measured only for boiling from the top of an immersed heated body. Peak boiling from the bottom is much less and (probably) depends strongly on the extent of the bottom surface. Equations are presented by which one can calculate the critical boiling heat flux for parallel wall vertical channels subject to either natural convection or forced flow boiling, with one or both walls heated. The one-heated-wall forced flow equation is discussed with regard to design of a spiral wound solenoid (pancake magnet) having a slippery insulating tape between the windings

Deformation mechanism of the Cryostat in the CADS Injector II

Science.gov (United States)

Yuan, Jiandong; Zhang, Bin; Wan, Yuqin; Sun, Guozhen; Bai, Feng; Zhang, Juihui; He, Yuan

2018-01-01

Thermal contraction and expansion of the Cryostat will affect its reliability and stability. To optimize and upgrade the Cryostat, we analyzed the heat transfer in a cryo-vacuum environment from the theoretical point first. The simulation of cryo-vacuum deformation based on a finite element method was implemented respectively. The completed measurement based on a Laser Tracker and a Micro Alignment Telescope was conducted to verify its correctness. The monitored deformations were consistent with the simulated ones. After the predictable deformations in vertical direction have been compensated, the superconducting solenoids and Half Wave Resonator cavities approached the ideal "zero" position under liquid helium conditions. These guaranteed the success of 25 MeV@170 uA continuous wave protons of Chinese accelerator driven subcritical system Injector II. By correlating the vacuum and cryo-deformation, we have demonstrated that the complete deformation was the superposition effect of the atmospheric pressure, gravity and thermal stress during both the process of cooling down and warming up. The results will benefit to an optimization for future Cryostat's design.

Geometrical position of the Large Hadron Collider main dipole inside the cryostat

CERN Document Server

La China, M; Gubello, G; Hauviller, Claude; Scandale, Walter; Todesco, Ezio

2002-01-01

The superconducting dipole of the Large Hadron Collider (LHC) is a cylindrical structure made of a shrinking cylinder containing iron laminations and collared coils. This 15 m long structure, weighing about 28 t, is horizontally bent by 5 mrad. Its geometrical shape should be preserved, from the assembly phase to the operational condition at cryogenic temperature. When inserted in its cryostat, the dipole cold mass is supported by three posts also providing the thermal insulation. Sliding interfaces should minimize the interference between the dipole and the cryostat during cooling down and warming up. Indeed, a possible non-linear response of the sliding interface can detrimentally affect the final dipole shape. This paper presents the results of dedicated tests investigating interferences and of specific simulations with a 3D finite element model (FEM) describing the mechanical behaviour of the dipole inside the cryostat. Comparison between measurements and FEM simulations is also discussed.

Cooling for SC devices of test cryomodule for ADS Injector II at IMP

Energy Technology Data Exchange (ETDEWEB)

Wang, L.; Wang, S. Y.; Sun, S.; Wang, S. H.; Liu, Y. Y. [Shanghai Institute of Applied Physics, CAS, Shanghai 201204 (China); Guo, X. L. [JiangSu University, Zhenjiang 212013 (China)

2014-01-29

The superconducting half-wave resonance cavities connected in series with superconducting solenoids will be applied to the Injector II of the Accelerator Driven Sub-critical System (ADS) to be built at the Modern Physics Institute, China. A test system has been developed for the purpose of performance test of the HWR cavities as well as validating the relevant technique for cooling the cavity and the solenoids together. It mainly comprises a cryogenic valve box (TVB), a test cryomodule (TCM1) and transfer lines. The TCM1 includes one HWR cavity, two superconducting solenoids, one cold BPM and their cooling system. The design of the TCM1 cryostat was carried out by the Shanghai Institute of Applied Physics (SINAP), CAS. Both the cavity and the solenoids will work at 4.4 K by bath cooling. The fast cooling down for the cavity from around 100 K to 120 K is required to avoid degrading of the cavity performance. After cool down and before energization, the solenoids should be warmed up to above 10 K and re-cooled down for the purpose of degaussing. The TCM1 can not only be cooled by using the dewar-filling system, but also operated by the refrigerator system. For the purpose of reducing the heat loads to the cold mass at 4 K from room temperature, thermal radiation shields cooled by liquid nitrogen flowing in tubing were employed. This paper presents the design details of cooling circuits and thermal shields of the TCM1 as well as related calculations and analyses.

A new cryostat for 'in situ' radiation damage studies

International Nuclear Information System (INIS)

Hariharan, Y.; Radhakrishnan, T.S.

1977-01-01

Conventional cryostats to study properties of materials between 4deg K and 300deg K base their designs either on continuous flow or bath type. A new cryostat which incorporates the advantages of both these has been designed and fabricated. This essentially has three chambers isolated from each other by poor thermal links. These are enclosed in a vacuum chamber and the whole assembly is immersed in a 4 He bath. The lowermost chamber is kept in good thermal contact with the bath. The second chamber can be maintained between 4deg K and 77deg K by circulation of cold 4 He vapour. The uppermost chamber can be maintained between 77deg K and 300deg K by circulating cold nitrogen vapours. There is a through axial hole in the centre, through which the sample can be moved up and down by means of a thin walled stainless steel tube. This comes out from the top of the cryostat through a Wilson seal. Thus the specimen can be anchored in any of the three chambers. This cryostat can be used to study the radiation damages caused by α-particles the sample being kept at 4.2deg K. There is provision for isolating the sample from the radiation zone. Isothermal and isochronal annealing of the damage caused can also be studied. Provision for taking out electrical leads from both inside and outside the sample chamber are also there. (auth.)

Operational experience with double acting piston pumps for cryogenic helium and nitrogen

International Nuclear Information System (INIS)

Vosswinkel, F.

1978-01-01

The design of a high efficiency double acting piston pump suitable for pumping liquefied gases at cryogenic temperatures for cable cooling, is reported. The pump has proved flexible, reliable and efficient in operation. The plunger-type pumps can be used for filling cryostats or dewars with liquid helium or nitrogen from a pressure free or pressurized storage vessel, or as circulators for subcooled, saturated and/or supercritical helium in large scale cooling experiments. Flow rates of up to 17 g/s, maximum operating pressure of 600 kPa absolute and maximum differential pressure of approximately 100 kPa are obtained. (UK)

Design of closed-loop nitrogen Joule-Thomson refrigeration cycle for 67 K with sub-atmospheric device

Energy Technology Data Exchange (ETDEWEB)

Lee, C.; Lee, J.; Jeong, S. [Cryogenic Engineering Laboratory, Korea Advanced Institute of Science and Technology, Daejeon (Korea, Republic of)

2013-05-15

Closed-loop J-T (Joule-Thomson) refrigeration cycle is advantageous compared to common open loop N{sub 2} decompression system in terms of nitrogen consumption. In this study, two closed-loop pure N{sub 2} J-T refrigeration systems with sub-atmospheric device for cooling High Temperature Superconductor (HTS) power cable are investigated. J-T cooling systems include 2-stage compressor, 2-stage precooling cycle, J-T valve and a cold compressor or an auxiliary vacuum pump at the room temperature. The cold compressor and the vacuum pump are installed after the J-T valve to create sub-atmospheric condition. The temperature of 67 K is possible by lowering the pressure up to 24 kPa at the cold part. The optimized hydrocarbon mixed refrigerant (MR) J-T system is applied for precooling stage. The cold head of precooling MR J-T have the temperature from 120 K to 150 K. The various characteristics of cold compressor are investigated and applied to design parameter of the cold compressor. The Carnot efficiency of cold compressor system is calculated as 16.7% and that of vacuum pump system as 16.4%. The efficiency difference between the cold compressor system and the vacuum pump system is due to difference of enthalpy change at cryogenic temperature, enthalpy change at room temperature and different work load at the pre-cooling cycle. The efficiency of neon-nitrogen MR J-T system is also presented for comparison with the sub-atmospheric devices. These systems have several pros and cons in comparison to typical MR J-T systems such as vacuum line maintainability, system's COP and etc. In this paper, the detailed design of the subcooled N{sub 2} J-T systems are examined and some practical issues of the sub-atmospheric devices are discussed.

NIF target fill, transport and insertion cryostat

International Nuclear Information System (INIS)

Warren, R.

1994-01-01

A cryostat to support the fielding of a cryogenic target within the NIF is described. The present design is predicated upon fuel layer symmetry being achieved with the β layering process and modifications needed for other fuel symmetrization processes are discussed. These include the vertically differentially heated capsule with a uniform liquid layer stabilized by a surface tension gradient, foam supported liquid layers and solid D 2 or HD layers symmetrized by bulk irradiation from a laser source. The cold sinks to be incorporated in these techniques could, in principal, be cooled with the high pressure helium envisioned for the heat sink rings of the present design. Supplementary laser access would be provided for differential heating of the capsule for surface tension gradient stabilization of a liquid layer or bulk heating of a solid layer. The cryostat in each of these cases would look substantially the same as in the present case with the only significant differences being in the details of the design in the immediate vicinity of the target

A Liquid-Cryogen-Free Cryostat for Ultrahigh Resolution Gamma-Ray Spectrometers

International Nuclear Information System (INIS)

Dreyer, J.G.; Hertrich, T.; Drury, O.B.; Hohne, J.; Friedrich, S.

2008-01-01

We are developing ultra-high energy resolution gamma-ray detectors based on superconducting transition edge sensors (TESs) for nuclear non-proliferation and fundamental science applications. They use bulk tin absorbers attached to molybdenum-copper multilayer TESs, and have achieved an energy resolution between 50 and 90 eV FWHM for gamma-ray energies below 122 keV. For increased user-friendliness, we have built a cryostat that attains the required detector operating temperature of 0.1 K at the push of a button without the use of cryogenic liquids. It uses a two-stage mechanical pulse tube refrigerator for precooling to ∼3 K, and a two-stage adiabatic demagnetization refrigerator for cooling to the base temperature. The cryostat is fully automated, attains a base temperature below 30 mK without the use of cryogenic liquids, and has a hold time of ∼2 days at 0.1 K between 1-hour demagnetization cycles. Here we discuss the performance of the cryostat for operation in a Gamma-spectrometer with 112-pixel arrays of superconducting TES detectors

Cryostat with Foil and MLI

Energy Technology Data Exchange (ETDEWEB)

Hwang, Peter K.F.; Gung, Chen-yu

2005-10-06

Induction cores are used to accelerate heavy ion beam array, which are built around the outer diameter of the cryostat housing the superconducting quadruple array. Compact cryostat is highly desirable to reduce the cost of the induction cores. Recent experiences in fabrication of a cryostat for single beam transport revealed that it is possible to reduce the spacing in the cryostat vacuum jacket by using low-emissivity thermal insulation material instead of conventional MLI. However, it is labor-intensive to install the new type of insulation as compared with using MLI. It is promising to build a cost-effective compact cryostat for quadruple magnet array for heavy ion beam array transport by using low-emissivity material combined with conventional MLI as radiation insulation. A matrix of insulation designs and tests will be performed as the feasibility study and for the selection of the optimal thermal insulation as the Phase I work. The selected mixed insulation will be used to build prototype compact cryostats in the Phase II project, which are aiming for housing quadruple doublet array. In this STTR phase I study, a small cryostat has been designed and built to perform calorimetric characterization of the heat load in a liquid helium vessel insulated with a vacuum layer with a nominal clearance of 3.5 mm. The vacuum clearance resembled that used in the warm-bore beam tube region in a prototype cryostat previously built for the heavy ion beam transport experiment. The vacuum clearance was geometrically restricted with a heater shell with the temperature controlled at near 300 K. Various combinations of radiation and thermal shields were installed in the tight vacuum clearance for heat load measurements. The measured heat loads are reported and compared with previous test result using a compact vacuum layer. Further developments of the thermal insulations used in the present study are discussed. The compact cryostat with foil and MLI insulation may be used in the

Deep Cryogenic Low Power 24 Bits Analog to Digital Converter with Active Reverse Cryostat

Science.gov (United States)

Turqueti, Marcos; Prestemon, Soren; Albright, Robert

LBNL is developing an innovative data acquisition module for superconductive magnets where the front-end electronics and digitizer resides inside the cryostat. This electronic package allows conventional electronic technologies such as enhanced metal-oxide-semiconductor to work inside cryostats at temperatures as low as 4.2 K. This is achieved by careful management of heat inside the module that keeps the electronic envelop at approximately 85 K. This approach avoids all the difficulties that arise from changes in carrier mobility that occur in semiconductors at deep cryogenic temperatures. There are several advantages in utilizing this system. A significant reduction in electrical noise from signals captured inside the cryostat occurs due to the low temperature that the electronics is immersed in, reducing the thermal noise. The shorter distance that signals are transmitted before digitalization reduces pickup and cross-talk between channels. This improved performance in signal-to-noise rate by itself is a significant advantage. Another important advantage is the simplification of the feedthrough interface on the cryostat head. Data coming out of the cryostat is digital and serial, dramatically reducing the number of lines going through the cryostat feedthrough interface. It is important to notice that all lines coming out of the cryostat are digital and low voltage, reducing the possibility of electric breakdown inside the cryostat. This paper will explain in details the architecture and inner workings of this data acquisition system. It will also provide the performance of the analog to digital converter when the system is immersed in liquid helium, and in liquid nitrogen. Parameters such as power dissipation, integral non-linearity, effective number of bits, signal-to-noise and distortion, will be presented for both temperatures.

Mount makes liquid nitrogen-cooled gamma ray detector portable

Science.gov (United States)

Fessler, T. E.

1966-01-01

Liquid nitrogen-cooled gamma ray detector system is made portable by attaching the detector to a fixture which provides a good thermal conductive path between the detector and the liquid nitrogen in a dewar flask and a low heat leak path between the detector and the external environment.

PLC-controlled cryostats for the BlackGEM and MeerLICHT detectors

Science.gov (United States)

Raskin, Gert; Morren, Johan; Pessemier, Wim; Bloemen, Steven; Klein-Wolt, Marc; Roelfsema, Ronald; Groot, Paul; Aerts, Conny

2016-08-01

BlackGEM is an array of telescopes, currently under development at the Radboud University Nijmegen and at NOVA (Netherlands Research School for Astronomy). It targets the detection of the optical counterparts of gravitational waves. The first three BlackGEM telescopes are planned to be installed in 2018 at the La Silla observatory (Chile). A single prototype telescope, named MeerLICHT, will already be commissioned early 2017 in Sutherland (South Africa) to provide an optical complement for the MeerKAT radio array. The BlackGEM array consists of, initially, a set of three robotic 65-cm wide-field telescopes. Each telescope is equipped with a single STA1600 CCD detector with 10.5k x 10.5k 9-micron pixels that covers a 2.7 square degrees field of view. The cryostats for housing these detectors are developed and built at the KU Leuven University (Belgium). The operational model of BlackGEM requires long periods of reliable hands-off operation. Therefore, we designed the cryostats for long vacuum hold time and we make use of a closed-cycle cooling system, based on Polycold PCC Joule-Thomson coolers. A single programmable logic controller (PLC) controls the cryogenic systems of several BlackGEM telescopes simultaneously, resulting in a highly reliable, cost-efficient and maintenance-friendly system. PLC-based cryostat control offers some distinct advantages, especially for a robotic facility. Apart of temperature monitoring and control, the PLC also monitors the vacuum quality, the power supply and the status of the PCC coolers (compressor power consumption and temperature, pressure in the gas lines, etc.). Furthermore, it provides an alarming system and safe and reproducible procedures for automatic cool down and warm up. The communication between PLC and higher-level software takes place via the OPC-UA protocol, offering a simple to implement, yet very powerful interface. Finally, a touch-panel display on the PLC provides the operator with a user-friendly and robust

A compact sub-Kelvin ultrahigh vacuum scanning tunneling microscope with high energy resolution and high stability.

Science.gov (United States)

Zhang, L; Miyamachi, T; Tomanić, T; Dehm, R; Wulfhekel, W

2011-10-01

We designed a scanning tunneling microscope working at sub-Kelvin temperatures in ultrahigh vacuum (UHV) in order to study the magnetic properties on the nanoscale. An entirely homebuilt three-stage cryostat is used to cool down the microscope head. The first stage is cooled with liquid nitrogen, the second stage with liquid (4)He. The third stage uses a closed-cycle Joule-Thomson refrigerator of a cooling power of 1 mW. A base temperature of 930 mK at the microscope head was achieved using expansion of (4)He, which can be reduced to ≈400 mK when using (3)He. The cryostat has a low liquid helium consumption of only 38 ml/h and standing times of up to 280 h. The fast cooling down of the samples (3 h) guarantees high sample throughput. Test experiments with a superconducting tip show a high energy resolution of 0.3 meV when performing scanning tunneling spectroscopy. The vertical stability of the tunnel junction is well below 1 pm (peak to peak) and the electric noise floor of tunneling current is about 6fA/√Hz. Atomic resolution with a tunneling current of 1 pA and 1 mV was achieved on Au(111). The lateral drift of the microscope at stable temperature is below 20 pm/h. A superconducting spilt-coil magnet allows to apply an out-of-plane magnetic field of up to 3 T at the sample surface. The flux vortices of a Nb(110) sample were clearly resolved in a map of differential conductance at 1.1 K and a magnetic field of 0.21 T. The setup is designed for in situ preparation of tip and samples under UHV condition.

The New Superfluid Helium Cryostats for the Short Straight Sections of the CERN Large Hadron Collider (LHC)

CERN Document Server

Cameron, W; Kurtyka, T; Parma, Vittorio; Renaglia, T; Rifflet, J M; Rohmig, P; Skoczen, Blazej; Tortschanoff, Theodor; Trilhe, P; Védrine, P; Vincent, D

1998-01-01

The lattice of the CERN Large Hadron Collider (LHC) contains 364 Short Straight Section (SSS) units, one in every 53 m long half-cell. An SSS consists of three major assemblies: the standard cryostat section, the cryogenic service module, and the jumper connection. The standard cryostat section of an SSS contains the twin aperture high-gradient superconducting quadrupole and two pairs of superconducting corrector magnets, operating in pressurized helium II at 1.9 K. Components for isolating cryostat insulation vacuum, and the cryogenic supply lines, have to be foreseen. Special emphasis is given to the design changes of the SSS following adoption of an external cryogenic supply line (QRL). A jumper connection connects the SSS to the QRL, linking all the cryogenic tubes necessary for the local full-cell cooling loop [at every second SSS]. The jumper is connected to one end of the standard cryostat section via the cryogenic service module, which also houses beam diagnostics, current feedthroughs, and instrument...

Dependence of the residual surface resistance of superconducting radio frequency cavities on the cooling dynamics around T{sub c}

Energy Technology Data Exchange (ETDEWEB)

Romanenko, A., E-mail: aroman@fnal.gov; Grassellino, A., E-mail: annag@fnal.gov; Melnychuk, O.; Sergatskov, D. A. [Fermi National Accelerator Laboratory, Batavia, Illinois 60510 (United States)

2014-05-14

We report a strong effect of the cooling dynamics through T{sub c} on the amount of trapped external magnetic flux in superconducting niobium cavities. The effect is similar for fine grain and single crystal niobium and all surface treatments including electropolishing with and without 120 °C baking and nitrogen doping. Direct magnetic field measurements on the cavity walls show that the effect stems from changes in the flux trapping efficiency: slow cooling leads to almost complete flux trapping and higher residual resistance, while fast cooling leads to the much more efficient flux expulsion and lower residual resistance.

Liquid nitrogen-cooled diamond-wire concrete cutting. Innovative technology summary report

International Nuclear Information System (INIS)

1998-12-01

Liquid nitrogen-cooled diamond-wire concrete cutting can be used to cut through thick concrete walls, floors, and structures without using water to cool the cutting wire. The diamond wire is cooled with liquid nitrogen in a 0.9-m (3-ft) long by 7.6-cm (3-in.) diameter pipe housing. The nitrogen evaporates, so no contaminated liquid waste is generated. Other than the use of liquid nitrogen, the system is a conventional diamond-wire saw assembly with remote hydraulic controls. Setup of the hydraulic-powered drive wheel and the diamond wire for cutting requires a relatively short period of time using people with minimal training. Concrete dust generated during the cutting is considerable and requires control. The production rate of this improved technology is 0.78 m 2 /hr (8.4 ft 2 /hr). The production rates of traditional (baseline) water-cooled diamond-wire cutting and circular saw cutting technologies are 1.11 m 2 /hr (12 ft 2 /hr), and 0.45 m 2 /hr (4.8 ft 2 /hr), respectively. The liquid nitrogen-cooled system costs 189% more than conventional diamond-wire cutting if contaminated liquid wastes collection, treatment, and disposal are not accounted for with the baseline. The new technology was 310% more costly than a conventional diamond circular saw, under the conditions of this demonstration (no wastewater control). For cutting a 0.9-m x 3.7-m (3-ft x 12-ft) wall, the improved technology costs $17,000, while baseline diamond-wire cutting would cost $9,000 and baseline circular-saw cutting would cost $5,500. The improved system may cost less than the baseline technologies or may be comparable in cost if wastewater control is included

Liquid nitrogen-cooled diamond-wire concrete cutting. Innovative technology summary report

Energy Technology Data Exchange (ETDEWEB)

NONE

1998-12-01

Liquid nitrogen-cooled diamond-wire concrete cutting can be used to cut through thick concrete walls, floors, and structures without using water to cool the cutting wire. The diamond wire is cooled with liquid nitrogen in a 0.9-m (3-ft) long by 7.6-cm (3-in.) diameter pipe housing. The nitrogen evaporates, so no contaminated liquid waste is generated. Other than the use of liquid nitrogen, the system is a conventional diamond-wire saw assembly with remote hydraulic controls. Setup of the hydraulic-powered drive wheel and the diamond wire for cutting requires a relatively short period of time using people with minimal training. Concrete dust generated during the cutting is considerable and requires control. The production rate of this improved technology is 0.78 m{sup 2}/hr (8.4 ft{sup 2}/hr). The production rates of traditional (baseline) water-cooled diamond-wire cutting and circular saw cutting technologies are 1.11 m{sup 2}/hr (12 ft{sup 2}/hr), and 0.45 m{sup 2}/hr (4.8 ft{sup 2}/hr), respectively. The liquid nitrogen-cooled system costs 189% more than conventional diamond-wire cutting if contaminated liquid wastes collection, treatment, and disposal are not accounted for with the baseline. The new technology was 310% more costly than a conventional diamond circular saw, under the conditions of this demonstration (no wastewater control). For cutting a 0.9-m x 3.7-m (3-ft x 12-ft) wall, the improved technology costs $17,000, while baseline diamond-wire cutting would cost $9,000 and baseline circular-saw cutting would cost $5,500. The improved system may cost less than the baseline technologies or may be comparable in cost if wastewater control is included.

Conceptual study of the cryostats for the cold powering system for the triplets of the High Luminosity LHC

Science.gov (United States)

Ballarino, A.; Giannelli, S.; Jacquemod, A.; Leclercq, Y.; Ortiz Ferrer, C.; Parma, V.

2017-12-01

The High Luminosity LHC (HL-LHC) is a project aiming to upgrade the Large Hadron Collider (LHC) after 2020-2025 in order to increase the integrated luminosity by about one order of magnitude and extend the operational capabilities until 2035. The upgrade of the focusing triplet insertions for the Atlas and CMS experiments foresees using superconducting magnets operating in a pressurised superfluid helium bath at 1.9 K. The increased radiation levels from the particle debris produced by particle collisions in the experiments require that the power converters are placed in radiation shielded zones located in a service gallery adjacent to the main tunnel. The powering of the magnets from the gallery is achieved by means of MgB2 superconducting cables in a 100-m long flexible cryostat transfer line, actively cooled by 4.5 K to 20 K gaseous helium generated close to the magnets. At the highest temperature end, the helium flow cools the High Temperature Superconducting (HTS) current leads before being recovered at room temperature. At the magnet connection side, a dedicated connection box allows connection to the magnets and a controlled boil-off production of helium for the cooling needs of the powering system. This paper presents the overall concept of the cryostat system from the magnet connection boxes, through the flexible cryostat transfer line, to the connection box of the current leads.

Electroluminescence in quantum well heterostructures p-Al{sub x}Ga{sub 1-x}As/GaAs{sub 1-y}P{sub y}/n-Al{sub x}Ga{sub 1-x}As under uniaxial stress

Energy Technology Data Exchange (ETDEWEB)

Berman, Irina V. [Physics Department, San Jose State University, CA (United States); Bogdanov, Evgeniy V.; Minina, Natalia Ya.; Shirokov, Stanislav S.; Yunovich, Alexander E. [Physics Department, Lomonosov Moscow State University (Russian Federation); Kissel, Heiko [R and D Department, DILAS Diodenlaser GmbH, (Germany)

2009-03-15

We present new results on the influence of uniaxial stress up to P=4 kbar on the electroluminescence spectra and current-voltage characteristics of p-Al{sub x}Ga{sub 1-x}As/GaAs{sub 1-y}P{sub y}/n-Al{sub x}Ga{sub 1-x}As double heterostructures usually used in TM emitting 808 nm high-power diode lasers. With increasing stress, the emission spectra demonstrate a blue shift of up to 25 meV at a pressure of P=4 kbar, while the electroluminescence intensity increases under compression. The different behavior of the current-voltage characteristics under uniaxial stress along[110] and[1 anti 10] directions is mainly determined by the arising piezoelectric field. The results are also discussed in terms of changes in the band structure under uniaxial compression. The construction of the cryostat for optical measurements under uniaxial stress at liquid nitrogen temperature is described in the paper. (copyright 2009 WILEY-VCH Verlag GmbH and Co. KGaA, Weinheim) (orig.)

Development, setup, and test of a new cryostat module for the S-DALINAC; Entwicklung, Aufbau und Test eines neuen Kryostatmoduls fuer den S-DALINAC

Energy Technology Data Exchange (ETDEWEB)

Kuerzeder, Thorsten

2013-07-01

superconducting cavities. For the first time, this will allow the achievement of an intrinsic quality factor Q{sub 0} of 3 . 10{sup 9} for the superconducting cavities at the S-DALINAC, if state-of-the-art preparation techniques are used. Three new 20-cell cavities were built to meet the increased requirements for the new accelerator module. Instead of fabricating these structures from single cells, state-of-the-art techniques using dumbbells were applied in order to provide an optimal treatment of the 20-cell cavities. Prior to the production, simulations and measurements were carried out during the course of the present work, such that all three cavities were successfully tuned to the right frequency and field flatness at the correct length. For an offline test the cryostat module was equipped with one cavity and cooled down. Tests at 2 K and 4 K demonstrated leak tightness of the various pressure stages and the thermal losses of 5-6 W to the helium vessel were also within requirements. Finally, the external quality factor Q{sub ex} of the new RF input coupler was measured to be 6.25 . 10{sup 6}, thus almost matching the desired design value of 5.10{sup 6}. After these successful tests the new module is ready to be installed at the injector of the S-DALINAC. Equipped with two of the three new cavities it will replace the current module, which, in turn, will serve as a spare for the main accelerator of the S-DALINAC, thus reducing maintenance periods in future.

Conceptual design of JT-60SA cryostat

International Nuclear Information System (INIS)

Shibama, Y.K.; Sakurai, S.; Masaki, K.; Sukekawa, A.M.; Kaminaga, A.; Sakasai, A.; Matsukawa, M.

2008-01-01

This paper describes the conceptual design of cryostat for the JT-60SA, which is a research device for the commercial production of electricity from the controlled fusion reaction in the future. JT-60SA is designed to be a fully superconducting device and cryostat is one of the main components to allow the normal operation. Cryostat covers up the tokamak device, which is 15 m of total height and 7 m of radius, and supports the total weight of 25 MN. Cryostat components consist of vessel body, gravity support and auxiliary systems, such as 80 K thermal shield and vacuum exhaust. The functions required of cryostat are these three, thermal insulation for superconducting magnets, gravity support for the tokamak device, and bio-shielding. The design conditions for each cryostat component are outlined and the features of auxiliary systems such as capacity of vacuum exhaust related to 80 K thermal shield design are summarized

Nitrogen And Oxygen Amount In Weld After Welding With Micro-Jet Cooling

Directory of Open Access Journals (Sweden)

Węgrzyn T.

2015-06-01

Full Text Available Micro-jet cooling after welding was tested only for MIG welding process with argon, helium and nitrogen as a shielded gases. A paper presents a piece of information about nitrogen and oxygen in weld after micro-jet cooling. There are put down information about gases that could be chosen both for MIG/MAG welding and for micro-jet process. There were given main information about influence of various micro-jet gases on metallographic structure of steel welds. Mechanical properties of weld was presented in terms of nitrogen and oxygen amount in WMD (weld metal deposit.

Does One Need a 4.5 K Screen in Cryostats of Superconducting Accelerator Devices Operating in Superfluid Helium? Lessons from the LHC

CERN Document Server

Lebrun, Ph; Tavian, L

2014-01-01

Superfluid helium is increasingly used as a coolant for superconducting devices in particle accelerators: the lower temperature enhances the performance of superconductors in high-field magnets and reduces BCS losses in RF acceleration cavities, while the excellent transport properties of superfluid helium can be put to work in efficient distributed cooling systems. The thermodynamic penalty of operating at lower temperature however requires careful management of the heat loads, achieved inter alia through proper design and construction of the cryostats. A recurrent question appears to be that of the need and practical feasibility of an additional screen cooled by normal helium at around 4.5 K surrounding the cold mass at about 2 K, in such cryostats equipped with a standard 80 K screen. We introduce the issue in terms of first principles applied to the configuration of the cryostats, discuss technical constraints and economical limitations, and illustrate the argumentation with examples taken from large proj...

Conceptual design and structural analysis of the CFETR cryostat

Energy Technology Data Exchange (ETDEWEB)

Wang, Zhen, E-mail: wangzhen@ipp.ac.cn; Yang, Qingxi; Xu, Hao

2015-04-15

Highlights: • The CFETR cryostat is a large vacuum container surrounding the tokamak basic machine. • Two conceptual design schemes of CFETR cryostat were proposed. • A series of structural analyses were performed for cryostat cylinder. • The design of base section is feasible for cryostat. - Abstract: CFETR (China Fusion Engineering Test Reactor) is a new tokamak device, one important component of which is cryostat and it is now under designing by China national integration design group. The CFETR cryostat is a large single-wall vacuum-tight container surrounding the tokamak basic machine, which consists of top dome-shape lid, two cylindrical sections with circumferential stiffening ribs and bottom flat head. It shall provide a vacuum environment (10{sup −4} Pa) for the operation of the superconducting coils and all the loads that derive from cryostat itself and inner components should be transferred to the floor of tokamak pit. In this paper, two schemes of cryostat were proposed and then the structural analyses including seismic response analysis, elastic stress analysis and buckling analysis were performed to validate the conceptual design of CFETR cryostat. Based on the analysis results, it can be inferred that the cryostat II has a higher stiffness and stability. The structure of cryostat I needs to be improved against buckling and it is more difficult to manufacture for cryostat II due to its complex curved surface compared with cryostat I. Finally, the structural analysis for base section was performed and the design of main support was proved to be feasible. The design of CFETR cryostat has not been finalized and structural optimization still need to be proceeded based on the analysis results.

Conceptual design and structural analysis of the CFETR cryostat

International Nuclear Information System (INIS)

Wang, Zhen; Yang, Qingxi; Xu, Hao

2015-01-01

Highlights: • The CFETR cryostat is a large vacuum container surrounding the tokamak basic machine. • Two conceptual design schemes of CFETR cryostat were proposed. • A series of structural analyses were performed for cryostat cylinder. • The design of base section is feasible for cryostat. - Abstract: CFETR (China Fusion Engineering Test Reactor) is a new tokamak device, one important component of which is cryostat and it is now under designing by China national integration design group. The CFETR cryostat is a large single-wall vacuum-tight container surrounding the tokamak basic machine, which consists of top dome-shape lid, two cylindrical sections with circumferential stiffening ribs and bottom flat head. It shall provide a vacuum environment (10 −4 Pa) for the operation of the superconducting coils and all the loads that derive from cryostat itself and inner components should be transferred to the floor of tokamak pit. In this paper, two schemes of cryostat were proposed and then the structural analyses including seismic response analysis, elastic stress analysis and buckling analysis were performed to validate the conceptual design of CFETR cryostat. Based on the analysis results, it can be inferred that the cryostat II has a higher stiffness and stability. The structure of cryostat I needs to be improved against buckling and it is more difficult to manufacture for cryostat II due to its complex curved surface compared with cryostat I. Finally, the structural analysis for base section was performed and the design of main support was proved to be feasible. The design of CFETR cryostat has not been finalized and structural optimization still need to be proceeded based on the analysis results

LHC IRQ cryostat support mechanical performance

International Nuclear Information System (INIS)

Darve, C.; Nicol, T.; Knauf, A.

1999-01-01

The LHC Interaction Region Quadrupoles (IRQ) will be shipped from Fermilab to CERN. The IRQ magnets are supported by glass fiber supports. A prototype cryostat support has been tested under various mechanical forces in order to check its mechanical behavior. These measurements have been made in order to validate a numerical model. A large range of mechanical loads simulates loads due to the shipment of the device, the weight of the cold mass as well as the cool down conditions. Its mechanical properties are measured by means of a dedicated arrangement operating at room temperature. This study appears to be essential to optimize the design of the support. The purpose of this note is to summarize the first measurements related to mechanical tests performed with the support

Sub-Doppler cooling in reduced-period optical lattice geometries

International Nuclear Information System (INIS)

Berman, P.R.; Raithel, G.; Zhang, R.; Malinovsky, V.S.

2005-01-01

It is shown that sub-Doppler cooling occurs in an atom-field geometry that can lead to reduced-period optical lattices. Four optical fields are combined to produce a 'standing wave' Raman field that drives transitions between two ground state sublevels. In contrast to conventional Sisyphus cooling, sub-Doppler cooling to zero velocity occurs when all fields are polarized in the same direction. Solutions are obtained using both semiclassical and quantum Monte Carlo methods in the case of exact two-photon resonance. The connection of the results with conventional Sisyphus cooling is established using a dressed state basis

Insertion of the first half-barrel of the ATLAS electromagnetic calorimeter into its cryostat

CERN Multimedia

Maximilien Brice

2003-01-01

The first cylinder of the ATLAS electromagnetic calorimeter barrel and the presampler have been inserted in the cryostat.The ATLAS electromagnetic calorimeter is intended to detect electrons, positrons and photons by measuring the energy they deposit on being absorbed. The cylinder of the calorimeter is in two halves, that will be sunk in a liquid-argon bath cooled to 90 kelvin (-180°C). Each half-barrel is 3.2 metres long, 53 cm thick and formed by assembling 16 modules. Each module is made up of alternate lead absorbers and electrodes pressed into 64 layers folded accordion-fashion. The presampler, set up inside the cylinder, is an integral part of the calorimeter system: It measures the energy lost by a particle before it reaches the calorimeter. To ensure an ultra-clean environment, a tent (visible here) was erected round the calorimeter and entry point to the cryostat. The detector and presampler, fitted together, could then be slid gradually into the cryostat like a drawer. To do so, the insertion team...

Insertion of the first half-barrel of the ATLAS electromagnetic calorimeter into its cryostat

CERN Multimedia

Maximilien Brice

2003-01-01

The first cylinder of the ATLAS electromagnetic calorimeter barrel and the presampler have been inserted in the cryostat. The ATLAS electromagnetic calorimeter is intended to detect electrons, positrons and photons by measuring the energy they deposit on being absorbed. The cylinder of the calorimeter is in two halves, that will be sunk in a liquid-argon bath cooled to 90 kelvin (-180°C). Each half-barrel is 3.2 metres long, 53 cm thick and formed by assembling 16 modules. Each module is made up of alternate lead absorbers and electrodes pressed into 64 layers folded accordion-fashion. The presampler, set up inside the cylinder, is an integral part of the calorimeter system: It measures the energy lost by a particle before it reaches the calorimeter. To ensure an ultra-clean environment, a tent was erected round the calorimeter and entry point to the cryostat. The detector and presampler, fitted together, could then be slid gradually into the cryostat like a drawer. To do so, the insertion team had to fine-t...

Polymerization, shock cooling and ionization of liquid nitrogen

International Nuclear Information System (INIS)

Ross, M; Rogers, F

2005-01-01

The trajectory of thermodynamic states passed through by the nitrogen Hugoniot starting from the liquid and up to 10 6 GPa has been studied. An earlier report of cooling in the doubly shocked liquid, near 50 to 100 GPa and 7500 K, is revisited in light of the recent discovery of solid polymeric nitrogen. It is found that cooling occurs when the doubly shocked liquid is driven into a volume near the molecular to polymer transition and raising the possibility of a liquid-liquid phase transition (LLPT). By increasing the shock pressure and temperature by an order of magnitude, theoretical calculations predict thermal ionization of the L shell drives the compression maxima to 5-6 fold compression at 10 Mbar (T ∼ 3.5 10 5 K) and at 400 Mbar (T ∼ 2.3 10 6 K) from K shell ionization. Near a pressure of 10 6 GPa the K shell ionizes completely and the Hugoniot approaches the classical ideal gas compression fourfold limit

Liquid Argon Barrel Cryostat Arrived

CERN Multimedia

Pailler, P

Last week the first of three cryostats for the ATLAS liquid argon calorimeter arrived at CERN. It had travelled for 46 days over several thousand kilometers from Japan to CERN. During three years it has been fabricated by Kawasaki Heavy Industries Ltd. at Harima, close to Kobe, under contract from Brookhaven National Laboratory (BNL) of the U.S.. This cryostat consists of two concentric cylinders made of aluminium: the outer vacuum vessel with a diameter of 5.5 m and a length of 7 m, and the inner cold vessel which will contain the electromagnetic barrel calorimeter immersed in liquid argon. The total weight will be 270 tons including the detectors and the liquid argon. The cryostat is now located in building 180 where it will be equipped with 64 feed-throughs which serve for the passage of 122,880 electrical lines which will carry the signals of the calorimeter. After integration of the calorimeter, the solenoidal magnet of ATLAS will be integrated in the vacuum vessel. A final cold test of the cryostat inc...

Thermodynamic Factors Affecting UC<sub>1-xsub>N_{x>Irradiation and Synthesis}

Energy Technology Data Exchange (ETDEWEB)

Lindemer, T.B.

2005-04-22

There is interest in attempting to synthesize nearly pure uranium nitride (UN) kernels for high-temperature gas-cooled reactor (HTGR) fuel. Because the proposed process involves carbothermic conversion of a urania-carbon mixture in nitrogen and because there is a complete ideal solution of uranium carbide (UC) and UN, which is written as UC{sub 1-x}N{sub x}, the practical value of x for fuel irradiation needs to be determined. Insight is to be gained by relevant thermodynamic calculations of carbide-nitride equilibria for the fuel and fission product systems. The equilibria are readily compared on the nitrogen-based Ellingham diagram, which, in turn, provides guidance in interpreting past irradiations and in synthesis of the UC{sub 1-x}N{sub x} kernels.

Performance of the Conduction-Cooled LDX Levitation Coil

Science.gov (United States)

Michael, P. C.; Schultz, J. H.; Smith, B. A.; Titus, P. H.; Radovinsky, A.; Zhukovsky, A.; Hwang, K. P.; Naumovich, G. J.; Camille, R. J.

2004-06-01

The Levitated Dipole Experiment (LDX) was developed to study plasma confinement in a dipole magnetic field. Plasma is confined in the magnetic field of a 680-kg Nb3Sn Floating Coil (F-coil) that is electromagnetically supported at the center of a 5-m diameter by 3-m tall vacuum chamber. The Levitation Coil (L-coil) is a 2800-turn, double pancake winding that supports the weight of the F-coil and controls its vertical position within the vacuum chamber. The use of high-temperature superconductor (HTS) Bi-2223 for the L-coil minimizes the electrical and cooling power needed for levitation. The L-coil winding pack and support plate are suspended within the L-coil cryostat and cooled by conduction to a single-stage cryocooler rated for 25-W heat load at approximately 20 K. The coil current leads consist of conduction-cooled copper running from room temperature to 80 K and a pair of commercially-available, 150-A HTS leads. An automatically filled liquid-nitrogen reservoir provides cooling for the coil's radiation shield and for the leads' 80-K heat stations. This paper discusses the L-coil system design and its observed cryogenic performance.

Nitrogen And Oxygen Amount In Weld After Welding With Micro-Jet Cooling

OpenAIRE

Węgrzyn T.; Piwnik J.

2015-01-01

Micro-jet cooling after welding was tested only for MIG welding process with argon, helium and nitrogen as a shielded gases. A paper presents a piece of information about nitrogen and oxygen in weld after micro-jet cooling. There are put down information about gases that could be chosen both for MIG/MAG welding and for micro-jet process. There were given main information about influence of various micro-jet gases on metallographic structure of steel welds. Mechanical properties of weld was pr...

Sub-Doppler laser cooling of potassium atoms

Energy Technology Data Exchange (ETDEWEB)

Landini, M. [LENS and Dipartimento di Fisica e Astronomia, Universita di Firenze, I-50019 Sesto Fiorentino (Italy); INFN, Sezione di Firenze, I-50019 Sesto Fiorentino (Italy); Dipartimento di fisica, Universita di Trento, I-38123 Povo (Trento) (Italy); Roy, S.; Carcagni, L.; Trypogeorgos, D. [LENS and Dipartimento di Fisica e Astronomia, Universita di Firenze, I-50019 Sesto Fiorentino (Italy); Fattori, M.; Inguscio, M.; Modugno, G. [LENS and Dipartimento di Fisica e Astronomia, Universita di Firenze, I-50019 Sesto Fiorentino (Italy); INFN, Sezione di Firenze, I-50019 Sesto Fiorentino (Italy)

2011-10-15

We investigate the sub-Doppler laser cooling of bosonic potassium isotopes, whose small hyperfine splitting has so far prevented cooling below the Doppler temperature. We find instead that the combination of a dark optical molasses scheme that naturally arises in this kind of system and an adiabatic ramping of the laser parameters allows us to reach sub-Doppler temperatures for small laser detunings. We demonstrate temperatures as low as 25{+-}3 {mu}K and 47{+-}5 {mu}K in high-density samples of the two isotopes {sup 39}K and {sup 41}K, respectively. Our findings should find application to other atomic systems.

Sub-Doppler laser cooling of potassium atoms

International Nuclear Information System (INIS)

Landini, M.; Roy, S.; Carcagni, L.; Trypogeorgos, D.; Fattori, M.; Inguscio, M.; Modugno, G.

2011-01-01

We investigate the sub-Doppler laser cooling of bosonic potassium isotopes, whose small hyperfine splitting has so far prevented cooling below the Doppler temperature. We find instead that the combination of a dark optical molasses scheme that naturally arises in this kind of system and an adiabatic ramping of the laser parameters allows us to reach sub-Doppler temperatures for small laser detunings. We demonstrate temperatures as low as 25±3 μK and 47±5 μK in high-density samples of the two isotopes 39 K and 41 K, respectively. Our findings should find application to other atomic systems.

Influence of the post-annealing cooling rate on the superconducting and mechanical properties of LFZ textured Bi-2212 rods

CERN Document Server

Natividad, E; Angurel, L A; Salazar, A; Pastor, J Y; Llorca, J

2002-01-01

Laser floating zone textured Bi sub 2 Sr sub 2 CaCu sub 2 O sub 8 sub + subdelta (Bi-2212) thin rods were manufactured and subjected to a two-step annealing process at 870 deg C and 801 deg C in air. It was found that the subsequent cooling process led to marked changes in electrical properties. Three cooling rates were tested: (i) quenching in liquid nitrogen, (ii) cooling in air inside an alumina tube and (iii) cooling inside the furnace. The results showed that the faster the cooling rate, the higher the normal state resistivity. The T sub c distribution across the rods was also affected by the cooling rate, but no large differences were observed in the magnitude of the critical current at 77 K since the homogeneity of furnace-cooled samples compensated for the higher outer J sub c values of fast-cooled ones. The mechanical properties (elastic modulus and flexure strength) were not influenced by the cooling rate, but the samples quenched in liquid nitrogen were often cracked by thermal shock. The elastic m...

Combination closed-cycle refrigerator/liquid-He4 cryostat for e- damage of bulk samples

International Nuclear Information System (INIS)

Johnson, E.C.

1987-01-01

A closed-cycle refrigerator/cryostat system for use in ultrasonic studies of electron irradiation damaged bulk specimens is described. The closed-cycle refrigerator provides a convenient means for long-term (several days) sample irradiation at low temperatures. A neon filled ''thermal diode'' is employed to permit efficient cooling, via liquid helium, of the sample below the base temperature of the refrigerator

Does one need a 4.5 K screen in cryostats of superconducting accelerator devices operating in superfluid helium? lessons from the LHL

Science.gov (United States)

Lebrun, Philippe; Parma, Vittorio; Tavian, Laurent

2014-01-01

Superfluid helium is increasingly used as a coolant for superconducting devices in particle accelerators: the lower temperature enhances the performance of superconductors in high-field magnets and reduces BCS losses in RF acceleration cavities, while the excellent transport properties of superfluid helium can be put to work in efficient distributed cooling systems. The thermodynamic penalty of operating at lower temperature however requires careful management of the heat loads, achieved inter alia through proper design and construction of the cryostats. A recurrent question appears to be that of the need and practical feasibility of an additional screen cooled by normal helium at around 4.5 K surrounding the cold mass at about 2 K, in such cryostats equipped with a standard 80 K screen. We introduce the issue in terms of first principles applied to the configuration of the cryostats, discuss technical constraints and economical limitations, and illustrate the argumentation with examples taken from large projects confronted with this issue, i.e. CEBAF, SPL, ESS, LHC, TESLA, European X-FEL, ILC.

influence of sub-cooling on the energy performance of two eco

African Journals Online (AJOL)

PUBLICATIONS1

frigerants, consistently exhibited better performance than R22 in sub-cooling heat ... 2014 Kwame Nkrumah University of Science and Technology (KNUST) ... sales volume among all refrigerants. .... The sub-cooling heat exchanger affects the.

Experimental study of nitrogen oxide absorption by a liquid nitrogen tetroxide flow

Energy Technology Data Exchange (ETDEWEB)

Verzhinskaya, A B; Saskovets, V V; Borovik, T F

1984-01-01

The system of N/sub 2/O/sub 4/ based coolant regeneration needs productive and efficient absorbers, providing effective production of nitrogen oxide, decreasing upon NPP operation at the expense of radiation-thermal decomposition. The experimental istallation flowsheet for studying the nitrogen oxide absorbtion by liquid nitrogen tetroxide is given. The experiments have been carried out in removable test sections, looked like helical tubes with internal steam-and-liquid mixture flow and external water cooling. Six test sections with variable geometry factors have been manufactured. The plotted results of the experiments are given as dependences of extraction level and mass transfer volumetric coefficients on the geometry factor, pressure and Froude number.

Autometallographic silver enhancement of zinc sulfide crystals created in cryostat sections from human brain biopsies

DEFF Research Database (Denmark)

Danscher, G; Juhl, S; Stoltenberg, M

1997-01-01

samples containing zinc-enriched (ZEN) cells, are frozen in liquid nitrogen or by CO2 gas immediately after removal. The tissue blocks are cut in a cryostat and the sections placed on glass slides. The slides are transferred to an H2S exposure chamber placed in a -15 C freezer. After 1-24 hr of gas...

Cooling rate dependence of simulated Cu{sub 64.5}Zr{sub 35.5} metallic glass structure

Energy Technology Data Exchange (ETDEWEB)

Ryltsev, R. E. [Institute of Metallurgy, Ural Branch of Russian Academy of Sciences, 101 Amundsen Str., 620016 Ekaterinburg (Russian Federation); Ural Federal University, 19 Mira Str., 620002 Ekaterinburg (Russian Federation); L.D. Landau Institute for Theoretical Physics, Russian Academy of Sciences, 2 Kosygina Str., 119334 Moscow (Russian Federation); Klumov, B. A. [L.D. Landau Institute for Theoretical Physics, Russian Academy of Sciences, 2 Kosygina Str., 119334 Moscow (Russian Federation); Aix-Marseille-Université, CNRS, Laboratoire PIIM, UMR 7345, 13397 Marseille Cedex 20 (France); High Temperature Institute, Russian Academy of Sciences, 13/2 Izhorskaya Str., 125412 Moscow (Russian Federation); Chtchelkatchev, N. M. [Institute of Metallurgy, Ural Branch of Russian Academy of Sciences, 101 Amundsen Str., 620016 Ekaterinburg (Russian Federation); L.D. Landau Institute for Theoretical Physics, Russian Academy of Sciences, 2 Kosygina Str., 119334 Moscow (Russian Federation); Moscow Institute of Physics and Technology, 9 Institutskiy Per., Dolgoprudny, 141700 Moscow Region (Russian Federation); All-Russia Research Institute of Automatics, 22 Sushchevskaya, 127055 Moscow (Russian Federation); Shunyaev, K. Yu. [Institute of Metallurgy, Ural Branch of Russian Academy of Sciences, 101 Amundsen Str., 620016 Ekaterinburg (Russian Federation); Ural Federal University, 19 Mira Str., 620002 Ekaterinburg (Russian Federation)

2016-07-21

Using molecular dynamics simulations with embedded atom model potential, we study structural evolution of Cu{sub 64.5}Zr{sub 35.5} alloy during the cooling in a wide range of cooling rates γ ∈ (1.5 ⋅ 10{sup 9}, 10{sup 13}) K/s. Investigating short- and medium-range orders, we show that the structure of Cu{sub 64.5}Zr{sub 35.5} metallic glass essentially depends on cooling rate. In particular, a decrease of the cooling rate leads to an increase of abundances of both the icosahedral-like clusters and Frank-Kasper Z16 polyhedra. The amounts of these clusters in the glassy state drastically increase at the γ{sub min} = 1.5 ⋅ 10{sup 9} K/s. Analysing the structure of the glass at γ{sub min}, we observe the formation of nano-sized crystalline grain of Cu{sub 2}Zr intermetallic compound with the structure of Cu{sub 2}Mg Laves phase. The structure of this compound is isomorphous with that for Cu{sub 5}Zr intermetallic compound. Both crystal lattices consist of two types of clusters: Cu-centered 13-atom icosahedral-like cluster and Zr-centered 17-atom Frank-Kasper polyhedron Z16. That suggests the same structural motifs for the metallic glass and intermetallic compounds of Cu–Zr system and explains the drastic increase of the abundances of these clusters observed at γ{sub min}.

Cryostat

International Nuclear Information System (INIS)

Sasaki, Takashi; Fujita, Jun-ya.

1998-01-01

The present invention provides a rational structural member of a cryostat of a thermonuclear reactor or a thermonuclear device. Namely, the cryostat comprises a cylindrical body structural member and a lid structural member covering the upper end opening thereof. The lid structural member comprises (1) a lid bottom plate for vacuum sealing, comprising a flat board mounted substantially horizontally to the upper end opening of the body structural member, (2) lid reinforcing ribs comprising linear beams mounted integrally to the surface of the lid bottom plate and (3) neutron shielding concretes disposed on the surface of the lid bottom plate. With such a constitution, curving fabrication of the lid bottom plate and bending fabrication for the lid reinforcing ribs which have been conducted in an existent construction method are made unnecessary. In addition, an outer lid plate (lid top plate) which has been required for a lid structural member of an existent plate-type structure is also made unnecessary. As a result, the number of structural parts can be reduced, the structure can be simplified and the number of construction steps can be reduced. (I.S.)

Polymerization, shock cooling and ionization of liquid nitrogen

Energy Technology Data Exchange (ETDEWEB)

Ross, M; Rogers, F

2005-07-21

The trajectory of thermodynamic states passed through by the nitrogen Hugoniot starting from the liquid and up to 10{sup 6} GPa has been studied. An earlier report of cooling in the doubly shocked liquid, near 50 to 100 GPa and 7500 K, is revisited in light of the recent discovery of solid polymeric nitrogen. It is found that cooling occurs when the doubly shocked liquid is driven into a volume near the molecular to polymer transition and raising the possibility of a liquid-liquid phase transition (LLPT). By increasing the shock pressure and temperature by an order of magnitude, theoretical calculations predict thermal ionization of the L shell drives the compression maxima to 5-6 fold compression at 10 Mbar (T {approx} 3.5 10{sup 5} K) and at 400 Mbar (T {approx} 2.3 10{sup 6} K) from K shell ionization. Near a pressure of 10{sup 6} GPa the K shell ionizes completely and the Hugoniot approaches the classical ideal gas compression fourfold limit.

Development of liquid nitrogen Centrifugal Pump

International Nuclear Information System (INIS)

Abe, M; Sagiyama, R; Tsuchiya, H; Takayama, T; Torii, Y; Nakamura, M; Hoshino, Y; Odashima, Y

2009-01-01

Usually liquid nitrogen (LN 2 ) transfer from a container to a laboratory equipment takes place by applying pressure to the container to push out liquid or pouring liquid into the cryostat directly by lifting the container. In order to overcome inconvenience of pressuring or lifting containers, we have been developing the Liquid Nitrogen Centrifugal Pump of a small electric turbine pump. Significant advantages that both reducing time to fill LN 2 and controlling the flow rate of liquid into the cryostat are obtained by introducing this pump. We have achieved the lift of about 800mm with the vessel's opening diameter of 28mm.

The design of the new LHC connection cryostats

Science.gov (United States)

Vande Craen, A.; Barlow, G.; Eymin, C.; Moretti, M.; Parma, V.; Ramos, D.

2017-12-01

In the frame of the High Luminosity upgrade of the LHC, improved collimation schemes are needed to cope with the superconducting magnet quench limitations due to the increasing beam intensities and particle debris produced in the collision points. Two new TCLD collimators have to be installed on either side of the ALICE experiment to intercept heavy-ion particle debris. Beam optics solutions were found to place these collimators in the continuous cryostat of the machine, in the locations where connection cryostats, bridging a gap of about 13 m between adjacent magnets, are already present. It is therefore planned to replace these connection cryostats with two new shorter ones separated by a bypass cryostat allowing the collimators to be placed close to the beam pipes. The connection cryostats, of a new design when compared to the existing ones, will still have to ensure the continuity of the technical systems of the machine cryostat (i.e. beam lines, cryogenic and electrical circuits, insulation vacuum). This paper describes the functionalities and the design solutions implemented, as well as the plans for their construction.

Final Design and Experimental Validation of the Thermal Performance of the LHC Lattice Cryostats

International Nuclear Information System (INIS)

Bourcey, N.; Capatina, O.; Parma, V.; Poncet, A.; Rohmig, P.; Serio, L.; Skoczen, B.; Tock, J.-P.; Williams, L. R.

2004-01-01

The recent commissioning and operation of the LHC String 2 have given a first experimental validation of the global thermal performance of the LHC lattice cryostat at nominal cryogenic conditions. The cryostat designed to minimize the heat inleak from ambient temperature, houses under vacuum and thermally protects the cold mass, which contains the LHC twin-aperture superconducting magnets operating at 1.9 K in superfluid helium. Mechanical components linking the cold mass to the vacuum vessel, such as support posts and insulation vacuum barriers are designed with efficient thermalisations for heat interception to minimise heat conduction. Heat inleak by radiation is reduced by employing multilayer insulation (MLI) wrapped around the cold mass and around an aluminium thermal shield cooled to about 60 K.Measurements of the total helium vaporization rate in String 2 gives, after substraction of supplementary heat loads and end effects, an estimate of the total thermal load to a standard LHC cell (107 m) including two Short Straight Sections and six dipole cryomagnets. Temperature sensors installed at critical locations provide a temperature mapping which allows validation of the calculated and estimated thermal performance of the cryostat components, including efficiency of the heat interceptions

Final Design and Experimental Validation of the Thermal Performance of the LHC Lattice Cryostats

Science.gov (United States)

Bourcey, N.; Capatina, O.; Parma, V.; Poncet, A.; Rohmig, P.; Serio, L.; Skoczen, B.; Tock, J.-P.; Williams, L. R.

2004-06-01

The recent commissioning and operation of the LHC String 2 have given a first experimental validation of the global thermal performance of the LHC lattice cryostat at nominal cryogenic conditions. The cryostat designed to minimize the heat inleak from ambient temperature, houses under vacuum and thermally protects the cold mass, which contains the LHC twin-aperture superconducting magnets operating at 1.9 K in superfluid helium. Mechanical components linking the cold mass to the vacuum vessel, such as support posts and insulation vacuum barriers are designed with efficient thermalisations for heat interception to minimise heat conduction. Heat inleak by radiation is reduced by employing multilayer insulation (MLI) wrapped around the cold mass and around an aluminium thermal shield cooled to about 60 K. Measurements of the total helium vaporization rate in String 2 gives, after substraction of supplementary heat loads and end effects, an estimate of the total thermal load to a standard LHC cell (107 m) including two Short Straight Sections and six dipole cryomagnets. Temperature sensors installed at critical locations provide a temperature mapping which allows validation of the calculated and estimated thermal performance of the cryostat components, including efficiency of the heat interceptions.

Cooling rate dependence of structural order in Al{sub 90}Sm{sub 10} metallic glass

Energy Technology Data Exchange (ETDEWEB)

Sun, Yang [Hefei National Laboratory for Physical Sciences at the Microscale and Department of Physics, University of Science and Technology of China, Hefei, Anhui 230026 (China); Ames Laboratory, US Department of Energy, Ames, Iowa 50011 (United States); Zhang, Yue; Zhang, Feng, E-mail: fzhang@ameslab.gov; Ye, Zhuo [Ames Laboratory, US Department of Energy, Ames, Iowa 50011 (United States); Ding, Zejun [Hefei National Laboratory for Physical Sciences at the Microscale and Department of Physics, University of Science and Technology of China, Hefei, Anhui 230026 (China); Wang, Cai-Zhuang [Ames Laboratory, US Department of Energy, Ames, Iowa 50011 (United States); Department of Physics, Iowa State University, Ames, Iowa 50011 (United States); Ho, Kai-Ming [Hefei National Laboratory for Physical Sciences at the Microscale and Department of Physics, University of Science and Technology of China, Hefei, Anhui 230026 (China); Ames Laboratory, US Department of Energy, Ames, Iowa 50011 (United States); Department of Physics, Iowa State University, Ames, Iowa 50011 (United States); International Center for Quantum Design of Functional Materials (ICQD), and Synergetic Innovation Center of Quantum Information and Quantum Physics, University of Science and Technology of China, Hefei, Anhui 230026 (China)

2016-07-07

The atomic structure of Al{sub 90}Sm{sub 10} metallic glass is studied using molecular dynamics simulations. By performing a long sub-T{sub g} annealing, we developed a glass model closer to the experiments than the models prepared by continuous cooling. Using the cluster alignment method, we found that “3661” cluster is the dominating short-range order in the glass samples. The connection and arrangement of “3661” clusters, which define the medium-range order in the system, are enhanced significantly in the sub-T{sub g} annealed sample as compared with the fast cooled glass samples. Unlike some strong binary glass formers such as Cu{sub 64.5}Zr{sub 35.5}, the clusters representing the short-range order do not form an interconnected interpenetrating network in Al{sub 90}Sm{sub 10,} which has only marginal glass formability.

Optimum dry-cooling sub-systems for a solar air conditioner

Science.gov (United States)

Chen, J. L. S.; Namkoong, D.

1978-01-01

Dry-cooling sub-systems for residential solar powered Rankine compression air conditioners were economically optimized and compared with the cost of a wet cooling tower. Results in terms of yearly incremental busbar cost due to the use of dry-cooling were presented for Philadelphia and Miami. With input data corresponding to local weather, energy rate and capital costs, condenser surface designs and performance, the computerized optimization program yields design specifications of the sub-system which has the lowest annual incremental cost.

Design and assembly technology for the thermal insulation of the W7-X cryostat

Energy Technology Data Exchange (ETDEWEB)

Risse, K., E-mail: konrad.risse@ipp.mpg.de [Max-Planck-Institut fuer Plasmaphysik (IPP), Euratom Association, Wendelsteinstrasse 1, D-17491 Greifswald (Germany); Nagel, M.; Pietsch, M.; Braatz, A. [Max-Planck-Institut fuer Plasmaphysik (IPP), Euratom Association, Wendelsteinstrasse 1, D-17491 Greifswald (Germany); Binni, A. [MAN Diesel and Turbo SE, Dpt. OSA, Werftstrasse 17, D-94469 Deggendorf (Germany); Posselt, H. [Linde AG Engineering Div., Dr.-Carl-von-Linde-Strasse 6-14, D-82049 Hoellriegelskreuth (Germany)

2011-10-15

The Max-Planck-Institut fuer Plasmaphysik in Greifswald is building up the stellarator fusion experiment Wendelstein 7-X (W7-X). To operate the superconducting magnet system the vacuum and the cold structures are protected by a thermal insulated cryostat. The plasma vessel forms the inner cryostat wall, the outer wall is realised by a thermal insulated outer vessel. In addition 254 thermal insulated ports are fed through the cryogenic vacuum to allow the access to the plasma vessel for heating systems, supply lines or plasma diagnostics. The thermal insulation is being manufactured and assembled by MAN Diesel and Turbo SE (Germany). It consists of a multi-layer insulation (MLI) made of aluminized Kapton with a silk like fibreglass spacer and a thermal shield covering the inner cryostat surfaces. The shield on the plasma vessel is made of fibreglass reinforced epoxy resin with integrated copper meshes. The outer vessel insulation is made of brass panels with an average size of 3.3 x 2.0 m{sup 2}. Cooling loops made of stainless steel are connected via copper strips to the brass panels. Especially the complex 3 D shape of the plasma vessel, the restricted space inside the cryostat and the consideration of the operational component movements influenced the design work heavily. The manufacturing and the assembly has to fulfil stringent geometrical tolerances e.g. for the outer vessel panels +3/-2 mm.

Design and assembly technology for the thermal insulation of the W7-X cryostat

International Nuclear Information System (INIS)

Risse, K.; Nagel, M.; Pietsch, M.; Braatz, A.; Binni, A.; Posselt, H.

2011-01-01

The Max-Planck-Institut fuer Plasmaphysik in Greifswald is building up the stellarator fusion experiment Wendelstein 7-X (W7-X). To operate the superconducting magnet system the vacuum and the cold structures are protected by a thermal insulated cryostat. The plasma vessel forms the inner cryostat wall, the outer wall is realised by a thermal insulated outer vessel. In addition 254 thermal insulated ports are fed through the cryogenic vacuum to allow the access to the plasma vessel for heating systems, supply lines or plasma diagnostics. The thermal insulation is being manufactured and assembled by MAN Diesel and Turbo SE (Germany). It consists of a multi-layer insulation (MLI) made of aluminized Kapton with a silk like fibreglass spacer and a thermal shield covering the inner cryostat surfaces. The shield on the plasma vessel is made of fibreglass reinforced epoxy resin with integrated copper meshes. The outer vessel insulation is made of brass panels with an average size of 3.3 x 2.0 m 2 . Cooling loops made of stainless steel are connected via copper strips to the brass panels. Especially the complex 3 D shape of the plasma vessel, the restricted space inside the cryostat and the consideration of the operational component movements influenced the design work heavily. The manufacturing and the assembly has to fulfil stringent geometrical tolerances e.g. for the outer vessel panels +3/-2 mm.

Analysis of EAST tokamak cryostat anti-seismic performance

International Nuclear Information System (INIS)

Chen Wei; Kong Xiaoling; Liu Sumei; Ni Xiaojun; Wang Zhongwei

2014-01-01

A 3-D finite element model for EAST tokamak cryostat is established by using ANSYS. On the basis of the modal analysis, the seismic response of the EAST tokamak cryostat structure is calculated according to an input of the design seismic response spectrum referring to code for seismic design of nuclear power plants. Calculation results show that EAST cryostat displacement and stress response is small under the action of earthquake. According to the standards, EAST tokamak cryostat structure under the action of design seismic can meet the requirements of anti-seismic design intensity, and ensure the anti-seismic safety of equipment. (authors)

Conceptual design of JT-60SA cryostat

International Nuclear Information System (INIS)

Shibama, Y.K.; Sakurai, S.; Masaki, K.; Sukekawa, A.M.; Kaminaga, A.; Yoshida, K.; Matsukawa, M.

2007-01-01

JT-60U modification program to fully superconducting device has been proceeded, namely ''JT-60SA'', toward early realization of fusion energy based on tokamak concept. The design of JT-60SA cryostat is expected to achieve a vacuum thermal insulation for super conducting coils, a bio-shielding boundary and structural gravity support. The cryostat is required to cover JT-60SA tokamak device, which is 15 m of total height and 7 m of radius, but there is geometrical limit due to surrounding devices reutilized. Although the cryostat consists of vessel body and gravity support, and the structural material is low cobalt 304 stainless steel (Co: 2 , and the design of the leaf spring is considered to reduce thermal stress, and to withstand the mechanical loads of plasma disruption and seismic loads. The coolant is 80 K gas helium and both sides of panel are covered with multi-layers super insulation (SI) to reduce heat load (radiation) up to 1/100. Fraction of non-covered region is assumed to be 2% due to many port-joints and supports for the vacuum vessel. Total heat load for inner surface of cryostat (600 m 2 ) is 9kW and the heat load for the port-joints (-300 m 2 ) is assumed up to 9 kW. The operational pressure of the cryostat is required to keep less than 10 -2 Pa and about 100,000 m 2 of structural surfaces is considered for exhaust system specification. Another role of the cryostat is the radiation protection. Biological shielding up to 10 micro-Sv/h (for maintenance acceptance) is required of the cryostat surface after the 10 years operation. Thus the cryostat consists of boron (2 wt%) doped concrete of 220 mm thickness and structural SS304 of total 40 mm thickness. The concrete reduces the air activation (41Ar) in the torus hall by 90% rather than the normal one by the thermal neutron absorption of boron. (orig.)

Dynamics of liquid nitrogen cooling process of solid surface at wetting contact coefficient

International Nuclear Information System (INIS)

Smakulski, P; Pietrowicz, S

2015-01-01

Liquid cryogens cooling by direct contact is very often used as a method for decreasing the temperature of electronic devices or equipment i.e. HTS cables. Somehow, cooldown process conducted in that way could not be optimized, because of cryogen pool boiling characteristic and low value of the heat transfer coefficient. One of the possibilities to increase the efficiency of heat transfer, as well as the efficiency of cooling itself, it is to use a spray cooling method. The paper shows dynamics analysis of liquid nitrogen cooling solid surface process. The model of heat transfer for the single droplet of liquid nitrogen, which hits on a flat and smooth surface with respect to the different Weber numbers, is shown. Temperature profiles in calculation domains are presented, as well as the required cooling time. The numerical calculations are performed for different initial and boundary conditions, to study how the wetting contact coefficient is changing, and how it contributed to heat transfer between solid and liquid cryogen. (paper)

Convection-type LH{sub 2} absorber R and D for muon ionization cooling

Energy Technology Data Exchange (ETDEWEB)

Ishimoto, S. E-mail: shigeru.ishimoto@kek.jp; Bandura, L.; Black, E.L.; Boghosian, M.; Cassel, K.W.; Cummings, M.A.; Darve, C.; Dyshkant, A.; Errede, D.; Geer, S.; Haney, M.; Hedin, D.; Johnson, R.; Johnstone, C.J.; Kaplan, D.M.; Kubik, D.; Kuno, Y.; Majewski, S.; Popovic, M.; Reep, M.; Summers, D.; Suzuki, S.; Yoshimura, K

2003-05-01

A feasibility study on liquid hydrogen (LH{sub 2}) absorbers for muon ionization cooling is reported. In muon ionization cooling, an LH{sub 2} absorber is required to have a high cooling power greater than 100 W to cool heat deposited by muons passing through. That heat in LH{sub 2} can be removed at either external or internal heat exchangers, which are cooled by cold helium gas. As one of the internal heat exchanger types, a convection-type absorber is proposed. In the convection-type absorber, heat is taken away by the convection of LH{sub 2} in the absorber. The heat exchanger efficiency for the convection-type absorber is calculated. A possible design is presented.

Nitrogen uptake in the northeastern Arabian Sea during winter cooling

Digital Repository Service at National Institute of Oceanography (India)

Kumar, S.; Ramesh, R.; Dwivedi, R.M.; Raman, M.; Sheshshayee, M.S.; DeSouza, W.

/plain; charset=UTF-8 Hindawi Publishing Corporation International Journal of Oceanography Volume 2010, Article ID 819029, 11 pages doi:10.1155/2010/819029 Research Article Nitrogen Uptake in the Northeastern Arabian Sea during Winter Cooling S. Kumar, 1...

Helium leak testing of superconducting magnets, thermal shields and cryogenic lines of SST -1

International Nuclear Information System (INIS)

Thankey, P.L.; Joshi, K.S.; Semwal, P.; Pathan, F.S.; Raval, D.C.; Khan, Z.; Patel, R.J.; Pathak, H.A.

2005-01-01

Tokamak SST - 1 is under commissioning at Institute for Plasma Research. It comprises of a toroidal doughnut shaped plasma chamber, surrounded by liquid helium cooled superconducting magnets, housed in a cryostat chamber. The cryostat has two cooling circuits, (1) liquid nitrogen cooling circuit operating at 80 K to minimize the radiation heat load on the magnets, and (2) liquid helium cooling circuit to cool magnets and cold mass support structure to 4.5 K. In this paper we describe (a) the leak testing of copper - SS joints, brazing joints, interconnecting joints of the superconducting magnets, and (b) the leak testing of the liquid nitrogen cooling circuit, comprising of the main supply header, the thermal shields, interconnecting pipes, main return header and electrical isolators. All these tests were carried out using both vacuum and sniffer methods. (author)

Investigation of fluorine adsorption on nitrogen doped MgAl{sub 2}O{sub 4} surface by first-principles

Energy Technology Data Exchange (ETDEWEB)

Lv, Xiaojun; Xu, Zhenming [School of Metallurgy and Environment, Central South University, Changsha 410083 (China); Li, Jie, E-mail: 15216105346@163.com [School of Metallurgy and Environment, Central South University, Changsha 410083 (China); Chen, Jiangan [Faculty of Resource and Environmental Engineering, Jiangxi University of Science and Technology, Ganzhou 341000 (China); Liu, Qingsheng [Faculty of Metallurgical and Chemical Engineering, Jiangxi University of Science and Technology, Ganzhou 341000 (China)

2016-07-15

Graphical abstract: First-principles calculations indicate that MgAl{sub 2}O{sub 4} surface is fluorine-loving, but hydrophobic. N doped MgAl{sub 2}O{sub 4} (100) surface structure shows the highest fluorine adsorption performance and fluorine atom is more preferentially adsorbed on the Mg-Al bridge site. The fluorine adsorption intensity follow this order: N doped MgAl{sub 2}O{sub 4} (100) > Al{sub 2}O{sub 3} (0001) > MgAl{sub 2}O{sub 4} (100) > MgO (100). N doped MgAl{sub 2}O{sub 4} is a promising candidate for fluorine removal. - Highlights: • MgAl{sub 2}O{sub 4} surface is fluorine-loving, not hydrophilic. • Fluorine preferentially adsorbs on the Mg-Al bridge site. • Adsorption intensity follow this order: N doped MgAl{sub 2}O{sub 4} > Al{sub 2}O{sub 3} > MgAl{sub 2}O{sub 4} > MgO. • Excellent adsorption performance attributes to electron compensation of N atom. • Nitrogen doped MgAl{sub 2}O{sub 4} is a promising candidate for fluorine removal. - Abstract: The nature of fluorine adsorption on pure and N doped MgAl{sub 2}O{sub 4} surface has been investigated by first-principles calculations based on the density functional theory. Calculated results indicate that MgAl{sub 2}O{sub 4} surface is fluorine-loving, not hydrophilic. Nitrogen doped MgAl{sub 2}O{sub 4} (100) surface shows the highest fluorine adsorption performance and fluorine atom preferentially adsorbs on the Mg-Al bridge site. The fluorine adsorption intensity follow this order: Nitrogen doped MgAl{sub 2}O{sub 4} (100) > Al{sub 2}O{sub 3} (0001) > MgAl{sub 2}O{sub 4} (100) > MgO (100). In-depth PDOS analysis suggested that 2p orbitals of F atom strongly hybridized with 3s- and 3p-orbitals of Al atom contribute to its high adsorption intensity. According to the analysis of Hirshfeld charge, the excellent fluorine adsorption performance of nitrogen doped MgAl{sub 2}O{sub 4} attributes to the electron compensation effect of nitrogen atom and strong electrostatic interactions. All these

Mathematical Model-Based Temperature Preparation of Liquid-Propellant Components Cooled by Liquid Nitrogen in the Heat Exchanger with a Coolant

Directory of Open Access Journals (Sweden)

S. K. Pavlov

2014-01-01

Full Text Available Before fuelling the tanks of missiles, boosters, and spacecraft with liquid-propellant components (LPC their temperature preparation is needed. The missile-system ground equipment performs this operation during prelaunch processing of space-purpose missiles (SPM. Usually, the fuel cooling is necessary to increase its density and provide heat compensation during prelaunch operation of SPM. The fuel temperature control systems (FTCS using different principles of operation and types of coolants are applied for fuel cooling.To determine parameters of LPC cooling process through the fuel heat exchange in the heat exchanger with coolant, which is cooled by liquid nitrogen upon contact heat exchange in the coolant reservoir, a mathematical model of this process and a design technique are necessary. Both allow us to determine design parameters of the cooling system and the required liquid nitrogen reserve to cool LPC to the appropriate temperature.The article presents an overview of foreign and domestic publications on cooling processes research and implementation using cryogenic products such as liquid nitrogen. The article draws a conclusion that it is necessary to determine the parameters of LPC cooling process through the fuel heat exchange in the heat exchanger with coolant, which is liquid nitrogen-cooled upon contact heat exchange in the coolant reservoir allowing to define rational propellant cooling conditions to the specified temperature.The mathematical model describes the set task on the assumption that a heat exchange between the LPC and the coolant in the heat exchanger and with the environment through the walls of tanks and pipelines of circulation loops is quasi-stationary.The obtained curves allow us to calculate temperature changes of LPC and coolant, cooling time and liquid nitrogen consumption, depending on the process parameters such as a flow rate of liquid nitrogen, initial coolant temperature, pump characteristics, thermal

Sealed liquid helium cryostats for mobile superconducting magnets

International Nuclear Information System (INIS)

Mulhall, B.E.; Rhodes, R.G.

1976-01-01

The predicted behaviour of the sealed cryostat system, which has been designed for the niobium-titanium superconducting coils of the on-board refrigerator of the small Wolfson electrodynamically levitated vehicle now under development, is summarized. Calculations suggest that the time taken by a sealed liquid helium cryostat to reach a specified final temperature is reasonably insensitive to the level of initial filling. Moreover, with a sufficiently large initial fill (for example, 70%) two or possibly three such temperature cycles, separated by the simple process of gas recovery, should be possible before replenishment of the helium is necessary. The useful time of operation of the cryostat between transfers of liquid helium is then not very much less than can be obtained with a freely boiling bath of liquid. For the low pressures involved the sealed cryostat is probably not much heavier or more complex than the open cryostat, and thus is ideal for a mobile application. (U.K.)

Studies on nitrogen oxides (NO{sub x} and N{sub 2}O) in pressurized fluidized bed combustion

Energy Technology Data Exchange (ETDEWEB)

Lu Yong

1998-09-01

This thesis describes the experimental studies of nitrogen oxide (NO, NO{sub 2}, N{sub 2}O) emissions in pressurized fluidized bed combustion (PFBC). In the first part of the thesis the background and the objectives of this study are introduced. The second part summarizes the fundamental knowledge about the formation and destruction of nitrogen oxides in coal combustion, particularly in the conditions of PFBC. The instrumentation of test facilities, measurement and data analysis is described in the third part. Then the most important experimental results follow in the next parts. The forth part describes the results from a PFBC test rig and an empirical modelling for predicting the emissions of NO{sub x} and N{sub 2}O. Finally, the fundamental work on coal combustion and fuel nitrogen conversion in a PFBC batch reactor is presented. These studies clearly confirm the potential of PFBC technology in the control nitrogen of oxide emissions. The research in the test rig was concentrated on determining the effects of process parameters on the emissions of nitrogen oxides with different fuels. Another objective was to examine the reduction of nitrogen oxides with the control methods in PFBC conditions, including ammonia injection and air staging combustion for reducing NO, and high temperature operations for reducing N{sub 2}0. The results indicate that pressurized operation suppresses the conversion of fuel-N to nitrogen oxides and favors with employing the reduction methods for further nitrogen oxide reduction, for instance the temperature window of NO reduction with ammonia injection has been found to be widened to even lower temperature range. Maximum reductions of 80-85 % with ammonia injection and 75-80 % with air staging combustion were achieved in the conditions examined. Considerably low emissions of N{sub 2}O (<7 ppm) were obtained in the tests of N{sub 2}O control, and thermal decomposition proved to be the laming pathway of N{sub 2}O destruction in PFBC. In

Assessment of external heat transfer coefficient during oocyte vitrification in liquid and slush nitrogen using numerical simulations to determine cooling rates.

Science.gov (United States)

Santos, M V; Sansinena, M; Zaritzky, N; Chirife, J

2012-01-01

In oocyte vitrification, plunging directly into liquid nitrogen favor film boiling and strong nitrogen vaporization. A survey of literature values of heat transfer coefficients (h) for film boiling of small metal objects with different geometries plunged in liquid nitrogen revealed values between 125 to 1000 W per per square m per K. These h values were used in a numerical simulation of cooling rates of two oocyte vitrification devices (open-pulled straw and Cryotop), plunged in liquid and slush nitrogen conditions. Heat conduction equation with convective boundary condition was considered a linear mathematical problem and was solved using the finite element method applying the variational formulation. COMSOL Multiphysics was used to simulate the cooling process of the systems. Predicted cooling rates for OPS and Cryotop when cooled at -196 degree C (liquid nitrogen) or -207 degree C (average for slush nitrogen) for heat transfer coefficients estimated to be representative of film boiling, indicated lowering the cooling temperature produces only a maximum 10 percent increase in cooling rates; confirming the main benefit of plunging in slush over liquid nitrogen does not arise from their temperature difference. Numerical simulations also demonstrated that a hypothetical four-fold increase in the cooling rate of vitrification devices when plunging in slush nitrogen would be explained by an increase in heat transfer coefficient. This improvement in heat transfer (i.e., high cooling rates) in slush nitrogen is attributed to less or null film boiling when a sample is placed in slush (mixture of liquid and solid nitrogen) because it first melts the solid nitrogen before causing the liquid to boil and form a film.

A cryostatic setup for the low-temperature measurement of thermal diffusivity with the photothermal method

International Nuclear Information System (INIS)

Bertolotti, M.; Liakhou, G.; Li Voti, R.; Paoloni, S.; Sibilia, C.; Sparvieri, N.

1995-01-01

A cryostatic setup is described to perform photothermal deflection measurements from room temperature to 77 K. The setup uses gaseous nitrogen as a medium where the photodeflection is produced. The ability of the system to work is demonstrated presenting some measurements of thermal diffusivity of high-temperature superconductor samples and of yttrium-iron garnets with variable aluminum content. copyright 1995 American Institute of Physics

Development of liquid-nitrogen-cooling friction stir spot welding for AZ31 magnesium alloy joints

Science.gov (United States)

Wu, Dong; Shen, Jun; Zhou, Meng-bing; Cheng, Liang; Sang, Jia-xing

2017-10-01

A liquid-nitrogen-cooling friction stir spot welding (C-FSSW) technology was developed for welding AZ31 magnesium alloy sheets. The liquid-nitrogen cooling degraded the deformability of the welded materials such that the width of interfacial cracks increased with increasing cooling time. The grain size of the stirred zone (SZ) and the heat-affected zone (HAZ) of the C-FSSW-welded joints decreased, whereas that of the thermomechanically affected zone (TMAZ) increased with increasing cooling time. The maximum tensile shear load of the C-FSSW-welded joints welded with a cooling time of 5 or 7 s was larger than that of the friction stir spot welding (FSSW)-welded joint, and the tensile shear load decreased with increasing cooling time. The microhardness of the C-FSSW-welded joints was greater than that of the FSSW-welded joint. Moreover, the microhardness of the SZ and the HAZ of the C-FSSW-welded joints increased, whereas that of the TMAZ decreased, with increasing cooling time.

FE simulation of the Wendelstein 7-X cryostat system

International Nuclear Information System (INIS)

Tereshchenko, A.; Bykov, V.; Schauer, F.; Ye, M.Y.; Weissflog, S.; Andreeva, T.

2009-01-01

The purpose of the Wendelstein 7-X cryostat is to thermally insulate the magnet system (operating at cryo-temperature) by high vacuum and super insulation, to provide and enclose the working space for the plasma, and to serve as a bearing structure for the system components that have to be placed in the immediate vicinity of the plasma, such as the first wall, the divertor and some of the diagnostic devices. Concerning structural components only, the cryostat is composed of the plasma vessel, the outer vessel and the ports that interconnect the vessels. The cryostat together with the machine base comprises the so called cryostat system, and this is the system that is under consideration in this paper. Due to both the geometrical complexity and the complexity of loading, individual subsystems of the cryostat system could not be analyzed separately. For that reason, a global finite element model of the whole cryostat system had to be created. The paper presents an overview of finite element modeling, simulations with ANSYS performed on this system, and the corresponding calculation results.

Cryostat for mechanical testing of materials at 4.2 K [Paper No. : VII-3

International Nuclear Information System (INIS)

Valsakumar, M.C.; Kannan, N.; Radhakrishnan, T.S.

1978-01-01

A liquid helium cryostat has been fabricated to be coupled to a Instron Model 1195 Universal Testing Machine for mechanical testing of materials at low temperatures. The sample is held between two grip assemblies, the top one being connected to the load cell by a long pull-rod. The bottom grip is connected to a tube, co-axial to the pull-rod, which in turn is attached to the moving cross-head. Studies with this set-up give information about the yield characteristics at room temperature, 77 K and at 4.2 K. With a manostat, the temperature ranges can be extended to 64-80 K and 1-5 K. The effect of magnetic field on yield characteristics, especially due to the viscous drag of dislocations by electron cloud, can be studied by a 10 kG superconducting magnet around the sample. The cryostat has been tested to the load capacity which is 5 KN. Results of tests done on annealed copper with this set-up are in agreement with the literature. Temperature stability at liquid nitrogen temperature makes it possible to do stress relaxation experiments for a duration of 15 minutes. The cryostat has a liquid helium consumption of about 3 litres per test. (author)

Insulation systems for superconducting transmission cables

DEFF Research Database (Denmark)

Tønnesen, Ole

1996-01-01

the electrical insulation is placed outside both the superconducting tube and the cryostat. The superconducting tube is cooled by liquid nitrogen which is pumped through the hollow part of the tube.2) The cryogenic dielectric design, where the electrical insulation is placed inside the cryostat and thus is kept...

Effect of cooling the recirculated exhaust gases on diesel engine emissions

Energy Technology Data Exchange (ETDEWEB)

Abu-Hamdeh, Nidal H. [Jordan Univ. of Science and Technology, Irbid (Jordan)

2003-11-01

Although combustion is essential in most energy generation processes, it is one of the major causes of air pollution. Spiral fin exhaust pipes were designed to study the effect of cooling the recirculated exhaust gases (EGR) of Diesel engines on the chemical composition of the exhaust gases and the reduction in the percentages of pollutant emissions. The gases examined in this study were oxides of nitrogen (NO{sub x}), carbon dioxide (CO{sub 2}) and carbon monoxide (CO). In addition, O{sub 2} concentration in the exhaust was measured. The two designs adopted in this study were exhaust pipes with solid and hollow fins around them. The first type uses air flow around the fins to cool the exhaust gases. The second type consists of hollow fins around the exhaust pipe to allow cooling water to flow in the hollow passage. Different combinations and arrangements of the solid and hollow fins exhaust pipes were used. It was found that decreasing the temperature of the EGR resulted in reductions in the oxides of nitrogen (NO{sub x}) and carbon dioxide (CO{sub 2}) but increased the carbon monoxide (CO) in the exhaust gases. In addition, the oxygen (O{sub 2}) concentration in the exhaust was decreased. As a general trend, the percentages of reduction in the NO{sub x} gas concentrations were lower than the percentages of increase in the CO emissions as a result of cooling the EGR of a Diesel engine by a heat exchanger. Using water as a cooling medium decreased the exhaust gases temperature and the amount of pollutants more than did air as a cooling medium. In a separate series of tests, increasing the cooled EGR ratios decreased the exhaust NO{sub x} but increased the particulate matter concentrations in the exhaust gases. (Author)

First scientific application of the membrane cryostat technology

Energy Technology Data Exchange (ETDEWEB)

Montanari, David; Adamowski, Mark; Baller, Bruce R.; Barger, Robert K.; Chi, Edward C.; Davis, Ronald P.; Johnson, Bryan D.; Kubinski, Bob M.; Najdzion, John J.; Rucinski, Russel A.; Schmitt, Rich L.; Tope, Terry E. [Particle Physics Division, Fermilab, P.O. Box 500, Batavia, IL 60510 (United States); Mahoney, Ryan; Norris, Barry L.; Watkins, Daniel J. [Technical Division, Fermilab, P.O. Box 500, Batavia, IL 60510 (United States); McCluskey, Elaine G. [LBNE Project, Fermilab, P.O. Box 500, Batavia, IL 60510 (United States); Stewart, James [Physics Department, Brookhaven National Laboratory, P.O. Box 5000, Uptown, NY 11973 (United States)

2014-01-29

We report on the design, fabrication, performance and commissioning of the first membrane cryostat to be used for scientific application. The Long Baseline Neutrino Experiment (LBNE) has designed and fabricated a membrane cryostat prototype in collaboration with IHI Corporation (IHI). Original goals of the prototype are: to demonstrate the membrane cryostat technology in terms of thermal performance, feasibility for liquid argon, and leak tightness; to demonstrate that we can remove all the impurities from the vessel and achieve the purity requirements in a membrane cryostat without evacuation and using only a controlled gaseous argon purge; to demonstrate that we can achieve and maintain the purity requirements of the liquid argon during filling, purification, and maintenance mode using mole sieve and copper filters from the Liquid Argon Purity Demonstrator (LAPD) R and D project. The purity requirements of a large liquid argon detector such as LBNE are contaminants below 200 parts per trillion oxygen equivalent. This paper gives the requirements, design, construction, and performance of the LBNE membrane cryostat prototype, with experience and results important to the development of the LBNE detector.

The ATLAS cryostat comes into the lime-light

CERN Multimedia

2002-01-01

Jean-Jacques Aubert, director of IN2P3, addresses the teams involved in the ATLAS electromagnetic calorimeter. At the rear, the barrel cryostat being equipped. In response to an invitation from IN2P3, the French national institute for nuclear and particle physics, the ATLAS experiment teams have celebrated progress made in the construction of their Liquid Argon Detector. In particular they wanted to salute the arrival of the cryostat for one of the end-caps, built by the company Simic in Italy. The second is expected at the end of January 2003. The cryostats are the fruit of a collaboration between IN2P3, the Max Planck Institute in Munich and the German Ministry for education and research (BMBF). The barrel cryostat arrived from Japan last year. The three cryostats will contain four types of different detectors made by the collaboration. They will contain in total nearly 400 modules including electromagnetic modules. More than half the modules for one of the two electromagnetic calorimeter barrels have bee...

Experimental research on rock fracture failure characteristics under liquid nitrogen cooling conditions

Science.gov (United States)

Gao, Feng; Cai, Chengzheng; Yang, Yugui

2018-06-01

As liquid nitrogen is injected into a wellbore as fracturing fluid, it can rapidly absorb heat from warmer rock and generate cryogenic condition in downhole region. This will alter the physical conditions of reservoir rocks and further affect rock failure characteristics. To investigate rock fracture failure characteristics under liquid nitrogen cooling conditions, the fracture features of four types of sandstones and one type of marble were tested on original samples (the sample without any treatment) and cryogenic samples (the samples just taken out from the liquid nitrogen), respectively. The differences between original samples and cryogenic samples in load-displacement curves, fracture toughness, energy evolution and the crack density of ruptured samples were compared and analyzed. The results showed that at elastic deformation stage, cryogenic samples presented less plastic deformation and more obvious brittle failure characteristics than original ones. The average fracture toughness of cryogenic samples was 10.47%-158.33% greater than that of original ones, indicating that the mechanical strength of rocks used were enhanced under cooling conditions. When the samples ruptured, the cryogenic ones were required to absorb more energy and reserve more elastic energy. In general, the fracture degree of cryogenic samples was higher than that of original ones. As the samples were entirely fractured, the crack density of cryogenic samples was about 536.67% at most larger than that of original ones. This indicated that under liquid nitrogen cooling conditions, the stimulation reservoir volume is expected to be improved during fracturing. This work could provide a reference to the research on the mechanical properties and fracture failure of rock during liquid nitrogen fracturing.

Superconducting linear accelerator cryostat

International Nuclear Information System (INIS)

Ben-Zvi, I.; Elkonin, B.V.; Sokolowski, J.S.

1984-01-01

A large vertical cryostat for a superconducting linear accelerator using quarter wave resonators has been developed. The essential technical details, operational experience and performance are described. (author)

Design for a low temperature ion implantation and luminescence cryostat

International Nuclear Information System (INIS)

Noonan, J.R.; Kirkpatrick, C.G.; Myers, D.R.; Streetman, B.G.

1976-01-01

Several simple design changes of a conventional liquid helium optical Dewar can significantly improve the cryostat's versatility for use in low temperature particle irradiation. A bellows assembly provides precise sample positioning and allows convenient access for electrical connections. A heat exchanger consisting of thin walled tubing with a 'goose neck' bend provides a simple, effective means of cooling the sample as well as excellent thermal isolation of the sample holder from the coolant reservoir during controlled anneals. The addition of a vane-type vacuum valve, optical windows, and a rotatable tailpiece facilitates the study of optical properties of materials following low temperature ion implantation. (author)

Solar cooling - Economical assessment and CO{sub 2} balance; Solar Cooling. Oekonomische Bewertung und CO{sub 2} Bilanzierung

Energy Technology Data Exchange (ETDEWEB)

Gantenbein, P.; Machein, T.; Frank, E.

2010-07-01

This short, illustrated final report discusses how thermally-driven sorption chiller systems can help meet future cooling needs in houses and workplaces. Increasing global temperatures are commented on and their influence on space heating and cooling is discussed. The modelling of a single-family home, an office building and an industrial building is described. Three cooling systems are taken into consideration: a single-stage LiBr-H{sub 2}O absorber machine using solar energy from vacuum-pipe collectors, a compressor refrigeration system with a heating function powered by photovoltaics and a compressor system run on mains electricity. The simulations were carried out for locations in three different climate zones, in Lugano, Switzerland, Athens, Greece and Dubai, United Arab Emirates. The results are commented on.

Evaluating cryostat performance for naval applications

Science.gov (United States)

Knoll, David; Willen, Dag; Fesmire, James; Johnson, Wesley; Smith, Jonathan; Meneghelli, Barry; Demko, Jonathan; George, Daniel; Fowler, Brian; Huber, Patti

2012-06-01

The Navy intends to use High Temperature Superconducting Degaussing (HTSDG) coil systems on future Navy platforms. The Navy Metalworking Center (NMC) is leading a team that is addressing cryostat configuration and manufacturing issues associated with fabricating long lengths of flexible, vacuum-jacketed cryostats that meet Navy shipboard performance requirements. The project includes provisions to evaluate the reliability performance, as well as proofing of fabrication techniques. Navy cryostat performance specifications include less than 1 Wm-1 heat loss, 2 MPa working pressure, and a 25-year vacuum life. Cryostat multilayer insulation (MLI) systems developed on the project have been validated using a standardized cryogenic test facility and implemented on 5-meterlong test samples. Performance data from these test samples, which were characterized using both LN2 boiloff and flow-through measurement techniques, will be presented. NMC is working with an Integrated Project Team consisting of Naval Sea Systems Command, Naval Surface Warfare Center-Carderock Division, Southwire Company, nkt cables, Oak Ridge National Laboratory (ORNL), ASRC Aerospace, and NASA Kennedy Space Center (NASA-KSC) to complete these efforts. Approved for public release; distribution is unlimited. This material is submitted with the understanding that right of reproduction for governmental purposes is reserved for the Office of Naval Research, Arlington, Virginia 22203-1995.

LHC interaction region quadrupole cryostat design

International Nuclear Information System (INIS)

Nicol, T.H.; Darve, Ch.; Huang, Y.; Page, T.M.

2002-01-01

The cryostat of a Large Hadron Collider (LHC) Interaction Region (IR) quadrupole magnet consists of all components of the inner triplet except the magnet assembly itself. It serves to support the magnet accurately and reliably within the vacuum vessel, to house all required cryogenic piping, and to insulate the cold mass from heat radiated and conducted from the environment. It must function reliably during storage, shipping and handling, normal magnet operation, quenches, and seismic excitations, and must be able to be manufactured at low cost. The major components of the cryostat are the vacuum vessel, thermal shield, multi-layer insulation system, cryogenic piping, and suspension system. The overall design of a cryostat for superconducting accelerator magnets requires consideration of fluid flow, proper selection of materials for their thermal and structural performance at both ambient and operating temperature, and knowledge of the environment to which the magnets will be subjected over the course of their expected operating lifetime. This paper describes the current LHC IR inner triplet quadrupole magnet cryostats being designed and manufactured at Fermilab as part of the US-LHC collaboration, and includes discussions on the structural and thermal considerations involved in the development of each of the major systems

Vertical cryostat for guidance and propulsion of superconducting magnetic levitation vehicle

International Nuclear Information System (INIS)

Nakashima, H.; Arima, K.

1974-01-01

The superconducting magnetic levitation vehicle requires two types of magnet: one for levitation, and one for guidance and propulsion (linear synchronous motor). Cryostats for these magnets have to satisfy three fundamental conditions; lightness, small heat leak, and enough strength to ensure the electromagnetic forces. A prototype vertical cryostat was designed for research into on-board cryostats for guidance and propulsion. A small refrigerator can be connected to the cryostat, to facilitate testing of the fundamental refrigeration system on board. The performance of the cryostat, and the test results, are reported in this paper. (author)

Use of ultrasonic waves in sub-cooled boiling

International Nuclear Information System (INIS)

Bartoli, Carlo; Baffigi, Federica

2012-01-01

This work focuses on the use of ultrasounds in heat transfer fields. Under particular conditions, ultrasonic waves induce a convection coefficient increase. This initial research work, indicates that there are some practical applications in the cooling of the latest generation electronic components. In the first part of this paper, some background on this subject is reported. The ultrasound's influence on heat transfer rate has been observed since the 60's: different authors studied the cooling effect due to ultrasonic waves from different heat transfer regimes. The most investigated configuration was a thin platinum wire immersed in water. Later, a bibliographic research on possible practical applications of ultrasounds was carried out. This research focused in particular on the issue for 3D highly integrated electronic components. For these systems the thermal problem is a major challenge, because they cannot exceed critical temperatures, after which they could be damaged irreversibly. On the basis of our experimental results, ultrasounds could represent a valid means to overcome these thermal problems. Finally, the paper presents a series of experiments performed in the Thermal-Fluid- Dynamic Lab at the Energy and Engineering Systems Department of University of Pisa. The experiments provide systematic evidence of ultrasonic waves effects, on free convection heat transfer, from a heated circular cylinder to sub-cooled water, at atmospheric pressure. Many variables involved in the heat transfer rise were tested, for example: the ultrasonic generator's power, the position of the heater inside the ultrasonic tank, the variation of the water sub-cooling degree, as function of the heat flux needed dissipating. The aim of the experiment was to find out the set of optimal conditions, in order to successively apply all the results to real packaging systems, as mentioned before. The maximum increase in the heat transfer coefficient, due to ultrasonic waves, was 57

Morphological and magnetic properties of the hydrothermally prepared α-Fe{sub 2}O{sub 3} nanorods

Energy Technology Data Exchange (ETDEWEB)

Hadia, N.M.A., E-mail: nomery_abass@science.sohag.edu.eg [Departamentos de Química Física y Analítica y Química Orgánica e Inorgánica, Universidad de Oviedo, 33006 Oviedo (Spain); Physics Department, Faculty of Science, Sohag University, 82524 Sohag (Egypt); García-Granda, Santiago; García, José R. [Departamentos de Química Física y Analítica y Química Orgánica e Inorgánica, Universidad de Oviedo, 33006 Oviedo (Spain); Martínez-Blanco, D. [Servicios Científico-Técnicos, Universidad de Oviedo, 33006 Oviedo (Spain); Mohamed, S.H. [Physics Department, Faculty of Science, Sohag University, 82524 Sohag (Egypt)

2014-10-15

α-Fe{sub 2}O{sub 3} nanorods were synthesized via hydrothermal method. X-ray powder diffraction revealed the formation of rhombohedral α-Fe{sub 2}O{sub 3} single crystal phase with fiber texture. Scanning and transmission electron micrographs analyses showed that the rhombohedral α-Fe{sub 2}O{sub 3} has nanorods in shape with diameters of 40–85 nm and lengths of 150–45,000 nm. Isothermal magnetization vs. applied magnetic field curves measured at room and liquid nitrogen temperatures displayed a variation on magnetic ordering: from weak ferromagnetism at room temperature to not hysteretic behavior at liquid nitrogen temperature that is well described by a Langevin function. Moreover, the zero field cooling-field cooling curves under applied magnetic field of 100 Oe confirms the decreasing of Morin temperature transition due to nanometric size of the samples. - Highlights: • The structural and magnetic properties of α-Fe{sub 2}O{sub 3} nanorods are examined. • Rietveld and Harris texture indicated the [001] is preferentially oriented. • The magnetic characterization evidenced the presence of hematite α-Fe{sub 2}O{sub 3}.

The Effects of Cooling Rate on the Microstructure and Mechanical Properties of Ti{sub 4}0Zr{sub 1}0Cu{sub 3}6Pd{sub 1}4 Metallic Glass Matrix Composites

Energy Technology Data Exchange (ETDEWEB)

Park, Seon Yong; Lim, Ka Ram; Na, Young Sang; Kim, Seong Eon [Korea Institute of Materials Science, Changwon (Korea, Republic of); Choi, Youn Suk [Pusan National University, Busan (Korea, Republic of)

2016-11-15

In this paper, we demonstrate that the microstructure and mechanical properties in the Ti{sub 4}0Zr{sub 1}0Cu{sub 3}6Pd{sub 1}4 alloy can be tailored by controlling the cooling rate during solidification. A lower cooling rate increases the volume fraction of crystalline phase such as B2 but decreases the free volume of the glassy matrix. The increase of the B2 volume fraction can dramatically enhance the toughness of the composites, since the B2 phase is relatively ductile compared to the glassy matrix and seems to have good interface stability with the matrix. From the experimental results, it was found that there is a transition point in the plasticity of the composites depending on the cooling rate. Here, we explain how the toughness of the composites varies in accordance with the cooling rate in the Ti{sub 4}0Zr{sub 1}0Cu{sub 3}6Pd{sub 1}4 alloy system.

A facile fabrication of nitrogen-doped electrospun In{sub 2}O{sub 3} nanofibers with improved visible-light photocatalytic activity

Energy Technology Data Exchange (ETDEWEB)

Lu, Na; Shao, Changlu, E-mail: clshao@nenu.edu.cn; Li, Xinghua, E-mail: lixh781@nenu.edu.cn; Miao, Fujun; Wang, Kexin; Liu, Yichun

2017-01-01

Highlights: • N-doped In{sub 2}O{sub 3} nanofibers are facilely fabricated by gaseous ammonia treatment. • Adjusting the annealing temperature leads to different N-doped In{sub 2}O{sub 3} nanofibers. • Nitrogen doping was found to be interstitial mode. • N-In{sub 2}O{sub 3} exhibited effective charge carrier separation and photocatalytic activity. • The photocatalysts can be easily separated from the reaction system. - Abstract: Semiconductor photocatalysis demonstrates to be an effective approach for eliminating most types of environment contaminants and for producing hydrogen. Herein, a facile synthesis route combining electrospinning technique and thermal treatment method under NH{sub 3} atmosphere has been presented as a straightforward protocol for the fabrication of nitrogen-doped In{sub 2}O{sub 3} (N-In{sub 2}O{sub 3}) nanofibers, the nitrogen content of which can be well controlled by adjusting the annealing temperature. Photocatalytic tests show that the N-In{sub 2}O{sub 3} nanofibers demonstrate an improved degradation rate of Rhodamine B (RB) compared with pure In{sub 2}O{sub 3} nanofibers under visible-light irradiation. This can be attributed to the nitrogen atom introducing at interstitial sites as well as the generation of oxygen vacancy on the surface of In{sub 2}O{sub 3} nanofibers, resulting in the enhanced utilization of visible light for the N-In{sub 2}O{sub 3} nanofibers. Furthermore, the obtained N-In{sub 2}O{sub 3} nanofibers with the advantage of ultra-long one-dimensional nanostructures can be recycled several times by facile sedimentation and hence present almost no decrease in photocatalytic activity indicative of a well regeneration capability. Therefore, the as-fabricated nitrogen-doped In{sub 2}O{sub 3} nanofibers as a promising photocatalyst present good photocatalytic degradation of organic pollutant in waste water for practical application.

Crystal structure and magnetic properties of a nitrogenated melt-spun Sm[sub 2]Fe[sub 17] compound

Energy Technology Data Exchange (ETDEWEB)

Yang, Choong-Jin [Electromagnetic Materials Laboratory, Research Institute of Industrial Science and Technology, P.O. Box 135, 790-330 Pohang (Korea, Republic of); Lee, Woo-Young [Electromagnetic Materials Laboratory, Research Institute of Industrial Science and Technology, P.O. Box 135, 790-330 Pohang (Korea, Republic of); Choi, Seung-Duck [Electromagnetic Materials Laboratory, Research Institute of Industrial Science and Technology, P.O. Box 135, 790-330 Pohang (Korea, Republic of)

1994-05-15

Sm[sub 2]Fe[sub 17]N[sub 2.9] compound powders were prepared from parent alloys of Sm[sub 2]Fe[sub 17] which were made by both arc melting and rapid solidification processes. The cast Sm[sub 2]Fe[sub 17] contained mixed phases of SmFe[sub 3] and [alpha]-Fe, and correspondingly formed less Sm[sub 2]Fe[sub 17]N[sub x] with a rather large amount of residual [alpha]-Fe after nitrogenation. The melt-spun Sm[sub 2]Fe[sub 17] compound, however, was single phase and exhibited a negligible amount of residual [alpha]+Fe after nitrogenation. The residual amount of free iron was found to increase as a function of milling time and to impede the development of promising permanent magnetic properties. The melt-spun Sm[sub 2]Fe[sub 17]N[sub x] compound powders exhibited a coercivity value [sub i]H[sub c] of 5 kOe, which is double that of the as-cast Sm[sub 2]Fe[sub 17]N[sub x] powders and a high remanence B[sub r]=60 e.m.u. g[sup -1]. The average magnetic moment of Fe atoms in the crystal is estimated to be 2.29 [mu][sub B] and the Fe atom in the 6c site exhibits the highest magnetic moment of 2.65 [mu][sub B]. The expansion in the c axial direction of the nitrogenated crystal was found to be mainly due to extension of Sm(6c)-Fe(c) and Fe(18f)-Fe(18f) distances. ((orig.))

Nitrogen system for the SSC

International Nuclear Information System (INIS)

McAshan, M.; Thirumaleshwar, M.; Abramovich, S.; Ganni, V.

1992-10-01

The Superconducting Super Collider consists of two parallel magnet rings, each 87,120 m in circumference, constructed in a tunnel 25 m to 74 m below ground level. They are operated at a controlled low helium temperature in order to maintain the magnet windings in the superconducting state. To obtain this condition, the magnet cryostat is designed with a high-quality insulation obtained by a high vacuum chamber, multilayer insulation, and thermal shields at nominal temperatures of 84 K and 20 K. Thermal radiation and the conduction heat load through the supports are intercepted and absorbed by the 84-K shield. Liquid nitrogen provides the refrigeration for these loads. The 84-K shield is anchored to two 63.5-mm stainless-steel tubes. One of the tubes, the ''liquid line,'' serves as a conduit in the distribution system of liquid nitrogen. The other tube, the ''vapor line,'' is used to collect the nitrogen vapor generated in the cooling process and to supply this vapor to,the helium refrigerators for precooling. The vapor line may also be used as a continuous cooler by injecting controlled amounts of liquid nitrogen. The nitrogen system consists of nitrogen supplies; ten nitrogen dewars for the collider and two for the High Energy Booster located on the ground at the main shaft entrances; liquid and vapor transfer lines through the shaft to connect the surface and the tunnel systems; and transfer lines to bypass warm equipment sections of the collider. The nitrogen system is expected to operate at steady state condition except for cooldown, warmup, and system repair, for which transients are expected. During normal operation and standby modes of the collider, temperature, pressure, and mass flow are expected to be constant in all circuits of the nitrogen system. The conceptual design requirements for various flow schemes and the engineering considerations are presented in this report

Determination of the nitrogen concentration in epitaxial layers of GaAs /SUB 1-x/ p /SUB x/ by the optical method

International Nuclear Information System (INIS)

Lupal, M.V.; Klot, B; Nikhter, K.; Pikhtin, A.N.; Trapp, M.

1986-01-01

This paper determines the dependence of the cross section for absorption in the A /SUB N/ line of a bound exciton on the nitrogen content in the solid solution GaAs /SUB 1-x/ P /SUB x/ by comparing the results of optical measurements with the data from secondary ionic mass spectrometry, and these results are used to study the effect of technological factors on the nitrogen concentration epitaxial layers obtained by the gas-transport method. Doping was carried out with nitrogen by injecting ammonia into the reactor zone; the partial pressure of the ammonia was varied from 1 to 25 kPa. Aside from nitrogen, the authors doped the layers with shallow donor Te. It is established that the solubility of nitrogen in the solid solution decreases as the arsenic content increases when the convenient optical method for determining the nitrogen concentration in epitaxial GaAs /SUB 1-x/ P /SUB x/ layers is used

Cycle time improvement for plastic injection moulding process by sub groove modification in conformal cooling channel

Science.gov (United States)

Kamarudin, K.; Wahab, M. S.; Batcha, M. F. M.; Shayfull, Z.; Raus, A. A.; Ahmed, Aqeel

2017-09-01

Mould designers have been struggling for the improvement of the cooling system performance, despite the fact that the cooling system complexity is physically limited by the fabrication capability of the conventional tooling methods. However, the growth of Solid Free Form Technology (SFF) allow the mould designer to develop more than just a regular conformal cooling channel. Numerous researchers demonstrate that conformal cooling channel was tremendously given significant result in the improvement of productivity and quality in the plastic injection moulding process. This paper presents the research work that applies the passive enhancement method in square shape cooling channel to enhance the efficiency of cooling performance by adding the sub groove to the cooling channel itself. Previous design that uses square shape cooling channel was improved by adding various numbers of sub groove to meet the best sub groove design that able reduced the cooling time. The effect of sub groove design on cooling time was investigated by Autodesk Modlflow Insight software. The simulation results showed that the various sub groove designs give different values to ejection time. The Design 7 showed the lowest value of ejection time with 24.3% increment. The addition of sub groove significantly increased a coolant velocity and a rate of heat transfer from molten plastic to coolant.

The refrigeration of high temperature superconductors between 25K and 65K

International Nuclear Information System (INIS)

Richardson, R.N.; Scurlock, R.G.; Tavner, A.C.R.

1996-01-01

The present state of the art indicates that acceptable j - H characteristics for power applications of the new high Tc superconductors will only be achieved using materials at temperatures below liquid nitrogen temperature. A boiling point of 27.1K and high specific cooling capacity make neon an eminently suitable choice of refrigerant at these temperatures. A cryostat has been constructed which employs a two stage Gifford-McMahon cooler to liquefy neon gas. The cryostat contains up to 5 litres of liquid neon which can be used for open-quote in-situ close-quote experiments or transfer to another cryostat. Another set of cryostats are being used with liquid nitrogen/oxygen mixtures at reduced pressure for temperatures down to 50K. All these cryostats provide a core facility for characterising and operating high T c superconductors at Southampton

Assessment of the effect of nitrogen gas on passive containment cooling system performance

International Nuclear Information System (INIS)

Ha, Huiun; Suh, Jungsoo

2016-01-01

As a part of the passive containment cooling system (PCCS) of Innovative PWR development project, we have been investigating the effect of the nitrogen gas released from safety injection tank (SIT) on PCCS performance. With the design characteristics of APR1400 and conceptual design of PCCS, we developed a GOTHIC model of the APR1400 containment with PCCS. The calculation model is described herein, and representative results from the calculation are presented as well. The results of the present work will be used for the design of PCCS. APR1400 GOTHIC model was developed for assessment on the effect of SIT nitrogen gas on passive containment cooling system performance. Calculation results confirmed that influence of nitrogen gas release is negligible; however, further studies should be performed to confirm effect of non-condensable gas on the final performance of PCCS. These insights are important for developing the PCCS of Innovative PWR

Assessment of the effect of nitrogen gas on passive containment cooling system performance

Energy Technology Data Exchange (ETDEWEB)

Ha, Huiun; Suh, Jungsoo [KHNP CRI, Daejeon (Korea, Republic of)

2016-10-15

As a part of the passive containment cooling system (PCCS) of Innovative PWR development project, we have been investigating the effect of the nitrogen gas released from safety injection tank (SIT) on PCCS performance. With the design characteristics of APR1400 and conceptual design of PCCS, we developed a GOTHIC model of the APR1400 containment with PCCS. The calculation model is described herein, and representative results from the calculation are presented as well. The results of the present work will be used for the design of PCCS. APR1400 GOTHIC model was developed for assessment on the effect of SIT nitrogen gas on passive containment cooling system performance. Calculation results confirmed that influence of nitrogen gas release is negligible; however, further studies should be performed to confirm effect of non-condensable gas on the final performance of PCCS. These insights are important for developing the PCCS of Innovative PWR.

High-stability cryogenic scanning tunneling microscope based on a closed-cycle cryostat

Energy Technology Data Exchange (ETDEWEB)

Hackley, Jason D.; Kislitsyn, Dmitry A.; Beaman, Daniel K.; Nazin, George V., E-mail: gnazin@uoregon.edu [Department of Chemistry and Biochemistry, 1253 University of Oregon, Eugene, Oregon 97403 (United States); Ulrich, Stefan [RHK Technology, Inc., 1050 East Maple Road, Troy, Michigan 48083 (United States)

2014-10-15

We report on the design and operation of a cryogenic ultra-high vacuum (UHV) scanning tunneling microscope (STM) coupled to a closed-cycle cryostat (CCC). The STM is thermally linked to the CCC through helium exchange gas confined inside a volume enclosed by highly flexible rubber bellows. The STM is thus mechanically decoupled from the CCC, which results in a significant reduction of the mechanical noise transferred from the CCC to the STM. Noise analysis of the tunneling current shows current fluctuations up to 4% of the total current, which translates into tip-sample distance variations of up to 1.5 picometers. This noise level is sufficiently low for atomic-resolution imaging of a wide variety of surfaces. To demonstrate this, atomic-resolution images of Au(111) and NaCl(100)/Au(111) surfaces, as well as of carbon nanotubes deposited on Au(111), were obtained. Thermal drift analysis showed that under optimized conditions, the lateral stability of the STM scanner can be as low as 0.18 Å/h. Scanning Tunneling Spectroscopy measurements based on the lock-in technique were also carried out, and showed no detectable presence of noise from the closed-cycle cryostat. Using this cooling approach, temperatures as low as 16 K at the STM scanner have been achieved, with the complete cool-down of the system typically taking up to 12 h. These results demonstrate that the constructed CCC-coupled STM is a highly stable instrument capable of highly detailed spectroscopic investigations of materials and surfaces at the atomic scale.

High-stability cryogenic scanning tunneling microscope based on a closed-cycle cryostat.

Science.gov (United States)

Hackley, Jason D; Kislitsyn, Dmitry A; Beaman, Daniel K; Ulrich, Stefan; Nazin, George V

2014-10-01

We report on the design and operation of a cryogenic ultra-high vacuum (UHV) scanning tunneling microscope (STM) coupled to a closed-cycle cryostat (CCC). The STM is thermally linked to the CCC through helium exchange gas confined inside a volume enclosed by highly flexible rubber bellows. The STM is thus mechanically decoupled from the CCC, which results in a significant reduction of the mechanical noise transferred from the CCC to the STM. Noise analysis of the tunneling current shows current fluctuations up to 4% of the total current, which translates into tip-sample distance variations of up to 1.5 picometers. This noise level is sufficiently low for atomic-resolution imaging of a wide variety of surfaces. To demonstrate this, atomic-resolution images of Au(111) and NaCl(100)/Au(111) surfaces, as well as of carbon nanotubes deposited on Au(111), were obtained. Thermal drift analysis showed that under optimized conditions, the lateral stability of the STM scanner can be as low as 0.18 Å/h. Scanning Tunneling Spectroscopy measurements based on the lock-in technique were also carried out, and showed no detectable presence of noise from the closed-cycle cryostat. Using this cooling approach, temperatures as low as 16 K at the STM scanner have been achieved, with the complete cool-down of the system typically taking up to 12 h. These results demonstrate that the constructed CCC-coupled STM is a highly stable instrument capable of highly detailed spectroscopic investigations of materials and surfaces at the atomic scale.

Probing the ground state and zero-field cooled exchange bias by magnetoresistance measurement in Mn{sub 50}Ni{sub 41}Sn{sub 9} ribbon

Energy Technology Data Exchange (ETDEWEB)

Chen, Jiyun [Jiangsu Laboratory of Advanced Functional Materials, Department of Physics, Changshu Institute of Technology, Changshu 215500 (China); School of Materials Science and Engineering, China University of Mining & Technology, Xuzhou 221116 (China); Tu, Ruikang [Jiangsu Laboratory of Advanced Functional Materials, Department of Physics, Changshu Institute of Technology, Changshu 215500 (China); School of Materials Science and Engineering, Soochow University, Suzhou 215000 (China); Fang, Xiaoting [Jiangsu Laboratory of Advanced Functional Materials, Department of Physics, Changshu Institute of Technology, Changshu 215500 (China); Gu, Quanchao [Jiangsu Laboratory of Advanced Functional Materials, Department of Physics, Changshu Institute of Technology, Changshu 215500 (China); School of Materials Science and Engineering, Soochow University, Suzhou 215000 (China); Zhou, Yanying [Jiangsu Laboratory of Advanced Functional Materials, Department of Physics, Changshu Institute of Technology, Changshu 215500 (China); Cui, Rongjing [Department of Chemistry, Changshu Institute of Technology, Changshu 215500 (China); Han, Zhida, E-mail: han@cslg.edu.cn [Jiangsu Laboratory of Advanced Functional Materials, Department of Physics, Changshu Institute of Technology, Changshu 215500 (China); Zhang, Lei; Fang, Yong [Jiangsu Laboratory of Advanced Functional Materials, Department of Physics, Changshu Institute of Technology, Changshu 215500 (China); Qian, Bin, E-mail: njqb@cslg.edu.cn [Jiangsu Laboratory of Advanced Functional Materials, Department of Physics, Changshu Institute of Technology, Changshu 215500 (China); Zhang, Chengliang [School of Science, Jiangnan University, Wuxi 214122 (China); Jiang, Xuefan [Jiangsu Laboratory of Advanced Functional Materials, Department of Physics, Changshu Institute of Technology, Changshu 215500 (China)

2017-03-15

Recently, a new type of exchange bias (EB) after zero-field cooling has attracted considerable interest mainly in bulk magnetic competing systems. Here, we use a detailed magnetotransport investigation to probe the ground state and zero-field cooled EB (ZEB) in Mn{sub 50}Ni{sub 41}Sn{sub 9} ribbon. Both ZEB and field cooled EB were detected in magnetoresistance results consistent with magnetic measurement. A pure spin-glass ground state is proposed based on parabolic shape of low-field magnetoresistance combined with AC magnetization, memory effect. The appearance of ZEB is attributed to the field-induced nucleation and growth of ferromagnetic domains in the spin glass matrix forming unidirectional anisotropy at the interface. - Highlights: • Magnetoresistance was first used to probe the ground state and ZEB in Ni-Mn-based alloys. • A pure spin-glass ground state is proposed in Mn{sub 50}Ni{sub 41}Sn{sub 9} ribbon. • Field-induced nucleation and growth of ferromagnetic domains in SG results in ZEB.

Arrival of the last cryostat for the ATLAS LAr calorimeter at CERN

CERN Multimedia

Aleksa, M; Oberlack, H

On Wednesday, 4th June the last cryostat for the ATLAS LAr calorimeter (end-cap A) arrived at CERN and was immediately unloaded from the truck in building 180 (see Figures 1 and 2), where the integration of the LAr calorimeters into their cryostats takes place. The transport from the Italian company SIMIC, where both end-cap calorimeters have been produced took longer than expected due to delays because of the G8 summit. Thanks to the great effort by the CERN Host State office and the French-German steering group that supplies the end-cap cryostat as an in-kind contribution to the LAr collaboration, an exceptional convoy was finally available and the cryostat could make its way to CERN. Fig.1 (left): Truck with the end-cap cryostat. Fig.2 (right): Unloading the cryostat in bldg. 180. Each end-cap cryostat will contain an electromagnetic calorimeter wheel, two wheels of a hadronic calorimeter, and a forward calorimeter. The design of the cryostat as a double vessel structure made of Aluminum fulfills t...

Design and construction of a high temperature superconducting power cable cryostat for use in railway system applications

International Nuclear Information System (INIS)

Tomita, M; Muralidhar, M; Suzuki, K; Fukumoto, Y; Ishihara, A; Akasaka, T; Kobayashi, Y

2013-01-01

The primary objective of the current effort was to design and test a cryostat using a prototype five-meter long high temperature Bi 2 Sr 2 Ca 2 Cu 3 O y (Bi-2223) superconducting dc power cable for railway systems. To satisfy the safety regulations of the Govt of Japan a mill sheet covered by super-insulation was used inside the walls of the cryostat. The thicknesses of various walls in the cryostat were obtained from a numerical analysis. A non-destructive inspection was utilized to find leaks under vacuum or pressure. The cryostat target temperature range was around 50 K, which is well below liquid nitrogen temperature, the operating temperature of the superconducting cable. The qualification testing was carried out from 77 down to 66 K. When using only the inner sheet wire, the maximum current at 77.3 K was 10 kA. The critical current (I c ) value increased with decreasing temperature and reached 11.79 kA at 73.7 K. This is the largest dc current reported in a Bi 2 Sr 2 Ca 2 Cu 3 O y or YBa 2 Cu 3 O y (Y-123) superconducting prototype cable so far. These results verify that the developed DC superconducting cable is reliable and fulfils all the requirements necessary for successful use in various power applications including railway systems. The key issues for the design of a reliable cryogenic system for superconducting power cables for railway systems are discussed. (paper)

Characteristic evaluation of cooling technique using liquid nitrogen and metal porous media

International Nuclear Information System (INIS)

Tanno, Yusuke; Ito, Satoshi; Hashizume, Hidetoshi

2014-01-01

A remountable high-temperature superconducting magnet, whose segments can be mounted and demounted repeatedly, has been proposed for construction and maintenance of superconducting magnet and inner reactor components of a fusion reactor. One of the issues in this design is that the performance of the magnet deteriorates by a local temperature rise due to Joule heating in jointing regions. In order to prevent local temperature rise, a cooling system using a cryogenic coolant and metal porous media was proposed and experimental studies have been carried out using liquid nitrogen. In this study, flow and heat transfer characteristics of cooling system using subcooled liquid nitrogen and bronze particle sintered porous media are evaluated through experiments in which the inlet degree of subcooling and flow rate of the liquid nitrogen. The flow characteristics without heat input were coincided with Ergun’s equation expressing single-phase flow in porous materials. The obtained boiling curve was categorized into three conditions; convection region, nucleate boiling region and mixed region with nucleate and film boiling. Wall superheat did not increase drastically with porous media after departure from nucleate boiling point, which is different from a situation of usual boiling curve in a smooth tube. The fact is important characteristic to cooling superconducting magnet to avoid its quench. Heat transfer coefficient with bronze particle sintered porous media was at least twice larger than that without the porous media. It was also indicated qualitatively that departure from nucleate boiling point and heat transfer coefficient depends on degree of subcooling and mass flow rate. The quantitative evaluation of them and further discussion for the cooling system will be performed as future tasks

Cryogenic cooling system for HTS cable

Energy Technology Data Exchange (ETDEWEB)

Yoshida, Shigeru [Taiyo Nippon Sanso, Tsukuba (Japan)

2017-06-15

Recently, Research and development activity of HTS (High Temperature Superconducting) power application is very progressive worldwide. Especially, HTS cable system and HTSFCL (HTS Fault current limiter) system are proceeding to practical stages. In such system and equipment, cryogenic cooling system, which makes HTS equipment cooled lower than critical temperature, is one of crucial components. In this article, cryogenic cooling system for HTS application, mainly cable, is reviewed. Cryogenic cooling system can be categorized into conduction cooling system and immersion cooling system. In practical HTS power application area, immersion cooling system with sub-cooled liquid nitrogen is preferred. The immersion cooling system is besides grouped into open cycle system and closed cycle system. Turbo-Brayton refrigerator is a key component for closed cycle system. Those two cooling systems are focused in this article. And, each design and component of the cooling system is explained.

Surface Quality Improvement of AA6060 Aluminum Extruded Components through Liquid Nitrogen Mold Cooling

Directory of Open Access Journals (Sweden)

Andrea Francesco Ciuffini

2018-06-01

Full Text Available 6xxx aluminum alloys are suitable for the realization of both structural applications and architectural decorative elements, thanks to the combination of high corrosion resistance and good surface finish. In areas where the aesthetic aspects are fundamental, further improvements in surface quality are significant. The cooling of the extrusion mold via internal liquid nitrogen fluxes is emerging as an important innovation in aluminum extrusion. Nowadays, this innovation is providing a large-scale solution to obtain high quality surface finishes in extruded aluminum semi-finished products. These results are also coupled to a significant increase in productivity. The aim of the work is to compare the surface quality of both cooled liquid nitrogen molds and classically extruded products. In this work, adhesion phenomena, occurring during the extrusion between the mold and the flowing material, have been detected as the main causes of the presence of surface defects. The analysis also highlighted a strong increase in the surface quality whenever the extrusion mold was cooled with liquid nitrogen fluxes. This improvement has further been confirmed by an analysis performed on the finished products, after painting and chromium plating. This work on the AA6060 alloy has moreover proceeded to roughness measurements and metallographic analyses, to investigate the eventual occurrence of other possible benefits stemming from this new extrusion mold cooling technology.

Laser sub-Doppler cooling of atoms in an arbitrarily directed magnetic field

International Nuclear Information System (INIS)

Chang, Soo; Kwon, Taeg Yong; Lee, Ho Seong; Minogin, V.G.

2002-01-01

We analyze the influence of an arbitrarily directed uniform magnetic field on the laser sub-Doppler cooling of atoms. The analysis is done for a (3+5)-level atom excited by a σ + -σ - laser field configuration. Our analysis shows that the effects of the magnetic field depend strongly on the direction of the magnetic field. In an arbitrarily directed magnetic field the laser cooling configuration produces both the main resonance existing already at zero magnetic field and additional sub-Doppler resonances caused by two-photon and higher-order multiphoton processes. These sub-Doppler resonances are, however, well separated on the velocity scale if the Zeeman shift exceeds the widths of the resonances. This allows one to use the main sub-Doppler resonance for an effective laser cooling of atoms even in the presence of the magnetic field. The effective temperature of the atomic ensemble at the velocity of the main resonance is found to be almost the same as in the absence of the magnetic field. The defined structure of the multiphoton resonances may be of importance for the sub-Doppler laser cooling of atoms, atomic extraction from magneto-optical traps, and applications related to the control of atomic motion

Conceptual & Engineering Design of Plug-in Cryostat Cylinder for Super-Conducting Central Solenoid of SST-1

Science.gov (United States)

Biswas, Prabal; Santra, Prosenjit; Vasava, Kirit; Jayswal, Snehal; Parekh, Tejas; Chauhan, Pradeep; Patel, Hitesh; Pradhan, Subrata

2017-04-01

SST-1, country’s first indigenously built steady state super-conducting tokamak is planned to be equipped with an Nb3Sn based superconducting central solenoid, which will replace the existing copper conductor TR1 coil for the purpose of Ohmic breakdown. This central solenoid (CS) of four layers with each layer having 144 turns with an OD of 573 mm, ID of 423 mm length of 2483 mm will be housed inside a high vacuum, CRYO compatible plug-in cryostat thin shell having formed from SS 304L plate duly rolled and welded to form cylinder along with necessary accessories like LN2 bubble panel, current lead chamber, coil and cylinder support structure etc. This paper will present the design drivers, material selection, advantages and constraints of the plug-in cryostat concept, sub-systems of plug-in cryostat, its conceptual and engineering design, CAD models, finite element analysis using ANSYS, safety issues and diagnostics, on-going works about fabrication, quality assurance/control and assembly/integration aspects with in the existing SST-1 machine bore.

Effects of SO/sub 2/ on photosynthesis and nitrogen fixation

Energy Technology Data Exchange (ETDEWEB)

Haellgren, J E; Huss, K

1975-06-15

Responses of photosynthesis and nitrogen fixation to NaHSO/sub 3/ (10/sup -5/ to 5 x 10/sup -3/ M) were investigated in the lichen Stereocaulon paschale (L.) Fr. and the blue-green alga Anabaena cylindrica Lemmermann. The treatments were performed in buffered media with varying pH (5.8 to 8.1) and light conditions (0 to 32 W x m/sup -2/). The activities of the intact organisms were investigated, under the same environmental conditions, with /sup 14/C liquid scintillation and acetylene reduction techniques respectively. The nitrogen fixation proved to be more susceptible than photosynthesis, in both organisms, and in all cases treatments at pH 5.8 were more inhibitory than at higher pH-values. Treatment with 5 x 10/sup -4/ M NaHSO/sub 3/ at pH 5.8 caused no reduction of photosynthesis in S. paschale, while the inhibition of nitrogen fixation was 97%. For A. cylindrica the corresponding values were 40% and 75% respectively. Short-time treatments of A. cylindrica showed that the nitrogen fixation was more rapidly affected than photosynthesis. The inhibition of nitrogenase activity and CO/sub 2/-fixation was smaller in the dark and increased at higher light intensities. Both processes showed a good capacity for recovery after removal of the NaHSO/sub 3/ solution. Also the clumping ability of A. cylindrica was disturbed by NaHSO/sub 3/ treatments.

Construction of an ultra low temperature cryostat and transverse acoustic spectroscopy in superfluid helium-3 in compressed aerogels

Science.gov (United States)

Bhupathi, Pradeep

An ultra low temperature cryostat is designed and implemented in this work to perform experiments at sub-millikelvin temperatures, specifically aimed at understanding the superfluid phases of 3He in various scenarios. The cryostat is a combination of a dilution refrigerator (Oxford Kelvinox 400) with a base temperature of 5.2 mK and a 48 mole copper block as the adiabatic nuclear demagnetization stage with a lowest temperature of ≈ 200 muK. With the various techniques implemented for limiting the ambient heat leak to the cryostat, we were able to stay below 1 mK for longer than 5 weeks. The details of design, construction and performance of the cryostat are presented. We measured high frequency shear acoustic impedance in superfluid 3He in 98% porosity aerogel at pressures of 29 bar and 32 bar in magnetic fields upto 3 kG with the aerogel cylinder compressed along the symmetry axis to generate global anisotropy. With 5% compression, there is an indication of a supercooled A-like to B-like transition in aerogel in a wider temperature width than the A phase in the bulk, while at 10% axial compression, the A-like to B-like transition is absent on cooling down to ≈ 300 muK in zero magnetic field and in magnetic fields up to 3 kG. This behavior is in contrast to that in 3He in uncompressed aerogels, in which the supercooled A-like to B-like transitions have been identified by various experimental techniques. Our result is consistent with theoretical predictions. To characterize the anisotropy in compressed aerogels, optical birefringence is measured in 98% porosity silica aerogel samples subjected to various degrees of uniaxial compression up to 15% strain, with wavelengths between 200 to 800 nm. Uncompressed aerogels exhibit no or a minimal degree of birefringence, indicating the isotropic nature of the material over the length scale of the wavelength. Uniaxial compression of aerogel introduces global anisotropy, which produces birefringence in the material. We

Nitrogen Cycling in Agroforestry Systems of Sub-humid Zimbabwe: Closing the loop

NARCIS (Netherlands)

Chikowo, R.

2004-01-01

Keywords: improved fallows, biological N <sub>2sub> -fixation, nitrogen cycling, nitrate leaching, oxide emissions, N mineralization -immobilization, granitic sandsThis thesis focuses on nitrogen: its

Simulation of the Compact Ignition Tokamak (CIT) conceptual design

International Nuclear Information System (INIS)

Carlson, K.E.; Wareing, T.L.

1988-01-01

Calculations have been made using the Advanced Thermal Hydraulic Energy Network Analysis (ATHENA) code that simulate the cool down of the cryostat and the performance of the condensing heat exchanger. The purpose of this simulation was to confirm the estimated 30 minute cool down time and to size a condensing heat exchanger for the CIT liquid nitrogen cooling system. This report includes a brief description of the ATHENA code, descriptions of proposed CIT cryostat and condenser designs, and the associated ATHENA models representing these design. This is followed by the ATHENA calculated results and conclusions concerning the results. 6 refs., 17 figs

Feasibility analysis of gas turbine inlet air cooling by means of liquid nitrogen evaporation for IGCC power augmentation

International Nuclear Information System (INIS)

Morini, Mirko; Pinelli, Michele; Spina, Pier Ruggero; Vaccari, Anna; Venturini, Mauro

2015-01-01

Integrated Gasification Combined Cycles (IGCC) are energy systems mainly composed of a gasifier and a combined cycle power plant. Since the gasification process usually requires oxygen as the oxidant, an Air Separation Unit (ASU) is also part of the plant. In this paper, a system for power augmentation in IGCC is evaluated. The system is based on gas turbine inlet air cooling by means of liquid nitrogen spray. In fact, nitrogen is a product of the ASU, but is not always exploited. In the proposed plant, the nitrogen is first liquefied to be used for inlet air cooling or stored for later use. This system is not characterized by the limits of water evaporative cooling systems (the lower temperature is limited by air saturation) and refrigeration cooling (the effectiveness is limited by the pressure drop in the heat exchanger). A thermodynamic model of the system is built by using a commercial code for energy conversion system simulation. A sensitivity analysis on the main parameters is presented. Finally the model is used to study the capabilities of the system by imposing the real temperature profiles of different sites for a whole year and by comparing to traditional inlet air cooling strategies. - Highlights: • Gas turbine inlet air cooling by means of liquid nitrogen spray. • Humidity condensation may form a fog which provides further power augmentation. • High peak and off peak electric energy price ratios make the system profitable

The structure analysis of ITER cryostat based on the finite element method

International Nuclear Information System (INIS)

Liang Chao; Ye, M.Y.; Yao, D.M.; Cao, Lei; Zhou, Z.B.; Xu, Teijun; Wang Jian

2013-01-01

In the ITER project the cryostat is one of the most important components. Cryostat shall transfer all the loads that derive from the TOKAMAK inner basic machine, and from the cryostat itself, to the floor of the TOKAMAK pit (during the normal and off-normal operational regimes, and at specified accidental conditions). This paper researches the dynamic structure strength of the ITER cryostat during the operation of TOKAMAK. Firstly the paper introduces the types of loads and the importance of every type load to the research. Then it gives out the method of building model and principle of simplified model, boundary conditions and the way of applying loads on the cryostat. Finally the author discussed the analysis result and the strength questions of cryostat, also, the author pointed out the opinions according to the analysis results.

Cycle Design of Reverse Brayton Cryocooler for HTS Cable Cooling Using Exergy Analysis

Science.gov (United States)

Gupta, Sudeep Kumar; Ghosh, Parthasarathi

2017-02-01

The reliability and price of cryogenic refrigeration play an important role in the successful commercialization of High Temperature Superconducting (HTS) cables. For cooling HTS cable, sub-cooled liquid nitrogen (LN2) circulation system is used. One of the options to maintain LN2 in its sub-cooled state is by providing refrigeration with the help of Reverse Brayton Cryo-cooler (RBC). The refrigeration requirement is 10 kW for continuously sub-cooling LN2 from 72 K to 65 K for cooling 1 km length of HTS cable [1]. In this paper, a parametric evaluation of RBC for sub-cooling LN2 has been performed using helium as a process fluid. Exergy approach has been adopted for this analysis. A commercial process simulator, Aspen HYSYS® V8.6 has been used for this purpose. The critical components have been identified and their exergy destruction and exergy efficiency have been obtained for a given heat load condition.

A second-generation superconducting undulator cryostat for the APS

Science.gov (United States)

Fuerst, J.; Hasse, Q.; Ivanyushenkov, Y.; Kasa, M.; Shiroyanagi, Y.

2017-12-01

A second-generation cryocooler-based cryostat has been designed and built to support a new helically wound superconducting undulator (SCU) magnet for the Advanced Photon Source (APS) at Argonne National Laboratory (ANL). The design represents an evolution of existing SCU cryostats currently in operation in the APS storage ring. Value engineering and lessons learned have resulted in a smaller, cheaper, and simpler cryostat design compatible with existing planar magnets as well as the new helically wound device. We describe heat load and quench response results, design and operational details, and the “build-to-spec” procurement strategy.

Proposed sub-criticality level for an 80 MWTHd-bismuth-cooled Ads

International Nuclear Information System (INIS)

Mansani, L.; Monti, R.; Neuhold, P.

2003-01-01

The degree of operational sub-criticality of an Accelerator-driven System (ADS) on the one hand directly affects key accelerator system parameters, such as the proton beam current required to sustain the selected rated power level and, on the other, the likelihood of approaching or attaining criticality under abnormal or accident conditions. Then, if in all such conditions the safety goal is pursued to design the sub-critical core so that it stays away from criticality with adequate margin, the required operational sub-criticality level must be determined by a properly balanced approach between excessively demanding accelerator system performances and risk of accidental criticality. The approach must necessarily include evaluation and appropriate combination of the relevant reactivity effects (e.g. from system cool-down, postulated accident scenarios, geometrical variations) and proper consideration of specific design features (such as, for instance, the absence of safety rods, intended as neutron absorbing devices having a role equivalent to the shutdown rods in critical reactors). The paper presents a possible approach to the determination of the operational sub-criticality level of an 80 MWth Lead-Bismuth-cooled pool type ADS, initially conceived and developed by a team of Italian Organisations led by Ansaldo, with funding from the Ministry of University and Scientific and Technological Research, and currently in the process of being assessed, versus a gas-cooled concept, in the frame of a contract with the Commission of the European Communities. After a brief description of the Lead-Bismuth-cooled ADS concept relevant features and of the key safety goals in terms of required sub-criticality margin, the evaluated reactivity effects are presented, a method to combine them is discussed and a proposed operational sub-criticality level is derived. (author)

Development of the Facet Cryostat

Science.gov (United States)

Nash, A.; Shields, P.; Jirmanus, M.

1999-01-01

A proof of concept prototype cryostat has been developed to demonstrate the ability to accommodate low temperature science investigations within the constraints of the Hitchhiker siderail carrier on the Space Shuttle.

Altering the cooling rate dependence of phase formation during rapid solidification in the Nd{sub 2}Fe{sub 14}B system

Energy Technology Data Exchange (ETDEWEB)

Branagan, D.J. [USDOE, Ames, IA (United States). Ames Lab.]|[Iowa State Univ. of Science and Technology, Ames, IA (United States). Dept. of Materials Science and Engineering; McCallum, R.W. [USDOE, Ames, IA (United States). Ames Lab.]|[Iowa State Univ. of Science and Technology, Ames, IA (United States). Dept. of Materials Science and Engineering

1995-04-26

In order to evaluate the effects of additions on the solidification behavior of Nd{sub 2}Fe{sub 14}B, a stoichiometric alloy was modified with elemental additions of Ti or C and a compound addition of Ti with C. For each alloy, a series of wheel speed runs was undertaken, from which the optimum wheel speeds and optimum energy products were determined. On the BH{sub max} versus wheel speed plots, regions were identified in order to analyze the changes with cooling rates leading to phase formation brought about by the alloy modifications. The compilation of the regional data of the modified alloys showed their effects on altering the cooling rate dependence of phase formation. It was found that the regions of properitectic iron formation, glass formation, and the optimum cooling rate can be changed by more than a factor of two through appropriate alloying additions. The effects of the alloy modifications can be visualized in a convenient fashion through the use of a model continuous cooling transformation (CCT) diagram which represents phase formation during the solidification process under continuous cooling conditions for a wide range of cooling rates from rapid solidification to equilibrium cooling. ((orig.)).

European standardization activities on safety of liquid helium cryostats

CERN Multimedia

CERN. Geneva

2016-01-01

This talk gives a general overview on the challenges of designing safety units for liquid helium cryostats with regard to existing industry standards. It reviews the work of a national working group that published the technical guideline DIN SPEC 4683 in April 2015, which is dedicated to the particular conditions in liquid helium cryostats. Based on both this guideline and equivalent documents from e.g. CEA, CERN, a working group is being formed at the European Committee for Standardization, associated to CEN/TC 268, which will work on a European standard on safety of liquid helium cryostats. The actual status and the schedule of this project are presented.

Safety analysis results for cryostat ingress accidents in ITER

International Nuclear Information System (INIS)

Merrill, B.J.; Cadwallader, L.C.; Petti, D.A.

1996-01-01

Accidents involving the ingress of air or water into the cryostat of the International Thermonuclear Experimental Reactor (ITER) tokamak design have been analyzed with a modified version of the MELCOR code for the ITER Non-site Specific Safety Report (NSSR-1). The air ingress accident is the result of a postulated breach of the cryostat boundary into an adjoining room. MELCOR results for this accident demonstrate that the condensed air mass and increased heat loads are not a magnet safety concern, but that the partial vacuum in the adjoining room must be accommodated in the building design. The water ingress accident is the result of a postulated magnet arc that results in melting of a Primary Heat Transport System (PHTS) coolant pipe, discharging PHTS water and PHTS water activated corrosion products and HTO into the cryostat. MELCOR results for this accident demonstrate that the condensed water mass and increased heat loads are not a magnet safety concern, that the cryostat pressure remains below design limits, and that the corrosion product and HTO releases are well within the ITER release limits

PCU arrangement of a supercritical CO{sub 2} cooled micro modular reactor

Energy Technology Data Exchange (ETDEWEB)

Kim, Seong Gu; Baik, Seungjoon; Cho, Seong Kuk; Oh, Bong Seong; Lee, Jeong Ik [KAIST, Daejeon (Korea, Republic of)

2016-05-15

As part of the SMR(Small Modular Reactor)s development effort, the authors propose a concept of supercritical CO{sub 2} (S-CO{sub 2}) cooled fast reactor combined with the S-CO{sub 2} Brayton cycle. The reactor concept is named as KAIST Micro Modular Reactor (MMR). The S-CO{sub 2} Brayton cycle has many strong points when it is used for SMR's power conversion unit. It occupies small footprints due to the compact cycle components and simple layout. Thus, a concept of one module containing the S-CO{sub 2} cooled fast reactor and power conversion system is possible. This module can be shipped via ground transportation (by trailer) or marine transportation. In this study, the authors propose a new conceptual layout for the S-CO{sub 2} cooled direct cycle while considering various issues for arranging cycle components. The new design has an improved cycle efficiency (from 31% to 34%) than the earlier version of MMR by reducing pressure drops in the heat exchangers. As a more efficient option, a recompression recuperated cycle was also designed. It improves 5% of thermal efficiency while 18tons of mass can be added in comparison to the simple recuperated cycle. Even if we adopt recompression cycle as a PCU, the weight of module (152tons) is less than the ground transportable limit (260tons)

Comparison of methods for cryostating superconducting dipole magnets

International Nuclear Information System (INIS)

Son Zun Gan; Filippov, Yu.P.; Zinchenko, S.I.

1985-01-01

An attempt is made to refine basic parameters of the UNK cryogenic system with account of real characteristics of horizontal two-phase helium flows and to project ways of optimizing these parameters. The method 1 where liquid helium in the state close to saturation is supplied to the chain of magnets and removes heat releasing in coils and coming from environment at the expense of phase transformation and it leaves the chain as vapour-liquid mixture, is compared with the method 2 where magnet cooling is arranged at the expense of heat transfer from one-phase direct flow to two-phase helium counter flow. The results of calculations are presented as dependences of maximum temperatures of coils on the length of magnetic path. It is shown that at the length of chain of about 300-400 m both methods are practically equivalent by temperature criterion, but the method 1 is preferable due to simpler design of the cryostat and lesser helium quantity in the system

Effect of cooling rate on the phase structure and magnetic properties of Fe{sub 26.7}Co{sub 28.5}Ni{sub 28.5}Si{sub 4.6}B{sub 8.7}P{sub 3} high entropy alloy

Energy Technology Data Exchange (ETDEWEB)

Wei, Ran; Sun, Huan; Chen, Chen [School of Materials Science and Engineering, Zhengzhou University, Zhengzhou 450001 (China); Han, Zhenhua [School of Materials Science and Engineering, Xi’an University of Technology, Xi’an 710068 (China); Li, Fushan, E-mail: fsli@zzu.edu.cn [School of Materials Science and Engineering, Zhengzhou University, Zhengzhou 450001 (China)

2017-08-01

Highlights: • High entropy alloy with amorphous phase and FCC solid solution phase are successfully developed respectively. • The amorphous phase exhibits better soft magnetic properties than that of the solid solution phase. • The BCC phase transformed into FCC phase, and then into BCC phase was found in this HEA. - Abstract: The effect of cooling rate on phase structure and magnetic properties of the Fe{sub 26.7}Co{sub 28.5}Ni{sub 28.5}Si{sub 4.6}B{sub 8.7}P{sub 3} high entropy alloy (HEA) was investigated. The HEA forms into amorphous phase by melt spinning method at high cooling rate and FCC solid solution phase at low cooling rate. The soft magnetic properties of the amorphous phase (saturation magnetization B{sub s} of 1.07T and coercivity H{sub c} of 4 A/m) are better than that of the solid solution phase (B{sub s} of 1.0 T and H{sub c} of 168 A/m). In order to study the phase evolution of the present HEA, anneal experiments were conducted. It is found that crystallization products of amorphous phase are solid solution phase which constitute much of FCC and a small amount of BCC. BCC phase transforms into FCC phase, and then into BCC phase with the increase of annealing temperature.

Influence of cooling and annealing procedure on the intergranular coupling of Ag-Bi[sub 2]Sr[sub 2]CaCu[sub 2]O[sub x] screen-printed tape. [BiSrCaCuO

Energy Technology Data Exchange (ETDEWEB)

Noji, H; Zhou, W [IRC in Superconductivity, Univ. of Cambridge (United Kingdom); Glowacki, B A [IRC in Superconductivity, Univ. of Cambridge (United Kingdom) Dept. of Materials Science and Metallurgy, Univ. of Cambridge (United Kingdom); Oota, A [IRC in Superconductivity, Univ. of Cambridge (United Kingdom) Dept. of Electric and Electronic Engineering, Toyohashi Univ. of Tech. (Japan)

1993-02-01

A study of the influence of the processing conditions of screen-printed ''Bi-2212'' tapes on their intergranular coupling properties, measured by AC susceptibility and DC transport critical current density, has been conducted. Samples have been prepared by melt-solidification and sintering on silver substrates under the same conditions but with different cooling procedures, such as slow cooling, slow cooling and reannealing, rapid cooling and quenching. The cooling rate and the annealing procedure strongly affect not only the superconducting critical temperature, Tc, but also the intergranular coupling properties of the samples. It was found that the Tc value decreases with a decrease in cooling rate. The reannealing in N[sub 2] can improve the Tc value of the slow-cooled samples. The different cooling procedures lead to the crossover of the field dependence of the AC loss-peak temperature of [chi]'' characteristics for all investigated samples. The crossover phenomena do not alter the correlation between the transport critical current density, J[sub c], versus temperature and the AC loss-peak temperature versus AC applied field for the samples in the range of the LN[sub 2] temperature (90-65 K), except for the slow-cooled one. The lack of correlation for the slow-cooled sample in this temperature range can be explained by a very significant difference of flux creep between the slow-cooled sample and the rest of the fast-cooled or reannealed samples. (orig.).

Modification of band offsets of InGaZnO{sub 4}/Si heterojunction through nitrogenation treatment

Energy Technology Data Exchange (ETDEWEB)

Chen, X.F. [School of Physics and Materials Science, Radiation Detection Materials & Devices Lab, Anhui University, Hefei 230601 (China); He, G., E-mail: hegang@ahu.edu.cn [School of Physics and Materials Science, Radiation Detection Materials & Devices Lab, Anhui University, Hefei 230601 (China); National Laboratory for Infrared Physics, Chinese Academy of Sciences, Shanghai Institute of Technical Physics, 500 Yutian Road, Shanghai 200083 (China); Lv, J.G., E-mail: jglv@hftc.edu.cn [Department of Physics and Electronic Engineering, Hefei Normal University, Hefei 230061 (China); Liu, M., E-mail: mliu@issp.ac.cn [Key Laboratory of Materials Physics, Anhui Key Laboratory of Nanomaterials and Nanostructure, Institute of Solid State Physics, Chinese Academy of Sciences, Hefei 230031 (China); Wang, P.H. [School of Physics and Materials Science, Radiation Detection Materials & Devices Lab, Anhui University, Hefei 230601 (China); Chen, X.S. [National Laboratory for Infrared Physics, Chinese Academy of Sciences, Shanghai Institute of Technical Physics, 500 Yutian Road, Shanghai 200083 (China); Sun, Z.Q. [School of Physics and Materials Science, Radiation Detection Materials & Devices Lab, Anhui University, Hefei 230601 (China)

2015-10-25

The effect of nitrogen on the band offset of sputtering-derived InZnGaO{sub 4} (IGZO)/Si heterostructures has been systematically investigated by x-ray photoelectron spectroscopy (XPS) measurements. Elemental analysis indicates that nitrogen has been successfully incorporated into the IGZO film. By using In 3d{sub 5/2}, In 3d{sub 3/2} and Ga 3d core level (CL) XPS spectra as references, values of valence band offsets (ΔE{sub v}) of have been determined to be 2.56 ± 0.02 and 2.44 ± 0.02 eV for IGZO/Si and IGZO:N/Si heterojunctions, respectively. Using the experimental band gap of 3.59 and 3.50 eV of the IGZO/Si and IGZO:N/Si, the calculated values of conduction band offset (ΔE{sub c}) is 0.09 ± 0.01 and 0.06 ± 0.01 eV, respectively. The results indicate that nitrogen incorporation leads to the reduction in band gap and ΔE{sub v} and the slight effect on the ΔE{sub c} has also been detected. - Highlights: • α-IGZO/Si and α-IGZO:N/Si heterostructures have been obtained by sputtering. • Nitrogen dependent ΔE{sub v} and ΔE{sub v} have been determined by XPS measurements. • Nitrogen incorporation in IGZO leads to the reduced band gap and increased ΔE{sub v}. • Nitrogen incorporation has no apparent effect on the ΔE{sub c} of α-IGZO/Si.

Elastic properties of sub-stoichiometric nitrogen ion implanted silicon

Energy Technology Data Exchange (ETDEWEB)

Sarmanova, M.F., E-mail: marina.sarmanova@iom-leipzig.de [Leibniz Institute of Surface Modification, D-04318 Leipzig (Germany); Karl, H. [University Augsburg, Institute of Physics, D-86135 Augsburg (Germany); Mändl, S.; Hirsch, D. [Leibniz Institute of Surface Modification, D-04318 Leipzig (Germany); Mayr, S.G.; Rauschenbach, B. [Leibniz Institute of Surface Modification, D-04318 Leipzig (Germany); University Leipzig, Institute for Experimental Physics II, D-04103 Leipzig (Germany)

2015-04-15

Elastic properties of sub-stoichiometric nitrogen implanted silicon were measured with nanometer-resolution using contact resonance atomic force microscopy (CR-AFM) as function of ion fluence and post-annealing conditions. The determined range of indentation moduli was between 100 and 180 GPa depending on the annealing duration and nitrogen content. The high indentation moduli can be explained by formation of Si–N bonds, as verified by X-ray photoelectron spectroscopy.

A Dual Operational Refrigerator/Flow Cryostat with Wide Bore Medium Field Magnet for Application Demonstration

Science.gov (United States)

Young, E. A.; Bailey, W. O. S.; Al-Mosawi, M. K.; Beduz, C.; Yang, Y.; Chappell, S.; Twin, A.

Since stand alone cryocooler systems have become more widely available, there has been increased commercial interest in superconductor applications in the temperature range intermediate to liquid helium and liquid nitrogen. There are however few facilities that have large in-field bore size with variable temperatures. A large bore system can reduce costs associated with full scale demonstration magnets by testing smaller coils and qualify medium length (up to meters) conductors. A 5 T, wide bore, (170 mm) Nb3Sn Oxford Instrument magnet has been integrated into a custom built dual mode refrigerator/helium flow cryostat with 600A HTS current leads. In one mode the system can be used with zero field without cost of liquid helium relying for cooling on a Sumitomo GM cryocooler with 1.5W at 4.2K: (no He) this can be used either as the sole characterisation method, or as a preliminary check before more expensive and extensive measurements are taken. The first measurements using MgB2 wire from 10 to 20K were made using a transient current step of ∼5s duration, as opposed to a DC measurement. This has the advantage of not requiring thermal equilibrium to be achieved at nominal current. The feasibility of this technique for determining critical transport properties is discussed.

ITER In-Cryostat inspection and repair feasibility studies

International Nuclear Information System (INIS)

Reich, J.; Cordier, J.-J.; Houtte, D. van; Evrard, D.; Mercier, E.; Popa, T.; Doshi, B.

2011-01-01

The ITER In-Cryostat maintenance study is an important precondition to guarantee the operation over the ITER lifetime. The ITER operation is subdivided mainly into two phases: 1.Hydrogen phase (non-nuclear operation phase). 2.Deuterium/Tritium phase (nuclear DT phase). The commissioning phase includes the initial phase of assembly. Within the first phase the ITER components will be tested; afterwards they will go into operation. The In-Cryostat maintenance shall facilitate all operations that could be required by In-Cryostat systems and the Cryostat itself. In cases of failures or unlikely events (e.g. earthquakes) it is necessary to provide man and tool access to In-Cryostat components. Overall functions which have to be implemented are: ·Inspection of components including leak localization (helium, water, air). ·Repair and replacement of component (instrumentation, parts or complete components). ·Regulatory inspections. It is presumed that most of component failure would occur at the beginning of the operational phase. This failure rate is expected to be very unlikely when ITER is being operating during the nuclear phase. For maintenance activities it is assumed that: ·The intervention frequency on each component is limited during its lifetime (e.g. inspections/repair during global shutdown). ·Most of these interventions will be required during the inactive phase. According to ALARA (As Low as Reasonable Achievable) rules maintenance activities will be planned in order to minimize the required human interventions during the active phase. Different tools have to be designed to perform the maintenance actions. As there are quiet all heavy components to be handled and removed, humans cannot perform the work without semi hands-on tools. The required permanent fixtures and tools are considered and pre-designed.

ITER In-Cryostat inspection and repair feasibility studies

Energy Technology Data Exchange (ETDEWEB)

Reich, J., E-mail: Jens.Reich@iter.org [ITER Organization, CS 90 046, 13115 St Paul lez Durance Cedex (France); Cordier, J.-J.; Houtte, D. van [ITER Organization, CS 90 046, 13115 St Paul lez Durance Cedex (France); Evrard, D. [Sogeti High Tech, 180 rue Rene Descartes, 13857 Aix en Provence (France); Mercier, E. [AREVA CNIM KAH System Engineering Support, CS 50497, 13593 Aix en Provence Cedex 3 (France); Popa, T.; Doshi, B. [ITER Organization, CS 90 046, 13115 St Paul lez Durance Cedex (France)

2011-10-15

The ITER In-Cryostat maintenance study is an important precondition to guarantee the operation over the ITER lifetime. The ITER operation is subdivided mainly into two phases: 1.Hydrogen phase (non-nuclear operation phase). 2.Deuterium/Tritium phase (nuclear DT phase). The commissioning phase includes the initial phase of assembly. Within the first phase the ITER components will be tested; afterwards they will go into operation. The In-Cryostat maintenance shall facilitate all operations that could be required by In-Cryostat systems and the Cryostat itself. In cases of failures or unlikely events (e.g. earthquakes) it is necessary to provide man and tool access to In-Cryostat components. Overall functions which have to be implemented are: {center_dot}Inspection of components including leak localization (helium, water, air). {center_dot}Repair and replacement of component (instrumentation, parts or complete components). {center_dot}Regulatory inspections. It is presumed that most of component failure would occur at the beginning of the operational phase. This failure rate is expected to be very unlikely when ITER is being operating during the nuclear phase. For maintenance activities it is assumed that: {center_dot}The intervention frequency on each component is limited during its lifetime (e.g. inspections/repair during global shutdown). {center_dot}Most of these interventions will be required during the inactive phase. According to ALARA (As Low as Reasonable Achievable) rules maintenance activities will be planned in order to minimize the required human interventions during the active phase. Different tools have to be designed to perform the maintenance actions. As there are quiet all heavy components to be handled and removed, humans cannot perform the work without semi hands-on tools. The required permanent fixtures and tools are considered and pre-designed.

Transfer Efficiency and Cooling Cost by Thermal Loss based on Nitrogen Evaporation Method for Superconducting MAGLEV System

Science.gov (United States)

Chung, Y. D.; Kim, D. W.; Lee, C. Y.

2017-07-01

This paper presents the feasibility of technical fusion between wireless power transfer (WPT) and superconducting technology to improve the transfer efficiency and evaluate operating costs such as refrigerant consumption. Generally, in WPT technology, the various copper wires have been adopted. From this reason, the transfer efficiency is limited since the copper wires of Q value are intrinsically critical point. On the other hand, as superconducting wires keep larger current density and relatively higher Q value, the superconducting resonance coil can be expected as a reasonable option to deliver large transfer power as well as improve the transfer ratio since it exchanges energy at a much higher rate and keeps stronger magnetic fields out. However, since superconducting wires should be cooled indispensably, the cooling cost of consumed refrigerant for resonance HTS wires should be estimated. In this study, the transmission ratios using HTS resonance receiver (Rx) coil and various cooled and noncooled copper resonance Rx coils were presented under non cooled copper antenna within input power of 200 W of 370 kHz respectively. In addition, authors evaluated cooling cost of liquid nitrogen for HTS resonance coil and various cooled copper resonance coils based on nitrogen evaporation method.

Transfer Efficiency and Cooling Cost by Thermal Loss based on Nitrogen Evaporation Method for Superconducting MAGLEV System

International Nuclear Information System (INIS)

Chung, Y D; Kim, D W; Lee, C Y

2017-01-01

This paper presents the feasibility of technical fusion between wireless power transfer (WPT) and superconducting technology to improve the transfer efficiency and evaluate operating costs such as refrigerant consumption. Generally, in WPT technology, the various copper wires have been adopted. From this reason, the transfer efficiency is limited since the copper wires of Q value are intrinsically critical point. On the other hand, as superconducting wires keep larger current density and relatively higher Q value, the superconducting resonance coil can be expected as a reasonable option to deliver large transfer power as well as improve the transfer ratio since it exchanges energy at a much higher rate and keeps stronger magnetic fields out. However, since superconducting wires should be cooled indispensably, the cooling cost of consumed refrigerant for resonance HTS wires should be estimated. In this study, the transmission ratios using HTS resonance receiver (Rx) coil and various cooled and noncooled copper resonance Rx coils were presented under non cooled copper antenna within input power of 200 W of 370 kHz respectively. In addition, authors evaluated cooling cost of liquid nitrogen for HTS resonance coil and various cooled copper resonance coils based on nitrogen evaporation method. (paper)

Influence of sulfur and nitrogen supply on the susceptibility of Pisum sativum to SO/sub 2/

Energy Technology Data Exchange (ETDEWEB)

Klein, H; Jaeger, H J; Steubing, L

1974-01-01

The susceptibility of Pisum to SO/sub 2/ injury was examined in relation to the sulfur and nitrogen nutrition. The injury was measured by comparing the dry matter yield to control and treated plants. SO/sub 2/ effects on metabolism were established by determining the content of organic and inorganic sulfur and, indirectly, by measuring total nitrogen, amino acid nitrogen, and protein nitrogen. The plants grown in nutrient solutions deficient in sulfur or nitrogen showed a decreased sensitivity to SO/sub 2/ pollution compared to the control. The higher content of amino acid nitrogen and organic sulfur of the plants grown in a nitrogen-deficient solution suggests that an increased synthesis of sulfur containing amino acids occurs. The slighter injury of the plants deficient in sulfur may be explained by the delayed sulfur supply.

A variable temperature cryostat that produces in situ clean-up germanium detector surfaces

International Nuclear Information System (INIS)

Pehl, R.H.; Madden, N.W.; Malone, D.F.; Cork, C.P.; Landis, D.A.; Xing, J.S.; Friesel, D.L.

1988-11-01

Variable temperature cryostats that can maintain germanium detectors at temperatures from 82 K to about 400 K while the thermal shield surrounding the detectors remains much colder when the detectors are warmed have been developed. Cryostats such as these offer the possibility of cryopumping material from the surface of detectors to the colder thermal shield. The diode characteristics of several detectors have shown very significant improvement following thermal cycles up to about 150 K in these cryostats. Important applications for cryostats having this attribute are many. 4 figs

CO{sub 2} removal potential of carbons prepared by co-pyrolysis of sugar and nitrogen containing compounds

Energy Technology Data Exchange (ETDEWEB)

Arenillas, A.; Drage, T.C.; Smith, K.; Snape, C.E. [University of Nottingham, Fuel Science Group, School of Chemical, Environmental and Mining Engineering, University Park, Nottingham NG7 2RD (United Kingdom)

2005-08-15

The nitrogen enrichment of active carbons is reported to be effective in enhancing the specific adsorbate-adsorbent interactions for CO{sub 2}. In this work, nitrogen-enriched carbons were prepared by co-pyrolysis of sugar and a series of nitrogen compounds with different nitrogen functionalities. The results show that although the amount of nitrogen incorporated to the final adsorbent is important, the N-functionality seems to be more relevant for increasing CO{sub 2} uptake. Thus, the adsorbent obtained from urea co-pyrolysis presents the highest nitrogen content but the lowest CO{sub 2} adsorption capacity. However, the adsorbent obtained from carbazole co-pyrolysis, despite the lower amount of N incorporated, shows high CO{sub 2} uptake, up to 9wt.%, probably because the presence of more basic functionalities as determined by XPS analysis.

Helical muon beam cooling channel engineering design

Energy Technology Data Exchange (ETDEWEB)

Johnson, Rolland [Muons, Inc., Batavia, IL (United States)

2015-08-07

The Helical Cooling Channel (HCC) achieves effective ionization cooling of the six-dimensional (6d) phase space of a muon beam by means of a series of 21st century inventions. In the HCC, hydrogen-pressurized RF cavities enable high RF gradients in strong external magnetic fields. The theory of the HCC, which requires a magnetic field with solenoid, helical dipole, and helical quadrupole components, demonstrates that dispersion in the gaseous hydrogen energy absorber provides effective emittance exchange to enable longitudinal ionization cooling. The 10-year development of a practical implementation of a muon-beam cooling device has involved a series of technical innovations and experiments that imply that an HCC of less than 300 m length can cool the 6d emittance of a muon beam by six orders of magnitude. We describe the design and construction plans for a prototype HCC module based on oxygen-doped hydrogen-pressurized RF cavities that are loaded with dielectric, fed by magnetrons, and operate in a superconducting helical solenoid magnet. The first phase of this project saw the development of a conceptual design for the integration of 805 MHz RF cavities into a 10 T Nb<sub>3sub>Sn-based HS test section. Two very novel ideas are required to realize the design. The first idea is the use of dielectric inserts in the RF cavities to make them smaller for a given frequency so that the cavities and associated plumbing easily fit inside the magnet cryostat. Calculations indicate that heat loads will be tolerable, while RF breakdown of the dielectric inserts will be suppressed by the pressurized hydrogen gas. The second new idea is the use of a multi-layer Nb<sub>3sub>Sn helical solenoid. The technology demonstrations for the two aforementioned key components of a 10T, 805 MHz HCC were begun in this project. The work load in the Fermilab Technical Division made it difficult to test a multi-layer Nb<sub>3sub>Sn solenoid as originally planned. Instead, a complementary

Design of the LHC US ATLAS Barrel Cryostat

CERN Document Server

Rehak, M L; Farah, Y; Grandinetti, R; Müller, T; Norton, S; Sondericker, J

2002-01-01

One of the experiments of CERN's Large Hadron Collider (LHC) is the ATLAS Liquid Argon detector. The Liquid Argon Barrel Cryostat is part of the United States contribution to the LHC project and its design is presented here. The device is made up of four concentric cylinders: the smallest and largest of which form a vacuum vessel enclosing a cold vessel cryostat filled with liquid argon. The Cryostat serves as the housing for an electromagnetic barrel calorimeter, supports and provides space in vacuum for a solenoid magnet while the toroidal opening furnishes room for a tracker detector. Design requirements are determined by its use in a collider experiment: the construction has to be compact, the material between the interaction region and the calorimeter has to be minimal and made of aluminum to reduce the amount of absorbing material. The design complies with code regulations while being optimized for its use in a physics environment. (2 refs).

Comparative Experiments to Assess the Effects of Accumulator Nitrogen Injection on Passive Core Cooling During Small Break LOCA

Directory of Open Access Journals (Sweden)

Li Yuquan

2017-02-01

Full Text Available The accumulator is a passive safety injection device for emergency core cooling systems. As an important safety feature for providing a high-speed injection flow to the core by compressed nitrogen gas pressure during a loss-of-coolant accident (LOCA, the accumulator injects its precharged nitrogen into the system after its coolant has been emptied. Attention has been drawn to the possible negative effects caused by such a nitrogen injection in passive safety nuclear power plants. Although some experimental work on the nitrogen injection has been done, there have been no comparative tests in which the effects on the system responses and the core safety have been clearly assessed. In this study, a new thermal hydraulic integral test facility—the advanced core-cooling mechanism experiment (ACME—was designed and constructed to support the CAP1400 safety review. The ACME test facility was used to study the nitrogen injection effects on the system responses to the small break loss-of-coolant accident LOCA (SBLOCA transient. Two comparison test groups—a 2-inch cold leg break and a double-ended direct-vessel-injection (DEDVI line break—were conducted. Each group consists of a nitrogen injection test and a nitrogen isolation comparison test with the same break conditions. To assess the nitrogen injection effects, the experimental data that are representative of the system responses and the core safety were compared and analyzed. The results of the comparison show that the effects of nitrogen injection on system responses and core safety are significantly different between the 2-inch and DEDVI breaks. The mechanisms of the different effects on the transient were also investigated. The amount of nitrogen injected, along with its heat absorption, was likewise evaluated in order to assess its effect on the system depressurization process. The results of the comparison and analyses in this study are important for recognizing and understanding the

Comparative experiments to assess the effects of accumulator nitrogen injection on passive core cooling during small break LOCA

Energy Technology Data Exchange (ETDEWEB)

Li, YuQuan; Hao, Botao; Zhong, Jia; Wan Nam [State Nuclear Power Technology R and D Center, South Park, Beijing Future Science and Technology City, Beijing (China)

2017-02-15

The accumulator is a passive safety injection device for emergency core cooling systems. As an important safety feature for providing a high-speed injection flow to the core by compressed nitrogen gas pressure during a loss-of-coolant accident (LOCA), the accumulator injects its precharged nitrogen into the system after its coolant has been emptied. Attention has been drawn to the possible negative effects caused by such a nitrogen injection in passive safety nuclear power plants. Although some experimental work on the nitrogen injection has been done, there have been no comparative tests in which the effects on the system responses and the core safety have been clearly assessed. In this study, a new thermal hydraulic integral test facility—the advanced core-cooling mechanism experiment (ACME)—was designed and constructed to support the CAP1400 safety review. The ACME test facility was used to study the nitrogen injection effects on the system responses to the small break loss-of-coolant accident LOCA (SBLOCA) transient. Two comparison test groups—a 2-inch cold leg break and a double-ended direct-vessel-injection (DEDVI) line break—were conducted. Each group consists of a nitrogen injection test and a nitrogen isolation comparison test with the same break conditions. To assess the nitrogen injection effects, the experimental data that are representative of the system responses and the core safety were compared and analyzed. The results of the comparison show that the effects of nitrogen injection on system responses and core safety are significantly different between the 2-inch and DEDVI breaks. The mechanisms of the different effects on the transient were also investigated. The amount of nitrogen injected, along with its heat absorption, was likewise evaluated in order to assess its effect on the system depressurization process. The results of the comparison and analyses in this study are important for recognizing and understanding the potential negative

Conceptual design of the inner cryostat support and jack

International Nuclear Information System (INIS)

Guarino, V.; Petereit, E.

1998-01-01

The Endcap Cryostat will be supported by the End Barrel Tilecalorimeter at four points. The outer support points will be carried by a structure that is external to the End Barrel modules while the inner support points will be directly on the modules. This paper concerns the design of these inner support points. The design parameters for the inner support points are: (1) must be able to support twice the front load from the Endcap Cryostat (70 tons); (2) the support point must make contact on the inner radius surface provided on the Endcap Cryostat; (3) vertical adjust must be allowed of up to ± 6mm; (4) the support must be a simple support; (5) the support must be contained within the envelope of one End Barrel submodule

Superconducting super collider second generation dipole magnet cryostat design

International Nuclear Information System (INIS)

Niemann, R.C.; Bossert, R.C.; Carson, J.A.; Engler, N.H.; Gonczy, J.D.; Larson, E.T.; Nicol, T.H.; Ohmori, T.

1988-12-01

The Superconducting Super Collider, a planned colliding beam particle physics research facility, requires /approximately/10,000 superconducting devices for the control of high energy particle beams. The /approximately/7,500 collider ring superconducting dipole magnets require cryostats that are functional, cryogenically efficient, mass producible and cost effective. A second generation cryostat design has been developed utilizing the experiences gained during the construction, installation and operation of several full length first generation dipole magnet models. The nature of the cryostat improvements is presented. Considered are the connections between the magnet cold mass and its supports, cryogenic supports, cold mass axial anchor, thermal shields, insulation, vacuum vessel and interconnections. The details of the improvements are enumerated and the abstracted results of available component and system evaluations are presented. 8 refs., 11 figs

Cryogenic system for TRISTAN superconducting RF cavities

International Nuclear Information System (INIS)

Hosoyama, K.; Hara, K.; Kabe, A.; Kojima, Y.; Ogitsu, T.; Sakamoto, Y.; Kawamura, S.; Matsumoto, K.

1993-01-01

A large cryogenic system has been designed, constructed and operated in the TRISTAN electron-positron collider at KEK for 508 MHz, 32x5-cell superconducting RF cavities. A 6.5 kW, 4.4 K helium refrigerator with 5 turbo-expanders on the ground level supplies liquid helium in parallel to the 16 cryostats in the TRISTAN tunnel through about 250 m long multichannel transfer line. Two 5-cell cavities are coupled together, enclosed in a cryostat and cooled by about 830 L pool boiling liquid helium. A liquid nitrogen circulation system with a turbo-expander has been adopted for 80 K radiation shields in the multichannel transfer line and the cryostats to reduce liquid nitrogen consumption and to increase the operation stability of the system. The cryogenic system has a total of about 18 000 hours of operating time from the first cool down test in August 1988 to November 1991. The design principle and outline of the cryogenic system and the operational experience are presented. (orig.)

The final cool down

CERN Multimedia

Thursday 29th May, the cool-down of the final sector (sector 4-5) of LHC has begun, one week after the start of the cool-down of sector 1-2. It will take five weeks for the sectors to be cooled from room temperature to 5 K and a further two weeks to complete the cool down to 1.9 K and the commissioning of cryogenic instrumentation, as well as to fine tune the cryogenic plants and the cooling loops of cryostats.Nearly a year and half has passed since sector 7-8 was cooled for the first time in January 2007. For Laurent Tavian, AT/CRG Group Leader, reaching the final phase of the cool down is an important milestone, confirming the basic design of the cryogenic system and the ability to operate complete sectors. “All the sectors have to operate at the same time otherwise we cannot inject the beam into the machine. The stability and reliability of the cryogenic system and its utilities are now very important. That will be the new challenge for the coming months,” he explains. The status of the cool down of ...

Comparison of heat transfer in liquid and slush nitrogen by numerical simulation of cooling rates for French straws used for sperm cryopreservation.

Science.gov (United States)

Sansinena, M; Santos, M V; Zaritzky, N; Chirife, J

2012-05-01

Slush nitrogen (SN(2)) is a mixture of solid nitrogen and liquid nitrogen, with an average temperature of -207 °C. To investigate whether plunging a French plastic straw (commonly used for sperm cryopreservation) in SN(2) substantially increases cooling rates with respect to liquid nitrogen (LN(2)), a numerical simulation of the heat conduction equation with convective boundary condition was used to predict cooling rates. Calculations performed using heat transfer coefficients in the range of film boiling confirmed the main benefit of plunging a straw in slush over LN(2) did not arise from their temperature difference (-207 vs. -196 °C), but rather from an increase in the external heat transfer coefficient. Numerical simulations using high heat transfer (h) coefficients (assumed to prevail in SN(2)) suggested that plunging in SN(2) would increase cooling rates of French straw. This increase of cooling rates was attributed to a less or null film boiling responsible for low heat transfer coefficients in liquid nitrogen when the straw is placed in the solid-liquid mixture or slush. In addition, predicted cooling rates of French straws in SN(2) tended to level-off for high h values, suggesting heat transfer was dictated by heat conduction within the liquid filled plastic straw. Copyright © 2012 Elsevier Inc. All rights reserved.

Synergistic effect of oxygen vacancy and nitrogen doping on enhancing the photocatalytic activity of Bi{sub 2}O{sub 2}CO{sub 3} nanosheets with exposed {0 0 1} facets for the degradation of organic pollutants

Energy Technology Data Exchange (ETDEWEB)

Zhang, Yafei [School of Physics and Information Technology, Shaanxi Normal University, Xi’an 710062 (China); Zhu, Gangqiang, E-mail: zgq2006@snnu.edu.cn [School of Physics and Information Technology, Shaanxi Normal University, Xi’an 710062 (China); Hojamberdiev, Mirabbos [School of Physics and Information Technology, Shaanxi Normal University, Xi’an 710062 (China); Department of Natural and Mathematic Sciences, Turin Polytechnic University in Tashkent, Kichik Halqa Yo’li 17, Tashkent 100095 (Uzbekistan); Gao, Jianzhi [School of Physics and Information Technology, Shaanxi Normal University, Xi’an 710062 (China); Hao, Jing [Xi' an Rejee Industry Development Co., Ltd., Xi’an 710016 (China); Zhou, Jianping; Liu, Peng [School of Physics and Information Technology, Shaanxi Normal University, Xi’an 710062 (China)

2016-05-15

Highlights: • Nitrogen-doped Bi{sub 2}O{sub 2}CO{sub 3} flower-like microstructures were synthesized by hydrothermal method. • Surface oxygen vacancy were obtained by irradiating the nitrogen-doped Bi{sub 2}O{sub 2}CO{sub 3} with UV light. • Photocatalytic activity was studied by degrading Rhodamine B. • A synergistic effect between oxygen vacancy and nitrogen doping in Bi{sub 2}O{sub 2}CO{sub 3}. - Abstract: Single-crystalline bare Bi{sub 2}O{sub 2}CO{sub 3} (BOC) nanosheets with exposed {0 0 1} facets and nitrogen-doped Bi{sub 2}O{sub 2}CO{sub 3} (NBOC) flower-like microstructures were synthesized by a simple hydrothermal method. The nitrogen-doped Bi{sub 2}O{sub 2}CO{sub 3} flower-like microstructures with oxygen vacancy (UV-NBOC) were obtained by irradiating the NBOC microstructures with UV light for 2 h in ethanol. The UV–vis diffuse reflectance spectra showed that the NBOC and UV-NBOC nanosheets exhibit an obvious red shift in light absorption band compared with the pure BOC nanosheets. Rhodamine B (RhB) was chosen as a model organic pollutant to verify the influence of oxygen vacancy and nitrogen doping on the photocatalytic activity of Bi{sub 2}O{sub 2}CO{sub 3} under simulated solar light irradiation. Judging from the kinetics of RhB photodegradation over the synthesized samples, a synergistic effect between oxygen vacancy and nitrogen doping was found with a remarkable increase (more than 10 and 2 times) in the photocatalytic activity of UV-NBOC compared with BOC and NBOC, respectively. Moreover, the UV-NBOC also exhibited an excellent cyclability and superior photocatalytic activity toward degradation of other organic pollutants (methylene blue, Congo red, Bisphenol A) under simulated solar light irradiation.

FORMATION OF N{sub 3}, CH{sub 3}, HCN, AND HNC FROM THE FAR-UV PHOTOLYSIS OF CH{sub 4} IN NITROGEN ICE

Energy Technology Data Exchange (ETDEWEB)

Lo, Jen-Iu; Chou, Sheng-Lung; Peng, Yu-Chain; Lin, Meng-Yeh; Lu, Hsiao-Chi; Cheng, Bing-Ming, E-mail: bmcheng@nsrrc.org.tw [National Synchrotron Radiation Research Center, No. 101, Hsin-Ann Road, Hsinchu Science Park, Hsinchu 30076, Taiwan (China)

2015-11-15

The irradiation of pure solid N{sub 2} at 3 K with far-ultraviolet light from a synchrotron produced infrared absorption lines at 1657.7, 1655.6, and 1652.4 cm{sup −1} and an ultraviolet absorption line at 272.0 nm, which are characteristic of the product N{sub 3}. The threshold wavelength at which N{sub 3} was generated was 145.6 ± 2.9 nm, corresponding to an energy of 8.52 ± 0.17 eV. The photolysis of isotopically labeled {sup 15}N{sub 2} at 3 K consistently led to the formation of {sup 15}N{sub 3} with the same threshold wavelength of 145.6 ± 2.9 nm for its formation. The photolysis of CH{sub 4} in nitrogen ice in low concentrations also led to the formation of N{sub 3}, together with CH{sub 3}, HCN, and HNC, with the same threshold wavelength of 145.6 ± 2.9 nm. These results indicate that N{sub 3} radicals may play an important role in the photochemistry of nitrogen ices in astronomical environments.

Effect of cooling to different sub-zero temperatures on boar sperm cryosurvival

OpenAIRE

Angelica Garcia-Olivares; Cesar Garzon-Perez; Oscar Gutierrez-Perez; Alfredo Medrano

2016-01-01

Objective: To compare different cooling temperatures before ice formation on pig sperm quality, before and after cryopreservation. Methods: Semen diluted in BF5 was cooled from 23 °C to 5 °C (1% glycerol, 200 × 106 cells/mL). Sperm were packaged in plastic straws, and maintained at +5 °C per 16 h. 1. Freezing point of diluted spermatozoa was determined by exposing straws to nitrogen vapors. 2. Straws (at +5 °C) were further cooled to −3 °C, −5 °C, and −7 °C, and rewarmed. 3. Straws (at +5 ...

Alternate design of ITER cryostat skirt support system

International Nuclear Information System (INIS)

Pandey, Manish Kumar; Gupta, Girish Kumar; Bhardwaj, Anil Kumar; Jha, Saroj Kumar

2015-01-01

The skirt support of ITER cryostat is a support system which takes all the load of cryostat cylinder and dome during normal and operational condition. The present design of skirt support has full penetration weld joints at the bottom (shell to horizontal plate joint). To fulfill the requirements of tolerances and control the welding distortions, we have proposed to change the full penetration weld into fillet weld. A detail calculation is done to check the feasibility and structural impact due to proposed design. The calculations provide the size requirements of fillet weld. To verify the structural integrity during most severe load case, finite element analysis (FEA) has been done in line with ASME section VIII division 2. By FEA 'Plastic Collapse' and 'Local Failure' modes has been assessed. 5° sector of skirt clamp has been modeled in CATIA V5 R21 and used in FEA. Fillet weld at shell to horizontal plate joint has been modeled and symmetry boundary condition at ± 2.5° applied. 'Elastic Plastic Analysis' has been performed for the most severe loading case i.e. Category IV loading. The alternate design of Cryostat Skirt support system has been found safe by analysis against Plastic collapse and Local Failure Modes with load proportionality factor 2.3. Alternate design of Cryostat skirt support system has been done and validated by FEA. As per alternate design, the proposal of fillet weld has been implemented in manufacturing. (author)

Structural and magnetocaloric properties of (Mn,Fe){sub 2}(P,Si) materials with added nitrogen

Energy Technology Data Exchange (ETDEWEB)

Thang, N.V., E-mail: v.t.nguyen-1@tudelft.nl; Miao, X.F., E-mail: X.F.Miao@tudelft.nl; Dijk, N.H. van, E-mail: N.H.vanDijk@tudelft.nl; Brück, E., E-mail: E.H.Bruck@tudelft.nl

2016-06-15

Amongst magnetic materials that exhibit a giant magnetocaloric effect near room temperature, the (Mn,Fe){sub 2}(P,Si) system is one of the most promising candidates for magnetic refrigeration. Although the (Mn,Fe){sub 2}(P,Si) materials hold many advantages, controlling the magnetic entropy change ΔS{sub m}, the adiabatic temperature change ΔT{sub ad}, the thermal hysteresis and the mechanical stability across the ferromagnetic transition requires a delicate tuning of the composition. This work investigates the addition of nitrogen, as an interstitial or substitutional element, as a new parameter to tune the properties of (Mn,Fe){sub 2}(P,Si) materials. We found that the nitrogen addition results in a decrease of the Curie temperature, consistent with the observed increase in the c/a ratio. The introduction of nitrogen in (Mn,Fe){sub 2}(P,Si) materials also results in a strong enhancement of the mechanical stability. - Highlights: • N-doped materials were synthesized by high-energy ball milling and solid-state reactions. • Nitrogen atoms enter the structure both as substitutional and as interstitial element in (Mn,Fe){sub 2}(P,Si) materials. • Nitrogen addition leads to a decrease in the Curie temperature, while improving the mechanical stability and preserving the magnetocaloric properties. • The origin of the increase in the thermal hysteresis by increasing the N content has been investigated by analyzing the XRD data.

A study on the barrier effect with respect to the condition of solid insulation materials in GN{sub 2}

Energy Technology Data Exchange (ETDEWEB)

Lee, Hong Seok; Mo, Young Kyu; Lee, On You; Kim, Jun Il; Bang, Seung Min; Kang, Jong O; Kang, Hyoung Ku [Dept. of Electrical Engineering, Korea National University of Transportation, Chungju (Korea, Republic of); Nam, Seo Ho [Dept. of Electrical and Electronic Engineering, Applied Superconductivity Lab., Yonsei University, Seoul (Korea, Republic of)

2015-03-15

High voltage superconducting apparatuses have been developed presently around the world under AC and DC sources. In order to improve electrical reliability of superconducting apparatuses with AC and DC networks, a study on the DC as well as the AC electrical breakdown characteristics of cryogenic insulations should be conducted for developing a high voltage superconducting apparatus. Recently, a sub-cooled liquid nitrogen cooling system is known to be promising method for developing a high voltage superconducting apparatus. A sub-cooled liquid nitrogen cooling system uses gaseous nitrogen to control the pressure and enhance the dielectric characteristics. However, the dielectric characteristics of gaseous nitrogen are not enough to satisfy the grade of insulation for a high voltage superconducting apparatus. In this case, the application of solid insulating barriers is regarded as an effective method to reinforce the dielectric characteristics of a high voltage superconducting apparatus. In this paper, it is dealt with a barrier effect on the DC and AC dielectric characteristics of gaseous nitrogen with respect to the position and number of solid insulating barriers. As results, the DC and AC electrical breakdown characteristics by various barrier effects is verified.

CO{sub 2} evaporative cooling: The future for tracking detector thermal management

Energy Technology Data Exchange (ETDEWEB)

Tropea, P., E-mail: paola.tropea@cern.ch [CERN, Geneva (Switzerland); Daguin, J.; Petagna, P.; Postema, H. [CERN, Geneva (Switzerland); Verlaat, B. [CERN, Geneva (Switzerland); Nikhef, Amsterdam (Netherlands); Zwalinski, L. [CERN, Geneva (Switzerland)

2016-07-11

In the last few years, CO{sub 2} evaporative cooling has been one of the favourite technologies chosen for the thermal management of tracking detectors at LHC. ATLAS Insertable B-Layer and CMS Pixel phase 1 upgrade have adopted it and their systems are now operational or under commissioning. The CERN PH-DT team is now merging the lessons learnt on these two systems in order to prepare the design and construction of the cooling systems for the new Upstream Tracker and the Velo upgrade in LHCb, due by 2018. Meanwhile, the preliminary design of the ATLAS and CMS full tracker upgrades is started, and both concepts heavily rely on CO{sub 2} evaporative cooling. This paper highlights the performances of the systems now in operation and the challenges to overcome in order to scale them up to the requirements of the future generations of trackers. In particular, it focuses on the conceptual design of a new cooling system suited for the large phase 2 upgrade programmes, which will be validated with the construction of a common prototype in the next years.

Sub-ambient carbon dioxide adsorption properties of nitrogen doped graphene

Energy Technology Data Exchange (ETDEWEB)

Tamilarasan, P.; Ramaprabhu, Sundara, E-mail: ramp@iitm.ac.in [Alternative Energy and Nanotechnology Laboratory (AENL), Nano Functional Materials Technology Centre (NFMTC), Department of Physics, Indian Institute of Technology Madras, Chennai 600036 (India)

2015-04-14

Carbon dioxide adsorption on carbon surface can be enhanced by doping the surface with heterogeneous atoms, which can increase local surface affinity. This study presents the carbon dioxide adsorption properties of nitrogen doped graphene at low pressures (<100 kPa). Graphene was exposed to nitrogen plasma, which dopes nitrogen atoms into carbon hexagonal lattice, mainly in pyridinic and pyrrolic forms. It is found that nitrogen doping significantly improves the CO{sub 2} adsorption capacity at all temperatures, due to the enrichment of local Lewis basic sites. In general, isotherm and thermodynamic parameters suggest that doped nitrogen sites have nearly same adsorption energy of surface defects and residual functional groups. The isosteric heat of adsorption remains in physisorption range, which falls with surface coverage, suggesting the distribution of magnitude of adsorption energy. The absolute values of isosteric heat and entropy of adsorption are slightly increased upon nitrogen doping.

Downward transfer of a sub-cooled cryoliquid

CERN Document Server

Wertelaers, P

2016-01-01

An alternative is proposed to the traditional transfer of a cryo fluid in gaseous -- and warm -- form, a method of low productivity and high energy cost. In order to prevent the much-feared geysering, focus is on sub-cooling of the liquid, and the safe maintaining of such state all along the journey. A cryogenic transfer line of simplest construction is proposed, and the difficulties with such line extending over a transfer depth of the order of the kilometre, are discussed.

Cryostats for SQUID magnetometers

International Nuclear Information System (INIS)

Testard, O.A.; Locatelli, M.

1982-05-01

A non metallic and non magnetic cryostat, with a very low thermal budget and a container type autonomy was developed, to condition S.Q.U.I.D. magnetometers which maximum sensitivity reaches 10 -14 Tesla Hertzsup(-1/2). This instrumentation puts in hand new concepts of composite materials, thermal shock and vibration resistant, multilayer thermal radiative insulation also to the prouve of vibrations with thermal equivalent emissivity lower than 10 -3

HL-LHC vertical cryostat during construction

CERN Multimedia

Lanaro, Andrea

2016-01-01

7m high "Cluster D" vertical test cryostat during construction at contractor's premises, Alca Technology Srl, in Schio, Italy. The inner helium vessel with its heat exchanger are visible. To be installed in the D pit in SMA18.

Application of nitrogen-doped TiO{sub 2} nano-tubes in dye-sensitized solar cells

Energy Technology Data Exchange (ETDEWEB)

Tran, Vy Anh; Truong, Trieu Thinh; Phan, Thu Anh Pham; Nguyen, Trang Ngoc [Faculty of Chemistry, University of Science, Vietnam National University, Ho Chi Minh City (Viet Nam); Huynh, Tuan Van [Faculty of Physics and Engineering Physics, University of Science, Vietnam National University, Ho Chi Minh City (Viet Nam); Agresti, Antonio; Pescetelli, Sara [CHOSE (Centre for Hybrid and Organic Solar Energy), Department of Electronic Engineering, University of Rome Tor Vergata (Italy); Le, Tien Khoa [Faculty of Chemistry, University of Science, Vietnam National University, Ho Chi Minh City (Viet Nam); Di Carlo, Aldo [CHOSE (Centre for Hybrid and Organic Solar Energy), Department of Electronic Engineering, University of Rome Tor Vergata (Italy); Lund, Torben [Department of Science and Environment, Roskilde University, DK-4000 (Denmark); Le, So-Nhu [Faculty of Chemistry, University of Science, Vietnam National University, Ho Chi Minh City (Viet Nam); Nguyen, Phuong Tuyet, E-mail: ngtuyetphuong@gmail.com [Faculty of Chemistry, University of Science, Vietnam National University, Ho Chi Minh City (Viet Nam)

2017-03-31

Highlights: • N-doped TiO{sub 2} nanotubes are synthesized by alkaline hydrothermal and reflux method. • Formation of TiO{sub 2} nanotube morphology and anatase phase is shown by TEM, XRD, Raman. • Coordination of NH{sub 4}{sup +} via Ti−O−NH{sub 4}{sup +} or H{sub 4}N{sup +}−Ti−O bonds is indicated by FT-IR and XPS. • Blocking effect of N-doped toward electron transfer on TiO{sub 2} anode is studied by CV. • N-doped TiO{sub 2} improved DSC performance up to 30–40% mainly due to an increase in J{sub sc}. - Abstract: Our research aimed to improve the overall energy conversion efficiency of DSCs by applying nitrogen-doped TiO{sub 2} nano-tubes (N-TNT) for the preparation of DSCs photo-anodes. The none-doped TiO{sub 2} nano-tubes (TNTs) were synthesized by alkaline hydrothermal treatment of Degussa P25 TiO{sub 2} particles in 10 M NaOH. The nano-tubes were N-doped by reflux in various concentrations of NH{sub 4}NO{sub 3}. The effects of nitrogen doping on the structure, morphology, and crystallography of N-TNT were analyzed by transmission electron microscopy (TEM), infrared spectroscopy (IR), Raman spectroscopy, and X-ray photoelectron spectra (XPS). DSCs fabricated with doped N-TNT and TNT was characterized by J-V measurements. Results showed that nitrogen doping significantly enhanced the efficiency of N-TNT cells, reaching the optimum value (η = 7.36%) with 2 M nitrogen dopant, compared to η = 4.75% of TNT cells. The high efficiency of the N-TNT cells was attributed to increased current density due to the reduction of dark current in the DSCs.

Formation of VO{sub 2} by rapid thermal annealing and cooling of sputtered vanadium thin films

Energy Technology Data Exchange (ETDEWEB)

Ba, Cheikhou O. F., E-mail: cheikhou.ba.1@ulaval.ca; Fortin, Vincent; Bah, Souleymane T.; Vallée, Réal [Centre d' optique, photonique et laser (COPL), Université Laval, Québec G1V 0A6 (Canada); Pandurang, Ashrit [Thin Films and Photonics Research Group (GCMP), Department of Physics and Astronomy, Université de Moncton, Moncton, New Brunswick E1A 3E9 (Canada)

2016-05-15

Sputtered vanadium-rich films were subjected to rapid thermal annealing-cooling (RTAC) in air to produce vanadium dioxide (VO{sub 2}) thin films with thermochromic switching behavior. High heating and cooling rates in the thermal oxidation process provided an increased ability to control the film's microstructure. X-ray diffraction patterns of the films revealed less intense VO{sub 2} peaks compared to traditional polycrystalline samples fabricated with a standard (slower) cooling time. Such films also exhibit a high optical switching reflectance contrast, unlike the traditional polycrystalline VO{sub 2} thin films, which show a more pronounced transmittance switching. The authors find that the RTAC process stabilizes the VO{sub 2} (M2) metastable phase, enabling a rutile-semiconductor phase transition (R-M2), followed by a semiconductor–semiconductor phase transition (M2-M1).

Hydrothermal synthesis of NiCo{sub 2}O{sub 4} nanowires/nitrogen-doped graphene for high-performance supercapacitor

Energy Technology Data Exchange (ETDEWEB)

Yu, Mei, E-mail: yumei@buaa.edu.cn; Chen, Jianpeng; Ma, Yuxiao; Zhang, Jingdan; Liu, Jianhua; Li, Songmei; An, Junwei

2014-09-30

Highlights: • NCO/NG composites were synthesized in a water–glycerol mixed solvent via hydrothermal treatment and subsequent calcination. • NiCo{sub 2}O{sub 4} nanowires are dispersed on NG nanosheets and the composite has porous structure. • The NCO/NG composite exhibits a high specific capacitance and long cycling performance. - Abstract: NiCo{sub 2}O{sub 4} nanowires/nitrogen-doped graphene (NCO/NG) composite materials were synthesized by hydrothermal treatment in a water–glycerol mixed solvent and subsequent thermal transformation. The obtained materials were characterized by X-ray diffraction, scanning electron microscopy, transmission electron microscopy, Fourier transform infrared spectroscopy and Raman spectroscopy. The electrochemical performance of the composites was evaluated by cyclic voltammetry, galvanostatic charge/discharge and electrochemical impedance spectrum techniques. NiCo{sub 2}O{sub 4} nanowires are densely coated by nitrogen-doped graphene and the composite displays good electrochemical performance. The maximum specific capacitance of NCO/NG is 1273.13 F g{sup −1} at 0.5 A g{sup −1} in 6 M KOH aqueous solution, and it exhibits good capacity retention without noticeable degradation after 3000 cycles at 4 A g{sup −1}.

Magnetic cooling close to a quantum phase transition—The case of Er{sub 2}Ti{sub 2}O{sub 7}

Energy Technology Data Exchange (ETDEWEB)

Wolf, B.; Tutsch, U.; Dörschug, S.; Krellner, C.; Ritter, F.; Assmus, W.; Lang, M. [Physikalisches Institut, Goethe Universität, SFB-TR49, 60438 Frankfurt (Germany)

2016-10-14

Magnetic cooling, first introduced in the late twenties of last century, has regained considerable interest recently as a cost-efficient and easy-to-handle alternative to {sup 3}He-based refrigeration techniques. Especially, adiabatic demagnetization of paramagnets—the standard materials for magnetic refrigeration—has become indispensable for the present space applications. To match the growing demand for increasing the efficiency in these applications, a new concept for magnetic cooling based on many-body effects around a quantum-critical-point has been introduced and successfully tested [B. Wolf et al., Proc. Natl. Acad. Sci. U.S.A. 108, 6862 (2011)]. By extending this concept to three-dimensional magnetic systems, we present here the magnetothermal response of the cubic pyrochlore material Er{sub 2}Ti{sub 2}O{sub 7} in the vicinity of its B-induced quantum-critical point which is located around 1.5 T. We discuss performance characteristics such as the range of operation, the efficiency, and the hold time. These figures are compared with those of state-of-the-art paramagnetic coolants and with other quantum-critical systems which differ by the dimensionality of the magnetic interactions and the degree of frustration.

Design of the multilayer insulation system for the Superconducting Super Collider 50mm dipole cryostat

International Nuclear Information System (INIS)

Boroski, W.N.; Nicol, T.H.; Schoo, C.J.

1991-03-01

The development of the multilayer insulation (MLI) system for the Superconducting Super Collider (SSC) 50 mm collider dipole cryostat is an ongoing extension of work conducted during the 40 mm cryostat program. While the basic design of the MLI system for the 50 mm cryostat resembles that of the 40 mm cryostat, results from measurements of MLI thermal performance below 80K have prompted a re-design of the MLI system for the 20K thermal radiation shield. Presented is the design of the MLI system for the 50 mm collider dipole cryostat, with discussion focusing on system performance, blanket geometry, cost-effective fabrication techniques, and built-in quality control measures that assure consistent thermal performance throughout the SSC accelerator. 16 refs., 8 figs., 2 tabs

Liquid nitrogen cooling considerations of the compact ignition tokamak

International Nuclear Information System (INIS)

Dabiri, A.E.

1986-01-01

An analytical procedure was developed to estimate the cooldown time between pulses of the Compact Ignition Tokamak (CIT) utilizing liquid nitrogen. Fairly good agreement was obtained between the analysis results and those measured in the early fusion experimental devices. The cooldown time between pulses in the CIT is controlled by the energy disposition in the inner leg of the TF coil. A cooldown time of less than one hour is feasible for the CIT if fins are used in the cooling channels. An R and D experimental program is proposed to determine the actual cooldown time between pulses since this would be considered an issue in the conceptual design of the CIT

The CEA JOSEFA test facility for sub-size conductors and joints

International Nuclear Information System (INIS)

Decool, P.; Libeyre, P.; Van Houtte, D.; Ciazynski, D.; Zani, L.; Serries, J.P.; Cloez, H.; Bej, S.

2003-01-01

The JOSEFA (Joint Sub-size Experiment FAcility) experimental test facility, installed at CEA/Cadarache is devoted to perform tests at cryogenic temperature on sub-size superconducting conductor and joint samples under parallel or transverse magnetic field. This facility was built in 1993 to investigate the performances of joints of cable-in-conduit conductors at sub-size level and further upgraded in the framework of European tasks. The samples of hairpin type using sub-size ITER conductors are cooled by a circulation of supercritical helium in a temperature range from 5 to 15 K and tested at a maximum current up to 10 kA. Two different helium bath cooled magnets allow to apply DC or AC transverse magnetic field up to 3.5 T or longitudinal magnetic field up to 7.5 T. A sliding system with a 240 mm stroke on the sample cryostat allows to test separately in the same sample either the conductor or the joint performances. The paper reports on how, through the conductor and joint development tasks, the facility performances were successfully increased and tested. The ITER TFMC joints using Nb3Sn conductors were first developed on this facility. The last developments, performed on ITER PF NbTi conductors and joints proved this facility to be a versatile and useful tool for superconducting magnet developments and showed the interest of possible upgrading to finalize conductor design. (author)

Model SSC [Superconducting Super Collider] dipole magnet cryostat assembly at Fermilab

International Nuclear Information System (INIS)

Niemann, R.C.

1989-03-01

The Superconducting Super Collider (SSC) magnet development program includes the design, fabrication and testing of full length model dipole magnets. A result of the program has been the development of a magnet cryostat design. The cryostat subsystems consist of cold mass connection-slide, suspension, thermal shields, insulation, vacuum vessel and interconnections. Design details are presented along with model magnet production experience. 6 refs., 13 figs

Structural analysis of the JT-60SA cryostat vessel body

Energy Technology Data Exchange (ETDEWEB)

Botija, José, E-mail: jose.botija@ciemat.es [Association EURATOM – CIEMAT, Avda. Complutense 40, 28040 Madrid (Spain); Alonso, Javier; Fernández, Pilar; Medrano, Mercedes; Ramos, Francisco; Rincon, Esther; Soleto, Alfonso [Association EURATOM – CIEMAT, Avda. Complutense 40, 28040 Madrid (Spain); Davis, Sam; Di Pietro, Enrico; Tomarchio, Valerio [Fusion for Energy, JT-60SA European Home Team, 85748 Garching bei Munchen (Germany); Masaki, Kei; Sakasai, Akira; Shibama, Yusuke [JAEA – Japan Atomic Energy Agency, Naka Fusion Institute, Ibaraki 311-0193 (Japan)

2013-10-15

Highlights: ► Structural analysis to validate the JT-60SA cryostat vessel body design. ► Design code ASME 2007 “Boiler and Pressure Vessel Code. Section VIII”. ► First buckling mode: load multiplier of 10.644, higher than the minimum factor 4.7. ► Elastic and elastic–plastic stress analysis meets ASME against plastic collapse. ► Bolted fasteners have been analyzed showing small gaps closed by strong welding. -- Abstract: The JT-60SA cryostat is a stainless steel vacuum vessel (14 m diameter, 16 m height) which encloses the Tokamak providing the vacuum environment (10{sup −3} Pa) necessary to limit the transmission of thermal loads to the components at cryogenic temperature. It must withstand both external atmospheric pressure during normal operation and internal overpressure in case of an accident. The paper summarizes the structural analyses performed in order to validate the JT-60SA cryostat vessel body design. It comprises several analyses: a buckling analysis to demonstrate stability under the external pressure; an elastic and an elastic–plastic stress analysis according to ASME VIII rules, to evaluate resistance to plastic collapse including localized stress concentrations; and, finally, a detailed analysis with bolted fasteners in order to evaluate the behavior of the flanges, assuring the integrity of the vacuum sealing welds of the cryostat vessel body.

Nitrogen-modified nano-titania: True phase composition, microstructure and visible-light induced photocatalytic NO{sub x} abatement

Energy Technology Data Exchange (ETDEWEB)

Tobaldi, D.M., E-mail: david.tobaldi@ua.pt [Department of Materials and Ceramic Engineering / CICECO−Aveiro Institute of Materials, University of Aveiro, Campus Universitário de Santiago, 3810-193 Aveiro (Portugal); Pullar, R.C. [Department of Materials and Ceramic Engineering / CICECO−Aveiro Institute of Materials, University of Aveiro, Campus Universitário de Santiago, 3810-193 Aveiro (Portugal); Gualtieri, A.F. [Dipartimento di Scienze Chimiche e Geologiche, Università degli studi di Modena e Reggio Emilia, I-41121 Modena (Italy); Otero-Irurueta, G.; Singh, M.K. [Center for Mechanical Technology and Automation – TEMA, University of Aveiro, Campus Universitário de Santiago, 3810-193 Aveiro (Portugal); Seabra, M.P.; Labrincha, J.A. [Department of Materials and Ceramic Engineering / CICECO−Aveiro Institute of Materials, University of Aveiro, Campus Universitário de Santiago, 3810-193 Aveiro (Portugal)

2015-11-15

Titanium dioxide (TiO{sub 2}) is a popular photocatalyst used for many environmental and anti-pollution applications, but it normally operates under UV light, exploiting ∼5% of the solar spectrum. Nitrification of titania to form N-doped TiO{sub 2} has been explored as a way to increase its photocatalytic activity under visible light, and anionic doping is a promising method to enable TiO{sub 2} to harvest visible-light by changing its photo-absorption properties. In this paper, we explore the insertion of nitrogen into the TiO{sub 2} lattice using our green sol–gel nanosynthesis method, used to create 10 nm TiO{sub 2} NPs. Two parallel routes were studied to produce nitrogen-modified TiO{sub 2} nanoparticles (NPs), using HNO{sub 3}+NH{sub 3} (acid-precipitated base-peptised) and NH{sub 4}OH (totally base catalysed) as nitrogen sources. These NPs were thermally treated between 450 and 800 °C. Their true phase composition (crystalline and amorphous phases), as well as their micro-/nanostructure (crystalline domain shape, size and size distribution, edge and screw dislocation density) was fully characterised through advanced X-ray methods (Rietveld-reference intensity ratio, RIR, and whole powder pattern modelling, WPPM). As pollutants, nitrogen oxides (NO{sub x}) are of particular concern for human health, so the photocatalytic activity of the NPs was assessed by monitoring NO{sub x} abatement, using both solar and white-light (indoor artificial lighting), simulating outdoor and indoor environments, respectively. Results showed that the onset of the anatase-to-rutile phase transformation (ART) occurred at temperatures above 450 °C, and NPs heated to 450 °C possessed excellent photocatalytic activity (PCA) under visible white-light (indoor artificial lighting), with a PCA double than that of the standard P25 TiO{sub 2} NPs. However, higher thermal treatment temperatures were found to be detrimental for visible-light photocatalytic activity, due to the effects

CARR-CNS with crescent-shape moderator cell and sub-cooling helium jacket surrounding cell

International Nuclear Information System (INIS)

Yu, Qingfeng; Feng, Quanke; Kawai, Takeshi; Shen, Feng; Yuan, Luzheng

2005-01-01

The new type of the moderator cell was developed for the Cold Neutron Source (CNS) of the China Advanced Research Reactor (CARR) which is now constructing at the China Institute of Atomic Energy in Beijing. A crescent-shape moderator cell covered by the sub-cooling helium jacket is adopted. A crescent-shape would help to increase the volume of the moderator cell for corresponding it to the 4 cold neutron guide tubes, even if liquid hydrogen not liquid deuterium were used as a cold moderator. The sub-cooling helium jacket covering the moderator cell removes the nuclear heating of the outer shell wall of the cell. It contributes to reduce the void fraction of liquid hydrogen in the inner shell. Such a type of a moderator cell is suitable for the CNS with higher nuclear heating. The cold helium gas flows down firstly into the sub-cooling helium jacket and then flows up to the condenser. Therefore, the theory of the self-regulation for the thermo-siphon type of the CNS is also applicable

CARR-CNS with crescent-shape moderator cell and sub-cooling helium jacket around cell

International Nuclear Information System (INIS)

Yu, Qingfeng; Feng, Quanke; Kawai, Takeshi; Cheng, Liang; Shen, Feng; Yuan, Luzheng

2005-01-01

The new type of the moderator cell was developed for the Cold Neutron Source (CNS) of the China Advanced Research Reactor (CARR) which is now constructing at the China Institute of Atomic Energy in Beijing. A crescent-shape moderator cell covered by the sub-cooling helium jacket is adopted. A crescent-shape would help to increase the volume of the moderator cell for corresponding it to the 4 cold neutron guide tubes, even if liquid hydrogen not liquid deuterium were used as a cold moderator. The sub-cooling helium jacket covering the moderator cell removes the nuclear heating of the outer shell wall of the cell. It contributes to reduce the void fraction of liquid hydrogen in the inner shell. Such a type of a moderator cell is suitable for the CNS with higher nuclear heating. The cold helium gas flows down firstly into the sub-cooling helium jacket and then flows up to the condenser. Therefore, the theory of the self-regulation for the thermo-siphon type of the CNS is also applicable

Efficient sub-Doppler transverse laser cooling of an indium atomic beam

Energy Technology Data Exchange (ETDEWEB)

Kim, Jae-Ihn

2009-07-23

Laser cooled atomic gases and atomic beams are widely studied samples in experimental research in atomic and optical physics. For the application of ultra cold gases as model systems for e.g. quantum many particle systems, the atomic species is not very important. Thus this field is dominated by alkaline, earthalkaline elements which are easily accessible with conventional laser sources and have convenient closed cooling transition. On the other hand, laser cooled atoms may also be interesting for technological applications, for instance for the creation of novel materials by atomic nanofabrication (ANF). There it will be important to use technologically relevant materials. As an example, using group III atoms of the periodical table in ANF may open a route to generate fully 3D structured composite materials. The minimal requirement in such an ANF experiment is the collimation of an atomic beam which is accessible by one dimensional laser cooling. In this dissertation, I describe transverse laser cooling of an Indium atomic beam. For efficient laser cooling on a cycling transition, I have built a tunable, continuous-wave coherent ultraviolet source at 326 nm based on frequency tripling. For this purpose, two independent high power Yb-doped fiber amplifiers for the generation of the fundamental radiation at {lambda}{sub {omega}} = 977 nm have been constructed. I have observed sub-Doppler transverse laser cooling of an Indium atomic beam on a cycling transition of In by introducing a polarization gradient in the linear-perpendicular-linear configuration. The transverse velocity spread of a laser-cooled In atomic beam at full width at half maximum was achieved to be 13.5{+-}3.8 cm/s yielding a full divergence of only 0.48 {+-} 0.13 mrad. In addition, nonlinear spectroscopy of a 3-level, {lambda}-type level system driven by a pump and a probe beam has been investigated in order to understand the absorption line shapes used as a frequency reference in a previous two

First-principles study of nitrogen doping in cubic and amorphous Ge{sub 2}Sb{sub 2}Te{sub 5}

Energy Technology Data Exchange (ETDEWEB)

Caravati, S; Mazzarello, R; Kuehne, T D; Parrinello, M [Computational Science, Department of Chemistry and Applied Biosciences, ETH Zurich, USI Campus, Via Giuseppe Buffi 13, CH-6900 Lugano (Switzerland); Colleoni, D; Bernasconi, M [Dipartimento di Scienza dei Materiali, Universita di Milano-Bicocca, Via R Cozzi 53, I-20125 Milano (Italy); Krack, M [Paul Scherrer Institut, CH-5232 Villigen (Switzerland)

2011-07-06

We investigated the structural, electronic and vibrational properties of amorphous and cubic Ge{sub 2}Sb{sub 2}Te{sub 5} doped with N at 4.2 at.% by means of large scale ab initio simulations. Nitrogen can be incorporated in molecular form in both the crystalline and amorphous phases at a moderate energy cost. In contrast, insertion of N in the atomic form is very energetically costly in the crystalline phase, though it is still possible in the amorphous phase. These results support the suggestion that N segregates at the grain boundaries during the crystallization of the amorphous phase, resulting in a reduction in size of the crystalline grains and an increased crystallization temperature.

ITER cryostat main chamber and vacuum vessel pressure suppression system design

International Nuclear Information System (INIS)

Ito, Akira; Nakahira, Masataka; Takahashi, Hiroyuki; Tada, Eisuke; Nakashima, Yoshitane; Ueno, Osamu

1999-03-01

Design of Cryostat Main Chamber and Vacuum Vessel Pressure Suppression System (VVPS) of International Thermonuclear Experimental Reactor (ITER) has been conducted. The cryostat is a cylindrical vessel that includes in-vessel component such as vacuum vessel, superconducting toroidal coils and poloidal coils. This cryostat provides the adiabatic vacuum about 10 -4 Pa for the superconducting coils operating at 4 K and forms the second confinement barrier to tritium. The adiabatic vacuum is to reduce thermal loads applied to the superconducting coils and their supports so as to keep their temperature 4 K. The VVPS consists of a suppression tank located under the lower bio-shield and 4 relief pipes to connect the vacuum vessel and the suppression tank. The VVPS is to keep the maximum pressure rise of the vacuum vessel below the design value of 0.5 MPa in case of the in-vessel LOCA (water spillage from in-vessel component). The spilled water and steam are lead to the suppression tank through the relief pipes when the internal pressure of vacuum vessel is over 0.2 MPa, and then the internal pressure is kept below 0.5 MPa. This report summarizes the structural design of the cryostat main chamber and pressure suppression system, together with their fabrication and installation. (author)

ITER cryostat main chamber and vacuum vessel pressure suppression system design

Energy Technology Data Exchange (ETDEWEB)

Ito, Akira; Nakahira, Masataka; Takahashi, Hiroyuki; Tada, Eisuke [Japan Atomic Energy Research Inst., Tokai, Ibaraki (Japan). Tokai Research Establishment; Nakashima, Yoshitane; Ueno, Osamu

1999-03-01

Design of Cryostat Main Chamber and Vacuum Vessel Pressure Suppression System (VVPS) of International Thermonuclear Experimental Reactor (ITER) has been conducted. The cryostat is a cylindrical vessel that includes in-vessel component such as vacuum vessel, superconducting toroidal coils and poloidal coils. This cryostat provides the adiabatic vacuum about 10{sup -4} Pa for the superconducting coils operating at 4 K and forms the second confinement barrier to tritium. The adiabatic vacuum is to reduce thermal loads applied to the superconducting coils and their supports so as to keep their temperature 4 K. The VVPS consists of a suppression tank located under the lower bio-shield and 4 relief pipes to connect the vacuum vessel and the suppression tank. The VVPS is to keep the maximum pressure rise of the vacuum vessel below the design value of 0.5 MPa in case of the in-vessel LOCA (water spillage from in-vessel component). The spilled water and steam are lead to the suppression tank through the relief pipes when the internal pressure of vacuum vessel is over 0.2 MPa, and then the internal pressure is kept below 0.5 MPa. This report summarizes the structural design of the cryostat main chamber and pressure suppression system, together with their fabrication and installation. (author)

Irradiation cryostat for LiH and LiD polarized solid targets

International Nuclear Information System (INIS)

Goertz, S.

1991-01-01

Scattering experiments with polarized nucleon targets are an important tool to understand the nuclear spin structure. Pion photoproduction experiments on polarized protrons and neutrons as well as measurements of the neutron and deuteron formfactors will be performed at ELSA. 7 LiH and 6 LiD seem to be attractive target materials for these experiments, because they offer high proton and deuteron polarisation, respectively. Expecially 6 LiD has further very important advantages compared to the common deuteron target materials as d-Butanol and ND 3 . This work describes the mechanism of DNP (Dynamic Nuclear Polarization) in LiH and LiD and gives a view on the nature of the so-called paramagnetic impurities in these materials. In order to maximize the nuclear polarization, the production of these radicals have to take place under well defined temperature conditions. Therefore the first version of an irradiation cryostat was built and tested in regard to its cooling power and temperature adjustment. (orig.)

Performance evaluation of a stack cooling system using CO{sub 2} air conditioner in fuel cell vehicles

Energy Technology Data Exchange (ETDEWEB)

Kim, Sung Chul; Won, Jong Phil [Thermal Management Research Center, Korea Automotive Technology Institute, Chungnam 330-912 (Korea); Park, Yong Sun; Lim, Tae Won [Corporate Research and Development Division, Hyundai-Kia Motors, Gyeonggi 449-912 (Korea); Kim, Min Soo [School of Mechanical and Aerospace Engineering, Seoul National University, Seoul 151-744 (Korea)

2009-01-15

A relation between the heat release from a fuel cell stack and an air conditioning system's performance was investigated. The air conditioning system installed in a fuel cell vehicle can be used for stack cooling when additional stack heat release is required over a fixed radiator capacity during high vehicle power generation. This study investigated the performance of a stack cooling system using CO{sub 2} air conditioner at various operating conditions. Also, the heat releasing effectiveness and mutual interference were analyzed and compared with those for the conventional radiator cooling system with/without cabin cooling. When the radiator coolant inlet temperature and flow rate were 65 C and 80 L/min, respectively, for the outdoor air inlet speed of 5 m/s, the heat release of the stack cooling system with the aid of CO{sub 2} air conditioner increased up to 36% more than that of the conventional radiator cooling system with cabin cooling. Furthermore, this increased by 7% versus the case without cabin cooling. (author)

Mechanism of NH{sub 3} desorption during the reaction of H{sub 2} with nitrogen containing carbonaceous materials

Energy Technology Data Exchange (ETDEWEB)

Juan F. Espinal; Thanh N. Truong; Fanor Mondragon [University of Antioquia, Medellin (Colombia). Institute of Chemistry

2005-07-01

The continued increase in demand for natural gas has stimulated the interest in coal conversion to methane as synthetic natural gas by hydropyrolysis of coal (pyrolysis in a H{sub 2} atmosphere). Because the produced raw gas contains considerable amounts of gaseous N-containing products that have to be removed before delivering to final users, the information on distribution of coal-N is important for designing purification processes. It has been reported in the literature that NH{sub 3} is the main nitrogen containing gas that is released during the hydropyrolysis process. Other gases such as HCN and N{sub 2} are also released but in a much smaller amount. To the best of our knowledge, the mechanism for NH{sub 3} desorption during hydrogen reaction with carbonaceous materials has not been studied. We carried out a molecular modeling study using Density Functional Theory in order to get an insight of the mechanism and thermodynamics for NH{sub 3} evolution using pyridinic nitrogen as a model of N-containing carbonaceous material. We propose a mechanism that involves consecutive hydrogenation steps that lead to C-N bond breakage and NH{sub 3} desorption to the gas phase. It was found that the first hydrogenation reaction is highly exothermic. However, further hydrogenations are endothermic. Several pathways for NH{sub 3} evolution were proposed and most of them show high exothermicity. 17 refs., 2 figs.

Enhanced relative cooling power of Fe-doped La{sub 0.67}Sr{sub 0.22}Ba{sub 0.11}Mn{sub 1-x}Fe{sub x}O{sub 3} perovskites: Structural, magnetic and magnetocaloric properties

Energy Technology Data Exchange (ETDEWEB)

Ben Hassine, R.; Cherif, W. [Sfax University, Faculty of Sciences, B. P. 1171, 3000 (Tunisia); Alonso, J.A., E-mail: ja.alonso@icmm.csic.es [Instituto de Ciencia de Materiales de Madrid, Consejo Superior de Investigaciones Científicas, Cantoblanco, E-28049 Madrid (Spain); Mompean, F. [Instituto de Ciencia de Materiales de Madrid, Consejo Superior de Investigaciones Científicas, Cantoblanco, E-28049 Madrid (Spain); Fernández-Díaz, M.T. [Institut Laue-Langevin, B.P. 156, F-38042 Grenoble Cedex 9 (France); Elhalouani, F. [Sfax University, National School of Engineers, B. P. W 3038 (Tunisia)

2015-11-15

We present the structural and magnetic properties of a novel series of La{sub 0.67}Sr{sub 0.22}Ba{sub 0.11}Mn{sub 1-x}Fe{sub x}O{sub 3} (0 ≤ x ≤ 0.3) perovskites prepared by the sol–gel method. These oxides were characterized by x-ray (XRD), neutron powder diffraction (NDP) at room temperature and magnetization measurements versus temperature and various applied magnetic fields. The NPD data, very sensitive to the octahedral tilting, show a crystallographic phase transition from an orthorhombic structure (Pnma) for x = 0 to a rhombohedral structure (R-3c) for Fe-doped samples. Magnetic data show that x = 0 and x = 0.1 perovskites exhibit a paramagnetic–ferromagnetic transition at low temperature, while for 0.2 ≤ x ≤ 0.3 a strong divergence between ZFC and FC curves suggest the presence of antagonistic antiferromagnetic and ferromagnetic interactions. The magnetic entropy change (|ΔSmax|) takes values of 2.46 J kg{sup −1} K{sup −1}, 2.43 J kg{sup −1} K{sup −1} and 0.91 J kg{sup −1} for x = 0, x = 0.1 and 0.2, respectively at 5 T. The relative cooling power (RCP) amounts 169 J Kg{sup −1}, 241 J Kg{sup −1} and 70 J Kg{sup −1} at 5 T for x = 0, 0.1, 0.2 respectively. These values are compared favorably with those of some others reported manganites, making La{sub 0.67}Sr{sub 0.22}Ba{sub 0.11}Mn{sub 0.9}Fe{sub 0.1}O{sub 3} a promising candidate for magnetic refrigeration. - Graphical abstract: The title perovskites present a crystallographic phase transition from an orthorhombic structure (Pnma) for x = 0 to a rhombohedral structure (R-3c) for Fe-doped samples, as shown in a neutron study. Magnetic data show that x = 0 and x = 0.1 perovskites exhibit sharp paramagnetic–ferromagnetic transitions. The relative cooling power (RCP) is as high as 241 J Kg{sup −1} for x = 0.1, being a promising candidate for magnetic refrigeration. - Highlights: • Novel Fe-doped manganite oxides prepared by a sol–gel procedure. • Neutron diffraction shows

Cooling tests of the cryomodules at superconducting RF test facility (STF)

International Nuclear Information System (INIS)

Ohuchi, Norihito; Nakai, Hirotaka; Kojima, Yuuji

2009-01-01

KEK has been constructing the Superconducting RF Test Facility (STF) with aiming at a center of the ILC-R and D in Asia from 2005. In this project, KEK targets manufacturing and operational experiences of the RF cavity and cryomodule toward the ILC, and two cryomodules have been developed. These cryomodules are 6 meter long and have 4 nine-cell cavities in each cryostat. The designs of the cryomodules are based on the TESLA Type-3 (TTF-3) at DESY, however, each cryostat has the different type of cavities, TESLA-like type and Low-Loss type. The tests of the cryomodules were performed in two steps. In the first test, measurements of the cryogenic performances of these cryomodules were the main objective. One nine-cell cavity was assembled in each cryomodule and cool-down of the two cryomodules was performed, individually. In the second test, the four TESLA-like cavities were assembled in the cryomodule as complete integration. Cool-down of the cryomodule to 2 K was successfully completed, and thermal performances of the cryomodule and cooling capacity of the cryogenics system were studied in detail. In this paper, we will report the design of the cryomodules and the thermal performances at these cold tests. (author)

Update of the ITER MELCOR model for the validation of the Cryostat design

Energy Technology Data Exchange (ETDEWEB)

Martínez, M.; Labarta, C.; Terrón, S.; Izquierdo, J.; Perlado, J.M.

2015-07-01

Some transients can compromise the vacuum in the Cryostat of ITER and cause significant loads. A MELCOR model has been updated in order to assess this loads. Transients have been run with this model and its result will be used in the mechanical assessment of the cryostat. (Author)

Second sector cool down

CERN Multimedia

2007-01-01

At the beginning of July, cool-down is starting in the second LHC sector, sector 4-5. The cool down of sector 4-5 may occasionally generate mist at Point 4, like that produced last January (photo) during the cool-down of sector 7-8.Things are getting colder in the LHC. Sector 7-8 has been kept at 1.9 K for three weeks with excellent stability (see Bulletin No. 16-17 of 16 April 2007). The electrical tests in this sector have got opt to a successful start. At the beginning of July the cryogenic teams started to cool a second sector, sector 4-5. At Point 4 in Echenevex, where one of the LHC’s cryogenic plants is located, preparations for the first phase of the cool-down are underway. During this phase, the sector will first be cooled to 80 K (-193°C), the temperature of liquid nitrogen. As for the first sector, 1200 tonnes of liquid nitrogen will be used for the cool-down. In fact, the nitrogen circulates only at the surface in the ...

Design Construction and Operation of a Supercritical Carbon Dioxide (sCO<sub>2sub>) Loop for Investigation of Dry Cooling and Natural Circulation Potential for Use in Advanced Small Modular Reactors Utilizing sCO<sub>2sub> Power Conversion Cycles.

Energy Technology Data Exchange (ETDEWEB)

Middleton, Bobby D. [Sandia National Lab. (SNL-NM), Albuquerque, NM (United States); Rodriguez, Salvador B. [Sandia National Lab. (SNL-NM), Albuquerque, NM (United States); Carlson, Matthew David [Sandia National Lab. (SNL-NM), Albuquerque, NM (United States)

2015-11-01

This report outlines the work completed for a Laboratory Directed Research and Development project at Sandia National Laboratories from October 2012 through September 2015. An experimental supercritical carbon dioxide (sCO <sub>2sub> ) loop was designed, built, and o perated. The experimental work demonstrated that sCO <sub>2sub> can be uti lized as the working fluid in an air - cooled, natural circulation configuration to transfer heat from a source to the ultimate heat sink, which is the surrounding ambient environment in most ca ses. The loop was also operated in an induction - heated, water - cooled configuration that allows for measurements of physical parameters that are difficult to isolate in the air - cooled configuration. Analysis included the development of two computational flu id dynamics models. Future work is anticipated to answer questions that were not covered in this project.

Controllable nitrogen doping in as deposited TiO{sub 2} film and its effect on post deposition annealing

Energy Technology Data Exchange (ETDEWEB)

Deng, Shaoren; Devloo-Casier, Kilian; Devulder, Wouter; Dendooven, Jolien; Deduytsche, Davy; Detavernier, Christophe, E-mail: Christophe.Detavernier@ugent.be [Department of Solid State Sciences, Ghent University, Krijgslaan 281/S1, B-9000 Gent (Belgium); Verbruggen, Sammy W. [Department of Bio-Engineering Sciences, University of Antwerp, Groenenborgerlaan 171, B-2020 Antwerp, Belgium and Center for Surface Chemistry and Catalysis, KU Leuven, Kasteelpark Arenberg 23, B-3001 Heverlee (Belgium); Lenaerts, Silvia [Department of Bio-Engineering Sciences, University of Antwerp, Groenenborgerlaan 171, B-2020 Antwerp (Belgium); Martens, Johan A. [Center for Surface Chemistry and Catalysis, KU Leuven, Kasteelpark Arenberg 23, B-3001 Heverlee (Belgium); Van den Berghe, Sven [SCK-CEN, Boeretang 200, B-2400 Mol (Belgium)

2014-01-15

In order to narrow the band gap of TiO{sub 2}, nitrogen doping by combining thermal atomic layer deposition (TALD) of TiO{sub 2} and plasma enhanced atomic layer deposition (PEALD) of TiN has been implemented. By altering the ratio between TALD TiO{sub 2} and PEALD TiN, the as synthesized TiO{sub x}N{sub y} films showed different band gaps (from 1.91 eV to 3.14 eV). In situ x-ray diffraction characterization showed that the crystallization behavior of these films changed after nitrogen doping. After annealing in helium, nitrogen doped TiO{sub 2} films crystallized into rutile phase while for the samples annealed in air a preferential growth of the anatase TiO{sub 2} along (001) orientation was observed. Photocatalytic tests of the degradation of stearic acid were done to evaluate the effect of N doping on the photocatalytic activity.

High rate capability of TiO{sub 2}/nitrogen-doped graphene nanocomposite as an anode material for lithium–ion batteries

Energy Technology Data Exchange (ETDEWEB)

Cai, Dandan; Li, Dongdong; Wang, Suqing [School of Chemistry and Chemical Engineering, South China University of Technology, Wushan Road, Guangzhou (China); Zhu, Xuefeng; Yang, Weishen [State Key Laboratory of Catalysis, Dalian Institute of Chemical Physics, Chinese Academy of Sciences, Dalian (China); Zhang, Shanqing [Centre for Clean Environment and Energy, Environmental Futures Centre and Griffith School of Environment, Gold Coast Campus, Griffith University, QLD 4222 (Australia); Wang, Haihui, E-mail: hhwang@scut.edu.cn [School of Chemistry and Chemical Engineering, South China University of Technology, Wushan Road, Guangzhou (China)

2013-06-05

Highlights: ► TiO{sub 2}/N-doped graphene composite was synthesized by a gas/liquid interfacial method. ► The nanocomposite was used to fabricate lithium-ion batteries. ► Its electrochemical performance was evaluated for the first time. ► The anode material exhibits a good cycling performance and rate capability. -- Abstract: TiO{sub 2}/nitrogen-doped graphene nanocomposite was synthesized by a facile gas/liquid interface reaction. The structure and morphology of the sample were analyzed by X-ray diffraction analysis, X-ray photoelectron spectroscopy, scanning electron microscopy and transmission electron microscopy. The results indicate that nitrogen atoms were successfully doped into graphene sheets. The TiO{sub 2} nanoparticles (8–13 nm in size) were homogenously anchored on the nitrogen-doped graphene sheets through gas/liquid interface reaction. The as-prepared TiO{sub 2}/nitrogen-doped graphene nanocomposite shows a better electrochemical performance than the TiO{sub 2}/graphene nanocomposite and the bare TiO{sub 2} nanoparticles. TiO{sub 2}/nitrogen-doped graphene nanocomposite exhibits excellent cycling stability and shows high capacity of 136 mAh g{sup −1} (at a current density of 1000 mA g{sup −1}) after 80 cycles. More importantly, a high reversible capacity of 109 mAh g{sup −1} can still be obtained even at a super high current density of 5000 mA g{sup −1}. The superior electrochemical performance is attributed to the good electronic conductivity introduced by the nitrogen-doped graphene sheets and the positive synergistic effect between nitrogen-doped graphene sheets and TiO{sub 2} nanoparticles.

Construction of Z-scheme Ag{sub 2}CO{sub 3}/N-doped graphene photocatalysts with enhanced visible-light photocatalytic activity by tuning the nitrogen species

Energy Technology Data Exchange (ETDEWEB)

Song, Shaoqing [State Key Laboratory of Advanced Technology for Materials Synthesis and Processing, Wuhan University of Technology, Wuhan 430070 (China); Key Laboratory of Radioactive Geology and Exploration Technology Fundamental Science for National Defense, East China Institute of Technology, Nanchang, Jiangxi Province 330013 (China); Meng, Aiyun [State Key Laboratory of Advanced Technology for Materials Synthesis and Processing, Wuhan University of Technology, Wuhan 430070 (China); Jiang, Shujuan [Key Laboratory of Radioactive Geology and Exploration Technology Fundamental Science for National Defense, East China Institute of Technology, Nanchang, Jiangxi Province 330013 (China); Cheng, Bei [State Key Laboratory of Advanced Technology for Materials Synthesis and Processing, Wuhan University of Technology, Wuhan 430070 (China); Jiang, Chuanjia, E-mail: jiangcj2016@yahoo.com [State Key Laboratory of Advanced Technology for Materials Synthesis and Processing, Wuhan University of Technology, Wuhan 430070 (China)

2017-02-28

Highlights: • Z-scheme photocatalyst composed of Ag{sub 2}CO{sub 3} and N-doped graphene (NG). • Pyridinic nitrogen species of NG spontaneously promoted plasmonic Ag formation. • Graphitic N of NG facilitated the Z-scheme transfer option and O{sub 2} adsorption. • Z-scheme Ag{sub 2}CO{sub 3}-NG showed high photocatalytic performance. - Abstract: Semiconductor-based photocatalysis has great potential in various environmental and energy applications, and Z-scheme photocatalysts have many advantages over single-component photocatalysts. The construction of a highly efficient Z-scheme photocatalytic system depends on the geometric structure arrangement, microscopic and crystalline form of the stoichiometric species, and it has not been elucidated whether the Z-scheme photocatalysts can be designed by tuning the electronic structures of cocatalysts alone. Here, using N-doped graphene (NG) as cocatalyst, we successfully constructed Z-scheme Ag{sub 2}CO{sub 3}-NG photocatalysts with enhanced activity for the photooxidative degradation of phenol pollutant. It was found that the pyridinic nitrogen species (N{sub p}) of NG could spontaneously reduce Ag{sup +} to produce plasmonic Ag nanoparticles on Ag{sub 2}CO{sub 3}-NG, while the efficiency of the photogenerated charge separation, Z-scheme transfer option, and O{sub 2} adsorption were promoted by the graphitic nitrogen species (N{sub g}). Therefore, the as-designed Z-scheme Ag{sub 2}CO{sub 3}-NG photocatalysts showed much higher activity than Ag{sub 2}CO{sub 3} and its composites with graphene oxide (GO) or reduced GO as cocatalysts in the photocatalytic degradation of phenol. Hence, our results provide a new strategy for exploring advanced Z-scheme photocatalysts with NG as cocatalyst by rationally tuning the N{sub p} and N{sub g} species.

Modeling and Thermal Performance Evaluation of Porous Curd Layers in Sub-Cooled Boiling Region of PWRs and Effects of Sub-Cooled Nucleate Boiling on Anomalous Porous Crud Deposition on Fuel Pin Surfaces

International Nuclear Information System (INIS)

Barclay Jones

2005-01-01

A significant number of current PWRs around the world are experiencing anomalous crud deposition in the sub-cooled region of the core, resulting in an axial power shift or Axial Offset Anomaly (AOA), a condition that continues to elude prediction of occurrence and thermal/neutronic performance. This creates an operational difficulty of not being able to accurately determine power safety margin. In some cases this condition has required power ''down rating'' by as much as thirty percent and the concomitant considerable loss of revenue for the utility. This study examines two aspects of the issue: thermal performance of crud layer and effect of sub-cooled nucleate boiling on the solute concentration and its influence on initiation of crud deposition/formation on fuel pin surface

Nd Fe{sub 10} Mo{sub 2} alloys production through reduction-diffusion for nitrogenation; Obtencao de ligas NdFe{sub 10}Mo{sub 2} por reducao-difusao para posterior nitrogenacao

Energy Technology Data Exchange (ETDEWEB)

Guilherme, Eneida da G. [Instituto de Pesquisas Energeticas e Nucleares (IPEN), Sao Paulo, SP (Brazil); Rechenberg, Hercilio R. [Sao Paulo Univ., SP (Brazil). Inst. de Fisica

1996-12-31

In this work we have examined the effect of various processing variables on the Nd Fe{sub 10} Mo{sub 2} phase formation by reduction-diffusion calciothermic process (R D C). The best results were obtained for 4 hours treatment at 950 deg C with 40% excess content Nd Cl{sub 3} and 50% excess content of Ca, for alloy Nd Fe{sub 10.5} Mo{sub 1.5}. Preliminary nitrogen absorption experiments have been done, without any further powder size reduction at temperatures between 300 and 350 deg C. (author) 9 refs., 6 figs., 1 tab.

Flow distribution analysis on the cooling tube network of ITER thermal shield

International Nuclear Information System (INIS)

Nam, Kwanwoo; Chung, Wooho; Noh, Chang Hyun; Kang, Dong Kwon; Kang, Kyoung-O; Ahn, Hee Jae; Lee, Hyeon Gon

2014-01-01

Thermal shield (TS) is to be installed between the vacuum vessel or the cryostat and the magnets in ITER tokamak to reduce the thermal radiation load to the magnets operating at 4.2K. The TS is cooled by pressurized helium gas at the inlet temperature of 80K. The cooling tube is welded on the TS panel surface and the composed flow network of the TS cooling tubes is complex. The flow rate in each panel should be matched to the thermal design value for effective radiation shielding. This paper presents one dimensional analysis on the flow distribution of cooling tube network for the ITER TS. The hydraulic cooling tube network is modeled by an electrical analogy. Only the cooling tube on the TS surface and its connecting pipe from the manifold are considered in the analysis model. Considering the frictional factor and the local loss in the cooling tube, the hydraulic resistance is expressed as a linear function with respect to mass flow rate. Sub-circuits in the TS are analyzed separately because each circuit is controlled by its own control valve independently. It is found that flow rates in some panels are insufficient compared with the design values. In order to improve the flow distribution, two kinds of design modifications are proposed. The first one is to connect the tubes of the adjacent panels. This will increase the resistance of the tube on the panel where the flow rate is excessive. The other design suggestion is that an orifice is installed at the exit of tube routing where the flow rate is to be reduced. The analysis for the design suggestions shows that the flow mal-distribution is improved significantly

Remote refilling of LN2 cryostats for high sensitivity astronomical applications

Science.gov (United States)

l'Allemand, J. L. Lizon a.

2017-12-01

The most sensitive observation mode of the ESO VLT (European Southern Observatory Very Large Telescope) is the interferometric mode, where the 4 Units Telescopes are directed to the same stellar object in order to operate as a gigantic interferometer. The beam is then re-combined in the main interferometry laboratory and fed into the analyzing instruments. In order not to disturb the performance of the Interferometer, this room is considered as a sanctuary where one enters only in case of extreme need. A simple opening of the door would create air turbulences affecting the stability for hours. Any cold spot in the room could also cause convection which might change the optical path by fraction of a micron. Most of the instruments are operating at cryogenic temperatures using passive cooling based on LN2 bath cryostat. For this reason, dedicated strategy has been developed for the transfer of LN2 to the various instruments. The present document describes the various aspects and care taken in order to guarantee the very high thermal and mechanical environmental stability.

Thermal structural analysis of SST-1 vacuum vessel and cryostat assembly using ANSYS

International Nuclear Information System (INIS)

Santra, Prosenjit; Bedakihale, Vijay; Ranganath, Tata

2009-01-01

Steady state super-conducting tokamak-1 (SST-1) is a medium sized tokamak, which has been designed to produce a 'D' shaped double null divertor plasma and operate in quasi steady state (1000 s). SST-1 vacuum system comprises of plasma chamber (vacuum vessel, interconnecting rings, baking and cooling channels), and cryostat all made of SS 304L material designed to meet ultra high vacuum requirements for plasma generation and confinement. Prior to plasma shot and operation the vessel assembly is baked to 250/150 deg. C from room temperature and discharge cleaned to remove impurities/trapped gases from wall surfaces. Due to baking the non-uniform temperature pattern on the vessel assembly coupled with atmospheric pressure loading and self-weight give rise to high thermal-structural stresses, which needs to be analyzed in detail. In addition the vessel assembly being a thin shell vessel structure needs to be checked for critical buckling load caused by atmospheric and baking thermal loads. Considering symmetry of SST-1, 1/16th of the geometry is modeled for finite element (FE) analysis using ANSYS for different loading scenarios, e.g. self-weight, pressure loading considering normal operating conditions, and off-normal loads coupled with baking of vacuum vessel from room temperature 250 deg. C to 150 deg. C, buckling and modal analysis for future dynamic analysis. The paper will discuss details about SST-1 vacuum system/cryostat, solid and FE model of SST-1, different loading scenarios, material details and the stress codes used. We will also present the thermal structural results of FE analysis using ANSYS for various load cases being investigated and our observations under different loading conditions.

Constraining the role of iron in environmental nitrogen transformations. Dual stable isotope systematics of abiotic NO<sub>2sub>- reduction by Fe(II) and its production of N<sub>2sub>O

Energy Technology Data Exchange (ETDEWEB)

Johnston, David [Harvard Univ., Cambridge, MA (United States); Wankel, Scott David [Woods Hole Oceanographic Inst., MA (United States); Buchwald, Carolyn [Woods Hole Oceanographic Inst., MA (United States); Hansel, Colleen [Woods Hole Oceanographic Inst., MA (United States)

2015-09-16

Redox reactions involving nitrogen and iron have been shown to have important implications for mobilization of priority contaminants. Thus, an understanding of the linkages between their biogeochemical cycling is critical for predicting subsurface mobilization of radionuclides such as uranium. Despite mounting evidence for biogeochemical interactions between iron and nitrogen, our understanding of their environmental importance remains limited. Here we present an investigation of abiotic nitrite (NO<sub>2sub>^-) reduction by Fe(II) or ‘chemodenitrification,’ and its relevance to the production of nitrous oxide (N<sub>2sub>O), specifically focusing on dual (N and O) isotope systematics under a variety of environmentally relevant conditions. We observe a range of kinetic isotope effects that are regulated by reaction rates, with faster rates at higher pH (~8), higher concentrations of Fe(II) and in the presence of mineral surfaces. A clear non-linear relationship between rate constant and kinetic isotope effects of NO<sub>2sub>^- reduction was evident (with larger isotope effects at slower rates) and is interpreted as reflecting the dynamics of Fe(II)-N reaction intermediates. N and O isotopic composition of product N<sub>2sub>O also suggests a complex network of parallel and/or competing pathways. Our findings suggest that NO<sub>2sub>^- reduction by Fe(II) may represent an important abiotic source of environmental N<sub>2sub>O, especially in iron-rich environments experiencing dynamic redox variations. This study provides a multi-compound, multi-isotope framework for evaluating the environmental occurrence of abiotic NO<sub>2sub>^- reduction and N<sub>2sub>O formation, helping future studies constrain the relative roles of abiotic and biological N<sub>2sub>O production pathways.

Development of a CO{sub 2} cooling system for the CBM silicon tracking system

Energy Technology Data Exchange (ETDEWEB)

Sanchez Rosado, Jorge; Degirmenciler, Burak; Heuser, Johann; Sturm, Christian [GSI Helmholtzzentrum fuer Schwerionenforschung GmbH (Germany); Lymanets, Anton; Schmidt, Hans Rudolf [Eberhard Karls Universitaet Tuebingen (Germany)

2015-07-01

The demanding requirements of current high-energy physics experiments curiously bring back the idea of using a well-known and present refrigerant in nature: CO{sub 2}. As an outcome of previous studies and effort made within the current upgrade programs of detectors like ATLAS or CMS, this refrigerant is the optimum solution. Due to its highest volumetric heat transfer coefficient, it fulfills the requirements in this kind of detectors such as reduction of mass budget and the use of smaller diameter for cooling pipes. A two-phase (evaporative) CO{sub 2} cooling system is taken as the first choice to extract the 42 kW dissipated by the electronics of the Silicon Tracking System, the central detector of the CBM experiment at FAIR that will be installed in the gap of the 1 T super-conducting dipole magnet in a confined volume of 2 m{sup 3}. As a step towards the final design of this a cooling system, a 1 kW cooling unit called TRACI-XL was conceived at GSI in cooperation with CERN. This scaled prototype allows gaining insight into the behavior of the full system with valuable conclusions in terms of thermodynamics, process engineering and automation.

A small scale remote cooling system for a superconducting cyclotron magnet

Science.gov (United States)

Haug, F.; Berkowitz Zamorra, D.; Michels, M.; Gomez Bosch, R.; Schmid, J.; Striebel, A.; Krueger, A.; Diez, M.; Jakob, M.; Keh, M.; Herberger, W.; Oesterle, D.

2017-02-01

Through a technology transfer program CERN is involved in the R&D of a compact superconducting cyclotron for future clinical radioisotope production, a project led by the Spanish research institute CIEMAT. For the remote cooling of the LTc superconducting magnet operating at 4.5 K, CERN has designed a small scale refrigeration system, the Cryogenic Supply System (CSS). This refrigeration system consists of a commercial two-stage 1.5 W @ 4.2 K GM cryocooler and a separate forced flow circuit. The forced flow circuit extracts the cooling power of the first and the second stage cold tips, respectively. Both units are installed in a common vacuum vessel and, at the final configuration, a low loss transfer line will provide the link to the magnet cryostat for the cooling of the thermal shield with helium at 40 K and the two superconducting coils with two-phase helium at 4.5 K. Currently the CSS is in the testing phase at CERN in stand-alone mode without the magnet and the transfer line. We have added a “validation unit” housed in the vacuum vessel of the CSS representing the thermo-hydraulic part of the cyclotron magnet. It is equipped with electrical heaters which allow the simulation of the thermal loads of the magnet cryostat. A cooling power of 1.4 W at 4.5 K and 25 W at the thermal shield temperature level has been measured. The data produced confirm the design principle of the CSS which could be validated.

A facile method to synthesize nitrogen and fluorine co-doped TiO{sub 2} nanoparticles by pyrolysis of (NH{sub 4}){sub 2}TiF{sub 6}

Energy Technology Data Exchange (ETDEWEB)

Chen Daimei; Jiang Zhongyi; Geng Jiaqing; Zhu Juhong; Yang Dong, E-mail: dyangdong@hotmail.co [Tianjin University, Key Laboratory for Green Chemical Technology, School of Chemical Engineering and Technology (China)

2009-02-15

The nitrogen and fluorine co-doped TiO{sub 2} (N-F-TiO{sub 2}) nanoparticles of anatase crystalline structure were prepared by a facile method of (NH{sub 4}){sub 2}TiF{sub 6} pyrolysis, and characterized by thermogravimetry-differential thermal analysis (TG-DTA), X-ray diffraction (XRD), transmission electron microscopy (TEM), X-ray photoelectron spectroscopy (XPS), and ultraviolet visible (UV-Vis) spectroscopy etc. With the increase of calcination temperature, (NH{sub 4}){sub 2}TiF{sub 6} decomposed into TiOF{sub 2} and NH{sub 4}TiOF{sub 3} at first, and then formed anatase-type TiO{sub 2} with thin sheet morphology. H{sub 3}BO{sub 3} as oxygen source can promote the formation of anatase TiO{sub 2}, but decrease the F content in the N-F-TiO{sub 2} materials due to the formation of volatile BF{sub 3} during the precursor decomposition. The photocatalytic activity of the obtained N-F-TiO{sub 2} samples was evaluated by the methylene blue degradation under visible light, and all the samples exhibited much higher photocatalytic activity than P25. Moreover, the merits and disadvantages of this proposed method to prepare doped TiO{sub 2} are discussed.

Electrically-cooled HPGe detector for advanced x-ray spectroscopy and imaging

Energy Technology Data Exchange (ETDEWEB)

Marian, V.; Clauss, J.; Pirard, B.; Quirin, P.; Flamanc, J.; Lampert, M.O. [CANBERRA France, Parc des Tanneries, 1, chemin de la roseraie, 67380 Lingolsheim (France)

2015-07-01

High Purity Germanium (HPGe) detectors are used for high-resolution x- and gamma-ray spectroscopy. For their operation, the necessary cryogenic cooling is performed with liquid nitrogen or with electromechanical coolers. Although mature and industrialized solutions, most of HPGe detectors integrating electrical coolers present a limited spectroscopic performance due to the generated mechanical vibration and electromagnetic interference. This paper describes a novel HPGe detector, specifically designed to address the challenges of ultimate x-ray spectroscopy and imaging applications. Due to the stringent demands associated with nano-scale imaging in synchrotron applications, a custom-designed cryostat was built around a Canberra CP5-Plus electrical cooler featuring extremely low vibration levels and high cooling power. The heat generated by the cryo-cooler itself, as well as the electronics, is evacuated via an original liquid cooling circuit. This architecture can also be used to address high ambient temperature, which does not allow conventional cryo-coolers to work properly. The multichannel detector head can consist of a segmented monolithic HPGe sensor, or several closely packed sensors. Each sensor channel is read out by state-of-the-art pulse-reset preamplifiers in order to achieve excellent energy resolution for count rates in excess of 1 Mcps. The sensitive electronics are located in EMI-proof housings to avoid any interference from other devices on a beam-line. The front-end of the detector is built using selected high-purity materials and alloys to avoid any fluorescence effects. We present a detailed description of the detector design and we report on its performance. A discussion is also given on the use of electrically cooled HPGe detectors for applications requiring ultimate energy resolution, such as synchrotron, medicine or nuclear industry. (authors)

Conceptual design for accelerator-driven sodium-cooled sub-critical transmutation reactors using scale laws

Energy Technology Data Exchange (ETDEWEB)

Lee, Kwang Gu; Chang, Soon Heung [Korea Advanced Institute of Science and Technology, Taejon (Korea, Republic of)

1998-12-31

The feasibility study on conceptual design methodology for accelerator-driven sodium-cooled sub-critical transmutation reactors has been conducted to optimize the design parameters from the scale laws and validates the reactor performance with the integrated code system. A 1000 MWth sodium-cooled sub-critical transmutation reactor has been scaled and verified through the methodology in this paper, which is referred to Advanced Liquid Metal Reactor (ALMR). A Pb-Bi target material and a partitioned fuel are the liquid phases, and they are cooled by the circulation of secondary Pb-Bi coolant and by primary sodium coolant, respectively. Overall key design parameters are generated from the scale laws and they are improved and validated by the integrated code system. Integrated Code System (ICS) consists of LAHET, HMCNP, ORIGEN2, and COMMIX codes and some files. Through ICS the target region, the core region, and thermal-hydraulic related regions are analyzed once-through Results of conceptual design are attached in this paper. 5 refs., 4 figs., 1 tab. (Author)

Thin films of amorphous nitrogenated carbon a-CN{sub x}: Electron transfer and surface reactivity

Energy Technology Data Exchange (ETDEWEB)

Tamiasso-Martinhon, P.; Cachet, H.; Debiemme-Chouvy, C.; Deslouis, C. [Universite Pierre et Marie Curie-Paris 6, Laboratoire Interfaces et Systemes Electrochimiques, CNRS, UPR15-LISE, 4 Place Jussieu, Paris F-75005 (France)

2008-08-01

The electrochemical behaviour of thin films of nitrogenated amorphous carbon a-CN{sub x} is similar to that of boron-doped diamond, with a wide potential window in aqueous media. They are elaborated by cathodic sputtering of a graphite target in an Ar-N{sub 2} active plasma for varying nitrogen contents, determined by XPS (0.06 {<=} x {<=} 0.39). Their electrochemical reactivity is sensitive to the surface state. The present study reports on the influence of electrochemical pre treatment on the electronic transfer rate of a fast redox system ferri-ferrocyanide, by focusing on the direction of the potential excursion. On the other hand, the role of both the pH and the potential on the interfacial capacitance in the presence of Na{sub 2}SO{sub 4} without redox species is documented. The results show up the sensitivity of the film surface to the electrochemical conditions. (author)

CO{sub 2} capture by adsorption with nitrogen enriched carbons

Energy Technology Data Exchange (ETDEWEB)

M.G. Plaza; C. Pevida; A. Arenillas; F. Rubiera; J.J. Pis [Instituto Nacional del Carbon (CSIC), Oviedo (Spain)

2007-09-15

The success of CO{sub 2} capture with solid sorbents is dependent on the development of a low cost sorbent with high CO{sub 2} selectivity and adsorption capacity. Immobilised amines are expected to offer the benefits of liquid amines in the typical absorption process, with the added advantages that solids are easy to handle and that they do not give rise to corrosion problems. In this work, different alkylamines were evaluated as a potential source of basic sites for CO{sub 2} capture, and a commercial activated carbon was used as a preliminary support in order to study the effect of the impregnation. The amine coating increased the basicity and nitrogen content of the carbon. However, it drastically reduced the microporous volume of the activated carbon, which is chiefly responsible for CO{sub 2} physisorption, thus decreasing the capacity of raw carbon at room temperature. 33 refs., 7 figs., 3 tabs.

Vacuum system of SST-1 Tokamak

Energy Technology Data Exchange (ETDEWEB)

Khan, Ziauddin, E-mail: ziauddin@ipr.res.in [Institute for Plasma Research, Near Indira Bridge, Bhat, Gandhinagar 382 428 (India); Pathan, Firozkhan; George, Siju; Semwal, Pratibha; Dhanani, Kalpesh; Paravastu, Yuvakiran; Thankey, Prashant; Ramesh, Gattu; Himabindu, Manthena; Pradhan, Subrata [Institute for Plasma Research, Near Indira Bridge, Bhat, Gandhinagar 382 428 (India)

2013-10-15

Highlights: ► Air leaks developed during ongoing SST-1 cooldown campaign were detected online using RGA. ► The presence of N{sub 2} and O{sub 2} gases with the ratio of their partial pressures with ∼3.81:1 confirmed the air leaks. ► Baking of SST-1 was done efficiently by flowing hot N{sub 2} gas in C-channels welded on inner surfaces without any problem. ► In-house fabricated demountable bull nose couplers were demonstrated for high temperature and pressure applications. ► Cryopumping effect was observed when liquid helium cooled superconducting magnets reached below 63 K. -- Abstract: Vacuum chambers of Steady State Superconducting (SST-1) Tokamak comprises of the vacuum vessel and the cryostat. The plasma will be confined inside the vacuum vessel while the cryostat houses the superconducting magnet systems (TF and PF coils), LN{sub 2} cooled thermal shields and hydraulics for these circuits. The vacuum vessel is an ultra-high (UHV) vacuum chamber while the cryostat is a high-vacuum (HV) chamber. In order to achieve UHV inside the vacuum vessel, it would be baked at 150 °C for longer duration. For this purpose, U-shaped baking channels are welded inside the vacuum vessel. The baking will be carried out by flowing hot nitrogen gas through these channels at 250 °C at 4.5 bar gauge pressure. During plasma operation, the pressure inside the vacuum vessel will be raised between 1.0 × 10{sup −4} mbar and 1.0 × 10{sup −5} mbar using piezoelectric valves and control system. An ultimate pressure of 4.78 × 10{sup −6} mbar is achieved inside the vacuum vessel after 100 h of pumping. The limitation is due to the development of few leaks of the order of 10{sup −5} mbar l/s at the critical locations of the vacuum vessel during baking which was confirmed with the presence of nitrogen gas and oxygen gas with the ratio of ∼3.81:1 indicating air leak. Similarly an ultimate vacuum of 2.24 × 10{sup −5} mbar is achieved inside the cryostat. Baking of the

A method for the determination of volatile ammonia in air, using a nitrogen-cooled trap and fluorometric detection

NARCIS (Netherlands)

Westra, H.G.; Tigchelaar, R.G.; Berden, J.A.

2001-01-01

A quick, cheap, and accurate method for the determination of ammonia in air is described. Ammonia and water vapor are trapped simultaneously in a gas sampling tube cooled in liquid nitrogen. Subsequently ammonia is derivatized with o-phthaldialdehyde and determined using fluorescence detection. The

Theoretical analysis and experimental investigation on performance of the thermal shield of accelerator cryomodules by thermo-siphon cooling of liquid nitrogen

Science.gov (United States)

Datta, T. S.; Kar, S.; Kumar, M.; Choudhury, A.; Chacko, J.; Antony, J.; Babu, S.; Sahu, S. K.

2015-12-01

Five beam line cryomodules with total 27 superconducting Radio Frequency (RF) cavities are installed and commissioned at IUAC to enhance the energy of heavy ion from 15 UD Pelletron. To reduce the heat load at 4.2 K, liquid nitrogen (LN2) cooled intermediate thermal shield is used for all these cryomodules. For three linac cryomodules, concept of forced flow LN2 cooling is used and for superbuncher and rebuncher, thermo-siphon cooling is incorporated. It is noticed that the shield temperature of superbuncher varies from 90 K to 110 K with respect to liquid nitrogen level. The temperature difference can't be explained by using the basic concept of thermo-siphon with the heat load on up flow line. A simple thermo-siphon experimental set up is developed to simulate the thermal shield temperature profile. Mass flow rate of liquid nitrogen is measured with different heat load on up flow line for different liquid levels. It is noticed that small amount of heat load on down flow line have a significant effect on mass flow rate. The present paper will be investigating the data generated from the thermosiphon experimental set up and a theoretical analysis will be presented here to validate the measured temperature profile of the cryomodule shield.

Electromagnetic losses in a three-phase high temperature superconducting cable determined by calorimetric measurements

DEFF Research Database (Denmark)

Traeholt, C.; Veje, E.; Tønnesen, Ole

2002-01-01

conventional phases (600 mm2 Cu) could be moved in the plane. It was possible to vary the inter-phase distance (centre to centre distance) from 9 to 48 cm. The HTS cable conductor was placed in a stainless steel cryostat and cooled with flowing liquid nitrogen (LN2). The losses were determined using...

Methods and apparatus for cooling electronics

Science.gov (United States)

Hall, Shawn Anthony; Kopcsay, Gerard Vincent

2014-12-02

Methods and apparatus are provided for choosing an energy-efficient coolant temperature for electronics by considering the temperature dependence of the electronics' power dissipation. This dependence is explicitly considered in selecting the coolant temperature T.sub.0 that is sent to the equipment. To minimize power consumption P.sub.Total for the entire system, where P.sub.Total=P.sub.0+P.sub.Cool is the sum of the electronic equipment's power consumption P.sub.0 plus the cooling equipment's power consumption P.sub.Cool, P.sub.Total is obtained experimentally, by measuring P.sub.0 and P.sub.Cool, as a function of three parameters: coolant temperature T.sub.0; weather-related temperature T.sub.3 that affects the performance of free-cooling equipment; and computational state C of the electronic equipment, which affects the temperature dependence of its power consumption. This experiment provides, for each possible combination of T.sub.3 and C, the value T.sub.0* of T.sub.0 that minimizes P.sub.Total. During operation, for any combination of T.sub.3 and C that occurs, the corresponding optimal coolant temperature T.sub.0* is selected, and the cooling equipment is commanded to produce it.

High-resolution spectroscopy of jet-cooled CH{sub 5}{sup +}: Progress

Energy Technology Data Exchange (ETDEWEB)

Savage, C.; Dong, F.; Nesbitt, D. J. [JILA, University of Colorado and National Institute of Standards and Technology, and Department of Chemistry and Biochemistry, University of Colorado, Boulder, Colorado 80309-0440 (United States)

2015-01-22

Protonated methane (CH{sub 5}{sup +}) is thought to be a highly abundant molecular ion in interstellar medium, as well as a potentially bright μwave- mm wave emitter that could serve as a tracer for methane. This paper describes progress and first successful efforts to obtain a high resolution, supersonically cooled spectrum of CH{sub 5}{sup +} in the 2900-3100 cm{sup −1} region, formed in a slit supersonic discharge at low jet temperatures and with sub-Doppler resolution. Short term precision in frequency measurement (< 5 MHz on an hour time scale) is obtained from a thermally controlled optical transfer cavity servoloop locked onto a frequency stabilized HeNe laser. Long term precision (< 20 MHz day-to-day) due to pressure, temperature and humidity dependent index of refraction effects in the optical transfer cavity is also present and discussed.

Mechanical design of ISABELLE magnet cryostats

International Nuclear Information System (INIS)

Kassner, D.

1977-01-01

It has been proposed to construct an intersecting storage ring accelerator, ISABELLE, at BNL, consisting of two concentric rings of magnets containing counter-rotating beams of charged particles. Each ring contains 216 dipole magnets and 138 quadrupoles. All magnets are superconducting and operate at a temperature of 4.3 K. A description of the design of the cryostats, including the internal supports, heat shield superinsulation system and the vacuum vessel is given. Details of fabrication techniques are also included

Secondary containment system for a high tritium research cryostat

International Nuclear Information System (INIS)

Tsugawa, R.T.; Fearon, D.; Souers, P.C.; Hickman, R.G.; Roberts, P.E.

1976-01-01

A 4.2- to 300-K liquid helium cryostat has been constructed for cryogenic samples of D--T containing up to 4 x 10 14 dis/s (10,000 Ci) of tritium radioactivity. The cryostat is enclosed in a secondary box, which acts as the ultimate container in case of a tritium release. Dry argon is flushed through the box, and the box atmosphere is monitored for tritium, oxygen, and water vapor. A rupture disk and abort tank protect the box atmosphere in case the sample cell breaks. If tritium breaks into the box, a powdered uranium getter trap reduces the 4 x 10 14 dis/s (10,000 Ci) to 4 x 10 9 dis/s (0.1 Ci) in 24 h. A backup palladium--zeolite getter system goes into operation if an overabundance of oxygen contaminates the uranium getter

Sub-channel analysis of LBE-cooled fuel assemblies of accelerator driven systems

International Nuclear Information System (INIS)

Cheng, X.; Hwang, D.H.

2005-01-01

In the frame of the European PDS-XADS project, two concepts of the sub-critical reactor core cooled by liquid lead-bismuth eutectic (LBE) were proposed. In this paper, the local thermal-hydraulic behavior of both LBE-cooled fuel assemblies was analyzed. For this purpose, the sub-channel analysis code MATRA was selected, and modification was made for its applications to XADS conditions. Compared to the small core concept, the large core concept has a much lower temperatures of coolant, cladding and fuel pins. This enables a short-term realization of the core design using available technologies. The high power density of the small core results in high local temperatures of coolant, cladding and fuel. Both coolant velocity and cladding temperature are such that special attention has to be paid to avoid corrosion and erosion damage of cladding materials. A parametric study shows that under the parameters considered, mixing coefficient has the biggest effect on the coolant temperature distribution, whereas the cladding temperature is strongly affected by the selection of heat transfer correlations. (author)

Effects of Nitrogen Content on the HAZ Softening of Ti-Containing High Strength Steels Manufactured by Accelerated Cooling

Energy Technology Data Exchange (ETDEWEB)

Bang, Kook-soo; Jung, Ho-shin; Park, Chan [Pukyong National University, Busan (Korea, Republic of)

2017-03-15

The effects of nitrogen content on the HAZ softening of Ti-containing high strength steels manufactured by accelerating cooling were investigated and interpreted in terms of the microstructures in the softening zone. Regardless of their content, all of the steels investigated showed a softened zone 9-10 mm wide. The minimum hardness in the zone, however, was different, with lower hardness in the higher nitrogen content steel. Microstructural observations of the steel showed that the amount of soft ferrite was increased in the zone with an increase of nitrogen content of the steel, suggesting that microstructural evolution in the HAZ is influenced by the nitrogen content. Measurements of TiN particles showed that the degree of particles coarsening in the HAZ was lower in the higher nitrogen content steel. Therefore, it is believed that finer TiN particles in the HAZ inhibit austenite grain growth more effectively, and lead to an accelerated ferrite transformation in higher nitrogen content steel, resulting in a higher amount of soft ferrite microstructure in the softened zone.

Design and fabrication of a cryostat for low temperature mechanical testing for the Mechanical and Materials Engineering group at CERN

CERN Document Server

Aviles Santillana, I; Gerardin, A; Guinchard, M; Langeslag, S A E; Sgobba, S

2015-01-01

Mechanical testing of materials at low temperatures is one of the cornerstones of the Mechanical and Materials Engineering (MME) group at CERN. A long tradition of more than 20 years and a unique know - how of such tests has been developed with an 18 kN double-walled cryostat. Large campaigns of material qualification have been carried out and the mechanical behaviour of materials at 4 K has been vastly studied in sub - size samples for projects like LEP, LHC and its experiments. With the aim of assessing the mechanical properties of materials of higher strength and/or issued from heavy gauge products for which testing standardized specimens of larger cross section might be more adapted, a new 100 kN cryostat capable of hosting different shapes of normalized samples has been carefully designed and fabricated inhouse together with the associated tooling and measurement instrumentation. It has been conceived to be able to adapt to different test frames both dynamic and static, which will be of paramount importa...

Analytical approximations for thermophysical properties of supercritical nitrogen (SCN) to be used in futuristic high temperature superconducting (HTS) cables

Energy Technology Data Exchange (ETDEWEB)

Dondapati, Raja Sekhar, E-mail: drsekhar@ieee.org [School of Mechanical Engineering, Lovely Professional University, Phagwara, Punjab 144401 (India); Ravula, Jeswanth [School of Mechanical Engineering, Lovely Professional University, Phagwara, Punjab 144401 (India); Thadela, S. [Department of Mechanical Engineering, Andhra University, Visakhapatnam, Andhra Pradesh (India); Usurumarti, Preeti Rao [Department of Mechanical Engineering, P.V.K. Institute of Technology, Anantapur, Andhra Pradesh (India)

2015-12-15

Future power transmission applications demand higher efficiency due to the limited resources of energy. In order to meet such demand, a novel method of transmission is being developed using High Temperature Superconducting (HTS) cables. However, these HTS cables need to be cooled below the critical temperature of superconductors used in constructing the cable to retain the superconductivity. With the advent of new superconductors whose critical temperatures having reached up to 134 K (Hg based), a need arises to find a suitable coolant which can accommodate the heating loads on the superconductors. The present work proposes, Supercritical Nitrogen (SCN) to be a feasible coolant to achieve the required cooling. Further, the feasibility of proposed coolant to be used in futuristic HTS cables is investigated by studying the thermophysical properties such as density, viscosity, specific heat and thermal conductivity with respect to temperature (T{sub C} + 10 K) and pressure (P{sub C} + 10 bar). In addition, few temperature dependent analytical functions are developed for thermophysical properties of SCN which are useful in predicting thermohydraulic performance (pressure drop, pumping power and cooling capacity) using numerical or computational techniques. Also, the developed analytical functions are used to calculate the pumping power and the temperature difference between inlet and outlet of HTS cable. These results are compared with those of liquid nitrogen (LN2) and found that the circulating pumping power required to pump SCN is significantly smaller than that to pump LN2. Further, it is found that the temperature difference between the inlet and outlet is smaller as compared to that when LN2 is used, SCN can be preferred to cool long length Hg based HTS cables. - Highlights: • Analytical functions are developed for thermophysical properties of Supercritical Nitrogen. • Error analysis shows extremely low errors in the developed analytical functions. �

Theoretical Modeling and Experimental Investigation of the Thermal Performance of the LHC Prototype Lattice Cryostats

CERN Document Server

Riddone, G

1997-01-01

This thesis presents the thermal performance of the LHC (Large Hadron Collider) prototype cryostats both in steady-state and in transient conditions. LHC will be built in the 27 km LEP tunnel and will provide proton-proton collisions. It will make use of superconducting magnets operating in static bath of superfluid helium at 1.9 K. The thesis is mainly divided in three parts. The first part cont ains three chapters which present a brief overview of the LHC project. Part 1-Chapter 1 gives a short introduction to the LHC design layout and performance. Part 1-Chapter 2 refers to LHC cryogenic s ystem and describes the general architecture of the cryogenic plants, the temperature levels and the heat loads. The 50 m long LHC prototype half-cell contains one twin-bore quadrupole and four twin-a perture dipoles. In Part 1-Chapter 3 the design and construction of the prototype dipole and quadrupole cryostats are presented. The LHC prototype cryostats have integrated cryogenic lines, while the final LHC cryostats hav...

CO/sub 2/ enrichment improves recovery of growth and photosynthesis from drought and nitrogen stress in maize

International Nuclear Information System (INIS)

Zong, Y.

2014-01-01

In the context of the increasing risk of extreme drought as a result of climate change and increasing CO/sub 2/ in the future of northwest China, evaluation of crops ability to recover and survive droughts requires further attention. To test the effects of re-watering on plants suffering water and nitrogen limitations in the presence of elevated CO/sub 2/, maize (Zea mays) was planted to experience combined elevated CO/sub 2/ (380 or 750 micro mol/sup -1/, climate chamber), water stress (15% PEG-6000) and nitrogen limitation (5 or 15mM N in Hoagland solutions) and then re-watered at three levels (300mL, 600mL, 900mL per pot of distilled water). When plants were re-watered, drought stressed and N limited plants with ambient CO/sub 2/ increased their water content more than that of elevated CO/sub 2/, while the enhancement of growth rate were negatively related to the increasing plant water content. Elevated CO/sub 2/ could help re-watered seedlings to have higher photosynthetic capacity (Fv/Fm, PSII, Pn,Pn/Tr and Pn/Gs) and new leaf growth under low water content, apart from nitrogen deficiency. The results demonstrated that elevated CO2 could help drought stressed seedlings to maintain higher carbon assimilation rates under low water content, as a result to improve leaf water use efficiency. (author)

Impact of CO/sub 2/ on cooling of snow and water surfaces

Energy Technology Data Exchange (ETDEWEB)

Choudhury, B [Computer Sciences Corp., Silver Spring, MD; Kukla, G

1979-08-23

The levels of CO/sub 2/ in the atmosphere are being increased by the burning of fossil fuels and reduction of biomass. It has been calculated that the increase in CO/sub 2/ levels should lead to global warming because of increased absorption by the atmosphere of terrestrial longwave radiation in the far IR (> 5 ..mu..m). From model computations, CO/sub 2/ is expected to produce the largest climatic effect in high latitudes by reducing the size of ice and snow fields. We present here computations of spectral radiative transfer and scattering within a snow pack and water. The results suggest that CO/sub 2/ significantly reduces the shortwave energy absorbed by the surface of snow and water. The energy deficit, when not compensated by downward atmospheric radiation, may delay the recrystallisation of snow and dissipation of packice and result in a cooling rather than a warming effect.

GreenChill Store Certification Protocol for Sub-Cooling Contained on Racks Separate from Refrigeration Equipment

Science.gov (United States)

Document describes the protocol used to determine the total load and refrigerant charge of stores that have placed all sub-cooling on a rack separate from all other commercial refrigeration equipment.

Bi-phase CO{sub 2} cooling of the CBM STS detector

Energy Technology Data Exchange (ETDEWEB)

Lavrik, Evgeny [Physikalisches Institut der Universitaet Tuebingen (Germany); Collaboration: CBM-Collaboration

2016-07-01

The Compressed Baryonic Matter (CBM) experiment aims to study the properties of nuclear matter at high net-baryon densities. The Silicon Tracking System (STS) is the key detector to reconstruct charged particle tracks created in heavy-ion interactions. The foreseen interaction rate of up to 10 MHz requires radiation hard detectors as well as efficient cooling of the silicon sensors. To avoid thermal runaway the system must be kept at -5 C or below all the time. This is rather challenging because the overall thermal load in the 2 m{sup 3} STS enclosure is up to 40 kW. Because of these requirements liquid CO{sub 2} is used as a cooling agent as it is superior in terms of volumetric heat transfer coefficient compared to other agents. This contribution shows the thermal simulations and measurement results of the STS front-end electronic boxes as well as an overview of 1 kW TRACI-XL cooling plant developed at GSI and its use to perform thermal measurements of a fully heat loaded STS quarter station.

Superconducting generators and motors and methods for employing same

Energy Technology Data Exchange (ETDEWEB)

Tomsic, Michael J.; Long, Larry

2017-08-29

A superconducting electrical generator or motor having a plurality of cryostats is described. The cryostats contain coolant and a first cryostat encloses at least one of a plurality of superconducting coils. A first coil is in superconducting electrical communication with a second coil contained in a second cryostat through a superconducting conduction cooling cable enclosing a conductor. The first cryostat and the second cryostat may be in fluid communication through at least one cryogen channel within the at least one superconducting conduction cooling cable. In other embodiments, none of the plurality of cryostats may be in fluid communication and the cable may be cooled by conduction along the conductor from the first or second cryostat, or from both. The conductor may have different segments at temperatures equal to or above the temperature of the coolant and the superconducting conduction cooling cables may be connected through quick connect fittings.

Molecular nitrogen fixation and nitrogen cycle in nature

Energy Technology Data Exchange (ETDEWEB)

Virtanen, A I

1952-01-01

The origin of nitrogen oxides in the atmosphere is discussed. Evidently only a small proportion of the nitrate-and nitrite-nitrogen found in the precipitation is formed through electric discharges from molecular nitrogen, photochemical nitrogen fixation being probably of greater importance. Formation of nitrate nitrogen through atmospheric oxidation of nitrous oxide (N/sub 2/O) evaporating from the soil is also considered likely. Determination of nitrogen compounds at different altitudes is indispensable for gaining information of the N/sub 2/-fixation in the atmosphere and, in general, of the origin of nitrogen oxides and their decomposition. International cooperation is needed for this as well as for the quantitative determination of the nitrogen compounds removed from the soil by leaching and brought by waters into the seas.

Vitrification of human pronuclear oocytes by direct plunging into cooling agent: Non sterile liquid nitrogen vs. sterile liquid air.

Science.gov (United States)

Isachenko, Vladimir; Todorov, Plamen; Seisenbayeva, Akerke; Toishibekov, Yerzhan; Isachenko, Evgenia; Rahimi, Gohar; Mallmann, Peter; Foth, Dolores; Merzenich, Markus

2018-02-01

In fact, a full sterilization of commercially-produced liquid nitrogen contaminated with different pathogens is not possible. The aim of this study was to compare the viability of human pronuclear oocytes subjected to cooling by direct submerging of open carrier in liquid nitrogen versus submerging in clean liquid air (aseptic system). One- and three-pronuclei stage embryos (n = 444) were cryopreserved by direct plunging into liquid nitrogen (vitrified) in ethylene glycol (15%), dimethylsulphoxide (15%) and 0.2M sucrose. Oocytes were exposed in 20, 33, 50 and 100% vitrification solution for 2, 1 and 1 min, and 30-50 s, respectively at room temperature. Then first part of oocytes (n = 225) were directly plunged into liquid nitrogen, and second part of oocytes (n = 219) into liquid air. Oocytes were thawed rapidly at a speed of 20,000 °C/min and then subsequently were placed into a graded series of sucrose solutions (0.5, 0.25, 0.12 and 0.06M) at 2.5 min intervals and cultured in vitro for 3 days. In both groups, the rate of high-quality embryos (Grade 6A: 6 blastomeres, no fragmentation; Grade 8A: 8 blastomeres, no fragmentation; Grade 8A compacting: 8 blastomeres, beginning of compacting) was noted. The rates of high-quality embryos developed from one-pronuclear oocytes vitrified by cooling in liquid nitrogen and liquid air were: 39.4% ± 0.6 and 38.7% ± 0.8, respectively (P > 0.1). These rates for three-pronuclear oocytes were: 45.8 ± 0.8% and 52.0 ± 0.7%, respectively (P liquid air (aseptic system) is a good alternative for using of not sterile liquid nitrogen. Copyright © 2017. Published by Elsevier Inc.

TiO{sub 2} nanoparticles on nitrogen-doped graphene as anode material for lithium ion batteries

Energy Technology Data Exchange (ETDEWEB)

Li Dan; Shi Dongqi [Institute for Superconducting and Electronic Materials, University of Wollongong (Australia); Liu Zongwen [University of Sydney, School of Chemical and Biomolecular Engineering (Australia); Liu Huakun; Guo Zaiping, E-mail: zguo@uow.edu.au [Institute for Superconducting and Electronic Materials, University of Wollongong (Australia)

2013-05-15

Anatase TiO{sub 2} nanoparticles in situ grown on nitrogen-doped, reduced graphene oxide (rGO) have been successfully synthesized as an anode material for the lithium ion battery. The nanosized TiO{sub 2} particles were homogeneously distributed on the reduced graphene oxide to inhibit the restacking of the neighbouring graphene sheets. The obtained TiO{sub 2}/N-rGO composite exhibits improved cycling performance and rate capability, indicating the important role of reduced graphene oxide, which not only facilitates the formation of uniformly distributed TiO{sub 2} nanocrystals, but also increases the electrical conductivity of the composite material. The introduction of nitrogen on the reduced graphene oxide has been proved to increase the conductivity of the reduced graphene oxide and leads to more defects. A disordered structure is thus formed to accommodate more lithium ions, thereby further improving the electrochemical performance.

Enzymology under global change: organic nitrogen turnover in alpine and sub-Arctic soils

NARCIS (Netherlands)

Weedon, J.T.; Aerts, R.; Kowalchuk, G.A.; van Bodegom, P.M.

2011-01-01

Understanding global change impacts on the globally important carbon storage in alpine, Arctic and sub-Arctic soils requires knowledge of the mechanisms underlying the balance between plant primary productivity and decomposition. Given that nitrogen availability limits both processes, understanding

Enzymology under global change: organic nitrogen turnover in alpine and sub-Arctic soils.

NARCIS (Netherlands)

Weedon, J.T.; Aerts, R.; Kowalchuk, G.A.; van Bodegom, P.M.

2011-01-01

Understanding global change impacts on the globally important carbon storage in alpine, Arctic and sub-Arctic soils requires knowledge of the mechanisms underlying the balance between plant primary productivity and decomposition. Given that nitrogen availability limits both processes, understanding

Azo dyes decomposition on new nitrogen-modified anatase TiO{sub 2} with high adsorptivity

Energy Technology Data Exchange (ETDEWEB)

Janus, M., E-mail: mjanus@ps.pl [Szczecin University of Technology, Department of Sanitary Engineering, al. Piastow 50, 70-310 Szczecin (Poland); Szczecin University of Technology, Institute of Chemical and Environment Engineering, Department of Water Technology and Environment Engineering, ul. Pulaskiego 10, 70-322 Szczecin (Poland); Choina, J.; Morawski, A.W. [Szczecin University of Technology, Institute of Chemical and Environment Engineering, Department of Water Technology and Environment Engineering, ul. Pulaskiego 10, 70-322 Szczecin (Poland)

2009-07-15

New vis active photocatalyst was obtained by the modification of commercial anatase TiO{sub 2} (Police, Poland) in pressure reactor in an ammonia water atmosphere at 100 {sup o}C for 4 h. The photocatalytic activity of new material was tested during three azo dyes decomposition: monoazo (Reactive Read), diazo (Reactive Black) and poliazodye (Direct Green). Obtained photocatalyst had new bands at 1430-1440 cm{sup -1} attributed to the bending vibrations of NH{sub 4}{sup +} and at 1535 cm{sup -1} associated with NH{sub 2} groups or NO{sub 2} and NO. UV-vis/DR spectra of photocatalyst had also insignificant decrease in visible region. Fluorescence technique was used for studying the amount of hydroxyl radicals produced on TiO{sub 2} surface during visible light irradiation. The hydroxyl radicals produced react with coumarin present in the solution to form 7-hydroxycoumarin which has fluorescent capacity. Photocatalytic activity of modified TiO{sub 2} was compared with commercial titanium dioxide P25 (Degussa, Germany). The photocatalytic activity of TiO{sub 2}/N was higher than that of unmodified material and P25 under visible light irradiation. The ability for dye adsorption (Reactive Red) on photocatalyst surface was also tested. Unmodified TiO{sub 2} and P25 has isotherm of adsorption by Freundlich model, and nitrogen-modified TiO{sub 2} by Langmuir model. The presence of nitrogen at the surface of TiO{sub 2} significantly increased adsorption capacity of TiO{sub 2} as well as OH{center_dot} radicals formation under visible radiation.

Optimization of the outer support in the ITER lower cryostat thermal shield

International Nuclear Information System (INIS)

Noh, C.H.; Chung, W.; Lim, J.; Lee, B.C.

2016-01-01

Highlights: • Design methodology for the ITER lower cryostat thermal shield support is described. • Design optimization is performed using the kriging meta-model. • Single plate support design is proposed as an alternative design. • Proposed design has 24% reduced weight compared with the initial design. - Abstract: ITER Lower Cryostat Thermal Shield (LCTS) is fixed to the cryostat floor by a thin flexible plate support. Double plate made of titanium alloy is adopted as a reference design. Double plate is effective to get structural reliability for the high inertia load and buckling load. Thin plate with titanium alloy has good flexibility to the thermal movement and reduces conduction heat load from cryostat floor to the thermal shield. Double plate support has enough structural margin. In addition, titanium alloy requires high cost for fabrication. Design optimization is required to save manufacturing expenses. In addition to the mass minimization, design modification from double plate to single plate is proposed, because welding of double plate is difficult due to narrow gap between two plates. In this paper, design process to find optimal design of LCTS support is described. The sensitivities of the design variables such as thickness, height, width and gap between two plates are investigated. Optimal design solution is obtained by Sequential Quadratic Programming (SQP) algorithm based on the meta-model developed by randomly selected experimental samples. Through the design optimization process, optimal designs of the LCTS support are obtained. The weight of the support plates can be reduced to 24% compared with the initial design.

Optimization of the outer support in the ITER lower cryostat thermal shield

Energy Technology Data Exchange (ETDEWEB)

Noh, C.H., E-mail: chnoh@nfri.re.kr [National Fusion Research Institute, Daejeon, 305-333 (Korea, Republic of); Korea Advanced Institute of Science and Technology, Daejeon, 305-338 (Korea, Republic of); Chung, W., E-mail: whchung@nfri.re.kr [National Fusion Research Institute, Daejeon, 305-333 (Korea, Republic of); Lim, J., E-mail: jongmin.lim@kaist.ac.kr [Korea Advanced Institute of Science and Technology, Daejeon, 305-338 (Korea, Republic of); Lee, B.C., E-mail: bclee@kaist.ac.kr [Korea Advanced Institute of Science and Technology, Daejeon, 305-338 (Korea, Republic of)

2016-02-15

Highlights: • Design methodology for the ITER lower cryostat thermal shield support is described. • Design optimization is performed using the kriging meta-model. • Single plate support design is proposed as an alternative design. • Proposed design has 24% reduced weight compared with the initial design. - Abstract: ITER Lower Cryostat Thermal Shield (LCTS) is fixed to the cryostat floor by a thin flexible plate support. Double plate made of titanium alloy is adopted as a reference design. Double plate is effective to get structural reliability for the high inertia load and buckling load. Thin plate with titanium alloy has good flexibility to the thermal movement and reduces conduction heat load from cryostat floor to the thermal shield. Double plate support has enough structural margin. In addition, titanium alloy requires high cost for fabrication. Design optimization is required to save manufacturing expenses. In addition to the mass minimization, design modification from double plate to single plate is proposed, because welding of double plate is difficult due to narrow gap between two plates. In this paper, design process to find optimal design of LCTS support is described. The sensitivities of the design variables such as thickness, height, width and gap between two plates are investigated. Optimal design solution is obtained by Sequential Quadratic Programming (SQP) algorithm based on the meta-model developed by randomly selected experimental samples. Through the design optimization process, optimal designs of the LCTS support are obtained. The weight of the support plates can be reduced to 24% compared with the initial design.

A study of parameter setting and characterization of visible-light driven nitrogen-modified commercial TiO{sub 2} photocatalysts

Energy Technology Data Exchange (ETDEWEB)

Kuo, Yu-Lin, E-mail: ylkuo@mail.ntust.edu.tw [Department of Mechanical Engineering, National Taiwan University of Science and Technology, No. 43, Sec. 4, Keelung Rd., Taipei 106, Taiwan (China); Su, Te-Li [Department of Cosmetic Application and Management, St. Mary' s Medicine, Nursing and Management College, Yilan 266, Taiwan (China); Kung, Fu-Chen [Department of Health Developing and Health Marketing, Kainan University, Taoyuan County 338, Taiwan (China); Wu, Tsai-Jung [Department of Mechanical Engineering, National Taiwan University of Science and Technology, No. 43, Sec. 4, Keelung Rd., Taipei 106, Taiwan (China)

2011-06-15

Highlights: {yields} A cost-effective and highly-efficient visible-light driven nitrogen-modified TiO{sub 2} photocatalyst was prepared by a simple hydrolysis method. {yields} The obtained optimum conditions applied to Taguchi method for preparing visible-light driven photocatalyst were undergone by the process of stirring for 1 day using 4M ammonium as the nitrogen source, and then calcining at 400{sup Degree-Sign }C for 2 h. {yields} Several materials technologies of characterizing N-TiO2 photocatalyst have been used to realize the modification of TiO2 by ammonia water as the nitrogen source. - Abstract: An optimal condition applied to the Taguchi method with an L{sub 9} orthogonal array for preparing a visible-light driven nitrogen-modified TiO{sub 2} (N-TiO{sub 2}) photocatalyst by a simple hydrolysis method has been examined for material characteristics and a photodecolorization test of methyl blue (MB) under various visible light source (fluorescent and blue LED lamps) irradiations. Results of the material characterization showed that the absorption of prepared N-TiO{sub 2} powder exhibited a significant extension into visible light regimes with an optical bandgap (Eg) of around 2.96 eV, which subsequently improved the visible-light photocatalytic activity of N-TiO{sub 2} samples. The superior photocatalytic properties, the pseudo first-order reaction rate constants (k) and photodecolorization efficiency ({eta}%) of a N-TiO{sub 2} photocatalyst during the photodecolorization test of methyl blue (MB) under two different visible light irradiations were very evident compared to those for pure TiO{sub 2}. For photodecolorization of practical dyeing from the waste water from the dyeing and finishing industry, a higher photodecolorization efficiency of N-TiO{sub 2} powder toward Direct blue-86 (DB-86) (Direct Fast Turquoise Blue GL) dye was also achieved.

Reduction of circulation power for helium-cooled fusion reactor blanket using additive CO{sub 2} gas

Energy Technology Data Exchange (ETDEWEB)

Lee, Yeon-Gun [Department of Nuclear Engineering, Seoul National University, 1 Gwanak-ro, Gwanak-gu, Seoul 151-744 (Korea, Republic of); Department of Nuclear and Energy Engineering, Jeju National University, 102 Jejudaehakno, Jeju-si 690-756, Jeju (Korea, Republic of); Park, Il-Woong [Department of Nuclear Engineering, Seoul National University, 1 Gwanak-ro, Gwanak-gu, Seoul 151-744 (Korea, Republic of); Lee, Dong Won [Nuclear Fusion Engineering Development Center, Korea Atomic Energy Research Institute, Daedeokdaero 989 beon-gil, Yuseong-gu, Daejeon 305-353 (Korea, Republic of); Park, Goon-Cherl [Department of Nuclear Engineering, Seoul National University, 1 Gwanak-ro, Gwanak-gu, Seoul 151-744 (Korea, Republic of); Kim, Eung-Soo, E-mail: kes7741@snu.ac.kr [Department of Nuclear Engineering, Seoul National University, 1 Gwanak-ro, Gwanak-gu, Seoul 151-744 (Korea, Republic of)

2015-11-15

Helium (He) cooling requires large circulation power to remove high heat from plasma side and nuclear heating by high energy neutron in fusion reactors due to its low density. Based on the recent findings that the heat transfer capability of the light gas can be enhanced by mixing another heavier gas, this study adds CO{sub 2} to a reference helium coolant and evaluates the cooling performance of the binary mixture for various compositions. To assess the cooling performance, computational fluid dynamic (CFD) analyses on the KO HCML (Korea Helium Cooled Molten Lithium) TBM are conducted. As a result, it is revealed that the binary mixing of helium, which has favorable thermophysical properties but the density, with a heavier noble gas or an unreactive gas significantly reduces the required circulation power by an order of magnitude with meeting the thermal design requirements. This is attributed to the fact that the density can be highly increased with small amount of a heavier gas while other gas properties are kept relatively comparable. The optimal CO{sub 2} mole fraction is estimated to be 0.4 and the circulation power, in this case, can be reduced to 13% of that of pure helium. This implies that the thermal efficiency of a He-cooled blanket system can be fairly enhanced by means of the proposed binary mixing.

Model estimate of NO{sub x} production during the cooling of a lightning flash

Energy Technology Data Exchange (ETDEWEB)

Berton, R. [Office National d`Etudes et de Recherches Aerospatiales (ONERA), 92 - Chatillon (France)

1997-12-31

Since discrepancies of two orders of magnitude are detected in current estimations, the question of NO{sub x} production by lightning has been addressed, and a new theoretical estimate is proposed. The new model deals with a unit length of an evanescent cooling branch of lightning supposed to be cylindrical and axisymmetrical, 1 mm in radius. The kinetics of five chemical species (N, O, N{sub 2}, O{sub 2}, NO) has been coupled to the full set of hydrodynamic equations expressing the conservation of momentum and energy together with an equation of state. This highly nonlinear system is completed by suitable boundary conditions in subsonic regime and then time-integrated by finite differences. It appears that the amount of NO produced in a cross section of channel reaches a maximum at 4,6.10{sup -7} mol/m after 50 {mu}s cooling. At that moment the average temperature is about 3000 K, at which NO is most easily formed. The net yield of NO is found to be 10{sup 16} molecules per Joule, which is one order of magnitude smaller than other theoretical results. (author) 4 refs.

Model estimate of NO{sub x} production during the cooling of a lightning flash

Energy Technology Data Exchange (ETDEWEB)

Berton, R [Office National d` Etudes et de Recherches Aerospatiales (ONERA), 92 - Chatillon (France)

1998-12-31

Since discrepancies of two orders of magnitude are detected in current estimations, the question of NO{sub x} production by lightning has been addressed, and a new theoretical estimate is proposed. The new model deals with a unit length of an evanescent cooling branch of lightning supposed to be cylindrical and axisymmetrical, 1 mm in radius. The kinetics of five chemical species (N, O, N{sub 2}, O{sub 2}, NO) has been coupled to the full set of hydrodynamic equations expressing the conservation of momentum and energy together with an equation of state. This highly nonlinear system is completed by suitable boundary conditions in subsonic regime and then time-integrated by finite differences. It appears that the amount of NO produced in a cross section of channel reaches a maximum at 4,6.10{sup -7} mol/m after 50 {mu}s cooling. At that moment the average temperature is about 3000 K, at which NO is most easily formed. The net yield of NO is found to be 10{sup 16} molecules per Joule, which is one order of magnitude smaller than other theoretical results. (author) 4 refs.

Properties of the (Sm sub 0 sub . sub 3 sub 3 Eu sub 0 sub . sub 3 sub 3 Gd sub 0 sub . sub 3 sub 3)Ba sub 2 Cu sub 3 O sub y superconductor prepared by different processes in air

CERN Document Server

Giovannelli, F; Monot-Laffez, I

2003-01-01

Bars and pellets of the (Sm sub 0 sub . sub 3 sub 3 Eu sub 0 sub . sub 3 sub 3 Gd sub 0 sub . sub 3 sub 3)Ba sub 2 Cu sub 3 O sub x superconductor were processed in air, using the floating zone method and the top-seeded melt-textured growth method, respectively. The samples were prepared using different experimental conditions, i.e. maximal processing temperature, translation rate or cooling rate. Their physical properties and their microstructure were studied. All the samples exhibit a satisfying superconducting transition whereas the critical current density greatly depends on the processing parameters. The sample prepared by the floating zone method at 1070 deg C with a translation rate of 2 mm h sup - sup 1 exhibits a very high J sub c value of 70000 A cm sup - sup 2 in the self-field and more than 30000 A cm sup - sup 2 at 1.7 T. The pellet processed at 1080 deg C with a cooling rate of 2 deg C h sup - sup 1 has a high J sub c reaching about 56000 A cm sup - sup 2 in the self-field and more than 32000 A ...

A Conduction-Cooled Superconducting Magnet System-Design, Fabrication and Thermal Tests

DEFF Research Database (Denmark)

Song, Xiaowei (Andy); Holbøll, Joachim; Wang, Qiuliang

2015-01-01

A conduction-cooled superconducting magnet system with an operating current of 105.5 A was designed, fabricated and tested for material processing applications. The magnet consists of two coaxial NbTi solenoid coils with an identical vertical height of 300 mm and is installed in a high-vacuumed c......A conduction-cooled superconducting magnet system with an operating current of 105.5 A was designed, fabricated and tested for material processing applications. The magnet consists of two coaxial NbTi solenoid coils with an identical vertical height of 300 mm and is installed in a high......-vacuumed cryostat. A two-stage GM cryocooler with a cooling power of 1.5 W at 4.2 K in the second stage is used to cool the system from room temperature to 4.2 K. In this paper, the detailed design, fabrication, thermal analysis and tests of the system are presented....

Strength analysis of CARR-CNS with crescent-shape moderator cell and helium sub-cooling jacket covering cell

International Nuclear Information System (INIS)

Yu Qingfeng; Feng Quanke; Kawai Takeshi; Shen Feng; Yuan Luzheng; Cheng Liang

2005-01-01

The new type of the moderator cell was developed for the cold neutron source (CNS) of the China Advanced Research Reactor (CARR) which is now being constructed at the China Institute of Atomic Energy in Beijing. A crescent-shape moderator cell covered by the helium sub-cooling jacket is adopted. The structure of the moderator cell is optimized by the stress FEM analysis. A crescent-shape would help to increase the volume of the moderator cell for fitting it to the four cold neutron guide tubes, even if liquid hydrogen, not liquid deuterium, was used as a cold moderator. The helium sub-cooling jacket covering the moderator cell removes the nuclear heating of the outer shell wall of the cell. It contributes to reduce the void fraction of liquid hydrogen in the outer shell of the moderator cell. Such a type of a moderator cell is suitable for the CNS with higher nuclear heating. The cold helium gas flows down first into the helium sub-cooling jacket and then flows up to the condenser. The theory of the self-regulation suitable to the thermo-siphon type of the CNS is also applicable and validated

Exciton-related nonlinear optical response and photoluminescence in dilute nitrogen In{sub x}Ga{sub 1−x}N{sub y}As{sub 1−y}/GaAs cylindrically shaped quantum dots

Energy Technology Data Exchange (ETDEWEB)

Duque, C.M.; Morales, A.L. [Grupo de Materia Condensada-UdeA, Instituto de Física, Facultad de Ciencias Exactas y Naturales, Universidad de Antioquia UdeA, Calle 70 No. 52-21, Medellín (Colombia); Mora-Ramos, M.E. [Grupo de Materia Condensada-UdeA, Instituto de Física, Facultad de Ciencias Exactas y Naturales, Universidad de Antioquia UdeA, Calle 70 No. 52-21, Medellín (Colombia); Facultad de Ciencias, Universidad Autónoma del Estado de Morelos, Av. Universidad 1001, CP 62209 Cuernavaca, Morelos (Mexico); Duque, C.A. [Grupo de Materia Condensada-UdeA, Instituto de Física, Facultad de Ciencias Exactas y Naturales, Universidad de Antioquia UdeA, Calle 70 No. 52-21, Medellín (Colombia)

2014-10-15

An investigation of the effects of the dilute nitrogen contents in the exciton states of cylindrical In{sub x}Ga{sub 1−x}N{sub y}As{sub 1−y}/GaAs quantum dots is presented. The exciton states in the system are obtained within the effective mass theory and the band anti-crossing model. Exciton-related nonlinear optical absorption and refractive index change, as well as excitonic photoluminescence are studied with the help of the calculated exciton states. - Highlights: • Theoretical study of excitons in cylindrical In{sub x}Ga{sub 1−x}N{sub y}As{sub 1−y}/GaAs quantum dots. • Calculations of binding energy for different configurations of electron-hole pairs. • Nonlinear optical absorption and refractive index changes. • Dependence of photoluminescence energy transitions with several inputs.

Ellipsometric investigation of nitrogen doped diamond thin films grown in microwave CH{sub 4}/H{sub 2}/N{sub 2} plasma enhanced chemical vapor deposition

Energy Technology Data Exchange (ETDEWEB)

Ficek, Mateusz, E-mail: rbogdan@eti.pg.gda.pl [Department of Metrology and Optoelectronics, Faculty of Electronics, Telecommunications and Informatics, Gdansk University of Technology, 11/12 G. Narutowicza St., 80-233 Gdansk (Poland); Institute for Materials Research (IMO), Hasselt University, Wetenschapspark 1, B-3590 Diepenbeek (Belgium); Sankaran, Kamatchi J.; Haenen, Ken [Institute for Materials Research (IMO), Hasselt University, Wetenschapspark 1, B-3590 Diepenbeek (Belgium); IMOMEC, IMEC vzw, Wetenschapspark 1, B-3590 Diepenbeek (Belgium); Ryl, Jacek; Darowicki, Kazimierz [Department of Electrochemistry, Corrosion and Material Engineering, Gdansk University of Technology, 11/12 Narutowicza St., 80-233 Gdansk (Poland); Bogdanowicz, Robert [Department of Metrology and Optoelectronics, Faculty of Electronics, Telecommunications and Informatics, Gdansk University of Technology, 11/12 G. Narutowicza St., 80-233 Gdansk (Poland); Materials and Process Simulation Center, California Institute of Technology, Pasadena, California 91125 (United States); Lin, I-Nan [Department of Physics, Tamkang University, Tamsui 251, Taiwan (China)

2016-06-13

The influence of N{sub 2} concentration (1%–8%) in CH{sub 4}/H{sub 2}/N{sub 2} plasma on structure and optical properties of nitrogen doped diamond (NDD) films was investigated. Thickness, roughness, and optical properties of the NDD films in the VIS–NIR range were investigated on the silicon substrates using spectroscopic ellipsometry. The samples exhibited relatively high refractive index (2.6 ± 0.25 at 550 nm) and extinction coefficient (0.05 ± 0.02 at 550 nm) with a transmittance of 60%. The optical investigation was supported by the molecular and atomic data delivered by Raman studies, bright field transmission electron microscopy imaging, and X-ray photoelectron spectroscopy diagnostics. Those results revealed that while the films grown in CH{sub 4}/H{sub 2} plasma contained micron-sized diamond grains, the films grown using CH{sub 4}/H{sub 2}/(4%)N{sub 2} plasma exhibited ultranano-sized diamond grains along with n-diamond and i-carbon clusters, which were surrounded by amorphous carbon grain boundaries.

Electrochemical study of a novel high performance supercapacitor based on MnO{sub 2}/nitrogen-doped graphene nanocomposite

Energy Technology Data Exchange (ETDEWEB)

Naderi, Hamid Reza, E-mail: hrnaderi@ut.ac.ir [Center of Excellence in Electrochemistry, Faculty of Chemistry, University of Tehran, Tehran (Iran, Islamic Republic of); Norouzi, Parviz, E-mail: norouzi@khayam.ut.ac.ir [Center of Excellence in Electrochemistry, Faculty of Chemistry, University of Tehran, Tehran (Iran, Islamic Republic of); Biosensor Research Center, Endocrinology & Metabolism Molecular-Cellular Sciences Institute, Tehran University of Medical Sciences, Tehran (Iran, Islamic Republic of); Ganjali, Mohammad Reza, E-mail: ganjali@khayam.ut.ac.ir [Center of Excellence in Electrochemistry, Faculty of Chemistry, University of Tehran, Tehran (Iran, Islamic Republic of); Biosensor Research Center, Endocrinology & Metabolism Molecular-Cellular Sciences Institute, Tehran University of Medical Sciences, Tehran (Iran, Islamic Republic of)

2016-03-15

Graphical abstract: - Highlights: • MnO{sub 2} nanoparticles was prepared by sonochemical method. • MnO{sub 2} are anchored on the surface of nitrogen-doped reduced graphene oxide (NRGO). • MnO{sub 2}/NRGO nanocomposite show high capacitance, good rate and cycling performance. • The nanocomposite electrode exhibits specific capacitance of 522 F g{sup −1} in 2 mV s{sup −1}. • The electrode reveals 97% retention of initial capacitance after 4000 cycles. - Abstract: A new nanocomposite was synthesized via deposition of MnO{sub 2} on Nitrogen-doped reduced graphene (MnO{sub 2}/NRGO) by sonochemical method, in which, the particles of manganese oxide were uniformly distributed on NRGO sheets. The structure and morphology of MnO{sub 2}/NRGO nanocomposites are characterized by X-ray diffraction (XRD), X-ray photoemission spectroscopy (XPS), scanning electron microscopy (SEM), transmission electron microscopy (TEM) and Raman spectroscopy. The electrochemical supercapacitive performance of the nanocomposite was investigated by cyclic voltammetry (CV), continuous cyclic voltammetry (CCV), galvanostatic charge/discharge, and electrochemical impedance spectroscopy (EIS) methods. The MnO{sub 2}/NRGO nanocomposite shows enhanced specific capacitance of 522 F g{sup −1} at 2 mV s{sup −1} and its high synergistic effect was compared with MnO{sub 2}/RGO. The high specific capacitance and exceptionally high cyclic stability of MnO{sub 2}/NRGO attributes to the doping of nitrogen and uniform dispersion of MnO{sub 2} particles on NRGO. The CCV showed that the capacity retention for MnO{sub 2}/NRGO and MnO{sub 2}/RGO still maintained at 96.3% and 93% after 4000 CVs. The improved supercapacitive performance enables this nanocomposite as efficient electrode material for supercapacitor electrodes.

Influence of stripping and cooling atmospheres on surface properties and corrosion of zinc galvanizing coatings

Energy Technology Data Exchange (ETDEWEB)

Yasakau, K.A., E-mail: kyasakau@ua.pt [Department of Materials and Ceramic Engineering, CICECO—Aveiro Institute of Materials, University of Aveiro, 3810-193 Aveiro (Portugal); Giner, I. [Universität Paderborn, Fakultät NW—Department Chemie, Technische und Makromolekulare Chemie, Warburger Strasse 100, D-33098 Paderborn (Germany); Vree, C. [Salzgitter Mannesmann Forschung, GmbH Division Surface Technology, Eisenhüttenstrasse 99, 38239 Salzgitter (Germany); Ozcan, O.; Grothe, R. [Universität Paderborn, Fakultät NW—Department Chemie, Technische und Makromolekulare Chemie, Warburger Strasse 100, D-33098 Paderborn (Germany); Oliveira, A. [Department of Materials and Ceramic Engineering, CICECO—Aveiro Institute of Materials, University of Aveiro, 3810-193 Aveiro (Portugal); Grundmeier, G. [Universität Paderborn, Fakultät NW—Department Chemie, Technische und Makromolekulare Chemie, Warburger Strasse 100, D-33098 Paderborn (Germany); Ferreira, M.G.S. [Department of Materials and Ceramic Engineering, CICECO—Aveiro Institute of Materials, University of Aveiro, 3810-193 Aveiro (Portugal); Zheludkevich, M.L. [Department of Materials and Ceramic Engineering, CICECO—Aveiro Institute of Materials, University of Aveiro, 3810-193 Aveiro (Portugal); Department of Corrosion and Surface Technology, Institute of Materials Research Helmholtz-Zentrum Geesthacht, Max-Planck Str. 1, 21502 Geesthacht (Germany)

2016-12-15

Highlights: • Stripping/cooling atmosphere affects surfaces chemical composition of Zn and Zn-Al-Mg galvanized coatings. • Higher peel forces of model adhesive films were obtained on zinc alloys samples prepared under nitrogen atmosphere. • Localized corrosion attack originates at grain boundaries on Zn galvanized coating. • Visible dissolution of MgZn{sub 2} phase was observed by in situ AFM only at binary eutectics and not at ternary ones. - Abstract: In this work the influence of stripping/cooling atmospheres used after withdrawal of steel sheet from Zn or Zn-alloy melt on surface properties of Zn (Z) and Zn-Al-Mg (ZM) hot-dip galvanizing coatings has been studied. The aim was to understand how the atmosphere (composed by nitrogen (N{sub 2}) or air) affects adhesion strength to model adhesive and corrosive behaviour of the galvanized substrates. It was shown that the surface chemical composition and Volta potential of the galvanizing coatings prepared under the air or nitrogen atmosphere are strongly influenced by the atmosphere. The surface chemistry Z and ZM surfaces prepared under N{sub 2} contained a higher content of metal atoms and a richer hydroxide density than the specimens prepared under air atmosphere as assessed by X-ray photoelectron spectroscopy (XPS). The induced differences on the microstructure of the galvanized coatings played a key role on the local corrosion induced defects as observed by means of in situ Atomic force microscopy (AFM). Peel force tests performed on the substrates coated by model adhesive films indicate a higher adhesive strength to the surfaces prepared under nitrogen atmosphere. The obtained results have been discussed in terms of the microstructure and surface chemical composition of the galvanizing coatings.

Fluxes of oxidised and reduced nitrogen above a mixed coniferous forest exposed to various nitrogen emission sources

Energy Technology Data Exchange (ETDEWEB)

Neirynck, J. [Research Institute for Nature and Forest, Gaverstraat 4, B-9500 Geraardsbergen (Belgium)]. E-mail: johan.neirynck@inbo.be; Kowalski, A.S. [Departamento de Fisica Aplicida, Facultad de Ciencias, Universidad de Granada, Calle Fuentenueva, SP-18071 Granada (Spain); Carrara, A. [Fundacion CEAM, Parque Technologico, Calle Charles H. Darwin 14, SP-46980 Paterna (Valencia) (Spain); Genouw, G. [Research Institute for Nature and Forest, Gaverstraat 4, B-9500 Geraardsbergen (Belgium); Berghmans, P. [Flemish Institute for Technological Research, Boeretang 200, B-2400 Mol (Belgium); Ceulemans, R. [Department of Biology, University of Antwerp, Universiteitsplein 1, B-2610 Wilrijk (Antwerp) (Belgium)

2007-09-15

Concentrations of nitrogen gases (NH{sub 3}, NO{sub 2}, NO, HONO and HNO{sub 3}) and particles (pNH{sub 4} and pNO{sub 3}) were measured over a mixed coniferous forest impacted by high nitrogen loads. Nitrogen dioxide (NO{sub 2}) represented the main nitrogen form, followed by nitric oxide (NO) and ammonia (NH{sub 3}). A combination of gradient method (NH{sub 3} and NO {sub x} ) and resistance modelling techniques (HNO{sub 3}, HONO, pNH{sub 4} and pNO{sub 3}) was used to calculate dry deposition of nitrogen compounds. Net flux of NH{sub 3} amounted to -64 ng N m{sup -2} s{sup -1} over the measuring period. Net fluxes of NO {sub x} were upward (8.5 ng N m{sup -2} s{sup -1}) with highest emission in the morning. Fluxes of other gases or aerosols substantially contributed to dry deposition. Total nitrogen deposition was estimated at -48 kg N ha{sup -1} yr{sup -1} and consisted for almost 80% of NH {sub x} . Comparison of throughfall nitrogen with total deposition suggested substantial uptake of reduced N ({+-}15 kg N ha{sup -1} yr{sup -1}) within the canopy. - Reduced nitrogen was found to be the main contributor to total deposition which was predominantly governed by dry deposition.

SU-F-J-149: Beam and Cryostat Scatter Characteristics of the Elekta MR-Linac

Energy Technology Data Exchange (ETDEWEB)

Duglio, M; Towe, S; Roberts, D [Elekta Limited, Crawley, West Sussex (United Kingdom)

2016-06-15

Purpose: The Elekta MR-Linac combines a digital linear accelerator system with a 1.5T Philips MRI machine. This study aimed to determine key characteristic information regarding the MR-Linac beam and in particular it evaluated the effect of the MR cryostat on the out of field scatter dose. Methods: Tissue phantom ratios, profiles and depth doses were acquired in plastic water with an IC-profiler or with an MR compatible water tank using multiple system configurations (Full (B0= 1.5T), Full (B0=0T) and No cryostat). Additionally, an in-house CAD based Monte Carlo code based on Penelope was used to provide comparative data. Results: With the cryostat in place and B0=0T, the measured TPR for the MR Linac system was 0.702, indicating an energy of around 7MV. Without the cryostat, the measured TPR was 0.669. For the Full (B0=0T) case, out of field dose at a depth of 10 cm in the isocentric plane, 5 cm from the field edge was 0.8%, 3.1% and 5.4% for 3×3 cm{sup 2}, 10×10 cm{sup 2} and 20×20 cm{sup 2} fields respectively.The out of field dose (averaged between 5 cm and 10 cm beyond the field edges) in the “with cryostat” case is 0.78% (absolute difference) higher than without the cryostat for clinically relevant field sizes (i.e. 10×10 cm{sup 2}) and comparable to measured conventional 6MV treatment beams at a depth of 10 cm (within 0.1% between 5 cm and 6 cm from field edge). At dose maximum and at 5 cm from the field edge, the “with cryostat” out of field scatter for a 10×10 cm{sup 2} field is 1.5% higher than “without cryostat', with a modest increase (0.9%) compared to Agility 6MV in the same conditions. Conclusion: The study has presented typical characteristics of the MR-Linac beam and determined that out of field dose is comparable to conventional treatment beams. All authors are employed by Elekta Ltd., who are developing an MR-Linac.

Superconducting magnet and cryostat for a space application

Science.gov (United States)

Pope, W. L.; Smoot, G. F.; Smith, L. H.; Taylor, C. E.

1975-01-01

The paper describes the design concepts, development, and testing of a superconducting coil and cryostat for an orbiting superconducting magnetic spectrometer. Several coils were subject to overall thermal performance and coil charging tests. The coils have low but persistent currents and have proven themselves to be rugged and reliable for mobile balloon flights. Satellite experiments will be conducted on a new, similar design.

Performance of highly rated UO<sub>2sub> fuel in the WR-1 organic-cooled reactor

Energy Technology Data Exchange (ETDEWEB)

Schankula, M. H.; Hastings, I. J.

1977-07-15

Information on oxide fuel behaviour in organic coolant was required as part of the organic-cooled power reactor (OCR) study. Of major interest were data on the release of fission gases from fuel operating at high fuel surface temperatures and low external restraint; features which are peculiar to the OCR. To provide these and other data, UO<sub>2sub> fuel with cold-worked Zr-2.5wt%Nb sheathing was irradiated in the WR-1 organic-cooled reactor to burnups of 135-154 MWh/kgU at a time-averaged linear power of 60-63 kW/m. Elements with 0.38 and 0.69 mm thick sheathing showed maximum diametral increases averaging 3.7 and 1.7% respectively at pellet mid-planes. Reduced fuel/sheath heat transfer resulting from a difference between internal gas pressure and coolant pressure produced high operating temperatures, and there was evidence of central melting in some elements. Fission gas releases were 30-60%. In the heat affected zone adjacent to brazed appendages, the diametral increases were lower, averaging 0.9 and 0.5% for 0.38 and 0.69 mm thick sheathing respectively. Heat treatment during the brazing process produced a local improvement in sheath creep strength. Highly rated oxide fuel irradiated in organic coolant will require sheathing with improved high temperature creep properties; heat-treated Zr-2.5 wt% Nb may provide this improvement.

Activated carbon-based magnetic TiO{sub 2} photocatalyst codoped with iodine and nitrogen for organic pollution degradation

Energy Technology Data Exchange (ETDEWEB)

Wang, Xuejiang, E-mail: wangxj@tongji.edu.cn; Song, Jingke; Huang, Jiayu; Zhang, Jing; Wang, Xin; Ma, RongRong; Wang, Jiayi; Zhao, Jianfu, E-mail: zhaojianfu@tongji.edu.cn

2016-12-30

Highlights: • Iodine-nitrogen codoped magnetic photocatalyst was prepared. • A suitable I/Ti ratio was required for good performance of I{sub x}-N-T/CMAC. • I{sub 0.1}-N-T/CMAC own the best photocatalytic performance and can be separated easily. • Both Cl{sup −} and SO{sub 4}{sup 2−} have negative effect on the photocatalytic degradation of SA. • Suitable concentration of humic acid could enhance the photodegradation of SA. - Abstract: Magnetic photocatalyst − iodine and nitrogen codoped TiO{sub 2} based on chitosan decorated magnetic activated carbon (I-N-T/CMAC) was prepared via simple coprecipitation and sol-gel method. The characteristics of photocatalysts were investigated by X-ray diffraction (XRD), N{sub 2} adsorption–desorption isotherm, field emission scanning electron microscopy (FESEM), energy dispersive spectrometry (EDS), fourier transform infrared (FTIR), X-ray photoelectron spectroscopy (XPS), UV–vis diffuse reflection spectroscopy (UV–vis DRS), photoluminescence (PL) spectroscopy and vibrating sample magnetometer (VSM). It turned out that the prepared material had large surface area, enhanced absorption of visible light, and magnetically separable properties when mole ratio of I/Ti was 0.1. Iodine-nitrogen codoped magnetic photocatalyst was used for the removal of salicylic acid (SA), and the rate of adsorption reaction for SA by I{sub 0.1}-N-T/CMAC followed the pseudo second-order kinetic. Under visible light irradiation, 89.71% SA with initial concentration = 30 mg/L could be removed by I{sub 0.1}-N-T/CMAC, and photodegradation rate of SA on I{sub 0.1}-N-T/CMAC composites was 0.0084 min{sup −1} which is about 4 times higher than that of magnetic photocatalyst with nitrogen doped only. The effects of SA initial concentration, pH, coexisting anions and humic acid to the degradation of SA with the prepared material were also investigated. Main oxidative species in the photodegradation process are ·OH and h{sup +}.

New hardware and software platform for experiments on a HUBER-5042 X-ray diffractometer with a DISPLEX DE-202 helium cryostat in the temperature range of 20-300 K

Science.gov (United States)

Dudka, A. P.; Antipin, A. M.; Verin, I. A.

2017-09-01

Huber-5042 diffractometer with a closed-cycle Displex DE-202 helium cryostat is a unique scientific instrument for carrying out X-ray diffraction experiments when studying the single crystal structure in the temperature range of 20-300 K. To make the service life longer and develop new experimental techniques, the diffractometer control is transferred to a new hardware and software platform. To this end, a modern computer; a new detector reader unit; and new control interfaces for stepper motors, temperature controller, and cryostat vacuum pumping system are used. The system for cooling the X-ray tube, the high-voltage generator, and the helium compressor and pump for maintaining the desired vacuum in the cryostat are replaced. The system for controlling the primary beam shutter is upgraded. A biological shielding is installed. The new program tools, which use the Linux Ubuntu operating system and SPEC constructor, include a set of drivers for control units through the aforementioned interfaces. A program for searching reflections from a sample using fast continuous scanning and a priori information about crystal is written. Thus, the software package for carrying out the complete cycle of precise diffraction experiment (from determining the crystal unit cell to calculating the integral reflection intensities) is upgraded. High quality of the experimental data obtained on this equipment is confirmed in a number of studies in the temperature range from 20 to 300 K.

Properties of tin oxide base gas sensors for nitrogen oxides (NO{sub x}). Modelling the NO{sub x}-SnO{sub 2} interactions; Proprietes des capteurs de gaz a base d'oxyde d'etain vis a vis des oxydes d'azote (NO{sub x}). Modelisation des interactions NO{sub x}-SnO{sub 2}

Energy Technology Data Exchange (ETDEWEB)

Leblanc, E.

1999-12-22

In order to better resolve the selectivity problems of the tin oxide base sensors for nitrogen oxides (NO{sub x}), three points have been considered: 1)a thoroughly study of the knowledge of the nitrogen oxides properties: experimental and theoretical studies of the gases present in the studied conditions (thermodynamic aspect) and of their transformation velocities (kinetic aspect) have been carried out 2)an understanding of the NO{sub x}-SnO{sub 2} interactions which lead to the conductance variation of the sensors: studies of the NO{sub x} conversion at the surface of the tin dioxide made with a differential reactor allow to specify the reactional mechanism of the reaction: 2 NO + O{sub 2} = 2 NO{sub 2}. The characterization of the adsorbed species reveals the adsorption of NO{sub 2} in great amount under the nitrate form as well as the key role of these species in the catalytic mechanism. A modelling of the conductance variations of a SnO{sub 2} base sensor under an atmosphere of NO, NO{sub 2} and O{sub 2} is proposed 3)an optimization of the gas sensors properties: after having revealed the strong influence on the sensor sensitivity of the electrodes-SnO{sub 2}, a study on the geometry effects of the electrodes is carried out. No major improvement of the sensitivity has been noticed. The addition of MoO{sub 3} to SnO{sub 2} has been considered. This addition has allowed to strongly improve the sensitivity to the carbon monoxide and to the nitrogen oxide at 450 degrees Celsius. Nevertheless, it has not resolved the selectivity problems. In this study, the perfection of a total NO{sub x} sensor able to measure the sum of the NO and NO{sub 2} amounts has been considered too. (O.M.)

Effect of nitrogen flow rate on structural, morphological and optical properties of In-rich In{sub x}Al{sub 1−x}N thin films grown by plasma-assisted dual source reactive evaporation

Energy Technology Data Exchange (ETDEWEB)

Alizadeh, M., E-mail: alizadeh_kozerash@yahoo.com [Low Dimensional Materials Research Centre (LDMRC), Department of Physics, Faculty of Science, University of Malaya, 50603 Kuala Lumpur (Malaysia); Ganesh, V.; Goh, B.T. [Low Dimensional Materials Research Centre (LDMRC), Department of Physics, Faculty of Science, University of Malaya, 50603 Kuala Lumpur (Malaysia); Dee, C.F.; Mohmad, A.R. [Institute of Microengineering and Nanoelectronics (IMEN), Universiti Kebangsaan Malaysia, Bangi, Selangor (Malaysia); Rahman, S.A., E-mail: saadah@um.edu.my [Low Dimensional Materials Research Centre (LDMRC), Department of Physics, Faculty of Science, University of Malaya, 50603 Kuala Lumpur (Malaysia)

2016-08-15

Highlights: • In-rich In{sub x}Al{sub 1−x}N films were grown by Plasma-aided reactive evaporation. • Effect of nitrogen flow rate on the films properties was investigated. • The band gap of the films was varied from 1.17 to 0.90 eV. • By increasing N{sub 2} flow rate the In{sub x}Al{sub 1−x}N films tend to turn into amorphous state. • At higher N{sub 2} flow rate agglomeration of the particles is highly enhanced. - Abstract: In-rich In{sub x}Al{sub 1−x}N thin films were deposited on quartz substrate at various nitrogen flow rates by plasma-assisted dual source reactive evaporation technique. The elemental composition, surface morphology, structural and optical properties of the films were investigated by X-ray photoelectron spectroscopy (XPS), field emission scanning electron microscopy (FESEM), Raman spectroscopy, X-ray diffraction (XRD), UV–vis spectrophotometer and photoluminescence (PL) measurements. XPS results revealed that the indium composition (x) of the In{sub x}Al{sub 1−x}N films increases from 0.90 to 0.97 as the nitrogen flow rate is increased from 40 to 100 sccm, respectively. FESEM images of the surface and cross-sectional microstructure of the In{sub x}Al{sub 1−x}N films showed that by increasing the N{sub 2} flow rate, the grown particles are highly agglomerated. Raman and XRD results indicated that by increasing nitrogen flow rate the In-rich In{sub x}Al{sub 1−x}N films tend to turn into amorphous state. It was found that band gap energy of the films are in the range of 0.90–1.17 eV which is desirable for the application of full spectra solar cells.

Enhanced nitrogen selectivity for nitrate reduction on Cu–nZVI by TiO{sub 2} photocatalysts under UV irradiation

Energy Technology Data Exchange (ETDEWEB)

Krasae, Nalinee, E-mail: k_nalinee@kkumail.com [Department of Chemical Engineering, Faculty of Engineering, Khon Kaen University, Khon Kaen 40002 (Thailand); Chemical Kinetics and Applied Catalysis Laboratory (CKCL), Faculty of Engineering, Khon Kaen University, Khon Kaen 40002 (Thailand); Wantala, Kitirote, E-mail: kitirote@kku.ac.th [Department of Chemical Engineering, Faculty of Engineering, Khon Kaen University, Khon Kaen 40002 (Thailand); Chemical Kinetics and Applied Catalysis Laboratory (CKCL), Faculty of Engineering, Khon Kaen University, Khon Kaen 40002 (Thailand); Research Center for Environmental and Hazardous Substance Management (EHSM), Faculty of Engineering, Khon Kaen University, Khon Kaen 40002 (Thailand)

2016-09-01

Highlights: • Photocatalytic process has been enhancing the nitrate removal over Cu–nZVI/TiO{sub 2}. • Highly nitrogen selectivity more than 80% over Cu–nZVI/TiO{sub 2}. • Nitrate removal can be reacted in neutral pH of solutions. - Abstract: The aims of this work were to study the effect of Cu–nZVI with and without TiO{sub 2} on nitrate reduction and to study the pathway of nitrate reduction utilizing to nitrogen gas. The chemical and physical properties of Cu–nZVI and Cu–nZVI/TiO{sub 2} such as specific surface area, crystalline phase, oxidation state of Cu and Fe and morphology were determined by N{sub 2} adsorption–desorption Brunauer–Emmett–Teller (BET) analytical technique, X-ray diffraction (XRD), X-ray Absorption Near Edge Structure (XANES) technique and Transmittance Electron Microscopy (TEM). The full factorial design (FFD) was used in this experiment for the effect of Cu–nZVI with and without TiO{sub 2}, where the initial solution pH was varied at 4, 5.5, and 7 and initial nitrate concentration was varied at 50, 75, and 100 ppm. Finally, the pathway of nitrate reduction was examined to calculate the nitrogen gas selectivity. The specific area of Cu–nZVI and Cu–nZVI/TiO{sub 2} was found to be about 4 and 36 m{sup 2}/g, respectively. The XRD pattern of Fe{sup 0} in Cu–nZVI was found at 45° (2θ), whereas Cu–nZVI/TiO{sub 2} cannot be observed. TEM images can confirm the position of the core and the shell of nZVI for Fe{sup 0} and ferric oxide. Cu–nZVI/TiO{sub 2} proved to have higher activity in nitrogen reduction performance than that without TiO{sub 2} and nitrate can be completely degraded in both of solution pH of 4 and 7 in 75 ppm of initial nitrate concentration. It can be highlighted that the nitrogen gas selectivity of Cu–nZVI/TiO{sub 2} greater than 82% was found at an initial solution pH of 4 and 7. The main effects of Cu–nZVI with and without TiO{sub 2} and the initial nitrate concentration on nitrate

Nitrogen bonding in aluminum oxynitride films

Energy Technology Data Exchange (ETDEWEB)

Wang, Paul W., E-mail: pwang@bradley.edu [Department of Physics, Bradley University, 1501 W. Bradley Ave., Peoria, IL 61625 (United States); Hsu, Jin-Cherng [Department of Physics, Fu Jen Catholic University, Hsinchuang, Taipei Hsien 24205, Taiwan (China); Lin, Yung-Hsin; Chen, Huang-Lu [Graduate Institute of Applied Science and Engineering, Fu Jen Catholic University, Hsinchuang, Taipei Hsien 24205, Taiwan (China)

2010-04-15

Assignment of oxidation states of N{sub 1s} in XPS spectra of aluminum oxynitride by curve fitting is difficult. The XPS curve fitting was previously discussed in the paper published in J. Non-Cryst. Solids, 224 (1998) 31, in which O{sub 1s} photoelectrons from GeO{sub 2} glass were used to illustrate how to fit the XPS spectra. Three different ways were pointed out to eliminate the ambiguity caused by curve fitting such as comparing the data to data from standard samples, investigating the continuous surface modifications caused by slowly sputtering the surface, and monitoring the continuous surface modifications due to gradual increases in surface species under heating, cooling, or irradiation. Our recent work in aluminum oxynitride films provides another example of how to fit the XPS spectra of N{sub 1s} by three different oxidation states of N{sup +}, N{sup 2+}, and N{sup 3+}, by comparison of the measured data to data from previously published results, and by the gradual changes of spectra as functions of the oxygen contents in the films. Three oxidation states in different nitrogen bonding in the aluminum oxynitride, AlO{sub 2}N, Al{sub 2}O{sub 5}N{sub 2}, and AlO{sub 3}N, were clearly deduced.

Assessment of the Use of Nitrogen Trifluoride for Purifying Coolant and Heat Transfer Salts in the Fluoride Salt-Cooled High-Temperature Reactor

Energy Technology Data Exchange (ETDEWEB)

Scheele, Randall D.; Casella, Andrew M.

2010-09-28

This report provides an assessment of the use of nitrogen trifluoride for removing oxide and water-caused contaminants in the fluoride salts that will be used as coolants in a molten salt cooled reactor.

Efficient sub-Doppler transverse laser cooling of an indium atomic beam

International Nuclear Information System (INIS)

Kim, Jae-Ihn

2009-01-01

Laser cooled atomic gases and atomic beams are widely studied samples in experimental research in atomic and optical physics. For the application of ultra cold gases as model systems for e.g. quantum many particle systems, the atomic species is not very important. Thus this field is dominated by alkaline, earthalkaline elements which are easily accessible with conventional laser sources and have convenient closed cooling transition. On the other hand, laser cooled atoms may also be interesting for technological applications, for instance for the creation of novel materials by atomic nanofabrication (ANF). There it will be important to use technologically relevant materials. As an example, using group III atoms of the periodical table in ANF may open a route to generate fully 3D structured composite materials. The minimal requirement in such an ANF experiment is the collimation of an atomic beam which is accessible by one dimensional laser cooling. In this dissertation, I describe transverse laser cooling of an Indium atomic beam. For efficient laser cooling on a cycling transition, I have built a tunable, continuous-wave coherent ultraviolet source at 326 nm based on frequency tripling. For this purpose, two independent high power Yb-doped fiber amplifiers for the generation of the fundamental radiation at λ ω = 977 nm have been constructed. I have observed sub-Doppler transverse laser cooling of an Indium atomic beam on a cycling transition of In by introducing a polarization gradient in the linear-perpendicular-linear configuration. The transverse velocity spread of a laser-cooled In atomic beam at full width at half maximum was achieved to be 13.5±3.8 cm/s yielding a full divergence of only 0.48 ± 0.13 mrad. In addition, nonlinear spectroscopy of a 3-level, Λ-type level system driven by a pump and a probe beam has been investigated in order to understand the absorption line shapes used as a frequency reference in a previous two-color spectroscopy experiment

Effective visible light-active nitrogen and samarium co-doped BiVO{sub 4} for the degradation of organic pollutants

Energy Technology Data Exchange (ETDEWEB)

Wang, Min; Niu, Chao [College of Environmental and Chemical Engineering, Shenyang Ligong University, Shenyang 110165 (China); Liu, Jun, E-mail: minwang62@msn.com [Shenyang Military General Hospital, Shenyang 110016 (China); Wang, Qianwu; Yang, Changxiu; Zheng, Haoyan [College of Environmental and Chemical Engineering, Shenyang Ligong University, Shenyang 110165 (China)

2015-11-05

Nitrogen and samarium co-doped BiVO{sub 4} (N–xSm–BiVO{sub 4}) nanoparticles were synthesized using a sol–gel method with a corn stem template. The physicochemical properties of the resultant N–xSm–BiVO{sub 4} particles were characterized using various methods: XPS, XRD, SEM, BET, and UV–Vis DRS analyses. The visible-light photocatalytic activity was successfully demonstrated by degrading a model dye, namely, methyl orange. The dopant content was optimized, and the nitrogen and samarium co-doped BiVO{sub 4} extended the light absorption spectrum toward the visible region, significantly enhancing the photodegradation of the model dye. The Sm and N co-doped BiVO{sub 4} exhibited the highest photocatalytic activity compared to materials with a single dopant or no dopant. The significantly enhanced photocatalytic activity of the N–Sm co-doped BiVO{sub 4} under visible-light irradiation can be attributed to the synergistic effects of the nitrogen and samarium. - Highlights: • The N–Sm codoped BiVO{sub 4} were synthesized using a sol–gel method with a corn stem template. • The N and Sm codoped BiVO{sub 4} has excellent photocatalytic activity of methyl orange degradation. • The maximum activity was observed when the molar ratio of Sm/Bi was 1.0. • The high photocatalytic activity was caused by the synergistic effects between N doping and Sm doping.

Quaternary selenostannates Na{sub 2-x}Ga{sub 2-x}Sn{sub 1+x}Se{sub 6} and AGaSnSe{sub 4} (A=K, Rb, and Cs) through rapid cooling of melts. Kinetics versus thermodynamics in the polymorphism of AGaSnSe{sub 4}

Energy Technology Data Exchange (ETDEWEB)

Hwang, S -J; Iyer, R G; Kanatzidis, M G

2004-10-01

The quaternary alkali-metal gallium selenostannates, Na{sub 2-x}Ga{sub 2-x}Sn{sub 1+x}Se{sub 6} and AGaSnSe{sub 4} (A=K, Rb, and Cs), were synthesized by reacting alkali-metal selenide, Ga, Sn, and Se with a flame melting-rapid cooling method. Na{sub 2-x}Ga{sub 2-x}Sn{sub 1+x}Se{sub 6} crystallizes in the non-centrosymmetric space group C2 with cell constants a=13.308(3) A, b=7.594(2) A, c=13.842(3) A, {beta}=118.730(4) deg., V=1226.7(5) A{sup 3}. {alpha}-KGaSnSe{sub 4} crystallizes in the tetragonal space group I4/mcm with a=8.186(5) A and c=6.403(5) A, V=429.1(5) A{sup 3}. {beta}-KGaSnSe{sub 4} crystallizes in the space group P2{sub 1}/c with cell constants a=7.490(2) A, b=12.578(3) A, c=18.306(5) A, {beta}=98.653(5) deg., V=1705.0(8) A{sup 3}. The unit cell of isostructural RbGaSnSe{sub 4} is a=7.567(2) A, b=12.656(3) A, c=18.277(4) A, {beta}=95.924(4) deg., V=1741.1(7) A{sup 3}. CsGaSnSe{sub 4} crystallizes in the orthorhombic space group Pmcn with a=7.679(2) A, b=12.655(3) A, c=18.278(5) A, V=1776.1(8) A{sup 3}. The structure of Na{sub 2-x}Ga{sub 2-x}Sn{sub 1+x}Se{sub 6} consists of a polar three-dimensional network of trimeric (Sn,Ga){sub 3}Se{sub 9} units with Na atoms located in tunnels. The AGaSnSe{sub 4} possess layered structures. The compounds show nearly the same Raman spectral features, except for Na{sub 2-x}Ga{sub 2-x}Sn{sub 1+x}Se{sub 6}. Optical band gaps, determined from UV-Vis spectroscopy, range from 1.50 eV in Na{sub 2-x}Ga{sub 2-x}Sn{sub 1+x}Se{sub 6} to 1.97 eV in CsGaSnSe{sub 4}. Cooling of the melts of KGaSnSe{sub 4} and RbGaSnSe{sub 4} produces only kinetically stable products. The thermodynamically stable product is accessible under extended annealing, which leads to the so-called {gamma}-form (BaGa{sub 2}S{sub 4}-type) of these compounds.

Changes in susceptibility of beech (Fagus sylvatica) seedlings towards Phytophthora citricola under the influence of elevated atmospheric CO{sub 2} and nitrogen fertilization

Energy Technology Data Exchange (ETDEWEB)

Fleischmann, F., E-mail: fleischmann@wzw.tum.d [Phytopathology of Woody Plants, Technische Universitaet Muenchen, Am Hochanger 13, 85354 Freising (Germany); Raidl, S. [Department Biology I and GeoBioCenterLMU, Systematic Mycology, Ludwig Maximilians Universitaet Muenchen, Menzinger Strasse 67, 80638 Muenchen (Germany); Osswald, W.F. [Phytopathology of Woody Plants, Technische Universitaet Muenchen, Am Hochanger 13, 85354 Freising (Germany)

2010-04-15

The growth-differentiation balance hypothesis (GDBH) predicts changes in susceptibility of plants against herbivores with changing resource availability. In the presented study we tested the validity of the GDBH for trees infected with a root pathogen. For this purpose Fagus sylvatica seedlings grown under different atmospheric CO{sub 2}- and soil nitrogen regimes were infected with the root pathogen Phytophthora citricola. High nitrogen supply increased total biomass of beech regardless of the CO{sub 2}-treatment, whereas elevated CO{sub 2} enhanced biomass only in the high nitrogen treatment. The responses of beech under the different growing regimes to the Phytophthora root infection were not in line with the predictions of the GDBH. Enhanced susceptibility of beech against P. citricola was found in seedlings grown under elevated CO{sub 2} and low nitrogen supply. Fifteen months after inoculation these plants were characterized by enhanced water use efficiency, by altered root-shoot ratios, and by enhanced specific root tip densities. - Susceptibility of Fagus sylvatica to the root pathogen Phytophthora citricola increased under elevated CO{sub 2}

Microstructure and properties of nitrogen ion implantation/AlN/CrAlN/MoS{sub 2}-phenolic resin duplex coatings on magnesium alloys

Energy Technology Data Exchange (ETDEWEB)

Xie, Zhiwen [University of Science and Technology Liaoning, Anshan 114051 (China); Chongqing Institute of Green and Intelligent Technology, Chinese Academy of Sciences, Chongqing 400714 (China); Chen, Qiang, E-mail: 2009chenqiang@163.com [Southwest Technique and Engineering Research Institute, Chongqing 400039 (China); Chen, Tian [Chongqing Institute of Green and Intelligent Technology, Chinese Academy of Sciences, Chongqing 400714 (China); Gao, Xu; Yu, Xiaoguang; Song, Hua; Feng, Yongjun [University of Science and Technology Liaoning, Anshan 114051 (China)

2015-06-15

The novel nitrogen ion implantation/AlN/CrAlN/MoS{sub 2}-phenolic resin duplex coatings are fabricated on the AM60 magnesium alloys. The microstructure, tribological and electrochemical properties of the duplex coatings are characterized by X-ray diffraction, X-ray photoelectron spectroscopy, scanning electron microscopy, Fourier transform infrared spectroscopy, Raman spectroscopy, nano-indenter, electrochemical corrosion and wear tester. These studies reveal that the MoS{sub 2}-phenolic resin coating has a two-phase microstructure crystalline MoS{sub 2} particles embedded in the amorphous phenolic resin matrix. The single-layer MoS{sub 2}-phenolic resin enhances the corrosion resistance of magnesium alloys, but shows poor wear resistance due to the low substrate's load bearing capacity. The addition of nitrogen ion implantation/AlN/CrAlN interlayer in the MoS{sub 2}-phenolic resin/substrate system greatly enhances the substrate's load bearing capacity. The AlN/CrAlN/MoS{sub 2}-phenolic resin duplex coating with a high load bearing capacity demonstrates super wear resistance (i.e., long wear life and low friction coefficient). In addition, the nitrogen ion implantation/AlN interlayer greatly depresses the effect of galvanic corrosion because its potential is close to that of the magnesium alloys, but the nitrogen ion implantation/AlN/CrAlN interlayer is inefficient in reducing the galvanic corrosion due to the large potential difference between the CrN phase and the substrate. As a result, the nitrogen ion implantation/AlN/MoS{sub 2}-phenolic resin duplex coating shows a better corrosion resistance compared to the nitrogen ion implantation/AlN/CrAlN/MoS{sub 2}-phenolic resin. - Highlights: • Ion implantation/AlN/CrAlN/MoS{sub 2}-phenolic resin duplex coatings were presented. • Ion implantation/AlN/CrAlN interlayer greatly enhanced the load bearing capacity. • Ion implantation/AlN interlayer greatly depressed the effect of galvanic corrosion. • The

Experience with two large-scale Hell-cryostats for a superconducting RF particle separator working in closed cycle with a 300 W refrigerator

CERN Document Server

Barth, W

1976-01-01

The contribution of the Karlsruhe Institut fur Experimental Kernphysik to the RF particle separator at the SPS/CERN consists of the two superconducting deflectors and their Hell-cryostats with the cryogenic and vacuum accessories. The cryostats have to fulfil specifications concerning tightness, thermal insulation, adjustment of the cavities to the beam and reliability. Corresponding cryogenic and RF tests are performed in Karlsruhe before a 300 W refrigerator simulating normal and emergency conditions. Following a description of cryostats design the results of these measurements are compared with the specifications. Operating experience with the cryostats in closed circuit with the refrigerator are reported. (5 refs).

Development of membrane cryostats for large liquid argon neutrino detectors

CERN Document Server

Montanari, D; Gendotti, A; Geynisman, M; Hentschel, S; Loew, T; Mladenov, D; Montanari, C; Murphy, S; Nessi, M; Norris, B; Noto, F; Rubbia, A; Sharma, R; Smargianaki, D; Stewart, J; Vignoli, C; Wilson, P; Wu, S

2015-01-01

A new collaboration is being formed to develop a multi-kiloton Long-Baseline neutrino experiment that will be located at the Surf Underground Research Facility (SURF) in Lead, SD. In the present design, the detector will be located inside cryostats filled with 68,400 ton of ultrapure liquid argon (less than 100 parts per trillion of oxygen equivalent contamination). To qualify the membrane technology for future very large-scale and underground implementations, a strong prototyping effort is ongoing: several smaller detectors of growing size with associated cryostats and cryogenic systems will be designed and built at Fermilab and CERN. They will take physics data and test different detector elements, filtration systems, design options and installation procedures. In addition, a 35 ton prototype is already operational at Fermilab and will take data with single-phase detector in early 2016. After the prototyping phase, the multi-kton detector will be constructed. After commissioning, it will detect and study ne...

Convenient and large-scale synthesis of nitrogen-rich hierarchical porous carbon spheres for supercapacitors and CO{sub 2} capture

Energy Technology Data Exchange (ETDEWEB)

Chang, Binbin, E-mail: binbinchang@infm.hhstu.edu.cn [Institute of Nanostructured Functional Materials, Huanghe Science and Technology College, Zhengzhou, Henan 450006 (China); Henan Provincial Key Laboratory of Nano-composite and Application, Zhengzhou, Henan 450006 (China); Zhang, Shouren; Yin, Hang [Institute of Nanostructured Functional Materials, Huanghe Science and Technology College, Zhengzhou, Henan 450006 (China); Henan Provincial Key Laboratory of Nano-composite and Application, Zhengzhou, Henan 450006 (China); Yang, Baocheng, E-mail: baochengyang@yahoo.com [Institute of Nanostructured Functional Materials, Huanghe Science and Technology College, Zhengzhou, Henan 450006 (China); Henan Provincial Key Laboratory of Nano-composite and Application, Zhengzhou, Henan 450006 (China)

2017-08-01

Highlights: • Convenient and large-scale synthesis route for N-doped hierarchical porous carbon sphere. • The resultant own spherical morphology, tunable hierarchical porosity, high surface area. • The optimal material exhibits a high CO{sub 2} capture capacity of 4.23 mmol g{sup −1}. • It shows a large voltage window of 1.8 V for symmetric cell in 0.5 M Na{sub 2}SO{sub 4}. - Abstract: Herein, considering the great potential of nitrogen-doped hierarchical porous carbons in energy storage and CO{sub 2} capture, we designed a convenient and easily large-scale production strategy for preparing nitrogen-doped hierarchical porous carbon sphere (NHPCS) materials. In this synthesis route, spherical resorcinol-formaldehyde (RF) resins were selected as carbon precursor, and then the ZnCl{sub 2}-impregnated RF resin spheres were carbonized in a NH{sub 3} atmosphere at a temperature range of 600–800 °C. During the one-step heat-treatment process, nitrogen atom could be efficiently incorporated into the carbon skeleton, and the interconnected and hierarchical pore structure with different micro/mesopore proportion could be generated and tuned by adjusting the activating agent ZnCl{sub 2} dosage and carbonization temperature. The resultant nitrogen-doped hierarchical porous carbon sphere materials exhibited a satisfactory charge storage capacity, and the optimal sample of NHPCS-2-8 with a high mesopore proportion obtained at 800 °C with a ZnCl{sub 2}/RF mass ratio of 2:1 presented a specific capacitance of 273.8 F g{sup −1} at a current density of 0.5 A g{sup −1}. More importantly, the assembled NHPCS-2-8-based symmetric capacitor displayed a high energy density of 17.2 Wh kg{sup −1} at a power density of 178.9 W kg{sup −1} within a voltage window of 0 ∼ 1.8 V in 0.5 M Na{sub 2}SO{sub 4} aqueous electrolyte. In addition, the CO{sub 2} capture application of these NHPCS materials was also explored, and the optimal sample of NHPCS-0-8 with a large

Experimental investigations on cryogenic cooling by liquid nitrogen in the end milling of hardened steel

Science.gov (United States)

Ravi, S.; Pradeep Kumar, M.

2011-09-01

Milling of hardened steel generates excessive heat during the chip formation process, which increases the temperature of cutting tool and accelerates tool wear. Application of conventional cutting fluid in milling process may not effectively control the heat generation also it has inherent health and environmental problems. To minimize health hazard and environmental problems caused by using conventional cutting fluid, a cryogenic cooling set up is developed to cool tool-chip interface using liquid nitrogen (LN 2). This paper presents results on the effect of LN 2 as a coolant on machinability of hardened AISI H13 tool steel for varying cutting speed in the range of 75-125 m/min during end milling with PVD TiAlN coated carbide inserts at a constant feed rate. The results show that machining with LN 2 lowers cutting temperature, tool flank wear, surface roughness and cutting forces as compared with dry and wet machining. With LN 2 cooling, it has been found that the cutting temperature was reduced by 57-60% and 37-42%; the tool flank wear was reduced by 29-34% and 10-12%; the surface roughness was decreased by 33-40% and 25-29% compared to dry and wet machining. The cutting forces also decreased moderately compared to dry and wet machining. This can be attributed to the fact that LN 2 machining provides better cooling and lubrication through substantial reduction in the cutting zone temperature.

Combined He3 cryostats and He3-He4 dilution refrigerators

International Nuclear Information System (INIS)

Kovac, L.; Balla, J.

1974-07-01

A modular set of equipment was designed, which consists of a 4 He Dewar vessel with a very low evaporation rate, having a pumped 4 He bath in which either a 3 He cryostat or a dilution refrigerator within removable inserts can be placed. Any of them can be simply and rapidly connected to the versatile Dewar, auxiliary 4 He-, vacuum; and 3 He- 4 He systems. Two such sets have already been completed and can be used at temperatures from 1.5K to 0.05K for thermodynamic and neutron diffraction measurements. The performance of all inserts was stable and reliable, differences between the cryostats and runs were small - nearly all within the accuracy of temperature determination. The construction of a lot of parts is identical, allowing rapid manufacture. Assembling and repairs are simple, all parts are easily accessible. (K.A.)

Manufacturing and assembly of the plasma- and outer vessel of the cryostat for Wendelstein 7-X

Energy Technology Data Exchange (ETDEWEB)

Hein, Bernd, E-mail: Bernd.Hein@ipp.mpg.de [Max-Planck Institut fuer Plasmaphysik, EURATOM Association, Teilinstitut Greifswald, Wendelsteinstrasse 1, D-17491 Greifswald (Germany); Cardella, Antonio; Hermann, Dieter; Hansen, Andreas [Max-Planck Institut fuer Plasmaphysik, EURATOM Association, Teilinstitut Greifswald, Wendelsteinstrasse 1, D-17491 Greifswald (Germany); Leher, Franz; Binni, Andreas; Segl, Juergen [MAN Diesel and Turbo SE Deggendorf, Werftstrasse 17, D-94469 Deggendorf (Germany)

2012-02-15

Wendelstein 7-X is an advanced helical stellarator, which is presently under construction at the Greifswald branch of IPP. A set of 70 superconducting coils arranged in five modules provides a twisted shaped magnetic cage for the plasma and allows steady state operation. Operation of the magnet system at cryogenic temperatures requires a cryostat which provides thermal protection and gives access to the plasma. The main components of the cryostat are the plasma vessel, the outer vessel, the ports, and the thermal insulation. The German company, MAN Diesel and Turbo SE Deggendorf (former MAN DWE GmbH Deggendorf), is responsible for the manufacture and assembly of the plasma vessel, the outer vessel and the thermal insulation. This paper describes the manufacturing and assembly technology of the plasma and outer vessel of the cryostat for Wendelstein 7-X.

Manufacturing and assembly of the plasma- and outer vessel of the cryostat for Wendelstein 7-X

International Nuclear Information System (INIS)

Hein, Bernd; Cardella, Antonio; Hermann, Dieter; Hansen, Andreas; Leher, Franz; Binni, Andreas; Segl, Jürgen

2012-01-01

Wendelstein 7-X is an advanced helical stellarator, which is presently under construction at the Greifswald branch of IPP. A set of 70 superconducting coils arranged in five modules provides a twisted shaped magnetic cage for the plasma and allows steady state operation. Operation of the magnet system at cryogenic temperatures requires a cryostat which provides thermal protection and gives access to the plasma. The main components of the cryostat are the plasma vessel, the outer vessel, the ports, and the thermal insulation. The German company, MAN Diesel and Turbo SE Deggendorf (former MAN DWE GmbH Deggendorf), is responsible for the manufacture and assembly of the plasma vessel, the outer vessel and the thermal insulation. This paper describes the manufacturing and assembly technology of the plasma and outer vessel of the cryostat for Wendelstein 7-X.

The photosynthetic and stomatal response of Medicago sativa cv. saranac to free-air CO{sub 2} enrichment (F.A.C.E.) and nitrogen

Energy Technology Data Exchange (ETDEWEB)

Bridson, N.P.

1996-08-01

Plots of Medicago sativa cv. saranac were grown in the field at ambient (355 {mu}mol CO{sub 2} mol{sup -1} air) or elevated (600{mu}mol CO{sub 2} mol{sup -1} air) CO{sub 2} concentrations. High (200kg yr{sup -1}) or low (20kg yr{sup -1}) nitrogen levels were applied to two isogeneic lines, one able and one unable to use nitrogen fixing bacteria. Plants were in the second year of field growth. Exposure to elevated CO{sub 2} was via a Free-Air CO{sub 2} Enrichment System (FACE). Elevated CO{sub 2} increased diurnal assimilation by between 12% and 92%. Analysis of A/C{sub i} responses showed that effective nitrogen fertilisation was more important to rubisCO and RuBP activity than elevated CO{sub 2}. No acclimation was consistently observed. Leaves lower down the canopy were found to have lower Vc{sub max} and J{sub max} values, though age may be the cause of the latter effect. FACE conditions have only a small effect on these responses. There was some evidence found for the down-regulation of photosynthesis in the late afternoon. The FACE conditions had no affect on stomatal density but did increase epidermal cell density.

Mutual passivation of group IV donors and isovalent nitrogen in diluted GaN{sub x}As{sub 1-x} alloys

Energy Technology Data Exchange (ETDEWEB)

Yu, K.M.; Wu, J.; Walukiewicz, W.; Shan, W.; Beeman, J.; Mars, D.E.; Chamberlin, D.R.; Scarpulla, M.A.; Dubon, O.D.; Ridgway, M.C.; Geisz, J.F.

2003-07-23

We demonstrate the mutual passivation of electrically active group IV donors and isovalent N atoms in the GaN{sub x}As{sub 1-x} alloy system. This phenomenon occurs through the formation of a donor-nitrogen bond in the nearest neighbor IV{sub Ga}-N{sub As} pairs. In Si doped GaInN{sub 0.017}As{sub 0.983} the electron concentration starts to decrease rapidly at an annealing temperature of 700 C from {approx} 3 x 10{sup 19}cm{sup -3} in the as-grown state to less than 10{sup 16}cm{sup -3} after an annealing at 900 C for 10 s. At the same time annealing of this sample at 950 C increases the gap by about 35 meV, corresponding to a reduction of the concentration of the active N atoms by an amount very close to the total Si concentration. We also show that the formation of Si{sub Ga}-N{sub As} pairs is controlled by the diffusion of Si via Ga vacancies to the nearest N{sub As} site. The general nature of this mutual passivation effect is confirmed by our study of Ge doped GaN{sub x}As{sub 1-x} layers formed by N and Ge co-implantation in GaAs followed by pulsed laser melting.

Photocatalytic activity and RNO dye degradation of nitrogen-doped TiO{sub 2} prepared by ionothermal synthesis

Energy Technology Data Exchange (ETDEWEB)

Pipi, Angelo; Ruotolo, Luis, E-mail: pluis@ufscar.br [Universidade Federal de Sao Carlos (UFSCar), SP (Brazil). Departamento de Engenharia Quimica; Byzynski, Gabriela [Universidade Estadual Paulista Julio de Mesquita Filho (UNESP), Araraquara, SP (Brazil)

2017-05-15

This work concerns the preparation a nitrogen-doped TiO{sub 2} by ionothermal synthesis methods and the photocatalytic studies. In this procedure, alkoxide was used as a titanium source, and a deep eutectic mixture of choline chloride and urea (molar ratio 1:2) served as a solvent and source of nitrogen. Different samples were synthesized varying the percentages of the eutectic mixture, titanium butoxide, and water, as well as temperature and reaction time. The catalysts were characterized by X-ray diffraction, Raman spectrometry, scanning electron microscopy, and diffuse reflectance spectroscopy. N-doping was confirmed by X-ray photoelectron spectroscopy. The photocatalytic activity of the N-TiO{sub 2} nanoparticles was evaluated in the oxidation of N,N-dimethyl-4-nitrosoaniline (RNO) dye. The best photocatalytic activity under illumination by UV and visible light was found for the catalysts prepared under reflux in the presence of water, and for the catalysts prepared hydrothermally using intermediate percentages of the nitrogen source (the eutectic mixture). (author)

Temperature and cooling field dependent exchange coupling in [Cr/Gd]{sub 5} multilayers

Energy Technology Data Exchange (ETDEWEB)

Jiao, Z.W.; Chen, H.J.; Jiang, W.D.; Wang, J.F.; Yu, S.J. [Department of Physics, China Jiliang University, Hangzhou (China); Hou, Y.L.; Lu, B.; Ye, Q.L. [Department of Physics, Hangzhou Normal University, Hangzhou (China)

2016-09-15

Exchange coupling has been investigated in the [Cr/Gd]{sub 5} multilayers deposited at 25, 200, and 400 C, where the Neel temperature (T{sub N}) of antiferromagnetic Cr is slightly higher than the Curie temperature (T{sub C}) of ferromagnetic Gd. It was found that the exchange coupling existed not only at T{sub C} < T < T{sub N}, but also above the temperature (T{sub N}) of antiferromagnetic orderings with incommensurate spin-density wave structures transiting to paramagnetic state. These results can be discussed in terms of the crucial role played by the antiferromagnetic spins of Cr with commensurate spin-density wave structures in the vicinity of the Cr/Gd interfaces. Moreover, the exchange coupling of the multilayers grown at different temperatures exhibited different dependencies on the measuring temperature and the cooling field, respectively. Positive exchange bias was observed in the multilayers grown at 200 and 400 C. The interfacial roughness, grain size, and the antiferromagnetic orderings of Cr may be responsible for the anomalous exchange coupling of the multilayers. In addition, the competition between the exchange coupling at Cr/Gd interfaces and the external field-Cr surface magnetic coupling can explain the appearance of negative or positive exchange bias. (copyright 2016 WILEY-VCH Verlag GmbH and Co. KGaA, Weinheim)

Alternatives for metal hydride storage bed heating and cooling

International Nuclear Information System (INIS)

Fisher, I.A.; Ramirez, F.B.; Koonce, J.E.; Ward, D.E.; Heung, L.K.; Weimer, M.; Berkebile, W.; French, S.T.

1991-01-01

The reaction of hydrogen isotopes with the storage bed hydride material is exothermic during absorption and endothermic during desorption. Therefore, storage bed operation requires a cooling system to remove heat during absorption, and a heating system to add the heat needed for desorption. Three storage bed designs and their associated methods of heating and cooling and accountability are presented within. The first design is the current RTF (Replacement Tritium Facility) nitrogen heating and cooling system. The second design uses natural convection cooling with ambient glove box nitrogen and electrical resistance for heating. This design is referred to as the Naturally Cooled/Electrically Heated (NCEH) design. The third design uses forced convection cooling with ambient glove box nitrogen and electrical resistance for heating. The design is referred to as the Forced Convection Cooled/Electrically Heated (FCCEH) design. In this report the operation, storage bed design, and equipment required for heating, cooling, and accountability of each design are described. The advantages and disadvantages of each design are listed and discussed. Based on the information presented within, it is recommended that the NCEH design be selected for further development

Determination of heat transfer coefficient for an interaction of sub-cooled gas and metal

International Nuclear Information System (INIS)

Sidek, Mohd Zaidi; Kamarudin, Muhammad Syahidan

2016-01-01

Heat transfer coefficient (HTC) for a hot metal surface and their surrounding is one of the need be defined parameter in hot forming process. This study has been conducted to determine the HTC for an interaction between sub-cooled gas sprayed on a hot metal surface. Both experiments and finite element have been adopted in this work. Initially, the designated experiment was conducted to obtain temperature history of spray cooling process. Then, an inverse method was adopted to calculate the HTC value before we validate in a finite element simulation model. The result shows that the heat transfer coefficient for interaction of subcooled gas and hot metal surface is 1000 W/m 2 K. (paper)

Analysis of neutronics and dynamic characteristics with reactivity injection in LBE cooled sub-critical reactor

International Nuclear Information System (INIS)

Chen Sen; Wu Yican; Jin Ming; Chen Zhibin; Bai Yunqing; Zhao Zhumin

2014-01-01

Accelerator Driven Sub-critical System (ADS) has particular neutronics behaviors compared with the critical system. Prompt jump approximation point reactor kinetics equations taken external source into account have been deduced using an approach of prompt jump approximation. And the relationship between injection reactivity and power ampliation has been achieved. In addition, based on the RELAP5 code the prolong development of point reactor kinetics code used into assessing sub-critical system have been promoted. Different sub-criticality (k eff = 0.90, 0.95, 0.97, 0.98 and 0.99) have been assessed in preliminary design of a type of natural circulation cooling sub-critical reactor under conditions of reactivity injection +1 β in one second. It shows that the external source prompt transient approximation method has an accurate solution after injecting reactivity around short time and has a capacity to solve the dynamic equation, and the sub-critical system has an inner stability while the deeper sub-criticality the less impact on the sub-critical system. (authors)

Sub-recoil cooling up to nano-Kelvin. Direct measurement of spatial coherency length. New tests for Levy statistics

International Nuclear Information System (INIS)

Saubamea, B.

1998-12-01

This thesis presents a new method to measure the temperature of ultracold atoms from the spatial autocorrelation function of the atomic wave-packets. We thus determine the temperature of metastable helium-4 atoms cooled by velocity selective dark resonance, a method known to cool the atoms below the temperature related to the emission or the absorption of a single photon by an atom at rest, namely the recoil temperature. This cooling mechanism prepares each atom in a coherent superposition of two wave-packets with opposite mean momenta, which are initially superimposed and then drift apart. By measuring the temporal decay of their overlap, we have access to the Fourier transform of the momentum distribution of the atoms. Using this method, we can measure temperatures as low as 5 nK, 800 times as small as the recoil temperature. Moreover we study in detail the exact shape of the momentum distribution and compare the experimental results with two different theoretical approaches: a quantum Monte Carlo simulation and an analytical model based on Levy statistics. We compare the calculated line shape with the one deduced from simulations, and each theoretical model with experimental data. A very good agreement is found with each approach. We thus demonstrate the validity of the statistical model of sub-recoil cooling and give the first experimental evidence of some of its characteristics: the absence of steady-state, the self-similarity and the non Lorentzian shape of the momentum distribution of the cooled atoms. All these aspects are related to the non ergodicity of sub-recoil cooling. (author)

Independent CO{sub 2} loop for cooling the samples irradiated in the RA reactor vertical experimental channels, Task 2.50.05; Nezavisno kolo CO{sub 2} za hladjenje uzoraka ozracivanih u vertikalnim eksperimentalnim kanalima reaktora RA, Zad. 2.50.05

Energy Technology Data Exchange (ETDEWEB)

Stojic, M; Pavicevic, M

1964-07-01

This report contains the following volumes V and VI of the Project 'Independent CO{sub 2} loop for cooling the samples irradiated in RA reactor vertical experimental channels': Design project of the dosimetry control system in the independent CO{sub 2} loop for cooling the samples irradiated in the RA reactor vertical experimental channels, and Safety report for the Independent CO{sub 2} loop for cooling the samples irradiated in the RA reactor vertical experimental channels. Ovaj izvestaj sadrzi dva albuma zadatka 'Nezavisno kolo CO{sub 2} za hladjenje uzoraka ozracivanih u vertikalnim eksperimentalnim kanalima reaktora RA', Zad. 2.50.05: Album V: Predprojekat sistema dozimetrijske kontrole u nezavisnom kolu CO{sub 2} za hladjenje uzoraka ozracivanih u VEK reaktora RA i Album VI: Izvestaj o sigurnosti za nezavisno kolo CO{sub 2} za hladjenje uzoraka ozracivanih u VEK reaktora RA.

Design, Manufacturing and Integration of LHC Cryostat Components an Example of Collaboration between CERN and Industry

CERN Document Server

Slits, Ivo; Canetti, Marco; Colombet, Thierry; Gangini, Fabrizio; Parma, Vittorio; Tock, Jean-Philippe

2006-01-01

The components for the LHC cryostats and interconnections are supplied by European industry. The manufacturing, assembly and testing of these components in accordance with CERN technical specifications require a close collaboration and dedicated approach from the suppliers. This paper presents the different phases of design, manufacturing, testing and integration of four LHC cryostat components supplied by RIAL Vacuum (Parma, Italy), including 112 Insulation Vacuum Barriers (IVB), 482 Cold-mass Extension Tubes (CET), 121 cryostat vacuum vessel Jumper Elbows (JE) and 10800 Interconnection Sleeves (IS). The Quality Assurance Plan, which the four projects have in common, is outlined. The components are all leak-tight thin stainless steel assemblies (<10-8 mbar l/s), most of them operating at cryogenic temperature (2 K), however each having specific requirements. The particularities of each component are presented with respect to manufacturing, assembly and testing. These components are being integrated ...

Calorimetric and magnetic study for Ni{sub 50}Mn{sub 36}In{sub 14} and relative cooling power in paramagnetic inverse magnetocaloric systems

Energy Technology Data Exchange (ETDEWEB)

Chen, Jing-Han, E-mail: jhchen@tamu.edu [Department of Physics and Astronomy, Texas A and M University, College Station, Texas 77843 (United States); Bruno, Nickolaus M. [Department of Mechanical Engineering, Texas A and M University, College Station, Texas 77843 (United States); Karaman, Ibrahim [Department of Mechanical Engineering, Texas A and M University, College Station, Texas 77843 (United States); Department of Materials Science and Engineering, Texas A and M University, College Station, Texas 77843 (United States); Huang, Yujin; Li, Jianguo [School of Materials Science and Engineering, Shanghai Jiaotong University, Shanghai 200240 (China); Ross, Joseph H. [Department of Physics and Astronomy, Texas A and M University, College Station, Texas 77843 (United States); Department of Materials Science and Engineering, Texas A and M University, College Station, Texas 77843 (United States)

2014-11-28

The non-stoichiometric Heusler alloy Ni{sub 50}Mn{sub 36}In{sub 14} undergoes a martensitic phase transformation in the vicinity of 345 K, with the high temperature austenite phase exhibiting paramagnetic rather than ferromagnetic behavior, as shown in similar alloys with lower-temperature transformations. Suitably prepared samples are shown to exhibit a sharp transformation, a relatively small thermal hysteresis, and a large field-induced entropy change. We analyzed the magnetocaloric behavior both through magnetization and direct field-dependent calorimetry measurements. For measurements passing through the first-order transformation, an improved method for heat-pulse relaxation calorimetry was designed. The results provide a firm basis for the analytic evaluation of field-induced entropy changes in related materials. An analysis of the relative cooling power (RCP), based on the integrated field-induced entropy change and magnetizing behavior of the Mn spin system with ferromagnetic correlations, shows that a significant RCP may be obtained in these materials by tuning the magnetic and structural transformation temperatures through minor compositional changes or local order changes.

Synthesis and characterization of Cu{sub 3}TaIn{sub 3}Se{sub 7} and CuTa{sub 2}InTe{sub 4}

Energy Technology Data Exchange (ETDEWEB)

Calderon, E.; Munoz-Pinto, M.; Duran-Pina, S.; Quintero, M.; Quintero, E.; Morocoima, M. [Centro de Estudios de Semiconductores, Departamento de Fisica, Facultad de Ciencias, Universidad de Los Andes, Merida (Venezuela); Delgado, G.E. [Laboratorio de Cristalografia, Departamento de Quimica, Facultad de Ciencias, Universidad de Los Andes, Merida (Venezuela); Romero, H. [Laboratorio de Magnetismo, Departamento de Fisica, Facultad de Ciencias, Universidad de Los Andes, Merida (Venezuela); Briceno, J.M.; Fernandez, J. [Laboratorio de Analisis Quimico y Estructural (LAQUEM), Departamento de Fisica, Facultad de Ciencias, Merida (Venezuela); Grima-Gallardo, P.

2008-07-15

Polycrystalline samples of Cu{sub 3}TaIn{sub 3}Se{sub 7} and CuTa{sub 2}InTe{sub 4} were synthesized by the usual melt and anneal technique. X-ray powder diffraction showed a single phase behavior for both samples with tetragonal symmetry and unit cell parameter values a=5.794{+-}0.002 A, c=11.66{+-}0.01 A, c/a=2.01, V=391{+-}1 A{sup 3} and a=6.193{+-}0.001 A, c=12.400 {+-}0.002A, c/a=2.00, V=475{+-}1 A{sup 3}, respectively. Differential thermal analysis (DTA) measurements suggested a complicated behavior near the melting point with several thermal transitions observed in the heating and cooling runs. From the shape of the DTA peaks it was deduced that the melting is incongruent for both materials. Magnetic susceptibility measurements (zero-field cooling and field cooling) indicated an antiferromagnetic character with transition temperatures of T=70 K (Cu{sub 3}TaIn{sub 3}Se{sub 7}) and 42 K (CuTa{sub 2}InTe{sub 4}). A spin-glass transition was observed in Cu{sub 3}TaIn{sub 3}Se{sub 7} with T{sub f}{approx}50 K. (copyright 2008 WILEY-VCH Verlag GmbH and Co. KGaA, Weinheim) (orig.)

Pulse shape analysis of enriched BEGe detectors in vacuum cryostat and liquid argon

Energy Technology Data Exchange (ETDEWEB)

Wagner, Victoria [Max-Planck-Institut fuer Kernphysik, Heidelberg (Germany); Collaboration: GERDA-Collaboration

2013-07-01

The Gerda experiment searches for the lepton number violating neutrinoless double beta (0νββ) decay of {sup 76}Ge. Germanium diodes of BEGe type (Canberra, Belgium) made from isotopically modified material have been procured for Phase II of Gerda. They will improve the sensitivity of the experiment by additional target mass, improved energy resolution and enhanced pulse shape discrimination (PSD) against background events. The PSD efficiencies of the new enriched BEGe detectors were studied in vacuum cryostats as part of the characterization campaign at the HADES underground laboratory. For a deeper understanding of the pulse shape performance of the enriched BEGe detectors, detailed {sup 241}Am surface scans were performed. Unexpectedly high position-dependence of the pulse shape parameter Amplitude-over-Energy was found for some of the detectors. With further investigation this effect was traced to surface charge effects specific to the operational configuration of the detectors inside the vacuum cryostats. The standard behavior is restored when they are operated in liquid argon in the configuration intended for Gerda Phase II. Finally, five of the enriched BEGe diodes were installed in the Gerda liquid argon cryostat prior to the full upgrade. They show a good performance and are able to reject efficiently multi-site-events as well as β- and α-particles.

Almost there: Sector 7-8 being cooled to 4.5K!

CERN Multimedia

2007-01-01

The cool down of the 3km long LHC sector 7-8 between point 7 (Ferney-Voltaire) and point 8 (Prévessin) has entered a new phase. The cryostats with the superconducting magnets, which had been kept around 20 K (-253°C) for the past week, are gradually being cooled down to 4.5 K (-268°C) and filled with liquid helium. This new phase in the cooling process was successfully started on Monday 5 March and is progressing after a tuning session that lasted most of the day. To get down to 1.9K (-271°C), a new component of the cryogenics plant, the 1.8K units, will be turned on. In the meantime the teams who will carry out the magnet powering are busy validating the test procedures and running the interlock tests to ensure safe operation of the equipment. They are ready to start the powering as soon as the cryo team reaches stable conditions at 1.9 K. Follow the cool down on the Hardware Commissioning Coordination website.

Influence of nitrogen surface functionalities on the catalytic activity of activated carbon in low temperature SCR of NO{sub x} with NH{sub 3}

Energy Technology Data Exchange (ETDEWEB)

Szymanski, Grzegorz S. [Faculty of Chemistry, Nicolaus Copernicus University, Gagarina 7, 87-100 Torun (Poland); Grzybek, Teresa [Faculty of Fuels and Energy, AGH, University of Science and Technology, Al. Mickiewicza 30, 30-059 Krakow (Poland); Papp, Helmut [Faculty of Chemistry and Mineralogy, Institute of Technical Chemistry, University of Leipzig, Linnerstrasse 3, 04103 Leipzig (Germany)

2004-06-15

The reduction of nitrogen oxide with ammonia was studied using carbon catalysts with chemically modified surfaces. Carbon samples with different surface chemistry were obtained from commercial activated carbon D43/1 (CarboTech, Essen, Germany) by chemical modification involving oxidation with conc. nitric acid (DOx) (1); high temperature treatment (=1000K) under vacuum (DHT) (2); or in ammonia (DHTN, DOxN) (3). Additionally, a portion of the DOx sample was promoted with iron(III) ions (DOxFe). The catalytic tests were performed in a microreactor at a temperature range of 413-573K. The carbon sample annealed under vacuum (DHT) showed the lowest activity. The formation of surface acidic surface oxides by nitric acid treatment (DOx) enhanced the catalytic activity only slightly. However, as can be expected, subsequent promotion of the DOx sample with iron(III) ions increased drastically its catalytic activity. However, this was accompanied by some loss of selectivity, i.e. formation of N{sub 2}O as side product. This effect can be avoided using ammonia-treated carbons which demonstrated reasonable activity with simultaneous high selectivity. The most active and selective among them was the sample that was first oxidized with nitric acid and then heated in an ammonia stream (DOxN). A correlation between catalytic activity and surface nitrogen content was observed. Surface nitrogen species seem to play an important role in catalytic selective reduction of nitrogen oxide with ammonia, possibly facilitating NO{sub 2} formation (a reaction intermediate) as a result of easier chemisorption of oxygen and nitrogen oxide.

Conceptual design of the cryostat for the new high luminosity (HL-LHC) triplet magnets

Science.gov (United States)

Ramos, D.; Parma, V.; Moretti, M.; Eymin, C.; Todesco, E.; Van Weelderen, R.; Prin, H.; Berkowitz Zamora, D.

2017-12-01

The High Luminosity LHC (HL-LHC) is a project to upgrade the LHC collider after 2020-2025 to increase the integrated luminosity by about one order of magnitude and extend the physics production until 2035. An upgrade of the focusing triplets insertion system for the ATLAS and CMS experiments is foreseen using superconducting magnets operating in a pressurised superfluid helium bath at 1.9 K. This will require the design and construction of four continuous cryostats, each about sixty meters in length and one meter in diameter, for the final beam focusing quadrupoles, corrector magnets and beam separation dipoles. The design is constrained by the dimensions of the existing tunnel and accessibility restrictions imposing the integration of cryogenic piping inside the cryostat, thus resulting in a very compact integration. As the alignment and position stability of the magnets is crucial for the luminosity performance of the machine, the magnet support system must be carefully designed in order to cope with parasitic forces and thermo-mechanical load cycles. In this paper, we present the conceptual design of the cryostat and discuss the approach to address the stringent and often conflicting requirements of alignment, integration and thermal aspects.

Improvement of photoluminescence intensity of Ce-doped Y{sub 3}Al{sub 5}O{sub 12} phosphor by Si{sub 3}N{sub 4} addition

Energy Technology Data Exchange (ETDEWEB)

Shyu, Jiin-Jyh, E-mail: jjshyu@ttu.edu.tw; Yang, Chia-Wei

2017-06-01

Yttrium aluminum garnet (Y{sub 3}Al{sub 5}O{sub 12}, YAG) has been widely used as a host for luminescent ions. The present paper describes the effects of Si{sub 3}N{sub 4} addition on the formation and photoluminescence properties of the Ce-doped YAG yellow phosphors. Phosphor powders with the nominal compositions of Y{sub 2.95}Ce{sub 0.05}Al{sub 5-m}Si{sub m}O{sub 12-m}N{sub m} (m = 0–0.6) were prepared by calcining the mixed raw materials at 1500 °C in nitrogen atmosphere. X-ray diffraction, x-ray photoelectron spectroscopy, scanning electron microscope, and transmission electron microscopy equipped with an energy dispersive x-ray spectrometer were used to characterize the structure of the calcined powders. The photoluminescence properties were measured with fluorescence spectrophotometry. It was found that in the range of m = 0–0.27, single phase YAG solid solution (s.s.) in which the Y, Al, and O sites are partially occupied by Ce, Si, and N ions, respectively. The nitrogen ions do not distribute homogeneously over the YAG lattice. The tendency to bond with nitrogen ion for the cations is (Y, Ce) > Si > Al. With the increase in the Si{sub 3}N{sub 4} content, the increase in both the Ce{sup 3+}/(Ce{sup 3+} + Ce{sup 4+}) ratio and the Ce-N bonds improve the intensity of the photoluminescent emission. At m = 0.27, the emission intensity reaches a maximum which is about 2.5 and 1.6 times of that for the Si{sub 3}N{sub 4}-free composition (m = 0) calcined in air and nitrogen, respectively. When the Si{sub 3}N{sub 4} content (m) is higher than 0.27, the emission intensity decreases due to the existence of residual Si{sub 3}N{sub 4} phase. - Highlights: • Addition of Si{sub 3}N{sub 4} can increase the emission intensity of YAG:Ce up to 2.5 times. • Increase in the Ce{sup 3+}/Ce{sup 4+} ratio and the number of Ce-N bonds improve the emission. • The tendency to bond with nitrogen ion for cations in YAG:Ce is (Y, Ce) > Si > Al. • The incomplete dissolution

Explosion hazard in liquid nitrogen cooled fusion systems

International Nuclear Information System (INIS)

Brereton, S.J.

1988-01-01

The explosion hazard associated with the use of liquid nitrogen in a radiation environment in fusion facilities has been investigated. The principal product of irradiating liquid nitrogen is thought to be ozone, resulting from the action of radiation on oxygen impurity. Ozone is a very unstable material, and explosions may occur as it rapidly decomposes to oxygen. Occurrences of this problem in irradiated liquid nitrogen systems are reviewed. An empirical expression, from early experiments, for the yield of ozone in liquid nitrogen-oxygen mixtures exposed to gamma radiation is employed to assess the degree of ozone explosion hazard expected at fusion facilities. The problem is investigated for the Compact Ignition Tokamak (CIT) as a particular example. 16 refs., 5 figs., 1 tab

COOLING STAGES OF CRYOGENIC SYSTEMS

OpenAIRE

Троценко, А. В.

2011-01-01

The formalized definition for cooling stage of low temperature system is done. Based on existing information about the known cryogenic unit cycles the possible types of cooling stages are single out. From analyses of these stages their classification by various characteristics is suggested. The results of thermodynamic optimization of final throttle stage of cooling, which are used as working fluids helium, hydrogen and nitrogen, are shown.

Development of the Cryogenic System of AEgIS at CERN

CERN Document Server

Derking, J H; Burghart, G; Doser, M; Dudarev, A; Haider, S

2014-01-01

The AEgIS (Antimatter Experiment: Gravity, Interferometry, Spectroscopy) experiment is located at the antiproton decelerator complex of CERN. The main goal of the experiment is to perform the first direct measurement of the Earth’s gravitational acceleration on antihydrogen atoms within 1% precision. The antihydrogen is produced in a cylindrical Penning trap by combining antiprotons with positrons. To reach the precision of 1%, the antihydrogen has to be cooled to 100 mK to reduce its random velocity. A dilution refrigerator is selected to deliver the necessary cooling capacity of 100 μW at 50 mK. The AEgIS cryogenic system basically consists of cryostats for a 1-T and for a 5-T superconducting magnet, a central region cryostat, a dilution refrigerator cryostat and a measurement cryostat with a Moiré deflectometer to measure the gravitational acceleration. In autumn 2012, the 1-T cryostat, 5-T cryostat and central region cryostat were assembled and commissioned. The apparatus is cooled down in eight days ...

ATLAS endcap liquid argon calorimeters. Description and construction of the cryostats

Energy Technology Data Exchange (ETDEWEB)

Mace, Guy; Prat, Serge; Veillet, Jean-Jacques [Laboratoire de l' Accelerateur Lineaire IN2P3-CNRS et Universite de Paris-Sud 11, BP 34, F-91898 Orsay Cedex (France)

2006-05-15

All forward calorimeters of the ATLAS detector use the same detection technique, energy loss in passive plates, followed by ionisation and charge detection in liquid argon. They are therefore all grouped in the same vessel which must basically support and keep in place the heavy plates and the detection electrodes and maintain liquid argon at cold and stable temperature. Taking into account all the constraints as detailed below, and the overall detector size, 5 meter diameter by 3 meter length this was quite a challenge. The design, construction and tests of these two cryostats, up to their delivery at CERN, are described in this document. These two cryostats are a joint 'in kind' contribution to the Atlas experiment of LAL (Orsay), Max Planck Institute (Muenchen) and Wuppertal University (Wuppertal) and have been designed and built under the responsibility of LAL (Orsay) with contributions of the technical groups of the above institutions and of ATLAS-CERN. (authors)

ATLAS endcap liquid argon calorimeters. Description and construction of the cryostats

International Nuclear Information System (INIS)

Mace, Guy; Prat, Serge; Veillet, Jean-Jacques

2006-05-01

All forward calorimeters of the ATLAS detector use the same detection technique, energy loss in passive plates, followed by ionisation and charge detection in liquid argon. They are therefore all grouped in the same vessel which must basically support and keep in place the heavy plates and the detection electrodes and maintain liquid argon at cold and stable temperature. Taking into account all the constraints as detailed below, and the overall detector size, 5 meter diameter by 3 meter length this was quite a challenge. The design, construction and tests of these two cryostats, up to their delivery at CERN, are described in this document. These two cryostats are a joint 'in kind' contribution to the Atlas experiment of LAL (Orsay), Max Planck Institute (Muenchen) and Wuppertal University (Wuppertal) and have been designed and built under the responsibility of LAL (Orsay) with contributions of the technical groups of the above institutions and of ATLAS-CERN. (authors)

Visible sub-band gap photoelectron emission from nitrogen doped and undoped polycrystalline diamond films

Energy Technology Data Exchange (ETDEWEB)

Elfimchev, S., E-mail: sergeyel@tx.technion.ac.il; Chandran, M.; Akhvlediani, R.; Hoffman, A.

2017-07-15

Highlights: • Nitrogen related centers in diamond film are mainly responsible for visible sub-band-gap photoelectron emission. • The influence of film thickness and substrate on the measured photoelectron emission yields was not found. • Nanocrystalline diamonds have low electron emission yields most likely because of high amount of defects. • Visible sub-band gap photoelectron emission may increase with temperature due to electron trapping/detrapping processes. - Abstract: In this study the origin of visible sub-band gap photoelectron emission (PEE) from polycrystalline diamond films is investigated. The PEE yields as a function of temperature were studied in the wavelengths range of 360–520 nm. Based on the comparison of electron emission yields from diamond films deposited on silicon and molybdenum substrates, with different thicknesses and nitrogen doping levels, we suggested that photoelectrons are generated from nitrogen related centers in diamond. Our results show that diamond film thickness and substrate material have no significant influence on the PEE yield. We found that nanocrystalline diamond films have low electron emission yields, compared to microcrystalline diamond, due to the presence of high amount of defects in the former, which trap excited electrons before escaping into the vacuum. However, the low PEE yield of nanocrystalline diamond films was found to increase with temperature. The phenomenon was explained by the trap assisted photon enhanced thermionic emission (ta-PETE) model. According to the ta-PETE model, photoelectrons are trapped by shallow traps, followed by thermal excitation at elevated temperatures and escape into the vacuum. Activation energies of trap levels were estimated for undoped nanocrystalline, undoped microcrystalline and N-doped diamond films using the Richardson-Dushman equation, which gives 0.13, 0.39 and 0.04 eV, respectively. Such low activation energy of trap levels makes the ta-PETE process very

Characteristics of poly- and mono-crystalline BeO and SiO{sub 2} as thermal and cold neutron filters

Energy Technology Data Exchange (ETDEWEB)

Adib, M.; Habib, N. [Reactor Physics Department, NRC, Atomic Energy Authority, Cairo (Egypt); Bashter, I.I. [Physics Department, Faculty of Science, Zagazig University (Egypt); Morcos, H.N.; El-Mesiry, M.S. [Reactor Physics Department, NRC, Atomic Energy Authority, Cairo (Egypt); Mansy, M.S., E-mail: drmohamedmansy88@hotmail.com [Reactor Physics Department, NRC, Atomic Energy Authority, Cairo (Egypt)

2015-09-01

Highlights: • Neutron filtering features of BeO and SiO{sub 2} poly- and mono-crystals. • Calculations of the cold and thermal neutron cross sections and transmission with the code “HEXA-FILTERS”. • Optimal mosaic spread, thicknesses and cutting planes for BeO and SiO{sub 2} mono-crystals. - Abstract: A simple model along with a computer code “HEXA-FILTERS” is used to carry out the calculation of the total cross-sections of BeO and SiO{sub 2} having poly or mono-crystalline form as a function of neutron wavelength at room (R.T.) and liquid nitrogen (L.N.) temperatures. An overall agreement is indicated between the calculated neutron cross-sections and experimental data. Calculation shows that 25 cm thick of polycrystalline BeO cooled at liquid nitrogen temperature was found to be a good filter for neutron wavelengths longer than 0.46 nm. While, 50 cm of SiO{sub 2}, with much less transmission, for neutrons with wavelengths longer than 0.85 nm. It was also found that 10 cm of BeO and 15 cm SiO{sub 2} thick mono-crystals cut along their (0 0 2) plane, with 0.5° FWHM on mosaic spread and cooled at L.N., are a good thermal neutron filter, with high effect-to-noise ratio.

Carbon and nitrogen co-doping self-assembled MoS{sub 2} multilayer films

Energy Technology Data Exchange (ETDEWEB)

Zhang, Xiaoqin [State Key Laboratory of Solid Lubrication, Lanzhou Institute of Chemical Physics, Chinese Academy of Sciences, Lanzhou 730000 (China); School of Materials Science and Engineering, Lanzhou University of Technology, Lanzhou 730050 (China); Xu, Jiao; Chai, Liqiang [State Key Laboratory of Solid Lubrication, Lanzhou Institute of Chemical Physics, Chinese Academy of Sciences, Lanzhou 730000 (China); He, Tengfei [State Key Laboratory of Solid Lubrication, Lanzhou Institute of Chemical Physics, Chinese Academy of Sciences, Lanzhou 730000 (China); School of Materials Science and Engineering, Lanzhou University of Technology, Lanzhou 730050 (China); Yu, Fucheng [School of Materials Science and Engineering, Lanzhou University of Technology, Lanzhou 730050 (China); Wang, Peng, E-mail: pengwang@licp.cas.cn [State Key Laboratory of Solid Lubrication, Lanzhou Institute of Chemical Physics, Chinese Academy of Sciences, Lanzhou 730000 (China)

2017-06-01

Highlights: • Mo–S–C–N composite films were synthesized by using reactive magnetron sputtering. • A self-assembled multilayer structure with periodicity in the nanometer scale was formed in the composite film. • The hardness of Mo–S–C–N film deposited at optimized parameter reaches up to 9.76 GPa. • The wear rate of deposited Mo–S–C–N film both in vacuum and ambient atmosphere decreases dramatically. - Abstract: Mo–S–C–N composite films were prepared using reactive magnetron sputtering of graphite and MoS{sub 2} targets in argon and nitrogen atmospheres. The effects of carbon/nitrogen co-doping and carbon concentration on the composition, microstructure, mechanical and tribological properties of deposited films have been investigated by various characterization techniques. The results show that the deposited films comprise MoS{sub 2} nanocrystalline and amorphous carbon, and the incorporating nitrogen forms Mo-N and C–N chemical bonds. Increasing carbon concentration leads to the increase of sp{sup 2} carbon fraction in the films. Furthermore, the high-resolution transmission electron microscopy reveals that a self-assembled multilayer structure with periodicity in the nanometer scale is formed in the Mo–S–C–N film. Benefiting from the composite and self-assembled multilayer structures, the hardness of Mo–S–C–N film deposited at optimized parameter reaches up to 9.76 GPa, and corresponding friction experiment indicates that this composite films display low friction coefficient and high wear resistance both in vacuum and ambient air conditions.

Lattice parameter values and phase transitions for the Cu{sub 2}Cd{sub 1-z}Mn {sub z}GeSe{sub 4} and Cu{sub 2}Cd{sub 1-z}Fe {sub z}GeSe{sub 4} alloys

Energy Technology Data Exchange (ETDEWEB)

Quintero, E. [Centro de Estudios de Semiconductores, Departamento de Fisica, Facultad de Ciencias, Universidad de Los Andes, Merida 5101 (Venezuela); Tovar, R. [Centro de Estudios de Semiconductores, Departamento de Fisica, Facultad de Ciencias, Universidad de Los Andes, Merida 5101 (Venezuela); Quintero, M. [Centro de Estudios de Semiconductores, Departamento de Fisica, Facultad de Ciencias, Universidad de Los Andes, Merida 5101 (Venezuela)]. E-mail: mquinter@ula.ve; Delgado, G.E. [Laboratorio de Cristalografia, Departamento de Quimica, Facultad de Ciencias, Universidad de Los Andes, Merida 5101 (Venezuela); Morocoima, M. [Centro de Estudios de Semiconductores, Departamento de Fisica, Facultad de Ciencias, Universidad de Los Andes, Merida 5101 (Venezuela); Caldera, D. [Centro de Estudios de Semiconductores, Departamento de Fisica, Facultad de Ciencias, Universidad de Los Andes, Merida 5101 (Venezuela); Ruiz, J. [Centro de Estudios de Semiconductores, Departamento de Fisica, Facultad de Ciencias, Universidad de Los Andes, Merida 5101 (Venezuela); Mora, A.E. [Laboratorio de Analisis Quimico y Estructural de Materiales, Departamento de Fisica, Universidad de Los Andes, Merida 5101 (Venezuela); Briceno, M. [Laboratorio de Analisis Quimico y Estructural de Materiales, Departamento de Fisica, Universidad de Los Andes, Merida 5101 (Venezuela); Fernandez, J.L. [Laboratorio de Analisis Quimico y Estructural de Materiales, Departamento de Fisica, Universidad de Los Andes, Merida 5101 (Venezuela)

2007-04-25

X-ray powder diffraction measurements and differential thermal analysis (DTA) were made on polycrystalline samples of the Cu{sub 2}Cd{sub 1-z}Mn {sub z}GeSe{sub 4} and Cu{sub 2}Cd{sub 1-z}Fe {sub z}GeSe{sub 4} alloy systems. The diffraction patterns were used to show the equilibrium conditions and to derive lattice parameter values. The effect of the annealing temperature and cooling rate to room temperature are discussed. For the Cu{sub 2}Cd{sub 1-z}Fe {sub z}GeSe{sub 4} system, only two single solid phase fields, the tetragonal stannite {alpha} and the wurtz-stannite {delta} structures were found to occur in the diagram. For the Cu{sub 2}Cd{sub 1-z}Mn {sub z}GeSe{sub 4} system, in addition to the tetragonal stannite {alpha} and the wurtz-stannite {delta} phases, MnSe was found to exist in the diagram. The DTA experiments showed that the cooling curves for both systems exhibited effects of undercooling.

Enhanced photocatalytic degradation of dye under visible light on mesoporous microspheres by defects in manganese- and nitrogen-co-doped TiO{sub 2}

Energy Technology Data Exchange (ETDEWEB)

Feng, Lu; Jiang, Heng, E-mail: hjiang78@hotmail.com [Liaoning Shihua University, School of Chemistry and Materials Science (China); Zou, Mingming; Xiong, Fengqiang; Ganeshraja, Ayyakannu Sundaram; Pervaiz, Erum [Chinese Academy of Sciences, Dalian National Laboratory for Clean Energy, Dalian Institute of Chemical Physics (China); Liu, Yinan; Zou, Shunying [Dalian Environmental Protection Laboratory (China); Yang, Minghui, E-mail: myang@dicp.ac.cn [Chinese Academy of Sciences, Dalian National Laboratory for Clean Energy, Dalian Institute of Chemical Physics (China)

2016-09-15

Manganese- and nitrogen-co-doped mesoporous TiO{sub 2} microsphere photocatalysts are prepared by a simple sol–gel method with controllable sizes in the range of 400–500 nm and high surface area of 112 m{sup 2} g{sup −1}. Manganous acetate is the Mn source, and ammonia gas is the nitrogen source used. The dopants are found to be uniformly distributed in the TiO{sub 2} matrix. Interestingly, in (Mn,N)-co-doped TiO{sub 2}, we observe an effective indirect band gap of ~2.58 eV. (Mn,N)-co-doped mesoporous TiO{sub 2} microspheres show higher photocatalytic activity than Mn–TiO{sub 2} microspheres under visible light irradiation. Among the samples reported in this work, 0.2 at.% Mn doping and 500 °C 2-h nitriding condition give the highest photocatalytic activity. The observed photocatalytic activity in the (Mn,N)-co-doped TiO{sub 2} is attributed to the contribution from improved absorption due to trap levels of Mn, oxygen vacancies and N doping.Graphical AbstractManganese- and nitrogen-co-doped mesoporous TiO{sub 2} microspheres containing substitutional N, interstitial N and O vacancies show high visible light photocatalytic activity.

Visible-light activity of N-LiInO{sub 2}: Band structure modifications through interstitial nitrogen doping

Energy Technology Data Exchange (ETDEWEB)

Xu, Kaiqiang [College of Material Science and Engineering, Hunan University, Changsha, 410082 (China); Xu, Difa, E-mail: xudifa@sina.com [Hunan Key Laboratory of Applied Environmental Photocatalysis, Changsha University, Changsha, 410022 (China); Zhang, Xiangchao; Luo, Zhuo; Wang, Yutang [Hunan Key Laboratory of Applied Environmental Photocatalysis, Changsha University, Changsha, 410022 (China); Zhang, Shiying, E-mail: cdzhangshiying@163.com [College of Material Science and Engineering, Hunan University, Changsha, 410082 (China); Hunan Key Laboratory of Applied Environmental Photocatalysis, Changsha University, Changsha, 410022 (China)

2017-01-01

Highlights: • The interstitial nitrogen doping into LiInO{sub 2} is achieved at low temperature. • The band gap narrowing to an extent of 2.8 eV from 3.5 eV is observed. • The doping favours charge carrier separation and photocatalytic activity. • Superoxide radical is the dominant active specie in the pollutant degradation. - Abstract: Element doping is a promising strategy to improve the photo-response and photocatalytic activity of semiconductor photocatalyst with a wide band gap. To reduce the band gap of LiInO{sub 2} that is considered as a novel photocatalyst, nitrogen-doped LiInO{sub 2} (N-LiInO{sub 2}) is successfully fabricated by treating LiInO{sub 2} and urea at 200 °C. It is found that interstitial instead of substitutional configurations are formed in the crystal structure of N-LiInO{sub 2} due to the low-treating temperature and rich-oxygen conditions. The interstitial N-doping forms a doping state with 0.6 eV above the valence band maximum and a defect state with 0.1 eV below the conduction band minimum, reducing the band gap of LiInO{sub 2} from 3.5 to 2.8 eV. N-LiInO{sub 2} exhibits higher photocatalytic activity towards methylene blue (MB) degradation under 380 nm light irradiation, which is 1.4 times that of pure LiInO{sub 2}. The enhanced photocatalytic activity of N-LiInO{sub 2} is attributed to the extended light absorption and the improved charge carrier separation, which result in more reactive species participating in the photcatalytic process. This work provides a further understanding on tuning the band structure of semiconductor photocatalyst by N-doping strategies.

Effect of titanium dioxide (TiO{sub 2}) on largely improving solar reflectance and cooling property of high density polyethylene (HDPE) by influencing its crystallization behavior

Energy Technology Data Exchange (ETDEWEB)

Wang, Shichao; Zhang, Jun, E-mail: zhangjun@njtech.edu.cn

2014-12-25

Highlights: • HDPE/TiO{sub 2} composites have more perfect crystal structure. • Refractive index is the key factor affecting the final solar reflectance. • HDPE/TiO{sub 2} composites can achieve high solar reflectance. • The real cooling property is in accordance with solar reflectance. - Abstract: In this study, the different crystal forms of titanium dioxide (TiO{sub 2}) were added into high density polyethylene (HDPE) to fabricate cool material. Crystal structure, crystallization behavior, crystal morphology were investigated by wide angle X-ray diffraction (WAXD), differential scanning calorimetry (DSC) and polarized optical microscope (POM). Scanning electron microscope (SEM) was applied to observe dispersion of TiO{sub 2} particles in the HDPE matrix and the cross section morphology. The solar reflectance and actual cooling property were evaluated by UV–Vis–NIR spectrometer and a self-designed device. By adding TiO{sub 2} particles into HDPE matrix, the polymer chain could crystallize into more perfect and thermal stable lamella. The presence of TiO{sub 2} particles dramatically increased the number of nucleation site therefore decreased the crystal size. The subsequent solar reflectance was related to the degree of crystallinity, the spherulite size of HDPE, refractive index, and distribution of TiO{sub 2} particles in HDPE matrix. It was found the rutile TiO{sub 2} could largely improve the total solar reflectance from 28.2% to 51.1%. Finally, the temperature test showed that the composites had excellent cooling property, which was in accordance with solar reflectance result.

Understanding Nitrogen Fixation

Energy Technology Data Exchange (ETDEWEB)

Paul J. Chirik

2012-05-25

The purpose of our program is to explore fundamental chemistry relevant to the discovery of energy efficient methods for the conversion of atmospheric nitrogen (N{sub 2}) into more value-added nitrogen-containing organic molecules. Such transformations are key for domestic energy security and the reduction of fossil fuel dependencies. With DOE support, we have synthesized families of zirconium and hafnium dinitrogen complexes with elongated and activated N-N bonds that exhibit rich N{sub 2} functionalization chemistry. Having elucidated new methods for N-H bond formation from dihydrogen, C-H bonds and Broensted acids, we have since turned our attention to N-C bond construction. These reactions are particularly important for the synthesis of amines, heterocycles and hydrazines with a range of applications in the fine and commodity chemicals industries and as fuels. One recent highlight was the discovery of a new N{sub 2} cleavage reaction upon addition of carbon monoxide which resulted in the synthesis of an important fertilizer, oxamide, from the diatomics with the two strongest bonds in chemistry. Nitrogen-carbon bonds form the backbone of many important organic molecules, especially those used in the fertilizer and pharamaceutical industries. During the past year, we have continued our work in the synthesis of hydrazines of various substitution patterns, many of which are important precursors for heterocycles. In most instances, the direct functionalization of N{sub 2} offers a more efficient synthetic route than traditional organic methods. In addition, we have also discovered a unique CO-induced N{sub 2} bond cleavage reaction that simultaneously cleaves the N-N bond of the metal dinitrogen compound and assembles new C-C bond and two new N-C bonds. Treatment of the CO-functionalized core with weak Broensted acids liberated oxamide, H{sub 2}NC(O)C(O)NH{sub 2}, an important slow release fertilizer that is of interest to replace urea in many applications. The

Characterisation of a cryostat using simultaneous, single-beam multiple-surface laser vibrometry

Energy Technology Data Exchange (ETDEWEB)

Kissinger, Thomas; Charrett, Thomas O. H.; James, Stephen W.; Tatam, Ralph P., E-mail: r.p.tatam@cranfield.ac.uk [Engineering Photonics, Cranfield University, Cranfield, MK43 0AL (United Kingdom); Adams, Alvin; Twin, Andrew [Oxford Instruments Nanoscience, Tubney Woods, Abingdon, Oxon, OX13 5QX (United Kingdom)

2016-06-28

A novel range-resolved interferometric signal processing technique that uses sinusoidal optical frequency modulation is applied to multi-surface vibrometry, demonstrating simultaneous optical measurements of vibrations on two surfaces using a single, collimated laser beam, with a minimum permissible distance of 3.5 cm between surfaces. The current system, using a cost-effective laser diode and a fibre-coupled, downlead insensitive setup, allows an interferometric fringe rate of up to 180 kHz to be resolved with typical displacement noise levels of 8 pm · Hz{sup −05}. In this paper, the system is applied to vibrometry measurements of a table-top cryostat, with concurrent measurements of the optical widow and the sample holder target inside. This allows the separation of common-mode vibrations of the whole cryostat from differential vibrations between the window and the target, allowing any resonances to be identified.

Cooling unit for a superconducting power cable. Two years successful operation

Energy Technology Data Exchange (ETDEWEB)

Herzog, Friedhelm [Messer Group GmbH, Krefeld (Germany); Kutz, Thomas [Messer Industriegase GmbH, Bad Soden (Germany); Stemmle, Mark [Nexans Deutschland GmbH, Hannover (Germany); Kugel, Torsten [Westnetz GmbH, Essen (Germany)

2016-07-01

High temperature super conductors (HTS) can efficiently be cooled with liquid nitrogen down to a temperature of 64 K (-209 C). Lower temperatures are not practical, because nitrogen becomes solid at 63 K (-210 C). To achieve this temperature level the coolant has to be vaporized below atmospheric pressure. Messer has developed a cooling unit with an adequate vacuum subcooler, a liquid nitrogen circulation system, and a storage vessel for cooling an HTS power cable. The cooling unit was delivered in 2013 for the German AmpaCity project of RWE Deutschland AG, Nexans and Karlsruhe Institute of Technology. Within this project RWE and Nexans installed the worldwide longest superconducting power cable in the city of Essen, Germany. The cable is in operation since March 10th, 2014.

Amorphous phase formation in the Cu{sub 36}Zr{sub 59}A{sub l5} and Cu{sub 48}Zr{sub 43}A{sub l9} ternary alloys studied by molecular dynamics; Estudo da formacao de fase amorfa nas ligas ternarias Cu{sub 36}Zr{sub 59}A{sub l5} e Cu{sub 48}Zr{sub 43}A{sub l9} por dinamica molecular

Energy Technology Data Exchange (ETDEWEB)

Aliaga, L.C.R.; Schimidt, C.S.; Lima, L.V.; Domingues, G.M.B.; Bastos, I.N., E-mail: aliaga@iprj.uer.br [Universidade do Estado do Rio de Janeiro (UERJ), Nova friburgo, RJ (Brazil). Departamento de Materiais

2016-07-01

Amorphous alloys presents better mechanical and physical properties than its crystalline counterparts. However, there is a scarce understanding on structure - properties relationship in this class of materials. This paper presents the results of the molecular dynamics application to obtain an atomistic description of melting, solidification and the glass forming ability in the ternary Cu{sub 36}Zr{sub 59}A{sub l5} and Cu{sub 48}Zr{sub 43}A{sub l9} alloys. In the study we used the EAM potential and different cooling rates, β = 0.1, 1 and 100 K/ps to form the amorphous phase in a system consisting of 32,000 atoms by using the free code LAMMPS. The solidus and liquidus temperatures, on a heating rate of the 5 K/ps, were obtained. Also, on the cooling down step, it was observed that the glass transition temperature (T{sub g}) decreases as cooling rate increases. The structural evolution was analyzed through the radial distribution functions and Voronoi polyhedra. Furthermore, it was determined the evolution of viscosity upper T{sub g}, as well as the fragility (m) parameter for each amorphous alloy. The thermal parameters of the simulation obtained are compared with those of the experiments. (author)

Nitrogen isotope ratios in surface and sub-surface soil horizons

International Nuclear Information System (INIS)

Rennie, D.A.; Paul, E.A.

1975-01-01

Nitrogen isotope analysis of surface soils and soil-derived nitrate for selected chernozemic and luvisolic soils showed mean delta 15 N values of 11.7 and 11.3, respectively. Isotope enrichment of the total N reached a maximum in the lower B horizon. Sub-soil parent material samples from the one deep profile included in the study indicated a delta 15 N value (NO 3 -N) of 1/3 that of the Ap horizon, at a depth of 180 cm. The delta 15 N of sub-surface soil horizons containing residual fertilizer N were low (-2.2) compared to the surface horizon (9.9). The data reported from this preliminary survey suggest that the natural variations in 15 N abundance between different soils and horizons of the same soil reflect the cumulative effects of soil genesis and soil management. More detailed knowledge and understanding of biological and other processes which control N isotope concentrations in these soils must be obtained before the data reported can be interpreted. (author)

Effect of simultaneous cooling on microwave-assisted wet digestion of biological samples with diluted nitric acid and O{sub 2} pressure

Energy Technology Data Exchange (ETDEWEB)

Bizzi, Cezar A. [Departamento de Química, Universidade Federal de Santa Maria, Santa Maria, Rio Grande do Sul 97105-900 (Brazil); Nóbrega, Joaquim A. [Departamento de Química, Universidade Federal de São Carlos, São Carlos, São Paulo 13565-905 (Brazil); Barin, Juliano S. [Departamento de Tecnologia e Ciência dos Alimentos, Universidade Federal de Santa Maria, Santa Maria, Rio Grande do Sul 97105-900 (Brazil); Oliveira, Jussiane S.S.; Schmidt, Lucas; Mello, Paola A. [Departamento de Química, Universidade Federal de Santa Maria, Santa Maria, Rio Grande do Sul 97105-900 (Brazil); Flores, Erico M.M., E-mail: ericommf@gmail.br [Departamento de Química, Universidade Federal de Santa Maria, Santa Maria, Rio Grande do Sul 97105-900 (Brazil)

2014-07-21

Highlights: • Simultaneously cooling during microwave heating for improving digestion efficiency. • Maximum MW power delivered into cavity, improving the temperature in liquid phase. • Temperature gradient increases regeneration reaction of HNO{sub 3} in O{sub 2} rich atmosphere. • Digestion of several matrices using diluted HNO{sub 3} combined with O{sub 2} pressure. - Abstract: The present work evaluates the influence of vessel cooling simultaneously to microwave-assisted digestion performed in a closed system with diluted HNO{sub 3} under O{sub 2} pressure. The effect of outside air flow-rates (60–190 m{sup 3} h{sup −1}) used for cooling of digestion vessels was evaluated. An improvement in digestion efficiency caused by the reduction of HNO{sub 3} partial pressure was observed when using higher air flow-rate (190 m{sup 3} h{sup −1}), decreasing the residual carbon content for whole milk powder from 21.7 to 9.3% (lowest and highest air flow-rate, respectively). The use of high air flow-rate outside the digestion vessel resulted in a higher temperature gradient between liquid and gas phases inside the digestion vessel and improved the efficiency of sample digestion. Since a more pronounced temperature gradient was obtained, it contributed for increasing the condensation rate and thus allowed a reduction in the HNO{sub 3} partial pressure of the digestion vessel, which improved the regeneration of HNO{sub 3}. An air flow-rate of 190 m{sup 3} h{sup −1} was selected for digestion of animal fat, bovine liver, ground soybean, non fat milk powder, oregano leaves, potato starch and whole milk powder samples, and a standard reference material of apple leaves (NIST 1515), bovine liver (NIST 1577) and whole milk powder (NIST 8435) for further metals determination by inductively coupled plasma atomic emission spectroscopy (ICP-OES). Results were in agreement with certified values and no interferences caused by matrix effects during the determination step

Nitrogen oxides produced during CO/sub 2/ enrichment. II. Effects on different tomato and lettuce cultivars

Energy Technology Data Exchange (ETDEWEB)

Mortensen, L.M.

1985-01-01

Eight cultivars of Lycopersicon esculentum (tomato) and six cultivars of Lactuca sativa (lettuce) were subjected to CO/sub 2/-enriched air (1000 ..mu..l l/sup -1/) containing 0.7 or 0.9 ..mu..l l/sup -1/ nitrogen oxides (NO/sub x/). CO/sub 2/ enrichment without NO/sub x/ significantly increased the dry weight of all tomato (35-81%) and lettuce cultivars (25-101%). In six of the eight tomato cultivars the dry weight was reduced by the addition of NO/sub x/. The mean relative growth rate (RGR) decreased by 4-19% depending on the cultivar. This meant that the benefit of CO/sub 2/ enrichment was almost completely eliminated in most of the cultivars. Marginal leaf necrosis appeared in some of the cultivars, while in others no visible injury developed. None of the lettuce cultivars was significantly affected by the addition of NO/sub x/. 16 references, 4 tables.

One unit-cell seed layer induced epitaxial growth of heavily nitrogen doped anatase TiO{sub 2} films

Energy Technology Data Exchange (ETDEWEB)

Chen, T L; Hirose, Y; Hitosugi, T; Hasegawa, T [Kanagawa Academy of Science and Technology (KAST), Kawasaki 213-0012 (Japan)], E-mail: chen@ksp.or.jp

2008-03-21

We present a novel way to obtain heavily nitrogen doped anatase TiO{sub 2} films by using a solid-state nitrogen source. Epitaxial growth of the films was realized by introducing one unit-cell seed layer, which was indicated by reflection high-energy electron diffraction as intensity oscillation. Results of x-ray diffraction and x-ray photoelectron spectroscopy confirmed that the films were in the anatase phase heavily doped with nitrogen of {approx}15 at%. The films obtained exhibited considerable narrowing of the optical bandgap, resulting in an enhancement of absorption in the visible-light region. (fast track communication)

Validation and implementation of sandwich structure bottom plate to rib weld joint in the base section of ITER Cryostat

Energy Technology Data Exchange (ETDEWEB)

Prajapati, Rajnikant, E-mail: rajnikant@iter-india.org [ITER-India, Institute For Plasma Research, A-29, GIDC Electronics Estate, Sector-25, Gandhinagar 382016 (India); Bhardwaj, Anil K.; Gupta, Girish; Joshi, Vaibhav; Patel, Mitul; Bhavsar, Jagrut; More, Vipul; Jindal, Mukesh; Bhattacharya, Avik; Jogi, Gaurav; Palaliya, Amit; Jha, Saroj; Pandey, Manish [ITER-India, Institute For Plasma Research, A-29, GIDC Electronics Estate, Sector-25, Gandhinagar 382016 (India); Jadhav, Pandurang; Desai, Hemal [Larsen & Toubro Limited, Heavy Engineering, Hazira Manufacturing Complex, Gujarat (India)

2016-11-01

Highlights: • ITER Cryostat base section sandwich structure bottom plate to rib weld joint is qualified through mock-up. • Established welding sequence was successfully implemented on all six sectors of cryostat base section. • Each layer liquid penetrant examination has been carried out for these weld joints and found satisfactory. - Abstract: Cryostat is a large stainless steel vacuum vessel providing vacuum environment to ITER machine components. The cryostat is ∼30 m in diameter and ∼30 m in height having variable thickness from 25 mm to 180 mm. Sandwich structure of cryostat base section withstands vacuum loading and limits the deformation under service conditions. Sandwich structure consists of top and bottom plates internally strengthened with radial and circular ribs. In current work, sandwich structure bottom plate to rib weld joint has been designed with full penetration joint as per ITER Vacuum Handbook requirement considering nondestructive examinations and welding feasibility. Since this joint was outside the scope of ASME Section VIII Div. 2, it was decided to validate through mock-up of bottom plate to rib joint. Welding sequence was established to control the distortion. Tensile test, macro-structural examination and layer by layer LPE were carried out for validation of this weld joint. However possibility of ultrasonic examination method was also investigated. The test results from the welded joint mock-up were found to confirm all code and specification requirements. The same was implemented in first sector (0–60°) of base section sandwich structure.

Doping dependent magnetism and exchange bias in CaMn{sub 1−x}W{sub x}O{sub 3} manganites

Energy Technology Data Exchange (ETDEWEB)

Markovich, V., E-mail: markoviv@bgu.ac.il; Gorodetsky, G. [Department of Physics, Ben-Gurion University of the Negev, 84105 Beer-Sheva (Israel); Fita, I. [Institute of Physics, Polish Academy of Sciences, Aleja Lotnikow 32/46, PL-02-668 Warsaw (Poland); Donetsk Institute for Physics and Technology, National Academy of Sciences, 83114 Donetsk (Ukraine); Wisniewski, A.; Puzniak, R. [Institute of Physics, Polish Academy of Sciences, Aleja Lotnikow 32/46, PL-02-668 Warsaw (Poland); Mogilyansky, D. [The Ilse Katz Institute for Nanoscale Science and Technology, Ben-Gurion University of the Negev, Beer-Sheva 84105 (Israel); Naumov, S. V.; Mostovshchikova, E. V.; Telegin, S. V. [Institute of Metal Physics, Ural Branch of RAS, Kovalevskaya Street 18, Ekaterinburg 620990 (Russian Federation); Jung, G. [Department of Physics, Ben-Gurion University of the Negev, 84105 Beer-Sheva (Israel); Institute of Physics, Polish Academy of Sciences, Aleja Lotnikow 32/46, PL-02-668 Warsaw (Poland)

2014-09-07

Magnetic properties of CaMn{sub 1−x}W{sub x}O{sub 3} (0 ≤ x ≤ 0.1) have been investigated, and the research was focused on the exchange bias (EB) phenomenon in CaMn{sub 0.93}W{sub 0.07}O{sub 3}. Magnetic ground state was found to be dependent on tungsten doping level and the following states were distinguished: (i) G-type antiferromagnetic (AFM) state with a weak ferromagnetic (FM) component at x = 0 and 0.04; (ii) mostly orbitally ordered C-type AFM at x = 0.07 and 0.1. For the studied manganites, spontaneous magnetization increases sharply with increasing doping level reaching M{sub 0} ≈ 9.5 emu/g at T = 10 K for x = 0.04, and then decreases rapidly reaching zero for x = 0.1. Exchange bias effect, manifested by vertical and horizontal shifts in the hysteresis loop for field cooled sample, has been observed in CaMn{sub 0.93}W{sub 0.07}O{sub 3}. Exchange bias field, coercivity, remanence asymmetry, and magnetic coercivity depend strongly on temperature, cooling field, and maximal measuring field. Horizontal and vertical shifts of magnetization loop sharply decrease with increasing temperature and vanish above 70 K, whereas coercivity and magnetic coercivity disappear only above 100 K (temperature of transition to the G-type AFM state). The exchange bias field H{sub EB} increases with increasing cooling field H{sub cool} and goes through a broad maximum at 40 kOe, while the remanence asymmetry increases monotonously in the entire investigated cooling field range, up to 50 kOe. For the compound with x = 0.07, the size of the FM regions ≈2 nm was estimated from the dependence of exchange bias field H{sub EB} upon H{sub cool}. It is suggested that the exchange bias originates from interface exchange coupling between small FM clusters and the G-type AFM phase inside the primary C-type orbitally ordered AFM phase.

Continuous cooling transformation behaviors of CLAM steel

Energy Technology Data Exchange (ETDEWEB)

Wu, Qing-sheng, E-mail: qingsheng.wu@fds.org.cn; Zheng, Shu-hui; Huang, Qun-ying; Liu, Shao-jun; Han, Yang-yang

2013-11-15

The continuous cooling transformation (CCT) behaviors of CLAM (China Low Activation Martensitic) steel were studied, the CCT diagram was constructed, and the influence of cooling rates on the microstructures was also investigated. The microstructures were investigated using optical microscopy (OM) and microhardness tests were also carried out. The results showed that CLAM steel possessed high hardenability and there were ferrite and martensite transformation regions only. The maximum cooling rate to form ferrite microstructure was found to be 10–12 K/min. In order to obtain fully ferrite microstructure, the cooling rate should be lower than 1 K/min. The CCT diagram also gave relevant parameters such as the transformation temperatures, i.e., A{sub c1}, A{sub c3}, M{sub s} and M{sub f} were 1124 K, 1193 K, 705 K and 593 K, respectively. The diagram made it possible to predict the microstructures and properties of CLAM steel with different cooling rates.

Improvement of critical current density in thallium-based (Tl,Bi)Sr{sub 1.6}Ba{sub 0.4}Ca{sub 2}Cu{sub 3}O{sub x} superconductors

Energy Technology Data Exchange (ETDEWEB)

Ren, Z.F.; Wang, C.A.; Wang, J.H. [State Univ. of New York at Buffalo, Amherst, NY (United States)] [and others

1994-12-31

Epitaxial (Tl,Bi)Sr{sub 1.6}Ba{sub 0.4}Ca{sub 2}Cu{sub 3}O{sub x} (Tl,Bi)-1223 thin films on (100) single crystal LaAlO{sub 3} substrates were synthesized by a two-step procedure. Phase development, microstructure, and relationships between film and substrate were studied by X-ray diffraction (XRD), scanning electron microscopy (SEM), and transmission electron microscopy (TEM). Resistance versus temperature, zero-field-cooled and field-cooled magnetization, and transport critical current density (J{sub c}) were measured. The zero-resistance temperature was 105-111 K. J{sub c} at 77 K and zero field was > 2 x 10{sup 6} A/cm{sup 2}. The films exhibited good flux pinning properties.

Soft X-ray and cathodoluminescence measurement, optimisation and analysis at liquid nitrogen temperatures

Science.gov (United States)

MacRae, C. M.; Wilson, N. C.; Torpy, A.; Delle Piane, C.

2018-01-01

Advances in field emission gun electron microprobes have led to significant gains in the beam power density and when analysis at high resolution is required then low voltages are often selected. The resulting beam power can lead to damage and this can be minimised by cooling the sample down to cryogenic temperatures allowing sub-micrometre imaging using a variety of spectrometers. Recent advances in soft X-ray emission spectrometers (SXES) offer a spectral tool to measure both chemistry and bonding and when combined with spectral cathodoluminescence the complementary techniques enable new knowledge to be gained from both mineral and materials. Magnesium and aluminium metals have been examined at both room and liquid nitrogen temperatures by SXES and the L-emission Fermi-edge has been observed to sharpen at the lower temperatures directly confirming thermal broadening of the X-ray spectra. Gains in emission intensity and resolution have been observed in cathodoluminescence for liquid nitrogen cooled quartz grains compared to ambient temperature quartz. This has enabled subtle growth features at quartz to quartz-cement boundaries to be imaged for the first time.

Three-dimensional eddy current analysis of cryostat outer-vessel in superconductive magnetically levitated vehicle

International Nuclear Information System (INIS)

Nonaka, S.; Sakamoto, T.; Veno, T.

1987-01-01

The eddy currents on the cryostat outer-vessel of an SCM(superconducting magnet) are investigated taking into account of the non-contact on-board power generator system. Numerical expressions are developed by combining a Fourier series method and an integral equation method. It becomes clear that the 5-th space harmonic field which is due to the ground levitation coils, is a dominant factor in the eddy currents of the outer-vessel, and that a concentration of the currents occurs in the corner on the inner side of the bottom of the cryostat outer-vessel. Designs such as the distance between the two arrays of the ground levitation coils, and the lateral location of the induction coils of the power generator are also discussed

M<sub>5sub>Si>3sub>(M=Ti, Nb, Mo) Based Transition-Metal Silicides for High Temperature Applications

Energy Technology Data Exchange (ETDEWEB)

Tang, Zhihong [Iowa State Univ., Ames, IA (United States)

2007-01-01

Transition metal silicides are being considered for future engine turbine components at temperatures up to 1600 C. Although significant improvement in high temperature strength, room temperature fracture toughness has been realized in the past decade, further improvement in oxidation resistance is needed. Oxidation mechanism of Ti<sub>5sub>Si>3sub>-based alloys was investigated. Oxidation behavior of Ti<sub>5sub>Si>3sub>-based alloy strongly depends on the atmosphere. Presence of Nitrogen alters the oxidation behavior of Ti<sub>5sub>Si>3sub> by nucleation and growth of nitride subscale. Ti<sub>5sub>Si>3.2sub>and Ti<sub>5sub>Si>3sub>C>0.5sub> alloys exhibited an excellent oxidation resistance in nitrogen bearing atmosphere due to limited dissolution of nitrogen and increased Si/Ti activity ratio. MoSi<sub>2sub> coating developed by pack cementation to protect Mo-based Mo-Si-B composites was found to be effective up to 1500 C. Shifting coating composition to T1+T2+Mo<sub>3sub>Si region showed the possibility to extend the coating lifetime above 1500 C by more than ten times via formation of slow growing Mo<sub>3sub>Si or T2 interlayer without sacrificing the oxidation resistance of the coating. The phase equilibria in the Nb-rich portion of Nb-B system has been evaluated experimentally using metallographic analysis and differential thermal analyzer (DTA). It was shown that Nb<sub>ss> (solid solution) and NbB are the only two primary phases in the 0-40 at.% B composition range, and the eutectic reaction L {leftrightarrow} Nb<sub>SS> + NbB was determined to occur at 2104 ± 5 C by DTA.

Pressure relief protection in cryostats: CERN’s experience on LHC and HIE Isolde

CERN Multimedia

CERN. Geneva

2016-01-01

Cryostats contain large cold surfaces, cryogenic fluids, and sometimes large stored energy (e.g. energized magnets), with the potential risk of sudden liberation of energy through thermodynamic transformations of the fluids, which can be uncontrolled and lead to a dangerous increase of pressure inside the cryostat envelopes. The consequence, in the case of a rupture of the envelopes, may be serious for personnel (injuries from deflagration, burns, and oxygen deficiency hazard) as well as for the equipment. Performing a thorough risk analysis is an essential step to identify and understand risk hazards that may cause a pressure increase and in order to assess consequences, define mitigation actions, and design adequate safety relief devices to limit pressure accordingly. Lessons learnt from real cases are essential for improving safety awareness for future projects: LHC and HIE Isolde are amongst these examples.

Is cold better ? - exploring the feasibility of liquid-helium-cooled optics

International Nuclear Information System (INIS)

Assoufid, L.; Mills, D.; Macrander, A.; Tajiri, G.

1999-01-01

Both simulations and recent experiments conducted at the Advanced Photon Source showed that the performance of liquid-nitrogen-cooled single-silicon crystal monochromators can degrade in a very rapid nonlinear fashion as the power and for power density is increased. As a further step towards improving the performance of silicon optics, we propose cooling with liquid helium, which dramatically improves the thermal properties of silicon beyond that of liquid nitrogen and brings the performance of single silicon-crystal-based synchrotrons radiation optics up to the ultimate limit. The benefits of liquid helium cooling as well as some of the associated technical challenges will be discussed, and results of thermal and structural finite elements simulations comparing the performance of silicon monochromators cooled with liquid nitrogen and helium will be given

High resolution spectroscopy of jet cooled phenyl radical: The ν{sub 1} and ν{sub 2} a{sub 1} symmetry C–H stretching modes

Energy Technology Data Exchange (ETDEWEB)

Chang, Chih-Hsuan; Nesbitt, David J. [JILA, National Institute of Standards and Technology, University of Colorado, Boulder, Colorado 80309, USA and Department of Chemistry and Biochemistry, University of Colorado, Boulder, Colorado 80309 (United States)

2016-07-28

A series of CH stretch modes in phenyl radical (C{sub 6}H{sub 5}) has been investigated via high resolution infrared spectroscopy at sub-Doppler resolution (∼60 MHz) in a supersonic discharge slit jet expansion. Two fundamental vibrations of a{sub 1} symmetry, ν{sub 1} and ν{sub 2}, are observed and rotationally analyzed for the first time, corresponding to in-phase and out-of-phase symmetric CH stretch excitation at the ortho/meta/para and ortho/para C atoms with respect to the radical center. The ν{sub 1} and ν{sub 2} band origins are determined to be 3073.968 50(8) cm{sup −1} and 3062.264 80(7) cm{sup −1}, respectively, which both agree within 5 cm{sup −1} with theoretical anharmonic scaling predictions based on density functional B3LYP/6-311g++(3df,3dp) calculations. Integrated band strengths for each of the CH stretch bands are analyzed, with the relative intensities agreeing remarkably well with theoretical predictions. Frequency comparison with previous low resolution Ar-matrix spectroscopy [A. V. Friderichsen et al., J. Am. Chem. Soc. 123, 1977 (2001)] reveals a nearly uniform Δν ≈ + 10-12 cm{sup −1} blue shift between gas phase and Ar matrix values for ν{sub 1} and ν{sub 2}. This differs substantially from the much smaller red shift (Δν ≈ − 1 cm{sup −1}) reported for the ν{sub 19} mode, and suggests a simple physical model in terms of vibrational mode symmetry and crowding due to the matrix environment. Finally, the infrared phenyl spectra are well described by a simple asymmetric rigid rotor Hamiltonian and show no evidence for spectral congestion due to intramolecular vibrational coupling, which bodes well for high resolution studies of other ring radicals and polycyclic aromatic hydrocarbons. In summary, the combination of slit jet discharge methods with high resolution infrared lasers enables spectroscopic investigation of even highly reactive combustion and interstellar radical intermediates under gas phase, jet-cooled

Comparative growth analysis of cool- and warm-season grasses in a cool-temperate environment

International Nuclear Information System (INIS)

Belesky, D.P.; Fedders, J.M.

1995-01-01

Using both cool-season (C3) and warm-season (C4) species is a viable means of optimizing herbage productivity over varying climatic conditions in temperate environments. Despite well-documented differences in water, N, and radiation use, no consistent evidence demonstrates productivity differences among C3 and C4 perennial grass species under identical management. A field study was conducted to determine relative growth rates (RGR), nitrogen productivity (NP), and mean radiation productivity (RP) (dry matter production as a function of incident radiation) of cool- and warm-season grasses managed identically. Results were used to identify management practices thd could lead to optimal productivity in combinations or mixtures of cool- and warm-season grasses. Dry matter yields of warm-season grasses equaled or surpassed those of cool-season grasses, despite a 40% shorter growth interval. Certain cool- and warm-season grasses appear to be suitable for use in mixtures, based on distribution of herbage production; however, actual compatibility may be altered by defoliation management. Relative growth rates varied among years and were about 40% lower for canopies clipped to a 10-cm residue height each time 20-cm of growth accumulated compared with other treatments. The RGR of warm-season grasses was twice that of cool-season grasses Nitrogen productivity (g DM g-1 N d -1) and mean radiation productivity (g DM MJ-1) for warm-season grasses was also more than twice that of cool-season grasses. Radiation productivity of cool-season grasses was dependent on N, while this was not always the case for warm-season grasses. The superior production capability of certain warm-season compared with cool-season grasses in a cool-temperate environment can be sustained under a range of defoliation treatments and demonstrates suitability for use in frequently defoliated situations

Development and test of an axial flux type PM synchronous motor with liquid nitrogen cooled HTS armature windings

International Nuclear Information System (INIS)

Sugimoto, H; Morishita, T; Tsuda, T; Takeda, T; Togawa, H; Oota, T; Ohmatsu, K; Yoshida, S

2008-01-01

We developed an axial gap permanent magnet type superconducting synchronous motor cooled by liquid nitrogen (LN 2 ). The motor includes 8 poles and 6 armature windings. The armature windings are made from BSCCO wire operated at the temperature level between 66K∼70K. The design of the rated output is 400kW at 250rpm. Because HTS wires produce AC loss, there are few motors developed with a superconducting armature winding. In a large capacity motor, HTS windings need to be connected in parallel way. However, the parallel connection causes different current flowing to each HTS winding. To solve this problem, we connected a current distributor to the motor. As a result, not only the current difference can be suppressed, but also the current of each winding can be adjusted freely. The low frequency and less flux penetrating HTS wire because of current distributor contribute to low AC loss. This motor is an axial gap rotating-field one, the cooling parts are fixed. This directly leads to simple cooling system. The motor is also brushless. This paper presents the structure, the analysis of the motor and the tests

Numerical simulation of draining and drying procedure for the ITER Generic Equatorial Port Plug cooling system

International Nuclear Information System (INIS)

Tanchuk, Victor; Grigoriev, Sergey; Lyublin, Boris; Maquet, Philippe; Senik, Konstantin; Pak, Sunil; Udintsev, Victor

2016-01-01

Highlights: • The cooling system of the ITER Generic Equatorial Port Plug (GEPP) is of a complicated combination of horizontal and vertical channels. • The calculation model for the entire GEPP cooling circuit comprising 12 sub-circuits and built up of 2421 finite-volume elements has been developed. • Transient analysis of this model simulating the draining procedure by the KORSAR/B1 code has been performed. • Water in amount of 263 g of initial 531 kg in the GEPP remains in the dead-ends of the DSM and DFW channels in 150 s of draining procedure. • Almost 3 h are required to boil off 263 g of water trapped in the dead-ends. - Abstract: For effective vacuum leak testing all cooling circuits serving the ITER vessel and in-vessel components shall be drained and dried so that after this procedure taking less than 100 h the purge gas passing through a component has water content less than 100 ppm. This process is four-stage, with the first stage using a short blast of compressed nitrogen to blow most of water in the coolant channels out of the circuit. This process is hindered by volumes which trap water due to gravity. To remove the trapped water, it is necessary, first, to heat up the structure by hot and compressed nitrogen, and then water is evaporated by depressurized nitrogen. The cooling system of the ITER Diagnostic Equatorial Port Plugs is of a complicated hydraulic configuration. The system branching might make difficult removal of water from the piping in the scheduled draining mode. The authors have proposed the KORSAR computation code to simulate draining of the GEPP cooling circuit. The numerical simulation performed has made it possible to describe the process dynamics during draining of the entire GEPP cooling circuit and to define the process time, amount and location of residual water and evolution of two-phase flow regime.

Numerical simulation of draining and drying procedure for the ITER Generic Equatorial Port Plug cooling system

Energy Technology Data Exchange (ETDEWEB)

Tanchuk, Victor, E-mail: Victor.Tanchuk@sintez.niiefa.spb.su [JSC “D.V. Efremov Institute of Electrophysical Apparatus”, 196641 St. Petersburg (Russian Federation); Grigoriev, Sergey; Lyublin, Boris [JSC “D.V. Efremov Institute of Electrophysical Apparatus”, 196641 St. Petersburg (Russian Federation); Maquet, Philippe [ITER Organization, Route de Vinon sur Verdon, 13115 St Paul-lez-Durance (France); Senik, Konstantin [JSC “D.V. Efremov Institute of Electrophysical Apparatus”, 196641 St. Petersburg (Russian Federation); Pak, Sunil [National Fusion Research Institute, Daejeon (Korea, Republic of); Udintsev, Victor [ITER Organization, Route de Vinon sur Verdon, 13115 St Paul-lez-Durance (France)

2016-11-01

Highlights: • The cooling system of the ITER Generic Equatorial Port Plug (GEPP) is of a complicated combination of horizontal and vertical channels. • The calculation model for the entire GEPP cooling circuit comprising 12 sub-circuits and built up of 2421 finite-volume elements has been developed. • Transient analysis of this model simulating the draining procedure by the KORSAR/B1 code has been performed. • Water in amount of 263 g of initial 531 kg in the GEPP remains in the dead-ends of the DSM and DFW channels in 150 s of draining procedure. • Almost 3 h are required to boil off 263 g of water trapped in the dead-ends. - Abstract: For effective vacuum leak testing all cooling circuits serving the ITER vessel and in-vessel components shall be drained and dried so that after this procedure taking less than 100 h the purge gas passing through a component has water content less than 100 ppm. This process is four-stage, with the first stage using a short blast of compressed nitrogen to blow most of water in the coolant channels out of the circuit. This process is hindered by volumes which trap water due to gravity. To remove the trapped water, it is necessary, first, to heat up the structure by hot and compressed nitrogen, and then water is evaporated by depressurized nitrogen. The cooling system of the ITER Diagnostic Equatorial Port Plugs is of a complicated hydraulic configuration. The system branching might make difficult removal of water from the piping in the scheduled draining mode. The authors have proposed the KORSAR computation code to simulate draining of the GEPP cooling circuit. The numerical simulation performed has made it possible to describe the process dynamics during draining of the entire GEPP cooling circuit and to define the process time, amount and location of residual water and evolution of two-phase flow regime.

Cryogenic system of steady state superconducting Tokamak SST-1: Operational experience and controls

International Nuclear Information System (INIS)

Sarkar, B.; Tank, Jignesh; Panchal, Pradip; Sahu, A.K.; Bhattacharya, Ritendra; Phadke, Gaurang; Gupta, N.C.; Gupta, Girish; Shah, Nitin; Shukla, Pawan; Singh, Manoj; Sonara, Dasarath; Sharma, Rajiv; Saradha, S.; Patel, J.C.; Saxena, Y.C.

2006-01-01

The cryogenic system of SST-1 consists of the helium cryogenic system and the nitrogen cryogenic system. The main components of the helium cryogenic system are (a) 1.3 kW helium refrigerator/liquefier (HRL) and (b) warm gas management system (WGM), where as, the nitrogen cryogenic system called as liquid nitrogen (LN 2 ) management system consists of storage tanks and a distribution system. The helium flow distribution and control to different sub-systems is achieved by the integrated flow distribution and control (IFDC) system. The HRL has been commissioned and operated for performing a single toroidal field coil test as well as for the first commissioning of SST-1 superconducting-magnets up to 68 K. Analysis of the results shows that the compressor and turbine parameters of the HRL, namely, the speed and pressure are very stable during operation of the HRL, confirming to the reliability in control of thermo-dynamic parameters of the system. The thermal shield of the SST-1 cryostat consists of ten different types of panels, which have been cooled down to the minimum temperature of 80 K and maintained during the first commissioning of SST-1. The operation and controls of the LN2 management system have been found to be as per the design consideration

A 5 tesla superconducting magnet and cryostats for an EPR/FMR spectrometer

NARCIS (Netherlands)

Reuvekamp, E.M.C.M.; Gerritsma, G.J.; ten Kate, Herman H.J.; van de Klundert, L.J.M.

1988-01-01

A description is given of the cryogenic part of an electron paramagnetic resonance (EPR)/ferromagnetic resonance (FMR) spectrometer using Ka-band (26.5-40 GHz) and U-band (40-60 GHz) frequencies for resonance measurements on large magnetic thin-films. The unit has two cryostats; the first has a

Short Nissl staining for incubated cryostat sections of the brain.

Science.gov (United States)

Lindroos, O F

1991-01-01

Nissl stain often binds poorly to cryostat sections which have been incubated in solutions of radiolabeled ligands. Such incubation is used in receptor autoradiography of the brain when using the in vitro method. We have developed a rapid (16 min) modification of Nissl staining for sections that bind stain poorly, e.g., incubated sections. The method stains well sections which cannot be stained with other rapid Nissl staining methods.

Simulation of the compressor-assisted triple-effect H{sub 2}O/LiBr absorption cooling cycles

Energy Technology Data Exchange (ETDEWEB)

Kim, Jin Soo; Ziegler, F. [Bavarian Center for Applied Energy Research, Garching (Germany); Lee, Huen [Korea Advanced Inst. of Science and Technology, Taejon (Korea). Dept. of Chemical Engineering

2002-03-01

The construction of a triple-effect absorption cooling machine using the lithium bromide-based working fluid is strongly limited by the corrosion problem caused by the high generator temperature. In this study four compressor-assisted H{sub 2}O/LiBr cooling cycles were suggested to solve the problem by lowering the generator temperature of the basic theoretical triple-effect cycle. Each cycle includes one compressor at a different state point to elevate the pressure of the refrigerant vapor up to a useful condensation temperature. Cycle simulations were carried out to investigate both a basic triple-effect cycle and four compressor-assisted cycles. All types of compressor-assisted cycles were found to be operable with a significantly lowered generator temperature. The temperature decrements increase with elevated compression ratios. This means that, if a part of energy input is changed from heat to mechanical energy, the machine can be operated in a favorable region of generator temperature not to cause corrosion problems. In order to obtain 40 K of generator temperature decrement (from 475.95 K) for all cycles, 3-5% of cooling capacity equivalent mechanical energies were required for operating the compressor. A great advantage of the investigated triple-effect cycles is that the conventionally used H{sub 2}O/LiBr solution can be used as a working fluid without the danger of corrosion or without integrating multiple solution circuits.(author)

Effect on C-axis transport properties of a critical state in Bi{sub 2}Sr{sub 2}CaCu{sub 2}O{sub 8}

Energy Technology Data Exchange (ETDEWEB)

Cho, J.H.; Maley, M.P.; Bulaevskii, L.N.

1995-12-31

At low temperatures, the c-axis transport properties of Bi{sub 2}Sr{sub 2}CaCu{sub 2}O{sub 8} single crystals depend strongly on the magnetic field history for fields applied along the c-axis, indicating the effect of a critical state in the ab direction. In this study, the authors report zero field cooled (ZFC), field cooled warming (FCW), and field cooled cooling (FCC) c-axis transport properties. In addition, they also report magnetic relaxation measurements on the same samples to identify the c-axis dissipation mechanism. They observe a relaxation of the c-axis resistivity that follows the relaxation of the flux profile across the ab plane. By identifying the irreversible temperature vs. magnetic field for H // c, they construct a phase diagram of vortex states. Finally, they will discuss the implication of the phase diagram and the features related to the transport properties of the Josephson-coupled system and the role of pancake vortices in highly two-dimensional superconductors.

Room temperature ferromagnetism and absorption red-shift in nitrogen-doped TiO{sub 2} nanoparticles

Energy Technology Data Exchange (ETDEWEB)

Gómez-Polo, C., E-mail: gpolo@unavarra.es [Departamento de Física, Universidad Pública de Navarra, Campus de Arrosadia, 31006 Pamplona (Spain); Larumbe, S. [Departamento de Física, Universidad Pública de Navarra, Campus de Arrosadia, 31006 Pamplona (Spain); Monge, M. [Departamento de Química, Universidad de la Rioja, Centro de Investigación en Síntesis Química (CISQ), Complejo Científico Tecnológico, 26006 Logroño (Spain)

2014-11-05

Highlights: • N-doped TiO{sub 2} anatase nanoparticles were obtained by sol–gel. • The nanoparticle size, controlled by the N doping, determines lattice parameters. • Correlation between room temperature ferromagnetism and absorption red-shift. • Oxygen vacancies reinforce both phenomena. • Metal transition impurities contribute to the room temperature ferromagnetism. - Abstract: In this work, room-temperature ferromagnetism and the red-shift of the optical absorption is analyzed in nitrogen doped TiO{sub 2} semiconductor nanoparticles. The nanoparticles were synthesized by the sol–gel method using urea as the nitrogen source. Titanium Tetraisopropoxide (TTIP) was employed as the alkoxyde precursor and dissolved in ethanol. The as prepared gels were dried and calcined in air at 300 °C. Additionally, post-annealing treatments under vacuum atmosphere were performed to modify the oxygen stoichiometry of the samples. The anatase lattice parameters, analyzed by means of powder X-ray diffractometry, depend on the nanometer grain size of the nanoparticles (increase and decrease, respectively, of the tetragonal a and c lattice parameters with respect to the bulk values). The diffuse reflectance ultraviolet–visible (UV–Vis) absorbance spectra show a clear red-shift as consequence of the nitrogen and the occurrence of intragap energy levels. The samples display ferromagnetic features at room temperature that are reinforced with the nitrogen content and after the post annealings in vacuum. The results indicate a clear correlation between the room temperature ferromagnetism and the shift of the absorbance spectrum. In both phenomena, oxygen vacancies (either induced by the nitrogen doping or by the post vacuum annealings) play a dominant role. However, we conclude the existence of very low concentration of diluted transition metal impurities that determine the room ferromagnetic response (bound magnetic polaron BMP model). The contraction of the c soft axis

Soil Carbon Storage and N{sub 2}O Emissions from Wheat Agroecosystems as Affected by Free-Air CO{sub 2} Enrichment (FACE) and Nitrogen Treatments. Annual Progress Report - Year 1: August 1, 1996 to July 31, 1997 [Final Report

Energy Technology Data Exchange (ETDEWEB)

Leavitt, S.W.; Matthias, A.; Thompson, T.L.

1999-02-17

Rising atmospheric CO{sub 2} concentrations have prompted concern about response of plants and crops to future elevated CO{sub 2} levels, and particularly the extent to which ecosystems will sequester carbon and thus impact the rate of rise of CO{sub 2} concentrations. Free-air CO{sub 2} enrichment (FACE) experimentation was used with wheat agroecosystems for two growing seasons to assess effects of CO{sub 2} and soil nitrogen. Over 20 researchers on this experiment variously examined plant production and grow yield, phenology, length of growing season, water-use efficiency, ecosystem productivity, below ground processes (root and microbial activity, carbon and nitrogen cycling), etc.

Performance of a conduction-cooled high-temperature superconducting bearing

International Nuclear Information System (INIS)

Strasik, M.; Hull, J.R.; Johnson, P.E.; Mittleider, J.; McCrary, K.E.; McIver, C.R.; Day, A.C.

2008-01-01

We report rotational loss measurements for a high-temperature superconducting (HTS) bearing whose cooling consists of a thermal conduction path to the cold head of a cryocooler. Losses have been measured for rotational rates up to 14,500 rpm at different HTS temperatures. The rotational losses decrease with decreasing HTS temperature. For temperatures that can be obtained in a liquid-nitrogen thermosiphon system, at a given speed and gap, the loss of the conduction-cooled HTS bearing is not significantly higher than the loss of a nearly identical HTS bearing cooled by flowing nitrogen from the thermosiphon

Assembly work and transport of JT-60SA cryostat base

International Nuclear Information System (INIS)

Okano, Fuminori; Masaki, Kei; Yagyu, Jun-ichi; Shibama, Yusuke; Sakasai, Akira; Miyo, Yasuhiko; Kaminaga, Atsushi; Nishiyama, Tomokazu; Suzuki, Sadaaki; Nakamura, Shigetoshi; Shibanuma, Kiyoshi

2013-11-01

Japan Atomic Energy Agency started to construct a fully superconducting tokamak experiment device, JT-60SA, to support the ITER since January, 2013 at the Fusion Research and Development Directorate in Naka, Japan. The JT-60SA will be constructed with enhancing the previous JT-60 infrastructures, in the JT-60 torus hall, where the ex-JT-60 machine was disassembled. The JT-60SA Cryostat Base, for base of the entire tokamak structure, were assembly as the first step of this construction. The Cryostat Base (CB, 250tons) is consists of 7 main components made of stainless steel, in 12 m diameter and 3 m height. The CB was built in the Spain and transported to the Naka site, via Hitachi port. After pre-assembly work including preliminary measurements and sole plate adjustments of its height/flatness, the JT-60SA CB was carefully set on the sole plate. JT-60SA CB was assembled with high accuracy by using a laser tracker. The CB was adjusted in the height and flatness against the assembly reference position and determined by the absolute coordinates. This report introduces the concrete result of assembly work and transport of JT-60SA CB. (author)

Thermo-mechanical tests on W7-X current lead flanges

International Nuclear Information System (INIS)

Dhard, Chandra Prakash; Rummel, Thomas; Zacharias, Daniel; Bykov, Victor; Moennich, Thomas; Buscher, Klaus-Peter

2013-01-01

Highlights: • There are significant mechanical loads on the cryostat and radial flanges for W7-X current leads. • These are due to evacuation of W7-X cryostat, cool-down of cold mass, electro-magnetic forces and self weight of leads. • The actual mechanical loads were reduced to simplify the experimental set-up. • The tests were carried out on mock-up flanges test assembly at ambient temperature and at 77 K. • The thermo-mechanical tests on W7-X current lead flanges validate the design and joints of these flanges to the leads. -- Abstract: Fourteen pieces of high temperature superconducting current leads (CL) arranged in seven pairs, will be installed on the outer vessel of Wendelstein 7-X (W7-X) stellarator. In order to support the CL, it is provided with two glass fiber reinforce plastic (GFRP) flanges, namely, the lower cryostat flange (CF) remaining at room temperature and upper radial flange (RF) at about 5 K. Both the flanges i.e. CF and RF experience high mechanical loads with respect to the CL, due to the evacuation of W7-X cryostat, cool-down of cold mass including the CL, electro-magnetic forces due to current and plasma operations and self weight of CL. In order to check the integrity of these flanges for such mechanical loads, thermo-mechanical tests were carried out on these flanges at room temperatures and at liquid nitrogen (LN2) temperatures. The details of test set-up, results and modeling are described in the paper

Preliminary thermal architecture of the X-IFU instrument dewar

Science.gov (United States)

Charles, Ivan; Daniel, Christophe; André, Jérome; Duband, Lionel; Duval, Jean-Marc; den Hartog, Roland; Mitsuda, Kazuhisa; Shinozaki, Keisuke; van Weers, Henk; Yamasaki, Noriko Y.

2016-07-01

The ESA Athena mission will implement 2 instruments to study the hot and energetic universe. The X-ray Integral Field Unit (X-IFU) will provide spatially resolved high resolution spectroscopy. This high energy resolution of 2.5 eV at 7 keV could be achieved thanks to TES (Transition Edge Sensor) detectors that need to be cooled to very low temperature. To obtain the required 50 mK temperature level, a careful design of the cryostat and of the cooling chain including different technologies in cascade is needed. The preliminary cryogenic architecture of the X-IFU instrument that fulfils the TES detector thermal requirements is described. In particular, the thermal design of the detector focal plane assembly (FPA), that uses three temperature stages (from 2 K to 50 mK) to limit the thermal loads on the lowest temperature stage, is described. The baseline cooling chain is based on European and Japanese mechanical coolers (Stirling, Pulse tube and Joule Thomson coolers) that precool a sub Kelvin cooler made of a 3He sorption cooler coupled with a small ADR (Adiabatic Demagnetization Refrigerator). Preliminary thermal budgets of the X-IFU cryostat are presented and discussed regarding cooling chain performances.

Series-produced Helium II Cryostats for the LHC Magnets Technical Choices, Industrialisation, Costs

CERN Document Server

Poncet, A

2008-01-01

Assembled in 8 continuous segments of approximately 2.7 km length each, the He II cryostats for the 1232 cryodipoles and 474 Short Straight Sections (SSS housing the quadrupoles) must fulfil tight technical requirements. They have been produced by industry in large series according to cost-effective industrial production methods to keep expenditure within the financial constraints of the project and assembled under contract at CERN. The specific technical requirements of the generic systems of the cryostat (vacuum, cryogenic, electrical distribution, magnet alignment) are briefly recalled, as well as the basic design choices leading to the definition of their components (vacuum vessels, thermal shielding, supporting systems). Early in the design process emphasis was placed on the feasibility of manufacturing techniques adequate for large series production of components, optimal tooling for time-effective assembly methods, and reliable quality assurance systems. An analytical review of the costs of the cryosta...

Deposition of tellurium films by decomposition of electrochemically-generated H{sub 2}Te: application to radiative cooling devices

Energy Technology Data Exchange (ETDEWEB)

Engelhard, T.; Jones, E.D.; Viney, I. [Coventry Univ. (United Kingdom). Centre for Data Storage Mater.; Mastai, Y.; Hodes, G. [Department of Materials and Interfaces, Weizmann Institute of Science, 76100, Rehovot (Israel)

2000-07-17

The preparation of homogenous, large area thin layers of tellurium on thin polyethylene foils is described. The tellurium was formed by room temperature decomposition of electrochemically generated H{sub 2}Te. Pre-treatment of the polyethylene substrates with KMnO{sub 4} to give a Mn-oxide layer was found to improve the Te adhesion and homogeneity. Optical characterization of the layers was performed using UV/VIS/NIR spectroscopy. Such coatings have favorable characteristics for use as solar radiation shields in radiative cooling devices. The simplicity of generation of the very unstable H{sub 2}Te was also exploited to demonstrate formation of size-quantized CdTe nanocrystals. (orig.)

Soil Carbon Storage and N(sub 2)O Emissions from Wheat Agroecosystems as Affected by Free-Air CO(sub 2) Enrichment (FACE) and Nitrogen Treatments. Annual Progress Report - Year 1: August 1, 1996 to July 31, 1997[Final Report]; FINAL

International Nuclear Information System (INIS)

Leavitt, S.W.; Matthias, A.; Thompson, T.L.

1999-01-01

Rising atmospheric CO(sub 2) concentrations have prompted concern about response of plants and crops to future elevated CO(sub 2) levels, and particularly the extent to which ecosystems will sequester carbon and thus impact the rate of rise of CO(sub 2) concentrations. Free-air CO(sub 2) enrichment (FACE) experimentation was used with wheat agroecosystems for two growing seasons to assess effects of CO(sub 2) and soil nitrogen. Over 20 researchers on this experiment variously examined plant production and grow yield, phenology, length of growing season, water-use efficiency, ecosystem productivity, below ground processes (root and microbial activity, carbon and nitrogen cycling), etc

Magnetocaloric properties of Eu{sub 1−x}La{sub x}TiO{sub 3} (0.01 ≤ x ≤ 0.2) for cryogenic magnetic cooling

Energy Technology Data Exchange (ETDEWEB)

Rubi, Km; Midya, A.; Mahendiran, R., E-mail: phyrm@nus.edu.sg [Physics Department, Faculty of Science, National University of Singapore, 2 Science Drive 3, Singapore, Singapore 117551 (Singapore); Maheswar Repaka, D. V.; Ramanujan, R. V. [School of Materials Science and Engineering, Nanyang Technological University, 50 Nanyang Avenue, Singapore, Singapore 639798 (Singapore)

2016-06-28

We report magnetic and magnetocaloric (MCE) properties of polycrystalline Eu{sub 1−x}La{sub x}TiO{sub 3} samples over a wide composition range (0.01 ≤ x ≤ 0.20). It is found that the ground state changes from antiferromagnetic for x = 0.01 (T{sub N} = 5.2 K) to ferromagnetic for x ≥ 0.03 and the ferromagnetic Curie temperature increases from T{sub C} = 5.7 K for x = 0.03 to T{sub C} = 7.9 K for x = 0.20. The x = 0.01 sample shows a large reversible isothermal magnetic entropy change of −ΔS{sub m} = 23 (41.5) J/kg K and adiabatic temperature change of ΔT{sub ad} = 9 (17.2) K around 6.7 K for a field change of μ{sub 0}ΔH = 2 (5) Tesla. Although the peak value of −ΔS{sub m} decreases as La content increases, it is impressive in x = 0.2(−ΔS{sub m} = 31.41 J/kg K at T = 7.5 K for μ{sub 0}ΔH = 5 T). The large value of MCE arises from suppression of the spin entropy associated with the localized moment (J = 7/2) of Eu{sup 2+}:4f{sup 7} ions. This large MCE over a wide compositional range suggests that the Eu{sub 1−x}La{sub x}TiO{sub 3} series could be useful for magnetic cooling below 40 K.

Correlative light and immuno-electron microscopy of retinal tissue cryostat sections

Science.gov (United States)

Burgoyne, Thomas; Lane, Amelia; Laughlin, William E.; Cheetham, Michael E.

2018-01-01

Correlative light-electron microscopy (CLEM) is a powerful technique allowing localisation of specific macromolecules within fluorescence microscopy (FM) images to be mapped onto corresponding high-resolution electron microscopy (EM) images. Existing methods are applicable to limited sample types and are technically challenging. Here we describe novel methods to perform CLEM and immuno-electron microscopy (iEM) on cryostat sections utilising the popular FM embedding solution, optimal cutting temperature (OCT) compound. Utilising these approaches, we have (i) identified the same phagosomes by FM and EM in the retinal pigment epithelium (RPE) of retinal tissue (ii) shown the correct localisation of rhodopsin on photoreceptor outer segment disc like-structures in iPSC derived optic cups and (iii) identified a novel interaction between peroxisomes and melanosomes as well as phagosomes in the RPE. These data show that cryostat sections allow easy characterisation of target macromolecule localisation within tissue samples, thus providing a substantial improvement over many conventional methods that are limited to cultured cells. As OCT embedding is routinely used for FM this provides an easily accessible and robust method for further analysis of existing samples by high resolution EM. PMID:29315318

Neutronic design for a 100MW{sub th} Small modular natural circulation lead or lead-alloy cooled fast reactors core

Energy Technology Data Exchange (ETDEWEB)

Chen, C.; Chen, H.; Zhang, H.; Chen, Z.; Zeng, Q., E-mail: shchshch@ustc.edu.cn, E-mail: hlchen1@ustc.edu.cn, E-mail: kulah@mail.ustc.edu.cn, E-mail: zchen214@mail.ustc.edu.cn, E-mail: zengqin@ustc.edu.cn [Univ. of Science and Technology of China, School of Nuclear Science and Technology, Hefei, Anhui (China)

2015-07-01

Lead or lead-alloy cooled fast reactor with good fuel proliferation and nuclear waste transmutation capability, as well as high security and economy, is a great potential for the development of fourth-generation nuclear energy systems. Small natural circulation reactor is an important technical route lead cooled fast reactors industrial applications, which has been chosen as one of the three reference technical for solution lead or lead-alloy cooled fast reactors by GIF lead-cooled fast reactor steering committee. The School of Nuclear Science and Technology of USTC proposed a small 100MW{sub th} natural circulation lead cooled fast reactor concept called SNCLFR-100 based realistic technology. This article describes the SNCLFR-100 reactor of the overall technical program, core physics calculation and analysis. The results show that: SNCLFR-100 with good neutronic and safety performance and relevant design parameters meet the security requirements with feasibility. (author)

Effects of dopants on the amorphous-to-fcc transition in Ge{sub 2}Sb{sub 2}Te{sub 5} thin films

Energy Technology Data Exchange (ETDEWEB)

Privitera, S. [R and D Department, Micro, Power, Analog (MPA) Group, STMicroelectronics, MP8, Stradale Primosole 50, 95121 Catania (Italy)]. E-mail: stefania.privitera@st.com; Rimini, E. [Istituto di Microelettronica e Microsistemi (IMM), Consiglio Nazionale delle Ricerche (CNR), Stradale Primosole 50, 95121 Catania (Italy); Bongiorno, C. [Istituto di Microelettronica e Microsistemi (IMM), Consiglio Nazionale delle Ricerche (CNR), Stradale Primosole 50, 95121 Catania (Italy); Pirovano, A. [FTM, Advanced R and D, NVMTD, STMicroelectronics, Via Olivetti 2, 20041, Agrate Brianza (Italy); Bez, R. [FTM, Advanced R and D, NVMTD, STMicroelectronics, Via Olivetti 2, 20041, Agrate Brianza (Italy)

2007-04-15

The amorphous-to-crystal transition has been studied through in situ resistance measurements in Ge{sub 2}Sb{sub 2}Te{sub 5} thin films doped by ion implantation with nitrogen, oxygen or fluorine at different concentrations. Enhancement of the thermal stability has been observed in O and N amorphous doped Ge{sub 2}Sb{sub 2}Te{sub 5}. Larger effects have been found in the case of nitrogen doping. On the contrary, doping with Fluorine produced a decrease in the crystallization temperature. The electrical properties have been related to the structural phase change through in situ transmission electron microscopy analysis. The comparison between undoped and doped Ge{sub 2}Sb{sub 2}Te{sub 5} shows that the introduction of oxygen or nitrogen modifies in a different way the kinetics of the amorphous-to-fcc transition and gives new insight on the effects of doping with light elements in GeSbTe alloys.

Bubble formation upon crystallization of high nitrogen iron base alloys

International Nuclear Information System (INIS)

Svyazhin, A.G.; Sivka, E.; Skuza, Z.

2000-01-01

A study is made into the conditions of nitrogen bubble formation during crystallization of unalloyed iron, alloys of Fe-O, Fe-O-S systems, steels 1Kh13, 0Kh18N9 and a two-phase Fe-11%Cr-1%Mo-0.2%V steel. It is revealed that the amount of bubbles in a high nitrogen steel casting increases with a degree of nitrogen supersaturation and decreases with a cooling rate growth and with a rise of surfactant concentration in the metal. In sound castings a nitrogen content can be increased due to a cooling rate growth, nitrogen dilution with inert gas, an increase of nitrogen pressure during crystallization as well as due to the introduction of such surfactants as sulphur, selenium, tellurium, tin [ru

Axions from cooling compact stars: pair-breaking processes

Energy Technology Data Exchange (ETDEWEB)

Keller, Jochen; Sedrakian, Armen [Frankfurt Univ. (Germany). Inst. fuer Theoretische Physik

2013-07-01

Once formed in a supernova explosion, a neutron star cools rapidly via neutrino emission during the first 10{sup 4}-10{sup 5} years of its life-time. Here we compute the axion emission rate from baryonic components of a star at temperatures below their respective critical temperatures T{sub c} for normal-superfluid phase transition. The axion production is driven by a charge neutral weak process, associated with Cooper pair breaking and recombination. The requirement that the axion cooling does not overshadow the neutrino cooling yields a lower bound on the axion decay constant f{sub a} > 6 x 10{sup 9} T{sup -1}{sub c9} GeV, with T{sub c9} = T{sub c}/10{sup 9} K. This translates into an upper bound on the axion mass m{sub a} < 10{sup -3} T{sub c9} eV.

Axions from cooling compact stars: Pair-breaking processes

Energy Technology Data Exchange (ETDEWEB)

Keller, Jochen [Institute for Theoretical Physics, J.W. Goethe-University, D-60438 Frankfurt am Main (Germany); Sedrakian, Armen, E-mail: sedrakian@th.physik.uni-frankfurt.de [Institute for Theoretical Physics, J.W. Goethe-University, D-60438 Frankfurt am Main (Germany)

2013-01-02

Once formed in a supernova explosion, a neutron star cools rapidly via neutrino emission during the first 10{sup 4}-10{sup 5} yr of its life-time. Here we compute the axion emission rate from baryonic components of a star at temperatures below their respective critical temperatures T{sub c} for normal-superfluid phase transition. The axion production is driven by a charge neutral weak process, associated with Cooper pair breaking and recombination. The requirement that the axion cooling does not overshadow the neutrino cooling puts a lower bound on the axion decay constant f{sub a}>6 Multiplication-Sign 10{sup 9}T{sub c9}{sup -1} GeV, with T{sub c9}=T{sub c}/10{sup 9} K. This translates into an upper bound on the axion mass m{sub a}<10{sup -3}T{sub c9} eV.

2001, the ATLAS Cryostat Odyssey

CERN Multimedia

2001-01-01

After a journey of several thousand kilometres, over sea and land, by canal and highway, the cryogenics barrel of the ATLAS electromagnetic calorimeter finally arrived at CERN last week. Installed in Hall 180, the cryogenics barrel of the ATLAS electromagnetic calorimeter will be fitted out to take the central superconducting solenoid and the electromagnetic calorimeter. On Monday 2 July, different French police units and EDF officials were once again keeping careful watch around the hairpin bends of the road twisting down from the Col de la Faucille: a special load weighing 100 tonnes, 7 metres high, 5.8 metres wide and 7.2 metres long was being brought down into the Pays de Gex to the Meyrin site of CERN. This time the destination was the ATLAS experiment. A huge blue tarpaulin cover concealed the cryogenics barrel of the experiment's liquid argon electromagnetic calorimeter. The cryostat consists of a vacuum chamber, a cylinder that is 5.5 metres in diameter, 7 metres long, and a concentric cold chamber ...

First signal from a broadband cryogenic preamplifier cooled by circulating liquid nitrogen in a 7 T Fourier transform ion cyclotron resonance mass spectrometer.

Science.gov (United States)

Choi, Myoung Choul; Lee, Jeong Min; Lee, Se Gyu; Choi, Sang Hwan; Choi, Yeon Suk; Lee, Kyung Jae; Kim, SeungYong; Kim, Hyun Sik; Stahl, Stefan

2012-12-18

Despite the outstanding performance of Fourier transform ion cyclotron/mass spectrometry (FTICR/MS), the complexity of the cellular proteome or natural compounds presents considerable challenges. Sensitivity is a key performance parameter of a FTICR mass spectrometer. By improving this parameter, the dynamic range of the instrument can be increased to improve the detection signal of low-abundance compounds or fragment ion peaks. In order to improve sensitivity, a cryogenic detection system was developed by the KBSI (Korean Basic Science Institute) in collaboration with Stahl-Electronics (Mettenheim, Germany). A simple, efficient liquid circulation cooling system was designed and a cryogenic preamplifier implemented inside a FTICR mass spectrometer. This cooling system circulates a cryoliquid from a Dewar to the "liquid circulation unit" through a CF flange to cool a copper block and a cryopreamplifier; the cooling medium is subsequently exhausted into the air. The cryopreamplifier can be operated over a very wide temperature range, from room temperature to low temperature environments (4.2 K). First, ion signals detected by the cryopreamplifier using a circulating liquid nitrogen cooling system were observed and showed a signal-to-noise ratio (S/N) about 130% better than that obtained at room temperature.

Progress in the development of Li{sub 2}ZrO{sub 3} and Li{sub 2}TiO{sub 3} pebbles

Energy Technology Data Exchange (ETDEWEB)

Lulewicz, J D; Roux, N [CEA Centre d` Etudes de Saclay, 91 - Gif-sur-Yvette (France)

1998-03-01

Li{sub 2}ZrO{sub 3} and Li{sub 2}TiO{sub 3} pebbles are being developed as ceramic breeder for the European Helium-cooled pebble bed DEMO blanket concept. Status is given of the fabrication work, and of the properties characteristics determination. (author)

Thermal and structural performance of a single tube support post for the Superconducting Super Collider dipole magnet cryostat

International Nuclear Information System (INIS)

Boroski, W.N.; Nicol, T.H.; Ruschman, M.K.; Schoo, C.J.

1993-07-01

The reentrant support post currently incorporated in the Superconducting Super Collider (SSC) dipole cryostat has been shown to meet the structural and thermal requirements of the cryostat, both in prototype magnet assemblies and through component testing. However, the reentrant post design has two major drawbacks: tight dimensional control on all components, and cost driven by these tolerance constraints and a complex assembly procedure. A single tube support post has been developed as an alternative to the reentrant post design. Several prototype assemblies have been fabricated and subjected to structural testing. Compressive, tensile, and bending forces were applied to each assembly with deflection measured at several locations. A prototype support post has also been thermally evaluated in a heat leak measurement facility. Heat load to 4.2 K was measured with the intermediate post intercept operating at various temperatures while thermometers positioned along the conductive path of the post mapped thermal gradients. Results from these measurements indicate the single tube support post meets the design criteria for the SSC dipole magnet cryostat support system

The effect of cooling and strain on martensitic transformation in Fe-Ni-Cr-Mn-Si alloy

International Nuclear Information System (INIS)

Park, Shin Hwa; Nam, Won Jong; Yoon, Man Son; Kang, Shin Wang; Lee, Dong Hyung

1991-01-01

In Fe-Ni-Cr-Mn-Si shape memory alloy, the effect of cooling methods and strain on the martensitic transformation was investigated. After the solution treatment at 900 deg C for 30 minutes, the specimens were air cooled, water cooled and quenched in liquid nitrogen. For air cooled specimens only austenite phase was detected, whereas austenite and ε-martensite phases were detected for specimens water cooled or quenched in liquid nitrogen. The amount of ε-martensite was increased with the cooling rate and strain. But the increasing rate of the amount of ε-martensite was decreased at 5% strain in air cooling and at 3% strain in water cooling, respectively. The occurrence of α-martensite was found at about 5% strain in air cooled specimens. For water cooled specimens it was found at about 3% strain. These strains almost coinceded with the strains at which the increasing rate of the amount of ε-martensite was changed. The occurrence of α-martensite in specimens quenched in liquid nitrogen was found less than 0.5% strain. (Author)

Permanent magnets prepared from Sm{sub 10.5}Fe{sub 88.5}Zr{sub 1.0}N{sub y} without homogenization

Energy Technology Data Exchange (ETDEWEB)

Gebel, B.; Kubis, M.; Mueller, K.-H. [Institut fuer Festkoerper- und Werkstofforschung Dresden e.V. (Germany). Inst. fuer Metallische Werkstoffe

1997-10-01

In as-cast Sm{sub 2}Fe{sub 17} the high amount of {alpha}-Fe caused by a peritectic reaction can be considerably reduced by a small addition of about 1 at% Zr. X-ray diffraction showed that as-cast Sm{sub 10.5}Fe{sub 88.5}Zr{sub 1.0} mainly consists of a phase with the Th{sub 2}Zn{sub 17}-type structure and SmFe{sub 3}. Non-homogenized Sm{sub 10.5}Fe{sub 88.5}Zr{sub 1.0} was milled and (i) annealed in vacuum or (ii) treated with a hydrogenation-disproportionation-desorp tion-recombination (HDDR) process. The annealed and subsequently nitrogenated powder is magnetically anisotropic and has a coercivity {mu}{sub 0J}H{sub C} up to 2.0 T and an energy product (BH){sub max} up to 136 kJ/m{sup 3}. HDDR-treated and nitrogenated powder is isotropic and exhibits values of {mu}{sub 0J}H{sub C} = 3.1 T and (BH){sub max} 103 kJ/m{sup 3}. Consequently, Sm{sub 10.5}Fe{sub 88.5}Zr{sub 1.0}N{sub y} (y {approx} 16) permanent magnets with very good properties can be prepared without the time-consuming homogenization procedure. (orig.). 11 refs.

The Role of Absorption Cooling for Reaching Sustainable Energy Systems

Energy Technology Data Exchange (ETDEWEB)

Lindmark, Susanne

2005-07-01

This thesis focuses on the role and potential of absorption cooling in future energy systems. Two types of energy systems are investigated: a district energy system based on waste incineration and a distributed energy system with natural gas as fuel. In both cases, low temperature waste heat is used as driving energy for the absorption cooling. The main focus is to evaluate the absorption technology in an environmental perspective, in terms of reduced CO{sub 2} emissions. Economic evaluations are also performed. The reduced electricity when using absorption cooling instead of compression cooling is quantified and expressed as an increased net electrical yield. The results show that absorption cooling is an environmentally friendly way to produce cooling as it reduces the use of electrically driven cooling in the energy system and therefore also reduces global CO{sub 2} emissions. In the small-scale trigeneration system the electricity use is lowered with 84 % as compared to cooling production with compression chillers only. The CO{sub 2} emissions can be lowered to 45 CO{sub 2}/MWh{sub c} by using recoverable waste heat as driving heat for absorption chillers. However, the most cost effective cooling solution in a district energy system is a combination between absorption and compression cooling technologies according to the study. Absorption chillers have the potential to be suitable bottoming cycles for power production in distributed systems. Net electrical yields over 55 % may be reached in some cases with gas motors and absorption chillers. This small-scale system for cogeneration of power and cooling shows electrical efficiencies comparable to large-scale power plants and may contribute to reducing peak electricity demand associated with the cooling demand.

Mechanical properties of partially meltable superconducting YBa/sub 2/Cu/sub 3/O/sub 7-x/

International Nuclear Information System (INIS)

Selvamanickam, V.; Salama, K.

1988-01-01

Partial melting has been suggested as a method for the processing of the high temperatures superconducting YBa/sub 2/Cu/sub 3/O/sub 7-x/ to improve the current carrying capacity in this material. The authors have investigated the possibility of using this method for the improvement of bulk mechanical properties in addition to those related to superconductivity. Four parameters, namely, oxygen annealing temperature, melting temperature, melting time and cooling rate are identified and studied. Each parameter is varied individually and its effects on microstructure and mechanical and superconducting properties are examined. The results indicate that the properties of superconducting YBa/sub 2/Cu/sub 3/O/sub 7-x/ can be improved significantly using the proper melting temperature, melting time, cooling rate and oxygen annealing temperature

Tracking nitrogen losses in a greenhouse crop rotation experiment in North China using the EU-Rotate{sub N} simulation model

Energy Technology Data Exchange (ETDEWEB)

Guo Ruiying [Ministry of Education Key Laboratory of Arid and Grassland Ecology, School of Life Sciences, Lanzhou University, No. 222 Tianshui Nanlu, Lanzhou 730000, Gansu Province (China); Nendel, Claas, E-mail: nendel@zalf.d [Institute for Landscape Systems Analysis, Leibniz-Center for Agricultural Landscape Research, Eberswalder Strasse 84, 15374 Muencheberg (Germany); Rahn, Clive [Warwick HRI, Wellesbourne CV35 9EF (United Kingdom); Jiang Chunguang; Chen Qing [College of Resources and Environmental Sciences, China Agricultural University, No. 2 Yuanmingyuan Xilu, Haidian, Beijing 100193 (China)

2010-06-15

Vegetable production in China is associated with high inputs of nitrogen, posing a risk of losses to the environment. Organic matter mineralisation is a considerable source of nitrogen (N) which is hard to quantify. In a two-year greenhouse cucumber experiment with different N treatments in North China, non-observed pathways of the N cycle were estimated using the EU-Rotate{sub N} simulation model. EU-Rotate{sub N} was calibrated against crop dry matter and soil moisture data to predict crop N uptake, soil mineral N contents, N mineralisation and N loss. Crop N uptake (Modelling Efficiencies (ME) between 0.80 and 0.92) and soil mineral N contents in different soil layers (ME between 0.24 and 0.74) were satisfactorily simulated by the model for all N treatments except for the traditional N management. The model predicted high N mineralisation rates and N leaching losses, suggesting that previously published estimates of N leaching for these production systems strongly underestimated the mineralisation of N from organic matter. - The EU-Rotate{sub N} model can satisfactorily simulate crop N uptake and N{sub min} dynamics in a typical greenhouse cucumber production system of North China

Pre-conceptual core design of a small modular fast reactor cooled by supercritical CO{sub 2}

Energy Technology Data Exchange (ETDEWEB)

Liu, Baolin; Cao, Liangzhi; Wu, Hongchun [School of Nuclear Science and Technology, Xi’an Jiaotong University, No 28, Xianning West Road, Xi’an 710049, Shaanxi (China); Yuan, Xianbao, E-mail: ztsbaby@163.com [School of Nuclear Science and Technology, Xi’an Jiaotong University, No 28, Xianning West Road, Xi’an 710049, Shaanxi (China); College of Mechanical & Power Engineering, China Three Gorges University, No 8, Daxue Road, Yichang 443002, Hubei (China); Wang, Kunpeng [Nuclear and Radiation Safety Center, PO Box 8088, Beijing 100082 (China)

2016-04-15

Abstracts: A Small Modular fast reactor cooled by Supercritical CO{sub 2} (SMoSC) is pre-conceptually designed through three-dimensional coupled neutronics/thermal-hydraulics analysis. The power rating of the SMoSC is designed to be 300 MW{sub th} to meet the energy demand of small electrical grids. The excellent thermal properties of supercritical CO{sub 2} (S-CO{sub 2}) are employed to obtain a high thermal efficiency of about 40% with an electric output of 120 MWe. MOX fuel is utilized in the core design to improve fuel efficiency. The tube-in-duct (TID) assembly is applied to get lower coolant volume fraction and reduce the positive coolant void reactivity. According to the coupled neutronics/thermal-hydraulics calculations, the coolant void reactivity is kept negative throughout the whole core life. With a specific power density of 9.6 kW/kg and an average discharge burnup of 70.1 GWd/tHM, the SmoSC can be operated for 20 Effective Full Power Years (EFPYs) without refueling.

Planning and production of a low cost cryostat for electrical characterization of materials; Planejamento e producao de um criostato de baixo custo para caracterizacao eletrica de materiais

Energy Technology Data Exchange (ETDEWEB)

Torsoni, G.B.; Carvalho, C.L.; Brito, G.A. [UNESP, Ilha Solteira, SP (Brazil). Dept. de Fisica e Quimica. Grupo de Vidros e Ceramicas

2010-07-01

The system BSCCO can show three main Bi{sub 2}Sr{sub 2}CuO, Bi{sub 2}Sr{sub 2}CaCu{sub 2}O and Bi{sub 2}Sr{sub 2}Ca{sub 2}Cu{sub 3}O with critical temperatures around 20 K, 80 K and 110 K, respectively. Therefore, it is fundamental to study these materials in details at lowest temperatures, with simple systems and low cost equipment. In this work was projected a cryogenic system with capacity to reach temperatures below the liquid nitrogen temperature (77 K). Based on thermodynamic principles, which is used with liquid nitrogen system, with the vacuum application and control, it has been achieved temperatures about 63 K (freezing nitrogen temperature) in the sample holder. With the availability of a large range temperature becomes possible to identify at least two superconducting phases as in system BSCCO, which also involves a cost/benefit ratio more favorable, avoiding the use of more expensive refrigerates as liquid helium. (author)

Effect of cooling rate on achieving thermodynamic equilibrium in uranium–plutonium mixed oxides

Energy Technology Data Exchange (ETDEWEB)

Vauchy, Romain, E-mail: romain.vauchy@cea.fr [CEA, DEN, DTEC, Marcoule, 30207, Bagnols-sur-Cèze (France); CEA, DEN, DEC, Cadarache, 13108, Saint-Paul-lez-Durance (France); Belin, Renaud C.; Robisson, Anne-Charlotte [CEA, DEN, DEC, Cadarache, 13108, Saint-Paul-lez-Durance (France); Hodaj, Fiqiri [Univ. Grenoble Alpes, SIMAP, F-38000, Grenoble (France); CNRS, Grenoble INP, SIMAP, F-38000, Grenoble (France)

2016-02-15

In situ X-ray diffraction was used to study the structural changes occurring in uranium–plutonium mixed oxides U{sub 1−y}Pu{sub y}O{sub 2−x} with y = 0.15; 0.28 and 0.45 during cooling from 1773 K to room-temperature under He + 5% H{sub 2} atmosphere. We compare the fastest and slowest cooling rates allowed by our apparatus i.e. 2 K s{sup −1} and 0.005 K s{sup −1}, respectively. The promptly cooled samples evidenced a phase separation whereas samples cooled slowly did not due to their complete oxidation in contact with the atmosphere during cooling. Besides the composition of the annealing gas mixture, the cooling rate plays a major role on the control of the Oxygen/Metal ratio (O/M) and then on the crystallographic properties of the U{sub 1−y}Pu{sub y}O{sub 2−x} uranium–plutonium mixed oxides.

Titanium dioxide use (TiO{sub 2}) in cement matrix as a photocatalyst of nitrogen oxides (NO{sub x}); Utilizacao de dioxido de titanio (TiO{sub 2}) em matriz cimenticia como fotocatalisador de oxidos de nitrogenio (NO{sub x})

Energy Technology Data Exchange (ETDEWEB)

Casagrande, C.A.; Hotza, D.; Repette, W.L.; Jochem, L.F., E-mail: cezar.acasa@gmail.com [Universidade Federal de Santa Catarina (UFSC), Florianopolis, SC (Brazil)

2012-07-01

The use of titanium dioxide (TiO{sub 2}) in the photodegradation of nitrogen oxides (NO{sub x}) is a technology that can contribute against to environmental pollution. This work shows the feasibility of using TiO{sub 2} in mortars for photocatalysis. The Degussa P25 titania were characterized chemically and physically, revealing that the sample consists of nanoparticles, but has become crowded. Tests Samples (TS) were manufactured with added titania and the NO{sub x} tests at 28, 60 and 120 days of age of TSs, showing that it was 3% capable of degrading 100% of the NO{sub x} gas flow. Proved that conditions like relative humidity, flow and radiation intensity are relevant when it comes to efficiency in photocatalysis, altering the efficiency by varying these conditions. The photocatalysis with titania in cement matrix was efficient in NO{sub x} degradation, presenting itself as a promising technique to control environmental pollution.

Cryodeposition of nitrogen gas on a surface cooled by helium II

International Nuclear Information System (INIS)

Dhuley, R. C.; Bosque, E. S.; Van Sciver, S. W.

2014-01-01

Catastrophic loss of beam tube vacuum in a superconducting particle accelerator can be simulated by sudden venting of a long high vacuum channel cooled on its outer surface by He II. The rapid rush of atmospheric air in such an event shows an interesting propagation effect, which is much slower than the shock wave that occurs with vacuum loss at ambient conditions. This is due to flash frosting/deposition of air on the cold walls of the channel. Hence to characterize the propagation as well as the associated heat transfer, it is first necessary to understand the deposition process. Here we attempt to model the growth of nitrogen frost layer on a cold plate in order to estimate its thickness with time. The deposition process can be divided into two regimes- free molecular and continuum. It is shown that in free molecular regime, the frost growth can be modeled reasonably well using cryopump theory and general heat transfer relations. The continuum regime is more complex to model, given the higher rate of gas incident on cryosurface causing a large heat load on helium bath and changing cryosurface temperature. Results from the continuum regime are discussed in the context of recent experiments performed in our laboratory

Cryodeposition of nitrogen gas on a surface cooled by helium II

Energy Technology Data Exchange (ETDEWEB)

Dhuley, R. C.; Bosque, E. S.; Van Sciver, S. W. [Cryogenics Group, National High Magnetic Field Laboratory, Tallahassee, FL 32310 USA and Mechanical Engineering Department, FAMU-FSU College of Engineering, Tallahassee, FL 32310 (United States)

2014-01-29

Catastrophic loss of beam tube vacuum in a superconducting particle accelerator can be simulated by sudden venting of a long high vacuum channel cooled on its outer surface by He II. The rapid rush of atmospheric air in such an event shows an interesting propagation effect, which is much slower than the shock wave that occurs with vacuum loss at ambient conditions. This is due to flash frosting/deposition of air on the cold walls of the channel. Hence to characterize the propagation as well as the associated heat transfer, it is first necessary to understand the deposition process. Here we attempt to model the growth of nitrogen frost layer on a cold plate in order to estimate its thickness with time. The deposition process can be divided into two regimes- free molecular and continuum. It is shown that in free molecular regime, the frost growth can be modeled reasonably well using cryopump theory and general heat transfer relations. The continuum regime is more complex to model, given the higher rate of gas incident on cryosurface causing a large heat load on helium bath and changing cryosurface temperature. Results from the continuum regime are discussed in the context of recent experiments performed in our laboratory.

Reactive nitrogen in the environment and its effect on climate change

International Nuclear Information System (INIS)

Erisman, J.W.; Bleeker, A.; Galloway, J.; Seitzinger, S.; Butterbach-Bahl, K.

2011-01-01

Humans have doubled levels of reactive nitrogen in circulation, largely as a result of fertilizer application and fossil fuel burning. This massive alteration of the nitrogen cycle affects climate, food security, energy security, human health and ecosystem services. Our estimates show that nitrogen currently leads to a net-cooling effect on climate with very high uncertainty. The many complex warming and cooling interactions between nitrogen and climate need to be better assessed, taking also into account the other effects of nitrogen on human health, environment and ecosystem services. Through improved nitrogen management substantial reductions in atmospheric greenhouse gas concentrations could be generated, also allowing for other co-benefits, including improving human health and improved provision of ecosystem services, for example clean air and water, and biodiversity.

Second generation superconducting super collider dipole magnet cryostat design

International Nuclear Information System (INIS)

Niemann, R.C.; Bossert, R.C.; Carson, J.A.; Engler, N.H.; Gonczy, J.D.; Larson, E.T.; Nicol, T.H.; Ohmori, T.

1988-12-01

The SSC Magnet Development Program is developing accelerator dipole magnets in successive iterations. The initial iteration is complete with six full length model magnets and a thermal model having been built and tested. This initial experience along with the evolving SSC Magnet System Requirements have resulted in the second generation magnet cryostat design. It is this configuration that will be employed for the near term ongoing magnetic, thermal, string and accelerated life testing and will be the design considered for Phase I; i.e., Technology Orientation, of the SSC Magnet Industrialization Program. 5 refs., 7 figs., 1 tab

Cooling process in separation devices of krypton gas

Energy Technology Data Exchange (ETDEWEB)

Kimura, S; Sugimoto, K

1975-06-11

To prevent entry of impurities into purified gases and to detect leaks of heat exchanger in a separation and recovering device of krypton gas by means of liquefaction and distillation, an intermediate refrigerant having the same or slightly higher boiling point than that of gas to be cooled is used between the gas to be cooled (process gas) and refrigerant (nitrogen), and the pressure of the gas to be cooled is controlled to have a pressure higher than the intermediate refrigerant to cool the gas to be cooled.

Fusion-driven sub-critical dual-cooled waste transmutation blanket: design and analysis

International Nuclear Information System (INIS)

Wang Weihua; Wu Yican; Ke Yan; Kang Zhicheng; Wang Hongyan; Huang Qunying

2003-01-01

The Fusion-Driven Sub-critical System (FDS) is one of the Chinese programs to be further developed for fusion application. Its Dual-cooled Waste Transmutation Blanket (DWTB), as one the most important part of the FDS is cooled by helium and liquid metal, and have the features of safety, tritium self-sustaining, high efficiency and feasibility. Its conceptual design has been finished. This paper is mainly involved with the basic structure design and thermal-hydraulics analysis of DWTB. On the basis of a three-dimensional (3-D) model of radial-toroidal sections of the segment box, thermal temperature gradients and structure analysis made with a comprehensive finite element method (FEM) have been performed with the computer code ANSYS5.7 and computational fluid dynamic finite element codes. The analysis refers to the steady-state operating condition of an outboard blanket segment. Furthermore, the mechanical loads due to coolant pressure in normal operating conditions have been also taken into account. All the above loads have been combined as an input for a FEM stress analysis and the resulting stress distribution has been evaluated. Finally, the structure design and Pb-17Li flow velocity has been optimized according to the calculations and analysis

The inverse perovskite nitrides (Sr{sub 3}N{sub 2/3-x})Sn, (Sr{sub 3}N{sub 2/3-x})Pb, and (Sr{sub 3}N)Sb. Flux crystal growth, crystal structures, and physical properties

Energy Technology Data Exchange (ETDEWEB)

Pathak, Manisha; Bobnar, Matej; Ormeci, Alim; Prots, Yurii; Hoehn, Peter [Chemische Metallkunde, Max-Planck-Institut fuer Chemische Physik fester Stoffe, Dresden (Germany); Stoiber, Dominik; Niewa, Rainer [Institut fuer Anorganische Chemie, Universitaet Stuttgart (Germany)

2018-02-15