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Sample records for strongly textured ti

  1. Investigation on the evolution of microstructure and texture of electroplated Ni–Ti composite coating by Rietveld method

    Energy Technology Data Exchange (ETDEWEB)

    Zhao, Yuantao, E-mail: zhaoyuantao@sjtu.edu.cn; Cai, Fei, E-mail: caifei32@126.com; Wang, Chengxi, E-mail: sjtucxw@sjtu.edu.cn; Chai, Ze, E-mail: zechaisjtu@163.com; Zhu, Kaiyuan, E-mail: xrd125@163.com; Xu, Zhou, E-mail: xuzhou@sjtu.edu.cn; Jiang, Chuanhai, E-mail: chjiang-sjtu@hotmail.com

    2015-10-30

    Highlights: • Ni–Ti composite coatings were prepared by electroplating. • Morphology and Ti content of Ni–Ti coatings were studied upon SEM and EDXS. • Microstructures of Ni–Ti coatings were studied upon the Rietveld method. • The texture of Ni–Ti coatings was studied upon the pole figure. - Abstract: Rietveld refinement was utilized to investigate the evolution of microstructure and texture of the Ni–Ti composite coatings electroplated at different applied current densities. Scanning Electron Microscope and Energy Dispersive Spectroscopy were utilized to investigate the morphology and chemical composition of the coatings. Relative texture coefficients (RTC) and measured pole figures were utilized to investigate the texture evolution of the coatings. The results showed that the surface morphology of the coatings changed from a colonial structure to a polyhedral one. And the incorporated Ti content decreased with increasing applied current density. As the applied current density increased, the crystallite sizes increased and their distribution got less uniform, and the microstrain and dislocation density decreased. The results of simulated pole figures obtained from Rietveld refinement illustrated that the texture of the coatings changed from no obvious texture to a strong [2 0 0] fiber texture with increasing applied current density. The texture evolution obtained from simulated pole figures was confirmed by the result of RTC and the measured pole figures. The evolutions of the microstructure and texture were derived from the change of the applied current density and incorporated Ti content in the Ni–Ti composite coatings.

  2. Texture memory and strain-texture mapping in a NiTi shape memory alloy

    International Nuclear Information System (INIS)

    Ye, B.; Majumdar, B. S.; Dutta, I.

    2007-01-01

    The authors report on the near-reversible strain hysteresis during thermal cycling of a polycrystalline NiTi shape memory alloy at a constant stress that is below the yield strength of the martensite. In situ neutron diffraction experiments are used to demonstrate that the strain hysteresis occurs due to a texture memory effect, where the martensite develops a texture when it is cooled under load from the austenite phase and is thereafter ''remembered.'' Further, the authors quantitatively relate the texture to the strain by developing a calculated strain-texture map or pole figure for the martensite phase, and indicate its applicability in other martensitic transformations

  3. HOS cell adhesion on Ti6Al4V ELI texturized by CO2 laser

    Science.gov (United States)

    Sandoval-Amador, A.; Bayona–Alvarez, Y. M.; Carreño Garcia, H.; Escobar-Rivero, P.; Y Peña-Ballesteros, D.

    2017-12-01

    In this work, the response of HOS cells on Ti6Al4V ELI textured surfaces by a CO2 laser was evaluated. The test surfaces were; smooth Ti6Al4V, used as the control, and four textured surfaces with linear geometry. These four surfaces had different separation distances between textured lines, D1 (1000 microns), D2 (750 microns), D3 (500 microns) and D4 (250 microns). Toxicity of textured surfaces was assessed by MTT and the cellular adhesion test was performed using HOS ATCC CRL 1543 line cells. This test was done after 5 days of culture in a RPMI 1640 medium supplemented with 10% fetal bovine serum and 1% antibiotics. The results showed that the linear textures present 23% toxicity after 30 days of incubation, nevertheless, the adhesion tests results are inconclusive in such conditions and therefore the effect of the line separation on the cell adhesion cannot be determined.

  4. Effect of Thermomechanical Processing on Texture and Superelasticity in Fe-Ni-Co-Al-Ti-B Alloy

    Science.gov (United States)

    Lee, Doyup; Omori, Toshihiro; Han, Kwangsik; Hayakawa, Yasuyuki; Kainuma, Ryosuke

    2018-03-01

    The texture and superelasticity were investigated in austenitic Fe-Ni-Co-Al-Ti-B alloy with various reduction ratios of cold rolling and heating ratios in annealing. The rolled sheets show the {110} deformation texture at a reduction ratio higher than 80%, while the texture hardly changes in the primary recrystallization at 1000 °C. The β (B2) precipitates inhibit the grain growth at this temperature, but they dissolve during heating, and secondary recrystallization occurs due to decreased pinning force at temperatures higher than 1100 °C, resulting in texture change to {210} . The recrystallization texture is more strongly developed when the reduction ratio and heating rate are high and slow, respectively. The 90% cold-rolled and slowly heated sheet shows the recrystallization texture and high fraction of low-angle boundaries. As a result, ductility and superelasticity can be drastically improved in the 90% cold-rolled sheet, although superelasticity was previously obtained only in thin sheets with 98.5% reduction.

  5. Mechanisms of texture evolution during annealing of Zr and Ti alloys

    International Nuclear Information System (INIS)

    Gerspacher, F.

    2007-12-01

    Zirconium and Titanium are hexagonal metals. Thus, they have a weaker symmetry than cubic metals, and a stronger crystalline anisotropy. Despite this strong anisotropy, the fundamental mechanisms of the texture evolution of these metals have not been deeply investigated yet. We studied here the texture and microstructure evolution during annealing after several conditions of deformation, and showed that: - slow texture change is expected in grain growth after severe rolling, because of oriented growth - rapid texture change after low reductions is due to oriented nucleation - transverse rolling gives rise to a correlation between orientation and stored energy in the deformed material, which also induces fast texture changes. These mechanisms have been explained on the basis of microstructure specificities. In addition, texture evolution during normal grain growth was studied and the use of modeling allowed to confirm some hypotheses made on boundary mobility anisotropy. The mechanisms of appearance of abnormal grain growth have also been clarified. (author)

  6. Grain Refinement and Texture Mitigation in Low Boron Containing TiAl-Alloys

    Science.gov (United States)

    Hecht, Ulrike; Witusiewicz, Victor T.

    2017-12-01

    Controlling the grain size and texture of lamellar TiAl-alloys is essential for well-balanced creep and fatigue properties. Excellent refinement and texture mitigation are achieved in aluminum lean alloys by low boron additions of 0.2 at.%. This amount is sufficient to promote in situ formation of ultrafine borides during the last stages of body centered cubic (BCC) solidification. The borides subsequently serve as nucleation sites for hexagonal close packed (HCP) during the BCC-HCP phase transformation. Bridgman solidification experiments with alloy Ti-43Al-8Nb-0.2C-0.2B were performed under a different growth velocity, i.e., cooling rate, to evaluate the HCP grain size distribution and texture. For slow-to-moderate cooling rates, about 65% of HCP grains are randomly oriented, despite the pronounced texture of the parent BCC phase resulting from directional solidification. For high cooling rates, obtained by quenching, texture mitigation is less pronounced. Only 28% of the HCP grains are randomly oriented, the majority being crystallographic variants of the Burgers orientation relationship.

  7. Optimum rolling ratio for obtaining {001} recrystallization texture in Ti-Nb-Al biomedical shape memory alloy.

    Science.gov (United States)

    Inamura, T; Shimizu, R; Kim, H Y; Miyazaki, S; Hosoda, H

    2016-04-01

    The rolling rate (r) dependence of textures was investigated in the Ti-26Nb-3Al (mol%) alloy to reveal the conditions required to form the {001} recrystallization texture, which is a desirable orientation for the β-titanium shape memory alloy. {001} was the dominant cold-rolling texture when r=90% and it was transferred to the recrystallization texture without forming {112}, which is detrimental for the isotropic mechanical properties of the rolled sheet. A further increase in r resulted in the formation of {112} in both rolling and recrystallization textures. Therefore, r should be controlled to form only the {001} rolling texture, because the {112} texture can overwhelm the {001} texture during recrystallization. Copyright © 2016 Elsevier B.V. All rights reserved.

  8. Texture development and anisotropic behaviour of a TI-44.2NI4.9CU (AT.%) shape memory alloy

    NARCIS (Netherlands)

    Zhao, L.

    1997-01-01

    The objective of this work was to determine the relationship between texture development and anisotropy of shape memory properties. A commercial Ti-45Ni-5Cu (at.%) shape memory alloy was selected. Textures were developed by controlling rolling parameters, such as rolling temperature, intermediate

  9. Surface passivation of nano-textured fluorescent SiC by atomic layer deposited TiO2

    DEFF Research Database (Denmark)

    Lu, Weifang; Ou, Yiyu; Jokubavicius, Valdas

    2016-01-01

    Nano-textured surfaces have played a key role in optoelectronic materials to enhance the light extraction efficiency. In this work, morphology and optical properties of nano-textured SiC covered with atomic layer deposited (ALD) TiO2 were investigated. In order to obtain a high quality surface...

  10. Evaluation of casting textures in Al/Al{sub 3}Ti platelet functionally graded material fabricated by a centrifugal solid-particle method

    Energy Technology Data Exchange (ETDEWEB)

    Watanabe, Y.; Eryu, H.; Yamamoto, T. [Dept. of Functional Machinery and Mechanics, Shinshu Univ., Ueda (Japan); Andiarwanto, S.; Miura, H. [Dept. of Mechanical Engineering and Intelligent Systems, The Univ. of Electro-Communications, Tokyo (Japan)

    2002-07-01

    In this study, crystal orientation of the Al matrix in Al/Al{sub 3}Ti FGMs fabricated by the centrifugal solid-particle method was investigated by using orientation image microscopy (OIM). It was found that strong orientation of the Al{sub 3}Ti platelets was developed in the FGM fabricated under large G number, which is the ratio of the centrifugal force to the gravity. Contrarily to the expectation, strong texture of the Al matrix was not developed in the FGM even by solidification under strong centrifugal force, Moreover, there exists no specific relationship of crystallographical orientation between Al matrix and Al{sub 3}Ti platelets. Therefore, it would be concluded that nucleation and growth of Al matrix grains keeping specific orientation relationship with the pre-existing solid platelets seem to be difficult under dynamic casting with centrifugal force. (orig.)

  11. Strong morphological and crystallographic texture and resulting yield strength anisotropy in selective laser melted tantalum

    International Nuclear Information System (INIS)

    Thijs, Lore; Montero Sistiaga, Maria Luz; Wauthle, Ruben; Xie, Qingge; Kruth, Jean-Pierre; Van Humbeeck, Jan

    2013-01-01

    Selective laser melting (SLM) makes use of a high energy density laser beam to melt successive layers of metallic powders in order to create functional parts. The energy density of the laser is high enough to melt refractory metals like Ta and produce mechanically sound parts. Furthermore, the localized heat input causes a strong directional cooling and solidification. Epitaxial growth due to partial remelting of the previous layer, competitive growth mechanism and a specific global direction of heat flow during SLM of Ta result in the formation of long columnar grains with a 〈1 1 1〉 preferential crystal orientation along the building direction. The microstructure was visualized using both optical and scanning electron microscopy equipped with electron backscattered diffraction and the global crystallographic texture was measured using X-ray diffraction. The thermal profile around the melt pool was modeled using a pragmatic model for SLM. Furthermore, rotation of the scanning direction between different layers was seen to promote the competitive growth. As a result, the texture strength increased to as large as 4.7 for rotating the scanning direction 90° every layer. By comparison of the yield strength measured by compression tests in different orientations and the averaged Taylor factor calculated using the viscoplastic self-consistent model, it was found that both the morphological and crystallographic texture observed in SLM Ta contribute to yield strength anisotropy

  12. Development of a strong Goss texture during annealing of a heavily rolled Al–0.3% Cu alloy

    DEFF Research Database (Denmark)

    Wakeel, Aneela; Huang, T.L.; Wu, G.L.

    2015-01-01

    The evolution of microstructure and texture during isochronal annealing of a heavily cold rolled Al–0.3% Cu alloy has been characterized using electron backscatter diffraction. It is found that the rolling texture of this alloy is dominated by the Brass component and that recrystallization during...... annealing leads to the formation of a pronounced Goss texture. It is suggested that the development of the strong Goss texture in Al–0.3% Cu is caused by preferred growth of Goss-oriented grains into the Brass-oriented matrix....

  13. Orientation dependent slip and twinning during compression and tension of strongly textured magnesium AZ31 alloy

    Energy Technology Data Exchange (ETDEWEB)

    Al-Samman, T., E-mail: al-samman@imm.rwth-aachen.de [Institut fuer Metallkunde und Metallphysik, RWTH Aachen, Kopernikusstr. 14, D-52064 Aachen (Germany); Li, X. [Institut fuer Metallkunde und Metallphysik, RWTH Aachen, Kopernikusstr. 14, D-52064 Aachen (Germany); Chowdhury, S. Ghosh [CSIR National Metallurgical Laboratory, MST Division, Jamshedpur 831007 (India)

    2010-06-15

    Over recent years there have been a remarkable number of studies dealing with compression of magnesium. A literature search, however, shows a noticeably less number of papers concerned with tension and a very few papers comparing both modes, systematically, in one study. The current investigation reports the anisotropic deformation behavior and concomitant texture and microstructure evolution investigated in uniaxial tension and compression tests in two sample directions performed on an extruded commercial magnesium alloy AZ31 at different Z conditions. For specimens with the loading direction parallel to the extrusion axis, the tension-compression strength anisotropy was pronounced at high Z conditions. Loading at 45{sup o} from the extrusion axis yielded a tension-compression strength behavior that was close to isotropic. During tensile loading along the extrusion direction the extrusion texture resists twinning and favors prismatic slip (contrary to compression). This renders the shape change maximum in the basal plane and equal to zero along the c-axis, which resulted in the orientation of individual grains remaining virtually intact during all tension tests at different Z conditions. For the other investigated sample direction, straining was accommodated along the c-axis, which was associated with a lattice rotation, and thus, a change of crystal orientation. Uniaxial compression at a low Z condition (400 deg. C/10{sup -4} s{sup -1}) yielded a desired texture degeneration, which was explained on the basis of a more homogeneous partitioning of slip systems that reduces anisotropy and enhanced dynamic recrystallization (DRX), which counteracts the strong deformation texture. The critical strains for the nucleation of DRX in tensiled specimens at the highest investigated Z condition (200 deg. C/10{sup -2} s{sup -1}) were found to range between 4% and 5.6%.

  14. Preparation of textured Bi3TiNbO9 ceramics

    International Nuclear Information System (INIS)

    Zhou Zhiyong; Cheng Baozhu; Li Yuchen; Dong Xianlin

    2007-01-01

    Single phase of textured Bi 3 TiNbO 9 (BTNO) ceramics were prepared by a two-step sintering method: synthesizing seed-crystal platelets by molten-salt method with oxide mixture as precursor and then sintering the platelets via hot-pressing method. Molten-salt-synthesized fine BTNO plate-like crystallines (∼400 nm) had an orientation degree of 0.42. After hot-pressed under different conditions, textured BTNO ceramics with different orientation degree were obtained and the orientation degree of textured BTNO ceramics increased with the applied pressure as well as the sintering temperature. X-ray diffraction (XRD) patterns of textured BTNO revealed that the face perpendicular to the hot-pressing axis (-perpendicular ) exhibits stronger (0 0 l) diffraction peaks, while the face parallel to the hot-pressing axis (-parallel ) shows stronger (0 2 0)/(2 0 0) and weaker (0 0 l) diffraction peaks, which also can be apparently observed from SEM images. Highly oriented BTNO with a degree of 0.78 was obtained under an applied pressure of 60 MPa at 1050 deg. C

  15. Effects of strong interactions between Ti and ceria on the structures of Ti/CeO2.

    Science.gov (United States)

    Yao, Xiao-Dan; Zhu, Kong-Jie; Teng, Bo-Tao; Yu, Cao-Ming; Zhang, Yun-Lei; Liu, Ya; Fan, Maohong; Wen, Xiao-Dong

    2016-11-30

    The effects of strong interactions between Ti and ceria on the structures of Ti/CeO 2 (111) are systematically investigated by density functional theory calculation. To our best knowledge, the adsorption energy of a Ti atom at the hollow site of CeO 2 is the highest value (-7.99 eV) reported in the literature compared with those of Au (-0.88--1.26 eV), Ag (-1.42 eV), Cu (-2.69 eV), Pd (-1.75 eV), Pt (-2.62 eV) and Sn (-3.68 eV). It is very interesting to find that Ti adatoms disperse at the hollow site of CeO 2 (111) to form surface TiO x species, instead of aggregating to form Ti metal clusters for the Ti-CeO 2 interactions that are much stronger than those of Ti-Ti ones. Ti adatoms are completely oxidized to Ti 4+ ions if they are monatomically dispersed on the next near hollow sites of CeO 2 (111) (xTi-NN-hollow); while Ti 3+ ions are observed when they locate at the near hollow sites (xTi-N-hollow). Due to the electronic repulsive effects among Ti 3+ ions, the adsorption energies of xTi-N-hollow are slightly weaker than those of xTi-NN-hollow. Simultaneously, the existence of unstable Ti 3+ ions on xTi-N-hollow also leads to the restructuring of xTi-N-hollow by surface O atoms of ceria transferring to the top of Ti 3+ ions, or oxidation by O 2 adsorption and dissociation. Both processes improve the stability of the xTi/CeO 2 system by Ti 3+ oxidation. Correspondingly, surface TiO 2 -like species form. This work sheds light into the structures of metal/CeO 2 catalysts with strong interactions between the metal and the ceria support.

  16. Effect of triangular texture on the tribological performance of die steel with TiN coatings under lubricated sliding condition

    Science.gov (United States)

    Chen, Ping; Xiang, Xin; Shao, Tianmin; La, Yingqian; Li, Junling

    2016-12-01

    The friction and wear of stamping die surface can affect the service life of stamping die and the quality of stamping products. Surface texturing and surface coating have been widely used to improve the tribological performance of mechanical components. This study experimentally investigated the effect of triangular surface texture on the friction and wear properties of the die steel substrate with TiN coatings under oil lubrication. TiN coatings were deposited on a die steel (50Cr) substrate through a multi-arc ion deposition system, and then triangular surface texturing was fabricated by a laser surface texturing. The friction and wear test was conducted by a UMT-3 pin-on-disk tribometer under different sliding speeds and different applied loads, respectively. The adhesion test was performed to evaluate the effectiveness of triangular texturing on the interfacial bonding strength between the TiN coating and the die steel substrate. Results show that the combination method of surface texturing process and surface coating process has excellent tribological properties (the lowest frictional coefficient and wear volume), compared with the single texturing process or the single coating process. The tribological performance is improved resulting from the high hardness and low elastic modulus of TiN coatings, and the generation of hydrodynamic pressure, function of micro-trap for wear debris and micro-reservoirs for lubricating oil of the triangular surface texture. In addition, the coating bonding strength of the texturing sample is 3.63 MPa, higher than that of the single coating sample (3.48 MPa), but the mechanisms remain to be further researched.

  17. Supercube grains leading to a strong cube texture and a broad grain size distribution after recrystallization

    DEFF Research Database (Denmark)

    Lin, F.X.; Zhang, Y. B.; Pantleon, W.

    2015-01-01

    growth rates. However, most other cube grains do not grow preferentially. Because of the few supercube grains, the grain size distribution after recrystallization is broad. Reasons for the higher growth rates of supercube grains are discussed, and are related to the local deformed microstructure.......This work revisits the classical subject of recrystallization of cold-rolled copper. Two characterization techniques are combined: three-dimensional X-ray diffraction using synchrotron X-rays, which is used to measure the growth kinetics of individual grains in situ, and electron backscatter...... diffraction, which is used for statistical analysis of the microstructural evolution. As the most striking result, the strong cube texture after recrystallization is found to be related to a few super large cube grains, which were named supercube grains. These few supercube grains become large due to higher...

  18. Early Stages of Microstructure and Texture Evolution during Beta Annealing of Ti-6Al-4V

    Science.gov (United States)

    Pilchak, A. L.; Sargent, G. A.; Semiatin, S. L.

    2018-03-01

    The early stages of microstructure evolution during annealing of Ti-6Al-4V in the beta phase field were established. For this purpose, a series of short-time heat treatments was performed using sheet samples that had a noticeable degree of alpha-phase microtexture in the as-received condition. Reconstruction of the beta-grain structure from electron-backscatter-diffraction measurements of the room-temperature alpha-phase texture revealed that microstructure evolution at short times was controlled not by general grain growth, but rather by nucleation-and-growth events analogous to discontinuous recrystallization. The nuclei comprised a small subset of beta grains that were highly misoriented relative to those comprising the principal texture component of the beta matrix. From a quantitative standpoint, the transformation kinetics were characterized by an Avrami exponent of approximately unity, thus suggestive of metadynamic recrystallization. The recrystallization process led to the weakening and eventual elimination of the initial beta texture through the growth of a population of highly misoriented grains.

  19. Initial growth and texture formation during reactive magnetron sputtering of TiN on Si(111)

    CERN Document Server

    Li, T Q; Tsuji, Y; Ohsawa, T; Komiyama, H

    2002-01-01

    The initial growth and texture formation mechanism of titanium nitride (TiN) films were investigated by depositing TiN films on (111) silicon substrates by using reactive magnetron sputtering of a Ti metallic target under a N sub 2 /Ar atmosphere, and then analyzing the films in detail by using transmission electron microscopy (TEM) and x-ray diffraction (XRD). Two power sources for the sputtering, dc and rf, were compared. At the initial growth stage, a continuous amorphous film containing randomly oriented nuclei was observed when the film thickness was about 3 nm. The nuclei grew and formed a polycrystalline layer when the film thickness was about 6 nm. As the film grew further, its orientation changed depending on the deposition conditions. For dc sputtering, the appearance of (111) or (200)-preferred orientations depended on the N sub 2 partial pressure, and the intensity of the preferred orientation increased with increasing film thickness. For rf sputtering, however, when the film thickness was small (...

  20. In situ observation of texture and microstructure evolution during rolling and globularization of Ti-6Al-4V

    KAUST Repository

    Warwick, Jonnathan L W

    2013-03-01

    The evolution of texture in β-annealed Ti-6Al-4V during α-β rolling and so-called recrystallization annealing has been examined using synchrotron X-ray diffraction and ex situ characterization. During rolling, the initial α (0 0 0 2) texture softens and the colony α becomes kinked. During globularization, the texture strengthens as highly strained (and hence misoriented) areas of the laths disappear and this strengthening continues once coarsening of the primary α becomes dominant. At shorter heat treatment times the αs laths that form on cooling do so with a range of variant-related orientations to the β, but at longer annealing times this αs takes on the orientation of the surrounding αp. The implications for the mechanical performance of macrozone-containing bimodal Ti-6Al-4V material are discussed. © 2012 Acta Materialia Inc. Published by Elsevier Ltd. All rights reserved.

  1. Unidirectionally Textured CaBi4Ti4O15 Ceramics by the Reactive Templated Grain Growth with an Extrusion

    Science.gov (United States)

    Takeuchi, Tsuguto; Tani, Toshihiko; Saito, Yasuyoshi

    2000-09-01

    Dense CaBi4Ti4O15 (CBT) ceramics with a unique texture were prepared by the reactive templated grain growth (RTGG) method using an extrusion technique. Plate-like Bi4Ti3O12 (BIT) particles, a reactive template for CBT, were mixed with other oxide and carbonate powders and unidirectionally aligned by extrusion. During sintering, oriented CBT grains were formed in situ topotaxially on the oriented BIT particles, and the templated grain growth and their densification eventually fabricated textured CBT ceramics. X-ray diffraction measurements and scanning electron microscopic observations revealed that the plate-like CBT grains were unidirectionally oriented parallel to the extruding direction without uniaxial alignment. Textured CBT ceramics poled in the extruding direction exhibited electromechanical coupling coefficients (k33) and piezoelectric coefficients (d33 and g33) more than two times as large as one of nontextured ceramics with the same composition.

  2. Nanostructured thin film formation on femtosecond laser-textured Ti-35Nb-xZr alloy for biomedical applications

    Energy Technology Data Exchange (ETDEWEB)

    Jeong, Yong-Hoon [Department of Dental Materials and Research Center of Nano-Interface Activation for Biomaterials, School of Dentistry, Chosun University, Gwangju (Korea, Republic of); Choe, Han-Cheol, E-mail: hcchoe@chosun.ac.kr [Department of Dental Materials and Research Center of Nano-Interface Activation for Biomaterials, School of Dentistry, Chosun University, Gwangju (Korea, Republic of); Brantley, William A. [Division of Restorative and Prosthetic Dentistry and Primary Care, College of Dentistry, Ohio State University, Columbus, OH (United States)

    2011-05-31

    The aim of this study was to investigate the nanostructured thin film formation on femtosecond (FS) laser-textured Ti-35Nb-xZr alloy for biomedical applications. The initial surface roughening treatment involved irradiation with the FS laser in ambient air. After FS laser texturing, nanotubes were formed on the alloy surface using a potentiostat and a 1 M H{sub 3}PO{sub 4} solution containing 0.8 wt.% NaF with an applied cell voltage of 10 V for 2 h. The surface phenomena were investigated by FE-SEM, EDS, XRD, XPS and a cell proliferation test. It was found that nanostructured Ti-35Nb-xZr alloys after FS laser texturing had a hybrid surface topography with micro and nano scale structures, which should provide very effective osseointegration.

  3. Comparison of the Electrochemical Behavior of Ti and Nanostructured Ti-Coated AISI 304 Stainless Steel in Strongly Acidic Solutions

    Science.gov (United States)

    Attarzadeh, Farid Reza; Elmkhah, Hassan; Fattah-Alhosseini, Arash

    2017-02-01

    In this study, the electrochemical behaviors of pure titanium (Ti) and nanostructured (NS) Ti-coated AISI 304 stainless steel (SS) in strongly acidic solutions of H2SO4 were investigated and compared. A type of physical vapor deposition method, cathodic arc evaporation, was applied to deposit NS Ti on 304 SS. Scanning electron microscope and X-ray diffraction were used to characterize surface coating morphology. Potentiodynamic polarization, electrochemical impedance spectroscopy, and Mott-Schottky (M-S) analysis were used to evaluate the passive behavior of the samples. Electrochemical measurements revealed that the passive behavior of NS Ti coating was better than that of pure Ti in 0.1 and 0.01 M H2SO4 solutions. M-S analysis indicated that the passive films behaved as n-type semiconductors in H2SO4 solutions and the deposition method did not affect the semiconducting type of passive films formed on the coated samples. In addition, this analysis showed that the NS Ti coating had lower donor densities. Finally, all electrochemical tests showed that the passive behavior of the Ti-coated samples was superior, mainly due to the formation of thicker, yet less defective passive films.

  4. Texture development and strain hysteresis in a NiTi shape-memory alloy during thermal cycling under load

    International Nuclear Information System (INIS)

    Ye, B.; Majumdar, B.S.; Dutta, I.

    2009-01-01

    Thermal cycling experiments were conducted on a NiTi shape-memory alloy at different constant applied stresses below the yield strength of the martensite. The mechanical strain response manifested as strain hysteresis loops, whose range was proportional to the applied stress. In situ neutron diffraction experiments show that the strain hysteresis occurs as a result of the establishment of a stress-dependent crystallographic texture of the martensite during the first cool-down from austenite, and thereafter repeated during thermal cycling under the same load. This texture is found to depend on the stress during the thermal cycling experiments. A strain-pole map is derived and shown to explain the observed texture during thermal cycling. The strain-pole methodology is shown to work with similar martensitic transformations in other material systems.

  5. Textural, structural and electrical properties of TiO2 nanoparticles using Brij 35 and P123 as surfactants

    Directory of Open Access Journals (Sweden)

    Dora Solís et al

    2008-01-01

    Full Text Available The effect of the use of the triblock copolymer Pluronic P123[(PEO20(PPO70(PEO20, Aldrich] and the non-ionic polyoxyethylene-lauryl ether Brij 35 as surfactants on the textural, structural and electrical properties of nanosized TiO2 is analyzed in this work. The as-obtained samples were thermally treated at 400 °C to eliminate the surfactant, promote dehydroxylation and crystallize the sample. The TiO2 samples were characterized by thermal analysis, N2 physisorption, x-ray diffraction analysis, micro-Raman spectroscopy and scanning electron microscopy. To evaluate the TiO2 electrical features, I–V data were obtained. The x-ray diffraction results show that in the chemical synthesis using surfactants, the crystallite size is smaller than that of the commercial sample. The Raman spectroscopy results clearly indicate that, when P123 is used, the anatase phase of TiO2 is obtained, whereas when Brij 35 is used a mixture of the anatase and brookite phases is obtained. The specific surface area and crystallite size of the TiO2 prepared as indicated above are higher and smaller, respectively, than the corresponding properties found in commercial TiO2. The I–V plot showed a nonlinear behavior of the nanosized TiO2. The samples obtained with P123 showed the best electrical conductivity.

  6. On the texture, phase and tensile properties of commercially pure Ti produced via selective laser melting assisted by static magnetic field.

    Science.gov (United States)

    Kang, Nan; Yuan, Hao; Coddet, Pierre; Ren, Zhongming; Bernage, Charles; Liao, Hanlin; Coddet, Christian

    2017-01-01

    Tensile strength and ductility of Selective Laser Melting (SLM) processed commercially pure Ti (CP-Ti) were simultaneous enhanced by preforming the melting/solidification processes under Static Magnetic Field (SMF). The effects of SMF on microstructure and tensile properties were examined. The SMF-SLMed CP-Ti sample presents a microstructure of fine acicular martensitic α'-Ti and lath-shaped α-Ti. Meanwhile, the texture structure of SLMed CP-Ti was eliminated after adding a SMF. The SMF-SLM process offers new avenues to ameliorate the microstructure and improve the mechanical properties of SLMed sample. Copyright © 2016 Elsevier B.V. All rights reserved.

  7. Surface Texture-Based Surface Treatments on Ti6Al4V Titanium Alloys for Tribological and Biological Applications: A Mini Review

    Directory of Open Access Journals (Sweden)

    Naiming Lin

    2018-03-01

    Full Text Available Surface texture (ST has been confirmed as an effective and economical surface treatment technique that can be applied to a great range of materials and presents growing interests in various engineering fields. Ti6Al4V which is the most frequently and successfully used titanium alloy has long been restricted in tribological-related operations due to the shortcomings of low surface hardness, high friction coefficient, and poor abrasive wear resistance. Ti6Al4V has benefited from surface texture-based surface treatments over the last decade. This review begins with a brief introduction, analysis approaches, and processing methods of surface texture. The specific applications of the surface texture-based surface treatments for improving surface performance of Ti6Al4V are thoroughly reviewed from the point of view of tribology and biology.

  8. Surface Texture-Based Surface Treatments on Ti6Al4V Titanium Alloys for Tribological and Biological Applications: A Mini Review.

    Science.gov (United States)

    Lin, Naiming; Li, Dali; Zou, Jiaojuan; Xie, Ruizhen; Wang, Zhihua; Tang, Bin

    2018-03-24

    Surface texture (ST) has been confirmed as an effective and economical surface treatment technique that can be applied to a great range of materials and presents growing interests in various engineering fields. Ti6Al4V which is the most frequently and successfully used titanium alloy has long been restricted in tribological-related operations due to the shortcomings of low surface hardness, high friction coefficient, and poor abrasive wear resistance. Ti6Al4V has benefited from surface texture-based surface treatments over the last decade. This review begins with a brief introduction, analysis approaches, and processing methods of surface texture. The specific applications of the surface texture-based surface treatments for improving surface performance of Ti6Al4V are thoroughly reviewed from the point of view of tribology and biology.

  9. Acoustoelastic effect of textured (Ba,Sr)TiO{sub 3} thin films under an initial mechanical stress

    Energy Technology Data Exchange (ETDEWEB)

    Kamel, Marwa; Mseddi, Souhir; Njeh, Anouar; Ben Ghozlen, Mohamed Hédi [Laboratoire de Physique des Matériaux, Faculté des Sciences de Sfax, Université de Sfax, Sfax (Tunisia); Donner, Wolfgang [Institute of Materials Science, University of Technology, Alarich-Weiss-Strasse.2, 64287 Darmstadt (Germany)

    2015-12-14

    Acoustoelastic (AE) analysis of initial stresses plays an important role as a nondestructive tool in current engineering. Two textured BST (Ba{sub 0.65}Sr{sub 0.35}TiO{sub 3}) thin films, with different substrate to target distance, were grown on Pt(111)/TiO{sub 2}/SiO{sub 2}/Si(001) substrate by rf-magnetron sputtering deposition techniques. A conventional “sin{sup 2} ψ” method to determine residual stress and strain in BST films by X-ray diffraction is applied. A laser acoustic waves (LA-waves) technique is used to generate surface acoustic waves (SAW) propagating in both samples. Young's modulus E and Poisson ratio ν of BST films in different propagation directions are derived from the measured dispersion curves. Estimation of effective second-order elastic constants of BST thin films in stressed states is served in SAW study. This paper presents an original investigation of AE effect in prestressed Ba{sub 0.65}Sr{sub 0.35}TiO{sub 3} films, where the effective elastic constants and the effect of texture on second and third order elastic tensor are considered and used. The propagation behavior of Rayleigh and Love waves in BST thin films under residual stress is explored and discussed. The guiding velocities affected by residual stresses, reveal some shifts which do not exceed four percent mainly in the low frequency range.

  10. Grain growth kinetics of textured-BaTiO3 ceramics

    Indian Academy of Sciences (India)

    Administrator

    TGG is one of the most convenient methods to prepare textured ceramics by sintering a green compact with matrix and template particles. Template often con- sidered being the key of TGG method, which usually chose anisotropic powders or small single crystals. BT- textured ceramics can also be fabricated by TGG method ...

  11. Highly stable colloidal TiO2 nanocrystals with strong violet-blue emission

    International Nuclear Information System (INIS)

    Ghamsari, Morteza Sasani; Gaeeni, Mohammad Reza; Han, Wooje; Park, Hyung-Ho

    2016-01-01

    Improved sol–gel method has been applied to prepare highly stable colloidal TiO 2 nanocrystals. The synthesized titania nanocrystals exhibit strong emission in the violet-blue wavelength region. Very long evolution time was obtained by preventing the sol to gel conversion with reflux process. FTIR, XRD, UV–vis absorption, photoluminescence and high resolution transmission electron microscope (HRTEM) were used to study the optical properties, crystalline phase, morphology, shape and size of prepared TiO 2 colloidal nanocrystals. HRTEM showed that the diameter of TiO 2 colloidal nanocrystals is about 5 nm. Although the PL spectra show similar spectral features upon excitation wavelengths at 280, 300 and 350 nm, but their emission intensities are significantly different from each other. Photoluminescence quantum yield for TiO 2 colloidal nanocrystals is estimated to be 49% with 280 nm excitation wavelength which is in agreement and better than reported before. Obtained results confirm that the prepared colloidal TiO 2 sample has enough potential for optoelectronics applications.

  12. The influence of surface nanoroughness, texture and chemistry of TiZr implant abutment on oral biofilm accumulation.

    Science.gov (United States)

    Xing, Rui; Lyngstadaas, Ståle P; Ellingsen, Jan Eirik; Taxt-Lamolle, Sébastien; Haugen, Håvard J

    2015-06-01

    The aim of the study was to examine surface nanoroughness, texture and chemistry of dental implant abutment and to investigate how these parameters influence oral biofilm formation in healthy subjects. Eight different nanorough TiZr surfaces were produced by polishing, machining, cathodic polarization and acid etching. Surface topography was examined using field emission scanning electron microscope and a blue light laser profilometer. Surface chemistry was analyzed by secondary ion mass spectrometry and X-ray photoelectron spectroscopy. Surface hydrophilicity was tested by measuring contact angle on the surfaces. A human in vivo study using a splint model was employed to evaluate oral biofilm accumulation on these surfaces. Different surface textures (flat, grooved and irregular) were created with nanoroughness from 29 to 214 nm. Some test surfaces were incorporated with hydrogen by cathodic polarization and/or acid etching with HCl/H(2)SO(4). Nanoroughness (S(a)) positively correlated with microbial adhesion. Biofilm accumulation was less pronounced on flat and grooved than on irregular surfaces. No significant association between hydrogen content or hydrophilicity of the surface and biofilm accumulation was observed. Nanoroughness (< 214 nm) and surface texture influence oral biofilm accumulation independent of surface chemistry and hydrophilicity. Surface hydrogen, which has previously been shown to promote fibroblast growth, does not affect biofilm formation. © 2014 John Wiley & Sons A/S. Published by John Wiley & Sons Ltd.

  13. Experimental investigation with respect to the performance of deep submillimeter-scaled textured tools in dry turning titanium alloy Ti-6Al-4V

    Science.gov (United States)

    Li, Ning; Chen, Yongjie; Kong, Dongdong; Tan, Shenglin

    2017-05-01

    Titanium alloy Ti-6Al-4V falls under the category of the most difficult to machine materials due to its inherent high strength maintained at elevated temperature and low thermal conductivity. Based on size effect, the poor machinability may be improved by surface texturing on the tools. Thus, the effect of deep submillimeter-scaled textures on the cutting performance in Ti-6Al-4V turning was investigated. To this end, three kinds of surface textures with different sizes were fabricated using femtosecond laser on rake faces of the uncoated cemented carbide (WC/Co) inserts. Then, dry cutting experiments were conducted with these textured inserts and conventional inserts under the condition of cutting speed Vc = 50m/min, depth of cut ap = 2 mm, and feed rate f = 0.3 mm/rev. The cutting performance is evaluated in terms of cutting forces, coefficient of friction at the tool-chip interface. Results obtained in this work show the feasibility of fabricating deep submillimeter-scaled textures on tool rake face to improve the machinability of Ti-6Al-4V. The parallel type of textured tool P01 demonstrates the best performance in both reducing cutting force and improving the friction properties on the rake face. This result can be explained by the reduced tool-chip contact area and the ploughing effect.

  14. Interpretation of zircon coronae textures from metapelitic granulites of the Ivrea–Verbano Zone, northern Italy: two-stage decomposition of Fe–Ti oxides

    OpenAIRE

    E. Kovaleva; E. Kovaleva; H. O. Austrheim; U. S. Klötzli

    2017-01-01

    In this study, we report the occurrence of zircon coronae textures in metapelitic granulites of the Ivrea–Verbano Zone. Unusual zircon textures are spatially associated with Fe–Ti oxides and occur as (1) vermicular-shaped aggregates 50–200 µm long and 5–20 µm thick and as (2) zircon coronae and fine-grained chains, hundreds of micrometers long and ≤ 1 µm thick, spatially associated with the larger zircon grains. Formation of such textures is a result of zircon precipitati...

  15. Interpretation of zircon corona textures from metapelitic granulites of Ivrea-Verbano Zone, Northern Italy: Two-stage decomposition of Fe-Ti oxides

    OpenAIRE

    Kovaleva, Elizaveta; Austrheim, Håkon; Klötzli, Urs

    2016-01-01

    In this study we report the occurrence of zircon corona textures in metapelitic granulites of the Ivrea-Verbano Zone. Unusual zircon textures are spatially associated with Fe-Ti oxides and occur as (1) vermicular-shaped aggregates 50–200 µm long and 5–20 µm thick, and as (2) zircon coronas and fine-grain chains, hundreds of µm long and ≤ 1 µm thick, spatially associated with (1). Formation of such textures is a result of mineral-fluid reactions, which o...

  16. Surface texture and specific adsorption sites of sol-gel synthesized anatase TiO{sub 2} nanoparticles

    Energy Technology Data Exchange (ETDEWEB)

    Zaki, Mohamed I., E-mail: mizaki@link.net [Chemistry Department, Faculty of Science, Minia University, El-Minia, 61519 (Egypt); Mekhemer, Gamal A.H.; Fouad, Nasr E. [Chemistry Department, Faculty of Science, Minia University, El-Minia, 61519 (Egypt); Jagadale, Tushar C. [Physical and Materials Chemistry Division, National Chemical Laboratory, Dr. Homi Bhabha Road, Pashan, Pune 411008 (India); Ogale, Satishchandra B., E-mail: sb.ogale@ncl.res.in [Physical and Materials Chemistry Division, National Chemical Laboratory, Dr. Homi Bhabha Road, Pashan, Pune 411008 (India)

    2010-10-15

    The surface properties of sol-gel synthesized anatase titania (TiO{sub 2}) nanoparticles are probed by sorptiometry, infrared absorption spectroscopy, UV-vis diffuse reflectance spectroscopy and high resolution transmission electron microscopy. The results reveal strong correlations of the surface area, porosity, pyridine adsorption capacity and strength, and catalytic methylbutynol decomposition activity.

  17. Improved performance of TiC-coated graphite limiters by surface texturing

    International Nuclear Information System (INIS)

    Whitley, J.B.; Mattox, D.M.; Trester, P.W.; Emerson, L.C.

    1983-01-01

    TicC-coated graphite limiters are currently in wide use as tokamak limiters. These limiters usually suffer a groove type of damage caused by plasma disruptions. A surface texturing treatment is described that reduces the occurrence of this type of damage

  18. Influence of laser parameters in surface texturing of Ti6Al4V and AA2024-T3 alloys

    Science.gov (United States)

    Ahuir-Torres, J. I.; Arenas, M. A.; Perrie, W.; de Damborenea, J.

    2018-04-01

    Laser texturing can be used for surface modification of metallic alloys in order to improve their properties under service conditions. The generation of textures is determined by the relationship between the laser processing parameters and the physicochemical properties of the alloy to be modified. In the present work the basic mechanism of dimple generation is studied in two alloys of technological interest, titanium alloy Ti6Al4V and aluminium alloy AA2024-T3. Laser treatment was performed using a pulsed solid state Nd: Vanadate (Nd: YVO4) laser with a pulse duration of 10 ps, operating at a wavelength of 1064 nm and 5 kHz repetition rate. Dimpled surface geometries were generated through ultrafast laser ablation while varying pulse energy between 1 μJ and 20 μJ/pulse and with pulse numbers from 10 to 200 pulses per spot. In addition, the generation of Laser Induced Periodic Surface Structures (LIPSS) nanostructures in both alloys, as well as the formation of random nanostructures in the impact zones are discussed.

  19. Grain growth kinetics of textured-BaTiO3 ceramics

    Indian Academy of Sciences (India)

    Administrator

    2Functional Materials Research Laboratory, Tongji University, Shanghai 200092, China .... Fang Fu et al. 782. Figure 3. SEM images of BT-textured ceramics sintered at 1250 °C for (a) 0 h, (b) 1 h,. (c) 2 h, (d) 5 h, (e) 10 h and (f) 20 h. matrix grains almost disappeared in this ..... Ding X Y, Shen B and Zhai J W 2009 J. Chin.

  20. Studies of laser textured Ti-6Al-4V wettability for implants

    Science.gov (United States)

    Kumar, N.; Prakash, S.; Kumar, S.

    2016-09-01

    Wettability plays a notable role in success of any bio-implant. It influences tissue amalgamation, protein adsorption and cell attachment at the surface of an implant. Hence, wettability enhancement of the implant is a field of today's dynamic research. In this work, laser based direct melting approach was employed to generate four separate surface patterns on Ti-6Al-4V by means of nanosecond pulse fibre laser. The modification of surface morphology was assessed by means of SEM. Wettability was measured by the help of goniometer. The obtained results revealed that pulsed laser irradiation can substantially improve the biocompatibility of Ti-6AL-4V by making its surface super hydrophilic.

  1. Growth and characterization of textured YBaCo2O5+δ thin films grown on (001)-SrTiO3 via DC magnetron sputtering

    International Nuclear Information System (INIS)

    Galeano, V.; Arnache, O.; Supelano, I.; Vargas, C.A. Parra; Morán, O.

    2016-01-01

    Thin films of the layered cobaltite YBaCo 2 O 5+δ were successfully grown on (001)-oriented SrTiO 3 single-crystal substrates by means of DC magnetron sputtering. The 112 phase of the compound was stabilized by choosing an adequate Co reactant and through careful thermal treatment of the target. The results demonstrate the strong influence of these variables on the final phase of the compound. A substrate temperature of 1053 K and an oxygen pressure of 300 Pa seemed to be appropriate growing conditions for depositing (00ℓ)-textured YBaCo 2 O 5+δ thin films onto the chosen substrate. In like fashion to the polycrystalline YBaCo 2 O 5+δ , the films showed a clear sequence of antiferromagnetic–ferromagnetic–paramagnetic transitions within a narrow temperature range. Well-defined hysteresis loops were observed at temperatures as high as 270 K, which supports the existence of a FM order in the films. In turn, the dependence of the resistivity on the temperature shows a semiconductor-like behavior, without any distinguishable structure, within the temperature range measured (50–350 K). The analysis of the experimental data showed that the transport mechanism in the films is well described by using the Mott variable range hopping (VRH) conduction model. - Highlights: • YBaCo 2 O 5+δ thin films are grown on SrTiO 3 substrates. • Strong (00ℓ) reflections are observed in the X-ray diffraction pattern. • A clear sequence of magnetic transitions is observed. • Semiconducting-like behavior is verified.

  2. Yttrium deposition on mesoporous TiO2: textural design and UV ...

    Indian Academy of Sciences (India)

    as to the yttrium dopant; (ii) the inclusion of tubular instead of ink-bottle pores facilitates the transport of organic species in and out of the pore structure. The most active mesoporous substrate resulted to be made of 2wt% Y; contrastingly, when Y=8 wt%, photoinactivity arose because of Y2Ti2O7 formation. The involvement ...

  3. Strong efficiency improvement in dye-sensitized solar cells by novel multi-dimensional TiO2 photoelectrode

    Science.gov (United States)

    Zhao, Fengyang; Ma, Rong; Jiang, Yongjian

    2018-03-01

    Titanium dioxide (TiO2) based dye-sensitized solar cells (DSSCs) often exhibit superior power conversion performance. Here we report a DSSC with novel hierarchical TiO2 composite structure (TCS) composed of anatase TiO2 micro-spheres and rutile TiO2 nanobelt framework by hydrothermal approach for high-performance. As photoanode, the TCS based DSSC shows a strong efficiency enhancement by 58% compared with Degussa TiO2 (P25)-DSSC (4.33%). The excellent performance is mainly attribute to its special multi-dimensional structures of TiO2: much active sites of 0D nanoparticle with exposed excellent {001} facet, special electronic transmission channel of 1D nanobelt, good dye adsorption capacity of 2D nanosheet and high light scattering ability of 3D micro-spheres. The novel multi-dimensional TCS materials will open up a new avenue to the electronic devices fields.

  4. Planar irregularities of texture and stress field in Ti detected by X-ray diffraction technique

    Science.gov (United States)

    Tarkowski, L.; Bonarski, J.; Alexandrov, I.

    2010-02-01

    Regardless of the origin of structure irregularities of materials, the recognition of their spatial distribution in a sample or constructing elements is a great research problem. One of the most effective and non-destructive tools used for this purpose is the X-ray diffraction technique, assisted by an appropriate experimental method and data processing. The work presents the results of investigations of planar distribution of crystallographic texture and stress irregularities manifested by changes of diffraction effects registered by the X-ray technique. As an example, the introduced method is tested on a titanium rod after severe plastic deformation process.

  5. Growth of TiO2 thin films on chemically textured Si for solar cell applications as a hole-blocking and antireflection layer

    Science.gov (United States)

    Singh, Ranveer; Kumar, Mohit; Saini, Mahesh; Singh, Avanendra; Satpati, Biswarup; Som, Tapobrata

    2017-10-01

    In this work, we investigate the broad-band photoabsorption of an n-TiO2 thin film and its hole-blocking properties when a heterostructure is grown on a chemically textured p-Si substrate. We demonstrate that average specular reflectance of conformally grown TiO2 thin films on chemically prepared pyramidally textured Si substrates can be brought down to ∼0.2% (in the wavelength range of 300-1200 nm), which increases up to ∼0.53% after annealing at 673 K in air for 1 h. X-ray diffraction data reveal the amorphous nature of as-grown TiO2 thin films which undergoes a transition to a crystalline one after annealing. In addition, bulk current-voltage characteristics show that the leakage current increases after annealing which corroborates well a with change in the band gap, as is measured from the optical absorption spectra, due to a transition from amorphous to crystalline (anatase phase) of TiO2. Moreover, TiO2/Si heterojunction allows the transport of electrons but blocks the transport of holes. The present results are not only important for the fundamental understanding of the charge transport across TiO2/Si heterostructures but also to design hole-blocking solar cells.

  6. Effect of micro/nano-scale textures on anti-adhesive wear properties of WC/Co-based TiAlN coated tools in AISI 316 austenitic stainless steel cutting

    Science.gov (United States)

    Zhang, Kedong; Deng, Jianxin; Sun, Jialin; Jiang, Chao; Liu, Yayun; Chen, Shuai

    2015-11-01

    In cutting of stainless steel with coated tool, the steel chip adhering to tool surface is usually severe and consequently causes serious adhesive and frictional problems, which is the major reason for the failure of coated tool. To solve the problem, a surface engineering approach, namely, a highly functionalization of tool surfaces by textures may be of great importance. Thus, the effect of micro/nano-scale textures on anti-adhesive wear properties of TiAlN coated tools in AISI 316 austenitic stainless steel cutting was investigated. For this purpose, two types of surface textures were fabricated on the rake faces of WC/Co carbide tools: (i) micro-scale textures fabricated by Nd:YAG laser, (ii) micro/nano-scales textures fabricated by Nd:YAG laser and femtosecond laser. Then, these textured tools were deposited with TiAlN coatings using cathode arc-evaporation technique. Wet cutting experiments were carried out with the micro-scale textured coated tool (MCT), micro/nano-scale textured coated tool (MNCT), and the conventional coated tool (CCT). Results obtained in this work demonstrated the feasibility of fabricating micro- or micro/nano-scale textures on tools substrate surfaces to improve the anti-adhesive wear properties of TiAlN coated tool. The rake face micro/nano-scale textured tool was the most effective. Moreover, mechanisms for the anti-adhesive properties enhancement were proposed.

  7. Ti(IV)-doped γ-Fe2O3 nanoparticles possessing unique textural and chemical properties: Enhanced suppression of phase transformation and promising catalytic activity

    Science.gov (United States)

    Khaleel, Abbas; Parvin, Maliha; AlTabaji, Moahmmed; Al-zamly, Ahmed

    2018-03-01

    Nanostructured Ti(IV)-doped γ-Fe2O3 was prepared via a sol-gel method, and the effect of doping on the phase stability, textural properties, and catalytic activity was investigated. Well-dispersed 10% Ti in γ-Fe2O3 structure was found to significantly suppress its conversion to α-Fe2O3. While undoped product contained both phases, γ- and α-Fe2O3, at 400 °C, its doped counterpart contained γ-Fe2O3 as the sole phase at temperatures as high as 500 °C and partial conversion started only at 550 °C. Doping also resulted in modified textural properties, including smaller particles, larger surface areas, and higher mesoporosity, as well as enhanced reducibility and catalytic activity.

  8. Highly controlled orientation of CaBi4Ti4O15 using a strong magnetic field

    Science.gov (United States)

    Suzuki, Tohru S.; Kimura, Masahiko; Shiratsuyu, Kosuke; Ando, Akira; Sakka, Yoshio; Sakabe, Yukio

    2006-09-01

    The texture of feeble magnetic ceramics can be controlled by a strong magnetic field. When the magnetic susceptibility of the c axis is smaller than that of the other axes, the c axis aligns perpendicular to the magnetic field; however, the direction is randomly oriented on the plane perpendicular to the magnetic field. The authors demonstrate in this letter that a highly controlled texture in bismuth titanate, which has a c-axis susceptibility smaller than the other axes, can be achieved using a two-step magnetic field procedure. This highly controlled orientation is effective for improving the electromechanical coupling coefficient.

  9. Texture evolution during isothermal, isostrain, and isobaric loading of polycrystalline shape memory NiTi

    Science.gov (United States)

    Nicholson, D. E.; Padula, S. A.; Benafan, O.; Vaidyanathan, R.

    2017-06-01

    In situ neutron diffraction was used to provide insights into martensite variant microstructures during isothermal, isobaric, and isostrain loading in shape memory NiTi. The results show that variant microstructures were equivalent for the corresponding strain, and more importantly, the reversibility and equivalency were immediately evident in variant microstructures that were first formed isobarically but then reoriented to near random self-accommodated microstructures following isothermal deformation. Variant microstructures formed isothermally were not significantly affected by a subsequent thermal cycle under constant strain. In all loading cases considered, the resulting variant microstructure correlated with strain and did not correlate with stress. Based on the ability to select a variant microstructure for a given strain despite thermomechanical loading history, the results demonstrated here can be obtained by following any sequence of thermomechanical loading paths over multiple cycles. Thus, for training shape memory alloys (repeating thermomechanical cycling to obtain the desired variant microstructure), optimal paths can be selected so as to minimize the number of training cycles required, thereby increasing the overall stability and fatigue life of these alloys in actuator or medical applications.

  10. Alternating and direct current field effects on the structure-property relationships in Na{sub 0.5}Bi{sub 0.5}TiO{sub 3}-x%BaTiO{sub 3} textured ceramics

    Energy Technology Data Exchange (ETDEWEB)

    Ge, Wenwei; Li, Jiefang; Viehland, D. [Department of Materials Science and Engineering, Virginia Tech, Blacksburg, Virginia 24061 (United States); Maurya, Deepam; Priya, Shashank [Center for Energy Harvesting Materials and Systems (CEHMS), Bio-Inspired Materials and Devices Laboratory (BMDL), Virginia Tech, Blacksburg, Virginia 24061 (United States)

    2013-06-03

    The influence of alternating (ac) and direct current (dc) fields on the structural and dielectric properties of [001]{sub PC} textured Na{sub 0.5}Bi{sub 0.5}TiO{sub 3}-7%BaTiO{sub 3} (NBT-7%BT) ceramics has been investigated. X-ray diffraction measurements revealed that the depolarization at temperature T{sub d} in poled samples resulted from a tetragonal {yields} pseudo-cubic transition on heating. Moderate ac drive and dc bias had opposite influences on T{sub d}: ac drive decreased the T{sub d}, whereas dc bias increased it. These investigations suggested an effective method to expand the working temperature range of NBT-x%BT textured ceramics to a high temperature.

  11. Interfacial reaction pathways and kinetics during annealing of 111-textured Al/TiN bilayers: A synchrotron x-ray diffraction and transmission electron microscopy study

    International Nuclear Information System (INIS)

    Chun, J.-S.; Desjardins, P.; Lavoie, C.; Petrov, I.; Cabral, C. Jr.; Greene, J. E.

    2001-01-01

    Growth of TiN layers in most diffusion-barrier applications is limited to deposition temperatures T s s =450 deg. C on SiO 2 by ultrahigh vacuum reactive magnetron sputter deposition in pure N 2 . Al overlayers, 160 nm thick with inherited 111 preferred orientation, were then deposited at T s =100 deg. C without breaking vacuum. The as-deposited TiN layer is underdense due to the low deposition temperature (T s /T m ≅0.23 in which T m is the melting point) resulting in kinetically limited adatom mobilities leading to atomic shadowing which, in turn, results in a columnar microstructure with both inter- and intracolumnar voids. The Al overlayer is fully dense. Synchrotron x-ray diffraction was used to follow interfacial reaction kinetics during postdeposition annealing of the 111-textured Al/TiN bilayers as a function of time (t a =12-1200 s) and temperature (T a =440-550 deg. C). Changes in bilayer microstructure and microchemistry were investigated using transmission electron microscopy (TEM) and scanning TEM to obtain compositional maps of plan-view and cross-sectional specimens. Interfacial reaction during annealing is initiated at the Al/TiN interface. Al diffuses rapidly into TiN voids during anneals at temperatures ∼ 3 Ti at the interface. Al 3 Ti exhibits a relatively planar growth front extending toward the Al free surface. Analyses of time-dependent x-ray diffraction peak intensities during isothermal annealing as a function of temperature show that Al 3 Ti growth kinetics are, for the entire temperature range investigated, diffusion limited with an activation energy of 1.5±0.2 eV

  12. Light-weight steels based on iron-aluminium - influence of micro alloying elements (B, Ti, Nb) on microstructures, textures and mechanical properties

    Energy Technology Data Exchange (ETDEWEB)

    Bruex, U.; Frommeyer, G. [Dept. of Materials Technology, Max-Planck-Inst. fuer Eisenforschung GmbH, Duesseldorf (Germany); Jimenez, J. [Centro Nacional de Investigaciones Metalurgicas (C.S.I.C.), Madrid (Spain)

    2002-12-01

    The influence of the micro alloying elements B, Ti and Nb on the recrystallization texture and mechanical properties of iron aluminium light-weight steels, particularly with reference to their improved deep drawing properties was investigated. Depending on the combination of the alloying elements the microstructures of the investigated micro alloyed Fe-6Al steels are influenced by grain refinement. Likewise, variable combinations of micro alloying elements differently affect the texture. Generally, the mechanical properties are improved. However, small amounts of B, Ti and Nb cause superior deep drawing and stretch forming properties of these iron aluminium light-weight steels. The microstructures of various micro alloyed cold rolled Fe-6Al steel sheets were evaluated by optical microscopy, scanning electron microscopy (SEM) inclusively EDAX and X-ray diffraction. Texture measurements were performed using a goniometer with a closed Eulerian cradle and analysed by ODF calculations. Tensile tests were carried out at room temperature and 200 C, respectively. The deep drawing behaviour was determined by performing cupping tests and digitalised strain analysis. (orig.)

  13. Exceptionally High Piezoelectric Coefficient and Low Strain Hysteresis in Grain-Oriented (Ba, Ca)(Ti, Zr)O3 through Integrating Crystallographic Texture and Domain Engineering.

    Science.gov (United States)

    Liu, Yingchun; Chang, Yunfei; Li, Fei; Yang, Bin; Sun, Yuan; Wu, Jie; Zhang, Shantao; Wang, Ruixue; Cao, Wenwu

    2017-09-06

    Both low strain hysteresis and high piezoelectric performance are required for practical applications in precisely controlled piezoelectric devices and systems. Unfortunately, enhanced piezoelectric properties were usually obtained with the presence of a large strain hysteresis in BaTiO 3 (BT)-based piezoceramics. In this work, we propose to integrate crystallographic texturing and domain engineering strategies into BT-based ceramics to resolve this challenge. [001] c grain-oriented (Ba 0.94 Ca 0.06 )(Ti 0.95 Zr 0.05 )O 3 (BCTZ) ceramics with a texture degree as high as 98.6% were synthesized by templated grain growth. A very high piezoelectric coefficient (d 33 ) of 755 pC/N, and an extremely large piezoelectric strain coefficient (d 33 * = 2027 pm/V) along with an ultralow strain hysteresis (H s ) of 4.1% were simultaneously achieved in BT-based systems for the first time, which are among the best values ever reported on both lead-free and lead-based piezoceramics. The exceptionally high piezoelectric response is mainly from the reversible contribution, and can be ascribed to the piezoelectric anisotropy, the favorable domain configuration, and the formation of smaller sized domains in the BCTZ textured ceramics. This study paves a new pathway to develop lead-free piezoelectrics with both low strain hysteresis and high piezoelectric coefficient. More importantly, it represents a very exciting discovery with potential application of BT-based ceramics in high-precision piezoelectric actuators.

  14. Texture development, microstructure and phase transformation characteristics of sputtered Ni-Ti Shape Memory Alloy films grown on TiN<111>

    Energy Technology Data Exchange (ETDEWEB)

    Martins, R.M.S., E-mail: rmsm@fct.unl.p [Unidade de Fisica e Aceleradores, Instituto Tecnologico e Nuclear, EN10, 2696-953 Sacavem (Portugal); Institute of Ion Beam Physics and Materials Research, Forschungszentrum Dresden-Rossendorf, P.O. Box 510119, 01314 Dresden (Germany); Centro de Fisica Nuclear da Universidade de Lisboa (CFNUL), Av. Prof. Gama Pinto 2, 1649-003 Lisboa (Portugal); Schell, N. [GKSS Research Center Geesthacht, Max-Planck-Str. 1, 21502 Geesthacht (Germany); Reuther, H. [Institute of Ion Beam Physics and Materials Research, Forschungszentrum Dresden-Rossendorf, P.O. Box 510119, 01314 Dresden (Germany); Pereira, L.; Mahesh, K.K.; Silva, R.J.C.; Fernandes, F.M. Braz [CENIMAT/I3N, Departamento de Ciencia dos Materiais, Faculdade de Ciencias e Tecnologia, FCT, Universidade Nova de Lisboa, 2829-516 Caparica (Portugal)

    2010-10-29

    Near equiatomic Ni-Ti films have been deposited by magnetron co-sputtering on TiN films with a topmost layer formed by < 111> oriented grains (TiN/SiO{sub 2}/Si(100) substrate) in a chamber installed at a synchrotron radiation beamline. In-situ X-ray diffraction during Ni-Ti film growth and their complementary ex-situ characterization by Auger electron spectroscopy, scanning electron microscopy and electrical resistivity measurements during temperature cycling have allowed us to establish a relationship between the structure and processing parameters. A preferential development of < 110> oriented grains of the B2 phase since the beginning of the deposition has been observed (without and with the application of a substrate bias voltage of -45 and -90 V). The biaxial stress state is considerably influenced by the energy of the bombarding ions, which is dependent on the substrate bias voltage value applied during the growth of the Ni-Ti film. Furthermore, the present work reveals that the control of the energy of the bombarding ions is a promising tool to vary the transformation characteristics of Ni-Ti films, as shown by electrical resistivity measurements during temperature cycling. The in-situ study of the structural evolution of the growing Ni-Ti film as a consequence of changing the Ti:Ni ratio during deposition (on a TiN<111> layer) has also been performed. The preferential growth of < 110> oriented grains of the Ni-Ti B2 phase has been as well observed despite the precipitation of Ti{sub 2}Ni during the deposition of a Ti-rich Ni-Ti film fraction. Functionally graded Ni-Ti films should lead to an intrinsic 'two-way' shape memory effect which is a plus for the miniaturization of Ni-Ti films based devices in the field of micro-electro-mechanical systems.

  15. Magnetism, Spin Texture, and In-Gap States: Atomic Specialization at the Surface of Oxygen-Deficient SrTiO_{3}.

    Science.gov (United States)

    Altmeyer, Michaela; Jeschke, Harald O; Hijano-Cubelos, Oliver; Martins, Cyril; Lechermann, Frank; Koepernik, Klaus; Santander-Syro, Andrés F; Rozenberg, Marcelo J; Valentí, Roser; Gabay, Marc

    2016-04-15

    Motivated by recent spin- and angular-resolved photoemission (SARPES) measurements of the two-dimensional electronic states confined near the (001) surface of oxygen-deficient SrTiO_{3}, we explore their spin structure by means of ab initio density functional theory (DFT) calculations of slabs. Relativistic nonmagnetic DFT calculations display Rashba-like spin winding with a splitting of a few meV and when surface magnetism on the Ti ions is included, bands become spin-split with an energy difference ∼100  meV at the Γ point, consistent with SARPES findings. While magnetism tends to suppress the effects of the relativistic Rashba interaction, signatures of it are still clearly visible in terms of complex spin textures. Furthermore, we observe an atomic specialization phenomenon, namely, two types of electronic contributions: one is from Ti atoms neighboring the oxygen vacancies that acquire rather large magnetic moments and mostly create in-gap states; another comes from the partly polarized t_{2g} itinerant electrons of Ti atoms lying further away from the oxygen vacancy, which form the two-dimensional electron system and are responsible for the Rashba spin winding and the spin splitting at the Fermi surface.

  16. Effects of strong electron correlations in Ti8C12 Met-Car

    International Nuclear Information System (INIS)

    Varganov, Sergey A.; Gordon, Mark S.

    2006-01-01

    The results of multireference configuration interaction (MRCI) with single and double excitations and single reference coupled cluster (CCSD(T)) calculations on Ti 8 C 12 metallocarbohedryne (Met-Car) are reported. The distortions of the T d structure to D 2d and C 3v structures due to the Jahn-Teller effect are studied. It is shown that the Ti 8 C 12 wave function has significant multireference character. The choice of the active space for multireference self-consistent field (MCSCF) calculations is discussed. The failure of multireference perturbation theory with a small active space is attributed to multiple intruder states. A new, novel type of MCSCF calculation, ORMAS (occupation restricted multiple active spaces) with a large active space are carried out for several electronic states of Ti 8 C 12 . The Jahn-Teller distorted D 2d 1 A 1 (nearly T d ) structure is predicted to be the Ti 8 C 12 ground state. Predictions of the Ti 8 C 12 ionization potential with different ab initio methods are presented

  17. Early Stages of Microstructure and Texture Evolution during Beta Annealing of Ti 6Al 4V (Preprint)

    Science.gov (United States)

    2016-09-27

    beta-grain structure from electron -backscatter-diffraction measurements of the room-temperature alpha-phase texture revealed that microstructure...RESPONSIBLE PERSON (Monitor) a. REPORT Unclassified b. ABSTRACT Unclassified c. THIS PAGE Unclassified Bill Song 19b. TELEPHONE...Reconstruction of the beta-grain structure from electron -backscatter-diffraction measurements of the room-temperature alpha-phase texture revealed

  18. Anomalous metallic state with strong charge fluctuations in BaxTi8O16 +δ revealed by hard x-ray photoemission spectroscopy

    Science.gov (United States)

    Dash, S.; Kajita, T.; Okawa, M.; Saitoh, T.; Ikenaga, E.; Saini, N. L.; Katsufuji, T.; Mizokawa, T.

    2018-04-01

    We have studied a charge-orbital driven metal-insulator transition (MIT) in hollandite-type BaxTi8O16 +δ by means of hard x-ray photoemission spectroscopy (HAXPES). The Ti 2 p HAXPES indicates strong Ti3 +/Ti4 + charge fluctuation in the metallic phase above the MIT temperature. The metallic phase is characterized by a power-law spectral function near the Fermi level which would be a signature of bad metal with non-Drude polaronic behavior. The power-law spectral shape is associated with the large Seebeck coefficient of the metallic phase in BaxTi8O16 +δ .

  19. Use of the generalized spherical harmonic model for describing crystallographic texture in polycrystalline NiTi shape-memory alloy with time-of-flight neutron powder diffraction data

    CERN Document Server

    Sitepu, H; Dreele, R B V

    2002-01-01

    We present a feasibility study to extract quantitative texture and precise crystal structure information of polycrystalline monoclinic NiTi shape-memory alloys from a simultaneous refinement of 52 time-of-flight neutron-diffraction patterns taken in 13 orientations in the diffractometer. The multiple-data-set capabilities and the generalized spherical harmonic texture model of the GSAS program system were employed. (orig.)

  20. Preparation of textured CaBi4Ti4O15 based ceramics and dielectric properties optimized with La3+ doping

    Directory of Open Access Journals (Sweden)

    ZHENG Qianqian

    2012-12-01

    Full Text Available A batch of 001>textured CaBi4Ti4O15(x=0,0.1,0.2,0.3,0.4 (CBLT-x ceramics were fabricated by a two-step sintering method:synthesizing seed-crystal platelets by molten-salt method with oxide mixture as precursor,and then sintering the platelets via grain orientation technique (OCAP.Microstructural characterization by SEM was performed to establish the effect of increased doping of La3+ and sintering temperature on grain growth and texture development.Increasing La3+(to x=0.4 resulted in dielectric constant improvement up to 570 sintered at 1150℃ in the direction perpendicular to the tapecasting plan.The dielectric constant as well as loss of CBLT-x samples in the perpendicular direction is higher than that of parallel plane.The mechanism controlling the texture and grain growth in CBLT-xceramics is firstly discussed by 3D patterns in this letter.

  1. Interpretation of zircon coronae textures from metapelitic granulites of the Ivrea–Verbano Zone, northern Italy: two-stage decomposition of Fe–Ti oxides

    Directory of Open Access Journals (Sweden)

    E. Kovaleva

    2017-07-01

    Full Text Available In this study, we report the occurrence of zircon coronae textures in metapelitic granulites of the Ivrea–Verbano Zone. Unusual zircon textures are spatially associated with Fe–Ti oxides and occur as (1 vermicular-shaped aggregates 50–200 µm long and 5–20 µm thick and as (2 zircon coronae and fine-grained chains, hundreds of micrometers long and ≤ 1 µm thick, spatially associated with the larger zircon grains. Formation of such textures is a result of zircon precipitation during cooling after peak metamorphic conditions, which involved: (1 decomposition of Zr-rich ilmenite to Zr-bearing rutile, and formation of the vermicular-shaped zircon during retrograde metamorphism and hydration; and (2 recrystallization of Zr-bearing rutile to Zr-depleted rutile intergrown with quartz, and precipitation of the submicron-thick zircon coronae during further exhumation and cooling. We also observed hat-shaped grains that are composed of preexisting zircon overgrown by zircon coronae during stage (2. Formation of vermicular zircon (1 preceded ductile and brittle deformation of the host rock, as vermicular zircon is found both plastically and cataclastically deformed. Formation of thin zircon coronae (2 was coeval with, or immediately after, brittle deformation as coronae are found to fill fractures in the host rock. The latter is evidence of local, fluid-aided mobility of Zr. This study demonstrates that metamorphic zircon can nucleate and grow as a result of hydration reactions and mineral breakdown during cooling after granulite-facies metamorphism. Zircon coronae textures indicate metamorphic reactions in the host rock and establish the direction of the reaction front.

  2. Interpretation of zircon coronae textures from metapelitic granulites of the Ivrea-Verbano Zone, northern Italy: two-stage decomposition of Fe-Ti oxides

    Science.gov (United States)

    Kovaleva, Elizaveta; Austrheim, Håkon O.; Klötzli, Urs S.

    2017-07-01

    In this study, we report the occurrence of zircon coronae textures in metapelitic granulites of the Ivrea-Verbano Zone. Unusual zircon textures are spatially associated with Fe-Ti oxides and occur as (1) vermicular-shaped aggregates 50-200 µm long and 5-20 µm thick and as (2) zircon coronae and fine-grained chains, hundreds of micrometers long and ≤ 1 µm thick, spatially associated with the larger zircon grains. Formation of such textures is a result of zircon precipitation during cooling after peak metamorphic conditions, which involved: (1) decomposition of Zr-rich ilmenite to Zr-bearing rutile, and formation of the vermicular-shaped zircon during retrograde metamorphism and hydration; and (2) recrystallization of Zr-bearing rutile to Zr-depleted rutile intergrown with quartz, and precipitation of the submicron-thick zircon coronae during further exhumation and cooling. We also observed hat-shaped grains that are composed of preexisting zircon overgrown by zircon coronae during stage (2). Formation of vermicular zircon (1) preceded ductile and brittle deformation of the host rock, as vermicular zircon is found both plastically and cataclastically deformed. Formation of thin zircon coronae (2) was coeval with, or immediately after, brittle deformation as coronae are found to fill fractures in the host rock. The latter is evidence of local, fluid-aided mobility of Zr. This study demonstrates that metamorphic zircon can nucleate and grow as a result of hydration reactions and mineral breakdown during cooling after granulite-facies metamorphism. Zircon coronae textures indicate metamorphic reactions in the host rock and establish the direction of the reaction front.

  3. High mobility of the strongly confined hole gas in AgTaO3/SrTiO3

    KAUST Repository

    Nazir, Safdar

    2012-05-18

    A theoretical study of the two-dimensional hole gas at the (AgO)−/(TiO2)0 p-type interface in the AgTaO3/SrTiO3 (001) heterostructure is presented. The Ag 4d states strongly hybridize with the O 2p states and contribute to the hole gas. It is demonstrated that the holes are confined to an ultra thin layer (∼4.9Å) with a considerable carrier density of ∼1014cm−2. We estimate a hole mobility of 18.6 cm2 V−1 s−1, which is high enough to enable device applications.

  4. Strong out-of-plane magnetic anisotropy in ion irradiated anatase TiO2 thin films

    Directory of Open Access Journals (Sweden)

    M. Stiller

    2016-12-01

    Full Text Available The temperature and field dependence of the magnetization of epitaxial, undoped anatase TiO2 thin films on SrTiO3 substrates was investigated. Low-energy ion irradiation was used to modify the surface of the films within a few nanometers, yet with high enough energy to produce oxygen and titanium vacancies. The as-prepared thin film shows ferromagnetism which increases after irradiation with low-energy ions. An optimal and clear magnetic anisotropy was observed after the first irradiation, opposite to the expected form anisotropy. Taking into account the experimental parameters, titanium vacancies as di-Frenkel pairs appear to be responsible for the enhanced ferromagnetism and the strong anisotropy observed in our films. The magnetic impurities concentrations was measured by particle-induced X-ray emission with ppm resolution. They are ruled out as a source of the observed ferromagnetism before and after irradiation.

  5. Textured PbTiO3, Pb(Ca)TiO3-Al2O3 composite films prepared by chemical solution deposition method

    Czech Academy of Sciences Publication Activity Database

    Buršík, Josef; Kužel, R.; Marek, J.; Drbohlav, Ivo

    2003-01-01

    Roč. 26, 1-3 (2003), s. 727-733 ISSN 0928-0707 R&D Projects: GA MŠk LN00A028 Institutional research plan: CEZ:AV0Z4032918 Keywords : thin films * texture * chemical solution deposition Subject RIV: CA - Inorganic Chemistry Impact factor: 1.546, year: 2003

  6. Neutron diffraction studies of the stress effect on texture transformations in NiTi shape memory alloys

    Czech Academy of Sciences Publication Activity Database

    Šittner, Petr; Neov, Dimitar; Lukáš, Petr; Toebbens, D. M.

    2004-01-01

    Roč. 12, - (2004), s. 115-120 ISSN 1023-8166 R&D Projects: GA AV ČR IAA1048107; GA ČR GA106/01/0396 Institutional research plan: CEZ:AV0Z1010914; CEZ:AV0Z1048901 Keywords : shape memory alloy * martensitic transformation * texture * neutron diffraction Subject RIV: BM - Solid Matter Physics ; Magnetism

  7. Comparative Study of the Optical and Textural Properties of Tetrapyrrole Macrocycles Trapped Within ZrO2, TiO2, and SiO2 Translucent Xerogels

    Directory of Open Access Journals (Sweden)

    Eduardo Salas-Bañales

    2015-10-01

    Full Text Available The entrapping of physicochemical active molecules inside mesoporous networks is an appealing field of research due to the myriad of potential applications in optics, photocatalysis, chemical sensing, and medicine. One of the most important reasons for this success is the possibility of optimizing the properties that a free active species displays in solution but now trapped inside a solid substrate. Additionally it is possible to modulate the textural characteristics of substrates, such as pore size, specific surface area, polarity and chemical affinity of the surface, toward the physical or chemical adhesion of a variety of adsorbates. In the present document, two kinds of non-silicon metal alkoxides, Zr and Ti, are employed to prepare xerogels containing entrapped tetrapyrrolic species that could be inserted beforehand in analogue silica systems. The main goal is to develop efficient methods for trapping or binding tetrapyrrole macrocycles inside TiO2 and ZrO2 xerogels, while comparing the properties of these systems against those of the SiO2 analogues. Once the optimal synthesis conditions for obtaining translucent monolithic xerogels of ZrO2 and TiO2 networks were determined, it was confirmed that these substrates allowed the entrapment, in monomeric form, of macrocycles that commonly appear as aggregates within the SiO2 network. From these experiments, it could be determined that the average pore diameters, specific surface areas, and water sorption capacities depicted by each one of these substrates, are a consequence of their own nature combined with the particular structure of the entrapped tetrapyrrole macrocycle. Furthermore, the establishment of covalent bonds between the intruding species and the pore walls leads to the obtainment of very similar pore sizes in the three different metal oxide (Ti, Zr, and Si substrates as a consequence of the templating effect of the encapsulated species.

  8. Facile one-step hydrothermal synthesis toward strongly coupled TiO2/graphene quantum dots photocatalysts for efficient hydrogen evolution

    International Nuclear Information System (INIS)

    Min, Shixiong; Hou, Jianhua; Lei, Yonggang; Ma, Xiaohua; Lu, Gongxuan

    2017-01-01

    Highlights: • TiO 2 /GQDs composites were prepared by a facile one-step hydrothermal method. • GQDs were strongly coupled onto the surface of TiO 2 nanoparticles by this method. • The TiO 2 /GQDs showed enhanced light absorption and charge separation efficiency. • The TiO 2 /GQDs exhibited higher photocatalytic H 2 evolution activity than pure TiO 2 . • GQDs play synergistic roles by acting as both photosensitizer and electron acceptor. - Abstract: The coupling of semiconductor photocatalysts with graphene quantum dots (GQDs) has been proven to be an effective strategy to enhance the photocatalytic and photoelectrical conversion performances of the resulted composites; however, the preparation of semiconductor/GQDs composites usually involves several time-inefficient and tedious post-treatment steps. Herein, we present a facile one-step hydrothermal route for the preparation of GQDs coupled TiO 2 (TiO 2 /GQDs) photocatalysts using 1,3,6-trinitropyrene (TNP) as the sole precursor of GQDs. During the hydrothermal process, TNP molecules undergo an intramolecular fusion to form GQDs, which simultaneously decorate on the surface of TiO 2 nanoparticles, leading to a strong surface interaction between the two components. The effective coupling of GQDs on TiO 2 can effectively extend the light absorption of the TiO 2 to visible region and enhance the charge separation efficiency of TiO 2 /GQDs composites as a result of GQDs acting as a photosensitizer and an excellent electron acceptor. These key advances make the TiO 2 /GQDs photocatalyst highly active towards the H 2 evolution reaction, resulting in 7 and 3 times higher H 2 evolution rate and photocurrent response at optimal GQDs content than TiO 2 alone, respectively. This study provides a new methodology for the development of high-performance GQDs modified semiconductor photocatalysts for energy conversion applications.

  9. Effect of the reaction time on the microstructure and porous texture of carbon materials obtained by chlorination of Ti(C5H5)Cl2

    International Nuclear Information System (INIS)

    Araujo-Pérez, D.J.; González-García, P.; Poisot, M.; García-González, L.

    2015-01-01

    Carbon materials have been obtained by the chlorination reaction of Ti(C 5 H 5 )Cl 2 at 900 °C, varying the reaction time at 30, 60, 90 and 120 min. The average microstructure, studied by X ray powder diffraction, suggest that these materials consist mainly of disordered carbon with low graphitization degree (from 13.5 to 16.5%). These results are in agreement with the Raman data since the D band (at ≈ 1350 cm −1 ) indicates that disordered carbon networks have appeared. The calculated in-plane correlation length increases from 4.04 to 4.70 nm as the chlorination time increases from 30 to 120 min. The textural analyses reveal adsorption isotherms type 1 with hysteresis H4, microporous areas as high as 855 m 2 /g and pore volume of 0.55 cm 3 /g. Additionally, an important contribution of mesoporosity, around 3.6 nm, was also detected. - Highlights: • Micro-mesoporous carbon materials were obtained by chlorination of Ti(C 5 H 5 ) 2 Cl 2 at 900 °C. • The effect of chlorination exposure time on the microstructure and textural properties was studied. • Microstructural analysis by XRD and Raman showed that carbon samples are mainly disordered. • N 2 adsorption/desorption isotherms showed isotherms type 1 with hysteresis H4. • Micropore size increases at longer chlorination time; in contrast, pore volume decreases.

  10. Growth and characterization of textured YBaCo{sub 2}O{sub 5+δ} thin films grown on (001)-SrTiO{sub 3} via DC magnetron sputtering

    Energy Technology Data Exchange (ETDEWEB)

    Galeano, V. [Universidad Nacional de Colombia, Campus Medellín, Facultad de Ciencias, Departamento de Física, Laboratorio de Cerámicos y Vítreos, A.A. 568, Medellín (Colombia); Arnache, O. [Grupo de Estado Sólido, Departamento de Física, Universidad de Antioquia, A.A. 1226, Medellín (Colombia); Supelano, I.; Vargas, C.A. Parra [Universidad Pedagógica y Tecnológica de Colombia, Departamento de Física, Avenida Central del Norte 39-115, Tunja (Colombia); Morán, O., E-mail: omoranc@unal.edu.co [Universidad Nacional de Colombia, Campus Medellín, Facultad de Ciencias, Departamento de Física, Laboratorio de Cerámicos y Vítreos, A.A. 568, Medellín (Colombia)

    2016-06-30

    Thin films of the layered cobaltite YBaCo{sub 2}O{sub 5+δ} were successfully grown on (001)-oriented SrTiO{sub 3} single-crystal substrates by means of DC magnetron sputtering. The 112 phase of the compound was stabilized by choosing an adequate Co reactant and through careful thermal treatment of the target. The results demonstrate the strong influence of these variables on the final phase of the compound. A substrate temperature of 1053 K and an oxygen pressure of 300 Pa seemed to be appropriate growing conditions for depositing (00ℓ)-textured YBaCo{sub 2}O{sub 5+δ} thin films onto the chosen substrate. In like fashion to the polycrystalline YBaCo{sub 2}O{sub 5+δ}, the films showed a clear sequence of antiferromagnetic–ferromagnetic–paramagnetic transitions within a narrow temperature range. Well-defined hysteresis loops were observed at temperatures as high as 270 K, which supports the existence of a FM order in the films. In turn, the dependence of the resistivity on the temperature shows a semiconductor-like behavior, without any distinguishable structure, within the temperature range measured (50–350 K). The analysis of the experimental data showed that the transport mechanism in the films is well described by using the Mott variable range hopping (VRH) conduction model. - Highlights: • YBaCo{sub 2}O{sub 5+δ} thin films are grown on SrTiO{sub 3} substrates. • Strong (00ℓ) reflections are observed in the X-ray diffraction pattern. • A clear sequence of magnetic transitions is observed. • Semiconducting-like behavior is verified.

  11. Crystallization behavior and domain structure in textured Pb(Zr0.52Ti0.48)O3 thin films by different annealing processes

    International Nuclear Information System (INIS)

    Huang, W.; Jiang, S.W.; Li, Y.R.; Zhu, J.; Zhang, Y.; Wei, X.H.; Zeng, H.Z.

    2006-01-01

    Amorphous Pb(Zr 0.52 Ti 0.48 )O 3 (PZT) thin films were prepared on the Pt/Ti/SiO 2 /Si substrates by radio-frequency magnetron sputtering at room temperature. After rapid thermal annealing (RTA) and conventional furnace annealing (CFA) at different temperatures, the films were transformed into polycrystalline PZT thin films with (111) and (100) orientation, respectively. The phase formation and ferroelectric domains correlated with different orientation were systematically investigated by X-ray diffraction and piezoresponse force microscopy. The results showed that the perovskite PZT crystal with [111] orientation hetero-nucleated preferentially on top of the PtPb intermetallic phase at the PZT/Pt interface during RTA process. It is of interest to find that the domain self-organized into a structure with rounded shape at the early stage of crystallization. While the nucleation of the films treated by CFA dominantly homo-nucleated, thus the (100) orientation grains with minimum surface energy were easy to grow. The texture effects on ferroelectric properties of PZT films were also discussed in relation to the domain structure

  12. Effects of laser shock peening with contacting foil on micro laser texturing surface of Ti6Al4V

    Science.gov (United States)

    Dai, Fengze; Zhang, Zidong; Ren, Xudong; Lu, Jinzhong; Huang, Shu

    2018-02-01

    Ti6Al4V samples with micro-dimple arrays were subjected to laser shock peening in contact with foil (HCLSP). The surface roughness, micro-hardness, the residual stress distribution and the surface morphology of the micro-dimple arrays were studied to evaluate the effects of HCLSP. Moreover, the surface topography of the foils in contact was also analyzed. The gap existence between the foil and the to-be treated surface led the mechanism of HCLSP to be different compared to regular laser shock peening. The surface roughness reduction, the work-hardening effects, the compressive residual stress and the micro crack enclosure were achieved. A simplified ball-hitting-surface model was utilized to analyze the HCLSP impact. The model could well explain the experimental results. When treated by the HCLSP with H62 foil at the laser power density of 4.24 GW/cm2, the Ti6Al4V samples with micro-dimple arrays exhibit well surface topography and mechanical performance.

  13. Growth mode and texture development in TiN films during magnetron sputtering - An in situ synchrotron radiation study

    CERN Document Server

    Schell, N; Matz, W; Chevallier, J

    2003-01-01

    For the materials research experimental station of the Rossendorf beamline ROBL at the European Synchrotron Radiation Facility in Grenoble, France, a two magnetron sputter deposition chamber for in situ study of film growth by synchrotron X-ray diffraction and reflectivity was developed. It allows high-quality depositions of compound films and multilayers. Heteroepitaxial layer-by-layer growth of TiN on single crystal MgO(0 0 1) was observed by real-time specular X-ray reflectivity showing characteristic oscillations. The pseudomorphic growth was confirmed by high-resolution TEM micrographs. During growth on amorphous SiO sub 2 on Si(0 0 1) substrates, the microstructural development of TiN films was studied in situ as a function of film thickness. With the deposition parameters chosen, a crossover was observed: grains with a (0 0 2) plane parallel to the film surface dominate at small thicknesses, while, at larger thicknesses, (1 1 1) grains dominate. Recrystallisation was identified as a mechanism that cont...

  14. Densification and texture evolution of Bi{sub 4}Ti{sub 3}O{sub 12} templated Na{sub 0.5}Bi{sub 0.5}TiO{sub 3}-BaTiO{sub 3} ceramics: Effects of excess Bi{sub 2}O{sub 3}

    Energy Technology Data Exchange (ETDEWEB)

    Su Shi [Institute of Electro Ceramics and Devices, School of Materials Science and Engineering, Hefei University of Technology, Hefei 230009 (China); Zuo Ruzhong, E-mail: piezolab@hfut.edu.cn [Institute of Electro Ceramics and Devices, School of Materials Science and Engineering, Hefei University of Technology, Hefei 230009 (China); Lv Danya [Institute of Electro Ceramics and Devices, School of Materials Science and Engineering, Hefei University of Technology, Hefei 230009 (China)

    2012-04-05

    Highlights: Black-Right-Pointing-Pointer Excess Bi{sub 2}O{sub 3} induces anomalous microstructure in BIT templated NBT-BT ceramics. Black-Right-Pointing-Pointer Undoped samples have a high degree grain orientation compared to Bi{sub 2}O{sub 3} doped ones. Black-Right-Pointing-Pointer The mechanism of texture development in Bi{sub 2}O{sub 3} liquid phase was put forward. - Abstract: 0.94Na{sub 0.5}Bi{sub 0.5}TiO{sub 3}-0.06BaTiO{sub 3} lead-free ceramics were fabricated by templated grain growth method using 5 vol% platelet Bi{sub 4}Ti{sub 3}O{sub 12} (BIT) templates. The effect of the addition of excess Bi{sub 2}O{sub 3} on the densification and the texture evolution was investigated. A high degree of grain orientation (f {approx} 0.93) and an excellent piezoelectric coefficient d{sub 33} of {approx}290 pC/N were obtained for undoped samples, however the texture was hardly developed for Bi{sub 2}O{sub 3} doped samples whose densification behavior yet could be significantly improved. It was found that the Bi{sub 2}O{sub 3} liquid phase can promote the particle rearrangement and mass transport, but simultaneously change the surface morphology of BIT templates and matrix grains from an atomically rough to smooth structure. The Ostwald growth was thus induced dominantly in the diametrical direction and little in the thickness direction of plate-like templates. The results provided a good reference for selecting the sintering aid in the fabrication of textured ceramics.

  15. cis-Thioindigo (TI) - a new ligand with accessible radical anion and dianion states. Strong magnetic coupling in the {[TI-(μ2-O),(μ-O)]Cp*Cr}2 dimers.

    Science.gov (United States)

    Konarev, Dmitri V; Khasanov, Salavat S; Shestakov, Alexander F; Fatalov, Alexey M; Batov, Mikhail S; Otsuka, Akihiro; Yamochi, Hideki; Kitagawa, Hiroshi; Lyubovskaya, Rimma N

    2017-10-24

    Reaction of decamethylchromocene (Cp* 2 Cr) with thioindigo (TI) yields a coordination complex {[TI-(μ 2 -O), (μ-O)]Cp*Cr} 2 ·C 6 H 14 (1) in which one Cp* ligand in Cp* 2 Cr is substituted by TI. TI adopts cis-conformation in 1 allowing the coordination of both carbonyl groups to chromium. Additionally, one oxygen atom of TI becomes a μ 2 -bridge for two chromium atoms to form {[TI-(μ 2 -O), (μ-O)]Cp*Cr} 2 dimers with a CrCr distance of 3.12 Å. According to magnetic data, diamagnetic TI 2- dianions and two Cr 3+ atoms with a high S = 3/2 spin state are present in a dimer allowing strong antiferromagnetic coupling between two Cr 3+ spins with an exchange interaction of -35.4 K and the decrease of molar magnetic susceptibility below 140 K. Paramagnetic TI˙ - radical anions with the S = 1/2 spin state have also been obtained and studied in crystalline {cryptand[2,2,2](Na + )}(TI˙ - ) (2) salt showing that both radical anion and dianion states are accessible for TI.

  16. Facile one-step hydrothermal synthesis toward strongly coupled TiO{sub 2}/graphene quantum dots photocatalysts for efficient hydrogen evolution

    Energy Technology Data Exchange (ETDEWEB)

    Min, Shixiong, E-mail: sxmin@nun.edu.cn [School of Chemistry and Chemical Engineering, Beifang University of Nationalities, Yinchuan, 750021, Ningxia Province (China); Hou, Jianhua; Lei, Yonggang; Ma, Xiaohua [School of Chemistry and Chemical Engineering, Beifang University of Nationalities, Yinchuan, 750021, Ningxia Province (China); Lu, Gongxuan [State Key Laboratory for Oxo Synthesis and Selective Oxidation, Lanzhou Institute of Chemical Physics, Chinese Academy of Sciences, Lanzhou, 730000 (China)

    2017-02-28

    Highlights: • TiO{sub 2}/GQDs composites were prepared by a facile one-step hydrothermal method. • GQDs were strongly coupled onto the surface of TiO{sub 2} nanoparticles by this method. • The TiO{sub 2}/GQDs showed enhanced light absorption and charge separation efficiency. • The TiO{sub 2}/GQDs exhibited higher photocatalytic H{sub 2} evolution activity than pure TiO{sub 2}. • GQDs play synergistic roles by acting as both photosensitizer and electron acceptor. - Abstract: The coupling of semiconductor photocatalysts with graphene quantum dots (GQDs) has been proven to be an effective strategy to enhance the photocatalytic and photoelectrical conversion performances of the resulted composites; however, the preparation of semiconductor/GQDs composites usually involves several time-inefficient and tedious post-treatment steps. Herein, we present a facile one-step hydrothermal route for the preparation of GQDs coupled TiO{sub 2} (TiO{sub 2}/GQDs) photocatalysts using 1,3,6-trinitropyrene (TNP) as the sole precursor of GQDs. During the hydrothermal process, TNP molecules undergo an intramolecular fusion to form GQDs, which simultaneously decorate on the surface of TiO{sub 2} nanoparticles, leading to a strong surface interaction between the two components. The effective coupling of GQDs on TiO{sub 2} can effectively extend the light absorption of the TiO{sub 2} to visible region and enhance the charge separation efficiency of TiO{sub 2}/GQDs composites as a result of GQDs acting as a photosensitizer and an excellent electron acceptor. These key advances make the TiO{sub 2}/GQDs photocatalyst highly active towards the H{sub 2} evolution reaction, resulting in 7 and 3 times higher H{sub 2} evolution rate and photocurrent response at optimal GQDs content than TiO{sub 2} alone, respectively. This study provides a new methodology for the development of high-performance GQDs modified semiconductor photocatalysts for energy conversion applications.

  17. Strong Energy-momentum Dispersion of Phonon Dressed Carriers in the Lightly Doped Band Insulator SrTiO3

    Energy Technology Data Exchange (ETDEWEB)

    Meevasana, Warawat

    2010-05-26

    Much progress has been made recently in the study of the effects of electron-phonon (el-ph) coupling in doped insulators using angle resolved photoemission (ARPES), yielding evidence for the dominant role of el-ph interactions in underdoped cuprates. As these studies have been limited to doped Mott insulators, the important question arises how this compares with doped band insulators where similar el-ph couplings should be at work. The archetypical case is the perovskite SrTiO{sub 3} (STO), well known for its giant dielectric constant of 10000 at low temperature, exceeding that of La{sub 2}CuO{sub 4} by a factor of 500. Based on this fact, it has been suggested that doped STO should be the archetypical bipolaron superconductor. Here we report an ARPES study from high-quality surfaces of lightly doped SrTiO{sub 3}. Comparing to lightly doped Mott insulators, we find the signatures of only moderate electron-phonon coupling: a dispersion anomaly associated with the low frequency optical phonon with a {lambda}{prime} {approx} 0.3 and an overall bandwidth renormalization suggesting an overall {lambda}{prime} {approx} 0.7 coming from the higher frequency phonons. Further, we find no clear signatures of the large pseudogap or small polaron phenomena. These findings demonstrate that a large dielectric constant itself is not a good indicator of el-ph coupling and highlight the unusually strong effects of the el-ph coupling in doped Mott insulators.

  18. Symmetric textures

    International Nuclear Information System (INIS)

    Ramond, P.

    1993-01-01

    The Wolfenstein parametrization is extended to the quark masses in the deep ultraviolet, and an algorithm to derive symmetric textures which are compatible with existing data is developed. It is found that there are only five such textures

  19. TEXTURAL FRACTOGRAPHY

    Directory of Open Access Journals (Sweden)

    Hynek Lauschmann

    2011-05-01

    Full Text Available The reconstitution of the history of a fatigue process is based on the knowledge of any correspondences between the morphology of the crack surface and the velocity of the crack growth (crack growth rate - CGR. The textural fractography is oriented to mezoscopic SEM magnifications (30 to 500x. Images contain complicated textures without distinct borders. The aim is to find any characteristics of this texture, which correlate with CGR. Pre-processing of images is necessary to obtain a homogeneous texture. Three methods of textural analysis have been developed and realized as computational programs: the method based on the spectral structure of the image, the method based on a Gibbs random field (GRF model, and the method based on the idealization of light objects into a fibre process. In order to extract and analyze the fibre process, special methods - tracing fibres and a database-oriented analysis of a fibre process - have been developed.

  20. An Unusual Strong Visible-Light Absorption Band in Red Anatase TiO2 Photocatalyst Induced by Atomic Hydrogen-Occupied Oxygen Vacancies.

    Science.gov (United States)

    Yang, Yongqiang; Yin, Li-Chang; Gong, Yue; Niu, Ping; Wang, Jian-Qiang; Gu, Lin; Chen, Xingqiu; Liu, Gang; Wang, Lianzhou; Cheng, Hui-Ming

    2018-02-01

    Increasing visible light absorption of classic wide-bandgap photocatalysts like TiO 2 has long been pursued in order to promote solar energy conversion. Modulating the composition and/or stoichiometry of these photocatalysts is essential to narrow their bandgap for a strong visible-light absorption band. However, the bands obtained so far normally suffer from a low absorbance and/or narrow range. Herein, in contrast to the common tail-like absorption band in hydrogen-free oxygen-deficient TiO 2 , an unusual strong absorption band spanning the full spectrum of visible light is achieved in anatase TiO 2 by intentionally introducing atomic hydrogen-mediated oxygen vacancies. Combining experimental characterizations with theoretical calculations reveals the excitation of a new subvalence band associated with atomic hydrogen filled oxygen vacancies as the origin of such band, which subsequently leads to active photo-electrochemical water oxidation under visible light. These findings could provide a powerful way of tailoring wide-bandgap semiconductors to fully capture solar light. © 2018 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

  1. Strong room-temperature chemiresistive effect of TiO2 nanowires to nitro-aromatic compounds

    Science.gov (United States)

    Wang, Danling; Chen, Antao; Zhang, Qifeng; Cao, Guozhong

    2011-05-01

    Nanostructured TiO2 thin films are found to be highly responsive to trace vapors of common nitro-explosives at room temperature. Thin films of TiO2 nanowires, made with high yield hydrothermal synthesis, present very reliable sensing characteristics to nitro-aromatic molecules with high sensitivity and fast response at ambient condition. The detection limit of 2, 4-dinitrotoluene (DNT) vapor at room temperature could reach up to 3ppb. The experimental results indicate titania nanowires as a novel chemical sensor to explosive gas have a great commercial potential due to its unique advantages: high sensitivity, rapid response and recovery, small size suitable for intergration with microelectronics and low fabrication cost. Experimental results and a theoretical model are presented.

  2. Strong red-emission of Eu{sup 3+}:Li{sub 4}Ti{sub 5}O{sub 12} powders for phosphor applications

    Energy Technology Data Exchange (ETDEWEB)

    Yang, Yan [Kazuo Inamori School of Engineering, New York State College of Ceramics, Alfred University, Alfred, NY 14802 (United States); Jiménez, José A. [Department of Chemistry, University of North Florida, Jacksonville, FL 32224 (United States); Wu, Yiquan, E-mail: wuy@alfred.edu [Kazuo Inamori School of Engineering, New York State College of Ceramics, Alfred University, Alfred, NY 14802 (United States)

    2016-08-15

    The synthesis and photoluminescence properties of trivalent europium doped lithium titanate (Eu{sup 3+}:Li{sub 4}Ti{sub 5}O{sub 12}) with different Eu{sup 3+} concentrations (0.1 mol%, 0.3 mol%, 1.0 mol%, 3.0 mol%) are reported and analyzed as a phosphor. Europium (III) nitrate (Eu(NO{sub 3}){sub 3}) was employed as Eu{sup 3+} source, while lithium acetate dihydrate (CH{sub 3}COOLi·2H{sub 2}O) and titanium n-butoxide (Ti(OC{sub 4}H{sub 9}){sub 4}) were adopted as raw materials to synthesize the host lithium titanate with a Li:Ti stoichiometry of 4.5:1. Phase identification was performed using X-ray diffraction (XRD), and morphology was examined using scanning electron microscopy (SEM). Eu{sup 3+}:Li{sub 4}Ti{sub 5}O{sub 12} powders showed strong red emission at 612 nm, corresponding to the {sup 5}D{sub 0}–{sup 7}F{sub 2} transition, with the strongest excitation peak observed in the blue light region at 464 nm. Decay time analyses revealed relatively short lifetimes accompanying typical exponential decay rates. The effect of Eu{sup 3+} concentration (0.1 mol%, 0.3 mol%, 1.0 mol%, 3.0 mol%) on photoluminescence intensity and decay time was explored, and is reported here. It was determined that the CIE color coordinates (0.66, 0.34) of the doped Li{sub 4}Ti{sub 5}O{sub 12} powders were independent of Eu{sup 3+} concentration, and that the coordinates are very similar to the ideal red chromaticity (0.67, 0.33) designated by the National Television Standard Committee (NTSC) system.

  3. Strong light-extraction enhancement in GaInN light-emitting diodes patterned with TiO2 micro-pillars with tapered sidewalls

    Science.gov (United States)

    Ma, Ming; Cho, Jaehee; Fred Schubert, E.; Park, Yongjo; Bum Kim, Gi; Sone, Cheolsoo

    2012-10-01

    An effective method to enhance the light extraction for GaInN light-emitting diodes (LEDs) is reported. The method employs TiO2 micro-pillars with tapered sidewalls, which are refractive-index-matched to the underlying GaN. The tapered micro-pillars are fabricated by using reflowed photoresist as mask during CHF3-based dry etch, with O2 added in order to precisely control the taper angle. LEDs patterned with TiO2 micro-pillars with tapered sidewalls show a 100% enhancement in light-output power over planar reference LEDs. The measured results are in good agreement with ray-tracing simulations, showing strong potential of optical surfaces that are controlled in terms of refractive index and lateral structure.

  4. Crystallographic textures

    Directory of Open Access Journals (Sweden)

    Klosek Vincent

    2017-01-01

    Full Text Available In material science, crystallographic texture is an important microstructural parameter which directly determines the anisotropy degree of most physical properties of a polycrystalline material at the macro scale. Its characterization is thus of fundamental and applied importance, and should ideally be performed prior to any physical property measurement or modeling. Neutron diffraction is a tool of choice for characterizing crystallographic textures: its main advantages over other existing techniques, and especially over the X-ray diffraction techniques, are due to the low neutron absorption by most elements. The obtained information is representative of a large number of grains, leading to a better accuracy of the statistical description of texture.

  5. Microstructure and crystallographic texture of pure titanium parts generated by laser additive manufacturing

    Science.gov (United States)

    Arias-González, Felipe; del Val, Jesús; Comesaña, Rafael; Penide, Joaquín; Lusquiños, Fernando; Quintero, Félix; Riveiro, Antonio; Boutinguiza, Mohamed; Gil, Francisco Javier; Pou, Juan

    2018-01-01

    In this paper, the microstructure and crystallographic texture of pure Ti thin walls generated by Additive Manufacturing based on Laser Cladding (AMLC) are analyzed in depth. From the results obtained, it is possible to better understand the AMLC process of pure titanium. The microstructure observed in the samples consists of large elongated columnar prior β grains which have grown epitaxially from the substrate to the top, in parallel to the building direction. Within the prior β grains, α-Ti lamellae and lamellar colonies are the result of cooling from above the β-transus temperature. This transformation follows the Burgers relationship and the result is a basket-weave microstructure with a strong crystallographic texture. Finally, a thermal treatment is proposed to transform the microstructure of the as-deposited samples into an equiaxed microstructure of α-Ti grains.

  6. Texture in state-of-the-art Nb3Sn multifilamentary superconducting wires

    CERN Document Server

    Scheuerlein, C; Alknes, P; Jimenez, N; Bordini, B; Ballarino, A; Di Michiel, M; Thilly, L; Besara, T; Siegrist, T

    2014-01-01

    The texture of Nb3Sn in recent multifilamentary composite wires has been studied by neutron diffraction, synchrotron x-ray diffraction and electron backscatter diffraction. In powder-in-tube (PIT) type superconductors the Nb precursor filaments exhibit a strong 〈110〉 fiber texture as a consequence of the severe cold drawing process, and a 〈110〉 texture is also observed in the Nb3Sn. In the Nb–Ta precursor of the restacked rod process (RRP) strand there is an additional texture component, and in both Ta-alloyed and Ti-alloyed RRP type conductors the Nb3Sn grains grow with a preferential 〈100〉 orientation.

  7. High gain and double phase conjugation with strongly doped CO:BaTiO 3 in reflection grating configurations

    Science.gov (United States)

    Glick, Yaakov; Sternklar, Shmuel

    1997-02-01

    A study of highly doped photorefractive Co:BaTiO 3 reveals its usefulness for wave mixing through reflection grating interactions. Gain and noise figures are characterized for a counter-propagating pump-signal amplifier. Gain as high as 3 × 10 7, extraction efficiency as high as 40% and noise equivalent power as low as 0.15 pW were demonstrated. To the best of our knowledge this is the highest photorefractive gain reported to date. In addition the double phase conjugate mirror (DPCM) is operated in a reflection grating geometry. High absorption limits the DPCM reflectivity to about 1%.

  8. Tiny cause with huge impact: polar instability through strong magneto-electric-elastic coupling in bulk EuTiO3.

    Science.gov (United States)

    Reuvekamp, Patrick; Caslin, Kevin; Guguchia, Zurab; Keller, Hugo; Kremer, Reinhard K; Simon, Arndt; Köhler, Jürgen; Bussmann-Holder, Annette

    2015-07-08

    EuTiO3 exhibits strong magneto-electric coupling at the onset of antiferromagnetic order below TN = 5.7 K. The dielectric permittivity drops at TN by 7% and recovers to normal values with increasing magnetic field. This effect is shown to stem from tiny lattice effects as seen in magnetostriction data which directly affect the soft optic mode and its polarizability coordinate. By combining experimental results with theory we show that marginal changes in the lattice parameter of the order of 0.01% have a more than 1000% effect on the transverse optic soft mode of ETO and thus easily induce a ferroelectric instability.

  9. Fast neutron induced flux pinning in Tl-based high-Tc single crystals and thin films, highly textured tapes and melt-textured bulk 123-superconductors

    International Nuclear Information System (INIS)

    Brandstaetter, G.; Samadi Hosseinalli, G.; Kern, C.; Sauerzopf, F.M.; Schulz, G.W.; Straif, W.; Yang, X.; Weber, H.W.; Hu, Q.Y.

    1999-01-01

    Various compounds (TI-2223, TI-1223, TI-2212) as well as material forms (single crystals, thin films, ceramics, tapes) of TI-based high temperature superconductors were investigated by magnetic and transport techniques. TI-2223 has a very 'low lying' irreversibility line (H parallel e) and negligible critical current densities J c at 77 K. However, the irreversibility line shifts to higher fields and temperatures and J c is strongly enhanced, even at 77 K, after fast neutron irradiation. In contrast, the related TI-1223 compound has a much steeper irreversibility line (H parallel c) similar to that of Y-123. J c is significant up to 77 K, even in the unirradiated state, and can be largely improved by neutron irradiation. Transport measurements made on TI-1223 tapes still show much lower critical current densities. TI-2212 and Tl-2223 thin films have J c 's at 77 K, which are comparable to those of TI-1223 single crystals. Transport measurements on highly textured Bi-2223 tapes as well as flux profile measurements on Nd-123 bulk superconductors confirm the beneficial effects of neutron induced defects (collision cascades) for flux pinning. (author)

  10. Effect of the reaction time on the microstructure and porous texture of carbon materials obtained by chlorination of Ti(C{sub 5}H{sub 5})Cl{sub 2}

    Energy Technology Data Exchange (ETDEWEB)

    Araujo-Pérez, D.J. [Centro de Investigación en Micro y Nanotecnología, Universidad Veracruzana, 94294, Boca del Río, Veracruz (Mexico); González-García, P., E-mail: pedro.gonzalez@cidesi.edu.mx [CONACYT Research Fellow – Centro de Ingeniería y Desarrollo Industrial, 76130, Querétaro, Querétaro (Mexico); Poisot, M. [Instituto de Química Aplicada, Universidad del Papaloapan, 68301, San Juan Bautista Tuxtepec, Oaxaca (Mexico); García-González, L. [Centro de Investigación en Micro y Nanotecnología, Universidad Veracruzana, 94294, Boca del Río, Veracruz (Mexico)

    2015-09-15

    Carbon materials have been obtained by the chlorination reaction of Ti(C{sub 5}H{sub 5})Cl{sub 2} at 900 °C, varying the reaction time at 30, 60, 90 and 120 min. The average microstructure, studied by X ray powder diffraction, suggest that these materials consist mainly of disordered carbon with low graphitization degree (from 13.5 to 16.5%). These results are in agreement with the Raman data since the D band (at ≈ 1350 cm{sup −1}) indicates that disordered carbon networks have appeared. The calculated in-plane correlation length increases from 4.04 to 4.70 nm as the chlorination time increases from 30 to 120 min. The textural analyses reveal adsorption isotherms type 1 with hysteresis H4, microporous areas as high as 855 m{sup 2}/g and pore volume of 0.55 cm{sup 3}/g. Additionally, an important contribution of mesoporosity, around 3.6 nm, was also detected. - Highlights: • Micro-mesoporous carbon materials were obtained by chlorination of Ti(C{sub 5}H{sub 5}){sub 2}Cl{sub 2} at 900 °C. • The effect of chlorination exposure time on the microstructure and textural properties was studied. • Microstructural analysis by XRD and Raman showed that carbon samples are mainly disordered. • N{sub 2} adsorption/desorption isotherms showed isotherms type 1 with hysteresis H4. • Micropore size increases at longer chlorination time; in contrast, pore volume decreases.

  11. Textures and mineral compositions of the Xinjie layered intrusion, SW China: Implications for the origin of magnetite and fractionation process of Fe-Ti-rich basaltic magmas

    Directory of Open Access Journals (Sweden)

    Huan Dong

    2013-09-01

    Full Text Available The Xinjie layered intrusion in the Panxi region, SW China, hosts both Fe-Ti oxide and platinum-group element (PGE sulfide mineralization. The intrusion can be divided, from the base upward, into Units I, II and III, in terms of mineral assemblages. Units I and II are mainly composed of wehrlite and clinopyroxenite, whereas Unit III is mainly composed of gabbro. PGE sulfide-rich layers mainly occur in Unit I, whereas thick Fe-Ti oxide-rich layers mainly occur in Unit III. An ilmenite-rich layer occurs at the top of Unit I. Fe-Ti oxides include magnetite and ilmenite. Small amounts of cumulus and intercumulus magnetite occur in Units I and II. Cumulus magnetite grains are commonly euhedral and enclosed within olivine and clinopyroxene. They have high Cr2O3 contents ranging from 6.02 to 22.5 wt.%, indicating that they are likely an early crystallized phase from magmas. Intercumulus magnetite that usually displays ilmenite exsolution occupies the interstices between cumulus olivine crystals and coexists with interstitial clinopyroxene and plagioclase. Intercumulus magnetite has Cr2O3 ranging from 1.65 to 6.18 wt.%, lower than cumulus magnetite. The intercumulus magnetite may have crystallized from the trapped liquid. Large amounts of magnetite in Unit III contains Cr2O3 (<0.28 wt.% much lower than magnetite in Units I and II. The magnetite in Unit III is proposed to be accumulated from a Fe-Ti-rich melt. The Fe-Ti-rich melt is estimated to contain 35.9 wt.% of SiO2, 26.9 wt.% of FeOt, 8.2 wt.% of TiO2, 13.2 wt.% of CaO, 8.3 wt.% of MgO, 5.5 wt.% of Al2O3 and 1.0 wt.% of P2O5. The composition is comparable with the Fe-rich melts in the Skaergaard and Sept Iles intrusions. Paired non-reactive microstructures, granophyre pockets and ilmenite-rich intergrowths, are representative of Si-rich melt and Fe-Ti-rich melt, and are the direct evidence for the existence of an immiscible Fe-Ti-rich melt that formed from an evolved ferro-basaltic magma.

  12. Strings, texture, and inflation

    International Nuclear Information System (INIS)

    Hodges, H.M.; Primack, J.R.

    1991-01-01

    We examine mechanisms, several of which are proposed here, to generate structure formation, or to just add large-scale features, through either gauged or global cosmic strings or global texture, within the framework of inflation. We first explore the possibility that strings or texture form if there is no coupling between the topological theory and the inflaton or spacetime curvature, via (1) quantum creation, and (2) a sufficiently high reheat temperature. In addition, we examine the prospects for the inflaton field itself to generate strings or texture. Then, models with the string/texture field coupled to the curvature, and an equivalent model with coupling to the inflaton field, are considered in detail. The requirement that inflationary density fluctuations are not so large as to conflict with observations leads to a number of constraints on model parameters. We find that strings of relevance for structure formation can form in the absence of coupling to the inflaton or curvature through the process of quantum creation, but only if the strings are strongly type I, or if they are global strings. If formed after reheating, naturalness suggests that gauged cosmic strings correspond to a type-I superconductor. Similarly, gauged strings formed during inflation via conformal coupling ξ=1/6 to the spacetime curvature (in a model suggested by Yokoyama in order to evade the millisecond pulsar constraint on cosmic strings) are expected to be strongly type I

  13. Effect of the RE (RE = Eu, Er) doping on the structural and textural properties of mesoporous TiO{sub 2} thin films obtained by evaporation induced self-assembly method

    Energy Technology Data Exchange (ETDEWEB)

    Borlaf, Mario, E-mail: mborlaf@icv.csic.es [Instituto de Cerámica y Vidrio, CSIC, C/Kelsen, 5, Cantoblanco, E-28049 Madrid (Spain); Caes, Sebastien; Dewalque, Jennifer [LCIS-GREENMAT, Institute of Chemistry, University of Liege, B6 Sart Tilman, 4000 Liege (Belgium); Colomer, María Teresa; Moreno, Rodrigo [Instituto de Cerámica y Vidrio, CSIC, C/Kelsen, 5, Cantoblanco, E-28049 Madrid (Spain); Cloots, Rudi; Boschini, Frederic [LCIS-GREENMAT, Institute of Chemistry, University of Liege, B6 Sart Tilman, 4000 Liege (Belgium); APTIS, Institute of Physics, University of Liege, B5 Sart Tilman, 4000 Liege (Belgium)

    2014-05-02

    Polymeric sol–gel route has been used for the preparation of TiO{sub 2} and RE{sub 2}O{sub 3–}TiO{sub 2} (RE = Eu, Er) mesoporous thin films by evaporation induced self-assembly method using Si (100) as a substrate. The influence of the relative humidity (RH) on the preparation of the film has been studied being necessary to work under 40% RH in order to obtain homogeneous and transparent thin films. The films were annealed at different temperatures until 900 °C/1 h and the anatase crystallization and its crystal size evolution were followed by low angle X-ray diffraction. Neither the anatase–rutile transition nor the formation of other compounds was observed in the studied temperature range. Ellipsoporosimetry studies demonstrated that the thickness of the thin films did not change after calcination at 500 °C, the porosity was constant until 700 °C, the pore size increased and the specific surface area decreased with temperature. Moreover, the effect of the doping with Er{sup 3+} and Eu{sup 3+} was studied and a clear inhibition of the crystal growth and the sintering process was detected (by transmission electron and atomic force microscopy) when the doped films are compared with the undoped ones. Finally, Eu{sup 3+} and Er{sup 3+} f–f transitions were detected by PL measurements. - Highlights: • Eu and Er–TiO{sub 2} mesoporous films were prepared by evaporation induced self-assembly. • Influence of humidity on porosity and photoluminescent properties has been tested. • Influence of calcination on structural and textural properties has been also studied. • f–f transitions indicate that the thin films are active photoluminescent materials.

  14. Texture dependent lattice strains and texture gradient in AI7020

    Science.gov (United States)

    Y Zhong, Z.; Brokmeier, H.-G.; Maawad, E.; Schell, N.

    2015-04-01

    Firstly, an Al7020 block was characterized by the texture gradient, which was remarkably strong. Texture sharpness in the center with about 30 mrd (multiple random distribution) shows typical plain strain texture components. On the surface and close to the surface the texture sharpness is much weaker showing also shear components. Strongest shear was not directly at the surface but 4 mm deeper. The texture analysis at HEMS Beamline (Petra III/DESY-Hamburg) was done with continuous scanning mode to include all grains to improve the grain statistics. Secondly, with an in situ synchrotron experiment the texture dependent lattice strain behavior was investigated using flat tensile samples oriented 0°, 45° and 90° to the rolling direction (RD). Texture induced anisotropy influenced on the lattice dependent yield strength and the lattice dependent stress-strain behavior, which will be discussed in detail. Due to the high energy synchrotron beam complete Debye-Scherrer rings were obtained so that the patterns, parallel and perpendicular to loading direction (LD), were obtained simultaneously.

  15. Aesthetic Perception of Visual Textures: A Holistic Exploration using Texture Analysis, Psychological Experiment and Perception Modeling

    Directory of Open Access Journals (Sweden)

    Jianli eLiu

    2015-11-01

    Full Text Available Modeling human aesthetic perception of visual textures is important and valuable in numerous industrial domains, such as product design, architectural design and decoration. Based on results from a semantic differential rating experiment, we modeled the relationship between low-level basic texture features and aesthetic properties involved in human aesthetic texture perception. First, we compute basic texture features from textural images using four classical methods. These features are neutral, objective and independent of the socio-cultural context of the visual textures. Then, we conduct a semantic differential rating experiment to collect from evaluators their aesthetic perceptions of selected textural stimuli. In semantic differential rating experiment, eights pairs of aesthetic properties are chosen, which are strongly related to the socio-cultural context of the selected textures and to human emotions. They are easily understood and connected to everyday life. We propose a hierarchical feed-forward layer model of aesthetic texture perception and assign 8 pairs of aesthetic properties to different layers. Finally, we describe the generation of multiple linear and nonlinear regression models for aesthetic prediction by taking dimensionality-reduced texture features and aesthetic properties of visual textures as dependent and independent variables, respectively. Our experimental results indicate that the relationships between each layer and its neighbors in the hierarchical feed-forward layer model of aesthetic texture perception can be fitted well by linear functions, and the models thus generated can successfully bridge the gap between computational texture features and aesthetic texture properties.

  16. Strong energy-momentum dispersion of phonon-dressed carriers in the lightly doped band insulator SrTiO3

    International Nuclear Information System (INIS)

    Meevasana, W; Chen, C-C; He, R H; Mo, S-K; Shen, Z-X; Zhou, X J; Moritz, B; Lu, D H; Moore, R G; Devereaux, T P; Fujimori, S-I; Baumberger, F; Van der Marel, D; Nagaosa, N; Zaanen, J

    2010-01-01

    Much progress has been made recently in the study of the effects of electron-phonon (el-ph) coupling in doped insulators using angle-resolved photoemission (ARPES), yielding evidence for the dominant role of el-ph interactions in underdoped cuprates. As these studies have been limited to doped Mott insulators, the important question arises as to how this compares with doped band insulators where similar el-ph couplings should be at work. The archetypical case is that of perovskite SrTiO 3 (STO), well known for its giant dielectric constant of 10 000 at low temperatures, exceeding that of La 2 CuO 4 by a factor of 500. Based on this fact, it has been suggested that doped STO should be the archetypical bipolaron superconductor. Here we report an ARPES study from high-quality surfaces of lightly doped STO. In comparison to lightly doped Mott insulators, we find the signatures of only moderate el-ph coupling; a dispersion anomaly associated with the low-frequency optical phonon with a λ ' ∼0.3 and an overall bandwidth renormalization suggesting an overall λ ' ∼0.7 coming from the higher frequency phonons. Furthermore, we find no clear signatures of the large pseudogap or small-polaron phenomena. These findings demonstrate that a large dielectric constant itself is not a good indicator of el-ph coupling and highlight the unusually strong effects of the el-ph coupling in doped Mott insulators.

  17. Caracterização textural e estrutural de V2O5/TiO2 obtidos via sol-gel: comparação entre secagem convencional e supercrítica Textural and structural characterization of V2O5/TiO2 catalysts obtained by the sol-gel method: comparison between conventional and supercritical drying

    Directory of Open Access Journals (Sweden)

    Cristiane B. Rodella

    2002-05-01

    Full Text Available This work describes a modified sol-gel method for the preparation of V2O5/TiO2 catalysts. The samples have been characterized by N2 adsorption at 77K, x-ray diffractometry (XRD and Fourier Transform Infrared (FT-IR. The surface area increases with the vanadia loading from 24 m² g-1, for pure TiO2, to 87 m² g-1 for 9wt.% of V2O5. The rutile form is predominant for pure TiO2 but became enriched with anatase phase when vanadia loading is increased. No crystalline V2O5 phase was observed in the catalysts diffractograms. Two species of surface vanadium observed by FT-IR spectroscopy a monomeric vanadyl and polymeric vanadates, the vanadyl/vanadate ratio remains practically constant.

  18. TiB2-Based Composites for Ultra-High-Temperature Devices, Fabricated by SHS, Combining Strong and Weak Exothermic Reactions

    Directory of Open Access Journals (Sweden)

    Marta Ziemnicka-Sylwester

    2013-05-01

    Full Text Available TiB2-based ceramic matrix composites (CMCs were fabricated using elemental powders of Ti, B and C. The self-propagating high temperature synthesis (SHS was carried out for the highly exothermic “in situ” reaction of TiB2 formation and the “tailing” synthesis of boron carbide characterized by weak exothermicity. Two series of samples were fabricated, one of them being prepared with additional milling of raw materials. The effects of TiB2 vol fraction as well as grain size of reactant were investigated. The results revealed that combustion was not successful for a TiB2:B4C molar ratio of 0.96, which corresponds to 40 vol% of TiB2 in the composite, however the SHS reaction was initiated and self-propagated for the intended TiB2:B4C molar ratio of 2.16 or above. Finally B13C2 was formed as the matrix phase in each composite. Significant importance of the grain size of the C precursor with regard to the reaction completeness, which affected the microstructure homogeneity and hardness of investigated composites, was proved in this study. The grain size of Ti powder did not influence the microstructure of TiB2 grains. The best properties (HV = 25.5 GPa, average grain size of 9 μm and homogenous microstructure, were obtained for material containing 80 vol% of TiB2, fabricated using a graphite precursor of 2 μm.

  19. FCC Rolling Textures Reviewed in the Light of Quantitative Comparisons between Simulated and Experimental Textures

    DEFF Research Database (Denmark)

    Wierzbanowski, Krzysztof; Wroński, Marcin; Leffers, Torben

    2014-01-01

    The crystallographic texture of metallic materials has a very strong effect on the properties of the materials. In the present article, we look at the rolling textures of fcc metals and alloys, where the classical problem is the existence of two different types of texture, the "copper-type texture......} slip without or with deformation twinning, but we also consider slip on other slip planes and slip by partial dislocations. We consistently make quantitative comparison of the simulation results and the experimental textures by means of a scalar correlation factor. We find that the development...

  20. Enhanced texture evolution and piezoelectric properties in CuO-doped Pb(In1/2Nb1/2)O3-Pb(Mg1/3Nb2/3)O3-PbTiO3 grain-oriented ceramics

    Science.gov (United States)

    Chang, Yunfei; Watson, Beecher; Fanton, Mark; Meyer, Richard J.; Messing, Gary L.

    2017-12-01

    In this work, both crystallographic texture and doping engineering strategies were integrated to develop relaxor-PbTiO3 (PT) based ternary ferroelectric ceramics with enhanced texture evolution and superior electromechanical properties. CuO-doped Pb(In1/2Nb1/2)O3-Pb(Mg1/3Nb2/3)O3-PbTiO3 (PIN-PMN-PT) piezoelectric ceramics with [001]c texture fraction ≥97% were synthesized by templated grain growth. The addition of CuO significantly promotes densification and oriented grain growth in the templated ceramics, leading to full texture development at dramatically reduced times and temperatures. Moreover, the CuO dopant remarkably enhances the piezoelectric properties of the textured ceramics while maintaining high phase transition temperatures and large coercive fields. Doping 0.125 wt. % CuO yields the electromechanical properties of d33 = 927 pC/N, d33* = 1510 pm/V, g33 = 43.2 × 10-3 Vm/N, Kp = 0.87, Ec=8.8 kV/cm, and tan δ = 1.3%, which are the best values reported so far in PIN-PMN-PT based ceramics. The high piezoelectric coefficient is mainly from the reversible piezoelectric response, with the irreversible contribution being on the order of 13.1%. We believe that this work not only facilitates closing the performance gap between ceramics and single crystals but also can expand relaxor-PT based piezoelectric application fields.

  1. Colloidal aspects of texture perception

    NARCIS (Netherlands)

    Vliet, van T.

    2010-01-01

    The perception of complex textures in food is strongly related to the way food is processed during eating, and is modulated by other basic characteristics, such as taste and aroma. An understanding at the colloidal level of the basic processes in the mouth is essential in order to link the

  2. Colloidal aspects of texture perception

    NARCIS (Netherlands)

    Vliet, T. van; Aken, G.A. van; Jongh, H.H.J. de; Hamer, R.J.

    2009-01-01

    Recently, considerable attention has been given to the understanding of texture attributes that cannot directly be related to physical properties of food, such as creamy, crumbly and watery. The perception of these attributes is strongly related to the way the food is processed during food intake,

  3. Structural evolution of Ti/TiC multilayers

    International Nuclear Information System (INIS)

    Dahan, I.; Frage, N.; Dariel, M.P.

    2004-01-01

    Hard coatings based on metal/ceramic multilayers with periods in the nanometer range have been shown to possess some potential for improved tribological and mechanical properties. The present work is concerned with the structural evolution of (Ti/TiC) multilayers. Two kinds of multilayers consisting of 30 equithick (40 nm)TiC layers and 20 and 60 nm thick Ti layers, respectively, were sputter deposited on Mo substrates. The structural and the compositional evolution of these multilayers were examined by x-ray diffraction, transition electron microscopy (TEM), high-resolution TEM, Auger electron microscopy spectroscopy and differential thermal analysis (DTA), in the as-deposited state and after various heat treatments up to 500 deg. C. Initially, the Ti layers had a crystalline columnar grain structure displaying a (002) texture. The TiC layers displayed weak crystallinity with a pronounced (111) texture. In the course of the heat treatments, carbon diffused from the carbide layer into the adjacent Ti layers transforming the latter into off-stoichiometric TiC x with x≅0.5 and simultaneously depleting the carbon content of the initial carbide layer. The formed TiC x layers maintained the textural relationship with the neighboring TiC layers, consistent with a transformation that involved only a ABAB to ABC stacking change of the Ti sublattice. Increased mobility of the Ti atoms in carbon-depleted original TiC layers led to their full or partial recrystallization. The thermal effects associated both with the transformation of Ti layers into TiC, due to the influx of carbon atoms, and with the recrystallization of the original TiC layers were clearly revealed by the DTA measurements

  4. Role of the substrate on the growth of Ni-Ti sputtered thin films

    Energy Technology Data Exchange (ETDEWEB)

    Martins, R.M.S. [Forschungszentrum Rossendorf, P.O. Box 510119, D-01314 Dresden (Germany)], E-mail: rui.martins@esrf.fr; Schell, N.; Beckers, M. [Forschungszentrum Rossendorf, P.O. Box 510119, D-01314 Dresden (Germany); Silva, R.J.C.; Mahesh, K.K.; Fernandes, F.M. Braz [CENIMAT, Campus da FCT/UNL, 2829-516 Monte de Caparica (Portugal)

    2008-05-25

    Ni-Ti thin films have been recognized as promising and high performance materials in the field of microelectromechanical system applications. However, important issues like formation of film texture and its control are still unresolved. Widening the scope of previous experiments concerning the influence of the deposition parameters on the Ni-Ti films structure, here we show how different crystallographic orientations can be obtained by changing the substrate type. The growth of near-equiatomic Ni-Ti films, deposited by magnetron co-sputtering from Ni-Ti and Ti targets on heated substrates ({approx}470 deg. C), has been studied in situ by X-ray diffraction at a synchrotron radiation beamline. As mentioned in other studies for depositions on Si{sub 100}, a 1 1 0 fiber texture is observed for the B2 phase. However, a preferential stacking of 1 0 0 planes of the B2 phase parallel to the film surface was observed when using a MgO{sub 100} substrate. The preferential orientation of B2{sub 100}||MgO{sub 100} was very strong and was kept as such until the end of the deposition, which lasted for 7.2 ks ({approx}900 nm). Ni-Ti films were also deposited on a TiN layer ({approx}15 nm) previously deposited on top of a SiO{sub 2}/Si{sub 100} substrate. In this case, a crossover from 1 1 0 oriented grains dominating at small thicknesses, to 2 1 1 oriented grains taking over at larger thicknesses was observed. These are promising results concerning the manipulation of the crystallographic orientations of Ni-Ti thin films, since the texture has a strong influence on the extent of the strain recovery.

  5. Titanium: light, strong, and white

    Science.gov (United States)

    Woodruff, Laurel; Bedinger, George

    2013-01-01

    Titanium (Ti) is a strong silver-gray metal that is highly resistant to corrosion and is chemically inert. It is as strong as steel but 45 percent lighter, and it is twice as strong as aluminum but only 60 percent heavier. Titanium dioxide (TiO2) has a very high refractive index, which means that it has high light-scattering ability. As a result, TiO2 imparts whiteness, opacity, and brightness to many products. ...Because of the unique physical properties of titanium metal and the whiteness provided by TiO2, titanium is now used widely in modern industrial societies.

  6. BREAD CRUMBS TEXTURE OF SPELT

    Directory of Open Access Journals (Sweden)

    Joanna Korczyk – Szabó

    2014-02-01

    Full Text Available Texture analysis is an objective physical examination of baked products and gives direct information on the product quality, oppositely to dough rheology tests what inform on the baking suitability of the flour, as raw material. Evaluation of the mechanical properties of bread crumb is important not only for quality assurance in the bakeries, but also for assessing the effects of changes in dough ingredients and processing condition and also for describing the changes in bread crumb during storage. Crumb cellular structure is an important quality criterion used in commercial baking and research laboratories to judge bread quality alongside taste, crumb colour and crumb physical texture. In the framework of our research during the years 2010 – 2011 were analyzed selected indicators of bread crumb for texture quality of three Triticum spelta L. cultivars – Altgold, Rubiota and Ostro grown in an ecological system. The bread texture quality was evaluated on texture analyzer TA.XT Plus (Stable Micro Systems, Surrey, UK, following the AACC (74-09 standard and expressed as crumb firmness (N, stiffness (N.mm-1 and relative elasticity (%. Our research proved that all selected indicators were significantly influenced by the year of growing and variety. The most soft bread was achieved in Rubiota, whereas bread crumb samples from Altgold and Ostro were the most firm and stiff. Correlation analysis showed strong negative correlation between relative elasticity and bread crumb firmness as well as bread stiffness (-0.65++, -0.66++. The spelt wheat bread crumb texture need further investigation as it can be a reliable quality parameter.

  7. Investigation on the effect of chemical composition on the texture and bake hardening I F steels

    International Nuclear Information System (INIS)

    Kariman, M.; Motaghi, A.; Raygan, Sh.; Habibi Parsa, M.; Nili Ahmadabadi, M.

    2008-01-01

    Interstitial free steels have good formability and also excellent deep draw ability. These features make them one of the applicable materials in automotive industry. Chemical composition and thermomechanical treatment used to process these steels have important role in final properties of them. In this study, the effect of chemical composition on texture, anisotropic properties and bake harden ability of these steels were investigated. The results showed that contribution of vanadium as a weak carbonitride former element with titanium as strong carbonitride former could change the texture of steels. Replacing titanium with vanadium caused harmful effect on mechanical properties. In this research deep drawing properties of five steels were compared based on I {111} / I{001} and I {111} / I{110} parameters. The results of bake harden ability test showed that there were critical limits for vanadium volume fractions above which bake harden properties was improved. It was shown that the bake harden properties of Nb-steels were better than that of Ti-steels. This was due to the better solution of Nb(C,N) compared to Ti(C,N). Addition of vanadium to Ti-steels may improve bake harden properties of I F steels

  8. Crystallographic Texture in Ceramics and Metals.

    Science.gov (United States)

    Vaudin, M D

    2001-01-01

    Preferred crystallographic orientation, or texture, occurs almost universally, both in natural and man-made systems. Many components and devices in electronic and magnetic systems are fabricated from materials that have crystallographic texture. With the rapidly increasing use of thin film technology, where sharp axisymmetric crystallographic texture normal to the film plane is frequently observed, the occurrence and impact of texture are rising. Thin film applications in which the texture of the material plays a key role in determining properties and performance are broad: complex oxides in random access memory devices, ZnO thin film resonators for cell phone applications, metallic alloys in magnetic recording media, and Al and Cu interconnects in integrated circuits are but a few examples. Texture is established during the synthesis or post-synthesis heat treatment of a material and thus has a strong dependence upon processing history. Accurate measurement of texture is not simple and a variety of tools and approaches are being actively employed in texture studies. X-ray, neutron and electron diffraction based techniques are practiced around the world at varying levels of complexity with regard to equipment and analysis methods. Despite the well-documented existence of these varied approaches, many reported texture measurements on electronic materials are based solely on the relative intensities of conventional θ-2θ x-ray diffraction peaks, which typically yield inaccurate results. NIST has developed quantitative texture measurement techniques that employ equipment commonly available in most industrial and academic settings. A number of examples of texture measurement in ceramic and metal systems will be presented, taken from the historical development and application of these techniques at NIST over the past 7 years.

  9. Effects of Ti addition on LFZ Bi-2212 thin rods

    Directory of Open Access Journals (Sweden)

    Angurel, L. A.

    2003-06-01

    Full Text Available In order to reproduce previous results in Bi-2212 single crystals, the effects associated with the addition of Ti to the precursors of Laser Floating Zone textured Bi-2212 thin rods have been analyzed. It has been found that Ti induces a great number of nucleation centers in the molten zone and, in consequence, it reduces the grain size one order of magnitude. In addition, using the same growth conditions, the texture of the sample is strongly degraded. These microstructural changes strongly affect the superconducting properties showing that Ti addition destroys the network of low angle grain boundaries that are responsible for the high critical currents in these materials.

    Se ha analizado el efecto de la introducción de Ti en precursores de Bi-2212 para ser texturados mediante láser a través del método de zona flotante, todo ello debido a los resultados esperanzadores obtenidos en monocristales. Se ha encontrado que el Ti introduce un gran número de centros de nucleación en la zona fundida, por lo que se reducen las dimensiones de los granos en un orden de magnitud aproximadamente. Por otra parte, y utilizando las mismas condiciones de crecimiento, se observa que la textura de la muestra se degrada severamente, Estos cambios microestructurales afectan en gran medida a las propiedades superconductoras, demostrándose que la introducción de Ti destruye la red de fronteras de grano de bajo ángulo, que son las responsables en estos materiales de las altas corrientes criticas.

  10. Texture and neutron diffraction

    International Nuclear Information System (INIS)

    Szpunar, J.

    1976-01-01

    The neutron diffraction method has only recently become a tool for studying the structure of polycrystalline materials. There are some fields such as texture studies where this method offers several advantages over other more common methods. Texture is the main subject of the review. The current status of the theory or deformation and recrystallization texture is discussed briefly. Texture is then described with the aid of the ODF function. Finally, applications of the neutron diffraction method are discussed using several examples of textures measured in metals and in non-metallic materials. Other, less known applications of neutron diffraction are also given, e.g. in stress measurements. The neutron diffraction method is extremely useful for studying the texture of coarse-grained materials. This method provides information on the average texture in a large volume. This enables one to measure texture in the same specimen in which anisotropy of the physical roperties has been measured. Selected examples are provided in which correlations between elastic, plastic and magnetic properties of polycrystalline materials and their texture are pointed out. Texture was measured in all these cases using the neutron diffraction method. (author)

  11. Strong magnetoelectric coupling in CoFe2O4-BaTiO3 composites prepared by molten-salt synthesis method

    International Nuclear Information System (INIS)

    Nie Junwu; Xu Guoyue; Yang Ying; Cheng Chuanwei

    2009-01-01

    Magnetoelectric nano-composites (1 - x)CoFe 2 O 4 + (x)BaTiO 3 with x varies as 0, 0.5, 0.65 and 1.0 in molar ratio were prepared by molten-salt synthesis method. The structural analysis carried out by X-ray diffraction (XRD) technique has confirmed that both phases are present in all the nano-composites powders and ceramic composites. The TEM images show that the nano-particle crystallite size is about 50-80 nm, which is consistent to the result calculated by XRD. The dielectric constant was studied as a function of frequency for ceramic composites sintered by using those nano-composite powders. The saturation magnetization (Ms) and remnant polarization (Pr) were calculated from the magnetic hysteresis loop and electric hysteresis loop, respectively. And a large ME coefficient of about 17.04 mV cm -1 Oe -1 was observed for 0.5CoFe 2 O 4 + 0.5BaTiO 3 ME composite under the ac superimposed magnetic signal with 20 kHz frequency by using the lock-in technique

  12. Aspects of electron-phonon interactions with strong forward scattering in FeSe Thin Films on SrTiO3 substrates

    Science.gov (United States)

    Wang, Y.; Nakatsukasa, K.; Rademaker, L.; Berlijn, T.; Johnston, S.

    2016-05-01

    Mono- and multilayer FeSe thin films grown on SrTiO3 and BiTiO3 substrates exhibit a greatly enhanced superconductivity over that found in bulk FeSe. A number of proposals have been advanced for the mechanism of this enhancement. One possibility is the introduction of a cross-interface electron-phonon (e-ph) interaction between the FeSe electrons and oxygen phonons in the substrates that is peaked in the forward scattering (small {q}) direction due to the two-dimensional nature of the interface system. Motivated by this, we explore the consequences of such an interaction on the superconducting state and electronic structure of a two-dimensional system using Migdal-Eliashberg (ME) theory. This interaction produces not only deviations from the expectations of conventional phonon-mediated pairing but also replica structures in the spectral function and density of states, as probed by angle-resolved photoemission spectroscopy, scanning tunneling microscopy/spectroscopy, and quasiparticle interference imaging. We also discuss the applicability of ME theory for a situation where the e-ph interaction is peaked at small momentum transfer and in the FeSe/STO system.

  13. Synthesis and characterization of Sn doped TiO{sub 2} photocatalysts: Effect of Sn concentration on the textural properties and on the photocatalytic degradation of 2,4-dichlorophenoxyacetic acid

    Energy Technology Data Exchange (ETDEWEB)

    Rangel-Vázquez, I.; Del Angel, G.; Bertin, V. [Departamento de Química, Universidad Autónoma Metropolitana-Iztapalapa, Av. San Rafael, Atlixco No 1865, México 09340 D.F. (Mexico); González, F. [Departamento de Ingeniería de Procesos e Hidráulica, Universidad Autónoma Metropolitana-Iztapalapa, Av. San Rafael, Atlixco No 1865, México 09340 D.F. (Mexico); Vázquez-Zavala, A.; Arrieta, A. [Departamento de Química, Universidad Autónoma Metropolitana-Iztapalapa, Av. San Rafael, Atlixco No 1865, México 09340 D.F. (Mexico); Padilla, J.M. [Universidad Tecnológica del Centro de Veracruz, Área de Tecnología, Av. Universidad Carretera Federal Cuitláhuac-La Tinaja No. 350, Cuitláhuac, Veracruz 94910 (Mexico); Barrera, A. [Universidad de Guadalajara, Centro Universitario de la Ciénega, Av. Universidad, Número 1115, Col. Linda Vista, Apdo. Postal 106, Ocotlán Jal. (Mexico); Ramos-Ramirez, E. [Departamento de Química, División de Ciencias Naturales y Exactas, Campus Guanajuato de la Universidad de Guanajuato Noria Alta S/N, Col. Noria Alta, Guanajuato, Gto. C.P. 36050 (Mexico)

    2015-09-15

    Abstract: TiO{sub 2} and Sn-doped TiO{sub 2} materials were prepared by sol–gel method using titanium and tin alkoxides at different Sn concentration (0.1 mol%, 0.5 mol%, 1 mol%, 3 mol% and 5 mol%). Samples were characterized by thermo gravimetric analyzer with differential scanning calorimeter (TGA–DSC), X-ray Rietveld refinement, N{sub 2} adsorption (BET), transmission electron microscopy (TEM), UV–vis spectroscopies technology and Raman spectroscopy. Only anatase phase was observed in pure TiO{sub 2}, whereas anatase and brookite were obtained in Sn-doped TiO{sub 2} samples. Sn dopant acts as a promoter in phase transformation of TiO{sub 2}. The Rietveld refinements method was used to determine the relative weight of anatase and brookite, and crystallite size as a function of Sn concentration after calcination of samples at 673 K. It was also demonstrated the incorporation of Sn{sup 4+} into the anatase TiO{sub 2} structure. Sn{sup 4+} inhibits the growth of TiO{sub 2} crystallite size, which leads to an increase of the specific surface area of TiO{sub 2}. From XRD analysis, the solid solution limit of Sn{sup 4+} into TiO{sub 2} is 5 mol% Sn. The photocatalytic activity on Sn{sup 4+} doped TiO{sub 2} was determined for the 2,4-dichlorophenoxyacetic acid reaction. The maximum in activity was attributed to the coexistence of anatase and brookite phases in the appropriate ratio and crystallite size.

  14. Nanocrystal Size-Dependent Efficiency of Quantum Dot Sensitized Solar Cells in the Strongly Coupled CdSe Nanocrystals/TiO2 System.

    Science.gov (United States)

    Yun, Hyeong Jin; Paik, Taejong; Diroll, Benjamin; Edley, Michael E; Baxter, Jason B; Murray, Christopher B

    2016-06-15

    Light absorption and electron injection are important criteria determining solar energy conversion efficiency. In this research, monodisperse CdSe quantum dots (QDs) are synthesized with five different diameters, and the size-dependent solar energy conversion efficiency of CdSe quantum dot sensitized solar cell (QDSSCs) is investigated by employing the atomic inorganic ligand, S(2-). Absorbance measurements and transmission electron microscopy show that the diameters of the uniform CdSe QDs are 2.5, 3.2, 4.2, 6.4, and 7.8 nm. Larger CdSe QDs generate a larger amount of charge under the irradiation of long wavelength photons, as verified by the absorbance results and the measurements of the external quantum efficiencies. However, the smaller QDs exhibit faster electron injection kinetics from CdSe QDs to TiO2 because of the high energy level of CBCdSe, as verified by time-resolved photoluminescence and internal quantum efficiency results. Importantly, the S(2-) ligand significantly enhances the electronic coupling between the CdSe QDs and TiO2, yielding an enhancement of the charge transfer rate at the interfacial region. As a result, the S(2-) ligand helps improve the new size-dependent solar energy conversion efficiency, showing best performance with 4.2-nm CdSe QDs, whereas conventional ligand, mercaptopropionic acid, does not show any differences in efficiency according to the size of the CdSe QDs. The findings reported herein suggest that the atomic inorganic ligand reinforces the influence of quantum confinement on the solar energy conversion efficiency of QDSSCs.

  15. Measurement of Color Texture

    NARCIS (Netherlands)

    Hoang, M.A.; Geusebroek, J.M.; Deprettere, E.F.; Belloum, A.; Heijnsdijk, J.W.J.; van der Stappen, F.

    2002-01-01

    In computer vision, measurement of image properties such as color or texture is essential. However, existing methods for measuring color and texture in combination are not well-defined neither from a measurement theoretical basis nor from a physical point of view. We propose a solid framework for

  16. Textured perovskite cells

    NARCIS (Netherlands)

    Deelen, J. van; Tezsevin, Y.; Barink, M.

    2017-01-01

    Most research of texturization of solar cells has been devoted to Si based cells. For perovskites, it was assumed that texturization would not have much of an impact because of the relatively low refractive indexes lead to relatively low reflection as compared to the Si based cells. However, our

  17. Mimicking human texture classification

    NARCIS (Netherlands)

    Rogowitz, B.E.; van Rikxoort, Eva M.; van den Broek, Egon; Pappas, T.N.; Schouten, Theo E.; Daly, S.J.

    2005-01-01

    In an attempt to mimic human (colorful) texture classification by a clustering algorithm three lines of research have been encountered, in which as test set 180 texture images (both their color and gray-scale equivalent) were drawn from the OuTex and VisTex databases. First, a k-means algorithm was

  18. Mechanical properties of ion-beam-textured surgical implant alloys

    Science.gov (United States)

    Weigand, A. J.

    1977-01-01

    An electron-bombardment Hg ion thruster was used as an ion source to texture surfaces of materials used to make orthopedic and/or dental prostheses or implants. The materials textured include 316 stainless steel, titanium-6% aluminum, 4% vanadium, and cobalt-20% chromium, 15% tungsten. To determine the effect of ion texturing on the ultimate strength and yield strength, stainless steel and Co-Cr-W alloy samples were tensile tested to failure. Three types of samples of both materials were tested. One type was ion-textured (the process also heats each sample to 300 C), another type was simply heated to 300 C in an oven, and the third type was untreated. Stress-strain diagrams, 0.2% offset yield strength data, total elongation data, and area reduction data are presented. Fatigue specimens of ion textured and untextured 316 stainless steel and Ti-6% Al-4% V were tested. Included as an ion textured sample is a Ti-6% Al-4% V sample which was ion machined by means of Ni screen mask so as to produce an array of 140 mu m x 140 mu m x 60 mu m deep pits. Scanning electron microscopy was used to characterize the ion textured surfaces.

  19. Texture of uniaxial compressed two-phase titanium-aluminides

    International Nuclear Information System (INIS)

    Bermig, G.; Tobisch, J.; Brokmeier, H.G.; Wurzwallner, K.

    1993-01-01

    Texture is, among others, an essential parameter to document the different states of a polycrystalline material from production to application. Therefore, texture studies were carried out in γ-base titanium aluminide series, Ti-48at%Al and Ti-48at%Al-2at%Cr, in order to describe their microstructural changes during uniaxial compression. The fabrication of the material started by casting an ingot of the desired composition. After hot isostatic pressing (HIP) the specimens were deformed up to 77% with a compression rate of ∼ 10mm/s, X-ray diffraction and microscopical investigations confirm the expected two-phase material composition of tetragonal γ-Tial and hexagonal α 2 -Ti 3 Al respectively. The texture measurements were carried out by X-ray as well as by neutron diffraction. A comparison of both techniques is necessary in order to document that only a combination of X-ray and neutron diffraction allows to obtain the whole texture information of all samples. Finally, the determined textures are discussed in correlation with deformation. (orig.)

  20. Textures and ores structure

    International Nuclear Information System (INIS)

    Khasanov, A.Kh.

    1988-01-01

    In this part of book author made conclusion that structural-texture particularities reflect the physical and chemical conditions, velocity of minerals crystallization, further tectonic situation, presence appearances of meta-somatic substitution, second decomposition and minerals leaching

  1. Methods of making textured catalysts

    Science.gov (United States)

    Werpy, Todd [West Richland, WA; Frye, Jr., John G.; Wang, Yong [Richland, WA; Zacher, Alan H [Kennewick, WA

    2010-08-17

    A textured catalyst having a hydrothermally-stable support, a metal oxide and a catalyst component is described. Methods of conducting aqueous phase reactions that are catalyzed by a textured catalyst are also described. The invention also provides methods of making textured catalysts and methods of making chemical products using a textured catalyst.

  2. Theory of magnetoelectric coupling in 2-2-type magnetostrictive/piezoelectric composite film with texture

    International Nuclear Information System (INIS)

    Liu Chaoqian; Fei Weidong; Li Weili

    2008-01-01

    It is well accepted that textures in polycrystalline films have significant effects on film properties. The magnetoelectric (ME) coupling in a 2-2-type multiferroic composite film was theoretically discussed using Landau-Ginsburg-Devonshire theory, where the influences of dispersive texture and residual stress were considered. As an example, the 2-2-type CoFe 2 O 4 /BaTiO 3 composite film was theoretically analysed, wherein the case of both the magnetostrictive phase and the piezoelectric phase with (0 0 1)-oriented texture was considered. Our results show that the ME coupling is enhanced with the texture degree of the piezoelectric phase and/or the magnitude of the residual tensile stress, but weakened with the magnitude of residual compressive stress. With increasing texture degree of the magnetostrictive phase, the ME coupling is enhanced when the texture degree is smaller than a critical value, but weakened when the texture degree is larger than the critical value

  3. Computer Texture Mapping for Laser Texturing of Injection Mold

    Directory of Open Access Journals (Sweden)

    Yongquan Zhou

    2014-04-01

    Full Text Available Laser texturing is a relatively new multiprocess technique that has been used for machining 3D curved surfaces; it is more flexible and efficient to create decorative texture on 3D curved surfaces of injection molds so as to improve the surface quality and achieve cosmetic surface of molded plastic parts. In this paper, a novel method of laser texturing 3D curved surface based on 3-axis galvanometer scanning unit has been presented to prevent the texturing of injection mold surface from much distortion which is often caused by traditional texturing processes. The novel method has been based on the computer texture mapping technology which has been developed and presented. The developed texture mapping algorithm includes surface triangulation, notations, distortion measurement, control, and numerical method. An interface of computer texture mapping has been built to implement the algorithm of texture mapping approach to controlled distortion rate of 3D texture math model from 2D original texture applied to curvature surface. Through a case study of laser texturing of a high curvature surface of injection mold of a mice top case, it shows that the novel method of laser texturing meets the quality standard of laser texturing of injection mold.

  4. Ion-beam texturing of uniaxially textured Ni films

    International Nuclear Information System (INIS)

    Park, S.J.; Norton, D.P.; Selvamanickam, Venkat

    2005-01-01

    The formation of biaxial texture in uniaxially textured Ni thin films via Ar-ion irradiation is reported. The ion-beam irradiation was not simultaneous with deposition. Instead, the ion beam irradiates the uniaxially textured film surface with no impinging deposition flux, which differs from conventional ion-beam-assisted deposition. The uniaxial texture is established via a nonion beam process, with the in-plane texture imposed on the uniaxial film via ion beam bombardment. Within this sequential ion beam texturing method, grain alignment is driven by selective etching and grain overgrowth

  5. Texture transition in experimentally deformed quartzite

    Science.gov (United States)

    Kilian, Rüdiger; Heilbronner, Renée

    2017-04-01

    Quartz crystallographic preferred orientations (textures), most commonly presented in the form of pole figures, are often used to infer deformation processes or conditions - despite the fact that we still do not understand fully how the different types of texture are generated. Here, we re-analyse experimentally deformed Black Hills Quartzite using EBSD maps. Samples were deformed in general shear in the dislocation creep regimes 1 to 3 at temperatures ranging from 875 to 915°C, constant shear strain rates of 1e-5/s (Heilbronner & Tullis, 2006), and resulting flow stresses of (600 MPa ≥ Tau ≥ 100 MPa). Already at low strain, a strong alignment of in the shear plane and of {10-11} with the maximum principal stress direction is observed. [0001] pole figures of recrystallized grains in regime 1 exhibit a peripheral maximum, roughly perpendicular to the shear plane while in regime 3 two elongated maxima are formed very close to the kinematic y-direction. Regime 2 shows a mixture of these two texture types. In regime 1, dynamic recrystallization is dominated by bulging recrystallization (nucleation of new grains), and in regime 3 by subgrain rotation recrystallization. In regime 2, again a mixture of regime 1 and 3 can be observed. Texture strength increases with the amount of crystal plastic deformation and is generally the lowest for the texture type with peripheral [0001]. During crystal plastic deformation [0001] rotate towards the kinematic y-direction. The coexistence and transition from one to the other texture type is suggested to result from two different texture-forming processes. The first process is thought to be crystal plasticity by glide on various slip systems and associated rotation of the crystal lattice, with the attractor of [0001] close to - but not exactly parallel to - the kinematic y-direction. The second process is suggested to be the growth of oriented grains during bulging recrystallization and associated (fracturing and) grain boundary

  6. Austenitic Reversion of Cryo-rolled Ti-Stabilized Austenitic Stainless Steel: High-Resolution EBSD Investigation

    Science.gov (United States)

    Tiamiyu, A. A.; Odeshi, A. G.; Szpunar, J. A.

    2018-02-01

    In this study, AISI 321 austenitic stainless steel (ASS) was cryo-rolled and subsequently annealed at 650 and 800 °C to reverse BCC α'-martensite to FCC γ-austenite. The texture evolution associated with the reversion at the selected temperatures was investigated using high-resolution EBSD. After the reversion, TiC precipitates were observed to be more stable in 650 °C-annealed specimens than those reversed at 800 °C. {110} texture was mainly developed in specimens subjected to both annealing temperatures. However, specimens reversed at 650 °C have stronger texture than those annealed at 800 °C, even at the higher annealing time. The strong intensity of {110} texture component is attributed to the ability of AISI 321 ASS to memorize the crystallographic orientation of the deformed austenite, a phenomenon termed texture memory. The development of weaker texture in 800 °C-annealed specimens is attributed to the residual strain relief in grains, dissolution of grain boundary precipitates, and an increase in atomic migration along the grain boundaries. Based on the observed features of the reversed austenite grains and estimation from an existing model, it is suspected that the austenite reversion at 650 and 800 °C undergone diffusional and martensitic shear reversion, respectively.

  7. In situ texture analysis under applied load

    International Nuclear Information System (INIS)

    Brokmeier, H.G.

    2005-01-01

    The in-situ measurement of a crystallographic texture is a special type of a non-destructive measurement, which need special equipments. Due to the high photon flux and the excellent brilliance high energetic synchrotron radiations are a fantastic tool particular in fast experimentation. Moreover, a high penetration power allows the investigation of standard tensile sample of the DIN-norm. A loading device with a power up to 20 kN was installed at the hard wiggler beamline BW5 (HASYLAB-DESY) to perform in-situ strain and in-situ texture analysis. Using 100keV X-rays one gets short wavelength so that a 2D image-plate detector offers a wide range of diffraction pattern within the first 10 degree in 2 theta. Thermal neutron is another radiation with a high penetration power, which is the standard method for global texture analysis of bulk samples. As an example rectangular extruded Mg- Az31 was investigated by an in-situ. tensile experiment. Samples with 0 degree, 45 degree and 90 degree to the extrusion direction were cut. In-situ strain studies show the lattice dependent strains perpendicular and parallel to the loading direction. Moreover, in hexagonal Mg-Az31 a strong influence of the initial texture on the tensile behavior can be explained by the combination of texture simulation with in-situ measurements. (author)

  8. Texture analysis of

    NARCIS (Netherlands)

    Lubsch, A.; Timmermans, K.

    2017-01-01

    Texture analysis is a method to test the physical properties of a material by tension and compression. The growing interest in commercialisation of seaweeds for human food has stimulated research into the physical properties of seaweed tissue. These are important parameters for the survival of

  9. Texture affects color emotion

    NARCIS (Netherlands)

    Lucassen, M.P.; Gevers, T.; Gijsenij, A.

    2011-01-01

    Several studies have recorded color emotions in subjects viewing uniform color (UC) samples. We conduct an experiment to measure and model how these color emotions change when texture is added to the color samples. Using a computer monitor, our subjects arrange samples along four scales: warm-cool,

  10. Texture & Textiles, Together

    Science.gov (United States)

    Guhin, Paula

    2011-01-01

    Creating a painting with texture is easy, although using heavy gel medium or modeling paste may be pricey ways to go about it. High school artists generally like making collages and mixed-media. In this article, the author suggests ways to capitalize on that interest with inexpensive fabric in a painting project.

  11. Chameleons: Reptilian Texture

    Science.gov (United States)

    Petersen, Hugh

    2009-01-01

    This article presents an art project inspired by a drawing of a chameleon the author saw in an art-supply catalog. Chameleons prove to be a good subject to highlight shape, color and texture with eigth-graders. In this project, middle- and high-school students draw a chameleon, learn how to use shapes to add to their chameleon drawing, learn how…

  12. Texture studies using neutron diffraction

    International Nuclear Information System (INIS)

    Szpunar, J.A.

    1984-01-01

    Various aspects of the application of neutron scattering methods to texture studies are reviewed. The neutron method is compared with other methods of texture measurement and techniques of neutron diffraction registration of texture are discussed. Examples are presented of the use of neutron scattering for texture examination in materials having various grain sizes and degrees of structural inhomogeneity. It is also demonstrated that the information about texture can be used in the discussion of the deformation and recrystallization processes in metals. Neutron diffraction results are shown to be helpful in the examination of the influence of texture on the anisotropy of physical properties in materials. The possibility of neutron diffraction measurements of magnetic texture is reported. Finally the accuracy of texture measurements using the neutron method is discussed. (author)

  13. Magnetron sputtered Cu3N/NiTiCu shape memory thin film heterostructures for MEMS applications

    Science.gov (United States)

    Kaur, Navjot; Choudhary, Nitin; Goyal, Rajendra N.; Viladkar, S.; Matai, I.; Gopinath, P.; Chockalingam, S.; Kaur, Davinder

    2013-03-01

    In the present study, for the first time, Cu3N/NiTiCu/Si heterostructures were successfully grown using magnetron sputtering technique. Nanocrystalline copper nitride (Cu3N with thickness 200 nm) thin films and copper nanodots were subsequently deposited on the surface of 2-μm-thick NiTiCu shape memory thin films in order to improve the surface corrosion and nickel release properties of NiTiCu thin films. Interestingly, the phase transformation from martensite phase to austenite phase has been observed in Cu3N/NiTiCu heterostructures with corresponding change in texture and surface morphology of top Cu3N films. Field emission scanning electron microscopy and atomic force microscope images of the heterostructures reveals the formation of 20-nm-sized copper nanodots on NiTiCu surface at higher deposition temperature (450 °C) of Cu3N. Cu3N passivated NiTiCu films possess low corrosion current density with higher corrosion potential and, therefore, better corrosion resistance as compared to pure NiTiCu films. The concentration of Ni released from the Cu3N/NiTiCu samples was observed to be much less than that of pure NiTiCu film. It can be reduced to the factor of about one-ninth after the surface passivation resulting in smooth, homogeneous and highly corrosion resistant surface. The antibacterial and cytotoxicity of pure and Cu3N coated NiTiCu thin films were investigated through green fluorescent protein expressing E. coli bacteria and human embryonic kidney cells. The results show the strong antibacterial property and non cytotoxicity of Cu3N/NiTiCu heterostructure. This work is of immense technological importance due to variety of BioMEMS applications.

  14. Space-optimized texture atlases

    OpenAIRE

    Martínez Bayona, Jonàs

    2009-01-01

    Texture atlas parameterization provides an effective way to map a variety of colour and data attributes from 2D texture domains onto polygonal surface meshes. Most of the existing literature focus on how to build seamless texture atlases for continuous photometric detail, but little e ort has been devoted to devise e cient techniques for encoding self-repeating, uncontinuous signals such as building facades. We present a perception-based scheme for generating space-optimized texture ...

  15. Parallel-Sequential Texture Analysis

    NARCIS (Netherlands)

    van den Broek, Egon; Singh, Sameer; Singh, Maneesha; van Rikxoort, Eva M.; Apte, Chid; Perner, Petra

    2005-01-01

    Color induced texture analysis is explored, using two texture analysis techniques: the co-occurrence matrix and the color correlogram as well as color histograms. Several quantization schemes for six color spaces and the human-based 11 color quantization scheme have been applied. The VisTex texture

  16. Nonlinear operator for oriented texture

    NARCIS (Netherlands)

    Kruizinga, Peter; Petkov, Nikolay

    1999-01-01

    Texture is an important part of the visual world of animals and humans and their visual systems successfully detect, discriminate, and segment texture. Relatively recently progress was made concerning structures in the brain that are presumably responsible for texture processing. Neurophysiologists

  17. Application of TiN/TiO2 coatings on stainless steel: composition and mechanical reliability

    Science.gov (United States)

    Nikolova, M. P.; Genov, A.; Valkov, S.; Yankov, E.; Dechev, D.; Ivanov, N.; Bezdushnyi, R.; Petrov, P.

    2018-03-01

    The paper reports on the effect of the substrate temperature (350 °C, 380 °C and 420 °C) during reactive magnetron sputtering of a TiN film on the phase composition, texture and mechanical properties of TiN/TiO2 coatings on 304L stainless steel substrates. Pure Ti was used as a cathode source of Ti. The texture and unit cell parameters of both TiN and TiO2 phases of the coating are discussed in relation with the tribological properties and adhesion of the coating. The scratch tests performed showed that the nitride deposited at 380 °C, having the highest unit cell parameter and a predominant (111) texture, possessed the lowest friction coefficient (μ), tangential force and brittleness. The anatase-type TiO2 with predominant (101) pole density and increased c unit cell parameter showed the highest stability on the nitride deposited at 420 °C. The results indicated that the friction coefficient, tangential force and critical forces of fracture could be varied by controlling the coating deposition temperature.

  18. Laser surface textured titanium alloy (Ti–6Al–4V): Part 1 – Surface characterization

    Energy Technology Data Exchange (ETDEWEB)

    Pfleging, Wilhelm [Karlsruhe Institute of Technology, IAM-AWP, P.O. Box 3640, 76021 Karlsruhe (Germany); Karlsruhe Nano Micro Facility, H.-von-Helmholtz-Pl. 1, 76344 Egg.-Leopoldshafen (Germany); Kumari, Renu [Department of Metal. and Maters. Eng., I. I. T. Kharagpur, WB 721302 (India); Besser, Heino [Karlsruhe Institute of Technology, IAM-AWP, P.O. Box 3640, 76021 Karlsruhe (Germany); Scharnweber, Tim [Karlsruhe Institute of Technology, IBG-1, P.O. Box 3640, 76021 Karlsruhe (Germany); Majumdar, Jyotsna Dutta, E-mail: jyotsna@metal.iitkgp.ernet.in [Department of Metal. and Maters. Eng., I. I. T. Kharagpur, WB 721302 (India)

    2015-11-15

    Highlights: • Texturing of Ti–6Al–4V with linear and dimple patterns are developed with ArF laser. • Linear textures have width of 25 μm and are at an interval of 20 μm. • Dimple textures are equi-spaced and have a diameter of 60 μm. • Significant refinement of microstructure in textured zone as compared to substrate. • Increased wettability of the textured surface against simulated body fluid. - Abstract: In the present study, a detailed study of the characterization of laser-surface textured titanium alloy (Ti–6Al–4V) with line and dimple geometry developed by using an ArF excimer laser operating at a wavelength of 193 nm with a pulse length of 5 ns is undertaken. The characterization of the textured surface (both the top surface and cross section) is carried out by scanning electron microscopy, electron back scattered diffraction (EBSD) technique and X-ray diffraction techniques. There is refinement of microstructure along with presence of titanium oxides (rutile, anatase and few Ti{sub 2}O{sub 3} phase) in the textured surface as compared to as-received one. The area fractions of linear texture and dimple texture measured by image analysis software are 45% and 20%, respectively. The wettability is increased after laser texturing. The total surface energy is decreased due to linear (29.6 mN/m) texturing and increased due to dimple (67.6 mN/m) texturing as compared to as-received Ti–6Al–4V (37 mN/m). The effect of polar component is more in influencing the surface energy of textured surface.

  19. Seismic texture classification. Final report

    Energy Technology Data Exchange (ETDEWEB)

    Vinther, R.

    1997-12-31

    The seismic texture classification method, is a seismic attribute that can both recognize the general reflectivity styles and locate variations from these. The seismic texture classification performs a statistic analysis for the seismic section (or volume) aiming at describing the reflectivity. Based on a set of reference reflectivities the seismic textures are classified. The result of the seismic texture classification is a display of seismic texture categories showing both the styles of reflectivity from the reference set and interpolations and extrapolations from these. The display is interpreted as statistical variations in the seismic data. The seismic texture classification is applied to seismic sections and volumes from the Danish North Sea representing both horizontal stratifications and salt diapers. The attribute succeeded in recognizing both general structure of successions and variations from these. Also, the seismic texture classification is not only able to display variations in prospective areas (1-7 sec. TWT) but can also be applied to deep seismic sections. The seismic texture classification is tested on a deep reflection seismic section (13-18 sec. TWT) from the Baltic Sea. Applied to this section the seismic texture classification succeeded in locating the Moho, which could not be located using conventional interpretation tools. The seismic texture classification is a seismic attribute which can display general reflectivity styles and deviations from these and enhance variations not found by conventional interpretation tools. (LN)

  20. RotoTexture: automated tools for texturing raw video.

    Science.gov (United States)

    Fang, Hui; Hart, John C

    2006-01-01

    We propose a video editing system that allows a user to apply a time-coherent texture to a surface depicted in the raw video from a single uncalibrated camera, including the surface texture mapping of a texture image and the surface texture synthesis from a texture swatch. Our system avoids the construction of a 3D shape model and instead uses the recovered normal field to deform the texture so that it plausibly adheres to the undulations of the depicted surface. The texture mapping method uses the nonlinear least-squares optimization of a spring model to control the behavior of the texture image as it is deformed to match the evolving normal field through the video. The texture synthesis method uses a coarse optical flow to advect clusters of pixels corresponding to patches of similarly oriented surface points. These clusters are organized into a minimum advection tree to account for the dynamic visibility of clusters. We take a rather crude approach to normal recovering and optical flow estimation, yet the results are robust and plausible for nearly diffuse surfaces such as faces and t-shirts.

  1. Texture Enhanced Appearance Models

    DEFF Research Database (Denmark)

    Larsen, Rasmus; Stegmann, Mikkel Bille; Darkner, Sune

    2007-01-01

    Statistical region-based registration methods such as the Active Appearance Model (AAM) are used for establishing dense correspondences in images. At low resolution, images correspondences can be recovered reliably in real-time. However, as resolution increases this becomes infeasible due...... to excessive storage and computational requirements. We propose to reduce the dimensionality of the textural components by selecting a subset of basis functions from a larger dictionary, estimate regression splines and model only the coeffcients of the retained basis functions. We demonstrate the use of two...

  2. Flavour Democracy in Strong Unification

    CERN Document Server

    Abel, S A; Abel, Steven; King, Steven

    1998-01-01

    We show that the fermion mass spectrum may naturally be understood in terms of flavour democratic fixed points in supersymmetric theories which have a large domain of attraction in the presence of "strong unification". Our approach provides an alternative to the approximate Yukawa texture zeroes of the Froggatt-Nielsen mechanism. We discuss a particular model based on a broken gauged $SU(3)_L\\times SU(3)_R$ family symmetry which illustrates our approach.

  3. Tape Textured Works of Art

    Science.gov (United States)

    Skophammer, Karen

    2009-01-01

    Texture is how things feel or how they look as though they might feel if one touches them. Some surfaces are rough and some are smooth to the touch. There are many other words, such as bumpy, used to describe texture when one feels or sees it. This article presents an art project in which elementary students explain how texture is used in art,…

  4. Texture determination by neutron diffraction

    International Nuclear Information System (INIS)

    Dervin, P.

    1981-02-01

    Application of neutron diffraction to crystallographic texture determination shows many advantages: possibility of an important grain size, the quantity of material contributing to diffraction is more important than with X rays, good accuracy and complete pole figures are obtained by transmission only eliminating corrections needed with X rays. Texture determination allows control and improvement of material quality. Texture studies give good informations on mechanisms occuring in deformation or recrystallization of polycrystals and on anisotropy of physical and mechanical properties [fr

  5. General relativistic collapse of textures

    International Nuclear Information System (INIS)

    Durrer, R.; Heusler, M.; Jetzer, P.; Straumann, N.

    1991-01-01

    We present an exact self-similar solution of the coupled Einstein-σ model equations which describes the general relativistic collapse of global textures. In one coordinate system the texture geometry has a simple interpretation in terms of a deficit solid angle. We also briefly discuss the behavior of matter and light in this geometry. In particular we show that the weak field approximation for the metric perturbations of flat space texture solutions is quantitatively quite reliable. (orig.)

  6. LOCAL TEXTURE DESCRIPTION FRAMEWORK FOR TEXTURE BASED FACE RECOGNITION

    Directory of Open Access Journals (Sweden)

    R. Reena Rose

    2014-02-01

    Full Text Available Texture descriptors have an important role in recognizing face images. However, almost all the existing local texture descriptors use nearest neighbors to encode a texture pattern around a pixel. But in face images, most of the pixels have similar characteristics with that of its nearest neighbors because the skin covers large area in a face and the skin tone at neighboring regions are same. Therefore this paper presents a general framework called Local Texture Description Framework that uses only eight pixels which are at certain distance apart either circular or elliptical from the referenced pixel. Local texture description can be done using the foundation of any existing local texture descriptors. In this paper, the performance of the proposed framework is verified with three existing local texture descriptors Local Binary Pattern (LBP, Local Texture Pattern (LTP and Local Tetra Patterns (LTrPs for the five issues viz. facial expression, partial occlusion, illumination variation, pose variation and general recognition. Five benchmark databases JAFFE, Essex, Indian faces, AT&T and Georgia Tech are used for the experiments. Experimental results demonstrate that even with less number of patterns, the proposed framework could achieve higher recognition accuracy than that of their base models.

  7. Surface Hydrophilicity and Antifungal Properties of TiO2 Films Coated on a Co-Cr Substrate

    Directory of Open Access Journals (Sweden)

    Lijuan Huang

    2017-01-01

    Full Text Available The purpose of this study was to deposit a thin layer of TiO2 on a Co-Cr substrate, serving as a deactivation film protecting the metallic fitting surface. The crystalline structure and surface morphology of the film were characterized by X-ray diffraction (XRD and scanning electron microscopy (SEM. A scratch tester was used to examine the adhesion strength between the TiO2 film and the Co-Cr substrate. The water contact angles and antifungal efficacy against C. albicans of the TiO2-deposited Co-Cr samples were investigated and further compared with those of uncoated Co-Cr substrates. The results indicated that a pure anatase microstructure and dense and smooth surface texture as well as strong binding to the underlying metallic surface were obtained. The originally hydrophobic Co-Cr alloy surface turned hydrophilic after TiO2 film coating. Most importantly, the TiO2-coated surface showed a superior antifungal capability under UV-irradiation compared to those without TiO2 coating. This work contains meaningful results for the development of a new metallic framework coating with improved hydrophilicity and antifungal properties.

  8. Electro-optic effect in Ba1-xPbxTiO3 films

    Science.gov (United States)

    Fuflyigin, V.; Wang, F.; Jiang, H.; Zhao, J.; Norris, P.

    2000-03-01

    High quality Ba1-xPbxTiO3 (x=0-0.25) films were grown on R-Al2O3 in a wide thickness range of 0.5-3 μm. Significant improvement of the films' crystallinity and optical quality was observed in the presence of lead oxide for the films prepared at 650-700 °C. Strong texture of (110) type was observed in these films. The material is transparent at 350-2000 nm, indicating the possibility of its application in light controlling devices at wavelengths used in optical communication: 1300 and 1500 nm. Maximum field induced relative phase shift of 0.22 rad was measured in the film with composition of Ba0.9Pb0.1TiO3 under a field strength of 3×106 V/cm.

  9. Depth-resolved X-ray residual stress analysis in PVD (Ti, Cr) N hard coatings

    CERN Document Server

    Genzel, C

    2003-01-01

    Physical vapour deposition (PVD) of thin hard coatings on TiN basis is usually performed at rather low temperatures (T sub D < 500 C) far from thermal equilibrium, which leads to high intrinsic residual stresses in the growing film. In contrast to the extrinsic thermal residual stresses which can easily be estimated from the difference of the coefficients of thermal expansion between the substrate and the coating, a theoretical prediction of the intrinsic residual stresses is difficult, because their amount as well as their distribution within the film depend in a very complex way on the deposition kinetics. By the example of strongly fibre-textured PVD (Ti, Cr)N coatings which have been prepared under defined variation of the deposition parameters in order to adjust the residual stress distribution within the coatings, the paper compares different X-ray diffraction techniques with respect to their applicability for detecting residual stresses which are non-uniform over the coating thickness. (orig.)

  10. Quantitative Characterisation of Surface Texture

    DEFF Research Database (Denmark)

    De Chiffre, Leonardo; Lonardo, P.M.; Trumpold, H.

    2000-01-01

    This paper reviews the different methods used to give a quantitative characterisation of surface texture. The paper contains a review of conventional 2D as well as 3D roughness parameters, with particular emphasis on recent international standards and developments. It presents new texture...

  11. Emotional effects of dynamic textures

    NARCIS (Netherlands)

    Toet, A.; Henselmans, M.; Lucassen, M.P.; Gevers, T.

    2011-01-01

    This study explores the effects of various spatiotemporal dynamic texture characteristics on human emotions. The emotional experience of auditory (eg, music) and haptic repetitive patterns has been studied extensively. In contrast, the emotional experience of visual dynamic textures is still largely

  12. Cartoon+Texture Image Decomposition

    Directory of Open Access Journals (Sweden)

    Antoni Buades

    2011-09-01

    Full Text Available In this article we give a thorough description of the algorithm proposed in [A. Buades, T. Le, J.M. Morel and L. Vese, Fast cartoon + texture image filters, IEEE Transactions on Image Processing, 2010] for cartoon+texture decomposition using of a nonlinear low pass-high pass filter pair.

  13. Human versus artificial texture perception

    NARCIS (Netherlands)

    Petiet, Peter J.; van Erp, J.; Drullman, R.; van den Broek, Egon; Beintema, J.; van Wijngaarden, S.

    2006-01-01

    The performances of current texture analysis algorithms are still poor, especially when applied to a large, diffuse texture domain. Most of these purely computationally driven techniques are created to function within a highly restricted domain. When applied as computer vision techniques, frequently

  14. Emotional Effects of Dynamic Textures

    Directory of Open Access Journals (Sweden)

    Alexander Toet

    2011-12-01

    Full Text Available This study explores the effects of various spatiotemporal dynamic texture characteristics on human emotions. The emotional experience of auditory (eg, music and haptic repetitive patterns has been studied extensively. In contrast, the emotional experience of visual dynamic textures is still largely unknown, despite their natural ubiquity and increasing use in digital media. Participants watched a set of dynamic textures, representing either water or various different media, and self-reported their emotional experience. Motion complexity was found to have mildly relaxing and nondominant effects. In contrast, motion change complexity was found to be arousing and dominant. The speed of dynamics had arousing, dominant, and unpleasant effects. The amplitude of dynamics was also regarded as unpleasant. The regularity of the dynamics over the textures' area was found to be uninteresting, nondominant, mildly relaxing, and mildly pleasant. The spatial scale of the dynamics had an unpleasant, arousing, and dominant effect, which was larger for textures with diverse content than for water textures. For water textures, the effects of spatial contrast were arousing, dominant, interesting, and mildly unpleasant. None of these effects were observed for textures of diverse content. The current findings are relevant for the design and synthesis of affective multimedia content and for affective scene indexing and retrieval.

  15. Evolution of microstructure, texture and topography during additional annealing of cube-textured Ni–5at.%W substrate for coated conductors

    DEFF Research Database (Denmark)

    Wulff, Anders Christian; Mishin, Oleg; Grivel, Jean-Claude

    2012-01-01

    Microstructure, texture and topography have been studied in a recrystallized Ni–5at.%W substrate before and after additional annealing at 1025C for 1 h. The initial recrystallized material contained a strong cube texture and a high fraction of low angle grain boundaries. R3 boundaries were also f...

  16. Through-thickness texture gradient in continuous cast AA 5052 aluminum alloy sheet

    Energy Technology Data Exchange (ETDEWEB)

    Liu, W.C. [Department of Chemical and Materials Engineering, University of Kentucky, 177 Anderson Hall, Lexington, KY 40506 (United States)], E-mail: wcliu@engr.uky.edu; Radhakrishnan, B. [Oak Ridge National Laboratory, P.O. Box 2008, MS-6140, Oak Ridge, TN 37831-6140 (United States); Li, Z. [Aleris International Inc., 1505 Bull Lea Road, Lexington, KY 40511 (United States); Morris, J.G. [Department of Chemical and Materials Engineering, University of Kentucky, 177 Anderson Hall, Lexington, KY 40506 (United States)

    2008-01-15

    The development of through-thickness texture gradient during continuous cast (CC) processing of AA 5052 aluminum alloy was investigated by X-ray diffraction. The CC slab and the hot bands after each of three rolling passes were obtained from an industrial CC processing operation. The results show that a through-thickness texture gradient exists near the surface after the first pass. The subsurface layer exhibits a very weak texture, while the center layer shows the {beta} fiber rolling texture. After the third pass, a strong {beta} fiber rolling texture is obtained at different through-thickness layers. The roll-gap geometry does not produce any shear deformation at the intermediate layer. After recrystallization annealing, the through-thickness texture gradient still exists in the AA 5052 aluminum alloy sheets. As the measured position moves towards the center from the surface, the cube recrystallization texture strengthens.

  17. Development and application of a green-chemistry solution deposition technique for buffer layer coating on cube-textured metal substrates in view of further deposition of rare-earth based superconductors

    DEFF Research Database (Denmark)

    Pallewatta, Pallewatta G A P

    which consist of YBCO superconducting coatings on cube-textured Ni based alloy tapes.  Before the epitaxial deposition this superconducting layer, a buffer layer is applied on the metal substrate as a diffusion barrier which is also required to transfer the strong texture of the underlying substrate......, allowing the epitaxial growth of the superconducting layer. State-of-the-art coated conductor hetero structures are mainly based on CeO2 based buffer stacks that consist of a sequence of several different buffer layers. Buffer layers deposited by continuous chemical deposition techniques, which...... are the most suitable for large scale production, use to suffer from porosity and cracks that lead to material diffusion from the metal substrate into the superconductor as well as oxidation of the metal during high-temperature processing of the buffer layer. SrTiO3 buffer layers have attracted interest due...

  18. Calculation of skid resistance from texture measurements

    Directory of Open Access Journals (Sweden)

    Andreas Ueckermann

    2015-02-01

    Full Text Available There is a wide range of routine skid resistance measurement devices on the market. All of them are measuring the friction force between a rubber wheel and the wetted road surface. Common to all of them is that they are relatively complex and costly because generally a truck carrying a large water tank is needed to wet the surface with a defined water layer. Because of the limited amount of water they can carry they are limited in range. Besides that the measurement is depending on factors like water film thickness, temperature, measurement speed, rubber aging, rubber wear and even road evenness and curviness. All of these factors will affect the skid resistance and are difficult to control. We present a concept of contactless skid resistance measurement which is based on optical texture measurement and consists of two components: measurement of the pavement texture by means of an optical measuring system and calculation of the skid resistance based on the measured texture by means of a rubber friction model. The basic assumptions underlying the theoretical approach and the model itself based on the theory of Persson are presented. The concept is applied to a laboratory device called Wehner/Schulze (W/S machine to prove the theoretical approach. The results are very promising. A strong indication could be provided that skid resistance could be measured without contact in the future.

  19. Correlation between texture and mechanical stress durability of thin aluminum films

    Energy Technology Data Exchange (ETDEWEB)

    Nüssl, R., E-mail: rudolf.nuessl@uct.ac.za [Institut für Physik, Universität der Bundeswehr München, Werner-Heisenberg-Weg 39, 85579 Neubiberg (Germany); Jewula, T.; Ruile, W. [TDK Corporation, Systems, Acoustics, Waves Business Group, Anzingerstraße 13, 81617 Munich (Germany); Sulima, T.; Hansch, W. [Institut für Physik, Universität der Bundeswehr München, Werner-Heisenberg-Weg 39, 85579 Neubiberg (Germany)

    2014-04-01

    In this article, differently textured aluminum (Al) metallizations of surface acoustic wave (SAW) devices have been exposed to cyclic mechanical stress in order to investigate a potential correlation between their texture and their mechanical stress durability. Samples of SAW devices with differently textured Al thin film electrodes have been manufactured, and texture measurements have been carried out on all samples with electron backscatter diffraction. Subsequently, the SAW devices have been operated at heavy electrical load until a defined mechanical fatigue of its Al electrodes occurred. SAW devices with highly textured Al electrodes showed almost 20 times higher power durability than SAW devices with untextured Al electrodes. We show that this increase in electrical power durability has to be fully attributed to the strongly enhanced mechanical stress durability of highly textured Al films. Furthermore, a positive correlation between the Al films' texture and its electrical conductivity has been found. - Highlights: • We show highly textured growth of thin Al films on a clean, monocrystalline LiTaO{sub 3} • Highly textured Al growth gets disturbed by prior photolithographic process steps • Power durability of a SAW device increases with texture of its metallization • Texture and mechanical stress durability of a thin Al film are tightly correlated.

  20. Textures in Utopia Planitia

    Science.gov (United States)

    2002-01-01

    [figure removed for brevity, see original site] Bizarre textures cover the surface of eastern Utopia Planitia where there is a high probability that ground ice has played a role in the formation of this unusual landscape.Note: this THEMIS visual image has not been radiometrically nor geometrically calibrated for this preliminary release. An empirical correction has been performed to remove instrumental effects. A linear shift has been applied in the cross-track and down-track direction to approximate spacecraft and planetary motion. Fully calibrated and geometrically projected images will be released through the Planetary Data System in accordance with Project policies at a later time.NASA's Jet Propulsion Laboratory manages the 2001 Mars Odyssey mission for NASA's Office of Space Science, Washington, D.C. The Thermal Emission Imaging System (THEMIS) was developed by Arizona State University, Tempe, in collaboration with Raytheon Santa Barbara Remote Sensing. The THEMIS investigation is led by Dr. Philip Christensen at Arizona State University. Lockheed Martin Astronautics, Denver, is the prime contractor for the Odyssey project, and developed and built the orbiter. Mission operations are conducted jointly from Lockheed Martin and from JPL, a division of the California Institute of Technology in Pasadena.

  1. TOPICAL REVIEW Textured silicon nitride: processing and anisotropic properties

    Directory of Open Access Journals (Sweden)

    Xinwen Zhu and Yoshio Sakka

    2008-01-01

    Full Text Available Textured silicon nitride (Si3N4 has been intensively studied over the past 15 years because of its use for achieving its superthermal and mechanical properties. In this review we present the fundamental aspects of the processing and anisotropic properties of textured Si3N4, with emphasis on the anisotropic and abnormal grain growth of β-Si3N4, texture structure and texture analysis, processing methods and anisotropic properties. On the basis of the texturing mechanisms, the processing methods described in this article have been classified into two types: hot-working (HW and templated grain growth (TGG. The HW method includes the hot-pressing, hot-forging and sinter-forging techniques, and the TGG method includes the cold-pressing, extrusion, tape-casting and strong magnetic field alignment techniques for β-Si3N4 seed crystals. Each processing technique is thoroughly discussed in terms of theoretical models and experimental data, including the texturing mechanisms and the factors affecting texture development. Also, methods of synthesizing the rodlike β-Si3N4 single crystals are presented. Various anisotropic properties of textured Si3 N4 and their origins are thoroughly described and discussed, such as hardness, elastic modulus, bending strength, fracture toughness, fracture energy, creep behavior, tribological and wear behavior, erosion behavior, contact damage behavior and thermal conductivity. Models are analyzed to determine the thermal anisotropy by considering the intrinsic thermal anisotropy, degree of orientation and various microstructure factors. Textured porous Si3N4 with a unique microstructure composed of oriented elongated β-Si3N4 and anisotropic pores is also described for the first time, with emphasis on its unique mechanical and thermal-mechanical properties. Moreover, as an important related material, textured α-Sialon is also reviewed, because the presence of elongated α-Sialon grains allows the production of textured

  2. Symmetry realization of texture zeros

    International Nuclear Information System (INIS)

    Grimus, W.; Joshipura, A.S.; Lavoura, L.; Tanimoto, M.

    2004-01-01

    We show that it is possible to enforce texture zeros in arbitrary entries of the fermion mass matrices by means of Abelian symmetries; in this way, many popular mass-matrix textures find a symmetry justification. We propose two alternative methods which allow one to place zeros in any number of elements of the mass matrices that one wants. They are applicable simultaneously in the quark and lepton sectors. They are also applicable in grand unified theories. The number of scalar fields required by our methods may be large; still, in many interesting cases this number can be reduced considerably. The larger the desired number of texture zeros is, the simpler are the models which reproduce the texture. (orig.)

  3. Real-time texture experiments

    International Nuclear Information System (INIS)

    Juul Jensen, D.

    1985-01-01

    A technique for fast in-situ texture determination by neutron diffraction is described. The basic instrument is variable wavelength neutron spectrometer modified to incorporate a linear position-sensitive detector and a fully automatic Eulergoniometer. At present a complete textural analysis with an accuracy of 2-3% determined by counting statistics, requires from 15 to 30 minutes measuring time depending on the sample material. By on-line recording of the change in texture, which commonly accompanies such processes as deformation, recrystallization and grain growth in crystalline materials, information about the process and its kinetics is obtained. This is illustrated by in-situ kinetic investigations of recrystallization and grain growth in various polycrystalline metals; the potential of the technique for problems related to metallurgical practice is demonstrated by an approach of texture tailoring in commercially pure aluminium. (author)

  4. EUROMET SUPPLEMENTARY COMPARISON - SURFACE TEXTURE

    DEFF Research Database (Denmark)

    Koenders, L.; Andreasen, Jan Lasson; De Chiffre, Leonardo

    At the length meeting in Prague in Oct. 1999 a new comparison was suggested on surface texture. The last comparison on this field was finished in 1989. In the meantime the instrumentation, the standards and the written standards have been improved including some software filters. The pilot...... laboratories for this supplementary comparison on surface texture are the Centre for Geometrical Metrology at the Technical University of Denmark and the Micro- and Nanotopography laboratory at the Physikalisch-Technische Bundesanstalt, Germany....

  5. A determination of the texture of a directionally solidified sample of high-purity copper

    DEFF Research Database (Denmark)

    Grant, Evan; Juul Jensen, Dorte; Ralph, Brian

    1986-01-01

    A study making a combined use of neutron diffraction and selected-area electron channelling to determine the solidification texture in a high-purity copper sample is described. Good correlation between the techniques is shown with both demonstrating a strong [100] fibre texture in the directionally...

  6. Audio Classification from Time-Frequency Texture

    OpenAIRE

    Yu, Guoshen; Slotine, Jean-Jacques

    2008-01-01

    Time-frequency representations of audio signals often resemble texture images. This paper derives a simple audio classification algorithm based on treating sound spectrograms as texture images. The algorithm is inspired by an earlier visual classification scheme particularly efficient at classifying textures. While solely based on time-frequency texture features, the algorithm achieves surprisingly good performance in musical instrument classification experiments.

  7. Food Texture Preferences in Infants Versus Toddlers.

    Science.gov (United States)

    Lundy, Brenda; And Others

    1998-01-01

    Compared food texture preferences during infancy and toddlerhood. Found that infants displayed more negative expressions and head and body movements in response to complex textures than to simple textures. Toddlers displayed more positive head and body movements and more eagerness in response to complex than to simple textures. Experience with…

  8. X-ray stress analysis in textured polycrystalline materials

    International Nuclear Information System (INIS)

    Yokoyama, Ryouichi; Harada, Jimpei

    2010-01-01

    The relationship between stress and strain in polycrystalline materials with fibre texture is examined on the basis of the strain analysis in the constituent crystallites within the Reuss approximation. By introducing the symmetry of reciprocal lattices for the constituent crystallites, the physical meaning of taking an average of the strains observed by X-ray diffraction (XRD) is made clear. By using formulae obtained by the present treatment for the stress-strain relation in cubic specimens with fibre texture in the Laue classes m3-bar m hkl Bragg reflections with h≠k≠l split into doublets owing to the existence of crystallites with two different orientations under the stress field. This technique was confirmed by the profile analysis in XRD data observed for reflections of 222 and 420 in a cubic TiN thin film sputtered on a polyimide film. The technique of the stress analysis and its confirmation are introduced. (author)

  9. Texture-dependent effects of pseudo-chewing sound on perceived food texture and evoked feelings in response to nursing care foods.

    Science.gov (United States)

    Endo, Hiroshi; Ino, Shuichi; Fujisaki, Waka

    2017-09-01

    Because chewing sounds influence perceived food textures, unpleasant textures of texture-modified diets might be improved by chewing sound modulation. Additionally, since inhomogeneous food properties increase perceived sensory intensity, the effects of chewing sound modulation might depend on inhomogeneity. This study examined the influences of texture inhomogeneity on the effects of chewing sound modulation. Three kinds of nursing care foods in two food process types (minced-/puréed-like foods for inhomogeneous/homogeneous texture respectively) were used as sample foods. A pseudo-chewing sound presentation system, using electromyogram signals, was used to modulate chewing sounds. Thirty healthy elderly participants participated in the experiment. In two conditions with and without the pseudo-chewing sound, participants rated the taste, texture, and evoked feelings in response to sample foods. The results showed that inhomogeneity strongly influenced the perception of food texture. Regarding the effects of the pseudo-chewing sound, taste was less influenced, the perceived food texture tended to change in the minced-like foods, and evoked feelings changed in both food process types. Though there were some food-dependent differences in the effects of the pseudo-chewing sound, the presentation of the pseudo-chewing sounds was more effective in foods with an inhomogeneous texture. In addition, it was shown that the pseudo-chewing sound might have positively influenced feelings. Copyright © 2017 Elsevier Ltd. All rights reserved.

  10. On soil textural classifications and soil-texture-based estimations

    Science.gov (United States)

    Ángel Martín, Miguel; Pachepsky, Yakov A.; García-Gutiérrez, Carlos; Reyes, Miguel

    2018-02-01

    The soil texture representation with the standard textural fraction triplet sand-silt-clay is commonly used to estimate soil properties. The objective of this work was to test the hypothesis that other fraction sizes in the triplets may provide a better representation of soil texture for estimating some soil parameters. We estimated the cumulative particle size distribution and bulk density from an entropy-based representation of the textural triplet with experimental data for 6240 soil samples. The results supported the hypothesis. For example, simulated distributions were not significantly different from the original ones in 25 and 85 % of cases when the sand-silt-clay and very coarse+coarse + medium sand - fine + very fine sand - silt+clay were used, respectively. When the same standard and modified triplets were used to estimate the average bulk density, the coefficients of determination were 0.001 and 0.967, respectively. Overall, the textural triplet selection appears to be application and data specific.

  11. Auditory Perception of Statistically Blurred Sound Textures

    DEFF Research Database (Denmark)

    McWalter, Richard Ian; MacDonald, Ewen; Dau, Torsten

    Sound textures have been identified as a category of sounds which are processed by the peripheral auditory system and captured with running timeaveraged statistics. Although sound textures are temporally homogeneous, they offer a listener with enough information to identify and differentiate...... sources. This experiment investigated the ability of the auditory system to identify statistically blurred sound textures and the perceptual relationship between sound textures. Identification performance of statistically blurred sound textures presented at a fixed blur increased over those presented...

  12. Characterization of an Amorphous Titanium Oxide Film Deposited onto a Nano-Textured Fluorination Surface

    Directory of Open Access Journals (Sweden)

    Pei-Yu Li

    2016-05-01

    Full Text Available The photocatalytic activity of an amorphous titanium oxide (a-TiOx film was modified using a two-step deposition. The fluorinated base layer with a nano-textured surface prepared by a selective fluorination etching process acted as growth seeds in the subsequent a-TiOx deposition. A nanorod-like microstructure was achievable from the resulting a-TiOx film due to the self-assembled deposition. Compared to the a-TiOx film directly deposited onto the untreated base layer, the rate constant of this fluorinate-free a-TiOx film surface for decomposing methylene blue (MB solution that was employed to assess the film’s photocatalytic activity was markedly increased from 0.0076 min−1 to 0.0267 min−1 as a mechanism for the marked increase in the specific surface area.

  13. The role of textures in the forming of automotive sheet steels

    International Nuclear Information System (INIS)

    Sanak Mishra

    1996-01-01

    Crystallographic textures generally have a strong bearing on the drawability of sheet steels. Particularly in the case of automotive sheets, texture control is of paramount importance. In the last two decades, therefore, texture research has assumed much significance in the steel industry. X-ray diffraction continues to remain the most used tool for the study of textures. Early researches, from about 1940 to 1980, were invariably carried out by the pole figure method. However, for more quantitative results the ODF (Orientation Distribution Functions) analysis technique was developed. Since 1980, the ODF analysis has come to be used extensively. In the present paper, several unique features of textures in automotive grade deep drawing steels, as revealed from X-ray ODFS, will be presented. The relative importance of the various textural components with respect to forming will also be dealt with

  14. A crystallographic texture perspective formability investigation of aluminium 5052 alloy sheets at various annealing temperatures

    Energy Technology Data Exchange (ETDEWEB)

    Narayanasamy, R. [Department of Production Engineering, National Institute of Technology, Tiruchirappalli - 620015, Tamilnadu (India); Ravindran, R. [Department of Mechanical Engineering, VLB Janakiammal College of Engineering and Technology, Coimbatore - 641042, Tamilnadu (India)], E-mail: mceravindran@yahoo.co.in; Manonmani, K. [Department of Mechanical Engineering, Government College of Technology, Coimbatore - 641013, Tamilnadu (India)], E-mail: manokmani@yahoo.co.in; Satheesh, J. [Department of Production Engineering, National Institute of Technology, Tiruchirappalli - 620015, Tamilnadu (India)

    2009-05-15

    Formability, an important mechanical property of the sheet metal is strongly reliant on the crystallographic texture. Consequently deep drawability is also influenced. This paper deals with the perspective of crystallographic texture and its relevance with the formability of AA 5052 aluminium alloy sheet of 2 mm thickness annealed at four different temperatures namely 200 deg. C, 250 deg. C, 300 deg. C and 350 deg. C. Forming limit diagrams determined and plotted experimentally, their crystallographic textures obtained and their ODF plots prepared by X-ray diffraction were analyzed. The Forming limit diagrams (FLDs) of AA 5052 sheets annealed under different temperatures were examined with respect to the crystallographic texture point of view. The FLDs and crystallographic textures were then correlated with normal anisotropy of the sheet metal. It was found that the formability of aluminium alloy AA 5052 annealed at 350 deg. C possessed good formability, optimal texture and high normal anisotropy value.

  15. TEM characterization of a Cr/Ti/TiC graded interlayer for magnetron-sputtered TiC/a-C:H nanocomposite coatings

    International Nuclear Information System (INIS)

    Galvan, D.; Pei, Y.T.; De Hosson, J.Th.M.

    2005-01-01

    A TiC/a-C:H nanocomposite coating is deposited on top of a Cr/Ti/TiC graded interlayer. Cross-section transmission electron microscopy is employed to investigate the detailed structure of the interlayer and the coating. Five different phases are formed as a consequence of the compositional gradient within the interlayer: pure Cr, a solid solution of Ti in Cr, a Ti/Cr amorphous/nanocrystalline phase, α-Ti and TiC. Solid state amorphization occurs during the interlayer deposition to give a dispersion of TiCr β-phase nanocrystals in an amorphous matrix. The TiC phase is textured and contains numerous stacking faults as a result of the growth in under-stoichiometric carbon concentration. C-enriched columnar boundaries are present within the coating, originating from the TiC column boundaries of the interlayer. The work indicates that an interlayer of amorphous/nanocrystalline Ti/Cr phase would reduce the presence of growth defects such as columnar boundaries within nanocomposite TiC/a-C:H coatings

  16. Ti, Al

    Indian Academy of Sciences (India)

    In the present study, authors report on the effect that substrate bias voltage has on the microstructure and mechanical properties of (Ti, Al)N hard coatings deposited with cathodic arc evaporation (CAE) technique. The coatings were deposited from a Ti0.5Al0.5 powder metallurgical target in a reactive nitrogen atmosphere at ...

  17. Texture classification using logical operators.

    Science.gov (United States)

    Manian, V; Vasquez, R; Katiyar, P

    2000-01-01

    In this paper, a new algorithm for texture classification based on logical operators is presented. Operators constructed from logical building blocks are convolved with texture images. An optimal set of six operators are selected based on their texture discrimination ability. The responses are then converted to standard deviation matrices computed over a sliding window. Zonal sampling features are computed from these matrices. A feature selection process is applied and the new set of features are used for texture classification. Classification of several natural and synthetic texture images are presented demonstrating the excellent performance of the logical operator method. The computational superiority and classification accuracy of the algorithm is demonstrated by comparison with other popular methods. Experiments with different classifiers and feature normalization are also presented. The Euclidean distance classifier is found to perform best with this algorithm. The algorithm involves only convolutions and simple arithmetic in the various stages which allows faster implementations. The algorithm is applicable to different types of classification problems which is demonstrated by segmentation of remote sensing images, compressed and reconstructed images and industrial images.

  18. Di-uniform texture spaces

    Directory of Open Access Journals (Sweden)

    Selma Ozcag

    2003-04-01

    Full Text Available Textures were introduced by the second author as a point-based setting for the study of fuzzy sets, and have since proved to be an appropriate framework for the development of complement-free mathematical concepts. In this paper the authors lay the foundation for a theory of uniformities in a textural context. Analogues are given for both the diagonal and covering approaches to the classical theory of uniform structures, the notion of uniform topology is generalized and an analogue given for the well known result that a topological space is uniformizable if and only if it is completely regular. Finally a textural analogue of the classical interplay between uniformities and families of pseudo-metrics is presented.

  19. Texture in thin film silicides and germanides: A review

    Energy Technology Data Exchange (ETDEWEB)

    De Schutter, B., E-mail: bob.deschutter@ugent.be; De Keyser, K.; Detavernier, C. [Department of Solid State Sciences, Ghent University, Ghent (Belgium); Lavoie, C. [IBM Research Division, T.J. Watson Research Center, P.O. Box 218, Yorktown Heights, New York 10598 (United States)

    2016-09-15

    Silicides and germanides are compounds consisting of a metal and silicon or germanium. In the microelectronics industry, silicides are the material of choice for contacting silicon based devices (over the years, CoSi{sub 2}, C54-TiSi{sub 2}, and NiSi have been adopted), while germanides are considered as a top candidate for contacting future germanium based electronics. Since also strain engineering through the use of Si{sub 1−x}Ge{sub x} in the source/drain/gate regions of MOSFET devices is an important technique for improving device characteristics in modern Si-based microelectronics industry, a profound understanding of the formation of silicide/germanide contacts to silicon and germanium is of utmost importance. The crystallographic texture of these films, which is defined as the statistical distribution of the orientation of the grains in the film, has been the subject of scientific studies since the 1970s. Different types of texture like epitaxy, axiotaxy, fiber, or combinations thereof have been observed in such films. In recent years, it has become increasingly clear that film texture can have a profound influence on the formation and stability of silicide/germanide contacts, as it controls the type and orientation of grain boundaries (affecting diffusion and agglomeration) and the interface energy (affecting nucleation during the solid-state reaction). Furthermore, the texture also has an impact on the electrical characteristics of the contact, as the orientation and size of individual grains influences functional properties such as contact resistance and sheet resistance and will induce local variations in strain and Schottky barrier height. This review aims to give a comprehensive overview of the scientific work that has been published in the field of texture studies on thin film silicide/germanide contacts.

  20. Electromigration-induced plasticity and texture in Cu interconnects

    International Nuclear Information System (INIS)

    Advanced Light Source; Tamura, Nobumichi; Budiman, A. S.; Hau-Riege, C.S.; Besser, P. R.; Marathe, A.; Joo, Y.-C.; Tamura, N.; Patel, J. R.; Nix, W. D.

    2007-01-01

    Plastic deformation has been observed in damascene Cu interconnect test structures during an in-situ electromigration experiment and before the onset of visible microstructural damage (ie. voiding) using a synchrotron technique of white beam X-ray microdiffraction. We show here that the extent of this electromigration-induced plasticity is dependent on the texture of the Cu grains in the line. In lines with strong textures, the extent of plastic deformation is found to be relatively large compared to our plasticity results in the previous study [1] using another set of Cu lines with weaker textures. This is consistent with our earlier observation that the occurrence of plastic deformation in a given grain can be strongly correlated with the availability of a direction of the crystal in the proximity of the direction of the electron flow in the line (within an angle of 10 o ). In out-of-plane oriented grains in a damascene interconnect scheme, the crystal plane facing the sidewall tends to be a {110} plane,[2-4] so as to minimize interfacial energy. Therefore, it is deterministic rather than probabilistic that the grains will have a direction nearly parallel to the direction of electron flow. Thus, strong textures lead to more plasticity, as we observe

  1. Electromigration-induced plasticity and texture in Cu interconnects

    Energy Technology Data Exchange (ETDEWEB)

    Advanced Light Source; Tamura, Nobumichi; Budiman, A. S.; Hau-Riege, C.S.; Besser, P. R.; Marathe, A.; Joo, Y.-C.; Tamura, N.; Patel, J. R.; Nix, W. D.

    2007-10-31

    Plastic deformation has been observed in damascene Cu interconnect test structures during an in-situ electromigration experiment and before the onset of visible microstructural damage (ie. voiding) using a synchrotron technique of white beam X-ray microdiffraction. We show here that the extent of this electromigration-induced plasticity is dependent on the texture of the Cu grains in the line. In lines with strong <111> textures, the extent of plastic deformation is found to be relatively large compared to our plasticity results in the previous study [1] using another set of Cu lines with weaker textures. This is consistent with our earlier observation that the occurrence of plastic deformation in a given grain can be strongly correlated with the availability of a <112> direction of the crystal in the proximity of the direction of the electron flow in the line (within an angle of 10{sup o}). In <111> out-of-plane oriented grains in a damascene interconnect scheme, the crystal plane facing the sidewall tends to be a {l_brace}110{r_brace} plane,[2-4] so as to minimize interfacial energy. Therefore, it is deterministic rather than probabilistic that the <111> grains will have a <112> direction nearly parallel to the direction of electron flow. Thus, strong <111> textures lead to more plasticity, as we observe.

  2. Rietveld texture analysis of complex oxides: examples of polyphased Bi2223 superconducting and Co349 thermoelectric textured ceramics characterization using neutron and X-ray diffraction

    International Nuclear Information System (INIS)

    Guilmeau, E.; Chateigner, D.; Noudem, J.; Funahashi, R.; Horii, S.

    2005-01-01

    Orientation distributions of cobaltite thermoelectric and polyphased bismuth-based cuprate superconducting textured materials are determined from neutron and X-ray diffraction analysis. Curved position-sensitive detectors coupled to a tilt-angle (χ) scan enable the treatment of the whole diffraction pattern using the combined Rietveld-WIMV-Popa algorithm. The textures of three phases of superconducting compounds are determined. The critical current densities, measured for four samples, are strongly dependent on the calculated texture strengths, crystallite sizes and phase ratios. For the cobaltite compounds, a comparison between X-ray and neutron analysis shows the advantages of the latter technique for avoiding the limitations of the X-ray analysis with respect to the defocusing effect. The results highlight the necessity and efficiency of the combined approach for a quantitative texture analysis of complex materials and exemplify the texture-anisotropic physical properties relationship for a better understanding and design of improved bulk superconducting and thermoelectric materials

  3. Laser surface texturing of tool steel: textured surfaces quality evaluation

    Science.gov (United States)

    Šugár, Peter; Šugárová, Jana; Frnčík, Martin

    2016-05-01

    In this experimental investigation the laser surface texturing of tool steel of type 90MnCrV8 has been conducted. The 5-axis highly dynamic laser precision machining centre Lasertec 80 Shape equipped with the nano-second pulsed ytterbium fibre laser and CNC system Siemens 840 D was used. The planar and spherical surfaces first prepared by turning have been textured. The regular array of spherical and ellipsoidal dimples with a different dimensions and different surface density has been created. Laser surface texturing has been realized under different combinations of process parameters: pulse frequency, pulse energy and laser beam scanning speed. The morphological characterization of ablated surfaces has been performed using scanning electron microscopy (SEM) technique. The results show limited possibility of ns pulse fibre laser application to generate different surface structures for tribological modification of metallic materials. These structures were obtained by varying the processing conditions between surface ablation, to surface remelting. In all cases the areas of molten material and re-cast layers were observed on the bottom and walls of the dimples. Beside the influence of laser beam parameters on the machined surface quality during laser machining of regular hemispherical and elipsoidal dimple texture on parabolic and hemispherical surfaces has been studied.

  4. Electromagnetic behavior of bulk textured YBaCuO

    International Nuclear Information System (INIS)

    Winter, V.; Herrmann, P.F.; Agnoux, C.; Leriche, A.; Mautref, M.; Grivon, F.; Fevrier, A.

    1992-01-01

    This paper reports electrical and magnetic results obtained on bulk YBaCuO samples manufactured by Melt Textured Growth process. These studies are important for the understanding of the limitation mechanisms of transport current. Resistive measurements on textured sample confirm the interest of these materials. Transport critical current densities in excess of 2.5 10 8 A/m 2 have been measured in a field of 2 T, at 77 K in oriented YBaCuO. The critical state concept for the calculation of internal flux profiles is used to model the magnetization behavior of textured materials. The authors compare magnetization measurements with theoretical curves for different orientations of the magnetic field with respect to crystallographic axes. This study allows to determine inductive critical current densities which are strongly influenced by the current path geometry. Then the authors compare these results to transport J ct values. Self field losses values are also presented

  5. Evaporation dynamics of completely wetting drops on geometrically textured surfaces

    Science.gov (United States)

    Mekhitarian, Loucine; Sobac, Benjamin; Dehaeck, Sam; Haut, Benoît; Colinet, Pierre

    2017-10-01

    This study deals with the evaporation dynamics of completely wetting and highly volatile drops deposited on geometrically textured but chemically homogeneous surfaces. The texturation consists in a cylindrical pillars array with a square pitch. The triple line dynamics and the drop shape are characterized by an interferometric method. A parametric study is realized by varying the radius and the height of the pillars (at fixed interpillar distance), allowing to distinguish three types of dynamics: i) an evaporation-dominated regime with a receding triple line; ii) a spreading-dominated regime with an initially advancing triple line; iii) a cross-over region with strong pinning effects. The overall picture is in qualitative agreement with a mathematical model showing that the selected regime mostly depends on the value of a dimensionless parameter comparing the time scales for evaporation and spreading into the substrate texture.

  6. Effect of environmental dust particles on laser textured yttria-stabilized zirconia surface in humid air ambient

    Science.gov (United States)

    Yilbas, B. S.; Ali, H.; Al-Sharafi, A.; Al-Sulaiman, F.; Karatas, C.

    2018-05-01

    Zirconium nitride is used as a selective surface for concentrated solar heating applications and one of the methods to form a zirconium nitride is texturing of zirconia surface by a high intensity laser beam under high pressure nitrogen gas environment. Laser texturing also provides hydrophobic surface characteristics via forming micro/nano pillars at the surface; however, environmental dust settlement on textured surface influences the surface characteristics significantly. In the present study, laser texturing of zirconia surface and effects of the dust particles on the textured surface in a humid air ambient are investigated. Analytical tools are used to assess the morphological changes on the laser textured surface prior and after the dust settlement in the humid air ambient. It is found that laser textured surface has hydrophobic characteristics. The mud formed during condensate of water on the dust particles alters the characteristics of the laser textured surface. The tangential force required to remove the dry mud from the textured surface remains high; in which case, the dried liquid solution at the mud-textured surface interface is responsible for the strong adhesion of the dry mud on the textured surface. The textured surface becomes hydrophilic after the dry mud was removed from the surface by a desalinated water jet.

  7. Study of amino acids dynamics, superconducting alloys and texture determination by neutron scattering. Coordinated programme on neutron scattering techniques in applied research

    International Nuclear Information System (INIS)

    Huhn Jun Kim

    1982-02-01

    Based on Bunges formalism, a computer program to analyze the fiber-type texture has been developed by expanding the orientation distribution function up to the 50th term. By annealing 99.9% cold-drawn copper wire, various degree of texture were developed. Using these samples, the accuracy of texture analysis has been studied by comparing experimental results with calculations obtained with various series truncations. Using the oriented silicon steels as sample, the sheet-type texture has been studied. Experimental evidences of the primary extinction and simultaneous reflections are discussed. From these, use of single-procedure geometry for pole figure measurement and precluding of strong reflections from input data for texture analysis are proposed to obtain accurate information for coarse-grained and strongly-textured materials. For the quantitative correlation between texture and physical anisotropy, the magnetic anisotropy energy and Young modulus in silicon steel have been studied by comparing measurements with theoretical results predicted from texture

  8. Height and Tilt Geometric Texture

    DEFF Research Database (Denmark)

    Andersen, Vedrana; Desbrun, Mathieu; Bærentzen, Jakob Andreas

    2009-01-01

    compromise between functionality and simplicity: it can efficiently handle and process geometric texture too complex to be represented as a height field, without having recourse to full blown mesh editing algorithms. The height-and-tilt representation proposed here is fully intrinsic to the mesh, making...

  9. Texture analysis using Gabor wavelets

    Science.gov (United States)

    Naghdy, Golshah A.; Wang, Jian; Ogunbona, Philip O.

    1996-04-01

    Receptive field profiles of simple cells in the visual cortex have been shown to resemble even- symmetric or odd-symmetric Gabor filters. Computational models employed in the analysis of textures have been motivated by two-dimensional Gabor functions arranged in a multi-channel architecture. More recently wavelets have emerged as a powerful tool for non-stationary signal analysis capable of encoding scale-space information efficiently. A multi-resolution implementation in the form of a dyadic decomposition of the signal of interest has been popularized by many researchers. In this paper, Gabor wavelet configured in a 'rosette' fashion is used as a multi-channel filter-bank feature extractor for texture classification. The 'rosette' spans 360 degrees of orientation and covers frequencies from dc. In the proposed algorithm, the texture images are decomposed by the Gabor wavelet configuration and the feature vectors corresponding to the mean of the outputs of the multi-channel filters extracted. A minimum distance classifier is used in the classification procedure. As a comparison the Gabor filter has been used to classify the same texture images from the Brodatz album and the results indicate the superior discriminatory characteristics of the Gabor wavelet. With the test images used it can be concluded that the Gabor wavelet model is a better approximation of the cortical cell receptive field profiles.

  10. Sensory memory and food texture

    NARCIS (Netherlands)

    Mojet, J.; Köster, E.P.

    2005-01-01

    Memory for texture plays an important role in food expectations. After fasting overnight, subjects (41 women, 35 men, age 19-60 years) received a breakfast including breakfast drink, biscuits and yoghurt. Subsequently, they rated their hunger feelings every hour, and returned for a taste experiment

  11. Sensory memory and food texture

    NARCIS (Netherlands)

    Mojet, J.; Koster, E.P.

    2005-01-01

    Memory for texture plays an important role in food expectations. After fasting overnight, subjects (41 women, 35 men, age 19¿60 years) received a breakfast including breakfast drink, biscuits and yoghurt. Subsequently, they rated their hunger feelings every hour, and returned for a taste experiment

  12. Euromet Comparison on Surface Texture

    DEFF Research Database (Denmark)

    Koenders, L.; Andreasen, Jan Lasson; De Chiffre, Leonardo

    2004-01-01

    In the region of EUROMET, we performed from 2001 to 2003 a comparison covering a number among the most interesting parameters in the field of surface texture, i.e. Pt, D, Ra, Rz, RSm, and the Rk-parameters. 16 institutes carried out measurements on typical roughness standards as described in ISO...

  13. Texture of lipid bilayer domains

    DEFF Research Database (Denmark)

    Jensen, Uffe Bernchou; Brewer, Jonathan R.; Midtiby, Henrik Skov

    2009-01-01

    We investigate the texture of gel (g) domains in binary lipid membranes composed of the phospholipids DPPC and DOPC. Lateral organization of lipid bilayer membranes is a topic of fundamental and biological importance. Whereas questions related to size and composition of fluid membrane domain...

  14. Texture analysis of oxide dispersion strengthened (ODS) Fe alloys by X-ray and neutron diffraction

    Science.gov (United States)

    Béchade, J. L.; Mathon, M. H.; Branger, V.; Réglé, H.; Alamo, A.

    2002-07-01

    The ferritic ODS alloys studied were obtained by mechanical alloying. This strengthening method is very attractive, in particular for nuclear applications. In order to ensure the alloy a good compromise between mechanical resistance and ductility at high temperatures, it is necessary to control the microstructure and in particular the evolution during the recrystallization. First, a preliminary study, performed by X ray diffraction and optical microscopy, shows several grain growth mechanisms ; in particular, the “abnormal” grain growth mechanism which conducts to a large grain size [1], [2]. After annealing (3600s at 1470^{circ}C), the 30% cold-worked (swaging) alloys exhibit an heterogeneous microstructure with a large grains size ( 200 to 500 μm) in the heart and near the surface of the material when the intermediate zone is inhabited by small grains ( 1 μm). Fora higher cold-work level (60%), large size grains are only present in the periphery of the material. On account of the large grain size and strong heterogeneity of the microstructure, texture analysis using laboratory x-ray beam in not well adapted and so we have decided to use neutron beam. The neutron diffraction texture analysis has been performed at the Laboratoire Léon Brillouin on the 6T1 diffractometer on 2 different rods of the alloy (corresponding to the reduction ratios of 30% and 60%). Specific samples have been machined to characterise separately the zones with a different microstructure. After deformation, the alloys exhibit a typical α-fibre texture \\{ hkl \\} whatever the area of the sample and the reduction ratio. After recrystallization, a very inhomogeneous texture is evidenced through the thickness of the sample, in particular for the rod deformed with a reduction ratio of 30% : in the heart and in the periphery of the rod, a “single-crystal” type texture is observed; the a fibre remains for the intermediate diameter of the rod. For the rod cold rolled with a reduction

  15. Synchrotron high energy X-ray diffraction study of microstructure evolution of severely cold drawn NiTi wire during annealing

    Energy Technology Data Exchange (ETDEWEB)

    Yu, Cun; Aoun, Bachir; Cui, Lishan; Liu, Yinong; Yang, Hong; Jiang, Xiaohua; Cai, Song; Jiang, Daqiang; Liu, Zunping; Brown, Dennis E.; Ren, Yang

    2016-08-01

    Microstructure evolution of a cold-drawn NiTi shape memory alloy wire was investigated by means of in-situ synchrotron high-energy X-ray diffraction during continuous heating. The cold-drawn wire contained amorphous regions and nano-crystalline domains in its microstructure. Pair distribution function analysis revealed that the amorphous regions underwent structural relaxation via atomic rearrangement when heated above 100 °C. The nano-crystalline domains were found to exhibit a strong cold work induced lattice strain anisotropy having a preferential <111> fiber orientation along the wire axial direction. The lattice strain anisotropy systematically decreased upon heating above 200 °C, implying a structural recovery. A broad conical texture was formed in the wire specimen after crystallization similar in detail to the initial <111> texture axial orientation of the nano-crystalline domains produced by the severe cold wire drawing deformation.

  16. Textured strontium titanate layers on platinum by atomic layer deposition

    International Nuclear Information System (INIS)

    Blomberg, T.; Anttila, J.; Haukka, S.; Tuominen, M.; Lukosius, M.; Wenger, Ch.; Saukkonen, T.

    2012-01-01

    Formation of textured strontium titanate (STO) layers with large lateral grain size (0.2–1 μm) and low X-ray reflectivity roughness (∼ 1.36 nm) on Pt electrodes by industry proven atomic layer deposition (ALD) method is demonstrated. Sr(t-Bu 3 Cp) 2 , Ti(OMe) 4 and O 3 precursors at 250 °C were used to deposit Sr rich STO on Pt/Ti/SiO 2 /Si ∅200 mm substrates. After crystallization post deposition annealing at 600 °C in air, most of the STO grains showed a preferential orientation of the {001} plane parallel to the substrate surface, although other orientations were also present. Cross sectional and plan view transmission electron microscopy and electron diffraction analysis revealed more than an order of magnitude larger lateral grain sizes for the STO compared to the underlying multicrystalline {111} oriented platinum electrode. The combination of platinum bottom electrodes with ALD STO(O 3 ) shows a promising path towards the formation of single oriented STO film. - Highlights: ► Amorphous strontium titanate (STO) on platinum formed a textured film after annealing. ► Single crystal domains in 60 nm STO film were 0.2–1 μm wide. ► Most STO grains were {001} oriented.

  17. Feature-aware natural texture synthesis

    KAUST Repository

    Wu, Fuzhang

    2014-12-04

    This article presents a framework for natural texture synthesis and processing. This framework is motivated by the observation that given examples captured in natural scene, texture synthesis addresses a critical problem, namely, that synthesis quality can be affected adversely if the texture elements in an example display spatially varied patterns, such as perspective distortion, the composition of different sub-textures, and variations in global color pattern as a result of complex illumination. This issue is common in natural textures and is a fundamental challenge for previously developed methods. Thus, we address it from a feature point of view and propose a feature-aware approach to synthesize natural textures. The synthesis process is guided by a feature map that represents the visual characteristics of the input texture. Moreover, we present a novel adaptive initialization algorithm that can effectively avoid the repeat and verbatim copying artifacts. Our approach improves texture synthesis in many images that cannot be handled effectively with traditional technologies.

  18. Diversity of primary CL textures in quartz from porphyry environments: implication for origin of quartz eyes

    Science.gov (United States)

    Vasyukova, O. V.; Kamenetsky, V. S.; Goemann, K.; Davidson, P.

    2013-10-01

    Porphyry-style mineralization is related to the intrusion and crystallization of small stocks, which can be of different compositions (from intermediate to felsic) and can intrude into different host rocks (from magmatic to sedimentary). We used cathodoluminescence and electron probe microanalysis to study the internal textures of more than 300 quartz eyes from six porphyry deposits, Panguna (Papua New Guinea), Far Southeast porphyry (Philippines), Batu Hijau (Indonesia), Antapaccay (Peru), Rio Blanco (Chile) and Climax (USA). Significant diversity of the internal textures in quartz eyes was revealed, sometimes even within a single sample. Quartz grains with Ti-rich cores surrounded by Ti-poor mantles were found next to the grains showing the opposite Ti distribution or only slight Ti fluctuations.We propose that diversity of the internal patterns in quartz eyes can actually reflect in situ crystallization history, and that prolonged crystallization after magma emplacement under conditions of continuous cooling can account for the observed features of internal textures. Formation of quartz eyes begins at high temperatures with crystallization of high titanium Quartz 1, which as the melt becomes more and more evolved and cooler, is overgrown by low Ti Quartz 2. Subsequent fluid exsolution brings about dramatic change in the melt composition: OH - , alkalis and other Cl-complexed elements partition into the fluid phase, whereas Ti stays in the melt, contributing to a rapid increase in Ti activity. Separation of the fluid and its further cooling causes disequilibrium in the system, and the Quartz 2 becomes partially resorbed. Exsolution of the fluid gradually builds up the pressure until it exceeds the yield strength of the host rocks and they then fracture. This pressure release most likely triggers crystallization of Quartz 3, which is higher in Ti than Quartz 2 because Ti activity in the melt is higher and pressure of crystallization is lower. As a result of the

  19. A multi-resolution texture fusion algorithm

    Science.gov (United States)

    Li, Yu Qin; Zhou, Xiang; Guo, Jia Yu; Yang, Tao; Fei, Zi Xuan

    2017-09-01

    Texture fusion is essential for three-dimensional photo-realistic texture model reconstruction. Multi-resolution texture fusion mainly is applied to reconstruct three-dimensional models that the local texture is very realistic. This paper presents a multi-resolution texture fusion algorithm based on digital image processing. The technique utilizes the depth camera to obtain range data and the texture camera to obtain the local interested high-resolution texture of the object. And each point of the range images a pixel of the picture corresponding to this view should be found, so the map between high-resolution texture and local three-dimensional points could be obtained by calibrating texture camera and depth camera to register the local high-resolution texture with the low resolution texture collected by the depth camera or calibrating texture camera and depth camera. ICP is applied to register models, and mapping different-resolution textures onto three-dimensional models. Then the light source correction of textures is applied to remove the systematic differences such as lighting change which are achieved by computing linear regression correction mode. Finally, the global correction is applied to refine the observable variations in color that may still exist near the fusion boundaries. These corrections will utilize the grid triangle vertex color as a constraint to drive texture fusion to remove discontinuities from different resolutions. The advantage of this technique is that it utilizes the light source correction and global correction to fuse different resolutions textures. Experiments with this technique indicate that it significantly corrects the observable discontinuities within the overlapping areas, which are given from different resolutions, lighting change, non-lambertian object surface, etc.

  20. Texture analysis using Renyi's generalized entropies

    NARCIS (Netherlands)

    Grigorescu, SE; Petkov, N

    2003-01-01

    We propose a texture analysis method based on Renyi's generalized entropies. The method aims at identifying texels in regular textures by searching for the smallest window through which the minimum number of different visual patterns is observed when moving the window over a given texture. The

  1. Real-time Texture Error Detection

    Directory of Open Access Journals (Sweden)

    Dan Laurentiu Lacrama

    2008-01-01

    Full Text Available This paper advocates an improved solution for the real-time error detection of texture errors that occurs in the production process in textile industry. The research is focused on the mono-color products with 3D texture model (Jacquard fabrics. This is a more difficult task than, for example, 2D multicolor textures.

  2. Evaluation of color representation for texture analysis

    NARCIS (Netherlands)

    Verbrugge, R.; van den Broek, Egon; van Rikxoort, E.M.; Taatgen, N.; Schomaker, L.

    2004-01-01

    Since more than 50 years texture in image material is a topic of research. Hereby, color was ignored mostly. This study compares 70 different configurations for texture analysis, using four features. For the configurations we used: (i) a gray value texture descriptor: the co-occurrence matrix and a

  3. Texture Control: Theoretical and Practical Study

    DEFF Research Database (Denmark)

    Leffers, Torben; Gangli, P.

    1978-01-01

    The possibility of controlling the rolling texture by simple modifications to the rolling process is investigated. It is demonstrated that the computer programs developed for simulation of the normal rolling textures can also satisfactorily predict textures formed under new rolling conditions...

  4. Deposition and characterisation of multilayer hard coatings. Ti/TiNδ/TiCxNy/(TiC) a-C:H/(Ti) a-C:H

    International Nuclear Information System (INIS)

    Burinprakhon, T.

    2001-02-01

    Multilayer hard coatings containing Ti, TiNδ, TiC x N y , (TiC m ) a-C:H, (TiC n ) a-C:H, and (Ti) a-C:H were deposited on commercially pure titanium substrates by using an asymmetric bipolar pulsed-dc reactive magnetron sputtering of a titanium target, with Ar, Ar+N 2 , Ar+N 2 +CH 4 , and Ar+CH 4 gas mixtures. The microstructures, elemental compositions and bonding states of the interlayers and the coating surfaces were studied by using cross-sectional transmission electron microscopy (XTEM), electron energy loss spectroscopy (EELS), X-ray diffraction (XRD), Raman spectroscopy, and X-ray photoelectron spectroscopy (XPS). The microstructure development of the multilayer coating was strongly influenced by target poisoning. As a result of the complete poisoning of the titanium target during the deposition of TiNδ and TiC x N y interlayers, the a-C:H interlayers containing graded titanium and nitrogen contents were found to develop successively to the TiC x N y interlayer without the formation of near-stoichiometric TiC. The (TiC m ) a-C:H interlayer consisted of nano-particles of distorted fcc crystal structure embedded in the a-C:H matrix. The (TiC n ) a-C:H and (Ti) a-C:H top layers were found to be a-C:H matrix without nano-particles. In the (Ti) a-C:H top layer there was no measurable amount of Ti observed, regardless of the variation of CH 4 concentration between 37.5 and 60 % flow rate in Ar+-CH4 gas mixture. The top layer (Ti) a-C:H was found to contain approximately 10 atomic % nitrogen, due to N 2 contamination during deposition caused by low conductance of N 2 through the nominally closed valve of the mass flow controller. The change of the CH 4 concentration during deposition of the top layer (Ti) a-C:H, however, showed a strong influence on the hydrogen content. The comparison of the fluorescence background of the Raman spectra revealed that hydrogen-less (Ti) a-C:H was deposited at a CH 4 concentration of less than 50 % flow rate in Ar. The hardness

  5. Watermarking textures in video games

    Science.gov (United States)

    Liu, Huajian; Berchtold, Waldemar; Schäfer, Marcel; Lieb, Patrick; Steinebach, Martin

    2014-02-01

    Digital watermarking is a promising solution to video game piracy. In this paper, based on the analysis of special challenges and requirements in terms of watermarking textures in video games, a novel watermarking scheme for DDS textures in video games is proposed. To meet the performance requirements in video game applications, the proposed algorithm embeds the watermark message directly in the compressed stream in DDS files and can be straightforwardly applied in watermark container technique for real-time embedding. Furthermore, the embedding approach achieves high watermark payload to handle collusion secure fingerprinting codes with extreme length. Hence, the scheme is resistant to collusion attacks, which is indispensable in video game applications. The proposed scheme is evaluated in aspects of transparency, robustness, security and performance. Especially, in addition to classical objective evaluation, the visual quality and playing experience of watermarked games is assessed subjectively in game playing.

  6. Estimates of Aboveground Biomass from Texture Analysis of Landsat Imagery

    Directory of Open Access Journals (Sweden)

    Katharine C. Kelsey

    2014-07-01

    Full Text Available Maps of forest biomass are important tools for managing natural resources and reporting terrestrial carbon stocks. Using the San Juan National Forest in Southwest Colorado as a case study, we evaluate regional biomass maps created using physical variables, spectral vegetation indices, and image textural analysis on Landsat TM imagery. We investigate eight gray level co-occurrence matrix based texture measures (mean, variance, homogeneity, contrast, dissimilarity, entropy, second moment and correlation on four window sizes (3 × 3, 5 × 5, 7 × 7, 9 × 9 at four offsets ([1,0], [1,1], [0,1], [1,−1] on four Landsat TM bands (2, 3, 4, and 5. The map with the highest prediction quality was created using three texture metrics calculated from Landsat Band 2 on a 3 × 3 window and an offset of [0,1]: entropy, mean and correlation; and one physical variable: slope. The correlation of predicted versus observed biomass values for our texture-based biomass map is r = 0.86, the Root Mean Square Error is 45.6 Mg∙ha−1, and the Coefficient of Variation of the Root Mean Square Error is 0.31. We find that models including image texture variables are more strongly correlated with biomass than models using only physical and spectral variables. Additionally, we suggest that the use of texture appears to better capture the magnitude and direction of biomass change following disturbance compared to spectral approaches. The biomass mapping methods we present here are widely applicable throughout the US, as they are based on publically available datasets and utilize relatively simple analytical routines.

  7. Pattern Formation and Reaction Textures during Dunite Carbonation

    Science.gov (United States)

    Lisabeth, H. P.; Zhu, W.

    2015-12-01

    Alteration of olivine-bearing rocks by fluids is one of the most pervasive geochemical processes on the surface of the Earth. Serpentinized and/or carbonated ultramafic rocks often exhibit characteristic textures on many scales, from polygonal mesh textures on the grain-scale to onion-skin or kernel patterns on the outcrop scale. Strong disequilibrium between pristine ultramafic rocks and common geological fluids such as water and carbon dioxide leads to rapid reactions and coupled mechanical and chemical feedbacks that manifest as characteristic textures. Textural evolution during metasomatic reactions can control effective reaction rates by modulating dynamic porosity and therefore reactant supply and reactive surface area. We run hydrostatic experiments on thermally cracked dunites saturated with carbon dioxide bearing brine at 15 MPa confining pressure and 150°C to explore the evolution of physical properties and reaction textures as carbon mineralization takes place in the sample. Compaction and permeability reduction are observed throughout experiments. Rates of porosity and permeability changes are sensitive to pore fluid chemistry. After reaction, samples are imaged in 3-dimension (3D) using a dual-beam FIB-SEM. Analysis of the high resolution 3D microstructure shows that permeable, highly porous domains are created by olivine dissolution at a characteristic distance from pre-existing crack surfaces while precipitation of secondary minerals such as serpentine and magnesite is limited largely to the primary void space. The porous dissolution channels provide an avenue for fluid ingress, allow reactions to continue and could lead to progressive hierarchical fracturing. Initial modeling of the system indicates that this texture is the result of coupling between dissolution-precipitation reactions and the local stress state of the sample.

  8. Texture evaluation in warm deformation of an extruded Mg–6Al–3Zn alloy

    Directory of Open Access Journals (Sweden)

    M. Kavyani

    2016-06-01

    Full Text Available To assess the effect of strain and strain rate on texture evolution of an extruded Mg–6Al–3Zn alloy, compression tests were carried out. Samples were prepared in the extrusion direction (ED and normal direction (ND. The compression tests were performed at 250 °C and with different strain rates of 0.01 sec−1 and 1 sec−1 and different strains. Microstructural observation and texture investigation show that at early stages of deformation, extension twins lead to the development of strong basal texture intensity along rolling direction (RD in ED samples and contraction twins result in texture evolution along transverse direction (TD in ND samples. Also, microstructural investigation at high strains reveals that dynamic recrystallization occurs in both samples and consequently the basal texture intensity has been decreased.

  9. Dielectric enhancement of BaTiO3/SrTiO3 superlattices with embedded Ni nanocrystals

    International Nuclear Information System (INIS)

    Xiong Zhengwei; Sun Weiguo; Wang Xuemin; Jiang Fan; Wu Weidong

    2012-01-01

    Highlights: ► The BaTiO 3 /SrTiO 3 superlattices with embedded Ni NCs were successfully fabricated by L-MBE. ► The influence with the various concentrations of Ni nanocrystals embedded in BaTiO 3 /SrTiO 3 superlattices was also discussed. ► The BaTiO 3 /SrTiO 3 superlattices with lower concentration of embedded Ni NCs had higher permittivity and dielectric loss compared with the pure BaTiO 3 /SrTiO 3 superlattices. ► The dielectric enhancement of BaTiO 3 /SrTiO 3 superlattices with embedded Ni NCs was proposed to explained by Drude quasi-free-electron theory. - Abstract: The self-organized Ni nanocrystals (NCs) were embedded in BaTiO 3 /SrTiO 3 superlattices using laser molecular beam epitaxy (L-MBE). The stress of the composite films was increased with the increasing concentration of embedded Ni NCs, as investigation in stress calculation. The influence with the various concentrations of Ni NCs embedded in BaTiO 3 /SrTiO 3 superlattices was also discussed. The internal stress of the films was too strong to epitaxial growth of BaTiO 3 /SrTiO 3 superlattices. Compared with the pure BaTiO 3 /SrTiO 3 superlattices, the BaTiO 3 /SrTiO 3 superlattices with lower concentration of embedded Ni NCs had higher permittivity and dielectric loss. Furthermore, the dielectric enhancement of BaTiO 3 /SrTiO 3 superlattices with embedded Ni NCs was proposed to explained by Drude quasi-free-electron theory.

  10. Microstructure and mechanical characteristics of laser coating-texturing alloying dimples

    International Nuclear Information System (INIS)

    Wan Daping; Chen Bingkui; Shao Yimin; Wang Shilong; Hu Dejin

    2008-01-01

    A novel laser coating-texturing (LCT) technique was proposed to achieve appropriate surface topographies and frictional behaviour. The LCT process was realized by applying laser pulses at very high repetition rate to produce innumerable micro-craters with required shape profile on the surface of the workpiece. Moreover, surface alloying of the dimples was carried out by melting submicron WC-TiC-Co alloy powder on the substrates. Morphology and microstructures of the texturing layers were characterised using optical microscopy (OM), scanning electron microscopy (SEM), and X-ray diffraction (XRD). Mechanical properties of the textured samples were evaluated by abrasive resistance tests and microhardness measurement. Experimental results show that good fusion bonding between the texturing layers and the substrate has been formed, and the texturing layers are mainly composed of dense and hard fine-grained structures. The abrasive wear resistance of the laser coating-textured surface was 10 times higher than that of the substrates. The average surface microhardness values were as high as 830 HV.

  11. Texture Classification for 3D Urban Map

    Directory of Open Access Journals (Sweden)

    Inatsuka Hiroyuki

    2009-01-01

    Full Text Available This paper proposes a method to control texture resolution for rendering large-scale 3D urban maps. Since on the 3D maps texture data generally tend to be far larger than geometry information such as vertices and triangles, it is more effective to reduce the texture by exploiting the LOD (Level of Detail in order to decrease whole data size. For this purpose, we propose a new method to control the resolution of the texture. In our method we classify the textures to four classes based on their salient features. The appropriate texture resolutions are decided based on the classification resulsts, their rendered sizes on a display, and their level of importance. We verify the validity of our texture classification algorithm by applying it to the large-scale 3D urban map rendering.

  12. Residual stress in magnetron sputtered TiN

    NARCIS (Netherlands)

    Zoestbergen, E; de Hosson, J.T.M.; Brebbia, CA; Kenny, JM

    1999-01-01

    In this study magnetron sputtered TiN layers are investigated with X-ray diffraction. The measurements show that there is a texture present and in these layers a non-linear d-sin(2)psi behavior for the (200) planes was found. The latter cannot be explained by the well-known causes that may generate

  13. Measurement and analysis of field-induced crystallographic texture using curved position-sensitive diffraction detectors

    DEFF Research Database (Denmark)

    Simons, Hugh; Daniels, John E.; Studer, Andrew J.

    2014-01-01

    This paper outlines measurement and analysis methodologies created for determining the structural responses of electroceramics to an electric field. A sample stage is developed to apply electric fields to ceramic materials at elevated temperatures during neutron diffraction experiments. The tested...... employing a curved positive sensitive detector. Methodologies are proposed to account for the geometrical effects when vector fields are applied to textured materials with angularly dispersive detector geometries. Representative results are presented for the ferroelectric (Bi1/2Na1/2)TiO3-6%BaTiO3 (BNT-6BT......) which show both phase transformation and ferroelectric domain texturing under the application of an electric field. This experimental and analysis approach is well suited for time-resolved measurements such as stroboscopic and in situ studies on a variety of electro-active materials....

  14. Texturing in Earth's inner core due to preferential growth in its equatorial belt

    Science.gov (United States)

    Deguen, Renaud; Cardin, Philippe; Merkel, Sébastien; Lebensohn, Ricardo A.

    2011-10-01

    We propose an extension of the model by Yoshida et al., 1996 where deformation in the inner core is forced by preferential growth in the equatorial belt, by taking into account the presence of a stable compositional stratification. Stratification inhibits vertical motion, imposes a flow parallel to isodensity surfaces, and concentrates most deformation in a shallow shear layer of thickness ˜ B-1/5, where B is the dimensionless buoyancy number. The localization of the flow results in large strain rates and enables the development of a strong alignment of iron crystals in the upper inner core. We couple our dynamical model with a numerical model of texture development and compute the time evolution of the lattice preferred orientation of different samples in the inner core. With sufficient stratification, texturing is significant in the uppermost inner core. In contrast, the deeper inner core is unaffected by any flow and may preserve a fossil texture. We investigate the effect of an initial texture resulting from solidification texturing at the ICB. In the present inner core, the deformation rate in the shallow shear layer is large and can significantly alter the solidification texturing, but the solidification texture acquired early in the inner core history can be preserved in the deeper part. Using elastic constants from ab initio calculations, we predict different maps of anisotropy in the modern inner core. A model with both solidification texturing and subsequent deformation in a stratified inner core produces a global anisotropy in reasonable agreement with seismological observations.

  15. Investigation of rail wheel steel crystallographic texture changes due to modification and thermomechanical treatment

    Science.gov (United States)

    Lychagina, T.; Nikolayev, D.; Sanin, A.; Tatarko, J.; Ullemeyer, K.

    2015-04-01

    In this work crystallographic texture for a set of rail wheel steel samples with different regimes of thermo-mechanical treatment and with and without modification by system Al-Mg-Si- Fe-C-Ca-Ti-Ce was measured by neutron diffraction. The texture measurements were carried out by using time-of-flight technique at SKAT diffractometer situated at IBR-2 reactor (Dubna, JINR, Russia). The three complete pole figures (110), (200), (211) of α-Fe phase in 5°×5°grid were extracted from a set of 1368 spectra measured for each sample. The samples were cut from rail wheel rim and from transitional zone (between rail wheel hub and wheel disk). It was concluded that the steel modification and some changes in the heat treatment modes of the rail wheels from the experimental (modified) and the conventional (non-modified) steel lead to reorientation of texture component.

  16. Cirrhosis Classification Based on Texture Classification of Random Features

    Directory of Open Access Journals (Sweden)

    Hui Liu

    2014-01-01

    Full Text Available Accurate staging of hepatic cirrhosis is important in investigating the cause and slowing down the effects of cirrhosis. Computer-aided diagnosis (CAD can provide doctors with an alternative second opinion and assist them to make a specific treatment with accurate cirrhosis stage. MRI has many advantages, including high resolution for soft tissue, no radiation, and multiparameters imaging modalities. So in this paper, multisequences MRIs, including T1-weighted, T2-weighted, arterial, portal venous, and equilibrium phase, are applied. However, CAD does not meet the clinical needs of cirrhosis and few researchers are concerned with it at present. Cirrhosis is characterized by the presence of widespread fibrosis and regenerative nodules in the hepatic, leading to different texture patterns of different stages. So, extracting texture feature is the primary task. Compared with typical gray level cooccurrence matrix (GLCM features, texture classification from random features provides an effective way, and we adopt it and propose CCTCRF for triple classification (normal, early, and middle and advanced stage. CCTCRF does not need strong assumptions except the sparse character of image, contains sufficient texture information, includes concise and effective process, and makes case decision with high accuracy. Experimental results also illustrate the satisfying performance and they are also compared with typical NN with GLCM.

  17. Electromigration-induced Plasticity: Texture Correlation and Implications for Reliability Assessment

    Energy Technology Data Exchange (ETDEWEB)

    Budiman, A.S.; Besser, P.R.; Hau-Riege, C.S.; Marathe, A.; Joo, Y.-C.; Tamura, N.; Patel, J.R.; Nix, W.D.

    2008-05-29

    Plastic behavior has previously been observed in metallic interconnects undergoing high current density electromigration (EM) loading. In this study of Cu interconnects, using the synchrotron technique of white beam X-ray microdiffraction, we have further found preliminary evidence of a texture correlation. In lines with strong (111) textures, the extent of plastic deformation is found to be relatively large compared to that of weaker textures. We suggest that this strong (111) texture may lead to an extra path of mass transport in addition to the dominant interface diffusion in Cu EM. When this extra mass transport begins to affect the overall transport process, then the effective diffusivity, D{sub eff}, of the EM process is expected to deviate from that of interface diffusion only. This would have fundamental implications. We have some preliminary observations that this might be the case, and we report its implications for EM lifetime assessment in this manuscript.

  18. New Developments of Ti-Based Alloys for Biomedical Applications

    Science.gov (United States)

    Li, Yuhua; Yang, Chao; Zhao, Haidong; Qu, Shengguan; Li, Xiaoqiang; Li, Yuanyuan

    2014-01-01

    Ti-based alloys are finding ever-increasing applications in biomaterials due to their excellent mechanical, physical and biological performance. Nowdays, low modulus β-type Ti-based alloys are still being developed. Meanwhile, porous Ti-based alloys are being developed as an alternative orthopedic implant material, as they can provide good biological fixation through bone tissue ingrowth into the porous network. This paper focuses on recent developments of biomedical Ti-based alloys. It can be divided into four main sections. The first section focuses on the fundamental requirements titanium biomaterial should fulfill and its market and application prospects. This section is followed by discussing basic phases, alloying elements and mechanical properties of low modulus β-type Ti-based alloys. Thermal treatment, grain size, texture and properties in Ti-based alloys and their limitations are dicussed in the third section. Finally, the fourth section reviews the influence of microstructural configurations on mechanical properties of porous Ti-based alloys and all known methods for fabricating porous Ti-based alloys. This section also reviews prospects and challenges of porous Ti-based alloys, emphasizing their current status, future opportunities and obstacles for expanded applications. Overall, efforts have been made to reveal the latest scenario of bulk and porous Ti-based materials for biomedical applications. PMID:28788539

  19. New Developments of Ti-Based Alloys for Biomedical Applications

    Directory of Open Access Journals (Sweden)

    Yuhua Li

    2014-03-01

    Full Text Available Ti-based alloys are finding ever-increasing applications in biomaterials due to their excellent mechanical, physical and biological performance. Nowdays, low modulus β-type Ti-based alloys are still being developed. Meanwhile, porous Ti-based alloys are being developed as an alternative orthopedic implant material, as they can provide good biological fixation through bone tissue ingrowth into the porous network. This paper focuses on recent developments of biomedical Ti-based alloys. It can be divided into four main sections. The first section focuses on the fundamental requirements titanium biomaterial should fulfill and its market and application prospects. This section is followed by discussing basic phases, alloying elements and mechanical properties of low modulus β-type Ti-based alloys. Thermal treatment, grain size, texture and properties in Ti-based alloys and their limitations are dicussed in the third section. Finally, the fourth section reviews the influence of microstructural configurations on mechanical properties of porous Ti-based alloys and all known methods for fabricating porous Ti-based alloys. This section also reviews prospects and challenges of porous Ti-based alloys, emphasizing their current status, future opportunities and obstacles for expanded applications. Overall, efforts have been made to reveal the latest scenario of bulk and porous Ti-based materials for biomedical applications.

  20. Simulation of Deformation Texture Evolution During Multi Axial Forging of Interstitial Free Steel

    Science.gov (United States)

    Gurao, N. P.; Kumar, P.; Sarkar, A.; Brokmeier, H.-G.; Suwas, Satyam

    2013-04-01

    Bulk texture measurement of multi-axial forged body center cubic interstitial free steel performed in this study using x-ray and neutron diffraction indicated the presence of a strong {101} single texture component. Viscoplastic self-consistent simulations could successfully predict the formation of this texture component by incorporating the complicated strain path followed during this process and assuming the activity of {101} slip system. In addition, a first-order estimate of mechanical properties in terms of highly anisotropic yield locus and Lankford parameter was also obtained from the simulations.

  1. Epitaxial growth of textured YBa2Cu3O7-δ films on silver

    International Nuclear Information System (INIS)

    Liu Dan-Min; Liu Wei-Peng; Suo Hong-Li; Zhou Mei-Ling

    2005-01-01

    YBa 2 Cu 3 O 7-δ (YBCO) films were deposited on (100), (110) and (111) oriented silver single crystals and {100} left angle 100 right angle, {110} left angle 211 right angle, {110} left angle 100 right angle +{110} left angle 011 right angle {110} left angle 011 right angle and {012} left angle 100 right angle textured Ag substrates using pulsed laser deposition. The relationship between the epitaxial growth YBCO film and silver substrate has been determined. It is shown that among polycrystalline Ag substrates, {110} left angle 011 right angle textured tape is suitable for the deposition of YBCO thin films having strong texture. (orig.)

  2. Effect of Nano-TiC Dispersed Particles and Electro-Codeposition Parameters on Morphology and Structure of Hybrid Ni/TiC Nanocomposite Layers.

    Science.gov (United States)

    Benea, Lidia; Celis, Jean-Pierre

    2016-04-06

    This research work describes the effect of dispersed titanium carbide (TiC) nanoparticles into nickel plating bath on Ni/TiC nanostructured composite layers obtained by electro-codeposition. The surface morphology of Ni/TiC nanostructured composite layers was characterized by scanning electron microscopy (SEM). The composition of coatings and the incorporation percentage of TiC nanoparticles into Ni matrix were studied and estimated by using energy dispersive X-ray analysis (EDX). X-ray diffractometer (XRD) has been applied in order to investigate the phase structure as well as the corresponding relative texture coefficients of the composite layers. The results show that the concentration of nano-TiC particles added in the nickel electrolyte affects the inclusion percentage of TiC into Ni/TiC nano strucured layers, as well as the corresponding morphology, relative texture coefficients and thickness indicating an increasing tendency with the increasing concentration of nano-TiC concentration. By increasing the amount of TiC nanoparticles in the electrolyte, their incorporation into nickel matrix also increases. The hybrid Ni/nano-TiC composite layers obtained revealed a higher roughness and higher hardness; therefore, these layers are promising superhydrophobic surfaces for special application and could be more resistant to wear than the pure Ni layers.

  3. Effect of Nano-TiC Dispersed Particles and Electro-Codeposition Parameters on Morphology and Structure of Hybrid Ni/TiC Nanocomposite Layers

    Directory of Open Access Journals (Sweden)

    Lidia Benea

    2016-04-01

    Full Text Available This research work describes the effect of dispersed titanium carbide (TiC nanoparticles into nickel plating bath on Ni/TiC nanostructured composite layers obtained by electro-codeposition. The surface morphology of Ni/TiC nanostructured composite layers was characterized by scanning electron microscopy (SEM. The composition of coatings and the incorporation percentage of TiC nanoparticles into Ni matrix were studied and estimated by using energy dispersive X-ray analysis (EDX. X-ray diffractometer (XRD has been applied in order to investigate the phase structure as well as the corresponding relative texture coefficients of the composite layers. The results show that the concentration of nano-TiC particles added in the nickel electrolyte affects the inclusion percentage of TiC into Ni/TiC nano strucured layers, as well as the corresponding morphology, relative texture coefficients and thickness indicating an increasing tendency with the increasing concentration of nano-TiC concentration. By increasing the amount of TiC nanoparticles in the electrolyte, their incorporation into nickel matrix also increases. The hybrid Ni/nano-TiC composite layers obtained revealed a higher roughness and higher hardness; therefore, these layers are promising superhydrophobic surfaces for special application and could be more resistant to wear than the pure Ni layers.

  4. Measurement of neutral Ti atoms from TiC and Ti targets sputtered by low-energy H+ and Ar+ ions using laser-induced fluorescence

    International Nuclear Information System (INIS)

    Yamada, R.; Bay, H.L.; Schweer, B.

    1984-01-01

    The sputtering of Ti from TiC and also from pure Ti targets for 500 eV H + and Ar + ion irradiation at normal incidence has been investigated by laser-induced fluorescence. The sputtered neutral Ti atoms in the ground state were observed as a function of fluence and target temperature. This technique is shown to be applicable for in-situ sputtering investigations of TiC. Strong fluence dependences of the fluorescence intensities for Ti and TiC targets were observed. These results are discussed from the viewpoint of chemisorption of oxygen on the target surfaces. In the case of H + bombardment, the depleted layer of carbon atoms near the surface of TiC due to chemical sputtering should also be taken into account to explain the fluence dependence of the fluorescence intensity. No significant temperature dependence of the Ti sputtering yield of TiC for Ar + and H + ion bombardment was found in the steady state, and the physical sputtering yield of the Ti component of TiC is about half the Ti yield from a Ti target for Ar + ion bombardment. (orig.)

  5. Structural and Electrical Properties of Ag/ n-TiO2/ p-Si/Al Heterostructure Fabricated by Pulsed Laser Deposition Technique

    Science.gov (United States)

    Kumar, Arvind; Sharma, K. K.; Kumar, Rajender; Chand, Subhash; Kumar, Ashwani

    2017-11-01

    We have investigated the structural and electrical characteristics of the Ag/ n-TiO2/ p-Si/Al heterostructure. Thin films of pure TiO2 were deposited on p-type silicon (100) by optimized pulsed laser ablation with a KrF-excimer laser in an oxygen-controlled environment. X-ray diffraction analysis showed the formation of crystalline TiO2 film having a tetragonal texture with a strong (210) plane as the preferred direction. High purity aluminium and silver metals were deposited to obtain ohmic contacts on p-Si and n-TiO2, respectively. The current-voltage ( I- V) characteristics of the fabricated heterostructure were studied by using thermionic emission diffusion mechanism over the temperature range of 80-300 K. Parameters such as barrier height and ideality factor were derived from the measured I- V data of the heterostructure. The detailed analysis of I- V measurements revealed good rectifying behavior in the inhomogeneous Ag/ n-TiO2/ p-Si(100)/Al heterostructure. The variations of barrier height and ideality factor with temperature and the non-linearity of the activation energy plot confirmed that barrier heights at the interface follow Gaussian distributions. The value of Richardson's constant was found to be 6.73 × 105 Am-2 K-2, which is of the order of the theoretical value 3.2 × 105 Am-2 K-2. The capacitance-voltage ( C- V) measurements of the heterostructure were investigated as a function of temperature. The frequency dependence (Mott-Schottky plot) of the C- V characteristics was also studied. These measurements indicate the occurrence of a built-in barrier and impurity concentration in TiO2 film. The optical studies were also performed using a UV-Vis spectrophotometer. The optical band gap energy of TiO2 films was found to be 3.60 eV.

  6. Growth and Characterisation of Pulsed-Laser Deposited Tin Thin Films on Cube-Textured Copper at Different Temperatures

    Directory of Open Access Journals (Sweden)

    Szwachta G.

    2016-06-01

    Full Text Available High-quality titanium nitride thin films have been grown on a cube-textured copper surface via pulsed laser deposition. The growth of TiN thin films has been very sensitive to pre-treatment procedure and substrate temperature. It is difficult to grow heteroexpitaxial TiN films directly on copper tape due to large differences in lattice constants, thermal expansion coefficients of the two materials as well as polycrystalline structure of substrate. The X-Ray diffraction measurement revealed presence of high peaks belonged to TiN(200 and TiN(111 thin films, depending on used etcher of copper surface. The electron diffraction patterns of TiN(200/Cu films confirmed the single-crystal nature of the films with cube-on-cube epitaxy. The high-resolution microscopy on our films revealed sharp interfaces between copper and titanium nitride with no presence of interfacial reaction.

  7. Comments on "Steganography Using Reversible Texture Synthesis".

    Science.gov (United States)

    Zhou, Hang; Chen, Kejiang; Zhang, Weiming; Yu, Nenghai

    2017-04-01

    Message hiding in texture image synthesis is a novel steganography approach by which we resample a smaller texture image and synthesize a new texture image with a similar local appearance and an arbitrary size. However, the mirror operation over the image boundary is flawed and is easy to attack. We propose an attacking method on this steganography, which can not only detect the stego-images but can also extract the hidden messages.

  8. Dry texturing of solar cells

    Science.gov (United States)

    Sopori, Bhushan L.

    1994-01-01

    A textured backside of a semiconductor device for increasing light scattering and absorption in a semiconductor substrate is accomplished by applying infrared radiation to the front side of a semiconductor substrate that has a metal layer deposited on its backside in a time-energy profile that first produces pits in the backside surface and then produces a thin, highly reflective, low resistivity, epitaxial alloy layer over the entire area of the interface between the semiconductor substrate and a metal contact layer. The time-energy profile includes ramping up to a first energy level and holding for a period of time to create the desired pit size and density and then rapidly increasing the energy to a second level in which the entire interface area is melted and alloyed quickly. After holding the second energy level for a sufficient time to develop the thin alloy layer over the entire interface area, the energy is ramped down to allow epitaxial crystal growth in the alloy layer. The result is a textured backside an optically reflective, low resistivity alloy interface between the semiconductor substrate and the metal electrical contact layer.

  9. Cascaded Amplitude Modulations in Sound Texture Perception

    Directory of Open Access Journals (Sweden)

    Richard McWalter

    2017-09-01

    Full Text Available Sound textures, such as crackling fire or chirping crickets, represent a broad class of sounds defined by their homogeneous temporal structure. It has been suggested that the perception of texture is mediated by time-averaged summary statistics measured from early auditory representations. In this study, we investigated the perception of sound textures that contain rhythmic structure, specifically second-order amplitude modulations that arise from the interaction of different modulation rates, previously described as “beating” in the envelope-frequency domain. We developed an auditory texture model that utilizes a cascade of modulation filterbanks that capture the structure of simple rhythmic patterns. The model was examined in a series of psychophysical listening experiments using synthetic sound textures—stimuli generated using time-averaged statistics measured from real-world textures. In a texture identification task, our results indicated that second-order amplitude modulation sensitivity enhanced recognition. Next, we examined the contribution of the second-order modulation analysis in a preference task, where the proposed auditory texture model was preferred over a range of model deviants that lacked second-order modulation rate sensitivity. Lastly, the discriminability of textures that included second-order amplitude modulations appeared to be perceived using a time-averaging process. Overall, our results demonstrate that the inclusion of second-order modulation analysis generates improvements in the perceived quality of synthetic textures compared to the first-order modulation analysis considered in previous approaches.

  10. Impact of Soil Texture on Soil Ciliate Communities

    Science.gov (United States)

    Chau, J. F.; Brown, S.; Habtom, E.; Brinson, F.; Epps, M.; Scott, R.

    2014-12-01

    Soil water content and connectivity strongly influence microbial activities in soil, controlling access to nutrients and electron acceptors, and mediating interactions between microbes within and between trophic levels. These interactions occur at or below the pore scale, and are influenced by soil texture and structure, which determine the microscale architecture of soil pores. Soil protozoa are relatively understudied, especially given the strong control they exert on bacterial communities through predation. Here, ciliate communities in soils of contrasting textures were investigated. Two ciliate-specific primer sets targeting the 18S rRNA gene were used to amplify DNA extracted from eight soil samples collected from Sumter National Forest in western South Carolina. Primer sets 121F-384F-1147R (semi-nested) and 315F-959R were used to amplify soil ciliate DNA via polymerase chain reaction (PCR), and the resulting PCR products were analyzed by gel electrophoresis to obtain quantity and band size. Approximately two hundred ciliate 18S rRNA sequences were obtained were obtained from each of two contrasting soils. Sequences were aligned against the NCBI GenBank database for identification, and the taxonomic classification of best-matched sequences was determined. The ultimate goal of the work is to quantify changes in the ciliate community under short-timescale changes in hydrologic conditions for varying soil textures, elucidating dynamic responses to desiccation stress in major soil ciliate taxa.

  11. Identification of ultra-fine Ti-rich precipitates in V-Cr-Ti alloys irradiated below 300 deg. C by using positron CDB technique

    International Nuclear Information System (INIS)

    Fukumoto, Ken-ichi; Matsui, Hideki; Ohkubo, Hideaki; Tang, Zheng; Nagai, Yasuyoshi; Hasegawa, Masayuki

    2008-01-01

    Irradiation-induced Ti-rich precipitates in V-Ti and V-4Cr-4Ti alloys are studied by TEM and positron annihilation methods (positron lifetime, and coincidence Doppler broadening (CDB)). The characteristics of small defect clusters formed in V alloys containing Ti at irradiation temperatures below 300 deg. C have not been identified by TEM techniques. Strong interaction between vacancy and Ti solute atoms for irradiated V alloys containing Ti at irradiation temperatures from 220 to 350 deg. C are observed by positron lifetime measurement. The vacancy-multi Ti solute complexes in V-alloys containing Ti are definitely identified by using CDB measurement. It is suggested that ultra-fine Ti-rich precipitates or Ti segregation at periphery of dislocation loops are formed in V alloys containing Ti at irradiation temperatures below 300 deg. C

  12. Contrast-negation and texture synthesis differentially disrupt natural texture appearance

    Directory of Open Access Journals (Sweden)

    Benjamin J Balas

    2012-11-01

    Full Text Available Natural textures have characteristic image statistics that make them discriminable from unnatural textures. For example, both contrast-negation and texture synthesis alter the appearance of natural textures even though each manipulation preserves some features while disrupting others. Here, we examined the extent to which contrast-negation and texture synthesis each introduce or remove critical perceptual features for discriminating unnatural textures from natural textures. We find that both manipulations remove information that observers use for distinguishing natural textures from transformed versions of the same patterns, but do so in different ways. Texture synthesis removes information that is relevant for discrimination in both abstract patterns and ecologically valid textures, and we also observe a category-dependent asymmetry for identifying an oddball real texture among synthetic distractors. Contrast negation exhibits no such asymmetry, and also does not impact discrimination performance in abstract patterns. We discuss our results in the context of the visual system’s tuning to ecologically relevant patterns and other results describing sensitivity to higher-order statistics in texture patterns.

  13. Textured strontium titanate layers on platinum by atomic layer deposition

    Energy Technology Data Exchange (ETDEWEB)

    Blomberg, T., E-mail: tom.blomberg@asm.com [ASM Microchemistry Ltd., Vaeinoe Auerin katu 12 A, 00560 Helsinki (Finland); Anttila, J.; Haukka, S.; Tuominen, M. [ASM Microchemistry Ltd., Vaeinoe Auerin katu 12 A, 00560 Helsinki (Finland); Lukosius, M.; Wenger, Ch. [IHP, Im Technologiepark 25, 15236 Frankfurt (Oder) (Germany); Saukkonen, T. [Aalto University, Puumiehenkuja 3, 02150 Espoo (Finland)

    2012-08-31

    Formation of textured strontium titanate (STO) layers with large lateral grain size (0.2-1 {mu}m) and low X-ray reflectivity roughness ({approx} 1.36 nm) on Pt electrodes by industry proven atomic layer deposition (ALD) method is demonstrated. Sr(t-Bu{sub 3}Cp){sub 2}, Ti(OMe){sub 4} and O{sub 3} precursors at 250 Degree-Sign C were used to deposit Sr rich STO on Pt/Ti/SiO{sub 2}/Si Empty-Set 200 mm substrates. After crystallization post deposition annealing at 600 Degree-Sign C in air, most of the STO grains showed a preferential orientation of the {l_brace}001{r_brace} plane parallel to the substrate surface, although other orientations were also present. Cross sectional and plan view transmission electron microscopy and electron diffraction analysis revealed more than an order of magnitude larger lateral grain sizes for the STO compared to the underlying multicrystalline {l_brace}111{r_brace} oriented platinum electrode. The combination of platinum bottom electrodes with ALD STO(O{sub 3}) shows a promising path towards the formation of single oriented STO film. - Highlights: Black-Right-Pointing-Pointer Amorphous strontium titanate (STO) on platinum formed a textured film after annealing. Black-Right-Pointing-Pointer Single crystal domains in 60 nm STO film were 0.2-1 {mu}m wide. Black-Right-Pointing-Pointer Most STO grains were {l_brace}001{r_brace} oriented.

  14. The Honeycomb illusion: Uniform textures not perceived as such

    Directory of Open Access Journals (Sweden)

    Marco Bertamini

    2016-07-01

    Full Text Available We present a series of patterns, in which texture is perceived differently at fixation in comparison to the periphery, such that a physically uniform stimulus yields a nonuniform percept. We call this the Honeycomb illusion, and we discuss it in relation to the similar Extinction illusion (Ninio & Stevens, 2000. The effect remains strong despite multiple fixations, dynamic changes, and manipulations of the size of texture elements. We discuss the phenomenon in relation to how vision achieves a detailed and stable representation of the environment despite changes in retinal spatial resolution and dramatic changes across saccades. The Honeycomb illusion complements previous related observations in suggesting that this representation is not necessarily based on multiple fixations (i.e., memory or on extrapolation from information available to central vision.

  15. Texture developed during deformation of Transformation Induced Plasticity (TRIP) steels

    International Nuclear Information System (INIS)

    Bhargava, M; Asim, T; Sushil, M; Shanta, C

    2015-01-01

    Automotive industry is currently focusing on using advanced high strength steels (AHSS) due to its high strength and formability for closure applications. Transformation Induced Plasticity (TRIP) steel is promising material for this application among other AHSS. The present work is focused on the microstructure development during deformation of TRIP steel sheets. To mimic complex strain path condition during forming of automotive body, Limit Dome Height (LDH) tests were conducted and samples were deformed in servo hydraulic press to find the different strain path. FEM Simulations were done to predict different strain path diagrams and compared with experimental results. There is a significant difference between experimental and simulation results as the existing material models are not applicable for TRIP steels. Micro texture studies were performed on the samples using EBSD and X-RD techniques. It was observed that austenite is transformed to martensite and texture developed during deformation had strong impact on limit strain and strain path. (paper)

  16. Structure, Texture and Phases in 3D Printed IN718 Alloy Subjected to Homogenization and HIP Treatments

    Directory of Open Access Journals (Sweden)

    Ahmad Mostafa

    2017-05-01

    Full Text Available 3D printing results in anisotropy in the microstructure and mechanical properties. The focus of this study is to investigate the structure, texture and phase evolution of the as-printed and heat treated IN718 superalloy. Cylindrical specimens, printed by powder-bed additive manufacturing technique, were subjected to two post-treatments: homogenization (1100 °C, 1 h, furnace cooling and hot isostatic pressing (HIP (1160 °C, 100 MPa, 4 h, furnace cooling. The Selective laser melting (SLM printed microstructure exhibited a columnar architecture, parallel to the building direction, due to the heat flow towards negative z-direction. Whereas, a unique structural morphology was observed in the x-y plane due to different cooling rates resulting from laser beam overlapping. Post-processing treatments reorganized the columnar structure of a strong {002} texture into fine columnar and/or equiaxed grains of random orientations. Equiaxed structure of about 150 µm average grain size, was achieved after homogenization and HIP treatments. Both δ-phase and MC-type brittle carbides, having rough morphologies, were formed at the grain boundaries. Delta-phase formed due to γ″-phase dissolution in the γ matrix, while MC-type carbides nucleates grew by diffusion of solute atoms. The presence of (Nb0.78Ti0.22C carbide phase, with an fcc structure having a lattice parameter a = 4.43 Å, was revealed using Energy dispersive spectrometer (EDS and X-ray diffractometer (XRD analysis. The solidification behavior of IN718 alloy was described to elucidate the evolution of different phases during selective laser melting and post-processing heat treatments of IN718.

  17. Effect of strontium tantalate surface texture on nickel nanoparticle dispersion by electroless deposition

    Energy Technology Data Exchange (ETDEWEB)

    Compean-González, C.L. [Universidad Autónoma de Nuevo León, Facultad de Ingeniería Civil, Departamento de Ecomateriales y Energía, Av. Universidad s/n, Ciudad Universitaria, San Nicolás de los Garza, Nuevo León C.P. 66451 (Mexico); Arredondo-Torres, V.M. [Facultad de Químico Farmacobiología, Universidad Michoacana de San Nicolás de Hidalgo, Tzintzuntzan #173, Col. Matamoros, Morelia, Michoacán C.P. 58240 (Mexico); Zarazúa-Morin, M.E. [Universidad Autónoma de Nuevo León, Facultad de Ingeniería Civil, Departamento de Ecomateriales y Energía, Av. Universidad s/n, Ciudad Universitaria, San Nicolás de los Garza, Nuevo León C.P. 66451 (Mexico); Figueroa-Torres, M.Z., E-mail: m.zyzlila@gmail.com [Universidad Autónoma de Nuevo León, Facultad de Ingeniería Civil, Departamento de Ecomateriales y Energía, Av. Universidad s/n, Ciudad Universitaria, San Nicolás de los Garza, Nuevo León C.P. 66451 (Mexico)

    2015-09-15

    Highlights: • Efficient short-time procedure for nickel nanoparticles dispersion by electroless. • Nanoparticles are spherical in shape with an average size of 15 nm. • Influence of surface texture on deposition temperature and time was observed. • Nickel deposition can be done below 50 °C. - Abstract: The present work studies the effect of smooth and porous texture of Sr{sub 2}Ta{sub 2}O{sub 7} on its surface modification with nickel nanoparticles through electroless deposition technique. The influence of temperature to control Ni nanoparticles loading amount and dispersion were analyzed. Nitrogen adsorption isotherms were used to examine surface texture characteristics. The morphology was observed by scanning electron microscopy (MEB) equipped with an energy dispersive spectrometry system (EDS), which was used to determine the amount of deposited Ni. The material with smooth texture (SMT) consists of big agglomerates of semispherical shape particles of 400 nm. Whilst the porous texture (PRT) exhibit a pore-wall formed of needles shape particles of around 200 nm in size. Results indicated that texture characteristics strongly influence the deposition reaction rate; for PRT oxide, Ni deposition can be done from 20 °C while for SMT oxide deposition begins at 40 °C. Analysis of Sr{sub 2}Ta{sub 2}O{sub 7} surface indicated that in both textures, Ni nanoparticles with spherical shape in the range of 10–20 nm were obtained.

  18. Effect of strontium tantalate surface texture on nickel nanoparticle dispersion by electroless deposition

    International Nuclear Information System (INIS)

    Compean-González, C.L.; Arredondo-Torres, V.M.; Zarazúa-Morin, M.E.; Figueroa-Torres, M.Z.

    2015-01-01

    Highlights: • Efficient short-time procedure for nickel nanoparticles dispersion by electroless. • Nanoparticles are spherical in shape with an average size of 15 nm. • Influence of surface texture on deposition temperature and time was observed. • Nickel deposition can be done below 50 °C. - Abstract: The present work studies the effect of smooth and porous texture of Sr 2 Ta 2 O 7 on its surface modification with nickel nanoparticles through electroless deposition technique. The influence of temperature to control Ni nanoparticles loading amount and dispersion were analyzed. Nitrogen adsorption isotherms were used to examine surface texture characteristics. The morphology was observed by scanning electron microscopy (MEB) equipped with an energy dispersive spectrometry system (EDS), which was used to determine the amount of deposited Ni. The material with smooth texture (SMT) consists of big agglomerates of semispherical shape particles of 400 nm. Whilst the porous texture (PRT) exhibit a pore-wall formed of needles shape particles of around 200 nm in size. Results indicated that texture characteristics strongly influence the deposition reaction rate; for PRT oxide, Ni deposition can be done from 20 °C while for SMT oxide deposition begins at 40 °C. Analysis of Sr 2 Ta 2 O 7 surface indicated that in both textures, Ni nanoparticles with spherical shape in the range of 10–20 nm were obtained

  19. Mechanical seal with textured sidewall

    Energy Technology Data Exchange (ETDEWEB)

    Khonsari, Michael M.; Xiao, Nian

    2017-02-14

    The present invention discloses a mating ring, a primary ring, and associated mechanical seal having superior heat transfer and wear characteristics. According to an exemplary embodiment of the present invention, one or more dimples are formed onto the cylindrical outer surface of a mating ring sidewall and/or a primary ring sidewall. A stationary mating ring for a mechanical seal assembly is disclosed. Such a mating ring comprises an annular body having a central axis and a sealing face, wherein a plurality of dimples are formed into the outer circumferential surface of the annular body such that the exposed circumferential surface area of the annular body is increased. The texture added to the sidewall of the mating ring yields superior heat transfer and wear characteristics.

  20. Cool Polar Bears: Dabbing on the Texture

    Science.gov (United States)

    O'Connell, Jean

    2011-01-01

    In this article, the author describes how her second-graders created their cool polar bears. The students used the elements of shape and texture to create the bears. They used Monet's technique of dabbing paint so as to give the bear some texture on his fur.

  1. On the origin of recrystallization textures

    Indian Academy of Sciences (India)

    Unknown

    specially oriented grains have a high mobility boundary and thus can migrate faster and grow to a larger size as compared to random orientations thus contributing to the final recrystallization texture. In FCC metals and alloys like aluminium, cube orientation [(001) 〈100〉] is the recrystallization texture component.

  2. On texture formation of chromium electrodeposits

    DEFF Research Database (Denmark)

    Nielsen, Christian Bergenstof; Leisner, Peter; Horsewell, Andy

    1998-01-01

    The microstructure, texture and hardness of electrodeposited hard, direct current (DC) chromium and pulsed reversed chromium has been investigated. These investigations suggest that the growth and texture of hard chromium is controlled by inhibition processes and reactions. Further, it has been...... established that codeposition of Cr2O3 nanoparticles is a general feature of DC chromium electrodeposition....

  3. Friction tensor concept for textured surfaces

    Indian Academy of Sciences (India)

    Depending on the sliding direction the coefficient of friction varies between maximum and minimum for textured surfaces. For random surfaces without any texture the friction coefficient becomes independent of the sliding direction. This paper proposes the concept of a friction tensor analogous to the heat conduction tensor ...

  4. On the origin of recrystallization textures

    Indian Academy of Sciences (India)

    Unknown

    specially oriented grains have a high mobility boundary and thus can migrate faster and grow to a larger size as compared to random orientations thus contributing to the final recrystallization texture. In FCC metals and alloys like aluminium, cube orientation [(001) 〈100〉] is the recrystallization texture component. In the ...

  5. Cascaded Amplitude Modulations in Sound Texture Perception

    DEFF Research Database (Denmark)

    McWalter, Richard Ian; Dau, Torsten

    2017-01-01

    Sound textures, such as crackling fire or chirping crickets, represent a broad class of sounds defined by their homogeneous temporal structure. It has been suggested that the perception of texture is mediated by time-averaged summary statistics measured from early auditory representations...

  6. Texture design for light touch perception

    NARCIS (Netherlands)

    Zhang, S.; Zeng, X.; Matthews, D.T.A.; Igartua, A.; Rodriguez Vidal, E.; Fortes, J. Contreras; Van Der Heide, E.

    This study focused on active light touch with predefined textures specially-designed for tactile perception. The counter-body material is stainless steel sheet. Three geometric structures (grid, crater and groove) were fabricated by pulsed laser surface texturing. A total number of twenty volunteers

  7. Carbon Dioxide Sealing Capacity: Textural or Compositional Controls?

    Energy Technology Data Exchange (ETDEWEB)

    Cranganu, Constantin; Soleymani, Hamidreza; Sadiqua, Soleymani; Watson, Kieva

    2013-11-30

    . Mercury Injection Porosimetry (MIP), Scanning Electron Microsco-py SEM, and Sedigraph measurements are used to assess the pore-throat-size distribu-tion, sorting, texture, and grain size of the samples. Also, displacement pressure at 10% mercury saturation (Pd) and graphically derived threshold pressure (Pc) were deter-mined by MIP technique. SEM images were used for qualitative study of the minerals and pores texture of the core samples. Moreover, EDS (Energy Dispersive X-Ray Spec-trometer), BET specific surface area, and Total Organic Carbon (TOC) measurements were performed to study various parameters and their possible effects on sealing capaci-ty of the samples. We found that shales have the relatively higher average sealing threshold pressure (Pc) than carbonate and sandstone samples. Based on these observations, shale formations could be considered as a promising caprock in terms of retarding scCO{sub 2} flow and leak-age into above formations. We hypothesized that certain characteristics of shales (e.g., 3 fine pore size, pore size distribution, high specific surface area, and strong physical chemical interaction between wetting phase and mineral surface) make them an effi-cient caprock for sealing super critical CO{sub 2}. We found that the displacement pressure at 10% mercury saturation could not be the ultimate representative of the sealing capacity of the rock sample. On the other hand, we believe that graphical method, introduced by Cranganu (2004) is a better indicator of the true sealing capacity. Based on statistical analysis of our samples from Oklahoma Panhandle we assessed the effects of each group of properties (textural and compositional) on maximum supercriti-cal CO{sub 2} height that can be hold by the caprock. We conclude that there is a relatively strong positive relationship (+.40 to +.69) between supercritical CO{sub 2} column height based on Pc and hard/ soft mineral content index (ratio of minerals with Mohs hardness more than 5 over minerals

  8. Effects of hot-rolling reduction on microstructure, texture and magnetic properties of high silicon steel produced by strip casting

    Science.gov (United States)

    Hou, D. Y.; Xu, H. J.; Jiao, H. T.; Zhao, C. W.; Xiong, W.; Yang, J. P.; Qiu, W. Z.; Xu, Y. B.

    2017-01-01

    Non-oriented Fe-7.1wt.% Si as-cast strips were produced by twin-roll strip casting process. Then the as-cast strips were hot rolled with different reductions, followed by warm rolling and final annealing. The microstructure, texture evolution and magnetic properties were investigated in detail. The texture of hot rolled sheets with 40% reduction showed strongest {001} texture, whereas the dominated texture was turned into {110} and {110}as the reduction was increased to 56% and 68%. After warm rolling and annealing, the average grain size was decreased firstly and then increased with an increase in hot rolling reduction. In the case of 40% hot rolling reduction, the recrystallization texture was dominated by strong γ (//ND) texture. With an increase in hot rolling reduction, the γ texture was gradually weakened while α (//RD) texture was enhanced. In addition, relatively stronger {100} texture was presented in the sheet of 68% hot rolling reduction. The highest B50 value attained was 1.66 T and the lowest P10/400 was 24.26 W/kg at a reduction of 56%.

  9. Bayesian exploration for intelligent identification of textures

    Directory of Open Access Journals (Sweden)

    Jeremy A. Fishel

    2012-06-01

    Full Text Available In order to endow robots with humanlike abilities to characterize and identify objects, they must be provided with tactile sensors and intelligent algorithms to select, control and interpret data from useful exploratory movements. Humans make informed decisions on the sequence of exploratory movements that would yield the most information for the task, depending on what the object may be and prior knowledge of what to expect from possible exploratory movements. This study is focused on texture discrimination, a subset of a much larger group of exploratory movements and percepts that humans use to discriminate, characterize, and identify objects. Using a testbed equipped with a biologically inspired tactile sensor (the BioTac® we produced sliding movements similar to those that humans make when exploring textures. Measurement of tactile vibrations and reaction forces when exploring textures were used to extract measures of textural properties inspired from psychophysical literature (traction, roughness, and fineness. Different combinations of normal force and velocity were identified to be useful for each of these three properties. A total of 117 textures were explored with these three movements to create a database of prior experience to use for identifying these same textures in future encounters. When exploring a texture, the discrimination algorithm adaptively selects the optimal movement to make and property to measure based on previous experience to differentiate the texture from a set of plausible candidates, a process we call Bayesian exploration. Performance of 99.6% in correctly discriminating pairs of similar textures was found to exceed human capabilities. Absolute classification from the entire set of 117 textures generally required a small number of well-chosen exploratory movements (median=5 and yielded a 95.4% success rate. The method of Bayesian exploration developed and tested in this paper may generalize well to other

  10. Evolution of Intergranular Stresses in a Martensitic and an Austenitic NiTi Wire During Loading–Unloading Tensile Deformation

    Energy Technology Data Exchange (ETDEWEB)

    Cai, S.; Schaffer, J. E.; Yu, C.; Daymond, M. R.; Ren, Y.

    2015-03-19

    In situ synchrotron X-ray diffraction testing was carried out on a martensitic and an austenitic NiTi wire to study the evolution of internal stresses and the stress-induced martensite (SIM) phase transformation during room temperature tensile deformation. From the point of lattice strain evolution, it is concluded that (1) for the martensitic NiTi wire, detwinning of the [011](B19') type II twins and the {010}(B19') compound twins is responsible for internal strains formed at the early stage of deformation. (2) The measured diffraction moduli of individual martensite families show large elastic anisotropy and strong influences of texture. (3) For the austenitic NiTi wire, internal residual stresses were produced due to transformation-induced plasticity, which is more likely to occur in austenite families that have higher elastic moduli than their associated martensite families. (4) Plastic deformation was observed in the SIM at higher stresses, which largely decreased the lower plateau stresses.

  11. Minerals Concentration and Textural Properties of Romanian Beef Row and Cooked Meat and Offal

    Directory of Open Access Journals (Sweden)

    Liliana Tudoreanu

    2013-11-01

    Full Text Available Introduction: Consumers preferences for solid food are, for the majority of foods groups, influenced by their textural properties. Romanian traditional cuisine is rich in meat foods and therefore this food group has an important contribution to the total mineral intake as well as the ingestion of potentially toxic metals such as Cd and Pb. Although beef liver is an important source of minerals for human consumption, its concentrations in Cd and Pb and heterogeneous textural properties may hinder its acceptability. Aims: The purpose of the work was to estimate raw and cooked beef meat and offal mineral quality including Cd and Pb concentrations and their contribution to a balanced human diet and health  as well as the influenced of thermal preparation on their mineral and textural properties. Materials and methods:  Beef liver, kidney and longissimus dorsi muscle were bought from local markets. Thermal preparation was conducted by microwave and boiling with no water contact. Texture profile analyses was conducted for quantifying textural properties such as  Hardness, Cohesiveness, Springiness, Springiness Index, Chewiness, Adhesiveness and Stiffness. The mineral concentrations of the raw and cooked samples were analyzed by ICP-MS. Conclusion: The offal textural parameters variability was very large within the same organ and compared to the muscle textural parameters variability too. Muscle and offal thermal preparation strongly influenced their minerals’ concentrations as well as their textural properties. Thermal preparation significantly decreased beef liver and kidney samples’ total K and Na concentrations. It is suggested that for improving beef liver acceptability, the consumer has to be advised on the influence of the thermal preparation on beef liver parts’ textural properties as well as minerals concentrations.

  12. Review of the Methods for Production of Spherical Ti and Ti Alloy Powder

    Science.gov (United States)

    Sun, Pei; Fang, Zhigang Zak; Zhang, Ying; Xia, Yang

    2017-10-01

    Spherical titanium alloy powder is an important raw material for near-net-shape fabrication via a powder metallurgy (PM) manufacturing route, as well as feedstock for powder injection molding, and additive manufacturing (AM). Nevertheless, the cost of Ti powder including spherical Ti alloy has been a major hurdle that prevented PM Ti from being adopted for a wide range of applications. Especially with the increasing importance of powder-bed based AM technologies, the demand for spherical Ti powder has brought renewed attention on properties and cost, as well as on powder-producing processes. The performance of Ti components manufactured from powder has a strong dependence on the quality of powder, and it is therefore crucial to understand the properties and production methods of powder. This article aims to provide a cursory review of the basic techniques of commercial and emerging methods for making spherical Ti powder. The advantages as well as limitations of different methods are discussed.

  13. Application of Hydrothermal and Non-Hydrothermal TiO2 Nanoporous Materials as New Adsorbents for Removal of Heavy Metal Ions from Aqueous System

    Directory of Open Access Journals (Sweden)

    Mansoor Anbia

    2016-06-01

    Full Text Available Hydrothermal and non-hydrothermal spherical TiO2 nanoporous with crystalline framework were prepared by sol-gel method. The Crystalline structures, morphologies and surface texturing of materials were determined by X-ray diffraction (XRD, scanning electron microscopy (SEM and N2 adsorption-desorption isotherms. The Hydrothermal spherical TiO2 nanoporous was found to have a narrow and strong pore size distribution peaks with average of 37.8 Å and pore volume of 0.41 cm3/g and the (Brunauer–Emmett–TellerBET specific surface area of 365 m2/g. Hydrothermal and non-hydrothermal spherical TiO2 nanoporous have been used as adsorbent to study of the adsorption behavior of Pb(II, Co(II and Ni(II ions from aqueous system in a batch system. Effect of equilibrium time on adsorption Pb(II, Co(II and Ni(II ions on these adsorbent was studied The results show that the shaking time 0.5 to 10h has no serious effect on the percentage of ions removal, and the adsorption is fast in all cases. The maximum uptake capacities of Hydrothermal and non-hydrothermal spherical TiO2 nanoporous was calculated. Both hydrothermal and non-hydrothermal TiO2 nanoporous materials were found to have very good potential as new adsorbents in removal of these ions. In batch systems the maximum uptake capacities of Pb(II, Ni(II and Co(II on the hydrothermal and non-hydrothermal TiO2 nanoporous materials was Co(II > Pb(II > Ni(II and Co(II > Ni(II > Pb(II, respectively.

  14. The importance of secondary and ternary twinning in compressed Ti

    International Nuclear Information System (INIS)

    Tirry, W.; Nixon, M.; Cazacu, O.; Coghe, F.; Rabet, L.

    2011-01-01

    Twin formation during uniaxial compression of high-purity α-Ti at room temperature is investigated for both quasi-static and dynamic conditions using electron backscatter diffraction techniques. The initial texture is favorable for {101-bar 2} twinning, yet it is observed that secondary and ternary twins occur for both strain rates, showing a higher propensity in the dynamic case. While secondary twins may explain the difference in texture change and strain hardening between the two loading conditions, the ternary twins mainly contribute to grain fractioning.

  15. Thin NiTi Films Deposited on Graphene Substrates

    Science.gov (United States)

    Hahn, S.; Schulze, A.; Böhme, M.; Hahn, T.; Wagner, M. F.-X.

    2017-03-01

    We present experimental results on the deposition of Nickel Titanium (NiTi) films on graphene substrates using a PVD magnetron sputter process. Characterization of the 2-4 micron thick NiTi films by electron microscopy, electron backscatter diffraction, and transmission electron microscopy shows that grain size and orientation of the thin NiTi films strongly depend on the type of combination of graphene and copper layers below. Our experimental findings are supported by density functional theory calculations: a theoretical estimation of the binding energies of different NiTi-graphene interfaces is in line with the experimentally determined microstructural features of the functional NiTi top layer.

  16. Solid-texture synthesis: a survey.

    Science.gov (United States)

    Pietroni, Nico; Cignoni, Paolo; Otaduy, Miguel; Scopigno, Roberto

    2010-01-01

    Solid textures are an efficient way to compactly represent 3D objects' external and internal appearance, providing practical advantages over classic 2D texturing. Two main methods exist for synthesizing solid textures. Procedural methods obtain colors through functions that algorithmically encode the texture's appearance and structural properties. Example-based methods capture and replicate the appearance as described by a set of input exemplars. These methods can also be classified as boundary independent or boundary dependent. For boundary-independent methods, the shape of the object to be textured is irrelevant, and texture information can be freely generated for each point in the space. Boundary-dependent methods conform the synthesis process to the object's actual shape so that they can exploit this information to orient and guide texture generation. This article reviews the different methodologies' strengths and weaknesses, the classes of appearances they can successfully synthesize, and failure cases. In particular, it focuses on boundary-independent methods' advantages and drawbacks compared to boundary-dependent methods.

  17. Probing Majorana neutrino textures at DUNE

    Science.gov (United States)

    Bora, Kalpana; Borah, Debasish; Dutta, Debajyoti

    2017-10-01

    We study the possibility of probing different texture zero neutrino mass matrices at the long baseline neutrino experiment DUNE, particularly focusing on its sensitivity to the octant of atmospheric mixing angle θ23 and leptonic Dirac C P phase δcp. Assuming a diagonal charged lepton basis and Majorana nature of light neutrinos, we first classify the possible light neutrino mass matrices with one and two texture zeros and then numerically evaluate the parameter space which satisfies the texture zero conditions. Apart from using the latest global fit 3 σ values of neutrino oscillation parameters, we also use the latest bound on the sum of absolute neutrino masses (∑i |mi|) from the Planck mission data and the updated bound on effective neutrino mass Me e from neutrinoless double beta decay (0 ν β β ) experiments to find the allowed Majorana texture zero mass matrices. For the allowed texture zero mass matrices from all these constraints, we then feed the corresponding light neutrino parameter values satisfying the texture zero conditions into the numerical analysis in order to study the capability of DUNE to allow or exclude them once it starts taking data. We find that DUNE will be able to exclude some of these texture zero mass matrices which restrict (θ23-δcp) to a very specific range of values, depending on the values of the parameters that nature has chosen.

  18. Silicate glasses corrosion. Texture analysis of the corrosion layer

    International Nuclear Information System (INIS)

    Portal, Sabine

    2001-01-01

    We have studied the kinetic and the texture evolution of the corroded layer that forms on glass surfaces exposed to acidic solutions. The corroded layer is depleted in alkali cations and is produced by an ion exchange mechanism. It is porous and shows a lower refractive index than the one of the bulk glass. Spectroscopic ellipsometry allows determining the thickness of the layer and its refractive index. Several other techniques have been developed for characterizing the corrosion behaviour of glass surfaces: porosity is thus investigated by adsorption-desorption of nitrogen; the thickness and the composition of the layer are studied by secondary ion mass spectroscopy (S.I.M.S.); sodium concentration in the solution has been analyzed by atomic absorption. This study shows the importance of leaching conditions and glass preparation. The type of drying employed is susceptible to modify the texture and the structure of the layer. The layers produced in the early stages of the leaching process are not easily detectable. The different results lead however to the same conclusion: after a strong increase of porosity, a densification of the layer is observed with increasing time. The evolution of the layer texture could therefore modify the kinetic of the glass corrosion. (author) [fr

  19. Texture and wettability of metallic lotus leaves

    Science.gov (United States)

    Frankiewicz, C.; Attinger, D.

    2016-02-01

    Superhydrophobic surfaces with the self-cleaning behavior of lotus leaves are sought for drag reduction and phase change heat transfer applications. These superrepellent surfaces have traditionally been fabricated by random or deterministic texturing of a hydrophobic material. Recently, superrepellent surfaces have also been made from hydrophilic materials, by deterministic texturing using photolithography, without low-surface energy coating. Here, we show that hydrophilic materials can also be made superrepellent to water by chemical texturing, a stochastic rather than deterministic process. These metallic surfaces are the first analog of lotus leaves, in terms of wettability, texture and repellency. A mechanistic model is also proposed to describe the influence of multiple tiers of roughness on wettability and repellency. This demonstrated ability to make hydrophilic materials superrepellent without deterministic structuring or additional coatings opens the way to large scale and robust manufacturing of superrepellent surfaces.Superhydrophobic surfaces with the self-cleaning behavior of lotus leaves are sought for drag reduction and phase change heat transfer applications. These superrepellent surfaces have traditionally been fabricated by random or deterministic texturing of a hydrophobic material. Recently, superrepellent surfaces have also been made from hydrophilic materials, by deterministic texturing using photolithography, without low-surface energy coating. Here, we show that hydrophilic materials can also be made superrepellent to water by chemical texturing, a stochastic rather than deterministic process. These metallic surfaces are the first analog of lotus leaves, in terms of wettability, texture and repellency. A mechanistic model is also proposed to describe the influence of multiple tiers of roughness on wettability and repellency. This demonstrated ability to make hydrophilic materials superrepellent without deterministic structuring or additional

  20. Shaping drops with textured surfaces

    Science.gov (United States)

    Ehlinger, Quentin; Biance, Anne-Laure; Ybert, Christophe

    2017-11-01

    When a drop impacts a substrate, it can behave differently depending on the nature of the surface and of the liquid (spreading, bouncing, resting, splashing ...). Understanding these behaviors is crucial to predict the drop morphology during and after impact. Whereas surface wettability has extensively been studied, the effect of surface roughness remains hardly explored. In this work, we consider the impact of a drop in a pure non-wetting situation by using superheated substrates i.e. in the Leidenfrost regime. The surface texture consists of a well-controlled microscopic defect shaped with photolithography on a smooth silicon wafer. Different regimes are observed, depending on the distance between the defect and the impact point and the defect size. Comparing the lamella thickness versus the defect height proves relevant as the transition criteria between regimes. Others characteristics of the drop behavior (direction of satellite droplet ejection, lamella rupture) are also well captured by inertial/capillary models. Drop impacts on multiple defects are also investigated and drop shape well predicted considering the interactions between the local flow and the defects.

  1. Texture investigation by neutron diffraction

    International Nuclear Information System (INIS)

    Feldmann, K.

    1987-01-01

    In the conventional angle dispersive neutron diffraction a monochromatic neutron beam is used. The pole figures under investigation have to be scanned one after another. The commonly applied angle dispersive method is limited to the consideration of Bragg reflection being isolated in the diffraction pattern. The application of multidetectors or position sensitive detectors is discussed. In the neutron time-of-flight (TOF) diffraction a white pulsed neutron beam allows one to satisfy the Bragg law for all lattice spacing at a fixed scattering angle. The main charateristics of the TOF diffraction experiment are shortly outlined. In this method all non-forbidden Bragg reflections are recorded in one pattern simultaneously. The TOF technique is well-suited to study low symmetric or multiphased specimens, especially geological materials, requiring a large number of pole figures for mathematical texture analysis. Multidetector systems can be used to shorten the necessary time for experiments. The registration of all Bragg reflections of fixed scattering geometry is equivalent to the information of the inverse pole figure for the corresponding sample position. Having short exposition times this approach can be applied for in-situ investigations. The magnetic moments of neutrons can be used to study magnetic anisotropies in materials. Two different techniques are discussed

  2. Role of City Texture in Urban Heat Islands at Nighttime

    Science.gov (United States)

    Sobstyl, J. M.; Emig, T.; Qomi, M. J. Abdolhosseini; Ulm, F.-J.; Pellenq, R. J.-M.

    2018-03-01

    An urban heat island (UHI) is a climate phenomenon that results in an increased air temperature in cities when compared to their rural surroundings. In this Letter, the dependence of an UHI on urban geometry is studied. Multiyear urban-rural temperature differences and building footprints data combined with a heat radiation scaling model are used to demonstrate for more than 50 cities worldwide that city texture—measured by a building distribution function and the sky view factor—explains city-to-city variations in nocturnal UHIs. Our results show a strong correlation between nocturnal UHIs and the city texture.

  3. Scale-free texture of the fast solar wind

    Science.gov (United States)

    Hnat, B.; Chapman, S. C.; Gogoberidze, G.; Wicks, R. T.

    2011-12-01

    The higher-order statistics of magnetic field magnitude fluctuations in the fast quiet solar wind are quantified systematically, scale by scale. We find a single global non-Gaussian scale-free behavior from minutes to over 5 h. This spans the signature of an inertial range of magnetohydrodynamic turbulence and a ˜1/f range in magnetic field components. This global scaling in field magnitude fluctuations is an intrinsic component of the underlying texture of the solar wind and puts a strong constraint on any theory of solar corona and the heliosphere. Intriguingly, the magnetic field and velocity components show scale-dependent dynamic alignment outside of the inertial range.

  4. Testing strong interaction theories

    International Nuclear Information System (INIS)

    Ellis, J.

    1979-01-01

    The author discusses possible tests of the current theories of the strong interaction, in particular, quantum chromodynamics. High energy e + e - interactions should provide an excellent means of studying the strong force. (W.D.L.)

  5. A comparative study of precipitation effects in Ti only and Ti-V Ultra Low Carbon (ULC) strip steels

    International Nuclear Information System (INIS)

    Ooi, S.W.; Fourlaris, G.

    2006-01-01

    Two ULC steel grades were investigated, one based on combined vanadium and titanium additions and the other based on titanium only additions. It has been established that TiC formation during interphase precipitation retards grain growth of the {111} texture grains during continuous annealing and hence positively affects the r value of the Ti only steel. The formation of newly formed TiC precipitates on dislocations during continuous annealing has been found to result in an increase of the yield strength in both steel grades, as the annealing temperature is increased. It is also confirmed that VC particles formed during the coiling process dissolve during the continuous annealing cycles. Suitable continuous annealing cycles can be adopted to produce high formable steels with a bake hardening potential using the beneficial effects of combined Ti-V additions

  6. Diffraction analysis of materials under strong plastic deformation

    International Nuclear Information System (INIS)

    Pyzalla, A.

    2001-01-01

    The applicability of X-ray diffraction in analyses of the microstructure texture and intrinsic stresses of materials under strong plastic deformation is illustrated by examples and discussed. The experimental methods and findings are supplemented by numeric calculations. It is shown how the microstructure, texture and intrinsic stresses can thus be optimized already in the production process. Analyses of changes in materials during operation of a component provide information on loads and material response to loads which can then be used for optimization of the component, e.g. by constructional modifications or selective heat treatment [de

  7. Strain glass transition in a multifunctional β-type Ti alloy

    Science.gov (United States)

    Wang, Yu; Gao, Jinghui; Wu, Haijun; Yang, Sen; Ding, Xiangdong; Wang, Dong; Ren, Xiaobing; Wang, Yunzhi; Song, Xiaoping; Gao, Jianrong

    2014-02-01

    Recently, a class of multifunctional Ti alloys called GUM metals attracts tremendous attentions for their superior mechanical behaviors (high strength, high ductility and superelasticity) and novel physical properties (Invar effect, Elinvar effect and low modulus). The Invar and Elinvar effects are known to originate from structural or magnetic transitions, but none of these transitions were found in the GUM metals. This challenges our fundamental understanding of their physical properties. In this study, we show that the typical GUM metal Ti-23Nb-0.7Ta-2Zr-1.2O (at%) alloy undergoes a strain glass transition, where martensitic nano-domains are frozen gradually over a broad temperature range by random point defects. These nano-domains develop strong texture after cold rolling, which causes the lattice elongation in the rolling direction associated with the transition upon cooling and leads to its Invar effect. Moreover, its Elinvar effect and low modulus can also be explained by the nano-domain structure of strain glass.

  8. SMAPVEX12 Soil Texture Map V001

    Data.gov (United States)

    National Aeronautics and Space Administration — This data set consists of soil texture classification data derived from field surveys as part of the Soil Moisture Active Passive Validation Experiment 2012...

  9. Neutron diffraction texture analysis for industrial applications

    International Nuclear Information System (INIS)

    Brokmeier, H.G.

    1994-01-01

    Considering the high transmission of neutron radiation, neutron diffraction is an efficient tool for the analysis of various material parameters of bulk material in a non-destructive way. Industrial application of texture analysis by X-ray diffraction is well established, whereas neutron diffraction applications are seldom. Thus a brief description explains the main differences between X-ray and neutron diffraction regarding texture measurements such as the investigation of coarse-grained materials, of large sample volumes and of multi-phase materials. The investigation of average textures of large sample volumes allows directly a correlation to material properties (e.g. Young's modulus, electric conductivity, plastic deformability, strength), which were determined on a workpiece. Examples will be given to show some applications of neutron diffraction texture analysis for technological interests. (orig.)

  10. Evolution of solidification texture during additive manufacturing

    Science.gov (United States)

    Wei, H. L.; Mazumder, J.; DebRoy, T.

    2015-01-01

    Striking differences in the solidification textures of a nickel based alloy owing to changes in laser scanning pattern during additive manufacturing are examined based on theory and experimental data. Understanding and controlling texture are important because it affects mechanical and chemical properties. Solidification texture depends on the local heat flow directions and competitive grain growth in one of the six preferred growth directions in face centered cubic alloys. Therefore, the heat flow directions are examined for various laser beam scanning patterns based on numerical modeling of heat transfer and fluid flow in three dimensions. Here we show that numerical modeling can not only provide a deeper understanding of the solidification growth patterns during the additive manufacturing, it also serves as a basis for customizing solidification textures which are important for properties and performance of components. PMID:26553246

  11. ZrC zone structure and features of electronic structure of solid solutions on the base ZrC, ZrN, TiC and TiN

    International Nuclear Information System (INIS)

    Mokhracheva, L.P.; Gel'd, P.V.; Tskhaj, V.A.

    1983-01-01

    The results of ZrC zone structure calculation conducted using the strong bond method in the three-centre variant are given. Essentially higher degree of M-C chemical bond ionicity than in TiC is shown to take place for it. Solid solution formation in TiC-ZrC, TiN-ZrC and ZrC-ZrN systems differing from TiC-TiN, TiN-ZrN and TiC-TiN is stated to be followed by essential deformation of component zone structures that, obviously, should prevent formation of solid solutions without vacancies in sublatices in these systems

  12. A parametric texture model based on deep convolutional features closely matches texture appearance for humans.

    Science.gov (United States)

    Wallis, Thomas S A; Funke, Christina M; Ecker, Alexander S; Gatys, Leon A; Wichmann, Felix A; Bethge, Matthias

    2017-10-01

    Our visual environment is full of texture-"stuff" like cloth, bark, or gravel as distinct from "things" like dresses, trees, or paths-and humans are adept at perceiving subtle variations in material properties. To investigate image features important for texture perception, we psychophysically compare a recent parametric model of texture appearance (convolutional neural network [CNN] model) that uses the features encoded by a deep CNN (VGG-19) with two other models: the venerable Portilla and Simoncelli model and an extension of the CNN model in which the power spectrum is additionally matched. Observers discriminated model-generated textures from original natural textures in a spatial three-alternative oddity paradigm under two viewing conditions: when test patches were briefly presented to the near-periphery ("parafoveal") and when observers were able to make eye movements to all three patches ("inspection"). Under parafoveal viewing, observers were unable to discriminate 10 of 12 original images from CNN model images, and remarkably, the simpler Portilla and Simoncelli model performed slightly better than the CNN model (11 textures). Under foveal inspection, matching CNN features captured appearance substantially better than the Portilla and Simoncelli model (nine compared to four textures), and including the power spectrum improved appearance matching for two of the three remaining textures. None of the models we test here could produce indiscriminable images for one of the 12 textures under the inspection condition. While deep CNN (VGG-19) features can often be used to synthesize textures that humans cannot discriminate from natural textures, there is currently no uniformly best model for all textures and viewing conditions.

  13. Texture characterisation of hexagonal metals: Magnesium AZ91 alloy, welded by laser processing

    International Nuclear Information System (INIS)

    Kouadri, A.; Barrallier, L.

    2006-01-01

    Cooled and cast magnesium AZ91 alloy was welded using a CO 2 laser. The changes in the microstructure were analysed by optical and scanning electron microscopy and X-ray diffraction. Modification of the anisotropic properties was evaluated by the characterization of the texture in the base metal, in the core of the welded zone and in the welded zone close to the surface. In the two former zones, we have not observed a texture. Laser welding only leads to a change of the grain size and a disappearance of the eutectic phase. By contrast, in the welded zone close to the surface, the laser process leads both to a finer microstructure, to a loss of the Al-content and to the presence of several texture components. In this zone, our results showed that these textures are on pyramidal {101-bar 1} and prismatic {101-bar 0} planes. Much of the explanation for such texture rests with the fact that during the laser welding, material solidifies in strong non-equilibrium conditions. The kinetics of the nucleation and the growth are partly controlled by the high-rise and high fall of the temperature and the power produced by the laser process. The nature of the texture has been explained by the presence of a columnar to equiaxed transition in the welded zone

  14. Performance evolution of fully and partially textured hydrodynamic journal bearings lubricated with two lubricants

    Science.gov (United States)

    Tala-ighil, N.; Fillon, M.

    2017-02-01

    This study investigates the evolution of the main bearing performance of partially and fully textured hydrodynamic journal bearing. The viscosity effect is also analysed by the mean of numerical simulations for two types of oil: the oil 1 (ISO VG 32, 31.3 cSt at 40 °C) has a lower viscosity than oil 2 (ISO VG 100, 93 cSt at 40 °C). Reynolds equation is solved by finite difference and Gauss-Seidel methods with over-relaxation for various operating conditions. It is shown that, under hydrodynamic lubrication regime, the improvement of the most important characteristics (the friction coefficient and minimum film thickness) of a textured journal bearing depend strongly on the lubricant viscosity and the journal rotational speed. The fully textured journal bearing is highly favorable at very low speeds while the partially textured journal bearing is more suitable for slightly higher speeds. The gain in bearing performance due to the texturing of the bushing disappears at a critical speed of the journal and then, for higher rotational speeds, the presence of textures becomes detrimental.

  15. Image-based non-contact monitoring of skin texture changed by piloerection for emotion estimation

    Science.gov (United States)

    Uchida, Mihiro; Akaho, Rina; Ogawa, Keiko; Tsumura, Norimichi

    2018-02-01

    In this paper, we find the effective feature values of skin textures captured by non-contact camera to monitor piloerection on the skin for emotion estimation. Recently, emotion estimation is required for service robots to interact with human more naturally. There are a lot of researches of estimating emotion and additional methods are required to improve emotion estimation because using only a few methods may not give enough information for emotion estimation. In the previous study, it is necessary to fix a device on the subject's arm for detecting piloerection, but the contact monitoring can be stress itself and distract the subject from concentrating in the stimuli and evoking strong emotion. So, we focused on the piloerection as the object obtained with non-contact methods. The piloerection is observed as goose bumps on the skin when the subject is emotionally moved, scared and so on. This phenomenon is caused by contraction of arrector pili muscles with the activation of sympathetic nervous system. This piloerection changes skin texture. Skin texture is important in the cosmetic industry to evaluate skin condition. Therefore, we thought that it will be effective to evaluate the condition of skin texture for emotion estimation. The evaluations were performed by extracting the effective feature values from skin textures captured with a high resolution camera. The effective feature values should have high correlation with the degree of piloerection. In this paper, we found that standard deviation of short-line inclination angles in the texture is well correlated with the degree of piloerection.

  16. Viable textures for the fermion sector

    International Nuclear Information System (INIS)

    Hernández, A E Cárcamo; Varzielas, I de Medeiros

    2015-01-01

    We consider a modification of the Fukuyama–Nishiura texture and compare it to the precision quark flavour data, finding that it fits the data very well but at the cost of accidental cancelations between parameters. We then propose different viable textures for quarks, where only the Cabibbo mixing arises from the down sector, and extend to the charged leptons while constructing a complementary neutrino structure that leads to viable lepton masses and mixing. (paper)

  17. Laser surface modification of Ti implants to improve osseointegration

    International Nuclear Information System (INIS)

    Marticorena, M; Corti, G; Olmedo, D; Guglielmotti, M B; Duhalde, S

    2007-01-01

    Commercially Pure Titanium foils, were irradiated using a pulsed Nd:YAG laser under ambient air, in order to produce and characterize a well controlled surface texture (roughness and waviness) that enhances osseointegration. To study the 'peri-implant' reparative process response, the laser treated Ti foils were implanted in the tibia of 10 male Wistar rats. At 14 days post-implantation, the histological analysis showed a tendency to more bone formation compared to the untreated control implants. The formation of a layer of TiN on the surface and the obtained roughness, have been demonstrated to improve bone response

  18. Combining fine texture and coarse color features for color texture classification

    Science.gov (United States)

    Wang, Junmin; Fan, Yangyu; Li, Ning

    2017-11-01

    Color texture classification plays an important role in computer vision applications because texture and color are two fundamental visual features. To classify the color texture via extracting discriminative color texture features in real time, we present an approach of combining the fine texture and coarse color features for color texture classification. First, the input image is transformed from RGB to HSV color space to separate texture and color information. Second, the scale-selective completed local binary count (CLBC) algorithm is introduced to extract the fine texture feature from the V component in HSV color space. Third, both H and S components are quantized at an optimal coarse level. Furthermore, the joint histogram of H and S components is calculated, which is considered as the coarse color feature. Finally, the fine texture and coarse color features are combined as the final descriptor and the nearest subspace classifier is used for classification. Experimental results on CUReT, KTH-TIPS, and New-BarkTex databases demonstrate that the proposed method achieves state-of-the-art classification performance. Moreover, the proposed method is fast enough for real-time applications.

  19. Fast Image Texture Classification Using Decision Trees

    Science.gov (United States)

    Thompson, David R.

    2011-01-01

    Texture analysis would permit improved autonomous, onboard science data interpretation for adaptive navigation, sampling, and downlink decisions. These analyses would assist with terrain analysis and instrument placement in both macroscopic and microscopic image data products. Unfortunately, most state-of-the-art texture analysis demands computationally expensive convolutions of filters involving many floating-point operations. This makes them infeasible for radiation- hardened computers and spaceflight hardware. A new method approximates traditional texture classification of each image pixel with a fast decision-tree classifier. The classifier uses image features derived from simple filtering operations involving integer arithmetic. The texture analysis method is therefore amenable to implementation on FPGA (field-programmable gate array) hardware. Image features based on the "integral image" transform produce descriptive and efficient texture descriptors. Training the decision tree on a set of training data yields a classification scheme that produces reasonable approximations of optimal "texton" analysis at a fraction of the computational cost. A decision-tree learning algorithm employing the traditional k-means criterion of inter-cluster variance is used to learn tree structure from training data. The result is an efficient and accurate summary of surface morphology in images. This work is an evolutionary advance that unites several previous algorithms (k-means clustering, integral images, decision trees) and applies them to a new problem domain (morphology analysis for autonomous science during remote exploration). Advantages include order-of-magnitude improvements in runtime, feasibility for FPGA hardware, and significant improvements in texture classification accuracy.

  20. Texture and Elastic Anisotropy of Mantle Olivine

    Science.gov (United States)

    Nikitin, A. N.; Ivankina, T. I.; Bourilitchev, D. E.; Klima, K.; Locajicek, T.; Pros, Z.

    Eight olivine rock samples from different European regions were collected for neu- tron texture analyses and for P-wave velocity measurements by means of ultrasonic sounding at various confining pressures. The orientation distribution functions (ODFs) of olivine were determined and pole figures of the main crystallographic planes were calculated. The spatial P-wave velocity distributions were determined at confining pressures from 0.1 to 400 MPa and modelled from the olivine textures. In dependence upon the type of rock (xenolith or dunite) different behavior of both the P-wave veloc- ity distributions and the anisotropy coefficients with various confining pressures was observed. In order to explain the interdependence of elastic anisotropy and hydrostatic pressure, a model for polycrystalline olivine rocks was suggested, which considers the influence of the crystallographic and the mechanical textures on the elastic behaviour of the polycrystal. Since the olivine texture depends upon the active slip systems and the deformation temperature, neutron texture analyses enable us to estimate depth and thermodynamical conditions during texture formation.

  1. Investigation into the Effects of Textural Properties on Cuttability Performance of a Chisel Tool

    Science.gov (United States)

    Tumac, Deniz; Copur, Hanifi; Balci, Cemal; Er, Selman; Avunduk, Emre

    2018-04-01

    The main objective of this study is to investigate the effect of textural properties of stones on cutting performance of a standard chisel tool. Therewithal, the relationships between textural properties and cutting performance parameters and physical and mechanical properties were statistically analyzed. For this purpose, physical and mechanical property tests and mineralogical and petrographic analyses were carried out on eighteen natural stone samples, which can be grouped into three fundamentally different geological origins, i.e., metamorphic, igneous, and sedimentary. Then, texture coefficient analyses were performed on the samples. To determine the cuttability of the stones; the samples were cut with a portable linear cutting machine using a standard chisel tool at different depths of cut in unrelieved (non-interactive) cutting mode. The average and maximum forces (normal and cutting) and specific energy were measured, and the obtained values were correlated with texture coefficient, packing weighting, and grain size. With reference to the relation between depth of cut and cutting performance of the chisel tool for three types of natural stone groups, specific energy decreases with increasing depth of cut, and cutting forces increase in proportion to the depth of cut. The same is observed for the relationship between packing weighting and both of specific energy and cutter forces. On the other hand, specific energy and the forces decrease while grain size increases. Based on the findings of the present study, texture coefficient has strong correlation with specific energy. Generally, the lower depth of cut values in cutting tests shows higher and more reliable correlations with texture coefficient than the increased depth of cut. The results of cutting tests show also that, at a lower depth of cut (less than 1.5 mm), even stronger correlations can be observed between texture coefficient and cutting performance. Experimental studies indicate that cutting

  2. Texture development in Al-Mg alloys during high temperature annealing

    International Nuclear Information System (INIS)

    Saitou, T.; Inagaki, H.

    2001-01-01

    To clarify the effect of Mg content on annealing textures developed in Al-Mg alloys during high temperature annealing, Al-Mg alloys containing up to 9 wt.% Mg in supersaturated solid solution were cold rolled 95% and isothermally annealed at 450 C. Their textures were investigated with the orientation distribution function analysis. It was found that, in the recrystallization textures observed at complete recrystallization, addition of more than 1 wt.% Mg was sufficient to suppress the development of {100} left angle 001 right angle. With increasing Mg content, {100} left angle 001 right angle decreased remarkably, whereas {100} left angle 013 right angle and {103} left angle 321 right angle increased. Thus, {100} left angle 013 right angle and {103} left angle 321 right angle were found to be the main orientations of the recrystallization textures of Al-Mg alloys annealed at high temperatures. {100} left angle 013 right angle developed most remarkably at 4 wt.% Mg, while {103} left angle 321 right angle showed the maximum development at 7 wt.% Mg. During subsequent grain growth at 450 C, remarkable texture changes were observed only in the alloys containing Mg in the range between 2 and 4 wt.%. In these alloys, {100} left angle 013 right angle developed at the expense of {100} left angle 001 right angle at earlier stages of grain growth, whereas {103} left angle 321 right angle increased independently of these two orientations at later stages of grain growth. Reflecting these texture changes, grain growth occurred in these alloys discontinuously. Such a discontinuous grain growth with large texture changes is expected, if strong textures are already present before grain growth, and if recrystallized grains having similar orientations are distributed by forming large clusters before grain growth. (orig.)

  3. Photogrammetry of the three-dimensional shape and texture of a nanoscale particle using scanning electron microscopy and free software.

    Science.gov (United States)

    Gontard, Lionel C; Schierholz, Roland; Yu, Shicheng; Cintas, Jesús; Dunin-Borkowski, Rafal E

    2016-10-01

    We apply photogrammetry in a scanning electron microscope (SEM) to study the three-dimensional shape and surface texture of a nanoscale LiTi2(PO4)3 particle. We highlight the fact that the technique can be applied non-invasively in any SEM using free software (freeware) and does not require special sample preparation. Three-dimensional information is obtained in the form of a surface mesh, with the texture of the sample stored as a separate two-dimensional image (referred to as a UV Map). The mesh can be used to measure parameters such as surface area, volume, moment of inertia and center of mass, while the UV map can be used to study the surface texture using conventional image processing techniques. We also illustrate the use of 3D printing to visualize the reconstructed model. Copyright © 2016 Elsevier B.V. All rights reserved.

  4. My Experience with Ti-Ni-Based and Ti-Based Shape Memory Alloys

    Science.gov (United States)

    Miyazaki, Shuichi

    2017-12-01

    The present author has been studying shape memory alloys including Cu-Al-Ni, Ti-Ni-based, and Ni-free Ti-based alloys since 1979. This paper reviews the present author's research results for the latter two materials since 1981. The topics on the Ti-Ni-based alloys include the achievement of superelasticity in Ti-Ni alloys through understanding of the role of microstructures consisting of dislocations and precipitates, followed by the contribution to the development of application market of shape memory effect and superelasticity, characterization of the R-phase and monoclinic martensitic transformations, clarification of the basic characteristics of fatigue properties, development of sputter-deposited shape memory thin films and fabrication of prototypes of microactuators utilizing thin films, development of high temperature shape memory alloys, and so on. The topics of Ni-free Ti-based shape memory alloys include the characterization of the orthorhombic phase martensitic transformation and related shape memory effect and superelasticity, the effects of texture, omega phase and adding elements on the martensitic transformation and shape memory properties, clarification of the unique effects of oxygen addition to induce non-linear large elasticity, Invar effect and heating-induced martensitic transformation, and so on.

  5. Conical surface textures formed by ion bombarding 2% Be Cu alloy

    International Nuclear Information System (INIS)

    Panitz, J.K.G.

    1990-01-01

    A homogeneous, micrometer-sized conical surface texture forms on 2% Be-Cu alloy which is bombarded with an argon beam produced by a Kaufman ion source. The dimensions of the features that form strongly depend on: (1) argon energy (from 250 to 1500 eV), (2) fluence (10 19 to 10 20 ions/cm 2 ), and (3) flux (0.1 to 1 mA/cm 2 ). The texture morphology depends less strongly on the background ambient (Mo vs graphite), earlier alloy heat treatments and the temperature during bombardment (100 degree C and 450 degree C). As the texture matures with increasing fluence, the number of large features increases at the expense of the number of small features. The observed relationship between texture formation and ion flux suggests that the evolution of these features is not adequately described by theories predicting that the mature conical sidewall angle is related to the angle of the maximum sputtering yield. These textured surfaces can be coated with other metals for a variety of possible applications including: (1) pulsed power Li+ beam anodes, (2) cold cathode field emission devices, (3) optical absorbers and (4) catalysis supports. 18 refs., 5 figs

  6. Effect of surface shear on cube texture formation in heavy cold-rolled Cu-45 at%Ni alloy substrates

    DEFF Research Database (Denmark)

    Tian, Hui; Suo, Hongli; Liang, Yaru

    2015-01-01

    Two types of Cu-45 at%Ni alloy thin tapes with and without surface shear were obtained by different heavy cold rolling processes. The deformation and recrystallization textures of the two tapes were thoroughly investigated by electron back scattering diffraction technique. The results showed...... that a shear texture mainly covered the surface of the heavy deformed tapes because of the fraction between the surface of rolling mills and the thin tapes when the rolling force strongly reduced at high strain, which significantly reduced the fraction of rolling texture on the surface of the Cu-45at %Ni alloy...

  7. Chemically synthesized TiO2 and PANI/TiO2 thin films for ethanol sensing applications

    Science.gov (United States)

    Gawri, Isha; Ridhi, R.; Singh, K. P.; Tripathi, S. K.

    2018-02-01

    Ethanol sensing properties of chemically synthesized titanium dioxide (TiO2) and polyaniline/titanium dioxide nanocomposites (PANI/TiO2) had been performed at room temperature. In-situ oxidative polymerization process had been employed with aniline as a monomer in presence of anatase titanium dioxide nanoparticles. The prepared samples were structurally and morphologically characterized by x-ray diffraction, fourier transform infrared spectra, high resolution-transmission electron microscopy and field emission-scanning electron microscopy. The crystallinity of PANI/TiO2 nanocomposite was revealed by XRD and FTIR spectra confirmed the presence of chemical bonding between the polymer chains and metal oxide nanoparticles. HR-TEM micrographs depicted that TiO2 particles were embedded in polymer matrix, which provides an advantage over pure TiO2 nanoparticles in efficient adsorption of vapours. These images also revealed that the TiO2 nanoparticles were irregular in shape with size around 17 nm. FE-SEM studies revealed that in the porous structure of PANI/TiO2 film, the intercalation of TiO2 in PANI chains provides an advantage over pure TiO2 film for uniform interaction with ethanol vapors. The sensitivity values of prepared samples were examined towards ethanol vapours at room temperature. The PANI/TiO2 nanocomposite exhibited better sensing response and faster response-recovery examined at different ethanol concentrations ranging from 5 ppm to 20 ppm in comparison to pure TiO2 nanoparticles. The increase in vapour sensing of PANI/TiO2 sensing film as compared to pure TiO2 film had been explained in detail with the help of gas sensing mechanism of TiO2 and PANI/TiO2. This provides strong evidence that gas sensing properties of TiO2 had been considerably improved and enhanced with the addition of polymer matrix.

  8. Nanofrictional behavior of amorphous, polycrystalline and textured Y-Cr-O films

    Energy Technology Data Exchange (ETDEWEB)

    Gervacio-Arciniega, J.J. [Centro de Nanociencias y Nanotecnología (CNyN), Universidad Nacional Autónoma de México (UNAM), km. 107, Carretera Tijuana-Ensenada, 22860 Ensenada, B.C. (Mexico); Flores-Ruiz, F.J., E-mail: fcojfloresr@gmail.com [Centro de Nanociencias y Nanotecnología (CNyN), Universidad Nacional Autónoma de México (UNAM), km. 107, Carretera Tijuana-Ensenada, 22860 Ensenada, B.C. (Mexico); Diliegros-Godines, C.J. [Centro de Nanociencias y Nanotecnología (CNyN), Universidad Nacional Autónoma de México (UNAM), km. 107, Carretera Tijuana-Ensenada, 22860 Ensenada, B.C. (Mexico); Broitman, E. [Thin Film Physics Division, IFM, Linköping University, SE-58183 Linköping (Sweden); Enriquez-Flores, C.I.; Espinoza-Beltrán, F.J. [CINVESTAV Unidad Querétaro, Lib. Norponiente 2000, Real de Juriquilla, 76230 Querétaro, Qro. (Mexico); Siqueiros, J.; Cruz, M.P. [Centro de Nanociencias y Nanotecnología (CNyN), Universidad Nacional Autónoma de México (UNAM), km. 107, Carretera Tijuana-Ensenada, 22860 Ensenada, B.C. (Mexico)

    2016-08-15

    Highlights: • Friction coefficient (μ) of ferroelectric textured and polycrystalline YCrO{sub 3} films. • A simple method to evaluate μ from a single AFM image is presented. • The AFM-cantilever spring constant was determined from its dynamic response. • Polycrystalline and amorphous films have a lower μ than textured samples. - Abstract: Differences in friction coefficients (μ) of ferroelectric YCrO{sub 3}, textured and polycrystalline films, and non-ferroelectric Y-Cr-O films are analyzed. The friction coefficient was evaluated by atomic force microscopy using a simple quantitative procedure where the dependence of friction force with the applied load is obtained in only one topographical image. A simple code was developed with the MATLAB{sup ®} software to analyze the experimental data. The code includes a correction of the hysteresis in the forward and backward scanning directions. The quantification of load exerted on the sample surface was obtained by finite element analysis of the AFM cantilever starting from its experimental dynamic information. The results show that the ferroelectric YCrO{sub 3} film deposited on a Pt(150 nm)/TiO{sub 2}(30 nm)/SiO{sub 2}/Si (100) substrate is polycrystalline and has a lower friction coefficient than the deposited on SrTiO{sub 3} (110), which is highly textured. From a viewpoint of industrial application in ferroelectric memories, where the writing process is electrical or mechanically achieved by sliding AFM tips on the sample, polycrystalline YCrO{sub 3} films seem to be the best candidates due to their lower μ.

  9. Nanofrictional behavior of amorphous, polycrystalline and textured Y-Cr-O films

    International Nuclear Information System (INIS)

    Gervacio-Arciniega, J.J.; Flores-Ruiz, F.J.; Diliegros-Godines, C.J.; Broitman, E.; Enriquez-Flores, C.I.; Espinoza-Beltrán, F.J.; Siqueiros, J.; Cruz, M.P.

    2016-01-01

    Highlights: • Friction coefficient (μ) of ferroelectric textured and polycrystalline YCrO 3 films. • A simple method to evaluate μ from a single AFM image is presented. • The AFM-cantilever spring constant was determined from its dynamic response. • Polycrystalline and amorphous films have a lower μ than textured samples. - Abstract: Differences in friction coefficients (μ) of ferroelectric YCrO 3 , textured and polycrystalline films, and non-ferroelectric Y-Cr-O films are analyzed. The friction coefficient was evaluated by atomic force microscopy using a simple quantitative procedure where the dependence of friction force with the applied load is obtained in only one topographical image. A simple code was developed with the MATLAB ® software to analyze the experimental data. The code includes a correction of the hysteresis in the forward and backward scanning directions. The quantification of load exerted on the sample surface was obtained by finite element analysis of the AFM cantilever starting from its experimental dynamic information. The results show that the ferroelectric YCrO 3 film deposited on a Pt(150 nm)/TiO 2 (30 nm)/SiO 2 /Si (100) substrate is polycrystalline and has a lower friction coefficient than the deposited on SrTiO 3 (110), which is highly textured. From a viewpoint of industrial application in ferroelectric memories, where the writing process is electrical or mechanically achieved by sliding AFM tips on the sample, polycrystalline YCrO 3 films seem to be the best candidates due to their lower μ.

  10. Textural guidance cues for controlling process outgrowth of mammalian neurons.

    Science.gov (United States)

    Hanson, Jennifer N; Motala, Michael J; Heien, Michael L; Gillette, Martha; Sweedler, Jonathan; Nuzzo, Ralph G

    2009-01-07

    We explore textural cues as a mechanism for controlling neuronal process outgrowth in primary cultures of mammalian neurons. The work uses a form of decal transfer lithography to generate arrays of PDMS posts of various dimensions and spacings on glass substrates that are rendered growth-compliant by subsequent treatment with a protein activator. Hippocampal neurons plated on these substrates are used to determine how the posts direct process growth by acting as attachment points or guidance cues. Textural features varying over a large range, even as large as 100 microm in diameter, dramatically affect process growth. Indeed, two growth regimes are observed; at the smaller feature sizes considered, process branching strongly aligns (at right angles) along the post mesh, while neuronal outgrowth on the larger feature sizes elicits process wrapping. The latter behavior most strongly manifests in neurons plated initially at approximately 100 cells/mm(2), where the cells were able to form networks, while for isolated neurons, the cells exhibit poorer viability and development. Bag cell neurons from Aplysia californica also display regular growth patterns, but in this case are guided by contact avoidance of the posts, a behavior qualitatively different than that of the hippocampal neurons.

  11. Photogrammetry of the three-dimensional shape and texture of a nanoscale particle using scanning electron microscopy and free software

    International Nuclear Information System (INIS)

    Gontard, Lionel C.; Schierholz, Roland; Yu, Shicheng; Cintas, Jesús; Dunin-Borkowski, Rafal E.

    2016-01-01

    We apply photogrammetry in a scanning electron microscope (SEM) to study the three-dimensional shape and surface texture of a nanoscale LiTi 2 (PO 4 ) 3 particle. We highlight the fact that the technique can be applied non-invasively in any SEM using free software (freeware) and does not require special sample preparation. Three-dimensional information is obtained in the form of a surface mesh, with the texture of the sample stored as a separate two-dimensional image (referred to as a UV Map). The mesh can be used to measure parameters such as surface area, volume, moment of inertia and center of mass, while the UV map can be used to study the surface texture using conventional image processing techniques. We also illustrate the use of 3D printing to visualize the reconstructed model. - Highlights: • 3D shape and surface texture of a nanoscale LiTi 2 (PO 4 ) 3 particle. • The technique can be applied non-invasively in any SEM using freeware software. • The mesh can be used to measure parameters such as surface area, volume, moment of inertia and center of mass. • The UV map can be processed using 2D image processing software.

  12. Photogrammetry of the three-dimensional shape and texture of a nanoscale particle using scanning electron microscopy and free software

    Energy Technology Data Exchange (ETDEWEB)

    Gontard, Lionel C., E-mail: lionelcg@gmail.com [Departamento de Ciencia de los Materiales e Ingeniería Metalúrgica y Química Inorgánica, Universidad de Cádiz, Puerto Real 11510 (Spain); Faico PCT Cartuja. Edif. TI Marie Curie, C/ Leonardo da Vinci 18, 4a Planta, 41092 Sevilla (Spain); Schierholz, Roland; Yu, Shicheng [Institute of Energy and Climate Research, Fundamental Electrochemistry (IEK-9), Forschungszentrum Jülich, D-52425 Jülich (Germany); Cintas, Jesús [Servicio de Microscopía Centro de Investigación, Tecnología e Innovación (CITIUS), Universidad de Sevilla, Av. Reina Mercedes 4b, 41012 Sevilla (Spain); Dunin-Borkowski, Rafal E. [Ernst Ruska-Centre for Microscopy and Spectroscopy with Electrons and Peter Grünberg Institute, Forschungszentrum Jülich, D-52425 Jülich (Germany)

    2016-10-15

    We apply photogrammetry in a scanning electron microscope (SEM) to study the three-dimensional shape and surface texture of a nanoscale LiTi{sub 2}(PO{sub 4}){sub 3} particle. We highlight the fact that the technique can be applied non-invasively in any SEM using free software (freeware) and does not require special sample preparation. Three-dimensional information is obtained in the form of a surface mesh, with the texture of the sample stored as a separate two-dimensional image (referred to as a UV Map). The mesh can be used to measure parameters such as surface area, volume, moment of inertia and center of mass, while the UV map can be used to study the surface texture using conventional image processing techniques. We also illustrate the use of 3D printing to visualize the reconstructed model. - Highlights: • 3D shape and surface texture of a nanoscale LiTi{sub 2}(PO{sub 4}){sub 3} particle. • The technique can be applied non-invasively in any SEM using freeware software. • The mesh can be used to measure parameters such as surface area, volume, moment of inertia and center of mass. • The UV map can be processed using 2D image processing software.

  13. In Situ Neutron Diffraction Study of NiTi-21Pt High-Temperature Shape Memory Alloys

    Science.gov (United States)

    Benafan, O.; Gaydosh, D. J.; Noebe, R. D.; Qiu, S.; Vaidyanathan, R.

    2016-12-01

    In situ neutron diffraction was used to investigate the microstructural features of stoichiometric and Ti-rich NiTiPt high-temperature shape memory alloys with target compositions of Ni29Ti50Pt21 and Ni28.5Ti50.5Pt21 (in atomic percent), respectively. The alloys' isothermal and thermomechanical properties (i.e., moduli, thermal expansion, transformation strains, and dimensional stability) were correlated to the lattice strains, volume-averaged elastic moduli, and textures as determined by neutron diffraction. In addition, the unique aspects of this technique when applied to martensitic transformations in shape memory alloys are highlighted throughout the paper.

  14. Preparation of Ti-coated diamond particles by microwave heating

    International Nuclear Information System (INIS)

    Gu, Quanchao; Peng, Jinghui; Xu, Lei; Srinivasakannan, C.

    2016-01-01

    Highlights: • The Ti-Coated diamond particles have been prepared using by microwave heating. • The uniform and dense coating can be produced, and the TiC species was formed. • With increases the temperature results in the thickness of coating increased. • The coating/diamond interfacial bonding strength increased with temperature increasing until 760 °C, then decreased. - Abstract: Depositing strong carbide-forming elements on diamond surface can dramatically improve the interfacial bonding strength between diamond grits and metal matrix. In the present work, investigation on the preparation of Ti-coated diamond particles by microwave heating has been conducted. The morphology, microstructure, and the chemical composition of Ti-coated diamond particles were characterized by scanning electron microscopy (SEM), X-ray diffraction (XRD), and energy dispersive x-ray spectrometer (EDX). The thickness of Ti coating was measured and the interfacial binding strength between Ti coating and diamond was analyzed. The results show that the surface of the diamond particles could be successfully coated with Ti, forming a uniform and continuous Ti-coated layer. The TiC was found to form between the surface of diamond particles and Ti-coated layer. The amount of TiC as well as the thickness of coating increased with increasing coating temperature, furthermore, the grain size of the coating also grew gradually. The interfacial bonding strength between coating and diamond was found to be best at the temperature of 760 °C.

  15. Preparation of Ti-coated diamond particles by microwave heating

    Energy Technology Data Exchange (ETDEWEB)

    Gu, Quanchao [National Local Joint Laboratory of Engineering Application of Microwave Energy and Equipment Technology, Faculty of Metallurgical and Energy Engineering, Kunming University of Science and Technology, Kunming 650093 (China); Yunnan Copper Smelting and Processing Complex, Yunnan Copper (Group) CO., LTD., Kunming 650102 (China); International Joint Research Center of Advanced Preparation of Superhard Materials Field, Kunming Academician Workstation of Advanced Preparation of Superhard Materials Field, Kunming 650093 (China); Peng, Jinghui [National Local Joint Laboratory of Engineering Application of Microwave Energy and Equipment Technology, Faculty of Metallurgical and Energy Engineering, Kunming University of Science and Technology, Kunming 650093 (China); International Joint Research Center of Advanced Preparation of Superhard Materials Field, Kunming Academician Workstation of Advanced Preparation of Superhard Materials Field, Kunming 650093 (China); Xu, Lei, E-mail: xulei_kmust@aliyun.com [National Local Joint Laboratory of Engineering Application of Microwave Energy and Equipment Technology, Faculty of Metallurgical and Energy Engineering, Kunming University of Science and Technology, Kunming 650093 (China); Mechanical Engineering, University of Washington, Seattle, WA 98195 (United States); International Joint Research Center of Advanced Preparation of Superhard Materials Field, Kunming Academician Workstation of Advanced Preparation of Superhard Materials Field, Kunming 650093 (China); Srinivasakannan, C. [Chemical Engineering Department, The Petroleum Institute, P.O. Box 2533, Abu Dhabi (United Arab Emirates); and others

    2016-12-30

    Highlights: • The Ti-Coated diamond particles have been prepared using by microwave heating. • The uniform and dense coating can be produced, and the TiC species was formed. • With increases the temperature results in the thickness of coating increased. • The coating/diamond interfacial bonding strength increased with temperature increasing until 760 °C, then decreased. - Abstract: Depositing strong carbide-forming elements on diamond surface can dramatically improve the interfacial bonding strength between diamond grits and metal matrix. In the present work, investigation on the preparation of Ti-coated diamond particles by microwave heating has been conducted. The morphology, microstructure, and the chemical composition of Ti-coated diamond particles were characterized by scanning electron microscopy (SEM), X-ray diffraction (XRD), and energy dispersive x-ray spectrometer (EDX). The thickness of Ti coating was measured and the interfacial binding strength between Ti coating and diamond was analyzed. The results show that the surface of the diamond particles could be successfully coated with Ti, forming a uniform and continuous Ti-coated layer. The TiC was found to form between the surface of diamond particles and Ti-coated layer. The amount of TiC as well as the thickness of coating increased with increasing coating temperature, furthermore, the grain size of the coating also grew gradually. The interfacial bonding strength between coating and diamond was found to be best at the temperature of 760 °C.

  16. Full-PAW calculations of XANES/ELNES spectra of Ti-bearing oxide crystals and TiO-SiO glasses: Relation between pre-edge peaks and Ti coordination

    Science.gov (United States)

    Tamura, Tomoyuki; Tanaka, Shingo; Kohyama, Masanori

    2012-05-01

    We performed first-principles full-projector-augmented-wave calculations of the Ti and O K-edge x-ray absorption near-edge structure/energy-loss near-edge structure spectra for Ti-doped SiO2 glasses and Ti-bearing crystalline oxides with various Ti coordination. Obtained spectra showed satisfactory agreement with the experimental results. From combined interpretation of the electronic structures and the spectra, we clarified that the pre-edge peaks in Ti K edge used in determining Ti coordination can be accounted mainly from the symmetry of Ti-O polyhedra to dominate on-site mixing of Ti p and Ti d orbitals. We showed that an isolated fourfold coordinated Ti atom in a SiO2 glass produces a strong pre-edge peak in Ti K edge and a narrow peak below the threshold in O K edge of a SiO2 glass, as observed experimentally. This supports the idea that Ti exists in fourfold coordination in a SiO2 glass at low Ti contents. We observed that the main region of a Ti K-edge spectrum depends on the intermediate-range structure around the Ti atom in Ti-doped SiO2 glasses, while it is averaged in the observed spectra. Chemical shifts in the Ti and O K-edge threshold energies for Ti-bearing oxides and Ti-doped SiO2 glasses were also examined, and the O K-edge threshold energy showed clear correlation with the iconicity or covalency of each system.

  17. Texture and deformation mechanism of yttrium

    International Nuclear Information System (INIS)

    Adamesku, R.A.; Grebenkin, S.V.; Stepanenko, A.V.

    1992-01-01

    X-ray pole figure analysis was applied to study texture and deformation mechanism in pure and commercial polycrystalline yttrium on cold working. It was found that in cast yttrium the texture manifected itself weakly enough both for pure and commercial metal. Analysis of the data obtained made it possible to assert that cold deformation of pure yttrium in the initial stage occurred mainly by slip the role of which decreased at strains higher than 36%. The texture of heavily deformed commercial yttrium contained two components, these were an 'ideal' basic orientation and an axial one with the angle of inclination about 20 deg. Twinning mechanism was revealed to be also possible in commercial yttrium

  18. Road surface texture and skid resistance

    Science.gov (United States)

    Do, Minh-Tan; Cerezo, Veronique

    2015-12-01

    This paper deals with the relationship between road surface texture and skid resistance. Mechanisms underlying the tire/wet road friction are first described. Definitions of road surface irregularities scales are given. The rest of the paper is then focused on the macrotexture and microtexture scales and their respective roles in what happens at the tire/road interface. Existing methods to measure and characterize the road surface texture are presented. On the one hand, problems encountered when using sensors developed for machined surfaces for the measurement of road surface profiles or cartographies are discussed. On the other hand, potential improvements when applying characterization methods developed for machined surfaces to road surfaces are highlighted. The paper presents finally modeling approaches to calculate friction forces from road surface texture. The generalized form of the models is presented from which terms related respectively to the macrotexture and the microtexture are identified. Approaches used to calculate these terms, integrating eventually other variables, are presented.

  19. Anisotropy of thermal fatigue properties of cold-rolled TiNi sheet

    NARCIS (Netherlands)

    Mulder, J.H.; Mulder, J.H.; Thoma, P.E.; Beyer, J.

    1994-01-01

    The texture of cold-rolled and heat-treated TiNi sheet has been measured and designated as {110}(110)p. This material has been used in thermal fatigue tests during and after which the anisotropy and development of several thermomechanical properties, such as transformation temperatures and strains,

  20. Microstructural evolution and mechanical properties of Ti3SiC2-TiC composites

    International Nuclear Information System (INIS)

    Tian, WuBian; Sun, ZhengMing; Hashimoto, Hitoshi; Du, YuLei

    2010-01-01

    Ti 3 SiC 2 -TiC composites were fabricated by pulse discharge sintering technique using three different sets of powder mixtures, i.e. Ti/Si/TiC (TC30), Ti/Si/C/TiC (SI30) and Ti/Si/C (TSC30). Based on X-ray diffraction (XRD) analysis and microstructural observations, starting powder reactants were found to have little effect on phase content but strong influence on the microstructure in terms of phase distribution. The phase distribution mainly relies on the heat released from reaction and the liquid phase content formed during sintering. The mechanical properties of the fabricated dense samples demonstrate that more homogeneous phase distribution, available by choosing the starting reactants of SI30, results in higher flexural strength, whereas the Vickers hardness is almost independent of the microstructure. The enhanced flexural strength in sample SI30 sintered at 1400 o C is mainly attributed to the homogeneous TiC distribution in the microstructure.

  1. Fabrication of mesoporus TiO2 from TiOSO4 from leached ilmenite

    International Nuclear Information System (INIS)

    Wahyuningsih S; Ramelan AH; Rinawati L; Munifa RMI; Saputri LNMZ; Hanif QA; Pranata HP; Ismoyo YA

    2016-01-01

    The fabrication of mesoporous TiO 2 from TiOSO 4 precursor through roasted process, leaching, and homogeneous hydrolysis of ilmenite had been done. Analysis of X-ray Diffraction (XRD) showed the characteristics of ilmenite, hematite and rutile. After roasting the mineral ilmenite with the addition of Na 2 S at a temperature of 800°C the XRD characterization showed peaks characteristic for hematite, TiO 2 anatase, TiO 2 rutile, Na 2 SO 4 , NaFeS 2 , and NaFeO 2 . Leaching processes of roasted ilmenite which maintained with an addition of strong acid H 2 SO 4 6; 7.2; 9; 12, and 18 N were obtained TiOSO 4 filtrate. The results indicated that the more concentration of H 2 SO 4 the more solubility of ilmenite, where optimum solubility was achieved when H 2 SO 4 concentration was 12 N. The fabrication of mesoporous TiO 2 from TiOSO 4 was conducted with homogeneous hydrolysis method used urea and surfactant template F-127. XRD characterization results indicated the dominant peak of TiO 2 anatase. Crystallite size of 3.2 nm was obtained and the results of Scanning Electron Microscopy (SEM) showed that the presence of urea and surfactant be able to arrange porosity. (author)

  2. A new, energy-efficient chemical pathway for extracting Ti metal from Ti minerals.

    Science.gov (United States)

    Fang, Zhigang Zak; Middlemas, Scott; Guo, Jun; Fan, Peng

    2013-12-11

    Titanium is the ninth most abundant element, fourth among common metals, in the Earth's crust. Apart from some high-value applications in, e.g., the aerospace, biomedicine, and defense industries, the use of titanium in industrial or civilian applications has been extremely limited because of its high embodied energy and high cost. However, employing titanium would significantly reduce energy consumption of mechanical systems such as civilian transportation vehicles, which would have a profound impact on the sustainability of a global economy and the society of the future. The root cause of the high cost of titanium is its very strong affinity for oxygen. Conventional methods for Ti extraction involve several energy-intensive processes, including upgrading ilmenite ore to Ti-slag and then to synthetic rutile, high-temperature carbo-chlorination to produce TiCl4, and batch reduction of TiCl4 using Mg or Na (Kroll or Hunter process). This Communication describes a novel chemical pathway for extracting titanium metal from the upgraded titanium minerals (Ti-slag) with 60% less energy consumption than conventional methods. The new method involves direct reduction of Ti-slag using magnesium hydride, forming titanium hydride, which is subsequently purified by a series of chemical leaching steps. By directly reducing Ti-slag in the first step, Ti is chemically separated from impurities without using high-temperature processes.

  3. Electrodynamics of strongly disordered superconductors

    NARCIS (Netherlands)

    Coumou, P.C.J.J.

    2015-01-01

    Thin films of superconducting materials with a high resistance in the normal state, such as TiN, NbTiN, NbN and InO, are intensively studied from both an application and a fundamental point of view. A spatially inhomogeneous superconducting state can arise in these materials as a result of the

  4. A Noise Robust Statistical Texture Model

    DEFF Research Database (Denmark)

    Hilger, Klaus Baggesen; Stegmann, Mikkel Bille; Larsen, Rasmus

    2002-01-01

    This paper presents a novel approach to the problem of obtaining a low dimensional representation of texture (pixel intensity) variation present in a training set after alignment using a Generalised Procrustes analysis.We extend the conventional analysis of training textures in the Active...... Appearance Models segmentation framework. This is accomplished by augmenting the model with an estimate of the covariance of the noise present in the training data. This results in a more compact model maximising the signal-to-noise ratio, thus favouring subspaces rich on signal, but low on noise....... Differences in the methods are illustrated on a set of left cardiac ventricles obtained using magnetic resonance imaging....

  5. Martensitic textures: Multiscale consequences of elastic compatibility

    International Nuclear Information System (INIS)

    Shenoy, S.R.; Lookman, T.; Saxena, A.; Bishop, A.R.

    2001-03-01

    We show that a free energy entirely in the order-parameter strain variable(s), rather than the displacement field, provides a unified understanding of martensitic textures. We use compatibility equations, linking the strain tensor components in the bulk and at interfaces, that induce anisotropic order-parameter strain interactions. These two long-range bulk/interface potentials, together with local compositional fluctuations, drive the formation of global elastic textures. Relaxational simulations show the spontaneous formation (and evolution under stress/temperature quenches) of equal width parallel twins, branched twins, and tweed, including characteristic scaling of twin width with twin length. (author)

  6. Biaxially textured articles formed by powder metallurgy

    Science.gov (United States)

    Goyal, Amit; Williams, Robert K.; Kroeger, Donald M.

    2003-07-29

    A biaxially textured alloy article having a magnetism less than pure Ni includes a rolled and annealed compacted and sintered powder-metallurgy preform article, the preform article having been formed from a powder mixture selected from the group of mixtures consisting of: at least 60 at % Ni powder and at least one of Cr powder, W powder, V powder, Mo powder, Cu powder, Al powder, Ce powder, YSZ powder, Y powder, Mg powder, and RE powder; the article having a fine and homogeneous grain structure; and having a dominant cube oriented {100} orientation texture; and further having a Curie temperature less than that of pure Ni.

  7. Biaxially textured articles formed by power metallurgy

    Science.gov (United States)

    Goyal, Amit; Williams, Robert K.; Kroeger, Donald M.

    2003-08-26

    A biaxially textured alloy article having a magnetism less than pure Ni includes a rolled and annealed compacted and sintered powder-metallurgy preform article, the preform article having been formed from a powder mixture selected from the group of mixtures consisting of: at least 60 at % Ni powder and at least one of Cr powder, W powder, V powder, Mo powder, Cu powder, Al powder, Ce powder, YSZ powder, Y powder, Mg powder, and RE powder; the article having a fine and homogeneous grain structure; and having a dominant cube oriented {100} orientation texture; and further having a Curie temperature less than that of pure Ni.

  8. CNN based texture synthesize with Semantic segment

    OpenAIRE

    Liang, Xianye; Zhuo, Bocheng; Li, Peijie; He, Liangju

    2016-01-01

    Deep learning algorithm display powerful ability in Computer Vision area, in recent year, the CNN has been applied to solve problems in the subarea of Image-generating, which has been widely applied in areas such as photo editing, image design, computer animation, real-time rendering for large scale of scenes and for visual effects in movies. However in the texture synthesize procedure. The state-of-art CNN can not capture the spatial location of texture in image, lead to significant distorti...

  9. Strongly Correlated Topological Insulators

    Science.gov (United States)

    2016-02-03

    Strongly Correlated Topological Insulators In the past year, the grant was used for work in the field of topological phases, with emphasis on finding...surface of topological insulators. In the past 3 years, we have started a new direction, that of fractional topological insulators. These are materials...in which a topologically nontrivial quasi-flat band is fractionally filled and then subject to strong interactions. The views, opinions and/or

  10. Phenomenon of primary and secondary extinction in textured material

    International Nuclear Information System (INIS)

    Kryshtab, T.G.; Palacios G, J.; Mazin, M.O.

    2002-01-01

    A new X-ray diffraction method is proposed for a more exact calculation of pole figures to determine the crystallite orientation distribution function (CODF) in textured materials, by the introduction of a correction of the integrated intensity of the diffracted beam due to the phenomenon of extinction. Besides, for the case of a symmetrical Bragg reflection from an ''infinitely thick'' flat parallel plate textured sample a simple solution is developed for the problem of separation and determination of primary and secondary extinction parameters, which can be present simultaneously. The determination of these parameters gives additional information about crystallite structure and allows us to evaluate the average subgrains size and their disorientation, respectively. In this work according to the dynamic diffraction theory, it is shown that the extinction length, which is directly connected with the phenomenon of primary extinction, in the Bragg geometry for σ polarization (perpendicular) is independent on the wavelength used for a given reflection. On the other hand, the additional contribution from secondary extinction depends on X-ray wavelength due to the change of effective absorption coefficient. Considering this fact, the calculations of pole density and the parameters of primary and secondary extinction are performed using the same strong reflection for two different wavelengths and, for one of these wavelengths, a second order of reflection. For confirmation of the proposed method a partially cold rolled aluminium sample and an aluminium powder standard sample were measured. The corrected pole densities, the values of primary and secondary extinction and the average sizes of perfect coherent areas and average angle of disorientation of subgrains in the selected directions were obtained. The obtained results show that the precise X-ray diffraction characterization of textured materials requires the consideration, in general, of primary as well as secondary

  11. Strong Cosmic Censorship

    Science.gov (United States)

    Isenberg, James

    2017-01-01

    The Hawking-Penrose theorems tell us that solutions of Einstein's equations are generally singular, in the sense of the incompleteness of causal geodesics (the paths of physical observers). These singularities might be marked by the blowup of curvature and therefore crushing tidal forces, or by the breakdown of physical determinism. Penrose has conjectured (in his `Strong Cosmic Censorship Conjecture`) that it is generically unbounded curvature that causes singularities, rather than causal breakdown. The verification that ``AVTD behavior'' (marked by the domination of time derivatives over space derivatives) is generically present in a family of solutions has proven to be a useful tool for studying model versions of Strong Cosmic Censorship in that family. I discuss some of the history of Strong Cosmic Censorship, and then discuss what is known about AVTD behavior and Strong Cosmic Censorship in families of solutions defined by varying degrees of isometry, and discuss recent results which we believe will extend this knowledge and provide new support for Strong Cosmic Censorship. I also comment on some of the recent work on ``Weak Null Singularities'', and how this relates to Strong Cosmic Censorship.

  12. New apparatus for ceramic texturing working under uniaxial stress and in a magnetic field

    International Nuclear Information System (INIS)

    Noudem, J.G.; Beille, J.; Draperi, A.; Sulpice, A.; Tournier, R.

    1993-01-01

    We have developed a new versatile apparatus combining the effect of hot pressing and the effect of magnetic field to texture HTSC (high-temperature superconductor) ceramics. The experimental set-up allows application of uniaxial stress up to 1100 degrees C under a maximum pressure of 60 MPa, in a controlled atmosphere and a magnetic field of 8 T. We have optimized the cycle for stress application along with the thermal cycle to produce highly-textured ceramics. In this paper, we describe the stress and thermal cycles used to texture Bi-Pb-Sr-Ca-Cu-O (2223 phase) ceramics. We present the physical and chemical characterizations of the samples which show a strong degree of crystallite orientation. (author)

  13. Texture side information generation for distributed coding of video-plus-depth

    DEFF Research Database (Denmark)

    Salmistraro, Matteo; Raket, Lars Lau; Zamarin, Marco

    2013-01-01

    components) is strongly correlated, so the additional depth information may be used to generate more accurate SI for the texture stream, increasing the efficiency of the system. In this paper we propose various methods for accurate texture SI generation, comparing them with other state-of-the-art solutions......We consider distributed video coding in a monoview video-plus-depth scenario, aiming at coding textures jointly with their corresponding depth stream. Distributed Video Coding (DVC) is a video coding paradigm in which the complexity is shifted from the encoder to the decoder. The Side Information....... The proposed system achieves gains on the reference decoder up to 1.49 dB....

  14. PIIID-formed (Ti, O)/Ti, (Ti, N)/Ti and (Ti, O, N)/Ti coatings on NiTi shape memory alloy for medical applications

    International Nuclear Information System (INIS)

    Sun Tao; Wang Langping; Wang Min; Tong Howang; Lu, William W.

    2012-01-01

    (Ti, O)/Ti, (Ti, N)/Ti and (Ti, O, N)/Ti composite coatings were fabricated on NiTi shape memory alloy via plasma immersion ion implantation and deposition (PIIID). Surface morphology of samples was investigated using atomic force microscopy (AFM) and scanning electron microscopy (SEM). Cross-sectional morphology indicated that the PIIID-formed coatings were dense and uniform. X-ray diffraction (XRD) was used to characterize the phase composition of samples. X-ray photoelectron spectroscopy (XPS) results showed that the surface of coated NiTi SMA samples was Ni-free. Nanoindentation measurements and pin-on-disc tests were carried out to evaluate mechanical properties and wear resistance of coated NiTi SMA, respectively. For the in vitro biological assessment of the composite coatings in terms of cell morphology and cell viability, osteoblast-like SaOS-2 cells and breast cancer MCF-7 cells were cultured on NiTi SMA samples, respectively. SaOS-2 cells attached and spread better on coated NiTi SMA. Viability of MCF-7 cells showed that the PIIID-formed composite coatings were noncytotoxic and coated samples were more biocompatible than uncoated samples. - Highlights: ► PIIID-formed coatings were fabricated on NiTi SMA to improve its biocompatibility. ► Microstructure, mechanical properties and biocompatibility of coatings were investigated. ► All PIIID-formed composite coatings were noncytotoxic and cytocompatible.

  15. Impacts of terrain attributes and human activities on soil texture class variations in hilly areas, south-west China.

    Science.gov (United States)

    Li, Ai-Di; Guo, Peng-Tao; Wu, Wei; Liu, Hong-Bin

    2017-06-01

    Knowledge of soil texture variations is critical for agricultural and engineering applications because texture influences many other soil properties. This study used random forest method to evaluate the effects of human activities and topographic parameters on the spatial variability of soil texture in hilly areas where soil parent material was uniform. The study site covers 252 km 2 and is located in the Upper Yangtze River Basin of south-west China. A total of 3636 samples were collected from the cultivated soils at a depth of 20 cm of dryland (sloping field and terraced land) landscape. The soil texture class for each sample was estimated by experienced soil scientists in the field. Two soil texture classes (loam and clay) were observed in the watershed. Eleven terrain parameters were derived from a digital elevation model with a resolution of 30 m. Compared with loamy soils, clayey soils were mostly observed in the areas with lower elevation and gentle slopes. The outcome of random forest indicated that human activities and elevation had strong effects on soil texture class variations across the study site. Further results showed that the relative importance of terrain parameters to soil texture class variations varied with dryland landscape. Topographic wetness index and elevation were the most important variables for sloping field and terraced land landscapes, respectively.

  16. Texture evolution by shear on two planes during ECAP of a high-strength aluminum alloy

    Energy Technology Data Exchange (ETDEWEB)

    Wang Shuncai [Materials Research Group, School of Engineering Sciences, University of Southampton, Southampton SO17 1BJ (United Kingdom)], E-mail: wangs@soton.ac.uk; Starink, Marco J.; Gao Nong; Qiao Xiaoguang [Materials Research Group, School of Engineering Sciences, University of Southampton, Southampton SO17 1BJ (United Kingdom); Xu Cheng [Departments of Aerospace and Mechanical Engineering and Materials Science, University of Southern California, Los Angeles, CA 90089-1453 (United States); Langdon, Terence G. [Materials Research Group, School of Engineering Sciences, University of Southampton, Southampton SO17 1BJ (United Kingdom); Departments of Aerospace and Mechanical Engineering and Materials Science, University of Southern California, Los Angeles, CA 90089-1453 (United States)

    2008-09-15

    The evolution of texture was examined during equal-channel angular pressing (ECAP) of an Al-Zn-Mg-Cu alloy having a strong initial texture. An analysis of the local texture using electron backscatter diffraction demonstrates that shear occurs on two shear planes: the main shear plane (MSP) equivalent to the simple shear plane, and a secondary shear plane which is perpendicular to the MSP. Throughout most regions of the ECAP billet, the MSP is close to the intersection plane of the two channels but with a small (5 deg.) deviation. Only the {l_brace}1 1 1{r_brace}<1 1 0> and {l_brace}0 0 1{r_brace}<1 1 0> shear systems were activated and there was no experimental evidence for the existence of other shear systems. In a small region at the bottom edge of the billet that passed through the zone of intersection of the channels, the observed textures were fully consistent with the rolling textures of Copper and Goss.

  17. Quantitative Analysis of the Cervical Texture by Ultrasound and Correlation with Gestational Age.

    Science.gov (United States)

    Baños, Núria; Perez-Moreno, Alvaro; Migliorelli, Federico; Triginer, Laura; Cobo, Teresa; Bonet-Carne, Elisenda; Gratacos, Eduard; Palacio, Montse

    2017-01-01

    Quantitative texture analysis has been proposed to extract robust features from the ultrasound image to detect subtle changes in the textures of the images. The aim of this study was to evaluate the feasibility of quantitative cervical texture analysis to assess cervical tissue changes throughout pregnancy. This was a cross-sectional study including singleton pregnancies between 20.0 and 41.6 weeks of gestation from women who delivered at term. Cervical length was measured, and a selected region of interest in the cervix was delineated. A model to predict gestational age based on features extracted from cervical images was developed following three steps: data splitting, feature transformation, and regression model computation. Seven hundred images, 30 per gestational week, were included for analysis. There was a strong correlation between the gestational age at which the images were obtained and the estimated gestational age by quantitative analysis of the cervical texture (R = 0.88). This study provides evidence that quantitative analysis of cervical texture can extract features from cervical ultrasound images which correlate with gestational age. Further research is needed to evaluate its applicability as a biomarker of the risk of spontaneous preterm birth, as well as its role in cervical assessment in other clinical situations in which cervical evaluation might be relevant. © 2016 S. Karger AG, Basel.

  18. Influence of texture on iodine-induced stress corrosion cracking of Zircaloy-4 cladding tubes

    International Nuclear Information System (INIS)

    Schuster, I.; Lemaignan, C.

    1992-01-01

    The specific study was carried out to measure the influence of texture on the behaviour of Zircaloy-4 under iodine-induced stress corrosion cracking. The aim was to determine the relative effects of various metallurgical parameters involved in fuel rod fracture by pellet-clad interaction (PCI). Cladding tubes of different geometries were manufactured from a given Zircaloy-4 ingot. In this way tubes with different textures were obtained. Rings from these tubes were then subjected to slow tensile tests in an inert atmosphere and in an iodine vapour atmosphere. The sensitivity of the tubes to stress corrosion cracking is quantified by the loss of ductility of fracture between the tests in each atmosphere. Combined with the findings of other studies, the results showed that: (a) Texture has a strong effect on the stress corrosion cracking behaviour of Zircaloy-4, (b) the mechanical properties do not have any bearing on the material behaviour under stress corrosion cracking, and that the better behaviour of a recrystallized material - compared to the same material in a stress-relieved state - can be explained solely by the texture effect, (c) texture is a more important parameter than chemical composition of Zircaloy-4, on condition that this composition remains within the ASTM specification. The conflict between the various mechanisms involved in stress corrosion crack propagation may explain these observations. Preliminary extrapolation of these conclusions to the irradiated material shows that a more specific study is needed using appropriate parameters. (orig.)

  19. The brass-type texture and its deviation from the copper-type texture

    DEFF Research Database (Denmark)

    Leffers, Torben; Ray, R.K.

    2009-01-01

    development of significant texture components with {1 1 1} approximately parallel to the rolling plane. (4) The deformation pattern during the later stages of the development of the brass-type texture is normally dominated by shear banding. (5) Copper–manganese alloys with more than 5% manganese develop...... results from a preliminary attempt to introduce the composite pattern in a complex model. We also suggest that more advanced models (like n-site models) are applied to the shear banding stage. As to the fundamental physical process governing the fcc rolling texture transition we quote recent...

  20. Preparation of textured Ni-Mn-Ga alloys

    Energy Technology Data Exchange (ETDEWEB)

    Poetschke, Martin; Gaitzsch, Uwe; Huerrich, Claudia; Thoss, Franziska; Roth, Stefan; Rellinghaus, Bernd; Schultz, Ludwig [IFW Dresden, Helmholzstr. 20, 01069 Dresden (Germany)

    2009-07-01

    NiMnGa alloys have gained large research interest because of their possible application as magnetic shape memory materials. This effect is caused by the motion of twin boundaries in a magnetic field. Up to now most of the research was concentrated on single crystals. However, the preparation of single crystals is a time consuming and cost intensive process and compositional changes along the growth axis as well as segregations may occur. This is why for technical applications there is a great interest in polycrystals. To extend this effect to polycrystals, directional solidification was applied in order to prepare coarse grained, textured samples. Stationary casting in a pre-heated ceramic mold mounted on a copper plate was employed to generate a heat flow towards the bottom of the sample and thereby a directional solidification in the opposite direction. The martensitic transformation temperature which strongly depends on the composition was monitored by DSC, and it is shown that the chemical homogeneity along the sample axis is improved in likewise treated samples. The preferred solidification-induced growth direction was determined by EBSD. Investigations on the influence of MnS - precipitates in the samples, originating from the used rare Manganese, are discussed. The results are compared to samples, which were prepared by a Bridgeman method with draw rates in the range of several 100 mm/h to obtain a texture.

  1. Recrystallization texture in nickel heavily deformed by accumulative roll bonding

    Science.gov (United States)

    Mishin, O. V.; Zhang, Y. B.; Godfrey, A.

    2017-07-01

    The recrystallization behavior of Ni processed by accumulative roll bonding to a total accumulated von Mises strain of 4.8 has been examined, and analyzed with respect to heterogeneity in the deformation microstructure. The regions near the bonding interface are found to be more refined and contain particle deformation zones around fragments of the steel wire brush used to prepare the surface for bonding. Sample-scale gradients are also observed, manifested as differences between the subsurface, intermediate and central layers, where the distributions of texture components are different. These heterogeneities affect the progress of recrystallization. While the subsurface and near-interface regions typically contain lower frequencies of cube-oriented grains than anywhere else in the sample, a strong cube texture forms in the sample during recrystallization, attributed to both a high nucleation rate and fast growth rate of cube-oriented grains. The observations highlight the sensitivity of recrystallization to heterogeneity in the deformation microstructure and demonstrate the importance of characterizing this heterogeneity over several length scales.

  2. Textural remanence - A new model of lunar rock magnetism

    Science.gov (United States)

    Brecher, A.

    1976-01-01

    In reexamining the accumulated magnetic data on lunar rocks, several common patterns of magnetic behavior are recognized. Their joint occurrence strongly suggests a new model of lunar rock magnetism, which is based on partial preferred textural alignment of the spontaneous moments of magnetic grains without requiring the existence of ancient lunar magnetic fields. This magnetic fabric, mimetic to locally oriented petrofabric, gives rise to an apparent 'textural remanent magnetization'. In order to account for the observed intensity of 'stable remanence' in lunar rocks, only a minute fraction (0.001 to 0.00001) of the single-domain iron grains present need be preferentially aligned. Several mechanisms operating on the lunar surface, including shock and diurnal thermal cycling, appear adequate for producing the required type and degree of magnetic alignment in all lunar rock classes. The model is supported by a wide variety of direct and indirect evidence, and its predictions (e.g., regarding anisotropic susceptibility and remanence acquisition) can be experimentally tested.

  3. Wetting transitions on textured hydrophilic surfaces.

    Science.gov (United States)

    Ishino, C; Okumura, K

    2008-04-01

    We consider the quasi-static energy of a drop on a textured hydrophilic surface, with taking the contact angle hysteresis (CAH) into account. We demonstrate how energy varies as the contact state changes from the Cassie state (in which air is trapped at the drop bottom) to the Wenzel state (in which liquid fills the texture at the drop bottom) assuming that the latter state nucleates from the center of the drop bottom. When the textured substrate is hydrophilic enough to allow spontaneous penetration of liquid film of the texture thickness, the present theory asserts that the drop develops into an experimentally observed state in which a drop looks like an egg fried without flipped over (sunny-side up) with a well-defined radius of "the egg yolk." Otherwise, the final contact state of the drop becomes like a Wenzel state, but with the contact circle smaller than the original Wenzel state due to the CAH. We provide simple analytical estimations for the yolk radius of the "sunny-side-up" state and for the final radius of the contact circle of the pseudo-Wenzel state.

  4. AN ILLUMINATION INVARIANT TEXTURE BASED FACE RECOGNITION

    Directory of Open Access Journals (Sweden)

    K. Meena

    2013-11-01

    Full Text Available Automatic face recognition remains an interesting but challenging computer vision open problem. Poor illumination is considered as one of the major issue, since illumination changes cause large variation in the facial features. To resolve this, illumination normalization preprocessing techniques are employed in this paper to enhance the face recognition rate. The methods such as Histogram Equalization (HE, Gamma Intensity Correction (GIC, Normalization chain and Modified Homomorphic Filtering (MHF are used for preprocessing. Owing to great success, the texture features are commonly used for face recognition. But these features are severely affected by lighting changes. Hence texture based models Local Binary Pattern (LBP, Local Derivative Pattern (LDP, Local Texture Pattern (LTP and Local Tetra Patterns (LTrPs are experimented under different lighting conditions. In this paper, illumination invariant face recognition technique is developed based on the fusion of illumination preprocessing with local texture descriptors. The performance has been evaluated using YALE B and CMU-PIE databases containing more than 1500 images. The results demonstrate that MHF based normalization gives significant improvement in recognition rate for the face images with large illumination conditions.

  5. Geometric Total Variation for Texture Deformation

    DEFF Research Database (Denmark)

    Bespalov, Dmitriy; Dahl, Anders Lindbjerg; Shokoufandeh, Ali

    2010-01-01

    In this work we propose a novel variational method that we intend to use for estimating non-rigid texture deformation. The method is able to capture variation in grayscale images with respect to the geometry of its features. Our experimental evaluations demonstrate that accounting for geometry of...

  6. Physicochemical and textural properties of kombucha fermented ...

    African Journals Online (AJOL)

    The possibility of kombucha application cultivated on two different tea types in combination with probiotics for milk fermentation at different temperatures, as well as the physicochemical and textural properties of manufactured fermented milk products were investigated. Combination of probiotic starter culture and kombucha ...

  7. Friction tensor concept for textured surfaces

    Indian Academy of Sciences (India)

    This paper proposes the concept of a friction tensor analogous to the heat conduc- tion tensor in anisotropic media. This implies that there exists two principal friction coefficients μ1,2 analogous to the principal conductivities k1,2. For symmetrically textured surfaces the principal directions are orthogonal with atleast one ...

  8. Combinatorial design of textured mechanical metamaterials.

    Science.gov (United States)

    Coulais, Corentin; Teomy, Eial; de Reus, Koen; Shokef, Yair; van Hecke, Martin

    2016-07-28

    The structural complexity of metamaterials is limitless, but, in practice, most designs comprise periodic architectures that lead to materials with spatially homogeneous features. More advanced applications in soft robotics, prosthetics and wearable technology involve spatially textured mechanical functionality, which requires aperiodic architectures. However, a naive implementation of such structural complexity invariably leads to geometrical frustration (whereby local constraints cannot be satisfied everywhere), which prevents coherent operation and impedes functionality. Here we introduce a combinatorial strategy for the design of aperiodic, yet frustration-free, mechanical metamaterials that exhibit spatially textured functionalities. We implement this strategy using cubic building blocks-voxels-that deform anisotropically, a local stacking rule that allows cooperative shape changes by guaranteeing that deformed building blocks fit together as in a three-dimensional jigsaw puzzle, and three-dimensional printing. These aperiodic metamaterials exhibit long-range holographic order, whereby the two-dimensional pixelated surface texture dictates the three-dimensional interior voxel arrangement. They also act as programmable shape-shifters, morphing into spatially complex, but predictable and designable, shapes when uniaxially compressed. Finally, their mechanical response to compression by a textured surface reveals their ability to perform sensing and pattern analysis. Combinatorial design thus opens up a new avenue towards mechanical metamaterials with unusual order and machine-like functionalities.

  9. Multidimensional Texture Analysis for Unsupervised Pattern Classification

    OpenAIRE

    Hammouche, K.; Postaire, J.-G.

    2008-01-01

    After a series of adaptations of classical image processing tools to cluster analysis such as thresholding, edge detection, relaxation, Markov field models and mathematical morphology, this chapter shows how texture analysis concepts can be introduced in the field of pattern classification. A general-purpose clustering procedure has been presented,

  10. Rheological and textural properties of cosmetic emulsions

    Czech Academy of Sciences Publication Activity Database

    Morávková, Tereza; Štern, Petr

    2011-01-01

    Roč. 21, č. 3 (2011), č. článku 35200. ISSN 1430-6395 Institutional research plan: CEZ:AV0Z20600510 Keywords : cosmetic emulsions * rheology * texture * sensory analysis * psychorheology Subject RIV: BK - Fluid Dynamics Impact factor: 1.000, year: 2011

  11. On Texture and Geometry in Image Analysis

    DEFF Research Database (Denmark)

    Gustafsson, David Karl John

    2009-01-01

    -out of the captured scene will also change. At large viewing distances, the sky occupies a large region in the image and buildings, trees and lawns appear as uniformly colored regions. The following questions are addressed: How much of the visual appearance in terms of geometry and texture of an image can...

  12. THE CAUSAL TEXTURE OF TRADE UNION ENVIRONMENTS

    African Journals Online (AJOL)

    Admin

    This paper is an attempt to fill an important gap in the existing literature on trade unions by providing a more adequate theoretical formulation of trade union environments. The discussion suggests that unlike the environment of business and related organisations whose causal texture is understood in terms of uncertainty, ...

  13. Development of a texture averaged Reynolds equation

    NARCIS (Netherlands)

    Kraker, A. de; Ostayen, R.A.J. van; Rixen, D.J.

    2010-01-01

    The application of textured bearing surfaces results in a more complex lubricant flow pattern compared to smooth bearing surfaces. In order to capture the more complex flow pattern and possible inertia effects in the vicinity of the surface pockets, the NavierStokes equations should be used to model

  14. Mathematical modelling of dropwise condensation on textured ...

    Indian Academy of Sciences (India)

    The minimum drop radius is insensitive to surface texturing and does not provide controllability at larger length and timescales. A closer examination of droplet distribution over the substrate reveals that small drops are locations of high heat transfer rates, which diminishes with increasing drop radius. The largest drop ...

  15. On the origin of recrystallization textures

    Indian Academy of Sciences (India)

    In the ON model, it has been argued that a higher frequency of the special orientation (grains) than random occur, thus accounting for the texture. In the OG model, it has been argued that the specially oriented grains have a high mobility boundary and thus can migrate faster and grow to a larger size as compared to random ...

  16. Textural characterization of coals using fractal analysis

    Energy Technology Data Exchange (ETDEWEB)

    Mahamud, Manuel; Lopez, Oscar [Faculty of Chemistry, Department of Chemical and Environmental Engineering, University of Oviedo, Campus de El Cristo, 33071 Oviedo (Spain); Pis, Jose Juan; Pajares, Jesus Alberto [Instituto Nacional del Carbon (C.S.I.C.), Apartado 73, 33080 Oviedo (Spain)

    2003-05-15

    The aim of this study is to show how fractal analysis can be effectively used to characterize the texture of porous solids. The materials under study were series of coals oxidized in air at various temperatures for different time intervals. Data from mercury porosimetry determinations of samples was analyzed using fractal models. The methods employed were those proposed by Neimark, Friesen and Mikula and that developed by Zhang and Li. Some methods are able to supply a fractal profile or 'fractal fingerprint' of materials, i.e. ranges of pore sizes with different fractal dimensions are detected. These fractal profiles are very sensitive to the oxidation treatment. The average fractal dimension can also be used as a valid parameter to monitor the textural evolution of the coals as the treatment progresses, as this behaves in a similar way to other textural parameters. The use of fractal analysis in conjunction with the results of classical characterization methods leads to a better understanding of textural modifications in the processing of materials.

  17. Textural characterization of chars using fractal analysis

    Energy Technology Data Exchange (ETDEWEB)

    Mahamud, Manuel; Lopez, Oscar [Department of Chemical and Environmental Engineering, Faculty of Chemistry, University of Oviedo, Campus de El Cristo, 33071 Oviedo (Spain); Pis, Jose Juan; Pajares, Jesus Alberto [Instituto Nacional del Carbon C.S.I.C., Apartado 73, 33080 Oviedo (Spain)

    2004-11-25

    The aim of this study is to explore the potential of fractal analysis in helping to understand the textural changes of materials during the manufacture of active carbons. Textural characterization of the chars is carried out in order to obtain a better understanding of the phenomena underlying char formation. The materials selected for study were a series of chars obtained from coals oxidized in air at various temperatures for different periods of time. The data from mercury porosimetry were analyzed using fractal models. The average fractal dimensions for the chars were calculated by using the methods proposed by Friesen and Mikula and that of Zhang and Li. Fractal profiles of the chars obtained by the method of Neimark were compared with the corresponding fractal profiles of the precursor coals. Pore development during carbonization depends-among other factors that are kept constant in this study-on the textural properties of the precursor coal, the devolatilization process and the plastic properties of coals. The evolution of the fractal characteristics of the chars is also studied. At the same time pore volume development is analyzed. These analyses help to clarify the role that various phenomena occurring during carbonization have on the textural properties of the chars.

  18. Some Numerical Characteristics of Image Texture

    Directory of Open Access Journals (Sweden)

    O. Samarina

    2012-05-01

    Full Text Available Texture classification is one of the basic images processing tasks. In this paper we present some numerical characteristics to the images analysis and processing. It can be used at the solving of images classification problems, their recognition, problems of remote sounding, biomedical images analysis, geological researches.

  19. Prague texture segmentation data generator and benchmark

    Czech Academy of Sciences Publication Activity Database

    Mikeš, Stanislav; Haindl, Michal

    2006-01-01

    Roč. 2006, č. 64 (2006), s. 67-68 ISSN 0926-4981 R&D Projects: GA MŠk(CZ) 1M0572; GA AV ČR(CZ) 1ET400750407; GA AV ČR IAA2075302 Institutional research plan: CEZ:AV0Z10750506 Keywords : image segmentation * texture * benchmark * web Subject RIV: BD - Theory of Information

  20. Preparation of supported Au–Pd and Cu–Pd by the combined strong ...

    Indian Academy of Sciences (India)

    BOONTIDA PONGTHAWORNSAKUN

    2017-10-25

    Oct 25, 2017 ... Abstract. TiO2 supported Au–Pd and Cu–Pd catalysts were prepared by strong electrostatic adsorption (SEA) of Pd followed by electroless deposition (ED) of a second metal with incremental surface coverages of Au or. Cu. High dispersion of small Pd particles on the Pd/TiO2 prepared by SEA led to the ...

  1. Strong Arcwise Connectedness

    OpenAIRE

    Espinoza, Benjamin; Gartside, Paul; Kovan-Bakan, Merve; Mamatelashvili, Ana

    2012-01-01

    A space is `n-strong arc connected' (n-sac) if for any n points in the space there is an arc in the space visiting them in order. A space is omega-strong arc connected (omega-sac) if it is n-sac for all n. We study these properties in finite graphs, regular continua, and rational continua. There are no 4-sac graphs, but there are 3-sac graphs and graphs which are 2-sac but not 3-sac. For every n there is an n-sac regular continuum, but no regular continuum is omega-sac. There is an omega-sac ...

  2. Abortion: Strong's counterexamples fail

    DEFF Research Database (Denmark)

    Di Nucci, Ezio

    2009-01-01

    This paper shows that the counterexamples proposed by Strong in 2008 in the Journal of Medical Ethics to Marquis's argument against abortion fail. Strong's basic idea is that there are cases--for example, terminally ill patients--where killing an adult human being is prima facie seriously morally......'s scenarios have some valuable future or admitted that killing them is not seriously morally wrong. Finally, if "valuable future" is interpreted as referring to objective standards, one ends up with implausible and unpalatable moral claims....

  3. Effect of Ti content in the photo catalytic behavior of Fe/TiO2-SiO2 systems

    International Nuclear Information System (INIS)

    Leon C, A.; Portillo V, N.; Hernandez P, I.; May L, M.; Gonzalez R, L.; Luna P, R.; Suarez P, R.

    2013-01-01

    In this work we report the synthesis of Fe/TiO 2 -SiO 2 systems with different concentrations of TiO 2 in order to determine the influence of titanium content on the structural, textural, optical properties and their photo catalytic behavior. The materials were synthesized by the sol-gel method and their modification was carried out by incipient impregnation. All samples were characterized be means of X-ray diffraction, N 2 physisorption (Bet method), Dr-UV-Vis and Raman spectroscopy. The modifications of the structural and optical properties are discussed on the basis of long-range order reduction, suggesting the formation of highly dispersed TiO 2 species. On the other hand, it was observed that the energy of the optical band gap decreases by introducing Fe. On the basis of these phenomena, the photo catalytic activity was measured, employing the degradation of orange II azo dye as a model reaction. (Author)

  4. PIIID-formed (Ti, O)/Ti, (Ti, N)/Ti and (Ti, O, N)/Ti coatings on NiTi shape memory alloy for medical applications.

    Science.gov (United States)

    Sun, Tao; Wang, Lang-Ping; Wang, Min; Tong, Ho-Wang; Lu, William W

    2012-08-01

    (Ti, O)/Ti, (Ti, N)/Ti and (Ti, O, N)/Ti composite coatings were fabricated on NiTi shape memory alloy via plasma immersion ion implantation and deposition (PIIID). Surface morphology of samples was investigated using atomic force microscopy (AFM) and scanning electron microscopy (SEM). Cross-sectional morphology indicated that the PIIID-formed coatings were dense and uniform. X-ray diffraction (XRD) was used to characterize the phase composition of samples. X-ray photoelectron spectroscopy (XPS) results showed that the surface of coated NiTi SMA samples was Ni-free. Nanoindentation measurements and pin-on-disc tests were carried out to evaluate mechanical properties and wear resistance of coated NiTi SMA, respectively. For the in vitro biological assessment of the composite coatings in terms of cell morphology and cell viability, osteoblast-like SaOS-2 cells and breast cancer MCF-7 cells were cultured on NiTi SMA samples, respectively. SaOS-2 cells attached and spread better on coated NiTi SMA. Viability of MCF-7 cells showed that the PIIID-formed composite coatings were noncytotoxic and coated samples were more biocompatible than uncoated samples. Copyright © 2012 Elsevier B.V. All rights reserved.

  5. Spin Transport in Ferromagnetic and Antiferromagnetic Textures

    KAUST Repository

    Akosa, Collins A.

    2016-12-07

    In this dissertation, we provide an accurate description of spin transport in magnetic textures and in particular, we investigate in detail, the nature of spin torque and magnetic damping in such systems. Indeed, as will be further discussed in this thesis, the current-driven velocity of magnetic textures is related to the ratio between the so-called non-adiabatic torque and magnetic damping. Uncovering the physics underlying these phenomena can lead to the optimal design of magnetic systems with improved efficiency. We identified three interesting classes of systems which have attracted enormous research interest (i) Magnetic textures in systems with broken inversion symmetry: We investigate the nature of magnetic damping in non-centrosymmetric ferromagnets. Based on phenomenological and microscopic derivations, we show that the magnetic damping becomes chiral, i.e. depends on the chirality of the magnetic texture. (ii) Ferromagnetic domain walls, skyrmions and vortices: We address the physics of spin transport in sharp disordered magnetic domain walls and vortex cores. We demonstrate that upon spin-independent scattering, the non-adiabatic torque can be significantly enhanced. Such an enhancement is large for vortex cores compared to transverse domain walls. We also show that the topological spin currents owing in these structures dramatically enhances the non-adiabaticity, an effect unique to non-trivial topological textures (iii) Antiferromagnetic skyrmions: We extend this study to antiferromagnetic skyrmions and show that such an enhanced topological torque also exist in these systems. Even more interestingly, while such a non-adiabatic torque inuences the undesirable transverse velocity of ferromagnetic skyrmions, in antiferromagnetic skyrmions, the topological non-adiabatic torque directly determines the longitudinal velocity. As a consequence, scaling down the antiferromagnetic skyrmion results in a much more efficient spin torque.

  6. Texture of semi-solids : sensory flavor-texture interactions for custard desserts

    NARCIS (Netherlands)

    Wijk, de R.A.; Rasing, F.; Wilkinson, C.L.

    2003-01-01

    Possible interactions between flavor and oral texture sensations were investigated for four flavorants, diacetyl, benzaldehyde, vanillin, and caffeine, added in two concentrations to model vanilla custard desserts. The flavorants affected viscosities and resulted in corresponding changes in

  7. Effects of pavement surface texture on noise and frictional characteristics.

    Science.gov (United States)

    1987-02-01

    An experimental modification of the transverse groove : surface texture of a section of an urban interstate highway was : performed by the Iowa Department of Transportation. Transverse : groove texturing is a design feature required by the Federal : ...

  8. A strong comeback

    International Nuclear Information System (INIS)

    Marier, D.

    1992-01-01

    This article presents the results of a financial rankings survey which show a strong economic activity in the independent energy industry. The topics of the article include advisor turnover, overseas banks, and the increase in public offerings. The article identifies the top project finance investors for new projects and restructurings and rankings for lenders

  9. Contextual influences in texture-segmentation: distinct effects from elements along the edge and in the texture-region.

    Science.gov (United States)

    Robol, Valentina; Grassi, Massimo; Casco, Clara

    2013-08-09

    Both neurophysiological and psychophysical evidence suggest a strong influence of context on texture-segmentation. Here we extend and further analyse this issue, with a particular focus on the underlying mechanism. Specifically, we use a texture-edge discrimination task and separately investigate the effect of elements far from and along the edge. Consistent with previous studies, we report both an iso-near contextual effect - whereby performance is better if elements along the edge are iso-oriented compared to ortho-oriented to the edge - as well as an ortho-far effect - whereby discrimination is higher when elements far from the edge are orthogonal to the edge. We found that backward mask, which is known to interrupt re-entrant processing from extrastriate areas, only interferes with the iso-near effect whereas perturbing orientation, position or contrast polarity of elements far from the edge only abolishes the ortho-far effect. This suggests that feedback processes may be involved in the iso-near effect. Instead, the ortho-far effect may be accounted for by recurrent interactions among 1st order filters. Copyright © 2013 Elsevier Ltd. All rights reserved.

  10. Surface modification of coronary artery stent by Ti-O/Ti-N complex film coating prepared with plasma immersion ion implantation and deposition

    International Nuclear Information System (INIS)

    Huang, N.; Leng, Y.X.; Yang, P.

    2006-01-01

    This paper reported the work of surface coating of Ti-O/Ti-N complex films on coronary stents by means of the plasma immersion ion implantation/deposition process. The deformation behavior of the Ti-O/Ti-N coated stainless steel stents was investigated. In vivo investigation of the anticoagulation behavior of Ti-O coated coronary stents was also performed. The results of mechanical characterization of the Ti-O/Ti-N coated stents show that the film has strong binding strength, and to some extent the ability to withstand plastic deformation. The biological response behavior of the coated stent surface was significantly different from the uncoated. The results of implantation of stents into rabbit ventral aorta show no thrombus formation on the surfaces of the Ti-O coated stents, although serious coagulation had occurred on the surfaces of unmodified stents over a period of 4 weeks under conditions with no anticoagulant

  11. Intradomain Textures in Block Copolymers: Multizone Alignment and Biaxiality

    Science.gov (United States)

    Prasad, Ishan; Seo, Youngmi; Hall, Lisa M.; Grason, Gregory M.

    2017-06-01

    Block copolymer (BCP) melt assembly has been studied for decades, focusing largely on self-organized spatial patterns of periodically ordered segment density. Here, we demonstrate that underlying the well-known composition profiles (i.e., ordered lamella, cylinders, spheres, and networks) are generic and heterogeneous patterns of segment orientation that couple strongly to morphology, even in the absence of specific factors that promote intra or interchain segment alignment. We employ both self-consistent field theory and coarse-grained simulation methods to measure polar and nematic order parameters of segments in a freely jointed chain model of diblock melts. We show that BCP morphologies have a multizone texture, with segments predominantly aligned normal and parallel to interdomain interfaces in the respective brush and interfacial regions of the microdomain. Further, morphologies with anisotropically curved interfaces (i.e., cylinders and networks) exhibit biaxial order that is aligned to the principal curvature axes of the interface.

  12. Obtention of the TiFe compound by high-energy milling of Ti+Fe and TiH{sub 2}+Fe powder mixtures; Obtencao do composto TiFe a partir da moagem de alta energia de misturas Ti+Fe e TiH{sub 2}+Fe

    Energy Technology Data Exchange (ETDEWEB)

    Falcao, R.B.; Dammann, E.D.C.C.; Rocha, C.J.; Leal Neto, R.M., E-mail: railson.falcao@usp.b [Instituto de Pesquisas Energeticas e Nucleares (IPEN/CNEN-SP), Sao Paulo, SP (Brazil). Centro de Ciencias e Tecnologia de Materiais. Lab. de Intermetalicos

    2010-07-01

    In this work TiFe compound was obtained by two process routes involving high-energy ball milling: mechanical alloying from Ti and Fe powders (route 1) and mechanical milling from TiH{sub 2} and Fe powders, both followed by an annealing heat treatment. Shaker and planetary ball mills were utilized for times varying from 1-25 hours. Milled and annealed powders were characterized by SEM and X-ray diffraction analyses. TiFe compound was formed in both routes. A strong powder adherence in the milling vial and balls occurred with route 1 in both mills. Powder adherence was significantly reduced by using TiH{sub 2} (route 2) mainly in the planetary mill, in spite of TiFe formation has only occurred after the annealing treatment. (author)

  13. Texture Analysis Using Rényi’s Generalized Entropies

    NARCIS (Netherlands)

    Grigorescu, S.E.; Petkov, N.

    2003-01-01

    We propose a texture analysis method based on Rényi’s generalized entropies. The method aims at identifying texels in regular textures by searching for the smallest window through which the minimum number of different visual patterns is observed when moving the window over a given texture. The

  14. A dynamical system approach to texel identification in regular textures

    NARCIS (Netherlands)

    Grigorescu, S.E.; Petkov, N.; Loncaric, S; Neri, A; Babic, H

    2003-01-01

    We propose a texture analysis method based on Rényi’s entropies. The method aims at identifying texels in regular textures by searching for the smallest window through which the minimum number of different visual patterns is observed when moving the window over a given texture. The experimental

  15. TEXTURE ANALYSIS OF EXTRUDED APPLE POMACE - WHEAT SEMOLINA BLENDS

    Directory of Open Access Journals (Sweden)

    Ivan Bakalov

    2016-03-01

    Full Text Available Apple pomace - wheat semolina blends were extruded in a laboratory single screw extruder (Brabender 20 DN, Germany. Effects apple pomace content, moisture content, screw speed, and temperature of final cooking zone on texture of extrudates were studied applying response surface methodology. The texture characteristics of the extrudates were measured using a TA.XT Plus Texture Analyser, Stable Micro Systems.

  16. Brightness perception in low resolution images of 3d textures

    NARCIS (Netherlands)

    Spreeuwers, Lieuwe Jan; van der Heijden, Ferdinand; Siteur, J.

    1996-01-01

    A first step towards the analysis of the appearance of 3 dimensional textures is presented in this paper. It is assumed that the scale of the texture is small relative to the resolution of the camera. Therefore, the texture itself is not distinguishable.However, the perceived brightness of the

  17. Evaluation of texture differences among varieties of cooked quinoa

    Science.gov (United States)

    Texture is one of the most significant factors for consumers’ experience of foods. Texture difference of cooked quinoa among thirteen different varieties was studied. Correlations between the texture and seed composition, seed characteristics, cooking qualities, flour pasting properties and flour th...

  18. Line Laser and Triple Laser Quantification of the Difference in International Roughness Index between Textured and Non-Textured Strips

    Science.gov (United States)

    2017-07-01

    Practitioners have often wondered whether, during ride measurement with inertial devices, the motion of the laser through pavement texture introduces non representative values of international roughness index (IRI), particularly in certain textures. ...

  19. Strong Electroweak Symmetry Breaking

    CERN Document Server

    Grinstein, Benjamin

    2011-01-01

    Models of spontaneous breaking of electroweak symmetry by a strong interaction do not have fine tuning/hierarchy problem. They are conceptually elegant and use the only mechanism of spontaneous breaking of a gauge symmetry that is known to occur in nature. The simplest model, minimal technicolor with extended technicolor interactions, is appealing because one can calculate by scaling up from QCD. But it is ruled out on many counts: inappropriately low quark and lepton masses (or excessive FCNC), bad electroweak data fits, light scalar and vector states, etc. However, nature may not choose the minimal model and then we are stuck: except possibly through lattice simulations, we are unable to compute and test the models. In the LHC era it therefore makes sense to abandon specific models (of strong EW breaking) and concentrate on generic features that may indicate discovery. The Technicolor Straw Man is not a model but a parametrized search strategy inspired by a remarkable generic feature of walking technicolor,...

  20. Plasmons in strong superconductors

    International Nuclear Information System (INIS)

    Baldo, M.; Ducoin, C.

    2011-01-01

    We present a study of the possible plasmon excitations that can occur in systems where strong superconductivity is present. In these systems the plasmon energy is comparable to or smaller than the pairing gap. As a prototype of these systems we consider the proton component of Neutron Star matter just below the crust when electron screening is not taken into account. For the realistic case we consider in detail the different aspects of the elementary excitations when the proton, electron components are considered within the Random-Phase Approximation generalized to the superfluid case, while the influence of the neutron component is considered only at qualitative level. Electron screening plays a major role in modifying the proton spectrum and spectral function. At the same time the electron plasmon is strongly modified and damped by the indirect coupling with the superfluid proton component, even at moderately low values of the gap. The excitation spectrum shows the interplay of the different components and their relevance for each excitation modes. The results are relevant for neutrino physics and thermodynamical processes in neutron stars. If electron screening is neglected, the spectral properties of the proton component show some resemblance with the physical situation in high-T c superconductors, and we briefly discuss similarities and differences in this connection. In a general prospect, the results of the study emphasize the role of Coulomb interaction in strong superconductors.

  1. Microstructure and high-temperature strength of textured and non-textured ZrB2 ceramics

    Directory of Open Access Journals (Sweden)

    Wen-Wen Wu

    2014-01-01

    Full Text Available Zirconium diboride (ZrB2 ceramic possesses a unique combination of nice mechanical performance, high melting point (> 3000 °C and great high-temperature oxidation resistance (up to 1600 °C, which makes it a promising material system for ever-increasing ultra-high temperature (UHT applications. However, ZrB2 suffers from poor mechanical performance at UHTs, which could strongly limit its applications at UHT. Here, we successfully demonstrate that texturing is an effective strategy to greatly enhance the flexural strength of monolithic ZrB2, reaching a high value of 810 ± 60 MPa at 1600 °C when loaded in c-axis direction. We thoroughly discuss the strengthening mechanism by in-depth microstructural observations and analysis. Our discovery has technological and scientific implications for other UHT ceramic systems, especially those using ZrB2 as a matrix.

  2. Phosphorus leaching in a soil textural gradient

    DEFF Research Database (Denmark)

    Glæsner, Nadia; Kjærgaard, Charlotte; Rubæk, Gitte Holton

    2009-01-01

    Texture is a major factor influencing mobilization and transport of P in soil owing partly to differences in adsorptive properties, and partly to differences in pore-size distribution and pore organization. Slurry application strategies may be important mitigation measures for reducing agricultural...... in soils with matrix dominated flow behaviour We tested these hypotheses on three textural soil classes (Olsen-P 1.6 mg P 100 g-1) on intact soil columns (20*20 cm) and compared them to in situ P leaching before slurry application. In a loamy sand P leaching with both slurry application techniques slightly...... exceeded the in situ leaching. However, the two application techniques did not vary significantly. In a sandy and a clay loam preferential flow paths within the soil columns caused high P leaching when slurry was applied at the soil surface. The effect increased with increasing clay content. Injection...

  3. Soil texture reclassification by an ensemble model

    Science.gov (United States)

    Cisty, Milan; Hlavcova, Kamila

    2015-04-01

    Many environmental problems in which soil data serves as an inputs to simulation models are not restricted to national boundaries and therefore require international cooperation if solutions are to be found. The classification of soils according to their texture is one of the basic methods used for soil description. The term "soil texture" indicates the distribution of soil particles in the soil according to their size (diameter). The most preferred representation of texture classification is a grading curve. Because not all countries use the same classification system, databases from these countries cannot provide us with uniform data, which can serve as the inputs for various computations or models. This study deals with a description of a texture system reclassification to USDA classification system by the proposed model on a data set from Slovakia originally labeled by Slovakian national classification system. However, the authors of the paper suppose that the methodology proposed could be used more generally and that the information provided is also applicable when dealing with other existing soil texture classification systems. Some researchers have already proposed to fit the measured PSDs by various continuous parametric grading curves. When gaining such a relationship, it is possible to obtain a granular fraction's percentage ratio in the sample under consideration for any size of the particle diameter, which means that it is possible to get the values necessary for accomplishing a translation from one texture classification system to another. Several authors have conducted comparative studies on various PSD models in order to determine the best model for the soil groups selected for their studies (Nemes et al., 1999; Hwang, 2004; Botula et al., 2013). The reported findings of the abovementioned works somewhat differ from each other, and there is no generally suitable PSD model available. Because the transformation of a soil texture system is usually only

  4. SURFACE TEXTURE ANALYSIS FOR FUNCTIONALITY CONTROL

    DEFF Research Database (Denmark)

    De Chiffre, Leonardo; Andreasen, Jan Lasson; Tosello, Guido

    This document is used in connection with three exercises of 3 hours duration as a part of the course VISION ONLINE – One week course on Precision & Nanometrology. The exercises concern surface texture analysis for functionality control, in connection with three different case stories. This docume...... contains a short description of each case story, 3-D roughness parameters analysis and relation with the product’s functionality.......This document is used in connection with three exercises of 3 hours duration as a part of the course VISION ONLINE – One week course on Precision & Nanometrology. The exercises concern surface texture analysis for functionality control, in connection with three different case stories. This document...

  5. Probabilistic Discrete Mixtures Colour Texture Models

    Czech Academy of Sciences Publication Activity Database

    Haindl, Michal; Havlíček, Vojtěch; Grim, Jiří

    2008-01-01

    Roč. 2008, č. 5197 (2008), s. 675-682 ISSN 0302-9743. [Iberoamerican Congress on Pattern Recognition /13./. Havana, 09.092008-12.09.2008] R&D Projects: GA AV ČR 1ET400750407; GA MŠk 1M0572; GA ČR GA102/07/1594; GA ČR GA102/08/0593 Grant - others:GA MŠk(CZ) 2C06019 Institutional research plan: CEZ:AV0Z10750506 Keywords : Discrete distribution mixtures * EM algorithm * texture modeling Subject RIV: BD - Theory of Information http://library.utia.cas.cz/separaty/2008/RO/haindl-havlicek-grim-probabilistic%20discrete%20mixtures%20colour%20texture%20models.pdf

  6. Topological image texture analysis for quality assessment

    Science.gov (United States)

    Asaad, Aras T.; Rashid, Rasber Dh.; Jassim, Sabah A.

    2017-05-01

    Image quality is a major factor influencing pattern recognition accuracy and help detect image tampering for forensics. We are concerned with investigating topological image texture analysis techniques to assess different type of degradation. We use Local Binary Pattern (LBP) as a texture feature descriptor. For any image construct simplicial complexes for selected groups of uniform LBP bins and calculate persistent homology invariants (e.g. number of connected components). We investigated image quality discriminating characteristics of these simplicial complexes by computing these models for a large dataset of face images that are affected by the presence of shadows as a result of variation in illumination conditions. Our tests demonstrate that for specific uniform LBP patterns, the number of connected component not only distinguish between different levels of shadow effects but also help detect the infected regions as well.

  7. Dropwise condensation on inclined textured surfaces

    CERN Document Server

    Khandekar, Sameer

    2014-01-01

    Dropwise Condensation on Textured Surfaces presents a holistic framework for understanding dropwise condensation through mathematical modeling and meaningful experiments. The book presents a review of the subject required to build up models as well as to design experiments. Emphasis is placed on the effect of physical and chemical texturing and their effect on the bulk transport phenomena. Application of the model to metal vapor condensation is of special interest. The unique behavior of liquid metals, with their low Prandtl number and high surface tension, is also discussed. The model predicts instantaneous drop size distribution for a given level of substrate subcooling and derives local as well as spatio-temporally averaged heat transfer rates and wall shear stress.

  8. Texture-based analysis of COPD

    DEFF Research Database (Denmark)

    Sørensen, Lauge; Nielsen, Mads; Lo, Pechin Chien Pau

    2012-01-01

    This study presents a fully automatic, data-driven approach for texture-based quantitative analysis of chronic obstructive pulmonary disease (COPD) in pulmonary computed tomography (CT) images. The approach uses supervised learning where the class labels are, in contrast to previous work, based...... on measured lung function instead of on manually annotated regions of interest (ROIs). A quantitative measure of COPD is obtained by fusing COPD probabilities computed in ROIs within the lung fields where the individual ROI probabilities are computed using a k nearest neighbor (kNN ) classifier. The distance...... and subsequently applied to classify 200 independent images from the same screening trial. The texture-based measure was significantly better at discriminating between subjects with and without COPD than were the two most common quantitative measures of COPD in the literature, which are based on density...

  9. Composite biaxially textured substrates using ultrasonic consolidation

    Science.gov (United States)

    Blue, Craig A; Goyal, Amit

    2013-04-23

    A method of forming a composite sheet includes disposing an untextured metal or alloy first sheet in contact with a second sheet in an aligned opposing position; bonding the first sheet to the second sheet by applying an oscillating ultrasonic force to at least one of the first sheet and the second sheet to form an untextured intermediate composite sheet; and annealing the untextured intermediate composite sheet at a temperature lower than a primary re-crystallization temperature of the second sheet and higher than a primary re-crystallization temperature of the first sheet to convert the untextured first sheet into a cube textured sheet, wherein the cube texture is characterized by a .phi.-scan having a FWHM of no more than 15.degree. in all directions, the second sheet remaining untextured, to form a composite sheet.

  10. Efficient rolling texture predictions and texture-sensitive thermomechanical properties of α-uranium foils

    Science.gov (United States)

    Steiner, Matthew A.; Klein, Robert W.; Calhoun, Christopher A.; Knezevic, Marko; Garlea, Elena; Agnew, Sean R.

    2017-11-01

    Finite element (FE) analysis was used to simulate the strain history of an α-uranium foil during cold straight-rolling, with the sheet modeled as an isotropic elastoplastic continuum. The resulting strain history was then used as input for a viscoplastic self-consistent (VPSC) polycrystal plasticity model to simulate crystallographic texture evolution. Mid-plane textures predicted via the combined FE→VPSC approach show alignment of the (010) poles along the rolling direction (RD), and the (001) poles along the normal direction (ND) with a symmetric splitting along RD. The surface texture is similar to that of the mid-plane, but with a shear-induced asymmetry that favors one of the RD split features of the (001) pole figure. Both the mid-plane and surface textures predicted by the FE→VPSC approach agree with published experimental results for cold straight-rolled α-uranium plates, as well as predictions made by a more computationally intensive full-field crystal plasticity based finite element model. α-uranium foils produced by cold-rolling must typically undergo a recrystallization anneal to restore ductility prior to their final application, resulting in significant texture evolution from the cold-rolled plate deformation texture. Using the texture measured from a foil in the final recrystallized state, coefficients of thermal expansion and the elastic stiffness tensors were calculated using a thermo-elastic self-consistent model, and the anisotropic yield loci and flow curves along the RD, TD, and ND were predicted using the VPSC code.

  11. Texture analyses of Sauropod dinosaur bones from Tendaguru

    International Nuclear Information System (INIS)

    Pyzalla, A.R.; Sander, P.M.; Hansen, A.; Ferreyro, R.; Yi, S.-B.; Stempniewicz, M.; Brokmeier, H.-G.

    2006-01-01

    The apatite texture of fossil Brachiosaurus brancai and Barosaurus africanus sauropod bones from the excavation site at Tendaguru, Tanzania, was characterized by neutron diffraction pole figures. The results obtained reveal predominantly -fibre textures of the apatite; the fibre direction coincides with the longitudinal direction of the long bones of the skeletons. Neutron pole figures further indicate that other texture types may also be present. Texture strength is similar to dinosaur tendons and contemporary turkey tendon studied by others. Variations of texture strength across the bone wall cross-sections are not significantly large

  12. Exploring Sound-Motion Textures in drum set performance

    DEFF Research Database (Denmark)

    Godøy, Rolf Inge; song, minho; Dahl, Sofia

    2017-01-01

    A musical texture, be that of an ensemble or of a solo in- strumentalist, may be perceived as combinations of both simultaneous and sequential sound events. However, we believe that also sensations of the corresponding sound- producing events (e.g. hitting, stroking, bowing, blowing) contribute...... to our perceptions of musical textures. Musical textures could thus be understood as multimodal, with features of both sound and motion, hence the idea here of sound-motion textures in music. The study of such multi- modal sound-motion textures will necessitate collecting and analyzing data of both...

  13. Influence of texture on the physical properties of materials

    International Nuclear Information System (INIS)

    Penelle, R.; Baudin, T.

    1996-01-01

    The principles of crystallographic texture characterization by the means of X-ray or neutron diffraction statistical techniques are reviewed, and examples of their application to the study of the effects of texture on the properties of materials are presented: texture of magnetic steels, magneto-crystalline anisotropy, elasticity anisotropy and Young's modulus, plastic anisotropy (textural hardening), residual stresses. Neutron diffraction allows for the continuous monitoring of the recrystallization texture generation kinetics during in-situ annealing or for the follow-up of phase transformations. Backscattered electron diffraction allows for the quantification of the spatial distribution of grain and grain joint orientations and thus microstructure reconstruction

  14. Texture analyses of Sauropod dinosaur bones from Tendaguru

    Energy Technology Data Exchange (ETDEWEB)

    Pyzalla, A.R. [TU Wien, Institute of Material Science and Technology, Karlsplatz 13-308, A-1040 Vienna (Austria) and MPI fuer Eisenforschung GmbH, Max-Planck-Str. 1, D-40237 Duesseldorf (Germany)]. E-mail: pyzalla@mpie.de; Sander, P.M. [University of Bonn, Institute of Palaeontology, Nusseallee, D-53115 Bonn (Germany); Hansen, A. [TU Clausthal, Institute of Materials Science and Engineering. A, Structural Materials: Properties, Microstructure and Processingnd GKSS Research Centre Geesthacht GmbH, Geesthacht, Max-Planck-Str.1, D-21502 Geesthacht (Germany); Ferreyro, R. [TU Wien, Institute of Material Science and Technology, Karlsplatz 13-308, A-1040 Vienna (Austria); Yi, S.-B. [TU Clausthal, Institute of Materials Science and Engineering. A, Structural Materials: Properties, Microstructure and Processingnd GKSS Research Centre Geesthacht GmbH, Geesthacht, Max-Planck-Str.1, D-21502 Geesthacht (Germany); MPI fuer Eisenforschung GmbH, Max-Planck-Str. 1, D-40237 Duesseldorf (Germany); Stempniewicz, M. [TU Wien, Institute of Material Science and Technology, Karlsplatz 13-308, A-1040 Vienna (Austria); Brokmeier, H.-G. [TU Clausthal, Institute of Materials Science and Engineering. A, Structural Materials: Properties, Microstructure and Processingnd GKSS Research Centre Geesthacht GmbH, Geesthacht, Max-Planck-Str.1, D-21502 Geesthacht (Germany)

    2006-11-10

    The apatite texture of fossil Brachiosaurus brancai and Barosaurus africanus sauropod bones from the excavation site at Tendaguru, Tanzania, was characterized by neutron diffraction pole figures. The results obtained reveal predominantly <0 0 0 1>-fibre textures of the apatite; the fibre direction coincides with the longitudinal direction of the long bones of the skeletons. Neutron pole figures further indicate that other texture types may also be present. Texture strength is similar to dinosaur tendons and contemporary turkey tendon studied by others. Variations of texture strength across the bone wall cross-sections are not significantly large.

  15. Texture modelling by discrete distribution mixtures

    Czech Academy of Sciences Publication Activity Database

    Grim, Jiří; Haindl, Michal

    2003-01-01

    Roč. 41, 3-4 (2003), s. 603-615 ISSN 0167-9473 R&D Projects: GA ČR GA102/00/0030; GA AV ČR KSK1019101 Institutional research plan: CEZ:AV0Z1075907 Keywords : discrete distribution mixtures * EM algorithm * texture modelling Subject RIV: JC - Computer Hardware ; Software Impact factor: 0.711, year: 2003

  16. Colour texture segmentation using modelling approach

    Czech Academy of Sciences Publication Activity Database

    Haindl, Michal; Mikeš, Stanislav

    2005-01-01

    Roč. 3687, č. - (2005), s. 484-491 ISSN 0302-9743. [International Conference on Advances in Pattern Recognition /3./. Bath, 22.08.2005-25.08.2005] R&D Projects: GA MŠk 1M0572; GA AV ČR 1ET400750407; GA AV ČR IAA2075302 Institutional research plan: CEZ:AV0Z10750506 Keywords : colour texture segmentation * image models * segmentation benchmark Subject RIV: BD - Theory of Information

  17. Dynamic texture as foreground and background

    Czech Academy of Sciences Publication Activity Database

    Chetverikov, D.; Fazekas, S.; Haindl, Michal

    2011-01-01

    Roč. 22, č. 5 (2011), s. 741-750 ISSN 0932-8092 R&D Projects: GA ČR GA102/08/0593 EU Projects: European Commission(XE) 507752 - MUSCLE Institutional research plan: CEZ:AV0Z10750506 Keywords : Dynamic texture * Optical flow * SVD Subject RIV: BD - Theory of Information Impact factor: 1.009, year: 2011 http://library.utia.cas.cz/separaty/2011/RO/haindl-0345450.pdf

  18. Strong-coupling approximations

    International Nuclear Information System (INIS)

    Abbott, R.B.

    1984-03-01

    Standard path-integral techniques such as instanton calculations give good answers for weak-coupling problems, but become unreliable for strong-coupling. Here we consider a method of replacing the original potential by a suitably chosen harmonic oscillator potential. Physically this is motivated by the fact that potential barriers below the level of the ground-state energy of a quantum-mechanical system have little effect. Numerically, results are good, both for quantum-mechanical problems and for massive phi 4 field theory in 1 + 1 dimensions. 9 references, 6 figures

  19. Strong interaction and QFD

    International Nuclear Information System (INIS)

    Ebata, T.

    1981-01-01

    With an assumed weak multiplet structure for bosonic hadrons, which is consistent with the ΔI = 1/2 rule, it is shown that the strong interaction effective hamiltonian is compatible with the weak SU(2) x U(1) gauge transformation. Especially the rho-meson transforms as a triplet under SU(2)sub(w), and this is the origin of the rho-photon analogy. It is also shown that the existence of the non-vanishing Cabibbo angle is a necessary condition for the absence of the exotic hadrons. (orig.)

  20. Nominated Texture Based Cervical Cancer Classification

    Directory of Open Access Journals (Sweden)

    Edwin Jayasingh Mariarputham

    2015-01-01

    Full Text Available Accurate classification of Pap smear images becomes the challenging task in medical image processing. This can be improved in two ways. One way is by selecting suitable well defined specific features and the other is by selecting the best classifier. This paper presents a nominated texture based cervical cancer (NTCC classification system which classifies the Pap smear images into any one of the seven classes. This can be achieved by extracting well defined texture features and selecting best classifier. Seven sets of texture features (24 features are extracted which include relative size of nucleus and cytoplasm, dynamic range and first four moments of intensities of nucleus and cytoplasm, relative displacement of nucleus within the cytoplasm, gray level cooccurrence matrix, local binary pattern histogram, tamura features, and edge orientation histogram. Few types of support vector machine (SVM and neural network (NN classifiers are used for the classification. The performance of the NTCC algorithm is tested and compared to other algorithms on public image database of Herlev University Hospital, Denmark, with 917 Pap smear images. The output of SVM is found to be best for the most of the classes and better results for the remaining classes.

  1. Model for understanding consumer textural food choice.

    Science.gov (United States)

    Jeltema, Melissa; Beckley, Jacqueline; Vahalik, Jennifer

    2015-05-01

    The current paradigm for developing products that will match the marketing messaging is flawed because the drivers of product choice and satisfaction based on texture are misunderstood. Qualitative research across 10 years has led to the thesis explored in this research that individuals have a preferred way to manipulate food in their mouths (i.e., mouth behavior) and that this behavior is a major driver of food choice, satisfaction, and the desire to repurchase. Texture, which is currently thought to be a major driver of product choice, is a secondary factor, and is important only in that it supports the primary driver-mouth behavior. A model for mouth behavior is proposed and the qualitative research supporting the identification of different mouth behaviors is presented. The development of a trademarked typing tool for characterizing mouth behavior is described along with quantitative substantiation of the tool's ability to group individuals by mouth behavior. The use of these four groups to understand textural preferences and the implications for a variety of areas including product design and weight management are explored.

  2. Crystallographic texture and mechanical anisotropy of zircaloys

    International Nuclear Information System (INIS)

    Hussien, S.A.

    1987-01-01

    Hexagonal-closed-packed metals are inherently anisotropic, and deformation during processing leads to the development of preferred orientation or texture in the finished product. Tube Reduced Extrusions (TREXs) are an intermediate product in the production of zircaloy canning tubes for nuclear reactors. The objective of this research has been to study the mechanical anisotropy which has a direct relation to the formability of Zircaloy TREXs. Anisotropy parameters (R and P) in the modified Hills equation were investigated. The use of the impression test for measuring R and P under different annealing temperatures, test temperatures and strain rates, and the grid-analysis technique for measuring R and P gradients through the TREX thickness are demonstrated. The mechanical-test results are compared with the predictions of the Bishop-Hill model using the quantitative orientation distribution function. There is a good agreement between the model prediction and the mechanical-test data. The value of R was found to be insensitive to the strain rate, test temperature, annealing temperature, and texture gradient. The value of P was found to increase with the annealing temperature within the recrystallization range and to be relatively insensitive elsewhere, to decrease with increasing test temperature and to be considerable sensitive to texture gradient

  3. Modelling Thermal Diffusivity of Differently Textured Soils

    Science.gov (United States)

    Lukiashchenko, K. I.; Arkhangelskaya, T. A.

    2018-02-01

    A series of models has been proposed for estimating thermal diffusivity of soils at different water contents. Models have been trained on 49 soil samples with the texture range from sands to silty clays. The bulk density of the studied soils varied from 0.86 to 1.82 g/cm3; the organic carbon was between 0.05 and 6.49%; the physical clay ranged from 1 to 76%. The thermal diffusivity of undisturbed soil cores measured by the unsteady-state method varied from 0.78×10-7 m2/s for silty clay at the water content of 0.142 cm3/cm3 to 10.09 × 10-7 m2/s for sand at the water content of 0.138 cm3/cm3. Each experimental curve was described by the four-parameter function proposed earlier. Pedotransfer functions were then developed to estimate the parameters of the thermal diffusivity vs. water content function from data on soil texture, bulk density, and organic carbon. Models were tested on 32 samples not included in the training set. The root mean square errors of the best-performing models were 17-38%. The models using texture data performed better than the model using only data on soil bulk density and organic carbon.

  4. Focal Conic Flower Textures at Curved Interfaces

    Directory of Open Access Journals (Sweden)

    Daniel A. Beller

    2013-12-01

    Full Text Available Focal conic domains (FCDs in smectic-A liquid crystals have drawn much attention, both for their exquisitely structured internal form and for their ability to direct the assembly of micromaterials and nanomaterials in a variety of patterns. A key to directing FCD assembly is control over the eccentricity of the domain. Here, we demonstrate a new paradigm for creating spatially varying FCD eccentricity by confining a hybrid-aligned smectic with curved interfaces. In particular, we manipulate interface behavior with colloidal particles in order to experimentally produce two examples of what has recently been dubbed the flower texture [C. Meyer et al., Focal Conic Stacking in Smectic A Liquid Crystals: Smectic Flower and Apollonius Tiling, Materials 2, 499, 2009MATEG91996-194410.3390/ma2020499], where the focal hyperbolæ diverge radially outward from the center of the texture, rather than inward as in the canonical éventail or fan texture. We explain how this unconventional assembly can arise from appropriately curved interfaces. Finally, we present a model for this system that applies the law of corresponding cones, showing how FCDs may be embedded smoothly within a “background texture” of large FCDs and concentric spherical layers, in a manner consistent with the qualitative features of the smectic flower. Such understanding could potentially lead to disruptive liquid-crystal technologies beyond displays, including patterning, smart surfaces, microlens arrays, sensors, and nanomanufacturing.

  5. Preparation of well-distributed titania nanopillar arrays on Ti6Al4V surface by induction heating for enhancing osteogenic differentiation of stem cells

    Science.gov (United States)

    Li, Ning-Bo; Sun, Sheng-Jun; Bai, Han-Ying; Xiao, Gui-Yong; Xu, Wen-Hua; Zhao, Jun-Han; Chen, Xin; Lu, Yu-Peng; Zhang, Yi-Lin

    2018-01-01

    Great effort has recently been devoted to the preparation of nanoscale surfaces on titanium-based implants to achieve clinically fast osteoinduction and osseointegration, which relies on the unique characteristics of the nanostructure. In this work, we used induction heating treatment (IHT) as a rapid oxidation method to fabricate a porous nanoscale oxide layer on the Ti6Al4V surface for better medical application. Well-distributed vertical nanopillars were yielded by IHT for 20-35 s on the alloy surface. The composition of the oxides contained rutile/anatase TiO2 and a small amount of Al2O3 between the TiO2 grain boundaries (GBs). This technology resulted in a reduction and subsequent increase of surface roughness of 26-32 nm when upregulating the heating time, followed by the successive enhancement of the thickness, wettability and adhesion strength of the oxidation layer to the matrix. The surface hardness also distinctly rose to 554 HV in the IHT-35 s group compared with the 350 HV of bare Ti6Al4V. The massive small-angle GBs in the bare alloy promoted the formation of nanosized oxide crystallites. The grain refinement and deformation texture reduction further improved the mechanical properties of the matrix after IHT. Moreover, in vitro experiments on a mesenchymal stem cell (BMSC) culture derived from human bone marrow for 1-7 days indicated that the nanoscale layers did not cause cytotoxicity, and facilitated cell differentiation in osteoblasts by enhancing the gene and osteogenesis-related protein expressions after 1-3 weeks of culturing. The increase of the IHT time slightly advanced the BMSC proliferation and differentiation, especially during long-term culture. Our findings provide strong evidence that IHT oxidation technology is a novel nanosurface modification technology, which is potentially promising for further clinical development.

  6. Analysis of partially textured slider and journal bearing

    Science.gov (United States)

    Rao, T. V. V. L. N.; Rani, A. M. A.; Nagarajan, T.; Hashim, F. M.

    2012-06-01

    The partial texturing of bearing surfaces with different shapes of textures and at different locations is an effective approach to improve the performance of bearings. The present study examines the effects of texture configuration on improvement in load capacity and reduction in friction coefficient for slider and journal bearing. This work presents nondimensional pressure expressions for the partially textured slider and journal bearing. The nondimensional pressure expressions are derived taking into consideration of texture geometry and extent of partial texture on the bearing surface. The Reynolds boundary conditions are used in the analysis to predict nondimensional load capacity and coefficient of friction. Even for nominally parallel surfaces, partial texturing of bearing surfaces has a potential to generate load carrying capacity and reduce coefficient of friction.

  7. Scale-Space Mutual Information for Textural-Patterns Characterization

    Energy Technology Data Exchange (ETDEWEB)

    Seedahmed, Gamal H.; Ward, Andy L.

    2005-08-22

    The essence of image texture is typically understood by two aspects. First, within a texture-pattern there is a significant variation in intensity values between nearby pixels. Second, texture is a homogeneous property at some spatial scale larger than the spatial resolution of the image. Motivated by the essential aspects of image texture, this paper proposes a novel methodology that combines the use of scale-space and mutual information to characterize textural-patterns. Scale-space offers the mechanism for a multi-scale representation of the image, which will be used to address the scale aspect of texture. On the other hand, mutual information provides a measure to quantify the dependency relationship across the scale-space. It has been found that the proposed methodology has the potential to capture different properties of texture such as periodicity, scale, fineness, coarseness, and spatial extent or size. Practical examples are provided to demonstrate the applicability of the proposed methodology.

  8. A Novel Texture Classification Procedure by using Association Rules

    Directory of Open Access Journals (Sweden)

    L. Jaba Sheela

    2008-11-01

    Full Text Available Texture can be defined as a local statistical pattern of texture primitives in observer’s domain of interest. Texture classification aims to assign texture labels to unknown textures, according to training samples and classification rules. Association rules have been used in various applications during the past decades. Association rules capture both structural and statistical information, and automatically identify the structures that occur most frequently and relationships that have significant discriminative power. So, association rules can be adapted to capture frequently occurring local structures in textures. This paper describes the usage of association rules for texture classification problem. The performed experimental studies show the effectiveness of the association rules. The overall success rate is about 98%.

  9. Automatic Texture Optimization for 3D Urban Reconstruction

    Directory of Open Access Journals (Sweden)

    LI Ming

    2017-03-01

    Full Text Available In order to solve the problem of texture optimization in 3D city reconstruction by using multi-lens oblique images, the paper presents a method of seamless texture model reconstruction. At first, it corrects the radiation information of images by camera response functions and image dark channel. Then, according to the corresponding relevance between terrain triangular mesh surface model to image, implements occlusion detection by sparse triangulation method, and establishes the triangles' texture list of visible. Finally, combines with triangles' topology relationship in 3D triangular mesh surface model and means and variances of image, constructs a graph-cuts-based texture optimization algorithm under the framework of MRF(Markov random filed, to solve the discrete label problem of texture optimization selection and clustering, ensures the consistency of the adjacent triangles in texture mapping, achieves the seamless texture reconstruction of city. The experimental results verify the validity and superiority of our proposed method.

  10. Strong Coupling Holography

    CERN Document Server

    Dvali, Gia

    2009-01-01

    We show that whenever a 4-dimensional theory with N particle species emerges as a consistent low energy description of a 3-brane embedded in an asymptotically-flat (4+d)-dimensional space, the holographic scale of high-dimensional gravity sets the strong coupling scale of the 4D theory. This connection persists in the limit in which gravity can be consistently decoupled. We demonstrate this effect for orbifold planes, as well as for the solitonic branes and string theoretic D-branes. In all cases the emergence of a 4D strong coupling scale from bulk holography is a persistent phenomenon. The effect turns out to be insensitive even to such extreme deformations of the brane action that seemingly shield 4D theory from the bulk gravity effects. A well understood example of such deformation is given by large 4D Einstein term in the 3-brane action, which is known to suppress the strength of 5D gravity at short distances and change the 5D Newton's law into the four-dimensional one. Nevertheless, we observe that the ...

  11. Preparation of Ti-coated diamond particles by microwave heating

    Science.gov (United States)

    Gu, Quanchao; Peng, Jinghui; Xu, Lei; Srinivasakannan, C.; Zhang, Libo; Xia, Yi; Wu, Qingtian; Xia, Hongying

    2016-12-01

    Depositing strong carbide-forming elements on diamond surface can dramatically improve the interfacial bonding strength between diamond grits and metal matrix. In the present work, investigation on the preparation of Ti-coated diamond particles by microwave heating has been conducted. The morphology, microstructure, and the chemical composition of Ti-coated diamond particles were characterized by scanning electron microscopy (SEM), X-ray diffraction (XRD), and energy dispersive x-ray spectrometer (EDX). The thickness of Ti coating was measured and the interfacial binding strength between Ti coating and diamond was analyzed. The results show that the surface of the diamond particles could be successfully coated with Ti, forming a uniform and continuous Ti-coated layer. The TiC was found to form between the surface of diamond particles and Ti-coated layer. The amount of TiC as well as the thickness of coating increased with increasing coating temperature, furthermore, the grain size of the coating also grew gradually. The interfacial bonding strength between coating and diamond was found to be best at the temperature of 760 °C.

  12. Epoxidation of limonene over Ti MCM 41 and Ti BETA

    International Nuclear Information System (INIS)

    Cubillos Lobo, Jairo Antonio; Gonzalez Rodriguez, Lina Maria; Montes de Correa, Consuelo

    2002-01-01

    Ti MCM 41 were synthesized and evaluated in the epoxidation of limonene, using peroxide of hydrogen (H 2 O) as agent oxidizer. The characteristic hexagonal phase of Ti MCM 41 was obtained by heating the precursor gel during three days at 100 centigrade degrees. Further heating up to ten days leads to a decrease of this phase. The increase (Ti) in the synthesis gel also decreases that phase. The increase of Ti in the synthesis gel also decreases that phase UV VIS and FTIR spectroscopy indicates that Ti was incorporated in the lattice of Ti MCM 41 as well as, in Ti BETA. SEM micrographs of Ti MCM 41 show that the morphology changes with the Ti loading. Ti MCM 41 was most active than Ti BETA for limonene epoxidation even though both show high selectivity to epoxides

  13. Bulk texture measurement of interstitial-free annealed steel using Gaussian integrated intensities of neutron diffraction spectra

    International Nuclear Information System (INIS)

    Xu, P.G.; Tomota, Y.; Suzuki, Hiroshi; Machiya, Shutaro; Suzuki, T.; Yin, F.X.

    2008-01-01

    {110}, {200} and {211} neutron diffraction profiles of an interstitial-free annealed steel sheet were measured on 5x5 degrees stereographic angle grids, and several evaluation methods of diffraction intensity were employed to calculate the bulk texture, including the peak intensity at a constant 2 theta angle, the simply summed intensity in a constant 2 theta angle spread and the Gaussian integrated intensity obtained by single peak fitting of each profile. The comparison among differently evaluated bulk textures shows that a stronger {111} fiber component and a weaker {001} rotated cube component appear in the texture of investigated steel and the Gaussian integrated intensity method with proper coefficient constraints possesses a higher sensitivity to both weak texture components and strong ones. The crystallographic orientation maps obtained from electron backscattering diffraction and the bulk textures estimated from X-ray diffraction confirm the feasibility of the neutron bulk texture based on the Gaussian integrated intensity, suggesting that it can be suitably utilized to evaluate the global orientation distribution characteristics of heterogeneous materials. (author)

  14. Feasibility and reproducibility of fetal lung texture analysis by Automatic Quantitative Ultrasound Analysis and correlation with gestational age.

    Science.gov (United States)

    Cobo, Teresa; Bonet-Carne, Elisenda; Martínez-Terrón, Mónica; Perez-Moreno, Alvaro; Elías, Núria; Luque, Jordi; Amat-Roldan, Ivan; Palacio, Montse

    2012-01-01

    To evaluate the feasibility and reproducibility of fetal lung texture analysis using a novel automatic quantitative ultrasound analysis and to assess its correlation with gestational age. Prospective cross-sectional observational study. To evaluate texture features, 957 left and right lung images in a 2D four-cardiac-chamber view plane were previously delineated from fetuses between 20 and 41 weeks of gestation. Quantification of lung texture was performed by the Automatic Quantitative Ultrasound Analysis (AQUA) software to extract image features. A standard learning approach composed of feature transformation and a regression model was used to evaluate the association between texture features and gestational age. The association between weeks of gestation and fetal lung texture quantified by the AQUA software presented a Pearson correlation of 0.97. The association was not influenced by delineation parameters such as region of interest (ROI) localization, ROI size, right/left lung selected or sonographic parameters such as ultrasound equipment or transducer used. Fetal lung texture analysis measured by the AQUA software demonstrated a strong correlation with gestational age. This supports further research to explore the use of this technology to the noninvasive prediction of fetal lung maturity. Copyright © 2012 S. Karger AG, Basel.

  15. Nanoscale texture analysis of d-HDDR processed Nd-Fe-B powder particles

    OpenAIRE

    Duerrschnabel, Michael; Bruder, Enrico; Güth, Konrad; Gauss, Roland K.; Gutfleisch, Oliver; Molina-Luna, Leopoldo

    2016-01-01

    A strong texture in polycrystalline Nd-Fe-B powder particles processed by dynamic hydrogenation disproportionation desorption and recombination (d-HDDR) method is of importance for enhanced macroscopic magnetic properties [1]. This heavily depends on the processing parameters such as the hydrogen partial pressure [2]. The initial and the final step of the HDDR process has already been extensively studied by electron backscatter diffraction (EBSD) technique in the scanning electron microscope ...

  16. Production and characterization of multilayer coatings of Ti/TiN on AISI 316L stainless steel by the PVD technique of cathodic arc ion plating

    International Nuclear Information System (INIS)

    Forlerer, Elena; Rodriguez, Fernando; Mingolo, Norma

    2006-01-01

    Multilayer coatings were produced from bi-layers (compound layers) of Ti/TiN in a PVD reactor of cathodic arc ion plating. The process was carried out at an Argon gas pressure of 5x10 -3 Torr for the interlayer of Ti and a nitrogen + argon pressure of 2x10 -2 Torr for the deposit of TiN and a Bias voltage of -500V for the Ti layer and -100V for the TiN layer. The arc current held constant at 80 amp. The samples were kept at high temperatures ≥ 300 o C, mounted on a rotating system that held the test piece 15-25 cm from the Ti electrode. Certified composition AISI 316L and AISI 410 stainless steel were used for the substrate. Coatings with one or two compound layers with similar thicknesses were made. The coatings were characterized mechanically by adherence, thickness and microhardness by Vickers indentation with 25g loads. The texture was studied by X-ray diffraction and present phases and residual tensions were determined. The results of the X-ray diffraction show the presence of the mostly TiN phase, with fcc structure in the mono-layer and the bi-layer. Residual tensions are compressive and elevated due to the expansion of the TiN network during the deposition process. Measurements of the bi-layers at different angles showed a relaxing of the tensions close to the surface, which could be due to the effect of the second interlayer of Ti. Preferential orientations associated with the growth process of the layers and the developed microstructure were detected in the TiN (CW)

  17. LIGO: The strong belief

    CERN Multimedia

    Antonella Del Rosso

    2016-01-01

    Twenty years of designing, building and testing a number of innovative technologies, with the strong belief that the endeavour would lead to a historic breakthrough. The Bulletin publishes an abstract of the Courier’s interview with Barry Barish, one of the founding fathers of LIGO.   The plots show the signals of gravitational waves detected by the twin LIGO observatories at Livingston, Louisiana, and Hanford, Washington. (Image: Caltech/MIT/LIGO Lab) On 11 February, the Laser Interferometer Gravitational-Wave Observatory (LIGO) and Virgo collaborations published a historic paper in which they showed a gravitational signal emitted by the merger of two black holes. These results come after 20 years of hard work by a large collaboration of scientists operating the two LIGO observatories in the US. Barry Barish, Linde Professor of Physics, Emeritus at the California Institute of Technology and former Director of the Global Design Effort for the Internat...

  18. Surface Textural Analysis of Quartz Grains from Modern Point Bar Deposits in Lower Reaches of the Yellow River

    Science.gov (United States)

    Cheng, Yong; Liu, Cong; Lu, Ping; Zhang, Yu; Nie, Qi; Wen, Yiming

    2018-01-01

    The surfaces of quartz grains contain characteristic textures formed during the process of transport, due to their stable physical and chemical properties. The surface textures include the information about source area, transporting force, sedimentary environment and evolution history of sediment. Surface textures of quartz grains from modern point bar deposits in the lower reaches of the Yellow River are observed and studied by scanning electron microscopy (SEM). Results indicate that there are 22 kinds of surface textures. The overall surface morphology of quartz grains shows short transporting time and distance and weak abrasive action of the river water. The combined surface textures caused by mechanical action indicate that quartz grains are transporting in a high-energy hydrodynamic condition and suffer a strong mechanical impact and abrasion. The common solution pits prove that the chemical property of transportation medium is very active and quartz grains receive an obvious chemical action. The combination of these surface textures can be an identification mark of fluvial environment, and that is: quartz grains are main subangular outline, whose roundness is higher with the farther motion distance; Surface fluctuation degree of quartz grains is relatively high, and gives priority to high and medium relief; V-shaped percussion marks are very abundant caused by mechanical action; The conchoidal of different sizes and steps are common-developed with paragenesis relationship; Solution pits are common-developed as well. The study makes up for the blank of surface textures analysis of quartz grains from modern fluvial deposits in China. It provides new ideas and evidence for studies of the sedimentary process and environmental significance, although the deep meanings of these micro textures remain to be further researched.

  19. Model for texture evolution in cold rolling of 2.4 wt.-% Si non-oriented electrical steel

    Science.gov (United States)

    Wei, X.; Hojda, S.; Dierdorf, J.; Lohmar, J.; Hirt, G.

    2017-10-01

    Iron loss and limited magnetic flux density are constraints for NGO electrical steel used in highly efficient electrical machinery cores. The most important factors that affect these properties are the final microstructure and the texture of the NGO steel. Reviewing the whole process chain, cold rolling plays an important role because the recrystallization and grain growth during the final heat treatment can be strongly affected by the stored energy and microstructure of cold rolling, and some texture characteristics can be inherited as well. Therefore, texture evolution during cold rolling of NGO steel is worth a detailed investigation. In this paper, texture evolution in cold rolling of non-oriented (NGO) electrical steel is simulated with a crystal plasticity finite element method (CPFEM) model. In previous work, a CPFEM model has been implemented for simulating the texture evolution with periodic boundary conditions and a phenomenological constitutive law. In a first step the microstructure in the core of the workpiece was investigated and mapped to a representative volume element to predict the texture evolution. In this work an improved version of the CPFEM model is described that better reflects the texture evolution in cold rolling of NGO electrical steel containing 2.4 wt.-% Si. This is achieved by applying the deformation gradient and calibrating the flow curve within the CPFEM model. Moreover, the evolution of dislocation density is calculated and visualized in this model. An in depth comparison of the numerical and experimental results reveals, that the improved CPFEM model is able to represent the important characteristics of texture evolution in the core of the workpiece during cold rolling with high precision.

  20. Characterization of microstructure and texture across dissimilar super duplex/austenitic stainless steel weldment joint by super duplex filler metal

    Energy Technology Data Exchange (ETDEWEB)

    Eghlimi, Abbas, E-mail: a.eghlimi@ma.iut.ac.ir [Department of Materials Engineering, Isfahan University of Technology, Isfahan 84156-83111 (Iran, Islamic Republic of); Shamanian, Morteza [Department of Materials Engineering, Isfahan University of Technology, Isfahan 84156-83111 (Iran, Islamic Republic of); Eskandarian, Masoomeh [Department of Materials Engineering, Shiraz University, Shiraz 71348-51154 (Iran, Islamic Republic of); Zabolian, Azam [Department of Natural Resources, Isfahan University of Technology, Isfahan 84156-83111 (Iran, Islamic Republic of); Szpunar, Jerzy A. [Department of Mechanical Engineering, University of Saskatchewan, Saskatoon SK S7N 5A9 (Canada)

    2015-08-15

    In the present paper, microstructural changes across an as-welded dissimilar austenitic/duplex stainless steel couple welded by a super duplex stainless steel filler metal using gas tungsten arc welding process is characterized with optical microscopy and electron back-scattered diffraction techniques. Accordingly, variations of microstructure, texture, and grain boundary character distribution of base metals, heat affected zones, and weld metal were investigated. The results showed that the weld metal, which was composed of Widmanstätten austenite side-plates and allotriomorphic grain boundary austenite morphologies, had the weakest texture and was dominated by low angle boundaries. The welding process increased the ferrite content but decreased the texture intensity at the heat affected zone of the super duplex stainless steel base metal. In addition, through partial ferritization, it changed the morphology of elongated grains of the rolled microstructure to twinned partially transformed austenite plateaus scattered between ferrite textured colonies. However, the texture of the austenitic stainless steel heat affected zone was strengthened via encouraging recrystallization and formation of annealing twins. At both interfaces, an increase in the special character coincident site lattice boundaries of the primary phase as well as a strong texture with <100> orientation, mainly of Goss component, was observed. - Graphical abstract: Display Omitted - Highlights: • Weld metal showed local orientation at microscale but random texture at macroscale. • Intensification of <100> orientated grains was observed adjacent to the fusion lines. • The austenite texture was weaker than that of the ferrite in all duplex regions. • Welding caused twinned partially transformed austenites to form at SDSS HAZ. • At both interfaces, the ratio of special CSL boundaries of the primary phase increased.

  1. Effects of alkali on protein polymerization and textural characteristics of textured wheat protein.

    Science.gov (United States)

    Li, Ting; Guo, Xiao-Na; Zhu, Ke-Xue; Zhou, Hui-Ming

    2018-01-15

    The impact of alkali addition on the degree of gluten polymerization and textural characteristics of textured wheat protein was investigated. Results showed that the extrusion process increased the average molecular weight of gluten as evidenced by SDS-PAGE and SDS extractable protein. The addition of alkali not only promoted the degree of gluten polymerization, but also induced dehydroalanine-derived cross-linking. Alkali addition decreased the content of cystine and increased the contents of dehydroalanine and lanthionine. The obvious decrease of free SH showed that dehydroalanine-derived cross-linking was quantitatively less crucial than disulfide cross-linking. Furthermore, the protein cross-linking induced by alkali improved the texture properties of gluten extrudates. SEM analysis showed extrusion under alkaline condition conferred a more fibrous microstructure as a consequence of a compact gluten network. Copyright © 2017 Elsevier Ltd. All rights reserved.

  2. Development of crystal texture in R-lean RFeCoNbB (R = Nd, Pr) alloy during melt spinning processes

    International Nuclear Information System (INIS)

    Li, Wei; Li, Lanlan; Liu, Yanguo; Zhang, Xiangyi

    2012-01-01

    Highlights: ► We study the texture development during the melt spinning processes of R-lean alloys. ► A strong (0 0 l) texture parallel to the ribbon plane for (Nd,Pr) 2 Fe 14 B is obtained. ► The texture for R 2 Fe 14 B crystals can develop by a seeding effect of α-Fe texture. ► The anisotropic nanocomposite magnet yields M r = 0.78M s and large (BH) max = 25.2 MGOe. - Abstract: The formation of crystal texture of R 2 Fe 14 B nanocrystals in R–Fe–B (R = rare earth) alloys with low R content ( 2 Fe 14 B nanocrystals during the melt spinning processes of Nd 3.6 Pr 5.4 Fe 80 Co 3 NbB 7 by effectively employing the seeding effect of α-Fe nanocrystal texture. The (Nd,Pr) 2 Fe 14 B nanocrystals produced from the R-lean alloy at a wheel speed of 18 m/s show a strong (0 0 l) texture parallel to the ribbon plane, which yields a high remanence M r = 0.78M s and a large energy product (BH) max = 25.2 MGOe for the α-Fe/(Nd,Pr) 2 Fe 14 B nanocomposite ribbons. The present study provides a promising approach to prepare anisotropic nanocomposite magnets from R-lean alloys.

  3. The formation of cosmic structure in a texture-seeded cold dark matter cosmogony

    Science.gov (United States)

    Gooding, Andrew K.; Park, Changbom; Spergel, David N.; Turok, Neil; Gott, Richard, III

    1992-01-01

    The growth of density fluctuations induced by global texture in an Omega = 1 cold dark matter (CDM) cosmogony is calculated. The resulting power spectra are in good agreement with each other, with more power on large scales than in the standard inflation plus CDM model. Calculation of related statistics (two-point correlation functions, mass variances, cosmic Mach number) indicates that the texture plus CDM model compares more favorably than standard CDM with observations of large-scale structure. Texture produces coherent velocity fields on large scales, as observed. Excessive small-scale velocity dispersions, and voids less empty than those observed may be remedied by including baryonic physics. The topology of the cosmic structure agrees well with observation. The non-Gaussian texture induced density fluctuations lead to earlier nonlinear object formation than in Gaussian models and may also be more compatible with recent evidence that the galaxy density field is non-Gaussian on large scales. On smaller scales the density field is strongly non-Gaussian, but this appears to be primarily due to nonlinear gravitational clustering. The velocity field on smaller scales is surprisingly Gaussian.

  4. Effect of substrate on texture and mechanical properties of Mg-Cu-Zn thin films

    Science.gov (United States)

    Eshaghi, F.; Zolanvari, A.

    2018-04-01

    In this work, thin films of Mg-Cu-Zn with 60 nm thicknesses have been deposited on the Si(100), Al, stainless steel, and Cu substrates using DC magnetron sputtering. FESEM images displayed uniformity of Mg-Cu-Zn particles on the different substrates. AFM micrograph revealed the roughness of thin film changes due to the different kinds of the substrates. XRD measurements showed the existence of strong Mg (002) reflections and weak Mg (101) peaks. Residual stress and adhesion force have been measured as the mechanical properties of the Mg-Cu-Zn thin films. The residual stresses of thin films which have been investigated by X-ray diffraction method revealed that the thin films sputtered on the Si and Cu substrates endure minimum and maximum stresses, respectively, during the deposition process. However, the force spectroscopy analysis indicated that the films grew on the Si and Cu experienced maximum and minimum adhesion force. The texture analysis has been done using XRD instrument to make pole figures of Mg (002) and Mg (101) reflections. ODFs have been calculated to evaluate the distribution of the orientations within the thin films. It was found that the texture and stress have an inverse relation, while the texture and the adhesion force of the Mg-Cu-Zn thin films have direct relation. A thin film that sustains the lowest residual stresses and highest adhesive force had the strongest {001} basal fiber texture.

  5. Numerosity but not texture-density discrimination correlates with math ability in children.

    Science.gov (United States)

    Anobile, Giovanni; Castaldi, Elisa; Turi, Marco; Tinelli, Francesca; Burr, David C

    2016-08-01

    Considerable recent work suggests that mathematical abilities in children correlate with the ability to estimate numerosity. Does math correlate only with numerosity estimation, or also with other similar tasks? We measured discrimination thresholds of school-age (6- to 12.5-years-old) children in 3 tasks: numerosity of patterns of relatively sparse, segregatable items (24 dots); numerosity of very dense textured patterns (250 dots); and discrimination of direction of motion. Thresholds in all tasks improved with age, but at different rates, implying the action of different mechanisms: In particular, in young children, thresholds were lower for sparse than textured patterns (the opposite of adults), suggesting earlier maturation of numerosity mechanisms. Importantly, numerosity thresholds for sparse stimuli correlated strongly with math skills, even after controlling for the influence of age, gender and nonverbal IQ. However, neither motion-direction discrimination nor numerosity discrimination of texture patterns showed a significant correlation with math abilities. These results provide further evidence that numerosity and texture-density are perceived by independent neural mechanisms, which develop at different rates; and importantly, only numerosity mechanisms are related to math. As developmental dyscalculia is characterized by a profound deficit in discriminating numerosity, it is fundamental to understand the mechanism behind the discrimination. (PsycINFO Database Record (c) 2016 APA, all rights reserved).

  6. Non-Uniform Laser Surface Texturing of an Un-Tapered Square Pad for Tribological Applications

    Directory of Open Access Journals (Sweden)

    Antonio Ancona

    2017-10-01

    Full Text Available Femtosecond laser surface micro-texturing has emerged as a promising technology to enhance the tribological properties of different kinds of electromechanical devices. In this research paper, we have exploited the intrinsic flexibility and micrometric accuracy of femtosecond laser ablation to realize complex micro-structural modifications on the surface of a laboratory prototype of a steel thrust bearing (un-tapered pad. The Bruggeman Texture Hydrodynamics theory (BTH is employed for the design of the anisotropic and non-uniform texture maximizing the thrust load of the pad prototype. The preliminary experimental results, reported in this work, show that the non-uniform micro-texture largely affects the friction characteristics of the contact. In particular, in agreement with the BTH predictions, the tribo-system shows friction properties that are strongly sensitive to the direction of the sliding speed, as a consequence of the micro-fluid dynamics which are designed to occur only in a specific sliding direction. We suggest that the joint action of virtual prototyping (BTH lubrication theory and ultrafast laser micro-prototyping can lead to unconventional and impressive results in terms of enhanced or tailored contact mechanics properties of the generic lubricated tribopair.

  7. Heterogeneous nucleation of solid Al from the melt by TiB2 and Al3Ti: An ab initio molecular dynamics study

    KAUST Repository

    Wang, Junsheng

    2010-11-16

    The nucleation of solid Al from the melt by TiB2 is well established and is believed to involve the formation of Al3Ti. Since the atomic-scale mechanisms involved are not fully understood, we look to computer simulation to provide insight. As there is an absence of suitable potentials for all of this complex system we have performed large-scale density-functional-theory molecular dynamics simulations of the nucleation of solid Al from the melt on TiB2 and Al3Ti substrates at undercoolings of around 2 K. Using periodic boundary conditions, we find limited ordering and no signs of incipient growth in the liquid Al close to the B-terminated surface of TiB2. By contrast, we see fcc-like ordering near the Ti-terminated surface, with growth being frustrated by the lattice mismatch between bulk Al and the TiB2 substrate. The Al interatomic distances at the Ti-terminated surface are similar to distances found in Al3Ti; we suggest that the layer encasing TiB2 observed experimentally may be strained Al on a Ti-terminated surface rather than Al3Ti. For the Al3Ti substrate, fcc-like structures are observed on both sides which extend rapidly into the melt. Periodic boundaries introduce unphysical stresses which we removed by introducing a vacuum region to separate the liquid from the solid at one of the interfaces. We see ordering in the Al on both the B-terminated (0001) surface of TiB2, and on Al3Ti(112), with the ordering able to be stronger on the Al3Ti substrate. However, we cannot draw strong conclusions as these simulations need more time to allow long-ranged fluctuations in the liquid Al to dampen out. The huge computational cost restricted the range and duration of simulations that was possible.

  8. Crystalline TiO2: A Generic and Effective Electron-Conducting Protection Layer for Photoanodes and -cathodes

    DEFF Research Database (Denmark)

    Mei, Bastian Timo; Pedersen, Thomas; Malacrida, Paolo

    2015-01-01

    and illuminated conditions by performing the oxygen evolution reaction (OER) and using the Fe(II)/Fe(III) redox couple. These measurements reveal that the performance of the Si/TiO2-photoanode assembly is strongly dependent on the TiO2/electrolyte interaction. Finally, the conditions and requirements that make Ti...

  9. Effect of Grain Misorientation Angle on Twinning Propagation in Ti-15Mo Alloy

    Science.gov (United States)

    Im, Y.-D.; Lee, Y.-K.; Song, K. H.

    2018-03-01

    This study was carried out to evaluate the effect of grain misorientation angle distribution on the deformation behavior and twinning of Ti-15Mo alloy. Cold rolling exhibited a significant texture with grains oriented along the {111}//normal direction, which correlate with a higher fraction of low-angle boundaries. This material showed a lower yield strength and higher elongation than those of the hot rolled material. The twinning propagation mainly occurred between neighboring grains with a low-angle relation. Consequently, the texture development was correlated with low-angle boundaries and affected by the increase in the twinning density, which increased the strain hardening rate.

  10. Experimental Analysis of Grease Friction Properties on Sliding Textured Surfaces

    Directory of Open Access Journals (Sweden)

    Xijun Hua

    2017-10-01

    Full Text Available There is comprehensive work on the tribological properties and lubrication mechanisms of oil lubricant used on textured surfaces, however the use of grease lubrication on textured surfaces is rather new. This research article presents an experimental study of the frictional behaviours of grease lubricated sliding contact under mixed lubrication conditions. The influences of surface texture parameters on the frictional properties were investigated using a disc-on-ring tribometer. The results showed that the friction coefficient is largely dependent on texture parameters, with higher and lower texture density resulting in a higher friction coefficient at a fixed texture depth. The sample with texture density of 15% and texture depth of 19 μm exhibited the best friction properties in all experimental conditions because it can store more grease and trap wear debris. The reduction of friction is mainly attributable to the formation of a stable grease lubrication film composed of oil film, transfer film and deposited film, and the hydrodynamic pressure effect of the surface texture, which increases the mating gap and reduces the probability of asperity contact. This result will help in understanding the tribological behaviour of grease on a textured surface and in predicting the lubrication conditions of sliding bearings for better operation in any machinery.

  11. Forest Classification Based on Forest texture in Northwest Yunnan Province

    Science.gov (United States)

    Wang, Jinliang; Gao, Yan; Wang, Xiaohua; Fu, Lei

    2014-03-01

    Forest texture is an intrinsic characteristic and an important visual feature of a forest ecological system. Full utilization of forest texture will be a great help in increasing the accuracy of forest classification based on remote sensed data. Taking Shangri-La as a study area, forest classification has been based on the texture. The results show that: (1) From the texture abundance, texture boundary, entropy as well as visual interpretation, the combination of Grayscale-gradient co-occurrence matrix and wavelet transformation is much better than either one of both ways of forest texture information extraction; (2) During the forest texture information extraction, the size of the texture-suitable window determined by the semi-variogram method depends on the forest type (evergreen broadleaf forest is 3×3, deciduous broadleaf forest is 5×5, etc.). (3)While classifying forest based on forest texture information, the texture factor assembly differs among forests: Variance Heterogeneity and Correlation should be selected when the window is between 3×3 and 5×5 Mean, Correlation, and Entropy should be used when the window in the range of 7×7 to 19×19 and Correlation, Second Moment, and Variance should be used when the range is larger than 21×21.

  12. Forest Classification Based on Forest texture in Northwest Yunnan Province

    International Nuclear Information System (INIS)

    Wang, Jinliang; Gao, Yan; Fu, Lei; Wang, Xiaohua

    2014-01-01

    Forest texture is an intrinsic characteristic and an important visual feature of a forest ecological system. Full utilization of forest texture will be a great help in increasing the accuracy of forest classification based on remote sensed data. Taking Shangri-La as a study area, forest classification has been based on the texture. The results show that: (1) From the texture abundance, texture boundary, entropy as well as visual interpretation, the combination of Grayscale-gradient co-occurrence matrix and wavelet transformation is much better than either one of both ways of forest texture information extraction; (2) During the forest texture information extraction, the size of the texture-suitable window determined by the semi-variogram method depends on the forest type (evergreen broadleaf forest is 3×3, deciduous broadleaf forest is 5×5, etc.). (3)While classifying forest based on forest texture information, the texture factor assembly differs among forests: Variance Heterogeneity and Correlation should be selected when the window is between 3×3 and 5×5; Mean, Correlation, and Entropy should be used when the window in the range of 7×7 to 19×19; and Correlation, Second Moment, and Variance should be used when the range is larger than 21×21

  13. Can dental microwear textures record inter-individual dietary variations?

    Directory of Open Access Journals (Sweden)

    Gildas Merceron

    Full Text Available BACKGROUND: Dental microwear analyses are commonly used to deduce the diet of extinct mammals. Conventional methods rely on the user identifying features within a 2D image. However, recent interdisciplinary research has lead to the development of an advanced methodology that is free of observer error, based on the automated quantification of 3D surfaces by combining confocal microscopy with scale-sensitive fractal analysis. This method has already proved to be very efficient in detecting dietary differences between species. Focusing on a finer, intra-specific scale of analysis, the aim of this study is to test this method's ability to track such differences between individuals from a single population. METHODOLOGY/PRINCIPAL FINDINGS: For the purposes of this study, the 3D molar microwear of 78 individuals from a well-known population of extant roe deer (Capreolus caprelous is quantified. Multivariate statistical analyses indicate significant seasonal and sexual differences in individual dental microwear design. These are probably the consequence of seasonal variations in fruit, seed and leaf availability, as well as differences in feeding preference between males and females due to distinct energy requirements during periods of rutting, gestation or giving birth. Nevertheless, further investigations using two-block Partial Least-Squares analysis show no strong relationship between individual stomach contents and microwear texture. This is an expected result, assuming that stomach contents are composed of food items ingested during the last few hours whereas dental microwear texture records the physical properties of items eaten over periods of days or weeks. CONCLUSIONS/SIGNIFICANCE: Microwear 3D scale-sensitive fractal analysis does detect differences in diet ranging from the inter-feeding styles scale to the intra-population between-season and between-sex scales. It is therefore a possible tool, to be used with caution, in the further

  14. Tropical Texture Determination by Proximal Sensing Using a Regional Spectral Library and Its Relationship with Soil Classification

    Directory of Open Access Journals (Sweden)

    Marilusa P. C. Lacerda

    2016-08-01

    Full Text Available The search for sustainable land use has increased in Brazil due to the important role that agriculture plays in the country. Soil detailed classification is related with texture attribute. How can one discriminate the same soil class with different textures using proximal soil sensing, as to reach surveys, land use planning and increase crop productivity? This study aims to evaluate soil texture using a regional spectral library and its usefulness on classification. We collected 3750 soil samples covering 3 million ha within strong soil class variations in São Paulo State. The spectral analyses of soil samples from topsoil and subsoil were measured in laboratory (400–2500 nm. The potential of a regional soil spectral library was evaluated on the discrimination of soil texture. We considered two types of soil texture systems, one related with soil classification and another with soil managements. The soil line technique was used to assess differentiation between soil textural groups. Soil spectra were summarized by principal component analysis (PCA to select relevant information on the spectra. Partial least squares regression (PLSR was used to predict texture. Spectral curves indicated different shapes according to soil texture and discriminated particle size classes from clayey to sandy soils. In the visible region, differences were small because of the organic matter, while the short wave infrared (SWIR region showed more differences; thus, soil texture variation could be differentiated by quartz. Angulation differences are on a spectral curve from NIR to SWIR. The statistical models predicted clay and sand levels with R2 = 0.93 and 0.96, respectively. Indeed, we achieved a difference of 1.2% between laboratory and spectroscopy measurement for clay. The spectral information was useful to classify Ferralsols with different texture classification. In addition, the spectra differentiated Lixisols from Ferralsols and Arenosols. This work can

  15. John Strong (1941 - 2006)

    CERN Multimedia

    Wickens, F

    Our friend and colleague John Strong was cruelly taken from us by a brain tumour on Monday 31st July, a few days before his 65th birthday John started his career working with a group from Westfield College, under the leadership of Ted Bellamy. He obtained his PhD and spent the early part of his career on experiments at Rutherford Appleton Laboratory (RAL), but after the early 1970s his research was focussed on experiments in CERN. Over the years he made a number of notable contributions to experiments in CERN: The Omega spectrometer adopted a system John had originally developed for experiments at RAL using vidicon cameras to record the sparks in the spark chambers; He contributed to the success of NA1 and NA7, where he became heavily involved in the electronic trigger systems; He was responsible for the second level trigger system for the ALEPH detector and spent five years leading a team that designed and built the system, which ran for twelve years with only minor interventions. Following ALEPH he tur...

  16. Stirring Strongly Coupled Plasma

    CERN Document Server

    Fadafan, Kazem Bitaghsir; Rajagopal, Krishna; Wiedemann, Urs Achim

    2009-01-01

    We determine the energy it takes to move a test quark along a circle of radius L with angular frequency w through the strongly coupled plasma of N=4 supersymmetric Yang-Mills (SYM) theory. We find that for most values of L and w the energy deposited by stirring the plasma in this way is governed either by the drag force acting on a test quark moving through the plasma in a straight line with speed v=Lw or by the energy radiated by a quark in circular motion in the absence of any plasma, whichever is larger. There is a continuous crossover from the drag-dominated regime to the radiation-dominated regime. In the crossover regime we find evidence for significant destructive interference between energy loss due to drag and that due to radiation as if in vacuum. The rotating quark thus serves as a model system in which the relative strength of, and interplay between, two different mechanisms of parton energy loss is accessible via a controlled classical gravity calculation. We close by speculating on the implicati...

  17. Strong-interaction nonuniversality

    International Nuclear Information System (INIS)

    Volkas, R.R.; Foot, R.; He, X.; Joshi, G.C.

    1989-01-01

    The universal QCD color theory is extended to an SU(3) 1 direct product SU(3) 2 direct product SU(3) 3 gauge theory, where quarks of the ith generation transform as triplets under SU(3)/sub i/ and singlets under the other two factors. The usual color group is then identified with the diagonal subgroup, which remains exact after symmetry breaking. The gauge bosons associated with the 16 broken generators then form two massive octets under ordinary color. The interactions between quarks and these heavy gluonlike particles are explicitly nonuniversal and thus an exploration of their physical implications allows us to shed light on the fundamental issue of strong-interaction universality. Nonuniversality and weak flavor mixing are shown to generate heavy-gluon-induced flavor-changing neutral currents. The phenomenology of these processes is studied, as they provide the major experimental constraint on the extended theory. Three symmetry-breaking scenarios are presented. The first has color breaking occurring at the weak scale, while the second and third divorce the two scales. The third model has the interesting feature of radiatively induced off-diagonal Kobayashi-Maskawa matrix elements

  18. Titanium Matrix Composite Ti/TiN Produced by Diode Laser Gas Nitriding

    Directory of Open Access Journals (Sweden)

    Aleksander Lisiecki

    2015-01-01

    Full Text Available A high power direct diode laser, emitting in the range of near infrared radiation at wavelength 808–940 nm, was applied to produce a titanium matrix composite on a surface layer of titanium alloy Ti6Al4V by laser surface gas nitriding. The nitrided surface layers were produced as single stringer beads at different heat inputs, different scanning speeds, and different powers of laser beam. The influence of laser nitriding parameters on the quality, shape, and morphology of the surface layers was investigated. It was found that the nitrided surface layers consist of titanium nitride precipitations mainly in the form of dendrites embedded in the titanium alloy matrix. The titanium nitrides are produced as a result of the reaction between molten Ti and gaseous nitrogen. Solidification and subsequent growth of the TiN dendrites takes place to a large extent at the interface of the molten Ti and the nitrogen gas atmosphere. The direction of TiN dendrites growth is perpendicular to the surface of molten Ti. The roughness of the surface layers depends strongly on the heat input of laser nitriding and can be precisely controlled. In spite of high microhardness up to 2400 HV0.2, the surface layers are crack free.

  19. Effect of Ti seed and spacer layers on structure and magnetic properties of FeNi thin films and FeNi-based multilayers

    Energy Technology Data Exchange (ETDEWEB)

    Svalov, A.V., E-mail: andrey.svalov@ehu.es [Departamento de Electricidad y Electrónica, Universidad del País Vasco (UPV/EHU), 48080 Bilbao (Spain); Department of Magnetism and Magnetic Nanomaterials, Ural Federal University, 620002 Ekaterinburg (Russian Federation); Larrañaga, A. [SGIker, Servicios Generales de Investigación, Universidad del País Vasco (UPV/EHU), 48080 Bilbao (Spain); Kurlyandskaya, G.V. [Departamento de Electricidad y Electrónica, Universidad del País Vasco (UPV/EHU), 48080 Bilbao (Spain); Department of Magnetism and Magnetic Nanomaterials, Ural Federal University, 620002 Ekaterinburg (Russian Federation)

    2014-10-15

    Highlights: • Fe{sub 19}Ni{sub 81} films and FeNi-based multilayers were prepared by magnetron sputtering. • The samples were deposited onto glass substrates at room temperature. • Ti/FeNi films exhibit good (1 1 1) texture and crystallinity. • The thick Cu seed increases the coercive force of the magnetic layer. • The thin Ti spacer restores the magnetic softness of the Cu/Ti/FeNi multilayers. - Abstract: The microstructure and magnetic properties of sputtered permalloy films and FeNi-based multilayers prepared by magnetron sputtering have been studied. X-ray diffraction measurements indicate that Ti/FeNi films exhibit good (1 1 1) texture and crystallinity. Ti/FeNi bilayers with high crystallographic quality have relatively low resistivity. The Ti seed layer does not influence the magnetic properties of FeNi film in Ti/FeNi bilayers, but the thick Cu seed layer leads to an increase of the coercive force of the magnetic layer. For the FeNi films deposited on thick Cu seed layer, the (0 1 0) and (0 0 2) diffraction peaks of hcp nickel were clearly observed. The thin Ti spacer between Cu and FeNi layers prevents the formation of the nickel phase and restores the magnetic softness of the FeNi layer in the Cu/Ti/FeNi sample. Obtained results can be important for the development of multilayer sensitive elements for giant magnetoimpedance or magnetoresistance detectors.

  20. Texturing and modeling a procedural approach

    CERN Document Server

    Ebert, David S

    1994-01-01

    Congratulations to Ken Perlin for his 1997 Technical Achievement Award from the Academy of Motion Picture Arts and Science Board of Governors, given in recognition of the development of ""Turbulence"", Perlin Noise, a technique discussed in this book which is used to produce natural appearing textures on computer-generated surfaces for motion picture visual effects. Dr. Perlin joins Darwyn Peachey (co-developer of RenderMan(R), also discussed in the book) in being honored with this prestigious award.* * Written at a usable level by the developers of the techniques* Serves as a source book for

  1. Maya Studio Projects Texturing and Lighting

    CERN Document Server

    Lanier, Lee

    2011-01-01

    Learn to create realistic digital assets for film and games with this project-based guide Focused entirely on practical projects, this hands-on guide shows you how to use Maya's texturing and lighting tools in real-world situations. Whether you need to sharpen your skills or you're looking to break into the field for the first time, you'll learn top industry techniques for this important skill as you follow the instructions for several specific projects. You can even create your own version, using final Maya scene files to validate results. The companion DVD includes supplemental videos, proje

  2. Quantitative texture analysis of electrodeposited line patterns

    DEFF Research Database (Denmark)

    Pantleon, Karen; Somers, Marcel A.J.

    2005-01-01

    Free-standing line patterns of Cu and Ni were manufactured by electrochemical deposition into lithographically prepared patterns. Electrodeposition was carried out on top of a highly oriented Au-layer physically vapor deposited on glass. Quantitative texture analysis carried out by means of x......-ray diffraction for both the substrate layer and the electrodeposits yielded experimental evidence for epitaxy between Cu and Au. An orientation relation between film and substrate was discussed with respect to various concepts of epitaxy. While the conventional mode of epitaxy fails for the Cu...

  3. Properties of TiO2 prepared by acid treatment of BaTiO3

    International Nuclear Information System (INIS)

    Okada, Kiyoshi; Yanagisawa, Tomoki; Kameshima, Yoshikazu; Nakajima, Akira

    2007-01-01

    TiO 3 powders were prepared by acid treatment of BaTiO 3 and their properties were investigated. The BaTiO 3 powder was subjected to HNO 3 in concentrations ranging from 10 -3 to 8 M at 90 deg. C for 0.5-6 h. Dissolution of BaTiO 3 and precipitation of TiO 2 occurred at acid concentrations of 2-5 M. BaTiO 3 dissolves completely to form a clear solution at reaction times of 0.5-1 h, but a rutile precipitate is formed after 2 h of acid treatment. By contrast, anatase is precipitated by adjusting the pH of the clear solution to 2-3 using NaOH or NH 4 OH solution. The rutile crystals were small and rod-shaped, consisting of many small coherent domains connected by grain boundaries with small inclination angles and edge dislocations, giving them a high specific surface area (S BET ). With increasing HNO 3 concentration, the S BET value increased from 100 to 170 m 2 /g while the crystallite size decreased from 25 to 11 nm. The anatase crystals obtained here were very small equi-axial particles with a smaller crystallite size than the rutile and S BET values of about 270 m 2 /g (higher than the rutile samples). The photocatalytic activity of these TiO 2 was determined from the decomposition rate of Methylene Blue under ultraviolet irradiation. Higher decomposition rates were obtained with larger crystallite sizes resulting from heat treatment. The maximum decomposition rates were obtained in samples heated at 500-600 deg. C. The photocatalytic activity of the TiO 2 was found to depend more strongly on the sample crystallite size than on S BET

  4. Influence of annealing on the interface-correlated mechanical properties of a Ti/STS clad sheet

    International Nuclear Information System (INIS)

    Jo, Yu Mi; Lee, Kwang Seok; Lee, Young-Seon; Kang, Namhyun

    2014-01-01

    We investigated effects of annealing conditions on the interface-correlated microstructural evolution and subsequent mechanical properties of a Ti/STS439 clad sheet. The evolution of the interface microstructure was first analyzed with optical microscopy, scanning electron microscopy, transmission electron microscopy, and energy dispersive spectroscopy. The generation and growth of a diffusive layer consisted of μm-scale β- Ti adjacent to the parent Ti, and the nm-scale intermetallic compounds Fe 2 Ti and FeTi adjacent to STS phases were indexed. The thicknesses of β-Ti, Fe 2 Ti, and FeTi increased with annealing time and temperature. Mechanical properties were evaluated by peel, micro indentation and uniaxial tensile tests. Improvement of bonding strength between Ti and STS by feasible annealing below 650 ℃ seemed to be strongly related to the generation of considerable metallurgical bonding.

  5. Dilute Al and V NMR in α-Ti

    International Nuclear Information System (INIS)

    Chou, L.H.; Rowland, T.J.

    1992-01-01

    We report a nuclear-magnetic-resonance investigation of four titanium alloys: Ti--1 at. % V, Ti--2 at. % V, Ti--1 at. % Al, and Ti--2 at. % Al. Interpretation of the experimental 51 V and 27 Al absorption curves was accomplished largely by comparison with computer-simulated curves. Since the latter include the effects of nuclear-quadrupole and anisotropic Knight-shift interactions, dipolar broadening, and inhomogeneous Knight shift for the V and Al solute nuclei, the comparison yields experimental values for the electric-field gradient, axially symmetric anistropic Knight shift, and isotropic Knight shift, from which we attempt to deduce the local charge distribution at the V or Al atoms in the hcp α-Ti matrix. We find that the localized states on an Al impurity exhibit very little of the character of the host Ti atomic structure. There is no orbital contribution to the Knight shift and the s conduction-electron density at Al sites is small. On the other hand, when vanadium is present as a dilute solute in the Ti lattice, only minor changes in its Knight shift are found. There is a large orbital-shift contribution, and the V nuclear absorption exhibits much the same character as in pure metallic V; there is, however, clear evidence of the V charge distribution assuming the hexagonal symmetry of the Ti lattice. The measured temperature dependences of the anisotropic Knight shift and electric-field-gradient values at V solute sites in Ti are also discussed. On partitioning the field gradient we find that the contribution from local non-s electrons is about two to five times larger in magnitude than the Ti-lattice ion value, a strong indication that the electronic structure near V (but not Al) resembles that of the matrix Ti

  6. Effect of microstructure of TiN film on properties as bipolar plate coatings in polymer electrolyte membrane fuel cell prepared by inductively coupled plasma assisted magnetron sputtering

    International Nuclear Information System (INIS)

    Feng, Kai; Li, Zhuguo

    2013-01-01

    As potential application in bipolar plate of polymer electrolyte membrane fuel cell, the microstructure, corrosion resistance and the electrical conductivity of titanium nitride (TiN) and Si doped titanium nitride (Ti 0.9 Si 0.1 N) films deposited by magnetron sputtering with different bias voltages are investigated by X-ray diffraction (XRD), scanning electron microscope (SEM), atomic force microscope (AFM), electrochemical test and four-point probe method, respectively. XRD, SEM and AFM results reveal that the texture and topography of TiN film depend on the bias voltage and incorporation of Si. When the bias voltage is − 20 V and − 30 V, the TiN and Ti 0.9 Si 0.1 N films exhibit a dense (111) plane preferred growth, denser structure and smoother surface topography. The potentiodynamic test results indicate that the TiN and Ti 0.9 Si 0.1 N films have higher chemical inertness and better corrosion resistance. The films can satisfy the requirement of current density for bipolar plate materials. Incorporation of Si element into TiN film makes the passive current density more stable. Four-point probe measurement results show that the resistivity of both TiN and Ti 0.9 Si 0.1 N films reaches minimum when the deposition bias voltage is − 20 V. - Highlights: • Dense TiN and Ti 0.9 Si 0.1 N films are deposited by magnetron sputtering. • Preferred growth orientation of TiN depends on the bias voltage and Si doping. • TiN and Ti 0.9 Si 0.1 N films have excellent corrosion resistance. • Surface conductivity of TiN and Ti 0.9 Si 0.1 N films evolves with bias voltage

  7. Fabrication of TiN nanorods by electrospinning and their electrochemical properties

    International Nuclear Information System (INIS)

    Sun, Dongfei; Lang, Junwei; Yan, Xingbin; Hu, Litian; Xue, Qunji

    2011-01-01

    TiN nanorods were synthesized using electrospinning technique followed by thermolysis in different atmospheres. A dimethyl formamide-ethanol solution of poly-(vinyl pyrrolidone) and Ti (IV)-isopropoxide was used as the electrospinning precursor solution and as-spun nanofibers were calcined at 500 o C in air to generate TiO 2 nanofibers. Subsequently, a conversion from TiO 2 nanofibers to TiN nanorods was employed by the nitridation treatment at 600∼1400 o C in ammonia atmosphere. A typical characteristic of the final products was that the pristine nanofibers were cut into nanorods. The conversion from TiO 2 to TiN was realized when the nitridation temperature was above 800 o C. As-prepared nanorods were composed of TiN nano-crystallites and the average crystallite size gradually increased with the increase of the nitridation temperature. Electrochemical properties of TiN nanorods showed strong dependence on the nitridation temperature. The maximum value of the specific capacitance was obtained from the TiN nanorods prepared at 800 o C. -- Graphical Abstract: TiN nanorods were prepared using electrospinning followed by thermolysis under different atmospheres. Electrochemical properties of the TiN nanorods showed strong dependence on the nitridation temperature. Display Omitted Highlights: → TiN nanorods were synthesized by a combination of electrospinning and thermolysis. → Electrochemical properties showed strong dependence on the nitridation temperature. → The TiN nanorods prepared at 800 o C possessed the highest specific capacitance.

  8. Numerical study of the collapse of a global texture

    Science.gov (United States)

    Barriola, Manuel

    1993-12-01

    We study the numerical solution to the full field equations describing the evolution of a spherically symmetric global texture. We concentrate on the evolution of the fields after the texture collapses. We compare this result with a previous analytical solution found by Turok and Spergel using the nonlinear σ model approximation. The energy produced in massive modes is of the order of 1016 GeV and is almost independent of the initial size of the texture.

  9. Texture development during recrystallization of aluminium containing large particles

    DEFF Research Database (Denmark)

    Juul Jensen, Dorte; Hansen, Niels; Humphreys, F. J.

    1985-01-01

    The recrystallization process in heavily deformed commercially pure aluminium containing large intermetallic particles was studied by in situ neutron diffraction texture measurements and various microscopical techniques including texture measurements in local areas and simultaneous determination...... of orientations takes place close to larger particles or clusters of particles early in the recrystallization process. The texture of fully recrystallized material, however, contains only a relatively weak random component showing that the randomisation effect of the particles was limited. This was ascribed...

  10. Evidence for metalsupport interactions in Au modified TiO_{x}/SBA-15 materials prepared by photodeposition

    OpenAIRE

    Mei, Bastian; Wiktor, Christian; Turner, Stuart; Pougin, Anna; Tendeloo, Van, Gustaaf; Fischer, Roland A.; Muhler, Martin; Strunk, Jennifer

    2013-01-01

    Abstract: Gold nanoparticles have been efficiently photodeposited onto titanate-loaded SBA-15 (Ti(x)/SBA-15) with different titania coordination. Transmission electron microscopy shows that relatively large Au nanoparticles are photodeposited on the outer surface of the Ti(x)/SBA-15 materials and that TiOx tends to form agglomerates in close proximity to the Au nanoparticles, often forming coreshell Au/TiOx structures. This behavior resembles typical processes observed due to strong-metal sup...

  11. Hydrazine-based synergistic Ti(III)/N doping of surfactant-templated TiO{sub 2} thin films for enhanced visible light photocatalysis

    Energy Technology Data Exchange (ETDEWEB)

    Islam, Syed Z.; Rankin, Stephen E., E-mail: srankin@engr.uky.edu

    2016-10-01

    lattice of surfactant-templated TiO{sub 2} films and enhanced visible light photoactivity, but that the benefits are limited by gradual mesostructure deterioration. - Highlights: • Photocatalysis by surfactant-templated ordered mesoporous TiO{sub 2} films measured. • Hydrazine treatment was performed for co-doping of Ti{sup 3+} and N. • Visible light absorption increases with Ti{sup 3+} and N co-doping. • Visible-light driven water splitting enhanced up to 4× over undoped titania. • Optimal time of hydrazine exposure found due to pore texture coarsening.

  12. Texture classification by texton: statistical versus binary.

    Directory of Open Access Journals (Sweden)

    Zhenhua Guo

    Full Text Available Using statistical textons for texture classification has shown great success recently. The maximal response 8 (Statistical_MR8, image patch (Statistical_Joint and locally invariant fractal (Statistical_Fractal are typical statistical texton algorithms and state-of-the-art texture classification methods. However, there are two limitations when using these methods. First, it needs a training stage to build a texton library, thus the recognition accuracy will be highly depended on the training samples; second, during feature extraction, local feature is assigned to a texton by searching for the nearest texton in the whole library, which is time consuming when the library size is big and the dimension of feature is high. To address the above two issues, in this paper, three binary texton counterpart methods were proposed, Binary_MR8, Binary_Joint, and Binary_Fractal. These methods do not require any training step but encode local feature into binary representation directly. The experimental results on the CUReT, UIUC and KTH-TIPS databases show that binary texton could get sound results with fast feature extraction, especially when the image size is not big and the quality of image is not poor.

  13. Surface texture measurement for additive manufacturing

    International Nuclear Information System (INIS)

    Triantaphyllou, Andrew; Tomita, Ben; Milne, Katherine A; Giusca, Claudiu L; Macaulay, Gavin D; Roerig, Felix; Hoebel, Matthias; Leach, Richard K

    2015-01-01

    The surface texture of additively manufactured metallic surfaces made by powder bed methods is affected by a number of factors, including the powder’s particle size distribution, the effect of the heat source, the thickness of the printed layers, the angle of the surface relative to the horizontal build bed and the effect of any post processing/finishing. The aim of the research reported here is to understand the way these surfaces should be measured in order to characterise them. In published research to date, the surface texture is generally reported as an Ra value, measured across the lay. The appropriateness of this method for such surfaces is investigated here. A preliminary investigation was carried out on two additive manufacturing processes—selective laser melting (SLM) and electron beam melting (EBM)—focusing on the effect of build angle and post processing. The surfaces were measured using both tactile and optical methods and a range of profile and areal parameters were reported. Test coupons were manufactured at four angles relative to the horizontal plane of the powder bed using both SLM and EBM. The effect of lay—caused by the layered nature of the manufacturing process—was investigated, as was the required sample area for optical measurements. The surfaces were also measured before and after grit blasting. (paper)

  14. Dynamic air layer on textured superhydrophobic surfaces

    KAUST Repository

    Vakarelski, Ivan Uriev

    2013-09-03

    We provide an experimental demonstration that a novel macroscopic, dynamic continuous air layer or plastron can be sustained indefinitely on textured superhydrophobic surfaces in air-supersaturated water by a natural gas influx mechanism. This type of plastron is an intermediate state between Leidenfrost vapor layers on superheated surfaces and the equilibrium Cassie-Baxter wetting state on textured superhydrophobic surfaces. We show that such a plastron can be sustained on the surface of a centimeter-sized superhydrophobic sphere immersed in heated water and variations of its dynamic behavior with air saturation of the water can be regulated by rapid changes of the water temperature. The simple experimental setup allows for quantification of the air flux into the plastron and identification of the air transport model of the plastron growth. Both the observed growth dynamics of such plastrons and millimeter-sized air bubbles seeded on the hydrophilic surface under identical air-supersaturated solution conditions are consistent with the predictions of a well-mixed gas transport model. © 2013 American Chemical Society.

  15. Orientation relations during the α-ω phase transition of zirconium: in situ texture observations at high pressure and temperature.

    Science.gov (United States)

    Wenk, H-R; Kaercher, P; Kanitpanyacharoen, W; Zepeda-Alarcon, E; Wang, Y

    2013-11-08

    Transition metals Ti, Zr, and Hf have a hexagonal close-packed structure (α) at ambient conditions, but undergo phase transformations with increasing temperature and pressure. Of particular significance is the high-pressure hexagonal ω phase which is brittle compared to the α phase. There has been a long debate about transformation mechanisms and orientation relations between the two crystal structures. Here we present the first high pressure experiments with in situ synchrotron x-ray diffraction texture studies on polycrystalline aggregates. We follow crystal orientation changes in Zr, confirming the original suggestion by Silcock for an α→ω martensitic transition for Ti, with (0001)(α)||(1120)(ω), and a remarkable orientation memory when ω reverts back to α.

  16. Shape-Tailored Features and their Application to Texture Segmentation

    KAUST Repository

    Khan, Naeemullah

    2014-04-01

    Texture Segmentation is one of the most challenging areas of computer vision. One reason for this difficulty is the huge variety and variability of textures occurring in real world, making it very difficult to quantitatively study textures. One of the key tools used for texture segmentation is local invariant descriptors. Texture consists of textons, the basic building block of textures, that may vary by small nuisances like illumination variation, deformations, and noise. Local invariant descriptors are robust to these nuisances making them beneficial for texture segmentation. However, grouping dense descriptors directly for segmentation presents a problem: existing descriptors aggregate data from neighborhoods that may contain different textured regions, making descriptors from these neighborhoods difficult to group, leading to significant errors in segmentation. This work addresses this issue by proposing dense local descriptors, called Shape-Tailored Features, which are tailored to an arbitrarily shaped region, aggregating data only within the region of interest. Since the segmentation, i.e., the regions, are not known a-priori, we propose a joint problem for Shape-Tailored Features and the regions. We present a framework based on variational methods. Extensive experiments on a new large texture dataset, which we introduce, show that the joint approach with Shape-Tailored Features leads to better segmentations over the non-joint non Shape-Tailored approach, and the method out-performs existing state-of-the-art.

  17. Progress in bulk texture measurement using neutron diffraction

    International Nuclear Information System (INIS)

    Xu, Pingguang; Suzuki, Hiroshi; Akita, Koichi; Harjo, Stefanus; Gong, Wu; Tomota, Yo; Ito, Takayoshi; Morii, Yukio; Suzuki, Tetsuya; Lutterotti, Luca

    2015-01-01

    The current status of bulk texture measurements both using angle dispersive neutron diffraction and time-of-flight neutron diffraction at JAEA was briefly reviewed, then the effect of sample orientation coverage in the time-of-flight neutron diffraction on the reliability of reconstructed pole figure on the reliability of reconstructed pole figure was simply compared after the simultaneous Rietveld texture analysis. The similar texture results obtained at different orientation coverage levels suggests that it is possible to reduce the sample rotation times reasonably during the bulk texture measurement. (author)

  18. The Example of Texture Influence in Stress Analysis

    CERN Document Server

    Lychagina, T A

    2002-01-01

    Influence of texture on the stress-strain curves experimentally measured in the elastic region by neutron diffraction of an extruded Cu rod is shown. Texture information is obtained from the pole figures measured by neutron diffraction as well. Stress-strain curves are computed with elastic polycrystalline properties calculated with and without taking texture into account. Calculations of elastic polycrystalline properties with texture are carried out according to geometric mean model. The advantage of geometric mean averaging recently developed for diffraction elastic constant calculation is experimentally confirmed.

  19. Chemical composition and temperature influence on honey texture properties.

    Science.gov (United States)

    Oroian, Mircea; Paduret, Sergiu; Amariei, Sonia; Gutt, Gheorghe

    2016-01-01

    The aim of this study is to evaluate the chemical composition and temperatures (20, 30, 40, 50 and 60 °C) influence on the honey texture parameters (hardness, viscosity, adhesion, cohesiveness, springiness, gumminess and chewiness). The honeys analyzed respect the European regulation in terms of moisture content and inverted sugar concentration. The texture parameters are influenced negatively by the moisture content, and positively by the °Brix concentration. The texture parameters modelling have been made using the artificial neural network and the polynomial model. The polynomial model predicted better the texture parameters than the artificial neural network.

  20. Extreme Compression and Modeling of Bidirectional Texture Function

    Czech Academy of Sciences Publication Activity Database

    Haindl, Michal; Filip, Jiří

    2007-01-01

    Roč. 29, č. 10 (2007), s. 1859-1865 ISSN 0162-8828 R&D Projects: GA AV ČR 1ET400750407; GA MŠk 1M0572; GA AV ČR IAA2075302 EU Projects: European Commission(XE) 507752 - MUSCLE Grant - others:GA MŠk(CZ) 2C06019 Institutional research plan: CEZ:AV0Z10750506 Keywords : Rough texture * 3D texture * BTF * texture synthesis * texture modeling * data compression Subject RIV: BD - Theory of Information Impact factor: 3.579, year: 2007 http://doi.ieeecomputersociety.org/10.1109/TPAMI.2007.1139

  1. Subtle changes in the flavour and texture of a drink enhance expectations of satiety

    Directory of Open Access Journals (Sweden)

    McCrickerd Keri

    2012-10-01

    Full Text Available Abstract Background The consumption of liquid calories has been implicated in the development of obesity and weight gain. Energy-containing drinks are often reported to have a weak satiety value: one explanation for this is that because of their fluid texture they are not expected to have much nutritional value. It is important to consider what features of these drinks can be manipulated to enhance their expected satiety value. Two studies investigated the perception of subtle changes in a drink’s viscosity, and the extent to which thick texture and creamy flavour contribute to the generation of satiety expectations. Participants in the first study rated the sensory characteristics of 16 fruit yogurt drinks of increasing viscosity. In study two, a new set of participants evaluated eight versions of the fruit yogurt drink, which varied in thick texture, creamy flavour and energy content, for sensory and hedonic characteristics and satiety expectations. Results In study one, participants were able to perceive small changes in drink viscosity that were strongly related to the actual viscosity of the drinks. In study two, the thick versions of the drink were expected to be more filling and have a greater expected satiety value, independent of the drink’s actual energy content. A creamy flavour enhanced the extent to which the drink was expected to be filling, but did not affect its expected satiety. Conclusions These results indicate that subtle manipulations of texture and creamy flavour can increase expectations that a fruit yogurt drink will be filling and suppress hunger, irrespective of the drink’s energy content. A thicker texture enhanced expectations of satiety to a greater extent than a creamier flavour, and may be one way to improve the anticipated satiating value of energy-containing beverages.

  2. Synergetic Effect of Ti3+and Oxygen Doping on Enhancing Photoelectrochemical and Photocatalytic Properties of TiO2/g-C3N4Heterojunctions.

    Science.gov (United States)

    Li, Kai; Huang, Zhenyu; Zeng, Xiaoqiao; Huang, Baibiao; Gao, Shanmin; Lu, Jun

    2017-04-05

    To improve the utilization of visible light and reduce photogenerated electron/hole recombination, Ti 3+ self-doped TiO 2 /oxygen-doped graphitic carbon nitride (Ti 3+ -TiO 2 /O-g-C 3 N 4 ) heterojunctions were prepared via hydrothermal treatment of a mixture of g-C 3 N 4 and titanium oxohydride sol obtained from the reaction of TiH 2 with H 2 O 2 . In this way, exfoliated O-g-C 3 N 4 and Ti 3+ -TiO 2 nanoparticles were obtained. Simultaneously, strong bonding was formed between Ti 3+ -TiO 2 nanoparticles and exfoliated O-g-C 3 N 4 during the hydrothermal process. Charge transfer and recombination processes were characterized by transient photocurrent responses, electrochemical impedance test, and photoluminescence spectroscopy. The photocatalytic performances were investigated through rhodamine B degradation test under an irradiation source based on 30 W cold visible-light-emitting diode. The highest visible-light photoelectrochemical and photocatalytic activities were observed from the heterojunction with 1:2 mass ratio of Ti 3+ -TiO 2 to O-g-C 3 N 4 . The photodegradation reaction rate constant based on this heterojuction is 0.0356 min -1 , which is 3.87 and 4.56 times higher than those of pristine Ti 3+ -TiO 2 and pure g-C 3 N 4 , respectively. The remarkably high photoelectrochemical and photocatalytic performances of the heterojunctions are mainly attributed to the synergetic effect of efficient photogenerated electron-hole separation, decreased electron transfer resistance from interfacial chemical hydroxy residue bonds, and oxidizing groups originating from Ti 3+ -TiO 2 and O-g-C 3 N 4 .

  3. Nanomechanical properties of TiCN and TiCN/Ti coatings on Ti prepared by Filtered Arc Deposition

    International Nuclear Information System (INIS)

    Sun, Yong; Lu, Cheng; Yu, Hailiang; Kiet Tieu, A.; Su, Lihong; Zhao, Yue; Zhu, Hongtao; Kong, Charlie

    2015-01-01

    Monolayer TiCN and multilayer TiCN/Ti coatings were deposited on the surface of Ti using the Filtered Arc Deposition System (FADS). Nanoindentation tests were performed on both coatings. The multilayer TiCN/Ti coating exhibited better ductility than the monolayer TiCN coating. The lattice constants of the coatings were characterized by X-ray diffraction. Transmission Electron Microscopy (TEM) was used to investigate the fracture behavior of the coatings. Inter-columnar, inclined and lateral cracks were found to be the dominant crack modes in the monolayer TiCN coatings while small bending crack and radial crack were the dominant crack modes in the multilayer TiCN/Ti coatings. The Finite Element Method (FEM) was used to simulate the indentation process. It was found that the Ti interlayer in the multilayer TiCN/Ti coating could efficiently suppress the fracture, which is responsible for the improved ductility of the multilayer TiCN/Ti coating

  4. Nanomechanical properties of TiCN and TiCN/Ti coatings on Ti prepared by Filtered Arc Deposition

    Energy Technology Data Exchange (ETDEWEB)

    Sun, Yong [School of Mechanical, Materials & Mechatronic Engineering, University of Wollongong, Wollongong, NSW 2522 (Australia); Lu, Cheng, E-mail: chenglu@uow.edu.au [School of Mechanical, Materials & Mechatronic Engineering, University of Wollongong, Wollongong, NSW 2522 (Australia); Yu, Hailiang [School of Mechanical, Materials & Mechatronic Engineering, University of Wollongong, Wollongong, NSW 2522 (Australia); School of Mechanical Engineering, Shenyang University, Shenyang 110044 (China); Kiet Tieu, A.; Su, Lihong; Zhao, Yue; Zhu, Hongtao [School of Mechanical, Materials & Mechatronic Engineering, University of Wollongong, Wollongong, NSW 2522 (Australia); Kong, Charlie [Electron Microscope Unit, University of New South Wales, Sydney, NSW 2052 (Australia)

    2015-02-11

    Monolayer TiCN and multilayer TiCN/Ti coatings were deposited on the surface of Ti using the Filtered Arc Deposition System (FADS). Nanoindentation tests were performed on both coatings. The multilayer TiCN/Ti coating exhibited better ductility than the monolayer TiCN coating. The lattice constants of the coatings were characterized by X-ray diffraction. Transmission Electron Microscopy (TEM) was used to investigate the fracture behavior of the coatings. Inter-columnar, inclined and lateral cracks were found to be the dominant crack modes in the monolayer TiCN coatings while small bending crack and radial crack were the dominant crack modes in the multilayer TiCN/Ti coatings. The Finite Element Method (FEM) was used to simulate the indentation process. It was found that the Ti interlayer in the multilayer TiCN/Ti coating could efficiently suppress the fracture, which is responsible for the improved ductility of the multilayer TiCN/Ti coating.

  5. Multi-phase EBSD mapping and local texture analysis in NdFeB sintered magnets

    Energy Technology Data Exchange (ETDEWEB)

    Woodcock, T.G., E-mail: t.woodcock@ifw-dresden.de [IFW Dresden, Institute for Metallic Materials, PO Box 270116, 01171 Dresden (Germany); Gutfleisch, O. [IFW Dresden, Institute for Metallic Materials, PO Box 270116, 01171 Dresden (Germany)

    2011-02-15

    A combination of electron backscatter diffraction and energy-dispersive X-ray spectroscopy has been used to identify the crystal structure and composition of all the phases present in commercially available NdFeB sintered magnets and to map their spatial distribution. The Nd{sub 2}Fe{sub 14}B and NdO grains were shown to have low defect densities. The fcc Nd-rich and Nd{sub 2}O{sub 3} grains had intra-grain misorientation angles of up to 14{sup o}, which was shown to be due to defects. Large numbers ({approx}100) of data points for each phase were used to study texture in the NdO, Nd{sub 2}O{sub 3} and Nd{sub 2}Fe{sub 14}B phases. The Nd{sub 2}Fe{sub 14}B grains exhibited a <0 0 1> fibre texture. The Nd oxide phases showed no strong texture, which implied that no strongly preferred orientation relationships between those phases and Nd{sub 2}Fe{sub 14}B exist. The result was shown to be valid for optimally annealed samples exhibiting high coercivity and as-sintered samples exhibiting low coercivity.

  6. Texture Analysis using The Neutron Diffraction Method on The Non Standardized Austenitic Steel Process by Machining,Annealing, and Rolling

    Directory of Open Access Journals (Sweden)

    Tri Hardi Priyanto

    2016-04-01

    Full Text Available Austenitic steel is one type of stainless steel which is widely used in the industry. Many studies on  austenitic stainless steel have been performed to determine the physicalproperties using various types of equipment and methods. In this study, the neutron diffraction method is used to characterize the materials which have been made from  minerals extracted from the mines in Indonesia. The materials consist of a granular ferro-scrap, nickel, ferro-chrome, ferro-manganese, and ferro-silicon added with a little titanium. Characterization of the materials was carried out in threeprocesses, namely: machining, annealing, and rolling. Experimental results obtained from the machining process generally produces a texture in the 〈100〉direction. From the machining to annealing process, the texture index decreases from 3.0164 to 2.434.Texture strength in the machining process (BA2N sample is  8.13 mrd and it then decreases to 6.99 in the annealing process (A2DO sample. In the annealing process the three-component texture appears, cube-on-edge type texture{110}〈001〉, cube-type texture {001}〈100〉, and brass-type {110}〈112〉. The texture is very strong leading to the direction of orientation {100}〈001〉, while the {011}〈100〉is weaker than that of the {001}, and texture withorientation {110}〈112〉is weak. In the annealing process stress release occurred, and this was shown by more randomly pole compared to stress release by the machining process. In the rolling process a brass-type texture{110}〈112〉with a spread towards the goss-type texture {110}〈001〉 appeared,  and  the  brass  component  is markedly  reinforced  compared  to  the undeformed state (before rolling. Moreover, the presence of an additional {110} component was observed at the center of the (110 pole figure. The pole density of three components increases withthe increasing degree of thickness reduction. By increasing degrees

  7. Strong saturable absorption of black titanium oxide nanoparticle films

    Science.gov (United States)

    Zhang, Rong-Fang; Guo, Deng-Zhu; Zhang, Geng-Min

    2017-12-01

    Nonlinear optical materials with strong saturable absorption (SA) properties play an essential role in passive mode-locking generation of ultrafast lasers. Here we report black TiO2-x nanoparticles are promising candidate for such an application. Black TiO2-x nanoparticles are synthesized by using cathodic plasma electrolysis, and nanoparticle films are deposited on optical glass plates via natural sedimentation and post annealing. Characterization of the samples with TEM, SEM, XRD and XPS reveal that nanoparticles have diameters of 8-70 nm, and are in polycrystalline structure and co-existence of anatase, rutile and abundant oxygen-deficient phases. Optical transmittance and reflectance measurements with a UV/VIS/NIR spectrophotometer evidence an excellent wide-spectral optical absorption property. The nonlinear optical properties of the samples were measured by using open-aperture Z-scan technique with picosecond 532-nm laser, and verified by direct transmission measurements using nanosecond 1064-nm laser. Strong SA behavior was detected, and the nonlinear absorption coefficient is as high as β = - 4.9 × 10-8 m/W, at least two orders larger than most previous reports on ordinary TiO2. The strong SA behaviors are ascribed to the existence of plenty surface states and defect states within bandgap, and the relaxation rates of electrons from upper energy levels to lower ones are much slower than excitation rates.

  8. The Microstructural, Textural, and Mechanical Properties of Extruded and Equal Channel Angularly Pressed Mg-Li-Zn Alloys

    Science.gov (United States)

    Karami, M.; Mahmudi, R.

    2013-08-01

    The microstructural and textural evolution of the Mg-6Li-1Zn (LZ61), Mg-8Li-1Zn (LZ81), and Mg-12Li-1Zn (LZ121) alloys were investigated in the as-extruded condition and after being equal channel angularly pressed (ECAPed) for one, two, and four passes. The shear punch testing technique was employed to evaluate the room-temperature mechanical properties of the extruded and ECAPed materials. Microstructural analysis revealed that the grain refinement in both LZ61 and LZ121 alloys could be achieved after multipass ECAP through the continuous dynamic recovery and recrystallization process. For the LZ81 alloy, however, the occurrence of Li loss in the four passes of ECAP condition partly offsets the grain refining effect of the ECAP process by increasing grain size and volume fraction of the α phase. Textural studies in both LZ61 and LZ81 alloys indicated that the developed fiber texture after extrusion could be replaced by a typical ECAP texture, where the basal planes are mainly inclined about 45 deg to the extrusion axis. The increased volume fraction of the β phase in LZ81 significantly affected the α-phase texture by decreasing the intensity of the maximum orientations of the basal and prismatic planes in all deformation conditions, compared with the LZ61 alloy. It was also observed that the abnormal grain growth might be promoted by the strong texture developed in the extruded LZ121 alloy. This texture became more randomized when the number of ECAP passes increased. The SPT results showed that the shear yield stress, ultimate shear strength and normalized displacement in all studied alloys were improved through the grain refinement strengthening caused by ECAP. It was also established that increasing Li content decreased the shear strength and enhanced the shear elongation in all deformation conditions.

  9. A hydrodynamic approach to cosmology - Texture-seeded cold dark matter and hot dark matter cosmogonies

    Science.gov (United States)

    Cen, R. Y.; Ostriker, J. P.; Spergel, D. N.; Turok, N.

    1991-01-01

    Hydrodynamical simulations of galaxy formation in a texture-seeded cosmology are presented, with attention given to Omega = 1 galaxies dominated by both hot dark matter (HDM) and cold dark matter (CDM). The simulations include both gravitational and hydrodynamical physics with a detailed treatment of collisional and radiative thermal processes, and use a cooling criterion to estimate galaxy formation. Background radiation fields and Zel'dovich-Sunyaev fluctuations are explicitly computed. The derived galaxy mass function is well fitted by the observed Schechter luminosity function for a baryonic M/L of 3 and total M/L of 60 in galaxies. In both HDM and CDM texture scenarios, the 'galaxies' and 'clusters' are significantly more strongly correlated than the dark matter due to physical bias processes. The slope of the correlation function in both cases is consistent with observations. In contrast to Gaussian models, peaks in the dark matter density distributrion are less correlated than average.

  10. Effect of saliva on physical food properties in fat texture perception.

    Science.gov (United States)

    Kupirovič, Urška Pivk; Elmadfa, Ibrahim; Juillerat, Marcel-Alexandre; Raspor, Peter

    2017-04-13

    Sensory properties of food drive our food choices and it is generally accepted that lipids greatly contribute to the sensory properties of many foods and consequently to eating pleasure. Many studies have investigated the mechanisms of the fat perception. Unfortunately they used a variety of methods and products, thereby making generalization very difficult. The mechanism of fat perception in oral cavity is combined of several processes. Lipid composition and its properties strongly influence food structure. During consumption food is exposed to a range of in-mouth processing steps. Oral sensation of fat texture changes with time, from a first bite to chewing, while mixing with saliva, up to swallowing and even after swallowing. The present work reviews many aspects of fat texture perception from physical chemistry to physiology. Understanding the underlying mechanisms of in-mouth lipid processing would provide new concepts to produce low-fat food products with full-fat perception.

  11. Correlation of normal and superconducting transport properties on textured Bi-2212 ceramic thin rods

    International Nuclear Information System (INIS)

    Natividad, E.; Castro, M.; Burriel, R.; Diez, J.C.; Navarro, R.; Angurel, L.A.

    2002-01-01

    The electric and thermal properties well above and below T c of Bi-2212 textured ceramics have been correlated through a careful analysis of the microstructure and the transport measurements. Thin rods with the same Bi-2122 stoichiometry and textured by a laser floating zone technique have been studied with that aim. By changing the growth parameters, it has been possible to produce strong changes in microstructure and critical current density, J c , with small variations in the thermal conductivity. The existence of phase and composition gradients across the thin rods, which explains the variations of T c , makes the relation difficult between the normal state resistivity and J c (77 K). A simple qualitative analysis that takes into account the observed microstructure has been developed to correlate the electric transport properties in the normal and in the superconducting states. (author)

  12. Aural analysis of image texture via cepstral filtering and sonification

    Science.gov (United States)

    Rangayyan, Rangaraj M.; Martins, Antonio C. G.; Ruschioni, Ruggero A.

    1996-03-01

    Texture plays an important role in image analysis and understanding, with many applications in medical imaging and computer vision. However, analysis of texture by image processing is a rather difficult issue, with most techniques being oriented towards statistical analysis which may not have readily comprehensible perceptual correlates. We propose new methods for auditory display (AD) and sonification of (quasi-) periodic texture (where a basic texture element or `texton' is repeated over the image field) and random texture (which could be modeled as filtered or `spot' noise). Although the AD designed is not intended to be speech- like or musical, we draw analogies between the two types of texture mentioned above and voiced/unvoiced speech, and design a sonification algorithm which incorporates physical and perceptual concepts of texture and speech. More specifically, we present a method for AD of texture where the projections of the image at various angles (Radon transforms or integrals) are mapped to audible signals and played in sequence. In the case of random texture, the spectral envelopes of the projections are related to the filter spot characteristics, and convey the essential information for texture discrimination. In the case of periodic texture, the AD provides timber and pitch related to the texton and periodicity. In another procedure for sonification of periodic texture, we propose to first deconvolve the image using cepstral analysis to extract information about the texton and horizontal and vertical periodicities. The projections of individual textons at various angles are used to create a voiced-speech-like signal with each projection mapped to a basic wavelet, the horizontal period to pitch, and the vertical period to rhythm on a longer time scale. The sound pattern then consists of a serial, melody-like sonification of the patterns for each projection. We believe that our approaches provide the much-desired `natural' connection between the image

  13. Surface modification of Ti6Al4V by nanosecond laser ablation for biomedical applications

    Science.gov (United States)

    Fiorucci, M. P.; López, A. J.; Ramil, A.

    2015-04-01

    This paper presents the surface textured process of biometal Ti6Al4V by means of 355 nm Nd:YVO4 nanosecond laser. Our target is to create structures with sizes which favour osseointegration. In this work a pattern of parallel grooves was generated after a deep analysis of the irradiation parameters involved. Ablation modifies not only the topography but also physico-chemical properties of the metal surface. Changes in the morphology and the physico-chemical state of the laser induced groove pattern were studied by a scanning electron microscopy, X-ray diffraction and X- ray photoelectron spectroscopy, which revealed, among others, an increase of micro roughness and a oxide layer entirely formed by TiO2, which can improve biocompatibility properties of the textured surface.

  14. Variable range hopping in TiO2 insulating layers for oxide electronic devices

    Directory of Open Access Journals (Sweden)

    Y. L. Zhao

    2012-03-01

    Full Text Available TiO2 thin films are of importance in oxide electronics, e.g., Pt/TiO2/Pt for memristors and Co-TiO2/TiO2/Co-TiO2 for spin tunneling devices. When such structures are deposited at a variety of oxygen pressures, how does TiO2 behave as an insulator? We report the discovery of an anomalous resistivity minimum in a TiO2 film at low pressure (not strongly dependent on deposition temperature. Hall measurements rule out band transport and in most of the pressure range the transport is variable range hopping (VRH though below 20 K it was difficult to differentiate between Mott and Efros-Shklovskii's (ES mechanism. Magnetoresistance (MR of the sample with lowest resistivity was positive at low temperature (for VRH but negative above 10 K indicating quantum interference effects.

  15. Thermodynamic and mechanical properties of TiC from ab initio calculation

    International Nuclear Information System (INIS)

    Dang, D. Y.; Fan, J. L.; Gong, H. R.

    2014-01-01

    The temperature-dependent thermodynamic and mechanical properties of TiC are systematically investigated by means of a combination of density-functional theory, quasi-harmonic approximation, and thermal electronic excitation. It is found that the quasi-harmonic Debye model should be pertinent to reflect thermodynamic properties of TiC, and the elastic properties of TiC decease almost linearly with the increase of temperature. Calculations also reveal that TiC possesses a pronounced directional pseudogap across the Fermi level, mainly due to the strong hybridization of Ti 3d and C 2p states. Moreover, the strong covalent bonding of TiC would be enhanced (reduced) with the decrease (increase) of temperature, while the change of volume (temperature) should have negligible effect on density of states at the Fermi level. The calculated results agree well with experimental observations in the literature.

  16. A double Fe-Ti oxide and Fe-sulphide liquid immiscibility in the Itsindro Gabbro Complex, Madagascar

    Science.gov (United States)

    Augé, Thierry; Bailly, Laurent; Roig, Jean-Yves

    2017-11-01

    The petrology and mineralogy of the Itsindro complex in south-central Madagascar has been investigated through samples obtained from the 320.7 m-deep Lanjanina borehole. The section consists of a 254 m-thick pyroxenite unit with interbedded gabbro layers that overlies a gabbro unit and is itself overlain by a 19 m-thick granite unit. Most of the structures are sub-horizontal. A weak magmatic layering is locally observed but at the scale of the core, the intrusion does not appear to be a layered complex. Pyroxenite and gabbro show a systematic disseminated mineralization consisting of Fe-Ti-P oxides and Fe-(Cu-Ni) sulphides that takes the form of ilmenite-titanomagnetite ± apatite and pyrrhotite ± chalcopyrite ± pentlandite. In the upper zone, from 90 to 72 m, sub-massive centimetre-to decimetre-sized layers of oxides and sulphides comprise a total of 16 m of sub-massive sulphide (the main mineralized zone). In this mineralized zone the oxide/sulphide ratio is close to 1/1. The sulphide is strongly dominated by pyrrhotite, which may locally contain inclusions of molybdenite crystals with the Re sulphide rheniite (ReS2). Oxides are generally euhedral, included in or attached to the Fe-sulphide, and also locally form sub-massive centimetre-sized bands. Apatite as a cumulus phase is ubiquitous. Locally it may account for 30% of the ore-rich samples and some samples consist of apatite-Fe-Ti oxides-Fe-Cu-Ni sulphides with virtually no silicate. Apatite is the main REE carrier but the total REE content remains low (<90 ppm). Mineral compositions and whole rock geochemistry indicate that the rocks are highly differentiated, and in spite of a relatively limited thickness, the differentiation process is observed. Two zones can be distinguished: from the bottom to 162.8 m we see a decrease in the Mg number of olivine and pyroxene, and a drop in TiO2 and Al2O3 for the latter. A reverse trend is then observed within the pyroxenite unit from the 162.8 m level upwards. The

  17. Microstructure and texture evolution of ultra-thin grain-oriented silicon steel sheet fabricated using strip casting and three-stage cold rolling method

    Energy Technology Data Exchange (ETDEWEB)

    Song, Hong-Yu; Liu, Hai-Tao, E-mail: liuht@ral.neu.edu.cn; Wang, Yin-Ping; Wang, Guo-Dong

    2017-03-15

    A 0.1 mm-thick grain-oriented silicon steel sheet was successfully produced using strip casting and three-stage cold rolling method. The microstructure, texture and inhibitor evolution during the processing was briefly analyzed. It was found that Goss texture was absent in the hot rolled sheet because of the lack of shear deformation. After normalizing, a large number of dispersed MnS precipitates with the size range of 15–90 nm were produced. During first cold rolling, dense shear bands were generated in the deformed ferrite grains, resulting in the intense Goss texture after first intermediate annealing. The microstructure was further refined and homogenized during the subsequent cold rolling and annealing processes. After primary recrystallization annealing, a homogeneous microstructure consisting of fine and equiaxed grains was produced while the associated texture was characterized by a strong γ-fiber texture. Finally, a complete secondary recrystallization microstructure consisting of entirely large Goss grains was produced. The magnetic induction B{sub 8} and iron loss P{sub 10/400} was 1.79 T and 6.9 W/kg, respectively. - Highlights: • Ultra-thin grain-oriented silicon steel was produced by strip casting process. • Microstructure, texture and inhibitor evolution was briefly investigated. • Goss texture was absent in primary recrystallization annealed sheet. • MnS precipitates with a size range of 15–90 nm formed after normalizing. • A complete secondary recrystallization microstructure was produced.

  18. Microstructure, Texture Evolution and Mechanical Properties of VT3-1 Titanium Alloy Processed by Multi-Pass Drawing and Subsequent Isothermal Annealing

    Directory of Open Access Journals (Sweden)

    Xiaofei Lei

    2017-04-01

    Full Text Available Microstructure, texture evolution, and mechanical properties of Ti–6Al–1.5Cr–2.5Mo–0.5Fe–0.3Si (VT3-1 titanium alloy processed by multi-pass drawing and subsequent isothermal annealing were systematically investigated. A fiber-like microstructure is formed after warm drawing at 760 °C with 60% area reduction. After isothermal annealing, the samples deformed to different amounts of area reduction show a similar volume fraction (80% of α phase, while the sample deformed to 60% exhibits a homogeneous microstructure with a larger grain size (5.8 μm. The major texture component of α phase developed during warm drawing is centered at a position of {φ1 = 10°, φ = 65°, φ2 = 0°}. The textures for annealed samples are almost along the orientation of original deformation textures and show significant increases in orientation density and volume fraction compared with their deformed states. In addition, for the drawn samples, the ultimate tensile strength increases but the ductility decreases with increasing drawing deformation. A negative slope of yield strength of annealed samples versus grain size (d−1/2 is found due to the difference between texture softening for as-rolled + annealed state and texture hardening for drawn + annealed state. The mechanical properties of annealed samples are found to be strongly dependent on grain size and texture, resulting in the balance of the strength and ductility.

  19. Yttrium deposition on mesoporous TiO 2: textural design and UV ...

    Indian Academy of Sciences (India)

    M L Ojeda1 C Velasquez1 V Renteria1 A Campero2 M A García-Sánchez2 F Rojas2. Centro de Investigación en Nanociencias y Nanotecnología, Universidad de Guadalajara, Universitario de los Valles, CP 46600 Ameca, Jalisco, México; Departamento de Química, Universidad Autónoma Metropolitana-Iztapalapa, ...

  20. Grain growth kinetics of textured-BaTiO3 ceramics

    Indian Academy of Sciences (India)

    Author Affiliations. Fang Fu1 Jiwei Zhai2 Zhengkui Xu3 Bo Shen2 Xi Yao2. Luoyang Institute of Science and Technology, Luoyang 471023, China; Functional Materials Research Laboratory, Tongji University, Shanghai 200092, China; Department of Physics and Materials Science, City University of Hong Kong, Hong Kong ...

  1. Influence of Texture on Impact Toughness of Ferritic Fe-20Cr-5Al Oxide Dispersion Strengthened Steel

    Science.gov (United States)

    Sánchez-Gutiérrez, Javier; Chao, Jesus; Vivas, Javier; Galvez, Francisco; Capdevila, Carlos

    2017-01-01

    Fe-based oxide dispersion strengthened (ODS) steels are oriented to applications where high operating temperatures and good corrosion resistance is paramount. However, their use is compromised by their fracture toughness, which is lower than other competing ferritic-martenstic steels. In addition, the route required in manufacturing these alloys generates texture in the material, which induces a strong anisotropy in properties. The V-notched Charpy tests carried out on these alloys, to evaluate their impact toughness, reveal that delaminations do not follow the path that would be expected. There are many hypotheses about what triggers these delaminations, but the most accepted is that the joint action of particles in the grain boundaries, texture induced in the manufacturing process, and the actual microstructure of these alloys are responsible. In this paper we focused on the actual role of crystallographic texture on impact toughness in these materials. A finite elements simulation is carried out to solely analyze the role of texture and eliminate other factors, such as grain boundaries and the dispersed particles. The work allows us to conclude that crystallographic texture plays an important role in the distribution of stresses in the Charpy specimens. The observed delaminations might be explained on the basis that the crack in the grain, causing the delamination, is directly related to the shear stresses τ12 on both sides of the grain boundary, while the main crack propagation is a consequence of the normal stress to the crack. PMID:28773104

  2. Formation and texture of palladium germanides studied by in situ X-ray diffraction and pole figure measurements

    Energy Technology Data Exchange (ETDEWEB)

    Geenen, F.A., E-mail: Filip.Geenen@UGent.be [Ghent University, Department of Solid-State Sciences, Krijgslaan 281 (S1), 9000 Gent (Belgium); Knaepen, W.; De Keyser, K. [Ghent University, Department of Solid-State Sciences, Krijgslaan 281 (S1), 9000 Gent (Belgium); Opsomer, K. [Interuniversitair Micro-Electronica Centrum (IMEC), Kapeldreef 75, 3001 Leuven (Belgium); Vanmeirhaeghe, R.L. [Ghent University, Department of Solid-State Sciences, Krijgslaan 281 (S1), 9000 Gent (Belgium); Jordan-Sweet, J.; Lavoie, C. [IBM T.J. Watson Research Center, Yorktown (United States); Detavernier, C. [Ghent University, Department of Solid-State Sciences, Krijgslaan 281 (S1), 9000 Gent (Belgium)

    2014-01-31

    The solid state reaction between 30 nm Pd films and various Ge substrates (Ge(100), Ge(111), polycrystalline Ge and amorphous Ge) was studied by means of in situ X-ray diffraction and in situ sheet resistance measurements. The reported phase sequence of Pd{sub 2}Ge followed by PdGe was verified on all substrates. The texture of the germanides was analysed by pole figure measurements on samples quenched in the Pd{sub 2}Ge and in the PdGe phase on both Ge(100) and (111) substrates. We report an epitaxial growth of Pd{sub 2}Ge on Ge(111) and on Ge(100). The formed PdGe has an axiotaxial alignment on Ge(111). On Ge(100), the axiotaxial texture is observed together with a fibre texture. The higher formation temperature of PdGe on Ge(111) could be related to the epitaxial alignment of the Pd{sub 2}Ge parent phase on Ge(111). - Highlights: • Solid-state reaction is studied on a Pd film with Ge substrates. • Pd2Ge grains have an epitaxial texture on both Ge 100 and Ge 111. • PdGe grains are found to grow with an axiotaxial texture. • Retarded PdGe formation on Ge111 is related with strong epitaxy of Pd2Ge.

  3. Influence of Texture on Impact Toughness of Ferritic Fe-20Cr-5Al Oxide Dispersion Strengthened Steel.

    Science.gov (United States)

    Sánchez-Gutiérrez, Javier; Chao, Jesus; Vivas, Javier; Galvez, Francisco; Capdevila, Carlos

    2017-07-03

    Fe-based oxide dispersion strengthened (ODS) steels are oriented to applications where high operating temperatures and good corrosion resistance is paramount. However, their use is compromised by their fracture toughness, which is lower than other competing ferritic-martenstic steels. In addition, the route required in manufacturing these alloys generates texture in the material, which induces a strong anisotropy in properties. The V-notched Charpy tests carried out on these alloys, to evaluate their impact toughness, reveal that delaminations do not follow the path that would be expected. There are many hypotheses about what triggers these delaminations, but the most accepted is that the joint action of particles in the grain boundaries, texture induced in the manufacturing process, and the actual microstructure of these alloys are responsible. In this paper we focused on the actual role of crystallographic texture on impact toughness in these materials. A finite elements simulation is carried out to solely analyze the role of texture and eliminate other factors, such as grain boundaries and the dispersed particles. The work allows us to conclude that crystallographic texture plays an important role in the distribution of stresses in the Charpy specimens. The observed delaminations might be explained on the basis that the crack in the grain, causing the delamination, is directly related to the shear stresses τ 12 on both sides of the grain boundary, while the main crack propagation is a consequence of the normal stress to the crack.

  4. Effect of nano-CeO 2 on microstructure properties of TiC/TiN+TiCN ...

    Indian Academy of Sciences (India)

    TiC/TiN+TiCN-reinforced composite coatings were fabricated on Ti–6Al–4V alloy by laser cladding, which improved surface performance of the substrate. ... X-ray diffraction results indicated that Al3Ti+TiC/TiN+nano-CeO2 laser-cladded coating consisted of Ti3Al, TiC, TiN, Ti2Al20Ce, TiC0.3N0.7, Ce(CN)3 and CeO2, this ...

  5. Effect of annealing temperature on microstructure and superelastic properties of a Ti-18Zr-4.5Nb-3Sn-2Mo alloy.

    Science.gov (United States)

    Fu, Jie; Kim, Hee Young; Miyazaki, Shuichi

    2017-01-01

    In this study a new superelastic Ti-18Zr-4.5Nb-3Sn-2Mo alloy was prepared by adding 2at% of Mo as a substitute for Nb to the Ti-18Zr-11Nb-3Sn alloy, and heat treatment at different temperatures was conducted. The temperature dependence of superelasticity and annealing texture was investigated. Texture showed a dependence of annealing temperature: the specimen annealed at 923K for 0.3ks exhibited {113} β β type texture which was similar to the deformation texture, while specimens annealed at 973, 1073K, and 1173K showed {001} β β type recrystallization texture which was preferable for recovery strain. The largest recovery strain of 6.2%, which is the same level as that of the Ti-18Zr-11Nb-3Sn alloy, was obtained in the specimen annealed at 1173K for 0.3ks due to the well-developed {001} β β type recrystallization texture. The Ti-18Zr-3Nb-3Sn-2Mo alloy presented a higher tensile strength compared with the Ti-18Zr-11Nb-3Sn alloy when heat treated at 1173K for 0.3ks, which was due to the solid solution strengthening effect of Mo. Annealing at 923K for 0.3ks was effective in obtaining a good combination of a high strength as 865MPa and a large recovery strain as 5.6%. The high recovery strain was due to the high stress at which the maximum recovery stain was obtained which was attributed to the small grain size formed at low annealing temperature. Copyright © 2016 Elsevier Ltd. All rights reserved.

  6. M-HinTS: Mimicking Humans in Texture Sorting

    NARCIS (Netherlands)

    van den Broek, Egon; Rogowitz, Bernice E.; van Rikxoort, Eva M.; Pappas, Thrasyvoulos N.; Kok, Thijs; Daly, Scott J.; Schouten, Theo E.

    2006-01-01

    Various texture analysis algorithms have been developed the last decades. However, no computational model has arisen that mimics human texture perception adequately. In 2000, Payne, Hepplewhite, and Stoneham and in 2005, Van Rikxoort, Van den Broek, and Schouten achieved mappings between humans and

  7. Fast color/texture segmentation for outdoor robots

    DEFF Research Database (Denmark)

    Blas, Morten Rufus; Agrawal, Motilal; Sundaresan, Aravind

    2008-01-01

    We present a fast integrated approach for online segmentation of images for outdoor robots. A compact color and texture descriptor has been developed to describe local color and texture variations in an image. This descriptor is then used in a two-stage fast clustering framework using K-means...

  8. Texturized pinto bean protein fortification in straight dough bread formulation

    Science.gov (United States)

    Pinto beans were milled and then air-classified to obtain a raw high protein fraction (RHPF) followed by extrusion to texturize the protein fraction. The texturized high protein fraction (THPF) was then milled to obtain flour, and combined with wheat flour at 5%, 10%, and 15% levels to make bread. A...

  9. Stone -Cech compactifications of ditopological texture spaces | Ugur ...

    African Journals Online (AJOL)

    Then (S, S) is called a texture space. In this paper, a suitable evaluation difunction is defined and an approach for the construction of the Stone- Cech compactification of ditopological texture spaces is given. It is also shown that the Stone- Cech compactification of a topological space can be obtained using highly economic ...

  10. Synthesis of nano-textured biocompatible scaffolds from chicken eggshells

    International Nuclear Information System (INIS)

    Asghar, Waseem; Ilyas, Azhar; Sankaran, Jeyantt; Wan Yuan; Iqbal, Samir M; Kim, Young-Tae

    2012-01-01

    Cell adhesion, morphology and growth are influenced by surface topography at nano and micrometer scales. Nano-textured surfaces are prepared using photolithography, plasma etching and long polymer chemical etching which are cost prohibitive and require specialized equipment. This article demonstrates a simple approach to synthesize nano-textured scaffolds from chicken eggshells. Varieties of pattern are made on the eggshells like micro-needle forests and nanopores, giving very uniform nano-textures to the surfaces. The surfaces are characterized for chemical composition and crystal phase. The novel patterns are transferred to PDMS surfaces and the nano-textured PDMS surfaces are used to study the effect of texturing on human fibroblast cell growth and attachment. The effects of surface topographies, along with laminin coating on cell cultures, are also studied. We find an exciting phenomenon that the initial seeding density of the fibroblast cells affects the influence of the nano-texturing on cell growth. These nano-textured surfaces give 16 times more fibroblast growth when compared to flat PDMS surfaces. The novel nano-textured patterns also double the laminin adsorption on PDMS. (paper)

  11. Design of textured surfaces for super-hydrophobicity

    Indian Academy of Sciences (India)

    Although the Cassie–Baxter and Wenzel equations predict contact angles for relative dimensions of micro-pillars on textured surfaces, the absolute pillar dimensions are determined by trial and error. Alternatively, geometries of natural super-hydrophobic surfaces are often imitated to design textured surfaces. Knowing the ...

  12. Quantitative comparison between simulated and experimental FCC rolling textures

    DEFF Research Database (Denmark)

    Wronski, M.; Wierzbanowski, K.; Leffers, Torben

    2015-01-01

    The degree of similarity between simulated and experimental fcc rolling textures is characterized by a single scalar parameter. The textures are simulated with a relatively simple and efficient 1-point model which allows us to vary the strength of the interaction between the grains and the surrou...

  13. Surface texturing of crystalline silicon and effective area measurement

    Science.gov (United States)

    Sun, Tietun; Chen, Dong; Chui, Rongqiang

    2000-11-01

    In this paper, the surface area of solar cell is determined by the capacitance measurements of MOS structure. The texture etching technology can be controlled according to the change of silicon surface area, furthermore, the textured silicon surface and interface characteristic of solar cell can be studied by measuring the relationship of capacitance and voltage for MOS structure.

  14. Shape and Texture Based Classification of Fish Species

    DEFF Research Database (Denmark)

    Larsen, Rasmus; Ólafsdóttir, Hildur; Ersbøll, Bjarne Kjær

    2009-01-01

    , and a few features including the eye and backbone contour were also annotated. From these annotations an optimal MDL curve correspondence and a subsequent image registration were derived. We have analyzed a series of shape and texture and combined shape and texture modes of variation for their ability...

  15. Instrumental textural perception of food and comparative biomaterials

    Science.gov (United States)

    Texture is an important food quality attribute affecting consumer acceptance. Consumers characterize texture as either crispy or crunchy, and the moisture content and internal structure of the products are significant factors in its perception. Exposing an extruded corn snack (ECS), an extruded biod...

  16. Enhancement of Human Cheek Skin Texture by Acacia Nilotica Bark ...

    African Journals Online (AJOL)

    ... < 0.05) and the texture parameter of energy showed significant increase (p < 0.05). Conclusion: Our findings indicate that the cream containing 3 % Acacia nilotica bark extract possesses anti-aging effect and improves skin surface appearance.. Keywords: Acacia nilotica, Cream, Visioscan VC 98, Skin texture, Anti-aging ...

  17. Post tsunami rebuilding of beaches and the texture of sediments

    Digital Repository Service at National Institute of Oceanography (India)

    Loveson, V.J.; Gujar, A.R.; Rajamanickam, G.V.; Chandrasekar, N.; Manickaraj, D.S.; Chandrasekaran, R.; Chaturvedi, S.K.; Mahesh, R.; Josephine, P.J.; Deepa, V.; Sudha, V.; Sunderasen, D.

    and textural statistic studies. In view of the presence tsunami in between, the beach sand composition and texture have been drastically changed, the studies on beach re-building effort has been initiated in continuing the beach sand sample collection to 2006...

  18. Texture Segmentation Based on Gabor Filters and Neutrosophic Graph Cut

    OpenAIRE

    Akbulut, Y.; Sengur, Abdulkadir; Yanhui, Guo

    2015-01-01

    Image segmentation is the first step of image processing and image analysis. Texture segmentation is a challenging task in image segmentation applications. Neutrosophy hasanaturalabilitytohandletheindeterminateinformation.In this work, we investigate the texture image segmentation based on Gabor filters (GFs) and neutrosophic graph cut (NGC).

  19. Highly textured Gd2Zr2O7 films grown on textured Ni-5 at.%W substrates by solution deposition route: Growth, texture evolution, and microstructure dependency

    DEFF Research Database (Denmark)

    Yue, Zhao; Grivel, Jean-Claude; Napari, M.

    2012-01-01

    or crystallization in the thicker films. This work not only demonstrates a route for producing textured Gd2Zr2O7 buffer layers with dense structure directly on technical substrates, but also provides some fundamental understandings related to chemical solution derived films grown on metallic substrates.......Growth, texture evolution and microstructure dependency of solution derived Gd2Zr2O7 films deposited on textured Ni-5 at.%W substrates have been extensively studied. Influence of processing parameters, in particular annealing temperature and dwell time, as well as thickness effect on film texture...... the difference of interfacial energy along two directions in the anisotropic metallic substrate. Growth of Gd2Zr2O7 films displays an ultrafast kinetics under optimized conditions. Independency of sharp epitaxial (004) and polycrystalline (222) orientation is revealed from further synchrotron diffraction studies...

  20. Optical Properties of TiO2 Nanoparticles Dressed on MWCNT

    International Nuclear Information System (INIS)

    Mohamad, F.K.; Shahidan Radiman; Akrajas Ali Umar; Mohammad Hafizuddin Jumali

    2011-01-01

    Optical properties of TiO 2 nanoparticles dressed on the surface of Multi walled CNT (MWCNT) have been investigated. The samples were prepared using modified microwave method and characterized using TEM, XRD and UV-Vis spectroscopy. A clear interface between MWCNT and TiO 2 indicated strong attachment between these two nano structures. Significant change in absorption spectra proved the absorption wavelength and energy gap of TiO 2 nano structures can be controlled via dressing of MWCNT. (author)

  1. Theoretical study on the correlation between the nature of atomic Li intercalation and electrochemical reactivity in TiS2 and TiO2.

    Science.gov (United States)

    Kim, Yang-Soo; Kim, Hee-Jin; Jeon, Young-A; Kang, Yong-Mook

    2009-02-12

    The electronic structures of LiTiS(2) and LiTiO(2) (having alpha-NaFeO(2) structure) have been investigated using discrete variational Xalpha molecular orbital methods. The alpha-NaFeO(2) structure is the equilibrium structure for LiCoO(2), which is widely used as a commercial cathode material for lithium secondary batteries. This study especially focused on the charge state of Li ions and the magnitude of covalency around Li ions. When the average voltage of lithium intercalation was calculated using pseudopotential methods, the average intercalation voltage of LiTiO(2) (2.076 V) was higher than that of LiTiS(2) (1.958 V). This can be explained by the differences in Mulliken charge of lithium and the bond overlap population between the intercalated Li ions and anion in LiTiO(2) as well as LiTiS(2). The Mulliken charge, which is the ionicity of Li atom, was approximately 0.12 in LiTiS(2), and the bond overlap population (BOP) indicating the covalency between Ti and S was about 0.339. When compared with the BOP (0.6) of C-H, which is one of the most famous example of covalent bonding, the intercalated Li ions in LiTiS(2) tend to form a quite strong covalent bond with the host material. In contrast, the Mulliken charge of lithium was about 0.79, which means that Li is fully ionized and the BOP, the covalency between Ti and O, was 0.181 in LiTiO(2). Because of the high ionicity of Li and the weak covalency between Ti and the nearest anion, LiTiO(2) has a higher intercalation voltage than LiTiS(2).

  2. Low-order non-spatial effects dominate second-order spatial effects in the texture quantifier analysis of 18F-FDG-PET images.

    Directory of Open Access Journals (Sweden)

    Frank J Brooks

    Full Text Available There is increasing interest in applying image texture quantifiers to assess the intra-tumor heterogeneity observed in FDG-PET images of various cancers. Use of these quantifiers as prognostic indicators of disease outcome and/or treatment response has yielded inconsistent results. We study the general applicability of some well-established texture quantifiers to the image data unique to FDG-PET.We first created computer-simulated test images with statistical properties consistent with clinical image data for cancers of the uterine cervix. We specifically isolated second-order statistical effects from low-order effects and analyzed the resulting variation in common texture quantifiers in response to contrived image variations. We then analyzed the quantifiers computed for FIGOIIb cervical cancers via receiver operating characteristic (ROC curves and via contingency table analysis of detrended quantifier values.We found that image texture quantifiers depend strongly on low-effects such as tumor volume and SUV distribution. When low-order effects are controlled, the image texture quantifiers tested were not able to discern only the second-order effects. Furthermore, the results of clinical tumor heterogeneity studies might be tunable via choice of patient population analyzed.Some image texture quantifiers are strongly affected by factors distinct from the second-order effects researchers ostensibly seek to assess via those quantifiers.

  3. Influence of texture on fracture toughness of zircaloy cladding

    International Nuclear Information System (INIS)

    Grigoriev, V.; Andersson, Stefan

    1997-06-01

    The correlation between texture and fracture toughness of Zircaloy 2 cladding has been investigated in connection with axial cracks in fuel rods. The texture of the cladding determines the anisotropy of plasticity of the cladding which, in turn, should influence the strain conditions at the crack-tip. Plastic strains in the cladding under uniaxial tension were characterised by means of the anisotropy constants F, G and H calculated according to Hill's theory. Test temperatures between 20 and 300 deg C do not influence the F, G and H values. Any significant effect of hydrogen (about 500 wtppm) on the anisotropy constants F, G and H has not been revealed at a test temperature of 300 deg C. The results, obtained for stress-relieved and recrystallized cladding with different texture, show an obvious influence of texture on the fracture toughness of Zircaloy cladding. A higher fracture toughness has been found for cladding with more radial texture

  4. Texture of YBCO/Ag PIT-tapes

    DEFF Research Database (Denmark)

    Paturi, P.; Kulmala, T.; Raittila, J.

    2004-01-01

    with X-ray diffraction. A clear correlation between 1, and c-axis texture is found and even some evidence of ab-texturing in the very best tapes. Less texture is found when the middle of the filament is exposed by cutting the tape. This suggests that multifilament tapes with smaller filament cross......YBCO/Ag tapes prepared using nanosized YBCO powder are currently the best powder-in-tube YBCO tapes with their I-c = 5.02 A and J(c) = 3300 A/cm(2) in self-field and at 77 K. The texture of these tapes was studied by removing the silver with mercury and then measuring the texture of the surface...

  5. SHAPE FROM TEXTURE USING LOCALLY SCALED POINT PROCESSES

    Directory of Open Access Journals (Sweden)

    Eva-Maria Didden

    2015-09-01

    Full Text Available Shape from texture refers to the extraction of 3D information from 2D images with irregular texture. This paper introduces a statistical framework to learn shape from texture where convex texture elements in a 2D image are represented through a point process. In a first step, the 2D image is preprocessed to generate a probability map corresponding to an estimate of the unnormalized intensity of the latent point process underlying the texture elements. The latent point process is subsequently inferred from the probability map in a non-parametric, model free manner. Finally, the 3D information is extracted from the point pattern by applying a locally scaled point process model where the local scaling function represents the deformation caused by the projection of a 3D surface onto a 2D image.

  6. Phosphorous gettering in acidic textured multicrystalline solar cells

    Energy Technology Data Exchange (ETDEWEB)

    Montesdeoca-Santana, A. [Departamento de Fisica Basica, Universidad de La Laguna (ULL), Avenida Astrofisico Francisco Sanchez 2, 38206 La Laguna, S/C de Tenerife (Spain); Fraunhofer Institut fuer Solare Energiesysteme ISE, Laboratory and Servicecenter Gelsenkirchen, Auf der Reihe 2, 45884 Gelsenkirchen (Germany); Jimenez-Rodriguez, E.; Diaz-Herrera, B.; Hernandez-Rodriguez, C. [Departamento de Fisica Basica, Universidad de La Laguna (ULL), Avenida Astrofisico Francisco Sanchez 2, 38206 La Laguna, S/C de Tenerife (Spain); Gonzalez-Diaz, B. [Departamento de Fisica Basica, Universidad de La Laguna (ULL), Avenida Astrofisico Francisco Sanchez 2, 38206 La Laguna, S/C de Tenerife (Spain); Departamento de Energia Fotovoltaica, Instituto Tecnologico y de Energias Renovables. Poligono Industrial de Granadilla s/n, 38600 San Isidro-Granadilla de Abona, S/C de Tenerife (Spain); Rinio, M.; Borchert, D. [Fraunhofer Institut fuer Solare Energiesysteme ISE, Laboratory and Servicecenter Gelsenkirchen, Auf der Reihe 2, 45884 Gelsenkirchen (Germany); Guerrero-Lemus, R. [Departamento de Fisica Basica, Universidad de La Laguna (ULL), Avenida Astrofisico Francisco Sanchez 2, 38206 La Laguna, S/C de Tenerife (Spain); Fundacion de Estudios de Economia Aplicada, Catedra Focus-Abengoa, Jorge Juan 46, 28001 Madrid (Spain)

    2011-03-15

    The influence of phosphorus gettering is studied in this work applied to an acidic textured multicrystalline silicon substrate. The texturization was achieved with an HF/HNO{sub 3} solution leading to nanostructures on the silicon surface. It has been demonstrated in previous works that this textured surface decreases the reflectance on the solar cell and increases the surface area improving the photon collection and enhancing the short circuit current. The present study investigates the effect on the minority carrier lifetime of the phosphorous diffusion when it is carried out on this textured surface. The lifetime is measured by means microwave photoconductance decay and quasi steady state phototoconductance devices. The diffused textured wafers are used to fabricate solar cells and their electrical parameters are analyzed. (copyright 2011 WILEY-VCH Verlag GmbH and Co. KGaA, Weinheim) (orig.)

  7. Proximity Band Structure and Spin Textures on Both Sides of Topological-Insulator/Ferromagnetic-Metal Interface and Their Charge Transport Probes.

    Science.gov (United States)

    Marmolejo-Tejada, Juan Manuel; Dolui, Kapildeb; Lazić, Predrag; Chang, Po-Hao; Smidstrup, Søren; Stradi, Daniele; Stokbro, Kurt; Nikolić, Branislav K

    2017-09-13

    The control of recently observed spintronic effects in topological-insulator/ferromagnetic-metal (TI/FM) heterostructures is thwarted by the lack of understanding of band structure and spin textures around their interfaces. Here we combine density functional theory with Green's function techniques to obtain the spectral function at any plane passing through atoms of Bi 2 Se 3 and Co or Cu layers comprising the interface. Instead of naively assumed Dirac cone gapped by the proximity exchange field spectral function, we find that the Rashba ferromagnetic model describes the spectral function on the surface of Bi 2 Se 3 in contact with Co near the Fermi level E F 0 , where circular and snowflake-like constant energy contours coexist around which spin locks to momentum. The remnant of the Dirac cone is hybridized with evanescent wave functions from metallic layers and pushed, due to charge transfer from Co or Cu layers, a few tenths of an electron-volt below E F 0 for both Bi 2 Se 3 /Co and Bi 2 Se 3 /Cu interfaces while hosting distorted helical spin texture wounding around a single circle. These features explain recent observation of sensitivity of spin-to-charge conversion signal at TI/Cu interface to tuning of E F 0 . Crucially for spin-orbit torque in TI/FM heterostructures, few monolayers of Co adjacent to Bi 2 Se 3 host spectral functions very different from the bulk metal, as well as in-plane spin textures (despite Co magnetization being out-of-plane) due to proximity spin-orbit coupling in Co induced by Bi 2 Se 3 . We predict that out-of-plane tunneling anisotropic magnetoresistance in Cu/Bi 2 Se 3 /Co vertical heterostructure can serve as a sensitive probe of the type of spin texture residing at E F 0 .

  8. Stress analysis and microstructure of PVD monolayer TiN and multilayer TiN/(Ti,Al)N coatings

    NARCIS (Netherlands)

    Carvalho, NJM; Zoestbergen, E; Kooi, BJ; De Hosson, JTM

    2003-01-01

    Two PVD titanium nitride based coatings; monolayer TiN and multilayer resulting from the stacking of TiN and (Ti,Al)N layers were evaluated with respect to their stress state and microstructure. The TiN was deposited by triode evaporation ion plating, whereas the TiN/(Ti,AI)N was deposited using a

  9. Fabrication and characterization of laminated Ti-(TiB+La2O3/Ti composite

    Directory of Open Access Journals (Sweden)

    Yuanfei Han

    2015-10-01

    Full Text Available The incorporation of ceramic particulate reinforcements into titanium alloys can improve the specific strength and specific stiffness, while inevitably reduce the plasticity and ductility. In this study, in situ synthesized multilayer Ti-(TiB+La2O3/Ti composite was designed by learning from the microstructure of nature biological materials with excellent mechanical properties. The Ti-(TiB+La2O3/Ti composite with unique characteristic of laminated structure was prepared by combined powder metallurgy and hot rolling. The method has the synthesize advantages with in-situ reaction of Ti and LaB6 at high temperature and controllability of reinforcements size and constituent phases in composites. The result shows that the pores in the as sintered laminated structure composite completely disappeared after hot rolling at 1050 °C. The agglomerated reinforcement particles were well dispersed and distributed uniformly along the rolling direction. The thickness of pure Ti layer and (TiB+La2O3/Ti composite layer decreased from 1 mm to about 200 μm. Meanwhile, the grains size was refined obviously after rolling deformation. The room temperature tensile test indicates that the elongation of the laminated Ti-(TiB+La2O3/Ti composite improved from 13% to 17% in comparison with the uniform (TiB+La2O3/Ti composite, while the tensile strength had little change. It provides theoretical and experimental basis for fabricating the novel high performance laminated Ti-(TiB+La2O3/Ti composites.

  10. Elemental evolution of the SiOxFy self-masking layer of plasma textured silicon and its modification during air exposure

    Science.gov (United States)

    Gaudig, Maria; Hirsch, Jens; Naumann, Volker; Werner, Martina; Großer, Stephan; Hagendorf, Christian; Bernhard, Norbert; Lausch, Dominik

    2017-02-01

    The influence of the SiOxFy selfmasking process on the formation of black-Silicon (b-Si) textures by maskless SF6/O2 plasma etching is of great interest with regard to the optimization of the texturing process for highly antireflective silicon. For that reason, the elemental composition of plasma textured silicon surfaces is analyzed by transmission electron microscopy and X-ray photoelectron spectroscopy. The chemical composition of a fluorine containing oxide layer on top of the surface was confirmed and determined quantitatively. A strongly reduced F content was found after ambient air exposure. A qualitative model of the chemical and physical processes caused by maskless plasma texturing was developed to explain the observed experimental results. The decrease in the F content is assumed to be caused by hydrolysis of F by air moisture, resulting in a successive desorption of HF and transformation of SiOxFy to silicon oxide.

  11. AUTOMATIC TEXTURE RECONSTRUCTION OF 3D CITY MODEL FROM OBLIQUE IMAGES

    Directory of Open Access Journals (Sweden)

    J. Kang

    2016-06-01

    Full Text Available In recent years, the photorealistic 3D city models are increasingly important in various geospatial applications related to virtual city tourism, 3D GIS, urban planning, real-estate management. Besides the acquisition of high-precision 3D geometric data, texture reconstruction is also a crucial step for generating high-quality and visually realistic 3D models. However, most of the texture reconstruction approaches are probably leading to texture fragmentation and memory inefficiency. In this paper, we introduce an automatic framework of texture reconstruction to generate textures from oblique images for photorealistic visualization. Our approach include three major steps as follows: mesh parameterization, texture atlas generation and texture blending. Firstly, mesh parameterization procedure referring to mesh segmentation and mesh unfolding is performed to reduce geometric distortion in the process of mapping 2D texture to 3D model. Secondly, in the texture atlas generation step, the texture of each segmented region in texture domain is reconstructed from all visible images with exterior orientation and interior orientation parameters. Thirdly, to avoid color discontinuities at boundaries between texture regions, the final texture map is generated by blending texture maps from several corresponding images. We evaluated our texture reconstruction framework on a dataset of a city. The resulting mesh model can get textured by created texture without resampling. Experiment results show that our method can effectively mitigate the occurrence of texture fragmentation. It is demonstrated that the proposed framework is effective and useful for automatic texture reconstruction of 3D city model.

  12. Automatic Texture Reconstruction of 3d City Model from Oblique Images

    Science.gov (United States)

    Kang, Junhua; Deng, Fei; Li, Xinwei; Wan, Fang

    2016-06-01

    In recent years, the photorealistic 3D city models are increasingly important in various geospatial applications related to virtual city tourism, 3D GIS, urban planning, real-estate management. Besides the acquisition of high-precision 3D geometric data, texture reconstruction is also a crucial step for generating high-quality and visually realistic 3D models. However, most of the texture reconstruction approaches are probably leading to texture fragmentation and memory inefficiency. In this paper, we introduce an automatic framework of texture reconstruction to generate textures from oblique images for photorealistic visualization. Our approach include three major steps as follows: mesh parameterization, texture atlas generation and texture blending. Firstly, mesh parameterization procedure referring to mesh segmentation and mesh unfolding is performed to reduce geometric distortion in the process of mapping 2D texture to 3D model. Secondly, in the texture atlas generation step, the texture of each segmented region in texture domain is reconstructed from all visible images with exterior orientation and interior orientation parameters. Thirdly, to avoid color discontinuities at boundaries between texture regions, the final texture map is generated by blending texture maps from several corresponding images. We evaluated our texture reconstruction framework on a dataset of a city. The resulting mesh model can get textured by created texture without resampling. Experiment results show that our method can effectively mitigate the occurrence of texture fragmentation. It is demonstrated that the proposed framework is effective and useful for automatic texture reconstruction of 3D city model.

  13. Adhesion measurement of highly-ordered TiO2 nanotubes on Ti-6Al-4V alloy

    Directory of Open Access Journals (Sweden)

    Masoud Sarraf

    2017-12-01

    Full Text Available Self-assembled nanotubular arrays on Ti alloys could be used for more effective implantable devices in various medical approaches. In the present work, the adhesion of TiO2 nanotubes (TiO2 NTs on Ti-6Al-4V (Ti64 was investigated by laser spallation and scratch test techniques. At first, electrochemical anodization was performed in an ammonium fluoride solution dissolved in a 90:10 ethane-1,2-diol (ethylene glycol and water solvent mixture. This process was performed at room temperature (23 °C at a steady potential of 60 V for 1 h. Next, the TiO2 nanotubes layer was heat-treated to improve the adhesion of the coating. The formation of selforganized TiO2 nanotubes as well as the microstructural evolution, are strongly dependent on the processing parameters and subsequent annealing. From microscopic analysis, highly oriented arrays of TiO2 nanotubes were grown by thermal treatment for 90 min at 500 °C. Further heat treatment above 500 °C led to the detachment of the nanotubes and the complete destruction of the nanotubes occurred at temperature above 700 °C. Scratch test analysis over a constant scratch length (1000 µm indicated that the failure point was shifted from 247.4 to 557.9 µm while the adhesion strength was increased from ∼862 to ∼1814 mN after annealing at 500 °C. The adhesion measurement determined by laser spallation technique provided an intrinsic adhesion strength of 51.4 MPa for the TiO2 nanotubes on the Ti64 substrate.

  14. (Ti, O)/Ti and (Ti, O, N)/Ti composite coatings fabricated via PIIID for the medical application of NiTi shape memory alloy.

    Science.gov (United States)

    Sun, Tao; Wang, Lang-Ping; Wang, Min

    2011-02-01

    In this investigation, the plasma immersion ion implantation and deposition (PIIID) technique was used to fabricate (Ti, O)/Ti or (Ti, O, N)/Ti coatings on a NiTi shape memory alloy (SMA, 50.8 at.% Ni) to improve its corrosion, wear resistance, and bioactivity. After coating fabrication, the structure and properties of composite coatings were studied, and the coated and uncoated NiTi SMA samples were compared with each other. Scanning electron microscopic (SEM) examination of coating surfaces and cross-sections showed that (Ti, O)/Ti and (Ti, O, N)/Ti composite coatings were dense and uniform, having thickness values of 1.16 ± 0.08 μm and 0.95 ± 0.06 μm, respectively. X-ray diffraction (XRD) results revealed that there were no diffraction peaks corresponding to TiO(2) or TiN for (Ti, O)/Ti and (Ti, O, N)/Ti composite coatings, suggesting that after the PIIID treatment, TiO(2) and TiN were amorphous or nanosized in the coatings. Energy dispersive X-ray (EDX) analysis indicated that the interface between the coating and NiTi SMA substrate was gradual rather than sharp. In addition, EDX elemental mapping of coating cross-sections showed that Ni was depleted from the surface. Differential scanning calorimetry (DSC) curves revealed that the shape memory ability of NiTi SMA was not degraded by the PIIID treatment. The width of wear tracks on (Ti, O, N)/Ti coated NiTi SMA samples was reduced 6.5-fold, in comparison with that on uncoated samples. The corrosion potential (E(corr) ) was improved from -466.20 ± 37.82 mV for uncoated samples to 125.50 ± 21.49 mV and -185.40 ± 37.05 mV for (Ti, O)/Ti coated and (Ti, O, N)/Ti coated samples, respectively. Both types of coatings facilitated bone-like apatite formation on the surface of NiTi SMA in simulated body fluid (SBF), indicating their in vitro bioactivity. Copyright © 2010 Wiley Periodicals, Inc.

  15. Multifunctional Beta Ti Alloy with Improved Specific Strength

    Science.gov (United States)

    Park, Chan Hee; Hong, Jae-Keun; Lee, Sang Won; Yeom, Jong-Taek

    2017-12-01

    Gum metals feature properties such as ultrahigh strength, ultralow elastic modulus, superelasticity, and superplasticity. They are composed of elements from Groups 4 and 5 of the periodic table and exist when the valance electron concentration (\\overline{e/a}) is 4.24; the bond order (\\overline{Bo}) is 2.87; and the "d" electron-orbital energy level (\\overline{Md}) is 2.45 eV. Typical compositions include Ti-23Nb-2Zr-0.7Ta-O and Ti-12Ta-9Nb-6Zr-3 V-O, which contain large amounts of heavy Group-5 elements such as Nb and Ta. In the present study, to improve the specific strength of a multifunctional beta Ti alloy, three alloys (Ti-20Nb-5Zr-1Fe-O, Ti-12Zr-10Mo-4Nb-O, and Ti-24Zr-9Cr-3Mo-O) were designed by satisfying the above three requirements while adding Fe, Mo, and Cr, which are not only lightweight but also have strong hardening effects. Microstructural and mechanical property analyses revealed that Ti-20Nb-5Zr-1Fe-O has a 25% higher specific strength than gum metal while maintaining an ultralow elastic modulus.

  16. DFT study on the interaction of TiO2 (001) surface with HCHO molecules

    Science.gov (United States)

    Wu, Guofei; Zhao, Cuihua; Guo, Changqing; Chen, Jianhua; Zhang, Yibing; Li, Yuqiong

    2018-01-01

    The interactions of formaldehyde (HCHO) molecule with TiO2 (001) surface were studied using density functional theory calculations. HCHO molecules are dissociated by the cleavage of Csbnd H bonds after adsorption on TiO2 surface. The strong interactions between HCHO melecules and TiO2 surface are largely attributed to the bonding of hydrogen of HCHO and oxygen of TiO2 surface, which is mainly from the hybridization of the H 1s, O 2p and O 2s. The newly formed Hsbnd O bonds cause the structure changes of TiO2 surface, and lead to the cleavage of Osbnd Ti bond of TiO2 surface. The Csbnd O bond that the dissociated remains of HCHO and newly formed Hsbnd O bond can be oxidized to form carbon dioxide and water in subsequent action by oxygen from the atomosphere. The charges transfer from HCHO to TiO2 surface, and the sum amount of the charges transferred from four HCHO molecules to TiO2 surface is bigger than that from one HCHO molecule to TiO2 surface due to the combined interaction of four HCHO molecules with TiO2 surface.

  17. Mechanism of multi-defect induced ferromagnetism in undoped rutile TiO{sub 2}

    Energy Technology Data Exchange (ETDEWEB)

    Wang, Hongxia, E-mail: jwhongxia@gmail.com; Zong, Zhaocun [College of Mathematics, Physics and Information Science, Zhejiang Ocean University, Zhoushan 316000 (China); Yan, Yu [State Key Laboratory of Superhard Materials and Department of Physics, Jilin University, Changchun 130012 (China)

    2014-06-21

    Based on first-principles calculations, the coexistence of Ti vacancies (V{sub Ti}) and O vacancies (V{sub O}) is first considered to study the origin of the ferromagnetic ordering in undoped rutile TiO{sub 2}. The calculations show that V{sub O} can induce local magnetic moments in TiO{sub 2}, however, the ferromagnetic (FM) exchange interaction of two V{sub O} is not strong enough to induce room-temperature (RT) ferromagnetism on their own in undoped TiO{sub 2}. The FM coupling between two V{sub Ti} is about four times stronger than that between two V{sub O}. More importantly, the FM coupling between two V{sub Ti} is further enhanced after V{sub O} is introduced. Our results indicate that the electrons induced by V{sub O} mediate the long-range FM exchange interaction between two distant V{sub Ti}. This maybe the ferromagnetism mechanism in undoped TiO{sub 2}: V{sub Ti} produce local moments while the electrons induced by V{sub O} mediated the long-range FM exchange interaction. The results are in excellent agreement with the experimental evidences that V{sub O} alone cannot induce RT ferromagnetism while V{sub O} can promote the ferromagnetic ordering in undoped TiO{sub 2}.

  18. Fiber vs Rolling Texture: Stress State Dependence for Cold-Drawn Wire

    Science.gov (United States)

    Zorina, M. A.; Karabanalov, M. S.; Stepanov, S. I.; Demakov, S. L.; Loginov, Yu. N.; Lobanov, M. L.

    2018-02-01

    The texture of the cold-drawn copper wire was investigated along the radius using electron backscatter diffraction. The complex fiber texture of the central region of the wire was considered as the rolling texture consisting of a set of preferred orientations. The texture of the periphery region was revealed to be similar to the shear texture. The orientation-dependent properties of the wire were proven to be determined by the texture of the near-surface layers.

  19. Preparation of TiO₂ supported Au–Pd and Cu–Pd by the combined ...

    Indian Academy of Sciences (India)

    TiO₂ supported Au–Pd and Cu–Pd catalysts were prepared by strong electrostatic adsorption (SEA) of Pd followed by electroless deposition (ED) of a second metal with incremental surface coverages of Au or Cu. High dispersion of small Pd particles on the Pd/TiO2 prepared by SEA led to the high amount of second metal ...

  20. Cold rolled texture and microstructure in types 304 and 316L austenitic stainless steels

    International Nuclear Information System (INIS)

    Wasnik, D.N.; Samajdar, I.; Gopalakrishnan, I.K.; Yakhmi, J.V.; Kain, V.

    2003-01-01

    Two grades of austenitic stainless steel (ASS), types 304 (UNS S 30400) and 316L (UNS S 31603), were cold rolled to different reductions by unidirectional and by cross-rolling. The steels had reasonable difference in stacking fault energy (estimated respectively as 15 and 61 mJ/m 2 in types 304 and 316L) and also in starting (or pre-deformation) crystallographic texture-being relatively weak and reasonably strong in types 304 and 316L respectively. The cold rolling increased texturing in type 304, but not in type 316L ASS. The more significant effect of cold rolled texture development was in the relative increase of Brass ({011} ) against Copper ({112} ) and S ({231} ) orientations. In type 304 the increase in Brass was significant, while in type 316L the increase in Copper and S was stronger. This effect could be captured by Taylor type deformation texture simulations considering stronger twinning contributions in type 304 - for example the respective 'best-fits' (in terms of matching the changes in the volume fractions of Brass against Copper and S) were obtained by full constraint Taylor model with 1:100 and 1:10 slip:twin activities in types 304 and 316L ASS respectively. Microstructural developments during cold rolling were generalized as strain induced martensite formation and developments of dislocation substructure. The former, as estimated by vibrating sample magnetometer (VSM), increased with cold reduction, being significantly more in type 304 and was also noticeably stronger in both grades under cross-rolling. The most significant aspect of substructural developments was the formation of strain localizations. These were observed as dense dislocation walls (DDWs), micro-bands (MBs) and twin lamellar structures (TLS). The TLS contribution gained significance at higher reductions and during cross-rolling, especially in type 304. Large misorientation development and the accompanying grain splittings were always associated with such strain localizations