The use of stir bar sorptive extraction-A potential alternative method for the determination of furan, evaluated using two example food matrices

Energy Technology Data Exchange (ETDEWEB)

Ridgway, Kathy, E-mail: Kathy.Ridgway@Unilever.com [Safety and Environmental Assurance Centre, Unilever Colworth, Bedfordshire, MK44 1LQ (United Kingdom); Lalljie, Sam P.D. [Safety and Environmental Assurance Centre, Unilever Colworth, Bedfordshire, MK44 1LQ (United Kingdom); Smith, Roger M. [Department of Chemistry, Loughborough University, Loughborough, Leics, LE11 3TU (United Kingdom)

2010-01-11

A comparison is made between static headspace analysis and stir bar sorptive extraction (SBSE) for the quantitative determination of furan. The SBSE technique was optimised and evaluated using two example food matrices (coffee and jarred baby food). The use of the SBSE technique in most cases, gave comparable results to the static headspace method, using the method of standard additions with d{sub 4}-labelled furan as an internal standard. Using the SBSE method, limits of detection down to 2 ng g{sup -1} were achieved, with only a 1 h extraction. The method was performed at ambient temperatures, thus eliminating the possibility of formation of furan during extraction.

The use of stir bar sorptive extraction-A potential alternative method for the determination of furan, evaluated using two example food matrices

International Nuclear Information System (INIS)

Ridgway, Kathy; Lalljie, Sam P.D.; Smith, Roger M.

2010-01-01

A comparison is made between static headspace analysis and stir bar sorptive extraction (SBSE) for the quantitative determination of furan. The SBSE technique was optimised and evaluated using two example food matrices (coffee and jarred baby food). The use of the SBSE technique in most cases, gave comparable results to the static headspace method, using the method of standard additions with d 4 -labelled furan as an internal standard. Using the SBSE method, limits of detection down to 2 ng g -1 were achieved, with only a 1 h extraction. The method was performed at ambient temperatures, thus eliminating the possibility of formation of furan during extraction.

Analysis of Volatile Components of Varietal English Wines Using Stir Bar Sorptive Extraction/Gas Chromatography-Mass Spectrometry

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Darren J. Caven-Quantrill

2017-12-01

Full Text Available Aroma is an important property of wine and it can be influenced significantly by enological practices. The aim of this work was, by use of stir bar sorptive extraction/gas chromatography-mass spectrometry (SBSE/GC-MS, to compare semi-quantitative concentrations of the volatile constituents of stainless steel tank-fermented/matured Huxelrebe, Ortega, Schönburger and Siegerrebe varietal wines from a commercial English vineyard, with corresponding wines produced by oak cask (‘barrel’ fermentation/maturation. Aroma profiles of tank and barrel wines were different, with more volatiles detected and net concentrations being higher in barrel wines. Long chain ethyl carboxylate esters were generally more abundant in barrel wines, whereas acetate esters were generally more prominent in tank wines. By conducting a short (~7 month maturation period in secondhand (third or fourth fill casks, it was possible to make wines with more complex aromas, but without obvious oak aroma.

Graphene oxide-coated stir bar sorptive extraction of trace aflatoxins from soy milk followed by high performance liquid chromatography-laser-induced fluorescence detection.

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Ma, Haiyan; Ran, Congcong; Li, Mengjiao; Gao, Jinglin; Wang, Xinyu; Zhang, Lina; Bian, Jing; Li, Junmei; Jiang, Ye

2018-04-01

Mycotoxins are potential food pollutants produced by fungi. Among them, aflatoxins (AFs) are the most toxic. Therefore, AFs were selected as models, and a sensitive, simple and green graphene oxide (GO)-based stir bar sorptive extraction (SBSE) method was developed for extraction and determination of AFs with high performance liquid chromatography-laser-induced fluorescence detector (HPLC-LIF). This method improved the sensitivity of AFs detection and solved the deposition difficulty of the direct use of GO as adsorbent. Several parameters including a spiked amount of NaCl, stirring rate, extraction time and desorption time were investigated. Under optimal conditions, the quantitative method had low limits of detection of 2.4-8.0 pg/mL, which were better than some reported AFs analytical methods. The developed method has been applied to soy milk samples with good recoveries ranging from 80.5 to 102.3%. The prepared GO-based SBSE can be used as a sensitive screening technique for detecting AFs in soy milk.

Molecularly imprinted polymers based stir bar sorptive extraction for determination of cefaclor and cefalexin in environmental water.

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Peng, Jun; Liu, Donghao; Shi, Tian; Tian, Huairu; Hui, Xuanhong; He, Hua

2017-07-01

Although stir bar sportive extraction was thought to be a highly efficiency and simple pretreatment approach, its wide application was limited by low selectivity, short service life, and relatively high cost. In order to improve the performance of the stir bar, molecular imprinted polymers and magnetic carbon nanotubes were combined in the present study. In addition, two monomers were utilized to intensify the selectivity of molecularly imprinted polymers. Fourier transform infrared spectroscopy, scanning electron microscopy, and selectivity experiments showed that the molecularly imprinted polymeric stir bar was successfully prepared. Then micro-extraction based on the obtained stir bar was coupled with HPLC for determination of trace cefaclor and cefalexin in environmental water. This approach had the advantages of stir bar sportive extraction, high selectivity of molecular imprinted polymers, and high sorption efficiency of carbon nanotubes. To utilize this pretreatment approach, pH, extraction time, stirring speed, elution solvent, and elution time were optimized. The LOD and LOQ of cefaclor were found to be 3.5 ng · mL -1 and 12.0 ng · mL -1 , respectively; the LOD and LOQ of cefalexin were found to be 3.0 ng · mL -1 and 10.0 ng · mL -1 , respectively. The recoveries of cefaclor and cefalexin were 86.5 ~ 98.6%. The within-run precision and between-run precision were acceptable (relative standard deviation bar did not decrease dramatically. This demonstrated that the molecularly imprinted polymeric stir bar based micro-extraction was a convenient, efficient, low-cost, and a specific method for enrichment of cefaclor and cefalexin in environmental samples.

Determination of synthetic phenolic antioxidants in soft drinks by stir-bar sorptive extraction coupled to gas chromatography-mass spectrometry.

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Cacho, Juan Ignacio; Campillo, Natalia; Viñas, Pilar; Hernández-Córdoba, Manuel

2015-01-01

The synthetic phenolic antioxidants butylated hydroxyanisole (BHA), butylated hydroxytoluene (BHT) and tert-butyl hydroquinone (TBHQ) were pre-concentrated by stir-bar sorptive extraction and thermally desorbed (SBSE-TD) before analysis by GC-MS. Several parameters affecting the derivatisation step and both SBSE extraction and thermal desorption were carefully optimised. When the analyses of BHA and TBHQ in their acetylated, silylated and underivatised forms were compared, the best results were obtained when the in-situ derivatisation procedure with acetic anhydride was employed. Quantification was carried out using carvacrol as the internal standard, providing quantification limits of between 0.11 and 0.15 ng ml(-1), depending on the compound. Recovery assays for samples spiked at two concentration levels, 1 and 5 ng ml(-1), provided recoveries in the 81-117% range. The proposed method was applied in the analysis canned soft drinks and the analytes were found in five of the 10 samples analysed.

Barbell-shaped stir bar sorptive extraction using dummy template molecularly imprinted polymer coatings for analysis of bisphenol A in water.

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Liu, Ruimei; Feng, Feng; Chen, Guolin; Liu, Zhimin; Xu, Zhigang

2016-07-01

This study reports the development of a novel dummy template molecularly imprinted polymer (MIP)-coated barbell-shaped stir bar. The MIP stir bar coatings were prepared by using 2,2-bis(4-hydroxyphenyl)butane (BPB), 4,4'-dihydroxydiphenylmethane (BPF), 4-tert-butylphenol (PTBP), and tetrabromobisphenol A (TBBA) as dummy templates using a capillary in situ polymerization method. Uniform coatings can be prepared controllably. The method is simple, easy, and reproducible. The barbell-shaped stir bar was developed by using medical silicone tubes as wheels. The wheels could be removed and reinstalled when necessary; therefore, the barbell-shaped stir bar was easy to disassemble and reassemble. The novel MIP-coated stir bar showed good selectivity for the target analyte, bisphenol A (BPA). The established method is selective and sensitive with a lower detection limit for BPA of 0.003 μg/L. The dummy template MIP-coated stir bar is suitable for trace BPA analysis in real environmental water samples without template leakage. The novel stir bar can be used at least 100 times.

Sorptive extraction using polydimethylsiloxane/metal-organic framework coated stir bars coupled with high performance liquid chromatography-fluorescence detection for the determination of polycyclic aromatic hydrocarbons in environmental water samples.

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Hu, Cong; He, Man; Chen, Beibei; Zhong, Cheng; Hu, Bin

2014-08-22

In this work, metal-organic frameworks (MOFs, Al-MIL-53-NH₂) were synthesized via the hydrothermal method, and novel polydimethylsiloxane/metal-organic framework (PDMS/MOFs, PDMS/Al-MIL-53-NH₂)-coated stir bars were prepared by the sol-gel technique. The preparation reproducibility of the PDMS/MOFs-coated stir bar was good, with relative standard deviations (RSDs) ranging from 4.8% to 14.9% (n=7) within one batch and from 6.2% to 16.9% (n=6) among different batches. Based on this fact, a new method of PDMS/MOFs-coated stir bar sorptive extraction (SBSE) and ultrasonic-assisted liquid desorption (UALD) coupled with high performance liquid chromatography-fluorescence detection (HPLC-FLD) was developed for the determination of polycyclic aromatic hydrocarbons (PAHs) in environmental water samples. To obtain the best extraction performance for PAHs, several parameters affecting SBSE, such as extraction time, stirring rate, and extraction temperature, were investigated. Under optimal experimental conditions, wide linear ranges and good RSDs (n=7) were obtained. With enrichment factors (EFs) of 16.1- to 88.9-fold (theoretical EF, 142-fold), the limits of detection (LODs, S/N=3) of the developed method for the target PAHs were found to be in the range of 0.05-2.94 ng/L. The developed method was successfully applied to the analysis of PAHs in Yangtze River and East Lake water samples. Copyright © 2014 Elsevier B.V. All rights reserved.

Stir bar sorptive extraction and liquid chromatography-tandem mass spectrometry determination of polar and non-polar emerging and priority pollutants in environmental waters.

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Aparicio, Irene; Martín, Julia; Santos, Juan Luis; Malvar, José Luis; Alonso, Esteban

2017-06-02

An analytical method based on stir bar sorptive extraction (SBSE) was developed and validated for the determination of environmental concern pollutants in environmental waters by liquid chromatography-tandem mass spectrometry (LC-MS/MS). Target compounds include six water and oil repellents (perfluorinated compounds), four preservatives (butylated hydroxytoluene and three parabens), two plasticizers (bisphenol A and di(2-ethylhexyl)phthalate), seven surfactants (four linear alkylbenzene sulfonates, nonylphenol and two nonylphenol ethoxylates), a flame retardant (hexabromocyclododecane), four hormones, fourteen pharmaceutical compounds, an UV-filter (2-ethylhexyl 4-methoxycinnamate) and nine pesticides. To achieve the simultaneous extraction of polar and non-polar pollutants two stir bar coatings were tested, the classic polydimethylsiloxane (PDMS) coating and the novel ethylene glycol modified silicone (EG-silicone). The best extraction recoveries were obtained using EG-silicone coating. The effects of sample pH, volume and ionic strength and extraction time on extraction recoveries were evaluated. The analytical method was validated for surface water and tap water samples. The method quantification limits ranged from 7.0ngL -1 to 177ngL -1 . The inter-day precision, expressed as relative standard deviation, was lower than 20%. Accuracy, expressed as relative recovery values, was in the range from 61 to 130%. The method was applied for the determination of the 48 target compounds in surface and tap water samples. Copyright © 2017 Elsevier B.V. All rights reserved.

Simple and sensitive monitoring of sulfonamide veterinary residues in milk by stir bar sorptive extraction based on monolithic material and high performance liquid chromatography analysis.

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Huang, Xiaojia; Qiu, Ningning; Yuan, Dongxing

2009-11-13

A simple, rapid, and sensitive method for the quantitative monitoring of five sulfonamide antibacterial residues (SAs) in milk was developed by stir bar sorptive extraction (SBSE) coupling to high performance liquid chromatography with diode array detection. The analytes were concentrated by SBSE based on poly (vinylimidazole-divinylbenzene) monolithic material as coating. The extraction procedure was very simple, milk was diluted with water then directly sorptive extraction without elimination of fats and protein in samples was required. To achieve optimum extraction performance for SAs, several parameters, including extraction and desorption time, desorption solvent, ionic strength and pH value of sample matrix were investigated. Under the optimized experimental conditions, low detection limits (S/N=3) quantification limits (S/N=10) of the proposed method for the target compounds were achieved within the range of 1.30-7.90 ng/mL and 4.29-26.3 ng/mL from spiked milk, respectively. Good linearities were obtained for SAs with the correlation coefficients (R(2)) above 0.996. Finally, the proposed method was successfully applied to the determination of SAs compounds in different milk samples and satisfied recoveries of spiked target compounds in real samples were obtained.

Introducing a new and rapid microextraction approach based on magnetic ionic liquids: Stir bar dispersive liquid microextraction.

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Chisvert, Alberto; Benedé, Juan L; Anderson, Jared L; Pierson, Stephen A; Salvador, Amparo

2017-08-29

With the aim of contributing to the development and improvement of microextraction techniques, a novel approach combining the principles and advantages of stir bar sorptive extraction (SBSE) and dispersive liquid-liquid microextraction (DLLME) is presented. This new approach, termed stir bar dispersive liquid microextraction (SBDLME), involves the addition of a magnetic ionic liquid (MIL) and a neodymium-core magnetic stir bar into the sample allowing the MIL coat the stir bar due to physical forces (i.e., magnetism). As long as the stirring rate is maintained at low speed, the MIL resists rotational (centrifugal) forces and remains on the stir bar surface in a manner closely resembling SBSE. By increasing the stirring rate, the rotational forces surpass the magnetic field and the MIL disperses into the sample solution in a similar manner to DLLME. After extraction, the stirring is stopped and the MIL returns to the stir bar without the requirement of an additional external magnetic field. The MIL-coated stir bar containing the preconcentrated analytes is thermally desorbed directly into a gas chromatographic system coupled to a mass spectrometric detector (TD-GC-MS). This novel approach opens new insights into the microextraction field, by using the benefits provided by SBSE and DLLME simultaneously, such as automated thermal desorption and high surface contact area, respectively, but most importantly, it enables the use of tailor-made solvents (i.e., MILs). To prove its utility, SBDLME has been used in the extraction of lipophilic organic UV filters from environmental water samples as model analytical application with excellent analytical features in terms of linearity, enrichment factors (67-791), limits of detection (low ng L -1 ), intra- and inter-day repeatability (RSD<15%) and relative recoveries (87-113%, 91-117% and 89-115% for river, sea and swimming pool water samples, respectively). Copyright © 2017 Elsevier B.V. All rights reserved.

Development, optimisation and application of polyurethane foams as new polymeric phases for stir bar sorptive extraction.

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Neng, N R; Pinto, M L; Pires, J; Marcos, P M; Nogueira, J M F

2007-11-09

In this contribution, polyurethane foams are proposed as new polymeric phases for stir bar sorptive extraction (SBSE). Assays performed for polyurethane synthesis demonstrated that four series of formulations (P(1), P(2), P(3) and P(4)) present remarkable stability and excellent mechanical resistance to organic solvents. For polymer clean-up treatment, acetonitrile proved to be the best solvent under sonification, ensuring the reduction of the contamination and interferences. SBSE assays performed on these polyurethane polymers followed by liquid desorption and high-performance liquid chromatography-diode array detection (LD-HPLC-DAD) or large volume injection-capillary gas chromatography-mass spectrometry (LD-LVI-GC-MS), showed that P(2) presents the best recovery yields for atrazine, 2,3,4,5-tetrachlorophenol and fluorene, used as model compounds in water samples at a trace level. SBSE(P(2)) assays performed on this polymer mixed up with several adsorbent materials, i.e. activated carbon, a mesoporous material and a calixarene, did not bring any advantages in relation with the polymeric matrix alone. The comparison between assays performed by SBSE(P(2)) and by the conventional SBSE(PDMS) showed much better performance for the former phase on aqueous samples spiked with atrazine, 2,3,4,5-tetrachlorophenol and fluorene, in which the foremost two analytes present recovery values 3- and 10-fold higher, respectively. The polyurethanes proposed as new polymeric phases for SBSE provided powerful capabilities for the enrichment of organic compounds from aqueous matrices, showing to be indicated mainly in the case of the more polar analytes.

Introducing a new and rapid microextraction approach based on magnetic ionic liquids: Stir bar dispersive liquid microextraction

International Nuclear Information System (INIS)

Chisvert, Alberto; Benedé, Juan L.; Anderson, Jared L.; Pierson, Stephen A.; Salvador, Amparo

2017-01-01

With the aim of contributing to the development and improvement of microextraction techniques, a novel approach combining the principles and advantages of stir bar sorptive extraction (SBSE) and dispersive liquid-liquid microextraction (DLLME) is presented. This new approach, termed stir bar dispersive liquid microextraction (SBDLME), involves the addition of a magnetic ionic liquid (MIL) and a neodymium-core magnetic stir bar into the sample allowing the MIL coat the stir bar due to physical forces (i.e., magnetism). As long as the stirring rate is maintained at low speed, the MIL resists rotational (centrifugal) forces and remains on the stir bar surface in a manner closely resembling SBSE. By increasing the stirring rate, the rotational forces surpass the magnetic field and the MIL disperses into the sample solution in a similar manner to DLLME. After extraction, the stirring is stopped and the MIL returns to the stir bar without the requirement of an additional external magnetic field. The MIL-coated stir bar containing the preconcentrated analytes is thermally desorbed directly into a gas chromatographic system coupled to a mass spectrometric detector (TD-GC-MS). This novel approach opens new insights into the microextraction field, by using the benefits provided by SBSE and DLLME simultaneously, such as automated thermal desorption and high surface contact area, respectively, but most importantly, it enables the use of tailor-made solvents (i.e., MILs). To prove its utility, SBDLME has been used in the extraction of lipophilic organic UV filters from environmental water samples as model analytical application with excellent analytical features in terms of linearity, enrichment factors (67–791), limits of detection (low ng L −1 ), intra- and inter-day repeatability (RSD<15%) and relative recoveries (87–113%, 91–117% and 89–115% for river, sea and swimming pool water samples, respectively). - Highlights: • A new microextraction method combining the

Zirconia coated stir bar sorptive extraction combined with large volume sample stacking capillary electrophoresis-indirect ultraviolet detection for the determination of chemical warfare agent degradation products in water samples.

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Li, Pingjing; Hu, Bin; Li, Xiaoyong

2012-07-20

In this study, a sensitive, selective and reliable analytical method by combining zirconia (ZrO₂) coated stir bar sorptive extraction (SBSE) with large volume sample stacking capillary electrophoresis-indirect ultraviolet (LVSS-CE/indirect UV) was developed for the direct analysis of chemical warfare agent degradation products of alkyl alkylphosphonic acids (AAPAs) (including ethyl methylphosphonic acid (EMPA) and pinacolyl methylphosphonate (PMPA)) and methylphosphonic acid (MPA) in environmental waters. ZrO₂ coated stir bar was prepared by adhering nanometer-sized ZrO₂ particles onto the surface of stir bar with commercial PDMS sol as adhesion agent. Due to the high affinity of ZrO₂ to the electronegative phosphonate group, ZrO₂ coated stir bars could selectively extract the strongly polar AAPAs and MPA. After systematically optimizing the extraction conditions of ZrO₂-SBSE, the analytical performance of ZrO₂-SBSE-CE/indirect UV and ZrO₂-SBSE-LVSS-CE/indirect UV was assessed. The limits of detection (LODs, at a signal-to-noise ratio of 3) obtained by ZrO₂-SBSE-CE/indirect UV were 13.4-15.9 μg/L for PMPA, EMPA and MPA. The relative standard deviations (RSDs, n=7, c=200 μg/L) of the corrected peak area for the target analytes were in the range of 6.4-8.8%. Enhancement factors (EFs) in terms of LODs were found to be from 112- to 145-fold. By combining ZrO₂ coating SBSE with LVSS as a dual preconcentration strategy, the EFs were magnified up to 1583-fold, and the LODs of ZrO₂-SBSE-LVSS-CE/indirect UV were 1.4, 1.2 and 3.1 μg/L for PMPA, EMPA, and MPA, respectively. The RSDs (n=7, c=20 μg/L) were found to be in the range of 9.0-11.8%. The developed ZrO₂-SBSE-LVSS-CE/indirect UV method has been successfully applied to the analysis of PMPA, EMPA, and MPA in different environmental water samples, and the recoveries for the spiked water samples were found to be in the range of 93.8-105.3%. Copyright © 2012 Elsevier B.V. All rights reserved.

Development of a sensitive determination method for benzotriazole UV stabilizers in enviromental water samples with stir bar sorption extraction and liquid desorption prior to ultra-high performance liquid chromatography with tandem mass spectrometry.

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Montesdeoca-Esponda, Sarah; del Toro-Moreno, Adrián; Sosa-Ferrera, Zoraida; Santana-Rodríguez, José Juan

2013-07-01

Benzotriazole UV stabilizers are emerging compounds used in personal care products and can enter surface water after passing through wastewater treatment plants without being removed. Because these analytes are strongly hydrophobic, there is an environmental risk of accumulation in solid matrices and magnification through the trophic chain. In this work, a method based on stir bar sorption extraction with liquid desorption is presented for the extraction of benzotriazole UV stabilizers from water samples. Stir bar sorptive extraction was combined with ultra-high performance LC with MS/MS detection. All important factors affecting the stir bar sorptive extraction procedure are discussed, and the optimized method was applied to seawater and wastewater samples from Gran Canaria Island, providing good selectivity and sensitivity with LODs and limits of quantification in the range of 18.4-55.1 and 61.5-184 ng/L, respectively. Recoveries between 68.4-92.2% were achieved for the more polar compounds, whereas the recoveries were lower for the two less polar compounds, most likely due to their strong absorption into the polydimethylsiloxane stir bar phase that does not allows the complete desorption. The repeatability studies gave RSDs of between 6.45 and 12.6% for all compounds in the real samples. © 2013 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

Trace determination of volatile polycyclic aromatic hydrocarbons in natural waters by magnetic ionic liquid-based stir bar dispersive liquid microextraction.

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Benedé, Juan L; Anderson, Jared L; Chisvert, Alberto

2018-01-01

In this work, a novel hybrid approach called stir bar dispersive liquid microextraction (SBDLME) that combines the advantages of stir bar sorptive extraction (SBSE) and dispersive liquid-liquid microextraction (DLLME) has been employed for the accurate and sensitive determination of ten polycyclic aromatic hydrocarbons (PAHs) in natural water samples. The extraction is carried out using a neodymium stir bar magnetically coated with a magnetic ionic liquid (MIL) as extraction device, in such a way that the MIL is dispersed into the solution at high stirring rates. Once the stirring is ceased, the MIL is magnetically retrieved onto the stir bar, and subsequently subjected to thermal desorption (TD) coupled to a gas chromatography-mass spectrometry (GC-MS) system. The main parameters involved in TD, as well as in the extraction step affecting the extraction efficiency (i.e., MIL amount, extraction time and ionic strength) were evaluated. Under the optimized conditions, the method was successfully validated showing good linearity, limits of detection and quantification in the low ng L -1 level, good intra- and inter-day repeatability (RSD < 13%) and good enrichment factors (18 - 717). This sensitive analytical method was applied to the determination of trace amounts of PAHs in three natural water samples (river, tap and rainwater) with satisfactory relative recovery values (84-115%), highlighting that the matrices under consideration do not affect the extraction process. Copyright © 2017 Elsevier B.V. All rights reserved.

Ultra-trace determination of Persistent Organic Pollutants in Arctic ice using stir bar sorptive extraction and gas chromatography coupled to mass spectrometry.

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Lacorte, S; Quintana, J; Tauler, R; Ventura, F; Tovar-Sánchez, A; Duarte, C M

2009-12-04

This study presents the optimization and application of an analytical method based on the use of stir bar sorptive extraction (SBSE) gas chromatography coupled to mass spectrometry (GC-MS) for the ultra-trace analysis of POPs (Persistent Organic Pollutants) in Arctic ice. In a first step, the mass-spectrometry conditions were optimized to quantify 48 compounds (polycyclic aromatic hydrocarbons, brominated diphenyl ethers, chlorinated biphenyls, and organochlorinated pesticides) at the low pg/L level. In a second step, the performance of this analytical method was evaluated to determine POPs in Arctic cores collected during an oceanographic campaign. Using a calibration range from 1 to 1800 pg/L and by adjusting acquisition parameters, limits of detection at the 0.1-99 and 102-891 pg/L for organohalogenated compounds and polycyclic aromatic hydrocarbons, respectively, were obtained by extracting 200 mL of unfiltered ice water. alpha-hexachlorocyclohexane, DDTs, chlorinated biphenyl congeners 28, 101 and 118 and brominated diphenyl ethers congeners 47 and 99 were detected in ice cores at levels between 0.5 to 258 pg/L. We emphasise the advantages and disadvantages of in situ SBSE in comparison with traditional extraction techniques used to analyze POPs in ice.

Characterisation of dissolved organic compounds in hydrothermal fluids by stir bar sorptive extraction - gas chomatography - mass spectrometry. Case study: the Rainbow field (36°N, Mid-Atlantic Ridge

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Konn Cecile

2012-11-01

Full Text Available Abstract The analysis of the dissolved organic fraction of hydrothermal fluids has been considered a real challenge due to sampling difficulties, complexity of the matrix, numerous interferences and the assumed ppb concentration levels. The present study shows, in a qualitative approach, that Stir Bar Sorptive Extraction (SBSE followed by Thermal Desorption – Gas Chromatography – Mass Spectrometry (TD-GC-MS is suitable for extraction of small sample volumes and detection of a wide range of volatile and semivolatile organic compounds dissolved in hydrothermal fluids. In a case study, the technique was successfully applied to fluids from the Rainbow ultramafic-hosted hydrothermal field located at 36°14’N on the Mid-Atlantic Ridge (MAR. We show that n-alkanes, mono- and poly- aromatic hydrocarbons as well as fatty acids can be easily identified and their retention times determined. Our results demonstrate the excellent repeatability of the method as well as the possibility of storing stir bars for at least three years without significant changes in the composition of the recovered organic matter. A preliminary comparative investigation of the organic composition of the Rainbow fluids showed the great potential of the method to be used for assessing intrafield variations and carrying out time series studies. All together our results demonstrate that SBSE-TD-GC-MS analyses of hydrothermal fluids will make important contributions to the understanding of geochemical processes, geomicrobiological interactions and formation of mineral deposits.

Amino modified multi-walled carbon nanotubes/polydimethylsiloxane coated stir bar sorptive extraction coupled to high performance liquid chromatography-ultraviolet detection for the determination of phenols in environmental samples.

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Hu, Cong; Chen, Beibei; He, Man; Hu, Bin

2013-07-26

In this work, amino modified multi-walled carbon nanotubes/polydimethylsiloxane (multi-walled carbon nanotubes-4,4'-diaminodiphenylmethane/polydimethylsiloxane, MWCNTs-DDM/PDMS) was synthesized, and utilized as a novel coating for stir bar sorptive extraction (SBSE) of seven phenols (phenol, 2-chlorophenol, 2-nitrophenol, 4-nitrophenol, 2,4-dimethylphenol, p-choro-m-cresol and 2,4,6-trichlorphenol) in environmental water and soil samples, followed by high performance liquid chromatography-ultraviolet detection (HPLC-UV). The prepared MWCNTs-DDM/PDMS coated stir bar was characterized and good preparation reproducibility was obtained with the relative standard deviations (RSDs) ranging from 4.7% to 11.3% (n=9) in one batch, and from 4.8% to 13.9% (n=8) among different batches. Several parameters affecting the extraction of seven target phenols by MWCNTs-DDM/PDMS-SBSE including extraction time, stirring rate, pH, ionic strength, desorption solvent and desorption time were investigated. Under the optimal experimental conditions, the limits of detection (LODs, S/N=3) were found to be in the range of 0.14μg/L (2-nitrophenol) to 1.76μg/L (phenol) and the limits of quantification (LOQs, S/N=10) were found to be in the range of 0.46μg/L (2-nitrophenol) to 5.8μg/L (phenol). The linear range was 5-1000μg/L for phenol and 4-nitrophenol, 1-1000μg/L for 2-nitrophenol and 2-1000μg/L for other phenols, respectively. The RSDs of the developed method were in the range of 6.2-11.6% (n=8, c=10μg/L) and the enrichment factors were from 6.5 to 62.8-fold (theoretical enrichment factor was 100-fold). The proposed method was successfully applied to the analysis of phenols in environmental water and soil samples, and good recoveries were obtained for the spiked samples. The proposed method is simple, highly sensitive and suitable for the analysis of trace phenols in environmental samples with complex matrix. Copyright © 2013 Elsevier B.V. All rights reserved.

Determination of tributyltin in environmental water matrices using stir bar sorptive extraction with in-situ derivatisation and large volume injection-gas chromatography-mass spectrometry.

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Neng, N R; Santalla, R P; Nogueira, J M F

2014-08-01

Stir bar sorptive extraction with in-situ derivatization using sodium tetrahydridoborate (NaBH4) followed by liquid desorption and large volume injection-gas chromatography-mass spectrometry detection under the selected ion monitoring mode (SBSE(NaBH4)in-situ-LD/LVI-GC-MS(SIM)) was successfully developed for the determination of tributyltin (TBT) in environmental water matrices. NaBH4 proved to be an effective and easy in-situ speciation agent for TBT in aqueous media, allowing the formation of adducts with enough stability and suitable polarity for SBSE analysis. Assays performed on water samples spiked at the 10.0μg/L, yielded convenient recoveries (68.2±3.0%), showed good accuracy, suitable precision (RSD<9.0%), low detection limits (23ng/L) and excellent linear dynamic range (r(2)=0.9999) from 0.1 to 170.0µg/L, under optimized experimental conditions. By using the standard addition method, the application of the present methodology to real surface water samples allowed very good performance at the trace level. The proposed methodology proved to be a feasible alternative for routine quality control analysis, easy to implement, reliable and sensitive to monitor TBT in environmental water matrices. Copyright © 2014 Elsevier B.V. All rights reserved.

Quantitative analysis of perfumes in talcum powder by using headspace sorptive extraction.

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Ng, Khim Hui; Heng, Audrey; Osborne, Murray

2012-03-01

Quantitative analysis of perfume dosage in talcum powder has been a challenge due to interference of the matrix and has so far not been widely reported. In this study, headspace sorptive extraction (HSSE) was validated as a solventless sample preparation method for the extraction and enrichment of perfume raw materials from talcum powder. Sample enrichment is performed on a thick film of poly(dimethylsiloxane) (PDMS) coated onto a magnetic stir bar incorporated in a glass jacket. Sampling is done by placing the PDMS stir bar in the headspace vial by using a holder. The stir bar is then thermally desorbed online with capillary gas chromatography-mass spectrometry. The HSSE method is based on the same principles as headspace solid-phase microextraction (HS-SPME). Nevertheless, a relatively larger amount of extracting phase is coated on the stir bar as compared to SPME. Sample amount and extraction time were optimized in this study. The method has shown good repeatability (with relative standard deviation no higher than 12.5%) and excellent linearity with correlation coefficients above 0.99 for all analytes. The method was also successfully applied in the quantitative analysis of talcum powder spiked with perfume at different dosages. © 2012 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

An improved hollow fiber solvent-stir bar microextraction for the preconcentration of anabolic steroids in biological matrix with determination by gas chromatography-mass spectrometry.

Science.gov (United States)

Liu, Wei; Zhang, Lan; Fan, Liangbiao; Lin, Zian; Cai, Yimin; Wei, Zhenyi; Chen, Guonan

2012-04-13

In this paper, a convenient and self-assembled hollow fiber solvent-stir bar microextraction (HF-SSBME) device was developed, which could stir by itself. In the extraction process, the proposed device made the solvent "bar" not floating at the sample solution and exposing to air while organic solvents outside hollow fiber always wrapped with donor phase solvent, which reduced the vaporization of organic solvents. This design could improve the precisions and recoveries of experiments. For evaluating the device, seven anabolic steroids (prasterone, 5α-androstane-3α, 17β-diol, methandriol, 19-norandrostenediol, androstenediol, methyltestosterone and methandienone) were used as model analytes and extraction conditions such as type and volume of organic solvents, agitation speed, extraction time, extraction temperature and salt addition were studied in detail. Under the optimum conditions (15 μL toluene, 40 °C, stirring at 750 rpm for 30 min with 1.5 g sodium chloride addition in 20.0 mL donor phase), the linear ranges of anabolic steroids were 0.25-200 ng mL(-1) with gas chromatography-mass spectrometry. The limits of detection were lower than 0.10 ng mL(-1). The recoveries and precisions in spiked urine and hair samples were between 73.97-93.56% and 2.18-4.47% (n=5). HF-SSBME method combined the intrinsical merits of hollow fiber with the superiority of the proposed self-stirring device which can be developed to two-phase, three-phase and in situ derivatization modes with wide prospect of application. Besides, the pedestal of this proposed device can be converted to fix stir bar in stir bar sorptive extraction (SBSE) method. Copyright © 2012 Elsevier B.V. All rights reserved.

New Functionalized Sol-Gel Hybrid Sorbent Coating for Stir Bar Sorptive Extraction of Selected Non-Steroidal Anti Inflammatory Drugs in Human Urine Samples

International Nuclear Information System (INIS)

Mashkurah Abd Rahim; Wan Aini Wan Ibrahim; Zainab Ramli; Mohd Marsin Sanagi

2015-01-01

A new sol-gel hybrid material, methyltrimethoxysilane-cyanopropyltriethoxysilane (MTMOS-CNPrTEOS) was successfully synthesized and used as a coating material in stir bar sorptive extraction (SBSE) of selected non-steroidal anti-inflammatory drugs (NSAIDs) in urine samples. The MTMOS-CNPrTEOS hybrid was synthesized by hydrolysis and condensation of MTMOS and CNPrTEOS in the presence of trifluoroacetic acid as catalyst via sol-gel method. Several factors influencing the synthesized sol-gel hybrid MTMOS-CNPrTEOS process such as mole ratio of MTMOS-CNPrTEOS, NaOH concentrations as etching solution, etching time, coating time and water content were investigated and optimized in this study. The optimum synthesis conditions obtained were 1:1 mol ratio of MTMOS-CNPrTEOS, 1 M NaOH as etching solution, 60 min etching time, 2 h coating time and 6 mmol water. The sol-gel hybrid MTMOS-CNPrTEOS synthesized under the optimum conditions was used to determine selected NSAIDs in human urine samples using normal stacking mode capillary electrophoresis with ultraviolet detection. MTMOS-CNPrTEOS SBSE method demonstrated good linearity (60 to 20,000 μg L -1 ) with excellent coefficient of determination (r 2 > 0.9990). The sol-gel hybrid MTMOS-CNPrTEOS SBSE method showed low limit of detection (35 - 41 μg L -1 ) with good precision (RSD < 6 %, n = 3) and excellent extraction recoveries (83.5 - 98.9 %) for the selected NSAIDs. The sol-gel hybrid MTMOS-CNPrTEOS SBSE method demonstrated good potential as an alternative sorbent in SBSE method for NSAIDs. (author)

Cadmium (II) imprinted 3-mercaptopropyltrimethoxysilane coated stir bar for selective extraction of trace cadmium from environmental water samples followed by inductively coupled plasma mass spectrometry detection

Energy Technology Data Exchange (ETDEWEB)

Zhang Nan [Key Laboratory of Analytical Chemistry for Biology and Medicine (Ministry of Education), Department of Chemistry, Wuhan University, Wuhan 430072 (China); Hu Bin, E-mail: binhu@whu.edu.cn [Key Laboratory of Analytical Chemistry for Biology and Medicine (Ministry of Education), Department of Chemistry, Wuhan University, Wuhan 430072 (China)

2012-04-20

Graphical abstract: Ion imprinted 3-mercaptopropyltrimethoxysilane (MPTS) coated stir bar for selective extraction of trace Cd(II). Highlights: Black-Right-Pointing-Pointer Ion imprinted polymers were proposed as the coating for SBSE for the first time. Black-Right-Pointing-Pointer Cd(II) imprinted MPTS-silica coating was prepared by a double-imprinting concept. Black-Right-Pointing-Pointer A novel method of SBSE-ICP-MS was developed for the determination of Cd in waters. Black-Right-Pointing-Pointer This method is rapid, selective, sensitive and applicable for determining trace Cd(II) in waters. - Abstract: Cd(II) imprinted 3-mercaptopropyltrimethoxysilane (MPTS)-silica coated stir bar was prepared by sol-gel technique combining with a double-imprinting concept for the first time and was employed for stir bar sorptive extraction (SBSE) of trace Cd(II) from water samples followed by inductively coupled plasma mass spectrometry (ICP-MS) detection. A tetramethoxysilane (TMOS) coating was first in situ created on the glass bar surface. Afterward, a sol solution containing MPTS as the functional precursor, ethanol as the solvent and both Cd(II) and surfactant micelles (cetyltrimethylammonium bromide, CTAB) as the template was again coated on the TMOS bar. The structures of the stir bar coating were characterized by FT-IR spectroscopy. Round-bottom vial was used for the extraction of Cd(II) by SBSE to avoid abrasion of stir bar coatings. The factors affecting the extraction of Cd(II) by SBSE such as pH, stirring rate and time, sample/elution volume and interfering ions have been investigated in detail, and the optimized experimental parameters were obtained. Under the optimized conditions, the adsorption capacities of non-imprinted and imprinted coating stir bars were found to be 0.5 {mu}g and 0.8 {mu}g bar{sup -1}. The detection limit (3{sigma}) based on three times standard deviations of the method blanks by 7 replicates was 4.40 ng L{sup -1} and the relative standard

Cadmium (II) imprinted 3-mercaptopropyltrimethoxysilane coated stir bar for selective extraction of trace cadmium from environmental water samples followed by inductively coupled plasma mass spectrometry detection

International Nuclear Information System (INIS)

Zhang Nan; Hu Bin

2012-01-01

Graphical abstract: Ion imprinted 3-mercaptopropyltrimethoxysilane (MPTS) coated stir bar for selective extraction of trace Cd(II). Highlights: ► Ion imprinted polymers were proposed as the coating for SBSE for the first time. ► Cd(II) imprinted MPTS-silica coating was prepared by a double-imprinting concept. ► A novel method of SBSE–ICP-MS was developed for the determination of Cd in waters. ► This method is rapid, selective, sensitive and applicable for determining trace Cd(II) in waters. - Abstract: Cd(II) imprinted 3-mercaptopropyltrimethoxysilane (MPTS)-silica coated stir bar was prepared by sol–gel technique combining with a double-imprinting concept for the first time and was employed for stir bar sorptive extraction (SBSE) of trace Cd(II) from water samples followed by inductively coupled plasma mass spectrometry (ICP-MS) detection. A tetramethoxysilane (TMOS) coating was first in situ created on the glass bar surface. Afterward, a sol solution containing MPTS as the functional precursor, ethanol as the solvent and both Cd(II) and surfactant micelles (cetyltrimethylammonium bromide, CTAB) as the template was again coated on the TMOS bar. The structures of the stir bar coating were characterized by FT-IR spectroscopy. Round-bottom vial was used for the extraction of Cd(II) by SBSE to avoid abrasion of stir bar coatings. The factors affecting the extraction of Cd(II) by SBSE such as pH, stirring rate and time, sample/elution volume and interfering ions have been investigated in detail, and the optimized experimental parameters were obtained. Under the optimized conditions, the adsorption capacities of non-imprinted and imprinted coating stir bars were found to be 0.5 μg and 0.8 μg bar −1 . The detection limit (3σ) based on three times standard deviations of the method blanks by 7 replicates was 4.40 ng L −1 and the relative standard deviation (RSD) was 3.38% (c = 1 μg L −1 , n = 7). The proposed method was successfully applied for the

Enantioselective extraction of (+)-(S)-citalopram and its main metabolites using a tailor-made stir bar chiral imprinted polymer for their LC-ESI-MS/MS quantitation in urine samples.

Science.gov (United States)

Unceta, Nora; Gómez-Caballero, Alberto; García, Deiene; Díaz, Goretti; Guerreiro, Antonio; Piletsky, Sergey; Goicolea, M Aránzazu; Barrio, Ramón J

2013-11-15

This paper reports the application of a chiral imprinted polymer (CIP)-coated stir bar for the selective extraction of (+)-(S)-citalopram (SCIT) and its main metabolites, (+)-(S)-desmethylcitalopram (SDCIT) and (+)-(S)-didesmethylcitalopram (SDDCIT), from urine samples. The developed device has been demonstrated to be capable of selectively extracting the three target analytes from urine samples without saturating the imprinted sites. A CIP-coated stir bar sorptive extraction procedure (CIP-SBSE) is proposed for the isolation of SCIT, SDCIT and SDDCIT followed by their subsequent analysis using liquid chromatography ion trap mass spectrometry (LC-ITMS). Deuterated SCIT-d6 was used as an internal standard. The method was validated using a standard procedure, which revealed that a quantification of 5 ng mL(-1) was obtained in urine samples and that the accuracy and precision were within the established values while no matrix effect was observed. Copyright © 2013 Elsevier B.V. All rights reserved.

Atmospheric pressure gas chromatography-time-of-flight-mass spectrometry (APGC-ToF-MS) for the determination of regulated and emerging contaminants in aqueous samples after stir bar sorptive extraction (SBSE).

Science.gov (United States)

Pintado-Herrera, Marina G; González-Mazo, Eduardo; Lara-Martín, Pablo A

2014-12-03

This work presents the development, optimization and validation of a multi-residue method for the simultaneous determination of 102 contaminants, including fragrances, UV filters, repellents, endocrine disruptors, biocides, polycyclic aromatic hydrocarbons (PAHs), polychlorinated biphenyls (PCBs), and several types of pesticides in aqueous matrices. Water samples were processed using stir bar sorptive extraction (SBSE) after the optimization of several parameters: agitation time, ionic strength, presence of organic modifiers, pH, and volume of the derivatizing agent. Target compounds were extracted from the bars by liquid desorption (LD). Separation, identification and quantification of analytes were carried out by gas chromatography (GC) coupled to time-of-flight (ToF-MS) mass spectrometry. A new ionization source, atmospheric pressure gas chromatography (APGC), was tested. The optimized protocol showed acceptable recovery percentages (50-100%) and limits of detection below 1ngL(-1) for most of the compounds. Occurrence of 21 out of 102 analytes was confirmed in several environmental aquatic matrices, including seawater, sewage effluent, river water and groundwater. Non-target compounds such as organophosphorus flame retardants were also identified in real samples by accurate mass measurement of their molecular ions using GC-APGC-ToF-MS. To the best of our knowledge, this is the first time that this technique has been applied for the analysis of contaminants in aquatic systems. By employing lower energy than the more widely used electron impact ionization (EI), AGPC provides significant advantages over EI for those substances very susceptible to high fragmentation (e.g., fragrances, pyrethroids). Copyright © 2014 Elsevier B.V. All rights reserved.

Non-Destructive Assessment of Aroma Volatiles from a Climacteric Near-Isogenic Line of Melon Obtained by Headspace Stir-Bar Sorptive Extraction

Directory of Open Access Journals (Sweden)

Juan Pablo Fernández-Trujillo

2013-08-01

Full Text Available A climacteric aromatic near-isogenic line (NIL of melon (Cucumis melo L. SC3-5-1 contained an introgression of the non-climacteric Korean cultivar “Shongwan Charmi” accession PI 161375 (SC in the genetic background of the non-climacteric cultivar “Piel de Sapo” (PS. The aroma production was monitored during ripening at 21 °C in intact fruit using headspace sorptive bar extraction (HSSE. Bars were composed of polydimethylsiloxane (PDMS and aromas were desorbed and analyzed by gas-chromatography mass-spectrometry. The aromatic profile was composed of 70 aromatic compounds plus 21 alkanes with a predominance of esters, particularly acetate (2-methylbutyl acetate, 2-methylpropyl acetate, hexyl acetate, and phenylmethyl acetate. Some compounds were severely affected by postharvest time. The acetate esters (3-methylbutyl acetate, butan-2-yl acetate and phenylmethyl acetate decreased with ripening and sulfur-derived compounds (S-methyl butanethioate and S-methyl 3-methylbutanethioate increased gradually with ripening. A few compounds increased at the senescence phase (propyl ethanoate. Other compounds such as hexadecanoic acid showed a marked decrease after harvest, some decreasing from a relative maximum at harvest (2-methylpropyl hexanoate; n-hexanoic acid; nonanoic acid.

Molecularly imprinted polymeric stir bar: Preparation and application for the determination of naftopidil in plasma and urine samples.

Science.gov (United States)

Peng, Jun; Xiao, Deli; He, Hua; Zhao, Hongyan; Wang, Cuixia; Shi, Tian; Shi, Kexin

2016-01-01

In this study, molecularly imprinting technology and stir bar absorption technology were combined to develop a microextraction approach based on a molecularly imprinted polymeric stir bar. The molecularly imprinted polymer stir bar has a high performance, is specific, economical, and simple to prepare. The obtained naftopidil-imprinted polymer-coated bars could simultaneously agitate and adsorb naftopidil in the sample solution. The ratio of template/monomer/cross-linker and conditions of template removal were optimized to prepare a stir bar with highly efficient adsorption. Fourier transform infrared spectroscopy, scanning electron microscopy, selectivity, and extraction capacity experiments showed that the molecularly imprinted polymer stir bar was prepared successfully. To utilize the molecularly imprinted polymer stir bar for the determination of naftopidil in complex body fluid matrices, the extraction time, stirring speed, eluent, and elution time were optimized. The limits of detection of naftopidil in plasma and urine sample were 7.5 and 4.0 ng/mL, respectively, and the recoveries were in the range of 90-112%. The within-run precision and between-run precision were acceptable (relative standard deviation bar based microextraction with high-performance liquid chromatography was a convenient, rapid, efficient, and specific method for the precise determination of trace naftopidil in clinical analysis. © 2015 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

Atmospheric pressure gas chromatography–time-of-flight-mass spectrometry (APGC–ToF-MS) for the determination of regulated and emerging contaminants in aqueous samples after stir bar sorptive extraction (SBSE)

International Nuclear Information System (INIS)

Pintado-Herrera, Marina G.; González-Mazo, Eduardo; Lara-Martín, Pablo A.

2014-01-01

Graphical abstract: Examples of identification of target (triclosan, TCS) and non-target (tributhyl phosphate, TBP) compounds in environmental water samples by APGC–ToF-MS. Some confirmation criteria are shown (i.e. mass spectra, isotopic distribution, and accurate mass). - Highlights: • 102 regulated and emerging contaminants are simultaneously extracted by SBSE. • APGC–ToF-MS is presented as an alternative to EI for the analysis of microcontaminants. • Identification of non-target compounds in environmental matrices is also explored. - Abstract: This work presents the development, optimization and validation of a multi-residue method for the simultaneous determination of 102 contaminants, including fragrances, UV filters, repellents, endocrine disruptors, biocides, polycyclic aromatic hydrocarbons (PAHs), polychlorinated biphenyls (PCBs), and several types of pesticides in aqueous matrices. Water samples were processed using stir bar sorptive extraction (SBSE) after the optimization of several parameters: agitation time, ionic strength, presence of organic modifiers, pH, and volume of the derivatizing agent. Target compounds were extracted from the bars by liquid desorption (LD). Separation, identification and quantification of analytes were carried out by gas chromatography (GC) coupled to time-of-flight (ToF-MS) mass spectrometry. A new ionization source, atmospheric pressure gas chromatography (APGC), was tested. The optimized protocol showed acceptable recovery percentages (50–100%) and limits of detection below 1 ng L −1 for most of the compounds. Occurrence of 21 out of 102 analytes was confirmed in several environmental aquatic matrices, including seawater, sewage effluent, river water and groundwater. Non-target compounds such as organophosphorus flame retardants were also identified in real samples by accurate mass measurement of their molecular ions using GC-APGC–ToF-MS. To the best of our knowledge, this is the first time that this

Atmospheric pressure gas chromatography–time-of-flight-mass spectrometry (APGC–ToF-MS) for the determination of regulated and emerging contaminants in aqueous samples after stir bar sorptive extraction (SBSE)

Energy Technology Data Exchange (ETDEWEB)

Pintado-Herrera, Marina G.; González-Mazo, Eduardo; Lara-Martín, Pablo A., E-mail: pablo.lara@uca.es

2014-12-03

Graphical abstract: Examples of identification of target (triclosan, TCS) and non-target (tributhyl phosphate, TBP) compounds in environmental water samples by APGC–ToF-MS. Some confirmation criteria are shown (i.e. mass spectra, isotopic distribution, and accurate mass). - Highlights: • 102 regulated and emerging contaminants are simultaneously extracted by SBSE. • APGC–ToF-MS is presented as an alternative to EI for the analysis of microcontaminants. • Identification of non-target compounds in environmental matrices is also explored. - Abstract: This work presents the development, optimization and validation of a multi-residue method for the simultaneous determination of 102 contaminants, including fragrances, UV filters, repellents, endocrine disruptors, biocides, polycyclic aromatic hydrocarbons (PAHs), polychlorinated biphenyls (PCBs), and several types of pesticides in aqueous matrices. Water samples were processed using stir bar sorptive extraction (SBSE) after the optimization of several parameters: agitation time, ionic strength, presence of organic modifiers, pH, and volume of the derivatizing agent. Target compounds were extracted from the bars by liquid desorption (LD). Separation, identification and quantification of analytes were carried out by gas chromatography (GC) coupled to time-of-flight (ToF-MS) mass spectrometry. A new ionization source, atmospheric pressure gas chromatography (APGC), was tested. The optimized protocol showed acceptable recovery percentages (50–100%) and limits of detection below 1 ng L{sup −1} for most of the compounds. Occurrence of 21 out of 102 analytes was confirmed in several environmental aquatic matrices, including seawater, sewage effluent, river water and groundwater. Non-target compounds such as organophosphorus flame retardants were also identified in real samples by accurate mass measurement of their molecular ions using GC-APGC–ToF-MS. To the best of our knowledge, this is the first time that this

Sensitive determination of estrogens in environmental waters treated with polymeric ionic liquid-based stir cake sorptive extraction and liquid chromatographic analysis.

Science.gov (United States)

Chen, Lei; Mei, Meng; Huang, Xiaojia; Yuan, Dongxing

2016-05-15

A simple, sensitive and environmentally friendly method using polymeric ionic liquid-based stir cake sorptive extraction followed by high performance liquid chromatography with diode array detection (HPLC/DAD) has been developed for efficient quantification of six selected estrogens in environmental waters. To extract trace estrogens effectively, a poly (1-ally-3-vinylimidazolium chloride-co-ethylene dimethacrylate) monolithic cake was prepared and used as the sorbent of stir cake sorptive extraction (SCSE). The effects of preparation conditions of sorbent and extraction parameters of SCSE for estrogens were investigated and optimized. Under optimal conditions, the developed method showed satisfactory analytical performance for targeted analytes. Low limits of detection (S/N=3) and quantification limits (S/N=10) were achieved within the range of 0.024-0.057 µg/L and 0.08-0.19 µg/L, respectively. Good linearity of method was obtained for analytes with the correlation coefficients (R(2)) above 0.99. At the same time, satisfactory method repeatability and reproducibility was achieved in terms of intra- and inter-day precisions, respectively. Finally, the established SCSE-HPLC/DAD method was successfully applied for the determination of estrogens in different environmental water samples. Recoveries obtained for the determination of estrogens in spiked samples ranged from 71.2% to 108%, with RSDs below 10% in all cases. Copyright © 2016 Elsevier B.V. All rights reserved.

Dual solid-phase and stir bar sorptive extraction combined with gas chromatography-mass spectrometry analysis provides a suitable tool for assaying limonene-derived mint aroma compounds in red wine.

Science.gov (United States)

Picard, Magali; Franc, Céline; de Revel, Gilles; Marchand, Stéphanie

2018-02-25

A novel analytical method was developed for quantitative determination of eight limonene-derived monoterpenes responsible for the mint aroma in red wine. As these aromatic compounds are present at trace levels, a new dual extraction approach was proposed, combining solid-phase extraction (SPE) and stir bar sorptive extraction (SBSE), followed by gas chromatography-mass spectrometry analysis. The various parameters affecting the efficiency of extracting the analytes from wine samples in both the SPE and SBSE steps were first investigated, to determine the best compromise for the simultaneous analysis of the compounds studied. Following preliminary optimization of the dilution factor, phase ratio, and methanol content in the SBSE sample, cartridge sorbent mass, type of solvent, elution volume, and wine sample volume in the pre-concentration SPE step were studied. Highest response values were obtained when a 90 mL wine sample was extracted on a 500 mg SPE C18 cartridge and eluted with 1.5 mL methanol. The wine extract was then diluted in 10 mL water to obtain a final methanol content of 15% before the SBSE step. Good linearity, repeatability, reproducibility, accuracy and the required low detection and quantification limits were obtained under the conditions described, making this SPE-SBSE combination a suitable, powerful tool for routine analysis of the selected limonene-derived mint aroma compounds in large series of wine samples. Finally, the validated method was applied to 15 commercial red Bordeaux wines, aged from 3 to 23 years. Most of the compounds studied, present within the ng.L -1 range, were easily quantified for the first time in wine. Copyright © 2017 Elsevier B.V. All rights reserved.

Application of modified stir bar with nickel:zinc sulphide nanoparticles loaded on activated carbon as a sorbent for preconcentration of losartan and valsartan and their determination by high performance liquid chromatography.

Science.gov (United States)

Pebdani, Arezou Amiri; Dadfarnia, Shayesteh; Shabani, Ali Mohammad Haji; Khodadoust, Saeid; Haghgoo, Soheila

2016-03-11

In this study, the stir bar was coated for the first time with the ​nicel:zins sulphide nanoparticles (Ni:ZnS NPs) loaded on activated carbon (AC) (Ni:ZnS-AC) as well as 1-ethyl-3-methylimidazolium hexafluorophosphate ionic liquid (IL) using sol gel technique and was used for stir bar sorptive extraction (SBSE) of losartan (LOS) and valsartan (VAL) as the model compounds. The extracted analytes were then quantified by high performance liquid chromatography (HPLC) equipped with an ultra violet detector. The best extraction performance for LOS and VAL was obtained through the optimization of the parameters affecting SBSE including pH of sample solution, ionic strength, extraction time, volume of desorption solvent, desorption time, and stirring speed. The fractional factorial design (FFD) was used to find the most important parameters, which were then optimized by the central composite design (CCD) and the desirability function (DF). Under the optimal experimental conditions, wide linear ranges of 0.4-50μgL(-1) and 0.5-50μgL(-1) and good RSDs (at level of 5μgL(-1) and n=6) of 4.4 and 4.9% were obtained for LOS and VAL, respectively. With the enrichment factors (EFs) of 188.6 and 184.8-fold, the limits of detection (LODs, S/N=3) of the developed method were found to be 0.12 and 0.15μgL(-1) for LOS and VAL, respectively. The developed method was successfully applied to the determination of LOS and VAL in urine and plasma matrices. Copyright © 2016 Elsevier B.V. All rights reserved.

Comparison of a disposable sorptive sampler with thermal desorption in a gas chromatographic inlet, or in a dedicated thermal desorber, to conventional stir bar sorptive extraction-thermal desorption for the determination of micropollutants in water.

Science.gov (United States)

Wooding, Madelien; Rohwer, Egmont R; Naudé, Yvette

2017-09-01

The presence of micropollutants in the aquatic environment is a worldwide environmental concern. The diversity of micropollutants and the low concentration levels at which they may occur in the aquatic environment have greatly complicated the analysis and detection of these chemicals. Two sorptive extraction samplers and two thermal desorption methods for the detection of micropollutants in water were compared. A low-cost, disposable, in-house made sorptive extraction sampler was compared to SBSE using a commercial Twister sorptive sampler. Both samplers consisted of polydimethylsiloxane (PDMS) as a sorptive medium to concentrate micropollutants. Direct thermal desorption of the disposable samplers in the inlet of a GC was compared to conventional thermal desorption using a commercial thermal desorber system (TDS). Comprehensive gas chromatography coupled to time-of-flight mass spectrometry (GC × GC-TOFMS) was used for compound separation and identification. Ten micropollutants, representing a range of heterogeneous compounds, were selected to evaluate the performance of the methods. The in-house constructed sampler, with its associated benefits of low-cost and disposability, gave results comparable to commercial SBSE. Direct thermal desorption of the disposable sampler in the inlet of a GC eliminated the need for expensive consumable cryogenics and total analysis time was greatly reduced as a lengthy desorption temperature programme was not required. Limits of detection for the methods ranged from 0.0010 ng L -1 to 0.19 ng L -1 . For most compounds, the mean (n = 3) recoveries ranged from 85% to 129% and the % relative standard deviation (% RSD) ranged from 1% to 58% with the majority of the analytes having a %RSD of less than 30%. Copyright © 2017 Elsevier B.V. All rights reserved.

Stir-bar supported micro-solid-phase extraction for the determination of polychlorinated biphenyl congeners in serum samples.

Science.gov (United States)

Sajid, Muhammad; Basheer, Chanbasha

2016-07-15

In present work, a new configuration of micro-solid phase extraction was introduced and termed as stir-bar supported micro-solid-phase extraction (SB-μ-SPE). A tiny stir-bar was packed inside the porous polypropylene membrane along with sorbent material and the edges of membrane sheet were heat sealed to secure the contents. The packing of stir-bar inside the μ-SPE device does not allow the device to stick with the wall or any corner of the sample vial during extraction, which is, however, a frequent observation in routine μ-SPE. Moreover, it enhances effective surface area of the sorbent exposed to sample solution through continuous agitation (motion and rotation). It also completely immerses the SB-μ-SPE device in the sample solution even for non-polar sorbents. Polychlorinated biphenyls (PCBs) were selected as model compounds and the method performance was evaluated in human serum samples. After extraction, samples were analyzed by gas chromatography mass spectrometry (GC-MS). The factors that affect extraction efficiency of SB-μ-SPE were optimized. Under optimum conditions, a good linearity (0.1-100ngmL(-1)) with coefficients of determinations ranging from 0.9868 to 0.9992 was obtained. Limits of detections were ranged between 0.003 and 0.047ngmL(-1). Acceptable values for inter-day (3.2-9.1%) and intra-day (3.1-7.2%) relative standard deviations were obtained. The optimized method was successfully applied to determine the concentration of PCB congeners in human serum samples. Copyright © 2016 Elsevier B.V. All rights reserved.

Preparation of stir cake sorptive extraction based on polymeric ionic liquid for the enrichment of benzimidazole anthelmintics in water, honey and milk samples

Energy Technology Data Exchange (ETDEWEB)

Wang, Yulei [State Key Laboratory of Marine Environmental Science, Key Laboratory of the Ministry of Education for Coastal and Wetland Ecosystem, College of the Environment and Ecology, Xiamen University, Siming Road, P.O. Box 1009, Xiamen 361005 (China); Zhang, Jie [Key Lab of Urban Environment and Health, Institute of Urban Environment, Chinese Academy of Sciences (China); Huang, Xiaojia, E-mail: hxj@xmu.edu.cn [State Key Laboratory of Marine Environmental Science, Key Laboratory of the Ministry of Education for Coastal and Wetland Ecosystem, College of the Environment and Ecology, Xiamen University, Siming Road, P.O. Box 1009, Xiamen 361005 (China); Yuan, Dongxing [State Key Laboratory of Marine Environmental Science, Key Laboratory of the Ministry of Education for Coastal and Wetland Ecosystem, College of the Environment and Ecology, Xiamen University, Siming Road, P.O. Box 1009, Xiamen 361005 (China)

2014-08-20

Highlights: • A new polymeric ionic liquid-based monolith was prepared. • The monolith was used as the extractive medium of stir cake sorptive extraction. • The SCSE–AMIIDB can extract benzimidazole anthelmintics (BAs) effectively. • A combination of SCSE–AMIIDB–LD–HPLC/DAD was developed. • The combination was applied to monitor trace BAs in water, milk and honey samples. - Abstract: In this work, a new stir cake sorptive extraction (SCSE) using polymeric ionic liquid monolith as sorbent was prepared. The sorbent was obtained by in situ copolymerization of an ionic liquid, 1-allyl-3-methylimidazolium bis[(trifluoro methyl)sulfonyl]imide (AMII) and divinylbenzene (DB) in the presence of N,N-dimethylformamide. The influence of the content of ionic liquid and the porogen in the polymerization mixture on extraction performance was studied thoroughly. The physicochemical properties of the polymeric ionic liquid were characterized by infrared spectroscopy, elemental analysis, scanning electron microscopy and mercury intrusion porosimetry. The usefulness of SCSE–AMIIDB was demonstrated by the enrichment of trace benzimidazole anthelmintics. Several parameters affecting the extraction efficiency were investigated, and under the optimized conditions, a simple and effective method for the determination of trace benzimidazoles residues in water, milk and honey samples was established by coupling SCSE–AMIIDB with high performance liquid chromatography/diode array detection (SCSE–AMIIDB–HPLC/DAD). Results indicated that the limits of detection (S/N = 3) for target compounds were 0.020–0.072 μg L{sup −1}, 0.035–0.10 μg L{sup −1} and 0.026–0.076 μg L{sup −1} in water, milk and honey samples, respectively. In addition, an acceptable reproducibility was achieved by evaluating the repeatability and intermediate precision with relative standard deviations (RSD) of less than 9% and 11%, respectively. Finally, the established AMII�

Preparation of stir cake sorptive extraction based on poly(4-vinylbenzoic acid-divinylbenzene) monolith and its application in sensitive determination of β-agonists in milk and swine urine samples

Energy Technology Data Exchange (ETDEWEB)

Huang, Xiaojia, E-mail: hxj@xmu.edu.cn; Chen, Linli; Yuan, Dongxing

2013-11-15

Highlights: • A new poly(4-vinylbenzoic acid-divinylbenzene) monolith was first prepared. • The porous monolith was used as sorbent of stir cake sorptive extraction. • The new sorbent could extract β-agonists effectively by multiple interactions. • Method of determination of trace β-agonists in milk and urine samples was developed. -- Abstract: In this study, a new stir cake sorptive extraction (SCSE) based on poly(4-vinylbenzoic acid-divinylbenzene) (VBADB) monolith was prepared. The effect of preparation conditions of monolith on extraction efficiencies was investigated in detail. Several characteristic techniques, such as elemental analysis, infrared spectroscopy, mercury intrusion porosimetry and scanning electron microscopy were used to characterize the monolithic material. The combination of SCSE-VBADB with high-performance liquid chromatography tandem mass spectrometry (HPLC/MS/MS) detection was developed for sensitive determination of ultra-trace β-agonists in milk and swine urine samples. In order to obtain the optimal extraction conditions of SCSE-VBADB for β-agonists, several extractive parameters, including pH values and ionic strength in sample matrix, extraction and desorption time were optimized. Under the optimum conditions, the limits of detection (S/N = 3) for the target analytes were 0.007–0.030 μg/L in milk and 0.002–0.011 μg/L in swine urine, respectively. Excellent method reproducibility was achieved in terms of intraday and interday precisions, indicated by the RSDs of both <10.0%, respectively. Finally, the proposed method was successfully used to detect β-agonists in different milk and swine urines samples. Acceptable recoveries ranged from 50.3% to 113% and 50.1% to 92.2% for milk and swine urine samples, respectively; and the RSDs for reproducibility were less than 8.0% for target analytes in all real samples.

Determination of Phenols Isomers in Water by Novel Nanosilica/Polydimethylsiloxane-Coated Stirring Bar Combined with High Performance Liquid Chromatography-Fourier Transform Infrared Spectroscopy.

Science.gov (United States)

Zheng, Bei; Li, Wentao; Liu, Lin; Wang, Xin; Chen, Chen; Yu, Zhiyong; Li, Hongyan

2017-08-18

A novel nanosilica/polydimethylsiloxane (SiO 2 /PDMS) coated stirring bar was adopted in the sorption extraction (SBSE) of phenols in water, and the high performance liquid chromatography-fourier transform infrared spectroscopy (HPLC-FTIR) was subsequently used to determination of phenol concentration. The SiO 2 /PDMS coating was prepared by sol-gel method and characterized with respect to morphology and specific surface area. The results of field-emission scanning electron microscope (FE-SEM) and N 2 adsorption-desorption as well as phenol adsorption experiments denoted that SiO 2 /PDMS has larger surface area and better adsorption capacity than commercial PDMS. The extraction efficiency of phenol with SiO 2 /PDMS coated stirring bar was optimized in terms of ion strength, flow rate of phenol-involved influent, type of desorption solvent and desorption time. More than 75% of phenol desorption efficiency could be kept even after 50 cycles of extraction, indicating the high stability of the SiO 2 /PDMS coated stirring bar. Approximately 0.16 mg/L 2, 5-dimethylphenol (2, 5-DMP), which was 34-fold more toxic than phenol, was detected in water through HPLC-FTIR. However, 2, 5-DMP could be oxidized to 5-methy-2-hydroxy benzaldehyde after disinfection in drinking water treatment process. Therefore, the proposed method of SiO 2 /PDMS-SBSE-HPLC-FTIR is successfully applied in the analysis of phenols isomers in aqueous environment.

Polydimethylsiloxane rod extraction, a novel technique for the determination of organic micropollutants in water samples by thermal desorption-capillary gas chromatography-mass spectrometry.

Science.gov (United States)

Montero, L; Popp, P; Paschke, A; Pawliszyn, J

2004-01-30

A novel, simple and inexpensive approach to absorptive extraction of organic compounds from environmental samples is presented. It consists of a polydimethylsiloxane rod used as an extraction media, enriched with analytes during shaking, then thermally desorbed and analyzed by GC-MS. Its performance was illustrated and evaluated for the enrichment of sub- to ng/l of selected chlorinated compounds (chlorobenzenes and polychlorinated biphenyls) in water samples. The new approach was compared to the stir bar sorptive extraction performance. A natural ground water sample from Bitterfeld, Germany, was also extracted using both methods, showing good agreement. The proposed approach presented good linearity, high sensitivity, good blank levels and recoveries comparable to stir bars, together with advantages such as simplicity, lower cost and higher feasibility.

Determination of Carvedilol Enantiomers in Pharmaceutical Dosages by SBSE-HPLC Based on Diastereomer Formation.

Science.gov (United States)

Taraji, Maryam; Talebpour, Zahra; Adib, Nuoshin; Karimi, Shima; Haghighi, Farideh; Aboul-Enein, Hassan Y

2015-09-01

A sensitive, selective and simple method for the simultaneous determination of carvedilol enantiomers in aqueous solution has been developed using stir bar sorptive extraction (SBSE) followed by high-performance liquid chromatography (HPLC) with ultraviolet (UV) detection. This method is based on the reaction of carvedilol enantiomers with (-)-menthyl chloroformate (MCF) after extraction by the SBSE method to produce diastereomeric derivatives. The separation was achieved by use of a C18 analytical column and the influence of mobile phase composition on the enantioseparation of carvedilol was studied. The applicability of two sorptive phases, poly(methyl methacrylate/ethyleneglycol dimethacrylate) (PA-EG) and polydimethylsiloxane, were tested for extraction of carvedilol enantiomers from aqueous samples. The obtained results showed excellent linear dynamic ranges and precisions for each of them. The least limit of detection for (S)- and (R)-carvedilol obtained 8 and 11 µg L(-1), respectively, using the PA-EG sorptive phase. Inter- and intra-mean recoveries were also satisfactory, ranging from 98 to 103%, with coefficient of variation in the range of 1-5% at three fortified levels using a PA-EG coated stir bar. The proposed SBSE (PA-EG)-MCF derivatization-HPLC-UV method was successfully applied to enantioselective analysis of carvedilol in water and pharmaceutical dosages, confirming the application of this method. © The Author 2015. Published by Oxford University Press. All rights reserved. For Permissions, please email: journals.permissions@oup.com.

Removal of copper(II) from some environmental samples by sorptive-flotation using powdered marble wastes as sorbents and oleic acid as surfactant.

Science.gov (United States)

Ghazy, S E; Samra, S E; Mahdy, A F M; El-Morsy, S M

2004-11-01

A simple and economic experimental sorptive -flotation procedure is presented for the removal of copper(II) species from aqueous solutions. It is based on using powdered marble wastes (PMW), which are widespread and inexpensive and may represent an environmental problem, as the effective inorganic sorbent and oleic (HOL) as the surfactant. The main parameters (i.e. initial solution pH, sorbent, surfactant and copper concentrations, stirring times, ionic strength, temperature and the presence of foreign ions) influencing the flotation of PMW and /or Cu(II) were examined. Nearly, 100% of PMW and Cu(II) were removed from aqueous solutions at pH7 after stirring for 10 min and at room temperature, (approximately 25 degrees C). The procedure was successfully applied to recover Cu(II) spiked to some natural water samples. A mechanism for sorption and flotation is suggested.

Sol-gel-graphene-based fabric-phase sorptive extraction for cow and human breast milk sample cleanup for screening bisphenol A and residual dental restorative material before analysis by HPLC with diode array detection.

Science.gov (United States)

Samanidou, Victoria; Filippou, Olga; Marinou, Eirini; Kabir, Abuzar; Furton, Kenneth G

2017-06-01

Fabric-phase sorptive extraction has already been recognized as a simple and green alternative to the conventional sorbent-based sorptive microextraction techniques, using hybrid organic-inorganic sorbent coatings chemically bonded to a flexible fabric surface. Herein, we have investigated the synergistic combination of the advanced material properties offered by sol-gel graphene sorbent and the simplicity of Fabric phase sorptive extraction approach in selectively extracting bisphenol A and residual monomers including bisphenol A glycerolatedimethacrylate, urethane dimethacrylate, and triethylene glycol dimethacrylate derived dental restorative materials from cow and human breast milk samples. Different coatings were evaluated. Final method development employed sol-gel graphene coated media. The main experimental parameters influencing extraction of the compounds, such as sorbent chemistry used, sample loading conditions, elution solvent, sorption stirring time, elution time, impact of protein precipitation, amount of sample, and matrix effect, were investigated and optimized. Absolute recovery values from standard solutions were 50% for bisphenol A, 78% for T triethylene glycol dimethacrylate, 110% for urethane dimethacrylate, and 103% for bisphenol A glycerolatedimethacrylate, while respective absolute recovery values from milk were 30, 52, 104, and 42%. Method validation was performed according to European Decision 657/2002/EC in terms of selectivity, sensitivity, linearity, accuracy, and precision. © 2017 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

Preparation of a polymeric ionic liquid-based adsorbent for stir cake sorptive extraction of preservatives in orange juices and tea drinks

International Nuclear Information System (INIS)

Chen, Lei; Huang, Xiaojia

2016-01-01

In this study, a new polymeric ionic liquid-based adsorbent was prepared and used as the extraction medium of stir cake sorptive extraction (SCSE) of three organic acid preservatives, namely, p-hydroxybenzoic acid, sorbic acid and cinnamic acid. The adsorbent was synthesized by the copolymerization of 1-ally-3-vinylimidazolium chloride (AV) and divinylbenzene (DVB) in the presence of a porogen solvent containing 1-propanol and 1,4-butanediol. The effect of the content of monomer and the porogen solvent in the polymerization mixture on the extraction performance was investigated thoroughly. The adsorbent was characterized by infrared spectroscopy, elemental analysis, scanning electron microscopy and mercury intrusion porosimetry. To obtain the optimal extraction conditions of SCSE/AVDVB for target analytes, key parameters including desorption solvent, adsorption and desorption time, ionic strength and pH value in sample matrix were studied in detail. The results showed that under the optimized conditions, the SCSE/AVDVB could extract the preservatives effectively through multiply interactions. At the same time, a simple and sensitive method by combining SCSE/AVDVB and high-performance liquid chromatography with diode array detection was developed for the simultaneous analysis of the target preservatives in orange juices and tea drinks. Low limits of detection (S/N = 3) and quantification limits (S/N = 10) of the proposed method for the target analytes were achieved within the range of 0.012–0.23 μg/L and 0.039–0.42 μg/L, respectively. The precision of the proposed method was evaluated in terms of intra- and inter-assay variability calculated as relative standard deviation (RSD), and it was found that the values were all below 10%. Finally, the proposed method was used to detect preservatives in different orange juice and tea drink samples successfully. The recoveries were in the range of 71.9–116%, and the RSDs were below 10% in the all cases

Preparation of a polymeric ionic liquid-based adsorbent for stir cake sorptive extraction of preservatives in orange juices and tea drinks

Energy Technology Data Exchange (ETDEWEB)

Chen, Lei; Huang, Xiaojia, E-mail: hxj@xmu.edu.cn

2016-04-15

In this study, a new polymeric ionic liquid-based adsorbent was prepared and used as the extraction medium of stir cake sorptive extraction (SCSE) of three organic acid preservatives, namely, p-hydroxybenzoic acid, sorbic acid and cinnamic acid. The adsorbent was synthesized by the copolymerization of 1-ally-3-vinylimidazolium chloride (AV) and divinylbenzene (DVB) in the presence of a porogen solvent containing 1-propanol and 1,4-butanediol. The effect of the content of monomer and the porogen solvent in the polymerization mixture on the extraction performance was investigated thoroughly. The adsorbent was characterized by infrared spectroscopy, elemental analysis, scanning electron microscopy and mercury intrusion porosimetry. To obtain the optimal extraction conditions of SCSE/AVDVB for target analytes, key parameters including desorption solvent, adsorption and desorption time, ionic strength and pH value in sample matrix were studied in detail. The results showed that under the optimized conditions, the SCSE/AVDVB could extract the preservatives effectively through multiply interactions. At the same time, a simple and sensitive method by combining SCSE/AVDVB and high-performance liquid chromatography with diode array detection was developed for the simultaneous analysis of the target preservatives in orange juices and tea drinks. Low limits of detection (S/N = 3) and quantification limits (S/N = 10) of the proposed method for the target analytes were achieved within the range of 0.012–0.23 μg/L and 0.039–0.42 μg/L, respectively. The precision of the proposed method was evaluated in terms of intra- and inter-assay variability calculated as relative standard deviation (RSD), and it was found that the values were all below 10%. Finally, the proposed method was used to detect preservatives in different orange juice and tea drink samples successfully. The recoveries were in the range of 71.9–116%, and the RSDs were below 10% in the all cases

Sorptive thin film microextraction followed by direct solid state spectrofluorimetry: A simple, rapid and sensitive method for determination of carvedilol in human plasma.

Science.gov (United States)

Karimi, Shima; Talebpour, Zahra; Adib, Noushin

2016-06-14

A poly acrylate-ethylene glycol (PA-EG) thin film is introduced for the first time as a novel polar sorbent for sorptive extraction method coupled directly to solid-state spectrofluorimetry without the necessity of a desorption step. The structure, polarity, fluorescence property and extraction performance of the developed thin film were investigated systematically. Carvedilol was used as the model analyte to evaluate the proposed method. The entire procedure involved one-step extraction of carvedilol from plasma using PA-EG thin film sorptive phase without protein precipitation. Extraction variables were studied in order to establish the best experimental conditions. Optimum extraction conditions were the followings: stirring speed of 1000 rpm, pH of 6.8, extraction temperature of 60 °C, and extraction time of 60 min. Under optimal conditions, extraction of carvedilol was carried out in spiked human plasma; and the linear range of calibration curve was 15-300 ng mL(-1) with regression coefficient of 0.998. Limit of detection (LOD) for the method was 4.5 ng mL(-1). The intra- and inter-day accuracy and precision of the proposed method were evaluated in plasma sample spiked with three concentration levels of carvedilol; yielding a recovery of 91-112% and relative standard deviation of less than 8%, respectively. The established procedure was successfully applied for quantification of carvedilol in plasma sample of a volunteer patient. The developed PA-EG thin film sorptive phase followed by solid-state spectrofluorimetric method provides a simple, rapid and sensitive approach for the analysis of carvedilol in human plasma. Copyright © 2016 Elsevier B.V. All rights reserved.

Solar sorptive cooling. Technologies, user requirements, practical experience, future prospects

Energy Technology Data Exchange (ETDEWEB)

Treffinger, P. [DLR Deutsches Zentrum fuer Luft- und Raumfahrt e.V., Hardthausen (Germany); Hertlein, H.P. [eds.] [Forschungsverbund Sonnenenergie, Koeln (Germany)

1998-09-01

Sorptive cooling techniques permit the use of low-temperature solar heat, i.e. a renewable energy of low cost and world-wide availability. The Forschungsverbund Sonnenenergie intends to develop solar sorptive cooling technologies to the prototype stage and, in cooperation with the solar industry and its end users, to promote practical application in air conditioning of buildings and cold storage of food. The workshop presents an outline of the state of development of solar sorptive cooling from the view of users and developers. Exemplary solar cooling systems are described, and the potential of open and closed sorptive processes is assessed. Future central activities will be defined in an intensive discussion between planners, producers, users and developers. [German] Der Einsatz von Sorptionstechniken zur Kaelteerzeugung erlaubt es, als treibende Solarenergie Niedertemperatur-Solarwaerme einzusetzen, also eine regenerative Energie mit sehr geringen Kosten und weltweiter Verfuegbarkeit. Der Forschungsverbund Sonnenenergie hat sich als Aufgabe gestellt, die Techniken der solaren Sorptionskuehlung bis zum Prototyp zu entwickeln und mit Industrie und Nutzern die praktische Anwendung voranzubringen. Die Anwendungsfelder sind die Klimatisierung von Gebaeuden und die Kaltlagerung von Lebensmitteln. Der Workshop gibt einen Ueberblick zum Entwicklungsstand der solaren Sorptionskuehlung aus der Sicht der Anwender und Entwickler. Bereits ausgefuehrte Beispiele zur solaren Kuehlung werden vorgestellt und das Potential geschlossener und offener Sorptionsverfahren angegeben. In intensiver Diskussion zwischen Planern, Herstellern, Nutzern und Entwicklern sollen kuenftige Arbeitsschwerpunkte herausgearbeitet werden. (orig.)

Characterization of the aroma profile of Madeira wine by sorptive extraction techniques.

Science.gov (United States)

Alves, R F; Nascimento, A M D; Nogueira, J M F

2005-08-01

The characterization of the aroma profile of 33 samples of Madeira wine from five monovarieties (Sercial, Verdelho, Boal, Malvasia and Tinta Negra Mole) having different type and categories is presented, using solid phase microextraction and stir bar sorptive extraction techniques (SPME and SBSE) followed by capillary gas chromatography and mass spectrometry detection (GC-MS). Headspace SPME/GC-MS provided effectiveness to identify the major constituents of the aroma profile of Madeira wine, where no remarkable differences occur among the samples studied. The volatile compounds are mainly constituted by ethyl octanoate (11.3-256.9μgL -1 ), ethyl decanoate (21.5-210.5μgL -1 ), ethyl decenoate (0.1-112.8μgL -1 ), diethyl succinate (0.9-65.6μgL -1 ), ethyl dodecanoate (1.2-6.5μgL -1 ), ethyl nonanoate (0.6-5.2μgL -1 ), ethyl hexanoate (0.2-3.7μgL -1 ) and isoamyl octanoate (0-2.2μgL -1 ). C 13 norisoprenoids such as vitispirane (0.9-7.0μgL -1 ) and 1,1,6-trimethyl 1,2-dihydro naphthalene (0.7-12.5μgL -1 ), as well as phenyl ethanol (0-8.1μgL -1 ), were also found in Madeira wine samples. The powerful capabilities of SBSE followed thermal desorption and GC-MS analysis allowed higher ability for profiling traces and ultra traces of compounds in Madeira wine samples, including esters (80.7-89.7%), carboxylic acids (1.6-4.2%), alcohols (3.5-8.2%), aldehydes (0.9-3.7%), pyrans (0.2-1.7%), lactones (sensorial threshold limits. Excellent correlation between Madeira wine ageing and the abundance of cis-oak lactone was attained showing to be an important chemical descriptor to characterize reserves and Vintages as well as a contributor to wine flavour. The differentiation between reserves, dry/medium dry and sweet/medium sweet young wines could be well established by means of chemometric analysis, using particular aroma compounds such as diethyl succinate, cis-oak lactone and ethyl octanoate as discriminating variables.

Polytetrafluoroethylene-jacketed stirrer modified with graphene oxide and polydopamine for the efficient extraction of polycyclic aromatic hydrocarbons.

Science.gov (United States)

Zhang, Zinxin; Mwadini, Mwadini Ahmada; Chen, Zilin

2016-10-01

Steel stirrers jacketed with polytetrafluoroethylene can be regarded as an ideal substrate for stirrer bar sorptive extraction. However, it is still a great challenge to immobilize graphene onto a polytetrafluoroethylene stirrer due to the high chemical resistance of the surface of a polytetrafluoroethylene stirrer. We describe here a method to modify the surface of polytetrafluoroethylene stirrers with graphene. In this work, graphene was used as the sorbent due to its excellent adsorption capability for aromatic compounds, such as polycyclic aromatic compounds. Graphene was successfully immobilized onto polytetrafluoroethylene-stirrer by a bio-inspired polydopamine functionalization method. The graphene-modified polytetrafluoroethylene-stirrer shows good stability and tolerance to stirring, ultrasonication, strong acidic and basic solutions, and to organic solvents. The multilayer coating was characterized by scanning electronic microscopy and Fourier transform infrared spectroscopy. After the optimization of some experimental conditions, the graphene-modified polytetrafluoroethylene stirrer was used for the stirrer bar sorptive extraction of polycyclic aromatic hydrocarbons, in which the binding between the polycyclic aromatic hydrocarbons and the graphene layer was mainly based on π-π stacking and hydrophobic interactions. The graphene-modified polytetrafluoroethylene-stirrer-based stirrer bar sorptive extraction and high-performance liquid chromatography method was developed for the determination of polycyclic aromatic hydrocarbons with great extraction efficiency, with enrichment factors from 18 to 62. The method has low limits of detection of 1-5 pg/mL, wide linear range (5-100 and 10-200 pg/mL), good linearity (R ≥ 0.9957) and good reproducibility (RSD ≤ 6.45%). The proposed method has been applied to determine polycyclic aromatic hydrocarbons in real dust samples. Good recoveries were obtained, ranging from 88.53 to 109.43%. © 2016 WILEY-VCH Verlag

A molecular imprint-coated stirrer bar for selective extraction of caffeine, theobromine and theophylline

International Nuclear Information System (INIS)

Zhu, Quanfei; Ma, Chao; Chen, Huaixia; Wu, Yaqi; Huang, Jianlin

2014-01-01

We have prepared a novel caffeine imprinted polymer on a stir bar that can be used for selective extraction of caffeine, theobromine and theophylline from beverages. The polymerization time and quantities of reagents (template, cross-linker, porogenic solvent) were optimized. The morphology of the molecularly imprinted polymer-coating was studied by scanning electron microscopy and Fourier transform IR spectroscopy. A rapid and sensitive method was worked out for the extraction of caffeine, theobromine and theophylline from beverages by using the molecularly imprinted stir bar followed by HPLC analysis. The effects of extraction solvent, stirring speed, desorption solvent, adsorption and desorption time were optimized. The method displays a linear response in the 5–150 μg L −1 caffeine concentration range, with a correlation coefficient of >0.9904. The recoveries for three analytes in tea, carbonated and functional beverages were 91–108 %, 90–110 % and 93–109 %, with relative standard deviations ranging from 3.6–5.7 %, 3.5–7.9 % and 3.2–7.9 %, respectively. (author)

Quantitative analysis of fragrance in selectable one dimensional or two dimensional gas chromatography-mass spectrometry with simultaneous detection of multiple detectors in single injection.

Science.gov (United States)

Tan, Hui Peng; Wan, Tow Shi; Min, Christina Liew Shu; Osborne, Murray; Ng, Khim Hui

2014-03-14

A selectable one-dimensional ((1)D) or two-dimensional ((2)D) gas chromatography-mass spectrometry (GC-MS) system coupled with flame ionization detector (FID) and olfactory detection port (ODP) was employed in this study to analyze perfume oil and fragrance in shower gel. A split/splitless (SSL) injector and a programmable temperature vaporization (PTV) injector are connected via a 2-way splitter of capillary flow technology (CFT) in this selectable (1)D/(2)D GC-MS/FID/ODP system to facilitate liquid sample injections and thermal desorption (TD) for stir bar sorptive extraction (SBSE) technique, respectively. The dual-linked injectors set-up enable the use of two different injector ports (one at a time) in single sequence run without having to relocate the (1)D capillary column from one inlet to another. Target analytes were separated in (1)D GC-MS/FID/ODP and followed by further separation of co-elution mixture from (1)D in (2)D GC-MS/FID/ODP in single injection without any instrumental reconfiguration. A (1)D/(2)D quantitative analysis method was developed and validated for its repeatability - tR; calculated linear retention indices (LRI); response ratio in both MS and FID signal, limit of detection (LOD), limit of quantitation (LOQ), as well as linearity over a concentration range. The method was successfully applied in quantitative analysis of perfume solution at different concentration level (RSD≤0.01%, n=5) and shower gel spiked with perfume at different dosages (RSD≤0.04%, n=5) with good recovery (96-103% for SSL injection; 94-107% for stir bar sorptive extraction-thermal desorption (SBSE-TD). Copyright © 2014 Elsevier B.V. All rights reserved.

Optimum Installation of Sorptive Building Materials Using Contribution Ratio of Pollution Source for Improvement of Indoor Air Quality.

Science.gov (United States)

Park, Seonghyun; Seo, Janghoo

2016-04-01

Reinforcing the insulation and airtightness of buildings and the use of building materials containing new chemical substances have caused indoor air quality problems. Use of sorptive building materials along with removal of pollutants, constant ventilation, bake-out, etc. are gaining attention in Korea and Japan as methods for improving such indoor air quality problems. On the other hand, sorptive building materials are considered a passive method of reducing the concentration of pollutants, and their application should be reviewed in the early stages. Thus, in this research, activated carbon was prepared as a sorptive building material. Then, computational fluid dynamics (CFD) was conducted, and a method for optimal installation of sorptive building materials was derived according to the indoor environment using the contribution ratio of pollution source (CRP) index. The results show that a method for optimal installation of sorptive building materials can be derived by predicting the contribution ratio of pollutant sources according to the CRP index.

Análise dos produtos de degradação do esfenvalerato por SBSE/CLAE-UV/DAD utilizando planejamento fatorial fracionário

Directory of Open Access Journals (Sweden)

Renata Colombo

2014-06-01

Full Text Available A simple procedure based on stir bar sorptive extraction and high-performance liquid chromatography-ultraviolet/photodiode array detection (SBSE/LC-UV/PAD to determine intermediates and by-products of esfenvalerate is described. The influence of organic modifier, ionic strength, extraction time, temperature and pH were simultaneously evaluated by using a factorial experimental design. The utilization of different organic solvents and desorption times were also investigated to establish the optimal conditions for SBSE liquid desorption. Among the ten different peaks (intermediates and by-products detected after degradation of esfenvalerate, eight (including 3-phenoxybenzoic acid and 3-phenoxybenzaldehyde were successfully extracted by SBSE under the optimized conditions.

Examination of Some Commercial Sorptive Organobentonites

OpenAIRE

ÖNAL, Müşerref

2014-01-01

For controlling organophilic partition nanophase (OPN) formation in some commercial sorptive organobentonites (OBs), 4 sample were selected randomly and examined by X-ray diffraction (XRD), Fourier transform infrared (FTIR) spectroscopy, differential thermal analysis (DTA), thermal gravimetric analysis (TGA), element analysis (EA), and nitrogen adsorption/desorption (N2-AD) techniques. Since the d(001) values of the OB samples are between 1.94 and 3.36 nm, the pseudotrilayer or paraff...

Acoustics of multiscale sorptive porous materials

Science.gov (United States)

Venegas, R.; Boutin, C.; Umnova, O.

2017-08-01

This paper investigates sound propagation in multiscale rigid-frame porous materials that support mass transfer processes, such as sorption and different types of diffusion, in addition to the usual visco-thermo-inertial interactions. The two-scale asymptotic method of homogenization for periodic media is successively used to derive the macroscopic equations describing sound propagation through the material. This allowed us to conclude that the macroscopic mass balance is significantly modified by sorption, inter-scale (micro- to/from nanopore scales) mass diffusion, and inter-scale (pore to/from micro- and nanopore scales) pressure diffusion. This modification is accounted for by the dynamic compressibility of the effective saturating fluid that presents atypical properties that lead to slower speed of sound and higher sound attenuation, particularly at low frequencies. In contrast, it is shown that the physical processes occurring at the micro-nano-scale do not affect the macroscopic fluid flow through the material. The developed theory is exemplified by introducing an analytical model for multiscale sorptive granular materials, which is experimentally validated by comparing its predictions with acoustic measurements on granular activated carbons. Furthermore, we provide empirical evidence supporting an alternative method for measuring sorption and mass diffusion properties of multiscale sorptive materials using sound waves.

In-syringe-stirring: A novel approach for magnetic stirring-assisted dispersive liquid–liquid microextraction

International Nuclear Information System (INIS)

Horstkotte, Burkhard; Suárez, Ruth; Solich, Petr; Cerdà, Víctor

2013-01-01

Graphical abstract: -- Highlights: •We propose a new automatic magnetic stirring assisted dispersive liquid–liquid microextraction. •It allows the extraction of aluminum from seawater and freshwater samples within less than 4 min. •The method was applicable to the natural samples. -- Abstract: For the first time, the use of a magnetic stirrer within the syringe of an automated syringe pump and the resulting possible analytical applications are described. A simple instrumentation following roughly the one from sequential injection analyzer systems is used in combination with an adaptor, which is placed onto the barrel of a glass syringe. Swirling around the longitudinal axis of the syringe and holding two strong neodymium magnets, it causes a rotating magnetic field and serves as driver for a magnetic stirring bar placed inside of the syringe. In a first study it was shown that this approach leads to a sealed but also automatically adaptable reaction vessel, the syringe, in which rapid and homogeneous mixing of sample with the required reagents within short time can be carried out. In a second study in-a-syringe magnetic stirring-assisted dispersive liquid–liquid microextraction (MSA-DLLME) was demonstrated by the application of the analyzer system to fluorimetric determination of aluminum in seawater samples using lumogallion. A linear working range up to 1.1 μmol L −1 and a limit of detection of 6.1 nmol L −1 were found. An average recovery of 106.0% was achieved for coastal seawaters with a reproducibility of 4.4%. The procedure lasted 210 s including syringe cleaning and only 150 μL of hexanol and 4.1 mL of sample were required

Comparative study of cerium (IV) sorptive properties in zeolite Y and clinoptilolite

International Nuclear Information System (INIS)

Garcia D, O.C.

1993-01-01

Among the problems of protecting the environment from radioactive contamination, the reduction of radioactive releases by improving monitoring, decontamination, and burial methods is one of the most important. Natural sorbents are gaining increased significance for solving this problem. Among these, zeolites deserve special attention since they have sufficient sorptive capacity, are highly radiation resistant, are widely distributed exhibit selectivity and are inexpensive. In the present work we determine experimentally the sorptive characteristics of clinoptilolite as a function of various factors and demonstrate that clinoptilolite is capable of sorbing Ce(IV) over a wide pH range. (Author)

Determination of Endocrine Disrupting Compounds in surface waters by means of chromatographic techniques coupled to mass spectrometry

Directory of Open Access Journals (Sweden)

M. Di Carro

2011-01-01

Full Text Available Two analytical methods were developed to study five endocrine disrupting compounds (4-n-nonylphenol, bisphenol A, estrone, 17β-estradiol and 17α-ethinylestradiol in waters. One method includes a fast liquid chromatography-electrospray ionization-tandem mass spectrometry (LC-ESI-MS-MS analysis, while the second comprise a Stir Bar Sorptive Extraction (SBSE followed by a headspace derivatization and gaschromatography-mass spectrometry (GC-MS analysis. Passive samplers POCIS (Polar Organic Chemical Integrative Samplers were used as sampling and preconcentration steps in order to reach the very low levels of the analytes in environmental waters. Both methods were then applied to the determination of the analytes in different water samples.

Novel strategies for sample preparation in forensic toxicology.

Science.gov (United States)

Samanidou, Victoria; Kovatsi, Leda; Fragou, Domniki; Rentifis, Konstantinos

2011-09-01

This paper provides a review of novel strategies for sample preparation in forensic toxicology. The review initially outlines the principle of each technique, followed by sections addressing each class of abused drugs separately. The novel strategies currently reviewed focus on the preparation of various biological samples for the subsequent determination of opiates, benzodiazepines, amphetamines, cocaine, hallucinogens, tricyclic antidepressants, antipsychotics and cannabinoids. According to our experience, these analytes are the most frequently responsible for intoxications in Greece. The applications of techniques such as disposable pipette extraction, microextraction by packed sorbent, matrix solid-phase dispersion, solid-phase microextraction, polymer monolith microextraction, stir bar sorptive extraction and others, which are rapidly gaining acceptance in the field of toxicology, are currently reviewed.

Ionic liquids intercalated in montmorillonite as the sorptive phase for the extraction of low-polarity organic compounds from water by rotating-disk sorptive extraction

Energy Technology Data Exchange (ETDEWEB)

Fiscal-Ladino, Jhon A.; Obando-Ceballos, Mónica; Rosero-Moreano, Milton [Grupo de Investigación en Cromatografía y Técnicas Afines GICTA, Departamento de Química, Facultad de Ciencias Exactas y Naturales, Universidad de Caldas, Calle 65 No. 26-10, Manizales (Colombia); Montaño, Diego F.; Cardona, Wilson; Giraldo, Luis F. [Química de Plantas Colombianas, Instituto de Química, Escuela de Ciencias Exactas y Naturales, Universidad de Antioquia, Calle 70 No. 52-21, A.A, 1226, Medellín (Colombia); Richter, Pablo, E-mail: prichter@ciq.uchile.cl [Departamento de Química Inorgánica y Analítica, Facultad de Ciencias Químicas y Farmacéuticas, Universidad de Chile, Casilla 233, Santiago (Chile)

2017-02-08

Montmorillonite (MMT) clays were modified by the intercalation into their galleries of ionic liquids (IL) based on imidazolium quaternary ammonium salts. This new eco-materials exhibited good features for use as a sorptive phase in the extraction of low-polarity analytes from aqueous samples. Spectroscopic analyses of the modified clays were conducted and revealed an increase in the basal spacing and a shifting of the reflection plane towards lower values as a consequence of the effective intercalation of organic cations into the MMT structure. The novel sorbent developed herein was assayed as the sorptive phase in rotating-disk sorptive extraction (RDSE), using polychlorinated biphenyls (PCBs), representative of low-polarity pollutants, as model analytes. The final determination was made by gas chromatography with electron capture detection. Among the synthetized sorptive phases, the selected system for analytical purposes consisted of MMT modified with the 1-hexadecyl-3-methylimidazolium bromide (HDMIM-Br) IL. Satisfactory analytical features were achieved using a sample volume of 5 mL: the relative recoveries from a wastewater sample were higher than 80%, the detection limits were between 3 ng L{sup −1} and 43 ng L{sup −1}, the precision (within-run precision) expressed as the relative standard deviation ranged from 2% to 24%, and the enrichment factors ranged between 18 and 28. Using RDSE, the extraction efficiency achieved for the selected MMT-HDMIM-Br phase was compared with other commercial solid phases/supports, such as polypropylene, polypropylene with 1-octanol (as a supported liquid membrane), octadecyl (C18) and octyl (C8), and showed the highest response for all the studied analytes. Under the optimized extraction conditions, this new device was applied in the analysis of the influent of a wastewater treatment plant in Santiago (Chile), demonstrating its applicability through the good recoveries and precision achieved with real samples

HEURISTIC OPTIMIZATION AND ALGORITHM TUNING APPLIED TO SORPTIVE BARRIER DESIGN

Science.gov (United States)

While heuristic optimization is applied in environmental applications, ad-hoc algorithm configuration is typical. We use a multi-layer sorptive barrier design problem as a benchmark for an algorithm-tuning procedure, as applied to three heuristics (genetic algorithms, simulated ...

Estimation of hydraulic conductivities of Yucca Mountain tuffs from sorptivity and water retention measurements

International Nuclear Information System (INIS)

Zimmerman, R.W.; Bodvarsson, G.S.

1995-06-01

The hydraulic conductivity functions of the matrix rocks at Yucca Mountain, Nevada, are among the most important data needed as input for the site-scale hydrological model of the unsaturated zone. The difficult and time-consuming nature of hydraulic conductivity measurements renders it infeasible to directly measure this property on large numbers of cores. Water retention and sorptivity measurements, however, can be made relatively rapidly. The sorptivity is, in principle, a unique functional of the conductivity and water retention functions. It therefore should be possible to invert sorptivity and water retention measurements in order to estimate the conductivity; the porosity is the only other parameter that is required for this inversion. In this report two methods of carrying out this inversion are presented, and are tested against a limited data set that has been collected by Flint et al. at the USGS on a set of Yucca Mountain tuffs. The absolute permeability is usually predicted by both methods to within an average error of about 0.5 - 1.0 orders of magnitude. The discrepancy appears to be due to the fact that the water retention curves have only been measured during drainage, whereas the imbibition water retention curve is the one that is relevant to sorptivity measurements. Although the inversion methods also yield predictions of the relative permeability function, there are yet no unsaturated hydraulic conductivity data against which to test these predictions

Innovative sampling and extraction methods for the determination of nonsteroidal anti-inflammatory drugs in water.

Science.gov (United States)

Tanwar, Shivani; Di Carro, Marina; Magi, Emanuele

2015-03-15

Two different innovative approaches were used for the determination of nonsteroidal anti-inflammatory drugs (NSAIDs) in water: stir bar sorptive extraction (SBSE) and passive sampling, followed by electrospray ionization liquid chromatography-tandem mass spectrometry. SBSE was developed by comparing EG-Silicone and PDMS stir bars and optimizing main parameters to attain high preconcentration. Quantitative analysis was carried out by mass spectrometry in negative ionization mode and multiple reaction monitoring. The SBSE-LC-MS/MS method provided satisfactory figures of merit with LOD (7.5-71 ng L(-1)) and LOQ (22.5-213 ng L(-1)). The developed method was successfully applied to real samples collected from river water and wastewater effluents. The obtained results showed the presence of all analytes at trace levels, in a wide range of concentrations. The passive sampling approach was carried out by using Polar Organic Chemical Integrative Sampler (POCIS); samplers were deployed for 15 days in river and tap water, allowing to detect analytes at ultra-trace levels. Time-Weighted Average concentration of NSAIDs in river water was estimated in the range 0.33-0.46 ng L(-1), using the sampling rates previously obtained by means of a simple calibration system. Copyright © 2014 Elsevier B.V. All rights reserved.

Determination of sulfonamides in butter samples by ionic liquid magnetic bar liquid-phase microextraction high-performance liquid chromatography.

Science.gov (United States)

Wu, Lijie; Song, Ying; Hu, Mingzhu; Xu, Xu; Zhang, Hanqi; Yu, Aimin; Ma, Qiang; Wang, Ziming

2015-01-01

A novel, simple, and environmentally friendly pretreatment method, ionic liquid magnetic bar liquid-phase microextraction, was developed for the determination of sulfonamides in butter samples by high-performance liquid chromatography. The ionic liquid magnetic bar was prepared by inserting a stainless steel wire into the hollow of a hollow fiber and immobilizing ionic liquid in the micropores of the hollow fiber. In the extraction process, the ionic liquid magnetic bars were used to stir the mixture of sample and extraction solvent and enrich the sulfonamides in the mixture. After extraction, the analyte-adsorbed ionic liquid magnetic bars were readily isolated with a magnet from the extraction system. It is notable that the present method was environmentally friendly since water and only several microliters of ionic liquid were used in the whole extraction process. Several parameters affecting the extraction efficiency were investigated and optimized, including the type of ionic liquid, sample-to-extraction solvent ratio, the number of ionic liquid magnetic bars, extraction temperature, extraction time, salt concentration, stirring speed, pH of the extraction solvent, and desorption conditions. The recoveries were in the range of 73.25-103.85 % and the relative standard deviations were lower than 6.84 %. The experiment results indicated that the present method was effective for the extraction of sulfonamides in high-fat content samples.

Ultrasonic Stir Welding

Science.gov (United States)

Nabors, Sammy

2015-01-01

NASA Marshall Space Flight Center (MSFC) developed Ultrasonic Stir Welding (USW) to join large pieces of very high-strength metals such as titanium and Inconel. USW, a solid-state weld process, improves current thermal stir welding processes by adding high-power ultrasonic (HPU) energy at 20 kHz frequency. The addition of ultrasonic energy significantly reduces axial, frictional, and shear forces; increases travel rates; and reduces wear on the stir rod, which results in extended stir rod life. The USW process decouples the heating, stirring, and forging elements found in the friction stir welding process allowing for independent control of each process element and, ultimately, greater process control and repeatability. Because of the independent control of USW process elements, closed-loop temperature control can be integrated into the system so that a constant weld nugget temperature can be maintained during welding.

Permeable sorptive walls for treatment of hydrophobic organic contaminant plumes in groundwater

International Nuclear Information System (INIS)

Grathwohl, P.; Peschik, G.

1997-01-01

Highly hydrophobic contaminants are easily adsorbed from aqueous solutions. Since for many of these compounds sorption increases with increasing organic carbon content natural materials such as bituminous shales and coals may be used in permeable sorptive walls. This, however, only applies if sorption is at equilibrium, which may not always be the case in groundwater treatment using a funnel-and-gate system. In contrast to the natural solids, granular activated carbons (GACs) have very high sorption capacities and reasonably fast sorption kinetics. The laboratory results show that application of GACs (e.g. F100) is economically feasible for in situ removal of polycyclic aromatic hydrocarbons (PAH) from groundwater at a former manufactured gas plant site (MGP). For less sorbing compounds (such as benzene, toluene, xylenes) a combination of adsorption and biodegradation is necessary (i.e. sorptive + reactive treatment)

Mechano-sorptive creep of Portuguese pinewood chemically modified

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Barroso Lopes Duarte

2014-03-01

Full Text Available The effect of chemical modification on mechano-sorptive creep in bending was studied by experimental work. Stakes with 20 × 20 × 400 mm RTL of Portuguese wood species (Pinus pinaster Aiton modified with 1,3-dimethylol-4,5- dihydroxyethyleneurea (DMDHEU, m-methylated melamine resin (MMF, tetraethoxysilane (TEOS and amid wax (WA were measured under asymmetric moistening conditions over a period of 42 days (app. 1000 hours with stress level (SL of 12 MPa, according to ENV 1156.

Natural sorptive barriers in Yucca Mountain, Nevada, for long-term isolation of high-level waste

International Nuclear Information System (INIS)

Bish, D.L.; Vaniman, D.T.; Rundberg, R.S.; Wolfsberg, K.; Daniels, W.R.; Broxton, D.E.

1984-01-01

There are several sorptive phases occurring naturally in the silicic tuffs at Yucca Mountain, Nevada, that can aid in the long-term isolation of high-level wastes. These phases include hydrated volcanic glasses, smectites and zeolites. Los Alamos has a continuing programme to investigate the mineralogy and stratigraphy of the tuffs at Yucca Mountain. In addition, extensive data have been obtained on the sorptive behaviour of technetium, strontium, caesium, barium, cerium, europium, uranium, neptunium, plutonium and americium on the minerals in tuffs. Sorption of elements by ion-exchange processes is high in tuffs containing smectite and the zeolites clinoptilolite-heulandite and mordenite. Moreover, sorption correlates with abundances of these minerals. Sorption is not as high for the zeolite analcime and for volcanic glass. Elements that may not sorb by ion exchange, e.g. plutonium, also tend to be sorbed when the zeolite abundance is high, but the correlations are less clearly defined. Because of the correlation between sorptive capacity and mineralogy, an accurate knowledge of mineral distribution and stratigraphy is essential. The distribution of hydrated glasses is stratigraphically controlled, and the glasses occur in narrow unaltered horizons as vitrophyres and as vitric tuff. Although glasses are of minor importance as sorptive phases, they are very reactive and can alter to other minerals if heated in the presence of water. Smectite clays are reversibly expandable and are widespread in tuffs, but their beneficial properties can be modified by prolonged exposure to elevated temperatures. The zeolites clinoptilolite-heulandite and mordenite occur in high concentrations in silicic tuffs, mostly as secondary alterations of non-welded and poorly welded tuffs; their distribution is therefore stratigraphically controlled

Development of Microstructure and Crystallographic Texture in a Double-Sided Friction Stir Welded Microalloyed Steel

Science.gov (United States)

Rahimi, S.; Wynne, B. P.; Baker, T. N.

2017-01-01

The evolution of microstructure and crystallographic texture has been investigated in double-sided friction stir welded microalloyed steel, using electron backscatter diffraction (EBSD). The microstructure analyses show that the center of stirred zone reached a temperature between Ac1 and Ac3 during FSW, resulting in a dual-phase austenitic/ ferritic microstructure. The temperatures in the thermo-mechanically affected zone and the overlapped area between the first and second weld pass did not exceed the Ac1. The shear generated by the rotation probe occurs in austenitic/ferritic phase field where the austenite portion of the microstructure is transformed to a bainitic ferrite, on cooling. Analysis of crystallographic textures with regard to shear flow lines generated by the probe tool shows the dominance of simple shear components across the whole weld. The austenite texture at Ac1 - Ac3 is dominated by the B { {1bar{1}2} }D2 { {11bar{2}} }< 111rangle simple shear texture components. The formation of ultrafine equiaxed ferrite with submicron grain size has been observed in the overlapped area between the first and second weld pass. This is due to continuous dynamic strain-induced recrystallization as a result of simultaneous severe shear deformation and drastic undercooling.

Exotic open-flavor $bc\\bar{q}\\bar{q}$, $bc\\bar{s}\\bar{s}$ and $qc\\bar{q}\\bar{b}$, $sc\\bar{s}\\bar{b}$ tetraquark states

OpenAIRE

Chen, Wei; Steele, T. G.; Zhu, Shi-Lin

2013-01-01

We study the exotic $bc\\bar{q}\\bar{q}$, $bc\\bar{s}\\bar{s}$ and $qc\\bar{q}\\bar{b}$, $sc\\bar{s}\\bar{b}$ systems by constructing the corresponding tetraquark currents with $J^P=0^+$ and $1^+$. After investigating the two-point correlation functions and the spectral densities, we perform QCD sum rule analysis and extract the masses of these open-flavor tetraquark states. Our results indicate that the masses of both the scalar and axial vector tetraquark states are about $7.1-7.2$ GeV for the $bc\\...

An Approach for Measuring the Sorptive Behavior of Odorants Using a Multifunction Thermal Desorber Unit: Preliminary Tests on Reduced Sulfur Compounds

Directory of Open Access Journals (Sweden)

Sang-Woo Joo

2008-03-01

Full Text Available In this study, the sorptive behavior of reduced sulfur compounds (RSC was investigated using a combination of thermal desorber (TD unit and gas chromatography (GC. To examine the sorptive properties of RSC on textile materials, two types of experiments were conducted under experimental conditions favorable for sorptive processes. In all the experiments, gaseous standards of hydrogen sulfide, methanethiol, dimethyl sulfide, and dimethyl disulfide were supplied to initiate the adsorption processes on textile pieces. The textile pieces were then forced to release those adsorbed RSC under a fixed condition. It was found that the extent of adsorption, if evaluated quantitatively, occurred at approximately 1/1000 to 1/100 of the level of RSC standards supplied originally to induce adsorption. It also indicated that RSC adsorption was affected very sensitively by the initial exposure durations to induce RSC adsorption with an exponential decrease in relative recovery (RR values with increasing exposure time. The relative sorptive patterns, when compared between different RSCs, were affected most sensitively by such factors as molecular weight and/or physical contact conditions.

MSVAT-SPACE-STIR and SEMAC-STIR for Reduction of Metallic Artifacts in 3T Head and Neck MRI.

Science.gov (United States)

Hilgenfeld, T; Prager, M; Schwindling, F S; Nittka, M; Rammelsberg, P; Bendszus, M; Heiland, S; Juerchott, A

2018-05-24

The incidence of metallic dental restorations and implants is increasing, and head and neck MR imaging is becoming challenging regarding artifacts. Our aim was to evaluate whether multiple-slab acquisition with view angle tilting gradient based on a sampling perfection with application-optimized contrasts by using different flip angle evolution (MSVAT-SPACE)-STIR and slice-encoding for metal artifact correction (SEMAC)-STIR are beneficial regarding artifact suppression compared with the SPACE-STIR and TSE-STIR in vitro and in vivo. At 3T, 3D artifacts of 2 dental implants, supporting different single crowns, were evaluated. Image quality was evaluated quantitatively (normalized signal-to-noise ratio) and qualitatively (2 reads by 2 blinded radiologists). Feasibility was tested in vivo in 5 volunteers and 5 patients, respectively. Maximum achievable resolution and the normalized signal-to-noise ratio of MSVAT-SPACE-STIR were higher compared with SEMAC-STIR. Performance in terms of artifact correction was dependent on the material composition. For highly paramagnetic materials, SEMAC-STIR was superior to MSVAT-SPACE-STIR (27.8% smaller artifact volume) and TSE-STIR (93.2% less slice distortion). However, MSVAT-SPACE-STIR reduced the artifact size compared with SPACE-STIR by 71.5%. For low-paramagnetic materials, MSVAT-SPACE-STIR performed as well as SEMAC-STIR. Furthermore, MSVAT-SPACE-STIR decreased artifact volume by 69.5% compared with SPACE-STIR. The image quality of all sequences did not differ systematically. In vivo results were comparable with in vitro results. Regarding susceptibility artifacts and acquisition time, MSVAT-SPACE-STIR might be advantageous over SPACE-STIR for high-resolution and isotropic head and neck imaging. Only for materials with high-susceptibility differences to soft tissue, the use of SEMAC-STIR might be beneficial. Within limited acquisition times, SEMAC-STIR cannot exploit its full advantage over TSE-STIR regarding artifact

Nonequilibrium chemical instabilities in continuous flow stirred tank reactors: The effect of stirring

International Nuclear Information System (INIS)

Horsthemke, W.; Hannon, L.

1984-01-01

We present a stochastic model for stirred chemical reactors. In the limiting case of practical interest, i.e., fast stirring, we solve for the characteristic function in steady state and derive expressions for the stationary moments through a perturbation expansion. Moments are explicitly calculated for a generic model of bistable behavior. We find that stirring decreases the area of the bistable region essentially by changing the point of transition from the high reaction rate state to the low reaction rate state. This is in remarkable agreement with the experimental findings of Roux, et al. Our results indicate that stirring should not be considered simply as an ''enhanced diffusion'' process and that nucleation plays only a minor role in transitions between multiple steady states in a continuous flow stirred tank reactor (CSTR)

Stir zone microstructure of commercial purity titanium friction stir welded using pcBN tool

International Nuclear Information System (INIS)

Zhang Yu; Sato, Yutaka S.; Kokawa, Hiroyuki; Park, Seung Hwan C.; Hirano, Satoshi

2008-01-01

In the present study, friction stir welding was applied to commercial purity titanium using a polycrystalline cubic boron nitride tool, and microstructure and hardness in the weld were examined. Additionally, the microstructural evolution during friction stir welding was also discussed. The stir zone consisted of fine equiaxed α grains surrounded by serrate grain boundaries, which were produced through the β → α allotropic transformation during the cooling cycle of friction stir welding. The fine α grains caused higher hardness than that in the base material. A lath-shaped α grain structure containing Ti borides and tool debris was observed in the surface region of the stir zone, whose hardness was the highest in the weld

Early age compressive strength, porosity, and sorptivity of concrete using peat water to produce and cure concrete

Science.gov (United States)

Olivia, Monita; Ismeddiyanto, Wibisono, Gunawan; Sitompul, Iskandar R.

2017-09-01

Construction in peatland has faced scarce water sources for mixing and curing concrete. It is known that peat water has high organic content and low pH that can be harmful to concrete in the environment. In some remote areas in Riau Province, contractors used peat water directly without sufficient treatments to comply with SKSNI requirements of concrete mixing water. This paper presents a study of compressive strength, porosity and sorptivity of Ordinary Portland Cement (OPC) and blended OPC-Palm Oil Fuel Ash (OPC-POFA) concrete. The specimens were mixed using natural water and peat water, then some of them were cured in fresh water and peat water. Six mixtures were investigated using a variation of cement, mixing water and curing water. Tap water is used as control mixing and curing water for all specimens. The compressive strength, porosity and sorptivity were calculated at seven and 28 days. Results indicate that the use of peat water will cause low compressive strength, high porosity and sorptivity for both OPC and OPC-POFA concrete. Using peat water and curing the specimens in tap water could improve the early strength, porosity and sorptivity of OPC concrete; however, it has an adverse effect on OPC-POFA specimens. The properties of early age concrete of both types (OPC and OPC-POFA) using peat water were as good as those with tap water. Therefore, it is suggested that peat water should be considered as mixing and curing water for concrete where tap water resources are scarce. Investigation of its long-term properties, as well as extending the observed age of concrete is recommended before any use of peat water.

Sorptive removal of tetracycline from water by palygorskite

International Nuclear Information System (INIS)

Chang, Po-Hsiang; Li, Zhaohui; Yu, Tsai-Luen; Munkhbayer, Sandagdori; Kuo, Tzu-Hsing; Hung, Yu-Chiao; Jean, Jiin-Shuh; Lin, Kao-Hung

2009-01-01

Extensive use of pharmaceuticals and growth hormone in farm animal and live stocks has resulted in their frequent detection in soils, groundwater, and wastewater. The fate and transport of these compounds are strongly affected by their sorptive behavior to the soil minerals and humic materials. In this research, we conducted the sorption of tetracycline (TC), a common antibiotic, on palygorskite (PFL-1), a fibrous clay mineral of high surface area and high sorptivity towards organic compounds. The results showed that the sorption capacity of TC on PFL-1 was as high as 210 mmol/kg at pH 8.7. The sorption was relatively fast and reached equilibrium in 2 h. Solution pH and ionic strength had significant effects on TC sorption. The sorption of TC by palygorskite is endothermic and the free energy of sorption is in the range of -10 to -30 kJ/mol, suggesting a strong physical sorption. The X-ray diffraction patterns before and after TC sorption revealed no changes in d-spacing and intensity under different pH and initial TC concentrations, indicating that the sorbed TC molecules are on the external surface of the mineral in contrast to intercalation of TC into swelling clays, such as montmorillonite. The small positive value of entropy change suggested that TC molecules are in disordered arrangement on palygorskite surfaces. Surface sorption of TC on PFL-1 is further supported by the derivative of gravimetric analysis and by the calculation of the amount of TC sorption normalized to the surface area. The results suggest that palygorskite could be a good candidate to remove TC from wastewater containing higher amounts of TC.

Weathering products of basic rocks as sorptive materials of natural radionuclides

International Nuclear Information System (INIS)

Omelianenko, B.I.; Niconov, B.S.; Ryzhov, B.I.; Shikina, N.D.

1994-06-01

The principal requirements for employing natural minerals as buffer and backfill material in high-level waste (HLW) repositories are high sorptive properties, low water permeability, relatively high thermal conductivity, and thermostability. The major task of the buffer is to prevent the penetration of radionuclides into groundwater. The authors of this report examined weathered basic rocks from three regions of Russia in consideration as a suitable radioactive waste barrier

Impact of Magnetic Stirring on Stainless Steel Integrity: Effect on Biopharmaceutical Processing.

Science.gov (United States)

Thompson, Christopher; Wilson, Kelly; Kim, Yoen Joo; Xie, Min; Wang, William K; Wendeler, Michaela

2017-11-01

Stainless steel containers are widely used in the pharmaceutical and biopharmaceutical industry for the storage of buffers, process intermediates, and purified drug substance. They are generally held to be corrosion resistant, biocompatible, and nonreactive, although it is well established that trace amounts of metal ions can leach from stainless steel equipment into biopharmaceutical products. We report here that the use of stainless steel containers in conjunction with magnetic stirring bars leads to significantly aggravated metal contamination, consisting of both metal particles and significantly elevated metal ions in solution, the degree of which is several orders of magnitude higher than described for static conditions. Metal particles are analyzed by scanning electron microscopy with electron-dispersive X-ray spectroscopy, and metal content in solution is quantitated at different time points by inductively coupled plasma-mass spectrometry. The concentration of iron, chromium, nickel, and manganese increases with increasing stirring time and speed. We describe the impact of buffer components on the extent of metal particles and ions in solution and illustrate the effect on model proteins. Copyright © 2017 American Pharmacists Association®. Published by Elsevier Inc. All rights reserved.

Pseudo-stir bar hollow fiber solid/liquid phase microextraction combined with anodic stripping voltammetry for determination of lead and cadmium in water samples

Directory of Open Access Journals (Sweden)

Zarrin Es’haghi

2014-11-01

Full Text Available A new procedure is presented for the determination of low concentrations of lead and cadmium in water samples. Ligand assisted pseudo-stir bar hollow fiber solid/liquid phase microextraction using sol–gel sorbent reinforced with carbon nanotubes was combined with differential pulse anodic stripping voltammetry for simultaneous determination of cadmium and lead in tap water, and Darongar river water samples. In the present work, differential pulse anodic stripping voltammetry (DPASV using a hanging mercury drop electrode (HMDE was used in order to determine the ultra trace level of lead and cadmium ions in real samples. This method is based on accumulation of lead and cadmium ions on the electrode using different ligands; Quinolin-8-ol, 5,7-diiodo quinoline-8-ol, 4,5-diphenyl-1H-imidazole-2(3H-one and 2-{[2-(2-Hydroxy-ethylamino-ethylamino]-methyl}-phenol as the complexing agent. The optimized conditions were obtained. The relationship between the peak current versus concentration was linear over the range of 0.05–500 ng mL−1 for Cd (II and Pb (II. The limits of detection for lead and cadmium were 0.015 ng mL−1 and 0.012 ng mL−1, respectively. Under the optimized conditions, the pre-concentration factors are 2440 and 3710 for Cd (II and Pb (II in 5 mL of water sample, respectively.

High-Powered, Ultrasonically Assisted Thermal Stir Welding

Science.gov (United States)

Ding, Robert

2013-01-01

This method is a solid-state weld process capable of joining metallic alloys without melting. The weld workpieces to be joined by thermal stir welding (TSW) are drawn, by heavy forces, between containment plates past the TSW stir tool that then causes joining of the weld workpiece. TSW is similar to friction stir welding (FSW) in that material is heated into a plastic state (not melted) and stirred using a stir rod. The FSW pin tool is an integrated geometrical structure consisting of a large-diameter shoulder, and a smaller-diameter stir pin protruding from the shoulder. When the pin is plunged into a weld workpiece, the shoulder spins on the surface of the weld workpiece, thus inducing frictional heat into the part. The pin stirs the fraying surfaces of the weld joint, thus joining the weld workpiece into one structure. The shoulder and stir pin of the FSW pin tool must rotate together at a desired rotational speed. The induced frictional energy control and stir pin control of the pin tool cannot be de-coupled. The two work as one integrated unit. TSW, on the other hand, de-couples the heating and stirring of FSW, and allows for independent control of each process element. A uniquely designed induction coil heats the weld workpiece to a desired temperature, and once heated, the part moves into a stir rod whose RPM is also independently controlled. As the weld workpiece moves into the stir rod, the piece is positioned, or sandwiched, between upper and lower containment plates. The plate squeezes together, thus compressing the upper and lower surfaces of the weld workpiece. This compressive force, also called consolidation force, consolidates the plastic material within the weld nugget material as it is being stirred by the stir rod. The stir rod is positioned through the center of the top containment plate and protrudes midway through the opposite lower containment plate where it is mechanically captured. The upper and lower containment plates are separated by a

Equilibrium sorptive enrichment on poly(dimethylsiloxane) particles for trace analysis of volatile compounds in gaseous samples

NARCIS (Netherlands)

Baltussen, H.A.; David, F.; Sandra, P.J.F.; Janssen, J.G.M.; Cramers, C.A.M.G.

1999-01-01

A novel approach for sample enrichment, namely, equilibrium sorptive enrichment (ESE), is presented. A packed bed of sorption (or partitioning) material is used to enrich volatiles from gaseous samples. Normally, air sampling is stopped before breakthrough occurs, but this approach is not very

Removal of phosphorus from aqueous solution by Posidonia oceanica fibers using continuous stirring tank reactor

Energy Technology Data Exchange (ETDEWEB)

Wahab, Mohamed Ali, E-mail: waheb_med@yahoo.fr [University of Carthage, Water Research and Technologies Centre (CERTE), Wastewater Treatment and Recycling Laboratory, B.P. 273, 8020 Soliman (Tunisia); Hassine, Rafik Ben [International Environmental Green Technology (IGET) (Tunisia); Jellali, Salah, E-mail: salah.jallali@certe.rnrt.tn [University of Carthage, Water Research and Technologies Centre (CERTE), Wastewater Treatment and Recycling Laboratory, B.P. 273, 8020 Soliman (Tunisia)

2011-05-15

The present study aims to develop a new potentially low-cost, sustainable treatment approach to soluble inorganic phosphorus removal from synthetic solutions and secondary wastewater effluents in which a plant waste (Posidonia oceanica fiber: POF) is used for further agronomic benefit. Dynamic flow tests using a continuous stirred tank reactor (CSTR) were carried out to study the effect of initial concentration of phosphorus, amount of adsorbent, feeding flow rate and anions competition. The experimental results showed that the removal efficiency of phosphorus from synthetic solutions is about 80% for 10 g L{sup -1} of POF. In addition, the variation of the initial concentration of phosphorus from 8 to 50 mg L{sup -1} increased the adsorption capacity from 0.99 to 3.03 mg g{sup -1}. The use of secondary treated wastewater showed the presence of competition phenomenon between phosphorus and sulphate which could be overcoming with increasing the sorptive surface area and providing more adsorption sites when increasing the adsorbent dosage of POF. Compared with columns studies, this novel CSTR system showed more advantages for the removal of soluble phosphorus as a tertiary treatment of urban secondary effluents with more adsorption efficiency and capacity, in addition to the prospect use of saturated POF with nutriment as fertilizer and compost.

Removal of phosphorus from aqueous solution by Posidonia oceanica fibers using continuous stirring tank reactor

International Nuclear Information System (INIS)

Wahab, Mohamed Ali; Hassine, Rafik Ben; Jellali, Salah

2011-01-01

The present study aims to develop a new potentially low-cost, sustainable treatment approach to soluble inorganic phosphorus removal from synthetic solutions and secondary wastewater effluents in which a plant waste (Posidonia oceanica fiber: POF) is used for further agronomic benefit. Dynamic flow tests using a continuous stirred tank reactor (CSTR) were carried out to study the effect of initial concentration of phosphorus, amount of adsorbent, feeding flow rate and anions competition. The experimental results showed that the removal efficiency of phosphorus from synthetic solutions is about 80% for 10 g L -1 of POF. In addition, the variation of the initial concentration of phosphorus from 8 to 50 mg L -1 increased the adsorption capacity from 0.99 to 3.03 mg g -1 . The use of secondary treated wastewater showed the presence of competition phenomenon between phosphorus and sulphate which could be overcoming with increasing the sorptive surface area and providing more adsorption sites when increasing the adsorbent dosage of POF. Compared with columns studies, this novel CSTR system showed more advantages for the removal of soluble phosphorus as a tertiary treatment of urban secondary effluents with more adsorption efficiency and capacity, in addition to the prospect use of saturated POF with nutriment as fertilizer and compost.

Bar dimensions and bar shapes in estuaries

Science.gov (United States)

Leuven, Jasper; Kleinhans, Maarten; Weisscher, Steven; van der Vegt, Maarten

2016-04-01

Estuaries cause fascinating patterns of dynamic channels and shoals. Intertidal sandbars are valuable habitats, whilst channels provide access to harbors. We still lack a full explanation and classification scheme for the shapes and dimensions of bar patterns in natural estuaries, in contrast with bars in rivers. Analytical physics-based models suggest that bar length in estuaries increases with flow velocity, tidal excursion length or estuary width, depending on which model. However, these hypotheses were never validated for lack of data and experiments. We present a large dataset and determine the controls on bar shape and dimensions in estuaries, spanning bar lengths from centimeters (experiments) to 10s of kilometers length. First, we visually identified and classified 190 bars, measured their dimensions (width, length, height) and local braiding index. Data on estuarine geometry and tidal characteristics were obtained from governmental databases and literature on case studies. We found that many complex bars can be seen as simple elongated bars partly cut by mutually evasive ebb- and flood-dominated channels. Data analysis shows that bar dimensions scale with estuary dimensions, in particular estuary width. Breaking up the complex bars in simple bars greatly reduced scatter. Analytical bar theory overpredicts bar dimensions by an order of magnitude in case of small estuarine systems. Likewise, braiding index depends on local width-to-depth ratio, as was previously found for river systems. Our results suggest that estuary dimensions determine the order of magnitude of bar dimensions, while tidal characteristics modify this. We will continue to model bars numerically and experimentally. Our dataset on tidal bars enables future studies on the sedimentary architecture of geologically complex tidal deposits and enables studying effects of man-induced perturbations such as dredging and dumping on bar and channel patterns and habitats.

Volatile profile characterisation of Chilean sparkling wines produced by traditional and Charmat methods via sequential stir bar sorptive extraction.

Science.gov (United States)

Ubeda, C; Callejón, R M; Troncoso, A M; Peña-Neira, A; Morales, M L

2016-09-15

The volatile compositions of Charmat and traditional Chilean sparkling wines were studied for the first time. For this purpose, EG-Silicone and PDMS polymeric phases were compared and, afterwards, the most adequate was selected. The best extraction method turned out to be a sequential extraction in the headspace and by immersion using two PDMS twisters. A total of 130 compounds were determined. In traditional Chilean sparkling wines, ethyl esters were significantly higher, while acetic esters and ketones were predominant in the Charmat wines. PCA and LDA confirmed the differences in the volatile profiles between the production methods (traditional vs. Charmat). Copyright © 2016 Elsevier Ltd. All rights reserved.

Microstructure characterization of the stir zone of submerged friction stir processed aluminum alloy 2219

International Nuclear Information System (INIS)

Feng, Xiuli; Liu, Huijie; Lippold, John C.

2013-01-01

Aluminum alloy 2219-T6 was friction stir processed using a novel submerged processing technique to facilitate cooling. Processing was conducted at a constant tool traverse speed of 200 mm/min and spindle rotation speeds in the range from 600 to 800 rpm. The microstructural characteristics of the base metal and processed zone, including grain structure and precipitation behavior, were studied using optical microscopy (OM), scanning electron microscopy (SEM) and transmission electron microscopy (TEM). Microhardness maps were constructed on polished cross sections of as-processed samples. The effect of tool rotation speed on the microstructure and hardness of the stir zone was investigated. The average grain size of the stir zone was much smaller than that of the base metal, but the hardness was also lower due to the formation of equilibrium θ precipitates from the base metal θ′ precipitates. Stir zone hardness was found to decrease with increasing rotation speed (heat input). The effect of processing conditions on strength (hardness) was rationalized based on the competition between grain refinement strengthening and softening due to precipitate overaging. - Highlights: • SZ grain size (∼ 1 μm) is reduced by over one order of magnitude relative to the BM. • Hardness in the SZ is lower than that of the precipitation strengthened BM. • Metastable θ′ in the base metal transforms to equilibrium θ in the stir zone. • Softening in the SZ results from a decrease of precipitation strengthening

Microstructure characterization of the stir zone of submerged friction stir processed aluminum alloy 2219

Energy Technology Data Exchange (ETDEWEB)

Feng, Xiuli, E-mail: feng.97@osu.edu [Welding Engineering Program, Department of Materials Science and Engineering, The Ohio State University, Columbus, OH 43221 (United States); State Key Laboratory of Advanced Welding and Joining, Harbin Institute of Technology, Harbin 150001 (China); Liu, Huijie, E-mail: liuhj@hit.edu.cn [State Key Laboratory of Advanced Welding and Joining, Harbin Institute of Technology, Harbin 150001 (China); Lippold, John C., E-mail: lippold.1@osu.edu [Welding Engineering Program, Department of Materials Science and Engineering, The Ohio State University, Columbus, OH 43221 (United States)

2013-08-15

Aluminum alloy 2219-T6 was friction stir processed using a novel submerged processing technique to facilitate cooling. Processing was conducted at a constant tool traverse speed of 200 mm/min and spindle rotation speeds in the range from 600 to 800 rpm. The microstructural characteristics of the base metal and processed zone, including grain structure and precipitation behavior, were studied using optical microscopy (OM), scanning electron microscopy (SEM) and transmission electron microscopy (TEM). Microhardness maps were constructed on polished cross sections of as-processed samples. The effect of tool rotation speed on the microstructure and hardness of the stir zone was investigated. The average grain size of the stir zone was much smaller than that of the base metal, but the hardness was also lower due to the formation of equilibrium θ precipitates from the base metal θ′ precipitates. Stir zone hardness was found to decrease with increasing rotation speed (heat input). The effect of processing conditions on strength (hardness) was rationalized based on the competition between grain refinement strengthening and softening due to precipitate overaging. - Highlights: • SZ grain size (∼ 1 μm) is reduced by over one order of magnitude relative to the BM. • Hardness in the SZ is lower than that of the precipitation strengthened BM. • Metastable θ′ in the base metal transforms to equilibrium θ in the stir zone. • Softening in the SZ results from a decrease of precipitation strengthening.

Extraction optimization and pixel-based chemometric analysis of semi-volatile organic compounds in groundwater

DEFF Research Database (Denmark)

Christensen, Peter; Tomasi, Giorgio; Kristensen, Mette

2017-01-01

. In this study, we tested the combination of solid phase extraction (SPE) with dispersive liquid-liquid micro extraction (DLLME), or with stir bar sorptive extraction (SBSE), as an extraction method for semi-VOCs in groundwater. Combining SPE with DLLME or SBSE resulted in better separation of peaks...... in an unresolved complex mixture. SPE-DLLME was chosen as the preferred extraction method. SPE-DLLME covered a larger polarity range (logKo/w 2.0-11.2), had higher extraction efficiency at logKo/w 2.0-3.8 and 5.8-11.2, and was faster compared to SPE-SBSE. SPE-DLLME extraction combined with chemical analysis by gas...... chromatography-mass spectrometry (GC-MS) and pixel-based data analysis of summed extraction ion chromatograms (sEICs) was tested as a new method for chemical fingerprinting of semi-VOCs in 15 groundwater samples. The results demonstrate that SPE-DLLME-GC-MS provides an excellent compromise between compound...

OPTIMIZATION OF STIRRING SPEED AND STIRRING TIME TOWARD NANOPARTICLE SIZE OF CHITOSAN-SIAM CITRUS PEEL (Citrus nobilis L.var Microcarpa 70% ETHANOL EXTRACT

Directory of Open Access Journals (Sweden)

Wintari Taurina

2017-04-01

Full Text Available Siam citrus peel (Citrus nobilis L. var. Microcarpa is a plant derived from Sambas Regency, West Kalimantan Province. Bioavailability of herbal active compounds can be enhanced by formulating extract into nanoparticle. The polymer used was chitosan with crosslinker Na-TPP. Stirring speed and stirring time play an important role to produce small particle size in forming nanoparticle using ionic gelation method. Enhancement of stirring speed and stirring time could reduce particle size. Nanoparticles were prepared using ionic gelation method by mixing Na-TPP, extract and chitosan (1:1:6 with varying the stirring speed 500 rpm, 1000 rpm, 1500 rpm and stirring time 1 hrs, 2 hrs, 3 hrs. The particle size of nanoparticle was found to be 85.3 nm at 1000 rpm of stirring speed and 3 hrs of stirring times, with polidispersity index 0.287, zeta potential +32.37 mV and entrapment efficiency 87.12 %.

Mechanism for Self-Reacted Friction Stir Welding

Science.gov (United States)

Venable, Richard; Bucher, Joseph

2004-01-01

A mechanism has been designed to apply the loads (the stirring and the resection forces and torques) in self-reacted friction stir welding. This mechanism differs somewhat from mechanisms used in conventional friction stir welding, as described below. The tooling needed to apply the large reaction loads in conventional friction stir welding can be complex. Self-reacted friction stir welding has become popular in the solid-state welding community as a means of reducing the complexity of tooling and to reduce costs. The main problems inherent in self-reacted friction stir welding originate in the high stresses encountered by the pin-and-shoulder assembly that produces the weld. The design of the present mechanism solves the problems. The mechanism includes a redesigned pin-and-shoulder assembly. The welding torque is transmitted into the welding pin by a square pin that fits into a square bushing with set-screws. The opposite or back shoulder is held in place by a Woodruff key and high-strength nut on a threaded shaft. The Woodruff key reacts the torque, while the nut reacts the tensile load on the shaft.

Thermal Stir Welding: A New Solid State Welding Process

Science.gov (United States)

Ding, R. Jeffrey

2003-01-01

Thermal stir welding is a new welding process developed at NASA's Marshall Space Flight Center in Huntsville, AL. Thermal stir welding is similar to friction stir welding in that it joins similar or dissimilar materials without melting the parent material. However, unlike friction stir welding, the heating, stirring and forging elements of the process are all independent of each other and are separately controlled. Furthermore, the heating element of the process can be either a solid-state process (such as a thermal blanket, induction type process, etc), or, a fusion process (YG laser, plasma torch, etc.) The separation of the heating, stirring, forging elements of the process allows more degrees of freedom for greater process control. This paper introduces the mechanics of the thermal stir welding process. In addition, weld mechanical property data is presented for selected alloys as well as metallurgical analysis.

Deformation During Friction Stir Welding

Science.gov (United States)

White, Henry J.

2002-01-01

Friction Stir Welding (FSW) is a solid state welding process that exhibits characteristics similar to traditional metal cutting processes. The plastic deformation that occurs during friction stir welding is due to the superposition of three flow fields: a primary rotation of a radially symmetric solid plug of metal surrounding the pin tool, a secondary uniform translation, and a tertiary ring vortex flow (smoke rings) surrounding the tool. If the metal sticks to the tool, the plug surface extends down into the metal from the outer edge of the tool shoulder, decreases in diameter like a funnel, and closes up beneath the pin. Since its invention, ten years have gone by and still very little is known about the physics of the friction stir welding process. In this experiment, an H13 steel weld tool (shoulder diameter, 0.797 in; pin diameter, 0.312 in; and pin length, 0.2506 in) was used to weld three 0.255 in thick plates. The deformation behavior during friction stir welding was investigated by metallographically preparing a plan view sections of the weldment and taking Vickers hardness test in the key-hole region.

Effects of tool speeds and corresponding torque/energy on stir zone formation during friction stir welding/processing

International Nuclear Information System (INIS)

Cui, S; Chen, Z W

2009-01-01

The way processing parameters and the measurable thermomechanical responses relate to the individual and combined flows forming the different processed zones during friction stir welding/processing has been studied. Experimentally, a cast Al-7Si-0.3Mg alloy was used to provide readily identifiable processed zones. A series of friction stir experiments covering a wide range of tool forward and rotation speeds were conducted followed by the measurement of individual and combined stir areas. It has been found that the basic modes of material flow did not change but the relative volume of each flow depended on both forward and rotation speeds. The trends observed in the present data explain how pin rotation relates to the material transportation mechanism and the associated torque required. This data also explains how forward speed, not rotation speed, relates to specific energy and the volume of the total stir zone.

CP asymmetries in B-bar → K-bar *( → K-bar π) l-bar l and untagged B-bar s, Bs → φ( → K+K-) l-bar l decays at NLO

International Nuclear Information System (INIS)

Bobeth, Christoph; Hiller, Gudrun; Piranishvili, Giorgi

2008-01-01

The decay B-bar → K-bar *( → K-bar π) l-bar l offers great opportunities to explore the physics at and above the electroweak scale by means of an angular analysis. We investigate the physics potential of the seven CP asymmetries plus the asymmetry in the rate, working at low dilepton mass using QCD factorization at next-to leading order (NLO). The b → s CP asymmetries are doubly Cabibbo-suppressed ∼ d , B d → K*( → K 0 π 0 ) l-bar l and B-bar s , B s → φ( → K + K - ) l-bar l decays. Analyses of these CP asymmetries can rule out, or further support the minimal description of CP violation through the CKM mechanism. Experimental studies are promising for (super) flavor factories and at hadron colliders.

Effect of chemical modification on reduction and sorptive properties of chars from hydropyrolysis of coal

Energy Technology Data Exchange (ETDEWEB)

Stanczyk, K.; Miga, K.; Fabis, G.; Jastrzab, K. [Polskiej Akademii Nauk, Gliwice (Poland)

1998-01-01

Hydropyrolysis of bituminous coal and lignite as way of synthesis of adsorbents has been applied. Chemical modification of chars based on simultaneous carbonization of coal and plastics containing sulfur and nitrogen has been carried out. It was stated that modified chars exhibit better reduction and sorptive properties than non-modified and that modified adsorbents made of lignite exceed commercial ones. 7 refs., 4 figs., 3 tabs.

Study of the reactions $\\bar{p}p \\rightarrow \\bar{\\Lambda} \\Lambda , \\bar{\\Lambda} \\Sigma^{0}$ or $\\bar{\\Sigma^{0}} \\Lambda , \\bar{\\Sigma^{+}} \\Sigma^{+}$ at 3.6 GeV/c

CERN Document Server

Atherton, Henry W; Moebes, J P; Quercigh, Emanuele

1974-01-01

The reactions $\\bar{p}p \\rightarrow \\bar{\\Lambda} \\Lambda , \\bar{\\Lambda} \\Sigma^{0}$ or $\\bar{\\Sigma^{0}} \\Lambda , \\bar{\\Sigma^{+}} \\Sigma^{+}$ are studied at an incident momentum of 3.6 GeV/c in a 35.4 event/$\\mu$ b experiment performed in the CERN 2m HBC. Total and differential cross sections are presented. The polarization of the hyperons is measured as a function of $t$ and for the reaction $\\bar{p}p \\rightarrow \\bar{\\Lambda} \\Lambda$ the complete spin correlation matrix is given. (23 refs).

The Possible Heavy Tetraquarks $qQ\\bar q \\bar Q$, $qq\\bar Q \\bar Q$ and $qQ\\bar Q \\bar Q$

OpenAIRE

Cui, Ying; Chen, Xiao-Lin; Deng, Wei-Zhen; Zhu, Shi-Lin

2006-01-01

Assuming X(3872) is a $qc \\bar q \\bar c$ tetraquark and using its mass as input, we perform a schematic study of the masses of possible heavy tetraquarks using the color-magnetic interaction with the flavor symmetry breaking corrections.

Gimballed Shoulders for Friction Stir Welding

Science.gov (United States)

Carter, Robert; Lawless, Kirby

2008-01-01

In a proposed improvement of tooling for friction stir welding, gimballed shoulders would supplant shoulders that, heretofore, have been fixedly aligned with pins. The proposal is especially relevant to self-reacting friction stir welding. Some definitions of terms, recapitulated from related prior NASA Tech Briefs articles, are prerequisite to a meaningful description of the proposed improvement. In friction stir welding, one uses a tool that includes (1) a rotating shoulder on top (or front) of the workpiece and (2) a pin that rotates with the shoulder and protrudes from the shoulder into the depth of the workpiece. In conventional friction stir welding, the main axial force exerted by the tool on the workpiece is reacted through a ridged backing anvil under (behind) the workpiece. When conventional friction stir welding is augmented with an auto-adjustable pin-tool (APT) capability, the depth of penetration of the pin into the workpiece is varied in real time by a position- or forcecontrol system that extends or retracts the pin as needed to obtain the desired effect. In self-reacting (also known as self-reacted) friction stir welding as practiced heretofore, there are two shoulders: one on top (or front) and one on the bottom (or back) of the workpiece. In this case, a threaded shaft protrudes from the tip of the pin to beyond the back surface of the workpiece. The back shoulder is held axially in place against tension by a nut on the threaded shaft. Both shoulders rotate with the pin and remain aligned coaxially with the pin. The main axial force exerted on the workpiece by the tool and front shoulder is reacted through the back shoulder and the threaded shaft into the friction-stir-welding machine head, so that a backing anvil is no longer needed. A key transmits torque between the bottom shoulder and the threaded shaft, so that the bottom shoulder rotates with the shaft. This concludes the prerequisite definitions of terms.

Gimbaled-shoulder friction stir welding tool

Science.gov (United States)

Carter, Robert W. (Inventor); Lawless, Kirby G. (Inventor)

2010-01-01

A gimbaled-shoulder friction stir welding tool includes a pin and first and second annular shoulders coupled to the pin. At least one of the annular shoulders is coupled to the pin for gimbaled motion with respect thereto as the tool is rotated by a friction stir welding apparatus.

Dynamic fabric phase sorptive extraction for a group of pharmaceuticals and personal care products from environmental waters.

Science.gov (United States)

Lakade, Sameer S; Borrull, Francesc; Furton, Kenneth G; Kabir, Abuzar; Marcé, Rosa Maria; Fontanals, Núria

2016-07-22

This paper describes for the first time the use of a new extraction technique, based on fabric phase sorptive extraction (FPSE). This new mode proposes the extraction of the analytes in dynamic mode in order to reduce the extraction time. Dynamic fabric phase sorptive extraction (DFPSE) followed by liquid chromatography-tandem mass spectrometry was evaluated for the extraction of a group of pharmaceuticals and personal care products (PPCPs) from environmental water samples. Different parameters affecting the extraction were optimized and best conditions were achieved when 50mL of sample at pH 3 was passed through 3 disks and analytes retained were eluted with 10mL of ethyl acetate. The recoveries were higher than 60% for most of compounds with the exception of the most polar ones (between 8% and 38%). The analytical method was validated with environmental samples such as river water and effluent and influent wastewater, and good performance was obtained. The analysis of samples revealed the presence of some PPCPs at low ngL(-1) concentrations. Copyright © 2016 Elsevier B.V. All rights reserved.

The Effect of Premixed Al-Cu Powder on the Stir Zone in Friction Stir Welding of AA3003-H18

Science.gov (United States)

Abnar, B.; Kazeminezhad, M.; Kokabi, A. H.

2015-02-01

In this research, 3-mm-thick AA3003-H18 non-heat-treatable aluminum alloy plates were joined by friction stir welding (FSW). It was performed by adding pure Cu and premixed Cu-Al powders at various rotational speeds of 800, 1000, and 1200 rpm and constant traveling speeds of 100 mm/min. At first, the powder was filled into the gap (0.2 or 0.4 mm) between two aluminum alloy plates, and then the FSW process was performed in two passes. The microstructure, mechanical properties, and formation of intermetallic compounds were investigated in both cases of using pure Cu and premixed Al-Cu powders. The results of using pure Cu and premixed Al-Cu powders were compared in the stir zone at various rotational speeds. The copper particle distribution and formation of Al-Cu intermetallic compounds (Al2Cu and AlCu) in the stir zone were desirable using premixed Al-Cu powder into the gap. The hardness values were significantly increased by formation of Al-Cu intermetallic compounds in the stir zone and it was uniform throughout the stir zone when premixed Al-Cu powder was used. Also, longitudinal tensile strength from the stir zone was higher when premixed Al-Cu powder was used instead of pure Cu powder.

Reconstruction of Clear-PEM data with STIR

CERN Document Server

Martins, M V; Rodrigues, P; Trindade, A; Oliveira, N; Correia, M; Cordeiro, H; Ferreira, N C; Varela, J; Almeida, P

2006-01-01

The Clear-PEM scanner is a device based on planar detectors that is currently under development within the Crystal Clear Collaboration, at CERN. The basis for 3D image reconstruction in Clear-PEM is the software for tomographic image reconstruction (STIR). STIR is an open source object-oriented library that efficiently deals with the 3D positron emission tomography data sets. This library was originally designed for the traditional cylindrical scanners. In order to make its use compatible with planar scanner data, new functionalities were introduced into the library's framework. In this work, Monte Carlo simulations of the Clear-PEM scanner acquisitions were used as input for image reconstruction with the 3D OSEM algorithm available in STIR. The results presented indicate that dual plate PEM data can be accurately reconstructed using the enhanced STIR framework.

Triply heavy tetraquark states with the $QQ\\bar{Q}\\bar{q}$ configuration

OpenAIRE

Chen, Kan; Liu, Xiang; Wu, Jing; Liu, Yan-Rui; Zhu, Shi-Lin

2016-01-01

In the framework of the color-magnetic interaction, we systematically investigate the mass splittings of the $QQ\\bar{Q}\\bar{q}$ tetraquark states and estimated their rough masses in this work. These systems include the explicitly exotic states $cc\\bar{b}\\bar{q}$ and $bb\\bar{c}\\bar{q}$ and the hidden exotic states $cc\\bar{c}\\bar{q}$, $cb\\bar{b}\\bar{q}$, $bc\\bar{c}\\bar{q}$, and $bb\\bar{b}\\bar{q}$. If a state around the estimated mass region could be observed, its nature as a genuine tetraquark ...

Experimental and Kinetic Modeling Study of Ethyl Levulinate Oxidation in a Jet-Stirred Reactor

KAUST Repository

Wang, Jui-Yang

2017-06-01

A jet-stirred reactor was designed and constructed in the Clean Combustion Research Center (CCRC) at King Abdullah University of Science and Technology (KAUST); was validated with n-heptane, iso-octane oxidation and cyclohexene pyrolysis. Different configurations of the setup have been tested to achieve good agreement with results from the literature. Test results of the reactor indicated that installation of a pumping system at the downstream side in the experimental apparatus was necessary to avoid the reoccurrence of reactions in the sampling probe. Experiments in ethyl levulinate oxidation were conducted in the reactor under several equivalence ratios, from 600 to 1000 K, 1 bar and 2 s residence time. Oxygenated species detected included methyl vinyl ketone, levulinic acid and ethyl acrylate. Ethylene, methane, carbon monoxide, hydrogen, oxygen and carbon dioxide were further quantified with a gas chromatography, coupled with a flame ionization detector and a thermal conductivity detector. The ethyl levulinate chemical kinetic model was first developed by Dr. Stephen Dooley, Trinity College Dublin, and simulated under the same conditions, using the Perfect-Stirred Reactor code in Chemkin software. In comparing the simulation results with experimental data, some discrepancies were noted; predictions of ethylene production were not well matched. The kinetic model was improved by updating several classes of reactions: unimolecular decomposition, H-abstraction, C-C and C-O beta-scissions of fuel radicals. The updated model was then compared again with experimental results and good agreement was achieved, proving that the concerted eliminated reaction is crucial for the kinetic mechanism formulation of ethyl levulinate. In addition, primary reaction pathways and sensitivity analysis were performed to describe the role of molecular structure in combustion (800 and 1000 K for ethyl levulinate oxidation in the jet-stirred reactor).

Comparative study of cerium (IV) sorptive properties in zeolite Y and clinoptilolite; Estudio comparativo de la fijacion de cerio (IV) en zeolitas, faujasita-Y y clinoptilolita

Energy Technology Data Exchange (ETDEWEB)

Garcia D, O C

1994-12-31

Among the problems of protecting the environment from radioactive contamination, the reduction of radioactive releases by improving monitoring, decontamination, and burial methods is one of the most important. Natural sorbents are gaining increased significance for solving this problem. Among these, zeolites deserve special attention since they have sufficient sorptive capacity, are highly radiation resistant, are widely distributed exhibit selectivity and are inexpensive. In the present work we determine experimentally the sorptive characteristics of clinoptilolite as a function of various factors and demonstrate that clinoptilolite is capable of sorbing Ce(IV) over a wide pH range. (Author).

Experimental preparation of Kr/Xe hydrate at pressures up to 160 bar

International Nuclear Information System (INIS)

Simonis, R.

1985-06-01

A compound called gas (mixture) hydrate is formed under pressurized atmosphere by reaction of krypton, xenon and a mixture of both with water. The study under review reports on preparing such hydrates experimentally under pressures up to 160 bar. The dissociation function of the hydrates is determined by low and medium-pressure experiments. Observing the formation process it was found that a hydrate layer is formed at the interface of gas and water, its separating effect almost inhibiting continuance of hydrate reactions. Strong stirring will avoid or destroy the separating layer. It is shown that at pressures above 50 bar the dissociation function psub(D) (T) gets non-linear with logarithmic pressure plotting above the absolute, reciprocal temperature. The medium-temperature experiments show that the density of the gas consisting of Xe or Kr and Xe, respectively, reaches higher values than that of the water. In this case, the system collapses and the gas is found at the bottom of the pressure flask, and the water in the top region. The gas samples taken during the mixed hydrate preparation show that Kr is accumulated in the gaseous phase, and Xe in the hydrate phase. (orig./RB) [de

Flexible Friction Stir Joining Technology

Energy Technology Data Exchange (ETDEWEB)

Feng, Zhili [Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States); Lim, Yong Chae [Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States); Mahoney, Murray [MegaStir Technologies LLC, Orem, UT (United States); Sanderson, Samuel [MegaStir Technologies LLC, Orem, UT (United States); Larsen, Steve [MegaStir Technologies LLC, Orem, UT (United States); Steel, Russel [MegaStir Technologies LLC, Orem, UT (United States); Fleck, Dale [MegaStir Technologies LLC, Orem, UT (United States); Fairchild, Doug P [ExxonMobil, Upstream Research Company (URC), Houston, TX (United States); Wasson, Andrew J [ExxonMobil, Upstream Research Company (URC), Houston, TX (United States); Babb, Jon [MegaStir Technologies LLC, Orem, UT (United States); Higgins, Paul [MegaStir Technologies LLC, Orem, UT (United States)

2015-07-23

Reported herein is the final report on a U.S. Department of Energy (DOE) Advanced Manufacturing Office (AMO) project with industry cost-share that was jointly carried out by Oak Ridge National Laboratory (ORNL), ExxonMobil Upstream Research Company (ExxonMobil), and MegaStir Technologies (MegaStir). The project was aimed to advance the state of the art of friction stir welding (FSW) technology, a highly energy-efficient solid-state joining process, for field deployable, on-site fabrications of large, complex and thick-sectioned structures of high-performance and high-temperature materials. The technology innovations developed herein attempted to address two fundamental shortcomings of FSW: 1) the inability for on-site welding and 2) the inability to weld thick section steels, both of which have impeded widespread use of FSW in manufacturing. Through this work, major advance has been made toward transforming FSW technology from a “specialty” process to a mainstream materials joining technology to realize its pervasive energy, environmental, and economic benefits across industry.

Sorptive and desorptive fractionation of dissolved organic matter by mineral soil matrices.

Science.gov (United States)

Oren, Adi; Chefetz, Benny

2012-01-01

Interactions of dissolved organic matter (DOM) with soil minerals, such as metal oxides and clays, involve various sorption mechanisms and may lead to sorptive fractionation of certain organic moieties. While sorption of DOM to soil minerals typically involves a degree of irreversibility, it is unclear which structural components of DOM correspond to the irreversibly bound fraction and which factors may be considered determinants. To assist in elucidating that, the current study aimed at investigating fractionation of DOM during sorption and desorption processes in soil. Batch DOM sorption and desorption experiments were conducted with organic matter poor, alkaline soils. Fourier-transform infrared (FTIR) and UV-Vis spectroscopy were used to analyze bulk DOM, sorbed DOM, and desorbed DOM fractions. Sorptive fractionation resulted mainly from the preferential uptake of aromatic, carboxylic, and phenolic moieties of DOM. Soil metal-oxide content positively affected DOM sorption and binding of some specific carboxylate and phenolate functional groups. Desorptive fractionation of DOM was expressed by the irreversible-binding nature of some carboxylic moieties, whereas other bound carboxylic moieties were readily desorbed. Inner-sphere, as opposed to outer-sphere, ligand-exchange complexation mechanisms may be responsible for these irreversible, as opposed to reversible, interactions, respectively. The interaction of aliphatic DOM constituents with soil, presumably through weak van der Waals forces, was minor and increased with increasing proportion of clay minerals in the soil. Revealing the nature of DOM-fractionation processes is of great importance to understanding carbon stabilization mechanisms in soils, as well as the overall fate of contaminants that might be associated with DOM. Copyright © by the American Society of Agronomy, Crop Science Society of America, and Soil Science Society of America, Inc.

RELATING BOTTOM QUARK MASS IN DR-BAR AND MS-BAR REGULARIZATION SCHEMES

International Nuclear Information System (INIS)

2002-01-01

The value of the bottom quark mass at Q = M Z in the (bar D)(bar R) scheme is an important input for the analysis of supersymmetric models with a large value of tan β. Conventionally, however, the running bottom quark mass extracted from experimental data is quoted in the (bar M)(bar S) scheme at the scale Q = m b . We describe a two loop procedure for the conversion of the bottom quark mass from (bar M)(bar S) to (bar D)(bar R) scheme. The Particle Data Group value m b # bar M# # bar S#(m b # bar M# # bar S#) = 4.2 ± 0.2 GeV corresponds to a range of 2.65-3.03 GeV for m b # bar D# # bar R#(M Z )

Friction Stir Welding

Science.gov (United States)

Nunes, Arthur C., Jr.

2008-01-01

Friction stir welding (FSW) is a solid state welding process invented in 1991 at The Welding Institute in the United Kingdom. A weld is made in the FSW process by translating a rotating pin along a weld seam so as to stir the sides of the seam together. FSW avoids deleterious effects inherent in melting and promises to be an important welding process for any industries where welds of optimal quality are demanded. This article provides an introduction to the FSW process. The chief concern is the physical effect of the tool on the weld metal: how weld seam bonding takes place, what kind of weld structure is generated, potential problems, possible defects for example, and implications for process parameters and tool design. Weld properties are determined by structure, and the structure of friction stir welds is determined by the weld metal flow field in the vicinity of the weld tool. Metal flow in the vicinity of the weld tool is explained through a simple kinematic flow model that decomposes the flow field into three basic component flows: a uniform translation, a rotating solid cylinder, and a ring vortex encircling the tool. The flow components, superposed to construct the flow model, can be related to particular aspects of weld process parameters and tool design; they provide a bridge to an understanding of a complex-at-first-glance weld structure. Torques and forces are also discussed. Some simple mathematical models of structural aspects, torques, and forces are included.

Electrodeposition of uranium in stirred liquid cadmium cathode

International Nuclear Information System (INIS)

Koyama, T.; Tanaka, H.

1997-01-01

The electrodeposition of U in a liquid Cd cathode was known to be hampered by the formation of dendritic U on the Cd surface. Electrotransports of uranium to the stirred liquid Cd cathode were carried out at 773 K for different cathode current densities and different Reynolds number of stirring. The maximum amount of U taken in the liquid Cd cathode without forming dendrites was found to increase with an increasing Reynolds number of stirring and decrease with increasing cathode current density. (orig.)

Performance simulation of BaBar DIRC bar boxes in TORCH

Science.gov (United States)

Föhl, K.; Brook, N.; Castillo García, L.; Cussans, D.; Forty, R.; Frei, C.; Gao, R.; Gys, T.; Harnew, N.; Piedigrossi, D.; Rademacker, J.; Ros García, A.; van Dijk, M.

2017-12-01

TORCH is a large-area precision time-of-flight detector based on the DIRC principle. The DIRC bar boxes of the BaBar experiment at SLAC could possibly be reused to form a part of the TORCH detector time-of-flight wall area, proposed to provide positive particle identification of low momentum kaons in the LHCb experiment at CERN. For a potential integration of BaBar bar boxes into TORCH, new imaging readout optics are required. From the several designs of readout optics that have been considered, two are used in this paper to study the effect of BaBar bar optical imperfections on the detector reconstruction performance. The kaon-pion separation powers obtained from analysing simulated photon hit patterns show the performance reduction for a BaBar bar of non-square geometry compared to a perfectly rectangular cross section.

Sorptive capacities of lipids determined by passive dosing of non-polar organic chemicals

DEFF Research Database (Denmark)

Jahnke, Annika; Kierkegaard, Amelie; Bolinius, Damien

VMS), chlorobenzenes and polychlorinated biphenyls via a common headspace over an olive oil donor phase to transfer the same chemical activity into the samples; iii) sampling of EOM and olive oil controls at different time points; iv) purge-and-trap extraction of the model chemicals onto ENV+ SPE cartridges, elution...... and GC/MS analysis; v) characterization of the lipid composition in all samples via NMR. Our experiments demonstrate that the sorptive capacities of the EOM samples do not differ significantly from the olive oil controls if the EOM consists of neutral lipids only. However, the EOM samples show small...

Sorptive Uptake Studies of an Aryl-Arsenical with Iron Oxide Composites on an Activated Carbon Support

Directory of Open Access Journals (Sweden)

Jae H. Kwon

2014-03-01

Full Text Available Sorption uptake kinetics and equilibrium studies for 4-hydroxy-3-nitrobenzene arsonic acid (roxarsone was evaluated with synthetic magnetite (Mag-P, commercial magnetite (Mag-C, magnetite 10%, 19%, and 32% composite material (CM-10, -19, -32 that contains granular activated carbon (GAC, and synthetic goethite at pH 7.00 in water at 21 °C for 24 h. GAC showed the highest sorptive removal of roxarsone and the relative uptake for each sorbent material with roxarsone are listed in descending order as follows: GAC (471 mg/g > goethite (418 mg/g > CM-10 (377 mg/g CM-19 (254 mg/g > CM-32 (227 mg/g > Mag-P (132 mg/g > Mag-C (29.5 mg/g. The As (V moiety of roxarsone is adsorbed onto the surface of the iron oxide/oxyhydrate and is inferred as inner-sphere surface complexes; monodentate-mononuclear, bidentate-mononuclear, and bidentate-binuclear depending on the protolytic speciation of roxarsone. The phenyl ring of roxarsone provides the primary driving force for the sorptive interaction with the graphene surface of GAC and its composites. Thus, magnetite composites are proposed as multi-purpose adsorbents for the co-removal of inorganic and organic arsenicals due to the presence of graphenic and iron oxide active adsorption sites.

Modeling of the oxidation of methyl esters—Validation for methyl hexanoate, methyl heptanoate, and methyl decanoate in a jet-stirred reactor

Science.gov (United States)

Glaude, Pierre Alexandre; Herbinet, Olivier; Bax, Sarah; Biet, Joffrey; Warth, Valérie; Battin-Leclerc, Frédérique

2013-01-01

The modeling of the oxidation of methyl esters was investigated and the specific chemistry, which is due to the presence of the ester group in this class of molecules, is described. New reactions and rate parameters were defined and included in the software EXGAS for the automatic generation of kinetic mechanisms. Models generated with EXGAS were successfully validated against data from the literature (oxidation of methyl hexanoate and methyl heptanoate in a jet-stirred reactor) and a new set of experimental results for methyl decanoate. The oxidation of this last species was investigated in a jet-stirred reactor at temperatures from 500 to 1100 K, including the negative temperature coefficient region, under stoichiometric conditions, at a pressure of 1.06 bar and for a residence time of 1.5 s: more than 30 reaction products, including olefins, unsaturated esters, and cyclic ethers, were quantified and successfully simulated. Flow rate analysis showed that reactions pathways for the oxidation of methyl esters in the low-temperature range are similar to that of alkanes. PMID:23710076

Modeling of the oxidation of methyl esters-Validation for methyl hexanoate, methyl heptanoate, and methyl decanoate in a jet-stirred reactor.

Science.gov (United States)

Glaude, Pierre Alexandre; Herbinet, Olivier; Bax, Sarah; Biet, Joffrey; Warth, Valérie; Battin-Leclerc, Frédérique

2010-11-01

The modeling of the oxidation of methyl esters was investigated and the specific chemistry, which is due to the presence of the ester group in this class of molecules, is described. New reactions and rate parameters were defined and included in the software EXGAS for the automatic generation of kinetic mechanisms. Models generated with EXGAS were successfully validated against data from the literature (oxidation of methyl hexanoate and methyl heptanoate in a jet-stirred reactor) and a new set of experimental results for methyl decanoate. The oxidation of this last species was investigated in a jet-stirred reactor at temperatures from 500 to 1100 K, including the negative temperature coefficient region, under stoichiometric conditions, at a pressure of 1.06 bar and for a residence time of 1.5 s: more than 30 reaction products, including olefins, unsaturated esters, and cyclic ethers, were quantified and successfully simulated. Flow rate analysis showed that reactions pathways for the oxidation of methyl esters in the low-temperature range are similar to that of alkanes.

Characterization of the Key Aroma Compounds in Chinese Syrah Wine by Gas Chromatography-Olfactometry-Mass Spectrometry and Aroma Reconstitution Studies.

Science.gov (United States)

Zhao, Pengtao; Gao, Jinxin; Qian, Michael; Li, Hua

2017-06-24

The key aroma compounds and the organoleptic quality of two Chinese Syrah wines from the Yunnan Shangri-La region and Ningxia Helan mountain region were characterized. The most important eighty aroma-active compounds were identified by Gas Chromatography-Olfactometry. In both Syrah samples, ethyl 2-methylpropanoate, ethyl 3-methylbutanoate, 3-methylbutyl acetate, 2- and 3-methyl-1-butanol, ethyl hexanoate, ethyl octanoate, 2-phenethyl acetate, methional, 3-methylbutanoic acid, hexanoic acid, octanoic acid, β -damascenone, guaiacol, 2-phenylethanol, trans -whiskylactone, 4-ethylguaiacol, eugenol, 4-ethylphenol, and sotolon were detected to have the highest odor intensities. In the chemical analysis, 72 compounds were quantitated by Stir Bar Sorptive Extraction combined with Gas Chromatography Mass Spectrometry. Based on the Odor Activity Value (OAV), the aromas were reconstituted by combining aroma compounds in the synthetic wine, and sensory descriptive analysis was used to verify the chemical data. Fatty acid ethyl esters, acetate esters, and β -damascenone were found with higher OAVs in the more fruity-smelling sample of Helan Mountain rather than Shangri-La.

Soil-borne polycyclic aromatic hydrocarbons in El Paso, Texas: Analysis of a potential problem in the United States/Mexico border region

Science.gov (United States)

De La Torre-Roche, Roberto J.; Lee, Wen-Yee; Campos-Díaz, Sandra I.

2009-01-01

Ultrasonic extraction followed by Stir Bar Sorptive Extraction (SBSE) and thermal desorption inline coupled with Gas Chromatography and Mass Spectrometry (TD/GC/MS)was used to perform a comprehensive determination of soil-borne polycyclic aromatic hydrocarbons (PAHs) in El Paso, Texas. The method provided good sensitivity and faster processing time for the analysis. The total PAHs in El Paso soil ranged from 0.1 to 2225.5 µg kg−1. Although the majority of PAH concentrations did not exceed the soil screening levels regulated by the United States Environmental Protection Agency, the existence of PAHs in this ecosystem is ubiquitous. Naphthalene were found in 100% of the soil samples; while the heavy PAHs (five- and six-ring) were not often detected and mostly remained in closer proximity to industrial areas and major traffic points. The results ruled out the possibility of petroleum refining as the significant source of local soil-borne PAH contamination, but they suggested that the PAHs found in El Paso soil were closely linked to human activities and possible other industrial processes. PMID:18768257

Green approaches in sample preparation of bioanalytical samples prior to chromatographic analysis.

Science.gov (United States)

Filippou, Olga; Bitas, Dimitrios; Samanidou, Victoria

2017-02-01

Sample preparation is considered to be the most challenging step of the analytical procedure, since it has an effect on the whole analytical methodology, therefore it contributes significantly to the greenness or lack of it of the entire process. The elimination of the sample treatment steps, pursuing at the same time the reduction of the amount of the sample, strong reductions in consumption of hazardous reagents and energy also maximizing safety for operators and environment, the avoidance of the use of big amount of organic solvents, form the basis for greening sample preparation and analytical methods. In the last decade, the development and utilization of greener and sustainable microextraction techniques is an alternative to classical sample preparation procedures. In this review, the main green microextraction techniques (solid phase microextraction, stir bar sorptive extraction, hollow-fiber liquid phase microextraction, dispersive liquid - liquid microextraction, etc.) will be presented, with special attention to bioanalytical applications of these environment-friendly sample preparation techniques which comply with the green analytical chemistry principles. Copyright © 2016 Elsevier B.V. All rights reserved.

Comprehensive authentication of (E)-alpha(beta)-ionone from raspberries, using constant flow MDGC-C/P-IRMS and enantio-MDGC-MS.

Science.gov (United States)

Sewenig, Sabine; Bullinger, Dino; Hener, Uwe; Mosandl, Armin

2005-02-23

A new coupling system of GC-GC, connected via a Multi Column Switching Device MCS2 for measuring isotope ratios, is introduced. By means of several standard substances the precise and accurate measurement of isotopic values is proved. First applications concerning the authentication of raspberry aroma compounds are established. Consequently, the combination of constant flow multidimensional gas chromatography-combustion/pyrolysis-isotope ratio mass spectrometry (MDGC-C/P-IRMS) is applied to the authenticity assessment of (E)-alpha(beta)-ionone from six different raspberry cultivars. Furthermore, 12 commercially available raspberry products and samples of (E)-alpha(beta)-ionone, some declared to be natural, are investigated. delta(2)Eta(V)(-)(SMOW) and delta(13)C(V)(-)(PDB) values of (E)-alpha(beta)-ionone are determined, and characteristic authenticity ranges were concluded from raspberries by correlation of both delta(2)Eta(V)(-)(SMOW) and delta(13)C( V)(-)(PDB) values. The results are correlated with the determination of enantiomeric purities of (E)-alpha-ionone, using stir bar sorptive extraction enantio-multidimensional gas chromatography mass spectrometry (SBSE-enantio-MDGC-MS).

Damage Tolerance Behavior of Friction Stir Welds in Aluminum Alloys

Science.gov (United States)

McGill, Preston; Burkholder, Jonathan

2012-01-01

Friction stir welding is a solid state welding process used in the fabrication of various aerospace structures. Self-reacting and conventional friction stir welding are variations of the friction stir weld process employed in the fabrication of cryogenic propellant tanks which are classified as pressurized structure in many spaceflight vehicle architectures. In order to address damage tolerance behavior associated with friction stir welds in these safety critical structures, nondestructive inspection and proof testing may be required to screen hardware for mission critical defects. The efficacy of the nondestructive evaluation or the proof test is based on an assessment of the critical flaw size. Test data describing fracture behavior, residual strength capability, and cyclic mission life capability of friction stir welds at ambient and cryogenic temperatures have been generated and will be presented in this paper. Fracture behavior will include fracture toughness and tearing (R-curve) response of the friction stir welds. Residual strength behavior will include an evaluation of the effects of lack of penetration on conventional friction stir welds, the effects of internal defects (wormholes) on self-reacting friction stir welds, and an evaluation of the effects of fatigue cycled surface cracks on both conventional and selfreacting welds. Cyclic mission life capability will demonstrate the effects of surface crack defects on service load cycle capability. The fracture data will be used to evaluate nondestructive inspection and proof test requirements for the welds.

Calculation of energy costs of composite biomass stirring at biogas stations

Science.gov (United States)

Suslov, D. Yu; Temnikov, D. O.

2018-03-01

The paper is devoted to the study of the equipment to produce biogas fuel from organic wastes. The bioreactor equipped with a combined stirring system ensuring mechanical and bubbling stirring is designed. The method of energy cost calculation of the combined stirring system with original design is suggested. The received expressions were used in the calculation of the stirring system installed in the 10 m3 bioreactor: power consumed by the mixer during the start-up period made Nz =9.03 kW, operating power of the mixer made NE =1.406 kW, compressor power for bubbling stirring made NC =18.5 kW. Taking into account the operating mode of single elements of the stirring system, the energy cost made 4.38% of the total energy received by the biogas station.

STIR imaging of lymphadenopathy: Advantages over conventional spin-echo techniques

International Nuclear Information System (INIS)

Porter, B.A.; Neumann, E.B.; Olson, D.O.; Nyberg, D.A.; Teefy, S.A.; Shields, A.F.

1987-01-01

Spin-echo (SE) imaging of lymphadenopathy has been limited by the high signal of surrounding fat. With short TI Inversion Recovery (STIR), fat is cancelled (black), T1 and T2 contrast are additive, and pathologic nodes are white. STIR images (repetition time, 1,400 - 2,400; echo time, 36 or 40; inversion time, 100 or 125) of 69 patients with malignant adenopathy were compared with T1-weighted spin-echo (T1 SE) or intermediate SE and some T2 SE sequences at 0.15 T. Signal-intensity measurements of nodes versus adjacent tissues were used as a measure of contrast. Ratios of these values ranged from 2.5- to more than 17-fold greater for STIR versus T1 or intermediate SE sequences and to more than 40:1 for STIR versus T2 SE images. Some nodes detected on STIR were only identifiable in retrospection CT or T1 SE. In two cases, STIR detected minimally enlarged nodes not detected on CT; biopsy confirmed malignancy. Normal nodes have lower signal than malignant nodes; inflammatory nodes may mimic neoplasm. The authors replaced T2 SE with a combination of T1 SE and STIR, shortening imaging time and enhancing detection of lymphadenopathy

Mechanical properties of friction stir welded 11Cr-ferritic/martensitic steel

International Nuclear Information System (INIS)

Yano, Y.; Sato, Y.S.; Sekio, Y.; Ohtsuka, S.; Kaito, T.; Ogawa, R.; Kokawa, H.

2013-01-01

Friction stir welding was applied to the wrapper tube materials, 11Cr-ferritic/martensitic steel, designed for fast reactors and defect-free welds were successfully produced. The mechanical and microstructural properties of the friction stir welded steel were subsequently investigated. The hardness values of the stir zone were approximately 550 Hv (5.4 GPa) with minimal dependence on the rotational speed, even though they were much higher than those of the base material. However, tensile strengths and elongations of the stir zones were high at 298 K, compared to those of the base material. The excellent tensile properties are attributable to the fine grain formation during friction stir welding

Qq(Q-bar)(q-bar)' states in chiral SU(3) quark model

International Nuclear Information System (INIS)

Zhang Haixia; Zhang Min; Zhang Zongye

2007-01-01

We study the masses of Qq(Q-bar)(q-bar)' states with J PC =0 ++ , 1 ++ , 1 +- and 2 ++ in the chiral SU(3) quark model, where Q is the heavy quark (c or b) and q(q') is the light quark (u,d or s). According to our numerical results, it is improbable to make the interpretation of [cn(c-bar)(n-bar)] 1 ++ and [cn(c-bar)(n-bar)] 2 ++ (n=u,d) states as X(3872) and Y(3940), respectively. However, it is interesting to find the tetraquarks in the bq(b-bar)(q-bar)' system. (authors)

submitter Performance simulation of BaBar DIRC bar boxes in TORCH

CERN Document Server

Föhl, K; Castillo García, L; Cussans, D; Forty, R; Frei, C; Gao, R; Gys, T; Harnew, N; Piedigrossi, D; Rademacker, J; Ros García, A; van Dijk, M

2017-01-01

TORCH is a large-area precision time-of-flight detector based on the DIRC principle. The DIRC bar boxes of the BaBar experiment at SLAC could possibly be reused to form a part of the TORCH detector time-of-flight wall area, proposed to provide positive particle identification of low momentum kaons in the LHCb experiment at CERN. For a potential integration of BaBar bar boxes into TORCH, new imaging readout optics are required. From the several designs of readout optics that have been considered, two are used in this paper to study the effect of BaBar bar optical imperfections on the detector reconstruction performance. The kaon-pion separation powers obtained from analysing simulated photon hit patterns show the performance reduction for a BaBar bar of non-square geometry compared to a perfectly rectangular cross section.

[Optimization of stir-baking with vinegar technology for Curcumae Radix by orthogonal test].

Science.gov (United States)

Shi, Dianhua; Su, Benzheng; Sun, Lili; Zhang, Jun; Qu, Yongsheng

2011-05-01

To optimize the stir-baking with vinegar technology for Curcumae Radix. The intrinsic quality (the content of Curcumin) and traditional outward appearance were chosen as indexes. The best technology was determined by orthogonal test L9 (3(4)). The factors of the moistening time, stir-baking temperature and stir-baking time were investigated. The optimal technology was as follows: the quantity of vinegar was 10%, the moistening time was 10 min, the stir-baking temperature was 130 degrees C and the stir-baking time was 10 min. The optimal stir-baking with vinegar technology for Curcumae Radix is reasonable, which can be used to guide the standardized production of Curcumae Radix stir-baked with vinegar.

Thermal Stir Welding Development at Marshall Space Flight Center

Science.gov (United States)

Ding, Robert J.

2008-01-01

Solid state welding processes have become the focus of welding process development at NASA's Marshall Space Flight Center. Unlike fusion weld processes such as tungsten inert gas (TIG), variable polarity plasma arc (VPPA), electron beam (EB), etc., solid state welding processes do not melt the material during welding. The resultant microstructure can be characterized as a dynamically recrystallized morphology much different than the casted, dentritic structure typical of fusion weld processes. The primary benefits of solid state processes over fusion weld processes include superior mechanic properties and the elimination of thermal distortion and residual stresses. These solid state processes attributes have profoundly influenced the direction of advanced welding research and development within the NASA agency. Thermal Stir Welding (TSW) is a new solid state welding process being developed at the Marshall Space Flight Center. Unlike friction stir welding, the heating, stirring and forging elements of the weld process can be decoupled for independent control. An induction coil induces energy into a workpiece to attain a desired plastic temperature. An independently controlled stir rod, captured within non-rotating containment plates, then stirs the plasticized material followed by forging plates/rollers that work the stirred weld joint. The independent control (decoupling) of heating, stirring and forging allows, theoretically, for the precision control of microstructure morphology. The TSW process is being used to evaluate the solid state joining of Haynes 230 for ARES J-2X applications. It is also being developed for 500-in (12.5 mm) thick commercially pure grade 2 titanium for navy applications. Other interests include Inconel 718 and stainless steel. This presentation will provide metallurgical and mechanical property data for these high melting temperature alloys.

Low-field STIR imaging of avascular necrosis, marrow edema, and infarction

International Nuclear Information System (INIS)

Porter, B.A.; Schwartz, A.N.; Olson, D.O.

1987-01-01

Based on 12 months experience with low-field (0.15-T) short-T1 inversion recovery (STIR) imaging, the authors replaced T2-weighted spin echo (T2SE) images with STIR for avascular necrosis (AVN). With STIR (repetition time 1,600 echo time 36, inversion time 100, 2 Avg, 256 x 128), fat is black and edema or joint fluid is bright white; 14 contiguous images take less than 7 minutes and have much greater contrast than T1 or T2 SE images. MR examinations of 36 patients with suspected AVN, marrow edema, or infarction were reviewed. AVN was equally well diagnosed with T1 SE and STIR in 16 of 16 patients. However, small effusions and the extent of marrow edema or infarction were better delineated on STIR. Joints with effusions were almost always symptomatic. Asymptomatic AVN was detected and confirmed by pressure measurements. AVN or asymptomatic marrow infarction was detected in four of six renal transplant patients. Serial STIR imaging may allow clinical monitoring of AVN. STIR improves detection of effusion, permits shorter imaging time, and can replace T2SE for AVN

Formation of q bar q resonances in the bar NN system

International Nuclear Information System (INIS)

Ivanov, N.Ya.

1995-01-01

The formation of q bar q resonances lying on the leading Regge trajectories in the bar NN system is studied in the quark-gluon string model. The model predicts strong suppression of the decays of q bar q states into bar NN pairs in relation to two-meson modes. The author's analysis shows that the contributions of the resonances f 4 (2050) (I G J PC = 0 + 4 ++ ), ρ 5 (2240) (I G J PC = 1 + 5 -- ), and f 6 (2510) (I G J PC = 0 + 6 ++ ) to the processes of two-meson bar NN annihilation (bar pp → ππ, bar KK, hor-ellipsis) are about 1% of the corresponding experimental integrated cross sections. 30 refs., 2 figs., 1 tab

Friction stir method for forming structures and materials

Science.gov (United States)

Feng, Zhili; David, Stan A.; Frederick, David Alan

2011-11-22

Processes for forming an enhanced material or structure are disclosed. The structure typically includes a preform that has a first common surface and a recess below the first common surface. A filler is added to the recess and seams are friction stir welded, and materials may be stir mixed.

Production of n-bar's and Sigma-bar+-'s in e+e- annihilations

International Nuclear Information System (INIS)

Ferguson, T.; Buchanan, C.; Nodulman, L.; Poster, R.; Breidenbach, M.; Morehouse, C.C.; Vannucci, F.

1979-01-01

The production of antineutrons and charged Sigma-bar's in e + e - annihilations has been measured at √s +- production between 4 and 7 GeV is consistent with simple expectations for charmed-baryon production. A search for the decays Lambda-bar - /sub c/ → Sigma-bar +- π -+ π - and Sigma-baratsup asteriskat/sub c//Sigma-bar/sub c/ → Lambda-bar - /sub c/π +- yields no significant peaks. An upper limit, at the 90% confidence level, of sigmaatsub Lambda-baratc-italicB (Lambda-bar/sub c/ → Sigma-bar +- π -+ π - ) < 56 pb is set

Friction stir welding tool

Science.gov (United States)

Tolle,; Charles R. , Clark; Denis E. , Barnes; Timothy, A [Ammon, ID

2008-04-15

A friction stir welding tool is described and which includes a shank portion; a shoulder portion which is releasably engageable with the shank portion; and a pin which is releasably engageable with the shoulder portion.

Low temperature friction stir welding of P91 steel

Directory of Open Access Journals (Sweden)

Prasad Rao Kalvala

2016-08-01

Full Text Available Bead-on-plate friction stir welds were made on P91 alloy with low and high rotational speeds (100 and 1000 RPM to study their effects on weld microstructural changes and impression creep behavior. Temperatures experienced by the stir zone were recorded at the weld tool tip. Different zones of welds were characterized for their microstructural changes, hardness and creep behavior (by impression creep tests. The results were compared with submerged arc fusion weld. Studies revealed that the stir zone temperature with 100 RPM was well below Ac1 temperature of P91 steel while it was above Ac3 with 1000 RPM. The results suggest that the microstructural degradation in P91 welds can be controlled by low temperature friction stir welding technique.

Shear rate analysis of water dynamic in the continuous stirred tank

Science.gov (United States)

Tulus; Mardiningsih; Sawaluddin; Sitompul, O. S.; Ihsan, A. K. A. M.

2018-02-01

Analysis of mixture in a continuous stirred tank reactor (CSTR) is an important part in some process of biogas production. This paper is a preliminary study of fluid dynamic phenomenon in a continuous stirred tank numerically. The tank is designed in the form of cylindrical tank equipped with a stirrer. In this study, it is considered that the tank is filled with water. Stirring is done with a stirring speed of 10rpm, 15rpm, 20rpm, and 25rpm. Mathematical modeling of stirred tank is derived. The model is calculated by using the finite element method that are calculated using CFD software. The result shows that the shear rate is high on the front end portion of the stirrer. The maximum shear rate tend to a stable behaviour after the stirring time of 2 second. The relation between the speed and the maximum shear rate is in the form of linear equation.

Anisotropic chemical etching of semipolar {101-bar 1-bar}/{101-bar +1} ZnO crystallographic planes: polarity versus dangling bonds

International Nuclear Information System (INIS)

Palacios-Lidon, E; Perez-GarcIa, B; Colchero, J; Vennegues, P; Zuniga-Perez, J; Munoz-Sanjose, V

2009-01-01

ZnO thin films grown by metal-organic vapor phase epitaxy along the nonpolar [112-bar] direction and exhibiting semipolar {101-bar 1-bar}/{101-bar +1} facets have been chemically etched with HCl. In order to get an insight into the influence of the ZnO wurtzite structure in the chemical reactivity of the material, Kelvin probe microscopy and convergent beam electron diffraction have been employed to unambiguously determine the absolute polarity of the facets, showing that {101-bar +1} facets are unstable upon etching in an HCl solution and transform into (000+1)/{101-bar 1-bar} planes. In contrast, {101-bar 1-bar} undergo homogeneous chemical etching perpendicular to the initial crystallographic plane. The observed etching behavior has been explained in terms of surface oxygen dangling bond density, suggesting that the macroscopic polarity plays a secondary role in the etching process.

Four bars inn; Four bars inn

Energy Technology Data Exchange (ETDEWEB)

Nishiumi, T. [National Defense Academy, Kanagawa (Japan)

1999-05-15

The name Four Bars Inn puns on four drinking bars and four bars on a musical score. It is a public house sited on the busy St. Mary Street, Cardiff, England. During my stay in that town, I often attended the regular jam session that opened at the bar at nine o`clock every Monday evening. A jam session is an event in which any amateur player, and a professional artist occasionally, is allowed to come on the stage freely and to play jazz, the participation fee as low as 300-yen. It is an occasion that provides a friendly meeting of man and woman, young and old, everyone carrying a pint of ale. Senior people happily talking to young ones aged like their grandchildren certainly presents a heart-warming scene, which we scarcely encounter in Japan. The affection that the British entertain toward their domestic furnishings relayed down through many a generation may lead to their respect for senior citizens. I heartily look forward detecting like scenes some day at drinking spots in Japan where the consumption-happy days are over. (NEDO)

Derivation of asymptotic Vertical BarΔIVertical Bar = 1/2 rule

International Nuclear Information System (INIS)

Terasaki, K.; Oneda, S.

1982-01-01

It is argued that the origin of the observed approximate Vertical BarΔIVertical Bar = 1/2 rule is the presence of an asymptotic Vertical BarΔIVertical Bar = 1/2 rule which exists among certain two-body hadronic weak matrix elements, involving especially the ground-state hadrons

First Measurement of σ(gg → t$\\bar{t}$)/σ(p$\\bar{p}$ → t$\\bar{t}$)

Energy Technology Data Exchange (ETDEWEB)

Alamdari, Shabnaz Pashapour [Univ. of Toronto, ON (Canada)

2008-01-01

The work presented here is the first measurement of the fraction of top quark pair production through gluon-gluon fusion. We use an integrated luminosity of 0.96 ± 0.06 fb^-1 of p{bar p} collisions at √s of 1.96 TeV collected by the CDF II detector. We select t$\\bar{t}$ candidates by identifying a high-p_T lepton candidate, a large missing E_T as evidence for a neutrino candidate and at least four high E_T jets, one of which has to be identified as originating from a b quark. The challenge is to discriminate between the two production processes with the identical final state, gg → t$\\bar{t}$ and q$\\bar{p}$ → t$\\bar{t}$. We take advantage of the fact that compared to a quark, a gluon is more likely to radiate a low momentum gluon and therefore, one expects a larger number of charged particles with low p_T in a process involving more gluons. Given the large uncertainties associated with the modeling of the low p_T charged particle multiplicity, a data-driven technique was employed. Using calibration data samples, we show there exists a clear correlation between the observed average number of low p_T charged particles and the average number of gluons involved in the production process predicted by Monte Carlo calculations. Given the correlation, one can identify low p_T charged particle multiplicity distributions associated with specific average number of gluons. The W + 0 jet sample and dijets sample with leading jet E_T in the range of 80-100 GeV are used to find no-gluon and gluon-rich low p{sub T} charged particle multiplicity distributions, respectively. Using these no-gluon and gluon-rich distributions in a likelihood fit, we find the fraction of gluon-rich events in t{bar t} candidates. This fraction has contributions from the signal and background events. Taking into account these contributions and the gg → t$\\bar{t}$ and q$\\bar{q}$ → t$\\bar

Triangular fibrocartilage lesions: comparison STIR sequence versus arthroscopy findings

International Nuclear Information System (INIS)

Wang Zhi; Meng; Xianghong; Wang Linsen; Suo Yongmei

2013-01-01

Objective: To explore the diagnostic value of short TI inversion recovery (STIR) sequence in evaluating triangular fibrocartilage (TFC) lesions, and to compare the findings with the arthroscopy findings. Materials and Methods: Wrist joint MR examination using STIR sequence and arthroscopy were performed in 56 patients with TFC lesions. The parameters of STIR sequence were: TR: 1164 ms, TE: 16 ms, and TI: 90 ms. The sensibility, specificity, positive predictive value, negative predictive value, and accuracy in the diagnosis of TFC lesions with STIR sequence were calculated, using arthroscopy as the standard. Results: (1) STIR manifested 10 patients with normal TFC; 6 with small edema or mucous degeneration in the body portion but not involving joint surface edge; 6 with horizontal avulsion in the body portion, but not involving joint surface edge; 6 with avulsion involving joint surface edge; 11 with perforation in central portion; 6 with avulsion in radial attached end; 5 with avulsion in ulnar attached end; 3 with avulsion in both radial and ulnar attached ends; 3 with irregular shape and thin on the whole TFC. (2) Arthroscopy manifested 21 patients with normal TFC; 8 with avulsion involving joint surface edge; 10 with perforation in central portion; 7 with avulsion in radial attached end; 5 with avulsion in ulnar attached end; 2 with avulsion in both radial and ulnar attached ends; 3 with irregular shape on the whole TFC. Using STIR sequence, the sensibility, specificity, positive predictive value, negative predictive value. and accuracy were 85.7%, 23.8%, 65.2%, 50%, and 62.5%, respectively, in detection of TFC lesions, with arthroscopy as the standard. Conclusion: STIR sequence has high diagnostic value in detection of TFC lesions. (authors)

The He+H-bar → Hep-bar +e+ rearrangement

International Nuclear Information System (INIS)

Todd, Allan C.; Armour, Edward A.G.

2006-01-01

In this paper, we present a summary of our work in progress on calculating cross sections for the He+H-bar ->Hep-bar +e + rearrangement process in HeH-bar scattering. This has involved a study of the system Hep-bar within the Born-Oppenheimer (BO) approximation using the Rayleigh-Ritz variational method. This work has been reported in [A.C. Todd, E.A.G. Armour, J. Phys. B 38 (2005) 3367] and is summarised here. Similar calculations are in progress for the He+H-bar entrance channel. We intend to use the entrance channel and rearrangement channel wave functions to obtain the cross sections for the rearrangement using the distorted wave Born approximation T-matrix method described elsewhere in these proceedings [E.A.G. Armour, S. Jonsell, Y. Liu, A.C. Todd, these Proceedings, doi:10.1016/j.nimb.2006.01.049

Weld Nugget Temperature Control in Thermal Stir Welding

Science.gov (United States)

Ding, R. Jeffrey (Inventor)

2014-01-01

A control system for a thermal stir welding system is provided. The control system includes a sensor and a controller. The sensor is coupled to the welding system's containment plate assembly and generates signals indicative of temperature of a region adjacent and parallel to the welding system's stir rod. The controller is coupled to the sensor and generates at least one control signal using the sensor signals indicative of temperature. The controller is also coupled to the welding system such that at least one of rotational speed of the stir rod, heat supplied by the welding system's induction heater, and feed speed of the welding system's weld material feeder are controlled based on the control signal(s).

Friction stir welding of F82H steel for fusion applications

Energy Technology Data Exchange (ETDEWEB)

Noh, Sanghoon, E-mail: shnoh@kaeri.re.kr [Fusion Structural Materials Division, Japan Atomic Energy Agency, Rokkasho, Aomori (Japan); Nuclear Materials Division, Korea Atomic Energy Research Institute, Yuseong-gu, Daejeon (Korea, Republic of); Ando, Masami; Tanigawa, Hiroyasu [Fusion Structural Materials Division, Japan Atomic Energy Agency, Rokkasho, Aomori (Japan); Fujii, Hidetoshi [Joining and Welding Research Institute, Osaka University, Ibaraki, Osaka (Japan); Kimura, Akihiko [Institute of Advanced Energy, Kyoto University, Gokasho, Uji, Kyoto (Japan)

2016-09-15

In the present study, friction stir welding was employed to join F82H steels and develop a potential joining technique for a reduced activation ferritic/martensitic steel. The microstructures and mechanical properties on the joint region were investigated to evaluate the applicability of friction stir welding. F82H steel sheets were successfully butt-joined with various welding parameters. In welding conditions, 100 rpm and 100 mm/min, the stirred zone represented a comparable hardness distribution with a base metal. Stirred zone induced by 100 rpm reserved uniformly distributed precipitates and very fine ferritic grains, whereas the base metal showed a typical tempered martensite with precipitates on the prior austenite grain boundary and lath boundary. Although the tensile strength was decreased at 550 °C, the stirred zone treated at 100 rpm showed comparable tensile behavior with base metal up to 500 °C. Therefore, friction stir welding is considered a potential welding method to preserve the precipitates of F82H steel.

Friction stir welding of F82H steel for fusion applications

International Nuclear Information System (INIS)

Noh, Sanghoon; Ando, Masami; Tanigawa, Hiroyasu; Fujii, Hidetoshi; Kimura, Akihiko

2016-01-01

In the present study, friction stir welding was employed to join F82H steels and develop a potential joining technique for a reduced activation ferritic/martensitic steel. The microstructures and mechanical properties on the joint region were investigated to evaluate the applicability of friction stir welding. F82H steel sheets were successfully butt-joined with various welding parameters. In welding conditions, 100 rpm and 100 mm/min, the stirred zone represented a comparable hardness distribution with a base metal. Stirred zone induced by 100 rpm reserved uniformly distributed precipitates and very fine ferritic grains, whereas the base metal showed a typical tempered martensite with precipitates on the prior austenite grain boundary and lath boundary. Although the tensile strength was decreased at 550 °C, the stirred zone treated at 100 rpm showed comparable tensile behavior with base metal up to 500 °C. Therefore, friction stir welding is considered a potential welding method to preserve the precipitates of F82H steel.

Measurement of the asymmetry parameter for the decay $\\bar\\Lambda \\to \\bar p\\pi^+$

OpenAIRE

BES collaboration

2009-01-01

Based on a sample of $58\\times10^6J/\\psi$ decays collected with the BESII detector at the BEPC, the $\\bar\\Lambda$ decay parameter $\\alpha_{\\bar\\Lambda}$ for $\\bar\\Lambda\\to \\bar p \\pi^+$ is measured using about 9000 $J/\\psi\\to\\Lambda\\bar\\Lambda\\to p \\bar p \\pi^+\\pi^-$ decays. A fit to the joint angular distributions yields $\\alpha_{\\bar\\Lambda}(\\bar\\Lambda\\to \\bar p\\pi^+)=-0.755\\pm0.083\\pm0.063$, where the first error is statistical, and the second systematic.

Characterisation, quantity and sorptive properties of microplastics extracted from cosmetics.

Science.gov (United States)

Napper, Imogen E; Bakir, Adil; Rowland, Steven J; Thompson, Richard C

2015-10-15

Cosmetic products, such as facial scrubs, have been identified as potentially important primary sources of microplastics to the marine environment. This study characterises, quantifies and then investigates the sorptive properties of plastic microbeads that are used as exfoliants in cosmetics. Polyethylene microbeads were extracted from several products, and shown to have a wide size range (mean diameters between 164 and 327 μm). We estimated that between 4594 and 94,500 microbeads could be released in a single use. To examine the potential for microbeads to accumulate and transport chemicals they were exposed to a binary mixture of (3)H-phenanthrene and (14)C-DDT in seawater. The potential for transport of sorbed chemicals by microbeads was broadly similar to that of polythene (PE) particles used in previous sorption studies. In conclusion, cosmetic exfoliants are a potentially important, yet preventable source of microplastic contamination in the marine environment. Copyright © 2015 Elsevier Ltd. All rights reserved.

Steady shear viscosity of stirred yoghurts with varying ropiness

NARCIS (Netherlands)

van Marle, M.E.; van Marle, M.E.; van den Ende, Henricus T.M.; de Kruif, C.G.; de Kruif, C.G.; Mellema, J.

1999-01-01

Stirred yogurt was viewed as a concentrated dispersion of aggregates consisting of protein particles. The steady-shear behavior of three types of stirred yogurt with varying ropiness was investigated experimentally. To describe the shear-dependent viscosity, a microrheological model was used which

A Study of (bar B)0 --> D(*)0 (bar K)(*)0 Decays

International Nuclear Information System (INIS)

Aubert, B.

2004-01-01

The authors presented evidence for the decay (bar B) 0 --> D* 0 (bar K) 0 as well as new measurements of the branching fractions for the decays (bar B) 0 --> D 0 (bar K) 0 and D 0 (bar K)* 0 . Their measurements are in agreement with the expectation derived from a cited reference and with previous measurements. They use the central value of their measurement for B((bar B) 0 --> (bar D) 0 K* 0 ) and obtain τ < 0.8 at the 90% C.L. from a central value of τ = 0.4 ± 0.2 (stat.) ± 0.2 (syst.). The main contribution to the systematic uncertainty is from the estimated peaking background since most systematic uncertainties on the branching fractions cancel in the ratio

Retention model for sorptive extraction-thermal desorption of aqueous samples : application to the automated analysis of pesticides and polyaromatic hydrocarbons in water samples

NARCIS (Netherlands)

Baltussen, H.A.; David, F.; Sandra, P.J.F.; Janssen, J.G.M.; Cramers, C.A.M.G.

1998-01-01

In this report, an automated method for sorptive enrichment of aqueous samples is presented. It is based on sorption of the analytes of interest into a packed bed containing 100% polydimethylsiloxane (PDMS) particles followed by thermal desorption for complete transfer of the enriched solutes onto

Friction stir processing on high carbon steel U12

Energy Technology Data Exchange (ETDEWEB)

Tarasov, S. Yu., E-mail: tsy@ispms.ru; Rubtsov, V. E., E-mail: rvy@ispms.ru [Institute of Strength Physics and Materials Science SB RAS, Tomsk, 634055 (Russian Federation); National Research Tomsk Polytechnic University, Tomsk, 634050 (Russian Federation); Melnikov, A. G., E-mail: melnikov-ag@tpu.ru [National Research Tomsk Polytechnic University, Tomsk, 634050 (Russian Federation)

2015-10-27

Friction stir processing (FSP) of high carbon steel (U12) samples has been carried out using a milling machine and tools made of cemented tungsten carbide. The FSP tool has been made in the shape of 5×5×1.5 mm. The microstructural characterization of obtained stir zone and heat affected zone has been carried out. Microhardness at the level of 700 MPa has been obtained in the stir zone with microstructure consisting of large grains and cementitte network. This high-level of microhardness is explained by bainitic reaction developing from decarburization of austenitic grains during cementite network formation.

The value of STIR sequence in the characterization of mediastinal lymph nodes

Directory of Open Access Journals (Sweden)

Aylin Okur

2013-12-01

Full Text Available INTRODUCTION: To investigate availability of Short Time Inversion Recovery Turbo Spin Echo Magnetic Resonance imaging (STIR TSE MRI in the detection of mediastinal lymph nodes and in the distinguishing malign and benign lymph nodes detected in cases with pulmonary lesions. METHODS: Overall, 46 patients having mediastinal lymph nodes with confirmed or suspected lung cancer were included to the study. All patients underwent STIR TSE MR imaging before mediastinoscopy. Lymph nodes were assessed by signal characteristics on STIR TSE MRI. The results of histopathological evaluation and STIR TSE MRI were compared after mediastinoscopy. As data were qualitative, distributions were expressed as percentage and chi-square test was used to determine the difference between variables. RESULTS: Overall, 92 lymph nodes were analyzed. When a comparison was made between malign and benign lymph nodes, a significant difference was found between STIR MRI signal properties of lymph nodes and lymph node size. The specificity, sensitivity, positive predictive value and negative predictive value of STIR TSE MRI were estimated as 75.0%, 75.0%, 61.5% and 83.3%, respectively. DISCUSSION AND CONCLUSION: Although the negative predictive value is high in STIR TSE MRI, it has a low positive predictive value. Thus, the case may directly undergo surgery without performing mediastinoscopy when no malign lymph node is detected in STIR TSE MRI, while mediastinoscopy is warranted when a malign lymph node is detected.

Friction Stir Welding Process: A Green Technology

OpenAIRE

Esther T. Akinlabi; Stephen A. Akinlabi

2012-01-01

Friction Stir Welding (FSW) is a solid state welding process invented and patented by The Welding Institute (TWI) in the United Kingdom in 1991 for butt and lap welding of metals and plastics. This paper highlights the benefits of friction stir welding process as an energy efficient and a green technology process in the field of welding. Compared to the other conventional welding processes, its benefits, typical applications and its use in joining similar and dissimilar materia...

Microstructure Evolution during Friction Stir Spot Welding of TRIP Steel

DEFF Research Database (Denmark)

Lomholt, Trine Colding; Pantleon, Karen; Somers, Marcel A. J.

2010-01-01

In this study, the feasibility of friction stir spot welding of TRIP steel is investigated. In addition to manufacturing successful welds, the present study aims at a fundamental understanding of the mechanisms occurring at the (sub)micron scale during friction stir spot welding. As one of the ma...... electron microscopy, and electron backscatter diffraction. Microhardness measurements and lap-shear tensile tests completed the investigations of the welded samples and allow evaluation of the quality of the welds.......In this study, the feasibility of friction stir spot welding of TRIP steel is investigated. In addition to manufacturing successful welds, the present study aims at a fundamental understanding of the mechanisms occurring at the (sub)micron scale during friction stir spot welding. As one of the main...... parameters to control friction stir welding, the influence of the rotational speed of the tool was investigated. Three different rotational speeds (500 rpm, 1000 rpm and 1500 rpm, respectively) were applied. The microstructure of the welded samples was investigated with reflected light microscopy, scanning...

The Carnegie-Irvine Galaxy Survey. V. Statistical Study of Bars and Buckled Bars

Science.gov (United States)

Li, Zhao-Yu; Ho, Luis C.; Barth, Aaron J.

2017-08-01

Simulations have shown that bars are subject to a vertical buckling instability that transforms thin bars into boxy or peanut-shaped structures, but the physical conditions necessary for buckling to occur are not fully understood. We use the large sample of local disk galaxies in the Carnegie-Irvine Galaxy Survey to examine the incidence of bars and buckled bars across the Hubble sequence. Depending on the disk inclination angle (I), a buckled bar reveals itself as either a boxy/peanut-shaped bulge (at high I) or as a barlens structure (at low I). We visually identify bars, boxy/peanut-shaped bulges, and barlenses, and examine the dependence of bar and buckled bar fractions on host galaxy properties, including Hubble type, stellar mass, color, and gas mass fraction. We find that the barred and unbarred disks show similar distributions in these physical parameters. The bar fraction is higher (70%-80%) in late-type disks with low stellar mass (M * 1010.5 M ⊙), and decreases with higher gas mass ratio. These results suggest that bars are more difficult to grow in massive disks that are dynamically hotter than low-mass disks. However, once a bar forms, it can easily buckle in the massive disks, where a deeper potential can sustain the vertical resonant orbits. We also find a probable buckling bar candidate (ESO 506-G004) that could provide further clues to understand the timescale of the buckling process.

Lateral position detection and control for friction stir systems

Science.gov (United States)

Fleming, Paul; Lammlein, David; Cook, George E.; Wilkes, Don Mitchell; Strauss, Alvin M.; Delapp, David; Hartman, Daniel A.

2010-12-14

A friction stir system for processing at least a first workpiece includes a spindle actuator coupled to a rotary tool comprising a rotating member for contacting and processing the first workpiece. A detection system is provided for obtaining information related to a lateral alignment of the rotating member. The detection system comprises at least one sensor for measuring a force experienced by the rotary tool or a parameter related to the force experienced by the rotary tool during processing, wherein the sensor provides sensor signals. A signal processing system is coupled to receive and analyze the sensor signals and determine a lateral alignment of the rotating member relative to a selected lateral position, a selected path, or a direction to decrease a lateral distance relative to the selected lateral position or selected path. In one embodiment, the friction stir system can be embodied as a closed loop tracking system, such as a robot-based tracked friction stir welding (FSW) or friction stir processing (FSP) system.

Hybrid friction stir welding for dissimilar materials through electro-plastic effect

Science.gov (United States)

Liu, Xun; Lan, Shuhuai; Ni, Jun

2018-05-29

A hybrid Friction Stir Welding approach and device for dissimilar materials joining employing Electro-Plastic Effect. The approach and device include an introduction of high density, short period current pulses into traditional friction stir welding process, which therefore can generate a localized softened zone in the workpiece during plastic stirring without significant additional temperature increase. This material softened zone is created by high density current pulses based on Electro-Plastic Effect and will move along with the friction stir welding tool. Smaller downward force, larger processing window and better joint quality for dissimilar materials are expected to be achieved through this hybrid welding technique.

The Carnegie-Irvine Galaxy Survey. V. Statistical Study of Bars and Buckled Bars

Energy Technology Data Exchange (ETDEWEB)

Li, Zhao-Yu [Key Laboratory for Research in Galaxies and Cosmology, Shanghai Astronomical Observatory, Chinese Academy of Science, 80 Nandan Road, Shanghai 200030 (China); Ho, Luis C. [Kavli Institute for Astronomy and Astrophysics, Peking University, Beijing 100871 (China); Barth, Aaron J., E-mail: lizy@shao.ac.cn [Department of Physics and Astronomy, 4129 Frederick Reines Hall, University of California, Irvine, CA, 92697-4575 (United States)

2017-08-10

Simulations have shown that bars are subject to a vertical buckling instability that transforms thin bars into boxy or peanut-shaped structures, but the physical conditions necessary for buckling to occur are not fully understood. We use the large sample of local disk galaxies in the Carnegie-Irvine Galaxy Survey to examine the incidence of bars and buckled bars across the Hubble sequence. Depending on the disk inclination angle ( i ), a buckled bar reveals itself as either a boxy/peanut-shaped bulge (at high i ) or as a barlens structure (at low i ). We visually identify bars, boxy/peanut-shaped bulges, and barlenses, and examine the dependence of bar and buckled bar fractions on host galaxy properties, including Hubble type, stellar mass, color, and gas mass fraction. We find that the barred and unbarred disks show similar distributions in these physical parameters. The bar fraction is higher (70%–80%) in late-type disks with low stellar mass ( M {sub *} < 10{sup 10.5} M {sub ⊙}) and high gas mass ratio. In contrast, the buckled bar fraction increases to 80% toward massive and early-type disks ( M {sub *} > 10{sup 10.5} M {sub ⊙}), and decreases with higher gas mass ratio. These results suggest that bars are more difficult to grow in massive disks that are dynamically hotter than low-mass disks. However, once a bar forms, it can easily buckle in the massive disks, where a deeper potential can sustain the vertical resonant orbits. We also find a probable buckling bar candidate (ESO 506−G004) that could provide further clues to understand the timescale of the buckling process.

Decays of Higgs bosons to bb-bar, ττ-bar, and cc-bar as signatures of supersymmetry and CP phases

International Nuclear Information System (INIS)

Ibrahim, Tarek; Nath, Pran

2003-01-01

The branching ratio of the lightest Higgs boson decay into bb(bar sign), ττ-bar and cc-bar is sensitive to supersymmetric effects. We include in this work the effects of CP phases on the Higgs boson decays. Specifically we compute the deviation of the CP phase dependent branching ratio from the standard model result. The analysis includes the full one loop corrections of fermion masses including CP phases involving the gluino, the chargino and the neutralino exchanges. The analysis shows that the supersymmetric effects with CP phases can change the branching ratios by as much as 100% for the lightest Higgs boson decay into bb(bar sign) and ττ-bar with similar results holding for the heavier Higgs boson decays. A detailed analysis is also given for the effects of CP phases on the Higgs boson decays into cc-bar. The deviations of R b/τ and R b/c from the standard model result are investigated as a possible signature of supersymmetry and CP effects. Thus a measurement of the decays of the Higgs boson into bb-bar, ττ-bar and cc-bar may provide important clues regarding the existence of supersymmetry and CP phases

Recent Trends in Microextraction Techniques Employed in Analytical and Bioanalytical Sample Preparation

Directory of Open Access Journals (Sweden)

Abuzar Kabir

2017-12-01

Full Text Available Sample preparation has been recognized as a major step in the chemical analysis workflow. As such, substantial efforts have been made in recent years to simplify the overall sample preparation process. Major focusses of these efforts have included miniaturization of the extraction device; minimizing/eliminating toxic and hazardous organic solvent consumption; eliminating sample pre-treatment and post-treatment steps; reducing the sample volume requirement; reducing extraction equilibrium time, maximizing extraction efficiency etc. All these improved attributes are congruent with the Green Analytical Chemistry (GAC principles. Classical sample preparation techniques such as solid phase extraction (SPE and liquid-liquid extraction (LLE are being rapidly replaced with emerging miniaturized and environmentally friendly techniques such as Solid Phase Micro Extraction (SPME, Stir bar Sorptive Extraction (SBSE, Micro Extraction by Packed Sorbent (MEPS, Fabric Phase Sorptive Extraction (FPSE, and Dispersive Liquid-Liquid Micro Extraction (DLLME. In addition to the development of many new generic extraction sorbents in recent years, a large number of molecularly imprinted polymers (MIPs created using different template molecules have also enriched the large cache of microextraction sorbents. Application of nanoparticles as high-performance extraction sorbents has undoubtedly elevated the extraction efficiency and method sensitivity of modern chromatographic analyses to a new level. Combining magnetic nanoparticles with many microextraction sorbents has opened up new possibilities to extract target analytes from sample matrices containing high volumes of matrix interferents. The aim of the current review is to critically audit the progress of microextraction techniques in recent years, which has indisputably transformed the analytical chemistry practices, from biological and therapeutic drug monitoring to the environmental field; from foods to phyto

Additional merit of coronal STIR imaging for MR imaging of lumbar spine

Directory of Open Access Journals (Sweden)

Ranjana Gupta

2015-01-01

Full Text Available Introduction: Back pain is a common clinical problem and is the frequent complaint for referral of lumbar spine magnetic resonance imaging (MRI. Coronal short tau inversion recovery sequence (STIR can provide diagnostically significant information in small percentage of patients. Materials and Methods: MRI examinations of a total of 350 patients were retrospectively included in the study. MR sequences were evaluated in two settings. One radiologist evaluated sagittal and axial images only, while another radiologist evaluated all sequences, including coronal STIR sequence. After recording the diagnoses, we compared the MRI findings in two subsets of patients to evaluate additional merit of coronal STIR imaging. Results: With addition of coronal STIR imaging, significant findings were observed in 24 subjects (6.8%. Twenty-one of these subjects were considered to be normal on other sequences and in three subjects diagnosis was changed with the addition of coronal STIR. Additional diagnoses on STIR included sacroiliitis, sacroiliac joint degenerative disease, sacral stress/insufficiency fracture/Looser′s zones, muscular sprain and atypical appendicitis. Conclusion: Coronal STIR imaging can provide additional diagnoses in a small percentage of patients presenting for lumbar spine MRI for back pain. Therefore, it should be included in the routine protocol for MR imaging of lumbar spine.

Program plan: DWPF/HLWDP stirred Melter Program Plan

International Nuclear Information System (INIS)

Smith, M.E.

1994-01-01

Slurry Fed Melters (SFM) have been developed in the United States, Europe, and Japan for the conversion of high-level radioactive waste (HLW) to borosilicate glass for permanent disposal. The newest design, the stirred melter, combines the high production rates and high glass quality features of the Joule-heated melters with the low-cost, compact, simple maintenance features of the pot melters. However, further engineering design and demonstrations are needed to operate the stirred melter on a large scale. This document outlines the program which develops a full scale stirred melter for the DWPF (240 pph), and provides a basis which will allow further scale-up of the technology for use in the Hanford High Level Waste Disposal Program (HLWDP) for up to four times the reference capacity

Studying W‧ boson contributions in \\bar{B} \\rightarrow {D}^{(* )}{{\\ell }}^{-}{\\bar{\

Science.gov (United States)

Wang, Yi-Long; Wei, Bin; Sheng, Jin-Huan; Wang, Ru-Min; Yang, Ya-Dong

2018-05-01

Recently, the Belle collaboration reported the first measurement of the τ lepton polarization P τ (D*) in \\bar{B}\\to {D}* {τ }-{\\bar{ν }}τ decay and a new measurement of the rate of the branching ratios R(D*), which are consistent with the Standard Model (SM) predictions. These could be used to constrain the New Physics (NP) beyond the SM. In this paper, we probe \\bar{B}\\to {D}(* ){{\\ell }}-{\\bar{ν }}{\\ell } (ℓ = e, μ, τ) decays in the model-independent way and in the specific G(221) models with lepton flavour universality. Considering the theoretical uncertainties and the experimental errors at the 95% C.L., we obtain the quite strong bounds on the model-independent parameters {C}{{LL}}{\\prime },{C}{{LR}}{\\prime },{C}{{RR}}{\\prime },{C}{{RL}}{\\prime },{g}V,{g}A,{g}V{\\prime },{g}A{\\prime } and the specific G(221) model parameter rates. We find that the constrained NP couplings have no obvious effects on all (differential) branching ratios and their rates, nevertheless, many NP couplings have very large effects on the lepton spin asymmetries of \\bar{B}\\to {D}(* ){{\\ell }}-{\\bar{ν }}{\\ell } decays and the forward–backward asymmetries of \\bar{B}\\to {D}* {{\\ell }}-{\\bar{ν }}{\\ell }. So we expect precision measurements of these observables would be researched by LHCb and Belle-II.

Study of the {rho}-bar, {beta}-bar and {lambda} parameters of a light-water reactor; Etude des parametres {rho}-bar, {beta}-bar et {lambda} d'une pile a eau legere

Energy Technology Data Exchange (ETDEWEB)

Riche, R [Commissariat a l' Energie Atomique, Grenoble (France). Centre d' Etudes Nucleaires

1965-09-01

The kinetic and perturbation equations are derived from the time-dependent transport equation. Kinetic equations depend only on the ratios a = {rho}-bar/{beta}-bar and b = {beta}-bar/{lambda}, which are definite, while the reactivity {rho}-bar, the delayed neutron fraction ({beta}-bar and the generation time {lambda} are expressed in terms of an arbitrary function I. The 'static' definitions of these parameters, which reduce kinetic problems to a set of purely term dependent equations, introduce the effective fraction {beta}-bar. One way of determining experimentally the ratio b is presented; it consists in analysing the power transient after a rapid variation of the reactivity, caused by the implosion of an empty glass-bull. A simple interpretation is proposed. The apparatus can be transformed easily into a reactimeter. The value of the effective delayed neutron fraction {beta}-bar has been determined by averaging the reactivity effects of a copper sheet through out the reactor core. Experimental results: b = {beta}-bar/{lambda} = 129 s{sup -1} and {beta}-bar 795.10{sup -5}, have been determined on a light-water moderated, enriched-uranium fuelled reactor. The calculated values of the effectiveness of delayed neutrons {gamma} {beta}-bar/{beta} 1.23 and the generation time {lambda} 59.10{sup -6}s agrees fairly well with the experimental results. (author) [French] Les equations de la cinetique et de la perturbation sont deduites de la theorie du transport, par l'intermediaire de la 'notion' d'importance des neutrons. La cinetique ne depend que des rapports a = {rho}-bar/{beta}-bar et b = {beta}-bar/{lambda}, qui sont parfaitement definis; par contre, la reactivite {rho}-bar, la proportion de neutrons retardes {beta}-bar et le temps de generation des neutrons prompts {lambda} s'expriment a l'aide d'une meme fonction arbitraire I. Les definitions 'statiques' de ces parametres, qui permettent de rendre compte de la cinetique par des equations dependant purement du

Superplastic forming of 7475 Al sheet after friction stir processing (FSP)

Energy Technology Data Exchange (ETDEWEB)

Mahoney, M.; Bingel, W.H.; Fuller, C. [Rockwell Scientific Co., Thousand Oaks, CA (United States); Barnes, A.J. [Superform USA, Riverside, CA (United States)

2004-07-01

Since the invention of friction stir welding (FSW) in 1991, an increasing number of successful applications have been found for this unique solid-state welding technique. More recently, attention has been given to utilizing the mechanics of friction stirring to thermo-mechanically modify the microstructure of aluminum alloys to create or enhance superplasticity. Until now, superplasticity induced by friction stir processing (FSP) has only been demonstrated in small samples and evaluated by hot tensile elongation testing. The present work describes what we believe to be the first biaxial testing and full size component superplastic forming of friction stir processed aluminum sheet. The remarkable formability demonstrated in these 'first time' trials is described in detail. (orig.)

Stirring turbulence with turbulence

NARCIS (Netherlands)

Cekli, H.E.; Joosten, R.; van de Water, W.

2015-01-01

We stir wind-tunnel turbulence with an active grid that consists of rods with attached vanes. The time-varying angle of these rods is controlled by random numbers. We study the response of turbulence on the statistical properties of these random numbers. The random numbers are generated by the

H-bar and H-bar + production cross sections for the GBAR experiment

International Nuclear Information System (INIS)

Comini, P; Hervieux, P-A

2013-01-01

The production and cooling of the H-bar + ion is the key point of the GBAR experiment (Gravitational Behaviour of Antihydrogen at Rest), which aims at performing the free fall of antihydrogen atoms to measure g-bar , the acceleration of antimatter on Earth. H-bar + ions will be obtained from collisions between a positronium cloud and antiprotons delivered by the AD/ELENA facility at CERN, with intermediate formation of antihydrogen atoms. In order to optimise the experimental production of H-bar + ions, we computed the total cross sections of the two corresponding reactions, within the same theoretical framework of the Continuum Distorted Wave – Final State (CDW-FS) model. The different contributions of the H-bar excited states have been systematically investigated for different states of Ps. The results exhibit an increase of the H-bar production toward low kinetic energies, in agreement with experimental data and previous calculations, whereas the largest H-bar + production is obtained with low energy ground-state antihydrogen atoms. These theoretical predictions suggest that the overall production of H-bar + could be optimal for 2 keV antiproton impact energy, using positronium atoms prepared in the 2p state.

K-bar-mesic nuclei

International Nuclear Information System (INIS)

Dote, Akinobu; Akaishi, Yoshinori; Yamazaki, Toshimitsu

2005-01-01

New nuclei 'K-bar-Mesic Nuclei' having the strangeness are described. At first it is shown that the strongly attractive nature of K-bar N interaction is reasoned inductively from consideration of the relation between Kaonic hydrogen atom and Λ (1405) which is an excited state of hyperon Λ. The K-bar N interactions are reviewed and summarized into three categories: 1. Phenomenological approach with density dependent K-bar N interaction (DD), relativistic mean field (RMF) approach, and hybrid of them (RMF+DD). 2. Boson exchange model. 3. Chiral SU(3) theory. The investigation of some light K-bar-nuclei by Akaishi and Yamazaki using phenomenological K-bar N interaction is explained in detail. Studies by antisymmetrized molecular dynamics (AMD) approach are also presented. From these theoretical researches, the following feature of K-bar-mesic nuclei are revealed: 1) Ground state is discrete and bound by 100 MeV or more. 2) Density is very high in side the K-bar-mesic nuclei. 3) Strange structures develop which are not seen in ordinary nuclei. Finally some recent experiments to explore K-bar-mesic nuclei are reviewed. (S. Funahashi)

Ultra-trace determination of Persistent Organic Pollutants in Artic ice using stir bar sorptive extraction and gas chromatography coupled to mass spectrometry

OpenAIRE

Lacorte Bruguera, Silvia; Quintana, Jordi; Tauler, Romà; Ventura, Francesc; Tovar-Sánchez, Antonio; Duarte, Carlos M.

2010-01-01

This study presents the optimization and application of an analytical method based on the use of stirbarsorptiveextraction (SBSE) gaschromatographycoupled to massspectrometry (GC–MS) for the ultra-trace analysis of POPs (PersistentOrganicPollutants) in Arctic ice. In a first step, the mass-spectrometry conditions were optimized to quantify 48 compounds (polycyclic aromatic hydrocarbons, brominated diphenyl ethers, chlorinated biphenyls, and organochlorinated pesticides) at the low pg/L level....

Heat Control via Torque Control in Friction Stir Welding

Science.gov (United States)

Venable, Richard; Colligan, Kevin; Knapp, Alan

2004-01-01

In a proposed advance in friction stir welding, the torque exerted on the workpiece by the friction stir pin would be measured and controlled in an effort to measure and control the total heat input to the workpiece. The total heat input to the workpiece is an important parameter of any welding process (fusion or friction stir welding). In fusion welding, measurement and control of heat input is a difficult problem. However, in friction stir welding, the basic principle of operation affords the potential of a straightforward solution: Neglecting thermal losses through the pin and the spindle that supports it, the rate of heat input to the workpiece is the product of the torque and the speed of rotation of the friction stir weld pin and, hence, of the spindle. Therefore, if one acquires and suitably processes data on torque and rotation and controls the torque, the rotation, or both, one should be able to control the heat input into the workpiece. In conventional practice in friction stir welding, one uses feedback control of the spindle motor to maintain a constant speed of rotation. According to the proposal, one would not maintain a constant speed of rotation: Instead, one would use feedback control to maintain a constant torque and would measure the speed of rotation while allowing it to vary. The torque exerted on the workpiece would be estimated as the product of (1) the torque-multiplication ratio of the spindle belt and/or gear drive, (2) the force measured by a load cell mechanically coupled to the spindle motor, and (3) the moment arm of the load cell. Hence, the output of the load cell would be used as a feedback signal for controlling the torque (see figure).

Recent developments in Micro Friction Stir Welding: A review

International Nuclear Information System (INIS)

Sithole, Keydon; Rao, Veeredhi Vasudeva

2016-01-01

The advent of friction stir welding (FSW) in 1991 has been evolutionary in the joining of metals and related materials. Friction stir welding has enabled the joining of metals that could not be joined by other welding processes. Research has shown that dissimilar materials with very different properties, plastics, composites and even wood can be joined by FSW. Recent activities in the application of FSW has seen the development of micro friction stir welding (μFSW), which is the FSW of very thin sections of thickness 1000 μm (1 mm) or less. Micro friction stir welding further extends the applications of FSW to areas such as copper electrical contacts, tailor-welded blanks, wood. Though μFSW is relatively new development significant work has been done to date with interesting research findings being reported. This paper aims to review developments in μFSW to date. The focus of the paper will be on problems peculiar to μFSW due to downscaling to the micro scale and other practical considerations. (paper)

Bar-tailed

NARCIS (Netherlands)

Duijns, S.; Hidayati, N.A.; Piersma, T.

2013-01-01

Capsule Across the European wintering range Bar-tailed Godwits Limosa lapponica lapponica selected polychaete worms and especially Ragworms Hediste diversicolor, with differences between areas due to variations in prey availability.Aims To determine the diet of Bar-tailed Godwits across their

Calibration and performance of a stirred benthic chamber

Science.gov (United States)

Buchholtz-ten Brink, M. R.; Gust, G.; Chavis, D.

1989-07-01

The physical and chemical boundary layer parameters characteristic for a benthic chamber were cross-calibrated by the use of two methods in the laboratory: (1) flush-mounted hot-film sensors, which measure the friction velocity u ∗, and (2) the alabaster dissolution technique, which measures the equivalent film thickness z. Tests of five stirring devices were made, using both techniques, to improve the stirring mechanism in the MANOP Lander flux chambers. The stirring device that was finally implemented consisted of four rods and produced spatially averaged friction velocities u ∗ ranging from 0.1 to 0.5 cm s -1 (i.e. mean film thickness z from 500 to 180 μm) when running at speeds from 3 to 9 rpm. The friction velocity field at the sediment surface is related to the rpm of the stirring device and the penetration depth of the chamber into the sediments; combinations of both can create z and u ∗ inside the chamber that duplicate those of many natural environments. The log-log calibration relationship found between u ∗ and transfer coefficients K' also provides a means to predict the mass-transfer resistance of solutes at the sediment-water interface from measurements of mean bottom stress.

Possible heavy tetraquarks qQq-barQ-bar, qqQ-barQ-bar and qQQ-barQ-bar

International Nuclear Information System (INIS)

Cui Ying; Chen Xiaolin; Deng Weizhen; Zhu Shilin

2007-01-01

Assuming X(3872) is a qcq-barc-bar tetraquark and using its mass as input, the authors perform a schematic study of the masses of possible heavy tetraquarks using the color-magnetic interaction with the flavor symmetry breaking corrections. (authors)

Weld defect identification in friction stir welding using power spectral density

Science.gov (United States)

Das, Bipul; Pal, Sukhomay; Bag, Swarup

2018-04-01

Power spectral density estimates are powerful in extraction of useful information retained in signal. In the current research work classical periodogram and Welch periodogram algorithms are used for the estimation of power spectral density for vertical force signal and transverse force signal acquired during friction stir welding process. The estimated spectral densities reveal notable insight in identification of defects in friction stir welded samples. It was observed that higher spectral density against each process signals is a key indication in identifying the presence of possible internal defects in the welded samples. The developed methodology can offer preliminary information regarding presence of internal defects in friction stir welded samples can be best accepted as first level of safeguard in monitoring the friction stir welding process.

On Modified Bar recursion

DEFF Research Database (Denmark)

Oliva, Paulo Borges

2002-01-01

Modified bar recursion is a variant of Spector's bar recursion which can be used to give a realizability interpretation of the classical axiom of dependent choice. This realizability allows for the extraction of witnesses from proofs of forall-exists-formulas in classical analysis. In this talk I...... shall report on results regarding the relationship between modified and Spector's bar recursion. I shall also show that a seemingly weak form of modified bar recursion is as strong as "full" modified bar recursion in higher types....

The bridge technique for pectus bar fixation: a method to make the bar un-rotatable.

Science.gov (United States)

Park, Hyung Joo; Kim, Kyung Soo; Moon, Young Kyu; Lee, Sungsoo

2015-08-01

Pectus bar rotation is a major challenge in pectus repair. However, to date, no satisfactory technique to completely eliminate bar displacement has been introduced. Here, we propose a bar fixation technique using a bridge that makes the bar unmovable. The purpose of this study was to determine the efficacy of this bridge technique. A total of 80 patients underwent pectus bar repair of pectus excavatum with the bridge technique from July 2013 to July 2014. The technique involved connecting 2 parallel bars using plate-screws at the ends of the bars. To determine bar position change, the angles between the sternum and pectus bars were measured on postoperative day 5 (POD5) and 4 months (POM4) and compared. The mean patient age was 17.5 years (range, 6-38 years). The mean difference between POD5 and POM4 were 0.23° (P=.602) and 0.35° (P=.338) for the upper and lower bars, respectively. Bar position was virtually unchanged during the follow-up, and there was no bar dislocation or reoperation. A "bridge technique" designed to connect 2 parallel bars using plates and screws was demonstrated as a method to avoid pectus bar displacement. This approach was easy to implement without using sutures or invasive devices. Copyright © 2015 Elsevier Inc. All rights reserved.

Optimizing the stirring strategy for the vibrating intrinsic reverberation chamber

NARCIS (Netherlands)

Serra, Ramiro; Serra, Ramiro; Leferink, Frank Bernardus Johannes

2010-01-01

This work describes the definition, application and assessment of a factorial plan with the aim of gaining insight on what kind of stirring strategy could work the best in a vibrating intrinsic reverberation chamber. Three different stirring strategies were defined as factors of a factorial

continuous stirred tank reactor (CSTR)

African Journals Online (AJOL)

AFRICAN JOURNALS ONLINE (AJOL) · Journals · Advanced Search ... stirred tank reactor (CSTR) and the small and large intestines as plug flow reactor (PFR) ... from the two equations are used for the reactor sizing of the modeled reactors.

Applications of Friction Stir Processing during Engraving of Soft Materials

Directory of Open Access Journals (Sweden)

V. Kočović

2015-12-01

Full Text Available Friction stir processing has extensive application in many technological operations. Application area of friction stir processing can be extended to the processing of non-metallic materials, such as wood. The paper examines the friction stir processing contact between a specially designed hard and temperature-resistant rotating tool and workpiece which is made of wood. Interval of speed slip and temperature level under which the combustion occurs and carbonization layer of soft material was determined. The results of the research can be applied in technological process of wood engraving operations which may have significant technological and aesthetic effects.

Post-acquisition data processing for the screening of transformation products of different organic contaminants. Two-year monitoring of river water using LC-ESI-QTOF-MS and GCxGC-EI-TOF-MS.

Science.gov (United States)

López, S Herrera; Ulaszewska, M M; Hernando, M D; Martínez Bueno, M J; Gómez, M J; Fernández-Alba, A R

2014-11-01

This study describes a comprehensive strategy for detecting and elucidating the chemical structures of expected and unexpected transformation products (TPs) from chemicals found in river water and effluent wastewater samples, using liquid chromatography coupled to electrospray ionization quadrupole-time-of-flight mass spectrometer (LC-ESI-QTOF-MS), with post-acquisition data processing and an automated search using an in-house database. The efficacy of the mass defect filtering (MDF) approach to screen metabolites from common biotransformation pathways was tested, and it was shown to be sufficiently sensitive and applicable for detecting metabolites in environmental samples. Four omeprazole metabolites and two venlafaxine metabolites were identified in river water samples. This paper reports the analytical results obtained during 2 years of monitoring, carried out at eight sampling points along the Henares River (Spain). Multiresidue monitoring, for targeted analysis, includes a group of 122 chemicals, amongst which are pharmaceuticals, personal care products, pesticides and PAHs. For this purpose, two analytical methods were used based on direct injection with a LC-ESI-QTOF-MS system and stir bar sorptive extraction (SBSE) with bi-dimensional gas chromatography coupled with a time-of-flight spectrometer (GCxGC-EI-TOF-MS).

Analysis of mechano-sorptive effect in oscillatory drying of beech timber

Directory of Open Access Journals (Sweden)

Milić Goran

2016-01-01

Full Text Available The paper shows results of analysis of influences of oscillating parameters of drying on measuring wood moisture content in the kiln, rate and quality of drying. For this analysis, we used a conventional drying cycle, a cycle with oscillating equilibrium moisture content (EMC, and a cycle with oscillating temperatures. A special software tool was created for managing the oscillations. It was shown that oscillations of EMC and temperatures result in cyclic changes in wood MC, but also in the additional inaccuracies of MC measurements in the kiln. The drying process of the cycle with oscillating EMC lasted somewhat shorter than the other two cycles. Drying quality was the same or better in the cycles with oscillations as compared to the conventionally dried cycle, and the smaller tensions in the wood confirmed the activation of the additional mechano-sorptive effect during cyclic changes of MC in surface layers. [Projekat Ministarstva nauke Republike Srbije, br. TR 31041 i br. TR 37008

Search for W→cs-bar, Z→cc-bar,bb-bar in muon-jet events at the CERN proton-antiproton collider

International Nuclear Information System (INIS)

Ransdell, J.

1988-01-01

A search for quark decays of the W and Z particles produced in proton-antiproton collisions at √s of 630 GeV in the UA1 experiment at the CERN collider is described. The search was made in the channels W→cs-bar, Z→cc-bar,bb-bar where b and c quarks were identified by the presence of a high-p/sub T/ muon in or near a jet. Although these decay channels avoid the copious background of QCD produced light quark and gluon jets, it was not possible to detect a W or Z signal because of the large cross section for strong cc-bar and bb-bar production

Study of the {rho}-bar, {beta}-bar and {lambda} parameters of a light-water reactor; Etude des parametres {rho}-bar, {beta}-bar et {lambda} d'une pile a eau legere

Energy Technology Data Exchange (ETDEWEB)

Riche, R. [Commissariat a l' Energie Atomique, Grenoble (France). Centre d' Etudes Nucleaires

1965-09-01

The kinetic and perturbation equations are derived from the time-dependent transport equation. Kinetic equations depend only on the ratios a = {rho}-bar/{beta}-bar and b = {beta}-bar/{lambda}, which are definite, while the reactivity {rho}-bar, the delayed neutron fraction ({beta}-bar and the generation time {lambda} are expressed in terms of an arbitrary function I. The 'static' definitions of these parameters, which reduce kinetic problems to a set of purely term dependent equations, introduce the effective fraction {beta}-bar. One way of determining experimentally the ratio b is presented; it consists in analysing the power transient after a rapid variation of the reactivity, caused by the implosion of an empty glass-bull. A simple interpretation is proposed. The apparatus can be transformed easily into a reactimeter. The value of the effective delayed neutron fraction {beta}-bar has been determined by averaging the reactivity effects of a copper sheet through out the reactor core. Experimental results: b = {beta}-bar/{lambda} = 129 s{sup -1} and {beta}-bar 795.10{sup -5}, have been determined on a light-water moderated, enriched-uranium fuelled reactor. The calculated values of the effectiveness of delayed neutrons {gamma} {beta}-bar/{beta} 1.23 and the generation time {lambda} 59.10{sup -6}s agrees fairly well with the experimental results. (author) [French] Les equations de la cinetique et de la perturbation sont deduites de la theorie du transport, par l'intermediaire de la 'notion' d'importance des neutrons. La cinetique ne depend que des rapports a = {rho}-bar/{beta}-bar et b = {beta}-bar/{lambda}, qui sont parfaitement definis; par contre, la reactivite {rho}-bar, la proportion de neutrons retardes {beta}-bar et le temps de generation des neutrons prompts {lambda} s'expriment a l'aide d'une meme fonction arbitraire I. Les definitions 'statiques' de ces parametres, qui permettent de rendre compte de la

Microstructure and properties of friction stir butt-welded AZ31 magnesium alloy

International Nuclear Information System (INIS)

Wang Xunhong; Wang Kuaishe

2006-01-01

Friction stir welding (FSW) is a relatively new joining technique particularly for magnesium and aluminum alloys that are difficult to fusion weld. In this paper, an excellent friction stir weld of AZ31 magnesium alloy was obtained at proper parameter. In the friction stir zone (FSZ), the microstructure of the base material (BM) is replaced by fine grains and small particles of intermetallic compounds. The average microhardness of the friction stir zone is higher than that of the base material. The maximum tensile strength of joint can reach 93% that of the base material. And the failure locations are almost at the heating affected zone

Bar-spheroid interaction in galaxies

Science.gov (United States)

Hernquist, Lars; Weinberg, Martin D.

1992-01-01

N-body simulation and linear analysis is employed to investigate the secular evolution of barred galaxies, with emphasis on the interaction between bars and spheroidal components of galaxies. This interaction is argued to drive secular transfer of angular momentum from bars to spheroids, primarily through resonant coupling. A moderately strong bar, having mass within corotation about 0.3 times the enclosed spheroid mass, is predicted to shed all its angular momentum typically in less than about 10 exp 9 yr. Even shorter depletion time scales are found for relatively more massive bars. It is suggested either that spheroids around barred galaxies are structured so as to inhibit strong coupling with bars, or that bars can form by unknown processes long after disks are established. The present models reinforce the notion that bars can drive secular evolution in galaxies.

Certification of a weld produced by friction stir welding

Science.gov (United States)

Obaditch, Chris; Grant, Glenn J

2013-10-01

Methods, devices, and systems for providing certification of friction stir welds are disclosed. A sensor is used to collect information related to a friction stir weld. Data from the sensor is compared to threshold values provided by an extrinsic standard setting organizations using a certification engine. The certification engine subsequently produces a report on the certification status of the weld.

Effect of Fluidized Bed Stirring on Drying Process of Adhesive Particles

Directory of Open Access Journals (Sweden)

P. Hoffman

2017-04-01

Full Text Available This paper presents an attempt to optimize fluidized bed drying of wet and adhesive particles (with an initial diameter of about 580 mm with the use of stirring, and discusses the influence of stirring on the total drying time. The goal was to demonstrate the positive effect of stirring a fluidized bed to the drying time, to find the optimal parameters (stirrer design, speed, and size. Experiments were conducted on a drying chamber in batch operation. The objective was to evaluate the effect of stirring on the total drying time. The drying chambers were 85 mm, 100 mm, and 140 mm in diameter. An optimal stirrer shape and speed were specified. Our arrangement of the fluidized bed resulted in a decrease in drying time by up to 40 %.

On the Relation between Spector's Bar Recursion and Modified Bar Recursion

DEFF Research Database (Denmark)

Oliva, Paulo Borges

2002-01-01

We introduce a variant of Spector's Bar Recursion in finite types to give a realizability interpretation of the classical axiom of dependent choice allowing for the extraction of witnesses from proofs of Sigma_1 formulas in classical analysis. We also give a bar recursive definition of the fan...... functional and study the relationship of our variant of Bar Recursion with others....

Finite element modelling and updating of friction stir welding (FSW joint for vibration analysis

Directory of Open Access Journals (Sweden)

Zahari Siti Norazila

2017-01-01

Full Text Available Friction stir welding of aluminium alloys widely used in automotive and aerospace application due to its advanced and lightweight properties. The behaviour of FSW joints plays a significant role in the dynamic characteristic of the structure due to its complexities and uncertainties therefore the representation of an accurate finite element model of these joints become a research issue. In this paper, various finite elements (FE modelling technique for prediction of dynamic properties of sheet metal jointed by friction stir welding will be presented. Firstly, nine set of flat plate with different series of aluminium alloy; AA7075 and AA6061 joined by FSW are used. Nine set of specimen was fabricated using various types of welding parameters. In order to find the most optimum set of FSW plate, the finite element model using equivalence technique was developed and the model validated using experimental modal analysis (EMA on nine set of specimen and finite element analysis (FEA. Three types of modelling were engaged in this study; rigid body element Type 2 (RBE2, bar element (CBAR and spot weld element connector (CWELD. CBAR element was chosen to represent weld model for FSW joints due to its accurate prediction of mode shapes and contains an updating parameter for weld modelling compare to other weld modelling. Model updating was performed to improve correlation between EMA and FEA and before proceeds to updating, sensitivity analysis was done to select the most sensitive updating parameter. After perform model updating, total error of the natural frequencies for CBAR model is improved significantly. Therefore, CBAR element was selected as the most reliable element in FE to represent FSW weld joint.

Microstructural Characterization of Friction Stir Welded Aluminum-Steel Joints

Science.gov (United States)

2013-08-01

Sterling, R.J. Steel, C.-O. Pettersson. “Microstructure and mechanical properties of friction stir welded SAF 2507 super duplex stainless steel.” Mater...MICROSTRUCTURAL CHARACTERIZATION OF FRICTION STIR WELDED ALUMINUM-STEEL JOINTS By ERIN ELIZABETH PATTERSON A thesis submitted in...for his work producing the dissimilar weld samples used in this study. Without his work, this project would not have been possible. I would also

Dynamics of a stellar bar

International Nuclear Information System (INIS)

Miller, R.H.; Smith, B.F.

1979-01-01

The dynamical properties of a prolate bar have been studied by means of a three-dimensional computer model. The bar pattern rotates in the sense of the total angular momentum. The mean particle motion is a rapid streaming in the direction of pattern rotation as seen from a frame that rotates with the bar. Rotation rates that would be inferred from observation are significantly (2--3 times) faster than the pattern rotation speed. Velocity dispersions are anisotropic with the largest component along the bar. Particles oscillate in the bar potential significantly faster than pattern rotation: typical oscillation frequencies are around ω/sub z/=ω/sub y/=6Ω and ω/sub x/=3Ω where z is the direction of angular momentum, x lies along the bar, and Ω is the pattern angular velocity. About 25% of the star orbits are near 2:2:1 resonance with the slow motion along the bar. Particle motion is highly ordered in the bar:the ratio t=T/sub mean//vertical-barWvertical-bar is 0.21--0.24. Observable properties are described; where comparisons can be made, observable properties are in agreement with observations of brightness contours, velocity fields, and velocity dispersions. The bar has nearly exponential density profiles

New results from Fermilab E866 (NuSea) for d-bar/u-bar

International Nuclear Information System (INIS)

Isenhower, L. D.

1999-01-01

The Fermilab dimuon experiment 866/NuSea measured Drell-Yan yields from an 800 GeV/c proton beam incident on liquid hydrogen and deuterium targets. Over 370,000 Drell-Yan muon pairs were recorded. From these data, the ratio of anti-down (d-bar) to anti-up (u-bar) quark distributions in the proton sea is determined over a wide range in Bjorken-x. A strong x dependence is observed in the ratio d-bar/u-bar, showing substantial enhancement of d-bar with respect to u-bar for x < 0.2. The results presented here for the full data sets confirm previously published results from E866 and are compared with parametrizations of parton distribution functions calculated both before and after the publication of the high-mass E866 data

Impartial Triangular Chocolate Bar Games

OpenAIRE

Miyadera, Ryohei; Nakamura, Shunsuke; Fukui, Masanori

2017-01-01

Chocolate bar games are variants of the game of Nim in which the goal is to leave your opponent with the single bitter part of the chocolate bar. The rectangular chocolate bar game is a thinly disguised form of classical multi-heap Nim. In this work, we investigate the mathematical structure of triangular chocolate bar games in which the triangular chocolate bar can be cut in three directions. In the triangular chocolate bar game, a position is a $\\mathcal{P}$-position if and only if $x \\oplu...

Test of bar window with internal bars free from the glass surfaces

DEFF Research Database (Denmark)

Schultz, Jørgen Munthe

1998-01-01

A sealed glazing unit with 3 horisontal and 3 vertical bars and a reference glazing without bars have been tested in a guarded hotbox. The difference in measured heat loss coefficient between the two test objects is a measure of the thermal influence of the bars. The difference in heat loss...

Triple bar, high efficiency mechanical sealer

Science.gov (United States)

Pak, Donald J.; Hawkins, Samantha A.; Young, John E.

2013-03-19

A clamp with a bottom clamp bar that has a planar upper surface is provided. The clamp may also include a top clamp bar connected to the bottom clamp bar, and a pressure distribution bar between the top clamp bar and the bottom clamp bar. The pressure distribution bar may have a planar lower surface in facing relation to the upper surface of the bottom clamp bar. An object is capable of being disposed in a clamping region between the upper surface and the lower surface. The width of the planar lower surface may be less than the width of the upper surface within the clamping region. Also, the pressure distribution bar may be capable of being urged away from the top clamp bar and towards the bottom clamp bar.

Observations of barred spirals

International Nuclear Information System (INIS)

Elmegreen, D.M.

1990-01-01

Observations of barred spiral galaxies are discussed which show that the presence of a bar increases the likelihood for grand design spiral structure only in early Hubble types. This result is contrary to the more common notion that grand design spiral structure generally accompanies bars in galaxies. Enhanced deprojected color images are shown which reveal that a secondary set of spiral arms commonly occurs in barred galaxies and also occasionally in ovally distorted galaxies. 6 refs

Considerations on ultra-trace analysis of phthalates in drinking water.

Science.gov (United States)

Serôdio, P; Nogueira, J M F

2006-07-01

Stir bar sorptive extraction with liquid desorption followed by large volume injection and capillary gas chromatography coupled to mass spectrometry (SBSE-LD/LVI-GC-MS), had been applied for the determination of ultra-traces of seven-phthalates (dimethyl phthalate, diethyl phthalate, di-n-butyl phthalate, butyl benzyl phthalate, bis(2-ethylhexyl) adipate, bis(2-ethylhexyl) phthalate and bis(1-octyl) phthalate) in drinking water samples, which are included in the priority lists set by several international regulatory organizations. Instrumental calibration under the selected-ion monitoring mode acquisition (LVI-GC-MS(SIM)), experimental parameters that could affect the SBSE-LD efficiency, as well as, the control of the contamination profile are fully discussed. Throughout systematic assays on 30 mL water samples spiked at the 0.40 microg/L level, it had been established that stir bars coated with 47 microL of polydimethylsiloxane, an equilibrium time of 60 min (1,000 rpm) and methanol as back extraction solvent, allowed the best analytical performance to monitor phthalates in water matrices. From the data obtained, good accuracy and a remarkable reproducibility (water partition coefficients (K(PDMS/W) approximately K(O/W)), with the exception of bis(2-ethylhexyl) adipate, bis(2-ethylhexyl) phthalate and bis(1-octyl) phthalate, for which lower yields were measured. Additionally, a remarkable linear dynamic range between 25 and 2,000 ng/L (r(2)>0.99) and low detection limits (3-40 ng/L) were also achieved for the seven-phthalates studied. The application of the present method to monitor phthalates in tap and bottled mineral water samples, allowed convenient selectivity and high sensitivity up to 1.0 microg/L level, using the standard addition methodology. The proposed method showed to be feasible and sensitive with a low sample volume requirement to monitor phthalates in drinking water matrices at the ultra-trace level, in compliance with international regulatory

vertical bar Vub vertical bar from exclusive semileptonic B→π decays

International Nuclear Information System (INIS)

Flynn, Jonathan M.; Nieves, Juan

2007-01-01

We use Omnes representations of the form factors f + and f 0 for exclusive semileptonic B→π decays, paying special attention to the treatment of the B* pole and its effect on f + . We apply them to combine experimental partial branching fraction information with theoretical calculations of both form factors to extract vertical bar V ub vertical bar. The precision we achieve is competitive with the inclusive determination and we do not find a significant discrepancy between our result, vertical bar V ub vertical bar=(3.90+/-0.32+/-0.18)x10 -3 , and the inclusive world average value (4.45+/-0.20+/-0.26)x10 -3 [Heavy Flavor Averaging Group (HFAG), hep-ex/0603003

Unraveling the Processing Parameters in Friction Stir Welding

Science.gov (United States)

Schneider, Judy; Nunes, Arthur C., Jr.

2005-01-01

In friction stir welding (FSW), a rotating threaded pin tool is translated along a weld seam, literally stirring the edges of the seam together. To determine optimal processing parameters for producing a defect free weld, a better understanding of the resulting metal deformation flow path or paths is required. In this study, various markers are used to trace the flow paths of the metal. X-ray radiographs record the segmentation and position of the wire. Several variations in the trajectories can be differentiated within the weld zone.

Integrated sampling and analysis unit for the determination of sexual pheromones in environmental air using fabric phase sorptive extraction and headspace-gas chromatography-mass spectrometry.

Science.gov (United States)

Alcudia-León, M Carmen; Lucena, Rafael; Cárdenas, Soledad; Valcárcel, Miguel; Kabir, Abuzar; Furton, Kenneth G

2017-03-10

This article presents a novel unit that integrates for the first time air sampling and preconcentration based on the use of fabric phase sorptive extraction principles. The determination of Tuta absoluta sexual pheromone traces in environmental air has been selected as analytical problem. For this aim, a novel laboratory-built unit made up of commercial brass elements as holder of the sol-gel coated fabric extracting phase has been designed and optimized. The performance of the integrated unit was evaluated analyzing environmental air sampled in tomato crops. The unit can work under sampling and analysis mode which eliminates any need for sorptive phase manipulation prior to instrumental analysis. In the sampling mode, the unit can be connected to a sampling pump to pass the air through the sorptive phase at a controlled flow-rate. In the analysis mode, it is placed in the gas chromatograph autosampler without any instrumental modification. It also diminishes the risk of cross contamination between sampling and analysis. The performance of the new unit has been evaluated using the main components of the sexual pheromone of Tuta absoluta [(3E,8Z,11Z)-tetradecatrien-1-yl acetate and (3E,8Z)-tetradecadien-1-yl acetate] as model analytes. The limits of detection for both compounds resulted to be 1.6μg and 0.8μg, respectively, while the precision (expressed as relative standard deviation) was better than 3.7%. Finally, the unit has been deployed in the field to analyze a number of real life samples, some of them were found positive. Copyright © 2017 Elsevier B.V. All rights reserved.

Effect of Stirring and Seeding on Whey Protein Fibril Formation

NARCIS (Netherlands)

Bolder, S.G.; Sagis, L.M.C.; Venema, P.; Linden, van der E.

2007-01-01

The effect of stirring and seeding on the formation of fibrils in whey protein isolate (WPI) solutions was studied. More fibrils of a similar length are formed when WPI is stirred during heating at pH 2 and 80 C compared to samples that were heated at rest. Addition of seeds did not show an

A Rotating Plug Model of Friction Stir Welding Heat Transfer

Science.gov (United States)

Raghulapadu J. K.; Peddieson, J.; Buchanan, G. R.; Nunes, A. C.

2006-01-01

A simplified rotating plug model is employed to study the heat transfer phenomena associated with the fiction stir welding process. An approximate analytical solution is obtained based on this idealized model and used both to demonstrate the qualitative influence of process parameters on predictions and to estimate temperatures produced in typical fiction stir welding situations.

Determining vertical bar Vub vertical bar from the B-bar→Xulν-bar dilepton invariant mass spectrum

International Nuclear Information System (INIS)

Bauer, Christian W.; Ligeti, Zoltan; Luke, Michael

2001-01-01

The invariant mass spectrum of the lepton pair in inclusive semileptonic B-bar→X u lν-bar decay yields a model independent determination of vertical bar V ub vertical bar. Unlike the lepton energy and hadronic invariant mass spectra, nonperturbative effects are only important in the resonance region, and play a parametrically suppressed role when dΓ/dq 2 is integrated over q 2 >(m B -m D ) 2 , which is required to eliminate the B-bar→X c lν-bar background. We discuss these backgrounds for q 2 slightly below (m B -m D ) 2 , and point out that instead of q 2 >(m B -m D ) 2 =11.6 GeV 2 , the cut can be lowered to q 2 > or approx. 10.5 GeV 2 . This is important experimentally, particularly when effects of a finite neutrino reconstruction resolution are included

Improvement of lipase production at different stirring speeds and oxygen levels

Directory of Open Access Journals (Sweden)

F.O.M. Alonso

2005-03-01

Full Text Available Lipase production by a Brazilian wild strain of Yarrowia lipolytica at different stirring speeds and air flow rates was studied. The relationship among lipid consumption, cell growth and lipase production by this microorganism is presented. The most pronounced effect of oxygen on lipase production was determined by stirring speed. Maximum lipase activity was detected in the late stationary phase at 200 rpm and an air flow rate of 1-2 dm³/min (0.8-1.7 vvm when the lipid source had been fully consumed. Higher stirring speeds resulted in mechanical and/or oxidative stress, while lower stirring speeds seemed to limit oxygen levels. An increase in the availability of oxygen at higher air flow rates led to faster lipid uptake and anticipation of enzyme release into the culture medium. The highest lipase production was obtained at 200 rpm and 1 dm³/min (0.8 vvm.

Ultrasound-Guided Bar Edge Labeling in the Perioperative Assessment of Nuss Bar Removal.

Science.gov (United States)

Incerti, Filippo; Bertocchini, Alessia; Ghionzoli, Marco; Messineo, Antonio

2017-12-01

Nuss bar removal after minimally invasive repair of pectus excavatum in patients where bar ends are not palpable, can be a challenging procedure for the surgeon; a blind dissection toward the bar edges may lead to intercostal vessels or deep intercostal muscle injuries. In this article, we describe a fast, repeatable, low-cost technique to detect bar edge and stabilizers. A perioperative scan is performed by means of a portable ultrasonograph a few minutes before the operation. The bar edge stabilizer is detected as a hyperechogenic image with a concentric crescent while the bar edge is detected as a hyperechogenic dashed line with net edges. The scan is performed, and the actual projection on the skin of the metal plaque bulk is then labeled on the patient's chest by an ink marker. We believe that this method may improve morbidity, operative time, and consequently, hospitalization length and costs.

MR imaging in shoulder trauma. Value of STIR images

International Nuclear Information System (INIS)

Rand, T.; Trattnig, S.; Haller, J.; Imhof, H.; Nguyen, N.K.

1998-01-01

Purpose: To determine the adequacy of MR standard protocols by analyzing conventional T1- and T2-weighted SE sequences, and to evaluate the usefulness of additional fat-suppressed (STIR) images in shoulder trauma. Material and Methods: Paracoronal T1-weighted, T2-weighted SE, and STIR images were obtained on a 0.5 T superconductive system in 25 patients with shoulder trauma. In a separate evaluation of T1/T2 images and a combined evaluation of T1/T2 SE- and STIR images, we compared the number of patients with evidence of Hill-Sachs lesions, bone bruises, and/or rotator-cuff lesions. Results: Compared to the combined evaluation of T1/T2 and STIR images, the separate evaluation of T1/T2 SE images revealed identical results for rotator-cuff lesions and Hill-Sachs lesions, but different results for the bone bruises in the area of the major tubercle. Conclusion: Occult fractures of the major tubercle, indicated by areas of bone bruising, might be missed with MR using conventional SE images. We recommend the use of additional paracoronal fat-suppressed sequences in patients with clinically suspected lesions and equivocal findings on plain radiographs and on standard SE sequences. (orig.)

Measurement of $\\sigma_{t\\bar{t}b\\bar{b}}/\\sigma_{t\\bar{t}jj}$ ratio at 13 TeV with the CMS Detector

CERN Document Server

Jo, Young-kwon

2016-01-01

The measurement of the cross section ratio $\\sigma_{t\\bar{t}b\\bar{b}}/\\sigma_{t\\bar{t}jj}$ is presented using a data sample corresponding to an integrated luminosity of 2.3~$\\rm{fb}^{-1}$ collected in pp collisions at \\\\ $\\sqrt{s}$ = 13TeV with the CMS detector at the LHC. Events with two leptons and at least four reconstructed jets, including at least two identified as b quark jets, in the final state are selected. The measured ratio is $0.022 \\pm 0.003$(stat.)$\\pm0.006$(syst.) in the full phase space. The measured cross section $\\sigma_{t\\bar{t}b\\bar{b}}$ is $3.9 \\pm 0.6$(stat.)$\\pm1.3$(syst.) pb and $\\sigma_{t\\bar{t}jj}$ is $176 \\pm 5$(stat.)$ \\pm 33 $(syst.) pb.

The Effect of Rotation Stirring on Macrosegregation in Bi-Sn Alloy

Directory of Open Access Journals (Sweden)

Zulaida Yeni Muriani

2017-01-01

Full Text Available Macrosegregation is a defect that difficult to avoid in a metal alloy made by casting method. Macrosegregation can cause decreasing in mechanical properties of casting products. It will reduce their performance in industrial application. Macrosegregation is convinced occur during solidification time in liquid alloy. In the early solidified, The solids move upward/downward in liquid alloy during solidification are considered to contribute on macrosegregation formation. This movement occur due to the density differences between the solid and the surrounding liquid. This research want to observe the effect of stirring on macrosegregation formation for interfering on the movement of initial solidified solid. Stiring with rotation method is applied in this experiment at certain temperature. The temperature and the rotation speed of stirring are varied to observe the effect of rotation stirring on macrosegregation formation. The mold is covered by insulation jacket and kept the bottom part opened in order to obtain the directionally solidification. The result shows that the rotation stirring can change the macrostructure of casting but in case of composition distribution, the macrosegregation still appear. Increasing the rotation stirring will rise solid crystals up and the macrosegregation become more uniform and the treatment is better if conducting at lower temperature.

Biodenitrification of gaseous diffusion plant aqueous wastes: stirred bed reactor

International Nuclear Information System (INIS)

Holland, M.E.

1980-01-01

Approximately 30 kilograms of nitrates per day are discarded in the raffinates (acid wastes) of the Portsmouth Gaseous Diffusion Plant's X-705 Uranium Recovery and Decontamination Facility. A biodenitrification process employing continuous-flow, stirred-bed reactors has been successfully used to remove nitrates from similar acid wastes at the Oak Ridge Y-12 Plant. Laboratory studies have been made at Portsmouth to characterize the X-705 raffinates and to test the stirred-bed biodenitrification process on such raffinates. Raffinates which had been previously characterized were pumped through continuous-flow, stirred-bed, laboratory-scale reactors. Tests were conducted over a period of 146 days and involved variations in composition, mixing requirements, and the fate of several metal ions in the raffinates. Tests results show that 20 weight percent nitrates were reduced to a target nitrate effluent concentration of 100 μg/ml with a 99.64 percent efficiency. However, the average denitrification rate achieved was only 33% of that demonstrated with the Y-12 stirred-bed system. These low rates were probably due to the toxic effects of heavy metal ions on the denitrifying bacteria. Also, most of the uranium in the raffinate feed remained in the biomass and calcite, which collected in the reactor. This could cause criticality problems. For these reasons, it was decided not to make use of the stirred-bed bioreactor at Portsmouth. Instead, the biodenitrification installation now planned will use fluidized bed columns whose performance will be the subject of a subsequent report

The cc-bar and bb-bar spectroscopy in the two-step potential model

International Nuclear Information System (INIS)

Kulshreshtha, D.S.; Kaiserslautern Univ.

1984-07-01

We investigate the spectroscopy of the charmonium (cc-bar) and bottonium (bb-bar) bound states in a static flavour independent nonrelativistic quark-antiquark (qq-bar) two-step potential model proposed earlier. Our predictions are in good agreement with experimental data and with other theoretical predictions. (author)

Recent Developments and Research Progress on Friction Stir Welding of Titanium Alloys: An Overview

Science.gov (United States)

Karna, Sivaji; Cheepu, Muralimohan; Venkateswarulu, D.; Srikanth, V.

2018-03-01

Titanium and its alloys are joined by various welding processes. However, Fusion welding of titanium alloys resulted solidification problems like porosity, segregation and columnar grains. The problems occurred in conventional welding processes can be resolved using a solid state welding i.e. friction stir welding. Aluminium and Magnesium alloys were welded by friction stir welding. However alloys used for high temperature applications such as titanium alloys and steels are arduous to weld using friction stir welding process because of tool limitations. Present paper summarises the studies on joining of Titanium alloys using friction stir welding with different tool materials. Selection of tool material and effect of welding conditions on mechanical and microstructure properties of weldments were also reported. Major advantage with friction stir welding is, we can control the welding temperature above or below β-transus temperature by optimizing the process parameters. Stir zone in below beta transus condition consists of bi-modal microstructure and microstructure in above β-transus condition has large prior β- grains and α/β laths present in the grain. Welding experiments conducted below β- transus condition has better mechanical properties than welding at above β-transus condition. Hardness and tensile properties of weldments are correlated with the stir zone microstructure.

Development of an effective pinch bar

CSIR Research Space (South Africa)

Ottermann, RW

2003-02-01

Full Text Available . ....................................10 Figure 3-3: Layout of lightweight pinch bar extruded fibreglass tube. ..................................11 Figure 3-4: XDM lightweight pinch bar with manufactured glass fibre bar. ..........................12 Figure 3-5: XDM lightweight pinch... bar with extruded glass fibre tube. ................................12 Figure 3-6: Stiffness of a 2.8m lightweight pinch bar with an extruded glass fibre tube and a 25mm steel pinch bar...

$\\chi^{\\vphantom\\dagger}_{c0}(3915)$ As the Lightest $c\\bar c s \\bar s$ State

CERN Document Server

Lebed, Richard F.

2016-05-23

The state $\\chi^{\\vphantom\\dagger}_{c0}(3915)$ has recently been demoted by the Particle Data Group from its previous status as the conventional $c\\bar c$ $2 {}^3P_0$ state, largely due to the absence of expected $D\\bar D$ decays. We propose that $\\chi^{\\vphantom\\dagger}_{c0}(3915)$ is actually the lightest $c\\bar c s \\bar s$ state, and calculate the spectrum of such states using the diquark model, identifying many of the observed charmoniumlike states that lack open-charm decay modes as $c\\bar c s \\bar s$. Among other results, we argue that $Y(4140)$ is a $J^{PC} = 1^{++}$ $c\\bar c s \\bar s$ state that has been not been seen in two-photon fusion largely as a consequence of the Landau-Yang theorem.

Study of the ρ-bar, β-bar and Λ parameters of a light-water reactor

International Nuclear Information System (INIS)

Riche, R.

1965-09-01

The kinetic and perturbation equations are derived from the time-dependent transport equation. Kinetic equations depend only on the ratios a = ρ-bar/β-bar and b = β-bar/Λ, which are definite, while the reactivity ρ-bar, the delayed neutron fraction (β-bar and the generation time Λ are expressed in terms of an arbitrary function I. The 'static' definitions of these parameters, which reduce kinetic problems to a set of purely term dependent equations, introduce the effective fraction β-bar. One way of determining experimentally the ratio b is presented; it consists in analysing the power transient after a rapid variation of the reactivity, caused by the implosion of an empty glass-bull. A simple interpretation is proposed. The apparatus can be transformed easily into a reactimeter. The value of the effective delayed neutron fraction β-bar has been determined by averaging the reactivity effects of a copper sheet through out the reactor core. Experimental results: b = β-bar/Λ = 129 s -1 and β-bar 795.10 -5 , have been determined on a light-water moderated, enriched-uranium fuelled reactor. The calculated values of the effectiveness of delayed neutrons γ β-bar/β 1.23 and the generation time Λ 59.10 -6 s agrees fairly well with the experimental results. (author) [fr

Friction stir spot welding of dissimilar aluminium alloys

International Nuclear Information System (INIS)

Bozkurt, Yahya

2016-01-01

Friction stir spot welding (FSSW) has been proposed as an effective technology to spot weld the so-called “difficult to be welded” metal alloys such as thin sheets aluminum alloys and dissimilar materials. FSSW is derived from friction stir welding technology, its principle benefit being low cost joining, lower welding temperature and shorter welding time than conventional welding methods. In this study, dissimilar AlMg 3 and AlCu 4 Mg 1 aluminium alloy plates were FSSWed by offsetting the low strength sheet on upper side of the weld. The effects of tool rotation speed on the microstructure, lap shear fracture load (LSFL), microhardness and fracture features of the weld are investigated by constant welding parameters. The maximum LSFL was obtained by increasing the tool rotational speed. However, the joints exhibited pull-out nugget fracture mode under lap shear tensile testing conditions. The largest completely bonded zone was observed as 5.86 mm which was narrower at the opposite position of the joint. Key words: friction stir spot welding, aluminium alloys, mechanical properties, dissimilar joint, welding parameters

New Materials Design Through Friction Stir Processing Techniques

International Nuclear Information System (INIS)

Buffa, G.; Fratini, L.; Shivpuri, R.

2007-01-01

Friction Stir Welding (FSW) has reached a large interest in the scientific community and in the last years also in the industrial environment, due to the advantages of such solid state welding process with respect to the classic ones. The complex material flow occurring during the process plays a fundamental role in such solid state welding process, since it determines dramatic changes in the material microstructure of the so called weld nugget, which affects the effectiveness of the joints. What is more, Friction Stir Processing (FSP) is mainly being considered for producing high-strain-rate-superplastic (HSRS) microstructure in commercial aluminum alloys. The aim of the present research is the development of a locally composite material through the Friction Stir Processing (FSP) of two AA7075-T6 blanks and a different material insert. The results of a preliminary experimental campaign, carried out at the varying of the additional material placed at the sheets interface under different conditions, are presented. Micro and macro observation of the such obtained joints permitted to investigate the effects of such process on the overall joint performance

Measurement of vertical bar Vub vertical bar in semi-inclusive charmless B → πX decays

International Nuclear Information System (INIS)

Kim, C.S.; Lee, Jake; Oha, Sechul

2002-01-01

We study semi-inclusive charmless decays B → πX, where X does not contain a charm (anti)quark. The mode B-bar 0 → π - X turns out to be be particularly useful for determination of the CKM matrix element vertical bar V ub vertical bar. We present the branching ratio (BR) of B-bar 0 → π - X as a function of vertical bar V ub vertical bar, with an estimation of possible uncertainty. The BR is expected to be an order of 10 -4

Bank pull or bar push: What drives scroll-bar formation in meandering rivers?

NARCIS (Netherlands)

van de Lageweg, W. I.; van Dijk, W. M.; Baar, A. W.; Rutten, J.; Kleinhans, M. G.

2014-01-01

One of the most striking features of meandering rivers are quasi-regular ridges of the point bar, evidence of a pulsed lateral migration of meander bends. Scroll bars formed on the inner bend are preserved on the point-bar surface as a series of ridges as meanders migrate, and in the subsurface of

Study of Low Flow Rate Ladle Bottom Gas Stirring Using Triaxial Vibration Signals

Science.gov (United States)

Yenus, Jaefer; Brooks, Geoffrey; Dunn, Michelle; Li, Zushu; Goodwin, Tim

2018-02-01

Secondary steelmaking plays a great role in enhancing the quality of the final steel product. The metal quality is a function of metal bath stirring in ladles. The metal bath is often stirred by an inert gas to achieve maximum compositional and thermal uniformity throughout the melt. Ladle operators often observe the top surface phenomena, such as level of meniscus disturbance, to evaluate the status of stirring. However, this type of monitoring has significant limitations in assessing the process accurately especially at low gas flow rate bubbling. The present study investigates stirring phenomena using ladle wall triaxial vibration at a low flow rate on a steel-made laboratory model and plant scale for the case of the vacuum tank degasser. Cold model and plant data were successfully modeled by partial least-squares regression to predict the amount of stirring. In the cold model, it was found that the combined vibration signal could predict the stirring power and recirculation speed effectively in specific frequency ranges. Plant trials also revealed that there is a high structure in each data set and in the same frequency ranges at the water model. In the case of industrial data, the degree of linear relationship was strong for data taken from a single heat.

Effects of Fusion Tack Welds on Self-Reacting Friction Stir Welds

Science.gov (United States)

Nunes, A. C., Jr.; Pendleton, M. L.; Brooke, S. A.; Russell, C. K.

2012-01-01

In order to know whether fusion tack welds would affect the strength of self-reacting friction stir seam welds in 2195-T87 aluminum alloy, the fracture stresses of 144 tensile test coupons cut from 24 welded panels containing segments of friction stir welds were measured. Each of the panels was welded under unique processing conditions. A measure of the effect of the tack welds for each panel was devised. An analysis of the measures of the tack weld effect supported the hypothesis that fusion tack welds do not affect the strength of self-reacting friction stir welds to a 5% level of confidence.

Effects of Laser Peening, and Shot Peening, on Friction Stir Welding

Science.gov (United States)

Hatamleh, Omar; Hackel, Lloyd; Rankin, Jon; Truong, Chanh; Walter, Matt

2006-01-01

A viewgraph presentation describing the effects of laser peening and shot peening on friction stir welding is shown. The topics include: 1) Background; 2) Friction Stir Welding (FSW); 3) Microstructure; 4) Laser & Shot Peening; 5) Residual Stresses; 6) Tensile Behavior; 7) Fatigue Life & Surface Roughness; 8) Crack Growth; and 9) Benefits.

Determination of the quark coupling strength vertical bar V-ub vertical bar using baryonic decays

NARCIS (Netherlands)

Aaij, R.; Adeva, B.; Adinolfi, M.; Older, A. A.; Ajaltouni, Z.; Akar, S.; Albrecht, J.; Alessio, F.; Alexander, M.; Ali, S.; Alkhazov, G.; Cartelle, P. Alvarez; Alves, A. A.; Amato, S.; Amerio, S.; Amhis, Y.; An, L.; Anderlini, L.; Andreotti, M.; Andrews, J. E.; Appleby, R. B.; Gutierrez, O. Aquines; Archilli, F.; Artamonov, A.; Artuso, M.; Aslanides, E.; Auriemma, G.; Baalouch, M.; Bachmann, S.; Back, J. J.; Badalov, A.; Baesso, C.; Baldini, W.; Barlow, R. J.; Barschel, C.; Barsuk, S.; Barter, W.; Batozskaya, V.; Battista, V.; Beaucourt, L.; Beddow, J.; Bedeschi, F.; Bediaga, I.; Bel, L. J.; Belyaev, I.; Ben-Haim, E.; Bencivenni, G.; Onderwater, C. J. G.; Pellegrino, A.; Tolk, S.

In the Standard Model of particle physics, the strength of the couplings of the b quark to the u and c quarks, vertical bar V-ub vertical bar and vertical bar V-ub vertical bar, are governed by the coupling of the quarks to the Higgs boson. Using data from the LHCb experiment at the Large Hadron

What makes the family of barred disc galaxies so rich: damping stellar bars in spinning haloes

Science.gov (United States)

Collier, Angela; Shlosman, Isaac; Heller, Clayton

2018-05-01

We model and analyse the secular evolution of stellar bars in spinning dark matter (DM) haloes with the cosmological spin λ ˜ 0-0.09. Using high-resolution stellar and DM numerical simulations, we focus on angular momentum exchange between stellar discs and DM haloes of various axisymmetric shapes - spherical, oblate, and prolate. We find that stellar bars experience a diverse evolution that is guided by the ability of parent haloes to absorb angular momentum, J, lost by the disc through the action of gravitational torques, resonant and non-resonant. We confirm that dynamical bar instability is accelerated via resonant J-transfer to the halo. Our main findings relate to the long-term secular evolution of disc-halo systems: with an increasing λ, bars experience less growth and basically dissolve after they pass through vertical buckling instability. Specifically, with increasing λ, (1) the vertical buckling instability in stellar bars colludes with inability of the inner halo to absorb J - this emerges as the main factor weakening or destroying bars in spinning haloes; (2) bars lose progressively less J, and their pattern speeds level off; (3) bars are smaller, and for λ ≳ 0.06 cease their growth completely following buckling; (4) bars in λ > 0.03 haloes have ratio of corotation-to-bar radii, RCR/Rb > 2, and represent so-called slow bars without offset dust lanes. We provide a quantitative analysis of J-transfer in disc-halo systems, and explain the reasons for absence of growth in fast spinning haloes and its observational corollaries. We conclude that stellar bar evolution is substantially more complex than anticipated, and bars are not as resilient as has been considered so far.

Microstructure and mechanical properties of friction stir welded SAF 2507 super duplex stainless steel

International Nuclear Information System (INIS)

Sato, Y.S.; Nelson, T.W.; Sterling, C.J.; Steel, R.J.; Pettersson, C.-O.

2005-01-01

The microstructure and mechanical properties of friction stir (FS) welded SAF 2507 super duplex stainless steel were examined. High-quality, full-penetration welds were successfully produced in the super duplex stainless steel by friction stir welding (FSW) using polycrystalline cubic boron nitride (PCBN) tool. The base material had a microstructure consisting of the ferrite matrix with austenite islands, but FSW refined grains of the ferrite and austenite phases in the stir zone through dynamic recrystallisation. Ferrite content was held between 50 and 60% throughout the weld. The smaller grain sizes of the ferrite and austenite phases caused increase in hardness and strength within the stir zone. Welded transverse tensile specimen failed near the border between the stir zone and TMAZ at the retreating side as the weld had roughly the same strengths as the base material

Implementation of viscoelastic Hopkinson bars

Directory of Open Access Journals (Sweden)

Govender R.

2012-08-01

Full Text Available Knowledge of the properties of soft, viscoelastic materials at high strain rates are important in furthering our understanding of their role during blast or impact events. Testing these low impedance materials using a metallic split Hopkinson pressure bar setup results in poor signal to noise ratios due to impedance mismatching. These difficulties are overcome by using polymeric Hopkinson bars. Conventional Hopkinson bar analysis cannot be used on the polymeric bars due to the viscoelastic nature of the bar material. Implementing polymeric Hopkinson bars requires characterization of the viscoelastic properties of the material used. In this paper, 30 mm diameter Polymethyl Methacrylate bars are used as Hopkinson pressure bars. This testing technique is applied to polymeric foam called Divinycell H80 and H200. Although there is a large body of of literature containing compressive data, this rarely deals with strain rates above 250s−1 which becomes increasingly important when looking at the design of composite structures where energy absorption during impact events is high on the list of priorities. Testing of polymeric foams at high strain rates allows for the development of better constitutive models.

Numerical Simulation of Mechanical Property of Post Friction Stir Weld Artificial Ageing of Aluminum Alloy

Directory of Open Access Journals (Sweden)

WAN Zhenyu

2017-08-01

Full Text Available KWN model was used to establish the precipitation evolution model of friction stir welding of Al-Mg-Si alloy. The yield strength was divided into three parts:the contribution from grain size, the contribution from solid solution and the contribution from the precipitations. Based on this model, the yield strength and hardness of friction stir weld was predicted. The effect of post weld artificial ageing on mechanical properties of friction stir weld was further investigated. The results indicate that longer holding time can be beneficial to the recovery of mechanical properties in the stirring zone. Higher temperature can lead to quick recovery of mechanical properties in the stirring zone, but when the holding temperature is higher than 200℃, longer holding time can lead the base metal softened, which is harmful to the service of friction stir welds. The mechanical property in the heat affected zone cannot be improved by post weld artificial ageing.

Stir-Frying of Chinese Cabbage and Pakchoi Retains Health-Promoting Glucosinolates

NARCIS (Netherlands)

Nugrahedi, Probo Y.; Oliviero, Teresa; Heising, Jenneke K.; Dekker, Matthijs; Verkerk, Ruud

2017-01-01

Stir-frying is a cooking method, originating from Asia, in which food is fried in small amount of very hot oil. Nowadays in many other parts of the world stir-frying is a very popular method to prepare vegetables, because it is fast and fried vegetables are tasty. However, the retention of

Jet-stirred reactor oxidation of alkane-rich FACE gasoline fuels

KAUST Repository

Chen, Bingjie

2016-06-23

Understanding species evolution upon gasoline fuel oxidation can aid in mitigating harmful emissions and improving combustion efficiency. Experimentally measured speciation profiles are also important targets for surrogate fuel kinetic models. This work presents the low- and high-temperature oxidation of two alkane-rich FACE gasolines (A and C, Fuels for Advanced Combustion Engines) in a jet-stirred reactor at 10. bar and equivalence ratios from 0.5 to 2 by probe sampling combined with gas chromatography and Fourier Transformed Infrared Spectrometry analysis. Detailed speciation profiles as a function of temperature are presented and compared to understand the combustion chemistry of these two real fuels. Simulations were conducted using three surrogates (i.e., FGA2, FGC2, and FRF 84), which have similar physical and chemical properties as the two gasolines. The experimental results reveal that the reactivity and major product distributions of these two alkane-rich FACE fuels are very similar, indicating that they have similar global reactivity despite their different compositions. The simulation results using all the surrogates capture the two-stage oxidation behavior of the two FACE gasolines, but the extent of low temperature reactivity is over-predicted. The simulations were analyzed, with a focus on the n-heptane and n-butane sub-mechanisms, to help direct the future model development and surrogate fuel formulation strategies.

Jet-stirred reactor oxidation of alkane-rich FACE gasoline fuels

KAUST Repository

Chen, Bingjie; Togbé , Casimir; Wang, Zhandong; Dagaut, Philippe; Sarathy, Mani

2016-01-01

Understanding species evolution upon gasoline fuel oxidation can aid in mitigating harmful emissions and improving combustion efficiency. Experimentally measured speciation profiles are also important targets for surrogate fuel kinetic models. This work presents the low- and high-temperature oxidation of two alkane-rich FACE gasolines (A and C, Fuels for Advanced Combustion Engines) in a jet-stirred reactor at 10. bar and equivalence ratios from 0.5 to 2 by probe sampling combined with gas chromatography and Fourier Transformed Infrared Spectrometry analysis. Detailed speciation profiles as a function of temperature are presented and compared to understand the combustion chemistry of these two real fuels. Simulations were conducted using three surrogates (i.e., FGA2, FGC2, and FRF 84), which have similar physical and chemical properties as the two gasolines. The experimental results reveal that the reactivity and major product distributions of these two alkane-rich FACE fuels are very similar, indicating that they have similar global reactivity despite their different compositions. The simulation results using all the surrogates capture the two-stage oxidation behavior of the two FACE gasolines, but the extent of low temperature reactivity is over-predicted. The simulations were analyzed, with a focus on the n-heptane and n-butane sub-mechanisms, to help direct the future model development and surrogate fuel formulation strategies.

Bar codes for nuclear safeguards

International Nuclear Information System (INIS)

Keswani, A.N.; Bieber, A.M. Jr.

1983-01-01

Bar codes similar to those used in supermarkets can be used to reduce the effort and cost of collecting nuclear materials accountability data. A wide range of equipment is now commercially available for printing and reading bar-coded information. Several examples of each of the major types of commercially available equipment are given, and considerations are discussed both for planning systems using bar codes and for choosing suitable bar code equipment

Bar codes for nuclear safeguards

International Nuclear Information System (INIS)

Keswani, A.N.; Bieber, A.M.

1983-01-01

Bar codes similar to those used in supermarkets can be used to reduce the effort and cost of collecting nuclear materials accountability data. A wide range of equipment is now commercially available for printing and reading bar-coded information. Several examples of each of the major types of commercially-available equipment are given, and considerations are discussed both for planning systems using bar codes and for choosing suitable bar code equipment

The effect of time and stirring on product white colorant from titanium dioxide

International Nuclear Information System (INIS)

Ratnawati; Linda A; Yoshi; Zaenal K; Andri Y

2018-01-01

White Colorant is the main raw material in the paint making process in the depots. It made from TiO 2 pigment. The process of making white colorant requires a great stirring time and energy to mix the materials such as binders, pigments, solvents, and additives. The aim of this study is to get the optimum stirring time and speed from mixing the materials needed to obtain white colorant from TiO 2 pigment that meet the specification desired by paint Factory in Tangerang that is particle size of TiO 2 (10 μm to 30 μm), viscosity 1000 cps to 6000 cps, total solids 79 % to 83 %, DE color is 0.5, and CR is 80 % to 100 %. Variations made were stirring speed (1000, 1100 and 1200) rpm and stirring time(10, 15, 20, 25 and 30) minutes. The optimum results obtained are particle size of 15 μm, viscosity 1900 cps, total solids 81.81 %, color DE 0.49 and color CR 98.12 % at stirring condition 1200 rp min 15 minutes. (author)

Immersed friction stir welding of ultrafine grained accumulative roll-bonded Al alloy

International Nuclear Information System (INIS)

Hosseini, M.; Danesh Manesh, H.

2010-01-01

In this research, ultrafine grained strips of commercial pure strain hardenable aluminum (AA1050) were produced by accumulative roll-bonding (ARB) technique. These strips were joined by friction stir welding (FSW) in immersed (underwater) and conventional (in-air) conditions to investigate the effect of the immersion method on the microstructure and mechanical properties of the joint, aiming to reduce the deterioration of the mechanical properties of the joint. Transmission electron microscopy and X-ray diffraction analyses were used to evaluate the microstructure, showing smaller grains and subgrains in the stir zone of the immersed FSW condition with respect to the conventional FSW method. The hardness and tensile properties of the immersed friction stir welded sample and ARBed base metal show more similarity compared to the conventional friction stir welded sample. Moreover, the aforementioned method can result in the enhancement of the superplasticity tendency of the material.

Search for the decay of a B0 or B0bar meson to K*0bar K0 or K*0 K0bar

Energy Technology Data Exchange (ETDEWEB)

Aubert, B.

2006-06-27

The authors present a search for the decay of a B{sup 0} or {bar B}{sup 0} meson to a {bar K}*{sup 0} K{sup 0} or K*{sup 0} {bar K}{sup 0} final state, using a sample of approximately 232 million B{bar B} events collected with the BABAR detector at the PEP-II asymmetric energy e{sup +}e{sup -} collider at SLAC. The measured branching fraction is {Beta}(B{sup 0} {yields} {bar K}*{sup 0} K{sup 0}) + {Beta}(B{sup 0} {yields} K*{sup 0} {bar K}{sup 0}) = (0.2{sub -0.8, -0.3}{sup +0.9, +0.1}) x 10{sup -6}. They obtain the following upper limit for the branching fraction at 90% confidence level: {Beta}(B{sup 0} {yields} {bar K}*{sup 0} K{sup 0}) + {Beta}(B{sup 0} {yields} K*{sup 0} {bar K}{sup 0}) < 1.9 x 10{sup -6}. They use our result to constrain the Standard Model prediction for the deviation of the CP asymmetry in B{sup 0} {yields} {phi}K{sup 0} from sin 2{beta}.

Biodegradation of phenolic waste liquors in stirred-tank, packed-bed, and fluidized-bed bioreactors

Energy Technology Data Exchange (ETDEWEB)

Holladay, D W; Hancher, G W; Chilcote, D D; Scott, C D

1978-11-01

The biological degradation of phenolic scrub liquors similar to those that arise in coal conversion processes was studied for symbiotic bacterial populations contained in a continuously stirred tank bioreactor, a three-phase packed-bed bioreactor, and a three-phase, fluidized-bed bioreactor. The conversions of phenol compounds were comparable in the three-phase, packed-bed bioreactor and the continuously stirred tank bioreactor; however, the packed-bed bioreactor degradation rates were as much as twice those in the continuously stirred tank bioreactor, and packed-bed bioreactor retention times were as low as one- tenth those of the continuously stirred tank bioreactors (minimum time was 12 hours).

STIR: Microwave Response of Carbon Nanotubes in Polymer Nanocomposite Welds

Science.gov (United States)

2016-01-28

STIR: RDRL-ROE-M: Microwave Response of Carbon Nanotubes in Polymer Nanocomposite Welds Thrust 1 of the STIR project examines the heat response of...polymer composites loaded with carbon nanotubes (CNTs) to microwave irradiation. This involves (1) a study of how CNT loading affects dielectric...properties of polymer composites and (2) a study of how CNT loading affects the heating response to microwave radiation. Our hypothesis is that the

Friction Stir Weld Failure Mechanisms in Aluminum-Armor Structures Under Ballistic Impact Loading Conditions

Science.gov (United States)

2013-01-01

REPORT Friction Stir Weld Failure Mechanisms in Aluminum-Armor Structures Under Ballistic Impact Loading Conditions 14. ABSTRACT 16. SECURITY...properties and of the attendant ballistic-impact failure mechanisms in prototypical friction stir welding (FSW) joints found in armor structures made of high...mechanisms, friction stir welding M. Grujicic, B. Pandurangan, A. Arakere, C-F. Yen, B. A. Cheeseman Clemson University Office of Sponsored Programs 300

Use of limited MR protocol (coronal STIR) in the evaluation of patients with hip pain

International Nuclear Information System (INIS)

Khoury, N.J.; Birjawi, G.A.; Hourani, M.H.; Chaaya, M.

2003-01-01

To assess the role of a limited MR protocol (coronal STIR) as the initial part of the MR examination in patients with hip pain. Eighty-five patients presenting with hip pain, and normal radiographs of the pelvis, and who underwent our full MR protocol for hips were included retrospectively in the study. The full protocol consists of coronal T1-weighted and short tau inversion-recovery (STIR), and axial T2-weighted sequences. Ninety-three MR examinations were performed. Two radiologists interpreted the STIR (limited) examinations and the full studies separately, masked to each other's findings and to the final diagnosis. Comparison between the two protocols was then undertaken. For both readers, all normal MR examinations on the coronal STIR limited protocol were normal on the full protocol, with an interobserver reliability of 0.96. The STIR protocol was able to detect the presence or absence of an abnormality in 100% of cases (sensitivity). The STIR-only protocol provided a specific diagnosis in only 65% of cases (specificity). A normal coronal STIR study of the hips in patients with hip pain and normal radiographs precludes the need for further pelvic MR sequences. Any abnormality detected on this limited protocol should be further assessed by additional MR sequences. (orig.)

Microstructural evolution in friction stir welding of nanostructured ODS alloys

International Nuclear Information System (INIS)

Chen, C.-L.; Tatlock, G.J.; Jones, A.R.

2010-01-01

Nanostructured oxide dispersion strengthened (ODS) Fe-based alloys manufactured by mechanical alloying (MA) are generally considered to be promising candidate materials for high-temperature applications up to at least 1100 o C because of their excellent creep strength and good oxidation resistance. However, a key issue with these alloys is the difficulty in using fusion welding techniques to join components due to oxide particle agglomeration and loss in the weld zone and the disruption and discontinuity in the grain structure introduced at the bond. In this study, the evolution of microstructure has been comprehensively studied in friction stir welds in a ferritic ODS alloy. Initially, electron backscattering diffraction (EBSD) was used to analyze the grain orientation, the grain boundary geometries and recrystallization behaviour. It suggested that deformation heterogeneities were introduced during the friction stirring process which facilitated the onset of recrystallization. Transmission electron microscopy (TEM) and scanning transmission electron microscopy (STEM) were used to observe the effects of the friction stir welding (FSW) process on the grain structure and the distribution of Y 2 O 3 and other particles in the metal substrates in the FSW and adjacent regions, after the alloys had been recrystallized at temperatures up to 1380 o C for 1 h in air. The results show that fine-equiaxed grains and a uniform distribution of oxide particles were present in the friction stirred region but that the grain boundaries in the parent metal were pinned by particles. Friction stirring appeared to release these boundaries and allowed secondary recrystallization to occur after further heat treatment. The FSW process appears to be a promising technique for joining ferritic ODS alloys in the form of sheet and tube.

Investigation of the L-Glutamic acid polymorphism: Comparison between stirred and stagnant conditions

Science.gov (United States)

Tahri, Yousra; Gagnière, Emilie; Chabanon, Elodie; Bounahmidi, Tijani; Mangin, Denis

2016-02-01

This work highlights the effect of the stirring, the temperature and the supersaturation on the cooling crystallization of L-Glutamic acid (LGlu) polymorphs. First, solubility measurements of the metastable polymorph α and the stable polymorph β were performed. Then, crystallization experiments were carried out in stirred vessel and in stagnant cell. All these experiments were monitored by in situ devices. The effect of the temperature on the LGlu polymorphs was found to be more relevant than the supersaturation in the stirred crystallizer. In the stagnant cell, only the stable form β crystallized regardless of the operating conditions. Moreover, an unexpected and new habit of the β form was discovered and confirmed. These results suggest that the temperature and the stirring can strongly affect the nucleation and the growth kinetics of polymorphic forms.

The Effect of Stirring on the Morphology of Birnessite Nanoparticles

Directory of Open Access Journals (Sweden)

Marcos A. Cheney

2008-01-01

Full Text Available The effect of mechanical stirring on the morphology of hexagonal layer-structure birnessite nanoparticles produced from decomposition of KMnO4 in dilute aqueous H2SO4 is investigated, with characterization by X-ray diffraction (XRD, scanning electron microscopy (SEM, transmission electron microscopy (TEM, high-resolution transmission electron microscopy (HRTEM, thermogravimetric analysis (TGA, and N2 adsorption (BET. Mechanical stirring during an initial stage of synthesis is shown to produce black birnessite containing nanofibers, whereas granular particulates of brown birnessite are produced without stirring. This is the first reduction synthesis of black birnessite nanoparticles with dendritic morphology without any use of organic reductant, and suggests that a particular morphology can arise from structural preferences of Mn in acidic conditions rather than particular organic reactants. These results enlighten the possibility of synthesizing nanoparticles with controlled size and morphology.

A Brief Introduction to the Theory of Friction Stir Welding

Science.gov (United States)

Nunes, Arthur C., Jr.

2008-01-01

Friction stir welding (FSW) is a solid state welding process invented in 1991 at The Welding Institute in the United Kingdom. A weld is made in the FSW process by translating a rotating pin along a weld seam so as to stir the sides of the seam together. FSW avoids deleterious effects inherent in melting and is already an important welding process for the aerospace industry, where welds of optimal quality are demanded. The structure of welds determines weld properties. The structure of friction stir welds is determined by the flow field in the weld metal in the vicinity of the weld tool. A simple kinematic model of the FSW flow field developed at Marshall Space Flight Center, which enables the basic features of FSW microstructure to be understood and related to weld process parameters and tool design, is explained.

Friction stir weld tools having fine grain structure

Science.gov (United States)

Grant, Glenn J.; Frye, John G.; Kim, Jin Yong; Lavender, Curt A.; Weil, Kenneth Scott

2016-03-15

Tools for friction stir welding can be made with fewer process steps, lower cost techniques, and/or lower cost ingredients than other state-of-the-art processes by utilizing improved compositions and processes of fabrication. Furthermore, the tools resulting from the improved compositions and processes of fabrication can exhibit better distribution and homogeneity of chemical constituents, greater strength, and/or increased durability. In one example, a friction stir weld tool includes tungsten and rhenium and is characterized by carbide and oxide dispersoids, by carbide particulates, and by grains that comprise a solid solution of the tungsten and rhenium. The grains do not exceed 10 micrometers in diameter.

Fatigue and Damage Tolerance of Friction Stir Welded Joints for Aerospace Applications

NARCIS (Netherlands)

Lemmen, H.J.K.

2010-01-01

Friction stir welding is a young welding process with high potential to replace riveted joints in aerospace structures like the fuselage. Friction stir welding is a robust process and capable of welding high strength aluminum alloys. Therefore it can lead to both costs and weight savings. To

Hyperon polarisation in the reaction p-bar sup 1 sup 2 C -> LAMBDA-bar LAMBDA X

CERN Document Server

Pomp, S; Bröders, R; Bunker, B; Dennert, H; Eisenstein, R E; Eyrich, W; Fischer, H; Franklin, G; Franz, J; Geyer, R; Harris, P; Hauffe, J; Hertzog, D; Johansson, T; Jones, T; Kilian, K; Kraft, R A; Meyer, C; Oelert, W; Quinn, B; Röhrich, K; Rössle, E; Sachs, K; Schmitt, H; Schumacher, R; Sefzick, T; Stinzing, F; Tayloe, R; Todenhagen, R; Traneus, E; Wirth, S

2000-01-01

Data from the p-bar sup 1 sup 2 C -> LAMBDA-bar LAMBDA X reaction, collected by the PS185 experiment at antiproton momenta around 1.44 GeV/c, 1.66 GeV/c and 1.77 GeV/c, have been analyzed and the LAMBDA and LAMBDA-bar polarisations have been extracted. The events are classified as quasi-free or non-quasi-free and it is found that the polarisations for LAMBDA and LAMBDA-bar differ in the latter case. Such an effect comes from differences in the interaction of the outgoing LAMBDA and LAMBDA-bar with the residual nucleus and the measurement constitutes the first information on LAMBDA-bar interaction with nuclear matter.

Corrosion Performance of Friction Stir Linear Lap Welded AM60B Joints

Science.gov (United States)

Kish, J. R.; Birbilis, N.; McNally, E. M.; Glover, C. F.; Zhang, X.; McDermid, J. R.; Williams, G.

2017-11-01

A corrosion investigation of friction stir linear lap welded AM60B joints used to fabricate an Mg alloy-intensive automotive front end sub-assembly was performed. The stir zone exhibited a slightly refined grain size and significant break-up and re-distribution of the divorced Mg17Al12 (β-phase) relative to the base material. Exposures in NaCl (aq) environments revealed that the stir zone was more susceptible to localized corrosion than the base material. Scanning vibrating electrode technique measurements revealed differential galvanic activity across the joint. Anodic activity was confined to the stir zone surface and involved initiation and lateral propagation of localized filaments. Cathodic activity was initially confined to the base material surface, but was rapidly modified to include the cathodically-activated corrosion products in the filament wake. Site-specific surface analyses revealed that the corrosion observed across the welded joint was likely linked to variations in Al distribution across the surface film/metal interface.

Numerical simulations of wave propagation in long bars with application to Kolsky bar testing

Energy Technology Data Exchange (ETDEWEB)

Corona, Edmundo [Sandia National Lab. (SNL-NM), Albuquerque, NM (United States)

2014-11-01

Material testing using the Kolsky bar, or split Hopkinson bar, technique has proven instrumental to conduct measurements of material behavior at strain rates in the order of 10³ s^-1. Test design and data reduction, however, remain empirical endeavors based on the experimentalist's experience. Issues such as wave propagation across discontinuities, the effect of the deformation of the bar surfaces in contact with the specimen, the effect of geometric features in tensile specimens (dog-bone shape), wave dispersion in the bars and other particulars are generally treated using simplified models. The work presented here was conducted in Q3 and Q4 of FY14. The objective was to demonstrate the feasibility of numerical simulations of Kolsky bar tests, which was done successfully.

CP violation in hyperon decays: the case p-bar p → Λ-bar Λ → p-bar π+ pπ-

International Nuclear Information System (INIS)

Hamann, N.; He, X.G.; Landua, R.; Ohlsson, S.; Steger, H.; Valencia, G.; Fischer, H.; Geyer, R.; Hertzog, D.; Kolo, B.; Miller, J.P.; Rohrich, K.

1992-01-01

An account is given of the experimental status of CP violation and of the phenomenology of hyperon non-leptonic decays. Updated information on the estimate of CP-violating observable in these decays is presented. An experimental programme is outlined, which aims to pursue the search for direct CP violation in hyperon-antihyperon decays by means of the reaction p-bar p → Λ-bar Λ → p-bar π + pπ - . The experiment as well as analysis methods are described. Alternative approaches employing hyperons are also discussed. 54 refs., 1 tab., 13 figs

Role of biofilms in sorptive removal of steroidal hormones and 4-nonylphenol compounds from streams

Science.gov (United States)

Writer, Jeffrey H.; Ryan, Joseph N.; Barber, Larry B.

2011-01-01

Stream biofilms play an important role in geochemical processing of organic matter and nutrients, however, the significance of this matrix in sorbing trace organic contaminants is less understood. This study focused on the role of stream biofilms in sorbing steroidal hormones and 4-nonylphenol compounds from surface waters using biofilms colonized in situ on artificial substrata and subsequently transferred to the laboratory for controlled batch sorption experiments. Steroidal hormones and 4-nonylphenol compounds readily sorb to stream biofilms as indicated by organic matter partition coefficients (Kom, L kg–1) for 17β-estradiol (102.5–2.8 L kg–1), 17α-ethynylestradiol (102.5–2.9 L kg–1), 4-nonylphenol (103.4–4.6 L kg–1), 4-nonylphenolmonoethoxylate (103.5–4.0 L kg–1), and 4-nonylphenoldiethoxylate (103.9–4.3 L kg–1). Experiments using water quality differences to induce changes in the relative composition of periphyton and heterotrophic bacteria in the stream biofilm did not significantly affect the sorptive properties of the stream biofilm, providing additional evidence that stream biofilms will sorb trace organic compounds under of variety of environmental conditions. Because sorption of the target compounds to stream biofilms was linearly correlated with organic matter content, hydrophobic partition into organic matter appears to be the dominant mechanism. An analysis of 17β-estradiol and 4-nonylphenol hydrophobic partition into water, biofilm, sediment, and dissolved organic matter matrices at mass/volume ratios typical of smaller rivers showed that the relative importance of the stream biofilm as a sorptive matrix was comparable to bed sediments. Therefore, stream biofilms play a primary role in attenuating these compounds in surface waters. Because the stream biofilm represents the base of the stream ecosystem, accumulation of steroidal hormones and 4-nonylphenol compounds in the stream biofilm may be an exposure pathway for

QCD corrections to leptonic and hadronic observables from p bar p→W+X→ bar τντX

International Nuclear Information System (INIS)

Baer, H.; Reno, M.H.

1993-01-01

We set up a formalism for calculating the O(α s ) corrections to the process p bar p→W + X→ bar τν τ X with spin-correlated τ decays to leptons and mesons. Our results are applicable to Monte Carlo integration, which allows easy construction of any desired observable at next-to-leading-log level, and the possibility to include experimental cuts. Our results are applied explicitly to the decay modes τ→ bar ν τ bar eν e , bar τ→ bar ν τ π + , and bar τ→ bar ν τ π + π 0 ; other decay modes may be included in a straightforward fashion. We show results for transverse momentum and rapidity variables in leading-log and next-to-leading-log approximations; the leptonic observables are compared to similar observables from direct W→ bar eν e

Bar quenching in gas-rich galaxies

Science.gov (United States)

Khoperskov, S.; Haywood, M.; Di Matteo, P.; Lehnert, M. D.; Combes, F.

2018-01-01

Galaxy surveys have suggested that rapid and sustained decrease in the star-formation rate (SFR), "quenching", in massive disk galaxies is frequently related to the presence of a bar. Optical and near-IR observations reveal that nearly 60% of disk galaxies in the local universe are barred, thus it is important to understand the relationship between bars and star formation in disk galaxies. Recent observational results imply that the Milky Way quenched about 9-10 Gyr ago, at the transition between the cessation of the growth of the kinematically hot, old, metal-poor thick disk and the kinematically colder, younger, and more metal-rich thin disk. Although perhaps coincidental, the quenching episode could also be related to the formation of the bar. Indeed the transfer of energy from the large-scale shear induced by the bar to increasing turbulent energy could stabilize the gaseous disk against wide-spread star formation and quench the galaxy. To explore the relation between bar formation and star formation in gas rich galaxies quantitatively, we simulated gas-rich disk isolated galaxies. Our simulations include prescriptions for star formation, stellar feedback, and for regulating the multi-phase interstellar medium. We find that the action of stellar bar efficiently quenches star formation, reducing the star-formation rate by a factor of ten in less than 1 Gyr. Analytical and self-consistent galaxy simulations with bars suggest that the action of the stellar bar increases the gas random motions within the co-rotation radius of the bar. Indeed, we detect an increase in the gas velocity dispersion up to 20-35 km s-1 at the end of the bar formation phase. The star-formation efficiency decreases rapidly, and in all of our models, the bar quenches the star formation in the galaxy. The star-formation efficiency is much lower in simulated barred compared to unbarred galaxies and more rapid bar formation implies more rapid quenching.

Re-study of the contribution of scalar potential and spectra of cc-bar, bb-bar and bc-bar(b-bar c) families

International Nuclear Information System (INIS)

Yuan Xuhao; Ke Hongwei; Ding Yibing; Li Xueqian

2012-01-01

We indicated in our previous work that for QED the role of the scalar potential which appears at the loop level is much smaller than that of the vector potential and is in fact negligible. But the situation is different for QCD, one reason is that the loop effects are more significant because α s is much larger than α, and second the non-perturbative QCD effects may induce a sizable scalar potential. In this work, we study phenomenologically the contribution of the scalar potential to the spectra of charmonia, bottomonia and bc-bar (b-bar c) families. Taking into account both vector and scalar potentials, by fitting the well measured charmonia and bottomonia spectra, we re-fix the relevant parameters and test them by calculating other states of not only the charmonia and bottomonia families, but also the bc-bar family. We also consider the Lamb shift of the spectra. (authors)

Star formation suppression and bar ages in nearby barred galaxies

Science.gov (United States)

James, P. A.; Percival, S. M.

2018-03-01

We present new spectroscopic data for 21 barred spiral galaxies, which we use to explore the effect of bars on disc star formation, and to place constraints on the characteristic lifetimes of bar episodes. The analysis centres on regions of heavily suppressed star formation activity, which we term `star formation deserts'. Long-slit optical spectroscopy is used to determine H β absorption strengths in these desert regions, and comparisons with theoretical stellar population models are used to determine the time since the last significant star formation activity, and hence the ages of the bars. We find typical ages of ˜1 Gyr, but with a broad range, much larger than would be expected from measurement errors alone, extending from ˜0.25 to >4 Gyr. Low-level residual star formation, or mixing of stars from outside the `desert' regions, could result in a doubling of these age estimates. The relatively young ages of the underlying populations coupled with the strong limits on the current star formation rule out a gradual exponential decline in activity, and hence support our assumption of an abrupt truncation event.

Barred Owl [ds8

Data.gov (United States)

California Natural Resource Agency — These data define the current range of Barred and hybrid Barred/Spotted Owls in California. The current range includes the coastal mountains of northern California...

Spin-echo and STIR MR imaging of sports-related muscle injuries at 1.5 T

International Nuclear Information System (INIS)

Greco, A.; McNamara, M.T.; Escher, R.M.B.; Trifilio, G.; Parienti, J.

1990-01-01

This paper assesses the value of T2-weighted and short T1 inversion recovery (Stir 1,800,170,27) sequences in the MR diagnosis and follow-up of muscle strain injuries. Fifty-six athletes with clinically diagnosed traumatic muscular damage were studied at 1.5 T with SE T1-weighted, double T2-weighted, and STIR techniques. Images were evaluated in order to detect the presence of muscle tear with associated edema, muscle hemorrhage (focal or diffuse), and perimuscular hemorrhage. The relative conspicuity of muscle injuries on T2-weighted and STIR images was assessed. All acute and subacute muscle injuries were detected on both SE T2-weighted and STIR images, muscle edema and subacute hemorrhage appearing hyperintense to normal muscle. Acute hemorrhage could appear hypointense on T2-weighted images but was always hyperintense on STIR images

The investigation of typical welding defects for 5456 aluminum alloy friction stir welds

International Nuclear Information System (INIS)

Chen Huabin; Yan Keng; Lin Tao; Chen Shanben; Jiang Chengyu; Zhao Yong

2006-01-01

The external factors on the friction stir welding defects are so abundant that the experiments of friction stir welding were conducted for 5456 aluminum alloy. With the changes of the tool tilt angle and material condition, defects can be generated. These defects can be conventional ones (lack of penetration or voids), or lazy S, which are unique to friction stir welding. However, the origin of the defects remains an area of uncertainty. In this study, an attempt has been made to investigate the formation of these defects. The typical welding defects of friction stir welding joint for 5456 aluminum alloy were analyzed and discussed, respectively, by using optical microscopy (OM), energy-dispersive X-ray spectroscopy (EDS) and scanning electron microscope (SEM). The microscopic examination of the nugget zone and fracture location of the weld confirms that the tilt angle can change the plastic material flow patterns in the stir zone and accordingly control the weld properties. In addition, the oxide layer from the initial butt surface during FSW is dispersed at the grain boundary. These A1 2 O 3 particles are actually the major cause of failure of the joint

Removal of natural hormones in dairy farm wastewater using reactive and sorptive materials.

Science.gov (United States)

Cai, Kai; Phillips, Debra H; Elliott, Christopher T; Muller, Marc; Scippo, Marie-Louise; Connolly, Lisa

2013-09-01

The objective of this study was to examine the oestrogen and androgen hormone removal efficiency of reactive (Connelly zero-valent iron (ZVI), Gotthart Maier ZVI) and sorptive (AquaSorb 101 granular activated carbon (GAC) and OrganoLoc PM-100 organoclay (OC)) materials from HPLC grade water and constructed wetland system (CWS) treated dairy farm wastewater. Batch test studies were performed and hormone concentration analysis carried out using highly sensitive reporter gene assays (RGAs). The results showed that hormonal interaction with these materials is selective for individual classes of hormones. Connelly ZVI and AquaSorb 101 GAC were more efficient in removing testosterone (Te) than 17β-estradiol (E2) and showed faster removal rates of oestrogen and androgen than the other materials. Gotthart Maier ZVI was more efficient in removing E2 than Te. OrganoLoc PM-100 OC achieved the lowest final concentration of E2 equivalent (EEQ) and provided maximum removal of both oestrogens and androgens. Copyright © 2013 Elsevier B.V. All rights reserved.

Modelling of baffled stirred tanks

Energy Technology Data Exchange (ETDEWEB)

Ahlstedt, H.; Lahtinen, M. [Tampere Univ. of Technology (Finland). Energy and Process Engineering

1996-12-31

The three-dimensional flow field of a baffled stirred tank has been calculated using four different turbulence models. The tank is driven by a Rushton-type impeller. The boundary condition for the impeller region has been given as a source term or by calculating the impeller using the sliding mesh technique. Calculated values have been compared with measured data. (author)

Modelling of baffled stirred tanks

Energy Technology Data Exchange (ETDEWEB)

Ahlstedt, H; Lahtinen, M [Tampere Univ. of Technology (Finland). Energy and Process Engineering

1997-12-31

The three-dimensional flow field of a baffled stirred tank has been calculated using four different turbulence models. The tank is driven by a Rushton-type impeller. The boundary condition for the impeller region has been given as a source term or by calculating the impeller using the sliding mesh technique. Calculated values have been compared with measured data. (author)

Sorptivity of rocks and soils of the van Genuchten-Mualem type

Energy Technology Data Exchange (ETDEWEB)

Zimmerman, R.W.; Bodvarsson, G.S. [Lawrence Berkeley Lab., CA (United States)

1991-06-01

One hydrological process that will have great relevance to the performance of the proposed underground radioactive waste repository at Yucca Mountain, Nevada, is that of the absorption of water from a water-filled fracture into the adjacent unsaturated rock formation. The rate at which water is imbibed by a rock depends on the hydrological properties of the rock and on the initial saturation (or initial capillary suction) of the formation. The hydrological properties that affect imbibition are the relative permeability function and the capillary pressure function. These functions are often collectively referred to as the `characteristic functions` of the porous medium. For one-dimensional absorption, it can be shown that, regardless of the details of the characteristic functions, the total amount of water imbibed by the formation, per unit surface area, will be proportional to the square root of the elapsed time. Hence the ability of a rock or soil to imbibe water can be quantified by a parameter known as the sorptivity S, which is defined such that the cumulative volumetric liquid influx per unit area is given by Q = S{radical}t. The paper discusses the simplification of these characteristic functions of porous medium.

Mechanical properties of friction stir welded aluminum alloys 5083 and 5383

Directory of Open Access Journals (Sweden)

Jeom Kee Paik

2009-09-01

Full Text Available The use of high-strength aluminum alloys is increasing in shipbuilding industry, particularly for the design and construction of war ships, littoral surface craft and combat ships, and fast passenger ships. While various welding methods are used today to fabricate aluminum ship structures, namely gas metallic arc welding (GMAW, laser welding and friction stir welding (FSW, FSW technology has been recognized to have many advantages for the construction of aluminum structures, as it is a low-cost welding process. In the present study, mechanical properties of friction stir welded aluminum alloys are examined experimentally. Tensile testing is undertaken on dog-bone type test specimen for aluminum alloys 5083 and 5383. The test specimen includes friction stir welded material between identical alloys and also dissimilar alloys, as well as unwelded (base alloys. Mechanical properties of fusion welded aluminum alloys are also tested and compared with those of friction stir welded alloys. The insights developed from the present study are documented together with details of the test database. Part of the present study was obtained from the Ship Structure Committee project SR-1454 (Paik, 2009, jointly funded by its member agencies.

Performance Improvement of Friction Stir Welds by Better Surface Finish

Science.gov (United States)

Russell, Sam; Nettles, Mindy

2015-01-01

The as-welded friction stir weld has a cross section that may act as a stress concentrator. The geometry associated with the stress concentration may reduce the weld strength and it makes the weld challenging to inspect with ultrasound. In some cases, the geometry leads to false positive nondestructive evaluation (NDE) indications and, in many cases, it requires manual blending to facilitate the inspection. This study will measure the stress concentration effect and develop an improved phased array ultrasound testing (PAUT) technique for friction stir welding. Post-welding, the friction stir weld (FSW) tool would be fitted with an end mill that would machine the weld smooth, trimmed shaved. This would eliminate the need for manual weld preparation for ultrasonic inspections. Manual surface preparation is a hand operation that varies widely depending on the person preparing the welds. Shaving is a process that can be automated and tightly controlled.

Galaxy Zoo: Observing secular evolution through bars

International Nuclear Information System (INIS)

Cheung, Edmond; Faber, S. M.; Koo, David C.; Athanassoula, E.; Bosma, A.; Masters, Karen L.; Nichol, Robert C.; Melvin, Thomas; Bell, Eric F.; Lintott, Chris; Schawinski, Kevin; Skibba, Ramin A.; Willett, Kyle W.

2013-01-01

In this paper, we use the Galaxy Zoo 2 data set to study the behavior of bars in disk galaxies as a function of specific star formation rate (SSFR) and bulge prominence. Our sample consists of 13,295 disk galaxies, with an overall (strong) bar fraction of 23.6% ± 0.4%, of which 1154 barred galaxies also have bar length (BL) measurements. These samples are the largest ever used to study the role of bars in galaxy evolution. We find that the likelihood of a galaxy hosting a bar is anticorrelated with SSFR, regardless of stellar mass or bulge prominence. We find that the trends of bar likelihood and BL with bulge prominence are bimodal with SSFR. We interpret these observations using state-of-the-art simulations of bar evolution that include live halos and the effects of gas and star formation. We suggest our observed trends of bar likelihood with SSFR are driven by the gas fraction of the disks, a factor demonstrated to significantly retard both bar formation and evolution in models. We interpret the bimodal relationship between bulge prominence and bar properties as being due to the complicated effects of classical bulges and central mass concentrations on bar evolution and also to the growth of disky pseudobulges by bar evolution. These results represent empirical evidence for secular evolution driven by bars in disk galaxies. This work suggests that bars are not stagnant structures within disk galaxies but are a critical evolutionary driver of their host galaxies in the local universe (z < 1).

Field observations of nearshore bar formation

DEFF Research Database (Denmark)

Aagaard, Troels; Kroon, Aart; Greenwood, Brian

2008-01-01

  The formation of an inner nearshore bar was observed during a high-energy event at the sandy beach of Vejers, Denmark. The bar accreted in situ during surf zone conditions and the growth of the bar was associated with the development of a trough landward of the bar. Measurements of hydrodynamics...

Sustainability of Welding Process through Bobbin Friction Stir Welding

Science.gov (United States)

Sued, M. K.; Samsuri, S. S. M.; Kassim, M. K. A. M.; Nasir, S. N. N. M.

2018-03-01

Welding process is in high demand, which required a competitive technology to be adopted. This is important for sustaining the needs of the joining industries without ignoring the impact of the process to the environment. Friction stir welding (FSW) is stated to be benefitting the environment through low energy consumption, which cannot be achieved through traditional arc welding. However, this is not well documented, especially for bobbin friction stir welding (BFSW). Therefore, an investigation is conducted by measuring current consumption of the machine during the BFSW process. From the measurement, different phases of BFSW welding process and its electrical demand are presented. It is found that in general total energy in BFSW is about 130kW inclusive of all identified process phases. The phase that utilise for joint formation is in weld phase that used the highest total energy of 120kWs. The recorded total energy is still far below the traditional welding technology and the conventional friction stir welding (CFSW) energy demand. This indicates that BFSW technology with its vast benefit able to sustain the joining technology in near future.

Bar and Theta Hyperoperations

Directory of Open Access Journals (Sweden)

Thomas Vougiouklis

2011-12-01

Full Text Available In questionnaires the replacement of the scale of Likert by a bar was suggested in 2008 by Vougiouklis & Vougiouklis. The use of the bar was rapidly accepted in social sciences. The bar is closely related with fuzzy theory and has several advantages during both the filling-in questionnaires and mainly in the research processing. In this paper we relate hyperstructure theory with questionnaires and we study the obtained hyperstructures which are used as an organising device of the problem.

The role of graphene-based sorbents in modern sample preparation techniques.

Science.gov (United States)

de Toffoli, Ana Lúcia; Maciel, Edvaldo Vasconcelos Soares; Fumes, Bruno Henrique; Lanças, Fernando Mauro

2018-01-01

The application of graphene-based sorbents in sample preparation techniques has increased significantly since 2011. These materials have good physicochemical properties to be used as sorbent and have shown excellent results in different sample preparation techniques. Graphene and its precursor graphene oxide have been considered to be good candidates to improve the extraction and concentration of different classes of target compounds (e.g., parabens, polycyclic aromatic hydrocarbon, pyrethroids, triazines, and so on) present in complex matrices. Its applications have been employed during the analysis of different matrices (e.g., environmental, biological and food). In this review, we highlight the most important characteristics of graphene-based material, their properties, synthesis routes, and the most important applications in both off-line and on-line sample preparation techniques. The discussion of the off-line approaches includes methods derived from conventional solid-phase extraction focusing on the miniaturized magnetic and dispersive modes. The modes of microextraction techniques called stir bar sorptive extraction, solid phase microextraction, and microextraction by packed sorbent are discussed. The on-line approaches focus on the use of graphene-based material mainly in on-line solid phase extraction, its variation called in-tube solid-phase microextraction, and on-line microdialysis systems. © 2017 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

Characterisation of commercial aromatised vinegars: phenolic compounds, volatile composition and antioxidant activity.

Science.gov (United States)

Cejudo-Bastante, María J; Durán-Guerrero, Enrique; Natera-Marín, Ramón; Castro-Mejías, Remedios; García-Barroso, Carmelo

2013-04-01

Nineteen commercially available aromatised vinegars, which were representative of this type of product, were tested to ascertain their phenolic and volatile composition and antioxidant activity. The aromatised vinegars came from different raw materials such as fruits, spices, herbs and vegetables. The antioxidant activity was determined by means of photochemiluminescence, phenolic profile by using ultra performance liquid chromatography with ultraviolet detection, and the volatile composition was determined by using stir bar sorptive extraction-gas chromatography-mass spectrometry. Nine polyphenolic compounds and 141 volatile compounds were identified. Vinegar aromatised with black truffle and rosemary obtained the highest values of antioxidant activity, followed by those aromatised with lemon, tarragon, aromatic herbs and vegetables. Antioxidant activity was highly correlated with the presence of trans-p-coutaric acid, trans-caftaric acid, 5-hydroxy-methylfurfural and furfural. Moreover, (Z)-3-hexen-1-ol was exclusive to the vinegar aromatised with tarragon, while p-menth-1,8-ol, dimethyl styrene, 4-methyl acetophenone and nootkatone were only found in vinegar aromatised with lemon. On the basis of the results from the cluster analysis of cases, it can be concluded that the grouping responds more to the trademark of each vinegar than to the raw material. © 2012 Society of Chemical Industry.

Stirring the Ashes of Public Discourse.

Science.gov (United States)

Marinara, Martha

Sylvia Plath's confessional poem, "Lady Lazarus" can be used to illustrate a connection between autobiography and social critique. "You poke and stir" among the institutions that form social relations--the educational system, the court system, the economic system--to find individuals whose lives, whose joys and pains, and…

Numerical Study of Pollutant Emissions in a Jet Stirred Reactor under Elevated Pressure Lean Premixed Conditions

Directory of Open Access Journals (Sweden)

Karim Mazaheri

2016-01-01

Full Text Available Numerical study of pollutant emissions (NO and CO in a Jet Stirred Reactor (JSR combustor for methane oxidation under Elevated Pressure Lean Premixed (EPLP conditions is presented. A Detailed Flow-field Simplified Chemistry (DFSC method, a low computational cost method, is employed for predicting NO and CO concentrations. Reynolds Averaged Navier Stokes (RANS equations with species transport equations are solved. Improved-coefficient five-step global mechanisms derived from a new evolutionary-based approach were taken as combustion kinetics. For modeling turbulent flow field, Reynolds Stress Model (RSM, and for turbulence chemistry interactions, finite rate-Eddy dissipation model are employed. Effects of pressure (3, 6.5 bars and inlet temperature (408–573 K over a range of residence time (1.49–3.97 ms are numerically examined. A good agreement between the numerical and experimental distribution of NO and CO was found. The effect of decreasing the operating pressure on NO generation is much more than the effect of increase in the inlet temperature.

Measurement of the $\\bar{p}p \\rightarrow \\bar{n}n$ Charge-Exchange Differential Cross-Section

CERN Multimedia

2002-01-01

The aim of this proposal is a measurement of the differential cross-section of the $\\bar{p}$p $\\rightarrow$ $\\bar{n}$n charge-exchange reaction with a point-to-point precision of 1\\% in the forward direction, and an absolute normalization error of 3\\%. The high precision of the data should allow, inter alia, a determination of the $\\pi$NN coupling constant to better than 2\\%.\\\\ \\\\ The measurement will be done using the existing neutron and antineutron detectors built for experiment PS199 and liquid hydrogen target. In one week of running time, with a $\\bar{p}$ beam intensity of 3 $ 10 ^{5} $ $\\bar{p}$/sec, the reaction will be measured at a few $\\bar{p}$ momenta, in the range 500 to 900~MeV/c.

Effect of welding speed on microstructural and mechanical properties of friction stir welded Inconel 600

International Nuclear Information System (INIS)

Song, K.H.; Fujii, H.; Nakata, K.

2009-01-01

In order to evaluate the properties of a friction stir welded Ni base alloy, Inconel 600 (single phase type) was selected. Sound friction stir welds without weld defect were obtained at 150 and 200 mm/min in welding speed, however, a groove like defect occurred at 250 mm/min. The electron back scattered diffraction (EBSD) method was used to analyze the grain boundary character distribution. As a result, dynamic recrystallization was observed at all conditions, and the grain refinement was achieved in the stir zone, and it was gradually accelerated from 19 μm in average grain size of the base material to 3.4 μm in the stir zone with increasing the welding speed. It also has an effect on the mechanical properties so that friction stir welded zone showed 20% higher microhardness and 10% higher tensile strength than those of base material.

Nuss bar migrations: occurrence and classification

International Nuclear Information System (INIS)

Binkovitz, Lauren E.; Binkovitz, Larry A.; Zendejas, Benjamin; Moir, Christopher R.

2016-01-01

Pectus excavatum results from dorsal deviation of the sternum causing narrowing of the anterior-posterior diameter of the chest. It can result in significant cosmetic deformities and cardiopulmonary compromise if severe. The Nuss procedure is a minimally invasive technique that involves placing a thin horizontally oriented metal bar below the dorsal sternal apex for correction of the pectus deformity. To identify the frequency and types of Nuss bar migrations, to present a new categorization of bar migrations, and to present examples of true migrations and pseudomigrations. We retrospectively reviewed the electronic medical records and all pertinent radiologic studies of 311 pediatric patients who underwent a Nuss procedure. We evaluated the frequency and type of bar migrations. Bar migration was demonstrated in 23 of 311 patients (7%) and occurred within a mean period of 26 days after surgery. Bar migrations were subjectively defined as deviation of the bar from the position demonstrated on the immediate postoperative radiographs and categorized as superior, inferior, rotation, lateral or flipped using a new classification system. Sixteen of the 23 migrations required re-operation. Nuss bar migration can be diagnosed with careful evaluation of serial radiographs. Nuss bar migration has a wide variety of appearances and requires exclusion of pseudomigration resulting from changes in patient positioning between radiologic examinations. (orig.)

Nuss bar migrations: occurrence and classification

Energy Technology Data Exchange (ETDEWEB)

Binkovitz, Lauren E.; Binkovitz, Larry A. [Mayo Clinic, Department of Radiology, Rochester, MN (United States); Zendejas, Benjamin; Moir, Christopher R. [Mayo Clinic, Department of Surgery, Rochester, MN (United States)

2016-12-15

Pectus excavatum results from dorsal deviation of the sternum causing narrowing of the anterior-posterior diameter of the chest. It can result in significant cosmetic deformities and cardiopulmonary compromise if severe. The Nuss procedure is a minimally invasive technique that involves placing a thin horizontally oriented metal bar below the dorsal sternal apex for correction of the pectus deformity. To identify the frequency and types of Nuss bar migrations, to present a new categorization of bar migrations, and to present examples of true migrations and pseudomigrations. We retrospectively reviewed the electronic medical records and all pertinent radiologic studies of 311 pediatric patients who underwent a Nuss procedure. We evaluated the frequency and type of bar migrations. Bar migration was demonstrated in 23 of 311 patients (7%) and occurred within a mean period of 26 days after surgery. Bar migrations were subjectively defined as deviation of the bar from the position demonstrated on the immediate postoperative radiographs and categorized as superior, inferior, rotation, lateral or flipped using a new classification system. Sixteen of the 23 migrations required re-operation. Nuss bar migration can be diagnosed with careful evaluation of serial radiographs. Nuss bar migration has a wide variety of appearances and requires exclusion of pseudomigration resulting from changes in patient positioning between radiologic examinations. (orig.)

Optimization of friction stir welding process parameters to maximize tensile strength of stir cast AA6061-T6/AlNp composite

International Nuclear Information System (INIS)

Ashok Kumar, B.; Murugan, N.

2014-01-01

Highlights: • AA6061/AlN p cast composite was welded by FSW process. • Regression models were developed to predict UTS and elongation of the FS welded joint. • FS welded joint using the optimized parameters exhibited maximum UTS and joint efficiency. • Defect free weld joint was obtained with optimized parameters value. - Abstract: Aluminium Matrix Composites (AMCs) reinforced with particulate form of reinforcement has replaced monolithic alloys in many engineering industries due to its superior mechanical properties and tailorable thermal and electrical properties. As aluminium nitride (AlN) has high specific strength, high thermal conductivity, high electrical resistivity, low dielectric constant, low coefficient of thermal expansion and good compatibility with aluminium alloy, Al/AlN composite is extensively used in electronic packaging industries. Joining of AMCs is unavoidable in many engineering applications. Friction Stir Welding (FSW) is one of the most suitable welding process to weld the AMCs reinforced with particulate form of ceramics without deteriorating its superior mechanical properties. An attempt has been made to develop regression models to predict the Ultimate Tensile Strength (UTS) and Percent Elongation (PE) of the friction stir welded AA6061 matrix composite reinforced with aluminium nitride particles (AlN p ) by correlating the significant parameters such as tool rotational speed, welding speed, axial force and percentage of AlN p reinforcement in the AA6061 matrix. Statistical software SYSTAT 12 and statistical tools such as analysis of variance (ANOVA) and student’s t test, have been used to validate the developed models. It was observed from the investigation that these factors independently influenced the UTS and PE of the friction stir welded composite joints. The developed regression models were optimized to maximize UTS of friction stir welded AA6061/AlN p composite joints

Gas-solid hydroxyethylation of potato starch in a stirred vibrating fluidized bed reactor

NARCIS (Netherlands)

Kuipers, N.J M; Stamhuis, Eize; Beenackers, A.A C M

A novel reactor for modifying cohesive C-powders such as in the gas-solid hydroxyethylation of semidry potato starch is characterized, the so-called stirred vibrating fluidized bed reactor. Good fluidization characteristics are obtained in this reactor for certain combinations of stirring and

Friction Stir Processing of Cast Superalloys, Phase II

Data.gov (United States)

National Aeronautics and Space Administration — This SBIR effort examines the feasibility of an innovative fabrication technology incorporating sand casting and friction stir processing (FSP) for producing...

Analysis and Comparison of Friction Stir Welding and Laser Assisted Friction Stir Welding of Aluminum Alloy.

Science.gov (United States)

Campanelli, Sabina Luisa; Casalino, Giuseppe; Casavola, Caterina; Moramarco, Vincenzo

2013-12-18

Friction Stir Welding (FSW) is a solid-state joining process; i.e. , no melting occurs. The welding process is promoted by the rotation and translation of an axis-symmetric non-consumable tool along the weld centerline. Thus, the FSW process is performed at much lower temperatures than conventional fusion welding, nevertheless it has some disadvantages. Laser Assisted Friction Stir Welding (LAFSW) is a combination in which the FSW is the dominant welding process and the laser pre-heats the weld. In this work FSW and LAFSW tests were conducted on 6 mm thick 5754H111 aluminum alloy plates in butt joint configuration. LAFSW is studied firstly to demonstrate the weldability of aluminum alloy using that technique. Secondly, process parameters, such as laser power and temperature gradient are investigated in order to evaluate changes in microstructure, micro-hardness, residual stress, and tensile properties. Once the possibility to achieve sound weld using LAFSW is demonstrated, it will be possible to explore the benefits for tool wear, higher welding speeds, and lower clamping force.

Multiple pass and multiple layer friction stir welding and material enhancement processes

Science.gov (United States)

Feng, Zhili [Knoxville, TN; David, Stan A [Knoxville, TN; Frederick, David Alan [Harriman, TN

2010-07-27

Processes for friction stir welding, typically for comparatively thick plate materials using multiple passes and multiple layers of a friction stir welding tool. In some embodiments a first portion of a fabrication preform and a second portion of the fabrication preform are placed adjacent to each other to form a joint, and there may be a groove adjacent the joint. The joint is welded and then, where a groove exists, a filler may be disposed in the groove, and the seams between the filler and the first and second portions of the fabrication preform may be friction stir welded. In some embodiments two portions of a fabrication preform are abutted to form a joint, where the joint may, for example, be a lap joint, a bevel joint or a butt joint. In some embodiments a plurality of passes of a friction stir welding tool may be used, with some passes welding from one side of a fabrication preform and other passes welding from the other side of the fabrication preform.

Pulsed ultrasonic stir welding system

Science.gov (United States)

Ding, R. Jeffrey (Inventor)

2013-01-01

An ultrasonic stir welding system includes a welding head assembly having a plate and a rod passing through the plate. The rod is rotatable about a longitudinal axis thereof. During a welding operation, ultrasonic pulses are applied to the rod as it rotates about its longitudinal axis. The ultrasonic pulses are applied in such a way that they propagate parallel to the longitudinal axis of the rod.

In-Space Friction Stir Welding Machine, Phase I

Data.gov (United States)

National Aeronautics and Space Administration — Longhurst Engineering, PLC, and Vanderbilt University propose an in-space friction stir welding (FSW) machine for joining complex structural aluminum components. The...

Effect of microstructure on properties of friction stir welded Inconel Alloy 600

International Nuclear Information System (INIS)

Sato, Y.S.; Arkom, P.; Kokawa, H.; Nelson, T.W.; Steel, R.J.

2008-01-01

Friction stir welding (FSW) has been widely used to metals with moderate melting temperatures, primarily Al alloys. Recently, tool materials that withstand high stresses and temperatures necessary for FSW of materials with high melting temperatures have been developed. In the present study, polycrystalline cubic boron nitride (PCBN) tool was used for partially penetrated FSW of Inconel Alloy 600, and a defect-free weld was successfully produced. Microstructural characteristics, mechanical and corrosion properties in the weld were examined. The weld had better mechanical properties than the base material due to formation of fine grain structure in the stir zone, but exhibited slightly the lower corrosion resistance in a part of the stir zone and heat-affected zone (HAZ)

Friction stir welding process to repair voids in aluminum alloys

Science.gov (United States)

Rosen, Charles D. (Inventor); Litwinski, Edward (Inventor); Valdez, Juan M. (Inventor)

1999-01-01

The present invention provides an in-process method to repair voids in an aluminum alloy, particularly a friction stir weld in an aluminum alloy. For repairing a circular void or an in-process exit hole in a weld, the method includes the steps of fabricating filler material of the same composition or compatible with the parent material into a plug form to be fitted into the void, positioning the plug in the void, and friction stir welding over and through the plug. For repairing a longitudinal void (30), the method includes machining the void area to provide a trough (34) that subsumes the void, fabricating filler metal into a strip form (36) to be fitted into the trough, positioning the strip in the trough, and rewelding the void area by traversing a friction stir welding tool longitudinally through the strip. The method is also applicable for repairing welds made by a fusing welding process or voids in aluminum alloy workpieces themselves.

Modelling of the temperature field that accompanies friction stir welding

Directory of Open Access Journals (Sweden)

Nosal Przemysław

2017-01-01

Full Text Available The thermal modelling of the Friction Stir Welding process allows for better recognition and understanding of phenomena occurring during the joining process of different materials. It is of particular importance considering the possibilities of process technology parameters, optimization and the mechanical properties of the joint. This work demonstrates the numerical modelling of temperature distribution accompanying the process of friction stir welding. The axisymmetric problem described by Fourier’s type equation with internal heat source is considered. In order to solve the diffusive initial value problem a fully implicit scheme of the finite difference method is applied. The example under consideration deals with the friction stir welding of a plate (0.7 cm thick made of Al 6082-T6 by use of a tool made of tungsten alloy, whereas the material subjected to welding was TiC powder. Obtained results confirm both quantitatively and qualitatively experimental observations that the superior temperature corresponds to the zone where the pin joints the shoulder.

Reverberation chambers a la carte: an overview of the different mode-stirring techniques

NARCIS (Netherlands)

Serra, R.; Marvin, A.C.; Moglie, F.; Mariani Primiani, V.; Cozza, A.; Arnaut, L.R.; Huang, Y.; Hatfield, M.O.; Klingler, M.; Leferink, F.

2017-01-01

Reverberation chambers (RC), a name inspired in room acoustics, are also known in literature as reverberating, reverb, mode-stirred or mode-tuned chambers. In their basic form, they consist of a shielded metallic enclosure, forming a cavity resonator, together with some mode-stirring mechanism. The

Reverberation Chambers à La Carte : An Overview of the Different Mode-Stirring Techniques

NARCIS (Netherlands)

Serra, Ramiro; Marvin, Andy C.; Moglie, Franco; Mariani Primiani, Valter; Cozza, Andrea; Arnaut, Luk R.; Huang, Yi; Hatfield, Michael O.; Klingler, Marco; Leferink, Frank

2017-01-01

Reverberation chambers (RC), a name inspired in room acoustics, are also known in literature as reverberating, reverb, mode-stirred or mode-tuned chambers. In their basic form, they consist of a shielded metallic enclosure, forming a cavity resonator, together with some mode-stirring mechanism. The

Structural Phase Evolution in Ultrasonic-Assisted Friction Stir Welded 2195 Aluminum Alloy Joints

Science.gov (United States)

Eliseev, A. A.; Fortuna, S. V.; Kalashnikova, T. A.; Chumaevskii, A. V.; Kolubaev, E. A.

2017-10-01

The authors examined the structural and phase state of fixed joints produced by method of friction stir welding (FSW) and ultrasonic-assisted friction stir welding (UAFSW) from extruded profile of aluminum alloy AA2195. In order to identify the role of ultrasonic application in the course of welding, such characteristics, as volume fraction and average size of secondary particles are compared in the base material and stir zones of FSW and UAFSW joints. By applying the methods of SEM and TEM analysis, researchers established the complex character of phase transitions as a result of ultrasonic application.

Barred spiral structure of galaxies

International Nuclear Information System (INIS)

Chen, Z.; Weng, s.; Xu, M.

1982-01-01

Observational data indicate the grand design of spiral or barred spiral structure in disk galaxies. The problem of spiral structure has been thoroughly investigated by C. C. Lin and his collaborators, but yet the problem of barred spiral structure has not been investigated systematically, although much work has been done, such as in Ref. 3--7. Using the gasdynamic model for galaxies and a method of integral transform presented in Ref. 1, we investigated the barred spiral structure and obtained an analytical solution. It gives the large-scale pattern of barred-spirals, which is in fairly good agreement with observational data

Solid state crack repair by friction stir processing in 304L stainless steel

Institute of Scientific and Technical Information of China (English)

C.Gunter; M.P.Miles; F.C.Liu; T.W Nelson

2018-01-01

Friction stir processing (FSP) was investigated as a method of repairing cracks in 12mm thick 304L stainless steel plate.Healing feasibility was demonstrated by processing a tapered crack using a PCBN/WRe tool with a 25 mm diameter shoulder and a pin length of 6.4 mm.The experiment showed that it was possible to heal a crack that begins narrow and then progressively grows up to a width of 2 mm.Bead on plate experiments were used to find the best parameters for creating a consolidated stir zone with the least amount of hardness difference compared to the base metal.Grain refinement in some specimens resulted in much higher stir zone hardness,compared to base metal.A plot of grain size versus microhardness showed a very strong inverse correlation between grain size and hardness,as expected from the HallPetch relationship.Corrosion testing was carried out in order to evaluate the effect of FSP on potential sensitization of the stir zone.After 1000h of intermittent immersion in 3.5％ saline solution at room temperature it was found that no corrosion products formed on the base material controls or on any of the friction stir processed specimens.

Experimental studies of parameters affecting the heat generation in friction stir welding process

Directory of Open Access Journals (Sweden)

Mijajlović Miroslav M.

2012-01-01

Full Text Available Heat generation is a complex process of transformation of a specific type of energy into heat. During friction stir welding, one part of mechanical energy delivered to the welding tool is consumed in the welding process, another is used for deformational processes etc., and the rest of the energy is transformed into heat. The analytical procedure for the estimation of heat generated during friction stir welding is very complex because it includes a significant number of variables and parameters, and many of them cannot be fully mathematically explained. Because of that, the analytical model for the estimation of heat generated during friction stir welding defines variables and parameters that dominantly affect heat generation. These parameters are numerous and some of them, e. g. loads, friction coefficient, torque, temperature, are estimated experimentally. Due to the complex geometry of the friction stir welding process and requirements of the measuring equipment, adequate measuring configurations and specific constructional solutions that provide adequate measuring positions are necessary. This paper gives an overview of the process of heat generation during friction stir welding, the most influencing parameters on heat generation, constructional solutions for the measuring equipment needed for these experimental researches and examples of measured values.

Effect of electromagnetic stirring on solidification structure of austenitic stainless steel in horizontal continuous casting

Directory of Open Access Journals (Sweden)

ZHOU Shu-cai

2007-08-01

Full Text Available An investigation on the influence of low frequency rotary electromagnetic stirring on solidification structure of austenitic stainless steel in horizontal continuous casting was experimentally conducted and carried out on an industrial trial basis. The results show that application of appropriate electromagnetic stirring parameters can obviously improve the macrostructure of austenitic stainless steel, in which both columnar and equiaxed grains can be greatly refined and shrinkage porosity or cavity zone along centerline can be remarkably decreased due to eliminating intracrystalline and enlarging equiaxed grains zone. The industrial trials verify that the electromagnetic stirring intensity of austenitic stainless steel should be higher than that of plain carbon steel. Electromagnetic stirring has somewhat affected the macrostructure of austenitic stainless steel even if the magnetic flux density of the electromagnetic stirring reaches 90 mT (amplitude reaches 141 mT in average at frequency f=3-4Hz, which provides a reference for the optimization of design and process parameters when applying the rotary electromagnetic stirrer.

Friction Stir Processing of Cast Superalloys, Phase I

Data.gov (United States)

National Aeronautics and Space Administration — This SBIR Phase I effort examines the feasibility of an innovative fabrication technology incorporating sand casting and friction stir processing (FSP) for producing...

Too Much Bar and Not Enough Mitzvah? A Proposed Research Agenda on Bar/Bat Mitzvah

Science.gov (United States)

Schoenfeld, Stuart

2010-01-01

Jewish educators are understandably interested in research on how bar/bat mitzvah affect Jewish education or research on what Jewish schools have done to avoid the distortions of a focus on bar/bat mitzvah. Research might also focus on the somewhat different and more ambitious topic of the role that bar/bat mitzvah play in contemporary Jewish…

Measurement and Interpretation of Moments in Inclusive Semileptonic Decays (bar B) → Xc (ell)-(bar ν)

International Nuclear Information System (INIS)

Luth, Vera

2011-01-01

We present results for the moments of observed spectra in inclusive semileptonic B-meson decays to charm hadrons (bar B) → X c (ell) - (bar ν). Moments of the hadronic-mass and the combined mass-and-energy spectra for different minimum electron or muon momenta between 0.8 and 1.9 GeV/c are obtained from a sample of 232 x 10 6 Γ(4S) → B(bar B) events, collected with the BABAR detector at the PEP-II asymmetric-energy B-meson factory at SLAC. We also present a reevaluation of the moments of electron-energy spectra and partial decay fractions B((bar B) → X c e - (bar ν)) for minimum electron momenta between 0.6 and 1.5 GeV/c based on a sample of 51 x 10 6 Γ(4S) → B(bar B) events. The measurements are used for the extraction of the total decay fraction, the Cabibbo-Kobayashi-Maskawa (CKM) matrix element |V cb |, the quark masses m b and m c , and four heavy-quark QCD parameters in the framework of a Heavy-Quark Expansion (HQE). We find B((bar B) → X c (ell) - (bar ν)) = (10.64 ± 0.17 ± 0.06)% and |V cb | = (42.05 ± 0.45 ± 0.70) x 10 -3 .

Torque Control of Friction Stir Welding, Phase I

Data.gov (United States)

National Aeronautics and Space Administration — Longhurst Engineering, PLC and Vanderbilt University propose the innovation of torque control of friction stir welding (FSW) as a replacement to force control of...

Evaluation of sorptive flotation technique for enhanced removal of radioactive Eu(III) from aqueous solutions

Energy Technology Data Exchange (ETDEWEB)

Ezzat, Amir; Saad, Ebtissam A. [Ain Shams Univ., Cairo (Egypt). Chemistry Dept.; Mahmoud, Mamdoh R. [Atomic Energy Authority, Cairo (Egypt). Nuclear Chemistry Dept.; Soliman, Mohamed A. [Atomic Energy Authority, Cairo (Egypt). Egypt Second Research Reactor; Kandil, Abdelhakim [Helwan Univ., Cairo (Egypt). Chemistry Dept.

2017-06-01

The present study aims at the removal of Eu(III) from aqueous solutions by sorptive flotation process. This process involves adsorption of Eu(III) onto bentonite and kaolinite clays followed by floatation using sodium dodecyl sulfate (SDS) and cetyltrimethylammonium bromide (CTAB) collectors. The effect of adsorption parameters (pH, contact time, clay weight, Eu(III) concentration, ionic strength) as well as flotation parameters (collector and frother concentrations, bubbling time, concentrations of foreign cations and anions) on the removal efficiency of Eu(III) were studied. The obtained results show that Eu(III) ions are removed efficiently (R% ∝ 95%) at pH=4 after 1 h shaking with clay and 15 min floatation. The adsorption kinetics of Eu(III) onto the employed clays followed the pseudo-second-order model and the equilibrium data fitted well to the Freundlich isotherm model.

The Role of Friction Stir Welding in Nuclear Fuel Plate Fabrication

International Nuclear Information System (INIS)

Burkes, D.; Medvedev, P.; Chapple, M.; Amritkar, A.; Wells, P.; Charit, I

2009-01-01

The friction bonding process combines desirable attributes of both friction stir welding and friction stir processing. The development of the process is spurred on by the need to fabricate thin, high density, reduced enrichment fuel plates for nuclear research reactors. The work seeks to convert research and test reactors currently operating on highly enriched uranium fuel to operate on low enriched uranium fuel without significant loss in reactor performance, safety characteristics, or significant increase in cost. In doing so, the threat of global nuclear material proliferation will be reduced. Feasibility studies performed on the process show that this is a viable option for mass production of plate-type nuclear fuel. Adapting the friction stir weld process for nuclear fuel fabrication has resulted in the development of several unique ideas and observations. Preliminary results of this adaptation and process model development are discussed

Expandable antivibration bar for a steam generator

International Nuclear Information System (INIS)

Lagally, H.O.

1986-01-01

A steam generator tube support structure comprises expandable antivibration bars positioned between rows of tubes in the steam generator and attached to retaining rings surrounding the bundle of tubes. The antivibration bars have adjacent bar sections with mating surfaces formed as inclined planes which upon relative longitudinal motion between the upper and lower bars provides a means to increase the overall thickness across the structure to the required value. The bar section is retained against longitudinal movement in take-up assembly whereas the bar section is movable longitudinally by rotation of a nut. (author)

Study of J/psi -> p(p)over-bar and J/psi -> n(n)over-bar

NARCIS (Netherlands)

Ablikim, M.; Achasov, M. N.; Ambrose, D. J.; An, F. F.; An, Q.; An, Z. H.; Bai, J. Z.; Ban, Y.; Becker, J.; Berger, N.; Bertani, M.; Bian, J. M.; Boger, E.; Bondarenko, O.; Boyko, I.; Briere, R. A.; Bytev, V.; Cai, X.; Calcaterra, A.; Cao, G. F.; Chang, J. F.; Chelkov, G.; Chen, G.; Chen, H. S.; Chen, J. C.; Chen, M. L.; Chen, S. J.; Chen, Y.; Chen, Y. B.; Cheng, H. P.; Chu, Y. P.; Cronin-Hennessy, D.; Dai, H. L.; Dai, J. P.; Dedovich, D.; Deng, Z. Y.; Denig, A.; Denysenko, I.; Destefanis, M.; Ding, W. M.; Ding, Y.; Dong, L. Y.; Dong, M. Y.; Du, S. X.; Fang, J.; Fang, S. S.; Fava, L.; Feldbauer, F.; Feng, C. Q.; Ferroli, R. B.; Fu, C. D.; Fu, J. L.; Gao, Y.; Geng, C.; Goetzen, K.; Gong, W. X.; Gradl, W.; Greco, M.; Gu, M. H.; Gu, Y. T.; Guan, Y. H.; Guo, A. Q.; Guo, L. B.; Guo, Y. P.; Han, Y. L.; Hao, X. Q.; Harris, F. A.; He, K. L.; He, M.; He, Z. Y.; Held, T.; Heng, Y. K.; Hou, Z. L.; Hu, H. M.; Hu, J. F.; Hu, T.; Huang, B.; Huang, G. M.; Huang, J. S.; Huang, X. T.; Huang, Y. P.; Hussain, T.; Ji, C. S.; Ji, Q.; Ji, X. B.; Ji, X. L.; Jia, L. K.; Jiang, L. L.; Jiang, X. S.; Jiao, J. B.; Jiao, Z.; Jin, D. P.; Jin, S.; Jing, F. F.; Kalantar-Nayestanaki, N.; Kavatsyuk, M.; Kuehn, W.; Lai, W.; Lange, J. S.; Leung, J. K. C.; Li, C. H.; Li, Cheng; Li, Cui; Li, D. M.; Li, F.; Li, G.; Li, H. B.; Li, J. C.; Li, K.; Li, Lei; Li, N. B.; Li, Q. J.; Li, S. L.; Li, W. D.; Li, W. G.; Li, X. L.; Li, X. N.; Li, X. Q.; Li, X. R.; Li, Z. B.; Liang, H.; Liang, Y. F.; Liang, Y. T.; Liao, G. R.; Liao, X. T.; Liu, B. J.; Liu, B. J.; Liu, C. L.; Liu, C. X.; Liu, C. Y.; Liu, F. H.; Liu, Fang; Liu, Feng; Liu, H.; Liu, H. B.; Liu, H. H.; Liu, H. M.; Liu, H. W.; Liu, J. P.; Liu, K. Y.; Liu, Kai; Liu, Kun; Liu, P. L.; Liu, S. B.; Liu, X.; Liu, X. H.; Liu, Y.; Liu, Y. B.; Liu, Z. A.; Liu, Zhiqiang; Liu, Zhiqing; Loehner, H.; Lu, G. R.; Lu, H. J.; Lu, J. G.; Lu, Q. W.; Lu, X. R.; Lu, Y. P.; Luo, C. L.; Luo, M. X.; Luo, T.; Luo, X. L.; Lv, M.; Ma, C. L.; Ma, F. C.; Ma, H. L.; Ma, Q. M.; Ma, S.; Ma, T.; Ma, X. Y.; Ma, Y.; Maas, F. E.; Maggiora, M.; Malik, Q. A.; Mao, H.; Mao, Y. J.; Mao, Z. P.; Messchendorp, J. G.; Min, J.; Min, T. J.; Mitchell, R. E.; Mo, X. H.; Morales, C. Morales; Motzko, C.; Muchnoi, N. Yu.; Nefedov, Y.; Nicholson, C.; Nikolaev, I. B.; Ning, Z.; Olsen, S. L.; Ouyang, Q.; Pacetti, S.; Park, J. W.; Pelizaeus, M.; Peters, K.; Ping, J. L.; Ping, R. G.; Poling, R.; Prencipe, E.; Pun, C. S. J.; Qi, M.; Qian, S.; Qiao, C. F.; Qin, X. S.; Qin, Y.; Qin, Z. H.; Qiu, J. F.; Rashid, K. H.; Rong, G.; Ruan, X. D.; Sarantsev, A.; Schulze, J.; Shao, M.; Shen, C. P.; Shen, X. Y.; Sheng, H. Y.; Shepherd, M. R.; Song, X. Y.; Spataro, S.; Spruck, B.; Sun, D. H.; Sun, G. X.; Sun, J. F.; Sun, S. S.; Sun, X. D.; Sun, Y. J.; Sun, Y. Z.; Sun, Z. J.; Sun, Z. T.; Tang, C. J.; Tang, X.; Thorndike, E. H.; Tian, H. L.; Toth, D.; Ullrich, M.; Varner, G. S.; Wang, B.; Wang, B. Q.; Wang, K.; Wang, L. L.; Wang, L. S.; Wang, M.; Wang, P.; Wang, P. L.; Wang, Q.; Wang, Q. J.; Wang, S. G.; Wang, X. F.; Wang, X. L.; Wang, Y. D.; Wang, Y. F.; Wang, Y. Q.; Wang, Z.; Wang, Z. G.; Wang, Z. Y.; Wei, D. H.; Weidenkaff, P.; Wen, Q. G.; Wen, S. P.; Werner, M.; Wiedner, U.; Wu, L. H.; Wu, N.; Wu, S. X.; Wu, W.; Wu, Z.; Xia, L. G.; Xiao, Z. J.; Xie, Y. G.; Xiu, Q. L.; Xu, G. F.; Xu, G. M.; Xu, H.; Xu, Q. J.; Xu, X. P.; Xu, Y.; Xu, Z. R.; Xue, F.; Xue, Z.; Yan, L.; Yan, W. B.; Yan, Y. H.; Yang, H. X.; Yang, T.; Yang, Y.; Yang, Y. X.; Ye, H.; Ye, M.; Ye, M. H.; Yu, B. X.; Yu, C. X.; Yu, J. S.; Yu, S. P.; Yuan, C. Z.; Yuan, W. L.; Yuan, Y.; Zafar, A. A.; Zallo, A.; Zeng, Y.; Zhang, B. X.; Zhang, B. Y.; Zhang, C. C.; Zhang, D. H.; Zhang, H. H.; Zhang, H. Y.; Zhang, J.; Zhang, J. G.; Zhang, J. Q.; Zhang, J. W.; Zhang, J. Y.; Zhang, J. Z.; Zhang, L.; Zhang, S. H.; Zhang, T. R.; Zhang, X. J.; Zhang, X. Y.; Zhang, Y.; Zhang, Y. H.; Zhang, Y. S.; Zhang, Z. P.; Zhang, Z. Y.; Zhao, G.; Zhao, H. S.; Zhao, J. W.; Zhao, K. X.; Zhao, Lei; Zhao, Ling; Zhao, M. G.; Zhao, Q.; Zhao, S. J.; Zhao, T. C.; Zhao, X. H.; Zhao, Y. B.; Zhao, Z. G.; Zhemchugov, A.; Zheng, B.; Zheng, J. P.; Zheng, Y. H.; Zheng, Z. P.; Zhong, B.; Zhong, J.; Zhou, L.; Zhou, X. K.; Zhou, X. R.; Zhu, C.; Zhu, K.; Zhu, K. J.; Zhu, S. H.; Zhu, X. L.; Zhu, X. W.; Zhu, Y. M.; Zhu, Y. S.; Zhu, Z. A.; Zhuang, J.; Zou, B. S.; Zou, J. H.; Zuo, J. X.

2012-01-01

The decays J/psi -> p (p) over bar and J/psi -> n (n) over bar have been investigated with a sample of 225.2 x 10(6) J/psi events collected with the BESIII detector at the BEPCII e(+)e(-) collider. The branching fractions are determined to be B(J/psi -> p (p) over bar) = (2.112 +/- 0.004 +/- 0.031 x

The effect of postprocessing on tensile property and microstructure evolution of friction stir welding aluminum alloy joint

International Nuclear Information System (INIS)

Hu, Z.L.; Wang, X.S.; Pang, Q.; Huang, F.; Qin, X.P.; Hua, L.

2015-01-01

Friction stir welding is an efficient manufacturing method for joining aluminum alloy and can dramatically reduce grain size conferring excellent plastic deformation properties. Consequently, friction stir welding is used to manufacture tailor welded blanks to optimize weight or performance in the final component. In the study, the microstructural evolution and mechanical properties of friction stir welding joint during plastic forming and subsequent heat treatment were investigated. The microstructural characteristics of the friction stir welding joints were studied by Electron Backscattered Diffraction and Transmission Electron Microscopy. The mechanical properties were evaluated by tensile and microhardness tests. It is found that the tensile and yield strengths of friction stir welding joints are significantly improved after severe plastic deformation due to the grain refinement. Following heat treatment, the strength of the friction stir welding joints significantly decrease due to the obvious abnormal grain growth. Careful attention must be given to the processing route of any friction stir welding joint intended for plastic forming, especially the annealing between forming passes. Severe plastic deforming of the friction stir welding joint leads to a high level of stored energy/dislocation density, which causes the abnormal grain growth during subsequent heat treatment, and consequently reduce the mechanical properties of the friction stir welding joint. - Highlights: • Great changes are observed in the microstructure of FSW joint after postprocessing. • Postprocessing shows great effect on the microstructure stability of FSW joint. • The weld shows more significant decrease in strength than the BM due to the AGG. • Attention must be given to the processing route of FSW joint for plastic forming

Effect of tool geometry on friction stir spot welding of polypropylene sheets

Directory of Open Access Journals (Sweden)

M. K. Bilici

2012-10-01

Full Text Available The effects of tool geometry and properties on friction stir spot welding properties of polypropylene sheets were studied. Four different tool pin geometries, with varying pin angles, pin lengths, shoulder diameters and shoulder angles were used for friction stir spot welding. All the welding operations were done at the room temperature. Lap-shear tensile tests were carried out to find the weld static strength. Weld cross section appearance observations were also done. From the experiments the effect of tool geometry on friction stir spot weld formation and weld strength were determined. The optimum tool geometry for 4 mm thick polypropylene sheets were determined. The tapered cylindrical pin gave the biggest and the straight cylindrical pin gave the lowest lap-shear fracture load.

Stirred cell ultrafiltration of lignin from black liquor generated from South African kraft mills

CSIR Research Space (South Africa)

Kekana, Paul

2016-12-01

Full Text Available Ultrafiltration of lignin from black liquor was carried out in a stirred batch cell using polyethersulfone membranes. Parameters such as operating pressure, feed concentration, stirring rate and membrane cut-off size were varied and their effects...

Numerical optimisation of friction stir welding: review of future challenges

DEFF Research Database (Denmark)

Tutum, Cem Celal; Hattel, Jesper Henri

2011-01-01

During the last decade, the combination of increasingly more advanced numerical simulation software with high computational power has resulted in models for friction stir welding (FSW), which have improved the understanding of the determining physical phenomena behind the process substantially....... This has made optimisation of certain process parameters possible and has in turn led to better performing friction stir welded products, thus contributing to a general increase in the popularity of the process and its applications. However, most of these optimisation studies do not go well beyond manual...

Membrane-sculpting BAR domains generate stable lipid microdomains

DEFF Research Database (Denmark)

Zhao, Hongxia; Michelot, Alphée; Koskela, Essi V.

2013-01-01

Bin-Amphiphysin-Rvs (BAR) domain proteins are central regulators of many cellular processes involving membrane dynamics. BAR domains sculpt phosphoinositide-rich membranes to generate membrane protrusions or invaginations. Here, we report that, in addition to regulating membrane geometry, BAR...... domains can generate extremely stable lipid microdomains by "freezing" phosphoinositide dynamics. This is a general feature of BAR domains, because the yeast endocytic BAR and Fes/CIP4 homology BAR (F-BAR) domains, the inverse BAR domain of Pinkbar, and the eisosomal BAR protein Lsp1 induced...... phosphoinositide clustering and halted lipid diffusion, despite differences in mechanisms of membrane interactions. Lsp1 displays comparable low diffusion rates in vitro and in vivo, suggesting that BAR domain proteins also generate stable phosphoinositide microdomains in cells. These results uncover a conserved...

Membrane-Sculpting BAR Domains Generate Stable Lipid Microdomains

Science.gov (United States)

Zhao, Hongxia; Michelot, Alphée; Koskela, Essi V.; Tkach, Vadym; Stamou, Dimitrios; Drubin, David G.; Lappalainen, Pekka

2014-01-01

SUMMARY Bin-Amphiphysin-Rvs (BAR) domain proteins are central regulators of many cellular processes involving membrane dynamics. BAR domains sculpt phosphoinositide-rich membranes to generate membrane protrusions or invaginations. Here, we report that, in addition to regulating membrane geometry, BAR domains can generate extremely stable lipid microdomains by “freezing” phosphoinositide dynamics. This is a general feature of BAR domains, because the yeast endocytic BAR and Fes/CIP4 homology BAR (F-BAR) domains, the inverse BAR domain of Pinkbar, and the eisosomal BAR protein Lsp1 induced phosphoinositide clustering and halted lipid diffusion, despite differences in mechanisms of membrane interactions. Lsp1 displays comparable low diffusion rates in vitro and in vivo, suggesting that BAR domain proteins also generate stable phosphoinositide microdomains in cells. These results uncover a conserved role for BAR superfamily proteins in regulating lipid dynamics within membranes. Stable microdomains induced by BAR domain scaffolds and specific lipids can generate phase boundaries and diffusion barriers, which may have profound impacts on diverse cellular processes. PMID:24055060

A fundamental study on the structural integrity of magnesium alloys joined by friction stir welding

Science.gov (United States)

Rao, Harish Mangebettu

The goal of this research is to study the factors that influence the physical and mechanical properties of lap-shear joints produced using friction stir welding. This study focuses on understanding the effect of tool geometry and weld process parameters including the tool rotation rate, tool plunge depth and dwell time on the mechanical performance of similar magnesium alloy and dissimilar magnesium to aluminum alloy weld joints. A variety of experimental activities were conducted including tensile and fatigue testing, fracture surface and failure analysis, microstructure characterization, hardness measurements and chemical composition analysis. An investigation on the effect of weld process conditions in friction stir spot welding of magnesium to magnesium produced in a manner that had a large effective sheet thickness and smaller interfacial hook height exhibited superior weld strength. Furthermore, in fatigue testing of friction stir spot welded of magnesium to magnesium alloy, lap-shear welds produced using a triangular tool pin profile exhibited better fatigue life properties compared to lap-shear welds produced using a cylindrical tool pin profile. In friction stir spot welding of dissimilar magnesium to aluminum, formation of intermetallic compounds in the stir zone of the weld had a dominant effect on the weld strength. Lap-shear dissimilar welds with good material mixture and discontinues intermetallic compounds in the stir zone exhibited superior weld strength compared to lap-shear dissimilar welds with continuous formation of intermetallic compounds in the stir zone. The weld structural geometry like the interfacial hook, hook orientation and bond width also played a major role in influencing the weld strength of the dissimilar lap-shear friction stir spot welds. A wide scatter in fatigue test results was observed in friction stir linear welds of aluminum to magnesium alloys. Different modes of failure were observed under fatigue loading including crack

Effect of shoulder to pin ratio on magnesium alloy Friction Stir Welding

Science.gov (United States)

Othman, N. H.; Ishak, M.; Shah, L. H.

2017-09-01

This study focuses on the effect of shoulder to pin diameter ratio on friction stir welding of magnesium alloy AZ31. Two pieces of AZ31 alloy with thickness of 2 mm were friction stir welded by using conventional milling machine. The shoulder to pin diameter ratio used in this experiment are 2.25, 2.5, 2.75, 3, 3.33, 3.66, 4.5, 5 and 5.5. The rotational speed and welding speed used in this study are 1000 rpm and 100 mm/min, respectively. Microstructure observation of welded area was studied by using optical microscope. Equiaxed grains were observed at the TMAZ and stir zone indicating fully plastic deformation. The grain size of stir zone increased with decreasing shoulder to pin ratio from ratio 3.33 to 5.5 due to higher heat input. It is observed that, surface galling and faying surface defect is produced when excessive heat input is applied. To evaluate the mechanical properties of this specimen, tensile test was used in this study. Shoulder to pin ratio 5.5 shows lowest tensile strength while shoulder to pin diameter ratio 3.33 shows highest tensile strength with weld efficiency 91 % from based metal.

The BaBar Mini

International Nuclear Information System (INIS)

Brown, David N.

2003-01-01

BaBar has recently deployed a new event data format referred to as the Mini. The mini uses efficient packing and aggressive noise suppression to represent the average reconstructed BaBar event in under 7 KBytes. The Mini packs detector information into simple transient data objects, which are then aggregated into roughly 10 composite persistent objects per event. The Mini currently uses Objectivity persistence, and it is being ported to use Root persistence. The Mini contains enough information to support detailed detector studies, while remaining small and fast enough to be used directly in physics analysis. Mini output is customizable, allowing users to both truncate unnecessary content or add content, depending on their needs. The Mini has now replaced three older formats as the primary output of BaBar event reconstruction. A reduced form of the Mini will soon replace the physics analysis format as well, giving BaBar a single, flexible event data format covering all its needs

The BaBar mini

International Nuclear Information System (INIS)

Brown, David N.; BaBar Collaboration

2003-01-01

BaBar has recently deployed a new event data format referred to as the Mini. The mini uses efficient packing and aggressive noise suppression to represent the average reconstructed BaBar event in under 7 KBytes. The Mini packs detector information into simple transient data objects, which are then aggregated into roughly 10 composite persistent objects per event. The Mini currently uses Objectivity persistence, and it is being ported to use Root persistence. The Mini contains enough information to support detailed detector studies, while remaining small and fast enough to be used directly in physics analysis. Mini output is customizable, allowing users to both truncate unnecessary content or add content, depending on their needs. The Mini has now replaced three older formats as the primary output of BaBar event reconstruction. A reduced form of the Mini will soon replace the physics analysis format as well, giving BaBar a single, flexible event data format covering all its needs

A mathematical high bar-human body model for analysing and interpreting mechanical-energetic processes on the high bar.

Science.gov (United States)

Arampatzis, A; Brüggemann, G P

1998-12-01

The aims of this study were: 1. To study the transfer of energy between the high bar and the gymnast. 2. To develop criteria from the utilisation of high bar elasticity and the utilisation of muscle capacity to assess the effectiveness of a movement solution. 3. To study the influence of varying segment movement upon release parameters. For these purposes a model of the human body attached to the high bar (high bar-human body model) was developed. The human body was modelled using a 15-segment body system. The joint-beam element method (superelement) was employed for modelling the high bar. A superelement consists of four rigid segments connected by joints (two Cardan joints and one rotational-translational joint) and springs (seven rotation springs and one tension-compression spring). The high bar was modelled using three superelements. The input data required for the high bar human body model were collected with video-kinematographic (50 Hz) and dynamometric (500 Hz) techniques. Masses and moments of inertia of the 15 segments were calculated using the data from the Zatsiorsky et al. (1984) model. There are two major phases characteristic of the giant swing prior to dismounts from the high bar. In the first phase the gymnast attempts to supply energy to the high bar-humanbody system through muscle activity and to store this energy in the high bar. The difference between the energy transferred to the high bar and the reduction in the total energy of the body could be adopted as a criterion for the utilisation of high bar elasticity. The energy previously transferred into the high bar is returned to the body during the second phase. An advantageous increase in total body energy at the end of the exercise could only be obtained through muscle energy supply. An index characterising the utilisation of muscle capacity was developed out of the difference between the increase in total body energy and the energy returned from the high bar. A delayed and initially slow but

Understanding Friction Stir Welding

Science.gov (United States)

Nunes, A. C., Jr.

2018-01-01

This Technical Memorandum explains the friction stir welding process in terms of two basic concepts: the concentration of deformation in a shear surface enveloping the tool and the composition of the overall plastic flow field around the tool from simple flow field components. It is demonstrated how weld structure may be understood and torque, drag, and lateral tool forces may be estimated using these concepts. Some discrepancies between computations and accompanying empirical data are discussed in the text. This work is intended to be helpful to engineers in diagnosing problems and advancing technology.

Measurement of the absolute branching fraction of D-vertical bar -> (K)over-bar(0)e(vertical bar) nu(e) via (K)over-bar(0) -> pi(0)pi(0)

NARCIS (Netherlands)

Ablikim, M.; Achasov, N.; Ai, X. C.; Albayrak, O.; Albrecht, M.; Ambrose, D. J.; Amoroso, A.; An, F. F.; An, Q.; Bai, J. Z.; Ferroli, R. Baldini; Ban, Y.; Bennett, D. W.; Bennett, J. V.; Bertani, M.; Bettonin, D.; Bian, J. M.; Bianchi, F.; Boger, E.; Boyko, I.; Briere, R. A.; Cai, H.; Cai, X.; Cakir, O.; Caleaterra, A.; Cao, G. F.; Cetin, S. A.; Chang, J. F.; Chelkov, G.; Chen, G.; Chen, H. S.; Chen, H. Y.; Chen, J. C.; Chen, M. L.; Chen, S.; Chen, S. J.; Chen, X.; Chen, X. R.; Chen, Y. B.; Cheng, H. P.; Chu, X. K.; Cibinetto, G.; Dai, H. L.; Dai, J. P.; Dbeyssi, A.; Dedovich, D.; Deng, Z. Y.; Denig, A.; Denysenko, I.; Destefanis, M.; De Mori, F.; Ding, Y.; Dong, C.; Dong, J.; Dong, L. Y.; Dong, M. Y.; Dou, Z. L.; Du, S. X.; Duan, P. F.; Fan, J. Z.; Fang, J.; Fang, S. S.; Fang, X.; Fang, Y.; Farinelli, R.; Fava, L.; Fedorov, O.; Feldbauer, F.; Felici, G.; Feng, C. Q.; Fioravanti, E.; Fritsch, M.; Fu, C. D.; Gao, Q.; Gao, X. L.; Gao, X. Y.; Gao, Y.; Gao, Z.; Garzia, I.; Goetzen, K.; Gong, L.; Gong, W. X.; Gradl, W.; Greco, M.; Gu, M. H.; Gu, Y. T.; Guan, Y. H.; Guo, A. Q.; Guo, L. B.; Guo, R. P.; Guo, Y.; Guo, Y. P.; Haddadi, Z.; Hafner, A.; Han, S.; Hao, X. Q.; Harris, F. A.; He, K. L.; Held, T.; Heng, Y. K.; Hou, Z. L.; Hu, C.; Hu, H. M.; Hu, J. F.; Hu, T.; Hu, Y.; Huang, G. S.; Huang, J. S.; Huang, X. T.; Huang, X. Z.; Huang, Y.; Huang, Z. L.; Hussain, T.; Ji, Q.; Ji, Q. P.; Ji, X. B.; Ji, X. L.; Jiang, L. W.; Jiang, X. S.; Jiang, X. Y.; Jiao, J. B.; Jiao, Z.; Jin, D. P.; Jin, S.; Johansson, T.; Julin, A.; Kalantar-Nayestanaki, N.; Kang, X. L.; Kang, X. S.; Kavatsyuk, M.; Ke, B. C.; Kiese, P.; Kliemt, R.; Kloss, B.; Kolc, O. B.; Kopf, B.; Kornicer, M.; Kupse, A.; Kuehn, W.; Lange, J. S.; Lara, M.; Larin, P.; Leng, C.; Li, C.; Li, Cheng; Li, D. M.; Li, F.; Li, F. Y.; Li, G.; Li, H. B.; Li, H. J.; Li, J. C.; Li, Jin; Li, K.; Li, K.; Li, Lei; Li, P. R.; Li, Q. Y.; Li, T.; Li, W. D.; Li, W. G.; Li, X. L.; Li, X. N.; Li, X. Q.; Li, Y. B.; Li, Z. B.; Liang, H.; Liang, Y. F.; Liang, Y. T.; Liao, G. R.; Lin, D. X.; Liu, B.; Liu, B. J.; Liu, C. X.; Liu, D.; Liu, F. H.; Liu, Fang; Liu, Feng; Liu, H. B.; Liu, H. H.; Liu, H. H.; Liu, H. M.; Liu, J.; Liu, J. B.; Liu, J. P.; Liu, J. Y.; Liu, K.; Liu, K. Y.; Liu, L. D.; Liu, P. L.; Liu, Q.; Liu, S. B.; Liu, X.; Liu, Y. B.; Liu, Z. A.; Liu, Zhiqing; Loehner, H.; Lou, X. C.; Lu, H. J.; Lu, J. G.; Lu, Y.; Lu, Y. P.; Luo, C. L.; Luo, M. X.; Luo, T.; Luo, X. L.; Lu, X. R.; Ma, F. C.; Ma, H. L.; Ma, L. L.; Ma, M. M.; Ma, Q. M.; Ma, T.; Ma, X. N.; Ma, X. Y.; Ma, Y. M.; Maas, F. E.; Maggiora, M.; Mao, Y. J.; Mao, Z. P.; Marcello, S.; Messchendorp, J. G.; Min, J.; Min, T. J.; Mitchell, R. E.; Mo, X. H.; Mo, Y. J.; Morales, C. Morales; Muchnoi, N. Yu.; Muramatsu, H.; Nefedov, Y.; Nerling, F.; Nikolaev, I. B.; Ning, Z.; Nisar, S.; Niu, S. L.; Niu, X. Y.; Olsen, S. L.; Ouyang, Q.; Pacetti, S.; Pan, Y.; Patteri, P.; Pelizaeus, M.; Peng, H. P.; Peters, K.; Pettersson, J.; Ping, J. L.; Ping, R. G.; Poling, R.; Prasad, V.; Qi, H. R.; Qi, M.; Qian, S.; Qiao, C. F.; Qin, L. Q.; Qin, N.; Qin, X. S.; Qin, Z. H.; Qiu, J. F.; Rashid, K. H.; Redmer, C. F.; Ripka, M.; Rong, G.; Rosner, Ch.; Ruan, X. D.; Sarantsev, A.; Savrie, M.; Schoenning, K.; Schumann, S.; Shan, W.; Shao, M.; Shen, C. P.; Shen, P. X.; Shen, X. Y.; Sheng, H. Y.; Shi, M.; Song, W. M.; Song, X. Y.; Sosio, S.; Spataro, S.; Sun, G. X.; Sun, J. F.; Sun, S. S.; Sun, X. H.; Sun, Y. J.; Sun, Y. Z.; Sun, Z. J.; Sun, Z. T.; Tang, C. J.; Tang, X.; Tapan, I.; Thorndike, E. H.; Tiemens, M.; Ullrich, M.; Uman, I.; Varner, G. S.; Wang, B.; Wang, B. L.; Wang, D.; Wang, D. Y.; Wang, K.; Wang, L. L.; Wang, L. S.; Wang, M.; Wang, P.; Wang, P. L.; Wang, W.; Wang, W. P.; Wang, X. F.; Wang, Y.; Wang, Y. D.; Wang, Y. F.; Wang, Y. Q.; Wang, Z.; Wang, Z. G.; Wang, Z. H.; Wang, Z. Y.; Wang, Z. Y.; Weber, T.; Wei, D. H.; Weidenkaff, P.; Wen, S. P.; Wiedner, U.; Wolke, M.; Wu, L. H.; Wu, L. J.; Wu, Z.; Xia, L.; Xia, Y.; Xiao, D.; Xiao, H.; Xiao, Z. J.; Xie, Y. G.; Xiu, Q. L.; Xu, G. F.; Xu, J. J.; Xu, L.; Xu, Q. J.; Xu, Q. N.; Xu, X. P.; Yan, L.; Yan, W. B.; Yan, W. C.; Yan, Y. H.; Yang, H. J.; Yang, H. X.; Yang, L.; Yang, Y. X.; Ye, M.; Ye, M. H.; Yin, J. H.; Yu, B. X.; Yu, C. X.; Yu, J. S.; Yuan, C. Z.; Yuan, W. L.; Yuan, Y.; Yuncu, A.; Zafar, A. A.; Zallo, A.; Zeng, Y.; Zeng, Z.; Zhang, B. X.; Zhang, B. Y.; Zhang, C.; Zhang, C. C.; Zhang, D. H.; Zhang, H. H.; Zhang, H. Y.; Zhang, J.; Zhang, J. J.; Zhang, J. L.; Zhang, J. Q.; Zhang, J. W.; Zhang, J. Y.; Zhang, J. Z.; Zhang, K.; Zhang, L.; Zhang, S. Q.; Zhang, X. Y.; Zhang, Y.; Zhang, Y. H.; Zhang, Y. N.; Zhang, Y. T.; Zhang, Yu; Zhang, Z. H.; Zhang, Z. P.; Zhang, Z. Y.; Zhao, G.; Zhao, J. W.; Zhao, J. Y.; Zhao, J. Z.; Zhao, Lei; Zhao, Ling; Zhao, M. G.; Zhao, Q.; Zhao, Q. W.; Zhao, S. J.; Zhao, T. C.; Zhao, Y. B.; Zhao, Z. G.; Zhemchugov, A.; Zheng, B.; Zheng, J. P.; Zheng, W. J.; Zheng, Y. H.; Zhong, B.; Zhou, L.; Zhou, X.; Zhou, X. K.; Zhou, X. R.; Zhou, X. Y.; Zhu, K.; Zhu, K. J.; Zhu, S.; Zhu, S. H.; Zhu, X. L.; Zhu, Y. C.; Zhu, Y. S.; Zhu, Z. A.; Zhuangig, J.; Zotti, L.; Zou, B. S.; Zou, J. H.

2016-01-01

By analyzing 2.93 fb(-1) data collected at the center-of-mass energy root s = 3.773 GeV with the BESIII detector, we measure the absolute branching fraction of the semileptonic decay D+ -> (K) over bar (0)e(+)nu(e) to be B(D (+) -> (K) over bar (0)e(+)nu(e)) = (8.59 +/- 0.14 +/- 0.21)% using (K)

Mechanical properties and microstructural evaluation of AA1100 to AZ31 dissimilar friction stir welds

Energy Technology Data Exchange (ETDEWEB)

Azizieh, M., E-mail: azizieh@gmail.com [Department of Materials Science and Engineering, Ahvaz Branch, Islamic Azad University, Ahvaz (Iran, Islamic Republic of); Sadeghi Alavijeh, A. [School of Mechatronic Systems Engineering, Simon Fraser University, 250-13450 102 Avenue, Surrey, BC V3T 0A3 (Canada); Abbasi, M. [High Temperature Energy Materials, Korea Institute of Science and Technology, Seoul, 136-791 (Korea, Republic of); Balak, Z. [Department of Materials Science and Engineering, Ahvaz Branch, Islamic Azad University, Ahvaz (Iran, Islamic Republic of); Kim, H.S. [Department of Materials Science and Engineering, Pohang University of Science and Technology, Pohang, 790-784 (Korea, Republic of)

2016-02-15

In this paper, microstructure and mechanical properties of dissimilar friction stir welds of AA1100 and AZ31 were investigated to understand the effects of rotational and travel speed as well as pin position. The tensile results of welded samples revealed that the sound welds were formed when the stirring pin deviated from the centreline to the AZ31 side. The X-ray diffraction shows that Al{sub 3}Mg{sub 2} and Al{sub 12}Mg{sub 17} intermetallics formation occurs in the stir zone during the welding process. High hardness of these intermetallic phases increased the hardness of the stir zone to 110 Hv. The best tensile results were obtained in the sample processed in the range of 28–32 (rev/mm) rotational to travel speed ratio. - Highlights: • For Al to Mg friction stir welding, tool offset must be to Mg side. • There is an optimum rotational speed for obtain the highest strength. • Intermetallics form in any welding condition. • The volume fraction of intermetallic is directly related to FSW peak temperature.

The erosion performance of cold spray deposited metal matrix composite coatings with subsequent friction stir processing

Energy Technology Data Exchange (ETDEWEB)

Peat, Tom, E-mail: tompeat12@gmail.com [Department of Mechanical & Aerospace Engineering, University of Strathclyde, James Weir Building, 75 Montrose Street, Glasgow G1 1XJ (United Kingdom); Galloway, Alexander; Toumpis, Athanasios [Department of Mechanical & Aerospace Engineering, University of Strathclyde, James Weir Building, 75 Montrose Street, Glasgow G1 1XJ (United Kingdom); McNutt, Philip [TWI Ltd., Granta Park, Cambridge CB21 6AL (United Kingdom); Iqbal, Naveed [TWI Technology Centre, Wallis Way, Catcliff, Rotherham, S60 5TZ (United Kingdom)

2017-02-28

Highlights: • WC-CoCr, Cr{sub 3}C{sub 2}-NiCr and Al{sub 2}O{sub 3} coatings were cold spray deposited on AA5083 and friction stir processed. • The SprayStirred WC-CoCr demonstrated a hardness increase of 100% over the cold sprayed coating. • As-deposited and SprayStirred coatings were examined under slurry erosion test conditions. • Mass and volume loss was measured following 20-min exposure to the slurry. • The WC-CoCr and Al2O3 demonstrated a reduction in volume loss of approx. 40% over the cold sprayed coating. - Abstract: This study forms an initial investigation into the development of SprayStir, an innovative processing technique for generating erosion resistant surface layers on a chosen substrate material. Tungsten carbide – cobalt chromium, chromium carbide – nickel chromium and aluminium oxide coatings were successfully cold spray deposited on AA5083 grade aluminium. In order to improve the deposition efficiency of the cold spray process, coatings were co-deposited with powdered AA5083 using a twin powder feed system that resulted in thick (>300 μm) composite coatings. The deposited coatings were subsequently friction stir processed to embed the particles in the substrate in order to generate a metal matrix composite (MMC) surface layer. The primary aim of this investigation was to examine the erosion performance of the SprayStirred surfaces and demonstrate the benefits of this novel process as a surface engineering technique. Volumetric analysis of the SprayStirred surfaces highlighted a drop of approx. 40% in the level of material loss when compared with the cold spray deposited coating prior to friction stir processing. Micro-hardness testing revealed that in the case of WC-CoCr reinforced coating, the hardness of the SprayStirred material exhibits an increase of approx. 540% over the unaltered substrate and 120% over the as-deposited composite coating. Microstructural examination demonstrated that the increase in the hardness of the

Bar Coding and Tracking in Pathology.

Science.gov (United States)

Hanna, Matthew G; Pantanowitz, Liron

2016-03-01

Bar coding and specimen tracking are intricately linked to pathology workflow and efficiency. In the pathology laboratory, bar coding facilitates many laboratory practices, including specimen tracking, automation, and quality management. Data obtained from bar coding can be used to identify, locate, standardize, and audit specimens to achieve maximal laboratory efficiency and patient safety. Variables that need to be considered when implementing and maintaining a bar coding and tracking system include assets to be labeled, bar code symbologies, hardware, software, workflow, and laboratory and information technology infrastructure as well as interoperability with the laboratory information system. This article addresses these issues, primarily focusing on surgical pathology. Copyright © 2016 Elsevier Inc. All rights reserved.

Characterization of Bars Induced by Interactions

Directory of Open Access Journals (Sweden)

Inma Martinez-Valpuesta

2016-05-01

Full Text Available Whether the formation of bars is triggered by interactions or by internal processes has been discussed for many decades. In this work, we study differences between both mechanisms by means of numerical simulations. We relate our analysis to fly-by interactions in different mass groups or clusters according to the velocity of the encounters. We find that once the bar is created, the interaction does not much affect its evolution. We also find that bars can be triggered purely by a slow interaction. Those bars affected or triggered by interaction stay for a longer time in the slow regime, i.e., the corotation radius is more than 1.4 times the bar radius.

Hanging off a bar

NARCIS (Netherlands)

Mueller, F.; Walmink, W.; Toprak, C.; Bongers, Bert; Graether, E.; Hoven, van den E.A.W.H.

2012-01-01

Exertion Games involve physical effort and as a result can facilitate physical health benefits. We present Hanging off a Bar, an action hero-inspired Exertion Game in which players hang off an exercise bar over a virtual river for as long as possible. Initial observations from three events with

Raising the bar (6)

NARCIS (Netherlands)

Elhorst, Paul; Abreu, Maria; Amaral, Pedro; Bhattacharjee, Arnab; Corrado, Luisa; Doran, Justin; Fingleton, Bernard; Fuerst, Franz; Garretsen, Harry; Igliori, Danilo; Le Gallo, Julie; McCann, Philip; Monastiriotis, Vassilis; Quatraro, Francesco; Yu, Jihai

2017-01-01

Raising the bar (6). Spatial Economic Analysis. This editorial summarizes and comments on the papers published in issue 12(4) so as to raise the bar in applied spatial economic research and highlight new trends. The first paper addresses the question of whether 'jobs follow people' or 'people follow

A permeability model for coal and other fractured, sorptive-elastic media

Energy Technology Data Exchange (ETDEWEB)

Robertson, E.P.; Christiansen, R.L. [Marathon Oil Co., Houston, TX (United States). Research & Development Facility

2008-09-15

This paper describes the derivation of a new equation that can be used to model the permeability behavior of a fractured, sorptive-elastic medium, such as coal, under variable stress conditions. The equation is applicable to confinement pressure schemes commonly used during the collection of permeability data in the laboratory. The model is derived for cubic geometry under biaxial or hydrostatic confining pressures. The model is designed to handle changes in permeability caused by adsorption and desorption of gases onto and from the matrix blocks in fractured media. The model equations can be used to calculate permeability changes caused by the production of methane (CH{sub 4}) from coal as well as the injection of gases, such as carbon dioxide, for sequestration in coal. Sensitivity analysis of the model found that each of the input variables can have a significant impact on the outcome of the permeability forecast as a function of changing pore pressure, thus, accurate input data are essential. The permeability model also can be used as a tool to determine input parameters for field simulations by curve fitting laboratory-generated permeability data. The new model is compared to two other widely used coal-permeability models using a hypothetical coal with average properties.

Why Are Some Galaxies Not Barred?

Science.gov (United States)

Saha, Kanak; Elmegreen, Bruce

2018-05-01

Although more than two-thirds of star-forming disk galaxies in the local universe are barred, some galaxies remain unbarred, occupying the upper half of the Hubble tuning fork diagram. Numerical simulations almost always produce bars spontaneously, so it remains a challenge to understand how galaxies sometimes prevent bars from forming. Using a set of collisionless simulations, we first reproduce the common result that cold stellar disks surrounding a classical bulge become strongly unstable to non-axisymmetric perturbations, leading to the rapid formation of spiral structure and bars. However, our analyses show that galaxy models with compact classical bulges (whose average density is greater than or comparable to the disk density calculated within bulge half-mass radii) are able to prevent bar formation for at least 4 Gyr even when the stellar disk is maximal and having low Toomre Q. Such bar prevention is the result of several factors such as (a) a small inner Lindblad resonance with a high angular rate, which contaminates an incipient bar with x 2 orbits, and (b) rapid loss of angular momentum accompanied by a rapid heating in the center from initially strong bar and spiral instabilities in a low-Q disk; in other words, a rapid initial rise to a value larger than ∼5 of the ratio of the random energy to the rotational energy in the central region of the galaxy.

The role of the STIR sequence in magnetic resonance imaging examination of bone tumours

International Nuclear Information System (INIS)

Golfieri, R.; Baddeley, H.; Pringle, J.S.; Souhami, R.

1990-01-01

Sixty patients with primary bone tumours were evaluated with magnetic resonance imaging (MRI) at 0.5 T with both conventional spin-echo (SE) and short inversion time inversion recovery (STIR) sequences. The STIR sequence with T 1 of 120-130 ms in all cases suppressed the high signal from fatty bone marrow, giving a clear depiction of tumour extent, in both its intramedullary and soft-tissue components, and is superior to conventional SE images. The high sensitivity (100% of our cases) of this technique is counterbalanced by its lack of specificity: on STIR sequences both tumour and peritumorous oedema give an increase of signal intensity, limiting assessment of tumour extent. Peritumoral oedema, only present in this series in malignant neoplasms, may however be differentiated on the basis of the configuration of the abnormal areas, and by comparing STIR images with short repetition time/echo time sequence results. (author)

Anodising and corrosion resistance of AA 7050 friction stir welds

International Nuclear Information System (INIS)

Atz Dick, Pedro; Knörnschild, Gerhard H.; Dick, Luís F.P.

2017-01-01

Highlights: • Sulphuric Anodizing films of AA7050 friction stir welds are 25% thinner on the nugget zone. • Semicoherent MgZn_2 precipitates locally pin the formation of anodic oxide film. • Coarse Al_7Cu_2Fe precipitates anodize irregularly and produces locally thicker films. • Localized corrosion occurs preferentially on the nugget zone and is related to the thinner oxide film and irregular anodizing on stirring voids. - Abstract: The influence of friction stir welding on the sulphuric anodising and corrosion of AA7050 was studied in 0.1 M NaCl by the scanning vibrating electrode technique under simultaneous polarization. The oxide films obtained were characterized by scanning electron microscopy. The porous oxide films are up to 25% thicker on the thermomechanically and heat affected zones and 25% thinner on the nugget. This thinner defective oxide film explains the lower pitting resistance of the nugget zone. Individual pit current transients were indirectly determined from current maps. However, the calculated values are lower than expected, due to underestimation of electrolyte conductivity near pits.

Friction Stir Welding (FSW) of Aged CuCrZr Alloy Plates

Science.gov (United States)

Jha, Kaushal; Kumar, Santosh; Nachiket, K.; Bhanumurthy, K.; Dey, G. K.

2018-01-01

Friction Stir Welding (FSW) of Cu-0.80Cr-0.10Zr (in wt pct) alloy under aged condition was performed to study the effects of process parameters on microstructure and properties of the joint. FSW was performed over a wide range of process parameters, like tool-rotation speed (from 800 to 1200 rpm) and tool-travel speed (from 40 to 100 mm/min), and the resulting thermal cycles were recorded on both sides (advancing and retreating) of the joint. The joints were characterized for their microstructure and tensile properties. The welding process resulted in a sound and defect-free weld joint, over the entire range of the process parameters used in this study. Microstructure of the stir zone showed fine and equiaxed grains, the scale of which varied with FSW process parameters. Grain size in the stir zone showed direct correlation with tool rotation and inverse correlation with tool-travel speed. Tensile strength of the weld joints was ranging from 225 to 260 MPa, which is substantially lower than that of the parent metal under aged condition ( 400 MPa), but superior to that of the parent material under annealed condition ( 220 MPa). Lower strength of the FSW joint than that of the parent material under aged condition can be attributed to dissolution of the precipitates in the stir zone and TMAZ. These results are presented and discussed in this paper.

Preparation of a Breadfruit Flour Bar.

Science.gov (United States)

Nochera, Carmen L; Ragone, Diane

2016-05-20

Breadfruit is a nutritious, high energy food with a low quantity of protein but excellent protein quality. It has the potential to be developed into desired products which will help increase its utilization and add value to the crop. The overall purposes of this investigation were to develop a portable, nutritious, ready-to-eat breadfruit product (bar), test the sensory qualities of the product, and evaluate the nutritional properties of the product. Flour made from the Micronesian variety, Meinpadahk ( Artocarpus altilis × Artocarpus mariannensis ), was utilized for the development of the breadfruit bar. Breadfruit is a rich source of fiber, vitamins such as vitamin C, minerals such as potassium, and phytochemicals such as flavonoids. Nutritional labeling indicates that the breadfruit bar is high in carbohydrates and low in fat, and sensory evaluation indicates that 81% of the panelists found the bar acceptable while 19% disliked the bar. The breadfruit bar can provide an appealing and inexpensive gluten-free food source based on locally available breadfruit.

Effect of process parameters on mechanical properties of friction stir spot welded magnesium to aluminum alloys

International Nuclear Information System (INIS)

Rao, H.M.; Yuan, W.; Badarinarayan, H.

2015-01-01

Highlights: • Lap-shear failure load of ∼2.5 kN was achieved in dissimilar Mg to Al spot welds. • Failure load depends on both welding geometrical features and IMCs formation. • Thin and discontinuous IMCs formed in stir zone are beneficial for weld strength. • Low heat input and good material mixing/interlocking is essential for high strength. - Abstract: Friction stir spot welding was applied to dissimilar cast magnesium (Mg) alloy AM60B and wrought aluminum (Al) alloy 6022-T4 under various welding conditions. The influence of tool rotation rate and shoulder plunge depth on lap-shear failure load was examined. Welds were made at four different tool rotation rates of 1000, 1500, 2000 and 2500 revolution per minute (rpm) and various tool shoulder plunge depths from 0 mm to 0.9 mm. The cross section of each weld exhibited the formation of intermetallic compounds (IMCs) in the stir zone. An increase in tool rotation rate decreased the width of the stir zone and resulted in lower lap-shear failure loads. The stir zone width increased and interlocking of IMCs was observed with an increase in tool shoulder plunge depth at 1000 rpm. High lap-shear failure loads were achieved in welds having a large stir zone width with formation of discontinuous IMCs at the tip of the interfacial hook. An average lap-shear failure load of 2.5 kN was achieved for welds made at 1000 rpm and 0.9 mm shoulder plunge. The present study suggests that the mechanical properties of friction stir spot welded dissimilar alloys are greatly influenced by the stir zone width, interfacial hooks and IMCs which are all weld process dependent

21 CFR 886.1650 - Ophthalmic bar prism.

Science.gov (United States)

2010-04-01

... 21 Food and Drugs 8 2010-04-01 2010-04-01 false Ophthalmic bar prism. 886.1650 Section 886.1650...) MEDICAL DEVICES OPHTHALMIC DEVICES Diagnostic Devices § 886.1650 Ophthalmic bar prism. (a) Identification. An ophthalmic bar prism is a device that is a bar composed of fused prisms of gradually increasing...

Some microstructural characterisations in a friction stir welded oxide dispersion strengthened ferritic steel alloy

International Nuclear Information System (INIS)

Legendre, F.; Poissonnet, S.; Bonnaillie, P.; Boulanger, L.; Forest, L.

2009-01-01

The goal of this study is to characterize microstructure of a friction stir welded oxide dispersion strengthened alloy. The welded material is constituted by two sheets of an yttria-dispersion-strengthened PM 2000 ferritic steel. Different areas of the friction stir welded product were analyzed using field emission gun secondary electron microscopy (FEG-SEM) and electron microprobe whereas nanoindentation was used to evaluate mechanical properties. The observed microstructural evolution, including distribution of the yttria dispersoids, after friction stir welding process is discussed and a correlation between the microstructure and the results of nanoindentation tests is established.

Bar code instrumentation for nuclear safeguards

International Nuclear Information System (INIS)

Bieber, A.M. Jr.

1984-01-01

This paper presents a brief overview of the basic principles of bar codes and the equipment used to make and to read bar code labels, and a summary of some of the more important factors that need to be considered in integrating bar codes into an information system

49 CFR 236.705 - Bar, locking.

Science.gov (United States)

2010-10-01

... 49 Transportation 4 2010-10-01 2010-10-01 false Bar, locking. 236.705 Section 236.705..., MAINTENANCE, AND REPAIR OF SIGNAL AND TRAIN CONTROL SYSTEMS, DEVICES, AND APPLIANCES Definitions § 236.705 Bar, locking. A bar in an interlocking machine to which the locking dogs are attached. ...

Ionic liquid solvent bar micro-extraction of CdCln(n-2)- species for ultra-trace Cd determination in seawater.

Science.gov (United States)

Herce-Sesa, Belén; López-López, José A; Moreno, Carlos

2018-02-01

Water analysis of trace metals has been benefited by recent studies on sample preparation by liquid micro-extraction. However, there are still limitations for its application to seawater, such as the need of additives to preserve the sample or the availability of chemical extractants for the selective extraction from highly saline samples. In this work, a three phase solvent bar micro-extraction (3SBME) system containing the ionic liquid trioctylmethylammonium chloride (Aliquat ® 336) has been used for isolation and pre-concentration of Cd from seawater samples, due to its ability for ionic exchange of CdCl n (n-2)- . The system was optimized to work at the natural pH of seawater, and conditions for application to real samples were 0.18 M Aliquat ® 336 dissolved in kerosene with 0.25 M dodecan-1-ol as organic solution, 1.5 M HNO 3 as acceptor solution, 60 min extraction time, and 800 rpm stirring speed in the sample. Loss of organic solution into the sample during extraction was evaluated and revealed its dependence on stirring rate and extraction time. Under optimum conditions samples containing Cd 0.09-0.90 nM were pre-concentrated 65 times. GF-AAS was used for metal quantification with a limit of detection of 0.04 nM. Accuracy was successfully evaluated measuring Cd in a seawater certified reference material BCR-403. Copyright © 2017 Elsevier Ltd. All rights reserved.

Near Net Manufacturing Using Thin Gage Friction Stir Welding

Science.gov (United States)

Takeshita, Jennifer; Potter, David; Holquin, Michael

2006-01-01

Friction Stir Welding (FSW) and near net spin forming of FSW aluminumn blanks were investigated for large-scale pressure vessel applications. With a specific focus on very thin gage 2xxx and 7xxx aluminum alloys, the program concentrated on the following: the criteria used for material selection, a potential manufacturing flow, and the effectiveness and associated risks of near net spin forming. Discussion will include the mechanical properties of the friction stir welds and the parent material from before and after the spin forming process. This effort was performed under a NASA Space Exploration initiative focused on increasing the affordability, reliability and performance of pressure vessels larger than 10 ft. diameter.

Overview of Computational Fluid Dynamics (CFD) simulation of stirred vessel

International Nuclear Information System (INIS)

Mohd Rizal Mamat; Azraf Azman; Anwar Abdul Rahman; Noraishah Othman

2010-01-01

Stirred vessel is one of many widely used equipment in industrial process and chemical industry. The design of stirred vessel typically follows a certain standard chemical engineering practice that may also involve empirical data acquired from experiments. However the design may still take a different route which is computational engineering simulation and analysis. CFD has been identified as one of the possible tools for such purposes. CFD enables the flow fields variables such as velocity, temperature and pressure in the whole computational domain to be obtained and as such it presents an advantage over the experimental setup. (author)

A Survey on Friction Stir Welding Of Dissimilar Magnesium Alloys

Science.gov (United States)

Unnikrishnan, M. A.; Raja, Dhas. J. Edwin

2017-10-01

There is a consistent demand for superior materials in every industry. The areas on demand are automobile and aerospace sectors in major.. The most commonly used material in these fields is Aluminium.Though it possess all the properties up to some extent constant demand is pushing for alternate materials. Dissimilar alloys have been a relatively new approach towards these fields.. Friction stir welding dissimilar alloys is a big leap in Automobile sector. In this paper a detailed review of Friction stir welding of Dissimilar Magnesium alloys has been done. This work will serve as a reference to subsequent researchers.

First observations of $\\bar{B}_s^0\\to D^+D^-$, $D_s^+D^-$ and $D^0\\bar{D}^0$ decays

CERN Document Server

Aaij, R; Adeva, B; Adinolfi, M; Adrover, C; Affolder, A; Ajaltouni, Z; Albrecht, J; Alessio, F; Alexander, M; Ali, S; Alkhazov, G; Alvarez Cartelle, P; Alves Jr, A A; Amato, S; Amerio, S; Amhis, Y; Anderlini, L; Anderson, J; Andreassen, R; Appleby, R B; Aquines Gutierrez, O; Archilli, F; Artamonov, A; Artuso, M; Aslanides, E; Auriemma, G; Bachmann, S; Back, J J; Baesso, C; Balagura, V; Baldini, W; Barlow, R J; Barschel, C; Barsuk, S; Barter, W; Bauer, Th; Bay, A; Beddow, J; Bedeschi, F; Bediaga, I; Belogurov, S; Belous, K; Belyaev, I; Ben-Haim, E; Benayoun, M; Bencivenni, G; Benson, S; Benton, J; Berezhnoy, A; Bernet, R; Bettler, M -O; van Beuzekom, M; Bien, A; Bifani, S; Bird, T; Bizzeti, A; Bjørnstad, P M; Blake, T; Blanc, F; Blouw, J; Blusk, S; Bocci, V; Bondar, A; Bondar, N; Bonivento, W; Borghi, S; Borgia, A; Bowcock, T J V; Bowen, E; Bozzi, C; Brambach, T; van den Brand, J; Bressieux, J; Brett, D; Britsch, M; Britton, T; Brook, N H; Brown, H; Burducea, I; Bursche, A; Busetto, G; Buytaert, J; Cadeddu, S; Callot, O; Calvi, M; Calvo Gomez, M; Camboni, A; Campana, P; Carbone, A; Carboni, G; Cardinale, R; Cardini, A; Carranza-Mejia, H; Carson, L; Carvalho Akiba, K; Casse, G; Cattaneo, M; Cauet, Ch; Charles, M; Charpentier, Ph; Chen, P; Chiapolini, N; Chrzaszcz, M; Ciba, K; Cid Vidal, X; Ciezarek, G; Clarke, P E L; Clemencic, M; Cliff, H V; Closier, J; Coca, C; Coco, V; Cogan, J; Cogneras, E; Collins, P; Comerma-Montells, A; Contu, A; Cook, A; Coombes, M; Coquereau, S; Corti, G; Couturier, B; Cowan, G A; Craik, D; Cunliffe, S; Currie, R; D'Ambrosio, C; David, P; David, P N Y; De Bonis, I; De Bruyn, K; De Capua, S; De Cian, M; De Miranda, J M; De Oyanguren Campos, M; De Paula, L; De Silva, W; De Simone, P; Decamp, D; Deckenhoff, M; Del Buono, L; Derkach, D; Deschamps, O; Dettori, F; Di Canto, A; Dijkstra, H; Dogaru, M; Donleavy, S; Dordei, F; Dosil Suárez, A; Dossett, D; Dovbnya, A; Dupertuis, F; Dzhelyadin, R; Dziurda, A; Dzyuba, A; Easo, S; Egede, U; Egorychev, V; Eidelman, S; van Eijk, D; Eisenhardt, S; Eitschberger, U; Ekelhof, R; Eklund, L; El Rifai, I; Elsasser, Ch; Elsby, D; Falabella, A; Färber, C; Fardell, G; Farinelli, C; Farry, S; Fave, V; Ferguson, D; Fernandez Albor, V; Ferreira Rodrigues, F; Ferro-Luzzi, M; Filippov, S; Fitzpatrick, C; Fontana, M; Fontanelli, F; Forty, R; Francisco, O; Frank, M; Frei, C; Frosini, M; Furcas, S; Furfaro, E; Gallas Torreira, A; Galli, D; Gandelman, M; Gandini, P; Gao, Y; Garofoli, J; Garosi, P; Garra Tico, J; Garrido, L; Gaspar, C; Gauld, R; Gersabeck, E; Gersabeck, M; Gershon, T; Ghez, Ph; Gibson, V; Gligorov, V V; Göbel, C; Golubkov, D; Golutvin, A; Gomes, A; Gordon, H; Grabalosa Gándara, M; Graciani Diaz, R; Granado Cardoso, L A; Graugés, E; Graziani, G; Grecu, A; Greening, E; Gregson, S; Grünberg, O; Gui, B; Gushchin, E; Guz, Yu; Gys, T; Hadjivasiliou, C; Haefeli, G; Haen, C; Haines, S C; Hall, S; Hampson, T; Hansmann-Menzemer, S; Harnew, N; Harnew, S T; Harrison, J; Hartmann, T; He, J; Heijne, V; Hennessy, K; Henrard, P; Hernando Morata, J A; van Herwijnen, E; Hicks, E; Hill, D; Hoballah, M; Hombach, C; Hopchev, P; Hulsbergen, W; Hunt, P; Huse, T; Hussain, N; Hutchcroft, D; Hynds, D; Iakovenko, V; Idzik, M; Ilten, P; Jacobsson, R; Jaeger, A; Jans, E; Jaton, P; Jing, F; John, M; Johnson, D; Jones, C R; Jost, B; Kaballo, M; Kandybei, S; Karacson, M; Karbach, T M; Kenyon, I R; Kerzel, U; Ketel, T; Keune, A; Khanji, B; Kochebina, O; Komarov, I; Koopman, R F; Koppenburg, P; Korolev, M; Kozlinskiy, A; Kravchuk, L; Kreplin, K; Kreps, M; Krocker, G; Krokovny, P; Kruse, F; Kucharczyk, M; Kudryavtsev, V; Kvaratskheliya, T; La Thi, V N; Lacarrere, D; Lafferty, G; Lai, A; Lambert, D; Lambert, R W; Lanciotti, E; Lanfranchi, G; Langenbruch, C; Latham, T; Lazzeroni, C; Le Gac, R; van Leerdam, J; Lees, J -P; Lefèvre, R; Leflat, A; Lefrançois, J; Leo, S; Leroy, O; Leverington, B; Li, Y; Li Gioi, L; Liles, M; Lindner, R; Linn, C; Liu, B; Liu, G; von Loeben, J; Lohn, S; Lopes, J H; Lopez Asamar, E; Lopez-March, N; Lu, H; Lucchesi, D; Luisier, J; Luo, H; Machefert, F; Machikhiliyan, I V; Maciuc, F; Maev, O; Malde, S; Manca, G; Mancinelli, G; Marconi, U; Märki, R; Marks, J; Martellotti, G; Martens, A; Martin, L; Martín Sánchez, A; Martinelli, M; Martinez Santos, D; Martins Tostes, D; Massafferri, A; Matev, R; Mathe, Z; Matteuzzi, C; Maurice, E; Mazurov, A; McCarthy, J; McNulty, R; Mcnab, A; Meadows, B; Meier, F; Meissner, M; Merk, M; Milanes, D A; Minard, M -N; Molina Rodriguez, J; Monteil, S; Moran, D; Morawski, P; Morello, M J; Mountain, R; Mous, I; Muheim, F; Müller, K; Muresan, R; Muryn, B; Muster, B; Naik, P; Nakada, T; Nandakumar, R; Nasteva, I; Needham, M; Neufeld, N; Nguyen, A D; Nguyen, T D; Nguyen-Mau, C; Nicol, M; Niess, V; Niet, R; Nikitin, N; Nikodem, T; Nomerotski, A; Novoselov, A; Oblakowska-Mucha, A; Obraztsov, V; Oggero, S; Ogilvy, S; Okhrimenko, O; Oldeman, R; Orlandea, M; Otalora Goicochea, J M; Owen, P; Pal, B K; Palano, A; Palutan, M; Panman, J; Papanestis, A; Pappagallo, M; Parkes, C; Parkinson, C J; Passaleva, G; Patel, G D; Patel, M; Patrick, G N; Patrignani, C; Pavel-Nicorescu, C; Pazos Alvarez, A; Pellegrino, A; Penso, G; Pepe Altarelli, M; Perazzini, S; Perego, D L; Perez Trigo, E; Pérez-Calero Yzquierdo, A; Perret, P; Perrin-Terrin, M; Pessina, G; Petridis, K; Petrolini, A; Phan, A; Picatoste Olloqui, E; Pietrzyk, B; Pilař, T; Pinci, D; Playfer, S; Plo Casasus, M; Polci, F; Polok, G; Poluektov, A; Polycarpo, E; Popov, D; Popovici, B; Potterat, C; Powell, A; Prisciandaro, J; Pugatch, V; Puig Navarro, A; Punzi, G; Qian, W; Rademacker, J H; Rakotomiaramanana, B; Rangel, M S; Raniuk, I; Rauschmayr, N; Raven, G; Redford, S; Reid, M M; dos Reis, A C; Ricciardi, S; Richards, A; Rinnert, K; Rives Molina, V; Roa Romero, D A; Robbe, P; Rodrigues, E; Rodriguez Perez, P; Roiser, S; Romanovsky, V; Romero Vidal, A; Rouvinet, J; Ruf, T; Ruffini, F; Ruiz, H; Ruiz Valls, P; Sabatino, G; Saborido Silva, J J; Sagidova, N; Sail, P; Saitta, B; Salzmann, C; Sanmartin Sedes, B; Sannino, M; Santacesaria, R; Santamarina Rios, C; Santovetti, E; Sapunov, M; Sarti, A; Satriano, C; Satta, A; Savrie, M; Savrina, D; Schaack, P; Schiller, M; Schindler, H; Schlupp, M; Schmelling, M; Schmidt, B; Schneider, O; Schopper, A; Schune, M -H; Schwemmer, R; Sciascia, B; Sciubba, A; Seco, M; Semennikov, A; Senderowska, K; Sepp, I; Serra, N; Serrano, J; Seyfert, P; Shapkin, M; Shapoval, I; Shatalov, P; Shcheglov, Y; Shears, T; Shekhtman, L; Shevchenko, O; Shevchenko, V; Shires, A; Silva Coutinho, R; Skwarnicki, T; Smith, N A; Smith, E; Smith, M; Sokoloff, M D; Soler, F J P; Soomro, F; Souza, D; Souza De Paula, B; Spaan, B; Sparkes, A; Spradlin, P; Stagni, F; Stahl, S; Steinkamp, O; Stoica, S; Stone, S; Storaci, B; Straticiuc, M; Straumann, U; Subbiah, V K; Swientek, S; Syropoulos, V; Szczekowski, M; Szczypka, P; Szumlak, T; T'Jampens, S; Teklishyn, M; Teodorescu, E; Teubert, F; Thomas, C; Thomas, E; van Tilburg, J; Tisserand, V; Tobin, M; Tolk, S; Tonelli, D; Topp-Joergensen, S; Torr, N; Tournefier, E; Tourneur, S; Tran, M T; Tresch, M; Tsaregorodtsev, A; Tsopelas, P; Tuning, N; Ubeda Garcia, M; Ukleja, A; Urner, D; Uwer, U; Vagnoni, V; Valenti, G; Vazquez Gomez, R; Vazquez Regueiro, P; Vecchi, S; Velthuis, J J; Veltri, M; Veneziano, G; Vesterinen, M; Viaud, B; Vieira, D; Vilasis-Cardona, X; Vollhardt, A; Volyanskyy, D; Voong, D; Vorobyev, A; Vorobyev, V; Voß, C; Voss, H; Waldi, R; Wallace, R; Wandernoth, S; Wang, J; Ward, D R; Watson, N K; Webber, A D; Websdale, D; Whitehead, M; Wicht, J; Wiechczynski, J; Wiedner, D; Wiggers, L; Wilkinson, G; Williams, M P; Williams, M; Wilson, F F; Wishahi, J; Witek, M; Wotton, S A; Wright, S; Wu, S; Wyllie, K; Xie, Y; Xing, F; Xing, Z; Yang, Z; Young, R; Yuan, X; Yushchenko, O; Zangoli, M; Zavertyaev, M; Zhang, F; Zhang, L; Zhang, W C; Zhang, Y; Zhelezov, A; Zhokhov, A; Zhong, L; Zvyagin, A

2013-01-01

First observations and measurements of the branching fractions of the $\\bar{B}_s^0\\to D^+D^-$, $\\bar{B}_s^0\\to D_s^+D^-$ and $\\bar{B}_s^0\\to D^0\\bar{D}^0$ decays are presented using $1.0$~fb$^{-1}$ of data collected by the LHCb experiment. These branching fractions are normalized to those of $\\bar{B}^0\\to D^+D^-$, $B^0\\to D_s^+D^-$ and $B^-\\to D^0D_s^-$, respectively. An excess of events consistent with the decay $\\bar{B}^0\\to D^0\\bar{D}^0$ is also seen, and its branching fraction is measured relative to that of $B^-\\to D^0D_s^-$. Improved measurements of the branching fractions ${\\cal{B}}(\\bar{B}_s^0\\to D_s^+D_s^-)$ and ${\\cal{B}}(B^-\\to D^0D_s^-)$ are reported, each relative to ${\\cal{B}}(B^0\\to D_s^+D^-)$. The ratios of branching fractions are \\begin{align*} {{\\cal{B}}(\\bar{B}_s^0\\to D^+D^-)\\over {\\cal{B}}(\\bar{B}^0\\to D^+D^-)} &= 1.08\\pm 0.20\\pm0.10, \

MR analysis of sternal bone marrow using STIR in hematologic diseases

Energy Technology Data Exchange (ETDEWEB)

Kozawa, Eito [Saitama Medical School, Moroyama (Japan)

1998-12-01

The magnetic resonance (MR) signal intensity pattern of sternal bone marrow was examined in 21 normal volunteers and 10 patients with aplastic anemia (n=4), multiple myeloma (2), AML (2), gammaglobulinemia (1) and MDS (1) using a sagittal STIR sequence. Double Echo STIR images (TR/TI/TE/NEX=2000/180/20, 100/1) were obtained with a CP body array coil. Craniocaudal phase-encoding with a handmade positioning device effectively avoided overlapping artifacts due to cardiac pulsation. In the normal volunteers, age showed a significant inverse correlation with the calculated SIR (signal intensity ratio of bone marrow relative to subcutaneous fat) using STIR with short TE. The SIR in the sternal body was significantly higher than that in the manubrium (p<0.05). Knowledge of the sternal bone marrow distribution according to age is useful for evaluating hematologic diseases. The proposed method provided high spatial resolution and an excellent bone marrow signal, and may be useful for determining site for aspiration. (author)

Search for the Standard Model Higgs Boson in ZH → v$\\bar{v}$b$\\bar{b}$ channel in p$\\bar{p}$ collisions at √s= 1.96 TeV

Energy Technology Data Exchange (ETDEWEB)

Dubey, Abhinav [Univ. of Delhi, New Delhi (India)

2011-01-01

A search for the standard model Higgs boson is performed in 5.2 fb^-1 of p$\\bar{p}$ collisions at p √s = 1.96 TeV, collected with the DØ detector at the Fermilab Tevatron. The final state considered is a pair of b jets with large missing transverse energy, as expected from p$\\bar{p}$→ ZH → v$\\bar{v}$b$\\bar{b}$ production. The search is also sensitive to the WH → ℓvb$\\bar{b}$ channel, where the charged lepton is not identified. Boosted decision trees are used to discriminate signal from background. Good agreement is observed between data and expected backgrounds, and, for a Higgs-boson mass of 115 GeV, a limit is set at 95% C.L. on the cross section multiplied by branching fraction of (p$\\bar{p}$ → (Z/W)H) × (H → b$\\bar{b}$) that is a factor 4.57 expected and 3.73 observed larger than the value expected from the standard model.

Unit-bar migration and bar-trough deposition: impacts on hydraulic conductivity and grain size heterogeneity in a sandy streambed

Science.gov (United States)

Korus, Jesse T.; Gilmore, Troy E.; Waszgis, Michele M.; Mittelstet, Aaron R.

2018-03-01

The hydrologic function of riverbeds is greatly dependent upon the spatiotemporal distribution of hydraulic conductivity and grain size. Vertical hydraulic conductivity ( K v) is highly variable in space and time, and controls the rate of stream-aquifer interaction. Links between sedimentary processes, deposits, and K v heterogeneity have not been well established from field studies. Unit bars are building blocks of fluvial deposits and are key to understanding controls on heterogeneity. This study links unit bar migration to K v and grain size variability in a sand-dominated, low-sinuosity stream in Nebraska (USA) during a single 10-day hydrologic event. An incipient bar formed parallel to the thalweg and was highly permeable and homogenous. During high flow, this bar was submerged under 10-20 cm of water and migrated 100 m downstream and toward the channel margin, where it became markedly heterogeneous. Low- K v zones formed in the subsequent heterogeneous bar downstream of the original 15-40-cm-thick bar front and past abandoned bridge pilings. These low- K v zones correspond to a discontinuous 1-cm layer of fine sand and silt deposited in the bar trough. Findings show that K v heterogeneity relates chiefly to the deposition of suspended materials in low-velocity zones downstream of the bar and obstructions, and to their subsequent burial by migration of the bar during high flow. Deposition of the unit bar itself, although it emplaced the vast majority of the sediment volume, was secondary to bar-trough deposition as a control on the overall pattern of heterogeneity.

A Review of Permanent Magnet Stirring During Metal Solidification

Science.gov (United States)

Zeng, Jie; Chen, Weiqing; Yang, Yindong; Mclean, Alexander

2017-12-01

Rather than using conventional electromagnetic stirring (EMS) with three-phase alternating current, permanent magnet stirring (PMS), based on the use of sintered NdFeB material which has excellent magnetic characteristics, can be employed to generate a magnetic field for the stirring of liquid metal during solidification. Recent experience with steel casting indicates that PMS requires less than 20 pct of the total energy compared with EMS. Despite the excellent magnetic density properties and low power consumption, this relatively new technology has received comparatively little attention by the metal casting community. This paper reviews simulation modeling, experimental studies, and industrial trials of PMS conducted during recent years. With the development of magnetic simulation software, the magnetic field and associated flow patterns generated by PMS have been evaluated. Based on the results obtained from laboratory experiments, the effects of PMS on metal solidification structures and typical defects such as surface pinholes and center cavities are summarized. The significance of findings obtained from trials of PMS within the metals processing sector, including the continuous casting of steel, are discussed with the aim of providing an overview of the relevant parameters that are of importance for further development and industrial application of this innovative technology.

The improvement of ultrasonic characteristics in weld metal of austenitic stainless steel using magnetic stirring method

International Nuclear Information System (INIS)

Arakawa, T.; Tomisawa, Y.

1988-01-01

The magnetic stirring welding process was tested to save the difficulty of ultrasonic testing of austenitic stainless steel overlayed welds, due to grain refinement of weld solidification structure. The testing involved stirring the molten pool with Lorenz force induced by the interaction of welding current and alternative magnetic field applied from the outside magnetic coil. This report summarizes improvement of ultrasonic characteristic in austenitic stainless steel overlayed welds caused by magnetic stirring welding process

(Ln-bar, g)-spaces. General relativity over V4-bar - spaces

International Nuclear Information System (INIS)

Manoff, S.; Kolarov, A.; Dimitrov, B.

1998-01-01

The results from the considerations of differentiable manifolds with contravariant and covariant affine connections and metrics are specialized for the case of (L n bar, g)-spaces with metric transport (∇ ξ g = 0 for all ξ is T (M), g ij;k = 0 and f j i = e φ · g j i (the s.c. (pseudo)Riemannian spaces with contravariant and covariant symmetric affine connections). Einstein's theory of gravitation is considered in (pseudo)Riemannian spaces with different (not only by sign) contravariant and covariant affine connections ((V n bar)-spaces, n = 4). The Euler-Lagrange equations and the corresponding energy-momentum tensors (EMT-s) are obtained and compared with the Einstein equations and the EMT-s in V 4 -spaces. The geodesic and autoparallel equations in V 4 bar -spaces are found as different equations in contrast to the case of V 4 -spaces

Antihydrogen Production in $ \\bar{p} $ Z - interaction

CERN Multimedia

2002-01-01

% PS210 \\\\ \\\\ The production of the antihydrogen atom $ \\bar {H}^0 \\equiv \\bar{p}e $ as the simplest atomic bound state of antimatter has been studied. Nine $ \\bar {H}^0 $ have been observed.\\\\ \\\\ The production of $ \\bar {H}^0 $ is predominantly mediated by the two-photon mechanism in the antiproton-nucleus interaction. In principle $ \\bar {H}^0 $ is well suited for investigations of fundamental CPT violation studies under different forces, however, in the present experiment we concentrated on the production of this antimatter object, since so far it never had been observed.

Feasibility and acceptability of a bar-based sexual risk reduction intervention for bar patrons in Tshwane, South Africa.

Science.gov (United States)

Morojele, Neo K; Kitleli, Naledi; Ngako, Kgalabi; Kekwaletswe, Connie T; Nkosi, Sebenzile; Fritz, Katherine; Parry, Charles D H

2014-01-01

Alcohol consumption is a recognised risk factor for HIV infection. Alcohol serving establishments have been identified as appropriate venues in which to deliver HIV prevention interventions. This paper describes experiences and lessons learnt from implementing a combined HIV prevention intervention in bar settings in one city- and one township-based bar in Tshwane, South Africa. The intervention consisted of peer-led and brief intervention counselling sub-components. Thirty-nine bar patrons were recruited and trained, and delivered HIV and alcohol risk reduction activities to their peers as peer interventionists. At the same time, nine counsellors received training and visited the bars weekly to provide brief motivational interviewing counselling, advice, and referrals to the patrons of the bars. A responsible server sub-component that had also been planned was not delivered as it was not feasible to train the staff in the two participating bars. Over the eight-month period the counsellors were approached by and provided advice and counselling for alcohol and sexual risk-related problems to 111 bar patrons. The peer interventionists reported 1323 risk reduction interactions with their fellow bar patrons during the same period. The intervention was overall well received and suggests that bar patrons and servers can accept a myriad of intervention activities to reduce sexual risk behaviour within their drinking settings. However, HIV- and AIDS-related stigma hindered participation in certain intervention activities in some instances. The buy-in that we received from the relevant stakeholders (i.e. bar owners/managers and patrons, and the community at large) was an important contributor to the feasibility and acceptability of the intervention.

Orbits in weak and strong bars

CERN Document Server

Contopoulos, George

1980-01-01

The authors study the plane orbits in simple bar models embedded in an axisymmetric background when the bar density is about 1% (weak), 10% (intermediate) or 100% (strong bar) of the axisymmetric density. Most orbits follow the stable periodic orbits. The basic families of periodic orbits are described. In weak bars with two Inner Lindblad Resonances there is a family of stable orbits extending from the center up to the Outer Lindblad Resonance. This family contains the long period orbits near corotation. Other stable families appear between the Inner Lindblad Resonances, outside the Outer Lindblad Resonance, around corotation (short period orbits) and around the center (retrograde). Some families become unstable or disappear in strong bars. A comparison is made with cases having one or no Inner Lindblad Resonance. (12 refs).

High strain rate superplasticity in a friction stir processed 7075 Al alloy

Energy Technology Data Exchange (ETDEWEB)

Mishra, R.S.; Mahoney, M.W.; McFaden, S.X.; Mara, N.A.; Mukherjee, A.K.

1999-12-31

In this paper, the authors report the first results using friction stir processing (FSP). In the last ten years, a new technique of Friction Stir Welding (FSW) has emerged as an exciting solid state joining technique for aluminum alloys. This technique, developed by The Welding Institute (TWI), involves traversing a rotating tool that produces intense plastic deformation through a stirring action. The localized heating is produced by friction between the tool shoulder and the sheet top surface, as well as plastic deformation of the material in contact with the tool. This results in a stirred zone with a very fine grain size in a single pass. Mahoney et al. observed a grain size of 3 {micro}m in a 7075 Al alloy. This process can be easily adopted as a processing technique to obtain fine grain size. FSP of a commercial 7075 Al alloy resulted in significant enhancement of superplastic properties. The optimum superplastic strain rate was 10{sup {minus}2}s{sup {minus}1} at 490 C in the FSP 7075 Al alloy, an improvement of more than an order of magnitude in strain rate. The present results suggest an exciting possibility to use a simple FSP technique to enhance grain size dependent properties.

Microstructure-based modeling of tensile deformation of a friction stir welded AZ31 Mg alloy

Energy Technology Data Exchange (ETDEWEB)

He, Weijun, E-mail: weijun.he@cqu.edu.cn [College of Materials Science and Engineering, Chongqing University, Chongqing 400044 (China); Zheng, Li [College of Materials Science and Engineering, Shenyang University of Technology, Shenyang 110870 (China); Xin, Renlong, E-mail: rlxin@cqu.edu.cn [College of Materials Science and Engineering, Chongqing University, Chongqing 400044 (China); Liu, Qing [College of Materials Science and Engineering, Chongqing University, Chongqing 400044 (China)

2017-02-27

The deformation and fracture behaviors of friction stir welded (FSWed) Mg alloys are topics under investigation. The microstructure and texture of a FSWed Mg alloy were characterized by electron back scattered diffraction. Four characteristic sub-zones with different orientations in the FSWed Mg alloy joint were identified. The texture distribution across the stir zones and transition zone were obviously inhomogeneous. For comparison, four sub-regions in the base material were also characterized. Based on the experimental microstructure and texture, a crystal plasticity finite element model was developed to represent the friction stir welded Mg alloy. Simulations were carried out to study the effect of texture variation on the deformation behaviors during transverse tension. Compared with the base material case, strong macroscopic strain localization was observed for the FSWed joint case after transverse tension. Strain localization may have contributed to the decayed elongation of the FSWed joint in the transverse tension. Texture variation in the thermal-mechanical affected zone did not change the deformation mechanism in the stir zones, while it did decrease the strain localization, thus assuming to improve the elongation of the friction stir welded Mg alloy.

Microstructure-based modeling of tensile deformation of a friction stir welded AZ31 Mg alloy

International Nuclear Information System (INIS)

He, Weijun; Zheng, Li; Xin, Renlong; Liu, Qing

2017-01-01

The deformation and fracture behaviors of friction stir welded (FSWed) Mg alloys are topics under investigation. The microstructure and texture of a FSWed Mg alloy were characterized by electron back scattered diffraction. Four characteristic sub-zones with different orientations in the FSWed Mg alloy joint were identified. The texture distribution across the stir zones and transition zone were obviously inhomogeneous. For comparison, four sub-regions in the base material were also characterized. Based on the experimental microstructure and texture, a crystal plasticity finite element model was developed to represent the friction stir welded Mg alloy. Simulations were carried out to study the effect of texture variation on the deformation behaviors during transverse tension. Compared with the base material case, strong macroscopic strain localization was observed for the FSWed joint case after transverse tension. Strain localization may have contributed to the decayed elongation of the FSWed joint in the transverse tension. Texture variation in the thermal-mechanical affected zone did not change the deformation mechanism in the stir zones, while it did decrease the strain localization, thus assuming to improve the elongation of the friction stir welded Mg alloy.

Search for $t\\bar{t}H$ production in the $H \\rightarrow b\\bar{b}$ channel

CERN Document Server

David, Claire; The ATLAS collaboration

2018-01-01

A search for the Standard Model Higgs boson produced in association with top-quark pair, $t\\bar{t}H$, and targeting the $H \\rightarrow b\\bar{b}$ decay mode is presented. The analysis uses 36.1 fb$^{-1}$ of $pp$ collision data at $\\sqrt{s}$ = 13 TeV collected with the ATLAS detector at the Large Hadron Collider in 2015 and 2016. Events must contain either one or two electrons or muons from the top-quark decays and are further categorized according to the multiplicities of jets and jets containing a b-hadron (b-jets). Two-stage multivariate techniques are used to discriminate between signal and the dominant background $t\\bar{t}$ + jets. The ratio of the measured $t\\bar{t}H$ signal cross-section to the Standard Model expectation is found to be $\\mu = 0.84^{+0.64}_{-0.61}$. A value of μ greater than 2.0 is excluded at 95% confidence level. The expected upper limit is $\\mu$ < 1.2 in the absence of a $t\\bar{t}H$ signal.

Probing weld quality monitoring in friction stir welding through characterization of signals by fractal theory

Energy Technology Data Exchange (ETDEWEB)

Das, Bipul; Bag, Swarup; Pal, Sukhomay [Indian Institute of Technology Guwahati, Assam (India)

2017-05-15

Providing solutions towards the improvisation of welding technologies is the recent trend in the Friction stir welding (FSW) process. We present a monitoring approach for ultimate tensile strength of the friction stir welded joints based on information extracted from process signals through implementing fractal theory. Higuchi and Katz algorithms were executed on current and tool rotational speed signals acquired during friction stir welding to estimate fractal dimensions. Estimated fractal dimensions when correlated with the ultimate tensile strength of the joints deliver an increasing trend with the increase in joint strength. It is observed that dynamicity of the system strengthens the weld joint, i.e., the greater the fractal dimension, the better will be the quality of the weld. Characterization of signals by fractal theory indicates that the single-valued indicator can be an alternative for effective monitoring of the friction stir welding process.

Probing weld quality monitoring in friction stir welding through characterization of signals by fractal theory

International Nuclear Information System (INIS)

Das, Bipul; Bag, Swarup; Pal, Sukhomay

2017-01-01

Providing solutions towards the improvisation of welding technologies is the recent trend in the Friction stir welding (FSW) process. We present a monitoring approach for ultimate tensile strength of the friction stir welded joints based on information extracted from process signals through implementing fractal theory. Higuchi and Katz algorithms were executed on current and tool rotational speed signals acquired during friction stir welding to estimate fractal dimensions. Estimated fractal dimensions when correlated with the ultimate tensile strength of the joints deliver an increasing trend with the increase in joint strength. It is observed that dynamicity of the system strengthens the weld joint, i.e., the greater the fractal dimension, the better will be the quality of the weld. Characterization of signals by fractal theory indicates that the single-valued indicator can be an alternative for effective monitoring of the friction stir welding process.

The value of fat-suppressed T2 or STIR sequences in distinguishing lipoma from well-differentiated liposarcoma

Energy Technology Data Exchange (ETDEWEB)

Galant, J. [Servicio de Radiodiagnostico, Hospital Universitario San Juan de Alicante, Ctra. Nacional 332 Alicante-Valencia s/n, 03550 San Juan de Alicante (Spain); Resonancia Magnetica del Sureste, Murcia (Spain); Marti-Bonmati, L. [Department of Radiology, Hospital Universitario Dr. Peset, Valencia (Spain); Saez, F. [Department of Radiology, Hospital Cruces de Baracaldo, Vizcaya (Spain); Soler, R. [Department of Radiology, Hospital Juan Canalejo, A Coruna (Spain); Alcala-Santaella, R. [Department of Traumatology, Hospital Universitario San Juan de Alicante, Ctra. Nacional 332 Alicante-Valencia s/n, 03550 San Juan de Alicante (Spain); Navarro, M. [Servicio de Radiodiagnostico, Hospital Universitario San Juan de Alicante, Ctra. Nacional 332 Alicante-Valencia s/n, 03550 San Juan de Alicante (Spain)

2003-02-01

The objective of this study was to evaluate the diagnostic value of fat-suppressed T2-weighted (FS-T2) images or short tau inversion recovery (STIR) imaging in distinguishing lipoma from lipoma-like subtype of well-differentiated liposarcoma. Spin-echo T1-weighted and STIR or fat-suppression T2-weighted sequences were performed in 60 lipomas and 32 lipoma-like well-differentiated liposarcomas, histologically proven, looking for thick septa or nodules in T1-weighted images and linear, nodular, or amorphous hyperintensities on FS-T2/STIR sequences. Fourteen lipomas (23.3%) showed thick septa and/or nodules on T1, whereas on FS-T2 or STIR sequences only seven (11.7%) displayed hyperintense nodules and/or septa. All well-differentiated liposarcomas contained these signs on FS-T2 or STIR sequences. The presence of hyperintense septa or nodules in a predominantly lipomatous tumor on FS-T2/STIR sequences helps to differentiate malignant tumors from lipomas. Employing the presence of hyperintense nodules and/or septa as criteria of malignancy specificity was 76.6% and sensitivity 100%. Overdiagnoses of well-differentiated liposarcoma can occur due to the presence of non-lipomatous areas within lipomas. (orig.)

Evaluation of Microstructure, Mechanical Properties and Corrosion Resistance of Friction Stir-Welded Aluminum and Magnesium Dissimilar Alloys

Science.gov (United States)

Verma, Jagesvar; Taiwade, Ravindra V.; Sapate, Sanjay G.; Patil, Awanikumar P.; Dhoble, Ashwinkumar S.

2017-10-01

Microstructure, mechanical properties and corrosion resistance of dissimilar friction stir-welded aluminum and magnesium alloys were investigated by applying three different rotational speeds at two different travel speeds. Sound joints were obtained in all the conditions. The microstructure was examined by an optical and scanning electron microscope, whereas localized chemical information was studied by energy-dispersive spectroscopy. Stir zone microstructure showed mixed bands of Al and Mg with coarse and fine equiaxed grains. Grain size of stir zone reduced compared to base metals, indicated by dynamic recrystallization. More Al patches were observed in the stir zone as rotational speed increased. X-ray diffraction showed the presence of intermetallics in the stir zone. Higher tensile strength and hardness were obtained at a high rotational speed corresponding to low travel speed. Tensile fractured surface indicated brittle nature of joints. Dissimilar friction stir weld joints showed different behaviors in different corrosive environments, and better corrosion resistance was observed at a high rotational speed corresponding to low travel speed (FW3) in a sulfuric and chloride environments. Increasing travel speed did not significantly affect on microstructure, mechanical properties and corrosion resistance as much as the rotational speed.

The value of fat-suppressed T2 or STIR sequences in distinguishing lipoma from well-differentiated liposarcoma

International Nuclear Information System (INIS)

Galant, J.; Marti-Bonmati, L.; Saez, F.; Soler, R.; Alcala-Santaella, R.; Navarro, M.

2003-01-01

The objective of this study was to evaluate the diagnostic value of fat-suppressed T2-weighted (FS-T2) images or short tau inversion recovery (STIR) imaging in distinguishing lipoma from lipoma-like subtype of well-differentiated liposarcoma. Spin-echo T1-weighted and STIR or fat-suppression T2-weighted sequences were performed in 60 lipomas and 32 lipoma-like well-differentiated liposarcomas, histologically proven, looking for thick septa or nodules in T1-weighted images and linear, nodular, or amorphous hyperintensities on FS-T2/STIR sequences. Fourteen lipomas (23.3%) showed thick septa and/or nodules on T1, whereas on FS-T2 or STIR sequences only seven (11.7%) displayed hyperintense nodules and/or septa. All well-differentiated liposarcomas contained these signs on FS-T2 or STIR sequences. The presence of hyperintense septa or nodules in a predominantly lipomatous tumor on FS-T2/STIR sequences helps to differentiate malignant tumors from lipomas. Employing the presence of hyperintense nodules and/or septa as criteria of malignancy specificity was 76.6% and sensitivity 100%. Overdiagnoses of well-differentiated liposarcoma can occur due to the presence of non-lipomatous areas within lipomas. (orig.)

BAR domain proteins regulate Rho GTPase signaling.

Science.gov (United States)

Aspenström, Pontus

2014-01-01

BAR proteins comprise a heterogeneous group of multi-domain proteins with diverse biological functions. The common denominator is the Bin-Amphiphysin-Rvs (BAR) domain that not only confers targeting to lipid bilayers, but also provides scaffolding to mold lipid membranes into concave or convex surfaces. This function of BAR proteins is an important determinant in the dynamic reconstruction of membrane vesicles, as well as of the plasma membrane. Several BAR proteins function as linkers between cytoskeletal regulation and membrane dynamics. These links are provided by direct interactions between BAR proteins and actin-nucleation-promoting factors of the Wiskott-Aldrich syndrome protein family and the Diaphanous-related formins. The Rho GTPases are key factors for orchestration of this intricate interplay. This review describes how BAR proteins regulate the activity of Rho GTPases, as well as how Rho GTPases regulate the function of BAR proteins. This mutual collaboration is a central factor in the regulation of vital cellular processes, such as cell migration, cytokinesis, intracellular transport, endocytosis, and exocytosis.

The inhomogeneous microstructure and deformation of similar and dissimilar Al-Zn containing Mg friction stir welds

Science.gov (United States)

Hiscocks, Jessica

The magnesium-based aluminum-zinc alloys have excellent stiffness to weight ratios, and may be combined by friction stir welding to expand the possible applications. The high aluminum alloy AZ80 in particular has the advantage of being relatively stiff but still extrudable. However limited friction stir welding research is available for this alloy and extrapolation from the extensive work in aluminum alloys is impractical due differences in precipitation behaviour, and magnesium's high plastic anisotropy and tendency to form strong textures during friction stir welding. This work investigates the correlations between local friction stir welded microstructures, textures, residual strains, and the local deformation behaviour based on strain mapping during tensile tests. Covering bead-on-plate and butt configurations, joining of similar and dissimilar materials, and a range of processing conditions, many findings of interest for deformation modelling and industrial applications are presented. Synchrotron x-ray diffraction study of an entire friction stir weld was used to determine texture, residual strain and dislocation density data from a single experiment. A number of unique findings were made, mainly related to the asymmetric distribution of properties both between sides of the weld and through the depth. Particularly in the case of strain measurements, features not detectable at coarser measurement spacing or by line scan are presented and compared for multiple processing conditions. Investigation of the longitudinal material flow during welding showed that even when periodicity in grain size, precipitate distribution, or texture was not observed, periodic changes in texture intensity resulting from compaction of material behind the tool were present, providing evidence that movement of nugget material remained periodic. Strain localisation and fracture behaviour were found to be completely different between good quality similar and dissimilar friction stir welds

N-barN interaction theoretical models

International Nuclear Information System (INIS)

Loiseau, B.

1991-12-01

In the framework of antinucleon-nucleon interaction theoretical models, our present understanding on the N-barN interaction is discussed, either from quark- or/and meson- and baryon-degrees of freedom, by considering the N-barN annihilation into mesons and the N-barN elastic and charge-exchange scattering. (author) 52 refs., 11 figs., 2 tabs

Structure and Mechanical Properties of Friction Stir Weld Joints of Magnesium Alloy AZ31

Science.gov (United States)

Nagasawa, T.; Otsuka, M.; Yokota, T.; Ueki, T.

The applicability of friction stir welding to hot rolled sheet of commercial magnesium alloy AZ31 plates has been investigated. Friction stir weld joint showed mechanical strength comparable to that of base material, though the ductility remained at one half of that of the latter. The results are consistent with the microstructure which is characterized by a fine grained bond layer bounded by-intermediate grained base metals. It is found that both anodizing treatment and insertion of aluminum foil between batting faces do not degrade the joint properties at all. The results suggest that friction stir welding can be potentially applied to magnesium alloy.

Turbulence modeling of the Von Karman flow: Viscous and inertial stirrings

International Nuclear Information System (INIS)

Poncet, Sebastien; Schiestel, Roland; Monchaux, Romain

2008-01-01

The present work considers the turbulent Von Karman flow generated by two counter-rotating smooth flat (viscous stirring) or bladed (inertial stirring) disks. Numerical predictions based on one-point statistical modeling using a low-Reynolds number second-order full stress transport closure (RSM model) are compared to velocity measurements performed at CEA (Commissariat a l'Energie Atomique, France). The main and significant novelty of this paper is the use of a drag force in the momentum equations to reproduce the effects of inertial stirring instead of modeling the blades themselves. The influences of the rotational Reynolds number, the aspect ratio of the cavity, the rotating disk speed ratio and of the presence or not of impellers are investigated to get a precise knowledge of both the dynamics and the turbulence properties in the Von Karman configuration. In particular, we highlighted the transition between the merged and separated boundary layer regimes and the one between the Batchelor [Batchelor, G.K., 1951. Note on a class of solutions of the Navier-Stokes equations representing steady rotationally-symmetric flow. Quat. J. Mech. Appl. Math. 4 (1), 29-41] and the Stewartson [Stewartson, K., 1953. On the flow between two rotating coaxial disks. Proc. Camb. Philos. Soc. 49, 333-341] flow structures in the smooth disk case. We determined also the transition between the one cell and the two cell regimes for both viscous and inertial stirrings

MR diagnosis of bone metastases at 1.5 T and 3 T. Can STIR imaging be omitted?

Energy Technology Data Exchange (ETDEWEB)

Ohlmann-Knafo, S.; Tarnoki, A.D.; Tarnoki, D.L.; Pickuth, D. [Caritasklinikum Saarbruecken St. Theresia (Germany). Dept. of Diagnostic and Interventional Radiology

2015-10-15

To date, no prospective comparative study of the diagnostic value of STIR versus T1-weighted (T1w) sequences at both 1.5 T and 3 T has been performed with special focus on the detectability of bone metastases. 212 oncological patients had a whole-body MRI at 1.5 T and/or at 3 T. The standard protocol comprised STIR and T1w sequences. All patients who showed typical signs of bone metastases were included in the study. Evaluation of the images was performed by the calculation of the number of metastases by three independent readers and by visual assessment on a 4-point scale. 86 patients fulfilled the inclusion criteria. The total number of metastases was significantly higher on T1w than on STIR images at both field strengths (p < 0.05). T1w revealed a sensitivity of 99.72 % (3 T) and 100.00 % (1.5 T) versus STIR with 70.99 % (3 T) and 79.34 % (1.5 T). In 53 % (38/72) of all patients, STIR detected fewer bone metastases in comparison with T1w at 3 T. At 1.5 T, STIR showed inferior results in 37.5 % (18/48) of all patients. Qualitative analysis indicated a significantly better lesion conspicuity, lesion delineation and an improved image quality on T1w compared to STIR imaging at both field strengths (p < 0.05) with similar results for T1w at 1.5 T and 3 T, but inferior results for STIR especially at 3 T. The whole-body MRI protocol for the detection of bone metastases could safely be limited to the T1w sequence in adults, especially at 3 T. There is no need for an additional STIR sequence. These initial results will have a major impact on the department's workflow if confirmed by larger studies as they will help reduce examination time and therefore save financial resources.

TESTING THEORIES IN BARRED-SPIRAL GALAXIES

International Nuclear Information System (INIS)

Martínez-García, Eric E.

2012-01-01

According to one version of the recently proposed 'manifold' theory that explains the origin of spirals and rings in relation to chaotic orbits, galaxies with stronger bars should have a higher spiral arms pitch angle when compared to galaxies with weaker bars. A subsample of barred-spiral galaxies in the Ohio State University Bright Galaxy Survey was used to analyze the spiral arms pitch angle. These were compared with bar strengths taken from the literature. It was found that the galaxies in which the spiral arms maintain a logarithmic shape for more than 70° seem to corroborate the predicted trend.

Microstructure and mechanical properties of friction stir welded Al/Mg2Si metal matrix cast composite

International Nuclear Information System (INIS)

Nami, H.; Adgi, H.; Sharifitabar, M.; Shamabadi, H.

2011-01-01

In this research, friction stir weldability of 15 wt.% Mg 2 Si particulate aluminum matrix cast composite and effects of tool rotation speed and number of welding passes on microstructure and mechanical properties of the joints were investigated. Microstructural observations were carried out by employing optical and scanning electron microscopy of the cross sections perpendicular to the tool traverse direction. Mechanical properties including microhardness and tensile strength were evaluated in detail. The results showed fragmentation of Mg 2 Si particles and Mg 2 Si needles existing in eutectic structure in stir zone. Also, homogeneous distribution of Mg 2 Si particles was observed in the stir zone as a result of stirring with high plastic strains. Tension test results indicated that tensile strength of the joint had an optimum at 1120 rpm tool rotation speed and decreased with increasing of the number of welding passes. Hardness of the joint increased due to modification of solidification microstructure of the base composite. This research indicates that friction stir welding is a good candidate for joining of 15 wt.% Mg 2 Si aluminum matrix composite castings.

DYNAMICAL CALCULATIONS OF (K)over-bar AND MULTI-(K)over-bar NUCLEI

Czech Academy of Sciences Publication Activity Database

Gazda, D.; Mareš, Jiří; Friedman, E.; Gal, A.

2009-01-01

Roč. 24, 2-3 (2009), s. 438-441 ISSN 0217-751X. [Conference MESON 2008. Jagiellonian Univ, Cracow, 06.06.2008-10.06.2008] R&D Projects: GA AV ČR IAA100480617 Institutional research plan: CEZ:AV0Z10480505 Keywords : (K)over-bar-nuclear RMF calculations * (K)over-bar-nuclear bound states * kaon condensation Subject RIV: BE - Theoretical Physics Impact factor: 0.941, year: 2009

Thermal modelling of friction stir welding

DEFF Research Database (Denmark)

Schmidt, Henrik Nikolaj Blicher; Hattel, Jesper Henri

2008-01-01

The objective of the present work is to present the basic elements of the thermal modelling of friction stir welding as well as to clarify some of the uncertainties in the literature regarding the different contributions to the heat generation. Some results from a new thermal pseudomechanical model...... in which the temperature-dependent yield stress of the weld material controls the heat generation are also presented....

Bobbin-Tool Friction-Stir Welding of Thick-Walled Aluminum Alloy Pressure Vessels

Energy Technology Data Exchange (ETDEWEB)

Dalder, E C; Pastrnak, J W; Engel, J; Forrest, R S; Kokko, E; Ternan, K M; Waldron, D

2007-06-06

It was desired to assemble thick-walled Al alloy 2219 pressure vessels by bobbin-tool friction-stir welding. To develop the welding-process, mechanical-property, and fitness-for-service information to support this effort, extensive friction-stir welding-parameter studies were conducted on 2.5 cm. and 3.8 cm. thick 2219 Al alloy plate. Starting conditions of the plate were the fully-heat-treated (-T62) and in the annealed (-O) conditions. The former condition was chosen with the intent of using the welds in either the 'as welded' condition or after a simple low-temperature aging treatment. Since preliminary stress-analyses showed that stresses in and near the welds would probably exceed the yield-strength of both 'as welded' and welded and aged weld-joints, a post-weld solution-treatment, quenching, and aging treatment was also examined. Once a suitable set of welding and post-weld heat-treatment parameters was established, the project divided into two parts. The first part concentrated on developing the necessary process information to be able to make defect-free friction-stir welds in 3.8 cm. thick Al alloy 2219 in the form of circumferential welds that would join two hemispherical forgings with a 102 cm. inside diameter. This necessitated going to a bobbin-tool welding-technique to simplify the tooling needed to react the large forces generated in friction-stir welding. The bobbin-tool technique was demonstrated on both flat-plates and plates that were bent to the curvature of the actual vessel. An additional issue was termination of the weld, i.e. closing out the hole left at the end of the weld by withdrawal of the friction-stir welding tool. This was accomplished by friction-plug welding a slightly-oversized Al alloy 2219 plug into the termination-hole, followed by machining the plug flush with both the inside and outside surfaces of the vessel. The second part of the project involved demonstrating that the welds were fit for the intended

Microstructural characterizations and mechanical properties in underwater friction stir welding of aluminum and magnesium dissimilar alloys

International Nuclear Information System (INIS)

Zhao, Yong; Lu, Zhengping; Yan, Keng; Huang, Linzhao

2015-01-01

Highlights: • Aluminum and magnesium alloys were joined by underwater friction stir welding. • Underwater FSW was conducted to improve properties of joint with lower heat input. • Microstructures and mechanical properties of dissimilar joint were investigated. • Intermetallic compounds developed in the fracture interface were analyzed. • Fracture features of the tensile samples were analyzed. - Abstract: Formation of intermetallic compounds in the stir zone of dissimilar welds affects the mechanical properties of the joints significantly. In order to reduce heat input and control the amount and morphological characteristics of brittle intermetallic compounds underwater friction stir welding of 6013 Al alloy and AZ31 Mg alloy was carried out. Microstructures, mechanical properties, elements distribution, and the fracture surface of the joints were analyzed by optical microscopy, scanning electron microscopy and energy dispersive X-ray spectroscopy, etc. The result shows that sound dissimilar joint with good mechanical properties can be obtained by underwater friction stir welding. Al and Mg alloys were stirred together and undergone the process of recrystallization, forming complex intercalated flow patterns in the stir zone. Tensile strength of the dissimilar joint was up to 152.3 MPa. Maximum hardness (142HV) appeared in the middle of the centerline of the specimen. Intermetallic compounds layer consisting of Al 3 Mg 2 and Mg 17 Al 12 formed in the Al/Mg interface and resulted in the fracture of the joint

MR STIR imaging versus spin-echo imaging of the breast

International Nuclear Information System (INIS)

Zobel, B.B.; Tella, S.; Patrizio, G.; Confalone, D.; D'Archivio, C.; Passariello, R.

1989-01-01

A valid tissue characterization of human breast diseases with conventional spin-echo (SE) sequences has not been achieved yet. In spite of experimental works showing that fibroadenomas have a small but significant difference in T1 relaxation time, T1- and T2-weighted SE sequences are not always able to differentiate them. We tried to solve the problem employing two different short T1 inversion-recovery (STIR) sequences with T1 values adequate to nullify the signal of glandular and fatty tissues. This paper reports on twenty-five nodules, including cysts, fibroadenomas, phylloids, and adenocarcinomas, examined with both STIR sequences performed on a superconductive 0.5-T unit

Ceramic bar impact experiments for improved material model

International Nuclear Information System (INIS)

Brar, N.S.; Proud, W.G.; Rajendran, A.M.

2004-01-01

Ceramic bar-on-bar (uniaxial stress) experiments are performed to extend uniaxial strain deformation states imposed in flyer plate impact experiments. A number of investigators engaged in modeling the bar-on-bar experiments have varying degrees of success in capturing the observed fracture modes in bars and correctly simulating the measured in-situ axial stress or free surface velocity histories. The difficulties encountered are related to uncertainties in understanding the dominant failure mechanisms as a function of different stress states imposed in bar impacts. Free surface velocity of the far end of the target AD998 bar were measured using a VISAR in a series of bar-on-bar impact experiments at nominal impact speeds of 100 m/s, 220 m/s, and 300 m/s. Velocity history data at an impact of 100 m/s show the material response as elastic. At higher impact velocities of 200 m/s and 300 m/s the velocity history data suggest an inelastic material response. A high-speed (Imacon) camera was employed to examine the fracture and failure of impactor and target bars. High speed photographs provide comprehensive data on geometry of damage and failure patterns as a function of time to check the validity of a particular constitutive material model for AD998 alumina used in numerical simulations of fracture and failure of the bars on impact

Influence of the weighing bar size to determine optimal time of biodiesel-glycerol separation by using the buoyancy weighing-bar method

Science.gov (United States)

Tambun, R.; Sibagariang, Y.; Manurung, J.

2018-02-01

The buoyancy weighing-bar method is a novel method in the particle size distribution measurement. This method can measure particle size distributions of the settling particles and floating particles. In this study, the buoyancy weighing-bar method is applied to determine optimal time of biodiesel-glycerol separation. The buoyancy weighing-bar method can be applied to determine the separation time because biodiesel and glycerol have the different densities. The influences of diameter of weighing-bar by using the buoyancy weighing-bar method would be experimentally investigated. The diameters of weighing-bar in this experiment are 8 mm, 10 mm, 15 mm and 20 mm, while the graduated cylinder (diameter : 65 mm) is used as vessel. The samples used in this experiment are the mixture of 95 % of biodiesel and 5 % of glycerol. The data obtained by the buoyancy weighing-bar method are analized by using the gas chromatography to determine the purity of biodiesel. Based on the data obtained, the buoyancy weighing-bar method can be used to detect the separation time of biodiesel-glycerol by using the weighing-bar diameter of 8 mm, 10 mm, 15 mm and 20 mm, but the most accuracy in determination the biodiesel-glycerol separation time is obtained by using the weighing-bar diameter of 20 mm. The biodiesel purity of 97.97 % could be detected at 64 minutes by using the buoyancy weighing-bar method when the weighing-bar diameter of 20 mm is used.

Physics-based process model approach for detecting discontinuity during friction stir welding

Energy Technology Data Exchange (ETDEWEB)

Shrivastava, Amber; Pfefferkorn, Frank E.; Duffie, Neil A.; Ferrier, Nicola J.; Smith, Christopher B.; Malukhin, Kostya; Zinn, Michael

2015-02-12

The goal of this work is to develop a method for detecting the creation of discontinuities during friction stir welding. This in situ weld monitoring method could significantly reduce the need for post-process inspection. A process force model and a discontinuity force model were created based on the state-of-the-art understanding of flow around an friction stir welding (FSW) tool. These models are used to predict the FSW forces and size of discontinuities formed in the weld. Friction stir welds with discontinuities and welds without discontinuities were created, and the differences in force dynamics were observed. In this paper, discontinuities were generated by reducing the tool rotation frequency and increasing the tool traverse speed in order to create "cold" welds. Experimental force data for welds with discontinuities and welds without discontinuities compared favorably with the predicted forces. The model currently overpredicts the discontinuity size.

Effects of mechanical force on grain structures of friction stir welded oxide dispersion strengthened ferritic steel

International Nuclear Information System (INIS)

Han, Wentuo; Kimura, Akihiko; Tsuda, Naoto; Serizawa, Hisashi; Chen, Dongsheng; Je, Hwanil; Fujii, Hidetoshi; Ha, Yoosung; Morisada, Yoshiaki; Noto, Hiroyuki

2014-01-01

The weldability of oxide dispersion strengthened (ODS) ferritic steels is a critical obstructive in the development and use of these steels. Friction stir welding has been considered to be a promising way to solve this problem. The main purpose of this work was to reveal the effects of mechanical force on grain structures of friction stir welded ODS ferritic steel. The grain appearances and the misorientation angles of grain boundaries in different welded zones were investigated by the electron backscatter diffraction (EBSD). Results showed that the mechanical force imposed by the stir tool can activate and promote the recrystallization characterized by the transformation of boundaries from LABs to HABs, and contribute to the grain refinement. The type of recrystallization in the stir zone can be classified as the continuous dynamic recrystallization (CDRX)

Effects of mechanical force on grain structures of friction stir welded oxide dispersion strengthened ferritic steel

Energy Technology Data Exchange (ETDEWEB)

Han, Wentuo, E-mail: hanwentuo@hotmail.com [Institute of Advanced Energy, Kyoto University, Gokasho, Uji, Kyoto 611-0011 (Japan); Kimura, Akihiko [Institute of Advanced Energy, Kyoto University, Gokasho, Uji, Kyoto 611-0011 (Japan); Tsuda, Naoto [Graduate School of Energy Science, Kyoto University, Gokasho, Uji, Kyoto 611-0011 (Japan); Serizawa, Hisashi [Joining and Welding Research Institute, Osaka University, Ibaraki, Osaka 567-0047 (Japan); Chen, Dongsheng [Graduate School of Energy Science, Kyoto University, Gokasho, Uji, Kyoto 611-0011 (Japan); Je, Hwanil [Institute of Advanced Energy, Kyoto University, Gokasho, Uji, Kyoto 611-0011 (Japan); Fujii, Hidetoshi [Joining and Welding Research Institute, Osaka University, Ibaraki, Osaka 567-0047 (Japan); Ha, Yoosung [Graduate School of Energy Science, Kyoto University, Gokasho, Uji, Kyoto 611-0011 (Japan); Morisada, Yoshiaki [Joining and Welding Research Institute, Osaka University, Ibaraki, Osaka 567-0047 (Japan); Noto, Hiroyuki [Graduate School of Energy Science, Kyoto University, Gokasho, Uji, Kyoto 611-0011 (Japan)

2014-12-15

The weldability of oxide dispersion strengthened (ODS) ferritic steels is a critical obstructive in the development and use of these steels. Friction stir welding has been considered to be a promising way to solve this problem. The main purpose of this work was to reveal the effects of mechanical force on grain structures of friction stir welded ODS ferritic steel. The grain appearances and the misorientation angles of grain boundaries in different welded zones were investigated by the electron backscatter diffraction (EBSD). Results showed that the mechanical force imposed by the stir tool can activate and promote the recrystallization characterized by the transformation of boundaries from LABs to HABs, and contribute to the grain refinement. The type of recrystallization in the stir zone can be classified as the continuous dynamic recrystallization (CDRX)

Friction Stir Processing of ODS and FM Steels

Energy Technology Data Exchange (ETDEWEB)

Kang, Suk Hoon; Chun, Young Bum; Noh, Sang Hoon; Jang, Jin Sung; Kim, Tae Kyu [Korea Atomic Energy Research Institute, Daejeon (Korea, Republic of)

2013-10-15

In ODS steels, it is well known that uniform nano-oxide dispersoids act as pinning points to obstruct dislocation and grain boundary motion, however, those advantages will be disappeared while the material is subjected to the high temperature of conventional fusion welding. Rotary friction welding, also referred to as friction stir welding (FSW), has shown great promise as a method for welding traditionally difficult to weld materials such as aluminum alloys. This relatively new technology has more recently been applied to higher melting temperature alloys such as steels, nickel-based and titanium alloys. Friction stir processing (FSP) is a method of changing the properties of a metal through intense, localized plastic deformation. FSW is the precursor of the FSP technique. When ideally implemented, this process mixes the material without changing the phase and creates a microstructure with fine, equiaxed grains. This homogeneous grain structure, separated by high-angle boundaries, allows some alloys to take on superplastic properties. In this study, FSW is used as a substitutive welding process between FMS tube and ODS parts. The dimension of tube is 7.0 OD, 0.5 T. During the FSW, dynamic-recrystallized grains are developed; the uniform oxides dispersion is preserved in the metal matrix. The microstructure and microtexture of the material near the stir zone is found to be influenced by the rotational behavior of the tool. The additive effect from FSP on sample surface is considered. Since the mechanical alloying (MA) and FSP commonly apply extreme shear deformation on materials, the dispersion of oxide particle in ODS steels is very active during both processes. Friction stir welding appears to be a very promising technique for the welding of FMS and ODS steels in the form of sheet and tube. FSW could successfully produce defect-free welds on FMS tubes and ODS ring assembly. FSW produces a fine grain structure consisting of ferrite and martensite, and the oxide

Friction Stir Processing of ODS and FM Steels

International Nuclear Information System (INIS)

Kang, Suk Hoon; Chun, Young Bum; Noh, Sang Hoon; Jang, Jin Sung; Kim, Tae Kyu

2013-01-01

In ODS steels, it is well known that uniform nano-oxide dispersoids act as pinning points to obstruct dislocation and grain boundary motion, however, those advantages will be disappeared while the material is subjected to the high temperature of conventional fusion welding. Rotary friction welding, also referred to as friction stir welding (FSW), has shown great promise as a method for welding traditionally difficult to weld materials such as aluminum alloys. This relatively new technology has more recently been applied to higher melting temperature alloys such as steels, nickel-based and titanium alloys. Friction stir processing (FSP) is a method of changing the properties of a metal through intense, localized plastic deformation. FSW is the precursor of the FSP technique. When ideally implemented, this process mixes the material without changing the phase and creates a microstructure with fine, equiaxed grains. This homogeneous grain structure, separated by high-angle boundaries, allows some alloys to take on superplastic properties. In this study, FSW is used as a substitutive welding process between FMS tube and ODS parts. The dimension of tube is 7.0 OD, 0.5 T. During the FSW, dynamic-recrystallized grains are developed; the uniform oxides dispersion is preserved in the metal matrix. The microstructure and microtexture of the material near the stir zone is found to be influenced by the rotational behavior of the tool. The additive effect from FSP on sample surface is considered. Since the mechanical alloying (MA) and FSP commonly apply extreme shear deformation on materials, the dispersion of oxide particle in ODS steels is very active during both processes. Friction stir welding appears to be a very promising technique for the welding of FMS and ODS steels in the form of sheet and tube. FSW could successfully produce defect-free welds on FMS tubes and ODS ring assembly. FSW produces a fine grain structure consisting of ferrite and martensite, and the oxide

Bar Formation in Milky Way type Galaxies

Directory of Open Access Journals (Sweden)

Polyachenko E. V.

2016-12-01

Full Text Available Many barred galaxies, possibly including the Milky Way, have cusps in their centers. There is a widespread belief, however, that the usual bar instability, which occurs in bulgeless galaxy models, is impossible for cuspy models because of the presence of the inner Lindblad resonance for any pattern speed. At the same time, there is numerical evidence that the bar instability can form a bar. We analyze this discrepancy by performing accurate and diverse N-body simulations and calculating the normal modes. We show that bar formation in cuspy galaxies can be explained by taking into account the disk thickness. The exponential growth time is moderate (about 250 Myr for typical current disk masses, but it increases considerably (by a factor of two or more if the live halo and bulge are substituted by a rigid halo/bulge potential; the pattern speeds remain almost the same. Normal mode analysis with different disk mass favors a young bar hypothesis, according to which the bar instability has saturated only recently.

Kinematical and dynamical models for barred spiral galaxies

International Nuclear Information System (INIS)

Davoust, E.

1983-01-01

This is a review of published works on the kinematics and dynamics of stellar bars and barred spiral galaxies. The periodic orbits of stars are elongated along the bar and enhance it out to a certain distance from the center. The important role of the interstellar gas is pointed out by the models of gas clouds and flows: the trajectories are also along the bar, but shock waves arise in front of the bar and transient spiral structures appear at its ends. These models reproduce the observed velocity fields fairly well. The investigations of the stability of axisymmetric galactic disks show that they are very unstable with respect to bar shaped perturbations and might explain why two thirds of the known spiral galaxies are barred [fr

Microstructural transformations and mechanical properties of cast NiAl bronze: Effects of fusion welding and friction stir processing

International Nuclear Information System (INIS)

Fuller, M.D.; Swaminathan, S.; Zhilyaev, A.P.; McNelley, T.R.

2007-01-01

A plate of as-cast NiAl bronze (NAB) material was sectioned from a large casting. A six-pass fusion weld overlay was placed in a machined groove; a portion of the weld reinforcement was removed by milling and a single friction stir processing (FSP) pass was conducted in a direction transverse to the axis of and over the weld overlay. A procedure was developed for machining of miniature tensile samples and the distributions of strength and ductility were evaluated for the fusion weld metal; for the stir zone (SZ) produced by the friction stir processing; and for a region wherein friction stir processing had taken place over the fusion weld. A region of low ductility in the heat affected zone (HAZ) of the fusion weld and in the thermomechanically affected zone (TMAZ) of friction stir processed material was attributed to partial reversion of an equilibrium lamellar eutectoid constituent upon local heating above ∼800 deg. C and formation of non-equilibrium transformation products upon subsequent cooling. The adverse effect on ductility is worse in the heat affected zone of the fusion weld than in the thermomechanically affected zone of friction stir processing due to the lower heat input of the latter process. The implications of this work to engineering applications of friction stir processing are discussed

Effect of friction stirring on microstructure in equal channel angular pressed aluminum alloys

Energy Technology Data Exchange (ETDEWEB)

Sato, Y.S.; Urata, M.; Kokawa, H.; Ikeda, K. [Dept. of Materials Processing, Graduate School of Engineering, Tohoku Univ., Aoba-yama, Sendai (Japan)

2003-07-01

Friction stir welding (FSW) was applied to equal channel angular (ECA) pressed aluminum (Al) alloys with high strength and toughness, and the effect of FSW on microstructure and the hardness profile in ECA-pressed alloys was examined. In the weld of ECA-pressed Al alloy 1050 and 5083, the stir zone had roughly the same hardness as the ECA-pressed material, while the hardness was slightly reduced in the thermo-mechanically affected zone (TMAZ). The reduction of hardness in the TMAZ was due to dynamic recovery of dislocation cells of the ECA-pressed material. The addition of Zr to Al suppressed the reduction of hardness in the TMAZ. Consequently, friction stir (FS) weld of Al-Zr alloy retained the hardness of the ECA-pressed material throughout the weld. (orig.)

Characterization and Strain-Hardening Behavior of Friction Stir-Welded Ferritic Stainless Steel

Science.gov (United States)

Sharma, Gaurav; Dwivedi, Dheerendra Kumar; Jain, Pramod Kumar

2017-12-01

In this study, friction stir-welded joint of 3-mm-thick plates of 409 ferritic stainless steel (FSS) was characterized in light of microstructure, x-ray diffraction analysis, hardness, tensile strength, ductility, corrosion and work hardening properties. The FSW joint made of ferritic stainless steel comprises of three distinct regions including the base metal. In stir zone highly refined ferrite grains with martensite and some carbide precipitates at the grain boundaries were observed. X-ray diffraction analysis also revealed precipitation of Cr23C6 and martensite formation in heat-affected zone and stir zone. In tensile testing of the transverse weld samples, the failure eventuated within the gauge length of the specimen from the base metal region having tensile properties overmatched to the as-received base metal. The tensile strength and elongation of the longitudinal (all weld) sample were found to be 1014 MPa and 9.47%, respectively. However, in potentiodynamic polarization test, the corrosion current density of the stir zone was highest among all the three zones. The strain-hardening exponent for base metal, transverse and longitudinal (all weld) weld samples was calculated using various equations. Both the transverse and longitudinal weld samples exhibited higher strain-hardening exponents as compared to the as-received base metal. In Kocks-Mecking plots for the base metal and weld samples at least two stages of strain hardening were observed.

A dense cell retention culture system using stirred ceramic membrane reactor.

Science.gov (United States)

Suzuki, T; Sato, T; Kominami, M

1994-11-20

A novel reactor design incorporating porous ceramic tubes into a stirred jar fermentor was developed. The stirred ceramic membrane reactor has two ceramic tubular membrane units inside the vessel and maintains high filtration flux by alternating use for filtering and recovering from clogging. Each filter unit was linked for both extraction of culture broth and gas sparging. High permeability was maintained for long periods by applying the periodical control between filtering and air sparging during the stirred retention culture of Saccharomyces cerevisiae. The ceramic filter aeration system increased the k(L)a to about five times that of ordinary gas sparing. Using the automatic feeding and filtering system, cell mass concentration reached 207 g/L in a short time, while it was 64 g/L in a fed-batch culture. More than 99% of the growing cells were retained in the fermentor by the filtering culture. Both yield and productivity of cells were also increased by controlling the feeding of fresh medium and filtering the supernatant of the dense cells culture. (c) 1994 John Wiley & Sons, Inc.

Automatic Gap Detection in Friction Stir Welding Processes (Preprint)

National Research Council Canada - National Science Library

Yang, Yu; Kalya, Prabhanjana; Landers, Robert G; Krishnamurthy, K

2006-01-01

.... This paper develops a monitoring algorithm to detect gaps in Friction Stir Welding (FSW) processes. Experimental studies are conducted to determine how the process parameters and the gap width affect the welding process...

Quantities of Interest in Jet Stirred Reactor Oxidation of a High-Octane Gasoline

KAUST Repository

Chen, Bingjie

2017-03-28

This work examines the oxidation of a well-characterized, high-octane-number FACE (fuel for advanced combustion engines) F gasoline. Oxidation experiments were performed in a jet-stirred reactor (JSR) for FACE F gasoline under the following conditions: pressure, 10 bar; temperature, 530-1250 K; residence time, 0.7s; equivalence ratios, 0.5, 1.0, and 2.0. Detailed species profiles were achieved by identification and quantification from gas chromatography with mass spectrometry (GC-MS) and Fourier transform infrared spectrometry (FTIR). Four surrogates, with physical and chemical properties that mimic the real fuel properties, were used for simulations, with a detailed gasoline surrogate kinetic model. Fuel and species profiles were well-captured and-predicted by comparisons between experimental results and surrogate simulations. Further analysis was performed using a quantities of interest (QoI) approach to show the differences between experimental and simulation results and to evaluate the gasoline surrogate kinetic model. Analysis of the multicomponent surrogate kinetic model indicated that iso-octane and alkyl aromatic oxidation reactions had impact on species profiles in the high-temperature region;. however, the main production and consumption channels were related to smaller molecule reactions. The results presented here offer new insights into the oxidation chemistry of complex gasoline fuels and provide suggestions for the future development of surrogate kinetic models.

Pulsed ultrasonic stir welding method

Science.gov (United States)

Ding, R. Jeffrey (Inventor)

2013-01-01

A method of performing ultrasonic stir welding uses a welding head assembly to include a plate and a rod passing through the plate. The rod is rotatable about a longitudinal axis thereof. In the method, the rod is rotated about its longitudinal axis during a welding operation. During the welding operation, a series of on-off ultrasonic pulses are applied to the rod such that they propagate parallel to the rod's longitudinal axis. At least a pulse rate associated with the on-off ultrasonic pulses is controlled.

Measurement of the cross section ratio $\\sigma_\\mathrm{t \\bar{t} b \\bar{b}} / \\sigma_\\mathrm{t \\bar{t} jj }$ in pp collisions at $\\sqrt{s}$ = 8 TeV

CERN Document Server

Khachatryan, Vardan; Tumasyan, Armen; Adam, Wolfgang; Bergauer, Thomas; Dragicevic, Marko; Erö, Janos; Fabjan, Christian; Friedl, Markus; Fruehwirth, Rudolf; Ghete, Vasile Mihai; Hartl, Christian; Hörmann, Natascha; Hrubec, Josef; Jeitler, Manfred; Kiesenhofer, Wolfgang; Knünz, Valentin; Krammer, Manfred; Krätschmer, Ilse; Liko, Dietrich; Mikulec, Ivan; Rabady, Dinyar; Rahbaran, Babak; Rohringer, Herbert; Schöfbeck, Robert; Strauss, Josef; Taurok, Anton; Treberer-Treberspurg, Wolfgang; Waltenberger, Wolfgang; Wulz, Claudia-Elisabeth; Mossolov, Vladimir; Shumeiko, Nikolai; Suarez Gonzalez, Juan; Alderweireldt, Sara; Bansal, Monika; Bansal, Sunil; Cornelis, Tom; De Wolf, Eddi A; Janssen, Xavier; Knutsson, Albert; Luyckx, Sten; Ochesanu, Silvia; Roland, Benoit; Rougny, Romain; Van De Klundert, Merijn; Van Haevermaet, Hans; Van Mechelen, Pierre; Van Remortel, Nick; Van Spilbeeck, Alex; Blekman, Freya; Blyweert, Stijn; D'Hondt, Jorgen; Daci, Nadir; Heracleous, Natalie; Keaveney, James; Lowette, Steven; 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Baus, Colin; Berger, Joram; Böser, Christian; Butz, Erik; Chwalek, Thorsten; De Boer, Wim; Descroix, Alexis; Dierlamm, Alexander; Feindt, Michael; Frensch, Felix; Giffels, Manuel; Hartmann, Frank; Hauth, Thomas; Husemann, Ulrich; Katkov, Igor; Kornmayer, Andreas; Kuznetsova, Ekaterina; Lobelle Pardo, Patricia; Mozer, Matthias Ulrich; Müller, Thomas; Nürnberg, Andreas; Quast, Gunter; Rabbertz, Klaus; Ratnikov, Fedor; Röcker, Steffen; Simonis, Hans-Jürgen; Stober, Fred-Markus Helmut; Ulrich, Ralf; Wagner-Kuhr, Jeannine; Wayand, Stefan; Weiler, Thomas; Wolf, Roger; Anagnostou, Georgios; Daskalakis, Georgios; Geralis, Theodoros; Giakoumopoulou, Viktoria Athina; Kyriakis, Aristotelis; Loukas, Demetrios; Markou, Athanasios; Markou, Christos; Psallidas, Andreas; Topsis-Giotis, Iasonas; Agapitos, Antonis; Kesisoglou, Stilianos; Panagiotou, Apostolos; Saoulidou, Niki; Stiliaris, Efstathios; Aslanoglou, Xenofon; Evangelou, Ioannis; Flouris, Giannis; Foudas, Costas; Kokkas, Panagiotis; Manthos, Nikolaos; Papadopoulos, Ioannis; Paradas, Evangelos; Bencze, Gyorgy; Hajdu, Csaba; Hidas, Pàl; Horvath, Dezso; Sikler, Ferenc; Veszpremi, Viktor; Vesztergombi, Gyorgy; Zsigmond, Anna Julia; Beni, Noemi; Czellar, Sandor; Karancsi, János; Molnar, Jozsef; Palinkas, Jozsef; Szillasi, Zoltan; Raics, Peter; Trocsanyi, Zoltan Laszlo; Ujvari, Balazs; Swain, Sanjay Kumar; Beri, Suman Bala; Bhatnagar, Vipin; Gupta, Ruchi; Bhawandeep, Bhawandeep; Kalsi, Amandeep Kaur; Kaur, Manjit; Mittal, Monika; Nishu, Nishu; Singh, Jasbir; Kumar, Ashok; Kumar, Arun; Ahuja, Sudha; Bhardwaj, Ashutosh; Choudhary, Brajesh C; Kumar, Ajay; Malhotra, Shivali; Naimuddin, Md; Ranjan, Kirti; Sharma, Varun; Banerjee, Sunanda; Bhattacharya, Satyaki; Chatterjee, Kalyanmoy; Dutta, Suchandra; Gomber, Bhawna; Jain, Sandhya; Jain, Shilpi; Khurana, Raman; Modak, Atanu; Mukherjee, Swagata; Roy, Debarati; Sarkar, Subir; Sharan, Manoj; Abdulsalam, Abdulla; Dutta, Dipanwita; Kailas, Swaminathan; Kumar, Vineet; Mohanty, Ajit Kumar; Pant, Lalit Mohan; 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Margoni, Martino; Meneguzzo, Anna Teresa; Pazzini, Jacopo; Pozzobon, Nicola; Ronchese, Paolo; Simonetto, Franco; Torassa, Ezio; Tosi, Mia; Zotto, Pierluigi; Zucchetta, Alberto; Zumerle, Gianni; Gabusi, Michele; Ratti, Sergio P; Riccardi, Cristina; Salvini, Paola; Vitulo, Paolo; Biasini, Maurizio; Bilei, Gian Mario; Ciangottini, Diego; Fanò, Livio; Lariccia, Paolo; Mantovani, Giancarlo; Menichelli, Mauro; Romeo, Francesco; Saha, Anirban; Santocchia, Attilio; Spiezia, Aniello; Androsov, Konstantin; Azzurri, Paolo; Bagliesi, Giuseppe; Bernardini, Jacopo; Boccali, Tommaso; Broccolo, Giuseppe; Castaldi, Rino; Ciocci, Maria Agnese; Dell'Orso, Roberto; Donato, Silvio; Fiori, Francesco; Foà, Lorenzo; Giassi, Alessandro; Grippo, Maria Teresa; Ligabue, Franco; Lomtadze, Teimuraz; Martini, Luca; Messineo, Alberto; Moon, Chang-Seong; Palla, Fabrizio; Rizzi, Andrea; Savoy-Navarro, Aurore; Serban, Alin Titus; Spagnolo, Paolo; Squillacioti, Paola; Tenchini, Roberto; Tonelli, Guido; Venturi, Andrea; Verdini, Piero Giorgio; Vernieri, Caterina; Barone, Luciano; Cavallari, Francesca; D'imperio, Giulia; Del Re, Daniele; Diemoz, Marcella; Grassi, Marco; Jorda, Clara; Longo, Egidio; Margaroli, Fabrizio; Meridiani, Paolo; Micheli, Francesco; Nourbakhsh, Shervin; Organtini, Giovanni; Paramatti, Riccardo; Rahatlou, Shahram; Rovelli, Chiara; Santanastasio, Francesco; Soffi, Livia; Traczyk, Piotr; Amapane, Nicola; Arcidiacono, Roberta; Argiro, Stefano; Arneodo, Michele; Bellan, Riccardo; Biino, Cristina; Cartiglia, Nicolo; Casasso, Stefano; Costa, Marco; Degano, Alessandro; Demaria, Natale; Finco, Linda; Mariotti, Chiara; Maselli, Silvia; Migliore, Ernesto; Monaco, Vincenzo; Musich, Marco; Obertino, Maria Margherita; Ortona, Giacomo; Pacher, Luca; Pastrone, Nadia; Pelliccioni, Mario; Pinna Angioni, Gian Luca; Potenza, Alberto; Romero, Alessandra; Ruspa, Marta; Sacchi, Roberto; Solano, Ada; Staiano, Amedeo; Trapani, Pier Paolo; Belforte, Stefano; Candelise, Vieri; Casarsa, Massimo; Cossutti, Fabio; Della Ricca, Giuseppe; Gobbo, Benigno; La Licata, Chiara; Marone, Matteo; Montanino, Damiana; Schizzi, Andrea; Umer, Tomo; Zanetti, Anna; Chang, Sunghyun; Kropivnitskaya, Anna; Nam, Soon-Kwon; Kim, Dong Hee; Kim, Gui Nyun; Kim, Min Suk; Kong, Dae Jung; Lee, Sangeun; Oh, Young Do; Park, Hyangkyu; Sakharov, Alexandre; Son, Dong-Chul; Kim, Tae Jeong; Kim, Jae Yool; Song, Sanghyeon; Choi, Suyong; Gyun, Dooyeon; Hong, Byung-Sik; Jo, Mihee; Kim, Hyunchul; Kim, Yongsun; Lee, Byounghoon; Lee, Kyong Sei; Park, Sung Keun; Roh, Youn; Choi, Minkyoo; Kim, Ji Hyun; Park, Inkyu; Park, Sangnam; Ryu, Geonmo; Ryu, Min Sang; Choi, Young-Il; Choi, Young Kyu; Goh, Junghwan; Kim, Donghyun; Kwon, Eunhyang; Lee, Jongseok; Seo, Hyunkwan; Yu, Intae; Juodagalvis, Andrius; Komaragiri, Jyothsna Rani; Md Ali, Mohd Adli Bin; Castilla-Valdez, Heriberto; De La Cruz-Burelo, Eduard; Heredia-de La Cruz, Ivan; Lopez-Fernandez, Ricardo; Sánchez Hernández, Alberto; Carrillo Moreno, Salvador; Vazquez Valencia, Fabiola; Pedraza, Isabel; Salazar Ibarguen, Humberto Antonio; Casimiro Linares, Edgar; Morelos Pineda, Antonio; Krofcheck, David; Butler, Philip H; Reucroft, Steve; Ahmad, Ashfaq; Ahmad, Muhammad; Hassan, Qamar; Hoorani, Hafeez R; Khalid, Shoaib; Khan, Wajid Ali; Khurshid, Taimoor; Shah, Mehar Ali; Shoaib, Muhammad; Bialkowska, Helena; Bluj, Michal; Boimska, Bożena; Frueboes, Tomasz; Górski, Maciej; Kazana, Malgorzata; Nawrocki, Krzysztof; Romanowska-Rybinska, Katarzyna; Szleper, Michal; Zalewski, Piotr; Brona, Grzegorz; Bunkowski, Karol; Cwiok, Mikolaj; Dominik, Wojciech; Doroba, Krzysztof; Kalinowski, Artur; Konecki, Marcin; Krolikowski, Jan; Misiura, Maciej; Olszewski, Michał; Wolszczak, Weronika; Bargassa, Pedrame; Beirão Da Cruz E Silva, Cristóvão; Faccioli, Pietro; Ferreira Parracho, Pedro Guilherme; Gallinaro, Michele; Nguyen, Federico; Rodrigues Antunes, Joao; Seixas, Joao; Varela, Joao; Vischia, Pietro; Afanasiev, Serguei; Bunin, Pavel; Gavrilenko, Mikhail; Golutvin, Igor; Gorbunov, Ilya; Kamenev, Alexey; Karjavin, Vladimir; Konoplyanikov, Viktor; Lanev, Alexander; Malakhov, Alexander; Matveev, Viktor; Moisenz, Petr; Palichik, Vladimir; Perelygin, Victor; Shmatov, Sergey; Skatchkov, Nikolai; Smirnov, Vitaly; Zarubin, Anatoli; Golovtsov, Victor; Ivanov, Yury; Kim, Victor; Levchenko, Petr; Murzin, Victor; Oreshkin, Vadim; Smirnov, Igor; Sulimov, Valentin; Uvarov, Lev; Vavilov, Sergey; Vorobyev, Alexey; Vorobyev, Andrey; Andreev, Yuri; Dermenev, Alexander; Gninenko, Sergei; Golubev, Nikolai; Kirsanov, Mikhail; Krasnikov, Nikolai; Pashenkov, Anatoli; Tlisov, Danila; Toropin, Alexander; Epshteyn, Vladimir; Gavrilov, Vladimir; Lychkovskaya, Natalia; Popov, Vladimir; Safronov, Grigory; Semenov, Sergey; Spiridonov, Alexander; Stolin, Viatcheslav; Vlasov, Evgueni; Zhokin, Alexander; Andreev, Vladimir; Azarkin, Maksim; Dremin, Igor; Kirakosyan, Martin; Leonidov, Andrey; Mesyats, Gennady; Rusakov, Sergey V; Vinogradov, Alexey; Belyaev, Andrey; Boos, Edouard; Bunichev, Viacheslav; Dubinin, Mikhail; Dudko, Lev; Gribushin, Andrey; Klyukhin, Vyacheslav; Kodolova, Olga; Lokhtin, Igor; Obraztsov, Stepan; Perfilov, Maxim; Savrin, Viktor; Snigirev, Alexander; Azhgirey, Igor; Bayshev, Igor; Bitioukov, Sergei; Kachanov, Vassili; Kalinin, Alexey; Konstantinov, Dmitri; Krychkine, Victor; Petrov, Vladimir; Ryutin, Roman; Sobol, Andrei; Tourtchanovitch, Leonid; Troshin, Sergey; Tyurin, Nikolay; Uzunian, Andrey; Volkov, Alexey; Adzic, Petar; Ekmedzic, Marko; Milosevic, Jovan; Rekovic, Vladimir; Alcaraz Maestre, Juan; Battilana, Carlo; Calvo, Enrique; Cerrada, Marcos; Chamizo Llatas, Maria; Colino, Nicanor; De La Cruz, Begona; Delgado Peris, Antonio; Domínguez Vázquez, Daniel; Escalante Del Valle, Alberto; Fernandez Bedoya, Cristina; Fernández Ramos, Juan Pablo; Flix, Jose; Fouz, Maria Cruz; Garcia-Abia, Pablo; Gonzalez Lopez, Oscar; Goy Lopez, Silvia; Hernandez, Jose M; Josa, Maria Isabel; Merino, Gonzalo; Navarro De Martino, Eduardo; Pérez-Calero Yzquierdo, Antonio María; Puerta Pelayo, Jesus; Quintario Olmeda, Adrián; Redondo, Ignacio; Romero, Luciano; Senghi Soares, Mara; Albajar, Carmen; de Trocóniz, Jorge F; Missiroli, Marino; Moran, Dermot; Brun, Hugues; Cuevas, Javier; Fernandez Menendez, Javier; Folgueras, Santiago; Gonzalez Caballero, Isidro; Lloret Iglesias, Lara; Brochero Cifuentes, Javier Andres; Cabrillo, Iban Jose; Calderon, Alicia; Duarte Campderros, Jordi; Fernandez, Marcos; Gomez, Gervasio; Graziano, Alberto; Lopez Virto, Amparo; Marco, Jesus; Marco, Rafael; Martinez Rivero, Celso; Matorras, Francisco; Munoz Sanchez, Francisca Javiela; Piedra Gomez, Jonatan; Rodrigo, Teresa; Rodríguez-Marrero, Ana Yaiza; Ruiz-Jimeno, Alberto; Scodellaro, Luca; Vila, Ivan; Vilar Cortabitarte, Rocio; Abbaneo, Duccio; Auffray, Etiennette; Auzinger, Georg; Bachtis, Michail; Baillon, Paul; Ball, Austin; Barney, David; Benaglia, Andrea; Bendavid, Joshua; Benhabib, Lamia; Benitez, Jose F; Bernet, Colin; Bianchi, Giovanni; Bloch, Philippe; Bocci, Andrea; Bonato, Alessio; Bondu, Olivier; Botta, Cristina; Breuker, Horst; Camporesi, Tiziano; Cerminara, Gianluca; Colafranceschi, Stefano; D'Alfonso, Mariarosaria; D'Enterria, David; Dabrowski, Anne; David Tinoco Mendes, Andre; De Guio, Federico; De Roeck, Albert; De Visscher, Simon; Dobson, Marc; Dordevic, Milos; Dorney, Brian; Dupont-Sagorin, Niels; Elliott-Peisert, Anna; Eugster, Jürg; Franzoni, Giovanni; Funk, Wolfgang; Gigi, Dominique; Gill, Karl; Giordano, Domenico; Girone, Maria; Glege, Frank; Guida, Roberto; Gundacker, Stefan; Guthoff, Moritz; Hammer, Josef; Hansen, Magnus; Harris, Philip; Hegeman, Jeroen; Innocente, Vincenzo; Janot, Patrick; Kousouris, Konstantinos; Krajczar, Krisztian; Lecoq, Paul; Lourenco, Carlos; Magini, Nicolo; Malgeri, Luca; Mannelli, Marcello; Marrouche, Jad; Masetti, Lorenzo; Meijers, Frans; Mersi, Stefano; Meschi, Emilio; Moortgat, Filip; Morovic, Srecko; Mulders, Martijn; Musella, Pasquale; Orsini, Luciano; Pape, Luc; Perez, Emmanuelle; Perrozzi, Luca; Petrilli, Achille; Petrucciani, Giovanni; Pfeiffer, Andreas; Pierini, Maurizio; Pimiä, Martti; Piparo, Danilo; Plagge, Michael; Racz, Attila; Rolandi, Gigi; Rovere, Marco; Sakulin, Hannes; Schäfer, Christoph; Schwick, Christoph; Sharma, Archana; Siegrist, Patrice; Silva, Pedro; Simon, Michal; Sphicas, Paraskevas; Spiga, Daniele; Steggemann, Jan; Stieger, Benjamin; Stoye, Markus; Takahashi, Yuta; Treille, Daniel; Tsirou, Andromachi; Veres, Gabor Istvan; Vlimant, Jean-Roch; Wardle, Nicholas; Wöhri, Hermine Katharina; Wollny, Heiner; Zeuner, Wolfram Dietrich; Bertl, Willi; Deiters, Konrad; Erdmann, Wolfram; Horisberger, Roland; Ingram, Quentin; Kaestli, Hans-Christian; Kotlinski, Danek; Langenegger, Urs; Renker, Dieter; Rohe, Tilman; Bachmair, Felix; Bäni, Lukas; Bianchini, Lorenzo; Bortignon, Pierluigi; Buchmann, Marco-Andrea; Casal, Bruno; Chanon, Nicolas; Deisher, Amanda; Dissertori, Günther; Dittmar, Michael; Donegà, Mauro; Dünser, Marc; Eller, Philipp; Grab, Christoph; Hits, Dmitry; Lustermann, Werner; Mangano, Boris; Marini, Andrea Carlo; Martinez Ruiz del Arbol, Pablo; Meister, Daniel; Mohr, Niklas; Nägeli, Christoph; Nessi-Tedaldi, Francesca; Pandolfi, Francesco; Pauss, Felicitas; Peruzzi, Marco; Quittnat, Milena; Rebane, Liis; Rossini, Marco; Starodumov, Andrei; Takahashi, Maiko; Theofilatos, Konstantinos; Wallny, Rainer; Weber, Hannsjoerg Artur; Amsler, Claude; Canelli, Maria Florencia; Chiochia, Vincenzo; De Cosa, Annapaola; Hinzmann, Andreas; Hreus, Tomas; Kilminster, Benjamin; Lange, Clemens; Millan Mejias, Barbara; Ngadiuba, Jennifer; Robmann, Peter; Ronga, Frederic Jean; Taroni, Silvia; Verzetti, Mauro; Yang, Yong; Cardaci, Marco; Chen, Kuan-Hsin; Ferro, Cristina; Kuo, Chia-Ming; Lin, Willis; Lu, Yun-Ju; Volpe, Roberta; Yu, Shin-Shan; Chang, Paoti; Chang, You-Hao; Chang, Yu-Wei; Chao, Yuan; Chen, Kai-Feng; Chen, Po-Hsun; Dietz, Charles; Grundler, Ulysses; Hou, George Wei-Shu; Kao, Kai-Yi; Lei, Yeong-Jyi; Liu, Yueh-Feng; Lu, Rong-Shyang; Majumder, Devdatta; Petrakou, Eleni; Tzeng, Yeng-Ming; Wilken, Rachel; Asavapibhop, Burin; Srimanobhas, Norraphat; Suwonjandee, Narumon; Adiguzel, Aytul; Bakirci, Mustafa Numan; Cerci, Salim; Dozen, Candan; Dumanoglu, Isa; Eskut, Eda; Girgis, Semiray; Gokbulut, Gul; Gurpinar, Emine; Hos, Ilknur; Kangal, Evrim Ersin; Kayis Topaksu, Aysel; Onengut, Gulsen; Ozdemir, Kadri; Ozturk, Sertac; Polatoz, Ayse; Sogut, Kenan; Sunar Cerci, Deniz; Tali, Bayram; Topakli, Huseyin; Vergili, Mehmet; Akin, Ilina Vasileva; Bilin, Bugra; Bilmis, Selcuk; Gamsizkan, Halil; Karapinar, Guler; Ocalan, Kadir; Sekmen, Sezen; Surat, Ugur Emrah; Yalvac, Metin; Zeyrek, Mehmet; Gülmez, Erhan; Isildak, Bora; Kaya, Mithat; Kaya, Ozlem; Cankocak, Kerem; Vardarlı, Fuat Ilkehan; Levchuk, Leonid; Sorokin, Pavel; Brooke, James John; Clement, Emyr; Cussans, David; Flacher, Henning; Frazier, Robert; Goldstein, Joel; Grimes, Mark; Heath, Greg P; Heath, Helen F; Jacob, Jeson; Kreczko, Lukasz; Lucas, Chris; Meng, Zhaoxia; Newbold, Dave M; Paramesvaran, Sudarshan; Poll, Anthony; Senkin, Sergey; Smith, Vincent J; Williams, Thomas; Bell, Ken W; Belyaev, Alexander; Brew, Christopher; Brown, Robert M; Cockerill, David JA; Coughlan, John A; Harder, Kristian; Harper, Sam; Olaiya, Emmanuel; Petyt, David; Shepherd-Themistocleous, Claire; Thea, Alessandro; Tomalin, Ian R; Womersley, William John; Worm, Steven; Baber, Mark; Bainbridge, Robert; Buchmuller, Oliver; Burton, Darren; Colling, David; Cripps, Nicholas; Cutajar, Michael; Dauncey, Paul; Davies, Gavin; Della Negra, Michel; Dunne, Patrick; Ferguson, William; Fulcher, Jonathan; Futyan, David; Gilbert, Andrew; Hall, Geoffrey; Iles, Gregory; Jarvis, Martyn; Karapostoli, Georgia; Kenzie, Matthew; Lane, Rebecca; Lucas, Robyn; Lyons, Louis; Magnan, Anne-Marie; Malik, Sarah; Mathias, Bryn; Nash, Jordan; Nikitenko, Alexander; Pela, Joao; Pesaresi, Mark; Petridis, Konstantinos; Raymond, David Mark; Rogerson, Samuel; Rose, Andrew; Seez, Christopher; Sharp, Peter; Tapper, Alexander; Vazquez Acosta, Monica; Virdee, Tejinder; Zenz, Seth Conrad; Cole, Joanne; Hobson, Peter R; Khan, Akram; Kyberd, Paul; Leggat, Duncan; Leslie, Dawn; Martin, William; Reid, Ivan; Symonds, Philip; Teodorescu, Liliana; Turner, Mark; Dittmann, Jay; Hatakeyama, Kenichi; Kasmi, Azeddine; Liu, Hongxuan; Scarborough, Tara; Charaf, Otman; Cooper, Seth; Henderson, Conor; Rumerio, Paolo; Avetisyan, Aram; Bose, Tulika; Fantasia, Cory; Lawson, Philip; Richardson, Clint; Rohlf, James; Sperka, David; St John, Jason; Sulak, Lawrence; Alimena, Juliette; Berry, Edmund; Bhattacharya, Saptaparna; Christopher, Grant; Cutts, David; Demiragli, Zeynep; Dhingra, Nitish; Ferapontov, Alexey; Garabedian, Alex; Heintz, Ulrich; Kukartsev, Gennadiy; Laird, Edward; Landsberg, Greg; Luk, Michael; Narain, Meenakshi; Segala, Michael; Sinthuprasith, Tutanon; Speer, Thomas; Swanson, Joshua; Breedon, Richard; Breto, Guillermo; Calderon De La Barca Sanchez, Manuel; Chauhan, Sushil; Chertok, Maxwell; Conway, John; Conway, Rylan; Cox, Peter Timothy; Erbacher, Robin; Gardner, Michael; Ko, Winston; Lander, Richard; Miceli, Tia; Mulhearn, Michael; Pellett, Dave; Pilot, Justin; Ricci-Tam, Francesca; Searle, Matthew; Shalhout, Shalhout; Smith, John; Squires, Michael; Stolp, Dustin; Tripathi, Mani; Wilbur, Scott; Yohay, Rachel; Cousins, Robert; Everaerts, Pieter; Farrell, Chris; Hauser, Jay; Ignatenko, Mikhail; Rakness, Gregory; Takasugi, Eric; Valuev, Vyacheslav; Weber, Matthias; Babb, John; Burt, Kira; Clare, Robert; Ellison, John Anthony; Gary, J William; Hanson, Gail; Heilman, Jesse; Ivova Rikova, Mirena; Jandir, Pawandeep; Kennedy, Elizabeth; Lacroix, Florent; Liu, Hongliang; Long, Owen Rosser; Luthra, Arun; Malberti, Martina; Nguyen, Harold; Olmedo Negrete, Manuel; Shrinivas, Amithabh; Sumowidagdo, Suharyo; Wimpenny, Stephen; Andrews, Warren; Branson, James G; Cerati, Giuseppe Benedetto; Cittolin, Sergio; D'Agnolo, Raffaele Tito; Evans, David; Holzner, André; Kelley, Ryan; Klein, Daniel; Lebourgeois, Matthew; Letts, James; Macneill, Ian; Olivito, Dominick; Padhi, Sanjay; Palmer, Christopher; Pieri, Marco; Sani, Matteo; Sharma, Vivek; Simon, Sean; Sudano, Elizabeth; Tadel, Matevz; Tu, Yanjun; Vartak, Adish; Welke, Charles; Würthwein, Frank; Yagil, Avraham; Yoo, Jaehyeok; Barge, Derek; Bradmiller-Feld, John; Campagnari, Claudio; Danielson, Thomas; Dishaw, Adam; Flowers, Kristen; Franco Sevilla, Manuel; Geffert, Paul; George, Christopher; Golf, Frank; Gouskos, Loukas; Incandela, Joe; Justus, Christopher; Mccoll, Nickolas; Richman, Jeffrey; Stuart, David; To, Wing; West, Christopher; Apresyan, Artur; Bornheim, Adolf; Bunn, Julian; Chen, Yi; Di Marco, Emanuele; Duarte, Javier; Mott, Alexander; Newman, Harvey B; Pena, Cristian; Rogan, Christopher; Spiropulu, Maria; Timciuc, Vladlen; Wilkinson, Richard; Xie, Si; Zhu, Ren-Yuan; Azzolini, Virginia; Calamba, Aristotle; Carlson, Benjamin; Ferguson, Thomas; Iiyama, Yutaro; Paulini, Manfred; Russ, James; Vogel, Helmut; Vorobiev, Igor; Cumalat, John Perry; Ford, William T; Gaz, Alessandro; Luiggi Lopez, Eduardo; Nauenberg, Uriel; Smith, James; Stenson, Kevin; Ulmer, Keith; Wagner, Stephen Robert; Alexander, James; Chatterjee, Avishek; Chu, Jennifer; Dittmer, Susan; Eggert, Nicholas; Mirman, Nathan; Nicolas Kaufman, Gala; Patterson, Juliet Ritchie; Ryd, Anders; Salvati, Emmanuele; Skinnari, Louise; Sun, Werner; Teo, Wee Don; Thom, Julia; Thompson, Joshua; Tucker, Jordan; Weng, Yao; Winstrom, Lucas; Wittich, Peter; Winn, Dave; Abdullin, Salavat; Albrow, Michael; Anderson, Jacob; Apollinari, Giorgio; Bauerdick, Lothar AT; Beretvas, Andrew; Berryhill, Jeffrey; Bhat, Pushpalatha C; Burkett, Kevin; Butler, Joel Nathan; Cheung, Harry; Chlebana, Frank; Cihangir, Selcuk; Elvira, Victor Daniel; Fisk, Ian; Freeman, Jim; Gao, Yanyan; Gottschalk, Erik; Gray, Lindsey; Green, Dan; Grünendahl, Stefan; Gutsche, Oliver; Hanlon, Jim; Hare, Daryl; Harris, Robert M; Hirschauer, James; Hooberman, Benjamin; Jindariani, Sergo; Johnson, Marvin; Joshi, Umesh; Kaadze, Ketino; Klima, Boaz; Kreis, Benjamin; Kwan, Simon; Linacre, Jacob; Lincoln, Don; Lipton, Ron; Liu, Tiehui; Lykken, Joseph; Maeshima, Kaori; Marraffino, John Michael; Martinez Outschoorn, Verena Ingrid; Maruyama, Sho; Mason, David; McBride, Patricia; Mishra, Kalanand; Mrenna, Stephen; Musienko, Yuri; Nahn, Steve; Newman-Holmes, Catherine; O'Dell, Vivian; Prokofyev, Oleg; Sexton-Kennedy, Elizabeth; Sharma, Seema; Soha, Aron; Spalding, William J; Spiegel, Leonard; Taylor, Lucas; Tkaczyk, Slawek; Tran, Nhan Viet; Uplegger, Lorenzo; Vaandering, Eric Wayne; Vidal, Richard; Whitbeck, Andrew; Whitmore, Juliana; Yang, Fan; Acosta, Darin; Avery, Paul; Bourilkov, Dimitri; Carver, Matthew; Cheng, Tongguang; Curry, David; Das, Souvik; De Gruttola, Michele; Di Giovanni, Gian Piero; Field, Richard D; Fisher, Matthew; Furic, Ivan-Kresimir; Hugon, Justin; Konigsberg, Jacobo; Korytov, Andrey; Kypreos, Theodore; Low, Jia Fu; Matchev, Konstantin; Milenovic, Predrag; Mitselmakher, Guenakh; Muniz, Lana; Rinkevicius, Aurelijus; Shchutska, Lesya; Snowball, Matthew; Yelton, John; Zakaria, Mohammed; Hewamanage, Samantha; Linn, Stephan; Markowitz, Pete; Martinez, German; Rodriguez, Jorge Luis; Adams, Todd; Askew, Andrew; Bochenek, Joseph; Diamond, Brendan; Haas, Jeff; Hagopian, Sharon; Hagopian, Vasken; Johnson, Kurtis F; Prosper, Harrison; Veeraraghavan, Venkatesh; Weinberg, Marc; Baarmand, Marc M; Hohlmann, Marcus; Kalakhety, Himali; Yumiceva, Francisco; Adams, Mark Raymond; Apanasevich, Leonard; Bazterra, Victor Eduardo; Berry, Douglas; Betts, Russell Richard; Bucinskaite, Inga; Cavanaugh, Richard; Evdokimov, Olga; Gauthier, Lucie; Gerber, Cecilia Elena; Hofman, David Jonathan; Khalatyan, Samvel; Kurt, Pelin; Moon, Dong Ho; O'Brien, Christine; Silkworth, Christopher; Turner, Paul; Varelas, Nikos; Albayrak, Elif Asli; Bilki, Burak; Clarida, Warren; Dilsiz, Kamuran; Duru, Firdevs; Haytmyradov, Maksat; Merlo, Jean-Pierre; Mermerkaya, Hamit; Mestvirishvili, Alexi; Moeller, Anthony; Nachtman, Jane; Ogul, Hasan; Onel, Yasar; Ozok, Ferhat; Penzo, Aldo; Rahmat, Rahmat; Sen, Sercan; Tan, Ping; Tiras, Emrah; Wetzel, James; Yetkin, Taylan; Yi, Kai; Barnett, Bruce Arnold; Blumenfeld, Barry; Bolognesi, Sara; Fehling, David; Gritsan, Andrei; Maksimovic, Petar; Martin, Christopher; Swartz, Morris; Baringer, Philip; Bean, Alice; Benelli, Gabriele; Bruner, Christopher; Kenny III, Raymond Patrick; Malek, Magdalena; Murray, Michael; Noonan, Daniel; Sanders, Stephen; Sekaric, Jadranka; Stringer, Robert; Wang, Quan; Wood, Jeffrey Scott; Barfuss, Anne-Fleur; Chakaberia, Irakli; Ivanov, Andrew; Khalil, Sadia; Makouski, Mikhail; Maravin, Yurii; Saini, Lovedeep Kaur; Shrestha, Shruti; Skhirtladze, Nikoloz; Svintradze, Irakli; Gronberg, Jeffrey; Lange, David; Rebassoo, Finn; Wright, Douglas; Baden, Drew; Belloni, Alberto; Calvert, Brian; Eno, Sarah Catherine; Gomez, Jaime; Hadley, Nicholas John; Kellogg, Richard G; Kolberg, Ted; Lu, Ying; Marionneau, Matthieu; Mignerey, Alice; Pedro, Kevin; Skuja, Andris; Tonjes, Marguerite; Tonwar, Suresh C; Apyan, Aram; Barbieri, Richard; Bauer, Gerry; Busza, Wit; Cali, Ivan Amos; Chan, Matthew; Di Matteo, Leonardo; Dutta, Valentina; Gomez Ceballos, Guillelmo; Goncharov, Maxim; Gulhan, Doga; Klute, Markus; Lai, Yue Shi; Lee, Yen-Jie; Levin, Andrew; Luckey, Paul David; Ma, Teng; Paus, Christoph; Ralph, Duncan; Roland, Christof; Roland, Gunther; Stephans, George; Stöckli, Fabian; Sumorok, Konstanty; Velicanu, Dragos; Veverka, Jan; Wyslouch, Bolek; Yang, Mingming; Zanetti, Marco; Zhukova, Victoria; Dahmes, Bryan; Gude, Alexander; Kao, Shih-Chuan; Klapoetke, Kevin; Kubota, Yuichi; Mans, Jeremy; Pastika, Nathaniel; Rusack, Roger; Singovsky, Alexander; Tambe, Norbert; Turkewitz, Jared; Acosta, John Gabriel; Oliveros, Sandra; Avdeeva, Ekaterina; Bloom, Kenneth; Bose, Suvadeep; Claes, Daniel R; Dominguez, Aaron; Gonzalez Suarez, Rebeca; Keller, Jason; Knowlton, Dan; Kravchenko, Ilya; Lazo-Flores, Jose; Malik, Sudhir; Meier, Frank; Snow, Gregory R; Dolen, James; Godshalk, Andrew; Iashvili, Ia; Kharchilava, Avto; Kumar, Ashish; Rappoccio, Salvatore; Alverson, George; Barberis, Emanuela; Baumgartel, Darin; Chasco, Matthew; Haley, Joseph; Massironi, Andrea; Morse, David Michael; Nash, David; Orimoto, Toyoko; Trocino, Daniele; Wang, Ren-Jie; Wood, Darien; Zhang, Jinzhong; Hahn, Kristan Allan; Kubik, Andrew; Mucia, Nicholas; Odell, Nathaniel; Pollack, Brian; Pozdnyakov, Andrey; Schmitt, Michael Henry; Stoynev, Stoyan; Sung, Kevin; Velasco, Mayda; Won, Steven; Brinkerhoff, Andrew; Chan, Kwok Ming; Drozdetskiy, Alexey; Hildreth, Michael; Jessop, Colin; Karmgard, Daniel John; Kellams, Nathan; Lannon, Kevin; Luo, Wuming; Lynch, Sean; Marinelli, Nancy; Pearson, Tessa; Planer, Michael; Ruchti, Randy; Valls, Nil; Wayne, Mitchell; Wolf, Matthias; Woodard, Anna; Antonelli, Louis; Brinson, Jessica; Bylsma, Ben; Durkin, Lloyd Stanley; Flowers, Sean; Hill, Christopher; Hughes, Richard; Kotov, Khristian; Ling, Ta-Yung; Puigh, Darren; Rodenburg, Marissa; Smith, Geoffrey; Winer, Brian L; Wolfe, Homer; Wulsin, Howard Wells; Driga, Olga; Elmer, Peter; Hebda, Philip; Hunt, Adam; Koay, Sue Ann; Lujan, Paul; Marlow, Daniel; Medvedeva, Tatiana; Mooney, Michael; Olsen, James; Piroué, Pierre; Quan, Xiaohang; Saka, Halil; Stickland, David; Tully, Christopher; Werner, Jeremy Scott; Zuranski, Andrzej; Brownson, Eric; Mendez, Hector; Ramirez Vargas, Juan Eduardo; Barnes, Virgil E; Benedetti, Daniele; Bolla, Gino; Bortoletto, Daniela; De Mattia, Marco; Hu, Zhen; Jha, Manoj; Jones, Matthew; Jung, Kurt; Kress, Matthew; Leonardo, Nuno; Lopes Pegna, David; Maroussov, Vassili; Merkel, Petra; Miller, David Harry; Neumeister, Norbert; Radburn-Smith, Benjamin Charles; Shi, Xin; Shipsey, Ian; Silvers, David; Svyatkovskiy, Alexey; Wang, Fuqiang; Xie, Wei; Xu, Lingshan; Yoo, Hwi Dong; Zablocki, Jakub; Zheng, Yu; Parashar, Neeti; Stupak, John; Adair, Antony; Akgun, Bora; Ecklund, Karl Matthew; Geurts, Frank JM; Li, Wei; Michlin, Benjamin; Padley, Brian Paul; Redjimi, Radia; Roberts, Jay; Zabel, James; Betchart, Burton; Bodek, Arie; Covarelli, Roberto; de Barbaro, Pawel; Demina, Regina; Eshaq, Yossof; Ferbel, Thomas; Garcia-Bellido, Aran; Goldenzweig, Pablo; Han, Jiyeon; Harel, Amnon; Khukhunaishvili, Aleko; Petrillo, Gianluca; Vishnevskiy, Dmitry; Ciesielski, Robert; Demortier, Luc; Goulianos, Konstantin; Lungu, Gheorghe; Mesropian, Christina; Arora, Sanjay; Barker, Anthony; Chou, John Paul; Contreras-Campana, Christian; Contreras-Campana, Emmanuel; Duggan, Daniel; Ferencek, Dinko; Gershtein, Yuri; Gray, Richard; Halkiadakis, Eva; Hidas, Dean; Kaplan, Steven; Lath, Amitabh; Panwalkar, Shruti; Park, Michael; Patel, Rishi; Salur, Sevil; Schnetzer, Steve; Somalwar, Sunil; Stone, Robert; Thomas, Scott; Thomassen, Peter; Walker, Matthew; Rose, Keith; Spanier, Stefan; York, Andrew; Bouhali, Othmane; Castaneda Hernandez, Alfredo; Eusebi, Ricardo; Flanagan, Will; Gilmore, Jason; Kamon, Teruki; Khotilovich, Vadim; Krutelyov, Vyacheslav; Montalvo, Roy; Osipenkov, Ilya; Pakhotin, Yuriy; Perloff, Alexx; Roe, Jeffrey; Rose, Anthony; Safonov, Alexei; Sakuma, Tai; Suarez, Indara; Tatarinov, Aysen; Akchurin, Nural; Cowden, Christopher; Damgov, Jordan; Dragoiu, Cosmin; Dudero, Phillip Russell; Faulkner, James; Kovitanggoon, Kittikul; Kunori, Shuichi; Lee, Sung Won; Libeiro, Terence; Volobouev, Igor; Appelt, Eric; Delannoy, Andrés G; Greene, Senta; Gurrola, Alfredo; Johns, Willard; Maguire, Charles; Mao, Yaxian; Melo, Andrew; Sharma, Monika; Sheldon, Paul; Snook, Benjamin; Tuo, Shengquan; Velkovska, Julia; Arenton, Michael Wayne; Boutle, Sarah; Cox, Bradley; Francis, Brian; Goodell, Joseph; Hirosky, Robert; Ledovskoy, Alexander; Li, Hengne; Lin, Chuanzhe; Neu, Christopher; Wood, John; Clarke, Christopher; Harr, Robert; Karchin, Paul Edmund; Kottachchi Kankanamge Don, Chamath; Lamichhane, Pramod; Sturdy, Jared; Belknap, Donald; Carlsmith, Duncan; Cepeda, Maria; Dasu, Sridhara; Dodd, Laura; Duric, Senka; Friis, Evan; Hall-Wilton, Richard; Herndon, Matthew; Hervé, Alain; Klabbers, Pamela; Lanaro, Armando; Lazaridis, Christos; Levine, Aaron; Loveless, Richard; Mohapatra, Ajit; Ojalvo, Isabel; Perry, Thomas; Pierro, Giuseppe Antonio; Polese, Giovanni; Ross, Ian; Sarangi, Tapas; Savin, Alexander; Smith, Wesley H; Taylor, Devin; Vuosalo, Carl; Woods, Nathaniel

2015-04-30

The first measurement of the cross section ratio $\\sigma_\\mathrm{ t \\bar{t} b \\bar{b}} / \\sigma_\\mathrm{ t \\bar{t} jj }$ is presented using a data sample corresponding to an integrated luminosity of 19.6 fb$^{-1}$ collected in pp collisions at $\\sqrt{s}$ = 8 TeV with the CMS detector at the LHC. Events with two leptons ($\\mathrm{e}$ or $\\mu$) and four reconstructed jets, including two identified as b quark jets, in the final state are selected. The ratio is determined for a minimum jet transverse momentum $p_\\mathrm{T}$ of both 20 and 40 GeV/$c$. The measured ratio is 0.022 $\\pm$ 0.003 (stat) $\\pm$ 0.005 (syst) for $p_\\mathrm{T}$ greater than 20 GeV/$c$. The absolute cross sections $\\sigma_\\mathrm{ t \\bar{t} b \\bar{b}}$ and $\\sigma_\\mathrm{ t \\bar{t} jj }$ are also measured. The measured ratio for $p_\\mathrm{T}$ greater than 40 GeV/$c$ is compatible with a theoretical quantum chromodynamics calculation at next-to-leading order.

Microstructural characteristics and effects of TC4 titanium alloy processed by using friction stir welding

Directory of Open Access Journals (Sweden)

Bo LI

2016-02-01

Full Text Available Friction stir welding technique is used for the processing of TC4 titanium alloy under protective atmosphere, and it results with good formability. The research focues on the evolution mechanisms of α+β dual phase microstructure in stirred zone and the effects of processing parameters on structures hardness. The results show that with optimized technological parameters, stir zone structure experiences the α/β transformation, and finally changes to the α+β duplex structure which is based on the β phase. After mixing head leaves and the structure cools, the precipitated lamellar α phase is among and/or within-regions. Grain refining of α+β dual phase is obvious. The shortened α/β lamellar spacing distance may improve the strengthening effect of the α+β duplex phase and enhance the hardness of the stir zone. The increasing of the tool rotation speed could coarsen β-regions, while the increasing of the travel speed could help reduce the α phase ratio and generate needle-type Martensites.

Characterizing bars in low surface brightness disc galaxies

Science.gov (United States)

Peters, Wesley; Kuzio de Naray, Rachel

2018-05-01

In this paper, we use B-band, I-band, and 3.6 μm azimuthal light profiles of four low surface brightness galaxies (LSBs; UGC 628, F568-1, F568-3, F563-V2) to characterize three bar parameters: length, strength, and corotation radius. We employ three techniques to measure the radius of the bars, including a new method using the azimuthal light profiles. We find comparable bar radii between the I-band and 3.6 μm for all four galaxies when using our azimuthal light profile method, and that our bar lengths are comparable to those in high surface brightness galaxies (HSBs). In addition, we find the bar strengths for our galaxies to be smaller than those for HSBs. Finally, we use Fourier transforms of the B-band, I-band, and 3.6 μm images to characterize the bars as either `fast' or `slow' by measuring the corotation radius via phase profiles. When using the B- and I-band phase crossings, we find three of our galaxies have faster than expected relative bar pattern speeds for galaxies expected to be embedded in centrally dense cold dark matter haloes. When using the B-band and 3.6 μm phase crossings, we find more ambiguous results, although the relative bar pattern speeds are still faster than expected. Since we find a very slow bar in F563-V2, we are confident that we are able to differentiate between fast and slow bars. Finally, we find no relation between bar strength and relative bar pattern speed when comparing our LSBs to HSBs.

Colosed-Loop Control of the Thermal Stir Welding Process to Enable Rapid Process/Ppart Qualification, Phase I

Data.gov (United States)

National Aeronautics and Space Administration — Thermal Stir Welding (TSW) provides advancement over the more conventional Friction Stir Welding (C-FSW) process because it separates the primary processes variables...

Closed-Loop Control of the Thermal Stir Welding Process to Enable Rapid Process/Part Qualification, Phase II

Data.gov (United States)

National Aeronautics and Space Administration — Thermal Stir Welding (TSW) provides advancement over the more conventional Friction Stir Welding (C-FSW) process because it separates the primary processes variables...

Analysis of lime-slurry stirred tank carbonation reactor

International Nuclear Information System (INIS)

McAleese, J.P.; Belt, B.A.; Datesh, J.R.; Shaeffer, M.C.

1977-01-01

Gas residence time distributions were determined for a stirred tank carbonation reactor. Empirical correlations for the first and second moments of the residence time distribution (RTD) curves as functions of flow rates and impeller speeds were obtained. Decontamination factors for 85 Kr were measured

Fungi solubilisation of low rank coal: performances of stirred tank, fluidised bed and packed bed reactors

CSIR Research Space (South Africa)

Oboirien, BO

2013-02-01

Full Text Available Coal biosolubilisation was investigated in stirred tank reactor, fluidised bed and fixed bed bioreactors with a view to highlight the advantages and shortcomings of each of these reactor configurations. The stirred aerated bioreactor and fluidised...

The Effect of Vibration during Friction Stir Welding on Corrosion Behavior, Mechanical Properties, and Machining Characteristics of Stir Zone

Directory of Open Access Journals (Sweden)

Sajad Fouladi

2017-10-01

Full Text Available Different methods have been applied to refine various characteristics of the zone (or nugget obtained by friction stir welding (FSW. In the current research, joining components are vibrated normal to the weld line during FSW to refine the zone microstructure. This process is described as friction stir vibration welding (FSVW. The effect of FSVW on mechanical properties, corrosion behavior, and machining characteristics of the zone are investigated. Al5052 alloy specimens are welded using FSW and FSVW processes and their different characteristics are compared and discussed. The results show that the strength and ductility of the welded parts increase when the vibration is applied. The outcomes also show that corrosion resistance of the nugget for FSV-welded specimens is lower than FS welded samples, and machining force of the former specimens is higher than the latter ones. These are related to smaller grain size in the zone of FSV-welded specimens compared to FS welded parts. Smaller grain size leads to a greater volume fraction of grain boundaries and, correspondingly, higher strength and hardness, as well as lower corrosion resistance.

Biotransformation of ferulic acid to vanillin in the packed bed-stirred fermentors.

Science.gov (United States)

Yan, Lei; Chen, Peng; Zhang, Shuang; Li, Suyue; Yan, Xiaojuan; Wang, Ningbo; Liang, Ning; Li, Hongyu

2016-10-06

We performed the biotransformation of ferulic acid to vanillin using Bacillus subtilis (B. subtilis) in the stirring packed-bed reactors filled with carbon fiber textiles (CFT). Scanning electron microscope (SEM), HPLC, qRT-PCR and ATP assay indicated that vanillin biotransformation is tightly related to cell growth, cellar activity and the extent of biofilm formation. The biotransformation was affected by hydraulic retention time (HRT), temperature, initial pH, stirring speed and ferulic acid concentration, and the maximum vanillin production was obtained at 20 h, 35 °C, 9.0, 200 rpm, 1.5 g/L, respectively. Repeated batch biotransformation performed under this optimized condition showed that the maximum productivity (0.047 g/L/h) and molar yield (60.43%) achieved in immobilized cell system were 1.84 and 3.61 folds higher than those achieved in free cell system. Therefore, the stirring reactor packed with CFT carrier biofilm formed by B. subtilis represented a valid biocatalytic system for the production of vanillin.

Inverse Thermal Analysis of Ti-6Al-4V Friction Stir Welds Using Numerical-Analytical Basis Functions with Pseudo-Advection

Science.gov (United States)

Lambrakos, S. G.

2018-04-01

Inverse thermal analysis of Ti-6Al-4V friction stir welds is presented that demonstrates application of a methodology using numerical-analytical basis functions and temperature-field constraint conditions. This analysis provides parametric representation of friction-stir-weld temperature histories that can be adopted as input data to computational procedures for prediction of solid-state phase transformations and mechanical response. These parameterized temperature histories can be used for inverse thermal analysis of friction stir welds having process conditions similar those considered here. Case studies are presented for inverse thermal analysis of friction stir welds that use three-dimensional constraint conditions on calculated temperature fields, which are associated with experimentally measured transformation boundaries and weld-stir-zone cross sections.

The Concept of Electrically Assisted Friction Stir Welding (EAFSW) and Application to the Processing of Various Metals

National Research Council Canada - National Science Library

Ferrando, William A

2008-01-01

This report introduces a novel variant of conventional friction stir welding (FSW). Since 1991, friction stir welding provides an alternative to arc welding as a metal joining method in numerous applications...

Tensile behavior of friction stir welded AA 6061-T4 aluminum alloy joints

International Nuclear Information System (INIS)

Heidarzadeh, A.; Khodaverdizadeh, H.; Mahmoudi, A.; Nazari, E.

2012-01-01

Highlights: ► Range of parameters for defect-free friction stir welded AA 6061-T4 was reached. ► A model was developed for predicting UTS and EL of friction stir welded AA 6061-T4. ► The maximum values of UTS and EL of joints were estimated by developed model. ► The optimum values of FSW process parameters were determined. -- Abstract: In this investigation response surface methodology based on a central composite rotatable design with three parameters, five levels and 20 runs, was used to develop a mathematical model predicting the tensile properties of friction stir welded AA 6061-T4 aluminum alloy joints at 95% confidence level. The three welding parameters considered were tool rotational speed, welding speed and axial force. Analysis of variance was applied to validate the predicted model. Microstructural characterization and fractography of joints were examined using optical and scanning electron microscopes. Also, the effects of the welding parameters on tensile properties of friction stir welded joints were analyzed in detail. The results showed that the optimum parameters to get a maximum of tensile strength were 920 rev/min, 78 mm/min and 7.2 kN, where the maximum of tensile elongation was obtained at 1300 rev/min, 60 mm/min and 8 kN.

21 CFR 610.67 - Bar code label requirements.

Science.gov (United States)

2010-04-01

... 21 Food and Drugs 7 2010-04-01 2010-04-01 false Bar code label requirements. 610.67 Section 610.67...) BIOLOGICS GENERAL BIOLOGICAL PRODUCTS STANDARDS Labeling Standards § 610.67 Bar code label requirements. Biological products must comply with the bar code requirements at § 201.25 of this chapter. However, the bar...

Friction stir welding of 6061 aluminium alloy

International Nuclear Information System (INIS)

Abdel Rahman, M.A.M.S.

2009-01-01

6061 AA (Al-Mg-Si alloy) has gathered wide acceptance in the fabrication of light weight structures requiring a high strength-to-weight ratio and good corrosion resistance such as marine frames, pipelines, storage tanks, and aircraft components [1]. It is also used for the manufacturing of fuel elements in the nuclear research reactors. Compared to many of the fusion welding processes that are routinely used for joining structural alloys, friction stir welding (FSW) is a solid state joining process in which the material that is being welded is not melted and recast [2]. The welding parameters such as tool rotational speed, welding traverse speed, and tool profile play a major role in deciding the weld quality. Several FSW tools (differ from each other in pin angle, shoulder diameter, and shoulder concavity) have been used to fabricate a number of joints in order to obtain a tool with which a sound weld can be produced. It was found that the FSW tool with tapered cone pin, concave shoulder, and shoulder diameter equal to four times the welded plate thickness is suitable to produce a sound weld. The effect of the traverse speed on the global and local tensile properties of friction stir welded joints has been investigated in the 6061-T6 AA. The global tensile properties of the FSW joints were improved with increasing the traverse speed at constant rotation rate. It is found that the global tensile strength of the FSW joint is limited by the local tensile strength of the nearest region to the weld center at which the cross section is composed mainly of the HAZ. The effect of the initial butt surface on the formation of the zigzag line on the tensile properties of the welds was examined by using three types of welding samples differ in the preparation of the initial butt surface. The first type of samples welded without removing the oxide layer from the initial butt surface (uncleaned butt surfaces joint). In the second type of samples the oxide layer was removed from

Magnetic fields in barred galaxies I. The atlas

CERN Document Server

Beck, R; Ehle, M; Harnett, J I; Haynes, R F; Shukurov, A M; Sokoloff, D D; Thierbach, M

2002-01-01

The total and polarized radio continuum emission of 20 barred galaxies was observed with the Very Large Array (VLA) at 3, 6, 18 and 22 cm and with the Australia Telescope Compact Array (ATCA) at 6 cm and 13 cm. Maps at 30 arcsec angular resolution are presented here. Polarized emission (and therefore a large-scale regular magnetic field) was detected in 17 galaxies. Most galaxies of our sample are similar to non-barred galaxies with respect to the radio/far-infrared flux correlation and equipartition strength of the total magnetic field. Galaxies with highly elongated bars are not always radio-bright. We discuss the correlation of radio properties with the aspect ratio of the bar and other measures of the bar strength. We introduce a new measure of the bar strength, \\Lambda, related to the quadrupole moment of the bar's gravitational potential. The radio surface brightness I of the barred galaxies in our sample is correlated with \\Lambda, I \\propto \\Lambda^0.4+/-0.1, and thus is highest in galaxies with a lon...

Recent developments and future trends in solid phase microextraction techniques towards green analytical chemistry.

Science.gov (United States)

Spietelun, Agata; Marcinkowski, Łukasz; de la Guardia, Miguel; Namieśnik, Jacek

2013-12-20

Solid phase microextraction find increasing applications in the sample preparation step before chromatographic determination of analytes in samples with a complex composition. These techniques allow for integrating several operations, such as sample collection, extraction, analyte enrichment above the detection limit of a given measuring instrument and the isolation of analytes from sample matrix. In this work the information about novel methodological and instrumental solutions in relation to different variants of solid phase extraction techniques, solid-phase microextraction (SPME), stir bar sorptive extraction (SBSE) and magnetic solid phase extraction (MSPE) is presented, including practical applications of these techniques and a critical discussion about their advantages and disadvantages. The proposed solutions fulfill the requirements resulting from the concept of sustainable development, and specifically from the implementation of green chemistry principles in analytical laboratories. Therefore, particular attention was paid to the description of possible uses of novel, selective stationary phases in extraction techniques, inter alia, polymeric ionic liquids, carbon nanotubes, and silica- and carbon-based sorbents. The methodological solutions, together with properly matched sampling devices for collecting analytes from samples with varying matrix composition, enable us to reduce the number of errors during the sample preparation prior to chromatographic analysis as well as to limit the negative impact of this analytical step on the natural environment and the health of laboratory employees. Copyright © 2013 Elsevier B.V. All rights reserved.

Bound volatile precursors in genotypes in the pedigree of 'Marion' blackberry (Rubus sp.).

Science.gov (United States)

Du, Xiaofen; Finn, Chad E; Qian, Michael C

2010-03-24

Glycosidically bound volatiles and precursors in genotypes representing the pedigree for 'Marion' blackberry were investigated over two growing seasons. The volatile precursors were isolated using a C18 solid-phase extraction column. After enzymatic hydrolysis, the released volatiles were analyzed using stir bar sorptive extraction gas chromatography-mass spectrometry (GC-MS) and direct microvial insert thermal desorption GC-MS. The most abundant volatile precursors in the genotypes were alcohols, followed by shikimic acid derivatives. High amounts of furanone glycosides were also detected, while norisoprenoids only existed in a small amount in blackberries. The volatile precursor composition in the genotypes in the 'Marion' pedigree was very similar to their free volatile distribution. 'Logan' and 'Olallie' predominantly had bound norisoprenoids. Wild 'Himalaya' predominated with terpene alcohol and furaneol glycosides, whereas 'Santiam' and 'Chehalem' contained a high level of terpene alcohol glycosides. A similar inheritance pattern was also observed for some volatile precursors in the genotypes in the 'Marion' pedigree. A high content of linalool, hydroxylinalool, and alpha-ionol glycosides in 'Olallie' and a low content in 'Chehalem' resulted in a moderate level in their offspring 'Marion', while a low content of (E)-linalool oxide precursor in 'Olallie' and a high content in 'Chehalem' also resulted in a moderate level in 'Marion'. However, the concentration of furaneol glycosides in 'Marion' exceeded that of its two parents.

Defect Detectability Improvement for Conventional Friction Stir Welds

Science.gov (United States)

Hill, Chris

2013-01-01

This research was conducted to evaluate the effects of defect detectability via phased array ultrasound technology in conventional friction stir welds by comparing conventionally prepped post weld surfaces to a machined surface finish. A machined surface is hypothesized to improve defect detectability and increase material strength.

Engineered Alloy Structures by Friction Stir Reaction Processing, Phase I

Data.gov (United States)

National Aeronautics and Space Administration — This SBIR Phase I effort examines the feasibility of an innovative surface modification technology incorporating friction stir reaction processing for producing...

Rapid monitoring of residual UV-stabilizers in seawater samples from beaches using fabric phase sorptive extraction and UHPLC-MS/MS.

Science.gov (United States)

García-Guerra, Romualdo B; Montesdeoca-Esponda, Sarah; Sosa-Ferrera, Zoraida; Kabir, Abuzar; Furton, Kenneth G; Santana-Rodríguez, José Juan

2016-12-01

Benzotriazole UV stabilizers (BUVSs) are a group of compounds added to personal care products such as sunscreens, hair dyes, make up formulations, soaps or shampoos, among others. Direct input from beaches or another aquatic recreational areas is the main source of BUVSs incorporation to the environment, where they can be mutagenic, toxic, pseudo-persistent and bioaccumulative. Due to the low levels of concentration of these compounds found in environmental samples, an extraction process is required prior to their determination. Fabric phase sorptive extraction integrates the advanced material properties of sol-gel hybrid inorganic-organic sorbents with flexible, permeable and functionally active fabric substrates, being a highly responsive, efficient and cheap device that also can be reused. In this paper, we applied fabric phase sorptive extraction methodology to analyse six BUVSs in twenty-four seawater samples from different coastal areas of Gran Canaria Island (Spain). It was coupled to ultra high performance liquid chromatography with tandem mass spectrometry in order to achieve a fast, reliable and sensitive separation and determination of the analytes from different simple matrices, regardless of its complexity and composition. Under the optimum conditions, the proposed method provided enrichment factors of 25 times with limits of detection from 1.06 to 8.96 ng L -1 and limits of quantification from 3.54 to 29.9 ng L -1 for the analytes under study in spiked samples. Intra and inter-day relative standard deviations were between 3.97 and 20.8% for all compounds. The application of the optimized methodology to non-spiked seawater samples allows detecting and quantifying the UV 360 in the range from 41.12 to 544.9 ng L -1 . Copyright © 2016 Elsevier Ltd. All rights reserved.

Anti-vibration bars for nuclear steam generators

International Nuclear Information System (INIS)

Gowda, B.V.; Wilson, R.M.; Wepfer, R.M.

1986-01-01

A method of installing tubular anti-vibration bars into a tube bundle of a steam generator wherein the tube bundle comprises rows of tubes, with the anti-vibration bars received between adjacent rows of the tube bundle for stabilizing the tubes against vibration. The anti-vibration bars are first inserted between adjacent rows of the tube bundle and a pressurized fluid is then introduced into the anti-vibration bars which are thus expanded into contact with the tubes of the adjacent rows for support

Expandable antivibration bar for a steam generator

International Nuclear Information System (INIS)

Lagally, H.O.

1987-01-01

This patent describes a steam generator for a nuclear power plant comprising a shell, a plurality of tubes having a U-shaped configuration arranged in successive columns within the shell. The tubes are adapted to heat feedwater flowing around the outside of the tubes by the flow of hot reactor coolant within the tubes, and antivibration bars any vibrations of the tubes as a result of steam between the columns of tubes. The improvement described here comprises means for varying the thickness of the antivibration bars to fit substantially the actual space between the columns of tubes comprising first and second bars, with at least one bar being movable, and with at least one mating inclined surface between the first and second bars

Friction Stir Welding of Dissimilar Al/Al and Al/Non-Al Alloys: A Review

Science.gov (United States)

Wang, Xiangbin; Pan, Yi; Lados, Diana A.

2018-05-01

Friction stir welding is a solid-state welding technique that has many advantages over traditional fusion welding, and has been widely adopted in the aerospace and automotive industries. This article reviews research developments in friction stir welding of dissimilar alloys systems, including combinations of aluminum alloys with Mg alloys, Cu, and steel. Microstructural evolution, hardness, tensile and fatigue properties, residual stresses, and corrosion behavior of dissimilar welds will be reported. The effects of processing parameters such as tool rotation and traverse speeds, tool position, material position, and tool geometry on the weld quality are also presented. Discussions on future research directions in friction stir welding will also be provided in the context of existing literature and future high-integrity applications.

Tensile Properties of Friction Stir Welded Joints of AA 2024-T6 Alloy at Different Welding Speeds

Science.gov (United States)

Avula, Dhananjayulu; Devuri, Venkateswarlu; Cheepu, Muralimohan; Dwivedi, Dheerendra Kumar

2018-03-01

The influence of welding speed on the friction stir welded joint properties of hardness, tensile properties, defects and microstructure characterization are studied in the present study. The friction stir welding was conducted on AA2014-T6 heat treated alloy with 5 mm thickness plate in butt joint configuration. The welding speed was varied from 8 mm/min to 120 mm/min at the fixed travel speed and load conditions. It is observed that the welding speeds at higher rate with wide range can be possible to weld this alloy at higher rates of tool revolution suggesting that the inherent capability of friction stir welding technique for aluminum 2014 alloys. The strength of the joints gradually increases with enhancing of welding speed. The micro structural observations exhibited the formation of equiaxed grains in the stir zone and slightly in the thermo-mechanically affected zone. In addition, the size of the grains decreases with increase in welding speed owing to the presence of low heat input. Hence the hardness of the joints slightly increased in the stir zones over the other zones of the weld nugget. The joint strength initially increases with the welding speed and starts to decreases after reaching to the maximum value. The relationship between the welding conditions and friction stir welded joint properties has been discussed.

The Effect of Friction Stir Welding on Corrosion Behavior of Ti-6Al-4V

Science.gov (United States)

Nasresfahani, Ali Reza; Soltanipur, Abdol Reza; Farmanesh, Khosro; Ghasemi, Ali

2017-09-01

Fusion welding can deteriorate corrosion behavior of Ti-6Al-4V alloy. However, the use of friction stir welding leads to a more appropriate corrosion resistance. In this study, the corrosion resistance of welded zones of Ti-6Al-4V alloy using friction stir welding technique is evaluated. For these purposes, the study of structural characteristics using SEM and FESEM equipped with EDS micro-analyses was conducted. Micro-hardness test was also employed to estimate the hardness of welded zones. Corrosion behavior was investigated by a potentiostat instrument. SEM micrographs, EDS and XRD analyses confirmed non-uniformity of chemical composition within the welded zones. The results reveal that the stir zone contains typical alpha and prior beta phases. Nevertheless, thermomechanical zone included equiaxed and bimodal lamellae structure. Furthermore, the presence of different types of phases and microstructure in the thermomechanical zone led to reduced corrosion resistance. The corresponding values of corrosion current density in the stir zone, thermomechanical zone and base metal were 0.048, 0.55 and 0.032 µA, respectively. Corresponding corrosion potential for these zones was estimated as -207, -110 and -157 mV. Evidently, the results show that corrosion resistance of thermomechanical zone is less than that of the stir zone and both zones have lower value than the base metal.

Low energy bar pp physics

International Nuclear Information System (INIS)

Amsler, C.; Crowe, K.

1989-02-01

A detailed investigation of proton-antiproton interactions at low energy has become feasible with the commissioning of the LEAR facility in 1983. We shall shortly review the status of bar pp annihilation at rest and the physics motivations for second generation experiments with the Crystal Barrel detector. This type of detector would be adequate for the study of both Kp and bar pp interactions on an extracted beam of the KAON Factory. We shall conclude with a few remarks on the physics opportunities with bar p's at the KAON Factory which, in our opinion, will not be covered by the present LEAR facility. 11 refs., 10 figs., 2 tabs

A Preliminary Study on Detecting Fake Gold Bars Using Prompt Gamma Activation Analysis: Simulation of Neutron Transmission in Gold Bar

Energy Technology Data Exchange (ETDEWEB)

Lee, K. M.; Sun, G. M. [KAERI, Daejeon (Korea, Republic of)

2016-05-15

The purpose of this study is to develop fake gold bar detecting method by using Prompt-gamma activation analysis (PGAA) facility at the Korea Atomic Energy Research Institute (KAERI). PGAA is an established nuclear analytical technique for non-destructive determination of elemental and isotopic compositions. For a preliminary study on detecting fake gold bar, Monte Carlo simulation of neutron transmission in gold bar was conducted and the possibility for detecting fake gold bar was confirmed. Under the gold bullion standard, it guaranteed the government would redeem any amount of currency for its value in gold. After the gold bullion standard ended, gold bars have been the target for investment as ever. But it is well known that fake gold bar exist in the gold market. This cannot be identified easily without performing a testing as it has the same appearance as the pure gold bar. In order to avoid the trading of fake gold bar in the market, they should be monitored thoroughly. Although the transmissivity of cold neutrons are low comparing that of thermal neutrons, the slower neutrons are more apt to be absorbed in a target, and can increase the prompt gamma emission rate. Also the flux of both thermal and cold neutron beam is high enough to activate thick target. If the neutron beam is irradiated on the front and the reverse side of gold bar, all insides of it can be detected.

A Preliminary Study on Detecting Fake Gold Bars Using Prompt Gamma Activation Analysis: Simulation of Neutron Transmission in Gold Bar

International Nuclear Information System (INIS)

Lee, K. M.; Sun, G. M.

2016-01-01

The purpose of this study is to develop fake gold bar detecting method by using Prompt-gamma activation analysis (PGAA) facility at the Korea Atomic Energy Research Institute (KAERI). PGAA is an established nuclear analytical technique for non-destructive determination of elemental and isotopic compositions. For a preliminary study on detecting fake gold bar, Monte Carlo simulation of neutron transmission in gold bar was conducted and the possibility for detecting fake gold bar was confirmed. Under the gold bullion standard, it guaranteed the government would redeem any amount of currency for its value in gold. After the gold bullion standard ended, gold bars have been the target for investment as ever. But it is well known that fake gold bar exist in the gold market. This cannot be identified easily without performing a testing as it has the same appearance as the pure gold bar. In order to avoid the trading of fake gold bar in the market, they should be monitored thoroughly. Although the transmissivity of cold neutrons are low comparing that of thermal neutrons, the slower neutrons are more apt to be absorbed in a target, and can increase the prompt gamma emission rate. Also the flux of both thermal and cold neutron beam is high enough to activate thick target. If the neutron beam is irradiated on the front and the reverse side of gold bar, all insides of it can be detected

21 CFR 886.5800 - Ophthalmic bar reader.

Science.gov (United States)

2010-04-01

... 21 Food and Drugs 8 2010-04-01 2010-04-01 false Ophthalmic bar reader. 886.5800 Section 886.5800...) MEDICAL DEVICES OPHTHALMIC DEVICES Therapeutic Devices § 886.5800 Ophthalmic bar reader. (a) Identification. An ophthalmic bar reader is a device that consists of a magnifying lens intended for use by a...

Effect of stirring on striae in glass melts

DEFF Research Database (Denmark)

Jensen, Martin; Yue, Yuanzheng

2012-01-01

Chemical striae have often negative effect on the glass properties, and hence, elimination of striae has been a key issue in glass science and technology. To produce highly homogeneous glasses, it is necessary to stir melts during the melting process. To explore the physical origin of the stria...

Simulation of MILD combustion using Perfectly Stirred Reactor model

KAUST Repository

Chen, Z.; Vanteru, Mahendra Reddy; Ruan, S.; Doan, N. A K; Roberts, William L.; Swaminathan, N.

2016-01-01

A simple model based on a Perfectly Stirred Reactor (PSR) is proposed for moderate or intense low-oxygen dilution (MILD) combustion. The PSR calculation is performed covering the entire flammability range and the tabulated chemistry approach is used

Deciphering the BAR code of membrane modulators.

Science.gov (United States)

Salzer, Ulrich; Kostan, Julius; Djinović-Carugo, Kristina

2017-07-01

The BAR domain is the eponymous domain of the "BAR-domain protein superfamily", a large and diverse set of mostly multi-domain proteins that play eminent roles at the membrane cytoskeleton interface. BAR domain homodimers are the functional units that peripherally associate with lipid membranes and are involved in membrane sculpting activities. Differences in their intrinsic curvatures and lipid-binding properties account for a large variety in membrane modulating properties. Membrane activities of BAR domains are further modified and regulated by intramolecular or inter-subunit domains, by intermolecular protein interactions, and by posttranslational modifications. Rather than providing detailed cell biological information on single members of this superfamily, this review focuses on biochemical, biophysical, and structural aspects and on recent findings that paradigmatically promote our understanding of processes driven and modulated by BAR domains.

Influence of the weighing bar position in vessel on measurement of cement’s particle size distribution by using the buoyancy weighing-bar method

Science.gov (United States)

Tambun, R.; Sihombing, R. O.; Simanjuntak, A.; Hanum, F.

2018-02-01

The buoyancy weighing-bar method is a new simple and cost-effective method to determine the particle size distribution both settling and floating particle. In this method, the density change in a suspension due to particle migration is measured by weighing buoyancy against a weighing-bar hung in the suspension, and then the particle size distribution is calculated using the length of the bar and the time-course change in the mass of the bar. The apparatus of this method consists of a weighing-bar and an analytical balance with a hook for under-floor weighing. The weighing bar is used to detect the density change in suspension. In this study we investigate the influences of position of weighing bar in vessel on settling particle size distribution measurements of cement by using the buoyancy weighing-bar method. The vessel used in this experiment is graduated cylinder with the diameter of 65 mm and the position of weighing bar is in center and off center of vessel. The diameter of weighing bar in this experiment is 10 mm, and the kerosene is used as a dispersion liquids. The results obtained show that the positions of weighing bar in vessel have no significant effect on determination the cement’s particle size distribution by using buoyancy weighing-bar method, and the results obtained are comparable to those measured by using settling balance method.

Numerical Simulations of the Kolsky Compression Bar Test

Energy Technology Data Exchange (ETDEWEB)

Corona, Edmundo [Sandia National Lab. (SNL-NM), Albuquerque, NM (United States)

2015-10-01

The Kolsky compression bar, or split Hopkinson pressure bar (SHPB), is an ex- perimental apparatus used to obtain the stress-strain response of material specimens at strain rates in the order of 10 ² to 10 ⁴ 1/s. Its operation and associated data re- duction are based on principles of one-dimensional wave propagation in rods. Second order effects such as indentation of the bars by the specimen and wave dispersion in the bars, however, can significantly affect aspects of the measured material response. Finite element models of the experimental apparatus were used here to demonstrate these two effects. A procedure proposed by Safa and Gary (2010) to account for bar indentation was also evaluated and shown to improve the estimation of the strain in the bars significantly. The use of pulse shapers was also shown to alleviate the effects of wave dispersion. Combining the two can lead to more reliable results in Kolsky compression bar testing.

Enabling Dissimilar Material Joining Using Friction Stir Scribe Technology

Energy Technology Data Exchange (ETDEWEB)

Hovanski, Yuri; Upadyay, Piyush; Kleinbaum, Sarah; Carlson, Blair; Boettcher, Eric; Ruokolainen, Robert

2017-04-05

One challenge in adapting welding processes to dissimilar material joining is the diversity of melting temperatures of the different materials. Although the use of mechanical fasteners and adhesives have mostly paved the way for near-term implementation of dissimilar material systems, these processes only accentuate the need for low-cost welding processes capable of joining dissimilar material components regardless of alloy, properties, or melting temperature. Friction stir scribe technology was developed to overcome the challenges of joining dissimilar material components where melting temperatures vary greatly, and properties and/or chemistry are not compatible with more traditional welding processes. Although the friction stir scribe process is capable of joining dissimilar metals and metal/polymer systems, a more detailed evaluation of several aluminum/steel joints is presented herein to demonstrate the ability to both chemically and mechanically join dissimilar materials.

Mitigating Abnormal Grain Growth for Friction Stir Welded Al-Li 2195 Spun Formed Domes

Science.gov (United States)

Chen, Po-Shou; Russell, Carolyn

2012-01-01

Formability and abnormal grain growth (AGG) are the two major issues that have been encountered for Al alloy spun formed dome development using friction stir welded blanks. Material properties that have significant influence on the formability include forming range and strain hardening exponent. In this study, tensile tests were performed for two 2195 friction stir weld parameter sets at 400 F to study the effects of post weld anneal on the forming range and strain hardening exponent. It was found that the formability can be enhanced by applying a newly developed post weld anneal to heat treat the friction stir welded panels. This new post weld anneal leads to a higher forming range and much improved strain hardening exponent. AGG in the weld nugget is known to cause a significant reduction of ductility and fracture toughness. This study also investigated how AGG may be influenced by the heating rate to the solution heat treatment temperature. After post-weld annealing, friction stir welds were strained to 15% and 39% by compression at 400 F before they were subjected to SHT at 950 F for 1 hour. Salt bath SHT is very effective in reducing the grain size as it helps arrest the onset of AGG and promote normal recrystallization and grain growth. However, heat treating a 18 ft dome using a salt bath is not practical. Efforts are continuing at Marshall Space Flight Center to identify the welding parameters and heat treating parameters that can help mitigate the AGG in the friction stir welds.

A Modern Picture of Barred Galaxy Dynamics

Science.gov (United States)

Petersen, Michael; Weinberg, Martin; Katz, Neal

2018-01-01

Observations of disk galaxies suggest that bars are responsible for altering global galaxy parameters (e.g. structures, gas fraction, star formation rate). The canonical understanding of the mechanisms underpinning bar-driven secular dynamics in disk galaxies has been largely built upon the analysis of linear theory, despite galactic bars being clearly demonstrated to be nonlinear phenomena in n-body simulations. We present simulations of barred Milky Way-like galaxy models designed to elucidate nonlinear barred galaxy dynamics. We have developed two new methodologies for analyzing n-body simulations that give the best of both powerful analytic linear theory and brute force simulation analysis: orbit family identification and multicomponent torque analysis. The software will be offered publicly to the community for their own simulation analysis.The orbit classifier reveals that the details of kinematic components in galactic disks (e.g. the bar, bulge, thin disk, and thick disk components) are powerful discriminators of evolutionary paradigms (i.e. violent instabilities and secular evolution) as well as the basic parameters of the dark matter halo (mass distribution, angular momentum distribution). Multicomponent torque analysis provides a thorough accounting of the transfer of angular momentum between orbits, global patterns, and distinct components in order to better explain the underlying physics which govern the secular evolution of barred disk galaxies.Using these methodologies, we are able to identify the successes and failures of linear theory and traditional n-body simulations en route to a detailed understanding of the control bars exhibit over secular evolution in galaxies. We present explanations for observed physical and velocity structures in observations of barred galaxies alongside predictions for how structures will vary with dynamical properties from galaxy to galaxy as well as over the lifetime of a galaxy, finding that the transfer of angular

STIR-Physics: Cold Atoms and Nanocrystals in Tapered Nanofiber and High-Q Resonator Potentials

Science.gov (United States)

2016-11-02

STIR- Physics : Cold Atoms and Nanocrystals in Tapered Nanofiber and High-Q Resonator Potentials We worked on a tapered fiber in cold atomic cloud...reviewed journals: Number of Papers published in non peer-reviewed journals: Final Report: STIR- Physics : Cold Atoms and Nanocrystals in Tapered Nanofiber...other than abstracts): Number of Peer-Reviewed Conference Proceeding publications (other than abstracts): Books Number of Manuscripts: 0.00Number of

Tensile behavior of dissimilar friction stir welded joints of aluminium alloys

International Nuclear Information System (INIS)

Shanmuga Sundaram, N.; Murugan, N.

2010-01-01

The heat treatable aluminium alloy AA2024 is used extensively in the aircraft industry because of its high strength to weight ratio and good ductility. The non-heat treatable aluminium alloy AA5083 possesses medium strength and high ductility and used typically in structural applications, marine, and automotive industries. When compared to fusion welding processes, friction stir welding (FSW) process is an emerging solid state joining process which is best suitable for joining these alloys. The friction stir welding parameters such as tool pin profile, tool rotational speed, welding speed, and tool axial force influence the mechanical properties of the FS welded joints significantly. Dissimilar FS welded joints are fabricated using five different tool pin profiles. Central composite design with four parameters, five levels, and 31 runs is used to conduct the experiments and response surface method (RSM) is employed to develop the model. Mathematical regression models are developed to predict the ultimate tensile strength (UTS) and tensile elongation (TE) of the dissimilar friction stir welded joints of aluminium alloys 2024-T6 and 5083-H321, and they are validated. The effects of the above process parameters and tool pin profile on tensile strength and tensile elongation of dissimilar friction stir welded joints are analysed in detail. Joints fabricated using Tapered Hexagon tool pin profile have the highest tensile strength and tensile elongation, whereas the Straight Cylinder tool pin profile have the lowest tensile strength and tensile elongation. The results are useful to have a better understanding of the effects of process parameters, to fabricate the joints with desired tensile properties, and to automate the FS welding process.

Serial quantitative MR assessment of optic neuritis in a case of neuromyelitis optica, using gadolinium-'enhanced' STIR imaging

International Nuclear Information System (INIS)

Barkhof, F.; Scheltens, P.; Valk, J.; Waalewijn, C.; Uitdehaag, B.M.J.; Polman, C.H.

1991-01-01

A patient is presented with neuromyelitis optica. MR imaging, using a short inversion time inversion recovery (STIR) technique, clearly depicted the lesion in the left optic nerve. Subsequent serial STIR imaging, with and without Gadolinium-DTPA, allowed quantitative assessment of changes parallel to improved optic nerve function. STIR imaging is a sensitive technique to demonstrate optic nerve lesions, and enables quantitative assessment to be made of the effect of (steroid) medication. (orig.)

Scroll bar growth on the coastal Trinity River, TX, USA

Science.gov (United States)

Mason, J.; Hassenruck-Gudipati, H. J.; Mohrig, D. C.

2017-12-01

The processes leading to the formation and growth of scroll bars remain relatively mysterious despite how often they are referenced in fluvial literature. Their definition is descriptive; they are characterized as arcuate topographic highs present on the inner banks of channel bends on meandering rivers, landward of point bars. Often, they are used as proxies for previous positions of point bars. This assumption of a one-to-one correspondence between point bars and scroll bars should be reconsidered as 1) planform curvature for scroll bars is consistently smaller than the curvature for adjacent point bars, and 2) deposition on the scroll bar is typically distinct and disconnected from the adjacent point bar deposition. Results from time-lapse airborne lidar data as well as from trenches through five separate scroll bar - point bar pairings on the Trinity River in east TX, USA, will be discussed in relation to formative scroll bar processes and their connection to point bars. On the lidar difference map, scroll bar growth appears as a strip of increased deposition flanked on both the land- and channel-ward sides by areas with no or limited deposition. Trenches perpendicular to these scrolls typically show a base of dune-scale cross stratification interpreted to be associated with a previous position of the point bar. These dune sets are overlain by sets of climbing-ripple cross-strata that form the core of the modern scroll bar and preserve a record of multiple transport directions (away from, towards, and parallel to the channel). Preliminary Trinity River grain-size analyses show that the constructional scrolls are enriched in all grain sizes less than 250 microns in diameter, while point bars are enriched in all grain sizes above this cut off. Scroll bars are hypothesized to be akin to levees along the inner banks of channels-flow expansion caused by the presence of point bars induces deposition of suspended sediment that defines the positions of the scroll bars.

Friction stir scribe welding technique for dissimilar joining of aluminium and galvanised steel

Energy Technology Data Exchange (ETDEWEB)

Wang, Tianhao [Center for Friction Stir Processing, Department of Materials Science and Engineering, University of North Texas, Denton, TX, USA; Sidhar, Harpreet [Center for Friction Stir Processing, Department of Materials Science and Engineering, University of North Texas, Denton, TX, USA; Mishra, Rajiv S. [Center for Friction Stir Processing, Department of Materials Science and Engineering, University of North Texas, Denton, TX, USA; Hovanski, Yuri [Pacific Northwest National Laboratory, Energy Materials and Manufacturing, Richland, WA, USA; Upadhyay, Piyush [Pacific Northwest National Laboratory, Energy Materials and Manufacturing, Richland, WA, USA; Carlson, Blair [General Motors Technical Center, Warren, MI, USA

2017-10-04

Friction stir scribe technology, a derivative of friction stir welding, was applied for the dissimilar lap welding of an aluminum alloy and galvanized mild steel sheets. During the process, the rotating tool with a cobalt steel scribe first penetrated the top material — aluminum — and then the scribe cut the bottom material — steel. The steel was displaced into the upper material to produce a characteristic hook feature. Lap welds were shear tested, and their fracture paths were studied. Welding parameters affected the welding features including hook height, which turned out to be highly related to fracture position. Therefore, in this paper, the relationships among welding parameters, hook height, joint strength and fracture position are presented. In addition, influence of zinc coating on joint strength was also studied. Keywords: friction stir scribe technology; dissimilar material welding; zinc coating; hook height; joint strength; fracture position

Nutritional Evaluation of NASA's Rodent Food Bar Diet

Science.gov (United States)

Barrett, Joyce E.; Yu, Diane S.; Dalton, Bonnie P.

2000-01-01

Tests are being conducted on NASA's rodent Food Bar in preparation for long-term use as the rat and mouse diet aboard the International Space Station. Nutritional analyses are performed after the bars are manufactured and then repeated periodically to determine nutritional stability. The primary factors analyzed are protein, ash, fat, fiber, moisture, amino acids, fatty acids, and minerals. Nutrient levels are compared to values published in the National Research Council's dietary requirements for rodents, and also to those contained in several commonly used commercial rodent lab diets. The Food Bar is manufactured from a powdered diet to which moisture is added as it is processed through an extruder. The bars are dipped into potassium sorbate, vacuum-sealed, and irradiated. In order to determine nutrient changes during extrusion and irradiation, the powdered diet, the non-irradiated bars, and the irradiated bars are all analyzed. We have observed lower values for some nutrients (iodine, vitamin K, and iron) in the Food Bars compared with NRC requirements. Many nutrients in the Food Bars are contained at a higher level than levels in the NRC requirements. An additional factor we are investigating is the 26% moisture level in the Food Bars, which drops to about 15% within a week, compared to a stable 10% moisture in many standard lab chow diets. In addition to the nutritional analyses, the food bar is being fed to several strains of rats and mice, and feeding study and necropsy results are being observed (Barrett et al, unpublished data). Information from the nutritional analyses and from the rodent studies will enable us to recommend the formulation that will most adequately meet the rodent Food Bar requirements for long-term use aboard the Space Station.

The investigation of abnormal particle-coarsening phenomena in friction stir repair weld of 2219-T6 aluminum alloy

International Nuclear Information System (INIS)

Li, Bo; Shen, Yifu

2011-01-01

Highlights: → Defective friction stir welds were repaired by overlapping FSW technique. → Abnormal Al 2 Cu-coarsening phenomena were found in 2219-T6 friction stir repair weld. → Three formation mechanisms were proposed for reasonable explanations. -- Abstract: The single-pass friction stir weld of aluminum 2219-T6 with weld-defects was repaired by overlapping friction stir welding technique. However, without any post weld heat treatment process, it was found that the phenomena of abnormal particle-coarsening of Al 2 Cu had occurred in the overlapping friction stir repair welds. The detecting results of non-destructive X-ray inspection proved that not only one group of repair FSW process parameters could lead to occurrence of the abnormal phenomena. And the abnormally coarsened particles always appeared on the advancing side of repair welds rather than the retreating side where the fracture behaviors occurred after mechanical tensile testing. The size of the biggest particle lying in the dark bands of 'Onion-rings' was more than 150 μm. After the related investigation by scanning electron microscope and X-ray energy spectrometer, three types of formation mechanisms were proposed for reasonably explaining the abnormal phenomenon: Aggregation Mechanism, Diffusion Mechanisms I and II. Aggregation Mechanism was according to the motion-laws of stir-pin. Diffusion Mechanisms were based on the classical theories of precipitate growth in metallic systems. The combined action of the three detailed mechanisms contributed to the abnormal coarsening behavior of Al 2 Cu particles in the friction stir repair weld.

TiB2 reinforced aluminum based in situ composites fabricated by stir casting

International Nuclear Information System (INIS)

Chen, Fei; Chen, Zongning; Mao, Feng; Wang, Tongmin; Cao, Zhiqiang

2015-01-01

In this study, a new technique involving mechanical stirring at the salts/aluminum interface was developed to fabricate TiB 2 particulate reinforced aluminum based in situ composites with improved particle distribution. Processing parameters in terms of stirring intensity, stirring duration and stirring start time were optimized according to the microstructure and mechanical properties evaluation. The results show that, the first and last 15 min of the entire 60 min holding are of prime importance to the particle distribution of the final composites. When applying 180 rpm (revolutions per minute) stirring at the salts/aluminum interface in these two intervals, a more uniform microstructure can be achieved and the Al-4 wt% TiB 2 composite thus produced exhibits superior mechanical performance. Synchrotron radiation X-ray computed tomography (SR-CT) was used to give a full-scale imaging of the particle distribution. From the SR-CT results, the in situ Al–xTiB 2 composites (x=1, 4 and 7, all in wt%) fabricated by the present technique are characterized by fine and clean TiB 2 particles distributed uniformly throughout the Al matrix. These composites not only have higher yield strength (σ 0.2 ) and ultimate tensile strength (UTS), but also exhibit superior ductility, with respect to the Al–TiB 2 composites fabricated by the conventional process. The σ 0.2 and UTS of the Al–7TiB 2 composite in the present work, are 260% and 180% higher than those of the matrix. A combined mechanism was also presented to interpret the improvements in yield strength of the composites as influenced by their microstructures and processing history. The predicted values are in good agreement with the experimental results, strongly supporting the strengthening mechanism we proposed. Fractography reveals that the composites thus fabricated, follow ductile fracture mechanism in spite of the presence of stiff reinforcements

Characterization of Friction Stir Welded Tubes by Means of Tube Bulge Test

International Nuclear Information System (INIS)

D'Urso, G.; Longo, M.; Giardini, C.

2011-01-01

Mechanical properties of friction stir welded joints are generally evaluated by means of conventional tensile test. This testing method might provide insufficient information because maximum strain obtained in tensile test before necking is small; moreover, the application of tensile test is limited when the joint path is not linear or even when the welds are executed on curved surfaces. Therefore, in some cases, it would be preferable to obtain the joints properties from other testing methods. Tube bulge test can be a valid solution for testing circumferential or longitudinal welds executed on tubular workpieces. The present work investigates the mechanical properties and the formability of friction stir welded tubes by means of tube bulge tests. The experimental campaign was performed on tubular specimens having a thickness of 3 mm and an external diameter of 40 mm, obtained starting from two semi-tubes longitudinally friction stir welded. The first step, regarding the fabrication of tubes, was performed combining a conventional forming process and friction stir welding. Sheets in Al-Mg-Si-Cu alloy AA6060 T6 were adopted for this purpose. Plates having a dimension of 225x60 mm were bent (with a bending axis parallel to the main dimension) in order to obtain semi-tubes. A particular care was devoted to the fabrication of forming devices (punch and die) in order to minimize the springback effects. Semi-tubes were then friction stir welded by means of a CNC machine tool. Some preliminary tests were carried out by varying the welding parameters, namely feed rate and rotational speed. A very simple tool having flat shoulder and cylindrical pin was used. The second step of the research was based on testing the welded tubes by means of tube bulge test. A specific equipment having axial actuators with a conical shape was adopted for this study. Some analyses were carried out on the tubes bulged up to a certain pressure level. In particular, the burst pressure and the

Microstructure and microtexture studies of a friction stir welded Al 6061 alloy

International Nuclear Information System (INIS)

Kumbhar, N.T.; Tewari, R.; Dey, G.K.; Bhanumurthy, K.; Sahoo, S.K.; Samajdar, I.

2009-01-01

Friction stir welding is a solid state joining technique used extensively for the joining of various metals and alloys and also has been applied to the joining of steels. The friction stir welding of Al and its alloys has been extensively delt with over a period exceeding the last decade and a half due to its numerous advantages over other conventional fusion welding techniques in terms of weld quality, efficiency, cost effectiveness etc. to name a few. This technique is being increasingly seeked by industries in mass production/engineering such as the railways, marine and aerospace industries. The friction stir welding of a precipitation hardened Al 6061 alloy plates of 6 mm. thickness was performed at various tool rotation speeds and tool traverse speeds with a constant tilt of 3 deg using a high strength steel (HSS) tool of appropriate dimensions. The cross section of the weld perpendicular to the welding direction was analyzed for a detailed microstructural investigation using electron probe microanalysis, orientation imaging microscopy and transmission electron microscopy. Various microstructural changes are observed in the various regions of the friction stir welded AA 6061. The nugget region which is highly deformed is characterized by the dissolution and reprecipitation of the coarse precipitates, grain size refinement and recrystallization. The adjoining regions near the nugget viz the thermomechanically affected zone (TMAZ) and the heat affected zone (HAZ) also show heterogeneous microstructure in terms of grain size and precipitation which is mainly attributed to the heating cycle experienced during welding. This heterogeneity is also evident from the plot of microhardness distribution across the cross section of the weld region. However, the electron probe microanalysis studies do not show any significant pickup of oxygen in the weld interior as compared to a little oxygen pickup upto 30 μm from the top surface. Further, using orientation imaging

Friction stir welding of Aluminium matrix composites – A Review

Directory of Open Access Journals (Sweden)

Subramanya Prabhu

2018-01-01

Full Text Available Friction stir welding (FSW is established as one of the prominent welding techniques to join aluminium matrix composites (AMCs. It is a solid state welding process, takes place well below the melting temperature of the material, eliminates the detrimental effects of conventional fusion welding process. Although the process is capable to join AMCs, challenges are still open that need to be fulfill to widen its applications. This paper gives the outline of the friction stir welding technique used to join AMCs. Effect of process variables on the microstructure and mechanical properties of the joints, behavior of reinforcing materials during welding, effect of tool profiles on the joint strength are discussed in detail. Few improvements and direction for future research are also proposed.

Microstructure evolution in dissimilar AA6060/copper friction stir welded joints

Science.gov (United States)

Kalashnikova, T. A.; Shvedov, M. A.; Vasilyev, P. A.

2017-12-01

Friction stir welding process has been applied for making a dissimilar copper/aluminum alloy joint. The grain microstructure and mechanical properties of the obtained joint were studied. The structure of the cross-section of the FSW compound was analyzed. The microstructural evolution of the joint was examined using optical microscopy. The mechanical properties of the intermetallic particles were evaluated by measuring the microhardness according to the Vickers method. The microhardness of the intermetallic particles was by a factor of 4 lower than that of the particles obtained by fusion welding. The results of the investigations enable using friction stir welding for making dissimilar joints.

Ultrasonic stir welding process and apparatus

Science.gov (United States)

Ding, R. Jeffrey (Inventor)

2009-01-01

An ultrasonic stir welding device provides a method and apparatus for elevating the temperature of a work piece utilizing at least one ultrasonic heater. Instead of relying on a rotating shoulder to provide heat to a workpiece an ultrasonic heater is utilized to provide ultrasonic energy to the workpiece. A rotating pin driven by a motor assembly performs the weld on the workpiece. A handheld version can be constructed as well as a fixedly mounted embodiment.

Searches for $B^0_{(s)} \\to J/\\psi p\\bar{p}$ and $B^+ \\to J/\\psi p\\bar{p}\\pi^+$ decays

CERN Document Server

INSPIRE-00258707; Adeva, B; Adinolfi, M; Adrover, C; Affolder, A; Ajaltouni, Z; Albrecht, J; Alessio, F; Alexander, M; Ali, S; Alkhazov, G; Alvarez Cartelle, P; Alves Jr, A A; Amato, S; Amerio, S; Amhis, Y; Anderlini, L; Anderson, J; Andreassen, R; Andrews, J E; Appleby, R B; Aquines Gutierrez, O; Archilli, F; Artamonov, A; Artuso, M; Aslanides, E; Auriemma, G; Baalouch, M; Bachmann, S; Back, J J; Baesso, C; Balagura, V; Baldini, W; Barlow, R J; Barschel, C; Barsuk, S; Barter, W; Bauer, Th; Bay, A; Beddow, J; Bedeschi, F; Bediaga, I; Belogurov, S; Belous, K; Belyaev, I; Ben-Haim, E; Bencivenni, G; Benson, S; Benton, J; Berezhnoy, A; Bernet, R; Bettler, M -O; van Beuzekom, M; Bien, A; Bifani, S; Bird, T; Bizzeti, A; Bjørnstad, P M; Blake, T; Blanc, F; Blouw, J; Blusk, S; Bocci, V; Bondar, A; Bondar, N; Bonivento, W; Borghi, S; Borgia, A; Bowcock, T J V; Bowen, E; Bozzi, C; Brambach, T; van den Brand, J; Bressieux, J; Brett, D; Britsch, M; Britton, T; Brook, N H; Brown, H; Burducea, I; Bursche, A; Busetto, G; Buytaert, J; Cadeddu, S; Callot, O; Calvi, M; Calvo Gomez, M; Camboni, A; Campana, P; Campora Perez, D; Carbone, A; Carboni, G; Cardinale, R; Cardini, A; Carranza-Mejia, H; Carson, L; Carvalho Akiba, K; Casse, G; Castillo Garcia, L; Cattaneo, M; Cauet, Ch; Cenci, R; Charles, M; Charpentier, Ph; Chen, P; Chiapolini, N; Chrzaszcz, M; Ciba, K; Cid Vidal, X; Ciezarek, G; Clarke, P E L; Clemencic, M; Cliff, H V; Closier, J; Coca, C; Coco, V; Cogan, J; Cogneras, E; Collins, P; Comerma-Montells, A; Contu, A; Cook, A; Coombes, M; Coquereau, S; Corti, G; Couturier, B; Cowan, G A; Craik, D C; Cunliffe, S; Currie, R; D'Ambrosio, C; David, P; David, P N Y; Davis, A; De Bonis, I; De Bruyn, K; De Capua, S; De Cian, M; De Miranda, J M; De Paula, L; De Silva, W; De Simone, P; Decamp, D; Deckenhoff, M; Del Buono, L; Déléage, N; Derkach, D; Deschamps, O; Dettori, F; Di Canto, A; Di Ruscio, F; Dijkstra, H; Dogaru, M; Donleavy, S; Dordei, F; Dosil Suárez, A; Dossett, D; Dovbnya, A; Dupertuis, F; Durante, P; Dzhelyadin, R; Dziurda, A; Dzyuba, A; Easo, S; Egede, U; Egorychev, V; Eidelman, S; van Eijk, D; Eisenhardt, S; Eitschberger, U; Ekelhof, R; Eklund, L; El Rifai, I; Elsasser, Ch; Falabella, A; Färber, C; Fardell, G; Farinelli, C; Farry, S; Fave, V; Ferguson, D; Fernandez Albor, V; Ferreira Rodrigues, F; Ferro-Luzzi, M; Filippov, S; Fiore, M; Fitzpatrick, C; Fontana, M; Fontanelli, F; Forty, R; Francisco, O; Frank, M; Frei, C; Frosini, M; Furcas, S; Furfaro, E; Gallas Torreira, A; Galli, D; Gandelman, M; Gandini, P; Gao, Y; Garofoli, J; Garosi, P; Garra Tico, J; Garrido, L; Gaspar, C; Gauld, R; Gersabeck, E; Gersabeck, M; Gershon, T; Ghez, Ph; Gibson, V; Giubega, L; Gligorov, V V; Göbel, C; Golubkov, D; Golutvin, A; Gomes, A; Gordon, H; Grabalosa Gándara, M; Graciani Diaz, R; Granado Cardoso, L A; Graugés, E; Graziani, G; Grecu, A; Greening, E; Gregson, S; Griffith, P; Grünberg, O; Gui, B; Gushchin, E; Guz, Yu; Gys, T; Hadjivasiliou, C; Haefeli, G; Haen, C; Haines, S C; Hall, S; Hamilton, B; Hampson, T; Hansmann-Menzemer, S; Harnew, N; Harnew, S T; Harrison, J; Hartmann, T; He, J; Head, T; Heijne, V; Hennessy, K; Henrard, P; Hernando Morata, J A; van Herwijnen, E; Hicheur, A; Hicks, E; Hill, D; Hoballah, M; Holtrop, M; Hombach, C; Hopchev, P; Hulsbergen, W; Hunt, P; Huse, T; Hussain, N; Hutchcroft, D; Hynds, D; Iakovenko, V; Idzik, M; Ilten, P; Jacobsson, R; Jaeger, A; Jans, E; Jaton, P; Jawahery, A; Jing, F; John, M; Johnson, D; Jones, C R; Joram, C; Jost, B; Kaballo, M; Kandybei, S; Kanso, W; Karacson, M; Karbach, T M; Kenyon, I R; Ketel, T; Keune, A; Khanji, B; Kochebina, O; Komarov, I; Koopman, R F; Koppenburg, P; Korolev, M; Kozlinskiy, A; Kravchuk, L; Kreplin, K; Kreps, M; Krocker, G; Krokovny, P; Kruse, F; Kucharczyk, M; Kudryavtsev, V; Kvaratskheliya, T; La Thi, V N; Lacarrere, D; Lafferty, G; Lai, A; Lambert, D; Lambert, R W; Lanciotti, E; Lanfranchi, G; Langenbruch, C; Latham, T; Lazzeroni, C; Le Gac, R; van Leerdam, J; Lees, J -P; Lefèvre, R; Leflat, A; Lefrançois, J; Leo, S; Leroy, O; Lesiak, T; Leverington, B; Li, Y; Li Gioi, L; Liles, M; Lindner, R; Linn, C; Liu, B; Liu, G; Lohn, S; Longstaff, I; Lopes, J H; Lopez-March, N; Lu, H; Lucchesi, D; Luisier, J; Luo, H; Machefert, F; Machikhiliyan, I V; Maciuc, F; Maev, O; Malde, S; Manca, G; Mancinelli, G; Maratas, J; Marconi, U; Marino, P; Märki, R; Marks, J; Martellotti, G; Martens, A; Martín Sánchez, A; Martinelli, M; Martinez Santos, D; Martins Tostes, D; Massafferri, A; Matev, R; Mathe, Z; Matteuzzi, C; Maurice, E; Mazurov, A; Mc Skelly, B; McCarthy, J; McNab, A; McNulty, R; Meadows, B; Meier, F; Meissner, M; Merk, M; Milanes, D A; Minard, M -N; Molina Rodriguez, J; Monteil, S; Moran, D; Morawski, P; Mordà, A; Morello, M J; Mountain, R; Mous, I; Muheim, F; Müller, K; Muresan, R; Muryn, B; Muster, B; Naik, P; Nakada, T; Nandakumar, R; Nasteva, I; Needham, M; Neubert, S; Neufeld, N; Nguyen, A D; Nguyen, T D; Nguyen-Mau, C; Nicol, M; Niess, V; Niet, R; Nikitin, N; Nikodem, T; Nomerotski, A; 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Wimberley, J; Wishahi, J; Witek, M; Wotton, S A; Wright, S; Wu, S; Wyllie, K; Xie, Y; Xing, Z; Yang, Z; Young, R; Yuan, X; Yushchenko, O; Zangoli, M; Zavertyaev, M; Zhang, F; Zhang, L; Zhang, W C; Zhang, Y; Zhelezov, A; Zhokhov, A; Zhong, L; Zvyagin, A

2013-01-01

The results of searches for $B^0_{(s)} \\to J/\\psi p\\bar{p}$ and $B^+ \\to J/\\psi p\\bar{p}\\pi^+$ decays are reported. The analysis is based on a data sample, corresponding to an integrated luminosity of 1.0 fb$^{-1}$ of $pp$ collisions, collected with the LHCb detector. An excess with 2.8 $\\sigma$ significance is seen for the decay $B^0_{s} \\to J/\\psi p\\bar{p}$ and an upper limit on the branching fraction is set at the 90% confidence level: $B(B^0_s \\to J/\\psi p\\bar{p}) \\lt$ 4.8 x 10$^{-6}$, which is the first such limit. No significant signals are seen for $B^0 \\to J/\\psi p\\bar{p}$ and $B^+ \\to J/\\psi p\\bar{p}\\pi^+$ decays, for which the corresponding limits are set: $B(B^0 \\to J/\\psi p\\bar{p}) \\lt$ 5.2 x 10$^{-7}$, which significantly improves the existing limit; and $B(B^+ \\to J/\\psi p\\bar{p}\\pi^+) \\lt$ 5.0 x 10$^{-7}$, which is the first limit on this branching fraction.

Low-temperature growth of (2 1-bar 1-bar 0) ZnO nanofilm on NaCl (0 0 1) surface by ion beam sputtering

International Nuclear Information System (INIS)

Shen, Jung-Hsiung; Yeh, Sung-Wei; Huang, Hsing-Lu; Gan, Dershin

2009-01-01

ZnO nanofilm of the (2 1 -bar 1 -bar 0) surface was prepared by ion beam sputtering deposition. The nanofilm was prepared on NaCl (0 0 1) surface at 200 o C to produce nearly pure (2 1 -bar 1 -bar 0) ZnO texture and the orientation relationship was determined and the interface discussed. Transmission electron microscopy lattice images were used to find the interface formed between ZnO nanocrystals. The ZnO nanocrystals coalesced to form a straight (0 1 -bar 1 -bar 2) interface. The photoluminescence spectrum from the (2 1 -bar 1 -bar 0) ZnO surface showed only a near-band-edge UV emission peak.

Nearshore bars and the break-point hypothesis

Science.gov (United States)

Sallenger, A.H.; Howd, P.A.

1989-01-01

The set of hypotheses calling for bar formation at the break point was tested with field data. During two different experiments, waves were measured across the surf zone coincident with the development of a nearshore bar. We use a criterion, based on the wave height to depth ratio, to determine the offshore limit of the inner surf zone. During the first experiment, the bar became better developed and migrated offshore while remaining well within the inner surf zone. During the second experiment, the surf zone was narrower and we cannot rule out the possibility of break point processes contributing to bar development. We conclude that bars are not necessarily coupled with the break point and can become better developed and migrate offshore while being in the inner surf zone landward from initial wave breaking in the outer surf zone. ?? 1989.

Charmonium and bottomonium in bar pp interactions

International Nuclear Information System (INIS)

Pordes, S.

1993-12-01

In this talk, I presented some examples of data from the CDF collaboration on J/ψ, χ, ψ' and Γ production. Such data are used to test models of production dynamics and for the understanding of rates for b quark production. I am not a member of the CDF experiment and showed their data with permission as an interested and impressed spectator. Data from D0 may be found in the talk of D. Denisov. As a complement to this data from the highest energy accelerator experiment, operating at √ bar s= 1.8 TeV, I also showed data from Fermilab experiment E760 on masses, widths, states and branching ratios in the Charmonium system, obtained by studying resonant formation of c bar c states in p bar p annihilation at √ bar s = m(c bar c)

ON THE CURVATURE OF DUST LANES IN GALACTIC BARS

International Nuclear Information System (INIS)

Comeron, Sebastien; MartInez-Valpuesta, Inma; Knapen, Johan H.; Beckman, John E.

2009-01-01

We test the theoretical prediction that the straightest dust lanes in bars are found in strongly barred galaxies, or more specifically, that the degree of curvature of the dust lanes is inversely proportional to the strength of the bar. The test uses archival images of barred galaxies for which a reliable nonaxisymmetric torque parameter (Q b ) and the radius at which Q b has been measured (r(Q b )) have been published in the literature. Our results confirm the theoretical prediction but show a large spread that cannot be accounted for by measurement errors. We simulate 238 galaxies with different bar and bulge parameters in order to investigate the origin of the spread in the dust lane curvature versus Q b relation. From these simulations, we conclude that the spread is greatly reduced when describing the bar strength as a linear combination of the bar parameters Q b and the quotient of the major and minor axes of the bar, a/b. Thus, we conclude that the dust lane curvature is predominantly determined by the parameters of the bar.

Experimental Study on Basic Mechanical Properties of BFRP Bars

Science.gov (United States)

Fan, Xiaochun; Xu, Ting; Zhou, Zhengrong; Zhou, Xun

2017-10-01

Basalt Fiber Reinforced Polymer (BFRP) bars have the advantages of corrosion resistance, high strength, light weight, good dielectric properties, and they are new type of green reinforced alternative material. In order to determine the mechanical properties of BFRP bars, the tensile strength of basalt fiber bars was necessary to be studied. The diameters of the basalt fiber bars were compared by means of uniaxial tensile test in this article. Then the stress-strain curve can be drawn out. The results show that the stress - strain curve of BFRP bars present straight line relation, and there is no sign before failure; there is no yield platform on the stress-strain curve of BFRP bars, which are typical brittle material;the tensile strength of BFRP bars is about 3 times higher than that of ordinary steel bars. and the elastic modulus is about 1/5 of that of ordinary steel; the ultimate tensile strength of BFRP bars varies little with the increase of diameter, but there exist some differences in modulus values.

Mechanical Properties of Welded Deformed Reinforcing Steel Bars

Directory of Open Access Journals (Sweden)

Ghafur H. Ahmed

2015-05-01

Full Text Available Reinforcement strength, ductility and bendability properties are important components in design of reinforced concrete members, as the strength of any member comes mainly from reinforcement. Strain compatibility and plastic behaviors are mainly depending on reinforcement ductility. In construction practice, often welding of the bars is required. Welding of reinforcement is an instant solution in many cases, whereas welding is not a routine connection process. Welding will cause deficiencies in reinforcement bars, metallurgical changes and re-crystallization of microstructure of particles. Weld metal toughness is extremely sensitive to the welding heat input that decreases both of its strength and ductility. For determining the effects of welding in reinforcement properties, 48 specimens were tested with 5 different bar diameters, divided into six groups. Investigated parameters were: properties of un-welded bars; strength, ductility and density of weld metal; strength and ductility reduction due to heat input for bundled bars and transverse bars; welding effect on bars’ bending properties; behavior of different joint types; properties of three weld groove shapes also the locations and types of failures sections. Results show that, strength and elongation of the welded bars decreased by (10-40% and (30-60% respectively. Cold bending of welded bars and groove welds shall be prevented.

A compact active grid for stirring pipe flow

NARCIS (Netherlands)

Verbeek, A.A.; Pos, R.C.; Stoffels, G.G.M.; Geurts, B.J.; Meer, van der Th.

2013-01-01

A compact active grid is developed with which a pipe flow can be stirred in order to enhance the turbulence. The active grid is composed of a stationary and a rotating disk with characteristic hole patterns. This active grid is placed inside the pipe, allowing flow to pass through it. With only one

A compact active grid for stirring pipe flow

NARCIS (Netherlands)

Verbeek, Antonie Alex; Pos, R.C.; Stoffels, Genie G.M.; Geurts, Bernardus J.; van der Meer, Theodorus H.

A compact active grid is developed with which a pipe flow can be stirred in order to enhance the turbulence. The active grid is composed of a stationary and a rotating disk with characteristic hole patterns. This active grid is placed inside the pipe, allowing flow to pass through it. With only one