WorldWideScience

Sample records for stream produced water

  1. Methodology to produce a water and energy stream map (WESM in the South African manufacturing industry

    Directory of Open Access Journals (Sweden)

    Davies, Edward

    2016-11-01

    Full Text Available The increasing demand for water and energy in South Africa, and the capacity constraints and restrictions of both resources, have led to a rapid increase in their cost. The manufacturing industry remains South Africa’s third-largest consumer of water and second- largest consumer of national energy. The improvement of water and energy efficiency is becoming an increasingly important theme for both organisational success and national economic sustainability. This paper presents the ‘lean based water and energy stream mapping framework’ developed for the manufacturing industry, with the specific objective of decreasing its water and energy intensity. As with the traditional value stream mapping tool, the water and energy stream mapping focuses on eliminating water- and energy-specific wastes within a process. Water and energy waste categories that will be used in conjunction with the framework will also be discussed. The key objective of this paper is to detail the process of creating the water and energy stream mapping, and the statistical forecasting methodology used to develop the baseline water and energy demand data. The outcome of the implementation of the framework is the future state water and energy stream mapping, which is effectively a blueprint for increased water and energy efficiency within a studied process.

  2. Stream mesocosm response sensitivities to simulated ion stress in produced waters from resource extraction activities

    Science.gov (United States)

    To increase the ecological relevance of laboratory exposures intent on determining species sensitivity to ion stress from resource extraction activities we have conducted several stream mesocosm dosing studies that pair single-species and community-level responses in-situ and all...

  3. Discharges of produced waters from oil and gas extraction via wastewater treatment plants are sources of disinfection by-products to receiving streams

    Science.gov (United States)

    Hladik, Michelle; Focazio, Michael J.; Engle, Mark

    2014-01-01

    Fluids co-produced with oil and gas production (produced waters) are often brines that contain elevated concentrations of bromide. Bromide is an important precursor of several toxic disinfection by-products (DBPs) and the treatment of produced water may lead to more brominated DBPs. To determine if wastewater treatment plants that accept produced waters discharge greater amounts of brominated DBPs, water samples were collected in Pennsylvania from four sites along a large river including an upstream site, a site below a publicly owned wastewater treatment plant (POTW) outfall (does not accept produced water), a site below an oil and gas commercial wastewater treatment plant (CWT) outfall, and downstream of the POTW and CWT. Of 29 DBPs analyzed, the site at the POTW outfall had the highest number detected (six) ranging in concentration from 0.01 to 0.09 μg L− 1 with a similar mixture of DBPs that have been detected at POTW outfalls elsewhere in the United States. The DBP profile at the CWT outfall was much different, although only two DBPs, dibromochloronitromethane (DBCNM) and chloroform, were detected, DBCNM was found at relatively high concentrations (up to 8.5 μg L− 1). The water at the CWT outfall also had a mixture of inorganic and organic precursors including elevated concentrations of bromide (75 mg L− 1) and other organic DBP precursors (phenol at 15 μg L− 1). To corroborate these DBP results, samples were collected in Pennsylvania from additional POTW and CWT outfalls that accept produced waters. The additional CWT also had high concentrations of DBCNM (3.1 μg L− 1) while the POTWs that accept produced waters had elevated numbers (up to 15) and concentrations of DBPs, especially brominated and iodinated THMs (up to 12 μg L− 1 total THM concentration). Therefore, produced water brines that have been disinfected are potential sources of DBPs along with DBP precursors to streams wherever these wastewaters are discharged.

  4. Heavy-water extraction from non-electrolytic hydrogen streams

    International Nuclear Information System (INIS)

    LeRoy, R.L.; Hammerli, M.; Butler, J.P.

    1981-01-01

    Heavy water may be produced from non-electrolytic hydrogen streams using a combined electrolysis and catalytic exchange process. The method comprises contacting feed water in a catalyst column with hydrogen gas originating partly from a non-electrolytic hydrogen stream and partly from an electrolytic hydrogen stream, so as to enrich the feed water with the deuterium extracted from both the non-electrolytic and electrolytic hydrogen gas, and passing the deuterium water to an electrolyser wherein the electrolytic hydrogen gas is generated and then fed through the catalyst column. (L.L.)

  5. Relation between Streaming Potential and Streaming Electrification Generated by Streaming of Water through a Sandwich-type Cell

    OpenAIRE

    Maruyama, Kazunori; Nikaido, Mitsuru; Hara, Yoshinori; Tanizaki, Yoshie

    2012-01-01

    Both streaming potential and accumulated charge of water flowed out were measured simultaneously using a sandwich-type cell. The voltages generated in divided sections along flow direction satisfied additivity. The sign of streaming potential agreed with that of streaming electrification. The relation between streaming potential and streaming electrification was explained from a viewpoint of electrical double layer in glass-water interface.

  6. Determination of water quality index and portability of Iguedo stream ...

    African Journals Online (AJOL)

    Determination of water quality index and portability of Iguedo stream in Edo ... has been found functional in assessing the water quality of this stream based on the ... Key words: Water quality index, physicochemical parameters, Iguedo Stream.

  7. Tekna's produced water conference 2005

    International Nuclear Information System (INIS)

    2005-01-01

    The conference has 22 presentations discussing topics on discharge reduction, produced water quality, produced water re-injection, chemicals particularly environmentally friendly ones, separation technology, reservoir souring, total water management systems, pollution, oil in water problems and platform operation. Various field tests and experiences particularly from the offshore petroleum sector are presented (tk)

  8. Produced water - composition and analysis

    International Nuclear Information System (INIS)

    Kvernheim, Arne Lund

    1998-01-01

    Produced water can be defined as ''High volume waste-water separated from oil and gas that is produced from subsurface formations''. The water contains aliphatic and aromatic hydrocarbons, particulate matter and soluble salts as well as elements originating from formations and from sea water injections. Residues of chemicals may also be present. The accepted North Sea discharge limit is 40 ppm. In this presentation the focus will be on the chemical composition of produced water and on the challenges involved in developing and implementing analytical methods. The focus will also be on the development of a new oil-in-water analytical method as a replacement for the Freon method. 7 refs., 1 tab

  9. Producing deep-water hydrocarbons

    International Nuclear Information System (INIS)

    Pilenko, Thierry

    2011-01-01

    Several studies relate the history and progress made in offshore production from oil and gas fields in relation to reserves and the techniques for producing oil offshore. The intention herein is not to review these studies but rather to argue that the activities of prospecting and producing deep-water oil and gas call for a combination of technology and project management and, above all, of devotion and innovation. Without this sense of commitment motivating men and women in this industry, the human adventure of deep-water production would never have taken place

  10. Membrane crystallization for recovery of salts from produced water

    DEFF Research Database (Denmark)

    Quist-Jensen, Cejna Anna; Jensen, Henriette Casper; Ali, Aamer

    Membrane Crystallization (MCr) is a novel technology able to recover freshwater and high-purity salts from complex solutions and therefore, is suggested for a better exploitation of wastewater streams. Unlike other membrane processes, MCr is not limited by high concentrations and, therefore, the ......, the membrane maintained its hydrophobic nature despite that produced water contained oil residues. Conductivity and HPLC was utilized to analyze the quality of the permeate stream......., the solutions can be treated to achieve saturation level. Hereby different salts can be precipitated and directly recovered from various streams. In this study, it is shown that MCr is able to treat produced water by producing clean water and simultaneously NaCl crystals. The recovered crystals exhibited high...

  11. Identify the dominant variables to predict stream water temperature

    Science.gov (United States)

    Chien, H.; Flagler, J.

    2016-12-01

    Stream water temperature is a critical variable controlling water quality and the health of aquatic ecosystems. Accurate prediction of water temperature and the assessment of the impacts of environmental variables on water temperature variation are critical for water resources management, particularly in the context of water quality and aquatic ecosystem sustainability. The objective of this study is to measure stream water temperature and air temperature and to examine the importance of streamflow on stream water temperature prediction. The measured stream water temperature and air temperature will be used to test two hypotheses: 1) streamflow is a relatively more important factor than air temperature in regulating water temperature, and 2) by combining air temperature and streamflow data stream water temperature can be more accurately estimated. Water and air temperature data loggers are placed at two USGS stream gauge stations #01362357and #01362370, located in the upper Esopus Creek watershed in Phonecia, NY. The ARIMA (autoregressive integrated moving average) time series model is used to analyze the measured water temperature data, identify the dominant environmental variables, and predict the water temperature with identified dominant variable. The preliminary results show that streamflow is not a significant variable in predicting stream water temperature at both USGS gauge stations. Daily mean air temperature is sufficient to predict stream water temperature at this site scale.

  12. In-stream Physical Heterogeneity, Rainfall Aided Flushing, and Discharge on Stream Water Quality.

    Science.gov (United States)

    Gomes, Pattiyage I A; Wai, Onyx W H

    2015-08-01

    Implications of instream physical heterogeneity, rainfall-aided flushing, and stream discharge on water quality control have been investigated in a headwater stream of a climatic region that has contrasting dry and wet seasons. Dry (low flow) season's physical heterogeneity showed a positive correlation with good water quality. However, in the wet season, physical heterogeneity showed minor or no significance on water quality variations. Furthermore, physical heterogeneity appeared to be more complementary with good water quality subsequent to rainfall events. In many cases stream discharge was a reason for poor water quality. For the dry season, graywater inputs to the stream could be held responsible. In the wet season, it was probably the result of catchment level disturbances (e.g., regulation of ephemeral freshwater paths). Overall, this study revealed the importance of catchment-based approaches on water quality improvement in tandem with in-stream approaches framed on a temporal scale.

  13. Contaminated Stream Water as Source for Escherichia coli O157 Illness in Children.

    Science.gov (United States)

    Probert, William S; Miller, Glen M; Ledin, Katya E

    2017-07-01

    In May 2016, an outbreak of Shiga toxin-producing Escherichia coli O157 infections occurred among children who had played in a stream flowing through a park. Analysis of E. coli isolates from the patients, stream water, and deer and coyote scat showed that feces from deer were the most likely source of contamination.

  14. How and Why Does Stream Water Temperature Vary at Small Spatial Scales in a Headwater Stream?

    Science.gov (United States)

    Morgan, J. C.; Gannon, J. P.; Kelleher, C.

    2017-12-01

    The temperature of stream water is controlled by climatic variables, runoff/baseflow generation, and hyporheic exchange. Hydrologic conditions such as gaining/losing reaches and sources of inflow can vary dramatically along a stream on a small spatial scale. In this work, we attempt to discern the extent that the factors of air temperature, groundwater inflow, and precipitation influence stream temperature at small spatial scales along the length of a stream. To address this question, we measured stream temperature along the perennial stream network in a 43 ha catchment with a complex land use history in Cullowhee, NC. Two water temperature sensors were placed along the stream network on opposite sides of the stream at 100-meter intervals and at several locations of interest (i.e. stream junctions). The forty total sensors recorded the temperature every 10 minutes for one month in the spring and one month in the summer. A subset of sampling locations where stream temperature was consistent or varied from one side of the stream to the other were explored with a thermal imaging camera to obtain a more detailed representation of the spatial variation in temperature at those sites. These thermal surveys were compared with descriptions of the contributing area at the sample sites in an effort to discern specific causes of differing flow paths. Preliminary results suggest that on some branches of the stream stormflow has less influence than regular hyporheic exchange, while other tributaries can change dramatically with stormflow conditions. We anticipate this work will lead to a better understanding of temperature patterns in stream water networks. A better understanding of the importance of small-scale differences in flow paths to water temperature may be able to inform watershed management decisions in the future.

  15. Heavy metal contamination in stream water and sediments of gold ...

    African Journals Online (AJOL)

    This study assessed the seasonal variation in heavy metal contamination of stream water and sediments in the gold mining area of Atakunmosa West local Government, Osun State, Nigeria. Twelve villages of prominence in illegal gold mining were selected for the study covering dry and wet seasons of 2012. Stream water ...

  16. Treatment of offshore produced water - an effective membrane process

    International Nuclear Information System (INIS)

    Taylor, J.; Larson, R.; Scherer, B.

    1991-01-01

    The conference paper describes a new membrane technology being extremely effective in separating hydrocarbons from water streams. The membrane is composed of a completely natural cellulose and is resistant to all hydrocarbons and organic solvents, and preliminary tests have shown that it is resistant to fouling by oily molecules and calcium scaling. The membrane system being designed shows good potential for the treatment of offshore produced water with a hydrocarbon content well within present and emerging standards. 6 refs., 8 figs., 3 tabs

  17. Control of microbially generated hydrogen sulfide in produced waters

    Energy Technology Data Exchange (ETDEWEB)

    Burger, E.D.; Vance, I.; Gammack, G.F.; Duncan, S.E.

    1995-12-31

    Production of hydrogen sulfide in produced waters due to the activity of sulfate-reducing bacteria (SRB) is a potentially serious problem. The hydrogen sulfide is not only a safety and environmental concern, it also contributes to corrosion, solids formation, a reduction in produced oil and gas values, and limitations on water discharge. Waters produced from seawater-flooded reservoirs typically contain all of the nutrients required to support SRB metabolism. Surface processing facilities provide a favorable environment in which SRB flourish, converting water-borne nutrients into biomass and H{sub 2}S. This paper will present results from a field trial in which a new technology for the biochemical control of SRB metabolism was successfully applied. A slip stream of water downstream of separators on a produced water handling facility was routed through a bioreactor in a side-steam device where microbial growth was allowed to develop fully. This slip stream was then treated with slug doses of two forms of a proprietary, nonbiocidal metabolic modifier. Results indicated that H{sub 2}S production was halted almost immediately and that the residual effect of the treatment lasted for well over one week.

  18. Investigation of plasma stream collision produced by thin films irradiated by powerful pulsed electron beam

    International Nuclear Information System (INIS)

    Efremov, V P; Demidov, B A; Ivkin, M V; Mescheryakov, A N; Petrov, V A; Potapenko, A I

    2006-01-01

    Collision of fast plasma streams in vacuum is investigated. Plasma streams were produced by irradiation of thin foils with a powerful pulsed electron beam. Interaction of the plasma flows was studied by using frame and streak cameras. One-dimensional numerical simulation was carried out. Application of this method for porous ICF targets and high-energy physics is discussed

  19. The role of headwater streams in downstream water quality

    Science.gov (United States)

    Alexander, R.B.; Boyer, E.W.; Smith, R.A.; Schwarz, G.E.; Moore, R.B.

    2007-01-01

    Knowledge of headwater influences on the water-quality and flow conditions of downstream waters is essential to water-resource management at all governmental levels; this includes recent court decisions on the jurisdiction of the Federal Clean Water Act (CWA) over upland areas that contribute to larger downstream water bodies. We review current watershed research and use a water-quality model to investigate headwater influences on downstream receiving waters. Our evaluations demonstrate the intrinsic connections of headwaters to landscape processes and downstream waters through their influence on the supply, transport, and fate of water and solutes in watersheds. Hydrological processes in headwater catchments control the recharge of subsurface water stores, flow paths, and residence times of water throughout landscapes. The dynamic coupling of hydrological and biogeochemical processes in upland streams further controls the chemical form, timing, and longitudinal distances of solute transport to downstream waters. We apply the spatially explicit, mass-balance watershed model SPARROW to consider transport and transformations of water and nutrients throughout stream networks in the northeastern United States. We simulate fluxes of nitrogen, a primary nutrient that is a water-quality concern for acidification of streams and lakes and eutrophication of coastal waters, and refine the model structure to include literature observations of nitrogen removal in streams and lakes. We quantify nitrogen transport from headwaters to downstream navigable waters, where headwaters are defined within the model as first-order, perennial streams that include flow and nitrogen contributions from smaller, intermittent and ephemeral streams. We find that first-order headwaters contribute approximately 70% of the mean-annual water volume and 65% of the nitrogen flux in second-order streams. Their contributions to mean water volume and nitrogen flux decline only marginally to about 55% and

  20. Effect of boiling regime on melt stream breakup in water

    International Nuclear Information System (INIS)

    Spencer, B.W.; Gabor, J.D.; Cassulo, J.C.

    1986-01-01

    A study has been performed examining the breakup and mixing behavior of an initially coherent stream of high-density melt as it flows downward through water. This work has application to the quenching of molten core materials as they drain downward during a postulated severe reactor accident. The study has included examination of various models of breakup distances based upon interfacial instabilities dominated either by liquid-liquid contact or by liquid-vapor contact. A series of experiments was performed to provide a data base for assessment of the various modeling approaches. The experiments involved Wood's metal (T/sub m/ = 73 0 C, rho = 9.2 g/cm 3 , d/sub j/ = 20 mm) poured into a deep pool of water. The temperature of the water and wood's metal were varied to span the range from single-phase, liquid-liquid contact to the film boiling regime. Experiment results showed that breakup occurred largely as a result of the spreading and entrainment from the leading edge of the jet. However, for streams of sufficient lengths a breakup length could be discerned at which there was no longer a coherent central core of the jet to feed the leading edge region. The erosion of the vertical trailing column is by Kelvin-Helmoltz instabilities and related disengagement of droplets from the jet into the surrounding fluid. For conditions of liquid-liquid contact, the breakup length has been found to be about 20 jet diameters; when substantial vapor is produced at the interface due to heat transfer from the jet to the water, the breakup distance was found to range to as high as 50 jet diameters. The former values are close to the analytical prediction of Taylor, whereas the latter values are better predicted by the model of Epstein and Fauske

  1. Physico-chemical characteristics of water sample from Aiba Stream ...

    African Journals Online (AJOL)

    This study aimed at assessing the effectiveness of solar distillation in purification of water. The water sample collected from Aiba stream was subjected to double slope solar water distillation unit. The physico- chemical characteristics of the raw sample and the distillate were determined using standard methods. The.

  2. Health risk assessment for radium discharged in produced waters

    International Nuclear Information System (INIS)

    Hamilton, L.D.; Meinhold, A.F.; Nagy, J.

    1991-01-01

    Produced water generated during the production of oil and gas can contain enhanced levels of radium. This naturally occurring radioactive material (NORM) is discharged into freshwater streams, estuarine, coastal and outer continental shelf waters. Large volumes of produced waters are discharged to coastal waters along the Gulf Coast of Louisiana. The Gulf of Mexico is an important producer of fish and shellfish, and there is concern that radium discharged to coastal Louisiana could contaminate fish and shellfish used by people for food, and present a significant increase in cancer risk. This paper describes a screening-level assessment of the potential cancer risks posed by radium discharged to coastal Louisiana in oil-field produced waters. This screening analysis was performed to determine if a more comprehensive and realistic assessment is necessary, and because of the conservative assumptions embedded in the analysis overestimates the risk associated with the discharge of radium in produced waters. Two isotopes of radium (Ra-226 and Ra-228) are the radionuclides of most concern in produced water in terms of potential human health effects

  3. Modification of semiconductor materials using laser-produced ion streams additionally accelerated in the electric fields

    International Nuclear Information System (INIS)

    Rosinski, M.; Badziak, B.; Parys, P.; Wolowski, J.; Pisarek, M.

    2009-01-01

    The laser-produced ion stream may be attractive for direct ultra-low-energy ion implantation in thin layer of semiconductor for modification of electrical and optical properties of semiconductor devices. Application of electrostatic fields for acceleration and formation of laser-generated ion stream enables to control the ion stream parameters in broad energy and current density ranges. It also permits to remove the useless laser-produced ions from the ion stream designed for implantation. For acceleration of ions produced with the use of a low fluence repetitive laser system (Nd:glass: 2 Hz, pulse duration: 3.5 ns, pulse energy:∼0.5 J, power density: 10 10 W/cm 2 ) in IPPLM the special electrostatic system has been prepared. The laser-produced ions passing through the diaphragm (a ring-shaped slit in the HV box) have been accelerated in the system of electrodes. The accelerating voltage up to 40 kV, the distance of the diaphragm from the target, the diaphragm diameter and the gap width were changed for choosing the desired parameters (namely the energy band of the implanted ions) of the ion stream. The characteristics of laser-produced Ge ion streams were determined with the use of precise ion diagnostic methods, namely: electrostatic ion energy analyser and various ion collectors. The laser-produced and post-accelerated Ge ions have been used for implantation into semiconductor materials for nanocrystal fabrication. The characteristics of implanted samples were measured using AES

  4. Produced water volumes and management practices in the United States.

    Energy Technology Data Exchange (ETDEWEB)

    Clark, C. E.; Veil, J. A. (Environmental Science Division)

    2009-09-01

    Produced water volume generation and management in the United States are not well characterized at a national level. The U.S. Department of Energy (DOE) asked Argonne National Laboratory to compile data on produced water associated with oil and gas production to better understand the production volumes and management of this water. The purpose of this report is to improve understanding of produced water by providing detailed information on the volume of produced water generated in the United States and the ways in which produced water is disposed or reused. As the demand for fresh water resources increases, with no concomitant increase in surface or ground water supplies, alternate water sources, like produced water, may play an important role. Produced water is water from underground formations that is brought to the surface during oil or gas production. Because the water has been in contact with hydrocarbon-bearing formations, it contains some of the chemical characteristics of the formations and the hydrocarbons. It may include water from the reservoir, water previously injected into the formation, and any chemicals added during the production processes. The physical and chemical properties of produced water vary considerably depending on the geographic location of the field, the geologic formation, and the type of hydrocarbon product being produced. Produced water properties and volume also vary throughout the lifetime of a reservoir. Produced water is the largest volume by-product or waste stream associated with oil and gas exploration and production. Previous national produced water volume estimates are in the range of 15 to 20 billion barrels (bbl; 1 bbl = 42 U.S. gallons) generated each year in the United States (API 1988, 2000; Veil et al. 2004). However, the details on generation and management of produced water are not well understood on a national scale. Argonne National Laboratory developed detailed national-level information on the volume of produced

  5. Produced water radionuclide hazard/risk assessment, Phase 1

    Energy Technology Data Exchange (ETDEWEB)

    Hamilton, L.D.; Meinhold, A.F.; Nagy, J.

    1991-06-01

    Petroleum production may be accompanied by the production of saline water, called produced water.'' Produced water discharged into freshwater streams, estuaries, coastal and outer continental shelf waters can contained enhanced levels of radium isotopes. This document reports on the first phase of a study to estimate the risk to human health and the environment from radium discharged in produced water. The study involved five major steps: (1) evaluate the usefulness of available produced water outfall data for developing estimates of radium environmental concentrations; (2) review the literature on the bioaccumulation of radium by aquatic organism; (3) review the literature on the effects of radiation on aquatic organisms; (4) review the information available concerning the human health risks associated with exposure to Ra-226 and Ra-228 and (5) perform a conservative, screening-level assessment of the health and environmental risks posed by Ra-226 and Ra-228 discharged in produced waters. A screening-level analysis was performed to determine whether radium discharged to coastal Louisiana in produced waters presents potential health or environmental risks requiring further study. This conservative assessment suggested that no detectable impact on populations of fish, molluscs or crustaceans from radium discharged in produced waters is likely. The analysis also suggested that there is a potential for risk were an individual to ingest a large amount of seafood harvested near a produced water discharge point over a lifetime. The number of excess cancers predicted per year under a conservative scenario is comparable to those expected to result from background concentrations of radium.

  6. Produced water radionuclide hazard/risk assessment, Phase 1

    Energy Technology Data Exchange (ETDEWEB)

    Hamilton, L.D.; Meinhold, A.F.; Nagy, J.

    1991-06-01

    Petroleum production may be accompanied by the production of saline water, called ``produced water.`` Produced water discharged into freshwater streams, estuaries, coastal and outer continental shelf waters can contained enhanced levels of radium isotopes. This document reports on the first phase of a study to estimate the risk to human health and the environment from radium discharged in produced water. The study involved five major steps: (1) evaluate the usefulness of available produced water outfall data for developing estimates of radium environmental concentrations; (2) review the literature on the bioaccumulation of radium by aquatic organism; (3) review the literature on the effects of radiation on aquatic organisms; (4) review the information available concerning the human health risks associated with exposure to Ra-226 and Ra-228 and (5) perform a conservative, screening-level assessment of the health and environmental risks posed by Ra-226 and Ra-228 discharged in produced waters. A screening-level analysis was performed to determine whether radium discharged to coastal Louisiana in produced waters presents potential health or environmental risks requiring further study. This conservative assessment suggested that no detectable impact on populations of fish, molluscs or crustaceans from radium discharged in produced waters is likely. The analysis also suggested that there is a potential for risk were an individual to ingest a large amount of seafood harvested near a produced water discharge point over a lifetime. The number of excess cancers predicted per year under a conservative scenario is comparable to those expected to result from background concentrations of radium.

  7. Produced water radionuclide hazard/risk assessment, Phase 1

    International Nuclear Information System (INIS)

    Hamilton, L.D.; Meinhold, A.F.; Nagy, J.

    1991-06-01

    Petroleum production may be accompanied by the production of saline water, called ''produced water.'' Produced water discharged into freshwater streams, estuaries, coastal and outer continental shelf waters can contained enhanced levels of radium isotopes. This document reports on the first phase of a study to estimate the risk to human health and the environment from radium discharged in produced water. The study involved five major steps: (1) evaluate the usefulness of available produced water outfall data for developing estimates of radium environmental concentrations; (2) review the literature on the bioaccumulation of radium by aquatic organism; (3) review the literature on the effects of radiation on aquatic organisms; (4) review the information available concerning the human health risks associated with exposure to Ra-226 and Ra-228 and (5) perform a conservative, screening-level assessment of the health and environmental risks posed by Ra-226 and Ra-228 discharged in produced waters. A screening-level analysis was performed to determine whether radium discharged to coastal Louisiana in produced waters presents potential health or environmental risks requiring further study. This conservative assessment suggested that no detectable impact on populations of fish, molluscs or crustaceans from radium discharged in produced waters is likely. The analysis also suggested that there is a potential for risk were an individual to ingest a large amount of seafood harvested near a produced water discharge point over a lifetime. The number of excess cancers predicted per year under a conservative scenario is comparable to those expected to result from background concentrations of radium

  8. Produced Water Management and Beneficial Use

    International Nuclear Information System (INIS)

    Brown, Terry; Frost, Carol; Hayes, Thomas; Heath, Leo; Johnson, Drew; Lopez, David; Saffer, Demian; Urynowicz, Michael; Wheaton, John; Zoback, Mark

    2007-01-01

    Large quantities of water are associated with the production of coalbed methane (CBM) in the Powder River Basin (PRB) of Wyoming. The chemistry of co-produced water often makes it unsuitable for subsequent uses such as irrigated agriculture. However, co-produced waters have substantial potential for a variety of beneficial uses. Achieving this potential requires the development of appropriate water management strategies. There are several unique characteristics of co-produced water that make development of such management strategies a challenge. The production of CBM water follows an inverse pattern compared to traditional wells. CBM wells need to maintain low reservoir pressures to promote gas production. This need renders the reinjection of co-produced waters counterproductive. The unique water chemistry of co-produced water can reduce soil permeability, making surface disposal difficult. Unlike traditional petroleum operations where co-produced water is an undesirable by-product, co-produced water in the PRB often is potable, making it a highly valued resource in arid western states. This research project developed and evaluated a number of water management options potentially available to CBM operators. These options, which focus on cost-effective and environmentally-sound practices, fall into five topic areas: Minimization of Produced Water, Surface Disposal, Beneficial Use, Disposal by Injection and Water Treatment. The research project was managed by the Colorado Energy Research Institute (CERI) at the Colorado School of Mines (CSM) and involved personnel located at CERI, CSM, Stanford University, Pennsylvania State University, the University of Wyoming, the Argonne National Laboratory, the Gas Technology Institute, the Montana Bureau of Mining and Geology and PVES Inc., a private firm

  9. Produced Water Management and Beneficial Use

    Energy Technology Data Exchange (ETDEWEB)

    Terry Brown; Carol Frost; Thomas Hayes; Leo Heath; Drew Johnson; David Lopez; Demian Saffer; Michael Urynowicz; John Wheaton; Mark Zoback

    2007-10-31

    Large quantities of water are associated with the production of coalbed methane (CBM) in the Powder River Basin (PRB) of Wyoming. The chemistry of co-produced water often makes it unsuitable for subsequent uses such as irrigated agriculture. However, co-produced waters have substantial potential for a variety of beneficial uses. Achieving this potential requires the development of appropriate water management strategies. There are several unique characteristics of co-produced water that make development of such management strategies a challenge. The production of CBM water follows an inverse pattern compared to traditional wells. CBM wells need to maintain low reservoir pressures to promote gas production. This need renders the reinjection of co-produced waters counterproductive. The unique water chemistry of co-produced water can reduce soil permeability, making surface disposal difficult. Unlike traditional petroleum operations where co-produced water is an undesirable by-product, co-produced water in the PRB often is potable, making it a highly valued resource in arid western states. This research project developed and evaluated a number of water management options potentially available to CBM operators. These options, which focus on cost-effective and environmentally-sound practices, fall into five topic areas: Minimization of Produced Water, Surface Disposal, Beneficial Use, Disposal by Injection and Water Treatment. The research project was managed by the Colorado Energy Research Institute (CERI) at the Colorado School of Mines (CSM) and involved personnel located at CERI, CSM, Stanford University, Pennsylvania State University, the University of Wyoming, the Argonne National Laboratory, the Gas Technology Institute, the Montana Bureau of Mining and Geology and PVES Inc., a private firm.

  10. Technique for producing a continuous interference-free stream of Argon-41 in air

    International Nuclear Information System (INIS)

    Tseng, T.-T.; Jester, W.A.

    1984-01-01

    A monitoring system was developed for the detection of 131 I in the presence of orders of magnitude higher concentrations of radioactive noble gas. During the course of this work, a technique was developed for producing a continuous air stream of 41 Ar required for testing this concept. The 41 Ar stream is produced by the neutron activation of air using a research reactor. The 41 Ar content of the air stream can be varied by many orders of magnitude by varying the reactor power level and the rate at which the air is pumped through a vertically positioned tube in or in front of the reactor. It was found that the neutrons also activate other air constituents, producing undesirable interference radionuclides. Selective filtering techniques have therefore been developed to remove these interference radionuclides from the 41 Ar air stream

  11. Mild desalination of various raw water streams

    NARCIS (Netherlands)

    Groot, C.K.; Broek, W.B.P. van den; Loewenberg, J.; Koeman-Stein-N.E.; Heidekamp, M.; Schepper, W. de

    2015-01-01

    For chemical industries, fresh water availability is a pre-requisite for sustainable operation. However, in many delta areas around the world, fresh water is scarce. Therefore, the E4Water project (http://www.e4water.eu) comprises a case study at the Dow site in Terneuzen, The Netherlands, which is

  12. Beneficial Reuse of Produced and Flowback Water

    Science.gov (United States)

    Water reuse and recycling is a significant issue in the development of oil and gas shale plays in the United StatesDrilling operations – 60,000 to 650,000 gallons per wellHydraulic fracturing operations – 3 million to 5 million gallons per wellDefinition of produced water and flowback waterInteractions of water quality constituents as they relate to water reuse and recyclingTesting criteria in the laboratory and field operations

  13. Link between DOC in near surface peat and stream water in an upland catchment.

    Science.gov (United States)

    Clark, Joanna M; Lane, Stuart N; Chapman, Pippa J; Adamson, John K

    2008-10-15

    Hydrologic transport of dissolved organic carbon (DOC) from peat soils may differ to organo-mineral soils in how they responded to changes in flow, because of differences in soil profile and hydrology. In well-drained organo-mineral soils, low flow is through the lower mineral layer where DOC is absorbed and high flow is through the upper organic layer where DOC is produced. DOC concentrations in streams draining organo-mineral soils typically increase with flow. In saturated peat soils, both high and low flows are through an organic layer where DOC is produced. Therefore, DOC in stream water draining peat may not increase in response to changes in flow as there is no switch in flow path between a mineral and organic layer. To verify this, we conducted a high-resolution monitoring study of soil and stream water at an upland peat catchment in northern England. Our data showed a strong positive correlation between DOC concentrations at -1 and -5 cm depth and stream water, and weaker correlations between concentrations at -20 to -50 cm depth and stream water. Although near surface organic material appears to be the key source of stream water DOC in both peat and organo-mineral soils, we observed a negative correlation between stream flow and DOC concentrations instead of a positive correlation as DOC released from organic layers during low and high flow was diluted by rainfall. The differences in DOC transport processes between peat and organo-mineral soils have different implications for our understanding of long-term changes in DOC exports. While increased rainfall may cause an increase in DOC flux from peat due to an increase in water volume, it may cause a decrease in concentrations. This response is contrary to expected changes in DOC exports from organo-mineral soils, where increase rainfall is likely to result in an increase in flux and concentration.

  14. The effect of in-stream activities on the Njoro River, Kenya. Part I: Stream flow and chemical water quality

    Science.gov (United States)

    Yillia, Paul T.; Kreuzinger, Norbert; Mathooko, Jude M.

    For shallow streams in sub-Saharan Africa, in-stream activities could be described as the actions by people and livestock, which take place within or besides stream channels. This study examined the nature of in-stream activities along a rural stream in Kenya and established the inequality in water allocation for various livelihood needs, as well as the negative impact they have on dry weather stream flow and chemical water quality. Seven locations along the stream were studied in wet and dry weather of 2006. Enumeration consisted of making head counts of people and livestock and tallying visitors at hourly intervals from 6 a.m. to 7 p.m. To estimate water abstraction, filled containers of known volume were counted and the stream was sampled to examine the impact on water quality. Water samples were obtained upstream and downstream of in-stream activities before (6 a.m.) and during (11 a.m., 6 p.m.) activities. Samples were analyzed for suspended solids, turbidity, BOD 5, total nitrogen and total phosphorus. The daily total abstraction at the middle reaches during dry weather was 120-150 m 3 day -1. More than 60% of abstraction was done by water vendors. Vended water from the stream was sold at US 3.5-7.5 per m 3 and vendors earned between US 3-6 a day. Abstracted water contributed approximately 40-60% of the total daily consumptive water use in the riparian area during dry weather but >30% of the morning stream flow was abstracted thereby upsetting stream flow in the lower reaches. The daily total water abstraction correlated positively ( R2, 0.98) and significantly ( p < 0.05) with the daily total human visit, which was diurnally periodic with two peaks, occurring between 9 a.m. and 10 a.m. and from 4 p.m. to 5 p.m. This diurnal pattern of visits and the corresponding in-stream activities affected water quality. In particular, suspended solids, turbidity and BOD 5 levels increased significantly ( p < 0.05) downstream during in-stream activities. It was concluded

  15. Wintertime Emissions from Produced Water Ponds

    Science.gov (United States)

    Evans, J.; Lyman, S.; Mansfield, M. L.

    2013-12-01

    Every year oil and gas drilling in the U.S. generates billions of barrels of produced water (water brought to the surface during oil or gas production). Efficiently disposing of produced water presents a constant financial challenge for producers. The most noticeable disposal method in eastern Utah's Uintah Basin is the use of evaporation ponds. There are 427 acres of produced water ponds in the Uintah Basin, and these were used to evaporate more than 5 million barrels of produced water in 2012, 6% of all produced water in the Basin. Ozone concentrations exceeding EPA standards have been observed in the Uintah Basin during winter inversion conditions, with daily maximum 8 hour average concentrations at some research sites exceeding 150 parts per billion. Produced water contains ozone-forming volatile organic compounds (VOC) which escape into the atmosphere as the water is evaporated, potentially contributing to air quality problems. No peer-reviewed study of VOC emissions from produced water ponds has been reported, and filling this gap is essential for the development of accurate emissions inventories for the Uintah Basin and other air sheds with oil and gas production. Methane, carbon dioxide, and VOC emissions were measured at three separate pond facilities in the Uintah Basin in February and March of 2013 using a dynamic flux chamber. Pond emissions vary with meteorological conditions, so measurements of VOC emissions were collected during winter to obtain data relevant to periods of high ozone production. Much of the pond area at evaporation facilities was frozen during the study period, but areas that actively received water from trucks remained unfrozen. These areas accounted for 99.2% of total emissions but only 9.5% of the total pond area on average. Ice and snow on frozen ponds served as a cap, prohibiting VOC from being emitted into the atmosphere. Emissions of benzene, toluene, and other aromatic VOCs averaged over 150 mg m-2 h-1 from unfrozen pond

  16. Partial oxidation process for producing a stream of hot purified gas

    Science.gov (United States)

    Leininger, T.F.; Robin, A.M.; Wolfenbarger, J.K.; Suggitt, R.M.

    1995-03-28

    A partial oxidation process is described for the production of a stream of hot clean gas substantially free from particulate matter, ammonia, alkali metal compounds, halides and sulfur-containing gas for use as synthesis gas, reducing gas, or fuel gas. A hydrocarbonaceous fuel comprising a solid carbonaceous fuel with or without liquid hydrocarbonaceous fuel or gaseous hydrocarbon fuel, wherein said hydrocarbonaceous fuel contains halides, alkali metal compounds, sulfur, nitrogen and inorganic ash containing components, is reacted in a gasifier by partial oxidation to produce a hot raw gas stream comprising H{sub 2}, CO, CO{sub 2}, H{sub 2}O, CH{sub 4}, NH{sub 3}, HCl, HF, H{sub 2}S, COS, N{sub 2}, Ar, particulate matter, vapor phase alkali metal compounds, and molten slag. The hot raw gas stream from the gasifier is split into two streams which are separately deslagged, cleaned and recombined. Ammonia in the gas mixture is catalytically disproportionated into N{sub 2} and H{sub 2}. The ammonia-free gas stream is then cooled and halides in the gas stream are reacted with a supplementary alkali metal compound to remove HCl and HF. Alkali metal halides, vaporized alkali metal compounds and residual fine particulate matter are removed from the gas stream by further cooling and filtering. The sulfur-containing gases in the process gas stream are then reacted at high temperature with a regenerable sulfur-reactive mixed metal oxide sulfur sorbent material to produce a sulfided sorbent material which is then separated from the hot clean purified gas stream having a temperature of at least 1000 F. 1 figure.

  17. Beneficial Reuse of San Ardo Produced Water

    Energy Technology Data Exchange (ETDEWEB)

    Robert A. Liske

    2006-07-31

    This DOE funded study was performed to evaluate the potential for treatment and beneficial reuse of produced water from the San Ardo oilfield in Monterey County, CA. The potential benefits of a successful full-scale implementation of this project include improvements in oil production efficiency and additional recoverable oil reserves as well as the addition of a new reclaimed water resource. The overall project was conducted in two Phases. Phase I identified and evaluated potential end uses for the treated produced water, established treated water quality objectives, reviewed regulations related to treatment, transport, storage and use of the treated produced water, and investigated various water treatment technology options. Phase II involved the construction and operation of a small-scale water treatment pilot facility to evaluate the process's performance on produced water from the San Ardo oilfield. Cost estimates for a potential full-scale facility were also developed. Potential end uses identified for the treated water include (1) agricultural use near the oilfield, (2) use by Monterey County Water Resources Agency (MCWRA) for the Salinas Valley Water Project or Castroville Seawater Intrusion Project, (3) industrial or power plant use in King City, and (4) use for wetlands creation in the Salinas Basin. All of these uses were found to have major obstacles that prevent full-scale implementation. An additional option for potential reuse of the treated produced water was subsequently identified. That option involves using the treated produced water to recharge groundwater in the vicinity of the oil field. The recharge option may avoid the limitations that the other reuse options face. The water treatment pilot process utilized: (1) warm precipitation softening to remove hardness and silica, (2) evaporative cooling to meet downstream temperature limitations and facilitate removal of ammonia, and (3) reverse osmosis (RO) for removal of dissolved salts, boron

  18. Influence of climate on alpine stream chemistry and water sources

    Science.gov (United States)

    Foks, Sydney; Stets, Edward; Singha, Kamini; Clow, David W.

    2018-01-01

    The resilience of alpine/subalpine watersheds may be viewed as the resistance of streamflow or stream chemistry to change under varying climatic conditions, which is governed by the relative size (volume) and transit time of surface and subsurface water sources. Here, we use end‐member mixing analysis in Andrews Creek, an alpine stream in Rocky Mountain National Park, Colorado, from water year 1994 to 2015, to explore how the partitioning of water sources and associated hydrologic resilience change in response to climate. Our results indicate that four water sources are significant contributors to Andrews Creek, including snow, rain, soil water, and talus groundwater. Seasonal patterns in source‐water contributions reflected the seasonal hydrologic cycle, which is driven by the accumulation and melting of seasonal snowpack. Flushing of soil water had a large effect on stream chemistry during spring snowmelt, despite making only a small contribution to streamflow volume. Snow had a large influence on stream chemistry as well, contributing large amounts of water with low concentrations of weathering products. Interannual patterns in end‐member contributions reflected responses to drought and wet periods. Moderate and significant correlations exist between annual end‐member contributions and regional‐scale climate indices (the Palmer Drought Severity Index, the Palmer Hydrologic Drought Index, and the Modified Palmer Drought Severity Index). From water year 1994 to 2015, the percent contribution from the talus‐groundwater end member to Andrews Creek increased an average of 0.5% per year (p < 0.0001), whereas the percent contributions from snow plus rain decreased by a similar amount (p = 0.001). Our results show how water and solute sources in alpine environments shift in response to climate variability and highlight the role of talus groundwater and soil water in providing hydrologic resilience to the system.

  19. Local geology determines responses of stream producers and fungal decomposers to nutrient enrichment: A field experiment.

    Science.gov (United States)

    Mykrä, Heikki; Sarremejane, Romain; Laamanen, Tiina; Karjalainen, Satu Maaria; Markkola, Annamari; Lehtinen, Sirkku; Lehosmaa, Kaisa; Muotka, Timo

    2018-04-16

    We examined how short-term (19 days) nutrient enrichment influences stream fungal and diatom communities, and rates of leaf decomposition and algal biomass accrual. We conducted a field experiment using slow-releasing nutrient pellets to increase nitrate (NO 3 -N) and phosphate (PO 4 -P) concentrations in a riffle section of six naturally acidic (naturally low pH due to catchment geology) and six circumneutral streams. Nutrient enrichment increased microbial decomposition rate on average by 14%, but the effect was significant only in naturally acidic streams. Nutrient enrichment also decreased richness and increased compositional variability of fungal communities in naturally acidic streams. Algal biomass increased in both stream types, but algal growth was overall very low. Diatom richness increased in response to nutrient addition by, but only in circumneutral streams. Our results suggest that primary producers and decomposers are differentially affected by nutrient enrichment and that their responses to excess nutrients are context dependent, with a potentially stronger response of detrital processes and fungal communities in naturally acidic streams than in less selective environments.

  20. ANAEROBIC BIOLOGICAL TREATMENT OF PRODUCED WATER; TOPICAL

    International Nuclear Information System (INIS)

    John R. Gallagher

    2001-01-01

    During the production of oil and gas, large amounts of water are brought to the surface and must be disposed of in an environmentally sensitive manner. This is an especially difficult problem in offshore production facilities where space is a major constraint. The chief regulatory criterion for produced water is oil and grease. Most facilities have little trouble meeting this criterion using conventional oil-water separation technologies. However, some operations have significant amounts of naphthenic acids in the water that behave as oil and grease but are not well removed by conventional technologies. Aerobic biological treatment of naphthenic acids in simulated-produced water has been demonstrated by others; however, the system was easily overloaded by the large amounts of low-molecular-weight organic acids often found in produced waters. The objective of this research was to determine the ability of an anaerobic biological system to treat these organic acids in a simulated produced water and to examine the potential for biodegradation of the naphthenic acids in the anaerobic environment. A small fixed-film anaerobic biological reactor was constructed and adapted to treat a simulated produced water. The bioreactor was tubular, with a low-density porous glass packing material. The inocula to the reactor was sediment from a produced-water holding pond from a municipal anaerobic digester and two salt-loving methanogenic bacteria. During start-up, the feed to the reactor contained glucose as well as typical produced-water components. When glucose was used, rapid gas production was observed. However, when glucose was eliminated and the major organic component was acetate, little gas was generated. Methane production from acetate may have been inhibited by the high salt concentrations, by sulfide, or because of the lack, despite seeding, of microbes capable of converting acetate to methane. Toluene, a minor component of the produced water (0.1 g/L) was removed in the

  1. ANAEROBIC BIOLOGICAL TREATMENT OF PRODUCED WATER

    Energy Technology Data Exchange (ETDEWEB)

    John R. Gallagher

    2001-07-31

    During the production of oil and gas, large amounts of water are brought to the surface and must be disposed of in an environmentally sensitive manner. This is an especially difficult problem in offshore production facilities where space is a major constraint. The chief regulatory criterion for produced water is oil and grease. Most facilities have little trouble meeting this criterion using conventional oil-water separation technologies. However, some operations have significant amounts of naphthenic acids in the water that behave as oil and grease but are not well removed by conventional technologies. Aerobic biological treatment of naphthenic acids in simulated-produced water has been demonstrated by others; however, the system was easily overloaded by the large amounts of low-molecular-weight organic acids often found in produced waters. The objective of this research was to determine the ability of an anaerobic biological system to treat these organic acids in a simulated produced water and to examine the potential for biodegradation of the naphthenic acids in the anaerobic environment. A small fixed-film anaerobic biological reactor was constructed and adapted to treat a simulated produced water. The bioreactor was tubular, with a low-density porous glass packing material. The inocula to the reactor was sediment from a produced-water holding pond from a municipal anaerobic digester and two salt-loving methanogenic bacteria. During start-up, the feed to the reactor contained glucose as well as typical produced-water components. When glucose was used, rapid gas production was observed. However, when glucose was eliminated and the major organic component was acetate, little gas was generated. Methane production from acetate may have been inhibited by the high salt concentrations, by sulfide, or because of the lack, despite seeding, of microbes capable of converting acetate to methane. Toluene, a minor component of the produced water (0.1 g/L) was removed in the

  2. Characterization of Soluble Organics in Produced Water

    Energy Technology Data Exchange (ETDEWEB)

    Bostick, D.T.

    2002-01-16

    Soluble organics in produced water and refinery effluents represent treatment problems for the petroleum industry. Neither the chemistry involved in the production of soluble organics nor the impact of these chemicals on total effluent toxicity is well understood. The U.S. Department of Energy provides funding for Oak Ridge National Laboratory (ORNL) to support a collaborative project with Shell, Chevron, Phillips, and Statoil entitled ''Petroleum and Environmental Research Forum project (PERF 9844: Manage Water-Soluble Organics in Produced Water''). The goal of this project, which involves characterization and evaluation of these water-soluble compounds, is aimed at reducing the future production of such contaminants. To determine the effect that various drilling conditions might have on water-soluble organics (WSO) content in produced water, a simulated brine water containing the principal inorganic components normally found in Gulf of Mexico (GOM) brine sources was prepared. The GOM simulant was then contacted with as-received crude oil from a deep well site to study the effects of water cut, produced-water pH, salinity, pressure, temperature, and crude oil sources on the type and content of the WSO in produced water. The identities of individual semivolatile organic compounds (SVOCs) were determined in all as-received crude and actual produced water samples using standard USEPA Method (8270C) protocol. These analyses were supplemented with the more general measurements of total petroleum hydrocarbon (TPH) content in the gas (C{sub 6}-C{sub 10}), diesel (C{sub 10}-C{sub 20}), and oil (C{sub 20}-C{sub 28}) carbon ranges as determined by both gas chromatographic (GC) and infrared (IR) analyses. An open liquid chromatographic procedure was also used to differentiate the saturated hydrocarbon, aromatic hydrocarbon, and polar components within the extractable TPH. Inorganic constituents in the produced water were analyzed by ion

  3. Cover Crops for Managing Stream Water Quantity and Improving Stream Water Quality of Non-Tile Drained Paired Watersheds

    OpenAIRE

    Gurbir Singh; Jon E. Schoonover; Karl W. J. Williard

    2018-01-01

    In the Midwestern United States, cover crops are being promoted as a best management practice for managing nutrient and sediment losses from agricultural fields through surface and subsurface water movement. To date, the water quality benefits of cover crops have been inferred primarily from plot scale studies. This project is one of the first to analyze the impacts of cover crops on stream water quality at the watershed scale. The objective of this research was to evaluate nitrogen, phosphor...

  4. Does stream water chemistry reflect watershed characteristics?

    Czech Academy of Sciences Publication Activity Database

    Chuman, Tomáš; Hruška, Jakub; Oulehle, Filip; Gürtlerová, P.; Majer, V.

    2013-01-01

    Roč. 185, č. 7 (2013), s. 5683-5701 ISSN 0167-6369 R&D Projects: GA MŠk(CZ) ED1.1.00/02.0073 Institutional support: RVO:67179843 Keywords : Anions * Cations * Land cover * Water quality * Geochemical reactivity * Czech Republic Subject RIV: EH - Ecology, Behaviour Impact factor: 1.679, year: 2013

  5. Precipitation and stream water stable isotope data from the Marys River, Oregon in water year 2015.

    Data.gov (United States)

    U.S. Environmental Protection Agency — Water stable isotope data collected from a range of streams throughout the Marys River basin in water year 2015, and precipitation data collected within the basin at...

  6. Water quality of some logged and unlogged California streams

    Science.gov (United States)

    Fredric R. Kopperdahl; James W. Burns; Gary E. Smith

    1971-01-01

    Water quality was monitored in 1968 and 1969 in six coastal streams in northern California, four of which were subjected to logging and/or road building (Bummer Lake Creek, South Fork Yager Creek, Little North Fork Noyo River, and South Fork Caspar Creek), while the others remained undisturbed (Godwood Creek and North Fork Caspar Creek). The purposes of this study were...

  7. 244-AR vault cooling water stream-specific report

    International Nuclear Information System (INIS)

    1990-08-01

    The proposed wastestream designation for the 244-AR Vault cooling water wastestream is that this stream is not a dangerous waste, pursuant to the Washington (State) Administration Code (WAC) 173-303, Dangerous Waste Regulations. A combination of process knowledge and sampling data was used to make this determination. 21 refs., 6 figs., 7 tabs

  8. Heavy metal contamination in stream water and sediments of gold ...

    African Journals Online (AJOL)

    I.O.OLABANJI

    3D) with 0.457 ± 0.061 and 0.364 ± 0.056 mg/L in dry and wet seasons. The mean .... safe limit clearly indicating that Cd contamination of the stream water might be ... of lead contaminant in the study area is the formation of acid mine drainage.

  9. Stream water responses to timber harvest: Riparian buffer width effectiveness

    Science.gov (United States)

    Barton D. Clinton

    2011-01-01

    Vegetated riparian buffers are critical for protecting aquatic and terrestrial processes and habitats in southern Appalachian ecosystems. In this case study, we examined the effect of riparian buffer width on stream water quality following upland forest management activities in four headwater catchments. Three riparian buffer widths were delineated prior to cutting; 0m...

  10. Produced water treatment methods for SAGD

    Energy Technology Data Exchange (ETDEWEB)

    Minnich, K. [Veolia Water Solutions and Technologies, Mississauga, ON (Canada)

    2008-07-01

    Produced water treatment methods for steam assisted gravity drainage (SAGD) processes were presented. Lime softening is used to remove sludge before weak acid cation processes. However, the process is not reliable in cold climates, and disposal of the sludge is now posing environmental problems in Alberta. High pH MVC evaporation processes use sodium hydroxide (NaOH) additions to prevent silica scaling. However the process produces silica wastes that are difficult to dispose of. The sorption slurry process was designed to reduce the use of caustic soda and develop a cost-effective method of disposing evaporator concentrates. The method produces 98 per cent steam quality for SAGD injection. Silica is sorbed onto crystals in order to prevent silica scaling. The evaporator concentrate from the process is suitable for on- and off-site deep well disposal. The ceramic membrane process was designed to reduce the consumption of chemicals and improve the reliability of water treatment processes. The ion exchange desilication process uses 80 per cent less power and produces 80 per cent fewer CO{sub 2} emissions than MVC evaporators. A comparative operating cost evaluation of various electric supply configurations and produced water treatment processes was also included, as well as an analysis of produced water chemistry. tabs., figs.

  11. Stream-Groundwater Interaction Buffers Seasonal Changes in Urban Stream Water Quality

    Science.gov (United States)

    Ledford, S. H.; Lautz, L. K.

    2013-12-01

    Urban streams in the northeastern United States have large road salt inputs during winter, increased nonpoint sources of inorganic nitrogen, and decreased short-term and permanent storage of nutrients. Meadowbrook Creek, a first order stream in Syracuse, New York, flows along a negative urbanization gradient, from a channelized and armored stream running through the middle of a roadway to a pool-riffle stream meandering through a broad, vegetated floodplain with a riparian aquifer. In this study we investigated how reconnection to groundwater and introduction of riparian vegetation impacted surface water chemistry by making bi-weekly longitudinal surveys of stream water chemistry in the creek from May 2012 until June 2013. Chloride concentrations in the upstream, urban reach of Meadowbrook Creek were strongly influenced by discharge of road salt to the creek during snow melt events in winter and by the chemistry of water draining an upstream retention basin in summer. Chloride concentrations ranged from 161.2 mg/L in August to 2172 mg/L in February. Chloride concentrations in the downstream, 'connected' reach had less temporal variation, ranging from 252.0 mg/L in August to 1049 mg/L in January, and were buffered by groundwater discharge, as the groundwater chloride concentrations during the sampling period ranged from 84.0 to 655.4 mg/L. Groundwater discharge resulted in higher chloride concentrations in summer and lower concentrations in winter in the connected reach relative to the urban reach, minimizing annual variation. In summer, there was little-to-no nitrate in the urban reach due to a combination of limited sources and high primary productivity. In contrast, during the summer, nitrate concentrations reached over 1 mg N/L in the connected reach due to the presence of riparian vegetation and lower nitrate uptake due to cooler temperatures and shading. During the winter, when temperatures fell below freezing, nitrate concentrations in the urban reach

  12. Heated water jet in coflowing turbulent stream

    International Nuclear Information System (INIS)

    Shirazi, M.A.; McQuivey, R.S.; Keefer, T.N.

    1974-01-01

    Effects of ambient turbulence on temperature and salinity distributions of heated water and neutrally buoyant saltwater jets were studied for a wide range of densimetric jet Froude numbers, jet discharge velocities, and ambient turbulence levels in a 4-ft-wide channel. Estimates of vertical and lateral diffusivity coefficients for heat and for salt were obtained from salinity and temperature distributions taken at several stations downstream of the injection point. Readily usable correlations are presented for plume center-line temperature, plume width, and trajectory. The ambient turbulence affects the gross behavior characteristics of the plume. The effects vary with the initial jet Froude number and the jet to ambient velocity ratio. Heat and salinity are transported similarly and the finite source dimensions and the initial jet characteristics alter the numerical value of the diffusivity

  13. Angular distributions of atomic vapor stream produced by electron beam heating

    Energy Technology Data Exchange (ETDEWEB)

    Ohba, Hironori; Amekawa, Kazuhiro; Shibata, Takemasa [Japan Atomic Energy Research Inst., Tokai, Ibaraki (Japan). Tokai Research Establishment

    1997-03-01

    The angular distributions were measured as a function of deposition rate for aluminium, copper, gadolinium and cerium vapor stream produced by an electron beam gun with water-cooled copper crucible. The distributions were recorded on the mounted on a semicircular (120mm in radius) mask over the evaporation source. The measured distributions were able to be described by a simple cosine law, that is cos{sup n} {theta}, except for the case of extremely high evaporation rate with a porous material, where n is a rate-dependent beaming exponent, {theta} is the angle from the vertical. For many kinds of evaporants, it was confirmed that the beaming exponents increase continuously from unity to 3 or 4 with increasing deposition rate and are approximately proportional to R{sup 0.25} where R is the deposition rate. Moreover, it was found that the beaming exponents n are able to be expressed as n = {alpha} Kn{sub 0}{sup -0.25}, where Kn{sub 0}{sup -1} is the inverse of Knudsen number, which is defined by the mean free path of evaporated atoms and the evaporation spot size, and {alpha} is the constant. (author)

  14. Angular distributions of atomic vapor stream produced by electron beam heating

    International Nuclear Information System (INIS)

    Ohba, Hironori; Amekawa, Kazuhiro; Shibata, Takemasa

    1997-03-01

    The angular distributions were measured as a function of deposition rate for aluminium, copper, gadolinium and cerium vapor stream produced by an electron beam gun with water-cooled copper crucible. The distributions were recorded on the mounted on a semicircular (120mm in radius) mask over the evaporation source. The measured distributions were able to be described by a simple cosine law, that is cos n θ, except for the case of extremely high evaporation rate with a porous material, where n is a rate-dependent beaming exponent, θ is the angle from the vertical. For many kinds of evaporants, it was confirmed that the beaming exponents increase continuously from unity to 3 or 4 with increasing deposition rate and are approximately proportional to R 0.25 where R is the deposition rate. Moreover, it was found that the beaming exponents n are able to be expressed as n = α Kn 0 -0.25 , where Kn 0 -1 is the inverse of Knudsen number, which is defined by the mean free path of evaporated atoms and the evaporation spot size, and α is the constant. (author)

  15. innovation in radioactive waste water-stream management

    International Nuclear Information System (INIS)

    Shaaban, D.A.E.F.

    2010-01-01

    treatment of radioactive waste dtreams is receiving considereble attention in most countries. the present work is for the radioactive wastewater stream management, by volume reduction by a mutual heating and humidificaction of a compressed dry air introduced through the wastewater. in the present work, a mathematical model describing the volume reduction by at the optimum operating condition is determined. a set of coupled first order differential equations, obtained through the mass and energy conservations laws, are used to obtain the humidity ratio, water diffused to the air stream, water temperature, and humid air stream temperature distributions through the bubbling column. these coupled differential equations are simulataneously solved numerically by the developed computer program using fourth order rung-kutta method. the results obtained, according to the present mathematical model, revealed that the air bubble state variables such as mass transfer coefficient (K G ) and interfacial area (a) have a strong effect on the process. therefore, the behavior of the air bubble state variables with coulmn height can be predicted and optimized. moreover, the design curves of the volumetric reduction of the wastewater streams are obtained and assessed at the different operating conditions. an experimental setup was constructed to verify the suggested model. comperhensive comparison between suggested model results, recent experimental measurements and the results of previous work was carried out

  16. ADVANCED STRIPPER GAS PRODUCED WATER REMEDIATION

    International Nuclear Information System (INIS)

    Ray W. Sheldon

    2001-01-01

    Natural gas and oil production from stripper wells also produces water contaminated with hydrocarbons, and in most locations, salts and trace elements. The hydrocarbons are not generally present in concentrations that allow the operator to economically recover these liquids. Produced liquids, (stripper gas water) which are predominantly water, present the operator with two options; purify the water to acceptable levels of contaminates, or pay for the disposal of the water. The project scope involves testing SynCoal as a sorbent to reduce the levels of contamination in stripper gas well produced water to a level that the water can be put to a productive use. Produced water is to be filtered with SynCoal, a processed sub-bituminous coal. It is expected that the surface area of and in the SynCoal would sorb the hydrocarbons and other contaminates and the effluent would be usable for agricultural purposes. Test plan anticipates using two well locations described as being disparate in the level and type of contaminates present. The loading capacity and the rate of loading for the sorbent should be quantified in field testing situations which include unregulated and widely varying liquid flow rates. This will require significant flexibility in the initial stages of the investigation. The scope of work outlined below serves as the guidelines for the testing of SynCoal carbon product as a sorbent to remove hydrocarbons and other contaminants from the produced waters of natural gas wells. A maximum ratio of 1 lb carbon to 100 lbs water treated is the initial basis for economic design. While the levels of contaminants directly impact this ratio, the ultimate economics will be dictated by the filter servicing requirements. This experimental program is intended to identify those treatment parameters that yield the best technological practice for a given set of operating conditions. The goal of this research is to determine appropriate guidelines for field trials by accurately

  17. Fragmentation and quench behavior of corium melt streams in water

    International Nuclear Information System (INIS)

    Spencer, B.W.; Wang, K.; Blomquist, C.A.; McUmber, L.M.; Schneider, J.P.

    1994-02-01

    The interaction of molten core materials with water has been investigated for the pour stream mixing mode. This interaction plays a crucial role during the later stages of in-vessel core melt progression inside a light water reactor such as during the TMI-2 accident. The key issues which arise during the molten core relocation include: (i) the thermal attack and possible damage to the RPV lower head from the impinging molten fuel stream and/or the debris bed, (ii) the molten fuel relocation pathways including the effects of redistribution due to core support structure and the reactor lower internals, (iii) the quench rate of the molten fuel through the water in the lower plenum, (iv) the steam generation and hydrogen generation during the interaction, (v) the transient pressurization of the primary system, and (vi) the possibility of a steam explosion. In order to understand these issues, a series of six experiments (designated CCM-1 through -6) was performed in which molten corium passed through a deep pool of water in a long, slender pour stream mode. Results discussed include the transient temperatures and pressures, the rate and magnitude of steam/hydrogen generation, and the posttest debris characteristics

  18. Water's Journey from Rain to Stream in perspective

    Science.gov (United States)

    Rodhe, Allan; Grip, Harald

    2015-04-01

    The International Hydrological Decade (IHD) 1965-1974, sponsored by UNESCO, initiated a research effort for coordinating the fragmented branches of hydrology and for understanding and quantifying the hydrologic cycle on various scales, from continents to small catchments. One important part of the Swedish IHD-program was to quantify the terms of the water budget, including detailed data on soil water and groundwater storage dynamics, of several medium sized to small. As an outcome of these studies and subsequent process oriented studies, a new view of the runoff process in forested till soils was developed in the 1970's, stressing the dominating role of groundwater in delivering water to the streams and the usefulness of subdividing catchments into recharge and discharge areas for groundwater for understanding the flowpaths of water. This view contrasted with the general view among the public, and also among professionals within the field and in text books, according to which overland flow is the main process for runoff. With this latter view it would, for instance, not be possible to understand stream water chemistry, which had become an important question in a time of growing environmental concern. In order to decrease the time lag between research results and practice, the Swedish Natural Science Research Council initiated a text book project for presenting the recent results of hydrologic research on stream flow generation applied to Swedish conditions, and in 1985 our book "Water's Journey from Rain to Stream" was published. Founded on the basic principles for water storage and flow in soils, the book gives a general picture of the water flow through the forested till landscape, with separate chapters for recharge and discharge areas. Chemical processes along the flowpaths of water are treated and the book concludes with a few applications to current issues. The book is written in Swedish and the target audience is those working professionally with water and

  19. Using Biosurfactants Produced from Agriculture Process Waste Streams to Improve Oil Recovery in Fractured Carbonate Reservoirs

    Energy Technology Data Exchange (ETDEWEB)

    Stephen Johnson; Mehdi Salehi; Karl Eisert; Sandra Fox

    2009-01-07

    This report describes the progress of our research during the first 30 months (10/01/2004 to 03/31/2007) of the original three-year project cycle. The project was terminated early due to DOE budget cuts. This was a joint project between the Tertiary Oil Recovery Project (TORP) at the University of Kansas and the Idaho National Laboratory (INL). The objective was to evaluate the use of low-cost biosurfactants produced from agriculture process waste streams to improve oil recovery in fractured carbonate reservoirs through wettability mediation. Biosurfactant for this project was produced using Bacillus subtilis 21332 and purified potato starch as the growth medium. The INL team produced the biosurfactant and characterized it as surfactin. INL supplied surfactin as required for the tests at KU as well as providing other microbiological services. Interfacial tension (IFT) between Soltrol 130 and both potential benchmark chemical surfactants and crude surfactin was measured over a range of concentrations. The performance of the crude surfactin preparation in reducing IFT was greater than any of the synthetic compounds throughout the concentration range studied but at low concentrations, sodium laureth sulfate (SLS) was closest to the surfactin, and was used as the benchmark in subsequent studies. Core characterization was carried out using both traditional flooding techniques to find porosity and permeability; and NMR/MRI to image cores and identify pore architecture and degree of heterogeneity. A cleaning regime was identified and developed to remove organic materials from cores and crushed carbonate rock. This allowed cores to be fully characterized and returned to a reproducible wettability state when coupled with a crude-oil aging regime. Rapid wettability assessments for crushed matrix material were developed, and used to inform slower Amott wettability tests. Initial static absorption experiments exposed limitations in the use of HPLC and TOC to determine

  20. StreamStats: A water resources web application

    Science.gov (United States)

    Ries, Kernell G.; Guthrie, John G.; Rea, Alan H.; Steeves, Peter A.; Stewart, David W.

    2008-01-01

    Streamflow statistics, such as the 1-percent flood, the mean flow, and the 7-day 10-year low flow, are used by engineers, land managers, biologists, and many others to help guide decisions in their everyday work. For example, estimates of the 1-percent flood (the flow that is exceeded, on average, once in 100 years and has a 1-percent chance of being exceeded in any year, sometimes referred to as the 100-year flood) are used to create flood-plain maps that form the basis for setting insurance rates and land-use zoning. This and other streamflow statistics also are used for dam, bridge, and culvert design; water-supply planning and management; water-use appropriations and permitting; wastewater and industrial discharge permitting; hydropower facility design and regulation; and the setting of minimum required streamflows to protect freshwater ecosystems. In addition, researchers, planners, regulators, and others often need to know the physical and climatic characteristics of the drainage basins (basin characteristics) and the influence of human activities, such as dams and water withdrawals, on streamflow upstream from locations of interest to understand the mechanisms that control water availability and quality at those locations. Knowledge of the streamflow network and downstream human activities also is necessary to adequately determine whether an upstream activity, such as a water withdrawal, can be allowed without adversely affecting downstream activities.Streamflow statistics could be needed at any location along a stream. Most often, streamflow statistics are needed at ungaged sites, where no streamflow data are available to compute the statistics. At U.S. Geological Survey (USGS) streamflow data-collection stations, which include streamgaging stations, partial-record stations, and miscellaneous-measurement stations, streamflow statistics can be computed from available data for the stations. Streamflow data are collected continuously at streamgaging stations

  1. Purification of produced waters in oil fields

    Energy Technology Data Exchange (ETDEWEB)

    Niyazov, R S; Baikov, U M

    1970-01-01

    Experience has shown that a single step water-conditioning process cannot be used to prepare Bashkirian produced waters for underground injection. In the single-step process, the water is passed through horizontal or vertical settling basins to remove solids. This system does not work when suspended solids increase above 200 to 500 mg/liter. The required quality of injection water can be obtained by filtering the water through sand at flow velocities of 5 to 10 m/hr. The filter has a sand layer 0.6 to 1 m thick, composed of 0.35 to 1.0 mm sand. Water entering the filters should not contain more than 100 to 150 mg/liter of oil products. The filters are backwashed at velocity of 10 to 15 m/hr and rates of 12 to 16 liters/sec sq m for 10 to 15 min. Clean water is used in backwashing. When surfactant is added to the backwash water, the filter cycle lasts longer.

  2. Potential Impacts of Organic Wastes on Small Stream Water Quality

    Science.gov (United States)

    Kaushal, S. S.; Groffman, P. M.; Findlay, S. E.; Fischer, D. T.; Burke, R. A.; Molinero, J.

    2005-05-01

    We monitored concentrations of dissolved organic carbon (DOC), dissolved oxygen (DO) and other parameters in 17 small streams of the South Fork Broad River (SFBR) watershed on a monthly basis for 15 months. The subwatersheds were chosen to reflect a range of land uses including forested, pasture, mixed, and developed. The SFBR watershed is heavily impacted by organic wastes, primarily from its large poultry industry, but also from its rapidly growing human population. The poultry litter is primarily disposed of by application to pastures. Our monthly monitoring results showed a strong inverse relationship between mean DOC and mean DO and suggested that concentrations of total nitrogen (TN), DOC, and the trace gases nitrous oxide, methane and carbon dioxide are impacted by organic wastes and/or nutrients from animal manure applied to the land and/or human wastes from wastewater treatment plants or septic tanks in these watersheds. Here we estimate the organic waste loads of these watersheds and evaluate the impact of organic wastes on stream DOC and alkalinity concentrations, electrical conductivity, sediment potential denitrification rate and plant stable nitrogen isotope ratios. All of these water quality parameters are significantly correlated with watershed waste loading. DOC is most strongly correlated with total watershed waste loading whereas conductivity, alkalinity, potential denitrification rate and plant stable nitrogen isotope ratio are most strongly correlated with watershed human waste loading. These results suggest that more direct inputs (e.g., wastewater treatment plant effluents, near-stream septic tanks) have a greater relative impact on stream water quality than more dispersed inputs (land applied poultry litter, septic tanks far from streams) in the SFBR watershed. Conductivity, which is generally elevated in organic wastes, is also significantly correlated with total watershed waste loading suggesting it may be a useful indicator of overall

  3. Application of regression model on stream water quality parameters

    International Nuclear Information System (INIS)

    Suleman, M.; Maqbool, F.; Malik, A.H.; Bhatti, Z.A.

    2012-01-01

    Statistical analysis was conducted to evaluate the effect of solid waste leachate from the open solid waste dumping site of Salhad on the stream water quality. Five sites were selected along the stream. Two sites were selected prior to mixing of leachate with the surface water. One was of leachate and other two sites were affected with leachate. Samples were analyzed for pH, water temperature, electrical conductivity (EC), total dissolved solids (TDS), Biological oxygen demand (BOD), chemical oxygen demand (COD), dissolved oxygen (DO) and total bacterial load (TBL). In this study correlation coefficient r among different water quality parameters of various sites were calculated by using Pearson model and then average of each correlation between two parameters were also calculated, which shows TDS and EC and pH and BOD have significantly increasing r value, while temperature and TDS, temp and EC, DO and BL, DO and COD have decreasing r value. Single factor ANOVA at 5% level of significance was used which shows EC, TDS, TCL and COD were significantly differ among various sites. By the application of these two statistical approaches TDS and EC shows strongly positive correlation because the ions from the dissolved solids in water influence the ability of that water to conduct an electrical current. These two parameters significantly vary among 5 sites which are further confirmed by using linear regression. (author)

  4. Environmental Monitoring, Water Quality - MO 2009 Stream Team Volunteer Water Quality Monitoring Sites (SHP)

    Data.gov (United States)

    NSGIC State | GIS Inventory — This data set shows the monitoring locations of trained Volunteer Water Quality Monitors. A monitoring site is considered to be a 300 foot section of stream channel....

  5. Treatment of Oil & Gas Produced Water.

    Energy Technology Data Exchange (ETDEWEB)

    Dwyer, Brian P. [Sandia National Lab. (SNL-NM), Albuquerque, NM (United States)

    2016-02-01

    Production of oil and gas reserves in the New Mexico Four Corners Region results in large volumes of "produced water". The common method for handling the produced water from well production is re-injection in regulatory permitted salt water disposal wells. This is expensive (%7E $5/bbl.) and does not recycle water, an ever increasingly valuable commodity. Previously, Sandia National Laboratories and several NM small business tested pressure driven membrane-filtration techniques to remove the high TDS (total dissolved solids) from a Four Corners Coal Bed Methane produced water. Treatment effectiveness was less than optimal due to problems with pre-treatment. Inadequate pre-treatment allowed hydrocarbons, wax and biological growth to foul the membranes. Recently, an innovative pre-treatment scheme using ozone and hydrogen peroxide was pilot tested. Results showed complete removal of hydrocarbons and the majority of organic constituents from a gas well production water. ACKNOWLEDGEMENTS This report was made possible through funding from the New Mexico Small Business Administration (NMSBA) Program at Sandia National Laboratories. Special thanks to Juan Martinez and Genaro Montoya for guidance and support from project inception to completion. Also, special thanks to Frank McDonald, the small businesses team POC, for laying the ground work for the entire project; Teresa McCown, the gas well owner and very knowledgeable- fantastic site host; Lea and Tim Phillips for their tremendous knowledge and passion in the oil & gas industry.; and Frank Miller and Steve Addleman for providing a pilot scale version of their proprietary process to facilitate the pilot testing.

  6. Automated disposal of produced water from a coalbed methane well field, a case history

    International Nuclear Information System (INIS)

    Luckianow, B.J.; Findley, M.L.; Paschal, W.T.

    1994-01-01

    This paper provides an overview of the automated disposal system for produced water designed and operated by Taurus Exploration, Inc. This presentation draws from Taurus' case study in the planning, design, construction, and operation of production water disposal facilities for the Mt. Olive well field, located in the Black Warrior Basin of Alabama. The common method for disposing of water produced from coalbed methane wells in the Warrior Basin is to discharge into a receiving stream. The limiting factor in the discharge method is the capability of the receiving stream to assimilate the chloride component of the water discharged. During the winter and spring, the major tributaries of the Black Warrior River are capable of assimilating far more production water than operations can generate. During the summer and fall months, however, these same tributaries can approach near zero flow, resulting in insufficient flow for dilution. During such periods pumping shut-down within the well field can be avoided by routing production waters into a storage facility. This paper discusses the automated production water disposal system on Big Sandy Creek designed and operated by Taurus. This system allows for continuous discharge to the receiving stream, thus taking full advantage of Big Sandy Creek's assimilative capacity, while allowing a provision for excess produced water storage and future stream discharge

  7. Bivariate functional data clustering: grouping streams based on a varying coefficient model of the stream water and air temperature relationship

    Science.gov (United States)

    H. Li; X. Deng; Andy Dolloff; E. P. Smith

    2015-01-01

    A novel clustering method for bivariate functional data is proposed to group streams based on their water–air temperature relationship. A distance measure is developed for bivariate curves by using a time-varying coefficient model and a weighting scheme. This distance is also adjusted by spatial correlation of streams via the variogram. Therefore, the proposed...

  8. Accumulation of anthropogenic radionuclides in crops in conditions of water stream and classical hydroponics

    Energy Technology Data Exchange (ETDEWEB)

    Mayrapetyan, Khachatur; Hovsepyan, Albert; Daryadar, Mahsa; Alexanyan, Julietta; Tovmasyan, Anahit; Ghalachyan, Laura; Tadevosyan, Anna; Mayrapetyan, Stepan [Institute of Hydroponics Problems, NAS, Noragyugh 108, 0082, Yerevan (Armenia)

    2014-07-01

    Natural and artificial radionuclides (RN) dangerous for health are emitted into ecosystems because of human anthropogenic activities in the field of nuclear energetics. Biologically artificial RN {sup 90}Sr(T{sub 1/2}=28,6 years) and {sup 137}Cs (T{sub 1/2}=30,1 years)are very dangerous. Therefore obtaining radio-ecologically safe raw material of high quality is a very urgent problem now. Taking into account the above mentioned, in order to obtain ecologically safe raw material we carried out comparative radiochemical investigations on essential oil and medicinal plants peppermint(Mentha piperita L.) and sweet basil (Ocimum basilicum L.) grown in new water-stream (continuous, gully, cylindrical) and classical hydroponics, with the aim of revealing accumulation peculiarities of {sup 90}Sr and {sup 137}Cs. The results of experiments have shown that in classical hydroponics peppermint and sweet basil exceeded the same indices of water-stream hydroponics with {sup 90}Sr and {sup 137}Cs content 1,1-1,2; 1,2-1,3 and 1,5-1,8; 1,4-1,8 times, respectively. Moreover, sweet basil exceeded peppermint in water-stream hydroponics {sup 90}Sr 1,3-1,6; {sup 137}Cs 1,2-1,4 times and in classical hydroponics {sup 90}Sr 1,6; {sup 137}Cs 1,2 times. The content of controlled artificial RN in raw material did not exceed the allowed concentration limit (ACL). New water-stream hydroponics system worked out in Institute of Hydroponics Problems is a radio-ecologically more profitable method for producing raw material than classical hydroponics. At the same time water-stream hydroponics system in comparison with classical hydroponics promoted productivity (dry raw material) increase of peppermint and sweet basil 1,1-1,4 times. (authors)

  9. Cover Crops for Managing Stream Water Quantity and Improving Stream Water Quality of Non-Tile Drained Paired Watersheds

    Directory of Open Access Journals (Sweden)

    Gurbir Singh

    2018-04-01

    Full Text Available In the Midwestern United States, cover crops are being promoted as a best management practice for managing nutrient and sediment losses from agricultural fields through surface and subsurface water movement. To date, the water quality benefits of cover crops have been inferred primarily from plot scale studies. This project is one of the first to analyze the impacts of cover crops on stream water quality at the watershed scale. The objective of this research was to evaluate nitrogen, phosphorus, and sediment loss in stream water from a no-till corn-soybean rotation planted with winter cover crops cereal rye (Secale cereale and hairy vetch (Vicia villosa in non-tile drained paired watersheds in Illinois, USA. The paired watersheds are under mixed land use (agriculture, forest, and pasture. The control watershed had 27 ha of row-crop agriculture, and the treatment watershed had 42 ha of row crop agriculture with cover crop treatment (CC-treatment. During a 4-year calibration period, 42 storm events were collected and Event Mean Concentrations (EMCs for each storm event were calculated for total suspended solids (TSS, nitrate-N (NO3-N, ammonia-N (NH4-N, dissolved reactive phosphorus (DRP, and total discharge. Predictive regression equations developed from the calibration period were used for calculating TSS, NO3-N, NH4-N, and DRP losses of surface runoff for the CC-treatment watershed. The treatment period consisted of total 18 storm events, seven of which were collected during the cereal rye, eight in the hairy vetch cover crop season and three during cash crop season. Cover crops reduced TSS and discharge by 33% and 34%, respectively in the CC-treatment watershed during the treatment period. However, surprisingly, EMCs for NO3-N, NH4-N, and DRP did not decrease. Stream discharge from the paired-watersheds will continue to be monitored to determine if the current water quality results hold or new patterns emerge.

  10. Impact of Industrial Effluents on Water Quality of Streams in Nakawa ...

    African Journals Online (AJOL)

    Impact of Industrial Effluents on Water Quality of Streams in Nakawa-Ntinda, Uganda. ... Journal of Applied Sciences and Environmental Management ... physicochemical parameters of streams that receive effluents from different categories of industries in Nakawa -Ntinda industrial area of Kampala. the stream water quality ...

  11. Machine learning and hurdle models for improving regional predictions of stream water acid neutralizing capacity

    Science.gov (United States)

    Nicholas A. Povak; Paul F. Hessburg; Keith M. Reynolds; Timothy J. Sullivan; Todd C. McDonnell; R. Brion Salter

    2013-01-01

    In many industrialized regions of the world, atmospherically deposited sulfur derived from industrial, nonpoint air pollution sources reduces stream water quality and results in acidic conditions that threaten aquatic resources. Accurate maps of predicted stream water acidity are an essential aid to managers who must identify acid-sensitive streams, potentially...

  12. Minimizing water consumption when producing hydropower

    Science.gov (United States)

    Leon, A. S.

    2015-12-01

    In 2007, hydropower accounted for only 16% of the world electricity production, with other renewable sources totaling 3%. Thus, it is not surprising that when alternatives are evaluated for new energy developments, there is strong impulse for fossil fuel or nuclear energy as opposed to renewable sources. However, as hydropower schemes are often part of a multipurpose water resources development project, they can often help to finance other components of the project. In addition, hydropower systems and their associated dams and reservoirs provide human well-being benefits, such as flood control and irrigation, and societal benefits such as increased recreational activities and improved navigation. Furthermore, hydropower due to its associated reservoir storage, can provide flexibility and reliability for energy production in integrated energy systems. The storage capability of hydropower systems act as a regulating mechanism by which other intermittent and variable renewable energy sources (wind, wave, solar) can play a larger role in providing electricity of commercial quality. Minimizing water consumption for producing hydropower is critical given that overuse of water for energy production may result in a shortage of water for other purposes such as irrigation, navigation or fish passage. This paper presents a dimensional analysis for finding optimal flow discharge and optimal penstock diameter when designing impulse and reaction water turbines for hydropower systems. The objective of this analysis is to provide general insights for minimizing water consumption when producing hydropower. This analysis is based on the geometric and hydraulic characteristics of the penstock, the total hydraulic head and the desired power production. As part of this analysis, various dimensionless relationships between power production, flow discharge and head losses were derived. These relationships were used to withdraw general insights on determining optimal flow discharge and

  13. Missouri StreamStats—A water-resources web application

    Science.gov (United States)

    Ellis, Jarrett T.

    2018-01-31

    The U.S. Geological Survey (USGS) maintains and operates more than 8,200 continuous streamgages nationwide. Types of data that may be collected, computed, and stored for streamgages include streamgage height (water-surface elevation), streamflow, and water quality. The streamflow data allow scientists and engineers to calculate streamflow statistics, such as the 1-percent annual exceedance probability flood (also known as the 100-year flood), the mean flow, and the 7-day, 10-year low flow, which are used by managers to make informed water resource management decisions, at each streamgage location. Researchers, regulators, and managers also commonly need physical characteristics (basin characteristics) that describe the unique properties of a basin. Common uses for streamflow statistics and basin characteristics include hydraulic design, water-supply management, water-use appropriations, and flood-plain mapping for establishing flood-insurance rates and land-use zones. The USGS periodically publishes reports that update the values of basin characteristics and streamflow statistics at selected gaged locations (locations with streamgages), but these studies usually only update a subset of streamgages, making data retrieval difficult. Additionally, streamflow statistics and basin characteristics are most often needed at ungaged locations (locations without streamgages) for which published streamflow statistics and basin characteristics do not exist. Missouri StreamStats is a web-based geographic information system that was created by the USGS in cooperation with the Missouri Department of Natural Resources to provide users with access to an assortment of tools that are useful for water-resources planning and management. StreamStats allows users to easily obtain the most recent published streamflow statistics and basin characteristics for streamgage locations and to automatically calculate selected basin characteristics and estimate streamflow statistics at ungaged

  14. Testing a community water supply well located near a stream for susceptibility to stream contamination and low-flows.

    Science.gov (United States)

    Stewart-Maddox, N. S.; Tysor, E. H.; Swanson, J.; Degon, A.; Howard, J.; Tsinnajinnie, L.; Frisbee, M. D.; Wilson, J. L.; Newman, B. D.

    2014-12-01

    A community well is the primary water supply to the town of El Rito. This small rural town in is located in a semi-arid, mountainous portion of northern New Mexico where water is scarce. The well is 72 meters from a nearby intermittent stream. Initial tritium sampling suggests a groundwater connection between the stream and well. The community is concerned with the sustainability and future quality of the well water. If this well is as tightly connected to the stream as the tritium data suggests, then the well is potentially at risk due to upstream contamination and the impacts of extended drought. To examine this, we observed the well over a two-week period performing pump and recovery tests, electrical resistivity surveys, and physical observations of the nearby stream. We also collected general chemistry, stable isotope and radon samples from the well and stream. Despite the large well diameter, our pump test data exhibited behavior similar to a Theis curve, but the rate of drawdown decreased below the Theis curve late in the test. This decrease suggests that the aquifer is being recharged, possibly through delayed yield, upwelling of groundwater, or from the stream. The delayed yield hypothesis is supported by our electrical resistivity surveys, which shows very little change in the saturated zone over the course of the pump test, and by low values of pump-test estimated aquifer storativity. Observations of the nearby stream showed no change in stream-water level throughout the pump test. Together this data suggests that the interaction between the stream and the well is low, but recharge could be occurring through other mechanisms such as delayed yield. Additional pump tests of longer duration are required to determine the exact nature of the aquifer and its communication with the well.

  15. The Influence of Geology and Other Environmental Factors on Stream Water Chemistry and Benthic Invertebrate Assemblages

    OpenAIRE

    Olson, John R.

    2012-01-01

    Catchment geology is known to influence water chemistry, which can significantly affect both species composition and ecosystem processes in streams. However, current predictions of how stream water chemistry varies with geology are limited in both scope and precision, and we have not adequately tested the specific mechanisms by which water chemistry influences stream biota. My dissertation research goals were to (1) develop empirical models to predict natural base-flow water chemistry from ca...

  16. Precipitation of metals in produced water : influence on contaminant transport and toxicity

    International Nuclear Information System (INIS)

    Azetsu-Scott, K.; Wohlgeschaffen, G.; Yeats, P.; Dalziel, J.; Niven, S.; Lee, K.

    2006-01-01

    Produced water contains a number of compounds of environmental concern and is the largest volume waste stream from oil and gas production activities. Recent studies have shown that chemicals dissolved in waste water from oil platforms stunted the growth of North Sea cod and affected their breeding patterns. Scientific research is needed to identify the impact of produced water discharges on the environment as well as to identify acceptable disposal limits for produced water. This presentation provided details of a study to characterize produced water discharged within the Atlantic regions of Canada. The study included dose response biological effect studies; research on processes controlling the transport and transformation of contaminants associated with produced water discharges and the development of risk assessment models. The sample location for the study was a site near Sable Island off the coast of Nova Scotia. Chemical analysis of the produced water was conducted as well as toxicity tests. Other tests included a time-series particulate matter sedimentation test; time-series metal and toxicity analysis; time-series change in metal precipitates tests and a produced water/seawater layering experiment. Dissolved and particulate fractions were presented, and the relationship between toxicity and particulate concentrations was examined. Results of the study suggested that produced water contaminants are variable over spatial and temporal scales due to source variations and changes in discharge rates. Chemical changes occur within 24 hours of produced water being mixed with seawater and facilitate contaminant partitioning between the surface micro layer, water column and sediments. Changes in the toxicity of the produced water are correlated with the partitioning of chemical components. The impact zone may be influenced by chemical kinetics that control the distribution of potential toxic metals. Further research is needed to investigate the effects of low level

  17. Widespread occurrence of neonicotinoid insecticides in streams in a high corn and soybean producing region, USA

    Science.gov (United States)

    Hladik, Michelle; Kolpin, Dana W.; Kuivila, Kathryn

    2014-01-01

    Neonicotinoid insecticides are of environmental concern, but little is known about their occurrence in surface water. An area of intense corn and soybean production in the Midwestern United States was chosen to study this issue because of the high agricultural use of neonicotinoids via both seed treatments and other forms of application. Water samples were collected from nine stream sites during the 2013 growing season. The results for the 79 water samples documented similar patterns among sites for both frequency of detection and concentration (maximum:median) with clothianidin (75%, 257 ng/L:8.2 ng/L) > thiamethoxam (47%, 185 ng/L: imidacloprid (23%, 42.7 ng/L: <2 ng/L). Neonicotinoids were detected at all nine sites sampled even though the basin areas spanned four orders of magnitude. Temporal patterns in concentrations reveal pulses of neonicotinoids associated with rainfall events during crop planting, suggesting seed treatments as their likely source.

  18. Widespread occurrence of neonicotinoid insecticides in streams in a high corn and soybean producing region, USA

    Science.gov (United States)

    Hladik, Michelle; Kolpin, Dana W.; Kuivila, Kathryn

    2014-01-01

    Neonicotinoid insecticides are of environmental concern, but little is known about their occurrence in surface water. An area of intense corn and soybean production in the Midwestern United States was chosen to study this issue because of the high agricultural use of neonicotinoids via both seed treatments and other forms of application. Water samples were collected from nine stream sites during the 2013 growing season. The results for the 79 water samples documented similar patterns among sites for both frequency of detection and concentration (maximum:median) with clothianidin (75%, 257 ng/L:8.2 ng/L) > thiamethoxam (47%, 185 ng/L: imidacloprid (23%, 42.7 ng/L: treatments as their likely source.

  19. Interactions between hyporheic flow produced by stream meanders, bars, and dunes

    Science.gov (United States)

    Stonedahl, Susa H.; Harvey, Judson W.; Packman, Aaron I.

    2013-01-01

    Stream channel morphology from grain-scale roughness to large meanders drives hyporheic exchange flow. In practice, it is difficult to model hyporheic flow over the wide spectrum of topographic features typically found in rivers. As a result, many studies only characterize isolated exchange processes at a single spatial scale. In this work, we simulated hyporheic flows induced by a range of geomorphic features including meanders, bars and dunes in sand bed streams. Twenty cases were examined with 5 degrees of river meandering. Each meandering river model was run initially without any small topographic features. Models were run again after superimposing only bars and then only dunes, and then run a final time after including all scales of topographic features. This allowed us to investigate the relative importance and interactions between flows induced by different scales of topography. We found that dunes typically contributed more to hyporheic exchange than bars and meanders. Furthermore, our simulations show that the volume of water exchanged and the distributions of hyporheic residence times resulting from various scales of topographic features are close to, but not linearly additive. These findings can potentially be used to develop scaling laws for hyporheic flow that can be widely applied in streams and rivers.

  20. Performance of the air2stream model that relates air and stream water temperatures depends on the calibration method

    Science.gov (United States)

    Piotrowski, Adam P.; Napiorkowski, Jaroslaw J.

    2018-06-01

    A number of physical or data-driven models have been proposed to evaluate stream water temperatures based on hydrological and meteorological observations. However, physical models require a large amount of information that is frequently unavailable, while data-based models ignore the physical processes. Recently the air2stream model has been proposed as an intermediate alternative that is based on physical heat budget processes, but it is so simplified that the model may be applied like data-driven ones. However, the price for simplicity is the need to calibrate eight parameters that, although have some physical meaning, cannot be measured or evaluated a priori. As a result, applicability and performance of the air2stream model for a particular stream relies on the efficiency of the calibration method. The original air2stream model uses an inefficient 20-year old approach called Particle Swarm Optimization with inertia weight. This study aims at finding an effective and robust calibration method for the air2stream model. Twelve different optimization algorithms are examined on six different streams from northern USA (states of Washington, Oregon and New York), Poland and Switzerland, located in both high mountains, hilly and lowland areas. It is found that the performance of the air2stream model depends significantly on the calibration method. Two algorithms lead to the best results for each considered stream. The air2stream model, calibrated with the chosen optimization methods, performs favorably against classical streamwater temperature models. The MATLAB code of the air2stream model and the chosen calibration procedure (CoBiDE) are available as Supplementary Material on the Journal of Hydrology web page.

  1. Effects of water removal on a Hawaiian stream ecosystem

    Science.gov (United States)

    Kinzie, R. A.; Chong, C.; Devrell, J.; Lindstrom, D.; Wolff, R.

    2006-01-01

    A 3-year study of Wainiha River on Kaua'i, Hawai'i, was carried out to determine the impact that water removal had on key stream ecosystem parameters and functions. The study area included a diversion dam for a hydroelectric plant that removes water at an elevation of 213 m and returns it to the stream about 6 km downstream at an elevation of 30 m. There were two high-elevation sites, one with undiverted flow and one with reduced flow, and two low-elevation sites, one with reduced flow and one with full flow restored. Monthly samples were taken of instream and riparian invertebrates and plants. When samples from similar elevations were compared, dewatered sites had lower concentrations of benthic photosynthetic pigments than full-flow sites, and benthic ash-free dry mass (AFDM) was higher at the two low-elevation sites regardless of flow. Benthic chlorophyll a (chl a) and AFDM were higher in summer months than in the winter. Benthic invertebrate abundance was highest at the full-flow, low-elevation site and benthic invertebrate biomass was highest at the full-flow, high-elevation site. Season had only marginal effects on abundance and biomass of benthic invertebrates. Diversity of benthic invertebrates was higher at the more-downstream sites. Abundance of drifting invertebrates was highest at the site above the diversion dam and generally higher in winter than in summer months. Biomass of drifting invertebrates was also highest at the above-dam site but there was little seasonal difference. Almost all parameters measured were lowest at the site just downstream of the diversion dam. The biotic parameters responded only weakly to flows that had occurred up to 1 month before the measurements were made. Flow, elevation, and season interact in complex ways that impact ecosystem parameters and functions, but water diversion can override all these environmental factors. ?? 2006 by University of Hawai'i Press All rights reserved.

  2. Physical and Chemical Connectivity of Streams and Riparian Wetlands to Downstream Waters: A Synthesis

    Science.gov (United States)

    Streams, riparian areas, floodplains, alluvial aquifers, and downstream waters (e.g., large rivers, lakes, and oceans) are interconnected by longitudinal, lateral, and vertical fluxes of water, other materials, and energy. Collectively, these interconnected waters are called fluv...

  3. Spatio-temporal variation in stream water chemistry in a tropical urban watershed

    Science.gov (United States)

    A. Ramirez; K.G. Rosas; A.E. Lugo; O.M. Ramos-Gonzalez

    2014-01-01

    Urban activities and related infrastructure alter the natural patterns of stream physical and chemical conditions. According to the Urban Stream Syndrome, streams draining urban landscapes are characterized by high concentrations of nutrients and ions, and might have elevated water temperatures and variable oxygen concentrations. Here, we report temporal and spatial...

  4. Changes in Stream Water Temperatures in the Chesapeake Bay Region, 1960-2014

    Science.gov (United States)

    This map shows the changes in stream water temperatures in the Chesapeake Bay region from 1960 to 2014. Blue circles represent cooling trends in stream water temperatures, and red circles represent warming trends in stream water temperatures. Data were analyzed by Mike Kolian of EPA in partnership with John Jastram and Karen Rice of the U.S. Geological Survey. For more information: www.epa.gov/climatechange/science/indicators

  5. Troubled Waters: where Multiple Streams of Inequality Converge in the Math and Science Experiences of Nonprivileged Girls

    Science.gov (United States)

    Parrott, Laurel; Spatig, Linda; Kusimo, Patricia S.; Carter, Carolyn C.; Keyes, Marian

    Water is often hardest to navigate at the confluence of individual streams. As they experience math and science, nonprivileged girls maneuver through roiling waters where the streams of gender, ethnicity, poverty, place, and teaching practices converge. Just as waters of separate streams blend, these issues - too often considered separate factors - become blended and difficult to isolate, and the resulting turbulence produces a bumpy ride. We draw on 3 years of qualitative data collected as part of an intervention program to explore the math and science experiences and perceptions of a group of ethnically diverse, low socioeconomic status rural and urban adolescent Appalachian girls. After describing program and community contexts, we explore "opportunity to leant" issues - specifically, expectations, access to content, and support networks - and examine their schooling experiences against visions of science and math reform and pressures for accountability. Data are discussed within a framework of critical educational theory.

  6. Assessing the impact of groundwater contamination on stream water quality by multiple approaches at the groundwater-surface water interface (Invited Presentation)

    DEFF Research Database (Denmark)

    Bjerg, Poul Løgstrup; Rønde, Vinni Kampman; Balbarini, Nicola

    Contaminants such as chlorinated solvents and pesticides, as well as new classes of compounds or emerging micropollutants are extensively produced, utilized and then discarded in society and subsequently released to streams from multiple point and diffuse sources. Sustainable management of water...

  7. TREATMENT OF PRODUCED OIL AND GAS WATERS WITH SURFACTANT-MODIFIED ZEOLITE

    Energy Technology Data Exchange (ETDEWEB)

    Lynn E. Katz; R.S. Bowman; E.J. Sullivan

    2003-11-01

    Co-produced water from the oil and gas industry accounts for a significant waste stream in the United States. It is by some estimates the largest single waste stream in the country, aside from nonhazardous industrial wastes. Characteristics of produced water include high total dissolved solids content, dissolved organic constituents such as benzene and toluene, an oil and grease component, and chemicals added during the oil-production process. While most of the produced water is disposed via reinjection, some must be treated to remove organic constituents before the water is discharged. Current treatment options are successful in reducing the organic content; however, they cannot always meet the levels of current or proposed regulations for discharged water. Therefore, an efficient, cost-effective treatment technology is needed. Surfactant-modified zeolite (SMZ) has been used successfully to treat contaminated ground water for organic and inorganic constituents. In addition, the low cost of natural zeolites makes their use attractive in water-treatment applications. This report summarizes the work and results of this four-year project. We tested the effectiveness of surfactant-modified zeolite (SMZ) for removal of BTEX with batch and column experiments using waters with BTEX concentrations that are comparable to those of produced waters. The data from our experimental investigations showed that BTEX sorption to SMZ can be described by a linear isotherm model, and competitive effects between compounds were not significant. The SMZ can be readily regenerated using air stripping. We field-tested a prototype SMZ-based water treatment system at produced water treatment facilities and found that the SMZ successfully removes BTEX from produced waters as predicted by laboratory studies. When compared to other existing treatment technologies, the cost of the SMZ system is very competitive. Furthermore, the SMZ system is relatively compact, does not require the storage of

  8. Watershed features and stream water quality: Gaining insight through path analysis in a Midwest urban landscape, USA

    Science.gov (United States)

    Jiayu Wu; Timothy W. Stewart; Janette R. Thompson; Randy Kolka; Kristie J. Franz

    2015-01-01

    Urban stream condition is often degraded by human activities in the surrounding watershed. Given the complexity of urban areas, relationships among variables that cause stream degradation can be difficult to isolate. We examined factors affecting stream condition by evaluating social, terrestrial, stream hydrology and water quality variables from 20 urban stream...

  9. Predicting Hyporheic Exchange of Water and Solutes in Streams on the Basis of a Priori Estimates of Stream Physical Characteristics

    Science.gov (United States)

    Stone, S. H.; Harvey, J.; Packman, A.; Worman, A.

    2005-12-01

    It is very important to accurately model solute transport in rivers in order to analyze contaminant transport, water quality, and a variety of ecological processes. The purpose of this research is to determine the physical characteristics of a stream or river that are sufficient to predict hyporheic exchange and downstream solute transport. In the fall of 2004, we conducted a bromide tracer injection and made physical measurements in Sugar Creek, a small agricultural stream in northwestern Indiana. As is typical for small mid-western agricultural streams, Sugar Creek has been ditched and straightened, and subsequent downcutting through glacial sediments and slumpage of bank sediments composed of finer grain sizes has created a stream of intermediate complexity. In order to relate the observed solute transport to more basic physical characteristics of the stream, we determined the bathymetry of Sugar Creek over a wide range of scales (centimeters to decameters), and measured velocity profiles, the water elevation surface profile, hydraulic conductivity via in situ measurements, and bed sediment grain size distributions throughout the study reach. Our most detailed topographic measurements revealed fine scale bed variations with wavelengths on the order of ten centimeters, while surveying of the entire study reach characterized large scale meanders with wavelengths on the order of five meters. The distribution of wavelengths influences the driving forces that cause solute to enter the bed and banks. Hydraulic conductivity determines the resistance to flow of stream water through the (meander) stream banks and streambed. We used a scaling approach to relate the geometric and hydrogeologic characteristics of the stream to solute transport and also applied a new analytical solution for the subsurface flows resulting from topographic variations over a wide range of spatial scales. These models captured the main features of the observed solute transport. The greatest

  10. National water summary 1990-91: Hydrologic events and stream water quality

    Science.gov (United States)

    Paulson, Richard W.; Chase, Edith B.; Williams, John S.; Moody, David W.

    1993-01-01

    National Water Summary 1990-91 Hydrologic Events and Stream Water Quality was planned to complement existing Federal-State water-quality reporting to the U.S. Congress that is required by the Clean Water Act of 1972. This act, formally known as the Federal Water Pollution Control Act Amendments of 1972 (Public Law 92-500), and its amendments in 1977,1979,1980,1981,1983, and 1987, is the principal basis for Federal-State cooperation on maintaining and reporting on water quality in the United States. Under section 305(b) of the Clean Water Act, the States must designate uses for waterbodies, biennially assess whether the waterbodies meet designated uses, and report to the U.S. Environmental Protection Agency (EPA), which in turn summarizes the findings of the State assessments in a biennial National Water Quality Inventory report to the Congress.

  11. Produced Water Treatment Using the Switchable Polarity Solvent Forward Osmosis (SPS FO) Desalination Process: Preliminary Engineering Design Basis

    Energy Technology Data Exchange (ETDEWEB)

    Wendt, Daniel; Adhikari, Birendra; Orme, Christopher; Wilson, Aaron

    2016-05-01

    Switchable Polarity Solvent Forward Osmosis (SPS FO) is a semi-permeable membrane-based water treatment technology. INL is currently advancing SPS FO technology such that a prototype unit can be designed and demonstrated for the purification of produced water from oil and gas production operations. The SPS FO prototype unit will used the thermal energy in the produced water as a source of process heat, thereby reducing the external process energy demands. Treatment of the produced water stream will reduce the volume of saline wastewater requiring disposal via injection, an activity that is correlated with undesirable seismic events, as well as generate a purified product water stream with potential beneficial uses. This paper summarizes experimental data that has been collected in support of the SPS FO scale-up effort, and describes how this data will be used in the sizing of SPS FO process equipment. An estimate of produced water treatment costs using the SPS FO process is also provided.

  12. Towards benchmarking an in-stream water quality model

    Directory of Open Access Journals (Sweden)

    2007-01-01

    Full Text Available A method of model evaluation is presented which utilises a comparison with a benchmark model. The proposed benchmarking concept is one that can be applied to many hydrological models but, in this instance, is implemented in the context of an in-stream water quality model. The benchmark model is defined in such a way that it is easily implemented within the framework of the test model, i.e. the approach relies on two applications of the same model code rather than the application of two separate model codes. This is illustrated using two case studies from the UK, the Rivers Aire and Ouse, with the objective of simulating a water quality classification, general quality assessment (GQA, which is based on dissolved oxygen, biochemical oxygen demand and ammonium. Comparisons between the benchmark and test models are made based on GQA, as well as a step-wise assessment against the components required in its derivation. The benchmarking process yields a great deal of important information about the performance of the test model and raises issues about a priori definition of the assessment criteria.

  13. Macro Invertebrates As Bio Indicators Of Water Quality In Nzovwe Stream In Mbeya Tanzania

    Directory of Open Access Journals (Sweden)

    Fredrick Ojija

    2015-08-01

    Full Text Available This study was carried out to assess the water quality of Nzovwe stream using macroinvertebrates as bioindicators. Biological monitoring working party BMWP scoring system was the index used to assess the ecosystem health of Nzovwe stream. A total of 584 aquatic macroinvertebrates were identified from Nzovwe stream. They belonged to 22 families. The most abundant taxa were Odonata 35.959 Hemiptera 25.514 Coleoptera 18.493 and Diptera 12.842. Whereas the least abundant taxa were Ephemeroptera and Gastropoda each constituting 1.028 of all macroinvertebrates. The most abundant macroinvertebrates were Dragonflies 27.226 Water striders 13.185 and Creeping water bugs 10.274 whereas the least abundant were Giant water bugs 0.514 and Backswimmers 0.514. The BMWP score of Nzovwe stream was 115. Based on this score the water of Nzovwe stream is neither very clean nor significantly altered aquatic environment. Hence the Nzovwe stream is moderately polluted due to non-point source pollution from several sources. Moreover it was found that agricultural activities washing and bathing could alter physico-chemical parameters of the stream and hence changing the abundance of macroinvertebrates as well as the quality of water. This study therefore recommends that the source of pollutants should be controlled and the stream regularly monitored by the relevant authorities. Additionally biological indicators and their indices are suggested to be used in assessing the condition of a stream ecosystem.

  14. Tekna's produced water conference 2005

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    2005-07-01

    The conference has 22 presentations discussing topics on discharge reduction, produced water quality, produced water re-injection, chemicals particularly environmentally friendly ones, separation technology, reservoir souring, total water management systems, pollution, oil in water problems and platform operation. Various field tests and experiences particularly from the offshore petroleum sector are presented (tk)

  15. The Role of Riparian Vegetation in Protecting and Improving Chemical Water Quality in Streams

    Science.gov (United States)

    Michael G. Dosskey; Philippe Vidon; Noel P. Gurwick; Craig J. Allan; Tim P. Duval; Richard Lowrance

    2010-01-01

    We review the research literature and summarize the major processes by which riparian vegetation influences chemical water quality in streams, as well as how these processes vary among vegetation types, and discuss how these processes respond to removal and restoration of riparian vegetation and thereby determine the timing and level of response in stream water quality...

  16. STREAM

    DEFF Research Database (Denmark)

    Godsk, Mikkel

    This paper presents a flexible model, ‘STREAM’, for transforming higher science education into blended and online learning. The model is inspired by ideas of active and collaborative learning and builds on feedback strategies well-known from Just-in-Time Teaching, Flipped Classroom, and Peer...... Instruction. The aim of the model is to provide both a concrete and comprehensible design toolkit for adopting and implementing educational technologies in higher science teaching practice and at the same time comply with diverse ambitions. As opposed to the above-mentioned feedback strategies, the STREAM...... model supports a relatively diverse use of educational technologies and may also be used to transform teaching into completely online learning. So far both teachers and educational developers have positively received the model and the initial design experiences show promise....

  17. The application and testing of diatom-based indices of stream water ...

    African Journals Online (AJOL)

    The application and testing of diatom-based indices of stream water quality in Chinhoyi Town, Zimbabwe. ... PROMOTING ACCESS TO AFRICAN RESEARCH ... test the applicability of foreign diatom-based water quality assessment indices to ...

  18. Review of produced water recycle and beneficial reuse

    Energy Technology Data Exchange (ETDEWEB)

    Hum, F.; Tsang, P. [Calgary Univ., AB (Canada). Tomographic Imaging and Porous Media Laboratory; Harding, T. [Calgary Univ., AB (Canada). Dept. of Chemical and Petroleum Engineering; Kantzas, A. [Calgary Univ., AB (Canada). Tomographic Imaging and Porous Media Laboratory]|[Calgary Univ., AB (Canada). Dept. of Chemical and Petroleum Engineering

    2006-11-15

    Fresh water scarcity and increasing water demands are concerns facing jurisdictions around the world. A number of water management initiatives involving produced water recycling and reuse in Alberta and Canada will have a significant impact on sustainable development in Alberta. Produced water must first be treated to meet water quality requirements and regulatory guidelines for specific applications. This paper presented a comprehensive technical and economic review of commercially available water treatment technologies and discussed technical challenges in recycling produced water for steam generation and for commercial use. It provided an introduction to fresh water allocations and oil, gas and water production volumes in Alberta. In addition to research and development activities, the paper identified guidelines from Alberta Environment and the Energy and Utilities Board. Benefits of treated produced water were discussed. Desalination technologies include both distillation processes and membrane processes. The paper provided cost estimates based on a literature view and discussed the potential water treatment for south-east Alberta. The paper also offered a number of recommendations for further research. It was concluded that treating and recycling produced water for agriculture, irrigation, commercial and domestic uses are at early stages of research and development and that regulatory guidelines on water quality, health and safety for specific industries, ownership and transfer of produced water need to be developed in order to facilitate beneficial reuse of produced water. 57 refs., 7 tabs., 14 figs.

  19. Pasture size effects on the ability of off-stream water or restricted stream access to alter the spatial/temporal distribution of grazing beef cows.

    Science.gov (United States)

    Bisinger, J J; Russell, J R; Morrical, D G; Isenhart, T M

    2014-08-01

    For 2 grazing seasons, effects of pasture size, stream access, and off-stream water on cow distribution relative to a stream were evaluated in six 12.1-ha cool-season grass pastures. Two pasture sizes (small [4.0 ha] and large [12.1 ha]) with 3 management treatments (unrestricted stream access without off-stream water [U], unrestricted stream access with off-stream water [UW], and stream access restricted to a stabilized stream crossing [R]) were alternated between pasture sizes every 2 wk for 5 consecutive 4-wk intervals in each grazing season. Small and large pastures were stocked with 5 and 15 August-calving cows from mid May through mid October. At 10-min intervals, cow location was determined with Global Positioning System collars fitted on 2 to 3 cows in each pasture and identified when observed in the stream (0-10 m from the stream) or riparian (0-33 m from the stream) zones and ambient temperature was recorded with on-site weather stations. Over all intervals, cows were observed more (P ≤ 0.01) frequently in the stream and riparian zones of small than large pastures regardless of management treatment. Cows in R pastures had 24 and 8% less (P cows in or near pasture streams regardless of pasture size. In 2011, the probability of cow presence in the stream and riparian zones increased at greater (P cow presence in the stream and riparian zones increased at greater (P cow presence in the stream and riparian zone increased less (P cow presence in shade (within 10 m of tree drip lines) in the total pasture with increasing temperatures did not differ between treatments. However, probability of cow presence in riparian shade increased at greater (P cows in or near pasture streams with unrestricted access.

  20. Air - water temperature relationships in the trout streams of southeastern Minnesota’s carbonate - sandstone landscape

    Science.gov (United States)

    Krider, Lori A.; Magner, Joseph A.; Perry, Jim; Vondracek, Bruce C.; Ferrington, Leonard C.

    2013-01-01

    Carbonate-sandstone geology in southeastern Minnesota creates a heterogeneous landscape of springs, seeps, and sinkholes that supply groundwater into streams. Air temperatures are effective predictors of water temperature in surface-water dominated streams. However, no published work investigates the relationship between air and water temperatures in groundwater-fed streams (GWFS) across watersheds. We used simple linear regressions to examine weekly air-water temperature relationships for 40 GWFS in southeastern Minnesota. A 40-stream, composite linear regression model has a slope of 0.38, an intercept of 6.63, and R2 of 0.83. The regression models for GWFS have lower slopes and higher intercepts in comparison to surface-water dominated streams. Regression models for streams with high R2 values offer promise for use as predictive tools for future climate conditions. Climate change is expected to alter the thermal regime of groundwater-fed systems, but will do so at a slower rate than surface-water dominated systems. A regression model of intercept vs. slope can be used to identify streams for which water temperatures are more meteorologically than groundwater controlled, and thus more vulnerable to climate change. Such relationships can be used to guide restoration vs. management strategies to protect trout streams.

  1. Process for the exchange of hydrogen isotopes between streams of liquid water and gaseous halohydrocarbon and an apparatus therefor

    International Nuclear Information System (INIS)

    Symons, E.A.; Rolston, J.H.; Clermont, M.J.; Paterson, L.M.

    1983-01-01

    This invention provides a process for the exchange of hydrogen isotopes between streams of liquid water and gaseous halohydrocarbons comprising: (a) bringing into contact a water stream, a halohydrocarbon stream, and a catalytic porous anion exchange resin so that the isotope-deficient halohydrocarbon stream is enriched; (b) decomposing the halohydrocarbon stream photolytically into two gaseous streams, one enriched and the other deficient; (c) removing as a product the first, enriched stream; and (d) recycling the second stream for enrichment. An apparatus is also provided

  2. Mapping spatial and temporal variation of stream water temperature in the upper Esopus Creek watershed

    Science.gov (United States)

    Chien, H.; McGlinn, L.

    2017-12-01

    The upper Esopus Creek and its tributary streams located in the Catskill Mountain region of New York State provide habitats for cold-adapted aquatic species. However, ongoing global warming may change the stream water temperature within a watershed and disturb the persistence of coldwater habitats. Characterizing thermal regimes within the upper Esopus Creek watershed is important to provide information of thermally suitable habitats for aquatic species. The objectives of this study are to measure stream water temperature and map thermal variability among tributaries to the Esopus Creek and within Esopus Creek. These objectives will be achieved by measuring stream water temperature for at least two years. More than 100 water temperature data loggers have been placed in the upper Esopus Creek and their tributaries to collect 30-minute interval water temperatures. With the measured water temperature, we will use spatial interpolation in ArcGIS to create weekly and monthly water temperature surface maps to evaluate the thermal variation over time and space within the upper Esopus Creek watershed. We will characterize responsiveness of water temperature in tributary streams to air temperature as well. This information of spatial and temporal variation of stream water temperature will assist stream managers with prioritizing management practices that maintain or enhance connectivity of thermally suitable habitats in high priority areas.

  3. Removal of organic pollutants from produced water using Fenton oxidation

    Directory of Open Access Journals (Sweden)

    Afzal Talia

    2018-01-01

    Full Text Available Produced water (PW is the largest stream of wastewater from oil and gas exploration. It is highly polluted and requires proper treatment before disposal. The main objective of this study was to investigate the effectiveness of Fenton oxidation in degradation of organic matter in PW. The role of operating factors viz., H2O2 concentration (0.12 × 10-3 moles/L to 3 moles/L, [H2O2]/[Fe2+] molar ratio (2 to 75, and reaction time (30 to 200 minutes, on COD removal was determined through a series of batch experiments conducted in acidic environment at room temperature. The experiments were conducted with 500 mL PW samples in 1L glass beakers covered on the outside with aluminum foil to protect them from sunlight. Pre-decided amounts of ferrous sulfate heptahydrate (FeSO4.7H2O and hydrogen peroxide (H2O2 were added to initiate the Fenton reaction. An increase in COD removal was observed with increase in reaction time and [H2O2]/[Fe2+] molar ratio. COD removal also increased with H2O2 concentration up to 0.01 moles/L; further increase in H2O2 concentration decreased the COD removal efficiency. Over 90% COD removal was achieved under optimum reaction conditions. The study indicates that Fenton oxidation is effective for remediation of PW in terms of organic matter removal.

  4. Removal of organic pollutants from produced water using Fenton oxidation

    Science.gov (United States)

    Afzal, Talia; Hasnain Isa, Mohamed; Mustafa, Muhammad Raza ul

    2018-03-01

    Produced water (PW) is the largest stream of wastewater from oil and gas exploration. It is highly polluted and requires proper treatment before disposal. The main objective of this study was to investigate the effectiveness of Fenton oxidation in degradation of organic matter in PW. The role of operating factors viz., H2O2 concentration (0.12 × 10-3 moles/L to 3 moles/L), [H2O2]/[Fe2+] molar ratio (2 to 75), and reaction time (30 to 200 minutes), on COD removal was determined through a series of batch experiments conducted in acidic environment at room temperature. The experiments were conducted with 500 mL PW samples in 1L glass beakers covered on the outside with aluminum foil to protect them from sunlight. Pre-decided amounts of ferrous sulfate heptahydrate (FeSO4.7H2O) and hydrogen peroxide (H2O2) were added to initiate the Fenton reaction. An increase in COD removal was observed with increase in reaction time and [H2O2]/[Fe2+] molar ratio. COD removal also increased with H2O2 concentration up to 0.01 moles/L; further increase in H2O2 concentration decreased the COD removal efficiency. Over 90% COD removal was achieved under optimum reaction conditions. The study indicates that Fenton oxidation is effective for remediation of PW in terms of organic matter removal.

  5. Dry Stream Reaches in Carbonate Terranes: Surface Indicators of Ground-Water Reservoirs

    Science.gov (United States)

    Brahana, J.V.; Hollyday, E.F.

    1988-01-01

    In areas where dry stream reaches occur, subsurface drainage successfully competes with surface drainage, and sheet-like dissolution openings have developed parallel to bedding creating the ground-water reservoir. Union Hollow in south-central Tennessee is the setting for a case study that illustrates the application of the dry stream reach technique. In this technique, dry stream reach identification is based on two types of readily acquired information: remotely sensed black and white infrared aerial photography; and surface reconnaissance of stream channel characteristics. Test drilling in Union Hollow subsequent to identification of the dry reach proved that a localized ground-water reservoir was present.

  6. Long-term biomonitoring of a produced water discharge from the Cedar Cove degasification field, Alabama. January 1991

    Energy Technology Data Exchange (ETDEWEB)

    O' Neil, P.E.; Harris, S.C.; Mettee, M.F.; McGregor, S.W.; Shepard, T.E.

    1991-01-01

    Development of coalbed methane has become a major industry for the state of Alabama. In excess of 1,300 wells were producing methane by the end of July 1990. A byproduct of methane production is produced water containing elevated concentrations of chloride, sodium, iron and bicarbonate. These waters are currently permitted for discharge into streams or as a land application. The purpose of the study was to examine the long-term impacts of produced waters to streams relative to water-quality changes and aquatic biological effects. Distinct water-quality changes in the receiving stream were documented and consisted primarily of increased dissolved solids, changes in the pH regime and changes in the carbonate buffering system. In contrast, no significant or consistent detrimental change in the structure or function of the stream biological community could be detected. Subtle changes in biological community structure and composition were noted and most likely due to effects associated with algal productivity in settling lagoons. These changes, however, were within the boundaries of variation typically observed for the communities. Based on the results of this and earlier studies, it was concluded that the national water-quality criterion for chloride was protective of stream life as examined in the study.

  7. Olfactory responses to natal stream water in sockeye salmon by BOLD fMRI.

    Directory of Open Access Journals (Sweden)

    Hiroshi Bandoh

    Full Text Available Many studies have shown that juvenile salmon imprint olfactory memory of natal stream odors during downstream migration, and adults recall this stream-specific odor information to discriminate their natal stream during upstream migration for spawning. The odor information processing of the natal stream in the salmon brain, however, has not been clarified. We applied blood oxygenation level-dependent (BOLD functional magnetic resonance imaging to investigate the odor information processing of the natal stream in the olfactory bulb and telencephalon of lacustrine sockeye salmon (Oncorhynchus nerka. The strong responses to the natal stream water were mainly observed in the lateral area of dorsal telencephalon (Dl, which are homologous to the medial pallium (hippocampus in terrestrial vertebrates. Although the concentration of L-serine (1 mM in the control water was 20,000-times higher than that of total amino acid in the natal stream water (47.5 nM, the BOLD signals resulting from the natal stream water were stronger than those by L-serine in the Dl. We concluded that sockeye salmon could process the odor information of the natal stream by integrating information in the Dl area of the telencephalon.

  8. Multimedia applications in nursing curriculum: the process of producing streaming videos for medication administration skills.

    Science.gov (United States)

    Sowan, Azizeh K

    2014-07-01

    Streaming videos (SVs) are commonly used multimedia applications in clinical health education. However, there are several negative aspects related to the production and delivery of SVs. Only a few published studies have included sufficient descriptions of the videos and the production process and design innovations. This paper describes the production of innovative SVs for medication administration skills for undergraduate nursing students at a public university in Jordan and focuses on the ethical and cultural issues in producing this type of learning resource. The curriculum development committee approved the modification of educational techniques for medication administration procedures to include SVs within an interactive web-based learning environment. The production process of the videos adhered to established principles for "protecting patients' rights when filming and recording" and included: preproduction, production and postproduction phases. Medication administration skills were videotaped in a skills laboratory where they are usually taught to students and also in a hospital setting with real patients. The lab videos included critical points and Do's and Don'ts and the hospital videos fostered real-world practices. The range of time of the videos was reasonable to eliminate technical difficulty in access. Eight SVs were produced that covered different types of the medication administration skills. The production of SVs required the collaborative efforts of experts in IT, multimedia, nursing and informatics educators, and nursing care providers. Results showed that the videos were well-perceived by students, and the instructors who taught the course. The process of producing the videos in this project can be used as a valuable framework for schools considering utilizing multimedia applications in teaching. Copyright © 2014 Elsevier Ireland Ltd. All rights reserved.

  9. Pollution Impact and Alternative Treatment for Produced Water

    Directory of Open Access Journals (Sweden)

    Hedar Yusran

    2018-01-01

    Full Text Available Oil and gas exploration and production are two of the activities that potentially cause pollution and environmental damage. The largest waste generated from this activity is produced water. Produced water contains hazardous pollutants of both organic and inorganic materials, so that the produced water of oil and gas production cannot be discharged directly to the environment. Uncontrolled discharge can lead to the environmental damage, killing the life of water and plants. The produced water needs to be handled and fulfill the quality standards before being discharged to the environment. Several studies to reduce the contaminants in the produced water were conducted by researchers. Among them were gravity based separation - flotation, separation technique based on filtration, and biological process treatment. Therefore, some of these methods can be used as an alternative waste handling of produced water.

  10. Pollution Impact and Alternative Treatment for Produced Water

    Science.gov (United States)

    Hedar, Yusran; Budiyono

    2018-02-01

    Oil and gas exploration and production are two of the activities that potentially cause pollution and environmental damage. The largest waste generated from this activity is produced water. Produced water contains hazardous pollutants of both organic and inorganic materials, so that the produced water of oil and gas production cannot be discharged directly to the environment. Uncontrolled discharge can lead to the environmental damage, killing the life of water and plants. The produced water needs to be handled and fulfill the quality standards before being discharged to the environment. Several studies to reduce the contaminants in the produced water were conducted by researchers. Among them were gravity based separation - flotation, separation technique based on filtration, and biological process treatment. Therefore, some of these methods can be used as an alternative waste handling of produced water.

  11. Use of stream water pH and specific conductance measurements to identify ground water discharges of fly ash leachate

    International Nuclear Information System (INIS)

    Price, R.M.

    1992-01-01

    Low pH and high specific conductance are typical chemical characteristics of coal fly ash leachate. Measurements of these parameters in streams adjacent to a fly ash facility were used to identify areas of ground water discharge into the streams. In-situ specific conductance and pH were determined at approximately 50 surface water stations from on-site and off-site streams. The results of the in-situ determinations were used to select twelve surface water stations for more detailed chemical analyses. The chemical character of the stream water affected by ground water discharges was similar to the water quality of sedimentation ponds which received drainage from the fly ash embankment. The results indicated that in-situ measurements of indicator parameters such as pH and specific conductance can be used as a screening method for identifying surface water quality impacts at fly ash facilities

  12. Characteristics and applications of ion streams produced by long-pulse lasers

    International Nuclear Information System (INIS)

    Rohlena, K.; Laska, L.; Jungwirth, K.; Krasa, J.; Krousky, E.; Masek, M.; Pleifer, M.; Ullschmied, J.; Badziak, J.; Parys, P.; Wolowski, J.; Gammino, S.; Torrisi, L.; Boody, F. P.

    2005-01-01

    If a laser plasma generated on a target with a high Z if left to expand it becomes a very efficient source of highly charged ions. Depending on the parameters of the laser driver, ions with charge states from 1+up to more than 50+can be produced, with ion energies ranging from tens of eV up to tens of MeV, with no external acceleration. The ion current density may reach tens of mA/cm''3 at a distance of 1 m from the target. they can be used either for a direct to accelerator injection, for a hybrid ion source based on coupling of a laser with an Electron Cyclotron Resonance Ion Source for easier evaporation and pre-ionisation of the target material and a subsequent charge state enhancement, or for a direct ion implantation. As substrates for the implantation metallic and polymer materials are usually exposed to the laser produced ion streams with an appropriate tuning of the implantation regime to modify their surface properties. Although the interaction of the laser beam with the plasma is a fairly complex process certain fundamental phenomena have been identified based on a careful analysis of the charge-energy spectra of the outgoing ion streams. The most striking feature is a multi peak structure of the energy spectra suggesting the presence of several fast electron groups guiding the plasma expansion and assisting the charge freezing by its acceleration. On the other hand, an inherent asymmetry of the ion spectra with respect to the laser caustic can be interpreted as the onset of self focusing of the heating laser-beam inside the self-created plasma of the developing laser corona (or a pre-pulse plasma either formed by an engineered double pulse or generated spontaneously in the case of an unduly bad contrast of the heating pulse) with a dramatic increase in the power density impinging on the target. Experimental and theoretical arguments are given in support of this notion, which was first advanced by Hora. (Author)

  13. Biological responses to acidification reversal in Cumbrian streamwaters - stream water chemistry

    Energy Technology Data Exchange (ETDEWEB)

    Tipping, E.; Hardie, D.J.; Lawlor, A.J.; Lofts, S.; Simon, B.M.; Vincent, C.D. [Institute of Freshwater Ecology, Ambleside (United Kingdom)

    1999-07-01

    This reports summarises the findings of a study sampling the streams for invertebrates and comparing the results with those made in the 1960s and 1970s, The distribution of the bacterium Cytophaga was examined, and the results of the chemical analysis of the stream waters were compared with the results from previous years. The background to the study is traced, and details of the sampling and chemical analysis are given. Evidence of the reversal of acidification in the streams is considered.

  14. Oilfield Produced Water Reuse and Reinjection with Membrane

    Directory of Open Access Journals (Sweden)

    Siagian Utjok W.R.

    2018-01-01

    Full Text Available Produced water has become a global environmental issue due to its huge volume and toxicity that may pose detrimental effects on receiving environment. Several approaches have been proposed to provide a strategy for produced water handling such as reinjection, reuse, or discharge. With various advantages, membrane technology has been increasingly used in produced water treatment replacing the conventional technologies. However, fouling is a major drawback of membrane processes in this application which needs to be controlled. This paper gives an overview and comparison of different produced water management. Special attention is given to produced water treatment for reuse purpose. Furthermore, the use of membrane processes in produced water reuse including performance, challenges, and future outlook are discussed.

  15. Channel water balance and exchange with subsurface flow along a mountain headwater stream in Montana, United States

    Science.gov (United States)

    R.A. Payn; M.N. Gooseff; B.L. McGlynn; K.E. Bencala; S.M. Wondzell

    2009-01-01

    Channel water balances of contiguous reaches along streams represent a poorly understood scale of stream-subsurface interaction. We measured reach water balances along a headwater stream in Montana, United States, during summer base flow recessions. Reach water balances were estimated from series of tracer tests in 13 consecutive reaches delineated evenly along a 2.6-...

  16. Impacts by point and diffuse micropollutant sources on the stream water quality at catchment scale

    DEFF Research Database (Denmark)

    Petersen, Mette Fjendbo; Eriksson, Eva; Binning, Philip John

    2012-01-01

    the stream and analyzed for general water quality parameters, inorganic constituents, pesticides, sulfonamides, chlorinated solvents, BTEXs, and paracetamol and ibuprofen. The latter two groups were not detected. The general water quality showed typical conditions for a stream in western Jutland. Minor...... at the pharmaceutical factory site, the drainage ditch and the waste deposits is similar in composition containing among others sulfonamides and chlorinated solvents (including vinyl chloride). Vinyl chloride concentrations surpassed Danish stream water quality criteria with a factor 10. The largest chemical impact...

  17. Evaluation of the Physico-Chemical Properties of Produced Water ...

    African Journals Online (AJOL)

    ADOWIE PERE

    Samples were obtained at different periods within two months. Produced water ... sometimes, naturally occurring radioactive materials .... particular sample of soil, water, or air (Khatib and ... several other elements in solution particularly Barium.

  18. Operational forest stream crossings effects on water quality in the Virginia Piedmont

    Science.gov (United States)

    Wallace M. Aust; Matthew B. Carroll; M. Chad Bolding; Andy Dolloff

    2011-01-01

    Water quality indices were examined for paired upstream and downstream samples for 23 operational stream crossings and approaches during four periods. Stream crossings were (1) portable bridges (BRIDGE), (2) culverts backfilled with poles (POLE), (3) culverts with earth backfill (CULVERT), and (4) reinforced fords (FORD). The four operational periods were (1) prior to...

  19. Mixing Hot and Cold Water Streams at a T-Junction

    Science.gov (United States)

    Sharp, David; Zhang, Mingqian; Xu, Zhenghe; Ryan, Jim; Wanke, Sieghard; Afacan, Artin

    2008-01-01

    A simple mixing of a hot- and cold-water stream at a T-junction was investigated. The main objective was to use mass and energy balance equations to predict mass low rates and the temperature of the mixed stream after the T-junction, and then compare these with the measured values. Furthermore, the thermocouple location after the T-junction and…

  20. Use of index analysis to evaluate the water quality of a stream ...

    African Journals Online (AJOL)

    In this paper, the water quality of a stream that receives industrial effluents is evaluated through the analysis of two indices. Data (dissolved oxygen, biochemical oxygen demand, pH, turbidity, colour, temperature and thermotolerant coliforms) were collected from five stations in the Mussuré Stream, located in João Pessoa ...

  1. Flowing water affects fish fast-starts: escape performance of the Hawaiian stream goby, Sicyopterus stimpsoni.

    Science.gov (United States)

    Diamond, Kelly M; Schoenfuss, Heiko L; Walker, Jeffrey A; Blob, Richard W

    2016-10-01

    Experimental measurements of escape performance in fishes have typically been conducted in still water; however, many fishes inhabit environments with flow that could impact escape behavior. We examined the influences of flow and predator attack direction on the escape behavior of fish, using juveniles of the amphidromous Hawaiian goby Sicyopterus stimpsoni In nature, these fish must escape ambush predation while moving through streams with high-velocity flow. We measured the escape performance of juvenile gobies while exposing them to a range of water velocities encountered in natural streams and stimulating fish from three different directions. Frequency of response across treatments indicated strong effects of flow conditions and attack direction. Juvenile S. stimpsoni had uniformly high response rates for attacks from a caudal direction (opposite flow); however, response rates for attacks from a cranial direction (matching flow) decreased dramatically as flow speed increased. Mechanical stimuli produced by predators attacking in the same direction as flow might be masked by the flow environment, impairing the ability of prey to detect attacks. Thus, the likelihood of successful escape performance in fishes can depend critically on environmental context. © 2016. Published by The Company of Biologists Ltd.

  2. Geology, Streamflow, and Water Chemistry of the Talufofo Stream Basin, Saipan, Northern Mariana Islands

    Science.gov (United States)

    Izuka, Scot K.; Ewart, Charles J.

    1995-01-01

    A study of the geology, streamflow, and water chemistry of Talufofo Stream Basin, Saipan, Commonwealth of the Northern Mariana Islands, was undertaken to determine the flow characteristics of Talufofo Stream and the relation to the geology of the drainage basin. The Commonwealth government is exploring the feasibility of using water from Talufofo Stream to supplement Saipan's stressed municipal water supply. Streamflow records from gaging stations on the principal forks of Talufofo Stream indicate that peak streamflows and long-term average flow are higher at the South Fork gaging station than at the Middle Fork gaging station because the drainage area of the South Fork gaging station is larger, but persistent base flow from ground-water discharge during dry weather is greater in the Middle Fork gaging station. The sum of the average flows at the Middle Fork and South Fork gaging stations, plus an estimate of the average flow at a point in the lower reaches of the North Fork, is about 2.96 cubic feet per second or 1.91 million gallons per day. Although this average represents the theoretical maximum long-term draft rate possible from the Talufofo Stream Basin if an adequate reservoir can be built, the actual amount of surface water available will be less because of evaporation, leaks, induced infiltration, and reservoir-design constraints. Base-flow characteristics, such as stream seepage and spring discharge, are related to geology of the basin. Base flow in the Talufofo Stream Basin originates as discharge from springs near the base of limestones located in the headwaters of Talufofo Stream, flows over low-permeability volcanic rocks in the middle reaches, and seeps back into the high-permeability limestones in the lower reaches. Water sampled from Talufofo Stream during base flow had high dissolved-calcium concentrations (between 35 and 98 milligrams per liter), characteristic of water from a limestone aquifer. Concentrations of potassium, sodium, and chloride

  3. Depauperate macroinvertebrates in a mine affected stream: Clean water may be the key to recovery

    International Nuclear Information System (INIS)

    Battaglia, M.; Hose, G.C.; Turak, E.; Warden, B.

    2005-01-01

    Acid mine drainage (AMD) is frequently linked with changes in macroinvertebrate assemblages, but the relative contribution of water and sediment to toxicity is equivocal. We have shown that the macroinvertebrate fauna of Neubecks Ck, a mine impacted stream in New South Wales, Australia, was much poorer than in two reference streams. Multivariate RELATE analyses indicated that the patterns in the biological data were more strongly correlated with the concentrations of common metals in the surface water than the pore water of these streams. From this we hypothesised that the water was more toxic to the biota than the sediment and we tested this hypothesis with a sediment transplant experiment. Sediment from Neubecks Ck that was placed in reference streams retained high concentrations of metals throughout the experiment, yet supported a macroinvertebrate assemblage similar to that in the reference streams. Sediment from the reference streams that was placed in Neubecks Ck supported few, if any, animals. This indicates that water in Neubecks Ck is toxic to biota, but that sediment is able to support aquatic biota in clean water. Therefore, remediation should focus on improving water quality rather than sediment quality. - Macroinvertebrates colonise contaminated sediment in clean water

  4. Spatiotemporal dynamics of spring and stream water chemistry in a high-mountain area

    International Nuclear Information System (INIS)

    Zelazny, Miroslaw; Astel, Aleksander; Wolanin, Anna; Malek, Stanislaw

    2011-01-01

    The present study deals with the application of the self-organizing map (SOM) technique in the exploration of spatiotemporal dynamics of spring and stream water samples collected in the Chocholowski Stream Basin located in the Tatra Mountains (Poland). The SOM-based classification helped to uncover relationships between physical and chemical parameters of water samples and factors determining the quality of water in the studied high-mountain area. In the upper part of the Chocholowski Stream Basin, located on the top of the crystalline core of the Tatras, concentrations of the majority of ionic substances were the lowest due to limited leaching. Significantly higher concentration of ionic substances was detected in spring and stream samples draining sedimentary rocks. The influence of karst-type springs on the quality of stream water was also demonstrated. - Highlights: → We use SOM approach to explore physiochemical data for mountain waters. → Geologic structure and hydrological events impact water chemistry. → Limited leaching, typical of crystalline core, reflects in low water mineralization. → Sedimentary rocks are susceptible for leaching. → Eutrophication has not been shown to be a threat in the Chocholowska Valley. - Spatiotemporal dynamics of spring and stream water chemistry in unique high-mountain area was evaluated by the self-organizing map technique.

  5. Impacts by point and diffuse micropollutant sources on the stream water quality at catchment scale

    Science.gov (United States)

    Petersen, M. F.; Eriksson, E.; Binning, P. J.; Bjerg, P. L.

    2012-04-01

    The water quality of surface waters is threatened by multiple anthropogenic pollutants and the large variety of pollutants challenges the monitoring and assessment of the water quality. The aim of this study was to characterize and quantify both point and diffuse sources of micropollutants impacting the water quality of a stream at catchment scale. Grindsted stream in western Jutland, Denmark was used as a study site. The stream passes both urban and agricultural areas and is impacted by severe groundwater contamination in Grindsted city. Along a 12 km reach of Grindsted stream, the potential pollution sources were identified including a pharmaceutical factory site with a contaminated old drainage ditch, two waste deposits, a wastewater treatment plant, overflow structures, fish farms, industrial discharges and diffuse agricultural and urban sources. Six water samples were collected along the stream and analyzed for general water quality parameters, inorganic constituents, pesticides, sulfonamides, chlorinated solvents, BTEXs, and paracetamol and ibuprofen. The latter two groups were not detected. The general water quality showed typical conditions for a stream in western Jutland. Minor impacts by releases of organic matter and nutrients were found after the fish farms and the waste water treatment plant. Nickel was found at concentrations 5.8 - 8.8 μg/l. Nine pesticides and metabolites of both agricultural and urban use were detected along the stream; among these were the two most frequently detected and some rarely detected pesticides in Danish water courses. The concentrations were generally consistent with other findings in Danish streams and in the range 0.01 - 0.09 μg/l; except for metribuzin-diketo that showed high concentrations up to 0.74 μg/l. The groundwater contamination at the pharmaceutical factory site, the drainage ditch and the waste deposits is similar in composition containing among others sulfonamides and chlorinated solvents (including vinyl

  6. Effects of chronic pollution and water flow intermittency on stream biofilms biodegradation capacity.

    Science.gov (United States)

    Rožman, Marko; Acuña, Vicenç; Petrović, Mira

    2018-02-01

    A mesocosm case study was conducted to gain understanding and practical knowledge on biofilm emerging contaminants biodegradation capacity under stressor and multiple stressor conditions. Two real life scenarios: I) biodegradation in a pristine intermittent stream experiencing acute pollution and II) biodegradation in a chronically polluted intermittent stream, were examined via a multifactorial experiment using an artificial stream facility. Stream biofilms were exposed to different water flow conditions i.e. permanent and intermittent water flow. Venlafaxine, a readily biodegradable pharmaceutical was used as a measure of biodegradation capacity while pollution was simulated by a mixture of four emerging contaminants (erythromycin, sulfisoxazole, diclofenac and imidacloprid in addition to venlafaxine) in environmentally relevant concentrations. Biodegradation kinetics monitored via LC-MS/MS was established, statistically evaluated, and used to link biodegradation with stress events. The results suggest that the effects of intermittent flow do not hinder and may even stimulate pristine biofilm biodegradation capacity. Chronic pollution completely reduced biodegradation in permanent water flow experimental treatments while no change in intermittent streams was observed. A combined effect of water flow conditions and emerging contaminants exposure on biodegradation was found. The decrease in biodegradation due to exposure to emerging contaminants is significantly greater in streams with permanent water flow suggesting that the short and medium term biodegradation capacity in intermittent systems may be preserved or even greater than in perennial streams. Copyright © 2017 Elsevier Ltd. All rights reserved.

  7. Recycling produced water for algal cultivation for biofuels

    Energy Technology Data Exchange (ETDEWEB)

    Neal, Justin N. [Los Alamos National Laboratory; Sullivan, Enid J. [Los Alamos National Laboratory; Dean, Cynthia A. [Los Alamos National Laboratory; Steichen, Seth A. [Los Alamos National Laboratory

    2012-08-09

    Algal growth demands a continuous source of water of appropriate salinity and nutritional content. Fresh water sources are scarce in the deserts of the Southwestern United States, hence, salt water algae species are being investigated as a renewable biofuel source. The use of produced water from oil wells (PW) could offset the demand for fresh water in cultivation. Produced water can contain various concentrations of dissolved solids, metals and organic contaminants and often requires treatment beyond oil/water separation to make it suitable for algae cultivation. The produced water used in this study was taken from an oil well in Jal, New Mexico. An F/2-Si (minus silica) growth media commonly used to cultivate Nannochloropsis salina 1776 (NS 1776) was prepared using the produced water (F/2-Si PW) taking into account the metals and salts already present in the water. NS 1776 was seeded into a bioreactor containing 5L of the (F/2-Si PW) media. After eleven days the optical density at 750 nm (an indicator of algal growth) increased from 0 to 2.52. These results indicate algae are able to grow, though inhibited when compared with non-PW media, in the complex chemical conditions found in produced water. Savings from using nutrients present in the PW, such as P, K, and HCO{sub 3}{sup -}, results in a 44.38% cost savings over fresh water to mix the F/2-Si media.

  8. Physico-chemical analyses and corrosion effect of produced water ...

    African Journals Online (AJOL)

    Physico-chemical characteristics of the composite produced water sample used for the study has a higher concentration compared with DPR standard for discharge of produced formation water into surface environment. It was assumed that the corrosion of the coupons was due to presence of high chemical matters in the ...

  9. Hyper-saline produced water treatment for beneficial use

    NARCIS (Netherlands)

    Al-Furaiji, Mustafa

    2016-01-01

    Producing oil and gas is always accompanied with large amounts of effluent water, called “produced water” (PW). These huge quantities of water can be used (if treated efficiently and economically) for many useful purposes like industrial applications, irrigation, cattle and animal consumption, and

  10. Reclamation of potable water from mixed gas streams

    Science.gov (United States)

    Judkins, Roddie R; Bischoff, Brian L; Debusk, Melanie Moses; Narula, Chaitanya

    2013-08-20

    An apparatus for separating a liquid from a mixed gas stream can include a wall, a mixed gas stream passageway, and a liquid collection assembly. The wall can include a first surface, a second surface, and a plurality of capillary condensation pores. The capillary condensation pores extend through the wall, and have a first opening on the first surface of the wall, and a second opening on the second surface of the wall. The pore size of the pores can be between about 2 nm to about 100 nm. The mixed gas stream passageway can be in fluid communication with the first opening. The liquid collection assembly can collect liquid from the plurality of pores.

  11. Near-field Oblique Remote Sensing of Stream Water-surface Elevation, Slope, and Surface Velocity

    Science.gov (United States)

    Minear, J. T.; Kinzel, P. J.; Nelson, J. M.; McDonald, R.; Wright, S. A.

    2014-12-01

    A major challenge for estimating discharges during flood events or in steep channels is the difficulty and hazard inherent in obtaining in-stream measurements. One possible solution is to use near-field remote sensing to obtain simultaneous water-surface elevations, slope, and surface velocities. In this test case, we utilized Terrestrial Laser Scanning (TLS) to remotely measure water-surface elevations and slope in combination with surface velocities estimated from particle image velocimetry (PIV) obtained by video-camera and/or infrared camera. We tested this method at several sites in New Mexico and Colorado using independent validation data consisting of in-channel measurements from survey-grade GPS and Acoustic Doppler Current Profiler (ADCP) instruments. Preliminary results indicate that for relatively turbid or steep streams, TLS collects tens of thousands of water-surface elevations and slopes in minutes, much faster than conventional means and at relatively high precision, at least as good as continuous survey-grade GPS measurements. Estimated surface velocities from this technique are within 15% of measured velocity magnitudes and within 10 degrees from the measured velocity direction (using extrapolation from the shallowest bin of the ADCP measurements). Accurately aligning the PIV results into Cartesian coordinates appears to be one of the main sources of error, primarily due to the sensitivity at these shallow oblique look angles and the low numbers of stationary objects for rectification. Combining remotely-sensed water-surface elevations, slope, and surface velocities produces simultaneous velocity measurements from a large number of locations in the channel and is more spatially extensive than traditional velocity measurements. These factors make this technique useful for improving estimates of flow measurements during flood flows and in steep channels while also decreasing the difficulty and hazard associated with making measurements in these

  12. High purity heavy water production: need for total organic carbon determination in process water streams

    International Nuclear Information System (INIS)

    Ayushi; Kumar, Sangita D.; Reddy, A.V.R.; Vithal, G.K.

    2009-01-01

    In recent times, demand for high purity heavy water (99.98% pure) in industries and laboratories has grown by manifold. Its application started in nuclear industry with the design of CANDU reactor, which uses natural uranium as fuel. In this reactor the purest grade of heavy water is used as the moderator and the primary coolant. Diverse industrial applications like fibre optics, medicine, semiconductors etc. use high purity heavy water extensively to achieve better performance of the specific material. In all these applications there is a stringent requirement that the total organic carbon content (TOC) of high purity heavy water should be very low. This is because the presence of TOC can lead to adverse interactions in different applications. To minimize the TOC content in the final product there is a need to monitor and control the TOC content at each and every stage of heavy water production. Hence a simple, rapid and accurate method was developed for the determination of TOC content in process water samples. The paper summarizes the results obtained for the TOC content in the water samples collected from process streams of heavy water production plant. (author)

  13. Stream water temperature limits occupancy of salamanders in mid-Atlantic protected areas

    Science.gov (United States)

    Grant, Evan H. Campbell; Wiewel, Amber N. M.; Rice, Karen C.

    2014-01-01

    Stream ecosystems are particularly sensitive to urbanization, and tolerance of water-quality parameters is likely important to population persistence of stream salamanders. Forecasted climate and landscape changes may lead to significant changes in stream flow, chemical composition, and temperatures in coming decades. Protected areas where landscape alterations are minimized will therefore become increasingly important for salamander populations. We surveyed 29 streams at three national parks in the highly urbanized greater metropolitan area of Washington, DC. We investigated relationships among water-quality variables and occupancy of three species of stream salamanders (Desmognathus fuscus, Eurycea bislineata, and Pseudotriton ruber). With the use of a set of site-occupancy models, and accounting for imperfect detection, we found that stream-water temperature limits salamander occupancy. There was substantial uncertainty about the effects of the other water-quality variables, although both specific conductance (SC) and pH were included in competitive models. Our estimates of occupancy suggest that temperature, SC, and pH have some importance in structuring stream salamander distribution.

  14. Impacts of groundwater metal loads from bedrock fractures on water quality of a mountain stream.

    Science.gov (United States)

    Caruso, Brian S; Dawson, Helen E

    2009-06-01

    Acid mine drainage and metal loads from hardrock mines to surface waters is a significant problem in the western USA and many parts of the world. Mines often occur in mountain environments with fractured bedrock aquifers that serve as pathways for metals transport to streams. This study evaluates impacts from current and potential future groundwater metal (Cd, Cu, and Zn) loads from fractures underlying the Gilt Edge Mine, South Dakota, on concentrations in Strawberry Creek using existing flow and water quality data and simple mixing/dilution mass balance models. Results showed that metal loads from bedrock fractures to the creek currently contribute water quality is achieved upstream in Strawberry Creek, fracture metal loads would be water quality standards exceedances once groundwater with elevated metals concentrations in the aquifer matrix migrates to the fractures and discharges to the stream. Potential future metal loads from an upstream fracture would contribute a small proportion of the total load relative to current loads in the stream. Cd has the highest stream concentrations relative to standards. Even if all stream water was treated to remove 90% of the Cd, the standard would still not be achieved. At a fracture farther downstream, the Cd standard can only be met if the upstream water is treated achieving a 90% reduction in Cd concentrations and the median stream flow is maintained.

  15. Development of a stream-aquifer numerical flow model to assess river water management under water scarcity in a Mediterranean basin.

    Science.gov (United States)

    Mas-Pla, Josep; Font, Eva; Astui, Oihane; Menció, Anna; Rodríguez-Florit, Agustí; Folch, Albert; Brusi, David; Pérez-Paricio, Alfredo

    2012-12-01

    Stream flow, as a part of a basin hydrological cycle, will be sensible to water scarcity as a result of climate change. Stream vulnerability should then be evaluated as a key component of the basin water budget. Numerical flow modeling has been applied to an alluvial formation in a small mountain basin to evaluate the stream-aquifer relationship under these future scenarios. The Arbúcies River basin (116 km(2)) is located in the Catalan Inner Basins (NE Spain) and its lower reach, which is related to an alluvial aquifer, usually becomes dry during the summer period. This study seeks to determine the origin of such discharge losses whether from natural stream leakage and/or induced capture due to groundwater withdrawal. Our goal is also investigating how discharge variations from the basin headwaters, representing potential effects of climate change, may affect stream flow, aquifer recharge, and finally environmental preservation and human supply. A numerical flow model of the alluvial aquifer, based on MODFLOW and especially in the STREAM routine, reproduced the flow system after the usual calibration. Results indicate that, in the average, stream flow provides more than 50% of the water inputs to the alluvial aquifer, being responsible for the amount of stored water resources and for satisfying groundwater exploitation for human needs. Detailed simulations using daily time-steps permit setting threshold values for the stream flow entering at the beginning of the studied area so surface discharge is maintained along the whole watercourse and ecological flow requirements are satisfied as well. The effects of predicted rainfall and temperature variations on the Arbúcies River alluvial aquifer water balance are also discussed from the outcomes of the simulations. Finally, model results indicate the relevance of headwater discharge management under future climate scenarios to preserve downstream hydrological processes. They also point out that small mountain basins

  16. Changes in vegetative communities and water table dynamics following timber harvesting in small headwater streams

    Science.gov (United States)

    B. Choi; J.C. Dewey; J. A. Hatten; A.W. Ezell; Z. Fan

    2012-01-01

    In order to better understand the relationship between vegetation communities and water table in the uppermost portions (ephemeral–intermittent streams) of headwater systems, seasonal plot-based field characterizations of vegetation were used in conjunction with monthly water table measurements. Vegetation, soils, and water table data were examined to determine...

  17. An economically viable alternative to coastal discharge of produced water

    International Nuclear Information System (INIS)

    D'Unger, C.V.; Carr, R.S.; Chapman, D.C.

    1993-01-01

    The discharge of produced waters to coastal estuaries has been common practice on the Texas coast for many years as these discharges are currently exempt from NPDES permitting. A study of the active produced water discharges in Nueces Bay, Texas revealed that all eight effluents were highly toxic as determined by the sea urchin (Arbacia punctulata) fertilization and embryological development assays. An alternative to discharging produced water into coastal estuaries is the use of disposal wells. Inactive wells can be converted to produced water disposal wells. Production records for the Nueces Bay, Texas area reveal that 52% of the gas wells produce less than 100 mcf/d and 50% of the oil wells produce less than 10 b/d. Using conservative estimates, the cost of converting an inactive well to a disposal well was calculated to be $31,500 which could be paid out by a gas well producing as little as 100 mcf/d in 26 months using only 50% of the well's profit. Combining multiple leases to a single disposal well would reduce proportionately the cost to each operation. This study has demonstrated that economically viable disposal options could be achieved in the Nueces Bay area through the imaginative and cooperative formation of produced water disposal ventures. This same model could be applied to produced water discharges in other coastal areas

  18. MODIFIED REVERSE OSMOSIS SYSTEM FOR TREATMENT OF PRODUCED WATERS

    Energy Technology Data Exchange (ETDEWEB)

    T.M. Whitworth; Liangxiong Li

    2002-09-15

    This report describes work performed during the first year of the project ''Modified Reverse Osmosis System for Treatment of Produced Waters.'' This research project has two objectives. The first objective is to test the use of clay membranes in the treatment of produced waters by reverse osmosis. The second objective is to test the ability of a system patented by the New Mexico Tech Research Foundation to remove salts from reverse osmosis waste streams as a solid. We performed 12 experiments using clay membranes in cross-flow experimental cells. We found that, due to dispersion in the porous frit used adjacent to the membrane, the concentration polarization layer seems to be completely (or nearly completely) destroyed at low flow rates. This observation suggests that clay membranes used with porous frit material many reach optimum rejection rates at lower pumping rates than required for use with synthetic membranes. The solute rejection efficiency decreases with increasing solution concentration. For the membranes and experiments reported here, the rejection efficiency ranged from 71% with 0.01 M NaCl solution down to 12% with 2.3 M NaCl solution. More compacted clay membranes will have higher rejection capabilities. The clay membranes used in our experiments were relatively thick (approximately 0.5 mm). The active layer of most synthetic membranes is only 0.04 {micro}m (0.00004 mm), approximately 1250 times thinner than the clay membranes used in these experiments. Yet clay membranes as thin as 12 {micro}m have been constructed (Fritz and Eady, 1985). Since Darcy's law states that the flow through a material of constant permeability is inversely proportional to it's the material's thickness, then, based on these experimental observations, a very thin clay membrane would be expected to have much higher flow rates than the ones used in these experiments. Future experiments will focus on testing very thin clay membranes. The

  19. Assessment of physicochemical quality of sachet water produced in ...

    African Journals Online (AJOL)

    Fifty (50) brands of sachet water produced from bore hole and tap water in five (5) local government areas of Kano metropolis were analysed for physicochemical quality. Ten (10) brands of sachet water were sampled from each of the five (5) local government areas of; Nasarawa, Tarauni, Gwale, Kumbotso and Ungogo.

  20. Acoustic streaming produced by a cylindrical bubble undergoing volume and translational oscillations in a microfluidic channel.

    Science.gov (United States)

    Doinikov, Alexander A; Combriat, Thomas; Thibault, Pierre; Marmottant, Philippe

    2016-09-01

    A theoretical model is developed for acoustic streaming generated by a cylindrical bubble confined in a fluid channel between two planar elastic walls. The bubble is assumed to undergo volume and translational oscillations. The volume oscillation is caused by an imposed acoustic pressure field and generates the bulk scattered wave in the fluid gap and Lamb-type surface waves propagating along the fluid-wall interfaces. The translational oscillation is induced by the velocity field of an external sound source such as another bubble or an oscillatory fluid flow. The acoustic streaming is assumed to result from the interaction of the volume and the translational modes of the bubble oscillations. The general solutions for the linear equations of fluid motion and the equations of acoustic streaming are calculated with no restrictions on the ratio between the viscous penetration depth and the bubble size. Approximate solutions for the limit of low viscosity are provided as well. Simulations of streamline patterns show that the geometry of the streaming resembles flows generated by a source dipole, while the vortex orientation is governed by the driving frequency, bubble size, and the distance of the bubble from the source of translational excitation. Experimental verification of the developed theory is performed using data for streaming generated by bubble pairs.

  1. Assessing the Effects of Water Right Purchases on Stream Temperatures and Fish Habitat

    Science.gov (United States)

    Elmore, L.; Null, S. E.

    2012-12-01

    Warm stream temperature and low flow conditions are limiting factors for native trout species in Nevada's Walker River. Water rights purchases are being considered to increase instream flow and improve habitat conditions. However, the effect of water rights purchases on stream temperatures and fish habitat have yet to be assessed. Manipulating flow conditions affect stream temperatures by altering water depth, velocity, and thermal mass. This study uses the River Modeling System (RMSv4), an hourly, physically-based hydrodynamic and water quality model, to estimate flows and stream temperatures in the Walker River. The model is developed for two wet years (2010-2011). Study results highlight reaches with cold-water habitat that is suitable for native trout species. Previous research on the Walker River has evaluated instream flow changes with water rights purchases. This study incorporates stream temperatures as a proxy for trout habitat, and thus explicitly incorporates water quality and fish habitat into decision-making regarding water rights purchases. Walker River

  2. Monitoring of water quality of a stream at the Federal University of Pernambuco, Brazil

    Directory of Open Access Journals (Sweden)

    Marlyete Chagas de Araújo

    2013-12-01

    Full Text Available The Cavouco stream is an affluent of Pernambuco’s main river, the Capibaribe, and has its source on the campus of the Federal University of Pernambuco (UFPE. The stretch of the river that runs within the university receives an influx of pollution in the form of chemicals, and household and hospital waste. In light of this situation, and hoping to mitigate it, the aim of this study was to analyze the water quality of this stream and to raise the academic community’s awareness regarding this issue. To this end, stream water samples were collected in two different periods (dry and rainy at five strategic points on campus. The water samples were sent to the Water Treatment Plant and to the Laboratory for Analysis of Mineral, Soil and Water of the UFPE where 16 physicochemical parameters were analyzed (temperature, turbidity, conductivity, total dissolved solids, pH, dissolved oxygen, ammonia, nitrite, nitrate, iron, manganese, cadmium, lead, copper, chromium, zinc according to the methodology of 21st Standard Methods for the Examination of Water and Wastewater. The results show that the water of the Cavouco stream has a high load of pollution, with the points P2 and P5 being the most impacted. Additionally, the results of the Index of Water Quality for the Protection of Aquatic Life indicated that currently the stream has a low capacity for maintenance of aquatic life.

  3. Radon in streams and ground waters of Pennsylvania as a guide to uranium deposits

    International Nuclear Information System (INIS)

    Korner, L.A.; Rose, A.W.

    1977-06-01

    Radon-222, a daughter in the radioactive decay of uranium, has potential as a geochemical guide to uranium ores because of its chemical inertness and its relatively easy determination. The radon contents of 59 stream and 149 ground waters have been determined with a newly designed portable radon detector in order to test the method in uranium exploration. Radon contents of stream waters do not appear useful for reconnaissance uranium exploration of areas like Pennsylvania because of relatively rapid degassing of radon from turbulent waters, and because most radon is derived from nearby influx of ground waters into the streams. Radon in streams near uranium occurrences in Carbon and Lycoming counties is lower than many background streams. Radon in ground water is recommended as a reconnaissance method of uranium exploration because most samples from near mineralized areas are anomalous in radon. In contrast, uranium in ground waters is not anomalous near mineralized areas in Carbon County. Equations are derived to show the relation of radon in ground waters to uranium contents of enclosing rocks, emanation of radon from the solids to water, and porosity or fracture width. Limonites are found to be highly enriched in radium, the parent of radon. A model for detection of a nearby uranium ore body by radon measurement on a pumping well has been developed

  4. Contamination of water in Oliwski Stream after the flood in 2016

    Directory of Open Access Journals (Sweden)

    Matej-Łukowicz Karolina

    2017-01-01

    Full Text Available In the article pollution of stream waters with surface runoff from an urbanized area caused by an extremely high rainfall is discussed. The analyzes were carried out after the rainfall of the depth 152 mm which took place in Gdańsk on 14th and 15th July 2016. This extreme rainfall caused urban flooding, damage of several retention ponds and pollution of surface waters. In the article the results of physical and chemical analyzes of the water samples from Oliwski Stream, inflowing to the Gulf of Gdańsk at the beach in Jelitkowo, are presented. The samples were collected at six points along the Stream in order to evaluate potential pollution sources. The results of the study indicated elevated concentrations of phosphorus compounds and nitrates (V. Additionally, the concentrations of total suspended solids (TSS, solids granulometry and grain size distribution along the stream was investigated.

  5. A review of crosslinked fracturing fluids prepared with produced water

    Directory of Open Access Journals (Sweden)

    Leiming Li

    2016-12-01

    Full Text Available The rapidly increasing implementations of oilfield technologies such as horizontal wells and multistage hydraulic fracturing, particularly in unconventional formations, have expanded the need for fresh water in many oilfield locations. In the meantime, it is costly for services companies and operators to properly dispose large volumes of produced water, generated annually at about 21 billion barrels in the United States alone. The high operating costs in obtaining fresh water and dealing with produced water have motivated scientists and engineers, especially in recent years, to use produced water in place of fresh water to formulate well treatment fluids. The objective of this brief review is to provide a summary of the up-to-date technologies of reusing oilfield produced water in preparations of a series of crosslinked fluids implemented mainly in hydraulic fracturing operations. The crosslinked fluids formulated with produced water include borate- and metal-crosslinked guar and derivatized guar fluids, as well as other types of crosslinked fluid systems such as crosslinked synthetic polymer fluids and crosslinked derivatized cellulose fluids. The borate-crosslinked guar fluids have been successfully formulated with produced water and used in oilfield operations with bottomhole temperatures up to about 250 °F. The produced water sources involved showed total dissolved solids (TDS up to about 115,000 mg/L and hardness up to about 11,000 mg/L. The metal-crosslinked guar fluids prepared with produced water were successfully used in wells at bottomhole temperatures up to about 250 °F, with produced water TDS up to about 300,000 mg/L and hardness up to about 44,000 mg/L. The Zr-crosslinked carboxymethyl hydroxypropyl guar (CMHPG fluids have been successfully made with produced water and implemented in operations with bottomhole temperatures at about 250+ °F, with produced water TDS up to about 280,000 mg/L and hardness up to about 91,000

  6. Water quality of streams in Johnson County, Kansas, 2002-07

    Science.gov (United States)

    Rasmussen, T.J.

    2009-01-01

    Water quality of streams in Johnson County, Kansas was evaluated from October 2002 through December 2007 in a cooperative study between the U.S. Geological Survey and the Johnson County Stormwater Management Program. Water quality at 42 stream sites, representing urban and rural basins, was characterized by evaluating benthic macroinvertebrates, water (discrete and continuous data), and/or streambed sediment. Point and nonpoint sources and transport were described for water-quality constituents including suspended sediment, dissolved solids and major ions, nutrients (nitrogen and phosphorus), indicator bacteria, pesticides, and organic wastewater and pharmaceutical compounds. The information obtained from this study is being used by city and county officials to develop effective management plans for protecting and improving stream quality. This fact sheet summarizes important results from three comprehensive reports published as part of the study and available on the World Wide Web at http://ks.water.usgs.gov/Kansas/studies/qw/joco/. ?? 2009 ASCE.

  7. Process Design and Techno-economic Analysis for Materials to Treat Produced Waters.

    Energy Technology Data Exchange (ETDEWEB)

    Heimer, Brandon Walter [Sandia National Lab. (SNL-CA), Livermore, CA (United States); Paap, Scott M [Sandia National Lab. (SNL-CA), Livermore, CA (United States); Sasan, Koroush [Sandia National Laboratories (SNL-NM), Albuquerque, NM (United States); Brady, Patrick Vane. [Sandia National Laboratories (SNL-NM), Albuquerque, NM (United States); Nenoff, Tina M. [Sandia National Laboratories (SNL-NM), Albuquerque, NM (United States)

    2017-09-01

    Significant quantities of water are produced during enhanced oil recovery making these “produced water” streams attractive candidates for treatment and reuse. However, high concentrations of dissolved silica raise the propensity for fouling. In this paper, we report the design and economic analysis for a new ion exchange process using calcined hydrotalcite (HTC) to remove silica from water. This process improves upon known technologies by minimizing sludge product, reducing process fouling, and lowering energy use. Process modeling outputs included raw material requirements, energy use, and the minimum water treatment price (MWTP). Monte Carlo simulations quantified the impact of uncertainty and variability in process inputs on MWTP. These analyses showed that cost can be significantly reduced if the HTC materials are optimized. Specifically, R&D improving HTC reusability, silica binding capacity, and raw material price can reduce MWTP by 40%, 13%, and 20%, respectively. Optimizing geographic deployment further improves cost competitiveness.

  8. A floating water bridge produces water with excess charge

    Science.gov (United States)

    Fuchs, Elmar C.; Sammer, Martina; Wexler, Adam D.; Kuntke, Philipp; Woisetschläger, Jakob

    2016-03-01

    Excess positive and negative Bjerrum-defect like charge (protonic and ‘aterprotonic’, from ancient Greek ἄ'τɛρ, ‘without’) in anolyte and catholyte of high voltage electrolysis of highly pure water was found during the so-called ‘floating water bridge’ experiment. The floating water bridge is a special case of an electrohydrodynamic liquid bridge and constitutes an intriguing phenomenon that occurs when a high potential difference (~kV cm-1) is applied between two beakers of water. To obtain such results impedance spectroscopy was used. This measurement technique allows the depiction and simulation of complex aqueous systems as simple electric circuits. In the present work we show that there is an additional small contribution from the difference in conductivity between anolyte and catholyte which cannot be measured with a conductivity meter, but is clearly visible in an impedance spectrum.

  9. A floating water bridge produces water with excess charge

    International Nuclear Information System (INIS)

    Fuchs, Elmar C; Sammer, Martina; Wexler, Adam D; Kuntke, Philipp; Woisetschläger, Jakob

    2016-01-01

    Excess positive and negative Bjerrum-defect like charge (protonic and ‘aterprotonic’, from ancient Greek ατερ, ‘without’) in anolyte and catholyte of high voltage electrolysis of highly pure water was found during the so-called ‘floating water bridge’ experiment. The floating water bridge is a special case of an electrohydrodynamic liquid bridge and constitutes an intriguing phenomenon that occurs when a high potential difference (∼kV cm −1 ) is applied between two beakers of water. To obtain such results impedance spectroscopy was used. This measurement technique allows the depiction and simulation of complex aqueous systems as simple electric circuits. In the present work we show that there is an additional small contribution from the difference in conductivity between anolyte and catholyte which cannot be measured with a conductivity meter, but is clearly visible in an impedance spectrum. (paper)

  10. High contents of rare earth elements (REEs) in stream waters of a Cu-Pb-Zn mining area.

    Science.gov (United States)

    Protano, G; Riccobono, F

    2002-01-01

    Stream waters draining an old mining area present very high rare earth element (REE) contents, reaching 928 microg/l as the maximum total value (sigmaREE). The middle rare earth elements (MREEs) are usually enriched with respect to both the light (LREEs) and heavy (HREEs) elements of this group, producing a characteristic "roof-shaped" pattern of the shale Post-Archean Australian Shales-normalized concentrations. At the Fenice Capanne Mine (FCM), the most important base metal mine of the study area, the REE source coincides with the mine tailings, mostly the oldest ones composed of iron-rich materials. The geochemical history of the REEs released into Noni stream from wastes in the FCM area is strictly determined by the pH, which controls the REE speciation and in-stream processes. The formation of Al-rich and mainly Fe-rich flocs effectively scavenges the REEs, which are readily and drastically removed from the solution when the pH approaches neutrality. Leaching experiments performed on flocs and waste materials demonstrate that Fe-oxides/oxyhydroxides play a key role in the release of lanthanide elements into stream waters. The origin of the "roof-shaped" REE distribution pattern as well as the peculiar geochemical behavior of some lanthanide elements in the aqueous system are discussed.

  11. The influence of riparian woodland on the spatial and temporal variability of stream water temperatures in an upland salmon stream

    Directory of Open Access Journals (Sweden)

    I. A. Malcolm

    2004-01-01

    Full Text Available The spatio-temporal variability of stream water temperatures was investigated at six locations on the Girnock Burn (30km2 catchment, Cairngorms, Scotland over three hydrological years between 1998 and 2002. The key site-specific factors affecting the hydrology and climatology of the sampling points were investigated as a basis for physical process inference. Particular emphasis was placed on assessing the effects of riparian forest in the lower catchment versus the heather moorland riparian zones that are spatially dominant in the upper catchment. The findings were related to river heat budget studies that provided process detail. Gross changes in stream temperature were affected by the annual cycle of incoming solar radiation and seasonal changes in hydrological and climatological conditions. Inter-annual variation in these controlling variables resulted in inter-annual variability in thermal regime. However, more subtle inter-site differences reflected the impact of site-specific characteristics on various components of the river energy budget. Inter-site variability was most apparent at shorter time scales, during the summer months and for higher stream temperatures. Riparian woodland in the lower catchment had a substantial impact on thermal regime, reducing diel variability (over a period of 24 hours and temperature extremes. Observed inter-site differences are likely to have a substantial effect on freshwater ecology in general and salmonid fish in particular. Keywords: temperature, thermal regime, forest, salmon, hydrology, Girnock Burn, Cairngorm

  12. Assessing effects of water abstraction on fish assemblages in Mediterranean streams

    Science.gov (United States)

    Benejam, Lluis; Angermeier, Paul L.; Munne, Antoni; García-Berthou, Emili

    2010-01-01

    1. Water abstraction strongly affects streams in arid and semiarid ecosystems, particularly where there is a Mediterranean climate. Excessive abstraction reduces the availability of water for human uses downstream and impairs the capacity of streams to support native biota. 2. We investigated the flow regime and related variables in six river basins of the Iberian Peninsula and show that they have been strongly altered, with declining flows (autoregressive models) and groundwater levels during the 20th century. These streams had lower flows and more frequent droughts than predicted by the official hydrological model used in this region. Three of these rivers were sometimes dry, whereas there were predicted by the model to be permanently flowing. Meanwhile, there has been no decrease in annual precipitation. 3. We also investigated the fish assemblage of a stream in one of these river basins (Tordera) for 6 years and show that sites more affected by water abstraction display significant differences in four fish metrics (catch per unit effort, number of benthic species, number of intolerant species and proportional abundance of intolerant individuals) commonly used to assess the biotic condition of streams. 4. We discuss the utility of these metrics in assessing impacts of water abstraction and point out the need for detailed characterisation of the natural flow regime (and hence drought events) prior to the application of biotic indices in streams severely affected by water abstraction. In particular, in cases of artificially dry streams, it is more appropriate for regulatory agencies to assign index scores that reflect biotic degradation than to assign ‘missing’ scores, as is presently customary in assessments of Iberian streams.

  13. Assessment of produced water contaminated soils to determine remediation requirements

    International Nuclear Information System (INIS)

    Clodfelter, C.

    1995-01-01

    Produced water and drilling fluids can impact the agricultural properties of soil and result in potential regulatory and legal liabilities. Produced water typically is classified as saline or a brine and affects surface soils by increasing the sodium and chloride content. Sources of produced water which can lead to problems include spills from flowlines and tank batteries, permitted surface water discharges and pit areas, particularly the larger pits including reserve pits, emergency pits and saltwater disposal pits. Methods to assess produced water spills include soil sampling with various chemical analyses and surface geophysical methods. A variety of laboratory analytical methods are available for soil assessment which include electrical conductivity, sodium adsorption ratio, cation exchange capacity, exchangeable sodium percent and others. Limiting the list of analytical parameters to reduce cost and still obtain the data necessary to assess the extent of contamination and determine remediation requirements can be difficult. The advantage to using analytical techniques is that often regulatory remediation standards are tied to soil properties determined from laboratory analysis. Surface geophysical techniques can be an inexpensive method to rapidly determine the extent and relative magnitude of saline soils. Data interpretations can also provide an indication of the horizontal as well as the vertical extent of impacted soils. The following discussion focuses on produced water spills on soil and assessment of the impacted soil. Produced water typically contains dissolved hydrocarbons which are not addressed in this discussion

  14. Scale-dependence of land use effects on water quality of streams in agricultural catchments

    International Nuclear Information System (INIS)

    Buck, Oliver; Niyogi, Dev K.; Townsend, Colin R.

    2004-01-01

    The influence of land use on water quality in streams is scale-dependent and varies in time and space. In this study, land cover patterns and stocking rates were used as measures of agricultural development in two pasture and one native grassland catchment in New Zealand and were related to water quality in streams of various orders. The amount of pasture per subcatchment correlated well to total nitrogen and nitrate in one catchment and turbidity and total phosphorous in the other catchment. Stocking rates were only correlated to total phosphorous in one pasture catchment but showed stronger correlations to ammonium, total phosphorous and total nitrogen in the other pasture catchment. Winter and spring floods were significant sources of nutrients and faecal coliforms from one of the pasture catchments into a wetland complex. Nutrient and faecal coliform concentrations were better predicted by pastural land cover in fourth-order than in second-order streams. This suggests that upstream land use is more influential in larger streams, while local land use and other factors may be more important in smaller streams. These temporal and spatial scale effects indicate that water-monitoring schemes need to be scale-sensitive. - Land use influences water quality of streams at various spatial scales

  15. Using of CFD software for setting the location of water stream micro turbines

    Directory of Open Access Journals (Sweden)

    Borsuk Łukasz

    2016-01-01

    Full Text Available The aim of this work was to estimate the efficiency of CFD software in calculating flow velocity magnitude in natural water streams. These kinds of estimations are essential for setting the locations of water stream micro turbines. These devices can be useful to provide electricity in areas remote from power generating facilities or as backup power supply in case of power grid failure. The analysed water stream has length of 100 m and its average slope was approximately 10%. Water velocity varies in the range from 0.5 m3*s−1 to 5 m3*s−1. Additionally, the influence of ground roughness on the stream velocity was also an important factor. Results proved to be satisfactory. In the analysed stream, velocities were in a range which allows the proposed micro turbine to be effective. Calculation grid created by CFD software did not have many areas which may raise doubts. Also, the influence of changes in the ground roughness factor was noticeable. Preliminary CFD simulations allow to estimate where in the stream the micro turbine will be most efficient. On the other hand, despite these calculations, profitability and return on the investment still can be questionable.

  16. Scale-dependence of land use effects on water quality of streams in agricultural catchments

    Energy Technology Data Exchange (ETDEWEB)

    Buck, Oliver; Niyogi, Dev K.; Townsend, Colin R

    2004-07-01

    The influence of land use on water quality in streams is scale-dependent and varies in time and space. In this study, land cover patterns and stocking rates were used as measures of agricultural development in two pasture and one native grassland catchment in New Zealand and were related to water quality in streams of various orders. The amount of pasture per subcatchment correlated well to total nitrogen and nitrate in one catchment and turbidity and total phosphorous in the other catchment. Stocking rates were only correlated to total phosphorous in one pasture catchment but showed stronger correlations to ammonium, total phosphorous and total nitrogen in the other pasture catchment. Winter and spring floods were significant sources of nutrients and faecal coliforms from one of the pasture catchments into a wetland complex. Nutrient and faecal coliform concentrations were better predicted by pastural land cover in fourth-order than in second-order streams. This suggests that upstream land use is more influential in larger streams, while local land use and other factors may be more important in smaller streams. These temporal and spatial scale effects indicate that water-monitoring schemes need to be scale-sensitive. - Land use influences water quality of streams at various spatial scales.

  17. Water Quality in Tortum Stream and its Tributaries (Erzurum/Turkey

    Directory of Open Access Journals (Sweden)

    Mine KÖKTÜRK

    2015-04-01

    Full Text Available This study was undertaken with the aim of determining the effects of domestic waste and hydroelectric dams on water quality in the Tortum Stream and its tributaries. Water samples were taken monthly from nine sampling points of Tortum Stream and its tributaries between July 2012 and May 2013. Analyzed for temperature (°C, pH, dissolved oxygen (DO, total suspended solids (TSS, alkalinity, Ca, total hardness, sulfate (SO4, ammonia-nitrogen (N-NH3−, nitrite-nitrogen (N-NO2− and nitrate nitrogen (N-NO3− as well as total phosphorus (TP, total orthophosphate (TO, total iron and silica (SiO2 were carried out. Physical and chemical characteristics of Tortum Stream and its tributaries which were examined according to the Water Framework Directive and the Water Pollution Control Regulations. It can be said that the stream has a low water quality standard except for water temperature, dissolved oxygen and sulfate. The results showed that Tortum Stream and tributaries are under threat because of domestic waste, fertilizers and hydroelectric constructions.

  18. Natural and anthropogenic sources and processes affecting water chemistry in two South Korean streams

    International Nuclear Information System (INIS)

    Shin, Woo-Jin; Ryu, Jong-Sik; Mayer, Bernhard; Lee, Kwang-Sik; Lee, Sin-Woo

    2014-01-01

    Acid mine drainage (AMD) in a watershed provides potential sources of pollutants for surface and subsurface waters that can deteriorate water quality. Between March and early August 2011, water samples were collected from two streams in South Korea, one dominantly draining a watershed with carbonate bedrock affected by coal mines and another draining a watershed with silicate bedrock and a relatively undisturbed catchment area. The objective of the study was to identify the sources and processes controlling water chemistry, which was dependent on bedrock and land use. In the Odae stream (OS), the stream in the silicate-dominated catchment, Ca, Na, and HCO 3 were the dominant ions and total dissolved solids (TDS) was low (26.1–165 mg/L). In the Jijang stream (JS), in the carbonate-dominated watershed, TDS (224–434 mg/L) and ion concentrations were typically higher, and Ca and SO 4 were the dominant ions due to carbonate weathering and oxidation of pyrite exposed at coal mines. Dual isotopic compositions of sulfate (δ 34 S SO4 and δ 18 O SO4 ) verified that the SO 4 in JS is derived mainly from sulfide mineral oxidation in coal mines. Cl in JS was highest upstream and decreased progressively downstream, which implies that pollutants from recreational facilities in the uppermost part of the catchment are the major source governing Cl concentrations within the discharge basin. Dual isotopic compositions of nitrate (δ 15 N NO3 and δ 18 O NO3 ) indicated that NO 3 in JS is attributable to nitrification of soil organic matter but that NO 3 in OS is derived mostly from manure. Additionally, the contributions of potential anthropogenic sources to the two streams were estimated in more detail by using a plot of δ 34 S SO4 and δ 15 N NO3 . This study suggests that the dual isotope approach for sulfate and nitrate is an excellent additional tool for elucidating the sources and processes controlling the water chemistry of streams draining watersheds having different

  19. Produced water treatment for beneficial use : emulsified oil removal

    NARCIS (Netherlands)

    Waisi, Basma

    2016-01-01

    The development of novel carbon material, high accessible surface area, interconnected porosity, and stable nanofiber nonwoven media for emulsified oil droplets separation from oily wastewater, in particular for oilfields produced water treatment, is discussed in this thesis. Firstly, the quantity

  20. IMPACT OF MUNICIPAL LANDFILL SITE ON WATER QUALITY IN THE WŁOSANKA STREAM

    Directory of Open Access Journals (Sweden)

    Włodzimierz Kanownik

    2016-09-01

    Full Text Available Hydrochemical research conducted in the years 2007–2010 comprised monitoring of the Włosanka stream waters and leachate waters from the municipal landfill in Kulerzów in the Malopolskie province. 16 leachate samples were collected from the container taking into consideration the vertical stratification of the quality and samples of water from the Włosanka stream in measurement points situated before and after the landfill. Concentrations of metals: calcium, magnesium, sodium, potassium, iron, manganese and heavy metals: chromium, zinc, copper, cadmium, nickel and lead were determined in the leachates and the stream water. Analysis of the studied metals in the leachates revealed that only potassium concentration exceeded the highest admissible value which is the condition of introducing sewage to water bodies or to soil. Water along the investigated reach of the Włosanka stream, both above and below the municipal landfill was of quality class 1. The landfill had no significant effect on the studied metal concentrations in the stream water – no statistically significant differences were registered between the concentrations of the studied metals (including heavy metals either in the point above or below the landfill. However, statistical tests comparing values of metal concentrations in the landfill leachates with the stream water revealed that the concentrations of 7 out of 12 tested metals were significantly higher in the leachates. Therefore, the landfill site monitoring should be continued, leachate waters should be collected in the container and supplied to the sewage treatment plant to prevent any threat to human life and health, or to the environment.

  1. Emissions from Produced Water Treatment Ponds, Uintah Basin, Utah, USA

    Science.gov (United States)

    Mansfield, M. L.; Lyman, S. N.; Tran, H.; O'Neil, T.; Anderson, R.

    2015-12-01

    An aqueous phase, known as "produced water," usually accompanies the hydrocarbon fluid phases that are extracted from Earth's crust during oil and natural gas extraction. Produced water contains dissolved and suspended organics and other contaminants and hence cannot be discharged directly into the hydrosphere. One common disposal method is to discharge produced water into open-pit evaporation ponds. Spent hydraulic fracturing fluids are also often discharged into the same ponds. It is obvious to anyone with a healthy olfactory system that such ponds emit volatile organics to the atmosphere, but very little work has been done to characterize such emissions. Because oil, gas, and water phases are often in contact in geologic formations, we can expect that more highly soluble compounds (e.g., salts, alcohols, carbonyls, carboxyls, BTEX, etc.) partition preferentially into produced water. However, as the water in the ponds age, many physical, chemical, and biological processes alter the composition of the water, and therefore the composition and strength of volatile organic emissions. For example, some ponds are aerated to hasten evaporation, which also promotes oxidation of organics dissolved in the water. Some ponds are treated with microbes to promote bio-oxidation. In other words, emissions from ponds are expected to be a complex function of the composition of the water as it first enters the pond, and also of the age of the water and of its treatment history. We have conducted many measurements of emissions from produced water ponds in the Uintah Basin of eastern Utah, both by flux chamber and by evacuated canister sampling with inverse modeling. These measurements include fluxes of CO2, CH4, methanol, and many other volatile organic gases. We have also measured chemical compositions and microbial content of water in the ponds. Results of these measurements will be reported.

  2. Catchment hydrochemical processes controlling acidity and nitrogen in forest stream water

    International Nuclear Information System (INIS)

    Foelster, Jens

    2001-01-01

    Atmospheric deposition of air pollutants has been a severe threat to terrestrial and forest ecosystems for several decades. In Sweden sulphur deposition has caused acidification of soils and runoff, while nitrogen deposition only had a minor or local impact on runoff quality so far. During the last three decades, emission control has caused a decline in sulphur deposition, whereas nitrogen deposition on the other hand, has continued to increase to a rate several times above the natural background level. Long term changes in runoff acidity and nitrogen chemistry after these changes in deposition are of great concern. Monitoring of small, well-defined catchments including hydrochemistry of precipitation, soil and runoff, is a valuable tool for addressing this concern. When interpreting runoff data from such sites, the near-stream zone has been identified to be of crucial importance. The main objective for this thesis was to explain how catchment processes were related to short-term variation and long-term trends in the hydrochemistry of forest stream water. The field work was conducted on the strongly acidified and nitrogen limited Kindla catchment, with a special emphasis on the relationship between the near-stream zone and both stream acidity and nitrogen leaching. Furthermore, time series of hydrochemistry in forest stream water from 13 catchments were analysed for changes in acidity and nitrogen leaching. In three of these sites, soil water from E- and B-horizons was also analysed with regards to these questions. The investigations revealed that the near-stream zone was a net source of acidity in runoff at Kindla due to leaching of organic acids, although this contribution was overshadowed by sulphate from upland soils and deposition. The near-stream zone was also the main source for both organic nitrogen and nitrate to the stream, but the leaching rate was low, especially for inorganic nitrogen. In the 13 reference streams, sulphate concentrations declined in

  3. The potential of using organic side-streams produced in Ghana for generation of bio-fuel

    International Nuclear Information System (INIS)

    Laryea, G. N; Abdul-Samii, R.; Tottimeh, G.

    2014-01-01

    Bio-fuel can be generated from organic side-streams of maize, rice, millet, sorghum and groundnut by using fast pyrolysis technology. Data on side-streams of these crops were obtained from the Ministry of Food and Agriculture (MoFA) in 2010 for the study. The study shows that the estimated total crop side-streams generated was 3,475,413 t of which 2,345,903.5 of bio-fuel can be produced, given a potential energy equivalent of 42,226 PJ/y. The result shows a growth rate of 12.9 per cent in energy equivalent potential for synthetic fuel production as compared to the estimated production in 2009. Northern Region had the highest energy potential of 9,676 PJ/y (22.91%) of the total energy equivalent of bio-fuel, whereas, Greater Accra Region had the lowest with 183 PJ/y (0.43%). It is recommended that the available energy potential at the three northern regions of Ghana be utilised effectively when renewable energy policy is improved for a wider applications of side-streams from crops.(au)

  4. NM WAIDS: A PRODUCED WATER QUALITY AND INFRASTRUCTURE GIS DATABASE FOR NEW MEXICO OIL PRODUCERS

    Energy Technology Data Exchange (ETDEWEB)

    Martha Cather; Robert Lee; Ibrahim Gundiler; Andrew Sung; Naomi Davidson; Ajeet Kumar Reddy; Mingzhen Wei

    2003-04-01

    The New Mexico Water and Infrastructure Data System (NM WAIDS) seeks to alleviate a number of produced water-related issues in southeast New Mexico. The project calls for the design and implementation of a Geographical Information System (GIS) and integral tools that will provide operators and regulators with necessary data and useful information to help them make management and regulatory decisions. The major components of this system are: (1) databases on produced water quality, cultural and groundwater data, oil pipeline and infrastructure data, and corrosion information, (2) a web site capable of displaying produced water and infrastructure data in a GIS or accessing some of the data by text-based queries, (3) a fuzzy logic-based, site risk assessment tool that can be used to assess the seriousness of a spill of produced water, and (4) a corrosion management toolkit that will provide operators with data and information on produced waters that will aid them in deciding how to address corrosion issues. The various parts of NM WAIDS will be integrated into a website with a user-friendly interface that will provide access to previously difficult-to-obtain data and information. Primary attention during the first six months of this project has been focused on creating the water quality databases for produced water and surface water, along with collection of corrosion information and building parts of the corrosion toolkit. Work on the project to date includes: (1) Creation of a water quality database for produced water analyses. The database was compiled from a variety of sources and currently has over 4000 entries for southeast New Mexico. (2) Creation of a web-based data entry system for the water quality database. This system allows a user to view, enter, or edit data from a web page rather than having to directly access the database. (3) Creation of a semi-automated data capturing system for use with standard water quality analysis forms. This system improves the

  5. Characterization of water quality for streams in the southern Yampa River basin, northwestern Colorado. Water Resources Investigation

    International Nuclear Information System (INIS)

    Parker, R.S.

    1991-01-01

    Historically, the Yampa River basin in northwestern Colorado has been an area of coal-mining development. Coal mining generally has been developed in the southern part of the basin and at lower elevations. The purpose of the report is to characterize the stream water quality by summarizing selected major dissolved constituents for the streams that drain the southern part of the Yampa River basin. Characterization is done initially by providing a statistical summary of the constituents for individual water-quality sites in the study area. These statistical summaries can be used to help assess water-quality within specified stream reaches. Water-quality data are available for sites on most perennial streams in the study area, and these data provide the best information about the immediate stream reach. Water-quality data from all sites are combined into regions, and linear-regression equations between dissolved constituents and specific conductance are calculated. Such equations provide an estimate of the water-quality relations within these regions. The equations also indicate an increase in error as individual sites are combined

  6. Process for purification of waste water produced by a Kraft process pulp and paper mill

    Science.gov (United States)

    Humphrey, M. F. (Inventor)

    1979-01-01

    The water from paper and pulp wastes obtained from a mill using the Kraft process is purified by precipitating lignins and lignin derivatives from the waste stream with quaternary ammonium compounds, removing other impurities by activated carbon produced from the cellulosic components of the water, and then separating the water from the precipitate and solids. The activated carbon also acts as an aid to the separation of the water and solids. If recovery of lignins is also desired, then the precipitate containing the lignins and quaternary ammonium compounds is dissolved in methanol. Upon acidification, the lignin is precipitated from the solution. The methanol and quaternary ammonium compound are recovered for reuse from the remainder.

  7. Incorporation of water-use summaries into the StreamStats web application for Maryland

    Science.gov (United States)

    Ries, Kernell G.; Horn, Marilee A.; Nardi, Mark R.; Tessler, Steven

    2010-01-01

    Approximately 25,000 new households and thousands of new jobs will be established in an area that extends from southwest to northeast of Baltimore, Maryland, as a result of the Federal Base Realignment and Closure (BRAC) process, with consequent new demands on the water resources of the area. The U.S. Geological Survey, in cooperation with the Maryland Department of the Environment, has extended the area of implementation and added functionality to an existing map-based Web application named StreamStats to provide an improved tool for planning and managing the water resources in the BRAC-affected areas. StreamStats previously was implemented for only a small area surrounding Baltimore, Maryland, and it was extended to cover all BRAC-affected areas. StreamStats could provide previously published streamflow statistics, such as the 1-percent probability flood and the 7-day, 10-year low flow, for U.S. Geological Survey data-collection stations and estimates of streamflow statistics for any user-selected point on a stream within the implemented area. The application was modified for this study to also provide summaries of water withdrawals and discharges upstream from any user-selected point on a stream. This new functionality was made possible by creating a Web service that accepts a drainage-basin delineation from StreamStats, overlays it on a spatial layer of water withdrawal and discharge points, extracts the water-use data for the identified points, and sends it back to StreamStats, where it is summarized for the user. The underlying water-use data were extracted from the U.S. Geological Survey's Site-Specific Water-Use Database System (SWUDS) and placed into a Microsoft Access database that was created for this study for easy linkage to the Web service and StreamStats. This linkage of StreamStats with water-use information from SWUDS should enable Maryland regulators and planners to make more informed decisions on the use of water resources in the BRAC area, and

  8. A stochastic dynamic programming model for stream water quality ...

    Indian Academy of Sciences (India)

    R. Narasimhan (Krishtel eMaging) 1461 1996 Oct 15 13:05:22

    constraints of the water quality management problem; (ii) a water quality simulation model ... of acceptance and limited implementation of optimisation techniques. .... The response of river system to these sources of pollution can be integrated ...

  9. Surface and ground water quality in a restored urban stream affected by road salts

    Science.gov (United States)

    In 2001 research began in Minebank Run, MD to examine the impact of restoration on water quality. Our research area was to determine if road salts in the surface and ground waters are detrimental to the stream channel restoration. The upstream reach (UP), above the Baltimore I-...

  10. A model to predict stream water temperature across the conterminous USA

    Science.gov (United States)

    Catalina Segura; Peter Caldwell; Ge Sun; Steve McNulty; Yang Zhang

    2014-01-01

    Stream water temperature (ts) is a critical water quality parameter for aquatic ecosystems. However, ts records are sparse or nonexistent in many river systems. In this work, we present an empirical model to predict ts at the site scale across the USA. The model, derived using data from 171 reference sites selected from the Geospatial Attributes of Gages for Evaluating...

  11. Nitrogen patterns in subsurface waters of the Yzeron stream: effect of combined sewer overflows and subsurface-surface water mixing.

    Science.gov (United States)

    Aucour, A M; Bariac, T; Breil, P; Namour, P; Schmitt, L; Gnouma, R; Zuddas, P

    2013-01-01

    Urbanization subjects streams to increased nitrogen loads. Therefore studying nitrogen forms at the interface between urban stream and groundwater is important for water resource management. In this study we report results on water δ(18)O and nitrogen forms in subsurface waters of a stream (Yzeron, France). The sites studied were located upstream and downstream of combined sewer overflows (CSO) in a rural area and a periurban area, respectively. Water δ(18)O allowed us to follow the mixing of subsurface water with surface water. Dissolved organic nitrogen and organic carbon of fine sediment increased by 20-30% between rural and periurban subsurface waters in the cold season, under high flow. The highest nitrate levels were observed in rural subsurface waters in the cold season. The lowest nitrate levels were found in periurban subsurface waters in the warm season, under low flow. They corresponded to slow exchange of subsurface waters with channel water. Thus reduced exchange between surface and subsurface waters and organic-matter-rich input seemed to favor nitrate reduction in the downstream, periurban, subsurface waters impacted by CSO.

  12. NM WAIDS: A PRODUCED WATER QUALITY AND INFRASTRUCTURE GIS DATABASE FOR NEW MEXICO OIL PRODUCERS

    Energy Technology Data Exchange (ETDEWEB)

    Martha Cather; Robert Lee; Ibrahim Gundiler; Andrew Sung

    2003-09-24

    The New Mexico Water and Infrastructure Data System (NM WAIDS) seeks to alleviate a number of produced water-related issues in southeast New Mexico. The project calls for the design and implementation of a Geographical Information System (GIS) and integral tools that will provide operators and regulators with necessary data and useful information to help them make management and regulatory decisions. The major components of this system are: (1) Databases on produced water quality, cultural and groundwater data, oil pipeline and infrastructure data, and corrosion information. (2) A web site capable of displaying produced water and infrastructure data in a GIS or accessing some of the data by text-based queries. (3) A fuzzy logic-based, site risk assessment tool that can be used to assess the seriousness of a spill of produced water. (4) A corrosion management toolkit that will provide operators with data and information on produced waters that will aid them in deciding how to address corrosion issues. The various parts of NM WAIDS will be integrated into a website with a user-friendly interface that will provide access to previously difficult-to-obtain data and information. Primary attention during the first six months of this project was focused on creating the water quality databases for produced water and surface water, along with collecting of corrosion information and building parts of the corrosion toolkit. Work on the project to date includes: (1) Creation of a water quality database for produced water analyses. The database was compiled from a variety of sources and currently has over 7000 entries for New Mexico. (2) Creation of a web-based data entry system for the water quality database. This system allows a user to view, enter, or edit data from a web page rather than having to directly access the database. (3) Creation of a semi-automated data capturing system for use with standard water quality analysis forms. This system improves the accuracy and speed

  13. Produced water management - clean and safe oil and gas production

    International Nuclear Information System (INIS)

    2006-01-01

    The conference contains 22 presentations on topics within pollution sources and abatement, discharge reductions, water analysis and monitoring, water production, treatment and injection, enhanced recovery, condensate water, produced water markets, separation technologies for oil/gas/condensate and water, oil removal from solids, environmental risks of oil and gas production and environmental impacts on ecosystems and fisheries. Some oil field case histories are presented. The main focus is on the northern areas such as the North Sea, the north Atlantic Ocean and the Barents Sea, and technological aspects (tk)

  14. Produced water management - clean and safe oil and gas production

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    2006-07-01

    The conference contains 22 presentations on topics within pollution sources and abatement, discharge reductions, water analysis and monitoring, water production, treatment and injection, enhanced recovery, condensate water, produced water markets, separation technologies for oil/gas/condensate and water, oil removal from solids, environmental risks of oil and gas production and environmental impacts on ecosystems and fisheries. Some oil field case histories are presented. The main focus is on the northern areas such as the North Sea, the north Atlantic Ocean and the Barents Sea, and technological aspects (tk)

  15. Lithium recovery from shale gas produced water using solvent extraction

    International Nuclear Information System (INIS)

    Jang, Eunyoung; Jang, Yunjai; Chung, Eunhyea

    2017-01-01

    Shale gas produced water is hypersaline wastewater generated after hydraulic fracturing. Since the produced water is a mixture of shale formation water and fracturing fluid, it contains various organic and inorganic components, including lithium, a useful resource for such industries as automobile and electronics. The produced water in the Marcellus shale area contains about 95 mg/L lithium on average. This study suggests a two-stage solvent extraction technique for lithium recovery from shale gas produced water, and determines the extraction mechanism of ions in each stage. All experiments were conducted using synthetic shale gas produced water. In the first-stage, which was designed for the removal of divalent cations, more than 94.4% of Ca"2"+, Mg"2"+, Sr"2"+, and Ba"2"+ ions were removed by using 1.0 M di-(2-ethylhexyl) phosphoric acid (D2EHPA) as an extractant. In the second-stage, for lithium recovery, we could obtain a lithium extraction efficiency of 41.2% by using 1.5 M D2EHPA and 0.3 M tributyl phosphate (TBP). Lithium loss in the first-stage was 25.1%, and therefore, the total amount of lithium recovered at the end of the two-step extraction procedure was 30.8%. Through this study, lithium, one of the useful mineral resources, could be selectively recovered from the shale gas produced water and it would also reduce the wastewater treatment cost during the development of shale gas. - Highlights: • Lithium was extracted from shale gas produced water using an organic solvent. • Two-stage solvent extraction technique was applied. • Divalent cations were removed in the first stage by D2EHPA. • Lithium was selectively recovered in the second stage by using TBP with D2EHPA.

  16. Potential Impacts of Climate Change on Stream Water Temperatures Across the United States

    Science.gov (United States)

    Ehsani, N.; Knouft, J.; Ficklin, D. L.

    2017-12-01

    Analyses of long-term observation data have revealed significant changes in several components of climate and the hydrological cycle over the contiguous United States during the twentieth and early twenty-first century. Mean surface air temperatures have significantly increased in most areas of the country. In addition, water temperatures are increasing in many watersheds across the United States. While there are numerous studies assessing the impact of climate change on air temperatures at regional and global scales, fewer studies have investigated the impacts of climate change on stream water temperatures. Projecting increases in water temperature are particularly important to the conservation of freshwater ecosystems. To achieve better insights into attributes regulating population and community dynamics of aquatic biota at large spatial and temporal scales, we need to establish relationships between environmental heterogeneity and critical biological processes of stream ecosystems at these scales. Increases in stream temperatures caused by the doubling of atmospheric carbon dioxide may result in a significant loss of fish habitat in the United States. Utilization of physically based hydrological-water temperature models is computationally demanding and can be onerous to many researchers who specialize in other disciplines. Using statistical techniques to analyze observational data from 1760 USGS stream temperature gages, our goal is to develop a simple yet accurate method to quantify the impacts of climate warming on stream water temperatures in a way that is practical for aquatic biologists, water and environmental management purposes, and conservation practitioners and policy-makers. Using an ensemble of five global climate models (GCMs), we estimate the potential impacts of climate change on stream temperatures within the contiguous United States based on recent trends. Stream temperatures are projected to increase across the US, but the magnitude of the

  17. Assessing the suitability of stream water for five different uses and its aquatic environment.

    Science.gov (United States)

    Fulazzaky, Mohamad Ali

    2013-01-01

    Surface water is one of the essential resources for supporting sustainable development. The suitability of such water for a given use depends both on the available quantity and tolerable quality. Temporary status for a surface water quality has been identified extensively. Still the suitability of the water for different purposes needs to be verified. This study proposes a water quality evaluation system to assess the aptitude of the Selangor River water for aquatic biota, drinking water production, leisure and aquatic sport, irrigation use, livestock watering, and aquaculture use. Aptitude of the water has been classified in many parts of the river segment as unsuitable for aquatic biota, drinking water production, leisure and aquatic sport as well as aquaculture use. The water quality aptitude classes of the stream water for nine locations along the river are evaluated to contribute to decision support system. The suitability of the water for five different uses and its aquatic ecosystem are verified.

  18. E. coli Surface Properties Differ between Stream Water and Sediment Environments.

    Science.gov (United States)

    Liang, Xiao; Liao, Chunyu; Thompson, Michael L; Soupir, Michelle L; Jarboe, Laura R; Dixon, Philip M

    2016-01-01

    The importance of E. coli as an indicator organism in fresh water has led to numerous studies focusing on cell properties and transport behavior. However, previous studies have been unable to assess if differences in E. coli cell surface properties and genomic variation are associated with different environmental habitats. In this study, we investigated the variation in characteristics of E. coli obtained from stream water and stream bottom sediments. Cell properties were measured for 77 genomically different E. coli strains (44 strains isolated from sediments and 33 strains isolated from water) under common stream conditions in the Upper Midwestern United States: pH 8.0, ionic strength 10 mM and 22°C. Measured cell properties include hydrophobicity, zeta potential, net charge, total acidity, and extracellular polymeric substance (EPS) composition. Our results indicate that stream sediment E. coli had significantly greater hydrophobicity, greater EPS protein content and EPS sugar content, less negative net charge, and higher point of zero charge than stream water E. coli . A significant positive correlation was observed between hydrophobicity and EPS protein for stream sediment E. coli but not for stream water E. coli . Additionally, E. coli surviving in the same habitat tended to have significantly larger (GTG) 5 genome similarity. After accounting for the intrinsic impact from the genome, environmental habitat was determined to be a factor influencing some cell surface properties, such as hydrophobicity. The diversity of cell properties and its resulting impact on particle interactions should be considered for environmental fate and transport modeling of aquatic indicator organisms such as E. coli .

  19. E. coli Surface Properties Differ between Stream Water and Sediment Environments

    Directory of Open Access Journals (Sweden)

    Xiao Liang

    2016-11-01

    Full Text Available The importance of E. coli as an indicator organism in fresh water has led to numerous studies focusing on cell properties and transport behavior. However, previous studies have been unable to assess if differences in E. coli cell surface properties and genomic variation are associated with different environmental habitats. In this study, we investigated the variation in characteristics of E. coli obtained from stream water and stream bottom sediments. Cell properties were measured for 77 genomically different E. coli strains (44 strains isolated from sediments and 33 strains isolated from water under common stream conditions in the Upper Midwestern United States: pH 8.0, ionic strength 10mM and 22˚C. Measured cell properties include hydrophobicity, zeta potential, net charge, total acidity and extracellular polymeric substance (EPS composition. Our results indicate that stream sediment E. coli had significantly greater hydrophobicity, greater EPS protein content and EPS sugar content, less negative net charge, and higher point of zero charge than stream water E. coli. A significant positive correlation was observed between hydrophobicity and EPS protein for stream sediment E. coli but not for stream water E. coli. Additionally, E. coli surviving in the same habitat tended to have significantly larger (GTG5 genome similarity. After accounting for the intrinsic impact from the genome, environmental habitat was determined to be a factor influencing some cell surface properties, such as hydrophobicity. The diversity of cell properties and its resulting impact on particle interactions should be considered for environmental fate and transport modeling of aquatic indicator organisms such as E. coli.

  20. Sources of trends in water-quality data for selected streams in Texas, 1975-89 water years

    Science.gov (United States)

    Schertz, T.L.; Wells, F.C.; Ohe, D.J.

    1994-01-01

    Sources of trends in water-quality data for selected streams in Texas for the 1975-89 water years were investigated in this study. The investigation of sources was confined to distinct geographic patterns in the trend indicators for one constituent or for a group of related constituents.

  1. An assessment of whole effluent toxicity testing as a means of regulating waters produced by the oil and gas industry

    International Nuclear Information System (INIS)

    Hill, S.L.; Bergman, H.L.

    1993-01-01

    Approximately 500 million barrels of produced water are discharged to Wyoming's surface waters by the oil and gas industry. This discharges are of two types: direct and indirect. The direct discharges have been issued NPDES permits requiring whole effluent toxicity testing. Toxicity testing requirements have not been incorporated into permits written for indirect discharges because of the applicability of toxicity testing for regulating these waters has not been determined. Preliminary testing has shown that most produced waters are toxic at the point of discharge because of high concentrations of hydrogen sulfide, but that the toxicity of an indirect discharge is often lost before it reaches a receiving stream. Thus, whole effluent toxicity testing of an indirect discharge may be overly stringent, resulting in treatment or reinjection of the water or closure of the well. Any of these options would have severe economic consequences for oil producers and the state's agricultural industry. The purpose of this study was to determine whether whole effluent toxicity testing actually predicts the in-stream effects of indirect discharges on water quality and benthic invertebrate populations. The authors will report the results of short-term ambient toxicity tests and in-stream bioassessments performed upstream and downstream of six indirect discharges located in four drainages in Wyoming

  2. Three-dimensionally spiral structure of the water stream induced by a centrifugal stirrer in large aqua-cultural ponds

    Science.gov (United States)

    Itano, Tomoaki; Inagaki, Taishi; Nakamura, Choji; Sugihara-Seki, Masako; Hyodo, Jinsuke

    2017-11-01

    We have conducted measurements of the water stream produced by a mechanical stirrer (diameter 2.4[m], electric power 50[W]) located in shallow rectangular reservoirs (small 0.7[ha], large 3.7[ha]), which may be employed as a cost-efficient aerator for the aqua-cultural purpose, with the aid of both particle tracking velocimetry by passive tracers floating on the surface and direct measurement by electro-magnetic velocimeter under the surface. The present measurements indicate that the stirrer drives primarily the horizontally rotating water stream and secondarily the vertical convection between the surface and the bottom of the reservoir, which results in the three-dimensionally spiral-shaped water streams scaled vertically by just a meter but horizontally by more than ten meters. It is suggested that the spiral structure driven by the stirrer may activate the underwater vertical mixing and enhance dissolved oxygen at the bottom of aqua-cultural pond more effectively than the paddle-wheel aerators commonly used in aqua-cultural ponds. This research was financially supported in part by the Kansai University Fund for Supporting Young Scholars, 2016-2017.

  3. Variations in statewide water quality of New Jersey streams, water years 1998-2009

    Science.gov (United States)

    Heckathorn, Heather A.; Deetz, Anna C.

    2012-01-01

    (control stations that are located on reaches of streams relatively unaffected by human activity) during water years 1998-2009. Results of tests on concentrations of total dissolved solids, dissolved chloride, dissolved nitrite plus nitrate, total phosphorus, and total nitrogen indicate a significant difference in water quality at Statewide Status stations but not at Background stations during the study period. Excluding water year 2009, all significant changes that were observed in the median concentrations were ultimately increases, except for total phosphorus, which varied significantly but in an inconsistent pattern during water years 1998-2009. Streamflow data aided in the interpretation of the results for this study. Extreme values of water-quality constituents generally followed inverse patterns of streamflow. Low streamflow conditions helped explain elevated concentrations of several constituents during water years 2001-02. During extreme drought conditions in 2002, maximum concentrations occurred for four of the six water-quality constituents examined in this study at Statewide Status stations (maximum concentration of 4,190 milligrams per liter of total dissolved solids) and three of six constituents at Background stations (maximum concentration of 179 milligrams per liter of total dissolved solids). The changes in water quality observed in this study parallel many of the findings from previous studies of trends in New Jersey.

  4. Geochemical orientation survey of stream sediment, stream water, and ground water near uranium prospects, Monticello area, New York. National Uranium Resource Evaluation Program

    International Nuclear Information System (INIS)

    Rose, A.W.; Smith, A.T.; Wesolowski, D.

    1982-08-01

    A detailed geochemical test survey has been conducted in a 570 sq km area around six small copper-uranium prospects in sandstones of the Devonian Catskill Formation near Monticello in southern New York state. This report summarizes and interprets the data for about 500 stream sediment samples, 500 stream water samples, and 500 ground water samples, each analyzed for 40 to 50 elements. The groundwater samples furnish distinctive anomalies for uranium, helium, radon, and copper near the mineralized localities, but the samples must be segregated into aquifers in order to obtain continuous well-defined anomalies. Two zones of uranium-rich water (1 to 16 parts per billion) can be recognized on cross sections; the upper zone extends through the known occurrences. The anomalies in uranium and helium are strongest in the deeper parts of the aquifers and are diluted in samples from shallow wells. In stream water, copper and uranium are slightly anomalous, as in an ore factor derived from factor analysis. Ratios of copper, uranium, and zinc to conductivity improve the resolution of anomalies. In stream sediment, extractable uranium, copper, niobium, vanadium, and an ore factor furnish weak anomalies, and ratios of uranium and copper to zinc improve the definition of anomalies. The uranium/thorium ratio is not helpful. Published analyses of rock samples from the nearby stratigraphic section show distinct anomalies in the zone containing the copper-uranium occurrences. This report is being issued without the normal detailed technical and copy editing, to make the data available to the public before the end of the National Uranium Reconnaissance Evaluation program

  5. Geochemical orientation survey of stream sediment, stream water, and ground water near uranium prospects, Monticello area, New York. National Uranium Resource Evaluation Program

    Energy Technology Data Exchange (ETDEWEB)

    Rose, A. W.; Smith, A. T.; Wesolowski, D.

    1982-08-01

    A detailed geochemical test survey has been conducted in a 570 sq km area around six small copper-uranium prospects in sandstones of the Devonian Catskill Formation near Monticello in southern New York state. This report summarizes and interprets the data for about 500 stream sediment samples, 500 stream water samples, and 500 ground water samples, each analyzed for 40 to 50 elements. The groundwater samples furnish distinctive anomalies for uranium, helium, radon, and copper near the mineralized localities, but the samples must be segregated into aquifers in order to obtain continuous well-defined anomalies. Two zones of uranium-rich water (1 to 16 parts per billion) can be recognized on cross sections; the upper zone extends through the known occurrences. The anomalies in uranium and helium are strongest in the deeper parts of the aquifers and are diluted in samples from shallow wells. In stream water, copper and uranium are slightly anomalous, as in an ore factor derived from factor analysis. Ratios of copper, uranium, and zinc to conductivity improve the resolution of anomalies. In stream sediment, extractable uranium, copper, niobium, vanadium, and an ore factor furnish weak anomalies, and ratios of uranium and copper to zinc improve the definition of anomalies. The uranium/thorium ratio is not helpful. Published analyses of rock samples from the nearby stratigraphic section show distinct anomalies in the zone containing the copper-uranium occurrences. This report is being issued without the normal detailed technical and copy editing, to make the data available to the public before the end of the National Uranium Reconnaissance Evaluation program.

  6. Application of HEC-RAS water quality model to estimate contaminant spreading in small stream

    Energy Technology Data Exchange (ETDEWEB)

    Halaj, Peter; Bárek, Viliam; Halajová, Anna Báreková; Halajová, Denisa [Slovak University of Agriculture in Nitra, Nitra (Slovakia)

    2013-07-01

    The paper presents study of some aspects of HEC-RAS water quality model connected to simulation of contaminant transport in small stream. Authors mainly focused on one of the key tasks in process of pollutant transport modelling in streams - determination of the dispersion characteristics represented by longitudinal dispersion coefficient D. Different theoretical and empirical formulas have been proposed for D value determination and they have revealed that the coefficient is variable parameter that depends on hydraulic and morphometric characteristics of the stream reaches. Authors compare the results of several methods of coefficient D assessment, assuming experimental data obtained by tracer studies and compare them with results optimized by HEC-RAS water quality model. The analyses of tracer study and computation outputs allow us to outline the important aspects of longitudinal dispersion coefficient set up in process of the HEC-RAS model use. Key words: longitudinal dispersion coefficient, HEC-RAS, water quality modeling.

  7. Assessment of Heavy Metals in the Water of Sahastradhara Hill Stream at Dehradun, India

    Directory of Open Access Journals (Sweden)

    Pawan Kumar Bharti

    2014-09-01

    Full Text Available A study on heavy metals assessment in the water of Sahastradhara hill-stream was conducted with different five sites at significant differences. The present paper deals with the water quality status of Sahastradhara stream by the assessment of heavy metals. Heavy Metals were found in fluctuated trend from first upstream to last downstream. The values of almost all Heavy Metals were found in increasing manner especially after the fourth sampling site. After the third sampling station, a solid waste dumping site was found. So, there may be a relation between heavy metals in stream water and solid waste dumping site. Concentrations of all Heavy Metals at fourth and fifth sampling site were found very high. DOI: http://dx.doi.org/10.3126/ije.v3i3.11076 International Journal of Environment Vol.3(3 2014: 164-172

  8. USE OF DIATOMS TO ASSES WATER QUALITY OF ANTHROPOGENICALLY MODIFIED MATYSÓWKA STREAM

    Directory of Open Access Journals (Sweden)

    Teresa Noga

    2013-04-01

    Full Text Available Matysówka stream is small, under 6 km long watercourse, which is a right-bank tributary of Strug River. In 2009–2011studies on the subject of diversity of diatom communities using diatom indices IPS, GDI and TDI for water quality assessment were conducted. On the stream 271 diatom taxa were identified, among which: Achnanthidium minutissimum var. minutissimum, Navicula cryptotenella, N. gregaria, N. lanceolata, N. tripunctata, Nitzschia linearis, N. pusilla, N. recta, Planothidium frequentissimum, Rhoicosphenia abbreviata were the most frequent. Middle and lower section of Matysówka stream was characterized by increased concentrations of phosphates, nitrites, ammonium, total phosphorus and nitrogen, BOD5. On the basis of diatom indices IPS and GDI waters were characterized as III–IV quality classes, while the TDI index revealed the worst water quality classes (IV–V.

  9. Shade and flow effects on ammonia retention in macrophyte-rich streams: implications for water quality

    International Nuclear Information System (INIS)

    Wilcock, Robert J.; Scarsbrook, Mike R.; Cooke, James G.; Costley, Kerry J.; Nagels, John W.

    2004-01-01

    Controlled releases of NH 4 -N and conservative tracers (Br - and Cl - ) to five reaches of four streams with contrasting macrophyte communities have shown differing retentions, largely as a result of the way plants interact with stream flow and velocity. First-order constants (k) were 1.0-4.8 d -1 and retention of NH 4 -N was 6-71% of amounts added to each reach. Distance travelled before a 50% reduction in concentration was achieved were 40-450 m in three streams under low-flow conditions, and 2400-3800 m at higher flows. Retention (%) of NH 4 -N can be approximated by a simple function of travel time and k, highlighting the importance of the relationship between macrophytes and stream velocity on nutrient processing. This finding has significant management implications, particularly with respect to restoration of riparian shade. Small streams with predominantly marginal emergent plants are likely to have improved retention of NH 4 -N as a result of shading or other means of reducing plant biomass. Streams dominated by submerged macrophytes will have impaired NH 4 -N retention if plant biomass is reduced because of reduced contact times between NH 4 -N molecules and reactive sites. In these conditions water resource managers should utilise riparian shading in concert with unshaded vegetated reaches to achieve a balance between enhanced in-stream habitat and nutrient processing capacity

  10. Development of device producing electrolyzed water for home care

    International Nuclear Information System (INIS)

    Umimoto, K; Nagata, S; Yanagida, J

    2013-01-01

    When water containing ionic substances is electrolyzed, electrolyzed water with strong bactericidal ability due to the available chlorine(AC) is generated on the anode side. Slightly acidic to neutral electrolyzed water (pH 6.5 to 7.5) is physiological pH and is suitable for biological applications. For producing slightly acidic to neutral electrolyzed water simply, a vertical-type electrolytic tank with an asymmetric structure was made. As a result, a small amount of strongly alkaline water was generated in the upper cathodic small chamber, and a large amount of weakly acidic water generated in the lower anodic large chamber. The pH and AC concentration in solutin mixed with both electrolyzed water were 6.3 and 39.5 ppm, respectively, This solution was slightly acidic to neutral electrolyzed water and had strong bactericidal activity. This device is useful for producing slightly acidic to neutral electrolyzed water as a disinfectant to employ at home care, when considering economic and environmental factors, since it returns to ordinary water after use.

  11. Low-Cost Alternative for the Measurement of Water Levels in Surface Water Streams

    Directory of Open Access Journals (Sweden)

    Luis E. PEÑA

    2017-11-01

    Full Text Available Flood risk management and water resources planning involve a deep knowledge of surface streams so that mitigation strategies and climate change adaptations can be implemented. Commercially, there is a wide range of technologies for the measurement of hydroclimatic variables; however, many of these technologies may not be affordable for institutions with limited budgets. This paper has two main objectives: 1 Present the design of an ultrasound-based water level measurement system, and 2 Propose a methodological alternative for the development of instruments, according to the needs of institutions conducting monitoring of surface waterbodies. To that end, the proposed methodology is based on selection processes defined according to the specific needs of each waterbody. The prototype was tested in real-world scale, with the potential to obtain accurate measurements. Lastly, we present the design of the ultrasound-based water level measurement instrument, which can be built at a low cost. Low-cost instruments can potentially contribute to the sustainable instrumental autonomy of environmental entities and help define measurement and data transmission standards based on the specific requirements of the monitoring.

  12. Flat Branch monitoring project: stream water temperature and sediment responses to forest cutting in the riparian zone

    Science.gov (United States)

    Barton D. Clinton; James M. Vose; Dick L. Fowler

    2010-01-01

    Stream water protection during timber-harvesting activities is of primary interest to forest managers. In this study, we examine the potential impacts of riparian zone tree cutting on water temperature and total suspended solids. We monitored stream water temperature and total suspended solids before and after timber harvesting along a second-order tributary of the...

  13. Sampling procedure for lake or stream surface water chemistry

    Science.gov (United States)

    Robert Musselman

    2012-01-01

    Surface waters collected in the field for chemical analyses are easily contaminated. This research note presents a step-by-step detailed description of how to avoid sample contamination when field collecting, processing, and transporting surface water samples for laboratory analysis.

  14. Phytophthora pseudopolonica sp. nov., a new species recovered from stream water in subtropical forests of China.

    Science.gov (United States)

    Li, Wen-Wen; Zhao, Wen-Xia; Huai, Wen-Xia

    2017-09-01

    A new species of the genus Phytophthora was isolated from stream water in the subtropical forests of China during a survey of forest Phytophthora from 2011 to 2013. This new species is formally described here and named Phytophthora pseudopolonica sp. nov. This new homothallic species is distinct from other known Phytophthora species in morphology and produces nonpapillate and noncaducous sporangia with internal proliferation. Spherical hyphal swellings and thin-walled chlamydospores are abundant when the species is kept in sterile water. The P. pseudopolonica sp. nov. forms smooth oogonia with paragynous and sometimes amphigynous antheridia. The optimum growth temperature of the species is 30 °C in V8-juice agar with β-sitosterol, yet it barely grows at 5 °C and 35 °C. Based on sequences of the internal transcribed spacer and the combined β-tubulin and elongation factor 1α gene sequence data, isolates of the new species cluster together into a single branch and are close to Phytophthora polonicabelonging to clade 9.

  15. Occurrence and in vitro bioactivity of estrogen, androgen, and glucocorticoid compounds in a nationwide screen of United States stream waters

    Data.gov (United States)

    U.S. Environmental Protection Agency — In vitro bioactivity concentrations and chemical concentrations of estrogens, androgens, and glucocorticoids from a nationwide screen of United States stream water...

  16. Membrane Technology for Produced Water in Lea County

    Energy Technology Data Exchange (ETDEWEB)

    Cecilia Nelson; Ashok Ghosh

    2011-06-30

    Southeastern New Mexico (SENM) is rich in mineral resources, including oil and gas. Produced water is a byproduct from oil and gas recovery operations. SENM generates approximately 400 million barrels per year of produced water with total dissolved solids (TDS) as high as ~ 200,000 ppm. Typically, produced water is disposed of by transporting it to injection wells or disposal ponds, costing around $1.2 billion per year with an estimated use of 0.3 million barrels of transportation fuel. New Mexico ranks first among U.S. states in potash production. Nationally, more than 85% of all potash produced comes from the Carlsbad potash district in SENM. Potash manufacturing processes use large quantities of water, including fresh water, for solution mining. If the produced water from oilfield operations can be treated and used economically in the potash industry, it will provide a beneficial use for the produced water as well as preserve valuable water resources in an area where fresh water is scarce. The goal of this current research was to develop a prototype desalination system that economically treats produced water from oil and/or natural gas operations for the beneficial use of industries located in southeastern New Mexico. Up until now, most water cleaning technologies have been developed for treating water with much lower quantities of TDS. Seawater with TDS of around 30,000 ppm is the highest concentration that has been seriously studied by researchers. Reverse osmosis (RO) technology is widely used; however the cost remains high due to high-energy consumption. Higher water fluxes and recoveries are possible with a properly designed Forward Osmosis (FO) process as large driving forces can be induced with properly chosen membranes and draw solution. Membrane fouling and breakdown is a frequent and costly problem that drives the cost of desalination very high. The technology developed by New Mexico Tech (NMT) researchers not only protects the membrane, but has also

  17. Agriculture and stream water quality: A biological evaluation of erosion control practices

    Science.gov (United States)

    Lenat, David R.

    1984-07-01

    Agricultural runoff affects many streams in North Carolina. However, there is is little information about either its effect on stream biota or any potential mitigation by erosion control practices. In this study, benthic macroinvertebrates were sampled in three different geographic areas of North Carolina, comparing control watersheds with well-managed and poorly managed watersheds. Agricultural streams were characterized by lower taxa richness (especially for intolerant groups) and low stability. These effects were most evident at the poorly managed sites. Sedimentation was the apparent major problem, but some changes at agricultural sites implied water quality problems. The groups most intolerant of agricultural runoff were Ephemeroptera, Plecoptera and Trichoptera. Tolerant species were usually filter-feeders or algal grazers, suggesting a modification of the food web by addition of particulate organic matter and nutrients. This study clearly indicates that agricultural runoff can severely impact stream biota. However, this impact can be greatly mitigated by currently recommended erosion control practices.

  18. Environmental contaminants in oil field produced waters discharged into wetlands

    International Nuclear Information System (INIS)

    Ramirez, P. Jr.

    1994-01-01

    The 866-acre Loch Katrine wetland complex in Park County, Wyoming provides habitat for many species of aquatic birds. The complex is sustained primarily by oil field produced waters. This study was designed to determine if constituents in oil field produced waters discharged into Custer Lake and to Loch Katrine pose a risk to aquatic birds inhabiting the wetlands. Trace elements, hydrocarbons and radium-226 concentrations were analyzed in water, sediment and biota collected from the complex during 1992. Arsenic, boron, radium-226 and zinc were elevated in some matrices. The presence of radium-226 in aquatic vegetation suggests that this radionuclide is available to aquatic birds. Oil and grease concentrations in water from the produced water discharge exceeded the maximum 10 mg/l permitted by the WDEQ (1990). Total aliphatic and aromatic hydrocarbon concentrations in sediments were highest at the produced water discharge, 6.376 μg/g, followed by Custer Lake, 1.104 μg/g. The higher levels of hydrocarbons found at Custer Lake, compared to Loch Katrine, may be explained by Custer Lake's closer proximity to the discharge. Benzo(a)pyrene was not detected in bile from gadwalls collected at Loch Katrine but was detected in bile from northern shovelers collected at Custer Lake. Benzo(a)pyrene concentrations in northern shoveler bile ranged from 500 to 960 ng/g (ppb) wet weight. The presence of benzo(a)pyrene in the shovelers indicates exposure to petroleum hydrocarbons

  19. Concentration of radiocesium in stream water from a mountainous catchment area during rainfall events

    International Nuclear Information System (INIS)

    Nakamura, Kimihito; Yasutaka, Tetsuo; Hatakeyama, Masato

    2012-01-01

    Terrestrial and aquatic systems were contaminated with radioactive materials following the nuclear accident at Fukushima Daiichi Nuclear Power Station on 11 March, 2011. It is important that levels of radiocesium (Cs) in stream water from affected areas be monitored as this water is used for paddy irrigation and domestic water. Additionally, soil particles and organic matter from the streams are deposited in rivers, estuaries and into the ocean. Predictions suggest that Cs levels will increase during intense rainfall-runoff events. To check this prediction, we monitored temporal changes in runoff events and Cs levels in stream water from a mountainous catchment area northwest of the Fukushima plant. In March and April, 2012, the concentrations of Cs and suspended solids (SS) in stream water taken from low-level water flow were found to be 0.2–0.3 Bq/L and 2–7 mg/L, respectively. A heavy rainfall event in July 2012 resulted in an increase and subsequent decrease of both the runoff volume and SS concentration. At the beginning of the rainfall event the concentration of Cs absorbed in the SS was measured to be 23 Bq/L, this decreased gradually to 0.3 Bq/L over the course of the event. The concentration of Cs dissolved in the water was 0.1 Bq/L, this decreased only slightly during the runoff event. During a low rainfall event in September 2012 the concentration of Cs absorbed in the SS at the beginning of the rainfall event was found to be 15 Bq/L, this decreased gradually to 0.5 Bq/L as the amount of SS in the water decreased. The concentration of Cs dissolved in the water was 0.2 Bq/L, again this decreased only slightly over the course of the runoff event. The Cs levels in stream water, during rainfall-runoff events, were primary influenced by the concentration of SS. The amount of Cs dissolved in the water, on the other hand, was roughly constant at 0.1–0.2 Bq/L. The results of this study indicate that, although the concentration of Cs in stream water is below

  20. Concentration of radiocesium in stream water from a mountainous catchment area during rainfall events

    International Nuclear Information System (INIS)

    Nakamura, Kimihito; Yasutaka, Tetsuo; Hatakeyama, Masato

    2013-01-01

    Terrestrial and aquatic systems were contaminated with radioactive materials following the nuclear accident at Fukushima Daiichi Nuclear Power Station on 11 March, 2011. It is important that levels of radiocesium (Cs) in stream water from affected areas be monitored as this water is used for paddy irrigation and domestic water. Additionally, soil particles and organic matter from the streams are deposited in rivers, estuaries and into the ocean. Predictions suggest that Cs levels will increase during intense rainfall-runoff events. To check this prediction, we monitored temporal changes in runoff events and Cs levels in stream water from a mountainous catchment area northwest of the Fukushima plant. In March and April, 2012, the concentrations of Cs and suspended solids (SS) in stream water taken from low-level water flow were found to be 0.2-0.3 Bq/L and 2-7 mg/L, respectively. A heavy rainfall event in July 2012 resulted in an increase and subsequent decrease of both the runoff volume and SS concentration. At the beginning of the rainfall event the concentration of Cs absorbed in the SS was measured to be 23 Bq/L, this decreased gradually to 0.3 Bq/L over the course of the event. The concentration of Cs dissolved in the water was 0.1 Bq/L, this decreased only slightly during the runoff event. During a low rainfall event in September 2012 the concentration of Cs absorbed in the SS at the beginning of the rainfall event was found to be 15 Bq/L, this decreased gradually to 0.5 Bq/L as the amount of SS in the water decreased. The concentration of Cs dissolved in the water was 0.2 Bq/L, again this decreased only slightly over the course of the runoff event. The Cs levels in stream water, during rainfall-runoff events, were primary influenced by the concentration of SS. The amount of Cs dissolved in the water, on the other hand, was roughly constant at 0.1-0.2 Bq/L. The results of this study indicate that, although the concentration of Cs in stream water is below the

  1. Natural and artificial radionuclides in the Suez Canal bottom sediments and stream water

    International Nuclear Information System (INIS)

    El-Tahawy, M.S.; Farouk, M.A.; Ibrahiem, N.M.; El-Mongey, S.A.M.

    1994-01-01

    Concentration of natural and artificial radionuclides in Suez Canal bottom sediments and stream water have been measured using γ spectrometers based on a hyper-pure Ge detector. The activity concentrations of 238 U series, 232 Th series and 40 K did not exceed 16.0, 15.5 and 500.0 Bq kg -1 dry weight for sediments. The activity concentration of 238 U series and 40 K did not exceed 0.6 and 18.0 Bq l -1 for stream water. (author)

  2. Natural and artificial radionuclides in the Suez Canal bottom sediments and stream water

    Science.gov (United States)

    El-Tahawy, M. S.; Farouk, M. A.; Ibrahiem, N. M.; El-Mongey, S. A. M.

    1994-07-01

    Concentration of natural and artificial radionuclides in Suez Canal bottom sediments and stream water have been measured using γ spectrometers based on a hyper-pure Ge detector. The activity concentrations of 238U series, 232Th series and 40K did not exceed 16.0, 15.5 and 500.0 Bq kg-1 dry weight for sediments. The activity concentration of 238U series and 40K did not exceed 0.6 and 18.0 Bq 1-1 for stream water.

  3. A simple metric to predict stream water quality from storm runoff in an urban watershed.

    Science.gov (United States)

    Easton, Zachary M; Sullivan, Patrick J; Walter, M Todd; Fuka, Daniel R; Petrovic, A Martin; Steenhuis, Tammo S

    2010-01-01

    The contribution of runoff from various land uses to stream channels in a watershed is often speculated and used to underpin many model predictions. However, these contributions, often based on little or no measurements in the watershed, fail to appropriately consider the influence of the hydrologic location of a particular landscape unit in relation to the stream network. A simple model was developed to predict storm runoff and the phosphorus (P) status of a perennial stream in an urban watershed in New York State using the covariance structure of runoff from different landscape units in the watershed to predict runoff in time. One hundred and twenty-seven storm events were divided into parameterization (n = 85) and forecasting (n = 42) data sets. Runoff, dissolved P (DP), and total P (TP) were measured at nine sites distributed among three land uses (high maintenance, unmaintained, wooded), three positions in the watershed (near the outlet, midwatershed, upper watershed), and in the stream at the watershed outlet. The autocorrelation among runoff and P concentrations from the watershed landscape units (n = 9) and the covariance between measurements from the landscape units and measurements from the stream were calculated and used to predict the stream response. Models, validated using leave-one-out cross-validation and a forecasting method, were able to correctly capture temporal trends in streamflow and stream P chemistry (Nash-Sutcliffe efficiencies, 0.49-0.88). The analysis suggests that the covariance structure was consistent for all models, indicating that the physical processes governing runoff and P loss from these landscape units were stationary in time and that landscapes located in hydraulically active areas have a direct hydraulic link to the stream. This methodology provides insight into the impact of various urban landscape units on stream water quantity and quality.

  4. Variations in surface water-ground water interactions along a headwater mountain stream: comparisons between transient storage and water balance analyses

    Science.gov (United States)

    Adam S. Ward; Robert A. Payn; Michael N. Gooseff; Brian L. McGlynn; Kenneth E. Bencala; Christa A. Kellecher; Steven M. Wondzell; Thorsten. Wagener

    2013-01-01

    The accumulation of discharge along a stream valley is frequently assumed to be the primary control on solute transport processes. Relationships of both increasing and decreasing transient storage, and decreased gross losses of stream water have been reported with increasing discharge; however, we have yet to validate these relationships with extensive field study. We...

  5. 49 Trace Metals' Contamination of Stream Water and Irrigated Crop ...

    African Journals Online (AJOL)

    ABUBAKAR AHMED

    human consumption as they pose serious health risks due to contamination with the metals. For environmental ... mining activities, industrial and domestic effluents, urban ... drinking and bathing water, irrigation, food, fuel and energy.

  6. GENDER MAIN STREAMING IN WATER SUPPLY AND SANITATION PROJECTS

    Directory of Open Access Journals (Sweden)

    Simona FRONE

    2014-06-01

    Full Text Available As we have stated in the previous year conference paper, the human right to water and sanitation entitles everyoneto water and sanitation services which are available, accessible, affordable, acceptable and safe. Developmentprograms for water and sanitation services, as many other socio-economic development programs have often beenassumed to be neutral in terms of gender. However, sometimes there can be failures in the implementation andharnessing of such projects because of errors arising from lack of adequate integration of gender equality. In thispaper are highlighted some aspects and issues of gender mainstreaming in water supply and sanitation developmentprojects, including conclusions from a case study conducted by an NGO in a commune of Romania and ownrecommendations.

  7. OZONE TREATMENT OF SOLUBLE ORGANICS IN PRODUCED WATER

    Energy Technology Data Exchange (ETDEWEB)

    Klasson, KT

    2002-03-14

    This project was an extension of previous research to improve the applicability of ozonation and will help address the petroleum-industry problem of treating produced water containing soluble organics. The goal of this project was to maximize oxidation of hexane-extractable organics during a single-pass operation. The project investigated: (1) oxidant production by electrochemical and sonochemical methods, (2) increasing the mass transfer rate in the reactor by forming microbubbles during ozone injection into the produced water, and (3) using ultraviolet irradiation to enhance the reaction if needed. Several types of methodologies for treatment of soluble organics in synthetic and actual produced waters have been performed. The technologies tested may be categorized as follows: (1) Destruction via sonochemical oxidation at different pH, salt concentration, ultraviolet irradiation, and ferrous iron concentrations. (2) Destruction via ozonation at different pH, salt concentration, hydrogen peroxide concentrations, ultraviolet irradiation, temperature, and reactor configurations.

  8. Method of producing deuterium-oxide-enriched water

    International Nuclear Information System (INIS)

    Mandel, H.

    1976-01-01

    A method and apparatus for producing deuterium-oxide-enriched water (e.g., as a source of deuterium-rich gas mixtures) are disclosed wherein the multiplicity of individual cooling cycles of a power plant are connected in replenishment cascade so that fresh feed water with a naturally occurring level of deuterium oxide is supplied to replace the vaporization losses, sludge losses and withdrawn portion of water in a first cooling cycle, the withdrawn water being fed as the feed water to the subsequent cooling cycle or stage and serving as the sole feed-water input to the latter. At the end of the replenishment-cascade system, the withdrawn water has a high concentration of deuterium oxide and may serve as a source of water for the production of heavy water or deuterium-enriched gas by conventional methods of removing deuterium oxide or deuterium from the deuterium-oxide-enriched water. Each cooling cycle may form part of a thermal or nuclear power plant in which a turbine is driven by part of the energy and air-cooling of the water takes place in the atmosphere, e.g., in a cooling tower

  9. Indicators of streamflow alteration, habitat fragmentation, impervious cover, and water quality for Massachusetts stream basins

    Science.gov (United States)

    Weiskel, Peter K.; Brandt, Sara L.; DeSimone, Leslie A.; Ostiguy, Lance J.; Archfield, Stacey A.

    2010-01-01

    Massachusetts streams and stream basins have been subjected to a wide variety of human alterations since colonial times. These alterations include water withdrawals, treated wastewater discharges, construction of onsite septic systems and dams, forest clearing, and urbanization—all of which have the potential to affect streamflow regimes, water quality, and habitat integrity for fish and other aquatic biota. Indicators were developed to characterize these types of potential alteration for subbasins and groundwater contributing areas in Massachusetts. The potential alteration of streamflow by the combined effects of withdrawals and discharges was assessed under two water-use scenarios. Water-use scenario 1 incorporated publicly reported groundwater withdrawals and discharges, direct withdrawals from and discharges to streams, and estimated domestic-well withdrawals and septic-system discharges. Surface-water-reservoir withdrawals were excluded from this scenario. Water-use scenario 2 incorporated all the types of withdrawal and discharge included in scenario 1 as well as withdrawals from surface-water reservoirs—all on a long-term, mean annual basis. All withdrawal and discharge data were previously reported to the State for the 2000–2004 period, except domestic-well withdrawals and septic-system discharges, which were estimated for this study. The majority of the state’s subbasins and groundwater contributing areas were estimated to have relatively minor (less than 10 percent) alteration of streamflow under water-use scenario 1 (seasonally varying water use; no surface-water-reservoir withdrawals). However, about 12 percent of subbasins and groundwater contributing areas were estimated to have extensive alteration of streamflows (greater than 40 percent) in August; most of these basins were concentrated in the outer metropolitan Boston region. Potential surcharging of streamflow in August was most commonly indicated for main-stem river subbasins, although

  10. Discrete simulations of spatio-temporal dynamics of small water bodies under varied stream flow discharges

    Science.gov (United States)

    Daya Sagar, B. S.

    2005-01-01

    Spatio-temporal patterns of small water bodies (SWBs) under the influence of temporally varied stream flow discharge are simulated in discrete space by employing geomorphologically realistic expansion and contraction transformations. Cascades of expansion-contraction are systematically performed by synchronizing them with stream flow discharge simulated via the logistic map. Templates with definite characteristic information are defined from stream flow discharge pattern as the basis to model the spatio-temporal organization of randomly situated surface water bodies of various sizes and shapes. These spatio-temporal patterns under varied parameters (λs) controlling stream flow discharge patterns are characterized by estimating their fractal dimensions. At various λs, nonlinear control parameters, we show the union of boundaries of water bodies that traverse the water body and non-water body spaces as geomorphic attractors. The computed fractal dimensions of these attractors are 1.58, 1.53, 1.78, 1.76, 1.84, and 1.90, respectively, at λs of 1, 2, 3, 3.46, 3.57, and 3.99. These values are in line with general visual observations.

  11. Reconnaissance study of uranium and fluorine contents of stream and lake waters, West Greenland

    International Nuclear Information System (INIS)

    Steenfelt, A.; Dam, E.

    1982-01-01

    The present study forms part of a current investigation on the applicability of geochemical methods in mineral exploration in Greenland. The sampling programme of 1981 comprised three parts: (1) A helicopter supported, low density, regional sampling (1 sample/30 km 2 ) of stream water and stream sediment in the area covered by map sheet 66 V.2, south-east of Soendre Stroemfjord. A total of 207 water samples was obtained. (2) Detailed sampling within a 20 km 2 area of lake and stream water (71 samples) from a camp at 66deg49'N, 25deg37'W, 25 km south-west of Soendre Stroemfjord. (3) Reconnaissance sampling, by boat, along the southern part of the west coast of Greenland. The aim of this reconnaissance was to obtain information on the character of the drainage systems and on the availability of sample media (water, stream sediment, aquatic moss) for geochemical exploration. A total of 195 water samples were collected. In addition, rust zones and areas of known mineralisation along the coast were sampled. (author)

  12. Use of neural networks for monitoring surface water quality changes in a neotropical urban stream.

    Science.gov (United States)

    da Costa, Andréa Oliveira Souza; Silva, Priscila Ferreira; Sabará, Millôr Godoy; da Costa, Esly Ferreira

    2009-08-01

    This paper reports the using of neural networks for water quality analysis in a tropical urban stream before (2002) and after sewerage building and the completion of point-source control-based sanitation program (2003). Mathematical modeling divided water quality data in two categories: (a) input of some in situ water quality variables (temperature, pH, O2 concentration, O2 saturation and electrical conductivity) and (b) water chemical composition (N-NO2(-); N-NO3(-); N-NH4(+) Total-N; P-PO4(3-); K+; Ca2+; Mg+2; Cu2+; Zn2+ and Fe+3) as the output from tested models. Stream water data come from fortnightly sampling in five points along the Ipanema stream (Southeast Brazil, Minas Gerais state) plus two points downstream and upstream Ipanema discharge into Doce River. Once the best models are consistent with variables behavior we suggest that neural networking shows potential as a methodology to enhance guidelines for urban streams restoration, conservation and management.

  13. Evaluation of water quality at the source of streams of the Sinos River Basin, southern Brazil

    Directory of Open Access Journals (Sweden)

    T Benvenuti

    Full Text Available The Sinos River Basin (SRB is located in the northeastern region of the state of Rio Grande do Sul (29º20' to 30º10'S and 50º15' to 51º20'W, southern Brazil, and covers two geomorphologic provinces: the southern plateau and the central depression. It is part of the Guaíba basin, has an area of approximately 800 km2 and contains 32 counties. The basin provides drinking water for 1.6 million inhabitants in one of the most important industrial centres in Brazil. This study describes different water quality indices (WQI used for the sub-basins of three important streams in the SRB: Pampa, Estância Velha/Portão and Schmidt streams. Physical, chemical and microbiological parameters assessed bimonthly using samples collected at each stream source were used to calculate the Horton Index (HI, the Dinius Index (DI and the water quality index adopted by the US National Sanitation Foundation (NSF WQI in the additive and multiplicative forms. These indices describe mean water quality levels at the streams sources. The results obtained for these 3 indexes showed a worrying scenario in which water quality has already been negatively affected at the sites where three important sub-basins in the Sinos River Basin begin to form.

  14. Discrete simulations of spatio-temporal dynamics of small water bodies under varied stream flow discharges

    Directory of Open Access Journals (Sweden)

    B. S. Daya Sagar

    2005-01-01

    Full Text Available Spatio-temporal patterns of small water bodies (SWBs under the influence of temporally varied stream flow discharge are simulated in discrete space by employing geomorphologically realistic expansion and contraction transformations. Cascades of expansion-contraction are systematically performed by synchronizing them with stream flow discharge simulated via the logistic map. Templates with definite characteristic information are defined from stream flow discharge pattern as the basis to model the spatio-temporal organization of randomly situated surface water bodies of various sizes and shapes. These spatio-temporal patterns under varied parameters (λs controlling stream flow discharge patterns are characterized by estimating their fractal dimensions. At various λs, nonlinear control parameters, we show the union of boundaries of water bodies that traverse the water body and non-water body spaces as geomorphic attractors. The computed fractal dimensions of these attractors are 1.58, 1.53, 1.78, 1.76, 1.84, and 1.90, respectively, at λs of 1, 2, 3, 3.46, 3.57, and 3.99. These values are in line with general visual observations.

  15. Considerations for producing re-usable and sustainable educational streaming materials

    Directory of Open Access Journals (Sweden)

    Gayle Calverley

    2006-02-01

    Full Text Available Useful lifetime of educational materials should be defined by their continuing ability to help meet defined learning objectives. More often lifetime is compromised by changes in the educational environment that do not specifically relate to the capacity of the material to assist learning. Approaches for integration of materials into the learning environment can be designed to maximise useful lifetime of materials against potential barriers created by, for example, instances of technological change. In this study, the impact of different approaches is demonstrated by examining the development of 163 learning objects, based on several licensed collections of streaming video procured for cross-sector educational use by the UK Lifesign project. Constraints relating to sustainability work within the limitations of a short-term project environment are specifically considered.

  16. Streaming flows produced by oscillating interface of magnetic fluid adsorbed on a permanent magnet in alternating magnetic field

    Science.gov (United States)

    Sudo, S.; Ito, M.; Ishimoto, Y.; Nix, S.

    2017-04-01

    This paper describes microstreaming flows generated by oscillating interface of magnetic fluid adsorbed on a circular cylindrical permanent magnet in alternating magnetic field. The interface of magnetic fluid adsorbed on the NdFeB magnet responds to the external alternating magnetic flied as harmonic oscillation. The directions of alternating magnetic field are parallel and antiparallel to the magnetic field of permanent magnet. The oscillation of magnetic fluid interface generates streaming flow around the magnet-magnetic fluid element in water. Microstreaming flows are observed with a high-speed video camera analysis system. The flow pattern generated by magnetic fluid motion depends on the Keulegan-Carpenter number and the Reynolds number.

  17. Headwater streams in the EU Water Framework Directive: Evidence-based decision support to select streams for river basin management plans

    DEFF Research Database (Denmark)

    Baattrup-Pedersen, Annette; Larsen, Søren Erik; Andersen, Dagmar K.

    2018-01-01

    , however, it is intensely debated whether the small size and low slopes, typical of Danish streams, in combination with degraded habitat conditions obstruct their ability to fulfill the ecological quality objectives required by the EU Water Framework Directive (WFD). The purpose of this studywas to provide...... an analytically based framework for guiding the selection of headwater streams for RBMP. Specifically, the following hypotheses were addressed: i) stream slope, width, planform, and general physical habitat quality can act as criteria for selecting streams for the next generation of RBMPs, and ii) probability......-based thresholds for reaching good ecological status can be established for some or all of these criteria, thus creating a sound, scientifically based, and clear selection process. The hypotheses were tested using monitoring data on Danish streams from the period 2004–2015. Significant linear relationships were...

  18. Inference of Stream Network Fragmentation Patterns from Ground Water - Surface Water Interactions on the High Plains Aquifer

    Science.gov (United States)

    Chandler, D. G.; Yang, X.; Steward, D. R.; Gido, K.

    2007-12-01

    Stream networks in the Great Plains integrate fluxes from precipitation as surface runoff in discrete events and groundwater as base flow. Changes in land cover and agronomic practices and development of ground water resources to support irrigated agriculture have resulted in profound changes in the occurrence and magnitude of stream flows, especially near the Ogallala aquifer, where precipitation is low. These changes have demonstrably altered the aquatic habitat of western Kansas, with documented changes in fish populations, riparian communities and groundwater quality due to stream transmission losses. Forecasting future changes in aquatic and riparian ecology and groundwater quality requires a large scale spatially explicit model of groundwater- surface water interaction. In this study, we combine historical data on land use, stream flow, production well development and groundwater level observations with groundwater elevation modeling to support a geospatial framework for assessing changes in refugia for aquatic species in four rivers in western Kansas between 1965 and 2005. Decreased frequency and duration of streamflow occurred in all rivers, but the extent of change depended on the geomorphology of the river basin and the extent of groundwater development. In the absence of streamflow, refugia for aquatic species were defined as the stream reaches below the phreatic surface of the regional aquifer. Changes in extent, location and degree of fragmentation of gaining reaches was found to be a strong predictor of surface water occurrence during drought and a robust hydrological template for the analysis of changes in recharge to alluvial and regional aquifers and riparian and aquatic habitat.

  19. Impact of Unconventional Shale Gas Waste Water Disposal on Surficial Streams

    Science.gov (United States)

    Cozzarelli, I.; Akob, D.; Mumford, A. C.

    2014-12-01

    The development of unconventional natural gas resources has been rapidly increasing in recent years, however, the environmental impacts and risks are not yet well understood. A single well can generate up to 5 million L of produced water (PW) consisting of a blend of the injected fluid and brine from a shale formation. With thousands of wells completed in the past decade, the scope of the challenge posed in the management of this wastewater becomes apparent. The USGS Toxic Substances Hydrology Program is studying both intentional and unintentional releases of PW and waste solids. One method for the disposal of PW is underground injection; we are assessing the potential risks of this method through an intensive, interdisciplinary study at an injection disposal facility in the Wolf Creek watershed in WV. Disposal of PW via injection begun in 2002, with over 5.5 mil. L of PW injected to date. The facility consists of the injection well, a tank farm, and two former holding ponds (remediated in early 2014) and is bordered by two small tributaries of Wolf Creek. Water and sediments were acquired from these streams in June 2014, including sites upstream, within, and downstream from the facility. We are analyzing aqueous and solid phase geochemistry, mineralogy, hydrocarbon content, microbial community composition, and potential toxicity. Field measurements indicated that conductivity downstream (416 μS/cm) was elevated in comparison to upstream (74 μS/cm) waters. Preliminary data indicated elevated Cl- (115 mg/L) and Br- (0.88 mg/L) concentrations downstream, compared to 0.88 mg/L Cl- and impacting nearby streams. In addition, total Fe concentrations downstream were 8.1 mg/L, far in excess of the 0.13 mg/L found upstream from the facility, suggesting the potential for microbial Fe cycling. We are conducting a broad suite of experiments to assess the potential for microbial metabolism of the organic components of PW, and to determine the effects of this metabolism on the

  20. Factors affecting reservoir and stream-water quality in the Cambridge, Massachusetts, drinking-water source area and implications for source-water protection

    Science.gov (United States)

    Waldron, Marcus C.; Bent, Gardner C.

    2001-01-01

    This report presents the results of a study conducted by the U.S. Geological Survey, in cooperation with the city of Cambridge, Massachusetts, Water Department, to assess reservoir and tributary-stream quality in the Cambridge drinking-water source area, and to use the information gained to help guide the design of a comprehensive water-quality monitoring program for the source area. Assessments of the quality and trophic state of the three primary storage reservoirs, Hobbs Brook Reservoir, Stony Brook Reservoir, and Fresh Pond, were conducted (September 1997-November 1998) to provide baseline information on the state of these resources and to determine the vulnerability of the reservoirs to increased loads of nutrients and other contaminants. The effects of land use, land cover, and other drainage-basin characteristics on sources, transport, and fate of fecal-indicator bacteria, highway deicing chemicals, nutrients, selected metals, and naturally occurring organic compounds in 11 subbasins that contribute water to the reservoirs also was investigated, and the data used to select sampling stations for incorporation into a water-quality monitoring network for the source area. All three reservoirs exhibited thermal and chemical stratification, despite artificial mixing by air hoses in Stony Brook Reservoir and Fresh Pond. The stratification produced anoxic or hypoxic conditions in the deepest parts of the reservoirs and these conditions resulted in the release of ammonia nitrogen orthophosphate phosphorus, and dissolved iron and manganese from the reservoir bed sediments. Concentrations of sodium and chloride in the reservoirs usually were higher than the amounts recommended by the U.S. Environmental Protection agency for drinking-water sources (20 milligrams per liter for sodium and 250 milligrams per liter for chloride). Maximum measured sodium concentrations were highest in Hobbs Brook Reservoir (113 milligrams per liter), intermediate in Stony Brook Reservoir (62

  1. Dynamics of physicochemical parameter concentrations in the Graniczna Woda stream water

    Directory of Open Access Journals (Sweden)

    Żarnowiec Wioletta

    2017-12-01

    Full Text Available The paper presents variability of physicochemical parameter concentrations and determined the potential and chemical status of water in the Graniczna Woda stream, the right bank tributary to the Stoła River. The stream catchment area of 41.5 km2 is covered mainly by forests. A lowland stream flows through part of the Upper Silesia Industrial Region through three districts. A biological-mechanical municipal sewage treatment plant operates in the area of Miasteczko Śląskie, as well as a factory sewage treatment plant of Zinc Plant. The data base used in the papers consisted of the results obtained from the Provincial Inspectorate of the Environmental Protection in Katowice, monthly analyses of water samples collected in the years 2009–2013 in the control-measurement points located by the mouth of the Stoła River. 34 physicochemical indices were analyzed in the paper. Statistically significant upward trends were determined over the period of investigations for values of electrical conductivity (EC, total suspended solids, Cl, SO4, NO2-N and Zn in the stream water. Statistically significant downward trend was noted for total hardness. It was stated that both the potential and chemical status o the stream water were below good. Exceeded limit values for quality class II determined for oxygen and organic indices (chemical oxygen demand COD-Mn, total organic carbon TOC, salinity (EC, SO4, Cl, Ca, hardness and biogenic indices and substances particularly harmful for aquatic environment (Zn, Tl as well as exceeded allowable heavy metal concentrations may evidence a constant inflow of heavy metals to the aquatic environment of the Graniczna Woda stream from municipal and industrial sewage.

  2. Treatment of Produced Water Using a Surfactant Modified Zeolite/Vapor Phase Bioreactor System

    Energy Technology Data Exchange (ETDEWEB)

    Lynn E. Katz; Kerry A. Kinney; Robert S. Bowman; Enid J. Sullivan; Soondong Kwon; Elaine B. Darby; Li-Jung Chen; Craig R. Altare

    2006-01-31

    Co-produced water from the oil and gas industry accounts for a significant waste stream in the United States. Produced waters typically contain a high total dissolved solids content, dissolved organic constituents such as benzene and toluene, an oil and grease component as well as chemicals added during the oil-production process. It has been estimated that a total of 14 billion barrels of produced water were generated in 2002 from onshore operations (Veil, 2004). Although much of this produced water is disposed via reinjection, environmental and cost considerations can make surface discharge of this water a more practical means of disposal. In addition, reinjection is not always a feasible option because of geographic, economic, or regulatory considerations. In these situations, it may be desirable, and often necessary from a regulatory viewpoint, to treat produced water before discharge. It may also be feasible to treat waters that slightly exceed regulatory limits for re-use in arid or drought-prone areas, rather than losing them to reinjection. A previous project conducted under DOE Contract DE-AC26-99BC15221 demonstrated that surfactant modified zeolite (SMZ) represents a potential treatment technology for produced water containing BTEX. Laboratory and field experiments suggest that: (1) sorption of benzene, toluene, ethylbenzene and xylenes (BTEX) to SMZ follows linear isotherms in which sorption increases with increasing solute hydrophobicity; (2) the presence of high salt concentrations substantially increases the capacity of the SMZ for BTEX; (3) competitive sorption among the BTEX compounds is negligible; and, (4) complete recovery of the SMZ sorption capacity for BTEX can be achieved by air sparging the SMZ. This report summarizes research for a follow on project to optimize the regeneration process for multiple sorption/regeneration cycles, and to develop and incorporate a vapor phase bioreactor (VPB) system for treatment of the off-gas generated during

  3. Multivariate statistical techniques for the evaluation of surface water quality of the Himalayan foothills streams, Pakistan

    Science.gov (United States)

    Malik, Riffat Naseem; Hashmi, Muhammad Zaffar

    2017-10-01

    Himalayan foothills streams, Pakistan play an important role in living water supply and irrigation of farmlands; thus, the water quality is closely related to public health. Multivariate techniques were applied to check spatial and seasonal trends, and metals contamination sources of the Himalayan foothills streams, Pakistan. Grab surface water samples were collected from different sites (5-15 cm water depth) in pre-washed polyethylene containers. Fast Sequential Atomic Absorption Spectrophotometer (Varian FSAA-240) was used to measure the metals concentration. Concentrations of Ni, Cu, and Mn were high in pre-monsoon season than the post-monsoon season. Cluster analysis identified impaired, moderately impaired and least impaired clusters based on water parameters. Discriminant function analysis indicated spatial variability in water was due to temperature, electrical conductivity, nitrates, iron and lead whereas seasonal variations were correlated with 16 physicochemical parameters. Factor analysis identified municipal and poultry waste, automobile activities, surface runoff, and soil weathering as major sources of contamination. Levels of Mn, Cr, Fe, Pb, Cd, Zn and alkalinity were above the WHO and USEPA standards for surface water. The results of present study will help to higher authorities for the management of the Himalayan foothills streams.

  4. Chloride dynamics in a restored urban stream and the influence of road salts on water quality

    Science.gov (United States)

    Understanding the connection between road salts and water quality is essential to assess the implications for human health and ecosystem services from these widely used de-icers. Preliminary analysis identified a probable connection between road salt application and a stream wat...

  5. Relating road salt to exceedances of the water quality standard for chloride in New Hampshire streams.

    Science.gov (United States)

    Trowbridge, Philip R; Kahl, J Steve; Sassan, Dari A; Heath, Douglas L; Walsh, Edward M

    2010-07-01

    Six watersheds in New Hampshire were studied to determine the effects of road salt on stream water quality. Specific conductance in streams was monitored every 15 min for one year using dataloggers. Chloride concentrations were calculated from specific conductance using empirical relationships. Stream chloride concentrations were directly correlated with development in the watersheds and were inversely related to streamflow. Exceedances of the EPA water quality standard for chloride were detected in the four watersheds with the most development. The number of exceedances during a year was linearly related to the annual average concentration of chloride. Exceedances of the water quality standard were not predicted for streams with annual average concentrations less than 102 mg L(-1). Chloride was imported into three of the watersheds at rates ranging from 45 to 98 Mg Cl km(-2) yr(-1). Ninety-one percent of the chloride imported was road salt for deicing roadways and parking lots. A simple, mass balance equation was shown to predict annual average chloride concentrations from streamflow and chloride import rates to the watershed. This equation, combined with the apparent threshold for exceedances of the water quality standard, can be used for screening-level TMDLs for road salt in impaired watersheds.

  6. Stream habitat or water quality - what influences stronger fish and macrozoobenthos biodiversity?

    Czech Academy of Sciences Publication Activity Database

    Adámek, Z.; Jurajda, Pavel

    2001-01-01

    Roč. 1, č. 3 (2001), s. 305-311 ISSN 1642-3593. [Ecohydrology as a tool for restoration of physically degraded fish habitats. Warsaw, 11.06.2001-13.06.2001] Institutional research plan: CEZ:AV0Z6093917 Keywords : stream ecology * water quality * fish communities Subject RIV: EH - Ecology, Behaviour

  7. Tritium removal from air streams by catalytic oxidation and water adsorption

    International Nuclear Information System (INIS)

    Sherwood, A.E.

    1976-06-01

    An effective method of capturing tritium from air streams is by catalytic oxidation followed by water adsorption on a microporous solid adsorbent. Performance of a burner/dryer combination is illustrated by overall mass balance equations. Engineering design methods for packed bed reactors and adsorbers are reviewed, emphasizing the experimental data needed for design and the effect of operating conditions on system performance

  8. Influence of maximum water temperature on occurrence of Lahontan cutthroat trout within streams

    Science.gov (United States)

    J. Dunham; R. Schroeter; B. Rieman

    2003-01-01

    We measured water temperature at 87 sites in six streams in two different years (1998 and 1999) to test for association with the occurrence of Lahontan cutthroat trout Oncorhynchus clarki henshawi. Because laboratory studies suggest that Lahontan cutthroat trout begin to show signs of acute stress at warm (>22°C) temperatures, we focused on the...

  9. Effect of Strip Mining on Water Quality in Small Streams in Eastern Kentucky, 1967-1975

    Science.gov (United States)

    Kenneth L. Dyer; Willie R. Curtis

    1977-01-01

    Eight years of streamflow data are analyzed to show the effects of strip mining on chemical quality of water in six first-order streams in Breathitt County, Kentucky. All these watersheds were unmined in August, 1967, but five have since been strip mined. The accumulated data from this case history study indicate that strip mining causes large increases in the...

  10. Watershed scale assessment of the impact of forested riparian zones on stream water quality

    Science.gov (United States)

    J. A. Webber; K. W. J. Williard; M. R. Whiles; M. L. Stone; J. J. Zaczek; D. K. Davie

    2003-01-01

    Federal and state land management agencies have been promoting forest and grass riparian zones to combat non-point source nutrient and sediment pollution of our nations' waters. The majority of research examining the effectiveness of riparian buffers at reducing nutrient and sediment inputs to streams has been conducted at the field scale. This study took a...

  11. Land-based sources of marine pollution: Pesticides, PAHs and phthalates in coastal stream water, and heavy metals in coastal stream sediments in American Samoa.

    Science.gov (United States)

    Polidoro, Beth A; Comeros-Raynal, Mia T; Cahill, Thomas; Clement, Cassandra

    2017-03-15

    The island nations and territories of the South Pacific are facing a number of pressing environmental concerns, including solid waste management and coastal pollution. Here we provide baseline information on the presence and concentration of heavy metals and selected organic contaminants (pesticides, PAHs, phthalates) in 7 coastal streams and in surface waters adjacent to the Futiga landfill in American Samoa. All sampled stream sediments contained high concentrations of lead, and some of mercury. Several coastal stream waters showed relatively high concentrations of diethyl phthalate and of organophosphate pesticides, above chronic toxicity values for fish and other aquatic organisms. Parathion, which has been banned by the US Environmental Protection Agency since 2006, was detected in several stream sites. Increased monitoring and initiatives to limit non-point source land-based pollution will greatly improve the state of freshwater and coastal resources, as well as reduce risks to human health in American Samoa. Copyright © 2016 Elsevier Ltd. All rights reserved.

  12. Spatio-temporal variation in stream water chemistry in a tropical urban watershed

    Directory of Open Access Journals (Sweden)

    Alonso Ramírez

    2014-06-01

    Full Text Available Urban activities and related infrastructure alter the natural patterns of stream physical and chemical conditions. According to the Urban Stream Syndrome, streams draining urban landscapes are characterized by high concentrations of nutrients and ions, and might have elevated water temperatures and variable oxygen concentrations. Here, we report temporal and spatial variability in stream physicochemistry in a highly urbanized watershed in Puerto Rico. The main objective of the study was to describe stream physicochemical characteristics and relate them to urban intensity, e.g., percent impervious surface cover, and watershed infrastructure, e.g., road and pipe densities. The Río Piedras Watershed in the San Juan Metropolitan Area, Puerto Rico, is one of the most urbanized regions on the island. The Río Piedras presented high solute concentrations that were related to watershed factors, such as percent impervious cover. Temporal variability in ion concentrations lacked seasonality, as did all other parameters measured except water temperature, which was lower during winter and highest during summer, as expected based on latitude. Spatially, stream physicochemistry was strongly related to watershed percent impervious cover and also to the density of urban infrastructure, e.g., roads, pipe, and building densities. Although the watershed is serviced by a sewage collection system, illegal discharges and leaky infrastructure are probably responsible for the elevated ion concentration found. Overall, the Río Piedras is an example of the response of a tropical urban watershed after major sewage inputs are removed, thus highlighting the importance of proper infrastructure maintenance and management of runoff to control ion concentrations in tropical streams.

  13. Understanding and quantifying focused, indirect groundwater recharge from ephemeral streams using water table fluctuations

    Science.gov (United States)

    Cuthbert, M. O.; Acworth, R. I.; Andersen, M. S.; Larsen, J. R.; McCallum, A. M.; Rau, G. C.; Tellam, J. H.

    2016-02-01

    Understanding and managing groundwater resources in drylands is a challenging task, but one that is globally important. The dominant process for dryland groundwater recharge is thought to be as focused, indirect recharge from ephemeral stream losses. However, there is a global paucity of data for understanding and quantifying this process and transferable techniques for quantifying groundwater recharge in such contexts are lacking. Here we develop a generalized conceptual model for understanding water table and groundwater head fluctuations due to recharge from episodic events within ephemeral streams. By accounting for the recession characteristics of a groundwater hydrograph, we present a simple but powerful new water table fluctuation approach to quantify focused, indirect recharge over both long term and event time scales. The technique is demonstrated using a new, and globally unparalleled, set of groundwater observations from an ephemeral stream catchment located in NSW, Australia. We find that, following episodic streamflow events down a predominantly dry channel system, groundwater head fluctuations are controlled by pressure redistribution operating at three time scales from vertical flow (days to weeks), transverse flow perpendicular to the stream (weeks to months), and longitudinal flow parallel to the stream (years to decades). In relative terms, indirect recharge decreases almost linearly away from the mountain front, both in discrete monitored events as well as in the long-term average. In absolute terms, the estimated indirect recharge varies from 80 to 30 mm/a with the main uncertainty in these values stemming from uncertainty in the catchment-scale hydraulic properties.

  14. Organic Pollutants in Shale Gas Flowback and Produced Waters

    NARCIS (Netherlands)

    Butkovskyi, Andrii; Bruning, Harry; Kools, Stefan A.E.; Rijnaarts, Huub H.M.; Wezel, van Annemarie P.

    2017-01-01

    Organic contaminants in shale gas flowback and produced water (FPW) are traditionally expressed as total organic carbon (TOC) or chemical oxygen demand (COD), though these parameters do not provide information on the toxicity and environmental fate of individual components. This review addresses

  15. Dispersed droplet dynamics during produced water treatment in oil industry

    NARCIS (Netherlands)

    van Eijkeren, D.F.

    2016-01-01

    For Lagrangian particle tracking applied to swirling flow produced water treatment the influence of the history force is investigated. In the expression for the history force an existing Reynolds number dependent kernel is adapted and validated for a range of experimental data for settling spheres.

  16. Plant-wide Control Strategy for Improving Produced Water Treatment

    DEFF Research Database (Denmark)

    Yang, Zhenyu; Pedersen, Simon; Løhndorf, Petar Durdevic

    2016-01-01

    This work focuses on investigation and development of an innovative Produced Water Treatment (PWT) technology for offshore oil & gas production by employing the model-based plant-wide control strategy. The key contributions lie in two folds: (i) the advanced anti-slug analysis and control...

  17. Re-injection of produced water: ''Environmental friendliness pays off''

    International Nuclear Information System (INIS)

    Bjerke, E.

    1995-01-01

    The article deals with the re-injection of produced water for minimizing the emission of polluting components and for enhancing the oil recovery on the Norwegian oil field Ula. A closed cycle system is installed increasing the oil production by 4-5.000 bbl per day

  18. Performance Evaluation of Produced Water Quality from a ...

    African Journals Online (AJOL)

    Michael Horsfall

    1Department of Chemical Engineering, Federal University of Technology, Owerri, Nigeria, ... ABSTRACT: Produced water, which is a mixture of organic and inorganic compounds, is a major waste ... from one viewpoint, an approach to reducing adverse environmental ... pipette onto a glass-fiber filter with applied vacuum.

  19. Mercury removal from water streams through the ion exchange membrane bioreactor concept.

    Science.gov (United States)

    Oehmen, Adrian; Vergel, Dario; Fradinho, Joana; Reis, Maria A M; Crespo, João G; Velizarov, Svetlozar

    2014-01-15

    Mercury is a highly toxic heavy metal that causes human health problems and environmental contamination. In this study, an ion exchange membrane bioreactor (IEMB) process was developed to achieve Hg(II) removal from drinking water and industrial effluents. Hg(II) transport through a cation exchange membrane was coupled with its bioreduction to Hg(0) in order to achieve Hg removal from concentrated streams, with minimal production of contaminated by-products observed. This study involves (1) membrane selection, (2) demonstration of process effectiveness for removing Hg from drinking water to below the 1ppb recommended limit, and (3) process application for treatment of concentrated water streams, where >98% of the Hg was removed, and the throughput of contaminated water was optimised through membrane pre-treatment. The IEMB process represents a novel mercury treatment technology with minimal generation of contaminated waste, thereby reducing the overall environmental impact of the process. Copyright © 2013 Elsevier B.V. All rights reserved.

  20. Cross-regional prediction of long-term trajectory of stream water DOC response to climate change

    Science.gov (United States)

    H. Laudon; J.M. Buttle; S.K. Carey; J.J. McDonnell; K.J. McGuire; J. Seibert; J. Shanley; C. Soulsby; D. Tetzlaff

    2012-01-01

    There is no scientific consensus about how dissolved organic carbon (DOC) in surface waters is regulated. Here we combine recent literature data from 49 catchments with detailed stream and catchment process information from nine well established research catchments at mid- to high latitudes to examine the question of how climate controls stream water DOC. We show for...

  1. Effects of forest harvest on stream-water quality and nitrogen cycling in the Caspar Creek watershed

    Science.gov (United States)

    Randy A. Dahlgren

    1998-01-01

    The effects of forest harvest on stream-water quality and nitrogen cycling were examined for a redwood/Douglas-fir ecosystem in the North Fork, Caspar Creek experimental watershed in northern California. Stream-water samples were collected from treated (e.g., clearcut) and reference (e.g., noncut) watersheds, and from various locations downstream from the treated...

  2. Impacts of Catfish Effluents on Water Quality Parameters of Majidun Stream, South-West, Nigeria

    Directory of Open Access Journals (Sweden)

    O. E. Omofunmi

    2017-06-01

    Full Text Available There has been a great concern about the level of safety of surface waters, especially in developing countries where there is an exponential increase in water pollution and water-borne diseases. The aim of this study was to assess the effect of catfish pond effluents on water quality of stream water where five catfish farms were located. Water samples were taken on monthly basis, 20 cm of below water surface from the streams that receive effluents from neighboring fishponds. Water quality indicators like dissolved oxygen, biochemical oxygen demand (BOD5, nitrate, nitrite, water temperature, ammonia and Hydrogen ion Concentration (pH were examined in the sampled waters in accordance with the American Public Health Association standards. The average values of water quality indicators examined at effluents and non-effluents discharged sites of the stream indicated that water (24.6 ± 0.2, 24.2 ±0.1, (7.29±0.30, 7.30±0.10, (6.90±0.4, 7.07±0.1 mg/l, (0.40±0.04, 0.27±0.01, (3.77±0.26, 2.34±0.16 mg/l, (3.59±0.11, 2.80±0.02 mg/l and (3.51±0.24, 2.46±0.21 mg/l at (p≥0.05 respectively for temperature, pH, dissolved oxygen, total ammonia, total nitrogen, total phosphorus, and BODs. They were significant differences (P 0.05 excepts temperature and pH, between values obtained at effluents discharged and non-effluents discharged sites, indicating that improper discharges of catfish pond effluents could resulted into environmental contamination

  3. Guidelines for the collection of continuous stream water-temperature data in Alaska

    Science.gov (United States)

    Toohey, Ryan C.; Neal, Edward G.; Solin, Gary L.

    2014-01-01

    Objectives of stream monitoring programs differ considerably among many of the academic, Federal, state, tribal, and non-profit organizations in the state of Alaska. Broad inclusion of stream-temperature monitoring can provide an opportunity for collaboration in the development of a statewide stream-temperature database. Statewide and regional coordination could reduce overall monitoring cost, while providing better analyses at multiple spatial and temporal scales to improve resource decision-making. Increased adoption of standardized protocols and data-quality standards may allow for validation of historical modeling efforts with better projection calibration. For records of stream water temperature to be generally consistent, unbiased, and reproducible, data must be collected and analyzed according to documented protocols. Collection of water-temperature data requires definition of data-quality objectives, good site selection, proper selection of instrumentation, proper installation of sensors, periodic site visits to maintain sensors and download data, pre- and post-deployment verification against an NIST-certified thermometer, potential data corrections, and proper documentation, review, and approval. A study created to develop a quality-assurance project plan, data-quality objectives, and a database management plan that includes procedures for data archiving and dissemination could provide a means to standardize a statewide stream-temperature database in Alaska. Protocols can be modified depending on desired accuracy or specific needs of data collected. This document is intended to guide users in collecting time series water-temperature data in Alaskan streams and draws extensively on the broader protocols already published by the U.S. Geological Survey.

  4. Influence of softening sequencing on electrocoagulation treatment of produced water.

    Science.gov (United States)

    Esmaeilirad, Nasim; Carlson, Ken; Omur Ozbek, Pinar

    2015-01-01

    Electrocoagulation has been used to remove solids and some metals from both water and wastewater sources for decades. Additionally, chemical softening is commonly employed in water treatment systems to remove hardness. This paper assesses the combination and sequence of softening and EC methods to treat hydraulic fracturing flowback and produced water from shale oil and gas operations. EC is one of the available technologies to treat produced water for reuse in frac fluids, eliminating not only the need to transport more water but also the costs of providing fresh water. In this paper, the influence of chemical softening on EC was studied. In the softening process, pH was raised to 9.5 and 10.2 before and after EC, respectively. Softening, when practiced before EC was more effective for removing turbidity with samples from wells older than one month (99% versus 88%). However, neither method was successful in treating samples collected from early flowback (1-day and 2-day samples), likely due to the high concentration of organic matter. For total organic carbon, hardness, Ba, Sr, and B removal, application of softening before EC appeared to be the most efficient approach, likely due to the formation of solids before the coagulation process. Copyright © 2014 Elsevier B.V. All rights reserved.

  5. Effects of pasture management and off-stream water on temporal/spatial distribution of cattle and stream bank characteristics in cool-season grass pastures.

    Science.gov (United States)

    Schwarte, K A; Russell, J R; Morrical, D G

    2011-10-01

    A 2-yr grazing experiment was conducted to assess the effects of grazing management on cattle distribution and pasture and stream bank characteristics. Six 12.1-ha cool-season grass pastures in central Iowa were allotted to 1 of 3 treatments: continuous stocking with unrestricted stream access (CSU), continuous stocking with stream access restricted to 4.9-m-wide stabilized crossings (CSR), or rotational stocking with stream access restricted to a riparian paddock (RP). Pastures were stocked with 15 fall-calving Angus cows (Bos taurus L.) from mid-May to mid-October for 153 d in 2008 and 2009. A global positioning system (GPS) collar recording cow position every 10 min was placed on at least 1 cow per pasture for 2 wk of each month from May through September. Off-stream water was provided to cattle in CSU and CSR treatments during the second of the 2 wk when GPS collars were on the cattle. A black globe temperature relative humidity index (BGTHI) was measured at 10-min intervals to match the time of the GPS measurements. Each month of the grazing season, forage characteristics (sward height, forage mass, and CP, IVDMD, and P concentrations) and bare and fecal-covered ground were measured. Stream bank erosion susceptibility was visually scored in May, August, and October (pre-, mid-, and post-stocking). Cattle in RP and CSR treatments spent less time (P CSR treatment reduced the probability (P CSR and RP treatments in the stream and streamside zones in September and October and in July and September. Streams in pastures with the CSU treatment had less stable banks (P CSR treatments. Results show that time spent by cattle near pasture streams can be reduced by RP or CSR treatments, thereby decreasing risks of sediment and nutrient loading of pasture streams even during periods of increased BGTHI.

  6. Natural and anthropogenic sources and processes affecting water chemistry in two South Korean streams

    Energy Technology Data Exchange (ETDEWEB)

    Shin, Woo-Jin [Division of Earth and Environmental Sciences, Korea Basic Science Institute, Cheongwon-gun, Chungbuk 363-883 (Korea, Republic of); Department of Geoscience, University of Calgary, Calgary, Alberta T2N 1N4 (Canada); Ryu, Jong-Sik [Division of Earth and Environmental Sciences, Korea Basic Science Institute, Cheongwon-gun, Chungbuk 363-883 (Korea, Republic of); Mayer, Bernhard [Department of Geoscience, University of Calgary, Calgary, Alberta T2N 1N4 (Canada); Lee, Kwang-Sik, E-mail: kslee@kbsi.re.kr [Division of Earth and Environmental Sciences, Korea Basic Science Institute, Cheongwon-gun, Chungbuk 363-883 (Korea, Republic of); Lee, Sin-Woo [Division of Earth and Environmental Sciences, Korea Basic Science Institute, Cheongwon-gun, Chungbuk 363-883 (Korea, Republic of); Department of Geology, Chungnam National University, Yuseong-gu, Daejeon 305-764 (Korea, Republic of)

    2014-07-01

    Acid mine drainage (AMD) in a watershed provides potential sources of pollutants for surface and subsurface waters that can deteriorate water quality. Between March and early August 2011, water samples were collected from two streams in South Korea, one dominantly draining a watershed with carbonate bedrock affected by coal mines and another draining a watershed with silicate bedrock and a relatively undisturbed catchment area. The objective of the study was to identify the sources and processes controlling water chemistry, which was dependent on bedrock and land use. In the Odae stream (OS), the stream in the silicate-dominated catchment, Ca, Na, and HCO{sub 3} were the dominant ions and total dissolved solids (TDS) was low (26.1–165 mg/L). In the Jijang stream (JS), in the carbonate-dominated watershed, TDS (224–434 mg/L) and ion concentrations were typically higher, and Ca and SO{sub 4} were the dominant ions due to carbonate weathering and oxidation of pyrite exposed at coal mines. Dual isotopic compositions of sulfate (δ{sup 34}S{sub SO4} and δ{sup 18}O{sub SO4}) verified that the SO{sub 4} in JS is derived mainly from sulfide mineral oxidation in coal mines. Cl in JS was highest upstream and decreased progressively downstream, which implies that pollutants from recreational facilities in the uppermost part of the catchment are the major source governing Cl concentrations within the discharge basin. Dual isotopic compositions of nitrate (δ{sup 15}N{sub NO3} and δ{sup 18}O{sub NO3}) indicated that NO{sub 3} in JS is attributable to nitrification of soil organic matter but that NO{sub 3} in OS is derived mostly from manure. Additionally, the contributions of potential anthropogenic sources to the two streams were estimated in more detail by using a plot of δ{sup 34}S{sub SO4} and δ{sup 15}N{sub NO3}. This study suggests that the dual isotope approach for sulfate and nitrate is an excellent additional tool for elucidating the sources and processes

  7. Radiological quality of packaged waters produced in France

    International Nuclear Information System (INIS)

    Franques, Nathalie; Perrin, Marie-Line; Godet, Jean-Luc; Pineau, Cyril; Loyen, Jeanne; Brassac, Annette; Gleizes, Marc; Baudry, Michel

    2013-09-01

    Based on radionuclide and uranium analyses performed in 2012 by the IRSN on packaged waters produced in France, this report presents the main results on this national survey. The objectives were a systematic measurement of radioactivity indicators, a systematic measurement of uranium content, and a limited measurement of radon-222 content in some samples. After some recalls on the notions of radioactivity and exposure, on uranium and radon properties, and of the present regulation, this report presents the adopted methodology, and discusses the range and limitation of this study. It presents and comments the results of systematic analyses of spring and natural mineral waters (presence of tritium, global beta and alpha activity, uranium concentration), the results of measurements of radon-222, and the results of additional analyses of spring and natural mineral waters (main radionuclides, radium-226, uranium isotopes, other radionuclides). It reports the calculation of doses and the interpretation of results for waters which have been submitted to additional analyses

  8. Seasonality, water quality trends and biological responses in four streams in the Cairngorm Mountains, Scotland

    Directory of Open Access Journals (Sweden)

    C. Soulsby

    2001-01-01

    Full Text Available The chemical composition and invertebrate communities found in four streams in the Cairngorms, Scotland, were monitored between 1985-1997. Stream waters were mildly acidic (mean pH ca. 6.5, with low alkalinity (mean acid neutralising capacity varying from 35-117 meq l-1 and low ionic strength. Subtle differences in the chemistry of each stream were reflected in their invertebrate faunas. Strong seasonality in water chemistry occurred, with the most acid, low alkalinity waters observed during the winter and early spring. This was particularly marked during snowmelt between January and April. In contrast, summer flows were usually groundwater dominated and characterised by higher alkalinity and higher concentrations of most other weathering-derived solutes. Seasonality was also clear in the invertebrate data, with Canonical Correspondence Analysis (CCA separating seasonal samples along axes related to water temperature and discharge characteristics. Inter-annual hydrological and chemical differences were marked, particularly with respect to the winter period. Invertebrate communities found in each of the streams also varied from year to year, with spring communities significantly more variable (PHydrochemical trends over the study period were analysed using a seasonal Kendall test, LOcally WEighted Scatterplot Smoothing (LOWESS and graphical techniques. These indicated that a reduction in sulphate concentrations in stream water is occurring, consistent with declining levels of atmospheric deposition. This may be matched by increases in pH and declining calcium concentrations, though available evidence is inconclusive. Other parameters, such as chloride, total organic carbon and zinc, reveal somewhat random patterns, probably reflecting irregular variations in climatic factors and/or atmospheric deposition. Previous studies have shown that the stream invertebrate communities have remained stable over this period (i.e. no significant linear trends

  9. Modeling Air Temperature/Water Temperature Relations Along a Small Mountain Stream Under Increasing Urban Influence

    Science.gov (United States)

    Fedders, E. R.; Anderson, W. P., Jr.; Hengst, A. M.; Gu, C.

    2017-12-01

    greater. This indicates a possible tipping point in the stream temperature-water temperature relationship at which increased urbanization overpowers increasing stream thermal inertia.

  10. Occurrence of carbapenemase-producing bacteria in coastal recreational waters.

    Science.gov (United States)

    Montezzi, Lara Feital; Campana, Eloiza Helena; Corrêa, Laís Lisboa; Justo, Livia Helena; Paschoal, Raphael Paiva; da Silva, Isabel Lemos Vieira Dias; Souza, Maria do Carmo Maciel; Drolshagen, Marcia; Picão, Renata Cristina

    2015-02-01

    The spread of carbapenemase-producing Gram-negative rods is an emerging global problem. Although most infections due to carbapenemase producers are limited to healthcare institutions, reports of the occurrence of clinically relevant carbapenemase producers in sewage and polluted rivers are increasingly frequent. Polluted rivers flowing to oceans may contaminate coastal waters with multidrug-resistant bacteria, potentially threatening the safety of recreational activities in these locations. Here we assessed the occurrence of carbapenemase producers in water from touristic beaches located in Rio de Janeiro, Brazil, showing distinct pollution patterns. The presence of enterobacteria was noted, including the predominantly environmental genus Kluyvera spp., producing either Klebsiella pneumoniae carbapenemase (KPC) or Guyana extended-spectrum (GES)-type carbapenemases and often associated with quinolone resistance determinants. An Aeromonas sp. harbouring blaKPC and qnrS was also observed. These findings strengthen the role of aquatic matrices as reservoirs and vectors of clinically relevant antimicrobial-resistant bacteria, with potential to favour the spread of these resistance threats throughout the community. Copyright © 2014 Elsevier B.V. and the International Society of Chemotherapy. All rights reserved.

  11. Produced water: Market and global trends - oil production - water production - choice of technology

    International Nuclear Information System (INIS)

    Robertson, Steve

    2006-01-01

    The presentation discusses various aspects of the world oil production, the energy demand, the future oil supply, the oil prices and the production growth. Some problems with produced water are also discussed as well as aspects of the market for produced water technology (tk)

  12. Storm water runoff-a source of emerging contaminants in urban streams

    Science.gov (United States)

    Xia, K.; Chen, C.; FitzGerald, K.; Badgley, B.

    2016-12-01

    Emerging contaminants (ECs) that refers to prescription, over-the-counter, veterinary, and illicit drugs in addition to products intended to have primary effects on the human body, such as sunscreens and insect repellants. Historically municipal wastewater treatment effluent has been considered to be the main source of ECs in aquatic environment. However, recent investigations have suggested urban storm water runoff as an important source of ECs in the environment. The objective of this multi-year study was to investigate the occurrence of a wide range of ECs and the special and temporal change of 4-Nonlyphenol (4-NP), an endocrine disruptor, in a stream solely impacted by the storm water runoff from Blacksburg, VA. Urban land cover has doubled during the past 15 years surrounding this. Water and sediment samples were collected periodically along the stream during a 3-year period and analyzed for 4-NP using a gas chromatography/tandem mass spectrometry and for EC screening using an ultra- performance liquid chromatography/tandem mass spectrometry. In addition, human-associated Bacteroides sp. (HF183) was analyzed to explore possible cross contamination between the sewer system and storm water collection system of the city. Fifteen ECs were detected in water samples from various locations along the stream at estimated levels ranging from low ppt to low ppb. The levels of 4-NP in the storm water sediment samples, ranging from 30-1500 µg/kg (d.w.), positively correlated with the levels of Human-associated Bacteroides sp. (HF183) in the storm water. Our study suggested: 1) collective urban activity and leaky urban sewer systems are significant sources of ECs in storm water runoff that are often untreated or with minimum treatment before flowing into urban streams; and 2) sediment transport and re-suspension can further releases accumulated ECs back into stream water during rain events, resulting in occurrence of ECs downstream and possibly in the receiving river. This

  13. Viscosity changes of riparian water controls diurnal fluctuations of stream-flow and DOC concentration

    Science.gov (United States)

    Schwab, Michael; Klaus, Julian; Pfister, Laurent; Weiler, Markus

    2015-04-01

    Diurnal fluctuations in stream-flow are commonly explained as being triggered by the daily evapotranspiration cycle in the riparian zone, leading to stream flow minima in the afternoon. While this trigger effect must necessarily be constrained by the extent of the growing season of vegetation, we here show evidence of daily stream flow maxima in the afternoon in a small headwater stream during the dormant season. We hypothesize that the afternoon maxima in stream flow are induced by viscosity changes of riparian water that is caused by diurnal temperature variations of the near surface groundwater in the riparian zone. The patterns were observed in the Weierbach headwater catchment in Luxembourg. The catchment is covering an area of 0.45 km2, is entirely covered by forest and is dominated by a schistous substratum. DOC concentration at the outlet of the catchment was measured with the field deployable UV-Vis spectrometer spectro::lyser (scan Messtechnik GmbH) with a high frequency of 15 minutes over several months. Discharge was measured with an ISCO 4120 Flow Logger. During the growing season, stream flow shows a frequently observed diurnal pattern with discharge minima in the afternoon. During the dormant season, a long dry period with daily air temperature amplitudes of around 10 ° C occurred in March and April 2014, with discharge maxima in the afternoon. The daily air temperature amplitude led to diurnal variations in the water temperature of the upper 10 cm of the riparian zone. Higher riparian water temperatures cause a decrease in water viscosity and according to the Hagen-Poiseuille equation, the volumetric flow rate is inversely proportional to viscosity. Based on the Hagen-Poiseuille equation and the viscosity changes of water, we calculated higher flow rates of near surface groundwater through the riparian zone into the stream in the afternoon which explains the stream flow maxima in the afternoon. With the start of the growing season, the viscosity

  14. Enrichment of Arsenic in Surface Water, Stream Sediments and Soils in Tibet.

    Science.gov (United States)

    Li, Shehong; Wang, Mingguo; Yang, Qiang; Wang, Hui; Zhu, Jianming; Zheng, Baoshan; Zheng, Yan

    2013-12-01

    Groundwater in sedimentary deposits in China, Southern, and Southeast Asia down gradient from the Tibetan plateau contain elevated As concentrations on a regional scale. To ascertain the possibility of source region As enrichment, samples of water (n=86), stream sediment (n=77) and soil (n=73) were collected from the Singe Tsangpo (upstream of the Indus River), Yarlung Tsangpo (upstream of the Brahmaputra River) and other drainage basins in Tibet in June of 2008. The average arsenic concentration in stream waters, sediments and soils was 58±70 μg/L (n=39, range 2-252 μg/L), 42±40 mg/kg (n=37, range 12-227 mg/kg), and 44±27mg/kg (n=28, range 12-84 mg/kg) respectively for the Singe Tsangpo and was 11±17 μg/L (n=30, range 2-83 μg/L), 28±11 mg/kg (n=28, range 2-61 mg/kg), and 30±34 mg/kg (n=21, range 6-173 mg/kg) respectively for the Yarlung Tsangpo. A dug well contained 195 μg/L of As. In addition to elevated As levels in surface and shallow groundwater of Tibet, hot spring and alkaline salt lake waters displayed very high As levels, reaching a maximum value of 5,985 μg/L and 10,626 μg/L As, respectively. The positive correlation between [As] and [Na]+[K] in stream waters indicates that these surface water arsenic enrichments are linked to the hot springs and/or salt lakes. Further, 24% of As in stream sediment is reductively leachable, with bulk As displaying a positive correlation with stream water As, suggesting sorption from stream water. In contrast, the fraction of reductively leachable As is negligible for soils and several rock samples, suggesting that As in them are associated with unweathered minerals. Whether the pronounced As anomaly found in Tibet affects the sedimentary As content in deltas downstream or not requires further study.

  15. Application of the water gas shift reaction to fusion fuel exhaust streams

    International Nuclear Information System (INIS)

    McKay, A.M.; Cheh, C.H.; Glass, R.W.

    1983-10-01

    In a Fusion Fuel Clean Up (FCU) system, impurities will be removed from the fusion reactor exhaust and neutral beam line streams. Tritium in this impurity stream will be recovered and recycled to the fuel stream. In one flowsheet configuration of the Tritium Systems Test Assembly (TSTA), tritium is recovered from a simulated impurity stream via uranium hot metal beds and recycled to an isotope separation system. This study has shown, however, that the catalyzed water gas shift reaction, by which (H,D,T) 2 O and CO are converted to (H,D,T) 2 and CO 2 is a better method of (H,D,T) 2 O reduction than the hot metal beds. Catalytic reactors were designed, built and tested to provide data for the design of a prototype reactor to replace the hot metal beds in the FCU system. The prototype reactor contains only 10 g of catalyst and is expected to last at least 5 years. The reactor is small (1.3 cm OD x 13 cm long), operates at low temperatures (approximately 490 K) and will convert water to hydrogen, at a CO/H 2 O ratio of 1.5, with an efficiency of greater than 98 percent. Results show that the catalytic reactor is very stable even during upset conditions. Wide ranges of flow and a CO/H 2 O ratio variance from 1.3 upward have little effect on the conversion efficiency. Short term high temperature excursions do not affect the catalyst and lower temperatures will simply decrease the reaction rate resulting in lower conversions. The reactor appears to be unaffected by NO 2 , CO 2 , O 2 and N 2 in the feed stream at concentration levels expected in a fusion reactor exhaust stream

  16. High resolution stream water quality assessment in the Vancouver, British Columbia region: a citizen science study.

    Science.gov (United States)

    Shupe, Scott M

    2017-12-15

    Changing land cover and climate regimes modify water quantity and quality in natural stream systems. In regions undergoing rapid change, it is difficult to effectively monitor and quantify these impacts at local to regional scales. In Vancouver, British Columbia, one of the most rapidly urbanizing areas in Canada, 750 measurements were taken from a total of 81 unique sampling sites representing 49 streams located in urban, forest, and agricultural-dominant watersheds at a frequency of up to 12 times per year between 2013 and 2016. Dissolved nitrate (NO 3 -N) and phosphate (PO 4 -P) concentrations, turbidity, water temperature, pH and conductivity were measured by citizen scientists in addition to observations of hydrology, vegetation, land use, and visible stream impacts. Land cover was mapped at a 15-m resolution using Landsat 8 OLI imagery and used to determine dominant land cover for each watershed in which a sample was recorded. Regional, seasonal, and catchment-type trends in measurements were determined using statistical analyses. The relationships of nutrients to land cover varied seasonally and on a catchment-type basis. Nitrate showed seasonal highs in winter and lows in summer, though phosphate had less seasonal variation. Overall, nitrate concentrations were positively associated to agriculture and deciduous forest and negatively associated with coniferous forest. In contrast, phosphate concentrations were positively associated with agricultural, deciduous forest, and disturbed land cover and negatively associated with urban land cover. Both urban and agricultural land cover were significantly associated with an increase in water conductivity. Increased forest land cover was associated with better water quality, including lower turbidity, conductivity, and water temperature. This study showed the importance of high resolution sampling in understanding seasonal and spatial dynamics of stream water quality, made possible with the large number of

  17. Land-based sources of marine pollution: Pesticides, PAHs and phthalates in coastal stream water, and heavy metals in coastal stream sediments in American Samoa

    International Nuclear Information System (INIS)

    Polidoro, Beth A.; Comeros-Raynal, Mia T.; Cahill, Thomas; Clement, Cassandra

    2017-01-01

    The island nations and territories of the South Pacific are facing a number of pressing environmental concerns, including solid waste management and coastal pollution. Here we provide baseline information on the presence and concentration of heavy metals and selected organic contaminants (pesticides, PAHs, phthalates) in 7 coastal streams and in surface waters adjacent to the Futiga landfill in American Samoa. All sampled stream sediments contained high concentrations of lead, and some of mercury. Several coastal stream waters showed relatively high concentrations of diethyl phthalate and of organophosphate pesticides, above chronic toxicity values for fish and other aquatic organisms. Parathion, which has been banned by the US Environmental Protection Agency since 2006, was detected in several stream sites. Increased monitoring and initiatives to limit non-point source land-based pollution will greatly improve the state of freshwater and coastal resources, as well as reduce risks to human health in American Samoa. - Highlights: • Several coastal stream sediments in American Samoa are high in lead and mercury. • Organophosphate pesticides, including Parathion, are present in coastal streams. • More research is needed on the sources, fate and impacts of these contaminants.

  18. Residence times and nitrate transport in ground water discharging to streams in the Chesapeake Bay Watershed

    Science.gov (United States)

    Lindsey, Bruce D.; Phillips, Scott; Donnelly, Colleen A.; Speiran, Gary K.; Plummer, Niel; Bohlke, John Karl; Focazio, Michael J.; Burton, William C.; Busenberg, Eurybiades

    2003-01-01

    One of the major water-quality problems in the Chesapeake Bay is an overabundance of nutrients from the streams and rivers that discharge to the Bay. Some of these nutrients are from nonpoint sources such as atmospheric deposition, agricultural manure and fertilizer, and septic systems. The effects of efforts to control nonpoint sources, however, can be difficult to quantify because of the lag time between changes at the land surface and the response in the base-flow (ground water) component of streams. To help resource managers understand the lag time between implementation of management practices and subsequent response in the nutrient concentrations in the base-flow component of streamflow, a study of ground-water discharge, residence time, and nitrate transport in springs throughout the Chesapeake Bay Watershed and in four smaller watersheds in selected hydrogeomorphic regions (HGMRs) was conducted. The four watersheds were in the Coastal Plain Uplands, Piedmont crystalline, Valley and Ridge carbonate, and Valley and Ridge siliciclastic HGMRs.A study of springs to estimate an apparent age of the ground water was based on analyses for concentrations of chlorofluorocarbons in water samples collected from 48 springs in the Chesapeake Bay Watershed. Results of the analysis indicate that median age for all the samples was 10 years, with the 25th percentile having an age of 7 years and the 75th percentile having an age of 13 years. Although the number of samples collected in each HGMR was limited, there did not appear to be distinct differences in the ages between the HGMRs. The ranges were similar between the major HGMRs above the Fall Line (modern to about 50 years), with only two HGMRs of small geographic extent (Piedmont carbonate and Mesozoic Lowland) having ranges of modern to about 10 years. The median values of all the HGMRs ranged from 7 to 11 years. Not enough samples were collected in the Coastal Plain for comparison. Spring samples showed slightly younger

  19. Meteorological, stream-discharge, and water-quality data for water year 1992 from two basins in Central Nevada

    International Nuclear Information System (INIS)

    McKinley, P.W.; Oliver, T.A.

    1995-01-01

    The US Geological Survey, in cooperation with the US Department of Energy, is studying Yucca Mountain, Nevada, as a potential repository for high level nuclear waste. As part of the Yucca Mountain Site Project, the analog recharge study is providing data for the evaluation of recharge to the Yucca Mountain ground-water system given a cooler and wetter climate than currently exists. The current and climatic conditions are favorable to the isolation of radioactive waste. Because waste isolation from the accessible environment for 10,000 years is necessary, climatic change and the potential for increased ground-water recharge need to be considered as part of the characterization of the potential repository. Therefore, two small basins, measuring less than 2 square miles, were studied to determine the volume of precipitation available for recharge to ground water. The semiarid 3-Springs Basin is located to the east of Kawich Peak in the Kawich Range east of Tonopah, Nevada. Stewart Basin is a subalpine drainage basin north of Arc Dome in the Toiyabe Range north of Tonopah, Nevada. The purpose of this publication is to make available the meteorological, stream-discharge, and water-quality data collected during the study. Meteorological data collected include air temperature, soil temperature, solar radiation, and relative humidity. Stream-discharge data were collected from the surface-water outlet of each basin. Water-quality data are chemical analyses of water samples collected from surface- and ground-water sources. Each basin has a meteorological station located in the lower and upper reaches of the basin. Hydrologic records include stream-discharge and water-quality data from the lower meteorological site and water-quality data from springs within the basins

  20. Water quality and ecological condition of urban streams in Independence, Missouri, June 2005 through December 2008

    Science.gov (United States)

    Christensen, D.; Harris, Thomas E.; Niesen, Shelley L.

    2010-01-01

    To identify the sources of selected constituents in urban streams and better understand processes affecting water quality and their effects on the ecological condition of urban streams and the Little Blue River in Independence, Missouri the U.S. Geological Survey in cooperation with the City of Independence Water Pollution Control Department initiated a study in June 2005 to characterize water quality and evaluate the ecological condition of streams within Independence. Base-flow and stormflow samples collected from five sites within Independence, from June 2005 to December 2008, were used to characterize the physical, chemical, and biologic effects of storm runoff on the water quality in Independence streams and the Little Blue River. The streams draining Independence-Rock Creek, Sugar Creek, Mill Creek, Fire Prairie Creek, and the Little Blue River-drain to the north and the Missouri River. Two small predominantly urban streams, Crackerneck Creek [12.9-square kilometer (km2) basin] and Spring Branch Creek (25.4-km2 basin), were monitored that enter into the Little Blue River between upstream and downstream monitoring sites. The Little Blue River above the upstream site is regulated by several reservoirs, but streamflow is largely uncontrolled. The Little Blue River Basin encompasses 585 km2 with about 168 km2 or 29 percent of the basin lying within the city limits of Independence. Water-quality samples also were collected for Rock Creek (24.1-km2 basin) that drains the western part of Independence. Data collection included streamflow, physical properties, dissolved oxygen, chloride, metals, nutrients, common organic micro-constituents, and fecal indicator bacteria. Benthic macroinvertebrate community surveys and habitat assessments were conducted to establish a baseline for evaluating the ecological condition and health of streams within Independence. Additional dry-weather screenings during base flow of all streams draining Independence were conducted to

  1. Using heat to characterize streambed water flux variability in four stream reaches

    Science.gov (United States)

    Essaid, H.I.; Zamora, C.M.; McCarthy, K.A.; Vogel, J.R.; Wilson, J.T.

    2008-01-01

    Estimates of streambed water flux are needed for the interpretation of streambed chemistry and reactions. Continuous temperature and head monitoring in stream reaches within four agricultural watersheds (Leary Weber Ditch, IN; Maple Creek, NE; DR2 Drain, WA; and Merced River, CA) allowed heat to be used as a tracer to study the temporal and spatial variability of fluxes through the streambed. Synoptic methods (seepage meter and differential discharge measurements) were compared with estimates obtained by using heat as a tracer. Water flux was estimated by modeling one-dimensional vertical flow of water and heat using the model VS2DH. Flux was influenced by physical heterogeneity of the stream channel and temporal variability in stream and ground-water levels. During most of the study period (April-December 2004), flux was upward through the streambeds. At the IN, NE, and CA sites, high-stage events resulted in rapid reversal of flow direction inducing short-term surface-water flow into the streambed. During late summer at the IN site, regional ground-water levels dropped, leading to surface-water loss to ground water that resulted in drying of the ditch. Synoptic measurements of flux generally supported the model flux estimates. Water flow through the streambed was roughly an order of magnitude larger in the humid basins (IN and NE) than in the arid basins (WA and CA). Downward flux, in response to sudden high streamflows, and seasonal variability in flux was most pronounced in the humid basins and in high conductivity zones in the streambed. Copyright ?? 2008 by the American Society of Agronomy, Crop Science Society of America, and Soil Science Society of America. All rights reserved.

  2. Ceramic membrane ozonator for soluble organics removal from produced water

    Science.gov (United States)

    Siagian, U. W. R.; Dwipramana, A. S.; Perwira, S. B.; Khoiruddin; Wenten, I. G.

    2018-01-01

    In this work, the performance of ozonation for degradation of soluble organic compounds in produced water was investigated. Tubular ceramic membrane diffuser (with and without a static mixer in the lumen side) was used to facilitate contact between ozone and produced water. The ozonation was conducted at ozone flow rate of 8 L.min-1, ozone concentration of 0.4 ppm, original pH of the solution, and pressure of 1.2 bar, while the flow rates of the produced water were varied (192, 378 and 830 mL.min-1). It was found that the reduction of benzene, toluene, ethylbenzene, and xylene were 85%, 99%, 85%, and 95%, respectively. A lower liquid flow rate in a laminar state showed a better component reduction due to the longer contacting time between the liquid and the gas phase. The introduction of the static mixer in the lumen side of the membrane as a turbulence promoter provided a positive effect on the performance of the membrane diffuser. The twisted static mixer exhibited the better removal rate than the spiral static mixer.

  3. Survival of Acetate in Biodegraded Stream Water DOM: New Insights Based on NMR Spectroscopy

    Science.gov (United States)

    Whitty, S.; Waggoner, D. C.; Bowen, J. C.; Cory, R. M.; Kaplan, L.; Hatcher, P.

    2017-12-01

    DOM is a complex chemical mixture of high- (HMW) and low-molecular-weight (LMW) organic molecules that serve as the primary energy sources for heterotrophic bacteria in freshwater environments. However, there are still large uncertainties on the composition of DOM that is labile and thus rapidly metabolized. The current thinking is that labile DOM is primarily composed of monosaccharides, amino acids, and other LMW organic acids such as formic, acetic, or propionic among others, although some humic substances also are biologically labile. To test the contribution of LMW organic acids to the labile fraction of DOM, freshwater samples were collected from five streams within the Rio Tempisquito watershed in Costa Rica and subjected to differing degrees of biodegradation using a series of plug-flow bioreactors with residence times ranging from 0.5-150 min. Varying the residence times of bioreactors allows for separation and identification of labile from less labile to more recalcitrant DOM. The stream water fed into the bioreactors had DOC concentrations that ranged from 0.7-1.2 ppm C and the GF/F-filtered stream water as well as the bioreactor effluents were analyzed directly without pre-treatment using proton nuclear magnetic resonance spectroscopy (1H NMR). Small molecules dominated the 1H NMR spectra with the greatest changes, as a function of bioreactor residence time, in the carbohydrate, terminal methyl, and long-chain methylene structures. In contrast, acetate remained relatively constant after 150 min of bioreactor residence time, thus raising the question of why this inherently labile volatile fatty acid was not consumed by stream microbes colonizing bioreactors that otherwise metabolized approximately 35% of the total dissolved organic carbon present in the stream water. We suggest that acetate may resist biodegradation because it is complexed strongly with inorganic cations.

  4. Diel changes in water chemistry in an arsenic-rich stream and treatment-pond system

    Science.gov (United States)

    Gammons, C.H.; Grant, T.M.; Nimick, D.A.; Parker, S.R.; DeGrandpre, M.D.

    2007-01-01

    Arsenic concentrations are elevated in surface waters of the Warm Springs Ponds Operable Unit (WSPOU), located at the head of the upper Clark Fork River Superfund site, Montana, USA. Arsenic is derived from historical deposition of smelter emissions (Mill and Willow Creeks) and historical mining and milling wastes (Silver Bow Creek). Although long-term monitoring has characterized the general seasonal and flow-related trends in As concentrations in these streams and the pond system used to treat Silver Bow Creek water, little is known about solubility controls and sorption processes that influence diel cycles in As concentrations. Diel (24-h) sampling was conducted in July 2004 and August 2005 at the outlet of the treatment ponds, at two locations along a nearby reconstructed stream channel that diverts tributary water around the ponds, and at Silver Bow Creek 2??km below the ponds. Dissolved As concentration increased up to 51% during the day at most of the stream sites, whereas little or no diel change was displayed at the treatment-pond outlet. The strong cycle in streams is explained by pH- and temperature-dependent sorption of As onto hydrous metal oxides or biofilms on the streambed. Concentrations of dissolved Ca2+ and HCO3- at the stream sites showed a diel temporal pattern opposite to that of As, and geochemical modeling supports the hypothesis that the concentrations of Ca2+ and HCO3- were controlled by precipitation of calcite during the warm afternoon hours when pH rose above 9.0. Nightly increases in dissolved Mn and Fe(II) concentrations were out of phase with concentrations of other divalent cations and are more likely explained by redox phenomena. ?? 2007 Elsevier B.V. All rights reserved.

  5. Water diffusion in cytoplasmic streaming in Elodea internodal cells under the effect of antimitotic agents.

    Science.gov (United States)

    Vorob'ev, Vladimir N; Anisimov, Alexander V; Dautova, Nailya R

    2008-07-01

    The translational displacement of the cytoplasmic water in Elodea stem cells resulting from protein motor activity was measured using the NMR method. A 24-h treatment with vincristine results in a reduction of the translational displacement of the cytoplasmic water. With a constant cytoplasmic streaming velocity, the dynamics of the translational displacement of the cytoplasmic water under the effect of taxol are characterized by a continuous increase at a concentration of 0.05 mM, and reaching a plateau at a concentration of 0.5 mM.

  6. Have Norwegian producers of hydroelectric power wasted the water?

    International Nuclear Information System (INIS)

    2003-01-01

    Norwegian producers of hydroelectric power have been criticized for having exported power to Sweden during the autumn and winter 2003/2004. As this analysis shows, although the reservoir level in Norway was below normal in October already, the negative deviation from the normal reservoir level was even greater in Sweden till the end of the year. Also when the magnitude of the reserve is measured relative to the number of weeks with normal winter production for which it lasts, the situation was worse in Sweden than in Norway. After New Year the deviation from the normal reservoir level has been much the same in the two countries and has changed in parallel. During this period the exchange between the two countries has approximately balanced and the power flow from Sweden to Norway has grown gradually. With this as a background, there is no basis for asserting that the Norwegian producers have managed the water resources in an irresponsible way. In general, the power flow and the water resource management in the two countries appear reasonable considering the water influx and the prices. Different market imperfections may nevertheless have rendered the water resource management socially less then optimal.

  7. Reaction of Aluminum with Water to Produce Hydrogen - 2010 Update

    Energy Technology Data Exchange (ETDEWEB)

    Petrovic, John [Los Alamos National Lab. (LANL), Los Alamos, NM (United States); Thomas, George [Sandia National Lab. (SNL-NM), Albuquerque, NM (United States)

    2011-06-01

    A Study of Issues Related to the Use of Aluminum for On-Board Vehicular Hydrogen Storage The purpose of this White Paper is to describe and evaluate the potential of aluminum-water reactions for the production of hydrogen for on-board hydrogen-powered vehicle applications. Although the concept of reacting aluminum metal with water to produce hydrogen is not new, there have been a number of recent claims that such aluminum-water reactions might be employed to power fuel cell devices for portable applications such as emergency generators and laptop computers, and might even be considered for possible use as the hydrogen source for fuel cell-powered vehicles.

  8. Revised Methods for Characterizing Stream Habitat in the National Water-Quality Assessment Program

    Science.gov (United States)

    Fitzpatrick, Faith A.; Waite, Ian R.; D'Arconte, Patricia J.; Meador, Michael R.; Maupin, Molly A.; Gurtz, Martin E.

    1998-01-01

    Stream habitat is characterized in the U.S. Geological Survey's National Water-Quality Assessment (NAWQA) Program as part of an integrated physical, chemical, and biological assessment of the Nation's water quality. The goal of stream habitat characterization is to relate habitat to other physical, chemical, and biological factors that describe water-quality conditions. To accomplish this goal, environmental settings are described at sites selected for water-quality assessment. In addition, spatial and temporal patterns in habitat are examined at local, regional, and national scales. This habitat protocol contains updated methods for evaluating habitat in NAWQA Study Units. Revisions are based on lessons learned after 6 years of applying the original NAWQA habitat protocol to NAWQA Study Unit ecological surveys. Similar to the original protocol, these revised methods for evaluating stream habitat are based on a spatially hierarchical framework that incorporates habitat data at basin, segment, reach, and microhabitat scales. This framework provides a basis for national consistency in collection techniques while allowing flexibility in habitat assessment within individual Study Units. Procedures are described for collecting habitat data at basin and segment scales; these procedures include use of geographic information system data bases, topographic maps, and aerial photographs. Data collected at the reach scale include channel, bank, and riparian characteristics.

  9. Human-Nature Relationship in Mediterranean Streams: Integrating Different Types of Knowledge to Improve Water Management

    Directory of Open Access Journals (Sweden)

    Carla Gonzalez

    2009-12-01

    Full Text Available The social and ecological systems of Mediterranean streams are intrinsically linked as a result of long human occupation. In this region, these links vary greatly across small distances due to geomorphology, resulting in great diversity across space, which poses particular challenges for understanding and managing these systems. This demands (i interdisciplinary integration of knowledge that focuses on the social-ecological interactions, while according due consideration to the whole; and also (ii transdisciplinary integration, integrating lay and expert knowledge to understand local specificities. To address these needs - a focus on interactions and local knowledge - the research presented here studies the human-nature relationship in Mediterranean streams. Its main objective is to improve understanding of Mediterranean streams, but it also provides practical inputs to enhance local-level management. The study adopts an applied approach from the perspective of natural resources management. A case study was developed conducting field work on streams within the Natura 2000 site of Monfurado, Portugal - a mainly privately owned area with conflicting land uses between conservation and farming. Rivers and streams in Portugal are considered to be in very bad condition, particularly with regard to water quality. The experimental design was based, from a critical realism perspective of inter- and trans-disciplinarity, on the complementarities between methodologies from (i the social sciences: value survey and analysis of discourse; and (ii the natural sciences: biomonitoring and integrity biotic indexes. Results characterized the connected systems from both ecological and social points of view. They also characterized the relationship between both dimensions. We concluded that well-established riparian vegetation cover of streams is a key structural element of the human-nature relationship in the Mediterranean streams of Monfurado at several levels

  10. Water Quality of Combined Sewer Overflows, Stormwater, and Streams, Omaha, Nebraska, 2006-07

    Science.gov (United States)

    Vogel, Jason R.; Frankforter, Jill D.; Rus, David L.; Hobza, Christopher M.; Moser, Matthew T.

    2009-01-01

    The U.S. Geological Survey, in cooperation with the City of Omaha, investigated the water quality of combined sewer overflows, stormwater, and streams in the Omaha, Nebraska, area by collecting and analyzing 1,175 water samples from August 2006 through October 2007. The study area included the drainage area of Papillion Creek at Capeheart Road near Bellevue, Nebraska, which encompasses the tributary drainages of the Big and Little Papillion Creeks and Cole Creek, along with the Missouri River reach that is adjacent to Omaha. Of the 101 constituents analyzed during the study, 100 were detected in at least 1 sample during the study. Spatial and seasonal comparisons were completed for environmental samples. Measured concentrations in stream samples were compared to water-quality criteria for pollutants of concern. Finally, the mass loads of water-quality constituents in the combined sewer overflow discharges, stormwater outfalls, and streams were computed and compared. The results of the study indicate that combined sewer overflow and stormwater discharges are affecting the water quality of the streams in the Omaha area. At the Papillion Creek Basin sites, Escherichia coli densities were greater than 126 units per 100 milliliters in 99 percent of the samples (212 of 213 samples analyzed for Escherichia coli) collected during the recreational-use season from May through September (in 2006 and 2007). Escherichia coli densities in 76 percent of Missouri River samples (39 of 51 samples) were greater than 126 units per 100 milliliters in samples collected from May through September (in 2006 and 2007). None of the constituents with human health criteria for consumption of water, fish, and other aquatic organisms were detected at levels greater than the criteria in any of the samples collected during this study. Total phosphorus concentrations in water samples collected in the Papillion Creek Basin were in excess of the U.S. Environmental Protection Agency's proposed

  11. PCBs in Rain Water, Streams and a Reservoir in a Small Catchment of NW Spain

    Science.gov (United States)

    Delgado-Martín, Jordi; Cereijo-Arango, José Luis; García-Morrondo, David; Juncosa-Rivera, Ricardo; Cillero-Castro, Carmen; Muñoz-Ibáñez, Andrea

    2016-04-01

    Polychlorinated biphenyls (PCBs) constitute a significant environmental concern due to its persistence, tendency to bio-accumulate, acknowledged toxicity and ubiquity. In the present study, a small water catchment (~100 km2) inclusive of a two-tailed water supply reservoir (Abegondo-Cecebre) has been monitored between 2009 and 2014. Sampling stations include: a) one precipitation gauge used to collect monthly-integrated bulk precipitation (25 samples); b) seven streams (95 samples); c) five surface and one bottom points within the reservoir (104 samples); d) five points for sediment sampling in two surveys (spring and summer; 10 samples). All the water samples as well as the leachates of sediment washing have been analyzed for their concentration in 6 marker PCB (congeners 28, 52, 101, 138, 153 and 180) and 12 dioxin-like PCB (congeners 77, 81, 105, 114, 118, 123, 126, 156, 157, 167, 169 and 189) compounds. The average concentration of PCBtot in the bulk precipitation during the sampling period is ~406 pg/L although a very significant decrease has occurred since the end of 2011 (~800 pg/L) to the end of 2014 (~60 pg/L). Likewise, the mean concentration of PCBtot in the stream water samples is 174 pg/L and a similar reduction in the concentration of PCBtot is also acknowledged for the same period of time (~250 pg/L before the end of 2011 and ~30 pg/L after then). Reservoir surface water has a PCBtot concentration of ~234 pg/L which, according to its sampling time (2010-2011) is consistent with the measured stream waters. However, deep reservoir water reveals an average concentration which is higher than the corresponding top water (~330 pg/L) but significantly smaller than the water-leached sediments (~860 pg/L). The available data suggest that up to a 30% of PCBs associated with precipitation becomes sequestered by the soil/sediment system while no significant change takes place during the transfer of water from the stream to the reservoir system, at least in

  12. Arsenic transport in groundwater, surface water, and the hyporheic zone of a mine-influenced stream-aquifer system

    OpenAIRE

    Brown, Brendan

    2005-01-01

    We investigated the transport of dissolved arsenic in groundwater, surface water and the hyporheic zone in a stream-aquifer system influenced by an abandoned arsenopyrite mine. Mine tailing piles consisting of a host of arsenic-bearing minerals including arsenopyrite and scorodite remain adjacent to the stream and represent a continuous source of arsenic. Arsenic loads from the stream, springs, and groundwater were quantified at the study reach on nine dates from January to August 2005 and ...

  13. Study of Uranium Concentrations in Water and Organic Material from Streams in Sweden

    International Nuclear Information System (INIS)

    Ek, J.

    1981-12-01

    The purpose of the investigation has been to study how uranium concentrations in stream water and organic material are related to various geological parameters such as rock types, average uranium content and radioactivity, fracturing, leachability of uranium from the bedrock, occurrence of uranium mineralisations and thickness and type of Quarternary deposits. The investigation has also taken account of the effects of environmental factors such as climate , precipitation, height above sea level and topography. The background concentration of uranium in organic stream sediment varies from 1 ppm to 45 ppm, with a background value of 10 ppm for all 14 areas considered together. The threshold value for organic stream material varies from 3 ppm U to 303 ppm U with a threshold value of 133 ppm U for all 14 areas considered together. For water, the background concentration varies between the 5 areas from 0.2 ppb U to 0.7 ppb U with a background value of 0.4 ppb U for all 5 areas together. The threshold value varies from 0.3 ppb U to 5.2 ppb U with a threshold value of 2.9 ppb U for all 5 areas together. An investigation of the correlation between uranium concentrations in water and organic stream material from one and the same sampling point shows a positive correlation for high concentrations, but the correlation becomes successively less significant with lower concentrations. Uranium concentrations in organic stream material and water are positively correlated with the following geological parameters:1) Background concentrations of uranium in the bedrock. 2) Abundance of fractures in the bedrock. 3) Leachability of uranium from the bedrock. 4) Presence of uranium mineralisations. For organic stream material, this positive correlation is obtained for both high and low uranium concentrations whereas for water it occurs only with high concentrations. In areas of broken topography and high relief, there is a more clearly defined correlation to the bedrock than in areas of

  14. Assessing biogeochemical cycling and transient storage of surface water in Eastern Siberian streams using short-term solute additions

    Science.gov (United States)

    Schade, J. D.; Seybold, E.; Drake, T. W.; Bulygina, E. B.; Bunn, A. G.; Chandra, S.; Davydov, S.; Frey, K. E.; Holmes, R. M.; Sobczak, W. V.; Spektor, V. V.; Zimov, S. A.; Zimov, N.

    2009-12-01

    Recent studies highlight the role of stream networks in the processing of nutrient and organic matter inputs from the surrounding watershed. Clear evidence exists that streams actively regulate fluxes of carbon, nitrogen, and phosphorus from upland terrestrial ecosystems to downstream aquatic environments. This is of particular interest in Arctic streams because of the potential impact of permafrost thaw due to global warming on inputs of nutrients and organic matter to small streams high in the landscape. Knowledge of functional characteristics of these stream ecosystems is paramount to our ability to predict changes in stream ecosystems as climate changes. Biogeochemical models developed by stream ecologists, specifically nutrient spiraling models, provide a set of metrics that we used to assess nutrient processing rates in several streams in the Eastern Siberian Arctic. We quantified these metrics using solute addition experiments in which nitrogen and phosphorus were added simultaneously with chloride as a conservative tracer. We focused on 5 streams, three flowing across upland yedoma soils and two floodplain streams. Yedoma streams showed higher uptake of N than P, suggesting N limitation of biological processes, with large variation between these three streams in the severity of N limitation. Floodplain streams both showed substantially higher P uptake than N uptake, indicating strong P limitation. Given these results, it is probable that these two types of streams will respond quite differently to changes in nutrient and organic matter inputs as permafrost thaws. Furthermore, uptake was strongly linked to discharge and transient storage of surface water, measured using temporal patterns of the conservative tracer, with higher nutrient uptake in low discharge, high transient storage streams. Given the possibility that both discharge and nutrient inputs will increase as permafrost thaws, longer-term nutrient enrichment experiments are needed to develop

  15. Mercury in stream water at five Czech catchments across a Hg and S deposition gradient

    Science.gov (United States)

    Navrátil, Tomáš; Shanley, James B.; Rohovec, Jan; Oulehle, Filip; Krám, Pavel; Matoušková, Šárka; Tesař, Miroslav; Hojdová, Maria

    2015-01-01

    The Czech Republic was heavily industrialized in the second half of the 20th century but the associated emissions of Hg and S from coal burning were significantly reduced since the 1990s. We studied dissolved (filtered) stream water mercury (Hg) and dissolved organic carbon (DOC) concentrations at five catchments with contrasting Hg and S deposition histories in the Bohemian part of the Czech Republic. The median filtered Hg concentrations of stream water samples collected in hydrological years 2012 and 2013 from the five sites varied by an order of magnitude from 1.3 to 18.0 ng L− 1. The Hg concentrations at individual catchments were strongly correlated with DOC concentrations r from 0.64 to 0.93 and with discharge r from 0.48 to 0.75. Annual export fluxes of filtered Hg from individual catchments ranged from 0.11 to 13.3 μg m− 2 yr− 1 and were highest at sites with the highest DOC export fluxes. However, the amount of Hg exported per unit DOC varied widely; the mean Hg/DOC ratio in stream water at the individual sites ranged from 0.28 to 0.90 ng mg− 1. The highest stream Hg/DOC ratios occurred at sites Pluhův Bor and Jezeří which both are in the heavily polluted Black Triangle area. Stream Hg/DOC was inversely related to mineral and total soil pool Hg/C across the five sites. We explain this pattern by greater soil Hg retention due to inhibition of soil organic matter decomposition at the sites with low stream Hg/DOC and/or by precipitation of a metacinnabar (HgS) phase. Thus mobilization of Hg into streams from forest soils likely depends on combined effects of organic matter decomposition dynamics and HgS-like phase precipitation, which were both affected by Hg and S deposition histories.

  16. Biodegradable Polymeric Substances Produced by a Marine Bacterium from a Surplus Stream of the Biodiesel Industry

    Directory of Open Access Journals (Sweden)

    Sourish Bhattacharya

    2016-11-01

    Full Text Available Crude glycerol is generated as a by-product during transesterification process and during hydrolysis of fat in the soap-manufacturing process, and poses a problem for waste management. In the present approach, an efficient process was designed for simultaneous production of 0.2 g/L extracellular ε-polylysine and 64.6% (w/w intracellular polyhydroxyalkanoate (PHA in the same fermentation broth (1 L shake flask utilizing Jatropha biodiesel waste residues as carbon rich source by marine bacterial strain (Bacillus licheniformis PL26, isolated from west coast of India. The synthesized ε-polylysine and polyhydroxyalkanoate PHA by Bacillus licheniformis PL26 was characterized by thermogravimetric analysis (TGA, differential scanning colorimetry (DSC, Fourier transform infrared spectroscopy (FTIR, and 1H Nuclear magnetic resonance spectroscopy (NMR. The PHA produced by Bacillus licheniformis was found to be poly-3-hydroxybutyrate-co-3-hydroxyvalerate (P3HB-co-3HV. The developed process needs to be statistically optimized further for gaining still better yield of both the products in an efficient manner.

  17. Coalbed methane produced water in China: status and environmental issues.

    Science.gov (United States)

    Meng, Yanjun; Tang, Dazhen; Xu, Hao; Li, Yong; Gao, Lijun

    2014-01-01

    As one of the unconventional natural gas family members, coalbed methane (CBM) receives great attention throughout the world. The major associated problem of CBM production is the management of produced water. In the USA, Canada, and Australia, much research has been done on the effects and management of coalbed methane produced water (CMPW). However, in China, the environmental effects of CMPW were overlooked. The quantity and the quality of CMPW both vary enormously between coal basins or stratigraphic units in China. The unit produced water volume of CBM wells in China ranges from 10 to 271,280 L/well/day, and the concentration of total dissolved solids (TDS) ranges from 691 to 93,898 mg/L. Most pH values of CMPW are more than 7.0, showing the alkaline feature, and the Na-HCO3 and Na-HCO3-Cl are typical types of CMPW in China. Treatment and utilization of CMPW in China lag far behind the USA and Australia, and CMPW is mainly managed by surface impoundments and evaporation. Currently, the core environmental issues associated with CMPW in China are that the potential environmental problems of CMPW have not been given enough attention, and relevant regulations as well as environmental impact assessment (EIA) guidelines for CMPW are still lacking. Other potential issues in China includes (1) water quality monitoring issues for CMPW with special components in special areas, (2) groundwater level decline issues associated with the dewatering process, and (3) potential environmental issues of groundwater pollution associated with hydraulic fracturing.

  18. Carcinogenic ptaquiloside in stream water at base flow and during storm events

    DEFF Research Database (Denmark)

    Strobel, Bjarne W.; Clauson-Kaas, Frederik; Hansen, Hans Chr. Bruun

    2017-01-01

    identified, of which the compound ptaquiloside (PTA) is the most abundant. Ptaquiloside has been shown to be highly water soluble, leachable from bracken fronds and litter, and present in the soil below bracken stands. During storm events throughfall from the bracken canopy was collected as well. Stream...... water samples were taken as grab samples, while throughfall accumulated in glass jars set out below the canopy. Field blanks and fortified lab controls were included to ensure reliability of the analysis. Ptaquiloside concentrations were determined using LC-MS/MS after a clean-up using solid phase...... extraction. Results showed that PTA levels in the stream were highly dependent on precipitation, and was rising considerably during rain events, peaking at 2.28 μg/L, before quickly (conservation...

  19. MIB-producing cyanobacteria (Planktothrix sp.) in a drinking water reservoir: distribution and odor producing potential.

    Science.gov (United States)

    Su, Ming; Yu, Jianwei; Zhang, Junzhi; Chen, Hui; An, Wei; Vogt, Rolf D; Andersen, Tom; Jia, Dongmin; Wang, Jingshi; Yang, Min

    2015-01-01

    The production of odorant 2-methylisoborneol (MIB) in water bodies by Planktothrix sp. have not been understood very well. Through a four-year investigation in Miyun Reservoir, a huge mesotrophic drinking water reservoir known to have the MIB episodes, we found that the Planktothrix sp. bloomed during September and October causing the high levels of MIB in the reservoir. The concentration of MIB and the biomass of MIB-producing cyanobacteria Planktothrix were measured (n = 887) at different sites and depths during different seasons. The results indicated that the shallow region of the reservoir is the major habitat for Planktothrix sp. due to that the light is able to penetrate down to the relatively high concentrations of nutrients close to the sediments. Quantile regression analysis between Planktothrix biomass and MIB concentration shows that the risk of MIB exceeding the odor threshold (15 ng L⁻¹) in water was as high as 90% when the Planktothrix density was more than 4.0 × 10⁵ cells L⁻¹, while the risk was reduced to 10% when the Planktothrix density remained below 1.6 × 10⁴ cells L⁻¹. This study will improve the understanding of the environmental behaviors of Planktothrix sp., and can provide useful information for better management of drinking water lakes/reservoirs experiencing the taste and odor (T&O) problems caused by deep living cyanobacterial species.

  20. VARIABILITY OF VALUES OF PHYSICOCHEMICAL WATER QUALITY INDICES ALONG THE LENGTH OF THE IWONICZANKA STREAM

    Directory of Open Access Journals (Sweden)

    Andrzej Bogdał

    2015-11-01

    Full Text Available The paper aims at presentation of the effect of changes in the catchment area management on the value of water quality physicochemical indices along the length of the Iwoniczanka stream, which flows through Iwonicz-Zdrój, one of the oldest health resorts in Poland. Analyses of 14 water quality indices were conducted from November 2013 to May 2014 in five measurement points: two situated in the upper course of the stream – in forest areas, two located in the area of Iwonicz-Zdrój town, and one below the rural built-up area. On the basis of the conducted data analysis it was found that the mean values of pH, electrolytic conductivity, sulphates, calcium, total iron and manganese were increasing with the course of flowing water, as evidenced by the water enrichment in substances which had their sources in built-up areas. On average, the highest values of biogenic indices and chlorides but the lowest values of oxygen indices were registered immediately below the location of drain collector from the closed sewage treatment plant, which resulted in pollution of the analysed stream bed with the substances previously drained from the treatment plant. Water flowing through the forest areas had the maximum ecological potential in the built-up areas and due to phosphate concentrations it was classified to class II and then, due to self-purification, returned to the physicochemical parameters appropriate for class I water. The conducted hydro-chemical tests confirmed a significant negative effect of built-up areas on the quality of the flowing waters.

  1. Evaluation of Jacuba stream water and industrial effluents quality by SR-TXRF

    International Nuclear Information System (INIS)

    Moreira, Silvana; Oliveira, Renato W.M.

    2005-01-01

    The pollution of the environment became everywhere of public interest of the world. The developed countries not just come being affected for the environmental problems; the developing nations also begin to suffer the serious impacts of the pollution, what elapses of the fast economic growth associated to the exploration of natural resources. This work has as objective to use the TXRF technique on the study the water quality of the Jacuba stream in Hortolandia city. (author)

  2. Water Quality, Macroinvertebrates, and Fisheries in Tailwaters and Related Streams. An Annotated Bibliography.

    Science.gov (United States)

    1981-05-01

    more rapidly available source of energy and protein below the dam than that normally present in unregulated streams. Benthic diversity was lowest at...robusta; bluehead sucker, Pantosteus delphinus; and humpback sucker, Xyrauchen texanus) in Dinosaur National Monument were con- ducted from May 1964 to...duced successfully in Dinosaur National Monument every year since impoundment. During years of high summer discharge from the dam resultant lower water

  3. Evaluation of Jacuba stream water and industrial effluents quality by SR-TXRF

    Energy Technology Data Exchange (ETDEWEB)

    Moreira, Silvana; Oliveira, Renato W.M. [Universidade Estadual de Campinas, SP (Brazil). Faculdade de Engenharia Civil, Arquitetura e Urbanismo]. E-mail: silvana@fec.unicamp.br; Vives, Ana Elisa S. de [Universidade Metodista de Piracicaba (UNIMEP), Santa Barbara D' Oeste, SP (Brazil). Faculdade de Engenharia, Arquitetura e Urbanismo]. E-mail: aesvives@unimep.br; Zucchi, Orgheda L.A.D. [Sao Paulo Univ., Ribeirao Preto, SP (Brazil). Faculdade de Ciencias Farmaceuticas]. E-mail: olzucchi@fcfrp.usp.br; Nascimento Filho, Virgilio F. [Centro de Energia Nuclear na Agricultura (CENA), Piracicaba, SP (Brazil)]. E-mail: virgilio@cena.usp.br

    2005-07-01

    The pollution of the environment became everywhere of public interest of the world. The developed countries not just come being affected for the environmental problems; the developing nations also begin to suffer the serious impacts of the pollution, what elapses of the fast economic growth associated to the exploration of natural resources. This work has as objective to use the TXRF technique on the study the water quality of the Jacuba stream in Hortolandia city. (author)

  4. Controls on stream water dissolved mercury in three mid-Appalachian forested headwater catchments

    Science.gov (United States)

    Riscassi, Ami L.; Scanlon, Todd M.

    2011-12-01

    Determining the controls on dissolved mercury (HgD) transport is necessary to improve estimations of export from unmonitored watersheds and to forecast responses to changes in deposition and other environmental forcings. Stream water HgD and dissolved organic carbon (DOC) were evaluated over a range of discharge conditions in three streams within Shenandoah National Park, VA. Watersheds are distinguished by stream water pH (ranging from neutral to acidic) and soil size fractioning (ranging from clays to sands). At all sites, discharge was a significant but poor predictor of HgD concentrations (r2 from 0.13-0.52). HgD was strongly coupled with DOC at all sites (r2 from 0.74-0.89). UV absorbance at 254 nm (UV254), a proxy for DOC quantity and quality, slightly improved the predictions of HgD. Mean DOC quality differed between streams, with less aromatic DOC mobilized from the more acidic watershed. The site with less aromatic DOC and sandy soils mobilized more Hg to the stream for the same quantity and quality of DOC, likely due to the reduced capacity of the larger-grained soils to retain Hg, leaving a greater fraction associated with the organic matter. A similar amount of 0.54 ng HgD/mg DOC is transported at all sites, suggesting the less aromatic DOC transports less Hg per unit DOC, offsetting the effects of soil type. This research demonstrates that soil composition and DOC quality influence HgDexport. We also provide evidence that soil organic carbon is a primary control on Hg-DOC ratios (0.12-1.4 ng mg-1) observed across the U.S. and Sweden.

  5. Stormwater management impacts on urban stream water quality and quantity during and after development in Clarksburg, MD

    Science.gov (United States)

    Loperfido, J. V.; Noe, G. B.; Jarnagin, S.; Mohamoud, Y. M.; Van Ness, K.; Hogan, D. M.

    2012-12-01

    Urbanization and urban land use leads to degradation of local stream habitat and 'urban stream syndrome.' Best Management Practices (BMPs) are often used in an attempt to mitigate the impact of urban land use on stream water quality and quantity. Traditional development has employed stormwater BMPs that were placed in a centralized manner located either in the stream channel or near the riparian zone to treat stormwater runoff from large drainage areas; however, urban streams have largely remained impaired. Recently, distributed placement of BMPs throughout the landscape has been implemented in an attempt to detain, treat, and infiltrate stormwater runoff from smaller drainage areas near its source. Despite increasing implementation of distributed BMPs, little has been reported on the catchment-scale (1-10 km^2) performance of distributed BMPs and how they compare to centralized BMPs. The Clarksburg Special Protection Area (CSPA), located in the Washington, DC exurbs within the larger Chesapeake Bay watershed, is undergoing rapid urbanization and employs distributed BMPs on the landscape that treat small drainage areas with the goal of preserving high-quality stream resources in the area. In addition, the presence of a nearby traditionally developed (centralized BMPs) catchment and an undeveloped forested catchment makes the CSPA an ideal setting to understand how the best available stormwater management technology implemented during and after development affects stream water quality and quantity through a comparative watershed analysis. The Clarksburg Integrated Monitoring Partnership is a consortium of local and federal agencies and universities that conducts research in the CSPA including: monitoring of stream water quality, geomorphology, and biology; analysis of stream hydrological and water quality data; and GIS mapping and analysis of land cover, elevation change and BMP implementation data. Here, the impacts of urbanization on stream water quantity

  6. Risk assessment for produced water discharges to Louisiana Open Bays

    Energy Technology Data Exchange (ETDEWEB)

    Meinhold, A.F.; DePhillips, M.P.; Holtzman, S.

    1995-06-23

    Data were collected prior to termination of discharge at three sites (including two open bay sites at Delacroix Island and Bay De Chene) for the risk assessments. The Delacroix Island Oil and Gas Field has been in production since the first well drilling in 1940; the Bay De Chene Field, since 1942. Concentrations of 226Ra, 228Ra, 210Po, and 228Th were measured in discharges. Radium conc. were measured in fish and shellfish tissues. Sediment PAH and metal conc. were also available. Benthos sampling was conducted. A survey of fishermen was conducted. The tiered risk assessment showed that human health risks from radium in produced water appear to be small; ecological risk from radium and other radionuclides in produced water also appear small. Many of the chemical contaminants discharged to open Louisiana bays appear to present little human health or ecological risk. A conservative screening analysis suggested potential risks to human health from Hg and Pb and a potential risk to ecological receptors from total effluent, Sb, Cd, Cu, Pb, Ni, Ag, Zn, and phenol in the water column and PAHs in sediment; quantitiative risk assessments are being done for these contaminants.

  7. Functionalized sio2 microspheres for extracting oil from produced water

    KAUST Repository

    Mishra, Himanshu

    2017-03-16

    Functionalized material, methods of producing the functionalized material, and use thereof for separation processes such as but not limited to use for separating and extracting a dissolved organic foulant, charged contaminant or oily matter or any combination thereof from water, such as produced water, are provided. In an embodiment, the functionalized material is a mineral material, such as mica, silica (e.g. an SiO2 microsphere) or a metal oxide, and the outer surface of the material is functionalized with an alkyl chain or a perfluorinated species. In an embodiment, the method of making the functionalized material, includes: a) providing a mineral material; b) providing an alkyl chain and/or a perfluorinated species, the alkyl chain or perfluorinated species selected to dissolve organic foulants, charged contaminants or oily matter from water or any combination thereof; c) hydroxylating the material via a concentrated acid solution or a basic solution; and d) grafting the alkyl chain and/or the perfluorinated species onto the material via a silanation reaction.

  8. Experimental investigation of mixing of non-isothermal water streams at BWR operating conditions

    Energy Technology Data Exchange (ETDEWEB)

    Bergagio, Mattia, E-mail: bergagio@kth.se [AlbaNova University Center, Nuclear Reactor Technology Division, Department of Physics, Royal Institute of Technology, 106 91 Stockholm (Sweden); Anglart, Henryk, E-mail: henryk@kth.se [AlbaNova University Center, Nuclear Reactor Technology Division, Department of Physics, Royal Institute of Technology, 106 91 Stockholm (Sweden); Institute of Heat Engineering, Warsaw University of Technology, 21/25 Nowowiejska Street, 00-665 Warsaw (Poland)

    2017-06-15

    Highlights: • Temperatures are measured in the presence of mixing at BWR operating conditions. • The thermocouple support is moved along a pattern to extend the measurement region. • Uncertainty of 1.58 K for temperatures acquired at 1000 Hz. • Momenta of the hot streams and thermal stratification affect the data examined. • Unconventional spectral analysis is required to further study the data collected. - Abstract: In this experimental investigation, wall surface temperatures have been measured during mixing of three water streams in the annular gap between two coaxial stainless-steel tubes. The inner tube, with an outer diameter of 35 mm and a thickness of 5 mm, holds six K-type, ungrounded thermocouples with a diameter of 0.5 mm, which measured surface temperatures with a sampling rate of either 100 Hz or 1000 Hz. The tube was rotated from 0 to 360° and moved in a range of 387 mm in the axial direction to allow measurements of surface temperatures in the whole mixing region. The outer tube has an inner diameter of 80 mm and a thickness of 10 mm to withstand a water pressure of 9 MPa. A water stream at a temperature of either 333 K or 423 K and a Reynolds number between 1657 and 8410 rose vertically in the annular gap and mixed with two water streams at a temperature of 549 K and a Reynolds number between 3.56 × 10{sup 5} and 7.11 × 10{sup 5}. These two water streams entered the annulus radially on the same axial level, 180° apart. Water pressure was kept at 7.2 MPa. Temperature recordings were performed at five axial and eight azimuthal locations, for each set of boundary conditions. Each recording lasted 120 s to provide reliable data on the variance, intermittency and frequency of the surface temperature time series at hand. Thorough calculations indicate that the uncertainty in the measured temperature is of 1.58 K. The mixing region extends up to 0.2 m downward of the hot inlets. In most cases, measurements indicate non-uniform mixing in the

  9. Monitoring Environmental Recovery at Terminated Produced Water Discharge Sites in Coastal Louisiana Waters

    Energy Technology Data Exchange (ETDEWEB)

    Continental Shelf Associates, Inc.

    1999-08-16

    This report presents the results of a study of terminated produced water discharge sites in the coastal waters of Louisiana. Environmental recovery at the sites is documented by comparing pre-termination and post-termination (six months and one year) data. Produced water, sediments, and sediment interstitial water samples were analyzed for radionuclides, metals, and hydrocarbons. Benthic infauna were identified from samples collected in the vicinity of the discharge and reference sites. Radium isotope activities were determined in fish and crustacean samples. In addition, an environmental risk assessment is made on the basis of the concentrations of metals and hydrocarbons determined in the samples.

  10. Organic and inorganic species in produced water: Implications for water reuse

    Science.gov (United States)

    Kharaka, Yousif K.; Rice, Cynthia A.

    2004-01-01

    Currently 20-30 billion barrels of formation water are co-produced annually in the USA with conventional oil and natural gas. The large database on the geochemistry of this produced water shows salinities that vary widely from ~5,000 to >350,000 mg/L TDS. Chloride, Na and Ca are generally the dominant ions, and concentrations of Fe, Mn, B, NH3 and dissolved organics, including, BTEX, phenols and poly aromatic hydrocarbons (PAHs) may be relatively high. Hazardous concentrations of NORMs, including Ra-226 and Rn-222 have been reported in produced water from several states.Coal-bed methane (CBM) wells currently produce close to a billion barrels of water and deliver ~8% of total natural gas. The salinity of this produced water generally is lower than that of water from petroleum wells; salinity commonly is 1,000-20,000 mg/L, but ranges to150,000 mg/L TDS. Most CBM wells produce Na-HCO3-Cl type water that is low in trace metals and has no reported NORMs. This water commonly has no oil and grease and has relatively low DOC, but its organic composition has not been characterized in detail. The water is disposed of by injection into saline aquifers, through evaporation and/or percolation in disposal pits, road spreading, and surface discharge. Water that has an acceptable salinity and sodium absorption ratio (SAR) is considered acceptable for surface discharge and for injection into freshwater aquifers.As an alternative to costly disposal, low salinity produced water is being considered for reclamation, especially in the arid western USA. The cost of reclaiming this water to meet irrigation, industrial and drinking water standards was evaluated in a 10 gpm pilot field study at Placerita oil field, California. This produced water had a low salinity of ~8,000 mg/L, but high concentration of Si and organics. Removal of B, Si, NH3 and especially organics from this water proved difficult, and the estimated treatment cost was high at $0.08-$0.39/bbl for water treated for

  11. Tracing disturbance impacts on water quantity and quality through a stream network

    Science.gov (United States)

    Ross, Matthew; Nippgen, Fabian; McGlynn, Brian; Bernhardt, Emily

    2017-04-01

    By dismantling and redistributing 100s of meters of bedrock to mine coal from the surface, mountaintop mining with valley fills has dramatically changed catchment hydrology and biogeochemistry over more than 5,000 km2 in Central Appalachia. Throughout this expansive coal region, mining operators deposit tens of millions of m3 of crushed bedrock into headwater valleys, creating valley fills, which have substantial subsurface water storage potential. Streams draining mines have reduced peakflows, elevated baseflows, and lower event runoff ratios on average. The water stored in and percolating through valley fills drives the dissolution and oxidation of pyrite into sulfuric acid which reacts with carbonate-rich materials to rapidly weather out a suite of elements including Ca2+, Mg2+, K+, SO42-, HCO3-, and the pollutant Selenium. Together these ions increase the average specific conductance of mined streams from 60 to 1,500 µS/cm, 25-times higher than unmined streams, exporting 45-times more total dissolved solids. Together, the increased catchment storage, consequent elevated baseflow, and elevated weathering rates from mining have the potential to lower water quality throughout river networks in Central Appalachia, especially during the summer low flow period. To better understand the water quality impacts of mining at the river network scale, we used the paired catchment approach. Working in the Mud River, West Virginia, we instrumented a 4th order catchment 35 km2, that was 46% mined. Within the large catchment we instrumented 8 additional 1st-3rd order sub-catchments that varied in catchment size, mining cover, mine size, and mine age. At each site we measured stream discharge and specific conductance (SC). Using SC as a trace for mining we did simple hydrograph separations at our largest catchments, partitioning the hydrograph between mined and unmined water. Our results suggest that on an annual scale, mine water contributes a disproportionate percentage of

  12. Analysis on the Water Exchange between the Main Stream of the Yangtze River and the Poyang Lake

    NARCIS (Netherlands)

    Zhao, J.; Li, J.; Yan, H.; Zheng, L.; Dai, Z.

    2011-01-01

    Analysis on the hydrologic characteristics of the main stream of the Yangtze River and Poyang Lake were studied to discuss the water exchange between the main stream of the Yangtze River and Poyang Lake before and after the operation of Three Gorges Reservoir, as well as in the typical dry year of

  13. Effects of road salts on groundwater and surface water dynamics of socium and chloride in an urban restored stream

    Science.gov (United States)

    Road salts are a growing environmental concern in urban watersheds. We examined groundwater (GW) and surface water (SW) dynamics of Na+ and Cl− in Minebank Run (MBR), an urban stream in Maryland, USA. We observed an increasing salinity trend in this restored stream. Current basef...

  14. Groundwater and surface water dynamics of Na and Cl in an urban stream: effects of road salts

    Science.gov (United States)

    AbstractRoad salts are a growing environmental and health concern in urban watersheds. We examined groundwater (GW) and surface water (SW) dynamics of Na and Cl in an urban stream, Minebank Run (MBR), MD. We observed an increasing salinity trend in this restored stream. Current b...

  15. Evaluating the accotink creek restoration project for improving water quality, in-stream habitat, and bank stability

    Science.gov (United States)

    Struck, S.D.; Selvakumar, A.; Hyer, K.; O'Connor, T.

    2007-01-01

    Increased urbanization results in a larger percentage of connected impervious areas and can contribute large quantities of stormwater runoff and significant quantities of debris and pollutants (e.g., litter, oils, microorganisms, sediments, nutrients, organic matter, and heavy metals) to receiving waters. To improve water quality in urban and suburban areas, watershed managers often incorporate best management practices (BMPs) to reduce the quantity of runoff as well as to minimize pollutants and other stressors contained in stormwater runoff. It is well known that land-use practices directly impact urban streams. Stream flows in urbanized watersheds increase in magnitude as a function of impervious area and can result in degradation of the natural stream channel morphology affecting the physical, chemical, and biological integrity of the stream. Stream bank erosion, which also increases with increased stream flows, can lead to bank instability, property loss, infrastructure damage, and increased sediment loading to the stream. Increased sediment loads may lead to water quality degradation downstream and have negative impacts on fish, benthic invertebrates, and other aquatic life. Accotink Creek is in the greater Chesapeake Bay and Potomac watersheds, which have strict sediment criteria. The USEPA (United States Environmental Protection Agency) and USGS (United States Geological Survey) are investigating the effectiveness of stream restoration techniques as a BMP to decrease sediment load and improve bank stability, biological integrity, and in-stream water quality in an impaired urban watershed in Fairfax, Virginia. This multi-year project continuously monitors turbidity, specific conductance, pH, and water temperature, as well as biological and chemical water quality parameters. In addition, physical parameters (e.g., pebble counts, longitudinal and cross sectional stream surveys) were measured to assess geomorphic changes associated with the restoration. Data

  16. Water-supply potential of major streams and the Upper Floridan Aquifer in the vicinity of Savannah, Georgia

    Science.gov (United States)

    Garza, Reggina; Krause, Richard E.

    1997-01-01

    Surface- and ground-water resources in the Savannah, Georgia, area were evaluated for potential water-supply development. Stream-discharge and water-quality data were analyzed for two major streams considered to be viable water-supply sources. A ground-water flow model was developed to be used in conjunction with other previously calibrated models to simulate the effects of additional pumpage on water levels near areas of saltwater intrusion at Brunswick and seawater encroachment at Hilton Head Island. Hypothetical scenarios also were simulated involving redistributions and small increases, and decreases in pumpage.

  17. Rare earth elements (REE) and yttrium in stream waters, stream sediments, and Fe Mn oxyhydroxides: Fractionation, speciation, and controls over REE + Y patterns in the surface environment

    Science.gov (United States)

    Leybourne, Matthew I.; Johannesson, Karen H.

    2008-12-01

    We have collected ˜500 stream waters and associated bed-load sediments over an ˜400 km 2 region of Eastern Canada and analyzed these samples for Fe, Mn, and the rare earth elements (REE + Y). In addition to analyzing the stream sediments by total digestion (multi-acid dissolution with metaborate fusion), we also leached the sediments with 0.25 M hydroxylamine hydrochloride (in 0.05 M HCl), to determine the REE + Y associated with amorphous Fe- and Mn-oxyhydroxide phases. We are thus able to partition the REE into "dissolved" (primary sources, the host lithologies (i.e., mechanical dispersion) and hydromorphically transported (the labile fraction). Furthermore, Eu appears to be more mobile than the other REE, whereas Ce is preferentially removed from solution and accumulates in the stream sediments in a less labile form than the other REEs + Y. Despite poor statistical correlations between the REEs + Y and Mn in either the total sediment or partial extractions, based on apparent distribution coefficients and the pH of the stream waters, we suggest that either sediment organic matter and/or possibly δ-MnO 2/FeOOH are likely the predominant sinks for Ce, and to a lesser extent the other REE, in the stream sediments.

  18. Stream water chemistry after two forest fertilizations with Skog Vital in central Sweden

    International Nuclear Information System (INIS)

    Ring, E.; Nohrstedt, H.Oe.

    1993-05-01

    A study was made of the impact of forest fertilization (non-nitrogenous mix) on the water chemistry of two streams, which drain catchment areas in east Haerjedalen in Sweden. In summer 1990, part of one of the catchment areas was fertilized by tractor at a dose of 0.6 tonnes per hectare, and part of the other by helicopter at a dose of 0.5 tonnes per hectare. The fertilizer contained base cations, sulphur, phosphorus, zinc and boron. Water samples were taken at a water-sampling station upstream of the treated area and at a water-sampling station downstream of the treated area. A total of 30 samples were made and the water was analysed for pH, alkalinity, nitrogen, phosphorus, base cations, aluminium and sulphate. Discharge was both measured and simulated, the latter using a runoff model. An estimate was made of the additional leaching resulting from fertilization. 13 refs, 12 figs, 6 tabs

  19. Connectivity of streams and wetlands to downstream waters: An integrated systems framework

    Science.gov (United States)

    Leibowitz, Scott G.; Wigington, Parker J.; Schoefield, Kate A.; Alexander, Laurie C.; Vanderhoof, Melanie; Golden, Heather E.

    2018-01-01

    Interest in connectivity has increased in the aquatic sciences, partly because of its relevance to the Clean Water Act. This paper has two objectives: (1) provide a framework to understand hydrological, chemical, and biological connectivity, focusing on how headwater streams and wetlands connect to and contribute to rivers; and (2) briefly review methods to quantify hydrological and chemical connectivity. Streams and wetlands affect river structure and function by altering material and biological fluxes to the river; this depends on two factors: (1) functions within streams and wetlands that affect material fluxes; and (2) connectivity (or isolation) from streams and wetlands to rivers that allows (or prevents) material transport between systems. Connectivity can be described in terms of frequency, magnitude, duration, timing, and rate of change. It results from physical characteristics of a system, e.g., climate, soils, geology, topography, and the spatial distribution of aquatic components. Biological connectivity is also affected by traits and behavior of the biota. Connectivity can be altered by human impacts, often in complex ways. Because of variability in these factors, connectivity is not constant but varies over time and space. Connectivity can be quantified with field‐based methods, modeling, and remote sensing. Further studies using these methods are needed to classify and quantify connectivity of aquatic ecosystems and to understand how impacts affect connectivity.

  20. Continuous analytical control of the streaming waters in a uranium treatment plant and of various chemical products using automatic discharge valves

    International Nuclear Information System (INIS)

    Archimbaud, M.; Simeon, C.

    1968-01-01

    This report describes a method for controlling the streaming waters produced by the Pierrelatte Centre; it is based on continuous analysis, with simultaneous recording of the species liable to be found accidentally in the corresponding hydrological circuits (chlorides, fluorides, chromium VI, uranium). An alarm set off at pre-determined thresholds leads to an automatic cutting off of the discharge valves; the outward flow of the waters is thus interrupted. This study has shown the various applications which can be found for this water control method, and gives an idea of the cost price. (authors) [fr

  1. Distribution of clay minerals in the process streams produced by the extraction of bitumen from Athabasca oil sands

    Energy Technology Data Exchange (ETDEWEB)

    Kaminsky, H.A.W.; Etsell, T.H.; Ivey, D.G. [Alberta Univ., Edmonton, AB (Canada). Dept. of Chemical and Materials Engineering; Omotoso, O. [Natural Resources Canada, Devon, AB (Canada). CETC

    2009-02-15

    The clay minerals present in the oil sands were studied with particular reference to how they are partitioned in bitumen ore during the extraction process. Bitumen production from surface-mined oil sands accounts for nearly two-thirds of the total bitumen production in Alberta. Every cubic meter of mined ore results in 1.3 cubic meters of mature fine tailings (MFT). The characteristic differences between the clay minerals that report to the froth versus the tailings streams were also examined to determine which minerals could impact different unit operations in the bitumen extraction process. X-ray diffraction and random powder samples were used to quantify the clay minerals. Particle size distribution and clay activity balances were also conducted. The degree of partitioning during the conditioning and flotation stages in a batch extractor was determined by the surface properties of the clay minerals. The water-continuous tailings stream was separated into fine and coarse tailings fractions through sedimentation. The study showed that bitumen-clay interactions may be dominated by kaolinite or iron oxides. Clays are responsible for the poor settling behaviour of MFTs. The clay minerals present in the oil sands include illite, illite-smectite, kaolinite, kaolinite-smectite, and chlorite. The close proximity of the tailings ponds to the Athabasca River and volatile organic compounds (VOCs) emission require that the ponds be reclaimed to a natural landscape before mine closure. In addition to its impact on fine tailings reclamation, clay mineralogy plays a role in extraction froth flotation and emulsion stability during froth treatment. The mineralogy of the froth solids was found to be different from the mineralogy of the middlings and tailings solids. 39 refs., 6 tabs., 6 figs.

  2. The effects of human land use on flow regime and water chemistry of headwater streams in the highlands of Chiapas

    Directory of Open Access Journals (Sweden)

    Castillo M.M.

    2013-03-01

    Full Text Available We studied the effects of land use changes on flow regime and water chemistry of headwater streams in the highlands of Chiapas, a region in southern Mexico that has experienced high rates of deforestation in the last decades. Samples for water chemistry were collected and discharge was measured between September 2007 and August 2008 at eight streams that differed in the land uses of their riparian and catchment areas, including streams draining protected forested areas. Streams with high forest cover (>70% in their catchments maintained flow through the year. Streams draining more disturbed catchments exhibited reduced or no flow for 4 − 6 months during the dry season. Nitrate concentrations were lower at streams draining forested catchments while highest concentrations were measured where conventional agriculture covered a high proportion of the catchment and riparian zone. Highest phosphorus concentrations occurred at the catchment where poultry manure was applied as fertilizer. Differences between forest streams and those draining disturbed areas were correlated with the proportion of forest and agriculture in the riparian zone. Variation in stream variables among sampling dates was lower at the forest sites than at the more disturbed study streams. Conversion of forest into agriculture and urban areas is affecting flow regime and increasing nutrient concentrations, although the magnitude of the impacts are influenced by the type of agricultural practices and the alteration of the riparian zone.

  3. Effects of golf course construction and operation on water chemistry of headwater streams on the Precambrian Shield

    International Nuclear Information System (INIS)

    Winter, Jennifer G.; Dillon, Peter J.

    2005-01-01

    To investigate the effects of golf course construction and operation on the water chemistry of Shield streams, we compared the water chemistry in streams draining golf courses under construction (2) and in operation (5) to streams in forested reference locations and to upstream sites where available. Streams were more alkaline and higher in base cation and nitrate concentrations downstream of operational golf courses. Levels of these parameters and total phosphorus increased over time in several streams during golf course construction through to operation. There was evidence of inputs of mercury to streams on two of the operational courses. Nutrient (phosphorus and nitrogen) concentrations were significantly related to the area of unmanaged vegetation in a 30 x 30 m area on either side of the sampling sites, and to River Bank Quality Index scores, suggesting that maintaining vegetated buffers along the stream on golf courses will reduce in-stream nutrient concentrations. - Golf course construction and operation had a significant impact on alkalinity, nitrogen and base cation concentrations of streams

  4. Featured collection introduction: Connectivity of streams and wetlands to downstream waters

    Science.gov (United States)

    Alexander, Laurie C.; Fritz, Ken M.; Schofield, Kate; Autrey, Bradley; DeMeester, Julie; Golden, Heather E.; Goodrich, David C.; Kepner, William G.; Kiperwas, Hadas R.; Lane, Charles R.; LeDuc, Stephen D.; Leibowitz, Scott; McManus, Michael G.; Pollard, Amina I.; Ridley, Caroline E.; Vanderhoof, Melanie; Wigington, Parker J.

    2018-01-01

    Connectivity is a fundamental but highly dynamic property of watersheds. Variability in the types and degrees of aquatic ecosystem connectivity presents challenges for researchers and managers seeking to accurately quantify its effects on critical hydrologic, biogeochemical, and biological processes. However, protecting natural gradients of connectivity is key to protecting the range of ecosystem services that aquatic ecosystems provide. In this featured collection, we review the available evidence on connections and functions by which streams and wetlands affect the integrity of downstream waters such as large rivers, lakes, reservoirs, and estuaries. The reviews in this collection focus on the types of waters whose protections under the U.S. Clean Water Act have been called into question by U.S. Supreme Court cases. We synthesize 40+ years of research on longitudinal, lateral, and vertical fluxes of energy, material, and biota between aquatic ecosystems included within the Act's frame of reference. Many questions about the roles of streams and wetlands in sustaining downstream water integrity can be answered from currently available literature, and emerging research is rapidly closing data gaps with exciting new insights into aquatic connectivity and function at local, watershed, and regional scales. Synthesis of foundational and emerging research is needed to support science‐based efforts to provide safe, reliable sources of fresh water for present and future generations.

  5. Potential toxic elements in stream sediments, soils and waters in an abandoned radium mine (central Portugal).

    Science.gov (United States)

    Antunes, I M H R; Neiva, A M R; Albuquerque, M T D; Carvalho, P C S; Santos, A C T; Cunha, Pedro P

    2018-02-01

    The Alto da Várzea radium mine (AV) exploited ore and U-bearing minerals, such as autunite and torbernite. The mine was exploited underground from 1911 to 1922, closed in 1946 without restoration, and actually a commercial area is deployed. Stream sediments, soils and water samples were collected between 2008 and 2009. Stream sediments are mainly contaminated in As, Th, U and W, which is related to the AV radium mine. The PTEs, As, Co, Cr, Sr, Th, U, W, Zn, and electrical conductivity reached the highest values in soils collected inside the mine influence. Soils are contaminated with As and U and must not be used for any purpose. Most waters have pH values ranging from 4.3 to 6.8 and are poorly mineralized (EC = 41-186 µS/cm; TDS = 33-172 mg/L). Groundwater contains the highest Cu, Cr and Pb contents. Arsenic occurs predominantly as H 2 (AsO 4 ) - and H(AsO 4 ) 2- . Waters are saturated in goethite, haematite and some of them also in lepidocrocite and ferrihydrite, which adsorbs As (V). Lead is divalent in waters collected during the warm season, being mobile in these waters. Thorium occurs mainly as Th(OH) 3 (CO 3 ) - , Th(OH) 2 (CO 3 ) and Th(OH) 2 (CO 3 ) 2 2- , which increase water Th contents. Uranium occurs predominantly as UO 2 CO 3 , but CaUO 2 (CO 3 ) 3 2- and CaUO 2 (CO 3 ) 3 also occur, decreasing its mobility in water. The waters are contaminated in NO 2 - , Mn, Cu, As, Pb and U and must not be used for human consumption and in agricultural activities. The water contamination is mainly associated with the old radium mine and human activities. A restoration of the mining area with PTE monitoring is necessary to avoid a public hazard.

  6. Environmental effects of produced water from offshore petroleum industry

    International Nuclear Information System (INIS)

    Riksheim, H.; Johnsen, S.

    1993-01-01

    Mathematical models describing the fate and distribution of the discharged produced water are available for both the Statfjord and Gullfaks field. However, the value of these models are very limited if its predicted results cannot be verified by measurements of the actual results. An approach to this problem was made by sampling of water from locations in the vicinity of the discharge points at one of the oil producing platforms at the Statfjord and Gullfaks fields. Samples were collected at levels 5m below surface at locations 10m, 100m and 500m downstream of the discharge points, and at a reference site located midway between the fields. The concentrations of total hydrocarbon content, aromatic hydrocarbons, phenols and a number of heavy metals were determined in all samples. Increased levels of several of the analyzed parameters were detected at the innermost locations at both fields, compared to the distant locations and the natural background levels. At the Statfjord field increased levels of phenols and PAH were also observed at the locations 100 m and 500 m away from the discharge point. The results showed that dilution factors of 1:1000 and higher were found for the innermost locations, while the dilution models predicted a primary dilution of 1:30--1:50 within a distance of 100 m away from the platforms

  7. Biotreatment of produced waters for volume reduction and contaminant removal

    Energy Technology Data Exchange (ETDEWEB)

    Negri, M.C.; Hinchman, R.R. [Argonne National Lab., IL (United States); Mollock, J. [Devon Energy Corp., Oklahoma City, OK (United States)

    1997-10-01

    Produced water is wastewater that is brought to the surface from natural gas wells during natural gas production. Its constituents, mostly salt, with traces of hydrocarbons and heavy metals, are a significant disposal problem. Argonne National Laboratory (ANL), in partnership with the Gas Research Institute (GRI), has developed a low-cost, low-tech method, in which green plants are used to reduce the volume of produced water. The authors have designed an engineered bioreactor system, which is modeled after natural saline wetland ecosystems. The plant bioreactor system maximizes plant evapotranspiration to reduce wastewater volume and, concurrently, may function as a biological filter to enhance contaminant degradation and immobilization in the root/rhizosphere zone. Halophyte plant species having high salt tolerance and high transpiration rates were selected after they tested them in greenhouse experiments. Models obtained by using their greenhouse findings reduced the volume of the wastewater (up to 6% salt) by 75% in about 8 days. A field demonstration of the bioreactor, designed on the basis of the results from the greenhouse study, is successfully under way at a natural gas well site in Oklahoma. The process could offer the petroleum industry a low-cost biological alternative to existing expensive options.

  8. Distribution Channel Intensity among Table Water Producers in Nigeria

    Directory of Open Access Journals (Sweden)

    Joseph Edewor Agbadudu

    2017-09-01

    Full Text Available Planning for and making reasonable decisions regarding reaching the target market with an organization’s product is a critical task on the part of management, which involves a careful evaluation and selection of its channel structure and intensity.This study therefore examines distribution channel intensity among table water producers in Edo State, Nigeria. The focus of the study is to ascertain the variables that significantly predict distribution intensity among the firms in the table water industry in Edo State. The study seeks to proffer answer to fundamental question of why brands within a single category of a given consumer good differ significantly in their distribution intensity. Using a survey research design, the data used for this study were obtained by taking a sample of 110 table water firms within the three senatorial districts in the State. The data obtained were presented and analyzed using different statistical tools such as mean and multiple regression through Statistical Packages for Social Sciences (SPSS version 22 software. Findings revealed that manufacturers’ target focus, manufacturers’ support program, brand quality and level of firm’s technological advancement were significant predictors of distribution channel intensity among the industrial players in table water industry in the State. Based on the findings, the study recommended that table water firms within the State can secure a competitive edge over their fellow counterpart in the industry by designing an optimal distribution intensity that will meet up their marketing objectives. It is also recommended that the adoption of modern technology in form of online sales is an efficient way of sales and distribution which could be used to enhance their distribution techniques if there is a need to cut down on middle men due to increased cost. The study concluded that optimal distribution intensity could be achieved not by mere imitation of competitors but through

  9. Environmental impact of coal ash on tributary streams and nearshore water or Lake Erie. Final report

    Energy Technology Data Exchange (ETDEWEB)

    Wood, K.G.

    1978-08-01

    The environmental impact of coal ash disposal at a landfill site in north-central Chautauqua County, New York was studied from June 1975 through July 1977. Water samples taken from wells, ponds, and streams at 67 sites were analyzed for specific conductance, pH, alkalinity, arsenic, calcium, cadmium, chloride, chromium, copper, iron, magnesium, manganese, potassium, selenium, sodium, sulfate and zinc. Evidence suggests that ponds at the landfill were high in Ca, Fe, Mg, Mn, and SO/sub 4/ compared to control pands. A stream adjacent to the site contained greater Mn (207 ug/1) and SO/sub 4/ (229 ppm) than control streams. Shallow alkaline test wells in the landfill had elevated As, Ca, and Se. Acid-neutral test wells had elevated As, Ca, Cr, Mg and Mn. Household wells in the vicinity of the landfill showed no evident contamination from the landfill. Average iron concentrations in the biota were tripled, and manganese concentrations doubled in biota affected by the coal ash dump. However, any effects of the disposal area on the distribution of the biota could not be separated from effects of varying environment factors such as water movements, substrate composition and food availability. No harmful effects could be demonstrated on the biota in the creek which flowed past the disposal area.

  10. The effect of beaver ponds on water quality in rural coastal plain streams

    Science.gov (United States)

    Bason, Christopher W.; Kroes, Daniel; Brinson, Mark M.

    2017-01-01

    We compared water-quality effects of 13 beaver ponds on adjacent free-flowing control reaches in the Coastal Plain of rural North Carolina. We measured concentrations of nitrate, ammonium, soluble reactive phosphorus (SRP), and suspended sediment (SS) upstream and downstream of paired ponds and control reaches. Nitrate and SS concentrations decreased, ammonium concentrations increased, and SRP concentrations were unaffected downstream of the ponds and relative to the control reaches. The pond effect on nitrate concentration was a reduction of 112 ± 55 μg-N/L (19%) compared to a control-reach—influenced reduction of 28 ± 17 μg-N/L. The pond effect on ammonium concentration was an increase of 9.47 ± 10.9 μg-N/L (59%) compared to the control-reach—influenced reduction of 1.49 ± 1.37 μg-N/L. The pond effect on SS concentration was a decrease of 3.41 ± 1.68 mg/L (40%) compared to a control-reach—influenced increase of 0.56 ± 0.27 mg/L. Ponds on lower-order streams reduced nitrate concentrations by greater amounts compared to those in higher-order streams. Older ponds reduced SS concentrations by greater amounts compared to younger ponds. The findings of this study indicate that beaver ponds provide water-quality benefits to rural Coastal Plain streams by reducing concentrations of nitrate and suspended sediment.

  11. Changing Groundwater-Surface Water Interactions Impact Stream Chemistry and Ecology at the Arctic-Boreal Transition in Western Alaska

    Science.gov (United States)

    Koch, J. C.; Carey, M.; O'Donnell, J.; Sjoberg, Y.; Zimmerman, C. E.

    2016-12-01

    The arctic-boreal transition zone of Alaska is experiencing rapid change related to unprecedented warming and subsequent loss of permafrost. These changes in turn may affect groundwater-surface water (GW-SW) interactions, biogeochemical cycling, and ecosystem processes. While recent field and modeling studies have improved our understanding of hydrology in watersheds underlain by thawing permafrost, little is known about how these hydrologic shifts will impact bottom-up controls on stream food webs. To address this uncertainty, we are using an integrative experimental design to link GW-SW interactions to stream biogeochemistry and biota in 10 first-order streams in northwest Alaska. These study streams drain watersheds that span several gradients, including elevation, aspect, and vegetation (tundra vs. forest). We have developed a robust, multi-disciplinary data set to characterize GW-SW interactions and to mechanistically link GW-SW dynamics to water quality and the stream ecosystem. Data includes soil hydrology and chemistry; stream discharge, temperature, and inflow rates; water chemistry (including water isotopes, major ions, carbon concentration and isotopes, nutrients and chlorophyll-a), and invertebrate and fish communities. Stream recession curves indicate a decreasing rate later in the summer in some streams, consistent with seasonal thaw in lower elevation and south-facing catchments. Base cation and water isotope chemistry display similar impacts of seasonal thaw and also suggest the dominance of groundwater in many streams. Coupled with estimates of GW-SW exchange at point, reach, and catchment scales, these results will be used to predict how hydrology and water quality are likely to impact fish habitat and growth given continued warming at the arctic-boreal transition.

  12. Effects of land use change on streamflow and stream water quality of a coastal catchment

    CSIR Research Space (South Africa)

    Petersen, Chantel R

    2017-01-01

    Full Text Available Main stream length (km) 28.4 19.46 Main stream slope (%) 3.4 2.6 Drainage density (km/km2) 2.51 3.59 Length of overland flow (km) 0.19 0.139   Figure 1    Figure 1 Catchments of the Touws and Duiwe Rivers 141 http://dx.doi.org/10.4314/wsa.v43i1... catchment throughout the period examined (Fig. 2a, Table 3), as the natural forest areas were formally protected from the 142 http://dx.doi.org/10.4314/wsa.v43i1.16 Available on website http://www.wrc.org.za ISSN 1816-7950 (Online) = Water SA Vol. 43 No. 1...

  13. A method for producing a water and coal suspension

    Energy Technology Data Exchange (ETDEWEB)

    Mutase, T.; Khongo, T.; Minemura, N.; Nakai, S.; Ogura, K.; Savada, M.

    1983-08-30

    Coal dust (100 parts with a 95 to 99 percent content of particles with a size of 7 to 150 micrometers) is loaded into a mixture of hydrocarbon oil (1 to 20 parts) and water (300 to 1,000 parts) and mixed for 3 to 5 minutes at a rotation frequency of 1,800 to 1,500 per minute. The agglomerates of the coal dust and hydrocarbon (Uv) (100 parts) produced in this manner are then mixed with water (25 to 60 parts), an anion surfacant (PAV) (from 0.1 to 2 parts) which has high dispersion activity and a nonionogenic surfacant (0.1 to 2 parts) which has an HLB indicator of from 7 to 17 (preferably 13) to ensure a high consistency of the aqueous suspension of high quality coal, characterized by high fluidity (dynamic viscosity from 0.5 to 1.4 pascals times seconds). It is preferable to use a heavy oil fraction, kerosene, residue from oil distillation or an anthracite coal resin as the hydrocarbon oil. Separation of the ash from the suspension is increased by adding the surfacants and a water soluble inorganic salt which provides for an alkalinity of the aqueous solution (a pH of 7). It is recommended that a salt of alkylbenzolsulfo acid, a sodium salt of polyoxyethylenalkylphenolsulfo acid, sodium laurylsulfate, ammonium lauryl sulfate polyoxyethylensorbitantristearate, polyoxyethylenlaurylic acid, polyoxyethylennonylphenol ether or polyoxyethyllauric ether be used as the surfacant.

  14. Ecosystem effects from produced water and potash mine disposal activities

    International Nuclear Information System (INIS)

    Roy, R.; Davis, D.; Hopkins, S.

    1993-01-01

    This study was initiated to determine the chemical, physical, and ecosystem effects of produced water and potash mine disposal practices upon naturally occurring-hypersaline playas in southeast New Mexico, Several playas that receive discharges were compared to several nearby reference playas. Results revealed that the treatment playas had been significantly altered when compared to the reference playas. For example, the salinity of treatment playas were greater than 300 per-thousand and those of reference playas were less than 200 per-thousand. The dominant ions in water and sediments of treatment playas were sodium and chloride. The major ions in reference playa water and sediments were sodium, calcium, chloride, and sulfate. In some instances aromatic hydrocarbon concentrations exceeded 13,000 ng/g in sediments from treatment playas. Aromatic hydrocarbon concentrations were less than 100 ng/g in sediments from reference playas. Surveys revealed that treatment playas supported few, if any, invertebrates. On the other hand, reference playas supported dense populations of brine shrimp Artemis and brine fly Hydropyrus larvae. Surveys also indicated that reference playas were used by shorebirds for nesting and feeding, whereas treatment playas were used as loafing areas by waterfowl. Unfortunately, dead waterfowl were found along the shores of several treatment playas. Necropsies revealed that the most likely cause of death was salt toxicosis

  15. Tightening water quality regulations produces an innovative separation technology

    International Nuclear Information System (INIS)

    Welther, P.B.; Broussard, P.C.

    1994-01-01

    The impact of the recent proposed changes in the water quality standards for offshore producing platforms is having a far reaching effect on the oil and gas industry. At a time when oil companies are cutting back their work forces and reducing capital outlays in order to stay competitive in the market, water treatment equipment manufacturing companies are aggressively seeking innovative and cost effective solutions to meet the environmental requirements. Necessity drives advancements in technology, so Monosep Corporation has accepted the challenge to improve induced gas flotation technology and to develop enhanced gravity separation. This system of improved gas flotation and enhanced gravity separation can be used to consistently meet the proposed new guideline of an ''oil and grease'' maximum monthly average of 29 mg/l (milligrams per liter) in the discharged water from offshore platforms. The results demonstrated in the field suggest that adding enhanced gravity separation upstream of existing gas flotation units can improve performance sufficient to meet the Proposed stricter discharge limits. For platforms that do not have efficient gas flotation units, the old units can be replaced or modified to include the new features improved gas flotation technology like the Veirsep. For those few platforms are having difficulty meeting the current discharge requirements, both a new improved gas flotation unit, as well as a more sophisticated upstream gravity separator like the Cyclosep, may need to be installed. Chemical additives are sometimes a required necessity, but must be used sparingly due to the potential for creating soluble oil problems

  16. Using coal mine saline water to produce chlorine

    Energy Technology Data Exchange (ETDEWEB)

    Gnot, W; Turek, M; Walburg, Z

    1979-01-01

    Utilizing hard coal mine waters with salt concentration reaching 140 kg/mat3 in the chemical industry would significantly reduce the cost of protecting the natural environment from salt. The Institute of Chemistry and Inorganic Technology of the Silesian Technical University in Gliwice developed an efficient technology of producing chorine from underground black coal mine waters. A scheme of the technology is explained: double stage brine purification with magnesium hydroxide as by-product. During the first stage magnesium is precipitated using sodium hydroxide; after increasing salt content in the brine calcium and a low percentage of magnesium are removed by lye-sodium method. During the second stage sedimentation rate increases to 1.4 mm/s, and volume of sludge is only 1%. Magnesium hydroxide is removed using a method patented in Poland (after adding a flocculant magnesium hydroxide is left untouched). Only at a later stage does sedimentation occur. The proposed technology of utilizing mine water will be tested in an experimental plant which will be built at the Ziemowit black coal mine. (7 refs.) (In Polish)

  17. Experimental study of simulant melt stream-water thermal interaction in pool and narrow geometries

    International Nuclear Information System (INIS)

    Narayanan, K.S.; Jasmin Sudha, A.; Murthy, S.S.; Rao, E.H.V.M.; Lydia, G.; Das, S.K.; Harvey, J.; Kannan, S.E.

    2005-01-01

    Full text of publication follows: Small scale experiments were carried out to investigate the thermal interaction characteristics of a few kilograms of Sn Pb, Bi and Zn as hot melt, in the film boiling region of water in an attempt to simulate a coherent fuel coolant interaction during a postulated severe accident in a nuclear reactor. Melt stream solidification and detached debris generation were studied with different melt superheat up to 200 deg. C, at different coolant temperatures of 30 deg. C, 50 deg. C, 70 deg. C, 90 deg. C, in pool geometry and in long narrow coolant column. The material was heated in an Alumina crucible and poured through a hot stainless steel funnel with a nozzle diameter of 7.7 mm, into the coolant. A stainless steel plate was used to collect the solidified mass after the interaction. Temperature monitoring was done in the coolant column close to the melt stream. The melt stream movement inside the coolant was imaged using a video camera at 25 fps. Measured melt stream entry velocity was around 1.5 m/sec. For low melt superheat and low coolant temperature, solidified porous tree like structure extended from the collector plate up to the melt release point. For water temperature of 70 deg. C, the solidified bed height at the center was found to decrease with increase in the melt superheat up to 150 deg. C. Fragmentation was found to occur when the melt superheat exceeded 200 deg. C. Particle size distribution was obtained for the fragmented debris. In 1D geometry, with 50 deg. C superheat, columnar solidification was observed with no fine debris. The paper gives the details of the results obtained in the experiments and highlights the role of Rayleigh-Taylor, Kelvin-Helmholtz instabilities and the melt physical properties on the fragmentation kinetics. (authors)

  18. Forested wetland mitigation resulting from discharges of cooling water into streams

    International Nuclear Information System (INIS)

    Nelson, E.A.

    1993-01-01

    The Savannah River Swamp is a 3020-ha forested wetland on the floodplain of the Savannah River and is located on the US Department of Energy's Savannah River Site (SRS) near Aiken, South Carolina. Historically, the swamp consisted of ∼50% bald cypress-water tupelo stands, 40% mixed bottomland hardwood stands, and 10% shrub, marsh, and open water. The hydrology was controlled by flooding the Savannah River and by flow from four creeks that drain into the swamp prior to flow into the Savannah River. Upstream dams have caused some alteration of the water levels and timing of flooding within the floodplain. Major impacts to the swamp hydrology occurred with the completion of the production reactors and one coal-fired powerhouse at the SRS in the early 1950s. Water, often in excess of 40 to 50 degrees C was discharged into one of the small streams from 1954 to 1988, at various levels, ranging from 20 to 40 times the prior flow rate of the stream. This had a major impact on the adjacent swamp land, with erosion, silting, and vegetation destruction. The Final Environmental Impact Statement, Continued Operation of K, L, and P Reactors, Savannah River Site, Aiken, South Carolina, and the subsequent record of decision directed that these areas be restored to functional forested wetland status to the extent possible. This paper describes work begun to reach that objective

  19. Treatment of the oily produced water (OPW using coagulant mixtures

    Directory of Open Access Journals (Sweden)

    R. Hosny

    2016-09-01

    Full Text Available Treatment of the oily produced water (OPW before injection into oil reservoirs is necessary to reduce formation damage. This can be done using chemo-physical process to minimize the oil droplets in water. In this respect, this work aims to extract natural polymer (chitosan from shrimp shells and mix it with coagulants (chitosan/carboxy methyl cellulose and chitosan/aluminum sulfate to adsorb oil from OPW. Adsorption experiments were carried out in batch mode firstly to choose the best coagulants in water treatment, also to investigate the effects of pH on the adsorption uptake, adsorbent dosage, coagulant mixture doses and contact time. It was found that the oil removal by chitosan reached 96.35% and 59% at pH = 4 and pH = 9, respectively. The ability of chitosan to remove oil was increased after adding different coagulants CMC/or aluminum sulfate at average mixing time between 30 and 60 min. It was also found that the highest removal efficiency of chitosan/CMC is 99% at (90% chitosan: 10% CMC and chitosan/Al2(SO43 is 85% at (80% chitosan: 20% Al2(SO43. The SEM photographs of chitosan, chitosan/CMC and chitosan/Al2(SO43 mixture as oil removal showed that chitosan/Al2(SO43 lies between chitosan alone and chitosan/CMC mixture. Generally chitosan/CMC characterized significantly by its high ability to adsorb petroleum oil and suspended solids from OPW, additionally, reduces the economic cost of water treatment.

  20. Modernized approach for the remediation of produced water impacted sites

    Energy Technology Data Exchange (ETDEWEB)

    Knafla, A.; Carey, J. [Equilibrium Environmental Inc., Calgary, AB (Canada); Stokes, D. [Talisman Energy Inc., Calgary, AB (Canada); Carey, J.; Sunita, R.

    2007-10-01

    This article described a project conducted to remediate a site in southeast Saskatchewan polluted by releases of produced water-related salts and boron during the 1960s. A risk assessment was conducted to define endpoints based on equivalent land capability and the potential for health risks. Multiple toxic stressors complicated the assessment, and limited published data were available regarding cumulative and interactive effects. Boron concentrations exceeded recommended guidelines, and the poor permeability of surface soils caused reduced infiltration and increased run-off. An automated pumping system was designed to allow for variable leachate removal rates depending on groundwater elevations. A distillation system using moderately saline water from a nearby source was designed to offset scaling that occurred due to high calcium sulfate concentrations. Results of the project suggested that the combination of groundwater control, improving surface soil permeability, establishing plant growth, and available water for infiltration resulted in significant improvements in soil quality and an approach towards land capability endpoints. The use of moderately saline irrigation water led to significant improvements in the soil salinity of heavily impacted areas. Test plots were then formed to test the efficacy of manure and calcium nitrate as a remediation technique. Test plots were treated with Roundup, and calcium nitrate before seeding, or with manure and calcium nitrate followed by rototilling and seeding. In treated plots, plant growth was observed for barley, alkali grass, wheatgrasses, orchard grass, rye, and alfalfa. Greater plant height and yield was visible in the manure and calcium nitrate treated plots. A decrease in boron topsoil concentrations was also observed. Average bioconcentration factors was calculated as 29.5. It was concluded that the method can provide a 20 per cent annual soil concentration reduction rate. 6 figs.

  1. 77 FR 74985 - Water Quality Standards for the State of Florida's Streams and Downstream Protection Values for...

    Science.gov (United States)

    2012-12-18

    ... Water Quality Standards for the State of Florida's Streams and Downstream Protection Values for Lakes... its numeric water quality standards for nutrients in Florida that were promulgated and published on.... Water Quality Criteria D. EPA Determination Regarding Florida and EPA's Rulemaking E. EPA Promulgation...

  2. Water-quality trends for a stream draining the Southern Anthracite Field, Pennsylvania

    Science.gov (United States)

    Cravotta, C.A.; Bilger, Michael D.

    2001-01-01

    Stream flow, chemical and biological data for the northern part of Swatara Creek, which drains a 112 km2 area in the Southern Anthracite Field of eastern Pennsylvania, indicate progressive improvement in water quality since 1959, after which most mines in the watershed had been flooded. Drainage from the flooded mines contributes substantially to base flow in Swatara Creek. Beginning in 1995, a variety of treatment systems and surface reclamation were implemented at some of the abandoned mines. At Ravine, Pa., immediately downstream of the mined area, median SO4 concentration declined from about 150 mg l-1 in 1959 to 75 mg l-1 in 1999 while pH increased from acidic to near-neutral values (medians: c. pH 4 before 1975; c. pH 6 after 1975). Fish populations rebounded from non-existent during 1959-1990 to 21 species identified in 1999. Nevertheless, recent monitoring indicates (1) episodic acidification and elevated concentrations and transport of Fe, Al, Mn, and trace metals during storm flow; (2) elevated concentrations of Fe, Mn, Co, Cu, Pb, Ni, and Zn in streambed sediments relative to unmined areas and to toxicity guidelines for aquatic invertebrates and fish; and (3) elevated concentrations of metals in fish tissue, notably Zn. The metals are ubiquitous in the fine fraction (mining-affected tributaries and the main stem of Swatara Creek. As a result of scour and transport of streambed deposits, concentrations of suspended solids and total metals in the water column are correlated, and those for storm flow typically exceed base flow. Nevertheless, the metals concentrations are poorly correlated with stream flow because concentrations of suspended solids and total metals typically peak prior to peak stream stage. In contrast, SO4, specific conductance and pH are inversely correlated with stream flow as a result of dilution of poorly buffered stream water with weakly acidic storm runoff derived mainly from low-pH rainfall. Declines in pH to values approaching 5

  3. Water-quality trends for a stream draining the Southern Anthracite Field, Pennsylvania

    Science.gov (United States)

    Cravotta, C.A.; Bilger, Michael D.

    2001-01-01

    Stream flow, chemical and biological data for the northern part of Swatara Creek, which drains a 112 km2 area in the Southern Anthracite Field of eastern Pennsylvania, indicate progressive improvement in water quality since 1959, after which most mines in the watershed had been flooded. Drainage from the flooded mines contributes substantially to base flow in Swatara Creek. Beginning in 1995, a variety of treatment systems and surface reclamation were implemented at some of the abandoned mines. At Ravine, Pa., immediately downstream of the mined area, median SO4 concentration declined from about 150 mg l-1 in 1959 to 75 mg l-1 in 1999 while pH increased from acidic to near-neutral values (medians: c. pH 4 before 1975; c. pH 6 after 1975). Fish populations rebounded from non-existent during 1959-1990 to 21 species identified in 1999. Nevertheless, recent monitoring indicates (1) episodic acidification and elevated concentrations and transport of Fe, Al, Mn, and trace metals during storm flow; (2) elevated concentrations of Fe, Mn, Co, Cu, Pb, Ni, and Zn in streambed sediments relative to unmined areas and to toxicity guidelines for aquatic invertebrates and fish; and (3) elevated concentrations of metals in fish tissue, notably Zn. The metals are ubiquitous in the fine fraction (water column are correlated, and those for storm flow typically exceed base flow. Nevertheless, the metals concentrations are poorly correlated with stream flow because concentrations of suspended solids and total metals typically peak prior to peak stream stage. In contrast, SO4, specific conductance and pH are inversely correlated with stream flow as a result of dilution of poorly buffered stream water with weakly acidic storm runoff derived mainly from low-pH rainfall. Declines in pH to values approaching 5.0 during storm flow events or declines in redox potential during burial of sediment could result in the remobilization of metals associated with suspended solids and streambed deposits.

  4. MODIFIED REVERSE OSMOSIS SYSTEM FOR TREATMENT OF PRODUCED WATERS

    Energy Technology Data Exchange (ETDEWEB)

    Robert L. Lee; Junghan Dong

    2004-06-03

    This final report of ''Modified Reverse Osmosis System for Treatment of Produced Water,'' DOE project No. DE-FC26-00BC15326 describes work performed in the third year of the project. Several good results were obtained, which are documented in this report. The compacted bentonite membranes were replaced by supported bentonite membranes, which exhibited the same salt rejection capability. Unfortunately, it also inherited the clay expansion problem due to water invasion into the interlayer spaces of the compacted bentonite membranes. We noted that the supported bentonite membrane developed in the project was the first of its kind reported in the literature. An {alpha}-alumina-supported MFI-type zeolite membrane synthesized by in-situ crystallization was fabricated and tested. Unlike the bentonite clay membranes, the zeolite membranes maintained stability and high salt rejection rate even for a highly saline solution. Actual produced brines from gas and oil fields were then tested. For gas fields producing brine, the 18,300 ppm TDS (total dissolved solids) in the produced brine was reduced to 3060 ppm, an 83.3% rejection rate of 15,240 ppm salt rejection. For oilfield brine, while the TDS was reduced from 181,600 ppm to 148,900 ppm, an 18% rejection rate of 32,700 ppm reduction, the zeolite membrane was stable. Preliminary results show the dissolved organics, mainly hydrocarbons, did not affect the salt rejection. However, the rejection of organics was inconclusive at this point. Finally, the by-product of this project, the {alpha}-alumina-supported Pt-Co/Na Y catalytic zeolite membrane was developed and demonstrated for overcoming the two-step limitation of nonoxidation methane (CH{sub 4}) conversion to higher hydrocarbons (C{sub 2+}) and hydrogen (H{sub 2}). Detailed experiments to obtain quantitative results of H{sub 2} generation for various conditions are now being conducted. Technology transfer efforts included five manuscripts submitted to

  5. Ecological Status of Rivers and Streams in Saxony (Germany According to the Water Framework Directive and Prospects of Improvement

    Directory of Open Access Journals (Sweden)

    Uwe Müller

    2012-11-01

    Full Text Available The Federal State of Saxony (Germany transposed the EU Water Framework Directive into state law, identifying 617 surface water bodies (rivers and streams for implementation of the water framework directive (WFD. Their ecological status was classified by biological quality elements (macrophytes and phytobenthos, benthic invertebrates and fish, and in large rivers, phytoplankton and specific synthetic and non-synthetic pollutants. Hydromorphological and physico-chemical quality elements were used to identify significant anthropogenic pressures, which surface water bodies are susceptible to, and to assess the effect of these pressures on the status of surface water bodies. In 2009, the data for classification of the ecological status and the main pressures and impacts on water bodies were published in the river basin management plans (RBMP of the Elbe and Oder rivers. To that date, only 23 (4% streams achieved an ecological status of “good”, while the rest failed to achieve the environmental objective. The two main reasons for the failure were significant alterations to the stream morphology (81% of all streams and nutrient enrichment (62% caused by point (industrial and municipal waste water treatment plants and non-point (surface run-off from arable fields, discharges from urban drainages and decentralized waste water treatment plants sources. It was anticipated that a further 55 streams would achieve the environmental objective by 2015, but the remaining 539 need extended deadlines.

  6. Are the streams of the Sinos River basin of good water quality? Aquatic macroinvertebrates may answer the question

    Directory of Open Access Journals (Sweden)

    L. Bieger

    Full Text Available Macroinvertebrate communities are one of the most used groups in assessments of water quality, since they respond directly to the level of contamination of aquatic ecosystems. The main objective of this study was the assessment of the water quality of the Sinos River basin (Rio Grande do Sul state, Brazil through biotic indices based on the macroinvertebrate community ("Family Biotic Index - FBI", and "Biological Monitoring Working Party Score System - BMWP". Three lower order streams (2nd order were selected in each one of three main regions of the basin. In each stream, the samplings were performed in three reaches (upper, middle, and lower, totalling 27 reaches. Two samplings were carried in each reach over one year (winter and summer. A total of 6,847 macroinvertebrates distributed among 54 families were sampled. The streams from the upper region were of better water quality than the lower region. The water quality did not change between the upper, middle and lower reaches of the streams. However, the upper reaches of the streams were of better water quality in all the regions of the basin. The water quality of the streams did not vary between the summer and the winter. This result demonstrated that water quality may be analysed in both studied seasons (summer and winter using biotic indices. The analysis of the results allows us to conclude that the biotic indices used reflected the changes related to the water quality along the longitudinal gradient of the basin. Thus, aquatic macroinvertebrates were important bioindicators of the water and environmental quality of the streams of the Sinos River basin.

  7. A hierarchical bayesian model to quantify uncertainty of stream water temperature forecasts.

    Directory of Open Access Journals (Sweden)

    Guillaume Bal

    Full Text Available Providing generic and cost effective modelling approaches to reconstruct and forecast freshwater temperature using predictors as air temperature and water discharge is a prerequisite to understanding ecological processes underlying the impact of water temperature and of global warming on continental aquatic ecosystems. Using air temperature as a simple linear predictor of water temperature can lead to significant bias in forecasts as it does not disentangle seasonality and long term trends in the signal. Here, we develop an alternative approach based on hierarchical Bayesian statistical time series modelling of water temperature, air temperature and water discharge using seasonal sinusoidal periodic signals and time varying means and amplitudes. Fitting and forecasting performances of this approach are compared with that of simple linear regression between water and air temperatures using i an emotive simulated example, ii application to three French coastal streams with contrasting bio-geographical conditions and sizes. The time series modelling approach better fit data and does not exhibit forecasting bias in long term trends contrary to the linear regression. This new model also allows for more accurate forecasts of water temperature than linear regression together with a fair assessment of the uncertainty around forecasting. Warming of water temperature forecast by our hierarchical Bayesian model was slower and more uncertain than that expected with the classical regression approach. These new forecasts are in a form that is readily usable in further ecological analyses and will allow weighting of outcomes from different scenarios to manage climate change impacts on freshwater wildlife.

  8. Insecticide toxicity to Hyalella curvispina in runoff and stream water within a soybean farm (Buenos Aires, Argentina).

    Science.gov (United States)

    Mugni, H; Ronco, A; Bonetto, C

    2011-03-01

    Toxicity to the locally dominant amphipod Hyalella curvispina was assessed in a first-order stream running through a cultivated farm. Cypermethrin, chlorpyrifos, endosulfan and glyphosate were sprayed throughout the studied period. Toxicity was assayed under controlled laboratory conditions with runoff and stream water samples taken from the field under steady state and flood conditions. Ephemeral toxicity pulses were observed as a consequence of farm pesticide applications. After pesticide application, runoff water showed 100% mortality to H. curvispina for 1 month, but no mortality thereafter. Toxicity persistence was shortest in stream water, intermediate in stream sediments and longest in soil samples. Runoff had a more important toxicity effect than the exposure to direct aerial fumigation. The regional environmental features determining fast toxicity dissipation are discussed. Copyright © 2010. Published by Elsevier Inc.

  9. Evaluating the impact of irrigation on surface water - groundwater interaction and stream temperature in an agricultural watershed.

    Science.gov (United States)

    Essaid, Hedeff I; Caldwell, Rodney R

    2017-12-01

    Changes in groundwater discharge to streams caused by irrigation practices can influence stream temperature. Observations along two currently flood-irrigated reaches in the 640-square-kilometer upper Smith River watershed, an important agricultural and recreational fishing area in west-central Montana, showed a downstream temperature decrease resulting from groundwater discharge to the stream. A watershed-scale coupled surface water and groundwater flow model was used to examine changes in streamflow, groundwater discharge to the stream and stream temperature resulting from irrigation practices. The upper Smith River watershed was used to develop the model framework including watershed climate, topography, hydrography, vegetation, soil properties and current irrigation practices. Model results were used to compare watershed streamflow, groundwater recharge, and groundwater discharge to the stream for three scenarios: natural, pre-irrigation conditions (PreIrr); current irrigation practices involving mainly stream diversion for flood and sprinkler irrigation (IrrCurrent); and a hypothetical scenario with only groundwater supplying sprinkler irrigation (IrrGW). Irrigation increased groundwater recharge relative to natural PreIrr conditions because not all applied water was removed by crop evapotranspiration. Groundwater storage and groundwater discharge to the stream increased relative to natural PreIrr conditions when the source of irrigation water was mainly stream diversion as in the IrrCurrent scenario. The hypothetical IrrGW scenario, in which groundwater withdrawals were the sole source of irrigation water, resulted in widespread lowering of the water table and associated decreases in groundwater storage and groundwater discharge to the stream. A mixing analysis using model predicted groundwater discharge along the reaches suggests that stream diversion and flood irrigation, represented in the IrrCurrent scenario, has led to cooling of stream temperatures

  10. Estimation of unaltered daily mean streamflow at ungaged streams of New York, excluding Long Island, water years 1961-2010

    Science.gov (United States)

    Gazoorian, Christopher L.

    2015-01-01

    The lakes, rivers, and streams of New York State provide an essential water resource for the State. The information provided by time series hydrologic data is essential to understanding ways to promote healthy instream ecology and to strengthen the scientific basis for sound water management decision making in New York. The U.S. Geological Survey, in cooperation with The Nature Conservancy and the New York State Energy Research and Development Authority, has developed the New York Streamflow Estimation Tool to estimate a daily mean hydrograph for the period from October 1, 1960, to September 30, 2010, at ungaged locations across the State. The New York Streamflow Estimation Tool produces a complete estimated daily mean time series from which daily flow statistics can be estimated. In addition, the New York Streamflow Estimation Tool provides a means for quantitative flow assessments at ungaged locations that can be used to address the objectives of the Clean Water Act—to restore and maintain the chemical, physical, and biological integrity of the Nation’s waters.

  11. Quantitative produced water analysis using mobile 1H NMR

    International Nuclear Information System (INIS)

    Wagner, Lisabeth; Fridjonsson, Einar O; May, Eric F; Stanwix, Paul L; Graham, Brendan F; Carroll, Matthew R J; Johns, Michael L; Kalli, Chris

    2016-01-01

    Measurement of oil contamination of produced water is required in the oil and gas industry to the (ppm) level prior to discharge in order to meet typical environmental legislative requirements. Here we present the use of compact, mobile 1 H nuclear magnetic resonance (NMR) spectroscopy, in combination with solid phase extraction (SPE), to meet this metrology need. The NMR hardware employed featured a sufficiently homogeneous magnetic field, such that chemical shift differences could be used to unambiguously differentiate, and hence quantitatively detect, the required oil and solvent NMR signals. A solvent system consisting of 1% v/v chloroform in tetrachloroethylene was deployed, this provided a comparable 1 H NMR signal intensity for the oil and the solvent (chloroform) and hence an internal reference 1 H signal from the chloroform resulting in the measurement being effectively self-calibrating. The measurement process was applied to water contaminated with hexane or crude oil over the range 1–30 ppm. The results were validated against known solubility limits as well as infrared analysis and gas chromatography. (paper)

  12. State of the art of produced water treatment.

    Science.gov (United States)

    Jiménez, S; Micó, M M; Arnaldos, M; Medina, F; Contreras, S

    2018-02-01

    Produced water (PW) is the wastewater generated when water from underground reservoirs is brought to the surface during oil or gas extraction. PW is generated in large amounts and has a complex composition, containing various toxic organic and inorganic compounds. PW is currently treated in conventional trains that include phase separators, decanters, cyclones and coarse filters in order to comply with existing regulation for discharge. These treatment trains do not achieve more restrictive limitations related to the reuse of the effluent (reinjection into extraction wells) or other beneficial uses (e.g., irrigation). Therefore, and to prevent environmental pollution, further polishing processes need to be carried out. Characterization of the PW to determine major constituents is the first step to select the optimum treatment for PW, coupled with environmental factors, economic considerations, and local regulatory framework. This review tries to provide an overview of different treatments that are being applied to polish this type of effluents. These technologies include membranes, physical, biological, thermal or chemical treatments, where special emphasis has been made on advanced oxidation processes due to the advantages offered by these processes. Commercial treatments, based on the combination, modification and improvement of simpler treatments, were also discussed. Copyright © 2017 Elsevier Ltd. All rights reserved.

  13. Numerical investigation on effect of blade shape for stream water wheel performance.

    Science.gov (United States)

    Yah, N. F.; Oumer, A. N.; Aziz, A. A.; Sahat, I. M.

    2018-04-01

    Stream water wheels are one of the oldest and commonly used types of wheels for the production of energy. Moreover, they are economical, efficient and sustainable. However, few amounts of research works are available in the open literature. This paper aims to develop numerical model for investigation of the effect of blade shape on the performance of stream water wheel. The numerical model was simulated using Computational Fluid Dynamics (CFD) method and the developed model was validated by comparing the simulation results with experimental data obtained from literature. The performance of straight, curved type 1 and curved type 2 was observed and the power generated by each blade design was identified. The inlet velocity was set to 0.3 m/s static pressure outlet. The obtained results indicate that the highest power was generated by the Curved type 2 compared to straight blade and curved type 1. From the CFD result, Curved type 1 was able to generate 0.073 Watt while Curved type 2 generate 0.064 Watt. The result obtained were consistent with the experiment result hence can be used the numerical model as a guide to numerically predict the water wheel performance

  14. Analysis of trace dicyandiamide in stream water using solid phase extraction and liquid chromatography UV spectrometry.

    Science.gov (United States)

    Qiu, Huidong; Sun, Dongdi; Gunatilake, Sameera R; She, Jinyan; Mlsna, Todd E

    2015-09-01

    An improved method for trace level quantification of dicyandiamide in stream water has been developed. This method includes sample pretreatment using solid phase extraction. The extraction procedure (including loading, washing, and eluting) used a flow rate of 1.0mL/min, and dicyandiamide was eluted with 20mL of a methanol/acetonitrile mixture (V/V=2:3), followed by pre-concentration using nitrogen evaporation and analysis with high performance liquid chromatography-ultraviolet spectroscopy (HPLC-UV). Sample extraction was carried out using a Waters Sep-Pak AC-2 Cartridge (with activated carbon). Separation was achieved on a ZIC(®)-Hydrophilic Interaction Liquid Chromatography (ZIC-HILIC) (50mm×2.1mm, 3.5μm) chromatography column and quantification was accomplished based on UV absorbance. A reliable linear relationship was obtained for the calibration curve using standard solutions (R(2)>0.999). Recoveries for dicyandiamide ranged from 84.6% to 96.8%, and the relative standard deviations (RSDs, n=3) were below 6.1% with a detection limit of 5.0ng/mL for stream water samples. Copyright © 2015. Published by Elsevier B.V.

  15. Reconciling agriculture and stream restoration in Europe: A review relating to the EU Water Framework Directive

    DEFF Research Database (Denmark)

    Flavio, Hugo; Ferreira, P.; Formigo, N.

    2017-01-01

    Agriculture is widespread across the EU and has caused considerable impacts on freshwater ecosystems. To revert the degradation caused to streams and rivers, research and restoration efforts have been developed to recover ecosystem functions and services, with the European Water Framework Directive.......g. stakeholder management, land use conflicts, climate change effects), which may play an important role in guiding future policy. Our recommendations are important for the second WFD cycle because they 1) help secure the development and dissemination of science-based restoration strategies and 2) provide...

  16. Heavy metal contamination of stream water and sediment in the Taejon area

    Energy Technology Data Exchange (ETDEWEB)

    Kim, Kyoung Woong [Paichai University, Taejon (Korea, Republic of); Lee, Hyun Koo [Chungnam National University, Taejon (Korea, Republic of)

    1996-08-31

    Associated with the rapid pace of overpopulation and industrialization is the increase of municipal and industrial wastewater and heavy metal contamination from these point sources have received much attention in the Taejon area. To reduce the environmental problems, 21 stream sediments from Gap-chun, Yudeung-chun, Yusung-chun and Keum river have been analyzed for Cd, Cu, Pb and Zn. The results show that heavy metal concentrations are high in sediments from the Sintanjin and Taehwa Industrial Complex area with particular reference to 1388 {mu}g/g Cu in the stream sediment of Yusung-chun. When the geochemical map drawn from the Kriging technique of these data are compared with the industrialization and urbanization index map, high concentrations of heavy metals are found in stream sediments in industrialized areas resulting from the accumulation of heavy metals from the polluting factories. Concentrations of Cu in sediments from the Taehwa Industrial Complex area and those of Zn in sediments from the Sintanjin Complex area higher than EPA standard in the U.S.A and may be the potential sources of pollution in Keum river with possible implications to human health. For the speciation of Cu, Pb and Zn, the high proportions of exchangeable phase of Cu and Zn in stream sediments indicate that the metals originate not from parent materials but from wastewater and exist as the adsorbed phase on the surface of sediments. These metals are easily dissolved into the water by the reaction and relative amounts of easily dissolved phase of metals are in the order of Cu = Zn > Pb. (author). 17 refs., 4 tabs., 7 figs.

  17. Review of research on impacts to biota of discharges of naturally occurring radionuclides in produced water to the marine environment

    International Nuclear Information System (INIS)

    Hosseini, Ali; Brown, Justin E.; Gwynn, Justin P.; Dowdall, Mark

    2012-01-01

    Produced water has been described as the largest volume waste stream in the exploration and production process of oil and gas. It is accompanied by discharges of naturally occurring radionuclides raising concerns over the potential radiological impacts of produced water on marine biota. In the Northern European marine environment, radioactivity in produced water has received substantial attention owing to the OSPAR Radioactive Substances Strategy which aims at achieving ‘concentrations in the environment near background values for naturally occurring radioactive substances’. This review provides an overview of published research on the impacts to biota from naturally occurring radionuclides discharged in produced water by the offshore oil and gas industry. In addition to summarising studies and data that deal directly with the issue of dose and effect, the review also considers studies related to the impact of added chemicals on the fate of discharged radionuclides. The review clearly illustrates that only a limited number of studies have investigated possible impacts on biota from naturally occurring radionuclides present in produced water. Hence, although these studies indicate that the risk to the environment from naturally occurring radionuclides discharged in produced water is negligible, the substantial uncertainties involved in the assessments of impact make it difficult to be conclusive. With regard to the complexity involved in the problem under consideration there is a pressing need to supplement existing data and acquire new knowledge. Finally, the present work identifies some knowledge gaps to indicate future research requirements. -- Highlights: ► Produced water from offshore oil industry contains naturally occurring radionuclides. ► Published research on the impacts to biota from these radionuclides is reviewed. ► Review includes impact of added chemicals on the fate of discharged radionuclides. ► Studies indicate negligible risk to biota

  18. A short report regarding the physicochemical properties of surface water quality in Karaçomak stream, Turkey

    Science.gov (United States)

    Şuţan, Nicoleta Anca; Mutlu, Ekrem; Yanik, Telat; Dobre, Raluca

    2016-04-01

    Within the scope of present study, the water quality of stream Karaçomak in Kastamonu-Turkey was investigated. Water samples were collected from 9 stations selected on Karaçomak stream, considering the pollution points and the points, where the entrance of water into stream is high. The samples taken were analyzed in terms of water temperature, pH, dissolved oxygen, saltiness, electrical conductivity, chemical composition and heavy metal content, and for their genotoxic and cytotoxic potential. Physicochemical evaluation indicated that all samples had heterogeneous intensity of environmental influence, but the considerable impact was noticed for the third and seventh stations. The present study highlights the need for continuous evaluation of water pollution level, and is intended to help in mitigating the environmental impacts and improve environmental performance.

  19. Energy and Exergy Analyses of a New Combined Cycle for Producing Electricity and Desalinated Water Using Geothermal Energy

    Directory of Open Access Journals (Sweden)

    Mehri Akbari

    2014-04-01

    Full Text Available A new combined cogeneration system for producing electrical power and pure water is proposed and analyzed from the viewpoints of thermodynamics and economics. The system uses geothermal energy as a heat source and consists of a Kalina cycle, a LiBr/H2O heat transformer and a water purification system. A parametric study is carried out in order to investigate the effects on system performance of the turbine inlet pressure and the evaporator exit temperature. For the proposed system, the first and second law efficiencies are found to be in the ranges of 16%–18.2% and 61.9%–69.1%, respectively. For a geothermal water stream with a mass flow rate of 89 kg/s and a temperature of 124 °C, the maximum production rate for pure water is found to be 0.367 kg/s.

  20. Don't Cry over Spilled Water: Identifying Risks and Solutions for Produced Water Spills

    Science.gov (United States)

    Shores, Amanda Rose

    Resource requirements and future energy generation requires careful evaluation, particularly due to climate change and water scarcity. This thesis discusses one aspect of energy generation linked to water; oil-and-gas extraction and the large volumes of waste water produced, otherwise known as "produced water". This research focuses on surface spills of produced water, their ramifications, safeguards against groundwater contamination at spill sites and potential remediation strategies. Produced water contains a variety of contaminants that include the group of known toxins, BTEX (benzene, toluene, ethylbenzene and xylene), and high salt concentrations. A combination of factors such as large volumes of generated produced water, the need for storage and transportation across large distances and the toxic-and-mobile nature of produced water constituents creates risks for spills that can pollute groundwater. Spills occur regularly, particularly in Weld County, Colorado, where the demand for natural gas is high. To answer spill-related hypotheses, a multitude of methodology were employed: modeling, greenhouse experimentation, gas chromatography and summarization of spill reports and statistical analyses. Using publically available spill data, this research found that the frequency of oil-and-gas related spills and the average spilled volume has increased in Weld County from 2011-2015. Additionally, the number of spills that have resulted in groundwater contamination has increased in the area. By focusing on the oil-and-gas operators responsible for these spills, a linear relationship was found between the volumes of oil-and-gas produced compared to the volumes of produced-water generated. However, larger oil-and-gas producers did not show a linear relationship between oil-and-gas produced and produced-water generated, such that larger producers were more efficient and generated less water per unit of energy. So while scale-up efficiency seems to exist for produced-water

  1. Incorporation of the equilibrium temperature approach in a Soil and Water Assessment Tool hydroclimatological stream temperature model

    Science.gov (United States)

    Du, Xinzhong; Shrestha, Narayan Kumar; Ficklin, Darren L.; Wang, Junye

    2018-04-01

    Stream temperature is an important indicator for biodiversity and sustainability in aquatic ecosystems. The stream temperature model currently in the Soil and Water Assessment Tool (SWAT) only considers the impact of air temperature on stream temperature, while the hydroclimatological stream temperature model developed within the SWAT model considers hydrology and the impact of air temperature in simulating the water-air heat transfer process. In this study, we modified the hydroclimatological model by including the equilibrium temperature approach to model heat transfer processes at the water-air interface, which reflects the influences of air temperature, solar radiation, wind speed and streamflow conditions on the heat transfer process. The thermal capacity of the streamflow is modeled by the variation of the stream water depth. An advantage of this equilibrium temperature model is the simple parameterization, with only two parameters added to model the heat transfer processes. The equilibrium temperature model proposed in this study is applied and tested in the Athabasca River basin (ARB) in Alberta, Canada. The model is calibrated and validated at five stations throughout different parts of the ARB, where close to monthly samplings of stream temperatures are available. The results indicate that the equilibrium temperature model proposed in this study provided better and more consistent performances for the different regions of the ARB with the values of the Nash-Sutcliffe Efficiency coefficient (NSE) greater than those of the original SWAT model and the hydroclimatological model. To test the model performance for different hydrological and environmental conditions, the equilibrium temperature model was also applied to the North Fork Tolt River Watershed in Washington, United States. The results indicate a reasonable simulation of stream temperature using the model proposed in this study, with minimum relative error values compared to the other two models

  2. Water Stream in Bidet Toilet Commode as a Cause of Anterior Anal Fissure: A Case-Control Study

    Directory of Open Access Journals (Sweden)

    Pankaj Garg

    2017-03-01

    Full Text Available Background Water used as a single sharp stream in toilet commode for post defecation cleansing is a common practice in several countries across the globe including India. Repeated hitting of the anus by water stream could potentially cause injury to the anal canal epithelium and lead to development of fissure-in-ano. As the water stream is emanating from the backside of the toilet commode, the possible injury, if any, would be on the anterior anal canal. Objectives The present study aimed at determining whether water stream usage in toilet commodes increased the incidence of anterior fissure-in-ano; this was determined by the incidence of anterior fissure-in-ano the study and control groups. Methods All consecutive fissure-in-ano patients referring to a colorectal clinic from February 2012 to 2015 were included in the study. The patients were classified as a study group (who were using water stream for cleansing purposes in toilet commodes and a control group (patients who were not using water stream. The characteristics and location (position of the fissure-in-ano was noted. Results In this study, 165 patients were prospectively enrolled. Male/female ratio was 96/69, and the mean age was 36.3 ± 11.2 years. The anterior fissure-in-ano in the study group was 55.9% (47/84, while it was 17.3 % (14/81 in the control group (P < 0.0001, odds ratio: 6.08, 95% CI: 2.96 - 12.47]. Conclusions Water used as a single sharp stream to cleanse after defecation in toilet commodes is hazardous and should be avoided.

  3. Decadal stream water quality trends under varying climate, land use, and hydrogeochemical setting in, Iowa, USA

    Science.gov (United States)

    Green, Christopher; Bekins, Barbara; Kalkhoff, Stephen; Hirsch, Robert; Liao, Lixia; Barnes, Kimberlee

    2015-04-01

    Understanding how nitrogen fluxes respond to changes in agricultural practices and climatic variations is important for improving water quality in agricultural settings. In the central United States, intensification of corn cropping in support of ethanol production led to increases in N application rates in the 2000s during a period including both extreme dry and wet conditions. To examine the effect of these recent changes, a study was conducted on surface water quality in 10 major Iowa Rivers. Long term (~20 to 30 years) water quality and flow data were analyzed with Weighted Regression on Time, Discharge and Season (WRTDS), a statistical method that provides internally consistent estimates of the concentration history and reveals decadal trends that are independent of random variations of stream flow from seasonal averages. Trends of surface water quality showed constant or decreasing flow-normalized concentrations of nitrate+nitrite-N from 2000 to 2012 in all basins. To evaluate effects of annual discharge and N loading on these trends, multiple conceptual models were developed and calibrated to annual concentrations. The recent declining concentration trends can be attributed to both very high and very low streamflow discharge in the 2000's and to the long (e.g. 8-year) subsurface residence times in some basins. Dilution of surface water nitrate and depletion of stored nitrate may occur in years with very high discharge. Limited transport of N to streams and accumulation of stored N may occur in years with very low discharge. Central Iowa basins showed the greatest reduction in concentrations, likely because extensive tile-drains limit the effective volumes for storage of N and reduce residence times, and because the glacial sediments in these basins promote denitrification. Changes in nitrogen fluxes resulting from ethanol production and other factors will likely be delayed for years or decades in peripheral basins of Iowa, and may be obscured in the central

  4. Lead uptake of water plants in water stream at Kiteezi landfill site ...

    African Journals Online (AJOL)

    user

    2Chemistry Laboratory, Uganda Industrial Research Institute, P. O. Box 7086, Kampala, Uganda. Received ... contain heavy metals which compromise water quality .... MATERIALS AND METHODS ... discharged out of the waste water treatment plant pipes. ... with deionized water twice and separated into shoots, stems and.

  5. Asteroid/meteorite streams

    Science.gov (United States)

    Drummond, J.

    The independent discovery of the same three streams (named alpha, beta, and gamma) among 139 Earth approaching asteroids and among 89 meteorite producing fireballs presents the possibility of matching specific meteorites to specific asteroids, or at least to asteroids in the same stream and, therefore, presumably of the same composition. Although perhaps of limited practical value, the three meteorites with known orbits are all ordinary chondrites. To identify, in general, the taxonomic type of the parent asteroid, however, would be of great scientific interest since these most abundant meteorite types cannot be unambiguously spectrally matched to an asteroid type. The H5 Pribram meteorite and asteroid 4486 (unclassified) are not part of a stream, but travel in fairly similar orbits. The LL5 Innisfree meteorite is orbitally similar to asteroid 1989DA (unclassified), and both are members of a fourth stream (delta) defined by five meteorite-dropping fireballs and this one asteroid. The H5 Lost City meteorite is orbitally similar to 1980AA (S type), which is a member of stream gamma defined by four asteroids and four fireballs. Another asteroid in this stream is classified as an S type, another is QU, and the fourth is unclassified. This stream suggests that ordinary chondrites should be associated with S (and/or Q) asteroids. Two of the known four V type asteroids belong to another stream, beta, defined by five asteroids and four meteorite-dropping (but unrecovered) fireballs, making it the most probable source of the eucrites. The final stream, alpha, defined by five asteroids and three fireballs is of unknown composition since no meteorites have been recovered and only one asteroid has an ambiguous classification of QRS. If this stream, or any other as yet undiscovered ones, were found to be composed of a more practical material (e.g., water or metalrich), then recovery of the associated meteorites would provide an opportunity for in-hand analysis of a potential

  6. Reconciling records of ice streaming and ice margin retreat to produce a palaeogeographic reconstruction of the deglaciation of the Laurentide Ice Sheet

    Science.gov (United States)

    Margold, Martin; Stokes, Chris R.; Clark, Chris D.

    2018-06-01

    This paper reconstructs the deglaciation of the Laurentide Ice Sheet (LIS; including the Innuitian Ice Sheet) from the Last Glacial Maximum (LGM), with a particular focus on the spatial and temporal variations in ice streaming and the associated changes in flow patterns and ice divides. We build on a recent inventory of Laurentide ice streams and use an existing ice margin chronology to produce the first detailed transient reconstruction of the ice stream drainage network in the LIS, which we depict in a series of palaeogeographic maps. Results show that the drainage network at the LGM was similar to modern-day Antarctica. The majority of the ice streams were marine terminating and topographically-controlled and many of these continued to function late into the deglaciation, until the ice sheet lost its marine margin. Ice streams with a terrestrial ice margin in the west and south were more transient and ice flow directions changed with the build-up, peak-phase and collapse of the Cordilleran-Laurentide ice saddle. The south-eastern marine margin in Atlantic Canada started to retreat relatively early and some of the ice streams in this region switched off at or shortly after the LGM. In contrast, the ice streams draining towards the north-western and north-eastern marine margins in the Beaufort Sea and in Baffin Bay appear to have remained stable throughout most of the Late Glacial, and some of them continued to function until after the Younger Dryas (YD). The YD influenced the dynamics of the deglaciation, but there remains uncertainty about the response of the ice sheet in several sectors. We tentatively ascribe the switching-on of some major ice streams during this period (e.g. M'Clintock Channel Ice Stream at the north-west margin), but for other large ice streams whose timing partially overlaps with the YD, the drivers are less clear and ice-dynamical processes, rather than effects of climate and surface mass balance are viewed as more likely drivers. Retreat

  7. Water quality assessment of the Eastern Iowa Basins: Basic water chemistry of rivers and streams, 1996-98

    Science.gov (United States)

    Barnes, Kimberlee K.

    2001-01-01

    The U.S. Geological Survey began data-collection activities in the Eastern Iowa Basins study unit of the National Water-Quality Assessment Program in September 1995 with the purpose of determining the status and trends in water quality of water from the Wapsipinicon, Cedar, Iowa, and Skunk River basins. From March 1996 through September 1998, monthly surface-water samples were collected from 11 sites on the study's rivers and streams representing three distinct physiographic regions, the Des Moines Lobe, the Iowan Surface, the Southern Iowa Drift Plain, and one subregion, the Iowan Karst. These water samples were analyzed for basic water chemistry, including, but not limited to the following cations: sodium, potassium, magnesium, calcium, and silica; anions: chloride, fluoride, sulfate, and bicarbonate; and two metals - iron and maganese. Although none of the concentrations of the constituents exceeded health advisories or drinking-water regulations, extremely high or low concentrations could potentially affect aquatic life. Calcium, magnesium, and potassium are essential elements for both plant and animal life; manganese is an essential element in plant metabolism; and silica is important in the growth of diatom algae. Calcium had the largest median concentration of 61 milligrams per liter (mg/L) of the cations, and the largest maximum concentration of 100 mg/L. Bicarbonate had the largest median concentration of 210 mg/L of the anions, and the largest maximum concentration of 400 mg/L.

  8. Long-term changes in the water quality of rainfall, cloud water and stream water for moorland, forested and clear-felled catchments at Plynlimon, mid-Wales

    Directory of Open Access Journals (Sweden)

    C. Neal

    2001-01-01

    Full Text Available Long term changes in the water quality of rainfall, cloud water and stream waters draining acidic and acid sensitive moorland and forested catchments at Plynlimon, mid-Wales, are examined for the period 1983 to 2001. Atmospheric inputs of chloride and sulphate are influenced by the relative inputs of clean maritime and polluted land based air masses. There is no systematic increase or decrease over time for chloride and non-sea-salt sulphate. Rather, there is a decadal scale process possibly representative of the influence of the North Atlantic Oscillation that affects the maritime and pollution climate of the Atlantic seaboard of the UK. Over 17 years of study, there may be a small decrease in non-sea-salt sulphate of about 10 μeq l-1 and a small improvement in acid neutralising capacity of about 20 to 30 μeq l-1 in rainfall. There is a clear improvement in cloud water chemistry with respect to pollutant components (ammonium, nitrate, non-sea-salt sulphate and acidity (acid neutralising capacity improved by about 300 μeq l-1 through the study period. Many of the changes in cloud water chemistry are similar to rainfall over the same period except the magnitude of change is larger for the cloud water. Within the streams, there is some evidence for reductions in acidity as reflected by acid neutralising capacity becoming less negative. For one stream, deforestation occurred during the sampling period and this led to large increases in nitrate and smaller increases in aluminium midway through the study period. However, the climate and hydrological variability largely masked out other changes. The current analysis provides only a start to identifying trends for such a complex and variable environmental system. The need for strong statistical tools is emphasised to resolve issues of: (a hydrological induced water quality variability, (b changing soil and groundwater "endmember" chemistry contribution to the stream and (c the non-linear patterns of

  9. Initial Characterization and Water Quality Assessment of Stream Landscapes in Northern Mongolia

    Directory of Open Access Journals (Sweden)

    Jürgen Hofmann

    2015-06-01

    Full Text Available A comprehensive monitoring project (2006–2013 provided data on hydrology, hydromorphology, climatology, water physico-chemistry, sedimentology, macroinvertebrate community and fish diversity in the Kharaa River basin in northern Mongolia, thus enabling, for the first time, a detailed characterization of the stream landscapes. Surface waters were categorized into separate “water bodies” according to their identifiable abiotic and biocoenotic features, subsequently creating the smallest management sub-units within the river basin. Following the approach of the European Water Framework Directive (EC-WFD, in order to obtain a good ecological status (GES, four clearly identifiable water bodies in the Kharaa River main channel and seven water bodies consisting of the basin’s tributaries were delineated. The type-specific undisturbed reference state of various aquatic ecosystems was identified in the assessment and used to set standards for restoration goals. With regards to water quality and quantity, the upper reaches of the Kharaa River basin in the Khentii Mountains were classified as having a “good” ecological and chemical status. Compared with these natural reference conditions in the upper reaches, the initial risk assessment identified several “hot spot” regions with impacted water bodies in the middle and lower basin. Subsequently, the affected water bodies are at risk of not obtaining a level of good ecological and/or chemical status for surface waters. Finally, a matrix of cause-response relationships and stressor complexes has been developed and is presented here. The applicability of management approaches is discussed to better foster the development of a sustainable river basin management plan. The application of natural references states offers a sound scientific base to assess the impact of anthropogenic activities across the Kharaa River basin.

  10. Water quality and ecosystem management: Data-driven reality check of effects in streams and lakes

    Science.gov (United States)

    Destouni, Georgia; Fischer, Ida; Prieto, Carmen

    2017-08-01

    This study investigates nutrient-related water quality conditions and change trends in the first management periods of the EU Water Framework Directive (WFD; since 2009) and Baltic Sea Action Plan (BASP; since 2007). With mitigation of nutrients in inland waters and their discharges to the Baltic Sea being a common WFD and BSAP target, we use Sweden as a case study of observable effects, by compiling and analyzing all openly available water and nutrient monitoring data across Sweden since 2003. The data compilation reveals that nutrient monitoring covers only around 1% (down to 0.2% for nutrient loads) of the total number of WFD-classified stream and lake water bodies in Sweden. The data analysis further shows that the hydro-climatically driven water discharge dominates the determination of waterborne loads of both total phosphorus and total nitrogen across Sweden. Both water discharge and the related nutrient loads are in turn well correlated with the ecosystem status classification of Swedish water bodies. Nutrient concentrations do not exhibit such correlation and their changes over the study period are on average small, but concentration increases are found for moderate-to-bad status waters, for which both the WFD and the BSAP have instead targeted concentration decreases. In general, these results indicate insufficient distinction and mitigation of human-driven nutrient components in inland waters and their discharges to the sea by the internationally harmonized applications of the WFD and the BSAP. The results call for further comparative investigations of observable large-scale effects of such regulatory/management frameworks in different parts of the world.

  11. Reconciling agriculture and stream restoration in Europe: A review relating to the EU Water Framework Directive.

    Science.gov (United States)

    Flávio, H M; Ferreira, P; Formigo, N; Svendsen, J C

    2017-10-15

    Agriculture is widespread across the EU and has caused considerable impacts on freshwater ecosystems. To revert the degradation caused to streams and rivers, research and restoration efforts have been developed to recover ecosystem functions and services, with the European Water Framework Directive (WFD) playing a significant role in strengthening the progress. Analysing recent peer-reviewed European literature (2009-2016), this review explores 1) the conflicts and difficulties faced when restoring agriculturally impacted streams, 2) the aspects relevant to effectively reconcile agricultural land uses and healthy riverine ecosystems and 3) the effects and potential shortcomings of the first WFD management cycle. Our analysis reveals significant progress in restoration efforts, but it also demonstrates an urgent need for a higher number and detail of restoration projects reported in the peer-reviewed literature. The first WFD cycle ended in 2015 without reaching the goal of good ecological status in many European water-bodies. Addressing limitations reported in recent papers, including difficulties in stakeholder integration and importance of small headwater streams, is crucial. Analysing recent developments on stakeholder engagement through structured participatory processes will likely reduce perception discrepancies and increase stakeholder interest during the next WFD planning cycle. Despite an overall dominance of nutrient-related research, studies are spreading across many important topics (e.g. stakeholder management, land use conflicts, climate change effects), which may play an important role in guiding future policy. Our recommendations are important for the second WFD cycle because they 1) help secure the development and dissemination of science-based restoration strategies and 2) provide guidance for future research needs. Copyright © 2017 Elsevier B.V. All rights reserved.

  12. Point-Source Contributions to the Water Quality of an Urban Stream

    Science.gov (United States)

    Little, S. F. B.; Young, M.; Lowry, C.

    2014-12-01

    Scajaquada Creek, which runs through the heart of the city of Buffalo, is a prime example of the ways in which human intervention and local geomorphology can impact water quality and urban hydrology. Beginning in the 1920's, the Creek has been partially channelized and connected to Buffalo's combined sewer system (CSS). At Forest Lawn Cemetery, where this study takes place, Scajaquada Creek emerges from a 3.5-mile tunnel built to route stream flow under the city. Collocated with the tunnel outlet is a discharge point for Buffalo's CSS, combined sewer outlet (CSO) #53. It is at this point that runoff and sanitary sewage discharge regularly during rain events. Initially, this study endeavored to create a spatial and temporal picture for this portion of the Creek, monitoring such parameters as conductivity, dissolved oxygen, pH, temperature, and turbidity, in addition to measuring Escherichia coli (E. coli) concentrations. As expected, these factors responded directly to seasonality, local geomorphology, and distance from the point source (CSO #53), displaying a overall, linear response. However, the addition of nitrate and phosphate testing to the study revealed an entirely separate signal from that previously observed. Concentrations of these parameters did not respond to location in the same manner as E. coli. Instead of decreasing with distance from the CSO, a distinct periodicity was observed, correlating with a series of outflow pipes lining the stream banks. It is hypothesized that nitrate and phosphate occurring in this stretch of Scajaquada Creek originate not from the CSO, but from fertilizers used to maintain the lawns within the subwatershed. These results provide evidence of the complexity related to water quality issues in urban streams as a result of point- and nonpoint-source hydrologic inputs.

  13. MODIFIED REVERSE OSMOSIS SYSTEM FOR TREATMENT OF PRODUCED WATERS

    Energy Technology Data Exchange (ETDEWEB)

    T.M. Whitworth; Liangxiong Li

    2002-09-15

    This report describes work performed during the second year of the project ''Modified reverse osmosis system for treatment of produced waters.'' We performed two series of reverse osmosis experiments using very thin bentonite clay membranes compacted to differing degrees. The first series of 10 experiments used NaCl solutions with membranes that ranged between 0.041 and 0.064mm in thickness. Our results showed compaction of such ultra-thin clay membranes to be problematic. The thickness of the membranes was exceeded by the dimensional variation in the machined experimental cell and this is believed to have resulted in local bypassing of the membrane with a resultant decrease in solute rejection efficiency. In two of the experiments, permeate flow was varied as a percentage of the total flow to investigate results of changing permeate flow on solute rejection. In one experiment, the permeate flow was varied between 2.4 and 10.3% of the total flow with no change in solute rejection. In another experiment, the permeate flow was varied between 24.6 and 52.5% of the total flow. In this experiment, the solute rejection rate decreased as the permeate occupied greater fractions of the total flow. This suggests a maximum solute rejection efficiency for these clay membranes for a permeate flow of between 10.3 and 24.6% of the total; flow. Solute rejection was found to decrease with increasing salt concentration and ranged between 62.9% and 19.7% for chloride and between 61.5 and 16.8% for sodium. Due to problems with the compaction procedure and potential membrane bypassing, these rejection rates are probably not the upper limit for NaCl rejection by bentonite membranes. The second series of four reverse osmosis experiments was conducted with a 0.057mm-thick bentonite membrane and dilutions of a produced water sample with an original TDS of 196,250 mg/l obtained from a facility near Loco Hill, New Mexico, operated by an independent. These experiments

  14. A hierarchical model of daily stream temperature using air-water temperature synchronization, autocorrelation, and time lags

    Directory of Open Access Journals (Sweden)

    Benjamin H. Letcher

    2016-02-01

    Full Text Available Water temperature is a primary driver of stream ecosystems and commonly forms the basis of stream classifications. Robust models of stream temperature are critical as the climate changes, but estimating daily stream temperature poses several important challenges. We developed a statistical model that accounts for many challenges that can make stream temperature estimation difficult. Our model identifies the yearly period when air and water temperature are synchronized, accommodates hysteresis, incorporates time lags, deals with missing data and autocorrelation and can include external drivers. In a small stream network, the model performed well (RMSE = 0.59°C, identified a clear warming trend (0.63 °C decade−1 and a widening of the synchronized period (29 d decade−1. We also carefully evaluated how missing data influenced predictions. Missing data within a year had a small effect on performance (∼0.05% average drop in RMSE with 10% fewer days with data. Missing all data for a year decreased performance (∼0.6 °C jump in RMSE, but this decrease was moderated when data were available from other streams in the network.

  15. Pollutant loads and water quality in streams of heavily populated and industrialised towns

    Science.gov (United States)

    Ntengwe, F. W.

    The availability of portable water is often taken for granted and water allowed to get polluted. Industries, settlements, farms, markets, leaking sewer lines, poor hygiene practices are all potential sources of pollution. Each pollutant has its own effect on water and the environment. A study was conducted in Kitwe Stream in order to establish whether engineering and other human activities affect water quality. Samples were collected at ten points, the first point being at the source while the tenth point was at the confluence with the Kafue River. The samples were analysed for physical, chemical and biological parameters. The results revealed high levels of concentration and loads of total suspended solids (TSS). The points with high TSS values were P4 (118 mg/l) and P6 (140 mg/l) representing daily loads of 7.74 and 8.71 tonnes, respectively. The highest values of coliform were found at points P9 (2099), P10 (2558) followed by P4 (1149), P5 (1256) and P6 (1370). High values of nitrites were found at points P4 (34 mg/l), P5 (32 mg/l), P6 (21 mg/l) and P10 (12.4 mg/l). Chlorides were also found to be high at points P4, P5 and P6 with values of 70 mg/l, 80 mg/l and 87 mg/l, respectively. These parameters exceeded the maximum contaminant level (MCL) of 100 mg/l for TSS, 1 mg/l for nitrites, 500/100 ml for coliform in Zambia. The conductivity and coliform were also found to be high (>500 μS/cm, >500). The benthic study revealed a normal diversity of invertebrates but chironomidae was found to be on average 60% of total species counted. The fish activity was high upstream and low downstream at the mouth of the stream where it joins the Kafue River. There was no fish activity at the middle points. The planktons (phytoplankton and zooplankton) count revealed a high count (15-30 per ml) in places where there was high fish activity and a low count (1-5 per ml) where there was no activity. The stream water quality was therefore affected by the human activities.

  16. Decentralised water and wastewater treatment technologies to produce functional water for irrigation

    DEFF Research Database (Denmark)

    Battilani, Adriano; Steiner, Michele; Andersen, Martin

    2010-01-01

    The EU project SAFIR aimed to help farmers solve problems related to the use of low quality water for irrigation in a context of increasing scarcity of conventional freshwater resources. New decentralised water treatment devices (prototypes) were developed to allow a safe direct or indirect reuse...... of wastewater produced by small communities/industries or the use of polluted surface water. Water treatment technologies were coupled with irrigation strategies and technologies to obtain a flexible, easy to use, integrated management of the system. The challenge is to apply new strategies and technologies...... which allow using the lowest irrigation water quality without harming food safety or yield and fruit or derivatives quality. This study presents the results of prototype testing of a small-scale compact pressurized membrane bioreactor and of a modular field treatment system including commercial gravel...

  17. Removal of Radium isotopes from oil co-produced water using Bentonite

    International Nuclear Information System (INIS)

    Al Masri, M.S.; Al Attar, L.; Budeir, Y.; Al Chayah, O.

    2010-01-01

    In view of environmental concern, sorption of radium on natural bentonite mineral (Aleppo, Syria) was investigated using batch-type method. Data were expressed in terms of distribution coefficients. An attempt to increase the selectivity of bentonite for radium was made by preparing M-derivatives. Loss of mineral crystallinity in acidic media and the formation of new phase, such as BaCO 3 , in Ba-derivative were imposed by XRD characterisations. Of the cationic forms, Na-bentonite had shown the highest affinity. Mechanisms of radium uptake were pictured using M-derivatives and simulated radium solutions. The obtained results indicated that surface sorption/surface ion exchange were the predominated processes. The distinct sorption behaviour observed with Ba-form was, possibly, a reflection of radium co-precipitation with barium carbonate. The competing order of macro component, likely present in waste streams, was drawn by studying different concentrations of the corresponding salt media. As an outcome, sodium was the weakest inhibitor. The performance of natural bentonite and the most selective forms, i.e. Ba- and Na-derivatives, to sorb radium from actual oil co-produced waters, collected form Der Ezzor Petroleum Company (DEZPC), was studied. This mirrored the influential effect of waters pH over other comparable parameters. (author)

  18. Toxicity identification evaluations of produced-water effluents

    International Nuclear Information System (INIS)

    Sauer, T.C.; Costa, H.J.; Brown, J.S.; Ward, T.J.

    1997-01-01

    Toxicity identification evaluations (TIEs) were performed on 14 produced-water (PW) samples of various salinities from inland and offshore oil- and gas-production facilities operated by different companies in Wyoming, Texas, California, and Louisiana (USA) to evaluate the efficacy of TIE procedures in determining potential toxicants in PW effluents. The research involved acute (24- and 48-h) freshwater and marine toxicity tests on whole PW and PW fractions generated by standard US Environmental Protection Agency and PW-specific fractionation schemes. Factors influencing PW TIEs were investigated, such as the effect of salinity in selecting fractionation manipulations, the effect of toxicity test replication (i.e., reproducibility) in distinguishing changes in toxicities between whole PW and its fractions, and the suitability of different test species in PW TIEs. The results obtained and lessons learned from conducting these PW TIEs are presented in this article. Components, or fractions, contributing to toxicity differed for each PW with no specific fraction being consistently toxic. For most PW samples, toxicity attributed to any one fraction represented only part of the toxicity of the whole sample. However, no more than two fraction types were identified as potential toxicants in any sample. Potential toxicants identified during this study, besides salinity, included acidic and basic organic compound class fractions, particulates removed by filtration at pH 11, ammonia, hydrocarbons, hydrogen sulfide, material removed by pH change, and volatile compounds

  19. Effect of produced water on cod (Gadus morhua) immune responses

    Energy Technology Data Exchange (ETDEWEB)

    Hamoutene, D.; Mabrouk, G.; Samuelson, S.; Mansour, A.; Lee, K. [Fisheries and Oceans Canada, Dartmouth, NS (Canada). Maritimes Region, Ocean Sciences Division; Volkoff, H.; Parrish, C. [Memorial Univ. of Newfoundland, St. John' s, NL (Canada); Mathieu, A. [Oceans Ltd., St. John' s, NL (Canada)

    2007-07-01

    Studies have shown that produced water (PW) discharged from North Sea offshore platforms affects the biota at greater distances from operational platforms than originally presumed. According to PW dispersion simulations, dilution by at least 240 times occurs within 50-100 m, and up to 9000 times by 20 km from the discharge. In this study, the effect of PW on cod immunity was investigated by exposing fish to 0, 100 ppm (x 10,000 dilution) or 200 ppm (x 500) of PW for 76 days. Immune responses were evaluated at the end of the exposure. Fish from the 3 groups were injected with Aeromonas salmonicida lipopolysaccharides (LPS). Blood cell observation and flow cytometry were used to investigate the serum cortisol levels and gill histology along with ratios and respiratory burst (RB) responses of both circulating and head-kidney white blood cells (WBCs). The study revealed that baseline immunity and stress response were not affected by PW, other than an irritant-induced change in gill cells found in treated cod. In all groups, LPS injection resulted in a pronounced decrease in RB of head-kidney cells and an increase in serum cortisol and protein levels. However, the group exposed to 200 ppm of PW exhibited the most significant changes. LPS injection was also shown to influence WBC ratios, but further studies are needed to determine if this impact is stronger in fish exposed to PW. This study suggested an effect of PW on cod immunity after immune challenge with LPS.

  20. Effect of land cover, stream discharge, and precipitation on water quality in Puerto Rico

    Science.gov (United States)

    Hall, J. S.; Uriarte, M.

    2017-12-01

    In 2015, Puerto Rico experienced one of the worst droughts in its history, causing widespread water rationing and sparking concerns for future resources. The drought represents precipitation extremes that provide valuable insight into the effects of land cover (LC), on modulating discharge and water quality indices at varying spatial scales. We used data collected from 38 water quality and 55 precipitation monitoring stations in Puerto Rico from 2005 to 2016, paired with a 2010 land cover map to (1) determine whether temporal variability in discharge, precipitation, or antecedent precipitation was a better predictor of water quality, (2) find the spatial scale where LC has the greatest impact on water quality, and (3) quantify impacts of LC on water quality indices, including dissolved oxygen (mg/L), total nitrogen (mg/L), phosphorous (mg/L), turbidity (NTRU), fecal coliforms (colony units/100mL) and instantaneous discharge (ft3/s). The resulting linear mixed effects models account for between 36-68% of the variance in water quality. Preliminary results indicate that phosphorous and nitrogen were best predicted from instantaneous stream discharge, the log of discharge was the better predictor for turbidity and fecal coliforms, and summed 2 and 14-day antecedent precipitation indices were better predictors for dissolved oxygen and discharge, respectively. Increased urban and pasture area reliably decreased water quality in relation to forest cover, while agriculture and wetlands had little or mixed effects. Turbidity and nitrogen responded to a watershed level LC, while phosphorous, fecal coliforms, and discharge responded to LC in 60 m riparian buffers at the watershed scale. Our results indicate that LC modulates changing precipitation regimes and the ensuing impacts on water quality at a range of spatial scales.

  1. Measuring surface-water loss in Honouliuli Stream near the ‘Ewa Shaft, O‘ahu, Hawai‘i

    Science.gov (United States)

    Rosa, Sarah N.

    2017-05-30

    The Honolulu Board of Water Supply is currently concerned with the possibility of bacteria in the pumped water of the ‘Ewa Shaft (State well 3-2202-21). Groundwater from the ‘Ewa Shaft could potentially be used to meet future potable water needs in the ‘Ewa area on the island of O‘ahu. The source of the bacteria in the pumped water is unknown, although previous studies indicate that surface water may be lost to the subsurface near the site. The ‘Ewa Shaft consists of a vertical shaft, started near the south bank of Honouliuli Stream at an altitude of about 161 feet, and two horizontal infiltration tunnels near sea level. The shaft extracts groundwater from near the top of the freshwater lens in the Waipahu-Waiawa aquifer system within the greater Pearl Harbor Aquifer Sector, a designated Water Management Area.The surface-water losses were evaluated with continuous groundwater-level data from the ‘Ewa Shaft and a nearby monitoring well, continuous stream-discharge data from U.S. Geological Survey streamflow-gaging station 16212490 (Honouliuli Stream at H-1 Freeway near Waipahu), and seepage-run measurements in Honouliuli Stream and its tributary. During storms, discharge at the Honouliuli Stream gaging station increases and groundwater levels at ‘Ewa Shaft and a nearby monitoring well also increase. The concurrent increase in water levels at ‘Ewa Shaft and the nearby monitoring well during storms indicates that regional groundwater-level changes related to increased recharge, reduced withdrawals (due to a decrease in demand during periods of rainfall), or both may be occurring; although these data do not preclude the possibility of local recharge from Honouliuli Stream. Discharge measurements from two seepage runs indicate that surface water in the immediate area adjacent to ‘Ewa Shaft infiltrates into the streambed and may later reach the groundwater system developed by the ‘Ewa Shaft. The estimated seepage loss rates in the vicinity of

  2. Surface water quality in streams and rivers: introduction, scaling, and climate change: Chapter 5

    Science.gov (United States)

    Loperfido, John

    2013-01-01

    A variety of competing and complementary needs such as ecological health, human consumption, transportation, recreation, and economic value make management and protection of water resources in riverine environments essential. Thus, an understanding of the complex and interacting factors that dictate riverine water quality is essential in empowering stake-holders to make informed management decisions (see Chapter 1.15 for additional information on water resource management). Driven by natural and anthropogenic forcing factors, a variety of chemical, physical, and biological processes dictate riverine water quality, resulting in temporal and spatial patterns and cycling (see Chapter 1.2 for information describing how global change interacts with water resources). Furthermore, changes in climatic forcing factors may lead to long-term deviations in water quality outside the envelope of historical data. The goal of this chapter is to present fundamental concepts dictating the conditions of basic water quality parameters in rivers and streams (herein generally referred to as rivers unless discussing a specific system) in the context of temporal (diel (24 h) to decadal) longitudinal scaling. Understanding water quality scaling in rivers is imperative as water is continually reused and recycled (see also Chapters 3.1 and 3.15); upstream discharges from anthropogenic sources are incorporated into bulk riverine water quality that is used by downstream consumers. Water quality parameters reviewed here include temperature, pH, dissolved oxygen (DO), and suspended sediment and were selected given the abundance of data available for these parameters due to recent advances in water quality sensor technology (see Chapter 4.13 for use of hydrologic data in watershed management). General equations describing reactions affecting water temperature, pH, DO, and suspended sediment are included to convey the complexity of how simultaneously occurring reactions can affect water quality

  3. Bacteriological quality of sachet water produced and sold in Teshie ...

    African Journals Online (AJOL)

    Access to good quality drinking water is a challenge in most towns and cities in Ghana and households have for years depended on other sources of water to supplement their activities. The introduction of sachet water to consumers was to provide safe, hygienic and affordable instant drinking water to the public. Although ...

  4. Stream water chemistry in watersheds receiving different atmospheric inputs of H+, NH4+, NO3-, and SO42-1

    Science.gov (United States)

    Stottlemyer, R.

    1997-01-01

    Weekly precipitation and stream water samples were collected from small watersheds in Denali National Park, Alaska, the Fraser Experimental Forest, Colorado, Isle Royale National Park, Michigan, and the Calumet watershed on the south shore of Lake Superior, Michigan. The objective was to determine if stream water chemistry at the mouth and upstream stations reflected precipitation chemistry across a range of atmospheric inputs of H+, NH4+, NO3-, and SO42-. Volume-weighted precipitation H+, NH4+, NO3-, and SO42- concentrations varied 4 to 8 fold with concentrations highest at Calumet and lowest in Denali. Stream water chemistry varied among sites, but did not reflect precipitation chemistry. The Denali watershed, Rock Creek, had the lowest precipitation NO3- and SO42- concentrations, but the highest stream water NO3and SO42- concentrations. Among sites, the ratio of mean monthly upstream NO3- concentration to precipitation NO3- concentration declined (p 90 percent inputs) across inputs ranging from 0.12 to > 6 kg N ha-1 y-1. Factors possibly accounting for the weak or non-existent signal between stream water and precipitation ion concentrations include rapid modification of meltwater and precipitation chemistry by soil processes, and the presence of unfrozen soils which permits winter mineralization and nitrification to occur.

  5. Comparative experiments on polymer degradation technique of produced water of polymer flooding oilfield

    Science.gov (United States)

    Chen, Rong; Qi, Mei; Zhang, Guohui; Yi, Chenggao

    2018-02-01

    The application of polymer flooding technology in oilfields can result in polymer content increased in produced water. This increasing made produced water quality become poor. The efficiency of produced water processing decreased significantly. Processed water quality seriously exceeded criterion’s stipulation. The presence of the polymer in produced water is the main reason for more difficulties in processing of produced water, therefore the polymer degradation technology is a key coefficient in produced water processing for polymer flooding oilfields. We evaluated several physical and chemical polymer degradation methods with the solution of separated water from polymer flooding oilfields and hydrolyzed polyacrylamide. The experiment results can provide a basis for produced water processing technologies application in polymer flooding oilfields.

  6. Management of Reclaimed Produced Water in the Rocky Mountain States Enhanced with the Expanded U.S. Geological Survey Produced Waters Geochemical Database

    Science.gov (United States)

    Gans, K. D.; Blondes, M. S.; Reidy, M. E.; Conaway, C. H.; Thordsen, J. J.; Rowan, E. L.; Kharaka, Y. K.; Engle, M.

    2016-12-01

    The Rocky Mountain states; Wyoming, Colorado, Montana, New Mexico and Utah produce annually approximately 470,000 acre-feet (3.66 billion barrels) of produced water - water that coexists with oil and gas and is brought to the surface with the pumping of oil and gas wells. Concerns about severe drought, groundwater depletion, and contamination have prompted petroleum operators and water districts to examine the recycling of produced water. Knowledge of the geochemistry of produced waters is valuable in determining the feasibility of produced water reuse. Water with low salinity can be reclaimed for use inside and outside of the petroleum industry. Since a great proportion of petroleum wells in the Rocky Mountain states, especially coal-bed methane wells, have produced water with relatively low salinity (generally oil recovery, and even for municipal uses, such as drinking water. The USGS Produced Waters Geochemical Database, available at http://eerscmap.usgs.gov/pwapp, has 60,000 data points in this region (this includes 35,000 new data points added to the 2002 database) and will facilitate studies on the management of produced water for reclamation in the Rocky Mountain region. Expanding on the USGS 2002 database, which contains geochemical analyses of major ions and total dissolved solids, the new data also include geochemical analyses of minor ions and stable isotopes. We have added an interactive web map application which allows the user to filter data on chosen fields (e.g. TDS data set can provide critical insight for better management of produced waters in water-constrained regions of the Rocky Mountains.

  7. Innovative Water Management Technology to Reduce Environment Impacts of Produced Water

    Energy Technology Data Exchange (ETDEWEB)

    Castle, James; Rodgers, John; Alley, Bethany; Coffey, Ruthanne; Jurinko, Kristen; Pardue, Michael; Ritter, Tina; Spacil, Michael

    2013-05-15

    Clemson University with Chevron as an industry partner developed and applied treatment technology using constructed wetland systems to decrease targeted constituents in simulated and actual produced waters to achieve reuse criteria and discharge limits. Pilot-scale and demonstration constructed wetland treatment system (CWTS) experiments led to design strategies for treating a variety of constituents of concern (COCs) in produced waters including divalent metals, metalloids, oil and grease, and ammonia. Targeted biogeochemical pathways for treatment of COCs in pilot-scale CWTS experiments included divalent metal sulfide precipitation through dissimilatory sulfate reduction, metal precipitation through oxidation, reduction of selenite to insoluble elemental selenium, aerobic biodegradation of oil, nitrification of ammonia to nitrate, denitrification of nitrate to nitrogen gas, separation of oil using an oilwater separator, and sorption of ammonia to zeolite. Treatment performance results indicated that CWTSs can be designed and built to promote specific environmental and geochemical conditions in order for targeted biogeochemical pathways to operate. The demonstration system successfully achieved consistent removal extents even while inflow concentrations of COCs in the produced water differed by orders of magnitude. Design strategies used in the pilot-scale and demonstration CWTSs to promote specific conditions that can be applied to designing full-scale CWTSs include plant and soil selection, water-depth selection, addition of amendments, and hydraulic retention time (HRT). These strategies allow conditions within a CWTS to be modified to achieve ranges necessary for the preferred biogeochemical treatment pathways. In the case of renovating a produced water containing COCs that require different biogeochemical pathways for treatment, a CWTS can be designed with sequential cells that promote different conditions. For example, the pilot-scale CWTS for post

  8. Innovative Water Management Technology to Reduce Environmental Impacts of Produced Water

    Energy Technology Data Exchange (ETDEWEB)

    Castle, James; Rodgers, John; Alley, Bethany; Beebe, Alex; Coffey, Ruthanne; Jurinko, Kristen; Pardue, Michael; Ritter, Tina; Spacil, Michael

    2013-05-15

    Clemson University with Chevron as an industry partner developed and applied treatment technology using constructed wetland systems to decrease targeted constituents in simulated and actual produced waters to achieve reuse criteria and discharge limits. Pilot-scale and demonstration constructed wetland treatment system (CWTS) experiments led to design strategies for treating a variety of constituents of concern (COCs) in produced waters including divalent metals, metalloids, oil and grease, and ammonia. Targeted biogeochemical pathways for treatment of COCs in pilot-scale CWTS experiments included divalent metal sulfide precipitation through dissimilatory sulfate reduction, metal precipitation through oxidation, reduction of selenite to insoluble elemental selenium, aerobic biodegradation of oil, nitrification of ammonia to nitrate, denitrification of nitrate to nitrogen gas, separation of oil using an oilwater separator, and sorption of ammonia to zeolite. Treatment performance results indicated that CWTSs can be designed and built to promote specific environmental and geochemical conditions in order for targeted biogeochemical pathways to operate. The demonstration system successfully achieved consistent removal extents even while inflow concentrations of COCs in the produced water differed by orders of magnitude. Design strategies used in the pilot-scale and demonstration CWTSs to promote specific conditions that can be applied to designing full-scale CWTSs include plant and soil selection, water-depth selection, addition of amendments, and hydraulic retention time (HRT). These strategies allow conditions within a CWTS to be modified to achieve ranges necessary for the preferred biogeochemical treatment pathways. In the case of renovating a produced water containing COCs that require different biogeochemical pathways for treatment, a CWTS can be designed with sequential cells that promote different conditions. For example, the pilot-scale CWTS for post

  9. Innovative Water Management Technology to Reduce Environment Impacts of Produced Water

    Energy Technology Data Exchange (ETDEWEB)

    Castle, James W. [Clemson Univ., SC (United States); Rodgers, John H. [Clemson Univ., SC (United States); Alley, Bethany [Clemson Univ., SC (United States); Beebe, Alex [Clemson Univ., SC (United States); Coffey, Ruthanne [Clemson Univ., SC (United States); Jurinko, Kristen [Clemson Univ., SC (United States); Pardue, Michael [Clemson Univ., SC (United States); Ritter, Tina [Clemson Univ., SC (United States); Spacil, Michael M. [Clemson Univ., SC (United States)

    2013-08-08

    Clemson University with Chevron as an industry partner developed and applied treatment technology using constructed wetland systems to decrease targeted constituents in simulated and actual produced waters to achieve reuse criteria and discharge limits. Pilot-scale and demonstration constructed wetland treatment system (CWTS) experiments led to design strategies for treating a variety of constituents of concern (COCs) in produced waters including divalent metals, metalloids, oil and grease, and ammonia. Targeted biogeochemical pathways for treatment of COCs in pilot-scale CWTS experiments included divalent metal sulfide precipitation through dissimilatory sulfate reduction, metal precipitation through oxidation, reduction of selenite to insoluble elemental selenium, aerobic biodegradation of oil, nitrification of ammonia to nitrate, denitrification of nitrate to nitrogen gas, separation of oil using an oilwater separator, and sorption of ammonia to zeolite. Treatment performance results indicated that CWTSs can be designed and built to promote specific environmental and geochemical conditions in order for targeted biogeochemical pathways to operate. The demonstration system successfully achieved consistent removal extents even while inflow concentrations of COCs in the produced water differed by orders of magnitude. Design strategies used in the pilot-scale and demonstration CWTSs to promote specific conditions that can be applied to designing full-scale CWTSs include plant and soil selection, water-depth selection, addition of amendments, and hydraulic retention time (HRT). These strategies allow conditions within a CWTS to be modified to achieve ranges necessary for the preferred biogeochemical treatment pathways. In the case of renovating a produced water containing COCs that require different biogeochemical pathways for treatment, a CWTS can be designed with sequential cells that promote different conditions. For example, the pilot-scale CWTS for post

  10. Ground-water resources of Gregg County, Texas, with a section on Stream runoff

    Science.gov (United States)

    Broadhurst, W.L.; Breeding, S.D.

    1950-01-01

    Field work in the island of St. Croix, V. I., was carried on from December 1938 to April 1939 in connection with a test-drilling program for water sup- plies. The island is 21 miles long and has a maximum width of 6 miles. Its western part consists of a range of mountains flanked on the south by a rolling plain; its narrower eastern part is entirely mountainous. There are only a few small streams. The rolling and fiat lands are cultivated or are in grass, and the mountainous areas are either wooded or in grass. The average rain- fall of the island is 46.34 inches, but severe droughts and periods of excess precipitation are not uncommon. The island is made up of rocks of Upper Cretaceous age, mostly volcanic tufts and limestones known as the Mount Eagle volcanics; diorite intruded into the cretaceous rocks; and Oligocene to Miocene blue clays and yellow marls (the Jealousy formation and Kingshill marl, respectively). Alluvium is widely distributed. The Mount Eagle rocks were strongly folded in early Tertiary time and the Kingshill strata gently folded in post Lower-Miocene time along an east-northeast axis. Three early Tertiary cycles of erosion are recognized. After the folding of the Kingshill marl, streams followed the strike of the folded rocks in a westerly direction, but they gradually assumed southward courses across the marl plain and as a result a western area of old-age topography, a central area of late-mature topography, and an eastern area of early-mature topography have been created. Submerged reefs and emergent reefs and beaches indicate several fairly recent stands of the sea. Water for human consumption is obtained by collecting rain water in cis- terns, but water for other purposes is almost entirely supplied by wells which are generally less than 100 feet deep. Many dug wells are used, but in recent years drilled wells have been constructed. Most of them are discharged by wind-powered pumps of small capacity. Wells are developed in all the rocks

  11. Impact of Water Usage on the Hydrology of Streams in the Mill River Watershed, Massachusetts

    Science.gov (United States)

    Newton, R. M.; Rhodes, A. L.; Pufall, A.; Bradstreet, E.; Katchpole, S.; Mattison, E.; Woods, R.

    2001-05-01

    Removal of surface water for municipal water supplies has reduced base flow in two tributary streams to the Mill River in Whately Massachusetts. This reduction in the flow of high quality water from these tributaries reduces the amount of dilution of high anthropogenic chemical loads in the main branch of the Mill River leading to high concentrations of chloride and sulfate. The city of Northampton, operates a reservoir on West Brook that removes an average of 5,700 m3/day. West Brook occupies a 28.4 km2 watershed underlain by Paleozoic igneous and metamorphic rocks that are mainly overlain by thin deposits of Pleistocene till. There are isolated areas of stratified drift in the area of the reservoir and where West Brook enters into the area formerly occupied by Glacial Lake Hitchcock. The reservoir (0.35 km2 in area) lies within the upper third of the subcatchment and is primarily fed by Avery Brook (7.6 km2 watershed). Although the reservoirs watershed represent about one third of the West Brook watershed, high water demands limit the release of water from the reservoir to periods of high flow associated with intense rainfall or snowmelt events. A comparison of unit hydrographs from Avery Brook, upstream of the reservoir with those from West Brook near where it enters the Mill River show significant lower discharges downstream (1mm/day). A comparison of flow duration curves show that discharges below the reservoir are dramatically lower during low flow conditions. The town of South Deerfield operates a reservoir on Roaring Brook that removes approximately 3,800 m3/day. Roaring Brook occupies a 14.0 km2 watershed that is similar in geology to West Brook. The reservoir is located on the downstream section of the brook just above where it enters the Mill River. Unlike the Northampton reservoir, water is almost continually released from the reservoir although the rate does fluctuate greatly. Data from a gage station located just downstream of the dam show rapid

  12. The impact of the High Park Wildfire on stream water quality and implications for drinking water treatment

    Science.gov (United States)

    Rosario-Ortiz, F.

    2014-12-01

    The Cache La Poudre (CLP) watershed in Northern Colorado was impacted by the High Park fire, which burned from June 9th through July 1st of 2012. The CLP watershed serves as a source of drinking water for three water districts in Northern Colorado, including the City of Fort Collins. Sampling was conducted during four different storm events immediately after the fire was extinguished. The sampling was expanded through spring and summer 2013 in order to capture the flush of debris from the wildfire into the CLP River. Samples were also collected from an unburned control site for comparison. Surface water samples were analyzed for parameters including nutrients, dissolved organic carbon (DOC) concentration and dissolved organic matter (DOM) characterization. In addition, bench scale treatment analyses were conducted to better understand the impacts of the wildfire on treatment processes for drinking water utilities. Lastly, leaching of stream bank sediments was conducted to determine the potential longer term inputs of burned material to the stream water. The overarching goals of the sampling campaign were to: 1) Evaluate the impact that wildfires have on the properties of DOM, specifically with respect to DBP formation and speciation (TTHM, HAA5, HAN, NDMA); 2) Establish the condition under which the source water could be effectively treated (using coagulation) to remove DBP precursors; 3) Evaluate the use of fluorescence spectroscopy as a surrogate for the concentration and reactivity of DOM in the CLP watershed; and 4) Assess the quantity and quality of DOM leached from streambed sediments. Preliminary results showed elevated DOC levels during the storm events and at wildfire impacted sites compared to the unburned site following the fire. DBP yields were higher for the four storm events following the fire when compared to yields for the control site located upstream of the burn area, and also when compared to data from a previous DBP study conducted on similar

  13. A comparative study of stream water and stream sediment as geochemical exploration media in the Rio Tanama porphyry copper district, Puerto Rico

    Science.gov (United States)

    Learned, R.E.; Chao, T.T.; Sanzolone, R.F.

    1985-01-01

    To test the relative effectiveness of stream water and sediment as geochemical exploration media in the Rio Tanama porphyry copper district of Puerto Rico, we collected and subsequently analyzed samples of water and sediment from 29 sites in the rivers and tributaries of the district. Copper, Mo, Pb, Zn, SO42-, and pH were determined in the waters; Cu, Mo, Pb, and Zn were determined in the sediments. In addition, copper in five partial extractions from the sediments was determined. Geochemical contrast (anomaly-to-background quotient) was the principal criterion by which the effectiveness of the two media and the five extractions were judged. Among the distribution patterns of metals in stream water, that of copper most clearly delineates the known porphyry copper deposits and yields the longest discernable dispersion train. The distribution patterns of Mo, Pb, and Zn in water show little relationship to the known mineralization. The distribution of SO42- in water delineates the copper deposits and also the more extensive pyrite alteration in the district; its recognizable downstream dispersion train is substantially longer than those of the metals, either in water or sediment. Low pH values in small tributaries delineate areas of known sulfide mineralization. The distribution patterns of copper in sediments clearly delineate the known deposits, and the dispersion trains are longer than those of copper in water. The partial determinations of copper related to secondary iron and manganese oxides yield the strongest geochemical contrasts and longest recognizable dispersion trains. Significantly high concentrations of molybdenum in sediments were found at only three sites, all within one-half km downstream of the known copper deposits. The distribution patterns of lead and zinc in sediments are clearly related to the known primary lead-zinc haloes around the copper deposits. The recognizable downstream dispersion trains of lead and zinc are shorter than those of

  14. Quality of Sachet Water Produced at Tarkwa, Ghana*

    African Journals Online (AJOL)

    Michael

    2015-06-01

    Jun 1, 2015 ... Keywords: Sachet water quality, Protozoan organisms, Faecal coliforms. 1 Introduction. In Ghana ... problems to water production because of the ensuing high pollution ...... Mexico Institute of Mining and. Technology, USA in ...

  15. From a water resource to a point pollution source: the daily journey of a coastal urban stream

    Directory of Open Access Journals (Sweden)

    LR. Rörig

    Full Text Available The aim of this study was to understand how a stream ecosystem that flows from its fountainhead to its mouth inside a city, changes from a water resource to a point pollution source. A multidisciplinary descriptive approach was adopted, including the short-term temporal and spatial determination of physical, chemical, biological and ecotoxicological variables. Results showed that water quality rapidly decreases with increasing urbanization, leading the system to acquire raw sewage attributes even in the first hundred meters after the fountainheads. Despite the tidal circulation near the stream mouth being restricted by shallowness, some improvement of the water quality was detected in this area. The multidisciplinary evaluation showed to be useful for obtaining a more realistic understanding of the stream degradation process, and to forecast restoration and mitigation measures.

  16. The Role of Stream Water Carbon Dynamics and Export in the Carbon Balance of a Tropical Seasonal Rainforest, Southwest China

    Science.gov (United States)

    Zhou, Wen-Jun; Zhang, Yi-Ping; Schaefer, Douglas A.; Sha, Li-Qing; Deng, Yun; Deng, Xiao-Bao; Dai, Kai-Jie

    2013-01-01

    A two-year study (2009 ∼ 2010) was carried out to investigate the dynamics of different carbon (C) forms, and the role of stream export in the C balance of a 23.4-ha headwater catchment in a tropical seasonal rainforest at Xishuangbanna (XSBN), southwest China. The seasonal volumetric weighted mean (VWM) concentrations of total inorganic C (TIC) and dissolved inorganic C (DIC) were higher, and particulate inorganic C (PIC) and organic C (POC) were lower, in the dry season than the rainy season, while the VWM concentrations of total organic C (TOC) and dissolved organic C (DOC) were similar between seasons. With increased monthly stream discharge and stream water temperature (SWT), only TIC and DIC concentrations decreased significantly. The most important C form in stream export was DIC, accounting for 51.8% of the total C (TC) export; DOC, POC, and PIC accounted for 21.8%, 14.9%, and 11.5% of the TC export, respectively. Dynamics of C flux were closely related to stream discharge, with the greatest export during the rainy season. C export in the headwater stream was 47.1 kg C ha−1 yr−1, about 2.85% of the annual net ecosystem exchange. This finding indicates that stream export represented a minor contribution to the C balance in this tropical seasonal rainforest. PMID:23437195

  17. The role of stream water carbon dynamics and export in the carbon balance of a tropical seasonal rainforest, southwest China.

    Directory of Open Access Journals (Sweden)

    Wen-Jun Zhou

    Full Text Available A two-year study (2009 ~ 2010 was carried out to investigate the dynamics of different carbon (C forms, and the role of stream export in the C balance of a 23.4-ha headwater catchment in a tropical seasonal rainforest at Xishuangbanna (XSBN, southwest China. The seasonal volumetric weighted mean (VWM concentrations of total inorganic C (TIC and dissolved inorganic C (DIC were higher, and particulate inorganic C (PIC and organic C (POC were lower, in the dry season than the rainy season, while the VWM concentrations of total organic C (TOC and dissolved organic C (DOC were similar between seasons. With increased monthly stream discharge and stream water temperature (SWT, only TIC and DIC concentrations decreased significantly. The most important C form in stream export was DIC, accounting for 51.8% of the total C (TC export; DOC, POC, and PIC accounted for 21.8%, 14.9%, and 11.5% of the TC export, respectively. Dynamics of C flux were closely related to stream discharge, with the greatest export during the rainy season. C export in the headwater stream was 47.1 kg C ha(-1 yr(-1, about 2.85% of the annual net ecosystem exchange. This finding indicates that stream export represented a minor contribution to the C balance in this tropical seasonal rainforest.

  18. Diatom, cyanobacterial and microbial mats as indicators of hydrocarbon contaminated Arctic streams and waters

    Energy Technology Data Exchange (ETDEWEB)

    Ziervogel, H.; Selann, J.; Adeney, B. [EBA Engineering Consultants Ltd., Edmonton, AB (Canada); Nelson, J.A. [J.B. Services, Sarnia, ON (Canada); Murdock, E. [Nunavut Power, Iqaluit (Canada)

    2003-07-01

    An environmental assessment conducted at Repulse Bay, Nunavut in the summer of 2001 revealed a recent diesel spill flowing from the groundwater into a creek. The spill had not been reported. When Arctic surface waters mix with hydrocarbon impacted groundwater and sediments, distinctive mats of diatom, cyanobacteria and other bacteria are formed. These mats have the potential for phytoremediation of hydrocarbons. This paper explained the apparent dominance of mats in contaminated Arctic waters and why they promote biodegradation of hydrocarbons. Hydrocarbon-contaminated soils and groundwater are generally anaerobic. The higher dissolved carbon dioxide in polluted soils and groundwater can benefit photosynthetic cyanobacteria and diatom found in oligotrophic, lower alkalinity Arctic waters. The anaerobic and aerobic bacteria can potentially take advantage of the hydrogen substrate and the nitrogen fixing abilities of the cyanobacteria. Zooplankton predators may be killed off by the toxicity of the polluted groundwater. The paper provides examples where a microbial mat reduced the sulfate content of a hydrocarbon-impacted Arctic stream by 100 ppm, and where a pond covered in a benthic microbial mat showed no evidence of hydrocarbons in the water overlying sediments contaminated with hydrocarbons at concentrations measured at 30,000 ppm. 19 refs., 3 tabs., 8 figs.

  19. Rising air and stream-water temperatures in Chesapeake Bay region, USA

    Science.gov (United States)

    Rice, Karen C.; Jastram, John D.

    2015-01-01

    Monthly mean air temperature (AT) at 85 sites and instantaneous stream-water temperature (WT) at 129 sites for 1960–2010 are examined for the mid-Atlantic region, USA. Temperature anomalies for two periods, 1961–1985 and 1985–2010, relative to the climate normal period of 1971–2000, indicate that the latter period was statistically significantly warmer than the former for both mean AT and WT. Statistically significant temporal trends across the region of 0.023 °C per year for AT and 0.028 °C per year for WT are detected using simple linear regression. Sensitivity analyses show that the irregularly sampled WT data are appropriate for trend analyses, resulting in conservative estimates of trend magnitude. Relations between 190 landscape factors and significant trends in AT-WT relations are examined using principal components analysis. Measures of major dams and deciduous forest are correlated with WT increasing slower than AT, whereas agriculture in the absence of major dams is correlated with WT increasing faster than AT. Increasing WT trends are detected despite increasing trends in streamflow in the northern part of the study area. Continued warming of contributing streams to Chesapeake Bay likely will result in shifts in distributions of aquatic biota and contribute to worsened eutrophic conditions in the bay and its estuaries.

  20. Combination gas producing and waste-water disposal well

    Science.gov (United States)

    Malinchak, Raymond M.

    1984-01-01

    The present invention is directed to a waste-water disposal system for use in a gas recovery well penetrating a subterranean water-containing and methane gas-bearing coal formation. A cased bore hole penetrates the coal formation and extends downwardly therefrom into a further earth formation which has sufficient permeability to absorb the waste water entering the borehole from the coal formation. Pump means are disposed in the casing below the coal formation for pumping the water through a main conduit towards the water-absorbing earth formation. A barrier or water plug is disposed about the main conduit to prevent water flow through the casing except for through the main conduit. Bypass conduits disposed above the barrier communicate with the main conduit to provide an unpumped flow of water to the water-absorbing earth formation. One-way valves are in the main conduit and in the bypass conduits to provide flow of water therethrough only in the direction towards the water-absorbing earth formation.

  1. Norm removal from frac water

    Science.gov (United States)

    Silva, James Manio; Matis, Hope; Kostedt, IV, William Leonard

    2014-11-18

    A method for treating low barium frac water includes contacting a frac water stream with a radium selective complexing resin to produce a low radium stream, passing the low radium stream through a thermal brine concentrator to produce a concentrated brine; and passing the concentrated brine through a thermal crystallizer to yield road salt.

  2. Flocculation of organic carbon from headwaters to estuary - the impact of soil erosion, water quality and land use on carbon transformation processes in eight streams draining Exmoor, UK

    Science.gov (United States)

    Snoalv, J.; Groeneveld, M.; Quine, T. A.; Tranvik, L.

    2017-12-01

    Flocculation of dissolved organic carbon (DOC) in streams and rivers is a process that contributes to the pool of particulate organic carbon (POC) in the aquatic system. In low-energy waters the increased sedimentation rates of this higher-density fraction of organic carbon (OC) makes POC important in allocating organic carbon into limnic storage, which subsequently influences emissions of greenhouse gases from the continental environment to the atmosphere. Allochthonous OC, derived from the terrestrial environment by soil erosion and litterfall, import both mineral aggregate-bound and free OC into freshwaters, which comprise carbon species of different quality and recalcitrance than autochthonous in-stream produced OC, such as from biofilms, aquatic plants and algae. Increased soil erosion due to land use change (e.g. agriculture, deforestation etc.) influences the input of allochthonous OC, which can lead to increased POC formation and sedimentation of terrestrial OC at flocculation boundaries in the landscape, i.e. where coagulation and flocculation processes are prone to occur in the water column. This study investigates the seasonal variation in POC content and flocculation capacity with respect to water quality (elemental composition) in eight river systems (four agricultural and four wooded streams) with headwaters in Exmoor, UK, that drain managed and non-managed land into Bristol Channel. Through flocculation experiments the samples were allowed to flocculate by treatments with added clay and salt standards that simulate the flocculation processes by 1) increased input of sediment into streams, and 2) saline mixing at the estuarine boundary, in order to quantify floc production and investigate POC quality by each process respectively. The results show how floc production, carbon quality and incorporation (e.g. complexation) of metals and rare earth elements (REE) in produced POC and remaining DOC in solution vary in water samples over the season and how

  3. Microbial quality of irrigation water used in leafy green production in Southern Brazil and its relationship with produce safety.

    Science.gov (United States)

    Decol, Luana Tombini; Casarin, Letícia Sopeña; Hessel, Claudia Titze; Batista, Ana Carolina Fösch; Allende, Ana; Tondo, Eduardo César

    2017-08-01

    Irrigation water has been recognized as an important microbial risk factor for fruits and vegetables in many production areas, but there is still a lack of information about how the microbiological quality of different irrigation water sources and climatic conditions influence the safety of vegetables produced in Brazil. This study evaluated the distribution of generic E. coli and the prevalence of E. coli O157:H7 in two different water sources (ponds and streams bordering farmlands and urban areas) used for irrigation and on commercially produced lettuces in Southern Brazil. We also evaluated the effect of agricultural factors and meteorological conditions in the potential contamination of water and produce samples. A longitudinal study was conducted on four farms during a year (July 2014 to August 2015). The results showed generic E. coli prevalence of 84.8% and 38.3% in irrigation water samples and on lettuces, respectively, indicating irrigation water as an important source of contamination of lettuces. No significant differences were detected in the counts of E. coli between the two different surface water sources. The climatic conditions, particularly rainfall and environmental temperature, have influenced the high concentration of E. coli. The highest loads of E. coli in irrigation water and on lettuces were found during the warmest time of the year. E. coli O157:H7 was detected by qualitative polymerase chain reaction (qPCR) in 13 water samples but only 4 were confirmed by isolation in culture media. Copyright © 2017 Elsevier Ltd. All rights reserved.

  4. Assessment of forestry best management practices, I: stream water chemistry natural variability and fertilization influences

    Science.gov (United States)

    Erik Schilling; Daniel McLaughlin; Matt Cohen; Larry Korhnak; Paul Decker; Camille Flinders

    2016-01-01

    Nutrient pollution can be a leading cause of impairment to some U.S. waters. As a result, state and federal agencies are actively engaged in designing management programs and numeric nutrient criteria (NNC) to address nutrient impairments. Following implementation of the Clean Water Act, Florida, like other timber producing states, developed, tested and implemented...

  5. Evaluation of the freeze-thaw/evaporation process for the treatment of produced waters. Final report, August 1992--August 1996

    Energy Technology Data Exchange (ETDEWEB)

    Boysen, J.E.; Walker, K.L.; Mefford, J.L.; Kirsch, J.R. [Resource Technology Corp., Laramie, WY (United States); Harju, J.A. [North Dakota Univ., Grand Forks, ND (United States). Energy and Environmental Research Center

    1996-06-01

    The use of freeze-crystallization is becoming increasingly acknowledged as a low-cost, energy-efficient method for purifying contaminated water. The natural freezing process can be coupled with natural evaporative processes to treat oil and gas produced waters year round in regions where subfreezing temperatures seasonally occur. The climates typical of Colorado`s San Juan Basin and eastern slope, as well as the oil and gas producing regions of Wyoming, are well suited for application of these processes in combination. Specifically, the objectives of this research are related to the development of a commercially-economic FTE (freeze-thaw/evaporation) process for the treatment and purification of water produced in conjunction with oil and natural gas. The research required for development of this process consists of three tasks: (1) a literature survey and process modeling and economic analysis; (2) laboratory-scale process evaluation; and (3) field demonstration of the process. Results of research conducted for the completion of these three tasks indicate that produced water treatment and disposal costs for commercial application of the process, would be in the range of $0.20 to $0.30/bbl in the Rocky Mountain region. FTE field demonstration results from northwestern New Mexico during the winter of 1995--96 indicate significant and simultaneous removal of salts, metals, and organics from produced water. Despite the unusually warm winter, process yields demonstrate disposal volume reductions on the order of 80% and confirm the potential for economic production of water suitable for various beneficial uses. The total dissolved solids concentrations of the FTE demonstration streams were 11,600 mg/L (feed), 56,900 mg/L (brine), and 940 mg/L (ice melt).

  6. Producing propellants from water in lunar soil using solar lasers

    Science.gov (United States)

    de Morais Mendonca Teles, Antonio

    The exploration of the Solar System is directly related to the efficiency of engines designed to explore it, and consequently, to the propulsion techniques, materials and propellants for those engines. With the present day propulsion techniques it is necessary great quantities of propellants to impulse a manned spacecraft to Mars and beyond in the Solar System, which makes these operations financially very expensive because of the costs involved in launching it from planet Earth, due to its high gravity field strength. To solve this problem, it is needed a planetary place with smaller gravity field strength, near to the Earth and with great quantities of substances at the surface necessary for the in-situ production of propellants for spacecrafts. The only place available is Earth's natural satellite the Moon. So, here in this paper, I propose the creation of a Lunar Propellant Manufacturer. It is a robot-spacecraft which can be launched from Earth using an Energia Rocket, and to land on the Moon in an area (principally near to the north pole where it was discovered water molecules ice recently) with great quantities of oxygen and hydrogen (propellants) in the silicate soil, previously observed and mapped by spacecrafts in lunar orbit, for the extraction of those molecules from the soil and the in-situ production of the necessary propellants. The Lunar Propellant Manufacturer (LPM) spacecraft consists of: 1) a landing system with four legs (extendable) and rovers -when the spacecraft touches down, the legs retract in order that two apparatuses, analogue to tractor's wheeled belts parallel sided and below the spacecraft, can touch firmly the ground -it will be necessary for the displacement of the spacecraft to new areas with richer propellants content, when the early place has already exhausted in propellants; 2) a digging machine -a long, resistant extendable arm with an excavator hand, in the outer part of the spacecraft -it will extend itself to the ground

  7. Molecular detection of vertebrates in stream water: a demonstration using Rocky Mountain tailed frogs and Idaho giant salamanders.

    Science.gov (United States)

    Goldberg, Caren S; Pilliod, David S; Arkle, Robert S; Waits, Lisette P

    2011-01-01

    Stream ecosystems harbor many secretive and imperiled species, and studies of vertebrates in these systems face the challenges of relatively low detection rates and high costs. Environmental DNA (eDNA) has recently been confirmed as a sensitive and efficient tool for documenting aquatic vertebrates in wetlands and in a large river and canal system. However, it was unclear whether this tool could be used to detect low-density vertebrates in fast-moving streams where shed cells may travel rapidly away from their source. To evaluate the potential utility of eDNA techniques in stream systems, we designed targeted primers to amplify a short, species-specific DNA fragment for two secretive stream amphibian species in the northwestern region of the United States (Rocky Mountain tailed frogs, Ascaphus montanus, and Idaho giant salamanders, Dicamptodon aterrimus). We tested three DNA extraction and five PCR protocols to determine whether we could detect eDNA of these species in filtered water samples from five streams with varying densities of these species in central Idaho, USA. We successfully amplified and sequenced the targeted DNA regions for both species from stream water filter samples. We detected Idaho giant salamanders in all samples and Rocky Mountain tailed frogs in four of five streams and found some indication that these species are more difficult to detect using eDNA in early spring than in early fall. While the sensitivity of this method across taxa remains to be determined, the use of eDNA could revolutionize surveys for rare and invasive stream species. With this study, the utility of eDNA techniques for detecting aquatic vertebrates has been demonstrated across the majority of freshwater systems, setting the stage for an innovative transformation in approaches for aquatic research.

  8. Molecular detection of vertebrates in stream water: a demonstration using Rocky Mountain tailed frogs and Idaho giant salamanders.

    Directory of Open Access Journals (Sweden)

    Caren S Goldberg

    Full Text Available Stream ecosystems harbor many secretive and imperiled species, and studies of vertebrates in these systems face the challenges of relatively low detection rates and high costs. Environmental DNA (eDNA has recently been confirmed as a sensitive and efficient tool for documenting aquatic vertebrates in wetlands and in a large river and canal system. However, it was unclear whether this tool could be used to detect low-density vertebrates in fast-moving streams where shed cells may travel rapidly away from their source. To evaluate the potential utility of eDNA techniques in stream systems, we designed targeted primers to amplify a short, species-specific DNA fragment for two secretive stream amphibian species in the northwestern region of the United States (Rocky Mountain tailed frogs, Ascaphus montanus, and Idaho giant salamanders, Dicamptodon aterrimus. We tested three DNA extraction and five PCR protocols to determine whether we could detect eDNA of these species in filtered water samples from five streams with varying densities of these species in central Idaho, USA. We successfully amplified and sequenced the targeted DNA regions for both species from stream water filter samples. We detected Idaho giant salamanders in all samples and Rocky Mountain tailed frogs in four of five streams and found some indication that these species are more difficult to detect using eDNA in early spring than in early fall. While the sensitivity of this method across taxa remains to be determined, the use of eDNA could revolutionize surveys for rare and invasive stream species. With this study, the utility of eDNA techniques for detecting aquatic vertebrates has been demonstrated across the majority of freshwater systems, setting the stage for an innovative transformation in approaches for aquatic research.

  9. A Regional Assessment of the Effects of Conservation Practices on In-stream Water Quality

    Science.gov (United States)

    Garcia, A. M.; Alexander, R. B.; Arnold, J.; Norfleet, L.; Robertson, D. M.; White, M.

    2011-12-01

    The Conservation Effects Assessment Program (CEAP), initiated by USDA Natural Resources Conservation Service (NRCS), has the goal of quantifying the environmental benefits of agricultural conservation practices. As part of this effort, detailed farmer surveys were compiled to document the adoption of conservation practices. Survey data showed that up to 38 percent of cropland in the Upper Mississippi River basin is managed to reduce sediment, nutrient and pesticide loads from agricultural activities. The broader effects of these practices on downstream water quality are challenging to quantify. The USDA-NRCS recently reported results of a study that combined farmer surveys with process-based models to deduce the effect of conservation practices on sediment and chemical loads in farm runoff and downstream waters. As a follow-up collaboration, USGS and USDA scientists conducted a semi-empirical assessment of the same suite of practices using the USGS SPARROW (SPAtially Referenced Regression On Watershed attributes) modeling framework. SPARROW is a hybrid statistical and mechanistic stream water quality model of annual conditions that has been used extensively in studies of nutrient sources and delivery. In this assessment, the USDA simulations of the effects of conservation practices on loads in farm runoff were used as an explanatory variable (i.e., change in farm loads per unit area) in a component of an existing a SPARROW model of the Upper Midwest. The model was then re-calibrated and tested to determine whether the USDA estimate of conservation adoption intensity explained a statistically significant proportion of the spatial variability in stream nutrient loads in the Upper Mississippi River basin. The results showed that the suite of conservation practices that NRCS has catalogued as complete nutrient and sediment management are a statistically significant feature in the Midwestern landscape associated with phosphorous runoff and delivery to downstream waters

  10. The influence of data characteristics on detecting wetland/stream surface-water connections in the Delmarva Peninsula, Maryland and Delaware

    Science.gov (United States)

    Vanderhoof, Melanie; Distler, Hayley; Lang, Megan W.; Alexander, Laurie C.

    2018-01-01

    The dependence of downstream waters on upstream ecosystems necessitates an improved understanding of watershed-scale hydrological interactions including connections between wetlands and streams. An evaluation of such connections is challenging when, (1) accurate and complete datasets of wetland and stream locations are often not available and (2) natural variability in surface-water extent influences the frequency and duration of wetland/stream connectivity. The Upper Choptank River watershed on the Delmarva Peninsula in eastern Maryland and Delaware is dominated by a high density of small, forested wetlands. In this analysis, wetland/stream surface water connections were quantified using multiple wetland and stream datasets, including headwater streams and depressions mapped from a lidar-derived digital elevation model. Surface-water extent was mapped across the watershed for spring 2015 using Landsat-8, Radarsat-2 and Worldview-3 imagery. The frequency of wetland/stream connections increased as a more complete and accurate stream dataset was used and surface-water extent was included, in particular when the spatial resolution of the imagery was finer (i.e., watershed contributing direct surface water runoff to streamflow. This finding suggests that our interpretation of the frequency and duration of wetland/stream connections will be influenced not only by the spatial and temporal characteristics of wetlands, streams and potential flowpaths, but also by the completeness, accuracy and resolution of input datasets.

  11. Development and testing of an in-stream phosphorus cycling model for the soil and water assessment tool.

    Science.gov (United States)

    White, Michael J; Storm, Daniel E; Mittelstet, Aaron; Busteed, Philip R; Haggard, Brian E; Rossi, Colleen

    2014-01-01

    The Soil and Water Assessment Tool is widely used to predict the fate and transport of phosphorus (P) from the landscape through streams and rivers. The current in-stream P submodel may not be suitable for many stream systems, particularly those dominated by attached algae and those affected by point sources. In this research, we developed an alternative submodel based on the equilibrium P concentration concept coupled with a particulate scour and deposition model. This submodel was integrated with the SWAT model and applied to the Illinois River Watershed in Oklahoma, a basin influenced by waste water treatment plant discharges and extensive poultry litter application. The model was calibrated and validated using measured data. Highly variable in-stream P concentrations and equilibrium P concentration values were predicted spatially and temporally. The model also predicted the gradual storage of P in streambed sediments and the resuspension of this P during periodic high-flow flushing events. Waste water treatment plants were predicted to have a profound effect on P dynamics in the Illinois River due to their constant discharge even under base flow conditions. A better understanding of P dynamics in stream systems using the revised submodel may lead to the development of more effective mitigation strategies to control the impact of P from point and nonpoint sources. Copyright © by the American Society of Agronomy, Crop Science Society of America, and Soil Science Society of America, Inc.

  12. Influence of infrastructure on water quality and greenhouse gasdynamics in urban streams

    Science.gov (United States)

    Streams and rivers are significant sources of nitrous oxide (N2O), carbon dioxide (CO2), and methane (CH4), and watershed management can alter greenhouse gas emissions from streams. GHG emissions from streams in agricultural watersheds have been investigated in numerous studies,...

  13. Legacies of stream channel modification revealed using General Land Office surveys, with implications for water temperature and aquatic life

    Directory of Open Access Journals (Sweden)

    Seth M. White

    2017-02-01

    Full Text Available Land use legacies can have a discernible influence in present-day watersheds and should be accounted for when designing conservation strategies for riverine aquatic life. We describe the environmental history of three watersheds within the Grande Ronde subbasin of the Columbia River using General Land Office survey field notes from the 19th century. In the two watersheds severely impacted by Euro-American land use, stream channel widths—a metric representing habitat simplification—increased from an average historical width of 16.8 m to an average present width of 20.8 m in large streams; 4.3 m to 5.5 m in small, confined or partly confined streams; and 3.5 m to 6.5 m in small, laterally unconfined steams. Conversely, we did not detect significant change in stream widths in an adjacent, wilderness stream with minimal human impact. Using a mechanistic water temperature model and restoration scenarios based on the historical condition, we predicted that stream restoration in the impacted watersheds could notably decrease average water temperatures—especially when channel narrowing is coupled with riparian restoration—up to a 6.6°C reduction in the upper Grande Ronde River and 3.0°C in Catherine Creek. These reductions in water temperature translated to substantial changes in the percentage of stream network habitable to salmon and steelhead migration (from 29% in the present condition to 79% in the fully restored scenario and to core juvenile rearing (from 13% in the present condition to 36% in the fully restored scenario. We conclude that land use legacies leave an important footprint on the present landscape and are critical for understanding historic habitat-forming processes as a necessary first step towards restoration.

  14. AN EVALUATION OF WATER QALITY OF AKPINAR STREAM (DENİZLİ WHERE TROUT PRODUCTION TAKES PLACE

    Directory of Open Access Journals (Sweden)

    Esengül KÖSE

    2012-08-01

    Full Text Available In this study, 20 physicochemical parameters were measured mountly in 2007 and seasonaly in 2008 and 2009 on Akpınar Stream, which is located within the borders of Denizli and has 13 trout production facility. The data obtained were evaluated according to the fresh water fish directive which was agreed by the Commision of European Union (EC Directives and Water Pollution Control Regulation Criteria. We determined that, the measured parameters on the first station do not constitute any risk for Salmonids and Cyprinids according to EC Directives and in the second station, the valuesof biological oxygen demand and nitrite were high enough to adversely affect the health of fish. There is not a significant difference between two stations for the parameters of oxygen, nitrate, totalnitrogen, pH, chemical oxygen demand, acid binding capacity, total hardness and chlorine. The parametes of total suspended solids, ammonium, nitrite, secondary phosphate, total phosphorus, organicmatter, ammonia, biological oxygen demand, turbidity, temperature and flow rate were significantly high in second station (p<0.05. The reason of high levels of the parameters especially origin of organic pollution in the secod station is fish feces and feed wastes which directly given into the water. Settling ponds should be used properly and controls should be provided to increase for more healtyproduction.

  15. ARSENIC MOBILITY FROM IRON OXIDE SOLIDS PRODUCED DURING WATER TREATMENT

    Science.gov (United States)

    The Arsenic Rule under the Safe Drinking Water Act will require certain drinking water suppliers to add to or modify their existing treatment in order to comply with the new 10 ppb arsenic standard. One of the treatment options is co-precipitation of arsenic with iron. This tre...

  16. Benthic invertebrate fauna, small streams

    Science.gov (United States)

    J. Bruce Wallace; S.L. Eggert

    2009-01-01

    Small streams (first- through third-order streams) make up >98% of the total number of stream segments and >86% of stream length in many drainage networks. Small streams occur over a wide array of climates, geology, and biomes, which influence temperature, hydrologic regimes, water chemistry, light, substrate, stream permanence, a basin's terrestrial plant...

  17. Factors controlling stream water nitrate and phosphor loads during precipitation events

    Science.gov (United States)

    Rozemeijer, J.; van der Velde, Y.; van Geer, F.; de Rooij, G. H.; Broers, H.; Bierkens, M. F.

    2009-12-01

    Pollution of surface waters in densely populated areas with intensive land use is a serious threat to their ecological, industrial and recreational utilization. European and national manure policies and several regional and local pilot projects aim at reducing pollution loads to surface waters. For the evaluation of measures, water authorities and environmental research institutes are putting a lot of effort into monitoring surface water quality. Within regional surface water quality monitoring networks, the measurement locations are usually situated in the downstream part of the catchment to represent a larger area. The monitoring frequency is usually low (e.g. monthly), due to the high costs for sampling and analysis. As a consequence, human induced trends in nutrient loads and concentrations in these monitoring data are often concealed by the large variability of surface water quality caused by meteorological variations. Because this natural variability in surface water quality is poorly understood, large uncertainties occur in the estimates of (trends in) nutrient loads or average concentrations. This study aims at uncertainty reduction in the estimates of mean concentrations and loads of N and P from regional monitoring data. For this purpose, we related continuous records of stream water N and P concentrations to easier and cheaper to collect quantitative data on precipitation, discharge, groundwater level and tube drain discharge. A specially designed multi scale experimental setup was installed in an agricultural lowland catchment in The Netherlands. At the catchment outlet, continuous measurements of water quality and discharge were performed from July 2007-January 2009. At an experimental field within the catchment we collected continuous measurements of precipitation, groundwater levels and tube drain discharges. 20 significant rainfall events with a variety of antecedent conditions, durations and intensities were selected for analysis. Singular and

  18. Chironomus larvae (Chironomidae: Diptera as water quality indicators along an environmental gradient in a neotropical urban stream

    Directory of Open Access Journals (Sweden)

    Nadja Gomes Machado

    2015-04-01

    Full Text Available Anthropogenic interference in urban lotic systems is a factor affecting the biota of waterbodies. Aquatic macro invertebrates are an important food source for fish and are valuable indicators of water quality. The objective of this work was to study Chironomus larvae (Chironomidae: Diptera distribution along an environmental gradient in Barbado Stream, Cuiabá, MT, Brazil. No individual Chironomus was found in the springs of Barbado Stream, which may indicate preservation of the area. During the study period, we found 40.3 and 94.4 individuals/m2 at points 3 and 4 (low course, respectively. There is eutrophication in these sites due to domestic sewage discharges, indicating low quality water. The Barbado Stream needs restoration projects that include an awareness of the residents of their neighborhood’s environmental importance, and investments in the sanitation sector to prioritize the collection and treatment of wastewater and solid waste collection.

  19. Functionalized sio2 microspheres for extracting oil from produced water

    KAUST Repository

    Mishra, Himanshu; Farinha, A. S. F.; Sinha, Shahnawaz

    2017-01-01

    Functionalized material, methods of producing the functionalized material, and use thereof for separation processes such as but not limited to use for separating and extracting a dissolved organic foulant, charged contaminant or oily matter or any

  20. From Waste to Wealth: Using Produced Water for Agriculture in Colorado

    Science.gov (United States)

    Dolan, F.; Hogue, T. S.

    2017-12-01

    According to estimates from the Colorado Water Plan, the state's population may double by 2050. Due to increasing demand, as much as 0.8 million irrigated acres may dry up statewide from agricultural to municipal and industrial transfers. To help mitigate this loss, new sources of water are being explored in Colorado. One such source may be produced water. Oil and gas production in 2016 alone produced over 300 million barrels of produced water. Currently, the most common method of disposal of produced water is deep well injection, which is costly and has been shown to cause induced seismicity. Treating this water to agricultural standards eliminates the need to dispose of this water and provides a new source of water. This research explores which counties in Colorado may be best suited to reusing produced water for agriculture based on a combined index of need, quality of produced water, and quantity of produced water. The volumetric impact of using produced water for agricultural needs is determined for the top six counties. Irrigation demand is obtained using evapotranspiration estimates from a range of methods, including remote sensing products and ground-based observations. The economic feasibility of treating produced water to irrigation standards is also determined using treatment costs found in the literature and disposal costs in each county. Finally, data from the IHS database is used to obtain the ratio between hydraulic fracturing fluid volumes and produced water volumes in each county. The results of this research will aid in the transition between viewing produced water as a waste product and using it as a tool to help secure water for the arid West.

  1. Methods and Sources of Data Used to Develop Selected Water-Quality Indicators for Streams and Ground Water for EPA's 2007 Report on the Environment: Science Report

    Science.gov (United States)

    Baker, Nancy T.; Wilson, John T.; Moran, Michael J.

    2008-01-01

    The U.S. Geological Survey (USGS) was one of numerous governmental agencies, private organizations, and the academic community that provided data and interpretations for the U.S. Environmental Protection Agency?s (USEPA) 2007 Report on the Environment: Science Report. This report documents the sources of data and methods used to develop selected water?quality indicators for the 2007 edition of the report compiled by USEPA. Stream and ground?water?quality data collected nationally in a consistent manner as part of the USGS?s National Water?Quality Assessment Program (NAWQA) were provided for several water?quality indicators, including Nitrogen and Phosphorus in Streams in Agricultural Watersheds; Pesticides in Streams in Agricultural Watersheds; and Nitrate and Pesticides in Shallow Ground Water in Agricultural Watersheds. In addition, the USGS provided nitrate (nitrate plus nitrite) and phosphorus riverine load estimates calculated from water?quality and streamflow data collected as part of its National Stream Water Quality Accounting Network (NASQAN) and its Federal?State Cooperative Program for the Nitrogen and Phosphorus Discharge from Large Rivers indicator.

  2. Dissolved pesticides, dissolved organic carbon, and water-quality characteristics in selected Idaho streams, April--December 2010

    Science.gov (United States)

    Reilly, Timothy J.; Smalling, Kelly L.; Wilson, Emma R.; Battaglin, William A.

    2012-01-01

    Water-quality samples were collected from April through December 2010 from four streams in Idaho and analyzed for a suite of pesticides, including fungicides, by the U.S. Geological Survey. Water samples were collected from two agricultural and two nonagricultural (control) streams approximately biweekly from the beginning of the growing season (April) through the end of the calendar year (December). Samples were analyzed for 90 pesticides using gas chromatography/mass spectrometry. Twenty-three pesticides, including 8 fungicides, 10 herbicides, 3 insecticides, and 2 pesticide degradates, were detected in 45 water samples. The most frequently detected compounds in the two agricultural streams and their detection frequencies were metolachlor, 96 percent; azoxystrobin, 79 percent; boscalid, 79 percent; atrazine, 46 percent; pendimethalin, 33 percent; and trifluralin, 33 percent. Dissolved-pesticide concentrations ranged from below instrumental limits of detection (0.5-1.0 nanograms per liter) to 771 nanograms per liter (hexazinone). The total number of pesticides detected in any given water sample ranged from 0 to 11. Only three pesticides (atrazine, fipronil, and simazine) were detected in samples from the control streams during the sampling period.

  3. Influence of bedrock geology on water chemistry of slope wetlands and headwater streams in the southern Rocky Mountains

    Science.gov (United States)

    Monique LaPerriere Nelson; Charles C. Rhoades; Kathleen A. Dwire

    2011-01-01

    We characterized the water chemistry of nine slope wetlands and adjacent headwater streams in Colorado subalpine forests and compared sites in basins formed on crystalline bedrock with those formed in basins with a mixture of crystalline and sedimentary bedrock. The pH, Ca2+, Mg2+, NH4 +, acid neutralizing capacity, and electrical conductivity of wetland porewater and...

  4. Mediating water temperature increases due to livestock and global change in high elevation meadow streams of the Golden Trout Wilderness

    Science.gov (United States)

    Sebastien Nussle; Kathleen R. Matthews; Stephanie M. Carlson

    2015-01-01

    Rising temperatures due to climate change are pushing the thermal limits of many species, but how climate warming interacts with other anthropogenic disturbances such as land use remains poorly understood. To understand the interactive effects of climate warming and livestock grazing on water temperature in three high elevation meadow streams in the Golden Trout...

  5. Effects of soil data resolution on SWAT model stream flow and water quality predictions.

    Science.gov (United States)

    Geza, Mengistu; McCray, John E

    2008-08-01

    The prediction accuracy of agricultural nonpoint source pollution models such as Soil and Water Assessment Tool (SWAT) depends on how well model input spatial parameters describe the characteristics of the watershed. The objective of this study was to assess the effects of different soil data resolutions on stream flow, sediment and nutrient predictions when used as input for SWAT. SWAT model predictions were compared for the two US Department of Agriculture soil databases with different resolution, namely the State Soil Geographic database (STATSGO) and the Soil Survey Geographic database (SSURGO). Same number of sub-basins was used in the watershed delineation. However, the number of HRUs generated when STATSGO and SSURGO soil data were used is 261 and 1301, respectively. SSURGO, with the highest spatial resolution, has 51 unique soil types in the watershed distributed in 1301 HRUs, while STATSGO has only three distributed in 261 HRUS. As a result of low resolution STATSGO assigns a single classification to areas that may have different soil types if SSURGO were used. SSURGO included Hydrologic Response Units (HRUs) with soil types that were generalized to one soil group in STATSGO. The difference in the number and size of HRUs also has an effect on sediment yield parameters (slope and slope length). Thus, as a result of the discrepancies in soil type and size of HRUs stream flow predicted was higher when SSURGO was used compared to STATSGO. SSURGO predicted less stream loading than STATSGO in terms of sediment and sediment-attached nutrients components, and vice versa for dissolved nutrients. When compared to mean daily measured flow, STATSGO performed better relative to SSURGO before calibration. SSURGO provided better results after calibration as evaluated by R(2) value (0.74 compared to 0.61 for STATSGO) and the Nash-Sutcliffe coefficient of Efficiency (NSE) values (0.70 and 0.61 for SSURGO and STATSGO, respectively) although both are in the same satisfactory

  6. Variation in surface water-groundwater exchange with land use in an urban stream

    Science.gov (United States)

    Ryan, Robert J.; Welty, Claire; Larson, Philip C.

    2010-10-01

    SummaryA suite of methods is being utilized in the Baltimore metropolitan area to develop an understanding of the interaction between groundwater and surface water at multiple space and time scales. As part of this effort, bromide tracer experiments were conducted over two 10-day periods in August 2007 and May 2008 along two sections (each approximately 900 m long) of Dead Run, a small urban stream located in Baltimore County, Maryland, to investigate the influence of distinct zones of riparian land cover on surface-subsurface exchange and transient storage under low and high baseflow conditions. Riparian land cover varied by reach along a gradient of land use spanning parkland, suburban/residential, commercial, institutional, and transportation, and included wooded, meadow, turf grass, and impervious cover. Under summer low baseflow conditions, surface water-groundwater exchange, defined by gross inflow and gross outflow, was larger and net inflow (gross inflow minus gross outflow) had greater spatial variability, than was observed under spring high baseflow conditions. In addition, the fraction of nominal travel time attributable to transient storage ( Fmed) was lower and was more spatially variable under high baseflow conditions than under low baseflow conditions. The influence of baseflow condition on surface water-ground water exchange and transient storage was most evident in the subreaches with the least riparian forest cover and these effects are attributed to a lack of shading in reaches with little riparian forest cover. We suggest that under summer low baseflow conditions, the lack of shading allowed excess in-channel vegetation growth which acted as a transient storage zone and a conduit for outflow (i.e. uptake and evapotranspiration). Under spring high baseflow conditions the transient storage capacity of the channel was reduced because there was little in-channel vegetation.

  7. Measurement of dissolved Cs-137 in stream water, soil water and groundwater at Headwater Forested Catchment in Fukushima after Fukushima Dai-ichi Nuclear Power Plant Accident

    Science.gov (United States)

    Iwagami, Sho; Tsujimura, Maki; Onda, Yuichi; Sakakibara, Koichi; Konuma, Ryohei; Sato, Yutaro

    2016-04-01

    Radiocesium migration from headwater forested catchment is important perception as output from the forest which is also input to the subsequent various land use and downstream rivers after Fukushima Dai-ichi Nuclear Power Plant (FDNPP) accident. In this study, dissolved Cs-137 concentration of stream water, soil water and groundwater were measured. Observations were conducted at headwater catchment in Yamakiya district, located 35 km northwest of FDNPP from April 2014 to November 2015. Stream water discharge was monitored and stream water samples were taken at main channel and sub channel. Stream water discharge was monitored by combination of parshallflume and v-notch weir. Stream water was sampled manually at steady state condition in 3-4 month interval and also intense few hours interval sampling were conducted during rainfall events using automated water sampler. Around the sub channel, it is found that there is a regularly saturated area at the bottom of the slope, temporary saturated area which saturate during the rainy season in summer and regularly dry area. 6 interval cameras were installed to monitor the changing situation of saturated area. Suction lysimeters were installed at three areas (regularly saturated area, temporary saturated area and dry area) for sampling soil water in depth of 0.1 m and 0.3 m. Boreholes were installed at three points along the sub channel. Three boreholes with depth of 3 m, 5 m and 10 m were installed at temporary saturated area, 20 m upstream of sub channel weir. Another three boreholes with depth of 3 m, 5 m and 10 m were installed at dry area, 40 m upstream of sub channel weir. And a borehole with depth of 20 m was installed at ridge of sub catchment, 52 m upstream of sub channel weir. Groundwater was sampled by electrically powered pump and groundwater level was monitored. Also suction-free lysimeter was installed at temporary saturated area for sampling the near surface subsurface water. Soil water samples were collected

  8. Hydrography - Streams and Shorelines

    Data.gov (United States)

    California Natural Resource Agency — The hydrography layer consists of flowing waters (rivers and streams), standing waters (lakes and ponds), and wetlands -- both natural and manmade. Two separate...

  9. Quality of Sachet Water Produced at Tarkwa, Ghana | Ndur | Ghana ...

    African Journals Online (AJOL)

    Cholera outbreak in some cities and towns in Ghana in early 2011 necessitated a sachet water quality study in Tarkwa to determine their wholesomeness. The study was conducted in four phases in August 2011, December 2011, August 2012 and December, 2013. Most of the physico-chemical parameters analysed were ...

  10. Effects of produced waters at oilfield production sites on the Osage Indian Reservation, northeastern Oklahoma

    Science.gov (United States)

    Otton, James K.; Asher-Bolinder, Sigrid; Owen, Douglass E.; Hall, Laurel

    1997-01-01

    The authors conducted limited site surveys in the Wildhorse and Burbank oilfields on the Osage Indian Reservation, northeastern Oklahoma. The purpose was to document salt scarring, erosion, and soil and water salinization, to survey for radioactivity in oilfield equipment, and to determine if trace elements and naturally occurring radioactive materials (NORM) were present in soils affected by oilfield solid waste and produced waters. These surveys were also designed to see if field gamma spectrometry and field soil conductivity measurements were useful in screening for NORM contamination and soil salinity at these sites. Visits to oilfield production sites in the Wildhorse field in June of 1995 and 1996 confirmed the presence of substantial salt scarring, soil salinization, and slight to locally severe erosion. Levels of radioactivity on some oil field equipment, soils, and road surfaces exceed proposed state standards. Radium activities in soils affected by tank sludge and produced waters also locally exceed proposed state standards. Laboratory analyses of samples from two sites show moderate levels of copper, lead, and zinc in brine-affected soils and pipe scale. Several sites showed detectable levels of bromine and iodine, suggesting that these trace elements may be present in sufficient quantity to inhibit plant growth. Surface waters in streams at two sampled sites exceed total dissolved solid limits for drinking waters. At one site in the Wildhorse field, an EM survey showed that saline soils in the upper 6m extend from a surface salt scar downvalley about 150 m. (Photo [95k]: Dead oak trees and partly revegetated salt scar at Site OS95-2 in the Wildhorse field, Osage County, Oklahoma.) In the Burbank field, limited salt scarring and slight erosion occurs in soils at some sites and low to moderate levels of radioactivity were observed in oil field equipment at some sites. The levels of radioactivity and radium observed in some soils and equipment at these

  11. Produced water reinjection in Campos Basin; Reinjecao de agua produzida na Bacia de Campos

    Energy Technology Data Exchange (ETDEWEB)

    Mendes, Roberta A.; Furtado, Claudio J.A.; Luz Junior, Euripedes B. [PETROBRAS S.A., Rio de Janeiro, RJ (Brazil)

    2008-07-01

    To manage the increasing volume of produced water became one of the main challenges in the petroleum industry. PWRI (produced water re-injection) leads to a decrease operational cost in platforms, an increase in liquid flow rates on the topside facilities and a decrease in surface disposal of water. Nowadays in Brazilian fields for every barrel of produced oil three barrels of water need to be handled. PWRI is a process that has been widely diffused in many fields in the world. The main advantages of the PWRI are to reduce collected water, to decrease or eliminate surface disposal of produced water, and to help oil recovery. On the other hand, PWRI tends to increase corrosion when inappropriate materials in tubing and pipelines are used; increase souring potential due to the amount of nutrients for bacteria in the produced water; increase scale formation when sea-water and produced water are mixed and increase formation damage. Even in reservoirs with good qualities in terms of permeability and porosity, the poor quality of the reinjection water decreases injectivity. To minimize injectivity loss some requirements are important: to avoid solids in the produced water system, to inject above fracture propagation pressure to maintain injectivity whenever possible, to use compatible the chemical products for oil-water separation to avoid the formation solids-oil agglomerates. (author)

  12. Evaluation of Measurements Collected with Multi-Parameter Continuous Water-Quality Monitors in Selected Illinois Streams, 2001-03

    Science.gov (United States)

    Groschen, George E.; King, Robin B.

    2005-01-01

    Eight streams, representing a wide range of environmental and water-quality conditions across Illinois, were monitored from July 2001 to October 2003 for five water-quality parameters as part of a pilot study by the U.S. Geological Survey (USGS) in cooperation with the Illinois Environmental Protection Agency (IEPA). Continuous recording multi-parameter water-quality monitors were installed to collect data on water temperature, dissolved-oxygen concentrations, specific conductivity, pH, and turbidity. The monitors were near USGS streamflow-gaging stations where stage and streamflow are continuously recorded. During the study period, the data collected for these five parameters generally met the data-quality objectives established by the USGS and IEPA at all eight stations. A similar pilot study during this period for measurement of chlorophyll concentrations failed to achieve the data-quality objectives. Of all the sensors used, the temperature sensors provided the most accurate and reliable measurements (generally within ?5 percent of a calibrated thermometer reading). Signal adjustments and calibration of all other sensors are dependent upon an accurate and precise temperature measurement. The dissolved-oxygen sensors were the next most reliable during the study and were responsive to changing conditions and accurate at all eight stations. Specific conductivity was the third most accurate and reliable measurement collected from the multi-parameter monitors. Specific conductivity at the eight stations varied widely-from less than 40 microsiemens (?S) at Rayse Creek near Waltonville to greater than 3,500 ?S at Salt Creek at Western Springs. In individual streams, specific conductivity often changed quickly (greater than 25 percent in less than 3 hours) and the sensors generally provided good to excellent record of these variations at all stations. The widest range of specific-conductivity measurements was in Salt Creek at Western Springs in the Greater Chicago

  13. The effect of restored and native oxbows on hydraulic loads of nutrients and stream water quality

    Science.gov (United States)

    Kalkhoff, Stephen J.; Hubbard, Laura E.; Joseph P.Schubauer-Berigan,

    2016-01-01

    The use of oxbow wetlands has been identified as a potential strategy to reduce nutrient transport from agricultural drainage tiles to streams in Iowa. In 2013 and 2014, a study was conducted in north-central Iowa in a native oxbow in the Lyons Creek watershed and two restored oxbow wetlands in the Prairie Creek watershed (Smeltzer west and Smeltzer east) to assess their effectiveness at reducing nitrogen and phosphorus loads. The tile line inlets carrying agricultural runoff to the oxbows, the outfall from the oxbows, and the surface waters in the streams receiving the outfall water were monitored for discharge and nutrients from February 2013 to September 2015. Smeltzer west and east also had four monitoring wells each, two in the upland and two between the oxbow and Prairie Creek to monitor surface water-groundwater interaction. The Smeltzer west and east oxbow sites also were instrumented to continuously measure the nitrate concentration. Rainfall was measured at one Lyons Creek and one Smeltzer site. Daily mean nitrate-N concentrations in Lyons Creek in 2013 ranged from 11.8 mg/L to 40.9 mg/L, the median daily mean nitrate-N concentration was 33.0 mg/L. Daily mean nitrate-N concentrations in Prairie Creek in 2013 ranged from 0.07 mg/L in August to 32.2 mg/L in June. In 2014, daily mean nitrate-N concentrations in Prairie Creek ranged from 0.17 mg/L in April to 26.7 mg/L in July; the daily mean nitrate-N concentration for the sampled period was 9.78 mg/L. Nutrient load reduction occurred in oxbow wetlands in Lyons and Prairie Creek watersheds in north-central Iowa but efficiency of reduction was variable. Little nutrient reduction occurred in the native Lyons Creek oxbow during 2013. Concentrations of all nutrient constituents were not significantly (P>0.05, Wilcoxon rank sum) different in water discharging from the tile line than in water leaving the Lyons Creek oxbow. A combination of physical features and flow conditions suggest that the residence time of

  14. Desalination and reuse of high-salinity shale gas produced water: drivers, technologies, and future directions.

    Science.gov (United States)

    Shaffer, Devin L; Arias Chavez, Laura H; Ben-Sasson, Moshe; Romero-Vargas Castrillón, Santiago; Yip, Ngai Yin; Elimelech, Menachem

    2013-09-03

    In the rapidly developing shale gas industry, managing produced water is a major challenge for maintaining the profitability of shale gas extraction while protecting public health and the environment. We review the current state of practice for produced water management across the United States and discuss the interrelated regulatory, infrastructure, and economic drivers for produced water reuse. Within this framework, we examine the Marcellus shale play, a region in the eastern United States where produced water is currently reused without desalination. In the Marcellus region, and in other shale plays worldwide with similar constraints, contraction of current reuse opportunities within the shale gas industry and growing restrictions on produced water disposal will provide strong incentives for produced water desalination for reuse outside the industry. The most challenging scenarios for the selection of desalination for reuse over other management strategies will be those involving high-salinity produced water, which must be desalinated with thermal separation processes. We explore desalination technologies for treatment of high-salinity shale gas produced water, and we critically review mechanical vapor compression (MVC), membrane distillation (MD), and forward osmosis (FO) as the technologies best suited for desalination of high-salinity produced water for reuse outside the shale gas industry. The advantages and challenges of applying MVC, MD, and FO technologies to produced water desalination are discussed, and directions for future research and development are identified. We find that desalination for reuse of produced water is technically feasible and can be economically relevant. However, because produced water management is primarily an economic decision, expanding desalination for reuse is dependent on process and material improvements to reduce capital and operating costs.

  15. Energy consumption in desalinating produced water from shale oil and gas extraction

    OpenAIRE

    Tow, Emily W.; Chung, Hyung Won; Lienhard, John H.; Thiel, Gregory Parker; Banchik, Leonardo David

    2014-01-01

    On-site treatment and reuse is an increasingly preferred option for produced water management in unconventional oil and gas extraction. This paper analyzes and compares the energetics of several desalination technologies at the high salinities and diverse compositions commonly encountered in produced water from shale formations to guide technology selection and to inform further system development. Produced water properties are modeled using Pitzer's equations, and emphasis is placed on how t...

  16. Water Quality Assessment of Streams and Wetlands in a Fast Growing East African City

    Directory of Open Access Journals (Sweden)

    Niels De Troyer

    2016-03-01

    Full Text Available The combination of rapid urbanization, industrialization, population growth, and low environmental awareness poses a major threat to worldwide valuable freshwater resources, which provide important ecosystem services to humans. There is an urgent need to monitor and assess these resources, as this information is indispensable for sustainable decision-making and management. In this context, we analyzed the chemical and ecological water quality of the riverine environment of a fast growing city in Southwest Ethiopia for which we proposed possible remediation options that were evaluated with an empirical model. The chemical and ecological water quality was assessed at 53 sampling locations using the oxygen Prati index and the ETHbios, which is a biotic index based on macroinvertebrates. In addition, a microbiological analysis was performed to estimate the degree of fecal contamination. Finally, we analyzed the relationship between the oxygen content and the organic pollution to simulate the effect of organics removal from waste streams on the chemical water quality. Our results showed that the average values for dissolved oxygen (4.2 mg DO·L−1 and nutrients (0.9 mg oPO43−·L−1 and 12.8 mg TAN·L−1 exceeded international standards. Moreover, high turbidity levels revealed that land erosion is a severe problem in the region. Along the rivers, a significant increase in oxygen consumption and in nutrient concentrations was observed, indicating organic pollution originating from different diffuse and point sources of pollution. The lack of proper sanitation also led to exceedingly high abundances of fecal coliforms in the surface water (>320 MPN·mL−1. However, fecal contamination was strongly reduced (>92% after the polluted river water passed Boye wetland, indicating the purification potential of natural wetlands and the importance of conserving and protecting those ecosystems. The simulation results of the model showed that water quality

  17. Ground Water is a Chronic Source of Chloride to Surface Water of an Urban Stream Exposed to Road Salt in a Chesapeake Bay Watershed

    Science.gov (United States)

    Mayer, P.; Doheny, E.; Kaushal, S.; Groffman, P.; Striz, E.

    2006-05-01

    Recent evidence from the mid-Atlantic suggests that freshwater supplies are threatened by chronic chloride inputs from road salts applied to improve highway safety. Elevated chloride levels also may limit the ability of aquatic systems to microbially process nitrate nitrogen, a nutrient whose elevated levels pose human and ecological threats. Understanding the behavior of chloride in urban watersheds where road salts are applied is critical to predicting subsequent impacts to ecosystem health and drinking water supplies. Here we report on a long-term study of water chemistry in Minebank Run, a recently restored stream in an urban watershed of Towson, MD that receives chronic chloride inputs from the 695 Beltway highway and connecting arteries. Chloride, sodium, and specific conductance were greatly elevated in the both surface water and ground water of Minebank Run, spiking in correspondence to road salt application in the winter. Chloride levels were consistently higher in ground water of the bank side of a minor roadway and downstream of the 695 Beltway. Surface water chloride levels remained elevated throughout the year apparently because ground water continued to supply surface water with chloride even after road salt application ceased. Thus, ground water may represent a chronic source of chloride to surface water, thereby contributing to the upward trend in freshwater salinity in urbanizing areas. Stream susceptibility to road salt impacts may depend upon ground water hydrology and stream geomorphology. However, geomorphic stream restoration practices widely used in the mid-Atlantic are not designed to address salinity effects. Source control of road salts may be necessary to reduce environmental risk.

  18. Quantifying in-stream nitrate reaction rates using continuously-collected water quality data

    Science.gov (United States)

    Matthew Miller; Anthony Tesoriero; Paul Capel

    2016-01-01

    High frequency in situ nitrate data from three streams of varying hydrologic condition, land use, and watershed size were used to quantify the mass loading of nitrate to streams from two sources – groundwater discharge and event flow – at a daily time step for one year. These estimated loadings were used to quantify temporally-variable in-stream nitrate processing ...

  19. Stream water quality in the context of payments for environmental services in Southeastern Brazil

    Science.gov (United States)

    Piccolo, M. C.; Reis, L. D. C.; Figueiredo, R. D. O.; Camargo, P. B. D.; Costa, C. F. G. D.; Zuccari, M. L.; Green, T. R.

    2015-12-01

    Public policy of payment for environmental services (PES) was established in 2007 to face the challenge of recuperatingwater resources at one of the headwater areas of the Jaguari River Basin, which supplies an important reservoir for the metropolitan region of São Paulo, Brazil. Such effort consists of reforestation of riparian zones and spring lands at the hills of selected catchments, including the Ribeirão das Posses (RP) catchment. Since 2012 the University of São Paulo has developed research at RP to monitor the benefits of these practices on stream water quality, and identified a few parameters as good indicators to follow up the results of this PES program. The present study has the objective to show results of the monthly monitoring in2015,including 13 sampling stations at RP catchment distributed as follows: one in a spring forested area, three in spring areas of different ages of reforestation (3, 5 and 8 years), and nine at reaches of RP streamlocated in a way to contemplate the effects of the first order streams that comes from the studied spring areas entering RP. We established two additional stations at the Jaguari River, upstream and downstream of RP outlet. In situ measurements include temperature, pH, electric conductivity (EC) and dissolved oxygen (DO), and collect water samples to bring to the laboratory for analyses of dissolved organic and inorganic carbon (DOC and DIC), total nitrogen (TN) and alkalinity. Also, sediments (fine fraction: >0.45 μm; and coarse fraction: >63 μm) are collected for isotopic carbon analyses. Preliminary results show pH values ranging from 5.5 to 7.8, while DO ranges from 5.8 to 8.9 mg L-1. As for EC, the mean at the spring forested station was 34.6 μS cm-1, while at spring areas of 3, 6 and 8 years of reforestation they were 53.3, 73.8 and 34.8 μS cm-1, respectively. We expected that by the end of this annual monitoring the benefits of reforestation will be affirmed.

  20. Polyoxadiazole hollow fibers for produced water treatment by direct contact membrane distillation

    KAUST Repository

    Xu, Jingli; Srivatsa Bettahalli, N.M.; Chisca, Stefan; Khalid, Mohammed Khalil; Ghaffour, NorEddine; Vilagines, Ré gis; Nunes, Suzana Pereira

    2018-01-01

    Treatment of produced water in the petroleum industry has been a challenge worldwide. In this study, we evaluated the use of direct contact membrane distillation (DCMD) for this purpose, removing oil and dissolved elements and supplying clean water

  1. Process for the exchange of hydrogen isotopes between streams of liquid water and gaseous halohydrocarbon and an apparatus therefor

    International Nuclear Information System (INIS)

    Symons, E. A.; Clermont, M. J.; Paterson, L. M.; Rolston, J. H.

    1985-01-01

    Hydrogen isotope (e.g. deuterium) exchange from liquid water to a gaseous halohydrocarbon (e.g. fluoroform, CF 3 H-CF 3 D) is obtained at an operating temperature in the range 0 0 to 100 0 C. using a catalytically active mass comprising a porous anion exchange resin in the hydroxide ion form and enriched gaseous halohydrocarbon stream is decomposed by isotope selective photo-decomposition into a first, gaseous stream enriched in the hydrogen isotope, which is removed as a product, and a depleted gaseous halohydrocarbon stream, which is recirculated for enrichment again. The catalytically active mass may, for example, be in the form of resin particles suspended in a fluidized bed or packed as resin particles between sheets wound into a roll. One of the sheets may be corrugated and have open interstices to form a packing in a column which permits countercurrent gas and liquid flow past the resin. Preferably the wound sheets are hydrophilic to retard flooding by the liquid water. The liquid water stream may contain dimethyl sulfoxide (DMSO) added as co-solvent

  2. Characterization of NORM material produced in a water treatment plant

    Energy Technology Data Exchange (ETDEWEB)

    Suursoo, S.; Kiisk, M.; Jantsikene, A.; Koch, R.; Isakar, K.; Realo, E. [University of Tartu, Institute of Physics (Estonia); Lumiste, L. [Tallinn University of Technology (Estonia)

    2014-07-01

    In February 2012 a water treatment plant was opened in Viimsi, Estonia. The plant is designed for removal of iron, manganese, and radium from groundwater. The first 2 years of operation have shown that the purification process generates significant amounts of materials with elevated radium levels. The treatment plant is fed by nine wells, which open to radium-rich aquifers. Purification is achieved by aeration and filtration processes. Aerated water is led through two successive filter columns, first of them is filled with MnO{sub 2} coated material FMH and filtration sand, the second one with zeolite. The plant has five parallel treatment lines with a total of 95 tons of FMH + filtration sand, and 45 tons of zeolite. The average capacity of the facility has been 2400 m{sup 3}/day. Yearly input of radium to the plant is estimated to be 325 MBq for Ra-226, and 420 MBq for Ra-228. Most of the radium (about 90%) accumulates in the filter columns. Some 8-9% of it is removed by backwash water during regular filter backwash cycles. To characterize radium accumulation and its removal by backwash in detail, treatment line no. 5 is sampled monthly for filter materials and backwash water. A steady growth of radium activity concentrations is apparent in both filter materials. In the top layer of the first stage filter (FMH+sand), Ra-226 and Ra-228 activity concentrations (per unit dry weight) reached (1540 ± 60) Bq/kg and (2510 ± 50) Bq/kg (k=2), respectively, by April 2013. At the same time, radium content in the top layer of the second stage filter (zeolite) was an order of magnitude higher: (19 600 ± 130) Bq/kg for Ra-226, and (22 260 ± 170) Bq/kg for Ra-228 (k=2). Radium is not evenly distributed throughout the filter columns. A rough estimate can be given that after 1.25 years of operation (by April 2013) the accumulated activities in treatment line no. 5 reached 1000 MBq for Ra-226 and 1200 MBq for Ra-228. Although filters are the most important type of NORM

  3. Water chemistry in 179 randomly selected Swedish headwater streams related to forest production, clear-felling and climate.

    Science.gov (United States)

    Löfgren, Stefan; Fröberg, Mats; Yu, Jun; Nisell, Jakob; Ranneby, Bo

    2014-12-01

    From a policy perspective, it is important to understand forestry effects on surface waters from a landscape perspective. The EU Water Framework Directive demands remedial actions if not achieving good ecological status. In Sweden, 44 % of the surface water bodies have moderate ecological status or worse. Many of these drain catchments with a mosaic of managed forests. It is important for the forestry sector and water authorities to be able to identify where, in the forested landscape, special precautions are necessary. The aim of this study was to quantify the relations between forestry parameters and headwater stream concentrations of nutrients, organic matter and acid-base chemistry. The results are put into the context of regional climate, sulphur and nitrogen deposition, as well as marine influences. Water chemistry was measured in 179 randomly selected headwater streams from two regions in southwest and central Sweden, corresponding to 10 % of the Swedish land area. Forest status was determined from satellite images and Swedish National Forest Inventory data using the probabilistic classifier method, which was used to model stream water chemistry with Bayesian model averaging. The results indicate that concentrations of e.g. nitrogen, phosphorus and organic matter are related to factors associated with forest production but that it is not forestry per se that causes the excess losses. Instead, factors simultaneously affecting forest production and stream water chemistry, such as climate, extensive soil pools and nitrogen deposition, are the most likely candidates The relationships with clear-felled and wetland areas are likely to be direct effects.

  4. Dual pressurized light water reactor producing 2000 M We

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    2010-10-15

    The dual unit optimizer 2000 M We (Duo2000) is proposed as a new design concept for large nuclear power plant. Duo is being designed to meet economic and safety challenges facing the 21 century green and sustainable energy industry. Duo2000 has two nuclear steam supply systems (NSSS) of the unit nuclear optimizer (Uno) pressurized water reactor (PWR) in a single containment so as to double the capacity of the plant. Uno is anchored to the optimized power reactor 1000 M We (OPR1000) of the Korea Hydro and Nuclear Power Co., Ltd. The concept of Duo can be extended to any number of PWRs or pressurized heavy water reactors (PHWR s), or even boiling water reactor (BWRs). Once proven in water reactors, the technology may even be expanded to gas cooled, liquid metal cooled, and molten salt cooled reactors. In particular, since it is required that the small and medium sized reactors (SMRs) be built as units, the concept of Duo2000 will apply to SMRs as well. With its in-vessel retention as severe accident management strategy, Duo can not only put the single most querulous PWR safety issue to end, but also pave ways to most promising large power capacity dispensing with huge redesigning cost for generation III + nuclear systems. The strengths of Duo2000 include reducing the cost of construction by decreasing the number of containment buildings from two to one, minimizing the cost of NSSS and control systems by sharing between the dual units, and lessening the maintenance cost by uniting NSSS. The technology can further be extended to coupling modular reactors as dual, triple, or quadruple units to increase their economics, thus accelerating the commercialization as well as the customization of SMRs. (Author)

  5. The water quality of streams draining a plantation forest on gley soils: the Nant Tanllwyth, Plynlimon mid-Wales

    Directory of Open Access Journals (Sweden)

    C. Neal

    2004-01-01

    Full Text Available The water quality of the Nant Tanllwyth stream in the Plynlimon region of mid-Wales is related to the key hydrobiogeological controls and the effects of conifer harvesting based on an analysis of rain, cloud, stream and groundwater measurements. The results show the normal patterns of stream water quality response to hydrology. Thus, there is a high damping of atmospheric inputs due to storage in a highly heterogeneous soil and groundwater system. Correspondingly, there is a highly dynamic response for components such as calcium, bicarbonate and aluminium. This response links to the relative inputs of acidic and aluminium-bearing soil waters under high flow conditions and base enriched bicarbonate bearing waters from the groundwater areas under baseflow conditions. The introduction of a deep borehole near the main stem of the river opened up a groundwater flow route to the stream and other parts of the catchment. There were two aspects to this. Firstly, it caused a change to the stream water quality, particularly under baseflow conditions, by increasing the concentrations of calcium and magnesium and by reducing the acidity. The monitoring shows that this change has persisted for over eight years and that there is no sign of reversion to pre-borehole times. Secondly, it caused a change in the groundwater level and chemistry at a borehole on the other side of the river. This feature shows that the fracture system is of hydrogeochemical and hydrogeological complexity. The effects of conifer harvesting are remarkable. At the local scale, felling leads to the expected short term increase in nitrate, ammonium and phosphate from the disturbance of the soil and the reduction in uptake into the vegetation. Correspondingly, there is a reduction in sodium and chloride linked to reduced scavenging of atmospheric inputs from cloud water by the vegetation and also due to increased dilution potential due to reductions in transpiration by the trees. However

  6. Effect of Disinfectants on Preventing the Cross-Contamination of Pathogens in Fresh Produce Washing Water

    NARCIS (Netherlands)

    Banach, J.L.; Sampers, I.; Haute, van S.; Fels, van der H.J.

    2015-01-01

    The potential cross-contamination of pathogens between clean and contaminated produce in the washing tank is highly dependent on the water quality. Process wash water disinfectants are applied to maintain the water quality during processing. The review examines the efficacy of process wash water

  7. Is it possible to treat produced water for recycle and beneficial reuse?

    Energy Technology Data Exchange (ETDEWEB)

    Hum, F.; Tsang, P.; Kantzas, A.; Harding, T. [Calgary Univ., AB (Canada). Tomographic Imaging and Porous Media Laboratory

    2005-11-01

    In 2003, the oil and gas industry in Alberta injected 0.3 billion cubic metres of produced water into disposal wells. This paper addressed the issue of using the large volume of produced water for recycling and make water reuse a sustainable activity in Alberta to reduce fresh water demand. Although produced water represents a potential resource for recycling and beneficial reuse, it must first be treated to meet water quality criteria and regulatory guidelines for specific applications. A comprehensive technical and economic review of water treatment technologies was presented. Commonly used and new water desalination technologies were reviewed and key challenges associated with the recycling of produced water were identified. It was shown that water treatment processes are commercially available and that they are not prohibitively expensive. However, the cost of implementing treating processes to meet drinking water quality guidelines is about 3 times the current cost of municipal water supply in Alberta. For that reason, it is more feasible to recycle waste water for agricultural or petroleum applications, such as waterflooding. The water quality guidelines for these other purposes are less stringent than for drinking water and there is also growing public resistance for industry to use fresh water for commercial use. 42 refs., 3 tabs., 14 figs.

  8. Some physiochemical and heavy metal concentration in surface water streams of Tutuka in the Kenyasi mining catchment area

    Energy Technology Data Exchange (ETDEWEB)

    Boateng, Louis [University of Education, Winneba Ghana, P. O. Box 40, Mampong (Ghana)

    2013-07-01

    This research was conducted in the Akantansu stream of Tutuka in Kenyasi in the Brong Ahafo Region of Ghana in the months of October and November 2010 and January 2011. The major objectives of the study were to measure levels of pH, BOD (biochemical oxygen demand), lead, chromium, and arsenic in the Akantansu stream of Tutuka and to find ways that the community could ensure safe water use. To achieve the objectives of the study, sampling was done over a period of three months and data was collected and analyzed into graphs and ANOVA tables. The research revealed that the levels of arsenic and BOD were high as compared to the standards of WHO and EPA. If the people of Tutuka continue to use the stream, they may experience negative health effects (e.g., nausea, vomiting, diarrhea, etc.). The level of pH, chromium and lead was acceptable as compared to the standard of WHO and EPA. (authors)

  9. Experiments in water-macrophyte systems to uncover the dynamics of pesticide mitigation processes in vegetated surface waters/streams.

    Science.gov (United States)

    Stang, Christoph; Bakanov, Nikita; Schulz, Ralf

    2016-01-01

    Knowledge on the dynamics and the durability of the processes governing the mitigation of pesticide loads by aquatic vegetation in vegetated streams, which are characterized by dynamic discharge regimes and short chemical residence times, is scarce. In a static long-term experiment (48 h), the dissipation of five pesticides from the aqueous phase followed a biphasic pattern in the presence of aquatic macrophytes. A dynamic concentration decrease driven by sorption to the macrophytes ranged from 8.3 to 60.4% for isoproturon and bifenox, respectively, within the first 2 h of exposure. While the aqueous concentrations of imidacloprid, isoproturon, and tebufenozide remained constant thereafter, the continuous but decelerated concentration decrease of difenoconazole and bifenox in the water-macrophyte systems used here was assumed to be attributed to macrophyte-induced degradation processes. In addition, a semi-static short-term experiment was conducted, where macrophytes were transferred to uncontaminated medium after 2 h of exposure to simulate a transient pesticide peak. In the first part of the experiment, adsorption to macrophytes resulted in partitioning coefficients (logK D_Adsorp) ranging from 0.2 for imidacloprid to 2.2 for bifenox. One hour after the macrophytes were transferred to the uncontaminated medium, desorption of the compounds from the macrophytes resulted in a new phase equilibrium and K D_Desorp values of 1.46 for difenoconazole and 1.95 for bifenox were determined. A correlation analysis revealed the best match between the compound affinity to adsorb to macrophytes (expressed as K D_Adsorp) and their soil organic carbon-water partitioning coefficient (K OC) compared to their octanol-water partitioning coefficient (K OW) or a mathematically derived partitioning coefficient.

  10. Water management technologies used by Marcellus Shale Gas Producers.

    Energy Technology Data Exchange (ETDEWEB)

    Veil, J. A.; Environmental Science Division

    2010-07-30

    Natural gas represents an important energy source for the United States. According to the U.S. Department of Energy's (DOE's) Energy Information Administration (EIA), about 22% of the country's energy needs are provided by natural gas. Historically, natural gas was produced from conventional vertical wells drilled into porous hydrocarbon-containing formations. During the past decade, operators have increasingly looked to other unconventional sources of natural gas, such as coal bed methane, tight gas sands, and gas shales.

  11. The quality of our Nation's waters-Nutrients in the Nation's streams and groundwater, 1992-2004

    Science.gov (United States)

    Dubrovsky, N.M.; Burow, K.R.; Clark, G.M.; Gronberg, J.M.; Hamilton, P.A.; Hitt, K.J.; Mueller, D.K.; Munn, M.D.; Nolan, B.T.; Puckett, L.J.; Rupert, M.G.; Short, T.M.; Spahr, N.E.; Sprague, L.A.; Wilber, W.G.

    2010-01-01

    National Findings and Their Implications Although the use of artificial fertilizer has supported increasing food production to meet the needs of a growing population, increases in nutrient loadings from agricultural and, to a lesser extent, urban sources have resulted in nutrient concentrations in many streams and parts of aquifers that exceed standards for protection of human health and (or) aquatic life, often by large margins. Do NAWQA findings substantiate national concerns for aquatic and human health? National Water-Quality Assessment (NAWQA) findings indicate that nutrient concentrations in streams and groundwater in basins with significant agricultural or urban development are substantially greater than naturally occurring or ?background? levels. For example, median concentrations of total nitrogen and phosphorus in agricultural streams are about 6 times greater than background levels. Findings also indicate that concentrations in streams routinely were 2 to 10 times greater than regional nutrient criteria recommended by the U.S. Environmental Protection Agency (USEPA) to protect aquatic life. Such large differences in magnitude suggest that significant reductions in sources of nutrients, as well as greater use of land management strategies to reduce the transport of nutrients to streams, are needed to meet recommended criteria for streams draining areas with significant agricultural and urban development. Nitrate concentrations above the Federal drinking-water standard-or Maximum Contaminant Level (MCL)-of 10 milligrams per liter (mg/L, as nit-ogen) are relatively uncommon in samples from streams used for drinking water or from relatively deep aquifers; the MCL is exceeded, however, in more than 20 percent of shallow (less than 100 feet below the water table) domestic wells in agricultural areas. This finding raises concerns for human health in rural agricultural areas where shallow groundwater is used for domestic supply and may warn of future

  12. A dual pressurized water reactor producing 2000 MWe

    International Nuclear Information System (INIS)

    Kang, K. M.; Suh, K. Y.

    2010-01-01

    The Dual Unit Optimizer 2000 MWe (DUO2000) is proposed as a new design concept for large nuclear power plant. DUO is being designed to meet economic and safety challenges facing the 21. century green and sustainable energy industry. DUO2000 has two nuclear steam supply systems (NSSSs) of the Unit Nuclear Optimizer (UNO) pressurized water reactor (PWR) in a single containment so as to double the capacity of the plant. UNO is anchored to the Optimized Power Reactor 1000 MWe (OPR1000). The concept of DUO can be extended to any number of PWRs or pressurized heavy water reactors (PHWRs), or even boiling water reactor (BWRs). Once proven in water reactors, the technology may even be expanded to gas cooled, liquid metal cooled, and molten salt cooled reactors. In particular, since it is required that the Small and Medium sized Reactors (SMRs) be built as units, the concept of DUO2000 will apply to SMRs as well. With its in-vessel retention external reactor vessel cooling (IVR-ERVC) as severe accident management strategy, DUO can not only put the single most querulous PWR safety issue to end, but also pave ways to most promising large power capacity dispensing with huge redesigning cost for Generation III+ nuclear systems. Also, the strengths of DUO2000 include reducing the cost of construction by decreasing the number of containment buildings from two to one, minimizing the cost of NSSS and control systems by sharing between the dual units, and lessening the maintenance cost by uniting the NSSS. Two prototypes are presented for the DUO2000, and their respective advantages and drawbacks are considered. The strengths include, but are not necessarily limited to, reducing the cost of construction by decreasing the number of containment buildings from two to one, minimizing the cost of NSSS and control systems by sharing between the dual units, and lessening the maintenance cost by uniting the NSSS, just to name the few. The Coolant Unit Branching Apparatus (CUBA) is proposed

  13. POLICY ANALYSIS OF PRODUCED WATER ISSUES ASSOCIATED WITH IN-SITU THERMAL TECHNOLOGIES

    Energy Technology Data Exchange (ETDEWEB)

    Robert Keiter; John Ruple; Heather Tanana

    2011-02-01

    Commercial scale oil shale and oil sands development will require water, the amount of which will depend on the technologies adopted and the scale of development that occurs. Water in oil shale and oil sands country is already in scarce supply, and because of the arid nature of the region and limitations on water consumption imposed by interstate compacts and the Endangered Species Act, the State of Utah normally does not issue new water rights in oil shale or oil sands rich areas. Prospective oil shale and oil sands developers that do not already hold adequate water rights can acquire water rights from willing sellers, but large and secure water supplies may be difficult and expensive to acquire, driving oil shale and oil sands developers to seek alternative sources of supply. Produced water is one such potential source of supply. When oil and gas are developed, operators often encounter ground water that must be removed and disposed of to facilitate hydrocarbon extraction. Water produced through mineral extraction was traditionally poor in quality and treated as a waste product rather than a valuable resource. However, the increase in produced water volume and the often-higher quality water associated with coalbed methane development have drawn attention to potential uses of produced water and its treatment under appropriations law. This growing interest in produced water has led to litigation and statutory changes that must be understood and evaluated if produced water is to be harnessed in the oil shale and oil sands development process. Conversely, if water is generated as a byproduct of oil shale and oil sands production, consideration must be given to how this water will be disposed of or utilized in the shale oil production process. This report explores the role produced water could play in commercial oil shale and oil sands production, explaining the evolving regulatory framework associated with produced water, Utah water law and produced water regulation

  14. Interaction of Cu and plastic plasmas as a method of forming laser produced Cu plasma streams with a narrow jet or pipe geometry

    Czech Academy of Sciences Publication Activity Database

    Kasperczuk, A.; Pisarczyk, T.; Chodukowski, T.; Kalinowska, Z.; Parys, P.; Ullschmied, Jiří; Krouský, Eduard; Pfeifer, Miroslav; Skála, Jiří; Klir, D.; Kravarik, J.; Kubes, P.; Rezac, K.; Pisarczyk, P.

    2011-01-01

    Roč. 18, č. 4 (2011), 044503/1-044503/4 ISSN 1070-664X R&D Projects: GA MŠk(CZ) 7E09092; GA MŠk(CZ) LC528 Institutional research plan: CEZ:AV0Z20430508; CEZ:AV0Z10100523 Keywords : laser-produced plasma * plasma streams * Cu-plasma jets * laser targets Subject RIV: BH - Optics, Masers, Lasers Impact factor: 2.147, year: 2011 http://pop.aip.org/ resource /1/phpaen/v18/i4/p044503_s1

  15. Genes indicative of zoonotic and swine pathogens are persistent in stream water and sediment following a swine manure spill

    Science.gov (United States)

    Haack, Sheridan K.; Duris, Joseph W.; Kolpin, Dana W.; Fogarty, Lisa R.; Johnson, Heather E.; Gibson, Kristen E.; Focazio, Michael J.; Schwab, Kellogg J.; Hubbard, Laura E.; Foreman, William T.

    2015-01-01

    Manure spills to streams are relatively frequent, but no studies have characterized stream contamination with zoonotic and veterinary pathogens, or fecal chemicals, following a spill. We tested stream water and sediment over 25 days and downstream for 7.6 km for: fecal indicator bacteria (FIB); the fecal indicator chemicals cholesterol and coprostanol; 20 genes for zoonotic and swine-specific bacterial pathogens by presence/absence polymerase chain reaction (PCR) for viable cells; one swine-specific Escherichia coli toxin gene (STII) by quantitative PCR (qPCR); and nine human and animal viruses by qPCR, or reverse-transcriptase qPCR. Twelve days post-spill, and 4.2 km downstream, water concentrations of FIB, cholesterol, and coprostanol were 1-2 orders of magnitude greater than those detected before, or above, the spill, and genes indicating viable zoonotic or swine-infectious Escherichia coli, were detected in water or sediment. STII increased from undetectable before, or above the spill, to 105 copies/100 mL water 12 days post-spill. Thirteen of 14 water (8/9 sediment) samples had viable STII-carrying cells post-spill. Eighteen days post-spill porcine adenovirus and teschovirus were detected 5.6 km downstream. Sediment FIB concentrations (per gram wet weight) were greater than in water, and sediment was a continuous reservoir of genes and chemicals post-spill. Constituent concentrations were much lower, and detections less frequent, in a runoff event (200 days post-spill) following manure application, although the swine-associated STII and stx2e genes were detected. Manure spills are an underappreciated pathway for livestock-derived contaminants to enter streams, with persistent environmental outcomes, and the potential for human and veterinary health consequences.

  16. Recycled Coarse Aggregate Produced by Pulsed Discharge in Water

    Science.gov (United States)

    Namihira, Takao; Shigeishi, Mitsuhiro; Nakashima, Kazuyuki; Murakami, Akira; Kuroki, Kaori; Kiyan, Tsuyoshi; Tomoda, Yuichi; Sakugawa, Takashi; Katsuki, Sunao; Akiyama, Hidenori; Ohtsu, Masayasu

    In Japan, the recycling ratio of concrete scraps has been kept over 98 % after the Law for the Recycling of Construction Materials was enforced in 2000. In the present, most of concrete scraps were recycled as the Lower Subbase Course Material. On the other hand, it is predicted to be difficult to keep this higher recycling ratio in the near future because concrete scraps increase rapidly and would reach to over 3 times of present situation in 2010. In addition, the demand of concrete scraps as the Lower Subbase Course Material has been decreased. Therefore, new way to reuse concrete scraps must be developed. Concrete scraps normally consist of 70 % of coarse aggregate, 19 % of water and 11 % of cement. To obtain the higher recycling ratio, the higher recycling ratio of coarse aggregate is desired. In this paper, a new method for recycling coarse aggregate from concrete scraps has been developed and demonstrated. The system includes a Marx generator and a point to hemisphere mesh electrode immersed in water. In the demonstration, the test piece of concrete scrap was located between the electrodes and was treated by the pulsed discharge. After discharge treatment of test piece, the recycling coarse aggregates were evaluated under JIS and TS and had enough quality for utilization as the coarse aggregate.

  17. OPTIMIZATION OF PRODUCED WATER TREATMENT PROCESS - A CASE STUDY FOR DISPOSAL IN THE NIGER DELTA

    Directory of Open Access Journals (Sweden)

    BONIFACE A. ORIJI

    2017-12-01

    Full Text Available Produced water is the interstitial reservoir water that flows to the surface with the crude oil into the production separators. This study addressed the effects of some chemicals on produced water and the challenges of finding the optimal concentrations of these chemicals for treating produced water. In this study, produced water treatment was carried out in an oil production platform located in the Niger Delta so as to determine the effect of a particular scale inhibitor, biocide, demulsifier and water clarifier, also to obtain the optimum concentrations of these chemicals in the treatment of produced water. The physico-chemical properties and microbial content of the produced water were determined. The results showed that the conductivity, hardness, pH and alkalinity reduced with increasing concentration of the scale inhibitor. The total heterotrophic bacteria count (THBC, heterotrophic fungi count (THFC and the Sulphate reducing bacteria count (SRBC were found to reduce with increasing concentration of biocide and exposure time. The increase in biocide concentration from 64 PPM to 100 PPM resulted in the reduction of THBC by 99.78%, THFC by 81.32% and SRBC 99.85%. The water clarifier gave the optimum concentration for oil and grease in the produced water at 7.3 PPM.

  18. Application of carbon isotopes to detect seepage out of coalbed natural gas produced water impoundments

    International Nuclear Information System (INIS)

    Sharma, Shikha; Baggett, Joshua K.

    2011-01-01

    Highlights: → Coalbed natural gas extraction results in large amount of produced water. → Risk of deterioration of ambient water quality. → Carbon isotope natural tracer for detecting seepage from produced water impoundments. - Abstract: Coalbed natural gas (CBNG) production from coal bed aquifers requires large volumes of produced water to be pumped from the subsurface. The produced water ranges from high quality that meets state and federal drinking water standards to low quality due to increased salinity and/or sodicity. The Powder River Basin of northeastern Wyoming is a major coalbed natural gas producing region, where water quality generally decreases moving from the southeastern portion of the basin towards the center. Most produced water in Wyoming is disposed into impoundments and other surface drainages, where it may infiltrate into shallow groundwater. Groundwater degradation caused by infiltration of CBNG produced water holding impoundments into arid, soluble salt-rich soils is an issue of immense importance because groundwater is a major source for stock water, irrigation, and drinking water for many small communities in these areas. This study examines the potential of using stable C isotope signatures of dissolved inorganic C (δ 13 C DIC ) to track the fate of CBNG produced water after it is discharged into the impoundments. Other geochemical proxies like the major cations and major anions were used in conjunction with field water quality measurements to understand the geochemical differences between CBNG produced waters and ambient waters in the study area. Samples were collected from the CBNG discharge outfalls, produced water holding impoundments, and monitoring wells from different parts of the Powder River Basin and analyzed for δ 13 C DIC . The CBNG produced waters from outfalls and impoundments have positive δ 13 C DIC values that fall within the range of +12 per mille to +22 per mille, distinct from the ambient regional surface and

  19. Selective removal of lanthanides from natural waters, acidic streams and dialysate

    Energy Technology Data Exchange (ETDEWEB)

    Yantasee, Wassana, E-mail: wassana.yantasee@pnl.gov [Pacific Northwest National Laboratory (PNNL), P.O. Box 999, Richland, WA 99352 (United States); Fryxell, Glen E.; Addleman, R. Shane; Wiacek, Robert J.; Koonsiripaiboon, View; Pattamakomsan, Kanda; Sukwarotwat, Vichaya [Pacific Northwest National Laboratory (PNNL), P.O. Box 999, Richland, WA 99352 (United States); Xu Jide; Raymond, Kenneth N. [Chemistry Department, University of California, Berkeley, CA 94720 (United States); LBNL, Berkeley, CA 94720 (United States)

    2009-09-15

    The increased demand for the lanthanides in commercial products result in increased production of lanthanide containing ores, which increases public exposure to the lanthanides, both from various commercial products and from production wastes/effluents. This work investigates lanthanide (La, Ce, Pr, Nd, Eu, Gd and Lu) binding properties of self-assembled monolayers on mesoporous silica supports (SAMMS{sup TM}), that were functionalized with diphosphonic acid (DiPhos), acetamide phosphonic acid (AcPhos), propionamide phosphonic acid (Prop-Phos), and 1-hydroxy-2-pyridinone (1,2-HOPO), from natural waters (river, ground and sea waters), acid solutions (to mimic certain industrial process streams), and dialysate. The affinity, capacity, and kinetics of the lanthanide sorption, as well as regenerability of SAMMS materials were investigated. Going from the acid side over to the alkaline side, the AcPhos- and DiPhos-SAMMS maintain their outstanding affinity for lanthanides, which enable the use of the materials in the systems where the pH may fluctuate. In acid solutions, Prop-Phos- and 1,2-HOPO-SAMMS have differing affinity along the lanthanide series, suggesting their use in chromatographic lanthanide separation. Over 95% of 100 {mu}g/L of Gd in dialysate was removed by the Prop-Phos-SAMMS after 1 min and 99% over 10 min. SAMMS can be regenerated with an acid wash (0.5 M HCl) without losing the binding properties. Thus, they have a great potential to be used as in large-scale treatment of lanthanides, lanthanide separation prior to analytical instruments, and in sorbent dialyzers for treatment of acute lanthanide poisoning.

  20. Selective removal of lanthanides from natural waters, acidic streams and dialysate

    International Nuclear Information System (INIS)

    Yantasee, Wassana; Fryxell, Glen E.; Addleman, R. Shane; Wiacek, Robert J.; Koonsiripaiboon, View; Pattamakomsan, Kanda; Sukwarotwat, Vichaya; Xu Jide; Raymond, Kenneth N.

    2009-01-01

    The increased demand for the lanthanides in commercial products result in increased production of lanthanide containing ores, which increases public exposure to the lanthanides, both from various commercial products and from production wastes/effluents. This work investigates lanthanide (La, Ce, Pr, Nd, Eu, Gd and Lu) binding properties of self-assembled monolayers on mesoporous silica supports (SAMMS TM ), that were functionalized with diphosphonic acid (DiPhos), acetamide phosphonic acid (AcPhos), propionamide phosphonic acid (Prop-Phos), and 1-hydroxy-2-pyridinone (1,2-HOPO), from natural waters (river, ground and sea waters), acid solutions (to mimic certain industrial process streams), and dialysate. The affinity, capacity, and kinetics of the lanthanide sorption, as well as regenerability of SAMMS materials were investigated. Going from the acid side over to the alkaline side, the AcPhos- and DiPhos-SAMMS maintain their outstanding affinity for lanthanides, which enable the use of the materials in the systems where the pH may fluctuate. In acid solutions, Prop-Phos- and 1,2-HOPO-SAMMS have differing affinity along the lanthanide series, suggesting their use in chromatographic lanthanide separation. Over 95% of 100 μg/L of Gd in dialysate was removed by the Prop-Phos-SAMMS after 1 min and 99% over 10 min. SAMMS can be regenerated with an acid wash (0.5 M HCl) without losing the binding properties. Thus, they have a great potential to be used as in large-scale treatment of lanthanides, lanthanide separation prior to analytical instruments, and in sorbent dialyzers for treatment of acute lanthanide poisoning.

  1. Advanced Membrane Filtration Technology for Cost Effective Recovery of Fresh Water from Oil & Gas Produced Brine

    Energy Technology Data Exchange (ETDEWEB)

    David B. Burnett

    2004-09-29

    Produced water is a major waste generated at the oil and natural gas wells in the state of Texas. This water could be a possible source of new fresh water to meet the growing demands of the state after treatment and purification. Treatment of brine generated in oil fields or produced water with an ultrafiltration membranes were the subject of this thesis. The characterization of ultrafiltration membranes for oil and suspended solids removal of produced water, coupled with the reverse osmosis (RO) desalination of brine were studied on lab size membrane testing equipment and a field size testing unit to test whether a viable membrane system could be used to treat produced water. Oil and suspended solids were evaluated using turbidity and oil in water measurements taken periodically. The research considered the effect of pressure and flow rate on membrane performance of produced water treatment of three commercially available membranes for oily water. The study also analyzed the flux through the membrane and any effect it had on membrane performance. The research showed that an ultrafiltration membrane provided turbidity removal of over 99% and oil removal of 78% for the produced water samples. The results indicated that the ultrafiltration membranes would be asset as one of the first steps in purifying the water. Further results on selected RO membranes showed that salt rejection of greater than 97% could be achieved with satisfactory flux and at reasonable operating cost.

  2. Partitioning of semi-soluble organic compounds between the water phase and oil droplets in produced water

    Energy Technology Data Exchange (ETDEWEB)

    Faksness, Liv-Guri; Grini, Per Gerhard; Daling, Per S

    2004-04-01

    When selecting produced water treatment technologies, one should focus on reducing the major contributors to the total environmental impact. These are dispersed oil and semi-soluble hydrocarbons, alkylated phenols, and added chemicals. Experiments with produced water have been performed offshore on the Statoil operated platforms Gullfaks C and Statfjord B. These experiments were designed to find how much of the environmentally relevant compounds were dissolved in the water phase and not associated to the dispersed oil in the produced water. Results show that the distribution between the dispersed oil and the water phase varies highly for the different components groups. For example the concentration of PAHs and the C6-C9 alkylated phenols is strongly correlated to the content of dispersed oil. Therefore, the technologies enhancing the removal of dispersed oil have a higher potential for reducing the environmental impact of the produced water than previously considered.

  3. Partitioning of semi-soluble organic compounds between the water phase and oil droplets in produced water

    International Nuclear Information System (INIS)

    Faksness, Liv-Guri; Grini, Per Gerhard; Daling, Per S.

    2004-01-01

    When selecting produced water treatment technologies, one should focus on reducing the major contributors to the total environmental impact. These are dispersed oil and semi-soluble hydrocarbons, alkylated phenols, and added chemicals. Experiments with produced water have been performed offshore on the Statoil operated platforms Gullfaks C and Statfjord B. These experiments were designed to find how much of the environmentally relevant compounds were dissolved in the water phase and not associated to the dispersed oil in the produced water. Results show that the distribution between the dispersed oil and the water phase varies highly for the different components groups. For example the concentration of PAHs and the C6-C9 alkylated phenols is strongly correlated to the content of dispersed oil. Therefore, the technologies enhancing the removal of dispersed oil have a higher potential for reducing the environmental impact of the produced water than previously considered

  4. Some physiochemical and heavy metal concentration in surface water stream of Tutuka in the Kenyasi mining catchment area

    Directory of Open Access Journals (Sweden)

    B.M. Tiimub

    2012-09-01

    Full Text Available The research was conducted in the Akantansu stream of Tutuka in Kenyasi in the Brong Ahafo Region of Ghana from October 2010 to January 2011. The objectives of the study were to find out the contamination levels of pH, BOD5, Lead, Chromium, and Arsenic in the Akantansu stream of Tutuka to promote public health safety of people patronizing the stream for bathing and cooking. Determination of pH was achieved using Etech instrument (PC 300 series where as BOD5 level was assessed by means of empirical standard laboratory test which determined the relative oxygen requirements of waste water, effluents and polluted water using the standard procedure as per America Public Health Association (2006. An AAS 220 atomic absorption spectrometer was used for the analyses of heavy metals (lead, chromium and arsenic. The Research revealed that, the geometric mean levels of (0.01- 0.02, 0.03 – 0.26, 0 - 0.01, 3.99 – 7.06 mg/L and 5.64 – 6.40 for Arsenic, Lead, Chromium, BOD5 and pH compared to the EPA Maximum Permissible Limits of ( 0.5, 0.1, 0.1, 50 mg/L and 6-9 were respectively within the acceptable standards. However, due to slightly higher concentration of chromium (0.26 mg/L up the stream, the people of Tutuka may develop health effects such as nausea, vomiting, diarrhea, hallucinations, headaches, depression, sleeping disorders, skin cancers, tumours in lungs, bladder, kidney and liver if they continue to use water from the stream for bathing and cooking.

  5. A Molecular Explanation of How the Fog Is Produced When Dry Ice Is Placed in Water

    Science.gov (United States)

    Kuntzleman, Thomas S.; Ford, Nathan; No, Jin-Hwan; Ott, Mark E.

    2015-01-01

    Everyone enjoys seeing the cloudy white fog generated when solid carbon dioxide (dry ice) is placed in water. Have you ever wondered what physical and chemical processes occur to produce this fog? When asked this question, many chemical educators suggest that the fog is produced when atmospheric water vapor condenses on cold carbon dioxide gas…

  6. Barium in produced water: Is it a toxicological hazard to the marine environment?

    International Nuclear Information System (INIS)

    Neff, J.M.

    1993-01-01

    Produced water is a complex aqueous mixture of organic and inorganic chemicals that often is generated in large volumes as a by-product of production of oil and gas. Produced water from offshore oil production platforms sometimes is treated to remove particulate oil and then discharged to the ocean. Barium often is the most abundant inorganic chemical, other than the dominant sea salts, in produced water. Some concern has been expressed that the large amounts of barium discharged to the ocean in produced water may have adverse effects on marine biological communities. The ecological risks associated with discharge to the ocean in produced water may have adverse effects on marine biological communities. The ecological risks associated with discharge to the ocean of barium in produced water were evaluated. Concentrations of barium in produced water from different sources range from less than 1.0 to about 2,000 mg/L, and are inversely correlated with concentrations of sulfate. Concentrations of barium in the ocean usually are in the range of 10 to 20 μg/L; the ocean is undersaturated with respect to barite (BaSO 4 ). During mixing and dilution of a produced water plume in the ocean, barium reacts with the abundant sulfate in seawater and precipitates as barite. Barite is completely nontoxic to marine organisms. Because of the high concentration of sulfate in the ocean, ionic barium can not reach concentrations high enough to be toxic to marine organisms

  7. A Physically Based Analytical Model to Describe Effective Excess Charge for Streaming Potential Generation in Water Saturated Porous Media

    Science.gov (United States)

    Guarracino, L.; Jougnot, D.

    2018-01-01

    Among the different contributions generating self-potential, the streaming potential is of particular interest in hydrogeology for its sensitivity to water flow. Estimating water flux in porous media using streaming potential data relies on our capacity to understand, model, and upscale the electrokinetic coupling at the mineral-solution interface. Different approaches have been proposed to predict streaming potential generation in porous media. One of these approaches is the flux averaging which is based on determining the excess charge which is effectively dragged in the medium by water flow. In this study, we develop a physically based analytical model to predict the effective excess charge in saturated porous media using a flux-averaging approach in a bundle of capillary tubes with a fractal pore size distribution. The proposed model allows the determination of the effective excess charge as a function of pore water ionic concentration and hydrogeological parameters like porosity, permeability, and tortuosity. The new model has been successfully tested against different set of experimental data from the literature. One of the main findings of this study is the mechanistic explanation to the empirical dependence between the effective excess charge and the permeability that has been found by several researchers. The proposed model also highlights the link to other lithological properties, and it is able to reproduce the evolution of effective excess charge with electrolyte concentrations.

  8. Geostatistical prediction of microbial water quality throughout a stream network using meteorology, land cover, and spatiotemporal autocorrelation.

    Science.gov (United States)

    Holcomb, David Andrew; Messier, Kyle P; Serre, Marc L; Rowny, Jakob G; Stewart, Jill R

    2018-06-11

    Predictive modeling is promising as an inexpensive tool to assess water quality. We developed geostatistical predictive models of microbial water quality that empirically modelled spatiotemporal autocorrelation in measured fecal coliform (FC) bacteria concentrations to improve prediction. We compared five geostatistical models featuring different autocorrelation structures, fit to 676 observations from 19 locations in North Carolina's Jordan Lake watershed using meteorological and land cover predictor variables. Though stream distance metrics (with and without flow-weighting) failed to improve prediction over the Euclidean distance metric, incorporating temporal autocorrelation substantially improved prediction over the space-only models. We predicted FC throughout the stream network daily for one year, designating locations "impaired", "unimpaired", or "unassessed" if the probability of exceeding the state standard was >90%, 10% but <90%, respectively. We could assign impairment status to more of the stream network on days any FC were measured, suggesting frequent sample-based monitoring remains necessary, though implementing spatiotemporal predictive models may reduce the number of concurrent sampling locations required to adequately assess water quality. Together, these results suggest that prioritizing sampling at different times and conditions using geographically sparse monitoring networks is adequate to build robust and informative geostatistical models of water quality impairment.

  9. Organic substances in produced and formation water from unconventional natural gas extraction in coal and shale

    Science.gov (United States)

    Orem, William H.; Tatu, Calin A.; Varonka, Matthew S.; Lerch, Harry E.; Bates, Anne L.; Engle, Mark A.; Crosby, Lynn M.; McIntosh, Jennifer

    2014-01-01

    Organic substances in produced and formation water from coalbed methane (CBM) and gas shale plays from across the USA were examined in this study. Disposal of produced waters from gas extraction in coal and shale is an important environmental issue because of the large volumes of water involved and the variable quality of this water. Organic substances in produced water may be environmentally relevant as pollutants, but have been little studied. Results from five CBM plays and two gas shale plays (including the Marcellus Shale) show a myriad of organic chemicals present in the produced and formation water. Organic compound classes present in produced and formation water in CBM plays include: polycyclic aromatic hydrocarbons (PAHs), heterocyclic compounds, alkyl phenols, aromatic amines, alkyl aromatics (alkyl benzenes, alkyl biphenyls), long-chain fatty acids, and aliphatic hydrocarbons. Concentrations of individual compounds range from gas shale unimpacted by production chemicals have a similar range of compound classes as CBM produced water, and TOC levels of about 8 mg/L. However, produced water from the Marcellus Shale using hydraulic fracturing has TOC levels as high as 5500 mg/L and a range of added organic chemicals including, solvents, biocides, scale inhibitors, and other organic chemicals at levels of 1000 s of μg/L for individual compounds. Levels of these hydraulic fracturing chemicals and TOC decrease rapidly over the first 20 days of water recovery and some level of residual organic contaminants remain up to 250 days after hydraulic fracturing. Although the environmental impacts of the organics in produced water are not well defined, results suggest that care should be exercised in the disposal and release of produced waters containing these organic substances into the environment because of the potential toxicity of many of these substances.

  10. Percent Forest Adjacent to Streams

    Data.gov (United States)

    U.S. Environmental Protection Agency — The type of vegetation along a stream influences the water quality in the stream. Intact buffer strips of natural vegetation along streams tend to intercept...

  11. Percent Agriculture Adjacent to Streams

    Data.gov (United States)

    U.S. Environmental Protection Agency — The type of vegetation along a stream influences the water quality in the stream. Intact buffer strips of natural vegetation along streams tend to intercept...

  12. Renovate produced-water-treating facilities to handle increased water cuts

    International Nuclear Information System (INIS)

    Murti, D.G.K.; Al-Nuaimi, H.R.

    1991-01-01

    This paper reports on the modified skimmer tanks that have consistently demonstrated superior oil recovery characteristics compared to conventional design in an oil field tank battery system. The modified tanks have been in continuous service for more than 3 years in one of the oldest oil fields in the Arabian Gulf. The new design has helped recover skimmed oil from a mere 6 bpd (1.0 m 3 ) to more than 55 bpd (8.75 m 3 ) from produced water in a tank battery system alone. The recovery is expected to improve by up to 200 bpd (31.8 m 3 ) once skimmer tanks in all the tank batteries are upgraded to the new design

  13. Electrolytically generated hydrogen warm water cleanses the keratin-plug-clogged hair-pores and promotes the capillary blood-streams, more markedly than normal warm water does

    Directory of Open Access Journals (Sweden)

    Yoshiharu Tanaka

    2018-01-01

    Full Text Available Biomedical properties of hydrogen water have been extensively investigated, but the effect of hydrogen on good healthy subjects remains unclear. This study was designed to explore the hygiene improvement by electrolytically generated hydrogen warm water (40°C on capillary blood streams, skin moisture, and keratin plugs in skin pores in normal good healthy subjects with their informed consents. Fingertip-capillary blood stream was estimated after hand-immersing in hydrogen warm water by videography using a CCD-based microscope, and the blood flow levels increased to about 120% versus normal warm water, after 60 minutes of the hand-immersing termination. Skin moisture of subjects was assessed using an electro-conductivity-based skin moisture meter. Immediately after taking a bath filled with hydrogen warm water, the skin moisture increased by 5–10% as compared to before bathing, which was kept on for the 7-day test, but indistinct, because of lower solubility of hydrogen in “warm” water than in room-temperature water. Cleansing of keratin plugs in skin-pores was assessed by stereoscopic microscopy and scanning electron microscopy. After hydrogen warm water bathing, the numbers of cleansed keratin plugs also increased on cheek of subjects 2.30- to 4.47-fold as many as the control for normal warm water. And areas of cleansed keratin plugs in the cheeks increased about 1.3-fold as much as the control. More marked improvements were observed on cheeks than on nostrils. Hydrogen warm water may thoroughly cleanse even keratin-plugs of residual amounts that could not be cleansed by normal warm water, through its permeability into wide-ranged portions of hair-pores, and promote the fingertip blood streams more markedly than merely through warmness due to normal warm water.

  14. Effects of land use, stream habitat, and water quality on biological communities of wadeable streams in the Illinois River Basin of Arkansas, 2011 and 2012

    Science.gov (United States)

    Petersen, James C.; Justus, B.G.; Meredith, Bradley J.

    2014-01-01

    The Illinois River Basin includes an area of diverse land use in northwestern Arkansas. Land-use data collected in 2006 indicate that most of the land in the basin is agricultural. The agricultural land is used primarily for production of poultry and cattle. Eighteen sites were selected from the list of candidate sites based on drainage area, land use, presence or absence of an upstream wastewater-treatment plant, water quality, and other information gathered during the reconnaissance. An important consideration in the process was to select sites along gradients of forest to urban land use and forest to agricultural land use. Water-quality samples were collected for analysis of nutrients, and a multiparameter field meter was used to measure water temperature, specific conductance, pH, and dissolved oxygen. Streamflow was measured immediately following the water-quality sampling. Macroalgae coverage was estimated and periphyton, macroinvertebrate, and fish communities were sampled at each site. Stream habitat also was assessed. Many types of land-use, water-quality, and habitat factors affected one or more aspects of the biological communities. Several macroinvertebrate and fish metrics changed in response to changes in percent forest; sites that would be considered most disturbed, based on these metrics, are sites with the highest percentages of urban land use in their associated basins. The presence of large mats of macroalgae was one of the most noticeable biological characteristics in several streams within the Illinois River Basin. The highest macroalgae percent cover values were recorded at four sites downstream from wastewater-treatment plants. Macroalgae percent cover was strongly correlated only with bed substrate size, canopy closure, and specific conductance. Periphyton metrics were most often and most strongly correlated with riparian shading, specific conductance, substrate turbidity, percent agriculture, poultry house density, and unpaved road density

  15. Organic and inorganic compounds in the water streams of the paper machine; Haitta-ainevirrat ja -tasot paperikoneella - PMST 01

    Energy Technology Data Exchange (ETDEWEB)

    Tervonen, P; Edelmann, K; Kaijaluoto, S [VTT Energy