Petrol contaminated groundwater treatment with air-stripper in Balassagyarmat, Hungary

International Nuclear Information System (INIS)

Szabo, Peter; Bernath, Balazs

2005-01-01

Hydrocarbon contaminated groundwater is a common environmental problem in Hungary. Leakage of underground storage tanks, pipe break or illegal tapping as well as lorry accidents can be mentioned as main reasons. MEGATERRA Ltd. elaborated, adopted and tested several groundwater clean-up methods. These methods are based on detailed survey and investigation, sampling and analysis, delineation of contaminated groundwater, risk assessment, establishment of monitoring wells, pumping tests and remediation action plan. One of these methods was implemented by MEGATERRA Ltd. in Balassagyarmat, Hungary. Contamination source was a 10 m 3 vol. simple wall underground fuel-storage tank, which had been emptied. When the remediation started in April 1998, the petrol had already been accumulated on the ground water table forming a 5-7 m wide and 10-15 m long plume being expanded to SSE-NNW direction. The area of the dissolved hydrocarbon contaminated groundwater-body was 1 000 m 2 and its concentration reached up to 30-40 mg/l TPH. The free-phase hydrocarbon layer was 10 cm thick. For the remediation of contaminated groundwater MEGATERRA Ltd. applied pump and treat method, namely groundwater pumping using extraction well, skimming of free-phase hydrocarbon, stripping of the contaminated ground water in air-stripper tower and draining of the treated groundwater into a drainage ditch. In the centre of the plume we established an extraction well with 300 mm diameter in a 500 mm borehole. Peristaltic skimmer pump was used inside the extraction well to remove the free phase petrol from the ground water surface.Because of the intense volatility of the pollutant we applied aeration (stripping) technology. The extracted contaminated groundwater was cleaned in air-stripper equipment being able to eliminate efficiently the volatile pollutants from the water. The aeration tower is a compact cylindrical shaped column with 650 mm in diameter. Its height depends on the pollutant's type The

Performance Evaluation of Hap-Free Paint Strippers vs. Methylene-Chloride-Based Strippers for Removing Army Chemical Agent Resistant Coatings (CARC)

National Research Council Canada - National Science Library

Kelley, John; Considine, Thomas

2006-01-01

...). The purpose of this effort is to investigate HAP-free alternative chemical paint strippers as potential replacements for the methylene-chloride- based chemical strippers currently used in both processes...

P-type diamond stripper foils for tandem ion accelerators

International Nuclear Information System (INIS)

Phelps, A.W.; Koba, R.

1989-01-01

The authors are developing a stripper foil composed of a p-type diamond membrane. This diamond stripper foil should have a significantly longer lifetime than any conventional stripper foil material. To be useful for stripper foils, the boron-doped blue diamond films must be thinner than 0.8 μm and pore-free. Two methods are compared for their ability to achieve a high nucleation areal density on a W substrate. Some W substrates were first coated with think layer of boron (≤20 nm) in order to enhance nucleation. Other W substrates were scratched with submicron diamond particles. A schematic diagram of the stripper foil is shown. Stripper foils were created by etching away the central area of W substrates. The diamond membrane was then supported by an annulus of W. Tungsten was selected as a ring-support material because of its high electrical and thermal conductivity, relatively low thermal expansion, and proven suitability as a substrate for diamond CVD. Warping or fracture of the diamond film after substrate etch-back was investigated

Picker versus stripper harvesters on the High Plains of Texas

Science.gov (United States)

A break even analysis based on NPV was conducted to compare picker-based and stripper-based harvest systems with and without field cleaners. Under no conditions analyzed was the NPV of a stripper system without a field cleaner greater than a stripper system with a field cleaner. Break even curves re...

Charge state distribution of ^{86}Kr in hydrogen and helium gas charge strippers at 2.7  MeV/nucleon

Directory of Open Access Journals (Sweden)

H. Kuboki

2014-12-01

Full Text Available The charge state distributions of krypton (^{86}Kr with an energy of 2.7  MeV/nucleon were measured using hydrogen (H_{2} and helium (He gas charge strippers. A differential pumping system was constructed to confine H_{2} and He gases to a thickness sufficient for the charge state distributions to attain equilibrium. The mean charge states of ^{86}Kr in H_{2} and He gases attained equilibrium at 25.1 and 23.2, respectively, whereas the mean charge state in N_{2} gas at equilibrium was estimated to be less than 20. The charge distributions are successfully reproduced by the cross sections of ionization and electron capture processes optimized by a fitting procedure.

What You Should Know about Using Paint Strippers

Science.gov (United States)

... is readily absorbed through the skin and may cause health problems. Adverse health effects in the developing fetus have been noted in laboratory animals exposed to some of the chemicals in paint strippers. Therefore, women of child-bearing age who work with or use paint strippers on a regular ...

Development of a rotating graphite carbon disk stripper

Science.gov (United States)

Hasebe, Hiroo; Okuno, Hiroki; Tatami, Atsushi; Tachibana, Masamitsu; Murakami, Mutsuaki; Kuboki, Hironori; Imao, Hiroshi; Fukunishi, Nobuhisa; Kase, Masayuki; Kamigaito, Osamu

2018-05-01

Highly oriented graphite carbon sheets (GCSs) were successfully used as disk strippers. An irradiation test conducted in 2015 showed that GCS strippers have the longest lifetime and exhibit improved stripping and transmission efficiencies. The problem of disk deformation in previously used Be-disk was solved even with higher beam intensity.

ESTABLISHMENT OF AN INDUSTRY-DRIVEN CONSORTIUM FOCUSED ON IMPROVING THE PRODUCTION PERFORMANCE OF DOMESTIC STRIPPER WELLS

Energy Technology Data Exchange (ETDEWEB)

Joel L. Morrison

2001-09-12

The Pennsylvania State University, under contract to the US Department of Energy, National Energy Technology Laboratory will establish, promote, and manage a national industry-driven Stripper Well Consortium (SWC) that will be focused on improving the production performance of domestic petroleum and/or natural gas stripper wells. the consortium creates a partnership with the US petroleum and natural gas industries and trade associations, state funding agencies, academia, and the National Energy Technology Laboratory. This report serves as the third quarterly technical progress report for the SWC. During this reporting period the SWC entered into a co-funding arrangement with the New York State Energy Development Authority (NYSERDA) to provide an additional $100,000 in co-funding for stripper well production-orientated projects.The SWC hosted its first meeting in which members proposed research projects to the SWC membership. The meeting was held on April 9-10, 2001 in State College, Pennsylvania. Twenty three proposals were submitted to the SWC for funding consideration. Investigators of the proposed projects provided the SWC membership with a 20 minute (15 minute technical discussion, 5 minute question and answer session) presentation. Of the 23 proposals, the Executive Council approved $921,000 in funding for 13 projects. Penn State then immediately started the process of issuing subcontracts to the various projects approved for funding.

ESTABLISHMENT OF AN INDUSTRY-DRIVEN CONSORTIUM FOCUSED ON IMPROVING THE PRODUCTION PERFORMANCE OF DOMESTIC STRIPPER WELLS

International Nuclear Information System (INIS)

Joel L. Morrison

2001-01-01

The Pennsylvania State University, under contract to the US Department of Energy, National Energy Technology Laboratory will establish, promote, and manage a national industry-driven Stripper Well Consortium (SWC) that will be focused on improving the production performance of domestic petroleum and/or natural gas stripper wells. the consortium creates a partnership with the US petroleum and natural gas industries and trade associations, state funding agencies, academia, and the National Energy Technology Laboratory. This report serves as the third quarterly technical progress report for the SWC. During this reporting period the SWC entered into a co-funding arrangement with the New York State Energy Development Authority (NYSERDA) to provide an additional$100,000 in co-funding for stripper well production-orientated projects.The SWC hosted its first meeting in which members proposed research projects to the SWC membership. The meeting was held on April 9-10, 2001 in State College, Pennsylvania. Twenty three proposals were submitted to the SWC for funding consideration. Investigators of the proposed projects provided the SWC membership with a 20 minute (15 minute technical discussion, 5 minute question and answer session) presentation. Of the 23 proposals, the Executive Council approved$921,000 in funding for 13 projects. Penn State then immediately started the process of issuing subcontracts to the various projects approved for funding

Heavy water plant

International Nuclear Information System (INIS)

Rogers, D.G.

1978-01-01

This invention provides an auxiliary contactor column or exchange tower to receive stripped gas and vapour from a stripper. An auxiliary supply of heated feed water is passed in isotope exchanging relation with the gas in the auxiliary contactor to raise the deuterium content of the gas, which then is returned to the main process, at the hot tower or at the feed absorption tower as already described in relation to previous practice. Flow balance between gas and water in the auxiliary contactor is achieved relatively simply by monitoring the deuterium content of the hot water leaving the contactor column, and regulating the supply of hot water, to the contactor column in response thereto. (author)

Hybrid-type long-lived carbon stripper foils

International Nuclear Information System (INIS)

Sugai, Isao; Kato, Hajime

1989-01-01

A new method for the preparation of hybrid-type long-lived carbon stripper foils was developed. The new procedure is based on a modification of our controlled dc arc-discharge method. The carbon foils are of the multilayer type and the layers are composed of carbon particles emitted from the electrodes in the ac arc-discharge and from the cathode in the dc arc-discharge. With this simple and powerful method long lived carbon stripper foils can be prepared with higher reliability and reproducibility than with the previous procedure. (orig.)

Regeneration of an aqueous solution from an acid gas absorption process by matrix stripping

Science.gov (United States)

Rochelle, Gary T [Austin, TX; Oyenekan, Babatunde A [Katy, TX

2011-03-08

Carbon dioxide and other acid gases are removed from gaseous streams using aqueous absorption and stripping processes. By replacing the conventional stripper used to regenerate the aqueous solvent and capture the acid gas with a matrix stripping configuration, less energy is consumed. The matrix stripping configuration uses two or more reboiled strippers at different pressures. The rich feed from the absorption equipment is split among the strippers, and partially regenerated solvent from the highest pressure stripper flows to the middle of sequentially lower pressure strippers in a "matrix" pattern. By selecting certain parameters of the matrix stripping configuration such that the total energy required by the strippers to achieve a desired percentage of acid gas removal from the gaseous stream is minimized, further energy savings can be realized.

Liquid-film stripper for high-intensity heavy-ion beams

International Nuclear Information System (INIS)

Leemann, B.T.; Merrill, P.; Syversrud, H.K.; Wada, R.; Yourd, R.B.

1981-03-01

Electron strippers are widely used in heavy ion accelerators such as tandem Van de Graaff generators and heavy ion linacs. The SuperHILAC at Lawrence Berkeley Laboratory, employs a fluorocarbon oil vapor stripper at 113 keV/A for its high intensity injector ABEL, while after acceleration to 1.199 MeV/A a 35 μg/cm 2 carbon foil stripper is used. At present, the lifetime of these foils is about 1 hour for an 40 Ar beam of approx. 1 μA average particle current. With higher intensity high mass (100 less than or equal to A less than or equal to 238) beams available from ABEL injector the lifetime is expected to drop drastically and might be as low as one minute. A different approach to solve the stripper foil lifetime problem uses a thin free standing oil film spun from the edge of a sharp-edged rotating disc touching the surface of an oil reservoir. Areas of about 10 cm 2 with areal densities down to 20 μg/cm 2 have been reported. The work described here is based on the same concept, and produces a constantly regenerated, stable, free standing oil film of appropriate thickness for use at the SuperHILAC

Fabrication of versatile cladding light strippers and fiber end-caps with CO2 laser radiation

Science.gov (United States)

Steinke, M.; Theeg, T.; Wysmolek, M.; Ottenhues, C.; Pulzer, T.; Neumann, J.; Kracht, D.

2018-02-01

We report on novel fabrication schemes of versatile cladding light strippers and end-caps via CO2 laser radiation. We integrated cladding light strippers in SMA-like connectors for reliable and stable fiber-coupling of high-power laser diodes. Moreover, the application of cladding light strippers in typical fiber geometries for high-power fiber lasers was evaluated. In addition, we also developed processes to fuse end-caps to fiber end faces via CO2 laser radiation and inscribe the fibers with cladding light strippers near the end-cap. Corresponding results indicate the great potential of such devices as a monolithic and low-cost alternative to SMA connectors.

Techno-Economic Analysis of a Secondary Air Stripper Process

Energy Technology Data Exchange (ETDEWEB)

Heberle, J.R. [Electric Power Research Inst. (EPRI), Palo Alto, CA (United States); Nikolic, Heather [Center for Applied Energy Research, University of Kentucky, Lexington, KY (United States); Thompson, Jesse [Center for Applied Energy Research, University of Kentucky, Lexington, KY (United States); Liu, Kunlei [Center for Applied Energy Research, University of Kentucky, Lexington, KY (United States); Pinkerton, Lora L. [WorleyParsons, Reading, PA (United States); Brubaker, David [WorleyParsons, Reading, PA (United States); Simpson, James C. [WorleyParsons, Reading, PA (United States); Wu, Song [Mitsubishi Hitachi Power Systems America, Inc, Basking Ridge, NJ (United States); Bhown, Abhoyjit S. [Electric Power Research Inst. (EPRI), Palo Alto, CA (United States)

2017-08-22

We present results of an initial techno-economic assessment on a post-combustion CO2 capture process developed by the Center for Applied Energy Research (CAER) at the University of Kentucky using Mitsubishi Hitachi Power Systems’ H3-1 aqueous amine solvent. The analysis is based on data collected at a 0.7 MWe pilot unit combined with laboratory data and process simulations. The process adds a secondary air stripper to a conventional solvent process, which increases the cyclic loading of the solvent in two ways. First, air strips additional CO2 from the solvent downstream of the conventional steam-heated thermal stripper. This extra stripping of CO2 reduces the lean loading entering the absorber. Second, the CO2-enriched air is then sent to the boiler for use as secondary air. This recycling of CO2 results in a higher concentration of CO2 in the flue gas sent to the absorber, and hence a higher rich loading of the solvent exiting the absorber. A process model was incorporated into a full-scale supercritical pulverized coal power plant model to determine the plant performance and heat and mass balances. The performance and heat and mass balance data were used to size equipment and develop cost estimates for capital and operating costs. Lifecycle costs were considered through a levelized cost of electricity (LCOE) assessment based on the capital cost estimate and modeled performance. The results of the simulations show that the CAER process yields a regeneration energy of 3.12 GJ/t CO2, a $53.05/t CO2 capture cost, and LCOE of $174.59/MWh. This compares to the U.S. Department of Energy’s projected costs (Case 10) of regeneration energy of 3.58 GJ/t CO2 , a $61.31/t CO2 capture cost, and LCOE of $189.59/MWh. For H3-1, the CAER process results in a regeneration energy of 2.62 GJ/tCO2 with a stripper pressure of 5.2 bar, a capture cost of $46.93/t CO2, and an LCOE of $164.33/MWh.

Tests of prototype salt stripper system for IFR fuel cycle

International Nuclear Information System (INIS)

Carls, E.L.; Blaskovitz, R.J.; Johnson, T.R.; Ogata, T.

1993-01-01

One of the waste treatment steps for the on-site reprocessing of spent fuel from the Integral Fast Reactor fuel cycles is stripping of the electrolyte salt used in the electrorefining process. This involves the chemical reduction of the actinides and rare earth chlorides forming metals which then dissolve in a cadmium pool. To develop the equipment for this step, a prototype salt stripper system has been installed in an engineering scale argon-filled glovebox. Pumping trails were successful in transferring 90 kg of LiCl-KCl salt containing uranium and rare earth metal chlorides at 500 degree C from an electrorefiner to the stripper vessel at a pumping rate of about 5 L/min. The freeze seal solder connectors which were used to join sections of the pump and transfer line performed well. Stripping tests have commenced employing an inverted cup charging device to introduce a Cd-15 wt % Li alloy reductant to the stripper vessel

Preparation and investigation of diamond-like carbon stripper foils by filtered cathodic vacuum arc

International Nuclear Information System (INIS)

Fan, Qiwen; Du, Yinghui; Zhang, Rong; Xu, Guoji

2013-01-01

Thin diamond-like carbon (DLC) stripper foils ∼5μg/cm 2 in thickness were produced and evaluated as heavy-ion strippers for the Beijing HI-13 Tandem Accelerator. The DLC layers ∼4μg/cm 2 in thickness were produced by the filtered cathodic vacuum arc technology onto glass slides coated with betaine–saccharose as releasing agent, which were previously covered with evaporated carbon layers ∼1μg/cm 2 in thickness by the controlled ac arc-discharge method. Irradiation lifetimes of the DLC stripper foils were tested using the heavy-ion beams at the terminal of the Beijing HI-13 Tandem Accelerator, and compared with those of the standard carbon stripper foils made by the combined dc and ac arc-discharge method. The measurements indicate that the DLC stripper foils outlast the standard combined dc and ac arc-discharge carbon stripper foils by a factor of at least 13 and 4 for the 197 Au − (∼9MeV, ∼1μA) and 63 Cu − (∼9MeV, ∼1μA) ion beams, respectively. The structure and properties of the DLC foils deposited onto silicon substrates by the filtered cathodic vacuum arc technology were also evaluated and analyzed by scanning electron microscopy, Raman spectroscopy and X-ray photoelectron spectroscopy. The scanning electron microscopy images show that the DLC foils contain hardly droplets through the double 90° filters. The X-ray photoelectron spectrum indicates that sp 3 bonds of the DLC foils exceed 70%. The integral intensity ratio of the D peak to the G peak (I D /I G ) measured by the Raman spectroscopy is 0.78

Charge-state distribution measurements of ^{238}U and ^{136}Xe at 11  MeV/nucleon using gas charge stripper

Directory of Open Access Journals (Sweden)

H. Kuboki

2010-09-01

Full Text Available The charge-state distributions and equilibrium charge states of uranium (^{238}U and xenon (^{136}Xe ions at 11  MeV/nucleon were determined using a gas charge stripper. A differential pumping system facilitated the increase of the nitrogen gas thickness up to 1.3  mg/cm^{2}, which is sufficient for the most probable charge state to attain equilibrium. The charge states of ^{238}U attain equilibrium at 56.0, 56.6, and 55.7 in N_{2}, Ar, and CO_{2} media with thicknesses of 125, 79, and 126  μg/cm^{2}, respectively, while those of ^{136}Xe attain equilibrium at 40.5, 40.1, and 40.3 in N_{2}, Ar, and CO_{2} media with thicknesses of 163, 95, and 139  μg/cm^{2}, respectively. The equilibrium charge states of ^{136}Xe are acceptable for acceleration by the subsequent cyclotron. The measured data of ^{238}U were used to devise an empirical formula for the prediction of the equilibrium charge state in gaseous media over the energy region of 0.01–60  MeV/nucleon. The equilibrium charge state of ^{136}Xe as predicted by the devised formula is in good agreement with the data.

Production of thin carbon stripper foils using heated-substrates in a cathodic arc deposition system

International Nuclear Information System (INIS)

Merchant, A.R.; Lobanov, N.; Elliman, R.G.; Ophel, T.R.; Rode, A.; Weisser, D.C.; Turkentine, R.B.

1998-01-01

The lifetime of carbon stripper foil can have a marked impact on the successful running of a beam line. Standard techniques for production of carbon stripper foils include evaporation of carbon (ec) and laser-pulsed ablation (Ipa). Recent work by a using Ipa has been successful in substantially increasing the lifetime of a very thin foil. The suspected mechanism for the increased lifetime of the foil is that the amorphous carbon foil is density-matched to that of graphite (around 2.26g/cc). In this work, we attempt to reproduce this result by producing carbon stripper foils with a mass-density similar to graphite using a cathodic arc deposition system. The cathodic arc is well known for the production of tetrahedral amorphous carbon: a high density, high stress form of carbon with over 90% sp 3 -like bonds; to reduce the density of the carbon and promote more graphitic structure, a high bias was initially attempted but this proved unsuccessful. Another method is to use a heated-substrate holder to reduce compressive stress within the deposited film. The performance of the density-matched carbon stripper foils and the implications for future production of high-quality carbon stripper foils in our laboratory will be discussed. (authors)

Intense heavy ion beam-induced effects in carbon-based stripper foils

Energy Technology Data Exchange (ETDEWEB)

Kupka, Katharina

2016-08-15

Amorphous carbon or carbon-based stripper foils are commonly applied in accelerator technology for electron stripping of ions. At the planned facility for antiproton and ion research (FAIR) at the Helmholtzzentrum fuer Schwerionenforschung (GSI), Darmstadt, thin carbon stripper foils provide an option for directly delivering ions of intermediate charge states to the heavy ion synchrotron, SIS 18, in order to mitigate space charge limitations during high-intensity operation. In case of desired high end-energies in the synchrotron, a second stripping process by a thicker carbon foil provides ions of higher charge states for injection into the SIS18. High beam intensities and a pulsed beam structure as foreseen at FAIR pose new challenges to the stripper foils which experience enhanced degradation by radiation damage, thermal effects, and stress waves. In order to ensure reliable accelerator operation, radiation-hard stripper foils are required. This thesis aims to a better understanding of processes leading to degradation of carbon-based thin foils. Special focus is placed on ion-beam induced structure and physical property changes and on the influence of different beam parameters. Irradiation experiments were performed at the M3-beamline of the universal linear accelerator (UNILAC) at GSI, using swift heavy ion beams with different pulse lengths and repetition rates. Tested carbon foils were standard amorphous carbon stripper foils produced by the GSI target laboratory, as well as commercial amorphous and diamond-like carbon foils and buckypaper foils. Microstructural changes were investigated with various methods such as optical microscopy, scanning electron microscopy (SEM), profilometry and chromatic aberration measurements. For the investigation of structural changes X-ray photoelectron spectroscopy (XPS), Raman spectroscopy, high resolution transmission electron microscopy (HRTEM), in-situ Fourier-transform infrared spectroscopy (FTIR) and small angle X

Intense heavy ion beam-induced effects in carbon-based stripper foils

International Nuclear Information System (INIS)

Kupka, Katharina

2016-08-01

Amorphous carbon or carbon-based stripper foils are commonly applied in accelerator technology for electron stripping of ions. At the planned facility for antiproton and ion research (FAIR) at the Helmholtzzentrum fuer Schwerionenforschung (GSI), Darmstadt, thin carbon stripper foils provide an option for directly delivering ions of intermediate charge states to the heavy ion synchrotron, SIS 18, in order to mitigate space charge limitations during high-intensity operation. In case of desired high end-energies in the synchrotron, a second stripping process by a thicker carbon foil provides ions of higher charge states for injection into the SIS18. High beam intensities and a pulsed beam structure as foreseen at FAIR pose new challenges to the stripper foils which experience enhanced degradation by radiation damage, thermal effects, and stress waves. In order to ensure reliable accelerator operation, radiation-hard stripper foils are required. This thesis aims to a better understanding of processes leading to degradation of carbon-based thin foils. Special focus is placed on ion-beam induced structure and physical property changes and on the influence of different beam parameters. Irradiation experiments were performed at the M3-beamline of the universal linear accelerator (UNILAC) at GSI, using swift heavy ion beams with different pulse lengths and repetition rates. Tested carbon foils were standard amorphous carbon stripper foils produced by the GSI target laboratory, as well as commercial amorphous and diamond-like carbon foils and buckypaper foils. Microstructural changes were investigated with various methods such as optical microscopy, scanning electron microscopy (SEM), profilometry and chromatic aberration measurements. For the investigation of structural changes X-ray photoelectron spectroscopy (XPS), Raman spectroscopy, high resolution transmission electron microscopy (HRTEM), in-situ Fourier-transform infrared spectroscopy (FTIR) and small angle X

A new method for making long-lived carbon stripper foils

International Nuclear Information System (INIS)

Sugai, Isao; Ishii, Sabro; Hattori, Toshiyuki; Muto, Hideshi; Takahashi, Yohsuke; Kato, Hajime; Yamazaki, Kuniaki.

1989-01-01

We have developed a new method for preparation of long-lived carbon stripper foils, based on the modification of our 'controlled DC arc-discharge method'. The carbon foils consist of multi-layers, and carbon particles in each layer are emitted from the electrode in AC arc-discharge or from the cathode electrode in DC arc-discharge. The lifetimes of the carbon foils made by the new method are equal to or longer than those prepared by the controlled DC arc-discharge method. The new method is simple and powerful to make long-lived carbon stripper foils with higher reliability and reproducibility than the previous method. (author)

Removal and recovery of tritium from light and heavy water

International Nuclear Information System (INIS)

Butler, J.P.; Hammerli, M.

1979-01-01

A method and apparatus for removing tritium from light water are described, comprising contacting tritiated feed water in a catalyst column in countercurrent flow with hydrogen gas originating from an electrolysis cell so as to enrich this feed water with tritium from the electrolytic hydrogen gas and passing the tritium enriched water to an electrolysis cell wherein the electrolytic hydrogen gas is generated and then fed upwards through the catalyst column or recovered as product. The tritium content of the hydrogen gas leaving the top of the enricher catalyst column is further reduced in a stripper column containing catalyst which transfers the tritium to a countercurrent flow of liquid water. Anodic oxygen and water vapour from the anode compartment may be fed to a drier and condensed electrolyte recycled with a slip stream or recovered as a further tritium product stream. A similar method involving heavy water is also described. (author)

Modeling and experiment to threshing unit of stripper combine ...

African Journals Online (AJOL)

Modeling and experiment to threshing unit of stripper combine. ... were conducted with the different feed rates and drum rotator speeds for the rice stripped mixtures. ... and damage as well as for threshing unit design and process optimization.

Safety evaluation of the ITP filter/stripper test runs and quiet time runs using simulant solution. Revision 3

International Nuclear Information System (INIS)

Gupta, M.K.

1994-06-01

The purpose is to provide the technical bases for the evaluation of Unreviewed Safety Question for the In-Tank Precipitation (ITP) Filter/Stripper Test Runs (Ref. 7) and Quiet Time Runs Program (described in Section 3.6). The Filter/Stripper Test Runs and Quiet Time Runs program involves a 12,000 gallon feed tank containing an agitator, a 4,000 gallon flush tank, a variable speed pump, associated piping and controls, and equipment within both the Filter and the Stripper Building

All fiber cladding mode stripper with uniform heat distribution and high cladding light loss manufactured by CO2 laser ablation

Science.gov (United States)

Jebali, M. A.; Basso, E. T.

2018-02-01

Cladding mode strippers are primarily used at the end of a fiber laser cavity to remove high-power excess cladding light without inducing core loss and beam quality degradation. Conventional manufacturing methods of cladding mode strippers include acid etching, abrasive blasting or laser ablation. Manufacturing of cladding mode strippers using laser ablation consist of removing parts of the cladding by fused silica ablation with a controlled penetration and shape. We present and characterize an optimized cladding mode stripper design that increases the cladding light loss with a minimal device length and manufacturing time. This design reduces the localized heat generation by improving the heat distribution along the device. We demonstrate a cladding mode stripper written on a 400um fiber with cladding light loss of 20dB, with less than 0.02dB loss in the core and minimal heating of the fiber and coating. The manufacturing process of the designed component is fully automated and takes less than 3 minutes with a very high throughput yield.

Intense heavy ion beam-induced temperature effects in carbon-based stripper foils

International Nuclear Information System (INIS)

Kupka, K.; Tomut, M.; Simon, P.; Hubert, C.; Romanenko, A.; Lommel, B.; Trautmann, C.

2015-01-01

At the future FAIR facility, reliably working solid carbon stripper foils are desired for providing intermediate charge states to SIS18. With the expected high beam intensities, the foils experience enhanced degradation and limited lifetime due to severe radiation damage, stress waves, and thermal effects. This work presents systematic measurements of the temperature of different carbon-based stripper foils (amorphous, diamond-like, and carbon-nanotube based) exposed to 4.8 MeV/u U, Bi, and Au beams of different pulse intensities. Thermal and spectroscopic analyses were performed by means of infrared thermography and Fourier transform infrared spectroscopy. The resulting temperature depends on the foil thickness and strongly increases with increasing pulse intensity and repetition rate. (author)

Radiation lifetimes and failure mechanisms of carbon stripper foils

International Nuclear Information System (INIS)

Auble, R.L.

1981-01-01

Measurements of lifetimes of thin carbon foils under heavy-ion irradiation are compiled and recent advances in stripper foil technology are reviewed. The impact of recent foil lifetime improvements, many by more than an order of magnitude, on heavy-ion electrostatic accelerators is discussed. Foil inhomogeneities, particularly those caused by sputtering are suggested to be a prime factor in usable foil lifetimes

What is required for purification and processing of biogas to the natural gas standard?; Was brauchen wir zur Reinigung/Aufbereitung von Biogas zu Erdgasqualitaet

Energy Technology Data Exchange (ETDEWEB)

Tentscher, W. [eco Naturgas Handels GmbH, Berlin (Germany)

2002-07-01

The most common gas scrubbing process in Europe, i.e. the wet scrubbing process, is described. Preliminary stages are coarse filtering, coarse dehydration and coarse desulphurisation. Carbon dioxide and hydrogen sulphide are absorbed in counterflow in water at a pressure of 6 to 10 bar. The water can be generated by pressure relief and can be recirculated. Plant components like compressors, absorption column, strippers and dryers are gone into as well as the mode of operation and control. [German] Das europaweit zur Aufbereitung von Biogas am meisten genutzte Verfahren der nassen Gaswaesche wird beschrieben. Vorausgehende Reinigungsschritte des Biogases sind Grobfilterung, Grobentfeuchtung und Grobentschwefelung. Kohlendioxid und gleichzeitig H{sub 2}S werden im Gegenstrom unter Druck von 6 bis 10 bar in Wasser absorbiert. Das Wasser kann durch Entspannung regeneriert und im Kreislauf gefuehrt werden. Auf die Komponenten der Anlage wie Kompressor, Absorptionskolonne, Stripper und Trockner wird ebenso eingegangen wie auf die Betriebsfuehrung und Steuerung. (orig.)

Stripper, shut-in and orphan wells in joint operations

International Nuclear Information System (INIS)

Nixon, R.

1999-01-01

Low productivity wells, stripper wells, can be an excellent source of income to independent operators or small companies, but a serious financial burden for larger companies. Shut-in wells, for most companies, are either waiting on a market and production facilities, or represent deferred abandonment liabilities. Orphan wells also reflect financial distress. The firm, Cord Oil and Gas Management Ltd., was formed in 1986 to specifically assist oil and gas companies, sophisticated investors and financial institutions with the management, enhancement and disposition of non-core or low productivity assets. This type of production, depending on the number of wells and cumulative production, can be the life blood of a small organization or a serious drain on the administrative personnel and financial resources of larger organizations. Philosophically, industry and/or government needs to manage the eventuality of abandonments by establishing financial criteria. Some suggestions for industry include: (1) establish provisions within joint operating agreements to set aside an abandonment and environmental cleanup fund; (2) minimize the inventory of abandonment candidates by an ongoing program of reclamation; (3) offset abandonment costs with salvage value of tangible equipment under AFE approval; and (4) voluntarily restrict transfer abandonment liabilities with producing assets on a selective basis. Some suggestions for governments include: (1) fund the orphan well by a deposit for every well drilled; (2) restrict the transfer of liabilities for abandoned and inactive wells by ensuring that the transferee is financially capable; and (3) access the chain of title to ensure non-operators remain responsible for the proportionate shares of abandonment and cleanup costs

Tandem accelerator transmission and life measurement of 50 keV/amu Au ions using stripper foil made by INS

Energy Technology Data Exchange (ETDEWEB)

Ishii, Satoshi; Takahashi, Tsutomu; Shima, Kunihiro [Tsukuba Univ., Ibaraki (Japan). Tandem Accelerator Center; Sugai, Isamu; Oyaizu, Mitsuhiro

1996-12-01

The role of stripper foil is the charge exchange of ions. The thickness for attaining equilibrium in charge exchange becomes thinner as ions become lower speed and heavier. Accordingly, for the stripper foil, thin foil thickness is demanded in addition to the demand of long life. The stripper foil made by INS, University of Tokyo, is recognized as its long life. In the 12 UD PELETRON tandem accelerator in University of Tsukuba, in order to meet the demand of users to use heavy ions, the use of long life stripper foil has become urgent necessity. Therefore, as for the foil made by INS, the life by Au ion irradiation and the Au ion transmission were measured four times. As to the features of the test of this time, irradiation was carried out under the severe condition for the foil of low speed Au ions, and the change of beam transmission with time lapse was observed in addition to the life. The method of measurement is explained. The preparation of foils and the determination of their thickness are reported. As the results, the lifetime of the foils made by INS and the thickness dependence and time dependence or dose dependence of the transmission of low speed, heavy Au-197 ions are described. (K.I.)

Treatment of H0 and H- beams spilled at the stripper foil at full energy charge-exchange injection scheme

International Nuclear Information System (INIS)

Yamane, Isao

1991-01-01

The charge-exchange injection into a synchrotron to generate high-intensity pulsed proton beams for a spallation neutron source is reviewed while focusing on the treatment of H 0 and H - beams spilled at the stripper foil. After charge-exchange injection is briefly outlined, scattering by foil atoms and causes to spill H 0 and H - beams are described. These spilled beams can amount to several μA and should be carefully treated. It is then shown that a direct H - injection system needs to be considerably long and requires a very long straight section. Because of its simplicity, two-step H 0 injection has very wide applicability to various types of rings. However, it has a problem of emittance growth due to angular divergence in the stripper magnet and an ionoptical mismatch at the stripper foil. These problems are discussed, including a new proposal for a measure to remedy this problem. The laser photoionization injection is also briefly mentioned. (author)

A convenient way to double the capacity of a NEC type foil stripper

International Nuclear Information System (INIS)

Chapman, K.R.

1988-01-01

A convenient method is described to increase the capacity of a NEC type terminal stripper. This renders the necessity for tank entry to renew foils less frequent. This is especially useful when the use of heavy ion beams renders foil lifetimes very short. (orig.)

The stripper design and test at HIRFL-CSR

International Nuclear Information System (INIS)

Zhang Hongbin; Xiao Guoqing; Yuan Youjin; Xu Hushan; Li Zhankui; Lu Ziwei; Mao Ruishi; Zhao Tiecheng

2010-01-01

Charge stripping is employed to produce multi-charged ions for injecting the cooling storage ring. After penetrating through the carbon foil, the widened distribution of ion charge states poses a limit to the ion injection. Therefore, the carbon foil plays a key role in the charge stripping injection. In this paper,four strippers for Heavy Ion Research Facility at Lanzhou (HIRFL) and Cooling Storage Ring (CSR) are introduced. The charge state distribution of the stripped ions is measured and the stripping efficiency of the foils is investigated. The experimental results are consistent with the theoretical values. (authors)

Water recovery from flue gas

Energy Technology Data Exchange (ETDEWEB)

Heijboer, R.; Van Deelen-Bremer, M.H.; de Vos, F.; Zeijseink, A.G.L. [KEMA Nederland B.V. (Netherlands)

2007-07-01

In the power generation process a large amount of water is needed, for steam generation, flue gas cleaning etc. On the other hand a large amount of water is emitted to the atmosphere via the stack. For example a 400 MW coal fired power plant with a flue gas desulfurisation plant emits about 1,500,000 m{sup 3} per hour with a water concentration of about 11%. The emitted water has a rather good quality compared to surface water and needs less effort to be treated for use as make-up water. As the available amount of water in the flue gas from the earlier mentioned power plant is about 150 tons per hour, recovering 20% of this amount covers the make-up water needs of this 400 MW power plant. Direct condensation of the flue gas needs large cooling power and the condensed water is acidic and corrosive and needs cleanup treatment before it can be used in the water/steam cycle. KEMA developed a technology based on gas separation membranes which makes it possible to recover water from flue gas. The process is covered by a wide patent. The principle of the membrane is comparable to the material that is used in fabric like SympaTex{reg_sign} and GORE-TEX{reg_sign}. The GORE-TEX material is permeable to water vapor but rejects liquid water. The driving force is the water vapor pressure close to the human skin which is the higher than the water vapor pressure open the outside of the clothing. The selectivity of the GORE-TEX material however is not good enough to be used at the temperature of flue gas. The University of Twente (Netherlands) developed a membrane material based on modified PEEK which is highly selective of water vapor at flue gas temperatures. Based on the fact that flat membranes have an uneconomical surface to volume ratio, the choice has been made to use hollow fibre membranes. 6 figs.

Life cycle water consumption for shale gas and conventional natural gas.

Science.gov (United States)

Clark, Corrie E; Horner, Robert M; Harto, Christopher B

2013-10-15

Shale gas production represents a large potential source of natural gas for the nation. The scale and rapid growth in shale gas development underscore the need to better understand its environmental implications, including water consumption. This study estimates the water consumed over the life cycle of conventional and shale gas production, accounting for the different stages of production and for flowback water reuse (in the case of shale gas). This study finds that shale gas consumes more water over its life cycle (13-37 L/GJ) than conventional natural gas consumes (9.3-9.6 L/GJ). However, when used as a transportation fuel, shale gas consumes significantly less water than other transportation fuels. When used for electricity generation, the combustion of shale gas adds incrementally to the overall water consumption compared to conventional natural gas. The impact of fuel production, however, is small relative to that of power plant operations. The type of power plant where the natural gas is utilized is far more important than the source of the natural gas.

Shale gas: the water myth

Energy Technology Data Exchange (ETDEWEB)

O' Shea, Kerry [Dillon Consulting Limited (Canada)

2010-07-01

In recent years, due to the depletion of traditional fossil fuel resources and the rising price of energy, production from unconventional gas activities has increased. Large shale gas plays are available in Quebec but environmental concerns, mainly in terms of water resources, have been raised. The aim of this paper is to provide information on the impact of shale gas exploitation on water resources. It is shown herein that shale gas water use is not significant, the water use of 250 wells represents only 0.3% of the Quebec pulp and paper industry's water use, or 0.0004% of the flow of the St Lawrence. It is also shown that the environmental risk associated with fracking and drilling activities is low. This paper demonstrated that as long as industry practices conform to a well-designed regulatory framework, shale gas development in Quebec will have a low impact on water resources and the environment.

Stripper foil failure modes and cures at the Oak Ridge Spallation Neutron Source

Directory of Open Access Journals (Sweden)

M. A. Plum

2011-03-01

Full Text Available The Oak Ridge Spallation Neutron Source comprises a 1 GeV, 1.5 MW linear accelerator followed by an accumulator ring and a liquid mercury target. To manage the beam loss caused by the H^{0} excited states created during the H^{-} charge-exchange injection into the accumulator ring, the stripper foil is located inside one of the chicane dipoles. This has some interesting consequences that were not fully appreciated until the beam power reached about 840 kW. One consequence was sudden failure of the stripper foil system due to convoy electrons stripped from the incoming H^{-} beam, which circled around to strike the foil bracket and cause bracket failure. Another consequence is that convoy electrons can reflect back up from the electron catcher and strike the foil and bracket. An additional contributor to foil system failure is vacuum breakdown due to the charge developed on the foil by secondary electron emission. In this paper we detail these and other interesting failure mechanisms and describe the improvements we have made to mitigate them.

Water into gas

International Nuclear Information System (INIS)

Woodord, Julian.

1997-01-01

This article examines the move by water utilities into the gas market and potentially into the electricity supply market. Operation by Dee Valley Holdings, York Waterworks, York Gas, and North Wales Gas are reported, and investment, use of mail campaigns and telemarketing to secure customers, and the opportunities offered by diversification are considered. (UK)

NONPROCESS SOLVENT USE IN THE FURNITURE REFINISHING AND REPAIR INDUSTRY: EVALUATION OF ALTERNATIVE CHEMICAL STRIPPERS

Science.gov (United States)

The report gives results of an evaluation of the feasibility of using alternatives to high volatile organic compound/hazardous air pollutant (VOC/HAP) solvent-based, chemical strippers that are currently used in the furniture repair and refinishing industry to remove both traditi...

Gas in your water well

International Nuclear Information System (INIS)

2011-03-01

In Alberta, the presence of carbon dioxide, methane or hydrogen sulphide in water wells is common. The aim of this paper is to provide information to private owners of water wells. It is stated in this document that spurting taps or a gurgling noise indicate that there is gas in your water well; you can determine which gas it is by collecting a sample and having it analyzed. In order to address the risks associated with the presence of gas in the water well, the well pit or well pump should be properly vented to avoid any oxygen deficiency in the atmosphere. It is also possible to get rid of the gas by lowering the pump intake. It is also mentioned that the development of coalbed methane in Alberta should not contaminate private wells since regulations aimed at avoiding this have been implemented. This paper provided useful information to help private owners manage the presence of gas in their water wells.

Influence and efficiency of catalytic stripper in organic carbon removal from laboratory generated soot aerosols

Science.gov (United States)

A catalytic stripper (CS) is a device used to remove the semi-volatile, typically organic carbon, fraction by passing raw or diluted exhaust over an oxidation catalyst heated to 300˚C. The oxidation catalyst used in this study is a commercially available diesel oxidation ca...

Preliminary study on application of Pd composite membrane in helium purification system of high-temperature gas-cooled reactor

International Nuclear Information System (INIS)

Cai Jianhua; Yang Xiaoyong; Wang Jie; Yu Suyuan

2008-01-01

Helium purification system (HPS) is the main part of the helium auxiliary system of high-temperature gas-cooled reactors (HTGR), also in fusion reactors. Some exploratory work was carried out on the application of Pd composite membrane in the separation of He and H 2 . A typical single stripper permeator with recycle (SSP) system was designed, based on the design parameters of a small scale He purification test system CIGNE in CADARACHE, CEA, France, and finite element analysis method was used to solve the model. The total length of membrane module is fixed to 0.5 m. The results show that the concentration of H 2 is found to reduce from 1 000 μL/L in feed gas to 5 μL/L in the product He (the upper limitation of HPS in HTGR). And the molar ratio of product He to feed gas is 96.18% with the optimized ratio of sweep gas to retentive gas 0. 3970. It's an exponential distribution of H 2 concentration along the membrane module. The results were also compared with the other two popular designs, two stripper in series permeator (TSSP) and continuous membrane column (CMC). (authors)

Development of stripper films made of high strength, long life carbon nitride

International Nuclear Information System (INIS)

Oyaizu, Mitsuhiro; Sugai, Isamu; Yoshida, Koji; Haruyama, Yoichi.

1994-01-01

The heavy ion accelerators such as tandem type van de Graaff, linear accelerators, cyclotrons and so on raise the acceleration efficiency usually by producing multivalent ions by making the charge conversion of heavy ions using carbon thin films. However, when the electrons of large atomic number ions of low energy, high intensity current are stripped, the conventional carbon thin films on the market or home made were very short in their life, and have become the cause of remarkably lowering the acceleration efficiency. The concrete objectives of the development are the use of the charge conversion of unstable nuclear ions in the E arena accelerator for JHP of the future project of Institute of Nuclear Study and the manufacture of the carbon films which are used for the charge conversion of the H beam of high energy, but at the time of exchanging the films, there is the problem of the radiation exposure of large amount, therefore, the development of high reliability, long life stripper films has been strongly demanded. The experiment was carried out by controlled carbon arc discharge process using both AC and DC and the ion beam sputtering process using reactive nitrogen gas. The results are reported. (K.I.)

30 CFR 210.155 - What reports must I submit for Federal onshore stripper oil properties?

Science.gov (United States)

2010-07-01

... Minerals Management Service, P.O. Box 25165, MS 392B2, Denver, Colorado 80217-0165; or (ii) Special courier... 30 Mineral Resources 2 2010-07-01 2010-07-01 false What reports must I submit for Federal onshore stripper oil properties? 210.155 Section 210.155 Mineral Resources MINERALS MANAGEMENT SERVICE, DEPARTMENT...

Results from trialling aqueous NH{sub 3} based post combustion capture in a pilot plant at Munmorah power station. Desorption

Energy Technology Data Exchange (ETDEWEB)

Yu, Hai; Morgan, Scott; Allport, Andrew; Cottrell, Aaron; Do, Thong; McGregor, James; Wardhaugh, Leigh; Feron, Paul [CSIRO Energy Centre, Mayfield West, NSW (Australia)

2013-07-01

Australia's Commonwealth Scientific and Industrial Research Organization (CSIRO) and Delta Electricity have tested an aqueous ammonia based post combustion capture (PCC) process in a pilot plant at Munmorah black coal fired power station. This paper presents and discusses the experimental results obtained and primarily focuses on the desorption section. A high purity of CO{sub 2} product was obtained at the stripper gas outlet with the CO{sub 2} volumetric concentration generally between 99-100% and the remainder being water and NH{sub 3}. An increase in stripper pressure/temperature can lead to a decrease in NH{sub 3} concentration in the CO{sub 2} product. The NH{sub 3} concentration can be controlled within 200 ppm without wash at a stripper pressure of 850 kPa (the maximum pressure tested) at a stripper gas outlet temperatures of 20-25 C. The solid precipitation occurred in the stripper condenser and reflux lines. Due to the low ammonia content in the solution, CO{sub 2} content in the solution was low and generally more than 50% of regeneration energy was used to heat up the solvent under the pilot plant conditions. The lowest regeneration energy obtained from the pilot plant trials is 4-4.2 MJ/kg CO{sub 2} captured. The effect of various parameters including solvent flow-rate and stripper temperature/pressure in the solvent on the regeneration energy was investigated.

Safety evaluation of the ITP filter/stripper test runs and quiet time runs using simulant solution

International Nuclear Information System (INIS)

Gupta, M.K.

1993-10-01

In-Tank Precipitation is a process for removing radioactivity from the salt stored in the Waste Management Tank Farm at Savannah River. The process involves precipitation of cesium and potassium with sodium tetraphenylborate (STPB) and adsorption of strontium and actinides on insoluble sodium titanate (ST) particles. The purpose of this report is to provide the technical bases for the evaluation of Unreviewed Safety Question for the In-Tank Precipitation (ITP) Filter/Stripper Test Runs and Quiet Time Runs Program. The primary objective of the filter-stripper test runs and quiet time runs program is to ensure that the facility will fulfill its design basis function prior to the introduction of radioactive feed. Risks associated with the program are identified and include hazards, both personnel and environmental, associated with handling the chemical simulants; the presence of flammable materials; the potential for damage to the permanenet ITP and Tank Farm facilities. The risks, potential accident scenarios, and safeguards either in place or planned are discussed at length

Safety evaluation of the ITP filter/stripper test runs and quiet time runs using simulant solution

Energy Technology Data Exchange (ETDEWEB)

Gupta, M.K.

1993-10-01

In-Tank Precipitation is a process for removing radioactivity from the salt stored in the Waste Management Tank Farm at Savannah River. The process involves precipitation of cesium and potassium with sodium tetraphenylborate (STPB) and adsorption of strontium and actinides on insoluble sodium titanate (ST) particles. The purpose of this report is to provide the technical bases for the evaluation of Unreviewed Safety Question for the In-Tank Precipitation (ITP) Filter/Stripper Test Runs and Quiet Time Runs Program. The primary objective of the filter-stripper test runs and quiet time runs program is to ensure that the facility will fulfill its design basis function prior to the introduction of radioactive feed. Risks associated with the program are identified and include hazards, both personnel and environmental, associated with handling the chemical simulants; the presence of flammable materials; the potential for damage to the permanenet ITP and Tank Farm facilities. The risks, potential accident scenarios, and safeguards either in place or planned are discussed at length.

Amine Solvent Regeneration for CO2 Capture Using Geothermal Energy with Advanced Stripper Configurations

International Nuclear Information System (INIS)

Van Wagener, D.H.; Rochelle, G.T.; Gupta, A.; Bryant, S.L.

2014-01-01

Absorption/stripping using alkanol-amine solvents for removing CO 2 from the flue gas of coal-fired power plants requires a substantial amount of energy. Typical designs anticipate the use of steam extraction between the Intermediate Pressure (IP) and Low Pressure (LP) turbines to provide heat for the re-boiler. Geothermal energy in the form of hot brine offers an alternative to this large parasitic load on the power generation cycle. We investigate the requirements (number and spacing of extraction/injection well pairs) to provide heat at 150 deg. C for a pilot scale (60 MWe) and a full scale (900 MWe) capture process for thirty years. The calculations are based on properties of a geopressured/geothermal aquifer near the Texas Gulf Coast. In the vicinity of a large coal-fired power plant in South Texas, this aquifer lies between 3 050 and 3 350 m (10 000 and 11 000 ft) below the surface. We present a novel design of the stripper/regenerator process based on heat exchange with the brine, discharging the brine at 100 deg. C. The results indicate that the overall process is feasible and that costs are of similar magnitude to standard designs. (authors)

Geochemical evidence of water-soluble gas accumulation in the Weiyuan gas field, Sichuan Basin

Directory of Open Access Journals (Sweden)

Shengfei Qin

2016-01-01

Full Text Available At present, there are several different opinions on the formation process of the Weiyuan gas field in the Sichuan Basin and the source of its natural gas. In view of the fact that the methane carbon isotope of the natural gas in the Weiyuan gas field is abnormally heavy, the geologic characteristics of gas reservoirs and the geochemical characteristics of natural gas were first analyzed. In the Weiyuan gas field, the principal gas reservoirs belong to Sinian Dengying Fm. The natural gas is mainly composed of methane, with slight ethane and trace propane. The gas reservoirs are higher in water saturation, with well preserved primary water. Then, it was discriminated from the relationship of H2S content vs. methane carbon isotope that the heavier methane carbon isotope of natural gas in this area is not caused by thermochemical sulfate reduction (TSR. Based on the comparison of methane carbon isotope in this area with that in adjacent areas, and combined with the tectonic evolution background, it is regarded that the natural gas in the Weiyuan gas field is mainly derived from water-soluble gas rather than be migrated laterally from adjacent areas. Some conclusions are made. First, since methane released from water is carbon isotopically heavier, the water-soluble gas accumulation after degasification results in the heavy methane carbon isotope of the gas produced from Weiyuan gas field. Second, along with Himalayan movement, great uplift occurred in the Weiyuan area and structural traps were formed. Under high temperature and high pressure, the gas dissolved in water experienced decompression precipitation, and the released natural gas accumulated in traps, consequently leading to the formation of Weiyuan gas field. Third, based on calculation, the amount of natural gas released from water which is entrapped in the Weiyuan gas field after the tectonic uplift is basically equal to the proved reserves of this field, confirming the opinion of water

Emittance measurements at the new UNILAC-pre-stripper using a pepper-pot with a PC-controlled CCD-camera

CERN Document Server

Dolinska, M E; Forck, P; Hoffmann, T; Liakin, D; Peters, A; Strehl, P

2000-01-01

The complex mathematical algorithms and procedures to extract emittance data from intensity distributions measured with a single shot pepper-pot device are described. First results of mathematical evaluation from the commissioning of the new GSI pre-stripper linac structures are presented.

Comparison of a wire belt conveyor and cross auger conveyor for conveying burr cotton on a stripper harvester

Science.gov (United States)

Cotton fiber quality begins to degrade naturally with the opening of the boll, and mechanical harvesting processes are perceived to exacerbate fiber degradation. Previous research indicates that stripper-harvested cotton generally has lower fiber quality including on average lower micronaire, length...

Formation of gas bubbles in gas superheated water

International Nuclear Information System (INIS)

Finkelstein, Y.

1984-05-01

The phenomenon of bubbles formation in supersaturated solutions of gases in water is a transport process, the final result of which is a separation of phases. In spite of its widespread appearance in industry and in nature, no model exists that can explain it and predict the degree of supersaturation which a gas-water solution can tolerate before bubbles are formed. The objective of this study was to fill this gap, and indeed, an extensive experimental work was carried out, a model was established and simple but accurate means were developed for predicting the tolerable degree of supersaturation of gas-water solutions. The model is also capable of predicting quite accurately the activation phenomenon in water. Superheating and supercooling phenomena were also examined in the light of the new model. (author)

75 FR 61624 - Promotion of Development, Reduction of Royalty Rates for Stripper Well and Heavy Oil Properties

Science.gov (United States)

2010-10-06

...-241A.00] RIN 1004-AE04 Promotion of Development, Reduction of Royalty Rates for Stripper Well and Heavy... economy, productivity, competition, jobs, the environment, public health or safety, or State, local, or..., investment, productivity, innovation, or the ability of U.S.-based enterprises to compete with foreign-based...

The charge state distribution of Be, C, Cl and Al ions at the Lund Pelletron accelerator with the recently modified terminal pumping in use

International Nuclear Information System (INIS)

Kiisk, Madis; Hellborg, Ragnar; Persson, Per; Faarinen, Mikko; Skog, Goeran; Stenstroem, Kristina

2004-01-01

Some years ago terminal pumping for the gas stripper system at the 3 MV Lund Tandem Pelletron accelerator was installed and charge state distribution measurements using the new installation were reported. Since then, new modifications of the mechanical design of the stripper system have been made. The results of pressure profile measurements as well as the results of charge state distribution measurements in a N 2 and Ar gas stripper at different, new geometrical modifications of the stripper system using C, Be, Al and Cl ion beams are reported. A comparison between pressure profiles obtained for different geometries shows a clear improvement of the vacuum conditions outside the stripper housing for the smallest conductance pipes between the stripper system and the accelerator tubes. These improvements are also well reflected in the charge state distribution measurements, as a higher mean charge state is obtained under the same vacuum conditions in the accelerator tubes for the improved stripper system in comparison with the former mechanical design

Advanced treatment of flue gas condensate; Avancerad rening av roekgaskondensat

Energy Technology Data Exchange (ETDEWEB)

Axby, Fredrik [Carl Bro Energikonsult AB, Malmoe (Sweden); Ekengren, Oesten; Bjurhem, Jan Erik [IVL Swedish Environmental Research Inst. (Sweden)

2004-11-01

The aim of the project is to study different techniques to recover water to the process and to reduce emission of ammonia to water and air. Membrane technology (ultra- (UF) and nanofiltration (NF) and reverse osmosis (RO)) and a stripper have been studied for ammonia separation. The use of bio-fuel in energy production is increasing. The off-gases are often condensed to increase energy yield and to decrease emissions to air. Since the concentration of nitrogen (ammonium) is high in condensates from units with SNCR for NO{sub x}-reduction (selective non-catalytic reduction) this water has to be treated further. Another aim of the project is to replace a great part of the tap water used in the process. This can be accomplished with membrane technology. Laboratory tests revealed a certain degree of membrane fouling. However, both NF and RO worked well in the full-scale unit, in spite of problems in the condensate treatment that resulted in tar products in the water. There was no obvious negative effect on these membranes. Analyses of PAH have shown a low base concentration that may lead to fouling after a long time. UF removes most of these PAH and thus protects the following NF- or RO-membranes. NF gave about 3 times higher filtration capacity (flux) than RO for the condensate at 30 bars. This can save a lot of money, since the membrane area can be reduced to a third. High temperature also increases the flux. The results are of high interest but ought to be certified during long run tests. Fouling was low in both NF and RO, and initial flux was retained after cleaning. The reason is probably the good pre-treatment (UF). The concentration could proceed very far, which make it possibly to reuse the concentrate to the system. Simulations of an ammonia stripper showed some parameters to be critical in certain ranges, while others didn't affect the result. Airflow is a critical parameter during stable conditions within the design data. Simulated data were verified

Separation of water through gas hydrate formation

DEFF Research Database (Denmark)

Boch Andersen, Torben; Thomsen, Kaj

2009-01-01

Gas hydrate is normally recognized as a troublemaker in the oil and gas industry. However, gas hydrate has some interesting possibilities when used in connection with separation of water. Nordic Sugar has investigated the possibility of using gas hydrates for concentration of sugar juice. The goal...... of the project was to formulate an alternative separation concept, which can replace the traditional water evaporation process in the sugar production. Work with the separation concept showed that gas hydrates can be used for water separation. The process is not suitable for sugar production because of large...... volumes and the needs for high pressure. The process could be interesting for concentration of heat sensitive, high value products...

Assessment of a Hybrid Retrofit Gas Water Heater

Energy Technology Data Exchange (ETDEWEB)

Hoeschele, Marc [Davis Energy Group, Davis, CA (United States); Weitzel, Elizabeth [Davis Energy Group, Davis, CA (United States); Backman, Christine [Davis Energy Group, Davis, CA (United States)

2017-02-28

This project completed a modeling evaluation of a hybrid gas water heater that combines a reduced capacity tankless unit with a downsized storage tank. This product would meet a significant market need by providing a higher efficiency gas water heater solution for retrofit applications while maintaining compatibility with the 1/2 inch gas lines and standard B vents found in most homes. The TRNSYS simulation tool was used to model a base case 0.60 EF atmospheric gas storage water, a 0.82 EF non-condensing gas tankless water heater, an existing (high capacity) hybrid unit on the market, and an alternative hybrid unit with lower storage volume and reduced gas input requirements. Simulations were completed under a 'peak day' sizing scenario with 183 gpd hot water loads in a Minnesota winter climate case. Full-year simulations were then completed in three climates (ranging from Phoenix to Minneapolis) for three hot water load scenarios (36, 57, and 96 gpd). Model projections indicate that the alternative hybrid offers an average 4.5% efficiency improvement relative to the 0.60 EF gas storage unit across all scenarios modeled. The alternative hybrid water heater evaluated does show promise, but the current low cost of natural gas across much of the country and the relatively small incremental efficiency improvement poses challenges in initially building a market demand for the product.

Assessment of a Hybrid Retrofit Gas Water Heater

Energy Technology Data Exchange (ETDEWEB)

Hoeschele, Marc [Alliance for Residential Building Innovation (ARBI), Davis, CA (United States); Weitzel, Elizabeth [Alliance for Residential Building Innovation (ARBI), Davis, CA (United States); Backman, Christine [Alliance for Residential Building Innovation (ARBI), Davis, CA (United States)

2017-02-01

This project completed a modeling evaluation of a hybrid gas water heater that combines a reduced capacity tankless unit with a downsized storage tank. This product would meet a significant market need by providing a higher efficiency gas water heater solution for retrofit applications while maintaining compatibility with the 1/2 inch gas lines and standard B vents found in most homes. The TRNSYS simulation tool was used to model a base case 0.60 EF atmospheric gas storage water, a 0.82 EF non-condensing gas tankless water heater, an existing (high capacity) hybrid unit on the market, and an alternative hybrid unit with lower storage volume and reduced gas input requirements. Simulations were completed under a 'peak day' sizing scenario with 183 gpd hot water loads in a Minnesota winter climate case. Full-year simulations were then completed in three climates (ranging from Phoenix to Minneapolis) for three hot water load scenarios (36, 57, and 96 gpd). Model projections indicate that the alternative hybrid offers an average 4.5% efficiency improvement relative to the 0.60 EF gas storage unit across all scenarios modeled. The alternative hybrid water heater evaluated does show promise, but the current low cost of natural gas across much of the country and the relatively small incremental efficiency improvement poses challenges in initially building a market demand for the product.

Shale Gas Development and Drinking Water Quality.

Science.gov (United States)

Hill, Elaine; Ma, Lala

2017-05-01

The extent of environmental externalities associated with shale gas development (SGD) is important for welfare considerations and, to date, remains uncertain (Mason, Muehlenbachs, and Olmstead 2015; Hausman and Kellogg 2015). This paper takes a first step to address this gap in the literature. Our study examines whether shale gas development systematically impacts public drinking water quality in Pennsylvania, an area that has been an important part of the recent shale gas boom. We create a novel dataset from several unique sources of data that allows us to relate SGD to public drinking water quality through a gas well's proximity to community water system (CWS) groundwater source intake areas.1 We employ a difference-in-differences strategy that compares, for a given CWS, water quality after an increase in the number of drilled well pads to background levels of water quality in the geographic area as measured by the impact of more distant well pads. Our main estimate finds that drilling an additional well pad within 1 km of groundwater intake locations increases shale gas-related contaminants by 1.5–2.7 percent, on average. These results are striking considering that our data are based on water sampling measurements taken after municipal treatment, and suggest that the health impacts of SGD 1 A CWS is defined as the subset of public water systems that supplies water to the same population year-round. through water contamination remains an open question.

Charge state distributions for heavy ions in carbon stripper foils

International Nuclear Information System (INIS)

McMahan, M.A.; Lebed, R.F.; Feinberg, B.

1989-03-01

We have extended the database of measured charge state distributions available in the literature through measurements at the SuperHILAC using carbon stripper foils in the energy range 1.2--8.5 MeV/u. Modifying a semi-empirical model to include the effect of electronic shells, we are able to correctly predict the mean charge state to within 1/2 a charge state for 6≤Z≤92 and energies from 30 keV/u to 16 MeV/u. We have determined parameters for the widths of the distributions for each electronic shell. For distributions lying across a shell boundary, we join the two Gaussians of different widths to get an asymmetric distribution. 18 refs., 4 figs., 2 tabs

Kilowatt-level cladding light stripper for high-power fiber laser.

Science.gov (United States)

Yan, Ping; Sun, Junyi; Huang, Yusheng; Li, Dan; Wang, Xuejiao; Xiao, Qirong; Gong, Mali

2017-03-01

We designed and fabricated a high-power cladding light stripper (CLS) by combining a fiber-etched CLS with a cascaded polymer-recoated CLS. The etched fiber reorganizes the numerical aperture (NA) distribution of the cladding light, leading to an increase in the leakage power and a flatter distribution of the leakage proportion in the cascaded polymer-recoated fiber. The index distribution of the cascaded polymer-recoated fiber is carefully designed to ensure an even leakage of cladding light. More stages near the index of 1.451 are included to disperse the heat. The CLS is capable of working consistently under 1187 W of cladding light with an attenuation of 26.59 dB, and the highest local temperature is less than 35°C.

Carbon stripper foils held in place with carbon fibers

International Nuclear Information System (INIS)

Jolivet, Connie S.; Miller, Shawn A.; Stoner, John O.; Ladd, Peter

2008-01-01

The Spallation Neutron Source (SNS) currently under construction at Oak Ridge National Laboratory, Oak Ridge, Tennessee, is planned to initially utilize carbon stripper foils having areal densities approximately 260 μg/cm 2 . The projected design requires that each foil be supported by only one fixed edge. For stability of the foil, additional support is to be provided by carbon fibers. The feasibility of manufacturing and shipping such mounted carbon foils produced by arc evaporation was studied using two prototypes. Production of the foils is described. Fibers were chosen for satisfactory mechanical strength consistent with minimal interference with the SNS beam. Mounting of the fibers, and packaging of the assemblies for shipping are described. Ten completed assemblies were shipped to SNS for further testing. Preliminary evaluation of the survivability of the foils in the SNS foil changer is described

Surface treatment of glass substrates for the preparation of long-lived carbon stripper foils

International Nuclear Information System (INIS)

Takeuchi, Suehiro; Takekoshi, Eiko

1981-02-01

Glass substrates having uniformly distributed microscopic grains on the surfaces are useful to make long-lived carbon stripper foils for heavy ions. A method of surface treatment of glass substrates to form the surface structure is described. This method consists of precipitation of glass components, such as soda, onto the surfaces in a hot and humid atmosphere and a fogging treatment of forming microscopic grains of the precipitated substances. Some results of studies on the treatment conditions are also presented. (author)

Gas consumption for water heating in the Netherlands

International Nuclear Information System (INIS)

Bos, R.; Weegink, R.

1995-01-01

In 1994 the total gas consumption of Dutch households increased slightly. This is mainly due to an increase in the number of occupied homes by about 75,000, an advancing penetration of gas-fired tap water heaters and a marginal increase in gas consumption for space heating. Another striking feature is the stabilisation of gas consumption of an average household for hot water purposes, since it decreased in 1992 and 1993 by 3% and 4,5% respectively. The so-called Dutch BAK (basic survey of the small-scale gas consumption) study also shows that the penetration of gas appliances with higher outputs and changing water tapping behaviour, the major reasons for consumption increases in the previous years, have changed only moderately. Gas consumption for cooking purposes remained almost stable, though. 7 tabs., 1 ill

The compact 14C AMS facility of Paleo Labo Co., Ltd., Japan

International Nuclear Information System (INIS)

Kobayashi, Koichi; Niu, Etsuko; Itoh, Shigeru; Yamagata, Hideki; Lomtatidze, Zaur; Jorjoliani, Ineza; Nakamura, Kentaro; Fujine, Hisashi

2007-01-01

A compact AMS system was installed by a private company in Japan for a 14 C dating business. Since this system was designed to be very compact with a low voltage accelerator, it has unique features compared to larger AMS systems. For example, the stripper gas pressure has to be maintained at a high level to dissociate molecular ions. However, it cannot be too high because ion transmission decreases at higher stripper gas pressures due to increased angular straggling of the ions scattered by the high density stripper gas. The optimum pressure of the stripper gas for the lowest background and the highest transmission was investigated. With all the features of the compact system, the produced measurements can be of quite high precision. In the ten months after the installation of the equipment in November 2004, we have measured more than 1400 dating samples

Panorama 2011: Unconventional gas and water

International Nuclear Information System (INIS)

Vially, R.

2011-01-01

For a number of years now, the rapid development of unconventional gas use in North America has been revolutionising the natural gas market. This generic term refers to several production types, such as tight gas, shale gas and coal bed methane. What they have in common is that the rock needs to be 'stimulated' in order to extract gas from it that can be commercially produced. These methods (horizontal drilling, hydraulic fracturing) all involve sensible management of the water needed for gas production. (author)

Solar-assisted gas-energy water-heating feasibility for apartments

Science.gov (United States)

Davis, E. S.

1975-01-01

Studies of residential energy use, solar-energy technology for buildings, and the requirements for implementing technology in the housing industry led to a project to develop a solar water heater for apartments. A design study for a specific apartment was used to establish a solar water-heater cost model which is based on plumbing contractor bids and manufacturer estimates. The cost model was used to size the system to minimize the annualized cost of hot water. The annualized cost of solar-assisted gas-energy water heating is found to be less expensive than electric water heating but more expensive than gas water heating. The feasibility of a natural gas utility supplying the auxiliary fuel is evaluated. It is estimated that gas-utilizing companies will find it profitable to offer solar water heating as part of a total energy service option or on a lease basis when the price of new base-load supplies of natural gas reaches $2.50-$3.00 per million Btu.

Two-dimensional thermal simulations of aluminum and carbon ion strippers for experiments at SPIRAL2 using the highest beam intensities

International Nuclear Information System (INIS)

Tahir, N.A.; Kim, V.; Lamour, E.; Lomonosov, I.V.; Piriz, A.R.; Rozet, J.P.; Stöhlker, Th.; Sultanov, V.; Vernhet, D.

2012-01-01

In this paper we report on two-dimensional numerical simulations of heating of a rotating, wheel shaped target impacted by the full intensity of the ion beam that will be delivered by the SPIRAL2 facility at Caen, France. The purpose of this work is to study heating of solid targets that will be used to strip the fast ions of SPIRAL2 to the required high charge state for the FISIC (Fast Ion–Slow Ion Collision) experiments. Strippers of aluminum with different emissivities and of carbon are exposed to high beam current of different ion species as oxygen, neon and argon. These studies show that carbon, due to its much higher sublimation temperature and much higher emissivity, is more favorable compared to aluminum. For the highest beam intensities, an aluminum stripper does not survive. However, problem of the induced thermal stresses and long term material fatigue needs to be investigated before a final conclusion can be drawn.

Treatment of Oil & Gas Produced Water.

Energy Technology Data Exchange (ETDEWEB)

Dwyer, Brian P. [Sandia National Lab. (SNL-NM), Albuquerque, NM (United States)

2016-02-01

Production of oil and gas reserves in the New Mexico Four Corners Region results in large volumes of "produced water". The common method for handling the produced water from well production is re-injection in regulatory permitted salt water disposal wells. This is expensive (%7E $5/bbl.) and does not recycle water, an ever increasingly valuable commodity. Previously, Sandia National Laboratories and several NM small business tested pressure driven membrane-filtration techniques to remove the high TDS (total dissolved solids) from a Four Corners Coal Bed Methane produced water. Treatment effectiveness was less than optimal due to problems with pre-treatment. Inadequate pre-treatment allowed hydrocarbons, wax and biological growth to foul the membranes. Recently, an innovative pre-treatment scheme using ozone and hydrogen peroxide was pilot tested. Results showed complete removal of hydrocarbons and the majority of organic constituents from a gas well production water. ACKNOWLEDGEMENTS This report was made possible through funding from the New Mexico Small Business Administration (NMSBA) Program at Sandia National Laboratories. Special thanks to Juan Martinez and Genaro Montoya for guidance and support from project inception to completion. Also, special thanks to Frank McDonald, the small businesses team POC, for laying the ground work for the entire project; Teresa McCown, the gas well owner and very knowledgeable- fantastic site host; Lea and Tim Phillips for their tremendous knowledge and passion in the oil & gas industry.; and Frank Miller and Steve Addleman for providing a pilot scale version of their proprietary process to facilitate the pilot testing.

CO2 laser-fabricated cladding light strippers for high-power fiber lasers and amplifiers.

Science.gov (United States)

Boyd, Keiron; Simakov, Nikita; Hemming, Alexander; Daniel, Jae; Swain, Robert; Mies, Eric; Rees, Simon; Andrew Clarkson, W; Haub, John

2016-04-10

We present and characterize a simple CO2 laser processing technique for the fabrication of compact all-glass optical fiber cladding light strippers. We investigate the cladding light loss as a function of radiation angle of incidence and demonstrate devices in a 400 μm diameter fiber with cladding losses of greater than 20 dB for a 7 cm device length. The core losses are also measured giving a loss of cladding light stripping of a 300 W laser diode with minimal heating of the fiber coating and packaging adhesives.

Gas-driven pump for ground-water samples

Science.gov (United States)

Signor, Donald C.

1978-01-01

Observation wells installed for artificial-recharge research and other wells used in different ground-water programs are frequently cased with small-diameter steel pipe. To obtain samples from these small-diameter wells in order to monitor water quality, and to calibrate solute-transport models, a small-diameter pump with unique operating characteristics is required that causes a minimum alternation of samples during field sampling. A small-diameter gas-driven pump was designed and built to obtain water samples from wells of two-inch diameter or larger. The pump is a double-piston type with the following characteristics: (1) The water sample is isolated from the operating gas, (2) no source of electricity is ncessary, (3) operation is continuous, (4) use of compressed gas is efficient, and (5) operation is reliable over extended periods of time. Principles of operation, actual operation techniques, gas-use analyses and operating experience are described. Complete working drawings and a component list are included. Recent modifications and pump construction for high-pressure applications also are described. (Woodard-USGS)

The charge state distribution of a carbon beam measured at the Lund pelletron accelerator with the newly installed terminal pumping system in use

CERN Document Server

Kiisk, M; Faarinen, M P; Hellborg, R; Haakansson, K; Persson, P; Skog, G; Stenström, K

2002-01-01

Charge state distributions for sup 1 sup 2 C and sup 1 sup 3 C ions have been measured at the Lund Pelletron tandem accelerator for the N sub 2 gas stripper with a newly installed terminal pumping system in use. A comparison of the results obtained for the ion energies between 1.5 and 2.8 MeV with the foil stripper and the gas stripper without terminal pumping demonstrates the great improvement of the stripping process achieved with the new terminal pumping.

Permeability of volcanic rocks to gas and water

Science.gov (United States)

Heap, M. J.; Reuschlé, T.; Farquharson, J. I.; Baud, P.

2018-04-01

The phase (gas or liquid) of the fluids within a porous volcanic system varies in both time and space. Laboratory experiments have shown that gas and water permeabilities can differ for the same rock sample, but experiments are biased towards rocks that contain minerals that are expected react with the pore fluid (such as the reaction between liquid water and clay). We present here the first study that systematically compares the gas and water permeability of volcanic rocks. Our data show that permeabilities to argon gas and deionised water can differ by a factor between two and five in two volcanic rocks (basalt and andesite) over a confining pressure range from 2 to 50 MPa. We suggest here that the microstructural elements that offer the shortest route through the sample-estimated to have an average radius 0.1-0.5 μm using the Klinkenberg slip factor-are accessible to gas, but restricted or inaccessible to water. We speculate that water adsorption on the surface of these thin microstructural elements, assumed here to be tortuous/rough microcracks, reduces their effective radius and/or prevents access. These data have important implications for fluid flow and therefore the distribution and build-up of pore pressure within volcanic systems.

Waste rice seed in conventional and stripper-head harvested fields in California: Implications for wintering waterfowl

Science.gov (United States)

Fleskes, Joseph P.; Halstead, Brian J.; Casazza, Michael L.; Coates, Peter S.; Kohl, Jeffrey D.; Skalos, Daniel A.

2012-01-01

Waste rice seed is an important food for wintering waterfowl and current estimates of its availability are needed to determine the carrying capacity of rice fields and guide habitat conservation. We used a line-intercept method to estimate mass-density of rice seed remaining after harvest during 2010 in the Sacramento Valley (SACV) of California and compared results with estimates from previous studies in the SACV and Mississippi Alluvial Valley (MAV). Posterior mean (95% credible interval) estimates of total waste rice seed mass-density for the SACV in 2010 were 388 (336–449) kg/ha in conventionally harvested fields and 245 (198–307) kg/ha in stripper-head harvested fields; the 2010 mass-density is nearly identical to the mid-1980s estimate for conventionally harvested fields but 36% lower than the mid-1990s estimate for stripped fields. About 18% of SACV fields were stripper-head harvested in 2010 vs. 9–15% in the mid-1990s and 0% in the mid-1980s; but due to a 50% increase in planted rice area, total mass of waste rice seed in SACV remaining after harvest in 2010 was 43% greater than in the mid-1980s. However, total mass of seed-eating waterfowl also increased 82%, and the ratio of waste rice seed to seed-eating waterfowl mass was 21% smaller in 2010 than in the mid-1980s. Mass-densities of waste rice remaining after harvest in SACV fields are within the range reported for MAV fields. However, because there is a lag between harvest and waterfowl use in the MAV but not in the SACV, seed loss is greater in the MAV and estimated waste seed mass-density available to wintering waterfowl in SACV fields is about 5–30 times recent MAV estimates. Waste rice seed remains an abundant food source for waterfowl wintering in the SACV, but increased use of stripper-head harvesters would reduce this food. To provide accurate data on carrying capacities of rice fields necessary for conservation planning, trends in planted rice area, harvest method, and postharvest field

First operational experiences with the new biological waste water treatment plant at HKM; Erste Betriebserfahrungen mit der neuen biologischen Abwasserbehandlungsanlage der HKM

Energy Technology Data Exchange (ETDEWEB)

R. Wendt; L. Nelles

2002-07-01

The common process of coke oven gas purification in by-product plant produces process water that is namely composed of excess flushing water from the crude tar decantation and waste water from NH{sub 3} and H{sub 2}S scrubbers. In 1959, the coke plant at HKM (formerly Mannesmann Huettenwerken Huckingen AG) was commissioned. This plant made use of the phenol removal process. Utilizing the phenolsolvan method the phenols toxic to microbes were removed from ammonia waste water and crude phenol recovered. The process water was subsequently steam stripped in strippers and deacidifiers. After more than 40 years of operation the need for modernization of the phenol removal plant arose. As a consequence of more stringent limits on coke plant effluents that have already been in place for several years the HKM came to a resolution to construct a new biological waste water treatment plant instead of renewing the phenol removal plant.

Gas-Chromatographic Determination Of Water In Freon PCA

Science.gov (United States)

Melton, Donald M.

1994-01-01

Gas-chromatographic apparatus measures small concentrations of water in specimens of Freon PCA. Testing by use of apparatus faster and provides greater protection against accidental contamination of specimens by water in testing environment. Automated for unattended operation. Also used to measure water contents of materials, other than Freon PCA. Innovation extended to development of purgeable sampling accessory for gas chromatographs.

Impact of Shale Gas Development on Water Resource in Fuling, China

Science.gov (United States)

Yang, Hong; Huang, Xianjin; Yang, Qinyuan; Tu, Jianjun

2015-04-01

As a low-carbon energy, shale gas rapidly developed in U.S. in last years due to the innovation of the technique of hydraulic fracture, or fracking. Shale gas boom produces more gas with low price and reduced the reliance on fuel import. To follow the American shale gas success, China made an ambitious plan of shale gas extraction, 6.5 billion m3 by 2015. To extract shale gas, huge amount water is needed to inject into each gas well. This will intensify the competition of water use between industry, agricultural and domestic sectors. It may finally exacerbate the water scarcity in China. After the extraction, some water was returned to the ground. Without adequate treatment, the flowback water can introduce heavy metal, acids, pesticides, and other toxic material into water and land. This may inevitably worsen the water and land contamination. This study analysed the potential water consumption and wastewater generation in shale gas development in Fuling, Southwest China. The survey found the average water consumption is 30,000 cubic meter for one well, higher than shale well in U.S. Some 2%-20% water flowed back to the ground. The water quality monitoring showed the Total Suspended Solid (TSS) and Chemical Oxygen Demand (COD) were the main factors above those specified by China's water regulation. Shale gas is a lower-carbon energy, but it is important to recognize the water consuming and environmental pollution during the fracking. Strict monitoring and good coordination during the shale gas exploitation is urgently needed for the balance of economic development, energy demand and environmental protection.

WATER PINCH TECHNOLOGY APPLICATION TO MINIMIZE SULPHUROUS WASTEWATER IN AN OIL REFINERY

Directory of Open Access Journals (Sweden)

Gabriel Orlando Lobelles Sardiñas

2017-01-01

Full Text Available In oil refining industries there is a high water consumption, which influences the high production costs and impacts the environment due to the discharge of their wastes. It is known that there are no technological conditions for the reuse of industrial water at the oil refineries, based on hydroskimming processes. The objective of this study is to implement the process integration methodology, Water Pinch, to a sour water stripper unit, as a unitary process of an oil refinery, to minimize the amount of sulphurous waste water and reduce contamination of the bay that receives these wastes. The technology is applied to evaluate the volume of sulphurous wastewater generated in the Cienfuegos oil refinery. This technology allows identifying opportunities for recovery and reuse of water, based on concentration ranges of contaminants. To achieve this purpose, a sour water stripper tower was assessed with the help of Water Pinch software, which provided an optimized distribution network, as a proposed technological improvement. This facilitated to recover and reuse 667 757, 28 m3 of water per year, and 1 035 023, 78 CUC were saved, at the same time the amount of polluting effluents decreased in approximately 2 % of non-reusable treated water.

Gas and Water Permeability of Concrete

Energy Technology Data Exchange (ETDEWEB)

Villar, M. V.; Martin, P. L.; Romero, F. J.; Gutierrez-Rodirgo, V.; Barcala, J. M.

2012-11-01

The gas pressure of concrete samples was measured in an unsteady-state equipment working under low injection pressures and in a newly fine tuned steady-state setup working under different pressures. These measurements allowed the estimation of the intrinsic and relative gas permeability of the concrete and of the effect of boundary conditions on them. Permeability decreased with water content, but it was also greatly affected by the hydraulic history of concrete, i.e. if it had been previously dried or wetted. In particular, and for a given degree of saturation, the gas permeability of concrete previously saturated was lower than if the concrete had been just air dried or saturated after air drying. In any case, the gas permeability was about two orders of magnitude higher than the liquid water permeability (10-16 vs. 10-18 m2), probably due to the chemical reactions taking place during saturation (carbonation). The relative gas permeability of concrete increased sharply for water degrees of saturation smaller than 50%. The boundary conditions also affected the gas permeability, which seemed to be mostly conditioned by the back pressure and the confining pressure, increasing as the former increased and decreasing as the latter increased, i.e. decreasing as the effective pressure increased. Overall the increase of pressure head or injection pressure implied a decrease in gas permeability. External,microcracking during air-drying could not be ruled out as responsible for the decrease of permeability with confining pressure. The apparent permeability obtained applying the Klinkenberg method for a given effective pressure was only slightly smaller than the average of all the values measured for the same confining pressure range. For this reason it is considered that the Klinkenberg effect was not relevant in the range of pressures applied. (Author) 37 refs.

Water vapor and Gas Transport through Polymeric Membranes

NARCIS (Netherlands)

Metz, S.J.

2003-01-01

Water vapor transport through polymeric materials plays an important role in a large number of applications such as: food packaging, breathable clothing, roofing membranes, diapers, and the removal of water vapor from gas streams (e.g. dehydration of natural gas or the drying of compressed air).

Fission gas behaviour in water reactor fuels

International Nuclear Information System (INIS)

2002-01-01

During irradiation, nuclear fuel changes volume, primarily through swelling. This swelling is caused by the fission products and in particular by the volatile ones such as krypton and xenon, called fission gas. Fission gas behaviour needs to be reliably predicted in order to make better use of nuclear fuel, a factor which can help to achieve the economic competitiveness required by today's markets. These proceedings communicate the results of an international seminar which reviewed recent progress in the field of fission gas behaviour in light water reactor fuel and sought to improve the models used in computer codes predicting fission gas release. State-of-the-art knowledge is presented for both uranium-oxide and mixed-oxide fuels loaded in water reactors. (author)

40 CFR 1065.645 - Amount of water in an ideal gas.

Science.gov (United States)

2010-07-01

... 40 Protection of Environment 32 2010-07-01 2010-07-01 false Amount of water in an ideal gas. 1065... in an ideal gas. This section describes how to determine the amount of water in an ideal gas, which... of water in an ideal gas, x H20, as follows: ER30AP10.034 Where: x H20 = amount of water in an ideal...

Process for water-gas generation from degassed combustibles

Energy Technology Data Exchange (ETDEWEB)

1906-05-23

A process for water-gas generation in a continuous operation from degassed combustibles in the lower part of a vertical exterior-heated retort, whose middle part can serve to degas the combustibles, is described. It is characterized in that the water vapor employed is obtained by vaporizing water in the upper part of the retort by means of the waste heat from the heating gases, which had effected the coking of the combustibles before the water-gas recovery or after the latter.

On factors influencing air-water gas exchange in emergent wetlands

Science.gov (United States)

Ho, David T.; Engel, Victor C.; Ferron, Sara; Hickman, Benjamin; Choi, Jay; Harvey, Judson W.

2018-01-01

Knowledge of gas exchange in wetlands is important in order to determine fluxes of climatically and biogeochemically important trace gases and to conduct mass balances for metabolism studies. Very few studies have been conducted to quantify gas transfer velocities in wetlands, and many wind speed/gas exchange parameterizations used in oceanographic or limnological settings are inappropriate under conditions found in wetlands. Here six measurements of gas transfer velocities are made with SF6 tracer release experiments in three different years in the Everglades, a subtropical peatland with surface water flowing through emergent vegetation. The experiments were conducted under different flow conditions and with different amounts of emergent vegetation to determine the influence of wind, rain, water flow, waterside thermal convection, and vegetation on air-water gas exchange in wetlands. Measured gas transfer velocities under the different conditions ranged from 1.1 cm h−1 during baseline conditions to 3.2 cm h−1 when rain and water flow rates were high. Commonly used wind speed/gas exchange relationships would overestimate the gas transfer velocity by a factor of 1.2 to 6.8. Gas exchange due to thermal convection was relatively constant and accounted for 14 to 51% of the total measured gas exchange. Differences in rain and water flow among the different years were responsible for the variability in gas exchange, with flow accounting for 37 to 77% of the gas exchange, and rain responsible for up to 40%.

Increased stray gas abundance in a subset of drinking water wells near Marcellus shale gas extraction.

Science.gov (United States)

Jackson, Robert B; Vengosh, Avner; Darrah, Thomas H; Warner, Nathaniel R; Down, Adrian; Poreda, Robert J; Osborn, Stephen G; Zhao, Kaiguang; Karr, Jonathan D

2013-07-09

Horizontal drilling and hydraulic fracturing are transforming energy production, but their potential environmental effects remain controversial. We analyzed 141 drinking water wells across the Appalachian Plateaus physiographic province of northeastern Pennsylvania, examining natural gas concentrations and isotopic signatures with proximity to shale gas wells. Methane was detected in 82% of drinking water samples, with average concentrations six times higher for homes gas wells (P = 0.0006). Ethane was 23 times higher in homes gas wells (P = 0.0013); propane was detected in 10 water wells, all within approximately 1 km distance (P = 0.01). Of three factors previously proposed to influence gas concentrations in shallow groundwater (distances to gas wells, valley bottoms, and the Appalachian Structural Front, a proxy for tectonic deformation), distance to gas wells was highly significant for methane concentrations (P = 0.007; multiple regression), whereas distances to valley bottoms and the Appalachian Structural Front were not significant (P = 0.27 and P = 0.11, respectively). Distance to gas wells was also the most significant factor for Pearson and Spearman correlation analyses (P gas wells was the only statistically significant factor (P gas (4)He to CH4 in groundwater were characteristic of a thermally postmature Marcellus-like source in some cases. Overall, our data suggest that some homeowners living gas wells have drinking water contaminated with stray gases.

Membranes for Flue Gas Treatment - Transport behavior of water and gas in hydrophilic polymer membranes

NARCIS (Netherlands)

Potreck, Jens

2009-01-01

Fossil fuel fired power plants produce electricity and in addition to that large volume flows of flue gas, which mainly contain N2, O2, and CO2, but also large quantities of water vapor. To prevent condensation of the water vapor present in this flue gas stream, water needs to be removed before

Effective water influx control in gas reservoir development: Problems and countermeasures

Directory of Open Access Journals (Sweden)

Xi Feng

2015-03-01

Full Text Available Because of the diversity of geological characteristics and the complexity of percolation rules, many problems are found ineffective water influx control in gas reservoir development. The problems mainly focus on how to understand water influx rules, to establish appropriate countermeasures, and to ensure the effectiveness of technical measures. It is hard to obtain a complete applicable understanding through the isolated analysis of an individual gas reservoir due to many factors such as actual gas reservoir development phase, research work, pertinence and timeliness of measures, and so on. Over the past four decades, the exploration, practicing and tracking research have been conducted on water control in gas reservoir development in the Sichuan Basin, and a series of comprehensive water control technologies were developed integrating advanced concepts, successful experiences, specific theories and mature technologies. Though the development of most water-drive gas reservoirs was significantly improved, water control effects were quite different. Based on this background, from the perspective of the early-phase requirements of water influx control, the influencing factors of a water influx activity, the dynamic analysis method of water influx performance, the optimizing strategy of a water control, and the water control experience of typical gas reservoirs, this paper analyzed the key problems of water control, evaluated the influencing factors of water control effect, explored the practical water control strategies, and proposed that it should be inappropriate to apply the previous water control technological model to actual work but the pertinence should be improved according to actual circumstances. The research results in the paper provide technical reference for the optimization of water-invasion gas reservoir development.

Robust cladding light stripper for high-power fiber lasers using soft metals.

Science.gov (United States)

Babazadeh, Amin; Nasirabad, Reza Rezaei; Norouzey, Ahmad; Hejaz, Kamran; Poozesh, Reza; Heidariazar, Amir; Golshan, Ali Hamedani; Roohforouz, Ali; Jafari, S Naser Tabatabaei; Lafouti, Majid

2014-04-20

In this paper we present a novel method to reliably strip the unwanted cladding light in high-power fiber lasers. Soft metals are utilized to fabricate a high-power cladding light stripper (CLS). The capability of indium (In), aluminum (Al), tin (Sn), and gold (Au) in extracting unwanted cladding light is examined. The experiments show that these metals have the right features for stripping the unwanted light out of the cladding. We also find that the metal-cladding contact area is of great importance because it determines the attenuation and the thermal load on the CLS. These metals are examined in different forms to optimize the contact area to have the highest possible attenuation and avoid localized heating. The results show that sheets of indium are very effective in stripping unwanted cladding light.

The Value of Water in Extraction of Natural Gas from the Marcellus Shale

Science.gov (United States)

Rimsaite, R.; Abdalla, C.; Collins, A.

2013-12-01

Hydraulic fracturing of shale has increased the demand for the essential input of water in natural gas production. Increased utilization of water by the shale gas industry, and the development of water transport and storage related infrastructure suggest that the value of water is increasing where hydraulic fracturing is occurring. Few studies on the value of water in industrial uses exist and, to our knowledge, no studies of water's value in extracting natural gas from shale have been published. Our research aims to fill this knowledge gap by exploring several key dimensions of the value of water used in shale gas development. Our primary focus was to document the costs associated with water acquisition for shale gas extraction in West Virginia and Pennsylvania, two states located in the gas-rich Marcellus shale formation with active drilling and extraction underway. This research involved a) gathering data on the sources of and costs associated with water acquisition for shale gas extraction b) comparing unit costs with prices and costs paid by the gas industry users of water; c) determining factors that potentially impact total and per unit costs of water acquisition for the shale gas industry; and d) identifying lessons learned for water managers and policy-makers. The population of interest was all private and public entities selling water to the shale gas industry in Pennsylvania and West Virginia. Primary data were collected from phone interviews with water sellers and secondary data were gathered from state regulatory agencies. Contact information was obtained for 40 water sellers in the two states. Considering both states, the average response rate was 49%. Relatively small amounts of water, approximately 11% in West Virginia and 29% in Pennsylvania, were purchased from public water suppliers by the shale gas industry. The price of water reveals information about the value of water. The average price charged to gas companies was 6.00/1000 gallons and 7

Combination gas producing and waste-water disposal well

Science.gov (United States)

Malinchak, Raymond M.

1984-01-01

The present invention is directed to a waste-water disposal system for use in a gas recovery well penetrating a subterranean water-containing and methane gas-bearing coal formation. A cased bore hole penetrates the coal formation and extends downwardly therefrom into a further earth formation which has sufficient permeability to absorb the waste water entering the borehole from the coal formation. Pump means are disposed in the casing below the coal formation for pumping the water through a main conduit towards the water-absorbing earth formation. A barrier or water plug is disposed about the main conduit to prevent water flow through the casing except for through the main conduit. Bypass conduits disposed above the barrier communicate with the main conduit to provide an unpumped flow of water to the water-absorbing earth formation. One-way valves are in the main conduit and in the bypass conduits to provide flow of water therethrough only in the direction towards the water-absorbing earth formation.

Water vapor and gas transport through PEO PBT block copolymers

NARCIS (Netherlands)

Metz, S.J.; Potreck, Jens; Mulder, M.H.V.; Wessling, Matthias

2002-01-01

Introduction At the bore well natural gas is saturated with water. Downstream the presence of water may cause: formation of methane hydrates (blocking eventually the pipeline), condensation of water in the pipeline and corrosion effects. A process used for the dehydration of natural gas is glycol

Zeolite Membrane Reactor for Water Gas Shift Reaction for Hydrogen Production

Energy Technology Data Exchange (ETDEWEB)

Lin, Jerry Y.S. [Arizona State Univ., Mesa, AZ (United States)

2013-01-29

Gasification of biomass or heavy feedstock to produce hydrogen fuel gas using current technology is costly and energy-intensive. The technology includes water gas shift reaction in two or more reactor stages with inter-cooling to maximize conversion for a given catalyst volume. This project is focused on developing a membrane reactor for efficient conversion of water gas shift reaction to produce a hydrogen stream as a fuel and a carbon dioxide stream suitable for sequestration. The project was focused on synthesizing stable, hydrogen perm-selective MFI zeolite membranes for high temperature hydrogen separation; fabricating tubular MFI zeolite membrane reactor and stable water gas shift catalyst for membrane reactor applications, and identifying experimental conditions for water gas shift reaction in the zeolite membrane reactor that will produce a high purity hydrogen stream. The project has improved understanding of zeolite membrane synthesis, high temperature gas diffusion and separation mechanisms for zeolite membranes, synthesis and properties of sulfur resistant catalysts, fabrication and structure optimization of membrane supports, and fundamentals of coupling reaction with separation in zeolite membrane reactor for water gas shift reaction. Through the fundamental study, the research teams have developed MFI zeolite membranes with good perm-selectivity for hydrogen over carbon dioxide, carbon monoxide and water vapor, and high stability for operation in syngas mixture containing 500 part per million hydrogen sulfide at high temperatures around 500°C. The research teams also developed a sulfur resistant catalyst for water gas shift reaction. Modeling and experimental studies on the zeolite membrane reactor for water gas shift reaction have demonstrated the effective use of the zeolite membrane reactor for production of high purity hydrogen stream.

Shale gas development impacts on surface water quality in Pennsylvania

Science.gov (United States)

Olmstead, Sheila M.; Muehlenbachs, Lucija A.; Shih, Jhih-Shyang; Chu, Ziyan; Krupnick, Alan J.

2013-01-01

Concern has been raised in the scientific literature about the environmental implications of extracting natural gas from deep shale formations, and published studies suggest that shale gas development may affect local groundwater quality. The potential for surface water quality degradation has been discussed in prior work, although no empirical analysis of this issue has been published. The potential for large-scale surface water quality degradation has affected regulatory approaches to shale gas development in some US states, despite the dearth of evidence. This paper conducts a large-scale examination of the extent to which shale gas development activities affect surface water quality. Focusing on the Marcellus Shale in Pennsylvania, we estimate the effect of shale gas wells and the release of treated shale gas waste by permitted treatment facilities on observed downstream concentrations of chloride (Cl−) and total suspended solids (TSS), controlling for other factors. Results suggest that (i) the treatment of shale gas waste by treatment plants in a watershed raises downstream Cl− concentrations but not TSS concentrations, and (ii) the presence of shale gas wells in a watershed raises downstream TSS concentrations but not Cl− concentrations. These results can inform future voluntary measures taken by shale gas operators and policy approaches taken by regulators to protect surface water quality as the scale of this economically important activity increases. PMID:23479604

Safety distance between underground natural gas and water pipeline facilities

International Nuclear Information System (INIS)

Mohsin, R.; Majid, Z.A.; Yusof, M.Z.

2014-01-01

A leaking water pipe bursting high pressure water jet in the soil will create slurry erosion which will eventually erode the adjacent natural gas pipe, thus causing its failure. The standard 300 mm safety distance used to place natural gas pipe away from water pipeline facilities needs to be reviewed to consider accidental damage and provide safety cushion to the natural gas pipe. This paper presents a study on underground natural gas pipeline safety distance via experimental and numerical approaches. The pressure–distance characteristic curve obtained from this experimental study showed that the pressure was inversely proportional to the square of the separation distance. Experimental testing using water-to-water pipeline system environment was used to represent the worst case environment, and could be used as a guide to estimate appropriate safety distance. Dynamic pressures obtained from the experimental measurement and simulation prediction mutually agreed along the high-pressure water jetting path. From the experimental and simulation exercises, zero effect distance for water-to-water medium was obtained at an estimated horizontal distance at a minimum of 1500 mm, while for the water-to-sand medium, the distance was estimated at a minimum of 1200 mm. - Highlights: • Safe separation distance of underground natural gas pipes was determined. • Pressure curve is inversely proportional to separation distance. • Water-to-water system represents the worst case environment. • Measured dynamic pressures mutually agreed with simulation results. • Safe separation distance of more than 1200 mm should be applied

Slurried solid media for simultaneous water purification and carbon dioxide removal from gas mixtures

Science.gov (United States)

Aines, Roger D.; Bourcier, William L.; Viani, Brian

2013-01-29

A slurried solid media for simultaneous water purification and carbon dioxide removal from gas mixtures includes the steps of dissolving the gas mixture and carbon dioxide in water providing a gas, carbon dioxide, water mixture; adding a porous solid media to the gas, carbon dioxide, water mixture forming a slurry of gas, carbon dioxide, water, and porous solid media; heating the slurry of gas, carbon dioxide, water, and porous solid media producing steam; and cooling the steam to produce purified water and carbon dioxide.

Integrated Microfluidic Gas Sensors for Water Monitoring

Science.gov (United States)

Zhu, L.; Sniadecki, N.; DeVoe, D. L.; Beamesderfer, M.; Semancik, S.; DeVoe, D. L.

2003-01-01

A silicon-based microhotplate tin oxide (SnO2) gas sensor integrated into a polymer-based microfluidic system for monitoring of contaminants in water systems is presented. This device is designed to sample a water source, control the sample vapor pressure within a microchannel using integrated resistive heaters, and direct the vapor past the integrated gas sensor for analysis. The sensor platform takes advantage of novel technology allowing direct integration of discrete silicon chips into a larger polymer microfluidic substrate, including seamless fluidic and electrical interconnects between the substrate and silicon chip.

Flue gas CO{sub 2} capture by a green liquid membrane

Energy Technology Data Exchange (ETDEWEB)

Michael C. Trachtenberg; Lihong Bao; Stefanie L. Goldman; David A. Smith; Xiaoqiu Wu [Carbozyme, Inc., Monmouth Junction, NJ (United States)

2005-07-01

We have designed, developed, modeled and tested several different membrane-based, facilitated transport carbonate / bicarbonate reactors (conjoint absorber-strippers) for the post-combustion extraction of CO{sub 2} from both air and flue gas. We have assessed separately the reactive chemistry, the reactor design and the process engineering. Facilitation is achieved by means of the most efficient CO{sub 2} conversion catalyst, the enzyme carbonic anhydrase. Experimental data mirror model predictions very closely. CO{sub 2} permeance value for 10% feed stream (balanced dry air) is 3.35E-8 mole/m{sup 2} s Pa, and the selectivity vs. N{sub 2} and vs. O{sub 2} were 250 and 150. The only moving elements in this design are the feed gas and the sweep gas streams. Gas separation is driven by partial pressure difference alone. As a consequence, this design is extremely energy efficient. 10 refs., 4 figs., 1 tab.

Life-cycle comparison of greenhouse gas emissions and water consumption for coal and shale gas fired power generation in China

International Nuclear Information System (INIS)

Chang, Yuan; Huang, Runze; Ries, Robert J.; Masanet, Eric

2015-01-01

China has the world's largest shale gas reserves, which might enable it to pursue a new pathway for electricity generation. This study employed hybrid LCI (life cycle inventory) models to quantify the ETW (extraction-to-wire) GHG (greenhouse gas) emissions and water consumption per kWh of coal- and shale gas-fired electricity in China. Results suggest that a coal-to-shale gas shift and upgrading coal-fired power generation technologies could provide pathways to less GHG and water intensive power in China. Compared to different coal-fired generation technologies, the ETW GHG emissions intensity of gas-fired CC (combined cycle) technology is 530 g CO 2 e/kWh, which is 38–45% less than China's present coal-fired electricity. Gas-fired CT (combustion turbine) technology has the lowest ETW water consumption intensity at 960 g/kWh, which is 34–60% lower than China's present coal-fired electricity. The GHG-water tradeoff of the two gas-fired power generation technologies suggests that gas-fired power generation technologies should be selected based on regional-specific water resource availabilities and electricity demand fluctuations in China. However, the low price of coal-fired electricity, high cost of shale gas production, insufficient pipeline infrastructures, and multiple consumers of shale gas resources may serve as barriers to a coal-to-shale gas shift in China's power sector in the near term. - Highlights: • The GHG and water footprints of coal- and shale gas-fired electricity are estimated. • A coal-to-shale gas shift can enable less GHG and water intensive power in China. • The GHG emissions of shale gas-fired combined cycle technology is 530 g CO 2 e/kWh. • The water consumption of shale gas-fired combustion turbine technology is 960 g/kWh. • Shale gas-fired power generation technologies selection should be regional-specific

Proper Estimation of the Energy Consumption in A Carbon Dioxide-MEA Stripper

DEFF Research Database (Denmark)

Madeddu, Claudio; Errico, Massimiliano; Baratti, Roberto

In the field of CCS, the chemical absorption/desorption using amines represents one of the most easily implemented process for the reduction of the carbon dioxide generated by combustion plants. The high energy consumption in the solvent regeneration section represents the major concern for its...... fully industrial application. In the design of a carbon dioxide-MEA stripper, once the process targets are fixed, the estimation of the reboiler duty represents a crucial point for what concerns the quantification of the energy requirement. Furthermore, the vapor flow produced in the reboiler influences...... in simultaneous multicomponent material transfer, energy transfer and chemical reactions, is fundamental for an accurate design of the system. In this work the solvent regeneration section of a pilot-plant post-combustion CO2 capture facility was modeled using a rate-based approach, focusing on some key...

Building America Case Study: Assessment of a Hybrid Retrofit Gas Water Heater

Energy Technology Data Exchange (ETDEWEB)

M. Hoeschele, E. Weitzel, C. Backman

2017-06-01

This project completed a modeling evaluation of a hybrid gas water heater that combines a reduced capacity tankless unit with a downsized storage tank. This product would meet a significant market need by providing a higher efficiency gas water heater solution for retrofit applications while maintaining compatibility with the half-inch gas lines and standard B vents found in most homes. The TRNSYS simulation tool was used to model a base case 0.60 EF atmospheric gas storage water, a 0.82 EF non-condensing gas tankless water heater, an existing (high capacity) hybrid unit on the market, and an alternative hybrid unit with lower storage volume and reduced gas input requirements.

Simulation bidimensional of water and gas alternative injection; Simulacao bidimensional de injecao alternada de agua e gas

Energy Technology Data Exchange (ETDEWEB)

Santana, Ana Paula Silva C. de

1999-07-01

This dissertation presents a study of the unidimensional of water and gas alternate injection (WAG) using the stream line theory. It is considered incompressible fluid., unit mobility ratio, negligible capillary and gravitational effects, homogeneous and isotropic reservoir, isothermal flow two phases, oil and water, and three components, oil, water and gas. In the stream line theory, the following injection schemes are considered: staggered line five-spot, direct line and seven-spot. It is also considered that there is no flow among the streams. In the WAG calculations it is used the fractional flow theory and the method of characteristics, which consists of shock waves and rarefactions. The composition of these waves is said compatible if it satisfies the entropy condition. The solution goes through a certain path from the left to the right side constrained by the initial and boundary conditions. The gas injection is at a high pressure to ensure miscible displacement. It is considered first injection of a water bank and then, injection of a gas bank. We concluded that the gas injection at a high pressure recoveries all residual oil and the water saturation remains is greater than initial saturation. (author)

Supercritical water decontamination of town gas soil

International Nuclear Information System (INIS)

Kocher, B.S.; Azzam, F.O.; Lee, S.

1994-01-01

Town gas sites represent a large environmental problem that exists in more than 2,000 sites across North America alone. The major contaminants in town gas sods are polycyclic aromatic hydrocarbons (PAHs). These are stable compounds that migrate deep into the soil and are traditionally very difficult to remove by conventional remediation processes. Supercritical fluids offer enhanced solvating properties along with reduced mass transfer resistances that make them ideal for removing compounds that are difficult or impossible to remove by conventional processes. Supercritical water is ideal for removing PAHs and other hydrocarbons from soil due to its high solvating power towards most hydrocarbon species. Supercritical water was investigated for its ability to remediate two different town gas sods containing from 3--20 wt% contamination. The sod was remediated in a 300-cc semi-continuous system to a more environmentally acceptable level

Building America Case Study: Assessment of a Hybrid Retrofit Gas Water Heater

Energy Technology Data Exchange (ETDEWEB)

2017-06-19

This project completed a modeling evaluation of a hybrid gas water heater that combines a reduced capacity tankless unit with a downsized storage tank. This product would meet a significant market need by providing a higher efficiency gas water heater solution for retrofit applications while maintaining compatibility with the half-inch gas lines and standard B vents found in most homes. The TRNSYS simulation tool was used to model a base case 0.60 EF atmospheric gas storage water, a 0.82 EF non-condensing gas tankless water heater, an existing (high capacity) hybrid unit on the market, and an alternative hybrid unit with lower storage volume and reduced gas input requirements. Simulations were completed under a 'peak day' sizing scenario with 183 gpd hot water loads in a Minnesota winter climate case. Full-year simulations were then completed in three climates (ranging from Phoenix to Minneapolis) for three hot water load scenarios (36, 57, and 96 gpd). Model projections indicate that the alternative hybrid offers an average 4.5% efficiency improvement relative to the 0.60 EF gas storage unit across all scenarios modeled. The alternative hybrid water heater evaluated does show promise, but the current low cost of natural gas across much of the country and the relatively small incremental efficiency improvement poses challenges in initially building a market demand for the product.

Lithium recovery from shale gas produced water using solvent extraction

International Nuclear Information System (INIS)

Jang, Eunyoung; Jang, Yunjai; Chung, Eunhyea

2017-01-01

Shale gas produced water is hypersaline wastewater generated after hydraulic fracturing. Since the produced water is a mixture of shale formation water and fracturing fluid, it contains various organic and inorganic components, including lithium, a useful resource for such industries as automobile and electronics. The produced water in the Marcellus shale area contains about 95 mg/L lithium on average. This study suggests a two-stage solvent extraction technique for lithium recovery from shale gas produced water, and determines the extraction mechanism of ions in each stage. All experiments were conducted using synthetic shale gas produced water. In the first-stage, which was designed for the removal of divalent cations, more than 94.4% of Ca"2"+, Mg"2"+, Sr"2"+, and Ba"2"+ ions were removed by using 1.0 M di-(2-ethylhexyl) phosphoric acid (D2EHPA) as an extractant. In the second-stage, for lithium recovery, we could obtain a lithium extraction efficiency of 41.2% by using 1.5 M D2EHPA and 0.3 M tributyl phosphate (TBP). Lithium loss in the first-stage was 25.1%, and therefore, the total amount of lithium recovered at the end of the two-step extraction procedure was 30.8%. Through this study, lithium, one of the useful mineral resources, could be selectively recovered from the shale gas produced water and it would also reduce the wastewater treatment cost during the development of shale gas. - Highlights: • Lithium was extracted from shale gas produced water using an organic solvent. • Two-stage solvent extraction technique was applied. • Divalent cations were removed in the first stage by D2EHPA. • Lithium was selectively recovered in the second stage by using TBP with D2EHPA.

Thermodynamic Modeling of Natural Gas Systems Containing Water

DEFF Research Database (Denmark)

Karakatsani, Eirini K.; Kontogeorgis, Georgios M.

2013-01-01

As the need for dew point specifications remains very urgent in the natural gas industry, the development of accurate thermodynamic models, which will match experimental data and will allow reliable extrapolations, is needed. Accurate predictions of the gas phase water content in equilibrium...... with a heavy phase were previously obtained using cubic plus association (CPA) coupled with a solid phase model in the case of hydrates, for the binary systems of water–methane and water–nitrogen and a few natural gas mixtures. In this work, CPA is being validated against new experimental data, both water...... content and phase equilibrium data, and solid model parameters are being estimated for four natural gas main components (methane, ethane, propane, and carbon dioxide). Different tests for the solid model parameters are reported, including vapor-hydrate-equilibria (VHE) and liquid-hydrate-equilibria (LHE...

Minimization of steam requirements and enhancement of water-gas shift reaction with warm gas temperature CO2 removal

Science.gov (United States)

Siriwardane, Ranjani V; Fisher, II, James C

2013-12-31

The disclosure utilizes a hydroxide sorbent for humidification and CO.sub.2 removal from a gaseous stream comprised of CO and CO.sub.2 prior to entry into a water-gas-shift reactor, in order to decrease CO.sub.2 concentration and increase H.sub.2O concentration and shift the water-gas shift reaction toward the forward reaction products CO.sub.2 and H.sub.2. The hydroxide sorbent may be utilized for absorbtion of CO.sub.2 exiting the water-gas shift reactor, producing an enriched H.sub.2 stream. The disclosure further provides for regeneration of the hydroxide sorbent at temperature approximating water-gas shift conditions, and for utilizing H.sub.2O product liberated as a result of the CO.sub.2 absorption.

Gas stripping and recirculation process in heavy water separation plant

International Nuclear Information System (INIS)

Nazzer, D.B.; Thayer, V.R.

1976-01-01

Hydrogen sulfide is stripped from hot effluent, in a heavy water separation plant of the dual temperature isotope separation type, by taking liquid effluent from the hot tower before passage through the humidifier, passing the liquid through one or more throttle devices to flash-off the H 2 S gas content, and feeding the gas into an absorption tower containing incoming feed water, for recycling of the gas through the process

Impact of shale gas development on regional water quality.

Science.gov (United States)

Vidic, R D; Brantley, S L; Vandenbossche, J M; Yoxtheimer, D; Abad, J D

2013-05-17

Unconventional natural gas resources offer an opportunity to access a relatively clean fossil fuel that could potentially lead to energy independence for some countries. Horizontal drilling and hydraulic fracturing make the extraction of tightly bound natural gas from shale formations economically feasible. These technologies are not free from environmental risks, however, especially those related to regional water quality, such as gas migration, contaminant transport through induced and natural fractures, wastewater discharge, and accidental spills. We review the current understanding of environmental issues associated with unconventional gas extraction. Improved understanding of the fate and transport of contaminants of concern and increased long-term monitoring and data dissemination will help manage these water-quality risks today and in the future.

Shale gas vs. coal: Policy implications from environmental impact comparisons of shale gas, conventional gas, and coal on air, water, and land in the United States

International Nuclear Information System (INIS)

Jenner, Steffen; Lamadrid, Alberto J.

2013-01-01

The aim of this paper is to examine the major environmental impacts of shale gas, conventional gas and coal on air, water, and land in the United States. These factors decisively affect the quality of life (public health and safety) as well as local and global environmental protection. Comparing various lifecycle assessments, this paper will suggest that a shift from coal to shale gas would benefit public health, the safety of workers, local environmental protection, water consumption, and the land surface. Most likely, shale gas also comes with a smaller GHG footprint than coal. However, shale gas extraction can affect water safety. This paper also discusses related aspects that exemplify how shale gas can be more beneficial in the short and long term. First, there are technical solutions readily available to fix the most crucial problems of shale gas extraction, such as methane leakages and other geo-hazards. Second, shale gas is best equipped to smoothen the transition to an age of renewable energy. Finally, this paper will recommend hybrid policy regulations. - Highlights: ► We examine the impacts of (un)conventional gas and coal on air, water, and land. ► A shift from coal to shale gas would benefit public health. ► Shale gas extraction can affect water safety. ► We discuss technical solutions to fix the most crucial problems of shale gas extraction. ► We recommend hybrid regulations.

Produced water management - clean and safe oil and gas production

International Nuclear Information System (INIS)

2006-01-01

The conference contains 22 presentations on topics within pollution sources and abatement, discharge reductions, water analysis and monitoring, water production, treatment and injection, enhanced recovery, condensate water, produced water markets, separation technologies for oil/gas/condensate and water, oil removal from solids, environmental risks of oil and gas production and environmental impacts on ecosystems and fisheries. Some oil field case histories are presented. The main focus is on the northern areas such as the North Sea, the north Atlantic Ocean and the Barents Sea, and technological aspects (tk)

Produced water management - clean and safe oil and gas production

Energy Technology Data Exchange (ETDEWEB)

NONE

2006-07-01

The conference contains 22 presentations on topics within pollution sources and abatement, discharge reductions, water analysis and monitoring, water production, treatment and injection, enhanced recovery, condensate water, produced water markets, separation technologies for oil/gas/condensate and water, oil removal from solids, environmental risks of oil and gas production and environmental impacts on ecosystems and fisheries. Some oil field case histories are presented. The main focus is on the northern areas such as the North Sea, the north Atlantic Ocean and the Barents Sea, and technological aspects (tk)

Decomposition of water into highly combustible hydroxyl gas used in ...

African Journals Online (AJOL)

The method proposed involves the decomposition of water into highly combustible hydroxyl gas via electrolysis, which is used in internal combustion engines of electrical generators for electricity generation. The by-product obtained from combustion of this gas is water vapour and oxygen to replenish the atmosphere.

Hazard classification for the 200-ZP-1 Operable Unit Phase 2 and 3 interim remedial measure

International Nuclear Information System (INIS)

Oestreich, D.K.

1996-04-01

This safety assessment documents the Final Hazard Classification (FHC) for Phase 2 and 3 interim remedial measure (IRM) activities to be conducted in the 200 West Area of the Hanford Site. The 200-ZP-1 Phase 2 and 3 IRM activities will involve the air stripping of carbon tetrachloride (CCl 4 ) from extracted groundwater using a packed-bed stripper column followed by gas-phase adsorption of the CCl 4 from the stripper off-gas onto a granular activated carbon (GAC) bed. The stripper is designed to be operated at a feedwater flow rate of up to 1,893 L/min (500 gal/min) and to remove 13.6 kg/day (30.0 lb/day) of CCl 4 . For Phase 2, which includes the initial year of operation, it is planned to operate the stripper at 568 L/min (150 gal/min). The process flow diagram for the Phase 2 and 3 system is shown

Gas hydrate inhibition by perturbation of liquid water structure

Science.gov (United States)

Sa, Jeong-Hoon; Kwak, Gye-Hoon; Han, Kunwoo; Ahn, Docheon; Lee, Kun-Hong

2015-06-01

Natural gas hydrates are icy crystalline materials that contain hydrocarbons, which are the primary energy source for this civilization. The abundance of naturally occurring gas hydrates leads to a growing interest in exploitation. Despite their potential as energy resources and in industrial applications, there is insufficient understanding of hydrate kinetics, which hinders the utilization of these invaluable resources. Perturbation of liquid water structure by solutes has been proposed to be a key process in hydrate inhibition, but this hypothesis remains unproven. Here, we report the direct observation of the perturbation of the liquid water structure induced by amino acids using polarized Raman spectroscopy, and its influence on gas hydrate nucleation and growth kinetics. Amino acids with hydrophilic and/or electrically charged side chains disrupted the water structure and thus provided effective hydrate inhibition. The strong correlation between the extent of perturbation by amino acids and their inhibition performance constitutes convincing evidence for the perturbation inhibition mechanism. The present findings bring the practical applications of gas hydrates significantly closer, and provide a new perspective on the freezing and melting phenomena of naturally occurring gas hydrates.

Hydrodesulphurization of Light Gas Oil using hydrogen from the Water Gas Shift Reaction

Science.gov (United States)

Alghamdi, Abdulaziz

2009-12-01

The production of clean fuel faces the challenges of high production cost and complying with stricter environmental regulations. In this research, the ability of using a novel technology of upgrading heavy oil to treat Light Gas Oil (LGO) will be investigated. The target of this project is to produce cleaner transportation fuel with much lower cost of production. Recently, a novel process for upgrading of heavy oil has been developed at University of Waterloo. It is combining the two essential processes in bitumen upgrading; emulsion breaking and hydroprocessing into one process. The water in the emulsion is used to generate in situ hydrogen from the Water Gas Shift Reaction (WGSR). This hydrogen can be used for the hydrogenation and hydrotreating reaction which includes sulfur removal instead of the expensive molecular hydrogen. This process can be carried out for the upgrading of the bitumen emulsion which would improve its quality. In this study, the hydrodesulphurization (HDS) of LGO was conducted using in situ hydrogen produced via the Water Gas Shift Reaction (WGSR). The main objective of this experimental study is to evaluate the possibility of producing clean LGO over dispersed molybdenum sulphide catalyst and to evaluate the effect of different promoters and syn-gas on the activity of the dispersed Mo catalyst. Experiments were carried out in a 300 ml Autoclave batch reactor under 600 psi (initially) at 391°C for 1 to 3 hours and different amounts of water. After the hydrotreating reaction, the gas samples were collected and the conversion of carbon monoxide to hydrogen via WGSR was determined using a refinery gas analyzer. The sulphur content in liquid sample was analyzed via X-Ray Fluorescence. Experimental results showed that using more water will enhance WGSR but at the same time inhibits the HDS reaction. It was also shown that the amount of sulfur removed depends on the reaction time. The plan is to investigate the effect of synthesis gas (syngas

Universal model for water costs of gas exchange by animals and plants.

Science.gov (United States)

Woods, H Arthur; Smith, Jennifer N

2010-05-04

For terrestrial animals and plants, a fundamental cost of living is water vapor lost to the atmosphere during exchange of metabolic gases. Here, by bringing together previously developed models for specific taxa, we integrate properties common to all terrestrial gas exchangers into a universal model of water loss. The model predicts that water loss scales to gas exchange with an exponent of 1 and that the amount of water lost per unit of gas exchanged depends on several factors: the surface temperature of the respiratory system near the outside of the organism, the gas consumed (oxygen or carbon dioxide), the steepness of the gradients for gas and vapor, and the transport mode (convective or diffusive). Model predictions were largely confirmed by data on 202 species in five taxa--insects, birds, bird eggs, mammals, and plants--spanning nine orders of magnitude in rate of gas exchange. Discrepancies between model predictions and data seemed to arise from biologically interesting violations of model assumptions, which emphasizes how poorly we understand gas exchange in some taxa. The universal model provides a unified conceptual framework for analyzing exchange-associated water losses across taxa with radically different metabolic and exchange systems.

Water Extraction from Coal-Fired Power Plant Flue Gas

Energy Technology Data Exchange (ETDEWEB)

Bruce C. Folkedahl; Greg F. Weber; Michael E. Collings

2006-06-30

The overall objective of this program was to develop a liquid disiccant-based flue gas dehydration process technology to reduce water consumption in coal-fired power plants. The specific objective of the program was to generate sufficient subscale test data and conceptual commercial power plant evaluations to assess process feasibility and merits for commercialization. Currently, coal-fired power plants require access to water sources outside the power plant for several aspects of their operation in addition to steam cycle condensation and process cooling needs. At the present time, there is no practiced method of extracting the usually abundant water found in the power plant stack gas. This project demonstrated the feasibility and merits of a liquid desiccant-based process that can efficiently and economically remove water vapor from the flue gas of fossil fuel-fired power plants to be recycled for in-plant use or exported for clean water conservation. After an extensive literature review, a survey of the available physical and chemical property information on desiccants in conjunction with a weighting scheme developed for this application, three desiccants were selected and tested in a bench-scale system at the Energy and Environmental Research Center (EERC). System performance at the bench scale aided in determining which desiccant was best suited for further evaluation. The results of the bench-scale tests along with further review of the available property data for each of the desiccants resulted in the selection of calcium chloride as the desiccant for testing at the pilot-scale level. Two weeks of testing utilizing natural gas in Test Series I and coal in Test Series II for production of flue gas was conducted with the liquid desiccant dehumidification system (LDDS) designed and built for this study. In general, it was found that the LDDS operated well and could be placed in an automode in which the process would operate with no operator intervention or

Continuous measurement of air-water gas exchange by underwater eddy covariance

Science.gov (United States)

Berg, Peter; Pace, Michael L.

2017-12-01

Exchange of gases, such as O2, CO2, and CH4, over the air-water interface is an important component in aquatic ecosystem studies, but exchange rates are typically measured or estimated with substantial uncertainties. This diminishes the precision of common ecosystem assessments associated with gas exchanges such as primary production, respiration, and greenhouse gas emission. Here, we used the aquatic eddy covariance technique - originally developed for benthic O2 flux measurements - right below the air-water interface (˜ 4 cm) to determine gas exchange rates and coefficients. Using an acoustic Doppler velocimeter and a fast-responding dual O2-temperature sensor mounted on a floating platform the 3-D water velocity, O2 concentration, and temperature were measured at high-speed (64 Hz). By combining these data, concurrent vertical fluxes of O2 and heat across the air-water interface were derived, and gas exchange coefficients were calculated from the former. Proof-of-concept deployments at different river sites gave standard gas exchange coefficients (k600) in the range of published values. A 40 h long deployment revealed a distinct diurnal pattern in air-water exchange of O2 that was controlled largely by physical processes (e.g., diurnal variations in air temperature and associated air-water heat fluxes) and not by biological activity (primary production and respiration). This physical control of gas exchange can be prevalent in lotic systems and adds uncertainty to assessments of biological activity that are based on measured water column O2 concentration changes. For example, in the 40 h deployment, there was near-constant river flow and insignificant winds - two main drivers of lotic gas exchange - but we found gas exchange coefficients that varied by several fold. This was presumably caused by the formation and erosion of vertical temperature-density gradients in the surface water driven by the heat flux into or out of the river that affected the turbulent

Continuous measurement of air–water gas exchange by underwater eddy covariance

Directory of Open Access Journals (Sweden)

P. Berg

2017-12-01

Full Text Available Exchange of gases, such as O2, CO2, and CH4, over the air–water interface is an important component in aquatic ecosystem studies, but exchange rates are typically measured or estimated with substantial uncertainties. This diminishes the precision of common ecosystem assessments associated with gas exchanges such as primary production, respiration, and greenhouse gas emission. Here, we used the aquatic eddy covariance technique – originally developed for benthic O2 flux measurements – right below the air–water interface (∼ 4 cm to determine gas exchange rates and coefficients. Using an acoustic Doppler velocimeter and a fast-responding dual O2–temperature sensor mounted on a floating platform the 3-D water velocity, O2 concentration, and temperature were measured at high-speed (64 Hz. By combining these data, concurrent vertical fluxes of O2 and heat across the air–water interface were derived, and gas exchange coefficients were calculated from the former. Proof-of-concept deployments at different river sites gave standard gas exchange coefficients (k600 in the range of published values. A 40 h long deployment revealed a distinct diurnal pattern in air–water exchange of O2 that was controlled largely by physical processes (e.g., diurnal variations in air temperature and associated air–water heat fluxes and not by biological activity (primary production and respiration. This physical control of gas exchange can be prevalent in lotic systems and adds uncertainty to assessments of biological activity that are based on measured water column O2 concentration changes. For example, in the 40 h deployment, there was near-constant river flow and insignificant winds – two main drivers of lotic gas exchange – but we found gas exchange coefficients that varied by several fold. This was presumably caused by the formation and erosion of vertical temperature–density gradients in the surface water driven by the heat flux into or

Measurements of water molecule density by tunable diode laser absorption spectroscopy in dielectric barrier discharges with gas-water interface

Science.gov (United States)

Tachibana, Kunihide; Nakamura, Toshihiro; Kawasaki, Mitsuo; Morita, Tatsuo; Umekawa, Toyofumi; Kawasaki, Masahiro

2018-01-01

We measured water molecule (H2O) density by tunable diode-laser absorption spectroscopy (TDLAS) for applications in dielectric barrier discharges (DBDs) with a gas-water interface. First, the effects of water temperature and presence of gas flow were tested using a Petri dish filled with water and a gas injection nozzle. Second, the TDLAS system was applied to the measurements of H2O density in two types of DBDs; one was a normal (non-inverted) type with a dielectric-covered electrode above a water-filled counter electrode and the other was an inverted type with a water-suspending mesh electrode above a dielectric-covered counter electrode. The H2O density in the normal DBD was close to the density estimated from the saturated vapor pressure, whereas the density in the inverted DBD was about half of that in the former type. The difference is attributed to the upward gas flow in the latter type, that pushes the water molecules up towards the gas-water interface.

Universal model for water costs of gas exchange by animals and plants

OpenAIRE

Woods, H. Arthur; Smith, Jennifer N.

2010-01-01

For terrestrial animals and plants, a fundamental cost of living is water vapor lost to the atmosphere during exchange of metabolic gases. Here, by bringing together previously developed models for specific taxa, we integrate properties common to all terrestrial gas exchangers into a universal model of water loss. The model predicts that water loss scales to gas exchange with an exponent of 1 and that the amount of water lost per unit of gas exchanged depends on several factors: the surface t...

Conversion of tritium gas to tritiated water in the environment

International Nuclear Information System (INIS)

Noguchi, Hiroshi; Kato, Shohei

1985-01-01

The literature on conversion of tritium gas to tritiated water in various environments is reviewed. The conversion mechanisms and the conversion rates are as follows. 1. In the oxidation with oxygen and the isotopic exchange with water, tritium β-rays and metal catalyst are effective. The oxidation rate is ∼ 0.02 %/day at initial tritium concentration ≤ 10 -2 Ci/l and ∼ 2 %/day at 1 Ci/l. In the presence of oxygen and water, it is not clear whether the exchange reaction occurs or not because of the small amount of data. 2. For biological conversion, soil microorganisms contribute significantly. The conversion rate is greater than 10 %/hr. The tritium gas deposition velocity, which includes the uptake rate of tritium gas by soil and the conversion rate, ranges from 0.0025 to 0.11 cm/sec and is influenced by temperature and moisture of the soil. 3. Tritium gas is converted to the tritiated water through the reaction with hydroxyl radical produced by sunlight in the atmosphere. (author)

Cooling performance of helium-gas/water coolers in HENDEL

International Nuclear Information System (INIS)

Inagaki, Yoshiyuki; Takada, Shoji; Hayashi, Haruyoshi; Kobayashi, Toshiaki; Ohta, Yukimaru; Shimomura, Hiroaki; Miyamoto, Yoshiaki

1994-01-01

The helium engineering demonstration loop (HENDEL) has four helium-gas/water coolers where the cooling water flows in the tubes and helium gas on the shell side. Their cooling performance was studied using the operational data from 1982 to 1991. The heat transfer of helium gas on the shell was obtained for segmental and step-up baffle type coolers. Also, the change with operation time was investigated. The cooling performance was lowered by the graphite powder released from the graphite components for several thousand hours and thereafter recovered because the graphite powder from the components was reduced and the powder in the cooler shell was blown off during the operation. (orig.)

Beam transmission in MP equipment. New measurements. Main effects and application to VIVITRON

International Nuclear Information System (INIS)

Haas, F.; Muller, C.; Nadji, A.; Rebmeister, R.

1989-01-01

The MP equipment is presented and the vacuum values at different measuring points are indicated. The low energy transmission stage (foil and gas strippers) high energy stage (5, 10, and 15 micro-g/cm 2 foils and gas stripper) are described, as well as the global system. For the Vivitron, in order to reach equilibrium thickness, pression in the stripping channel should be higher than that in the MP channel, and pump power should be planned accordingly [fr

Increase in gas output by active modification of the water pressure regime

Energy Technology Data Exchange (ETDEWEB)

Zakirov, S N; Gordon, V Y; Kondrat, R M; Kravtsov, N A; Somov, B Y

1981-01-01

Based on gas-hydrodynamic calculations made on a planar model formation, two variants of formation working are examined. In the first variant, the modern ideology of working gas fields with a water pressure regime are simulated. In the second variant, working of the formation is modeled according to the suggested ideology of active modification of the water-pressure regime by operating the flooded gas wells. The calculations made indicate the efficiency of active modification of the water pressure regime from the viewpoint of controlling the fund of E wells, and most important, maximizing the final coefficient of gas bed output.

Energy Demodulation Algorithm for Flow Velocity Measurement of Oil-Gas-Water Three-Phase Flow

Directory of Open Access Journals (Sweden)

Yingwei Li

2014-01-01

Full Text Available Flow velocity measurement was an important research of oil-gas-water three-phase flow parameter measurements. In order to satisfy the increasing demands for flow detection technology, the paper presented a gas-liquid phase flow velocity measurement method which was based on energy demodulation algorithm combing with time delay estimation technology. First, a gas-liquid phase separation method of oil-gas-water three-phase flow based on energy demodulation algorithm and blind signal separation technology was proposed. The separation of oil-gas-water three-phase signals which were sampled by conductance sensor performed well, so the gas-phase signal and the liquid-phase signal were obtained. Second, we used the time delay estimation technology to get the delay time of gas-phase signals and liquid-phase signals, respectively, and the gas-phase velocity and the liquid-phase velocity were derived. At last, the experiment was performed at oil-gas-water three-phase flow loop, and the results indicated that the measurement errors met the need of velocity measurement. So it provided a feasible method for gas-liquid phase velocity measurement of the oil-gas-water three-phase flow.

MHD/gas turbine systems designed for low cooling water requirements

International Nuclear Information System (INIS)

Annen, K.D.; Eustis, R.H.

1983-01-01

The MHD/gas turbine combined-cycle system has been designed specifically for applications where the availability of cooling water is very limited. The base case systems which were studied consist of a coal-fired MHD plant with an air turbine bottoming plant and require no cooling water. In addition to the base case systems, systems were considered which included the addition of a vapor cycle bottoming plant to improve the thermal efficiency. These systems require a small amount of cooling water. The results show that the MHD/gas turbine systems have very good thermal and economic performances. The base case I MHD/gas turbine system (782 MW /SUB e/ ) requires no cooling water, has a heat rate which is 13% higher, and a cost of electricity which is only 7% higher than a comparable MHD/steam system (878 MW /SUB e/ ) having a cooling tower heat load of 720 MW. The case I vapor cycle bottomed systems have thermal and economic performances which approach and even exceed those of the MHD/steam system, while having substantially lower cooling water requirements. Performances of a second-generation MHD/gas turbine system and an oxygen-enriched, early commercial system are also evaluated. An analysis of nitric oxide emissions shows compliance with emission standards

Influence of surfactants on gas-hydrate formation' kinetics in water-oil emulsion

Science.gov (United States)

Zemenkov, Yu D.; Shirshova, A. V.; Arinstein, E. A.; Shuvaev, A. N.

2018-05-01

The kinetics of gas hydrate formation of propane in a water-oil emulsion is experimentally studied when three types of surfactants (SAA (surface acting agent)) - anionic type emulsifiers - are added to the aqueous phase. It is shown that all three types of surfactants decelerate the growth of the gas-hydrate in the emulsion and can be considered as anti-agglutinating and kinetic low-dose inhibitors. The most effective inhibitor of hydrate formation in water-oil emulsion of SV-102 surfactant was revealed. For comparison, experimental studies of gas-hydrate formation under the same conditions for bulk water have been carried out. It is shown that in bulk water, all the surfactants investigated act as promoters (accelerators) of hydrate formation. A qualitative explanation of the action mechanisms of emulsifiers in the process of gas-hydrate formation in water-oil emulsion is given.

Detritiation of Tritiated Effluent Gas and Water

International Nuclear Information System (INIS)

Ahn, Do Hee; Kim, Kwang Rag; Paek, Seung Woo; Lee, Min Soo; Yim, Sung Paal; Chung Hong Suk

2007-06-01

In a demonstration scale equipment for treatment of tritium in off-gas, Pt/SDBC as oxidation catalyst and Zeolite 13X as adsorbent was charged in the beds, respectively. It was confirmed from the performance test that decontamination factor of the equipment showed more than 100 under the flow rate of off-gas of 90 l/hr and at the temperature of 65 ∼ 80 .deg. C. A small scale CECE process has been developed combining LPCE catalytic column with SPE (solid polymer electrolyte) electrolysis. The catalytic column was a trickle-bed type packed with the mixture of 1 wt% Pt/SDBC catalyst and 4 mm Dixon wire-mesh ring. The experimental results of the CECE process proved that the decontamination factor of 13 ∼ 20 under the operating conditions of the water of the 4 l/day and the effluent hydrogen gas of 16.2 mol/h. A design code of CECE process also developed which will be applied the tritium industry. An experimental method for the reduction of tritiated organic waste by using catalytic oxidation was tested in a heated catalytic reactor of 0.5 wt% Pd/Al 2 O 3 . The simulated organic liquid was converted to water over 99%. A gas chromatographic column material was developed for the separation of mixed hydrogen isotopes. 17 wt% Pd-Pt on alumina showed 90% separation efficiency at 77 % yield for the separation of 29.2 % D 2 -H 2 gas mixture

Detritiation of Tritiated Effluent Gas and Water

Energy Technology Data Exchange (ETDEWEB)

Ahn, Do Hee; Kim, Kwang Rag; Paek, Seung Woo; Lee, Min Soo; Yim, Sung Paal; Chung Hong Suk

2007-06-15

In a demonstration scale equipment for treatment of tritium in off-gas, Pt/SDBC as oxidation catalyst and Zeolite 13X as adsorbent was charged in the beds, respectively. It was confirmed from the performance test that decontamination factor of the equipment showed more than 100 under the flow rate of off-gas of 90 l/hr and at the temperature of 65 {approx} 80 .deg. C. A small scale CECE process has been developed combining LPCE catalytic column with SPE (solid polymer electrolyte) electrolysis. The catalytic column was a trickle-bed type packed with the mixture of 1 wt% Pt/SDBC catalyst and 4 mm Dixon wire-mesh ring. The experimental results of the CECE process proved that the decontamination factor of 13 {approx} 20 under the operating conditions of the water of the 4 l/day and the effluent hydrogen gas of 16.2 mol/h. A design code of CECE process also developed which will be applied the tritium industry. An experimental method for the reduction of tritiated organic waste by using catalytic oxidation was tested in a heated catalytic reactor of 0.5 wt% Pd/Al{sub 2}O{sub 3}. The simulated organic liquid was converted to water over 99%. A gas chromatographic column material was developed for the separation of mixed hydrogen isotopes. 17 wt% Pd-Pt on alumina showed 90% separation efficiency at 77 % yield for the separation of 29.2 % D{sub 2}-H{sub 2} gas mixture.

Performance Assessment of Hazardous Air Pollutant (HAP)Free Chemical Paint Strippers on Military Coatings for Validation to Federal Specification TT-R-2918A

Science.gov (United States)

2016-03-01

ARL-TN-0742 ● MAR 2016 US Army Research Laboratory Performance Assessment of Hazardous Air Pollutant (HAP)–Free Chemical Paint...the originator. ARL-TN-0742 ● MAR 2016 US Army Research Laboratory Performance Assessment of Hazardous Air Pollutant (HAP...COVERED (From - To) 1–30 April 2014 4. TITLE AND SUBTITLE Performance Assessment of Hazardous Air Pollutant (HAP)–Free Chemical Paint Strippers

Water Saturation Relations and Their Diffusion-Limited Equilibration in Gas Shale: Implications for Gas Flow in Unconventional Reservoirs

Science.gov (United States)

Tokunaga, Tetsu K.; Shen, Weijun; Wan, Jiamin; Kim, Yongman; Cihan, Abdullah; Zhang, Yingqi; Finsterle, Stefan

2017-11-01

Large volumes of water are used for hydraulic fracturing of low permeability shale reservoirs to stimulate gas production, with most of the water remaining unrecovered and distributed in a poorly understood manner within stimulated regions. Because water partitioning into shale pores controls gas release, we measured the water saturation dependence on relative humidity (rh) and capillary pressure (Pc) for imbibition (adsorption) as well as drainage (desorption) on samples of Woodford Shale. Experiments and modeling of water vapor adsorption into shale laminae at rh = 0.31 demonstrated that long times are needed to characterize equilibrium in larger (5 mm thick) pieces of shales, and yielded effective diffusion coefficients from 9 × 10-9 to 3 × 10-8 m2 s-1, similar in magnitude to the literature values for typical low porosity and low permeability rocks. Most of the experiments, conducted at 50°C on crushed shale grains in order to facilitate rapid equilibration, showed significant saturation hysteresis, and that very large Pc (˜1 MPa) are required to drain the shales. These results quantify the severity of the water blocking problem, and suggest that gas production from unconventional reservoirs is largely associated with stimulated regions that have had little or no exposure to injected water. Gravity drainage of water from fractures residing above horizontal wells reconciles gas production in the presence of largely unrecovered injected water, and is discussed in the broader context of unsaturated flow in fractures.

Gas exchange rates across the sediment-water andd air-water interfaces in south San Francisco Bay

International Nuclear Information System (INIS)

Hartman, B.; Hammond, D.E.

1984-01-01

Radon 222 concentrations in the water and sedimentary columns and radon exchange rates across the sediment-water and air-water interfaces have been measured in a section of south San Francisco Bay. Two independent methods have been used to determine sediment-water exchange rates, and the annual averages of these methods agree within the uncertainity of the determinations, about 20%. The annual average of bethic fluxes from shoal areas is nearly a factor of 2 greater than fluxes from the channel areas. Fluxes from the shoal and channel areas exceed those expected from simple molecular diffusion by factors of 4 and 2, respectively, apparently due to macrofaunal irrigation. Values of the gas transfer coefficient for radon exchange across the air-water inteface were determined by constructing a radon mass balance for the water column and by direct measurement using floating chambers. The chamber method appears to yield results which are too high. Transfer coefficients computed using the mass balance method range from 0.4 m/day to 1.8 m/day, with a 6-year average of 1.0 m/day. Gas exchange is linearly dependent upon wind speed over a wind speed range of 3.2--6.4 m/s, but shows no dependence upon current velocity. Gas transfer coefficients predicted from an empirical relationship between gas exchange rates and wind speed observed in lakes and the oceans are within 30% of the coefficients determined from the radon mass balance and are considerably more accurate than coefficients predicted from theoretical gas exchange models

Gas exchange rates across the sediment-water and air-water interfaces in south San Francisco Bay

Science.gov (United States)

Hartman, Blayne; Hammond, Douglas E.

1984-01-01

Radon 222 concentrations in the water and sedimentary columns and radon exchange rates across the sediment-water and air-water interfaces have been measured in a section of south San Francisco Bay. Two independent methods have been used to determine sediment-water exchange rates, and the annual averages of these methods agree within the uncertainty of the determinations, about 20%. The annual average of benthic fluxes from shoal areas is nearly a factor of 2 greater than fluxes from the channel areas. Fluxes from the shoal and channel areas exceed those expected from simple molecular diffusion by factors of 4 and 2, respectively, apparently due to macrofaunal irrigation. Values of the gas transfer coefficient for radon exchange across the air-water interface were determined by constructing a radon mass balance for the water column and by direct measurement using floating chambers. The chamber method appears to yield results which are too high. Transfer coefficients computed using the mass balance method range from 0.4 m/day to 1.8 m/day, with a 6-year average of 1.0 m/day. Gas exchange is linearly dependent upon wind speed over a wind speed range of 3.2–6.4 m/s, but shows no dependence upon current velocity. Gas transfer coefficients predicted from an empirical relationship between gas exchange rates and wind speed observed in lakes and the oceans are within 30% of the coefficients determined from the radon mass balance and are considerably more accurate than coefficients predicted from theoretical gas exchange models.

Essentials of water systems design in the oil, gas, and chemical processing industries

CERN Document Server

Bahadori, Alireza; Boyd, Bill

2013-01-01

Essentials of Water Systems Design in the Oil, Gas and Chemical Processing Industries provides valuable insight for decision makers by outlining key technical considerations and requirements of four critical systems in industrial processing plants—water treatment systems, raw water and plant water systems, cooling water distribution and return systems, and fire water distribution and storage facilities. The authors identify the key technical issues and minimum requirements related to the process design and selection of various water supply systems used in the oil, gas, and chemical processing industries. This book is an ideal, multidisciplinary work for mechanical engineers, environmental scientists, and oil and gas process engineers.

Recovery of Water from Boiler Flue Gas Using Condensing Heat Exchangers

Energy Technology Data Exchange (ETDEWEB)

Edward Levy; Harun Bilirgen; John DuPoint

2011-03-31

Most of the water used in a thermoelectric power plant is used for cooling, and DOE has been focusing on possible techniques to reduce the amount of fresh water needed for cooling. DOE has also been placing emphasis on recovery of usable water from sources not generally considered, such as mine water, water produced from oil and gas extraction, and water contained in boiler flue gas. This report deals with development of condensing heat exchanger technology for recovering moisture from flue gas from coal-fired power plants. The report describes: (1) An expanded data base on water and acid condensation characteristics of condensing heat exchangers in coal-fired units. This data base was generated by performing slip stream tests at a power plant with high sulfur bituminous coal and a wet FGD scrubber and at a power plant firing high-moisture, low rank coals. (2) Data on typical concentrations of HCl, HNO{sub 3} and H{sub 2}SO{sub 4} in low temperature condensed flue gas moisture, and mercury capture efficiencies as functions of process conditions in power plant field tests. (3) Theoretical predictions for sulfuric acid concentrations on tube surfaces at temperatures above the water vapor dewpoint temperature and below the sulfuric acid dew point temperature. (4) Data on corrosion rates of candidate heat exchanger tube materials for the different regions of the heat exchanger system as functions of acid concentration and temperature. (5) Data on effectiveness of acid traps in reducing sulfuric acid concentrations in a heat exchanger tube bundle. (6) Condensed flue gas water treatment needs and costs. (7) Condensing heat exchanger designs and installed capital costs for full-scale applications, both for installation immediately downstream of an ESP or baghouse and for installation downstream of a wet SO{sub 2} scrubber. (8) Results of cost-benefit studies of condensing heat exchangers.

Recovery of Water from Boiler Flue Gas Using Condensing Heat Exchangers

Energy Technology Data Exchange (ETDEWEB)

Levy, Edward; Bilirgen, Harun; DuPont, John

2011-03-31

Most of the water used in a thermoelectric power plant is used for cooling, and DOE has been focusing on possible techniques to reduce the amount of fresh water needed for cooling. DOE has also been placing emphasis on recovery of usable water from sources not generally considered, such as mine water, water produced from oil and gas extraction, and water contained in boiler flue gas. This report deals with development of condensing heat exchanger technology for recovering moisture from flue gas from coal-fired power plants. The report describes: • An expanded data base on water and acid condensation characteristics of condensing heat exchangers in coal-fired units. This data base was generated by performing slip stream tests at a power plant with high sulfur bituminous coal and a wet FGD scrubber and at a power plant firing highmoisture, low rank coals. • Data on typical concentrations of HCl, HNO{sub 3} and H{sub 2}SO{sub 4} in low temperature condensed flue gas moisture, and mercury capture efficiencies as functions of process conditions in power plant field tests. • Theoretical predictions for sulfuric acid concentrations on tube surfaces at temperatures above the water vapor dewpoint temperature and below the sulfuric acid dew point temperature. • Data on corrosion rates of candidate heat exchanger tube materials for the different regions of the heat exchanger system as functions of acid concentration and temperature. • Data on effectiveness of acid traps in reducing sulfuric acid concentrations in a heat exchanger tube bundle. • Condensed flue gas water treatment needs and costs. • Condensing heat exchanger designs and installed capital costs for full-scale applications, both for installation immediately downstream of an ESP or baghouse and for installation downstream of a wet SO{sub 2} scrubber. • Results of cost-benefit studies of condensing heat exchangers.

The Effect of Rain on Air-Water Gas Exchange

Science.gov (United States)

Ho, David T.; Bliven, Larry F.; Wanninkhof, Rik; Schlosser, Peter

1997-01-01

The relationship between gas transfer velocity and rain rate was investigated at NASA's Rain-Sea Interaction Facility (RSIF) using several SF, evasion experiments. During each experiment, a water tank below the rain simulator was supersaturated with SF6, a synthetic gas, and the gas transfer velocities were calculated from the measured decrease in SF6 concentration with time. The results from experiments with IS different rain rates (7 to 10 mm/h) and 1 of 2 drop sizes (2.8 or 4.2 mm diameter) confirm a significant and systematic enhancement of air-water gas exchange by rainfall. The gas transfer velocities derived from our experiment were related to the kinetic energy flux calculated from the rain rate and drop size. The relationship obtained for mono-dropsize rain at the RSIF was extrapolated to natural rain using the kinetic energy flux of natural rain calculated from the Marshall-Palmer raindrop size distribution. Results of laboratory experiments at RSIF were compared to field observations made during a tropical rainstorm in Miami, Florida and show good agreement between laboratory and field data.

Emergency management in the gas and water supply; Notfallmanagement in der Gas- und Wasserversorgung

Energy Technology Data Exchange (ETDEWEB)

Boy, Stephan [KKI GmbH, Kompetenzzentrum Kritische Infrastrukturen GmbH, Berlin (Germany)

2013-06-15

Gas and water pipes belong to the critical infrastructure in Germany. Their protection requires a holistic risk analysis, which also keep an eye on the dependence of the power supply. [German] Gas- und Wasserleitungen gehoeren zu den kritischen Infrastrukturen in Deutschland. Ihr Schutz erfordert eine ganzheitliche Risikoanalyse, die auch die Abhaengigkeit von der Stromversorgung im Blick hat.

Gas-Induced Water-hammer Loads Calculation for Safety Related Systems

Energy Technology Data Exchange (ETDEWEB)

Lee, Seungchan; Yoon, Dukjoo [Korea Hydro and Nuclear Power Co., LTd, Daejeon (Korea, Republic of); Lee, Dooyong [Seoul National Univ., Seoul (Korea, Republic of)

2013-05-15

Of particular interest, gas accumulation can result in system pressure transient in pump discharge piping following a pump start. Consequently, this evolves into a gas-water, a water-hammer event and the accompanying force imbalances on the piping segments can be sufficient to challenge the piping supports and restraint. This paper describes an method performing to the water-hammer loads to determine the maximum loading that would occur in the piping system following the safety injection signal and to evaluate its integrity. For a given gas void volumes in the discharge piping, the result of the calculation shows the maximum loads of 18,894.2psi, which is smaller than the allowable criteria. Also, the maximum peak axial force imbalances acting on the support is 1,720lbf as above.

Gas-Induced Water-hammer Loads Calculation for Safety Related Systems

International Nuclear Information System (INIS)

Lee, Seungchan; Yoon, Dukjoo; Lee, Dooyong

2013-01-01

Of particular interest, gas accumulation can result in system pressure transient in pump discharge piping following a pump start. Consequently, this evolves into a gas-water, a water-hammer event and the accompanying force imbalances on the piping segments can be sufficient to challenge the piping supports and restraint. This paper describes an method performing to the water-hammer loads to determine the maximum loading that would occur in the piping system following the safety injection signal and to evaluate its integrity. For a given gas void volumes in the discharge piping, the result of the calculation shows the maximum loads of 18,894.2psi, which is smaller than the allowable criteria. Also, the maximum peak axial force imbalances acting on the support is 1,720lbf as above

Risks to Water Resources from Shale Gas Development and Hydraulic Fracturing in the United States

Science.gov (United States)

Vengosh, Avner; Jackson, Robert B.; Warner, Nathaniel; Darrah, Thomas H.; Kondash, Andrew

2014-05-01

The rise of shale gas development through horizontal drilling and high volume hydraulic fracturing has expanded oil and gas exploration in the USA. The rapid rate of shale gas exploration has triggered an intense public debate regarding the potential environmental and human health effects. A review of the updated literature has identified four potential risks for impacts on water resources: (1) stray gas contamination of shallow aquifers near shale gas sites; (2) contamination of surface water and shallow groundwater from spills, leaks, and disposal of inadequately treated wastewater or hydraulic fracturing fluids; (3) accumulation of toxic and radioactive residues in soil or stream sediments near disposal or spill sites; and (4) over-extraction of water resources for drilling and hydraulic fracturing that could induce water shortages and conflicts with other water users, particularly in water-scarce areas. As part of a long-term research on the potential water contamination associated with shale gas development, new geochemical and isotopic techniques have been developed for delineating the origin of gases and contaminants in water resource. In particular, multiple geochemical and isotopic (carbon isotopes in hydrocarbons, noble gas, strontium, boron, radium isotopes) tracers have been utilized to distinguish between naturally occurring dissolved gas and salts in water and contamination directly induced from shale gas drilling and hydraulic fracturing operations.

Corrosion behaviour of steels and CRA in sour gas environments

Energy Technology Data Exchange (ETDEWEB)

Lara, M. Alvarez de; Lancha, A.M.; Hernandez, F.; Gomez-Briceno, D. [CIEMAT, Avenida Complutense 22, 28040 Madrid (Spain); Coca, P. [ELCOGAS, S.A., C.T. GICC Puertollano, Carretera de Calzada de Calatrava a Puertollano, km 27, 13500 Puertollano, Ciudad Real (Spain)

2004-07-01

The ELCOGAS power plant in Puertollano (Spain), with 335 MWe (ISO conditions), is an Integrated Gasification Combined Cycle (IGCC) plant built to demonstrate both the technical and economic feasibility of this alternative for clean generation of electricity from coal. IGCC technology is based on a coal gasification process, namely the conversion of coal into combustible gas, which is then subjected to an exhaustive cleaning process. The result is a synthetic gas, virtually free of pollutants that can be burned with a high efficiency in a combined cycle electricity-generating unit. Basically, the ELCOGAS plant consists of three islands jointly designed and integrated into the process: gasification island, air separation island and combined cycle island. In the gasification island, the gas from the gasifier is cleaned (de-dusted and washed) and desulfurized before being sent to the combined cycle island. The washing system consists of a Venturi scrubber with a separator where halogens and alkalis (NH{sub 3}, HCl, HF) are removed from the previously de-dusted gas by means of the wash water. The halogens and alkalis removed are then stripped from the wash water as stripped gas, which is a sour gas. The coal-gas coming from the separator proceeds to sulphur removal in a MDEA system and then, the clean gas (mainly CO, H{sub 2}) is sent to the combined cycle plant. As COS is a significant part of the sulphur containing gases in the coal gas, hydrolysis of the COS to H{sub 2}S takes place before the desulfurization stage, since MDEA is a selective amine for H{sub 2}S. There are many important areas related to materials corrosion within the gas cleaning system. In the ELCOGAS plant carbon steels, austenitic stainless steels and nickel based alloys, such as AISI 316Ti, AISI 904L and Hastelloy C276, are used in the Venturi, the water separator and the strippers. AISI 316Ti is used for the gas piping from the separator to the COS hydrolysis system. Laboratory tests to evaluate

Drought Resilience of Water Supplies for Shale Gas Extraction and Related Power Generation in Texas

Science.gov (United States)

Reedy, R. C.; Scanlon, B. R.; Nicot, J. P.; Uhlman, K.

2014-12-01

There is considerable concern about water availability to support energy production in Texas, particularly considering that many of the shale plays are in semiarid areas of Texas and the state experienced the most extreme drought on record in 2011. The Eagle Ford shale play provides an excellent case study. Hydraulic fracturing water use for shale gas extraction in the play totaled ~ 12 billion gallons (bgal) in 2012, representing ~7 - 10% of total water use in the 16 county play area. The dominant source of water is groundwater which is not highly vulnerable to drought from a recharge perspective because water is primarily stored in the confined portion of aquifers that were recharged thousands of years ago. Water supply drought vulnerability results primarily from increased water use for irrigation. Irrigation water use in the Eagle Ford play was 30 billion gallons higher in the 2011 drought year relative to 2010. Recent trends toward increased use of brackish groundwater for shale gas extraction in the Eagle Ford also reduce pressure on fresh water resources. Evaluating the impacts of natural gas development on water resources should consider the use of natural gas in power generation, which now represents 50% of power generation in Texas. Water consumed in extracting the natural gas required for power generation is equivalent to ~7% of the water consumed in cooling these power plants in the state. However, natural gas production from shale plays can be overall beneficial in terms of water resources in the state because natural gas combined cycle power generation decreases water consumption by ~60% relative to traditional coal, nuclear, and natural gas plants that use steam turbine generation. This reduced water consumption enhances drought resilience of power generation in the state. In addition, natural gas combined cycle plants provide peaking capacity that complements increasing renewable wind generation which has no cooling water requirement. However, water

78 FR 64905 - Carriage of Conditionally Permitted Shale Gas Extraction Waste Water in Bulk

Science.gov (United States)

2013-10-30

...-ZA31 Carriage of Conditionally Permitted Shale Gas Extraction Waste Water in Bulk AGENCY: Coast Guard... availability of a proposed policy letter concerning the carriage of shale gas extraction waste water in bulk... transport shale gas extraction waste water in bulk. The policy letter also defines the information the Coast...

Ultra high vacuum activities and required modification at 14 UD BARC-TIFR pelletron accelerator facility

International Nuclear Information System (INIS)

Sharma, S.C.; Ninawe, N.G.; Ramjilal; Bhagwat, P.V.; Salvi, S.B.

2003-01-01

Full text: The 14 UD pelletron accelerator is working round the clock since 1989. The accelerator is housed inside a tank which is 6 meter in diameter and 25 meter long. The accelerator tank is pressurized with SF 6 at 80 to 100 PSIG in order to achieve 14MV. In pelletron, ions are extracted from SNICS are pre-accelerated up to 300 keV before being injected into low energy accelerator tube. In the terminal which is at high potential (4MV to 14 MV), the ion beam pass through the stripper and positive ions with high charge states are produced. The high energy beams are focussed and analyzed by 90 deg magnet. The analyzed beam is then transported to the various experimental ports. In order to achieve uniform ultra high vacuum (to reduce the loss of intensity and spread in the energy of ions beams) in more than 100 metre and 100 mm diameter beam lines including magnet chambers and various beam diagnostic devices, combination of getter-ion pumps and turbo pumps are being used at Pelletron Accelerator Facility. The 14 UD pelletron is equipped with a combination of foil and gas stripper in high voltage terminal section. The foil and gas stripper in the terminal section are mainly used for stripping of light and heavy ions respectively. The gas stripper plays a great role for stripping of heavy ions and its efficiency depends on gas stripper parameters and supporting pumps. The gas stripper is originally installed with getter pumps. These pumps required periodic replacement of titanium cartridges and slowly the pumping speed used to diminish with time. A new recirculation turbo molecular pumps based system is being designed to improve good beam transmission. Details of design will be presented. Proton beam of tens of MeV energy and μA range current is in demand to carry out specific radiochemistry experiments in this facility. It is proposed to built and accommodate a proton experimental setup in the tower area of the existing facility. Details of required UHV system for

Effect of water injection on nitric oxide emissions of a gas turbine combustor burning natural gas fuel

Science.gov (United States)

Marchionna, N. R.; Diehl, L. A.; Trout, A. M.

1973-01-01

The effect of direct water injection on the exhaust gas emissions of a turbojet combustor burning natural gas fuel was investigated. The results are compared with the results from similar tests using ASTM Jet-A fuel. Increasing water injection decreased the emissions of oxides of nitrogen (NOX) and increased the emissions of carbon monoxide and unburned hydrocarbons. The greatest percentage decrease in NOX with increasing water injection was at the lowest inlet-air temperature tested. The effect of increasing inlet-air temperature was to decrease the effect of the water injection. The reduction in NOX due to water injection was almost identical to the results obtained with Jet-A fuel. However, the emission indices of unburned hydrocarbons, carbon monoxide, and percentage nitric oxide in NOX were not.

Fracture lines: will Canada's water be protected in the rush to develop shale gas?

Energy Technology Data Exchange (ETDEWEB)

Parfitt, Ben [Munk School of Global Affairs at the University of Toronto (Canada)

2010-10-15

By combining hydraulic fracking with horizontal drilling, the gas industry has been able to unlock significant amounts of natural gas trapped inside deep and densely packed shale rock. The exploitation of shale gas has been a remarkable revolution in the last decade, going from hardly any production in 2000 to 20% of the United States' gas production in 2010. This cheap and abundant resource has been referred to as a game changer by North American industries and governments. However concerns about water usage and groundwater contamination have been raised. Indeed, the shale gas industry is responsible for the contamination of about 1,000 water wells and has been criticized for its important water withdrawals. This report intends to present the effects of shale gas production on the water supplies in Canada. It reviews the state of groundwater mapping in shale rich regions and reviews regulatory frameworks to determine if they are sufficient to protect water resources.

The Air-Carbon-Water Synergies and Trade-Offs in China's Natural Gas Industry

Science.gov (United States)

Qin, Yue

China's coal-dominated energy structure is partly responsible for its domestic air pollution, local water stress, and the global climate change. Primarily to tackle the haze issue, China has been actively promoting a nationwide coal to natural gas end-use switch. My dissertation focuses on evaluating the air quality, carbon, and water impacts and their interactions in China's natural gas industry. Chapter 2 assesses the lifecycle climate performance of China's shale gas in comparison to coal based on stage-level energy consumption and methane leakage rates. I find the mean lifecycle carbon footprint of shale gas is about 30-50% lower than that of coal under both 20 year and 100 year global warming potentials (GWP20 and GWP100). However, primarily due to large uncertainties in methane leakage, the lifecycle carbon footprint of shale gas in China could be 15-60% higher than that of coal across sectors under GWP20. Chapter 3 evaluates the air quality, human health, and the climate impacts of China's coal-based synthetic natural gas (SNG) development. Based on earlier 2020 SNG production targets, I conduct an integrated assessment to identify production technologies and end-use applications that will bring as large air quality and health benefits as possible while keeping carbon penalties as small as possible. I find that, due to inefficient and uncontrolled coal combustion in households, allocating currently available SNG to the residential sector proves to be the best SNG allocation option. Chapter 4 compares the air quality, carbon, and water impacts of China's six major gas sources under three end-use substitution scenarios, which are focused on maximizing air pollutant emission reductions, CO 2 emission reductions, and water stress index (WSI)-weighted water consumption reductions, respectively. I find striking national air-carbon/water trade-offs due to SNG, which also significantly increases water demands and carbon emissions in regions already suffering from

Economics of Condensing Gas Furnaces and Water Heaters Potential in Residential Single Family Homes

OpenAIRE

Lekov, Alex

2010-01-01

Residential space and water heating accounts for over 90percent of total residential primary gas consumption in the United States. Condensing space and water heating equipment are 10-30percent more energy-efficient than conventional space and water heating. Currently, condensing gas furnaces represent 40 percent of shipments and are common in the Northern U.S. market. Meanwhile, manufacturers are planning to develop condensing gas storage water heaters to qualify for Energy Star? certificati...

Test facility for fast gas injections into a vessel filled with water

International Nuclear Information System (INIS)

Wilhelm, D.; Kirstahler, M.

1987-11-01

The Fast Gas Injection Facility (SGI) was set up to study the hydrodynamics during the expansion of a gas bubble into a vessel filled with water. The gas stored in a pressure vessel expands against gravity through a circular duct into a large cylindrical vessel partly with water. This report covers the description of the test facility and the data acquisition. Results of the first test series are added. (orig.) [de

Gas and water permeability of concrete for reactor buildings small specimens

International Nuclear Information System (INIS)

Mills, R.H.

1986-03-01

The effect on permeability of artifical aging by drying shrinkage and by freeze-thaw was determined by observing mass transfer of gas and water under a pressure gradient. It was found that damage due to freeze-thaw was negligible but that cracking around aggregate caused by drying shrinkage resulted in significantly increased permeability to both gas and water. The absence of freeze-thaw damage was attributed to self-dessication. Since the concrete was not exposed to an external source of water, the chemical reaction was sustained by consumption of mixing water. The resulting air voids were, apparently, sufficient to absorb expansive pressures due to ice formation. The response to lateral prestress was different for cracked and uncracked concrete. Although, in all cases, increased prestress resulted in reduced leakage, the effect was stronger in cracked concrete. Mean pore diameter as determined by gas diffusion was not, however, substantially affected because the leakage in cracked concrete remained very low. Reinforcing steel did not have a great influence on permeability of small specimens. Gas transmission through concrete was strongly influenced by moisture content. Free moisture constituted a barrier to gas flow, acting as a virtual solid. This is important since aging of concrete results in reduced free moisture. Ultrasonic pulse velocity appeared to vary with moisture content and porosity of concrete in the same way as gas permeability and gave promise of being effective for in-situ monitoring of concrete in reactor buildings

Electric fields, electron production, and electron motion at the stripper foil in the Los Alamos Proton Storage Ring

International Nuclear Information System (INIS)

Plum, M.

1995-01-01

The beam instability at the Los Alamos Proton Storage Ring (PSR) most likely involves coupled oscillations between electrons and protons. For this instability to occur, there must be a strong source of electrons. Investigation of the various sources of electrons in the PSR had begun. Copious electron production is expected in the injection section because this section contains the stripper foil. This foil is mounted near the center of the beam pipe, and both circulating and injected protons pass through it, thus allowing ample opportunity for electron production. This paper discusses various mechanisms for electron production, beam-induced electric fields, and electron motion in the vicinity of the foil

An evaluation of water quality in private drinking water wells near natural gas extraction sites in the Barnett Shale formation.

Science.gov (United States)

Fontenot, Brian E; Hunt, Laura R; Hildenbrand, Zacariah L; Carlton, Doug D; Oka, Hyppolite; Walton, Jayme L; Hopkins, Dan; Osorio, Alexandra; Bjorndal, Bryan; Hu, Qinhong H; Schug, Kevin A

2013-09-03

Natural gas has become a leading source of alternative energy with the advent of techniques to economically extract gas reserves from deep shale formations. Here, we present an assessment of private well water quality in aquifers overlying the Barnett Shale formation of North Texas. We evaluated samples from 100 private drinking water wells using analytical chemistry techniques. Analyses revealed that arsenic, selenium, strontium and total dissolved solids (TDS) exceeded the Environmental Protection Agency's Drinking Water Maximum Contaminant Limit (MCL) in some samples from private water wells located within 3 km of active natural gas wells. Lower levels of arsenic, selenium, strontium, and barium were detected at reference sites outside the Barnett Shale region as well as sites within the Barnett Shale region located more than 3 km from active natural gas wells. Methanol and ethanol were also detected in 29% of samples. Samples exceeding MCL levels were randomly distributed within areas of active natural gas extraction, and the spatial patterns in our data suggest that elevated constituent levels could be due to a variety of factors including mobilization of natural constituents, hydrogeochemical changes from lowering of the water table, or industrial accidents such as faulty gas well casings.

In situ water and gas injection experiments performed in the Hades Underground Research Facility

Energy Technology Data Exchange (ETDEWEB)

Volckaert, G.; Ortiz, L.; Put, M. [SCK-CEN, Mol (Belgium). Geological Waste Disposal Unit

1995-12-31

The movement of water and gas through plastic clay is an important subject in the research at SCK-CEN on the possible disposal of high level radioactive waste in the Boom clay layer at Mol. Since the construction of the Hades underground research facility in 1983, SCK-CEN has developed and installed numerous piezometers for the geohydrologic characterization and for in situ radionuclide migration experiments. In situ gas and water injection experiments have been performed at two different locations in the underground laboratory. The first location is a multi filter piezometer installed vertically at the bottom of the shaft in 1986. The second location is a three dimensional configuration of four horizontal multi piezometers installed from the gallery. This piezometer configuration was designed for the MEGAS (Modelling and Experiments on GAS migration through argillaceous rocks) project and installed in 1992. It contains 29 filters at distances between 10 m and 15 m from the gallery in the clay. Gas injection experiments show that gas breakthrough occurs at a gas overpressure of about 0.6 MPa. The breakthrough occurs by the creation of gas pathways along the direction of lowest resistance i.e. the zone of low effective stress resulting from the drilling of the borehole. The water injections performed in a filter -- not used for gas injection -- show that the flow of water is also influenced by the mechanical stress conditions. Low effective stress leads to higher hydraulic conductivity. However, water overpressures up to 1.3 MPa did not cause hydrofracturing. Water injections performed in a filter previously used for gas injections, show that the occluded gas hinders the water flow and reduces the hydraulic conductivity by a factor two.

Demonstration of the Tilting of the Gas-Water Interface under Hydrodynamic Conditions.

Science.gov (United States)

Gretener, P. E.

1979-01-01

Describes the construction of an apparatus to demonstrate the tilting of an oil-water, gas-water, or gas-oil interface when the subsurface reservoir is under hydrodynamic conditions (i.e., when conditions of lateral flow exist). The model can be constructed of readily-available materials. (RE)

Investigations on KONUS beam dynamics using the pre-stripper drift tube linac at GSI

Science.gov (United States)

Xiao, C.; Du, X. N.; Groening, L.

2018-04-01

Interdigital H-mode (IH) drift tube linacs (DTLs) based on KONUS beam dynamics are very sensitive to the rf-phases and voltages at the gaps between tubes. In order to design these DTLs, a deep understanding of the underlying longitudinal beam dynamics is mandatory. The report presents tracking simulations along an IH-DTL using the PARTRAN and BEAMPATH codes together with MATHCAD and CST. Simulation results illustrate that the beam dynamics design of the pre-stripper IH-DTL at GSI is sensitive to slight deviations of rf-phase and gap voltages with impact to the mean beam energy at the DTL exit. Applying the existing geometrical design, rf-voltages, and rf-phases of the DTL were re-adjusted. In simulations this re-optimized design can provide for more than 90% of transmission of an intense 15 emA beam keeping the reduction of beam brilliance below 25%.

Storm water permitting for oil and gas facilities

International Nuclear Information System (INIS)

de Blanc, P.C.

1991-01-01

After several false starts, the US Environmental Protection Agency (EPA) published new federal storm water regulations in the November 16, 1990 Federal Register. These regulations identify facilities which must apply for a storm water permit and detail permit application requirements. The regulations appear at 40 CFR 122 Subpart B and became effective December 17, 1990. An outline of these regulations and their applicability to oil and gas facilities is presented. They are: facilities which require a storm water permit; types of storm water permits; permit application deadlines; permit application forms; facilities with existing storm water permits; storm water permit application data requirements; storm water sampling and analysis requirements; and EPA contacts for additional information

Combination gas-producing and waste-water disposal well. [DOE patent application

Science.gov (United States)

Malinchak, R.M.

1981-09-03

The present invention is directed to a waste-water disposal system for use in a gas recovery well penetrating a subterranean water-containing and methane gas-bearing coal formation. A cased bore hole penetrates the coal formation and extends downwardly therefrom into a further earth formation which has sufficient permeability to absorb the waste water entering the borehole from the coal formation. Pump means are disposed in the casing below the coal formation for pumping the water through a main conduit towards the water-absorbing earth formation. A barrier or water plug is disposed about the main conduit to prevent water flow through the casing except for through the main conduit. Bypass conduits disposed above the barrier communicate with the main conduit to provide an unpumped flow of water to the water-absorbing earth formation. One-way valves are in the main conduit and in the bypass conduits to provide flow of water therethrough only in the direction towards the water-absorbing earth formation.

Method of collecting helium cover gas for heavy water moderated reactor

International Nuclear Information System (INIS)

Miyamoto, Keiji; Ueda, Hiroshi.

1981-01-01

Purpose: To reduce the systematic facility cost in a heavy water moderated reactor by contriving the simplification of a helium cover gas collecting intake system. Method: A detachable low pressure metal tank and a neoprene balloon are prepared for a vacuum pump in a permanent vacuum drying facility. When all of the helium cover gas is collected from a heavy water moderated reactor, a large capacity of neoprene balloon capable of temporarily storing it under low pressure is connected to the exhaust of the vacuum pump. On the other hand, while the reactor is operating, a suitable amount of the low pressure tank or neoprene balloon is connected to the exhaust side of the pump, thereby regulating the pressure of the helium cover gas. When refeeding the cover gas, the balloon, with a large capacity for collecting and storing the cover gas is connected to the intake side of the pump. Thus, the pressure regulation, collection of all of the cover gas and refeeding of the cover gas can be conducted without using a high discharge pump and high pressure tank. (Kamimura, M.)

Engineered Osmosis for Energy Efficient Separations: Optimizing Waste Heat Utilization FINAL SCIENTIFIC REPORT DOE F 241.3

Energy Technology Data Exchange (ETDEWEB)

NATHAN HANCOCK

2013-01-13

The purpose of this study is to design (i) a stripper system where heat is used to strip ammonia (NH{sub 3}) and carbon dioxide (CO{sub 2}) from a diluted draw solution; and (ii) a condensation or absorption system where the stripped NH{sub 3} and CO{sub 2} are captured in condensed water to form a re-concentrated draw solution. This study supports the Industrial Technologies Program of the DOE Office of Energy Efficiency and Renewable Energy and their Industrial Energy Efficiency Grand Challenge award solicitation. Results from this study show that stimulated Oasys draw solutions composed of a complex electrolyte solution associated with the dissolution of NH{sub 3} and CO{sub 2} gas in water can successfully be stripped and fully condensed under standard atmospheric pressure. Stripper bottoms NH{sub 3} concentration can reliably be reduced to < 1 mg/L, even when starting with liquids that have an NH{sub 3} mass fraction exceeding 6% to stimulate diluted draw solution from the forward osmosis membrane component of the process. Concentrated draw solution produced by fully condensing the stripper tops was show to exceed 6 M-C with nitrogen-to-carbon (N:C) molar ratios on the order of two. Reducing the operating pressure of the stripper column serves to reduce the partial vapor pressure of both NH{sub 3} and CO{sub 2} in solution and enables lower temperature operation towards integration of industrial low-grade of waste heat. Effective stripping of solutes was observed with operating pressures as low as 100 mbar (3-inHg). Systems operating at reduced pressure and temperature require additional design considerations to fully condense and absorb these constituents for reuse within the Oasys EO system context. Comparing empirical data with process stimulation models confirmed that several key parameters related to vapor-liquid equilibrium and intrinsic material properties were not accurate. Additional experiments and refinement of material property databases within the

Drops of energy: conserving urban water to reduce greenhouse gas emissions.

Science.gov (United States)

Zhou, Yuanchun; Zhang, Bing; Wang, Haikun; Bi, Jun

2013-10-01

Water and energy are two essential resources of modern civilization and are inherently linked. Indeed, the optimization of the water supply system would reduce energy demands and greenhouse gas emissions in the municipal water sector. This research measured the climatic cobenefit of water conservation based on a water flow analysis. The results showed that the estimated energy consumption of the total water system in Changzhou, China, reached approximately 10% of the city's total energy consumption, whereas the industrial sector was found to be more energy intensive than other sectors within the entire water system, accounting for nearly 70% of the total energy use of the water system. In addition, four sustainable water management scenarios would bring the cobenefit of reducing the total energy use of the water system by 13.9%, and 77% of the energy savings through water conservation was indirect. To promote sustainable water management and reduce greenhouse gas emissions, China would require its water price system, both for freshwater and recycled water, to be reformed.

Gas-phase water-mediated equilibrium between methylglyoxal and its geminal diol

Science.gov (United States)

Axson, Jessica L.; Takahashi, Kaito; De Haan, David O.; Vaida, Veronica

2010-01-01

In aqueous solution, aldehydes, and to a lesser extent ketones, hydrate to form geminal diols. We investigate the hydration of methylglyoxal (MG) in the gas phase, a process not previously considered to occur in water-restricted environments. In this study, we spectroscopically identified methylglyoxal diol (MGD) and obtained the gas-phase partial pressures of MG and MGD. These results, in conjunction with the relative humidity, were used to obtain the equilibrium constant, KP, for the water-mediated hydration of MG in the gas phase. The Gibbs free energy for this process, ΔG°, obtained as a result, suggests a larger than expected gas-phase diol concentration. This may have significant implications for understanding the role of organics in atmospheric chemistry. PMID:20142510

Surprisingly low natural gas consumption for hot water in the Netherlands in 1996

International Nuclear Information System (INIS)

Geerse, C.

1997-01-01

The Dutch use hot water more efficient than previously expected. This conclusion is drawn from a recent study of hot water consumption in Dutch households and the corresponding natural gas consumption. Based on that (once-only) hot water use survey the hot water use models, as applied in the annual Basic Survey of Natural Gas Consumption of Small-scale Consumers in the Netherlands (BAK), will be modified. 6 tabs

Malignant human cell transformation of Marcellus shale gas drilling flow back water

OpenAIRE

Yao, Yixin; Chen, Tingting; Shen, Steven S.; Niu, Yingmei; DesMarais, Thomas L; Linn, Reka; Saunders, Eric; Fan, Zhihua; Lioy, Paul; Kluz, Thomas; Chen, Lung-Chi; Wu, Zhuangchun; Costa, Max

2015-01-01

The rapid development of high-volume horizontal hydraulic fracturing for mining natural gas from shale has posed potential impacts on human health and biodiversity. The produced flow back waters after hydraulic stimulation is known to carry high levels of saline and total dissolved solids. To understand the toxicity and potential carcinogenic effects of these waste waters, flow back water from five Marcellus hydraulic fracturing oil and gas wells were analyzed. The physicochemical nature of t...

Measurement of water absorption capacity in wheat flour by a headspace gas chromatographic technique.

Science.gov (United States)

Xie, Wei-Qi; Yu, Kong-Xian; Gong, Yi-Xian

2018-04-17

The purpose of this work is to introduce a new method for quantitatively analyzing water absorption capacity in wheat flour by a headspace gas chromatographic technique. This headspace gas chromatographic technique was based on measuring the water vapor released from a series of wheat flour samples with different contents of water addition. According to the different trends between the vapor and wheat flour phase before and after the water absorption capacity in wheat flour, a turning point (corresponding to water absorption capacity in wheat flour) can be obtained by fitting the data of the water gas chromatography peak area from different wheat flour samples. The data showed that the phase equilibrium in the vial can be achieved in 25 min at desired temperature (35°C). The relative standard deviation of the reaction headspace gas chromatographic technique in water absorption capacity determination was within 3.48%, the relative differences has been determined by comparing the water absorption capacity obtained from this new analytical technique with the data from the reference technique (i.e., the filtration method), which are less than 8.92%. The new headspace gas chromatographic method is automated, accurate and be a reliable tool for quantifying water absorption capacity in wheat flour in both laboratory research and mill applications. © 2018 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

Spraying of metallic powders by hybrid gas/water torch and the effects of inert gas shrouding

Czech Academy of Sciences Publication Activity Database

Kavka, Tetyana; Matějíček, Jiří; Ctibor, Pavel; Hrabovský, Milan

2012-01-01

Roč. 21, 3-4 (2012), s. 695-705 ISSN 1059-9630 R&D Projects: GA MPO FR-TI2/702; GA MPO FR-TI2/561 Institutional research plan: CEZ:AV0Z20430508 Keywords : copper * tungsten * hybrid water-gas torch * plasma facing materials * plasma spraying * gas shroud Subject RIV: BL - Plasma and Gas Discharge Physics Impact factor: 1.481, year: 2012 http://www.springerlink.com/content/j07t3222hnv87882/fulltext.pdf

A relative permeability model to derive fractional-flow functions of water-alternating-gas and surfactant-alternating-gas foam core-floods

International Nuclear Information System (INIS)

Al-Mossawy, Mohammed Idrees; Demiral, Birol; Raja, D M Anwar

2013-01-01

Foam is used in enhanced oil recovery to improve the sweep efficiency by controlling the gas mobility. The surfactant-alternating-gas (SAG) foam process is used as an alternative to the water-alternating-gas (WAG) injection. In the WAG technique, the high mobility and the low density of the gas lead the gas to flow in channels through the high permeability zones of the reservoir and to rise to the top of the reservoir by gravity segregation. As a result, the sweep efficiency decreases and there will be more residual oil in the reservoir. The foam can trap the gas in liquid films and reduces the gas mobility. The fractional-flow method describes the physics of immiscible displacements in porous media. Finding the water fractional flow theoretically or experimentally as a function of the water saturation represents the heart of this method. The relative permeability function is the conventional way to derive the fractional-flow function. This study presents an improved relative permeability model to derive the fractional-flow functions for WAG and SAG foam core-floods. The SAG flow regimes are characterized into weak foam, strong foam without a shock front and strong foam with a shock front. (paper)

A meta-analysis of leaf gas exchange and water status responses to drought.

Science.gov (United States)

Yan, Weiming; Zhong, Yangquanwei; Shangguan, Zhouping

2016-02-12

Drought is considered to be one of the most devastating natural hazards, and it is predicted to become increasingly frequent and severe in the future. Understanding the plant gas exchange and water status response to drought is very important with regard to future climate change. We conducted a meta-analysis based on studies of plants worldwide and aimed to determine the changes in gas exchange and water status under different drought intensities (mild, moderate and severe), different photosynthetic pathways (C3 and C4) and growth forms (herbs, shrubs, trees and lianas). Our results were as follows: 1) drought negatively impacted gas exchange and water status, and stomatal conductance (gs) decreased more than other physiological traits and declined to the greatest extent in shrubs and C3 plants. Furthermore, C4 plants had an advantage compared to C3 plants under the same drought conditions. 2) The decrease in gs mainly reduced the transpiration rate (Tr), and gs could explain 55% of the decrease in the photosynthesis (A) and 74% of the decline in Tr. 3). Finally, gas exchange showed a close relationship with the leaf water status. Our study provides comprehensive information about the changes in plant gas exchange and water status under drought.

Visual observation of gas hydrates nucleation and growth at a water - organic liquid interface

Science.gov (United States)

Stoporev, Andrey S.; Semenov, Anton P.; Medvedev, Vladimir I.; Sizikov, Artem A.; Gushchin, Pavel A.; Vinokurov, Vladimir A.; Manakov, Andrey Yu.

2018-03-01

Visual observation of nucleation sites of methane and methane-ethane-propane hydrates and their further growth in water - organic liquid - gas systems with/without surfactants was carried out. Sapphire Rocking Cell RCS6 with transparent sapphire cells was used. The experiments were conducted at the supercooling ΔTsub = 20.2 °C. Decane, toluene and crude oils were used as organics. Gas hydrate nucleation occurred on water - metal - gas and water - sapphire - organic liquid three-phase contact lines. At the initial stage of growth hydrate crystals rapidly covered the water - gas or water - organics interfaces (depending on the nucleation site). Further hydrate phase accrete on cell walls (sapphire surface) and into the organics volume. At this stage, growth was accompanied by water «drawing out» from under initial hydrate film formed at water - organic interface. Apparently, it takes place due to water capillary inflow in the reaction zone. It was shown that the hydrate crystal morphology depends on the organic phase composition. In the case of water-in-decane emulsion relay hydrate crystallization was observed in the whole sample, originating most likely due to the hydrate crystal intergrowth through decane. Contacts of such crystals with adjacent water droplets result in rapid hydrate crystallization on this droplet.

Tritium-gas/water-vapor monitor. Tests and evaluation

International Nuclear Information System (INIS)

Jalbert, R.A.

1982-07-01

A tritium gas/water-vapor monitor was designed and built by the Health Physics Group at the Los Alamos National Laboratory. In its prototype configuration, the monitor took the shape of two separate instruments: a (total) tritium monitor and a water-vapor monitor. Both instruments were tested and evaluated. The tests of the (total) tritium monitor, basically an improved version of the standard flow-through ion-chamber instrument, are briefly reported here and more completely elsewhere. The tests of the water-vapor monitor indicated that the novel approach used to condense water vapor for scintillation counting has a number of serious drawbacks and that further development of the instrument is unwarranted

Facile nanofibrillation of chitin derivatives by gas bubbling and ultrasonic treatments in water.

Science.gov (United States)

Tanaka, Kohei; Yamamoto, Kazuya; Kadokawa, Jun-ichi

2014-10-29

In this paper, we report that nanofiber network structures were constructed from chitin derivatives by gas bubbling and ultrasonic treatments in water. When chitin was first subjected to N2 gas bubbling with ultrasonication in water, the SEM images of the product showed nanofiber network morphology. However, nanofiber network was not re-constructed by the same N2 gas bubbling and ultrasonic treatments after agglomeration. We then have paid attention to an amidine group to provide the agglomeration-nanofibrillation behavior of chitin derivatives. An amidinated chitin was synthesized by the reaction of the amino groups in a partially deacetylated chitin with N,N-dimethylacetamide dimethyl acetal, which was subjected to CO2 gas bubbling and ultrasonic treatments in water to convert into an amidinium chitin by protonation. The SEM images of the product clearly showed nanofiber network morphology. We further examined re-nanofibrillation of the agglomerated material, which was obtained by mixing the nanofibrillated amidinium chitin with water, followed by drying under reduced pressure. Consequently, the material was re-nanofibrillated by N2 gas bubbling with ultrasonication in water owing to electrostatic repulsion between the amidinium groups. Furthermore, deprotonation of the amidinium chitin and re-protonation of the resulting amidinated chitin were conducted by alkaline treatment and CO2 gas bubbling-ultrasonic treatments, respectively. The material showed the agglomeration-nanofibrillation behavior during the processes. Copyright © 2014 Elsevier Ltd. All rights reserved.

Measurements of gas permeability and non-Darcy flow in gas-water-hydrate systems

Energy Technology Data Exchange (ETDEWEB)

Ersland, G.; Husebo, J.; Graue, A.; Kvamme, B. [Bergen Univ., Bergen (Norway). Dept. of Physics and Technology; Baldwin, B. [Green Country Petrophysics LLC, Dewey, OK (United States); Stevens, J.; Howard, J. [ConocoPhillips, OK (United States)

2008-07-01

Storage of carbon dioxide (CO{sub 2}) in natural gas hydrate reservoirs may offer stable long-term storage of a greenhouse gas while benefiting from methane production, without requiring heat. By exposing hydrate to a thermodynamically preferred hydrate former, CO{sub 2}, the hydrate may be maintained macroscopically in the solid state and retain the stability of the formation. However, there is concern over the flow capacity in such reservoirs. This depends on several factors, notably thermodynamic destabilization of hydrate in small pores due to capillary effects; the presence of liquid channels separating the hydrate from the mineral surfaces; and, the connectivity of gas or liquid filled pores and channels. This paper described a technique for measuring gas permeability in gas-water-hydrate systems. It reported on several experiments that measured gas permeability during stages of hydrate growth in sandstone core plugs. Interactions between minerals and surrounding molecules were also discussed. The formation of methane hydrate in porous media was monitored and quantified with magnetic resonance imaging (MRI). MRI images of hydrate growth within the porous rock were provided along with measurements of gas permeability and non-Darcy flow effects at various hydrate saturations. Gas permeability was measured at steady state flow of methane through the hydrate-bearing core sample. Significant gas permeability was recorded for porous sandstone even when hydrates occupied up to 60 per cent of the pore space. It was concluded that MRI imaging can be used effectively to map and quantify hydrate saturation in sandstone core plugs. 27 refs., 2 tabs., 10 figs.

Present status of the Kyushu University accelerator facility

International Nuclear Information System (INIS)

Mitarai, Shiro; Maeda, Toyokazu; Koga, Yoshihiro

2001-01-01

A large diameter gas stripper was developed and incorporated to a terminal port of the tandem accelerator and test operation was performed. The permeability of low-energy carbon beams in the tandem was remarkably improved with the gas stripper. A recoiled-nuclei mass spectrometer was also developed and facilitated for accurate measurement of the cross sections of 12 C( 4 He, γ) 16 O in cosmic nuclear reactions. Test operation was made for reduction of background due to the injection beams. The plasma-sputtering type ion source was introduced and the beams will be injected into the tandem. (H. Yokoo)

A review on risk assessment techniques for hydraulic fracturing water and produced water management implemented in onshore unconventional oil and gas production.

Science.gov (United States)

Torres, Luisa; Yadav, Om Prakash; Khan, Eakalak

2016-01-01

The objective of this paper is to review different risk assessment techniques applicable to onshore unconventional oil and gas production to determine the risks to water quantity and quality associated with hydraulic fracturing and produced water management. Water resources could be at risk without proper management of water, chemicals, and produced water. Previous risk assessments in the oil and gas industry were performed from an engineering perspective leaving aside important social factors. Different risk assessment methods and techniques are reviewed and summarized to select the most appropriate one to perform a holistic and integrated analysis of risks at every stage of the water life cycle. Constraints to performing risk assessment are identified including gaps in databases, which require more advanced techniques such as modeling. Discussions on each risk associated with water and produced water management, mitigation strategies, and future research direction are presented. Further research on risks in onshore unconventional oil and gas will benefit not only the U.S. but also other countries with shale oil and gas resources. Copyright © 2015 Elsevier B.V. All rights reserved.

Tritium removal by hydrogen isotopic exchange between hydrogen gas and water on hydrophobic catalyst

International Nuclear Information System (INIS)

Morishita, T.; Isomura, S.; Izawa, H.; Nakane, R.

1980-01-01

Many kinds of the hydrophobic catalysts for hydrogen isotopic exchange between hydrogen gas and water have been prepared. The carriers are the hydrophobic organic materials such as polytetrafluoroethylene(PTFE), monofluorocarbon-PTFE mixture(PTFE-FC), and styrene-divinylbenzene copolymer(SDB). 0.1 to 2 wt % Pt is deposited on the carriers. The Pt/SDB catalyst has much higher activity than the Pt/PTFE catalyst and the Pt/PTFE-FC catalyst shows the intermediate value of catalytic activity. The observation of electron microscope shows that the degrees of dispersion of Pt particles on the hydrophobic carriers result in the difference of catalytic activities. A gas-liquid separated type column containing ten stages is constructed. Each stage is composed of both the hydrophobic catalyst bed for the hydrogen gas/water vapor isotopic exchange and the packed column type bed for the water vapor/liquid water isotopic exchange. In the column hydrogen gas and water flow countercurrently and hydrogen isotopes are separated

Discontinuous gas exchange, water loss, and metabolism in Protaetia cretica (Cetoniinae, Scarabaeidae).

Science.gov (United States)

Matthews, Philip G D; White, Craig R

2012-01-01

Insects are at high risk of desiccation because of their small size, high surface-area-to-volume ratio, and air-filled tracheal system that ramifies throughout their bodies to transport O(2) and CO(2) to and from respiring cells. Although the tracheal system offers a high-conductance pathway for the movement of respiratory gases, it has the unintended consequence of allowing respiratory transpiration to the atmosphere. When resting, many species exchange respiratory gases discontinuously, and an early hypothesis for the origin of these discontinuous gas exchange cycles (DGCs) is that they serve to reduce respiratory water loss. In this study, we test this "hygric" hypothesis by comparing rates of CO(2) exchange and water loss among flower beetles Protaetia cretica (Cetoniinae, Scarabaeidae) breathing either continuously or discontinuously. We show that, consistent with the expectations of the hygric hypothesis, rates of total water loss are higher during continuous gas exchange than during discontinuous gas exchange and that the ratio of respiratory water loss to CO(2) exchange is lower during discontinuous gas exchange. This conclusion is in agreement with other studies of beetles and cockroaches that also support the hygric hypothesis. However, this result does not exclude other adaptive hypotheses supported by work on ants and moth pupae. This ambiguity may arise because there are multiple independent evolutionary origins of DGCs and no single adaptive function underlying their genesis. Alternatively, the observed reduction in water loss during DGCs may be a side effect of a nonadaptive gas exchange pattern that is elicited during periods of inactivity.

Analysis of pollutants in air and water using gas chromatography and headspace gas chromatography

Energy Technology Data Exchange (ETDEWEB)

Stenner, H.

1980-01-01

The combination 'personal sampling' with headspace gas chromatography to determine traces of formaldehyde, phenol and benzene in air is investigated in this work, with the aim of developing maximum workplace concentration values (MWL values). Further possible applications of gas chromatography in trace analysis in the environmentally protected area. The analysis of chromium in waste waters (Cr III as acetyl acetonate complex) is investigated as further possible application, whereby optimum conditions are obtained. A modified flame ionization detector was used to increase the detection sensitivity.

An Integrated Approach to Water-Energy Nexus in Shale-Gas Production

Directory of Open Access Journals (Sweden)

Fadhil Y. Al-Aboosi

2018-05-01

Full Text Available Shale gas production is associated with significant usage of fresh water and discharge of wastewater. Consequently, there is a necessity to create proper management strategies for water resources in shale gas production and to integrate conventional energy sources (e.g., shale gas with renewables (e.g., solar energy. The objective of this study is to develop a design framework for integrating water and energy systems including multiple energy sources, the cogeneration process and desalination technologies in treating wastewater and providing fresh water for shale gas production. Solar energy is included to provide thermal power directly to a multi-effect distillation plant (MED exclusively (to be more feasible economically or indirect supply through a thermal energy storage system. Thus, MED is driven by direct or indirect solar energy and excess or direct cogeneration process heat. The proposed thermal energy storage along with the fossil fuel boiler will allow for the dual-purpose system to operate at steady-state by managing the dynamic variability of solar energy. Additionally, electric production is considered to supply a reverse osmosis plant (RO without connecting to the local electric grid. A multi-period mixed integer nonlinear program (MINLP is developed and applied to discretize the operation period to track the diurnal fluctuations of solar energy. The solution of the optimization program determines the optimal mix of solar energy, thermal storage and fossil fuel to attain the maximum annual profit of the entire system. A case study is solved for water treatment and energy management for Eagle Ford Basin in Texas.

Experimental study on total dissolved gas supersaturation in water

Directory of Open Access Journals (Sweden)

Lu Qu

2011-12-01

Full Text Available More and more high dams have been constructed and operated in China. The total dissolved gas (TDG supersaturation caused by dam discharge leads to gas bubble disease or even death of fish. Through a series of experiments, the conditions and requirements of supersaturated TDG generation were examined in this study. The results show that pressure (water depth, aeration, and bubble dissolution time are required for supersaturated TDG generation, and the air-water contact area and turbulence intensity are the main factors that affect the generation rate of supersaturated TDG. The TDG supersaturation levels can be reduced by discharging water to shallow shoals downstream of the dam or using negative pressure pipelines. Furthermore, the TDG supersaturation levels in stilling basins have no direct relationship with those in reservoirs. These results are of great importance for further research on the prediction of supersaturated TDG generation caused by dam discharge and aquatic protection.

Fracture lines: will Canada's water be protected in the rush to develop shale gas?

Energy Technology Data Exchange (ETDEWEB)

Parfitt, Ben [Munk School of Global Affairs at the University of Toronto (Canada)

2010-10-15

By combining hydraulic fracking with horizontal drilling, the gas industry has been able to unlock significant amounts of natural gas trapped inside deep and densely packed shale rock. The exploitation of shale gas has been a remarkable revolution in the last decade, going from hardly any production in 2000 to 20% of the United States' gas production in 2010. This cheap and abundant resource has been referred to as a game changer by North American industries and governments. However concerns about water usage and groundwater contamination have been raised. Indeed, the shale gas industry is responsible for the contamination of about 1,000 water wells and has been criticized for its important water withdrawals. This report intends to present the effects of shale gas production on the water supplies in Canada. It reviews the state of groundwater mapping in shale rich regions and reviews regulatory frameworks to determine if they are sufficient to protect water resources.

A comparative economic assessment of hydrogen production from coke oven gas, water electrolysis and steam reforming of natural gas

International Nuclear Information System (INIS)

Nguyen, Y.V.; Ngo, Y.A.; Tinkler, M.J.; Cowan, N.

2003-01-01

This paper presents the comparative economics of producing hydrogen for the hydrogen economy by recovering it from waste gases from the steel industry, by water electrolysis and by conventional steam reforming of natural gas. Steel makers produce coke for their blast furnace operation by baking coal at high temperature in a reduced environment in their coke ovens. These ovens produce a coke oven gas from the volatiles in the coal. The gas, containing up to 60% hydrogen, is commonly used for its heating value with some of it being flared. The feasibility of recovering this hydrogen from the gas will be presented. A comparison of this opportunity with that of hydrogen from water electrolysis using low cost off-peak electricity from nuclear energy will be made. The impact of higher daily average electricity rate in Ontario will be discussed. The benefits of these opportunities compared with those from conventional steam reforming of natural gas will be highlighted. (author)

Conformational Preferences of Glycerol in the Gas Phase and in Water

Energy Technology Data Exchange (ETDEWEB)

Jeong, Keun Hong [Korea Military Academy, Seoul (Korea, Republic of); Byun, Byung Jin; Kang, Young Kee [Chungbuk National University, Cheongju (Korea, Republic of)

2012-03-15

The conformational study of glycerol has been carried out using the M06-2X/cc-pVTZ level of theory in the gas phase and the SMD M06-2X/cc-pVTZ level of theory in water in order to understand its conformational preferences and solvation effects. Most of the preferred conformers of glycerol have two C{sub 5} hydrogen bonds in the gas phase, as found by the analysis of calorimetric data. It has been known that the solvation drove the hydrogen bonds of glycerol to be weaker and its potential surface to be fatter and that glycerol exists as an ensemble of many feasible local minima in water. The calculated populations of glycerol in the gas phase and in water are consistent with the observed values, which are better than the previously calculated ones at the G2(MP2), CBS-QB3, and SM5.42 HF/6-31G(d) levels of theory

Determination of flow rates of oil, water and gas in pipelines

Energy Technology Data Exchange (ETDEWEB)

Roach, G J; Watt, J S; Zastawny, H W [Commonwealth Scientific and Industrial Research Organisation (CSIRO), Lucas Heights, NSW (Australia). Div. of Mineral Physics

1994-12-31

This paper describes a multiphase flow meter developed by CSIRO for determining of the flow rates of oil, water and gas in high pressure pipelines, and the results of a trial of this flow meter on an offshore oil platform. Two gamma-ray transmission gauges are mounted about a pipeline carrying the full flow of oil, water and gas. The flow rates are determined by combining single energy gamma-ray transmission measurements which determine the mass per unit area of fluids in the gamma-ray beam as a function of time, dual energy gamma-ray transmission (DUET) which determine the approximate mass fraction of oil in the liquids, cross-correlation of gamma-ray transmission measurements, with one gauge upstream of the other, which determines flow velocity, pressure and temperature measurements, and knowledge of the specific gravities of oil and (salt) water, and solubility of the gas in the liquids, all as a function of pressure and temperature. 3 figs.

Determination of flow rates of oil, water and gas in pipelines

Energy Technology Data Exchange (ETDEWEB)

Roach, G.J.; Watt, J.S.; Zastawny, H.W. [Commonwealth Scientific and Industrial Research Organisation (CSIRO), Lucas Heights, NSW (Australia). Div. of Mineral Physics

1993-12-31

This paper describes a multiphase flow meter developed by CSIRO for determining of the flow rates of oil, water and gas in high pressure pipelines, and the results of a trial of this flow meter on an offshore oil platform. Two gamma-ray transmission gauges are mounted about a pipeline carrying the full flow of oil, water and gas. The flow rates are determined by combining single energy gamma-ray transmission measurements which determine the mass per unit area of fluids in the gamma-ray beam as a function of time, dual energy gamma-ray transmission (DUET) which determine the approximate mass fraction of oil in the liquids, cross-correlation of gamma-ray transmission measurements, with one gauge upstream of the other, which determines flow velocity, pressure and temperature measurements, and knowledge of the specific gravities of oil and (salt) water, and solubility of the gas in the liquids, all as a function of pressure and temperature. 3 figs.

Determination of flow rates of oil, water and gas in pipelines

International Nuclear Information System (INIS)

Roach, G.J.; Watt, J.S.; Zastawny, H.W.

1993-01-01

This paper describes a multiphase flow meter developed by CSIRO for determining of the flow rates of oil, water and gas in high pressure pipelines, and the results of a trial of this flow meter on an offshore oil platform. Two gamma-ray transmission gauges are mounted about a pipeline carrying the full flow of oil, water and gas. The flow rates are determined by combining single energy gamma-ray transmission measurements which determine the mass per unit area of fluids in the gamma-ray beam as a function of time, dual energy gamma-ray transmission (DUET) which determine the approximate mass fraction of oil in the liquids, cross-correlation of gamma-ray transmission measurements, with one gauge upstream of the other, which determines flow velocity, pressure and temperature measurements, and knowledge of the specific gravities of oil and (salt) water, and solubility of the gas in the liquids, all as a function of pressure and temperature. 3 figs

Concentration of saline produced water from coalbed methane gas wells in multiple-effect evaporator using waste heat from the gas compressor and compressor drive engine

International Nuclear Information System (INIS)

Sadler, L.Y.; George, O.

1995-01-01

The use of heat of compression from the gas compressor and waste heat from the diesel compressor drive engine in a triple-effect feed forward evaporator was studied as a means of concentrating saline produced water to facilitate its disposal. The saline water, trapped in deeply buried coal seams, must be continuously pumped from coalbed natural gas wells so that the gas can desorb from the coal and make its way to the wellbore. Unlike conventional natural gas which is associated with petroleum and usually reaches the wellhead at high pressure, coalbed natural gas reaches the wellhead at low pressure, usually around 101 kPa (1 atm), and must be compressed near the well site for injection into gas transmission pipelines. The water concentration process was simulated for a typical 3.93 m 3 /s (500 MCF/h), at standard conditions (101 kPa, 289K), at the gas production field in the Warrior Coal Basin of Alabama, but has application to the coalbed gas fields being brought into production throughout the world. It was demonstrated that this process can be considered for concentrating saline water produced with natural gas in cases where the gas must be compressed near the wellhead for transportation to market. 9 refs., 1 fig., 2 tabs

Data and prediction of water content of high pressure nitrogen, methane and natural gas

DEFF Research Database (Denmark)

Folas, Georgios; Froyna, E.W.; Lovland, J.

2007-01-01

New data for the equilibrium water content of nitrogen, methane and one natural gas mixture are presented. The new binary data and existing binary sets were compared to calculated values of dew point temperature using both the CPA (Cubic-Plus-Association) EoS and the GERG-water EoS. CPA is purely...... predictive (i.e. all binary interaction parameters are set equal to 0), while GERG-water uses a temperature dependent interaction parameter fitted to published data. The GERG-water model is proposed as an ISO standard for determining the water content of natural gas. The data sets for nitrogen cover...... conclusion is that GERG-water must be used with caution outside its specified working range. For some selected natural gas mixtures the two models also perform very much alike. The water content of the mixtures decreases with increasing amount of heavier components, and it seems that both models slightly...

Cryogenic system for collecting noble gases from boiling water reactor off-gas

International Nuclear Information System (INIS)

Schmauch, G.E.

1973-01-01

In boiling water reactors, noncondensible gases are expelled from the main condenser. This off-gas stream is composed largely of radiolytic hydrogen and oxygen, air in-leakage, and traces of fission product krypton and xenon. In the Air Products' treatment system, the stoichiometric hydrogen and oxygen are reacted to form water in a catalytic recombiner. The design of the catalytic recombiner is an extension of industrial gas technology developed for purification of argon and helium. The off-gas after the recombiner is processed by cryogenic air-separation technology. The gas is compressed, passed into a reversing heat exchanger where water vapor and carbon dioxide are frozen out, further cooled, and expanded into a distillation column where refrigeration is provided by addition of liquid nitrogen. More than 99.99 percent of the krypton and essentially 100 percent of the xenon entering the column are accumulated in the column bottoms. Every three to six months, the noble-gas concentrate accumulated in the column bottom is removed as liquid, vaporized, diluted with steam, mixed with hydrogen in slight excess of oxygen content, and fed to a small recombiner where all the oxygen reacts to form water. The resulting gas stream, containing from 20 to 40 percent noble gases, is compressed into small storage cylinders for indefinite retention or for decay of all fission gases except krypton-85, followed by subsequent release under controlled conditions and favorable meteorology. This treatment system is based on proven technology that is practiced throughout the industrial gas industry. Only the presence of radioactive materials in the process stream and the application in a nuclear power plant environment are new. Adaptations to meet these new conditions can be made without sacrificing performance, reliability, or safety

Life cycle water consumption and wastewater generation impacts of a Marcellus shale gas well.

Science.gov (United States)

Jiang, Mohan; Hendrickson, Chris T; VanBriesen, Jeanne M

2014-01-01

This study estimates the life cycle water consumption and wastewater generation impacts of a Marcellus shale gas well from its construction to end of life. Direct water consumption at the well site was assessed by analysis of data from approximately 500 individual well completion reports collected in 2010 by the Pennsylvania Department of Conservation and Natural Resources. Indirect water consumption for supply chain production at each life cycle stage of the well was estimated using the economic input-output life cycle assessment (EIO-LCA) method. Life cycle direct and indirect water quality pollution impacts were assessed and compared using the tool for the reduction and assessment of chemical and other environmental impacts (TRACI). Wastewater treatment cost was proposed as an additional indicator for water quality pollution impacts from shale gas well wastewater. Four water management scenarios for Marcellus shale well wastewater were assessed: current conditions in Pennsylvania; complete discharge; direct reuse and desalination; and complete desalination. The results show that under the current conditions, an average Marcellus shale gas well consumes 20,000 m(3) (with a range from 6700 to 33,000 m(3)) of freshwater per well over its life cycle excluding final gas utilization, with 65% direct water consumption at the well site and 35% indirect water consumption across the supply chain production. If all flowback and produced water is released into the environment without treatment, direct wastewater from a Marcellus shale gas well is estimated to have 300-3000 kg N-eq eutrophication potential, 900-23,000 kg 2,4D-eq freshwater ecotoxicity potential, 0-370 kg benzene-eq carcinogenic potential, and 2800-71,000 MT toluene-eq noncarcinogenic potential. The potential toxicity of the chemicals in the wastewater from the well site exceeds those associated with supply chain production, except for carcinogenic effects. If all the Marcellus shale well wastewater is

An overview on exploration and environmental impact of unconventional gas sources and treatment options for produced water.

Science.gov (United States)

Silva, Tânia L S; Morales-Torres, Sergio; Castro-Silva, Sérgio; Figueiredo, José L; Silva, Adrián M T

2017-09-15

Rising global energy demands associated to unbalanced allocation of water resources highlight the importance of water management solutions for the gas industry. Advanced drilling, completion and stimulation techniques for gas extraction, allow more economical access to unconventional gas reserves. This stimulated a shale gas revolution, besides tight gas and coalbed methane, also causing escalating water handling challenges in order to avoid a major impact on the environment. Hydraulic fracturing allied to horizontal drilling is gaining higher relevance in the exploration of unconventional gas reserves, but a large amount of wastewater (known as "produced water") is generated. Its variable chemical composition and flow rates, together with more severe regulations and public concern, have promoted the development of solutions for the treatment and reuse of such produced water. This work intends to provide an overview on the exploration and subsequent environmental implications of unconventional gas sources, as well as the technologies for treatment of produced water, describing the main results and drawbacks, together with some cost estimates. In particular, the growing volumes of produced water from shale gas plays are creating an interesting market opportunity for water technology and service providers. Membrane-based technologies (membrane distillation, forward osmosis, membrane bioreactors and pervaporation) and advanced oxidation processes (ozonation, Fenton, photocatalysis) are claimed to be adequate treatment solutions. Copyright © 2017 Elsevier Ltd. All rights reserved.

Gas, gas, gas... discoveries and developments booming worldwide

International Nuclear Information System (INIS)

Maxwell, F.

2000-01-01

Deep water exploration is yielding more than billion barrel oil fields. Unocal's 3 May discovery of 2-3 Tcf of gas in its Kutei block of Indonesia marks the first major discovery of natural gas in the deep water frontier: Wildcats Gula and Gada were drilled in over 1800 m of water as part of an aggressive search for gas instigated by Unocal last year. The author makes a survey of gas exploration and development throughout the world. (author)

Simultaneous removal of water and BTEX from feed gas for a cryogenic plant

Energy Technology Data Exchange (ETDEWEB)

Jones, S.; Lee, S.; Evans, M.; Chen, R.

1999-07-01

The removal of water and benzene, toluene, ethyl benzene, xylene (BTEX) from the feed gas of a cryogenic plant is critical in order to avoid precipitation of these components in the cold section of the plant. The design of the Hannibal Gas Plant in Sfax, Tunisia, accomplishes the removal of water and BTEX simultaneously. The plant receives 7.1 million Nm{sub 3}/day of feed gas and produces high heating value pipeline quality sales gas by removing nitrogen in the cold box. A methyl diethanol amine (MDEA) treating system at the front end of the plant is designed to remove carbon dioxide. The glycol system takes the saturated gas from the MDEA contactor and reduces the water content to 7 lb/MMscf. The glycol system is also designed to remove more than half of the BTEX from the feed gas so that these aromatic components will not precipitate in the cold section of the plant. GPA experimental data were used to fit the interaction parameters for the computer simulator used to design the glycol system. The results of the plant performance test verify the validity of the design.

Effect of biochar on soil structural characteristics: water retention and gas transport

DEFF Research Database (Denmark)

Sun, Zhencai; Møldrup, Per; Vendelboe, Anders Lindblad

Biochar addition to agricultural soil has been reported to reduce climate gas emission, as well as improve soil fertility and crop productivity. Little, however, is known about biochar effects on soil structural characteristics. This study investigates if biochar-application changes soil structural...... characteristics, as indicated from water retention and gas transport measurements on intact soil samples. Soil was sampled from a field experiment on a sandy loam with four control plots (C) without biochar and four plots (B) with incorporated biochar at a rate of 20 tons per hectare (plot size, 6 x 8 m). The C......-gas diffusivity on intact 100cm3 soil samples (5 replicates in each plot). We found that biochar application significantly decreased soil bulk density, hereby creating higher porosity. At the same soil-water matric potential, all the soil-gas phase parameters (air-filled porosity, air permeability and gas...

Determination of thiobencarb in water samples by gas ...

African Journals Online (AJOL)

Homogeneous liquid-liquid microextraction via flotation assistance (HLLME-FA) coupled with gas chromatography-flame ionization detection (GC-FID) was applied for the extraction and determination of thiobencarb in water samples. In this study, a special extraction cell was designed to facilitate collection of the ...

Evaluation of a flue gas driven open absorption system for heat and water recovery from fossil fuel boilers

International Nuclear Information System (INIS)

Wang, Zhenying; Zhang, Xiaoyue; Li, Zhen

2016-01-01

Highlights: • Flue gas driven open absorption system that efficiently recovers total heat. • Efficient heat and water recovery for various kinds of fossil fuel boilers. • Heat and water recovery efficiencies increase with moisture content of flue gas. • Temperature requirements for district heat supply and domestic hot water were met. • Experimental system surpasses conventional condensing system in total heat recovery. - Abstract: This paper presents an open absorption system for total heat recovery from fossil fuel boilers using the high temperature flue gas as the regeneration heat source. In this system, liquid desiccant serves as the recycling medium, which absorbs waste heat and moisture contained in the low temperature flue gas in the packed tower and then regenerates in the regenerator by the high temperature flue gas. Water vapor generated in the regenerator gets condensed after releasing heat to the heating water system and the condensing water also gets recycled. The return water collects heat from the solution water heat exchanger, the flue gas water heat exchanger and the condenser respectively and is then used for district heating. Driven by the vapor pressure difference between high humidity flue gas and the liquid desiccant, the heat recovery efficiency of the system is not limited by the dew point of the flue gas, enabling a warmer water to be heated up than the conventional condensing boiler. The performance of this system was analyzed theoretically and experimentally and the results showed that the system operated well for both district heat supply and domestic hot water supply. The system efficiency increased with the moisture content of flue gas and the total heat recovery was about 8.5%, 17.2%, 21.2%, and 9.2% higher than the conventional condensing system in the case of coal fired boiler, fuel oil boiler, natural gas boiler, and coke oven gas boiler, respectively.

Development and Validation of a Gas-Fired Residential Heat Pump Water Heater - Final Report

Energy Technology Data Exchange (ETDEWEB)

Michael Garrabrant; Roger Stout; Paul Glanville; Janice Fitzgerald; Chris Keinath

2013-01-21

For gas-fired residential water heating, the U.S. and Canada is predominantly supplied by minimum efficiency storage water heaters with Energy Factors (EF) in the range of 0.59 to 0.62. Higher efficiency and higher cost ($700 - $2,000) options serve about 15% of the market, but still have EFs below 1.0, ranging from 0.65 to 0.95. To develop a new class of water heating products that exceeds the traditional limit of thermal efficiency, the project team designed and demonstrated a packaged water heater driven by a gas-fired ammonia-water absorption heat pump. This gas-fired heat pump water heater can achieve EFs of 1.3 or higher, at a consumer cost of $2,000 or less. Led by Stone Mountain Technologies Inc. (SMTI), with support from A.O. Smith, the Gas Technology Institute (GTI), and Georgia Tech, the cross-functional team completed research and development tasks including cycle modeling, breadboard evaluation of two cycles and two heat exchanger classes, heat pump/storage tank integration, compact solution pump development, combustion system specification, and evaluation of packaged prototype GHPWHs. The heat pump system extracts low grade heat from the ambient air and produces high grade heat suitable for heating water in a storage tank for domestic use. Product features that include conventional installation practices, standard footprint and reasonable economic payback, position the technology to gain significant market penetration, resulting in a large reduction of energy use and greenhouse gas emissions from domestic hot water production.

High-pressure water electrolysis: Electrochemical mitigation of product gas crossover

International Nuclear Information System (INIS)

Schalenbach, Maximilian; Stolten, Detlef

2015-01-01

Highlights: • New technique to reduce gas crossover during water electrolysis • Increase of the efficiency of pressurized water electrolysis • Prevention of safety hazards due to explosive gas mixtures caused by crossover • Experimental realization for a polymer electrolyte membrane electrolyzer • Discussion of electrochemical crossover mitigation for alkaline water electrolysis - Abstract: Hydrogen produced by water electrolysis can be used as an energy carrier storing electricity generated from renewables. During water electrolysis hydrogen can be evolved under pressure at isothermal conditions, enabling highly efficient compression. However, the permeation of hydrogen through the electrolyte increases with operating pressure and leads to efficiency loss and safety hazards. In this study, we report on an innovative concept, where the hydrogen crossover is electrochemically mitigated by an additional electrode between the anode and the cathode of the electrolysis cell. Experimentally, the technique was applied to a proton exchange membrane water electrolyzer operated at a hydrogen pressure that was fifty times larger than the oxygen pressure. Therewith, the hydrogen crossover was reduced and the current efficiency during partial load operation was increased. The concept is also discussed for water electrolysis that is operated at balanced pressures, where the crossover of hydrogen and oxygen is mitigated using two additional electrodes

Gas Bubbles Investigation in Contaminated Water Using Optical Tomography Based on Independent Component Analysis Method

Directory of Open Access Journals (Sweden)

Mohd Taufiq Mohd Khairi

2016-01-01

Full Text Available This paper presents the results of concentration profiles for gas bubble flow in a vertical pipeline containing contaminated water using an optical tomography system. The concentration profiles for the bubble flow quantities are investigated under five different flows conditions, a single bubble, double bubbles, 25% of air opening, 50% of air opening, and 100% of air opening flow rates where a valve is used to control the gas flow in the vertical pipeline. The system is aided by the independent component analysis (ICA algorithm to reconstruct the concentration profiles of the liquid-gas flow. The behaviour of the gas bubbles was investigated in contaminated water in which the water sample was prepared by adding 25 mL of colour ingredients to 3 liters of pure water. The result shows that the application of ICA has enabled the system to detect the presence of gas bubbles in contaminated water. This information provides vital information on the flow inside the pipe and hence could be very significant in increasing the efficiency of the process industries.

Air-water gas exchange and CO2 flux in a mangrove-dominated estuary

Science.gov (United States)

Ho, David T.; Ferrón, Sara; Engel, Victor C.; Larsen, Laurel G.; Barr, Jordan G.

2014-01-01

Mangrove forests are highly productive ecosystems, but the fate of mangrove-derived carbon remains uncertain. Part of that uncertainty stems from the fact that gas transfer velocities in mangrove-surrounded waters are not well determined, leading to uncertainty in air-water CO2 fluxes. Two SF6 tracer release experiments were conducted to determine gas transfer velocities (k(600) = 8.3 ± 0.4 and 8.1 ± 0.6 cm h−1), along with simultaneous measurements of pCO2 to determine the air-water CO2 fluxes from Shark River, Florida (232.11 ± 23.69 and 171.13 ± 20.28 mmol C m−2 d−1), an estuary within the largest contiguous mangrove forest in North America. The gas transfer velocity results are consistent with turbulent kinetic energy dissipation measurements, indicating a higher rate of turbulence and gas exchange than predicted by commonly used wind speed/gas exchange parameterizations. The results have important implications for carbon fluxes in mangrove ecosystems.

Rapid, Real-time Methane Detection in Ground Water Using a New Gas-Water Equilibrator Design

Science.gov (United States)

Ruybal, C. J.; DiGiulio, D. C.; Wilkin, R. T.; Hargrove, K. D.; McCray, J. E.

2014-12-01

Recent increases in unconventional gas development have been accompanied by public concern for methane contamination in drinking water wells near production areas. Although not a regulated pollutant, methane may be a marker contaminant for others that are less mobile in groundwater and thus may be detected later, or at a location closer to the source. In addition, methane poses an explosion hazard if exsolved concentrations reach 5 - 15% volume in air. Methods for determining dissolved gases, such as methane, have evolved over 60 years. However, the response time of these methods is insufficient to monitor trends in methane concentration in real-time. To enable rapid, real-time monitoring of aqueous methane concentrations during ground water purging, a new gas-water equilibrator (GWE) was designed that increases gas-water mass exchange rates of methane for measurement. Monitoring of concentration trends allows a comparison of temporal trends between sampling events and comparison of baseline conditions with potential post-impact conditions. These trends may be a result of removal of stored casing water, pre-purge ambient borehole flow, formation physical and chemical heterogeneity, or flow outside of well casing due to inadequate seals. Real-time information in the field can help focus an investigation, aid in determining when to collect a sample, save money by limiting costs (e.g. analytical, sample transport and storage), and provide an immediate assessment of local methane concentrations. Four domestic water wells, one municipal water well, and one agricultural water well were sampled for traditional laboratory analysis and compared to the field GWE results. Aqueous concentrations measured on the GWE ranged from non-detect to 1,470 μg/L methane. Some trends in aqueous methane concentrations measured on the GWE were observed during purging. Applying a paired t-test comparing the new GWE method and traditional laboratory analysis yielded a p-value 0

Laser-induced breakdown spectroscopy at a water/gas interface: A study of bath gas-dependent molecular species

International Nuclear Information System (INIS)

Adamson, M.; Padmanabhan, A.; Godfrey, G.J.; Rehse, S.J.

2007-01-01

Single-pulse laser-induced breakdown spectroscopy has been performed on the surface of a bulk water sample in an air, argon, and nitrogen gas environment to investigate emissions from hydrogen-containing molecules. A microplasma was formed at the gas/liquid interface by focusing a Nd:YAG laser beam operating at 1064 nm onto the surface of an ultra-pure water sample. A broadband Echelle spectrometer with a time-gated intensified charge-coupled device was used to analyze the plasma at various delay times (1.0-40.0 μs) and for incident laser pulse energies ranging from 20-200 mJ. In this configuration, the dominant atomic spectral features at short delay times are the hydrogen H-alpha and H-beta emission lines at 656 and 486 nm, respectively, as well as emissions from atomic oxygen liberated from the water and air and nitrogen emission lines from the air bath gas. For delay times exceeding approximately 8 μs the emission from molecular species (particularly OH and NH) created after the ablation process dominates the spectrum. Molecular emissions are found to be much less sensitive to variations in pulse energy and exhibit a temporal decay an order of magnitude slower than the atomic emission. The dependence of both atomic hydrogen and OH emission on the bath gas above the surface of the water was studied by performing the experiment at standard pressure in an atmospheric purge box. Electron densities calculated from the Stark broadening of the H-beta and H-gamma lines and plasma excitation temperatures calculated from the ratio of H-beta to H-gamma emission were measured for ablation in the three bath gases

Consideration of heat transfer performance of helium-gas/water coolers in HENDEL

International Nuclear Information System (INIS)

Inagaki, Yoshiyuki; Miyamoto, Yoshiaki

1986-10-01

The helium engineering loop (HENDEL) has four helium-gas/water coolers, where the cooling water flows in the tubes and the helium gas flows on the shell side. Their cooling performance depends on mainly the heat transfer of helium gas on the shell side. This report describes the operational data of the coolers and the consideration of the heat transfer performance which is important for the design of coolers. It becomes clear that Donohue's equation is close to the operational data and conservative for the segmental baffle type cooler and preduction by Fishenden-Saunders or Zukauskas' equation is conservation for the step-up baffle type cooler. (author)

Origin of salinity in produced waters from the Palm Valley gas field, Northern Territory, Australia

International Nuclear Information System (INIS)

Andrew, Anita S.; Whitford, David J.; Berry, Martin D.; Barclay, Stuart A.; Giblin, Angela M.

2005-01-01

The chemical composition and evolution of produced waters associated with gas production in the Palm Valley gas field, Northern Territory, has important implications for issues such as gas reserve calculations, reservoir management and saline water disposal. The occurrence of saline formation water in the Palm Valley field has been the subject of considerable debate. There were no occurrences of mobile water early in the development of the field and only after gas production had reduced the reservoir pressure, was saline formation water produced. Initially this was in small quantities but has increased dramatically with time, particularly after the initiation of compression in November 1996. The produced waters range from highly saline (up to 300,000 mg/L TDS), with unusual enrichments in Ca, Ba and Sr, to low salinity fluids that may represent condensate waters. The Sr isotopic compositions of the waters ( 87 Sr/ 86 Sr = 0.7041-0.7172) are also variable but do not correlate closely with major and trace element abundances. Although the extreme salinity suggests possible involvement of evaporite deposits lower in the stratigraphic sequence, the Sr isotopic composition of the high salinity waters suggests a more complex evolutionary history. The formation waters are chemically and isotopically heterogeneous and are not well mixed. The high salinity brines have Sr isotopic compositions and other geochemical characteristics more consistent with long-term residence within the reservoir rocks than with present-day derivation from a more distal pool of brines associated with evaporites. If the high salinity brines entered the reservoir during the Devonian uplift and were displaced by the reservoir gas into a stagnant pool, which has remained near the reservoir for the last 300-400 Ma, then the size of the brine pool is limited. At a minimum, it might be equivalent to the volume displaced by the reservoired gas

WAG (water-alternating-gas) process design: an update review

Energy Technology Data Exchange (ETDEWEB)

Zahoor, M.K. [University of Engineering and Technology, Lahore (Pakistan). Dept. of Petroleum and Gas Engineering], e-mail: mkzahoor@uet.edu.pk; Derahman, M.N.; Yunan, M.H. [Universiti Teknologi Malaysia, Johor (Malaysia). Dept. of Petroleum Engineering

2011-04-15

The design and implementation of water-alternating-gas (WAG) process in an improved and cost-effective way are still under process. Due to the complexities involved in implementing the process and the lack of information regarding fluid and reservoir properties, the water-alternating-gas process has not yet been as successful as initially expected. This situation can be overcome by better understanding the fluid distribution and flow behavior within the reservoir. The ultimate purpose can be achieved with improved knowledge on wettability and its influence on fluid distribution, capillary pressure, relative permeability, and other design parameters. This paper gives an insight on the WAG process design and the recently developed correlations which are helpful in incorporating the effects of wettability variations on fluid dynamics within the reservoir. (author)

Biogeochemical interactions between of coal mine water and gas well cement

Science.gov (United States)

Gulliver, D. M.; Gardiner, J. B.; Kutchko, B. G.; Hakala, A.; Spaulding, R.; Tkach, M. K.; Ross, D.

2017-12-01

Unconventional natural gas wells drilled in Northern Appalachia often pass through abandoned coal mines before reaching the Marcellus or Utica formations. Biogeochemical interactions between coal mine waters and gas well cements have the potential to alter the cement and compromise its sealing integrity. This study investigates the mineralogical, geochemical, and microbial changes of cement cores exposed to natural coal mine waters. Static reactors with Class H Portland cement cores and water samples from an abandoned bituminous Pittsburgh coal mine simulated the cement-fluid interactions at relevant temperature for time periods of 1, 2, 4, and 6 weeks. Fluids were analyzed for cation and anion concentrations and extracted DNA was analyzed by 16S rRNA gene sequencing and shotgun sequencing. Cement core material was evaluated via scanning electron microscope. Results suggest that the sampled coal mine water altered the permeability and matrix mineralogy of the cement cores. Scanning electron microscope images display an increase in mineral precipitates inside the cement matrix over the course of the experiment. Chemistry results from the reaction vessels' effluent waters display decreases in dissolved calcium, iron, silica, chloride, and sulfate. The microbial community decreased in diversity over the 6-week experiment, with Hydrogenophaga emerging as dominant. These results provide insight in the complex microbial-fluid-mineral interactions of these environments. This study begins to characterize the rarely documented biogeochemical impacts that coal waters may have on unconventional gas well integrity.

Desalination and reuse of high-salinity shale gas produced water: drivers, technologies, and future directions.

Science.gov (United States)

Shaffer, Devin L; Arias Chavez, Laura H; Ben-Sasson, Moshe; Romero-Vargas Castrillón, Santiago; Yip, Ngai Yin; Elimelech, Menachem

2013-09-03

In the rapidly developing shale gas industry, managing produced water is a major challenge for maintaining the profitability of shale gas extraction while protecting public health and the environment. We review the current state of practice for produced water management across the United States and discuss the interrelated regulatory, infrastructure, and economic drivers for produced water reuse. Within this framework, we examine the Marcellus shale play, a region in the eastern United States where produced water is currently reused without desalination. In the Marcellus region, and in other shale plays worldwide with similar constraints, contraction of current reuse opportunities within the shale gas industry and growing restrictions on produced water disposal will provide strong incentives for produced water desalination for reuse outside the industry. The most challenging scenarios for the selection of desalination for reuse over other management strategies will be those involving high-salinity produced water, which must be desalinated with thermal separation processes. We explore desalination technologies for treatment of high-salinity shale gas produced water, and we critically review mechanical vapor compression (MVC), membrane distillation (MD), and forward osmosis (FO) as the technologies best suited for desalination of high-salinity produced water for reuse outside the shale gas industry. The advantages and challenges of applying MVC, MD, and FO technologies to produced water desalination are discussed, and directions for future research and development are identified. We find that desalination for reuse of produced water is technically feasible and can be economically relevant. However, because produced water management is primarily an economic decision, expanding desalination for reuse is dependent on process and material improvements to reduce capital and operating costs.

Contact heating of water products of combustion of natural gas

Energy Technology Data Exchange (ETDEWEB)

Aronov, I Z

1978-01-01

The USSR's NIIST examined the processes and equipment for heating water by submerged combustion using natural gas. Written for engineers involved with the design and application of thermal engineering equipment operating with natural gas, the book emphasizes equipment, test results, and methods of calculating heat transfer for contact gas economizers developed by Scientific Research Institute of Sanitary Engineering and other Soviet organizations. The economic effectiveness of submerged-combustion heating depends on several factors, including equipment design. Recommendations cover cost-effective designs and applications of contact economizers and boilers.

Water-gas exchange of organochlorine pesticides at Lake Chaohu, a large Chinese lake.

Science.gov (United States)

Ouyang, Hui-Ling; He, Wei; Qin, Ning; Kong, Xiang-Zhen; Liu, Wen-Xiu; He, Qi-Shuang; Yang, Chen; Jiang, Yu-Jiao; Wang, Qing-Mei; Yang, Bin; Xu, Fu-Liu

2013-04-01

Organochlorine pesticides (OCPs), a potential threat to ecosystems and human health, are still widely residual in the environment. The residual levels of OCPs in the water and gas phase were monitored in Lake Chaohu, a large Chinese lake, from March 2010 to February 2011. Nineteen types of OCPs were detected in the water with a total concentration of 7.27 ± 3.32 ng/l. Aldrin, DDTs and HCHs were the major OCPs in the water, accounting for 38.3%, 28.9% and 23.6% of the total, respectively. The highest mean concentration (12.32 ng/l) in the water was found in September, while the lowest (1.74 ng/l) was found in November. Twenty types of gaseous OCPs were detected in the atmosphere with a total concentration of 542.0 ± 636.5 pg/m(3). Endosulfan, DDTs and chlordane were the major gaseous OCPs in the atmosphere, accounting for 48.9%, 22.5% and 14.4% of the total, respectively. The mean concentration of gaseous OCPs was significantly higher in summer than in winter. o,p'-DDE was the main metabolite of DDT in both the water and gas phase. Of the HCHs, 52.3% existed as β-HCH in the water, while α-HCH (37.9%) and γ-HCH (30.9%) were dominant isomers in the gas phase. The average fluxes were -21.11, -3.30, -152.41, -35.50 and -1314.15 ng/(m(2) day) for α-HCH, γ-HCH, HCB, DDT and DDE, respectively. The water-gas exchanges of the five types of OCPs indicate that water was the main potential source of gaseous OCPs in the atmosphere. A sensitivity analysis indicated that the water-gas flux of α-HCH, γ-HCH and DDT is more vulnerable than that of HCB and DDE to the variation of the parameters. The possible source of the HCHs in the water was from the historical usage of lindane; however, that in the air was mainly from the recent usage of lindane. The technical DDT and dicofol might be the source of DDTs in the water and air.

Linking otolith microchemistry and surface water contamination from natural gas mining.

Science.gov (United States)

Keller, David H; Zelanko, Paula M; Gagnon, Joel E; Horwitz, Richard J; Galbraith, Heather S; Velinsky, David J

2018-09-01

Unconventional natural gas drilling and the use of hydraulic fracturing technology have expanded rapidly in North America. This expansion has raised concerns of surface water contamination by way of spills and leaks, which may be sporadic, small, and therefore difficult to detect. Here we explore the use of otolith microchemistry as a tool for monitoring surface water contamination from generated waters (GW) of unconventional natural gas drilling. We exposed Brook Trout in the laboratory to three volumetric concentrations of surrogate generated water (SGW) representing GW on day five of drilling. Transects across otolith cross-sections were analyzed for a suite of elements by LA-ICP-MS. Brook Trout exposed to a 0.01-1.0% concentration of SGW for 2, 15, and 30 days showed a significant (p waters and provide support for the use of this technique in natural habitats. To our knowledge, this is the first demonstration of how trace elements in fish otoliths may be used to monitor for surface water contamination from GW. Copyright © 2018 Elsevier Ltd. All rights reserved.

Conversion of tritium gas to tritiated water

International Nuclear Information System (INIS)

Papagiannakopoulos, P.J.; Easterly, C.E.

1979-05-01

The mechanisms of conversion of tritium gas to tritiated water (HTO) have been examined for several tritium gaseous mixtures. The physical and chemical processes involved in the self-radiolysis of such mixtures have been analyzed and the kinetics involved in the formation of HTO has been presented. It has been determined that the formation of the H and/or OH free radicals, as intermediate species, are of significance in the formation of HTO. Therefore, the problem of reducing the rate of formation of tritiated water in a mixture of gaseous tritium with atmospheric components is one of finding an effective scavenger for the H and/or OH free radicals

Numerical simulation of the environmental impact of hydraulic fracturing of tight/shale gas reservoirs on near-surface ground water: background, base cases, shallow reservoirs, short-term gas and water transport

Science.gov (United States)

Researchers examined gas and water transport between a deep tight shale gas reservoir and a shallow overlying aquifer in the two years following hydraulic fracturing, assuming a pre-existing connecting pathway.

The Energy Efficiency of Hot Water Production by Gas Water Heaters with a Combustion Chamber Sealed with Respect to the Room

Directory of Open Access Journals (Sweden)

Grzegorz Czerski

2014-08-01

Full Text Available This paper presents investigative results of the energy efficiency of hot water production for sanitary uses by means of gas-fired water heaters with the combustion chamber sealed with respect to the room in single-family houses and multi-story buildings. Additionally, calculations were made of the influence of pre-heating the air for combustion in the chimney and air supply system on the energy efficiency of hot water production. CFD (Computational Fluid Dynamics software was used for calculation of the heat exchange in this kind of system. The studies and calculations have shown that the use of gas water heaters with a combustion chamber sealed with respect to the room significantly increases the efficiency of hot water production when compared to traditional heaters. It has also been proven that the pre-heating of combustion air in concentric chimney and air supply ducts essentially improves the energy efficiency of gas appliances for hot water production.

Evaluation of RSG-GAS purification system and pool warm water layer supplier performance

International Nuclear Information System (INIS)

Sudiyono; Suhadi; Diah-Erlina-Lestari

2005-01-01

Function of RSG-GAS purification system and warm water supplier (KBE 02) are to pick up dissolve activation result and another dirts of warm water layer. To keep quality of water at the decided level. The system is equipped by heater to supply warm water layer on the reactor pool surface the distribution is to reduce radiation level in the operation hall area a speciality on the reactor pool surface. Line KBE 02 tomord beam tube headitty system supplies water necessary to be shielding to beam tube in use off time. Of the RSG-GAS purification system and pool warm water layer performance date can be shown north of water is always in good condition. To require the dechded requirement. Resin live time is two years and then months

Malignant human cell transformation of Marcellus Shale gas drilling flow back water

Energy Technology Data Exchange (ETDEWEB)

Yao, Yixin [Department of Epidemiology, Shanghai Jiaotong University School of Public Health (China); Department of Environmental Medicine, New York University School of Medicine, Tuxedo, NY 10987 (United States); Chen, Tingting [School of Material Science and Engineering, Nanjing University of Science and Technology, Nanjing 210094 (China); Shen, Steven S. [Biochemistry and Molecular Pharmaceutical, New York University School of Medicine (United States); Niu, Yingmei; DesMarais, Thomas L.; Linn, Reka; Saunders, Eric; Fan, Zhihua [Department of Environmental Medicine, New York University School of Medicine, Tuxedo, NY 10987 (United States); Lioy, Paul [Robert Wood Johnson Medical School Rutgers, The State University of New Jersey, Piscataway, NJ 08854 (United States); Kluz, Thomas; Chen, Lung-Chi [Department of Environmental Medicine, New York University School of Medicine, Tuxedo, NY 10987 (United States); Wu, Zhuangchun, E-mail: wuzhuangchun@mail.njust.edu.cn [College of Science, Donghua University, Shanghai 201620 (China); Costa, Max, E-mail: max.costa@nyumc.org [Department of Environmental Medicine, New York University School of Medicine, Tuxedo, NY 10987 (United States)

2015-10-01

The rapid development of high-volume horizontal hydraulic fracturing for mining natural gas from shale has posed potential impacts on human health and biodiversity. The produced flow back waters after hydraulic stimulation are known to carry high levels of saline and total dissolved solids. To understand the toxicity and potential carcinogenic effects of these wastewaters, flow back waters from five Marcellus hydraulic fracturing oil and gas wells were analyzed. The physicochemical nature of these samples was analyzed by inductively coupled plasma mass spectrometry and scanning electron microscopy/energy dispersive X-ray spectroscopy. A cytotoxicity study using colony formation as the endpoint was carried out to define the LC{sub 50} values of test samples using human bronchial epithelial cells (BEAS-2B). The BEAS-2B cell transformation assay was employed to assess the carcinogenic potential of the samples. Barium and strontium were among the most abundant metals in these samples and the same metals were found to be elevated in BEAS-2B cells after long-term treatment. BEAS-2B cells treated for 6 weeks with flow back waters produced colony formation in soft agar that was concentration dependent. In addition, flow back water-transformed BEAS-2B cells show better migration capability when compared to control cells. This study provides information needed to assess the potential health impact of post-hydraulic fracturing flow back waters from Marcellus Shale natural gas mining. - Highlights: • This is the first report of potential cytotoxicity and transforming activity of Marcellus shale gas mining flow back to mammalian cells. • Barium and Strontium were elevated in flow back water exposed cells. • Flow back water malignantly transformed cells and formed tumor in athymic nude mice. • Flow back transformed cells exhibited altered transcriptome with dysregulated cell migration pathway and adherent junction pathway.

Malignant human cell transformation of Marcellus Shale gas drilling flow back water

International Nuclear Information System (INIS)

Yao, Yixin; Chen, Tingting; Shen, Steven S.; Niu, Yingmei; DesMarais, Thomas L.; Linn, Reka; Saunders, Eric; Fan, Zhihua; Lioy, Paul; Kluz, Thomas; Chen, Lung-Chi; Wu, Zhuangchun; Costa, Max

2015-01-01

The rapid development of high-volume horizontal hydraulic fracturing for mining natural gas from shale has posed potential impacts on human health and biodiversity. The produced flow back waters after hydraulic stimulation are known to carry high levels of saline and total dissolved solids. To understand the toxicity and potential carcinogenic effects of these wastewaters, flow back waters from five Marcellus hydraulic fracturing oil and gas wells were analyzed. The physicochemical nature of these samples was analyzed by inductively coupled plasma mass spectrometry and scanning electron microscopy/energy dispersive X-ray spectroscopy. A cytotoxicity study using colony formation as the endpoint was carried out to define the LC 50 values of test samples using human bronchial epithelial cells (BEAS-2B). The BEAS-2B cell transformation assay was employed to assess the carcinogenic potential of the samples. Barium and strontium were among the most abundant metals in these samples and the same metals were found to be elevated in BEAS-2B cells after long-term treatment. BEAS-2B cells treated for 6 weeks with flow back waters produced colony formation in soft agar that was concentration dependent. In addition, flow back water-transformed BEAS-2B cells show better migration capability when compared to control cells. This study provides information needed to assess the potential health impact of post-hydraulic fracturing flow back waters from Marcellus Shale natural gas mining. - Highlights: • This is the first report of potential cytotoxicity and transforming activity of Marcellus shale gas mining flow back to mammalian cells. • Barium and Strontium were elevated in flow back water exposed cells. • Flow back water malignantly transformed cells and formed tumor in athymic nude mice. • Flow back transformed cells exhibited altered transcriptome with dysregulated cell migration pathway and adherent junction pathway.

A Statistical Framework for Automatic Leakage Detection in Smart Water and Gas Grids

Directory of Open Access Journals (Sweden)

Marco Fagiani

2016-08-01

Full Text Available In the last few years, due to the technological improvement of advanced metering infrastructures, water and natural gas grids can be regarded as smart-grids, similarly to power ones. However, considering the number of studies related to the application of computational intelligence to distribution grids, the gap between power grids and water/gas grids is notably wide. For this purpose, in this paper, a framework for leakage identification is presented. The framework is composed of three sections aimed at the extraction and the selection of features and at the detection of leakages. A variation of the Sequential Feature Selection (SFS algorithm is used to select the best performing features within a set, including, also, innovative temporal ones. The leakage identification is based on novelty detection and exploits the characterization of a normality model. Three statistical approaches, The Gaussian Mixture Model (GMM, Hidden Markov Model (HMM and One-Class Support Vector Machine (OC-SVM, are adopted, under a comparative perspective. Both residential and office building environments are investigated by means of two datasets. One is the Almanac of Minutely Power dataset (AMPds, and it provides water and gas data consumption at 1, 10 and 30 min of time resolution; the other is the Department of International Development (DFID dataset, and it provides water and gas data consumption at 30 min of time resolution. The achieved performance, computed by means of the Area Under the Curve (AUC, reaches 90 % in the office building case study, thus confirming the suitability of the proposed approach for applications in smart water and gas grids.

Delineation of ground-water contamination using soil-gas analyses near Jackson, Tennessee

Science.gov (United States)

Lee, R.W.

1991-01-01

An investigation of the ground-water resources near Jackson, West Tennessee, was conducted during 1988-89. The study included determination of the occurrence of contaminants in the shallow aquifer using soil-gas analyses in the unsaturated zone. Between 1980 and 1988, an underground fuel-storage tank leaked about 3,000 gallons of unleaded fuel to the water table about 4 feet below land surface. A survey of soil gas using a gas chromatograph equipped with a photoionization detector showed concentrations of volatile organic compounds greater than IO, 000 parts per million near the leak These compounds were detected in an area about 240 feet long and 110 feet wide extending west from the point source. The chromatograms provided two distinct 'fingerprints' of volatile organic compounds. The first revealed the presence of benzene, toluene, andxylenes, which are constituents of unleaded fuel, in addition to other volatile compounds, in soil gas in the area near the leak The second did not reveal any detectable benzene, toluene, or xylenes in the soil-gas samples, but showed the presence of other unidentified volatile organic compounds in soil gas north of the storage tank. The distribution of total concentrations of volatile organic compounds in the unsaturated zone indicated that a second plume about 200 feet long and 90 feet wide was present about 100 feet north of the storage tank The second plume could have been the result of previous activities at this site during the 1950's or earlier. Activities at the site are believed to have included storage of solvents used at the nearby railyard and flushing of tanks containing tar onto a gravel-covered parking area. The delineation of these plumes has shown that soil-gas analyses can be a useful technique for identifying areas of contamination with volatile organic compounds in shallow water-table aquifers and may have broad applications in similar situations where the water table is relatively close to the surface.

Method for confirming flow pattern of gas-water flow in horizontal tubes under rolling state

International Nuclear Information System (INIS)

Luan Feng; Yan Changqi

2008-01-01

An experimental study on the flow patterns of gas-water flow was carried out in horizontal tubes under rolling state. It was found that the pressure drop of two phase flow was with an obvious periodical characteristic. The flow pattern of the gas-water flow was distinguished according to the characteristics of the pressure drop in this paper. It was proved that the characteristics of the pressure drop can distinguish the flow pattern of gas-water flow correctly through comparing with the result of careful observation and high speed digital camera. (authors)

Gas exchange patterns and water loss rates in the Table Mountain cockroach, Aptera fusca (Blattodea: Blaberidae).

Science.gov (United States)

Groenewald, Berlizé; Bazelet, Corinna S; Potter, C Paige; Terblanche, John S

2013-10-15

The importance of metabolic rate and/or spiracle modulation for saving respiratory water is contentious. One major explanation for gas exchange pattern variation in terrestrial insects is to effect a respiratory water loss (RWL) saving. To test this, we measured the rates of CO2 and H2O release ( and , respectively) in a previously unstudied, mesic cockroach, Aptera fusca, and compared gas exchange and water loss parameters among the major gas exchange patterns (continuous, cyclic, discontinuous gas exchange) at a range of temperatures. Mean , and per unit did not differ among the gas exchange patterns at all temperatures (P>0.09). There was no significant association between temperature and gas exchange pattern type (P=0.63). Percentage of RWL (relative to total water loss) was typically low (9.79±1.84%) and did not differ significantly among gas exchange patterns at 15°C (P=0.26). The method of estimation had a large impact on the percentage of RWL, and of the three techniques investigated (traditional, regression and hyperoxic switch), the traditional method generally performed best. In many respects, A. fusca has typical gas exchange for what might be expected from other insects studied to date (e.g. , , RWL and cuticular water loss). However, we found for A. fusca that expressed as a function of metabolic rate was significantly higher than the expected consensus relationship for insects, suggesting it is under considerable pressure to save water. Despite this, we found no consistent evidence supporting the conclusion that transitions in pattern type yield reductions in RWL in this mesic cockroach.

A Numerical Investigation on the Effect of Gas Pressure on the Water Saturation of Compacted Bentonite-Sand Samples

Directory of Open Access Journals (Sweden)

Jiang-Feng Liu

2017-01-01

Full Text Available In deep geological disposal for high-level radioactive waste, the generated gas can potentially affect the sealing ability of bentonite buffers. There is a competition between water and gas: the former provides sealing by swelling bentonite, and the latter attempts to desaturate the bentonite buffer. Thus, this study focused on numerically modelling the coupling effects of water and gas on the water saturation and sealing efficiency of compacted bentonite-sand samples. Different gas pressures were applied to the top surface of an upper sample, whereas the water pressure on the bottom side of the lower sample was maintained at 4 MPa. The results indicated that gas pressure did not significantly affect the saturation of the bentonite-sand sample until 2 MPa. At 2 MPa, the degree of water saturation of the upper sample was close to 1.0. As the gas pressure increased, this influence was more apparent. When the gas pressure was 6 MPa or higher, it was difficult for the upper sample to become fully saturated. Additionally, the lower sample was desaturated due to the high gas pressure. This indicated that gas pressure played an important role in the water saturation process and can affect the sealing efficiency of bentonite-based buffer materials.

Modelling a deep water oil/gas spill under conditions of gas hydrate formation and decomposition

International Nuclear Information System (INIS)

Zheng, L.; Yapa, P.D.

2000-01-01

A model for the behavior of oil and gas spills at deepwater locations was presented. Such spills are subjected to pressures and temperatures that can convert gases to gas hydrates which are lighter than water. Knowing the state of gases as they rise with the plume is important in predicting the fate of an oil or gas plume released in deepwater. The objective of this paper was to develop a comprehensive jet/plume model which includes computational modules that simulate the gas hydrate formation/decomposition of gas bubbles. This newly developed model is based on the kinetics of hydrate formation and decomposition coupled with mass and heat transfer phenomena. The numerical model was successfully tested using results of experimental data from the Gulf of Mexico. Hydrate formation and decomposition are integrated with an earlier model by Yapa and Zheng for underwater oil or gas jets and plumes. The effects of hydrate on the behavior of an oil or gas plume was simulated to demonstrate the models capabilities. The model results indicate that in addition to thermodynamics, the kinetics of hydrate formation/decomposition should be considered when studying the behavior of oil and gas spills. It was shown that plume behavior changes significantly depending on whether or not the local conditions force the gases to form hydrates. 25 refs., 4 tabs., 12 figs

Removal of organic compounds from shale gas flowback water

NARCIS (Netherlands)

Butkovskyi, Andrii; Faber, Ann-Hélène; Wang, Yue; Grolle, Katja; Hofman-Caris, Roberta; Bruning, Harry; Van Wezel, Annemarie P.; Rijnaarts, Huub H M

2018-01-01

Ozonation, sorption to granular activated carbon and aerobic degradation were compared as potential treatment methods for removal of dissolved organic carbon (DOC) fractions and selected organic compounds from shale gas flowback water after pre-treatment in dissolved air flotation unit. Flowback

Acoustic mapping of shallow water gas releases using shipborne multibeam systems

Science.gov (United States)

Urban, Peter; Köser, Kevin; Weiß, Tim; Greinert, Jens

2015-04-01

Water column imaging (WCI) shipborne multibeam systems are effective tools for investigating marine free gas (bubble) release. Like single- and splitbeam systems they are very sensitive towards gas bubbles in the water column, and have the advantage of the wide swath opening angle, 120° or more allowing a better mapping and possible 3D investigations of targets in the water column. On the downside, WCI data are degraded by specific noise from side-lobe effects and are usually not calibrated for target backscattering strength analysis. Most approaches so far concentrated on manual investigations of bubbles in the water column data. Such investigations allow the detection of bubble streams (flares) and make it possible to get an impression about the strength of detected flares/the gas release. Because of the subjective character of these investigations it is difficult to understand how well an area has been investigated by a flare mapping survey and subjective impressions about flare strength can easily be fooled by the many acoustic effects multibeam systems create. Here we present a semi-automated approach that uses the behavior of bubble streams in varying water currents to detect and map their exact source positions. The focus of the method is application of objective rules for flare detection, which makes it possible to extract information about the quality of the seepage mapping survey, perform automated noise reduction and create acoustic maps with quality discriminators indicating how well an area has been mapped.

Simulation of Water Level Fluctuations in a Hydraulic System Using a Coupled Liquid-Gas Model

Directory of Open Access Journals (Sweden)

Chao Wang

2015-08-01

Full Text Available A model for simulating vertical water level fluctuations with coupled liquid and gas phases is presented. The Preissmann implicit scheme is used to linearize the governing equations for one-dimensional transient flow for both liquid and gas phases, and the linear system is solved using the chasing method. Some classical cases for single liquid and gas phase transients in pipelines and networks are studied to verify that the proposed methods are accurate and reliable. The implicit scheme is extended using a dynamic mesh to simulate the water level fluctuations in a U-tube and an open surge tank without consideration of the gas phase. Methods of coupling liquid and gas phases are presented and used for studying the transient process and interaction between the phases, for gas phase limited in a chamber and gas phase transported in a pipeline. In particular, two other simplified models, one neglecting the effect of the gas phase on the liquid phase and the other one coupling the liquid and gas phases asynchronously, are proposed. The numerical results indicate that the asynchronous model performs better, and are finally applied to a hydropower station with surge tanks and air shafts to simulate the water level fluctuations and air speed.

A water column study of methane around gas flares located at the West Spitsbergen continental margin

DEFF Research Database (Denmark)

Gentz, Torben; Damm, Ellen; von Deimling, Jens Schneider

2014-01-01

L1. Our results suggest that the methane dissolved from gas bubbles is efficiently trapped below the pycnocline and thus limits the methane concentration in surface water and the air–sea exchange during summer stratification. During winter the lateral stratification breaks down and fractions...... and ebullition of methane into the water column at more than 250 sites in an area of 665 km2. We conducted a detailed study of a subregion of this area, which covers an active gas ebullition area of 175 km2 characterized by 10 gas flares reaching from the seafloor at ∼245 m up to 50 m water depth to identify...... in the δ13CCH4 values point to a 13C depleted methane source (∼ –60‰ VPDB) being mainly mixed with a background values of the ambient water (∼–37.5‰ VPDB). A gas bubble dissolution model indicates that ∼80% of the methane released from gas bubbles into the ambient water takes place below the pycnocline...

New technology for volatile components stripping in process fluids; Nova tecnologia para estripagem de componentes volateis em fluidos de processo

Energy Technology Data Exchange (ETDEWEB)

Yoshida, Roberto Massao [White Martins Gases Industriais, Rio de Janeiro, RJ (Brazil)

1992-12-31

Stripping is a process used in order to remove volatile contaminants during the purification step by bubbling inert gas in a contaminated liquid. This work defines the stripping process and its process parameters, describes some stripping techniques and introduces the supersonic stripper, that works at supersonic velocity. Dissolved oxygen reduction and stripping time reduction results are shown. The conclusion is that the supersonic stripper is superior to the in-line conventional systems. (author) 6 refs., 2 figs.

New technology for volatile components stripping in process fluids; Nova tecnologia para estripagem de componentes volateis em fluidos de processo

Energy Technology Data Exchange (ETDEWEB)

Yoshida, Roberto Massao [White Martins Gases Industriais, Rio de Janeiro, RJ (Brazil)

1993-12-31

Stripping is a process used in order to remove volatile contaminants during the purification step by bubbling inert gas in a contaminated liquid. This work defines the stripping process and its process parameters, describes some stripping techniques and introduces the supersonic stripper, that works at supersonic velocity. Dissolved oxygen reduction and stripping time reduction results are shown. The conclusion is that the supersonic stripper is superior to the in-line conventional systems. (author) 6 refs., 2 figs.

U.S. Geological Survey Noble Gas Laboratory’s standard operating procedures for the measurement of dissolved gas in water samples

Science.gov (United States)

Hunt, Andrew G.

2015-08-12

This report addresses the standard operating procedures used by the U.S. Geological Survey’s Noble Gas Laboratory in Denver, Colorado, U.S.A., for the measurement of dissolved gases (methane, nitrogen, oxygen, and carbon dioxide) and noble gas isotopes (helium-3, helium-4, neon-20, neon-21, neon-22, argon-36, argon-38, argon-40, kryton-84, krypton-86, xenon-103, and xenon-132) dissolved in water. A synopsis of the instrumentation used, procedures followed, calibration practices, standards used, and a quality assurance and quality control program is presented. The report outlines the day-to-day operation of the Residual Gas Analyzer Model 200, Mass Analyzer Products Model 215–50, and ultralow vacuum extraction line along with the sample handling procedures, noble gas extraction and purification, instrument measurement procedures, instrumental data acquisition, and calculations for the conversion of raw data from the mass spectrometer into noble gas concentrations per unit mass of water analyzed. Techniques for the preparation of artificial dissolved gas standards are detailed and coupled to a quality assurance and quality control program to present the accuracy of the procedures used in the laboratory.

Suitability of pipeline material for buried gas and water piping

Energy Technology Data Exchange (ETDEWEB)

Funk, R

1976-01-01

Following a brief review of the development of the individual pipe materials and their use in the field of gas and water supply, the various stressing possibilities are dealt with. The corrosion influences from inside and outside, the material specifically for internal and external insulation, as well as the stressing due to sediments, are particularly brought out in this connection. A few remarks on the pressure pipes made of ductile cast iron, steel, reinforced concrete, asbestos cement and plastics are followed by comparisons with representations on material parameters to be proved, safety factors, tensile and pressure resistance, breaking tension and stress-strain diagram, wall thicknesses, friction losses, reactions depending on the E. modulus and distribution of the single pipe materials in the gas and water supply.

CO2-Binding Organic Liquids Gas Capture with Polarity-Swing-Assisted Regeneration Full Technology Feasibility Study B1 - Solvent-based Systems

Energy Technology Data Exchange (ETDEWEB)

Heldebrant, David J

2014-08-31

PNNL, Fluor Corporation and Queens University (Kingston, ON) successfully completed a three year comprehensive study of the CO2BOL water-lean solvent platform with Polarity Swing Assisted Regeneration (PSAR). This study encompassed solvent synthesis, characterization, environmental toxicology, physical, thermodynamic and kinetic property measurements, Aspen Plus™ modeling and bench-scale testing of a candidate CO2BOL solvent molecule. Key Program Findings The key program findings are summarized as follows: • PSAR favorably reduced stripper duties and reboiler temperatures with little/no impact to absorption column • >90% CO2 capture was achievable at reasonable liquid-gas ratios in the absorber • High rich solvent viscosities (up to 600 cP) were successfully demonstrated in the bench-scale system. However, the projected impacts of high viscosity to capital cost and operational limits compromised the other levelized cost of electricity benefits. • Low thermal conductivity of organics significantly increased the required cross exchanger surface area, and potentially other heat exchange surfaces. • CO2BOL had low evaporative losses during bench-scale testing • There was no evidence of foaming during bench scale testing • Current CO2BOL formulation costs project to be $35/kg • Ecotoxicity (Water Daphnia) was comparable between CO2BOL and MEA (169.47 versus 103.63 mg/L) • Full dehydration of the flue gas was determined to not be economically feasible. However, modest refrigeration (13 MW for the 550 MW reference system) was determined to be potentially economically feasible, and still produce a water-lean condition for the CO2BOLs (5 wt% steady-state water loading). • CO2BOLs testing with 5 wt% water loading did not compromise anhydrous performance behavior, and showed actual enhancement of CO2 capture performance. • Mass transfer of CO2BOLs was not greatly impeded by viscosity • Facile separation of antisolvent from lean CO2BOL was

Organic Pollutants in Shale Gas Flowback and Produced Waters

NARCIS (Netherlands)

Butkovskyi, Andrii; Bruning, Harry; Kools, Stefan A.E.; Rijnaarts, Huub H.M.; Wezel, van Annemarie P.

2017-01-01

Organic contaminants in shale gas flowback and produced water (FPW) are traditionally expressed as total organic carbon (TOC) or chemical oxygen demand (COD), though these parameters do not provide information on the toxicity and environmental fate of individual components. This review addresses

Water augmented indirectly-fired gas turbine systems and method

Science.gov (United States)

Bechtel, Thomas F.; Parsons, Jr., Edward J.

1992-01-01

An indirectly-fired gas turbine system utilizing water augmentation for increasing the net efficiency and power output of the system is described. Water injected into the compressor discharge stream evaporatively cools the air to provide a higher driving temperature difference across a high temperature air heater which is used to indirectly heat the water-containing air to a turbine inlet temperature of greater than about 1,000.degree. C. By providing a lower air heater hot side outlet temperature, heat rejection in the air heater is reduced to increase the heat recovery in the air heater and thereby increase the overall cycle efficiency.

Relationships between water and gas chemistry in mature coalbed methane reservoirs of the Black Warrior Basin

Science.gov (United States)

Pashin, Jack C.; McIntyre-Redden, Marcella R.; Mann, Steven D.; Kopaska-Merkel, David C.; Varonka, Matthew S.; Orem, William H.

2014-01-01

Water and gas chemistry in coalbed methane reservoirs of the Black Warrior Basin reflects a complex interplay among burial processes, basin hydrodynamics, thermogenesis, and late-stage microbial methanogenesis. These factors are all important considerations for developing production and water management strategies. Produced water ranges from nearly potable sodium-bicarbonate water to hypersaline sodium-chloride brine. The hydrodynamic framework of the basin is dominated by structurally controlled fresh-water plumes that formed by meteoric recharge along the southeastern margin of the basin. The produced water contains significant quantities of hydrocarbons and nitrogen compounds, and the produced gas appears to be of mixed thermogenic-biogenic origin.Late-stage microbial methanogenesis began following unroofing of the basin, and stable isotopes in the produced gas and in mineral cements indicate that late-stage methanogenesis occurred along a CO2-reduction metabolic pathway. Hydrocarbons, as well as small amounts of nitrate in the formation water, probably helped nourish the microbial consortia, which were apparently active in fresh to hypersaline water. The produced water contains NH4+ and NH3, which correlate strongly with brine concentration and are interpreted to be derived from silicate minerals. Denitrification reactions may have generated some N2, which is the only major impurity in the coalbed gas. Carbon dioxide is a minor component of the produced gas, but significant quantities are dissolved in the formation water. Degradation of organic compounds, augmented by deionization of NH4+, may have been the principal sources of hydrogen facilitating late-stage CO2 reduction.

WATER-GAS SHIFT WITH INTEGRATED HYDROGEN SEPARATION; A

International Nuclear Information System (INIS)

Maria Flytzani-Stephanopoulos; Jerry Meldon; Xiaomei Qi

2001-01-01

Optimization of the water-gas shift (WGS) reaction system for hydrogen production for fuel cells is of particular interest to the energy industry. To this end, it is desirable to couple the WGS reaction to hydrogen separation using a semi-permeable membrane, with both processes carried out at high temperature to improve reaction kinetics. Reduced equilibrium conversion of the WGS reaction at high temperatures is overcome by product H(sub 2) removal via the membrane. This project involves fundamental research and development of novel cerium oxide-based catalysts for the water-gas-shift reaction and the integration of these catalysts with Pd-alloy H(sub 2)-separation membranes supplying high purity hydrogen for fuel cell use. Conditions matching the requirements of coal gasifier-exit gas streams will be examined in the project. In the first year of the project, we prepared a series of nanostructured Cu- and Fe-containing ceria catalysts by a special gelation/precipitation technique followed by air calcination at 650 C. Each sample was characterized by ICP for elemental composition analysis, BET-N2 desorption for surface area measurement, and by temperature-programmed reduction in H(sub 2) to evaluate catalyst reducibility. Screening WGS tests with catalyst powders were conducted in a flow microreactor at temperatures in the range of 200-550 C. On the basis of both activity and stability of catalysts in simulated coal gas, and in CO(sub 2)-rich gases, a Cu-CeO(sub 2) catalyst formulation was selected for further study in this project. Details from the catalyst development and testing work are given in this report. Also in this report, we present H(sub 2) permeation data collected with unsupported flat membranes of pure Pd and Pd-alloys over a wide temperature window

Ab initio study of gas phase and water-assisted tautomerization of ...

Indian Academy of Sciences (India)

WINTEC

Water-assisted tautomerization in maleimide and formamide showed that difference in energy barrier reduces to 2⋅83 kcal/mol from 10⋅41 kcal/mol (in gas phase) at B3LYP level, which resulted that maleimide readily undergoes tautomerization in water molecule. Keywords. Ab Initio calculations; maleimide; formamide; ...

Monitoring air pollutants due to gas flaring using rain water | Rim ...

African Journals Online (AJOL)

The mean levels of conductivity, TDS, and SO42- were within statutory safe limits, while that of pH, CO32- and NO3- were above the safe limits specified by the Federal Ministry of Environment guidelines and standards for drinking water quality. Keywords: rainwater, gas flare, pollutants, monitoring, water quality

Energy Requirement and Comfort of Gas- and Electric-powered Hot-water Systems

International Nuclear Information System (INIS)

Luedemann, B.; Schmitz, G.

1999-01-01

In view of the continuous reduction in the specific heating energy demand of new buildings the power demand for hot-water supply increasingly dominates the heating supply of residential buildings. Furthermore, the German energy-savings-regulation 2000 (ESVO) is intended to evaluate the techniques installed such as domestic heating or hot-water supply within an overall energetic view of the building. Planning advice for domestic heating, ventilation and hot-water systems in gas-heated, low-energy buildings has therefore been developed in a common research project of the Technical University of Hamburg Harburg (TUHH) and four energy supply companies. In this article different gas-or electricity-based hot-water systems in one family houses and multiple family houses are compared with one another with regard to the aspects of comfort and power requirements considering the user's behaviour. (author)

Water use in forest canopy black cherry trees and its relationship to leaf gas exchange and environment

Science.gov (United States)

B. J. Joyce; K. C. Steiner; J. M. Skelly

1996-01-01

Models of canopy gas exchange are needed to connect leaf-level measurement to higher scales. Because of the correspondence between leaf gas exchange and water use, it may be possible to predict variation in leaf gas exchange at the canopy level by monitoring rates of branch water use.

The influence of carrier gas flow rate in inverse gas chromatography on the estimation of water vapor adsorption on Nylon-6 micro fiber

OpenAIRE

丸井, 正樹; 山本, 直子; 牛腸, ヒロミ; マルイ, マサキ; ヤマモト, ナオコ; ゴチョウ, ヒロミ; MASAKI, MARUI; NAOKO, YAMAMOTO; HIROMI, GOCHO

2002-01-01

The adsorption behaviors of water vapor on Nylon-6 micro fiber are measured at 90℃ with inverse gas chromatography, of which the carrier gas flow rates are 10～40ml/min. The values of retention volume decrease when the peak area is on the increase. lt indicates that Nylon-6 micro fiber has strong adsorption of water vapor at low vapor pressure. The adsorption isotherm as a whole is found to be of BET II type with certain number of adsorption sites. The gas flow rate has no effect on the estima...

Identification, Verification, and Compilation of Produced Water Management Practices for Conventional Oil and Gas Production Operations

Energy Technology Data Exchange (ETDEWEB)

Rachel Henderson

2007-09-30

The project is titled 'Identification, Verification, and Compilation of Produced Water Management Practices for Conventional Oil and Gas Production Operations'. The Interstate Oil and Gas Compact Commission (IOGCC), headquartered in Oklahoma City, Oklahoma, is the principal investigator and the IOGCC has partnered with ALL Consulting, Inc., headquartered in Tulsa, Oklahoma, in this project. State agencies that also have partnered in the project are the Wyoming Oil and Gas Conservation Commission, the Montana Board of Oil and Gas Conservation, the Kansas Oil and Gas Conservation Division, the Oklahoma Oil and Gas Conservation Division and the Alaska Oil and Gas Conservation Commission. The objective is to characterize produced water quality and management practices for the handling, treating, and disposing of produced water from conventional oil and gas operations throughout the industry nationwide. Water produced from these operations varies greatly in quality and quantity and is often the single largest barrier to the economic viability of wells. The lack of data, coupled with renewed emphasis on domestic oil and gas development, has prompted many experts to speculate that the number of wells drilled over the next 20 years will approach 3 million, or near the number of current wells. This level of exploration and development undoubtedly will draw the attention of environmental communities, focusing their concerns on produced water management based on perceived potential impacts to fresh water resources. Therefore, it is imperative that produced water management practices be performed in a manner that best minimizes environmental impacts. This is being accomplished by compiling current best management practices for produced water from conventional oil and gas operations and to develop an analysis tool based on a geographic information system (GIS) to assist in the understanding of watershed-issued permits. That would allow management costs to be kept in

Methane recovery from coal mine gas using hydrate formation in water-in-oil emulsions

International Nuclear Information System (INIS)

Zhong, Dong-Liang; Ding, Kun; Lu, Yi-Yu; Yan, Jin; Zhao, Wei-Long

2016-01-01

Highlights: • A water-in-oil emulsion was developed for CH_4 separation from coal mine methane gas. • Stable W/O emulsions were obtained with water cut in the range of (10–70%). • Gas hydrates nucleated faster with the reduction of water–oil volume ratio. • Gas uptake increased with the decrease of water–oil volume ratio. • CH_4 recovery was greatly enhanced by hydrate formation in W/O emulsions. - Abstract: In this work, a water-in-oil (W/O) emulsion was developed using liquid water, mineral oil, Sorbitan monooleate (Span 80), and cyclopentane. It was employed to enhance gas hydrate formation for CH_4 separation from a simulated coal mine methane (CMM) gas (30 mol% CH_4, 60 mol% N_2, and 10 mol% O_2). The stability test at atmospheric pressure and at a high pressure of 3.5 MPa showed that stable W/O emulsions were obtained when the water–oil volume ratio (WOR) was below 80%. The emulsified droplets size was measured with WOR ranging from 10% to 70%. Then kinetic experiments of CH_4 separation by hydrate formation in W/O emulsions were carried out at 273.6 K and (3.5–5.0) MPa in batch operation. The results indicated that water–oil volume ratio is a key factor that affects the kinetics of gas hydrate formation from the CMM gas mixture. Hydrate nucleation was observed to occur faster while WOR was decreased, and gas uptake increased significantly with the decrease of WOR. CH_4 concentration in the recovered gas mixture was increased to 52 mol% as compared to 30 mol% in the original gas mixture through one-stage hydrate formation in the W/O emulsions. It was found that the experimental conditions of 273.6 K, 3.5 MPa and WOR = 30% were favorable for CH_4 recovery from the CMM gas. The CH_4 recovery obtained under these conditions was 43%. It was higher than those obtained at WOR = 10% and 70%, and was greatly increased as compared with those obtained in the same reactor with the presence of TBAB (26%) and CP (33%).

Impact of shale gas development on water resources: a case study in northern poland.

Science.gov (United States)

Vandecasteele, Ine; Marí Rivero, Inés; Sala, Serenella; Baranzelli, Claudia; Barranco, Ricardo; Batelaan, Okke; Lavalle, Carlo

2015-06-01

Shale gas is currently being explored in Europe as an alternative energy source to conventional oil and gas. There is, however, increasing concern about the potential environmental impacts of shale gas extraction by hydraulic fracturing (fracking). In this study, we focussed on the potential impacts on regional water resources within the Baltic Basin in Poland, both in terms of quantity and quality. The future development of the shale play was modeled for the time period 2015-2030 using the LUISA modeling framework. We formulated two scenarios which took into account the large range in technology and resource requirements, as well as two additional scenarios based on the current legislation and the potential restrictions which could be put in place. According to these scenarios, between 0.03 and 0.86% of the total water withdrawals for all sectors could be attributed to shale gas exploitation within the study area. A screening-level assessment of the potential impact of the chemicals commonly used in fracking was carried out and showed that due to their wide range of physicochemical properties, these chemicals may pose additional pressure on freshwater ecosystems. The legislation put in place also influenced the resulting environmental impacts of shale gas extraction. Especially important are the protection of vulnerable ground and surface water resources and the promotion of more water-efficient technologies.

Impact of Shale Gas Development on Water Resources: A Case Study in Northern Poland

Science.gov (United States)

Vandecasteele, Ine; Marí Rivero, Inés; Sala, Serenella; Baranzelli, Claudia; Barranco, Ricardo; Batelaan, Okke; Lavalle, Carlo

2015-06-01

Shale gas is currently being explored in Europe as an alternative energy source to conventional oil and gas. There is, however, increasing concern about the potential environmental impacts of shale gas extraction by hydraulic fracturing (fracking). In this study, we focussed on the potential impacts on regional water resources within the Baltic Basin in Poland, both in terms of quantity and quality. The future development of the shale play was modeled for the time period 2015-2030 using the LUISA modeling framework. We formulated two scenarios which took into account the large range in technology and resource requirements, as well as two additional scenarios based on the current legislation and the potential restrictions which could be put in place. According to these scenarios, between 0.03 and 0.86 % of the total water withdrawals for all sectors could be attributed to shale gas exploitation within the study area. A screening-level assessment of the potential impact of the chemicals commonly used in fracking was carried out and showed that due to their wide range of physicochemical properties, these chemicals may pose additional pressure on freshwater ecosystems. The legislation put in place also influenced the resulting environmental impacts of shale gas extraction. Especially important are the protection of vulnerable ground and surface water resources and the promotion of more water-efficient technologies.

GAS STORAGE TECHNOLOGY CONSORTIUM

Energy Technology Data Exchange (ETDEWEB)

Robert W. Watson

2004-10-18

Gas storage is a critical element in the natural gas industry. Producers, transmission and distribution companies, marketers, and end users all benefit directly from the load balancing function of storage. The unbundling process has fundamentally changed the way storage is used and valued. As an unbundled service, the value of storage is being recovered at rates that reflect its value. Moreover, the marketplace has differentiated between various types of storage services, and has increasingly rewarded flexibility, safety, and reliability. The size of the natural gas market has increased and is projected to continue to increase towards 30 trillion cubic feet (TCF) over the next 10 to 15 years. Much of this increase is projected to come from electric generation, particularly peaking units. Gas storage, particularly the flexible services that are most suited to electric loads, is critical in meeting the needs of these new markets. In order to address the gas storage needs of the natural gas industry, an industry-driven consortium was created--the Gas Storage Technology Consortium (GSTC). The objective of the GSTC is to provide a means to accomplish industry-driven research and development designed to enhance operational flexibility and deliverability of the Nation's gas storage system, and provide a cost effective, safe, and reliable supply of natural gas to meet domestic demand. To accomplish this objective, the project is divided into three phases that are managed and directed by the GSTC Coordinator. The first phase, Phase 1A, was initiated on September 30, 2003, and was completed on March 31, 2004. Phase 1A of the project included the creation of the GSTC structure, development and refinement of a technical approach (work plan) for deliverability enhancement and reservoir management. This report deals with Phase 1B and encompasses the period July 1, 2004, through September 30, 2004. During this time period there were three main activities. First was the

Analysis of Ion-Exchange Resin Capability of the RSG-GAS Demineralized Water System (GCA01)

International Nuclear Information System (INIS)

Diyah Erlina Lestari; Setyo Budi Utomo; Harsono

2012-01-01

The Demineralized water system (GCA01) is a system which is function to process raw water to be demineralized water using ion exchange resin unit consisting of a column of cation exchange resins, anion exchange resin column and the column resin mix bed. After certain time the ion exchange resins to be saturated so that is needed regeneration. The RSG-GAS demineralized water system (GCA01) not operated continuously and indication of when does an ion exchange resin regeneration on The RSG-GAS demineralized water system (GCA01) is the water conductivity from anion exchange resin column output indicates ≥ 5μS/cm. Analysis of capability of the ion exchange resin demineralized water system (GCA01) line I has been performed. The analysis was done by comparing the time required in the system operating cycle of regeneration to the next regeneration during the period 2011 and 2012. From the results of the analysis showed the cycle regeneration time is varies. This shows that ion exchange resin capability of the RSG-GAS demineralized water system (GCA01) is varies depending on the raw water quality and success of the regeneration ion exchange resin. (author)

Porn star/stripper/escort: economic and sexual dynamics in a sex work career.

Science.gov (United States)

Escoffier, Jeffrey

2007-01-01

This article explores the career dynamics of performers in the gay male pornography industry, by focusing on a common career path- from porn star to stripper to escort. Between 1995 and 2005, most men performing in gay porn films, unlike contract actresses in the straight porn industry, have been unable to earn enough income to work exclusively as performers in front of the camera. The industry's constant search for new faces and fresh performers creates what sociologist Paul Cressey has called "the retrogressive dynamic": The longer a person works in a sexual occupation, the less one is paid, and the lower the status of the work venue. In the porn industry, one aspect of this process is referred to as "overexposure," during which the performer experiences a diminishing "fantasy potential" as fans lose erotic interest in the porn star who has appeared too frequently in too many movies. Performers attempt to confront the retrogressive dynamic by limiting the number of adult films in which they appear in a year, diversifying their sexual repertoire, or shifting into other roles within the industry (behind the camera, marketing, production, etc.). One common option is to pursue work in economically complementary forms of sex work such as stripping and escorting.

Liquid water transport mechanism in the gas diffusion layer

Energy Technology Data Exchange (ETDEWEB)

Zhou, P.; Wu, C.W. [State Key Laboratory of Structure Analysis for Industrial Equipment, Department of Engineering Mechanics, Faculty of Vehicle Engineering and Mechanics, Dalian University of Technology, Dalian 116024 (China)

2010-03-01

We developed an equivalent capillary model of a microscale fiber-fence structure to study the microscale evolution and transport of liquid in a porous media and to reveal the basic principles of water transport in gas diffusion layer (GDL). Analytical solutions using the model show that a positive hydraulic pressure is needed to drive the liquid water to penetrate through the porous GDL even consisting of the hydrophilic fibers. Several possible contributions for the water configuration, such as capillary pressure, gravity, vapor condensation, wettability and microstructures of the GDL, are discussed using the lattice Boltzmann method (LBM). It is found that the distribution manners of the fibers and the spatial mixed-wettability in the GDL also play an important role in the transport of liquid water. (author)

Statistics of surface divergence and their relation to air-water gas transfer velocity

Science.gov (United States)

Asher, William E.; Liang, Hanzhuang; Zappa, Christopher J.; Loewen, Mark R.; Mukto, Moniz A.; Litchendorf, Trina M.; Jessup, Andrew T.

2012-05-01

Air-sea gas fluxes are generally defined in terms of the air/water concentration difference of the gas and the gas transfer velocity,kL. Because it is difficult to measure kLin the ocean, it is often parameterized using more easily measured physical properties. Surface divergence theory suggests that infrared (IR) images of the water surface, which contain information concerning the movement of water very near the air-water interface, might be used to estimatekL. Therefore, a series of experiments testing whether IR imagery could provide a convenient means for estimating the surface divergence applicable to air-sea exchange were conducted in a synthetic jet array tank embedded in a wind tunnel. Gas transfer velocities were measured as a function of wind stress and mechanically generated turbulence; laser-induced fluorescence was used to measure the concentration of carbon dioxide in the top 300 μm of the water surface; IR imagery was used to measure the spatial and temporal distribution of the aqueous skin temperature; and particle image velocimetry was used to measure turbulence at a depth of 1 cm below the air-water interface. It is shown that an estimate of the surface divergence for both wind-shear driven turbulence and mechanically generated turbulence can be derived from the surface skin temperature. The estimates derived from the IR images are compared to velocity field divergences measured by the PIV and to independent estimates of the divergence made using the laser-induced fluorescence data. Divergence is shown to scale withkLvalues measured using gaseous tracers as predicted by conceptual models for both wind-driven and mechanically generated turbulence.

Estimating national water use associated with unconventional oil and gas development

Science.gov (United States)

Carter, Janet M.; Macek-Rowland, Kathleen M.; Thamke, Joanna N.; Delzer, Gregory C.

2016-05-18

The U.S. Geological Survey’s (USGS) Water Availability and Use Science Program (WAUSP) goals are to provide a more accurate assessment of the status of the water resources of the United States and assist in the determination of the quantity and quality of water that is available for beneficial uses. These assessments would identify long-term trends or changes in water availability since the 1950s in the United States and help to develop the basis for an improved ability to forecast water avail- ability for future economic, energy-production, and environmental uses. The National Water Census (http://water.usgs.gov/watercensus/), a research program of the WAUSP, supports studies to develop new water accounting tools and assess water availability at the regional and national scales. Studies supported by this program target focus areas with identified water availability concerns and topical science themes related to the use of water within a specific type of environmental setting. The topical study described in this fact sheet will focus on understanding the relation between production of unconventional oil and gas (UOG) for energy and the water needed to produce and sustain this type of energy development. This relation applies to the life-cycle of renewable and nonrenewable forms of UOG energy and includes extraction, production, refinement, delivery, and disposal of waste byproducts. Water-use data and models derived from this topical study will be applied to other similar oil and gas plays within the United States to help resource managers assess and account for water used or needed in these areas. Additionally, the results from this topical study will be used to further refine the methods used in compiling water-use data for selected categories (for example, mining, domestic self-supplied, public supply, and wastewater) in the USGS’s 5-year national water-use estimates reports (http://water.usgs.gov/watuse/).

The Assessment of Instruments for Detecting Surface Water Spills Associated with Oil and Gas Operations

Energy Technology Data Exchange (ETDEWEB)

Harris, Aubrey E. [West Virginia Univ., Morgantown, WV (United States); National Energy Technology Lab. (NETL), Morgantown, WV (United States); U.S. Bureau of Reclamation, Albuquerque, NM (United States); Hopkinson, Leslie [West Virginia Univ., Morgantown, WV (United States); Soeder, Daniel [National Energy Technology Lab. (NETL), Morgantown, WV (United States)

2016-12-02

Surface water and groundwater risks associated with unconventional oil and gas development result from potential spills of the large volumes of chemicals stored on-site during drilling and hydraulic fracturing operations, and the return to the surface of significant quantities of saline water produced during oil or gas well production. To better identify and mitigate risks, watershed models and tools are needed to evaluate the dispersion of pollutants in possible spill scenarios. This information may be used to determine the placement of in-stream water-quality monitoring instruments and to develop early-warning systems and emergency plans. A chemical dispersion model has been used to estimate the contaminant signal for in-stream measurements. Spills associated with oil and gas operations were identified within the Susquehanna River Basin Commission’s Remote Water Quality Monitoring Network. The volume of some contaminants was found to be sufficient to affect the water quality of certain drainage areas. The most commonly spilled compounds and expected peak concentrations at monitoring stations were used in laboratory experiments to determine if a signal could be detected and positively identified using standard water-quality monitoring equipment. The results were compared to historical data and baseline observations of water quality parameters, and showed that the chemicals tested do commonly affect water quality parameters. This work is an effort to demonstrate that hydrologic and water quality models may be applied to improve the placement of in-stream water quality monitoring devices. This information may increase the capability of early-warning systems to alert community health and environmental agencies of surface water spills associated with unconventional oil and gas operations.

Waste heat gas utilization for HTGR gas turbine plant for sea water desalination

International Nuclear Information System (INIS)

Hunter, D.A.A.

1981-01-01

A thermodynamic analysis is performed for a HTGR - Gas Turbine Plant, coupled with a Rankine cycle for additional power generation and/or desalination of sea water with a multistage flash evaporator. Three basic alternatives are studied: a) Brayton cycle with inter-cooling and without regeneration, coupled with a Rankine cycle for power generation and steam for evaporator. b) Same as a) but without inter-cooling and with regeneration. c) Brayton cycle with regeneration, without inter-cooling, coupled with a Rankine cycle for sea water evaporator steam generation. The behavior of the three alternatives is established with a parametric study for the most representative variables. Economy, safety and control aspects were considered for the three different conceptions. (Author) [pt

Catalytic isotope exchange reaction between deuterium gas and water pre-adsorbed on platinum/alumina

International Nuclear Information System (INIS)

Iida, Itsuo; Kato, Junko; Tamaru, Kenzi.

1976-01-01

The catalytic isotope exchange reaction between deuterium gas and the water pre-adsorbed on Pt/Al 2 O 3 was studied. At reaction temperatures above 273 K, the exchange rate was proportional to the deuterium pressure and independent of the amount of adsorbed water, which suggests that the rate determining step is the supply of deuterium from the gas phase. Its apparent activation energy was 38 kJ mol -1 . Below freezing point of water, the kinetic behaviour was different from that above freezing point. At higher deuterium pressures the rate dropped abruptly at 273 K. Below the temperature the apparent activation energy was 54 kJ mol -1 and the exchange rate depended not on the deuterium pressure but on the amount of the pre-adsorbed water. At lower pressures, however, the kinetic behaviour was the same as the above 273 K, till the rate of the supply of deuterium from the gas phase exceeded the supply of hydrogen from adsorbed water to platinum surface. These results suggest that below 273 K the supply of hydrogen is markedly retarded, the state of the adsorbed water differing from that above 273 K. It was also demonstrated that when the adsorbed water is in the state of capillary condensation, the exchange rate becomes very small. (auth.)

Gas, Oil, and Water Production from Jonah, Pinedale, Greater Wamsutter, and Stagecoach Draw Fields in the Greater Green River Basin, Wyoming

Science.gov (United States)

Nelson, Philip H.; Ewald, Shauna M.; Santus, Stephen L.; Trainor, Patrick K.

2010-01-01

Gas, oil, and water production data were compiled from selected wells in four gas fields in rocks of Late Cretaceous age in southwestern Wyoming. This study is one of a series of reports examining fluid production from tight-gas reservoirs, which are characterized by low permeability, low porosity, and the presence of clay minerals in pore space. Production from each well is represented by two samples spaced five years apart, the first sample typically taken two years after commencement of production. For each producing interval, summary diagrams of oil versus gas and water versus gas production show fluid production rates, the change in rates during five years, the water-gas and oil-gas ratios, and the fluid type. These diagrams permit well-to-well and field-to-field comparisons. Fields producing water at low rates (water dissolved in gas in the reservoir) can be distinguished from fields producing water at moderate or high rates, and the water-gas ratios are quantified. The ranges of first-sample gas rates in Pinedale field and Jonah field are quite similar, and the average gas production rate for the second sample, taken five years later, is about one-half that of the first sample for both fields. Water rates are generally substantially higher in Pinedale than in Jonah, and water-gas ratios in Pinedale are roughly a factor of ten greater in Pinedale than in Jonah. Gas and water production rates from each field are fairly well grouped, indicating that Pinedale and Jonah fields are fairly cohesive gas-water systems. Pinedale field appears to be remarkably uniform in its flow behavior with time. Jonah field, which is internally faulted, exhibits a small spread in first-sample production rates. In the Greater Wamsutter field, gas production from the upper part of the Almond Formation is greater than from the main part of the Almond. Some wells in the main and the combined (upper and main parts) Almond show increases in water production with time, whereas increases

Distinguishing the Source of Natural Gas Accumulations with a Combined Gas and Co-produced Formation Water Geochemical Approach: a Case Study from the Appalachian Basin

Science.gov (United States)

The purpose of this study is to discuss the use of gas and co-produced formation water geochemistry for identifying the source of natural gas and present gas geochemistry for the northern Appalachian Basin.

Determination of petroleum fractions as contaminants in the waters by gas chromatography

International Nuclear Information System (INIS)

Kubinec, R.; Mracnova, R.; Kuran, P.; Ostrovsky, I.; Sojak, L.

1995-01-01

The method of micro-extraction of petroleum fractions from water and analysis using gas chromatography was developed. This method can be used for the analysis of gaseous oil and mineral oil in the water wit the detection limit 12 ppb and 18 ppb, respectively

Halogenated methyl-phenyl ethers (anisoles) in the environment: determination of vapor pressures, aqueous solubilities, Henry's law constants, and gas/water- (Kgw), n-octanol/water- (Kow) and gas/n-octanol (Kgo) partition coefficients.

Science.gov (United States)

Pfeifer, O; Lohmann, U; Ballschmiter, K

2001-11-01

Halogenated methyl-phenyl ethers (methoxybenzenes, anisoles) are ubiquitous organics in the environment although they are not produced in industrial quantities. Modelling the fate of organic pollutants such as halogenated anisoles requires a knowledge of the fundamental physico-chemical properties of these compounds. The isomer-specific separation and detection of 60 of the 134 possible congeners allowing an environmental fingerprinting are reported in this study. The vapor pressure p0(L) of more than 60 and further physico-chemical properties of 26 available congeners are given. Vapor pressures p0(L), water solubilities S(L)W, and n-octanol/water partition coefficients Kow were determined by capillary HR-GC (High Resolution Gas Chromatography) on a non-polar phase and by RP-HPLC (Reversed Phase High Performance Liquid Chromatography) on a C18 phase with chlorobenzenes as reference standards. From these experimental data the Henry's law constants H, and the gas/water Kgw and gas/n-octanol Kgo partition coefficients were calculated. We found that vapor pressures, water solubilities, and n-octanol/water partition coefficients of the halogenated anisoles are close to those of the chlorobenzenes. A similar environmental fate of both groups can, therefore, be predicted.

The impact of water depth on safety and environmental performance in offshore oil and gas production

International Nuclear Information System (INIS)

Muehlenbachs, Lucija; Cohen, Mark A.; Gerarden, Todd

2013-01-01

This paper reports on an empirical analysis of company-reported incidents on oil and gas production platforms in the Gulf of Mexico between 1996 and 2010. During these years, there was a dramatic increase in the water depths at which offshore oil and gas is extracted. Controlling for platform characteristics such as age, quantity of oil and gas produced, and number of producing wells, we find that incidents (such as blowouts, injuries, and oil spills) are positively correlated with deeper water. Controlling for these and other characteristics, for an average platform, each 100 feet of added depth increases the probability of a company-reported incident by 8.5%. While further research into the causal connections between water depth and platform risks is warranted, this study highlights the potential value of increased monitoring of deeper water platforms. - Highlights: ► Analysis of performance indicators for oil production platforms in Gulf of Mexico. ► In recent years there have been dramatic increases in the water depths at which offshore oil and gas is extracted. ► Self-reported incidents (e.g. blowouts, injuries, spills) increase with water depth

Innovative in-line separators: removal of water or sand in oil/water and gas/liquid/solid pipelines

Energy Technology Data Exchange (ETDEWEB)

Jepson, Paul; Cheolho Kang; Gopal, Madan [CC Technologies, Dublin, OH (United States)

2003-07-01

In oil and gas production, multiphase mixtures are often separated before downstream processing. The separators are large, often 20 - 40 feet long and large diameter and use sophisticated internals. The costs are in the millions of dollars. Further, the sand and water in the flow can cause severe internal erosion and corrosion respectively before the flow reaches the separators. The CC Technologies/MIST In line Separation System is a cost-effective, efficient device for use in multiphase environments. The device is applicable for gas/solid, gas/liquid/solid and oil/water systems and offers exceptional separation between phases for a fraction of the cost of expensive gravity separators and hydro cyclones. The System contains no moving parts and is designed to be of the same diameter as the pipe, and experiences low shear forces. It can be fabricated with standard pipes. The efficiency of the separator has been determined in an industrial scale, pilot plant test facility at CC Technologies in 4-inch diameter pipes and has been found to be in excess of 98-99% for the removal of sand. Two phase oil/water separation effectiveness is in excess of 90% in 1-stage and 95% in 2 - stage. (author)

Chemical evolution of formation waters in the Palm Valley gas field, Northern Territory

International Nuclear Information System (INIS)

Andrew, A.S.; Giblin, A.M.

2000-01-01

The chemical composition and evolution of formation waters associated with gas production in the Palm Valley field, Northern Territory, has important implications for reservoir management, saline water disposal, and gas reserve calculations. Historically, the occurrence of saline formation water in gas fields has been the subject of considerable debate. A better understanding of the origin, chemical evolution and movement of the formation water at Palm Valley has important implications for future reservoir management, disposal of highly saline water and accurate gas reserves estimation. Major and trace element abundance data suggest that a significant component of the highly saline water from Palm Valley has characteristics that may have been derived from a modified evaporated seawater source such as an evaporite horizon. The most dilute waters probably represent condensate and the variation in the chemistry of the intermediate waters suggests they were derived from a mixture of the condensate with the highly saline brine. The chemical and isotopic results raise several interrelated questions; the ultimate source of the high salinity and the distribution of apparently mixed compositions. In this context several key observation are highlighted. Strontium concentrations are extremely high in the brines; although broadly similar in their chemistry, the saline fluids are neither homogeneous nor well mixed; the 87 Sr/ 86 Sr ratios in the brines are higher than the signatures preserved in the evaporitic Bitter Springs Formation, and all other conceivably marine-related evaporites (Strauss, 1993); the 87 Sr/ 86 Sr ratios in the brines are lower than those measured from groundmass carbonates in the host rocks, and that the 87 Sr/ 86 Sr ratios of the brines are similar, but still somewhat higher than those measured in vein carbonates from the reservoir. It is concluded that the high salinity brine entered the reservoir during the Devonian uplift and was subsequently

Rate of Isotope Exchange Reaction Between Tritiated Water in a Gas Phase and Water on the Surface of Piping Materials

International Nuclear Information System (INIS)

Nakashio, Nobuyuki; Yamaguchi, Junya; Kobayashi, Ryusuke; Nishikawa, Masabumi

2001-01-01

The system effect of tritium arises from the interaction of tritium in the gas phase with water on the surface of piping materials. It has been reported that the system effect can be quantified by applying the serial reactor model to the piping system and that adsorption and isotope exchange reactions play the main roles in the trapping of tritium. The isotope exchange reaction that occurs when the chemical form of tritium in the gas phase is in the molecular form, i.e., HT or T 2 , has been named isotope exchange reaction 1, and that which occurs when tritium in the gas phase is in water form, i.e., HTO or T 2 O, has been named isotope exchange reaction 2.The rate of isotope exchange reaction 2 is experimentally quantified, and the rate is observed to be about one-third of the rate of adsorption. The trapping and release behavior of tritium from the piping surface due to isotope exchange reaction 2 is also discussed. It is certified that swamping of water vapor to process gas is effective to release tritium from the surface contaminated with tritium

PdZnAl Catalysts for the Reactions of Water-Gas-Shift, Methanol Steam Reforming, and Reverse-Water-Gas-Shift

Energy Technology Data Exchange (ETDEWEB)

Dagle, Robert A.; Platon, Alexandru; Datye, Abhaya K.; Vohs, John M.; Wang, Yong; Palo, Daniel R.

2008-03-07

Pd/ZnO/Al2O3 catalysts were studied for water-gas-shift (WGS), methanol steam reforming, and reverse-water-gas-shift (RWGS) reactions. WGS activity was found to be dependent on the Pd:Zn ratio with a maximum activity obtained at approximately 0.50, which was comparable to that of a commercial Pt-based catalyst. The catalyst stability was demonstrated for 100 hours time-on-stream at a temperature of 3600C without evidence of metal sintering. WGS reaction rates were approximately 1st order with respect to CO concentration, and kinetic parameters were determined to be Ea = 58.3 kJ mol-1 and k0 = 6.1x107 min-1. During methanol steam reforming, the CO selectivities were observed to be lower than the calculated equilibrium values over a range of temperatures and steam/carbon ratios studied while the reaction rate constants were approximately of the same magnitude for both WGS and methanol steam reforming. These results indicate that although Pd/ZnO/Al2O3 are active WGS catalysts, WGS is not involved in methanol steam reforming. RWGS rate constants are on the order of about 20 times lower than that of methanol steam reforming, suggesting that RWGS reaction could be one of the sources for small amount of CO formation in methanol steam reforming.

Differences in gas exchange contribute to habitat differentiation in Iberian columbines from contrasting light and water environments.

Science.gov (United States)

Jaime, R; Serichol, C; Alcántara, J M; Rey, P J

2014-03-01

During photosynthesis, respiration and transpiration, gas exchange occurs via the stomata and so plants face a trade-off between maximising photosynthesis while minimising transpiration (expressed as water use efficiency, WUE). The ability to cope with this trade-off and regulate photosynthetic rate and stomatal conductance may be related to niche differentiation between closely related species. The present study explored this as a possible mechanism for habitat differentiation in Iberian columbines. The roles of irradiance and water stress were assessed to determine niche differentiation among Iberian columbines via distinct gas exchange processes. Photosynthesis-irradiance curves (P-I curves) were obtained for four taxa, and common garden experiments were conducted to examine plant responses to water and irradiance stress, by measuring instantaneous gas exchange and plant performance. Gas exchange was also measured in ten individuals using two to four field populations per taxon. The taxa had different P-I curves and gas exchange in the field. At the species level, water stress and irradiance explained habitat differentiation. Within each species, a combination of irradiance and water stress explained the between-subspecies habitat differentiation. Despite differences in stomatal conductance and CO2 assimilation, taxa did not have different WUE under field conditions, which suggests that the environment equally modifies photosynthesis and transpiration. The P-I curves, gas exchange in the field and plant responses to experimental water and irradiance stresses support the hypothesis that habitat differentiation is associated with differences among taxa in tolerance to abiotic stress mediated by distinct gas exchange responses. © 2013 German Botanical Society and The Royal Botanical Society of the Netherlands.

The solvent absorption-extractive distillation (SAED) process for ethanol recovery from gas/vapor streams

Energy Technology Data Exchange (ETDEWEB)

Dale, M.C.

1993-12-31

A low energy system for ethanol recovery and dehydration has been developed. This system utilizes a solvent for (1) absorption of ethanol vapors, and then the same solvent for (2) extractive distillation. The ideal solvent for this process would have a high affinity for ethanol, and no affinity for water. Heavy alcohols such as dodecanol, and tridecanol, some phosphorals, and some fatty acids have been determined to meet the desired specifications. These solvents have the effect of making water more volatile than ethanol. Thus, a water stream is taken off initially in the dehydration column, and a near anhydrous ethanol stream is recovered from the ethanol/solvent stripper column. Thus the solvent serves dual uses (1) absorption media, and (2) dehydration media. The SAED process as conceptualized would use a solvent similar to solvents used for direct extractive separation of ethanol from aqueous ethanol solutions.

Diurnal Variation in Gas Exchange: The Balance between Carbon Fixation and Water Loss.

Science.gov (United States)

Matthews, Jack S A; Vialet-Chabrand, Silvere R M; Lawson, Tracy

2017-06-01

Stomatal control of transpiration is critical for maintaining important processes, such as plant water status, leaf temperature, as well as permitting sufficient CO 2 diffusion into the leaf to maintain photosynthetic rates ( A ). Stomatal conductance often closely correlates with A and is thought to control the balance between water loss and carbon gain. It has been suggested that a mesophyll-driven signal coordinates A and stomatal conductance responses to maintain this relationship; however, the signal has yet to be fully elucidated. Despite this correlation under stable environmental conditions, the responses of both parameters vary spatially and temporally and are dependent on species, environment, and plant water status. Most current models neglect these aspects of gas exchange, although it is clear that they play a vital role in the balance of carbon fixation and water loss. Future efforts should consider the dynamic nature of whole-plant gas exchange and how it represents much more than the sum of its individual leaf-level components, and they should take into consideration the long-term effect on gas exchange over time. © 2017 American Society of Plant Biologists. All Rights Reserved.

Gas exchange and hydraulics in seedlings of Hevea brasiliensis during water stress and recovery.

Science.gov (United States)

Chen, Jun-Wen; Zhang, Qiang; Li, Xiao-Shuang; Cao, Kun-Fang

2010-07-01

The response of plants to drought has received significant attention, but far less attention has been given to the dynamic response of plants during recovery from drought. Photosynthetic performance and hydraulic capacity were monitored in seedlings of Hevea brasiliensis under water stress and during recovery following rewatering. Leaf water relation, gas exchange rate and hydraulic conductivity decreased gradually after water stress fell below a threshold, whereas instantaneous water use efficiency and osmolytes increased significantly. After 5 days of rewatering, leaf water relation, maximum stomatal conductance (g(s-max)) and plant hydraulic conductivity had recovered to the control levels except for sapwood area-specific hydraulic conductivity, photosynthetic assimilation rate and osmolytes. During the phase of water stress, stomata were almost completely closed before water transport efficiency decreased substantially, and moreover, the leaf hydraulic pathway was more vulnerable to water stress-induced embolism than the stem hydraulic pathway. Meanwhile, g(s-max) was linearly correlated with hydraulic capacity when water stress exceeded a threshold. In addition, a positive relationship was shown to occur between the recovery of g(s-max) and of hydraulic capacity during the phase of rewatering. Our results suggest (i) that stomatal closure effectively reduces the risk of xylem dysfunction in water-stressed plants at the cost of gas exchange, (ii) that the leaf functions as a safety valve to protect the hydraulic pathway from water stress-induced dysfunction to a larger extent than does the stem and (iii) that the full drought recovery of gas exchange is restricted by not only hydraulic factors but also non-hydraulic factors.

Economics of residential gas furnaces and water heaters in United States new construction market

Energy Technology Data Exchange (ETDEWEB)

Lekov, Alex B.; Franco, Victor H.; Wong-Parodi, Gabrielle; McMahon, James E.; Chan, Peter

2009-05-06

New single-family home construction represents a significant and important market for the introduction of energy-efficient gas-fired space heating and water-heating equipment. In the new construction market, the choice of furnace and water-heater type is primarily driven by first cost considerations and the availability of power vent and condensing water heaters. Few analysis have been performed to assess the economic impacts of the different combinations of space and water-heating equipment. Thus, equipment is often installed without taking into consideration the potential economic and energy savings of installing space and water-heating equipment combinations. In this study, we use a life-cycle cost analysis that accounts for uncertainty and variability of the analysis inputs to assess the economic benefits of gas furnace and water-heater design combinations. This study accounts not only for the equipment cost but also for the cost of installing, maintaining, repairing, and operating the equipment over its lifetime. Overall, this study, which is focused on US single-family new construction households that install gas furnaces and storage water heaters, finds that installing a condensing or power-vent water heater together with condensing furnace is the most cost-effective option for the majority of these houses. Furthermore, the findings suggest that the new construction residential market could be a target market for the large-scale introduction of a combination of condensing or power-vent water heaters with condensing furnaces.

The feasibility of desorption on Zeolite-water pair using dry gas

Science.gov (United States)

Oktariani, E.; Nakashima, K.; Noda, A.; Xue, B.; Tahara, K.; Nakaso, K.; Fukai, J.

2018-04-01

The increase in temperature, reduction in partial pressure, reduction in concentration, purging with an inert fluid, and displacement with a more strongly adsorbing species are the basic things that occur in the practical method of desorption. In this study, dry gas at constant temperature and pressure was employed as the aid to reduce the partial pressure in the water desorption on the zeolite 13X. The objective of this study is to confirm the feasibility of desorption using dry gas experimentally and numerically. The implication of heat and mass transfers were numerically investigated to find the most influential. The results of numerical simulation agree with the experimental ones for the distribution of local temperature and average water adsorbed in the packed bed.

Influence of current velocity and wind speed on air-water gas exchange in a mangrove estuary

Science.gov (United States)

Ho, David T.; Coffineau, Nathalie; Hickman, Benjamin; Chow, Nicholas; Koffman, Tobias; Schlosser, Peter

2016-04-01

Knowledge of air-water gas transfer velocities and water residence times is necessary to study the fate of mangrove derived carbon exported into surrounding estuaries and ultimately to determine carbon balances in mangrove ecosystems. For the first time, the 3He/SF6 dual tracer technique, which has been proven to be a powerful tool to determine gas transfer velocities in the ocean, is applied to Shark River, an estuary situated in the largest contiguous mangrove forest in North America. The mean gas transfer velocity was 3.3 ± 0.2 cm h-1 during the experiment, with a water residence time of 16.5 ± 2.0 days. We propose a gas exchange parameterization that takes into account the major sources of turbulence in the estuary (i.e., bottom generated shear and wind stress).

Process for hydrogen isotope exchange and concentration between liquid water and hydrogen gas and catalyst assembly therefor

International Nuclear Information System (INIS)

Stevens, W.H.

1975-01-01

A bithermal, catalytic, hydrogen isotope exchange process between liquid water and hydrogen gas to effect concentration of the deuterium isotope of hydrogen is described. Liquid water and hydrogen gas are contacted with one another and with at least one catalytically active metal selected from Group VIII of the Periodic Table; the catalyst body has a water repellent, gas and water vapor permeable, organic polymer or resin coating, preferably a fluorinated olefin polymer or silicone resin coating, so that the isotope exchange takes place by two simultaneously occurring, and closely coupled in space, steps and concentration is effected by operating two interconnected sections containing catalyst at different temperatures. (U.S.)

Peach Water Relations, Gas Exchange, Growth and Shoot Mortality under Water Deficit in Semi-Arid Weather Conditions

OpenAIRE

Rahmati, Mitra; Davarynejad, Gholam Hossein; G?nard, Michel; Bannayan, Mohammad; Azizi, Majid; Vercambre, Gilles

2015-01-01

In this study the sensitivity of peach tree (Prunus persica L.) to three water stress levels from mid-pit hardening until harvest was assessed. Seasonal patterns of shoot and fruit growth, gas exchange (leaf photosynthesis, stomatal conductance and transpiration) as well as carbon (C) storage/mobilization were evaluated in relation to plant water status. A simple C balance model was also developed to investigate sink-source relationship in relation to plant water status at the tree level. The...

Water relations and gas exchange in poplar and willow under water stress and elevated atmospheric CO2.

Science.gov (United States)

Johnson, Jon D; Tognetti, Roberto; Paris, Piero

2002-05-01

Predictions of shifts in rainfall patterns as atmospheric [CO2] increases could impact the growth of fast growing trees such as Populus spp. and Salix spp. and the interaction between elevated CO2 and water stress in these species is unknown. The objectives of this study were to characterize the responses to elevated CO2 and water stress in these two species, and to determine if elevated CO2 mitigated drought stress effects. Gas exchange, water potential components, whole plant transpiration and growth response to soil drying and recovery were assessed in hybrid poplar (clone 53-246) and willow (Salix sagitta) rooted cuttings growing in either ambient (350 &mgr;mol mol-1) or elevated (700 &mgr;mol mol-1) atmospheric CO2 concentration ([CO2]). Predawn water potential decreased with increasing water stress while midday water potentials remained unchanged (isohydric response). Turgor potentials at both predawn and midday increased in elevated [CO2], indicative of osmotic adjustment. Gas exchange was reduced by water stress while elevated [CO2] increased photosynthetic rates, reduced leaf conductance and nearly doubled instantaneous transpiration efficiency in both species. Dark respiration decreased in elevated [CO2] and water stress reduced Rd in the trees growing in ambient [CO2]. Willow had 56% lower whole plant hydraulic conductivity than poplar, and showed a 14% increase in elevated [CO2] while poplar was unresponsive. The physiological responses exhibited by poplar and willow to elevated [CO2] and water stress, singly, suggest that these species respond like other tree species. The interaction of [CO2] and water stress suggests that elevated [CO2] did mitigate the effects of water stress in willow, but not in poplar.

Aqueous turbulence structure immediately adjacent to the air - water interface and interfacial gas exchange

Science.gov (United States)

Wang, Binbin

Air-sea interaction and the interfacial exchange of gas across the air-water interface are of great importance in coupled atmospheric-oceanic environmental systems. Aqueous turbulence structure immediately adjacent to the air-water interface is the combined result of wind, surface waves, currents and other environmental forces and plays a key role in energy budgets, gas fluxes and hence the global climate system. However, the quantification of turbulence structure sufficiently close to the air-water interface is extremely difficult. The physical relationship between interfacial gas exchange and near surface turbulence remains insufficiently investigated. This dissertation aims to measure turbulence in situ in a complex environmental forcing system on Lake Michigan and to reveal the relationship between turbulent statistics and the CO2 flux across the air-water interface. The major objective of this dissertation is to investigate the physical control of the interfacial gas exchange and to provide a universal parameterization of gas transfer velocity from environmental factors, as well as to propose a mechanistic model for the global CO2 flux that can be applied in three dimensional climate-ocean models. Firstly, this dissertation presents an advanced measurement instrument, an in situ free floating Particle Image Velocimetry (FPIV) system, designed and developed to investigate the small scale turbulence structure immediately below the air-water interface. Description of hardware components, design of the system, measurement theory, data analysis procedure and estimation of measurement error were provided. Secondly, with the FPIV system, statistics of small scale turbulence immediately below the air-water interface were investigated under a variety of environmental conditions. One dimensional wave-number spectrum and structure function sufficiently close to the water surface were examined. The vertical profiles of turbulent dissipation rate were intensively studied

Heat suppression of the fiber coating on a cladding light stripper in high-power fiber laser.

Science.gov (United States)

Yan, Ming-Jian; Wang, Zheng; Meng, Ling-Qiang; Yin, Lu; Han, Zhi-Gang; Shen, Hua; Wang, Hai-Lin; Zhu, Ri-Hong

2018-01-20

We present a theoretical model for the thermal effect of the fiber coating on a high-power cladding light stripper, which is fabricated by chemical etching. For the input and output of the fiber coating, a novel segmented corrosion method and increasing attenuation method are proposed for heat suppression, respectively. The relationship between the attenuation and temperature rise of the fiber coating at the output is experimentally demonstrated. The temperature distribution of the fiber coating at the input as well as the return light power caused by scattering are measured for the etched fiber with different surface roughness values. The results suggest that the rise in temperature is primarily caused by the scattering light propagating into the coating. Finally, an attenuation of 27 dB is achieved. At a room temperature of 23°C and input pump power of 438 W, the highest temperature of the input fiber coating decreases from 39.5°C to 27.9°C by segmented corrosion, and the temperature rise of the output fiber coating is close to 0.

Desalination of Produced Water via Gas Hydrate Formation and Post Treatment

OpenAIRE

Niu, Jing

2012-01-01

This study presents a two-step desalination process, in which produced water is cleaned by forming gas hydrate in it and subsequently dewatering the hydrate to remove the residual produced water trapped in between the hydrate crystals. All experiments were performed with pressure in the range of 450 to 800psi and temperature in the range of -1 to 1°C using CO? as guest molecule for the hydrate crystals. The experiments were conducted using artificial produced waters containing different amoun...

Radionuclides in produced water from Norwegian oil and gas installations - concentrations and bioavailability

International Nuclear Information System (INIS)

Eriksen, D.Oe.; Sidhu, R.; Stralberg, E.; Iden, K.I.; Hylland, K.; Ruus, A.; Roeyset, O.; Berntssen, M.H.G.; Rye, H.

2006-01-01

Substantial amounts of produced water, containing elevated levels of radionuclides (mainly 226 Ra and 228 Ra) are discharged to the sea as a result of oil and gas production on the Norwegian Continental Shelf. So far no study has assessed the potential radiological effects on marine biota in connection with radionuclide discharges to the North Sea. The main objective of the project is to establish radiological safe discharge limits for radium, lead and polonium associated with other components in produced water from oil and gas installations on the Norwegian continental shelf. This study reports results indicating that the presence of added chemicals such as scale inhibitors in produced water has a marked influence on the formation of radium and barium sulphates when produced water is mixed with sea water. Thus, the mobility and bioavailability of radium (and barium) will be larger than anticipated. Also, the bioavailability of food-borne radium is shown to increase due to presence of such chemicals. (author)

Experimental study of gas engine driven air to water heat pump in cooling mode

International Nuclear Information System (INIS)

Elgendy, E.; Schmidt, J.

2010-01-01

Nowadays a sustainable development for more efficient use of energy and protection of the environment is of increasing importance. Gas engine heat pumps represent one of the most practicable solutions which offer high energy efficiency and environmentally friendly for heating and cooling applications. In this paper, the performance characteristics of gas engine driven heat pump used in water cooling were investigated experimentally without engine heat recovery. The effects of several important factors (evaporator water inlet temperature, evaporator water volume flow rate, ambient air temperature, and engine speed) on the performance of gas engine driven heat pump were studied in a wide range of operating conditions. The results showed that primary energy ratio of the system increased by 22.5% as evaporator water inlet temperature increased from 13 o C to 24 o C. On the other hand, varying of engine speed from 1300 rpm to 1750 rpm led to decrease in system primary energy ratio by 13%. Maximum primary energy ratio has been estimated with a value of two over a wide range of operating conditions.

Greenhouse gas and energy co-benefits of water conservation[Water Sustainability Project

Energy Technology Data Exchange (ETDEWEB)

Maas, C.

2009-03-15

Energy is needed to deliver water to, within and from communities to remove contaminants from water and wastewater, and to heat water in homes. The interconnections between water and energy are referred to as the water-energy nexus. Large volumes of water are needed to generate energy, notably to power turbines, to cool thermal or nuclear energy plants, and to extract oil from tar sands. At the same time, large amounts of energy are needed to pump, treat, heat and distribute water for urban, industrial and agricultural use and to collect and treat the resulting wastewater. The two sides of the water-energy nexus are generating new research and policy proposals to address the challenges of climate change, energy security and increasing water scarcity. This report demonstrated that a large untapped opportunity exists for water conservation to reduce energy, municipal costs and greenhouse gas (GHG) emissions. The water-energy research in this study was based on a Soft Path for Water approach that incorporated facets of water demand management while moving beyond a short-term focus on cost-benefit criteria to examine how the services currently provided by water can be delivered to meet the need for economic, social and ecological sustainability. Although the research was conducted using data for municipalities in Ontario, the report is relevant to the rest of Canada and much of North America. Water conservation strategies included water efficiency measures such as high efficiency toilets and washing machines, as well as water saving measures such as xeriscaping and rainwater harvesting. The objectives of the study were to quantify the energy use associated with each component of the urban water use cycle and to determine the potential for energy and GHG emissions reductions associated with water conservation strategies. This report provided an overview of energy inputs needed for water provision. It outlined the methodology used to achieve the project objectives and

Can switching fuels save water? A life cycle quantification of freshwater consumption for Texas coal- and natural gas-fired electricity

International Nuclear Information System (INIS)

Grubert, Emily A; Beach, Fred C; Webber, Michael E

2012-01-01

Thermal electricity generation is a major consumer of freshwater for cooling, fuel extraction and air emissions controls, but the life cycle water impacts of different fossil fuel cycles are not well understood. Much of the existing literature relies on decades-old estimates for water intensity, particularly regarding water consumed for fuel extraction. This work uses contemporary data from specific resource basins and power plants in Texas to evaluate water intensity at three major stages of coal and natural gas fuel cycles: fuel extraction, power plant cooling and power plant emissions controls. In particular, the water intensity of fuel extraction is quantified for Texas lignite, conventional natural gas and 11 unconventional natural gas basins in Texas, including major second-order impacts associated with multi-stage hydraulic fracturing. Despite the rise of this water-intensive natural gas extraction method, natural gas extraction appears to consume less freshwater than coal per unit of energy extracted in Texas because of the high water intensity of Texas lignite extraction. This work uses new resource basin and power plant level water intensity data to estimate the potential effects of coal to natural gas fuel switching in Texas’ power sector, a shift under consideration due to potential environmental benefits and very low natural gas prices. Replacing Texas’ coal-fired power plants with natural gas combined cycle plants (NGCCs) would reduce annual freshwater consumption in the state by an estimated 53 billion gallons per year, or 60% of Texas coal power’s water footprint, largely due to the higher efficiency of NGCCs. (letter)

Solar heating, cooling and domestic hot water system installed at Columbia Gas System Service Corporation, Columbus, Ohio

Science.gov (United States)

1980-01-01

The solar energy system installed in the building has 2,978 sq ft of single axis tracking, concentrating collectors and provides solar energy for space heating, space cooling and domestic hot water. A 1,200,000 Btu/hour water tube gas boiler provides hot water for space heating. Space cooling is provided by a 100 ton hot water fired absorption chiller. Domestic hot water heating is provided by a 50 gallon natural gas domestic storage water heater. Extracts from the site files, specification references, drawings, installation, operation and maintenance instructions are included.

Gas exchange under water. Acclimation of terrestrial plants to submergence

NARCIS (Netherlands)

Mommer, L.

2005-01-01

Gas exchange between the plant and the environment is severely hampered when plants are submerged, leading to oxygen and energy deficits. A straightforward way to reduce these shortages of oxygen and carbohydrates would be prolonged photosynthesis under water, but this has received only little

Simulation of Water Gas Shift Zeolite Membrane Reactor

Science.gov (United States)

Makertiharta, I. G. B. N.; Rizki, Z.; Zunita, Megawati; Dharmawijaya, P. T.

2017-07-01

The search of alternative energy sources keeps growing from time to time. Various alternatives have been introduced to reduce the use of fossil fuel, including hydrogen. Many pathways can be used to produce hydrogen. Among all of those, the Water Gas Shift (WGS) reaction is the most common pathway to produce high purity hydrogen. The WGS technique faces a downstream processing challenge due to the removal hydrogen from the product stream itself since it contains a mixture of hydrogen, carbon dioxide and also the excess reactants. An integrated process using zeolite membrane reactor has been introduced to improve the performance of the process by selectively separate the hydrogen whilst boosting the conversion. Furthermore, the zeolite membrane reactor can be further improved via optimizing the process condition. This paper discusses the simulation of Zeolite Membrane Water Gas Shift Reactor (ZMWGSR) with variation of process condition to achieve an optimum performance. The simulation can be simulated into two consecutive mechanisms, the reaction prior to the permeation of gases through the zeolite membrane. This paper is focused on the optimization of the process parameters (e.g. temperature, initial concentration) and also membrane properties (e.g. pore size) to achieve an optimum product specification (concentration, purity).

Recent Advances in Water Analysis with Gas Chromatograph Mass Spectrometers

Science.gov (United States)

MacAskill, John A.; Tsikata, Edem

2014-01-01

We report on progress made in developing a water sampling system for detection and analysis of volatile organic compounds in water with a gas chromatograph mass spectrometer (GCMS). Two approaches are described herein. The first approach uses a custom water pre-concentrator for performing trap and purge of VOCs from water. The second approach uses a custom micro-volume, split-splitless injector that is compatible with air and water. These water sampling systems will enable a single GC-based instrument to analyze air and water samples for VOC content. As reduced mass, volume, and power is crucial for long-duration, manned space-exploration, these water sampling systems will demonstrate the ability of a GCMS to monitor both air and water quality of the astronaut environment, thereby reducing the amount of required instrumentation for long duration habitation. Laboratory prototypes of these water sampling systems have been constructed and tested with a quadrupole ion trap mass spectrometer as well as a thermal conductivity detector. Presented herein are details of these water sampling system with preliminary test results.

Variations of free gas content in water during pressure fluctuations

International Nuclear Information System (INIS)

Keller, A.; Zielke, W.

1977-01-01

In this paper an experimental programme is described in order to determine the influence of the cavitation nuclei distribution on cavitation inception. This programme has been used to measure air bubbles dimensions and number and particularly to determine the influence of quick pressure variations on the size on the number of bubbles in a pipe. An optical device counting scattered light is used as a measuring technique. Gas bubbles go through an optical control volume where they receive a high intensity light beam and scatter the light, then led to a photomultiplier; the signals are sorted and counted according to their size. If the number of nuclei, the dimensions of the control volume and the velocity of the water are known, it is possible to determine bubbles concentrations and the bulk modulus of the water. This measuring technique has been applied to a flow in a 140 mm diameter pipe with quick pressure variations from 2 bar to 0-10 bar. During the variations, the void fraction depends on the Reynolds number of the flow and on the gas content of the water. The bulk modulus has been computed with different conditions. Most results concern pressures slightly over the vapor pressure. Air content has a strong influence on cavitation and on water compressibility after a vapor cavity collapse

Energy consumption in desalinating produced water from shale oil and gas extraction

OpenAIRE

Tow, Emily W.; Chung, Hyung Won; Lienhard, John H.; Thiel, Gregory Parker; Banchik, Leonardo David

2014-01-01

On-site treatment and reuse is an increasingly preferred option for produced water management in unconventional oil and gas extraction. This paper analyzes and compares the energetics of several desalination technologies at the high salinities and diverse compositions commonly encountered in produced water from shale formations to guide technology selection and to inform further system development. Produced water properties are modeled using Pitzer's equations, and emphasis is placed on how t...

WAG (water-alternating-gas) as a method for petroleum advanced recovering

International Nuclear Information System (INIS)

Campozana, Fernando P.; Mato, Luiz F.

2000-01-01

Water-Alternating-Gas (WAG) injection is an oil recovery method that has been more and more applied worldwide. Oil recovery has been increased up to 20 % (over conventional waterflooding) in field-scale WAG projects. This additional recovery has been attributed to improved sweep and areal efficiency as well as microscopic displacement efficiency. Field results have shown that not only WAG method combines the advantages of gas and water injection but also leads to more stable fronts and better mobility control. Moreover, three-phase flow usually leads to a lower residual oil saturation when compared to that of two-phase flow. In this study, we show some theoretical aspects of WAG as well as some results obtained from numerical simulation of a pilot project to be implemented in Aracas field, Bahia, Brazil. (author)

Optimized CO2-flue gas separation model for a coal fired power plant

Energy Technology Data Exchange (ETDEWEB)

Arachchige, Udara S.P.R. [Telemark University College, Porsgrunn (Norway); Mohsin, Muhammad [Telemark University College, Porsgrunn (Norway); Melaaen, Morten C. [Telemark University College, Porsgrunn (Norway); Tel-Tek, Porsgrunn (Norway)

2013-07-01

The detailed description of the CO2 removal process using mono-ethylamine (MEA) as a solvent for coal-fired power plant is present in this paper. The rate based Electrolyte NRTL activity coefficient model was used in the Aspen Plus. The complete removal process with re-circulating solvent back to the absorber was implemented with the sequential modular method in Aspen Plus. The most significant cost related to CO2 capture is the energy requirement for re-generating solvent, i.e. re-boiler duty. Parameters’ effects on re-boiler duty were studied, resulting decreased re-boiler duty with the packing height and absorber packing diameter, absorber pressure, solvent temperature, stripper packing height and diameter. On the other hand, with the flue gas temperature, re-boiler duty is increased. The temperature profiles and CO2 loading profiles were used to check the model behavior.

Plasma Spraying of Copper by Hybrid Water-Gas DC Arc Plasma Torch

Czech Academy of Sciences Publication Activity Database

Kavka, Tetyana; Matějíček, Jiří; Ctibor, Pavel; Mašláni, Alan; Hrabovský, Milan

2011-01-01

Roč. 20, č. 4 (2011), s. 760-774 ISSN 1059-9630 R&D Projects: GA ČR GAP205/11/2070 Institutional research plan: CEZ:AV0Z20430508 Keywords : copper coatings * hybrid water-gas torch * metallic particle oxidation Subject RIV: BL - Plasma and Gas Discharge Physics Impact factor: 1.812, year: 2011 http://www.springerlink.com/content/78n3736855261197/fulltext.pdf

Quantitative variation in water-use efficiency across water regimes and its relationship with circadian, vegetative, reproductive, and leaf gas-exchange traits.

Science.gov (United States)

Edwards, Christine E; Ewers, Brent E; McClung, C Robertson; Lou, Ping; Weinig, Cynthia

2012-05-01

Drought limits light harvesting, resulting in lower plant growth and reproduction. One trait important for plant drought response is water-use efficiency (WUE). We investigated (1) how the joint genetic architecture of WUE, reproductive characters, and vegetative traits changed across drought and well-watered conditions, (2) whether traits with distinct developmental bases (e.g. leaf gas exchange versus reproduction) differed in the environmental sensitivity of their genetic architecture, and (3) whether quantitative variation in circadian period was related to drought response in Brassica rapa. Overall, WUE increased in drought, primarily because stomatal conductance, and thus water loss, declined more than carbon fixation. Genotypes with the highest WUE in drought expressed the lowest WUE in well-watered conditions, and had the largest vegetative and floral organs in both treatments. Thus, large changes in WUE enabled some genotypes to approach vegetative and reproductive trait optima across environments. The genetic architecture differed for gas-exchange and vegetative traits across drought and well-watered conditions, but not for floral traits. Correlations between circadian and leaf gas-exchange traits were significant but did not vary across treatments, indicating that circadian period affects physiological function regardless of water availability. These results suggest that WUE is important for drought tolerance in Brassica rapa and that artificial selection for increased WUE in drought will not result in maladaptive expression of other traits that are correlated with WUE.

Organic substances in produced and formation water from unconventional natural gas extraction in coal and shale

Science.gov (United States)

Orem, William H.; Tatu, Calin A.; Varonka, Matthew S.; Lerch, Harry E.; Bates, Anne L.; Engle, Mark A.; Crosby, Lynn M.; McIntosh, Jennifer

2014-01-01

Organic substances in produced and formation water from coalbed methane (CBM) and gas shale plays from across the USA were examined in this study. Disposal of produced waters from gas extraction in coal and shale is an important environmental issue because of the large volumes of water involved and the variable quality of this water. Organic substances in produced water may be environmentally relevant as pollutants, but have been little studied. Results from five CBM plays and two gas shale plays (including the Marcellus Shale) show a myriad of organic chemicals present in the produced and formation water. Organic compound classes present in produced and formation water in CBM plays include: polycyclic aromatic hydrocarbons (PAHs), heterocyclic compounds, alkyl phenols, aromatic amines, alkyl aromatics (alkyl benzenes, alkyl biphenyls), long-chain fatty acids, and aliphatic hydrocarbons. Concentrations of individual compounds range from gas shale unimpacted by production chemicals have a similar range of compound classes as CBM produced water, and TOC levels of about 8 mg/L. However, produced water from the Marcellus Shale using hydraulic fracturing has TOC levels as high as 5500 mg/L and a range of added organic chemicals including, solvents, biocides, scale inhibitors, and other organic chemicals at levels of 1000 s of μg/L for individual compounds. Levels of these hydraulic fracturing chemicals and TOC decrease rapidly over the first 20 days of water recovery and some level of residual organic contaminants remain up to 250 days after hydraulic fracturing. Although the environmental impacts of the organics in produced water are not well defined, results suggest that care should be exercised in the disposal and release of produced waters containing these organic substances into the environment because of the potential toxicity of many of these substances.

Heavy water moderated gas-cooled reactors

International Nuclear Information System (INIS)

Bailly du Bois, B.; Bernard, J.L.; Naudet, R.; Roche, R.

1964-01-01

France has based its main effort for the production of nuclear energy on natural Uranium Graphite-moderated gas-cooled reactors, and has a long term programme for fast reactors, but this country is also engaged in the development of heavy water moderated gas-cooled reactors which appear to present the best middle term prospects. The economy of these reactors, as in the case of Graphite, arises from the use of natural or very slightly enriched Uranium; heavy water can take the best advantages of this fuel cycle and moreover offers considerable development potential because of better reactor performances. A prototype plant EL 4 (70 MW) is under construction and is described in detail in another paper. The present one deals with the programme devoted to the development of this reactor type in France. Reasons for selecting this reactor type are given in the first part: advantages and difficulties are underlined. After reviewing the main technological problems and the Research and Development carried out, results already obtained and points still to be confirmed are reported. The construction of EL 4 is an important step of this programme: it will be a significant demonstration of reactor performances and will afford many experimentation opportunities. Now the design of large power reactors is to be considered. Extension and improvements of the mechanical structures used for EL 4 are under study, as well as alternative concepts. The paper gives some data for a large reactor in the present state of technology, as a result from optimization studies. Technical improvements, especially in the field of materials could lead to even more interesting performances. Some prospects are mentioned for the long run. Investment costs and fuel cycles are discussed in the last part. (authors) [fr

Geochemical and strontium isotope characterization of produced waters from Marcellus Shale natural gas extraction.

Science.gov (United States)

Chapman, Elizabeth C; Capo, Rosemary C; Stewart, Brian W; Kirby, Carl S; Hammack, Richard W; Schroeder, Karl T; Edenborn, Harry M

2012-03-20

Extraction of natural gas by hydraulic fracturing of the Middle Devonian Marcellus Shale, a major gas-bearing unit in the Appalachian Basin, results in significant quantities of produced water containing high total dissolved solids (TDS). We carried out a strontium (Sr) isotope investigation to determine the utility of Sr isotopes in identifying and quantifying the interaction of Marcellus Formation produced waters with other waters in the Appalachian Basin in the event of an accidental release, and to provide information about the source of the dissolved solids. Strontium isotopic ratios of Marcellus produced waters collected over a geographic range of ~375 km from southwestern to northeastern Pennsylvania define a relatively narrow set of values (ε(Sr)(SW) = +13.8 to +41.6, where ε(Sr) (SW) is the deviation of the (87)Sr/(86)Sr ratio from that of seawater in parts per 10(4)); this isotopic range falls above that of Middle Devonian seawater, and is distinct from most western Pennsylvania acid mine drainage and Upper Devonian Venango Group oil and gas brines. The uniformity of the isotope ratios suggests a basin-wide source of dissolved solids with a component that is more radiogenic than seawater. Mixing models indicate that Sr isotope ratios can be used to sensitively differentiate between Marcellus Formation produced water and other potential sources of TDS into ground or surface waters.

A critical review of the risks to water resources from unconventional shale gas development and hydraulic fracturing in the United States.

Science.gov (United States)

Vengosh, Avner; Jackson, Robert B; Warner, Nathaniel; Darrah, Thomas H; Kondash, Andrew

2014-01-01

The rapid rise of shale gas development through horizontal drilling and high volume hydraulic fracturing has expanded the extraction of hydrocarbon resources in the U.S. The rise of shale gas development has triggered an intense public debate regarding the potential environmental and human health effects from hydraulic fracturing. This paper provides a critical review of the potential risks that shale gas operations pose to water resources, with an emphasis on case studies mostly from the U.S. Four potential risks for water resources are identified: (1) the contamination of shallow aquifers with fugitive hydrocarbon gases (i.e., stray gas contamination), which can also potentially lead to the salinization of shallow groundwater through leaking natural gas wells and subsurface flow; (2) the contamination of surface water and shallow groundwater from spills, leaks, and/or the disposal of inadequately treated shale gas wastewater; (3) the accumulation of toxic and radioactive elements in soil or stream sediments near disposal or spill sites; and (4) the overextraction of water resources for high-volume hydraulic fracturing that could induce water shortages or conflicts with other water users, particularly in water-scarce areas. Analysis of published data (through January 2014) reveals evidence for stray gas contamination, surface water impacts in areas of intensive shale gas development, and the accumulation of radium isotopes in some disposal and spill sites. The direct contamination of shallow groundwater from hydraulic fracturing fluids and deep formation waters by hydraulic fracturing itself, however, remains controversial.

Local area water removal analysis of a proton exchange membrane fuel cell under gas purge conditions.

Science.gov (United States)

Lee, Chi-Yuan; Lee, Yu-Ming; Lee, Shuo-Jen

2012-01-01

In this study, local area water content distribution under various gas purging conditions are experimentally analyzed for the first time. The local high frequency resistance (HFR) is measured using novel micro sensors. The results reveal that the liquid water removal rate in a membrane electrode assembly (MEA) is non-uniform. In the under-the-channel area, the removal of liquid water is governed by both convective and diffusive flux of the through-plane drying. Thus, almost all of the liquid water is removed within 30 s of purging with gas. However, liquid water that is stored in the under-the-rib area is not easy to remove during 1 min of gas purging. Therefore, the re-hydration of the membrane by internal diffusive flux is faster than that in the under-the-channel area. Consequently, local fuel starvation and membrane degradation can degrade the performance of a fuel cell that is started from cold.

Effects of Irrigating with Treated Oil and Gas Product Water on Crop Biomass and Soil Permeability

Energy Technology Data Exchange (ETDEWEB)

Terry Brown; Jeffrey Morris; Patrick Richards; Joel Mason

2010-09-30

Demonstrating effective treatment technologies and beneficial uses for oil and gas produced water is essential for producers who must meet environmental standards and deal with high costs associated with produced water management. Proven, effective produced-water treatment technologies coupled with comprehensive data regarding blending ratios for productive long-term irrigation will improve the state-of-knowledge surrounding produced-water management. Effective produced-water management scenarios such as cost-effective treatment and irrigation will discourage discharge practices that result in legal battles between stakeholder entities. The goal of this work is to determine the optimal blending ratio required for irrigating crops with CBNG and conventional oil and gas produced water treated by ion exchange (IX), reverse osmosis (RO), or electro-dialysis reversal (EDR) in order to maintain the long term physical integrity of soils and to achieve normal crop production. The soils treated with CBNG produced water were characterized with significantly lower SAR values compared to those impacted with conventional oil and gas produced water. The CBNG produced water treated with RO at the 100% treatment level was significantly different from the untreated produced water, while the 25%, 50% and 75% water treatment levels were not significantly different from the untreated water. Conventional oil and gas produced water treated with EDR and RO showed comparable SAR results for the water treatment technologies. There was no significant difference between the 100% treated produced water and the control (river water). The EDR water treatment resulted with differences at each level of treatment, which were similar to RO treated conventional oil and gas water. The 100% treated water had SAR values significantly lower than the 75% and 50% treatments, which were similar (not significantly different). The results of the greenhouse irrigation study found the differences in biomass

Tomographic Imaging of Water Injection and Withdrawal in PEMFC Gas Diffusion Layers

Energy Technology Data Exchange (ETDEWEB)

McGill U; Gostick, J. T.; Gunterman, H. P.; Weber, A. Z.; Newman, J. S.; Kienitz, B. L.; MacDowell, A. A.

2010-06-25

X-ray computed tomography was used to visualize the water configurations inside gas diffusion layers for various applied capillary pressures, corresponding to both water invasion and withdrawal. A specialized sample holder was developed to allow capillary pressure control on the small-scale samples required. Tests were performed on GDL specimens with and without hydrophobic treatments.

Coupling Effect of Intruding Water and Inherent Gas on Coal Strength Based on the Improved (Mohr-Coulomb Failure Criterion

Directory of Open Access Journals (Sweden)

Yiyu Lu

2016-11-01

Full Text Available When employing hydraulic processes to increase gas drainage efficiency in underground coal mines, coal seams become a three-phase medium, containing water intruding into the coal pores with the inherent occurrence of gas. This can change the stress state of the coal and cause instability. This work studied the mechanical properties of coal containing water and gas and derived an appropriate failure criterion. Based on mixture theory of unsaturated porous media, the effective stress of coal, considering the interaction of water and gas, was analyzed, and the failure criterion established by combining this with the Mohr–Coulomb criterion. By introducing the stress factor of matrix suction and using fitted curves of experimentally determined matrix suction and moisture content, the relationships between coal strength, gas pressure, and moisture content were determined. To verify the established strength theory, a series of triaxial compression strength tests of coal containing water and gas were carried out on samples taken from the Songzao, Pingdingshan, and Tashan mines in China. The experimental results correlated well with the theoretical predictions. The results showed a linear decrease in the peak strength of coal with increasing gas pressure and an exponential reduction in peak strength with increasing moisture content. The strength theory of coal containing water and gas can become an important part of multiphase medium damage theory.

Numerical Investigation of a Liquid-Gas Ejector Used for Shipping Ballast Water Treatment

Directory of Open Access Journals (Sweden)

Xueguan Song

2014-01-01

Full Text Available Shipping ballast water can have significant ecological and economic impacts on aquatic ecosystems. Currently, water ejectors are widely used in marine applications for ballast water treatment owing to their high suction capability and reliability. In this communication, an improved ballast treatment system employing a liquid-gas ejector is introduced to clear the ballast water to reduce environmental risks. Commonly, the liquid-gas ejector uses ballast water as the primary fluid and chemical ozone as the secondary fluid. In this study, high-pressure water and air, instead of ballast water and ozone, are considered through extensive numerical and experimental research. The ejector is particularly studied by a steady three-dimensional multiphase computational fluid dynamics (CFD analysis with commercial software ANSYS-CFX 14.5. Different turbulence models (including standard k-ε, RNG k-ε, SST, and k-ω with different grid size and bubble size are compared extensively and the experiments are carried out to validate the numerical design and optimization. This study concludes that the RNG k-ε turbulence model is the most efficient and effective for the ballast water treatment system under consideration and simple change of nozzle shape can greatly improve the ejector performance under high back pressure conditions.

Flow structure of conical distributed multiple gas jets injected into a water chamber

Energy Technology Data Exchange (ETDEWEB)

Zhao, Jiajun; Yu, Yonggang [Nanjing University of Science and Technology, Nanjing (China)

2017-04-15

Based on an underwater gun firing project, a mock bullet with several holes on the head was designed and experimented to observe the combustion gas injected into a cylindrical water chamber through this mock bullet. The combustion gas jets contain one vertical central jet and 4 to 8 slant lateral jets. A high speed camera system was used to record the expansion of gas jets in the experimental study. In numerical simulations, the Euler two-fluid model and volume of fluid method were adopted to describe the gas-liquid flow. The results show the backflow zone in lateral jet is the main factor influencing the gas-liquid turbulent mixing in downstream. On cross sections, the gas volume fraction increased with time but the growth rate decreased. With a change of nozzle structure, the gas fraction was more affected than the shock structure.

Research for rolling effects on flow pattern of gas-water flow in horizontal tubes

International Nuclear Information System (INIS)

Luan Feng; Yan Changqi

2007-01-01

The flow pattern transition of two-phase flow is caused by the inertial force resulted from rolling and incline of horizontal tubes under rolling state. an experimental study on the flow patterns of gas-water flow was carried out in horizontal tubes under rolling state, which rolling period is 15 second and rolling angle is 10 degrees, and a pattern flow picture is shown. It was found that there are two flow patterns in one rolling period under some gas flux and water flux. (authors)

Generation of ozone by pulsed corona discharge over water surface in hybrid gas-liquid electrical discharge reactor

Energy Technology Data Exchange (ETDEWEB)

Lukes, Petr [Department of Pulse Plasma Systems, Institute of Plasma Physics, Academy of Sciences of the Czech Republic, Za Slovankou 3, PO Box 17, 182 21 Prague 8 (Czech Republic); Clupek, Martin [Department of Pulse Plasma Systems, Institute of Plasma Physics, Academy of Sciences of the Czech Republic, Za Slovankou 3, PO Box 17, 182 21 Prague 8 (Czech Republic); Babicky, Vaclav [Department of Pulse Plasma Systems, Institute of Plasma Physics, Academy of Sciences of the Czech Republic, Za Slovankou 3, PO Box 17, 182 21 Prague 8 (Czech Republic); Janda, Vaclav [Department of Water Technology and Environmental Engineering, Institute of Chemical Technology, Technicka 5, 160 28 Prague 6 (Czech Republic); Sunka, Pavel [Department of Pulse Plasma Systems, Institute of Plasma Physics, Academy of Sciences of the Czech Republic, Za Slovankou 3, PO Box 17, 182 21 Prague 8 (Czech Republic)

2005-02-07

Ozone formation by a pulse positive corona discharge generated in the gas phase between a planar high voltage electrode made from reticulated vitreous carbon and a water surface with an immersed ground stainless steel plate electrode was investigated under various operating conditions. The effects of gas flow rate (0.5-3 litre min{sup -1}), discharge gap spacing (2.5-10 mm), applied input power (2-45 W) and gas composition (oxygen containing argon or nitrogen) on ozone production were determined. Ozone concentration increased with increasing power input and with increasing discharge gap. The production of ozone was significantly affected by the presence of water vapour formed through vaporization of water at the gas-liquid interface by the action of the gas phase discharge. The highest energy efficiency for ozone production was obtained using high voltage pulses of approximately 150 ns duration in Ar/O{sub 2} mixtures with the maximum efficiency (energy yield) of 23 g kW h{sup -1} for 40% argon content.

Generation of ozone by pulsed corona discharge over water surface in hybrid gas-liquid electrical discharge reactor

International Nuclear Information System (INIS)

Lukes, Petr; Clupek, Martin; Babicky, Vaclav; Janda, Vaclav; Sunka, Pavel

2005-01-01

Ozone formation by a pulse positive corona discharge generated in the gas phase between a planar high voltage electrode made from reticulated vitreous carbon and a water surface with an immersed ground stainless steel plate electrode was investigated under various operating conditions. The effects of gas flow rate (0.5-3 litre min -1 ), discharge gap spacing (2.5-10 mm), applied input power (2-45 W) and gas composition (oxygen containing argon or nitrogen) on ozone production were determined. Ozone concentration increased with increasing power input and with increasing discharge gap. The production of ozone was significantly affected by the presence of water vapour formed through vaporization of water at the gas-liquid interface by the action of the gas phase discharge. The highest energy efficiency for ozone production was obtained using high voltage pulses of approximately 150 ns duration in Ar/O 2 mixtures with the maximum efficiency (energy yield) of 23 g kW h -1 for 40% argon content

Water-saturated systems of the largest gas and gas-condensate deposits of the USSR. Vodonapornye sistemy krupneishikh gazovykh i gazokondensatnykh mestorozhdenii sssr

Energy Technology Data Exchange (ETDEWEB)

Kortsenshtein, V.N.

1977-01-01

A description is given of water-pressure systems in a number of the largest gas and gas-condensate fields of the Soviet Union, whose industrial reserves exceed 500 billion cubic meters. These include fields located in the concluding stage of development with sharply reduced recovery (Shebelinsk), fields that have just begun to operate and are characterized by increasing production (Vuktyl, Medved, Orenburg, Shatlyk, Urengoisk), and fields that are not yet developed (Yamburg and Zapolyar). Problems in the theory and practice of studying water-pressure systems of the largest gas and gas-condensate fields are analyzed primarily in connection with conditions required for their rational development which would provide for a maximum extraction of hydrocarbons from the interior. Importance is also given to the hydrogeological aspects of the formation of large hydrocarbon deposits and their distribution in the earth's crust. The most reliable factual materials on hydrogeology are utilized. The book is designed for personnel in the gas and oil industries, hydrogeologists, and scientists interested in problems of the formation, survey, and development of the largest hydrocarbon deposits. 92 references, 65 figures, 71 tables.

The Water-Induced Linear Reduction Gas Diffusivity Model Extended to Three Pore Regions

DEFF Research Database (Denmark)

Chamindu, T. K. K. Deepagoda; de Jonge, Lis Wollesen; Kawamoto, Ken

2015-01-01

. Characterization of soil functional pore structure is an essential prerequisite to understand key gas transport processes in variably saturated soils in relation to soil ecosystems, climate, and environmental services. In this study, the water-induced linear reduction (WLR) soil gas diffusivity model originally...... gas diffusivity from moist to dry conditions across differently structured porous media, including narrow soil size fractions, perforated plastic blocks, fractured limestone, peaty soils, aggregated volcanic ash soils, and particulate substrates for Earth- or space-based applications. The new Cip...

Peach water relations, gas exchange, growth and shoot mortality under water deficit in semi-arid weather conditions.

Science.gov (United States)

Rahmati, Mitra; Davarynejad, Gholam Hossein; Génard, Michel; Bannayan, Mohammad; Azizi, Majid; Vercambre, Gilles

2015-01-01

In this study the sensitivity of peach tree (Prunus persica L.) to three water stress levels from mid-pit hardening until harvest was assessed. Seasonal patterns of shoot and fruit growth, gas exchange (leaf photosynthesis, stomatal conductance and transpiration) as well as carbon (C) storage/mobilization were evaluated in relation to plant water status. A simple C balance model was also developed to investigate sink-source relationship in relation to plant water status at the tree level. The C source was estimated through the leaf area dynamics and leaf photosynthesis rate along the season. The C sink was estimated for maintenance respiration and growth of shoots and fruits. Water stress significantly reduced gas exchange, and fruit, and shoot growth, but increased fruit dry matter concentration. Growth was more affected by water deficit than photosynthesis, and shoot growth was more sensitive to water deficit than fruit growth. Reduction of shoot growth was associated with a decrease of shoot elongation, emergence, and high shoot mortality. Water scarcity affected tree C assimilation due to two interacting factors: (i) reduction in leaf photosynthesis (-23% and -50% under moderate (MS) and severe (SS) water stress compared to low (LS) stress during growth season) and (ii) reduction in total leaf area (-57% and -79% under MS and SS compared to LS at harvest). Our field data analysis suggested a Ψstem threshold of -1.5 MPa below which daily net C gain became negative, i.e. C assimilation became lower than C needed for respiration and growth. Negative C balance under MS and SS associated with decline of trunk carbohydrate reserves--may have led to drought-induced vegetative mortality.

Photoacoustic infrared spectroscopy for conducting gas tracer tests and measuring water saturations in landfills

International Nuclear Information System (INIS)

Jung, Yoojin; Han, Byunghyun; Mostafid, M. Erfan; Chiu, Pei; Yazdani, Ramin; Imhoff, Paul T.

2012-01-01

Highlights: ► Photoacoustic infrared spectroscopy tested for measuring tracer gas in landfills. ► Measurement errors for tracer gases were 1–3% in landfill gas. ► Background signals from landfill gas result in elevated limits of detection. ► Technique is much less expensive and easier to use than GC. - Abstract: Gas tracer tests can be used to determine gas flow patterns within landfills, quantify volatile contaminant residence time, and measure water within refuse. While gas chromatography (GC) has been traditionally used to analyze gas tracers in refuse, photoacoustic spectroscopy (PAS) might allow real-time measurements with reduced personnel costs and greater mobility and ease of use. Laboratory and field experiments were conducted to evaluate the efficacy of PAS for conducting gas tracer tests in landfills. Two tracer gases, difluoromethane (DFM) and sulfur hexafluoride (SF 6 ), were measured with a commercial PAS instrument. Relative measurement errors were invariant with tracer concentration but influenced by background gas: errors were 1–3% in landfill gas but 4–5% in air. Two partitioning gas tracer tests were conducted in an aerobic landfill, and limits of detection (LODs) were 3–4 times larger for DFM with PAS versus GC due to temporal changes in background signals. While higher LODs can be compensated by injecting larger tracer mass, changes in background signals increased the uncertainty in measured water saturations by up to 25% over comparable GC methods. PAS has distinct advantages over GC with respect to personnel costs and ease of use, although for field applications GC analyses of select samples are recommended to quantify instrument interferences.

Raman spectroscopy measurement of CH4 gas and CH4 dissolved in water for laser remote sensing in water

Science.gov (United States)

Somekawa, Toshihiro; Fujita, Masayuki

2018-04-01

We examined the applicability of Raman spectroscopy as a laser remote sensing tool for monitoring CH4 in water. The Raman technique has already been used successfully for measurements of CO2 gas in water. In this paper, considering the spectral transmittance of water, third harmonics of Q-switched Nd:YAG laser at 355 nm (UV region) was used for detection of CH4 Raman signals. The Raman signal at 2892 cm-1 from CH4 dissolved in water was detected at a tail of water Raman signal.

Soil Gas Sample Handling: Evaluation of Water Removal and Sample Ganging

Energy Technology Data Exchange (ETDEWEB)

Fritz, Brad G. [Pacific Northwest National Lab. (PNNL), Richland, WA (United States); Abrecht, David G. [Pacific Northwest National Lab. (PNNL), Richland, WA (United States); Hayes, James C. [Pacific Northwest National Lab. (PNNL), Richland, WA (United States); Mendoza, Donaldo P. [Pacific Northwest National Lab. (PNNL), Richland, WA (United States)

2016-10-31

Soil gas sampling is currently conducted in support of Nuclear Test Ban treaty verification. Soil gas samples are collected and analyzed for isotopes of interest. Some issues that can impact sampling and analysis of these samples are excess moisture and sample processing time. Here we discuss three potential improvements to the current sampling protocol; a desiccant for water removal, use of molecular sieve to remove CO₂ from the sample during collection, and a ganging manifold to allow composite analysis of multiple samples.

Standard for baseline water-well testing for coalbed methane/natural gas in coal operations

International Nuclear Information System (INIS)

2006-04-01

Interest in developing coalbed methane (CBM) is increasing with the decline of conventional natural gas reserves. In Alberta, where CBM is in the early stages of development, the drilling, production and operational rules for CBM are the same as those that apply to natural gas. The government of Alberta is presently examining the rules and regulations that apply to CBM to determine if they are appropriate for responsible development and balanced with environmental protection. CBM development has the potential to affect water aquifers and water supply. As such, a new standard has been developed by Alberta Environment in collaboration with the Alberta Energy and Utilities Board which requires that companies involved in the development of shallow CBM must offer to test rural Albertan's water wells prior to drilling. The companies will submit baseline groundwater data to both Alberta Environment and the landowner. The broader application of groundwater testing will also support Alberta Environment's objective of mapping all groundwater resources in the province. This new standard will help achieve continued protection of provincial groundwater resources and Albertan's groundwater supplies. It will also facilitate responsible CBM development and the government's Water for Life strategy. This document explained the protocols for testing, sampling and analyzing groundwater. The standard provides scientific information to support achievement of the outcomes as well as a regulatory basis for water well testing and baseline data collection prior to CBM development. If a landowner registers a complaint regarding a perceived change in well water quantity and quality after CBM development, then the developers must retest the water well to address the landowner's concerns. The tests evaluate water well capacity, water quality, routine potability and analysis for water quality parameters, including major ionic constituents, bacteriological analysis and presence or absence of gas

Pilot test of pressure maintenance by water injection and gas injection in the M'Bega field

Energy Technology Data Exchange (ETDEWEB)

Hodee, B

1965-02-01

The M'Bega reservoir, Gabon, is one that is both fractured and fissured, and its reservoir rock, improperly referred to as silicified clay, is made up of opal-cement silt. At the time it began production, the major unknown factor in this field was the amount of oil it contained. The factor was finally determined after 18 mo. of production, once data was obtained concerning the advance of aquifiers. Up until that time, applied comparisons of successive data could not differentiate between the activity of aquifers and that of dissolved gas expansion with partial segregation. Consequently, a pilot test was made in which pressure was maintained by water injection. Then, with a double drainage phenomena (the tops by the gas, and the flanks by the aquifer water), production of the field consisted of bringing about a coincidence between the water and gas fronts at the level of the existing wells by means of gas injection.

Characterizing Natural Gas Hydrates in the Deep Water Gulf of Mexico: Applications for Safe Exploration and Production Activities

Energy Technology Data Exchange (ETDEWEB)

Bent, Jimmy

2014-05-31

In 2000 Chevron began a project to learn how to characterize the natural gas hydrate deposits in the deep water portion of the Gulf of Mexico (GOM). Chevron is an active explorer and operator in the Gulf of Mexico and is aware that natural gas hydrates need to be understood to operate safely in deep water. In August 2000 Chevron worked closely with the National Energy Technology Laboratory (NETL) of the United States Department of Energy (DOE) and held a workshop in Houston, Texas to define issues concerning the characterization of natural gas hydrate deposits. Specifically, the workshop was meant to clearly show where research, the development of new technologies, and new information sources would be of benefit to the DOE and to the oil and gas industry in defining issues and solving gas hydrate problems in deep water.

Leaf gas films delay salt entry and enhance underwater photosynthesis and internal aeration of Melilotus siculus submerged in saline water

DEFF Research Database (Denmark)

Teakle, Natasha Lea; Colmer, Timothy David; Pedersen, Ole

2014-01-01

A combination of flooding and salinity is detrimental to most plants. We studied tolerance of complete submergence in saline water for Melilotus siculus, an annual legume with superhydrophobic leaf surfaces that retain gas films when under water. M. siculus survived complete submergence of 1 week...... at low salinity (up to 50 mol m(-3) NaCl), but did not recover following de-submergence from 100 mol m(-3) NaCl. The leaf gas films protected against direct salt ingress into the leaves when submerged in saline water, enabling underwater photosynthesis even after 3 d of complete submergence. By contrast......, leaves with the gas films experimentally removed suffered from substantial Na(+) and Cl(-) intrusion and lost the capacity for underwater photosynthesis. Similarly, plants in saline water and without gas films lost more K(+) than those with intact gas films. This study has demonstrated that leaf gas...

Managing produced water from coal seam gas projects: implications for an emerging industry in Australia.

Science.gov (United States)

Davies, Peter J; Gore, Damian B; Khan, Stuart J

2015-07-01

This paper reviews the environmental problems, impacts and risks associated with the generation and disposal of produced water by the emerging coal seam gas (CSG) industry and how it may be relevant to Australia and similar physical settings. With only limited independent research on the potential environmental impacts of produced water, is it necessary for industry and government policy makers and regulators to draw upon the experiences of related endeavours such as mining and groundwater extraction accepting that the conclusions may not always be directly transferrable. CSG is widely touted in Australia as having the potential to provide significant economic and energy security benefits, yet the environmental and health policies and the planning and regulatory setting are yet to mature and are continuing to evolve amidst ongoing social and environmental concerns and political indecision. In this review, produced water has been defined as water that is brought to the land surface during the process of recovering methane gas from coal seams and includes water sourced from CSG wells as well as flowback water associated with drilling, hydraulic fracturing and gas extraction. A brief overview of produced water generation, its characteristics and environmental issues is provided. A review of past lessons and identification of potential risks, including disposal options, is included to assist in planning and management of this industry.

Advances of zeolite based membrane for hydrogen production via water gas shift reaction

Science.gov (United States)

Makertihartha, I. G. B. N.; Zunita, M.; Rizki, Z.; Dharmawijaya, P. T.

2017-07-01

Hydrogen is considered as a promising energy vector which can be obtained from various renewable sources. However, an efficient hydrogen production technology is still challenging. One technology to produce hydrogen with very high capacity with low cost is through water gas shift (WGS) reaction. Water gas shift reaction is an equilibrium reaction that produces hydrogen from syngas mixture by the introduction of steam. Conventional WGS reaction employs two or more reactors in series with inter-cooling to maximize conversion for a given volume of catalyst. Membrane reactor as new technology can cope several drawbacks of conventional reactor by removing reaction product and the reaction will favour towards product formation. Zeolite has properties namely high temperature, chemical resistant, and low price makes it suitable for membrane reactor applications. Moreover, it has been employed for years as hydrogen selective layer. This review paper is focusing on the development of membrane reactor for efficient water gas shift reaction to produce high purity hydrogen and carbon dioxide. Development of membrane reactor is discussed further related to its modification towards efficient reaction and separation from WGS reaction mixture. Moreover, zeolite framework suitable for WGS membrane reactor will be discussed more deeply.

Effects of water vapor on flue gas conditioning in the electric fields with corona discharge.

Science.gov (United States)

Liqiang, Qi; Yajuan, Zhang

2013-07-15

Sulfur dioxide (SO2) removal via pulsed discharge nonthermal plasma in the absence of ammonia was investigated to determine how electrostatic precipitators (ESPs) can effectively collect particulate matter less than 2.5μm in diameter from flue gas. SO2 removal increased as water vapor concentration increased. In a wet-type plasma reactor, directing a gas-phase discharge plasma toward the water film surface significantly enhanced the liquid-phase oxidation of HSO3(-) to SO4(2-). Comparisons of various absorbents revealed that the hydroxyl radical is a key factor in plasma-induced liquid-phase reactions. The resistivity, size distribution, and cohesive force of fly ash at different water vapor contents were measured using a Bahco centrifuge, which is a dust electrical resistivity test instrument, as well as a cohesive force test apparatus developed by the researchers. When water vapor content increased by 5%, fly ash resistivity in flue gas decreased by approximately two orders of magnitude, adhesive force and size increased, and specific surface area decreased. Therefore, ESP efficiency increased. Copyright © 2013 Elsevier B.V. All rights reserved.

Effects of water vapor on flue gas conditioning in the electric fields with corona discharge

Energy Technology Data Exchange (ETDEWEB)

Liqiang, QI, E-mail: qi_liqiang@163.com; Yajuan, Zhang

2013-07-15

Highlights: • The influence mechanism of water vapor humidification on SO{sub 2} oxidation was analyzed. •The effects of water vapor on the specific resistance in fly ash in ESPs were reported. • The effects of water vapor on the size distribution and specific surface area of fly ash were discussed. • The adhesive characteristic of fly ash in different water vapor was experimented. -- Abstract: Sulfur dioxide (SO{sub 2}) removal via pulsed discharge nonthermal plasma in the absence of ammonia was investigated to determine how electrostatic precipitators (ESPs) can effectively collect particulate matter less than 2.5 μm in diameter from flue gas. SO{sub 2} removal increased as water vapor concentration increased. In a wet-type plasma reactor, directing a gas-phase discharge plasma toward the water film surface significantly enhanced the liquid-phase oxidation of HSO{sub 3}{sup −} to SO{sub 4}{sup 2−}. Comparisons of various absorbents revealed that the hydroxyl radical is a key factor in plasma-induced liquid-phase reactions. The resistivity, size distribution, and cohesive force of fly ash at different water vapor contents were measured using a Bahco centrifuge, which is a dust electrical resistivity test instrument, as well as a cohesive force test apparatus developed by the researchers. When water vapor content increased by 5%, fly ash resistivity in flue gas decreased by approximately two orders of magnitude, adhesive force and size increased, and specific surface area decreased. Therefore, ESP efficiency increased.

Pulsed electrical discharge in gas bubbles in water

Science.gov (United States)

Gershman, Sophia

A phenomenological picture of pulsed electrical discharge in gas bubbles in water is produced by combining electrical, spectroscopic, and imaging methods. The discharge is generated by applying one microsecond long 5 to 20 kilovolt pulses between the needle and disk electrodes submerged in water. A gas bubble is generated at the tip of the needle electrode. The study includes detailed experimental investigation of the discharge in argon bubbles and a brief look at the discharge in oxygen bubbles. Imaging, electrical characteristics, and time-resolved optical emission data point to a fast streamer propagation mechanism and formation of a plasma channel in the bubble. Spectroscopic methods based on line intensity ratios and Boltzmann plots of line intensities of argon, atomic hydrogen, and argon ions and the examination of molecular emission bands from molecular nitrogen and hydroxyl radicals provide evidence of both fast beam-like electrons and slow thermalized ones with temperatures of 0.6 -- 0.8 electron-volts. The collisional nature of plasma at atmospheric pressure affects the decay rates of optical emission. Spectroscopic study of rotational-vibrational bands of hydroxyl radical and molecular nitrogen gives vibrational and rotational excitation temperatures of the discharge of about 0.9 and 0.1 electron-volt, respectively. Imaging and electrical evidence show that discharge charge is deposited on the bubble wall and water serves as a dielectric barrier for the field strength and time scales of this experiment. Comparing the electrical and imaging information for consecutive pulses applied at a frequency of 1 Hz indicates that each discharge proceeds as an entirely new process with no memory of the previous discharge aside from long-lived chemical species, such as ozone and oxygen. Intermediate values for the discharge gap and pulse duration, low repetition rate, and unidirectional character of the applied voltage pulses make the discharge process here unique

Local Fission Gas Release and Swelling in Water Reactor Fuel during Slow Power Transients

DEFF Research Database (Denmark)

Mogensen, Mogens Bjerg; Walker, C.T.; Ray, I.L.F.

1985-01-01

Gas release and fuel swelling caused by a power increase in a water reactor fuel (burn-up 2.7–4.5% FIMA) is described. At a bump terminal level of about 400 W/cm (local value) gas release was 25–40%. The formation of gas bubbles on grain boundaries and their degree of interlinkage are the two...... factors that determine the level of fission gas release during a power bump. Release begins when gas bubbles on grain boundaries start o interlink. This occurred at r/r0 ~ 0.75. Release tunnels were fully developed at r/r0 ~ 0.55 with the result that gas release was 60–70% at this position....

Coal seam gas water: potential hazards and exposure pathways in Queensland.

Science.gov (United States)

Navi, Maryam; Skelly, Chris; Taulis, Mauricio; Nasiri, Shahram

2015-01-01

The extraction of coal seam gas (CSG) produces large volumes of potentially contaminated water. It has raised concerns about the environmental health impacts of the co-produced CSG water. In this paper, we review CSG water contaminants and their potential health effects in the context of exposure pathways in Queensland's CSG basins. The hazardous substances associated with CSG water in Queensland include fluoride, boron, lead and benzene. The exposure pathways for CSG water are (1) water used for municipal purposes; (2) recreational water activities in rivers; (3) occupational exposures; (4) water extracted from contaminated aquifers; and (5) indirect exposure through the food chain. We recommend mapping of exposure pathways into communities in CSG regions to determine the potentially exposed populations in Queensland. Future efforts to monitor chemicals of concern and consolidate them into a central database will build the necessary capability to undertake a much needed environmental health impact assessment.

A simple technique for continuous measurement of time-variable gas transfer in surface waters

Science.gov (United States)

Tobias, Craig R.; Bohlke, John Karl; Harvey, Judson W.; Busenberg, Eurybiades

2009-01-01

Mass balance models of dissolved gases in streams, lakes, and rivers serve as the basis for estimating wholeecosystem rates for various biogeochemical processes. Rates of gas exchange between water and the atmosphere are important and error-prone components of these models. Here we present a simple and efficient modification of the SF6 gas tracer approach that can be used concurrently while collecting other dissolved gas samples for dissolved gas mass balance studies in streams. It consists of continuously metering SF6-saturated water directly into the stream at a low rate of flow. This approach has advantages over pulse injection of aqueous solutions or bubbling large amounts of SF6 into the stream. By adding the SF6 as a saturated solution, we minimize the possibility that other dissolved gas measurements are affected by sparging and/or bubble injecta. Because the SF6 is added continuously we have a record of changing gas transfer velocity (GTV) that is contemporaneous with the sampling of other nonconservative ambient dissolved gases. Over a single diel period, a 30% variation in GTV was observed in a second-order stream (Sugar Creek, Indiana, USA). The changing GTV could be attributed in part to changes in temperature and windspeed that occurred on hourly to diel timescales.

Radionuclides in produced water from Norwegian oil and gas installations — Concentrations and bioavailability

Science.gov (United States)

Eriksen, D. Ø.; Sidhu, R.; Strålberg, E.; Iden, K. I.; Hylland, K.; Ruus, A.; Røyset, O.; Berntssen, M. H. G.; Rye, H.

2006-01-01

Substantial amounts of produced water, containing elevated levels of radionuclides (mainly 226Ra and 228Ra) are discharged to the sea as a result of oil and gas production on the Norwegian Continental Shelf. So far no study has assessed the potential radiological effects on marine biota in connection with radionuclide discharges to the North Sea. The main objective of the project is to establish radiological safe discharge limits for radium, lead and polonium associated with other components in produced water from oil and gas installations on the Norwegian continental shelf. This study reports results indicating that the presence of added chemicals such as scale inhibitors in produced water has a marked influence on the formation of radium and barium sulphates when produced water is mixed with sea water. Thus, the mobility and bioavailability of radium (and barium) will be larger than anticipated. Also, the bioavailability of food-borne radium is shown to increase due to presence of such chemicals.

Description of gas hydrates equilibria in sediments using experimental data of soil water potential

Energy Technology Data Exchange (ETDEWEB)

Istomin, V. [NOVATEK, Moscow (Russian Federation); Chuvilin, E. [Moscow State Univ., Moscow (Russian Federation). Dept. of Geology; Makhonina, N.; Kvon, V. [VNIIGAZ, Moscow (Russian Federation); Safonov, S. [Schlumberger Moscow Research, Moscow (Russian Federation)

2008-07-01

Analytical relationships have been developed between hydrate dissociation pressure and vapor pressure above the pore water surface. In addition, experiments have been discussed in numerous publications on the effect of narrow interconnected throats between pores on clathrate dissociation conditions in porous media. This paper presented an approach that improved upon the available thermodynamic methods for calculation of hydrate phase equilibria. The approach took into account the properties of pore water in natural sediments including three-phase equilibrium of gas-pore water-gas hydrate in a similar way as for unfrozen water in geocryology science. The purpose of the paper was to apply and adapt geocryology and soil physics method to the thermodynamic calculation of non-clathrated water content in sediments. It answered the question of how to estimate the non-clathrated water content if pore water potential was known. The paper explained the thermodynamics of water phase in porous media including the thermodynamic properties of supercooled water, the thermodynamic properties of pore water and pore ice in sediments, and the phase equilibria of pore water. The paper also discussed the quantitative techniques that were utilized for determination of unfrozen water content in sediments and its dependence on temperature variation. These included contact-saturation, calorimetric, dielectric, nuclear magnetic resonance, and others. The thermodynamic calculations of pore water phase equilibria were also presented. 30 refs., 5 tabs., 8 figs.

A high charge state heavy ion beam source for heavy ion fusion

International Nuclear Information System (INIS)

Eylon, S.; Henestroza, E.

1996-01-01

A high current, low emittance, high charge state heavy ion beam source is being developed. This is designed to deliver a heavy ion fusion (HIF) driver accelerator scale beam. Using a high charge state beam in a driver accelerator for HIF may increase the acceleration efficiency, leading to a reduction in the driver accelerator size and cost. The proposed source system, which consists of a gas beam electron stripper followed by a high charge state beam separator, can be added to existing single charge state, low emittance, high brightness ion sources and injectors. We shall report on the source physics design using 3D beam simulations and experimental feasibility study results using a neutral gas stripper and a beam separator at the exit of the LBL 2 MV injector. (orig.)

A high charge state heavy ion beam source for HIF

International Nuclear Information System (INIS)

Eylon, S.; Henestroza, E.

1995-04-01

A high current low emittance high charge state heavy ion beam source is being developed. This is designed to deliver HIF (heavy ion fusion) driver accelerator scale beam. Using high-charge-state beam in a driver accelerator for HIF may increase the acceleration efficiency, leading to a reduction in the driver accelerator size and cost. The proposed source system which consists of the gas beam electron stripper followed by a high charge state beam separator, can be added to existing single charge state, low emittance, high brightness ion sources and injectors. We shall report on the source physics design using 2D beam envelope simulations and experimental feasibility studies' results using a neutral gas stripper and a beam separator at the exit of the LBL 2 MV injector

Investigating onychophoran gas exchange and water balance as a means to inform current controversies in arthropod physiology.

Science.gov (United States)

Clusella-Trullas, Susana; Chown, Steven L

2008-10-01

Several controversies currently dominate the fields of arthropod metabolic rate, gas exchange and water balance, including the extent to which modulation of gas exchange reduces water loss, the origins of discontinuous gas exchange, the relationship between metabolic rate and life-history strategies, and the causes of Palaeozoic gigantism. In all of these areas, repeated calls have been made for the investigation of groups that might most inform the debates, especially of taxa in key phylogenetic positions. Here we respond to this call by investigating metabolic rate, respiratory water loss and critical oxygen partial pressure (Pc) in the onychophoran Peripatopsis capensis, a member of a group basal to the arthropods, and by synthesizing the available data on the Onychophora. The rate of carbon dioxide release (VCO2) at 20 degrees C in P. capensis is 0.043 ml CO2 h(-1), in keeping with other onychophoran species; suggesting that low metabolic rates in some arthropod groups are derived. Continuous gas exchange suggests that more complex gas exchange patterns are also derived. Total water loss in P. capensis is 57 mg H2O h(-1) at 20 degrees C, similar to modern estimates for another onychophoran species. High relative respiratory water loss rates ( approximately 34%; estimated using a regression technique) suggest that the basal condition in arthropods may be a high respiratory water loss rate. Relatively high Pc values (5-10% O2) suggest that substantial safety margins in insects are also a derived condition. Curling behaviour in P. capensis appears to be a strategy to lower energetic costs when resting, and the concomitant depression of water loss is a proximate consequence of this behaviour.

Risk based asset management of pipeline networks for gas and water

NARCIS (Netherlands)

Abspoel, L.M.; Courage, W.M.G.; Broeck, W. van den; Kruse, H.

2017-01-01

Pipeline networks for gas and water are the lifelines of our society. Their presence and correct functioning translates in benefits and any disruption, malfunctioning or ruptures represent hazards for the community. Most pipelines are buried, which impedes direct monitoring of the structural

Enhanced Removal of Hydrophobic Gas by Aerial Ultrasonic Waves and Two Kinds of Water Mists of Different Particle Sizes

Science.gov (United States)

Matsumoto, Keisuke; Miura, Hikaru

2012-07-01

Air pollutants can cause health problems, such as bronchitis and cancer, and are now recognized as a social problem. Hence, a method is proposed for the collection and removal of gaseous air pollutants by aerial ultrasonic waves and water mist. Typically, gas removal effects are studied using lemon oil vapor (“lemon gas”), which is a hydrophobic gas. Previous experiments using lemon gas have shown that a removal rate of up to 40% can be achieved in an intense standing wave at 20 kHz, for an amount of water mist of 1.39 cm3/s and an electrical input power of 50 W. Increasing the surface area of the water mist leads to greater removal of hydrophobic gas. In this study, the effects of gas removal are examined by conducting experiments using intense aerial ultrasonic waves to disperse two kinds of water mists, each composed of particles of different sizes: small particles (diameter: ≈3 µm) and conventional large particles (diameter: ≈60 µm).

Water-saving liquid-gas conditioning system

Science.gov (United States)

Martin, Christopher; Zhuang, Ye

2014-01-14

A method for treating a process gas with a liquid comprises contacting a process gas with a hygroscopic working fluid in order to remove a constituent from the process gas. A system for treating a process gas with a liquid comprises a hygroscopic working fluid comprising a component adapted to absorb or react with a constituent of a process gas, and a liquid-gas contactor for contacting the working fluid and the process gas, wherein the constituent is removed from the process gas within the liquid-gas contactor.

[The hygienic evaluation of an aerosol-gas mixture as a preservative of potable water].

Science.gov (United States)

Prokopov, V A; Gakal, R K; Mironets, N V; Byshovets, T F; Martyshchenko, N V; Teteneva, I A; Nadvornaia, Zh N

1993-01-01

Complex hygienic assessment of the aerosol-gas method for the drinking water conservation demonstrated no significant effects on white rats in toxicological and genetical experiments. The method was recommended for long-term conservation of the drinking water in steel tanks.

Electricity, Gas and Water Supply. Industry Training Monograph No. 4.

Science.gov (United States)

Dumbrell, Tom

Australia's electricity, gas, and water supply industry employs only 0.8% of the nation's workers and employment in the industry has declined by nearly 39% in the last decade. This industry is substantially more dependent on the vocational education and training (VET) sector for skilled graduates than is the total Australian labor market. Despite…

Leaf water potential, gas exchange and chlorophyll a fluorescence in acariquara seedlings (Minquartia guianensis Aubl.) under water stress and recovery

OpenAIRE

Liberato, Maria Astrid Rocha; Gonçalves, José Francisco de Carvalho; Chevreuil, Larissa Ramos; Nina Junior, Adamir da Rocha; Fernandes, Andreia Varmes; Santos Junior, Ulysses Moreira dos

2006-01-01

The physiological performance of acariquara (Minquartia guianensis) seedlings submitted to water deficit and the recovery of physiological parameters during rehydration were investigated in a greenhouse experiment. The analyzed parameters were: leaf water potential, gas exchange and chlorophyll a fluorescence. After thirty-five days, non-irrigated plants exhibited a leaf water potential 70 % lower compared to control plants (irrigated daily) and the stomatal conductance reached values close t...

Disposal/recovery options for brine waters from oil and gas production in New York State. Final report

Energy Technology Data Exchange (ETDEWEB)

Matsumoto, M.R.; Atkinson, J.F.; Bunn, M.D.; Hodge, D.S.

1996-03-01

Produced water from oil and gas operations, or brine as it is typically referred, may be characterized as being highly saline, with total dissolved solids greater than 100 g/L. If these bribes are disposed improperly there may be severe adverse environmental effects. Thus, it is important that brine be disposed using environmentally sound methods. Unfortunately, costs for the disposal of brine water are a significant burden to oil and gas producers in New York State. These costs and the relatively low market price of oil and natural gas have contributed to the decline in gas and oil production in New York State during the past 10 years. The objectives of this study were to evaluate new and existing options for brine disposal in New York State, examine the technical and economic merits of these options, and assess environmental impacts associated with each option. Two new disposal options investigated for New York State oil and gas producers included construction of a regional brine treatment facility to treat brine prior to discharge into a receiving water and a salt production facility that utilizes produced water as a feed stock. Both options are technically feasible; however, their economic viability depends on facility size and volume of brine treated.

Disposal/recovery options for brine waters from oil and gas production in New York State. Final report

International Nuclear Information System (INIS)

Matsumoto, M.R.; Atkinson, J.F.; Bunn, M.D.; Hodge, D.S.

1996-03-01

Produced water from oil and gas operations, or brine as it is typically referred, may be characterized as being highly saline, with total dissolved solids greater than 100 g/L. If these bribes are disposed improperly there may be severe adverse environmental effects. Thus, it is important that brine be disposed using environmentally sound methods. Unfortunately, costs for the disposal of brine water are a significant burden to oil and gas producers in New York State. These costs and the relatively low market price of oil and natural gas have contributed to the decline in gas and oil production in New York State during the past 10 years. The objectives of this study were to evaluate new and existing options for brine disposal in New York State, examine the technical and economic merits of these options, and assess environmental impacts associated with each option. Two new disposal options investigated for New York State oil and gas producers included construction of a regional brine treatment facility to treat brine prior to discharge into a receiving water and a salt production facility that utilizes produced water as a feed stock. Both options are technically feasible; however, their economic viability depends on facility size and volume of brine treated

Low-btu gas in the US Midcontinent: A challenge for geologists and engineers

Science.gov (United States)

Newell, K. David; Bhattacharya, Saibal; Sears, M. Scott

2009-01-01

Several low-btu gas plays can be defined by mapping gas quality by geological horizon in the Midcontinent. Some of the more inviting plays include Permian strata west of the Central Kansas uplift and on the eastern flank of Hugoton field and Mississippi chat and other pays that subcrop beneath (and directly overlie) the basal Pennsylvanian angular unconformity at the southern end of the Central Kansas uplift. Successful development of these plays will require the cooperation of reservoir geologists and process engineers so that the gas can be economically upgraded and sold at a nominal pipeline quality of 950 btu/scf or greater. Nitrogen is the major noncombustible contaminant in these gas fields, and various processes can be utilized to separate it from the hydrocarbon gases. Helium, which is usually found in percentages corresponding to nitrogen, is a possible ancillary sales product in this region. Its separation from the nitrogen, of course, requires additional processing. The engineering solution for low-btu gas depends on the rates, volumes, and chemistry of the gas needing upgrading. Cryogenic methods of nitrogen removal are classically used for larger feed volumes, but smaller feed volumes characteristic of isolated, low-pressure gas fields can now be handled by available small-scale PSA technologies. Operations of these PSA plants are now downscaled for upgrading stripper well gas production. Any nitrogen separation process should be sized, within reason, to match the anticipated flow rate. If the reservoir rock surprises to the upside, the modularity of the upgrading units is critical, for they can be stacked to meet higher volumes. If a reservoir disappoints (and some will), modularity allows the asset to be moved to another site without breaking the bank.

Effect of damage on water retention and gas transport properties geo-materials: Application to geological storage of radioactive waste

International Nuclear Information System (INIS)

M'Jahad, S.

2012-01-01

In the context of geological disposal of radioactive waste, this work contributes to the characterization of the effect of diffuse damage on the water retention and gas transfer properties of concrete (CEM I and CEM V) selected by Andra, Callovo-Oxfordian argillite (host rock) and argillite / concrete interfaces. This study provides information on the concrete microstructure from Mercury porosimetry intrusion and water retention curves: each concrete has a distinct microstructure, CEM I concrete is characterized by a significant proportion of capillary pores while CEM V concrete has a large proportion of C-S-H pores. Several protocols have been developed in order to damage concrete. The damage reduces water retention capacity of CEM I concrete and increases its gas permeability. Indeed, gas breakthrough pressure decreases significantly for damaged concrete, and this regardless of the type of concrete. For argillite, the sample mass increases gradually at RH = 100%, which creates and increases damage in the material. This reduces its ability to retain water. Otherwise, water retention and gas transport properties of argillite are highly dependent of its initial water saturation, which is linked to its damage. Finally, we observed a clogging phenomenon at the argillite/concrete interfaces, which is first mechanical and then hydraulic (and probably chemical) after water injection. This reduces the gas breakthrough pressure interfaces. (author)

Hydrodynamics and mass transfer deaeration of water on thermal power plants when used natural gas as a desorbing agent

Science.gov (United States)

Sharapov, V. I.; Kudryavtseva, E. V.

2017-11-01

The technology of low-temperature deaeration of water in thermal power plants was developed. It is proposed to use natural gas supplied to the furnace as desorbing agent in the deaerator instead steam or superheated water. Natural gas has low, often - negative temperature after reducing installs. At the same time, it contains virtually no corrosive gases, oxygen and carbon dioxide, thereby successfully may be used as a stripping agent in water deaeration. The calculation of the energy efficiency of the technology for a typical unit of CHP has shown that achieved a significant annual saving of fuel equivalent in the transition from the traditional method of deaeration of water in the low temperature deaeration. Hydrodynamic and mass transfer indicators were determined for the deaerator thermal power plants using as stripping medium natural gas supplied to the boiler burners. Theoretically required amount and the real specific consumption of natural gas were estimated for deaeration of water standard quality. The calculation of the hydrodynamic characteristics was presented for jet-bubbling atmospheric deaerator with undescended perforated plate when operating on natural gas. The calculation shows the possibility of using commercially available atmospheric deaerators for the application of the new low-temperature water deaeration technology.

WATER-GAS SHIFT KINETICS OVER IRON OXIDE CATALYSTS AT MEMBRANE REACTOR CONDITIONS; A

International Nuclear Information System (INIS)

Carl R.F. Lund

2001-01-01

This report covers the second year of a project investigating water-gas shift catalysts for use in membrane reactors. It has been established that a simple iron high temperature shift catalyst becomes ineffective in a membrane reactor because the reaction rate is severely inhibited by the build-up of the product CO(sub 2). During the past year, an improved microkinetic model for water-gas shift over iron oxide was developed. Its principal advantage over prior models is that it displays the correct asymptotic behavior at all temperatures and pressures as the composition approaches equilibrium. This model has been used to explore whether it might be possible to improve the performance of iron high temperature shift catalysts under conditions of high CO(sub 2) partial pressure. The model predicts that weakening the surface oxygen bond strength by less than 5% should lead to higher catalytic activity as well as resistance to rate inhibition at higher CO(sub 2) partial pressures. Two promoted iron high temperature shift catalysts were studied. Ceria and copper were each studied as promoters since there were indications in the literature that they might weaken the surface oxygen bond strength. Ceria was found to be ineffective as a promoter, but preliminary results with copper promoted FeCr high temperature shift catalyst show it to be much more resistant to rate inhibition by high levels of CO(sub 2). Finally, the performance of sulfided CoMo/Al(sub 2)O(sub 3) catalysts under conditions of high CO(sub 2) partial pressure was simulated using an available microkinetic model for water-gas shift over this catalyst. The model suggests that this catalyst might be quite effective in a medium temperature water-gas shift membrane reactor, provided that the membrane was resistant to the H(sub 2)S that is required in the feed

New test for oil soluble/water dispersible gas pipeline inhibitors

Energy Technology Data Exchange (ETDEWEB)

Stegmann, D.W.; Asperger, R.G.

1987-01-01

The wheel test provides good mixing of the condensate and water phases, the coupons are exposed to both phases. Therefore, the wheel test cannot distinguish between inhibitors that need continuous mixing of the these phases to maintain a water dispersion of the inhibitor and inhibitors that will self disperse into the water. This concept becomes important for pipelines in stratified flow where the water can settle out. In these cases with low turbulence, the inhibitor must self disperse into the water to be effective. The paper describes a test method to measure the effectiveness of an inhibitor and its ability to self disperse. The effectiveness of several inhibitors as predicted by the new test method is discussed relative to data from the wheel test and breaker tests. Field performance of these inhibitors in a gas gathering line, with liquids in stratified flow, are cities and compared with the results of the various laboratory tests.

Water status and gas exchange of umbu plants (Spondias tuberosa Arr. Cam.) propagated by seeds and stem cuttings.

OpenAIRE

LIMA FILHO, J. M. P.

2008-01-01

The experiment was carried out at the Embrapa Semi-Árido, Petrolina-PE, Brazil, in order to study the physiological responses of umbu plants propagated by seeds and by stem cuttings under water stress conditions, based on leaf water potential and gas exchange measurements. Data were collected in one-year plants established in pots containing 30 kg of a sandy soil and submitted to twenty-day progressive soil water deficit. The evaluations were based on leaf water potential and gas exchange dat...

Analysis on blow-down transient in water ingress accident of high temperature gas-cooled reactor

International Nuclear Information System (INIS)

Wang, Yan; Zheng, Yanhua; Li, Fu; Shi, Lei

2014-01-01

Water ingress into the primary circuit is generally recognized as one of the severe accidents with potential hazard to the modular high temperature gas-cooled reactor, which will cause a positive reactivity introduction with the increase of steam density in reactor core to enhance neutron slowing-down, also the chemical corrosion of graphite fuel elements and the damage of reflector structure material. The increase of the primary pressure may result in the opening of the safety valves, consequently leading the release of radioactive isotopes and flammable water gas. The research on water ingress transient is significant for the verification of inherent safety characteristics of high temperature gas-cooled reactor. The 200 MWe high temperature gas-cooled reactor (HTR-PM), designed by the Institute of Nuclear and New Energy Technology of Tsinghua University, is exampled to be analyzed in this paper. The design basis accident (DBA) scenarios of double-ended guillotine break of single heat-exchange tube (steam generator heat-exchange tube rupture) are simulated by the thermal-hydraulic analysis code, and some key concerns which are relative to the amount of water into the reactor core during the blow-down transient are analyzed in detail. The results show that both of water mass and steam ratio of the fluid spouting from the broken heat-exchange tube are affected by break location, which will increase obviously with the broken location closing to the outlet of the heat-exchange tube. The double-ended guillotine rupture at the outlet of the heat-exchange will result more steam penetrates into the reactor core in the design basis accident of water ingress. The mass of water ingress will also be affected by the draining system. It is concluded that, with reasonable optimization on design to balance safety and economy, the total mass of water ingress into the primary circuit of reactor could be limited effectively to meet the safety requirements, and the pollution of

The beam matching system between the preaccelerator and the main accelerator of the Van-de-Graaff cyclotron combination VICKSI

International Nuclear Information System (INIS)

Hinderer, G.

1975-01-01

The beam matching between the two accelerators of the heavy-ion accelerator combination VICKSI (Van de Graaff Isochron-Cyclotron Kombination fuer schwere Ionen) which is under construction at the Hahn-Meitner-Institut Berlin is investigated. The main elements are a combined gas- and carbon foil-stripper to increase the charge state of the ions and two clystron type high frequency bunchers for matching the longitudinal phase space. In order to minimize the enlargement of phase space due to energy- and angle straggling in the foil stripper a focus in all three dimensions is generated at this position. (orig./WL) [de

Water-ingress analysis for the 200 MWe pebble-bed modular high temperature gas-cooled reactor

International Nuclear Information System (INIS)

Zheng Yanhua; Shi Lei; Wang Yan

2010-01-01

Water ingress into the primary circuit is generally recognized as one of the severe accidents with potential hazard to the modular high temperature gas-cooled reactor adopting steam-turbine cycle, which will cause a positive reactivity introduction, as well as the chemical corrosion of graphite fuel elements and reflector structure material. Besides, increase of the primary pressure may result in the opening of the safety valves, consequently leading the release of radioactive isotopes and flammable water gas. The analysis of such a kind of important and particular accident is significant to verify the inherent safety characteristics of the modular HTR plants. Based on the preliminary design of the 200 MWe high temperature gas-cooled reactor pebble-bed modular (HTR-PM), the design basis accident of a double-ended guillotine break of one heating tube and the beyond design basis accident of a large break of the main steam collection plate have been analyzed by using TINTE code, which is a special transient analysis program for high temperature gas-cooled reactors. Some safety relevant concerns, such as the fuel temperature, the primary loop pressure, the graphite corrosion, the water gas releasing amount, as well as the natural convection influence on the condition of failing to close the blower flaps, have been studied in detail. The calculation results indicate that even under some severe hypothetical postulates, the HTR-PM is able to keep the inherent safeties of the modular high temperature gas-cooled reactor and has a relatively good natural plant response, which will not result in environmental radiation hazard.

Water use competition scenarios during the upcoming development of shale gas reserves across the Mexican Eagle Ford play Image already added

Science.gov (United States)

Arciniega, S.; Breña-Naranjo, J. A.; Hernaández Espriú, A.; Pedrozo-Acuña, A.

2017-12-01

Mexico has significant shale oil and gas resources mainly contained within the Mexican part of the Eagle Ford play (Mex-EF), in the Burgos Basin located in northern Mexico. Over the last years, concerns about the water use associated to shale gas development using hydraulic fracturing (HF) have been increasing in the United States and Canada. In Mexico, the recent approval of a new energy bill allows the exploration, development and production of shale gas reserves. However, several of the Mexican shale gas resources are located in water-limited environments, such as the Mex-EF. The lack of climate and hydrological gauging stations across this region constrains information about how much freshwater from surface and groundwater sources is available and whether its interannual water availability is sufficient to satisfy the water demand by other users (agricultural, urban) of the region This work projects the water availability across the Mex-EF and its water use derived from the expansion of unconventional gas developments over the next 15 years. Water availability is estimated using a water balance approach, where the irrigation's groundwater withdrawals time series were reconstructed using remote sensing products (vegetation index and hydrological outputs from LSMs) and validated with in situ observed water use at three different irrigation districts of the region. Water use for HF is inferred using type curves of gas production, flowback and produced (FP) water and curves of drilled wells per year from the US experience, mainly from the Texas-EF play. Scenarios that combine freshwater use and FP water use for HF are developed and the spatial distribution of HF well pads is projected using random samples with a range of wells' horizontal length. This proposed methodology can be applied in other shale formations of the world under water stress and it also helps to determine whether water scarcity can be a limiting factor for the shale gas industry over the next

Pre-Gas Drilling Drinking Water Testing--An Educational Opportunity for Extension

Science.gov (United States)

Swistock, Brian; Clark, James

2015-01-01

The increase in shale gas drilling in Pennsylvania has resulted in thousands of landowners receiving predrilling testing of their drinking water. Landowners often have difficulty understanding test reports resulting in low awareness of pre-existing problems. Extension and several partners developed a program to improve understanding of…

Corrosion of API 5L B and X52 in crude oil/water/gas mixtures

Energy Technology Data Exchange (ETDEWEB)

Perdomo, J J; Gonzalez, J J; Viloria, A; De Veer, H; De Abreu, Y

2000-02-01

Laboratory and field tests were conducted to evaluate the corrosion behavior of API 5L grade B and X52 steels using Furrial's crude oil in the presence of water and gas containing carbon dioxide (CO{sub 2}) and hydrogen sulfide (H{sub 2}S). The results suggest that the corrosiveness of this crude oil/water/gas mixture is not detrimental to either steel. However, pitting corrosion was observed. The low general corrosion rates measured were attributed to the natural inhibiting properties of the crude oil.

A membrane inlet mass spectrometry system for noble gases at natural abundances in gas and water samples.

Science.gov (United States)

Visser, Ate; Singleton, Michael J; Hillegonds, Darren J; Velsko, Carol A; Moran, Jean E; Esser, Bradley K

2013-11-15

Noble gases dissolved in groundwater can reveal paleotemperatures, recharge conditions, and precise travel times. The collection and analysis of noble gas samples are cumbersome, involving noble gas purification, cryogenic separation and static mass spectrometry. A quicker and more efficient sample analysis method is required for introduced tracer studies and laboratory experiments. A Noble Gas Membrane Inlet Mass Spectrometry (NG-MIMS) system was developed to measure noble gases at natural abundances in gas and water samples. The NG-MIMS system consists of a membrane inlet, a dry-ice water trap, a carbon-dioxide trap, two getters, a gate valve, a turbomolecular pump and a quadrupole mass spectrometer equipped with an electron multiplier. Noble gases isotopes (4)He, (22)Ne, (38)Ar, (84)Kr and (132)Xe are measured every 10 s. The NG-MIMS system can reproduce measurements made on a traditional noble gas mass spectrometer system with precisions of 2%, 8%, 1%, 1% and 3% for He, Ne, Ar, Kr and Xe, respectively. Noble gas concentrations measured in an artificial recharge pond were used to monitor an introduced xenon tracer and to reconstruct temperature variations to within 2 °C. Additional experiments demonstrated the capability to measure noble gases in gas and in water samples, in real time. The NG-MIMS system is capable of providing analyses sufficiently accurate and precise for introduced noble gas tracers at managed aquifer recharge facilities, groundwater fingerprinting based on excess air and noble gas recharge temperature, and field and laboratory studies investigating ebullition and diffusive exchange. Copyright © 2013 John Wiley & Sons, Ltd.

Uncertainties in gas dispersion at the Bruce heavy water plant

International Nuclear Information System (INIS)

Alp, E.; Ciccone, A.

1995-07-01

There have been concerns regarding the uncertainties in atmospheric dispersion of gases released from the Bruce Heavy Water Plant (BHWP). The concern arises due to the toxic nature of H 2 S, and its combustion product SO 2 . In this study, factors that contribute to the uncertainties, such as the effect of the shoreline setting, the potentially heavy gas nature of H 2 S releases, and concentration fluctuations, have been investigated. The basic physics of each of these issues has been described along with fundamental modelling principles. Recommendations have been provided on available computer models that would be suitable for modelling gas dispersion in the vicinity of the BHWP. (author). 96 refs., 4 tabs., 25 figs

Uncertainties in gas dispersion at the Bruce heavy water plant

Energy Technology Data Exchange (ETDEWEB)

Alp, E; Ciccone, A [Concord Environmental Corp., Downsview, ON (Canada)

1995-07-01

There have been concerns regarding the uncertainties in atmospheric dispersion of gases released from the Bruce Heavy Water Plant (BHWP). The concern arises due to the toxic nature of H{sub 2}S, and its combustion product SO{sub 2}. In this study, factors that contribute to the uncertainties, such as the effect of the shoreline setting, the potentially heavy gas nature of H{sub 2}S releases, and concentration fluctuations, have been investigated. The basic physics of each of these issues has been described along with fundamental modelling principles. Recommendations have been provided on available computer models that would be suitable for modelling gas dispersion in the vicinity of the BHWP. (author). 96 refs., 4 tabs., 25 figs.

Responses to water stress of gas exchange and metabolites in Eucalyptus and Acacia spp.

Science.gov (United States)

Warren, Charles R; Aranda, Ismael; Cano, F Javier

2011-10-01

Studies of water stress commonly examine either gas exchange or leaf metabolites, and many fail to quantify the concentration of CO₂ in the chloroplasts (C(c)). We redress these limitations by quantifying C(c) from discrimination against ¹³CO₂ and using gas chromatography-mass spectrometry (GC-MS) for leaf metabolite profiling. Five Eucalyptus and two Acacia species from semi-arid to mesic habitats were subjected to a 2 month water stress treatment (Ψ(pre-dawn) = -1.7 to -2.3 MPa). Carbohydrates dominated the leaf metabolite profiles of species from dry areas, whereas organic acids dominated the metabolite profiles of species from wet areas. Water stress caused large decreases in photosynthesis and C(c), increases in 17-33 metabolites and decreases in 0-9 metabolites. In most species, fructose, glucose and sucrose made major contributions to osmotic adjustment. In Acacia, significant osmotic adjustment was also caused by increases in pinitol, pipecolic acid and trans-4-hydroxypipecolic acid. There were also increases in low-abundance metabolites (e.g. proline and erythritol), and metabolites that are indicative of stress-induced changes in metabolism [e.g. γ-aminobutyric acid (GABA) shunt, photorespiration, phenylpropanoid pathway]. The response of gas exchange to water stress and rewatering is rather consistent among species originating from mesic to semi-arid habitats, and the general response of metabolites to water stress is rather similar, although the specific metabolites involved may vary. © 2011 Blackwell Publishing Ltd.

Total dissolved gas, barometric pressure, and water temperature data, lower Columbia River, Oregon and Washington, 1996

Science.gov (United States)

Tanner, Dwight Q.; Harrison, Howard E.; McKenzie, Stuart W.

1996-01-01

Increased levels of total dissolved gas pressure can cause gas-bubble trauma in fish downstream from dams on the Columbia River. In cooperation with the U.S. Army Corps of Engineers, the U.S. Geological Survey collected data on total dissolved gas pressure, barometric pressure, water temperature, and dissolved oxygen pressure at 11 stations on the lower Columbia River from the John Day forebay (river mile 215.6) to Wauna Mill (river mile 41.9) from March to September 1996. Methods of data collection, review, and processing are described in this report. Summaries of daily minimum, maximum, and mean hourly values are presented for total dissolved gas pressure, barometric pressure, and water temperature. Hourly values for these parameters are presented graphically. Dissolved oxygen data are not presented in this report because the quality-control data show that the data have poor precision and high bias. Suggested changes to monitoring procedures for future studies include (1) improved calibration procedures for total dissolved gas and dissolved oxygen to better define accuracy at elevated levels of supersaturation and (2) equipping dissolved oxygen sensors with stirrers because river velocities at the shoreline monitoring stations probably cannot maintain an adequate flow of water across the membrane surface of the dissolved oxygen sensor.

A multiphase flow meter for the on-line determination of the flow rates of oil, water and gas

International Nuclear Information System (INIS)

Roach, G.J.; Watt, J.S.

1997-01-01

Multiphase mixtures of crude oil, formation water and gas are carried in pipelines from oil wells to production facilities. Multiphase flow meters (MFMs) are being developed to determine the flow rates of each component of the heterogeneous mixture in the pipeline. CSIRO Minerals has developed and field tested a gamma-ray MFM for the on-line determination of the flow rates of heterogeneous mixtures of oil, water and gas in pipelines. It consists of two specialised gamma-ray transmission gauges, and pressure and temperature sensors, mounted on the pipeline carrying the full flow of the production stream. The MFM separately measures liquids and gas flow rates, and the volume ratio of water and liquids (water cut). The MFM has been trialled at three offshore production facilities in Australia. In each, the MFM was mounted on the pipeline between the test manifold and the test separator. The multiphase streams from the various wells feeding to the platform were sequentially routed past the MFM. The MFM and test separator outputs were compared using regression analysis. The flow rates of oil, water and gas were each determined to relative errors in the range of 5-10% . The MFM has been in routine use on the West Kingfish platform in the Bass Strait since November 1994. The MFM was recently tested over a wide range of flow conditions at a Texaco flow facility near Houston. Water cut, based on pre-trial calibration, was determined to 2% rms over the range 0-100% water cut. The liquids and gas flow results were interpreted based on slip correlations obtained from comparison of the MFM and Texaco flows. Using these, the relative errors were respectively 6.6% for liquid flow, 6.2% for gas, 8% for oil and 8% for water. The MFM is licensed to Kvaerner FSSL of Aberdeen. Kvaerner will supply the gamma-ray MFM for both platform and subsea use. Technology transfer commenced in December 1996, and Kvaerner completed the manufacture of the first MFM in August 1997

Impacts of Coal Seam Gas (Coal Bed Methane) Extraction on Water Resources in Australia

Science.gov (United States)

Post, David

2017-04-01

While extraction of methane from shale gas deposits has been the principal source of the recent expansion of the industry in the United States, in Australia extraction of methane from coal bed methane deposits (termed 'coal seam gas' in Australia) has been the focus to date. The two sources of methane share many of the same characteristics including the potential requirement for hydraulic fracturing. However, as coal seam gas deposits generally occur at shallower depths than shale gas, the potential impacts of extraction on surface and groundwater resources may be of even greater concern. In Australia, an Independent Expert Scientific Committee (IESC) has been established to provide scientific advice to federal and state government regulators on the impact that coal seam gas and large coal mining developments may have on water resources. This advice is provided to enable decisions to be informed by the best available science about the potential water-related impacts associated with these developments. To support this advice, the Australian Government Department of the Environment has implemented a programme of research termed 'bioregional assessments' to investigate these potential impacts. A bioregional assessment is defined as a scientific analysis of the ecology, hydrology, geology and hydrogeology of a bioregion with explicit assessment of the potential direct, indirect and cumulative impacts of coal seam gas and large coal mining development on water resources. These bioregional assessments are currently being carried out across large portions of eastern Australia underlain by coal reserves. Further details of the programme and results to date can be found at http://www.bioregionalassessments.gov.au. The bioregional assessment programme has modelled the impacts of coal seam gas development on surface and groundwater resources in three regions of eastern Australia, namely the Clarence-Moreton, Gloucester, and Namoi regions. This presentation will discuss the

Direct gas-solid carbonation of serpentinite residues in the absence and presence of water vapor: a feasibility study for carbon dioxide sequestration.

Science.gov (United States)

Veetil, Sanoopkumar Puthiya; Pasquier, Louis-César; Blais, Jean-François; Cecchi, Emmanuelle; Kentish, Sandra; Mercier, Guy

2015-09-01

Mineral carbonation of serpentinite mining residue offers an environmentally secure and permanent storage of carbon dioxide. The strategy of using readily available mining residue for the direct treatment of flue gas could improve the energy demand and economics of CO2 sequestration by avoiding the mineral extraction and separate CO2 capture steps. The present is a laboratory scale study to assess the possibility of CO2 fixation in serpentinite mining residues via direct gas-solid reaction. The degree of carbonation is measured both in the absence and presence of water vapor in a batch reactor. The gas used is a simulated gas mixture reproducing an average cement flue gas CO2 composition of 18 vol.% CO2. The reaction parameters considered are temperature, total gas pressure, time, and concentration of water vapor. In the absence of water vapor, the gas-solid carbonation of serpentinite mining residues is negligible, but the residues removed CO2 from the feed gas possibly due to reversible adsorption. The presence of small amount of water vapor enhances the gas-solid carbonation, but the measured rates are too low for practical application. The maximum CO2 fixation obtained is 0.07 g CO2 when reacting 1 g of residue at 200 °C and 25 barg (pCO2 ≈ 4.7) in a gas mixture containing 18 vol.% CO2 and 10 vol.% water vapor in 1 h. The fixation is likely surface limited and restricted due to poor gas-solid interaction. It was identified that both the relative humidity and carbon dioxide-water vapor ratio have a role in CO2 fixation regardless of the percentage of water vapor.

Economics of residential gas furnaces and water heaters in United States new construction market

OpenAIRE

Lekov, Alex B.

2009-01-01

New single-family home construction represents a significant and important market for the introduction of energy-efficient gas-fired space heating and water-heating equipment. In the new construction market, the choice of furnace and water-heater type is primarily driven by first cost considerations and the availability of power vent and condensing water heaters. Few analysis have been performed to assess the economic impacts of the different combinations of space and water-heating equipment....

Air-water Gas Exchange Rates on a Large Impounded River Measured Using Floating Domes (Poster)

Science.gov (United States)

Mass balance models of dissolved gases in rivers typically serve as the basis for whole-system estimates of greenhouse gas emission rates. An important component of these models is the exchange of dissolved gases between air and water. Controls on gas exchange rates (K) have be...

Studi Numerik Variasi Pemilihan Gas Accumulator Untuk Pencegahan Water Hammer Pada Sistem Perpipaan Sepanjang 1 Kilometer dan Debit Aliran 800 GPM

Directory of Open Access Journals (Sweden)

Anindika Bagus Pradana

2013-09-01

Full Text Available Sistem jaringan perpipaan sangat penting dalam menunjang produksi pada bidang industri. Jaringan perpipaan mengalami beberapa fenomena seperti distribusi fluida dan water hammer. Water hammer sering terjadi di daerah discharge pompa saat pengoperasian dan gagalnya beroperasinya pompa. Water hammer dapat merusak jaringan perpipaan. Fenomena water hammer dapat terjadi hampir di setiap sistem instalasi perpipaan. Fenomena ini mempunyai dampak buruk apabila sistem perpipaan tersebut tidak memperhatikan akibat dari water hammer. Fenomena dalam sistem perpipaan mempunyai dampak negatif dengan selang waktu tertentu, water hammer adalah fenomena dimana dampak yang ditimbulkan terjadi seketika itu juga. Penanggulangan yang tidak tepat terhadap dampak tersebut dapat mengakibatkan instalasi tersebut harus dimatikan (shutdown. Pada simulasi ini digunakan sistem instalasi perpipaan dengan panjang 1 kilometer dan debit aliran 800 gpm.Pada sistem instalasi ini memiliki rangkaian pompa tunggal yang dilengkapi dengan gas accumulator di sisi discharge pompa. Ketika terjadi perubahan flow rate yang menyebabkan pompa beroprasi atau gagal beroprasi akan menimbulkan fenomena water hammer.Penelitian dilakukan secara numerik menggunakan software AFT Impulse 4.0. Water hammer dapat diminimalisi dengan memasang gas accumulator pada daerah dekat discharge pompa. Variasi gas accumulator adalah gas accumulator merk NOK tipe AT 175-20 dengan volume maksimum 20 liter, tipe AT 210-60 dengan volume maksimum 60 liter dan tipe AT 230-120 dengan volume maksimum 100 liter. Hasil yang didapatkan pada simulasi menunjukan pada jarak 4 meter dari rumah pompa masing-masing P max dan P min  untuk sistem perpipaan dengan simulasi proses trip pompa tanpa proteksi water hammer adalah 1729 Kpa dan 381 Kpa, untuk sistem perpipaan dengan gas accumulator volume setting 20 liter adalah 1228 Kpa dan 927 Kpa, untuk sistem perpipaan dengan gas accumulator volume setting 60 liter adalah 1161 Kpa

Polymer growth rate in a wire chamber with oxygen, water, or alcohol gas additives

International Nuclear Information System (INIS)

Boyarski, Adam M.

2009-01-01

The rate of polymer growth on wires was measured in a wire chamber while the chamber was aged initially with helium:isobutane (80:20) gas, and then with either oxygen, water, or alcohol added to the gas. At the completion of the aging process for each gas mixture, the carbon content on the wires was measured in a scanning electron microscope/energy dispersive X-ray (SEM/EDX) instrument. The same physical wires were used in all the gas mixtures, allowing measurement of polymer build-up or polymer depletion by each gas additive. It is found that the rate of polymer growth is not changed by the presence of oxygen, water, or alcohol. Conjecture that oxygen reduces breakdown by removing polymer deposits on field wires is negated by these measurements. Instead, it appears that the reduced breakdown is due to lower resistance in the polymer from oxygen ions being transported into the polymer. It is also observed that field wires bombarded by the electrons in the SEM and then placed back into the chamber show an abundance of single electrons being emitted, indicating that electron charge is trapped in the polymer layer and that a high electric field is necessary to remove the charge.

Corrosion of API 5L B and X52 in crude oil/water/gas mixtures

Energy Technology Data Exchange (ETDEWEB)

Perdomo, J.J.; Gonzalez, J.J.; Viloria, A.; De Veer, H.; De Abreu, Y.

2000-02-01

Laboratory and field tests were conducted to evaluate the corrosion behavior of API 5L grade B and X52 steels using Furrial's crude oil in the presence of water and gas containing carbon dioxide (CO{sub 2}) and hydrogen sulfide (H{sub 2}S). The results suggest that the corrosiveness of this crude oil/water/gas mixture is not detrimental to either steel. However, pitting corrosion was observed. The low general corrosion rates measured were attributed to the natural inhibiting properties of the crude oil.

Removal of calcium and magnesium ions from shale gas flowback water by chemically activated zeolite.

Science.gov (United States)

Chang, Haiqing; Liu, Teng; He, Qiping; Li, Duo; Crittenden, John; Liu, Baicang

2017-07-01

Shale gas has become a new sweet spot of global oil and gas exploration, and the large amount of flowback water produced during shale gas extraction is attracting increased attention. Internal recycling of flowback water for future hydraulic fracturing is currently the most effective, and it is necessary to decrease the content of divalent cations for eliminating scaling and maintaining effectiveness of friction reducer. Zeolite has been widely used as a sorbent to remove cations from wastewater. This work was carried out to investigate the effects of zeolite type, zeolite form, activation chemical, activation condition, and sorption condition on removal of Ca 2+ and Mg 2+ from shale gas flowback water. Results showed that low removal of Ca 2+ and Mg 2+ was found for raw zeolite 4A and zeolite 13X, and the efficiency of the mixture of both zeolites was slightly higher. Compared with the raw zeolites, the zeolites after activation using NaOH and NaCl greatly improved the sorption performance, and there was no significant difference between dynamic activation and static activation. Dynamic sorption outperformed static sorption, the difference exceeding 40% and 7-70% for removal of Ca 2+ and Mg 2+ , respectively. Moreover, powdered zeolites outperformed granulated zeolites in divalent cation removal.

Gas and water flow in the Callovo-Oxfordian argillite

International Nuclear Information System (INIS)

Harrington, J.F.; Noy, D.J.; Talandier, J.

2010-01-01

Document available in extended abstract form only. Understanding the impact and fate of this gas phase is of significant importance within performance assessment and for the accurate long-term prediction of repository evolution. This paper describes the initial results from an ongoing experimental study to measure the two-phase flow behaviour of the Callovo-Oxfordian argillite from the Bure underground research laboratory (URL) in France, using the custom-designed BGS permeameter. The primary objectives of the study are to measure: (i) the hydraulic conductivity and intrinsic permeability; (ii) the capillary displacement pressure; (iii) the effective gas permeability and relative permeability to gas for a range of conditions; and (iv) the post-test gas saturation. During testing, the specimen, a cylinder of 54 mm thickness, cut perpendicular to bedding, is subject to an isotropic confining stress, with fluids injected through the base of the specimen. A novel feature of the apparatus is the use of porous annular guard-ring filters around the inflow and outflow filters. The pressures in these two 'guard-rings' can be independently monitored to provide data on the distribution of pressure and anisotropy of the sample. Initial measurements, performed on a specimen orientation perpendicular to the bedding plane, have been divided into three components: re-saturation and consolidation; hydraulic properties; gas behaviour. During the initial period of equilibration, re-saturation of the sample were noted. Net volume change due to re-saturation closely agreed with pre-test geotechnical measurements of water saturation, suggesting the bulk of the gas phase was resident in non-dilatant pores and that the specimen was fully saturated at the onset of testing. A two step consolidation test was then performed with confining pressure raised to 11 MPa for 5 days and then to 12.5 MPa for a further 8 days. Values for drained bulk modulus based on the total volume of fluid

The Pennsylvania Experience with Hydraulic Fracturing for Shale Gas Development: Relatively Infrequent Water Quality Incidents with Lots of Public Attention

Science.gov (United States)

Brantley, S. L.; Li, Z.; Yoxtheimer, D.; Vidic, R.

2015-12-01

New techniques of hydraulic fracturing - "fracking" - have changed the United States over the last 10 years into a leading producer of natural gas extraction from shale. The first such gas well in Pennsylvania was drilled and completed using high-volume hydraulic fracturing in 2004. By late 2014, more than 8500 of these gas wells had been drilled in the Marcellus Shale gas field in Pennsylvania alone. Almost 1000 public complaints about groundwater quality were logged by the PA Department of Environmental Protection (PA DEP) between 2008 and 2012. Only a fraction of these were attributed to unconventional gas development. The most common problem was gas migration into drinking water, but contamination incidents also included spills, seepage, or leaks of fracking fluids, brine salts, or very occasionally, radioactive species. Many problems of gas migration were from a few counties in the northeastern part of the state. However, sometimes one gas well contaminated multiple water wells. For example, one gas well was reported by the state regulator to have contaminated 18 water wells with methane near Dimock PA. It can be argued that such problems at a relatively small fraction of gas wells initiated pockets of pushback against fracking worldwide. This resistance to fracking has grown even though fracking has been in use in the U.S.A. since the 1940s. We have worked as part of an NSF-funded project (the Shale Network) to share water quality data and publish it online using the CUAHSI Hydrologic Information System. Sharing data has led to collaborative investigation of specific contamination incidents to understand how problems can occur, and to efforts to quantify the frequency of impacts. The Shale Network efforts have also highlighted the need for more transparency with water quality data in the arena related to the energy-water nexus. As more data are released, new techniques of data analysis will allow better understanding of how to tune best practices to be

Tritium stripping by a catalytic exchange stripper

International Nuclear Information System (INIS)

Heung, L.K.; Gibson, G.W.; Ortman, M.S.

1991-01-01

A catalytic exchange process for stripping elemental tritium from gas streams has been demonstrated. The process uses a catalyzed isotopic exchange reaction between tritium in the gas phase and protium or deuterium in the solid phase on alumina. The reaction is catalyzed by platinum deposited on the alumina. The process has been tested with both tritium and deuterium. Decontamination factors (ration of inlet and outlet tritium concentrations) as high as 1000 have been achieved, depending on inlet concentration. The test results and some demonstrated applications are presented

Application of carbon isotopes to detect seepage out of coalbed natural gas produced water impoundments

International Nuclear Information System (INIS)

Sharma, Shikha; Baggett, Joshua K.

2011-01-01

Highlights: → Coalbed natural gas extraction results in large amount of produced water. → Risk of deterioration of ambient water quality. → Carbon isotope natural tracer for detecting seepage from produced water impoundments. - Abstract: Coalbed natural gas (CBNG) production from coal bed aquifers requires large volumes of produced water to be pumped from the subsurface. The produced water ranges from high quality that meets state and federal drinking water standards to low quality due to increased salinity and/or sodicity. The Powder River Basin of northeastern Wyoming is a major coalbed natural gas producing region, where water quality generally decreases moving from the southeastern portion of the basin towards the center. Most produced water in Wyoming is disposed into impoundments and other surface drainages, where it may infiltrate into shallow groundwater. Groundwater degradation caused by infiltration of CBNG produced water holding impoundments into arid, soluble salt-rich soils is an issue of immense importance because groundwater is a major source for stock water, irrigation, and drinking water for many small communities in these areas. This study examines the potential of using stable C isotope signatures of dissolved inorganic C (δ 13 C DIC ) to track the fate of CBNG produced water after it is discharged into the impoundments. Other geochemical proxies like the major cations and major anions were used in conjunction with field water quality measurements to understand the geochemical differences between CBNG produced waters and ambient waters in the study area. Samples were collected from the CBNG discharge outfalls, produced water holding impoundments, and monitoring wells from different parts of the Powder River Basin and analyzed for δ 13 C DIC . The CBNG produced waters from outfalls and impoundments have positive δ 13 C DIC values that fall within the range of +12 per mille to +22 per mille, distinct from the ambient regional surface and

Produced water ponds are an important source of aromatics and alcohols in Rocky Mountain oil and gas basins