Binary Polymer Brushes of Strongly Immiscible Polymers.
Chu, Elza; Babar, Tashnia; Bruist, Michael F; Sidorenko, Alexander
2015-06-17
The phenomenon of microphase separation is an example of self-assembly in soft matter and has been observed in block copolymers (BCPs) and similar materials (i.e., supramolecular assemblies (SMAs) and homo/block copolymer blends (HBCs)). In this study, we use microphase separation to construct responsive polymer brushes that collapse to generate periodic surfaces. This is achieved by a chemical reaction between the minor block (10%, poly(4-vinylpyridine)) of the block copolymer and a substrate. The major block of polystyrene (PS) forms mosaic-like arrays of grafted patches that are 10-20 nm in size. Depending on the nature of the assembly (SMA, HBC, or neat BCP) and annealing method (exposure to vapors of different solvents or heating above the glass transition temperature), a range of "mosaic" brushes with different parameters can be obtained. Successive grafting of a secondary polymer (polyacrylamide, PAAm) results in the fabrication of binary polymer brushes (BPBs). Upon being exposed to specific selective solvents, BPBs may adopt different conformations. The surface tension and adhesion of the binary brush are governed by the polymer occupying the top stratum. The "mosaic" brush approach allows for a combination of strongly immiscible polymers in one brush. This facilitates substantial contrast in the surface properties upon switching, previously only possible for substrates composed of predetermined nanostructures. We also demonstrate a possible application of such PS/PAAm brushes in a tunable bioadhesion-bioadhesive (PS on top) or nonbioadhesive (PAAm on top) surface as revealed by Escherichia coli bacterial seeding.
Directory of Open Access Journals (Sweden)
Suzuki Tomonari
2006-01-01
Full Text Available We prove Browder's type strong convergence theorems for infinite families of nonexpansive mappings. One of our main results is the following: let be a bounded closed convex subset of a uniformly smooth Banach space . Let be an infinite family of commuting nonexpansive mappings on . Let and be sequences in satisfying for . Fix and define a sequence in by for . Then converges strongly to , where is the unique sunny nonexpansive retraction from onto .
International Nuclear Information System (INIS)
Monreal, Marisa J.; Seaman, Lani A.; Goff, George S.; Michalczyk, Ryszard; Morris, David E.; Scott, Brian L.; Kiplinger, Jaqueline L.
2016-01-01
Two organometallic 1D infinite coordination polymers and two organometallic monometallic complexes of thorium diazide have been synthesized and characterized. Steric control of these self-assembled arrays, which are dense in thorium and nitrogen, has also been demonstrated: infinite chains can be circumvented by using steric bulk either at the metallocene or with a donor ligand in the wedge. (copyright 2016 WILEY-VCH Verlag GmbH and Co. KGaA, Weinheim)
Lactic acid polymers: strong, degradable thermoplastics
Energy Technology Data Exchange (ETDEWEB)
Wehrenberg, R.H.
1981-01-01
Copolymers of lactic and glycolic acids are being developed by researchers at Battelle and elsewhere as renewable-resource plastics. Other uses include matrices for controlled release of drugs and pesticides as well as in prosthetic devices. In contrast to conventional plastics, lactic acid polymers are biodegradable, and after several months exposure to moisture, these materials convert back to natural harmless products. The properties of lactic acid polymers are examined.
Mechanically Strong, Polymer Cross-linked Aerogels (X-Aerogels)
Leventis, Nicholas
2006-01-01
Aerogels comprise a class of low-density, high porous solid objects consisting of dimensionally quasi-stable self-supported three-dimensional assemblies of nanoparticles. Aerogels are pursued because of properties above and beyond those of the individual nanoparticles, including low thermal conductivity, low dielectric constant and high acoustic impedance. Possible applications include thermal and vibration insulation, dielectrics for fast electronics, and hosting of functional guests for a wide variety of optical, chemical and electronic applications. Aerogels, however, are extremely fragile materials, hence they have found only limited application in some very specialized environments, for example as Cerenkov radiation detectors in certain types of nuclear reactors, aboard spacecraft as collectors of hypervelocity particles (refer to NASA's Stardust program) and as thermal insulators on planetary vehicles on Mars (refer to Sojourner Rover in 1997 and Spirit and Opportunity in 2004). Along these lines, the X-Aerogel is a new NASA-developed strong lightweight material that has resolved the fragility problem of traditional (native) aerogels. X-Aerogels are made by applying a conformal polymer coating on the surfaces of the skeletal nanoparticles of native aerogels (see Scanning Electron Micrographs). Since the relative amounts of the polymeric crosslinker and the backbone are comparable, X-Aerogels can be viewed either as aerogels modified by the templated accumulation of polymer on the skeletal nanoparticles, or as nanoporous polymers made by remplated casting of polymer on a nanostructured framework. The most striking feature of X-Aerogels is that for a nominal 3-fold increase in density (still a ultralighweight material), the mechanical strength can be up to 300 times higher than the strength of the underlying native aerogel. Thus, X-Aerogels combine a multiple of the specific compressive strength of steel, with the the thermal conductivity of styrofoam. X
Wang, Lihua; Zeng, Yi; Shen, Aiguo; Zhou, Xiaodong; Hu, Jiming
2015-02-07
Novel three-dimensional (3D) nano-assemblies of noble metal nanoparticle (NP)-infinite coordination polymers (ICPs) are conveniently fabricated through the infiltration of HAuCl4 into hollow Au@Ag@ICPs core-shell nanostructures and its replacement reaction with Au@Ag NPs. The present 3D nano-assemblies exhibit highly efficient and specific intrinsic oxidase-like activity even without adding any cosubstrate.
Nambu, Y.
1967-01-01
The main ingredients of the method of infinite multiplets consist of: 1) the use of wave functions with an infinite number of components for describing an infinite tower of discrete states of an isolated system (such as an atom, a nucleus, or a hadron), 2) the use of group theory, instead of dynamical considerations, in determining the properties of the wave functions.
Pop, P.C.; Still, Georg J.
1999-01-01
In linear programming it is known that an appropriate non-homogeneous Farkas Lemma leads to a short proof of the strong duality results for a pair of primal and dual programs. By using a corresponding generalized Farkas lemma we give a similar proof of the strong duality results for semidefinite
Nonlinear Response of Strong Nonlinear System Arisen in Polymer Cushion
Directory of Open Access Journals (Sweden)
Jun Wang
2013-01-01
Full Text Available A dynamic model is proposed for a polymer foam-based nonlinear cushioning system. An accurate analytical solution for the nonlinear free vibration of the system is derived by applying He's variational iteration method, and conditions for resonance are obtained, which should be avoided in the cushioning design.
International Nuclear Information System (INIS)
Domanska, Urszula; Zolek-Tryznowska, Zuzanna
2010-01-01
Thermodynamic properties of the hyperbranched polymer, Boltorn H2004 (B-H2004), were investigated by inverse gas chromatography with 42 different solvents: n-alkanes (C 5 -C 10 ), cycloalkanes (C 5 -C 8 ), alkenes (C 5 -C 8 ), alkynes (C 5 -C 8 ), aromatic hydrocarbons (benzene, toluene, ethylbenzene, o-, m-, p-xylene, thiophene), alcohols (C 1 -C 5 ), water, ethers (tetrahydrofuran (THF), methyl-tert-butylether (MTBE), diethyl-, di-n-propyl-, di-n-butyl ether), and ketones (acetone, 2-pentanone, 3-pentanone, 2-hexanone, 3-hexanone, cyclopentanone) at the temperatures from (308.15 to 348.15) K using the inverse gas chromatography (IGC). The density and thermophysical properties of polymer were described. The specific retention volume (V g ), the mass-fraction activity coefficient at infinite dilution (Ω 13 ∞ ), the Flory-Huggins interaction parameter (χ 13 ∞ ), the molar enthalpy of sorption in the polymer (Δ s H), the partial molar excess enthalpy at infinite dilution (ΔH 1 E,∞ ), the molar enthalpy of vaporization to the ideal-gas state for the pure solutes (Δ vap H 0 ), the partial molar Gibbs excess energy at infinite dilution (ΔG 1 E,∞ ), and the solubility parameter of the polymer (δ 3 ), were calculated. The UNIFAC-FV model was used to predict the mass-fraction activity coefficient at infinite dilution for different solutes in the B-H2004 polymer.
Stochastic and infinite dimensional analysis
Carpio-Bernido, Maria; Grothaus, Martin; Kuna, Tobias; Oliveira, Maria; Silva, José
2016-01-01
This volume presents a collection of papers covering applications from a wide range of systems with infinitely many degrees of freedom studied using techniques from stochastic and infinite dimensional analysis, e.g. Feynman path integrals, the statistical mechanics of polymer chains, complex networks, and quantum field theory. Systems of infinitely many degrees of freedom create their particular mathematical challenges which have been addressed by different mathematical theories, namely in the theories of stochastic processes, Malliavin calculus, and especially white noise analysis. These proceedings are inspired by a conference held on the occasion of Prof. Ludwig Streit’s 75th birthday and celebrate his pioneering and ongoing work in these fields.
Rheology of Confined Polymer Melts under Shear Flow : Strong Adsorption Limit
Subbotin, A.; Manias, E.; Hadziioannou, G.; Brinke, G. ten
1995-01-01
The dynamics of a confined polymer melt between strong adsorbing surfaces is considered theoretically. In particular the influence of bridging on the theological behavior is investigated. It is shown that the bridges are very important for small enough shear velocities. Several regimes of
Static and kinetic friction of strongly confined polymer films under shear
Hirz, S; Subbotin, A; Frank, C; Hadziioannou, G
1996-01-01
In the present work, we investigate the dependence of relaxational processes in strongly confined polymer liquids as a function of the molecular mass and of the confining film thickness, both theoretically and experimentally. A qualitative agreement is observed between the theoretical predictions
Hirschman, Isidore Isaac
2014-01-01
This text for advanced undergraduate and graduate students presents a rigorous approach that also emphasizes applications. Encompassing more than the usual amount of material on the problems of computation with series, the treatment offers many applications, including those related to the theory of special functions. Numerous problems appear throughout the book.The first chapter introduces the elementary theory of infinite series, followed by a relatively complete exposition of the basic properties of Taylor series and Fourier series. Additional subjects include series of functions and the app
Energy Technology Data Exchange (ETDEWEB)
Domanska, Urszula, E-mail: ula@ch.pw.edu.p [Department of Physical Chemistry, Faculty of Chemistry, Warsaw University of Technology, Noakowskiego 3, 00-664 Warsaw (Poland); Zolek-Tryznowska, Zuzanna [Department of Physical Chemistry, Faculty of Chemistry, Warsaw University of Technology, Noakowskiego 3, 00-664 Warsaw (Poland)
2010-03-15
Thermodynamic properties of the hyperbranched polymer, Boltorn H2004 (B-H2004), were investigated by inverse gas chromatography with 42 different solvents: n-alkanes (C{sub 5}-C{sub 10}), cycloalkanes (C{sub 5}-C{sub 8}), alkenes (C{sub 5}-C{sub 8}), alkynes (C{sub 5}-C{sub 8}), aromatic hydrocarbons (benzene, toluene, ethylbenzene, o-, m-, p-xylene, thiophene), alcohols (C{sub 1}-C{sub 5}), water, ethers (tetrahydrofuran (THF), methyl-tert-butylether (MTBE), diethyl-, di-n-propyl-, di-n-butyl ether), and ketones (acetone, 2-pentanone, 3-pentanone, 2-hexanone, 3-hexanone, cyclopentanone) at the temperatures from (308.15 to 348.15) K using the inverse gas chromatography (IGC). The density and thermophysical properties of polymer were described. The specific retention volume (V{sub g}), the mass-fraction activity coefficient at infinite dilution (OMEGA{sub 13}{sup i}nfinity), the Flory-Huggins interaction parameter (chi{sub 13}{sup i}nfinity), the molar enthalpy of sorption in the polymer (DELTA{sub s}H), the partial molar excess enthalpy at infinite dilution (DELTAH{sub 1}{sup E,i}nfinity), the molar enthalpy of vaporization to the ideal-gas state for the pure solutes (DELTA{sub vap}H{sup 0}), the partial molar Gibbs excess energy at infinite dilution (DELTAG{sub 1}{sup E,i}nfinity), and the solubility parameter of the polymer (delta{sub 3}), were calculated. The UNIFAC-FV model was used to predict the mass-fraction activity coefficient at infinite dilution for different solutes in the B-H2004 polymer.
Semi-metallic, strong and stretchable wet-spun conjugated polymer microfibers
Zhou, Jian
2015-01-21
A dramatic improvement in electrical conductivity is necessary to make conductive polymer fibers viable candidates in applications such as flexible electrodes, conductive textiles, and fast-response sensors and actuators. In this study, high-performance poly(3,4-ethylenedioxythiophene)/poly(styrenesulfonate) (PEDOT/PSS) conjugated polymer microfibers were fabricated via wet-spinning followed by hot-drawing. Due to the combined effects of the vertical hot-drawing process and doping/de-doping the microfibers with ethylene glycol (EG), we achieved a record electrical conductivity of 2804 S cm−1. This is, to the best of our knowledge, a six-fold improvement over the best previously reported value for PEDOT/PSS fibers (467 S cm−1) and a two-fold improvement over the best values for conductive polymer films treated by EG de-doping (1418 S cm−1). Moreover, we found that these highly conductive fibers experience a semiconductor–metal transition at 313 K. They also have superior mechanical properties with a Young\\'s modulus up to 8.3 GPa, a tensile strength reaching 409.8 MPa and a large elongation before failure (21%). The most conductive fiber also demonstrates an extraordinary electrical performance during stretching/unstretching: the conductivity increased by 25% before the fiber rupture point with a maximum strain up to 21%. Simple fabrication of the semi-metallic, strong and stretchable wet-spun PEDOT/PSS microfibers described here could make them available for conductive smart electronics.
Zhou, Jian
2016-06-09
A method comprising: providing at least one first composition comprising at least one conjugated polymer and at least one solvent, wet spinning the at least one first composition to form at least one first fiber material, hot-drawing the at least one fiber to form at least one second fiber material. In lead embodiments, high-performance poly(3,4-ethylenedioxy- thiophene)/poly(styrenesulfonate) (PEDOT/PSS) conjugated polymer microfibers were fabricated via wet- spinning followed by hot-drawing. In these lead embodiments, due to the combined effects of the vertical hot-drawing process and doping/de-doping the microfibers with ethylene glycol (EG), a record electrical conductivity of 2804 S · cm-1 was achieved. This is believed to be a six-fold improvement over the best previously reported value for PEDOT/PSS fibers (467 S · cm-1) and a twofold improvement over the best values for conductive polymer films treated by EG de-doping (1418 S · cm-1). Moreover, these lead, highly conductive fibers experience a semiconductor-metal transition at 313 K. They also have superior mechanical properties with a Young\\'s modulus up to 8.3 GPa, a tensile strength reaching 409.8 MPa and a large elongation before failure (21%). The most conductive fiber also demonstrates an extraordinary electrical performance during stretching/unstretching: the conductivity increased by 25% before the fiber rupture point with a maximum strain up to 21%. Simple fabrication of the semi-metallic, strong and stretchable wet-spun PEDOT/PSS microfibers can make them available for conductive smart electronics. A dramatic improvement in electrical conductivity is needed to make conductive polymer fibers viable candidates in applications such as flexible electrodes, conductive textiles, and fast-response sensors and actuators.
Weakly infinite-dimensional spaces
International Nuclear Information System (INIS)
Fedorchuk, Vitalii V
2007-01-01
In this survey article two new classes of spaces are considered: m-C-spaces and w-m-C-spaces, m=2,3,...,∞. They are intermediate between the class of weakly infinite-dimensional spaces in the Alexandroff sense and the class of C-spaces. The classes of 2-C-spaces and w-2-C-spaces coincide with the class of weakly infinite-dimensional spaces, while the compact ∞-C-spaces are exactly the C-compact spaces of Haver. The main results of the theory of weakly infinite-dimensional spaces, including classification via transfinite Lebesgue dimensions and Luzin-Sierpinsky indices, extend to these new classes of spaces. Weak m-C-spaces are characterised by means of essential maps to Henderson's m-compacta. The existence of hereditarily m-strongly infinite-dimensional spaces is proved.
Polymer/Pristine Graphene Based Composites: From Emulsions to Strong, Electrically Conducting Foams
Woltornist, Steven; Carrillo, Jan-Michael; Xu, Thomas; Dobrynin, Andrey; Adamson, Douglas
2015-03-01
The unique electrical, thermal and mechanical properties of graphene make it a perfect candidate for applications in graphene/graphite based polymer composites, yet challenges due to the lack of solubility of pristine graphene/graphite in water, common organic solvents, and polymer solutions and melts have limited its practical utilization. Here we report a scalable and environmentally friendly technique to form water-in-oil type emulsions stabilized by a graphitic skin consisting of overlapping pristine graphene sheets that enables the synthesis of open cell foams containing a continuous graphitic skin network. At the heart of our technique is the strong attraction of graphene to high-energy oil and water interfaces. This allows for the creation of stable water-in-oil emulsions with controlled droplet size and overlapping graphene sheets playing the role of surfactant by covering the droplet surface and stabilizing the interfaces with a thin graphitic skin. These emulsions are used as templates for the synthesis of the open cell foams with densities below 0.35 g/cm3 and exhibiting remarkable mechanical and electrical properties including compressive moduli up to ~ 100 MPa, compressive strengths of over 8.3 MPa, and bulk conductivities approaching 7 S/m.
Prediction and design of first super-strong liquid-crystalline polymers
International Nuclear Information System (INIS)
Dowell, F.
1989-01-01
This paper presents the details of the theoretical prediction and design (atom by atom, bond by bond) of the molecule chemical structures of the first candidate super-strong liquid-crystalline polymers (SS LCPs). These LCPs are the first LCPs designed to have good compressive strengths, as well as to have tensile strengths and tensile moduli significantly larger than those of existing strong LCPs (such as Kevlar). The key feature of this new class of LCPs is that the exceptional strength is three dimensional on a microscopic, molecular level (thus, on a macroscopic level), in contrast to present LCPs (such as Kevlar) with their one-dimensional exceptional strength. These SS LCPs also have some solubility and processing advantages over existing strong LCPs. These SS LCPs are specially-designed combined LCPs such that the side chains of a molecule interdigitate with the side chains of other molecules. This paper also presents other essential general and specific features required for SS LCPs. Considerations in the design of SS LCPs include the spacing distance between side chains along the backbone, the need for rigid sections in the backbone and side chains, the degree of polymerization, the length of the side chains, the regularity of spacing of the side chains along the backbone, the interdigitation of side chains in submolecular strips, the packing of the side chains on one or two sides of the backbone, the symmetry of the side chains, the points of attachment of the side chains to the backbone, the flexibility and size of the chemical group connecting each side chain to the backbone, the effect of semiflexible sections in the backbone and side chains, and the choice of types of dipolar and/or hydrogen bonding forces in the backbones and side chains for easy alignment
Atkinson, D; van Steenwijk, F.J.
The resistance between two arbitrary nodes in an infinite square lattice of:identical resistors is calculated, The method is generalized to infinite triangular and hexagonal lattices in two dimensions, and also to infinite cubic and hypercubic lattices in three and more dimensions. (C) 1999 American
The Infinitive Marker across Scandinavian
DEFF Research Database (Denmark)
Christensen, Ken Ramshøj
2007-01-01
In this paper I argue that the base-position of the infinitive marker in the Scandinavian languages and English share a common origin site. It is inserted as the top-most head in the VP-domain. The cross-linguistic variation in the syntactic distribution of the infinitive marker can be accounted...... for by assuming that it undergoes head movement. This movement is optional in Danish, English, Norwegian, and Early Modern Danish and is not feature-driven. In Faroese, Icelandic, and Swedish, on the other hand, it is triggered by φ-feature checking on Finº. In Icelandic and Swedish these φ-features are strong...
Water-Soluble Polymers with Strong Photoluminescence through an Eco-Friendly and Low-Cost Route.
Guo, Zhaoyan; Ru, Yue; Song, Wenbo; Liu, Zhenjie; Zhang, Xiaohong; Qiao, Jinliang
2017-07-01
Photoluminescence (PL) of nonconjugated polymers brings a favorable opportunity for low-cost and nontoxic luminescent materials, while most of them still exhibit relatively weak emission. Strong PL from poly[(maleic anhydride)-alt-(vinyl acetate)] (PMV) from low-cost monomer has been found in organic solvents, yet the necessity of noxious solvents would hinder its practical applications. Herein, through a novel, eco-friendly, and one-step route, PMV-derived PL polymers can be fabricated with the highest quantum yield of 87% among water-soluble nonconjugated PL polymers ever reported. These PMV-derived polymers emit strong blue emission in both solutions and solids, and can be transformed into red-emission agents easily. These PL polymers exhibit application potentials in light-conversion agricultural films. It is assumed that this work not only puts forward a convenient preparation routine for nonconjugated polymers with high PL, but also provides an industrial application possibility for them. © 2017 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.
Diclofenac removal in urine using strong-base anion exchange polymer resins.
Landry, Kelly A; Boyer, Treavor H
2013-11-01
One of the major sources of pharmaceuticals in the environment is wastewater effluent of which human urine contributes the majority of pharmaceuticals. Urine source separation has the potential to isolate pharmaceuticals at a higher concentration for efficient removal as well as produce a nutrient byproduct. This research investigated the efficacy of using strong-base anion exchange polymer resins to remove the widely detected and abundant pharmaceutical, diclofenac, from synthetic human urine under fresh and ureolyzed conditions. The majority of experiments were conducted using a strong-base, macroporous, polystyrene resin (Purolite A520E). Ion-exchange followed a two-step removal rate with rapid removal in 1 h and equilibrium removal in 24 h. Diclofenac removal was >90% at a resin dose of 8 mL/L in both fresh and ureolyzed urine. Sorption of diclofenac onto A520E resin was concurrent with desorption of an equivalent amount of chloride, which indicates the ion-exchange mechanism is occurring. The presence of competing ions such as phosphate and citrate did not significantly impact diclofenac removal. Comparisons of three polystyrene resins (A520E, Dowex 22, Dowex Marathon 11) as well as one polyacrylic resin (IRA958) were conducted to determine the major interactions between anion exchange resin and diclofenac. The results showed that polystyrene resins provide the highest level of diclofenac removal due to electrostatic interactions between quaternary ammonium functional groups of resin and carboxylic acid of diclofenac and non-electrostatic interactions between resin matrix and benzene rings of diclofenac. Diclofenac was effectively desorbed from A520E resin using a regeneration solution that contained 4.5% (m/m) NaCl in an equal-volume mixture of methanol and water. The greater regeneration efficiency of the NaCl/methanol-water mixture over the aqueous NaCl solution supports the importance of non-electrostatic interactions between resin matrix and benzene rings
Olefin metathesis for effective polymer healing via dynamic exchange of strong carbon-carbon bonds
Guan, Zhibin; Lu, Yixuan
2015-09-15
A method of preparing a malleable and/or self-healing polymeric or composite material is provided. The method includes providing a polymeric or composite material comprising at least one alkene-containing polymer, combining the polymer with at least one homogeneous or heterogeneous transition metal olefin metathesis catalyst to form a polymeric or composite material, and performing an olefin metathesis reaction on the polymer so as to form reversible carbon-carbon double bonds in the polymer. Also provided is a method of healing a fractured surface of a polymeric material. The method includes bringing a fractured surface of a first polymeric material into contact with a second polymeric material, and performing an olefin metathesis reaction in the presence of a transition metal olefin metathesis catalyst such that the first polymeric material forms reversible carbon-carbon double bonds with the second polymeric material. Compositions comprising malleable and/or self-healing polymeric or composite material are also provided.
Role of strongly interacting additives in tuning the structure and properties of polymer systems
Daga, Vikram Kumar
Block copolymer (BCP) nanocomposites are an important class of hybrid materials in which the BCP guides the spatial location and the periodic assembly of the additives. High loadings of well-dispersed nanofillers are generally important for many applications including mechanical reinforcing of polymers. In particular the composites shown in this work might find use as etch masks in nanolithography, or for enabling various phase selective reactions for new materials development. This work explores the use of hydrogen bonding interactions between various additives (such as homopolymers and non-polymeric additives) and small, disordered BCPs to cause the formation of well-ordered morphologies with small domains. A detailed study of the organization of homopolymer chains and the evolution of structure during the process of ordering is performed. The results demonstrate that by tuning the selective interaction of the additive with the incorporating phase of the BCP, composites with significantly high loadings of additives can be formed while maintaining order in the BCP morphology. The possibility of high and selective loading of additives in one of the phases of the ordered BCP composite opens new avenues due to high degree of functionalization and the proximity of the additives within the incorporating phase. This aspect is utilized in one case for the formation of a network structure between adjoining additive cores to derive mesoporous inorganic materials with their structures templated by the BCP. The concept of additive-driven assembly is extended to formulate BCPadditive blends with an ability to undergo photo-induced ordering. Underlying this strategy is the ability to transition a weakly interacting additive to its strongly interacting form. This strategy provides an on-demand, non-intrusive route for formation of well-ordered nanostructures in arbitrarily defined regions of an otherwise disordered material. The second area explored in this dissertation deals
Xie, Meihua; Wang, Ling; Ge, Juan; Guo, Baolin; Ma, Peter X
2015-04-01
Preparation of functional shape memory polymer (SMP) for tissue engineering remains a challenge. Here the synthesis of strong electroactive shape memory polymer (ESMP) networks based on star-shaped polylactide (PLA) and aniline trimer (AT) is reported. Six-armed PLAs with various chain lengths were chemically cross-linked to synthesize SMP. After addition of an electroactive AT segment into the SMP, ESMP was obtained. The polymers were characterized by (1)H NMR, GPC, FT-IR, CV, DSC, DMA, tensile test, and degradation test. The SMP and ESMP exhibited strong mechanical properties (modulus higher than GPa) and excellent shape memory performance: short recovery time (several seconds), high recovery ratio (over 94%), and high fixity ratio (almost 100%). Moreover, cyclic voltammetry test confirmed the electroactivity of the ESMP. The ESMP significantly enhanced the proliferation of C2C12 cells compared to SMP and linear PLA (control). In addition, the ESMP greatly improved the osteogenic differentiation of C2C12 myoblast cells compared to PH10 and PLA in terms of ALP enzyme activity, immunofluorescence staining, and relative gene expression by quantitative real-time polymerase chain reaction (qRT-PCR). These intelligent SMPs and electroactive SMP with strong mechanical properties, tunable degradability, good electroactivity, biocompatibility, and enhanced osteogenic differentiation of C2C12 cells show great potential for bone regeneration.
Jämstorp, Erik; Yarra, Tejaswi; Cai, Bing; Engqvist, Håkan; Bredenberg, Susanne; Strømme, Maria
2012-01-01
Improving acid resistance, while maintaining the excellent mechanical stability is crucial in the development of a sustained and safe oral geopolymer dosage form for highly potent opioids. In the present work, commercially available Methacrylic acid-ethyl acrylate copolymer, Polyethylene-glycol (PEG) and Alginate polymer excipients were included in dissolved or powder form in geopolymer pellets to improve the release properties of Zolpidem, herein acting as a model drug for the highly potent opioid Fentanyl. Scanning electron microscopy, compression strength tests and drug release experiments, in gastric pH 1 and intestinal pH 6.8 conditions, were performed. The polymer excipients, with an exception for PEG, reduced the drug release rate in pH 1 due to their ability to keep the pellets in shape, in combination with the introduction of an insoluble excipient, and thereby maintain a barrier towards drug diffusion and release. Neither geopolymer compression strength nor the release in pH 6.8 was considerably impaired by the incorporation of the polymer excipients. The geopolymer/polymer composites combine high mechanical strength and good release properties under both gastric and intestinal pH conditions, and are therefore promising oral dosage forms for sustained release of highly potent opioids.
Czech Academy of Sciences Publication Activity Database
Hanková, Libuše; Holub, Ladislav; Jeřábek, Karel
2006-01-01
Roč. 66, č. 6 (2006), s. 592-598 ISSN 1381-5148 R&D Projects: GA ČR(CZ) GA104/02/1104 Institutional research plan: CEZ:AV0Z40720504 Keywords : catalysis * polymer supports * resin Subject RIV: CI - Industrial Chemistry, Chemical Engineering Impact factor: 1.561, year: 2006
Czech Academy of Sciences Publication Activity Database
Suchá, L.; Limpouchová, Z.; Procházka, Karel
2017-01-01
Roč. 295, č. 8 (2017), s. 1391-1403 ISSN 0303-402X R&D Projects: GA ČR GA15-19542S Institutional support: RVO:67985858 Keywords : cononsolvency * preferential solvation * star polymer Subject RIV: CF - Physical ; Theoretical Chemistry OBOR OECD: Physical chemistry Impact factor: 1.723, year: 2016
Leventis, Nicholas; Fabrizio, Eve F.; Johnston, Chris; Meador, Maryann
2004-01-01
In the search for materials with better mechanical, thermal, and electrical properties, it is becoming evident that oftentimes dispersing ceramic nanoparticles in plastics improves performance. Along these lines, chemical bonding (both covalent and noncovalent) between a filler and a polymer improves their compatibility, and thus enhances certain properties of the polymeric matrix above and beyond what is accomplished by simple doping with the filler. When a similarly sized dopant and matrix are used, elementary building blocks may also have certain distinct advantages (e.g., in catalysis). In this context, researchers at the NASA Glenn Research Center reasoned that in the extreme case, where the dopant and the matrix (e.g., a filler and a polymer) are not only sized similarly, but their relative amounts are comparable, the relative roles of the dopant and matrix can be reversed. Then, if the "filler," or a certain form thereof, possesses desirable properties of its own, such properties could be magnified by cross-linking with a polymer. We at Glenn have identified silica as such a filler in its lowest-density form, namely the silica aerogel.
On Geometric Infinite Divisibility
Sandhya, E.; Pillai, R. N.
2014-01-01
The notion of geometric version of an infinitely divisible law is introduced. Concepts parallel to attraction and partial attraction are developed and studied in the setup of geometric summing of random variables.
Strongly nonlinear wave dynamics in a chain of polymer coated beads
Daraio, C.; Nesterenko, V. F.
2006-01-01
Strongly nonlinear phononic crystals were assembled from a chain of Parylene-C coated steel spheres in a polytetrafluoroethylene (PTFE) holder. This system exhibits strongly nonlinear properties and extends the range of materials supporting "sonic vacuum" type behavior. The combination of a high density core and a soft (low elastic modulus) coating ensures a relatively low velocity of wave propagation. The beads contact interaction caused by the deformation of the Parylene coating can be desc...
Leventis, Nicholas
2005-01-01
In analogy to supramolecular assemblies, which are pursued because of properties above and beyond those of the individual molecules, self-standing monolithic three-dimensional assemblies of nanoparticles also have unique properties attributed to their structure. For example, ultra low-density 3-D assemblies of silica nanoparticles, known as silica aerogels, are characterized by large internal void space, high surface area and very low thermal conductivity. Aerogels, however, are also extremely fragile materials, limiting their application to a few specialized environments, e.g., in nuclear reactors as Cerenkov radiation detectors, in space (refer to NASA's Stardust Program) and aboard certain planetary vehicles (thermal insulators on Mars Rovers in 1997 and 2004). The fragility problem is traced to well-defined weak points in the aerogel skeletal framework, the interparticle necks. Using the surface functionality of the nanoparticle building blocks as a focal point, we have directed attachment of a conformal polymer coating over the entire framework, rendering all necks wider. Thus, although the bulk density may increase only by 3x, the mesoporosity (pores in the range 2-50 nm) remains unchanged, while the strength of the material increases by up to 300... Having addressed the fragility problem, aerogels are now robust materials, and a variety of applications, ranging from thermal/acoustic insulators to catalyst supports, to platform for sensors, and dielectrics are all within reach. Our approach employs molecular science to manipulate nanoscopic matter for achieving useful macroscopic properties, and in our view it resides at the core of what defines nanotechnology. In that spirit, this technology is expandable in three directions. Thus, we have already crosslinked successfully amine-modified silica, and we anticipate that more rich chemistry will be realized by been creative with the nanoparticle surface modifiers. On the other hand, although we do not expect
International Nuclear Information System (INIS)
Baccetti, Valentina; Visser, Matt
2013-01-01
Even if a probability distribution is properly normalizable, its associated Shannon (or von Neumann) entropy can easily be infinite. We carefully analyze conditions under which this phenomenon can occur. Roughly speaking, this happens when arbitrarily small amounts of probability are dispersed into an infinite number of states; we shall quantify this observation and make it precise. We develop several particularly simple, elementary, and useful bounds, and also provide some asymptotic estimates, leading to necessary and sufficient conditions for the occurrence of infinite Shannon entropy. We go to some effort to keep technical computations as simple and conceptually clear as possible. In particular, we shall see that large entropies cannot be localized in state space; large entropies can only be supported on an exponentially large number of states. We are for the time being interested in single-channel Shannon entropy in the information theoretic sense, not entropy in a stochastic field theory or quantum field theory defined over some configuration space, on the grounds that this simple problem is a necessary precursor to understanding infinite entropy in a field theoretic context. (paper)
DEFF Research Database (Denmark)
Srba, Jiří
2002-01-01
This paper provides a comprehensive summary of equivalence checking results for infinite-state systems. References to the relevant papers will be updated continuously according to the development in the area. The most recent version of this document is available from the web-page http://www.brics.dk/~srba/roadmap....
Justification by Infinite Loops
Peijnenburg, A.J.M.; Atkinson, David
2010-01-01
In an earlier paper we have shown that a proposition can have a well-defined probability value, even if its justification consists of an infinite linear chain. In the present paper we demonstrate that the same holds if the justification takes the form of a closed loop. Moreover, in the limit that
On infinitely divisible semimartingales
DEFF Research Database (Denmark)
Basse-O'Connor, Andreas; Rosiński, Jan
2015-01-01
processes, including linear fractional processes, mixed moving averages, and supOU processes, as particular cases. The proof of the main theorem relies on series representations of jumps of cadlag infinitely divisible processes given in Basse-O'Connor and Rosinski [2013, Ann. Probab. 41(6)] combined...... with techniques of stochastic analysis....
Wanko, Jeffrey J.
2009-01-01
This article provides a historical context for the debate between Georg Cantor and Leopold Kronecker regarding the cardinality of different infinities and incorporates the short story "Welcome to the Hotel Infinity," which uses the analogy of a hotel with an infinite number of rooms to help explain this concept. Wanko makes use of this history and…
Knopp, Konrad
1956-01-01
One of the finest expositors in the field of modern mathematics, Dr. Konrad Knopp here concentrates on a topic that is of particular interest to 20th-century mathematicians and students. He develops the theory of infinite sequences and series from its beginnings to a point where the reader will be in a position to investigate more advanced stages on his own. The foundations of the theory are therefore presented with special care, while the developmental aspects are limited by the scope and purpose of the book. All definitions are clearly stated; all theorems are proved with enough detail to ma
Bayramoglu, Gulay; Tekinay, Turgay; Ozalp, V Cengiz; Arica, M Yakup
2015-05-15
Lysozyme is an important polypetide used in medical and food applications. We report a novel magnetic strong cation exchange beads for efficient purification of lysozyme from chicken egg white. Magnetic chitosan (MCHT) beads were synthesized via phase inversion method, and then grafted with poly(glycidyl methacrylate) (p(GMA)) via the surface-initiated atom transfer radical polymerization (SI-ATRP). Epoxy groups of the grafted polymer, were modified into strong cation-exchange groups (i.e., sulfonate groups) in the presence of sodium sulfite. The MCTH and MCTH-g-p(GMA)-SO3H beads were characterized by ATR-FTIR, SEM, and VSM. The sulphonate groups content of the modified MCTH-g-p(GMA)-4 beads was found to be 0.53mmolg(-1) of beads by the potentiometric titration method. The MCTH-g-p(GMA)-SO3H beads were first used as an ion-exchange support for adsorption of lysozyme from aqueous solution. The influence of different experimental parameters such as pH, contact time, and temperature on the adsorption process was evaluated. The maximum adsorption capacity was found to be 208.7mgg(-1) beads. Adsorption of lysozyme on the MCTH-g-p(GMA)-SO3H beads fitted to Langmuir isotherm model and followed the pseudo second-order kinetic. More than 93% of the adsorbed lysozyme was desorbed using Na2CO3 solution (pH 11.0). The purity of the lysozyme was checked by HPLC and SDS gel electrophoresis. In addition, the MCTH-g-p(GMA)-SO3H beads prepared in this work showed promising potential for separation of various anionic molecules. Copyright © 2015 Elsevier B.V. All rights reserved.
Planar stochastic hyperbolic infinite triangulations
Curien, Nicolas
2014-01-01
Pursuing the approach of Angel & Ray, we introduce and study a family of random infinite triangulations of the full-plane that satisfy a natural spatial Markov property. These new random lattices naturally generalize Angel & Schramm's Uniform Infinite Planar Triangulation (UIPT) and are hyperbolic in flavor. We prove that they exhibit a sharp exponential volume growth, are non-Liouville, and that the simple random walk on them has positive speed almost surely. We conjecture that these infinit...
An infinite set of conservation laws for infinite symmetries
Rosenhaus, V.
2007-06-01
We consider partial differential equations of a variational problem admitting infinite-dimensional Lie symmetry algebras parameterized by arbitrary functions of dependent variables and their derivatives. We show that unlike differential systems with symmetry algebras parameterized by arbitrary functions of independent variables, these equations have infinite sets of essential conservation laws.
Riemann surfaces of infinite genus
Feldman, Joel S; Trubowitz, Eugene
2003-01-01
In this book, Riemann surfaces of infinite genus are constructed geometrically by pasting together plane domains and handles. To achieve a meaningful generalization of the classical theory of Riemann surfaces to the case of infinite genus, one must impose restrictions on the asymptotic behavior of the Riemann surface. In the construction carried out here, these restrictions are formulated in terms of the sizes and locations of the handles and in terms of the gluing maps. The approach used in this book has two main attractions. The first is that much of the classical theory of Riemann surfaces, including the Torelli theorem, can be generalized to this class. The second is that solutions of Kadomcev-Petviashvilli equations can be expressed in terms of theta functions associated with Riemann surfaces of infinite genus constructed in the book. Both of these are developed here. The authors also present in detail a number of important examples of Riemann surfaces of infinite genus (hyperelliptic surfaces of infinit...
Fujisawa, Shuji; Togawa, Eiji; Kuroda, Katsushi
2017-01-09
Cellulose nanofibril (CNF) is a promising nanofiller for polymer nanocomposite materials, and a critical challenge in designing these materials is organization of the nanostructure using a facile process. Here, we report a facile aqueous preparation process for nanostructured polystyrene (PS)/CNF composites via the formation of a CNF-stabilized Pickering emulsion. PS nanoparticles, with a narrow size distribution, were synthesized by free radical polymerization in water using CNF as a stabilizer. The nanoparticles were easily collected by filtration, and the resulting material had a composite structure of PS nanoparticles embedded in a CNF framework. The PS/CNF nanocomposite showed high optical transparency, strength, and thermal dimensional stability. Thus, this technique provides a simple and environmentally friendly method for the preparation of novel CNF/polymer nanocomposite materials.
Sun, Zheng; Xu, Yuan-Ping; Li, Sheng; George, Thomas F
2011-02-10
Through combining the electron transition process and dipole moment evolution as well as electron-phonon coupling, molecular dynamics calculations show that the radiative decay of singlet excitons in a conjugated polymer, such as a polymer light-emitting diode (PLED), is largely determined by the evolution of the dipole moment. Without an electric field, the decay life of a singlet exciton is about 1 ns. Once an electric field is applied and exceeds a critical value, with electron-phonon coupling, the original lattice structure evolves into two new localized lattice distortions, consistent with the experimental results. Owing to the new lattice structure and self-trapping, the dipole moment rapidly decreases to zero within 5 fs, eliminating the radiative decay of the singlet exciton.
Accelerated sampling by infinite swapping of path integral molecular dynamics with surface hopping
Lu, Jianfeng; Zhou, Zhennan
2018-02-01
To accelerate the thermal equilibrium sampling of multi-level quantum systems, the infinite swapping limit of a recently proposed multi-level ring polymer representation is investigated. In the infinite swapping limit, the ring polymer evolves according to an averaged Hamiltonian with respect to all possible surface index configurations of the ring polymer and thus connects the surface hopping approach to the mean-field path-integral molecular dynamics. A multiscale integrator for the infinite swapping limit is also proposed to enable efficient sampling based on the limiting dynamics. Numerical results demonstrate the huge improvement of sampling efficiency of the infinite swapping compared with the direct simulation of path-integral molecular dynamics with surface hopping.
Semi-infinite fractional programming
Verma, Ram U
2017-01-01
This book presents a smooth and unified transitional framework from generalised fractional programming, with a finite number of variables and a finite number of constraints, to semi-infinite fractional programming, where a number of variables are finite but with infinite constraints. It focuses on empowering graduate students, faculty and other research enthusiasts to pursue more accelerated research advances with significant interdisciplinary applications without borders. In terms of developing general frameworks for theoretical foundations and real-world applications, it discusses a number of new classes of generalised second-order invex functions and second-order univex functions, new sets of second-order necessary optimality conditions, second-order sufficient optimality conditions, and second-order duality models for establishing numerous duality theorems for discrete minmax (or maxmin) semi-infinite fractional programming problems. In the current interdisciplinary supercomputer-oriented research envi...
Papendorf, Benjamin; Nonnenmacher, Katharina; Ionescu, Emanuel; Kleebe, Hans-Joachim; Riedel, Ralf
2011-04-04
The present study focuses on the synthesis and ceramization of novel hafnium-alkoxide-modified silazanes as well as on their microstructure evolution at high temperatures. The synthesis of hafnia-modified polymer-derived SiCN ceramic nanocomposites is performed via chemical modification of a polysilazane and of a cyclotrisilazane, followed by cross-linking and pyrolysis in argon atmosphere. Spectroscopic investigation (i.e., NMR, FTIR, and Raman) shows that the hafnium alkoxide reacts with the N-H groups of the cyclotrisilazane; in the case of polysilazane, reactions of N-H as well as Si-H groups with the alkoxide are observed. Consequently, scanning and transmission electron microscopy studies reveal that the ceramic nanocomposites obtained from cyclotrisilazane and polysilazane exhibited markedly different microstructures, which is a result of the different reaction pathways of the hafnium alkoxide with cyclotrisilazane and with polysilazane. Furthermore, the two prepared ceramic nanocomposites are unexpectedly found to exhibit extremely different high-temperature behavior with respect to decomposition and crystallization; this essential difference is found to be related to the different distribution of hafnium throughout the ceramic network in the two samples. Thus, the homogeneous distribution of hafnium observed in the polysilazane-derived ceramic leads to an enhanced thermal stability with respect to decomposition, whereas the local enrichment of hafnium within the matrix of the cyclotrisilazane-based sample induces a pronounced decomposition upon annealing at high temperatures. The results indicate that the chemistry and architecture of the precursor has a crucial effect on the microstructure of the resulting ceramic material and consequently on its high-temperature behavior. Copyright © 2011 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.
Optimal Infinite Runs in One-Clock Priced Timed Automata
DEFF Research Database (Denmark)
David, Alexandre; Ejsing-Duun, Daniel; Fontani, Lisa
We address the problem of finding an infinite run with the optimal cost-time ratio in a one-clock priced timed automaton and pro- vide an algorithmic solution. Through refinements of the quotient graph obtained by strong time-abstracting bisimulation partitioning, we con- struct a graph with time...... of the one-clock priced timed automaton....
On infinite regular and chiral maps
Arredondo, John A.; Valdez, Camilo Ramírez y Ferrán
2015-01-01
We prove that infinite regular and chiral maps take place on surfaces with at most one end. Moreover, we prove that an infinite regular or chiral map on an orientable surface with genus can only be realized on the Loch Ness monster, that is, the topological surface of infinite genus with one end.
Teleportation schemes in infinite dimensional Hilbert spaces
International Nuclear Information System (INIS)
Fichtner, Karl-Heinz; Freudenberg, Wolfgang; Ohya, Masanori
2005-01-01
The success of quantum mechanics is due to the discovery that nature is described in infinite dimension Hilbert spaces, so that it is desirable to demonstrate the quantum teleportation process in a certain infinite dimensional Hilbert space. We describe the teleportation process in an infinite dimensional Hilbert space by giving simple examples
Kodama, Yukinobu; Shiokawa, Yumi; Nakamura, Tadahiro; Kurosaki, Tomoaki; Aki, Keisei; Nakagawa, Hiroo; Muro, Takahiro; Kitahara, Takashi; Higuchi, Norihide; Sasaki, Hitoshi
2014-01-01
We developed a novel small interfering RNA (siRNA) delivery system using a ternary complex with polyethyleneimine (PEI) and γ-polyglutamic acid (γ-PGA), which showed silencing effect and no cytotoxicity. The binary complexes of siRNA with PEI were approximately 73-102 nm in particle size and 45-52 mV in ζ-potential. The silencing effect of siRNA/PEI complexes increased with an increase of PEI, and siRNA/PEI complexes with a charge ratio greater than 16 showed significant luciferase knockdown in a mouse colon carcinoma cell line regularly expressing luciferase (Colon26/Luc cells). However, strong cytotoxicity and blood agglutination were observed in the siRNA/Lipofectamine complex and siRNA/PEI16 complex. Recharging cationic complexes with an anionic compound was reported to be a promising method for overcoming these toxicities. We therefore prepared ternary complexes of siRNA with PEI (charge ratio 16) by the addition of γ-PGA to reduce cytotoxicity and deliver siRNA. As expected, the cytotoxicity of the ternary complexes decreased with an increase of γ-PGA content, which decreased the ζ-potential of the complexes. A strong silencing effect comparable to siRNA/Lipofectamine complex was discovered in ternary complexes including γ-PGA with an anionic surface charge. The high incorporation of ternary complexes into Colon26/Luc cells was confirmed with fluorescence microcopy. Having achieved knockdown of an exogenously transfected gene, the ability of the complex to mediate knockdown of an endogenous housekeeping gene, glyceraldehyde 3-phosphate dehydrogenase (GAPDH), was assessed in B16-F10 cells. The ternary complex (siRNA/PEI16/γ-PGA12 complex) exhibited a significant GAPDH knockdown effect. Thus, we developed a useful siRNA delivery system.
Hamieh, Tayssir; Fadlallah, Mohamed-Baker; Schultz, Jacques
2002-09-06
In this paper, the inverse gas chromatography (IGC) technique was used to calculate the acid-base superficial characteristics of some solid substrates such as oxides, polymer and polymer adsorbed on oxide. The acid-base constants were calculated for many solids: Monogal, MgO, ZnO, SiO2 and Al2O3, four different carbon fibres and polymers such as poly(methyl methacrylate) (PMMA) at various tacticities adsorbed on alumina or silica. The determination, by IGC, of the specific free enthalpy deltaG(a)sp of adsorption corresponding to the specific interactions of polar molecules with the solid, as a function of the temperature, allowed to obtain the specific enthalpy deltaH(a)sp and specific entropy deltaS(a)sp. Knowing deltaH(a)sp of the various polar molecules, we were able to determine the acidic constant K(A) and basic constant K(D), the two constants characterizing solid substrates like PMMA, PMMA-SiO2 or PMMA-Al2O3, using the following classical expression: - deltaH(a)sp = K(A)DN + K(D)AN where DN and AN are respectively the electron donor and acceptor numbers of the solid substrates. This study showed an important effect of the tacticity on the acid-base properties. On the other hand, we proved that the previous relation was not correct in many cases and especially for some oxides (as MgO, ZnO and Monogal) and carbon fibres. We proposed a new relationship by adding a third parameter K reflecting the amphoteric character of the solid according to: - deltaH(a)sp = K(A)DN + K(D)AN - KDN x AN.
Escape rate scaling in infinite measure preserving systems
International Nuclear Information System (INIS)
Munday, Sara; Knight, Georgie
2016-01-01
We investigate the scaling of the escape rate from piecewise linear dynamical systems displaying intermittency due to the presence of an indifferent fixed point. Strong intermittent behaviour in the dynamics can result in the system preserving an infinite measure. We define a neighbourhood of the indifferent fixed point to be a hole through which points escape and investigate the scaling of the rate of this escape as the length of the hole decreases, both in the finite measure preserving case and infinite measure preserving case. In the infinite measure preserving systems we observe logarithmic corrections to and polynomial scaling of the escape rate with hole length. Finally we conjecture a relationship between the wandering rate and the observed scaling of the escape rate. (paper)
Reduction of infinite dimensional equations
Directory of Open Access Journals (Sweden)
Zhongding Li
2006-02-01
Full Text Available In this paper, we use the general Legendre transformation to show the infinite dimensional integrable equations can be reduced to a finite dimensional integrable Hamiltonian system on an invariant set under the flow of the integrable equations. Then we obtain the periodic or quasi-periodic solution of the equation. This generalizes the results of Lax and Novikov regarding the periodic or quasi-periodic solution of the KdV equation to the general case of isospectral Hamiltonian integrable equation. And finally, we discuss the AKNS hierarchy as a special example.
Automated Analysis of Infinite Scenarios
DEFF Research Database (Denmark)
Buchholtz, Mikael
2005-01-01
The security of a network protocol crucially relies on the scenario in which the protocol is deployed. This paper describes syntactic constructs for modelling network scenarios and presents an automated analysis tool, which can guarantee that security properties hold in all of the (infinitely many......) instances of a scenario. The tool is based on control flow analysis of the process calculus LySa and is applied to the Bauer, Berson, and Feiertag protocol where is reveals a previously undocumented problem, which occurs in some scenarios but not in other....
Squashed entanglement in infinite dimensions
Shirokov, M. E.
2016-03-01
We analyse two possible definitions of the squashed entanglement in an infinite-dimensional bipartite system: direct translation of the finite-dimensional definition and its universal extension. It is shown that the both definitions produce the same lower semicontinuous entanglement measure possessing all basis properties of the squashed entanglement on the set of states having at least one finite marginal entropy. It is also shown that the second definition gives an adequate lower semicontinuous extension of this measure to all states of the infinite-dimensional bipartite system. A general condition relating continuity of the squashed entanglement to continuity of the quantum mutual information is proved and its corollaries are considered. Continuity bound for the squashed entanglement under the energy constraint on one subsystem is obtained by using the tight continuity bound for quantum conditional mutual information (proved in the Appendix by using Winter's technique). It is shown that the same continuity bound is valid for the entanglement of formation. As a result the asymptotic continuity of the both entanglement measures under the energy constraint on one subsystem is proved.
Squashed entanglement in infinite dimensions
International Nuclear Information System (INIS)
Shirokov, M. E.
2016-01-01
We analyse two possible definitions of the squashed entanglement in an infinite-dimensional bipartite system: direct translation of the finite-dimensional definition and its universal extension. It is shown that the both definitions produce the same lower semicontinuous entanglement measure possessing all basis properties of the squashed entanglement on the set of states having at least one finite marginal entropy. It is also shown that the second definition gives an adequate lower semicontinuous extension of this measure to all states of the infinite-dimensional bipartite system. A general condition relating continuity of the squashed entanglement to continuity of the quantum mutual information is proved and its corollaries are considered. Continuity bound for the squashed entanglement under the energy constraint on one subsystem is obtained by using the tight continuity bound for quantum conditional mutual information (proved in the Appendix by using Winter’s technique). It is shown that the same continuity bound is valid for the entanglement of formation. As a result the asymptotic continuity of the both entanglement measures under the energy constraint on one subsystem is proved.
Integrable systems in the infinite genus limit
Gesztesy, Fritz
2001-01-01
We provide an elementary approach to integrable systems associated with hyperelliptic curves of infinite genus. In particular, we explore the extent to which the classical Burchnall-Chaundy theory generalizes in the infinite genus limit, and systematically study the effect of Darboux transformations for the KdV hierarchy on such infinite genus curves. Our approach applies to complex-valued periodic solutions of the KdV hierarchy and naturally identifies the Riemann surface familiar from stand...
Sehaqui, Houssine; Morimune, Seira; Nishino, Takashi; Berglund, Lars A
2012-11-12
Nonwoven membranes based on electrospun fibers are of great interest in applications such as biomedical, filtering, and protective clothing. The poor mechanical performance is a limitation, as is some of the electrospinning solvents. To address these problems, porous nonwoven membranes based on nanofibrillated cellulose (NFC) modified by a hydroxyethyl cellulose (HEC) polymer coating are prepared. NFC/HEC aqueous suspensions are subjected to simple vacuum filtration in a paper-making fashion, followed by supercritical CO(2) drying. These nonwoven nanocomposite membranes are truly nanostructured and exhibit a nanoporous network structure with high specific surface area, as analyzed by nitrogen adsorption and FE-SEM. Mechanical properties evaluated by tensile tests show high strength combined with remarkably high strain to failure of up to 55%. XRD analysis revealed significant fibril realignment during tensile stretching. After postdrawing of the random mats, the modulus and strength are strongly increased. The present preparation route uses components from renewable resources, is environmentally friendly, and results in permeable membranes of exceptional mechanical performance.
Cao, Ziyang; Feng, Liangzhu; Zhang, Guobing; Wang, Junxia; Shen, Song; Li, Dongdong; Yang, Xianzhu
2018-02-01
Near-infrared (NIR) light-induced photothermal therapy (PTT) has attracted much interest in recent years. In the NIR region, tissue penetration ability of the second biological near-infrared window (1000-1350 nm) is recognized to be stronger than that of the first window (650-950 nm). However, NIR light absorbers in the second NIR region (NIR-II) have been scant even though various NIR light absorbers in the first NIR region (NIR-I) have been widely explored. In this work, a thieno-isoindigo derivative-based semiconducting polymer, PBTPBF-BT, were formulated into PEGylated nanoparticles. The obtained nanoparticle NP PBTPBF-BT exhibited strong absorption in NIR-II region, inherent high photothermal conversion efficacy, and excellent photostability. The in vitro and in vivo PTT study employing 1064 nm laser in NIR-II window revealed that NP PBTPBF-BT could efficiently ablate tumor cell at a power density of 0.42 W/cm 2 (the skin tolerance threshold value). Moreover, NP PBTPBF-BT with excellent photostability exhibited enhanced photoacoustic (PA) imaging of tumor in living mice, suggesting the great probability of using NP PBTPBF-BT for in vivo PA imaging-guided PTT in the NIR-II window. Copyright © 2017 Elsevier Ltd. All rights reserved.
Smagin, A. V.
2017-01-01
The impact of two types of strongly swelling polymer hydrogel (SSPH) on the water retention capacity of quartz sand in pure water and Ag+ solutions (10-100 mg/l) has been studied by using a centrifugation method in a wide range of thermodynamic water potential (Gibbs energy) from 0 to 3030 J/kg. The experimental data for the water retention curves (WRC) were estimated by the van Genuchten model. Both hydrogels - the Aquasorb preparation (Germany) with hydrophilic properties and high degree of swelling in pure water (700-1000 g H2O/g) and the new Russian amphiphilic SSPH with a peat filler (degree of swelling 500-700 g H2O/g) were very effective as water adsorbing soil conditioners in relatively small doses from 0.05 to 0.3% per mass of dry (105°C) soil substrate. The water retention capacity of sandy substrate increases under the influence of SSPH with 2-3 times up to the level of native loamy sands and loams. Adding Ag+ to the water solution results just for the highest concentration of SSPH (0.3%) and iconic silver (100 mg/l) in a significant decrease of the water retention in the soil-gel compositions.
Infinite Horizon Discrete Time Control Problems for Bounded Processes
Directory of Open Access Journals (Sweden)
2009-03-01
Full Text Available We establish Pontryagin Maximum Principles in the strong form for infinite horizon optimal control problems for bounded processes, for systems governed by difference equations. Results due to Ioffe and Tihomirov are among the tools used to prove our theorems. We write necessary conditions with weakened hypotheses of concavity and without invertibility, and we provide new results on the adjoint variable. We show links between bounded problems and nonbounded ones. We also give sufficient conditions of optimality.
Optimality Conditions for Nondifferentiable Multiobjective Semi-Infinite Programming Problems
Barilla, D.; Caristi, G.; Puglisi, A.
2016-01-01
We have considered a multiobjective semi-infinite programming problem with a feasible set defined by inequality constraints. First we studied a Fritz-John type necessary condition. Then, we introduced two constraint qualifications and derive the weak and strong Karush-Kuhn-Tucker (KKT in brief) types necessary conditions for an efficient solution of the considered problem. Finally an extension of a Caristi-Ferrara-Stefanescu result for the ( $\\mathrm{\\Phi },\\rho $ )-invexity is proved, and so...
Czech Academy of Sciences Publication Activity Database
Calore, L.; Cavinato, g.; Canton, P.; Peruzzo, L.; Banavali, R.; Jeřábek, Karel; Corain, B.
2012-01-01
Roč. 391, AUG 30 (2012), s. 114-120 ISSN 0020-1693 Institutional support: RVO:67985858 Keywords : strongly acidic cross-linked polymer * frameworks * gold(0) nanoclusters Subject RIV: CI - Industrial Chemistry, Chemical Engineering Impact factor: 1.687, year: 2012
Improving the Instruction of Infinite Series
Lindaman, Brian; Gay, A. Susan
2012-01-01
Calculus instructors struggle to teach infinite series, and students have difficulty understanding series and related concepts. Four instructional strategies, prominently used during the calculus reform movement, were implemented during a 3-week unit on infinite series in one class of second-semester calculus students. A description of each…
Dynamical entropy for infinite quantum systems
International Nuclear Information System (INIS)
Hudetz, T.
1990-01-01
We review the recent physical application of the so-called Connes-Narnhofer-Thirring entropy, which is the successful quantum mechanical generalization of the classical Kolmogorov-Sinai entropy and, by its very conception, is a dynamical entropy for infinite quantum systems. We thus comparingly review also the physical applications of the classical dynamical entropy for infinite classical systems. 41 refs. (Author)
Understanding the Behaviour of Infinite Ladder Circuits
Ucak, C.; Yegin, K.
2008-01-01
Infinite ladder circuits are often encountered in undergraduate electrical engineering and physics curricula when dealing with series and parallel combination of impedances, as a part of filter design or wave propagation on transmission lines. The input impedance of such infinite ladder circuits is derived by assuming that the input impedance does…
On the Infinite Loch Ness monster
Arredondo, John A.; Maluendas, Camilo Ramírez
2017-01-01
In this paper we present in a topological way the construction of the orientable surface with only one end and infinite genus, called \\emph{The Infinite Loch Ness Monster}. In fact, we introduce a flat and hyperbolic construction of this surface. We discuss how the name of this surface has evolved and how it has been historically understood.
Infinite dimensional differential games with hybrid controls
Indian Academy of Sciences (India)
Abstract. A two-person zero-sum infinite dimensional differential game of infinite duration with discounted payoff involving hybrid controls is studied. The minimizing player is allowed to take continuous, switching and impulse controls whereas the maxi- mizing player is allowed to take continuous and switching controls.
Infinite Dimensional Differential Games with Hybrid Controls
Indian Academy of Sciences (India)
... zero-sum infinite dimensional differential game of infinite duration with discounted payoff involving hybrid controls is studied. The minimizing player is allowed to take continuous, switching and impulse controls whereas the maximizing player is allowed to take continuous and switching controls. By taking strategies in the ...
Properties of semi-infinite nuclei
International Nuclear Information System (INIS)
El-Jaick, L.J.; Kodama, T.
1976-04-01
Several relations among density distributions and energies of semi-infinite and infinite nuclei are iventigated in the framework of Wilets's statistical model. The model is shown to be consistent with the theorem of surface tension given by Myers and Swiatecki. Some numerical results are shown by using an appropriate nuclear matter equation of state
Variational Infinite Hidden Conditional Random Fields
Bousmalis, Konstantinos; Zafeiriou, Stefanos; Morency, Louis-Philippe; Pantic, Maja; Ghahramani, Zoubin
2015-01-01
Hidden conditional random fields (HCRFs) are discriminative latent variable models which have been shown to successfully learn the hidden structure of a given classification problem. An Infinite hidden conditional random field is a hidden conditional random field with a countably infinite number of
A survey of infinite time Turing machines
Hamkins, J.D.
2007-01-01
Infinite time Turing machines extend the operation of ordinary Turing machines into transfinite ordinal time, thereby providing a natural model of infinitary computability, with robust notions of computability and decidability on the reals, while remaining close to classical concepts of
Infinite genus surfaces and irrational polygonal billiards
Valdez, Ferrán
2009-01-01
We prove that the natural invariant surface associated with the billiard game on an irrational polygonal table is homeomorphic to the Loch Ness monster, that is, the only orientable infinite genus topological real surface with exactly one end.
Impulsive fractional differential inclusions with infinite delay
Directory of Open Access Journals (Sweden)
Khalida Aissani
2013-11-01
Full Text Available In this article, we apply Bohnenblust-Karlin's fixed point theorem to prove the existence of mild solutions for a class of impulsive fractional equations inclusions with infinite delay. An example is given to illustrate the theory.
Infinite Coordination Polymer Nano- and Micro-Particles
2015-06-12
repeatable synthesis of relatively mono -disperse particles (i.e., size control) and the high-yielding covalent attachment of oligonucleotides to the...the DLS results. After synthesis and characterization of the mono -disperse particles, which contained pendant azide 5 moieties, oligonucleotides...the nucleus in blue, whereas the Cy5 dye attached to DNA is red. 6 processes. To test our hypothesis, cellular uptake was examined in HeLa
Fractional supersymmetry and infinite dimensional lie algebras
International Nuclear Information System (INIS)
Rausch de Traubenberg, M.
2001-01-01
In an earlier work extensions of supersymmetry and super Lie algebras were constructed consistently starting from any representation D of any Lie algebra g. Here it is shown how infinite dimensional Lie algebras appear naturally within the framework of fractional supersymmetry. Using a differential realization of g this infinite dimensional Lie algebra, containing the Lie algebra g as a sub-algebra, is explicitly constructed
Linear (semi-)infinite programs and cooperative games
Timmer, Judith B.; Llorca, Natividad; Borm, Peter; Peters, Hans
2002-01-01
In 1975 Stef Tijs defended his Ph.D. thesis entitled “Semi-infinite and infinite matrix games and bimatrix games��?. Following this, his paper “Semi-infinite linear programs and semi-infinite matrix games��? was pub- lished in 1979. Both these works deal with programs and noncoopera- tive games in a
Optimality Conditions for Nondifferentiable Multiobjective Semi-Infinite Programming Problems
Directory of Open Access Journals (Sweden)
D. Barilla
2016-01-01
Full Text Available We have considered a multiobjective semi-infinite programming problem with a feasible set defined by inequality constraints. First we studied a Fritz-John type necessary condition. Then, we introduced two constraint qualifications and derive the weak and strong Karush-Kuhn-Tucker (KKT in brief types necessary conditions for an efficient solution of the considered problem. Finally an extension of a Caristi-Ferrara-Stefanescu result for the (Φ,ρ-invexity is proved, and some sufficient conditions are presented under this weak assumption. All results are given in terms of Clark subdifferential.
Infinite Random Graphs as Statistical Mechanical Models
DEFF Research Database (Denmark)
Durhuus, Bergfinnur Jøgvan; Napolitano, George Maria
2011-01-01
We discuss two examples of infinite random graphs obtained as limits of finite statistical mechanical systems: a model of two-dimensional dis-cretized quantum gravity defined in terms of causal triangulated surfaces, and the Ising model on generic random trees. For the former model we describe...
On How to Arrange Infinitely many Marriages!
Indian Academy of Sciences (India)
Home; Journals; Resonance – Journal of Science Education; Volume 6; Issue 2. On How to Arrange Infinitely many Marriages! B Sury. Classroom Volume 6 Issue 2 February 2001 pp 71-73. Fulltext. Click here to view fulltext PDF. Permanent link: http://www.ias.ac.in/article/fulltext/reso/006/02/0071-0073. Author Affiliations.
Infinite games and $sigma$-porosity
Czech Academy of Sciences Publication Activity Database
Doležal, Martin; Preiss, D.; Zelený, M.
2016-01-01
Roč. 215, č. 1 (2016), s. 441-457 ISSN 0021-2172 Institutional support: RVO:67985840 Keywords : infinite games Subject RIV: BA - General Mathematics Impact factor: 0.796, year: 2016 http://link.springer.com/article/10.1007%2Fs11856-016-1383-9
Self-Assembly of Infinite Structures
Directory of Open Access Journals (Sweden)
Scott M. Summers
2009-06-01
Full Text Available We review some recent results related to the self-assembly of infinite structures in the Tile Assembly Model. These results include impossibility results, as well as novel tile assembly systems in which shapes and patterns that represent various notions of computation self-assemble. Several open questions are also presented and motivated.
Generated topology on infinite sets by ultrafilters
Directory of Open Access Journals (Sweden)
Alireza Bagheri Salec
2017-10-01
Full Text Available Let $X$ be an infinite set, equipped with a topology $tau$. In this paper we studied the relationship between $tau$, and ultrafilters on $X$. We can discovered, among other thing, some relations of the Robinson's compactness theorem, continuity and the separation axioms. It is important also, aspects of communication between mathematical concepts.
Model Checking Structured Infinite Markov Chains
Remke, Anne Katharina Ingrid
2008-01-01
In the past probabilistic model checking hast mostly been restricted to finite state models. This thesis explores the possibilities of model checking with continuous stochastic logic (CSL) on infinite-state Markov chains. We present an in-depth treatment of model checking algorithms for two special
Infinite games and $sigma$-porosity
Czech Academy of Sciences Publication Activity Database
Doležal, Martin; Preiss, D.; Zelený, M.
2016-01-01
Roč. 215, č. 1 (2016), s. 441-457 ISSN 0021-2172 Institutional support: RVO:67985840 Keywords : infinite game s Subject RIV: BA - General Mathematics Impact factor: 0.796, year: 2016 http://link.springer.com/article/10.1007%2Fs11856-016-1383-9
Infinite matrices, wavelet coefficients and frames
Directory of Open Access Journals (Sweden)
N. A. Sheikh
2004-01-01
Full Text Available We study the action of A on f∈L2(ℝ and on its wavelet coefficients, where A=(almjklmjk is a double infinite matrix. We find the frame condition for A-transform of f∈L2(ℝ whose wavelet series expansion is known.
Torsional vibrations of infinite composite poroelastic cylinders
African Journals Online (AJOL)
user
(1963) studied dispersion of axially symmetric waves in composite elastic rods of infinite extent. Armenakas (1965) discussed .... Here parameter 'λ' is introduced in order to account the difference in sign in the recurrence relations to the derivatives of aforesaid. Bessel functions, respectively. By ignoring the liquid effects in ...
Gamma spectrometry of infinite 4Π geometry
International Nuclear Information System (INIS)
Nordemann, D.J.R.
1987-07-01
Owing to the weak absorption og gamma radiation by matter, gamma-ray spectrometry may be applied to samples of great volume. A very interesting case is that of the gamma-ray spectrometry applied with 4Π geometry around the detector on a sample assumed to be of infinite extension. The determination of suitable efficiencies allows this method to be quantitative. (author) [pt
History of the Infinitely Small and the Infinitely Large in Calculus.
Kleiner, Israel
2001-01-01
Considers examples of aspects of the infinitely small and large as they unfolded in the history of calculus from the 17th through the 20th centuries. Presents didactic observations at relevant places in the historical account. (Author/MM)
Yang, Li; Jensen, David S; Vail, Michael A; Dadson, Andrew; Linford, Matthew R
2010-12-03
We describe direct polymer attachment to hydrogen and deuterium-terminated diamond (HTD and DTD) surfaces using a radical initiator (di-tert-amyl peroxide, DTAP), a reactive monomer (styrene) and a crosslinking agent (divinylbenzene, DVB) to create polystyrene encapsulated diamond. Chemisorbed polystyrene is sulfonated with sulfuric acid in acetic acid. Surface changes were followed by X-ray photoelectron spectroscopy (XPS), time-of-flight secondary ion mass spectrometry (ToF-SIMS) and diffuse reflectance Fourier transform infrared spectroscopy (DRIFT). Finally, both polystyrene-modified DTD and sulfonated styrene-modified DTD were used in solid phase extraction (SPE). Percent recovery and column capacity were investigated for both phenyl (polystyrene) and sulfonic acid treated polystyrene SPE columns. These diamond-based SPE supports are stable under basic conditions, which is not the case for silica-based SPE supports. Copyright © 2010. Published by Elsevier B.V.
Gauge fields and infinite chains of dualities
Energy Technology Data Exchange (ETDEWEB)
Boulanger, Nicolas [Service de Mécanique et Gravitation, Université de Mons - UMONS,20 place du Parc, B-7000 Mons (Belgium); Sundell, Per [Departamento de Ciencias Físicas, Universidad Andres Bello - UNAB,Av. República 252, Santiago (Chile); West, Peter [Department of Mathematics, King’s College,London WC2R 2LS (United Kingdom)
2015-09-28
We show that the particle states of Maxwell’s theory, in D dimensions, can be represented in an infinite number of ways by using different gauge fields. Using this result we formulate the dynamics in terms of an infinite set of duality relations which are first order in space-time derivatives. We derive a similar result for the three form in eleven dimensions where such a possibility was first observed in the context of E{sub 11}. We also give an action formulation for some of the gauge fields. In this paper we give a pedagogical account of the Lorentz and gauge covariant formulation of the irreducible representations of the Poincaré group, used previously in higher spin theories, as this plays a key role in our constructions. It is clear that our results can be generalised to any particle.
Functional differential equations with infinite delay
Hino, Yoshiyuki; Naito, Toshiki
1991-01-01
In the theory of functional differential equations with infinite delay, there are several ways to choose the space of initial functions (phase space); and diverse (duplicated) theories arise, according to the choice of phase space. To unify the theories, an axiomatic approach has been taken since the 1960's. This book is intended as a guide for the axiomatic approach to the theory of equations with infinite delay and a culmination of the results obtained in this way. It can also be used as a textbook for a graduate course. The prerequisite knowledge is foundations of analysis including linear algebra and functional analysis. It is hoped that the book will prepare students for further study of this area, and that will serve as a ready reference to the researchers in applied analysis and engineering sciences.
Representations of the infinite symmetric group
Borodin, Alexei
2016-01-01
Representation theory of big groups is an important and quickly developing part of modern mathematics, giving rise to a variety of important applications in probability and mathematical physics. This book provides the first concise and self-contained introduction to the theory on the simplest yet very nontrivial example of the infinite symmetric group, focusing on its deep connections to probability, mathematical physics, and algebraic combinatorics. Following a discussion of the classical Thoma's theorem which describes the characters of the infinite symmetric group, the authors describe explicit constructions of an important class of representations, including both the irreducible and generalized ones. Complete with detailed proofs, as well as numerous examples and exercises which help to summarize recent developments in the field, this book will enable graduates to enhance their understanding of the topic, while also aiding lecturers and researchers in related areas.
Controllability of impulsive functional differential systems with infinite delay in Banach spaces
International Nuclear Information System (INIS)
Chang Yongkui
2007-01-01
The paper establishes a sufficient condition for the controllability of the first-order impulsive functional differential systems with infinite delay in Banach spaces. We use Schauder's fixed point theorem combined with a strongly continuous operator semigroup. An example is given to illustrate our results
The conduct of the sample average when the first moment is infinite
Mijnheer, J.L.
1968-01-01
Many books about probability and statistics only mention the weak and the strong law of large numbers for samples from distributions with finite expectation. However, these laws also hold for distributions with infinite expectation and then the sample average has to go to infinity with increasing
on the convergence of a new iterative algorithm of three infinite ...
Indian Academy of Sciences (India)
20
feasibility problems for an infinite family of quasi-φ-asymptotically nonexpansive mappings and obtained some strong convergence theorems under suitable conditions in Banach space. In the same year, Bunyawat and Suantai [5] introduced an iterative method for finding a common fixed point of a countable family of ...
Infinite degeneracy of states in quantum gravity
International Nuclear Information System (INIS)
Hackett, Jonathan; Wan Yidun
2011-01-01
The setting of Braided Ribbon Networks is used to present a general result in spin-networks embedded in manifolds: the existence of an infinite number of species of conserved quantities. Restricted to three-valent networks the number of such conserved quantities in a given network is shown to be determined by the number of nodes in the network. The implication of these conserved quantities is discussed in the context of Loop Quantum Gravity.
Comments related to infinite wedge representations
Grieve, Nathan
2016-01-01
We study the infinite wedge representation and show how it is related to the universal extension of $g[t,t^{-1}]$ the loop algebra of a complex semi-simple Lie algebra $g$. We also give an elementary proof of the boson-fermion correspondence. Our approach to proving this result is based on a combinatorial construction with partitions combined with an application of the Murnaghan-Nakayama rule.
Infinite Responsibility: An expression of Saintliness
Conceição Soares
2009-01-01
In this paper I will focus my attention in the distinctions embedded in standard moral philosophy, especially in the philosophy of Kant between, on the one hand, duty and supererogation on the other hand, with the aim to contrast them with the Levinas’s perspective, namely his notion of infinite responsibility. My account of Levinas’s philosophy will show that it challenges – breaking down – deeply entrenched distinctions in the dominant strands of moral philosophy, within which the theory of...
Yin, Kaifei; Liu, Anran; Shangguan, Li; Mi, Li; Liu, Xu; Liu, Yuanjian; Zhao, Yuewu; Li, Ying; Wei, Wei; Zhang, Yuanjian; Liu, Songqin
2017-04-15
We developed a new immunofluorescent biosensor by utilizing a novel nanobody (Nb) and iron-polymer-graphene nanocomposites for sensitive detection of 5-enolpyruvylshikimate-3-phosphate synthase from Agrobacdterium tumefaciens strain CP4 (CP4-EPSPS), which considered as biomarkers of genetically modified (GM) crops. Specifically, we prepared iron doped polyacrylic hydrazide modified reduced graphene nanocomposites (Fe@RGO/PAH) by in-situ polymerization approach and subsequent a one-pot reaction with hydrazine. The resulting Fe@RGO/PAH nanocomposites displayed low nonspecific adsorption to analytes (11% quenching caused by nonspecific adsorption) due to electrostatic, energetic and steric effect of the nanocomposites. After Nb immobilizing, the as-prepared Fe@RGO/PAH/Nbs showed good selectivity and high quenching ability (92% quenching) in the presence of antigen (Ag) and polyethylene glycol (PEG) modified CdTe QDs (Ag/QDs@PEG), which is a nearly 4 fold than that of the unmodified GO in same condition. The high quenching ability of Fe@RGO/PAH/Nbs can be used for detection of CP4-EPSPS based on competitive immunoassay with a linearly proportional concentration range of 5-100ng/mL and a detection limit of 0.34ng/mL. The good stability, reproducibility and specificity of the resulting immunofluorescent biosensor are demonstrated and might open a new window for investigation of fluorescent sensing with numerous multifunctional graphene based materials. Copyright © 2016 Elsevier B.V. All rights reserved.
Shen, Wenfei; Tang, Jianguo; Wang, Yao; Liu, Jixian; Huang, Linjun; Chen, Weichao; Yang, Lanlan; Wang, Wei; Wang, Yanxin; Yang, Renqiang; Yun, Jungheum; Belfiore, Laurence A
2017-02-15
A new way was meticulously designed to utilize the localized surface plasmon resonance (LSPR) effect and the light scattering effect of silver nanoplate (Ag-nPl) and core-shell Ag@SiO 2 nanoparticles (Ag@SiO 2 -NPs) to enhance the photovoltaic performances of polymer solar cells (PSCs). To prevent direct contact between silver nanoparticles (Ag-NPs) and photoactive materials which will cause electrons quenching, bare Ag-nPl were spin-coated on indium tin oxide and silica capsulated Ag-NPs were incorporated to a PBDTTT-C-T:PC 71 BM active layer. As a result, the devices incorporated with Ag-nPl and Ag@SiO 2 -NPs showed great enhancements. With the dual effects of Ag-nPl and Ag@SiO 2 -NPs in devices, all wavelength sensitization in the visible range was realized; therefore, the power conversion efficiency (PCE) of PSCs showed a great enhancement of 14.0% to 8.46%, with an increased short-circuit current density of 17.23 mA·cm -2 . The improved photovoltaic performances of the devices were ascribed to the LSPR effect and the light scattering effect of metallic nanoparticles. Apart from optical effects, the charge collection efficiency of PSCs was improved after the incorporation of Ag-nPl.
Supersolids: Solids Having Finite Volume and Infinite Surfaces.
Love, William P.
1989-01-01
Supersolids furnish an ideal introduction to the calculus topic of infinite series, and are useful for combining that topic with integration. Five examples of supersolids are presented, four requiring only a few basic properties of infinite series and one requiring a number of integration principles as well as infinite series. (MNS)
Infinite-Scroll Attractor Generated by the Complex Pendulum Model
Directory of Open Access Journals (Sweden)
Sachin Bhalekar
2013-01-01
Full Text Available We report the finding of the simple nonlinear autonomous system exhibiting infinite-scroll attractor. The system is generated from the pendulum equation with complex-valued function. The proposed system is having infinitely many saddle points of index two which are responsible for the infinite-scroll attractor.
The nominalized infinitive in French: structure and change
Sleeman, P.
2010-01-01
Many European languages have both nominal and verbal nominalized infinitives. They differ, however, in the degree to which the nominalized infinitives possess nominal and verbal properties. In this paper, nominalized infinitives in French are analyzed. It is shown that, whereas Old French was like
Soriano, Allan N.; Adamos, Kristoni G.; Bonifacio, Pauline B.; Adornado, Adonis P.; Bungay, Vergel C.; Vairavan, Rajendaran
2017-11-01
The fate of antibiotics entering the environment raised concerns on the possible effect of antimicrobial resistance bacteria. Prediction of the fate and transport of these particles are needed to be determined, significantly the diffusion coefficient of antibiotic in water at infinite dilution. A systematic determination of diffusion coefficient of antibiotic in water at infinite dilution of five different kinds of livestock antibiotics namely: Amtyl, Ciprotyl, Doxylak Forte, Trisullak, and Vetracin Gold in the 293.15 to 313.15 K temperature range are reported through the use of the method involving the electrolytic conductivity measurements. A continuous stirred tank reactor is utilized to measure the electrolytic conductivities of the considered systems. These conductivities are correlated by using the Nernst-Haskell equation to determine the infinite dilution diffusion coefficient. Determined diffusion coefficients are based on the assumption that in dilute solution, these antibiotics behave as strong electrolyte from which H+ cation dissociate from the antibiotic's anion.
Quantum correlations at infinite temperature: The dynamical Nagaoka effect
Kanász-Nagy, Márton; Lovas, Izabella; Grusdt, Fabian; Greif, Daniel; Greiner, Markus; Demler, Eugene A.
2017-07-01
Do quantum correlations play a role in high-temperature dynamics of many-body systems? A common expectation is that thermal fluctuations lead to fast decoherence and make dynamics classical. In this paper we provide a striking example that a single particle created in a featureless, infinite temperature spin bath not only exhibits nonclassical dynamics but it also induces strong long-lived correlations between the surrounding spins. We study the nonequilibrium dynamics of a hole created in a Mott insulator in the atomic limit, which corresponds to a degenerate spin system. In the absence of interactions, the spin correlations arise purely from quantum interference. Furthermore, these correlations are both antiferromagnetic and ferromagnetic, in striking contrast to the equilibrium Nagaoka effect. These results are relevant for a number of condensed matter spin systems and should be observable using state of the art bosonic or fermionic quantum gas microscopes.
Jin, Yunxia; Deng, Dunying; Cheng, Yuanrong; Kong, Lingqiang; Xiao, Fei
2014-04-01
As a promising candidate to replace the brittle and expensive transparent indium tin oxide (ITO) conductor, the use of silver nanowire (AgNW) networks still involves issues such as high-temperature post-treatments and poor substrate adhesion for industrial application. Here a room-temperature soldering and one-step solution method is developed to achieve high-performance Ag nanowire transparent conductive films (TCFs). A nonconductive binder is prepared from poly(dopamine) and alginic acid which contains abundant catechol and carboxylic acid functional groups. The drying of the binder on the Ag nanowire percolation networks induces tighter contact among the nanowires and strong adhesion to the substrate, simultaneously enhancing the electrical and mechanical properties without a high-temperature annealing process. As a result, a highly conductive and bendable AgNW film is demonstrated on a low-cost polyethylene glycol terephthalate (PET) substrate, showing an 89% optical transmittance at λ = 550 nm and a sheet resistance of 16.3 Ohm sq-1. Its optical and electrical performances are superior to those obtained from the reported indium tin oxide (ITO) films. Moreover, the AgNW film exhibits strong adhesion to the substrate, maintaining its conductivity after 100 tape tests, and it still resists the tape test even after exposure to solvent for several hours. Most importantly, the film shows good reliability during long-term 85 °C/85% RH (relative humidity) aging, which has been rarely investigated although it is a critical requirement for industrial application. The advanced and wide-ranging features of the prepared AgNW film greatly contribute to its use as a transparent electrode in multifunctional flexible electronic devices.
The QCD vacuum at infinite momentum
International Nuclear Information System (INIS)
White, A.R.
1988-01-01
We outline how ''topological confinement'' can be seen by the analysis of Regge limit infra-red divergences. We suggest that it is a necessary bridge between conventional confinement and the parton model at infinite momentum. It is produced by adding a chiral doublet of color sextet quarks to conventional QCD. An immediate signature of the resultant electroweak symmetry breaking would be large cross-sections for W + W/sup /minus// and Z 0 Z 0 pairs at the CERN and Fermilab /bar p/p colliders. 24 refs
Kuramoto model for infinite graphs with kernels
Canale, Eduardo
2015-01-07
In this paper we study the Kuramoto model of weakly coupled oscillators for the case of non trivial network with large number of nodes. We approximate of such configurations by a McKean-Vlasov stochastic differential equation based on infinite graph. We focus on circulant graphs which have enough symmetries to make the computations easier. We then focus on the asymptotic regime where an integro-partial differential equation is derived. Numerical analysis and convergence proofs of the Fokker-Planck-Kolmogorov equation are conducted. Finally, we provide numerical examples that illustrate the convergence of our method.
Approximation of the semi-infinite interval
Directory of Open Access Journals (Sweden)
A. McD. Mercer
1980-01-01
Full Text Available The approximation of a function f∈C[a,b] by Bernstein polynomials is well-known. It is based on the binomial distribution. O. Szasz has shown that there are analogous approximations on the interval [0,∞ based on the Poisson distribution. Recently R. Mohapatra has generalized Szasz' result to the case in which the approximating function is αe−ux∑k=N∞(uxkα+β−1Γ(kα+βf(kαuThe present note shows that these results are special cases of a Tauberian theorem for certain infinite series having positive coefficients.
Infinite Particle Systems: Complex Systems III
Directory of Open Access Journals (Sweden)
Editorial Board
2008-06-01
Full Text Available In the years 2002-2005, a group of German and Polish mathematicians worked under a DFG research project No 436 POL 113/98/0-1 entitled "Methods of stochastic analysis in the theory of collective phenomena: Gibbs states and statistical hydrodynamics". The results of their study were summarized at the German-Polish conference, which took place in Poland in October 2005. The venue of the conference was Kazimierz Dolny upon Vistula - a lovely town and a popular place for various cultural, scientific, and even political events of an international significance. The conference was also attended by scientists from France, Italy, Portugal, UK, Ukraine, and USA, which predetermined its international character. Since that time, the conference, entitled "Infinite Particle Systems: Complex Systems" has become an annual international event, attended by leading scientists from Germany, Poland and many other countries. The present volume of the "Condensed Matter Physics" contains proceedings of the conference "Infinite Particle Systems: Complex Systems III", which took place in June 2007.
A sampling theory for infinite weighted graphs
Directory of Open Access Journals (Sweden)
Palle E. T. Jorgensen
2011-01-01
Full Text Available We prove two sampling theorems for infinite (countable discrete weighted graphs \\(G\\; one example being "large grids of resistors" i.e., networks and systems of resistors. We show that there is natural ambient continuum \\(X\\ containing \\(G\\, and there are Hilbert spaces of functions on \\(X\\ that allow interpolation by sampling values of the functions restricted only on the vertices in \\(G\\. We sample functions on \\(X\\ from their discrete values picked in the vertex-subset \\(G\\. We prove two theorems that allow for such realistic ambient spaces \\(X\\ for a fixed graph \\(G\\, and for interpolation kernels in function Hilbert spaces on \\(X\\, sampling only from points in the subset of vertices in \\(G\\. A continuum is often not apparent at the outset from the given graph \\(G\\. We will solve this problem with the use of ideas from stochastic integration.
Behavioural equivalence for infinite systems - Partially decidable!
DEFF Research Database (Denmark)
Sunesen, Kim; Nielsen, Mogens
1996-01-01
For finite-state systems non-interleaving equivalences are computationally at least as hard as interleaving equivalences. In this paper we show that when moving to infinite-state systems, this situation may change dramatically. We compare standard language equivalence for process description...... languages with two generalizations based on traditional approaches capturing non-interleaving behaviour, pomsets representing global causal dependency, and locality representing spatial distribution of events. We first study equivalences on Basic Parallel Processes, BPP, a process calculus equivalent...... to communication free Petri nets. For this simple process language our two notions of non-interleaving equivalences agree. More interestingly, we show that they are decidable, contrasting a result of Hirshfeld that standard interleaving language equivalence is undecidable. Our result is inspired by a recent result...
Infinite-range quantum random Heisenberg magnet
Arrachea, Liliana; Rozenberg, Marcelo J.
2002-06-01
We study with exact diagonalization techniques the Heisenberg model for a system of SU(2) spins with S=1/2 and random infinite-range exchange interactions. We calculate the critical temperature Tg for the spin-glass to paramagnetic transition. We obtain Tg~0.13, in good agreement with previous quantum Monte Carlo and analytical estimates. We provide a detailed picture for the different kind of excitations which intervene in the dynamical response χ''(ω,T) at T=0 and analyze their evolution as T increases. We also calculate the specific heat Cv(T). We find that it displays a smooth maximum at TM~0.25, in good qualitative agreement with experiments. We argue that the fact that TM>Tg is due to a quantum disorder effect.
Developments and Trends in Infinite-Dimensional Lie Theory
Neeb, Karl-Hermann
2011-01-01
This collection of invited expository articles focuses on recent developments and trends in infinite-dimensional Lie theory, which has become one of the core areas of modern mathematics. The book is divided into three parts: infinite-dimensional Lie (super-)algebras, geometry of infinite-dimensional Lie (transformation) groups, and representation theory of infinite-dimensional Lie groups.Contributors: B. Allison, D. BeltiAGBPAE, W. Bertram, J. Faulkner, Ph. Gille, H. Glockner, K.-H. Neeb, E. Neher, I. Penkov, A. Pianzola, D. Pickrell, T.S. Ratiu, N.R. Scheithauer, C. Schweigert, V. Serganova,
Semantic coherence in English accusative-with-bare-infinitive constructions
DEFF Research Database (Denmark)
Jensen, Kim Ebensgaard
2013-01-01
Drawing on usage-based cognitively oriented construction grammar, this paper investigates the patterns of coattraction of items that appear in the two VP positions (the VP in the matrix clause, and the VP in the infinitive subordinate clause) in the English accusative-with-bare-infinitive constru......Drawing on usage-based cognitively oriented construction grammar, this paper investigates the patterns of coattraction of items that appear in the two VP positions (the VP in the matrix clause, and the VP in the infinitive subordinate clause) in the English accusative...... relations of English accusatives-with-bare-infinitives through the relations of semantic coherence between the two VPs....
Compactified Cosmological Simulations of the Infinite Universe
Rácz, Gábor; Szapudi, István; Csabai, István; Dobos, László
2018-03-01
We present a novel N-body simulation method that compactifies the infinite spatial extent of the Universe into a finite sphere with isotropic boundary conditions to follow the evolution of the large-scale structure. Our approach eliminates the need for periodic boundary conditions, a mere numerical convenience which is not supported by observation and which modifies the law of force on large scales in an unrealistic fashion. We demonstrate that our method outclasses standard simulations executed on workstation-scale hardware in dynamic range, it is balanced in following a comparable number of high and low k modes and, its fundamental geometry and topology match observations. Our approach is also capable of simulating an expanding, infinite universe in static coordinates with Newtonian dynamics. The price of these achievements is that most of the simulated volume has smoothly varying mass and spatial resolution, an approximation that carries different systematics than periodic simulations. Our initial implementation of the method is called StePS which stands for Stereographically Projected Cosmological Simulations. It uses stereographic projection for space compactification and naive O(N^2) force calculation which is nevertheless faster to arrive at a correlation function of the same quality than any standard (tree or P3M) algorithm with similar spatial and mass resolution. The N2 force calculation is easy to adapt to modern graphics cards, hence our code can function as a high-speed prediction tool for modern large-scale surveys. To learn about the limits of the respective methods, we compare StePS with GADGET-2 running matching initial conditions.
Ergodicity and Parameter Estimates for Infinite-Dimensional Fractional Ornstein-Uhlenbeck Process
International Nuclear Information System (INIS)
Maslowski, Bohdan; Pospisil, Jan
2008-01-01
Existence and ergodicity of a strictly stationary solution for linear stochastic evolution equations driven by cylindrical fractional Brownian motion are proved. Ergodic behavior of non-stationary infinite-dimensional fractional Ornstein-Uhlenbeck processes is also studied. Based on these results, strong consistency of suitably defined families of parameter estimators is shown. The general results are applied to linear parabolic and hyperbolic equations perturbed by a fractional noise
Stochastic PDEs and Infinite Horizon Backward Doubly Stochastic Differential Equations
Directory of Open Access Journals (Sweden)
Bo Zhu
2012-01-01
Full Text Available We give a sufficient condition on the coefficients of a class of infinite horizon BDSDEs, under which the infinite horizon BDSDEs have a unique solution for any given square integrable terminal values. We also show continuous dependence theorem and convergence theorem for this kind of equations. A probabilistic interpretation for solutions to a class of stochastic partial differential equations is given.
Quantum Probability, Renormalization and Infinite-Dimensional *-Lie Algebras
Directory of Open Access Journals (Sweden)
Luigi Accardi
2009-05-01
Full Text Available The present paper reviews some intriguing connections which link together a new renormalization technique, the theory of *-representations of infinite dimensional *-Lie algebras, quantum probability, white noise and stochastic calculus and the theory of classical and quantum infinitely divisible processes.
Semigroups on Frechet spaces and equations with infinite delays
Indian Academy of Sciences (India)
to cover a large class of functions to be used as initial functions to obtain existence and uniqueness of solutions. Keywords. Functional differential equation; infinite delay; semigroup; Frechet space. 1. Introduction and preliminaries. In this paper we study linear functional differential equations with infinite delay. Consider.
Infinitely many sign-changing solutions of an elliptic problem ...
Indian Academy of Sciences (India)
Infinitely many sign-changing solutions of an elliptic problem involving critical Sobolev and Hardy–Sobolev exponent. MOUSOMI ... Sign-changing solution; multiple critical exponent; Hardy-Sobolev; infinitely many solutions. Abstract. We study the existence and multiplicity of sign-changing solutions of the following equation.
An infinite-dimensional weak KAM theory via random variables
Gomes, Diogo A.
2016-08-31
We develop several aspects of the infinite-dimensional Weak KAM theory using a random variables\\' approach. We prove that the infinite-dimensional cell problem admits a viscosity solution that is a fixed point of the Lax-Oleinik semigroup. Furthermore, we show the existence of invariant minimizing measures and calibrated curves defined on R.
Discount-Optimal Infinite Runs in Priced Timed Automata
DEFF Research Database (Denmark)
Fahrenberg, Uli; Larsen, Kim Guldstrand
2009-01-01
of a certain part of the behaviour to the overall cost depends on how far into the future this part takes place. We consider the optimal infinite run problem under this semantics: Given a priced timed automaton, find an infinite path with minimal discounted price. We show that this problem is computable...
Big bang in a universe with infinite extension
Energy Technology Data Exchange (ETDEWEB)
Groen, Oeyvind [Oslo College, Department of Engineering, PO Box 4, St Olavs Pl, 0130 Oslo (Norway); Institute of Physics, University of Oslo, PO Box 1048 Blindern, 0316 Oslo (Norway)
2006-05-01
How can a universe coming from a point-like big bang event have infinite spatial extension? It is shown that the relativity of simultaneity is essential in answering this question. Space is finite as defined by the simultaneity of one observer, but it may be infinite as defined by the simultaneity of all the clocks participating in the Hubble flow.
Big bang in a universe with infinite extension
International Nuclear Information System (INIS)
Groen, Oeyvind
2006-01-01
How can a universe coming from a point-like big bang event have infinite spatial extension? It is shown that the relativity of simultaneity is essential in answering this question. Space is finite as defined by the simultaneity of one observer, but it may be infinite as defined by the simultaneity of all the clocks participating in the Hubble flow
Infinite measure~preserving~transformations with Radon MSJ
Danilenko, Alexandre I.
2015-01-01
We introduce concepts of Radon MSJ and Radon disjointness for infinite Radon measure preserving homeomorphisms of the locally compact Cantor space. We construct an uncountable family of pairwise Radon disjoint infinite Chacon like transformations. Every such transformation is Radon strictly ergodic, totally ergodic, asymmetric (not isomorphic to its inverse), has Radon MSJ and possesses Radon joinings whose ergodic components are not joinings.
The core and related solution concepts for infinite assignment games
Llorca, Natividad; Sanchez-Soriano, Joaquin; Tijs, Stef; Timmer, Judith B.
2004-01-01
Assignment problems where both sets of agents that have to be matched are countably infinite, the so-called infinite assignment problems, are studied as well as the related cooperative assignment games. Further, several solution concepts for these assignment games are studied. The first one is the
Countable Infinite Sets and Inflationary Models
Berezin, Alexander A.
2000-04-01
Unreasonable effectiveness of mathematics (E.Wigner) recasts pythagorean "all things are made of numbers". Hypotheses of eternal inflation (A.Linde) and/or quantum branching (H.Everett) buttressed by platonic pressure principle (PPP) resonates with "for deriving all from nothing there suffices a single principle" (G.W.Leibnitz). Externalization of PPP uses patterns of factorizations of super-long integers (tower exponents, TE). PPP-TE explosive emergence of space-time-matter-energy rests on infinite complexity of factorizational and iterational patterns of integers. Thus, PPP is direct translation of metaphysical principle to physics of material world ("metaphysics works"). Countability of quantum states of bounded systems allows "listing" of all states of all baby universes through Godel-like counting with TE of primes. At each breeding step upper (Nth) prime of TE stack p1...pN counts (by multidimensional Cantor diagonal scheme) all universes AND all states in them. Exclusive use of primes in TEs assures non-overlapping counting. Cantor counting with non-crossing subsets of primes (and actual PPP emergence) can proceed both in "forward" and "backward" direction in megauniversal ("Newtonian") time. format.
Ordered groups and infinite permutation groups
1996-01-01
The subjects of ordered groups and of infinite permutation groups have long en joyed a symbiotic relationship. Although the two subjects come from very different sources, they have in certain ways come together, and each has derived considerable benefit from the other. My own personal contact with this interaction began in 1961. I had done Ph. D. work on sequence convergence in totally ordered groups under the direction of Paul Conrad. In the process, I had encountered "pseudo-convergent" sequences in an ordered group G, which are like Cauchy sequences, except that the differences be tween terms of large index approach not 0 but a convex subgroup G of G. If G is normal, then such sequences are conveniently described as Cauchy sequences in the quotient ordered group GIG. If G is not normal, of course GIG has no group structure, though it is still a totally ordered set. The best that can be said is that the elements of G permute GIG in an order-preserving fashion. In independent investigations around that t...
Ricci flows and infinite dimensional algebras
International Nuclear Information System (INIS)
Bakas, I.
2004-01-01
The renormalization group equations of two-dimensional sigma models describe geometric deformations of their target space when the world-sheet length changes scale from the ultra-violet to the infra-red. These equations, which are also known in the mathematics literature as Ricci flows, are analyzed for the particular case of two-dimensional target spaces, where they are found to admit a systematic description as Toda system. Their zero curvature formulation is made possible with the aid of a novel infinite dimensional Lie algebra, which has anti-symmetric Cartan kernel and exhibits exponential growth. The general solution is obtained in closed form using Baecklund transformations, and special examples include the sausage model and the decay process of conical singularities to the plane. Thus, Ricci flows provide a non-linear generalization of the heat equation in two dimensions with the same dissipative properties. Various applications to dynamical problems of string theory are also briefly discussed. Finally, we outline generalizations to higher dimensional target spaces that exhibit sufficient number of Killing symmetries. (Abstract Copyright [2004], Wiley Periodicals, Inc.)
Dimensionally continued infinite reduction of couplings
Anselmi, Damiano; Halat, Milenko
2006-01-01
The infinite reduction of couplings is a tool to consistently renormalize a wide class of non-renormalizable theories with a reduced, eventually finite, set of independent couplings, and classify the non-renormalizable interactions. Several properties of the reduction of couplings, both in renormalizable and non-renormalizable theories, can be better appreciated working at the regularized level, using the dimensional-regularization technique. We show that, when suitable invertibility conditions are fulfilled, the reduction follows uniquely from the requirement that both the bare and renormalized reduction relations be analytic in ɛ = D-d, where D and d are the physical and continued spacetime dimensions, respectively. In practice, physically independent interactions are distinguished by relatively non-integer powers of ɛ. We discuss the main physical and mathematical properties of this criterion for the reduction and compare it with other equivalent criteria. The leading-log approximation is solved explicitly and contains sufficient information for the existence and uniqueness of the reduction to all orders.
Granick, Steve; Sukhishvili, Svetlana A.
2004-05-25
A film contains a first polymer having a plurality of hydrogen bond donating moieties, and a second polymer having a plurality of hydrogen bond accepting moieties. The second polymer is hydrogen bonded to the first polymer.
Antikaons in infinite nuclear matter and nuclei
Energy Technology Data Exchange (ETDEWEB)
Moeller, M.
2007-12-10
In this work we studied the properties of antikaons and hyperons in infinite cold nuclear matter. The in-medium antikaon-nucleon scattering amplitude and self-energy has been calculated within a covariant many-body framework in the first part. Nuclear saturation effects have been taken into account in terms of scalar and vector nucleon mean-fields. In the second part of the work we introduced a non-local method for the description of kaonic atoms. The many-body approach of anti KN scattering can be tested by the application to kaonic atoms. A self-consistent and covariant many-body approach has been used for the determination of the antikaon spectral function and anti KN scattering amplitudes. It considers s-, p- and d-waves and the application of an in-medium projector algebra accounts for proper mixing of partial waves in the medium. The on-shell reduction scheme is also implemented by means of the projector algebra. The Bethe-Salpeter equation has been rewritten, so that the free-space anti KN scattering can be used as the interaction kernel for the in-medium scattering equation. The latter free-space scattering is based on a realistic coupled-channel dynamics and chiral SU(3) Lagrangian. Our many-body approach is generalized for the presence of large scalar and vector nucleon mean-fields. It is supplemented by an improved renormalization scheme, that systematically avoids the occurrence of medium-induced power-divergent structures and kinematical singularities. A modified projector basis has been introduced, that allows for a convenient inclusion of nucleon mean-fields. The description of the results in terms of the 'physical' basis is done with the help of a recoupling scheme based on the projector algebra properties. (orig.)
Quantum walks induced by Dirichlet random walks on infinite trees
Higuchi, Yusuke; Segawa, Etsuo
2018-02-01
We consider the Grover walk on infinite trees from the viewpoint of spectral analysis. From the previous work, infinite regular trees provide localization. In this paper, we give the complete characterization of the eigenspace of this Grover walk, which involves localization of its behavior and recovers the previous work. Our result suggests that the Grover walk on infinite trees may be regarded as a limit of the quantum walk induced by the isotropic random walk with the Dirichlet boundary condition at the n-th depth rather than one with the Neumann boundary condition.
About the Infinite Repetition of Histories in Space
Directory of Open Access Journals (Sweden)
Manuel Alfonseca
2014-08-01
Full Text Available This paper analyzes two different proposals, one by Ellis and Brundrit, based on classical relativistic cosmology, the other by Garriga and Vilenkin, based on the DH interpretation of quantum mechanics, both concluding that, in an infinite universe, planets and beings must be repeated an infinite number of times. We point to possible shortcomings in these arguments. We conclude that the idea of an infinite repetition of histories in space cannot be considered strictly speaking a consequence of current physics and cosmology. Such ideas should be seen rather as examples of «ironic science» in the terminology of John Horgan.
A NOTE ON LOGARITHMIC SMOOTHING IN SEMI-INFINITE OPTIMIZATION UNDER REDUCTION APPROACH*
Directory of Open Access Journals (Sweden)
Francisco Guerra-Vazquez
2013-02-01
Full Text Available This note deals with a semi-infinite optimization problem which is defined by infinitely many inequality constraints. By applying a logarithmic barrier function, a family of interior point approximations of the feasible set is obtained where locally the original feasible set and its approximations are homeomorphic. Under generic assumptions on the structure of the original feasible set, strongly stable stationary points of the original problem are considered and it is shown that there is a one-to-one correspondence between the stationary points (and their stationary indices of the original problem and those of its approximations. Corresponding convergence results, global aspects and a relationship to a standard interior-point approach are discussed.
International Nuclear Information System (INIS)
Monthus, Cécile; Garel, Thomas
2012-01-01
To avoid the complicated topology of surviving clusters induced by standard strong disorder RG in dimension d > 1, we introduce a modified procedure called ‘boundary strong disorder RG’ where the order of decimations is chosen a priori. We apply this modified procedure numerically to the random transverse field Ising model in dimension d = 2. We find that the location of the critical point, the activated exponent ψ ≃ 0.5 of the infinite-disorder scaling, and the finite-size correlation exponent ν FS ≃ 1.3 are compatible with the values obtained previously using standard strong disorder RG. Our conclusion is thus that strong disorder RG is very robust with respect to changes in the order of decimations. In addition, we analyze the RG flows within the two phases in more detail, to show explicitly the presence of various correlation length exponents: we measure the typical correlation exponent ν typ ≃ 0.64 for the disordered phase (this value is very close to the correlation exponent ν pure Q (d=2)≅0.6 3 of the pure two-dimensional quantum Ising model), and the typical exponent ν h ≃ 1 for the ordered phase. These values satisfy the relations between critical exponents imposed by the expected finite-size scaling properties at infinite-disorder critical points. We also measure, within the disordered phase, the fluctuation exponent ω ≃ 0.35 which is compatible with the directed polymer exponent ω DP (1+1)= 1/3 in (1 + 1) dimensions. (paper)
Convectively driven flow past an infinite moving vertical cylinder with ...
Indian Academy of Sciences (India)
, free convective flow over an infinite moving vertical cylinder under combined buoyancy effects of heat and mass transfer with thermal and mass stratifications. Laplace transform technique is adopted for finding solutions for velocity, ...
Wigner's infinite spin representations and inert matter
Energy Technology Data Exchange (ETDEWEB)
Schroer, Bert [CBPF, Rio de Janeiro (Brazil); Institut fuer Theoretische Physik FU-Berlin, Berlin (Germany)
2017-06-15
Positive energy ray representations of the Poincare group are naturally subdivided into three classes according to their mass and spin content: m > 0, m = 0 finite helicity and m = 0 infinite spin. For a long time the localization properties of the massless infinite spin class remained unknown, until it became clear that such matter does not permit compact spacetime localization and its generating covariant fields are localized on semi-infinite space-like strings. Using a new perturbation theory for higher spin fields we present arguments which support the idea that infinite spin matter cannot interact with normal matter and we formulate conditions under which this also could happen for finite spin s > 1 fields. This raises the question of a possible connection between inert matter and dark matter. (orig.)
Borsuk-Ulam theorem in infinite-dimensional Banach spaces
International Nuclear Information System (INIS)
Gel'man, B D
2002-01-01
The well-known classical Borsuk-Ulam theorem has a broad range of applications to various problems. Its generalization to infinite-dimensional spaces runs across substantial difficulties because its statement is essentially finite-dimensional. A result established in the paper is a natural generalization of the Borsuk-Ulam theorem to infinite-dimensional Banach spaces. Applications of this theorem to various problems are discussed
Zheng, Chang-Jun; Bi, Chuan-Xing; Zhang, Chuanzeng; Gao, Hai-Feng; Chen, Hai-Bo
2018-04-01
The vibration behavior of thin elastic structures can be noticeably influenced by the surrounding water, which represents a kind of heavy fluid. Since the feedback of the acoustic pressure onto the structure cannot be neglected in this case, a strong coupled scheme between the structural and fluid domains is usually required. In this work, a coupled finite element and boundary element (FE-BE) solver is developed for the free vibration analysis of structures submerged in an infinite fluid domain or a semi-infinite fluid domain with a free water surface. The structure is modeled by the finite element method (FEM). The compressibility of the fluid is taken into account, and hence the Helmholtz equation serves as the governing equation of the fluid domain. The boundary element method (BEM) is employed to model the fluid domain, and a boundary integral formulation with a half-space fundamental solution is used to satisfy the Dirichlet boundary condition on the free water surface exactly. The resulting nonlinear eigenvalue problem (NEVP) is converted into a small linear one by using a contour integral method. Adequate modifications are suggested to improve the efficiency of the contour integral method and avoid missing the eigenfrequencies of interest. The Burton-Miller method is used to filter out the fictitious eigenfrequencies of the boundary integral formulations. Numerical examples are given to demonstrate the accuracy and applicability of the developed eigensolver, and also show that the fluid-loading effect strongly depends on both the water depth and the mode shapes.
Vroman, Isabelle; Tighzert, Lan
2009-01-01
Biodegradable materials are used in packaging, agriculture, medicine and other areas. In recent years there has been an increase in interest in biodegradable polymers. Two classes of biodegradable polymers can be distinguished: synthetic or natural polymers. There are polymers produced from feedstocks derived either from petroleum resources (non renewable resources) or from biological resources (renewable resources). In general natural polymers offer fewer advantages than synthetic polymers. ...
Solution of Exterior Helmholtz Problems Using Finite and Infinite Elements
Shirron, Joseph James
This dissertation discusses methods for the computation of solutions of the Helmholtz equation in unbounded domains. Two classes of methods are considered: one in which the infinite exterior domain is truncated and finite elements are used to discretize the resultant computational domain, and another in which the exterior domain is discretized by infinite elements. For the first class of methods a generalized Robin boundary condition is imposed on the truncating surface to replace the Sommerfeld radiation condition at infinity and to ensure uniqueness of the solution. Several of these approximate radiation conditions are discussed and a comparison is presented to illustrate their efficacy. For the second class of methods finite elements are used to discretize the exterior domain out to an enclosing circle or prolate spheroid, then infinite elements are used to discretize the remaining unbounded domain. Strikingly different approximation and convergence behavior is observed depending on whether a bilinear or sesquilinear form is chosen for the variational formulation of the problem. Convergence analysis for the infinite element methods is presented for both two and three spatial dimensions. A solution method based on the idea of domain decomposition is also discussed, as are various techniques for obtaining the solution in the far field. Numerical experiments for problems of acoustic scattering by bodies of revolution convincingly demonstrate the superiority in terms of computational expense of the infinite element methods over boundary element methods.
Post-optimal analysis in linear semi-infinite optimization
Goberna, Miguel A
2014-01-01
Post-Optimal Analysis in Linear Semi-Infinite Optimization examines the following topics in regards to linear semi-infinite optimization: modeling uncertainty, qualitative stability analysis, quantitative stability analysis and sensitivity analysis. Linear semi-infinite optimization (LSIO) deals with linear optimization problems where the dimension of the decision space or the number of constraints is infinite. The authors compare the post-optimal analysis with alternative approaches to uncertain LSIO problems and provide readers with criteria to choose the best way to model a given uncertain LSIO problem depending on the nature and quality of the data along with the available software. This work also contains open problems which readers will find intriguing a challenging. Post-Optimal Analysis in Linear Semi-Infinite Optimization is aimed toward researchers, graduate and post-graduate students of mathematics interested in optimization, parametric optimization and related topics.
Infinite populations and counterfactual frequencies in evolutionary theory.
Abrams, Marshall
2006-06-01
One finds intertwined with ideas at the core of evolutionary theory claims about frequencies in counterfactual and infinitely large populations of organisms, as well as in sets of populations of organisms. One also finds claims about frequencies in counterfactual and infinitely large populations--of events--at the core of an answer to a question concerning the foundations of evolutionary theory. The question is this: to what do the numerical probabilities found throughout evolutionary theory correspond? The answer in question says that evolutionary probabilities are 'hypothetical frequencies' (including what are sometimes called 'long-run frequencies' and 'long-run propensities'). In this paper, I review two arguments against hypothetical frequencies. The arguments have implications for the interpretation of evolutionary probabilities, but more importantly, they seem to raise problems for biologists' claims about frequencies in counterfactual or infinite populations of organisms and sets of populations of organisms. I argue that when properly understood, claims about frequencies in large and infinite populations of organisms and sets of populations are not threatened by the arguments. Seeing why gives us a clearer understanding of the nature of counterfactual and infinite population claims and probability in evolutionary theory.
Confining multiple polymers between sticky walls: a directed walk model of two polymers
International Nuclear Information System (INIS)
Wong, Thomas; Rechnitzer, Andrew; Owczarek, Aleksander L
2014-01-01
We study a model of two polymers confined to a slit with sticky walls. More precisely, we find and analyse the exact solution of two directed friendly walks in such a geometry on the square lattice. We compare the infinite slit limit, in which the length of the polymer (thermodynamic limit) is taken to infinity before the width of the slit is considered to become large, to the opposite situation where the order of the limits are swapped, known as the half-plane limit when one polymer is modelled. In contrast with the single polymer system we find that the half-plane and infinite slit limits coincide. We understand this result in part due to the tethering of polymers on both walls of the slit. We also analyse the entropic force exerted by the polymers on the walls of the slit. Again the results differ significantly from single polymer models. In a single polymer system both attractive and repulsive regimes were seen, whereas in our two walk model only repulsive forces are observed. We do, however, see that the range of the repulsive force is dependent on the parameter values. This variation can be explained by the adsorption of the walks on opposite walls of the slit. (paper)
Ablative Rayleigh-Taylor instability in the limit of an infinitely large density ratio
International Nuclear Information System (INIS)
Clavin, P.; Almarcha, Ch.
2005-01-01
The instability of ablation fronts strongly accelerated toward the dense medium under the conditions of inertial confinement fusion (ICF) is addressed in the limit of an infinitely large density ratio. The analysis serves to demonstrate that the flow is irrotational to first order, reducing the nonlinear analysis to solve a two-potential flows problem. Vorticity appears at the following orders in the perturbation analysis. This result simplifies greatly the analysis. The possibility for using boundary integral methods opens new perspectives in the nonlinear theory of the ablative Rayleigh-Taylor instability in ICF. A few examples are given at the end of the paper. (authors)
Strongly coupled dust coulomb clusters
International Nuclear Information System (INIS)
Juan Wentau; Lai Yingju; Chen Mingheng; I Lin
1999-01-01
The structures and motions of quasi-2-dimensional strongly coupled dust Coulomb clusters with particle number N from few to hundreds in a cylindrical rf plasma trap are studied and compared with the results from the molecular dynamic simulation using more ideal models. Shell structures with periodic packing in different shells and intershell rotational motion dominated excitations are observed at small N. As N increases, the boundary has less effect, the system recovers to the triangular lattice with isotropic vortex type cooperative excitations similar to an infinite N system except the outer shell region. The above generic behaviors are mainly determined by the system symmetry and agree with the simulation results. The detailed interaction form causes minor effect such as the fine structure of packing
Instanton operators and the Higgs branch at infinite coupling
Energy Technology Data Exchange (ETDEWEB)
Cremonesi, Stefano [Department of Mathematics, King’s College London,The Strand, London WC2R 2LS (United Kingdom); Ferlito, Giulia; Hanany, Amihay [Theoretical Physics Group, Imperial College London,Prince Consort Road, London, SW7 2AZ (United Kingdom); Mekareeya, Noppadol [Theory Division, Physics Department, CERN,CH-1211, Geneva 23 (Switzerland)
2017-04-10
The richness of 5d N=1 theories with a UV fixed point at infinite coupling is due to the existence of local disorder operators known as instanton operators. By considering the Higgs branch of SU(2) gauge theories with N{sub f}≤7 flavours at finite and infinite coupling, we write down the explicit chiral ring relations between instanton operators, the glueball superfield and mesons. Exciting phenomena appear at infinite coupling: the glueball superfield is no longer nilpotent and the classical chiral ring relations are quantum corrected by instanton operators bilinears. We also find expressions for the dressing of instanton operators of arbitrary charge. The same analysis is performed for USp(2k) with an antisymmetric hypermultiplet and pure SU(N) gauge theories.
Instanton Operators and the Higgs Branch at Infinite Coupling
Cremonesi, Stefano; Hanany, Amihay; Mekareeya, Noppadol
2017-01-01
The richness of 5d $\\mathcal{N}=1$ theories with a UV fixed point at infinite coupling is due to the existence of local disorder operators known as instanton operators. By considering the Higgs branch of $SU(2)$ gauge theories with $N_f \\leq 7$ flavours at finite and infinite coupling, we write down the explicit chiral ring relations between instanton operators, the glueball superfield and mesons. Exciting phenomena appear at infinite coupling: the glueball superfield is no longer nilpotent and the classical chiral ring relations are quantum corrected by instanton operators bilinears. We also find expressions for the dressing of instanton operators of arbitrary charge. The same analysis is performed for $USp(2k)$ with an antisymmetric hypermultiplet and pure $SU(N)$ gauge theories.
Complexity Analysis of Precedence Terminating Infinite Graph Rewrite Systems
Directory of Open Access Journals (Sweden)
Naohi Eguchi
2015-05-01
Full Text Available The general form of safe recursion (or ramified recurrence can be expressed by an infinite graph rewrite system including unfolding graph rewrite rules introduced by Dal Lago, Martini and Zorzi, in which the size of every normal form by innermost rewriting is polynomially bounded. Every unfolding graph rewrite rule is precedence terminating in the sense of Middeldorp, Ohsaki and Zantema. Although precedence terminating infinite rewrite systems cover all the primitive recursive functions, in this paper we consider graph rewrite systems precedence terminating with argument separation, which form a subclass of precedence terminating graph rewrite systems. We show that for any precedence terminating infinite graph rewrite system G with a specific argument separation, both the runtime complexity of G and the size of every normal form in G can be polynomially bounded. As a corollary, we obtain an alternative proof of the original result by Dal Lago et al.
FEM and BIEM - A new infinite hybrid finite element
International Nuclear Information System (INIS)
Drakaliev, P.
1993-01-01
The finite element method (MFE) and the boundary integral equation method (BIEM) are general approximation procedures applicable to a wide variety of engineering problems. Each of them has many variants and each possesses certain merits and limitations of its own. The FEM may be easier to apply in domains with anisotropic or nonlinear behaviour. On the other hand the BEM is more attractive for unbounded domains or regions of high stress concentration. Therefore, the idea of combining both numerical techniques is of great interest in many practical problems, especially in solid and fluid mechanics, such as soil-structure and structure-fluid interaction problems. In the developments to follow an energy approach for symmetrizing the indirect BIEM is being used to obtain the stiffness matrix for the infinite or semi-infinite elastic medium. Thus the subdomain is considered as an infinite super element with an arbitrary shaped boundary and can be easily implemented into existing finite element codes
International Nuclear Information System (INIS)
Fathi, F.; Moayedi, S. K.; Shafabakhsh, M.
2015-01-01
More than 80 years ago, Born-Infeld electrodynamics was proposed in order to remove the point charge singularity in Maxwell electrodynamics. In this work, after a brief introduction to Lagrangian formulation of Abelian Born-Infeld model in the presence of an external source, we obtain the explicit forms of Gauss’s law and the energy density of an electrostatic field for Born-Infeld electrostatics. The electric field and the stored electrostatic energy per unit length for an infinite charged line and an infinitely long cylinder in Born-Infeld electrostatics are calculated. Numerical estimations in this paper show that the nonlinear corrections to Maxwell electrodynamics are considerable only for strong electric fields. We present an action functional for Abelian Born-Infeld model with an auxiliary scalar field in the presence of an external source. This action functional is a generalization of the action functional which was presented by Tseytlin in his studies on low energy dynamics of D-branes (Nucl. Phys. B469, 51 (1996); Int. J. Mod. Phys. A 19, 3427 (2004)). Finally, we derive the symmetric energy-momentum tensor for Abelian Born-Infeld model with an auxiliary scalar field
Infinite Spin Fields in d = 3 and Beyond
Directory of Open Access Journals (Sweden)
Yurii M. Zinoviev
2017-08-01
Full Text Available In this paper, we consider the frame-like formulation for the so-called infinite (continuous spin representations of the Poincare algebra. In the three-dimensional case, we give explicit Lagrangian formulation for bosonic and fermionic infinite spin fields (including the complete sets of the gauge-invariant objects and all the necessary extra fields. Moreover, we find the supertransformations for the supermultiplet containing one bosonic and one fermionic field, leaving the sum of their Lagrangians invariant. Properties of such fields and supermultiplets in four and higher dimensions are also briefly discussed.
Geometry of quantum dynamics in infinite-dimensional Hilbert space
Grabowski, Janusz; Kuś, Marek; Marmo, Giuseppe; Shulman, Tatiana
2018-04-01
We develop a geometric approach to quantum mechanics based on the concept of the Tulczyjew triple. Our approach is genuinely infinite-dimensional, i.e. we do not restrict considerations to finite-dimensional Hilbert spaces, contrary to many other works on the geometry of quantum mechanics, and include a Lagrangian formalism in which self-adjoint (Schrödinger) operators are obtained as Lagrangian submanifolds associated with the Lagrangian. As a byproduct we also obtain results concerning coadjoint orbits of the unitary group in infinite dimensions, embedding of pure states in the unitary group, and self-adjoint extensions of symmetric relations.
Infinite time interval backward stochastic differential equations with continuous coefficients.
Zong, Zhaojun; Hu, Feng
2016-01-01
In this paper, we study the existence theorem for [Formula: see text] [Formula: see text] solutions to a class of 1-dimensional infinite time interval backward stochastic differential equations (BSDEs) under the conditions that the coefficients are continuous and have linear growths. We also obtain the existence of a minimal solution. Furthermore, we study the existence and uniqueness theorem for [Formula: see text] [Formula: see text] solutions of infinite time interval BSDEs with non-uniformly Lipschitz coefficients. It should be pointed out that the assumptions of this result is weaker than that of Theorem 3.1 in Zong (Turkish J Math 37:704-718, 2013).
Infinite Runs in Weighted Timed Automata with Energy Constraints
DEFF Research Database (Denmark)
Bouyer, Patricia; Fahrenberg, Uli; Larsen, Kim Guldstrand
2008-01-01
We study the problems of existence and construction of infinite schedules for finite weighted automata and one-clock weighted timed automata, subject to boundary constraints on the accumulated weight. More specifically, we consider automata equipped with positive and negative weights on transitions...... and locations, corresponding to the production and consumption of some resource (e.g. energy). We ask the question whether there exists an infinite path for which the accumulated weight for any finite prefix satisfies certain constraints (e.g. remains between 0 and some given upper-bound). We also consider...
Orientations of infinite graphs with prescribed edge-connectivity
DEFF Research Database (Denmark)
Thomassen, Carsten
2016-01-01
We prove a decomposition result for locally finite graphs which can be used to extend results on edge-connectivity from finite to infinite graphs. It implies that every 4k-edge-connected graph G contains an immersion of some finite 2k-edge-connected Eulerian graph containing any prescribed vertex...... set (while planar graphs show that G need not containa subdivision of a simple finite graph of large edge-connectivity). Also, every 8k-edge connected infinite graph has a k-arc-connected orientation, as conjectured in 1989....
Hsin-Fei, Meng
2013-01-01
Polymer semiconductor is the only semiconductor that can be processed in solution. Electronics made by these flexible materials have many advantages such as large-area solution process, low cost, and high performance. Researchers and companies are increasingly dedicating time and money in polymer electronics. This book focuses on the fundamental materials and device physics of polymer electronics. It describes polymer light-emitting diodes, polymer field-effect transistors, organic vertical transistors, polymer solar cells, and many applications based on polymer electronics. The book also disc
Radiation of sound in a semi-infinite hard duct inserted axially into a larger infinite lined duct
Tiwana, Mazhar Hussain; Nawaz, Rab; Mann, Amer Bilal
2017-12-01
This article examines sound radiation from a hard semi-infinite duct placed symmetrically inside an acoustically lined duct. We introduce a wake on right handed region of the duct configuration to analyze sound radiation process for the trailing edge situation. The integral transforms together with Wiener-Hopf techniques render the solution of underlying problem. However expressions for field intensity involve infinite sums/products that enable solution using truncation approach. The sound radiation analysis is then observed graphically while using different choice of some pertinent parameters. It is worth mentioning that results of leading edge situation can be recovered as a limiting case.
Functional DNA: Teaching Infinite Series through Genetic Analogy
Kowalski, R. Travis
2011-01-01
This article presents an extended analogy that connects infinite sequences and series to the science of genetics, by identifying power series as "DNA for a function." This analogy allows standard topics such as convergence tests or Taylor approximations to be recast in a "forensic" light as mathematical analogs of genetic concepts such as DNA…
Explaining Infinite Series--An Exploration of Students' Images
Champney, Danielle Dawn
2013-01-01
This study uses self-generated representations (SGR)--images produced in the act of explaining--as a means of uncovering what university calculus students understand about infinite series convergence. It makes use of student teaching episodes, in which students were asked to explain to a peer what that student might have missed had they been…
Finding Sums for an Infinite Class of Alternating Series
Chen, Zhibo; Wei, Sheng; Xiao, Xuerong
2012-01-01
Calculus II students know that many alternating series are convergent by the Alternating Series Test. However, they know few alternating series (except geometric series and some trivial ones) for which they can find the sum. In this article, we present a method that enables the students to find sums for infinitely many alternating series in the…
Pareto optimality in infinite horizon linear quadratic differential games
Reddy, P.V.; Engwerda, J.C.
2013-01-01
In this article we derive conditions for the existence of Pareto optimal solutions for linear quadratic infinite horizon cooperative differential games. First, we present a necessary and sufficient characterization for Pareto optimality which translates to solving a set of constrained optimal
Cylindrical continuous martingales and stochastic integration in infinite dimensions
Veraar, M.C.; Yaroslavtsev, I.S.
2016-01-01
In this paper we define a new type of quadratic variation for cylindrical continuous local martingales on an infinite dimensional spaces. It is shown that a large class of cylindrical continuous local martingales has such a quadratic variation. For this new class of cylindrical continuous local
The infinite curvature limit of AdS/CFT
Alvarez, Enrique
2004-01-01
Some kinematical speculations on the infinite curvature limit of the conjectured duality of Maldacena between ten-dimensional strings living in $AdS_5\\times S_5$ and a ordinary four-dimensional quantum field theory, namely ${\\cal{N}}=4$ super Yang-Mills with gauge group SU(N) are given.
Pareto optimality for nonlinear infinite dimensional control systems
Directory of Open Access Journals (Sweden)
Evgenios P. Avgerinos
1990-01-01
Full Text Available In this note we establish the existence of Pareto optimal solutions for nonlinear, infinite dimensional control systems with state dependent control constraints and an integral criterion taking values in a separable, reflexive Banach lattice. An example is also presented in detail. Our result extends earlier ones obtained by Cesari and Suryanarayana.
On Nonlinear Neutral Fractional Integrodifferential Inclusions with Infinite Delay
Directory of Open Access Journals (Sweden)
Fang Li
2012-01-01
Full Text Available Of concern is a class of nonlinear neutral fractional integrodifferential inclusions with infinite delay in Banach spaces. A theorem about the existence of mild solutions to the fractional integrodifferential inclusions is obtained based on Martelli’s fixed point theorem. An example is given to illustrate the existence result.
Frege's Commitment to an Infinite Hierarchy of Senses | Boisvert ...
African Journals Online (AJOL)
Though it has been claimed that Frege's commitment to expressions in indirect contexts not having their customary senses commits him to an infinite number of semantic primitives, Terrence Parsons has argued that Frege's explicit commitments are compatible with a two-level theory of senses. In this paper, we argue Frege ...
Linear measure functional differential equations with infinite delay
Monteiro, G. (Giselle Antunes); Slavík, A.
2014-01-01
We use the theory of generalized linear ordinary differential equations in Banach spaces to study linear measure functional differential equations with infinite delay. We obtain new results concerning the existence, uniqueness, and continuous dependence of solutions. Even for equations with a finite delay, our results are stronger than the existing ones. Finally, we present an application to functional differential equations with impulses.
N-max infinite divisibility and N-max stability
Satheesh, S.; Sandhya, E.
2014-01-01
Here we give a necessary and sufficient condition for the convergence to a random max infinitely divisible law from that of a random maximum. We then discuss random max-stable laws, their domain of max-attraction and the associated extremal processes.
determination of stresses caused by infinitely long line loads on ...
African Journals Online (AJOL)
user
2016-10-04
Oct 4, 2016 ... system were used to express the governing equations of plane strain elasticity for a semi-infinite homogeneous soil as a biharmonic problem. The fourth order partial differential equation was then solved by an exponential Fourier transform .... whereμ is the Poisson's ratio,τyz and τyx are shear stresses on ...
A Bayesian Infinite Hidden Markov Vector Autoregressive Model
D. Nibbering (Didier); R. Paap (Richard); M. van der Wel (Michel)
2016-01-01
textabstractWe propose a Bayesian infinite hidden Markov model to estimate time-varying parameters in a vector autoregressive model. The Markov structure allows for heterogeneity over time while accounting for state-persistence. By modelling the transition distribution as a Dirichlet process mixture
Lyapunov equation for infinite-dimensional discrete bilinear systems
International Nuclear Information System (INIS)
Costa, O.L.V.; Kubrusly, C.S.
1991-03-01
Mean-square stability for discrete systems requires that uniform convergence is preserved between input and state correlation sequences. Such a convergence preserving property holds for an infinite-dimensional bilinear system if and only if the associate Lyapunov equation has a unique strictly positive solution. (author)
Zero Divisors in Associative Algebras over Infinite Fields
Schweitzer, Michael; Finch, Steven
1999-01-01
Let F be an infinite field. We prove that the right zero divisors of a three-dimensional associative F-algebra A must form the union of at most finitely many linear subspaces of A. The proof is elementary and written with students as the intended audience.
On generalized semi-infinite optimization and bilevel optimization
Stein, O.; Still, Georg J.
2000-01-01
The paper studies the connections and differences between bilevel problems (BL) and generalized semi-infinite problems (GSIP). Under natural assumptions (GSIP) can be seen as a special case of a (BL). We consider the so-called reduction approach for (BL) and (GSIP) leading to optimality conditions
On generalized semi-infinite optimization and bilevel optimization
Stein, Oliver; Still, Georg J.
2002-01-01
The paper studies the connections and differences between bilevel problems (BL) and generalized semi-infinite problems (GSIP). Under natural assumptions (GSIP) can be seen as a special case of a (BL). We consider the so-called reduction approach for (BL) and (GSIP) leading to optimality conditions
LQR control for scalar finite and infinite platoons
Curtain, R.F.; Iftime, O.V.; Zwart, Heiko J.; El Jai, A.; Afifi, L.; Zerrik, E.
In this paper we compare the behaviour of the LQR solution for a finite platoon model with its infinite version. We give examples where these are similar and some where they are quite different. For the scalar case we obtain sufficient conditions for the LQR solutions to be similar by relating the
A cutting- plane approach for semi- infinite mathematical programming
African Journals Online (AJOL)
Many situations ranging from industrial to social via economic and environmental problems may be cast into a Semi-infinite mathematical program. In this paper, the cutting-plane approach which lends itself better for standard non-linear programs is exploited with good reasons for grappling with linear, convex and ...
Some infinite dimensional representations of reductive groups with Frobenius maps
Xi, NanHua
2014-06-01
In this paper we construct certain irreducible infinite dimensional representations of algebraic groups with Frobenius maps. In particular, a few classical results of Steinberg and Deligne & Lusztig on complex representations of finite groups of Lie type are extended to reductive algebraic groups with Frobenius maps.
Euclidean null controllability of nonlinear infinite delay systems with ...
African Journals Online (AJOL)
Sufficient conditions for the Euclidean null controllability of non-linear delay systems with time varying multiple delays in the control and implicit derivative are derived. If the uncontrolled system is uniformly asymptotically stable and if the control system is controllable, then the non-linear infinite delay system is Euclidean null ...
Euclidean null controllability of perturbed infinite delay systems with ...
African Journals Online (AJOL)
Sufficient conditions for the Euclidean null controllability of perturbed infinite delay systems with limited control are developed. The results are established by placing conditions on the perturbation function which guarantee that, if the linear control base system is completely Euclidean controllable, then the perturbed system ...
Analysis of competitive equilibrium in an infinite dimensional ...
African Journals Online (AJOL)
This paper considered the cost of allocated goods and attaining maximal utility with such price in the finite dimensional commodity space and observed that there exist an equilibrium price. It goes further to establish that in an infinite dimensional commodity space with subsets as consumption and production set there exist a ...
Symmetry Reduction in Infinite Games with Finite Branching
DEFF Research Database (Denmark)
Markey, Nicolas; Vester, Steen
2014-01-01
infinite-state games on graphs with finite branching where the objectives of the players can be very general. As particular applications, it is shown that the technique can be applied to reduce the state space in parity games as well as when doing modelchecking of the Alternating-time temporal logic ATL....
Semigroups on Frechet Spaces and Equations with Infinite Delays
Indian Academy of Sciences (India)
In this paper, we show existence and uniqueness of a solution to a functional differential equation with infinite delay. We choose an appropriate Frechet space so as to cover a large class of functions to be used as initial functions to obtain existence and uniqueness of solutions.
Infinitely many sign-changing solutions of an elliptic problem ...
Indian Academy of Sciences (India)
MOUSOMI BHAKTA
Infinitely many sign-changing solutions of an elliptic problem involving critical Sobolev and Hardy–Sobolev exponent. MOUSOMI BHAKTA. Department of Mathematics, Indian Institute of Science Education and Research,. Pashan, Pune 411 008, India. E-mail: mousomi@iiserpune.ac.in. MS received 27 May 2015; revised ...
Infinite range correlations of intensity in random media
Indian Academy of Sciences (India)
Infinite range correlations of intensity in random media. A RETZKER and B SHAPIRO. Department of Physics, Technion-Israel Institute of Technology, Haifa 32000, Israel. Abstract. We study a new type of long-range correlations for waves propagating in a random medium. These correlations originate from scattering events ...
Plasmonic waves of a semi-infinite random nanocomposite
Energy Technology Data Exchange (ETDEWEB)
Moradi, Afshin [Department of Basic Sciences, Kermanshah University of Technology, Kermanshah, Iran and Department of Nano Science, Institute for Studies in Theoretical Physics and Mathematics (IPM), Tehran (Iran, Islamic Republic of)
2013-10-15
The dispersion curves of the plasmonic waves of a semi-infinite random metal-dielectric nanocomposite, consisting of bulk metal embedded with dielectric inclusions, are presented. Two branches of p-polarized surface plasmon-polariton modes are found to exist. The possibility of experimentally observing the surface waves by attenuated total reflection is demonstrated.
Rank theorem in infinite dimension and lagrange multipliers
Blot, Joël
2018-01-01
We use an extension to the infinite dimension of the rank theorem of the differential calculus to establish a Karush-Huhn-Tucker theorem for optimization problems in Banach spaces. We provide an application to variational problems on bounded processus under equality constraints.
Entropy of a black hole in infinite-derivative gravity
Myung, Yun Soo
2017-05-01
We compute the Wald entropy of the Schwarzschild black hole in the ghost-free, infinite-derivative gravity that is quadratic in curvature. This is not given purely by the area law but includes an additional contribution depending on the power of the d'Alembertian operator, when requiring that the massless graviton be the only propagating mode in the Minkowski spacetime.
Selfadjointness of the Liouville operator for infinite classical systems
International Nuclear Information System (INIS)
Marchioro, C.; Pellegrinotti, A.; Pulvirenti, M.
1978-01-01
We study some properties of the time evolution of an infinite one dimensional hard core system with singular two body interaction. We show that the Liouville operator is essentially antiselfadjoint an the algebra of local observables. Some consequences of this result are also discussed. (orig.) [de
Infinite conditional random fields for human behavior analysis
Bousmalis, Konstantinos; Zafeiriou, Stefanos; Morency, Louis-Philippe; Pantic, Maja
Hidden conditional random fields (HCRFs) are discriminative latent variable models that have been shown to successfully learn the hidden structure of a given classification problem (provided an appropriate validation of the number of hidden states). In this brief, we present the infinite HCRF
Semigroups on Frechet spaces and equations with infinite delays
Indian Academy of Sciences (India)
In this paper, we show existence and uniqueness of a solution to a functional differential equation with infinite delay. We choose an appropriate Frechet space so as to cover a large class of functions to be used as initial functions to obtain existence and uniqueness of solutions.
Theory of Spin Waves in Strongly Anisotropic Magnets
DEFF Research Database (Denmark)
Lindgård, Per-Anker; Cooke, J. F.
1976-01-01
A new infinite-order perturbation approach to the theory of spin waves in strongly anisotropic magnets is introduced. The system is transformed into one with effective two-ion anisotropy and considerably reduced ground-state corrections. A general expression for the spin-wave energy, valid to any...
Morichere, D; Malliaras, G.G; Krasnikov, V.V.; Bolink, H.J; Hadziioannou, G
The use of polymers as photorefractive materials offers many advantages : flexibility in synthesis, doping, processing and low cost. The required functionalities responsible for photorefractivity, namely charge generation, transport, trapping and linear electrooptic effect are given in the polymer
Indian Academy of Sciences (India)
polymer nanocompo- sites are used as advanced toner materials for high quality colour copiers and printers and as contrast agents in NMR analysis, memory devices. .... tions on polymer nanocomposite can thus pay rich dividends. Suggested Reading. [1] Metal-Polymer Nanocomposites Nicolais, Luigi(ed.) ; Carotenuto,.
Cycles through all finite vertex sets in infinite graphs
DEFF Research Database (Denmark)
Kundgen, Andre; Li, Binlong; Thomassen, Carsten
2017-01-01
that every one-ended planar cubic 3-connected bipartite graph has a Hamiltonian curve. It is also equivalent to the statement that every planar cubic 3-connected bipartite graph with a nowhere-zero 3-flow (with no restriction on the number of ends) has a Hamiltonian curve. However, there are 7-ended planar......A closed curve in the Freudenthal compactification |G| of an infinite locally finite graph G is called a Hamiltonian curve if it meets every vertex of G exactly once (and hence it meets every end at least once). We prove that |G| has a Hamiltonian curve if and only if every finite vertex set of G...... is contained in a cycle of G. We apply this to extend a number of results and conjectures on finite graphs to Hamiltonian curves in infinite locally finite graphs. For example, Barnette’s conjecture (that every finite planar cubic 3-connected bipartite graph is Hamiltonian) is equivalent to the statement...
Abstraction and Learning for Infinite-State Compositional Verification
Directory of Open Access Journals (Sweden)
Dimitra Giannakopoulou
2013-09-01
Full Text Available Despite many advances that enable the application of model checking techniques to the verification of large systems, the state-explosion problem remains the main challenge for scalability. Compositional verification addresses this challenge by decomposing the verification of a large system into the verification of its components. Recent techniques use learning-based approaches to automate compositional verification based on the assume-guarantee style reasoning. However, these techniques are only applicable to finite-state systems. In this work, we propose a new framework that interleaves abstraction and learning to perform automated compositional verification of infinite-state systems. We also discuss the role of learning and abstraction in the related context of interface generation for infinite-state components.
LES investigation of infinite staggered wind-turbine arrays
International Nuclear Information System (INIS)
Yang, Xiaolei; Sotiropoulos, Fotis
2014-01-01
The layouts of turbines affect the turbine wake interactions and thus the wind farm performance. The wake interactions in infinite staggered wind-turbine arrays are investigated and compared with infinite aligned turbine arrays in this paper. From the numerical results we identify three types of wake behaviours, which are significantly different from wakes in aligned wind-turbine arrays. For the first type, each turbine wake interferes with the pair of staggered downstream turbine wakes and the aligned downstream turbine. For the second type, each turbine wake interacts with the first two downstream turbine wakes but does not show significant interference with the second aligned downstream turbine. For the third type, each turbine wake recovers immediately after passing through the gap of the first two downstream turbines and has little interaction with the second downstream turbine wakes The extracted power density and power efficiency are also studied and compared with aligned wind-turbine arrays
Quantum spin systems on infinite lattices a concise introduction
Naaijkens, Pieter
2017-01-01
This course-based primer offers readers a concise introduction to the description of quantum mechanical systems with infinitely many degrees of freedom – and quantum spin systems in particular – using the operator algebraic approach. Here, the observables are modeled using elements of some operator algebra, usually a C*-algebra. This text introduces readers to the framework and the necessary mathematical tools without assuming much mathematical background, making it more accessible than advanced monographs. The book also highlights the usefulness of the so-called thermodynamic limit of quantum spin systems, which is the limit of infinite system size. For example, this makes it possible to clearly distinguish between local and global properties, without having to keep track of the system size. Together with Lieb-Robinson bounds, which play a similar role in quantum spin systems to that of the speed of light in relativistic theories, this approach allows ideas from relativistic field theories to be implemen...
Statistical inference using weak chaos and infinite memory
International Nuclear Information System (INIS)
Welling, Max; Chen Yutian
2010-01-01
We describe a class of deterministic weakly chaotic dynamical systems with infinite memory. These 'herding systems' combine learning and inference into one algorithm, where moments or data-items are converted directly into an arbitrarily long sequence of pseudo-samples. This sequence has infinite range correlations and as such is highly structured. We show that its information content, as measured by sub-extensive entropy, can grow as fast as K log T, which is faster than the usual 1/2 K log T for exchangeable sequences generated by random posterior sampling from a Bayesian model. In one dimension we prove that herding sequences are equivalent to Sturmian sequences which have complexity exactly log(T + 1). More generally, we advocate the application of the rich theoretical framework around nonlinear dynamical systems, chaos theory and fractal geometry to statistical learning.
Infinite statistics and the SU(1, 1) phase operator
International Nuclear Information System (INIS)
Gerry, Christopher C
2005-01-01
A few years ago, Agarwal (1991 Phys. Rev. A 44 8398) showed that the Susskind-Glogower phase operators, expressible in terms of Bose operators, provide a realization of the algebra for particles obeying infinite statistics. In this paper we show that the SU(1, 1) phase operators, constructed in terms of the elements of the su(1, 1) Lie algebra, also provide a realization of the algebra for infinite statistics. There are many realizations of the su(1, 1) algebra in terms of single or multimode bose operators, three of which are discussed along with their corresponding phase states. The Susskind-Glogower phase operator is a special case of the SU(1, 1) phase operator associated with the Holstein-Primakoff realization of su(1, 1). (letter to the editor)
Positive operator semigroups from finite to infinite dimensions
Bátkai, András; Rhandi, Abdelaziz
2017-01-01
This book gives a gentle but up-to-date introduction into the theory of operator semigroups (or linear dynamical systems), which can be used with great success to describe the dynamics of complicated phenomena arising in many applications. Positivity is a property which naturally appears in physical, chemical, biological or economic processes. It adds a beautiful and far reaching mathematical structure to the dynamical systems and operators describing these processes. In the first part, the finite dimensional theory in a coordinate-free way is developed, which is difficult to find in literature. This is a good opportunity to present the main ideas of the Perron-Frobenius theory in a way which can be used in the infinite dimensional situation. Applications to graph matrices, age structured population models and economic models are discussed. The infinite dimensional theory of positive operator semigroups with their spectral and asymptotic theory is developed in the second part. Recent applications illustrate t...
Studying the Quality of Colloquial Infinitives in Moin Persian Dictionary
Directory of Open Access Journals (Sweden)
Parisa Shekoohi
2017-04-01
Full Text Available Mohammad Moin has been considered as one of the most committed literary men of the present time who recorded a considerable amount of Persian words, expressions, and declarations in his own 6 volumes Persian dictionary according to scientific research methods and in a different way in comparison to the previous dictionaries. This article argues the quality of colloquial infinitives which have been recorded in Moin Persian Dictionary. The most important obstacles in all researches related to literature and colloquial language is the recognition criterion of "being colloquial". In this article, the recognition criterion is that of Moin's criterion who was a great master in this field. In the other words, any infinitives in front of which he put the abbreviation "Ɂam", have been extracted and at the next stage, according to the syntactic resources, have been divided into 8 categories. Finally, the examples of each category have been presented through tables.
Infinite-order symmetries for quantum separable systems
International Nuclear Information System (INIS)
Miller, W.; Kalnins, E.G.; Kress, J.M.; Pogosyan, G.S.
2005-01-01
A calculus to describe the (in general) infinite-order differential operator symmetries of a nonrelativistic Schroedinger eigenvalue equation that admits an orthogonal separation of variables in Riemannian n space is developed. The infinite-order calculus exhibits structure not apparent when one studies only finite-order symmetries. The search for finite-order symmetries can then be reposed as one of looking for solutions of a coupled system of PDEs that are polynomial in certain parameters. Among the simple consequences of the calculus is that one can generate algorithmically a canonical basis for the space. Similarly, it can develop a calculus for conformal symmetries of the time-dependent Schroedinger equation if it admits R separation in some coordinate system. This leads to energy-shifting symmetries [ru
Infinite-Order Symmetries for Quantum Separable Systems
International Nuclear Information System (INIS)
Miller, W.; Kalnins, E.G.; Kress, J.M.; Pogosyan, G.S.
2005-01-01
We develop a calculus to describe the (in general) infinite-order differential operator symmetries of a nonrelativistic Schroedinger eigenvalue equation that admits an orthogonal separation of variables in Riemannian n space. The infinite-order calculus exhibits structure not apparent when one studies only finite-order symmetries. The search for finite-order symmetries can then be reposed as one of looking for solutions of a coupled system of PDEs that are polynomial in certain parameters. Among the simple consequences of the calculus is that one can generate algorithmically a canonical basis for the space. Similarly, we can develop a calculus for conformal symmetries of the time-dependent Schroedinger equation if it admits R separation in some coordinate system. This leads to energy-shifting symmetries
Scattering by closely spaced infinite cylinders in an absorbing medium
Directory of Open Access Journals (Sweden)
S.-C. Lee
2011-09-01
Full Text Available Scattering by closely spaced parallel infinite cylinders in an absorbing medium is considered in this paper. The source wave is arbitrarily polarized and propagates in a general direction at the cylinders. The formulation utilizes the Hertz potential approach, and the scattering cross section and intensity distribution in the far-field are developed. Numerical results are presented to illustrate the influence of the absorbing medium on the scattering properties of two configurations of closely-spaced cylinders.
Sum rules for effective resistances in infinite graphs
Markowsky, Greg; Palacios, José Luis
2017-04-01
Extending work of Foster, Doyle, and others, we show how the Foster theorems, a family of results concerning effective resistances on finite graphs, can in certain cases be extended to infinite graphs. A family of sum rules is then obtained, which allows one to easily calculate the sum of the resistances over all paths of a given length. The results are illustrated with some of the most common grids in the plane, including the square, triangular, and hexagonal grids.
Copula Based Factorization in Bayesian Multivariate Infinite Mixture Models
Martin Burda; Artem Prokhorov
2012-01-01
Bayesian nonparametric models based on infinite mixtures of density kernels have been recently gaining in popularity due to their flexibility and feasibility of implementation even in complicated modeling scenarios. In economics, they have been particularly useful in estimating nonparametric distributions of latent variables. However, these models have been rarely applied in more than one dimension. Indeed, the multivariate case suffers from the curse of dimensionality, with a rapidly increas...
Numerical Integration of the Transport Equation For Infinite Homogeneous Media
Energy Technology Data Exchange (ETDEWEB)
Haakansson, Rune
1962-01-15
The transport equation for neutrons in infinite homogeneous media is solved by direct numerical integration. Accounts are taken to the anisotropy and the inelastic scattering. The integration has been performed by means of the trapezoidal rule and the length of the energy intervals are constant in lethargy scale. The machine used is a Ferranti Mercury computer. Results are given for water, heavy water, aluminium water mixture and iron-aluminium-water mixture.
Borel hierarchies in infinite products of Polish spaces
Indian Academy of Sciences (India)
E-mail: rana@isical.ac.in; maitra@stat.umn.edu. MS received 22 August 2005; revised 28 August 2006. Abstract. Let H be a product of countably infinite number of copies of an uncountable. Polish space X. Let ξ ( ξ ) be the class of Borel sets of additive class ξ for the product of copies of the discrete topology on X (the Polish ...
Extension of belief functions to infinite-valued events
Czech Academy of Sciences Publication Activity Database
Kroupa, Tomáš
2012-01-01
Roč. 16, č. 11 (2012), s. 1851-1861 ISSN 1432-7643 R&D Projects: GA MŠk 1M0572; GA ČR GA201/09/1891 Institutional support: RVO:67985556 Keywords : belief function * MV-algebra * Moebius transform Subject RIV: BA - General Mathematics Impact factor: 1.124, year: 2012 http://library.utia.cas.cz/separaty/2012/MTR/kroupa-extension of belief functions to infinite-valued events.pdf
Recent results relevant to the evaluation of infinite series
International Nuclear Information System (INIS)
Garibotti, C.R.; Grinstein, F.F.
1981-07-01
Convergence properties of the Punctual Pade Approximant method, as a procedure for the evaluation of some particular infinite series, are reviewed. Previous theorems are extended and stated more generally, so that they may be of use in other areas, besides that of potential scattering theory for which they were originally intended. The results show the value of the approach as a convergence acceleration method when dealing with convergent series, and as a regularizing procedure, otherwise. (author)
Annihilators in infinite-dimensional Grassmann-Banach algebras
International Nuclear Information System (INIS)
Ivashchuk, V.D.
1989-01-01
A family of infinite-dimensional Grassmann-Banach algebras over a complete normed field K is considered. It is shown that every element G of the family is an associative supercommutative Banach superalgebra over K: G double-bond G 0 circle-plus G 1 with zero annihilators G 0 perpendicular double-bond G 1 perpendicular double-bond(G 1 (κ) ) perpendicular double-bond(0), k ≥ 2
Marketingová strategie wellness centra Infinit Maximus
Přikrylová, Michaela
2015-01-01
The thesis deals with the analysis of present situation of marketing and promo-tional mix wellness centre Infinit Maximus and the proposal of a new marketing and promotional strategy that should contribute to its effectiveness. The theoreti-cal part is focused on a summary of theoretical findings on this topic, including the most important terms of marketing theory. The practical part devotes to analysis of present situation and there is suggested the proposal of a new marketing strategy, bas...
Subdifferential of Optimal Value Functions in Nonlinear Infinite Programming
International Nuclear Information System (INIS)
Huy, N. Q.; Giang, N. D.; Yao, J.-C.
2012-01-01
This paper presents an exact formula for computing the normal cones of the constraint set mapping including the Clarke normal cone and the Mordukhovich normal cone in infinite programming under the extended Mangasarian-Fromovitz constraint qualification condition. Then, we derive an upper estimate as well as an exact formula for the limiting subdifferential of the marginal/optimal value function in a general Banach space setting.
Progress of our knowledge towards the infinitely small
Energy Technology Data Exchange (ETDEWEB)
Teillac, J.
1985-10-01
The lecture given the 16th of October 1984 at ENSTA by Mr Teillac is reproduced here. He leads us in the infinitely small realm, through these queer families of particles and help us to catch a glimpse to the complexity of the interactions existing there. Underlining the always growing power of our investigation means, he gives an outline of the new orientations of physics.
Explosion and linear transit times in infinite trees
O. Amini; L. Devroye; S. Griffiths; N.K. Olver (Neil)
2014-01-01
textabstractLet $T$ be an infinite rooted tree with weights $w_e$ assigned to its edges. Denote by $m_n(T)$ the minimum weight of a path from the root to a node of the $n$th generation. We consider the possible behaviour of $m_n(T)$ with focus on the two following cases: we say $T$ is explosive if
Wormhole effect in a strong topological insulator
Rosenberg, G.; Guo, H.-M.; Franz, M.
2010-07-01
An infinitely thin solenoid carrying magnetic flux Φ (a “Dirac string”) inserted into an ordinary band insulator has no significant effect on the spectrum of electrons. In a strong topological insulator, remarkably, such a solenoid carries protected gapless one-dimensional fermionic modes when Φ=hc/2e . These modes are spin-filtered and represent a distinct bulk manifestation of the topologically nontrivial insulator. We establish this “wormhole” effect by both general qualitative considerations and by numerical calculations within a minimal lattice model. We also discuss the possibility of experimental observation of a closely related effect in artificially engineered nanostructures.
Infinite variance in fermion quantum Monte Carlo calculations
Shi, Hao; Zhang, Shiwei
2016-03-01
For important classes of many-fermion problems, quantum Monte Carlo (QMC) methods allow exact calculations of ground-state and finite-temperature properties without the sign problem. The list spans condensed matter, nuclear physics, and high-energy physics, including the half-filled repulsive Hubbard model, the spin-balanced atomic Fermi gas, and lattice quantum chromodynamics calculations at zero density with Wilson Fermions, and is growing rapidly as a number of problems have been discovered recently to be free of the sign problem. In these situations, QMC calculations are relied on to provide definitive answers. Their results are instrumental to our ability to understand and compute properties in fundamental models important to multiple subareas in quantum physics. It is shown, however, that the most commonly employed algorithms in such situations have an infinite variance problem. A diverging variance causes the estimated Monte Carlo statistical error bar to be incorrect, which can render the results of the calculation unreliable or meaningless. We discuss how to identify the infinite variance problem. An approach is then proposed to solve the problem. The solution does not require major modifications to standard algorithms, adding a "bridge link" to the imaginary-time path integral. The general idea is applicable to a variety of situations where the infinite variance problem may be present. Illustrative results are presented for the ground state of the Hubbard model at half-filling.
Verifying the Simulation Hypothesis via Infinite Nested Universe Simulacrum Loops
Sharma, Vikrant
2017-01-01
The simulation hypothesis proposes that local reality exists as a simulacrum within a hypothetical computer's dimension. More specifically, Bostrom's trilemma proposes that the number of simulations an advanced 'posthuman' civilization could produce makes the proposition very likely. In this paper a hypothetical method to verify the simulation hypothesis is discussed using infinite regression applied to a new type of infinite loop. Assign dimension n to any computer in our present reality, where dimension signifies the hierarchical level in nested simulations our reality exists in. A computer simulating known reality would be dimension (n-1), and likewise a computer simulating an artificial reality, such as a video game, would be dimension (n +1). In this method, among others, four key assumptions are made about the nature of the original computer dimension n. Summations show that regressing such a reality infinitely will create convergence, implying that the verification of whether local reality is a grand simulation is feasible to detect with adequate compute capability. The action of reaching said convergence point halts the simulation of local reality. Sensitivities to the four assumptions and implications are discussed.
Single file diffusion into a semi-infinite tube.
Farrell, Spencer G; Brown, Aidan I; Rutenberg, Andrew D
2015-11-23
We investigate single file diffusion (SFD) of large particles entering a semi-infinite tube, such as luminal diffusion of proteins into microtubules or flagella. While single-file effects have no impact on the evolution of particle density, we report significant single-file effects for individually tracked tracer particle motion. Both exact and approximate ordering statistics of particles entering semi-infinite tubes agree well with our stochastic simulations. Considering initially empty semi-infinite tubes, with particles entering at one end starting from an initial time t = 0, tracked particles are initially super-diffusive after entering the system, but asymptotically diffusive at later times. For finite time intervals, the ratio of the net displacement of individual single-file particles to the average displacement of untracked particles is reduced at early times and enhanced at later times. When each particle is numbered, from the first to enter (n = 1) to the most recent (n = N), we find good scaling collapse of this distance ratio for all n. Experimental techniques that track individual particles, or local groups of particles, such as photo-activation or photobleaching of fluorescently tagged proteins, should be able to observe these single-file effects. However, biological phenomena that depend on local concentration, such as flagellar extension or luminal enzymatic activity, should not exhibit single-file effects.
Anomalous current in periodic Lorentz gases with infinite horizon
International Nuclear Information System (INIS)
Dolgopyat, Dmitrii I; Chernov, Nikolai I
2009-01-01
Electric current is studied in a two-dimensional periodic Lorentz gas in the presence of a weak homogeneous electric field. When the horizon is finite, that is, free flights between collisions are bounded, the resulting current J is proportional to the voltage difference E, that is, J=1/2 D*E+o(||E||), where D* is the diffusion matrix of a Lorentz particle moving freely without an electric field (see a mathematical proof). This formula agrees with Ohm's classical law and the Einstein relation. Here the more difficult model with an infinite horizon is investigated. It is found that infinite corridors between scatterers allow the particles (electrons) to move faster, resulting in an abnormal current (causing 'superconductivity'). More precisely, the current is now given by J=1/2 DE| log||E|| | + O(||E||), where D is the 'superdiffusion' matrix of a Lorentz particle moving freely without an electric field. This means that Ohm's law fails in this regime, but the Einstein relation (suitably interpreted) still holds. New results are also obtained for the infinite-horizon Lorentz gas without external fields, complementing recent studies by Szasz and Varju. Bibliography: 31 titles.
Nakajima, Hajime; Dijkstra, Peter; Loos, Katja
2017-01-01
The main motivation for development of biobased polymers was their biodegradability, which is becoming important due to strong public concern about waste. Reflecting recent changes in the polymer industry, the sustainability of biobased polymers allows them to be used for general and engineering
Polymer adsorption kinetics: effects of supply rate.
Eijk, van M.C.P.; Cohen Stuart, M.A.
1997-01-01
The saturation adsorbed amount of polymers on solid surfaces is mostly found to be independent of the polymer transport rate, or flux J, to the surface. In most cases this is because the experimental rate of transport strongly deviates from the relaxation rate in the polymer layer. We studied the
Lilja, Dan
2017-11-01
Since its inception in the 1970s at the hands of Feigenbaum and, independently, Coullet and Tresser the study of renormalization operators in dynamics has been very successful at explaining universality phenomena observed in certain families of dynamical systems. The first proof of existence of a hyperbolic fixed point for renormalization of area-preserving maps was given by Eckmann et al. (Mem Am Math Soc 47(289):vi+122, 1984). However, there are still many things that are unknown in this setting, in particular regarding the invariant Cantor sets of infinitely renormalizable maps. In this paper we show that the invariant Cantor set of period doubling type of any infinitely renormalizable area-preserving map in the universality class of the Eckmann-Koch-Wittwer renormalization fixed point is always contained in a Lipschitz curve but never contained in a smooth curve. This extends previous results by de Carvalho, Lyubich and Martens about strongly dissipative maps of the plane close to unimodal maps to the area-preserving setting. The method used for constructing the Lipschitz curve is very similar to the method used in the dissipative case but proving the nonexistence of smooth curves requires new techniques.
On the number of return words in infinite words with complexity 2n+1
Vuillon, Laurent
2000-01-01
In this article, we count the number of return words in some infinite words with complexity 2n+1. We also consider some infinite words given by codings of rotation and interval exchange transformations on k intervals. We prove that the number of return words over a given word w for these infinite words is exactly k.
Kozłowska, Marta Karolina; Domańska, Urszula; Lempert, Małgorzata; Rogalski, Marek
2005-03-18
The partial molar volumes, V1(M), and the molar volume of isotactic crystalline low-molecular-weight poly(1-butene), iPBu-1, V1, have been calculated from the measured density of {iPBu-1 + solvent (n-hexane, n-heptane, n-nonane, n-decane, p-xylene, cyclohexane and chloroform)} systems. Some of the thermodynamic quantities were also obtained for the iPBu-1 with eight hydrocarbons (n-octane, n-decane, n-undecane, n-dodecane, n-tridecane, o-xylene, m-xylene, p-xylene) by the method of inverse gas chromatography at various temperatures. The weight fraction activity coefficients of the solvent at infinite dilution, omega2(infinity) and the Flory-Huggins thermodynamic interaction parameters, chi21(infinity), between polymer and solvents were determined. The partial molar free energy, deltaG2(infinity), the partial molar heat of mixing, deltaH2(infinity), at infinite dilution and the polymer solubility parameter, delta1, were calculated. Additionally, the (solid + liquid) binary mixtures equilibria, SLE, of iPBu-1 with three hydrocarbons (n-octane, n-decane and m-xylene) were studied by a dynamic method. By performing these experiments over a large concentration range, the T-x phase diagrams of the polymer-solvent systems were constructed. The excess Gibbs energy models were used to describe the nonideal behaviour of the liquid phase. The omega2(infinity) were determined from the solubility measurements and were predicted by using the UNIFAC FV model.
Nakajima, Hajime; Dijkstra, Peter; Loos, Katja
2017-01-01
The main motivation for development of biobased polymers was their biodegradability, which is becoming important due to strong public concern about waste. Reflecting recent changes in the polymer industry, the sustainability of biobased polymers allows them to be used for general and engineering applications. This expansion is driven by the remarkable progress in the processes for refining biomass feedstocks to produce biobased building blocks that allow biobased polymers to have more versati...
Infinite coherence time of edge spins in finite-length chains
Maceira, Ivo A.; Mila, Frédéric
2018-02-01
Motivated by the recent observation that exponentially long coherence times can be achieved for edge spins in models with strong zero modes, we study the impact of level crossings in finite-length spin chains on the dynamics of the edge spins. Focusing on the X Y spin-1 /2 chain with a transverse or longitudinal magnetic field, two models relevant to understanding recent experimental results on cobalt adatoms, we show that the edge spins can remain coherent for an infinite time even for a finite-length chain if the magnetic field is tuned to a value at which there is a level crossing. Furthermore, we show that the edge spins remain coherent for any initial state for the integrable case of a transverse field because all states have level crossings at the same value of the field, while the coherence time is increasingly large for lower temperatures in the case of a longitudinal field, which is nonintegrable.
Ablative Rayleigh Taylor instability in the limit of an infinitely large density ratio
Clavin, Paul; Almarcha, Christophe
2005-05-01
The instability of ablation fronts strongly accelerated toward the dense medium under the conditions of inertial confinement fusion (ICF) is addressed in the limit of an infinitely large density ratio. The analysis serves to demonstrate that the flow is irrotational to first order, reducing the nonlinear analysis to solve a two-potential flows problem. Vorticity appears at the following orders in the perturbation analysis. This result simplifies greatly the analysis. The possibility for using boundary integral methods opens new perspectives in the nonlinear theory of the ablative RT instability in ICF. A few examples are given at the end of the Note. To cite this article: P. Clavin, C. Almarcha, C. R. Mecanique 333 (2005).
Interference Energy Spectrum of the Infinite Square Well
Directory of Open Access Journals (Sweden)
Mordecai Waegell
2016-04-01
Full Text Available Certain superposition states of the 1-D infinite square well have transient zeros at locations other than the nodes of the eigenstates that comprise them. It is shown that if an infinite potential barrier is suddenly raised at some or all of these zeros, the well can be split into multiple adjacent infinite square wells without affecting the wavefunction. This effects a change of the energy eigenbasis of the state to a basis that does not commute with the original, and a subsequent measurement of the energy now reveals a completely different spectrum, which we call the interference energy spectrum of the state. This name is appropriate because the same splitting procedure applied at the stationary nodes of any eigenstate does not change the measurable energy of the state. Of particular interest, this procedure can result in measurable energies that are greater than the energy of the highest mode in the original superposition, raising questions about the conservation of energy akin to those that have been raised in the study of superoscillations. An analytic derivation is given for the interference spectrum of a given wavefunction Ψ ( x , t with N known zeros located at points s i = ( x i , t i . Numerical simulations were used to verify that a barrier can be rapidly raised at a zero of the wavefunction without significantly affecting it. The interpretation of this result with respect to the conservation of energy and the energy-time uncertainty relation is discussed, and the idea of alternate energy eigenbases is fleshed out. The question of whether or not a preferred discrete energy spectrum is an inherent feature of a particle’s quantum state is examined.
Geometric MCMC for infinite-dimensional inverse problems
Beskos, Alexandros; Girolami, Mark; Lan, Shiwei; Farrell, Patrick E.; Stuart, Andrew M.
2017-04-01
Bayesian inverse problems often involve sampling posterior distributions on infinite-dimensional function spaces. Traditional Markov chain Monte Carlo (MCMC) algorithms are characterized by deteriorating mixing times upon mesh-refinement, when the finite-dimensional approximations become more accurate. Such methods are typically forced to reduce step-sizes as the discretization gets finer, and thus are expensive as a function of dimension. Recently, a new class of MCMC methods with mesh-independent convergence times has emerged. However, few of them take into account the geometry of the posterior informed by the data. At the same time, recently developed geometric MCMC algorithms have been found to be powerful in exploring complicated distributions that deviate significantly from elliptic Gaussian laws, but are in general computationally intractable for models defined in infinite dimensions. In this work, we combine geometric methods on a finite-dimensional subspace with mesh-independent infinite-dimensional approaches. Our objective is to speed up MCMC mixing times, without significantly increasing the computational cost per step (for instance, in comparison with the vanilla preconditioned Crank-Nicolson (pCN) method). This is achieved by using ideas from geometric MCMC to probe the complex structure of an intrinsic finite-dimensional subspace where most data information concentrates, while retaining robust mixing times as the dimension grows by using pCN-like methods in the complementary subspace. The resulting algorithms are demonstrated in the context of three challenging inverse problems arising in subsurface flow, heat conduction and incompressible flow control. The algorithms exhibit up to two orders of magnitude improvement in sampling efficiency when compared with the pCN method.
Infinite volume of noncommutative black hole wrapped by finite surface
Energy Technology Data Exchange (ETDEWEB)
Zhang, Baocheng, E-mail: zhangbc.zhang@yahoo.com [School of Mathematics and Physics, China University of Geosciences, Wuhan 430074 (China); You, Li, E-mail: lyou@mail.tsinghua.edu.cn [State Key Laboratory of Low Dimensional Quantum Physics, Department of Physics, Tsinghua University, Beijing 100084 (China)
2017-02-10
The volume of a black hole under noncommutative spacetime background is found to be infinite, in contradiction with the surface area of a black hole, or its Bekenstein–Hawking (BH) entropy, which is well-known to be finite. Our result rules out the possibility of interpreting the entropy of a black hole by counting the number of modes wrapped inside its surface if the final evaporation stage can be properly treated. It implies the statistical interpretation for the BH entropy can be independent of the volume, provided spacetime is noncommutative. The effect of radiation back reaction is found to be small and doesn't influence the above conclusion.
Superconducting spin-triplet-MRAM with infinite magnetoresistance ratio
Energy Technology Data Exchange (ETDEWEB)
Lenk, Daniel; Ullrich, Aladin; Obermeier, Guenter; Mueller, Claus; Krug von Nidda, Hans-Albrecht; Horn, Siegfried; Tidecks, Reinhard [Institut fuer Physik, Universitaet Augsburg, D-86159 Augsburg (Germany); Morari, Roman [Institut fuer Physik, Universitaet Augsburg, D-86159 Augsburg (Germany); D. Ghitsu Institute of Electronic Engineering and Nanotechnologies ASM, Academiei Str. 3/3, MD2028 Kishinev (Moldova, Republic of); Solid State Physics Department, Kazan Federal University, 420008 Kazan (Russian Federation); Zdravkov, Vladimir I. [Institut fuer Physik, Universitaet Augsburg, D-86159 Augsburg (Germany); D. Ghitsu Institute of Electronic Engineering and Nanotechnologies ASM, Academiei Str. 3/3, MD2028 Kishinev (Moldova, Republic of); Institute of Applied Physics and Interdisciplinary Nanoscience Center, Universitaet Hamburg, Jungiusstrasse 9A, D-20355 Hamburg (Germany); Sidorenko, Anatoli S. [D. Ghitsu Institute of Electronic Engineering and Nanotechnologies ASM, Academiei Str. 3/3, MD2028 Kishinev (Moldova, Republic of); Tagirov, Lenar R. [Institut fuer Physik, Universitaet Augsburg, D-86159 Augsburg (Germany); Solid State Physics Department, Kazan Federal University, 420008 Kazan (Russian Federation)
2016-07-01
We fabricated a nanolayered hybrid superconductor-ferromagnet spin-valve structure, i.e. the superconducting transition temperature of this structure depends on its magnetic history. The observed spin-valve effect is based on the generation of the long range odd in frequency triplet component, arising from a non-collinear relative orientation of the constituent ferromagnetic layers. We investigated the effect both as a function of the sweep amplitude of the magnetic field, determining the magnetic history, and the applied transport current. Moreover, we demonstrate the possibility of switching the system from the normal o the superconducting state by applying field pulses, yielding an infinite magnetoresistance ratio.
Harmonic Functions and Potentials on Finite or Infinite Networks
Anandam, Victor
2011-01-01
Random walks, Markov chains and electrical networks serve as an introduction to the study of real-valued functions on finite or infinite graphs, with appropriate interpretations using probability theory and current-voltage laws. The relation between this type of function theory and the (Newton) potential theory on the Euclidean spaces is well-established. The latter theory has been variously generalized, one example being the axiomatic potential theory on locally compact spaces developed by Brelot, with later ramifications from Bauer, Constantinescu and Cornea. A network is a graph with edge-w
Nizamudin Hussain, Performance Limitations and Estimates for Infinite Array Antennas
Hussain, Nizamudin
2013-01-01
A novel quantitative measure for predicting the performance of arrays is tested on a few selected wide band arrays. This measure is called the array figure of merit. It is valid for lin-early polarized, infinite planar arrays, which are backed by a perfectly conducting ground plane. It predicts performance of arrays (which are free from grating lobes) in the E- or H-plane. The array figure of merit builds on the low frequency asymptotic expansion of the reflection coefficient and a sumrule of...
Backward Stochastic H2/H∞ Control: Infinite Horizon Case
Directory of Open Access Journals (Sweden)
Zhen Wu
2014-01-01
Full Text Available The mixed H2/H∞ control problem is studied for systems governed by infinite horizon backward stochastic differential equations (BSDEs with exogenous disturbance signal. A necessary and sufficient condition for the existence of a unique solution to the H2/H∞ control problem is derived. The equivalent feedback solution is also discussed. Contrary to deterministic or stochastic forward case, the feedback solution is no longer feedback of the current state; rather, it is feedback of the entire history of the state.
On the problem of quantum control in infinite dimensions
Mendes, R. Vilela; Man'ko, Vladimir I.
2010-01-01
In the framework of bilinear control of the Schr\\"odinger equation with bounded control operators, it has been proved that the reachable set has a dense complemement in ${\\cal S}\\cap {\\cal H}^{2}$. Hence, in this setting, exact quantum control in infinite dimensions is not possible. On the other hand it is known that there is a simple choice of operators which, when applied to an arbitrary state, generate dense orbits in Hilbert space. Compatibility of these two results is established in this...
Differentiation Theory over Infinite-Dimensional Banach Spaces
Directory of Open Access Journals (Sweden)
Claudio Asci
2016-01-01
Full Text Available We study, for any positive integer k and for any subset I of N⁎, the Banach space EI of the bounded real sequences xnn∈I and a measure over RI,B(I that generalizes the k-dimensional Lebesgue one. Moreover, we expose a differentiation theory for the functions defined over this space. The main result of our paper is a change of variables’ formula for the integration of the measurable real functions on RI,B(I. This change of variables is defined by some infinite-dimensional functions with properties that generalize the analogous ones of the standard finite-dimensional diffeomorphisms.
Quantum magnets with anisotropic infinite range random interactions.
Arrachea, Liliana; Rozenberg, Marcelo J
2005-04-01
Using exact diagonalization techniques, we study the dynamical response of the anisotropic disordered Heisenberg model for systems of S=1/2 spins with infinite range random exchange interactions at temperature T=0. The model can be considered as a generalization, to the quantum case, of the well-known Sherrington-Kirkpatrick classical spin glass model. We also compute and study the behavior of the Edwards Anderson order parameter and energy per spin as the anisotropy evolves from the Ising to the Heisenberg limits.
Williams, Martha; Roberson, Luke; Caraccio, Anne
2010-01-01
This viewgraph presentation describes new technologies in polymer and material chemistry that benefits NASA programs and missions. The topics include: 1) What are Polymers?; 2) History of Polymer Chemistry; 3) Composites/Materials Development at KSC; 4) Why Wiring; 5) Next Generation Wiring Materials; 6) Wire System Materials and Integration; 7) Self-Healing Wire Repair; 8) Smart Wiring Summary; 9) Fire and Polymers; 10) Aerogel Technology; 11) Aerogel Composites; 12) Aerogels for Oil Remediation; 13) KSC's Solution; 14) Chemochromic Hydrogen Sensors; 15) STS-130 and 131 Operations; 16) HyperPigment; 17) Antimicrobial Materials; 18) Conductive Inks Formulations for Multiple Applications; and 19) Testing and Processing Equipment.
Ren, Jing M; McKenzie, Thomas G; Fu, Qiang; Wong, Edgar H H; Xu, Jiangtao; An, Zesheng; Shanmugam, Sivaprakash; Davis, Thomas P; Boyer, Cyrille; Qiao, Greg G
2016-06-22
Recent advances in controlled/living polymerization techniques and highly efficient coupling chemistries have enabled the facile synthesis of complex polymer architectures with controlled dimensions and functionality. As an example, star polymers consist of many linear polymers fused at a central point with a large number of chain end functionalities. Owing to this exclusive structure, star polymers exhibit some remarkable characteristics and properties unattainable by simple linear polymers. Hence, they constitute a unique class of technologically important nanomaterials that have been utilized or are currently under audition for many applications in life sciences and nanotechnologies. This article first provides a comprehensive summary of synthetic strategies towards star polymers, then reviews the latest developments in the synthesis and characterization methods of star macromolecules, and lastly outlines emerging applications and current commercial use of star-shaped polymers. The aim of this work is to promote star polymer research, generate new avenues of scientific investigation, and provide contemporary perspectives on chemical innovation that may expedite the commercialization of new star nanomaterials. We envision in the not-too-distant future star polymers will play an increasingly important role in materials science and nanotechnology in both academic and industrial settings.
Hallinan, Daniel T.; Balsara, Nitash P.
2013-07-01
This review article covers applications in which polymer electrolytes are used: lithium batteries, fuel cells, and water desalination. The ideas of electrochemical potential, salt activity, and ion transport are presented in the context of these applications. Potential is defined, and we show how a cell potential measurement can be used to ascertain salt activity. The transport parameters needed to fully specify a binary electrolyte (salt + solvent) are presented. We define five fundamentally different types of homogeneous electrolytes: type I (classical liquid electrolytes), type II (gel electrolytes), type III (dry polymer electrolytes), type IV (dry single-ion-conducting polymer electrolytes), and type V (solvated single-ion-conducting polymer electrolytes). Typical values of transport parameters are provided for all types of electrolytes. Comparison among the values provides insight into the transport mechanisms occurring in polymer electrolytes. It is desirable to decouple the mechanical properties of polymer electrolyte membranes from the ionic conductivity. One way to accomplish this is through the development of microphase-separated polymers, wherein one of the microphases conducts ions while the other enhances the mechanical rigidity of the heterogeneous polymer electrolyte. We cover all three types of conducting polymer electrolyte phases (types III, IV, and V). We present a simple framework that relates the transport parameters of heterogeneous electrolytes to homogeneous analogs. We conclude by discussing electrochemical stability of electrolytes and the effects of water contamination because of their relevance to applications such as lithium ion batteries.
Polymer chemistry (revised edition)
International Nuclear Information System (INIS)
Kim, Jae Mum
1987-02-01
This book deals with polymer chemistry, which is divided into fourteen chapters. The contents of this book are development of polymer chemistry, conception of polymer, measurement of polymer chemistry, conception of polymer, measurement of polymer, molecule structure of polymer, thermal prosperities of solid polymer, basic theory of polymerization, radical polymerization, ion polymerization, radical polymerization, copolymerization, polymerization by step-reaction, polymer reaction, crown polymer and inorganic polymer on classification and process of creation such as polymeric sulfur and carbon fiber.
Conformal field theories with infinitely many conservation laws
Todorov, Ivan
2013-02-01
Globally conformal invariant quantum field theories in a D-dimensional space-time (D even) have rational correlation functions and admit an infinite number of conserved (symmetric traceless) tensor currents. In a theory of a scalar field of dimension D-2 they were demonstrated to be generated by bilocal normal products of free massless scalar fields with an O(N), U(N), or Sp(2N) (global) gauge symmetry [B. Bakalov, N. M. Nikolov, K.-H. Rehren, and I. Todorov, "Unitary positive energy representations of scalar bilocal fields," Commun. Math. Phys. 271, 223-246 (2007), 10.1007/s00220-006-0182-2; e-print arXiv:math-ph/0604069v3; B. Bakalov, N. M. Nikolov, K.-H. Rehren, and I. Todorov, "Infinite dimensional Lie algebras in 4D conformal quantum field theory," J. Phys. A Math Theor. 41, 194002 (2008), 10.1088/1751-8113/41/19/194002; e-print arXiv:0711.0627v2 [hep-th
Conformal field theories with infinitely many conservation laws
Todorov, Ivan
2013-01-01
Globally conformal invariant quantum field theories in a D-dimensional space-time (D even) have rational correlation functions and admit an infinite number of conserved (symmetric traceless) tensor currents. In a theory of a scalar field of dimension D-2 they were demonstrated to be generated by bilocal normal products of free massless scalar fields with an O(N), U(N), or Sp(2N) (global) gauge symmetry [BNRT]. Recently, conformal field theories "with higher spin symmetry" were considered for D=3 in [MZ] where a similar result was obtained (exploiting earlier study of CFT correlators). We suggest that the proper generalization of the notion of a 2D chiral algebra to arbitrary (even or odd) dimension is precisely a CFT with an infinite series of conserved currents. We shall recast and complement (part of) the argument of Maldacena and Zhiboedov into the framework of our earlier work. We extend to D=4 the auxiliary Weyl-spinor formalism developed in [GPY] for D=3. The free field construction only follows for D>3...
To infinity and beyond a cultural history of the infinite
Maor, Eli
1987-01-01
The infinite! No other question has ever moved so profoundly the spirit of man; no other idea has so fruitfully stimulated his intellect; yet no other concept stands in greater need of clarification than that of the infinite. . . - David Hilbert (1862-1943) Infinity is a fathomless gulf, There is a story attributed to David Hilbert, the preeminent mathe into which all things matician whose quotation appears above. A man walked into a vanish. hotel late one night and asked for a room. "Sorry, we don't have o Marcus Aurelius (121- 180), Roman Emperor any more vacancies," replied the owner, "but let's see, perhaps and philosopher I can find you a room after alL" Leaving his desk, the owner reluctantly awakened his guests and asked them to change their rooms: the occupant of room #1 would move to room #2, the occupant of room #2 would move to room #3, and so on until each occupant had moved one room over. To the utter astonish ment of our latecomer, room #1 suddenly became vacated, and he happily moved in and...
Matrix albedo for discrete ordinates infinite-medium boundary condition
International Nuclear Information System (INIS)
Mathews, K.; Dishaw, J.
2007-01-01
Discrete ordinates problems with an infinite exterior medium (reflector) can be more efficiently computed by eliminating grid cells in the exterior medium and applying a matrix albedo boundary condition. The albedo matrix is a discretized bidirectional reflection distribution function (BRDF) that accounts for the angular quadrature set, spatial quadrature method, and spatial grid that would have been used to model a portion of the exterior medium. The method is exact in slab geometry, and could be used as an approximation in multiple dimensions or curvilinear coordinates. We present an adequate method for computing albedo matrices and demonstrate their use in verifying a discrete ordinates code in slab geometry by comparison with Ganapol's infinite medium semi-analytic TIEL benchmark. With sufficient resolution in the spatial and angular grids and iteration tolerance to yield solutions converged to 6 digits, the conventional (scalar) albedo boundary condition yielded 2-digit accuracy at the boundary, but the matrix albedo solution reproduced the benchmark scalar flux at the boundary to all 6 digits. (authors)
Some strong limit theorems for nonhomogeneous Markov chains indexed by controlled trees
Directory of Open Access Journals (Sweden)
Weicai Peng
2016-02-01
Full Text Available Abstract In this paper, a kind of infinite, local finite tree T, named a controlled tree, is introduced. Some strong limit properties, such as the strong law of large numbers and the asymptotic equipartition property, for nonhomogeneous Markov chains indexed by T, are established. The outcomes are the generalizations of some well-known results.
Indian Academy of Sciences (India)
thane, PVC, polyesters, polystyrene and polypropylene. Also, some biocompatible polymers like PLA, poly (E-caprolactone) to mention a few, have been synthesized by varying methods and with different clay loadings (%by weight). The hydrophobicity /hydrophilicity ofthe polymer affects its dispersion in the clay.
Hu, Mingjun; Guo, Qiuquan; Zhang, Tengyuan; Zhou, Shaolin; Yang, Jun
2016-02-01
On account of in situ cross-linked reaction of epoxy SU-8 with poly(4-vinylpyridine) (P4VP) and its strong reactive bonding ability with different pretreated substrates, we developed a simple universal one-step solution-based coating method for fast surface modification of various objects. Through this method, a layer of P4VP molecules with controllable thickness can be tethered tightly onto substrates with the assistance of SU-8. P4VP molecules possess a lot of pyridine ligands to immobilize transitional metal ions that can behave as the catalyst of electroless copper plating for surface metallization while functioning as the adhesion-promoting layer between the substrate and deposited metal. Attributed to interpenetrated entanglement of P4VP molecules and as-deposited metal, ultrathick (>7 μm) strongly adhesive high-quality copper layer can be formed on flexible substrates without any delamination. Then through laser printer to print toner mask, a variety of designed circuits can be easily fabricated on modified flexible PET substrate.
Entangled Polymer Melts in Extensional Flow
DEFF Research Database (Denmark)
Hengeller, Ludovica
. On the other hand, addition of low-volatility solvents to polymers is also a common industrial practice that others a means for lowering the Tg of the polymers. Moreover industrial polymers present a wide distribution of chain lengths and/or branched architectures that strongly influence their response....... Understanding the behaviour of polymer melts and solutions in complex non-linearflows is crucial for the design of polymeric materials and polymer processes. Through rheological characterization, in shear and extensional flow, of model polymer systems,i.e. narrow molar mass distribution polymer melts......Many commercial materials derived from synthetic polymers exhibit a complex response under different processing operations such as fiber formation, injection moulding,film blowing, film casting or coatings. They can be processed both in the solid or in the melted state. Often they may contain two...
Competing irreversible cooperative reactions on polymer chains
International Nuclear Information System (INIS)
Evans, J.W.; Hoffman, D.K.; Burgess, D.R.
1984-01-01
We analyze model processes involving competition between several irreversible reactions at the sites of a 1D, infinite, uniform polymer chain. These reactions can be cooperative, i.e., the corresponding rates depend on the state of the surrounding sites. An infinite hierarchy of rate equations is readily derived for the probabilities of various subconfigurations. By exploiting a shielding property of suitable blocks of unreacted sites, we show how exact hierarchy truncation and solution is sometimes possible. The behavior of solutions is illustrated in several cases by plotting families of ''reaction trajectories'' for varying ratios of reactant concentrations. As a specific application, we consider competition between coordination of ZnCl 2 to pairs of oxygen atoms and to single oxygen atoms in poly(propylene oxide). The observed glass transition temperature behavior is eludicated
3D Printing of Biocompatible Supramolecular Polymers and their Composites.
Hart, Lewis R; Li, Siwei; Sturgess, Craig; Wildman, Ricky; Jones, Julian R; Hayes, Wayne
2016-02-10
A series of polymers capable of self-assembling into infinite networks via supramolecular interactions have been designed, synthesized, and characterized for use in 3D printing applications. The biocompatible polymers and their composites with silica nanoparticles were successfully utilized to deposit both simple cubic structures, as well as a more complex twisted pyramidal feature. The polymers were found to be not toxic to a chondrogenic cell line, according to ISO 10993-5 and 10993-12 standard tests and the cells attached to the supramolecular polymers as demonstrated by confocal microscopy. Silica nanoparticles were then dispersed within the polymer matrix, yielding a composite material which was optimized for inkjet printing. The hybrid material showed promise in preliminary tests to facilitate the 3D deposition of a more complex structure.
Elasticity of semiflexible polymers in two dimensions
Prasad, Ashok; Hori, Yuko; Kondev, Jané
2005-10-01
We study theoretically the entropic elasticity of a semiflexible polymer, such as DNA, confined to two dimensions. Using the worm-like-chain model we obtain an exact analytical expression for the partition function of the polymer pulled at one end with a constant force. The force-extension relation for the polymer is computed in the long chain limit in terms of Mathieu characteristic functions. We also present applications to the interaction between a semiflexible polymer and a nematic field, and derive the nematic order parameter and average extension of the polymer in a strong field.
Energy Dynamics of an Infinitely Large Offshore Wind Farm
DEFF Research Database (Denmark)
Frandsen, Sten Tronæs; Barthelmie, R.J.; Pryor, S.C.
of energy by wind turbines over a large area has a significant and lasting impact on the atmospheric boundary layer. Here we focus on developing understanding of the infinite wind farm through a combination of theoretical considerations, data analysis and modeling. Initial evaluation of power losses due...... the downstream wind climate by consideration of i) the amount of energy extracted in comparison to the kinetic and total energy available within the boundary layer and ii) consideration of the turbulence added by large wind farm developments.......Understanding of the energy dynamics of large offshore wind farms is particularly important given the scale of planned developments in Europe. At the end of 2008, almost 1.5GW of offshore wind farms had been installed, virtually all in Europe. According to the European Wind Energy Association...
On Real and Imaginary Libraries in Relation to the Infinite
Directory of Open Access Journals (Sweden)
Nena Škerlj
2017-12-01
Full Text Available Libraries as institutions, architectures, collections, symbols and metaphors are crucially determined by the concept of infinity. Forms of infinity may occur in real libraries (in architecture, in classification and arrangement of the collections, content of the materials, symbolism, imaginary libraries (which figure in imaginary places, immune to the laws of familiar time, space or perspective, and invisible libraries (which vary from reader to reader and are not referred to in texts, but can be supplied by the readers themselves and used to populate the places and worlds of the stories. The paper shows how real libraries may be infiltrated, through a creative turn of mind and a sharpened sense of the infinite, by visions of imaginary or even invisible libraries, and thus enriched in manifold ways.
Spectral theory of infinite-area hyperbolic surfaces
Borthwick, David
2016-01-01
This text introduces geometric spectral theory in the context of infinite-area Riemann surfaces, providing a comprehensive account of the most recent developments in the field. For the second edition the context has been extended to general surfaces with hyperbolic ends, which provides a natural setting for development of the spectral theory while still keeping technical difficulties to a minimum. All of the material from the first edition is included and updated, and new sections have been added. Topics covered include an introduction to the geometry of hyperbolic surfaces, analysis of the resolvent of the Laplacian, scattering theory, resonances and scattering poles, the Selberg zeta function, the Poisson formula, distribution of resonances, the inverse scattering problem, Patterson-Sullivan theory, and the dynamical approach to the zeta function. The new sections cover the latest developments in the field, including the spectral gap, resonance asymptotics near the critical line, and sharp geometric constan...
Riemann surfaces, Clifford algebras and infinite dimensional groups
International Nuclear Information System (INIS)
Carey, A.L.; Eastwood, M.G.; Hannabuss, K.C.
1990-01-01
We introduce of class of Riemann surfaces which possess a fixed point free involution and line bundles over these surfaces with which we can associate an infinite dimensional Clifford algebra. Acting by automorphisms of this algebra is a 'gauge' group of meromorphic functions on the Riemann surface. There is a natural Fock representation of the Clifford algebra and an associated projective representation of this group of meromorphic functions in close analogy with the construction of the basic representation of Kac-Moody algebras via a Fock representation of the Fermion algebra. In the genus one case we find a form of vertex operator construction which allows us to prove a version of the Boson-Fermion correspondence. These results are motivated by the analysis of soliton solutions of the Landau-Lifshitz equation and are rather distinct from recent developments in quantum field theory on Riemann surfaces. (orig.)
The gravitational field of an infinite flat slab
International Nuclear Information System (INIS)
Fulling, S A; Bouas, J D; Carter, H B
2015-01-01
We study Einstein's equations with a localized plane-symmetric source, with close attention to gauge freedom/fixing and to listing all physically distinct solutions. In the vacuum regions there are only two qualitatively different solutions, one curved and one flat; in addition, on each of the two sides there is a free parameter describing how the slab is embedded into the vacuum region. Surprisingly, for a generic slab source the solution must be curved on one side and flat on the other. We treat infinitely thin slabs in full detail and indicate how thick slabs can increase the variety of external geometry pairs. Positive energy density seems to force external geometries with curvature singularities at some distance from the slab; we speculate that such singularities occur in regions where the solution cannot be physically relevant anyway. (invited comment)
Rainbow Connectivity of Cacti and of Some Infinite Digraphs
Directory of Open Access Journals (Sweden)
Alva-Samos Jesús
2017-05-01
Full Text Available An arc-coloured digraph D = (V,A is said to be rainbow connected if for every pair {u, v} ⊆ V there is a directed uv-path all whose arcs have different colours and a directed vu-path all whose arcs have different colours. The minimum number of colours required to make the digraph D rainbow connected is called the rainbow connection number of D, denoted rc⃗ (D. A cactus is a digraph where each arc belongs to exactly one directed cycle. In this paper we give sharp upper and lower bounds for the rainbow connection number of a cactus and characterize those cacti whose rainbow connection number is equal to any of those bounds. Also, we calculate the rainbow con- nection numbers of some infinite digraphs and graphs, and present, for each n ≥ 6, a tournament of order n and rainbow connection number equal to 2.
New infinite-dimensional hidden symmetries for heterotic string theory
International Nuclear Information System (INIS)
Gao Yajun
2007-01-01
The symmetry structures of two-dimensional heterotic string theory are studied further. A (2d+n)x(2d+n) matrix complex H-potential is constructed and the field equations are extended into a complex matrix formulation. A pair of Hauser-Ernst-type linear systems are established. Based on these linear systems, explicit formulations of new hidden symmetry transformations for the considered theory are given and then these symmetry transformations are verified to constitute infinite-dimensional Lie algebras: the semidirect product of the Kac-Moody o(d,d+n-circumflex) and Virasoro algebras (without center charges). These results demonstrate that the heterotic string theory under consideration possesses more and richer symmetry structures than previously expected
On q-deformed infinite-dimensional n-algebra
Directory of Open Access Journals (Sweden)
Lu Ding
2016-03-01
Full Text Available The q-deformation of the infinite-dimensional n-algebras is investigated. Based on the structure of the q-deformed Virasoro–Witt algebra, we derive a nontrivial q-deformed Virasoro–Witt n-algebra which is nothing but a sh-n-Lie algebra. Furthermore in terms of the pseud-differential operators, we construct the (cosine n-algebra and the q-deformed SDiff(T2 n-algebra. We find that they are the sh-n-Lie algebras for the n even case. In terms of the magnetic translation operators, an explicit physical realization of the (cosine n-algebra is given.
Periodic waves with constant vorticity in water of infinite depth
vanden-Broeck, J.-M.
1996-06-01
Periodic waves propagating at a constant velocity at the surface of a fluid with constant vorticity in water of infinite depth are considered. The problem is solved numerically by a boundary-integral-equation method. Simmen & Saffman (Stud. Appl. Maths 75, 35, 1985) showed that there are families of solutions which have limiting configurations with a 120 degree angle at their crests or a trapped bubble at their troughs. It is shown that there are additional families of solutions. These families have limiting configurations with trapped bubbles at their crests. Each bubble is circular and contains fluid in rigid-body rotation. The results are consistent with previous calculations for solitary waves in water of finite depth.
Surprises in the suddenly-expanded infinite well
International Nuclear Information System (INIS)
Aslangul, Claude
2008-01-01
I study the time evolution of a particle prepared in the ground state of an infinite well after the latter is suddenly expanded. It turns out that the probability density |Ψ(x, t)| 2 shows up quite a surprising behaviour: for definite times, plateaux appear for which |Ψ(x, t)| 2 is constant on finite intervals for x. Elements of theoretical explanation are given by analysing the singular component of the second derivative ∂ xx Ψ(x, t). Analytical closed expressions are obtained for some specific times, which easily allow us to show that, at these times, the density organizes itself into regular patterns provided the size of the box is large enough; more, above some critical size depending on the specific time, the density patterns are independent of the expansion parameter. It is seen how the density at these times simply results from a construction game with definite rules acting on the pieces of the initial density
Anisotropic Heisenberg model for a semi-infinite crystal
International Nuclear Information System (INIS)
Queiroz, C.A.
1985-11-01
A semi-infinite Heisenberg model with exchange interactions between nearest and next-nearest neighbors in a simple cubic lattice. The free surface from the other layers of magnetic ions, by choosing a single ion uniaxial anisotropy in the surface (Ds) different from the anisotropy in the other layers (D). Using the Green function formalism, the behavior of magnetization as a function of the temperature for each layer, as well as the spectrum localized magnons for several values of ratio Ds/D for surface magnetization. Above this critical ratio, a ferromagnetic surface layer is obtained white the other layers are already in the paramagnetic phase. In this situation the critical temperature of surface becomes larger than the critical temperature of the bulk. (Author) [pt
Predictive optimized adaptive PSS in a single machine infinite bus.
Milla, Freddy; Duarte-Mermoud, Manuel A
2016-07-01
Power System Stabilizer (PSS) devices are responsible for providing a damping torque component to generators for reducing fluctuations in the system caused by small perturbations. A Predictive Optimized Adaptive PSS (POA-PSS) to improve the oscillations in a Single Machine Infinite Bus (SMIB) power system is discussed in this paper. POA-PSS provides the optimal design parameters for the classic PSS using an optimization predictive algorithm, which adapts to changes in the inputs of the system. This approach is part of small signal stability analysis, which uses equations in an incremental form around an operating point. Simulation studies on the SMIB power system illustrate that the proposed POA-PSS approach has better performance than the classical PSS. In addition, the effort in the control action of the POA-PSS is much less than that of other approaches considered for comparison. Copyright © 2016 ISA. Published by Elsevier Ltd. All rights reserved.
Guiding spoof surface plasmon polaritons by infinitely thin grooved metal strip
Directory of Open Access Journals (Sweden)
Xiang Wan
2014-04-01
Full Text Available In this paper, the propagation characteristics of spoof surface plasmon polaritons (SPPs on infinitely thin corrugated metal strips are theoretically analyzed. Compared with the situations of infinitely thick lateral thickness, the infinitely thin lateral thickness leads to lower plasma frequency according to the analyses. The propagation lengths and the binding capacity of the spoof SPPs are evaluated based on the derived dispersion equation. The effects of different lateral thicknesses are also investigated. At the end, a surface wave splitter is presented using infinitely thin corrugated metal strip. Other functional planar or flexible devices can also be designed using these metal strips in microwave or terahertz regimes.
Sequence Programmable Peptoid Polymers for Diverse Materials Applications.
Knight, Abigail S; Zhou, Effie Y; Francis, Matthew B; Zuckermann, Ronald N
2015-10-14
Polymer sequence programmability is required for the diverse structures and complex properties that are achieved by native biological polymers, but efforts towards controlling the sequence of synthetic polymers are, by comparison, still in their infancy. Traditional polymers provide robust and chemically diverse materials, but synthetic control over their monomer sequences is limited. The modular and step-wise synthesis of peptoid polymers, on the other hand, allows for precise control over the monomer sequences, affording opportunities for these chains to fold into well-defined nanostructures. Hundreds of different side chains have been incorporated into peptoid polymers using efficient reaction chemistry, allowing for a seemingly infinite variety of possible synthetically accessible polymer sequences. Combinatorial discovery techniques have allowed the identification of functional polymers within large libraries of peptoids, and newly developed theoretical modeling tools specifically adapted for peptoids enable the future design of polymers with desired functions. Work towards controlling the three-dimensional structure of peptoids, from the conformation of the amide bond to the formation of protein-like tertiary structure, has and will continue to enable the construction of tunable and innovative nanomaterials that bridge the gap between natural and synthetic polymers. © 2015 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.
Review of the theory of infinite nuclear matter
International Nuclear Information System (INIS)
Llano, M. de; Tolmachev, V.V.
1975-01-01
Given a two-body force, there seems to be two distinct starting points in the many-body perturbation-theoretic problem of computing the energy per nucleon of infinite (as well as finite) nuclear matter: ordinary Hartree-Fock theory and the Brueckner theory. The former theory, treated almost exclusively with plane-wave solutions, has long-ago fallen into disuse, to yield to the latter, apparently more sophisticated, theory. After a brief outline of many-fermion diagramatic techniques, the Brueckner-Bethe-Goldstone series expansion in terms of the density is discussed as a low density, non-ideal Fermi gas theory, whose convergence is analyzed. A calculation based on particle-hole Green's function techniques shows that a nucleon gas condenses to the liquid phase at about 3% of the empirical nuclear matter saturation density. The analogy between the BBG expansion and the virial expansion for a classical or quantum gas is studied with special emphasis on the apparent impossibility of analytical-continuing the latter gas theory to densities in the liquid regime, as first elucidated by Lee and Yang. It is finally argued that ordinary HF theory may provide a good starting point for the eventual understanding of nuclear matter as it gives (in the finite nuclear problem, at any rate) not only the basic liquid properties of a definite density and a surface but also provides independent-particle aspects, avoiding at the same time the idea of n-body clusters appropriate only for dilute gases. This program has to date not been carried out for infinite nuclear matter, mainly because of insufficient knowledge regarding low-energy, non-plane-wave solutions of the HF equations, in the thermodynamic limit [pt
Influence of polymer architectures on diffusion in unentangled polymer melts.
Chremos, Alexandros; Jeong, Cheol; Douglas, Jack F
2017-08-30
Recent simulations have indicated that the thermodynamic properties and the glassy dynamics of polymer melts are strongly influenced by the average molecular shape, as quantified by the radius of gyration tensor of the polymer molecules, and that the average molecular shape can be tuned by varying the molecular topology (e.g., ring, star, linear chain, etc.). In the present work, we investigate if the molecular shape is similarly a predominant factor in understanding the polymer center of mass diffusion D in the melt, as already established for polymer solutions. We find that all our D data for unentangled polymer melts having a range of topologies can be reasonably described as a power law of the polymer hydrodynamic radius, R h . In particular, this scaling is similar to the scaling of D for a tracer sphere having a radius on the order of the chain radius of gyration, R g . We conclude that the chain topology influences the molecular dynamics in as much as the polymer topology influences the average molecular shape. Experimental evidence seems to suggest that this situation is also true for entangled polymer melts.
Energy Technology Data Exchange (ETDEWEB)
Buchenau, U. [Forschungszentrum Juelich GmbH (Germany). Inst. fuer Energieverfahrenstechnik
1996-11-01
Neutron scattering from amorphous polymers allows to switch from incoherent to coherent scattering in the same substance. The power of the tool for the study of the picosecond dynamics of disordered matter is illustrated for polybutadiene, polycarbonate and polystyrene. The results suggest a mixture of sound waves and localized modes, strongly interacting with each other, in the picosecond range. (author) 8 figs., tabs., 39 refs.
International Nuclear Information System (INIS)
Buchenau, U.
1996-01-01
Neutron scattering from amorphous polymers allows to switch from incoherent to coherent scattering in the same substance. The power of the tool for the study of the picosecond dynamics of disordered matter is illustrated for polybutadiene, polycarbonate and polystyrene. The results suggest a mixture of sound waves and localized modes, strongly interacting with each other, in the picosecond range. (author) 8 figs., tabs., 39 refs
Simulations of Polymer Translocation
Vocks, H.
2008-07-01
Transport of molecules across membranes is an essential mechanism for life processes. These molecules are often long, and the pores in the membranes are too narrow for the molecules to pass through as a single unit. In such circumstances, the molecules have to squeeze -- i.e., translocate -- themselves through the pores. DNA, RNA and proteins are such naturally occuring long molecules in a variety of biological processes. Understandably, the process of translocation has been an active topic of current research: not only because it is a cornerstone of many biological processes, but also due to its relevance for practical applications. Translocation is a complicated process in living organisms -- the presence of chaperone molecules, pH, chemical potential gradients, and assisting molecular motors strongly influence its dynamics. Consequently, the translocation process has been empirically studied in great variety in biological literature. Study of translocation as a biophysical process is more recent. Herein, the polymer is simplified to a sequentially connected string of N monomers as it passes through a narrow pore on a membrane. The quantities of interest are the typical time scale for the polymer to leave a confining cell (the ``escape of a polymer from a vesicle'' time scale), and the typical time scale the polymer spends in the pore (the ``dwell'' time scale) as a function of N and other parameters like membrane thickness, membrane adsorption, electrochemical potential gradient, etc. Our research is focused on computer simulations of translocation. Since our main interest is in the scaling properties, we use a highly simplified description of the translocation process. The polymer is described as a self-avoiding walk on a lattice, and its dynamics consists of single-monomer jumps from one lattice site to another neighboring one. Since we have a very efficient program to simulate such polymer dynamics, which we decribe in Chapter 2, we can perform long
Carraher, Charles E., Jr.
1981-01-01
Reactions utilized to incorporate a metal-containing moiety into a polymer chain (addition, condensation, and coordination) are considered, emphasizing that these reactions also apply to smaller molecules. (JN)
Gertz, Susan
Background information on natural polymers, synthetic polymers, and the properties of polymers is presented as an introduction to this curriculum guide. Details are provided on the use of polymer products in consumer goods, polymer recycling, polymer densities, the making of a polymer such as GLUEP, polyvinyl alcohol, dissolving plastics, polymers…
Testing strong interaction theories
International Nuclear Information System (INIS)
Ellis, J.
1979-01-01
The author discusses possible tests of the current theories of the strong interaction, in particular, quantum chromodynamics. High energy e + e - interactions should provide an excellent means of studying the strong force. (W.D.L.)
International Nuclear Information System (INIS)
Hamieh, Tayssir; Schultz, Jacques
2002-01-01
Full text.The thermal behavior of thermoplastic polymers is unique and responsible for much of their attractiveness as industrially process able materials. In general, amorphous polymers change from hard, brittle, glassy materials at low temperatures to soft, deformable, rubbery materials at high temperatures. This is known as the glass transition and occurs over a relatively narrow range of temperatures characterized by the glass transition temperature. In the study of polymers and their applications, it is important to understand the concept of transition phenomena and especially, the glass transition temperature T g . As the temperature of o polymer drops below T g , it behaves in an increasingly brittle manner. As the temperature rises above the T g , the polymer becomes more rubber-like. Thus, knowledge of T g is essential in the selection of materials for various applications. In general, values of T g well below room temperature define the domain of elastomers and values above temperature define rigid, structural polymers. It is well-known that the polymer properties strongly depend temperature. Polymers can be easily affected by abrupt variations of the temperature. In fact, such modifications would induce modifications in the chain segment mobility of polymers. These changes in mobility arising at the glass transition temperatures of bulk polymers can be determined by using thermal methods, like differential thermal analysis or differential scanning calorimetry. Polymers typically display broad melting endotherms and glass transitions as major analytic features associated with their properties. Both the glass and melting transitions are strongly dependent on processing conditions and dispersion in structural and chemical properties of plastics. Characterization of polymers requires a detailed analysis of these characteristic thermal transitions using either differential scanning calorimeter (DSC) or differential thermal analysis (DTA). Temperature scans
Characterizing the Polymer:Fullerene Intermolecular Interactions
Sweetnam, Sean
2016-02-02
Polymer:fullerene solar cells depend heavily on the electronic coupling of the polymer and fullerene molecular species from which they are composed. The intermolecular interaction between the polymer and fullerene tends to be strong in efficient photovoltaic systems, as evidenced by efficient charge transfer processes and by large changes in the energetics of the polymer and fullerene when they are molecularly mixed. Despite the clear presence of these strong intermolecular interactions between the polymer and fullerene, there is not a consensus on the nature of these interactions. In this work, we use a combination of Raman spectroscopy, charge transfer state absorption, and density functional theory calculations to show that the intermolecular interactions do not appear to be caused by ground state charge transfer between the polymer and fullerene. We conclude that these intermolecular interactions are primarily van der Waals in nature. © 2016 American Chemical Society.
Strong curvature effects in Neumann wave problems
DEFF Research Database (Denmark)
Willatzen, Morten; Pors, A.; Gravesen, Jens
2012-01-01
Waveguide phenomena play a major role in basic sciences and engineering. The Helmholtz equation is the governing equation for the electric field in electromagnetic wave propagation and the acoustic pressure in the study of pressure dynamics. The Schro¨dinger equation simplifies to the Helmholtz...... equation for a quantum-mechanical particle confined by infinite barriers relevant in semiconductor physics. With this in mind and the interest to tailor waveguides towards a desired spectrum and modal pattern structure in classical structures and nanostructures, it becomes increasingly important...... to understand the influence of curvature effects in waveguides. In this work, we demonstrate analytically strong curvature effects for the eigenvalue spectrum of the Helmholtz equation with Neumann boundary conditions in cases where the waveguide cross section is a circular sector. It is found that the linear...
Statistical mechanics of polymer networks of any topology
International Nuclear Information System (INIS)
Duplantier, B.
1989-01-01
The statistical mechanics is considered of any polymer network with a prescribed topology, in dimension d, which was introduced previously. The basic direct renormalization theory of the associated continuum model is established. It has a very simple multiplicative structure in terms of the partition functions of the star polymers constituting the vertices of the network. A calculation is made to O(ε 2 ), where d = 4 -ε, of the basic critical dimensions σ L associated with any L=leg vertex (L ≥ 1). From this infinite series of critical exponents, any topology-dependent critical exponent can be derived. This is applied to the configuration exponent γ G of any network G to O(ε 2 ), including L-leg star polymers. The infinite sets of contact critical exponents θ between multiple points of polymers or between the cores of several star polymers are also deduced. As a particular case, the three exponents θ 0 , θ 1 , θ 2 calculated by des Cloizeaux by field-theoretic methods are recovered. The limiting exact logarithmic laws are derived at the upper critical dimension d = 4. The results are generalized to the series of topological exponents of polymer networks near a surface and of tricritical polymers at the Θ-point. Intersection properties of networks of random walks can be studied similarly. The above factorization theory of the partition function of any polymer network over its constituting L-vertices also applies to two dimensions, where it can be related to conformal invariance. The basic critical exponents σ L and thus any topological polymer exponents are then exactly known. Principal results published elsewhere are recalled
On the Structure of a Triangle-Free Infinite-Chromatic Graph of Gyarfas
Directory of Open Access Journals (Sweden)
Larry Eggan
1983-01-01
Full Text Available Gyárfás has recently constructed an elegant new example of a triangle-free infinite graph G with infinite chromatic number. We analyze its structure by studying the properties of a nested family of subgraphs Gn whose union is G.
Sheared semi-infinite crack originating at the boundary of a circular ...
African Journals Online (AJOL)
The configuration studied is that of a non-homogeneous infinite solid containing a central hole and a semi-infinite crack, originating from one side of the hole. Longitudinal shear loads of magnitude Tj, j = 1, 2 are applied on parts of the crack surface. It is found that the dominant fracture characteristic is that of a hole or semi ...
A Central Limit Theorem for Markov-Modulated Infinite-Server Queues
J.G. Blom (Joke); K.E.E.S deTurck; M.R.H. Mandjes (Michel); A. Dudin; K.E.E.S deTurck
2013-01-01
textabstractThis paper studies an infinite-server queue in a Markov environment, that is, an infinite-server queue with arrival rates and service times depending on the state of a Markovian background process. Scaling the arrival rates $\\lambda_i$ by a factor $N$ and the rate $q_{ij}$ of the
Central Limit Theorems for Markov-modulated infinite-server queues
J.G. Blom (Joke); K.E.E.S deTurck; M.R.H. Mandjes (Michel)
2013-01-01
textabstractThis paper studies an infinite-server queue in a Markov environment, that is, an infinite-server queue with arrival rates and service times depending on the state of an independently evolving Markovian background process. Scaling the arrival rates $\\lambda_i$ by a factor $N$ and the
Partition of a Set Which Contains an Infinite Arithmetic (Respectively Geometric) Progression
Smarandache, Florentin
2009-01-01
We prove that for any partition of a set which contains an infinite arithmetic (respectively geometric) progression into two disjoint subsets, at least one of these subsets contains an infinite number of triplets such that each triplet is an arithmetic (respectively geometric) progression.
Infinitely Many Solutions for a Boundary Value Problem with Discontinuous Nonlinearities
Directory of Open Access Journals (Sweden)
2009-03-01
Full Text Available The existence of infinitely many solutions for a Sturm-Liouville boundary value problem, under an appropriate oscillating behavior of the possibly discontinuous nonlinear term, is obtained. Several special cases and consequences are pointed out and some examples are presented. The technical approach is mainly based on a result of infinitely many critical points for locally Lipschitz functions.
Certain approximation problems for functions on the infinite-dimensional torus: Lipschitz spaces
Platonov, S. S.
2018-02-01
We consider some questions about the approximation of functions on the infinite-dimensional torus by trigonometric polynomials. Our main results are analogues of the direct and inverse theorems in the classical theory of approximation of periodic functions and a description of the Lipschitz spaces on the infinite-dimensional torus in terms of the best approximation.
DEFF Research Database (Denmark)
2005-01-01
The aim of the workshop is, to provide a forum for researchers interested in the development of mathematical techniques for the analysis and verification of systems with infinitely many states. Topics: Techniques for modeling and analysis of infinite-state systems; Equivalence-checking and model-...
DEFF Research Database (Denmark)
Glückstad, Fumiko Kano; Herlau, Tue; Schmidt, Mikkel Nørgaard
2013-01-01
This work presents a conceptual framework for learning an ontological structure of domain knowledge, which combines Jaccard similarity coefficient with the Infinite Relational Model (IRM) by (Kemp et al. 2006) and its extended model, i.e. the normal-Infinite Relational Model (n-IRM) by (Herlau et...
International Nuclear Information System (INIS)
Agarwal, Ravi P.; Baghli, Selma; Benchohra, Mouffak
2009-01-01
The controllability of mild solutions defined on the semi-infinite positive real interval for two classes of first order semilinear functional and neutral functional differential evolution equations with infinite delay is studied in this paper. Our results are obtained using a recent nonlinear alternative due to Avramescu for sum of compact and contraction operators in Frechet spaces, combined with the semigroup theory
Criterion for the nuclearity of spaces of functions of infinite number of variables
International Nuclear Information System (INIS)
Gali, I.M.
1977-08-01
The paper formulates a new necessary and sufficient condition for the nuclearity of spaces of infinite number of variables, and defines new nuclear spaces which play an important role in the field of functional analysis and quantum field theory. Also the condition for nuclearity of the infinite weighted tensor product of nuclear spaces is given
Some Notes on Linguistic Theory and Language Development: The Case of Root Infinitives.
Rizzi, Luigi
1994-01-01
Argues that root infinitives produced by Italian toddlers learning a second language are truncated structures, arising from the option of "stripping off" external clausal layers. The basic properties of the construction are shown to be amenable to the Truncation Hypothesis, in that root infinitives are incompatible with /wh/ elements,…
Quantum field theory with infinite component local fields as an alternative to the string theories
International Nuclear Information System (INIS)
Krasnikov, N.V.
1987-05-01
We show that the introduction of the infinite component local fields with higher order derivatives in the interaction makes the theory completely ultraviolet finite. For the γ 5 -anomalous theories the introduction of the infinite component field makes the theory renormalizable or superrenormalizable. (orig.)
Xie, Liangxu; Chan, Kwong-Yu; Quirke, Nick
2017-10-24
Canonical molecular dynamics simulations are performed to investigate the behavior of single-chain and multiple-chain poly(ethylene glycol) (PEG) contained within a cubic framework spanned by polyethylene (PE) chains. This simple model is the first of its kind to study the chemical physics of polymer-threaded organic frameworks, which are materials with potential applications in catalysis and separation processes. For a single-chain 9-mer, 14-mer, and 18-mer in a small framework, the PEG will interact strongly with the framework and assume a more linear geometry chain with an increased radius of gyration R g compared to that of a large framework. The interaction between PEG and the framework decreases with increasing mesh size in both vacuum and water. In the limit of a framework with an infinitely large cavity (infinitely long linkers), PEG behavior approaches simulation results without a framework. The solvation of PEG is simulated by adding explicit TIP3P water molecules to a 6-chain PEG 14-mer aggregate confined in a framework. The 14-mer chains are readily solvated and leach out of a large 2.6 nm mesh framework. There are fewer water-PEG interactions in a small 1.0 nm mesh framework, as indicated by a smaller number of hydrogen bonds. The PEG aggregate, however, still partially dissolves but is retained within the 1.0 nm framework. The preliminary results illustrate the effectiveness of the simple model in studying polymer-threaded framework materials and in optimizing polymer or framework parameters for high performance.
The extended reciprocity: Strong belief outperforms persistence.
Kurokawa, Shun
2017-05-21
The existence of cooperation is a mysterious phenomenon and demands explanation, and direct reciprocity is one key potential explanation for the evolution of cooperation. Direct reciprocity allows cooperation to evolve for cooperators who switch their behavior on the basis of information about the opponent's behavior. Here, relevant to direct reciprocity is information deficiency. When the opponent's last move is unknown, how should players behave? One possibility is to choose cooperation with some default probability without using any further information. In fact, our previous paper (Kurokawa, 2016a) examined this strategy. However, there might be beneficial information other than the opponent's last move. A subsequent study of ours (Kurokawa, 2017) examined the strategy which uses the own last move when the opponent's last move is unknown, and revealed that referring to the own move and trying to imitate it when information is absent is beneficial. Is there any other beneficial information else? How about strong belief (i.e., have infinite memory and believe that the opponent's behavior is unchanged)? Here, we examine the evolution of strategies with strong belief. Analyzing the repeated prisoner's dilemma game and using evolutionarily stable strategy (ESS) analysis against an invasion by unconditional defectors, we find the strategy with strong belief is more likely to evolve than the strategy which does not use information other than the opponent player's last move and more likely to evolve than the strategy which uses not only the opponent player's last move but also the own last move. Strong belief produces the extended reciprocity and facilitates the evolution of cooperation. Additionally, we consider the two strategies game between strategies with strong belief and any strategy, and we consider the four strategies game in which unconditional cooperators, unconditional defectors, pessimistic reciprocators with strong belief, and optimistic reciprocators with
Příklonky a vazaly infinitivu : Clitics and Infinitive Vassals
Directory of Open Access Journals (Sweden)
Ilona Starý Kořánová
2017-12-01
Full Text Available Word order of Czech enclitics is quite difficult to acquire for students of Czech as foreign language. While native speakers can “hear” the correct word order, the foreigner needs a set of rules to guide him. The usual rule for the word order of fixed enclitics seems to be breached quite often. The article focuses on one type of sentences in which the rule for the word order of fixed enclitics is violated, namely in sentences which except for a finite verb include an infinitive and consequently two series of enclitics. The finite verb and the infinitive each syntactically govern (are governor to their respective enclitics which in turn are their subjects (recta. If the infinitive is part of the sentence predicate, the enclitics follow the usual rule of word order unless the infinitive becomes part of the sentence rhema (comments. In that case its subjects precede it. If the infinitive is not part of the sentence predicate (in other words it is subject, object or complement, precedes it then the infinitive subjects follow it. However, if the infinitive is not part of the sentence predicate, and is placed at the sentence end, then its subjects precede it. If the infinitive functions as an attribute to a noun, it follows the noun. If the nominal phrase N + infinitive starts a sentence then the reflexive particle se/si follows the infinitive in 98% of cases. If the enclitic personal pronouns occur in the reversed order, i.e. Acc.–Dat. order, or two dative enclitics follow one immediately after another then the enclitics subjects are as close as possible to their regens/ governor. The so-called contact dative, which does not have a governor, is not bound in this way
A simple extrapolation of thermodynamic perturbation theory to infinite order.
Ghobadi, Ahmadreza F; Elliott, J Richard
2015-09-21
Recent analyses of the third and fourth order perturbation contributions to the equations of state for square well spheres and Lennard-Jones chains show trends that persist across orders and molecular models. In particular, the ratio between orders (e.g., A3/A2, where A(i) is the ith order perturbation contribution) exhibits a peak when plotted with respect to density. The trend resembles a Gaussian curve with the peak near the critical density. This observation can form the basis for a simple recursion and extrapolation from the highest available order to infinite order. The resulting extrapolation is analytic and therefore cannot fully characterize the critical region, but it remarkably improves accuracy, especially for the binodal curve. Whereas a second order theory is typically accurate for the binodal at temperatures within 90% of the critical temperature, the extrapolated result is accurate to within 99% of the critical temperature. In addition to square well spheres and Lennard-Jones chains, we demonstrate how the method can be applied semi-empirically to the Perturbed Chain - Statistical Associating Fluid Theory (PC-SAFT).
Infinitely Many Eigenfunctions for Polynomial Problems: Exact Results
Directory of Open Access Journals (Sweden)
Yi-Chou Chen
2015-01-01
Full Text Available Let Fx, y=asxys+as-1xys-1+⋯+a0x be a real-valued polynomial function in which the degree s of y in Fx, y is greater than or equal to 1. For any polynomial yx, we assume that T:Rx→Rx is a nonlinear operator with Tyx=Fx, yx. In this paper, we will find an eigenfunction yx∈Rx to satisfy the following equation: Fx, yx=ayx for some eigenvalue a∈R and we call the problem Fx, yx=ayx a fixed point like problem. If the number of all eigenfunctions in Fx, yx=ayx is infinitely many, we prove that (i any coefficients of Fx, y, asx, as-1x,…, a0x, are all constants in R and (ii yx is an eigenfunction in Fx, yx=ayx if and only if yx∈R.
Infinite cascades of phase transitions in the classical Ising chain
Timonin, P. N.; Chitov, Gennady Y.
2017-12-01
We report exact results on one of the best studied models in statistical physics: the classical antiferromagnetic Ising chain in a magnetic field. We show that the model possesses an infinite cascade of thermal phase transitions (also known as disorder lines or geometric phase transitions). The phase transition is signaled by a change of asymptotic behavior of the nonlocal string-string correlation functions when their monotonic decay becomes modulated by incommensurate oscillations. The transitions occur for rarefied (m -periodic) strings with arbitrary odd m . We propose a duality transformation which maps the Ising chain onto the m -leg Ising tube with nearest-neighbor couplings along the legs and the plaquette four-spin interactions of adjacent legs. Then the m -string correlation functions of the Ising chain are mapped onto the two-point spin-spin correlation functions along the legs of the m -leg tube. We trace the origin of these cascades of phase transitions to the lines of the Lee-Yang zeros of the Ising chain in m -periodic complex magnetic field, allowing us to relate these zeros to the observable (and potentially measurable) quantities.
The Concept of Free Will as an Infinite Metatheoretic Recursion
Directory of Open Access Journals (Sweden)
Hashim Hanaan
2015-07-01
Full Text Available It is argued that the concept of free will, like the concept of truth in formal languages, requires a separation between an object level and a meta-level for being consistently defined. The Jamesian two stage model, which deconstructs free will into the causally open “free” stage with its closure in the “will” stage, is implicitly a move in this direction. However, to avoid the dilemma of determinism, free will additionally requires an infinite regress of causal meta-stages, making free choice a hypertask. We use this model to define free will of the rationalist-compatibilist type. This is shown to provide a natural three-way distinction between quantum indeterminism, freedom and free will, applicable respectively to artificial intelligence (AI, animal agents and human agents. We propose that the causal hierarchy in our model corresponds to a hierarchy of Turing uncomputability. Possible neurobiological and behavioral tests to demonstrate free will experimentally are suggested. Ramifications of the model for physics, evolutionary biology, neuroscience, neuropathological medicine and moral philosophy are briefly outlined.
Spectral Methods Using Rational Basis Functions on an Infinite Interval
Boyd, John P.
1987-03-01
By using the map y = L cot( t) where L is a constant, differential equations on the interval yɛ [- ∞, ∞] can be transformed into tɛ [0, π] and solved by an ordinary Fourier series. In this article, earlier work by Grosch and Orszag ( J. Comput. Phys.25, 273 (1977)), Cain, Ferziger, and Reynolds ( J. Comput. Phys.56, 272 (1984)), and Boyd ( J. Comput. Phys.25, 43 (1982); 57, 454 (1985); SIAM J. Numer. Anal. (1987)) is extended in several ways. First, the series of orthogonal rational functions converge on the exterior of bipolar coordinate surfaces in the complex y-plane. Second, Galerkin's method will convert differential equations with polynomial or rational coefficients into banded matrix problems. Third, with orthogonal rational functions it is possible to obtain exponential convergence even for u( y) that asymptote to a constant although this behavior would wreck alternatives such as Hermite or sinc expansions. Fourth, boundary conditions are usually "natural" rather than "essential" in the sense that the singularities of the differential equation will force the numerical solution to have the correct behavior at infinity even if no constraints are imposed on the basis functions. Fifth, mapping a finite interval to an infinite one and then applying the rational Chebyshev functions gives an exponentially convergent method for functions with bounded endpoint singularities. These concepts are illustrated by five numerical examples.
English romantic movement: The vision of infinite or social engagement?
Directory of Open Access Journals (Sweden)
Mušović Azra
2009-01-01
Full Text Available English Romanticism can be seen as a creative period in which, owing to the radical changes taking place in the historical and social spheres, the cultural view of the world had to be reconstructured or totally readjusted. The attitudes of many Romantic writers were responses to the French and the Industrial Revolution. English Romanticism is best represented by poetry, which was more suitable to the expression of emotional experiences, individual feeling and imagination. Partly, Romanticism was the desire to express the 'inexpressible' - the infinite - through the powerful resources of language. The great English Romantics also experienced political disillusionment, which resulted in the clash between the ideal and reality in their poetry. Poetry thus became a medium to challenge the cosmos, nature, political and social order, or to escape from all this. Individualism, the alienation of the artist from society and escapism found expression in the different attitudes: the anti-conformist, rebellious and cynical attitude of 'Byronic Hero', the revolutionary spirit of Shelley's Prometheus and Keats's escape into the world of the past and beauty. It is clear that Romanticism transformed Western culture in many ways that survive into our own times.
A Nekhoroshev theorem for some infinite-dimensional systems
Perfetti, P
2005-01-01
We study the persistence for long times of the solutions of some infinite--dimensional discrete hamiltonian systems with {\\it formal hamiltonian} $\\sum_{i=1}^\\infty h(A_i) + V(\\vp),$ $(A,\\vp)\\in {\\Bbb R}^{\\Bbb N}\\times {\\Bbb T}^{\\Bbb N}.$ $V(\\vp)$ is not needed small and the problem is perturbative being the kinetic energy unbounded. All the initial data $(A_i(0), \\vp_i(0)),$ $i\\in {\\Bbb N}$ in the phase--space ${\\Bbb R}^{\\Bbb N} \\times {\\Bbb T}^{\\Bbb N},$ give rise to solutions with $\\mod A_i(t) - A_i(0).$ close to zero for exponentially--long times provided that $A_i(0)$ is large enough for $\\mod i.$ large. We need $\\o \\partial h,\\partial A_i,{\\scriptstyle (A_i(0))}$ unbounded for $i\\to+\\infty$ making $\\vp_i$ a {\\it fast variable}; the greater is $i,$ the faster is the angle $\\vp_i$ (avoiding the resonances). The estimates are obtained in the spirit of the averaging theory reminding the analytic part of Nekhoroshev--theorem.
Regularized semiclassical limits: Linear flows with infinite Lyapunov exponents
Athanassoulis, Agissilaos
2016-08-30
Semiclassical asymptotics for Schrödinger equations with non-smooth potentials give rise to ill-posed formal semiclassical limits. These problems have attracted a lot of attention in the last few years, as a proxy for the treatment of eigenvalue crossings, i.e. general systems. It has recently been shown that the semiclassical limit for conical singularities is in fact well-posed, as long as the Wigner measure (WM) stays away from singular saddle points. In this work we develop a family of refined semiclassical estimates, and use them to derive regularized transport equations for saddle points with infinite Lyapunov exponents, extending the aforementioned recent results. In the process we answer a related question posed by P.L. Lions and T. Paul in 1993. If we consider more singular potentials, our rigorous estimates break down. To investigate whether conical saddle points, such as -|x|, admit a regularized transport asymptotic approximation, we employ a numerical solver based on posteriori error control. Thus rigorous upper bounds for the asymptotic error in concrete problems are generated. In particular, specific phenomena which render invalid any regularized transport for -|x| are identified and quantified. In that sense our rigorous results are sharp. Finally, we use our findings to formulate a precise conjecture for the condition under which conical saddle points admit a regularized transport solution for the WM. © 2016 International Press.
Energy Technology Data Exchange (ETDEWEB)
McDonald, William F. (Utica, OH); Huang, Zhi-Heng (Walnut Creek, CA); Wright, Stacy C. (Columbus, GA)
2005-09-06
A polymeric composition having antimicrobial properties and a process for rendering the surface of a substrate antimicrobial are disclosed. The composition comprises a crosslinked chemical combination of (i) a polymer having amino group-containing side chains along a backbone forming the polymer, (ii) an antimicrobial agent selected from quaternary ammonium compounds, gentian violet compounds, substituted or unsubstituted phenols, biguanide compounds, iodine compounds, and mixtures thereof, and (iii) a crosslinking agent containing functional groups capable of reacting with the amino groups. In one embodiment, the polymer is a polyamide formed from a maleic anhydride or maleic acid ester monomer and alkylamines thereby producing a polyamide having amino substituted alkyl chains on one side of the polyamide backbone; the crosslinking agent is a phosphine having the general formula (A)3P wherein A is hydroxyalkyl; and the antimicrobial agent is chlorhexidine, dimethylchlorophenol, cetyl pyridinium chloride, gentian violet, triclosan, thymol, iodine, and mixtures thereof.
Geoghegan, Mark
2013-01-01
Polymer electronics is the science behind many important new developments in technology, such as the flexible electronic display (e-ink) and many new developments in transistor technology. Solar cells, light-emitting diodes, and transistors are all areas where plastic electronics is likely to, or is already having, a serious impact on our daily lives. With polymer transistors and light-emitting diodes now being commercialised, there is a clear need for a pedagogic text thatdiscusses the subject in a clear and concise fashion suitable for senior undergraduate and graduate students. The content
Monitoring of polymer melt processing
International Nuclear Information System (INIS)
Alig, Ingo; Steinhoff, Bernd; Lellinger, Dirk
2010-01-01
The paper reviews the state-of-the-art of in-line and on-line monitoring during polymer melt processing by compounding, extrusion and injection moulding. Different spectroscopic and scattering techniques as well as conductivity and viscosity measurements are reviewed and compared concerning their potential for different process applications. In addition to information on chemical composition and state of the process, the in situ detection of morphology, which is of specific interest for multiphase polymer systems such as polymer composites and polymer blends, is described in detail. For these systems, the product properties strongly depend on the phase or filler morphology created during processing. Examples for optical (UV/vis, NIR) and ultrasonic attenuation spectra recorded during extrusion are given, which were found to be sensitive to the chemical composition as well as to size and degree of dispersion of micro or nanofillers in the polymer matrix. By small-angle light scattering experiments, process-induced structures were detected in blends of incompatible polymers during compounding. Using conductivity measurements during extrusion, the influence of processing conditions on the electrical conductivity of polymer melts with conductive fillers (carbon black or carbon nanotubes) was monitored. (topical review)
International Nuclear Information System (INIS)
Wen Lili; Li Yizhi; Dang Dongbin; Tian Zhengfang; Ni Zhaoping; Meng Qingjin
2005-01-01
Two novel interesting d 1 metal coordination polymers, [Zn(H 2 bibzim)(BDC)] n (1) and [Cd(H 2 bibzim)(BDC)] n (2) [H 2 bibzim=2,2'-bibenzimidazole, BDC=1,4-benzenedicarboxylate] have been synthesized under solvothermal conditions and structurally characterized. Both 1 and 2 are constructed from infinite neutral zigzag-like one-dimensional (1D) chains. The π-π interactions and interchain hydrogen-bonding interactions further extend the 1D arrangement to generate a 3D supramolecular architecture for 1 and 2. Both complexes have high thermal stability and display strong blue fluorescent emissions in the solid state upon photo-excitation at 365 nm at room temperature. They are the first two examples that 2,2'-bibenzimidazole has been introduced into the d 1 coordination polymeric framework
Ultra strong polymer fibers : Ab initio calculations on polyethylene
Hageman, J.C.L.; Groot, R.A. de; Meier, Robert J.
1998-01-01
The Car-Parrinello technique is used to study the electronic structure of orthorhombic polyethylene as well as the elastic modulus. The theoretical band structure and density of states are in very good agreement with experiments. The best experimentally realized elastic modulus is better than 86% of
Indian Academy of Sciences (India)
backbone (by the process of doping) and make them electrically. Conducting Polymers. From a Laboratory Curiosity to the Market Place. S Ramakrishnan ..... switching occurs between transparent yellow and green in less than. 100ms. Thus, while these materials are yet to achieve the set target. (in terms of their life cycle) ...
Indian Academy of Sciences (India)
ized the plastics industry by providing a route to polypropylene. (Zeigler and Natta jointly won the. Nobel Prize in Chemistry in 1963 for their discovery.) ... transport of charge in these systems can be understood in a simple fashion, by causing the imine and amine nitrogens to exchange places along the polymer backbone (in ...
Indian Academy of Sciences (India)
the plastics industry by providing a route to polypropylene. (Zeigler and Natta jointly won the Nobel Prize in chemistry in 1963 for their discovery.) ... these systems can be understood in a simple fashion, by causing the imine and amine nitrogens to exchange places along the polymer backbone (in protonated emeraldinel.
Indian Academy of Sciences (India)
Home; Journals; Resonance – Journal of Science Education; Volume 16; Issue 12. Conducting Polymers - From a Laboratory Curiosity to the Market Place. S Ramakrishnan. Volume 16 Issue 12 December 2011 pp 1254-1265. Fulltext. Click here to view fulltext PDF. Permanent link:
Krawczyk, Gerhard Erich [Bremen, DE; Miller, Kevin Michael [West Dundee, IL
2011-07-26
There is provided a method of making a polymer solution comprising polymerizing one or more monomer in a solvent, wherein said monomer comprises one or more ethylenically unsaturated monomer that is a multi-functional Michael donor, and wherein said solvent comprises 40% or more by weight, based on the weight of said solvent, one or more multi-functional Michael donor.
Gedde, Ulf W
1999-01-01
This book is the result of my teaching efforts during the last ten years at the Royal Institute of Technology. The purpose is to present the subject of polymer physics for undergraduate and graduate students, to focus the fundamental aspects of the subject and to show the link between experiments and theory. The intention is not to present a compilation of the currently available literature on the subject. Very few reference citations have thus been made. Each chapter has essentially the same structure: starling with an introduction, continuing with the actual subject, summarizing the chapter in 30D-500 words, and finally presenting problems and a list of relevant references for the reader. The solutions to the problems presented in Chapters 1-12 are given in Chapter 13. The theme of the book is essentially polymer science, with the exclusion of that part dealing directly with chemical reactions. The fundamentals in polymer science, including some basic polymer chemistry, are presented as an introduction in t...
National Research Council Canada - National Science Library
Ciferri, A
2000-01-01
... to the new class of self-assembled polymers that undergo reversible growth by the formation of noncovalent bonds. This class (Part II) is wider than expected: not only mainchain assemblies of hydrogen-bonded repeating units, but also planar organization of S-layer proteins, micellar and related three-dimensional structures of blo...
Li, Xiaodi; Shen, Jianhua; Akca, Haydar; Rakkiyappan, R.
2018-04-01
We introduce the Razumikhin technique to comparison principle and establish some comparison results for impulsive functional differential equations (IFDEs) with infinite delays, where the infinite delays may be infinite time-varying delays or infinite distributed delays. The idea is, under the help of Razumikhin technique, to reduce the study of IFDEs with infinite delays to the study of scalar impulsive differential equations (IDEs) in which the solutions are easy to deal with. Based on the comparison principle, we study the qualitative properties of IFDEs with infinite delays , which include stability, asymptotic stability, exponential stability, practical stability, boundedness, etc. It should be mentioned that the developed results in this paper can be applied to IFDEs with not only infinite delays but also persistent impulsive perturbations. Moreover, even for the special cases of non-impulsive effects or/and finite delays, the criteria prove to be simpler and less conservative than some existing results. Finally, two examples are given to illustrate the effectiveness and advantages of the proposed results.
CLASSIFICATION OF BIODEGRADABLE POLYMERS
Directory of Open Access Journals (Sweden)
I. I. Karpunin
2015-01-01
Full Text Available The executed investigations have made it possible to ascertain that a morphological structure of starch granules mainly determine technological peculiarities of starch isolation from raw material, its modification and its later use. Morphological structure of starch granules primarily depends on type of plant starch-containing raw material which has been used for its isolation. Class of raw material exerts a strong impact on the shape and size of the granules. Linear “light” amylose chains and “heavy” amylopectin branch chains form a starch granule ultrastructure. X-ray research has proved that starch granules are characterized by presence of interlacing amorphous and crystalline regions. In this case polymer orientation using stretching of the obtained end product influences on its physical and mechanical indices which are increasing due to polymer orientation. For the purpose of packaging orientation of polymer films can solve such important problems as significant improvement of operational properties, creation of thermosetting film materials, improvement of qualitative indices of the recycled film.Results of the conducted research have proved the fact that it is necessary to make changes in technology in order to increase biological degradability of the recycled packaging made from polymers and improve physical and mechanical indices. In this regard film production technology presupposes usage of such substances as stark and others which are characterized by rather large presence of branch chains of molecules and interlacing amorphous and crystalline regions. Such approach makes it possible to obtain after-use package which is strong and quickly degradable by micro-organisms.
Gibbs Measures Over Locally Tree-Like Graphs and Percolative Entropy Over Infinite Regular Trees
Austin, Tim; Podder, Moumanti
2018-03-01
Consider a statistical physical model on the d-regular infinite tree Td described by a set of interactions Φ . Let Gn be a sequence of finite graphs with vertex sets V_n that locally converge to Td. From Φ one can construct a sequence of corresponding models on the graphs G_n. Let μ_n be the resulting Gibbs measures. Here we assume that μ n converges to some limiting Gibbs measure μ on Td in the local weak^* sense, and study the consequences of this convergence for the specific entropies |V_n|^{-1}H(μ _n). We show that the limit supremum of |V_n|^{-1}H(μ _n) is bounded above by the percolative entropy H_{it{perc}}(μ ), a function of μ itself, and that |V_n|^{-1}H(μ _n) actually converges to H_{it{perc}}(μ ) in case Φ exhibits strong spatial mixing on T_d. When it is known to exist, the limit of |V_n|^{-1}H(μ _n) is most commonly shown to be given by the Bethe ansatz. Percolative entropy gives a different formula, and we do not know how to connect it to the Bethe ansatz directly. We discuss a few examples of well-known models for which the latter result holds in the high temperature regime.
Linked-cluster expansion for the Green's function of the infinite-U Hubbard model.
Khatami, Ehsan; Perepelitsky, Edward; Rigol, Marcos; Shastry, B Sriram
2014-06-01
We implement a highly efficient strong-coupling expansion for the Green's function of the Hubbard model. In the limit of extreme correlations, where the onsite interaction is infinite, the evaluation of diagrams simplifies dramatically enabling us to carry out the expansion to the eighth order in powers of the hopping amplitude. We compute the finite-temperature Green's function analytically in the momentum and Matsubara frequency space as a function of the electron density. Employing Padé approximations, we study the equation of state, Kelvin thermopower, momentum distribution function, quasiparticle fraction, and quasiparticle lifetime of the system at temperatures lower than, or of the order of, the hopping amplitude. We also discuss several different approaches for obtaining the spectral functions through analytic continuation of the imaginary frequency Green's function, and show results for the system near half filling. We benchmark our results for the equation of state against those obtained from a numerical linked-cluster expansion carried out to the eleventh order.
Wave vector modification of the infinite order sudden approximation
Sachs, Judith Grobe; Bowman, Joel M.
1980-10-01
A simple method is proposed to modify the infinite order sudden approximation (IOS) in order to extend its region of quantitative validity. The method involves modifying the phase of the IOS scattering matrix to include a part calculated at the outgoing relative kinetic energy as well as a part calculated at the incoming kinetic energy. An immediate advantage of this modification is that the resulting S matrix is symmetric. We also present a closely related method in which the relative kinetic energies used in the calculation of the phase are determined from quasiclassical trajectory calculations. A set of trajectories is run with the initial state being the incoming state, and another set is run with the initial state being the outgoing state, and the average final relative kinetic energy of each set is obtained. One part of the S-operator phase is then calculated at each of these kinetic energies. We apply these methods to vibrationally inelastic collinear collisions of an atom and a harmonic oscillator, and calculate transition probabilities Pn1→nf for three model systems. For systems which are sudden, or nearly so, the agreement with exact quantum close-coupling calculations is substantially improved over standard IOS ones when Δn=‖nf-ni‖ is large, and the corresponding transition probability is small, i.e., less than 0.1. However, the modifications we propose will not improve the accuracy of the IOS transition probabilities for any collisional system unless the standard form of IOS already gives at least qualitative agreement with exact quantal calculations. We also suggest comparisons between some classical quantities and sudden predictions which should help in determining the validity of the sudden approximation. This is useful when exact quantal data is not available for comparison.
On the BRST charge over infinite-dimensional algebras
International Nuclear Information System (INIS)
Hlousek, Zvonimir.
1988-01-01
The author studies the BRST charge defined over an infinite algebra of gauged local symmetries. This is of great importance to string theories. The BRST charge of the gauge symmetry must be nilpotent. In string theories this implies the cancellation of conformal anomalies in critical dimension; 26 for bosonic string, 10 for superstring, and 2 for O(2) string. Furthermore, the O(2) symmetry of the O(2) string (a string theory with two, two-dimensional supersymmetries) is realized as a Kac-Moody symmetry. In general, the BRST quantization of the local, gauged KAC-Moody symmetry requires special care due to chiral anomaly. The chiral anomaly breaks the chiral gauge invariance, and the corresponding BRST charge is not nilpotent. To arrive at the nilpotent BRST charge for the gauged Kac-Moody symmetry, one has to modify the theory by adding a one-cocycle over the gauge group. A similar problem and its solution exist in the case of supersymmetric Kac-Moody algebras. The BRST charge of the first quantized string theory is a building block of the covariant string field theory. The BRST invariance of the first quantized theory generalizes to gauge invariance of string field theory. In Witten's open string field theory the BRST charge plays a role of exterior derivation on the space of string field functionals. The Fock space realization of the theory was given by Gross and Jevicki. For the consistency of the theory it is crucial that all the vertex operators are BRST invariant. The ghost part of the vertex comes in few varieties. The author has shown that all the versions of the ghost vertex are equivalent, as long as the total vertex is BRST invariant
Second law analysis of an infinitely segmented magnetohydrodynamic generator
International Nuclear Information System (INIS)
Arash, Ardeshir; Saidi, Mohammad Hassan; Najafi, Mohammad
2017-01-01
The performance of an infinitely segmented magnetohydrodynamic generator is analyzed using the second law of thermodynamics entropy generation criterion. The exact analytical solution of the velocity and temperature fields are provided by applying the modified Hartmann flow model, taking into account the occurrence of the Hall effect in the considered generator. Contributions of heat transfer, fluid friction, and ohmic dissipation to the destruction of useful available work are found, and the nature of irreversibilities in the considered generator is determined. In addition, the electrical isotropic efficiency scheme is used to evaluate the generator performance. Finally, the implication of the Hall parameter, Hartmann number, and load factor for the entropy generation and the generator performance are studied and the optimal operating conditions are determined. The results show that the heat transfer has the smallest contribution to the entropy generation compared to that of the friction and ohmic dissipation. The application of the Hall effect on the system showed an appreciable augmentation of entropy generation rate which is along with what the logic implies. A parametric study is conducted and its results provide the generated entropy and also efficiency diagrams which show the influence of the Hall effect on the considered generator. - Highlights: • The modified Hartmann flow in a segmented MHD generator has been analyzed. • Heat transfer has the smallest contribution to the entropy generation. • The optimum working conditions of the generator are discussed. • The significant adverse effect of taking into account the Hall effect is discussed. • The entropy generation increases while implementing modified Hartmann model.
INFINITE PLANNING HORIZON, LAND OPPORTUNITY COST AND FAUSTMANN METHODOLOGY
Directory of Open Access Journals (Sweden)
José Luiz Pereira de Rezende
2005-06-01
Full Text Available The paper studied and discussed The Faustmann Method (Land Expected Value - LEV comparing it with The NetDiscounted Value project evaluation criterion, in an infinite horizon (NDV . The method was applied for determining land value,envisaging eucalyptus plantation in savannah area (cerrado in Brazil, for the purpose of charcoal production. For the same situationthe Net Discounted Value was applied and compared. The costs considered were establishment, maintenance and harvesting and thatthe forest was managed with the substitution being done after cutting the original establishment at seven years of age, that is, there isno coppicing transport. The substitution cost was considered equal to that of establishment. The only income considered was the saleof the wood produced for energy (250 st/ha at the price of US$ 7.10/st in the cutting age. The main conclusions were: For anydiscount rate, LEV is always a larger value than NDV , because NDV considers land in the relationship of costs; the assumption thatland only has value for wood production, implied by Faustmann methodology, doesn t have theoretical nor practical support; if thereis no alternative for land use, then its opportunity cost is zero and there would be no reason to determine its value; land productivevalue is not the only value that enters in the formation of its price. The Faustmann methodology doesn t capture the other factors thataffect land price, for instance, the speculative effects, cultural values, land protective value, protection against inflation and of statusattribution, etc..; LEV indicates how much can be spent in any cost item left out of the calculations.
Quantum critical phase with infinite projected entangled paired states
Poilblanc, Didier; Mambrini, Matthieu
2017-07-01
A classification of SU(2)-invariant projected entangled paired states (PEPS) on the square lattice, based on a unique site tensor, has been recently introduced by Mambrini et al. [M. Mambrini, R. Orús, and D. Poilblanc, Phys. Rev. B 94, 205124 (2016), 10.1103/PhysRevB.94.205124]. It is not clear whether such SU(2)-invariant PEPS can either (i) exhibit long-range magnetic order (such as in the Néel phase) or (ii) describe a genuine quantum critical point (QCP) or quantum critical phase (QCPh) separating two ordered phases. Here, we identify a specific family of SU(2)-invariant PEPS of the classification which provides excellent variational energies for the J1-J2 frustrated Heisenberg model, especially at J2=0.5 , corresponding to the approximate location of the QCP or QCPh separating the Néel phase from a dimerized phase. The PEPS are built from virtual states belonging to the 1/2⊗N⊕0 SU(2) representation, i.e., with N "colors" of virtual spin-1/2 . Using a full-update infinite-PEPS approach directly in the thermodynamic limit, based on the corner transfer matrix renormalization algorithm supplemented by a conjugate gradient optimization scheme, we provide evidence of (i) the absence of magnetic order and of (ii) diverging correlation lengths (i.e., showing no sign of saturation with increasing environment dimension) in both the singlet and triplet channels, when the number of colors N ≥3 . We argue that such a PEPS gives a qualitative description of the QCP or QCPh of the J1-J2 model.
Infinite nuclear matter model and mass formulae for nuclei
International Nuclear Information System (INIS)
Satpathy, L.
2016-01-01
The matter composed of the nucleus is a quantum-mechanical interacting many-fermionic system. However, the shell and classical liquid drop have been taken as the two main features of nuclear dynamics, which have guided the evolution of nuclear physics. These two features can be considered as the macroscopic manifestation of the microscopic dynamics of the nucleons at fundamental level. Various mass formulae have been developed based on either of these features over the years, resulting in many ambiguities and uncertainties posing many challenges in this field. Keeping this in view, Infinite Nuclear Matter (INM) model has been developed during last couple of decades with a many-body theoretical foundation employing the celebrated Hugenholtz-Van Hove theorem, quite appropriate for the interacting quantum-mechanical nuclear system. A mass formula called INM mass formula based on this model yields rms deviation of 342 keV being the lowest in literature. Some of the highlights of its result includes its determination of INM density in agreement with the electron scattering data leading to the resolution of the long standing 'r 0 -paradox' it predicts new magic numbers giving rise to new island of stability in the drip-line regions. This is the manifestation of a new phenomenon where shell-effect over comes the repulsive component of nucleon-nucleon force resulting in the broadening of the stability peninsula. Shell quenching in N= 82,and N= 126 shells, and several islands of inversion have been predicted. The model determines the empirical value of the nuclear compression modulus, using high precission 4500 data comprising nuclear masses, neutron and proton separation energies. The talk will give a critical review of the field of mass formula and our understanding of nuclear dynamics as a whole
Polymer/metal nanocomposites for biomedical applications.
Zare, Yasser; Shabani, Iman
2016-03-01
Polymer/metal nanocomposites consisting of polymer as matrix and metal nanoparticles as nanofiller commonly show several attractive advantages such as electrical, mechanical and optical characteristics. Accordingly, many scientific and industrial communities have focused on polymer/metal nanocomposites in order to develop some new products or substitute the available materials. In the current paper, characteristics and applications of polymer/metal nanocomposites for biomedical applications are extensively explained in several categories including strong and stable materials, conductive devices, sensors and biomedical products. Moreover, some perspective utilizations are suggested for future studies. Copyright © 2015 Elsevier B.V. All rights reserved.
Enhanced photophysics of conjugated polymers
Chen, Liaohai [Darien, IL
2007-06-12
A particulate fluorescent conjugated polymer surfactant complex and method of making and using same. The particles are between about 15 and about 50 nm and when formed from a lipsome surfactant have a charge density similar to DNA and are strongly absorbed by cancer cells.
Dendronized Polymers with Ureidopyrimidinone Groups
DEFF Research Database (Denmark)
Scherz, Leon F.; Costanzo, Salvatore; Huang, Qian
2017-01-01
A library of poly(methyl methacrylate)-based dendronized polymers with generation numbers g = 1-3 was prepared, which contain different degrees of dendritic substitution (0-50%) with strongly hydrogen bonding 2-ureido-4[1H]-pyrimidinone (UPy) moieties at their respective g = 1 levels. Our...
Spectral asymptotics of a strong δ′ interaction supported by a surface
International Nuclear Information System (INIS)
Exner, Pavel; Jex, Michal
2014-01-01
Highlights: • Attractive δ ′ interactions supported by a smooth surface are considered. • Surfaces can be either infinite and asymptotically planar, or compact and closed. • Spectral asymptotics is determined by the geometry of the interaction support. - Abstract: We derive asymptotic expansion for the spectrum of Hamiltonians with a strong attractive δ ′ interaction supported by a smooth surface in R 3 , either infinite and asymptotically planar, or compact and closed. Its second term is found to be determined by a Schrödinger type operator with an effective potential expressed in terms of the interaction support curvatures
Strongly nonlinear waves in a chain of Teflon beads
Daraio, C.; Nesterenko, V. F.; Herbold, E. B.; Jin, S.
2005-01-01
One-dimensional “sonic vacuum” type phononic crystals were assembled from a chain of polytetrafluoroethylene (PTFE,Teflon) spheres with different diameters in a Teflon holder. It was demonstrated that this polymer-based sonic vacuum, with exceptionally low elastic modulus of particles, supports propagation of strongly nonlinear solitary waves with a very low speed. These solitary waves can be described using the classical nonlinear Hertz law despite the viscoelastic nature of the polymer and ...
Strongly Correlated Topological Insulators
2016-02-03
Strongly Correlated Topological Insulators In the past year, the grant was used for work in the field of topological phases, with emphasis on finding...surface of topological insulators. In the past 3 years, we have started a new direction, that of fractional topological insulators. These are materials...in which a topologically nontrivial quasi-flat band is fractionally filled and then subject to strong interactions. The views, opinions and/or
Bioinspired phospholipid polymer biomaterials for making high performance artificial organs
K Ishihara
2000-01-01
Novel polymer biomaterials, which can be used in contact with blood, are prepared with strong inspiration from the surface structure of biomembrane. That is, the polymers with a phospholipid polar group in the side chain, 2-methacrylooyloxyethyl phosphorylcholine (MPC) polymers were synthesized. The MPC polymers can inhibit surface-induced clot formation effectively, when they are in contact with blood even in the absence of an anticoagulant. This phenomenon was due to the reduction of plasma...
Isenberg, James
2017-01-01
The Hawking-Penrose theorems tell us that solutions of Einstein's equations are generally singular, in the sense of the incompleteness of causal geodesics (the paths of physical observers). These singularities might be marked by the blowup of curvature and therefore crushing tidal forces, or by the breakdown of physical determinism. Penrose has conjectured (in his `Strong Cosmic Censorship Conjecture`) that it is generically unbounded curvature that causes singularities, rather than causal breakdown. The verification that ``AVTD behavior'' (marked by the domination of time derivatives over space derivatives) is generically present in a family of solutions has proven to be a useful tool for studying model versions of Strong Cosmic Censorship in that family. I discuss some of the history of Strong Cosmic Censorship, and then discuss what is known about AVTD behavior and Strong Cosmic Censorship in families of solutions defined by varying degrees of isometry, and discuss recent results which we believe will extend this knowledge and provide new support for Strong Cosmic Censorship. I also comment on some of the recent work on ``Weak Null Singularities'', and how this relates to Strong Cosmic Censorship.
Order and Chaos in Some Deterministic Infinite Trigonometric Products
Albert, Leif; Kiessling, Michael K.-H.
2017-08-01
It is shown that the deterministic infinite trigonometric products \\prod _{n\\in N}[ 1- p +p cos ( style n^{-s}_{_{}}t) ] =: {{ Cl }_{p;s}^{}}(t) with parameters p\\in (0,1] & s>1/2, and variable t\\in R, are inverse Fourier transforms of the probability distributions for certain random series Ω p^ζ (s) taking values in the real ω line; i.e. the {{ Cl }_{p;s}^{}}(t) are characteristic functions of the Ω p^ζ (s). The special case p=1=s yields the familiar random harmonic series, while in general Ω p^ζ (s) is a "random Riemann-ζ function," a notion which will be explained and illustrated—and connected to the Riemann hypothesis. It will be shown that Ω p^ζ (s) is a very regular random variable, having a probability density function (PDF) on the ω line which is a Schwartz function. More precisely, an elementary proof is given that there exists some K_{p;s}^{}>0, and a function F_{p;s}^{}(|t|) bounded by |F_{p;s}^{}(|t|)|!≤ \\exp \\big (K_{p;s}^{} |t|^{1/(s+1)}), and C_{p;s}^{} =-1/s\\int _0^∞ ln |{1-p+p cos ξ }|1/ξ ^{1+1/s}{d}ξ , such that \\forall t\\in R:\\quad {{ Cl }_{p;s}^{}}(t) = \\exp \\bigl ({- C_{p;s}^{} |t|^{1/s}\\bigr )F_{p;s}^{}(|t|)}; the regularity of Ω p^ζ (s) follows. Incidentally, this theorem confirms a surmise by Benoit Cloitre, that ln {{ Cl }_{{{1}/{3}};2}^{}}(t) ˜ -C√{t} ( t→ ∞) for some C>0. Graphical evidence suggests that {{ Cl }_{{{1}/{3}};2}^{}}(t) is an empirically unpredictable (chaotic) function of t. This is reflected in the rich structure of the pertinent PDF (the Fourier transform of {{ Cl }_{{{1}/{3}};2}^{}}), and illustrated by random sampling of the Riemann-ζ walks, whose branching rules allow the build-up of fractal-like structures.
Development of Silicate Polymers
DEFF Research Database (Denmark)
Søgaard, Erik Gydesen; Simonsen, Morten Enggrob
an inorganic binder is developed based on fumed silica and potassium hydroxide. The optimal composition of the binder system was determined using compressive strength test. The investigation showed that the strength of the inorganic binder was strongly related to the content of potassium hydroxide...... hydroxide in acid and increase pH to saturation of the metal hydroxide. It is assumed that the syntheses of the inorganic polymer are carried out through polymerisation of oligomers (dimer, trimer) which provide the actual unit structures of the three dimensional macromolecular structure. In this work...
Energy Technology Data Exchange (ETDEWEB)
Allen, Scott D.; Naik, Sanjeev
2017-08-22
The present invention provides, among other things, extruded blends of aliphatic polycarbonates and polyolefins. In one aspect, provided blends comprise aliphatic polycarbonates such as poly(propylene carbonate) and a lesser amount of a crystalline or semicrystalline polymer. In certain embodiments, provided blends are characterized in that they exhibit unexpected improvements in their elongation properties. In another aspect, the invention provides methods of making such materials and applications of the materials in applications such as the manufacture of consumer packaging materials.
Infinite Multiplication Factor and Temperature Coefficient of MSR Calculated by HELIOS
International Nuclear Information System (INIS)
Nemeth, Z.; Necas, V.; Darilak, P.
2006-01-01
The aim of this study was to make a correct model of an elementary MSR cell calculated by HELIOS. Infinite multiplication factor and temperature coefficient of reactivity were calculated for various fuel channel diameters (Authors)
Existence of infinitely many periodic solutions for second-order nonautonomous Hamiltonian systems
Directory of Open Access Journals (Sweden)
Wen Guan
2015-04-01
Full Text Available By using minimax methods and critical point theory, we obtain infinitely many periodic solutions for a second-order nonautonomous Hamiltonian systems, when the gradient of potential energy does not exceed linear growth.
Directory of Open Access Journals (Sweden)
Benaouda Hedia
2015-07-01
Full Text Available In this paper we investigate the existence three positives solutions by using Leggett-Williams fixed point theorem in cones for three boundary value problem with fractional order and infinite delay.
Stochastic optimal control in infinite dimension dynamic programming and HJB equations
Fabbri, Giorgio; Święch, Andrzej
2017-01-01
Providing an introduction to stochastic optimal control in infinite dimension, this book gives a complete account of the theory of second-order HJB equations in infinite-dimensional Hilbert spaces, focusing on its applicability to associated stochastic optimal control problems. It features a general introduction to optimal stochastic control, including basic results (e.g. the dynamic programming principle) with proofs, and provides examples of applications. A complete and up-to-date exposition of the existing theory of viscosity solutions and regular solutions of second-order HJB equations in Hilbert spaces is given, together with an extensive survey of other methods, with a full bibliography. In particular, Chapter 6, written by M. Fuhrman and G. Tessitore, surveys the theory of regular solutions of HJB equations arising in infinite-dimensional stochastic control, via BSDEs. The book is of interest to both pure and applied researchers working in the control theory of stochastic PDEs, and in PDEs in infinite ...
International Nuclear Information System (INIS)
Sarmento, E.F.
1981-01-01
Results are found for the dynamical correlation functions (or its corresponding Green's functions) among any combination including operator pairs of electronic and nuclear spins in an antiferromagnet semi-infinite medium, at low temperatures T [pt
The numerical solution of boundary value problems over an infinite domain
International Nuclear Information System (INIS)
Shepherd, M.; Skinner, R.
1976-01-01
A method is presented for the numerical solution of boundary value problems over infinite domains. An example that illustrates also the strength and accuracy of a numerical procedure for calculating Green's functions is described in detail
Directory of Open Access Journals (Sweden)
Liu Yang
2014-01-01
Full Text Available We investigate a class of nonperiodic fourth order differential equations with general potentials. By using variational methods and genus properties in critical point theory, we obtain that such equations possess infinitely homoclinic solutions.
Study of the thermal shock between two semi-infinite bodies during ultra-fast transients
International Nuclear Information System (INIS)
Perret, R.
1977-01-01
For the heat-conduction system of two suddently-contacting semi-infinite bodies at different temperatures, the hyperbolic equation is compared with the Fourier equation. The times are reported during which the solutions differ significantly; in particular, at the initial instant of contact, the hyperbolic equation predicts a zero heat flux, while the classic equation an infinite heat flux. The temperature of contact obtained using the hyperbolic equation is used in a model of vapor explosion [fr
Infinite Dimensional Stochastic Analysis : in Honor of Hui-Hsiung Kuo
Sundar, Pushpa
2008-01-01
This volume contains current work at the frontiers of research in infinite dimensional stochastic analysis. It presents a carefully chosen collection of articles by experts to highlight the latest developments in white noise theory, infinite dimensional transforms, quantum probability, stochastic partial differential equations, and applications to mathematical finance. Included in this volume are expository papers which will help increase communication between researchers working in these areas. The tools and techniques presented here will be of great value to research mathematicians, graduate
When may unstable gravitating disk be considered an infinitely thin gravitating disk
Energy Technology Data Exchange (ETDEWEB)
Polyachenko, V.L.; Fridman, A.M. (AN SSSR, Irkutsk. Sibirskij Inst. Zemnogo Magnetizma Ionosfery i Rasprostraneniya Radiovoln; AN SSSR, Moscow. Astronomicheskij Sovet)
1981-03-01
It is shown that the model of an infinitely thin gravitating disk is valid for investigation of its stability only if a massive halo is present. Conditions for main parameters of the disk and halo are obtained when, firstly, most unstable wavelengths are much larger than the disk thickness (approximation of an infinitely thin disk) and, secondary, the contribution of a halo to the perturbed gravitational potential can be neglected. Density distributions of the disk and halo are obtained.
Infinite product expansion of the Fokker-Planck equation with steady-state solution.
Martin, R J; Craster, R V; Kearney, M J
2015-07-08
We present an analytical technique for solving Fokker-Planck equations that have a steady-state solution by representing the solution as an infinite product rather than, as usual, an infinite sum. This method has many advantages: automatically ensuring positivity of the resulting approximation, and by design exactly matching both the short- and long-term behaviour. The efficacy of the technique is demonstrated via comparisons with computations of typical examples.
Notes on the occupancy problem with infinitely many boxes: general asymptotics and power laws
Gnedin, Alexander; Hansen, Ben; Pitman, Jim
2007-01-01
This paper collects facts about the number of occupied boxes in the classical balls-in-boxes occupancy scheme with infinitely many positive frequencies: equivalently, about the number of species represented in samples from populations with infinitely many species. We present moments of this random variable, discuss asymptotic relations among them and with related random variables, and draw connections with regular variation, which appears in various manifestations.
Coherent states for canonical quantum general relativity and the infinite tensor product extension
International Nuclear Information System (INIS)
Sahlmann, H.; Thiemann, T.; Winkler, O.
2001-01-01
We summarize a recently proposed concrete programme for investigating the (semi)classical limit of canonical, Lorentzian, continuum quantum general relativity in four spacetime dimensions. The analysis is based on a novel set of coherent states labelled by graphs. These fit neatly together with an Infinite Tensor Product (ITP) extension of the currently used Hilbert space. The ITP construction enables us to give rigorous meaning to the infinite volume (thermodynamic) limit of the theory which has been out of reach so far
Infinite many conservation laws of discrete system associated with a 3×3 matrix spectral problem
Directory of Open Access Journals (Sweden)
Zhang Sheng
2017-01-01
Full Text Available Differential-difference equations are often considered as an alternative approach to describing some phenomena arising in heat/electron conduction and flow in carbon nanotubes and nanoporous materials. Infinite many conservation laws play important role in discussing the integrability of non-linear differential equations. In this paper, infinite many conservation laws of the non-linear differential-difference equations associated with a 3×3 matrix spectral problem are obtained.
Simulated Associating Polymer Networks
Billen, Joris
Telechelic associating polymer networks consist of polymer chains terminated by endgroups that have a different chemical composition than the polymer backbone. When dissolved in a solution, the endgroups cluster together to form aggregates. At low temperature, a strongly connected reversible network is formed and the system behaves like a gel. Telechelic networks are of interest since they are representative for biopolymer networks (e.g. F-actin) and are widely used in medical applications (e.g. hydrogels for tissue engineering, wound dressings) and consumer products (e.g. contact lenses, paint thickeners). In this thesis such systems are studied by means of a molecular dynamics/Monte Carlo simulation. At first, the system in rest is studied by means of graph theory. The changes in network topology upon cooling to the gel state, are characterized. Hereto an extensive study of the eigenvalue spectrum of the gel network is performed. As a result, an in-depth investigation of the eigenvalue spectra for spatial ER, scale-free, and small-world networks is carried out. Next, the gel under the application of a constant shear is studied, with a focus on shear banding and the changes in topology under shear. Finally, the relation between the gel transition and percolation is discussed.
International Nuclear Information System (INIS)
Kornreich, D.E.; Ganapol, B.D.
1997-01-01
The linear Boltzmann equation for the transport of neutral particles is investigated with the objective of generating benchmark-quality evaluations of solutions for homogeneous infinite media. In all cases, the problems are stationary, of one energy group, and the scattering is isotropic. The solutions are generally obtained through the use of Fourier transform methods with the numerical inversions constructed from standard numerical techniques such as Gauss-Legendre quadrature, summation of infinite series, and convergence acceleration. Consideration of the suite of benchmarks in infinite homogeneous media begins with the standard one-dimensional problems: an isotropic point source, an isotropic planar source, and an isotropic infinite line source. The physical and mathematical relationships between these source configurations are investigated. The progression of complexity then leads to multidimensional problems with source configurations that also emit particles isotropically: the finite line source, the disk source, and the rectangular source. The scalar flux from the finite isotropic line and disk sources will have a two-dimensional spatial variation, whereas a finite rectangular source will have a three-dimensional variation in the scalar flux. Next, sources emitting particles anisotropically are considered. The most basic such source is the point beam giving rise to the Green's function, which is physically the most fundamental transport problem, yet may be constructed from the isotropic point source solution. Finally, the anisotropic plane and anisotropically emitting infinite line sources are considered. Thus, a firm theoretical and numerical base is established for the most fundamental neutral particle benchmarks in infinite homogeneous media
International Nuclear Information System (INIS)
Baer, M.; Nakamura, H.; Kouri, D.J.
1986-01-01
In this work the ion-molecule reaction He + H 2 + (v/sub i/) → HeH + (v/sub f/) + H(v/sub i/ = 0-7, v/sub f/ = 0-2) was studied quantum mechanically in the energy range 1.3 eV ≤ E/sub tot/ ≤ 1.8 eV. The calculations were carried out employing the Reactive Infinite Order Sudden Approximation (RIOSA). The two features characteristic of this system in the above energy range, namely the strong enhancement of the reaction rate with the initial vibrational energy (at a fixed total energy) and the relatively weak dependence of the cross sections on translational energy, were found to be well reproduced in the numerical treatment. The results also revealed the existence of two mechanisms of the exchange process: one is the ordinary mechanism and the other is probably related to the spectator stripping model
Espinoza, Benjamin; Gartside, Paul; Kovan-Bakan, Merve; Mamatelashvili, Ana
2012-01-01
A space is `n-strong arc connected' (n-sac) if for any n points in the space there is an arc in the space visiting them in order. A space is omega-strong arc connected (omega-sac) if it is n-sac for all n. We study these properties in finite graphs, regular continua, and rational continua. There are no 4-sac graphs, but there are 3-sac graphs and graphs which are 2-sac but not 3-sac. For every n there is an n-sac regular continuum, but no regular continuum is omega-sac. There is an omega-sac ...
Abortion: Strong's counterexamples fail
DEFF Research Database (Denmark)
Di Nucci, Ezio
2009-01-01
This paper shows that the counterexamples proposed by Strong in 2008 in the Journal of Medical Ethics to Marquis's argument against abortion fail. Strong's basic idea is that there are cases--for example, terminally ill patients--where killing an adult human being is prima facie seriously morally......'s scenarios have some valuable future or admitted that killing them is not seriously morally wrong. Finally, if "valuable future" is interpreted as referring to objective standards, one ends up with implausible and unpalatable moral claims....
Dispersion of strongly confined channel plasmon polariton modes
DEFF Research Database (Denmark)
Zenin, Vladimir; Volkov, Valentyn S.; Han, Zhanghua
2011-01-01
We report on experimental (by use of scanning near-field optical microscopy) and theoretical investigations of strongly confined (∼λ/5) channel plasmon polariton (CPP) modes propagating at telecom wavelengths (1425–1630 nm) along V-grooves cut in a gold film. The main CPP characteristics (mode...... index, width, and propagation length) are determined directly from the experimental near-field images and compared to theoretical results obtained using an analytic description of CPP modes supported by (infinitely deep) V-grooves and finite-element simulations implemented in COMSOL....
Strongly interacting atom lasers in three-dimensional optical lattices.
Hen, Itay; Rigol, Marcos
2010-10-29
We show that the dynamical melting of a Mott insulator in a three-dimensional lattice leads to condensation at nonzero momenta, a phenomenon that can be used to generate strongly interacting atom lasers in optical lattices. For infinite on-site repulsion, the case considered here, the momenta at which bosons condense are determined analytically and found to have a simple dependence on the hopping amplitudes. The occupation of the condensates is shown to scale linearly with the total number of atoms in the initial Mott insulator. Our results are obtained by using a Gutzwiller-type mean-field approach, gauged against exact-diagonalization solutions of small systems.
International Nuclear Information System (INIS)
Marier, D.
1992-01-01
This article presents the results of a financial rankings survey which show a strong economic activity in the independent energy industry. The topics of the article include advisor turnover, overseas banks, and the increase in public offerings. The article identifies the top project finance investors for new projects and restructurings and rankings for lenders
Skvortsov, A.M.; Klushin, L.I.; Leermakers, F.A.M.
2007-01-01
An end-tethered polymer chain compressed between two pistons undergoes an abrupt transition from a confined coil state to an inhomogeneous flowerlike conformation partially escaped from the gap. This phase transition is first order in the thermodynamic limit of infinitely long chains. A rigorous
DEFF Research Database (Denmark)
Zhang, Yang; Hansen, Hans Nørgaard; De Grave, Arnaud
2011-01-01
was performed on the laser-machined polymer using an Alicona InfiniteFocus® microscope. Based on previous experiments, bearing area curve and its parameters are chosen to characterize the surface. In this paper, by comparison of plateable and non-plateable surfaces, and two types of plateable surface made...
DEFF Research Database (Denmark)
Larsen, Esben Kjær Unmack; Larsen, Niels Bent
2013-01-01
The non-specific adsorption of dissolved analytes strongly reduces the sensitivity and reliability in polymer microanalytical systems. Here, a one-step aqueous phase procedure modifies polymer material surfaces to strongly reduce their non-specific adsorption of a broad range of organic analytes ...... systems, including polystyrene (PS), cyclic olefin copolymer (COC), liquid crystalline polymer (LCP), and polyimide (PI)....
Poroelastic toughening in polymer gels: A theoretical and numerical study
Noselli, Giovanni; Lucantonio, Alessandro; McMeeking, Robert M.; DeSimone, Antonio
2016-09-01
We explore the Mode I fracture toughness of a polymer gel containing a semi-infinite, growing crack. First, an expression is derived for the energy release rate within the linearized, small-strain setting. This expression reveals a crack tip velocity-independent toughening that stems from the poroelastic nature of polymer gels. Then, we establish a poroelastic cohesive zone model that allows us to describe the micromechanics of fracture in gels by identifying the role of solvent pressure in promoting poroelastic toughening. We evaluate the enhancement in the effective fracture toughness through asymptotic analysis. We confirm our theoretical findings by means of numerical simulations concerning the case of a steadily propagating crack. In broad terms, our results explain the role of poroelasticity and of the processes occurring in the fracturing region in promoting toughening of polymer gels.
Strong Electroweak Symmetry Breaking
Grinstein, Benjamin
2011-01-01
Models of spontaneous breaking of electroweak symmetry by a strong interaction do not have fine tuning/hierarchy problem. They are conceptually elegant and use the only mechanism of spontaneous breaking of a gauge symmetry that is known to occur in nature. The simplest model, minimal technicolor with extended technicolor interactions, is appealing because one can calculate by scaling up from QCD. But it is ruled out on many counts: inappropriately low quark and lepton masses (or excessive FCNC), bad electroweak data fits, light scalar and vector states, etc. However, nature may not choose the minimal model and then we are stuck: except possibly through lattice simulations, we are unable to compute and test the models. In the LHC era it therefore makes sense to abandon specific models (of strong EW breaking) and concentrate on generic features that may indicate discovery. The Technicolor Straw Man is not a model but a parametrized search strategy inspired by a remarkable generic feature of walking technicolor,...
Plasmons in strong superconductors
International Nuclear Information System (INIS)
Baldo, M.; Ducoin, C.
2011-01-01
We present a study of the possible plasmon excitations that can occur in systems where strong superconductivity is present. In these systems the plasmon energy is comparable to or smaller than the pairing gap. As a prototype of these systems we consider the proton component of Neutron Star matter just below the crust when electron screening is not taken into account. For the realistic case we consider in detail the different aspects of the elementary excitations when the proton, electron components are considered within the Random-Phase Approximation generalized to the superfluid case, while the influence of the neutron component is considered only at qualitative level. Electron screening plays a major role in modifying the proton spectrum and spectral function. At the same time the electron plasmon is strongly modified and damped by the indirect coupling with the superfluid proton component, even at moderately low values of the gap. The excitation spectrum shows the interplay of the different components and their relevance for each excitation modes. The results are relevant for neutrino physics and thermodynamical processes in neutron stars. If electron screening is neglected, the spectral properties of the proton component show some resemblance with the physical situation in high-T c superconductors, and we briefly discuss similarities and differences in this connection. In a general prospect, the results of the study emphasize the role of Coulomb interaction in strong superconductors.
Bioinspired phospholipid polymer biomaterials for making high performance artificial organs
Directory of Open Access Journals (Sweden)
K Ishihara
2000-01-01
Full Text Available Novel polymer biomaterials, which can be used in contact with blood, are prepared with strong inspiration from the surface structure of biomembrane. That is, the polymers with a phospholipid polar group in the side chain, 2-methacrylooyloxyethyl phosphorylcholine (MPC polymers were synthesized. The MPC polymers can inhibit surface-induced clot formation effectively, when they are in contact with blood even in the absence of an anticoagulant. This phenomenon was due to the reduction of plasma protein and suppression of denaturation of adsorbed proteins, that is the MPC polymers interact with blood components very mildly. As the molecular structure of the MPC polymer was easily designed by changing the monomer units and their composition, it could be applied to surface modification of artificial organs and biomedical devices for improving blood and tissue compatibility. Thus, the MPC polymers are useful polymer biomaterials for manufacturing high performance artificial organs and biomedical devices to provide safe medical treatments.
Park, ChooJin; Hyun, Dong Choon; Lim, Min-Cheol; Kim, Su-Jeong; Kim, Young-Rok; Paik, Hyun-Jong; Jeong, Unyong
2011-08-17
This study reports a continuous prepartion of spherical or hemispherical polymer particles simply utilizing the phase separation in polymer blend films during the coating process. We took an advantage of the strong phase separation between a water-soluble crystalline polymer as a matrix and hydrophobic polymers as minor components. We demonstrated the prepartion of water-soluble polystyrene (PS) particles, nitrilotriacetic acid (NTA)-functionalized PS particles for protein separation, and semiconducting poly(3-hexylthiophene) (P3HT) particles. The sizes of the particles could be controlled by adjusting the film thickness and weight fraction of the minor component polymers in the blend film. It provides a simple facile way to prepare polymer particles in a continous process. Copyright © 2011 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.
Thermodynamic properties of hyperbranched polymer, Boltorn U3000, using inverse gas chromatography.
Domańska, Urszula; Zołek-Tryznowska, Zuzanna
2009-11-19
Mass-fraction activity coefficients at infinite dilution (Omega13(infinity)) of alkanes (C5-C10), cycloalkanes (C5-C8), alkenes (C5-C8), alkynes (C5-C8), aromatic hydrocarbons (benzene, toluene, ethylbenzene, o-, m-, p-xylene, thiophene), alcohols (C1-C5), water, ethers (tetrahydrofuran (THF), methyl-tert-butylether (MTBE), diethyl-, di-n-propyl-, di-n-butyl ether), and ketones (propanone, 2-pentanone, 3-pentanone, 2-hexanone, 3-hexanone, cyclopentanone) in the hyperbranched polymer, Boltorn U3000 (B-U3000), have been determined by inverse gas chromatography (IGC) using the polymer as the stationary phase. The measurements were carried out at different temperatures between 308.15 and 348.15 K. The density and thermophysical properties of polymer were described. The specific retention volume (V(g)), the Flory-Huggins interaction parameter (chi13(infinity)), the molar enthalpy of sorption (the partial molar enthalpies of solute dissolution) (Delta(s)H), the partial molar excess enthalpy at infinite dilution of the solute and polymer (DeltaH1(E,infinity)), the partial molar Gibbs excess energy at infinite dilution (DeltaG1(E,infinity)), and the solubility parameter (delta3) were calculated.
Strong-coupling approximations
International Nuclear Information System (INIS)
Abbott, R.B.
1984-03-01
Standard path-integral techniques such as instanton calculations give good answers for weak-coupling problems, but become unreliable for strong-coupling. Here we consider a method of replacing the original potential by a suitably chosen harmonic oscillator potential. Physically this is motivated by the fact that potential barriers below the level of the ground-state energy of a quantum-mechanical system have little effect. Numerically, results are good, both for quantum-mechanical problems and for massive phi 4 field theory in 1 + 1 dimensions. 9 references, 6 figures
International Nuclear Information System (INIS)
Ebata, T.
1981-01-01
With an assumed weak multiplet structure for bosonic hadrons, which is consistent with the ΔI = 1/2 rule, it is shown that the strong interaction effective hamiltonian is compatible with the weak SU(2) x U(1) gauge transformation. Especially the rho-meson transforms as a triplet under SU(2)sub(w), and this is the origin of the rho-photon analogy. It is also shown that the existence of the non-vanishing Cabibbo angle is a necessary condition for the absence of the exotic hadrons. (orig.)
Energy Technology Data Exchange (ETDEWEB)
Kinyanjui, M.; Kwanza, J.K.; Uppal, S.M. [Jomo Kenyatta University of Agriculture and Technology, Nairobi (Cayman Islands). Dept. of Mathematics and Statistics
2001-05-01
Simultaneous heat and mass transfer in unsteady free convection flow with radiation absorption past an impulsively started infinite vertical porous plate subjected to a strong magnetic field is presented. The governing equations for the problem are solved by a finite difference scheme. The influence of the various parameters on the convectively cooled or convectively heated plate in the laminar boundary layer are considered. An analysis of the effects of the parameters on the concentration, velocity and temperature profiles, as well as skin friction and the rates of mass and heat transfer, is done with the aid of graphs and tables. (author)
Dvali, Gia
2009-01-01
We show that whenever a 4-dimensional theory with N particle species emerges as a consistent low energy description of a 3-brane embedded in an asymptotically-flat (4+d)-dimensional space, the holographic scale of high-dimensional gravity sets the strong coupling scale of the 4D theory. This connection persists in the limit in which gravity can be consistently decoupled. We demonstrate this effect for orbifold planes, as well as for the solitonic branes and string theoretic D-branes. In all cases the emergence of a 4D strong coupling scale from bulk holography is a persistent phenomenon. The effect turns out to be insensitive even to such extreme deformations of the brane action that seemingly shield 4D theory from the bulk gravity effects. A well understood example of such deformation is given by large 4D Einstein term in the 3-brane action, which is known to suppress the strength of 5D gravity at short distances and change the 5D Newton's law into the four-dimensional one. Nevertheless, we observe that the ...
Improved Dispersion of Carbon Nanotubes in Polymers at High Concentrations.
Liu, Chao-Xuan; Choi, Jin-Woo
2012-10-26
The polymer nanocomposite used in this work comprises elastomer poly(dimethylsiloxane) (PDMS) as a polymer matrix and multi-walled carbon nanotubes (MWCNTs) as a conductive nanofiller. To achieve uniform distribution of carbon nanotubes within the polymer, an optimized dispersion process was developed, featuring a strong organic solvent-chloroform, which dissolved PDMS base polymer easily and allowed high quality dispersion of MWCNTs. At concentrations as high as 9 wt.%, MWCNTs were dispersed uniformly through the polymer matrix, which presented a major improvement over prior techniques. The dispersion procedure was optimized via extended experimentation, which is discussed in detail.
From commodity polymers to functional polymers.
Xiang, Tao; Wang, Ling-Ren; Ma, Lang; Han, Zhi-Yuan; Wang, Rui; Cheng, Chong; Xia, Yi; Qin, Hui; Zhao, Chang-Sheng
2014-04-08
Functional polymers bear specified chemical groups, and have specified physical, chemical, biological, pharmacological, or other uses. To adjust the properties while keeping material usage low, a method for direct synthesis of functional polymers is indispensable. Here we show that various functional polymers can be synthesized by in situ cross-linked polymerization/copolymerization. We demonstrate that the polymers synthesized by the facile method using different functional monomers own outstanding pH-sensitivity and pH-reversibility, antifouling property, antibacterial, and anticoagulant property. Our study opens a route for the functionalization of commodity polymers, which lead to important advances in polymeric materials applications.
Theoretical Research Progress in High-Velocity/Hypervelocity Impact on Semi-Infinite Targets
Directory of Open Access Journals (Sweden)
Yunhou Sun
2015-01-01
Full Text Available With the hypervelocity kinetic weapon and hypersonic cruise missiles research projects being carried out, the damage mechanism for high-velocity/hypervelocity projectile impact on semi-infinite targets has become the research keystone in impact dynamics. Theoretical research progress in high-velocity/hypervelocity impact on semi-infinite targets was reviewed in this paper. The evaluation methods for critical velocity of high-velocity and hypervelocity impact were summarized. The crater shape, crater scaling laws and empirical formulae, and simplified analysis models of crater parameters for spherical projectiles impact on semi-infinite targets were reviewed, so were the long rod penetration state differentiation, penetration depth calculation models for the semifluid, and deformed long rod projectiles. Finally, some research proposals were given for further study.
Monte Carlo method for critical systems in infinite volume: The planar Ising model.
Herdeiro, Victor; Doyon, Benjamin
2016-10-01
In this paper we propose a Monte Carlo method for generating finite-domain marginals of critical distributions of statistical models in infinite volume. The algorithm corrects the problem of the long-range effects of boundaries associated to generating critical distributions on finite lattices. It uses the advantage of scale invariance combined with ideas of the renormalization group in order to construct a type of "holographic" boundary condition that encodes the presence of an infinite volume beyond it. We check the quality of the distribution obtained in the case of the planar Ising model by comparing various observables with their infinite-plane prediction. We accurately reproduce planar two-, three-, and four-point of spin and energy operators. We also define a lattice stress-energy tensor, and numerically obtain the associated conformal Ward identities and the Ising central charge.
Limit Laws and Recurrence for the Planar Lorentz Process with Infinite Horizon
Szász, D
2006-01-01
As Bleher observed the free flight vector of the planar, infinite horizon, periodic Lorentz process $\\{S_n | n=0, 1, 2, \\dots \\}$ belongs to the non-standard domain of attraction of the Gaussian law --- actually with the $\\sqrt{n \\log n}$ scaling. Our first aim is to establish his conjecture that, indeed, $\\frac{S_n}{\\sqrt{n \\log n}}$ converges in distribution to the Gaussian law (a Global Limit Theorem). Here the recent method of B\\'alint and Gou\\"ezel, \\cite{BG} helped us to essentially simplify the ideas of our earlier sketchy proof. Moreover, we can also derive a.) the local version of the Global Limit Theorem, b.) the recurrence of the planar, infinite horizon, periodic Lorentz process, and finally c.) the ergodicity of its infinite invariant measure.
On the tensionless limit of bosonic strings, infinite symmetries and higher spins
Energy Technology Data Exchange (ETDEWEB)
Bonelli, Giulio E-mail: gbonelli@ulb.ac.be
2003-10-06
In the tensionless limit of string theory on flat background all the massive tower of states gets squeezed to a common zero mass level and the free theory is described by an infinite amount of massless free fields with arbitrary integer high spin. We notice that in this situation the very notion of critical dimension gets lost, the apparency of infinite global symmetries takes place, and the closed tensionless string can be realized as a constrained subsystem of the open one in a natural way. Moreover, we study the tensionless limit of the Witten's cubic sting field theory and find that the theory in such a limit can be represented as an infinite set of free arbitrary higher spin excitations plus an interacting sector involving their zero-modes only.
Band to Mott transition in the infinite dimensional Holstein model
Hague, J P
2001-01-01
down at intermediate couplings in the limit of low phonon frequency where it is supposed to be most applicable. By examining the effective hopping and renormalized phonon frequency, I suggest an intuitive explanation for the breakdown of Migdal-Eliashberg theory. For completeness, a description of the breakdown of Migdal's theorem in the limit of high phonon frequency is considered via the Lang-Firsov canonical transformation. The Holstein model can be seen as providing an interpolation scheme between Hubbard-like and Falicov-Kimball like behaviour and it may therefore help elucidate the nature of the transition between band and Mott states. I describe a number of approximations to the self-energy. By comparing these with results from the exact solution in various limits, I find that a second order iterated perturbation scheme may be capable of describing the intermediate behaviour. Application of this method reveals a strongly renormalized hybrid behaviour between band and miniature-Mott states, with unusual...
Antonella Del Rosso
2016-01-01
Twenty years of designing, building and testing a number of innovative technologies, with the strong belief that the endeavour would lead to a historic breakthrough. The Bulletin publishes an abstract of the Courier’s interview with Barry Barish, one of the founding fathers of LIGO. The plots show the signals of gravitational waves detected by the twin LIGO observatories at Livingston, Louisiana, and Hanford, Washington. (Image: Caltech/MIT/LIGO Lab) On 11 February, the Laser Interferometer Gravitational-Wave Observatory (LIGO) and Virgo collaborations published a historic paper in which they showed a gravitational signal emitted by the merger of two black holes. These results come after 20 years of hard work by a large collaboration of scientists operating the two LIGO observatories in the US. Barry Barish, Linde Professor of Physics, Emeritus at the California Institute of Technology and former Director of the Global Design Effort for the Internat...
Conjugated Polymers as Actuators: Modes of Actuation
DEFF Research Database (Denmark)
Skaarup, Steen
2004-01-01
The physical and chemical properties of conjugated polymers often depend very strongly on the degree of doping with anions or cations. The movement of ions in and out of the polymer matrix as it is redox cycled is also accompanied by mechanical changes. Both the volume and the stiffness can exhibit...... significant differences between the oxidized and reduced states. These effects form the basis of the use of conjugated polymers as actuators (or “artificial muscles”) controllable by a small (1-10 V) voltage. Three basic modes of actuation (bending, linear extension and stiffness change) have been proposed...
Conjugated polymers as actuators: modes of actuation
DEFF Research Database (Denmark)
Skaarup, Steen
2007-01-01
The physical and chemical properties of conjugated polymers often depend very strongly on the degree of doping with anions or cations. The movement of ions in and out of the polymer matrix as it is redox cycled is also accompanied by mechanical changes. Both the volume and the stiffness can exhibit...... significant differences between the oxidized and reduced states. These effects form the basis of the use of conjugated polymers as actuators (or “artificial muscles”) controllable by a small (1-10 V) voltage. Three basic modes of actuation (bending, linear extension and stiffness change) have been proposed...
Ablation of polymers by ultraviolet pulsed laser
International Nuclear Information System (INIS)
Brezini, A.; Benharrats, N.
1993-08-01
The surface modifications of different polymers treated by far UV-Excimer laser (λ = 193mn, 248, 308nm) are analysed by X-Ray Photoelectrons Spectroscopy. The main feature observed depends strongly on the absorption coefficients. For the high absorbing polymers such (PVC, PS, PI,...) the mechanism of the UV-Excimer Laser interaction appears to be governed by an ablative photodecomposition process (APD) with an APD threshold. In the other limit, i.e. low absorbing polymer the interaction leads to a photothermal process. (author). 51 refs, 24 figs, 7 tabs
Wilson, Thomas S.; Bearinger, Jane P.
2015-06-09
New shape memory polymer compositions, methods for synthesizing new shape memory polymers, and apparatus comprising an actuator and a shape memory polymer wherein the shape memory polymer comprises at least a portion of the actuator. A shape memory polymer comprising a polymer composition which physically forms a network structure wherein the polymer composition has shape-memory behavior and can be formed into a permanent primary shape, re-formed into a stable secondary shape, and controllably actuated to recover the permanent primary shape. Polymers have optimal aliphatic network structures due to minimization of dangling chains by using monomers that are symmetrical and that have matching amine and hydroxyl groups providing polymers and polymer foams with clarity, tight (narrow temperature range) single transitions, and high shape recovery and recovery force that are especially useful for implanting in the human body.
Do massive compact objects without event horizon exist in infinite derivative gravity?
Koshelev, Alexey S.; Mazumdar, Anupam
2017-10-01
Einstein's general theory of relativity is plagued by cosmological and black-hole type singularities Recently, it has been shown that infinite derivative, ghost free, gravity can yield nonsingular cosmological and mini-black hole solutions. In particular, the theory possesses a mass-gap determined by the scale of new physics. This paper provides a plausible argument, not a no-go theorem, based on the Area-law of gravitational entropy that within infinite derivative, ghost free, gravity nonsingular compact objects in the static limit need not have horizons.
Calculation of the local electric field for an infinite array of conducting nanosized objects
International Nuclear Information System (INIS)
Lim, Mikyoung; Kim, Dohyung; Kim, Sang Youl; Bouree, Jean-Eric
2007-01-01
The electric field for an infinite array of conducting nanosized objects in two-dimensional space has been calculated. The mirror symmetry for this physical problem has been introduced. By taking into account this symmetry, we transform the original problem into an infinite two-dimensional array of nanosized objects with the same solution. The electric field equation of the model has been successfully constructed using a single-layer potential of the periodic Green function. The electric field operator has been introduced. This mathematical approach yields a solution for determining the optimum structure of nanosized electronic devices such as carbon nanotube-based field emitters
One-loop β-function for an infinite-parameter family of gauge theories
Krasnov, Kirill
2015-03-01
We continue to study an infinite-parametric family of gauge theories with an arbitrary function of the self-dual part of the field strength as the Lagrangian. The arising one-loop divergences are computed using the background field method. We show that they can all be absorbed by a local redefinition of the gauge field, as well as multiplicative renormalisations of the couplings. Thus, this family of theories is one-loop renormalisable. The infinite set of β-functions for the couplings is compactly stored in a renormalisation group flow for a single function of the curvature. The flow is obtained explicitly.
The Hintermann-Merlini-Baxter-Wu and the infinite-coupling-limit Ashkin-Teller models
Energy Technology Data Exchange (ETDEWEB)
Huang Yuan, E-mail: huangy22@mail.ustc.edu.cn [Hefei National Laboratory for Physical Sciences at Microscale and Department of Modern Physics, University of Science and Technology of China, Hefei, Anhui 230026 (China); Deng Youjin, E-mail: yjdeng@ustc.edu.cn [Hefei National Laboratory for Physical Sciences at Microscale and Department of Modern Physics, University of Science and Technology of China, Hefei, Anhui 230026 (China); Jacobsen, Jesper Lykke, E-mail: jacobsen@lpt.ens.fr [Laboratoire de Physique Theorique, Ecole Normale Superieure, 24 rue Lhomond, 75231 Paris (France); Universite Pierre et Marie Curie, 4 place Jussieu, 75252 Paris (France); Salas, Jesus, E-mail: jsalas@math.uc3m.es [Grupo de Modelizacion, Simulacion Numerica y Matematica Industrial, Universidad Carlos III de Madrid, Avda. de la Universidad 30, 28911 Leganes (Spain); Grupo de Teorias de Campos y Fisica Estadistica, Instituto Gregorio Millan, Universidad Carlos III de Madrid, Unidad asociada al IEM-CSIC, Madrid (Spain)
2013-03-11
We show how the Hintermann-Merlini-Baxter-Wu model (which is a generalization of the well-known Baxter-Wu model to a general Eulerian triangulation) can be mapped onto a particular infinite-coupling-limit of the Ashkin-Teller model. We work out some mappings among these models, also including the standard and mixed Ashkin-Teller models. Finally, we compute the phase diagram of the infinite-coupling-limit Ashkin-Teller model on the square, triangular, hexagonal, and kagome lattices.
Atmospheric stability-dependent infinite wind-farm models and the wake-decay coefficient
Peña, Alfredo; Rathmann, Ole
2014-01-01
We extend the infinite wind-farm boundary-layer (IWFBL) model of Frandsen to take into account atmospheric static stability effects. This extended model is compared with the IWFBL model of Emeis and to the Park wake model used inWind Atlas Analysis and Application Program (WAsP), which is computed for an infinite wind farm. The models show similar behavior for the wind-speed reduction when accounting for a number of surface roughness lengths, turbine to turbine separations and wind speeds und...
Finding Limit Cycles in self-excited oscillators with infinite-series damping functions
Das, Debapriya; Banerjee, Dhruba; Bhattacharjee, Jayanta K.
2015-03-01
In this paper we present a simple method for finding the location of limit cycles of self excited oscillators whose damping functions can be represented by some infinite convergent series. We have used standard results of first-order perturbation theory to arrive at amplitude equations. The approach has been kept pedagogic by first working out the cases of finite polynomials using elementary algebra. Then the method has been extended to various infinite polynomials, where the fixed points of the corresponding amplitude equations cannot be found out. Hopf bifurcations for systems with nonlinear powers in velocities have also been discussed.
DEFF Research Database (Denmark)
Shen, Hong; Yang, Lili; Sun, Xiaofeng
2016-01-01
This study proposes to install a novel active power filter (IF-APF) mimicking the character of an infinitely long transmission line at the end of a radial feeder. The proposed IF-APF eliminates the reflected wave and realises the background harmonic voltage suppression capability throughout...... the feeder by mimicking the characteristic of an infinite feeder. The proposed IF-APF shows a better harmonic damping performance than the traditional resistive active power filter (R-APF). Moreover, the proposed IF-APF achieves a better harmonic suppression performance than the traditional R-APF, especially...
Identification of Functional Clusters in the Striatum Using Infinite Relational Modeling
DEFF Research Database (Denmark)
Andersen, Kasper Winther; Madsen, Kristoffer Hougaard; Siebner, Hartwig
2011-01-01
In this paper we investigate how the Infinite Relational Model can be used to infer functional groupings of the human striatum using resting state fMRI data from 30 healthy subjects. The Infinite Relational Model is a non-parametric Bayesian method for infering community structure in complex...... are involved in the same neural computations. The reproducibility of the groupings found are assessed by calculating mutual information between half splits of the subject sample for various hyperparameter values. Finally, the model's ability to predict unobserved links is assessed by randomly treating links...
Second order PDE’s in finite and infinite dimension a probabilistic approach
2001-01-01
This book deals with the study of a class of stochastic differential systems having unbounded coefficients, both in finite and in infinite dimension. The attention is focused on the regularity properties of the solutions and on the smoothing effect of the corresponding transition semigroups in the space of bounded and uniformly continuous functions. The application is to the study of the associated Kolmogorov equations, the large time behaviour of the solutions and some stochastic optimal control problems. The techniques are from the theory of diffusion processes and from stochastic analysis, but also from the theory of partial differential equations with finitely and infinitely many variables.
Calculating infinite-medium {alpha}-eigenvalue spectra with a transition rate matrix method
Energy Technology Data Exchange (ETDEWEB)
Betzler, B. R. [Department of Nuclear Engineering and Radiological Sciences, University of Michigan, 2355 Bonisteel Boulevard, Ann Arbor, MI 48109 (United States); Kiedrowski, B. C.; Brown, F. B. [X-Computational Physics Division, Monte Carlo Codes Group, Los Alamos National Laboratory, P.O. Box 1663, Los Alamos, NM 87545 (United States); Martin, W. R. [Department of Nuclear Engineering and Radiological Sciences, University of Michigan, 2355 Bonisteel Boulevard, Ann Arbor, MI 48109 (United States)
2013-07-01
The time-dependent behavior of the energy spectrum in neutron transport was investigated with a formulation, based on continuous-time Markov processes, for computing {alpha}-eigenvalues and eigenvectors in an infinite medium. For this, a research Monte Carlo code called TORTE was created and used to estimate elements of a transition rate matrix. TORTE is capable of using both multigroup and continuous-energy nuclear data, and verification was performed. Eigenvalue spectra for infinite homogeneous mixtures were obtained and an eigenfunction expansion was used to investigate transient behavior of the neutron energy spectrum. (authors)
An advance in infinite graph models for the analysis of transportation networks
Directory of Open Access Journals (Sweden)
Cera Martín
2016-12-01
Full Text Available This paper extends to infinite graphs the most general extremal issues, which are problems of determining the maximum number of edges of a graph not containing a given subgraph. It also relates the new results with the corresponding situations for the finite case. In particular, concepts from ‘finite’ graph theory, like the average degree and the extremal number, are generalized and computed for some specific cases. Finally, some applications of infinite graphs to the transportation of dangerous goods are presented; they involve the analysis of networks and percolation thresholds.
Directory of Open Access Journals (Sweden)
Viet-Thanh Pham
2016-01-01
Full Text Available Discovering systems with hidden attractors is a challenging topic which has received considerable interest of the scientific community recently. This work introduces a new chaotic system having hidden chaotic attractors with an infinite number of equilibrium points. We have studied dynamical properties of such special system via equilibrium analysis, bifurcation diagram, and maximal Lyapunov exponents. In order to confirm the system’s chaotic behavior, the findings of topological horseshoes for the system are presented. In addition, the possibility of synchronization of two new chaotic systems with infinite equilibria is investigated by using adaptive control.
Infinite soliton and kink-soliton trains for nonlinear Schrödinger equations
Le Coz, Stefan; Tsai, Tai-Peng
2014-11-01
We look for solutions to general nonlinear Schrödinger equations built upon solitons and kinks. Solitons are localized solitary waves, and kinks are their non-localized counter-parts. We prove the existence of infinite soliton trains, i.e. solutions behaving at large time as the sum of infinitely many solitons. We also show that one can attach a kink at one end of the train. Our proofs proceed by fixed point arguments around the desired profile. We present two approaches leading to different results, one based on a combination of Lp - Lp‧ dispersive estimates and Strichartz estimates, the other based only on Strichartz estimates.
Rare earth niobate coordination polymers
Muniz, Collin N.; Patel, Hiral; Fast, Dylan B.; Rohwer, Lauren E. S.; Reinheimer, Eric W.; Dolgos, Michelle; Graham, Matt W.; Nyman, May
2018-03-01
Rare-earth (RE) coordination polymers are infinitely tailorable to yield luminescent materials for various applications. Here we described the synthesis of a heterometallic rare-earth coordination compound ((CH3)2SO)3(RE)NbO(C2O4)3((CH3)2SO) = dimethylsulfoxide, DMSO, (C2O2= oxalate), (RE=La, Ce, Pr, Nd, Sm, Eu, Gd, Tb). The structure was obtained from single crystal X-ray diffraction of the La analogue. The Nb˭O and DMSO terminal-bonding character guides assembly of an open framework structure with noncentrosymmetric RE-coordination geometry, and large spacing between the RE centers. A second structure was observed by PXRD for the smaller rare earths (Dy, Ho, Er, Yb); this structure has not yet been determined. The materials were further characterized using FTIR, and photoluminescence measurements. Characteristic excitation and emission transitions were observed for RE = Nd, Sm, Eu, and Tb. Quantum yield (QY) measurements were performed by exciting Eu and Tb analoges at 394 nm (QY 66%) and 464 nm (QY 71%) for Eu; and 370 nm (QY=40%) for Tb. We attribute the high QY and bright luminescence to two main structure-function properties of the system; namely the absence of water in the structure, and absence of concentration quenching.
Strong curvature effects in Neumann wave problems
International Nuclear Information System (INIS)
Willatzen, M.; Pors, A.; Gravesen, J.
2012-01-01
Waveguide phenomena play a major role in basic sciences and engineering. The Helmholtz equation is the governing equation for the electric field in electromagnetic wave propagation and the acoustic pressure in the study of pressure dynamics. The Schrödinger equation simplifies to the Helmholtz equation for a quantum-mechanical particle confined by infinite barriers relevant in semiconductor physics. With this in mind and the interest to tailor waveguides towards a desired spectrum and modal pattern structure in classical structures and nanostructures, it becomes increasingly important to understand the influence of curvature effects in waveguides. In this work, we demonstrate analytically strong curvature effects for the eigenvalue spectrum of the Helmholtz equation with Neumann boundary conditions in cases where the waveguide cross section is a circular sector. It is found that the linear-in-curvature contribution originates from parity symmetry breaking of eigenstates in circular-sector tori and hence vanishes in a torus with a complete circular cross section. The same strong curvature effect is not present in waveguides subject to Dirichlet boundary conditions where curvature contributions contribute to second-order in the curvature only. We demonstrate this finding by considering wave propagation in a circular-sector torus corresponding to Neumann and Dirichlet boundary conditions, respectively. Results for relative eigenfrequency shifts and modes are determined and compared with three-dimensional finite element method results. Good agreement is found between the present analytical method using a combination of differential geometry with perturbation theory and finite element results for a large range of curvature ratios.
Glassy states in fermionic systems with strong disorder and interactions
Schwab, David J.; Chakravarty, Sudip
2009-03-01
We study the competition between interactions and disorder in two dimensions. Whereas a noninteracting system is always Anderson localized by disorder in two dimensions, a pure system can develop a Mott gap for sufficiently strong interactions. Within a simple model, with short-ranged repulsive interactions, we show that, even in the limit of strong interaction, the Mott gap is completely washed out by disorder for an infinite system for dimensions D≤2 , leading to a glassy state. Moreover, the Mott insulator cannot maintain a broken symmetry in the presence of disorder. We then show that the probability of a nonzero gap as a function of system size falls onto a universal curve, reflecting the glassy dynamics. An analytic calculation is also presented in one dimension that provides further insight into the nature of slow dynamics.
Polymer nanocomposites: polymer and particle dynamics
Kim, Daniel
2012-01-01
Polymer nanocomposites containing nanoparticles smaller than the random coil size of their host polymer chains are known to exhibit unique properties, such as lower viscosity and glass transition temperature relative to the neat polymer melt. It has been hypothesized that these unusual properties result from fast diffusion of the nanostructures in the host polymer, which facilitates polymer chain relaxation by constraint release and other processes. In this study, the effects of addition of sterically stabilized inorganic nanoparticles to entangled cis-1,4-polyisoprene and polydimethylsiloxane on the overall rheology of nanocomposites are discussed. In addition, insights about the relaxation of the host polymer chains and transport properties of nanoparticles in entangled polymer nanocomposites are presented. The nanoparticles are found to act as effective plasticizers for their entangled linear hosts, and below a critical, chemistry and molecular-weight dependent particle volume fraction, lead to reduced viscosity, glass transition temperature, number of entanglements, and polymer relaxation time. We also find that the particle motions in the polymer host are hyperdiffusive and at the nanoparticle length scale, the polymer host acts like a simple, ideal fluid and the composites\\' viscosity rises with increasing particle concentration. © 2012 The Royal Society of Chemistry.
Wickens, F
Our friend and colleague John Strong was cruelly taken from us by a brain tumour on Monday 31st July, a few days before his 65th birthday John started his career working with a group from Westfield College, under the leadership of Ted Bellamy. He obtained his PhD and spent the early part of his career on experiments at Rutherford Appleton Laboratory (RAL), but after the early 1970s his research was focussed on experiments in CERN. Over the years he made a number of notable contributions to experiments in CERN: The Omega spectrometer adopted a system John had originally developed for experiments at RAL using vidicon cameras to record the sparks in the spark chambers; He contributed to the success of NA1 and NA7, where he became heavily involved in the electronic trigger systems; He was responsible for the second level trigger system for the ALEPH detector and spent five years leading a team that designed and built the system, which ran for twelve years with only minor interventions. Following ALEPH he tur...
Stirring Strongly Coupled Plasma
Fadafan, Kazem Bitaghsir; Rajagopal, Krishna; Wiedemann, Urs Achim
2009-01-01
We determine the energy it takes to move a test quark along a circle of radius L with angular frequency w through the strongly coupled plasma of N=4 supersymmetric Yang-Mills (SYM) theory. We find that for most values of L and w the energy deposited by stirring the plasma in this way is governed either by the drag force acting on a test quark moving through the plasma in a straight line with speed v=Lw or by the energy radiated by a quark in circular motion in the absence of any plasma, whichever is larger. There is a continuous crossover from the drag-dominated regime to the radiation-dominated regime. In the crossover regime we find evidence for significant destructive interference between energy loss due to drag and that due to radiation as if in vacuum. The rotating quark thus serves as a model system in which the relative strength of, and interplay between, two different mechanisms of parton energy loss is accessible via a controlled classical gravity calculation. We close by speculating on the implicati...
Strong-interaction nonuniversality
International Nuclear Information System (INIS)
Volkas, R.R.; Foot, R.; He, X.; Joshi, G.C.
1989-01-01
The universal QCD color theory is extended to an SU(3) 1 direct product SU(3) 2 direct product SU(3) 3 gauge theory, where quarks of the ith generation transform as triplets under SU(3)/sub i/ and singlets under the other two factors. The usual color group is then identified with the diagonal subgroup, which remains exact after symmetry breaking. The gauge bosons associated with the 16 broken generators then form two massive octets under ordinary color. The interactions between quarks and these heavy gluonlike particles are explicitly nonuniversal and thus an exploration of their physical implications allows us to shed light on the fundamental issue of strong-interaction universality. Nonuniversality and weak flavor mixing are shown to generate heavy-gluon-induced flavor-changing neutral currents. The phenomenology of these processes is studied, as they provide the major experimental constraint on the extended theory. Three symmetry-breaking scenarios are presented. The first has color breaking occurring at the weak scale, while the second and third divorce the two scales. The third model has the interesting feature of radiatively induced off-diagonal Kobayashi-Maskawa matrix elements
Replica field theory for a polymer in random media
International Nuclear Information System (INIS)
Goldschmidt, Yadin Y.
2000-01-01
In this paper we revisit the problem of a (non-self-avoiding) polymer chain in a random medium which was previously investigated by Edwards and Muthukumar (EM) [J. Chem. Phys. 89, 2435 (1988)]. As noticed by Cates and Ball (CB) [J. Phys. (France) 49, 2009 (1988)] there is a discrepancy between the predictions of the replica calculation of EM and the expectation that in an infinite medium the quenched and annealed results should coincide (for a chain that is free to move) and a long polymer should always collapse. CB argued that only in a finite volume one might see a ''localization transition'' (or crossover) from a stretched to a collapsed chain in three spatial dimensions. Here we carry out the replica calculation in the presence of an additional confining harmonic potential that mimics the effect of a finite volume. Using a variational scheme with five variational parameters we derive analytically for d -1/(4-d) ∼(g ln V) -1/(4-d) , where R is the radius of gyration, g is the strength of the disorder, μ is the spring constant associated with the confining potential, and V is the associated effective volume of the system. Thus the EM result is recovered with their constant replaced by ln V as argued by CB. We see that in the strict infinite volume limit the polymer always collapses, but for finite volume a transition from a stretched to a collapsed form might be observed as a function of the strength of the disorder. For d V ' ∼exp(g 2/(2-d) L (4-d)/(2-d) ) the annealed results are recovered and R∼(Lg) 1/(d-2) , where L is the length of the polymer. Hence the polymer also collapses in the large L limit. The one-step replica symmetry breaking solution is crucial for obtaining the above results. (c) 2000 The American Physical Society
Ding, Wenxin; Žitko, Rok; Shastry, B. Sriram
2017-09-01
Using two approaches to strongly correlated systems, the extremely correlated Fermi liquid theory and the dynamical mean field theory, we compute the transverse transport coefficients, namely, the Hall constants RH and Hall angles θH, and the longitudinal and transverse optical response of the U =∞ Hubbard model in the limit of infinite dimensions. We focus on two successive low-temperature regimes, the Gutzwiller-correlated Fermi liquid (GCFL) and the Gutzwiller-correlated strange metal (GCSM). We find that the Hall angle cotθH is proportional to T2 in the GCFL regime, while upon warming into the GCSM regime it first passes through a downward bend and then continues as T2. Equivalently, RH is weakly temperature dependent in the GCFL regime, but becomes strongly temperature dependent in the GCSM regime. Drude peaks are found for both the longitudinal optical conductivity σx x(ω ) and the optical Hall angles tanθH(ω ) below certain characteristic energy scales. By comparing the relaxation rates extracted from fitting to the Drude formula, we find that in the GCFL regime there is a single relaxation rate controlling both longitudinal and transverse transport, while in the GCSM regime two different relaxation rates emerge. We trace the origin of this behavior to the dynamical particle-hole asymmetry of the Dyson self-energy, arguably a generic feature of doped Mott insulators.
Strongly correlated one-dimensional Bose–Fermi quantum mixtures: symmetry and correlations
Decamp, Jean; Jünemann, Johannes; Albert, Mathias; Rizzi, Matteo; Minguzzi, Anna; Vignolo, Patrizia
2017-12-01
We consider multi-component quantum mixtures (bosonic, fermionic, or mixed) with strongly repulsive contact interactions in a one-dimensional harmonic trap. In the limit of infinitely strong repulsion and zero temperature, using the class-sum method, we study the symmetries of the spatial wave function of the mixture. We find that the ground state of the system has the most symmetric spatial wave function allowed by the type of mixture. This provides an example of the generalized Lieb–Mattis theorem. Furthermore, we show that the symmetry properties of the mixture are embedded in the large-momentum tails of the momentum distribution, which we evaluate both at infinite repulsion by an exact solution and at finite interactions using a numerical DMRG approach. This implies that an experimental measurement of the Tan’s contact would allow to unambiguously determine the symmetry of any kind of multi-component mixture.
Nematic–isotropic transition in polydisperse systems of infinitely thin hard platelets
Bates, M.A.; Frenkel, D.
1999-01-01
We study the phase behavior of model colloidal systems composed of infinitely thin hard platelets, with polydispersity in the size of the particles. Semi-grand Gibbs ensemble simulations are used to study the coexisting nematic and isotropic phases for a range of systems with varying polydispersity.
Variable Input: What Sarah Reveals about Nonagreeing "Don't" and Theories of Root Infinitives
Miller, Karen
2013-01-01
Two recent proposals link the use of nonagreeing "don't" to the Root Infinitive (RI) Stage. Guasti & Rizzi (2002) argue for a misset parameter involving how agreement is spelled out. Schütze (2010) proposes that Infl is underspecified in child language and that "do" surfaces to support the contracted clitic/affix…
DEFF Research Database (Denmark)
Basse-O'Connor, Andreas; Rosiński, Jan
2013-01-01
We characterize the finite variation property for stationary increment mixed moving averages driven by infinitely divisible random measures. Such processes include fractional and moving average processes driven by Levy processes, and also their mixtures. We establish two types of zero-one laws...
On cyclic orthogonal double covers of circulant graphs by special infinite graphs
Directory of Open Access Journals (Sweden)
R. El-Shanawany
2017-12-01
Full Text Available In this article, a technique to construct cyclic orthogonal double covers (CODCs of regular circulant graphs by certain infinite graph classes such as complete bipartite and tripartite graphs and disjoint union of butterfly and K1,2n−10 is introduced.
Infinite stochastic acceleration of charged particles from non-relativistic initial energies
International Nuclear Information System (INIS)
Buts, V.A.; Manujlenko, O.V.; Turkin, Yu.A.
1997-01-01
Stochastic charged particle acceleration by electro-magnetic field due to overlapping of non-linear cyclotron resonances is considered. It was shown that non-relativistic charged particles are involved in infinitive stochastic acceleration regime. This effect can be used for stochastic acceleration or for plasma heating by regular electro-magnetic fields
A Kernel Representation of Dirac Structures for Infinite-dimensional Systems
Iftime, Orest; Roman, M.; Sandovici, A.
2014-01-01
Dirac structures are used as the underlying structure to mathematically formalize port-Hamiltonian systems. This note approaches the Dirac structures for infinite-dimensional systems using the theory of linear relations on Hilbert spaces. First, a kernel representation for a Dirac structure is
Reddy, P.V.; Engwerda, J.C.
2011-01-01
In this article we derive necessary and sufficient conditions for the existence of Pareto optimal solutions for infinite horizon cooperative differential games. We consider games defined by non autonomous and discounted autonomous systems. The obtained results are used to analyze the regular
A Luenberger observer for an infinite dimensional bilinear system: a UV disinfection example
Vries, D; Keesman, K.J.; Zwart, Heiko J.; Gomes da Silva Jr, J.M.; Malabre, M.; Bazanella, A.S.
Inspired by the UV disinfection process in food and water treatment industry, we design a Luenberger observer which works at the boundary of the infinite dimensional bilinear system. Existence of a solution, stability and some observer design issues are shown. Simulations of a disinfection process
Directory of Open Access Journals (Sweden)
Massimiliano Ferrara
2016-01-01
Full Text Available This paper discusses the existence of infinitely many periodic solutions for a semilinear fourth-order impulsive differential inclusion with a perturbed nonlinearity and two parameters. The approach is based on a critical point theorem for nonsmooth functionals.
Analysis of Diffusion Process in an Infinite Core | Adeniji | Journal of ...
African Journals Online (AJOL)
Mathematical and graphical illustrations of unsteady state diffusion in infinite porous core are analysed here for proper reservoir characterization. Since petroleum engineers are always advocating for some types of mathematical theory necessary to the application of laboratory data to field problems, the solution to one ...
K-theory for certain extension algebras of purely infinite simple C ...
Indian Academy of Sciences (India)
London/Singapore/Hong Kong/Bangalore: World Scientific) (2001). [6] Lin H, On the classification of C∗. -algebras of real rank zero with zero K1, J. Operator. Theory 35 (1996) 147–178. [7] Lin H, A classification theorem for infinite Toeplitz algebras, in Operator algebras and operator theory (Shanghai) (1997), vol. 228 of ...
The Schwartz Space: Tools for Quantum Mechanics and Infinite Dimensional Analysis
Directory of Open Access Journals (Sweden)
Jeremy Becnel
2015-06-01
Full Text Available An account of the Schwartz space of rapidly decreasing functions as a topological vector space with additional special structures is presented in a manner that provides all the essential background ideas for some areas of quantum mechanics along with infinite-dimensional distribution theory.
Analysis of Markov-modulated infinite-server queues in the central-limit regime
J.G. Blom (Joke); K. de Turck (Koen); M.R.H. Mandjes (Michel)
2014-01-01
textabstractThis paper focuses on an infinite-server queue modulated by an independently evolving finite-state Markovian background process, with transition rate matrix $Q\\equiv(q_{ij})_{i,j=1}^d$. {Both arrival rates and service rates are depending on the state of the background
Analysis of Markov-modulated infinite-server queues in the central-limit regime
J.G. Blom (Joke); K. de Turck (Koen); M.R.H. Mandjes (Michel)
2014-01-01
textabstractThis paper focuses on an infinite-server queue modulated by an independently evolving finite-state Markovian background process, with transition rate matrix $Q\\equiv(q_{ij})_{i,j=1}^d$. Both arrival rates and service rates are depending on the state of the background process. The
Analysis of Markov-modulated infinite-server queues in the central-limit regime
J.G. Blom (Joke); K. de Turck (Koen); M.R.H. Mandjes (Michel)
2015-01-01
textabstractThis paper focuses on an infinite-server queue modulated by an independently evolving finite-state Markovian background process, with transition rate matrix $Q\\equiv(q_{ij})_{i,j=1}^d$. {Both arrival rates and service rates are depending on the state of the background
The influence of hyper-parameters in the infinite relational model
DEFF Research Database (Denmark)
Albers, Kristoffer Jon; Mørup, Morten; Schmidt, Mikkel Nørgaard
2016-01-01
The infinite relational model (IRM) is a Bayesian nonparametric stochastic block model; a generative model for random networks parameterized for uni-partite undirected networks by a partition of the node set and symmetric matrix of inter-partion link probabilities. The prior for the node clusters...
An Introduction to Differentials Based on Hyperreal Numbers and Infinite Microscopes
Henry, Valerie
2010-01-01
In this article, we propose to introduce the differential of a function through a non-classical way, lying on hyperreals and infinite microscopes. This approach is based on the developments of nonstandard analysis, wants to be more intuitive than the classical one and tries to emphasize the functional and geometric aspects of the differential. In…
Pure infiniteness and ideal structure of C*-algebras associated to Fell bundles
DEFF Research Database (Denmark)
Kwasniewski, Bartosz; Szymanski, Wojciech
2017-01-01
We investigate structural properties of the reduced cross-sectional algebra C^*_r(B) of a Fell bundle B over a discrete group G. Conditions allowing one to determine the ideal structure of C^*_r(B) are studied. Notions of aperiodicity, paradoxicality and B-infiniteness for the Fell bundle B...
Expected shortfall estimation for apparently infinite-mean models of operational risk
Cirillo, P.; Taleb, Nassim Nicholas
2016-01-01
Statistical analyses on actual data depict operational risk as an extremely heavy-tailed phenomenon, able to generate losses so extreme as to suggest the use of infinite-mean models. But no loss can actually destroy more than the entire value of a bank or of a company, and this upper bound should be
Renner, R; Cirac, J I
2009-03-20
We show that the quantum de Finetti theorem holds for states on infinite-dimensional systems, provided they satisfy certain experimentally verifiable conditions. This result can be applied to prove the security of quantum key distribution based on weak coherent states or other continuous variable states against general attacks.
Energy Technology Data Exchange (ETDEWEB)
Cui Jing [College of Information Science and Technology, Donghua University, 2999 North Renmin Rd, Songjiang, Shanghai 201620 (China); Yan Litan, E-mail: jcui123@126.com, E-mail: litanyan@hotmail.com [Department of Mathematics, College of Science, Donghua University, 2999 North Renmin Rd, Songjiang, Shanghai 201620 (China)
2011-08-19
This paper is concerned with the existence of mild solutions for a class of fractional neutral stochastic integro-differential equations with infinite delay in Hilbert spaces. A sufficient condition for the existence is obtained under non-Lipschitz conditions by means of Sadovskii's fixed point theorem. An example is given to illustrate the theory.
Directory of Open Access Journals (Sweden)
Meili Li
2015-01-01
Full Text Available The approximate controllability of semilinear neutral stochastic integrodifferential inclusions with infinite delay in an abstract space is studied. Sufficient conditions are established for the approximate controllability. The results are obtained by using the theory of analytic resolvent operator, the fractional power theory, and the theorem of nonlinear alternative for Kakutani maps. Finally, an example is provided to illustrate the theory.
Energy Technology Data Exchange (ETDEWEB)
Chang, Y.-K. [Department of Mathematics, Lanzhou Jiaotong University, Lanzhou, Gansu 730070 (China)], E-mail: lzchangyk@163.com; Anguraj, A. [Department of Mathematics, PSG College of Arts and Science, Coimbatore 641 014, Tamil Nadu (India)], E-mail: angurajpsg@yahoo.com; Mallika Arjunan, M. [Department of Mathematics, PSG College of Arts and Science, Coimbatore 641 014, Tamil Nadu (India)], E-mail: arjunphd07@yahoo.co.in
2009-02-28
In this work, we establish a sufficient condition for the controllability of the first-order impulsive neutral functional differential inclusions with infinite delay in Banach spaces. The results are obtained by using the Dhage's fixed point theorem.
Controllability of fractional order integro-differential inclusions with infinite delay
Directory of Open Access Journals (Sweden)
Khalida Aissani
2014-11-01
Full Text Available This paper concerns for controllability of fractional order integro-differential inclusions with infinite delay in Banach spaces. A theorem about the existence of mild solutions to the controllability of fractional order integro-differential inclusions is obtained based on Dhage fixed point theorem. An example is given to illustrate the existence result.
Directory of Open Access Journals (Sweden)
Selma Baghli
2009-02-01
Full Text Available In this paper sufficient conditions are given ensuring the controllability of mild solutions defined on a bounded interval for two classes of first order semilinear functional and neutral functional differential equations involving evolution operators when the delay is infinite using the nonlinear alternative of Leray-Schauder type.
Directory of Open Access Journals (Sweden)
Mouffak Benchohra
2008-05-01
Full Text Available This article shows sufficient conditions for the existence of mild solutions, on the positive half-line, for two classes of first-order functional and neutral functional perturbed differential evolution equations with infinite delay. Our main tools are: the nonlinear alternative proved by Avramescu for the sum of contractions and completely continuous maps in Frechet spaces, and the semigroup theory.
Masiero, Federica; Richou, Adrien
2014-09-01
We study Hamilton Jacobi Bellman equations in an infinite dimensional Hilbert space, with Lipschitz coefficients, where the Hamiltonian has superquadratic growth with respect to the derivative of the value function, and the final condition is not bounded. This allows to study stochastic optimal control problems for suitable controlled state equations with unbounded control processes. The results are applied to a controlled wave equation.
Creating Visual Aids with Graphic Organisers on an Infinite Canvas--The Impact on the Presenter
Casteleyn, Jordi; Mottart, Andre; Valcke, Martin
2015-01-01
Instead of the traditional set of slides, the visual aids of a presentation can now be graphic organisers (concept maps, knowledge maps, mind maps) on an infinite canvas. Constructing graphic organisers has a beneficial impact on learning, but this topic has not been studied in the context of giving a presentation. The present study examined this…
Remark on the gravitational field produced by an infinite straight string
International Nuclear Information System (INIS)
Francisco, G.; Matsas, G.E.A.
1989-01-01
The results predicted by Newtonian gravity and general relativity are compared regarding the field produced by an infinite gauge string with constant density λ. A simple gedankenexperiment is suggested to stress the remarkable differences between these two theories. The existence of the usual Newtonian limit is discussed in this case
The Analysis of Corporate Bond Valuation under an Infinite Dimensional Compound Poisson Framework
Directory of Open Access Journals (Sweden)
Sheng Fan
2014-01-01
Full Text Available This paper analyzes the firm bond valuation and credit spread with an endogenous model for the pure default and callable default corporate bond. Regarding the stochastic instantaneous forward rates and the firm value as an infinite dimensional Poisson process, we provide some analytical results for the embedded American options and firm bond valuations.
analysis of pressure variation of fluid in an infinite acting reservoir
African Journals Online (AJOL)
The diffusivity equation was used in the analysis. The work covers the transient state where the reservoir is acting as if it was infinite in size. The finite element technique, using Lagrange quadratic shape elements was employed to carry out the analysis over the cross-section of the reservoir. The analysis was done with the ...
Linear quadratic Gaussian balancing for discrete-time infinite-dimensional linear systems
Opmeer, MR; Curtain, RF
2004-01-01
In this paper, we study the existence of linear quadratic Gaussian (LQG)-balanced realizations for discrete-time infinite-dimensional systems. LQG-balanced realizations are those for which the smallest nonnegative self-adjoint solutions of the control and filter Riccati equations are equal. We show
Uniqueness Conditions for the Infinite-Planning Horizon Open-Loop Linear Quadratic Differential Game
Engwerda, J.C.
2005-01-01
In this note we consider the open-loop Nash linear quadratic differential game with an infinite planning horizon.The performance function is assumed to be indefinite and the underlying system affine.We derive both necessary and sufficient conditions under which this game has a unique Nash
Infinitely-many conservation laws for two (2+1)-dimensional ...
Indian Academy of Sciences (India)
2014-07-01
Jul 1, 2014 ... Abstract. In this paper, a method that can be used to construct the infinitely-many conservation laws with the Lax pair is generalized from the (1+1)-dimensional nonlinear evolution equations. (NLEEs) to the (2+1)-dimensional ones. Besides, we apply that method to the Kadomtsev–. Petviashvili (KP) and ...
Conditions for the absence of infinite renormalization in masses and coupling constants
International Nuclear Information System (INIS)
Terrab, E.S.C.
1985-01-01
A model of scalar, pseudo-scalar and spin 1/2 particle interaction is studied. After reformulation of the problem in function of auxiliary fields, perturbative calculations up to one loop are developed, finding out certain relations among characteristics constants of system, which assure (until the considered order) the absence of infinite renormalization in masses and coupling constants. (M.C.K.) [pt
Edge-born waves in connected arrays: A finite × infinite analytical representation
Neto, A.; Cavallo, D.; Gerini, G.
2011-01-01
Connected arrays constitute one of the most promising options for wideband phased arrays. Like most phased arrays, they are designed using infinite array theory. However, when finiteness is included, edge effects perturb their behavior. These effects are more severe when the arrays are designed to
Infinite dimensional gauge structure of Kaluza-Klein theories II: D>5
International Nuclear Information System (INIS)
Aulakh, C.S.; Sahdev, D.
1985-12-01
We carry out the dimensional reduction of the pure gravity sector of Kaluza Klein theories without making truncations of any sort. This generalizes our previous result for the 5-dimensional case to 4+d(>1) dimensions. The effective 4-dimensional action has the structure of an infinite dimensional gauge theory
Effects of Unsteady Flow Past An Infinite Vertical Plate With Variable ...
African Journals Online (AJOL)
The effects of unsteady flow past an infinite vertical plate with variable temperature and constant mass flux are investigated. Laplace transform technique is used to obtain velocity and concentration fields. The computation of the results indicates that the velocity profiles increase with increase in Grashof numbers, mass ...
Wald Entropy for Ghost-Free, Infinite Derivative Theories of Gravity.
Conroy, Aindriú; Mazumdar, Anupam; Teimouri, Ali
2015-05-22
In this Letter, we demonstrate that the Wald entropy for any spherically symmetric black hole within an infinite derivative theory of gravity that is quadratic in curvature is determined solely by the area law. Thus, the infrared behavior of gravity is captured by the Einstein-Hilbert term, provided that the massless graviton remains the only propagating degree of freedom in the spacetime.
International Nuclear Information System (INIS)
Qian, Denghui; Shi, Zhiyu
2017-01-01
This paper couples the plane wave expansion (PWE) and finite element (FE) methods to calculate the band structures of the semi-infinite beam-like phononic crystals (PCs) with the infinite periodicity in z-direction and finiteness in x–y plane. Explicit matrix formulations are developed for the calculation of band structures. In order to illustrate the applicability and accuracy of the proposed coupled plane wave expansion and finite element (PWE/FE) method to beam-like PCs, several examples are displayed. At first, PWE/FE method is applied to calculate the band structures of the Pb/rubber beam-like PCs with circular and rectangular cross sections, respectively. Then, it is used to calculate the band structures of steel/epoxy and steel/aluminum beam-like PCs with the same geometric parameters. Last, the band structure of the three-component beam-like PC is also calculated by the proposed method. Moreover, all the results calculated by PWE/FE method are compared with those calculated by finite element (FE) method, and the corresponding results are in good agreement. - Highlights: • The concept of the semi-infinite beam-like phononic crystals (PCs) is proposed. • The PWE/FE method is proposed and formulized to calculate the band structures of the semi-infinite beam-like PCs. • The strong applicability and high accuracy of PWE/FE method are verified.
Strange metal from Gutzwiller correlations in infinite dimensions
Ding, Wenxin; Žitko, Rok; Mai, Peizhi; Perepelitsky, Edward; Shastry, B. Sriram
2017-08-01
correlate changes in these with the change in resistivity. This exercise casts valuable light on the nature of charge and spin correlations in the Gutzwiller correlated strange metal regime, which has features in common with the physically relevant strange metal phase seen in strongly correlated matter.
Chen, Yuejie; Wang, Shujing; Wang, Shan; Liu, Chengyu; Su, Ching; Hageman, Michael; Hussain, Munir; Haskell, Roy; Stefanski, Kevin; Qian, Feng
2016-10-01
To identify the key formulation factors controlling the initial drug and polymer dissolution rates from an amorphous solid dispersion (ASD). Ketoconazole (KTZ) ASDs using PVP, PVP-VA, HMPC, or HPMC-AS as polymeric matrix were prepared. For each drug-polymer system, two types of formulations with the same composition were prepared: 1. Spray dried dispersion (SDD) that is homogenous at molecular level, 2. Physical blend of SDD (80% drug loading) and pure polymer (SDD-PB) that is homogenous only at powder level. Flory-Huggins interaction parameters (χ) between KTZ and the four polymers were obtained by Flory-Huggins model fitting. Solution (13)C NMR and FT-IR were conducted to investigate the specific drug-polymer interaction in the solution and solid state, respectively. Intrinsic dissolution of both the drug and the polymer from ASDs were studied using a Higuchi style intrinsic dissolution apparatus. PXRD and confocal Raman microscopy were used to confirm the absence of drug crystallinity on the tablet surface before and after dissolution study. In solid state, KTZ is completely miscible with PVP, PVP-VA, or HPMC-AS, demonstrated by the negative χ values of -0.36, -0.46, -1.68, respectively; while is poorly miscible with HPMC shown by a positive χ value of 0.23. According to solution (13)C NMR and FT-IR studies, KTZ interacts with HPMC-AS strongly through H-bonding and dipole induced interaction; with PVPs and PVP-VA moderately through dipole-induced interactions; and with HPMC weakly without detectable attractive interaction. Furthermore, the "apparent" strength of drug-polymer interaction, measured by the extent of peak shift on NMR or FT-IR spectra, increases with the increasing number of interacting drug-polymer pairs. For ASDs with the presence of considerable drug-polymer interactions, such as KTZ/PVPs, KTZ/PVP-VA, or KTZ /HPMC-AS systems, drug released at the same rate as the polymer when intimate drug-polymer mixing was ensured (i.e., the SDD systems
Blood Clotting Inspired Polymer Physics
Sing, Charles Edward
The blood clotting process is one of the human body's masterpieces in targeted molecular manipulation, as it requires the activation of the clotting cascade at a specific place and a specific time. Recent research in the biological sciences have discovered that one of the protein molecules involved in the initial stages of the clotting response, von Willebrand Factor (vWF), exhibits counterintuitive and technologically useful properties that are driven in part by the physical environment in the bloodstream at the site of a wound. In this thesis, we take inspiration from initial observations of the vWF in experiments, and aim to describe the behaviors observed in this process within the context of polymer physics. By understanding these physical principles, we hope to harness nature's ability to both direct molecules in both spatial and conformational coordinates. This thesis is presented in three complementary sections. After an initial introduction describing the systems of interest, we first describe the behavior of collapsed Lennard-Jones polymers in the presence of an infinite medium. It has been shown that simple bead-spring homopolymer models describe vWF quite well in vitro. We build upon this previous work to first describe the behavior of a collapsed homopolymer in an elongational fluid flow. Through a nucleation-protrusion mechanism, scaling relationships can be developed to provide a clear picture of a first-order globule-stretch transition and its ramifications in dilute-solution rheology. The implications of this behavior and its relation to the current literature provides qualitative explanations for the physiological process of vasoconstriction. In an effort to generalize these observations, we present an entire theory on the behavior of polymer globules under influence of any local fluid flow. Finally, we investigate the internal dynamics of these globules by probing their pulling response in an analogous fashion to force spectroscopy. We elucidate
Zivić, Ivan; Elezović-Hadzić, Suncica; Milosević, Sava
2009-12-01
We present an exact and Monte Carlo renormalization group (MCRG) study of semiflexible polymer chains on an infinite family of the plane-filling (PF) fractals. The fractals are compact, that is, their fractal dimension df is equal to 2 for all members of the fractal family enumerated by the odd integer b(3fractals (for 3fractals to the same problem on the regular Euclidean lattices.
International Nuclear Information System (INIS)
Zagorski, Z.
2000-01-01
The article is the broad review of history and state of art in radiation chemistry of polymers. The scientific background of radiation interaction with polymers and mechanisms of radiolytic degradation for aqueous solutions and 'dry' state of polymers have been shown. Also the applications of radiation for polymer properties modifications has been discussed in terms of polymers grafting and cross-linking for achieve shape memory feature, preparation of radioresistant polymers used for medical supplies being devoted to radiation sterilization etc. The polish contribution in related studies has been presented as well
Directory of Open Access Journals (Sweden)
Jovanović Slobodan M.
2003-01-01
Full Text Available Conducting polymers represent a very interesting group of polymer materials Investigation of the synthesis, structure and properties of these materials has been the subject of considerable research efforts in the last twenty years. A short presentating of newer results obtained by investigating of the synthesis, structure and properties of two basic groups of conducting polymers: a conducting polymers the conductivity of which is the result of their molecular structure, and b conducting polymer composites (EPC, is given in this paper. The applications and future development of this group of polymer materials is also discussed.
Influence of polymer structure on plasma-polymer interactions in resist materials
Bruce, Robert Lawson
The controlled patterning of polymer resists by plasma plays an essential role in the fabrication of integrated circuits and nanostructures. As the dimensions of patterned structures continue to decrease, we require an atomistic understanding underlying the morphological changes that occur during plasma-polymer interactions. In this work, we investigated how plasma surface modifications and the initial polymer structure influenced plasma etch behavior and morphological changes in polymer resists. Using a prototypical argon discharge, we observed polymer modification by ions and vacuum ultraviolet (VUV) radiation from the plasma. A thin, highly dense modified layer was formed at the polymer surface due to ion bombardment. The thickness and physical properties of this ion-damaged layer was independent of polymer structure for the systems examined here. A relationship was observed that strongly suggests that buckling caused by ion-damaged layer formation on a polymer is the origin of roughness that develops during plasma etching. Our results indicate that with knowledge of the mechanical properties of the ion-damaged layer and the polymer being processed, plasma-induced surface roughness can be predicted and the surface morphology calculated. Examining a wide variety of polymer structures, the polymer poly(4-vinylpyridine) (P4VP) was observed to produce extremely smooth surfaces during high-ion energy plasma etching. Our data suggest that VUV crosslinking of P4VP below the ion-damaged layer may prevent wrinkling. We also studied another form of resists, silicon-containing polymers that form a SiO2 etch barrier layer during O2 plasma processing. In this study, we examined whether assisting SiO2 layer formation by adding Si-O bonds to the polymer structure would improve O2 etch behavior and reduce polymer surface roughness. Our results showed that while adding Si-O bonds decreased etch rates and silicon volatilization during O2 plasma exposure, the surface roughness
DEFF Research Database (Denmark)
Ara, Pere; Dykema, Kenneth J.; Rørdam, Mikael
2013-01-01
The proofs of Theorem 2.2 of K. J. Dykema and M. Rørdam, Purely infinite simple C∗-algebras arising from free product constructions}, Canad. J. Math. 50 (1998), 323--341 and of Theorem 3.1 of K. J. Dykema, Purely infinite simple C∗-algebras arising from free product constructions, II, Math. Scand...
Polymers in the gut compress the colonic mucus hydrogel.
Datta, Sujit S; Preska Steinberg, Asher; Ismagilov, Rustem F
2016-06-28
Colonic mucus is a key biological hydrogel that protects the gut from infection and physical damage and mediates host-microbe interactions and drug delivery. However, little is known about how its structure is influenced by materials it comes into contact with regularly. For example, the gut abounds in polymers such as dietary fibers or administered therapeutics, yet whether such polymers interact with the mucus hydrogel, and if so, how, remains unclear. Although several biological processes have been identified as potential regulators of mucus structure, the polymeric composition of the gut environment has been ignored. Here, we demonstrate that gut polymers do in fact regulate mucus hydrogel structure, and that polymer-mucus interactions can be described using a thermodynamic model based on Flory-Huggins solution theory. We found that both dietary and therapeutic polymers dramatically compressed murine colonic mucus ex vivo and in vivo. This behavior depended strongly on both polymer concentration and molecular weight, in agreement with the predictions of our thermodynamic model. Moreover, exposure to polymer-rich luminal fluid from germ-free mice strongly compressed the mucus hydrogel, whereas exposure to luminal fluid from specific-pathogen-free mice-whose microbiota degrade gut polymers-did not; this suggests that gut microbes modulate mucus structure by degrading polymers. These findings highlight the role of mucus as a responsive biomaterial, and reveal a mechanism of mucus restructuring that must be integrated into the design and interpretation of studies involving therapeutic polymers, dietary fibers, and fiber-degrading gut microbes.
Introduction to Polymer Chemistry.
Harris, Frank W.
1981-01-01
Reviews the physical and chemical properties of polymers and the two major methods of polymer synthesis: addition (chain, chain-growth, or chain-reaction), and condensation (step-growth or step-reaction) polymerization. (JN)
Antiviral Polymer Therapeutics
DEFF Research Database (Denmark)
Smith, Anton Allen Abbotsford
2014-01-01
polymerized in a controlled manner with carrier monomers of historically proven biocompatible polymers. The carrier polymers, the loading of ribavirin as well as the size of the polymer were varied systematically with the aid of an automated synthesis platform. These polymers were tested in a cellular assay...... of reversible-addition-fragmentation chain transfer polymerization, which not only controls the size of polymer, but also allows the introduction of a terminal amine on the polymer which can be used for further conjugation. This has allowed for not only fluorescent labeling of the polymer, but also protein......The field of drug delivery is in essence an exercise in engineered pharmacokinetics. Methods of doing so have been developed through the introduction of a vehicle carrying the drug, either by encapsulation or covalent attachment. The emergence of polymer therapeutics in anticancer therapy has...
Bird, R. Byron
1980-01-01
Problems in polymer fluid dynamics are described, including development of constitutive equations, rheometry, kinetic theory, flow visualization, heat transfer studies, flows with phase change, two-phase flow, polymer unit operations, and drag reduction. (JN)
Random polyfluorene co -polymers designed for a better optical ...
African Journals Online (AJOL)
Two alternating polyfluorenes (APFO15-F8BT and APFO3-F8BT) with full absorption of the visible region of the electromagnetic radiation were designed and synthesized for bulk-heterojunction solar cell devices. The optical and electrochemical properties of the two polymers were studied. The two polymers exhibited strong ...
Polymer dynamics from synthetic polymers to proteins
Indian Academy of Sciences (India)
Starting from the standard model of polymer motion - the Rouse model - we briefly present some key experimental results on the mesoscopic dynamics of polymer systems. We touch the role of topological confinement as expressed in the reptation model and discuss in some more detail processes limiting the confinement.
Antimicrobial Modifications of Polymers
Sedlarik, Vladimir
2013-01-01
This chapter is focused on antimicrobial modifications of polymer materials intended for medical devices production. Firstly, a brief introduction into the field of medical application of polymers is presented. Considering the fact that polymer medical devices are often connected with occurrence of nosocomial infections, the next part refers to this phenomenon and its causes. One of the possibilities of reducing of the infection occurrence is aimed at polymer modification. It is a key topic o...
Microgel polymer composite fibres
Kehren, Dominic
2014-01-01
In this thesis some novel ideas and advancements in the field of polymer composite fibres, specifically microgel-based polymer composite fibres have been achieved. The main task was to investigate and understand the electrospinning process of microgels and polymers and the interplay of parameter influences, in order to fabricate reproducible and continuously homogenous composite fibres. The main aim was to fabricate a composite material which combines the special properties of polymer fibres ...
Miscibility of polymer blends with engineering models
DEFF Research Database (Denmark)
Vassilis, Harismiadis; van Bergen, A. R. D.; Goncalves, Ana Saraiva
1996-01-01
The miscibility behavior of polymer blends that do not exhibit strong specific interactions is examined. Phase equilibrium calculations are presented with the van der Waals equation of state and three group-contribution models (UNIFAC, Entropic-FV, and GC-Flory). Performance of these models is also...... compared. The van der Waals equation of state was recently shown to accurately correlate and predict vapor-liquid and liquid-liquid equilibria for binary polymer/solvent solutions. In this work, it is demonstrated that it correlates the upper critical solution behavior of polymer blends with excellent......, the upper critical solution temperature can be predicted with an average error of less than 45 degrees C. The van der Waals equation of state can correlate the lower critical solution behavior of polymer blends, using an interaction parameter that is a linear function of temperature. The UNIFAC and Entropic...
Synthesis and supramolecular assembly of biomimetic polymers
Marciel, Amanda Brittany
A grand challenge in materials chemistry is the synthesis of macromolecules and polymers with precise shapes and architectures. Polymer microstructure and architecture strongly affect the resulting functionality of advanced materials, yet understanding the static and dynamic properties of these complex macromolecules in bulk has been difficult due to their inherit polydispersity. Single molecule studies have provided a wealth of information on linear flexible and semi-flexible polymers in dilute solutions. However, few investigations have focused on industrially relevant complex topologies (e.g., star, comb, hyperbranched polymers) in industrially relevant solution conditions (e.g., semi-dilute, concentrated). Therefore, from this perspective there is a strong need to synthesize precision complex architectures for bulk studies as well as complex architectures compatible with current single molecule techniques to study static and dynamic polymer properties. In this way, we developed a hybrid synthetic strategy to produce branched polymer architectures based on chemically modified DNA. Overall, this approach enables control of backbone length and flexibility, as well as branch grafting density and chemical identity. We utilized a two-step scheme based on enzymatic incorporation of non-natural nucleotides containing bioorthogonal dibenzocyclooctyne (DBCO) functional groups along the main polymer backbone, followed by copper-free "click" chemistry to graft synthetic polymer branches or oligonucleotide branches to the DNA backbone, thereby allowing for the synthesis of a variety of polymer architectures, including three-arm stars, H-polymers, graft block copolymers, and comb polymers for materials assembly and single molecule studies. Bulk materials properties are also affected by industrial processing conditions that alter polymer morphology. Therefore, in an alternative strategy we developed a microfluidic-based approach to assemble highly aligned synthetic
Physical theory of excitons in conducting polymers.
Brazovskii, Serguei; Kirova, Natasha
2010-07-01
In this tutorial review, we cover the solid state physics approach to electronic and optical properties of conducting polymers. We attempt to bring together languages and advantages of the solid state theory for polymers and of the quantum chemistry for monomers. We consider polymers as generic one-dimensional semiconductors with features of strongly correlated electronic systems. Our model combines the long range electron-hole Coulomb attraction with a specific effect of strong intra-monomer electronic correlations, which results in effective intra-monomer electron-hole repulsion. Our approach allows to go beyond the single-chain picture and to compare excitons for polymers in solutions and in films. The approach helps connecting such different questions as shallow singlet and deep triplet excitons, stronger binding of interchain excitons in films, crossings of excitons' branches, 1/N energies shifts in oligomers. We describe a strong suppression of the luminescence from free charge carriers by long-range Coulomb interactions. Main attention is devoted to the most requested in applications phenyl based polymers. The specifics of the benzene ring monomer give rise to existence of three possible types of excitons: Wannier-Mott, Frenkel and intermediate ones. We discuss experimental manifestations of various excitons and of their transformations. We touch effects of the time-resolved self-trapping by libron modes leading to formation of torsion polarons.
Modeling semiflexible polymer networks
Broedersz, C.P.; MacKintosh, F.C.
2014-01-01
This is an overview of theoretical approaches to semiflexible polymers and their networks. Such semiflexible polymers have large bending rigidities that can compete with the entropic tendency of a chain to crumple up into a random coil. Many studies on semiflexible polymers and their assemblies have
National Research Council Canada - National Science Library
Zhang, Xuejun, Ph.D
1999-01-01
Effects of the electronic structure of polymer/polymer interfaces on the electroluminescence efficiency and tunable multicolor emission of polymer heterojunction light-emitting diodes were explored...
Self-impedances of finite and infinite wires with earth-return
International Nuclear Information System (INIS)
Koglin, H.J.; Meyer, E.P.
1981-01-01
The electromagnetic field for a thin wire of finite length, embedded in a homogeneous earth of infinite extent in all directions, is given. The distribution of the electric field intensity close to the wire is examined. The mathematical model for the finite wire is expanded by substituting a spheroidal earth-electrode at each end. The external self-impedance of the wire between the earth-electrodes is calculated by integrating the electric field intensity along a presupposed radius. Especially in the case of short wires the results show considerable deviations to the known depth of current penetration as compared to that of an infinitely long wire. By considering the approximations used for short wires in this model, one can draw conclusions on the external self-impedance for short wires above, on and under the earth's surface. (orig.) [de
Option pricing for stochastic volatility model with infinite activity Lévy jumps
Gong, Xiaoli; Zhuang, Xintian
2016-08-01
The purpose of this paper is to apply the stochastic volatility model driven by infinite activity Lévy processes to option pricing which displays infinite activity jumps behaviors and time varying volatility that is consistent with the phenomenon observed in underlying asset dynamics. We specially pay attention to three typical Lévy processes that replace the compound Poisson jumps in Bates model, aiming to capture the leptokurtic feature in asset returns and volatility clustering effect in returns variance. By utilizing the analytical characteristic function and fast Fourier transform technique, the closed form formula of option pricing can be derived. The intelligent global optimization search algorithm called Differential Evolution is introduced into the above highly dimensional models for parameters calibration so as to improve the calibration quality of fitted option models. Finally, we perform empirical researches using both time series data and options data on financial markets to illustrate the effectiveness and superiority of the proposed method.
Large scale inference in the Infinite Relational Model: Gibbs sampling is not enough
DEFF Research Database (Denmark)
Albers, Kristoffer Jon; Moth, Andreas Leon Aagard; Mørup, Morten
2013-01-01
The stochastic block-model and its non-parametric extension, the Infinite Relational Model (IRM), have become key tools for discovering group-structure in complex networks. Identifying these groups is a combinatorial inference problem which is usually solved by Gibbs sampling. However, whether...... Gibbs sampling suffices and can be scaled to the modeling of large scale real world complex networks has not been examined sufficiently. In this paper we evaluate the performance and mixing ability of Gibbs sampling in the Infinite Relational Model (IRM) by implementing a high performance Gibbs sampler....... We find that Gibbs sampling can be computationally scaled to handle millions of nodes and billions of links. Investigating the behavior of the Gibbs sampler for different sizes of networks we find that the mixing ability decreases drastically with the network size, clearly indicating a need...
Weak convergence of the function-indexed integrated periodogram for infinite variance processes
DEFF Research Database (Denmark)
Can, Umut; Mikosch, Thomas Valentin; Samorodnitsky, Gennady
2010-01-01
), entropy conditions are needed for α ∈ [1, 2) to ensure the tightness of the sequence of integrated periodograms indexed by functions. The results of this paper are of additional interest since they provide limit results for infinite mean random quadratic forms with particular Toeplitz coefficient matrices.......In this paper, we study the weak convergence of the integrated periodogram indexed by classes of functions for linear processes with symmetric α-stable innovations. Under suitable summability conditions on the series of the Fourier coefficients of the index functions, we show that the weak limits...... constitute α-stable processes which have representations as infinite Fourier series with i.i.d. α-stable coefficients. The cases α ∈ (0, 1) and α ∈ [1, 2) are dealt with by rather different methods and under different assumptions on the classes of functions. For example, in contrast to the case α ∈ (0, 1...
Edholm, James
2018-03-01
General Relativity is known to produce singularities in the potential generated by a point source. Our universe can be modeled as a de Sitter (dS) metric and we show that ghost-free infinite derivative gravity (IDG) produces a nonsingular potential around a dS background, while returning to the GR prediction at large distances. We also show that although there are an apparently infinite number of coefficients in the theory, only a finite number actually affect the predictions. By writing the linearized equations of motion in a simplified form, we find that at distances below the Hubble length scale, the difference between the IDG potential around a flat background and around a de Sitter background is negligible.
Critical behaviour of continuous phase transitions with infinitely many absorbing states
International Nuclear Information System (INIS)
Hua Dayin; Wang Lieyan; Chen Ting
2006-01-01
A lattice gas model is proposed for the A 2 + 2B 2 → 2B 2 A reaction system with particle diffusion. In the model, A 2 dissociates in the random dimer-filling mechanism and B 2 dissociation is in the end-on dimer-filling mechanism. A reactive window appears and the system exhibits a continuous phase transition from a reactive state to a covered state with infinitely many absorbing states. When the diffusion of particle A and AB is included, there are still infinitely many absorbing states for the continuous phase transition, but it is found that the critical behaviour changes from the directed percolation (DP) class to the pair contact process with diffusion (PCPD) class
MARKOV: A methodology for the solution of infinite time horizon MARKOV decision processes
Williams, B.K.
1988-01-01
Algorithms are described for determining optimal policies for finite state, finite action, infinite discrete time horizon Markov decision processes. Both value-improvement and policy-improvement techniques are used in the algorithms. Computing procedures are also described. The algorithms are appropriate for processes that are either finite or infinite, deterministic or stochastic, discounted or undiscounted, in any meaningful combination of these features. Computing procedures are described in terms of initial data processing, bound improvements, process reduction, and testing and solution. Application of the methodology is illustrated with an example involving natural resource management. Management implications of certain hypothesized relationships between mallard survival and harvest rates are addressed by applying the optimality procedures to mallard population models.
Towers and ladders: Infinite parameter symmetries in Kaluza-Klein theories
International Nuclear Information System (INIS)
Aulakh, C.S.
1984-05-01
We introduce a class of infinite dimensional algebras with a 'generalized loop structure' by considering the global symmetries of the four dimensional Lagrangian obtained by compactifying general relativity coupled to Yang-Mills in six dimensions down to M 4 xS 2 . The generalization to arbitrary dimensions is then obvious. We show by explicit construction that such algebras possess an infinite number of finite sub-algebras. Among which, for the six dimensional case, is so(1,3) realized on S 2 with vanishing Casimir invariants. This so(1,3) may be interpreted, in accord with a previous conjecture of Salam and Strathdee [Ann. Phys. 141, 316(1982)], as the 'ladder' symmetry for the Kaluza-Klein towers. (author)
Of towers and ladders: Infinite parameter symmetries in Kaluza-Klein theories
International Nuclear Information System (INIS)
Aulakh, C.S.
1984-01-01
We introduce a class of infinite dimensional algebras with a 'generalized loop structure' by considering the global symmetries of the four-dimensional lagrangian obtained by compactifying general relativity coupled to Yang-Mills in six-dimensions down to M 4 x S 2 . The generalization to arbitrary dimensions is then obvious. We show by explicit construction that such algebras possess an infinite number of finite sub-algebras among which, for the six-dimensional case, is so (1, 3), realized on S 2 with vanishing Casimir invariants. This so (1, 3) may be interpreted, in accordance with a previous conjecture of Salam and Strathdee, as the 'ladder' symmetry for the Kaluza-Klein towers. (orig.)
Exact, rotational, infinite energy, blowup solutions to the 3-dimensional Euler equations
International Nuclear Information System (INIS)
Yuen, Manwai
2011-01-01
In this Letter, we construct a new class of blowup or global solutions with elementary functions to the 3-dimensional compressible or incompressible Euler and Navier-Stokes equations. And the corresponding blowup or global solutions for the incompressible Euler and Naiver-Stokes equations are also given. Our constructed solutions are similar to the famous Arnold-Beltrami-Childress (ABC) flow. The obtained solutions with infinite energy can exhibit the interesting behaviors locally. Furthermore, due to divu → =0 for the solutions, the solutions also work for the 3-dimensional incompressible Euler and Navier-Stokes equations. -- Highlights: → We construct a new class of solutions to the 3D compressible or incompressible Euler and Navier-Stokes equations. → The constructed solutions are similar to the famous Arnold-Beltrami-Childress flow. → The solutions with infinite energy can exhibit the interesting behaviors locally.
Calculating alpha Eigenvalues in a Continuous-Energy Infinite Medium with Monte Carlo
Energy Technology Data Exchange (ETDEWEB)
Betzler, Benjamin R. [Los Alamos National Laboratory; Kiedrowski, Brian C. [Los Alamos National Laboratory; Brown, Forrest B. [Los Alamos National Laboratory; Martin, William R. [Los Alamos National Laboratory
2012-09-04
The {alpha} eigenvalue has implications for time-dependent problems where the system is sub- or supercritical. We present methods and results from calculating the {alpha}-eigenvalue spectrum for a continuous-energy infinite medium with a simplified Monte Carlo transport code. We formulate the {alpha}-eigenvalue problem, detail the Monte Carlo code physics, and provide verification and results. We have a method for calculating the {alpha}-eigenvalue spectrum in a continuous-energy infinite-medium. The continuous-time Markov process described by the transition rate matrix provides a way of obtaining the {alpha}-eigenvalue spectrum and kinetic modes. These are useful for the approximation of the time dependence of the system.
Infinite sets of conservation laws for linear and non-linear field equations
International Nuclear Information System (INIS)
Niederle, J.
1984-01-01
The work was motivated by a desire to understand group theoretically the existence of an infinite set of conservation laws for non-interacting fields and to carry over these conservation laws to the case of interacting fields. The relation between an infinite set of conservation laws of a linear field equation and the enveloping algebra of its space-time symmetry group was established. It is shown that in the case of the Korteweg-de Vries (KdV) equation to each symmetry of the corresponding linear equation delta sub(o)uxxx=u sub() determined by an element of the enveloping algebra of the space translation algebra, there corresponds a symmetry of the full KdV equation
Transport of radioactive decay chains in finite and semi-infinite porous media
International Nuclear Information System (INIS)
Lung, H.C.; Chambre, P.L.; Pigford, T.H.; Lee, W.W.L.
1987-09-01
This report presents analytic solutions, numerical implementation and numerical illustrations for the transport of radioactive decay chains of arbitary length in porous media of limited and unlimited extent. The analytic solutions for the problem of chains transport in finite and semi-infinite media are complicated. Sophisticated numerical methods were required in order to implement the solutions as computer programs. These steps are detailed in the report. The main part of this report are illustrations of the solutions with problems in nuclear waste disposal. We show the transport of two chains, uranium 234 to radium 226 and curium 245 to thorium, from concentration-limited boundary condition and Bateman-type boundary condition, in a porous region of limited extent such as a backfill and in a semi-infinite field. These illustrations are examples of the capabilities and usefulness of these solutions. 5 refs., 33 figs
A remark on the infinite-volume Gibbs measures of spin glasses
Arguin, Louis-Pierre
2008-12-01
In this note, we point out that infinite-volume Gibbs measures of spin glass models on the hypercube can be identified as random probability measures on the unit ball of a Hilbert space. This simple observation follows from a result of Dovbysh and Sudakov on weakly exchangeable random matrices. Limiting Gibbs measures can then be studied as single well-defined objects. This approach naturally extends the space of random overlap structures as defined by Aizenman et al. We discuss the Ruelle probability cascades and the stochastic stability within this framework. As an application, we use an idea of Parisi and Talagrand to prove that if a sequence of finite-volume Gibbs measures satisfies the Ghirlanda-Guerra identities, then the infinite-volume measure must be singular as a measure on a Hilbert space.
An Interval Mixed-Integer Semi-Infinite Programming Method for Municipal Solid Waste Management.
He, Li; Huang, Guo H; Zeng, Guangming; Lu, Hongwei
2009-02-01
This study proposed an interval mixed-integer semi-infinite programming (IMISIP) method for solid waste management under uncertainty. The uncertainty can be expressed as various constants, intervals, and functional intervals. The method is mainly based on the previous efforts on interval mixed-integer linear programming (IMILP) and semi-infinite programming. The method is applied to a solid-waste management system to illustrate its effectiveness in handling complex inexact programming problems. Two scenarios are considered: one is a case with only expansions of waste-to-energy (WTE) facilities being considered, and the other is associated with potential expansions for both the WTE and the existing landfilling facilities. The results obtained can assist in identifying optimal waste management policies under uncertainties associated with interval and functional-interval parameters. Compared with conventional IMILP methods, the solutions obtained from IMISIP could be "globally" optimal because the dynamic fluctuations of the system inputs could be reflected effectively.
Nanoporous polymer electrolyte
Elliott, Brian [Wheat Ridge, CO; Nguyen, Vinh [Wheat Ridge, CO
2012-04-24
A nanoporous polymer electrolyte and methods for making the polymer electrolyte are disclosed. The polymer electrolyte comprises a crosslinked self-assembly of a polymerizable salt surfactant, wherein the crosslinked self-assembly includes nanopores and wherein the crosslinked self-assembly has a conductivity of at least 1.0.times.10.sup.-6 S/cm at 25.degree. C. The method of making a polymer electrolyte comprises providing a polymerizable salt surfactant. The method further comprises crosslinking the polymerizable salt surfactant to form a nanoporous polymer electrolyte.
International Nuclear Information System (INIS)
Clough, R.L.; Shalaby, S.W.
1991-01-01
This book covers polymer radiation effects to be available in more than a decade. This volume reviews the fundamental chemistry and physics of polymer-radiation interaction and examines recent progress in most major areas of the field. Its 38 chapters, cover: fundamentals of polymer radiation chemistry; technological applications of radiation to polymers (including radiation processing; radiation curing; sterilization; cross-linking, polymerization, grafting, x-ray resists, and others); and degradation of stabilization of irradiated polymers (including nuclear plants, scintillation detectors for particle physics, and others)
Biostable glucose permeable polymer
DEFF Research Database (Denmark)
2017-01-01
A new biostable glucose permeable polymer has been developed which is useful, for example, in implantable glucose sensors. This biostable glucose permeable polymer has a number of advantageous characteristics and, for example, does not undergo hydrolytic cleavage and degradation, thereby providing...... a composition that facilitates long term sensor stability in vivo. The versatile characteristics of this polymer allow it to be used in a variety of contexts, for example to form the body of an implantable glucose sensor. The invention includes the polymer composition, sensor systems formed from this polymer...
Polymer friction Molecular Dynamics
DEFF Research Database (Denmark)
Sivebæk, Ion Marius; Samoilov, Vladimir N.; Persson, Bo N. J.
We present molecular dynamics friction calculations for confined hydrocarbon solids with molecular lengths from 20 to 1400 carbon atoms. Two cases are considered: a) polymer sliding against a hard substrate, and b) polymer sliding on polymer. In the first setup the shear stresses are relatively...... independent of molecular length. For polymer sliding on polymer the friction is significantly larger, and dependent on the molecular chain length. In both cases, the shear stresses are proportional to the squeezing pressure and finite at zero load, indicating an adhesional contribution to the friction force....
Numerical Solution of the Flow of a Perfect Gas Over A Circular Cylinder at Infinite Mach Number
Hamaker, Frank M.
1959-01-01
A solution for the two-dimensional flow of an inviscid perfect gas over a circular cylinder at infinite Mach number is obtained by numerical methods of analysis. Nonisentropic conditions of curved shock waves and vorticity are included in the solution. The analysis is divided into two distinct regions, the subsonic region which is analyzed by the relaxation method of Southwell and the supersonic region which was treated by the method of characteristics. Both these methods of analysis are inapplicable on the sonic line which is therefore considered separately. The shapes of the sonic line and the shock wave are obtained by iteration techniques. The striking result of the solution is the strong curvature of the sonic line and of the other lines of constant Mach number. Because of this the influence of the supersonic flow on the sonic line is negligible. On comparison with Newtonian flow methods, it is found that the approximate methods show a larger variation of surface pressure than is given by the present solution.
Flow of a power-law fluid with memory past an infinite plate ...
African Journals Online (AJOL)
We examined the flow of a power law fluid with a non-constant relaxation λtb past an infinite plate. When λ is zero the fluid is pseudoplastic and when the power law exponent is 1, the fluid is a Maxwell fluid. It is shown that the problem has a solution when 0 < n ≤ 1. Moreover, we show that momentum penetration ...
Two sources are better than one for increasing the Kolmogorov complexity of infinite sequences
Zimand, Marius
2007-01-01
The randomness rate of an infinite binary sequence is characterized by the sequence of ratios between the Kolmogorov complexity and the length of the initial segments of the sequence. It is known that there is no uniform effective procedure that transforms one input sequence into another sequence with higher randomness rate. By contrast, we display such a uniform effective procedure having as input two independent sequences with positive but arbitrarily small constant randomness rate. Moreove...
Creating visual aids with graphic organisers on an infinite canvas : the impact on the presenter
Casteleyn, Jordi; Mottart, André; Valcke, Martin
2015-01-01
Instead of the traditional set of slides, the visual aids of a presentation can now be graphic organisers (concept maps, knowledge maps, mind maps) on an infinite canvas. Constructing graphic organisers has a beneficial impact on learning, but this topic has not been studied in the context of giving a presentation. The present study examined this issue by having 199 students prepare a presentation. The control sample created visual aids that are similar to a deck of slides with text and pictu...
On one problem of the busy period determination in queues with infinitely many servers
International Nuclear Information System (INIS)
Dvurecenskij, A.; Kuljukina, L.A.; Ososkov, G.A.
1982-01-01
In the paper the problem of the discretized cluster length probability determination based on the scanning in the track chambers is considered. This problem is solved in the frame of the queueing system with infinitely many servers as a discretized busy period probability determination of this system. The precise formulae of a probability are given and it is proved that those probabilities converge weakly to the probability distribution of the nondiscretized cluster when the discretization steps are diminished
Linear vs nonlinear and infinite vs finite: An interpretation of chaos
Energy Technology Data Exchange (ETDEWEB)
Protopopescu, V.
1990-10-01
An example of a linear infinite-dimensional system is presented that exhibits deterministic chaos and thus challenges the presumably unquestionable connection between chaos and nonlinearity. Via this example, the roles of, and relationships between, linearity, nonlinearity, infinity and finiteness in the occurrence of chaos are investigated. The analysis of these complementary but related aspects leads to: a new interpretation of chaos as the manifestation of incompressible and thus incompressible information and a conjecture about the nonexistence of operationally accessible linear systems.
Solution of the Dirichlet Problem for the Poisson's Equation in a Multidimensional Infinite Layer
Directory of Open Access Journals (Sweden)
O. D. Algazin
2015-01-01
Full Text Available The paper considers the multidimensional Poisson equation in the domain bounded by two parallel hyperplanes (in the multidimensional infinite layer. For an n-dimensional half-space method of solving boundary value problems for linear partial differential equations with constant coefficients is a Fourier transform to the variables in the boundary hyperplane. The same method can be used for an infinite layer, as is done in this paper in the case of the Dirichlet problem for the Poisson equation. For strip and infinite layer in three-dimensional space the solutions of this problem are known. And in the three-dimensional case Green's function is written as an infinite series. In this paper, the solution is obtained in the integral form and kernels of integrals are expressed in a finite form in terms of elementary functions and Bessel functions. A recurrence relation between the kernels of integrals for n-dimensional and (n + 2 -dimensional layers was obtained. In particular, is built the Green's function of the Laplace operator for the Dirichlet problem, through which the solution of the problem is recorded. Even in three-dimensional case we obtained new formula compared to the known. It is shown that the kernel of the integral representation of the solution of the Dirichlet problem for a homogeneous Poisson equation (Laplace equation is an approximate identity (δ-shaped system of functions. Therefore, if the boundary values are generalized functions of slow growth, the solution of the Dirichlet problem for the homogeneous equation (Laplace is written as a convolution of kernels with these functions.