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Sample records for stratified brine solutions

  1. Distinctive Microbial Community Structure in Highly Stratified Deep-Sea Brine Water Columns

    KAUST Repository

    Bougouffa, Salim; Yang, J. K.; Lee, O. O.; Wang, Y.; Batang, Zenon B.; Al-Suwailem, Abdulaziz M.; Qian, P. Y.

    2013-01-01

    Atlantis II and Discovery are two hydrothermal and hypersaline deep-sea pools in the Red Sea rift that are characterized by strong thermohalo-stratification and temperatures steadily peaking near the bottom. We conducted comprehensive vertical profiling of the microbial populations in both pools and highlighted the influential environmental factors. Pyrosequencing of the 16S rRNA genes revealed shifts in community structures vis-à-vis depth. High diversity and low abundance were features of the deepest convective layers despite the low cell density. Surprisingly, the brine interfaces had significantly higher cell counts than the overlying deep-sea water, yet they were lowest in diversity. Vertical stratification of the bacterial populations was apparent as we moved from the Alphaproteobacteria-dominated deep sea to the Planctomycetaceae- or Deferribacteres-dominated interfaces to the Gammaproteobacteria-dominated brine layers. Archaeal marine group I was dominant in the deep-sea water and interfaces, while several euryarchaeotic groups increased in the brine. Across sites, microbial phylotypes and abundances varied substantially in the brine interface of Discovery compared with Atlantis II, despite the near-identical populations in the overlying deep-sea waters. The lowest convective layers harbored interestingly similar microbial communities, even though temperature and heavy metal concentrations were very different. Multivariate analysis indicated that temperature and salinity were the major influences shaping the communities. The harsh conditions and the low-abundance phylotypes could explain the observed correlation in the brine pools.

  2. Distinctive Microbial Community Structure in Highly Stratified Deep-Sea Brine Water Columns

    KAUST Repository

    Bougouffa, Salim

    2013-03-29

    Atlantis II and Discovery are two hydrothermal and hypersaline deep-sea pools in the Red Sea rift that are characterized by strong thermohalo-stratification and temperatures steadily peaking near the bottom. We conducted comprehensive vertical profiling of the microbial populations in both pools and highlighted the influential environmental factors. Pyrosequencing of the 16S rRNA genes revealed shifts in community structures vis-à-vis depth. High diversity and low abundance were features of the deepest convective layers despite the low cell density. Surprisingly, the brine interfaces had significantly higher cell counts than the overlying deep-sea water, yet they were lowest in diversity. Vertical stratification of the bacterial populations was apparent as we moved from the Alphaproteobacteria-dominated deep sea to the Planctomycetaceae- or Deferribacteres-dominated interfaces to the Gammaproteobacteria-dominated brine layers. Archaeal marine group I was dominant in the deep-sea water and interfaces, while several euryarchaeotic groups increased in the brine. Across sites, microbial phylotypes and abundances varied substantially in the brine interface of Discovery compared with Atlantis II, despite the near-identical populations in the overlying deep-sea waters. The lowest convective layers harbored interestingly similar microbial communities, even though temperature and heavy metal concentrations were very different. Multivariate analysis indicated that temperature and salinity were the major influences shaping the communities. The harsh conditions and the low-abundance phylotypes could explain the observed correlation in the brine pools.

  3. Monitoring of Miit glass solution interactions by brine analysis

    International Nuclear Information System (INIS)

    Sassoon, R.E.; Gong, M.; Adel-Hadadi, M.; Brandys, M.; Barkatt, A.; Macedo, P.B.

    1989-01-01

    Analyses of brine samples taken from borehole MIIT=8 at the WIPP site were carried out in order to study the leaching behavior of the brine in this system. The standard addition method was used with the analytical techniques of AA, DCP and ICP-MS to determine the concentration of the components in the brine. The changes in the concentration of the major components, Na, Mg and K can be explained by reactions of the brine with the rock salt walls of the borehole. From the data obtained for the other components no leaching of the SRL-Y glass discs in the test could be observed. It was however possible to determine an upper limit for leaching of the glass from isotope ratio studies made on Li which yielded a value for the leach rate of lithium from the glass of 0.117 g m -2 d -1

  4. Brine transport in porous media self-similar solutions

    NARCIS (Netherlands)

    C.J. van Duijn (Hans); L.A. Peletier (Bert); R.J. Schotting (Ruud)

    1996-01-01

    textabstractIn this paper we analyze a model for brine transport in porous media, which includes a mass balance for the fluid, a mass balance for salt, Darcy's law and an equation of state, which relates the fluid density to the salt mass fraction. This model incorporates the effect of local volume

  5. Efficacy of chlorine dioxide against Listeria monocytogenes in brine chilling solutions.

    Science.gov (United States)

    Valderrama, W B; Mills, E W; Cutter, C N

    2009-11-01

    Chilled brine solutions are used by the food industry to rapidly cool ready-to-eat meat products after cooking and before packaging. Chlorine dioxide (ClO(2)) was investigated as an antimicrobial additive to eliminate Listeria monocytogenes. Several experiments were performed using brine solutions made of sodium chloride (NaCl) and calcium chloride (CaCl(2)) inoculated with L. monocytogenes and/or treated with 3 ppm of ClO(2). First, 10 and 20% CaCl(2) and NaCl solutions (pH 7.0) were inoculated with a five-strain cocktail of L. monocytogenes to obtain approximately 7 log CFU/ml and incubated 8 h at 0 degrees C. The results demonstrated that L. monocytogenes survived in 10% CaCl(2), 10 and 20% NaCl, and pure water. L. monocytogenes levels were reduced approximately 1.2 log CFU/ml in 20% CaCl(2). Second, inoculated ( approximately 7 log CFU/ml) brine solutions (10 and 20% NaCl and 10% CaCl(2)) treated with 3 ppm of ClO(2) resulted in a approximately 4-log reduction of the pathogen within 90 s. The same was not observed in a solution of 20% CaCl(2); further investigation demonstrated that high levels of divalent cations interfere with the disinfectant. Spent brine solutions from hot dog and ham chilling were treated with ClO(2) at concentrations of 3 or 30 ppm. At these concentrations, ClO(2) did not reduce L. monocytogenes. Removal of divalent cations and organic material in brine solutions prior to disinfection with ClO(2) should be investigated to improve the efficacy of the compound against L. monocytogenes. The information from this study may be useful to processing establishments and researchers who are investigating antimicrobials in chilling brine solutions.

  6. Subsurface transport of inorganic and organic solutes from experimental road spreading of oil-field brine

    International Nuclear Information System (INIS)

    Bair, E.S.; Digel, R.K.

    1990-01-01

    A study designed to evaluate ground water quality changes resulting from spreading oil-field brine on roads for ice and dust control was conducted using a gravel roadbed that received weekly applications of brine eight times during the winter phase and 11 times during the summer phase of the study. A network of 11 monitoring wells and five pressure-vacuum lysimeters was installed to obtain ground water and soil water samples. Thirteen sets of water-quality samples were collected and analyzed for major ions, trace metals, and volatile organic compounds. Two sets of samples were taken prior to brine spreading, four sets during winter-phase spreading, five sets during summer-phase spreading, and two sets during the interim between the winter and summer phases. A brine plume delineated by elevated specific-conductance values and elevated chloride concentrations in ground water samples to exceed US EPA public drinking-water standards by two-fold during the winter phase and five-fold during the summer phase. No other major ions, trace metals, or volatile organic compounds exceeded the standards during the winter or summer phases. More than 99% dilution of the solutes in the brine occurred between the roadbed surface and the local ground water flow system. Further attenuation of calcium, sodium, potassium, and strontium resulted from adsorption, whereas further attenuation of benzene resulted from volatilization and adsorption

  7. Review: Water recovery from brines and salt-saturated solutions: operability and thermodynamic efficiency considerations for desalination technologies.

    Science.gov (United States)

    Vane, Leland M

    2017-03-08

    When water is recovered from a saline source, a brine concentrate stream is produced. Management of the brine stream can be problematic, particularly in inland regions. An alternative to brine disposal is recovery of water and possibly salts from the concentrate. This review provides an overview of desalination technologies and discusses the thermodynamic efficiencies and operational issues associated with the various technologies particularly with regard to high salinity streams. Due to the high osmotic pressures of the brine concentrates, reverse osmosis, the most common desalination technology, is impractical. Mechanical vapor compression which, like reverse osmosis, utilizes mechanical work to operate, is reported to have the highest thermodynamic efficiency of the desalination technologies for treatment of salt-saturated brines. Thermally-driven processes, such as flash evaporation and distillation, are technically able to process saturated salt solutions, but suffer from low thermodynamic efficiencies. This inefficiency could be offset if an inexpensive source of waste or renewable heat could be used. Overarching issues posed by high salinity solutions include corrosion and the formation of scales/precipitates. These issues limit the materials, conditions, and unit operation designs that can be used.

  8. Forward Osmosis Brine Drying

    Science.gov (United States)

    Flynn, Michael; Shaw, Hali; Hyde, Deirdre; Beeler, David; Parodi, Jurek

    2015-01-01

    The Forward Osmosis Brine Drying (FOBD) system is based on a technique called forward osmosis (FO). FO is a membrane-based process where the osmotic potential between brine and a salt solution is equalized by the movement of water from the brine to the salt solution. The FOBD system is composed of two main elements, the FO bag and the salt regeneration system. This paper discusses the results of testing of the FO bag to determine the maximum water recovery ratio that can be attained using this technology. Testing demonstrated that the FO bag is capable of achieving a maximum brine water recovery ratio of the brine of 95%. The equivalent system mass was calculated to be 95 kg for a feed similar to the concentrated brine generated on the International Space Station and 86 kg for an Exploration brine. The results have indicated that the FOBD can process all the brine for a one year mission for between 11% to 10% mass required to bring the water needed to make up for water lost in the brine if not recycled. The FOBD saves 685 kg and when treating the International Space Station brine and it saves 829 kg when treating the Exploration brine. It was also demonstrated that saturated salt solutions achieve a higher water recovery ratios than solids salts do and that lithium chloride achieved a higher water recovery ratio than sodium chloride.

  9. Osmotic power generation by pressure retarded osmosis using seawater brine as the draw solution and wastewater retentate as the feed

    KAUST Repository

    Wan, Chunfeng; Chung, Neal Tai-Shung

    2015-01-01

    Pressure retarded osmosis (PRO) is a promising technology to produce clean and sustainable osmotic energy from salinity gradient. Fresh water is of scarcity in Singapore; however, alternative sources of feed solutions and draw solutions are well explored. For the first time, seawater brine from the TuaSpring desalination plant and wastewater retentate from the NEWater plant were used in a state-of-the-art TFC-PES hollow fiber membrane PRO process. The highest power densities obtained with 1 M NaCl solution and seawater brine were 27.0 W/m2 and 21.1 W/m2 at 20bar, respectively, when deionized (DI) water was used as the feed solution. However, the highest power density dropped to 4.6W/m2 when wastewater retentate was used as the feed solution. Fouling on the porous substrate induced by the wastewater retentate was identified as the main cause of the reduction in the power densities, while the negative effects of seawater brine on the PRO performances were negligible. Both ultrafiltration (UF) and nanofiltration (NF) pretreatment were employed to mitigate fouling from the wastewater retentate, and the power densities were boosted to 6.6W/m2 and 8.9W/m2, respectively, beyond the power density of 5W/m2 proposed by Statkraft for the PRO process to be economical.

  10. Osmotic power generation by pressure retarded osmosis using seawater brine as the draw solution and wastewater retentate as the feed

    KAUST Repository

    Wan, Chunfeng

    2015-04-01

    Pressure retarded osmosis (PRO) is a promising technology to produce clean and sustainable osmotic energy from salinity gradient. Fresh water is of scarcity in Singapore; however, alternative sources of feed solutions and draw solutions are well explored. For the first time, seawater brine from the TuaSpring desalination plant and wastewater retentate from the NEWater plant were used in a state-of-the-art TFC-PES hollow fiber membrane PRO process. The highest power densities obtained with 1 M NaCl solution and seawater brine were 27.0 W/m2 and 21.1 W/m2 at 20bar, respectively, when deionized (DI) water was used as the feed solution. However, the highest power density dropped to 4.6W/m2 when wastewater retentate was used as the feed solution. Fouling on the porous substrate induced by the wastewater retentate was identified as the main cause of the reduction in the power densities, while the negative effects of seawater brine on the PRO performances were negligible. Both ultrafiltration (UF) and nanofiltration (NF) pretreatment were employed to mitigate fouling from the wastewater retentate, and the power densities were boosted to 6.6W/m2 and 8.9W/m2, respectively, beyond the power density of 5W/m2 proposed by Statkraft for the PRO process to be economical.

  11. Approximate solutions and error bounds for the wave equation in a stratified ionosphere with turning points

    International Nuclear Information System (INIS)

    Nalesso, G.F.; Jacobson, A.R.

    1991-01-01

    A solution to the problem of a plane electromagnetic wave traveling parallel to a constant magnetic field in a horizontally stratified ionosphere was developed assuming that the permittivity of the medium can be represented as the sum of an unperturbed component and a perturbed component. The method is successfully applied to the case of a linearly varying permittivity of a lossless ionosphere with a superimposed Gaussian perturbing term. The feasibility of applying the method in the presence of an odd number of turning points is discussed. 13 refs

  12. Analysis of corrosion data for carbon steels in simulated salt repository brines and acid chloride solutions at high temperatures

    International Nuclear Information System (INIS)

    Diercks, D.R.; Hull, A.B.; Kassner, T.F.

    1988-03-01

    Carbon steel is currently the leading candidate material for fabrication of a container for isolation of high level nuclear waste in a salt repository. Since brine entrapped in the bedded salt can migrate to the container by several transport processes, corrosion is an important consideration in the long-term performance of the waste package. A detailed literature search was performed to compile relevant corrosion data for carbon steels in anoxic acid chloride solutions, and simulated salt repository brines at temperatures between ∼ 20 and 400 0 C. The hydrolysis of Mg 2+ ions in simulated repository brines containing high magnesium concentrations causes acidification at temperatures above 25 0 C, which, in turn, influences the protective nature of the magnetite corrosion product layer on carbon steel. The corrosion data for the steels were analyzed, and an analytical model for general corrosion was developed to calculate the amount of penetration (i.e., wall thinning) as a function of time, temperature, and the pressure of corrosion product hydrogen than can build up during exposure in a closed system (e.g., a sealed capsule). Both the temperature and pressure dependence of the corrosion rate of steels in anoxic acid chloride solutions indicate that the rate-controlling partial reaction is the cathodic reduction of water to form hydrogen. Variations in the composition and microstructure of the steels or the concentration of the ionic species in the chloride solutions (provided that they do not change the pH significantly) do not appear to strongly influence the corrosion rate

  13. Tests of the TRAC code against known analytical solutions for stratified flow

    International Nuclear Information System (INIS)

    Black, P.S.; Leslie, D.C.; Hewitt, G.F.

    1987-01-01

    The area averaged equations for gas-liquid flow are briefly summarized and related, for the specific case of stratified flow, to the shallow water equations commonly used in hydraulics. These equations are then compared to the equations used in TRAC-PF/MOD1 and are shown to differ in their treatment of the gravity head terms. A modification of the TRAC code is therefore necessary to bring it into line with established shallow water theory. The corrected form of the code was compared with a number of specific cases, each of which throws further light on the code behavior. The following areas are discussed in the paper: (1) the dam break problem; (2) Kelvin-Helmholtz instability; (3) counter-current flow; and (4) slug flow. It is concluded that detailed comparisons of the code with known analytic solutions and with a number of the more complex phenomenological experiments can give useful insights into its behavior

  14. Acid and base recovery from brine solution using PVP intermediate-based bipolar membrane through water splitting technology

    Science.gov (United States)

    Venugopal, Krishnaveni; Murugappan, Minnoli; Dharmalingam, Sangeetha

    2017-07-01

    Potable water has become a scarce resource in many countries. In fact, the world is not running out of water, but rather, the relatively fixed quantity is becoming too contaminated for many applications. Hence, the present work was designed to evaluate the desalination efficiency of resin and glass fiber-reinforced Polysulfone polymer-based monopolar and bipolar (BPM) ion exchange membranes (with polyvinyl pyrrolidone as the intermediate layer) on a real sample brine solution for 8 h duration. The prepared ion exchange membranes (IEMs) were characterized using FTIR, SEM, TGA, water absorption, and contact angle measurements. The BPM efficiency, electrical conductivity, salinity, sodium, and chloride ion concentration were evaluated for both prepared and commercial-based IEM systems. The current efficiency and energy consumption values obtained during BPMED process were found to be 45 % and 0.41 Wh for RPSu-PVP-based IEM system and 38 % and 1.60 Wh for PSDVB-based IEM system, respectively.

  15. Analysis of the corrosion of carbon steels in simulated salt repository brines and acid chloride solutions at high temperatures

    International Nuclear Information System (INIS)

    Diercks, D.R.; Kassner, T.F.

    1988-04-01

    An analysis of literature data on the corrosion of carbon steels in anoxic brines and acid chloride solutions was performed, and the results were used to assess the expected life of high-level nuclear waste package containers in a salt repository environment. The corrosion rate of carbon steels in moderately acidic aqueous chloride environments obeys an Arrhenius dependence on temperature and a (pH 2 ) -1/2 dependence on hydrogen partial pressure. The cathodic reduction of water to produce hydrogen is the rate-controlling step in the corrosion process. An expression for the corrosion rate incorporating these two dependencies was used to estimate the corrosion life of several proposed waste package configurations. 42 refs., 11 figs., 2 tabs

  16. A recursive transfer-matrix solution for a dipole radiating inside and outside a stratified sphere

    International Nuclear Information System (INIS)

    Moroz, Alexander

    2005-01-01

    Fast and numerically stable transfer-matrix solution is presented for the classical electromagnetics problem of a dipole radiating inside and outside a stratified sphere consisting of concentric spherical shells. There is no limitation on the dipole position, the number of the concentric shells, the shell medium, or on the sphere radius. Electromagnetic fields are determined anywhere in the space, the time-averaged angular distribution of the radiated power, the total radiated power, Ohmic losses due to an absorbing shell, and Green's function are calculated. An absorbing, optically active, and ultrathin (-bar 10nm) metallic shell (core), characterized by a nonlocal dielectric function, are all allowed. The classical results are then applied to inelastic light scattering (fluorescence and Raman), the radiative and nonradiative normalized decay rates, and frequency shift. Using correspondence principle, the radiative decay rate is calculated from the Poynting vector, whereas the nonradiative decay rate is calculated from the Ohmic losses inside a sphere absorptive shell. Numerical stability of our method and limitations of classical description of decay rates are addressed. The importance of grouping various radiative and nonradiative decay mechanisms into local and nonlocal decay rates is emphasized. Further possible extensions of the theory presented here to the case of an arbitrary multilayered (axially symmetric) particle and to the classical problem of a radiating quadrupole in the presence of a multilayered particle are briefly outlined. Various applications for chemical speciation, LIDAR, fluorescent microscopy, engineering of decay rates, identification of biological particles, and monitoring specific cell functions are envisaged. Computer program is freely available at http://www.wave-scattering.com

  17. Water recovery from brines and salt-saturated solutions: operability and thermodynamic efficiency considerations for desalination technologies

    Science.gov (United States)

    This review provides an overview of desalination technologies and discusses the thermodynamic efficiencies and operational issues associated with the various technologies particularly with regard to high salinity streams. When water is recovered from a saline source, a brine conc...

  18. Brine flow up a borehole caused by pressure perturbation from CO2 storage: Static and dynamic evaluations

    Energy Technology Data Exchange (ETDEWEB)

    Birkholzer, J.T.; Nicot, J.-P.; Oldenburg, C.M.; Zhou, Q.; Kraemer, S.; Bandilla, K.W.

    2011-05-01

    Industrial-scale storage of CO{sub 2} in saline sedimentary basins will cause zones of elevated pressure, larger than the CO{sub 2} plume itself. If permeable conduits (e.g., leaking wells) exist between the injection reservoir and overlying shallow aquifers, brine could be pushed upwards along these conduits and mix with groundwater resources. This paper discusses the potential for such brine leakage to occur in temperature- and salinity-stratified systems. Using static mass-balance calculations as well as dynamic well flow simulations, we evaluate the minimum reservoir pressure that would generate continuous migration of brine up a leaking wellbore into a freshwater aquifer. Since the brine invading the well is denser than the initial fluid in the wellbore, continuous flow only occurs if the pressure perturbation in the reservoir is large enough to overcome the increased fluid column weight after full invasion of brine into the well. If the threshold pressure is exceeded, brine flow rates are dependent on various hydraulic (and other) properties, in particular the effective permeability of the wellbore and the magnitude of pressure increase. If brine flow occurs outside of the well casing, e.g., in a permeable fracture zone between the well cement and the formation, the fluid/solute transfer between the migrating fluid and the surrounding rock units can strongly retard brine flow. At the same time, the threshold pressure for continuous flow to occur decreases compared to a case with no fluid/solute transfer.

  19. Analytical solution of laminar-laminar stratified two-phase flows with curved interfaces

    International Nuclear Information System (INIS)

    Brauner, N.; Rovinsky, J.; Maron, D.M.

    1995-01-01

    The present study represents a complete analytical solution for laminar two-phase flows with curved interfaces. The solution of the Navier-Stokes equations for the two-phases in bipolar coordinates provides the 'flow monograms' describe the relation between the interface curvature and the insitu flow geometry when given the phases flow rates and viscosity ratios. Energy considerations are employed to construct the 'interface monograms', whereby the characteristic interfacial curvature is determined in terms of the phases insitu holdup, pipe diameter, surface tension, fluids/wall adhesion and gravitation. The two monograms are then combined to construct the system 'operational monogram'. The 'operational monogram' enables the determination of the interface configuration, the local flow characteristics, such as velocity profiles, wall and interfacial shear stresses distribution as well as the integral characteristics of the two-phase flow: phases insitu holdup and pressure drop

  20. Analytical solution of laminar-laminar stratified two-phase flows with curved interfaces

    Energy Technology Data Exchange (ETDEWEB)

    Brauner, N.; Rovinsky, J.; Maron, D.M. [Tel-Aviv Univ. (Israel)

    1995-09-01

    The present study represents a complete analytical solution for laminar two-phase flows with curved interfaces. The solution of the Navier-Stokes equations for the two-phases in bipolar coordinates provides the `flow monograms` describe the relation between the interface curvature and the insitu flow geometry when given the phases flow rates and viscosity ratios. Energy considerations are employed to construct the `interface monograms`, whereby the characteristic interfacial curvature is determined in terms of the phases insitu holdup, pipe diameter, surface tension, fluids/wall adhesion and gravitation. The two monograms are then combined to construct the system `operational monogram`. The `operational monogram` enables the determination of the interface configuration, the local flow characteristics, such as velocity profiles, wall and interfacial shear stresses distribution as well as the integral characteristics of the two-phase flow: phases insitu holdup and pressure drop.

  1. The solubility of UO22+ in dilute sodium chloride solutions and in high-ionic strength sodium sulfate and chlorine brines

    International Nuclear Information System (INIS)

    Marquez, L.N.; Kadkhodayan, B.; Wruck, D.A.

    1995-01-01

    Uranium is a major component of high-level nuclear waste. In an oxidizing environment, UO 2 2+ would be expected to be the dominant dissolved species in solution. In addition to dilute solutions, because high-level nuclear waste may be stored in repositories containing salt, it is important to characterize the aqueous chemistry of UO 2 2+ and the solubility-controlling U(VI) solids in high-ionic strength brines as a function of pH. We have studied the solubility of UO 2 2+ by precipitation of solid phase in 0.001 molal NaCl, 5.2 molal NaCl, and saturated Na 2 SO 4 at pH values ranging from 5 to 12. The solution concentrations were measured by alpha particle liquid scintillation counting. The precipitated solids were characterized by powder x-ray diffraction, electron microscopy, infrared spectroscopy, and x-ray photoelectron spectroscopy

  2. High-order boundary integral equation solution of high frequency wave scattering from obstacles in an unbounded linearly stratified medium

    Science.gov (United States)

    Barnett, Alex H.; Nelson, Bradley J.; Mahoney, J. Matthew

    2015-09-01

    We apply boundary integral equations for the first time to the two-dimensional scattering of time-harmonic waves from a smooth obstacle embedded in a continuously-graded unbounded medium. In the case we solve, the square of the wavenumber (refractive index) varies linearly in one coordinate, i.e. (Δ + E +x2) u (x1 ,x2) = 0 where E is a constant; this models quantum particles of fixed energy in a uniform gravitational field, and has broader applications to stratified media in acoustics, optics and seismology. We evaluate the fundamental solution efficiently with exponential accuracy via numerical saddle-point integration, using the truncated trapezoid rule with typically 102 nodes, with an effort that is independent of the frequency parameter E. By combining with a high-order Nyström quadrature, we are able to solve the scattering from obstacles 50 wavelengths across to 11 digits of accuracy in under a minute on a desktop or laptop.

  3. Simulation of NaCl and KCl mass transfer during salting of Prato cheese in brine with agitation: a numerical solution

    Directory of Open Access Journals (Sweden)

    E. Bona

    2007-09-01

    Full Text Available The association of dietary NaCl with arterial hypertension has led to a reduction in the levels of this salt in cheeses. For salting, KCl has been used as a partial substitute for NaCl, which cannot be completely substituted without affecting product acceptability. In this study a sensorially adequate saline solution (NaCl/KCl was simultaneously diffused during salting of Prato cheese in brine with agitation. The simultaneous multicomponent diffusion during the process was modeled with Fick’s second generalized law. The system of partial differential equations formed was solved by the finite element method (FEM. In the experimental data concentration the deviation for NaCl was of 7.3% and for KCl of 5.4%, both of which were considered acceptable. The simulation of salt diffusion will allow control and modulation of salt content in Prato cheese, permitting the prediction of final content from initial conditions.

  4. Brine Sampling and Evaluation Program: Phase 1 report

    International Nuclear Information System (INIS)

    Deal, D.E.; Case, J.B.

    1987-01-01

    This interim report presents preliminary data obtained in the course of the WIPP Brine Sampling and Evaluation Program. The investigations focus on the brine present in the near-field environment around the WIPP underground workings. Although the WIPP underground workings are considered dry, small amounts of brine are present. This amount of brine is not unexpected in rocks of marine sedimentary origin. Part of that brine can and does migrate into the repository in response to pressure gradients, at essentially isothermal conditions. These small volumes of brine have little effect on the day-to-day operations, but are pervasive throughout the repository and may contribute enough moisture over a period of years to affect resaturation and repressurization after sealing and closure. Gas bubbles are observed in many of the brine occurrences. Gas is also known to exsolve from solution as the brine is poured from container to container. 68 refs., 9 figs., 2 tabs

  5. Anion exchange removal of Al3+ from Li+-Al3+ aqueous solution (originating from lithium recovery from brine

    Directory of Open Access Journals (Sweden)

    Anissa Somrani

    2014-06-01

    Full Text Available The purpose of this study is to separate aluminum(III ion from an aqueous solution containing Li+ at 25°C. Al3+ was transferred into [Al(C2O43]3- by means of complexation and removed by an anion exchange resin. This resin was anionic type Amberlite IRA 402 regenerated by sodium chloride. Hence, a theoretical study based on speciation diagrams was carried out to determine the best pH domain for separation. The complexation of aluminum ions by ammonium oxalate was studied. The motar ratio of Ox/Al and pH was investigated. Optimum values of these factors were found to be 3 and 4 respectively. In this case, the remaining lithium is 98.5%.

  6. Two-dimensional interaction of a shear flow with a free surface in a stratified fluid and its solitary-wave solutions via mathematical methods

    Science.gov (United States)

    Seadawy, Aly R.

    2017-12-01

    In this study, we presented the problem formulations of models for internal solitary waves in a stratified shear flow with a free surface. The nonlinear higher order of extended KdV equations for the free surface displacement is generated. We derived the coefficients of the nonlinear higher-order extended KdV equation in terms of integrals of the modal function for the linear long-wave theory. The wave amplitude potential and the fluid pressure of the extended KdV equation in the form of solitary-wave solutions are deduced. We discussed and analyzed the stability of the obtained solutions and the movement role of the waves by making graphs of the exact solutions.

  7. Jarosite dissolution rates in perchlorate brine

    Science.gov (United States)

    Legett, Carey; Pritchett, Brittany N.; Elwood Madden, Andrew S.; Phillips-Lander, Charity M.; Elwood Madden, Megan E.

    2018-02-01

    Perchlorate salts and the ferric sulfate mineral jarosite have been detected at multiple locations on Mars by both landed instruments and orbiting spectrometers. Many perchlorate brines have eutectic temperatures bearing rocks and sediments may have been altered by perchlorate brines. Here we measured jarosite dissolution rates in 2 M sodium perchlorate brine as well as dilute water at 298 K to determine the effects of perchlorate anions on jarosite dissolution rates and potential reaction products. We developed a simple method for determining aqueous iron concentrations in high salinity perchlorate solutions using ultraviolet-visible spectrophotometry that eliminates the risk of rapid oxidation reactions during analyses. Jarosite dissolution rates in 2 M perchlorate brine determined by iron release rate (2.87 × 10-12 ±0.85 × 10-12 mol m-2 s-1) were slightly slower than the jarosite dissolution rate measured in ultrapure (18.2 MΩ cm-1) water (5.06 × 10-12 mol m-2 s-1) using identical methods. No additional secondary phases were observed in XRD analyses of the reaction products. The observed decrease in dissolution rate may be due to lower activity of water (ɑH2O = 0.9) in the 2 M NaClO4 brine compared with ultrapure water (ɑH2O = 1). This suggests that the perchlorate anion does not facilitate iron release, unlike chloride anions which accelerated Fe release rates in previously reported jarosite and hematite dissolution experiments. Since dissolution rates are slower in perchlorate-rich solutions, jarosite is expected to persist longer in perchlorate brines than in dilute waters or chloride-rich brines. Therefore, if perchlorate brines dominate aqueous fluids on the surface of Mars, jarosite may remain preserved over extended periods of time, despite active aqueous processes.

  8. OUT Success Stories: Chemical Treatments for Geothermal Brines

    International Nuclear Information System (INIS)

    Burr, R.

    2000-01-01

    DOE research helped develop the large, untapped geothermal resource beneath the Salton Sea in California's Imperial Valley. The very hot brines under high pressure make them excellent for electric power production. The brines are very corrosive and contain high concentrations of dissolved silica. DOE worked with San Diego Gas and Electric Company to find a solution to the silica-scaling problem. This innovative brine treatment eliminated scaling and made possible the development of the Salton Sea geothermal resource

  9. Results for the Brine Evaporation Bag (BEB) Brine Processing Test

    Science.gov (United States)

    Delzeit, Lance; Flynn, Michael; Fisher, John; Shaw, Hali; Kawashima, Brian; Beeler, David; Howard, Kevin

    2015-01-01

    The recent Brine Processing Test compared the NASA Forward Osmosis Brine Dewatering (FOBD), Paragon Ionomer Water Processor (IWP), UMPQUA Ultrasonic Brine Dewatering System (UBDS), and the NASA Brine Evaporation Bag (BEB). This paper reports the results of the BEB. The BEB was operated at 70 deg C and a base pressure of 12 torr. The BEB was operated in a batch mode, and processed 0.4L of brine per batch. Two different brine feeds were tested, a chromic acid-urine brine and a chromic acid-urine-hygiene mix brine. The chromic acid-urine brine, known as the ISS Alternate Pretreatment Brine, had an average processing rate of 95 mL/hr with a specific power of 5kWhr/L. The complete results of these tests will be reported within this paper.

  10. Evaluation of Brine Processing Technologies for Spacecraft Wastewater

    Science.gov (United States)

    Shaw, Hali L.; Flynn, Michael; Wisniewski, Richard; Lee, Jeffery; Jones, Harry; Delzeit, Lance; Shull, Sarah; Sargusingh, Miriam; Beeler, David; Howard, Jeanie; hide

    2015-01-01

    Brine drying systems may be used in spaceflight. There are several advantages to using brine processing technologies for long-duration human missions including a reduction in resupply requirements and achieving high water recovery ratios. The objective of this project was to evaluate four technologies for the drying of spacecraft water recycling system brine byproducts. The technologies tested were NASA's Forward Osmosis Brine Drying (FOBD), Paragon's Ionomer Water Processor (IWP), NASA's Brine Evaporation Bag (BEB) System, and UMPQUA's Ultrasonic Brine Dewatering System (UBDS). The purpose of this work was to evaluate the hardware using feed streams composed of brines similar to those generated on board the International Space Station (ISS) and future exploration missions. The brine formulations used for testing were the ISS Alternate Pretreatment and Solution 2 (Alt Pretreat). The brines were generated using the Wiped-film Rotating-disk (WFRD) evaporator, which is a vapor compression distillation system that is used to simulate the function of the ISS Urine Processor Assembly (UPA). Each system was evaluated based on the results from testing and Equivalent System Mass (ESM) calculations. A Quality Function Deployment (QFD) matrix was also developed as a method to compare the different technologies based on customer and engineering requirements.

  11. Dissipative Nonlinear Schrödinger Equation for Envelope Solitary Rossby Waves with Dissipation Effect in Stratified Fluids and Its Solution

    Directory of Open Access Journals (Sweden)

    Yunlong Shi

    2014-01-01

    Full Text Available We solve the so-called dissipative nonlinear Schrödinger equation by means of multiple scales analysis and perturbation method to describe envelope solitary Rossby waves with dissipation effect in stratified fluids. By analyzing the evolution of amplitude of envelope solitary Rossby waves, it is found that the shear of basic flow, Brunt-Vaisala frequency, and β effect are important factors to form the envelope solitary Rossby waves. By employing trial function method, the asymptotic solution of dissipative nonlinear Schrödinger equation is derived. Based on the solution, the effect of dissipation on the evolution of envelope solitary Rossby wave is also discussed. The results show that the dissipation causes a slow decrease of amplitude of envelope solitary Rossby waves and a slow increase of width, while it has no effect on the propagation velocity. That is quite different from the KdV-type solitary waves. It is notable that dissipation has certain influence on the carrier frequency.

  12. Slumping of brine mounds : bounds on behaviour

    NARCIS (Netherlands)

    Philips, J.R.; Duijn, van C.J.

    1996-01-01

    Two modifications of the approximate analysis of interface motion during two-fluid density-driven flows of De Josselin de Jong (Proc. Euromech., 143: 75–82, 1981) are applied to the slumping of finite two-dimensional and axisymmetric brine mounds. Both lead to simple similarity solutions. One

  13. Brine flow in heated geologic salt.

    Energy Technology Data Exchange (ETDEWEB)

    Kuhlman, Kristopher L.; Malama, Bwalya

    2013-03-01

    This report is a summary of the physical processes, primary governing equations, solution approaches, and historic testing related to brine migration in geologic salt. Although most information presented in this report is not new, we synthesize a large amount of material scattered across dozens of laboratory reports, journal papers, conference proceedings, and textbooks. We present a mathematical description of the governing brine flow mechanisms in geologic salt. We outline the general coupled thermal, multi-phase hydrologic, and mechanical processes. We derive these processes governing equations, which can be used to predict brine flow. These equations are valid under a wide variety of conditions applicable to radioactive waste disposal in rooms and boreholes excavated into geologic salt.

  14. Pressure-induced brine migration in consolidated salt in a repository

    International Nuclear Information System (INIS)

    Hwang, Y.; Chambre, P.L.; Lee, W.W.L.; Pigford, T.H.

    1987-06-01

    This report describes a mathematical model for brine migration through intact salt near a radioactive waste package emplaced in salt. Solutions indicate limited movement following ten years emplacement

  15. Solubility of Nd in brine

    International Nuclear Information System (INIS)

    Khalili, F.I.; Symeopoulos, V.; Chen, J.F.; Choppin, G.R.

    1994-01-01

    The solubility of Nd(III) has been measured at 23±3 C in a synthetic brine at pcH 6.4, 8.4, 10.4 and 12.4. The brine consisted predominantly of (Na+K)Cl and MgCl 2 with an ionic strength of 7.8 M (9.4 m) a solid compound of Nd(III) at each pcH was assigned from X-ray diffraction patterns. The log values of the experimental solubilities decrease fomr -3 at pcH 6.4 to -5.8 at pcH 8.4; at pcH 10.4 and 12.4 the solubility was below the detection limit of -7.5. The experimental solubility does not follow closely the variation with pcH estimated from modeling of the species in solution in equilibrium with the Nd solid using S.I.T. (orig.)

  16. Soil washing for brine removal

    International Nuclear Information System (INIS)

    Ayyachamy, J.S.; Atalay, A.; Zaman, M.

    1992-01-01

    During the exploration for oil and thereafter, brine transfer lines get ruptured releasing the brine which contaminates the surrounding soil. The salinity level in brine is very high, sometimes approaching or exceeding that of sea water. Soils contaminated with brine are unproductive and unsuitable for plant growth. Several investigators have documented the pollution of surface water and groundwater due to brine disposal from oil and needed to clean up such sites. The objective of this study is to develop a soil washing technique that can be used to remove brine sites were collected and used in the study. This paper reports on results which indicate that soil washing using various surface active agents is effective in removing the brine

  17. Brine Sampling and Evaluation Program

    International Nuclear Information System (INIS)

    Deal, D.E.; Case, J.B.; Deshler, R.M.; Drez, P.E.; Myers, J.; Tyburski, J.R.

    1987-12-01

    The Brine Sampling and Evaluation Program (BSEP) Phase II Report is an interim report which updates the data released in the BSEP Phase I Report. Direct measurements and observations of the brine that seeps into the WIPP repository excavations were continued through the period between August 1986 and July 1987. That data is included in Appendix A, which extends the observation period for some locations to approximately 900 days. Brine observations at 87 locations are presented in this report. Although WIPP underground workings are considered ''dry,'' small amounts of brine are present. Part of that brine migrates into the repository in response to pressure gradients at essentially isothermal conditions. The data presented in this report is a continuation of moisture content studies of the WIPP facility horizon that were initiated in 1982, as soon as underground drifts began to be excavated. Brine seepages are manifested by salt efflorescences, moist areas, and fluid accumulations in drillholes. 35 refs., 6 figs., 11 tabs

  18. Effects of brine migration on waste storage systems. Final report

    International Nuclear Information System (INIS)

    Gaffney, E.S.; Nickell, R.E.

    1979-01-01

    Processes which can lead to mobilization of brine adjacent to spent fuel or nuclear waste canisters and some of the thermomechanical consequences have been investigated. Velocities as high as 4 x 10 -7 m s -1 (13 m y -1 ) are calculated at the salt/canister boundary. As much as 40 liters of pure NaCl brine could accumulate around each canister during a 10-year storage period. Accumulations of bittern brines would probably be less, in the range of 2 to 5 liters. With 0.5% water, NaCl brine accumulation over a 10-year storage cycle around a spent fuel canister producing 0.6 kW of heat is expected to be less than 1 liter for centimeter-size inclusions and less than 0.5 liter for millimeter-size inclusions. For bittern brines, about 25 years would be required to accumulate 0.4 liter. The most serious mechanical consequence of brine migration would be the increased mobility of the waste canister due to pressure solution. In pressure solution enhanced deformation, the existence of a thin film of fluid either between grains or between media (such as between a canister and the salt) provides a pathway by which the salt can be redistributed leading to a marked increase in strain rates in wet rock relative to dry rock. In salt, intergranular water will probably form discontinuous layers rather than films so that they would dominate pressure solution. A mathematical model of pressure solution indicates that pressure solution will not lead to appreciable canister motions except possibly in fine grained rocks (less than 10 -4 m). In fine grained salts, details of the contact surface between the canister and the salt bed may lead to large pressure solution motions. A numerical model indicates that heat transfer in the brine layer surrounding a spent fuel canister is not conduction dominated but has a significant convective component

  19. Local similar solution of MHD stagnation point flow in Carreau fluid over a non-linear stretched surface with double stratified medium

    Directory of Open Access Journals (Sweden)

    M. Farooq

    Full Text Available This article studies MHD double stratified stagnation point flow of Carreau fluid towards a non linear stretchable surface with radiation. Features of heat and mass transfer are evaluated by using convective boundary conditions. Resulting nonlinear problems are solved and studied for the velocity, temperature and concentration fields. Heat and mass transfer rates in addition to skin friction are discussed. Besides this for the verification of the present findings, the results of presented analysis have been compared with the available works in particular situations and reasonable agreement is noted. Keywords: Convective boundary condition, Thermal radiation, Double stratification, Stagnation point flow

  20. Searching for brine on Mars using Raman spectroscopy

    Energy Technology Data Exchange (ETDEWEB)

    Fischer, E.

    2016-07-01

    In the last few years, water ice and perchlorate salts capable of melting this ice and producing liquid solutions have been discovered at the surface and shallow subsurface of Mars. In addition to via melting of ice, perchlorate salts may also form liquid solutions by absorbing water vapor when the relative humidity is above a certain threshold in a process known as deliquescence. Formed either by melting or deliquescence, liquid solutions (brine) are the most likely way of liquid water activity on the Martian surface and in the shallow subsurface and are therefore important to understand the habitability of Mars. Using Raman spectroscopy, we provide reference spectra of various mixing states of liquid water, water ice and calcium perchlorate, all of which can occur during brine formation. We focus on the perchlorate symmetric stretching band and the O-H stretching vibrational band to distinguish brine from crystalline salt and water ice. We show that perchlorate brines can be identified by analyzing the peaks and their widths in the decomposed Raman spectra of the investigated samples. This serves as an important reference for future in-situ Raman spectrometers on Mars, such as those on the ExoMars and Mars 2020 rovers and can aid in the detection of brine formation on Mars. (Author)

  1. Thermodynamics of geothermal brines. I. Thermodynamic properties of vapor-saturated NaCl (aq) solutions from 0-300 {sup 0}C

    Energy Technology Data Exchange (ETDEWEB)

    Silvester, L.F.; Pitzer, K.S.

    1976-01-01

    Osmotic and activity coefficient data, enthalpy data, and heat capacity data on aqueous sodium chloride solutions from various sources have been fitted to a thirteen parameter equation. The equation reproduces the osmotic coefficient data to +-0.005 over the composition range 0-6M and temperature range 0-300{sup 0}C, enthalpy data to +-5-10 cal/mole for compositions of 0-5M at temperatures from 25-100{sup 0}C, and heat capacity data to +-0.5 cal/{sup 0}K for compositions of 0-2M at temperatures from 25-200{sup 0}C. Tabulated values of the total Gibbs energy, enthalpy, and heat capacity, plus partial molal and excess thermodynamic quantities of sodium chloride solutions for compositions of 0-6M at 25{sup 0}C intervals from 0-300{sup 0}C are given along with the same quantities in graphical form for compositions of 0-6M at temperatures of 100-350{sup 0}C.

  2. Effect of iron cation on geochemical trapping of CO2 in brine

    Science.gov (United States)

    Liu, Qi; Maroto-Valer, Mercedes

    2014-05-01

    Carbon dioxide sequestration using brines has emerged as a promising technology to mitigate the adverse impacts of climate change due to its large storage capacity and favorable chemistries. However, the permanent storage (mineral trapping) of CO2 in brines takes significantly long periods of time as the formation and precipitation of carbonates is very slow .[1]. The main parameters reported to effect on mineral trapping of CO2 sequestration in brines are brine composition, brine pH, system temperature and pressure.[2, 3]. It is suggested that the precipitation of mineral carbonates is mostly dependent on brine pH. Previous studies by the authors concluded that iron in natural brines causes pH instability, but it was not ascertained whether ferric iron or ferrous iron caused pH instability .[4]. Accordingly, the aim of this project is to study synthetic brines mimicking the major ions found in natural brines and including different concentrations of ferric and ferrous iron. Three brines were prepared, as follows: Brine 1 was prepared with ferric Fe3+ iron, Brine 2 prepared with ferrous Fe2+ iron and Brine 3 prepared with no iron. A series of pH stability studies and carbonation reactions were conducted using the above three brines. It is concluded that the ferrous iron causes pH instability, while ferric iron might promote carbonate precipitation. .1. Garcia, S., et al., Sequestration of non-pure carbon dioxide streams in iron oxyhydroxide-containing saline repositories. International Journal of Greenhouse Gas Control, 2012. 7: p. 89-97. 2. Liu, Q. and M.M. Maroto-Valer, Investigation of the pH effect of a typical host rock and buffer solution on CO 2 sequestration in synthetic brines. Fuel Processing Technology, 2010. 91(10): p. 1321-1329. 3. Liu, Q. and M.M. MarotoValer, Parameters affecting mineral trapping of CO2 sequestration in brines. Greenhouse Gases: Science and Technology, 2011. 1(3): p. 211-222. 4. Druckenmiller, M.L. and M.M. Maroto-Valer, Carbon

  3. Comparison of antimicrobial activities of brine salting, Chlorinated ...

    African Journals Online (AJOL)

    Chemical preservatives can be used to reduce the overall microbial populations in fish and fish products. This study was set to determine the antimicrobial activities of brine salting, chlorinated solution, and Moringa oleifera plant extracts treatments on enteric bacteria in Rastrineobola argentea and Oreochromis niloticus fish ...

  4. Chemistry of glass corrosion in high saline brines

    International Nuclear Information System (INIS)

    Grambow, B.; Mueller, R.

    1990-01-01

    Corrosion data obtained in laboratory tests can be used for the performance assessment of nuclear waste glasses in a repository if the data are quantitatively described in the frame of a geochemical model. Experimental data were obtained for conventional pH values corrected for liquid junction, amorphous silica solubility and glass corrosion in concentrated salt brines. The data were interpreted with a geochemical model. The brine chemistry was described with the Pitzer formalism using a data base which allows calculation of brine compositions in equilibrium with salt minerals at temperatures up to 200C. In MgCl 2 dominated brines Mg silicates form and due to the consumption of Mg the pH decreases with proceeding reaction. A constant pH (about 4) and composition of alteration products is achieved, when the alkali release from the glass balances the Mg consumption. The low pH results in high release of rare earth elements REE (rare earth elements) and U from the glass. In the NaCl dominated brine MgCl 2 becomes exhausted by Mg silicate formation. As long as there is still Mg left in solution the pH decreases. After exhaustion of Mg the pH rises with the alkali release from the glass and analcime is formed

  5. Stability of polyvinyl alcohol-coated biochar nanoparticles in brine

    Energy Technology Data Exchange (ETDEWEB)

    Griffith, Christopher, E-mail: cgriffith@utexas.edu; Daigle, Hugh [University of Texas at Austin, Department of Petroleum and Geosystems Engineering (United States)

    2017-01-15

    This paper reports on the dispersion stability of 150 nm polyvinyl alcohol coated biochar nanoparticles in brine water. Biochar is a renewable, carbon based material that is of significant interest for enhanced oil recovery operations primarily due to its wide ranging surface properties, low cost of synthesis, and low environmental toxicity. Nanoparticles used as stabilizing agents for foams (and emulsions) or in nanofluids have emerged as potential alternatives to surfactants for subsurface applications due to their improved stability at reservoir conditions. If, however, the particles are not properly designed, they are susceptible to aggregation because of the high salinity brines typical of oil and gas reservoirs. Attachment of polymers to the nanoparticle surface, through covalent bonds, provides steric stabilization, and is a necessary step. Our results show that as the graft density of polyvinyl alcohol increases, so too does the stability of nanoparticles in brine solutions. A maximum of 34 wt% of 50,000 Da polyvinyl alcohol was grafted to the particle surface, and the size of the particles was reduced from ~3500 nm (no coating) to 350 nm in brine. After 24 h, the particles had a size of ~500 nm, and after 48 h completely aggregated. 100,000 Da PVA coated at 24 wt% on the biochar particles were stable in brine for over 1 month with no change in mean particle size of ~330 nm.

  6. Brine Migration in Heated Salt: Lessons Learned from Field Experiments

    Science.gov (United States)

    Kuhlman, K. L.; Matteo, E. N.; Mills, M.

    2017-12-01

    We summarize several interesting brine migration related phenomena hinted at in field experiments from field testing related to salt radioactive waste repositories in Germany and the US. Past heater tests in salt have shown 1) thermal-hydrological-mechanical coupling is quite strong during both heating and cooling; 2) chemical composition of brine evolves during heating, and comprises a mix of several water sources; and 3) acid gas (HCl) generation has been observed during past heater tests and may have multiple mechanisms for formation. We present a heated brine migration test design, formulated with these complexities in mind. Sandia National Laboratories is a multimission laboratory managed and operated by National Technology and Engineering Solutions of Sandia LLC, a wholly owned subsidiary of Honeywell International Inc. for the U.S. Department of Energy's National Nuclear Security Administration under contract DE-NA0003525.

  7. Brine Sampling and Evaluation Program, 1991 report

    Energy Technology Data Exchange (ETDEWEB)

    Deal, D.E.; Abitz, R.J.; Myers, J.; Martin, M.L.; Milligan, D.J.; Sobocinski, R.W.; Lipponer, P.P.J. [International Technology Corp., Albuquerque, NM (United States); Belski, D.S. [Westinghouse Electric Corp., Carlsbad, NM (United States). Waste Isolation Div.

    1993-09-01

    The data presented in this report are the result of Brine Sampling and Evaluation Program (BSEP) activities at the Waste Isolation Pilot Plan (WIPP) during 1991. These BSEP activities document and investigate the origins, hydraulic characteristics, extent, and composition of brine occurrences in the Permian Salado Formation and seepage of that brine into the excavations at the WIPP. When excavations began at the WIPP in 1982, small brine seepages (weeps) were observed on the walls. Brine studies began as part of the Site Validation Program and were formalized as a program in its own right in 1985. During nine years of observations (1982--1991), evidence has mounted that the amount of brine seeping into the WIPP excavations is limited, local, and only a small fraction of that required to produce hydrogen gas by corroding the metal in the waste drums and waste inventory. The data through 1990 is discussed in detail and summarized by Deal and others (1991). The data presented in this report describes progress made during the calendar year 1991 and focuses on four major areas: (1) quantification of the amount of brine seeping across vertical surfaces in the WIPP excavations (brine ``weeps); (2) monitoring of brine inflow, e.g., measuring brines recovered from holes drilled downward from the underground drifts (downholes), upward from the underground drifts (upholes), and from subhorizontal holes; (3) further characterization of brine geochemistry; and (4) preliminary quantification of the amount of brine that might be released by squeezing the underconsolidated clays present in the Salado Formation.

  8. Microbiological study of naturally fermented Algerian green olives: isolation and identification of lactic acid bacteria and yeasts along with the effects of brine solutions obtained at the end of olive fermentation on Lactobacillus plantarum...

    Directory of Open Access Journals (Sweden)

    Nour-Eddine, Karam

    2006-09-01

    Full Text Available The microflora of naturally fermented green olives produced in Western Algeria was studied over 15, 60 and 90 day fermentation periods. Different microorganisms (aerobic bacteria, coliforms, staphylococci, lactic acid bacteria, lactobacilli, enterococci, yeasts, psychrotrophs and lipolytic bacteria were recorded at 15 and 60 days of fermentation. After 90 days (pH 4.40 of fermentation, the lactic acid bacteria population became dominant and persisted together with yeasts throughout the fermentation period. The lactic acid bacteria isolated (343 isolates were identified as L. casei, L. rhamnosus, L. paracasei, L. plantarum, L. lactis subsp. lactis, E. faecalis, E. faecium and E. durans. The dominant species was L. plantarum. Yeasts were isolated from all samples (32 isolates and were identified as Saccharomyces cerevisiae or Candida parapsilosis. Also, in this study we reported that brine solutions obtained at the end of olive fermentation were able to stimulate the growth of several L. plantarum strainsLa microflora de las aceitunas verdes fermentadas naturalmente elaboradas en Argelia Occidental fue estudiada en períodos de fermentación de 15, 60 y 90 días. Diferentes microorganismos (bacterias aeróbicas, coliformes, estafilococos, bacterias del ácido láctico, lactobacilos, enterococos, levaduras, psicotrofos y bacterias lipolíticas fueron detectados a los 15 y 60 días de fermentación. Después de 90 días de fermentación (pH 4.40, la población de bacterias lácticas se hizo dominante y persistió junto con las levaduras a lo largo de todo el proceso. Las bacterias lácticas aisladas (343 fueron identificadas como L. casei, L. rhamnosus, L. paracasei, L. plantarum, L. lactis subsp. lactis, E. faecalis, E. faecium y E. durans. La especie dominante fue L. plantarum. Las levaduras aisladas (32 de todas las muestras fueron identificadas como Saccharomyces cerevisiae o Candida parapsilosis. También se recoge en este estudio que las

  9. Possible Mars brines - Equilibrium and kinetic considerations

    Science.gov (United States)

    Zent, A. P.; Fanale, F. P.

    1986-01-01

    To determine the fate of postulated near surface brines on Mars, the rate of H2O mass loss from subsurface brines was calculated as a function of latitude, depth, regolith porosity, eutectic temperature, and pore size. A model for a chemically reasonable brine that could reproduce Martian radar results was developed, and the escape rate of H2O molecules from such a brine was estimated. It is suggested that the presence of a low-permeability duricrust may be required to preserve such a brine for reasonable periods, and to prevent detection of an extensive subsurface system by the Viking MAWD instrument.

  10. Cryogenic formation of brine and sedimentary mirabilite in submergent coastal lake basins, Canadian Arctic

    Science.gov (United States)

    Grasby, Stephen E.; Rod Smith, I.; Bell, Trevor; Forbes, Donald L.

    2013-06-01

    Two informally named basins (Mirabilite Basins 1 and 2) along a submergent coastline on Banks Island, Canadian Arctic Archipelago, host up to 1 m-thick accumulations of mirabilite (Na2SO4·10H2O) underlying stratified water bodies with basal anoxic brines. Unlike isostatically uplifting coastlines that trap seawater in coastal basins, these basins formed from freshwater lakes that were transgressed by seawater. The depth of the sill that separates the basins from the sea is shallow (1.15 m), such that seasonal sea ice formation down to 1.6 m isolates the basins from open water exchange through the winter. Freezing of seawater excludes salts, generating dense brines that sink to the basin bottom. Progressive freezing increases salinity of residual brines to the point of mirabilite saturation, and as a result sedimentary deposits of mirabilite accumulate on the basin floors. Brine formation also leads to density stratification and bottom water anoxia. We propose a model whereby summer melt of the ice cover forms a temporary freshwater lens, and rather than mixing with the underlying brines, it is exchanged with seawater once the ice plug that separates the basins from the open sea melts. This permits progressive brine development and density stratification within the basins.

  11. Numerical analysis for MHD thermal and solutal stratified stagnation point flow of Powell-Eyring fluid induced by cylindrical surface with dual convection and heat generation effects

    Science.gov (United States)

    Khalil-Ur-Rehman; Malik, M. Y.; Bilal, S.; Bibi, M.

    The current analysis reports the untapped characteristics of magneto-hydrodynamic dual convection boundary layer stagnation point flow of Powell-Eyring fluid by way of cylindrical surface. Flow exploration is carried out with the combined effects of thermal and solutal stratification. The strength of temperature and concentration adjacent to the cylindrical surface is assumed to be greater than the ambient fluid. Flow conducting mathematically modelled equations are fairly transformed into system of coupled non-linear ordinary differential equations with the aid of suitable transformations. The computations are made against these resultant coupled equations through shooting technique by the support of fifth order Runge-Kutta algorithm. A parametric study is performed to examine the effect logs of various pertinent flow controlling parameters on the velocity, temperature and concentration flow regime. The achieved outcomes are validated by developing comparison with existing published literature. In addition, numerical values of skin friction coefficient and Nusselt number are presented graphically for two different geometries namely, plate and cylinder.

  12. Brine Sampling and Evaluation Program, 1990 report

    International Nuclear Information System (INIS)

    Deal, D.E.; Abitz, R.J.; Myers, J.; Case, J.B.; Martin, M.L.; Roggenthen, W.M.; Belski, D.S.

    1991-08-01

    The data presented in this report are the result of Brine Sampling and Evaluation Program (BSEP) activities at the Waste Isolation Pilot Plant (WIPP) during 1990. When excavations began in 1982, small brine seepages (weeps) were observed on the walls. These brine occurrences were initially described as part of the Site Validation Program. Brine studies were formalized in 1985. The BSEP activities document and investigate the origins, hydraulic characteristics, extent, and composition of brine occurrences in the Permian Salado Formation and seepage of that brine into the excavations at the WIPP. The brine chemistry is important because it assists in understanding the origin of the brine and because it may affect possible chemical reactions in the buried waste after sealing the repository. The volume of brine and the hydrologic system that drives the brine seepage also need to be understood to assess the long-term performance of the repository. After more than eight years of observations (1982--1990), no credible evidence exists to indicate that enough naturally occurring brine will seep into the WIPP excavations to be of practical concern. The detailed observations and analyses summarized herein and in previous BSEP reports confirm the evidence apparent during casual visits to the underground workings -- that the excavations are remarkably dry

  13. Brine Sampling and Evaluation Program, 1990 report

    Energy Technology Data Exchange (ETDEWEB)

    Deal, D.E.; Abitz, R.J.; Myers, J.; Case, J.B.; Martin, M.L.; Roggenthen, W.M. [International Technology Corp., Albuquerque, NM (United States); Belski, D.S. [Westinghouse Electric Corp., Carlsbad, NM (United States). Waste Isolation Div.

    1991-08-01

    The data presented in this report are the result of Brine Sampling and Evaluation Program (BSEP) activities at the Waste Isolation Pilot Plant (WIPP) during 1990. When excavations began in 1982, small brine seepages (weeps) were observed on the walls. These brine occurrences were initially described as part of the Site Validation Program. Brine studies were formalized in 1985. The BSEP activities document and investigate the origins, hydraulic characteristics, extent, and composition of brine occurrences in the Permian Salado Formation and seepage of that brine into the excavations at the WIPP. The brine chemistry is important because it assists in understanding the origin of the brine and because it may affect possible chemical reactions in the buried waste after sealing the repository. The volume of brine and the hydrologic system that drives the brine seepage also need to be understood to assess the long-term performance of the repository. After more than eight years of observations (1982--1990), no credible evidence exists to indicate that enough naturally occurring brine will seep into the WIPP excavations to be of practical concern. The detailed observations and analyses summarized herein and in previous BSEP reports confirm the evidence apparent during casual visits to the underground workings -- that the excavations are remarkably dry.

  14. Kinetic Effect on the Freezing of Ammonium-Sodium-Carbonate-Chloride Brines and Implications for Origin of Ceres' Bright Spots

    Science.gov (United States)

    Hodyss, R. P.; Thomas, E. C.; Vu, T. H.; Johnson, P. V.; Choukroun, M.

    2017-12-01

    Subsurface brines on Ceres containing natrite (Na2CO3) and smaller amounts of NH4Cl or NH4HCO3 have been proposed to reach the dwarf planet's surface from an internal reservoir, where the brines freeze and result in bright spots across Ceres. Kinetically frozen solutions containing the likely constituents of Ceres' subsurface brines (ammonium, sodium, carbonate, and chloride ions) were studied via infrared and micro-Raman spectroscopy, where the flash-frozen mixtures were found to preferentially form ammonium chloride and ammonium bicarbonate, even in sodium-dominated solutions. Additionally, sodium chloride only formed when sodium or chloride (or both) were present in excess in the brine solutions. Raman spectroscopy was further employed to analyze the effect of vacuum exposure on these frozen brines over longer periods of time to simulate the surface conditions of Ceres.

  15. Handling the problem of the brine tubing bend on the basis of experiences gained during UGS - Mogilno construction

    International Nuclear Information System (INIS)

    Zola, P.; Skwarczynski, S.

    2005-01-01

    In the article problems of brine tubing bending and bent string cutting methods in the well conditions has been described. Implementation of safety joint in the brine string as an alternative solution that eliminates the need of cutting has been presented as well. (authors)

  16. Evaporation Rates of Brine on Mars

    Science.gov (United States)

    Sears, D. W. G.; Chittenden, J.; Moore, S. R.; Meier, A.; Kareev, M.; Farmer, C. B.

    2004-01-01

    While Mars is now largely a dry and barren place, recent data have indicated that water has flowed at specific locations within the last approx. 10(exp 6) y. This had led to a resurgence of interest in theoretical and experimental work aimed at understanding the behavior of water on Mars. There are several means whereby the stability of liquid water on Mars could be increased, one being the presence solutes that would depress the freezing point. Salt water on Earth is about 0.5M NaCl, but laboratory experiments suggest that martian salt water is quite different. We recently began a program of laboratory measurements of the stability of liquid water, ice and ice-dust mixtures under martian conditions and here report measurements of the evaporation rate of 0.25M brine.

  17. Brine Sampling and Evaluation Program: 1988 report

    International Nuclear Information System (INIS)

    Deal, D.E.; Abitz, R.J.; Case, J.B.; Crawley, M.E.; Deshler, R.M.; Drez, P.E.; Givens, C.A.; King, R.B.; Myers, J.; Pietz, J.M.; Roggenthen, W.M.; Tyburski, J.R.; Belski, D.S.; Niou, S.; Wallace, M.G.

    1989-12-01

    The data presented in this report are the result of Brine Sampling and Evaluation Program (BSEP) activities at the Waste Isolation Pilot Plant (WIPP) during 1988. These activities, which are a continuation and update of studies that began in 1982 as part of the Site Validation Program, were formalized as the BSEP in 1985 to document and investigate the origins, hydraulic characteristics, extent, and composition of brine occurrences in the Permian Salado Formation, and seepage of that brine into the excavations at the WIPP. Previous BSEP reports (Deal and Case, 1987; Deal and others, 1987) described the results of ongoing activities that monitor brine inflow into boreholes in the facility, moisture content of the Salado Formation, brine geochemistry, and brine weeps and crusts. The information provided in this report updates past work and describes progress made during the calendar year 1988. During 1988, BSEP activities focused on four major areas to describe and quantify brine activity: (1) monitoring of brine inflow parameters, e.g., measuring brines recovered from holes drilled upward from the underground drifts (upholes), downward from the underground drifts (downholes), and near-horizontal holes; (2) characterizing the brine, e.g., the geochemistry of the brine and the presence of bacteria and their possible interactions with experiments and operations; (3) characterizing formation properties associated with the occurrence of brine; e.g., determining the water content of various geologic units, examining these units in boreholes using a video camera system, and measuring their resistivity (conductivity); and (4) modeling to examine the interaction of salt deformation near the workings and brine seepage through the deforming salt. 77 refs., 48 figs., 32 tabs

  18. A carbon inventory for Orca Basin brines and sediments

    International Nuclear Information System (INIS)

    Sackett, W.M.; Brooks, J.M.; Bernard, B.B.; Schwab, C.R.; Chung, H.; Parker, R.A.

    1979-01-01

    Orca Basin, an intraslope depression at a depth of about 2400 m on the continental slope of the north-central Gulf of Mexico, contains an anoxic, hypersaline brine similar to composition to those reported in the Red Sea. Concentrations and stable carbon isotope compositions of various inorganic and organic carbon species have been determined on the brine and sediments in order to gain an understanding of the origin and cycling of carbon in this unique environment. ΣCO 2 in the brine (55 mg C/l) is about twice seawater with delta 13 C sub(PDB)=-16.4per thousand and Δ 14 C=-501per thousand. CH 4 has a concentration of 12 mg C/l and delta 13 C=-73.5per thousand. Dissolved and particulate organic carbon concentrations are seven times higher and have delta 13 C values several permil different than the overlying seawater, ΣCO 2 and CH 4 in the interstitial waters are considerably higher in concentrations and isotropically light than the overlying brine. Solution of near-surface salt deposits by seawater with subsequent microbial production and consumption of methane can be used to explain most of the data. (Auth.)

  19. Permeability of salt-crystal interfaces to brine

    International Nuclear Information System (INIS)

    Gilpatrick, L.O.; Baes, C.F. Jr.; Shor, A.J.; Canonico, C.M.

    1982-06-01

    To investigate the movement of brine along grain boundaries in polycrystalline salt, measurements have been made of the radial flow of brine through the interface between cylindrical salt crystals under axial stresses to 140 bar and temperatures to 80 0 C. For constant conditions, the total flow of brine showed a linear dependence on the logarithm of time, and the reciprocal permeability increased linearly with time. Loss of salt from the interface by pressure solution effects was more than enough to account for the decrease in the apparent thickness of the interface (i.e., that which may be estimated for an interface of the same permeability formed by plane parallel surfaces). This apparent thickness, initially as large as 10 μm, decreased to as little as 0.2 μm with exposure to stress and flowing brine. It decreased quickly with sudden increases in axial stress and usually increased, though not reversibly, with decreases in stress. The rate of increase in the reciprocal permeability with time was roughly proportional to the stress and to the square of the hydraulic pressure drop. Assuming similar apparent thicknesses for the grain boundaries in polycrystalline salt, permeabilities are predicted that are quite consistent with the low values reported for stressed core specimens

  20. Attempt to enrich of a new spontaneous fissioning nuclide by evaporation of natural brine

    International Nuclear Information System (INIS)

    Adamek, A.; Zhuravleva, E.L.; Constantinescu, M.; Constantinescu, o.; Chuburkov, Yu.T.

    1983-01-01

    The enrichment of the new spontaneous fissioning nuclide discovered in the Cheleken brine, was made by evaporation. The purpose of this work was the comparison of behaviour of the new spontaneous fissioning nuclide with that of the known elements in the formation processes of the high concentration brines. Spontaneous fission of the nuclide was measured by means of the counters for multiple emission of neutrons. It is shown that the new spontaneous fissioning nuclide was enriched as well as other trace elements (Hg, Tl, Bi and Pb) in a solution remained after the evaporation of the initial solution. The conclusion is drawn that from the sea water brines could be obtained by evaporation which are enriched in trace elements with an enrichment degree higher than the natural brines

  1. Indirect boundary element method on recursive matrix operation to compute waves in irregularly stratified media with infinitely extended interfaces. Perturbation by a point source; Kansetsu kyokai yosoho ni yoru fukisoku seiso kozochu no hadoba no keisanho. Tenshingen ni taisuru reference solution no riyo

    Energy Technology Data Exchange (ETDEWEB)

    Yokoi, T [Akita University, Akita (Japan). Mining College

    1996-05-01

    As a method of computation of wave fields in irregularly stratified media by use of the indirect boundary element method, an induction formula was proposed in a previous report, utilizing the reference solution representing the wave field in corresponding horizontally stratified media. This algorithm applies to other types of vibration source. In computation of a wave field with the focus in presence on the ground or in the ground, the algorithm is incorporated into the computation as a vector including the reference solution as a variable. There exists no need to modify the algorithm. Once the reference solution is obtained, the wave field in the irregularly stratified media is automatically constructed by the proposed algorithm. The wave field to be the reference solution to a point source in the horizontally stratified media, is determined when the solution is obtained of the frequency/wavenumber domain by use of the reflection/transmission matrix of Kennet (1983) and converted into the solution of the spatial domain by use of the discrete wavenumber representation of Bouchon and Aki (1977). 8 refs., 2 figs.

  2. Geochemical evolution of brines in the Salar of Uyuni, Bolivia.

    Science.gov (United States)

    Rettig, S.L.; Jones, B.F.; Risacher, F.

    1980-01-01

    Recent analyses of brines from the Salars of Uyuni and Coipasa have been compared with published data for Lakes Titicaca and Poopo to evaluate solute compositional trends in these remnants of two large Pleistocene lakes once connected by overflow from the N to the S of the Bolivian Altiplano. From Titicaca to Poopo the water shows an increase in Cl and N somewhat greater than the total solutes. Ca and SO4 increase to a lesser extent than total dissolved solids, and carbonate species are relatively constant. Between Poopo and Coipasa proportions of Ca, SO4 and CO3 continue to decrease. At Coipasa and Uyuni, the great salars frequently evaporate to halite saturation. Halite crystallization is accompanied by an increased K, Mg and SO4 in residual brines. - from Authors

  3. Origin of the yellow brine and the black brine in Sichuan Basin

    International Nuclear Information System (INIS)

    Wang Dongsheng

    1988-01-01

    The spring water, geothermal water and Cretaceous brine in the outer zone of the Sichuan Basin has the Craig relationship, and they are cycling waters. The brine in the inner zone is mainly metasedimentary water. A basic feature of them is poor in 2 H, but rich in 18 O. The δD-values of the yellow brine in Jurassic and Upper Triassic aquifer of continental facies varies from -62.25 to -22.4, and the δ 18 O-values are -6.72 - +6.02. The δD-values of the black brine in marine aquifer (T 2 ,T 1 ,P,C,O and so on) varies from -49 to -25.1, and the 18 O values are +3.89 - +6.14. The δD of yellow brine is similar to that of meteoric water, and the δD of the black brine is around that of crystallization water expelled from gypsum by anhydritization. Increases of salinity in Jurassic yellow brine result primarily from the evapotranspiration process. The salinity in Upper Triassic yellow brine in Aa sub-area originated from underlying rock salt which was leached by paleometeoric water. Triassic black brine derived from the mixing of the crystallization water leached from rock salt with the residual sea water after salt crystallization. In Zhigong, the composition of yellow brine has mainly been changed by the mixing of the yellow brine with the black brine. (author). 2 refs, 2 figs, 2 tabs

  4. REFUSE OF FERMENTATION BRINES IN THE CUCUMBER PICKLING INDUSTRY

    Science.gov (United States)

    The project evaluated on a commercial scale the technological and economic feasibility of recycling spent cucumber fermentation brine. Two brine treatment procedures, heat treatment and chemical treatment, were used. The results showed that brine recycling was practical on a comm...

  5. On the physico-chemical characteristics of brines

    Digital Repository Service at National Institute of Oceanography (India)

    Shirodkar, P.V.; Rao, P.V.S.S.D.P.; Singbal, S.Y.S.

    Analyses of the natural brines form the salt lakes, salt pans and the artificial brines obtained after the solar desalination of seawater respectively, showed wide differences in their physico-chemical characteristics. The natural brines are markEd...

  6. Grain distinct stratified nanolayers in aluminium alloys

    Energy Technology Data Exchange (ETDEWEB)

    Donatus, U., E-mail: uyimedonatus@yahoo.com [School of Materials, The University of Manchester, Manchester, M13 9PL, England (United Kingdom); Thompson, G.E.; Zhou, X.; Alias, J. [School of Materials, The University of Manchester, Manchester, M13 9PL, England (United Kingdom); Tsai, I.-L. [Oxford Instruments NanoAnalysis, HP12 2SE, High Wycombe (United Kingdom)

    2017-02-15

    The grains of aluminium alloys have stratified nanolayers which determine their mechanical and chemical responses. In this study, the nanolayers were revealed in the grains of AA6082 (T6 and T7 conditions), AA5083-O and AA2024-T3 alloys by etching the alloys in a solution comprising 20 g Cr{sub 2}O{sub 3} + 30 ml HPO{sub 3} in 1 L H{sub 2}O. Microstructural examination was conducted on selected grains of interest using scanning electron microscopy and electron backscatter diffraction technique. It was observed that the nanolayers are orientation dependent and are parallel to the {100} planes. They have ordered and repeated tunnel squares that are flawed at the sides which are aligned in the <100> directions. These flawed tunnel squares dictate the tunnelling corrosion morphology as well as appearing to have an affect on the arrangement and sizes of the precipitation hardening particles. The inclination of the stratified nanolayers, their interpacing, and the groove sizes have significant influence on the corrosion behaviour and seeming influence on the strengthening mechanism of the investigated aluminium alloys. - Highlights: • Stratified nanolayers in aluminium alloy grains. • Relationship of the stratified nanolayers with grain orientation. • Influence of the inclinations of the stratified nanolayers on corrosion. • Influence of the nanolayers interspacing and groove sizes on hardness and corrosion.

  7. The stratified Boycott effect

    Science.gov (United States)

    Peacock, Tom; Blanchette, Francois; Bush, John W. M.

    2005-04-01

    We present the results of an experimental investigation of the flows generated by monodisperse particles settling at low Reynolds number in a stably stratified ambient with an inclined sidewall. In this configuration, upwelling beneath the inclined wall associated with the Boycott effect is opposed by the ambient density stratification. The evolution of the system is determined by the relative magnitudes of the container depth, h, and the neutral buoyancy height, hn = c0(ρp-ρf)/|dρ/dz|, where c0 is the particle concentration, ρp the particle density, ρf the mean fluid density and dρ/dz Boycott layer transports dense fluid from the bottom to the top of the system; subsequently, the upper clear layer of dense saline fluid is mixed by convection. For sufficiently strong stratification, h > hn, layering occurs. The lowermost layer is created by clear fluid transported from the base to its neutral buoyancy height, and has a vertical extent hn; subsequently, smaller overlying layers develop. Within each layer, convection erodes the initially linear density gradient, generating a step-like density profile throughout the system that persists after all the particles have settled. Particles are transported across the discrete density jumps between layers by plumes of particle-laden fluid.

  8. Modelling CO2-Brine Interfacial Tension using Density Gradient Theory

    KAUST Repository

    Ruslan, Mohd Fuad Anwari Che

    2018-03-01

    Knowledge regarding carbon dioxide (CO2)-brine interfacial tension (IFT) is important for petroleum industry and Carbon Capture and Storage (CCS) strategies. In petroleum industry, CO2-brine IFT is especially importance for CO2 – based enhanced oil recovery strategy as it affects phase behavior and fluid transport in porous media. CCS which involves storing CO2 in geological storage sites also requires understanding regarding CO2-brine IFT as this parameter affects CO2 quantity that could be securely stored in the storage site. Several methods have been used to compute CO2-brine interfacial tension. One of the methods employed is by using Density Gradient Theory (DGT) approach. In DGT model, IFT is computed based on the component density distribution across the interface. However, current model is only applicable for modelling low to medium ionic strength solution. This limitation is due to the model only considers the increase of IFT due to the changes of bulk phases properties and does not account for ion distribution at interface. In this study, a new modelling strategy to compute CO2-brine IFT based on DGT was proposed. In the proposed model, ion distribution across interface was accounted for by separating the interface to two sections. The saddle point of tangent plane distance where ( ) was defined as the boundary separating the two sections of the interface. Electrolyte is assumed to be present only in the second section which is connected to the bulk liquid phase side. Numerical simulations were performed using the proposed approach for single and mixed salt solutions for three salts (NaCl, KCl, and CaCl2), for temperature (298 K to 443 K), pressure (2 MPa to 70 MPa), and ionic strength (0.085 mol·kg-1 to 15 mol·kg-1). The simulation result shows that the tuned model was able to predict with good accuracy CO2-brine IFT for all studied cases. Comparison with current DGT model showed that the proposed approach yields better match with the experiment data

  9. Brine crude oil interactions at the oil-water interface

    DEFF Research Database (Denmark)

    Chakravarty, Krishna Hara; Fosbøl, Philip Loldrup; Thomsen, Kaj

    2015-01-01

    The impact of brine salinity and its ionic composition on oil displacement efficiency has been investigated extensively in recent years due to the potential of enhanced oil recovery (EOR). Wettability alterations through relative interactions at the mineral surface have been the basis of proposed...... in enhancing oil emulsion formation by increasing interactions between polar acids and brine solutions. The results propose the potential use of HPO42- ions in reservoirs having inactive mineral surfaces. The relative oil affinity of different ions including K+, Na+, Mg2+, and Ca2+ (cations), and Cl-, SO42...... and thus reduces the interfacial viscoelasticity of the trapped oil. These results show significant correlation between oil emulsion formation and increased oil recovery. Copyright 2015; Society of Petroleum Engineers...

  10. Gypsum and hydrohalite dynamics in sea ice brines

    Science.gov (United States)

    Butler, Benjamin M.; Papadimitriou, Stathys; Day, Sarah J.; Kennedy, Hilary

    2017-09-01

    Mineral authigenesis from their dissolved sea salt matrix is an emergent feature of sea ice brines, fuelled by dramatic equilibrium solubility changes in the large sub-zero temperature range of this cryospheric system on the surface of high latitude oceans. The multi-electrolyte composition of seawater results in the potential for several minerals to precipitate in sea ice, each affecting the in-situ geochemical properties of the sea ice brine system, the habitat of sympagic biota. The solubility of two of these minerals, gypsum (CaSO4 ·2H2O) and hydrohalite (NaCl · 2H2O), was investigated in high ionic strength multi-electrolyte solutions at below-zero temperatures to examine their dissolution-precipitation dynamics in the sea ice brine system. The gypsum dynamics in sea ice were found to be highly dependent on the solubilities of mirabilite and hydrohalite between 0.2 and - 25.0 ° C. The hydrohalite solubility between - 14.3 and - 25.0 ° C exhibits a sharp change between undersaturated and supersaturated conditions, and, thus, distinct temperature fields of precipitation and dissolution in sea ice, with saturation occurring at - 22.9 ° C. The sharp changes in hydrohalite solubility at temperatures ⩽-22.9 °C result from the formation of an ice-hydrohalite aggregate, which alters the structural properties of brine inclusions in cold sea ice. Favourable conditions for gypsum precipitation in sea ice were determined to occur in the region of hydrohalite precipitation below - 22.9 ° C and in conditions of metastable mirabilite supersaturation above - 22.9 ° C (investigated at - 7.1 and - 8.2 ° C here) but gypsum is unlikely to persist once mirabilite forms at these warmer (>-22.9 °C) temperatures. The dynamics of hydrohalite in sea ice brines based on its experimental solubility were consistent with that derived from thermodynamic modelling (FREZCHEM code) but the gypsum dynamics derived from the code were inconsistent with that indicated by its

  11. Kinetics of radioisotope exchange between brine and rock in a geothermal system

    International Nuclear Information System (INIS)

    Hammond, D.E.; Zukin, J.G.; Teh-Lung Ku

    1988-01-01

    A wide range of isotopes in the /sup 238/U, /sup 235/U, and /sup 232/Th decay chains was measured in geothermal brines collected from two production zones at 1898 and 3220 m in the Salton Sea Scientific Drilling Project well. High concentrations of radium, radon, and lead isotopes are generated and maintained by the input of these isotopes from solid phases into brine by both recoil and leaching processes, by the high chloride content of the brine which complexes radium and lead, and by the apparent absence of suitable unoccupied adsorption sites. In contrast, uranium, thorium, actinium, bismuth, and polonium isotopes all have low concentrations due to their efficient sorption from brine to rock. Measurements of short-lived isotopes in these decay series yield insights regarding the mechanisms controlling radioisotope exchange, and they permit estimation of rates of brine-rock interaction. For example, the /sup 228/Ac//sup 228/Ra activity ratio of 0.2 in brines indicates that the mean residence time of actinium in solution before sorption onto solid surfaces is less than 2.5 hours

  12. Migration of brine inclusions in salt

    International Nuclear Information System (INIS)

    Pigford, T.H.

    1982-01-01

    Theories of the migration of brine inclusions in salt are interpreted as simple physical processes, and theories by Russian and U.S. workers are shown to yield the same results. The migration theory is used to predict threshold temperature gradients below which migration of brine inclusions should not occur. The predicted threshold gradients are compared with the temperature gradients expected at the Waste Isolation Pilot Plant in New Mexico. The theory of a threshold gradient helps explain the existence of brine inclusions in natural salt deposits

  13. Zooplankton at deep Red Sea brine pools

    KAUST Repository

    Kaartvedt, Stein

    2016-03-02

    The deep-sea anoxic brines of the Red Sea comprise unique, complex and extreme habitats. These environments are too harsh for metazoans, while the brine–seawater interface harbors dense microbial populations. We investigated the adjacent pelagic fauna at two brine pools using net tows, video records from a remotely operated vehicle and submerged echosounders. Waters just above the brine pool of Atlantis II Deep (2000 m depth) appeared depleted of macrofauna. In contrast, the fauna appeared to be enriched at the Kebrit Deep brine–seawater interface (1466 m).

  14. Waste glass/metal interactions in brines

    International Nuclear Information System (INIS)

    Shade, J.W.; Pederson, L.R.; McVay, G.L.

    1983-05-01

    Leaching studies of MCC 76-68 glass in synthetic brines high in NaCl were performed from 50 to 150 0 C and included interactive testing with ductile iron and titanium. Hydrolysis of the glass matrix was generally slower in saturated brines than in deionized water, due to a lower solubility of silica in the brines. Inclusion of ductile iron in the tests resulted in accelerated leach rates because irion-silica reactions occurred which reduced the silica saturation fraction. At 150 0 C, iron also accelerated the rate of crystalline reaction product formation which were primarily Fe-bearing sepiolite and talc. 16 references

  15. CONTACT ANGLE OF YUCCA MOUNTAIN WELDED TUFF WITH WATER AND BRINES

    International Nuclear Information System (INIS)

    H. Kalia

    2006-01-01

    A number of tests were performed to acquire contact angles between Yucca Mountain welded tuff from Topopah Springs Lower Lithophysal geologic unit and various brine solutions. The tests were performed on core disks received from Sample Management Facility (SMF), oven dried to a constant weight and the core disks vacuum saturated in: distilled water, J-13 water, calcium chloride brine and sodium chloride brine to constant weight. The contact angles were acquired from eight points on the surface of the core disks, four on rough surface, and four on polished surface. The contact angle was measured by placing a droplet of the test fluid, distilled water, J-13 water, calcium chloride brine and sodium chloride brine on the core disks. The objective of this test was to acquire contact angles as a potential input to estimating capillary forces in accumulated dust on the waste packages and drip shields slated for the proposed High-Level Radioactive Waste Repository at Yucca Mountain, Nevada. It was noted that once the droplet contacts the test surface, it continues to spread hence the contact angle continues to decrease with elapsed time. The maximum observed angle was at time 0 or when the drop contacted the rock surface. The measured contact angle, in all cases has significant scatter. In general, the time zero contact angles for core disks saturated in sodium chloride brine were smaller than those saturated in calcium chloride brine, distilled water, and J-13 water. The contact angles for samples saturated in distilled water, J-13 water and calcium chloride brine at time zero were similar. There was slight difference between the observed contact angles for smooth and rough surface of the test samples. The contact angles for smooth surfaces were smaller than for the rough surfaces

  16. Radiation chemistry of salt-mine brines and hydrates

    International Nuclear Information System (INIS)

    Jenks, G.H.; Walton, J.R.; Bronstein, H.R.; Baes, C.F. Jr.

    1981-07-01

    Certain aspects of the radiation chemistry of NaCl-saturated MgCl 2 solutions and MgCl 2 hydrates at temperatures in the range of 30 to 180 0 C were investigated through experiments. A principal objective was to establish the values for the yields of H 2 [G(H 2 )] and accompanying oxidants in the gamma-ray radiolysis of concentrated brines that might occur in waste repositories in salt. We concluded that G(H 2 ) from gamma-irradiated brine solution into a simultaneously irradiated, deaerated atmosphere above the solution is between 0.48 and 0.49 over most of the range 30 to 143 0 C. The yield is probably somewhat lower at the lower end of this range, averaging 0.44 at 30 to 45 0 C. Changes in the relative amounts of MgCl 2 and NaCl in the NaCl-saturated solutions have negligible effects on the yield. The yield of O 2 into the same atmosphere averages 0.13, independent of the temperature and brine composition, showing that only about 50% of the radiolytic oxidant that was formed along with the H 2 was present as O 2 . We did not identify the species that compose the remainder of the oxidant. We concluded that the yield of H 2 from a gamma-irradiated brine solution into a simultaneously irradiated atmosphere containing 5 to 8% air in He may be greater than the yield in deaerated systems by amounts ranging from 0% for temperatures of 73 to 85 0 C, to about 30 and 40% for temperatures in the ranges 100 to 143 0 C and 30 to 45 0 C, respectively. We did not establish the mechanism whereby the air affected the yields of H 2 and O 2 . The values found in this work for G(H 2 ) in deaerated systems are in approximate agreement with the value of 0.44 for the gamma-irradiation yield of H 2 in pure H 2 O at room temperature. They are also in agreement with the values predicted by extrapolation from the findings of previous researchers for the value for G(H 2 ) in 2 M NaCl solutions at room temperature

  17. Modeling Episodic Ephemeral Brine Lake Evaporation and Salt Crystallization on the Bonneville Salt Flats, Utah

    Science.gov (United States)

    Liu, T.; Harman, C. J.; Kipnis, E. L.; Bowen, B. B.

    2017-12-01

    Public concern about apparent reductions in the areal extent of the Bonneville Salt Flat (BSF) and perceived changes in inundation frequency has motivated renewed interest in the hydrologic and geochemical behavior of this salt playa. In this study, we develop a numerical modeling framework to simulate the relationship between hydrometeorologic variability, brine evaporation and salt crystallization processes on BSF. The BSF, locates in Utah, is the remnant of paleo-lake Bonneville, and is capped by up to 1 meter of salt deposition over a 100 km2 area. The BSF has two distinct hydrologic periods each year: a winter wet periods with standing surface brine and the summer dry periods when the brine is evaporated, exposing the surface salt crust. We develop a lumped non-linear dynamical models coupling conservation expressions from water, dissolved salt and thermal energy to investigate the seasonal and diurnal behavior of brine during the transition from standing brine to exposed salt at BSF. The lumped dynamic models capture important nonlinear and kinetic effects introduced by the high ionic concentration of the brine, including the pronounced effect of the depressed water activity coefficient on evaporation. The salt crystallization and dissolution rate is modeled as a kinetic process linearly proportional to the degree of supersaturation of brine. The model generates predictions of the brine temperature and the solute and solvent masses controlled by diurnal net radiation input and aerodynamic forcing. Two distinct mechanisms emerge as potential controls on salt production and dissolution: (1) evapo-concentration and (2) changes in solubility related to changes in brine temperature. Although the evaporation of water is responsible for ultimate disappearance of the brine each season ,variation in solubility is found to be the dominant control on diurnal cycles of salt precipitation and dissolution in the BSF case. Most salt is crystallized during nighttime, but the

  18. TOUGHREACT Testing in High Ionic Strength Brine Sandstone Systems

    International Nuclear Information System (INIS)

    Xu, Tianfu

    2008-01-01

    Deep saline formations and oil and gas reservoirs often contain concentrated brine solutions of ionic strength greater than 1 (I > 1 M). Geochemical modeling, involving high ionic strength brines, is a challenge. In the original TOUGHREACT code (Xu et al., 2004; Xu et al., 2006), activity coefficients of charged aqueous species are computed using an extended Debye-Huckel (DH) equation and parameters derived by Helgeson et al. (1981). The DH model can deal with ionic strengths from dilute to moderately saline water (up to 6 molal for an NaCl-dominant solution). The equations implemented for the DH model are presented in Appendix A. During the course of the Yucca Mountain project, a Pitzer ion-interaction model was implemented into TOUGHREACT. This allows the application of this simulator to problems involving much more concentrated aqueous solutions, such as those involving geochemical processes in and around high-level nuclear waste repositories where fluid evaporation and/or boiling is expected to occur (Zhang et al., 2007). The Pitzer ion-interaction model, which we refer to as the Pitzer virial approach, and associated ion-interaction parameters have been applied successfully to study non-ideal concentrated aqueous solutions. The formulation of the Pitzer model is presented in Appendix B; detailed information can be founded in Zhang et al. (2007). For CO 2 geological sequestration, the Pitzer ion-interaction model for highly concentrated brines was incorporated into TOUGHREACT/ECO2N, then was tested and compared with a previously implemented extended Debye-Hueckel (DH) ion activity model. The comparison was made through a batch geochemical system using a Gulf Coast sandstone saline formation

  19. Enhanced Brine Dewatering System, Phase I

    Data.gov (United States)

    National Aeronautics and Space Administration — The purpose of the Enhanced Brine Dewatering System (EBDS) is to provide an easily scalable means of completely recovering usable water from byproducts created by...

  20. Brine Dewatering Using Ultrasonic Nebulization, Phase I

    Data.gov (United States)

    National Aeronautics and Space Administration — Recovery of water from brine is critically important for manned space exploration. Resupply of water is prohibitively costly for extended missions. It is anticipated...

  1. Ice Control with Brine on Highways

    DEFF Research Database (Denmark)

    Bolet, Lars

    traffic flow the spread rate of pure sodium chloride (and thus the environmental impact) in the pre-salting operations was cut back by more than one third. Compared to neighbouring counties the use of salt is less than fifty percent per square meter. In addition, supply of brine from two mixer...... of interpreting this information. The improvements gained by the county of Funen were mainly due to the use of technologies (brine spreading with nozzles) giving a more precise spread pattern than the traditional gritting of pre-wetted salt. Major challenges in the process have been to verify the higher quality...... of the nozzles spread pattern, to ensure maximum utilization of volume of brine carried by the spreading vehicles and to control the mixing of brine without getting stratification in the mixture. Moreover, of course, to ensure political approval of abandoning a well-served technology and to organize...

  2. Brine Dewatering Using Ultrasonic Nebulization, Phase II

    Data.gov (United States)

    National Aeronautics and Space Administration — Recovery of water from brine is critically important for future manned space exploration. Resupply of water is prohibitively costly for such extended missions. Water...

  3. Distillation Brine Purification for Resource Recovery Applications

    Data.gov (United States)

    National Aeronautics and Space Administration — Wastewater processing systems for space generate residual brine that contains water and salts that could be recovered to reduce life support consumables. The project...

  4. Enhanced Brine Dewatering System, Phase II

    Data.gov (United States)

    National Aeronautics and Space Administration — The purpose of the Enhanced Brine Dewatering System (EBDS) is to provide a scalable means of completely recovering usable water from byproducts created by reverse...

  5. Space and Industrial Brine Drying Technologies

    Science.gov (United States)

    Jones, Harry W.; Wisniewski, Richard S.; Flynn, Michael; Shaw, Hali

    2014-01-01

    This survey describes brine drying technologies that have been developed for use in space and industry. NASA has long considered developing a brine drying system for the International Space Station (ISS). Possible processes include conduction drying in many forms, spray drying, distillation, freezing and freeze drying, membrane filtration, and electrical processes. Commercial processes use similar technologies. Some proposed space systems combine several approaches. The current most promising candidates for use on the ISS use either conduction drying with membrane filtration or spray drying.

  6. Influence of radiolytic products on the chemistry of uranium VI in brines

    International Nuclear Information System (INIS)

    Lucchini, J-F.; Reed, D.T.; Borkowski, M.; Rafalski, A.; Conca, J.

    2004-01-01

    In the near field of a salt repository of nuclear waste, ionizing radiations can strongly affect the chemistry of concentrated saline solutions. Radiolysis can locally modify the redox conditions, speciation, solubility and mobility of the actinide compounds. In the case of uranium VI, radiolytic products can not only reduce U(VI), but also react with uranium species. The net effect on the speciation of uranyl depends on the relative kinetics of the reactions and the buildup of molecular products in brine solutions. The most important molecular products in brines are expected to be hypochlorite ion, hypochlorous acid and hydrogen peroxide. Although U(VI) is expected not to be significantly affected by radiolysis, the combined effects of the major molecular radiolytic products on the chemistry of U(VI) in brines have not been experimentally established previously. (authors)

  7. Experimental evaporation of hyperacid brines : Effects on chemical composition and chlorine isotope fractionation

    NARCIS (Netherlands)

    Rodríguez, Alejandro; van Bergen, Manfred J.; Eggenkamp, H. G.M.

    2018-01-01

    Hyperacid brines from active volcanic lakes are some of the chemically most complex aqueous solutions on Earth. Their compositions provide valuable insights into processes of elemental transfer from a magma body to the surface and interactions with solid rocks and the atmosphere. This paper

  8. Natural heat storage in a brine-filled solar pond in the Tully Valley of central New York

    Science.gov (United States)

    Hayhurst, Brett; Kappel, William M.

    2014-01-01

    The Tully Valley, located in southern Onondaga County, New York, has a long history of unusual natural hydrogeologic phenomena including mudboils (Kappel, 2009), landslides (Tamulonis and others, 2009; Pair and others, 2000), landsurface subsidence (Hackett and others, 2009; Kappel, 2009), and a brine-filled sinkhole or “Solar pond” (fig. 1), which is documented in this report. A solar pond is a pool of salty water (brine) which stores the sun’s energy in the form of heat. The saltwater naturally forms distinct layers with increasing density between transitional zones (haloclines) of rapidly changing specific conductance with depth. In a typical solar pond, the top layer has a low salt content and is often times referred to as the upper convective zone (Lu and others, 2002). The bottom layer is a concentrated brine that is either convective or temperature stratified dependent on the surrounding environment. Solar insolation is absorbed and stored in the lower, denser brine while the overlying halocline acts as an insulating layer and prevents heat from moving upwards from the lower zone (Lu and others, 2002). In the case of the Tully Valley solar pond, water within the pond can be over 90 degrees Fahrenheit (°F) in late summer and early fall. The purpose of this report is to summarize observations at the Tully Valley brine-filled sinkhole and provide supplemental climate data which might affect the pond salinity gradients insolation (solar energy).

  9. Brine transport studies in the bedded salt of the Waste Isolation Pilot Plant (WIPP)

    International Nuclear Information System (INIS)

    McTigue, D.F.; Nowak, E.J.

    1987-01-01

    Brine flow has been measured to unheated boreholes for periods of a few days and to heated holes for two years in the WIPP facility. It is suggested that Darcy flow may dominate the observed influx of brine. Exact solutions to a linearized model for one-dimensional, radial flow are evaluated for conditions approximating the field experiments. Flow rates of the correct order of magnitude are calculated for permeabilities in the range 10 -21 to 10 -20 m 2 (1 to 10 nanodarcy) for both the unheated and heated cases. 20 refs., 3 figs., 1 tab

  10. Electromagnetic waves in stratified media

    CERN Document Server

    Wait, James R; Fock, V A; Wait, J R

    2013-01-01

    International Series of Monographs in Electromagnetic Waves, Volume 3: Electromagnetic Waves in Stratified Media provides information pertinent to the electromagnetic waves in media whose properties differ in one particular direction. This book discusses the important feature of the waves that enables communications at global distances. Organized into 13 chapters, this volume begins with an overview of the general analysis for the electromagnetic response of a plane stratified medium comprising of any number of parallel homogeneous layers. This text then explains the reflection of electromagne

  11. Lithium recovery from salt lake brine by H2TiO3.

    Science.gov (United States)

    Chitrakar, Ramesh; Makita, Yoji; Ooi, Kenta; Sonoda, Akinari

    2014-06-21

    The details of the ion exchange properties of layered H2TiO3, derived from the layered Li2TiO3 precursor upon treatment with HCl solution, with lithium ions in the salt lake brine (collected from Salar de Uyuni, Bolivia) are reported. The lithium adsorption rate is slow, requiring 1 d to attain equilibrium at room temperature. The adsorption of lithium ions by H2TiO3 follows the Langmuir model with an adsorptive capacity of 32.6 mg g(-1) (4.7 mmol g(-1)) at pH 6.5 from the brine containing NaHCO3 (NaHCO3 added to control the pH). The total amount of sodium, potassium, magnesium and calcium adsorbed from the brine was lithium ions from the brine containing competitive cations such as sodium, potassium, magnesium and calcium in extremely large excess. The results indicate that the selectivity order Li(+) ≫ Na(+), K(+), Mg(2+), Ca(2+) originates from a size effect. The H2TiO3 can be regenerated and reused for lithium exchange in the brine with an exchange capacity very similar to the original H2TiO3.

  12. Stratified medicine and reimbursement issues

    NARCIS (Netherlands)

    Fugel, Hans-Joerg; Nuijten, Mark; Postma, Maarten

    2012-01-01

    Stratified Medicine (SM) has the potential to target patient populations who will most benefit from a therapy while reducing unnecessary health interventions associated with side effects. The link between clinical biomarkers/diagnostics and therapies provides new opportunities for value creation to

  13. Portable brine evaporator unit, process, and system

    Science.gov (United States)

    Hart, Paul John; Miller, Bruce G.; Wincek, Ronald T.; Decker, Glenn E.; Johnson, David K.

    2009-04-07

    The present invention discloses a comprehensive, efficient, and cost effective portable evaporator unit, method, and system for the treatment of brine. The evaporator unit, method, and system require a pretreatment process that removes heavy metals, crude oil, and other contaminates in preparation for the evaporator unit. The pretreatment and the evaporator unit, method, and system process metals and brine at the site where they are generated (the well site). Thus, saving significant money to producers who can avoid present and future increases in transportation costs.

  14. Microstructural analysis of metal solution interfacial films in the multiphase brine CO{sub 2}, H{sub 2}S hydrocarbon inhibitor system; Analise microestrutural de filmes na interface metal-solucao no sistema multifasico salmoura Co{sub 2}/H{sub 2}S hidrocarboneto inibidor

    Energy Technology Data Exchange (ETDEWEB)

    Forero, Adriana; Yesid Pena, Dario [Universidad Industrial de Santander, Bucaramanga (Colombia); Bott, Ivani de S. [Pontificia Univ. Catolica do Rio de Janeiro, RJ (Brazil). Dept. de Ciencia dos Materiais e Metalurgia

    2005-07-01

    This work presents an analysis of the formation of different films obtained at the metal - solution interface in a multiphase Brine - CO{sub /}H{sub 2}S Hydrocarbon - Inhibitor - Steel AISI SAE 1020 system. Tests were carried out on loss of mass test pieces in a static autoclave, for exposure times of 21 days. Infrared Absorption Spectroscopy (IAS), X Ray Diffraction (XRD) and Scanning Electronic Microscopy (SEM) techniques, were used for the analysis of the products of corrosion and the inhibitor films formed. The results obtained for XRD indicate the formation hydrous oxide of iron, Siderite, Magnetite, and in some cases chloride crystals and iron sulphates. The results obtained by SEM, show that the thin films of the inhibitor and corrosion products have irregular surfaces, are porous, fragile and have little adhesion to the metal. Additionally the generation of primary films of carbonate of iron saturated with carbon and oxide of iron was confirmed and also the formation of secondary carbonates of iron due to recrystallization of the of iron carbonate. (author)

  15. The Stratified Legitimacy of Abortions.

    Science.gov (United States)

    Kimport, Katrina; Weitz, Tracy A; Freedman, Lori

    2016-12-01

    Roe v. Wade was heralded as an end to unequal access to abortion care in the United States. However, today, despite being common and safe, abortion is performed only selectively in hospitals and private practices. Drawing on 61 interviews with obstetrician-gynecologists in these settings, we examine how they determine which abortions to perform. We find that they distinguish between more and less legitimate abortions, producing a narrative of stratified legitimacy that privileges abortions for intended pregnancies, when the fetus is unhealthy, and when women perform normative gendered sexuality, including distress about the abortion, guilt about failure to contracept, and desire for motherhood. This stratified legitimacy can perpetuate socially-inflected inequality of access and normative gendered sexuality. Additionally, we argue that the practice by physicians of distinguishing among abortions can legitimate legislative practices that regulate and restrict some kinds of abortion, further constraining abortion access. © American Sociological Association 2016.

  16. RADIAL STABILITY IN STRATIFIED STARS

    International Nuclear Information System (INIS)

    Pereira, Jonas P.; Rueda, Jorge A.

    2015-01-01

    We formulate within a generalized distributional approach the treatment of the stability against radial perturbations for both neutral and charged stratified stars in Newtonian and Einstein's gravity. We obtain from this approach the boundary conditions connecting any two phases within a star and underline its relevance for realistic models of compact stars with phase transitions, owing to the modification of the star's set of eigenmodes with respect to the continuous case

  17. Thermodynamics of high temperature brines

    Energy Technology Data Exchange (ETDEWEB)

    Pitzer, K.S.; Bradley, D.J.; Rogers, P.S.Z.; Peiper, J.C.

    1979-04-01

    Osmotic and activity coefficient data and enthalpy and heat capacity data for NaCl solutions at saturation pressure of water from 0 to 300{sup 0}C and to saturation composition have been simultaneously fit to a 30 parameter equation. The data are reproduced by the equation, in most cases, to within experimental error. Calculated values of the osmotic coefficient, the activity of water, the activity of NaCl, and the heat capacity, enthalpy and entropy of the solution are given in Tables in 25{sup 0}C intervals from 0 to 300{sup 0}C and concentrations from 0.25 to 25 wt% NaCl.

  18. Strontium isotope systematics of mixing groundwater and oil-field brine at Goose Lake in northeastern Montana, USA

    Science.gov (United States)

    Peterman, Zell E.; Thamke, Joanna N.; Futa, Kiyoto; Preston, Todd

    2012-01-01

    Groundwater, surface water, and soil in the Goose Lake oil field in northeastern Montana have been affected by Cl−-rich oil-field brines during long-term petroleum production. Ongoing multidisciplinary geochemical and geophysical studies have identified the degree and local extent of interaction between brine and groundwater. Fourteen samples representing groundwater, surface water, and brine were collected for Sr isotope analyses to evaluate the usefulness of 87Sr/86Sr in detecting small amounts of brine. Differences in Sr concentrations and 87Sr/86Sr are optimal at this site for the experiment. Strontium concentrations range from 0.13 to 36.9 mg/L, and corresponding 87Sr/86Sr values range from 0.71097 to 0.70828. The local brine has 168 mg/L Sr and a 87Sr/86Sr value of 0.70802. Mixing relationships are evident in the data set and illustrate the sensitivity of Sr in detecting small amounts of brine in groundwater. The location of data points on a Sr isotope-concentration plot is readily explained by an evaporation-mixing model. The model is supported by the variation in concentrations of most of the other solutes.

  19. Expected brine movement at potential nuclear waste repository salt sites

    International Nuclear Information System (INIS)

    McCauley, V.S.; Raines, G.E.

    1987-08-01

    The BRINEMIG brine migration code predicts rates and quantities of brine migration to a waste package emplaced in a high-level nuclear waste repository in salt. The BRINEMIG code is an explicit time-marching finite-difference code that solves a mass balance equation and uses the Jenks equation to predict velocities of brine migration. Predictions were made for the seven potentially acceptable salt sites under consideration as locations for the first US high-level nuclear waste repository. Predicted total quantities of accumulated brine were on the order of 1 m 3 brine per waste package or less. Less brine accumulation is expected at domal salt sites because of the lower initial moisture contents relative to bedded salt sites. Less total accumulation of brine is predicted for spent fuel than for commercial high-level waste because of the lower temperatures generated by spent fuel. 11 refs., 36 figs., 29 tabs

  20. Microbially mediated barite dissolution in anoxic brines

    International Nuclear Information System (INIS)

    Ouyang, Bingjie; Akob, Denise M.; Dunlap, Darren; Renock, Devon

    2017-01-01

    Fluids injected into shale formations during hydraulic fracturing of black shale return with extraordinarily high total-dissolved-solids (TDS) and high concentrations of barium (Ba) and radium (Ra). Barite, BaSO_4, has been implicated as a possible source of Ba as well as a problematic mineral scale that forms on internal well surfaces, often in close association with radiobarite, (Ba,Ra)SO_4. The dissolution of barite by abiotic processes is well quantified. However, the identification of microbial communities in flowback and produced water necessitates the need to understand barite dissolution in the presence of bacteria. Therefore, we evaluated the rates and mechanisms of abiotic and microbially-mediated barite dissolution under anoxic and hypersaline conditions in the laboratory. Barite dissolution experiments were conducted with bacterial enrichment cultures established from produced water from Marcellus Shale wells located in northcentral Pennsylvania. These cultures were dominated by anaerobic halophilic bacteria from the genus Halanaerobium. Dissolved Ba was determined by ICP-OES and barite surfaces were investigated by SEM and AFM. Our results reveal that: 1) higher amounts of barium (up to ∼5 × ) are released from barite in the presence of Halanaerobium cultures compared to brine controls after 30 days of reaction, 2) etch pits that develop on the barite (001) surface in the presence of Halanaerobium exhibit a morphology that is distinct from those that form during control experiments without bacteria, 3) etch pits that develop in the presence of Halanaerobium exhibit a morphology that is similar to the morphology of etch pits formed in the presence of strong organic chelators, EDTA and DTPA, and 4) experiments using dialysis membranes to separate barite from bacteria suggest that direct contact between the two is not required in order to promote dissolution. These results suggest that Halanaerobium increase the rate of barite dissolution in anoxic

  1. Performance evaluation of a once-through multi-stage flash distillation system: Impact of brine heater fouling

    International Nuclear Information System (INIS)

    Baig, Hasan; Antar, Mohamed A.; Zubair, Syed M.

    2011-01-01

    Multi-stage flash distillation (MSF) system modeling involves a number of process variables. An estimation of all these process variables requires both analytical solutions and experimental/field analysis. However, the accurate estimate of variables related to the brine heater operation in a MSF system is very important for a reliable operation of the system. For example, steam operating conditions as well as the brine properties including fouling of the brine heater tubes have a significant effect on the heat transfer characteristics of the brine heater, which in turn influence the distillate output from the system. In this study, the effect of various design as well as operating conditions on the performance ratio (PR), brine temperature and salinity as it leaves the last flash stage are investigated in a once-through system. Increasing the number of stages from 24 to 32 has a significant effect on the PR, it ranges between 79% (for ΔT = 1.5) and 327% (for ΔT = 2.3) for a top-brine temperature of 106 o C. This value increase as the top-brine temperature increases. Increasing the stage-to-stage temperature difference increases the water salinity as it leaves the final stage and reduces its temperature that would imply better energy utilization within the plant. Results show that brine side heat exchanger fouling has a significant effect in decreasing the overall heat transfer coefficient, which reduces the production rate as the fouling increases with time. A sensitivity analysis to identify the key parameters, which can have a significant influence on the desalination plant performance, is carried out in an attempt to contribute a better understanding and operation of MSF desalination processes.

  2. FIELD IMPLEMENTATION PLAN FOR A WILLISTON BASIN BRINE EXTRACTION AND STORAGE TEST

    Energy Technology Data Exchange (ETDEWEB)

    Hamling, John; Klapperich, Ryan; Stepan, Daniel; Sorensen, James; Pekot, Lawrence; Peck, Wesley; Jacobson, Lonny; Bosshart, Nicholas; Hurley, John; Wilson, William; Kurz, Marc; Burnison, Shaughn; Salako, Olarinre; Musich, Mark; Botnen, Barry; Kalenze, Nicholas; Ayash, Scott; Ge, Jun; Jiang, Tao; Dalkhaa, Chantsalmaa; Oster, Benjamin; Peterson, Kyle; Feole, Ian; Gorecki, Charles; Steadman, Edward

    2016-03-31

    The Energy & Environmental Research Center (EERC) successfully completed all technical work of Phase I, including development of a field implementation plan (FIP) for a brine extraction and storage test (BEST) in the North Dakota portion of the Williston Basin. This implementation plan was commissioned by the U.S. Department of Energy (DOE) National Energy Technology Laboratory (NETL) as a proxy for managing formation pressure plumes and measuring/monitoring the movement of differential pressure and CO2 plumes in the subsurface for future saline CO2 storage projects. BEST comprises the demonstration and validation of active reservoir management (ARM) strategies and extracted brine treatment technologies. Two prospective commercial brine injection sites were evaluated for BEST to satisfy DOE’s goals. Ultimately, an active saltwater disposal (SWD) site, Johnsons Corner, was selected because it possesses an ideal combination of key factors making it uniquely suited to host BEST. This site is located in western North Dakota and operated by Nuverra Environmental Solutions (Nuverra), a national leader in brine handling, treatment, and injection. An integrated management approach was used to incorporate local and regional geologic characterization activities with geologic and simulation models, inform a monitoring, verification, and accounting (MVA) plan, and to conduct a risk assessment. This approach was used to design a FIP for an ARM schema and an extracted brine treatment technology test bed facility. The FIP leverages an existing pressure plume generated by two commercial SWD wells. These wells, in conjunction with a new brine extraction well, will be used to conduct the ARM schema. Results of these tests will be quantified based on their impact on the performance of the existing SWD wells and the surrounding reservoir system. Extracted brine will be injected into an underlying deep saline formation through a new injection well. The locations of proposed

  3. Approach to recover strategic metals from brines

    Energy Technology Data Exchange (ETDEWEB)

    Raber, E.; Harrar, J.; Gregg, D.

    1981-09-16

    The objective of the proposed research is to evaluate hypersaline brines from geothermal sources and salt domes as possible sources for some strategic metals. This research is suggested because several previous analyses of brine from geothermal wells in the Imperial Valley, California, and from Gulf Coast salt domes, indicate near commercial values for platinum as well as other metals (i.e., gold, silver). Extraction of the platinum should be technically feasible. A research program should include more complete systematic sampling and analysis for resource delineation, followed by bench-scale investigation of several potential extraction processes. This could be followed by engineering feasibility and design studies, for extraction of the metals either as a by-product of other operations or in a stand-alone process.

  4. Formation of brine channels in sea ice.

    Science.gov (United States)

    Morawetz, Klaus; Thoms, Silke; Kutschan, Bernd

    2017-03-01

    Liquid salty micro-channels (brine) between growing ice platelets in sea ice are an important habitat for CO 2 -binding microalgaea with great impact on polar ecosystems. The structure formation of ice platelets is microscopically described and a phase field model is developed. The pattern formation during solidification of the two-dimensional interstitial liquid is considered by two coupled order parameters, the tetrahedricity as structure of ice and the salinity. The coupling and time evolution of these order parameters are described by a consistent set of three model parameters. They determine the velocity of the freezing process and the structure formation, the phase diagram, the super-cooling and super-heating region, and the specific heat. The model is used to calculate the short-time frozen micro-structures. The obtained morphological structure is compared with the vertical brine pore space obtained from X-ray computed tomography.

  5. Free Falling in Stratified Fluids

    Science.gov (United States)

    Lam, Try; Vincent, Lionel; Kanso, Eva

    2017-11-01

    Leaves falling in air and discs falling in water are examples of unsteady descents due to complex interaction between gravitational and aerodynamic forces. Understanding these descent modes is relevant to many branches of engineering and science such as estimating the behavior of re-entry space vehicles to studying biomechanics of seed dispersion. For regularly shaped objects falling in homogenous fluids, the motion is relatively well understood. However, less is known about how density stratification of the fluid medium affects the falling behavior. Here, we experimentally investigate the descent of discs in both pure water and in stable linearly stratified fluids for Froude numbers Fr 1 and Reynolds numbers Re between 1000 -2000. We found that stable stratification (1) enhances the radial dispersion of the disc at landing, (2) increases the descent time, (3) decreases the inclination (or nutation) angle, and (4) decreases the fluttering amplitude while falling. We conclude by commenting on how the corresponding information can be used as a predictive model for objects free falling in stratified fluids.

  6. Stratified Medicine and Reimbursement Issues

    Directory of Open Access Journals (Sweden)

    Hans-Joerg eFugel

    2012-10-01

    Full Text Available Stratified Medicine (SM has the potential to target patient populations who will most benefit from a therapy while reducing unnecessary health interventions associated with side effects. The link between clinical biomarkers/diagnostics and therapies provides new opportunities for value creation to strengthen the value proposition to pricing and reimbursement (P&R authorities. However, the introduction of SM challenges current reimbursement schemes in many EU countries and the US as different P&R policies have been adopted for drugs and diagnostics. Also, there is a lack of a consistent process for value assessment of more complex diagnostics in these markets. New, innovative approaches and more flexible P&R systems are needed to reflect the added value of diagnostic tests and to stimulate investments in new technologies. Yet, the framework for access of diagnostic–based therapies still requires further development while setting the right incentives and appropriate align stakeholders interests when realizing long- term patient benefits. This article addresses the reimbursement challenges of SM approaches in several EU countries and the US outlining some options to overcome existing reimbursement barriers for stratified medicine.

  7. Effects of NaCl on Fermentative Metabolism of Mature Green Tomatoes cv. Ailsa Craig in Brine

    Directory of Open Access Journals (Sweden)

    Sotirios Fragkostefanakis

    2010-01-01

    Full Text Available The effect of osmotic strength on gene expression and activity of the major enzymes of fermentative metabolism of mature green tomato fruit (Solanum lycopersicum cv. Ailsa Craig has been studied by exposing fruit to brine containing 0 (water, 5 and 10 % NaCl. The fruits were surface sterilized prior to treatment to prevent the growth of microbes naturally present on the skin of the fruit. Changes in fruit expression of fermentation genes and the activity of the respective enzymes as well as physicochemical quality characteristics (soluble solid content, titratable acidity, pH and firmness were studied in both fruit and brine for 0.5, 1, 1.5, 2, 3, 7 and 14 days. Discrepancies in responses that resulted from the different salt concentrations were obtained at molecular and quality levels. The complex kinetics of solutes between the fruit and the surrounding solution due to osmotic potential has led to different responses of the tissue to fermentation. Tomato fruit showed cracking soon after storage in water; water-stored fruit had higher titratable acidity, lower soluble solid content, and higher induction of anaerobic metabolism as indicated by the expression or the activity of the fermentation enzymes compared to fruit stored in brine with 5 or 10 % NaCl. No cracking was observed in fruit stored in 5 (isotonic or 10 % NaCl (hypertonic brine, though in the latter, signs of dehydration were observed. The presence of salt in brine reduced the intensity of fermentative metabolism as indicated by the lower gene expression and enzyme activity. However, fruit stored in brine with 5 % NaCl survived longer than with 0 or 10 % NaCl. The presence of 5 % NaCl in brine caused mild changes of both the fermentative metabolism and the physicochemical characteristics and prevented fruit deterioration during storage.

  8. Kinetics of ikaite precipitation and dissolution in seawater-derived brines at sub-zero temperatures to 265 K

    Science.gov (United States)

    Papadimitriou, Stathys; Kennedy, Hilary; Kennedy, Paul; Thomas, David N.

    2014-09-01

    The kinetics of calcium carbonate hexahydrate (ikaite) precipitation and dissolution were investigated in seawater and seawater-derived brines at sub-zero temperatures using the constant addition experimental technique. The steady state rate of these two processes was found to be a function of the deviation of the solution from equilibrium with respect to ikaite and conformed to the same empirical rate law as the anhydrous CaCO3 polymorphs, calcite and aragonite. In addition to the saturation state of the brine with respect to ikaite, the salinity of the brine and the temperature of the reaction evidently exerted some control on the ikaite precipitation kinetics, while the dissolution kinetics of the polymorph were not noticeably influenced by these two parameters. The experimental salinity and temperature conditions were equivalent to those at thermal equilibrium between brine and ice in the sea ice cover of polar seas. Simple modelling of the CO2 system by extrapolation of the oceanic equivalent to sea ice brines showed that the physical concentration of seawater ions and the changes in ikaite solubility as a function of salinity and temperature, both inherent in the sea ice system, would be insufficient to drive the emergent brines to ikaite supersaturation and precipitation in sea ice down to -8 °C. The loss of dissolved inorganic carbon to the gas phase of sea ice and to sympagic autotrophs are two independent mechanisms which, in nature, could prompt the brine CO2 system towards ikaite supersaturation and precipitation. Under these conditions, the steady state precipitation rate of ikaite was found to be fast enough for rapid formation within short time scales (days to weeks) in sea ice. The observed ikaite dissolution kinetics were also found conducive to short turn-over time scales of a few hours to a few days in corrosive solutions, such as surface seawater.

  9. Guiding brine shrimp through mazes by solving reaction diffusion equations

    Science.gov (United States)

    Singal, Krishma; Fenton, Flavio

    Excitable systems driven by reaction diffusion equations have been shown to not only find solutions to mazes but to also to find the shortest path between the beginning and the end of the maze. In this talk we describe how we can use the Fitzhugh-Nagumo model, a generic model for excitable media, to solve a maze by varying the basin of attraction of its two fixed points. We demonstrate how two dimensional mazes are solved numerically using a Java Applet and then accelerated to run in real time by using graphic processors (GPUs). An application of this work is shown by guiding phototactic brine shrimp through a maze solved by the algorithm. Once the path is obtained, an Arduino directs the shrimp through the maze using lights from LEDs placed at the floor of the Maze. This method running in real time could be eventually used for guiding robots and cars through traffic.

  10. Modeling of brine migration in halite

    International Nuclear Information System (INIS)

    Cheung, H.; Fuller, M.E.; Gaffney, E.S.

    1979-01-01

    When canisters containing radwastes are emplaced in a repository the heat produced by the decaying radwaste will cause moderate thermal gradients to develop which will cause the brine present in a halite medium (salt deposits) to accumulate around the canister. Four different models of the migration process have been reviewed to determine their suitability as a working model. One model predicts that inclusions smaller than 0.1 mm dimension probably will not migrate. The other models do not consider size as a factor. Thermal diffusion (Soret effect) is considered insignificant in three models, while in the fourth model it is added to the concentration diffusion term. The following conclusions can be made: Temperature is the most significant parameter in all models and must be known as a function of time, and distance from the canister. All four models predict about the same migration velocity for it is a given set of conditions; for 100 0 C and 1 0 C/cm thermal gradient, it is 3.0, 4.8, 5.6 and 6.4 mm/y. Diffusion of ions through the brine inclusions is the rate controlling mechanism. The difference between the thermal gradients in the liquid and in the solid should always be considered and is a function of droplet shape. The model based upon work by Nernst is easiest to use, but it predicts the lowest migration rate. The maximum volume of pure brine accumulated at the canister surface would be less than 20-40 liters in 50 years, for a canister initial thermal power of 3.5 kW.Bitterns would migrate proportionately less volume. A computer code, BRINE, was developed to make these calculations by means of any of the four models

  11. Design of dry sand soil stratified sampler

    Science.gov (United States)

    Li, Erkang; Chen, Wei; Feng, Xiao; Liao, Hongbo; Liang, Xiaodong

    2018-04-01

    This paper presents a design of a stratified sampler for dry sand soil, which can be used for stratified sampling of loose sand under certain conditions. Our group designed the mechanical structure of a portable, single - person, dry sandy soil stratified sampler. We have set up a mathematical model for the sampler. It lays the foundation for further development of design research.

  12. The geochemistry of groundwater resources in the Jordan Valley: The impact of the Rift Valley brines

    Science.gov (United States)

    Farber, E.; Vengosh, A.; Gavrieli, I.; Marie, Amarisa; Bullen, T.D.; Mayer, B.; Polak, A.; Shavit, U.

    2007-01-01

    The chemical composition of groundwater in the Jordan Valley, along the section between the Sea of Galilee and the Dead Sea, is investigated in order to evaluate the origin of the groundwater resources and, in particular, to elucidate the role of deep brines on the chemical composition of the regional groundwater resources in the Jordan Valley. Samples were collected from shallow groundwater in research boreholes on two sites in the northern and southern parts of the Jordan Valley, adjacent to the Jordan River. Data is also compiled from previous published studies. Geochemical data (e.g., Br/Cl, Na/Cl and SO4/Cl ratios) and B, O, Sr and S isotopic compositions are used to define groundwater groups, to map their distribution in the Jordan valley, and to evaluate their origin. The combined geochemical tools enabled the delineation of three major sources of solutes that differentially affect the quality of groundwater in the Jordan Valley: (1) flow and mixing with hypersaline brines with high Br/Cl (>2 ?? 10-3) and low Na/Cl (shallow saline groundwaters influenced by brine mixing exhibit a north-south variation in their Br/Cl and Na/Cl ratios. This chemical trend was observed also in hypersaline brines in the Jordan valley, which suggests a local mixing process between the water bodies. ?? 2007 Elsevier Ltd. All rights reserved.

  13. Distinguishing seawater from geologic brine in saline coastal groundwater using radium-226; an example from the Sabkha of the UAE

    Science.gov (United States)

    Kraemer, Thomas F.; Wood, Warren W.; Sanford, Ward E.

    2014-01-01

    Sabkhat (Salt flats) are common geographic features of low-lying marine coastal areas that develop under hyper-arid climatic conditions. They are characterized by the presence of highly concentrated saline solutions and evaporitic minerals, and have been cited in the geologic literature as present-day representations of hyper-arid regional paleohydrogeology, paleoclimatology, coastal processes, and sedimentation in the geologic record. It is therefore important that a correct understanding of the origin and development of these features be achieved. Knowledge of the source of solutes is an important first step in understanding these features. Historically, two theories have been advanced as to the main source of solutes in sabkha brines: an early concept entailing seawater as the obvious source, and a more recent and dynamic theory involving ascending geologic brine forced upward into the base of the sabkha by a regional hydraulic gradient in the underlying formations. Ra-226 could uniquely distinguish between these sources under certain circumstances, as it is typically present at elevated activity of hundreds to thousands of Bq/m3 (Becquerels per cubic meter) in subsurface formation brines; at exceedingly low activities in open ocean and coastal water; and not significantly supplied to water from recently formed marine sedimentary framework material. The coastal marine sabkha of the Emirate of Abu Dhabi was used to test this hypothesis. The distribution of Ra-226 in 70 samples of sabkha brine (mean: 700 Bq/m3), 7 samples of underlying deeper formation brine (mean: 3416 Bq/m3), the estimated value of seawater (< 16 Bq/m3) and an estimate of supply from sabkha sedimentary framework grains (<~6 Bq/m3) provide the first direct evidence that ascending geologic brine contributes significantly to the solutes of this sabkha system.

  14. Evolution of hydrologic systems and brine geochemistry in a deforming salt medium: Data from WIPP brine seeps

    International Nuclear Information System (INIS)

    Deal, D.E.; Roggenthen, W.M.

    1991-01-01

    The Brine Sampling and Evaluation Program (BSEP) is a formalized continuation of studies that began in 1982 as part of the Site Validation Program. The program was established in 1985. The mission was to document and investigate the origins, hydraulic characteristics, extent, and composition of brine occurrences in the Permian Salado Formation and the seepage of that brine into the WIPP excavations. This document focuses on the cumulative data obtained from the BSEP. The overall activities of the BSEP described and quantified the brine. It includes documentation and study of brine inflow into boreholes in the facility. The BSEP investigated the occurrence and development of brine weeps, crusts, and brine geochemistry. The presence of salt-tolerant bacteria in the workings was recorded and their possible interactions with experiments and operations, was assessed. The formation properties associated with the occurrence of brine was characterized. The determination of formation properties included the water content of various geologic units, direct examination of these units in boreholes using a video camera system, and measurement of electrical properties relatable to the brine contents. Modeling examined the interaction of salt deformation near the workings and the flow of brine through the deforming rocks. 34 refs

  15. Suppression of stratified explosive interactions

    Energy Technology Data Exchange (ETDEWEB)

    Meeks, M.K.; Shamoun, B.I.; Bonazza, R.; Corradini, M.L. [Wisconsin Univ., Madison, WI (United States). Dept. of Nuclear Engineering and Engineering Physics

    1998-01-01

    Stratified Fuel-Coolant Interaction (FCI) experiments with Refrigerant-134a and water were performed in a large-scale system. Air was uniformly injected into the coolant pool to establish a pre-existing void which could suppress the explosion. Two competing effects due to the variation of the air flow rate seem to influence the intensity of the explosion in this geometrical configuration. At low flow rates, although the injected air increases the void fraction, the concurrent agitation and mixing increases the intensity of the interaction. At higher flow rates, the increase in void fraction tends to attenuate the propagated pressure wave generated by the explosion. Experimental results show a complete suppression of the vapor explosion at high rates of air injection, corresponding to an average void fraction of larger than 30%. (author)

  16. The Brine Sampling and Evaluation Program (PSEP) at WIPP

    International Nuclear Information System (INIS)

    Deal, D.E.; Roggenthen, W.M.

    1989-01-01

    The Permian salt beds of the WIPP facility are virtually dry. The amount of water present in the rocks exposed in the excavations that is free to migrate under pressure gradients was estimated by heating salt samples to 95 degrees C and measuring weight loss. Clear balite contains about 0.22 weight percent water and the more argillaceous units average about 0.75 percent. Measurements made since 1984 as part of the Brine Sampling and Evaluation Program (BSEP) indicate that small amounts of this brine can migrate into the excavations and does accumulate in the underground environment. Brine seepage into drillholes monitored since thy were drilled show that brine seepage decreases with time and that many have dried up entirely. Weeping of brine from the walls of the repository excavations also decreases after two or more years. Chemical analyses of brines shows that they are sodium-chloride saturated and magnesium-rich

  17. Development of a Rapid, Nondestructive Method to Measure Aqueous Carbonate in High Salinity Brines Using Raman Spectroscopy

    Science.gov (United States)

    McGraw, L.; Phillips-Lander, C. M.; Elwood Madden, A. S.; Parnell, S.; Elwood Madden, M.

    2015-12-01

    Traditional methods of quantitative analysis are often ill-suited to determining the bulk chemistry of high salinity brines due to their corrosive and clogging properties. Such methods are also often difficult to apply remotely in planetary environments. However, Raman spectroscopy can be used remotely without physical contact with the fluid and is not affected by many ionic brines. Developing methods to study aqueous carbonates is vital to future study of brines on Mars and other planetary bodies, as they can reveal important information about modern and ancient near-surface aqueous processes. Both sodium carbonate standards and unknown samples from carbonate mineral dissolution experiments in high salinity brines were analyzed using a 532 nm laser coupled to an inVia Renishaw spectrometer to collect carbonate spectra from near-saturated sodium chloride and sodium sulfate brines. A calibration curve was determined by collecting spectra from solutions of known carbonate concentrations mixed with a pH 13 buffer and a near-saturated NaCl or Na2SO4 brine matrix. The spectra were processed and curve fitted to determine the height ratio of the carbonate peak at 1066 cm-1 to the 1640 cm-1 water peak. The calibration curve determined using the standards was then applied to the experimental data after accounting for dilutions. Concentrations determined based on Raman spectra were compared against traditional acid titration measurements. We found that the two techniques vary by less than one order of magnitude. Further work is ongoing to verify the method and apply similar techniques to measure aqueous carbonate concentrations in other high salinity brines.Traditional methods of quantitative analysis are often ill-suited to determining the bulk chemistry of high salinity brines due to their corrosive and clogging properties. Such methods are also often difficult to apply remotely in planetary environments. However, Raman spectroscopy can be used remotely without physical

  18. Amorphous salts formed from rapid dehydration of multicomponent chloride and ferric sulfate brines: Implications for Mars

    Science.gov (United States)

    Sklute, Elizabeth C.; Rogers, A. Deanne; Gregerson, Jason C.; Jensen, Heidi B.; Reeder, Richard J.; Dyar, M. Darby

    2018-01-01

    Salts with high hydration states have the potential to maintain high levels of relative humidity (RH) in the near subsurface of Mars, even at moderate temperatures. These conditions could promote deliquescence of lower hydrates of ferric sulfate, chlorides, and other salts. Previous work on deliquesced ferric sulfates has shown that when these materials undergo rapid dehydration, such as that which would occur upon exposure to present day Martian surface conditions, an amorphous phase forms. However, the fate of deliquesced halides or mixed ferric sulfate-bearing brines are presently unknown. Here we present results of rapid dehydration experiments on Ca–, Na–, Mg– and Fe–chloride brines and multi-component (Fe2 (SO4)3 ± Ca, Na, Mg, Fe, Cl, HCO3) brines at ∼21°C, and characterize the dehydration products using visible/near-infrared (VNIR) reflectance spectroscopy, mid-infrared attenuated total reflectance spectroscopy, and X-ray diffraction (XRD) analysis. We find that rapid dehydration of many multicomponent brines can form amorphous solids or solids with an amorphous component, and that the presence of other elements affects the persistence of the amorphous phase under RH fluctuations. Of the pure chloride brines, only Fe–chloride formed an amorphous solid. XRD patterns of the multicomponent amorphous salts show changes in position, shape, and magnitude of the characteristic diffuse scattering observed in all amorphous materials that could be used to help constrain the composition of the amorphous salt. Amorphous salts deliquesce at lower RH values compared to their crystalline counterparts, opening up the possibility of their role in potential deliquescence-related geologic phenomena such as recurring slope lineae (RSLs) or soil induration. This work suggests that a wide range of aqueous mixed salt solutions can lead to the formation of amorphous salts and are possible for Mars; detailed studies of the formation mechanisms, stability and

  19. Amorphous salts formed from rapid dehydration of multicomponent chloride and ferric sulfate brines: Implications for Mars

    Science.gov (United States)

    Sklute, Elizabeth C.; Rogers, A. Deanne; Gregerson, Jason C.; Jensen, Heidi B.; Reeder, Richard J.; Dyar, M. Darby

    2018-03-01

    Salts with high hydration states have the potential to maintain high levels of relative humidity (RH) in the near subsurface of Mars, even at moderate temperatures. These conditions could promote deliquescence of lower hydrates of ferric sulfate, chlorides, and other salts. Previous work on deliquesced ferric sulfates has shown that when these materials undergo rapid dehydration, such as that which would occur upon exposure to present day Martian surface conditions, an amorphous phase forms. However, the fate of deliquesced halides or mixed ferric sulfate-bearing brines are presently unknown. Here we present results of rapid dehydration experiments on Ca-, Na-, Mg- and Fe-chloride brines and multicomponent (Fe2(SO4)3 ± Ca, Na, Mg, Fe, Cl, HCO3) brines at ∼21 °C, and characterize the dehydration products using visible/near-infrared (VNIR) reflectance spectroscopy, mid-infrared attenuated total reflectance spectroscopy, and X-ray diffraction (XRD) analysis. We find that rapid dehydration of many multicomponent brines can form amorphous solids or solids with an amorphous component, and that the presence of other elements affects the persistence of the amorphous phase under RH fluctuations. Of the pure chloride brines, only Fe-chloride formed an amorphous solid. XRD patterns of the multicomponent amorphous salts show changes in position, shape, and magnitude of the characteristic diffuse scattering observed in all amorphous materials that could be used to help constrain the composition of the amorphous salt. Amorphous salts deliquesce at lower RH values compared to their crystalline counterparts, opening up the possibility of their role in potential deliquescence-related geologic phenomena such as recurring slope lineae (RSLs) or soil induration. This work suggests that a wide range of aqueous mixed salt solutions can lead to the formation of amorphous salts and are possible for Mars; detailed studies of the formation mechanisms, stability and transformation

  20. Amorphous salts formed from rapid dehydration of multicomponent chloride and ferric sulfate brines: Implications for Mars.

    Science.gov (United States)

    Sklute, Elizabeth C; Rogers, A Deanne; Gregerson, Jason C; Jensen, Heidi B; Reeder, Richard J; Dyar, M Darby

    2018-03-01

    Salts with high hydration states have the potential to maintain high levels of relative humidity (RH) in the near subsurface of Mars, even at moderate temperatures. These conditions could promote deliquescence of lower hydrates of ferric sulfate, chlorides, and other salts. Previous work on deliquesced ferric sulfates has shown that when these materials undergo rapid dehydration, such as that which would occur upon exposure to present day Martian surface conditions, an amorphous phase forms. However, the fate of deliquesced halides or mixed ferric sulfate-bearing brines are presently unknown. Here we present results of rapid dehydration experiments on Ca-, Na-, Mg- and Fe-chloride brines and multi-component (Fe 2 (SO 4 ) 3 ± Ca, Na, Mg, Fe, Cl, HCO 3 ) brines at ∼21°C, and characterize the dehydration products using visible/near-infrared (VNIR) reflectance spectroscopy, mid-infrared attenuated total reflectance spectroscopy, and X-ray diffraction (XRD) analysis. We find that rapid dehydration of many multicomponent brines can form amorphous solids or solids with an amorphous component, and that the presence of other elements affects the persistence of the amorphous phase under RH fluctuations. Of the pure chloride brines, only Fe-chloride formed an amorphous solid. XRD patterns of the multicomponent amorphous salts show changes in position, shape, and magnitude of the characteristic diffuse scattering observed in all amorphous materials that could be used to help constrain the composition of the amorphous salt. Amorphous salts deliquesce at lower RH values compared to their crystalline counterparts, opening up the possibility of their role in potential deliquescence-related geologic phenomena such as recurring slope lineae (RSLs) or soil induration. This work suggests that a wide range of aqueous mixed salt solutions can lead to the formation of amorphous salts and are possible for Mars; detailed studies of the formation mechanisms, stability and transformation

  1. Reaction and devitrification of a prototype nuclear-waste-storage glass with hot magnesium-rich brine

    International Nuclear Information System (INIS)

    Komarneni, S.; Freeborn, W.P.; Scheetz, B.E.; White, W.B.; McCarthy, G.J.

    1982-10-01

    PNL 76-68, a prototype nuclear waste storage glass, was reacted under hydrothermal conditions at 100, 200, and 300 C with NBT-6a (Ca-Mg-K-Na-Cl) brine. Reaction products were identified, the state of the residual glass determined, and the concentrations of various elements remaining in the solutions analyzed. Solid products formed by reaction of the glass and brine talc (hydrated magnesium silicate), powellite (CaMoO 4 ), hematite (Fe 2 O 3 ) and rarely an unidentified uranium-containing phase. Glass fragments were leached to depths of 300 to 500 μm, depending on time and temperature. Most elements were extracted, but the silicate framework remained intact. Distinct diffusion fronts due to K/Na exchange and Mg/Zn exchange were identified. A complex compositional layering develops in the outer reaction rind. The concentration of silica in brine solution was lower by an order of magnitude than the concentration of silica in deionized water reacted under similar conditions. The concentration of cesium, strontium, uranium, rare earths, and other alkali and alkaline earth elements in solution increases exponentially with temperature of reaction. Behavior of the transition metals is more complex. In general the extraction of elements from the glass by hydrothermal brine leads to concentrations in solution that are from 10 to 100 times higher than the concentrations obtained by deionized water extraction under similar conditions of temperature and pressure

  2. Selective Recovery of Metals from Geothermal Brines

    Energy Technology Data Exchange (ETDEWEB)

    Ventura, Susanna [SRI International, Menlo Park, CA (United States); Bhamidi, Srinivas [SRI International, Menlo Park, CA (United States); Hornbostel, Marc [SRI International, Menlo Park, CA (United States); Nagar, Anoop [SRI International, Menlo Park, CA (United States); Perea, Elisabeth [SRI International, Menlo Park, CA (United States)

    2016-12-16

    The objective of this project was to determine the feasibility of developing a new generation of highly selective low-cost ion-exchange resins based on metal-ion imprinted polymers for the separation of metals from geothermal fluids. Expansion of geothermal energy production over the entire U.S. will involve exploitation of low-to-medium temperature thermal waters. Creating value streams from the recovery of critical and near-critical metals from these thermal waters will encourage geothermal expansion. Selective extraction of metals from geothermal fluids is needed to design a cost-effective process for the recovery of lithium and manganese-two near-critical metals with well-known application in the growing lithium battery industry. We have prepared new lithium- and manganese-imprinted polymers in the form of beads by crosslinking polymerization of a metal polymerizable chelate, where the metal acts as a template. Upon leaching out the metal template, the crosslinked polymer is expected to leave cavities defined by the ligand functional group with enhanced selectivity for binding the template metal. We have demonstrated that lithium- and manganese-imprinted polymer beads can be used as selective solid sorbents for the extraction of lithium and manganese from brines. The polymers were tested both in batch extractions and packed bed lab-scale columns at temperatures of 45-100°C. Lithium-imprinted polymers were found to have Li+ adsorption capacity as high as 2.8 mg Li+/g polymer at 45°C. Manganese-imprinted polymers were found to have a Mn2+ adsorption capacity of more than 23 mg Mn2+/g polymer at 75°C. The Li+ extraction efficiency of the Li-imprinted polymer was found to be more that 95% when a brine containing 390 ppm Li+, 410 ppm Na+, and 390 ppm K+ was passed through a packed bed of the polymer in a lab-scale column at 45°C. In brines containing 360 ppm Li

  3. Carbonate dissolution rates in high salinity brines: Implications for post-Noachian chemical weathering on Mars

    Science.gov (United States)

    Phillips-Lander, Charity M.; Parnell, S. R.; McGraw, L. E.; Elwood Madden, M. E.

    2018-06-01

    A diverse suite of carbonate minerals including calcite (CaCO3) and magnesite (MgCO3) have been observed on the martian surface and in meteorites. Terrestrial carbonates usually form via aqueous processes and often record information about the environment in which they formed, including chemical and textural biosignatures. In addition, terrestrial carbonates are often found in association with evaporite deposits on Earth. Similar high salinity environments and processes were likely active on Mars and some areas may contain active high salinity brines today. In this study, we directly compare calcite and magnesite dissolution in ultrapure water, dilute sulfate and chloride solutions, as well as near-saturated sulfate and chloride brines with known activity of water (aH2O) to determine how dissolution rates vary with mineralogy and aH2O, as well as aqueous cation and anion chemistry to better understand how high salinity fluids may have altered carbonate deposits on Mars. We measured both calcite and magnesite initial dissolution rates at 298 K and near neutral pH (6-8) in unbuffered solutions containing ultrapure water (18 MΩ cm-1 UPW; aH2O = 1), dilute (0.1 mol kg-1; aH2O = 1) and near-saturated Na2SO4 (2.5 mol kg-1, aH2O = 0.92), dilute (0.1 mol kg-1, aH2O = 1) and near-saturated NaCl (5.7 mol kg-1, aH2O = 0.75). Calcite dissolution rates were also measured in dilute and near-saturated MgSO4 (0.1 mol kg-1, aH2O = 1 and 2.7 mol kg-1, aH2O = 0.92, respectively) and MgCl2 (0.1 mol kg-1, aH2O = 1 and 3 mol kg-1, aH2O = 0.73, respectively), while magnesite dissolution rates were measured in dilute and near-saturated CaCl2 (0.1 mol kg-1, aH2O = 1 and 9 mol kg-1, aH2O = 0.35). Initial calcite dissolution rates were fastest in near-saturated MgCl2 brine, while magnesite dissolution rates were fastest in dilute (0.1 mol kg-1) NaCl and CaCl2 solutions. Calcite dissolution rates in near-saturated Na2SO4 were similar to those observed in the dilute solutions (-8.00 ± 0

  4. Consolidation and permeability of salt in brine

    International Nuclear Information System (INIS)

    Shor, A.J.; Baes, C.F. Jr.; Canonico, C.M.

    1981-07-01

    The consolidation and loss of permeability of salt crystal aggregates, important in assessing the effects of water in salt repositories, has been studied as a function of several variables. The kinetic behavior was similar to that often observed in sintering and suggested the following expression for the time dependence of the void fraction: phi(t) = phi(0) - (A/B)ln(1 + Bt/z(0) 3 ), where A and B are rate constants and z(0) is initial average particle size. With brine present, A and phi(0) varied linearly with stress. The initial void fraction was also dependent to some extent on the particle size distribution. The rate of consolidation was most rapid in brine and least rapid in the presence of only air as the fluid. A brine containing 5 m MgCl 2 showed an intermediate rate, presumably because of the greatly reduced solubility of NaCl. A substantial wall effect was indicated by an observed increase in the void fraction of consolidated columns with distance from the top where the stress was applied and by a dependence of consolidation rate on the column height and radius. The distance through which the stress fell by a factor of phi was estimated to change inversely as the fourth power of the column diameter. With increasing temperature (to 85 0 C), consolidation proceeded somewhat more rapidly and the wall effect was reduced. The permeability of the columns dropped rapidly with consolidation, decreasing with about the sixth power of the void fraction. In general, extrapolation of the results to repository conditions confirms the self-sealing properties of bedded salt as a storage medium for radioactive waste

  5. Laboratory tests to determine the effect of Olkiluoto bounding brine water on buffer performance

    International Nuclear Information System (INIS)

    Martikainen, J.; Schatz, T.

    2011-10-01

    This report presents a set of results from laboratory studies on the effect of bounding brine water exposure on buffer performance. In order to evaluate the effect of bounding brine water exposure on compacted bentonite buffer performance a series of experiments were conducted using swelling pressure and hydraulic conductivity measurements as follows: Direct exposure measurements were performed on MX-80 bentonite samples encompassing a range of dry density values from 1334 to 1585 kg/m 3 . These samples were saturated directly with a 70 g/L solution composed of calcium and sodium chloride at a Ca 2+ /Na + mass ratio of 3:2. Direct exposure measurements were performed on IBECO RWC samples encompassing a range of dry density values from 1314 to 1564 kg/m 3 . These samples were saturated directly with a 68.45 g/L solution composed of calcium and sodium chloride at a Ca 2+ /Na + mass ratio of 3.2:2. A set of MX-80 and IBECO RWC samples encompassing a range of dry density values from 1018 to 1607 kg/m 3 were initially saturated with tap water followed by (indirect) exposure to a 68.45 g/L solution composed of calcium and sodium chloride at a Ca 2+ /Na + mass ratio of 3.2:2. Sample swelling pressures were continuously monitored and hydraulic conductivity measurements were performed at each constant swelling pressure condition. In some cases, exchangeable cation analyses were performed. The specific test results are summarized as follows: All of the measured swelling pressure values upon exposure to bounding brine water were lower than the corresponding values after saturation with tap water. The relative swelling pressure decrease for the IBECO RWC samples was approximately half of the corresponding decrease for the MX-80 samples. On exposure to bounding brine water, hydraulic conductivity values were increased at the lowest densities, for both the MX-80 and IBECO samples, while at higher densities hydraulic conductivity values were essentially equivalent, for both the

  6. PHOTOSPHERIC EMISSION FROM STRATIFIED JETS

    International Nuclear Information System (INIS)

    Ito, Hirotaka; Nagataki, Shigehiro; Ono, Masaomi; Lee, Shiu-Hang; Mao, Jirong; Yamada, Shoichi; Pe'er, Asaf; Mizuta, Akira; Harikae, Seiji

    2013-01-01

    We explore photospheric emissions from stratified two-component jets, wherein a highly relativistic spine outflow is surrounded by a wider and less relativistic sheath outflow. Thermal photons are injected in regions of high optical depth and propagated until the photons escape at the photosphere. Because of the presence of shear in velocity (Lorentz factor) at the boundary of the spine and sheath region, a fraction of the injected photons are accelerated using a Fermi-like acceleration mechanism such that a high-energy power-law tail is formed in the resultant spectrum. We show, in particular, that if a velocity shear with a considerable variance in the bulk Lorentz factor is present, the high-energy part of observed gamma-ray bursts (GRBs) photon spectrum can be explained by this photon acceleration mechanism. We also show that the accelerated photons might also account for the origin of the extra-hard power-law component above the bump of the thermal-like peak seen in some peculiar bursts (e.g., GRB 090510, 090902B, 090926A). We demonstrate that time-integrated spectra can also reproduce the low-energy spectrum of GRBs consistently using a multi-temperature effect when time evolution of the outflow is considered. Last, we show that the empirical E p -L p relation can be explained by differences in the outflow properties of individual sources

  7. Brine Transport Experiments in Granular Salt

    Energy Technology Data Exchange (ETDEWEB)

    Jordan, Amy B. [Los Alamos National Lab. (LANL), Los Alamos, NM (United States); Boukhalfa, Hakim [Los Alamos National Lab. (LANL), Los Alamos, NM (United States); Caporuscio, Florie Andre [Los Alamos National Lab. (LANL), Los Alamos, NM (United States); Stauffer, Philip H. [Los Alamos National Lab. (LANL), Los Alamos, NM (United States)

    2016-06-06

    To gain confidence in the predictive capability of numerical models, experimental validation must be performed to ensure that parameters and processes are correctly simulated. The laboratory investigations presented herein aim to address knowledge gaps for heat-generating nuclear waste (HGNW) disposal in bedded salt that remain after examination of prior field and laboratory test data. Primarily, we are interested in better constraining the thermal, hydrological, and physicochemical behavior of brine, water vapor, and salt when moist salt is heated. The target of this work is to use run-of-mine (RoM) salt; however during FY2015 progress was made using high-purity, granular sodium chloride.

  8. Pressure-driven brine migration in a salt repository

    International Nuclear Information System (INIS)

    Hwang, Y.; Chambre, P.L.; Pigford, T.H.; Lee, W.W.L.

    1989-01-01

    The traditional view is that salt is the ideal rock for isolation of nuclear waste because it is ''dry'' and probably ''impermeable.'' The existence of salt through geologic time is prima facie evidence of such properties. Experiments and experience at potential salt sites for geologic repositories have indicated that while porosity and permeability of salt are low, the salt may be saturated with brine. If this hypothesis is correct, then it is possible to have brine flow due to pressure differences within the salt. If there is pressure-driven brine migration in salt repositories then it is paramount to know the magnitude of such flow because inward brine flow would affect the corrosion rate of nuclear waste containers and outward brine flow might affect radionuclide transport rates. Brine exists in natural salt as inclusions in salt crystals and in grain boundaries. Brine inclusions in crystals move to nearby grain boundaries when subjected to a temperature gradient, because of temperature-dependent solubility of salt. Brine in grain boundaries moves under the influence of a pressure gradient. When salt is mined to create a waste repository, brine from grain boundaries will migrate into the rooms, tunnels and boreholes because these cavities are at atmospheric pressure. After a heat-emitting waste package is emplaced and backfilled, the heat will impose a temperature gradient in the surrounding salt that will cause inclusions in the nearby salt to migrate to grain boundaries within a few years, adding to the brine that was already present in the grain boundaries. The formulation of brine movement with salt as a thermoelastic porous medium, in the context of the continuum theory of mixtures, has been described. In this report we show the mathematical details and discuss the results predicted by this analysis

  9. Thermodynamic modeling of phases equilibrium in aqueous systems to recover potassium chloride from natural brines

    Directory of Open Access Journals (Sweden)

    Ruberlan Gomes da Silva

    2017-01-01

    Full Text Available Chemical fertilizers, such as potassium chloride, ammonium nitrate and other chemical products like sodium hydroxide and soda ash are produced from electrolyte solutions or brines with a high content of soluble salts. Some of these products are manufactured by fractional crystallization, when several salts are separated as solid phases with high purity (>90%. Due to the large global demand for potassium fertilizers, a good knowledge about the compositions of salts and brines is helpful to design an effective process. A thermodynamic model based on Pitzer and Harvie's model was used to predict the composition of crystallized salts after water removal by forced evaporation and cooling from multicomponent solutions or brines. Initially, the salts’ solubilities in binary systems (NaCl–H2O, KCl–H2O and MgCl2–H2O and ternary system (KCl–MgCl2–H2O were calculated at 20 °C and compared with literature data. Next, the model was compared to our experimental data on the quinary system NaCl–KCl–MgCl2–CaCl2–H2O system at 20 °C. The Pitzer and Harvie's model represented well both the binary and ternary systems. Besides, for the quinary system the fit was good for brine densities up to 1350 kg/m3. The models were used to estimate the chemical composition of the solutions and salts produced by fractional crystallization and in association with material balance to respond to issues related to the production rates in a solar pond containing several salts dissolved, for instance, NaCl, KCl, MgCl2 and CaCl2.

  10. Rock-fluid chemical interactions at reservoir conditions: The influence of brine chemistry and extent of reaction

    Science.gov (United States)

    Anabaraonye, B. U.; Crawshaw, J.; Trusler, J. P. M.

    2016-12-01

    Following carbon dioxide injection in deep saline aquifers, CO2 dissolves in the formation brines forming acidic solutions that can subsequently react with host reservoir minerals, altering both porosity and permeability. The direction and rates of these reactions are influenced by several factors including properties that are associated with the brine system. Consequently, understanding and quantifying the impacts of the chemical and physical properties of the reacting fluids on overall reaction kinetics is fundamental to predicting the fate of the injected CO2. In this work, we present a comprehensive experimental study of the kinetics of carbonate-mineral dissolution in different brine systems including sodium chloride, sodium sulphate and sodium bicarbonate of varying ionic strengths. The impacts of the brine chemistry on rock-fluid chemical reactions at different extent of reactions are also investigated. Using a rotating disk technique, we have investigated the chemical interactions between the CO2-saturated brines and carbonate minerals at conditions of pressure (up to 10 MPa) and temperature (up to 373 K) pertinent to carbon storage. The changes in surface textures due to dissolution reaction were studied by means of optical microscopy and vertical scanning interferometry. Experimental results are compared to previously derived models.

  11. Advanced oxidation of iodinated X-ray contrast media in reverse osmosis brines: the influence of quenching.

    Science.gov (United States)

    Azerrad, Sara P; Gur-Reznik, Shirra; Heller-Grossman, Lilly; Dosoretz, Carlos G

    2014-10-01

    Among the main restrictions for the implementation of advanced oxidation processes (AOPs) for removal of micropollutants present in reverse osmosis (RO) brines of secondary effluents account the quenching performed by background organic and inorganic constituents. Natural organic matter (NOM) and soluble microbial products (SMP) are the main effluent organic matter constituents. The inorganic fraction is largely constituted by chlorides and bicarbonate alkalinity with sodium and calcium as main counterions. The quenching influence of these components, separately and their mixture, in the transformation of model compounds by UVA/TiO2 was studied applying synthetic brines solutions mimicking 2-fold concentrated RO secondary effluents brines. The results were validated using fresh RO brines. Diatrizoate (DTZ) and iopromide (IOPr) were used as model compound. They have been found to exhibit relative high resistance to oxidation process and therefore represent good markers for AOPs techniques. Under the conditions applied, oxidization of DTZ in the background of RO brines was strongly affected by quenching effects. The major contribution to quenching resulted from organic matter (≈70%) followed by bicarbonate alkalinity (≈30%). NOM displayed higher quenching than SMP in spite of its relative lower concentration. Multivalent cations, i.e., Ca(+2), were found to decrease effectiveness of the technique due to agglomeration of the catalyst. However this influence was lowered in presence of NOM. Different patterns of transformation were found for each model compound in which a delayed deiodination was observed for iopromide whereas diatrizoate oxidation paralleled deiodination. Copyright © 2014 Elsevier Ltd. All rights reserved.

  12. Minimizing the Environmental Impact of Sea Brine Disposal by Coupling Desalination Plants with Solar Saltworks: A Case Study for Greece

    Directory of Open Access Journals (Sweden)

    Stylianos Gialis

    2010-02-01

    Full Text Available The explosive increase in world population, along with the fast socio-economic development, have led to an increased water demand, making water shortage one of the greatest problems of modern society. Countries such as Greece, Saudi Arabia and Tunisia face serious water shortage issues and have resorted to solutions such as transporting water by ships from the mainland to islands, a practice that is expensive, energy-intensive and unsustainable. Desalination of sea-water is suitable for supplying arid regions with potable water, but extensive brine discharge may affect marine biota. To avoid this impact, we explore the option of directing the desalination effluent to a solar saltworks for brine concentration and salt production, in order to achieve a zero discharge desalination plant. In this context, we conducted a survey in order to evaluate the potential of transferring desalination brine to solar saltworks, so that its disposal to the sea is avoided. Our analysis showed that brine transfer by trucks is prohibitively expensive. In order to make the zero discharge desalination plant economically feasible, efforts should be directed into developing a more efficient technology that will result in the production of only a fraction of the brine that is produced from our systems today.

  13. Domal salt brine migration experiments at Avery Island, Louisiana

    International Nuclear Information System (INIS)

    Krause, W.B.; Gnirk, P.F.

    1981-01-01

    Three in-situ brine migration experiments were performed in domal salt in the Avery Island mine located in southwestern Louisiana. The primary measurements included temperature, moisture collection, and pre- and post-test permeability at the experimental sites. Experimental data are discussed and compared with calculations based on the single-crystal brine migration theory. Comparisons indicate reasonable agreement between experiment and theory

  14. Chemistry and geothermometry of brine produced from the Salton Sea Scientific drill hole, Imperial Valley, California

    Science.gov (United States)

    Thompson, J.M.; Fournier, R.O.

    1988-01-01

    The December 29-30, 1985, flow test of the State 2-14 well, also known as the Salton Sea Scientific drill hole, produced fluid from a depth of 1865-1877 m at a reservoir temperature of 305????5??C. Samples were collected at five different flashing pressures. The brines are Na-Ca-K-Cl-type waters with very high metal and low SO4 and HCO3 contents. Compositions of the flashed brines were normalized relative to the 25??C densities of the solutions, and an ionic charge balance was achieved by adjusting the Na concentration. Calculated Na/K geothermometer temperatures, using equations suggested by different investigators, range from 326?? to 364??C. The Mg/K2 method gives a temperature of about 350??C, Mg/Li2 about 282??, and Na/Li 395??-418??C. -from Authors

  15. Turbulent fluxes in stably stratified boundary layers

    International Nuclear Information System (INIS)

    L'vov, Victor S; Procaccia, Itamar; Rudenko, Oleksii

    2008-01-01

    We present here an extended version of an invited talk we gave at the international conference 'Turbulent Mixing and Beyond'. The dynamical and statistical description of stably stratified turbulent boundary layers with the important example of the stable atmospheric boundary layer in mind is addressed. Traditional approaches to this problem, based on the profiles of mean quantities, velocity second-order correlations and dimensional estimates of the turbulent thermal flux, run into a well-known difficulty, predicting the suppression of turbulence at a small critical value of the Richardson number, in contradiction to observations. Phenomenological attempts to overcome this problem suffer from various theoretical inconsistencies. Here, we present an approach taking into full account all the second-order statistics, which allows us to respect the conservation of total mechanical energy. The analysis culminates in an analytic solution of the profiles of all mean quantities and all second-order correlations, removing the unphysical predictions of previous theories. We propose that the approach taken here is sufficient to describe the lower parts of the atmospheric boundary layer, as long as the Richardson number does not exceed an order of unity. For much higher Richardson numbers, the physics may change qualitatively, requiring careful consideration of the potential Kelvin-Helmoholtz waves and their interaction with the vortical turbulence.

  16. Organic geochemistry and brine composition in Great Salt, Mono, and Walker Lakes

    Science.gov (United States)

    Domagalski, Joseph L.; Orem, W.H.; Eugster, H.P.

    1989-01-01

    Samples of Recent sediments, representing up to 1000 years of accumulation, were collected from three closed basin lakes (Mono Lake, CA, Walker Lake, NV, and Great Salt Lake, UT) to assess the effects of brine composition on the accumulation of total organic carbon, the concentration of dissolved organic carbon, humic acid structure and diagenesis, and trace metal complexation. The Great Salt Lake water column is a stratified Na-Mg-Cl-SO4 brine with low alkalinity. Algal debris is entrained in the high density (1.132-1.190 g/cc) bottom brines, and in this region maximum organic matter decomposition occurs by anaerobic processes, with sulfate ion as the terminal electron acceptor. Organic matter, below 5 cm of the sediment-water interface, degrades at a very slow rate in spite of very high pore-fluid sulfate levels. The organic carbon concentration stabilizes at 1.1 wt%. Mono Lake is an alkaline (Na-CO3-Cl-SO4) system. The water column is stratified, but the bottom brines are of lower density relative to the Great Salt Lake, and sedimentation of algal debris is rapid. Depletion of pore-fluid sulfate, near l m of core, results in a much higher accumulation of organic carbon, approximately 6 wt%. Walker Lake is also an alkaline system. The water column is not stratified, and decomposition of organic matter occurs by aerobic processes at the sediment-water interface and by anaerobic processes below. Total organic carbon and dissolved organic carbon concentrations in Walker Lake sediments vary with location and depth due to changes in input and pore-fluid sulfate concentrations. Nuclear magnetic resonance studies (13C) of humic substances and dissolved organic carbon provide information on the source of the Recent sedimentary organic carbon (aquatic vs. terrestrial), its relative state of decomposition, and its chemical structure. The spectra suggest an algal origin with little terrestrial signature at all three lakes. This is indicated by the ratio of aliphatic to

  17. Water swelling, brine soluble imidazole based zwitterionic polymers-synthesis and study of reversible UCST behaviour and gel-sol transitions

    NARCIS (Netherlands)

    Vasantha, Vivek Arjunan; Jana, Satyasankar; Parthiban, Anbanandam; Vancso, Julius G.

    2014-01-01

    New vinylbenzene substituted imidazole based zwitterionic polymers with unique characteristics like swelling in water and solubility in concentrated brine solution in which they exhibited a reversible upper critical solution temperature (UCST) and gel-sol transitions are reported herein. © 2014 The

  18. Experimental evaporation of hyperacid brines: Effects on chemical composition and chlorine isotope fractionation

    Science.gov (United States)

    Rodríguez, Alejandro; van Bergen, Manfred J.; Eggenkamp, H. G. M.

    2018-02-01

    Hyperacid brines from active volcanic lakes are some of the chemically most complex aqueous solutions on Earth. Their compositions provide valuable insights into processes of elemental transfer from a magma body to the surface and interactions with solid rocks and the atmosphere. This paper describes changes in chemical and δ37Cl signatures observed in a 1750 h isothermal evaporation experiment on hyperacid (pH 0.1) sulphate-chloride brine water from the active lake of Kawah Ijen volcano (Indonesia). Although gypsum was the only evaporite mineral identified in the evolving brine, decreasing Si concentrations may ultimately result in amorphous silica precipitation. Geochemical simulations predict the additional formation of elemental sulphur at lower water activities (aH2O ≤ 0.65) that were not reached in the experiment. Absence of other sulphates and halides despite the high load of dissolved elements (initial TDS ca. 100 g/kg) can be attributed to increased solubility of metals, promoted by extensive formation of complexes between the variety of cations and the major anions (HSO4-, Cl-, F-) present. Chlorine deviations from a conservative behaviour point to losses of gaseous hydrogen chloride (HCl(g)) and consequently an increase in Br/Cl ratios. Chlorine isotope fractionation that accompanied the escape of HCl(g) showed a marked change in sign and magnitude in the course of progressive evaporation of the brine. The calculated factor of fractionation between HCl(g) and dissolved Cl for the initial interval (before 500 h) is positive (1000lnαHCl(g)-Cldiss. = + 1.55 ± 0.49‰to + 3.37 ± 1.11‰), indicating that, at first, the escaping HCl(g) was isotopically heavier than the dissolved Cl remaining in the brine. Conversely, fractionation shifted to the opposite direction in the subsequent interval (1000lnαHCl(g)-Cldiss. = 5.67 ± 0.17‰to - 5.64 ± 0.08‰), in agreement with values reported in literature. It is proposed that Cl isotopic fractionation in

  19. Mantle helium in the Red Sea brines

    International Nuclear Information System (INIS)

    Lupton, J.E.; Weiss, R.F.; Craig, H.

    1977-01-01

    It is stated that He isotope studies of terrestrial samples have shown the existence of two He components that are clearly distinct from atmospheric He. These are termed 'crustal' He and 'mantle' He; the latter was discovered as 'excess 3 He' in deep ocean water and attributed to a flux of primordial He from the mantle. Studies of the 3 He/ 4 He ratio in deep Pacific water and in He trapped in submarine basalt glasses showed that this 'mantle' component is characterised by ratios about ten times the atmospheric ratio and 100 times the ratio in 'crustal' He. Basalt glasses from other deep sea waters also showed similar ratios, and it is indicated that 'mantle' He in areas in which new lithosphere is being formed has a unique and uniform isotopic signature. Measurements of He and Ne are here reported that reveal additional information on the origin of Red Sea brines and their relationship to the Red Sea rifts. (U.K.)

  20. Radionuclide transport in sandstones with WIPP brine

    International Nuclear Information System (INIS)

    Weed, H.C.; Bazan, F.; Fontanilla, J.; Garrison, J.; Rego, J.; Winslow, A.M.

    1981-02-01

    Retardation factors (R) have been measured for the transport of 3 H, /sup 95m/Tc, and 85 Sr in WIPP brine using St. Peter, Berea, Kayenta, and San Felipe sandstone cores. If tritium is assumed to have R=1, /sup 95m/Tc has R=1.0 to 1.3 and therefore is essentially not retarded. Strontium-85 has R = 1.0 to 1.3 on St. Peter, Berea, and Kayenta, but R=3 on San Felipe. This is attributed to sorption on the matrix material of San Felipe, which has 45 volume % matrix compared with 1 to 10 volume % for the others. Retardation factors (R/sub s/) for 85 Sr calculated from static sorption measurements are unity for all the sandstones. Therefore, the static and transport results for 85 Sr disagree in the case of San Felipe, but agree for St. Peter, Berea, and Kayenta

  1. Self-oscillations in large storages of highly mineralized brines

    Science.gov (United States)

    Lyubimova, Tatyana; Lepikhin, Anatoly; Tsiberkin, Kirill; Parshakova, Yanina

    2014-05-01

    One of the stages of the production process at large enrichment plants is settling of aqueous solutions in large technological storages. The present work is devoted to the modeling of hydrodynamic regimes of large storage of highly mineralized brines. The density of brines in these objects depends not only on the content of dissolved macrocomponents, but also on the concentration of fine particulate matter. This leads to the need to consider the dynamics of the suspended sediment under significant density stratification, which greatly complicates the problem. Because of that it is important to develop hydrodynamical models of these objects. A peculiarity of these systems is the possibility of self-oscillatory regimes the mechanism of which is as follows. In warm sunny days, with high solar insolation, the heating of the sediments and bottom water takes place. The bottom water warming and the decrease of its density give rise to flow. The slurry particles composing the sediments are involved in the flow. The heated particles entrained by the flow transfer the heat to the surrounding liquid and increase the absorption of the solar radiation in the volume, which leads to equalization of temperature and convective flow damping. After the particle settling on the bottom the process is repeated. We study the stability of equilibrium of the horizontal liquid layer containing heavy insoluble particles in the presence of evaporation from the free surface and solar radiation absorption by insoluble particles. The time-dependent solution of heat transfer problem is obtained and used for estimate of time of instability onset. It is found that for the layer of saturated brines of potassium chloride of the thickness about 10 m the time for instability onset is about one hour. By using analytical estimates based on the empirical model of turbulence by Prandtl we confirmed the time for the onset of instability and obtained the estimates for the period of self

  2. Brine migration in hot-pressed polycrystalline sodium chloride

    International Nuclear Information System (INIS)

    Biggers, J.V.; Dayton, G.O.

    1982-12-01

    This report describes experiments designed to provide data on brine migration in polycrystalline salt. Polycrystalling samples of various grain sizes, density, and purity were prepared from several commercial-grade salts by hot-pressing. Three distinct experimental set-ups were used to place salt billets in an induced thermal gradient in contact with brine source. The test designs varied primarily in the way in which the thermal gradient was applied and monitored and the way in which brine migration was determined. All migration was in enclosed vessels which precluded visual observation of brine movement through the microstructure. Migration velocities were estimated either by the timed appearance of brine at the hot face of the sample, or by determination of the penetration distance of migration artifacts in the microstructure after tests of fixed duration. For various reasons both of these methods were subject to a large degree of error. Our results suggest, however, that the migration velocity in dense polycrystalline salt may be at least an order of magnitude greater than that suggested by single-crystal experiments. Microstructural analysis shows that brine prefers to migrate along paths of high crystalline activity such as grain and subgrain boundaries and is dispersed rather quickly in the microstructure. A series of tests were performed using various types of tracers in brine in order to flag migration paths and locate brine in the microstructure more decisively. These attempts failed and it appears that only the aqueous portion of the brine moves through the microstructure with the dissolved ions being lost and replaced rather quickly. This suggests the use of deuterium as a tracer in future work

  3. Enrichment of extremophilic exoelectrogens in microbial electrolysis cells using Red Sea brine pools as inocula.

    Science.gov (United States)

    Shehab, Noura A; Ortiz-Medina, Juan F; Katuri, Krishna P; Hari, Ananda Rao; Amy, Gary; Logan, Bruce E; Saikaly, Pascal E

    2017-09-01

    Applying microbial electrochemical technologies for the treatment of highly saline or thermophilic solutions is challenging due to the lack of proper inocula to enrich for efficient exoelectrogens. Brine pools from three different locations (Valdivia, Atlantis II and Kebrit) in the Red Sea were investigated as potential inocula sources for enriching exoelectrogens in microbial electrolysis cells (MECs) under thermophilic (70°C) and hypersaline (25% salinity) conditions. Of these, only the Valdivia brine pool produced high and consistent current 6.8±2.1A/m 2 -anode in MECs operated at a set anode potential of +0.2V vs. Ag/AgCl (+0.405V vs. standard hydrogen electrode). These results show that exoelectrogens are present in these extreme environments and can be used to startup MEC under thermophilic and hypersaline conditions. Bacteroides was enriched on the anode of the Valdivia MEC, but it was not detected in the open circuit voltage reactor seeded with the Valdivia brine pool. Copyright © 2017 Elsevier Ltd. All rights reserved.

  4. Experimental Study of Cement - Sandstone/Shale - Brine - CO2 Interactions.

    Science.gov (United States)

    Carroll, Susan A; McNab, Walt W; Torres, Sharon C

    2011-11-11

    Reactive-transport simulation is a tool that is being used to estimate long-term trapping of CO2, and wellbore and cap rock integrity for geologic CO2 storage. We reacted end member components of a heterolithic sandstone and shale unit that forms the upper section of the In Salah Gas Project carbon storage reservoir in Krechba, Algeria with supercritical CO2, brine, and with/without cement at reservoir conditions to develop experimentally constrained geochemical models for use in reactive transport simulations. We observe marked changes in solution composition when CO2 reacted with cement, sandstone, and shale components at reservoir conditions. The geochemical model for the reaction of sandstone and shale with CO2 and brine is a simple one in which albite, chlorite, illite and carbonate minerals partially dissolve and boehmite, smectite, and amorphous silica precipitate. The geochemical model for the wellbore environment is also fairly simple, in which alkaline cements and rock react with CO2-rich brines to form an Fe containing calcite, amorphous silica, smectite and boehmite or amorphous Al(OH)3. Our research shows that relatively simple geochemical models can describe the dominant reactions that are likely to occur when CO2 is stored in deep saline aquifers sealed with overlying shale cap rocks, as well as the dominant reactions for cement carbonation at the wellbore interface.

  5. Kinetics of carbonate mineral dissolution in CO2-acidified brines at storage reservoir conditions.

    Science.gov (United States)

    Peng, Cheng; Anabaraonye, Benaiah U; Crawshaw, John P; Maitland, Geoffrey C; Trusler, J P Martin

    2016-10-20

    We report experimental measurements of the dissolution rate of several carbonate minerals in CO 2 -saturated water or brine at temperatures between 323 K and 373 K and at pressures up to 15 MPa. The dissolution kinetics of pure calcite were studied in CO 2 -saturated NaCl brines with molalities of up to 5 mol kg -1 . The results of these experiments were found to depend only weakly on the brine molality and to conform reasonably well with a kinetic model involving two parallel first-order reactions: one involving reactions with protons and the other involving reaction with carbonic acid. The dissolution rates of dolomite and magnesite were studied in both aqueous HCl solution and in CO 2 -saturated water. For these minerals, the dissolution rates could be explained by a simpler kinetic model involving only direct reaction between protons and the mineral surface. Finally, the rates of dissolution of two carbonate-reservoir analogue minerals (Ketton limestone and North-Sea chalk) in CO 2 -saturated water were found to follow the same kinetics as found for pure calcite. Vertical scanning interferometry was used to study the surface morphology of unreacted and reacted samples. The results of the present study may find application in reactive-flow simulations of CO 2 -injection into carbonate-mineral saline aquifers.

  6. Enrichment of extremophilic exoelectrogens in microbial electrolysis cells using Red Sea brine pools as inocula

    KAUST Repository

    Chehab, Noura A.

    2017-05-03

    Applying microbial electrochemical technologies for the treatment of highly saline or thermophilic solutions is challenging due to the lack of proper inocula to enrich for efficient exoelectrogens. Brine pools from three different locations (Valdivia, Atlantis II and Kebrit) in the Red Sea were investigated as potential inocula sources for enriching exoelectrogens in microbial electrolysis cells (MECs) under thermophilic (70°C) and hypersaline (25% salinity) conditions. Of these, only the Valdivia brine pool produced high and consistent current 6.8 ± 2.1 A/m2-anode in MECs operated at a set anode potential of +0.2 V vs. Ag/AgCl (+0.405 V vs. standard hydrogen electrode). These results show that exoelectrogens are present in these extreme environments and can be used to startup MEC under thermophilic and hypersaline conditions. Bacteroides was enriched on the anode of the Valdivia MEC, but it was not detected in the open circuit voltage reactor seeded with the Valdivia brine pool.

  7. Actinide Biocolloid Formation in Brine by Halophilic Bacteria

    Energy Technology Data Exchange (ETDEWEB)

    Gillow, J.B.; Francis, A.J.; Dodge, C.J.; Harris, R.; Beveridge, T.J.; Brady, P.V.; Papenguth, H.W.

    1999-07-28

    We examined the ability of a halophilic bacterium (WFP 1A) isolated from the Waste Isolation Pilot Plant (WIPP) site to accumulate uranium in order to determine the potential for biocolloid facilitated actinide transport. The bacterial cell Surface functional groups involved in the complexation of the actinide were determined by titration. Uranium, added as uranyl nitrate, was removed from solution at pH 5 by cells but at pH 7 and 9 very little uranium was removed due to its limited volubility. Although present as soluble species, uranyl citrate at pH 5, 7, and 9, and uranyl carbonate at pH 9 were not removed by the bacterium because they were not bioavailable due to their neutral or negative charge. Addition of uranyl EDTA to brine at pH 5, 7, and 9 resulted in the immediate precipitation of U. Transmission electron microscopy (TEM) and energy dispersive X-ray spectroscopy (EDS) analysis revealed that uranium was not only associated with the cell surface but also accumulated intracellulary as uranium-enriched granules. Extended X-ray absorption fine structure (EXAFS) analysis, of the bacterial cells indicated the bulk sample contained more than one uranium phase. Nevertheless these results show the potential for the formation of actinide bearing bacterial biocolloids that are strictly regulated by the speciation and bioavailability of the actinide.

  8. Actinide biocolloid formation in brine by halophilic bacteria

    International Nuclear Information System (INIS)

    Gillow, J.B.; Francis, A.J.; Dodge, C.J.; Harris, R.; Beveridge, T.J.; Brady, P.V.; Papenguth, H.W.

    1999-01-01

    The authors examined the ability of a halophilic bacterium (WIPP 1A) isolated from the Waste Isolation Pilot Plant (WIPP) site to accumulate uranium in order to determine the potential for biocolloid facilitated actinide transport. The bacterial cell surface functional groups involved in the complexation of the actinide were determined by titration. Uranium, added as uranyl nitrate, was removed from solution at pH 5 by cells but at pH 7 and 9 very little uranium was removed due to its limited solubility. Although present as soluble species, uranyl citrate at pH 5, 7, and 9, and uranyl carbonate at pH 9 were not removed by the bacterium because they were not bioavailable due to their neutral or negative charge. Addition of uranyl EDTA to brine at pH 5, 7, and 9 resulted in the immediate precipitation of U. Transmission electron microscopy (TEM) and energy dispersive X-ray spectroscopy (EDS) analysis revealed that uranium was not only associated with the cell surface but also accumulated intracellularly as uranium-enriched granules. Extended X-ray absorption fine structure (EXAFS) analysis of the bacterial cells indicated the bulk sample contained more than one uranium phase. Nevertheless these results show the potential for the formation of actinide bearing bacterial biocolloids that are strictly regulated by the speciation and bioavailability of the actinide

  9. Actinide Biocolloid Formation in Brine by Halophilic Bacteria

    International Nuclear Information System (INIS)

    Gillow, J.B.; Francis, A.J.; Dodge, C.J.; Harris, R.; Beveridge, T.J.; Brady, P.V.; Papenguth, H.W.

    1999-01-01

    We examined the ability of a halophilic bacterium (WFP 1A) isolated from the Waste Isolation Pilot Plant (WIPP) site to accumulate uranium in order to determine the potential for biocolloid facilitated actinide transport. The bacterial cell Surface functional groups involved in the complexation of the actinide were determined by titration. Uranium, added as uranyl nitrate, was removed from solution at pH 5 by cells but at pH 7 and 9 very little uranium was removed due to its limited volubility. Although present as soluble species, uranyl citrate at pH 5, 7, and 9, and uranyl carbonate at pH 9 were not removed by the bacterium because they were not bioavailable due to their neutral or negative charge. Addition of uranyl EDTA to brine at pH 5, 7, and 9 resulted in the immediate precipitation of U. Transmission electron microscopy (TEM) and energy dispersive X-ray spectroscopy (EDS) analysis revealed that uranium was not only associated with the cell surface but also accumulated intracellulary as uranium-enriched granules. Extended X-ray absorption fine structure (EXAFS) analysis, of the bacterial cells indicated the bulk sample contained more than one uranium phase. Nevertheless these results show the potential for the formation of actinide bearing bacterial biocolloids that are strictly regulated by the speciation and bioavailability of the actinide

  10. Actinide biocolloid formation in brine by halophilic bacteria

    International Nuclear Information System (INIS)

    Gillow, J.B.; Francis, A.J.; Dodge, C.J.; Harris, R.; Beveridge, T.J.; Brady, P.B.; Papenguth, H.W.

    1998-01-01

    The authors examined the ability of a halophilic bacterium (WIPP 1A) isolated from the Waste Isolation Pilot Plant (WIPP) site to accumulate uranium in order to determine the potential for biocolloid facilitated actinide transport. The bacterial cell surface functional groups involved in the complexation of the actinide were determined by titration. Uranium, added as uranyl nitrate, was removed from solution at pH 5 by cells but at pH 7 and 9 very little uranium was removed due to its limited solubility. Although present as soluble species, uranyl citrate at pH 5, 7, and 9, and uranyl carbonate at pH 9 were not removed by the bacterium because they were not bioavailable due to their neutral or negative charge. Addition of uranyl EDTA to brine at pH 5, 7, and 9 resulted in the immediate precipitation of U. Transmission electron microscopy (TEM) and energy dispersive X-ray spectroscopy (EDS) analysis revealed that uranium was not only associated with the cell surface but also accumulated intracellularly as uranium-enriched granules. Extended X-ray absorption fine structure (EXAFS) analysis of the bacterial cells indicated the bulk sample contained more than one uranium phase. Nevertheless these results show the potential for the formation of actinide bearing bacterial biocolloids that are strictly regulated by the speciation and bioavailability of the actinide

  11. Accessible reactive surface area and abiotic redox reactivity of iron oxyhydroxides in acidic brines

    Science.gov (United States)

    Strehlau, Jennifer H.; Toner, Brandy M.; Arnold, William A.; Penn, R. Lee

    2017-01-01

    The reactivity of iron oxyhydroxide nanoparticles in low pH and high ionic strength solutions was quantified to assess abiotic contributions to oxidation-reduction chemistry in acidic brine environments, such as mine groundwater seepage, lakes in Western Australia, and acid mine drainage settings, which are of global interest for their environmental impacts and unique geomicrobiology. Factors expected to influence accessible and reactive surface area, including Fe(II) adsorption and aggregate size, were measured as a function of pH and CaCl2 concentration and related to the kinetics of redox reactions in aqueous suspensions of synthetic goethite (α-FeOOH), akaganeite (β-FeOOH), and ferrihydrite (Fe10O14(OH)2) nanoparticles. Aqueous conditions and iron oxyhydroxides were chosen based on characterization of natural iron-rich mine microbial mats located in Soudan Underground Mine State Park, Minnesota, USA. Quinone species were used as redox sensors because they are well-defined probes and are present in natural organic matter. Fe(II) adsorption to the iron oxyhydroxide mineral surfaces from aqueous solution was measurable only at pH values above 4 and either decreased or was not affected by CaCl2 concentration. Concentrations at or above 0.020 M CaCl2 in acetate buffer (pH 4.5) induced particle aggregation. Assessment of Fe(II) adsorption and particle aggregation in acidic brine suggested that accessible reactive surface area may be limited in acidic brines. This was supported by observations of decreasing benzoquinone reduction rate by adsorbed Fe(II) at high CaCl2 concentration. In contrast, the hydroquinone oxidation rate increased at high CaCl2 concentrations, which may be due to suppressed adsorption of Fe(II) generated by the reaction. Results suggest that iron geochemical cycling in acidic brine environments will be substantially different than for iron oxyhydroxides in low-saline waters with circumneutral pH. These findings have implications for acidic

  12. Spinning phenomena and energetics of spherically pulsating patterns in stratified fluids

    International Nuclear Information System (INIS)

    Ibragimov, Ranis N; Dameron, Michael

    2011-01-01

    The nonlinear solutions of the two-dimensional Boussinesq equations describing internal waves in rotating stratified fluids were obtained as group invariant solutions. The latter nonlinear solutions correspond to the rotation transformation preserving the form of the original nonlinear equations of motion. It is shown that the obtained class of exact solutions can be associated with the spherically pulsating patterns observed in uniformly stratified fluids. It is also shown that the obtained rotationally symmetric solutions are bounded functions that can be visualized as spinning patterns in stratified fluids. It is also shown that the rotational transformation provides the energy conservation law together with other conservation laws for which the spinning phenomena is observed. The effects of nonlinearity and the Earth's rotation on such a phenomenon are also discussed.

  13. Modelling CO2-Brine Interfacial Tension using Density Gradient Theory

    KAUST Repository

    Ruslan, Mohd Fuad Anwari Che

    2018-01-01

    In this study, a new modelling strategy to compute CO2-brine IFT based on DGT was proposed. In the proposed model, ion distribution across interface was accounted for by separating the interface to two sections

  14. Effect of different brine concentrations and ripening period on some ...

    African Journals Online (AJOL)

    Administrator

    2011-09-26

    25240, Erzurum, Turkey. Accepted 25 ... ripened soft cheese that is maturated in brine to develop the desired ... functions, salt exerts a number of important effects on cheese. ..... In: Fox PF (ed) Cheese: chemistry, physics and.

  15. determination of toxicity levels of some savannah plants using brine

    African Journals Online (AJOL)

    DR. AMINU

    DETERMINATION OF TOXICITY LEVELS OF SOME SAVANNAH PLANTS. USING BRINE ... Adoum, O. A.. Department of Pure and Industrial Chemistry, Bayero University, P.M.B. 3011, Kano – Nigeria. ... 1000, 100, and 10 µg/ml, respectively.

  16. A network model for characterizing brine channels in sea ice

    Science.gov (United States)

    Lieblappen, Ross M.; Kumar, Deip D.; Pauls, Scott D.; Obbard, Rachel W.

    2018-03-01

    The brine pore space in sea ice can form complex connected structures whose geometry is critical in the governance of important physical transport processes between the ocean, sea ice, and surface. Recent advances in three-dimensional imaging using X-ray micro-computed tomography have enabled the visualization and quantification of the brine network morphology and variability. Using imaging of first-year sea ice samples at in situ temperatures, we create a new mathematical network model to characterize the topology and connectivity of the brine channels. This model provides a statistical framework where we can characterize the pore networks via two parameters, depth and temperature, for use in dynamical sea ice models. Our approach advances the quantification of brine connectivity in sea ice, which can help investigations of bulk physical properties, such as fluid permeability, that are key in both global and regional sea ice models.

  17. Coiled Brine Recovery Assembly (CoBRA) Project

    Data.gov (United States)

    National Aeronautics and Space Administration — The Coiled Brine Recovery Assembly (CoBRA) project will result in a proof-of-concept demonstration for a lightweight, compact, affordable, regenerable and disposable...

  18. Brine treatment, smoking and storage techniques: their effects on the ...

    African Journals Online (AJOL)

    Journal of Food Technology in Africa ... Brine treatment, smoking and storage techniques: their effects on the microbial quality of smoked mackerel. ... off odour development, softening of the fish and positively affected personal preference.

  19. Physiological characteristics of bacteria isolated from water brines within permafrost

    Science.gov (United States)

    Shcherbakova, V.; Rivkina, E.; Laurinavichuis, K.; Pecheritsina, S.; Gilichinsky, D.

    2004-01-01

    In the Arctic there are lenses of overcooled water brines (cryopegs) sandwiched within permafrost marine sediments 100 120 thousand years old. We have investigated the physiological properties of the pure cultures of anaerobic Clostridium sp. strain 14D1 and two strains of aerobic bacteria Psychrobacter sp. isolated from these cryopegs. The structural and physiological characteristics of new bacteria from water brines have shown their ability to survive and develop under harsh conditions, such as subzero temperatures and high salinity.

  20. Calcium extraction from brine water and seawater using oxalic acid

    Science.gov (United States)

    Natasha, Nadia Chrisayu; Lalasari, Latifa Hanum

    2017-01-01

    Calcium can be extracted not only from rocks but also from natural liquor such as seawater and brine water. In order to extract the calcium from seawater and brine water, oxalic acid was used in this research. Effect of variations of the volume of the oxalic acid at a constant concentration in seawater and brine water to produce calcium was investigated. The concentration of oxalic acid was 100 g/l and the variations of its volume were 2 ml, 4 ml, 6 ml, 8 ml, 10 ml, 20 ml, 30 ml, 40 ml, and 50 ml. The used seawater and brine water were firstly evaporated from 100 ml into 50 ml and then the oxalic acid was added into them with mixing to produce the calcium precipitates. The precipitates were analyzed by X-ray diffraction (XRD) and scanning electron microscope (SEM) and the filtrates were analyzed by inductively coupled plasma-optical emission spectrometry (ICP-OES). The SEM analysis showed that the precipitates from brine water were consisted of only calcium compound while from seawater sodium one was also found along with calcium compound. The XRD analysis showed that the calcium was present in the form of calcium oxalate for both seawater and brine water. The ICP-OES analysis of the filtrate from seawater precipitation showed that the its calcium content was decreased from 826.20 ppm to 0.04 ppm while from brine water, it decreased from 170.06 ppm to 1.96 ppm. These results showed that both seawater and brine water have the potential to be a raw material for calcium production.

  1. Internal and vorticity waves in decaying stratified flows

    Science.gov (United States)

    Matulka, A.; Cano, D.

    2009-04-01

    Most predictive models fail when forcing at the Rossby deformation Radius is important and a large range of scales have to be taken into account. When mixing of reactants or pollutants has to be accounted, the range of scales spans from hundreds of Kilometers to the Bachelor or Kolmogorov sub milimiter scales. We present some theoretical arguments to describe the flow in terms of the three dimensional vorticity equations, using a lengthscale related to the vorticity (or enstrophy ) transport. Effect of intermittent eddies and non-homogeneity of diffusion are also key issues in the environment because both stratification and rotation body forces are important and cause anisotropy/non-homogeneity. These problems need further theoretical, numerical and observational work and one approach is to try to maximize the relevant geometrical information in order to understand and therefore predict these complex environmental dispersive flows. The importance of the study of turbulence structure and its relevance in diffusion of contaminants in environmental flows is clear when we see the effect of environmental disasters such as the Prestige oil spill or the Chernobil radioactive cloud spread in the atmosphere. A series of Experiments have been performed on a strongly stratified two layer fluid consisting of Brine in the bottom and freshwater above in a 1 square meter tank. The evolution of the vortices after the passage of a grid is video recorded and Particle tracking is applied on small pliolite particles floating at the interface. The combination of internal waves and vertical vorticity produces two separate time scales that may produce resonances. The vorticity is seen to oscilate in a complex way, where the frecuency decreases with time.

  2. Effect of sodium chloride concentration on elemental analysis of brines by laser-induced breakdown spectroscopy (LIBS).

    Science.gov (United States)

    Goueguel, Christian; Singh, Jagdish P; McIntyre, Dustin L; Jain, Jinesh; Karamalidis, Athanasios K

    2014-01-01

    Leakage of injected carbon dioxide (CO2) or resident fluids, such as brine, is a major concern associated with the injection of large volumes of CO2 into deep saline formations. Migration of brine could contaminate drinking water resources by increasing their salinity or endanger vegetation and animal life as well as human health. The main objective of this study was to investigate the effect of sodium chloride (NaCl) concentration on the detection of calcium and potassium in brine samples using laser-induced breakdown spectroscopy (LIBS). The ultimate goals were to determine the suitability of the LIBS technique for in situ measurements of metal ion concentrations in NaCl-rich solution and to develop a chemical sensor that can provide the early detection of brine intrusion into formations used for domestic or agricultural water production. Several brine samples of NaCl-CaCl2 and NaCl-KCl were prepared at NaCl concentrations between 0.0 and 3.0 M. The effect of NaCl concentration on the signal-to-background ratio (SBR) and signal-to-noise ratio (SNR) for calcium (422.67 nm) and potassium (769.49 nm) emission lines was evaluated. Results show that, for a delay time of 300 ns and a gate width of 3 μs, the presence of and changes in NaCl concentration significantly affect the SBR and SNR for both emission lines. An increase in NaCl concentration from 0.0 to 3.0 M produced an increase in the SNR, whereas the SBR dropped continuously. The detection limits obtained for both elements were in the milligrams per liter range, suggesting that a NaCl-rich solution does not severely limit the ability of LIBS to detect trace amount of metal ions.

  3. Thermal-gradient migration of brine inclusions in salt

    International Nuclear Information System (INIS)

    Yagnik, S.K.

    1982-02-01

    It has been proposed that the high level nuclear waste be buried deep underground in a suitable geologic formation. Natural salt deposits have been under active consideration as one of the geologic formations where a nuclear waste repository may be built in future. The salt deposits, however, are known to contain a small amount (about 0.5 vol.%) of water in the form of brine inclusions which are dispersed throughout the medium. The temperature gradients imposed by the heat generating nuclear waste will mobilize these brine inclusions. It is important to know the rate and the amount of brine accumulating at the waste packages to properly evaluate the performance of a nuclear waste repository. An extensive experimental investigation of the migration velocities of brine inclusions in synthetic single crystals of NaCl and in polycrystalline natural salt crystals has been conducted. The results show that in a salt repository the brine inclusions within a grain would move with the diffusion controlled velocities. The brine reaching a grain boundary may be swept across, if the thermal gradient is high enough. Grain boundaries in polycrystalline rock salt are apparently quite weak and open up due to drilling the hole for a waste canister and to the thermal stresses which accompany the thermal gradient produced by the heat generating waste. The enhanced porosity allows the water reaching the grain boundary to escape by a vapor transport process

  4. Brine: a computer program to compute brine migration adjacent to a nuclear waste canister in a salt repository

    International Nuclear Information System (INIS)

    Duckworth, G.D.; Fuller, M.E.

    1980-01-01

    This report presents a mathematical model used to predict brine migration toward a nuclear waste canister in a bedded salt repository. The mathematical model is implemented in a computer program called BRINE. The program is written in FORTRAN and executes in the batch mode on a CDC 7600. A description of the program input requirements and output available is included. Samples of input and output are given

  5. Measurement and modeling of CO2 solubility in NaCl brine and CO2–saturated NaCl brine density

    DEFF Research Database (Denmark)

    Yan, Wei; Huang, Shengli; Stenby, Erling Halfdan

    2011-01-01

    over climate change and energy security. This work is an experimental and modeling study of two fundamental properties in high pressure CO2–NaCl brine equilibrium, i.e., CO2 solubility in NaCl brine and CO2–saturated NaCl brine density. A literature review of the available data was presented first...

  6. Understanding the kinetics of sulfate reduction in brines by hydrogen: Progress report

    International Nuclear Information System (INIS)

    Strachan, D.M.

    1988-07-01

    Experiments were conducted with mixtures of hydrogen gas and each of PBB1 and PBB3 brines to examine the reduction kinetics of sulfate in high ionic strength solutions. Results from the experiments with brines showed that the kinetics of sulfate reduction is slower in high ionic strength solutions than the kinetics in low ionic strength solutions. However, the kinetic mechanism does not seem to alter the slow kinetics, but the addition of much larger quantities of sulfide, about 40 mM, does accelerate the reduction of sulfate. Since the proposed reaction mechanism for the reduction of sulfate by hydrogen gas involves the reaction of sulfide with sulfate, slow initial kinetics in the absence of sulfide is understandable, but also implies an unknown rate-limiting reaction. Precipitation of calcium sulfate(s) and calcium sulfide may limit the sulfide and sulfate concentrations to low values. The coexistence of anhydrite and oldhamite may indicate a part of the Ca-S-H 2 O that has not yet been investigated. 6 refs., 4 figs., 3 tabs

  7. Thermal-gradient migration of brine inclusions in salt crystals

    International Nuclear Information System (INIS)

    Yagnik, S.K.

    1982-09-01

    It has been proposed that high-level nuclear waste be disposed in a geologic repository. Natural-salt deposits, which are being considered for this purpose, contain a small volume fraction of water in the form of brine inclusions distributed throughout the salt. Radioactive-decay heating of the nuclear wastes will impose a temperature gradient on the surrounding salt which mobilizes the brine inclusions. Inclusions filled completely with brine migrate up the temperature gradient and eventually accumulate brine near the buried waste forms. The brine may slowly corrode or degrade the waste forms which is undesirable. In this work, thermal gradient migration of both all-liquid and gas-liquid inclusions was experimentally studied in synthetic single crystals of NaCl and KCl using a hot-stage attachment to an optical microscope which was capable of imposing temperature gradients and axial compressive loads on the crystals. The migration velocities of the inclusions were found to be dependent on temperature, temperature gradient, and inclusion shape and size. The velocities were also dictated by the interfacial mass transfer resistance at brine/solid interface. This interfacial resistance depends on the dislocation density in the crystal, which in turn, depends on the axial compressive loading of the crystal. At low axial loads, the dependence between the velocity and temperature gradient is non-linear.At high axial loads, however, the interfacial resistance is reduced and the migration velocity depends linearly on the temperature gradient. All-liquid inclusions filled with mixed brines were also studied. For gas-liquid inclusions, three different gas phases (helium, air and argon) were compared. Migration studies were also conducted on single crystallites of natural salt as well as in polycrystalline natural salt samples. The behavior of the inclusions at large angle grain boundaries was observed. 35 figures, 3 tables

  8. Thermal gradient migration of brine inclusions in salt crystals

    International Nuclear Information System (INIS)

    Yagnik, S.K.

    1982-01-01

    Natural salt deposits, which are being considered for high-level nuclear wastes repositories, contain a small volume fraction of water in the form of brine inclusions distributed throughout the salt. Radioactive decay heating of the nuclear wastes will impose a temperature gradient on the surrounding salt which mobilizes the brine inclusions. Inclusions filled completely with brine (the all-liquid inclusions) migrate up the temperature gradient and eventually accumulate brine near the buried waste forms. The brine may slowly corrode or degrade the waste forms which is undesirable. In the present work, thermal gradient migration of both all-liquid and gas-liquid inclusions was experimentally studied in synthetic single crystals of NaCl and KCl using a hot-stage attachment to an optical microscope which was capable of imposing temperature gradients and axial compressive loads on the crystals. The migration velocities of the inclusions were found to be dependent on temperature, temperature gradient, and inclusion shape and size. The velocities were also dictated by the interfacial mass transfer resistance at brine/solid interface. This interfacial resistance depends on the dislocation density in the crystal, which in turn, depends on the axial compressive loading of the crystal. At low axial loads, the dependence between the velocity and temperature gradient is nonlinear. At high axial loads, however, the interfacial resistance is reduced and the migration velocity depends linearly on the temperature gradient. All-liquid inclusions filled with mixed brines were also studied. For gas-liquid inclusions, three different gas phases (helium, air and argon) were compared. Migration studies were also conducted on single crystallites of natural salt as well as in polycrystalline natural salt samples. The behavior of the inclusions at large angle grain boudaries was observed

  9. Stratified charge rotary engine for general aviation

    Science.gov (United States)

    Mount, R. E.; Parente, A. M.; Hady, W. F.

    1986-01-01

    A development history, a current development status assessment, and a design feature and performance capabilities account are given for stratified-charge rotary engines applicable to aircraft propulsion. Such engines are capable of operating on Jet-A fuel with substantial cost savings, improved altitude capability, and lower fuel consumption by comparison with gas turbine powerplants. Attention is given to the current development program of a 400-hp engine scheduled for initial operations in early 1990. Stratified charge rotary engines are also applicable to ground power units, airborne APUs, shipboard generators, and vehicular engines.

  10. Nitrogen transformations in stratified aquatic microbial ecosystems

    DEFF Research Database (Denmark)

    Revsbech, N. P.; Risgaard-Petersen, N.; Schramm, A.

    2006-01-01

    Abstract  New analytical methods such as advanced molecular techniques and microsensors have resulted in new insights about how nitrogen transformations in stratified microbial systems such as sediments and biofilms are regulated at a µm-mm scale. A large and ever-expanding knowledge base about n...

  11. Microbial Diversity and Ecology in the Interfaces of the Deep-sea Anoxic Brine Pools in the Red Sea

    KAUST Repository

    Hikmawan, Tyas I.

    2015-05-01

    Deep-sea anoxic brine pools are one of the most extreme ecosystems on Earth, which are characterized by drastic changes in salinity, temperature, and oxygen concentration. The interface between the brine and overlaying seawater represents a boundary of oxic-anoxic layer and a steep gradient of redox potential that would initiate favorable conditions for divergent metabolic activities, mainly methanogenesis and sulfate reduction. This study aimed to investigate the diversity of Bacteria, particularly sulfate-reducing communities, and their ecological roles in the interfaces of five geochemically distinct brine pools in the Red Sea. Performing a comprehensive study would enable us to understand the significant role of the microbial groups in local geochemical cycles. Therefore, we combined culture-dependent approach and molecular methods, such as 454 pyrosequencing of 16S rRNA gene, phylogenetic analysis of functional marker gene encoding for the alpha subunits of dissimilatory sulfite reductase (dsrA), and single-cell genomic analysis to address these issues. Community analysis based on 16S rRNA gene sequences demonstrated high bacterial diversity and domination of Bacteria over Archaea in most locations. In the hot and multilayered Atlantis II Deep, the bacterial communities were stratified and hardly overlapped. Meanwhile in the colder brine pools, sulfatereducing Deltaproteobacteria were the most prominent bacterial groups inhabiting the interfaces. Corresponding to the bacterial community profile, the analysis of dsrA gene sequences revealed collectively high diversity of sulfate-reducing communities. Desulfatiglans-like dsrA was the prevalent group and conserved across the Red Sea brine pools. In addition to the molecular studies, more than thirty bacterial strains were successfully isolated and remarkably were found to be cytotoxic against the cancer cell lines. However, none of them were sulfate reducers. Thus, a single-cell genomic analysis was used to study

  12. Extension of the EQ3/6 computer codes to geochemical modeling of brines

    Energy Technology Data Exchange (ETDEWEB)

    Jackson, K.J.; Wolery, T.J.

    1984-10-23

    Recent modifications to the EQ3/6 geochemical modeling software package provide for the use of Pitzer's equations to calculate the activity coefficients of aqueous species and the activity of water. These changes extend the range of solute concentrations over which the codes can be used to dependably calculate equilibria in geochemical systems, and permit the inclusion of ion pairs, complexes, and undissociated acids and bases as explicit component species in the Pitzer model. Comparisons of calculations made by the EQ3NR and EQ6 compuer codes with experimental data confirm that the modifications not only allow the codes to accurately evaluate activity coefficients in concentrated solutions, but also permit prediction of solubility limits of evaporite minerals in brines at 25/sup 0/C and elevated temperatures. Calculations for a few salts can be made at temperatures up to approx. 300/sup 0/C, but the temperature range for most electrolytes is constrained by the availability of requisite data to values less than or equal to 100/sup 0/C. The implementation of Pitzer's equations in EQ3/6 allows application of these codes to problems involving calculation of geochemical equilibria in brines; such as evaluation of the chemical environment which might be anticipated for nuclear waste canisters located in a salt repository. 26 references, 3 figures, 1 table.

  13. LONGITUDINAL OSCILLATIONS IN DENSITY STRATIFIED AND EXPANDING SOLAR WAVEGUIDES

    Energy Technology Data Exchange (ETDEWEB)

    Luna-Cardozo, M. [Instituto de Astronomia y Fisica del Espacio, CONICET-UBA, CC. 67, Suc. 28, 1428 Buenos Aires (Argentina); Verth, G. [School of Computing, Engineering and Information Sciences, Northumbria University, Newcastle Upon Tyne NE1 8ST (United Kingdom); Erdelyi, R., E-mail: mluna@iafe.uba.ar, E-mail: robertus@sheffield.ac.uk, E-mail: gary.verth@northumbria.ac.uk [Solar Physics and Space Plasma Research Centre (SP2RC), University of Sheffield, Hicks Building, Hounsfield Road, Sheffield S3 7RH (United Kingdom)

    2012-04-01

    Waves and oscillations can provide vital information about the internal structure of waveguides in which they propagate. Here, we analytically investigate the effects of density and magnetic stratification on linear longitudinal magnetohydrodynamic (MHD) waves. The focus of this paper is to study the eigenmodes of these oscillations. It is our specific aim to understand what happens to these MHD waves generated in flux tubes with non-constant (e.g., expanding or magnetic bottle) cross-sectional area and density variations. The governing equation of the longitudinal mode is derived and solved analytically and numerically. In particular, the limit of the thin flux tube approximation is examined. The general solution describing the slow longitudinal MHD waves in an expanding magnetic flux tube with constant density is found. Longitudinal MHD waves in density stratified loops with constant magnetic field are also analyzed. From analytical solutions, the frequency ratio of the first overtone and fundamental mode is investigated in stratified waveguides. For small expansion, a linear dependence between the frequency ratio and the expansion factor is found. From numerical calculations it was found that the frequency ratio strongly depends on the density profile chosen and, in general, the numerical results are in agreement with the analytical results. The relevance of these results for solar magneto-seismology is discussed.

  14. STRESS DISTRIBUTION IN THE STRATIFIED MASS CONTAINING VERTICAL ALVEOLE

    Directory of Open Access Journals (Sweden)

    Bobileva Tatiana Nikolaevna

    2017-08-01

    Full Text Available Almost all subsurface rocks used as foundations for various types of structures are stratified. Such heterogeneity may cause specific behaviour of the materials under strain. Differential equations describing the behaviour of such materials contain rapidly fluctuating coefficients, in view of this, solution of such equations is more time-consuming when using today’s computers. The method of asymptotic averaging leads to getting homogeneous medium under study to averaged equations with fixed factors. The present article is concerned with stratified soil mass consisting of pair-wise alternative isotropic elastic layers. In the results of elastic modules averaging, the present soil mass with horizontal rock stratification is simulated by homogeneous transversal-isotropic half-space with isotropy plane perpendicular to the standing axis. Half-space is loosened by a vertical alveole of circular cross-section, and virgin ground is under its own weight. For horizontal parting planes of layers, the following two types of surface conditions are set: ideal contact and backlash without cleavage. For homogeneous transversal-isotropic half-space received with a vertical alveole, the analytical solution of S.G. Lekhnitsky, well known in scientific papers, is used. The author gives expressions for stress components and displacements in soil mass for different marginal conditions on the alveole surface. Such research problems arise when constructing and maintaining buildings and when composite materials are used.

  15. Guidelines to Facilitate the Evaluation of Brines for Winter Roadway Maintenance Operations.

    Science.gov (United States)

    2017-09-19

    This document presents guidelines to facilitate the evaluation of brines for winter weather roadway maintenance applications in Texas. Brines are used in anti-icing applications which typically consist of placing liquid snow and ice control chemicals...

  16. A deep sea community at the Kebrit brine pool in the Red Sea

    KAUST Repository

    Vestheim, Hege; Kaartvedt, Stein

    2015-01-01

    Approximately 25 deep sea brine pools occur along the mid axis of the Red Sea. These hypersaline, anoxic, and acidic environments have previously been reported to host diverse microbial communities. We visited the Kebrit brine pool in April 2013

  17. Solubility and sorption characteristics of uranium(VI) associated with rock samples and brines/groundwaters from WIPP and NTS

    International Nuclear Information System (INIS)

    Dosch, R.G.

    1981-01-01

    Solubility measurements for U(VI) in WIPP-related brines/groundwaters were made using initial U(VI) concentrations in the range of 1 to 50 μg/ml. Distribution coefficients (Kd) for U(VI) were determined for Culebra and Magenta dolomites using four different brine/groundwater compositions and for argillaceous shale and hornfels samples from the Eleana and Calico Hills Formation on NTS using a groundwater simulant typical of that area. The Kd's were evaluated as functions of: (1) U(VI) concentration (1.4 x 10 -4 to 1.4 μg/ml); (2) solution volume-to-rock mass ratios used in the measurements (5 to 100 ml/g), and for WIPP material only; (3) water composition (0 to 100% brine in groundwater); and (4) sample location in the Culebra and Magenta dolomite members of the Rustler Formation. The results indicate that if groundwater intrudes into a repository and leaches a waste form, significant concentrations of dissolved or colloidal U(VI) could be maintained in the liquid phase. Should these solutions enter an aquifer system, there are reasonable sets of conditions which could lead to subsequent migration of U(VI) away from the repository site

  18. Chemical Composition and Enzymes Inhibitory, Brine Shrimp Larvae Toxicity, Antimicrobial and Antioxidant Activities of Caloplaca biatorina

    Directory of Open Access Journals (Sweden)

    Tahereh Valadbeigi

    2016-10-01

    Full Text Available Background This study evaluated the brine shrimp larvae toxicity and enzymes inhibitory especially anti-diabetic potential of Caloplaca biatorina via in vitro inhibition of α-amylase and α-glucosidase using the methanol extracts. Also aldehyde oxidase and xanthine oxidase enzymes inhibitory, cytotoxicity, and antioxidant activities of the species were determined. Methods In this experimental study, different concentrations of the extracts (0.2, 5.0, 1 and 1.5 mg/mL were incubated with enzyme substrate solution and the percentage of enzyme inhibitory activity and IC50 was calculated. Folin- Ciocalteu reagent and aluminium chloride colorimetric methods were used to estimate total phenolic and flavonoid content of extracts. The toxicity of the extract was assessed using the brine shrimp lethality bioassay. The minimal inhibitory concentration (MIC and minimum bactericidal concentration (MBC were determined. High-performance liquid chromatography and Thin-layer chromatography analysis were evaluated. The data were analyzed by SPSS V.21 software. Results Parietin, Emodin, 1,8-Dihydroxy-3-(hydroxymethyl-6- methoxy-9.10-anthracenedione and Rhein were identified. The extract showed strong α-glucosidase, aldehyde oxidase and xanthine oxidase inhibitory activities with IC50 value of 17.12, 40.09 and 11.02 µg/mL respectively. Also methanol extract displayed the strongest DPPH radical scavenging and brine shrimp toxicity (IC50 = 91.11 properties. Conclusions The result obtained suggests that the C. biatorina extract can be classified as non-toxic. Also, it revealed the antioxidant and antidiabetic potential of the lichen.

  19. Rock-brine chemical interactions. Final report

    Energy Technology Data Exchange (ETDEWEB)

    1982-02-01

    The results of experimental interaction of powdered volcanic rock with aqueous solutions are presented at temperatures from 200 to 400/sup 0/C, 500 to 1000 bars fluid pressure, with reaction durations of approximately 30 days under controlled laboratory conditions. The aim of this research is to develop data on the kinetics and equilibria of rock solution interactions that will provide insight into the complex geochemical processes attending geothermal reservoir development, stimulation, and reinjection. The research was done in the Stanford Hydrothermal Lab using gold cell equipment of the Dickson design. This equipment inverts the solution rock mixture several times a minute to ensure thorough mixing. Solution samples were periodically withdrawn without interruption of the experimental conditions. The data from these experiments suggests a path dependent series of reactions by which geothermal fluids might evolve from meteoric or magmatic sources.

  20. MC3D modelling of stratified explosion

    International Nuclear Information System (INIS)

    Picchi, S.; Berthoud, G.

    1999-01-01

    It is known that a steam explosion can occur in a stratified geometry and that the observed yields are lower than in the case of explosion in a premixture configuration. However, very few models are available to quantify the amount of melt which can be involved and the pressure peak that can be developed. In the stratified application of the MC3D code, mixing and fragmentation of the melt are explained by the growth of Kelvin Helmholtz instabilities due to the shear flow of the two phase coolant above the melt. Such a model is then used to recalculate the Frost-Ciccarelli tin-water experiment. Pressure peak, speed of propagation, bubble shape and erosion height are well reproduced as well as the influence of the inertial constraint (height of the water pool). (author)

  1. MC3D modelling of stratified explosion

    Energy Technology Data Exchange (ETDEWEB)

    Picchi, S.; Berthoud, G. [DTP/SMTH/LM2, CEA, 38 - Grenoble (France)

    1999-07-01

    It is known that a steam explosion can occur in a stratified geometry and that the observed yields are lower than in the case of explosion in a premixture configuration. However, very few models are available to quantify the amount of melt which can be involved and the pressure peak that can be developed. In the stratified application of the MC3D code, mixing and fragmentation of the melt are explained by the growth of Kelvin Helmholtz instabilities due to the shear flow of the two phase coolant above the melt. Such a model is then used to recalculate the Frost-Ciccarelli tin-water experiment. Pressure peak, speed of propagation, bubble shape and erosion height are well reproduced as well as the influence of the inertial constraint (height of the water pool). (author)

  2. Equipment for extracting and conveying stratified minerals

    Energy Technology Data Exchange (ETDEWEB)

    Blumenthal, G.; Kunzer, H.; Plaga, K.

    1991-08-14

    This invention relates to equipment for extracting stratified minerals and conveying the said minerals along the working face, comprising a trough shaped conveyor run assembled from lengths, a troughed extraction run in lengths matching the lengths of conveyor troughing, which is linked to the top edge of the working face side of the conveyor troughing with freedom to swivel vertically, and a positively guided chain carrying extraction tools and scrapers along the conveyor and extraction runs.

  3. Inviscid incompressible limits of strongly stratified fluids

    Czech Academy of Sciences Publication Activity Database

    Feireisl, Eduard; Jin, B.J.; Novotný, A.

    2014-01-01

    Roč. 89, 3-4 (2014), s. 307-329 ISSN 0921-7134 R&D Projects: GA ČR GA201/09/0917 Institutional support: RVO:67985840 Keywords : compressible Navier-Stokes system * anelastic approximation * stratified fluid Subject RIV: BA - General Mathematics Impact factor: 0.528, year: 2014 http://iospress.metapress.com/content/d71255745tl50125/?p=969b60ae82634854ab8bd25505ce1f71&pi=3

  4. Nitrogen transformations in stratified aquatic microbial ecosystems

    DEFF Research Database (Denmark)

    Revsbech, Niels Peter; Risgaard-Petersen, N.; Schramm, Andreas

    2006-01-01

    Abstract  New analytical methods such as advanced molecular techniques and microsensors have resulted in new insights about how nitrogen transformations in stratified microbial systems such as sediments and biofilms are regulated at a µm-mm scale. A large and ever-expanding knowledge base about n...... performing dissimilatory reduction of nitrate to ammonium have given new dimensions to the understanding of nitrogen cycling in nature, and the occurrence of these organisms and processes in stratified microbial communities will be described in detail.......Abstract  New analytical methods such as advanced molecular techniques and microsensors have resulted in new insights about how nitrogen transformations in stratified microbial systems such as sediments and biofilms are regulated at a µm-mm scale. A large and ever-expanding knowledge base about...... nitrogen fixation, nitrification, denitrification, and dissimilatory reduction of nitrate to ammonium, and about the microorganisms performing the processes, has been produced by use of these techniques. During the last decade the discovery of anammmox bacteria and migrating, nitrate accumulating bacteria...

  5. Large eddy simulation of stably stratified turbulence

    International Nuclear Information System (INIS)

    Shen Zhi; Zhang Zhaoshun; Cui Guixiang; Xu Chunxiao

    2011-01-01

    Stably stratified turbulence is a common phenomenon in atmosphere and ocean. In this paper the large eddy simulation is utilized for investigating homogeneous stably stratified turbulence numerically at Reynolds number Re = uL/v = 10 2 ∼10 3 and Froude number Fr = u/NL = 10 −2 ∼10 0 in which u is root mean square of velocity fluctuations, L is integral scale and N is Brunt-Vaïsälä frequency. Three sets of computation cases are designed with different initial conditions, namely isotropic turbulence, Taylor Green vortex and internal waves, to investigate the statistical properties from different origins. The computed horizontal and vertical energy spectra are consistent with observation in atmosphere and ocean when the composite parameter ReFr 2 is greater than O(1). It has also been found in this paper that the stratification turbulence can be developed under different initial velocity conditions and the internal wave energy is dominated in the developed stably stratified turbulence.

  6. Ikaite solubility in seawater-derived brines at 1 atm and sub-zero temperatures to 265 K

    Science.gov (United States)

    Papadimitriou, Stathys; Kennedy, Hilary; Kennedy, Paul; Thomas, David N.

    2013-05-01

    The concentration-based (stoichiometric) equilibrium solubility product of ikaite (CaCO3·6H2O) in seawater and cryogenic seawater-derived brines was determined at 1 atm total pressure over the temperature range from -1.1 to -7.5 °C and the salinity range from 34 to 124 in temperature-salinity pairs representative of sea ice brines. The solubility measurements were obtained in solutions that were undersaturated and supersaturated with respect to ikaite by equilibration with CO2/N2 gas mixtures of known pCO2 (20-400 μatm). The solutions were then equilibrated with synthetic ikaite (seed) for up to 3 months in a closed system. Arrival of the solid-solution system at a long-term chemical equilibrium was indicated by attainment of constant chemical solution composition with respect to total dissolved calcium, total dissolved inorganic carbon, and total alkalinity. Using these measurements, the stoichiometric equilibrium solubility product of ikaite (Ksp,ikaite∗=[Ca][CO32-], in molkgsolution-2) was determined, with the carbonate ion concentration computed from the measured total alkalinity and total dissolved inorganic carbon concentrations. The computed carbonate ion concentration and, by extension, the Ksp,ikaite∗ are both contingent on solving the system of equations that describe the parameters of the CO2 system in seawater by extrapolation to the experimental salinity and temperature conditions. The results show that the pKsp,ikaite∗=-logKsp,ikaite∗ in seawater of salinity 34 at -1.1 °C was 5.362 ± 0.004 and that the pKsp,ikaite∗ in sea ice at the freezing point of brines of salinity greater than 34 can be described as a function of temperature (T, in K) by the equation, pKsp,ikaite∗=-15489.09608+623443.70216T-1+2355.14596lnT, in the temperature range of 265.15 K 1 month) approach to chemical equilibrium when incubated without seeding ikaite crystals. Simple modeling indicated that ikaite should not precipitate from sea ice brines evolving under

  7. Solar desalination, brine and fine chemicals - a preliminary report

    Digital Repository Service at National Institute of Oceanography (India)

    Shirodkar, P.V.; Nagarajan, R.

    Solar stills put into operation by taking known quantities of sea water of different salinities varying from 27.75-36.27 x 10 super(3) during April-May 1990, indicated fresh water yield of 55-68% (av. 64). The volumes of brine as well as those...

  8. Durability of concrete materials in high-magnesium brine

    International Nuclear Information System (INIS)

    Wakeley, L.D.; Poole, T.S.; Burkes, J.P.

    1994-03-01

    Cement pastes and mortars representing 11 combinations of candidate concrete materials were cast in the laboratory and monitored for susceptibility to chemical deterioration in high-magnesium brine. Mixtures were selected to include materials included in the current leading candidate concrete for seals at the Waste Isolation Pilot Plant (WIPP). Some materials were included in the experimental matrix to answer questions that had arisen during study of the concrete used for construction of the liner of the WIPP waste-handling shaft. Mixture combinations compared Class C and Class F fly ashes, presence or absence of an expansive component, and presence or absence of salt as a mixture component. Experimental conditions exposed the pastes and mortars to extreme conditions, those being very high levels of Mg ion and an effectively unlimited supply of brine. All pastes and mortars showed deterioration with brine exposure. In general, mortars deteriorated more extensively than the corresponding pastes. Two-inch cube specimens of mortar were not uniformly deteriorated, but showed obvious zoning even after a year in the brine, with a relatively unreacted zone remaining at the center of each cube. Loss of calcium from the calcium hydroxide of paste/aggregate interfaces caused measurable strength loss in the reacted zone comprising the outer portion of every mortar specimen. The current candidate mass concrete for WIPP seals includes salt as an initial component, and has a relatively closed initial microstructure. Both of these features contribute to its suitability for use in large placements within the Salado Formation

  9. Brine Shrimp Toxicity Evaluation Of Some Tanzanian Plants Used ...

    African Journals Online (AJOL)

    Plants which are used by traditional healers in Tanzania have been evaluated to obtain preliminary data of their toxicity using the brine shrimps test. The results indicate that 9 out of 44 plant species whose extracts were tested exhibited high toxicity with LC50 values below 20μg/ml. These include Aloe lateritia Engl.

  10. Modeling the morphogenesis of brine channels in sea ice.

    Science.gov (United States)

    Kutschan, B; Morawetz, K; Gemming, S

    2010-03-01

    Brine channels are formed in sea ice under certain constraints and represent a habitat of different microorganisms. The complex system depends on a number of various quantities as salinity, density, pH value, or temperature. Each quantity governs the process of brine channel formation. There exists a strong link between bulk salinity and the presence of brine drainage channels in growing ice with respect to both the horizontal and vertical planes. We develop a suitable phenomenological model for the formation of brine channels both referring to the Ginzburg-Landau theory of phase transitions as well as to the chemical basis of morphogenesis according to Turing. It is possible to conclude from the critical wave number on the size of the structure and the critical parameters. The theoretically deduced transition rates have the same magnitude as the experimental values. The model creates channels of similar size as observed experimentally. An extension of the model toward channels with different sizes is possible. The microstructure of ice determines the albedo feedback and plays therefore an important role for large-scale global circulation models.

  11. Solar desalination, brine and fine chemicals - a preliminary report

    Digital Repository Service at National Institute of Oceanography (India)

    Shirodkar, P.V.; Nagarajan, R.

    from 3.65 - 4.63 ppm. The definite volumes of seawater samples (3.7 litres) taken in stills for desalination correspond to 13.08 - 31.16 mg of net boron content. Analyses on the recovery of the total content of boron in brines as well as in the bitterns...

  12. [Experimental interaction of halophilic prokaryotes and opportunistic bacteria in brine].

    Science.gov (United States)

    Selivanova, E A; Nemtseva, N V

    2013-01-01

    Study the effect of extremely halophilic archaea and moderately halophilic bacteria on preservation of opportunistic bacteria in brine. 17 strains of moderately halophilic bacteria and 2 strains of extremely halophilic archaea were isolated from continental hypersaline lake Razval of Sol-Iletsk area of Orenburg Region. Identification of pure cultures of prokaryotes was carried out taking into account their phenotype properties and based on determination of 16S RNA gene sequence. The effect of halophilic prokaryote on elimination of Escherichia coli from brine was evaluated during co-cultivation. Antagonistic activity of cell extracts of the studied microorganisms was evaluated by photometric method. A more prolonged preservation of an E. coli strain in brine in the presence of live cells of extremely halophilic archaea Halorubrum tebenquichense and moderately halophilic bacteria Marinococcus halophilus was established. Extracts of cells of extremely halophilic archaea and moderately halophilic bacteria on the contrary displayed antagonistic activity. The protective effect of live cells of halophilic prokaryotes and antagonistic activity of their cell extracts change the period of conservation of opportunistic bacteria in brine that regulates inter-microbial interactions and changes the period of self-purification that reflects the sanitary condition of a hypersaline water body.

  13. E25 stratified torch ignition engine emissions and combustion analysis

    International Nuclear Information System (INIS)

    Rodrigues Filho, Fernando Antonio; Baêta, José Guilherme Coelho; Teixeira, Alysson Fernandes; Valle, Ramón Molina; Fonseca de Souza, José Leôncio

    2016-01-01

    Highlights: • A stratified torch ignition (STI) engine was built and tested. • The STI engines was tested in a wide range of load and speed. • Significant reduction on emissions was achieved by means of the STI system. • Low cyclic variability characterized the lean combustion process of the torch ignition engine. • HC emission is the main drawback of the stratified torch ignition engine. - Abstract: Vehicular emissions significantly increase atmospheric air pollution and greenhouse gases (GHG). This fact associated with fast global vehicle fleet growth calls for prompt scientific community technological solutions in order to promote a significant reduction in vehicle fuel consumption and emissions, especially of fossil fuels to comply with future legislation. To meet this goal, a prototype stratified torch ignition (STI) engine was built from a commercial existing baseline engine. In this system, combustion starts in a pre-combustion chamber, where the pressure increase pushes the combustion jet flames through calibrated nozzles to be precisely targeted into the main chamber. These combustion jet flames are endowed with high thermal and kinetic energy, being able to generate a stable lean combustion process. The high kinetic and thermal energy of the combustion jet flame results from the load stratification. This is carried out through direct fuel injection in the pre-combustion chamber by means of a prototype gasoline direct injector (GDI) developed for a very low fuel flow rate. In this work the engine out-emissions of CO, NOx, HC and CO_2 of the STI engine are presented and a detailed analysis supported by the combustion parameters is conducted. The results obtained in this work show a significant decrease in the specific emissions of CO, NOx and CO_2 of the STI engine in comparison with the baseline engine. On the other hand, HC specific emission increased due to wall wetting from the fuel hitting in the pre-combustion chamber wall.

  14. The role of climate in the accumulation of lithium-rich brine in the Central Andes

    International Nuclear Information System (INIS)

    Godfrey, L.V.; Chan, L.-H.; Alonso, R.N.; Lowenstein, T.K.; McDonough, W.F.; Houston, J.; Li, J.; Bobst, A.; Jordan, T.E.

    2013-01-01

    Highlights: • δ 7 Li of waters and rocks in the Central Andes were measured. • Halite/brine partition coefficients of lithium and δ 7 Li of halite were determined. • Li-rich brines have a high component of fluids of geothermal origin. • Removal of lithium by clays is minor relative to other regions of the world. • The weathering flux of lithium and sodium decouple according to climate state. - Abstract: Lithium-rich brine within the sub-surface of the Salar del Hombre Muerto (SHM) salt pan in the Andes of northwestern Argentina has a chemical and isotopic composition which is consistent with Li derived from several sources: the modern halite saturated lagoon, Li-rich salts and brines formed recently, and dissolution of halite which precipitated from ancient saline lakes. SHM lies in the closed basin that includes part of the massive Cerro Galán caldera which is drained by the Río los Patos, which is responsible for 90% of surface runoff into the salar. The low Li isotope composition, +3.4‰, of this river is consistent with significant contributions of geothermal spring water. As water drains through the volcaniclastic deposits which cover a large proportion of the basin, Li removal, as indicated by decreasing Li/Na, occurs but without significant isotope fractionation. This indicates a mechanism of surface sorption onto smectite or ferrihydrite rather than Li incorporation into octahedral structural sites of clays. These observations suggest that conditions in this high altitude desert have limited the dilution of hydrothermal spring water as well as the formation of clay minerals, which jointly have allowed the Li resource to accumulate rapidly. Changes in climate on a multi-millennial time scale, specifically in the hydrologic budget, have resulted in solute accumulation rates that have been variable through time, and decoupled Li and Na fluxes. Inflow to the salar under modern conditions has high Li/Na (7.9 × 10 −3 by wt) with δ 7 Li

  15. Geochemistry of metal-rich brines from central Mississippi Salt Dome basin, U.S.A.

    Science.gov (United States)

    Kharaka, Y.K.; Maest, A.S.; Carothers, W.W.; Law, L.M.; Lamothe, P.J.; Fries, T.L.

    1987-01-01

    Oil-field brines are the most favored ore-forming solutions for the sediment-hosted Mississippi Valley-type ore deposits. Detailed inorganic and organic chemical and isotope analyses of water and gas samples from six oil fields in central Mississippi, one of the very few areas with high metal brines, were conducted to study the inorganic and organic complexes responsible for the high concentrations of these metals. The samples were obtained from production zones consisting of sandstone and limestone that range in depth from 1900 to 4000 m (70-120??C) and in age from Late Cretaceous to Late Jurassic. Results show that the waters are dominantly bittern brines related to the Louann Salt. The brines have extremely high salinities that range from 160,000 to 320,000 mg/l total dissolved solids and are NaCaCl-type waters with very high concentrations of Ca (up to 48,000 mg/l) and other alkaline-earth metals, but with low concentrations of aliphatic acid anions. The concentrations of metals in many water samples are very high, reaching values of 70 mg/l for Pb, 245 mg/l for Zn, 465 mg/l for Fe and 210 mg/l for Mn. The samples with high metal contents have extremely low concentrations (<0.02 mg/l) of H2S. Samples obtained from the Smackover Formation (limestone) have low metal contents that are more typical of oil-field waters, but have very high concentrations (up to 85 mg/l) of H2S. Computations with the geochemical code SOLMINEQ.87 give the following results: (1) both Pb and Zn are present predominantly as aqueous chloride complexes (mainly as PbCl42- and ZnCl42-, respectively); (2) the concentrations of metals complexed with short-chained aliphatic acid anions and reduced S species are minor; (3) organic acid anions are important in controlling the concentrations of metals because they affect the pH and buffer capacity of the waters at subsurface conditions; and (4) galena and sphalerite solubilities control the concentrations of Pb and Zn in these waters. ?? 1988.

  16. Origin, distribution, and movement of brine in the Permian Basin (U.S.A.). A model for displacement of connate brine

    International Nuclear Information System (INIS)

    Bein, A.; Dutton, A.R.

    1993-01-01

    Na-Cl, halite Ca-Cl, and gypsum Ca-Cl brines with salinities from 45 to >300 g/L are identified and mapped in four hydrostratigraphic units in the Permian Basin area beneath western Texas and Oklahoma and eastern New Mexico, providing spatial and lithologic constraints on the interpretation of the origin and movement of brine. Na-Cl brine is derived from meteoric water as young as 5-10 Ma that dissolved anhydrite and halite, whereas Ca-Cl brine is interpreted to be ancient, modified-connate Permian brine that now is mixing with, and being displaced by, the Na-Cl brine. Displacement fronts appear as broad mixing zones with no significant salinity gradients. Evolution of Ca-Cl brine composition from ideal evaporated sea water is attributed to dolomitization and syndepositional recycling of halite and bittern salts by intermittent influx of fresh water and sea water. Halite Ca-Cl brine in the evaporite section in the northern part of the basin differs from gypsum Ca-Cl brine in the south-central part in salinity and Na/Cl ratio and reflects segregation between halite- and gypsum-precipitating lagoons during the Permian. Ca-Cl brine moved downward through the evaporite section into the underlying Lower Permian and Pennsylvanian marine section that is now the deep-basin brine aquifer, mixing there with pre-existing sea water. Buoyancy-driven convection of brine dominated local flow for most of basin history, with regional advection governed by topographically related forces dominant only for the past 5 to 10 Ma. 71 refs., 11 figs

  17. Study of lithium extraction from brine water, Bledug Kuwu, Indonesia by the precipitation series of oxalic acid and carbonate sodium

    Science.gov (United States)

    Sulistiyono, Eko; Lalasari, Latifa Hanum; Mayangsari, W.; Prasetyo, A. B.

    2018-05-01

    Lithium is one of the key elements in the development of batteries for electric car applications. Currently, the resources of the world's lithium are derived from brine water and lithium mineral based on spodumene rock. Indonesia which is located in the area of the ring of fire, has potential brine water resources in some area, such as brine water from Bledug Kuwu, Central Java that used in this research. The purposes of this research are to characterize brine water, Bledug Kuwu and to investigate the influence of chemical solvents on Li, Na, K, Ca, Mg, Al, B ion precipitation from brine water. This research was done with 2 times the process of chemical precipitation that runs series as follows: 5 liters of brine water were chemically precipitated using 400 ml of 12.43 N oxalic acid and followed by chemical precipitation using 400 mL of 7.07 N sodium carbonate solutions. Evaporation and filtration processes were also done twice in an effort to separate white precipitate and filtrate. The filtrate was analyzed by ICP-OES and white precipitates (salts) were analyzed by SEM, XRD, and XRF. The result shows that oxalate precipitation process extracted 32.24% Al, 23.42% B, 22.43% Ca, 14.26% Fe, 3.21 % K, 9.86% Na and 14.26% Li, the following process by carbonate precipitation process extracted 98.86% Mg, 73% Ca, 22.53% Li, 82.04% Al, 14.38% B, 12.50% K, 2.27% Na. There is 63.21% lithium is not extracted from the series process. The SEM analysis shows that the structure of granules on the precipitated salts by oxalic acid form gentle cubic-shaped solid. In the other hand, oxalate precipitation followed by sodium carbonate has various particle sizes and the shape of crystals is fragments, prism and cube look like magnesium carbonate, calcium chloride, and calcite's crystal respectively. This is in accordance with XRD analysis that phases of whewellite (CaC2O4.H2O), disodium oxalate (Na2C2O4), magnesite (MgCO3), calcium lithium aluminum (Al1.19 Ca1Li0.81), dolomite (CaCO3

  18. Coastal California Wastewater Effluent as a Resource for Seawater Desalination Brine Commingling

    Directory of Open Access Journals (Sweden)

    Kelly E. Rodman

    2018-03-01

    Full Text Available California frequently experiences water scarcity, especially in high population areas. This has generated increased interest in using the Pacific Ocean as a water resource, with seawater desalination becoming a popular solution. To mitigate the environmental impacts of the high salinity brine from seawater desalination, California recommends commingling brine with wastewater effluent before ocean discharge. Results reveal that throughout the California coast, approximately 4872 MLD (1287 MGD of treated wastewater are discharged into the ocean and might be available as dilution water. Most of this dilution water resource is produced in Southern California (3161 MLD or 835 MGD and the San Francisco Bay Area (1503 MLD or 397 MGD, which are also the areas with the highest need for alternative water sources. With this quantity of dilution water, in principle, over 5300 MLD (1400 MGD of potable water could be produced in California through seawater desalination. Furthermore, this study provides a survey of the treatment levels and typical discharge violations of ocean wastewater treatment facilities in California.

  19. {sup 222}Rn determination in water and brine samples using liquid scintillation spectrometry

    Energy Technology Data Exchange (ETDEWEB)

    Oliveira, Thiago C.; Oliveira, Arno H., E-mail: oliveiratco2010@gmail.com [Universidade Federal de Minas Gerais (DEN/UFMG), Belo Horizonte (Brazil). Departamento de Engenharia Nuclear; Monteiro, Roberto P.G.; Moreira, Rubens M., E-mail: rpgm@cdtn.br [Centro de Desenvolvimento da Tecnologia Nuclear (CDTN-CNEN-MG), Belo Horizonte, MG (Brazil)

    2017-07-01

    Liquid scintillation spectrometry (LSC) is the most common technique used for {sup 222}Rn determination in environmental aqueous sample. In this study, the performance of water-miscible (Ultima Gold AB) and immiscible (Optiscint) liquid scintillation cocktails has been compared for different matrices. {sup 241}Am, {sup 90}Sr and {sup 226}Ra standard solutions were used for LSC calibration. {sup 214}Po region was defined as better for both cocktails. Counting efficiency of 76 % and optimum PSA level of 95 for Ultima Gold AB cocktail, and counting efficiency of 82 % and optimum PSA level of 85 for Optiscint cocktail were obtained. Both cocktails showed similar results when applied for {sup 222}Rn activity determination in water and brine samples. However the Optiscint is recommended due to its quenching resistance. Limit of detection of 0.08 and 0.06 Bq l{sup -1} were obtained for water samples using a sample:cocktail ratio of 10:12 mL for Ultima Gold AB and Optiscint cocktails, respectively. Limit of detection of 0.08 and 0.04 Bq l{sup -1} were obtained for brine samples using a sample:cocktail ratio of 8:12 mL for Ultima Gold AB and Optiscint cocktails, respectively. (author)

  20. 222Rn determination in water and brine samples using liquid scintillation spectrometry

    International Nuclear Information System (INIS)

    Oliveira, Thiago C.; Oliveira, Arno H.

    2017-01-01

    Liquid scintillation spectrometry (LSC) is the most common technique used for 222 Rn determination in environmental aqueous sample. In this study, the performance of water-miscible (Ultima Gold AB) and immiscible (Optiscint) liquid scintillation cocktails has been compared for different matrices. 241 Am, 90 Sr and 226 Ra standard solutions were used for LSC calibration. 214 Po region was defined as better for both cocktails. Counting efficiency of 76 % and optimum PSA level of 95 for Ultima Gold AB cocktail, and counting efficiency of 82 % and optimum PSA level of 85 for Optiscint cocktail were obtained. Both cocktails showed similar results when applied for 222 Rn activity determination in water and brine samples. However the Optiscint is recommended due to its quenching resistance. Limit of detection of 0.08 and 0.06 Bq l -1 were obtained for water samples using a sample:cocktail ratio of 10:12 mL for Ultima Gold AB and Optiscint cocktails, respectively. Limit of detection of 0.08 and 0.04 Bq l -1 were obtained for brine samples using a sample:cocktail ratio of 8:12 mL for Ultima Gold AB and Optiscint cocktails, respectively. (author)

  1. Lithium recovery from brine using a λ-MnO2/activated carbon hybrid supercapacitor system.

    Science.gov (United States)

    Kim, Seoni; Lee, Jaehan; Kang, Jin Soo; Jo, Kyusik; Kim, Seonghwan; Sung, Yung-Eun; Yoon, Jeyong

    2015-04-01

    Lithium is one of the most important elements in various fields including energy storage, medicine manufacturing and the glass industry, and demands for lithium are constantly increasing these days. The lime soda evaporation process using brine lake water is the major extraction method for lithium, but this process is not only inefficient and time-consuming but also causes a few environmental problems. Electrochemical recovery processes of lithium ions have been proposed recently, but the better idea for the silver negative electrodes used in these systems is required to reduce its cost or increase long term stability. Here, we report an electrochemical lithium recovery method based on a λ-MnO2/activated carbon hybrid supercapacitor system. In this system, lithium ions and counter anions are effectively captured at each electrode with low energy consumption in a salt solution containing various cationic species or simulated Salar de Atacama brine lake water in Chile. Furthermore, we designed this system as a flow process for practical applications. By experimental analyses, we confirmed that this system has high selectivity and long-term stability, with its performance being retained even after repetitive captures and releases of lithium ions. Copyright © 2015 Elsevier Ltd. All rights reserved.

  2. Stratification and space-time variability of Red Sea hot brines

    Energy Technology Data Exchange (ETDEWEB)

    Monin, A S; Plakhin, E A

    1982-11-01

    The results of hydrophysical studies in Red Sea hot brines prefaced with historical information are presented. The CTD-recorder readings show stratification of the upper brine in the Atlantis II Deep into meter-scale layers, in agreement with laboratory findings. Repeated soundings with the AIST CTD meter of the upper brine interface in the Valdivia Deep recorded internal waves of 3 to 4-h periods. The observations show the different nature of brines in the four deeps studied and the lack of contact between the brine layers of the Chain and Discovery deeps.

  3. Brine migration in salt and its implications in the geologic disposal of nuclear waste

    International Nuclear Information System (INIS)

    Jenks, G.H.; Claiborne, H.C.

    1981-12-01

    This report respresents a comprehensive review and analysis of available information relating to brine migration in salt surrounding radioactive waste in a salt repository. The topics covered relate to (1) the characteristics of salt formations and waste packages pertinent to considerations of rates, amounts, and effects of brine migration, (2) experimental and theoretical information on brine migration, and (3) means of designing to minimize any adverse effects of brine migration. Flooding, brine pockets, and other topics were not considered, since these features will presumably be eliminated by appropriate site selection and repository design. 115 references

  4. Assessment of Brine Management for Geologic Carbon Sequestration

    Energy Technology Data Exchange (ETDEWEB)

    Breunig, Hanna M. [Lawrence Berkeley National Lab. (LBNL), Berkeley, CA (United States). Environmental Energy Technologies Division; Birkholzer, Jens T. [Lawrence Berkeley National Lab. (LBNL), Berkeley, CA (United States). Environmental Energy Technologies Division; Borgia, Andrea [Lawrence Berkeley National Lab. (LBNL), Berkeley, CA (United States). Environmental Energy Technologies Division; Price, Phillip N. [Lawrence Berkeley National Lab. (LBNL), Berkeley, CA (United States). Environmental Energy Technologies Division; Oldenburg, Curtis M. [Lawrence Berkeley National Lab. (LBNL), Berkeley, CA (United States). Environmental Energy Technologies Division; McKone, Thomas E. [Lawrence Berkeley National Lab. (LBNL), Berkeley, CA (United States). Environmental Energy Technologies Division

    2013-06-13

    Geologic carbon sequestration (GCS) is the injection of carbon dioxide (CO2), typically captured from stationary emission sources, into deep geologic formations to prevent its entry into the atmosphere. Active pilot facilities run by regional United States (US) carbon sequestration partnerships inject on the order of one million metric tonnes (mt) CO2 annually while the US electric power sector emits over 2000 million mt-CO2 annually. GCS is likely to play an increasing role in US carbon mitigation initiatives, but scaling up GCS poses several challenges. Injecting CO2 into sedimentary basins raises fluid pressure in the pore space, which is typically already occupied by naturally occurring, or native, brine. The resulting elevated pore pressures increase the likelihood of induced seismicity, of brine or CO2 escaping into potable groundwater resources, and of CO2 escaping into the atmosphere. Brine extraction is one method for pressure management, in which brine in the injection formation is brought to the surface through extraction wells. Removal of the brine makes room for the CO2 and decreases pressurization. Although the technology required for brine extraction is mature, this form of pressure management will only be applicable if there are cost-­effective and sustainable methods of disposing of the extracted brine. Brine extraction, treatment, and disposal may increase the already substantial capital, energy, and water demands of Carbon dioxide Capture and Sequestration (CCS). But, regionally specific brine management strategies may be able to treat the extracted water as a source of revenue, energy, and water to subsidize CCS costs, while minimizing environmental impacts. By this approach, value from the extracted water would be recovered before disposing of any resulting byproducts. Until a price is placed on carbon, we expect that utilities and other CO2 sources will be

  5. [Causes of emergency dizziness stratified by etiology].

    Science.gov (United States)

    Qiao, Wenying; Liu, Jianguo; Zeng, Hong; Liu, Yugeng; Jia, Weihua; Wang, Honghong; Liu, Bo; Tan, Jing; Li, Changqing

    2014-06-03

    To explore the causes of emergency dizziness stratified to improve the diagnostic efficiency. A total of 1 857 cases of dizziness at our emergency department were collected and their etiologies stratified by age and gender. The top three diagnoses were benign paroxysmal positional vertigo (BPPV, 31.7%), hypertension (24.0%) and posterior circulation ischemia (PCI, 20.5%). Stratified by age, the main causes of dizziness included BPPV (n = 6), migraine-associated vertigo (n = 2), unknown cause (n = 1) for the group of vertigo (14.5%) and neurosis (7.3%) for 18-44 years; BPPV (36.8%), hypertension (22.4%) and migraine-associated vertigo (11.2%) for 45-59 years; hypertension (30.8%), PCI (29.8%) and BPPV (22.9%) for 60-74 years; PCI (30.7%), hypertension (28.6%) and BPPV (25.5%) for 75-92 years. BPPV, migraine and neurosis were more common in females while hypertension and PCI predominated in males (all P hypertension, neurosis and migraine showed the following significant demographic features: BPPV, PCI, hypertension, neurosis and migraine may be the main causes of dizziness. BPPV should be considered initially when vertigo was triggered repeatedly by positional change, especially for young and middle-aged women. And the other common causes of dizziness were migraine-associated vertigo, neurosis and Meniere's disease.Hypertension should be screened firstly in middle-aged and elderly patients presenting mainly with head heaviness and stretching. In elders with dizziness, BPPV is second in constituent ratio to PCI and hypertension.In middle-aged and elderly patients with dizziness, psychological factors should be considered and diagnosis and treatment should be offered timely.

  6. Evaluation and analysis of underground brine resources in the southern coastal area of Laizhou Bay

    Science.gov (United States)

    Tian, M.; Zhu, H. T.; Feng, J.; Zhao, Q. S.

    2016-08-01

    The southern coastal districts of Laizhou Bay are some of the most important areas for underground brine exploitation in Shandong Province. Recently, these areas have been gradually developed by the underground brine mining industry. Such economic interest has led to brine exploitation so that underground brine resources are running out. Based on this phenomenon, this study describes the supply, runoff and draining conditions of the area by collecting and organizing the background information of the studied area. Hydrogeological parameters are then calculated according to pumping tests, and the amount of sustainable resources in the coastal areas of the Southern Bank of Laizhou Bay are then calculated based on the uniform distribution of wells. Under the circumstances of underground brine mining, the exploitation potential of the underground brine is evaluated in accordance with the calculation results of exploitation quantum. Finally, suggestions are provided for the sustainable exploitation of underground brine in the area.

  7. White dwarf stars with chemically stratified atmospheres

    Science.gov (United States)

    Muchmore, D.

    1982-01-01

    Recent observations and theory suggest that some white dwarfs may have chemically stratified atmospheres - thin layers of hydrogen lying above helium-rich envelopes. Models of such atmospheres show that a discontinuous temperature inversion can occur at the boundary between the layers. Model spectra for layered atmospheres at 30,000 K and 50,000 K tend to have smaller decrements at 912 A, 504 A, and 228 A than uniform atmospheres would have. On the basis of their continuous extreme ultraviolet spectra, it is possible to distinguish observationally between uniform and layered atmospheres for hot white dwarfs.

  8. Bayesian stratified sampling to assess corpus utility

    Energy Technology Data Exchange (ETDEWEB)

    Hochberg, J.; Scovel, C.; Thomas, T.; Hall, S.

    1998-12-01

    This paper describes a method for asking statistical questions about a large text corpus. The authors exemplify the method by addressing the question, ``What percentage of Federal Register documents are real documents, of possible interest to a text researcher or analyst?`` They estimate an answer to this question by evaluating 200 documents selected from a corpus of 45,820 Federal Register documents. Bayesian analysis and stratified sampling are used to reduce the sampling uncertainty of the estimate from over 3,100 documents to fewer than 1,000. A possible application of the method is to establish baseline statistics used to estimate recall rates for information retrieval systems.

  9. Stratified B-trees and versioning dictionaries

    OpenAIRE

    Twigg, Andy; Byde, Andrew; Milos, Grzegorz; Moreton, Tim; Wilkes, John; Wilkie, Tom

    2011-01-01

    A classic versioned data structure in storage and computer science is the copy-on-write (CoW) B-tree -- it underlies many of today's file systems and databases, including WAFL, ZFS, Btrfs and more. Unfortunately, it doesn't inherit the B-tree's optimality properties; it has poor space utilization, cannot offer fast updates, and relies on random IO to scale. Yet, nothing better has been developed since. We describe the `stratified B-tree', which beats all known semi-external memory versioned B...

  10. Salted herring brine as a coating or additive for herring (Clupea harengus) products — A source of natural antioxidants?

    DEFF Research Database (Denmark)

    Albertos, Irene; Gringer, Nina; Rico, Daniel

    2016-01-01

    The objective of this study was to characterise herring brine and assess its use as natural antioxidant in herring preservation. Herring brines from different marinated products (brine from fillet-ripened spice-cured herring SC, traditional barrel-salted spice-cured herring TSp and brine from...

  11. Preliminary design and analysis of recovery of lithium from brine with the use of a selective extractant

    International Nuclear Information System (INIS)

    Dang, V.D.; Steinberg, M.

    1977-05-01

    Lithium requirements for battery and controlled thermonuclear fusion reactor uses in the next few decades may exceed the current availability of the mineral and brine reserves. It is thus prudent to search for new reserves and resources to satisfy these and other lithium applications in the future. It has been reported that the lithium content of Smackover oilfield waters ranges in order of 100--500 mg/l, and thus could represent a substantial reserve. A method is proposed to extract lithium from this source. Experimental evidence in the literature indicates that a specific chelating agent of the diketone type, dipivaloylmethane, has a specific selectivity toward lithium in the presence of other metal ions in aqueous solutions. Based in part on this unique property of dipivaloylmethane, a conceptual design of a full size plant is performed to extract lithium from the Smackover brine. The study includes alternate flow sheet development, design information on the major units of the process, energy requirement and an economic analysis of a 10 6 kg Li/yr production facility. The economics of three different process concepts depends on the amount of water evaporated from the initial oilfield feed waters to concentrate the brine. Results as a function of production rates are indicated in a general manner

  12. Mathematical modeling of turbulent stratified flows. Application of liquid metal fast breeders

    Energy Technology Data Exchange (ETDEWEB)

    Villand, M; Grand, D [CEA-Service des Transferts Thermiques, Grenoble (France)

    1983-07-01

    Mathematical model of turbulent stratified flow was proposed under the following assumptions: Newtonian fluid; incompressible fluid; coupling between temperature and momentum fields according to Boussinesq approximation; two-dimensional invariance for translation or rotation; coordinates cartesian or curvilinear. Solutions obtained by the proposed method are presented.

  13. Soil mixing of stratified contaminated sands.

    Science.gov (United States)

    Al-Tabba, A; Ayotamuno, M J; Martin, R J

    2000-02-01

    Validation of soil mixing for the treatment of contaminated ground is needed in a wide range of site conditions to widen the application of the technology and to understand the mechanisms involved. Since very limited work has been carried out in heterogeneous ground conditions, this paper investigates the effectiveness of soil mixing in stratified sands using laboratory-scale augers. This enabled a low cost investigation of factors such as grout type and form, auger design, installation procedure, mixing mode, curing period, thickness of soil layers and natural moisture content on the unconfined compressive strength, leachability and leachate pH of the soil-grout mixes. The results showed that the auger design plays a very important part in the mixing process in heterogeneous sands. The variability of the properties measured in the stratified soils and the measurable variations caused by the various factors considered, highlighted the importance of duplicating appropriate in situ conditions, the usefulness of laboratory-scale modelling of in situ conditions and the importance of modelling soil and contaminant heterogeneities at the treatability study stage.

  14. Stratified coastal ocean interactions with tropical cyclones

    Science.gov (United States)

    Glenn, S. M.; Miles, T. N.; Seroka, G. N.; Xu, Y.; Forney, R. K.; Yu, F.; Roarty, H.; Schofield, O.; Kohut, J.

    2016-01-01

    Hurricane-intensity forecast improvements currently lag the progress achieved for hurricane tracks. Integrated ocean observations and simulations during hurricane Irene (2011) reveal that the wind-forced two-layer circulation of the stratified coastal ocean, and resultant shear-induced mixing, led to significant and rapid ahead-of-eye-centre cooling (at least 6 °C and up to 11 °C) over a wide swath of the continental shelf. Atmospheric simulations establish this cooling as the missing contribution required to reproduce Irene's accelerated intensity reduction. Historical buoys from 1985 to 2015 show that ahead-of-eye-centre cooling occurred beneath all 11 tropical cyclones that traversed the Mid-Atlantic Bight continental shelf during stratified summer conditions. A Yellow Sea buoy similarly revealed significant and rapid ahead-of-eye-centre cooling during Typhoon Muifa (2011). These findings establish that including realistic coastal baroclinic processes in forecasts of storm intensity and impacts will be increasingly critical to mid-latitude population centres as sea levels rise and tropical cyclone maximum intensities migrate poleward. PMID:26953963

  15. Stratified Simulations of Collisionless Accretion Disks

    Energy Technology Data Exchange (ETDEWEB)

    Hirabayashi, Kota; Hoshino, Masahiro, E-mail: hirabayashi-k@eps.s.u-tokyo.ac.jp [Department of Earth and Planetary Science, The University of Tokyo, Tokyo, 113-0033 (Japan)

    2017-06-10

    This paper presents a series of stratified-shearing-box simulations of collisionless accretion disks in the recently developed framework of kinetic magnetohydrodynamics (MHD), which can handle finite non-gyrotropy of a pressure tensor. Although a fully kinetic simulation predicted a more efficient angular-momentum transport in collisionless disks than in the standard MHD regime, the enhanced transport has not been observed in past kinetic-MHD approaches to gyrotropic pressure anisotropy. For the purpose of investigating this missing link between the fully kinetic and MHD treatments, this paper explores the role of non-gyrotropic pressure and makes the first attempt to incorporate certain collisionless effects into disk-scale, stratified disk simulations. When the timescale of gyrotropization was longer than, or comparable to, the disk-rotation frequency of the orbit, we found that the finite non-gyrotropy selectively remaining in the vicinity of current sheets contributes to suppressing magnetic reconnection in the shearing-box system. This leads to increases both in the saturated amplitude of the MHD turbulence driven by magnetorotational instabilities and in the resultant efficiency of angular-momentum transport. Our results seem to favor the fast advection of magnetic fields toward the rotation axis of a central object, which is required to launch an ultra-relativistic jet from a black hole accretion system in, for example, a magnetically arrested disk state.

  16. Visualization periodic flows in a continuously stratified fluid.

    Science.gov (United States)

    Bardakov, R.; Vasiliev, A.

    2012-04-01

    To visualize the flow pattern of viscous continuously stratified fluid both experimental and computational methods were developed. Computational procedures were based on exact solutions of set of the fundamental equations. Solutions of the problems of flows producing by periodically oscillating disk (linear and torsion oscillations) were visualized with a high resolutions to distinguish small-scale the singular components on the background of strong internal waves. Numerical algorithm of visualization allows to represent both the scalar and vector fields, such as velocity, density, pressure, vorticity, stream function. The size of the source, buoyancy and oscillation frequency, kinematic viscosity of the medium effects were traced in 2D an 3D posing problems. Precision schlieren instrument was used to visualize the flow pattern produced by linear and torsion oscillations of strip and disk in a continuously stratified fluid. Uniform stratification was created by the continuous displacement method. The buoyancy period ranged from 7.5 to 14 s. In the experiments disks with diameters from 9 to 30 cm and a thickness of 1 mm to 10 mm were used. Different schlieren methods that are conventional vertical slit - Foucault knife, vertical slit - filament (Maksoutov's method) and horizontal slit - horizontal grating (natural "rainbow" schlieren method) help to produce supplementing flow patterns. Both internal wave beams and fine flow components were visualized in vicinity and far from the source. Intensity of high gradient envelopes increased proportionally the amplitude of the source. In domains of envelopes convergence isolated small scale vortices and extended mushroom like jets were formed. Experiments have shown that in the case of torsion oscillations pattern of currents is more complicated than in case of forced linear oscillations. Comparison with known theoretical model shows that nonlinear interactions between the regular and singular flow components must be taken

  17. An improved brine shrimp larvae lethality microwell test method.

    Science.gov (United States)

    Zhang, Yi; Mu, Jun; Han, Jinyuan; Gu, Xiaojie

    2012-01-01

    This article described an improved brine shrimp larvae lethality microwell test method. A simply designed connecting vessel with alternative photoperiod was used to culture and collect high yield of active Artemia parthenogenetica nauplii for brine shrimp larvae lethality microwell test. Using this method, pure A. parthenogenetica nauplii suspension was easily cultured and harvested with high density about 100-150 larvae per milliliter and the natural mortality was reduced to near zero by elimination of unnecessary artificial disturbance. And its sensitivity was validated by determination of LC(50)-24 h of different reference toxicants including five antitumor agents, two pesticides, three organic pollutants, and four heavy metals salts, most of which exhibited LC(50)-24 h between 0.07 and 58.43 mg/L except for bleomycin and mitomycin C with LC(50)-24 h over 300 mg/L.

  18. Insertion sequences enrichment in extreme Red sea brine pool vent

    KAUST Repository

    Elbehery, Ali H. A.

    2016-12-03

    Mobile genetic elements are major agents of genome diversification and evolution. Limited studies addressed their characteristics, including abundance, and role in extreme habitats. One of the rare natural habitats exposed to multiple-extreme conditions, including high temperature, salinity and concentration of heavy metals, are the Red Sea brine pools. We assessed the abundance and distribution of different mobile genetic elements in four Red Sea brine pools including the world’s largest known multiple-extreme deep-sea environment, the Red Sea Atlantis II Deep. We report a gradient in the abundance of mobile genetic elements, dramatically increasing in the harshest environment of the pool. Additionally, we identified a strong association between the abundance of insertion sequences and extreme conditions, being highest in the harshest and deepest layer of the Red Sea Atlantis II Deep. Our comparative analyses of mobile genetic elements in secluded, extreme and relatively non-extreme environments, suggest that insertion sequences predominantly contribute to polyextremophiles genome plasticity.

  19. The determination of vanadium in brines by atomic absorption spectroscopy

    Science.gov (United States)

    Crump-Wiesner, Hans J.; Feltz, H.R.; Purdy, W.C.

    1971-01-01

    A standard addition method is described for the determination of vanadium in brines by atomic absorption spectroscopy with a nitrous oxide-acetylene flame. Sample pH is adjusted to 1.0 with concentrated hydrochloric acid and the vanadium is directly extracted with 5% cupferron in methyl isobutyl ketone (MIBK). The ketone layer is then aspirated into the flame and the recorded absorption values are plotted as a function of the concentration of the added metal. As little as 2.5 ??g l-1 of vanadium can be detected under the conditions of the procedure. Tungsten and tin interfere when present in excess of 5 and 10 ??g ml-1, respectively. The concentrations of the two interfering ions normally found in brines are well below interference levels. ?? 1971.

  20. An investigation on the application of ohmic heating of cold water shrimp and brine mixtures

    DEFF Research Database (Denmark)

    Pedersen, Søren Juhl; Feyissa, Aberham Hailu; Brøkner Kavli, Sissel Therese

    2016-01-01

    Cooking is an important unit-operation in the production of cooked and peeled shrimps. The present study explores the feasibility of using ohmic heating for cooking of shrimps. The focus is on investigating the effects of different process parameters on heating time and quality of ohmic cooked...... shrimps (Pandalus Borelias). The shrimps were heated to a core temperature of 72 °C in a brine solution using a small batch ohmic heater. Three experiments were performed: 1) a comparative analyses of the temperature development between different sizes of shrimps and thickness (head and tail region...... of the shrimp) over varying salt concentrations (10 kg m−3 to 20 kg m−3) and electric field strengths (1150 V m−1 to 1725 V m−1) with the heating time as the response; 2) a 2 level factorial experiment for screening the impact of processing conditions using electric field strengths of 1250 V m−1 and 1580 V m−1...

  1. Stratified flows with variable density: mathematical modelling and numerical challenges.

    Science.gov (United States)

    Murillo, Javier; Navas-Montilla, Adrian

    2017-04-01

    Stratified flows appear in a wide variety of fundamental problems in hydrological and geophysical sciences. They may involve from hyperconcentrated floods carrying sediment causing collapse, landslides and debris flows, to suspended material in turbidity currents where turbulence is a key process. Also, in stratified flows variable horizontal density is present. Depending on the case, density varies according to the volumetric concentration of different components or species that can represent transported or suspended materials or soluble substances. Multilayer approaches based on the shallow water equations provide suitable models but are not free from difficulties when moving to the numerical resolution of the governing equations. Considering the variety of temporal and spatial scales, transfer of mass and energy among layers may strongly differ from one case to another. As a consequence, in order to provide accurate solutions, very high order methods of proved quality are demanded. Under these complex scenarios it is necessary to observe that the numerical solution provides the expected order of accuracy but also converges to the physically based solution, which is not an easy task. To this purpose, this work will focus in the use of Energy balanced augmented solvers, in particular, the Augmented Roe Flux ADER scheme. References: J. Murillo , P. García-Navarro, Wave Riemann description of friction terms in unsteady shallow flows: Application to water and mud/debris floods. J. Comput. Phys. 231 (2012) 1963-2001. J. Murillo B. Latorre, P. García-Navarro. A Riemann solver for unsteady computation of 2D shallow flows with variable density. J. Comput. Phys.231 (2012) 4775-4807. A. Navas-Montilla, J. Murillo, Energy balanced numerical schemes with very high order. The Augmented Roe Flux ADER scheme. Application to the shallow water equations, J. Comput. Phys. 290 (2015) 188-218. A. Navas-Montilla, J. Murillo, Asymptotically and exactly energy balanced augmented flux

  2. Inhibition of Weld Corrosion in Flowing Brines Containing Carbon Dioxide

    OpenAIRE

    Alawadhi, Khaled

    2009-01-01

    The aim of this research was to study the effectiveness of a typical oilfield corrosion inhibitor, which is considered to be a green inhibitor (non toxic to the environment) in controlling internal corrosion of welded X65 pipeline steel in brines saturated with carbon dioxide at one bar pressure, under dynamic flowing conditions, over a range of temperatures. Several experimental configurations were used ranging from a simple flat plate design to a novel rotating cylinder electrode, to all...

  3. Uranium, RADON and radon isotopes in selected brines of Poland

    International Nuclear Information System (INIS)

    Kozlowska, B.; Walencik, A.; Zipper, W.; Dorda, J.; Przylibski, T.A.

    2010-01-01

    Natural radioactive isotopes were studied in nine different types of brines from four locations in Poland. Investigated brines are exploited from various geological structures composed of the rocks of different chemical and mineral composition as well as different age and depth. All investigated brines are used in balneotherapy (i.e. baths, inhalations, showers). The main goal of this study was to obtain some basic knowledge on the activity range of natural elements such as uranium, RADON and radon in different brine types in Poland and their variability depending on their location in certain geological structures. Activities of 234,238 U, 226,228 Ra and 222 Rn isotopes were measured with the use of two nuclear spectrometry techniques: liquid scintillation and alpha spectrometry. The activity concentrations of 222 Rn vary from below 1 to 76.1±3.7 Bq/l, for the 226 Ra isotope from 0.19±0.01 to 85.5±0.4 Bq/l and for 228 Ra from below 0.03 to 2.17±0.09 Bq/l. For uranium isotopes, the concentrations are in the range from below 0.5 to 5.1±0.4 mBq/l for 238 U and from 1.6±0.4 to 45.6±2.0 mBq/l for 2 34U . The obtained results indicate high RADON activity concentrations corresponding to high mineralization of waters. (authors)

  4. Effect of different brine concentrations and ripening period on some ...

    African Journals Online (AJOL)

    Cheeses made from pasteurized milk (65°C for 30 min) were ripened in 11, 14 and 17 g 100 ml-1 NaCl for 90 days at 7±1°C. Some physicochemical and biochemical analyses were carried out during storage time. The effects of brine concentrations on total solids, protein, ash, salt, pH, and WSN values were found to be ...

  5. Photocatalytic reduction of nitrate using titanium dioxide for regeneration of ion exchange brine.

    Science.gov (United States)

    Yang, Ting; Doudrick, Kyle; Westerhoff, Paul

    2013-03-01

    Nitrate is often removed from groundwater by ion exchange (IX) before its use as drinking water. Accumulation of nitrate in IX brine reduces the efficiency of IX regeneration and the useful life of the regeneration brine. For the first time, we present a strategy to photocatalytically reduce nitrate in IX brine, thereby extending the use of the brine. Titanium dioxide (Evonik P90), acting as photocatalyst, reduced nitrate effectively in both synthetic brines and sulfate-removed IX brine when formic acid (FA) was used as the hole scavenger (i.e., electron donor) and the initial FA to nitrate molar ratio (IFNR) was 5.6. Increasing the NaCl level in the synthetic brine slowed the nitrate reduction rate without affecting by-product selectivity of ammonium and gaseous N species (e.g., N(2), N(2)O). In a non-modified IX brine, nitrate removal was greatly inhibited owing to the presence of sulfate, which competed with nitrate for active surface sites on P90 and induced aggregation of P90 nanoparticles. After removing sulfate through barium sulfate precipitation, nitrate was effectively reduced; approximately 3.6 × 10(24) photons were required to reduce each mole of nitrate to 83% N Gases and 17% NH(4)(+). To make optimum use of FA and control the residual FA level in treated brine, the IFNR was varied. High IFNRs (e.g., 4, 5.6) were found to be more efficient for nitrate reduction but left higher residual FA in brine. IX column tests were performed to investigate the impact of residual FA for brine reuse. The residual FA in the brine did not significantly affect the nitrate removal capacity of IX resins, and formate contamination of treated water could be eliminated by rinsing with one bed volume of fresh brine. Copyright © 2012 Elsevier Ltd. All rights reserved.

  6. Monte Carlo stratified source-sampling

    International Nuclear Information System (INIS)

    Blomquist, R.N.; Gelbard, E.M.

    1997-01-01

    In 1995, at a conference on criticality safety, a special session was devoted to the Monte Carlo open-quotes eigenvalue of the worldclose quotes problem. Argonne presented a paper, at that session, in which the anomalies originally observed in that problem were reproduced in a much simplified model-problem configuration, and removed by a version of stratified source-sampling. The original test-problem was treated by a special code designed specifically for that purpose. Recently ANL started work on a method for dealing with more realistic eigenvalue of the world configurations, and has been incorporating this method into VIM. The original method has been modified to take into account real-world statistical noise sources not included in the model problem. This paper constitutes a status report on work still in progress

  7. Ecosystem metabolism in a stratified lake

    DEFF Research Database (Denmark)

    Stæhr, Peter Anton; Christensen, Jesper Philip Aagaard; Batt, Ryan D.

    2012-01-01

    , differences were not significant. During stratification, daily variability in epilimnetic DO was dominated by metabolism (46%) and air-water gas exchange (44%). Fluxes related to mixed-layer deepening dominated in meta- and hypolimnic waters (49% and 64%), while eddy diffusion (1% and 14%) was less important....... Although air-water gas exchange rates differed among the three formulations of gas-transfer velocity, this had no significant effect on metabolic rates....... that integrates rates across the entire depth profile and includes DO exchange between depth layers driven by mixed-layer deepening and eddy diffusivity. During full mixing, NEP was close to zero throughout the water column, and GPP and R were reduced 2-10 times compared to stratified periods. When present...

  8. Stratified growth in Pseudomonas aeruginosa biofilms

    DEFF Research Database (Denmark)

    Werner, E.; Roe, F.; Bugnicourt, A.

    2004-01-01

    In this study, stratified patterns of protein synthesis and growth were demonstrated in Pseudomonas aeruginosa biofilms. Spatial patterns of protein synthetic activity inside biofilms were characterized by the use of two green fluorescent protein (GFP) reporter gene constructs. One construct...... synthesis was restricted to a narrow band in the part of the biofilm adjacent to the source of oxygen. The zone of active GFP expression was approximately 60 Am wide in colony biofilms and 30 Am wide in flow cell biofilms. The region of the biofilm in which cells were capable of elongation was mapped...... by treating colony biofilms with carbenicillin, which blocks cell division, and then measuring individual cell lengths by transmission electron microscopy. Cell elongation was localized at the air interface of the biofilm. The heterogeneous anabolic patterns measured inside these biofilms were likely a result...

  9. Thermal instability in a stratified plasma

    International Nuclear Information System (INIS)

    Hermanns, D.F.M.; Priest, E.R.

    1989-01-01

    The thermal instability mechansism has been studied in connection to observed coronal features, like, e.g. prominences or cool cores in loops. Although these features show a lot of structure, most studies concern the thermal instability in an uniform medium. In this paper, we investigate the thermal instability and the interaction between thermal modes and the slow magneto-acoustic subspectrum for a stratified plasma slab. We fomulate the relevant system of equations and give some straightforward properties of the linear spectrum of a non-uniform plasma slab, i.e. the existence of continuous parts in the spectrum. We present a numerical scheme with which we can investigate the linear spectrum for equilibrium states with stratification. The slow and thermal subspectra of a crude coronal model are given as a preliminary result. (author). 6 refs.; 1 fig

  10. Design of Tomato Drying System by Utilizing Brine Geothermal

    Science.gov (United States)

    Afuar, W.; Sibarani, B.; Abdurrahman, G.; Hendrarsakti, J.

    2016-09-01

    Cultivation of tomato plants in Indonesia has been started since 1961.Tomatoes generally will rot in three days if left on storage. Moreover, low quality tomatoes have cheaper price. After harvested, tomatoes need to be treated by drying process so it can last longer. Energy for drying tomatoes can be obtained by utilizing heat from geothermal brine. Purpose of this research is to design a tomato drying system by extracting heat of geothermal brine from separator with certain flow rate to heat up water by using a heat exchanger. Furthermore, this water will be used to heat up the surrounding air which is circulated by blower system to heat up the tomatoes chamber. Tomatoes drying process needs temperature range of 50-70°C to evaporate water content from 95.7% to 26%. After that treatment, the tomatoes are expected to have better durability. The objective of this study is to determine the quantity of hot brine which is needed for drying tomatoes and to design a drying system so that tomatoes can last longer.

  11. Reverse osmosis brine for phosphorus recovery from source separated urine.

    Science.gov (United States)

    Tian, Xiujun; Wang, Guotian; Guan, Detian; Li, Jiuyi; Wang, Aimin; Li, Jin; Yu, Zhe; Chen, Yong; Zhang, Zhongguo

    2016-12-01

    Phosphorus (P) recovery from waste streams has recently been recognized as a key step in the sustainable supply of this indispensable and non-renewable resource. The feasibility of using brine from a reverse osmosis (RO) membrane unit treating cooling water as a precipitant for P recovery from source separated urine was evaluated in the present study. P removal efficiency, process parameters and precipitate properties were investigated in batch and continuous flow experiments. More than 90% of P removal was obtained from both undiluted fresh and hydrolyzed urines by mixing with RO brine (1:1, v/v) at a pH over 9.0. Around 2.58 and 1.24 Kg of precipitates could be recovered from 1 m 3 hydrolyzed and fresh urine, respectively, and the precipitated solids contain 8.1-19.0% of P, 10.3-15.2% of Ca, 3.7-5.0% of Mg and 0.1-3.5% of ammonium nitrogen. Satisfactory P removal performance was also achieved in a continuous flow precipitation reactor with a hydraulic retention time of 3-6 h. RO brine could be considered as urinal and toilet flush water despite of a marginally higher precipitation tendency than tap water. This study provides a widely available, low - cost and efficient precipitant for P recovery in urban areas, which will make P recovery from urine more economically attractive. Copyright © 2016 Elsevier Ltd. All rights reserved.

  12. Certain questions about analysis of natural gas disolved in brine

    Energy Technology Data Exchange (ETDEWEB)

    Tezuka, M; Nakamura, M; Omi, K

    1983-01-01

    The composition of the gaseous phase of stratum brines is determined and the analysis technique is described. Ordinary analysis is performed with the assumptions that the contents of small components (excluding C02 and N2) are ignorably small and that the gas contains no 02. The determined concentrations of 02 and the proportional share of N2 are calculated from results of analysis as bound with pollutants. The high sensitivity of modern analytical methods makes it possible to identify quite small and trace concentrations of components, but corrections for air contamination may partially depreciate these results. Data are cited from gas chromatographic identifications of the components of gases disolved in the stratum brines of a Japanese deposit. C2H6 is established in all samples and C3H8 in two thirds of the samples, where H2 and helium were not detected anywhere. The concentrations of the gas phase on the whole in the brine were low. 02 falls into the samples in a water dissolved state; this demands the use of unconventional proportion of 02 to N2 (1 to 3.55), which is characteristic for air and a proportion of 1 to 2 which is characteristic for disolved air. With the conventional ordinary technique the consideration of the air contamination leads to a substantial underestimate of the N2 results. At the same time, the incorrect introduction of corrections for N2 has no effect on the heat creativity of the disolved gas.

  13. Brine migration test - Asse salt mine, Federal Republic of Germany

    International Nuclear Information System (INIS)

    Rothfuchs, T.; Wieczorek, K.; Feddersen, H.K.; Staupendahl, G.; Coyle, A.J.; Kalia, H.; Eckert, J.

    1988-03-01

    This document is the final report on the Cooperative German-American 'Brine Migration Tests' that were performed at the Asse Salt Mine in the Federal Republic of Germany (FRG), the Office of Nuclear Waste Isolation (ONWI), Columbus, Ohio, and the Institut fuer Tieflagerung (IfT), Braunschweig, of the Gesellschaft fuer Strahlen- und Umweltforschung mbH Muenchen (GSF). Final test and equipment design as well as manufacturing and installation was carried out by Westinghouse Electric Corporation. The tests were designed to simulate a nuclear waste repository to measure the effects of heat and gamma radiation on brine migration, salt decrepitation, disassociation of brine, and gases collected. The thermal mechanical behavior of salt, such as room closure, stresses and changes of the properties of salt are measured and compared with predicted behavior. The performance of an array of candidate waste package materials, test equipment and procedures under repository conditions will be evaluated with a view towards future in-depth testing of potential repository sites. (orig./RB)

  14. Fluid inclusion brine compositions from Palo Duro Basin salt sites

    International Nuclear Information System (INIS)

    Moody, J.B.

    1987-01-01

    The fluid inclusion analyses were done on salt samples from Lower San Andres Cycle 4 and 5. The stable isotope composition of the fluid inclusion brines was measured on duplicate samples taken from the same fluid inclusion brine for correlation of geochemical content with the stable isotopic content. The analyzed Palo Duro Basin salt fluid inclusions are predominantly one phase, i.e., the presence of a fluid only. However, many of the larger fluid inclusions do have a small vapor bubble. This liquid/vapor ratio is so high in these vapor-containing fluid inclusions that their behavior in a thermal gradient would be almost identical to that of all liquid inclusions. Closely associated with the fluid inclusions are cryptomelane where some fibers penetrate into halite host crystal. The fluid inclusions have a wide variability in content for those components that were analyzed, even within the same salt type. The fluid inclusion brines are also acidic, ranging from 3 to 6 as measured with pH test papers

  15. CO2/Brine transport into shallow aquifers along fault zones.

    Science.gov (United States)

    Keating, Elizabeth H; Newell, Dennis L; Viswanathan, Hari; Carey, J W; Zyvoloski, G; Pawar, Rajesh

    2013-01-02

    Unintended release of CO(2) from carbon sequestration reservoirs poses a well-recognized risk to groundwater quality. Research has largely focused on in situ CO(2)-induced pH depression and subsequent trace metal mobilization. In this paper we focus on a second mechanism: upward intrusion of displaced brine or brackish-water into a shallow aquifer as a result of CO(2) injection. Studies of two natural analog sites provide insights into physical and chemical mechanisms controlling both brackish water and CO(2) intrusion into shallow aquifers along fault zones. At the Chimayó, New Mexico site, shallow groundwater near the fault is enriched in CO(2) and, in some places, salinity is significantly elevated. In contrast, at the Springerville, Arizona site CO(2) is leaking upward through brine aquifers but does not appear to be increasing salinity in the shallow aquifer. Using multiphase transport simulations we show conditions under which significant CO(2) can be transported through deep brine aquifers into shallow layers. Only a subset of these conditions favor entrainment of salinity into the shallow aquifer: high aspect-ratio leakage pathways and viscous coupling between the fluid phases. Recognition of the conditions under which salinity is favored to be cotransported with CO(2) into shallow aquifers will be important in environmental risk assessments.

  16. Information content of household-stratified epidemics

    Directory of Open Access Journals (Sweden)

    T.M. Kinyanjui

    2016-09-01

    Full Text Available Household structure is a key driver of many infectious diseases, as well as a natural target for interventions such as vaccination programs. Many theoretical and conceptual advances on household-stratified epidemic models are relatively recent, but have successfully managed to increase the applicability of such models to practical problems. To be of maximum realism and hence benefit, they require parameterisation from epidemiological data, and while household-stratified final size data has been the traditional source, increasingly time-series infection data from households are becoming available. This paper is concerned with the design of studies aimed at collecting time-series epidemic data in order to maximize the amount of information available to calibrate household models. A design decision involves a trade-off between the number of households to enrol and the sampling frequency. Two commonly used epidemiological study designs are considered: cross-sectional, where different households are sampled at every time point, and cohort, where the same households are followed over the course of the study period. The search for an optimal design uses Bayesian computationally intensive methods to explore the joint parameter-design space combined with the Shannon entropy of the posteriors to estimate the amount of information in each design. For the cross-sectional design, the amount of information increases with the sampling intensity, i.e., the designs with the highest number of time points have the most information. On the other hand, the cohort design often exhibits a trade-off between the number of households sampled and the intensity of follow-up. Our results broadly support the choices made in existing epidemiological data collection studies. Prospective problem-specific use of our computational methods can bring significant benefits in guiding future study designs.

  17. Information content of household-stratified epidemics.

    Science.gov (United States)

    Kinyanjui, T M; Pellis, L; House, T

    2016-09-01

    Household structure is a key driver of many infectious diseases, as well as a natural target for interventions such as vaccination programs. Many theoretical and conceptual advances on household-stratified epidemic models are relatively recent, but have successfully managed to increase the applicability of such models to practical problems. To be of maximum realism and hence benefit, they require parameterisation from epidemiological data, and while household-stratified final size data has been the traditional source, increasingly time-series infection data from households are becoming available. This paper is concerned with the design of studies aimed at collecting time-series epidemic data in order to maximize the amount of information available to calibrate household models. A design decision involves a trade-off between the number of households to enrol and the sampling frequency. Two commonly used epidemiological study designs are considered: cross-sectional, where different households are sampled at every time point, and cohort, where the same households are followed over the course of the study period. The search for an optimal design uses Bayesian computationally intensive methods to explore the joint parameter-design space combined with the Shannon entropy of the posteriors to estimate the amount of information in each design. For the cross-sectional design, the amount of information increases with the sampling intensity, i.e., the designs with the highest number of time points have the most information. On the other hand, the cohort design often exhibits a trade-off between the number of households sampled and the intensity of follow-up. Our results broadly support the choices made in existing epidemiological data collection studies. Prospective problem-specific use of our computational methods can bring significant benefits in guiding future study designs. Copyright © 2016 The Authors. Published by Elsevier B.V. All rights reserved.

  18. Stratified sampling design based on data mining.

    Science.gov (United States)

    Kim, Yeonkook J; Oh, Yoonhwan; Park, Sunghoon; Cho, Sungzoon; Park, Hayoung

    2013-09-01

    To explore classification rules based on data mining methodologies which are to be used in defining strata in stratified sampling of healthcare providers with improved sampling efficiency. We performed k-means clustering to group providers with similar characteristics, then, constructed decision trees on cluster labels to generate stratification rules. We assessed the variance explained by the stratification proposed in this study and by conventional stratification to evaluate the performance of the sampling design. We constructed a study database from health insurance claims data and providers' profile data made available to this study by the Health Insurance Review and Assessment Service of South Korea, and population data from Statistics Korea. From our database, we used the data for single specialty clinics or hospitals in two specialties, general surgery and ophthalmology, for the year 2011 in this study. Data mining resulted in five strata in general surgery with two stratification variables, the number of inpatients per specialist and population density of provider location, and five strata in ophthalmology with two stratification variables, the number of inpatients per specialist and number of beds. The percentages of variance in annual changes in the productivity of specialists explained by the stratification in general surgery and ophthalmology were 22% and 8%, respectively, whereas conventional stratification by the type of provider location and number of beds explained 2% and 0.2% of variance, respectively. This study demonstrated that data mining methods can be used in designing efficient stratified sampling with variables readily available to the insurer and government; it offers an alternative to the existing stratification method that is widely used in healthcare provider surveys in South Korea.

  19. Stratified charge rotary engine combustion studies

    Science.gov (United States)

    Shock, H.; Hamady, F.; Somerton, C.; Stuecken, T.; Chouinard, E.; Rachal, T.; Kosterman, J.; Lambeth, M.; Olbrich, C.

    1989-07-01

    Analytical and experimental studies of the combustion process in a stratified charge rotary engine (SCRE) continue to be the subject of active research in recent years. Specifically to meet the demand for more sophisticated products, a detailed understanding of the engine system of interest is warranted. With this in mind the objective of this work is to develop an understanding of the controlling factors that affect the SCRE combustion process so that an efficient power dense rotary engine can be designed. The influence of the induction-exhaust systems and the rotor geometry are believed to have a significant effect on combustion chamber flow characteristics. In this report, emphasis is centered on Laser Doppler Velocimetry (LDV) measurements and on qualitative flow visualizations in the combustion chamber of the motored rotary engine assembly. This will provide a basic understanding of the flow process in the RCE and serve as a data base for verification of numerical simulations. Understanding fuel injection provisions is also important to the successful operation of the stratified charge rotary engine. Toward this end, flow visualizations depicting the development of high speed, high pressure fuel jets are described. Friction is an important consideration in an engine from the standpoint of lost work, durability and reliability. MSU Engine Research Laboratory efforts in accessing the frictional losses associated with the rotary engine are described. This includes work which describes losses in bearing, seal and auxillary components. Finally, a computer controlled mapping system under development is described. This system can be used to map shapes such as combustion chamber, intake manifolds or turbine blades accurately.

  20. Lithium- and boron-bearing brines in the Central Andes: exploring hydrofacies on the eastern Puna plateau between 23° and 23°30'S

    Science.gov (United States)

    Steinmetz, R. L. López

    2017-01-01

    Internally drained basins of the Andean Plateau are lithium- and boron-bearing systems. The exploration of ionic facies and parental links in a playa lake located in the eastern Puna (23°-23°30'S) was assessed by hydrochemical determinations of residual brines, feed waters and solutions from weathered rocks. Residual brines have been characterized by the Cl- (SO4 =)/Na+ (K+) ratio. Residual brines from the playa lake contain up to 450 mg/l of boron and up to 125 mg/l of lithium, and the Las Burras River supplies the most concentrated boron (20 mg/l) and lithium (3.75 mg/l) inflows of the basin. The hydro-geochemical assessment allowed for the identification of three simultaneous sources of boron: (1) inflow originating from granitic areas of the Aguilar and Tusaquillas ranges; (2) weathering of the Ordovician basement; and (3) boron-rich water from the Las Burras River. Most of the lithium input of the basin is likely generated by present geothermal sources rather than by weathering and leaching of ignimbrites and plutonic rocks. However, XRD analyses of playa lake sediments revealed the presence of lithian micas of clastic origin, including taeniolite and eucriptite. This study is the first to document these rare Li-micas from the Puna basin. Thus, both residual brines and lithian micas contribute to the total Li content in the studied hydrologic system.

  1. Comparison of Four Strong Acids on the Precipitation Potential of Gypsum in Brines During Distillation of Pretreated, Augmented Urine

    Science.gov (United States)

    Muirhead, Dean; Carrier, Christopher

    2012-01-01

    In this study, three different mineral acids were substituted for sulfuric acid (H2SO4) in the urine stabilizer solution to eliminate the excess of sulfate ions in pretreated urine and assess the impact on maximum water recovery to avoid precipitation of minerals during distillation. The study evaluated replacing 98% sulfuric acid with 85% phosphoric acid (H3PO4), 37% hydrochloric acid (HCl), or 70% nitric acid (HNO3). The effect of lowering the oxidizer concentration in the pretreatment formulation also was studied. This paper summarizes the test results, defines candidate formulations for further study, and specifies the injection masses required to stabilize urine and minimize the risk of mineral precipitation during distillation. In the first test with a brine ersatz acidified with different acids, the solubility of calcium in gypsum saturated solutions was measured. The solubility of gypsum was doubled in the brines acidified with the alternative acids compared to sulfuric acid. In a second series of tests, the alternative acid pretreatment concentrations were effective at preventing precipitation of gypsum and other minerals up to 85% water recovery from 95th-percentile pretreated, augmented urine. Based on test results, phosphoric acid is recommended as the safest alternative to sulfuric acid. It also is recommended that the injected mass concentration of chromium trioxide solution be reduced by 75% to minimize liquid resupply mass by about 50%, reduce toxicity of brines, and reduce the concentration of organic acids in distillate. The new stabilizer solution formulations and required doses to stabilize urine and prevent precipitation of minerals up to 85% water recovery are given. The formulations in this study were tested on a limited number of artificially augmented urine batches collected from employees at the Johnson Space Center (JSC). This study successfully demonstrated that the desired physical and chemical stability of pretreated urine and brines

  2. Scattering by multiple parallel radially stratified infinite cylinders buried in a lossy half space.

    Science.gov (United States)

    Lee, Siu-Chun

    2013-07-01

    The theoretical solution for scattering by an arbitrary configuration of closely spaced parallel infinite cylinders buried in a lossy half space is presented in this paper. The refractive index and permeability of the half space and cylinders are complex in general. Each cylinder is radially stratified with a distinct complex refractive index and permeability. The incident radiation is an arbitrarily polarized plane wave propagating in the plane normal to the axes of the cylinders. Analytic solutions are derived for the electric and magnetic fields and the Poynting vector of backscattered radiation emerging from the half space. Numerical examples are presented to illustrate the application of the scattering solution to calculate backscattering from a lossy half space containing multiple homogeneous and radially stratified cylinders at various depths and different angles of incidence.

  3. Microbial changes and growth of Listeria monocytogenes during chilled storage of brined shrimp ( Pandalus borealis )

    DEFF Research Database (Denmark)

    Mejlholm, Ole; Kjeldgaard, J.; Modberg, A.

    2008-01-01

    Thirteen storage trials and ten challenge tests were carried out to examine microbial changes, spoilage and the potential growth of Listeria monocytogenes in brined shrimp (Pandalus borealis). Shrimp in brine as well as brined and drained shrimp in modified atmosphere packaging (MAP) were produced...... and lactic acids were studied. Furthermore, the effect of adding diacetate to brined shrimp was evaluated. A single batch of cooked and peeled shrimp was used to study both industrially and manually processed brined shrimp with respect to the effect of process hygiene on microbial changes and the shelf life...... of products. Concentrations of microorganisms on newly produced brined shrimp from an industrial scale processing line were 1.0-2.3 log (CFU g(-1)) higher than comparable concentrations in manually processed samples. This resulted in a substantially shorter shelf life and a more diverse spoilage microflora...

  4. Pressurized brines in continental Antarctica as a possible analogue of Mars.

    Science.gov (United States)

    Forte, Emanuele; Dalle Fratte, Michele; Azzaro, Maurizio; Guglielmin, Mauro

    2016-09-12

    Interest in brines in extreme and cold environments has recently increased after they have been found on Mars. Those brines can be potential new subsurface habitats for peculiar ecosystems. In the McMurdo Dry Valleys of the Antarctic, the best analogue for Mars conditions, only a few cases of brines have been identified in some perennially frozen lakes and in one case in an underground aquifer. Here, we present the occurrence of pressurized brines in a shallow perennially ice-covered lake south of 70°S in an ice-free area of Victoria Land, Antarctica. For the first time, we also imaged, by means of ground penetrating radar data, the existence of a pingo-like-feature (PLF) formed by the extrusion of brines, which has also been confirmed by borehole evidence. Those brines are fed by an underground talik external to the lake basin, enhancing the possibility of unexploited ecosystems that could find an analogue in Martian environments.

  5. The technology of uranium extraction from the brine with high chlorine-ion content

    International Nuclear Information System (INIS)

    Khakimov, N.; Nazarov, Kh.M.; Mirsaidov, I.U.; Negmatov, Sh.I.; Barotov, B.B.

    2010-01-01

    Present article is devoted to technology of uranium extraction from the brine with high chlorine-ion content. The research results on uranium extraction from the brine of Sasik-Kul Lake by means of sorption method were considered. The chemical composition of salt was determined. The process of uranium sorption was described and analyzed. The technology of uranium extraction from the brine with high chlorine-ion content was proposed.

  6. Solution properties of hydrophobically modified

    Directory of Open Access Journals (Sweden)

    A.M. Al-Sabagh

    2016-12-01

    Full Text Available We tested nine hydrophobically modified polyacrylamides with molecular weights situated between 1.58 and 0.89 × 106 g/mol for enhanced oil recovery applications. Their solution properties were investigated in the distilled water, brine solution, formation water and sea water. Their critical association concentrations were determined from the relationship between their concentrations and the corresponding apparent viscosities (ηapp at 30 °C at shear rate 6 s−1. They were between 0.4 and 0.5 g/dl. The brine solutions of 0.5 g/dl of HM-PAMs were investigated at different conditions regarding their apparent viscosities. Such conditions were mono and divalent cations, temperature ranging from 30 to 90 °C, the shear rate ranging from 6 to 30 s−1 and the aging time for 45 days. The surface and interfacial tensions for the HM-PAMs were measured for concentration range from 0.01 to 1 g/dl brine solutions at 30 °C and their emulsification efficiencies were investigated for 7 days. The discrepancy in the properties and efficiencies of the tested copolymers was discussed in the light of their chemical structure.

  7. The effect of surfactant on stratified and stratifying gas-liquid flows

    Science.gov (United States)

    Heiles, Baptiste; Zadrazil, Ivan; Matar, Omar

    2013-11-01

    We consider the dynamics of a stratified/stratifying gas-liquid flow in horizontal tubes. This flow regime is characterised by the thin liquid films that drain under gravity along the pipe interior, forming a pool at the bottom of the tube, and the formation of large-amplitude waves at the gas-liquid interface. This regime is also accompanied by the detachment of droplets from the interface and their entrainment into the gas phase. We carry out an experimental study involving axial- and radial-view photography of the flow, in the presence and absence of surfactant. We show that the effect of surfactant is to reduce significantly the average diameter of the entrained droplets, through a tip-streaming mechanism. We also highlight the influence of surfactant on the characteristics of the interfacial waves, and the pressure gradient that drives the flow. EPSRC Programme Grant EP/K003976/1.

  8. Effect of sodium bicarbonate and varying concentrations of sodium chloride in brine on the liquid retention of fish (Pollachius virens L.) muscle.

    Science.gov (United States)

    Åsli, Magnus; Ofstad, Ragni; Böcker, Ulrike; Jessen, Flemming; Einen, Olai; Mørkøre, Turid

    2016-03-15

    Negative health effects associated with excessive sodium (Na) intake have increased the demand for tasty low-Na products (<2% NaCl) rather than traditional heavily salted fish products (∼20% NaCl). This study investigates the causes of improved yield and liquid retention of fish muscle brined with a combination of salt (NaCl) and sodium bicarbonate (NaHCO3 ). Water characteristics and microstructure of saithe (Pollachius virens L.) muscle brined in solutions of NaCl and NaHCO3 or NaCl alone were compared using low-field nuclear magnetic resonance (LF-NMR) T2 relaxometry, microscopy, salt content, liquid retention and colorimetric measurements. Saithe muscle was brined for 92 h in 0, 30, 60, 120 or 240 g kg(-1) NaCl or the respective solutions with added 7.5 g kg(-1) NaHCO3 . NaHCO3 inclusion improved the yield in solutions ranging from 0 to 120 g kg(-1) NaCl, with the most pronounced effect being observed at 30 g kg(-1) NaCl. The changes in yield were reflected in water mobility, with significantly shorter T2 relaxation times in all corresponding brine concentrations. Salt-dependent microstructural changes were revealed by light microscopy, where NaHCO3 supplementation resulted in greater intracellular space at 30 and 60 g kg(-1) NaCl. Sodium bicarbonate addition to low-salt solutions can improve yield and flesh quality of fish muscle owing to altered water mobility and wider space between the muscle cells. © 2015 Society of Chemical Industry.

  9. Pressurized brines in continental Antarctica as a possible analogue of Mars

    OpenAIRE

    Forte, Emanuele; Dalle Fratte, Michele; Azzaro, Maurizio; Guglielmin, Mauro

    2016-01-01

    Interest in brines in extreme and cold environments has recently increased after they have been found on Mars. Those brines can be potential new subsurface habitats for peculiar ecosystems. In the McMurdo Dry Valleys of the Antarctic, the best analogue for Mars conditions, only a few cases of brines have been identified in some perennially frozen lakes and in one case in an underground aquifer. Here, we present the occurrence of pressurized brines in a shallow perennially ice-covered lake sou...

  10. Strontium isotope evidence on the history of oilfield brines, Mediterranean Coastal Plain, Israel

    International Nuclear Information System (INIS)

    Starinsky, A.; Bielski, M.; Lazar, B.; Steinitz, G.; Raab, M.

    1983-01-01

    The isotopic composition of Sr in oil field brines from the Mediterranean Coastal Plain was determined in 18 drillholes. The brines are characterized by salinities ranging from 35 to 93 g/l (TDS), Sr from 28 to 350 mg/l, Sr/Ca molar ratios from 0.011 to 0.053 and 87 Sr/ 86 Sr ratios from 0.7075 to 0.7090. E and A = 0.7081 +- 0.0004 (2σ). The brines are classified into two groups: (a) Mavqi'im group - brines with relatively high 87 Sr/ 86 Sr ratios, sampled from clastics, dolomites and anhydrites of Upper Miocene age. (b) Heletz group - brines with relatively low 87 Sr/ 86 Sr ratios, sampled from sandstones and dolomites of Lower Cretaceous age. Equations were derived to show the relations between 87 Sr/ 86 Sr ratio of the brines and the processes through which they evolved. It is suggested that both groups of brines originated from Mediterranean evaporated seawater during the Messinian desiccation. The strontium isotope composition of the seawater is reflected in that of both groups of brines, the Mavqi'im group containing the original 87 Sr/ 86 Sr ratio. The Heletz group evolved later on, through exchange reactions of those primary brines with a carbonate sequence of Cretaceous age and consequently new 87 Sr/ 86 Sr ratios could have been developed. (author)

  11. Brine migrations in the Athabasca Basin platform, alteration and associated fluid-rock exchanges

    International Nuclear Information System (INIS)

    Mercadier, J.; Cathelineau, M.; Richard, A.; Boiron, M.Ch.; Cuney, M.; Milesi, J.P.

    2009-01-01

    Uranium deposits of Athabasca Basin (Saskatchewan, Canada) are considered as the richest in the world. They result from massive percolation of basin brines in the underlying platform. The authors describe the brine movements and how structures and micro-fractures promoted this percolation until very important depths (hundreds of meters under the discordance), and their chemical modifications as they interacted with platform rocks, thus promoting the transformation of an initially sodic brine into a uranium-enriched calcic brine which is essential to the formation of discordance-type deposit

  12. Improved patient selection by stratified surgical intervention

    DEFF Research Database (Denmark)

    Wang, Miao; Bünger, Cody E; Li, Haisheng

    2015-01-01

    BACKGROUND CONTEXT: Choosing the best surgical treatment for patients with spinal metastases remains a significant challenge for spine surgeons. There is currently no gold standard for surgical treatments. The Aarhus Spinal Metastases Algorithm (ASMA) was established to help surgeons choose...... the most appropriate surgical intervention for patients with spinal metastases. PURPOSE: The purpose of this study was to evaluate the clinical outcome of stratified surgical interventions based on the ASMA, which combines life expectancy and the anatomical classification of patients with spinal metastases...... survival times in the five surgical groups determined by the ASMA were 2.1 (TS 0-4, TC 1-7), 5.1 (TS 5-8, TC 1-7), 12.1 (TS 9-11, TC 1-7 or TS 12-15, TC 7), 26.0 (TS 12-15, TC 4-6), and 36.0 (TS 12-15, TC 1-3) months. The 30-day mortality rate was 7.5%. Postoperative neurological function was maintained...

  13. Experimental study of unsteady thermally stratified flow

    International Nuclear Information System (INIS)

    Lee, Sang Jun; Chung, Myung Kyoon

    1985-01-01

    Unsteady thermally stratified flow caused by two-dimensional surface discharge of warm water into a oblong channel was investigated. Experimental study was focused on the rapidly developing thermal diffusion at small Richardson number. The basic objectives were to study the interfacial mixing between a flowing layer of warm water and an underlying body of cold water and to accumulate experimental data to test computational turbulence models. Mean velocity field measurements were carried out by using NMR-CT(Nuclear Magnetic Resonance-Computerized Tomography). It detects quantitative flow image of any desired section in any direction of flow in short time. Results show that at small Richardson number warm layer rapidly penetrates into the cold layer because of strong turbulent mixing and instability between the two layers. It is found that the transfer of heat across the interface is more vigorous than that of momentum. It is also proved that the NMR-CT technique is a very valuable tool to measure unsteady three dimensional flow field. (Author)

  14. Classification of archaeologically stratified pumice by INAA

    International Nuclear Information System (INIS)

    Peltz, C.; Bichler, M.

    2001-01-01

    In the framework of the research program 'Synchronization of Civilization in the Eastern Mediterranean Region in the 2nd Millenium B.C.' instrumental neutron activation analysis (INAA) was used to determine 30 elements in pumice from archaeological excavations to reveal their specific volcanic origin. The widespread pumiceous products of several eruptions in the Aegean region were used as abrasive tools and were therefore popular trade objects. A remarkable quantity of pumice and pumiceous tephra (several km 3 ) was produced by the 'Minoan eruption' of Thera (Santorini), which is assumed to have happened between 1450 and 1650 B.C. Thus the discovery of the primary fallout of 'Minoan' tephra in archaeologically stratified locations can be used as a relative time mark. Additionally, pumice lumps used as abrasive can serve for dating by first appearance. Essential to an identification of the primary volcanic source is the knowledge that pumices from the Aegean region can easily be distinguished by their trace element distribution patterns, as previous work has shown. The elements Al, Ba, Ca, Ce, Co, Cr, Cs, Dy, Eu, Fe, Hf, K, La, Lu, Mn, Na, Nd, Rb, Sb, Sc, Sm, Ta, Tb, Th, Ti, U, V, Yb, Zn and Zr were determined in 16 samples of pumice lumps from excavations in Tell-el-Dab'a and Tell-el-Herr (Egypt). Two irradiation cycles and five measurement runs were applied. A reliable identification of the samples is achieved by comparing these results to the database compiled in previous studies. (author)

  15. Freezing of perchlorate and chloride brines under Mars-relevant conditions

    Science.gov (United States)

    Primm, K. M.; Gough, R. V.; Chevrier, V. F.; Tolbert, M. A.

    2017-09-01

    Perchlorate and chloride salts on Mars could readily absorb water vapor and deliquesce into aqueous solutions. The deliquescence relative humidity (RH) as well as the efflorescence (recrystallization) RH of several Mars-relevant salts are now well known; however, the conditions that could cause a brine to freeze are not well established. It is often assumed that ice formation will occur whenever the saturation with respect to ice, Sice, of the system is greater than or equal to unity; however, ice nucleation is often hindered due to a kinetic barrier. For ice to form, a critical cluster of the ice crystal must first be achieved, often requiring Sice > 1. Here we use a Raman microscope and an environmental cell to examine the RH and temperature conditions required for Mg(ClO4)2 and MgCl2 brines to freeze into ice. By examining the salt phase present both optically and spectrally under different low temperature conditions, it is found that both salts exhibit Sice values much greater than unity, meaning that supersaturation readily occurs and brines can persist under conditions previously thought to lead to freezing. The RH range of ice formation for Mg(ClO4)2 from 218 to 245 K is 83-95%, respectively, corresponding to Sice = 1.30-1.54. The RH of ice formation for MgCl2 ranges from 80 to 100% for temperatures between 221 and 252 K, corresponding to Sice = 1.30-1.35. In addition to ice nucleation, the deliquescence and efflorescence relative humidity values for MgCl2 were determined. Two hydrates for MgCl2 were observed, and exhibited different deliquescence relative humidity (DRH) values. The DRH for MgCl2·4H2O was found to be 12.8 ± 0.3% at 243 K with slightly increasing DRH as temperature decreased. The DRH for MgCl2·6H2O was found to be 31.3 ± 0.6% at 242 K with little temperature dependence. The DRH of MgCl2·6H2O was measured below the previously reported eutectic, 240 K, suggesting that the eutectic might be incorrect or that there is a different relevant

  16. Analysis of Turbulent Combustion in Simplified Stratified Charge Conditions

    Science.gov (United States)

    Moriyoshi, Yasuo; Morikawa, Hideaki; Komatsu, Eiji

    The stratified charge combustion system has been widely studied due to the significant potentials for low fuel consumption rate and low exhaust gas emissions. The fuel-air mixture formation process in a direct-injection stratified charge engine is influenced by various parameters, such as atomization, evaporation, and in-cylinder gas motion at high temperature and high pressure conditions. It is difficult to observe the in-cylinder phenomena in such conditions and also challenging to analyze the following stratified charge combustion. Therefore, the combustion phenomena in simplified stratified charge conditions aiming to analyze the fundamental stratified charge combustion are examined. That is, an experimental apparatus which can control the mixture distribution and the gas motion at ignition timing was developed, and the effects of turbulence intensity, mixture concentration distribution, and mixture composition on stratified charge combustion were examined. As a result, the effects of fuel, charge stratification, and turbulence on combustion characteristics were clarified.

  17. A study of stratified gas-liquid pipe flow

    Energy Technology Data Exchange (ETDEWEB)

    Johnson, George W.

    2005-07-01

    liquid accumulation in large gas condensate pipelines. Reducing the prediction uncertainties can lead to more optimal pipeline dimensioning, thus potentially reducing both costs and technical risks. The chapters may be summarized by the following. 1) Outlines the stratified two-fluid model in pipes which provides a basis for the theoretical models of this work. Assumptions and simplifications which result in the model equations are presented. Some relationships which were used to analyze the experimental data are also presented. 2) Discusses theoretical models and experimental investigations from the literature involving stratified flow inducts. 3) Presents a new mathematical model for stratified flow in inclined pipes which allow predictive discontinuous and continuous roll wave solutions. 4) Describes the facility used for the experimental work and data reduction methods. 5) Presents experimental results from horizontal and inclined two-phase pipe flow at 8 bara. 6) Compares model predictions with experimental observations. 7) Summarizes the ability of the models to predict the observational data and suggest further improvements. Draws conclusions about the ability of the models to predict observed quantities. (Author)

  18. Extraction of lithium from salt lake brine using room temperature ionic liquid in tributyl phosphate

    International Nuclear Information System (INIS)

    Shi, Chenglong; Jia, Yongzhong; Zhang, Chao; Liu, Hong; Jing, Yan

    2015-01-01

    Highlights: • We proposed a new system for Li recovery from salt lake brine by extraction using an ionic liquid. • Cation exchange was proposed to be the mechanism of extraction followed in ionic liquid. • This ionic liquid system shown considerable extraction ability for lithium and the single extraction efficiency of lithium reached 87.28% under the optimal conditions. - Abstract: Lithium is known as the energy metal and it is a key raw material for preparing lithium isotopes which have important applications in nuclear energy source. In this work, a typical room temperature ionic liquid (RTILs), 1-butyl-3-methyl-imidazolium hexafluorophosphate ([C 4 mim][PF 6 ]), was used as an alternative solvent to study liquid/liquid extraction of lithium from salt lake brine. In this system, the ionic liquid, NaClO 4 and tributyl phosphate (TBP) were used as extraction medium, co-extraction reagent and extractant respectively. The effects of solution pH value, phase ratio, ClO 4 − amount and other factors on lithium extraction efficiency had been investigated. Optimal extraction conditions of this system include the ratio of TBP/IL at 4/1 (v/v), O/A at 2:1, n(ClO 4 − )/n(Li + ) at 2:1, the equilibration time of 10 min and unadjusted pH. Under the optimal conditions, the single extraction efficiency of lithium was 87.28% which was much higher than the conventional extraction system. Total extraction efficiency of 99.12% was obtained by triple-stage countercurrent extraction. Study on the mechanism revealed that the use of ionic liquid increased the extraction yield of lithium through cation exchange in this system. Preliminary results indicated that the use of [C 4 mim][PF 6 ] as an alternate solvent to replace traditional organic solvents (VOCs) in liquid/liquid extraction was very promising

  19. A computer program incorporating Pitzer's equations for calculation of geochemical reactions in brines

    Science.gov (United States)

    Plummer, Niel; Parkhurst, D.L.; Fleming, G.W.; Dunkle, S.A.

    1988-01-01

    The program named PHRQPITZ is a computer code capable of making geochemical calculations in brines and other electrolyte solutions to high concentrations using the Pitzer virial-coefficient approach for activity-coefficient corrections. Reaction-modeling capabilities include calculation of (1) aqueous speciation and mineral-saturation index, (2) mineral solubility, (3) mixing and titration of aqueous solutions, (4) irreversible reactions and mineral water mass transfer, and (5) reaction path. The computed results for each aqueous solution include the osmotic coefficient, water activity , mineral saturation indices, mean activity coefficients, total activity coefficients, and scale-dependent values of pH, individual-ion activities and individual-ion activity coeffients , and scale-dependent values of pH, individual-ion activities and individual-ion activity coefficients. A data base of Pitzer interaction parameters is provided at 25 C for the system: Na-K-Mg-Ca-H-Cl-SO4-OH-HCO3-CO3-CO2-H2O, and extended to include largely untested literature data for Fe(II), Mn(II), Sr, Ba, Li, and Br with provision for calculations at temperatures other than 25C. An extensive literature review of published Pitzer interaction parameters for many inorganic salts is given. Also described is an interactive input code for PHRQPITZ called PITZINPT. (USGS)

  20. Modelling of vapour explosion in stratified geometrie

    International Nuclear Information System (INIS)

    Picchi, St.

    1999-01-01

    When a hot liquid comes into contact with a colder volatile liquid, one can obtain in some conditions an explosive vaporization, told vapour explosion, whose consequences can be important on neighbouring structures. This explosion needs the intimate mixing and the fine fragmentation between the two liquids. In a stratified vapour explosion, these two liquids are initially superposed and separated by a vapor film. A triggering of the explosion can induce a propagation of this along the film. A study of experimental results and existent models has allowed to retain the following main points: - the explosion propagation is due to a pressure wave propagating through the medium; - the mixing is due to the development of Kelvin-Helmholtz instabilities induced by the shear velocity between the two liquids behind the pressure wave. The presence of the vapour in the volatile liquid explains experimental propagation velocity and the velocity difference between the two fluids at the pressure wave crossing. A first model has been proposed by Brayer in 1994 in order to describe the fragmentation and the mixing of the two fluids. Results of the author do not show explosion propagation. We have therefore built a new mixing-fragmentation model based on the atomization phenomenon that develops itself during the pressure wave crossing. We have also taken into account the transient aspect of the heat transfer between fuel drops and the volatile liquid, and elaborated a model of transient heat transfer. These two models have been introduced in a multi-components, thermal, hydraulic code, MC3D. Results of calculation show a qualitative and quantitative agreement with experimental results and confirm basic options of the model. (author)

  1. Modeling of nonuniform corrosion in salt brines: Salt Repository Project

    International Nuclear Information System (INIS)

    Reimus, P.W.

    1988-03-01

    A mechanistic approach to modeling nonuniform corrosion in brines is presented in this report. Equations are derived for completely describing the electrochemical environment within a localized corrosion cavity, and appropriate initial and boundary conditions are invoked to obtain a solvable system of equations. The initial and boundary conditions can be adjusted to simulate pitting, crevice corrosion, or stress corrosion cracking. Although no numerical results are presented, a numerical strategy for solving the equations is presented. The report focuses on the nonuniform corrosion behavior of mild steel; however, the modeling approach presented is expected to apply to a broad range of metallic materials. 34 refs., 5 figs., 2 tabs

  2. Protein removal from waste brines generated during ham salting through acidification and centrifugation.

    Science.gov (United States)

    Gutiérrez-Martínez, Maria del Rosario; Muñoz-Guerrero, Hernán; Alcaína-Miranda, Maria Isabel; Barat, José Manuel

    2014-03-01

    The salting step in food processes implies the production of large quantities of waste brines, having high organic load, high conductivity, and other pollutants with high oxygen demand. Direct disposal of the residual brine implies salinization of soil and eutrophication of water. Since most of the organic load of the waste brines comes from proteins leaked from the salted product, precipitation of dissolved proteins by acidification and removal by centrifugation is an operation to be used in waste brine cleaning. The aim of this study is optimizing the conditions for carrying out the separation of proteins from waste brines generated in the pork ham salting operation, by studying the influence of pH, centrifugal force, and centrifugation time. Models for determining the removal of proteins depending on the pH, centrifugal force, and time were obtained. The results showed a high efficacy of the proposed treatment for removing proteins, suggesting that this method could be used for waste brine protein removal. The best pH value to be used in an industrial process seems to be 3, while the obtained results indicate that almost 90% of the proteins from the brine can be removed by acidification followed by centrifugation. A further protein removal from the brine should have to be achieved using filtrating techniques, which efficiency could be highly improved as a consequence of the previous treatment through acidification and centrifugation. Waste brines from meat salting have high organic load and electrical conductivity. Proteins can be removed from the waste brine by acidification and centrifugation. The total protein removal can be up to 90% of the initial content of the waste brine. Protein removal is highly dependent on pH, centrifugation rate, and time. © 2014 Institute of Food Technologists®

  3. Fermentation cover brine reformulation for cucumber processing with low salt to reduce bloater defect

    Science.gov (United States)

    Reformulation of calcium chloride cover brine for cucumber fermentation was explored as a mean to minimize the incidence of bloater defect. This study particularly focused on cover brine supplementation with calcium hydroxide, sodium chloride (NaCl), and acids to enhance buffer capacity, inhibit the...

  4. Brine Pockets in the Icy Shell on Europa: Distribution, Chemistry, and Habitability

    Science.gov (United States)

    Zolotov, M. Yu; Shock, E. L.; Barr, A. C.; Pappalardo, R. T.

    2004-01-01

    On Earth, sea ice is rich in brine, salt, and gas inclusions that form through capturing of seawater during ice formation. Cooling of the ice over time leads to sequential freezing of captured sea-water, precipitation of salts, exsolution of gases, and formation of brine channels and pockets. Distribution and composition of brines in sea ice depend on the rate of ice formation, vertical temperature gradient, and the age of the ice. With aging, the abundance of brine pockets decreases through downward migration. De- spite low temperatures and elevated salinities, brines in sea ice provide a habitat for photosynthetic and chemosynthetic organisms. On Europa, brine pockets and channels could exist in the icy shell that may be from a few km to a few tens of km thick and is probably underlain by a water ocean. If the icy shell is relatively thick, convection could develop, affecting the temperature pattern in the ice. To predict the distribution and chemistry of brine pockets in the icy shell we have combined numerical models of the temperature distribution within a convecting shell, a model for oceanic chemistry, and a model for freezing of Europan oceanic water. Possible effects of brine and gas inclusions on ice rheology and tectonics are discussed.

  5. Recovery of biomolecules from marinated herring (Clupea harengus) brine using ultrafiltration through ceramic membranes

    DEFF Research Database (Denmark)

    Gringer, Nina; Hosseini, Seyed Vali; Svendsen, Tore

    2015-01-01

    Marinated herring processing brines, which are usually discarded, are rich in salt, protein, non-protein nitrogen, iron, fatty acids, antioxidant and even possess enzymatic activity. This study investigated the performance of ceramic ultrafiltration of two herring spice brines with a major focus...

  6. Corrosion and hydrogen permeation of A216 Grade WCA steel in hydrothermal magnesium-containing brines

    International Nuclear Information System (INIS)

    Haberman, J.H.; Frydrych, D.J.; Westerman, R.E.

    1988-03-01

    Corrosion rates determined at 1 month in 150/degree/C brine increased with magnesium concentration. The structure of the corrosion product, as determined by x-ray diffraction, depended upon the magnesium concentration. In brines with less than 10,000 ppM magnesium, the primary corrosion product had a spinel structure characteristic of magnetite or magnesioferrite. In brines containing magnesium concentrations greater than 20,000 ppM, the primary corrosion product had the amakinite structure characteristic of a complex iron-magnesium hydroxide. The high corrosion rates observed in brines containing high magnesium concentrations suggest that the corrosion products having the amakinite structure is less protective than corrosion products having the spinel structure. Corrosion rates in high-magnesium (inclusion) brine determined over a 6-month test duration were essentially constant. Hydrogen permeation rates observed in exposing mild steel to high-Mg/sup 2/plus// brine at 150/degree/C could be potentially damaging to a mild steel waste package container. The rate of hydrogen permeation was proportional to the brine flow rate in the autoclave. Thiourea additions to the brine increased the hydrogen permeation rate; sulfate and bromide ion additions did not. The maximum gaseous hydrogen pressure attainable is not known (based on 3Fe /plus/ 4H 2 O /plus/ Fe(sub 3)O /plus/ 4H 2 , would be /approximately/900 atmospheres), and the dependence of permeation rate on temperature is not known. 8 refs., 13 figs., 3 tabs

  7. Geochemistry of Salado Formation brines recovered from the Waste Isolation Pilot Plant (WIPP) repository

    International Nuclear Information System (INIS)

    Abitz, R.; Myers, J.; Drez, P.; Deal, D.

    1990-01-01

    Intergranular brines recovered from the repository horizon of the Waste Isolation Pilot Plant (WIPP) have major- and trace-element compositions that reflect seawater evaporation and diagenetic processes. Brines obtained from repository drill holes are heterogenous with respect to composition, but their compositional fields are distinct from those obtained from fluid inclusions in WIPP halite. The heterogeneity of brine compositions within the drill-hole population indicates a lack of mixing and fluid homogenization within the salt at the repository level. Compositional differences between intergranular (drill hole) and intragranular (fluid inclusions) brines is attributed to isolation of the latter from diagenetic fluids that were produced from dehydration reactions involving gypsum and clay minerals. Modeling of brine-rock equilibria indicates that equilibration with evaporite minerals controls the concentrations of major elements in the brine. Drill-hole brines are in equilibrium with the observed repository minerals halite, anhydrite, magnesite, polyhalite and quartz. The equilibrium model supports the derivation of drill-hole brines from near-field fluid, rather than large-scale vertical migration of fluids from the overlying Rustler or underlying Castile Formations. 13 refs., 6 figs., 6 tabs

  8. Geochemistry of Salado formation brines recovered from the Waste Isolation Pilot Plant (WIPP) repository

    International Nuclear Information System (INIS)

    Abitz, R.; Myers, J.; Drez, P.; Deal, D.

    1990-01-01

    Intergranular brines recovered from the repository horizon of the Waste Isolation Pilot Plant (WIPP) have major- and trace-element compositions that reflect seawater evaporation and diagenetic processes. Brines obtained from repository drill holes are heterogeneous with respect to composition but their compositional fields are distinct from those obtained from fluid inclusions in WIPP halite. The heterogeneity of brine compositions within the drill-hole population indicates a lack of mixing and fluid homogenization within the salt at the repository level. Compositional differences between intergranular (drill hole) and intragranular (fluid inclusions) brines is attributed to isolation of the latter from diagenetic fluids that were produced from dehydration reactions involving gypsum and clay minerals. Modeling of brine-rock equilibria indicates that equilibration with evaporite minerals controls the concentrations of major elements in the brine. Drill-hole brines are in equilibrium with the observed repository minerals halite, anhydrite, magnesite, polyhalite and quartz. The equilibrium model supports the derivation of drill-hole brines from near-field fluid, rather than large-scale vertical migration of fluids from the overlying Rustler or underlying Castile Formations. 13 refs., 6 figs., 6 tabs

  9. Water Recovery from Brine in the Short and Long Term: A KSC Approach

    Science.gov (United States)

    Lunn, Griffin; Melendez, Orlando; Anthony, Steve

    2014-01-01

    KSC has spent many years researching Hollow Fiber Membrane Bioreactors as well as research encompassing:Alternate ammonia removal/Advanced oxidation. Brine purification technologies KSC-ISRU has built an electrolysis cell for the removal of acids in ISRU mining brines. Our goal is to combine all such technologies.

  10. Improving the performance of brine wells at Gulf Coast strategic petroleum reserve sites

    Energy Technology Data Exchange (ETDEWEB)

    Owen, L.B.; Quong, R. (eds.)

    1979-11-05

    At the request of the Department of Energy, field techniques were developed to evaluate and improve the injection of brine into wells at Strategic Petroleum Reserve (SPR) sites. These wells are necessary for the disposal of saturated brine removed from salt domes where oil is being stored. The wells, which were accepting brine at 50 percent or less of their initial design rates, were impaired by saturated brine containing particulates that deposited on the sand face and in the geologic formation next to the wellbore. Corrosion of the brine-disposal pipelines and injection wells contributed to the impairment by adding significant amounts of particulates in the form of corrosion products. When tests were implemented at the SPR sites, it was found that the poor quality of injected brines was the primary cause of impaired injection; that granular-media filtration, when used with chemical pretreatment, is an effective method for removing particulates from hypersaline brine; that satisfactory injection-well performance can be attained with prefiltered brines; and that corrosion rates can be substantially reduced by oxygen-scavenging.

  11. The use of bacconcentrate Herobacterin in brine cheese technology

    Directory of Open Access Journals (Sweden)

    I. Slyvka:

    2017-12-01

    Full Text Available In the article a comparative analysis of the use of the bacterial preparation Herobacterin and the starter RSF-742 (Chr. Hansen, Denmark in the technology of brine cheese was conducted. Herobacterin is a bacterial preparation created using bacteria Lactococcus lactis, Lactobacillus plantarum, Enterococcus faecium, Leuconostoc mesenteroides and Lactococcus garvieae, isolated from traditional Carpathian brine cheese brynza and identified using classical microbiological and modern molecular genetic methods (RAPD-PCR, RFLP-PCR, sequencing of the 16S rRNA gene. The results of investigations of organoleptic, physico-chemical, syneretical and microbiological parameters of cheese brynza with use of preparation Herobacterin are presented in comparison with the starter RSF-742, which includes cultures: Lactococcus lactis subsp. сremoris, Lactococcus lactis subsp. lactis, Streptococcus thermophilus, Lactobacillus helveticus. The use of Herobacterin has a positive effect on organoleptic, physico-chemical and microbiological parameters, all parameters complied with the requirements of DSTU 7065:2009. The level of survival of lactic acid bacteria in brynza during maturation and storage is high, which confirms the correctness of the selection of strains to preparation Herobakterin, which demonstrated good adaptability to the composition and properties of ewe's milk.

  12. Observations of brine plumes below melting Arctic sea ice

    Directory of Open Access Journals (Sweden)

    A. K. Peterson

    2018-02-01

    Full Text Available In sea ice, interconnected pockets and channels of brine are surrounded by fresh ice. Over time, brine is lost by gravity drainage and flushing. The timing of salt release and its interaction with the underlying water can impact subsequent sea ice melt. Turbulence measurements 1 m below melting sea ice north of Svalbard reveal anticorrelated heat and salt fluxes. From the observations, 131 salty plumes descending from the warm sea ice are identified, confirming previous observations from a Svalbard fjord. The plumes are likely triggered by oceanic heat through bottom melt. Calculated over a composite plume, oceanic heat and salt fluxes during the plumes account for 6 and 9 % of the total fluxes, respectively, while only lasting in total 0.5 % of the time. The observed salt flux accumulates to 7.6 kg m−2, indicating nearly full desalination of the ice. Bulk salinity reduction between two nearby ice cores agrees with accumulated salt fluxes to within a factor of 2. The increasing fraction of younger, more saline ice in the Arctic suggests an increase in desalination processes with the transition to the new Arctic.

  13. Observations of brine plumes below melting Arctic sea ice

    Science.gov (United States)

    Peterson, Algot K.

    2018-02-01

    In sea ice, interconnected pockets and channels of brine are surrounded by fresh ice. Over time, brine is lost by gravity drainage and flushing. The timing of salt release and its interaction with the underlying water can impact subsequent sea ice melt. Turbulence measurements 1 m below melting sea ice north of Svalbard reveal anticorrelated heat and salt fluxes. From the observations, 131 salty plumes descending from the warm sea ice are identified, confirming previous observations from a Svalbard fjord. The plumes are likely triggered by oceanic heat through bottom melt. Calculated over a composite plume, oceanic heat and salt fluxes during the plumes account for 6 and 9 % of the total fluxes, respectively, while only lasting in total 0.5 % of the time. The observed salt flux accumulates to 7.6 kg m-2, indicating nearly full desalination of the ice. Bulk salinity reduction between two nearby ice cores agrees with accumulated salt fluxes to within a factor of 2. The increasing fraction of younger, more saline ice in the Arctic suggests an increase in desalination processes with the transition to the new Arctic.

  14. Aligning the Economic Value of Companion Diagnostics and Stratified Medicines

    Directory of Open Access Journals (Sweden)

    Edward D. Blair

    2012-11-01

    Full Text Available The twin forces of payors seeking fair pricing and the rising costs of developing new medicines has driven a closer relationship between pharmaceutical companies and diagnostics companies, because stratified medicines, guided by companion diagnostics, offer better commercial, as well as clinical, outcomes. Stratified medicines have created clinical success and provided rapid product approvals, particularly in oncology, and indeed have changed the dynamic between drug and diagnostic developers. The commercial payback for such partnerships offered by stratified medicines has been less well articulated, but this has shifted as the benefits in risk management, pricing and value creation for all stakeholders become clearer. In this larger healthcare setting, stratified medicine provides both physicians and patients with greater insight on the disease and provides rationale for providers to understand cost-effectiveness of treatment. This article considers how the economic value of stratified medicine relationships can be recognized and translated into better outcomes for all healthcare stakeholders.

  15. Evolution of mineralizing brines in the east Tennessee Mississippi Valley-type ore field

    Energy Technology Data Exchange (ETDEWEB)

    Kesler, S.E.; Gesink, J.A.; Haynes, F.M. (Univ. of Michingan, Ann Arbor (USA))

    1989-05-01

    The east Tennessee Mississippi Valley-type (MVT) ore field contains barite-fluorite and sphalterite deposits in a continuous paleoaquifer consisting of breccia zones in the Upper Cambrian-Lower Ordovician Knox Group. Paragenetic observations and fluid inclusion compositions in these deposits indicate that the Knox paleoaquifer was invaded first by Ca-rich brines (Ca:Na about 1) that deposited fluorite and barite, and later by Na-Ca brines (Ca:Na = 0.1 to 0.5) that deposited sphalerite. Geologic relation sindicate that these brines were derived from the southeast, in the area of the Middle Ordovician Servier foreland shale basin, and that imposed by fluorite solubility indicate further that all original connate water in the Sevier basin was required to deposit the estimated flourite reserves of the ore field.Thus, the later, sphalerite-depositing brines represent recycled meteoric water from the Sevier basin or connate brines from underlying (Cambrian) shales.

  16. Scanning electron microscope observations of brine shrimp larvae from space shuttle experiments

    Science.gov (United States)

    DeBell, L.; Paulsen, A.; Spooner, B.

    1992-01-01

    Brine shrimp are encysted as gastrula stage embryos, and may remain dehydrated and encysted for years without compromising their viability. This aspect of brine shrimp biology is desirable for studying development of animals during space shuttle flight, as cysts placed aboard a spacecraft may be rehydrated at the convenience of an astronaut, guaranteeing that subsequent brine shrimp development occurs only on orbit and not on the pad during launch delays. Brine shrimp cysts placed in 5 ml syringes were rehydrated with salt water and hatched during a 9 day space shuttle mission. Subsequent larvae developed to the 8th larval stage in the sealed syringes. We studied the morphogenesis of the brine shrimp larvae and found the larvae from the space shuttle experiments similar in rate of growth and extent of development, to larvae grown in sealed syringes on the ground. Extensive differentiation and development of embryos and larvae can occur in a microgravity environment.

  17. Indoor tests to investigate the effect of brine depth on the performance of solar still

    Energy Technology Data Exchange (ETDEWEB)

    Ali, Marwah A.W.; Jabbar N. Khalifa, Abdul [Nahrain University, College of Engineering, Jadiriya, P.O. Box 64040, Baghdad (Iraq)

    2013-07-01

    Many experimental and numerical studies have been done on different configurations of solar stills to optimize the design by examining the effect of climatic, operational and design parameters on its performance. One of the most important of the operational parameters that has received a considerable attention in the literature is the brine depth. This paper reports indoor experimental investigations on the effect of brine depth on the productivity and efficiency of the solar stills at four different brine depths of 1.5, 2, 4 and 5.5 cm. Indoor tests were used by simulating the solar input by proper electric heaters located at the bottom of the still for heating the water contained in the basin of the still. The present study validated the decreasing trend in productivity with the increase of brine depth and showed that the still productivity could be influenced by the brine depth by up to 24%.

  18. Oil exudation and histological structures of duck egg yolks during brining.

    Science.gov (United States)

    Lai, K M; Chung, W H; Jao, C L; Hsu, K C

    2010-04-01

    Changes in oil exudation and histological structures of salted duck egg yolks during brining up to 5 wk were investigated. During brining, the salt contents of albumen, exterior yolk (hardened portion), and interior yolk (soft or liquid portion) gradually increased accompanied by slight decreases in moisture content. The hardening ratio of salted egg yolks increased rapidly to about 60% during the first week of brining and then reached 100% at the end of brining. After brining, part of the lipids in salted egg yolk became free due to the structural changes of low-density lipoprotein induced by dehydration and increase of salt content, and more free lipids in salted egg yolk were released after the cooking process. With the brining time increased up to 5 wk, the outer region of the cooked salted yolk gradually changed into dark brown, brown, orange, and then dark brown, whereas the center region changed into light yellow, yellow, dark yellow, and then yellow again. The microstructures of cooked salted egg yolks showed that the yolk spheres in the outer and middle regions retained their original shape, with some shrinking and being packed more loosely when brining time increased, and the exuded oil filled the space between the spheres. Furthermore, the yolk spheres in the center region transformed to a round shape but still showed granulation after 4 wk of brining, whereas they were mostly disrupted after 2 to 5 wk of brining. One of the most important characteristics of cooked salted egg yolks, gritty texture, contributed to oil exudation and granulated yolk spheres were observed at the brining time of 4 wk.

  19. Study of rhyolitic glasses alteration in contact with natural brines (Bolivia). Application to the study of the long-term behaviour of the R7T7 nuclear glass

    International Nuclear Information System (INIS)

    Abdelouas, A.

    1996-01-01

    The purpose of this work is to complement an experimental program on the R7T7 nuclear waste glass alteration in brines at 190 deg C in Germany by the analysis of the structure and the chemical composition of the alteration layers, and to study the alteration of rhyolitic glasses in natural brines from Bolivia as analogue for nuclear waste glasses disposed in salt formations. Alteration experiments with the R7T7 and basaltic glasses and obsidian in MgCl 2 -CaCl 2 -saturated brine at 190 deg. C were also conducted in order to study the influence of the glass composition on the nature of the secondary phases. The experiments with the R7T7 glass in three salt brines, saturated respectively in MgCl 2 , MgCl 2 -CaCl 2 and NaCl, showed that the solubilities of most radionuclides are controlled by the secondary phases. Nd, La, and Pr are trapped in powellite, Ce in cerianite, U in coffinite, and Sr is partially immobilized in barite. These phases are stable for more than one year. There is a good similarity between the secondary phases formed experimentally on volcanic glasses and the R7T7 glass altered in MgCl 2 -CaCl 2 -saturated brine. The abundance of Mg in solution permits the formation of similar magnesian clays on the glass samples independently of the nature of the initial glasses. These results support the use of volcanic glasses alteration patterns in Mg-rich solutions to understand the long-term behavior of nuclear waste glasses and to evaluate the stability of the secondary phases. The study of the sediments of Uyuni (Bolivia) showed that the corrosion rate of the rhyolitic glass in brines at 10 deg. C is 12 to 30 time lower than those of rhyolitic glasses altered in high dilute conditions. The low alteration rate of rhyolitic glasses in brines and the formation of secondary phases such as smectite, barite and cerianite (also formed during the experimental alteration of the R7T7 glass), permit us to expect the low alteration of nuclear waste glasses at long

  20. Inactivation of Shiga toxin-producing O157:H7 and non-O157:H7 Shiga toxin-producing Escherichia coli in brine-injected, gas-grilled steaks.

    Science.gov (United States)

    Luchansky, John B; Porto-Fett, Anna C S; Shoyer, Bradley A; Call, Jeffrey E; Schlosser, Wayne; Shaw, William; Bauer, Nathan; Latimer, Heejeong

    2011-07-01

    We quantified translocation of Escherichia coli O157:H7 (ECOH) and non-O157:H7 verocytotoxigenic E. coli (STEC) into beef subprimals after brine injection and subsequently monitored their viability after cooking steaks cut therefrom. Beef subprimals were inoculated on the lean side with ca. 6.0 log CFU/g of a five-strain cocktail of rifampin-resistant ECOH or kanamycin-resistant STEC, and then passed once through an automatic brine-injector tenderizer, with the lean side facing upward. Brine solutions (9.9% ± 0.3% over fresh weight) consisted of 3.3% (wt/vol) of sodium tripolyphosphate and 3.3% (wt/vol) of sodium chloride, prepared both with (Lac(+), pH = 6.76) and without (Lac(-), pH = 8.02) a 25% (vol/vol) solution of a 60% potassium lactate-sodium diacetate syrup. For all samples injected with Lac(-) or Lac(+) brine, levels of ECOH or STEC recovered from the topmost 1 cm (i.e., segment 1) of a core sample obtained from tenderized subprimals ranged from ca. 4.7 to 6.3 log CFU/g; however, it was possible to recover ECOH or STEC from all six segments of all cores tested. Next, brine-injected steaks from tenderized subprimals were cooked on a commercial open-flame gas grill to internal endpoint temperatures of either 37.8 °C (100 °F), 48.8 °C (120 °F), 60 °C (140 °F), or 71.1 °C (160 °F). Regardless of brine formulation or temperature, cooking achieved reductions (expressed as log CFU per gram) of 0.3 to 4.1 of ECOH and 0.5 to 3.6 of STEC. However, fortuitous survivors were recovered even at 71.1 °C (160 °F) for ECOH and for STEC. Thus, ECOH and STEC behaved similarly, relative to translocation and thermal destruction: Tenderization via brine injection transferred both pathogens throughout subprimals and cooking highly contaminated, brine-injected steaks on a commercial gas grill at 71.1 °C (160 °F) did not kill all cells due, primarily, to nonuniform heating (i.e., cold spots) within the meat. Copyright ©, International Association for Food Protection

  1. Sensory classification of table olives using an electronic tongue: Analysis of aqueous pastes and brines.

    Science.gov (United States)

    Marx, Ítala; Rodrigues, Nuno; Dias, Luís G; Veloso, Ana C A; Pereira, José A; Drunkler, Deisy A; Peres, António M

    2017-01-01

    Table olives are highly appreciated and consumed worldwide. Different aspects are used for trade category classification being the sensory assessment of negative defects present in the olives and brines one of the most important. The trade category quality classification must follow the International Olive Council directives, requiring the organoleptic assessment of defects by a trained sensory panel. However, the training process is a hard, complex and sometimes subjective task, being the low number of samples that can be evaluated per day a major drawback considering the real needs of the olive industry. In this context, the development of electronic tongues as taste sensors for defects' sensory evaluation is of utmost relevance. So, an electronic tongue was used for table olives classification according to the presence and intensity of negative defects. Linear discrimination models were established based on sub-sets of sensor signals selected by a simulated annealing algorithm. The predictive potential of the novel approach was first demonstrated for standard solutions of chemical compounds that mimic butyric, putrid and zapateria defects (≥93% for cross-validation procedures). Then its applicability was verified; using reference table olives/brine solutions samples identified with a single intense negative attribute, namely butyric, musty, putrid, zapateria or winey-vinegary defects (≥93% cross-validation procedures). Finally, the E-tongue coupled with the same chemometric approach was applied to classify table olive samples according to the trade commercial categories (extra, 1 st choice, 2 nd choice and unsuitable for consumption) and an additional quality category (extra free of defects), established based on sensory analysis data. Despite the heterogeneity of the samples studied and number of different sensory defects perceived, the predictive linear discriminant model established showed sensitivities greater than 86%. So, the overall performance

  2. The stratified H-index makes scientific impact transparent

    DEFF Research Database (Denmark)

    Würtz, Morten; Schmidt, Morten

    2017-01-01

    The H-index is widely used to quantify and standardize researchers' scientific impact. However, the H-index does not account for the fact that co-authors rarely contribute equally to a paper. Accordingly, we propose the use of a stratified H-index to measure scientific impact. The stratified H......-index supplements the conventional H-index with three separate H-indices: one for first authorships, one for second authorships and one for last authorships. The stratified H-index takes scientific output, quality and individual author contribution into account....

  3. Quorum Quenching Bacillus sonorensis Isolated from Soya Sauce Fermentation Brine

    Directory of Open Access Journals (Sweden)

    Kok-Gan Chan

    2012-03-01

    Full Text Available An N-acylhomoserine lactone (AHL-degrading bacterial strain, L62, was isolated from a sample of fermentation brine of Chinese soya sauce by using rich medium agar supplemented with soya sauce (10% v/v. L62, a rod-shaped Gram positive bacterium with amylolytic activity, was phylogentically related to Bacillus sonorensis by 16S ribosomal DNA and rpoB sequence analyses. B. sonorensis L62 efficiently degraded N-3-oxohexanoyl homoserine lactone and N-octanoylhomoserine lactone. However, the aiiA homologue, encoding an autoinducer inactivation enzyme catalyzing the degradation of AHLs, was not detected in L62, suggesting the presence of a different AHL-degrading gene in L62. To the best of our knowledge, this is the first report of AHL-degrading B. sonorensis from soya sauce liquid state fermentation.

  4. Ice Control with Brine Spread with Nozzles on Highways

    DEFF Research Database (Denmark)

    Bolet, Lars; Fonnesbech, Jens Kristian

    2010-01-01

    on the major roads (150 km) in the municipality of North Funen from the winter 2007/8. The result has been a dramatically reduction in the number of traffic accidents on slippery roads during the winter season. From 7 and 5 accidents in the previous 2 winters to 1 accident in the winter 2007/8. Neighbouring...... municipalities had an increasing number of traffic accidents on slippery roads in the same period.......During the years 1996-2006, the former county of Funen, Denmark, gradually replaced pre-wetted salt with brine spread with nozzles as anti-icing agent in all her ice control activities. The replacement related to 1000 kilometres of highways. Jeopardizing neither road safety nor traffic flow...

  5. In-situ fracture mapping using geotomography and brine tracers

    International Nuclear Information System (INIS)

    Deadrick, F.J.; Ramirez, A.L.; Lytle, R.J.

    1981-01-01

    The Lawrence Livermore National Laboratory is currently assessing the capabilities of high resolution geophysical methods to characterize geologic sites for the disposal of high level nuclear waste. A successful experiment has recently been performed in which salt water tracers and high frequency electromagnetic waves were utilized to map rock mass fracture zones in-situ. Multiple cross-borehole EM transmissions were used to generate a tomographic image of the fractured rock region between two boreholes. The tomographs obtained correlate well with conventional wireline geophysical logs which can be used to infer the location of fractured zones in the rock mass. This indirect data suggests that the geotomography and brine tracer technique may have merit in mapping fractured zones between boreholes

  6. Degradation rate of vitamin B6 on red chili pepper drying by blanching-brine-calcium pretreatment

    Directory of Open Access Journals (Sweden)

    Uma Fadzilia Arifin

    2017-12-01

    Full Text Available Drying is one of the alternatives to prevent spoilage in red chili pepper by removing moisture content. Red chili pepper (Capsicum frutescens has complex nutrition components such as vitamins and bioactive compound. However, vitamin B6 content in chili can degrade significantly in drying process by heat. This research studied degradation rate of vitamin B6 in chili drying process under various pretreatments and temperatures. In this study, post-harvest chili before dried was pretreated by blanching, osmotic dehydration with brine, immersing in calcium chloride solution and the combination of all them. They were dried in tray dyer at various temperatures 40°C, 50°C, 60°C and 70°C. Degradation of vitamin B6 content was analyzed every 2 hours by High-Performance Liquid Chromatography for 8 hours. Results showed that blanching-brine-calcium pretreatment was expected to reduce drying time and retain high content of vitamin B6 in red chili pepper. The degradation rate of vitamin B6 in chili followed second-order reaction. The degradation rate was influenced by temperature change referring to Arrhenius equation with activation energy was about 31.97 kJ/ mol K and constant rate (k0 was 3.769. Therefore, the vitamin B6 retention can be estimated at various pretreatments, times and temperatures. Furthermore, the favorable drying conditions can be evaluated.

  7. Improved productivity of the MSF (multi-stage flashing) desalination plant by increasing the TBT (top brine temperature)

    International Nuclear Information System (INIS)

    Hanshik, Chung; Jeong, Hyomin; Jeong, Kwang-Woon; Choi, Soon-Ho

    2016-01-01

    The evaporating process is very important in the system concerned with liquid foods, seawater distillation and wastewater treatment, which is to concentrate the aqueous solution by evaporating the pure water usually at a vacuum state. In general, the liquid concentration is performed through the membrane, electro-dialysis, and evaporation; the former are separation process and the latter is the phase change process. In this study, only the thermal process was treated for evaluating the specific energy consumption by changing the operating conditions of an existing MSF (multi-stage flashing) desalination plant, which is still dominant for a large scale distillation plant. This study shows the quantitative energy saving strategy in sweater distillation process and, additionally, indicates that the performance of the multi-stage evaporating system can be increased with the elevation of a TBT (top brine temperature). The calculated results were based on the operating data of the currently installed plants and suggests the alternative to improve the performance of the MSF desalination plant, which means that the energy saving can be achieved only by changing the operating conditions of the existing MSF plants. - Highlights: • Detailed operating principles of an multi-stage flashing (MSF) desalting process. • Improved freshwater productivity by increasing the top brine temperature (TBT). • Increased energy efficiency of an existing MSF plants by the TBT increase.

  8. Sulphate removal from sodium sulphate-rich brine and recovery of barium as a barium salt mixture.

    Science.gov (United States)

    Vadapalli, Viswanath R K; Zvimba, John N; Mulopo, Jean; Motaung, Solly

    2013-01-01

    Sulphate removal from sodium sulphate-rich brine using barium hydroxide and recovery of the barium salts has been investigated. The sodium sulphate-rich brine treated with different dosages of barium hydroxide to precipitate barium sulphate showed sulphate removal from 13.5 g/L to less than 400 mg/L over 60 min using a barium to sulphate molar ratio of 1.1. The thermal conversion of precipitated barium sulphate to barium sulphide achieved a conversion yield of 85% using coal as both a reducing agent and an energy source. The recovery of a pure mixture of barium salts from barium sulphide, which involved dissolution of barium sulphide and reaction with ammonium hydroxide resulted in recovery of a mixture of barium carbonate (62%) and barium hydroxide (38%), which is a critical input raw material for barium salts based acid mine drainage (AMD) desalination technologies. Under alkaline conditions of this barium salt mixture recovery process, ammonia gas is given off, while hydrogen sulfide is retained in solution as bisulfide species, and this provides basis for ammonium hydroxide separation and recovery for reuse, with hydrogen sulfide also recoverable for further industrial applications such as sulfur production by subsequent stripping.

  9. CO2/ brine substitution experiments at simulated reservoir conditions

    Science.gov (United States)

    Kummerow, Juliane; Spangenberg, Erik

    2015-04-01

    Capillary properties of rocks affect the mobility of fluids in a reservoir. Therefore, the understanding of the capillary pressure behaviour is essential to assess the long-term behaviour of CO2 reservoirs. Beyond this, a calibration of the petrophysical properties on water saturation of reservoir rocks at simulated in situ conditions is crucial for a proper interpretation of field monitoring data. We present a set-up, which allows for the combined measurements of capillary pressure, electric resistivity, and elastic wave velocities under controlled reservoir conditions (pconf = 400 bar, ppore = 180 bar, T = 65 ° C) at different brine-CO2 saturations. The capillary properties of the samples are measured using the micropore membrane technique. The sample is jacketed with a Viton tube (thickness = 4 mm) and placed between two current electrode endcaps, which as well contain pore fluid ports and ultrasonic P and S wave transducers. Between the sample and the lower endcap the hydrophilic semi-permeable micro-pore membrane (pore size = 100 nm) is integrated. It is embedded into filter papers to establish a good capillary contact and to protect the highly sensitive membrane against mechanical damage under load. Two high-precision syringe pumps are used to displace a quantified volume of brine by CO2 and determine the corresponding sample saturation. The fluid displacement induces a pressure gradient along the sample, which corresponds to the capillary pressure at a particular sample saturation. It is measured with a differential pressure sensor in the range between 0 - 0.2 MPa. Drainage and imbibition cycles are performed to provide information on the efficiency of capillary trapping and to get a calibration of the petrophysical parameters of the sample.

  10. Viruses-to-mobile genetic elements skew in the deep Atlantis II brine pool sediments

    KAUST Repository

    Adel, Mustafa

    2016-09-06

    The central rift of the Red Sea has 25 brine pools with different physical and geochemical characteristics. Atlantis II (ATIID), Discovery Deeps (DD) and Chain Deep (CD) are characterized by high salinity, temperature and metal content. Several studies reported microbial communities in these brine pools, but few studies addressed the brine pool sediments. Therefore, sediment cores were collected from ATIID, DD, CD brine pools and an adjacent brine-influenced site. Sixteen different lithologic sediment sections were subjected to shotgun DNA pyrosequencing to generate 1.47 billion base pairs (1.47 × 109 bp). We generated sediment-specific reads and attempted to annotate all reads. We report the phylogenetic and biochemical uniqueness of the deepest ATIID sulfur-rich brine pool sediments. In contrary to all other sediment sections, bacteria dominate the deepest ATIID sulfur-rich brine pool sediments. This decrease in virus-to-bacteria ratio in selected sections and depth coincided with an overrepresentation of mobile genetic elements. Skewing in the composition of viruses-to-mobile genetic elements may uniquely contribute to the distinct microbial consortium in sediments in proximity to hydrothermally active vents of the Red Sea and possibly in their surroundings, through differential horizontal gene transfer.

  11. Distribution of Cathepsin D Activity between Lysosomes and a Soluble Fraction of Marinating Brine.

    Science.gov (United States)

    Szymczak, Mariusz

    2016-08-01

    This paper is the first ever to describe the phenomenon of bimodal distribution of cathepsin D in the lysosomal and soluble fractions of brine left after herring marinating. Up to 2 times higher cathepsin D activity was observed in the lysosome fraction. Activity of cathepsin D in brine increased according to the logarithmic function during low frequency-high power ultrasounds treatment or according to the linear function after multiple freezing-thawing of brine. Activity enhancement was achieved only in the brine devoid of lipids and suspension. Study results show also that measurement of lysosomal cathepsin D activity in the marinating brine requires also determining cathepsin E activity. Decreasing pore size of microfilter from 2.7 to 0.3 μm significantly reduced the lysosome content in the brine. The presence of lysosomes and the possibility of their separation as well as the likely release of cathepsins shall be considered during industrial application of the marinating brine, as new cathepsins preparations in fish and meat technology. © 2016 Institute of Food Technologists®

  12. Alcohol Brine Freezing of Japanese Horse Mackerel (Trachurus japonicus) for Raw Consumption

    Science.gov (United States)

    Maeda, Toshimichi; Yuki, Atsuhiko; Sakurai, Hiroshi; Watanabe, Koichiro; Itoh, Nobuo; Inui, Etsuro; Seike, Kazunori; Mizukami, Yoichi; Fukuda, Yutaka; Harada, Kazuki

    In order to test the possible application of alcohol brine freezing to Japanese horse mackerel (Trachurus japonicus) for raw consumption, the quality and taste of fish frozen by direct immersion in 60% ethanol brine at -20, -25 and -30°C was compared with those by air freezing and fresh fish without freezing. Cracks were not found during the freezing. Smell of ethanol did not remain. K value, an indicator of freshness, of fish frozen in alcohol brine was less than 8.3%, which was at the same level as those by air freezing and fresh fish. Oxidation of lipid was at the same level as air freezing does, and lower than that of fresh fish. The pH of fish frozen in alcohol brine at -25 and -30°C was 6.5 and 6.6, respectively, which were higher than that by air freezing and that of fresh fish. Fish frozen in alcohol brine was better than that by air and at the same level as fresh fish in total evaluation of sensory tests. These results show that the alcohol brine freezing is superior to air freezing, and fish frozen in alcohol brine can be a material for raw consumption. The methods of thawing in tap water, cold water, refrigerator, and at room temperature were compared. Thawing in tap water is considered to be convenient due to the short thaw time and the quality of thawed fish that was best among the methods.

  13. Migration rates of brine inclusions in single crystals of NaCl

    International Nuclear Information System (INIS)

    Chou, I.M.

    1982-01-01

    Rock-salt deposits have been considered as a possible medium for the permanent storage of high-level radioactive wastes and spent fuel. Brine inclusions present in natural salt can migrate toward the waste if the temperature and the temperature gradients in the vicinity of the radioactive waste are large enough. This migration is due to the dissolution of salt at the hot side of the salt-brine interface, ion diffusion through the brine droplet, and the precipitation of salt at the cold side of the salt brine interface. In order to quantify the problem, the migration rate of these brine inclusions must be estimated under various repository conditions. This paper estimates migration rates for all-liquid brine inclusions in single crystals of NaCl by utilizing recent data for brines and the model of Anthony and Cline [T.R. Anthony and H.E. Cline, J. Appl. Phys., 42, pp. 3380-387 (1971)]. The predictions are compared with experimentally measured migration rates. 4 figures, 6 tables

  14. Uranium mobility in non-oxidizing brines: field and experimental evidence

    International Nuclear Information System (INIS)

    Giblin, A.M.; Appleyard, E.C.

    1987-01-01

    The present distribution of U in the Wollaston Sediments in Saskatchewan can be related to the movement of brines as revealed in Na-Ca-Mg-Cl-metasomes. Experiments were conducted at 60 and 200 0 C under stringently non-oxidizing conditions using solvents ranging from distilled water to a Ca-Na-K brine formulated to simulate the major element composition of the Salton Sea geothermal brines. The experiments were conducted on natural pitchblende (UOsub(2.67)) and synthetic uraninite (UOsub(2.01)). Natural pitchblende was more strongly dissolved than the synthetic uraninite, and the synthetic Salton Sea brine was a more potent solvent than distilled water, 1:4 diluted Salton Sea brine, or pure NaCl brine. Within analytical limits of detection the dissolved U is present in the uranous (U 4+ ) state. The evidence demonstrates empirically the mechanism of dissolution of naturally occurring U minerals in reduced brines and describes a geological case where this appears to have happened. (author)

  15. Modeling brine inflow to Room Q: A numerical investigation of flow mechanisms

    International Nuclear Information System (INIS)

    Freeze, G.A.; Christian-Frear, T.L.; Webb, S.W.

    1997-04-01

    A hydrologic modeling study was performed to gain insight into the flow mechanisms around Room Q. A summary of hydrologic and structural data and of predictive fluid flow models from Room Q are provided. Six years of measured data are available from the time of excavation. No brine accumulation in Room Q was measured in the first two years following excavation. However, there is considerable uncertainty associated with this early-time data due to inadequate sealing of the room. Brine may have been lost to evaporation or it may have flowed into newly created disturbed rock zone (DRZ) porosity resulting from excavation. Non-zero brine accumulation rates were measured from 2--5 years, but brine accumulation within the room dropped to zero after 5.5 years. A conceptual model for brine inflow to Room Q was developed which assumes far-field Darcy flow combined with an increasing DRZ pore volume. Numerical simulations employed TOUGH28W and used predictive DRZ porosity increase with time from SPECTROM-32 rock deformation simulations. Simulated brine inflow showed good agreement with measured brine accumulation rates for the first five years. Two important conclusions were drawn from the simulation results: (1) early-time brine inflow to the room can be reduced to zero if the DRZ pore volume increases with time, and (2) brine accumulation (inflow) rates from 2 to 5 years suggest a far-field permeability of 5 x 10 -22 m 2 with a bulk rock compressibility of 5.4 x 10 -12 Pa -1

  16. Weeks Island brine diffuser site study: baseline conditions and environmental assessment technical report

    Energy Technology Data Exchange (ETDEWEB)

    None

    1980-12-12

    This technical report presents the results of a study conducted at two alternative brine diffuser sites (A and B) proposed for the Weeks Island salt dome, together with an analysis of the potential physical, chemical, and biological effects of brine disposal for this area of the Gulf of Mexico. Brine would result from either the leaching of salt domes to form or enlarge oil storage caverns, or the subsequent use of these caverns for crude oil storage in the Strategic Petroleum Reserve (SPR) program. Brine leached from the Weeks Island salt dome would be transported through a pipeline which would extend from the salt dome either 27 nautical miles (32 statute miles) for Site A, or 41 nautical miles (47 statute miles) for Site B, into Gulf waters. The brine would be discharged at these sites through an offshore diffuser at a sustained peak rate of 39 ft/sup 3//sec. The disposal of large quantities of brine in the Gulf could have a significant impact on the biology and water quality of the area. Physical and chemical measurements of the marine environment at Sites A and B were taken between September 1977 and July 1978 to correlate the existing environmental conditions with the estimated physical extent of tthe brine discharge as predicted by the MIT model (US Dept. of Commerce, 1977a). Measurements of wind, tide, waves, currents, and stratification (water column structure) were also obtained since the diffusion and dispersion of the brine plume are a function of the local circulation regime. These data were used to calculate both near- and far-field concentrations of brine, and may also be used in the design criteria for diffuser port configuration and verification of the plume model. Biological samples were taken to characterize the sites and to predict potential areas of impact with regard to the discharge. This sampling focused on benthic organisms and demersal fish. (DMC)

  17. Cost-effective bioregeneration of nitrate-laden ion exchange brine through deliberate bicarbonate incorporation.

    Science.gov (United States)

    Li, Qi; Huang, Bin; Chen, Xin; Shi, Yi

    2015-05-15

    Bioregeneration of nitrate-laden ion exchange brine is desired to minimize its environmental impacts, but faces common challenges, i.e., enriching sufficient salt-tolerant denitrifying bacteria and stabilizing brine salinity and alkalinity for stable brine biotreatment and economically removing undesired organics derived in biotreatment. Incorporation of 0.25 M bicarbonate in 0.5 M chloride brine little affected resin regeneration but created a benign alkaline condition to favor bio-based brine regeneration. The first-quarter sulfate-mainly enriched spent brine (SB) was acidified with carbon source acetic acid for using CaCl2 at an efficiency >80% to remove sulfate. Residual Ca(2+) was limited below 2 mM by re-mixing the first-quarter and remained SB to favor denitrification. Under [Formula: see text] system buffered pH condition (8.3-8.8), nitrate was removed at 0.90 gN/L/d by hematite-enriched well-settled activated sludge (SVI 8.5 ml/g) and the biogenic alkalinity was retained as bicarbonate. The biogenic alkalinity met the need of alkalinity in removing residual Ca(2+) after sulfate removal and in CaCl2-induced CaCO3 flocculation to remove 63% of soluble organic carbon (SOC) in biotreated brine. Carbon-limited denitrification was also operated after activated sludge acclimation with sulfide to cut SOC formation during denitrification. Overall, this bicarbonate-incorporation approach, stabilizing the brine salinity and alkalinity for stable denitrification and economical removal of undesired SOC, suits long-term cost-effective brine bioregeneration. Copyright © 2015 Elsevier Ltd. All rights reserved.

  18. Threshold temperature gradient effect on migration of brine inclusions in salt

    International Nuclear Information System (INIS)

    Pigford, T.H.

    1987-01-01

    Theories of the migration of brine inclusions in salt were interpreted as simple physical processes, and theories by Russian and US workers were shown to yield the same results. The migration theory was used to predict threshold temperature gradients below which migration of brine inclusions should not occur. The predicted threshold gradients were compared with the temperature gradients expected at the Waste Isolation Pilot Plant in New Mexico. The theory of threshold gradients helps explain the existence of brine inclusions in natural salt deposits

  19. Evaluation of the bioactivities of some Myanmar medicinal plants using brine shrimp (Artemia salina) toxicity test

    International Nuclear Information System (INIS)

    Sabai; Khin Khin Win Aung; Nwe Ni Thin; Kyi Shwe; Tin Myint Htwe

    2001-01-01

    For a variety of toxic substances, brine shrimp larvae (Artemia salina) are usually used as a simple bioassay method and it is also applied for natural product research. The brine shrimp larvae (nauplii) are obtained by natural hatching method from Artemia cysts. By using the larvae, the results from these experiments lead to the lethal dose, LD 50 values of extracts of selected medicinal plants. Activities of a broad range of plant extracts are manifested as toxicity to the brine shrimp. Screening results with six plant extracts are compared with pure caffeine. This method is rapid, reliable, inexpensive and convenient. (author)

  20. Deep brine recognition upstream the EBE syndicate. Geochemical and isotopic investigations. Final report

    International Nuclear Information System (INIS)

    2009-01-01

    The authors report and discuss the results obtained after performing a drilling upstream the drinkable water harnessing field of a water supply syndicate in Alsace (Ensisheim, Bollwiller and surroundings), in order to confirm the existence of a deep brine source. This brine is diluted by recent waters. The first isotopic investigations do not allow the origin of this brine to be identified, but fractures due to some seismic events are suspected. The report presents the drilling and the various aspects of the chemical and isotopic studies (sampling, physico-chemical analysis, dating, identification of various isotopes)

  1. Ring Resonator for Detection of Melting Brine Under Shallow Subsurface of Mars

    Science.gov (United States)

    Ponchak, George E.; Jordan, Jennifer L.; Scardelletti, Maximilian C.

    2016-01-01

    Laboratory experimental evidence using Raman spectroscopy has shown that liquid brine may form below the shallow subsurface of Mars. A simpler experimental method to verify the presence of liquid brine or liquid water below Mars surface is needed. In this paper, a ring resonator is used to detect the phase change between frozen water and liquid water below a sandy soil that simulates the Mars surface. Experimental data shows that the ring resonator can detect the melting of thin layers of frozen brine or water up to 15 mm below the surface.

  2. Mixed Convection Flow along a Stretching Cylinder in a Thermally Stratified Medium

    Directory of Open Access Journals (Sweden)

    Swati Mukhopadhyay

    2012-01-01

    Full Text Available An analysis for the axisymmetric laminar boundary layer mixed convection flow of a viscous and incompressible fluid towards a stretching cylinder immersed in a thermally stratified medium is presented in this paper. Similarity transformation is employed to convert the governing partial differential equations into highly nonlinear ordinary differential equations. Numerical solutions of these equations are obtained by a shooting method. It is found that the heat transfer rate at the surface is lower for flow in a thermally stratified medium compared to that of an unstratified medium. Moreover, both the skin friction coefficient and the heat transfer rate at the surface are larger for a cylinder compared to that for a flat plate.

  3. Doubly stratified mixed convection flow of Maxwell nanofluid with heat generation/absorption

    Energy Technology Data Exchange (ETDEWEB)

    Abbasi, F.M., E-mail: abbasisarkar@gmail.com [Department of Mathematics, Comsats Institute of Information Technology, Islamabad 44000 (Pakistan); Shehzad, S.A. [Department of Mathematics, Comsats Institute of Information Technology, Sahiwal 57000 (Pakistan); Hayat, T. [Department of Mathematics, Quaid-i-Azam University, 45320, Islamabad 44000 (Pakistan); NAAM Research Group, Department of Mathematics, Faculty of Science, King Abdulaziz University, Jeddah 21589 (Saudi Arabia); Ahmad, B. [NAAM Research Group, Department of Mathematics, Faculty of Science, King Abdulaziz University, Jeddah 21589 (Saudi Arabia)

    2016-04-15

    Magnetohydrodynamic (MHD) doubly stratified flow of Maxwell nanofluid in presence of mixed convection is analyzed in this article. Effects of thermophoresis, Brownian motion and heat generation/absorption are present. The flow is induced due to linear stretching of sheet. Mathematical formulation is made under boundary layer approach. Expressions of velocity, temperature and nanoparticles concentration are developed. The obtained results are plotted and discussed to examine the variations in temperature and nanoparticles concentration due to different physical parameters. Numerical computations are made to obtain the values of local Nusselt and Sherwood numbers. Impact of sundry parameters on the flow quantities is analyzed graphically. - Highlights: • Double stratified flow of Maxwell nanofluid with mixed convection is modeled. • Thermophoresis and Brownian motion effects are encountered. • Computations are made to obtain the solution expressions. • Numerical values of local Nusselt and Sherwood numbers are computed and examined.

  4. Estimation of Finite Population Mean in Multivariate Stratified Sampling under Cost Function Using Goal Programming

    Directory of Open Access Journals (Sweden)

    Atta Ullah

    2014-01-01

    Full Text Available In practical utilization of stratified random sampling scheme, the investigator meets a problem to select a sample that maximizes the precision of a finite population mean under cost constraint. An allocation of sample size becomes complicated when more than one characteristic is observed from each selected unit in a sample. In many real life situations, a linear cost function of a sample size nh is not a good approximation to actual cost of sample survey when traveling cost between selected units in a stratum is significant. In this paper, sample allocation problem in multivariate stratified random sampling with proposed cost function is formulated in integer nonlinear multiobjective mathematical programming. A solution procedure is proposed using extended lexicographic goal programming approach. A numerical example is presented to illustrate the computational details and to compare the efficiency of proposed compromise allocation.

  5. Experimental and numerical investigation of stratified gas-liquid flow in inclined circular pipes

    International Nuclear Information System (INIS)

    Faccini, J.L.H.; Sampaio, P.A.B. de; Botelho, M.H.D.S.; Cunha, M.V.; Cunha Filho, J.S.; Su, J.

    2012-01-01

    In this paper, a stratified gas-liquid flow is experimentally and numerically investigated. Two measurement techniques, namely an ultrasonic technique and a visualization technique, are applied on an inclined circular test section using a fast single transducer pulse-echo technique and a high-speed camera. A numerical model is employed to simulate the stratified gas-liquid flow, formed by a system of non-linear differential equations consisting of the Reynolds averaged Navier-Stokes equations with the κ-ω turbulence model. The test section used in this work is comprised mainly of a transparent circular pipe with inner diameter 1 inch, and inclination angles varying from -2.5 to -10.0 degrees. Numerical solutions are obtained for the liquid height as a function of inclination angles, and compared with our own experimental data. (author)

  6. Emerging Techniques in Stratified Designs and Continuous Gradients for Tissue Engineering of Interfaces

    Science.gov (United States)

    Dormer, Nathan H.; Berkland, Cory J.; Detamore, Michael S.

    2013-01-01

    Interfacial tissue engineering is an emerging branch of regenerative medicine, where engineers are faced with developing methods for the repair of one or many functional tissue systems simultaneously. Early and recent solutions for complex tissue formation have utilized stratified designs, where scaffold formulations are segregated into two or more layers, with discrete changes in physical or chemical properties, mimicking a corresponding number of interfacing tissue types. This method has brought forth promising results, along with a myriad of regenerative techniques. The latest designs, however, are employing “continuous gradients” in properties, where there is no discrete segregation between scaffold layers. This review compares the methods and applications of recent stratified approaches to emerging continuously graded methods. PMID:20411333

  7. Draft Genome of Scalindua rubra, Obtained from the Interface Above the Discovery Deep Brine in the Red Sea, Sheds Light on Potential Salt Adaptation Strategies in Anammox Bacteria.

    Science.gov (United States)

    Speth, Daan R; Lagkouvardos, Ilias; Wang, Yong; Qian, Pei-Yuan; Dutilh, Bas E; Jetten, Mike S M

    2017-07-01

    Several recent studies have indicated that members of the phylum Planctomycetes are abundantly present at the brine-seawater interface (BSI) above multiple brine pools in the Red Sea. Planctomycetes include bacteria capable of anaerobic ammonium oxidation (anammox). Here, we investigated the possibility of anammox at BSI sites using metagenomic shotgun sequencing of DNA obtained from the BSI above the Discovery Deep brine pool. Analysis of sequencing reads matching the 16S rRNA and hzsA genes confirmed presence of anammox bacteria of the genus Scalindua. Phylogenetic analysis of the 16S rRNA gene indicated that this Scalindua sp. belongs to a distinct group, separate from the anammox bacteria in the seawater column, that contains mostly sequences retrieved from high-salt environments. Using coverage- and composition-based binning, we extracted and assembled the draft genome of the dominant anammox bacterium. Comparative genomic analysis indicated that this Scalindua species uses compatible solutes for osmoadaptation, in contrast to other marine anammox bacteria that likely use a salt-in strategy. We propose the name Candidatus Scalindua rubra for this novel species, alluding to its discovery in the Red Sea.

  8. Study on scale formation and suppression in heat-exchange systems for simulated geothermal brines. Final report, January 12, 1976-March 5, 1978

    Energy Technology Data Exchange (ETDEWEB)

    Wilson, J.S.; King, J.E.; Bullard, G.R.

    1978-01-01

    Control of scale formation in heat exchangers using simulated geothermal waters can be achieved by lowering the pH of the water to pH 6 or lower. This does not, however, appear to be an economic approach for highly buffered geothermal brines and would lead to severe corrosion problems. Two commercial scale control agents, Calgon CL-165 and Monsanto Dequest 2060, showed promise of effecting scaling in a minor way and should be tested further on actual geothermal waters. Other scale control methods tested were unsuccessful. These included seeding experiments, turbulence promotin and electostatic and electromagnetic devices reputated to modify scale formation. The experiments were performed with tube-in-shell heat exchangers using simulated geothermal waters prepared from a salt dome solution based brine. The scale formed was primarily silica with a small percent of calcium carbonate and traces of magnesium and iron. Physically it was a hydrous soft solid adhering only lightly to the heat exchange surface. This is not typical of geothermal water scales encountered in high temperature brine operations and the results of the scale control expeirments should be evaluated with that in mind.

  9. A Mechanism for Stratifying Lava Flows

    Science.gov (United States)

    Rice, A.

    2005-12-01

    Relict lava flows (e.g., komatiites) are often reported to be zoned in the vertical, each zone separated by a sharp contact. Such stratifications in igneous flows, both intrusive and extrusive, can be treated as analogues of suspended loads of sediments in rivers and streams, and hence amenable to quantitative treatment derived for the hydraulic environment as long as dynamic similitude is assured. Situations typically encountered in the hydraulic environment are streams carrying a bed load at the bottom of the stream, the bed load separated by a sharp horizon from a sediment load carried above it. This sediment load may be topped by others of decreasing density as one moves to the surface of the flow, with perhaps the uppermost layer clear of any suspended matter. Rules exist for estimating the thickness D of these loads: one of them is given by D ~ 4.4V3/rgcvs where V is the shear velocity or average velocity of the flow, r = (ρs - ρl)/ρl where ρs is the density of the suspended solid matter, ρl the density of the fluid, g the acceleration of gravity, c the concentration of the particulate content and vs the settling velocity. The settling velocity is secured through Stoke's Law and the velocity of the flow is given by V = R2/3S1/2/n where R is the hydraulic radius, S the gradient along which the fluid flows and n is the Manning Coefficient. In the igneous case, the bed load would be composed of primocrysts, i.e., of the first crystals to come out of solution as the flow cools along its run. This would leave the upper portions of the flow more evolved except perhaps for a quenched crust riding atop the flow. As the viscosity of the flow is dependent not only on temperature but on composition and crystal content, the mean velocity of each layer will be different from the layer above and below it. This requires shear at the interface of adjoining stratifications, which brings into play another mechanism: dispersive pressure (the Bagnold effect). Dispersive

  10. Anodic Behavior of Alloy 22 in Calcium Chloride and in Calcium Chloride Plus Calcium Nitrate Brines

    International Nuclear Information System (INIS)

    Evans, K.J.; Day, S.D.; Ilevbare, G.O.; Whalen, M.T.; King, K.J.; Hust, G.A.; Wong, L.L.; Estill, J.C.; Rebak, R.B.

    2003-01-01

    Alloy 22 (UNS N60622) is a nickel-based alloy, which is extensively used in aggressive industrial applications, especially due to its resistance to localized corrosion and stress corrosion cracking in high chloride environments. The purpose of this work was to characterize the anodic behavior of Alloy 22 in concentrated calcium chloride (CaCl 2 ) brines and to evaluate the inhibitive effect of nitrate, especially to localized corrosion. Standard electrochemical tests such as polarization resistance and cyclic polarization were used. Results show that the corrosion potential of Alloy 22 was approximately -360 mV in the silver-silver chloride (SSC) scale and independent of the tested temperature. Cyclic polarization tests showed that Alloy 22 was mainly susceptible to localized attack in 5 M CaCl 2 at 75 C and higher temperatures. The addition of nitrate in a molar ratio of chloride to nitrate equal to 10 increased the onset of localized corrosion to approximately 105 C. The addition of nitrate to the solution also decreased the uniform corrosion rate and the passive current of the alloy

  11. Environmentally assisted fracture of cast and wrought mild steels in brine

    International Nuclear Information System (INIS)

    Pitman, S.G.; Hall, E.E.

    1984-01-01

    Two test methods, slow strain rate (SSR) tests and corrosion fatigue tests, are being used to investigate the susceptibility of wrought and cast mild steels to environmentally assisted fracture. The SSR test provides an assessment of relative cracking susceptibility, and is most useful for comparing the effects of different environments on a given material, and for measuring the relative susceptibility of different materials to environmentally assisted cracking in a given environment. The corrosion fatigue test measures the stress intensity (which is proportional to stress times the square root of crack length) below which an existing flaw or crack will not grow. The test may also prove useful in measuring the stress intensity that provides an acceptable rate of crack growth. The SSR test has been used to investigate the effects of strain rate, temperature, and solution oxygen content on fracture properties of mild steel. The results of currently available corrosion fatigue tests are limited to crack growth rate measurements at one frequency in air and in brine. These measurements will be part of an overall program to evaluate allowable stress intensities, but this evaluation cannot be made until measurements are taken at different frequencies and at lower stress intensities. This report, then discusses the background of SSR testing, experimental procedures, results, and conclusions

  12. Extraction of lithium from salt lake brine using room temperature ionic liquid in tributyl phosphate

    Energy Technology Data Exchange (ETDEWEB)

    Shi, Chenglong [Key Laboratory of Salt Lake Resources and Chemistry, Qinghai Institute of Salt Lakes, Chinese Academy of Sciences, 810008 Xining (China); University of Chinese Academy of Sciences, 100049 Beijing (China); Jia, Yongzhong [Key Laboratory of Salt Lake Resources and Chemistry, Qinghai Institute of Salt Lakes, Chinese Academy of Sciences, 810008 Xining (China); Zhang, Chao [Key Laboratory of Salt Lake Resources and Chemistry, Qinghai Institute of Salt Lakes, Chinese Academy of Sciences, 810008 Xining (China); University of Chinese Academy of Sciences, 100049 Beijing (China); Liu, Hong [Qinghai Salt Chemical Products Supervision and Inspection Center, 816000 Golmud (China); Jing, Yan, E-mail: 1580707906@qq.com [Key Laboratory of Salt Lake Resources and Chemistry, Qinghai Institute of Salt Lakes, Chinese Academy of Sciences, 810008 Xining (China)

    2015-01-15

    Highlights: • We proposed a new system for Li recovery from salt lake brine by extraction using an ionic liquid. • Cation exchange was proposed to be the mechanism of extraction followed in ionic liquid. • This ionic liquid system shown considerable extraction ability for lithium and the single extraction efficiency of lithium reached 87.28% under the optimal conditions. - Abstract: Lithium is known as the energy metal and it is a key raw material for preparing lithium isotopes which have important applications in nuclear energy source. In this work, a typical room temperature ionic liquid (RTILs), 1-butyl-3-methyl-imidazolium hexafluorophosphate ([C{sub 4}mim][PF{sub 6}]), was used as an alternative solvent to study liquid/liquid extraction of lithium from salt lake brine. In this system, the ionic liquid, NaClO{sub 4} and tributyl phosphate (TBP) were used as extraction medium, co-extraction reagent and extractant respectively. The effects of solution pH value, phase ratio, ClO{sub 4}{sup −} amount and other factors on lithium extraction efficiency had been investigated. Optimal extraction conditions of this system include the ratio of TBP/IL at 4/1 (v/v), O/A at 2:1, n(ClO{sub 4}{sup −})/n(Li{sup +}) at 2:1, the equilibration time of 10 min and unadjusted pH. Under the optimal conditions, the single extraction efficiency of lithium was 87.28% which was much higher than the conventional extraction system. Total extraction efficiency of 99.12% was obtained by triple-stage countercurrent extraction. Study on the mechanism revealed that the use of ionic liquid increased the extraction yield of lithium through cation exchange in this system. Preliminary results indicated that the use of [C{sub 4}mim][PF{sub 6}] as an alternate solvent to replace traditional organic solvents (VOCs) in liquid/liquid extraction was very promising.

  13. Heat Exchangers for Utilization of the Heat of High-Temperature Geothermal Brines

    Science.gov (United States)

    Alkhasov, A. B.; Alkhasova, D. A.

    2018-03-01

    pulsed introduction of the agent solution into the brine at the heat exchanger inlet.

  14. Laboratory and field studies on an Indian strain of the brine shrimp Artemia

    Digital Repository Service at National Institute of Oceanography (India)

    Royan, J.P.

    The Tuticorin strain of the brine shrimp @iArtemia@@ was studied under both laboratory and field conditions. Studies on the survival of the nauplii at different temperatures and salinities revealed that the nauplii preferred a salinity of 35 ppt...

  15. Microbiology of the Red Sea (and other) deep-sea anoxic brine lakes

    KAUST Repository

    Antunes, Andre; Ngugi, David; Stingl, Ulrich

    2011-01-01

    environments on Earth. After 50 years of research mostly driven by chemists, geophysicists and geologists, the microbiology of the brines has been receiving increased interest in the last decade. Recent molecular and cultivation-based studies have provided us

  16. Bead Evaporator for Complete Water and Salt Recovery from Brine, Phase I

    Data.gov (United States)

    National Aeronautics and Space Administration — A microgravity-compatible Brine Evaporation and Mineralization System (BEMS) is proposed for 100% water recovery from highly contaminated wastewater as well as water...

  17. Brine shrimp lethality and antibacterial activity of extracts from the bark of Schleichera oleosa

    Directory of Open Access Journals (Sweden)

    Laxman Pokhrel

    2015-08-01

    Full Text Available Objective: To determine the antibacterial efficacy and brine shrimp toxicity of extracts (hexane, dichloromethane, ethyl acetate, methanol and water obtained from the bark of Schleichera oleosa. Methods: The powdered bark sample was Soxhlet extracted sequentially in hexanes, dichloromethane, ethyl acetate, methanol and water. Antibacterial evaluation was carried out by following the agar diffusion method and amoxicillin disc was used as a reference. Slightly modified Meyer’s method was used to determine the toxicity of the extracts in brine shrimps. Results: Among the nine bacterial strains tested, the methanolic and aqueous extracts showed promising antibacterial efficacy against Serratia marcescens, Escherarichia coli, Bacillus subtilis and Micrococcus luteus. None of the extracts were found significantly toxic to brine shrimps. Conclusions: Strong antibacterial activity and low brine shrimp toxicity of methanolic and aqueous extracts can provide new antibacterial compounds.

  18. Enrichment of extremophilic exoelectrogens in microbial electrolysis cells using Red Sea brine pools as inocula

    KAUST Repository

    Chehab, Noura A.; Ortiz-Madina, Juan F.; Katuri, Krishna; Rao, Hari Ananda; Amy, Gary L.; Logan, Bruce E.; Saikaly, Pascal

    2017-01-01

    environments and can be used to startup MEC under thermophilic and hypersaline conditions. Bacteroides was enriched on the anode of the Valdivia MEC, but it was not detected in the open circuit voltage reactor seeded with the Valdivia brine pool.

  19. Genomic and Transcriptomic Evidence for Carbohydrate Consumption among Microorganisms in a Cold Seep Brine Pool

    KAUST Repository

    Zhang, Weipeng; Ding, Wei; Yang, Bo; Tian, Renmao; Gu, Shuo; Luo, Haiwei; Qian, Pei-Yuan

    2016-01-01

    the Thuwal cold seep brine pool of the Red Sea. The recovered metagenome-assembled genomes (MAGs) belong to six different phyla: Actinobacteria, Proteobacteria, Candidatus Cloacimonetes, Candidatus Marinimicrobia, Bathyarchaeota, and Thaumarchaeota

  20. Meltability and Stretchability of White Brined Cheese: Effect of Emulsifier Salts

    OpenAIRE

    Khaled Abu-Alruz; Ayman S. Mazahreh; Ali F. Al-Shawabkeh; Amer A. Omari; Jihad M. Quasem

    2009-01-01

    Problem statement: This study was based on the hypothesis that by adding low concentrations of emulsifier salts, may specifically act on the cross linking bonds of the protein matrix, to the original brine (storage medium) it would be possible to induce meltability and stretchability in white brined cheese. Approach: A new apparatus for measuring the actual stretchability was designed and constructed; measurements on different cheese samples proved its validity and reliability to measure stre...

  1. Antagonism Between Osmophilic Lactic Acid Bacteria and Yeasts in Brine Fermentation of Soy Sauce

    OpenAIRE

    Noda, Fumio; Hayashi, Kazuya; Mizunuma, Takeji

    1980-01-01

    Brine fermentation by osmophilic lactic acid bacteria and yeasts for long periods of time is essential to produce a good quality of shoyu (Japanese fermented soy sauce). It is well known that lactic acid fermentation by osmophilic lactic acid bacteria results in the depression of alcoholic fermentation by osmophilic yeasts, but the nature of the interaction between osmophilic lactic acid bacteria and yeasts in brine fermentation of shoyu has not been revealed. The inhibitory effect of osmophi...

  2. Study of thermal-gradient-induced migration of brine inclusions in salt. Final report

    International Nuclear Information System (INIS)

    Olander, D.R.

    1984-08-01

    Natural salt deposits, which are being considered for high-level waste disposal, contain a small volume fraction of water in the form of brine inclusions distributed throughout the salt. Radioactive decay heating of the nuclear wastes will impose a temperature gradient on the surrounding salt which mobilizes the brine inclusions. Inclusions filled completely with brine (the all-liquid inclusions) migrate up the temperature gradient and eventually accumulate brine near the buried waste forms. The brine may slowly corrode or degrade the waste forms, which is undesirable. Therefore it is important to consider the migration of brine inclusions in salt under imposed temperature gradients to properly evaluate the performance of a future salt repository for nuclear wastes. The migration velocities of the inclusions were found to be dependent on temperature, temperature gradient, and inclusion shape and size. The velocities were also dictated by the interfacial mass transfer resistance at brine/solid interface. This interfacial resistance depends on the dislocation density in the crystal, which in turn, depends on the axial compressive loading of the crystal. At low axial loads, the dependence between the velocity and temperature gradient is nonlinear. At high axial loads, the interfacial resistance is reduced and the migration velocity depends linearly on the temperature gradient. All-liquid inclusions filled with mixed brines were also studied. For gas-liquid inclusions, helium, air and argon were compared. Migration studies were also conducted on single crystallites of natural salt as well as in polycrystalline natural salt samples. The behavior of the inclusions at large-ange grain boundaries was observed

  3. Study of thermal-gradient-induced migration of brine inclusions in salt. Final report

    Energy Technology Data Exchange (ETDEWEB)

    Olander, D.R.

    1984-08-01

    Natural salt deposits, which are being considered for high-level waste disposal, contain a small volume fraction of water in the form of brine inclusions distributed throughout the salt. Radioactive decay heating of the nuclear wastes will impose a temperature gradient on the surrounding salt which mobilizes the brine inclusions. Inclusions filled completely with brine (the all-liquid inclusions) migrate up the temperature gradient and eventually accumulate brine near the buried waste forms. The brine may slowly corrode or degrade the waste forms, which is undesirable. Therefore it is important to consider the migration of brine inclusions in salt under imposed temperature gradients to properly evaluate the performance of a future salt repository for nuclear wastes. The migration velocities of the inclusions were found to be dependent on temperature, temperature gradient, and inclusion shape and size. The velocities were also dictated by the interfacial mass transfer resistance at brine/solid interface. This interfacial resistance depends on the dislocation density in the crystal, which in turn, depends on the axial compressive loading of the crystal. At low axial loads, the dependence between the velocity and temperature gradient is nonlinear. At high axial loads, the interfacial resistance is reduced and the migration velocity depends linearly on the temperature gradient. All-liquid inclusions filled with mixed brines were also studied. For gas-liquid inclusions, helium, air and argon were compared. Migration studies were also conducted on single crystallites of natural salt as well as in polycrystalline natural salt samples. The behavior of the inclusions at large-ange grain boundaries was observed.

  4. Nuclear waste repository simulation experiments (brine migration), Asse Mine of the Federal Republic of Germany: Quarterly brine migration data report, October--December 1985

    International Nuclear Information System (INIS)

    Eckert, J.L.; Kalia, H.N.; Coyle, A.J.

    1988-03-01

    The tenth brine migration data report describes experiments simulating a nuclear waste repository at the 800-m (2624-ft) level of the Asse Salt Mine in the Federal Republic of Germany from May 1983 through December 1985. This report describes the test equipment, the Asse Salt Mine, and the pretest properties of the salt in the test gallery. This report includes test data for 31 months of operations on brine migration rates, borehole pressure, salt temperatures and thermomechanical behavior of the salt. 3 refs., 118 figs., 93 tabs

  5. Quarterly brine migration data report, May-September 1983: Nuclear Waste Repository simulation experiments (brine migration), Asse Mine of the Federal Republic of Germany

    International Nuclear Information System (INIS)

    Coyle, A.J.; Kalia, H.N.; Eckert, J.L.

    1987-04-01

    The first quarterly brine migration data report describes experiments simulating a nuclear waste repository at the 800-m (2624-ft) level of the Asse Salt Mine in the Federal Republic of Germany from May 1983 through September 1983. This report describes the test equipment, the Asse Salt Mine, and the pretest properties of the salt in the test gallery. This report also includes test data for the first 4 months of operations on brine migration rates, borehole pressure, salt temperatures, and thermomechanical behavior of the salt. The duration of the experiments will be approximately 2 years, ending in December 1985. 83 figs., 55 tabs

  6. Recovery of energy from geothermal brine and other hot water sources

    Science.gov (United States)

    Wahl, III, Edward F.; Boucher, Frederic B.

    1981-01-01

    Process and system for recovery of energy from geothermal brines and other hot water sources, by direct contact heat exchange between the brine or hot water, and an immiscible working fluid, e.g. a hydrocarbon such as isobutane, in a heat exchange column, the brine or hot water therein flowing countercurrent to the flow of the working fluid. The column can be operated at subcritical, critical or above the critical pressure of the working fluid. Preferably, the column is provided with a plurality of sieve plates, and the heat exchange process and column, e.g. with respect to the design of such plates, number of plates employed, spacing between plates, area thereof, column diameter, and the like, are designed to achieve maximum throughput of brine or hot water and reduction in temperature differential at the respective stages or plates between the brine or hot water and the working fluid, and so minimize lost work and maximize efficiency, and minimize scale deposition from hot water containing fluid including salts, such as brine. Maximum throughput approximates minimum cost of electricity which can be produced by conversion of the recovered thermal energy to electrical energy.

  7. Surface Complexation Modeling of Calcite Zeta Potential Measurement in Mixed Brines for Carbonate Wettability Characterization

    Science.gov (United States)

    Song, J.; Zeng, Y.; Biswal, S. L.; Hirasaki, G. J.

    2017-12-01

    We presents zeta potential measurements and surface complexation modeling (SCM) of synthetic calcite in various conditions. The systematic zeta potential measurement and the proposed SCM provide insight into the role of four potential determining cations (Mg2+, SO42- , Ca2+ and CO32-) and CO2 partial pressure in calcite surface charge formation and facilitate the revealing of calcite wettability alteration induced by brines with designed ionic composition ("smart water"). Brines with varying potential determining ions (PDI) concentration in two different CO2 partial pressure (PCO2) are investigated in experiments. Then, a double layer SCM is developed to model the zeta potential measurements. Moreover, we propose a definition for contribution of charged surface species and quantitatively analyze the variation of charged species contribution when changing brine composition. After showing our model can accurately predict calcite zeta potential in brines containing mixed PDIs, we apply it to predict zeta potential in ultra-low and pressurized CO2 environments for potential applications in carbonate enhanced oil recovery including miscible CO2 flooding and CO2 sequestration in carbonate reservoirs. Model prediction reveals that pure calcite surface will be positively charged in all investigated brines in pressurized CO2 environment (>1atm). Moreover, the sensitivity of calcite zeta potential to CO2 partial pressure in the various brine is found to be in the sequence of Na2CO3 > Na2SO4 > NaCl > MgCl2 > CaCl2 (Ionic strength=0.1M).

  8. Concentrated Brine Treatment using New Energy in Coal Mine Evaporation Ponds

    Science.gov (United States)

    Li, Ting; Li, Jingfeng

    2017-12-01

    Recently, more and more coal mine water is being advanced treated and reused in China. The concentrated brine that results from advanced treatment methods can only be evaporated in an evaporation pond. Because of limited treatment capabilities and winter freezing, evaporation ponds often overflow, causing environment contamination. In this paper, based on analysis of brine water quality and economic-technical feasibility, we present a suitable treatment method for brine in evaporation ponds as electrodialysis using solar energy. In addition, we propose a new system to treat brine in coal mine evaporation ponds, which is powered by solar and wind. The operating efficiency of this treatment system proposed in this paper can meet the concentrated brine treatment demands in most coal mines in western mining areas of China and it places the photovoltaic power generation plates on the surface of the evaporation pond on a fixed floating island, which reduces any risk associated with land acquisition. This system can enhance brine treatment efficiency, requires a reduced evaporation pond area, increases the utilization of coal mine water, and minimizes the risk of environment contamination.

  9. Water Recovery from Brines to Further Close the Water Recovery Loop in Human Spaceflight

    Science.gov (United States)

    Jackson, W. Andrew; Barta, Daniel J.; Anderson, Molly S.; Lange, Kevin E.; Hanford, Anthony J.; Shull, Sarah A.; Carter, D. Layne

    2014-01-01

    Further closure of water recovery systems will be necessary for future long duration human exploration missions. NASA's Space Technology Roadmap for Human Health, Life Support and Habitation Systems specified a milestone to advance water management technologies during the 2015 to 2019 timeframe to achieve 98% H2O recovery from a mixed wastewater stream containing condensate, urine, hygiene, laundry, and water derived from waste. This goal can only be achieved by either reducing the amount of brines produced by a water recovery system or by recovering water from wastewater brines. NASA convened a Technical Interchange Meeting (TIM) on the topic of Water Recovery from Brines (WRB) that was held on January14-15th, 2014 at Johnson Space Center. Objectives of the TIM were to review systems and architectures that are sources of brines and the composition of brines they produce, review the state of the art in NASA technology development and perspectives from other industries, capture the challenges and difficulties in developing brine processing hardware, identify key figures of merit and requirements to focus technology development and evaluate candidate technologies, and identify other critical issues including microgravity sensitivity, and concepts of operation, safety. This paper represents an initial summary of findings from the workshop.

  10. Turbulence Statistics of a Buoyant Jet in a Stratified Environment

    Science.gov (United States)

    McCleney, Amy Brooke

    Using non-intrusive optical diagnostics, turbulence statistics for a round, incompressible, buoyant, and vertical jet discharging freely into a stably linear stratified environment is studied and compared to a reference case of a neutrally buoyant jet in a uniform environment. This is part of a validation campaign for computational fluid dynamics (CFD). Buoyancy forces are known to significantly affect the jet evolution in a stratified environment. Despite their ubiquity in numerous natural and man-made flows, available data in these jets are limited, which constrain our understanding of the underlying physical processes. In particular, there is a dearth of velocity field data, which makes it challenging to validate numerical codes, currently used for modeling these important flows. Herein, jet near- and far-field behaviors are obtained with a combination of planar laser induced fluorescence (PLIF) and multi-scale time-resolved particle image velocimetry (TR-PIV) for Reynolds number up to 20,000. Deploying non-intrusive optical diagnostics in a variable density environment is challenging in liquids. The refractive index is strongly affected by the density, which introduces optical aberrations and occlusions that prevent the resolution of the flow. One solution consists of using index matched fluids with different densities. Here a pair of water solutions - isopropanol and NaCl - are identified that satisfy these requirements. In fact, they provide a density difference up to 5%, which is the largest reported for such fluid pairs. Additionally, by design, the kinematic viscosities of the solutions are identical. This greatly simplifies the analysis and subsequent simulations of the data. The spectral and temperature dependence of the solutions are fully characterized. In the near-field, shear layer roll-up is analyzed and characterized as a function of initial velocity profile. In the far-field, turbulence statistics are reported for two different scales, one

  11. Origin and Evolution of Li-rich Brines at Clayton Valley, Nevada, USA

    Science.gov (United States)

    Munk, L. A.; Bradley, D. C.; Hynek, S. A.; Chamberlain, C. P.

    2011-12-01

    Lithium is the key component in Li-ion batteries which are the primary energy storage for electric/hybrid cars and most electronics. Lithium is also an element of major importance on a global scale because of interest in increasing reliance on alternative energy sources. Lithium brines and pegmatites are the primary and secondary sources, respectively of all produced Li. The only Li-brine in the USA that is currently in production exists in Clayton Valley, NV. The groundwater brines at Clayton Valley are located in a closed basin with an average evaporation rate of 142 cm/yr. The brines are pumped from six aquifer units that are composed of varying amounts of volcanic ash, gravel, salt, tufa, and fine-grained sediments. Samples collected include spring water, fresh groundwater, groundwater brine, and meteoric water (snow). The brines are classified as Na-Cl waters and the springs and fresh groundwater have a mixed composition and are more dilute than the brines. The Li content of the waters in Clayton Valley ranges from less than 1 μg/L (snow) up to 406.9 mg/L in the lower ash aquifer system (one of six aquifers in the basin). The cold springs surrounding Clayton Valley have Li concentrations of about 1 mg/L. A hot spring located just east of Clayton Valley contains 1.6 mg/L Li. The Li concentration of the fresh groundwater is less than 1 mg/L. Hot groundwater collected in the basin contain 30-40 mg/L Li. Water collected from a geothermal drilling north of Silver Peak, NV, had water with 4.9 mg/L Li at a depth of >1000m. The δD and δ18O isotopic signatures of fresh groundwater and brine form an evaporation path that extends from the global meteoric water line toward the brine from the salt aquifer system (the most isotopically enriched brine with ave. δD = -3.5, ave. δ18O = -67.0). This suggests that mixing of inflow water with the salt aquifer brine could have played an important role in the evolution of the brines. Along with mixing, evaporation appears to

  12. Thermophysical Properties of Aqueous Solutions Used as Secondary Working Fluids

    OpenAIRE

    Melinder, Åke

    2007-01-01

    Secondary working fluids (secondary refrigerants, heat transfer fluids, antifreezes, brines) have long been used in various indirect re-frigeration and heat pump systems. Aqueous solutions (water solu-tions) have long been used as single phase (liquid only) secondary working fluids for cooling in supermarkets, ice rinks, heat recovery systems, heat pumps and other applications. However, aqueous solutions are increasingly used also for freezers in supermarkets and other applications in low tem...

  13. The effect of existing turbulence on stratified shear instability

    Science.gov (United States)

    Kaminski, Alexis; Smyth, William

    2017-11-01

    Ocean turbulence is an essential process governing, for example, heat uptake by the ocean. In the stably-stratified ocean interior, this turbulence occurs in discrete events driven by vertical variations of the horizontal velocity. Typically, these events have been modelled by assuming an initially laminar stratified shear flow which develops wavelike instabilities, becomes fully turbulent, and then relaminarizes into a stable state. However, in the real ocean there is always some level of turbulence left over from previous events, and it is not yet understood how this turbulence impacts the evolution of future mixing events. Here, we perform a series of direct numerical simulations of turbulent events developing in stratified shear flows that are already at least weakly turbulent. We do so by varying the amplitude of the initial perturbations, and examine the subsequent development of the instability and the impact on the resulting turbulent fluxes. This work is supported by NSF Grant OCE1537173.

  14. Non-Darcy Mixed Convection in a Doubly Stratified Porous Medium with Soret-Dufour Effects

    Directory of Open Access Journals (Sweden)

    D. Srinivasacharya

    2014-01-01

    Full Text Available This paper presents the nonsimilarity solutions for mixed convection heat and mass transfer along a semi-infinite vertical plate embedded in a doubly stratified fluid saturated porous medium in the presence of Soret and Dufour effects. The flow in the porous medium is described by employing the Darcy-Forchheimer based model. The nonlinear governing equations and their associated boundary conditions are initially cast into dimensionless forms and then solved numerically. The influence of pertinent parameters on dimensionless velocity, temperature, concentration, heat, and mass transfer in terms of the local Nusselt and Sherwood numbers is discussed and presented graphically.

  15. Unsteady natural convection flow past an accelerated vertical plate in a thermally stratified fluid

    Directory of Open Access Journals (Sweden)

    Deka Rudra Kt.

    2009-01-01

    Full Text Available An exact solution to one-dimensional unsteady natural convection flow past an infinite vertical accelerated plate, immersed in a viscous thermally stratified fluid is investigated. Pressure work term and the vertical temperature advection are considered in the thermodynamic energy equation. The dimensionless governing equations are solved by Laplace Transform techniques for the Prandtl number unity. The velocity and temperature profiles as well as the skin-friction and the rate of heat transfer are presented graphically and discussed the effects of the Grashof number Gr, stratification parameter S at various times t.

  16. Mixed convection boundary layer flow over a vertical surface embedded in a thermally stratified porous medium

    International Nuclear Information System (INIS)

    Ishak, Anuar; Nazar, Roslinda; Pop, Ioan

    2008-01-01

    The mixed convection boundary layer flow through a stable stratified porous medium bounded by a vertical surface is investigated. The external velocity and the surface temperature are assumed to vary as x m , where x is measured from the leading edge of the vertical surface and m is a constant. Numerical solutions for the governing Darcy and energy equations are obtained. The results indicate that the thermal stratification significantly affects the surface shear stress as well as the surface heat transfer, besides delays the boundary layer separation

  17. West Hackberry Strategic Petroleum Reserve site brine-disposal monitoring, Year I report. Volume III. Biological oceanography. Final report

    Energy Technology Data Exchange (ETDEWEB)

    DeRouen, L.R.; Hann, R.W.; Casserly, D.M.; Giammona, C.; Lascara, V.J. (eds.)

    1983-02-01

    The Department of Energy's Strategic Petroleum Reserve Program began discharging brine into the Gulf of Mexico from its West Hackberry site near Cameron, Louisiana in May 1981. The brine originates from underground salt domes being leached with water from the Intracoastal Waterway, making available vast underground storage caverns for crude oil. The effects of brine discharge on aquatic organisms are presented in this volume. The topics covered are: benthos; nekton; phytoplankton; zooplankton; and data management.

  18. Sorption of cesium and strontium from concentrated brines by backfill barrier materials

    International Nuclear Information System (INIS)

    Winslow, C.D.

    1981-03-01

    The sorption of radionuclides from potentially intruding groundwater at a nuclear waste repository is a major chemical function of backfill barriers. In this study, various materials (including clays, zeolites and an inorganic ion exchanger) were screened for the sorption of the fission products cesium and strontium in concentrated brines. Representative brines A and B for the Waste Isolation Pilot Plant (WIPP), a proposed radioactive waste repository and test facility in bedded salt were used. Sorption properties were quantified using empirical distribution coefficients, k/sub d/. Of the materials examined, sodium titanate had the highest k/sub d/ for the sorption of Sr(II) in both brine A (k/sub d/ = 125 ml/g) and brine B(k/sub d/ = 500 to 600 ml/g). A mordenite-type zeolite was the most effective getter for Cs(I) in brine A (k/sub d = 27 ml/g), while illite yielded the highest k/sub d/ for Cs(I) in brine B (k/sub d/ = 115 ml/g). The relative merit of these k/sub d/ values is evaluated in terms of calculated estimates of breakthrough times for a backfill barrier containing the getter. Results show that a backfill mixture containing these getters is potentially an effective barrier to the migration of Sr(II) and Cs(I), although further study (especially for the sorption of cesium from brine A) is recommended. Initial mechanistic studies revealed competing ion effects which would support an ion exchange mechanism. K/sub d/'s were constant over a Sr(II) concentration range of 10 -11 to 10 -5 M and a Cs(I) concentration range of 10 -8 to 10 -5 M, supporting the choice of a linear sorption isotherm as a model for the results. Constant batch composition was shown to be attained within one week

  19. Aerobic methanotrophic communities at the Red Sea brine-seawater interface

    Directory of Open Access Journals (Sweden)

    Rehab Z. Abdallah

    2014-09-01

    Full Text Available The central rift of the Red Sea contains 25 brine pools with different physicochemical conditions, dictating the diversity and abundance of the microbial community. Three of these pools, the Atlantis II, Kebrit and Discovery Deeps, are uniquely characterized by a high concentration of hydrocarbons. The brine-seawater interface, described as an anoxic-oxic (brine-seawater boundary, is characterized by a high methane concentration, thus favoring aerobic methane oxidation. The current study analyzed the aerobic free–living methane-oxidizing bacterial communities that potentially contribute to methane oxidation at the brine-seawater interfaces of the three aforementioned brine pools, using metagenomic pyrosequencing, 16S rRNA pyrotags and pmoA library constructs. The sequencing of 16S rRNA pyrotags revealed that these interfaces are characterized by high microbial community diversity. Signatures of aerobic methane-oxidizing bacteria were detected in the Atlantis II Interface (ATII-I and the Kebrit Deep Upper (KB-U and Lower (KB-L brine-seawater interfaces. Through phylogenetic analysis of pmoA, we further demonstrated that the ATII-I aerobic methanotroph community is highly diverse. We propose four ATII-I pmoA clusters. Most importantly, cluster 2 groups with marine methane seep methanotrophs, and cluster 4 represent a unique lineage of an uncultured bacterium with divergent alkane monooxygenases. Moreover, non-metric multidimensional scaling (NMDS based on the ordination of putative enzymes involved in methane metabolism showed that the Kebrit interface layers were distinct from the ATII-I and DD-I brine-seawater interfaces.

  20. Numerical studies of CO2 and brine leakage into a shallow aquifer through an open wellbore

    Science.gov (United States)

    Wang, Jingrui; Hu, Litang; Pan, Lehua; Zhang, Keni

    2018-03-01

    Industrial-scale geological storage of CO2 in saline aquifers may cause CO2 and brine leakage from abandoned wells into shallow fresh aquifers. This leakage problem involves the flow dynamics in both the wellbore and the storage reservoir. T2Well/ECO2N, a coupled wellbore-reservoir flow simulator, was used to analyze CO2 and brine leakage under different conditions with a hypothetical simulation model in water-CO2-brine systems. Parametric studies on CO2 and brine leakage, including the salinity, excess pore pressure (EPP) and initially dissolved CO2 mass fraction, are conducted to understand the mechanism of CO2 migration. The results show that brine leakage rates increase proportionally with EPP and inversely with the salinity when EPP varies from 0.5 to 1.5 MPa; however, there is no CO2 leakage into the shallow freshwater aquifer if EPP is less than 0.5 MPa. The dissolved CO2 mass fraction shows an important influence on the CO2 plume, as part of the dissolved CO2 becomes a free phase. Scenario simulation shows that the gas lifting effect will significantly increase the brine leakage rate into the shallow freshwater aquifer under the scenario of 3.89% dissolved CO2 mass fraction. The equivalent porous media (EPM) approach used to model the wellbore flow has been evaluated and results show that the EPM approach could either under- or over-estimate brine leakage rates under most scenarios. The discrepancies become more significant if a free CO2 phase evolves. Therefore, a model that can correctly describe the complex flow dynamics in the wellbore is necessary for investigating the leakage problems.

  1. State-of-the-art review of brine migration studies in salt. Technical memorandum report RSI-0075

    International Nuclear Information System (INIS)

    Gnirk, P.F.; Krause, W.B.; Fossum, A.F.

    1981-09-01

    This report provides a state-of-the-art review of brine migration studies in rock salt. Emphasis is placed on the review of literature relating to brine migration phenomena around nuclear waste canisters. This review includes experimental work which has been conducted in the laboratory and in the field. In addition to the literature review, some additional thoughts on brine migration are given and a series of laboratory experiments is proposed. The proposed laboratory experiments are designed to determine whether or not a relationship exists between brine migration and temperature, temperature gradient and stress in rock salt. 34 references, 9 figures, 3 tables

  2. Large eddy simulation of turbulent and stably-stratified flows

    International Nuclear Information System (INIS)

    Fallon, Benoit

    1994-01-01

    The unsteady turbulent flow over a backward-facing step is studied by mean of Large Eddy Simulations with structure function sub grid model, both in isothermal and stably-stratified configurations. Without stratification, the flow develops highly-distorted Kelvin-Helmholtz billows, undergoing to helical pairing, with A-shaped vortices shed downstream. We show that forcing injected by recirculation fluctuations governs this oblique mode instabilities development. The statistical results show good agreements with the experimental measurements. For stably-stratified configurations, the flow remains more bi-dimensional. We show with increasing stratification, how the shear layer growth is frozen by inhibition of pairing process then of Kelvin-Helmholtz instabilities, and the development of gravity waves or stable density interfaces. Eddy structures of the flow present striking analogies with the stratified mixing layer. Additional computations show the development of secondary Kelvin-Helmholtz instabilities on the vorticity layers between two primary structures. This important mechanism based on baroclinic effects (horizontal density gradients) constitutes an additional part of the turbulent mixing process. Finally, the feasibility of Large Eddy Simulation is demonstrated for industrial flows, by studying a complex stratified cavity. Temperature fluctuations are compared to experimental measurements. We also develop three-dimensional un-stationary animations, in order to understand and visualize turbulent interactions. (author) [fr

  3. Bacterial production, protozoan grazing, and mineralization in stratified Lake Vechten

    NARCIS (Netherlands)

    Bloem, J.

    1989-01-01

    The role of heterotrophic nanoflagellates (HNAN, size 2-20 μm) in grazing on bacteria and mineralization of organic matter in stratified Lake Vechten was studied.

    Quantitative effects of manipulation and fixation on HNAN were checked. Considerable losses were caused by

  4. The dynamics of small inertial particles in weakly stratified turbulence

    NARCIS (Netherlands)

    van Aartrijk, M.; Clercx, H.J.H.

    We present an overview of a numerical study on the small-scale dynamics and the large-scale dispersion of small inertial particles in stably stratified turbulence. Three types of particles are examined: fluid particles, light inertial particles (with particle-to-fluid density ratio 1Ͽp/Ͽf25) and

  5. Dispersion of (light) inertial particles in stratified turbulence

    NARCIS (Netherlands)

    van Aartrijk, M.; Clercx, H.J.H.; Armenio, Vincenzo; Geurts, Bernardus J.; Fröhlich, Jochen

    2010-01-01

    We present a brief overview of a numerical study of the dispersion of particles in stably stratified turbulence. Three types of particles arc examined: fluid particles, light inertial particles ($\\rho_p/\\rho_f = \\mathcal{O}(1)$) and heavy inertial particles ($\\rho_p/\\rho_f \\gg 1$). Stratification

  6. Stability of Miscible Displacements Across Stratified Porous Media

    Energy Technology Data Exchange (ETDEWEB)

    Shariati, Maryam; Yortsos, Yanis C.

    2000-09-11

    This report studied macro-scale heterogeneity effects. Reflecting on their importance, current simulation practices of flow and displacement in porous media were invariably based on heterogeneous permeability fields. Here, it was focused on a specific aspect of such problems, namely the stability of miscible displacements in stratified porous media, where the displacement is perpendicular to the direction of stratification.

  7. On Internal Waves in a Density-Stratified Estuary

    NARCIS (Netherlands)

    Kranenburg, C.

    1991-01-01

    In this article some field observations, made in recent years, of internal wave motions in a density-stratified estuary are presented, In order to facilitate the appreciation of the results, and to make some quantitative comparisons, the relevant theory is also summarized. Furthermore, the origins

  8. FDTD scattered field formulation for scatterers in stratified dispersive media.

    Science.gov (United States)

    Olkkonen, Juuso

    2010-03-01

    We introduce a simple scattered field (SF) technique that enables finite difference time domain (FDTD) modeling of light scattering from dispersive objects residing in stratified dispersive media. The introduced SF technique is verified against the total field scattered field (TFSF) technique. As an application example, we study surface plasmon polariton enhanced light transmission through a 100 nm wide slit in a silver film.

  9. Plane Stratified Flow in a Room Ventilated by Displacement Ventilation

    DEFF Research Database (Denmark)

    Nielsen, Peter Vilhelm; Nickel, J.; Baron, D. J. G.

    2004-01-01

    The air movement in the occupied zone of a room ventilated by displacement ventilation exists as a stratified flow along the floor. This flow can be radial or plane according to the number of wall-mounted diffusers and the room geometry. The paper addresses the situations where plane flow...

  10. Dual Spark Plugs For Stratified-Charge Rotary Engine

    Science.gov (United States)

    Abraham, John; Bracco, Frediano V.

    1996-01-01

    Fuel efficiency of stratified-charge, rotary, internal-combustion engine increased by improved design featuring dual spark plugs. Second spark plug ignites fuel on upstream side of main fuel injector; enabling faster burning and more nearly complete utilization of fuel.

  11. Prognosis research strategy (PROGRESS) 4: Stratified medicine research

    NARCIS (Netherlands)

    A. Hingorani (Aroon); D.A.W.M. van der Windt (Daniëlle); R.D. Riley (Richard); D. Abrams; K.G.M. Moons (Karel); E.W. Steyerberg (Ewout); S. Schroter (Sara); W. Sauerbrei (Willi); D.G. Altman (Douglas); H. Hemingway; A. Briggs (Andrew); N. Brunner; P. Croft (Peter); J. Hayden (Jill); P.A. Kyzas (Panayiotis); N. Malats (Núria); G. Peat; P. Perel (Pablo); I. Roberts (Ian); A. Timmis (Adam)

    2013-01-01

    textabstractIn patients with a particular disease or health condition, stratified medicine seeks to identify thosewho will have the most clinical benefit or least harm from a specific treatment. In this article, thefourth in the PROGRESS series, the authors discuss why prognosis research should form

  12. The brine shrimp Artemia: adapted to critical life conditions

    Directory of Open Access Journals (Sweden)

    Gonzalo M Gajardo

    2012-06-01

    Full Text Available The brine shrimp Artemia is a micro-crustacean, well adapted to the harsh conditions that severely hypersaline environments impose on survival and reproduction. Adaptation to these conditions has taken place at different functional levels or domains, from the individual (molecular-cellular-physiological to the population level. Such conditions are experienced by very few equivalent macro-planktonic organisms; thus, Artemia can be considered a model animal extremophile offering a unique suite of adaptations that are the focus of this review. The most obvious is a highly efficient osmoregulation system to withstand up to 10 times the salt concentration of ordinary seawater. Under extremely critical environmental conditions, for example when seasonal lakes dry out, Artemia takes refuge by producing a highly resistant encysted gastrula embryo (cyst capable of severe dehydration enabling an escape from population extinction. Cysts can be viewed as gene banks that store a genetic memory of historical population conditions. Their occurrence is due to the evolved ability of females to perceive forthcoming unstable environmental conditions expressed by their ability to switch reproductive mode, producing either cysts (oviparity when environmental conditions become deleterious or free-swimming nauplii (ovoviviparity that are able to maintain the population under suitable conditions.At the population level the trend is for conspecific populations to be fragmented into locally adapted populations, whereas species are restricted to salty lakes in particular regions (regional endemism. The Artemia model depicts adaptation as a complex response to critical life conditions, integrating and refining past and present experiences at all levels of organization. Although we consider an invertebrate restricted to a unique environment, the processes to be discussed are of general biological interest. Finally, we highlight the benefits of understanding the stress

  13. Acute toxicity, brine shrimp cytotoxicity and relaxant activity of fruits of callistemon citrinus curtis

    Directory of Open Access Journals (Sweden)

    Shah Ismail

    2011-10-01

    Full Text Available Abstract Background Callistemon citrinus Curtis belongs to family Myrtaceae that has a great medicinal importance. In our previous work, fruits of Callistemon citrinus were reported to have relaxant (antispasmodic activity. The current work describes the screening of fractions of the crude methanol extract for tracing spasmolytic constituents so that it shall help us for isolation of bioactive compounds. Acute toxicity and brine shrimp cytotoxicity of crude methanol extract are also performed to standardize it. Methods The crude methanol extract was obtained by maceration with distilled water (500 ml three times and fractionated successively with n-hexane, chloroform, ethyl acetate and n-butanol (300 ml of each solvent. Phytochemical analysis for crude methanol extract was performed. Acute toxicity studies were performed in mice. Brine shrimp cytotoxicity studies were performed to determine its cytotoxicity and standardize it. In other series of experiments, rabbits' jejunum preparations were used in screening for possible relaxant activities of various fractions. They were applied in concentrations of 0.01, 0.03, 0.1, 0.3, 1.0, 3.0, 5.0 and 10.0 mg/ml on spontaneous rabbits' jejunum preparations. In similar fashion, fractions were also tested on KCl (80 mM -induced contractions. Calcium chloride curves were constructed in K-rich Tyrode's solution. The effects of various fractions were tested on calcium chloride curves at concentrations 1.0, 3.0, 5.0 and 10.0 mg/ml. Curves of verapamil used as reference drug at concentration 0.1 μM and 0.3 μM were also constructed. The curves were compared with their respective controls for possible right shift. Results Methanol extract tested strongly positive for saponins and tannins. However, it tested mild positive for presence of proteins, amino acids, carbohydrates and phenolic compounds. LD50 value for crude methanol extract is 476.25 ± 10.3 (470-481, n = 4 mg/ml. Similarly, EC50 value for brine shrimp

  14. Near-field environment research at PNL relevant to brine migration phenomena

    International Nuclear Information System (INIS)

    Pederson, L.R.; Gray, W.J.; Hodges, F.N.

    1987-01-01

    Heat and radiation resulting from emplacement of a high level nuclear waste package in a repository in salt will cause physical and chemical changes in the host rock and any brines present. These changes may alter the performance of waste package materials. Gamma radiolysis decomposes water into hydrogen and oxygen, hydrogen peroxide, and various other free radical and ionic species. Gamma ray irradiation of rock salt decomposes that salt to sodium metal colloids and neutral chlorine (unknown form), changing both its physical and chemical properties. Sodium metal will react, if contacted by water, to form sodium hydroxide plus hydrogen gas, while chlorine will react to form hydrochloric plus hypochlorous acids. If irradiated salts are completely dissolved, little impact on the chemical environment is expected because the acids and bases formed will neutralize each other. Heat from the waste package can alter the chemistry of the host rock. Changes in temperature can also alter the chemistry of brines by precipitation of phases with retrograde solubility, addition of more soluble salt components to the brine, and by reaction with clays and other impurities in the salt. Some of these reactions could be accompanied by significant shifts in the pH. In experiments to date, no important changes in chemistry have been observed when typical Permian Basin intrusion or inclusion brines were heated up to 150 0 C with no excess site-specific salt present. When excess salt was included, acidic shifts were noted, increasing with brine-salt interaction time and temperature

  15. Sorption-reagent treatment of brines produced by reverse osmosis unit for liquid radioactive waste management

    International Nuclear Information System (INIS)

    Avramenko, V. A.; Zheleznov, V. V.; Sergienko, V. I.; Chizhevsky, I. Yu

    2003-01-01

    The results of the pilot plant tests (2002-2003) of the sorption-reagent decontamination of high salinity radioactive waste (brines) remaining after the low-salinity liquid radioactive waste (LRW) treatment in the reverse-osmosis unit from long-lived radionuclides are presented. The sorption-reagent materials used in this work were developed in the Institute of Chemistry FEDRAS. They enable one to decontaminate brines with total salt content up to 50 g/l from long-lived radionuclides of Cs, Sr and Co. At joint application of the reverse-osmosis and sorption-reagent technologies total volume of solid radioactive waste (SRW) decreases up to 100-fold as compared to the technology of cementation of reverse osmosis brines. In this case total cost of LRW treatment and SRW disposal decreases more than 10-fold. Brines decontaminated from radionuclides are then diluted down to the ecologically safe total salts content in water to be disposed of. Tests were performed to compare the efficiency of technologies including evaporation of brines remaining after reverse osmosis process and their decontamination by means of the sorption-reagent method. It was shown that, as compared to evaporation, the sorption-reagent technology provides substantial advantages as in regard to radioactive waste total volume reduction as in view of total cost of the waste management

  16. Design calculations for a combined ventilation and brine injection experiment at the Grimsel Rock Laboratory, Switzerland

    International Nuclear Information System (INIS)

    Finsterle, S.; Pruess, K.

    1993-07-01

    A combined ventilation and brine injection test is planned at the Grimsel Test Site. The objective of the experiment is to study the transport of liquid and gas in the vicinity of a ventilated drift in order to evaluate the impact of the drying process on the characterization of the rock matrix. The proposed test sequence includes a desaturation-resaturation cycle. In addition, brine and fresh water will be injected from a borehole as trace electrolytes in order to better track the propagation of the individual phases. Results of design calculations using the TOUGH2 code show that injection of brine may significantly influence the unsaturated flow behavior by changing the pressure and saturation distribution around the borehole. Transport velocity is predicted to be very slow, requiring several months for the brine to reach the draft wall. However, the presence of preferential flow paths may reduce travel time and alter brine content and saturation distribution so that certain sensors may respond earlier or not at all

  17. Recovery of Lithium from Geothermal Brine with Lithium-Aluminum Layered Double Hydroxide Chloride Sorbents.

    Science.gov (United States)

    Paranthaman, Mariappan Parans; Li, Ling; Luo, Jiaqi; Hoke, Thomas; Ucar, Huseyin; Moyer, Bruce A; Harrison, Stephen

    2017-11-21

    We report a three-stage bench-scale column extraction process to selectively extract lithium chloride from geothermal brine. The goal of this research is to develop materials and processing technologies to improve the economics of lithium extraction and production from naturally occurring geothermal and other brines for energy storage applications. A novel sorbent, lithium aluminum layered double hydroxide chloride (LDH), is synthesized and characterized with X-ray powder diffraction, scanning electron microscopy, inductively coupled plasma optical emission spectrometry (ICP-OES), and thermogravimetric analysis. Each cycle of the column extraction process consists of three steps: (1) loading the sorbent with lithium chloride from brine; (2) intermediate washing to remove unwanted ions; (3) final washing for unloading the lithium chloride ions. Our experimental analysis of eluate vs feed concentrations of Li and competing ions demonstrates that our optimized sorbents can achieve a recovery efficiency of ∼91% and possess excellent Li apparent selectivity of 47.8 compared to Na ions and 212 compared to K ions, respectively in the brine. The present work demonstrates that LDH is an effective sorbent for selective extraction of lithium from brines, thus offering the possibility of effective application of lithium salts in lithium-ion batteries leading to a fundamental shift in the lithium supply chain.

  18. Geochemical evaluation of flowback brine from Marcellus gas wells in Pennsylvania, USA

    International Nuclear Information System (INIS)

    Haluszczak, Lara O.; Rose, Arthur W.; Kump, Lee R.

    2013-01-01

    Large quantities of highly saline brine flow from gas wells in the Marcellus Formation after hydraulic stimulation (“fracking”). This study assesses the composition of these flowback waters from the Marcellus shale in Pennsylvania, USA. Concentrations of most inorganic components of flowback water (Cl, Br, Na, K, Ca, Mg, Sr, Ba, Ra, Fe, Mn, total dissolved solids, and others) increase with time from a well after hydraulic stimulation. Based on results in several datasets reported here, the greatest concentration of Cl − in flowback water is 151,000 mg/L. For total Ra (combined 226 Ra and 228 Ra) in flowback, the highest level reported is 6540 pCi/L. Flowback waters from hydraulic fracturing of Marcellus wells resemble brines produced from conventional gas wells that tap into other Paleozoic formations in the region. The Br/Cl ratio and other parameters indicate that both types of brine formed by the evaporation of seawater followed by dolomitization, sulfate reduction and subsurface mixing with seawater and/or freshwater. Trends and relationships in brine composition indicate that (1) increased salt concentration in flowback is not mainly caused by dissolution of salt or other minerals in rock units, (2) the flowback waters represent a mixture of injection waters with highly concentrated in situ brines similar to those in the other formations, and (3) these waters contain concentrations of Ra and Ba that are commonly hundreds of times the US drinking water standards.

  19. Fate of Brine Applied to Unpaved Roads at a Radioactive Waste Subsurface Disposal Area

    International Nuclear Information System (INIS)

    Larry C. Hull; Carolyn W. Bishop

    2004-01-01

    Between 1984 and 1993, MgCl 2 brine was used to suppress dust on unpaved roads at a radioactive waste subsurface disposal area. Because Cl - might enhance corrosion of buried metals in the waste, we investigated the distribution and fate of Cl - in the vadose zone using pore water samples collected from suction lysimeters and soluble salt concentrations extracted from sediment samples. The Cl/Br mass ratio and the total dissolved Cl - concentration of pore water show that brine contamination occurs primarily within 13 m of treated roads, but can extend as much as 30 m laterally in near-surface sedimentary deposits. Within the deep vadose zone, which consists of interlayered basalt lava flows and sedimentary interbeds, brine has moved up to 110 m laterally. This lateral migration suggests formation of perched water and horizontal transport during periods of high recharge. In a few locations, brine migrated to depths of 67 m within 3 to 5 yr. Elevated Cl - concentrations were found to depths of 2 m in roadbed material. In drainage ditches along roads, where runoff accumulates and recharge of surface water is high, Cl - was flushed from the sediments in 3 to 4 yr. In areas of lower recharge, Cl - remained in the sediments after 5 yr. Vertical brine movement is directly related to surface recharge through sediments. The distribution of Cl - in pore water and sediments is consistent with estimates of vadose zone residence times and spatial distribution of surface water recharge from other investigations at the subsurface disposal area

  20. Effects of gamma radiation on the survival and growth of brine shrimp, Artemia salina

    International Nuclear Information System (INIS)

    Engel, D.W.; Davis, E.M.

    1976-01-01

    To determine the effects of gamma radiation on the survival and growth of brine shrimp, nauplii and adults were exposed to different doses of radiation and maintained at different salinities and temperatures. The LD 50 determination demonstrated that nauplii were thirty to forty times more sensitive than the adults and had a 25-day LD 50 of 450 rads. Radiation and salinity reduced survival of adult female brine shrimp more than the males. The interaction of salinity, 5 and 50 ppt, temperature, 10, 20 and 30 0 C, and radiation, 25 to 100 kilorads, decreased the survival of both male and female brine shrimp, with the males having the greater sensitivity. Brine shrimp nauplii irradiated with doses of 500 and 2,500 rads had accelerated growth and matured earlier than the controls. A test of the effect of crowding on growth showed that volume per individual was important, and a dose of 500 rads accelerated brine shrimp growth in all concentrations, with the greatest increase at 8 ml/nauplius

  1. Shale-brine-CO2 interactions and the long-term stability of carbonate-rich shale caprock

    Science.gov (United States)

    Ilgen, A.; Aman, M.; Espinoza, D. N.; Rodriguez, M. A.; Griego, J.; Dewers, T. A.; Feldman, J.; Stewart, T.; Choens, R. C., II

    2017-12-01

    Geological carbon storage (GCS) requires an impermeable caprock (e.g., shale) that prevents the upward migration and escape of carbon dioxide (CO2) from the subsurface. Geochemical alteration can occur at the caprock-reservoir rock interface, which could lead to the altering of the rock's mechanical properties, compromising the seal. We performed laboratory experiments on Mancos shale to quantify the coupled chemical-mechanical response of carbonate-rich shale in CO2-brine mixtures at conditions typical to GCS. We constructed geochemical models, calibrated them using laboratory results, and extended to time scales required for GCS. We observed the dissolution of calcite and kaolinite and the precipitation of gypsum and amorphous aluminum (hydr)oxide following the introduction of CO2. To address whether this mineral alteration causes changes in micro-mechanical properties, we examined altered Mancos shale using micro-mechanical (scratch) testing, measuring the scratch toughness of mm-scale shale lithofacies. The quartz-rich regions of the Mancos shale did not show significant changes in scratch toughness following 1-week alteration in a CO2-brine mixture. However, the scratch toughness of the calcite-rich, originally softer regions decreased by about 50%. These observations illustrate a coupled and localized chemical-mechanical response of carbonate-rich shale to the injection of CO2. This suggests a localized weakening of the caprock may occur, potentially leading to the development of preferential flow paths. The identification of vulnerable lithofacies within caprock and a characterization of mineralogical heterogeneity is imperative at prospective GCS sites. Sandia National Laboratories is a multimission laboratory managed and operated by National Technology and Engineering Solutions of Sandia, LLC., a wholly owned subsidiary of Honeywell International, Inc., for the U.S. Department of Energy's National Nuclear Security Administration under contract DE

  2. High-rate nitrogen removal from waste brine by marine anammox bacteria in a pilot-scale UASB reactor.

    Science.gov (United States)

    Yokota, Nobuyuki; Watanabe, Yasutsugu; Tokutomi, Takaaki; Kiyokawa, Tomohiro; Hori, Tomoyuki; Ikeda, Daisuke; Song, Kang; Hosomi, Masaaki; Terada, Akihiko

    2018-02-01

    The goal of this study was to develop a startup strategy for a high-rate anaerobic ammonium oxidation (anammox) reactor to treat waste brine with high concentrations of ammonium from a natural gas plant. An upflow anaerobic sludge blanket (UASB) anammox reactor with an effective volume of 294 L was fed continuously with waste brine with a salinity of 3% and a NH 4 + concentration of 180 mg-N/L, as well as a NaNO 2 solution. By inoculating a methanogenic granular biomass as a biomass carrier, the reactor attained the maximum volumetric nitrogen removal rate (NRR) of 10.7 kg-N/m 3 /day on day 209, which was 1.7 times higher than the highest reported NRR for wastewater of comparable salinity. High-throughput sequencing of 16S rRNA gene amplicons revealed that Candidatus Scalindua wagneri was enriched successfully in granules in the UASB, and it replaced Methanosaeta and became dominant in the granule. The inhibitory effect of NO 2 - on the anammox reaction in the granules was assessed by a 15 N tracer method, and the results showed that anammox activity was maintained at 60% after exposure to 300 mg-N/L of NO 2 - for 24 h. Compared with previous studies of the susceptibilities of Candidatus Brocadia and Candidatus Kuenenia to NO 2 - , the enriched marine anammox bacteria were proven to have comparable or even higher tolerances for high NO 2 - concentrations after a long exposure.

  3. Exploring the role of wave drag in the stable stratified oceanic and atmospheric bottom boundary layer in the cnrs-toulouse (cnrm-game) large stratified water flume

    NARCIS (Netherlands)

    Kleczek, M.; Steeneveld, G.J.; Paci, A.; Calmer, R.; Belleudy, A.; Canonici, J.C.; Murguet, F.; Valette, V.

    2014-01-01

    This paper reports on a laboratory experiment in the CNRM-GAME (Toulouse) stratified water flume of a stably stratified boundary layer, in order to quantify the momentum transfer due to orographically induced gravity waves by gently undulating hills in a boundary layer flow. In a stratified fluid, a

  4. Interactive Fuzzy Goal Programming approach in multi-response stratified sample surveys

    Directory of Open Access Journals (Sweden)

    Gupta Neha

    2016-01-01

    Full Text Available In this paper, we applied an Interactive Fuzzy Goal Programming (IFGP approach with linear, exponential and hyperbolic membership functions, which focuses on maximizing the minimum membership values to determine the preferred compromise solution for the multi-response stratified surveys problem, formulated as a Multi- Objective Non Linear Programming Problem (MONLPP, and by linearizing the nonlinear objective functions at their individual optimum solution, the problem is approximated to an Integer Linear Programming Problem (ILPP. A numerical example based on real data is given, and comparison with some existing allocations viz. Cochran’s compromise allocation, Chatterjee’s compromise allocation and Khowaja’s compromise allocation is made to demonstrate the utility of the approach.

  5. Simulation of steam explosion in stratified melt-coolant configuration

    International Nuclear Information System (INIS)

    Leskovar, Matjaž; Centrih, Vasilij; Uršič, Mitja

    2016-01-01

    Highlights: • Strong steam explosions may develop spontaneously in stratified configurations. • Considerable melt-coolant premixed layer formed in subcooled water with hot melts. • Analysis with MC3D code provided insight into stratified steam explosion phenomenon. • Up to 25% of poured melt was mixed with water and available for steam explosion. • Better instrumented experiments needed to determine dominant mixing process. - Abstract: A steam explosion is an energetic fuel coolant interaction process, which may occur during a severe reactor accident when the molten core comes into contact with the coolant water. In nuclear reactor safety analyses steam explosions are primarily considered in melt jet-coolant pool configurations where sufficiently deep coolant pool conditions provide complete jet breakup and efficient premixture formation. Stratified melt-coolant configurations, i.e. a molten melt layer below a coolant layer, were up to now believed as being unable to generate strong explosive interactions. Based on the hypothesis that there are no interfacial instabilities in a stratified configuration it was assumed that the amount of melt in the premixture is insufficient to produce strong explosions. However, the recently performed experiments in the PULiMS and SES (KTH, Sweden) facilities with oxidic corium simulants revealed that strong steam explosions may develop spontaneously also in stratified melt-coolant configurations, where with high temperature melts and subcooled water conditions a considerable melt-coolant premixed layer is formed. In the article, the performed study of steam explosions in a stratified melt-coolant configuration in PULiMS like conditions is presented. The goal of this analytical work is to supplement the experimental activities within the PULiMS research program by addressing the key questions, especially regarding the explosivity of the formed premixed layer and the mechanisms responsible for the melt-water mixing. To

  6. Modeling gas and brine migration for assessing compliance of the Waste Isolation Pilot Plant

    International Nuclear Information System (INIS)

    Vaughn, P.; Butcher, B.; Helton, J.; Swift, P.

    1993-10-01

    At the request of the WIPP Project Integration Office (WPIO) of the DOE, the WIPP Performance Assessment (PA) Department of Sandia National Laboratories (SNL) has completed preliminary uncertainty and sensitivity analyses of gas and brine migration away from the undisturbed repository. This paper contains descriptions of the numerical model and simulations, including model geometries and parameter values, and a summary of major conclusions from sensitivity analyses. Because significant transport of contaminants can only occur in a fluid (gas or brine) medium, two-phase flow modeling can provide an estimate of the distance to which contaminants can migrate. Migration of gas or brine beyond the RCRA ''disposal-unit boundary'' or the Standard's accessible environment constitutes a potential, but not certain, violation and may require additional evaluations of contaminant concentrations

  7. Brine reuse in ion-exchange softening: salt discharge, hardness leakage, and capacity tradeoffs.

    Science.gov (United States)

    Flodman, Hunter R; Dvorak, Bruce I

    2012-06-01

    Ion-exchange water softening results in the discharge of excess sodium chloride to the aquatic environment during the regeneration cycle. In order to reduce sodium chloride use and subsequent discharge from ion-exchange processes, either brine reclaim operations can be implemented or salt application during regeneration can be reduced. Both result in tradeoffs related to loss of bed volumes treated per cycle and increased hardness leakage. An experimentally validated model was used to compare concurrent water softening operations at various salt application quantities with and without the direct reuse of waste brine for treated tap water of typical midwestern water quality. Both approaches were able to reduce salt use and subsequent discharge. Reducing salt use and discharge by lowering the salt application rate during regeneration consequently increased hardness leakage and decreased treatment capacity. Single or two tank brine recycling systems are capable of reducing salt use and discharge without increasing hardness leakage, although treatment capacity is reduced.

  8. In situ brine migration experiments at the Avery Island salt mine

    International Nuclear Information System (INIS)

    Krause, W.B.; Van Sambeek, L.L.; Stickney, R.G.

    1980-01-01

    An in situ brine movement study was conducted at the Avery Island Salt Mine of the International Salt Company in southwestern Louisiana. The objective of the in situ experiments was to relate field measurements to previously determined laboratory and analytical results for the purpose of determining the rate and amount of brine movement through dome salt when subjected to heating. The heating in the experiments was provided by electrical heaters emplaced in the salt mine floor. An understanding of thermally induced brine movement is essential from the standpoint of identifying conditions which may influence the physical integrity of the nuclear waste canisters or impede the functional performance of the waste package system in a nuclear waste repository in geologic salt. 28 refs

  9. Brine migration resulting from pressure increases in a layered subsurface system

    Science.gov (United States)

    Delfs, Jens-Olaf; Nordbeck, Johannes; Bauer, Sebastian

    2016-04-01

    Brine originating from the deep subsurface impairs parts of the freshwater resources in the North German Basin. Some of the deep porous formations (esp. Trias and Jurassic) exhibit considerable storage capacities for waste fluids (CO2, brine from oil production or cavern leaching), raising concerns among water providers that this type of deep subsurface utilization might impair drinking water supplies. On the one hand, overpressures induced by fluid injections and the geothermal gradient support brine migration from deep into shallow formations. On the other hand, the rising brine is denser than the surrounding less-saline formation waters and, therefore, tends to settle down. Aim of this work is to investigate the conditions under which pressurized formation brine from deep formations can reach shallow freshwater resources. Especially, the role of intermediate porous formations between the storage formation and the groundwater is studied. For this, complex thermohaline simulations using a coupled numerical process model are necessary and performed in this study, in which fluid density depends on fluid pressure, temperature and salt content and the governing partial differential equations are coupled. The model setup is 2D and contains a hypothetic series of aquifers and barriers, each with a thickness of 200 m. Formation pressure is increased at depths of about 2000 m in proximity to a salt wall and a permeable fault. The domain size reaches up to tens of kilometers horizontally to the salt wall. The fault connects the injection formation and the freshwater aquifer such that conditions can be considered as extremely favorable for induced brine migration (worst case scenarios). Brine, heat, and salt fluxes are quantified with reference to hydraulic permeabilities, storage capacities (in terms of domain size), initial salt and heat distribution, and operation pressures. The simulations reveal the development of a stagnation point in the fault region in each

  10. A deep sea community at the Kebrit brine pool in the Red Sea

    KAUST Repository

    Vestheim, Hege

    2015-02-26

    Approximately 25 deep sea brine pools occur along the mid axis of the Red Sea. These hypersaline, anoxic, and acidic environments have previously been reported to host diverse microbial communities. We visited the Kebrit brine pool in April 2013 and found macrofauna present just above the brine–seawater interface (~1465 m). In particular, inactive sulfur chimneys had associated epifauna of sea anemones, sabellid type polychaetes, and hydroids, and infauna consisting of capitellid polychaetes, gastropods of the genus Laeviphitus (fam. Elachisinidae), and top snails of the family Cocculinidae. The deep Red Sea generally is regarded as extremely poor in benthos. We hypothesize that the periphery along the Kebrit holds increased biomass and biodiversity that are sustained by prokaryotes associated with the brine pool or co-occurring seeps.

  11. Identification of major planktonic sulfur oxidizers in stratified freshwater lake.

    Directory of Open Access Journals (Sweden)

    Hisaya Kojima

    Full Text Available Planktonic sulfur oxidizers are important constituents of ecosystems in stratified water bodies, and contribute to sulfide detoxification. In contrast to marine environments, taxonomic identities of major planktonic sulfur oxidizers in freshwater lakes still remain largely unknown. Bacterioplankton community structure was analyzed in a stratified freshwater lake, Lake Mizugaki in Japan. In the clone libraries of 16S rRNA gene, clones very closely related to a sulfur oxidizer isolated from this lake, Sulfuritalea hydrogenivorans, were detected in deep anoxic water, and occupied up to 12.5% in each library of different water depth. Assemblages of planktonic sulfur oxidizers were specifically analyzed by constructing clone libraries of genes involved in sulfur oxidation, aprA, dsrA, soxB and sqr. In the libraries, clones related to betaproteobacteria were detected with high frequencies, including the close relatives of Sulfuritalea hydrogenivorans.

  12. Study of MRI in stratified viscous plasma configuration

    Science.gov (United States)

    Carlevaro, Nakia; Montani, Giovanni; Renzi, Fabrizio

    2017-02-01

    We analyze the morphology of the magneto-rotational instability (MRI) for a stratified viscous plasma disk configuration in differential rotation, taking into account the so-called corotation theorem for the background profile. In order to select the intrinsic Alfvénic nature of MRI, we deal with an incompressible plasma and we adopt a formulation of the local perturbation analysis based on the use of the magnetic flux function as a dynamical variable. Our study outlines, as consequence of the corotation condition, a marked asymmetry of the MRI with respect to the equatorial plane, particularly evident in a complete damping of the instability over a positive critical height on the equatorial plane. We also emphasize how such a feature is already present (although less pronounced) even in the ideal case, restoring a dependence of the MRI on the stratified morphology of the gravitational field.

  13. Mixing of stratified flow around bridge piers in steady current

    DEFF Research Database (Denmark)

    Jensen, Bjarne; Carstensen, Stefan; Christensen, Erik Damgaard

    2018-01-01

    This paper presents the results of an experimental and numerical investigation of the mixing of stratified flow around bridge pier structures. In this study, which was carried out in connection with the Fehmarnbelt Fixed Link environmental impact assessment, the mixing processes of two-layer stra......This paper presents the results of an experimental and numerical investigation of the mixing of stratified flow around bridge pier structures. In this study, which was carried out in connection with the Fehmarnbelt Fixed Link environmental impact assessment, the mixing processes of two......-layer stratification was studied in which the lower level had a higher salinity than the upper layer. The physical experiments investigated two different pier designs. A general study was made regarding forces on the piers in which the effect of the current angle relative to the structure was also included...

  14. Stratified charge rotary aircraft engine technology enablement program

    Science.gov (United States)

    Badgley, P. R.; Irion, C. E.; Myers, D. M.

    1985-01-01

    The multifuel stratified charge rotary engine is discussed. A single rotor, 0.7L/40 cu in displacement, research rig engine was tested. The research rig engine was designed for operation at high speeds and pressures, combustion chamber peak pressure providing margin for speed and load excursions above the design requirement for a high is advanced aircraft engine. It is indicated that the single rotor research rig engine is capable of meeting the established design requirements of 120 kW, 8,000 RPM, 1,379 KPA BMEP. The research rig engine, when fully developed, will be a valuable tool for investigating, advanced and highly advanced technology components, and provide an understanding of the stratified charge rotary engine combustion process.

  15. Analysis of photonic band-gap structures in stratified medium

    DEFF Research Database (Denmark)

    Tong, Ming-Sze; Yinchao, Chen; Lu, Yilong

    2005-01-01

    in electromagnetic and microwave applications once the Maxwell's equations are appropriately modeled. Originality/value - The method validates its values and properties through extensive studies on regular and defective 1D PBG structures in stratified medium, and it can be further extended to solving more......Purpose - To demonstrate the flexibility and advantages of a non-uniform pseudo-spectral time domain (nu-PSTD) method through studies of the wave propagation characteristics on photonic band-gap (PBG) structures in stratified medium Design/methodology/approach - A nu-PSTD method is proposed...... in solving the Maxwell's equations numerically. It expands the temporal derivatives using the finite differences, while it adopts the Fourier transform (FT) properties to expand the spatial derivatives in Maxwell's equations. In addition, the method makes use of the chain-rule property in calculus together...

  16. Biological screening of chitosan derivatives using Artemia spp. (brine shrimp test)

    International Nuclear Information System (INIS)

    Rozaini Mohd Zohdi; Norimah Yusof; Asnah Hassan

    2006-01-01

    The present study reported on the screening of six selected chitosan derivatives using the brine shrimp lethality bioassay. In addition, the irradiation effects towards the compounds at 25 kGy were also studied. Chitosan is a natural polysaccharide derived from chitin, extracted from the exoskeletons of crustaceans and insects as well as walls of some bacteria and fungi. Brine shrimp test is employed for the screening of toxicity of chitosan derivatives. Toxicity test was carried out by adding different concentrations of tested samples to approximately 5 to 15 Artemia salina larvae. Biological activity using the brine shrimp bioassay was recorded as LC 50 i.e. lethal concentration that kills 50% of the larvae within 24 hours of contact with the samples. Compounds are considered toxic when the LC 50 value is lower than 1 mg/ml by brine shrimp bioassay and practically non-toxic when the value is larger. Of the samples tested, none were toxic to the brine shrimp (LC 50 > 1 mg/ml). The LC 50 values of all chitosan derivatives tested, control and irradiated at 25 kGy were above 1 mg/ml thus all tested samples are considered non-toxic. This study demonstrated that irradiation at 25 kGy showed no significant effects towards the toxicity of the chitosan derivatives. After irradiation, only NO-CMC exhibited marked decrease in LC 50 value, reduced by 3-fold from 34.96 mg/ml to 11.07 mg/ml while O-CMC (5.45 mg/ml to 5 mg/ml) showed no clear differences based on rough estimation. This study suggested that brine shrimp bioassay is a simple, reliable and convenient method that could provide useful clues of the relative toxic potential of the sample tested. (Author)

  17. Community genomics among stratified microbial assemblages in the ocean's interior

    DEFF Research Database (Denmark)

    DeLong, Edward F; Preston, Christina M; Mincer, Tracy

    2006-01-01

    Microbial life predominates in the ocean, yet little is known about its genomic variability, especially along the depth continuum. We report here genomic analyses of planktonic microbial communities in the North Pacific Subtropical Gyre, from the ocean's surface to near-sea floor depths. Sequence......, and host-viral interactions. Comparative genomic analyses of stratified microbial communities have the potential to provide significant insight into higher-order community organization and dynamics....

  18. Large Eddy Simulation of stratified flows over structures

    OpenAIRE

    Brechler J.; Fuka V.

    2013-01-01

    We tested the ability of the LES model CLMM (Charles University Large-Eddy Microscale Model) to model the stratified flow around three dimensional hills. We compared the quantities, as the height of the dividing streamline, recirculation zone length or length of the lee waves with experiments by Hunt and Snyder[3] and numerical computations by Ding, Calhoun and Street[5]. The results mostly agreed with the references, but some important differences are present.

  19. Large Eddy Simulation of stratified flows over structures

    Directory of Open Access Journals (Sweden)

    Brechler J.

    2013-04-01

    Full Text Available We tested the ability of the LES model CLMM (Charles University Large-Eddy Microscale Model to model the stratified flow around three dimensional hills. We compared the quantities, as the height of the dividing streamline, recirculation zone length or length of the lee waves with experiments by Hunt and Snyder[3] and numerical computations by Ding, Calhoun and Street[5]. The results mostly agreed with the references, but some important differences are present.

  20. Large Eddy Simulation of stratified flows over structures

    Science.gov (United States)

    Fuka, V.; Brechler, J.

    2013-04-01

    We tested the ability of the LES model CLMM (Charles University Large-Eddy Microscale Model) to model the stratified flow around three dimensional hills. We compared the quantities, as the height of the dividing streamline, recirculation zone length or length of the lee waves with experiments by Hunt and Snyder[3] and numerical computations by Ding, Calhoun and Street[5]. The results mostly agreed with the references, but some important differences are present.

  1. Propagation of acoustic waves in a stratified atmosphere, 1

    Science.gov (United States)

    Kalkofen, W.; Rossi, P.; Bodo, G.; Massaglia, S.

    1994-01-01

    This work is motivated by the chromospheric 3 minute oscillations observed in the K(sub 2v) bright points. We study acoustic gravity waves in a one-dimensional, gravitationally stratified, isothermal atmosphere. The oscillations are excited either by a velocity pulse imparted to a layer in an atmosphere of infinite vertical extent, or by a piston forming the lower boundary of a semi-infinite medium. We consider both linear and non-linear waves.

  2. A statistical mechanics approach to mixing in stratified fluids

    OpenAIRE

    Venaille , Antoine; Gostiaux , Louis; Sommeria , Joël

    2016-01-01

    Accepted for the Journal of Fluid Mechanics; Predicting how much mixing occurs when a given amount of energy is injected into a Boussinesq fluid is a longstanding problem in stratified turbulence. The huge number of degrees of freedom involved in these processes renders extremely difficult a deterministic approach to the problem. Here we present a statistical mechanics approach yielding a prediction for a cumulative, global mixing efficiency as a function of a global Richard-son number and th...

  3. Sutudy on exchange flow under the unstably stratified field

    OpenAIRE

    文沢, 元雄

    2005-01-01

    This paper deals with the exchange flow under the unstably stratified field. The author developed the effective measurement system as well as the numerical analysis program. The system and the program are applied to the helium-air exchange flow in a rectangular channel with inclination. Following main features of the exchange flow were discussed based on the calculated results.(1) Time required for establishing a quasi-steady state exchange flow.(2) The relationship between the inclination an...

  4. Transport of Pb and Zn by carboxylate complexes in basinal ore fluids and related petroleum-field brines at 100°C: the influence of pH and oxygen fugacity

    Directory of Open Access Journals (Sweden)

    Giordano Thomas H

    2002-09-01

    can mobilize up to 3% of the total Pb and up to 1.3% of the total Zn as carboxylate complexes. Furthermore, these percentages, under the most favorable conditions, correspond to approximately 1 to 100 ppm of these metals in solution; concentrations that are adequate to form economic deposits of these metals. However, the field evidence suggests that all of these optimum conditions for carboxylate complexation are rarely met at the same time. A comparison of the composite ore fluid compositions from this study and modern brine data shows that the ore brines, corresponding to log –pH conditions based on the Anderson (1975 and Giordano (1994 model fluids, are similar in many respects to modern, high trace-metal petroleum-field brines. The principal differences between modern high trace-metal brines and the composite ore fluids of Anderson (1975 and Giordano (1994 relate to their carboxylate anion content. The reported concentrations of monocarboxylate anions (∑monocbx and dicarboxylate anions (Edicbx in high trace-metal petroleum-field brines (-1 and -1, respectively are significantly lower than the concentrations assumed in the modelled brines of this study (∑monocbx = 7 700 mg L-1 and ∑dicbx = 300 mg L-1. There are also major differences in the corresponding total chloride to carboxylate ratio (∑mCl/∑mcbx and monocarboxylate to dicarboxylate ratio (∑mmonocbx/∑mdicbx. Modern high trace-metal brines have much higher ∑mCl/∑mcbx values and, therefore, the contribution of carboxylate complexes to the total Pb and Zn content in these modern brines is likely to be significantly less than the 1 to 3 percent for the composite ore fluids of Anderson (1975 and Giordano (1994. The composite ore-brine based on the Giordano and Barnes (1981 MVT ore fluid is comparable to the high salinity (> 170 000 mg L-1 TDS subset of modern brines characterized by low trace-metal content and high total reduced sulfur (∑H2S. A comparison of the Sverjensky (1984 composite ore-brine

  5. Experimental Demonstration of the Formation of Liquid Brines under Martian Polar Conditions in the Michigan Mars Environmental Chamber

    Science.gov (United States)

    Fischer, Erik; Martinez, German; Elliott, Harvey; Borlina, Caue; Renno, Nilton

    2014-05-01

    observed within the Martian diurnal cycle. This greatly diminishes the possibility of liquid brine formation without water ice contact and has strong implications on future robotic and manned missions searching for liquid water on Mars. Acknowledgement: This research is supported by a grant from the NASA Astrobiology Program: Exobiology and Evolutionary Biology. Award #09-EXOB09-0050. References: [1] Martínez, G. M. and Renno, N. O. (2013), Water and Brines on Mars: Current Evidence and Implications for MSL, Space Sci. Rev., 175, 29-51. [2] Rennó, N. O., et al. (2009), Possible physical and thermodynamical evidence for liquid water at the Phoenix landing site, J. Geophys. Res., 114, E00E03. [3] Zorzano, M.-P., et al., Stability of liquid saline water on present day Mars, Geophys. Res. Lett., 36, L20201. [4] Hanley, J. et al. (2009), Low Temperature Aqueous Perchlorate Solutions on the Surface of Mars, Proceedings 40th Lunar and Planetary Sciences Conference, The Woodlands, TX, USA. [5] Marion, G. M. et al. (2010), Modeling Aqueous Perchlorate Chemistries with Applications to Mars, Icarus, 207, 675-685.

  6. Production and characterization of a functional Iranian white brined cheese by replacement of dairy fat with vegetable oils.

    Science.gov (United States)

    Achachlouei, B Fathi; Hesari, J; Damirchi, S Azadmard; Peighambardoust, Sh; Esmaiili, M; Alijani, S

    2013-10-01

    Full-fat cheese usually contains high amounts of saturated fatty acids and cholesterol, which may have negative health effects. In this study, full-fat white brined cheese, as a control sample, and experimental cheeses with olive and canola oils (T1, white brined cheese containing 50% canola oil, T2, white brined cheese containing 50% olive oil, T3, white brined cheese containing 100% canola oil and T4, white brined cheese containing 100% olive oil) were prepared from bovine milk. Physicochemical properties, lipolysis, proteolysis patterns and sensorial properties in the prepared samples were determined during 80 days of storage at 20-day intervals. Cheese incorporating vegetable oils showed lower amounts of saturated fatty acids and higher amounts of unsaturated fatty acids compared with the full-fat cheese (control) samples. Moisture, pH, lipolysis value, as assessed by the acid-degree value, and proteolysis values (pH 4.6 SN/TN% and NPN/TN%) significantly (p titrable acidity decreased during 40 days of ripening but then increased slightly. Sensory properties of white brined cheese incorporating with vegetable oils were different from those of full-fat cheese samples. White brined cheese containing olive and canola oils (100% fat substitution) received better sensory scores compared to other samples. The results showed that it is possible to replace dairy fat with olive and canola oils, which can lead to produce a new healthy and functional white brined cheese.

  7. Vertical distributions and speciation of dissolved rare earth elements in the anoxic brines of Bannock Basin, eastern Mediterranean Sea

    NARCIS (Netherlands)

    Schijf, Johan; Baar, Hein J.W. de; Millero, Frank J.; Byrne, R.H.

    1995-01-01

    Vertical distributions of dissolved rare earth elements (REEs) are presented for the anoxic, highly sulfidic brines of Bannock Basin in the eastern Mediterranean Sea. REE concentrations at the seawater-brine interface are the highest ever recorded in the water column of an anoxic basin and

  8. ASSESSMENT OF TECHNETIUM LEACHABILITY IN CEMENT STABILIZED BASIN 43 GROUNDWATER BRINE

    International Nuclear Information System (INIS)

    COOKE GA; DUNCAN JB; LOCKREM LL

    2008-01-01

    This report is an initial report on the laboratory effort executed under RPP-PLAN-33338, Test Plan for the Assessment of Technetium Leachability in Cement-Stabilized Basin 43 Groundwater Brine. This report delineates preliminary data obtained under subcontract 21065, release 30, from the RJ Lee Group, Inc., Center for Laboratory Sciences. The report is predicated on CLS RPT-816, Draft Report: Assessment of Technetium Leachability in Cement Stabilized Basin 43 Groundwater Brine. This document will be revised on receipt of the final RJ Lee Group, Inc., Center for Laboratory Sciences report, which will contain data subjected to quality control and quality assurance criteria

  9. Salting by vacuum brine impregnation in nitrite-free lonza: effect on Enterobacteriaceae

    Directory of Open Access Journals (Sweden)

    Annalisa Serio

    2017-01-01

    Full Text Available Lonza is a traditional Italian meat product made from whole pork muscles, which is typically cured by dry salting. In this work, we study the effects of vacuum brine impregnation (VBI as an alternative salting method on the survival of Enterobacteriaceae, in presence and in absence of nitrites. In comparison with the traditional brining process, VBI contributed to reducing the Enterobacteriaceae population on product surface but induced contamination of the inner muscle tissues. Our results suggest that the species isolated became adapted to processing conditions, and salt tolerance was species- or straindependent. This result is of particular importance for future applications of VBI in lonza manufacturing.

  10. Salting by Vacuum Brine Impregnation in Nitrite-Free Lonza: Effect on Enterobacteriaceae.

    Science.gov (United States)

    Serio, Annalisa; Chaves-López, Clemencia; Rossi, Chiara; Pittia, Paola; Rosa, Marco Dalla; Paparella, Antonello

    2017-01-24

    Lonza is a traditional Italian meat product made from whole pork muscles, which is typically cured by dry salting. In this work, we study the effects of vacuum brine impregnation (VBI) as an alternative salting method on the survival of Enterobacteriaceae, in presence and in absence of nitrites. In comparison with the traditional brining process, VBI contributed to reducing the Enterobacteriaceae population on product surface but induced contamination of the inner muscle tissues. Our results suggest that the species isolated became adapted to processing conditions, and salt tolerance was species- or strain-dependent. This result is of particular importance for future applications of VBI in lonza manufacturing.

  11. Antioxidant activities and functional properties of protein and peptide fractions isolated from salted herring brine

    DEFF Research Database (Denmark)

    Taheri, Ali; Farvin, Sabeena; Jacobsen, Charlotte

    2014-01-01

    In the present study proteins isolated from herring brine, which is a by-product of marinated herring production were evaluated for their functional properties and antioxidant activity. Herring brine was collected from the local herring industry and proteins were precipitated by adjusting the p...... to delay iron catalyzed lipid oxidation in 5% fish oil in water emulsions and the 10–50kDa fraction was the best. These results show the potential of proteins and peptide fractions recovered from waste water from the herring industry as source of natural antioxidants for use in food products....

  12. Long-term brine migration through an engineered shaft seal system

    International Nuclear Information System (INIS)

    Fryar, D.G.; Beach, J.A.; Kelley, V.A.; Knowles, M.K.

    1997-01-01

    The shaft seal system for the Waste Isolation Pilot Plant (WIPP) must provide a barrier to the migration of fluids within the shafts to prevent the release of contaminants to the accessible environment. To investigate the performance of the shaft seal system, a set of fluid flow performance models was developed based upon the physical characteristics of the WIPP shaft seal system and the surrounding geologic media. This paper describes the results of a numerical model used to investigate the long-term potential for brine migration through the shaft seal system. Modeling results demonstrate that the WIPP shaft seal system will effectively limit brine migration within the repository shafts

  13. Modeling Coupled THM Processes and Brine Migration in Salt at High Temperatures

    Energy Technology Data Exchange (ETDEWEB)

    Rutqvist, Jonny [Lawrence Berkeley National Lab. (LBNL), Berkeley, CA (United States); Blanco-Martin, Laura [Lawrence Berkeley National Lab. (LBNL), Berkeley, CA (United States); Molins, Sergi [Lawrence Berkeley National Lab. (LBNL), Berkeley, CA (United States); Trebotich, David [Lawrence Berkeley National Lab. (LBNL), Berkeley, CA (United States); Birkholzer, Jens [Lawrence Berkeley National Lab. (LBNL), Berkeley, CA (United States)

    2015-09-01

    In this report, we present FY2015 progress by Lawrence Berkeley National Laboratory (LBNL) related to modeling of coupled thermal-hydrological-mechanical-chemical (THMC) processes in salt and their effect on brine migration at high temperatures. This is a combined milestone report related to milestone Salt R&D Milestone “Modeling Coupled THM Processes and Brine Migration in Salt at High Temperatures” (M3FT-15LB0818012) and the Salt Field Testing Milestone (M3FT-15LB0819022) to support the overall objectives of the salt field test planning.

  14. Modeling Coupled THM Processes and Brine Migration in Salt at High Temperatures

    International Nuclear Information System (INIS)

    Rutqvist, Jonny; Blanco-Martin, Laura; Molins, Sergi; Trebotich, David; Birkholzer, Jens

    2015-01-01

    In this report, we present FY2015 progress by Lawrence Berkeley National Laboratory (LBNL) related to modeling of coupled thermal-hydrological-mechanical-chemical (THMC) processes in salt and their effect on brine migration at high temperatures. This is a combined milestone report related to milestone Salt R&D Milestone ''Modeling Coupled THM Processes and Brine Migration in Salt at High Temperatures'' (M3FT-15LB0818012) and the Salt Field Testing Milestone (M3FT-15LB0819022) to support the overall objectives of the salt field test planning.

  15. Background stratified Poisson regression analysis of cohort data.

    Science.gov (United States)

    Richardson, David B; Langholz, Bryan

    2012-03-01

    Background stratified Poisson regression is an approach that has been used in the analysis of data derived from a variety of epidemiologically important studies of radiation-exposed populations, including uranium miners, nuclear industry workers, and atomic bomb survivors. We describe a novel approach to fit Poisson regression models that adjust for a set of covariates through background stratification while directly estimating the radiation-disease association of primary interest. The approach makes use of an expression for the Poisson likelihood that treats the coefficients for stratum-specific indicator variables as 'nuisance' variables and avoids the need to explicitly estimate the coefficients for these stratum-specific parameters. Log-linear models, as well as other general relative rate models, are accommodated. This approach is illustrated using data from the Life Span Study of Japanese atomic bomb survivors and data from a study of underground uranium miners. The point estimate and confidence interval obtained from this 'conditional' regression approach are identical to the values obtained using unconditional Poisson regression with model terms for each background stratum. Moreover, it is shown that the proposed approach allows estimation of background stratified Poisson regression models of non-standard form, such as models that parameterize latency effects, as well as regression models in which the number of strata is large, thereby overcoming the limitations of previously available statistical software for fitting background stratified Poisson regression models.

  16. Stratified source-sampling techniques for Monte Carlo eigenvalue analysis

    International Nuclear Information System (INIS)

    Mohamed, A.

    1998-01-01

    In 1995, at a conference on criticality safety, a special session was devoted to the Monte Carlo ''Eigenvalue of the World'' problem. Argonne presented a paper, at that session, in which the anomalies originally observed in that problem were reproduced in a much simplified model-problem configuration, and removed by a version of stratified source-sampling. In this paper, stratified source-sampling techniques are generalized and applied to three different Eigenvalue of the World configurations which take into account real-world statistical noise sources not included in the model problem, but which differ in the amount of neutronic coupling among the constituents of each configuration. It is concluded that, in Monte Carlo eigenvalue analysis of loosely-coupled arrays, the use of stratified source-sampling reduces the probability of encountering an anomalous result over that if conventional source-sampling methods are used. However, this gain in reliability is substantially less than that observed in the model-problem results

  17. Ethanol dehydration to ethylene in a stratified autothermal millisecond reactor.

    Science.gov (United States)

    Skinner, Michael J; Michor, Edward L; Fan, Wei; Tsapatsis, Michael; Bhan, Aditya; Schmidt, Lanny D

    2011-08-22

    The concurrent decomposition and deoxygenation of ethanol was accomplished in a stratified reactor with 50-80 ms contact times. The stratified reactor comprised an upstream oxidation zone that contained Pt-coated Al(2)O(3) beads and a downstream dehydration zone consisting of H-ZSM-5 zeolite films deposited on Al(2)O(3) monoliths. Ethanol conversion, product selectivity, and reactor temperature profiles were measured for a range of fuel:oxygen ratios for two autothermal reactor configurations using two different sacrificial fuel mixtures: a parallel hydrogen-ethanol feed system and a series methane-ethanol feed system. Increasing the amount of oxygen relative to the fuel resulted in a monotonic increase in ethanol conversion in both reaction zones. The majority of the converted carbon was in the form of ethylene, where the ethanol carbon-carbon bonds stayed intact while the oxygen was removed. Over 90% yield of ethylene was achieved by using methane as a sacrificial fuel. These results demonstrate that noble metals can be successfully paired with zeolites to create a stratified autothermal reactor capable of removing oxygen from biomass model compounds in a compact, continuous flow system that can be configured to have multiple feed inputs, depending on process restrictions. Copyright © 2011 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

  18. Background stratified Poisson regression analysis of cohort data

    International Nuclear Information System (INIS)

    Richardson, David B.; Langholz, Bryan

    2012-01-01

    Background stratified Poisson regression is an approach that has been used in the analysis of data derived from a variety of epidemiologically important studies of radiation-exposed populations, including uranium miners, nuclear industry workers, and atomic bomb survivors. We describe a novel approach to fit Poisson regression models that adjust for a set of covariates through background stratification while directly estimating the radiation-disease association of primary interest. The approach makes use of an expression for the Poisson likelihood that treats the coefficients for stratum-specific indicator variables as 'nuisance' variables and avoids the need to explicitly estimate the coefficients for these stratum-specific parameters. Log-linear models, as well as other general relative rate models, are accommodated. This approach is illustrated using data from the Life Span Study of Japanese atomic bomb survivors and data from a study of underground uranium miners. The point estimate and confidence interval obtained from this 'conditional' regression approach are identical to the values obtained using unconditional Poisson regression with model terms for each background stratum. Moreover, it is shown that the proposed approach allows estimation of background stratified Poisson regression models of non-standard form, such as models that parameterize latency effects, as well as regression models in which the number of strata is large, thereby overcoming the limitations of previously available statistical software for fitting background stratified Poisson regression models. (orig.)

  19. Nuclear waste repository simulation experiments (brine migration), Asse Mine of the Federal of Germany: Quarterly brine migration data report, July-September 1984

    International Nuclear Information System (INIS)

    Coyle, A.J.; Kalia, H.N.; Eckert, J.L.

    1986-10-01

    The fifth brine migration data status report describes experiments simulating a nuclear waste repository at the 800-m (2624-ft) level of the Asse Salt Mine in the Federal Republic of Germany from May 1983 through September 1984. This report describes the test equipment, the Asse Salt Mine, and the pretest properties of the salt in the test gallery. This report also includes test data for the first 16 months of operations on brine migration rates, borehole pressure, salt temperatures, and thermomechanical behavior of the salt. Annual reports have been prepared for the years 1983 and 1984, describing the test activities on a yearly basis (Rothfuchs et al., 1984, 1986). The duration of the experiments will be approximately 2 years, ending in December 1985. 2 refs., 118 figs., 91 tabs

  20. Experimental alteration of R7T7 glass in salt brines at 90 deg C and 150 deg C

    International Nuclear Information System (INIS)

    Godon, N.; Vernaz, E.; Gin, S.; Beaufort, D.; Thomassin, J.H.

    1991-01-01

    Static experiments have been developed to investigate the R7T7 glass corrosion in four natural salt brines (brines 1 and 3: pure halite, brines 2 and 4: high Mg, K fluid inclusions rich halite), at 90 deg C and 150 deg C with 0.7 cm -1 S/V ratio and at 11 different running times. Analysis of brines after alteration (pHmeter and ICP) added to a detailed study of the crystalline phases developed at the interface glass-brine (XRD,SEM and Microprobe), showed that the influence of the compositional difference is more important on the nature of the secondary phases formed than on the corrosion rate of the glass. After 91 days of alteration at 150 deg C stady states to be reached (after 40 days at 90 deg C). A long term experiment (1 year) is necessary to confirm this hypothesis. 7 refs., 7 figs., 2 tabs

  1. SOLUTION OF A MULTIVARIATE STRATIFIED SAMPLING PROBLEM THROUGH CHEBYSHEV GOAL PROGRAMMING

    Directory of Open Access Journals (Sweden)

    Mohd. Vaseem Ismail

    2010-12-01

    Full Text Available In this paper, we consider the problem of minimizing the variances for the various characters with fixed (given budget. Each convex objective function is first linearised at its minimal point where it meets the linear cost constraint. The resulting multiobjective linear programming problem is then solved by Chebyshev goal programming. A numerical example is given to illustrate the procedure.

  2. TRANSPORT AND BIODEGRADATION OF SOLUTES IN STRATIFIED AQUIFERS UNDER ENHANCED IN SITU BIOREMEDIATION CONDITIONS. (R824785)

    Science.gov (United States)

    The perspectives, information and conclusions conveyed in research project abstracts, progress reports, final reports, journal abstracts and journal publications convey the viewpoints of the principal investigator and may not represent the views and policies of ORD and EPA. Concl...

  3. Chemistry of Frozen NaCl and MgSO4 Brines - Implications for Surface Expression of Europa's Ocean Composition

    Science.gov (United States)

    Johnson, P. V.; Hodyss, R. P.; Choukroun, M.; Vu, T. H.

    2015-12-01

    The composition of Europa's subsurface ocean is a critical determinant of its habitability, but current analysis of the ocean composition is limited to its expression on the Europan surface. While there is observational evidence indicating that ocean materials make their way to the surface, our understanding of the chemical processes that can alter this material under Europan surface conditions is limited. We present experimental data on the chemistry of mixed solutions of NaCl and MgSO4 as they are frozen to 100 K, replicating the conditions that may occur when subsurface ocean fluids are emplaced onto Europa's surface. Confocal micro-Raman spectroscopy is used to study the formation of salts during the freezing process, and the interaction of ions in the frozen brines. Our data indicate that mixed aqueous solutions of NaCl and MgSO4 form Na2SO4 and MgCl2 preferentially when frozen, rather than making NaCl and MgSO4 precipitates. The detection of epsomite (MgSO4Ÿ•7H2O) on Europa's surface may therefore imply an ocean composition relatively low in sodium, unless radiolytic chemistry converts MgCl2 to MgSO4 as suggested by Hand and Brown 2013 (ApJ 145 110). These results have important implications for the interpretation of remote sensing data of Europa's surface.

  4. Bioassay Screening of the Essential Oil and Various Extracts of Nigella sativa L. Seeds Using Brine Shrimp Toxicity Assay

    Directory of Open Access Journals (Sweden)

    Fariba Sharififar

    2017-03-01

    Full Text Available Background and Aim: Since cytotoxicity screening is the first step necessary for any new drug development, this study was designed to find out and compare the cytotoxicity effects of the essential oil and various extracts of Nigella sativa L. seeds using Brine Shrimp Lethality (BSL assay. Materials and Methods: Essential oils and various extracts of N. sativa were assessed by two methods of disk and solution of BSL. Data analysis was carried out using SPSS statistical package version 17.0 (SPSS Inc., Chicago, IL, 250 USA. Data were processed in probit-analysis program to estimate LC50 values. Results: All of the tested fractions demonstrated more cytotoxicity in the solution method. Petroleum ether and chloroform extract of N. sativa showed the most cytotoxicity with LC50 values 7 and 21 μg/ml respectively; while aqueous and ethanolic had no significant cytotoxicity. Moreover, the GC/MS analysis of the essential oil of N. sativa showed the p-cymene (48.1%, α-thujone (14.38% and dihydro carveol (9.11% as the main compounds. Conclusion: These results suggest some limitation for using this spice in diet. Furthermore, this plant could be considered as a source of cytotoxic compounds which should be studied in details.

  5. Effect of gas field production and CO2 injection on brine flow and salt precipitation

    NARCIS (Netherlands)

    Loeve, D.; Tambach, T.J.; Hofstee, C.; Plug, W.J.; Maas, J.

    2012-01-01

    This paper reports modeling of gas field produc-tion and CO2 injection from a theoretical reser-voir based on characteristics of the P18 gas field in the Dutch offshore, which consists of four geological deposits with different petrophysical properties. We especially focus on the brine flow during

  6. Construction of a cylindrical brine test room using a tunnel boring machine

    International Nuclear Information System (INIS)

    Likar, V.F.; Burrington, T.P.

    1990-01-01

    This paper discusses the construction of a horizontal cylindrical brine test room at the Waste Isolation Pilot Plant (WIPP). The room was constructed in the bedded salt formation at a depth of 655 meters with a tunnel boring machine. The machine leasing, technical and operational management, parameters involved, and successful completion of this effort are included. 3 figs

  7. Grain Size Data from the Brine Disposal Program, Gulf of Mexico

    Data.gov (United States)

    National Oceanic and Atmospheric Administration, Department of Commerce — These data are part of the Brine Disposal Program funded by NOAA in the US Gulf of Mexico, compiled by NOAA/CEAS and partially conducted by R. W. Hann of Texas A and...

  8. Aerobic methanotrophic communities at the Red Sea brine-seawater interface

    KAUST Repository

    Abdallah, Rehab Z.

    2014-09-23

    Abdallah RZ, Adel M, Ouf A, Sayed A, Ghazy MA, Alam I, Essack M, Lafi FF, Bajic VB, El-Dorry H and Siam R (2014) Aerobic methanotrophic communities at the Red Sea brine-seawater interface. Front. Microbiol. 5:487. doi: 10.3389/fmicb.2014.00487

  9. Autotrophic microbe metagenomes and metabolic pathways differentiate adjacent red sea brine pools

    KAUST Repository

    Wang, Yong; Cao, Huiluo; Zhang, Guishan; Bougouffa, Salim; Lee, On On; Al-Suwailem, Abdulaziz M.; Qian, Pei-Yuan

    2013-01-01

    In the Red Sea, two neighboring deep-sea brine pools, Atlantis II and Discovery, have been studied extensively, and the results have shown that the temperature and concentrations of metal and methane in Atlantis II have increased over the past

  10. Molecular Dynamics Simulation Study of Carbon Dioxide, Methane, and Their Mixture in the Presence of Brine

    KAUST Repository

    Yang, Yafan; Nair, Arun Kumar Narayanan; Sun, Shuyu

    2017-01-01

    We perform molecular dynamics simulation study of CO2, methane, and their mixture in the presence of brine over a broad range of temperature (311–473 K), pressure (up to about 100 MPa), and NaCl concentration (up to about 14 wt %). The general

  11. Review of the African distribution of the brine shrimp genus Artemia ...

    African Journals Online (AJOL)

    Brine shrimp (genus Artemia) are small (8 to 12 mm long) cosmopolitan crustaceans (Anostraca) found predominately in hypersaline water bodies such as inland salt lakes and pans, coastal lagoons, and salt works at salinity levels above 40 g·ℓ-1. They have been extensively studied due to their high monetary value as ...

  12. Construction of a cylindrical brine test room using a tunnel boring machine

    International Nuclear Information System (INIS)

    Likar, V.F.; Burrington, T.P.

    1990-01-01

    This paper discusses the construction of a horizontal cylindrical brine test room at the Waste Isolation Pilot Plant (WIPP). The room was constructed in the bedded salt formation at a depth of 655 meters with a tunnel boring machine. The machine leasing technical and operational management, parameters involved, and successful completion of this effort are included. 3 figs

  13. Design of the Brine Evaporation Bag for Increased Water Recovery in Microgravity

    Science.gov (United States)

    Hayden, Anna L.; Delzeit, Lance D.

    2015-01-01

    The existing water recovery system on the International Space Station (ISS) is limited to 75% reclamation; consequently, long duration space missions are currently unfeasible due to the large quantity of water necessary to sustain the crew. The Brine Evaporation Bag (BEB) is a proposed system to supplement the existing water recovery system aboard the ISS that can to increase water recovery to 99%. The largest barrier to high water recovery is mineral scaling inside the water recovery equipment, which leads to equipment failure; therefore, some water must remain to keep the minerals dissolved. This waste stream is liquid brine containing salts, acids, organics, and water. The BEB is designed to recover this remaining water while protecting the equipment from scale. The BEB consists of a sealed bag containing a hydrophobic membrane that allows water vapor and gas to pass through. It is operated under vacuum, heated, and continuously filled with brine to boil away the water. The water vapor is recovered and the solids are contained inside the bag for disposal. The BEB can dry the brine to a solid block. Ongoing work includes improving the design of the BEB and the evaporator to prevent leaks, maximize the rate of water removal, and minimize energy use and weight. Additional testing will determine whether designs are heat- or mass-transfer limited and the optimal water recovery rate.

  14. Antioxidative low molecular weight compounds in marinated herring (Clupea harengus) salt brine

    DEFF Research Database (Denmark)

    Gringer, Nina; Safafar, Hamed; du Mesnildot, Axelle

    2016-01-01

    salt brines contain LMWC holding ABTS-radical scavenging activity, reducing power and iron chelating activity. Generally, a strong correlation between TPC and ABTSradical scavenging was found. In contrast, reducing power and iron chelating activity seemed to be caused by peptides. Protein...

  15. Simulation of the high-pressure phase equilibria of hydrocarbon-water/brine systems

    DEFF Research Database (Denmark)

    Zuo, You-Xiang; Stenby, Erling Halfdan; Guo, Tian-Min

    1996-01-01

    The major objectives of this work are: (1) extend the modified Patel-Teja (MPT) equation of state proposed for aqueous electrolyte systems (Zuo and Guo, 1991) to describe the liquid-liquid and vapor-liquid-liquid equilibria of hydrocarbon-water/brine systems through introducing an unconventional...

  16. Metagenomic insights into the uncultured diversity and physiology of microbes in four hypersaline soda lake brines

    NARCIS (Netherlands)

    Vavourakis, Charlotte D.; Ghai, Rohit; Rodriguez-Valera, Francisco; Sorokin, Dimitry Y.; Tringe, Susannah G.; Hugenholtz, Philip; Muyzer, Gerard

    2016-01-01

    Soda lakes are salt lakes with a naturally alkaline pH due to evaporative concentration of sodium carbonates in the absence of major divalent cations. Hypersaline soda brines harbor microbial communities with a high species- and strain-level archaeal diversity and a large proportion of still

  17. Metagenomic Insights into the Uncultured Diversity and Physiology of Microbes in Four Hypersaline Soda Lake Brines

    NARCIS (Netherlands)

    Vavourakis, C.D.; Ghai, R.; Rodriguez-valera, F.; Sorokin, D.Y.; Tringe, S.G.; Hugenholtz, P.; Muyzer, G.

    2016-01-01

    Soda lakes are salt lakes with a naturally alkaline pH due to evaporative concentration of sodium carbonates in the absence of major divalent cations. Hypersaline soda brines harbor microbial communities with a high species- and strain-level archaeal diversity and a large proportion of still

  18. Origin of brine in the Kangan gasfield: isotopic and hydrogeochemical approaches

    NARCIS (Netherlands)

    Bagheri, R.; Nadri, A.; Raeisi, E.; Kazemi, G.A.; Eggenkamp, H.G.M.; Montaseri, A.

    2014-01-01

    The Kangan Permo-Triassic brine aquifer and the overlying gas reservoir in the southern Iran are located in Kangan and Dalan Formations, consisting dominantly of limestone, dolomite, and to a lesser extent, shale and anhydrite. The gasfield, 2,900 m in depth and is exploited by 36 wells, some of

  19. Characterization of Phytochemicals and Antioxidant Activities of Red Radish Brines during Lactic Acid Fermentation

    Directory of Open Access Journals (Sweden)

    Pu Jing

    2014-07-01

    Full Text Available Red radish (Raphanus L. pickles are popular appetizers or spices in Asian-style cuisine. However, tons of radish brines are generated as wastes from industrial radish pickle production. In this study, we evaluated the dynamic changes in colour properties, phenolics, anthocyanin profiles, phenolic acid composition, flavonoids, and antioxidant properties in radish brines during lactic acid fermentation. The results showed that five flavonoids detected were four anthocyanins and one kaempferol derivative, including pelargonidin-3-digluoside-5-glucoside derivatives acylated with p-coumaric acid, ferulic acid, p-coumaric and manolic acids, or ferulic and malonic acids. Amounts ranged from 15.5–19.3 µg/mL in total monomeric anthocyanins, and kaempferol-3,7-diglycoside (15–30 µg/mL. 4-Hydroxy-benzoic, gentisic, vanillic, syringic, p-coumaric, ferulic, sinapic and salicylic acids were detected in amounts that varied from 70.2–92.2 µg/mL, whereas the total phenolic content was 206–220 µg/mL. The change in colour of the brine was associated with the accumulation of lactic acid and anthocyanins. The ORAC and Fe2+ chelation capacity of radish brines generally decreased, whereas the reducing power measured as FRAP values was increased during the fermentation from day 5 to day 14. This study provided information on the phytochemicals and the antioxidative activities of red radish fermentation waste that might lead to further utilization as nutraceuticals or natural colorants.

  20. Bacterial use of choline to tolerate salinity shifts in sea-ice brines

    DEFF Research Database (Denmark)

    Firth, E.; Carpenter, S. D.; Sørensen, H. L.

    2016-01-01

    Bacteria within the brine network of sea ice experience temperature-driven fluctuations in salinity on both short and long temporal scales, yet their means of osmoprotection against such fluctuations is poorly understood. One mechanism used to withstand the ion fluxes caused by salinity shifts, w...

  1. Metagenomic insights into the uncultured diversity and physiology of microbes in four hypersaline soda lake brines.

    Czech Academy of Sciences Publication Activity Database

    Vavourakis, C. D.; Ghai, Rohit; Rodriguez-Valera, F.; Sorokin, D. Y.; Tringe, S. G.; Hugenholtz, P.; Muyzer, G.

    2016-01-01

    Roč. 7, February (2016), č. článku 211. ISSN 1664-302X R&D Projects: GA ČR(CZ) GA13-00243S Institutional support: RVO:60077344 Keywords : soda lake brines * Nanohaloarchaea * Halobacteria * Bacteroidetes * hydrolytics * cellulase * chitinase * rhodopsin Subject RIV: EE - Microbiology, Virology Impact factor: 4.076, year: 2016

  2. Carbonate and carbon isotopic evolution of groundwater contaminated by produced water brine with hydrocarbons

    International Nuclear Information System (INIS)

    Atekwana, Eliot A.; Seeger, Eric J.

    2015-01-01

    The major ionic and dissolved inorganic carbon (DIC) concentrations and the stable carbon isotope composition of DIC (δ"1"3C_D_I_C) were measured in a freshwater aquifer contaminated by produced water brine with petroleum hydrocarbons. Our aim was to determine the effects of produced water brine contamination on the carbonate evolution of groundwater. The groundwater was characterized by three distinct anion facies: HCO_3"−-rich, SO_4"2"−-rich and Cl"−-rich. The HCO_3"−-rich groundwater is undergoing closed system carbonate evolution from soil CO_2_(_g_) and weathering of aquifer carbonates. The SO_4"2"−-rich groundwater evolves from gypsum induced dedolomitization and pyrite oxidation. The Cl"−-rich groundwater is contaminated by produced water brine and undergoes common ion induced carbonate precipitation. The δ"1"3C_D_I_C of the HCO_3"−-rich groundwater was controlled by nearly equal contribution of carbon from soil CO_2_(_g_) and the aquifer carbonates, such that the δ"1"3C of carbon added to the groundwater was −11.6‰. In the SO_4"2"−-rich groundwater, gypsum induced dedolomitization increased the "1"3C such that the δ"1"3C of carbon added to the groundwater was −9.4‰. In the produced water brine contaminated Cl"−-rich groundwater, common ion induced precipitation of calcite depleted the "1"3C such that the δ"1"3C of carbon added to the groundwater was −12.7‰. The results of this study demonstrate that produced water brine contamination of fresh groundwater in carbonate aquifers alters the carbonate and carbon isotopic evolution. - Highlights: • We studied carbonate and δ"1"3C evolution in groundwater contaminated by produced water brine. • Multiple processes affect the carbonate and δ"1"3C evolution of the groundwater. • The processes are carbonate weathering, dedolomitization and common ion induce calcite precipitation. • The δ"1"3C added to DIC was −11.6‰ for weathering, −9.4‰ for dedolomitization

  3. Numerical simulations of the stratified oceanic bottom boundary layer

    Science.gov (United States)

    Taylor, John R.

    Numerical simulations are used to consider several problems relevant to the turbulent oceanic bottom boundary layer. In the first study, stratified open channel flow is considered with thermal boundary conditions chosen to approximate a shallow sea. Specifically, a constant heat flux is applied at the free surface and the lower wall is assumed to be adiabatic. When the surface heat flux is strong, turbulent upwellings of low speed fluid from near the lower wall are inhibited by the stable stratification. Subsequent studies consider a stratified bottom Ekman layer over a non-sloping lower wall. The influence of the free surface is removed by using an open boundary condition at the top of the computational domain. Particular attention is paid to the influence of the outer layer stratification on the boundary layer structure. When the density field is initialized with a linear profile, a turbulent mixed layer forms near the wall, which is separated from the outer layer by a strongly stable pycnocline. It is found that the bottom stress is not strongly affected by the outer layer stratification. However, stratification reduces turbulent transport to the outer layer and strongly limits the boundary layer height. The mean shear at the top of the boundary layer is enhanced when the outer layer is stratified, and this shear is strong enough to cause intermittent instabilities above the pycnocline. Turbulence-generated internal gravity waves are observed in the outer layer with a relatively narrow frequency range. An explanation for frequency content of these waves is proposed, starting with an observed broad-banded turbulent spectrum and invoking linear viscous decay to explain the preferential damping of low and high frequency waves. During the course of this work, an open-source computational fluid dynamics code has been developed with a number of advanced features including scalar advection, subgrid-scale models for large-eddy simulation, and distributed memory

  4. Direct contact condensation induced transition from stratified to slug flow

    International Nuclear Information System (INIS)

    Strubelj, Luka; Ezsoel, Gyoergy; Tiselj, Iztok

    2010-01-01

    Selected condensation-induced water hammer experiments performed on PMK-2 device were numerically modelled with three-dimensional two-fluid models of computer codes NEPTUNE C FD and CFX. Experimental setup consists of the horizontal pipe filled with the hot steam that is being slowly flooded with cold water. In most of the experimental cases, slow flooding of the pipe was abruptly interrupted by a strong slugging and water hammer, while in the selected experimental runs performed at higher initial pressures and temperatures that are analysed in the present work, the transition from the stratified into the slug flow was not accompanied by the water hammer pressure peak. That makes these cases more suitable tests for evaluation of the various condensation models in the horizontally stratified flows and puts them in the range of the available CFD (Computational Fluid Dynamics) codes. The key models for successful simulation appear to be the condensation model of the hot vapour on the cold liquid and the interfacial momentum transfer model. The surface renewal types of condensation correlations, developed for condensation in the stratified flows, were used in the simulations and were applied also in the regions of the slug flow. The 'large interface' model for inter-phase momentum transfer model was compared to the bubble drag model. The CFD simulations quantitatively captured the main phenomena of the experiments, while the stochastic nature of the particular condensation-induced water hammer experiments did not allow detailed prediction of the time and position of the slug formation in the pipe. We have clearly shown that even the selected experiments without water hammer present a tough test for the applied CFD codes, while modelling of the water hammer pressure peaks in two-phase flow, being a strongly compressible flow phenomena, is beyond the capability of the current CFD codes.

  5. Brine contamination to aquatic resources from oil and gas development in the Williston Basin, United States

    Science.gov (United States)

    Gleason, Robert A.; Contributions by Chesley-Preston, Tara L.; Coleman, James L.; Haines, Seth S.; Jenni, Karen E.; Nieman, Timothy L.; Peterman, Zell E.; van der Burg, Max Post; Preston, Todd M.; Smith, Bruce D.; Tangen, Brian A.; Thamke, Joanna N.; Gleason, Robert A.; Tangen, Brian A.

    2014-01-01

    The Williston Basin, which includes parts of Montana, North Dakota, and South Dakota in the United States and the provinces of Manitoba and Saskatchewan in Canada, has been a leading domestic oil and gas producing region for more than one-half a century. Currently, there are renewed efforts to develop oil and gas resources from deep geologic formations, spurred by advances in recovery technologies and economic incentives associated with the price of oil. Domestic oil and gas production has many economic benefits and provides a means for the United States to fulfill a part of domestic energy demands; however, environmental hazards can be associated with this type of energy production in the Williston Basin, particularly to aquatic resources (surface water and shallow groundwater) by extremely saline water, or brine, which is produced with oil and gas. The primary source of concern is the migration of brine from buried reserve pits that were used to store produced water during recovery operations; however, there also are considerable risks of brine release from pipeline failures, poor infrastructure construction, and flow-back water from hydraulic fracturing associated with modern oilfield operations. During 2008, a multidisciplinary (biology, geology, water) team of U.S. Geological Survey researchers was assembled to investigate potential energy production effects in the Williston Basin. Researchers from the U.S. Geological Survey participated in field tours and met with representatives from county, State, tribal, and Federal agencies to identify information needs and focus research objectives. Common questions from agency personnel, especially those from the U.S. Fish and Wildlife Service, were “are the brine plumes (plumes of brine-contaminated groundwater) from abandoned oil wells affecting wetlands on Waterfowl Production Areas and National Wildlife Refuges?” and “are newer wells related to Bakken and Three Forks development different than the older

  6. Technetium reduction and removal in a stratified fjord

    International Nuclear Information System (INIS)

    Keith-Roach, M.; Roos, P.

    2002-01-01

    The distribution of Tc in the water columns of a stratified fjord has been measured to investigate the behaviour and fate of Tc on reaching reducing waters. Slow mixing in the water column of the fjord results in vertical transport of the dissolved Tc to the oxic/anoxic interface. Tc is reduced just below the interface and at 21 m 60% is sorbed to particulate and colloidal material. Tc is carried to the sediments sorbed to the particulate material, where there is a current inventory of approximately 3 Bq m -2 . (LN)

  7. Stability of unstably stratified shear flow between parallel plates

    Energy Technology Data Exchange (ETDEWEB)

    Fujimura, Kaoru; Kelly, R E

    1987-09-01

    The linear stability of unstably stratified shear flows between two horizontal parallel plates was investigated. Eigenvalue problems were solved numerically by making use of the expansion method in Chebyshev polynomials, and the critical Rayleigh numbers were obtained accurately in the Reynolds number range of (0.01, 100). It was found that the critical Rayleigh number increases with an increase of the Reynolds number. The result strongly supports previous stability analyses except for the analysis by Makino and Ishikawa (J. Jpn. Soc. Fluid Mech. 4 (1985) 148 - 158) in which a decrease of the critical Rayleigh number was obtained.

  8. Stability of unstably stratified shear flow between parallel plates

    International Nuclear Information System (INIS)

    Fujimura, Kaoru; Kelly, R.E.

    1987-01-01

    The linear stability of unstably stratified shear flows between two horizontal parallel plates was investigated. Eigenvalue problems were solved numerically by making use of the expansion method in Chebyshev polynomials, and the critical Rayleigh numbers were obtained accurately in the Reynolds number range of [0.01, 100]. It was found that the critical Rayleigh number increases with an increase of the Reynolds number. The result strongly supports previous stability analyses except for the analysis by Makino and Ishikawa [J. Jpn. Soc. Fluid Mech. 4 (1985) 148 - 158] in which a decrease of the critical Rayleigh number was obtained. (author)

  9. Stratifying patients with peripheral neuropathic pain based on sensory profiles

    DEFF Research Database (Denmark)

    Vollert, Jan; Maier, Christoph; Attal, Nadine

    2017-01-01

    In a recent cluster analysis, it has been shown that patients with peripheral neuropathic pain can be grouped into 3 sensory phenotypes based on quantitative sensory testing profiles, which are mainly characterized by either sensory loss, intact sensory function and mild thermal hyperalgesia and...... populations that need to be screened to reach a subpopulation large enough to conduct a phenotype-stratified study. The most common phenotype in diabetic polyneuropathy was sensory loss (83%), followed by mechanical hyperalgesia (75%) and thermal hyperalgesia (34%, note that percentages are overlapping...

  10. Technetium reduction and removal in a stratified fjord

    Energy Technology Data Exchange (ETDEWEB)

    Keith-Roach, M.; Roos, P. [Risoe National Lab., Roskilde (Denmark)

    2002-04-01

    The distribution of Tc in the water columns of a stratified fjord has been measured to investigate the behaviour and fate of Tc on reaching reducing waters. Slow mixing in the water column of the fjord results in vertical transport of the dissolved Tc to the oxic/anoxic interface. Tc is reduced just below the interface and at 21 m 60% is sorbed to particulate and colloidal material. Tc is carried to the sediments sorbed to the particulate material, where there is a current inventory of approximately 3 Bq m{sup -2}. (LN)

  11. Development of a natural gas stratified charge rotary engine

    Energy Technology Data Exchange (ETDEWEB)

    Sierens, R.; Verdonck, W.

    1985-01-01

    A water model has been used to determine the positions of separate inlet ports for a natural gas, stratified charge rotary engine. The flow inside the combustion chamber (mainly during the induction period) has been registered by a film camera. From these tests the best locations of the inlet ports have been obtained, a prototype of this engine has been built by Audi NSU and tested in the laboratories of the university of Gent. The results of these tests, for different stratification configurations, are given. These results are comparable with the best results obtained by Audi NSU for a homogeneous natural gas rotary engine.

  12. Review of the impacts of leaking CO 2 gas and brine on groundwater quality

    Energy Technology Data Exchange (ETDEWEB)

    Qafoku, Nikolla P.; Lawter, Amanda R.; Bacon, Diana H.; Zheng, Liange; Kyle, Jennifer; Brown, Christopher F.

    2017-06-01

    This review paper provides a synthetic view of the existing knowledge and summarizes data and findings of the recent literature on the subject of the potential leaking of CO2 from the deep subsurface storage reservoirs and the effects on aquifer quality. New ideas and concepts are developed and insights are also provided. The objectives of this paper are to: 1) present and discuss potential risks for groundwater degradation due to CO2 gas and brine exposure; 2) identify the set of geochemical data required to assess and predict aquifer responses to CO2 and brine leakage. Specifically, this paper will discuss the following issues: 1) Aquifer responses (such as changes in aqueous phase/groundwater chemical composition; changes in solid phase chemistry and mineralogy; changes in the extent and rate of reactions and processes and possible establishment of a new network of reactions and processes affecting or controlling overall mobility of major, minor, and trace elements; development of conceptual and reduced order models (ROMs) to describe and predict aquifer responses); 2) The degree of impact such as significant or insignificant changes in pH and major, minor, and trace element release that depend on the following controlling variables; the effect of leaking plume characteristics (gas composition, pure CO2 and/or CO2 -CH4 -H2S mixtures and brine concentration and composition (trace metals); aquifer properties [such as initial aqueous phase conditions and mineralogy: minerals controlling sediments’ response (e.g., calcite, Si bearing minerals, etc.)]; overview of relevant hydrogeological and geochemical processes related to the impact of CO2 gas and brine on groundwater quality; the fate of the elements released from sediments or transported with brine (such as precipitation/incorporation into minerals (calcite and other minerals), adsorption, electron transfer reactions, the role of natural attenuation; whether or not the release of metals following exposure to

  13. Molecular Dynamics Simulation Study of Carbon Dioxide, Methane, and Their Mixture in the Presence of Brine

    KAUST Repository

    Yang, Yafan

    2017-10-03

    We perform molecular dynamics simulation study of CO2, methane, and their mixture in the presence of brine over a broad range of temperature (311–473 K), pressure (up to about 100 MPa), and NaCl concentration (up to about 14 wt %). The general decrease in the interfacial tension (IFT) values of the CH4–brine system with pressure and temperature is similar to that obtained for the corresponding CH4–water system. The IFT of methane and brine is a linearly increasing function of salt concentration, and the resulting slopes are dependent on the pressure. A similar behavior as methane is observed for such systems containing CO2 and CO2–CH4 mixture. The IFT of CO2 and brine increases linearly with increasing salt content; however, the resulting slopes are independent of pressure. The simulations show that the presence of CO2 decreases the IFT values of the CH4–water and CH4–brine systems, but the degree of reduction depends on the amount of CO2 in each sample, which is consistent with experimental evidence. These IFT values show a linear correlation with the amount of CO2, and the resulting slopes are dependent on the temperature and pressure. Furthermore, our results for the mole fractions of the different species in the CO2–CH4–water system at 323 K and 9 MPa are in agreement with those of experiments. The mole fractions of methane and CO2 in the water-rich phase decrease with increasing salt concentration, whereas that of H2O in the methane- or CO2-rich phases remains almost unaffected in all of the studied cases. Our results could be useful because of the importance of carbon dioxide sequestration and shale gas production.

  14. Comparison of the Sr isotopic signatures in brines of the Canadian and Fennoscandian shields

    International Nuclear Information System (INIS)

    Negrel, Philippe; Casanova, Joel

    2005-01-01

    A synthesis of Sr isotope data from shallow and deep groundwaters, and brines from the Fennoscandian and Canadian Shields is presented. A salinity gradient is evident in the water with concentrations varying from approximately 1-75 g L -1 below 1500 m depth in the Fennoscandian Shield and from 10 up to 300 g L -1 below 650 m depth in the Canadian Shield. Strontium isotope ratios were measured to assess the origin of the salinity and evaluate the degree of water-rock interaction in the systems. In both shields, the Sr concentrations are enriched relative to Cl, defining a positive trend parallel to the seawater dilution line and indicative of Sr addition through weathering processes. The depth distribution for Sr concentration increases strongly with increasing depth in both shields although the variation in Sr-isotope composition does not mirror that of Sr concentrations. Strontium-isotope compositions are presented for surface waters, and groundwaters in several sites in the Fennoscandian and Canadian Shields. Numerous mixing lines can be drawn reflecting water-rock interaction. A series of calculated lines links the surface end-members (surface water and shallow groundwater) and the deep brines; these mixing lines define a range of 87 Sr/ 86 Sr ratios for the deep brines in different selected sites. All sites show a specific 87 Sr/ 86 Sr signature and the occurrence of large 87 Sr/ 86 Sr variations is site specific in both shields. In Canadian Shield brines, the Sr isotope ratios clearly highlight large water rock interaction that increases the 87 Sr/ 86 Sr ratio from water that could have been of marine origin. In contrast to the Canadian Shield, groundwater does not occur in closed pockets in the Fennoscandian, and the well-constrained 87 Sr/ 86 Sr signatures in deep brines should correspond to a large, well-mixed and homogeneous water reservoir, whose Sr isotope signature results from water-rock interaction

  15. Thermal gradient brine inclusion migration in salt study: gas-liquid inclusions, preliminary model

    International Nuclear Information System (INIS)

    Olander, D.R.; Machiels, A.J.

    1979-10-01

    Natural salt deposits contain small cubical inclusions of brine distributed through the salt. Temperature gradients, resulting from storing heat-generating wastes in the salt, can cause the inclusions to move through the salt. Prediction of the rate and amount of brine-inclusion migration is necessary for the evaluation of bedded or domed salts as possible media for waste repositories. Inclusions filled exclusively with liquid migrate up the temperature gradient towards the heat source. The solubility of salt in the brine inclusion increases with temperature. Consequently, salt dissolves into the inclusion across the hot surface and crystallizes out at the cold surface. Diffusion of salt within the liquid phase from the hot to the cold faces causes the inclusions to move in the opposite direction. In so doing, they change shape and eventually become rectangular parallelipipeds with a width (dimension perpendicular to the thermal gradient) much larger than the thickness (dimension in the direction of the thermal gradient). The inclusions may also contain a gas phase predominantly consisting of water vapor. These entities are termed two-phase or gas-liquid inclusions. The two-phase inclusions usually migrate down the temperature gradient away from the heat source remaining more-or-less cubical. A two-phase inclusion also forms when an all-liquid inclusion reaches the waste package; upon opening up at the salt-package interface, the brine partially evaporates and the inclusion reseals with some insoluble gas trapped inside. These gas-liquid inclusions proceed to move down the temperature gradient, in the opposite sense of the all-liquid inclusions. The gas-liquid inclusions phenomenon provides a pathway by which radionuclides leached from the wasteform by the brine can be transported away from the waste package and thus might have greater access to the biosphere

  16. Estimates of the solubilities of waste element radionuclides in waste isolation pilot plant brines: A report by the expert panel on the source term

    Energy Technology Data Exchange (ETDEWEB)

    Hobart, D.E. [Sandia National Labs., Albuquerque, NM (United States)]|[Glenn T. Seaborg Inst. for Transactinium Science, Livermore, CA (United States); Bruton, C.J. [Sandia National Labs., Albuquerque, NM (United States)]|[Lawrence Livermore National Lab., CA (United States). Earth Sciences Dept.; Millero, F.J. [Sandia National Labs., Albuquerque, NM (United States)]|[Univ. of Miami, FL (United States). Rosenstiel School of Marine and Atmospheric Science; Chou, I.M. [Sandia National Labs., Albuquerque, NM (United States)]|[Geological Survey, Reston, VA (United States); Trauth, K.M.; Anderson, D.R. [Sandia National Labs., Albuquerque, NM (United States)

    1996-05-01

    Evaluation of the long-term performance of the WIPP includes estimation of the cumulative releases of radionuclide elements to the accessible environment. Nonradioactive lead is added because of the large quantity expected in WIPP wastes. To estimate the solubilities of these elements in WIPP brines, the Panel used the following approach. Existing thermodynamic data were used to identify the most likely aqueous species in solution through the construction of aqueous speciation diagrams. Existing thermodynamic data and expert judgment were used to identify potential solubility-limiting solid phases. Thermodynamic data were used to calculate the activities of the radionuclide aqueous species in equilibrium with each solid. Activity coefficients of the radionuclide-bearing aqueous species were estimated using Pitzer`s equations. These activity coefficients were then used to calculate the concentration of each radionuclide at the 0.1 and 0.9 fractiles. The 0.5 fractile was chosen to represent experimental data with activity coefficient corrections as described above. Expert judgment was used to develop the 0.0, 0.25, 0.75, and 1.0 fractiles by considering the sensitivity of solubility to the potential variability in the composition of brine and gas, and the extent of waste contaminants, and extending the probability distributions accordingly. The results were used in the 1991 and 1992 performance assessment calculations. 68 refs.

  17. Estimates of the solubilities of waste element radionuclides in waste isolation pilot plant brines: A report by the expert panel on the source term

    International Nuclear Information System (INIS)

    Hobart, D.E.; Bruton, C.J.; Trauth, K.M.; Anderson, D.R.

    1996-05-01

    Evaluation of the long-term performance of the WIPP includes estimation of the cumulative releases of radionuclide elements to the accessible environment. Nonradioactive lead is added because of the large quantity expected in WIPP wastes. To estimate the solubilities of these elements in WIPP brines, the Panel used the following approach. Existing thermodynamic data were used to identify the most likely aqueous species in solution through the construction of aqueous speciation diagrams. Existing thermodynamic data and expert judgment were used to identify potential solubility-limiting solid phases. Thermodynamic data were used to calculate the activities of the radionuclide aqueous species in equilibrium with each solid. Activity coefficients of the radionuclide-bearing aqueous species were estimated using Pitzer's equations. These activity coefficients were then used to calculate the concentration of each radionuclide at the 0.1 and 0.9 fractiles. The 0.5 fractile was chosen to represent experimental data with activity coefficient corrections as described above. Expert judgment was used to develop the 0.0, 0.25, 0.75, and 1.0 fractiles by considering the sensitivity of solubility to the potential variability in the composition of brine and gas, and the extent of waste contaminants, and extending the probability distributions accordingly. The results were used in the 1991 and 1992 performance assessment calculations. 68 refs

  18. Disposal/recovery options for brine waters from oil and gas production in New York State. Final report

    Energy Technology Data Exchange (ETDEWEB)

    Matsumoto, M.R.; Atkinson, J.F.; Bunn, M.D.; Hodge, D.S.

    1996-03-01

    Produced water from oil and gas operations, or brine as it is typically referred, may be characterized as being highly saline, with total dissolved solids greater than 100 g/L. If these bribes are disposed improperly there may be severe adverse environmental effects. Thus, it is important that brine be disposed using environmentally sound methods. Unfortunately, costs for the disposal of brine water are a significant burden to oil and gas producers in New York State. These costs and the relatively low market price of oil and natural gas have contributed to the decline in gas and oil production in New York State during the past 10 years. The objectives of this study were to evaluate new and existing options for brine disposal in New York State, examine the technical and economic merits of these options, and assess environmental impacts associated with each option. Two new disposal options investigated for New York State oil and gas producers included construction of a regional brine treatment facility to treat brine prior to discharge into a receiving water and a salt production facility that utilizes produced water as a feed stock. Both options are technically feasible; however, their economic viability depends on facility size and volume of brine treated.

  19. A review of theories on the origins of saline waters and brines in the Canadian Precambrian Shield

    International Nuclear Information System (INIS)

    Bottomley, D.J.

    1996-02-01

    Groundwater at depths greater that 500 m in the Canadian Precambrian Shield is typically saline with a sodium-calcium/chloride chemical composition. Brines with dissolved solid concentrations exceeding 100 g/L have been encountered in several deep mines (>1000 m) on the Shield. Theories on the origins of these deep saline waters and brines can be grouped into two general categories: (1) autochthonous (in situ) origins attributable to silicate mineral hydrolysis over geologic time scales, leaching of fluid inclusions or radiolysis effects, and (2) allochthonous (external) sources caused by the infiltration of brine of modified seawater origins in the geologic past. Although the chemical and isotopic compositions of these waters clearly reflect the effects of reaction between the water and their silicate host rocks, it is unlikely that the high chlorinity of the brines is in an autochthonous attribute. It is proposed that the compositions of these brines are most compatible with the Paleozoic residual brine hypothesis of Spencer (1987). This theory invokes deep infiltration of a high-density residual brine, formed by the evaporation of seawater during Devonian time, into underlying Precambrian basement rocks where subsequent chemical modifications occurred. (author) 39 refs., 2 figs

  20. Disposal/recovery options for brine waters from oil and gas production in New York State. Final report

    International Nuclear Information System (INIS)

    Matsumoto, M.R.; Atkinson, J.F.; Bunn, M.D.; Hodge, D.S.

    1996-03-01

    Produced water from oil and gas operations, or brine as it is typically referred, may be characterized as being highly saline, with total dissolved solids greater than 100 g/L. If these bribes are disposed improperly there may be severe adverse environmental effects. Thus, it is important that brine be disposed using environmentally sound methods. Unfortunately, costs for the disposal of brine water are a significant burden to oil and gas producers in New York State. These costs and the relatively low market price of oil and natural gas have contributed to the decline in gas and oil production in New York State during the past 10 years. The objectives of this study were to evaluate new and existing options for brine disposal in New York State, examine the technical and economic merits of these options, and assess environmental impacts associated with each option. Two new disposal options investigated for New York State oil and gas producers included construction of a regional brine treatment facility to treat brine prior to discharge into a receiving water and a salt production facility that utilizes produced water as a feed stock. Both options are technically feasible; however, their economic viability depends on facility size and volume of brine treated

  1. Doubly stratified MHD tangent hyperbolic nanofluid flow due to permeable stretched cylinder

    Science.gov (United States)

    Nagendramma, V.; Leelarathnam, A.; Raju, C. S. K.; Shehzad, S. A.; Hussain, T.

    2018-06-01

    An investigation is exhibited to analyze the presence of heat source and sink in doubly stratified MHD incompressible tangent hyperbolic fluid due to stretching of cylinder embedded in porous space under nanoparticles. To develop the mathematical model of tangent hyperbolic nanofluid, movement of Brownian and thermophoretic are accounted. The established equations of continuity, momentum, thermal and solutal boundary layers are reassembled into sets of non-linear expressions. These assembled expressions are executed with the help of Runge-Kutta scheme with MATLAB. The impacts of sundry parameters are illustrated graphically and the engineering interest physical quantities like skin friction, Nusselt and Sherwood number are examined by computing numerical values. It is clear that the power-law index parameter and curvature parameter shows favorable effect on momentum boundary layer thickness whereas Weissennberg number reveals inimical influence.

  2. Free convective flow of a stratified fluid through a porous medium bounded by a vertical plane

    Directory of Open Access Journals (Sweden)

    H. K. Mondal

    1994-01-01

    Full Text Available Steady two-dimensional free convection flow of a thermally stratified viscous fluid through a highly porous medium bounded by a vertical plane surface of varying temperature, is considered. Analytical expressions for the velocity, temperature and the rate of heat transfer are obtained by perturbation method. Velocity distribution and rate of heat transfer for different values of parameters are shown in graphs. Velocity distribution is also obtained for certain values of the parameters by integrating the coupled differential equations by Runge-Kutta method and compared with the analytical solution. The chief concern of the paper is to study the effect of equilibrium temperature gradient on the velocity and the rate of heat transfer.

  3. An algorithm for solving the optical problem for stratified anisotropic media

    Energy Technology Data Exchange (ETDEWEB)

    Palto, S P [Shubnikov Institute of Crystallography, Russian Academy of Sciences, Leninskii pr. 59, Moscow, 117333 (Russian Federation)

    2001-04-01

    An algorithm for solving the Maxwell equations for propagation of light through anisotropic stratified media is considered. The algorithm uses the Berreman matrices of order 4 x 4. In contrast to the numerical methods suggested by Berreman, the new method is exact. The Sylvester theorem for calculating functions of a matrix and the Laguerre method for determining eigenvalues provide the basis for an algorithm with an efficiency comparable to that of the algorithms based on analytic solutions, which exist only in the case of uniaxial media. The method suggested in this paper allows for the analysis of complex optical systems where the effects of biaxiality, magnetic anisotropy, and optical activity play an important role.

  4. Injection, injectivity and injectability in geothermal operations: problems and possible solutions. Phase I. Definition of the problems

    Energy Technology Data Exchange (ETDEWEB)

    Vetter, O.J.; Crichlow, H.B.

    1979-02-14

    The following topics are covered: thermodynamic instability of brine, injectivity loss during regular production and injection operations, injectivity loss caused by measures other than regular operations, heat mining and associated reservoir problems in reinjection, pressure maintenance through imported make-up water, suggested solutions to injection problems, and suggested solutions to injection problems: remedial and stimulation measures. (MHR)

  5. Crystallization of a compositionally stratified basal magma ocean

    Science.gov (United States)

    Laneuville, Matthieu; Hernlund, John; Labrosse, Stéphane; Guttenberg, Nicholas

    2018-03-01

    Earth's ∼3.45 billion year old magnetic field is regenerated by dynamo action in its convecting liquid metal outer core. However, convection induces an isentropic thermal gradient which, coupled with a high core thermal conductivity, results in rapid conducted heat loss. In the absence of implausibly high radioactivity or alternate sources of motion to drive the geodynamo, the Earth's early core had to be significantly hotter than the melting point of the lower mantle. While the existence of a dense convecting basal magma ocean (BMO) has been proposed to account for high early core temperatures, the requisite physical and chemical properties for a BMO remain controversial. Here we relax the assumption of a well-mixed convecting BMO and instead consider a BMO that is initially gravitationally stratified owing to processes such as mixing between metals and silicates at high temperatures in the core-mantle boundary region during Earth's accretion. Using coupled models of crystallization and heat transfer through a stratified BMO, we show that very high temperatures could have been trapped inside the early core, sequestering enough heat energy to run an ancient geodynamo on cooling power alone.

  6. Dyadic Green's function of an eccentrically stratified sphere.

    Science.gov (United States)

    Moneda, Angela P; Chrissoulidis, Dimitrios P

    2014-03-01

    The electric dyadic Green's function (dGf) of an eccentrically stratified sphere is built by use of the superposition principle, dyadic algebra, and the addition theorem of vector spherical harmonics. The end result of the analytical formulation is a set of linear equations for the unknown vector wave amplitudes of the dGf. The unknowns are calculated by truncation of the infinite sums and matrix inversion. The theory is exact, as no simplifying assumptions are required in any one of the analytical steps leading to the dGf, and it is general in the sense that any number, position, size, and electrical properties can be considered for the layers of the sphere. The point source can be placed outside of or in any lossless part of the sphere. Energy conservation, reciprocity, and other checks verify that the dGf is correct. A numerical application is made to a stratified sphere made of gold and glass, which operates as a lens.

  7. Crenothrix are major methane consumers in stratified lakes.

    Science.gov (United States)

    Oswald, Kirsten; Graf, Jon S; Littmann, Sten; Tienken, Daniela; Brand, Andreas; Wehrli, Bernhard; Albertsen, Mads; Daims, Holger; Wagner, Michael; Kuypers, Marcel Mm; Schubert, Carsten J; Milucka, Jana

    2017-09-01

    Methane-oxidizing bacteria represent a major biological sink for methane and are thus Earth's natural protection against this potent greenhouse gas. Here we show that in two stratified freshwater lakes a substantial part of upward-diffusing methane was oxidized by filamentous gamma-proteobacteria related to Crenothrix polyspora. These filamentous bacteria have been known as contaminants of drinking water supplies since 1870, but their role in the environmental methane removal has remained unclear. While oxidizing methane, these organisms were assigned an 'unusual' methane monooxygenase (MMO), which was only distantly related to 'classical' MMO of gamma-proteobacterial methanotrophs. We now correct this assignment and show that Crenothrix encode a typical gamma-proteobacterial PmoA. Stable isotope labeling in combination swith single-cell imaging mass spectrometry revealed methane-dependent growth of the lacustrine Crenothrix with oxygen as well as under oxygen-deficient conditions. Crenothrix genomes encoded pathways for the respiration of oxygen as well as for the reduction of nitrate to N 2 O. The observed abundance and planktonic growth of Crenothrix suggest that these methanotrophs can act as a relevant biological sink for methane in stratified lakes and should be considered in the context of environmental removal of methane.

  8. Random forcing of geostrophic motion in rotating stratified turbulence

    Science.gov (United States)

    Waite, Michael L.

    2017-12-01

    Random forcing of geostrophic motion is a common approach in idealized simulations of rotating stratified turbulence. Such forcing represents the injection of energy into large-scale balanced motion, and the resulting breakdown of quasi-geostrophic turbulence into inertia-gravity waves and stratified turbulence can shed light on the turbulent cascade processes of the atmospheric mesoscale. White noise forcing is commonly employed, which excites all frequencies equally, including frequencies much higher than the natural frequencies of large-scale vortices. In this paper, the effects of these high frequencies in the forcing are investigated. Geostrophic motion is randomly forced with red noise over a range of decorrelation time scales τ, from a few time steps to twice the large-scale vortex time scale. It is found that short τ (i.e., nearly white noise) results in about 46% more gravity wave energy than longer τ, despite the fact that waves are not directly forced. We argue that this effect is due to wave-vortex interactions, through which the high frequencies in the forcing are able to excite waves at their natural frequencies. It is concluded that white noise forcing should be avoided, even if it is only applied to the geostrophic motion, when a careful investigation of spontaneous wave generation is needed.

  9. Improvements to TRAC models of condensing stratified flow. Pt. 1

    International Nuclear Information System (INIS)

    Zhang, Q.; Leslie, D.C.

    1991-12-01

    Direct contact condensation in stratified flow is an important phenomenon in LOCA analyses. In this report, the TRAC interfacial heat transfer model for stratified condensing flow has been assessed against the Bankoff experiments. A rectangular channel option has been added to the code to represent the experimental geometry. In almost all cases the TRAC heat transfer coefficient (HTC) over-predicts the condensation rates and in some cases it is so high that the predicted steam is sucked in from the normal outlet in order to conserve mass. Based on their cocurrent and countercurrent condensing flow experiments, Bankoff and his students (Lim 1981, Kim 1985) developed HTC models from the two cases. The replacement of the TRAC HTC with either of Bankoff's models greatly improves the predictions of condensation rates in the experiment with cocurrent condensing flow. However, the Bankoff HTC for countercurrent flow is preferable because it is based only on the local quantities rather than on the quantities averaged from the inlet. (author)

  10. Designing Wood Supply Scenarios from Forest Inventories with Stratified Predictions

    Directory of Open Access Journals (Sweden)

    Philipp Kilham

    2018-02-01

    Full Text Available Forest growth and wood supply projections are increasingly used to estimate the future availability of woody biomass and the correlated effects on forests and climate. This research parameterizes an inventory-based business-as-usual wood supply scenario, with a focus on southwest Germany and the period 2002–2012 with a stratified prediction. First, the Classification and Regression Trees algorithm groups the inventory plots into strata with corresponding harvest probabilities. Second, Random Forest algorithms generate individual harvest probabilities for the plots of each stratum. Third, the plots with the highest individual probabilities are selected as harvested until the harvest probability of the stratum is fulfilled. Fourth, the harvested volume of these plots is predicted with a linear regression model trained on harvested plots only. To illustrate the pros and cons of this method, it is compared to a direct harvested volume prediction with linear regression, and a combination of logistic regression and linear regression. Direct harvested volume regression predicts comparable volume figures, but generates these volumes in a way that differs from business-as-usual. The logistic model achieves higher overall classification accuracies, but results in underestimations or overestimations of harvest shares for several subsets of the data. The stratified prediction method balances this shortcoming, and can be of general use for forest growth and timber supply projections from large-scale forest inventories.

  11. Internal circle uplifts, transversality and stratified G-structures

    Energy Technology Data Exchange (ETDEWEB)

    Babalic, Elena Mirela [Department of Theoretical Physics, National Institute of Physics and Nuclear Engineering,Str. Reactorului no.30, P.O.BOX MG-6, Postcode 077125, Bucharest-Magurele (Romania); Department of Physics, University of Craiova,13 Al. I. Cuza Str., Craiova 200585 (Romania); Lazaroiu, Calin Iuliu [Center for Geometry and Physics, Institute for Basic Science,Pohang 790-784 (Korea, Republic of)

    2015-11-24

    We study stratified G-structures in N=2 compactifications of M-theory on eight-manifolds M using the uplift to the auxiliary nine-manifold M̂=M×S{sup 1}. We show that the cosmooth generalized distribution D̂ on M̂ which arises in this formalism may have pointwise transverse or non-transverse intersection with the pull-back of the tangent bundle of M, a fact which is responsible for the subtle relation between the spinor stabilizers arising on M and M̂ and for the complicated stratified G-structure on M which we uncovered in previous work. We give a direct explanation of the latter in terms of the former and relate explicitly the defining forms of the SU(2) structure which exists on the generic locus U of M to the defining forms of the SU(3) structure which exists on an open subset Û of M̂, thus providing a dictionary between the eight- and nine-dimensional formalisms.

  12. A modified stratified model for the 3C 273 jet

    International Nuclear Information System (INIS)

    Liu Wenpo; Shen Zhiqiang

    2009-01-01

    We present a modified stratified jet model to interpret the observed spectral energy distributions of knots in the 3C 273 jet. Based on the hypothesis of the single index of the particle energy spectrum at injection and identical emission processes among all the knots, the observed difference of spectral shape among different 3C 273 knots can be understood as a manifestation of the deviation of the equivalent Doppler factor of stratified emission regions in an individual knot from a characteristic one. The summed spectral energy distributions of all ten knots in the 3C 273 jet can be well fitted by two components: a low-energy component (radio to optical) dominated by synchrotron radiation and a high-energy component (UV, X-ray and γ-ray) dominated by inverse Compton scattering of the cosmic microwave background. This gives a consistent spectral index of α = 0.88 (S v ∝ v -α ) and a characteristic Doppler factor of 7.4. Assuming the average of the summed spectrum as the characteristic spectrum of each knot in the 3C 273 jet, we further get a distribution of Doppler factors. We discuss the possible implications of these results for the physical properties in the 3C 273 jet. Future GeV observations with GLAST could separate the γ-ray emission of 3C 273 from the large scale jet and the small scale jet (i.e. the core) through measuring the GeV spectrum.

  13. Measuring mixing efficiency in experiments of strongly stratified turbulence

    Science.gov (United States)

    Augier, P.; Campagne, A.; Valran, T.; Calpe Linares, M.; Mohanan, A. V.; Micard, D.; Viboud, S.; Segalini, A.; Mordant, N.; Sommeria, J.; Lindborg, E.

    2017-12-01

    Oceanic and atmospheric models need better parameterization of the mixing efficiency. Therefore, we need to measure this quantity for flows representative of geophysical flows, both in terms of types of flows (with vortices and/or waves) and of dynamical regimes. In order to reach sufficiently large Reynolds number for strongly stratified flows, experiments for which salt is used to produce the stratification have to be carried out in a large rotating platform of at least 10-meter diameter.We present new experiments done in summer 2017 to study experimentally strongly stratified turbulence and mixing efficiency in the Coriolis platform. The flow is forced by a slow periodic movement of an array of large vertical or horizontal cylinders. The velocity field is measured by 3D-2C scanned horizontal particles image velocimetry (PIV) and 2D vertical PIV. Six density-temperature probes are used to measure vertical and horizontal profiles and signals at fixed positions.We will show how we rely heavily on open-science methods for this study. Our new results on the mixing efficiency will be presented and discussed in terms of mixing parameterization.

  14. Optimal energy growth in a stably stratified shear flow

    Science.gov (United States)

    Jose, Sharath; Roy, Anubhab; Bale, Rahul; Iyer, Krithika; Govindarajan, Rama

    2018-02-01

    Transient growth of perturbations by a linear non-modal evolution is studied here in a stably stratified bounded Couette flow. The density stratification is linear. Classical inviscid stability theory states that a parallel shear flow is stable to exponentially growing disturbances if the Richardson number (Ri) is greater than 1/4 everywhere in the flow. Experiments and numerical simulations at higher Ri show however that algebraically growing disturbances can lead to transient amplification. The complexity of a stably stratified shear flow stems from its ability to combine this transient amplification with propagating internal gravity waves (IGWs). The optimal perturbations associated with maximum energy amplification are numerically obtained at intermediate Reynolds numbers. It is shown that in this wall-bounded flow, the three-dimensional optimal perturbations are oblique, unlike in unstratified flow. A partitioning of energy into kinetic and potential helps in understanding the exchange of energies and how it modifies the transient growth. We show that the apportionment between potential and kinetic energy depends, in an interesting manner, on the Richardson number, and on time, as the transient growth proceeds from an optimal perturbation. The oft-quoted stabilizing role of stratification is also probed in the non-diffusive limit in the context of disturbance energy amplification.

  15. Water and waste water, when brine's just fine

    International Nuclear Information System (INIS)

    Lamb, Garth

    2007-01-01

    Desalination has always sounded a good solution to rainfall shortages, who wouldn't rather drink purified seawater than recycled sewage? But projects in Australia and around the world have often been dogged by question marks over cost and greenhouse effects and saline discharge issues. Solar powered pilot plant is being developed in South Australia which will not discharge a drop of briny reject water back to the sea

  16. Reflection and transmission of electromagnetic waves in planarly stratified media

    International Nuclear Information System (INIS)

    Caviglia, G.

    1999-01-01

    Propagation of time-harmonic electromagnetic waves in planarly stratified multilayers is investigated. Each layer is allowed to be inhomogeneous and the layers are separated by interfaces. The procedure is based on the representation of the electromagnetic field in the basis of the eigenvectors of the matrix characterizing the first-order system. Hence the local reflection and transmission matrices are defined and the corresponding differential equations, in the pertinent space variable are determined. The jump conditions at interfaces are also established. The present model incorporates dissipative materials and the procedure holds without any restrictions to material symmetries. Differential equations appeared in the literature are shown to hold in particular (one-dimensional) cases or to represent homogeneous layers only

  17. Microstructure of Turbulence in the Stably Stratified Boundary Layer

    Science.gov (United States)

    Sorbjan, Zbigniew; Balsley, Ben B.

    2008-11-01

    The microstructure of a stably stratified boundary layer, with a significant low-level nocturnal jet, is investigated based on observations from the CASES-99 campaign in Kansas, U.S.A. The reported, high-resolution vertical profiles of the temperature, wind speed, wind direction, pressure, and the turbulent dissipation rate, were collected under nocturnal conditions on October 14, 1999, using the CIRES Tethered Lifting System. Two methods for evaluating instantaneous (1-sec) background profiles are applied to the raw data. The background potential temperature is calculated using the “bubble sort” algorithm to produce a monotonically increasing potential temperature with increasing height. Other scalar quantities are smoothed using a running vertical average. The behaviour of background flow, buoyant overturns, turbulent fluctuations, and their respective histograms are presented. Ratios of the considered length scales and the Ozmidov scale are nearly constant with height, a fact that can be applied in practice for estimating instantaneous profiles of the dissipation rate.

  18. Hydrodynamics of stratified epithelium: Steady state and linearized dynamics

    Science.gov (United States)

    Yeh, Wei-Ting; Chen, Hsuan-Yi

    2016-05-01

    A theoretical model for stratified epithelium is presented. The viscoelastic properties of the tissue are assumed to be dependent on the spatial distribution of proliferative and differentiated cells. Based on this assumption, a hydrodynamic description of tissue dynamics at the long-wavelength, long-time limit is developed, and the analysis reveals important insights into the dynamics of an epithelium close to its steady state. When the proliferative cells occupy a thin region close to the basal membrane, the relaxation rate towards the steady state is enhanced by cell division and cell apoptosis. On the other hand, when the region where proliferative cells reside becomes sufficiently thick, a flow induced by cell apoptosis close to the apical surface enhances small perturbations. This destabilizing mechanism is general for continuous self-renewal multilayered tissues; it could be related to the origin of certain tissue morphology, tumor growth, and the development pattern.

  19. Hydromagnetic stability of rotating stratified compressible fluid flows

    Energy Technology Data Exchange (ETDEWEB)

    Srinivasan, V; Kandaswamy, P [Dept. of Mathematics, Bharathiar University, Coimbatore, Tamil Nadu, India; Debnath, L [Dept. of Mathematics, University of Central Florida, Orlando, USA

    1984-09-01

    The hydromagnetic stability of a radially stratified compressible fluid rotating between two coaxial cylinders is investigated. The stability with respect to axisymmetric disturbances is examined. The fluid system is found to be thoroughly stable to axisymmetric disturbances provided the fluid rotates very rapidly. The system is shown to be unstable to non-axisymmetric disturbances, and the slow amplifying hydromagnetic wave modes propagate against the basic rotation. The lower and upper bounds of the azimuthal phase speeds of the amplifying waves are determined. A quadrant theorem on the slow waves characteristic of a rapidly rotating fluid is derived. Special attention is given to the effects of compressibility of the fluid. Some results concerning the stability of an incompressible fluid system are obtained as special cases of the present analysis.

  20. The Risk-Stratified Osteoporosis Strategy Evaluation study (ROSE)

    DEFF Research Database (Denmark)

    Rubin, Katrine Hass; Holmberg, Teresa; Rothmann, Mette Juel

    2015-01-01

    The risk-stratified osteoporosis strategy evaluation study (ROSE) is a randomized prospective population-based study investigating the effectiveness of a two-step screening program for osteoporosis in women. This paper reports the study design and baseline characteristics of the study population....... 35,000 women aged 65-80 years were selected at random from the population in the Region of Southern Denmark and-before inclusion-randomized to either a screening group or a control group. As first step, a self-administered questionnaire regarding risk factors for osteoporosis based on FRAX......(®) was issued to both groups. As second step, subjects in the screening group with a 10-year probability of major osteoporotic fractures ≥15 % were offered a DXA scan. Patients diagnosed with osteoporosis from the DXA scan were advised to see their GP and discuss pharmaceutical treatment according to Danish...

  1. Temporally stratified sampling programs for estimation of fish impingement

    International Nuclear Information System (INIS)

    Kumar, K.D.; Griffith, J.S.

    1977-01-01

    Impingement monitoring programs often expend valuable and limited resources and fail to provide a dependable estimate of either total annual impingement or those biological and physicochemical factors affecting impingement. In situations where initial monitoring has identified ''problem'' fish species and the periodicity of their impingement, intensive sampling during periods of high impingement will maximize information obtained. We use data gathered at two nuclear generating facilities in the southeastern United States to discuss techniques of designing such temporally stratified monitoring programs and their benefits and drawbacks. Of the possible temporal patterns in environmental factors within a calendar year, differences among seasons are most influential in the impingement of freshwater fishes in the Southeast. Data on the threadfin shad (Dorosoma petenense) and the role of seasonal temperature changes are utilized as an example to demonstrate ways of most efficiently and accurately estimating impingement of the species

  2. Direct numerical simulation of homogeneous stratified rotating turbulence

    Energy Technology Data Exchange (ETDEWEB)

    Iida, O.; Tsujimura, S.; Nagano, Y. [Nagoya Institute of Technology, Department of Mech. Eng., Nagoya (Japan)

    2005-12-01

    The effects of the Prandtl number on stratified rotating turbulence have been studied in homogeneous turbulence by using direct numerical simulations and a rapid distortion theory. Fluctuations under strong stable-density stratification can be theoretically divided into the WAVE and the potential vorticity (PV) modes. In low-Prandtl-number fluids, the WAVE mode deteriorates, while the PV mode remains. Imposing rotation on a low-Prandtl-number fluid makes turbulence two-dimensional as well as geostrophic; it is found from the instantaneous turbulent structure that the vortices merge to form a few vertically-elongated vortex columns. During the period toward two-dimensionalization, the vertical vortices become asymmetric in the sense of rotation. (orig.)

  3. Advanced stratified charge rotary aircraft engine design study

    Science.gov (United States)

    Badgley, P.; Berkowitz, M.; Jones, C.; Myers, D.; Norwood, E.; Pratt, W. B.; Ellis, D. R.; Huggins, G.; Mueller, A.; Hembrey, J. H.

    1982-01-01

    A technology base of new developments which offered potential benefits to a general aviation engine was compiled and ranked. Using design approaches selected from the ranked list, conceptual design studies were performed of an advanced and a highly advanced engine sized to provide 186/250 shaft Kw/HP under cruise conditions at 7620/25,000 m/ft altitude. These are turbocharged, direct-injected stratified charge engines intended for commercial introduction in the early 1990's. The engine descriptive data includes tables, curves, and drawings depicting configuration, performance, weights and sizes, heat rejection, ignition and fuel injection system descriptions, maintenance requirements, and scaling data for varying power. An engine-airframe integration study of the resulting engines in advanced airframes was performed on a comparative basis with current production type engines. The results show airplane performance, costs, noise & installation factors. The rotary-engined airplanes display substantial improvements over the baseline, including 30 to 35% lower fuel usage.

  4. Prototypic Features of Loneliness in a Stratified Sample of Adolescents

    Directory of Open Access Journals (Sweden)

    Mathias Lasgaard

    2009-06-01

    Full Text Available Dominant theoretical approaches in loneliness research emphasize the value of personality characteristics in explaining loneliness. The present study examines whether dysfunctional social strategies and attributions in lonely adolescents can be explained by personality characteristics. A questionnaire survey was conducted with 379 Danish Grade 8 students (M = 14.1 years, SD = 0.4 from 22 geographically stratified and randomly selected schools. Hierarchical linear regression analysis showed that network orientation, success expectation and avoidance in affiliative situations predicted loneliness independent of personality characteristics, demographics and social desirability. The study indicates that dysfunctional strategies and attributions in affiliative situations are directly related to loneliness in adolescence. These strategies and attributions may preclude lonely adolescents from guidance and intervention. Thus, professionals need to be knowledgeable about prototypic features of loneliness in addition to employing a pro-active approach when assisting adolescents who display prototypic features.

  5. The optimism trap: Migrants' educational choices in stratified education systems.

    Science.gov (United States)

    Tjaden, Jasper Dag; Hunkler, Christian

    2017-09-01

    Immigrant children's ambitious educational choices have often been linked to their families' high level of optimism and motivation for upward mobility. However, previous research has mostly neglected alternative explanations such as information asymmetries or anticipated discrimination. Moreover, immigrant children's higher dropout rates at the higher secondary and university level suggest that low performing migrant students could have benefitted more from pursuing less ambitious tracks, especially in countries that offer viable vocational alternatives. We examine ethnic minority's educational choices using a sample of academically low performing, lower secondary school students in Germany's highly stratified education system. We find that their families' optimism diverts migrant students from viable vocational alternatives. Information asymmetries and anticipated discrimination do not explain their high educational ambitions. While our findings further support the immigrant optimism hypothesis, we discuss how its effect may have different implications depending on the education system. Copyright © 2017. Published by Elsevier Inc.

  6. Internal combustion engine using premixed combustion of stratified charges

    Science.gov (United States)

    Marriott, Craig D [Rochester Hills, MI; Reitz, Rolf D [Madison, WI

    2003-12-30

    During a combustion cycle, a first stoichiometrically lean fuel charge is injected well prior to top dead center, preferably during the intake stroke. This first fuel charge is substantially mixed with the combustion chamber air during subsequent motion of the piston towards top dead center. A subsequent fuel charge is then injected prior to top dead center to create a stratified, locally richer mixture (but still leaner than stoichiometric) within the combustion chamber. The locally rich region within the combustion chamber has sufficient fuel density to autoignite, and its self-ignition serves to activate ignition for the lean mixture existing within the remainder of the combustion chamber. Because the mixture within the combustion chamber is overall premixed and relatively lean, NO.sub.x and soot production are significantly diminished.

  7. Dynamics of the east India coastal current. 2. Numerical solutions

    Digital Repository Service at National Institute of Oceanography (India)

    McCreary, J.P.; Han, W.; Shankar, D.; Shetye, S.R.

    A linear, continuously stratified model is used to investigate the dynamics of the East India Coastal Current (EICC). Solutions are found numerically in a basin that resembles the Indian Ocean basin north of 29 degrees S, and they are forced...

  8. Longevity of Compositionally Stratified Layers in Ice Giants

    Science.gov (United States)

    Friedson, A. J.

    2017-12-01

    In the hydrogen-rich atmospheres of gas giants, a decrease with radius in the mixing ratio of a heavy species (e.g. He, CH4, H2O) has the potential to produce a density stratification that is convectively stable if the heavy species is sufficiently abundant. Formation of stable layers in the interiors of these planets has important implications for their internal structure, chemical mixing, dynamics, and thermal evolution, since vertical transport of heat and constituents in such layers is greatly reduced in comparison to that in convecting layers. Various processes have been suggested for creating compositionally stratified layers. In the interiors of Jupiter and Saturn, these include phase separation of He from metallic hydrogen and dissolution of dense core material into the surrounding metallic-H envelope. Condensation of methane and water has been proposed as a mechanism for producing stable zones in the atmospheres of Saturn and the ice giants. However, if a stably stratified layer is formed adjacent to an active region of convection, it may be susceptible to progressive erosion as the convection intrudes and entrains fluid into the unstable envelope. We discuss the principal factors that control the rate of entrainment and associated erosion and present a specific example concerning the longevity of stable layers formed by condensation of methane and water in Uranus and Neptune. We also consider whether the temporal variability of such layers may engender episodic behavior in the release of the internal heat of these planets. This research is supported by a grant from the NASA Solar System Workings Program.

  9. Investigations on flow reversal in stratified horizontal flow

    International Nuclear Information System (INIS)

    Staebler, T.; Meyer, L.; Schulenberg, T.; Laurien, E.

    2005-01-01

    The phenomena of flow reversal in stratified flows are investigated in a horizontal channel with application to the Emergency Core Cooling System (ECCS) in Pressurized Water Reactors (PWR). In case of a Loss-of-Coolant-Accident (LOCA), coolant can be injected through a secondary pipe within the feeding line of the primary circuit, the so called hot leg, counter-currently to the steam flow. It is essential that the coolant reaches the reactor core to prevent overheating. Due to high temperatures in such accident scenarios, steam is generated in the core, which escapes from the reactor vessel through the hot leg. In case of sufficiently high steam flow rates, only a reduced amount of coolant or even no coolant will be delivered to the reactor core. The WENKA test facility at the Institute for Nuclear and Energy Technologies (IKET) at Forschungszentrum Karlsruhe is capable to investigate the fluid dynamics of two-phase flows in such scenarios. Water and air flow counter-currently in a horizontal channel made of clear acrylic glass to allow full optical access. Flow rates of water and air can be varied independently within a wide range. Once flow reversal sets in, a strong hysteresis effect must be taken into account. This was quantified during the present investigations. Local experimental data are needed to expand appropriate models on flow reversal in horizontal two-phase flow and to include them into numerical codes. Investigations are carried out by means of Particle Image Velocimetry (PIV) to obtain local flow velocities without disturbing the flow. Due to the wavy character of the flow, strong reflections at the interfacial area must be taken into account. Using fluorescent particles and an optical filter allows eliminating the reflections and recording only the signals of the particles. The challenges in conducting local investigations in stratified wavy flows by applying optical measurement techniques are discussed. Results are presented and discussed allowing

  10. Stratified flow model for convective condensation in an inclined tube

    International Nuclear Information System (INIS)

    Lips, Stéphane; Meyer, Josua P.

    2012-01-01

    Highlights: ► Convective condensation in an inclined tube is modelled. ► The heat transfer coefficient is the highest for about 20° below the horizontal. ► Capillary forces have a strong effect on the liquid–vapour interface shape. ► A good agreement between the model and the experimental results was observed. - Abstract: Experimental data are reported for condensation of R134a in an 8.38 mm inner diameter smooth tube in inclined orientations with a mass flux of 200 kg/m 2 s. Under these conditions, the flow is stratified and there is an optimum inclination angle, which leads to the highest heat transfer coefficient. There is a need for a model to better understand and predict the flow behaviour. In this paper, the state of the art of existing models of stratified two-phase flows in inclined tubes is presented, whereafter a new mechanistic model is proposed. The liquid–vapour distribution in the tube is determined by taking into account the gravitational and the capillary forces. The comparison between the experimental data and the model prediction showed a good agreement in terms of heat transfer coefficients and pressure drops. The effect of the interface curvature on the heat transfer coefficient has been quantified and has been found to be significant. The optimum inclination angle is due to a balance between an increase of the void fraction and an increase in the falling liquid film thickness when the tube is inclined downwards. The effect of the mass flux and the vapour quality on the optimum inclination angle has also been studied.

  11. Synchronized dynamics of bacterial niche-specific functions during biofilm development in a cold seep brine pool

    KAUST Repository

    Zhang, Weipeng; Wang, Yong; Bougouffa, Salim; Tian, Renmao; Cao, Huiluo; Li, Yongxin; Cai, Lin; Wong, Yue Him; Zhang, Gen; Zhou, Guowei; Zhang, Xixiang; Bajic, Vladimir B.; Al-Suwailem, Abdulaziz M.; Qian, Pei-Yuan

    2015-01-01

    in the brine biofilms were reconstructed. Despite rather small genome sizes, the deltaproteobacterium possessed enhanced polysaccharide fermentation pathways, whereas the epsilonproteobacterium was a versatile nitrogen reactor possessing nar, nap and nif gene

  12. The effect of stratigraphic dip on brine inflow and gas migration at the Waste Isolation Pilot Plant

    International Nuclear Information System (INIS)

    Webb, S.W.; Larson, K.W.

    1996-02-01

    The natural dip of the Salado Formation at the Waste Isolation Pilot Plant (WIPP), although regionally only about 111, has the potential to affect brine inflow and gas-migration distances due to buoyancy forces. Current models, including those in WIPP Performance Assessment calculations, assume a perfectly horizontal repository and stratigraphy. With the addition of buoyancy forces due to the dip, brine and gas flow patterns can be affected. Brine inflow may increase due to countercurrent flow, and gas may preferentially migrate up dip. This scoping study has used analytical and numerical modeling to evaluate the impact of the dip on brine inflow and gas-migration distances at the WIPP in one, two, and three dimensions. Sensitivities to interbed permeabilities, two-phase curves, gas-generation rates, and interbed fracturing were studied

  13. The effect of stratigraphic dip on brine inflow and gas migration at the Waste Isolation Pilot Plant

    Energy Technology Data Exchange (ETDEWEB)

    Webb, S.W. [Sandia National Labs., Albuquerque, NM (United States); Larson, K.W. [INTERA, Inc., Albuquerque, NM (United States)

    1996-02-01

    The natural dip of the Salado Formation at the Waste Isolation Pilot Plant (WIPP), although regionally only about 111, has the potential to affect brine inflow and gas-migration distances due to buoyancy forces. Current models, including those in WIPP Performance Assessment calculations, assume a perfectly horizontal repository and stratigraphy. With the addition of buoyancy forces due to the dip, brine and gas flow patterns can be affected. Brine inflow may increase due to countercurrent flow, and gas may preferentially migrate up dip. This scoping study has used analytical and numerical modeling to evaluate the impact of the dip on brine inflow and gas-migration distances at the WIPP in one, two, and three dimensions. Sensitivities to interbed permeabilities, two-phase curves, gas-generation rates, and interbed fracturing were studied.

  14. Variations in isotopic compositions of chlorine in evaporation-controlled salt lake brines of Qaidam Basin, China

    Digital Repository Service at National Institute of Oceanography (India)

    Xiao, Ying-kai; Liu, Wei-guo; Zhou, Y.M.; Wang, Yun-hui; Shirodkar, P.V.

    The variations in the isotopic compositions of chlorine in evaporation-controlled saline lake brines were determined by using an improved procedure for precise measurement of chlorine isotopes based on Cs sub(2) Cl sup(+) ion by thermal ionization...

  15. Generation of Chemical Commodities and Fertilizer from ISS and ISRU Water Brines Using Combined Ion Exchange and Electrodialysis

    Data.gov (United States)

    National Aeronautics and Space Administration — The goal is to develop a next generation brine recovery and electrolysis grade potable water producing system for Environmental Control and Life Support System...

  16. Environmental impacts of oil and gas brine applications for dust and ice control in New York : final report.

    Science.gov (United States)

    2016-04-01

    Transportation agencies are required to treat roads for dust and ice control to ensure adequate safety for travelers. This is commonly achieved through application of solid and liquid chemicals. These materials can be conventional rock salt, brine fr...

  17. Changes of washing water during debittering and the brine during storage of irradiated olive fruits (Olea Europea. 1.)

    International Nuclear Information System (INIS)

    Al-Bachir, M.

    2003-01-01

    Olive fruits (Olea Europea. var. Surrany) treated with 0, 1, 2, and 3 kGy of gamma irradiation were debittered in distilled water for 8 days and stored in brine for 12 months at room temperature. Total dissolved and inorganic dissolved solids, Na, K, Ca, electric conductivity (EC) and pH values were evaluated in washing wastewater 9 daily), and in brine (after 6 and 12 months). The results showed that gamma irradiation increased the total and inorganic dissolved solids, Na and K in washing wastewater, and in brine throughout debittering and storage periods. Also, gamma irradiation had an effect on EC and pH values of washing wastewater and brine. (author)

  18. Changes of washing water during debittering and the brine during storage of irradiated olive fruits (Olea europea. L.)

    International Nuclear Information System (INIS)

    AL-Bachir, M.

    2001-01-01

    Olive fruits (Olea europea. var. Surrany) treated with 0, 1, 2 and 3 kGy of gamma irradiation were debittered in distilled water for 8 days and stored in brine for 12 months at room temperature. Total dissolved and inorganic dissolved solids, Na, K, Ca, electric conductivity (EC) and pH values were evaluated in washing wastewater (daily), and in brine (after 6 and 12 months). The results showed that gamma irradiation increased the total and inorganic dissolved solids, Na and K in washing wastewater, and in brine throughout debittering and storage periods. Also, gamma irradiation had an effect on EC and pH values of washing wastewater and brine [es

  19. Beyond Chloride Brines: Variable Metabolomic Responses in the Anaerobic Organism Yersinia intermedia MASE-LG-1 to NaCl and MgSO4 at Identical Water Activity

    Science.gov (United States)

    Schwendner, Petra; Bohmeier, Maria; Rettberg, Petra; Beblo-Vranesevic, Kristina; Gaboyer, Frédéric; Moissl-Eichinger, Christine; Perras, Alexandra K.; Vannier, Pauline; Marteinsson, Viggó T.; Garcia-Descalzo, Laura; Gómez, Felipe; Malki, Moustafa; Amils, Ricardo; Westall, Frances; Riedo, Andreas; Monaghan, Euan P.; Ehrenfreund, Pascale; Cabezas, Patricia; Walter, Nicolas; Cockell, Charles

    2018-01-01

    Growth in sodium chloride (NaCl) is known to induce stress in non-halophilic microorganisms leading to effects on the microbial metabolism and cell structure. Microorganisms have evolved a number of adaptations, both structural and metabolic, to counteract osmotic stress. These strategies are well-understood for organisms in NaCl-rich brines such as the accumulation of certain organic solutes (known as either compatible solutes or osmolytes). Less well studied are responses to ionic environments such as sulfate-rich brines which are prevalent on Earth but can also be found on Mars. In this paper, we investigated the global metabolic response of the anaerobic bacterium Yersinia intermedia MASE-LG-1 to osmotic salt stress induced by either magnesium sulfate (MgSO4) or NaCl at the same water activity (0.975). Using a non-targeted mass spectrometry approach, the intensity of hundreds of metabolites was measured. The compatible solutes L-asparagine and sucrose were found to be increased in both MgSO4 and NaCl compared to the control sample, suggesting a similar osmotic response to different ionic environments. We were able to demonstrate that Yersinia intermedia MASE-LG-1 accumulated a range of other compatible solutes. However, we also found the global metabolic responses, especially with regard to amino acid metabolism and carbohydrate metabolism, to be salt-specific, thus, suggesting ion-specific regulation of specific metabolic pathways. PMID:29535699

  20. Beyond Chloride Brines: Variable Metabolomic Responses in the Anaerobic Organism Yersinia intermedia MASE-LG-1 to NaCl and MgSO4 at Identical Water Activity

    Directory of Open Access Journals (Sweden)

    Petra Schwendner

    2018-02-01

    Full Text Available Growth in sodium chloride (NaCl is known to induce stress in non-halophilic microorganisms leading to effects on the microbial metabolism and cell structure. Microorganisms have evolved a number of adaptations, both structural and metabolic, to counteract osmotic stress. These strategies are well-understood for organisms in NaCl-rich brines such as the accumulation of certain organic solutes (known as either compatible solutes or osmolytes. Less well studied are responses to ionic environments such as sulfate-rich brines which are prevalent on Earth but can also be found on Mars. In this paper, we investigated the global metabolic response of the anaerobic bacterium Yersinia intermedia MASE-LG-1 to osmotic salt stress induced by either magnesium sulfate (MgSO4 or NaCl at the same water activity (0.975. Using a non-targeted mass spectrometry approach, the intensity of hundreds of metabolites was measured. The compatible solutes L-asparagine and sucrose were found to be increased in both MgSO4 and NaCl compared to the control sample, suggesting a similar osmotic response to different ionic environments. We were able to demonstrate that Yersinia intermedia MASE-LG-1 accumulated a range of other compatible solutes. However, we also found the global metabolic responses, especially with regard to amino acid metabolism and carbohydrate metabolism, to be salt-specific, thus, suggesting ion-specific regulation of specific metabolic pathways.

  1. Effects of temperature, temperature gradients, stress, and irradiation on migration of brine inclusions in a salt repository

    International Nuclear Information System (INIS)

    Jenks, G.H.

    1979-07-01

    Available experimental and theoretical information on brine migration in bedded salt are reviewed and analyzed. The effects of temperature, thermal gradients, stress, irradiation, and pressure in a salt repository are among the factors considered. The theoretical and experimental (with KCl) results of Anthony and Cline were used to correlate and explain the available data for rates of brine migration at temperatures up to 250 0 C in naturally occurring crystals of bedded salt from Lyons and Hutchinson, Kansas. Considerations of the effects of stressing crystals of bedded salt on the migratin properties of brine inclusions within the crystals led to the conclusion that the most probable effects are a small fractional increase in the solubility of the salt within the liquid and a concomitant and equal fractional increase in the rate of the thermal gradient-induced migration of the brine. The greatest uncertainty relative to the prediction of rates of migration of brine into a waste emplacement cavity in bedded salt is associated with questions concerning the effects of the grain boundaries (within the aggregates of single crystals which comprise a bedded salt deposit) on brine migration through the deposit. The results of some of the estimates of rates and total amounts of brine inflow to HLW and SURF waste packages emplaced in bedded salt were included to illustrate the inflow volumes which might occur in a repository. The results of the brine inflow estimates for 10-year-old HLW emplaced at 150 kW/acre indicated inflow rates starting at 0.7 liter/year and totaling 12 liters at 30 years after emplacement. The results of the estimates for 10-year-old PWR SURF emplaced at 60 kW/acre indicated a constant inflow of 0.035 liter/year for the first 35 years after emplacement

  2. Effects of brine contamination from energy development on wetland macroinvertebrate community structure in the Prairie Pothole Region

    Science.gov (United States)

    Preston, Todd M.; Borgreen, Michael J.; Ray, Andrew M.

    2018-01-01

    Wetlands in the Prairie Pothole Region (PPR) of North America support macroinvertebrate communities that are integral to local food webs and important to breeding waterfowl. Macroinvertebrates in PPR wetlands are primarily generalists and well adapted to within and among year changes in water permanence and salinity. The Williston Basin, a major source of U.S. energy production, underlies the southwest portion of the PPR. Development of oil and gas results in the coproduction of large volumes of highly saline, sodium chloride dominated water (brine) and the introduction of brine can alter wetland salinity. To assess potential effects of brine contamination on macroinvertebrate communities, 155 PPR wetlands spanning a range of hydroperiods and salinities were sampled between 2014 and 2016. Brine contamination was documented in 34 wetlands with contaminated wetlands having significantly higher chloride concentrations, specific conductance and percent dominant taxa, and significantly lower taxonomic richness, Shannon diversity, and Pielou evenness scores compared to uncontaminated wetlands. Non-metric multidimensional scaling found significant correlations between several water quality parameters and macroinvertebrate communities. Chloride concentration and specific conductance, which can be elevated in naturally saline wetlands, but are also associated with brine contamination, had the strongest correlations. Five wetland groups were identified from cluster analysis with many of the highly contaminated wetlands located in a single cluster. Low or moderately contaminated wetlands were distributed among the remaining clusters and had macroinvertebrate communities similar to uncontaminated wetlands. While aggregate changes in macroinvertebrate community structure were observed with brine contamination, systematic changes were not evident, likely due to the strong and potentially confounding influence of hydroperiod and natural salinity. Therefore, despite the observed

  3. Determination of nickel in chloralkali electrolysis brines by X-ray fluorescence spectrometry on a membrane filter

    International Nuclear Information System (INIS)

    Andrade, L.L.; Minzl, E.

    1984-01-01

    X-ray fluorescence spectrometry after ammonium pyrrolidinedithiocarbamate (APDC) preconcentration is proposed for the determination of nickel in chloralkali electrolysis brines. The optimum conditions for the precipitation target tube, peak intensity, background, analysing crystal, counters and exposure time were investigated. The method was applied to chloralkali brines of evaporite salts (halite, sylvinite, carnallite and tachhydrite), sodium, potassium and magnesium salts, explored in Sergipe (Brazil), by Petrobras-Mineracao S.A.(Author) [pt

  4. Chemistry of brines in salt from the Waste Isolation Pilot Plant (WIPP), southeastern New Mexico: a preliminary investigation

    International Nuclear Information System (INIS)

    Stein, C.L.; Krumhansl, J.L.

    1986-03-01

    We present here analyses of macro- and microscopic (intracrystalline) brines observed within the WIPP facility and in the surrounding halite, with interpretations regarding the origin and history of these fluids and their potential effect(s) on long-term waste storage. During excavation, several large fluid inclusions were recovered from an area of highly recrystallized halite in a thick salt bed at the repository horizon (2150 ft below ground level). In addition, 52 samples of brine ''weeps'' were collected from walls of recently excavated drifts at the same stratigraphic horizon from which the fluid inclusion samples are assumed to have been taken. Analyses of these fluids show that they differ substantially in composition from the inclusion fluids and cannot be explained by mixing of the fluid inclusion populations. Finally, holes in the facility floor that filled with brine were sampled but with no stratographic control; therefore it is not possible to interpret the compositions of these brines with any accuracy, except insofar as they resemble the weep compositions but with greater variation in both K/Mg and Na/Cl ratios. However, the Ca and SO 4 values for the floor holes are relatively close to the gypsum saturation curve, suggesting that brines filling floor holes have been modified by the presence of gypsum or anhydrite, possibly even originating in one or more of the laterally continuous anhydrite units referred to in the WIPP literature as marker beds. In conclusion, the wide compositional variety of fluids found in the WIPP workings suggest that (1) an interconnected hydrologic system which could effectively transport radonuclides away from the repository does not exist; (2) brine migration studies and experiments must consider the mobility of intergranular fluids as well as those in inclusions; and (3) near- and far-field radionuclide migration testing programs need to consider a wide range of brine compositions rather than a few reference brines

  5. West Hackberry Brine Disposal Project pre-discharge characterization. Final report

    Energy Technology Data Exchange (ETDEWEB)

    DeRouen, L.R.; Hann, R.W.; Casserly, D.M.; Giammona, C. (eds.)

    1982-01-01

    The physical, chemical and biological attributes are described for: (1) a coastal marine environment centered about a Department of Energy Strategic Petroleum Reserve (SPR) brine disposal site 11.4 km off the southwest coast of Louisiana; and (2) the lower Calcasieu and Sabine estuarine systems that provide leach waters for the SPR project. A three month sampling effort, February through April 1981, and previous investigations from the study area are integrated to establish baseline information for evaluation of impacts from brine disposal in the nearshore marine waters and from freshwater withdrawal from the coastal marsh of the Chenier Plain. January data are included for some tasks that sampled while testing and mobilizing their instruments prior to the February field effort. The study addresses the areas of physical oceanography, estuarine hydrology and hydrography, water and sediment quality, benthos, nekton, phytoplankton, zooplankton, and data management.

  6. Microbial succession and the functional potential during the fermentation of Chinese soy sauce brine.

    Science.gov (United States)

    Sulaiman, Joanita; Gan, Han Ming; Yin, Wai-Fong; Chan, Kok-Gan

    2014-01-01

    The quality of traditional Chinese soy sauce is determined by microbial communities and their inter-related metabolic roles in the fermentation tank. In this study, traditional Chinese soy sauce brine samples were obtained periodically to monitor the transitions of the microbial population and functional properties during the 6 months of fermentation process. Whole genome shotgun method revealed that the fermentation brine was dominated by the bacterial genus Weissella and later dominated by the fungal genus Candida. Metabolic reconstruction of the metagenome sequences demonstrated a characteristic profile of heterotrophic fermentation of proteins and carbohydrates. This was supported by the detection of ethanol with stable decrease of pH values. To the best of our knowledge, this is the first study that explores the temporal changes in microbial successions over a period of 6 months, through metagenome shotgun sequencing in traditional Chinese soy sauce fermentation and the biological processes therein.

  7. Microbial succession and the functional potential during the fermentation of Chinese soy sauce brine

    Directory of Open Access Journals (Sweden)

    Joanita eSulaiman

    2014-10-01

    Full Text Available The quality of traditional Chinese soy sauce is determined by microbial communities and their inter-related metabolic roles in the fermentation tank. In this study, traditional Chinese soy sauce brine samples were obtained periodically to monitor the transitions of the microbial population and functional properties during the six months of fermentation process. Whole genome shotgun (WGS method revealed that the fermentation brine was dominated by the bacterial genus Weissella and later dominated by the fungal genus Candida. Metabolic reconstruction of the metagenome sequences demonstrated a characteristic profile of heterotrophic fermentation of proteins and carbohydrates. This was supported by the detection of ethanol with stable decrease of pH values. To the best of our knowledge, this is the first study that explores the temporal changes in microbial successions over a period of six months, through metagenome shotgun sequencing in traditional Chinese soy sauce fermentation and the biological processes therein.

  8. Recovery Act: Molecular Simulation of Dissolved Inorganic Carbons for Underground Brine CO2 Sequestration

    Energy Technology Data Exchange (ETDEWEB)

    Goddard, William

    2012-11-30

    To further our understanding and develop the method for measuring the DICs under geological sequestration conditions, we studied the infrared spectra of DICs under high pressure and temperature conditions. First principles simulations of DICs in brine conditions were performed using a highly optimized ReaxFF-DIC forcefield. The thermodynamics stability of each species were determined using the 2PT method, and shown to be consistent with the Reax simulations. More importantly, we have presented the IR spectra of DIC in real brine conditions as a function of temperature and pressure. At near earth conditions, we find a breaking of the O-C-O bending modes into asymmetric and symmetric modes, separated by 100cm{sup -1} at 400K and 5 GPa. These results can now be used to calibrate FTIR laser measurements.

  9. In-Situ X-ray Tomography Study of Cement Exposed to CO2 Saturated Brine

    DEFF Research Database (Denmark)

    Chavez Panduro, E. A.; Torsæter, M.; Gawel, K.

    2017-01-01

    For successful CO2 storage in underground reservoirs, the potential problem of CO2 leakage needs to be addressed. A profoundly improved understanding of the behavior of fractured cement under realistic subsurface conditions including elevated temperature, high pressure and the presence of CO2...... saturated brine is required. Here, we report in situ X-ray micro computed tomography (μ-CT) studies visualizing the microstructural changes upon exposure of cured Portland cement with an artificially engineered leakage path (cavity) to CO2 saturated brine at high pressure. Carbonation of the bulk cement......, self-healing of the leakage path in the cement specimen, and leaching of CaCO3 were thus directly observed. The precipitation of CaCO3, which is of key importance as a possible healing mechanism of fractured cement, was found to be enhanced in confined regions having limited access to CO2...

  10. The Synthesis of Calcium Salt from Brine Water by Partial Evaporation and Chemical Precipitation

    Science.gov (United States)

    Lalasari, L. H.; Widowati, M. K.; Natasha, N. C.; Sulistiyono, E.; Prasetyo, A. B.

    2017-02-01

    In this study would be investigated the effects of partial evaporation and chemical precipitation in the formation of calcium salt from brine water resources. The chemical reagents used in the study was oxalate acid (C2H2O4), ammonium carbonate (NH4)2CO3) and ammonium hydroxide (NH4OH) with reagent concentration of 2 N, respectively. The procedure was 10 liters brine water evaporated until 20% volume and continued with filtration process to separate brine water filtrate from residue (salt). Salt resulted from evaporation process was characterized by Scanning Electron Microscopy (SEM), X-Ray Fluorescence (XRF) and X-Ray Diffraction (XRD) techniques. Filtrate then was reacted with C2H2O4, (NH4)2CO3 and NH4OH reagents to get salt products in atmospheric condition and variation ratio volume brine water/chemicals (v/v) [10/1; 10/5; 10/10; 10/20; 10/30; 10:50; 20/1; 20/5; 20/10; 20/20; 20/30; 20:50]. The salt product than were filtered, dried, measured weights and finally characterized by SEM/EDS and XRD techniques. The result of experiment showed the chemical composition of brine water from Tirta Sanita, Bogor was 28.87% Na, 9.17% Mg, 2.94% Ca, 22.33% O, 0.71% Sr, 30.02% Cl, 1.51% Si, 1.23% K, 0.55% S, 1.31% Al. The chemical composition of salt resulted by partial evaporation was 53.02% Ca, 28.93%O, 9.50% Na, 2.10% Mg, 1.53% Sr, 1.20% Cl, 1.10% Si, 0.63% K, 0.40% S, 0.39% Al. The salt resulted by total evaporation was indicated namely as NaCl. Whereas salt resulted by partial evaporation was CaCO3 with a purity of 90 % from High Score Plus analysis. In the experiment by chemical precipitation was reported that the reagents of ammonium carbonate were more reactive for synthesizing calcium salt from brine water compared to reagents of oxalate acid and ammonium hydroxide. The salts precipitated by NH4OH, (NH4)2CO3, and H2C2O4 reagents were indicated as NaCl, CaCO3 and CaC2O4.H2O, respectively. The techniques of partial evaporation until 20% volume sample of brine water and

  11. The application of bioflocs technology to protect brine shrimp (Artemia franciscana) from pathogenic Vibrio harveyi.

    Science.gov (United States)

    Crab, R; Lambert, A; Defoirdt, T; Bossier, P; Verstraete, W

    2010-11-01

    To study the potential biocontrol activity of bioflocs technology. Glycerol-grown bioflocs were investigated for their antimicrobial and antipathogenic properties against the opportunistic pathogen Vibrio harveyi. The bioflocs did not produce growth-inhibitory substances. However, bioflocs and biofloc supernatants decreased quorum sensing-regulated bioluminescence of V. harveyi. This suggested that the bioflocs had biocontrol activity against this pathogen because quorum sensing regulates virulence of vibrios towards different hosts. Interestingly, the addition of live bioflocs significantly increased the survival of gnotobiotic brine shrimp (Artemia franciscana) larvae challenged to V. harveyi. Bioflocs grown on glycerol as carbon source inhibit quorum sensing-regulated bioluminescence in V. harveyi and protect brine shrimp larvae from vibriosis. The results presented in this study indicate that in addition to water quality control and in situ feed production, bioflocs technology could help in controlling bacterial infections within the aquaculture pond. © 2010 The Authors. Journal of Applied Microbiology © 2010 The Society for Applied Microbiology.

  12. Microbiology of the Red Sea (and other) deep-sea anoxic brine lakes

    KAUST Repository

    Antunes, Andre

    2011-05-30

    Summary: The Red Sea harbours approximately 25 deep-sea anoxic brine pools. They constitute extremely unique and complex habitats with the conjugation of several extreme physicochemical parameters rendering them some of the most inhospitable environments on Earth. After 50 years of research mostly driven by chemists, geophysicists and geologists, the microbiology of the brines has been receiving increased interest in the last decade. Recent molecular and cultivation-based studies have provided us with a first glimpse on the enormous biodiversity of the local microbial communities, the identification of several new taxonomic groups, and the isolation of novel extremophiles that thrive in these environments. This review presents a general overview of these unusual biotopes and compares them with other similar environments in the Mediterranean Sea and the Gulf of Mexico, with a focus on their microbial ecology. © 2011 Society for Applied Microbiology and Blackwell Publishing Ltd.

  13. Effect of cold work on CO sub 2 corrosion behavior of 13% Cr (420 type) stainless steel in brine medium with and without addition of sodium sulphide

    International Nuclear Information System (INIS)

    Akram Ali Agil; Azmi Rahmat; Suraj Bhan

    1996-01-01

    Cold work introduces residual stresses and increases internal stored energy. Plastic deformation also causes slip steps on the surface. All these factors effect corrosion rate as corrosion is controlled by surface reaction. The residual stresses are caused by inhomogeneous deformation in cold rolling and are maximum at low deformation and then decrease as the samples get thinner on further rolling. In the absence of CO sub 2 the corrosion rates are found relatively low in brine solution with or without addition of Na sub 2 S, with only slight variation with % total deformation. However simultaneous presence of CO sub 2 and Na sub 2 S has synergic effect increasing the corrosion rate appreciably. Presence of sulphur is also found to increase the pitting tendency in the steel

  14. Liquid interfacial water and brines in the upper surface of Mars

    Science.gov (United States)

    Moehlmann, Diedrich

    2013-04-01

    Liquid interfacial water and brines in the upper surface of Mars Diedrich T.F. Möhlmann DLR Institut für Planetenforschung, Rutherfordstr. 2, D - 12489 Berlin, Germany dirk.moehlmann@dlr.de Interfacial water films and numerous brines are known to remain liquid at temperatures far below 0° C. The physical processes behind are described in some detail. Deliquescence, i.e. the liquefaction of hygroscopic salts at the threshold of a specific "Deliquescence Relative Humidity", is shown to be that process, which on present Mars supports the formation of stable interfacial water and bulk liquids in form of temporary brines on and in a salty upper surface of present Mars in a diurnally temporary and repetitive process. Temperature and relative humidity are the governing conditions for deliquescence (and the counterpart "efflorescence") to evolve. The current thermo-dynamical conditions on Mars support these processes to evolve on present Mars. The deliquescence-driven presence of liquid brines in the soil of the upper surface of Mars can expected to be followed by physical and chemical processes like "surface cementation", down-slope flows, and physical and chemical weathering processes. A remarkable and possibly also biologically relevant evolution towards internally interfacial water bearing structures of dendritic capillaries is related to their freezing - thawing driven formation. The internal walls of these network-pores or -tubes can be covered by films of interfacial water, providing that way possibly habitable crack-systems in soil and rock. These evolutionary processes of networks, driven by their tip-growth, can expected to be ongoing also at present.

  15. Biochemical solubilization of toxic salts from residual geothermal brines and waste waters

    Science.gov (United States)

    Premuzic, Eugene T.; Lin, Mow S.

    1994-11-22

    A method of solubilizing metal salts such as metal sulfides in a geothermal sludge using mutant Thiobacilli selected for their ability to metabolize metal salts at high temperature is disclosed, The method includes the introduction of mutated Thiobacillus ferrooxidans and Thiobacillus thiooxidans to a geothermal sludge or brine. The microorganisms catalyze the solubilization of metal salts, For instance, in the case of metal sulfides, the microorganisms catalyze the solubilization to form soluble metal sulfates.

  16. Coupled modelling of convergence, steel corrosion, gas production and brine flow in a rock salt repository

    International Nuclear Information System (INIS)

    Becker, D.A.; Hirsekorn, R.P.

    2013-01-01

    This poster presents the global simulation of the behaviour of thick-walled steel containers piled up in a borehole in a rock salt repository. The simulation takes into account: the convergence by the creeping of rock salt, the backfill and waste compaction, the porosity dependent flow resistance, the anaerobic corrosion (iron to magnetite transformation, gas production, brine consumption, water consumption and salt precipitation) and pressure development. Mechanical influence of corrosion has not yet been taken into account in the integrated code LOPOS

  17. Measured and calculated closures of open and brine filled shafts and deep vertical boreholes in salt

    International Nuclear Information System (INIS)

    Munson, D.E.; DeVries, K.L.; Schiermeister, D.M.; DeYonge, W.F.; Jones, R.L.

    1991-01-01

    Shaft closure measurements are presented which are based on a rather unusual emplacement of very early time closure points. These data are in good agreement with calculations based on the prediction technique developed for underground rooms in salt using a complete stratigraphy. However, a simplified calculational mesh also gives good agreement, which permits this mesh to be used for parametric studies of long term closures of open and brine filled shafts and boreholes

  18. Measured and calculated closures of open and brine filled shafts and deep vertical boreholes in salt

    International Nuclear Information System (INIS)

    Munson, D.E.; DeVries, K.L.; Schiermeister, D.M.; DeYonge, W.F.; Jones, R.L.

    1992-01-01

    Shaft closure measurements are presented which are based on a rather unusual emplacement of very early time closure points. These data are in good agreement with calculations based on the prediction techniques developed for underground rooms in salt using a complete stratigraphy. However, a simplified calculational mesh also gives good agreement, which permits this mesh to be used for parametric studies of long term closures of open and brine filled shafts and boreholes

  19. A method for the specific detection of resident bacteria in brine shrimp larvae.

    Science.gov (United States)

    Niu, Yufeng; Defoirdt, Tom; Rekecki, Anamaria; De Schryver, Peter; Van den Broeck, Wim; Dong, Shuanglin; Sorgeloos, Patrick; Boon, Nico; Bossier, Peter

    2012-04-01

    In this study, we describe an easy but efficient method to specifically target the intestinal resident microbiota in brine shrimp larvae during DGGE analysis, hereby excluding the interference of both transient (luminal) bacteria and body surface bacteria. This effective technique has several advantages over alternative methods, with respect of ease of use and rapidity. Copyright © 2012 Elsevier B.V. All rights reserved.

  20. Investigation of an innovative technology for oil-field brine treatment

    Energy Technology Data Exchange (ETDEWEB)

    Miskovic, D; Dalmacija, B; Hain, Z; Karlovic, E; Maric, S; Uzelac, N [Inst. of Chemistry, Faculty of Sciences, V. Vlahovica 2 (YU)

    1989-01-01

    Various aspects of an innovative technology for oil field brine treatment were investigated on a laboratory scale. The both free and dispersed oily matter were separated by gravitation and sedimentation. Apart from the physico-chemical oil removal process, special attention was paid to different variants of improved microbiological treatment: dilution with fresh water and application of powdered activated carbon (PAC). Advanced treatment was carried out on granular biological activated carbon (GBAC). A technological scheme for complete treatment was proposed. (author).